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0.8528645833333334}, {"start": 270.28, "end": 270.5, "word": " ولا", "probability": 0.80712890625}, {"start": 270.5, "end": 271.18, "word": " سلبه", "probability": 0.75732421875}, {"start": 271.18, "end": 273.14, "word": " سلبه", "probability": 0.810546875}, {"start": 273.14, "end": 274.46, "word": " اذا", "probability": 0.90087890625}, {"start": 274.46, "end": 274.74, "word": " كانت", "probability": 0.850830078125}, {"start": 274.74, "end": 275.2, "word": " العكس", "probability": 0.9562174479166666}, {"start": 275.2, "end": 275.46, "word": " ايش", "probability": 0.7256673177083334}, {"start": 275.46, "end": 275.82, "word": " هتكون", "probability": 0.6609700520833334}, {"start": 275.82, "end": 276.24, "word": " هين", "probability": 0.835693359375}, {"start": 276.24, "end": 276.66, "word": " سلبه", "probability": 0.9560546875}, {"start": 276.66, "end": 276.98, "word": " هين", "probability": 0.78955078125}, {"start": 276.98, "end": 277.76, "word": " موجبه", "probability": 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"word": " بناء", "probability": 0.788330078125}, {"start": 298.12, "end": 298.3, "word": " على", "probability": 0.84814453125}, {"start": 298.3, "end": 298.5, "word": " ال", "probability": 0.98388671875}, {"start": 298.5, "end": 298.92, "word": " convention", "probability": 0.955078125}, {"start": 298.92, "end": 299.42, "word": " هذا", "probability": 0.64404296875}, {"start": 299.42, "end": 300.5, "word": " إذا", "probability": 0.78857421875}, {"start": 300.5, "end": 300.86, "word": " باخد", "probability": 0.8649088541666666}, {"start": 300.86, "end": 301.38, "word": " section", "probability": 0.509765625}, {"start": 301.38, "end": 302.46, "word": " اللى", "probability": 0.899169921875}, {"start": 302.46, "end": 302.56, "word": " على", "probability": 0.482666015625}, {"start": 302.56, "end": 303.08, "word": " الشمال", "probability": 0.94580078125}, {"start": 303.08, "end": 303.62, "word": " أخد", "probability": 0.8639322916666666}, {"start": 303.62, "end": 303.84, "word": " الجزء", "probability": 0.80517578125}, {"start": 303.84, "end": 304.24, "word": " هذا", "probability": 0.89990234375}, {"start": 304.24, "end": 308.04, "word": " اه", "probability": 0.734130859375}, {"start": 308.04, "end": 310.2, "word": " فانا", "probability": 0.82470703125}, {"start": 310.2, "end": 310.48, "word": " الأصل", "probability": 0.79150390625}, {"start": 310.48, "end": 310.92, "word": " أخدت", "probability": 0.9554443359375}, {"start": 310.92, "end": 311.08, "word": " ال", "probability": 0.86474609375}, {"start": 311.08, "end": 311.44, "word": " section", "probability": 0.89501953125}, {"start": 311.44, "end": 311.66, "word": " أنا", "probability": 0.51318359375}, {"start": 311.66, "end": 311.9, "word": " عندى", "probability": 0.74658203125}, {"start": 311.9, "end": 312.04, "word": " هنا", "probability": 0.58251953125}, {"start": 312.04, "end": 312.4, "word": " أخدت", "probability": 0.94287109375}, {"start": 312.4, "end": 312.74, "word": " section", "probability": 0.67041015625}, {"start": 312.74, "end": 313.02, "word": " هنا", "probability": 0.79931640625}], "temperature": 1.0}, {"id": 12, "seek": 34027, "start": 315.51, "end": 340.27, "text": "هذا هتكون ال V عكس مظبوط و ال moment عكسه ال moment عكس و ال V عكس واضح يعني انا باخد يا جهة الشمال او الجهة اليامين لو خدت الجهة اليامين هتكون ال V عكس ال V و ال M عكس ال M بشكل عام", "tokens": [3224, 15730, 8032, 2655, 30544, 2423, 691, 6225, 4117, 3794, 3714, 19913, 3555, 2407, 9566, 4032, 2423, 1623, 6225, 4117, 3794, 3224, 2423, 1623, 6225, 4117, 3794, 4032, 2423, 691, 6225, 4117, 3794, 4032, 46958, 5016, 37495, 22653, 1975, 8315, 4724, 47283, 3215, 35186, 10874, 3224, 3660, 25124, 2304, 6027, 1975, 2407, 25724, 3224, 3660, 45595, 10943, 9957, 45164, 16490, 3215, 2655, 25724, 3224, 3660, 45595, 10943, 9957, 8032, 2655, 30544, 2423, 691, 6225, 4117, 3794, 2423, 691, 4032, 2423, 376, 6225, 4117, 3794, 2423, 376, 4724, 8592, 28820, 6225, 10943], "avg_logprob": -0.17170516109984854, "compression_ratio": 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negative بناخد زي ما حكينا هاي ال section تكملته هنا هكون V هكون عكسها V", "tokens": [28814, 15730, 16490, 3215, 2655, 27188, 16572, 28671, 11778, 1829, 10874, 2288, 10943, 9154, 25124, 2304, 6027, 4032, 25961, 25124, 13546, 5296, 2655, 5016, 23758, 3353, 13412, 13546, 4032, 11933, 15730, 25961, 2655, 2423, 22487, 1623, 5682, 35790, 4724, 3615, 4117, 3794, 6225, 4587, 9640, 3555, 21136, 995, 27884, 39894, 30544, 11933, 1829, 8592, 3353, 11778, 1829, 1975, 2655, 10721, 4117, 3215, 41850, 3353, 49429, 3671, 44945, 47283, 3215, 30767, 1829, 19446, 11331, 4117, 1829, 8315, 8032, 47302, 2423, 3541, 6055, 24793, 1211, 47395, 34105, 8032, 30544, 691, 8032, 30544, 6225, 4117, 3794, 11296, 691], "avg_logprob": -0.40266926245143014, "compression_ratio": 1.6422413793103448, "no_speech_prob": 0.0, "words": [{"start": 343.27, "end": 343.57, "word": "إذا", "probability": 0.64208984375}, {"start": 343.57, "end": 344.15, "word": " خدت", "probability": 0.60546875}, {"start": 344.15, "end": 344.59, 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{"start": 418.32, "end": 418.56, "word": " per", "probability": 0.89404296875}, {"start": 418.56, "end": 418.9, "word": " unit", "probability": 0.9658203125}, {"start": 418.9, "end": 419.54, "word": " length", "probability": 0.83935546875}, {"start": 419.54, "end": 420.82, "word": " load", "probability": 0.6484375}, {"start": 420.82, "end": 421.42, "word": " موزع", "probability": 0.9808349609375}, {"start": 421.42, "end": 422.08, "word": " يعني", "probability": 0.9404296875}, {"start": 422.08, "end": 422.52, "word": " حمل", "probability": 0.847412109375}, {"start": 422.52, "end": 423.14, "word": " لكل", "probability": 0.97998046875}, {"start": 423.14, "end": 423.76, "word": " وحدة", "probability": 0.8483072916666666}, {"start": 423.76, "end": 424.54, "word": " طول", "probability": 0.992431640625}], "temperature": 1.0}, {"id": 16, "seek": 45275, "start": 425.87, "end": 452.75, "text": "من ال mechanics of material كان في عندنا علاقات اللي هي V بيساوي DM by DX ال shear force بيساوي DM by DX هذا في ال mechanics of material معناه دي DM بيساوي V DX", "tokens": [27842, 2423, 12939, 295, 2527, 25961, 8978, 43242, 8315, 11203, 995, 4587, 9307, 13672, 1829, 39896, 691, 4724, 1829, 3794, 995, 45865, 15322, 538, 48817, 2423, 24082, 3464, 4724, 1829, 3794, 995, 45865, 15322, 538, 48817, 23758, 8978, 2423, 12939, 295, 2527, 20449, 8315, 3224, 11778, 1829, 15322, 4724, 1829, 3794, 995, 45865, 691, 48817], "avg_logprob": -0.29771204771740095, "compression_ratio": 1.5492957746478873, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 425.87, "end": 426.19, "word": "من", "probability": 0.74755859375}, {"start": 426.19, "end": 426.45, "word": " ال", "probability": 0.82177734375}, {"start": 426.45, "end": 426.81, "word": " mechanics", "probability": 0.58056640625}, {"start": 426.81, "end": 427.05, "word": " of", "probability": 0.6962890625}, {"start": 427.05, "end": 427.55, "word": " material", "probability": 0.744140625}, {"start": 427.55, "end": 429.41, "word": " كان", 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" pound", "probability": 0.841796875}, {"start": 3895.91, "end": 3897.45, "word": " انش", "probability": 0.7376708984375}, {"start": 3897.45, "end": 3897.69, "word": " وال", "probability": 0.54833984375}, {"start": 3897.69, "end": 3898.07, "word": " R1", "probability": 0.90625}, {"start": 3898.07, "end": 3898.23, "word": " ده", "probability": 0.773193359375}, {"start": 3898.23, "end": 3900.17, "word": " كم؟", "probability": 0.9029947916666666}, {"start": 3900.17, "end": 3900.39, "word": " ربما", "probability": 0.45361328125}, {"start": 3900.39, "end": 3900.65, "word": " تبقى", "probability": 0.48291015625}, {"start": 3900.65, "end": 3901.17, "word": " تمانين", "probability": 0.8955078125}, {"start": 3901.17, "end": 3901.93, "word": " تمانين", "probability": 0.9747721354166666}, {"start": 3901.93, "end": 3902.99, "word": " pound", "probability": 0.8564453125}], "temperature": 1.0}, {"id": 132, "seek": 394090, "start": 3914.58, "end": 3940.9, "text": "الـ V هتكون تساوي هد مش هتشتغل غير 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0000000000000000000000000000000000000000..d5600d10bdc41b6b8910f45d157bbc91eb70c1d2 --- /dev/null +++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/3L4rgUC4wgc_raw.srt @@ -0,0 +1,2524 @@ +1 +00:00:05,770 --> 00:00:09,130 +طيب بسم الله الرحمن الرحيم السلام عليكم ورحمة الله + +2 +00:00:09,130 --> 00:00:12,290 +وبركاته اليوم هنبدأ محاضرة زيدة في مادة تصميم + +3 +00:00:12,290 --> 00:00:16,590 +الألات هتكون chapter اللي هو load and stress + +4 +00:00:16,590 --> 00:00:20,370 +analysis ال chapter هذا فيه مراجعة على مادة + +5 +00:00:20,370 --> 00:00:24,990 +mechanics of material في إضافات أكتر على مستوى على + +6 +00:00:24,990 --> 00:00:28,890 +شوية من ال mechanics of material من حيث الموضوعات + +7 +00:00:28,890 --> 00:00:31,210 +أو من حيث العمق في التحليل + +8 +00:00:34,340 --> 00:00:39,800 +هنبدأ في ال shear و ال .. ال .. ال .. و ال bending + +9 +00:00:39,800 --> 00:00:47,060 +moment diagrams و كيفية حسابه + +10 +00:00:47,060 --> 00:00:54,260 +ان بيه عندى beam فى عندى beam فى support على أطراف + +11 +00:00:54,260 --> 00:00:58,440 +فى support على الطرف الأيصر و support على الطرف + +12 +00:00:58,440 --> 00:01:02,800 +الأيمن المحاور اللى هو عندى X + +13 +00:01:05,840 --> 00:01:15,760 +هذا المحور Y فين دي force F1 تأثر هنا فين F2 و F3 + +14 +00:01:15,760 --> 00:01:22,260 +طبعا هكون فين دي رد فعل R1 وهين + +15 +00:01:22,260 --> 00:01:33,550 +رد فعل R2 لو أخدت section على بعد X1وعملت free + +16 +00:01:33,550 --> 00:01:37,650 +body diagram هيكون + +17 +00:01:37,650 --> 00:01:43,450 +عندهين هاي المسافة X واحد هاي R واحد طبعا هاد ال X + +18 +00:01:43,450 --> 00:01:51,310 +هاد ال Y وعند ال force F واحد هيكون عكس الرد الفعل + +19 +00:01:51,310 --> 00:01:54,870 +shear force V + +20 +00:01:57,260 --> 00:02:03,120 +و بندق moment M كي share force يلا اخدت ال moment + +21 +00:02:03,120 --> 00:02:04,720 +حوالين هذه هتكون عنده + +22 +00:02:08,670 --> 00:02:13,290 +الار واحد هتروح هتكون F واحد في المسافة بتاعتها + +23 +00:02:13,290 --> 00:02:16,350 +زائد + +24 +00:02:16,350 --> 00:02:22,830 +V في X واحد minus M بالساوياش Zero و لو أخرص ماشي + +25 +00:02:22,830 --> 00:02:28,150 +ال force باتجاه ال Y بتكون R واحد بالساوياش F واحد + +26 +00:02:28,150 --> 00:02:32,650 +زائد V الأن + +27 +00:02:32,650 --> 00:02:37,200 +أنا أخدت section هنا على البعد X واحدفكان عندي .. + +28 +00:02:37,200 --> 00:02:41,800 +عندي section عندي shear force V و M لو أخدت + +29 +00:02:41,800 --> 00:02:48,100 +another section على بعد delta + +30 +00:02:48,100 --> 00:02:53,940 +X و + +31 +00:02:53,940 --> 00:03:01,040 +أخدت ال section اللي انطلعته كان + +32 +00:03:01,040 --> 00:03:02,220 +عندي هنا V + +33 +00:03:13,420 --> 00:03:20,620 +وعندي counter clause M هيكون + +34 +00:03:20,620 --> 00:03:25,980 +هنا معاكس له M + +35 +00:03:25,980 --> 00:03:35,960 +زاد delta M و لو حكي هنا عايش V هذه المسافة + +36 +00:03:51,650 --> 00:03:59,350 +الان بعتبر moment موجبة اذا بتحاول تتنى ال beam + +37 +00:03:59,350 --> 00:04:04,470 +لتحت تخلى ال moment موجبة اذا بتحاول تخلى ال beam + +38 +00:04:04,470 --> 00:04:08,330 +بالشكل هذا يعني اذا في عندى moment بالشكل هذا + +39 +00:04:11,600 --> 00:04:15,540 +هي تعتبر positive bending moment positive bending + +40 +00:04:15,540 --> 00:04:22,240 +moment اذا + +41 +00:04:22,240 --> 00:04:25,860 +هو يبين دي هين فهي positive bending moment وبعرف + +42 +00:04:25,860 --> 00:04:28,680 +انا باخد small increment delta X يعني في الحالة + +43 +00:04:28,680 --> 00:04:35,200 +هذه moment هين موجب ولا سلبه سلبه اذا كانت العكس + +44 +00:04:35,200 --> 00:04:39,460 +ايش هتكون هين سلبه هين موجبه ال shear force + +45 +00:04:46,160 --> 00:04:49,340 +هذا positive وهذا negative حالتنا مش هتكون المبينة + +46 +00:04:49,340 --> 00:04:56,100 +عندى هنا negative share negative share بشكل عام + +47 +00:04:56,100 --> 00:04:59,420 +عشان مافكرش كتير فيها بناء على ال convention هذا + +48 +00:04:59,420 --> 00:05:08,040 +إذا باخد section اللى على الشمال أخد الجزء هذا اه + +49 +00:05:08,040 --> 00:05:12,400 +فانا الأصل أخدت ال section أنا عندى هنا أخدت + +50 +00:05:12,400 --> 00:05:21,870 +section هناهذا هتكون ال V عكس مظبوط و ال moment + +51 +00:05:21,870 --> 00:05:30,130 +عكسه ال moment عكس و ال V عكس واضح يعني انا باخد + +52 +00:05:30,130 --> 00:05:34,350 +يا جهة الشمال او الجهة اليامين لو خدت الجهة + +53 +00:05:34,350 --> 00:05:39,990 +اليامين هتكون ال V عكس ال V و ال M عكس ال M بشكل + +54 +00:05:39,990 --> 00:05:40,270 +عام + +55 +00:05:43,270 --> 00:05:47,230 +إذا خدت الفريقة دي جرام من الشمال و كان الشير لتح + +56 +00:05:47,230 --> 00:05:49,870 +هذا positive شير و إذا كانت ال bending moment + +57 +00:05:49,870 --> 00:05:52,850 +counter clockwise بعكس عقارب الساعة بتكون إيش + +58 +00:05:52,850 --> 00:05:58,330 +positive دي + +59 +00:05:58,330 --> 00:06:05,210 +اتأكد أنا positive ولا negative بناخد + +60 +00:06:05,210 --> 00:06:09,530 +زي ما حكينا هاي ال section تكملته هنا هكون V هكون + +61 +00:06:09,530 --> 00:06:17,500 +عكسها Vو ال moment هيكون هاي عكسها و باخد + +62 +00:06:17,500 --> 00:06:22,260 +increment على جواه دلتا X هيكون هاي دي moment و + +63 +00:06:22,260 --> 00:06:26,440 +هاي V هذي الحالة تمثل positive moment و positive + +64 +00:06:26,440 --> 00:06:31,740 +share معناته + +65 +00:06:31,740 --> 00:06:37,680 +بشكل تلقائي بتكون share is positiveإذا كان نازل + +66 +00:06:37,680 --> 00:06:42,040 +لتحت و ماخد ال section على الشمال و ال moment تكون + +67 +00:06:42,040 --> 00:06:50,280 +بعكس عقارب الساعة بعتبرها positive عندى + +68 +00:06:50,280 --> 00:06:54,540 +beam simply supported beam في عندى عليه + +69 +00:06:54,540 --> 00:07:00,820 +distributed load QX يعني load per unit length load + +70 +00:07:00,820 --> 00:07:07,050 +موزع يعني حمل لكل وحدة طولمن ال mechanics of + +71 +00:07:07,050 --> 00:07:14,550 +material كان في عندنا علاقات اللي هي V بيساوي DM + +72 +00:07:14,550 --> 00:07:23,890 +by DX ال shear force بيساوي DM by DX هذا في ال + +73 +00:07:23,890 --> 00:07:30,670 +mechanics of material معناه دي DM بيساوي + +74 +00:07:30,670 --> 00:07:47,050 +V DXلو أخد التكامل بين a و b ما ل mb وهنا من xa ل + +75 +00:07:47,050 --> 00:07:59,790 +xb هكون ان ال mb minus ma بالساوية تكامل vdx من xa + +76 +00:07:59,790 --> 00:08:15,150 +ل xb يعني ال mbبستوى MA زائد تكامل XA ل XB VDX + +77 +00:08:15,150 --> 00:08:22,850 +يعني ال B اللي انتوا شايفينه هنا لاخد + +78 +00:08:22,850 --> 00:08:30,810 +سكشن هذه A نقطة A وهذه نقطة B يعني هذا هكون XA + +79 +00:08:34,850 --> 00:08:44,530 +وها دي إيش XB المعادرة + +80 +00:08:44,530 --> 00:08:49,650 +بتحكي ال moment عند B بتساوي + +81 +00:08:49,650 --> 00:08:56,930 +بين moment عند A زاد المساحة تحت منحنى الشير بين + +82 +00:08:56,930 --> 00:09:04,290 +XA و XBالـ moment عند B سواء الـ moment عند A زاد + +83 +00:09:04,290 --> 00:09:15,270 +المساحة تحت منحنة الـ shear من XA ل XB نفس + +84 +00:09:15,270 --> 00:09:22,010 +الشيء فيه عندنا علاقة اللي هو DV by DX بالسواء الـ + +85 +00:09:22,010 --> 00:09:24,550 +Q الـ Q اللي هو الـ distributed load load لكل + +86 +00:09:24,550 --> 00:09:25,610 +واحدة طول + +87 +00:09:29,210 --> 00:09:40,330 +بسوة Q DX وانا بعمل تكامل بين XA ل XB بين VA ل VB + +88 +00:09:40,330 --> 00:09:50,010 +يعني انا هكون عندي VB minus VA بسوة تكامل Q DX من + +89 +00:09:50,010 --> 00:10:05,040 +XA ل XB يعني VBبالساوية VA زائد تكامل QDX من XA ل + +90 +00:10:05,040 --> 00:10:14,240 +XB يعني ال shear and B ال shear and B بالساوية + +91 +00:10:14,240 --> 00:10:19,900 +shear and A زائد المساحة تحت منحنة ل Q مع ال X بين + +92 +00:10:19,900 --> 00:10:21,940 +XA و XB اللي هي هذه المعادلة + +93 +00:10:31,850 --> 00:10:46,970 +نحل مثال derive the + +94 +00:10:46,970 --> 00:10:51,450 +loading shear force and bending moment diagrams + +95 +00:10:51,450 --> 00:11:01,200 +for the beam shown and beam and رد فعلR1 وR2 هاي + +96 +00:11:01,200 --> 00:11:06,560 +ال X axis هاي ال Y axis فاندي load 200 pound بيأثر + +97 +00:11:06,560 --> 00:11:11,340 +على بعد 4 انش واندي load 100 pound بيأثر على بعد + +98 +00:11:11,340 --> 00:11:16,760 +10 انش و ال beam طوله 20 انش بدنا نحسب ال reaction + +99 +00:11:16,760 --> 00:11:24,480 +forces و ال shear diagram و ال moment diagram اول + +100 +00:11:24,480 --> 00:11:29,420 +خطوة حاولي ادقاشreactions يعني انا اخدت ال moment + +101 +00:11:29,420 --> 00:11:38,500 +حوالين هاي عندى ال X هاي ال Y يعني انا اخدت ال + +102 +00:11:38,500 --> 00:11:43,600 +moment حوالين ال O summation للمoment حوالين ال O + +103 +00:11:43,600 --> 00:11:49,900 +بالساوة 0 و اعتبر عكس عقار السي عاش موجب بالساوة + +104 +00:11:49,900 --> 00:12:02,910 +هكون minus 200 في 4مينوس متين في أربعة مينوس مية + +105 +00:12:02,910 --> 00:12:07,970 +في عشرة زاد + +106 +00:12:07,970 --> 00:12:13,250 +عشرين R اتنين ومنها + +107 +00:12:13,250 --> 00:12:17,790 +R اتنين تطلع + +108 +00:12:17,790 --> 00:12:20,910 +التمنمية + +109 +00:12:22,600 --> 00:12:34,460 +أو الف تونمية على عشرين تسعين تسعين pound بعد + +110 +00:12:34,460 --> 00:12:39,820 +أن باخد summation لل forces باتجاه ال Y الصوت Zero + +111 +00:12:39,820 --> 00:12:44,520 +هكون + +112 +00:12:44,520 --> 00:12:48,840 +دي R واحد ناقص + +113 +00:12:48,840 --> 00:12:50,460 +متين + +114 +00:12:52,380 --> 00:13:03,600 +minus 100 زائد 90 يعني R1 بستوى تلت مية ناقص تسعين + +115 +00:13:03,600 --> 00:13:13,720 +متين و عشرة pound force هيك + +116 +00:13:13,720 --> 00:13:17,800 +أنا عرفت ال reactions هرسم ال shear diagram + +117 +00:13:24,750 --> 00:13:47,050 +و ال moment ده يجرأ حيبدأ + +118 +00:13:47,050 --> 00:13:51,370 +عند R1 يعني عند R1 210 حد من هنا 210 + +119 +00:13:55,650 --> 00:14:07,590 +بعدين هترح ايش؟ متين متين بيضل ايش؟ عشرة هضل + +120 +00:14:07,590 --> 00:14:11,570 +ماشي هترح + +121 +00:14:11,570 --> 00:14:19,770 +مية هي سالب هضل + +122 +00:14:19,770 --> 00:14:26,430 +سالب تسعين وبعدين هطلع كمان تسعينمعناته هو هذا + +123 +00:14:26,430 --> 00:14:30,530 +الشير + +124 +00:14:30,530 --> 00:14:40,410 +ده جرام هذا + +125 +00:14:40,410 --> 00:14:46,030 +الشير ال + +126 +00:14:46,030 --> 00:14:46,670 +bedding moment + +127 +00:14:59,490 --> 00:15:08,250 +الـ moment عند O اشو الساوية عند O سفر هبدأ من سفر + +128 +00:15:08,250 --> 00:15:18,770 +هنحكي هنا اللي هو ال M B بسوء + +129 +00:15:18,770 --> 00:15:28,140 +M A زائد تكامل Vمن XA ل XB هذا الشكل العام لأن + +130 +00:15:28,140 --> 00:15:32,400 +معناته عند النقطة هذه عند النقطة هذه ال moment هي + +131 +00:15:32,400 --> 00:15:36,140 +نحسبها moment هي صفر زاد المساحة هذه يعني هتكون + +132 +00:15:36,140 --> 00:15:41,700 +عشرين متين و عشرة في أربعة تمامية و أربعين هذه + +133 +00:15:41,700 --> 00:15:47,580 +هتتمثل تمثل slope ل ال moment معناته هتكون هذه من + +134 +00:15:47,580 --> 00:15:50,400 +الدرجة الأولى slope constant يعني هتكون متين و + +135 +00:15:50,400 --> 00:15:50,780 +عشرة + +136 +00:15:57,420 --> 00:16:10,380 +تمنين و أربعين مظبوط تمنين و أربعين pound inch ال + +137 +00:16:10,380 --> 00:16:16,260 +moment عند النقطة هذه زاد المساحة هذه المساحة هذه + +138 +00:16:16,260 --> 00:16:21,840 +أكم ستة هذه ستة فعشرة ستة يعني تمنين و أربعين و + +139 +00:16:21,840 --> 00:16:28,450 +ستين تسع مية ال slope هنا شوف كم هو قيمتهأقل اقل + +140 +00:16:28,450 --> 00:16:37,270 +يعني مش هكون اعلى هيكون زي هيك هذا هتكون تسعمية + +141 +00:16:37,270 --> 00:16:44,290 +هنا المساحة ال moment هنا اللي هي تسعمية زي + +142 +00:16:44,290 --> 00:16:48,570 +المساحة هذه المساحة هذه هتكون بالسالف هتكون عندى + +143 +00:16:48,570 --> 00:16:53,070 +هذه عشرة تسعين + +144 +00:16:53,070 --> 00:16:55,930 +في عشرة تسعمية تسعمية نقص تسعمية صفر + +145 +00:17:00,850 --> 00:17:03,130 +فهي كتير مش sign convention انه في ال moment the + +146 +00:17:03,130 --> 00:17:08,430 +ground يكون الموجة لتحت و الساقية للأعلى؟ لأ لأ لأ + +147 +00:17:08,430 --> 00:17:11,490 +انت علي حالة بتعمل convention اللي بدك هي فرضي + +148 +00:17:11,490 --> 00:17:13,910 +يعني بس انت في الآخر نعمل .. احنا عاملين + +149 +00:17:13,910 --> 00:17:17,370 +convention متفق عليه، هيك عالميا أقول أكيد ما + +150 +00:17:17,370 --> 00:17:19,790 +أخدناها كانوا يقولون أنه ال .. sign convention + +151 +00:17:19,790 --> 00:17:22,670 +لتحت الموجة و الساقية لأعلى أنا ماعرفش في أي سياق + +152 +00:17:22,670 --> 00:17:27,510 +ذكرت عشان انا مش ه .. مش هجاوبك اهطب طب مثلا ال + +153 +00:17:27,510 --> 00:17:30,030 +study دي زي ايه؟ تكون ال sheer و ال moment دايما + +154 +00:17:30,030 --> 00:17:33,650 +ساوة و صفرة و داخرة و حنصل على الفرق؟ لأ مش + +155 +00:17:33,650 --> 00:17:37,370 +بالضرورة هتكون ساوة و صفرة، لو عندك cantilever و + +156 +00:17:37,370 --> 00:17:41,010 +عليه مثلا moment عليه في الطرف، فتكون سافرش، في + +157 +00:17:41,010 --> 00:17:46,370 +الحالة، في ال study supported، بيكوناش ساوة و صفرة + +158 +00:17:46,370 --> 00:17:48,430 +و ال sheer برضه زيه؟ + +159 +00:17:54,310 --> 00:17:59,830 +فى الآخر فى الآخر برا حدود ال beam مثلا عندك ال + +160 +00:17:59,830 --> 00:18:06,790 +beam طوله L ال XL بيستوى L plus مافيش هى لا شير + +161 +00:18:06,790 --> 00:18:12,830 +ولا ممد وال X بيستوى Zero minus مافيش هى لا شير + +162 +00:18:12,830 --> 00:18:17,650 +ولا ممد وبالتالى لازم على الأطراف مايكونش عندك + +163 +00:18:17,650 --> 00:18:20,490 +مسفر واضحات؟ + +164 +00:18:23,520 --> 00:18:35,180 +طيب نشوف فيه تكنيك جديد فيه + +165 +00:18:35,180 --> 00:18:44,560 +تكنيك جديد لحساب ال reactions و + +166 +00:18:44,560 --> 00:18:46,800 +حساب ال shear و ال bending moment ال diagrams + +167 +00:18:46,800 --> 00:18:50,820 +هنستخدم + +168 +00:18:50,820 --> 00:18:54,500 +ما يسمى singularity functionsالسيجارات ال + +169 +00:18:54,500 --> 00:18:57,480 +functions تعتمد على ال functions التالة اولش اللي + +170 +00:18:57,480 --> 00:19:00,080 +عندي اللي هو concentrated moment عندي هاي ال X + +171 +00:19:00,080 --> 00:19:12,480 +axis هاي ال X وهذه المسافة A وفي + +172 +00:19:12,480 --> 00:19:18,220 +عندي concentrated moment او + +173 +00:19:18,220 --> 00:19:27,260 +بيسموها unit doubledعندي هدا هتكون X minus A minus + +174 +00:19:27,260 --> 00:19:33,960 +2 هد مش تقص minus 2 X minus A تكتبش minus 2 هد ال + +175 +00:19:33,960 --> 00:19:44,940 +X في الحالة هد X minus A بتساوي by definition Zero + +176 +00:19:44,940 --> 00:19:48,280 +في + +177 +00:19:48,280 --> 00:19:54,120 +كل الأماكناللي بتكونش x بالساوية فيها ايه او + +178 +00:19:54,120 --> 00:19:59,220 +بتساوي plus or minus infinity at x بالساوية ايه + +179 +00:19:59,220 --> 00:20:04,780 +يعني لأن نقطة هذه فقط لها قيمة بتكون لأ بتكون فجأة + +180 +00:20:04,780 --> 00:20:11,600 +بيصير عندى jump في moment سموه unit doublet + +181 +00:20:11,600 --> 00:20:18,110 +infinity مفهوم مفتوحممكن الـ infinity تعتبرها واحد + +182 +00:20:18,110 --> 00:20:21,270 +ممكن تعتبرها مليار ممكن مليون ال infinity قيمة + +183 +00:20:21,270 --> 00:20:26,970 +كبيرة كثير minus infinity قيمة صغيرة كثير فهذه by + +184 +00:20:26,970 --> 00:20:31,390 +definition x minus a بتكون تساوي zero anywhere + +185 +00:20:31,390 --> 00:20:36,250 +except at x بالساوية a بتكون plus or minus + +186 +00:20:36,250 --> 00:20:43,450 +infinity التاني ال function التاني اللي هو x minus + +187 +00:20:43,450 --> 00:20:48,920 +aسالب واحد اللي هو concentrated force او unit + +188 +00:20:48,920 --> 00:20:59,580 +impulse هعندي X هدي A بيصير + +189 +00:20:59,580 --> 00:21:12,080 +فجأة قفزة ال X هين تكامل X minus A بيساوي + +190 +00:21:15,290 --> 00:21:27,670 +x minus a سالب واحد لان x minus a سالب واحد بتساوي + +191 +00:21:27,670 --> 00:21:36,770 +zero عند x not equal a و بتساوي plus infinity عند + +192 +00:21:36,770 --> 00:21:44,980 +x الساوي a و التكاملللـ X minus A سالو واحد DX + +193 +00:21:44,980 --> 00:21:53,760 +بسوا X minus A Zero يعني بتعطينا unit step + +194 +00:21:53,760 --> 00:22:05,980 +function ال unit step function هاندي ال X هي A هدا + +195 +00:22:05,980 --> 00:22:09,880 +X minus A Zero + +196 +00:22:11,740 --> 00:22:21,200 +الـ X minus A Zero اللي هي unit step بتساوي Zero + +197 +00:22:21,200 --> 00:22:31,040 +طالما X أقل من A بتساوي واحد إذا X أكبر أو يساوي A + +198 +00:22:31,040 --> 00:22:41,630 +و التكامل X minus A Zero DX بتساوي X minus Aواحد + +199 +00:22:41,630 --> 00:22:48,590 +بعد + +200 +00:22:48,590 --> 00:22:58,650 +ذلك يأتي الـ RAM طلع يعني RAM طلع عندي + +201 +00:22:58,650 --> 00:23:05,290 +هاي A هذه + +202 +00:23:05,290 --> 00:23:10,250 +X هذه X minus A واحد + +203 +00:23:11,880 --> 00:23:24,940 +ال X minus A واحد بيساوي Zero إذا X أقل من A أو + +204 +00:23:24,940 --> 00:23:32,420 +بتساوي X minus A إذا + +205 +00:23:32,420 --> 00:23:38,860 +X أكبر أوي يساوي A يعني إيش بوصل للدكتور من ال + +206 +00:23:38,860 --> 00:23:42,400 +minus اتنين و من ال minus واحدby definition هذي مش + +207 +00:23:42,400 --> 00:23:48,280 +أس by definition x minus a بتمثل اللي هو moment + +208 +00:23:48,280 --> 00:23:55,560 +مفاجئة مركزة moment مركزة ال x minus a by + +209 +00:23:55,560 --> 00:24:00,600 +definition بتمثل ليه impulse impulse هذي impulse + +210 +00:24:00,600 --> 00:24:09,240 +او اشي مركز هاي impulse مافيش اشي مفروض موزعاكس + +211 +00:24:09,240 --> 00:24:15,040 +ماينوس ايه؟ سويتش اكس ماينوس ايه؟ زيرو؟ سويتش بكون + +212 +00:24:15,040 --> 00:24:19,320 +طالما انا تحت ال a زيرو لما اصلا ال a السويتش + +213 +00:24:19,320 --> 00:24:24,800 +بيشتغل on بيصير الاكس + +214 +00:24:24,800 --> 00:24:31,300 +ماينوس ايه؟ واحد سويتش بس بقلى فيه بقلى فيه ال + +215 +00:24:31,300 --> 00:24:35,000 +load او ال voltage او ال امبير شوية شوية بطلع طلوع + +216 +00:24:40,390 --> 00:24:45,950 +طيب هنستخدم هذه ال mathematical definitions عشان + +217 +00:24:45,950 --> 00:24:51,090 +أحل المسائل + +218 +00:24:51,090 --> 00:24:54,950 +اللي هو ال load و ال shear و ال moment diagram لو + +219 +00:24:54,950 --> 00:24:57,330 +حلل مسألة السابقة رجعنا المسألة السابقة + +220 +00:25:14,820 --> 00:25:18,520 +أحنا في الأساس بشكل عام بيكون عندك Q بيكون عندك Q + +221 +00:25:18,520 --> 00:25:23,040 +بعدين + +222 +00:25:23,040 --> 00:25:30,940 +BGV شير Q يعني load موزع لكل واحدة الطول بعدين BGH + +223 +00:25:30,940 --> 00:25:37,560 +moment ال + +224 +00:25:37,560 --> 00:25:40,420 +ال + +225 +00:25:42,320 --> 00:25:49,120 +هنا حكينا اللي + +226 +00:25:49,120 --> 00:26:06,240 +هي ال V بيستوى DM بي DX و ال Q بيستوى DV بي DX طيب + +227 +00:26:06,240 --> 00:26:12,810 +خلينا نطلع نمثل ال loading بتاعهاالـ loading اللي + +228 +00:26:12,810 --> 00:26:18,250 +هو Q بتساوي + +229 +00:26:18,250 --> 00:26:22,010 +في + +230 +00:26:22,010 --> 00:26:28,570 +عند reaction عند ال O ال X عند O أشو يستوي؟ Zero + +231 +00:26:28,570 --> 00:26:37,090 +هذا يمثل إيه؟ impulse هتكون R واحد في + +232 +00:26:37,090 --> 00:26:44,570 +Xسالب واحد هي x minus a ال a ايش يساوي زي صفر + +233 +00:26:44,570 --> 00:26:53,950 +minus هذا m plus 3 هذا minus 200 minus + +234 +00:26:53,950 --> 00:27:04,350 +200 x minus 4 سالب واحد minus 100 + +235 +00:27:06,930 --> 00:27:17,310 +R2X-10-1R2X + +236 +00:27:17,310 --> 00:27:25,610 +-20-1R2X + +237 +00:27:25,610 --> 00:27:34,550 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X + +238 +00:27:34,550 --> 00:27:34,550 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X + +239 +00:27:34,550 --> 00:27:34,570 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X + +240 +00:27:34,570 --> 00:27:34,570 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X + +241 +00:27:34,570 --> 00:27:36,460 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1الـ V + +242 +00:27:36,460 --> 00:27:46,560 +بيستوع تكامل QDX هتكون R1 X + +243 +00:27:46,560 --> 00:27:50,880 +سفر + +244 +00:27:50,880 --> 00:27:54,220 +ناقص + +245 +00:27:54,220 --> 00:28:08,090 +200 X ناقص 4 سفر ناقص 100X ناقص عشرة سفر زاد R + +246 +00:28:08,090 --> 00:28:17,250 +اتنين X ناقص عشرين سفر عندي برضه ال moment ال DM + +247 +00:28:17,250 --> 00:28:26,870 +بيساوي VDX معناه ان ال moment بيساوي تكامل VDX + +248 +00:28:26,870 --> 00:28:30,750 +هكوندي R واحد + +249 +00:28:34,460 --> 00:28:55,280 +X1-200 X-4 1-100 X-10 1 R2 X-20 1 + +250 +00:29:10,110 --> 00:29:17,250 +لما نفحص هذه الـ R1 X ناقص واحد هذه بتكون هي قيمة + +251 +00:29:17,250 --> 00:29:19,630 +فقط عند X الساوية Zero عند X الساوية Zero بتكون هي + +252 +00:29:19,630 --> 00:29:26,930 +قيمة، صح؟ Jump التانية بتكون فقط لها قيمة عند X، + +253 +00:29:26,930 --> 00:29:32,910 +عند X أربعة التالتة عند X الساوية عشرة الرابعة عند + +254 +00:29:32,910 --> 00:29:34,890 +X الساوية عشرين + +255 +00:29:39,770 --> 00:29:44,270 +يعني لو حطيت X Zero minus يعني أقل من Zero شوية + +256 +00:29:44,270 --> 00:29:51,550 +كلهم يكونوا سواء سفر صح؟ + +257 +00:29:51,550 --> 00:29:58,450 +لو أخدت X عشرين plus كله + +258 +00:29:58,450 --> 00:30:03,850 +سفر ال shear + +259 +00:30:09,300 --> 00:30:17,080 +برضه عند x zero minus هذه + +260 +00:30:17,080 --> 00:30:30,000 +unit step function معناته هذه سامعها واحد وهذا + +261 +00:30:30,000 --> 00:30:34,760 +expression اتنين وهذا expression تلاتة وهذا اربعة + +262 +00:30:45,600 --> 00:30:58,900 +عندي سفر وهي عشرة وهي عشرين وهي أربعة هذا + +263 +00:30:58,900 --> 00:31:05,900 +هيكون بساوية .. هيكون R واحد R واحد بيداخل بس ال + +264 +00:31:05,900 --> 00:31:11,500 +function تبعه بدون ال R واحد هذا هتكون إذا X أقل + +265 +00:31:11,500 --> 00:31:16,440 +من سفرسفر اذا اكون سفر هتكون اياش واحد يعني ال + +266 +00:31:16,440 --> 00:31:20,380 +switch هذا بيشتغل على طول بعد ال X بيشتغل على طول + +267 +00:31:20,380 --> 00:31:26,300 +ال + +268 +00:31:26,300 --> 00:31:32,140 +switch بتاع الأولاني هذا اشتغل من بعد سفر ال + +269 +00:31:32,140 --> 00:31:37,360 +switch بتاع التانية اشتغل بعد الأربع هطلع شوية هك + +270 +00:31:37,360 --> 00:31:46,280 +عشان اميزك اشتغل بعدنعم انا بحكي بس على هذه بحكي + +271 +00:31:46,280 --> 00:31:51,120 +على ال switch انا عارف انا بحكي بس على ال X ناقص + +272 +00:31:51,120 --> 00:32:05,220 +أربعة ك switch ال X ناقص عشرة اشتغلت بعد العشرة ال + +273 +00:32:05,220 --> 00:32:09,380 +X ناقص عشرين بعد العشرين + +274 +00:32:19,160 --> 00:32:26,460 +بالنسبة لهدول همسح هذه انا + +275 +00:32:26,460 --> 00:32:32,080 +ماحكيش على الشير بحكي على ال function هذا اصبر + +276 +00:32:32,080 --> 00:32:36,760 +شوية بحكي على ال function هذا الان بدأ اخد ال + +277 +00:32:36,760 --> 00:32:44,620 +functions هدول هي عندي عشرة عشرين وهي عندي أربعة + +278 +00:32:45,990 --> 00:32:50,050 +هذا بيشتغل بعد الـ zero بسلوك واحد بيظل ماشي على + +279 +00:32:50,050 --> 00:32:57,030 +طول هذا + +280 +00:32:57,030 --> 00:33:06,230 +بيشتغل بعد الأربعة هذا + +281 +00:33:06,230 --> 00:33:14,130 +بيشتغل بعد العشرة هذا + +282 +00:33:14,130 --> 00:33:15,650 +بيشتغل بعد الأشترين + +283 +00:33:21,720 --> 00:33:34,060 +ماشي طيب الان + +284 +00:33:34,060 --> 00:33:54,440 +at V and M هكون R 0 at X equal 0 minus و atx عشرين + +285 +00:33:54,440 --> 00:34:02,020 +plus يعني + +286 +00:34:02,020 --> 00:34:15,040 +العواطف هذه and at x equal عشرين plus هكون + +287 +00:34:15,040 --> 00:34:18,160 +and v بالساوة zero بالساوة + +288 +00:34:21,970 --> 00:34:25,330 +هذه بيشتغل بعد السفر موجود بقناته هتكون R واحد في + +289 +00:34:25,330 --> 00:34:36,070 +واحد صح هتكون ايش؟ R واحد و هذا شغال بعد الأربع + +290 +00:34:36,070 --> 00:34:40,790 +ناقص متين في واحد و + +291 +00:34:40,790 --> 00:34:46,650 +هذا شغال بعد العشرة ناقص مية و هذا شغال بعد عشرين + +292 +00:34:46,650 --> 00:34:56,800 +انا حاكي عشرين plusزاد R2 يعني هكون ال R1 زاد R2 + +293 +00:34:56,800 --> 00:35:06,840 +بسوة 300 هذه المعادلة نجيل ال moment برضه at X + +294 +00:35:06,840 --> 00:35:12,360 +بسوة 20 plus هكون + +295 +00:35:12,360 --> 00:35:16,420 +ال moment بسوة Zero بتساوي + +296 +00:35:27,180 --> 00:35:38,280 +الان هضرب في X R1 R1 + +297 +00:35:38,280 --> 00:35:52,440 +في عشرين مظبوط ناقص متين خلينا نشوف كيف اجت هذه ال + +298 +00:35:52,440 --> 00:36:02,860 +X جاء زي هيكهيك جاي وهي ال X عشرين صح لأنها هتكون + +299 +00:36:02,860 --> 00:36:13,360 +عشرين فقر واحد لأن مسلوب يساوي واحد ناقص متين في + +300 +00:36:13,360 --> 00:36:25,980 +عشرين ناقص أربعة ناقص مية في عشرين ناقص عشرةزائد R + +301 +00:36:25,980 --> 00:36:33,140 +اتنين في عشرين ناقص عشرين يعني + +302 +00:36:33,140 --> 00:36:41,740 +انا هكون عندي اربعة عشرين R واحد ناقص عشرين ناقص + +303 +00:36:41,740 --> 00:36:53,560 +اربعة ستاشر في متين ناقص تلت تلاف و متين ناقص الف + +304 +00:36:56,460 --> 00:37:03,300 +زائد صفر يعني R واحد هيكون + +305 +00:37:03,300 --> 00:37:12,420 +ساوي تلت تلاف واربع تلاف ومتين على عشرين متين + +306 +00:37:12,420 --> 00:37:20,180 +وعشرة تطلع متين وعشرة pound عوض في هذه حسين انك + +307 +00:37:20,180 --> 00:37:26,900 +متين وعشرة زاد R اتنينبالساوية تلت مية معناته R + +308 +00:37:26,900 --> 00:37:36,100 +اتنين بالساوية تسعين pound force هيك اوجدنا ال + +309 +00:37:36,100 --> 00:37:42,760 +reactions صارت + +310 +00:37:42,760 --> 00:37:48,060 +معروف R واحد متين و عشرة لان عندما ندرسهم + +311 +00:38:04,100 --> 00:38:15,200 +هي ال shear diagram ال + +312 +00:38:15,200 --> 00:38:23,880 +V من صفر لاربعة بيكون + +313 +00:38:23,880 --> 00:38:33,650 +شغال بس ال R واحد كله طافلهذا كله بيكون طافى هتكون + +314 +00:38:33,650 --> 00:38:45,610 +R واحد ايه اكم 210 لما + +315 +00:38:45,610 --> 00:38:52,670 +بين اربعة و عشرة بيضلوا شغال ال R واحد مظبوط و + +316 +00:38:52,670 --> 00:38:59,490 +بيشتغل ال 200 بس بالسالمهكون متين و عشرة ناقص متين + +317 +00:38:59,490 --> 00:39:06,310 +هي عشرة بين + +318 +00:39:06,310 --> 00:39:14,910 +العشرة والعشرين يكون هذا شغال و هذا شغال و هذا + +319 +00:39:14,910 --> 00:39:19,510 +شغال هطلع حمية بيصير ناقص تسعين + +320 +00:39:28,510 --> 00:39:35,330 +لحد نصل ال 20 او نصل ال 20 بشتغل اللي هو ال R2 + +321 +00:39:35,330 --> 00:39:42,130 +بسفر ليه بالنسبة + +322 +00:39:42,130 --> 00:39:42,610 +ل ال moment + +323 +00:40:07,790 --> 00:40:18,130 +ال moment هتكون تساوي هاخد + +324 +00:40:18,130 --> 00:40:25,830 +x من 0 ل 4 هتكون + +325 +00:40:25,830 --> 00:40:26,930 +R1 في x + +326 +00:40:38,050 --> 00:40:42,430 +اللي هى R واحد اكمل دى اتين + +327 +00:40:42,430 --> 00:40:47,670 +و عشرة يعنى هتكون اتين + +328 +00:40:47,670 --> 00:40:51,990 +و عشرة X من + +329 +00:40:51,990 --> 00:41:00,510 +X بين الأربعة و العشرة بيشتغل + +330 +00:41:00,510 --> 00:41:11,550 +هده و هده صح بيصير عندك R واحد في Xناقص متين في X + +331 +00:41:11,550 --> 00:41:19,590 +ناقص أربعة بين + +332 +00:41:19,590 --> 00:41:32,570 +ال X عشرة و عشرين بيكون هذا شغال R واحد X ناقص + +333 +00:41:32,570 --> 00:41:34,810 +متين + +334 +00:41:36,400 --> 00:41:48,520 +فى x ناقص أربعة ناقص مية فى x ناقص عشرة وهذا لسه + +335 +00:41:48,520 --> 00:41:59,060 +ماشتغلش زائد زيرو صح بيشتغل بعد العشرين لأ نجربه + +336 +00:41:59,060 --> 00:42:08,580 +نجربه احنا حكينا لو x بالساوياربع هتكون ال moment + +337 +00:42:08,580 --> 00:42:14,380 +اكم تمامية و اربعين و اللي لأ هو واضح انه خطيه + +338 +00:42:14,380 --> 00:42:23,800 +لدرجته العامة تمامية و اربعين جربوا + +339 +00:42:23,800 --> 00:42:32,440 +X عشرة هنا هاي تمامية و اربعين ناقص اتين في عشرة + +340 +00:42:34,860 --> 00:42:44,720 +نقص اربعة ستين يعني تمانية و اربعين اه + +341 +00:42:44,720 --> 00:42:52,040 +متين و عشرة يصلي متين و عشرة في عشرة الفين و مية + +342 +00:42:52,040 --> 00:43:00,020 +يعني الفين و مية ناقص متين في ستة ناقص الف و متين + +343 +00:43:00,020 --> 00:43:00,620 +تسعة مية + +344 +00:43:10,060 --> 00:43:20,680 +حطوا هنا x بالساوية عشرين هكون متين و عشرة في + +345 +00:43:20,680 --> 00:43:31,780 +تسعين متين و عشرة في عشرين ناقص متين في ستة عشر + +346 +00:43:31,780 --> 00:43:37,500 +ناقص مية في عشرة اكم تطلع؟ + +347 +00:43:43,340 --> 00:43:48,660 +سيبوها اكيد هتطلع سفر بس تأكدوا سيبوها تطلع سفر + +348 +00:43:48,660 --> 00:43:56,240 +معاكم فانا جبت المعادلات مش رسمته بس باستخدام اللي + +349 +00:43:56,240 --> 00:44:03,860 +هو ال singularity functions طيب + +350 +00:44:03,860 --> 00:44:08,600 +الحل سؤال يعني في تفصيل اكتر + +351 +00:44:20,380 --> 00:44:23,740 +طيب شوف السؤال هذا + +352 +00:44:55,120 --> 00:45:02,600 +طيب عندي beam اللي + +353 +00:45:02,600 --> 00:45:13,140 +هو cantilever يعني fixed عن طرف هذا ال + +354 +00:45:13,140 --> 00:45:18,760 +beam طوله عشرة انش فاندي load موزع قيمته اشرين + +355 +00:45:18,760 --> 00:45:22,740 +pound four per inchبشتغل من بين التلاتة انش + +356 +00:45:22,740 --> 00:45:28,220 +والسبعة انش وفي عندي moment مركزة في نهاية ال beam + +357 +00:45:28,220 --> 00:45:33,320 +اللي هي قيمته اتين و اربعين pound force انش هذا ال + +358 +00:45:33,320 --> 00:45:42,940 +X axis طبعا هذا ال Y axis هذا ال EQ طبعا + +359 +00:45:42,940 --> 00:45:54,020 +هكون عندي هنا M1 عند رد فعل هنار واحد بدا نوجد ال + +360 +00:45:54,020 --> 00:45:58,500 +reactions ونرسم الشير ومدغرام باستخدام ال + +361 +00:45:58,500 --> 00:46:01,840 +singularity functions اول شئ I have to define ال Q + +362 +00:46:01,840 --> 00:46:06,720 +ال Q هكون + +363 +00:46:06,720 --> 00:46:13,560 +الساوية عند X بالساوية Zero عندي concentrated + +364 +00:46:13,560 --> 00:46:18,820 +moment نرجع على الشكل ال by convention هنا + +365 +00:46:21,000 --> 00:46:26,040 +Clockwise موجب Clockwise + +366 +00:46:26,040 --> 00:46:38,880 +هنا معرفه موجب نعم هيكون هذا سالب M واحد X X minus + +367 +00:46:38,880 --> 00:46:48,420 +Zero صح هتكون X سالب اتنين for a moment زائد R + +368 +00:46:48,420 --> 00:46:58,690 +واحدفى x هذه impulse سالب واحد الآن + +369 +00:46:58,690 --> 00:47:08,130 +عندي هنا fixed هكون step function zero لأن خليني + +370 +00:47:08,130 --> 00:47:14,710 +أحكي ل step function ناخد حالة عندي هاي a هذه + +371 +00:47:14,710 --> 00:47:27,690 +x minus aزيرو وهي حالة تانية هذه ايه بي هذه + +372 +00:47:27,690 --> 00:47:36,750 +اكس minus بي زيرو لو طرحت هذا من هذا ايش بيعطيناه + +373 +00:47:36,750 --> 00:47:44,390 +طبعا هذا كل واحد وهنا كل واحد هيسفر هيسير عندي من + +374 +00:47:44,390 --> 00:47:54,050 +هنا لهناهي من A ل B هدا هيكون ال function X minus + +375 +00:47:54,050 --> 00:48:06,490 +A Zero minus X minus B Zero واضحة هدا عندي unit + +376 +00:48:06,490 --> 00:48:10,050 +step function يعني before X سواء A بيكون سواء 0 + +377 +00:48:10,050 --> 00:48:14,710 +سفر بعد الواحد بعد ال A بيكون سواء واحد عندي كمان + +378 +00:48:14,710 --> 00:48:19,060 +another step functionبشتغل عند x يستوى بي يعني بعد + +379 +00:48:19,060 --> 00:48:23,540 +ال x يستوى بي بيصير واحد before بي سفر لو طلعت هذا + +380 +00:48:23,540 --> 00:48:29,780 +من هذا هكون واحد في المنطقة هذه واحد ناقص سفر واحد + +381 +00:48:29,780 --> 00:48:35,060 +في المنطقة هذه واحد ناقص واحد سفر يعني هيسفر بعد + +382 +00:48:35,060 --> 00:48:39,020 +ال بي يعني هكون ال functional شغل on هكون بين ال a + +383 +00:48:48,020 --> 00:48:55,480 +بزايد او ناقص عشرين في + +384 +00:49:09,110 --> 00:49:22,730 +نقص عشرين في X minus تلاتة Zero minus X ناقص سبعة + +385 +00:49:22,730 --> 00:49:26,770 +Zero + +386 +00:49:26,770 --> 00:49:30,730 +عن + +387 +00:49:30,730 --> 00:49:35,030 +الطرف عند ال moment برضه counter clockwise minus + +388 +00:49:35,030 --> 00:49:35,870 +متين و أربعين + +389 +00:49:40,510 --> 00:49:53,550 +فى x minus عشرة سالب اتنين ال + +390 +00:49:53,550 --> 00:49:57,130 +V هي + +391 +00:49:57,130 --> 00:50:09,770 +تكامل ل Q DX مظبوط هكون minus M واحد X سالب واحد + +392 +00:50:10,720 --> 00:50:19,000 +زاد R واحد في X سفر + +393 +00:50:19,000 --> 00:50:26,120 +minus عشرين في + +394 +00:50:26,120 --> 00:50:36,060 +X minus تلاتة واحد زاد + +395 +00:50:36,060 --> 00:50:37,920 +عشرين + +396 +00:50:39,220 --> 00:50:54,260 +فى x minus 7 و 1 ناقص 240 فى x ناقص 10 سالب 1 هذه + +397 +00:50:54,260 --> 00:50:59,480 +ال V ال M سوى + +398 +00:50:59,480 --> 00:51:03,800 +تكامل VDX بتساوي + +399 +00:51:11,220 --> 00:51:18,320 +-M1 X0 R1 + +400 +00:51:18,320 --> 00:51:22,260 +X1 + +401 +00:51:22,260 --> 00:51:31,800 +-20 X-3 2 + +402 +00:51:37,760 --> 00:51:43,720 +زائد عشرين اكس + +403 +00:51:43,720 --> 00:51:48,460 +ناقص سبعة اتنين + +404 +00:51:48,460 --> 00:51:51,800 +ماينوس + +405 +00:51:51,800 --> 00:52:00,680 +متين و اربعين اظن ان نرجع نص التكامل نص هذا على + +406 +00:52:00,680 --> 00:52:05,420 +اتنين هذا على + +407 +00:52:05,420 --> 00:52:05,920 +اتنين + +408 +00:52:08,980 --> 00:52:25,720 +هذه على اتنين ناقص متين واربعين X ناقص عشرة سفر لأ + +409 +00:52:25,720 --> 00:52:34,440 +لأ انت by definition هات by definition انا هنا صار + +410 +00:52:34,440 --> 00:52:38,100 +عندى ارتفعت الدرجة هناك مارتفعتش الدرجة + +411 +00:52:40,770 --> 00:52:57,390 +بالظبط بالظبط مش power صحيح طيب الان عند + +412 +00:52:57,390 --> 00:53:03,690 +x at x بالساوية at x بالساوية zero minus + +413 +00:53:10,660 --> 00:53:16,720 +ولا واحد فيهم بيشتغل طلعوا هذا مش شغال هذا مش شغال + +414 +00:53:16,720 --> 00:53:22,560 +مش شغال ولا واحد فيهم بيشتغل + +415 +00:53:22,560 --> 00:53:37,900 +و add x ساوية عشرة plus كون + +416 +00:53:37,900 --> 00:53:50,290 +هذا شغالهذا شغال، هذا شغال، كله شغالين، صح؟ + +417 +00:53:50,290 --> 00:54:02,830 +طيب معناته نحكي at x بالثاوية عشرة plus ال V + +418 +00:54:02,830 --> 00:54:07,050 +بالثاوية، سفر ششير بالثاوية + +419 +00:54:14,240 --> 00:54:27,360 +هذا هتكون minus ال + +420 +00:54:27,360 --> 00:54:35,140 +moment هذه بتكون لها قيمة عند x بستوى سفر any x + +421 +00:54:35,140 --> 00:54:41,180 +any other x هتكون سفر صح؟ هذا المقال هتكون سفر + +422 +00:54:45,970 --> 00:54:50,450 +وهذا step function او unit step function هتكون + +423 +00:54:50,450 --> 00:54:54,110 +زائد R واحد يعني يعني يعني يعني بعد السفر بيصير له + +424 +00:54:54,110 --> 00:55:03,710 +قيمة صح؟ زائد R واحد و هذا بعد التلاتة هذا بعد + +425 +00:55:03,710 --> 00:55:08,110 +التلاتة بيكون ايش زي هيك هاي X بالثاوض تلاتة هذا X + +426 +00:55:08,110 --> 00:55:16,000 +بالثاوض تلاتة يعني هتكون minus عشرين في عشرةناقص + +427 +00:55:16,000 --> 00:55:29,460 +تلاتة زائد عشرين في عشرة ناقص سبعة هذا + +428 +00:55:29,460 --> 00:55:35,320 +ال X عشرة plus مافيه قيمة فقط عند X يساوي عشرة + +429 +00:55:35,320 --> 00:55:44,380 +بالظبط يعني ناقص Zero يعني هتكون عند R واحد هتساوي + +430 +00:55:48,890 --> 00:55:53,450 +عشريف سبعة مية + +431 +00:55:53,450 --> 00:56:00,950 +و أربعين ناقص عشريف + +432 +00:56:00,950 --> 00:56:10,870 +تلاتة ستين مظبوط + +433 +00:56:10,870 --> 00:56:18,370 +صحيح + +434 +00:56:22,040 --> 00:56:26,960 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +435 +00:56:26,960 --> 00:56:28,700 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +436 +00:56:28,700 --> 00:56:28,740 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +437 +00:56:28,740 --> 00:56:28,780 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +438 +00:56:28,780 --> 00:56:28,880 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +439 +00:56:28,880 --> 00:56:30,340 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +440 +00:56:30,340 --> 00:56:47,300 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +441 +00:56:51,080 --> 00:56:54,420 +واضح؟ هذا step function بتكون قيمته قبل ال X في + +442 +00:56:54,420 --> 00:56:58,960 +السواء Zero و بعد X بيبقى أكبر ال X في السواء Zero + +443 +00:56:58,960 --> 00:57:04,060 +بيكون قيمته واحد واحد في R واحد R واحد صحيح طب + +444 +00:57:04,060 --> 00:57:09,020 +دكتور احنا قلنا انها لعشرة plus هل انه مش هي اخر + +445 +00:57:09,020 --> 00:57:14,140 +ايش هنكون محددين من الزفر للعشرة؟ صحيح يعني هي + +446 +00:57:14,140 --> 00:57:18,420 +منطقة غير قيمة ال step ماشي انت اتلقيت مرة ال بين + +447 +00:57:19,240 --> 00:57:24,540 +عشان هيك .. ما هي .. ما هي الفكرة ان انت ايك عشرة + +448 +00:57:24,540 --> 00:57:29,000 +plus عشرة plus تعتبر point او او او او او او او او + +449 +00:57:29,000 --> 00:57:29,920 +او او او او او او او او او او او او او او او او او + +450 +00:57:29,920 --> 00:57:30,080 +او او او او او او او او او او او او او او او او او + +451 +00:57:30,080 --> 00:57:30,080 +او او او او او او او او او او او او او او او او او + +452 +00:57:30,080 --> 00:57:30,420 +او او او او او او او او او او او او او او او او او + +453 +00:57:30,420 --> 00:57:30,500 +او او او او او او او او او او او او او او او او او + +454 +00:57:30,500 --> 00:57:38,380 +او او + +455 +00:57:38,380 --> 00:57:48,200 +او + +456 +00:57:48,500 --> 00:57:52,340 +في step function step function هذا بيشتغل بيصير on + +457 +00:57:52,340 --> 00:57:57,940 +بعد ال X بالساوية Zero مفتوح على طول شغال على مال + +458 +00:57:57,940 --> 00:58:06,120 +النهاية هذا شغال من عند X الساوية هذا RAM شغال من + +459 +00:58:06,120 --> 00:58:11,620 +عند X الساوية تلاتة وطلع يعني هاي X الساوية تلاتة + +460 +00:58:11,620 --> 00:58:17,860 +شغال على طول هذا شغال بعد X + +461 +00:58:22,190 --> 00:58:26,890 +سبعة هذا concentrated بيشتغل فقط عند x الساعة و + +462 +00:58:26,890 --> 00:58:43,090 +عشرة عند عشرة plus أو عشرة minus بيشتغلش الآن + +463 +00:58:43,090 --> 00:58:45,910 +هنشوفها واحدة واحدة اول خطوة هنجيه ال reactions + +464 +00:58:45,910 --> 00:58:47,770 +هنعوض x الساعة و عشرة + +465 +00:58:50,750 --> 00:58:56,490 +حسبنا ال R واحد ناخد معاملة ال moment برضه at X + +466 +00:58:56,490 --> 00:59:03,110 +بالساوية عشرة plus مافيش P أساسا ال moment شوفوا + +467 +00:59:03,110 --> 00:59:09,970 +الساوية بتساوية + +468 +00:59:09,970 --> 00:59:17,930 +هيا هذا step function بيشتغل بعد السفر معناته M + +469 +00:59:17,930 --> 00:59:18,710 +واحد موجودة + +470 +00:59:22,600 --> 00:59:30,720 +-M1 وهذا طلع شغالة بعد الـ X الساعة و سفر والـ X + +471 +00:59:30,720 --> 00:59:39,680 +قيمتها هكون زائد R1 في عشرة ناقص + +472 +00:59:39,680 --> 00:59:46,260 +هشيعتني ان ناقص عشرة في X + +473 +00:59:53,340 --> 01:00:00,280 +عشرة ناقص تلاتة لكل تربيع + +474 +01:00:00,280 --> 01:00:09,920 +زائد + +475 +01:00:09,920 --> 01:00:13,260 +عشرة + +476 +01:00:16,290 --> 01:00:23,030 +عشرة ناقص سبعة في عشرة ناقص سبعة تربية ناقص سبعة + +477 +01:00:23,030 --> 01:00:26,450 +ما الاتنين عليها نقص نعم ليش سبعة ما الاتنين عليها + +478 +01:00:26,450 --> 01:00:36,550 +نقص اه لو أخدنا الحلقة البسيطة الرقم + +479 +01:00:36,550 --> 01:00:43,890 +عنده هي الرقم اكس السبعة هي رايحة بالشكل هذا لبعض + +480 +01:00:43,890 --> 01:00:44,370 +النهاية + +481 +01:00:46,910 --> 01:00:53,610 +اجمعها ايش هتعطيلي؟ هتعطيلي هذه معادلة Y Y + +482 +01:00:53,610 --> 01:01:01,070 +بالساوية X كإنها التكمل تعالى ايش بالساوية؟ X + +483 +01:01:01,070 --> 01:01:10,150 +تربيع ع اتنين يعني هتكون ايه؟ برابولة رايح لما + +484 +01:01:10,150 --> 01:01:16,450 +لنهاية برابولة رايح لما لنهايةإذا كانت X بيستوي A + +485 +01:01:16,450 --> 01:01:24,850 +أساسا هي ال RAM بتاعتها اللي + +486 +01:01:24,850 --> 01:01:30,470 +صار أنه عندك بدأ الجزء الموجب من ال parabola بعد + +487 +01:01:30,470 --> 01:01:38,130 +ال X بيستوي A يعني هي هذي X بيستوي A واضحة + +488 +01:01:38,130 --> 01:01:45,610 +ليش النصأنا عملت shift سواء كان في ال calculus كان + +489 +01:01:45,610 --> 01:01:48,830 +ممكن اعمل shift باتجاه ال x axis او باتجاه ال y + +490 +01:01:48,830 --> 01:01:53,410 +axis انا عملتله هنا shift زحت ال parabola باتجاه + +491 +01:01:53,410 --> 01:01:58,510 +ال x axis لما حكيت x لما حكيت x ناقص تلاتة الكل + +492 +01:01:58,510 --> 01:02:03,650 +تربيع كأنه parabola مزاح سبع وحدها تجاه ال x axis + +493 +01:02:03,650 --> 01:02:08,310 +نفس ال parabola اللي عند x يستوى zero بس انا بزيحه + +494 +01:02:17,410 --> 01:02:24,470 +طيب وين وصلنا زاد عشرة ناقص متين واربعين ناقص متين + +495 +01:02:24,470 --> 01:02:33,010 +واربعين في صفر ناقص متين واربعين في اياش في صفر + +496 +01:02:33,010 --> 01:02:40,970 +يعني هيكون عنده متين + +497 +01:02:40,970 --> 01:02:45,830 +واربعين هتحط X الساوي لأ صحيح كلام ناقص متين + +498 +01:02:45,830 --> 01:02:50,780 +واربعينفى واحد ليش + +499 +01:02:50,780 --> 01:02:54,520 +لأن هذا unit step function بيشتغل مباشرة بعد ال X + +500 +01:02:54,520 --> 01:02:58,960 +الساوية ايش عشرة فهذا هتكون قيمته واحد ناقص تانية + +501 +01:02:58,960 --> 01:03:06,760 +واربعين فى واحد يعني هيكون عندى ناقص M واحد ال R + +502 +01:03:06,760 --> 01:03:14,020 +واحد أكتر حسبناها تمانين زائد تمانية ناقص + +503 +01:03:15,420 --> 01:03:20,380 +هنا سبعة تربية تسعة وأربعين في عشرة أربعين وتسعين + +504 +01:03:20,380 --> 01:03:30,660 +لاحظ + +505 +01:03:30,660 --> 01:03:39,640 +شوية ناقص أربعين وتسعين زاد عشرة عشرة عشرة + +506 +01:03:39,640 --> 01:03:52,580 +في تسعةتسعين لأ من الصفر عشرة في تسعة تسعين ناقص + +507 +01:03:52,580 --> 01:03:58,100 +متين واربعين بالساوي + +508 +01:03:58,100 --> 01:04:04,920 +ايش سفر ومنها بحسب ال M واحدهجيبها جهة تانية هتكون + +509 +01:04:04,920 --> 01:04:09,120 +تمامية نقص واحد وتسعين زي التسعين نقص اتنين + +510 +01:04:09,120 --> 01:04:17,620 +واربعين اكم تطلع مية وستين pound inch pound force + +511 +01:04:17,620 --> 01:04:23,180 +inch هيك حسبت ال reactions و ال moments اللي + +512 +01:04:23,180 --> 01:04:27,060 +هنخليه نعمل ال share و ال moment diagram + +513 +01:04:35,730 --> 01:04:43,670 +بحكي ال share ال V هيكون يساوي ال + +514 +01:04:43,670 --> 01:04:50,670 +share ال M1 حسبناها كم طلعت؟ مية و ستين مية و ستين + +515 +01:04:50,670 --> 01:04:58,070 +هحكيها عشان M1 بيساوي مية و ستين pound انش وال R1 + +516 +01:04:58,070 --> 01:05:02,990 +ده كم؟ ربما تبقى تمانين تمانين pound + +517 +01:05:14,580 --> 01:05:22,100 +الـ V هتكون + +518 +01:05:22,100 --> 01:05:33,000 +تساوي هد مش هتشتغل غير عند Zero صح هد هتشتغل زاد R + +519 +01:05:33,000 --> 01:05:42,520 +واحد مابعد يعني هناخد فترات بين سفر و تلاتةو تلاتة + +520 +01:05:42,520 --> 01:05:48,640 +و سبعة و سبعة و عشرة هاخد بين سفر و تلاتة X بين + +521 +01:05:48,640 --> 01:05:57,500 +سفر و تلاتة هتكون + +522 +01:05:57,500 --> 01:06:03,040 +هذا + +523 +01:06:03,040 --> 01:06:10,080 +هتكون ايه اش R واحد لان + +524 +01:06:10,080 --> 01:06:18,700 +هذا step functionناقص عشرين في + +525 +01:06:18,700 --> 01:06:34,580 +X ناقص تلاتة زائد عشرين في X ناقص سبعة وهذا + +526 +01:06:34,580 --> 01:06:40,360 +يكون الشغال صح؟ يعني + +527 +01:06:41,960 --> 01:06:45,920 +الان راح عندي تمانين لو حطينا X بالثانوية تلاتة + +528 +01:06:45,920 --> 01:06:46,900 +خلّين نرسم + +529 +01:07:28,550 --> 01:07:33,290 +انت أكد كده مرة عندي ال V من سفر من X من X من سفر + +530 +01:07:33,290 --> 01:07:39,870 +لتلاتة من سفر لتلاتة هذا بيكون الشغال هذا بيشتغل + +531 +01:07:39,870 --> 01:07:51,610 +هذا هذا مش شغال صح هذا لسه ماشتغلتش اه لو حطينا ال + +532 +01:07:51,610 --> 01:07:56,430 +X بالساوية تلاتة او لو حطيت ال X بالساوية + +533 +01:07:59,690 --> 01:08:04,410 +لحظة لحظة، الآن هذه برضه بتكون الشغالة، هذه بتكون + +534 +01:08:04,410 --> 01:08:14,410 +الشغالة، صح؟ هتكون R واحد، ال R واحد عندي أكم؟ + +535 +01:08:14,410 --> 01:08:15,810 +تمانين + +536 +01:08:31,150 --> 01:08:40,230 +طيب X بين التلاتة والسبعة بيكون + +537 +01:08:40,230 --> 01:08:46,930 +شغال ال R واحد واشتغل + +538 +01:08:46,930 --> 01:08:54,250 +X ناقص تلاتة minus عشرين في X ناقص تلاتة هذا لسه + +539 +01:08:54,250 --> 01:08:56,990 +ماشتغلش ولا هذا اشتغل صح؟ + +540 +01:08:59,490 --> 01:09:11,210 +لو حطينا x بالساوية سبعة سبعة + +541 +01:09:11,210 --> 01:09:11,210 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +542 +01:09:11,210 --> 01:09:11,210 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +543 +01:09:11,210 --> 01:09:11,370 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +544 +01:09:11,370 --> 01:09:13,550 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +545 +01:09:13,550 --> 01:09:14,030 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +546 +01:09:14,030 --> 01:09:14,030 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +547 +01:09:14,030 --> 01:09:23,110 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +548 +01:09:23,110 --> 01:09:26,170 +سبعة سب + +549 +01:09:27,160 --> 01:09:33,240 +لأ بتبدأ تشغّل يعني هذه ال function هذا مع بعض هذا + +550 +01:09:33,240 --> 01:09:40,280 +شغال هاي أول واحد هذا شغال وهذا شغال لكن هدول لسه + +551 +01:09:40,280 --> 01:09:45,700 +ماشتغلوش مش ماشتغل انه ببدأ عند السبعة بالظبط صفر + +552 +01:09:45,700 --> 01:09:48,720 +يعني قيمته عند السبعة بالظبط معناه مش مفيد احطه + +553 +01:09:48,720 --> 01:09:53,500 +فالشغال فعليا هو بيعطي قيمة ر واحد وعشرين في X + +554 +01:09:53,500 --> 01:09:57,130 +ناقص تلاتةيعني هتكون عند ار واحد لو حكيت ار واحد + +555 +01:09:57,130 --> 01:10:05,070 +عنده تمانين ناقص عشرين في سبعة ناقص تلاتة هتكون + +556 +01:10:05,070 --> 01:10:13,130 +تمانين ناقص تمانين صفر و هي اتطلعوا عشرين في أربعة + +557 +01:10:13,130 --> 01:10:18,710 +ناقص تمانين يعني هتكون ساوى صفر + +558 +01:10:29,050 --> 01:10:33,270 +ما حكيتلك عندي السبعة هذا ببدأ يشتغل بس كيبته سفر + +559 +01:10:33,270 --> 01:10:36,530 +بين + +560 +01:10:36,530 --> 01:10:46,110 +السبعة X بين السبعة والعشرة بيكون عندك R واحد ناقص + +561 +01:10:46,110 --> 01:10:52,670 +عشرين في X ناقص تلاتة زائد عشرين في X ناقص سبعة + +562 +01:11:05,770 --> 01:11:13,110 +أقل مش أقل لو يساوي طيب + +563 +01:11:13,110 --> 01:11:25,200 +لو حطيت X عشرة هكون عندى تمانين ناقص عشرينفي سبعة + +564 +01:11:25,200 --> 01:11:31,440 +زائد عشرين في + +565 +01:11:31,440 --> 01:11:39,860 +إيش؟ في صفر غلطان صح زيك؟ لأ عشرة بدي أحط عشرة + +566 +01:11:39,860 --> 01:11:49,630 +الآن التمانين ناقص عشرين في سبعة زائد عشرينفي + +567 +01:11:49,630 --> 01:11:57,890 +تلاتة يعني هكون تمانين ناقص مية و أربعين زائد ستين + +568 +01:11:57,890 --> 01:12:04,670 +ايش هسير فيه؟ صفر مستيرياش؟ + +569 +01:12:04,670 --> 01:12:17,070 +صفر معناته هكون ماشي زي هيك صح؟ + +570 +01:12:17,070 --> 01:12:19,050 +اه + +571 +01:12:20,480 --> 01:12:28,680 +عند السفر بالظبط عشان اكون دقيق ياد لازم تخلي + +572 +01:12:28,680 --> 01:12:38,920 +السفر لحاله خاطره اكبر اكبر عند السفر plus طيب + +573 +01:12:38,920 --> 01:12:45,960 +هذا بالنسبة لإياش لل share عند السفر لإياش + +574 +01:12:49,980 --> 01:12:56,440 +المشكلة بتقفز فجأة يعني انك عندك zero plus zero + +575 +01:12:56,440 --> 01:13:05,120 +plus فتقفز فجأة فبعتبرها كأنها سفر واضحة؟ + +576 +01:13:05,120 --> 01:13:12,940 +طيب الآن ال moment هناخد + +577 +01:13:12,940 --> 01:13:16,800 +بين X صفر و تلاتة + +578 +01:13:19,630 --> 01:13:24,390 +هي ال moment هذي + +579 +01:13:24,390 --> 01:13:29,870 +هتكون شغلة صح بعد أكبر من السفن سنة تلت هتكون شغلة + +580 +01:13:29,870 --> 01:13:36,310 +minus M واحد زائد + +581 +01:13:36,310 --> 01:13:46,810 +R واحد في X هذي لسه ماشتغلتش و هذي ماشتغلتش و هذي + +582 +01:13:46,810 --> 01:13:54,230 +ماشتغلتشيعني هتكون ال M واحد احنا حسبناها كم مية و + +583 +01:13:54,230 --> 01:14:02,030 +ستين يعني هتكون نقص مية و ستين زاد + +584 +01:14:02,030 --> 01:14:10,530 +تمانين في X تمانين + +585 +01:14:10,530 --> 01:14:11,250 +في تلاتين + +586 +01:14:18,240 --> 01:14:25,920 +حط x بالساوية صفر هتكون ناقص مية و ستين لأن في + +587 +01:14:25,920 --> 01:14:32,520 +عندي concentrated moment ناقص مية + +588 +01:14:32,520 --> 01:14:38,980 +و ستين حط x بالساوية تلاتة تمانين في تلاتة متين و + +589 +01:14:38,980 --> 01:14:43,880 +أربعين ناقص مية و ستين تمانين هذي constant فعلا + +590 +01:14:43,880 --> 01:14:47,860 +هذي هتكون عشر linear يعني هتكون عندهين + +591 +01:14:56,730 --> 01:15:06,710 +بين اكس بين تلاتة و سبعة هيكون ناقص مائة و ستين + +592 +01:15:06,710 --> 01:15:14,190 +زائد تمانين اكس هضيف ايه هاد + +593 +01:15:14,190 --> 01:15:17,930 +شغال هاد شغال وهاد اشتغلت ناقص عشرة + +594 +01:15:23,160 --> 01:15:30,500 +في x ناقص ثلاثة تربيع هذه لسه ما اشتغلت و لا هاد + +595 +01:15:30,500 --> 01:15:34,020 +اشتغلت + +596 +01:15:34,020 --> 01:15:45,140 +حط x بالساوية سبعة هكون دي ناقص مية و ستين زائد + +597 +01:15:45,140 --> 01:15:49,960 +خمس مية و ستين هين + +598 +01:15:49,960 --> 01:15:57,680 +اربع في اربع ستاشفعشرة ناقص مية و ستين أكمل طلع + +599 +01:15:57,680 --> 01:16:01,320 +خمسمية و ستين ناقص مية و ستين أربعمية ناقص مية + +600 +01:16:01,320 --> 01:16:05,940 +تلاتمية متين و أربعين صح؟ + +601 +01:16:05,940 --> 01:16:11,080 +متين و أربعين طبعا هذا إيش لاحظوا الدرجة بتاعتها + +602 +01:16:11,080 --> 01:16:13,120 +فرابولا + +603 +01:16:33,840 --> 01:16:44,060 +بين X سبعة وأقل من عشرة هكون ناقص مية ستين زائد + +604 +01:16:44,060 --> 01:16:49,000 +تمانين X ناقص عشرة في X ناقص تلاتة + +605 +01:16:54,160 --> 01:17:04,040 +في x ناقص ثلاثة هذا شغال شغال شغال زائد عشرة ناقص + +606 +01:17:04,040 --> 01:17:08,200 +ستين زائد + +607 +01:17:08,200 --> 01:17:12,140 +عشرة في + +608 +01:17:12,140 --> 01:17:15,780 +x ناقص + +609 +01:17:15,780 --> 01:17:18,980 +سبعة لكل تربيع + +610 +01:17:30,310 --> 01:17:38,350 +هذه مش هتكون شغالة عند X و الساعة عشرة minus الآن + +611 +01:17:38,350 --> 01:17:45,710 +لو عوّض X عندك X و الساعة عشر هكون ناقص مية و ستين + +612 +01:17:45,710 --> 01:17:52,810 +زائد تمانية ناقص + +613 +01:17:52,810 --> 01:17:57,870 +عشرة في سبعة ناقص سبعين + +614 +01:17:59,690 --> 01:18:06,650 +الان عندي هنا تلاتة تربية ناقص + +615 +01:18:06,650 --> 01:18:11,730 +اربعمية وتسعين زائد + +616 +01:18:11,730 --> 01:18:20,730 +تسعين احسبوها هتكون + +617 +01:18:20,730 --> 01:18:25,250 +تطلعاش + +618 +01:18:25,250 --> 01:18:28,010 +ميتين واربعين + +619 +01:18:30,060 --> 01:18:34,060 +واضح المسافة هذه بالساوية zero انا اتضلتها ماشي + +620 +01:18:34,060 --> 01:18:40,860 +عادل زي هيك وفجأة + +621 +01:18:40,860 --> 01:18:46,160 +نزلت .. نزلتها ال 240 لتحت نزلتها + +622 +01:18:46,160 --> 01:18:55,480 +ال 240 لتحت لو + +623 +01:18:55,480 --> 01:18:56,740 +حطيت مرحلة رابعة + +624 +01:19:01,440 --> 01:19:09,820 +أحط اليساوي بقضيف اللي عليها هذه واضح هى + +625 +01:19:09,820 --> 01:19:12,300 +كمان ال shear moment diagram جبنا الكويتش طبعا + +626 +01:19:12,300 --> 01:19:14,560 +الكويتش هتمكن تعمل ايه اللي هي ال simplification + +627 +01:19:14,560 --> 01:19:17,320 +عندها يعني ارواحها نقص شرين هي تبسطها اكتر + +628 +01:19:20,870 --> 01:19:23,830 +طبعا هذه مزيتها في البرمجة، برمجتها سهلة، انت + +629 +01:19:23,830 --> 01:19:27,610 +تبرمج على ال MATLAB او اي برنامج تاني، سهلة في + +630 +01:19:27,610 --> 01:19:30,610 +البرمجة و إذا اتعود عليها بتعطيلك سرعة، هي بس + +631 +01:19:30,610 --> 01:19:32,550 +تعود، في اي سؤال؟ + diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/OJ_cnqk3OA4.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/OJ_cnqk3OA4.srt new file mode 100644 index 0000000000000000000000000000000000000000..7b5b46588b70ed64bf80a91ab622e17212ae14e1 --- /dev/null +++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/OJ_cnqk3OA4.srt @@ -0,0 +1,2443 @@ +1 +00:00:05,150 --> 00:00:07,690 +طيب بسم الله الرحمن الرحيم السلام عليكم ورحمة الله + +2 +00:00:07,690 --> 00:00:12,470 +وبركاته اليوم هنكمل ال load and stress analysis من + +3 +00:00:12,470 --> 00:00:18,510 +chapter ثلاثة المحاضرة الماضية درسنا حالة ال plan + +4 +00:00:18,510 --> 00:00:26,030 +stress case أخدنا 2D stress element وعملنا free + +5 +00:00:26,030 --> 00:00:29,260 +body diagram عاملنا summation of forces باتجاه ال X + +6 +00:00:29,260 --> 00:00:32,620 +و summation of forces باتجاه ال Y ومنها حسبنا + +7 +00:00:32,620 --> 00:00:36,980 +سيجما آنى plane ميل في زاوية في مع ال X axis + +8 +00:00:36,980 --> 00:00:41,160 +اللي هي العلاقة هذه سيجما يساوي سيجما X زائد سيجما Y + +9 +00:00:41,160 --> 00:00:43,360 +على اثنين زائد سيجما X ناقص سيجما Y على اثنين + +10 +00:00:43,360 --> 00:00:48,760 +كوساين 2 في زائد تاو XY ساين 2 في و تاو يساوي ناقص + +11 +00:00:48,760 --> 00:00:51,640 +sigma X ناقص sigma Y على اثنين ساين 2 في زائد تاو XY + +12 +00:00:51,640 --> 00:00:52,480 +كوساين 2 في + +13 +00:00:55,310 --> 00:01:01,650 +طبعا المعادلة هذه إذا بنحورها بطريقة ما هذه تمثل + +14 +00:01:01,650 --> 00:01:08,410 +معادلة دائرة اللي هي Mohr circle حسبنا اللي هو ال + +15 +00:01:08,410 --> 00:01:10,810 +principal stresses ال stresses أو المستويات اللي + +16 +00:01:10,810 --> 00:01:15,390 +بتكون عندها ال normal stresses بتكون maximum أشتقينا + +17 +00:01:15,390 --> 00:01:19,950 +دي sigma by دي فايف صورناها لصفر وجبنا ال five P + +18 +00:01:19,950 --> 00:01:24,230 +إزاي وبيكون عندها ال stress أو المستوى اللي بيكون + +19 +00:01:24,230 --> 00:01:26,910 +عندها ال principal stress اللي هي تان 2 five P + +20 +00:01:26,910 --> 00:01:31,630 +يساوي اثنين تاو XY على sigma X ناقص sigma Y ومن + +21 +00:01:31,630 --> 00:01:33,770 +هنا حسبنا ال principal stress بيستخدم sigma X + +22 +00:01:33,770 --> 00:01:36,930 +زائد sigma Y على اثنين هتمثل إيه؟ تمثل ال center ل + +23 +00:01:36,930 --> 00:01:41,590 +Mohr circle زائد أو ناقص هتمثل ال radius تاع Mohr + +24 +00:01:41,590 --> 00:01:42,250 +circle + +25 +00:01:45,160 --> 00:01:49,600 +طبعا عند ال principal stress planes بيكونش عند + +26 +00:01:49,600 --> 00:01:55,020 +الشير stress يعني الشير stress بيكون يساوي zero ال + +27 +00:01:55,020 --> 00:01:59,200 +maximum shear stress بيكون الشير stress maximum + +28 +00:01:59,200 --> 00:02:02,460 +على مستوى يعمل plus or minus زاوية خمسة وأربعين + +29 +00:02:02,460 --> 00:02:06,760 +درجة مع ال principal planes والتاوة واحدة والثانية + +30 +00:02:06,760 --> 00:02:09,840 +المعطاة بالعلاقة هذه اللي هي تمثل ال radius ل Mohr + +31 +00:02:09,840 --> 00:02:14,660 +circle طيب + +32 +00:02:16,080 --> 00:02:20,140 +بعدين قصرنا Mohr circle حلينا example الآن ال + +33 +00:02:20,140 --> 00:02:23,640 +general 3D state of stress يعني عندي sigma X + +34 +00:02:48,390 --> 00:03:03,790 +x y z and + +35 +00:03:03,790 --> 00:03:10,010 +sigma x sigma + +36 +00:03:10,010 --> 00:03:14,770 +y و + +37 +00:03:14,770 --> 00:03:15,070 +sigma + +38 +00:03:24,080 --> 00:03:34,240 +z عندي tau xy عندي + +39 +00:03:34,240 --> 00:03:38,920 +tau xz + +40 +00:03:38,920 --> 00:03:44,520 +وعندي + +41 +00:03:44,520 --> 00:03:48,460 +tau yz + +42 +00:03:59,240 --> 00:04:04,140 +هذه ال 3D state of stress لو أخذت 3D stress + +43 +00:04:04,140 --> 00:04:07,760 +element أخذت + +44 +00:04:07,760 --> 00:04:13,560 +3D stress element يعني أخذت element بشكل + +45 +00:04:13,560 --> 00:04:17,020 +هذا هيكون + +46 +00:04:17,020 --> 00:04:17,580 +فيه surface + +47 +00:04:35,350 --> 00:04:39,570 +هيكون فيه surface عليها shear stress و normal + +48 +00:04:39,570 --> 00:04:43,230 +stress فممكن + +49 +00:04:43,230 --> 00:04:47,470 +أواجه الليلة قبلين ال normal stress على المستوى + +50 +00:04:47,470 --> 00:04:51,670 +هذا و shear stress مع sigma x sigma y sigma z + +51 +00:04:51,670 --> 00:04:56,850 +delta tau xy tau xz tau yz بنفس السياق اللي + +52 +00:04:56,850 --> 00:05:01,370 +حكيناه في ال 2d case منها بعدين بحسب ال principal + +53 +00:05:01,370 --> 00:05:07,610 +stresses بيطلع عندي معادلة اللي هي 3D case اللي هذه + +54 +00:05:07,610 --> 00:05:11,910 +المعادلة من الدرجة الثالثة عندي sigma تكعيب عندي + +55 +00:05:11,910 --> 00:05:17,010 +sigma تربيع هذا ال parameter هذا ال constant بتاع + +56 +00:05:17,010 --> 00:05:21,850 +sigma تربيع وعندي ال sigma وهذا ال constant تبعه + +57 +00:05:21,850 --> 00:05:30,650 +وعندي يعني هتكون polynomial على شكل sigma تكعيب ناقص + +58 +00:05:30,650 --> 00:05:46,230 +a sigma تربيع ناقص b sigma زائد b sigma ناقص c + +59 +00:05:46,230 --> 00:05:52,430 +يساوي صفر هذا هيكلها ثلاثة roots sigma واحد + +60 +00:05:52,430 --> 00:05:57,040 +sigma اثنين sigma ثلاثة sigma واحد والسيجما اثنين + +61 +00:05:57,040 --> 00:06:07,060 +والسيجما ثلاثة لها ثلاثة roots ممكن + +62 +00:06:07,060 --> 00:06:11,560 +أرسم ال Mohr circle ال Mohr circle طبعا في حالة 3D + +63 +00:06:11,560 --> 00:06:16,740 +case هيكون أنها سيجما واحد سيجما اثنين سيجما ثلاثة + +64 +00:06:16,740 --> 00:06:21,340 +في دائرة بين السيجما واحد وسيجما اثنين ودائرة بين + +65 +00:06:21,340 --> 00:06:26,270 +سيجما اثنين وسيجما ثلاثة ودائرة بين سيجما واحد و + +66 +00:06:26,270 --> 00:06:32,130 +sigma 3 ممكن أحسب ال maximum shear stress بين كل + +67 +00:06:32,130 --> 00:06:34,950 +واحدة بين sigma 1 و sigma 2 أو بين sigma 1 و sigma + +68 +00:06:34,950 --> 00:06:38,770 +3 أو بين sigma 2 و sigma 3 هيكون دي tau 1 2 يساوي + +69 +00:06:38,770 --> 00:06:43,210 +sigma 1 ناقص sigma 2 على 2 اللي هو مثل ال radius + +70 +00:06:43,210 --> 00:06:50,610 +للدائرة هذه و tau 2 3 اللي هو sigma 2-sigma 3 على 2 + +71 +00:06:50,610 --> 00:06:54,430 +اللي هو مثل ال radius الدائرة هذه وT1 ثلاثة مثل ال + +72 +00:06:54,430 --> 00:06:57,550 +radius الدائرة الكبيرة اللي هو sigma 1-sigma 3 على + +73 +00:06:57,550 --> 00:07:06,970 +2 إذا رتبتهم بترتيب بحيث أن تكون sigma 1 أكبر + +74 +00:07:06,970 --> 00:07:12,210 +من sigma 2 أكبر من sigma 3 بيكون أكبر T في الثلاثة + +75 +00:07:12,210 --> 00:07:12,710 +T maximum + +76 +00:07:26,560 --> 00:07:28,520 +طيب نكمل + +77 +00:07:42,540 --> 00:07:45,600 +إحنا في ال design أنه ندرس ال ... ال mechanical + +78 +00:07:45,600 --> 00:07:49,760 +parts في معظم الأحوال في ال elastic range يعني + +79 +00:07:49,760 --> 00:07:54,940 +ما ندخلش ل plastic range في المعادن بالذات بتكون + +80 +00:07:54,940 --> 00:07:57,840 +إذا فاكرين ال stress strain diagram + +81 +00:08:02,490 --> 00:08:05,770 +إحنا بتكون في ال range هذا في ال range هذا علاقة + +82 +00:08:05,770 --> 00:08:12,110 +بين هذا ال slope E بتكون ال sigma يساوي E في + +83 +00:08:12,110 --> 00:08:17,570 +أبسلون هتسميه Hooke's law إذا كانت عندي two states + +84 +00:08:17,570 --> 00:08:24,130 +of stress يعني عندي هاي mechanical element وعليه + +85 +00:08:24,130 --> 00:08:32,000 +sigma X بس Axial load بيكون ال strain باتجاه ال X + +86 +00:08:32,000 --> 00:08:40,600 +-axis أبسلون X يساوي سيجما X على A الآن صح فيه فيش + +87 +00:08:40,600 --> 00:08:44,940 +stresses باتجاه المستعرض باتجاه ال Y وال Z لكن + +88 +00:08:44,940 --> 00:08:48,920 +بيزن ratio effect بدخل على الخط لأن لما بزيق بقى + +89 +00:08:48,920 --> 00:08:55,000 +شد بزيد الطول والمقطع معناته بيصير عندي أبسلون Y + +90 +00:08:55,000 --> 00:09:01,940 +يساوي ناقص Nu أبسلون X يعني يساوي ناقص نيو في + +91 +00:09:01,940 --> 00:09:08,920 +سيجما X على A و أبسلون Z يساوي ناقص نيو في أبسلون + +92 +00:09:08,920 --> 00:09:23,100 +X يساوي ناقص نيو في سيجما Y في سيجما X على A لو + +93 +00:09:23,100 --> 00:09:24,440 +كان عندي element + +94 +00:09:29,140 --> 00:09:41,340 +ال 3D element عليه عليه + +95 +00:09:41,340 --> 00:09:45,580 +Sigma X و + +96 +00:09:45,580 --> 00:09:51,200 +Sigma Y و + +97 +00:09:51,200 --> 00:09:53,780 +Sigma Z + +98 +00:09:59,530 --> 00:10:05,770 +الأبسط من X لو كان بس Sigma X لحاله هيكون فيه strain + +99 +00:10:05,770 --> 00:10:13,610 +عندي اللي هو sigma X على + +100 +00:10:13,610 --> 00:10:20,330 +A لو كان sigma X لحاله لكن فيه عندي sigma Y بعكسه + +101 +00:10:20,330 --> 00:10:29,800 +من ناقص nu في sigma Y على a وفيه كمان sigma z + +102 +00:10:29,800 --> 00:10:38,780 +ناقص nu sigma z على a يعني خط واحد على a عام + +103 +00:10:38,780 --> 00:10:46,440 +مشترك بيكون يساوي sigma x ناقص nu في sigma y + +104 +00:10:46,440 --> 00:10:55,460 +زائد sigma z اللي هي المعادلة الأولى هذه بنفس المنطق + +105 +00:10:56,790 --> 00:11:03,890 +epsilon y لو لحاله هتقيم sigma y على a لكن أنا + +106 +00:11:03,890 --> 00:11:07,510 +موجود عند sigma x و sigma z هيكون عندي ال poisson + +107 +00:11:07,510 --> 00:11:12,510 +effect هيكون ناقص mu sigma x زائد sigma z نفس + +108 +00:11:12,510 --> 00:11:19,020 +الشيء لو عندي epsilon z في stress due ل sigma z وفي + +109 +00:11:19,020 --> 00:11:22,060 +stress due to the poisson effect of ناقص mu sigma + +110 +00:11:22,060 --> 00:11:33,260 +x أو strain ناقص mu sigma x زائد sigma y في + +111 +00:11:33,260 --> 00:11:44,780 +حالة ال shear إذا + +112 +00:11:44,780 --> 00:11:45,380 +عندي block + +113 +00:11:48,110 --> 00:12:00,650 +due to shear and + +114 +00:12:00,650 --> 00:12:14,930 +هنا shear stress tau هتصير angle gamma الآن + +115 +00:12:15,600 --> 00:12:21,940 +هيكون فعل قبلين التاو والجامعة تاو جي + +116 +00:12:21,940 --> 00:12:26,720 +في gamma الجامعة + +117 +00:12:26,720 --> 00:12:31,890 +نتيجة sharing حاسين دي rotation حاسين دي الزاوية + +118 +00:12:31,890 --> 00:12:37,690 +gamma بسميها angular strain angular strain ال G ال + +119 +00:12:37,690 --> 00:12:41,370 +shear modulus أو ال modulus of rigidity لأن في + +120 +00:12:41,370 --> 00:12:46,370 +حالة linear مادة خطية isotropic homogeneous + +121 +00:12:46,370 --> 00:12:50,990 +material بيكون علاقة بين ال E وال G اللي هي ال E + +122 +00:12:50,990 --> 00:12:58,390 +يساوي اثنين في G واحد زائد Nu طيب + +123 +00:13:02,950 --> 00:13:09,970 +اليوم هناخد حالات خاصة من ال stress أول حالة اللي + +124 +00:13:09,970 --> 00:13:15,090 +هي uniaxial state of stress يعني عندي mechanical + +125 +00:13:15,090 --> 00:13:19,710 +member وها + +126 +00:13:19,710 --> 00:13:24,290 +كتاعة إما شد أو + +127 +00:13:24,290 --> 00:13:32,010 +compression والمقطع بتاعهم مساحة مقطع إيه؟ هسيب عندي + +128 +00:13:32,010 --> 00:13:41,370 +axial أو normal stress sigma يساوي F على A ده حكي + +129 +00:13:41,370 --> 00:13:45,490 +plus أو minus؟ plus بيكون tension إذا كان عندي + +130 +00:13:45,490 --> 00:13:49,370 +tension force minus إذا كان عندي compression force + +131 +00:13:49,370 --> 00:13:53,190 +في + +132 +00:13:53,190 --> 00:13:55,290 +حالة direct shear إذا عندي element + +133 +00:14:00,090 --> 00:14:09,090 +العرض قليل كتير ومثبت وعليه force V direct shear + +134 +00:14:09,090 --> 00:14:14,810 +التاو V على A + +135 +00:14:23,100 --> 00:14:27,340 +في حالة bending طبعا هندرس ال bending في حالة + +136 +00:14:27,340 --> 00:14:32,560 +straight beams يعني الجسر عدل في آخر الشبط هناخد + +137 +00:14:32,560 --> 00:14:36,620 +ال bending في حالة curved beam بيختلف اختلاف كبير + +138 +00:14:36,620 --> 00:14:47,000 +الآن أنا عندي هنا beam هذا المحور ال x axis هذا + +139 +00:14:47,000 --> 00:14:50,620 +ال y axis هذا ال z axis + +140 +00:14:53,230 --> 00:15:02,770 +هذا متعرض ل bending moment موجبة ولا سالبة؟ موجبة + +141 +00:15:02,770 --> 00:15:09,270 +لأنه بتحاول تعمله concave بالشكل هذا فهذه M وعندي + +142 +00:15:09,270 --> 00:15:13,330 +M موجبة + +143 +00:15:15,640 --> 00:15:20,140 +الـ X-axis هذا المقطع يبين أنه مستطيل الـ X-axis + +144 +00:15:20,140 --> 00:15:22,660 +بيسميه الـ neutral axis الـ neutral axis بيكونش + +145 +00:15:22,660 --> 00:15:25,400 +فيه عنده strain مش بيكونش فيه عنده deformation + +146 +00:15:25,400 --> 00:15:34,240 +والـ XZ plane هو الـ neutral plane والـ bending + +147 +00:15:34,240 --> 00:15:39,280 +بيصير حوالين إيه؟ إنّها تمحور حوالين الـ Z-axis + +148 +00:15:40,190 --> 00:15:52,370 +المعادلة اللي + +149 +00:15:52,370 --> 00:15:57,390 +سنجربها بعد شوية based + +150 +00:15:57,390 --> 00:16:03,910 +على الفرضيات التالية أول شيء الفرضية إن أنا عندي + +151 +00:16:03,910 --> 00:16:09,030 +pure bending كأني ماسك هيك و بطعج بالشكل هذا. اثنين + +152 +00:16:09,030 --> 00:16:13,470 +material isotropic and homogeneous خواص متجانس و + +153 +00:16:13,470 --> 00:16:19,010 +ما فيش اختلاف في الخواص material obeys hook's law + +154 +00:16:19,010 --> 00:16:24,530 +يعني علاقة بين ال stress و ال strain خطية. سجن + +155 +00:16:24,530 --> 00:16:30,270 +مستوى E في أبسلون beam is initially straight with + +156 +00:16:30,270 --> 00:16:34,530 +constant cross section الجسر في البداية كان مستقيم + +157 +00:16:34,530 --> 00:16:37,470 +و المقطع بتاعه ثابت + +158 +00:16:40,570 --> 00:16:47,190 +beam has axis of symmetry in plane of bending يعني + +159 +00:16:47,190 --> 00:16:57,270 +المعادلات هذه مثلا هذه ال section مستطيل خلصت + +160 +00:16:57,270 --> 00:17:03,130 +axis لاحظوا هذه ال y axis في symmetry حول ال y + +161 +00:17:03,130 --> 00:17:05,630 +axis لكن لو كانت حالة + +162 +00:17:14,100 --> 00:17:21,540 +شيء زي هيك فيه symmetry حوالين ال y axis لا عن طبق + +163 +00:17:21,540 --> 00:17:27,680 +المعادلات failure + +164 +00:17:27,680 --> 00:17:31,740 +is by bending إذاً فصار failure نتيجة ال bending + +165 +00:17:31,740 --> 00:17:38,160 +يعني بيصير لايق بيصير طعج للمادة not by crushing, + +166 +00:17:38,400 --> 00:17:41,940 +wrinkling أو sideways buckling + +167 +00:17:44,240 --> 00:17:48,500 +من جنب أو crushing يعني بيصير فيه تكسير يعني بيصير + +168 +00:17:48,500 --> 00:17:54,200 +كأنه بتكسر و بيصرع. لعب بيصير bending طبيعي plain + +169 +00:17:54,200 --> 00:17:58,400 +cross sections remain plain نتيجة ال bending بيصير + +170 +00:17:58,400 --> 00:18:02,260 +rotation في المستويات يعني المستوي في الأول بيكون + +171 +00:18:02,260 --> 00:18:09,520 +مستوي ولا يصير bending بمئة صحيح بس هو مستوي لكنه + +172 +00:18:09,520 --> 00:18:12,480 +عرض واقعي بيصير فيه some curvature بس إحنا بنفترض + +173 +00:18:12,480 --> 00:18:19,240 +إنّ ال curvature مهمل من + +174 +00:18:19,240 --> 00:18:28,020 +ال mechanics of material عندي + +175 +00:18:28,020 --> 00:18:30,960 +ال sigma باتجاه ال X طبعًا هي عندي XY + +176 +00:18:37,130 --> 00:18:44,530 +Y Y Z Axis و ال moment جاي حوالين ال X Axis و ال + +177 +00:18:44,530 --> 00:18:50,630 +stress هيكون باتجاه ال X Axis طبعًا إحنا في الحالة + +178 +00:18:50,630 --> 00:19:00,550 +هذه أنا positive positive moment هاي MZ واضح + +179 +00:19:00,550 --> 00:19:05,610 +إنّه إنّه إذا في ال circumfecture بشكل هذامعناته + +180 +00:19:05,610 --> 00:19:10,670 +السطح اللي هو هيكون under compression مضغوط و + +181 +00:19:10,670 --> 00:19:20,950 +السطح السفلي يكون مشدود ال sigma X أو ال stress at + +182 +00:19:20,950 --> 00:19:24,190 +any location Y هذا ال X axis هو ال neutral axis + +183 +00:19:24,190 --> 00:19:27,330 +هذه المسافة Y + +184 +00:19:32,030 --> 00:19:35,070 +الـ stress at any location y من الـ neutral axis + +185 +00:19:35,070 --> 00:19:45,330 +sigma x بالسواء minus M z في y على I. I هي ال + +186 +00:19:45,330 --> 00:19:51,730 +moment of inertia لل section حوالين ال z axis. I هي + +187 +00:19:51,730 --> 00:19:55,250 +ال moment of inertia للsection حوالين ال z axis + +188 +00:19:55,250 --> 00:19:56,330 +خلّيني أسميها Iz + +189 +00:20:04,200 --> 00:20:08,220 +لأن ليش اختار الشرط ال minus؟ لأن إحنا اتفقنا إنّه + +190 +00:20:08,220 --> 00:20:13,900 +ال definition بتاع ال .. ال .. ال bending moment + +191 +00:20:13,900 --> 00:20:17,600 +الموجب بقى بالشكل هذا بالشكل اللي بتعمل إياه + +192 +00:20:17,600 --> 00:20:21,640 +compression. ما أنا متوقع إن يكون عنده stress هنا بال + +193 +00:20:21,640 --> 00:20:27,540 +negative فعنده هنا minus و ال y بطلع لاعلى بتكون + +194 +00:20:27,540 --> 00:20:31,360 +إياه موجبة بقى فلازم تطلع هذه إذا كانت ال bending + +195 +00:20:31,360 --> 00:20:35,980 +moment موجبة بقى وهذه موجبة بقى لازم أحط إشارة + +196 +00:20:35,980 --> 00:20:42,900 +السالب عشان هي أنا حاطط إشارة السالب. ال moment أو + +197 +00:20:42,900 --> 00:20:46,280 +ال stress بيكون maximum عند ال outer fibers عند + +198 +00:20:46,280 --> 00:20:51,380 +head outer fiber ال sigma maximum بالسواء في C على + +199 +00:20:51,380 --> 00:20:57,410 +I و في ندي هي ال moment بالموجب tension عند ال + +200 +00:20:57,410 --> 00:21:02,450 +outer fiber بيساوي اللي هي M في C على I أو في + +201 +00:21:02,450 --> 00:21:09,410 +معادلة ثانية ال sigma max بيساوي + +202 +00:21:09,410 --> 00:21:18,290 +M على Z اللي هي section modulus بيسموها ال Z بيساوي + +203 +00:21:18,290 --> 00:21:25,510 +I على C يعني هي الأساس بيساوي M في C على I قصة + +204 +00:21:25,510 --> 00:21:32,150 +والبسط على C والمقام على C بيصير M في I على C اللي + +205 +00:21:32,150 --> 00:21:42,410 +هي M على Z capital هنشوف + +206 +00:21:42,410 --> 00:21:42,870 +مثال + +207 +00:21:54,950 --> 00:22:02,230 +a beam and a beam having a T-section ال beam مقطع + +208 +00:22:02,230 --> 00:22:07,210 +على شكل حرف T مقطع ال beam and beam هي طويلة عملتله + +209 +00:22:07,210 --> 00:22:14,970 +مقطع مستعرض شكل المقطع حرف T is + +210 +00:22:14,970 --> 00:22:18,810 +subjected to a bending moment of 1600 Newton meter + +211 +00:22:18,810 --> 00:22:23,710 +متعرض ل bending moment قيمتها 1600 نيوتن متر + +212 +00:22:23,710 --> 00:22:34,180 +ال moment بس هو 1600 نيوتن متر about the + +213 +00:22:34,180 --> 00:22:39,160 +negative z axis that causes tension at the top + +214 +00:22:39,160 --> 00:22:44,620 +surface ال moment اللي هتجه تعمله tension على + +215 +00:22:44,620 --> 00:22:49,920 +السطح اللي هو إيه compression على السطح إيه؟ عشان + +216 +00:22:49,920 --> 00:22:55,620 +بس لأن جاية ال moment إيه؟ عشان negative locate بـ + +217 +00:22:55,620 --> 00:22:59,100 +neutral axis أول خطوة نعمل تحديد موقع ال neutral + +218 +00:22:59,100 --> 00:23:04,880 +axis عشان + +219 +00:23:04,880 --> 00:23:09,060 +أحدد موقع ال neutral axis أولًا شبه أختار محاول + +220 +00:23:09,060 --> 00:23:14,600 +إحداثيات صح؟ لو حكيت هاي ال X axis ممكن أختاره في + +221 +00:23:14,600 --> 00:23:22,400 +أي مكان دي هاي X axis وهذا + +222 +00:23:28,390 --> 00:23:35,870 +الـ y-axis وده أقسم المقطع لمساحتين ممكن أعمله + +223 +00:23:35,870 --> 00:23:40,250 +بكذا طريقة ممكن أحكي هذه مساحة واحد وهذه مساحة + +224 +00:23:40,250 --> 00:23:47,130 +اثنين أو هذه مساحة واحد وهذه + +225 +00:23:47,130 --> 00:23:51,750 +اتنين. مساحة اثنين في كذا طريقة فاحكي هذه هي + +226 +00:23:51,750 --> 00:23:52,970 +المساحة رقم واحد + +227 +00:23:56,740 --> 00:24:03,560 +و هذا المسطيل مساحة رقم اثنين يعني عندي مساحتين + +228 +00:24:03,560 --> 00:24:21,140 +هنعمل + +229 +00:24:21,140 --> 00:24:24,680 +جدول ال + +230 +00:24:24,680 --> 00:24:25,480 +number عندي هنا + +231 +00:24:29,120 --> 00:24:37,100 +المساحة الـ Area رقم واحد الـ Area بتاعتها + +232 +00:24:37,100 --> 00:24:40,900 +بالملي + +233 +00:24:40,900 --> 00:24:46,900 +ميتر تربيع Area + +234 +00:24:46,900 --> 00:24:50,400 +ال + +235 +00:24:50,400 --> 00:24:56,080 +unit بتاعتها ملي ميتر تربيع واحد + +236 +00:24:58,360 --> 00:25:05,340 +175 يعني 400 في 3 + +237 +00:25:05,340 --> 00:25:11,980 +900 صح 900 ملي + +238 +00:25:11,980 --> 00:25:20,740 +ميتر مربع المساحة رقم اثنين عندي + +239 +00:25:20,740 --> 00:25:25,760 +هذه كلها 100 وهذه 12 معناه في هذه الطول إيش + +240 +00:25:25,760 --> 00:25:31,370 +هيكون 88 في كم في 12 أدروها 8 + +241 +00:25:31,370 --> 00:25:38,330 +80 في 12 كم 8 + +242 +00:25:38,330 --> 00:25:44,750 +80 في 12 1056 1056 و + +243 +00:25:44,750 --> 00:25:49,230 +50 millimeter تربيع معناته ال area الكلية + +244 +00:25:49,230 --> 00:25:56,170 +مجموعهم صح أجمع ال areas هيكون 1056 + +245 +00:25:56,170 --> 00:26:04,710 +900 و 56 طبعًا + +246 +00:26:04,710 --> 00:26:12,510 +واضح ال beam symmetrical حوالين ال y axis المركز + +247 +00:26:12,510 --> 00:26:15,970 +المساحي هيكون واقع أكيد على المحور هذا ففيش ده + +248 +00:26:15,970 --> 00:26:20,150 +أشطر الشغل فبدي أخد moment حوالين ال x axis moment + +249 +00:26:20,150 --> 00:26:25,790 +حوالين ال x axis هتقرر يا واحد هقرر يا واحد + +250 +00:26:30,350 --> 00:26:43,470 +area 1 مركز + +251 +00:26:43,470 --> 00:26:54,190 +هو ده كم؟ 100 ناقص 36 = 64 و ال area + +252 +00:26:54,190 --> 00:26:54,650 +اثنين + +253 +00:27:00,370 --> 00:27:14,690 +802 أي شيء 44 بدي + +254 +00:27:14,690 --> 00:27:22,290 +أحسب ال I حوالين مركز المساحة لكل واحدة ال I طبعًا + +255 +00:27:22,290 --> 00:27:26,150 +أنا بدي أخد ال I حوالين Z axis ال I ل I بدي أحكي I + +256 +00:27:26,150 --> 00:27:26,490 +C + +257 +00:27:31,180 --> 00:27:36,180 +مومنت انيرشيا للمساحة + +258 +00:27:36,180 --> 00:27:40,540 +حوالين المركز هداش والساول 1 على 12 في 5 + +259 +00:27:40,540 --> 00:27:45,000 +70 في 12 تكيب يعني 570 في 104 + +260 +00:27:45,000 --> 00:27:53,440 +40 يعني هتكون هذه 1 على 12 في 570 + +261 +00:27:53,440 --> 00:28:06,970 +في 12 تكيب والتاني هتكون 1 على 12 في 12 + +262 +00:28:06,970 --> 00:28:10,110 +في + +263 +00:28:10,110 --> 00:28:15,670 +88 تربيع التكييب 88 تكيب + +264 +00:28:15,670 --> 00:28:25,250 +يعني هذا هتساوي سيبوليها اللي + +265 +00:28:25,250 --> 00:28:29,350 +تحت كم اللي فوق 1 1 + +266 +00:28:32,370 --> 00:28:40,650 +10800 هي باين الرقم إنّ هذا الرقم صحيح + +267 +00:28:40,650 --> 00:28:46,610 +التانية التانية + +268 +00:28:46,610 --> 00:28:51,450 +600 + +269 +00:28:51,450 --> 00:29:02,120 +و 180000 402 و 72 يعني 100 + +270 +00:29:02,120 --> 00:29:09,480 +100 100 مليون اه بتروح اه منطقي طيب + +271 +00:29:09,480 --> 00:29:16,460 +الآن + +272 +00:29:16,460 --> 00:29:22,020 +ال parallel axis theorem مثلًا ال I ال I حول ال X + +273 +00:29:22,020 --> 00:29:28,380 +axis ال I حول ال X axis لواحد بيساوي ال I C واحد + +274 +00:29:28,380 --> 00:29:42,340 +زائد ال A واحد في ال y ال y واحد تربيع صح مظبوط يعني + +275 +00:29:42,340 --> 00:29:49,980 +هتساوي ICU واحد دي 10800 زائد ال area + +276 +00:29:49,980 --> 00:29:58,380 +واحد 900 في y واحد تربيع 64 صح + +277 +00:30:03,750 --> 00:30:11,490 +هذا هسميها .. هسميها + +278 +00:30:11,490 --> 00:30:20,130 +ال area في Y تربيع .. هسميها ال area في Y تربيع + +279 +00:30:20,130 --> 00:30:28,290 +هتكون 900 في 64 تربيع صح؟ + +280 +00:30:43,020 --> 00:30:52,460 +7 مليون يعني يقول 1000 .. 1000 .. 10 آلاف تقريبًا + +281 +00:30:52,460 --> 00:30:54,620 +يعني .. ألف عشر تلف يعني عشر مليون .. سبعة مليون + +282 +00:30:54,620 --> 00:31:04,900 +أكم تطلع .. سبعة مليون طيب + +283 +00:31:04,900 --> 00:31:10,500 +التانية هتكون ال area عندي اللي هي الف و ستة و + +284 +00:31:10,500 --> 00:31:10,920 +خمسين + +285 +00:31:15,410 --> 00:31:24,590 +في اربع و اربعين تربيع صح كم + +286 +00:31:24,590 --> 00:31:31,770 +تطلع لأ + +287 +00:31:31,770 --> 00:31:37,910 +نزودش بس كم بعدين تسعين دولار و اربع تسعين تربيع + +288 +00:31:37,910 --> 00:31:42,490 +هي + +289 +00:31:42,490 --> 00:31:43,290 +سبعة مليون + +290 +00:31:45,920 --> 00:31:50,980 +سبعة .. سبعة مليون و + +291 +00:31:50,980 --> 00:31:54,020 +التانية + +292 +00:31:54,020 --> 00:31:59,580 +اتنين مليون اربعة و اربعين ألف اربع مين و ستة عشر + +293 +00:31:59,580 --> 00:32:03,680 +هطينا + +294 +00:32:03,680 --> 00:32:10,440 +.. هطينا أرقام الشمال اتنين سفر اربع مليون أيوة + +295 +00:32:12,930 --> 00:32:19,270 +اربع واحد ستة معناته + +296 +00:32:19,270 --> 00:32:27,810 +الـ I حوالي الـ X هتستوى هذا الرقم زي هذا الرقم إيش + +297 +00:32:27,810 --> 00:32:37,770 +بعمل إيه يا عم مش حافظ أعطني يعني أيوة والتاني + +298 +00:32:47,340 --> 00:32:56,000 +تسعة مليون كم اتنين + +299 +00:32:56,000 --> 00:33:00,400 +مليون + +300 +00:33:00,400 --> 00:33:04,980 +تلت + +301 +00:33:04,980 --> 00:33:11,560 +مية اجمعولي + +302 +00:33:11,560 --> 00:33:13,280 +كل الـ I حول الـ X Axis + +303 +00:33:17,530 --> 00:33:25,510 +أكمل بيطلع؟ اجمع هذا مع هذا عشرة مليون عشرة مليون + +304 +00:33:25,510 --> 00:33:29,870 +و ستمية وتسعة تمانين ألف و ستمية تسعة تمانين ألف + +305 +00:33:29,870 --> 00:33:33,590 +ثمانية ثمانية سفر ثمانية ثمانية + +306 +00:33:49,890 --> 00:33:53,390 +هنا عشان نحسب الـ .. الـ .. الـ .. الـ a الـ .. الـ .. + +307 +00:33:53,390 --> 00:34:01,850 +الـ .. الـ neutral axis هنجي نحكي a1 a1 + +308 +00:34:01,850 --> 00:34:12,050 +هناخد ال moment ده ال area a1 في y1 زاد + +309 +00:34:12,050 --> 00:34:24,430 +a2 في y2 بالثورة aفي الـ Y صح؟ + +310 +00:34:24,430 --> 00:34:27,110 +يعني مافقد ان أنا فيها ان مافيش حاجة نواصل هيكون + +311 +00:34:27,110 --> 00:34:36,410 +الساوية A1 اللي هي تسعمية في Y1 اللي هي اربعة + +312 +00:34:36,410 --> 00:34:45,670 +وتسعين زاد A2 الف و ستة و خمسين في Y2 اللي هي + +313 +00:34:45,670 --> 00:34:50,260 +اربعة و اربعين بالساوي الـ ايه الكليه اللي هي الف + +314 +00:34:50,260 --> 00:34:57,320 +تسعمائة و ستة و خمسين في Y و من هنا بحسب الـ Y + +315 +00:34:57,320 --> 00:35:02,880 +حسبوها كم تطلع كم + +316 +00:35:02,880 --> 00:35:14,560 +مية و واحد تلاتين الف يعني برا برا برا الدين هتكون + +317 +00:35:14,560 --> 00:35:17,340 +يعني أقل من + +318 +00:35:19,280 --> 00:35:25,720 +يعني أقل من سبعين ستكون 67 + +319 +00:35:25,720 --> 00:35:35,100 +ملي متر معناه + +320 +00:35:35,100 --> 00:35:38,860 +تعرفنا ال location ال location بتاع ال neutral + +321 +00:35:38,860 --> 00:35:39,400 +axis + +322 +00:35:49,400 --> 00:35:57,800 +بنسمي هذا C1 و هذا C2 C2 اللي هو سبعة ستين و + +323 +00:35:57,800 --> 00:36:05,780 +C1 بتطلع اللي هو تلاتة تلاتين صح اللي + +324 +00:36:05,780 --> 00:36:13,280 +هو مية نقل سبعة ستين بدي + +325 +00:36:13,280 --> 00:36:20,730 +أحسب الـ I يعني بدي أحسب الـ I حوالينه هو بده يعني + +326 +00:36:20,730 --> 00:36:28,430 +احسب ال maximum tensile stress اللي هو هنا و ال + +327 +00:36:28,430 --> 00:36:31,970 +maximum compression stress اللي هو تحت المعنى هو + +328 +00:36:31,970 --> 00:36:35,710 +لازم احسب الـ I حوالي ال neutral axis الـ I حوالي ال + +329 +00:36:35,710 --> 00:36:42,930 +neutral axis الـ I حوالي ال neutral axis هتكون + +330 +00:36:44,570 --> 00:36:47,750 +الـ I لكل واحد اللي هي الـ I حوالي مركزه اللي + +331 +00:36:47,750 --> 00:36:55,170 +هتكون اللي هي عشر تلف تونمية زائد تسعة مية في + +332 +00:36:55,170 --> 00:37:02,370 +المسافة هذه المسافة دي كم تلات + +333 +00:37:02,370 --> 00:37:10,830 +و تلاتين ماقص ستة اللي هي كم سبعة و عشرين في + +334 +00:37:10,830 --> 00:37:12,190 +السبعة و عشرين تربيع + +335 +00:37:16,660 --> 00:37:22,820 +زاد الـ I تاعت تاني اللي هي ستمية واحد تمانين الف + +336 +00:37:22,820 --> 00:37:26,420 +اربعمية + +337 +00:37:26,420 --> 00:37:35,480 +واتنين وسبعين زاد ال area تاعته الف وستة وخمسين في + +338 +00:37:35,480 --> 00:37:36,320 +المسافة هذه + +339 +00:37:40,590 --> 00:37:46,210 +اللي هتكون سبعة و ستين ناقص اربع و اربعين اللي + +340 +00:37:46,210 --> 00:37:53,890 +هتكون تلاتة و عشرين صح؟ + +341 +00:37:53,890 --> 00:37:58,250 +أنا قلت + +342 +00:37:58,250 --> 00:38:04,310 +بس مش لها داعي مافي لها داعي أنا + +343 +00:38:04,310 --> 00:38:08,790 +بدي ال moment و أنا احسبها على الشسم ال neutral + +344 +00:38:08,790 --> 00:38:13,520 +axis يعني أنا محسفت حوالين الـ I X مايلها لازمة يعني + +345 +00:38:13,520 --> 00:38:20,200 +هذه ماكان لها لازمة طيب هذه كلها سبعة وستين وهذه + +346 +00:38:20,200 --> 00:38:25,080 +اربع واربعين معناته هتكون سبعة وستين ناقص اربع + +347 +00:38:25,080 --> 00:38:31,720 +واربعين تلاتة وعشرين في تلاتة وعشرين تربيع + +348 +00:38:31,720 --> 00:38:34,860 +مليون + +349 +00:38:46,990 --> 00:38:58,150 +تسعمية مليمتر بص أربعة هوجد + +350 +00:38:58,150 --> 00:39:05,870 +ال sigma هدى عند ال fiber هدى نسميها سيجما واحد + +351 +00:39:05,870 --> 00:39:11,550 +هنا اندي ار سيجما اتنين عند واحد ال tension ولا + +352 +00:39:11,550 --> 00:39:20,600 +compression Tension سجن واحد بيستوى M في C واحد على + +353 +00:39:20,600 --> 00:39:24,320 +I هتساوي + +354 +00:39:24,320 --> 00:39:34,180 +ال M عندي الف ستمية في ال C واحد خناكتي + +355 +00:39:34,180 --> 00:39:39,100 +الوحدات يعني الف ستمية ال + +356 +00:39:39,100 --> 00:39:46,550 +نيوتن متر في ال C واحد اللي هي تلاتة وتلاتين اللي + +357 +00:39:46,550 --> 00:39:57,390 +هي point o تلاتة وتلاتين متر صح على I I اللي هي + +358 +00:39:57,390 --> 00:40:07,490 +واحد تسعمية وستة تسعمية وستة وتسعين فعشرة أس سالب + +359 +00:40:07,490 --> 00:40:12,690 +بقى كم اتناش لأن المتر الف ملي متر + +360 +00:40:17,610 --> 00:40:21,730 +عشان احاول اللي ميجا بسكال حاضره في إيش خلينا نحكي + +361 +00:40:21,730 --> 00:40:28,690 +هنا التالي عندي تلاتة تلاتين فعشرة أس سالب تلاتة + +362 +00:40:29,980 --> 00:40:32,680 +عشان احاول ان أنا اجي بس كده هضبه في عشرة أس أس أس + +363 +00:40:32,680 --> 00:40:34,540 +أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس + +364 +00:40:34,540 --> 00:40:35,140 +أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس + +365 +00:40:35,140 --> 00:40:39,560 +أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس + +366 +00:40:39,560 --> 00:40:40,080 +أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس + +367 +00:40:40,080 --> 00:40:41,200 +أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس أس + +368 +00:40:41,200 --> 00:40:48,660 +أس أس أس أس أس أس أس أس أس أس أس + +369 +00:40:53,320 --> 00:40:59,060 +الستمية النيوتن متر في تغيالاته تلاتين في عشر أقل + +370 +00:40:59,060 --> 00:41:06,760 +سالب تلاتة ماشي حسبوليها سبعة و عشرين point سبعة + +371 +00:41:06,760 --> 00:41:17,320 +ميجا بسكت سيجما تمين هتكون بالنجدة هيكون سواء + +372 +00:41:17,320 --> 00:41:25,350 +minus M في C2 على I أو اختصارا ممكن احكي بالساوي + +373 +00:41:25,350 --> 00:41:28,550 +minus + +374 +00:41:28,550 --> 00:41:38,290 +sigma 1 على C1 في C2 بنفعل + +375 +00:41:38,290 --> 00:41:46,290 +أو بنفعش اقسم على C1 هذه واضغطها C2 تعطينا هذه صح؟ + +376 +00:41:48,420 --> 00:41:52,720 +الرد بيبقى رقم مافيش ده اعوض هتكون السابعة و عشرين + +377 +00:41:52,720 --> 00:42:04,540 +point سبعة ع التلاتة و تلاتين في C2 اللي هي سبعة و + +378 +00:42:04,540 --> 00:42:14,920 +ستين يعني + +379 +00:42:14,920 --> 00:42:26,250 +هتكون معاقص سبعة اتنين اربعتاش سبعة اتنين مظبوط + +380 +00:42:26,250 --> 00:42:33,130 +اكتر + +381 +00:42:33,130 --> 00:42:35,770 +شوية اكتر بتطلع ستة و خمسين + +382 +00:42:47,040 --> 00:42:51,840 +ماجي بس كده يعني + +383 +00:42:51,840 --> 00:42:55,640 +كان هدول الخطوات مالهم مش لازم اللي عملتها أنا في + +384 +00:42:55,640 --> 00:43:00,820 +أي سؤال ال stress distribution لو بدأ اعمل stress + +385 +00:43:00,820 --> 00:43:09,680 +distribution هكوندي + +386 +00:43:09,680 --> 00:43:10,660 +highly neutral axis + +387 +00:43:18,680 --> 00:43:24,600 +and hand tension compression + +388 +00:43:45,780 --> 00:43:49,560 +هنا عند ال maximum اللي هي سبعة عشرين point سبعة + +389 +00:43:49,560 --> 00:43:56,360 +هنا عند ستة و خمسين point اتنين ستة و خمسين point + +390 +00:43:56,360 --> 00:44:02,880 +اتنين بيكونش فيه stress عند ال neutral axis هذا في + +391 +00:44:02,880 --> 00:44:04,000 +حالة straight beam + +392 +00:44:38,060 --> 00:44:41,380 +الحالة الأولى السابقة اللي دراسناها كانت one plane + +393 +00:44:41,380 --> 00:44:45,140 +bending يعني ال bending حوالين مستوى واحد الحالة + +394 +00:44:45,140 --> 00:44:47,840 +ال general ان بيكونت two plane bending يعني في + +395 +00:44:47,840 --> 00:44:50,960 +بنجي حوالين محور هذا و في بنجي حوالين محور هذا + +396 +00:44:50,960 --> 00:44:53,800 +يعني مثلا لو عندي Cantilever + +397 +00:45:13,790 --> 00:45:19,710 +و في عندي force هاي F و في عندي force بهذا الاتجاه + +398 +00:45:19,710 --> 00:45:34,310 +P وهي ال X Axis وهي ال Y Axis وهي ال Z Axis في + +399 +00:45:34,310 --> 00:45:38,650 +بننج نتيجة ال F حوالي ال Z Axis و في بننج حوالي ال + +400 +00:45:38,650 --> 00:45:47,230 +Y Axis فاحد بيسميها two plane bending يعني في عندي + +401 +00:45:47,230 --> 00:45:53,170 +bending في المستويات في ال XY plane و في ال XZ + +402 +00:45:53,170 --> 00:45:58,050 +plane ال + +403 +00:45:58,050 --> 00:46:03,870 +.. ال .. ال moment ال sigma X بيساوي + +404 +00:46:03,870 --> 00:46:17,440 +minus MZY على IZ زائد MY Z على IY هنا تحكي bending + +405 +00:46:17,440 --> 00:46:23,200 +حوالي Z axis وهذه bending حوالين ال Y axis في حالة + +406 +00:46:23,200 --> 00:46:29,820 +المقطع كان مدور الأمور بتكون أسهل بحكي ال sigma + +407 +00:46:29,820 --> 00:46:35,630 +maximum سواء M في C على I و ال moment هي ال .. ال + +408 +00:46:35,630 --> 00:46:39,110 +.. ال victorial sum للمoment حوالين y axis و z + +409 +00:46:39,110 --> 00:46:43,650 +axis هتكون my تربيع زد mz تربيع تحت الجدر تربيعي + +410 +00:46:43,650 --> 00:46:48,330 +في دي عتنين اللي هي .. اللي هي نص قطر الشافت وهذا + +411 +00:46:48,330 --> 00:46:52,850 +moment of .. moment of inertial cross section + +412 +00:46:52,850 --> 00:46:57,010 +فبتصف تنين تلاتين على بي ديتا كيب في my تربيع زد + +413 +00:46:57,010 --> 00:47:04,140 +mz تربيع نص .. نص هذا في حالة المقطع كان مدور نشوف + +414 +00:47:04,140 --> 00:47:17,100 +مثال بيم + +415 +00:47:17,100 --> 00:47:26,800 +O.C اللي هو هذا عندها بيم O.C عليه loading عنده + +416 +00:47:26,800 --> 00:47:32,910 +load موزع بقيمة خمسين pound force لكل انش باتجاه + +417 +00:47:32,910 --> 00:47:40,470 +الـ negative Y وفي عندي load 100 pound باتجاه الـ + +418 +00:47:40,470 --> 00:47:43,910 +negative Z واضح ال load هذا بيعمل bending حوالين + +419 +00:47:43,910 --> 00:47:48,450 +الـ Z axis الـ negative Z وهذا بيعمل bending + +420 +00:47:48,450 --> 00:47:53,490 +حوالين ال positive Y طيب + +421 +00:48:01,570 --> 00:48:07,410 +ال빔 طوله ثمانية انش من هذا الطول ثمانية انش و + +422 +00:48:07,410 --> 00:48:12,410 +مقطع مستطيل تلت اربع انش عرضه في ارتفاع انش و نص + +423 +00:48:12,410 --> 00:48:17,570 +for + +424 +00:48:17,570 --> 00:48:24,250 +the cross section shown للمقطع المبين determine + +425 +00:48:24,250 --> 00:48:27,950 +maximum tensile and compressive bending stresses + +426 +00:48:27,950 --> 00:48:34,670 +and where they act اوجد قيمة ال maximum tensile و + +427 +00:48:34,670 --> 00:48:42,870 +ال maximum compressive stress وين بيأثروا طيب إذا + +428 +00:48:42,870 --> 00:48:47,670 +تتطلع وين ال most critical location بتكون ال moment + +429 +00:48:47,670 --> 00:48:52,890 +maximum بغض النظر هي جاية من due to bending حوالي + +430 +00:48:52,890 --> 00:48:56,270 +Z axis او due to bending حوالي Y axis وين بتكون + +431 +00:48:56,270 --> 00:49:00,990 +maximum ال + +432 +00:49:00,990 --> 00:49:08,250 +bending هنا بتكون عند ال C في المنتصف يعني لو انا + +433 +00:49:08,250 --> 00:49:12,670 +حطيتلك خشبة هنا و ثبتها و حكيتلها هي فين وين ال + +434 +00:49:12,670 --> 00:49:17,870 +bending بتكون عند الطرف هناك هناك بيكون maximum + +435 +00:49:17,870 --> 00:49:25,590 +فالبنك بيكون maximum هنا أنا عندي هاي ال z axis + +436 +00:49:25,590 --> 00:49:34,230 +هاي ال y axis وهاي ال x axis الآن + +437 +00:49:34,230 --> 00:49:38,050 +ال distributed load ال moment اللي دي هو ال + +438 +00:49:38,050 --> 00:49:40,850 +distributed load هتكون اللي هي MZ + +439 +00:49:46,570 --> 00:49:53,210 +MZ قيمتها بحكي عنها هذا بيأثر في النص تقريبا أول + +440 +00:49:53,210 --> 00:50:01,650 +شيء قيمته هتكون خمسين في تمانية صح؟ هتكون خمسين في + +441 +00:50:01,650 --> 00:50:11,350 +تمانية في أربعة صح؟ اذا فاكرين نص WL تربيع في + +442 +00:50:11,350 --> 00:50:11,790 +أربعة + +443 +00:50:17,920 --> 00:50:22,120 +يعني هيكون خمسين + +444 +00:50:22,120 --> 00:50:29,140 +في .. في .. في التمانية 400 في 4000 + +445 +00:50:29,140 --> 00:50:37,960 +ستمائت نيوتن الف ستمائت pound انش هذي موجبة ولا + +446 +00:50:37,960 --> 00:50:41,280 +سلبية؟ سلبية + +447 +00:50:47,150 --> 00:50:51,830 +هذا ممكن أمثله ب one load هنا قيمته خمسين في + +448 +00:50:51,830 --> 00:50:55,670 +تمانية هذا + +449 +00:50:55,670 --> 00:51:04,890 +أكثر من ضال مسافة عشان احصل مموت pound + +450 +00:51:04,890 --> 01:01:14,370 +force inch هذا ال MZ ال + +451 +00:51:14,370 --> 00:51:14,690 +MY + +452 +00:51:23,180 --> 00:51:27,160 +الـ MY مية + +453 +00:51:27,160 --> 00:51:45,760 +في تمانية موجبة صح؟ مية في تمانية أنا + +454 +00:51:45,760 --> 00:51:47,580 +بدي أخد المقطع هذا هيا نجيبه هنا + +455 +00:51:58,460 --> 00:52:04,140 +هذه ال z axis وهذه + +456 +00:52:04,140 --> 00:52:13,540 +ال y axis خلّيني + +457 +00:52:13,540 --> 00:52:18,580 +أتطلع على ال bending due to mz واضح الصيد هذا هكون + +458 +00:52:18,580 --> 00:52:23,560 +under tension صح؟ هي يعني أنا هكون حكيت هي tension + +459 +00:52:23,560 --> 00:52:26,880 +tension tension + +460 +00:52:29,060 --> 00:52:32,120 +و تحت compression بدي أسميه z يعني compression + +461 +00:52:32,120 --> 00:52:43,300 +compression compression يعني z z z ال due لل one + +462 +00:52:43,300 --> 00:52:48,720 +pound صار هتحكوا إيه إيش tension حكوا عندي ال + +463 +00:52:48,720 --> 00:52:54,880 +tension هنا due to y هاي ال tension و هاي ال + +464 +00:52:54,880 --> 00:52:56,060 +tension due to y + +465 +00:52:59,420 --> 00:53:06,200 +هن compression و هن compression + +466 +00:53:06,200 --> 00:53:13,000 +طيب tension مع compression ايش معله موجبة مع سالبة + +467 +00:53:13,000 --> 00:53:21,680 +يعني هدول هدى هحاولوا + +468 +00:53:21,680 --> 00:53:27,920 +يخففوا صح عند هن tension مع compression برضه هتخفف + +469 +00:53:27,920 --> 00:53:28,240 +هن + +470 +00:53:32,100 --> 00:53:40,240 +طيب هنا tension مع tension هتزود معناته هذه و هنا + +471 +00:53:40,240 --> 00:53:44,800 +compression مع compression هتزود + +472 +00:53:44,800 --> 00:53:50,040 +يعني + +473 +00:53:50,040 --> 00:53:57,860 +ممكن احكي sigma ال sigma tension + +474 +00:53:57,860 --> 00:54:10,420 +due to z بسبب MZ لان في شغلتين نحسب IZ هذي point + +475 +00:54:10,420 --> 00:54:17,000 +سبعة خمسة و + +476 +00:54:17,000 --> 00:54:24,400 +هذي واحد و نص انش ال + +477 +00:54:24,400 --> 00:54:28,800 +IZ ده شو يساوي واحد + +478 +00:54:28,800 --> 00:54:39,440 +على اثنا عشر في point سبعة خمسة في واحد و نص تكيب صح + +479 +00:54:39,440 --> 00:54:47,220 +سيقول ايه يعني و ال IY بس واحد على اثنا عشر في واحد و + +480 +00:54:47,220 --> 00:54:56,080 +نص في point سبعة خمسة تكيب كم + +481 +00:55:07,720 --> 00:55:16,720 +والتانية 0.05272 + +482 +00:55:16,720 --> 00:55:25,180 +طيب + +483 +00:55:25,180 --> 00:55:36,770 +المعنى اللي بدي اخد هنا Tension due to MZ هتكون + +484 +00:55:36,770 --> 00:55:43,430 +تساوي MZ في + +485 +00:55:43,430 --> 00:55:49,910 +C على IZ هتكون + +486 +00:55:49,910 --> 00:55:54,390 +تساوي MZ يعني ده كم 1600 + +487 +00:56:01,100 --> 00:56:10,820 +في سبعة خمسة على I زد بنت 2109 + +488 +00:56:30,350 --> 00:56:35,370 +أكبر بتطلع؟ خمس + +489 +00:56:35,370 --> 00:56:43,710 +تلاف وستماية أكبر؟ point + +490 +00:56:43,710 --> 00:56:48,830 +تسعة صح؟ + +491 +00:56:48,830 --> 00:56:56,350 +pound per square inch PSI تسعين point تسعة قربت لأ + +492 +00:56:56,350 --> 00:57:09,340 +لأ ده طيب ال sigma Tension due to Y هتكون MY في + +493 +00:57:09,340 --> 00:57:16,240 +الـ CY على IY هتكون + +494 +00:57:16,240 --> 00:57:21,820 +الـ MY اللي هي 800 في + +495 +00:57:21,820 --> 00:57:24,620 +الـ CY اللي هي 0.75 على 2 اللي هي 0.375 + +496 +00:57:29,770 --> 00:57:40,570 +على ال IY اللي هي point 0 خمسة اتنين سبعة تلاتة + +497 +00:57:40,570 --> 00:57:50,850 +PSI + +498 +00:57:50,850 --> 00:57:56,270 +لاحظين + +499 +00:57:56,270 --> 00:57:56,870 +نفس الرقم + +500 +00:58:00,260 --> 00:58:06,560 +هو أكيد نفس الرقم بس مع التقريبات ماشي مش مشكلة هي + +501 +00:58:06,560 --> 00:58:11,140 +مش بالضروري تطلع نفس الرقم بس صدفة معناه طيب أو هو + +502 +00:58:11,140 --> 00:58:15,900 +ال example هيك مبرمج معناه عند النقطة هذه خلينا + +503 +00:58:15,900 --> 00:58:20,420 +نسمي هذه النقطة a ال + +504 +00:58:20,420 --> 00:58:29,540 +sigma عند a هتكون sigma عند t z زي ال sigma t y + +505 +00:58:32,580 --> 00:58:36,880 +هتكون اللي هي خمسة تلاف وستمائة وتسعين في اتنين اللي + +506 +00:58:36,880 --> 00:58:45,300 +هي كم أحد عشر الف و 198 PSI + +507 +00:58:45,300 --> 00:58:58,660 +وعند B هذه النقطة Sigma B هتكون minus Sigma A يعني + +508 +00:58:58,660 --> 00:59:16,970 +هتكون أحد عشر الف و 197 PSI طيب + +509 +00:59:16,970 --> 00:59:22,210 +خلينا نعمل stress distribution أحاول أعمله بال 3D + +510 +01:00:00,840 --> 01:00:25,260 +due to z due to mz عندي هي intention due + +511 +01:00:25,260 --> 01:00:34,790 +to mz اللي هي خمسة تلاف ناقص خمسة تلاف وستمائة وتسعين و + +512 +01:00:34,790 --> 01:00:40,770 +خمسة تلاف due + +513 +01:00:40,770 --> 01:00:47,990 +to my عندي هاي ال y و + +514 +01:00:47,990 --> 01:00:51,890 +هاي ال z due to my + +515 +01:01:07,640 --> 01:01:19,960 +عندي هنا tension هنا + +516 +01:01:19,960 --> 01:01:27,060 +خمسة تلاف وستمائة وتسعة تمانين خمسة تلاف وستمائة وتسعة + +517 +01:01:27,060 --> 01:01:30,980 +تمانين زي + +518 +01:01:30,980 --> 01:01:31,460 +هيك جاي + +519 +01:01:36,870 --> 01:01:57,110 +هي ناقص خمسة تلاف وستمائة وتسعة وتمانين فواضح + +520 +01:01:57,110 --> 01:02:01,490 +عند هنا قيمة + +521 +01:02:01,490 --> 01:02:09,090 +ال stress due to my ثابتة على كل الخط هذا صح لكن ال + +522 +01:02:09,090 --> 01:02:16,910 +mz ايش امشملها متغيرة قيمة هنا على هذا ال sigma due + +523 +01:02:16,910 --> 01:02:22,450 +to mz ثابت وهنا ايش امشملها متغيرة فواضح ان انا بجمع + +524 +01:02:22,450 --> 01:02:26,890 +هذه مع هذه النقطة هذه وهذه مع هذه بالسالب عن + +525 +01:02:26,890 --> 01:02:30,170 +النقطة هذه فحيصير عنده + +526 +01:02:38,260 --> 01:02:43,060 +بحاول تاخدوه على ال .. على ال .. على ال math lab + +527 +01:02:43,060 --> 01:02:51,180 +بعمل ال grid و خليه يجمع ال stresses يعمل .. هعمل + +528 +01:02:51,180 --> 01:02:56,740 +ال + +529 +01:02:56,740 --> 01:03:02,460 +plant surface هيكون .. هيكون سطح لأن إذا .. لو + +530 +01:03:02,460 --> 01:03:09,430 +أخدم معادلتين خطيتين عشان أبسط هذه معادلة خط مستقيم + +531 +01:03:09,430 --> 01:03:18,210 +وهذه خط مستقيم ثاني وجمعتهم + +532 +01:03:19,940 --> 01:03:25,400 +هيعطيني ايش معادلة جديدة لخط مستقيم جديد لأن + +533 +01:03:25,400 --> 01:03:31,400 +ببساطة هذه هتكون أول رحلة y واحد بالساوي m واحد x + +534 +01:03:31,400 --> 01:03:34,580 +أول + +535 +01:03:34,580 --> 01:03:42,140 +رحلة y y واحد m واحد x زائد b واحد والثاني y اثنين + +536 +01:03:42,140 --> 01:03:47,560 +بالساوي m اثنين x زائد b اثنين اجمعهم مع بعض + +537 +01:03:59,450 --> 01:04:06,250 +يعني خط جديد ب slope جديد ب intercept جديد معناه + +538 +01:04:06,250 --> 01:04:11,070 +هذه أنا بحكي عن surface هيطلع surface بيكونش + +539 +01:04:11,070 --> 01:04:18,520 +surface بيكون maximum هنا كثير ماشي وهنا كثير + +540 +01:04:18,520 --> 01:04:22,320 +بتجاه المعاكس وهنا minimum بتجاه الموجب اللي + +541 +01:04:22,320 --> 01:04:31,320 +بيكون أو إذا كان صفر وهنا برضه minimum هيكون جربوه + +542 +01:04:31,320 --> 01:04:40,280 +على المثل هذا طيب + +543 +01:04:40,280 --> 01:04:45,040 +هذا المطلوب الأول المطلوب الثاني + +544 +01:04:47,580 --> 01:04:50,400 +طبعا ممكن تعوض في المعادلة المباشرة المباشرة اللي + +545 +01:04:50,400 --> 01:04:58,520 +هي sigma X بالساوي minus M Z Y على I Z زائد M Y Z + +546 +01:04:58,520 --> 01:05:08,780 +على I Y يعني لو جربنا نقطة A ال Y + +547 +01:05:08,780 --> 01:05:15,760 +شو ساوي point سبعة خمسة و ال Z + +548 +01:05:20,360 --> 01:05:30,040 +بتساوي point تلاتة سبعة خمسة لما + +549 +01:05:30,040 --> 01:05:36,040 +نحكي sigma X عند A minus و ال MZ أساسا minus minus + +550 +01:05:36,040 --> 01:05:43,360 +minus plus ال MY موجبة و ZR موجبة بقى نتحجمها عند + +551 +01:05:43,360 --> 01:05:45,220 +A and B + +552 +01:05:47,920 --> 01:05:50,400 +الـ moment ما تغيرش و دلوقتي هو minus minus minus + +553 +01:05:50,400 --> 01:05:59,660 +لكن ال Y إيش minus هذه موجبة و ال Z minus بالظبط + +554 +01:05:59,660 --> 01:06:08,700 +فهو نحسب برضه عند C عند النقطة هذه هتكون دي لل MZ + +555 +01:06:08,700 --> 01:06:11,980 +ال MZ minus موجبة + +556 +01:06:14,150 --> 01:06:21,350 +مينوس مينوس بيصير موجبة و ال z إيش امشملها ال y + +557 +01:06:21,350 --> 01:06:30,170 +بتاعتها موجبة هذا ال m y موجبة ال z بتاعتها سالبة + +558 +01:06:30,170 --> 01:06:31,330 +فبتطرح معاها + +559 +01:07:04,740 --> 01:07:10,940 +إذا كان المقطع مدور قطره واحد واربع انش قطره واحد + +560 +01:07:10,940 --> 01:07:12,200 +واربع انش قطره واحد واربع انش قطره واحد واربع انش + +561 +01:07:12,200 --> 01:07:15,300 +قطره واحد واربع انش قطره واحد واربع انش قطره واحد + +562 +01:07:15,300 --> 01:07:17,560 +واربع انش قطره واحد واربع انش قطره واحد واربع انش + +563 +01:07:17,560 --> 01:07:17,780 +قطره واحد واربع انش قطره واحد واربع انش قطره واحد + +564 +01:07:17,780 --> 01:07:18,640 +واربع انش قطره واحد واربع انش قطره واحد واربع انش + +565 +01:07:18,640 --> 01:07:20,540 +قطره واحد واربع انش قطره واحد واربع انش قطره واحد + +566 +01:07:20,540 --> 01:07:25,920 +واربع انش قطره واحد واربع + +567 +01:07:25,920 --> 01:07:29,700 +انش + +568 +01:07:31,940 --> 01:07:39,440 +هذه الـ Z الـ + +569 +01:07:39,440 --> 01:07:47,400 +M حوالين الـ Y كانت موجبة صح؟ يعني هاي .. هاي الـ MY + +570 +01:07:47,400 --> 01:07:52,420 +أكم + +571 +01:07:52,420 --> 01:07:57,280 +كانت قبة هالـ MY؟ تمنميت؟ + +572 +01:07:57,710 --> 01:08:08,970 +pound force inch والـ M زد هتكون + +573 +01:08:08,970 --> 01:08:17,530 +بالسالب يعني هتكون اش زي هيك معناته + +574 +01:08:17,530 --> 01:08:24,310 +net bending moment هذه + +575 +01:08:24,310 --> 01:08:26,850 +M صح؟ + +576 +01:08:30,090 --> 01:08:36,110 +كأنه بيعمل bending حوالين هذا المستوى صح يعني أنا + +577 +01:08:36,110 --> 01:08:41,010 +بحكي حوالين الـ my بيعمل يعني بيكون بيعمل bending + +578 +01:08:41,010 --> 01:08:44,810 +حوالين المستوى هذا يعني بيكون في عندي tension + +579 +01:08:44,810 --> 01:08:50,710 +compression هين كان عندي tension compression + +580 +01:08:50,710 --> 01:08:58,030 +المحاصرة الـ M يعني هيكون عندي هنا منطقة قاعدة + +581 +01:08:58,030 --> 01:09:07,190 +tension وهنا compression يعني هاخد عمودي عليها الـ + +582 +01:09:07,190 --> 01:09:16,330 +M هتكون جزر التربيع لـ M Y تربيع زاد M زي التربيع + +583 +01:09:16,330 --> 01:09:23,990 +هتكون سوى جزر التربيع لـ 800 تربيع زاد 1600 تربيع + +584 +01:09:30,650 --> 01:09:48,690 +أه حسبوها يطلع + +585 +01:09:48,690 --> 01:09:54,330 +ألف سبعمائة دقائق ودقائق point خمس دقائق معاها + +586 +01:09:57,030 --> 01:10:04,270 +Pound Force Inch الزاوية + +587 +01:10:04,270 --> 01:10:10,550 +هذه التي هي + +588 +01:10:10,550 --> 01:10:21,070 +ثيتا سواء تان انفرس للـ MY التي هي تمانمية على + +589 +01:10:21,070 --> 01:10:21,730 +ألف وستمية + +590 +01:10:28,200 --> 01:10:36,120 +ع كام؟ ستة + +591 +01:10:36,120 --> 01:10:45,280 +وعشرين ونص ديجريز يعني هذا ازاي هتكون برضه تاتا + +592 +01:10:45,280 --> 01:10:52,140 +هي ممكن انديه tensile maximum وhand compression + +593 +01:10:52,140 --> 01:10:54,220 +maximum + +594 +01:10:57,080 --> 01:11:04,920 +الـ sigma maximum هتكون M الميزة + +595 +01:11:04,920 --> 01:11:10,240 +الدائرة أنه لو خدت الـ moment حوالين الـ Y axis أو + +596 +01:11:10,240 --> 01:11:13,040 +moment حوالين الـ Z axis أو moment حوالين المحور + +597 +01:11:13,040 --> 01:11:21,240 +هذا نفس الشيء الـ moment of inertia فالـ I هتكون M M + +598 +01:11:21,240 --> 01:11:34,100 +في C على I اللي هي M في D على 2 على Pi على 64 D أُس + +599 +01:11:34,100 --> 01:11:44,560 +4 يعني هتكون 32 M على Pi D تكيب يعني هتكون ساوى 32 + +600 +01:11:44,560 --> 01:11:54,340 +في 1789 على Pi الـ D بيعطيناها واحد وربع إنش + +601 +01:11:58,110 --> 01:12:02,230 +تسعة آلاف وتسعة آلاف وتسعة آلاف وتسعة آلاف وتسعة + +602 +01:12:02,230 --> 01:12:06,510 +آلاف وتسعة آلاف وتسعة آلاف تسعة آلاف تسعة آلاف تسعة آلاف + +603 +01:12:06,510 --> 01:12:07,430 +تسعة آلاف تسعة آلاف تسعة آلاف تسعة آلاف تسعة آلاف + +604 +01:12:07,430 --> 01:12:10,350 +تسعة آلاف تسعة آلاف تسعة آلاف تسعة آلاف تسعة آلاف + +605 +01:12:10,350 --> 01:12:10,650 +تسعة آلاف تسعة آلاف تسعة آلاف تسعة آلاف تسعة آلاف + +606 +01:12:10,650 --> 01:12:19,170 +تسعة آلاف تسعة + +607 +01:12:19,170 --> 01:12:26,850 +آلاف تسعة + +608 +01:12:26,850 --> 01:12:27,890 +آلاف تس + +609 +01:12:51,330 --> 01:13:02,930 +أ تطلع تسعة آلاف؟ و أكام؟ هذا + +610 +01:13:02,930 --> 01:13:08,830 +مدور، هذا بيم تان مختلف تيك ولا عافاك كمان خلصنا + +611 +01:13:08,830 --> 01:13:09,310 +المحاضرة diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/PdQg4WWo-pI_raw.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/PdQg4WWo-pI_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..d5600d10bdc41b6b8910f45d157bbc91eb70c1d2 --- /dev/null +++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/PdQg4WWo-pI_raw.srt @@ -0,0 +1,2524 @@ +1 +00:00:05,770 --> 00:00:09,130 +طيب بسم الله الرحمن الرحيم السلام عليكم ورحمة الله + +2 +00:00:09,130 --> 00:00:12,290 +وبركاته اليوم هنبدأ محاضرة زيدة في مادة تصميم + +3 +00:00:12,290 --> 00:00:16,590 +الألات هتكون chapter اللي هو load and stress + +4 +00:00:16,590 --> 00:00:20,370 +analysis ال chapter هذا فيه مراجعة على مادة + +5 +00:00:20,370 --> 00:00:24,990 +mechanics of material في إضافات أكتر على مستوى على + +6 +00:00:24,990 --> 00:00:28,890 +شوية من ال mechanics of material من حيث الموضوعات + +7 +00:00:28,890 --> 00:00:31,210 +أو من حيث العمق في التحليل + +8 +00:00:34,340 --> 00:00:39,800 +هنبدأ في ال shear و ال .. ال .. ال .. و ال bending + +9 +00:00:39,800 --> 00:00:47,060 +moment diagrams و كيفية حسابه + +10 +00:00:47,060 --> 00:00:54,260 +ان بيه عندى beam فى عندى beam فى support على أطراف + +11 +00:00:54,260 --> 00:00:58,440 +فى support على الطرف الأيصر و support على الطرف + +12 +00:00:58,440 --> 00:01:02,800 +الأيمن المحاور اللى هو عندى X + +13 +00:01:05,840 --> 00:01:15,760 +هذا المحور Y فين دي force F1 تأثر هنا فين F2 و F3 + +14 +00:01:15,760 --> 00:01:22,260 +طبعا هكون فين دي رد فعل R1 وهين + +15 +00:01:22,260 --> 00:01:33,550 +رد فعل R2 لو أخدت section على بعد X1وعملت free + +16 +00:01:33,550 --> 00:01:37,650 +body diagram هيكون + +17 +00:01:37,650 --> 00:01:43,450 +عندهين هاي المسافة X واحد هاي R واحد طبعا هاد ال X + +18 +00:01:43,450 --> 00:01:51,310 +هاد ال Y وعند ال force F واحد هيكون عكس الرد الفعل + +19 +00:01:51,310 --> 00:01:54,870 +shear force V + +20 +00:01:57,260 --> 00:02:03,120 +و بندق moment M كي share force يلا اخدت ال moment + +21 +00:02:03,120 --> 00:02:04,720 +حوالين هذه هتكون عنده + +22 +00:02:08,670 --> 00:02:13,290 +الار واحد هتروح هتكون F واحد في المسافة بتاعتها + +23 +00:02:13,290 --> 00:02:16,350 +زائد + +24 +00:02:16,350 --> 00:02:22,830 +V في X واحد minus M بالساوياش Zero و لو أخرص ماشي + +25 +00:02:22,830 --> 00:02:28,150 +ال force باتجاه ال Y بتكون R واحد بالساوياش F واحد + +26 +00:02:28,150 --> 00:02:32,650 +زائد V الأن + +27 +00:02:32,650 --> 00:02:37,200 +أنا أخدت section هنا على البعد X واحدفكان عندي .. + +28 +00:02:37,200 --> 00:02:41,800 +عندي section عندي shear force V و M لو أخدت + +29 +00:02:41,800 --> 00:02:48,100 +another section على بعد delta + +30 +00:02:48,100 --> 00:02:53,940 +X و + +31 +00:02:53,940 --> 00:03:01,040 +أخدت ال section اللي انطلعته كان + +32 +00:03:01,040 --> 00:03:02,220 +عندي هنا V + +33 +00:03:13,420 --> 00:03:20,620 +وعندي counter clause M هيكون + +34 +00:03:20,620 --> 00:03:25,980 +هنا معاكس له M + +35 +00:03:25,980 --> 00:03:35,960 +زاد delta M و لو حكي هنا عايش V هذه المسافة + +36 +00:03:51,650 --> 00:03:59,350 +الان بعتبر moment موجبة اذا بتحاول تتنى ال beam + +37 +00:03:59,350 --> 00:04:04,470 +لتحت تخلى ال moment موجبة اذا بتحاول تخلى ال beam + +38 +00:04:04,470 --> 00:04:08,330 +بالشكل هذا يعني اذا في عندى moment بالشكل هذا + +39 +00:04:11,600 --> 00:04:15,540 +هي تعتبر positive bending moment positive bending + +40 +00:04:15,540 --> 00:04:22,240 +moment اذا + +41 +00:04:22,240 --> 00:04:25,860 +هو يبين دي هين فهي positive bending moment وبعرف + +42 +00:04:25,860 --> 00:04:28,680 +انا باخد small increment delta X يعني في الحالة + +43 +00:04:28,680 --> 00:04:35,200 +هذه moment هين موجب ولا سلبه سلبه اذا كانت العكس + +44 +00:04:35,200 --> 00:04:39,460 +ايش هتكون هين سلبه هين موجبه ال shear force + +45 +00:04:46,160 --> 00:04:49,340 +هذا positive وهذا negative حالتنا مش هتكون المبينة + +46 +00:04:49,340 --> 00:04:56,100 +عندى هنا negative share negative share بشكل عام + +47 +00:04:56,100 --> 00:04:59,420 +عشان مافكرش كتير فيها بناء على ال convention هذا + +48 +00:04:59,420 --> 00:05:08,040 +إذا باخد section اللى على الشمال أخد الجزء هذا اه + +49 +00:05:08,040 --> 00:05:12,400 +فانا الأصل أخدت ال section أنا عندى هنا أخدت + +50 +00:05:12,400 --> 00:05:21,870 +section هناهذا هتكون ال V عكس مظبوط و ال moment + +51 +00:05:21,870 --> 00:05:30,130 +عكسه ال moment عكس و ال V عكس واضح يعني انا باخد + +52 +00:05:30,130 --> 00:05:34,350 +يا جهة الشمال او الجهة اليامين لو خدت الجهة + +53 +00:05:34,350 --> 00:05:39,990 +اليامين هتكون ال V عكس ال V و ال M عكس ال M بشكل + +54 +00:05:39,990 --> 00:05:40,270 +عام + +55 +00:05:43,270 --> 00:05:47,230 +إذا خدت الفريقة دي جرام من الشمال و كان الشير لتح + +56 +00:05:47,230 --> 00:05:49,870 +هذا positive شير و إذا كانت ال bending moment + +57 +00:05:49,870 --> 00:05:52,850 +counter clockwise بعكس عقارب الساعة بتكون إيش + +58 +00:05:52,850 --> 00:05:58,330 +positive دي + +59 +00:05:58,330 --> 00:06:05,210 +اتأكد أنا positive ولا negative بناخد + +60 +00:06:05,210 --> 00:06:09,530 +زي ما حكينا هاي ال section تكملته هنا هكون V هكون + +61 +00:06:09,530 --> 00:06:17,500 +عكسها Vو ال moment هيكون هاي عكسها و باخد + +62 +00:06:17,500 --> 00:06:22,260 +increment على جواه دلتا X هيكون هاي دي moment و + +63 +00:06:22,260 --> 00:06:26,440 +هاي V هذي الحالة تمثل positive moment و positive + +64 +00:06:26,440 --> 00:06:31,740 +share معناته + +65 +00:06:31,740 --> 00:06:37,680 +بشكل تلقائي بتكون share is positiveإذا كان نازل + +66 +00:06:37,680 --> 00:06:42,040 +لتحت و ماخد ال section على الشمال و ال moment تكون + +67 +00:06:42,040 --> 00:06:50,280 +بعكس عقارب الساعة بعتبرها positive عندى + +68 +00:06:50,280 --> 00:06:54,540 +beam simply supported beam في عندى عليه + +69 +00:06:54,540 --> 00:07:00,820 +distributed load QX يعني load per unit length load + +70 +00:07:00,820 --> 00:07:07,050 +موزع يعني حمل لكل وحدة طولمن ال mechanics of + +71 +00:07:07,050 --> 00:07:14,550 +material كان في عندنا علاقات اللي هي V بيساوي DM + +72 +00:07:14,550 --> 00:07:23,890 +by DX ال shear force بيساوي DM by DX هذا في ال + +73 +00:07:23,890 --> 00:07:30,670 +mechanics of material معناه دي DM بيساوي + +74 +00:07:30,670 --> 00:07:47,050 +V DXلو أخد التكامل بين a و b ما ل mb وهنا من xa ل + +75 +00:07:47,050 --> 00:07:59,790 +xb هكون ان ال mb minus ma بالساوية تكامل vdx من xa + +76 +00:07:59,790 --> 00:08:15,150 +ل xb يعني ال mbبستوى MA زائد تكامل XA ل XB VDX + +77 +00:08:15,150 --> 00:08:22,850 +يعني ال B اللي انتوا شايفينه هنا لاخد + +78 +00:08:22,850 --> 00:08:30,810 +سكشن هذه A نقطة A وهذه نقطة B يعني هذا هكون XA + +79 +00:08:34,850 --> 00:08:44,530 +وها دي إيش XB المعادرة + +80 +00:08:44,530 --> 00:08:49,650 +بتحكي ال moment عند B بتساوي + +81 +00:08:49,650 --> 00:08:56,930 +بين moment عند A زاد المساحة تحت منحنى الشير بين + +82 +00:08:56,930 --> 00:09:04,290 +XA و XBالـ moment عند B سواء الـ moment عند A زاد + +83 +00:09:04,290 --> 00:09:15,270 +المساحة تحت منحنة الـ shear من XA ل XB نفس + +84 +00:09:15,270 --> 00:09:22,010 +الشيء فيه عندنا علاقة اللي هو DV by DX بالسواء الـ + +85 +00:09:22,010 --> 00:09:24,550 +Q الـ Q اللي هو الـ distributed load load لكل + +86 +00:09:24,550 --> 00:09:25,610 +واحدة طول + +87 +00:09:29,210 --> 00:09:40,330 +بسوة Q DX وانا بعمل تكامل بين XA ل XB بين VA ل VB + +88 +00:09:40,330 --> 00:09:50,010 +يعني انا هكون عندي VB minus VA بسوة تكامل Q DX من + +89 +00:09:50,010 --> 00:10:05,040 +XA ل XB يعني VBبالساوية VA زائد تكامل QDX من XA ل + +90 +00:10:05,040 --> 00:10:14,240 +XB يعني ال shear and B ال shear and B بالساوية + +91 +00:10:14,240 --> 00:10:19,900 +shear and A زائد المساحة تحت منحنة ل Q مع ال X بين + +92 +00:10:19,900 --> 00:10:21,940 +XA و XB اللي هي هذه المعادلة + +93 +00:10:31,850 --> 00:10:46,970 +نحل مثال derive the + +94 +00:10:46,970 --> 00:10:51,450 +loading shear force and bending moment diagrams + +95 +00:10:51,450 --> 00:11:01,200 +for the beam shown and beam and رد فعلR1 وR2 هاي + +96 +00:11:01,200 --> 00:11:06,560 +ال X axis هاي ال Y axis فاندي load 200 pound بيأثر + +97 +00:11:06,560 --> 00:11:11,340 +على بعد 4 انش واندي load 100 pound بيأثر على بعد + +98 +00:11:11,340 --> 00:11:16,760 +10 انش و ال beam طوله 20 انش بدنا نحسب ال reaction + +99 +00:11:16,760 --> 00:11:24,480 +forces و ال shear diagram و ال moment diagram اول + +100 +00:11:24,480 --> 00:11:29,420 +خطوة حاولي ادقاشreactions يعني انا اخدت ال moment + +101 +00:11:29,420 --> 00:11:38,500 +حوالين هاي عندى ال X هاي ال Y يعني انا اخدت ال + +102 +00:11:38,500 --> 00:11:43,600 +moment حوالين ال O summation للمoment حوالين ال O + +103 +00:11:43,600 --> 00:11:49,900 +بالساوة 0 و اعتبر عكس عقار السي عاش موجب بالساوة + +104 +00:11:49,900 --> 00:12:02,910 +هكون minus 200 في 4مينوس متين في أربعة مينوس مية + +105 +00:12:02,910 --> 00:12:07,970 +في عشرة زاد + +106 +00:12:07,970 --> 00:12:13,250 +عشرين R اتنين ومنها + +107 +00:12:13,250 --> 00:12:17,790 +R اتنين تطلع + +108 +00:12:17,790 --> 00:12:20,910 +التمنمية + +109 +00:12:22,600 --> 00:12:34,460 +أو الف تونمية على عشرين تسعين تسعين pound بعد + +110 +00:12:34,460 --> 00:12:39,820 +أن باخد summation لل forces باتجاه ال Y الصوت Zero + +111 +00:12:39,820 --> 00:12:44,520 +هكون + +112 +00:12:44,520 --> 00:12:48,840 +دي R واحد ناقص + +113 +00:12:48,840 --> 00:12:50,460 +متين + +114 +00:12:52,380 --> 00:13:03,600 +minus 100 زائد 90 يعني R1 بستوى تلت مية ناقص تسعين + +115 +00:13:03,600 --> 00:13:13,720 +متين و عشرة pound force هيك + +116 +00:13:13,720 --> 00:13:17,800 +أنا عرفت ال reactions هرسم ال shear diagram + +117 +00:13:24,750 --> 00:13:47,050 +و ال moment ده يجرأ حيبدأ + +118 +00:13:47,050 --> 00:13:51,370 +عند R1 يعني عند R1 210 حد من هنا 210 + +119 +00:13:55,650 --> 00:14:07,590 +بعدين هترح ايش؟ متين متين بيضل ايش؟ عشرة هضل + +120 +00:14:07,590 --> 00:14:11,570 +ماشي هترح + +121 +00:14:11,570 --> 00:14:19,770 +مية هي سالب هضل + +122 +00:14:19,770 --> 00:14:26,430 +سالب تسعين وبعدين هطلع كمان تسعينمعناته هو هذا + +123 +00:14:26,430 --> 00:14:30,530 +الشير + +124 +00:14:30,530 --> 00:14:40,410 +ده جرام هذا + +125 +00:14:40,410 --> 00:14:46,030 +الشير ال + +126 +00:14:46,030 --> 00:14:46,670 +bedding moment + +127 +00:14:59,490 --> 00:15:08,250 +الـ moment عند O اشو الساوية عند O سفر هبدأ من سفر + +128 +00:15:08,250 --> 00:15:18,770 +هنحكي هنا اللي هو ال M B بسوء + +129 +00:15:18,770 --> 00:15:28,140 +M A زائد تكامل Vمن XA ل XB هذا الشكل العام لأن + +130 +00:15:28,140 --> 00:15:32,400 +معناته عند النقطة هذه عند النقطة هذه ال moment هي + +131 +00:15:32,400 --> 00:15:36,140 +نحسبها moment هي صفر زاد المساحة هذه يعني هتكون + +132 +00:15:36,140 --> 00:15:41,700 +عشرين متين و عشرة في أربعة تمامية و أربعين هذه + +133 +00:15:41,700 --> 00:15:47,580 +هتتمثل تمثل slope ل ال moment معناته هتكون هذه من + +134 +00:15:47,580 --> 00:15:50,400 +الدرجة الأولى slope constant يعني هتكون متين و + +135 +00:15:50,400 --> 00:15:50,780 +عشرة + +136 +00:15:57,420 --> 00:16:10,380 +تمنين و أربعين مظبوط تمنين و أربعين pound inch ال + +137 +00:16:10,380 --> 00:16:16,260 +moment عند النقطة هذه زاد المساحة هذه المساحة هذه + +138 +00:16:16,260 --> 00:16:21,840 +أكم ستة هذه ستة فعشرة ستة يعني تمنين و أربعين و + +139 +00:16:21,840 --> 00:16:28,450 +ستين تسع مية ال slope هنا شوف كم هو قيمتهأقل اقل + +140 +00:16:28,450 --> 00:16:37,270 +يعني مش هكون اعلى هيكون زي هيك هذا هتكون تسعمية + +141 +00:16:37,270 --> 00:16:44,290 +هنا المساحة ال moment هنا اللي هي تسعمية زي + +142 +00:16:44,290 --> 00:16:48,570 +المساحة هذه المساحة هذه هتكون بالسالف هتكون عندى + +143 +00:16:48,570 --> 00:16:53,070 +هذه عشرة تسعين + +144 +00:16:53,070 --> 00:16:55,930 +في عشرة تسعمية تسعمية نقص تسعمية صفر + +145 +00:17:00,850 --> 00:17:03,130 +فهي كتير مش sign convention انه في ال moment the + +146 +00:17:03,130 --> 00:17:08,430 +ground يكون الموجة لتحت و الساقية للأعلى؟ لأ لأ لأ + +147 +00:17:08,430 --> 00:17:11,490 +انت علي حالة بتعمل convention اللي بدك هي فرضي + +148 +00:17:11,490 --> 00:17:13,910 +يعني بس انت في الآخر نعمل .. احنا عاملين + +149 +00:17:13,910 --> 00:17:17,370 +convention متفق عليه، هيك عالميا أقول أكيد ما + +150 +00:17:17,370 --> 00:17:19,790 +أخدناها كانوا يقولون أنه ال .. sign convention + +151 +00:17:19,790 --> 00:17:22,670 +لتحت الموجة و الساقية لأعلى أنا ماعرفش في أي سياق + +152 +00:17:22,670 --> 00:17:27,510 +ذكرت عشان انا مش ه .. مش هجاوبك اهطب طب مثلا ال + +153 +00:17:27,510 --> 00:17:30,030 +study دي زي ايه؟ تكون ال sheer و ال moment دايما + +154 +00:17:30,030 --> 00:17:33,650 +ساوة و صفرة و داخرة و حنصل على الفرق؟ لأ مش + +155 +00:17:33,650 --> 00:17:37,370 +بالضرورة هتكون ساوة و صفرة، لو عندك cantilever و + +156 +00:17:37,370 --> 00:17:41,010 +عليه مثلا moment عليه في الطرف، فتكون سافرش، في + +157 +00:17:41,010 --> 00:17:46,370 +الحالة، في ال study supported، بيكوناش ساوة و صفرة + +158 +00:17:46,370 --> 00:17:48,430 +و ال sheer برضه زيه؟ + +159 +00:17:54,310 --> 00:17:59,830 +فى الآخر فى الآخر برا حدود ال beam مثلا عندك ال + +160 +00:17:59,830 --> 00:18:06,790 +beam طوله L ال XL بيستوى L plus مافيش هى لا شير + +161 +00:18:06,790 --> 00:18:12,830 +ولا ممد وال X بيستوى Zero minus مافيش هى لا شير + +162 +00:18:12,830 --> 00:18:17,650 +ولا ممد وبالتالى لازم على الأطراف مايكونش عندك + +163 +00:18:17,650 --> 00:18:20,490 +مسفر واضحات؟ + +164 +00:18:23,520 --> 00:18:35,180 +طيب نشوف فيه تكنيك جديد فيه + +165 +00:18:35,180 --> 00:18:44,560 +تكنيك جديد لحساب ال reactions و + +166 +00:18:44,560 --> 00:18:46,800 +حساب ال shear و ال bending moment ال diagrams + +167 +00:18:46,800 --> 00:18:50,820 +هنستخدم + +168 +00:18:50,820 --> 00:18:54,500 +ما يسمى singularity functionsالسيجارات ال + +169 +00:18:54,500 --> 00:18:57,480 +functions تعتمد على ال functions التالة اولش اللي + +170 +00:18:57,480 --> 00:19:00,080 +عندي اللي هو concentrated moment عندي هاي ال X + +171 +00:19:00,080 --> 00:19:12,480 +axis هاي ال X وهذه المسافة A وفي + +172 +00:19:12,480 --> 00:19:18,220 +عندي concentrated moment او + +173 +00:19:18,220 --> 00:19:27,260 +بيسموها unit doubledعندي هدا هتكون X minus A minus + +174 +00:19:27,260 --> 00:19:33,960 +2 هد مش تقص minus 2 X minus A تكتبش minus 2 هد ال + +175 +00:19:33,960 --> 00:19:44,940 +X في الحالة هد X minus A بتساوي by definition Zero + +176 +00:19:44,940 --> 00:19:48,280 +في + +177 +00:19:48,280 --> 00:19:54,120 +كل الأماكناللي بتكونش x بالساوية فيها ايه او + +178 +00:19:54,120 --> 00:19:59,220 +بتساوي plus or minus infinity at x بالساوية ايه + +179 +00:19:59,220 --> 00:20:04,780 +يعني لأن نقطة هذه فقط لها قيمة بتكون لأ بتكون فجأة + +180 +00:20:04,780 --> 00:20:11,600 +بيصير عندى jump في moment سموه unit doublet + +181 +00:20:11,600 --> 00:20:18,110 +infinity مفهوم مفتوحممكن الـ infinity تعتبرها واحد + +182 +00:20:18,110 --> 00:20:21,270 +ممكن تعتبرها مليار ممكن مليون ال infinity قيمة + +183 +00:20:21,270 --> 00:20:26,970 +كبيرة كثير minus infinity قيمة صغيرة كثير فهذه by + +184 +00:20:26,970 --> 00:20:31,390 +definition x minus a بتكون تساوي zero anywhere + +185 +00:20:31,390 --> 00:20:36,250 +except at x بالساوية a بتكون plus or minus + +186 +00:20:36,250 --> 00:20:43,450 +infinity التاني ال function التاني اللي هو x minus + +187 +00:20:43,450 --> 00:20:48,920 +aسالب واحد اللي هو concentrated force او unit + +188 +00:20:48,920 --> 00:20:59,580 +impulse هعندي X هدي A بيصير + +189 +00:20:59,580 --> 00:21:12,080 +فجأة قفزة ال X هين تكامل X minus A بيساوي + +190 +00:21:15,290 --> 00:21:27,670 +x minus a سالب واحد لان x minus a سالب واحد بتساوي + +191 +00:21:27,670 --> 00:21:36,770 +zero عند x not equal a و بتساوي plus infinity عند + +192 +00:21:36,770 --> 00:21:44,980 +x الساوي a و التكاملللـ X minus A سالو واحد DX + +193 +00:21:44,980 --> 00:21:53,760 +بسوا X minus A Zero يعني بتعطينا unit step + +194 +00:21:53,760 --> 00:22:05,980 +function ال unit step function هاندي ال X هي A هدا + +195 +00:22:05,980 --> 00:22:09,880 +X minus A Zero + +196 +00:22:11,740 --> 00:22:21,200 +الـ X minus A Zero اللي هي unit step بتساوي Zero + +197 +00:22:21,200 --> 00:22:31,040 +طالما X أقل من A بتساوي واحد إذا X أكبر أو يساوي A + +198 +00:22:31,040 --> 00:22:41,630 +و التكامل X minus A Zero DX بتساوي X minus Aواحد + +199 +00:22:41,630 --> 00:22:48,590 +بعد + +200 +00:22:48,590 --> 00:22:58,650 +ذلك يأتي الـ RAM طلع يعني RAM طلع عندي + +201 +00:22:58,650 --> 00:23:05,290 +هاي A هذه + +202 +00:23:05,290 --> 00:23:10,250 +X هذه X minus A واحد + +203 +00:23:11,880 --> 00:23:24,940 +ال X minus A واحد بيساوي Zero إذا X أقل من A أو + +204 +00:23:24,940 --> 00:23:32,420 +بتساوي X minus A إذا + +205 +00:23:32,420 --> 00:23:38,860 +X أكبر أوي يساوي A يعني إيش بوصل للدكتور من ال + +206 +00:23:38,860 --> 00:23:42,400 +minus اتنين و من ال minus واحدby definition هذي مش + +207 +00:23:42,400 --> 00:23:48,280 +أس by definition x minus a بتمثل اللي هو moment + +208 +00:23:48,280 --> 00:23:55,560 +مفاجئة مركزة moment مركزة ال x minus a by + +209 +00:23:55,560 --> 00:24:00,600 +definition بتمثل ليه impulse impulse هذي impulse + +210 +00:24:00,600 --> 00:24:09,240 +او اشي مركز هاي impulse مافيش اشي مفروض موزعاكس + +211 +00:24:09,240 --> 00:24:15,040 +ماينوس ايه؟ سويتش اكس ماينوس ايه؟ زيرو؟ سويتش بكون + +212 +00:24:15,040 --> 00:24:19,320 +طالما انا تحت ال a زيرو لما اصلا ال a السويتش + +213 +00:24:19,320 --> 00:24:24,800 +بيشتغل on بيصير الاكس + +214 +00:24:24,800 --> 00:24:31,300 +ماينوس ايه؟ واحد سويتش بس بقلى فيه بقلى فيه ال + +215 +00:24:31,300 --> 00:24:35,000 +load او ال voltage او ال امبير شوية شوية بطلع طلوع + +216 +00:24:40,390 --> 00:24:45,950 +طيب هنستخدم هذه ال mathematical definitions عشان + +217 +00:24:45,950 --> 00:24:51,090 +أحل المسائل + +218 +00:24:51,090 --> 00:24:54,950 +اللي هو ال load و ال shear و ال moment diagram لو + +219 +00:24:54,950 --> 00:24:57,330 +حلل مسألة السابقة رجعنا المسألة السابقة + +220 +00:25:14,820 --> 00:25:18,520 +أحنا في الأساس بشكل عام بيكون عندك Q بيكون عندك Q + +221 +00:25:18,520 --> 00:25:23,040 +بعدين + +222 +00:25:23,040 --> 00:25:30,940 +BGV شير Q يعني load موزع لكل واحدة الطول بعدين BGH + +223 +00:25:30,940 --> 00:25:37,560 +moment ال + +224 +00:25:37,560 --> 00:25:40,420 +ال + +225 +00:25:42,320 --> 00:25:49,120 +هنا حكينا اللي + +226 +00:25:49,120 --> 00:26:06,240 +هي ال V بيستوى DM بي DX و ال Q بيستوى DV بي DX طيب + +227 +00:26:06,240 --> 00:26:12,810 +خلينا نطلع نمثل ال loading بتاعهاالـ loading اللي + +228 +00:26:12,810 --> 00:26:18,250 +هو Q بتساوي + +229 +00:26:18,250 --> 00:26:22,010 +في + +230 +00:26:22,010 --> 00:26:28,570 +عند reaction عند ال O ال X عند O أشو يستوي؟ Zero + +231 +00:26:28,570 --> 00:26:37,090 +هذا يمثل إيه؟ impulse هتكون R واحد في + +232 +00:26:37,090 --> 00:26:44,570 +Xسالب واحد هي x minus a ال a ايش يساوي زي صفر + +233 +00:26:44,570 --> 00:26:53,950 +minus هذا m plus 3 هذا minus 200 minus + +234 +00:26:53,950 --> 00:27:04,350 +200 x minus 4 سالب واحد minus 100 + +235 +00:27:06,930 --> 00:27:17,310 +R2X-10-1R2X + +236 +00:27:17,310 --> 00:27:25,610 +-20-1R2X + +237 +00:27:25,610 --> 00:27:34,550 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X + +238 +00:27:34,550 --> 00:27:34,550 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X + +239 +00:27:34,550 --> 00:27:34,570 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X + +240 +00:27:34,570 --> 00:27:34,570 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X + +241 +00:27:34,570 --> 00:27:36,460 +-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1الـ V + +242 +00:27:36,460 --> 00:27:46,560 +بيستوع تكامل QDX هتكون R1 X + +243 +00:27:46,560 --> 00:27:50,880 +سفر + +244 +00:27:50,880 --> 00:27:54,220 +ناقص + +245 +00:27:54,220 --> 00:28:08,090 +200 X ناقص 4 سفر ناقص 100X ناقص عشرة سفر زاد R + +246 +00:28:08,090 --> 00:28:17,250 +اتنين X ناقص عشرين سفر عندي برضه ال moment ال DM + +247 +00:28:17,250 --> 00:28:26,870 +بيساوي VDX معناه ان ال moment بيساوي تكامل VDX + +248 +00:28:26,870 --> 00:28:30,750 +هكوندي R واحد + +249 +00:28:34,460 --> 00:28:55,280 +X1-200 X-4 1-100 X-10 1 R2 X-20 1 + +250 +00:29:10,110 --> 00:29:17,250 +لما نفحص هذه الـ R1 X ناقص واحد هذه بتكون هي قيمة + +251 +00:29:17,250 --> 00:29:19,630 +فقط عند X الساوية Zero عند X الساوية Zero بتكون هي + +252 +00:29:19,630 --> 00:29:26,930 +قيمة، صح؟ Jump التانية بتكون فقط لها قيمة عند X، + +253 +00:29:26,930 --> 00:29:32,910 +عند X أربعة التالتة عند X الساوية عشرة الرابعة عند + +254 +00:29:32,910 --> 00:29:34,890 +X الساوية عشرين + +255 +00:29:39,770 --> 00:29:44,270 +يعني لو حطيت X Zero minus يعني أقل من Zero شوية + +256 +00:29:44,270 --> 00:29:51,550 +كلهم يكونوا سواء سفر صح؟ + +257 +00:29:51,550 --> 00:29:58,450 +لو أخدت X عشرين plus كله + +258 +00:29:58,450 --> 00:30:03,850 +سفر ال shear + +259 +00:30:09,300 --> 00:30:17,080 +برضه عند x zero minus هذه + +260 +00:30:17,080 --> 00:30:30,000 +unit step function معناته هذه سامعها واحد وهذا + +261 +00:30:30,000 --> 00:30:34,760 +expression اتنين وهذا expression تلاتة وهذا اربعة + +262 +00:30:45,600 --> 00:30:58,900 +عندي سفر وهي عشرة وهي عشرين وهي أربعة هذا + +263 +00:30:58,900 --> 00:31:05,900 +هيكون بساوية .. هيكون R واحد R واحد بيداخل بس ال + +264 +00:31:05,900 --> 00:31:11,500 +function تبعه بدون ال R واحد هذا هتكون إذا X أقل + +265 +00:31:11,500 --> 00:31:16,440 +من سفرسفر اذا اكون سفر هتكون اياش واحد يعني ال + +266 +00:31:16,440 --> 00:31:20,380 +switch هذا بيشتغل على طول بعد ال X بيشتغل على طول + +267 +00:31:20,380 --> 00:31:26,300 +ال + +268 +00:31:26,300 --> 00:31:32,140 +switch بتاع الأولاني هذا اشتغل من بعد سفر ال + +269 +00:31:32,140 --> 00:31:37,360 +switch بتاع التانية اشتغل بعد الأربع هطلع شوية هك + +270 +00:31:37,360 --> 00:31:46,280 +عشان اميزك اشتغل بعدنعم انا بحكي بس على هذه بحكي + +271 +00:31:46,280 --> 00:31:51,120 +على ال switch انا عارف انا بحكي بس على ال X ناقص + +272 +00:31:51,120 --> 00:32:05,220 +أربعة ك switch ال X ناقص عشرة اشتغلت بعد العشرة ال + +273 +00:32:05,220 --> 00:32:09,380 +X ناقص عشرين بعد العشرين + +274 +00:32:19,160 --> 00:32:26,460 +بالنسبة لهدول همسح هذه انا + +275 +00:32:26,460 --> 00:32:32,080 +ماحكيش على الشير بحكي على ال function هذا اصبر + +276 +00:32:32,080 --> 00:32:36,760 +شوية بحكي على ال function هذا الان بدأ اخد ال + +277 +00:32:36,760 --> 00:32:44,620 +functions هدول هي عندي عشرة عشرين وهي عندي أربعة + +278 +00:32:45,990 --> 00:32:50,050 +هذا بيشتغل بعد الـ zero بسلوك واحد بيظل ماشي على + +279 +00:32:50,050 --> 00:32:57,030 +طول هذا + +280 +00:32:57,030 --> 00:33:06,230 +بيشتغل بعد الأربعة هذا + +281 +00:33:06,230 --> 00:33:14,130 +بيشتغل بعد العشرة هذا + +282 +00:33:14,130 --> 00:33:15,650 +بيشتغل بعد الأشترين + +283 +00:33:21,720 --> 00:33:34,060 +ماشي طيب الان + +284 +00:33:34,060 --> 00:33:54,440 +at V and M هكون R 0 at X equal 0 minus و atx عشرين + +285 +00:33:54,440 --> 00:34:02,020 +plus يعني + +286 +00:34:02,020 --> 00:34:15,040 +العواطف هذه and at x equal عشرين plus هكون + +287 +00:34:15,040 --> 00:34:18,160 +and v بالساوة zero بالساوة + +288 +00:34:21,970 --> 00:34:25,330 +هذه بيشتغل بعد السفر موجود بقناته هتكون R واحد في + +289 +00:34:25,330 --> 00:34:36,070 +واحد صح هتكون ايش؟ R واحد و هذا شغال بعد الأربع + +290 +00:34:36,070 --> 00:34:40,790 +ناقص متين في واحد و + +291 +00:34:40,790 --> 00:34:46,650 +هذا شغال بعد العشرة ناقص مية و هذا شغال بعد عشرين + +292 +00:34:46,650 --> 00:34:56,800 +انا حاكي عشرين plusزاد R2 يعني هكون ال R1 زاد R2 + +293 +00:34:56,800 --> 00:35:06,840 +بسوة 300 هذه المعادلة نجيل ال moment برضه at X + +294 +00:35:06,840 --> 00:35:12,360 +بسوة 20 plus هكون + +295 +00:35:12,360 --> 00:35:16,420 +ال moment بسوة Zero بتساوي + +296 +00:35:27,180 --> 00:35:38,280 +الان هضرب في X R1 R1 + +297 +00:35:38,280 --> 00:35:52,440 +في عشرين مظبوط ناقص متين خلينا نشوف كيف اجت هذه ال + +298 +00:35:52,440 --> 00:36:02,860 +X جاء زي هيكهيك جاي وهي ال X عشرين صح لأنها هتكون + +299 +00:36:02,860 --> 00:36:13,360 +عشرين فقر واحد لأن مسلوب يساوي واحد ناقص متين في + +300 +00:36:13,360 --> 00:36:25,980 +عشرين ناقص أربعة ناقص مية في عشرين ناقص عشرةزائد R + +301 +00:36:25,980 --> 00:36:33,140 +اتنين في عشرين ناقص عشرين يعني + +302 +00:36:33,140 --> 00:36:41,740 +انا هكون عندي اربعة عشرين R واحد ناقص عشرين ناقص + +303 +00:36:41,740 --> 00:36:53,560 +اربعة ستاشر في متين ناقص تلت تلاف و متين ناقص الف + +304 +00:36:56,460 --> 00:37:03,300 +زائد صفر يعني R واحد هيكون + +305 +00:37:03,300 --> 00:37:12,420 +ساوي تلت تلاف واربع تلاف ومتين على عشرين متين + +306 +00:37:12,420 --> 00:37:20,180 +وعشرة تطلع متين وعشرة pound عوض في هذه حسين انك + +307 +00:37:20,180 --> 00:37:26,900 +متين وعشرة زاد R اتنينبالساوية تلت مية معناته R + +308 +00:37:26,900 --> 00:37:36,100 +اتنين بالساوية تسعين pound force هيك اوجدنا ال + +309 +00:37:36,100 --> 00:37:42,760 +reactions صارت + +310 +00:37:42,760 --> 00:37:48,060 +معروف R واحد متين و عشرة لان عندما ندرسهم + +311 +00:38:04,100 --> 00:38:15,200 +هي ال shear diagram ال + +312 +00:38:15,200 --> 00:38:23,880 +V من صفر لاربعة بيكون + +313 +00:38:23,880 --> 00:38:33,650 +شغال بس ال R واحد كله طافلهذا كله بيكون طافى هتكون + +314 +00:38:33,650 --> 00:38:45,610 +R واحد ايه اكم 210 لما + +315 +00:38:45,610 --> 00:38:52,670 +بين اربعة و عشرة بيضلوا شغال ال R واحد مظبوط و + +316 +00:38:52,670 --> 00:38:59,490 +بيشتغل ال 200 بس بالسالمهكون متين و عشرة ناقص متين + +317 +00:38:59,490 --> 00:39:06,310 +هي عشرة بين + +318 +00:39:06,310 --> 00:39:14,910 +العشرة والعشرين يكون هذا شغال و هذا شغال و هذا + +319 +00:39:14,910 --> 00:39:19,510 +شغال هطلع حمية بيصير ناقص تسعين + +320 +00:39:28,510 --> 00:39:35,330 +لحد نصل ال 20 او نصل ال 20 بشتغل اللي هو ال R2 + +321 +00:39:35,330 --> 00:39:42,130 +بسفر ليه بالنسبة + +322 +00:39:42,130 --> 00:39:42,610 +ل ال moment + +323 +00:40:07,790 --> 00:40:18,130 +ال moment هتكون تساوي هاخد + +324 +00:40:18,130 --> 00:40:25,830 +x من 0 ل 4 هتكون + +325 +00:40:25,830 --> 00:40:26,930 +R1 في x + +326 +00:40:38,050 --> 00:40:42,430 +اللي هى R واحد اكمل دى اتين + +327 +00:40:42,430 --> 00:40:47,670 +و عشرة يعنى هتكون اتين + +328 +00:40:47,670 --> 00:40:51,990 +و عشرة X من + +329 +00:40:51,990 --> 00:41:00,510 +X بين الأربعة و العشرة بيشتغل + +330 +00:41:00,510 --> 00:41:11,550 +هده و هده صح بيصير عندك R واحد في Xناقص متين في X + +331 +00:41:11,550 --> 00:41:19,590 +ناقص أربعة بين + +332 +00:41:19,590 --> 00:41:32,570 +ال X عشرة و عشرين بيكون هذا شغال R واحد X ناقص + +333 +00:41:32,570 --> 00:41:34,810 +متين + +334 +00:41:36,400 --> 00:41:48,520 +فى x ناقص أربعة ناقص مية فى x ناقص عشرة وهذا لسه + +335 +00:41:48,520 --> 00:41:59,060 +ماشتغلش زائد زيرو صح بيشتغل بعد العشرين لأ نجربه + +336 +00:41:59,060 --> 00:42:08,580 +نجربه احنا حكينا لو x بالساوياربع هتكون ال moment + +337 +00:42:08,580 --> 00:42:14,380 +اكم تمامية و اربعين و اللي لأ هو واضح انه خطيه + +338 +00:42:14,380 --> 00:42:23,800 +لدرجته العامة تمامية و اربعين جربوا + +339 +00:42:23,800 --> 00:42:32,440 +X عشرة هنا هاي تمامية و اربعين ناقص اتين في عشرة + +340 +00:42:34,860 --> 00:42:44,720 +نقص اربعة ستين يعني تمانية و اربعين اه + +341 +00:42:44,720 --> 00:42:52,040 +متين و عشرة يصلي متين و عشرة في عشرة الفين و مية + +342 +00:42:52,040 --> 00:43:00,020 +يعني الفين و مية ناقص متين في ستة ناقص الف و متين + +343 +00:43:00,020 --> 00:43:00,620 +تسعة مية + +344 +00:43:10,060 --> 00:43:20,680 +حطوا هنا x بالساوية عشرين هكون متين و عشرة في + +345 +00:43:20,680 --> 00:43:31,780 +تسعين متين و عشرة في عشرين ناقص متين في ستة عشر + +346 +00:43:31,780 --> 00:43:37,500 +ناقص مية في عشرة اكم تطلع؟ + +347 +00:43:43,340 --> 00:43:48,660 +سيبوها اكيد هتطلع سفر بس تأكدوا سيبوها تطلع سفر + +348 +00:43:48,660 --> 00:43:56,240 +معاكم فانا جبت المعادلات مش رسمته بس باستخدام اللي + +349 +00:43:56,240 --> 00:44:03,860 +هو ال singularity functions طيب + +350 +00:44:03,860 --> 00:44:08,600 +الحل سؤال يعني في تفصيل اكتر + +351 +00:44:20,380 --> 00:44:23,740 +طيب شوف السؤال هذا + +352 +00:44:55,120 --> 00:45:02,600 +طيب عندي beam اللي + +353 +00:45:02,600 --> 00:45:13,140 +هو cantilever يعني fixed عن طرف هذا ال + +354 +00:45:13,140 --> 00:45:18,760 +beam طوله عشرة انش فاندي load موزع قيمته اشرين + +355 +00:45:18,760 --> 00:45:22,740 +pound four per inchبشتغل من بين التلاتة انش + +356 +00:45:22,740 --> 00:45:28,220 +والسبعة انش وفي عندي moment مركزة في نهاية ال beam + +357 +00:45:28,220 --> 00:45:33,320 +اللي هي قيمته اتين و اربعين pound force انش هذا ال + +358 +00:45:33,320 --> 00:45:42,940 +X axis طبعا هذا ال Y axis هذا ال EQ طبعا + +359 +00:45:42,940 --> 00:45:54,020 +هكون عندي هنا M1 عند رد فعل هنار واحد بدا نوجد ال + +360 +00:45:54,020 --> 00:45:58,500 +reactions ونرسم الشير ومدغرام باستخدام ال + +361 +00:45:58,500 --> 00:46:01,840 +singularity functions اول شئ I have to define ال Q + +362 +00:46:01,840 --> 00:46:06,720 +ال Q هكون + +363 +00:46:06,720 --> 00:46:13,560 +الساوية عند X بالساوية Zero عندي concentrated + +364 +00:46:13,560 --> 00:46:18,820 +moment نرجع على الشكل ال by convention هنا + +365 +00:46:21,000 --> 00:46:26,040 +Clockwise موجب Clockwise + +366 +00:46:26,040 --> 00:46:38,880 +هنا معرفه موجب نعم هيكون هذا سالب M واحد X X minus + +367 +00:46:38,880 --> 00:46:48,420 +Zero صح هتكون X سالب اتنين for a moment زائد R + +368 +00:46:48,420 --> 00:46:58,690 +واحدفى x هذه impulse سالب واحد الآن + +369 +00:46:58,690 --> 00:47:08,130 +عندي هنا fixed هكون step function zero لأن خليني + +370 +00:47:08,130 --> 00:47:14,710 +أحكي ل step function ناخد حالة عندي هاي a هذه + +371 +00:47:14,710 --> 00:47:27,690 +x minus aزيرو وهي حالة تانية هذه ايه بي هذه + +372 +00:47:27,690 --> 00:47:36,750 +اكس minus بي زيرو لو طرحت هذا من هذا ايش بيعطيناه + +373 +00:47:36,750 --> 00:47:44,390 +طبعا هذا كل واحد وهنا كل واحد هيسفر هيسير عندي من + +374 +00:47:44,390 --> 00:47:54,050 +هنا لهناهي من A ل B هدا هيكون ال function X minus + +375 +00:47:54,050 --> 00:48:06,490 +A Zero minus X minus B Zero واضحة هدا عندي unit + +376 +00:48:06,490 --> 00:48:10,050 +step function يعني before X سواء A بيكون سواء 0 + +377 +00:48:10,050 --> 00:48:14,710 +سفر بعد الواحد بعد ال A بيكون سواء واحد عندي كمان + +378 +00:48:14,710 --> 00:48:19,060 +another step functionبشتغل عند x يستوى بي يعني بعد + +379 +00:48:19,060 --> 00:48:23,540 +ال x يستوى بي بيصير واحد before بي سفر لو طلعت هذا + +380 +00:48:23,540 --> 00:48:29,780 +من هذا هكون واحد في المنطقة هذه واحد ناقص سفر واحد + +381 +00:48:29,780 --> 00:48:35,060 +في المنطقة هذه واحد ناقص واحد سفر يعني هيسفر بعد + +382 +00:48:35,060 --> 00:48:39,020 +ال بي يعني هكون ال functional شغل on هكون بين ال a + +383 +00:48:48,020 --> 00:48:55,480 +بزايد او ناقص عشرين في + +384 +00:49:09,110 --> 00:49:22,730 +نقص عشرين في X minus تلاتة Zero minus X ناقص سبعة + +385 +00:49:22,730 --> 00:49:26,770 +Zero + +386 +00:49:26,770 --> 00:49:30,730 +عن + +387 +00:49:30,730 --> 00:49:35,030 +الطرف عند ال moment برضه counter clockwise minus + +388 +00:49:35,030 --> 00:49:35,870 +متين و أربعين + +389 +00:49:40,510 --> 00:49:53,550 +فى x minus عشرة سالب اتنين ال + +390 +00:49:53,550 --> 00:49:57,130 +V هي + +391 +00:49:57,130 --> 00:50:09,770 +تكامل ل Q DX مظبوط هكون minus M واحد X سالب واحد + +392 +00:50:10,720 --> 00:50:19,000 +زاد R واحد في X سفر + +393 +00:50:19,000 --> 00:50:26,120 +minus عشرين في + +394 +00:50:26,120 --> 00:50:36,060 +X minus تلاتة واحد زاد + +395 +00:50:36,060 --> 00:50:37,920 +عشرين + +396 +00:50:39,220 --> 00:50:54,260 +فى x minus 7 و 1 ناقص 240 فى x ناقص 10 سالب 1 هذه + +397 +00:50:54,260 --> 00:50:59,480 +ال V ال M سوى + +398 +00:50:59,480 --> 00:51:03,800 +تكامل VDX بتساوي + +399 +00:51:11,220 --> 00:51:18,320 +-M1 X0 R1 + +400 +00:51:18,320 --> 00:51:22,260 +X1 + +401 +00:51:22,260 --> 00:51:31,800 +-20 X-3 2 + +402 +00:51:37,760 --> 00:51:43,720 +زائد عشرين اكس + +403 +00:51:43,720 --> 00:51:48,460 +ناقص سبعة اتنين + +404 +00:51:48,460 --> 00:51:51,800 +ماينوس + +405 +00:51:51,800 --> 00:52:00,680 +متين و اربعين اظن ان نرجع نص التكامل نص هذا على + +406 +00:52:00,680 --> 00:52:05,420 +اتنين هذا على + +407 +00:52:05,420 --> 00:52:05,920 +اتنين + +408 +00:52:08,980 --> 00:52:25,720 +هذه على اتنين ناقص متين واربعين X ناقص عشرة سفر لأ + +409 +00:52:25,720 --> 00:52:34,440 +لأ انت by definition هات by definition انا هنا صار + +410 +00:52:34,440 --> 00:52:38,100 +عندى ارتفعت الدرجة هناك مارتفعتش الدرجة + +411 +00:52:40,770 --> 00:52:57,390 +بالظبط بالظبط مش power صحيح طيب الان عند + +412 +00:52:57,390 --> 00:53:03,690 +x at x بالساوية at x بالساوية zero minus + +413 +00:53:10,660 --> 00:53:16,720 +ولا واحد فيهم بيشتغل طلعوا هذا مش شغال هذا مش شغال + +414 +00:53:16,720 --> 00:53:22,560 +مش شغال ولا واحد فيهم بيشتغل + +415 +00:53:22,560 --> 00:53:37,900 +و add x ساوية عشرة plus كون + +416 +00:53:37,900 --> 00:53:50,290 +هذا شغالهذا شغال، هذا شغال، كله شغالين، صح؟ + +417 +00:53:50,290 --> 00:54:02,830 +طيب معناته نحكي at x بالثاوية عشرة plus ال V + +418 +00:54:02,830 --> 00:54:07,050 +بالثاوية، سفر ششير بالثاوية + +419 +00:54:14,240 --> 00:54:27,360 +هذا هتكون minus ال + +420 +00:54:27,360 --> 00:54:35,140 +moment هذه بتكون لها قيمة عند x بستوى سفر any x + +421 +00:54:35,140 --> 00:54:41,180 +any other x هتكون سفر صح؟ هذا المقال هتكون سفر + +422 +00:54:45,970 --> 00:54:50,450 +وهذا step function او unit step function هتكون + +423 +00:54:50,450 --> 00:54:54,110 +زائد R واحد يعني يعني يعني يعني بعد السفر بيصير له + +424 +00:54:54,110 --> 00:55:03,710 +قيمة صح؟ زائد R واحد و هذا بعد التلاتة هذا بعد + +425 +00:55:03,710 --> 00:55:08,110 +التلاتة بيكون ايش زي هيك هاي X بالثاوض تلاتة هذا X + +426 +00:55:08,110 --> 00:55:16,000 +بالثاوض تلاتة يعني هتكون minus عشرين في عشرةناقص + +427 +00:55:16,000 --> 00:55:29,460 +تلاتة زائد عشرين في عشرة ناقص سبعة هذا + +428 +00:55:29,460 --> 00:55:35,320 +ال X عشرة plus مافيه قيمة فقط عند X يساوي عشرة + +429 +00:55:35,320 --> 00:55:44,380 +بالظبط يعني ناقص Zero يعني هتكون عند R واحد هتساوي + +430 +00:55:48,890 --> 00:55:53,450 +عشريف سبعة مية + +431 +00:55:53,450 --> 00:56:00,950 +و أربعين ناقص عشريف + +432 +00:56:00,950 --> 00:56:10,870 +تلاتة ستين مظبوط + +433 +00:56:10,870 --> 00:56:18,370 +صحيح + +434 +00:56:22,040 --> 00:56:26,960 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +435 +00:56:26,960 --> 00:56:28,700 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +436 +00:56:28,700 --> 00:56:28,740 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +437 +00:56:28,740 --> 00:56:28,780 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +438 +00:56:28,780 --> 00:56:28,880 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +439 +00:56:28,880 --> 00:56:30,340 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +440 +00:56:30,340 --> 00:56:47,300 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +441 +00:56:51,080 --> 00:56:54,420 +واضح؟ هذا step function بتكون قيمته قبل ال X في + +442 +00:56:54,420 --> 00:56:58,960 +السواء Zero و بعد X بيبقى أكبر ال X في السواء Zero + +443 +00:56:58,960 --> 00:57:04,060 +بيكون قيمته واحد واحد في R واحد R واحد صحيح طب + +444 +00:57:04,060 --> 00:57:09,020 +دكتور احنا قلنا انها لعشرة plus هل انه مش هي اخر + +445 +00:57:09,020 --> 00:57:14,140 +ايش هنكون محددين من الزفر للعشرة؟ صحيح يعني هي + +446 +00:57:14,140 --> 00:57:18,420 +منطقة غير قيمة ال step ماشي انت اتلقيت مرة ال بين + +447 +00:57:19,240 --> 00:57:24,540 +عشان هيك .. ما هي .. ما هي الفكرة ان انت ايك عشرة + +448 +00:57:24,540 --> 00:57:29,000 +plus عشرة plus تعتبر point او او او او او او او او + +449 +00:57:29,000 --> 00:57:29,920 +او او او او او او او او او او او او او او او او او + +450 +00:57:29,920 --> 00:57:30,080 +او او او او او او او او او او او او او او او او او + +451 +00:57:30,080 --> 00:57:30,080 +او او او او او او او او او او او او او او او او او + +452 +00:57:30,080 --> 00:57:30,420 +او او او او او او او او او او او او او او او او او + +453 +00:57:30,420 --> 00:57:30,500 +او او او او او او او او او او او او او او او او او + +454 +00:57:30,500 --> 00:57:38,380 +او او + +455 +00:57:38,380 --> 00:57:48,200 +او + +456 +00:57:48,500 --> 00:57:52,340 +في step function step function هذا بيشتغل بيصير on + +457 +00:57:52,340 --> 00:57:57,940 +بعد ال X بالساوية Zero مفتوح على طول شغال على مال + +458 +00:57:57,940 --> 00:58:06,120 +النهاية هذا شغال من عند X الساوية هذا RAM شغال من + +459 +00:58:06,120 --> 00:58:11,620 +عند X الساوية تلاتة وطلع يعني هاي X الساوية تلاتة + +460 +00:58:11,620 --> 00:58:17,860 +شغال على طول هذا شغال بعد X + +461 +00:58:22,190 --> 00:58:26,890 +سبعة هذا concentrated بيشتغل فقط عند x الساعة و + +462 +00:58:26,890 --> 00:58:43,090 +عشرة عند عشرة plus أو عشرة minus بيشتغلش الآن + +463 +00:58:43,090 --> 00:58:45,910 +هنشوفها واحدة واحدة اول خطوة هنجيه ال reactions + +464 +00:58:45,910 --> 00:58:47,770 +هنعوض x الساعة و عشرة + +465 +00:58:50,750 --> 00:58:56,490 +حسبنا ال R واحد ناخد معاملة ال moment برضه at X + +466 +00:58:56,490 --> 00:59:03,110 +بالساوية عشرة plus مافيش P أساسا ال moment شوفوا + +467 +00:59:03,110 --> 00:59:09,970 +الساوية بتساوية + +468 +00:59:09,970 --> 00:59:17,930 +هيا هذا step function بيشتغل بعد السفر معناته M + +469 +00:59:17,930 --> 00:59:18,710 +واحد موجودة + +470 +00:59:22,600 --> 00:59:30,720 +-M1 وهذا طلع شغالة بعد الـ X الساعة و سفر والـ X + +471 +00:59:30,720 --> 00:59:39,680 +قيمتها هكون زائد R1 في عشرة ناقص + +472 +00:59:39,680 --> 00:59:46,260 +هشيعتني ان ناقص عشرة في X + +473 +00:59:53,340 --> 01:00:00,280 +عشرة ناقص تلاتة لكل تربيع + +474 +01:00:00,280 --> 01:00:09,920 +زائد + +475 +01:00:09,920 --> 01:00:13,260 +عشرة + +476 +01:00:16,290 --> 01:00:23,030 +عشرة ناقص سبعة في عشرة ناقص سبعة تربية ناقص سبعة + +477 +01:00:23,030 --> 01:00:26,450 +ما الاتنين عليها نقص نعم ليش سبعة ما الاتنين عليها + +478 +01:00:26,450 --> 01:00:36,550 +نقص اه لو أخدنا الحلقة البسيطة الرقم + +479 +01:00:36,550 --> 01:00:43,890 +عنده هي الرقم اكس السبعة هي رايحة بالشكل هذا لبعض + +480 +01:00:43,890 --> 01:00:44,370 +النهاية + +481 +01:00:46,910 --> 01:00:53,610 +اجمعها ايش هتعطيلي؟ هتعطيلي هذه معادلة Y Y + +482 +01:00:53,610 --> 01:01:01,070 +بالساوية X كإنها التكمل تعالى ايش بالساوية؟ X + +483 +01:01:01,070 --> 01:01:10,150 +تربيع ع اتنين يعني هتكون ايه؟ برابولة رايح لما + +484 +01:01:10,150 --> 01:01:16,450 +لنهاية برابولة رايح لما لنهايةإذا كانت X بيستوي A + +485 +01:01:16,450 --> 01:01:24,850 +أساسا هي ال RAM بتاعتها اللي + +486 +01:01:24,850 --> 01:01:30,470 +صار أنه عندك بدأ الجزء الموجب من ال parabola بعد + +487 +01:01:30,470 --> 01:01:38,130 +ال X بيستوي A يعني هي هذي X بيستوي A واضحة + +488 +01:01:38,130 --> 01:01:45,610 +ليش النصأنا عملت shift سواء كان في ال calculus كان + +489 +01:01:45,610 --> 01:01:48,830 +ممكن اعمل shift باتجاه ال x axis او باتجاه ال y + +490 +01:01:48,830 --> 01:01:53,410 +axis انا عملتله هنا shift زحت ال parabola باتجاه + +491 +01:01:53,410 --> 01:01:58,510 +ال x axis لما حكيت x لما حكيت x ناقص تلاتة الكل + +492 +01:01:58,510 --> 01:02:03,650 +تربيع كأنه parabola مزاح سبع وحدها تجاه ال x axis + +493 +01:02:03,650 --> 01:02:08,310 +نفس ال parabola اللي عند x يستوى zero بس انا بزيحه + +494 +01:02:17,410 --> 01:02:24,470 +طيب وين وصلنا زاد عشرة ناقص متين واربعين ناقص متين + +495 +01:02:24,470 --> 01:02:33,010 +واربعين في صفر ناقص متين واربعين في اياش في صفر + +496 +01:02:33,010 --> 01:02:40,970 +يعني هيكون عنده متين + +497 +01:02:40,970 --> 01:02:45,830 +واربعين هتحط X الساوي لأ صحيح كلام ناقص متين + +498 +01:02:45,830 --> 01:02:50,780 +واربعينفى واحد ليش + +499 +01:02:50,780 --> 01:02:54,520 +لأن هذا unit step function بيشتغل مباشرة بعد ال X + +500 +01:02:54,520 --> 01:02:58,960 +الساوية ايش عشرة فهذا هتكون قيمته واحد ناقص تانية + +501 +01:02:58,960 --> 01:03:06,760 +واربعين فى واحد يعني هيكون عندى ناقص M واحد ال R + +502 +01:03:06,760 --> 01:03:14,020 +واحد أكتر حسبناها تمانين زائد تمانية ناقص + +503 +01:03:15,420 --> 01:03:20,380 +هنا سبعة تربية تسعة وأربعين في عشرة أربعين وتسعين + +504 +01:03:20,380 --> 01:03:30,660 +لاحظ + +505 +01:03:30,660 --> 01:03:39,640 +شوية ناقص أربعين وتسعين زاد عشرة عشرة عشرة + +506 +01:03:39,640 --> 01:03:52,580 +في تسعةتسعين لأ من الصفر عشرة في تسعة تسعين ناقص + +507 +01:03:52,580 --> 01:03:58,100 +متين واربعين بالساوي + +508 +01:03:58,100 --> 01:04:04,920 +ايش سفر ومنها بحسب ال M واحدهجيبها جهة تانية هتكون + +509 +01:04:04,920 --> 01:04:09,120 +تمامية نقص واحد وتسعين زي التسعين نقص اتنين + +510 +01:04:09,120 --> 01:04:17,620 +واربعين اكم تطلع مية وستين pound inch pound force + +511 +01:04:17,620 --> 01:04:23,180 +inch هيك حسبت ال reactions و ال moments اللي + +512 +01:04:23,180 --> 01:04:27,060 +هنخليه نعمل ال share و ال moment diagram + +513 +01:04:35,730 --> 01:04:43,670 +بحكي ال share ال V هيكون يساوي ال + +514 +01:04:43,670 --> 01:04:50,670 +share ال M1 حسبناها كم طلعت؟ مية و ستين مية و ستين + +515 +01:04:50,670 --> 01:04:58,070 +هحكيها عشان M1 بيساوي مية و ستين pound انش وال R1 + +516 +01:04:58,070 --> 01:05:02,990 +ده كم؟ ربما تبقى تمانين تمانين pound + +517 +01:05:14,580 --> 01:05:22,100 +الـ V هتكون + +518 +01:05:22,100 --> 01:05:33,000 +تساوي هد مش هتشتغل غير عند Zero صح هد هتشتغل زاد R + +519 +01:05:33,000 --> 01:05:42,520 +واحد مابعد يعني هناخد فترات بين سفر و تلاتةو تلاتة + +520 +01:05:42,520 --> 01:05:48,640 +و سبعة و سبعة و عشرة هاخد بين سفر و تلاتة X بين + +521 +01:05:48,640 --> 01:05:57,500 +سفر و تلاتة هتكون + +522 +01:05:57,500 --> 01:06:03,040 +هذا + +523 +01:06:03,040 --> 01:06:10,080 +هتكون ايه اش R واحد لان + +524 +01:06:10,080 --> 01:06:18,700 +هذا step functionناقص عشرين في + +525 +01:06:18,700 --> 01:06:34,580 +X ناقص تلاتة زائد عشرين في X ناقص سبعة وهذا + +526 +01:06:34,580 --> 01:06:40,360 +يكون الشغال صح؟ يعني + +527 +01:06:41,960 --> 01:06:45,920 +الان راح عندي تمانين لو حطينا X بالثانوية تلاتة + +528 +01:06:45,920 --> 01:06:46,900 +خلّين نرسم + +529 +01:07:28,550 --> 01:07:33,290 +انت أكد كده مرة عندي ال V من سفر من X من X من سفر + +530 +01:07:33,290 --> 01:07:39,870 +لتلاتة من سفر لتلاتة هذا بيكون الشغال هذا بيشتغل + +531 +01:07:39,870 --> 01:07:51,610 +هذا هذا مش شغال صح هذا لسه ماشتغلتش اه لو حطينا ال + +532 +01:07:51,610 --> 01:07:56,430 +X بالساوية تلاتة او لو حطيت ال X بالساوية + +533 +01:07:59,690 --> 01:08:04,410 +لحظة لحظة، الآن هذه برضه بتكون الشغالة، هذه بتكون + +534 +01:08:04,410 --> 01:08:14,410 +الشغالة، صح؟ هتكون R واحد، ال R واحد عندي أكم؟ + +535 +01:08:14,410 --> 01:08:15,810 +تمانين + +536 +01:08:31,150 --> 01:08:40,230 +طيب X بين التلاتة والسبعة بيكون + +537 +01:08:40,230 --> 01:08:46,930 +شغال ال R واحد واشتغل + +538 +01:08:46,930 --> 01:08:54,250 +X ناقص تلاتة minus عشرين في X ناقص تلاتة هذا لسه + +539 +01:08:54,250 --> 01:08:56,990 +ماشتغلش ولا هذا اشتغل صح؟ + +540 +01:08:59,490 --> 01:09:11,210 +لو حطينا x بالساوية سبعة سبعة + +541 +01:09:11,210 --> 01:09:11,210 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +542 +01:09:11,210 --> 01:09:11,210 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +543 +01:09:11,210 --> 01:09:11,370 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +544 +01:09:11,370 --> 01:09:13,550 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +545 +01:09:13,550 --> 01:09:14,030 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +546 +01:09:14,030 --> 01:09:14,030 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +547 +01:09:14,030 --> 01:09:23,110 +سبعة سبعة سبعة سبعة سبعة سبعة سبعة + +548 +01:09:23,110 --> 01:09:26,170 +سبعة سب + +549 +01:09:27,160 --> 01:09:33,240 +لأ بتبدأ تشغّل يعني هذه ال function هذا مع بعض هذا + +550 +01:09:33,240 --> 01:09:40,280 +شغال هاي أول واحد هذا شغال وهذا شغال لكن هدول لسه + +551 +01:09:40,280 --> 01:09:45,700 +ماشتغلوش مش ماشتغل انه ببدأ عند السبعة بالظبط صفر + +552 +01:09:45,700 --> 01:09:48,720 +يعني قيمته عند السبعة بالظبط معناه مش مفيد احطه + +553 +01:09:48,720 --> 01:09:53,500 +فالشغال فعليا هو بيعطي قيمة ر واحد وعشرين في X + +554 +01:09:53,500 --> 01:09:57,130 +ناقص تلاتةيعني هتكون عند ار واحد لو حكيت ار واحد + +555 +01:09:57,130 --> 01:10:05,070 +عنده تمانين ناقص عشرين في سبعة ناقص تلاتة هتكون + +556 +01:10:05,070 --> 01:10:13,130 +تمانين ناقص تمانين صفر و هي اتطلعوا عشرين في أربعة + +557 +01:10:13,130 --> 01:10:18,710 +ناقص تمانين يعني هتكون ساوى صفر + +558 +01:10:29,050 --> 01:10:33,270 +ما حكيتلك عندي السبعة هذا ببدأ يشتغل بس كيبته سفر + +559 +01:10:33,270 --> 01:10:36,530 +بين + +560 +01:10:36,530 --> 01:10:46,110 +السبعة X بين السبعة والعشرة بيكون عندك R واحد ناقص + +561 +01:10:46,110 --> 01:10:52,670 +عشرين في X ناقص تلاتة زائد عشرين في X ناقص سبعة + +562 +01:11:05,770 --> 01:11:13,110 +أقل مش أقل لو يساوي طيب + +563 +01:11:13,110 --> 01:11:25,200 +لو حطيت X عشرة هكون عندى تمانين ناقص عشرينفي سبعة + +564 +01:11:25,200 --> 01:11:31,440 +زائد عشرين في + +565 +01:11:31,440 --> 01:11:39,860 +إيش؟ في صفر غلطان صح زيك؟ لأ عشرة بدي أحط عشرة + +566 +01:11:39,860 --> 01:11:49,630 +الآن التمانين ناقص عشرين في سبعة زائد عشرينفي + +567 +01:11:49,630 --> 01:11:57,890 +تلاتة يعني هكون تمانين ناقص مية و أربعين زائد ستين + +568 +01:11:57,890 --> 01:12:04,670 +ايش هسير فيه؟ صفر مستيرياش؟ + +569 +01:12:04,670 --> 01:12:17,070 +صفر معناته هكون ماشي زي هيك صح؟ + +570 +01:12:17,070 --> 01:12:19,050 +اه + +571 +01:12:20,480 --> 01:12:28,680 +عند السفر بالظبط عشان اكون دقيق ياد لازم تخلي + +572 +01:12:28,680 --> 01:12:38,920 +السفر لحاله خاطره اكبر اكبر عند السفر plus طيب + +573 +01:12:38,920 --> 01:12:45,960 +هذا بالنسبة لإياش لل share عند السفر لإياش + +574 +01:12:49,980 --> 01:12:56,440 +المشكلة بتقفز فجأة يعني انك عندك zero plus zero + +575 +01:12:56,440 --> 01:13:05,120 +plus فتقفز فجأة فبعتبرها كأنها سفر واضحة؟ + +576 +01:13:05,120 --> 01:13:12,940 +طيب الآن ال moment هناخد + +577 +01:13:12,940 --> 01:13:16,800 +بين X صفر و تلاتة + +578 +01:13:19,630 --> 01:13:24,390 +هي ال moment هذي + +579 +01:13:24,390 --> 01:13:29,870 +هتكون شغلة صح بعد أكبر من السفن سنة تلت هتكون شغلة + +580 +01:13:29,870 --> 01:13:36,310 +minus M واحد زائد + +581 +01:13:36,310 --> 01:13:46,810 +R واحد في X هذي لسه ماشتغلتش و هذي ماشتغلتش و هذي + +582 +01:13:46,810 --> 01:13:54,230 +ماشتغلتشيعني هتكون ال M واحد احنا حسبناها كم مية و + +583 +01:13:54,230 --> 01:14:02,030 +ستين يعني هتكون نقص مية و ستين زاد + +584 +01:14:02,030 --> 01:14:10,530 +تمانين في X تمانين + +585 +01:14:10,530 --> 01:14:11,250 +في تلاتين + +586 +01:14:18,240 --> 01:14:25,920 +حط x بالساوية صفر هتكون ناقص مية و ستين لأن في + +587 +01:14:25,920 --> 01:14:32,520 +عندي concentrated moment ناقص مية + +588 +01:14:32,520 --> 01:14:38,980 +و ستين حط x بالساوية تلاتة تمانين في تلاتة متين و + +589 +01:14:38,980 --> 01:14:43,880 +أربعين ناقص مية و ستين تمانين هذي constant فعلا + +590 +01:14:43,880 --> 01:14:47,860 +هذي هتكون عشر linear يعني هتكون عندهين + +591 +01:14:56,730 --> 01:15:06,710 +بين اكس بين تلاتة و سبعة هيكون ناقص مائة و ستين + +592 +01:15:06,710 --> 01:15:14,190 +زائد تمانين اكس هضيف ايه هاد + +593 +01:15:14,190 --> 01:15:17,930 +شغال هاد شغال وهاد اشتغلت ناقص عشرة + +594 +01:15:23,160 --> 01:15:30,500 +في x ناقص ثلاثة تربيع هذه لسه ما اشتغلت و لا هاد + +595 +01:15:30,500 --> 01:15:34,020 +اشتغلت + +596 +01:15:34,020 --> 01:15:45,140 +حط x بالساوية سبعة هكون دي ناقص مية و ستين زائد + +597 +01:15:45,140 --> 01:15:49,960 +خمس مية و ستين هين + +598 +01:15:49,960 --> 01:15:57,680 +اربع في اربع ستاشفعشرة ناقص مية و ستين أكمل طلع + +599 +01:15:57,680 --> 01:16:01,320 +خمسمية و ستين ناقص مية و ستين أربعمية ناقص مية + +600 +01:16:01,320 --> 01:16:05,940 +تلاتمية متين و أربعين صح؟ + +601 +01:16:05,940 --> 01:16:11,080 +متين و أربعين طبعا هذا إيش لاحظوا الدرجة بتاعتها + +602 +01:16:11,080 --> 01:16:13,120 +فرابولا + +603 +01:16:33,840 --> 01:16:44,060 +بين X سبعة وأقل من عشرة هكون ناقص مية ستين زائد + +604 +01:16:44,060 --> 01:16:49,000 +تمانين X ناقص عشرة في X ناقص تلاتة + +605 +01:16:54,160 --> 01:17:04,040 +في x ناقص ثلاثة هذا شغال شغال شغال زائد عشرة ناقص + +606 +01:17:04,040 --> 01:17:08,200 +ستين زائد + +607 +01:17:08,200 --> 01:17:12,140 +عشرة في + +608 +01:17:12,140 --> 01:17:15,780 +x ناقص + +609 +01:17:15,780 --> 01:17:18,980 +سبعة لكل تربيع + +610 +01:17:30,310 --> 01:17:38,350 +هذه مش هتكون شغالة عند X و الساعة عشرة minus الآن + +611 +01:17:38,350 --> 01:17:45,710 +لو عوّض X عندك X و الساعة عشر هكون ناقص مية و ستين + +612 +01:17:45,710 --> 01:17:52,810 +زائد تمانية ناقص + +613 +01:17:52,810 --> 01:17:57,870 +عشرة في سبعة ناقص سبعين + +614 +01:17:59,690 --> 01:18:06,650 +الان عندي هنا تلاتة تربية ناقص + +615 +01:18:06,650 --> 01:18:11,730 +اربعمية وتسعين زائد + +616 +01:18:11,730 --> 01:18:20,730 +تسعين احسبوها هتكون + +617 +01:18:20,730 --> 01:18:25,250 +تطلعاش + +618 +01:18:25,250 --> 01:18:28,010 +ميتين واربعين + +619 +01:18:30,060 --> 01:18:34,060 +واضح المسافة هذه بالساوية zero انا اتضلتها ماشي + +620 +01:18:34,060 --> 01:18:40,860 +عادل زي هيك وفجأة + +621 +01:18:40,860 --> 01:18:46,160 +نزلت .. نزلتها ال 240 لتحت نزلتها + +622 +01:18:46,160 --> 01:18:55,480 +ال 240 لتحت لو + +623 +01:18:55,480 --> 01:18:56,740 +حطيت مرحلة رابعة + +624 +01:19:01,440 --> 01:19:09,820 +أحط اليساوي بقضيف اللي عليها هذه واضح هى + +625 +01:19:09,820 --> 01:19:12,300 +كمان ال shear moment diagram جبنا الكويتش طبعا + +626 +01:19:12,300 --> 01:19:14,560 +الكويتش هتمكن تعمل ايه اللي هي ال simplification + +627 +01:19:14,560 --> 01:19:17,320 +عندها يعني ارواحها نقص شرين هي تبسطها اكتر + +628 +01:19:20,870 --> 01:19:23,830 +طبعا هذه مزيتها في البرمجة، برمجتها سهلة، انت + +629 +01:19:23,830 --> 01:19:27,610 +تبرمج على ال MATLAB او اي برنامج تاني، سهلة في + +630 +01:19:27,610 --> 01:19:30,610 +البرمجة و إذا اتعود عليها بتعطيلك سرعة، هي بس + +631 +01:19:30,610 --> 01:19:32,550 +تعود، في اي سؤال؟ + diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/i3VwDY5UAc0_raw.json b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/i3VwDY5UAc0_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..c1165fb0aa60ee110bebfbe801b9d93b9d223e44 --- /dev/null +++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/i3VwDY5UAc0_raw.json 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"text": "مثلا مية وتسعة عينا جابولي strength واحد ستين ونص مية وتلاتين عينا جابولي خمس ستين ونص تسعة واربعين عينا جابولي سبعة ستين ونص اربع عينا جابولي سبعين ونص عينتين جابولي واحد سبعين ونص المجموع الف حصات كلها الف لما ندرجع الأرقام هذه تعطينا الف عينا عشان ت characterize لازم احسب اول شي ايش ال mean value", "tokens": [2304, 12984, 15040, 3714, 10632, 34683, 3794, 27884, 6225, 1829, 8315, 10874, 16758, 12610, 1829, 3800, 36764, 24401, 8608, 2655, 9957, 4032, 1863, 9381, 3714, 10632, 34683, 1211, 9307, 9957, 6225, 1829, 8315, 10874, 16758, 12610, 1829, 16490, 2304, 3794, 8608, 2655, 9957, 4032, 1863, 9381, 6055, 3794, 27884, 4032, 9640, 3555, 3615, 9957, 6225, 1829, 8315, 10874, 16758, 12610, 1829, 8608, 3555, 27884, 8608, 2655, 9957, 4032, 1863, 9381, 1975, 25513, 3615, 6225, 1829, 8315, 10874, 16758, 12610, 1829, 8608, 3555, 3615, 9957, 4032, 1863, 9381, 6225, 1829, 29399, 9957, 10874, 16758, 12610, 1829, 36764, 24401, 8608, 3555, 3615, 9957, 4032, 1863, 9381, 9673, 7435, 2304, 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1092.36, "end": 1092.52, "word": " ال", "probability": 0.71240234375}, {"start": 1092.52, "end": 1092.72, "word": " X", "probability": 0.85595703125}, {"start": 1092.72, "end": 1093.12, "word": " mean", "probability": 0.53515625}, {"start": 1093.12, "end": 1095.52, "word": " هتكون", "probability": 0.9392903645833334}, {"start": 1095.52, "end": 1096.08, "word": " واحد", "probability": 0.96826171875}, {"start": 1096.08, "end": 1096.26, "word": " على", "probability": 0.69189453125}, {"start": 1096.26, "end": 1096.62, "word": " N", "probability": 0.6630859375}], "temperature": 1.0}, {"id": 41, "seek": 112523, "start": 1097.77, "end": 1125.23, "text": "الصممش لل FI XI I من واحد لان او مش واحد لان اي اي مختلفة مش واحد لالف ده خليها N small الصممش كان لدي تلات ستين الف وستمية وخمسة وعشرين الان capital الف", "tokens": [6027, 9381, 2304, 2304, 8592, 24976, 479, 40, 1783, 40, 286, 9154, 36764, 24401, 5296, 7649, 1975, 2407, 37893, 36764, 24401, 5296, 7649, 1975, 1829, 1975, 1829, 3714, 46456, 46538, 3660, 37893, 36764, 24401, 5296, 6027, 5172, 11778, 3224, 16490, 20292, 11296, 426, 1359, 31767, 2304, 2304, 8592, 25961, 5296, 16254, 6055, 1211, 9307, 8608, 2655, 9957, 27188, 4032, 14851, 2304, 10632, 4032, 9778, 2304, 3794, 3660, 4032, 3615, 46309, 9957, 2423, 7649, 4238, 27188], "avg_logprob": -0.3474506500520204, "compression_ratio": 1.655844155844156, "no_speech_prob": 0.0, "words": [{"start": 1097.77, "end": 1098.61, "word": "الصممش", "probability": 0.60399169921875}, {"start": 1098.61, "end": 1099.47, "word": " لل", "probability": 0.2393798828125}, {"start": 1099.47, "end": 1100.27, "word": " FI", "probability": 0.41986083984375}, {"start": 1100.27, "end": 1102.01, "word": " XI", "probability": 0.716796875}, {"start": 1102.01, "end": 1103.29, "word": " I", "probability": 0.7529296875}, {"start": 1103.29, "end": 1103.61, "word": " من", "probability": 0.9267578125}, {"start": 1103.61, "end": 1104.15, "word": " واحد", "probability": 0.9462890625}, {"start": 1104.15, "end": 1106.61, "word": " لان", "probability": 0.54547119140625}, {"start": 1106.61, "end": 1110.91, "word": " او", "probability": 0.890625}, {"start": 1110.91, "end": 1112.61, "word": " مش", "probability": 0.71142578125}, {"start": 1112.61, "end": 1112.99, "word": " واحد", "probability": 0.97119140625}, {"start": 1112.99, "end": 1113.41, "word": " لان", "probability": 0.916015625}, {"start": 1113.41, "end": 1114.81, "word": " اي", "probability": 0.619873046875}, {"start": 1114.81, "end": 1115.07, "word": " اي", "probability": 0.575439453125}, {"start": 1115.07, "end": 1115.59, "word": " مختلفة", "probability": 0.80645751953125}, {"start": 1115.59, "end": 1115.71, "word": " مش", "probability": 0.90283203125}, {"start": 1115.71, "end": 1115.97, "word": " واحد", "probability": 0.982177734375}, {"start": 1115.97, "end": 1116.53, "word": " لالف", "probability": 0.8115234375}, {"start": 1116.53, "end": 1118.31, "word": " ده", "probability": 0.8935546875}, {"start": 1118.31, "end": 1118.61, "word": " خليها", "probability": 0.774169921875}, {"start": 1118.61, "end": 1118.77, "word": " N", "probability": 0.275146484375}, {"start": 1118.77, "end": 1119.27, "word": " small", "probability": 0.57275390625}, {"start": 1119.27, "end": 1120.57, "word": " الصممش", "probability": 0.9002685546875}, {"start": 1120.57, "end": 1120.79, "word": " كان", "probability": 0.9541015625}, {"start": 1120.79, "end": 1120.95, "word": " لدي", "probability": 0.330810546875}, {"start": 1120.95, "end": 1121.61, "word": " تلات", "probability": 0.732421875}, {"start": 1121.61, "end": 1121.91, "word": " ستين", "probability": 0.9423828125}, {"start": 1121.91, "end": 1122.23, "word": " الف", "probability": 0.62353515625}, {"start": 1122.23, "end": 1122.81, "word": " وستمية", "probability": 0.7628173828125}, {"start": 1122.81, "end": 1123.21, "word": " وخمسة", "probability": 0.844775390625}, {"start": 1123.21, "end": 1123.69, "word": " وعشرين", "probability": 0.8858642578125}, {"start": 1123.69, "end": 1124.03, "word": " الان", "probability": 0.78173828125}, {"start": 1124.03, "end": 1124.45, "word": " capital", "probability": 0.44921875}, {"start": 1124.45, "end": 1125.23, "word": " الف", "probability": 0.9189453125}], "temperature": 1.0}, {"id": 42, "seek": 115345, "start": 1126.67, "end": 1153.45, "text": "يعني بيطلع ال average عندي تلات ستين بون ستة اتنين خمسة kilo pound per square inch طيب البيانات هذه تمثل sample ولا population؟ ايش عن ال population؟ و ايش عن ال sample؟", "tokens": [40228, 22653, 4724, 1829, 9566, 1211, 3615, 2423, 4274, 18871, 16254, 6055, 1211, 9307, 8608, 2655, 9957, 4724, 11536, 8608, 2655, 3660, 1975, 2655, 1863, 9957, 16490, 2304, 3794, 3660, 21112, 12013, 680, 3732, 7227, 23032, 1829, 3555, 2423, 21292, 7649, 9307, 29538, 46811, 12984, 1211, 6889, 49429, 4415, 22807, 1975, 1829, 8592, 18871, 2423, 4415, 22807, 4032, 1975, 1829, 8592, 18871, 2423, 6889, 22807], "avg_logprob": -0.20348011205593744, "compression_ratio": 1.490909090909091, "no_speech_prob": 0.0, "words": [{"start": 1126.67, "end": 1126.93, "word": "يعني", "probability": 0.947998046875}, {"start": 1126.93, "end": 1127.25, "word": " بيطلع", "probability": 0.92060546875}, {"start": 1127.25, "end": 1127.39, "word": " ال", "probability": 0.97021484375}, {"start": 1127.39, "end": 1127.71, "word": " average", "probability": 0.55908203125}, {"start": 1127.71, "end": 1128.01, "word": " عندي", "probability": 0.6114501953125}, {"start": 1128.01, "end": 1128.31, "word": " تلات", "probability": 0.8068033854166666}, {"start": 1128.31, "end": 1128.81, "word": " ستين", "probability": 0.9724934895833334}, {"start": 1128.81, "end": 1129.77, "word": " بون", "probability": 0.25286865234375}, {"start": 1129.77, "end": 1130.35, "word": " ستة", "probability": 0.97509765625}, {"start": 1130.35, "end": 1130.81, "word": " اتنين", "probability": 0.90576171875}, {"start": 1130.81, "end": 1131.55, "word": " خمسة", "probability": 0.9591064453125}, {"start": 1131.55, "end": 1132.05, "word": " kilo", "probability": 0.218994140625}, {"start": 1132.05, "end": 1132.63, "word": " pound", "probability": 0.9287109375}, {"start": 1132.63, "end": 1133.01, "word": " per", "probability": 0.9521484375}, {"start": 1133.01, "end": 1133.37, "word": " square", "probability": 0.89111328125}, {"start": 1133.37, "end": 1133.85, "word": " inch", "probability": 0.97900390625}, {"start": 1133.85, "end": 1139.45, "word": " طيب", "probability": 0.9119466145833334}, {"start": 1139.45, "end": 1141.85, "word": " البيانات", "probability": 0.904052734375}, {"start": 1141.85, "end": 1142.33, "word": " هذه", "probability": 0.7294921875}, {"start": 1142.33, "end": 1144.23, "word": " تمثل", "probability": 0.9609375}, {"start": 1144.23, "end": 1145.11, "word": " sample", "probability": 0.83837890625}, {"start": 1145.11, "end": 1146.05, "word": " ولا", "probability": 0.8955078125}, {"start": 1146.05, "end": 1148.37, "word": " population؟", "probability": 0.718505859375}, {"start": 1148.37, "end": 1150.63, "word": " ايش", "probability": 0.81689453125}, {"start": 1150.63, "end": 1150.79, "word": " عن", "probability": 0.90234375}, {"start": 1150.79, "end": 1150.87, "word": " ال", "probability": 0.87841796875}, {"start": 1150.87, "end": 1152.41, "word": " population؟", "probability": 0.86962890625}, {"start": 1152.41, "end": 1152.63, "word": " و", "probability": 0.6826171875}, {"start": 1152.63, "end": 1152.69, "word": " ايش", "probability": 0.783935546875}, {"start": 1152.69, "end": 1152.81, "word": " عن", "probability": 0.99462890625}, {"start": 1152.81, "end": 1152.91, "word": " ال", "probability": 0.9765625}, {"start": 1152.91, "end": 1153.45, "word": " sample؟", "probability": 0.910400390625}], "temperature": 1.0}, {"id": 43, "seek": 117570, "start": 1155.06, "end": 1175.7, "text": "السبب اللي عين واحدة انه يعني مثلا لو أنا درست مرضى السكر كل المصابين بالسكر في قطاع غزة أخدت فحص السكر لكل مرضى السكر في قطاع غزة population طب أنا هالمنطقة أو عملي أنه أفحص كل قطاع غزة", "tokens": [6027, 3794, 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"word": " واحدة", "probability": 0.6703694661458334}, {"start": 1156.28, "end": 1156.7, "word": " انه", "probability": 0.880126953125}, {"start": 1156.7, "end": 1158.88, "word": " يعني", "probability": 0.636962890625}, {"start": 1158.88, "end": 1159.26, "word": " مثلا", "probability": 0.9248046875}, {"start": 1159.26, "end": 1159.4, "word": " لو", "probability": 0.458984375}, {"start": 1159.4, "end": 1159.56, "word": " أنا", "probability": 0.6005859375}, {"start": 1159.56, "end": 1160.08, "word": " درست", "probability": 0.8943684895833334}, {"start": 1160.08, "end": 1161.8, "word": " مرضى", "probability": 0.990234375}, {"start": 1161.8, "end": 1162.26, "word": " السكر", "probability": 0.876953125}, {"start": 1162.26, "end": 1162.64, "word": " كل", "probability": 0.701171875}, {"start": 1162.64, "end": 1163.02, "word": " المصابين", "probability": 0.8876953125}, {"start": 1163.02, "end": 1163.56, "word": " بالسكر", "probability": 0.8448893229166666}, {"start": 1163.56, "end": 1163.78, 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"word": " strength", "probability": 0.98583984375}, {"start": 1950.32, "end": 1950.48, "word": " اللي", "probability": 0.614501953125}, {"start": 1950.48, "end": 1950.7, "word": " سواء", "probability": 0.53564453125}, {"start": 1950.7, "end": 1950.96, "word": " مية", "probability": 0.5806884765625}, {"start": 1950.96, "end": 1951.2, "word": " kilo", "probability": 0.57275390625}, {"start": 1951.2, "end": 1952.0, "word": " pound", "probability": 0.9560546875}, {"start": 1952.0, "end": 1952.26, "word": " per", "probability": 0.94921875}, {"start": 1952.26, "end": 1952.58, "word": " square", "probability": 0.8369140625}, {"start": 1952.58, "end": 1952.96, "word": " inch", "probability": 0.97802734375}, {"start": 1952.96, "end": 1954.14, "word": " معناته", "probability": 0.8313802083333334}, {"start": 1954.14, "end": 1955.1, "word": " تسعة", "probability": 0.9186197916666666}, {"start": 1955.1, "end": 1955.42, "word": " وتسعين", "probability": 0.8680419921875}, {"start": 1955.42, "end": 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عبارة عن process بعمل plastic deformation على ال material بهدف رفع ال strength بتاعتها by strain hardening effect اذا فاكدين ال strain hardening effect بيزود عدد ال dislocations في المادة و بتكون مخربشة مع بعض فبصير المقاومة", "tokens": [6027, 3554, 1364, 39896, 6225, 3555, 9640, 3660, 18871, 1399, 4724, 25957, 1211, 5900, 34364, 15844, 2423, 2527, 39627, 3215, 5172, 12602, 5172, 3615, 2423, 3800, 39894, 995, 34268, 11296, 538, 14249, 1152, 4559, 1802, 1975, 15730, 6156, 995, 4117, 3215, 9957, 2423, 14249, 1152, 4559, 1802, 4724, 1829, 11622, 23328, 6225, 3215, 3215, 2423, 39025, 763, 8978, 9673, 18513, 3660, 4032, 39894, 30544, 3714, 9778, 25513, 8592, 3660, 20449, 45030, 11242, 6156, 3555, 9381, 13546, 9673, 4587, 995, 20498, 3660], "avg_logprob": -0.12576220111876, "compression_ratio": 1.4889867841409692, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1982.22, "end": 1982.52, "word": "ال", "probability": 0.8896484375}, {"start": 1982.52, "end": 1982.9, "word": " cold", 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"probability": 0.916015625}, {"start": 1997.84, "end": 1998.2, "word": " hardening", "probability": 0.952392578125}, {"start": 1998.2, "end": 1998.82, "word": " effect", "probability": 0.95263671875}, {"start": 1998.82, "end": 2000.7, "word": " بيزود", "probability": 0.9154052734375}, {"start": 2000.7, "end": 2002.02, "word": " عدد", "probability": 0.9864908854166666}, {"start": 2002.02, "end": 2002.32, "word": " ال", "probability": 0.9716796875}, {"start": 2002.32, "end": 2003.18, "word": " dislocations", "probability": 0.72021484375}, {"start": 2003.18, "end": 2003.72, "word": " في", "probability": 0.6513671875}, {"start": 2003.72, "end": 2004.4, "word": " المادة", "probability": 0.99072265625}, {"start": 2004.4, "end": 2005.1, "word": " و", "probability": 0.68359375}, {"start": 2005.1, "end": 2005.6, "word": " بتكون", "probability": 0.907958984375}, {"start": 2005.6, "end": 2006.3, "word": " مخربشة", "probability": 0.91005859375}, {"start": 2006.3, "end": 2006.54, "word": " مع", 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Iron والـ Cast Steel الـ Nonferrous metals هي البعادل اللي مافيه حديده اللي هي الألمنيوم المنجانيستي تلاتة مش كله طبعا الذاكرة تلاتة بس هم أكتر", "tokens": [6027, 39184, 22668, 11019, 13720, 16070, 39184, 5153, 349, 794, 293, 426, 378, 1040, 11019, 13720, 16070, 39184, 5552, 11019, 13720, 16070, 39184, 7190, 712, 11019, 13720, 16070, 39184, 1057, 939, 11019, 13720, 16070, 39184, 11019, 26038, 2423, 39184, 8774, 612, 21189, 22548, 39896, 29739, 3615, 18513, 1211, 13672, 1829, 19446, 41185, 3224, 11331, 16254, 3215, 3224, 13672, 1829, 39896, 16247, 19528, 22653, 20498, 9673, 1863, 7435, 7649, 1829, 14851, 1829, 6055, 1211, 9307, 3660, 37893, 28242, 3224, 23032, 3555, 3615, 995, 32545, 995, 4117, 25720, 6055, 1211, 9307, 3660, 4724, 3794, 8032, 2304, 5551, 4117, 2655, 2288], "avg_logprob": -0.3598484902670889, "compression_ratio": 1.7230046948356808, "no_speech_prob": 0.0, "words": [{"start": 3181.05, "end": 3181.33, "word": "الـ", "probability": 0.437255859375}, {"start": 3181.33, "end": 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ال filler ماتيها عبارة عن بتكون شبكة fibers ال filler هي اللى هى بتكون مثلا فى حالة ال fiberglass اللى هو اللى هو الياف الزجاجية الياف الزجاجية لحالها هشة بتتفتفت", "tokens": [45340, 29245, 23328, 43242, 8315, 4386, 9673, 29245, 23328, 4386, 28239, 45367, 13672, 7578, 43242, 8315, 3714, 29245, 23328, 6156, 2655, 39319, 6156, 7578, 32771, 11622, 1211, 31439, 28239, 45367, 23758, 2423, 34676, 3714, 9307, 1829, 11296, 6225, 3555, 9640, 3660, 18871, 39894, 30544, 13412, 3555, 4117, 3660, 25252, 2423, 34676, 39896, 13672, 7578, 8032, 7578, 39894, 30544, 50113, 15040, 6156, 7578, 11331, 6027, 3660, 2423, 12874, 28851, 13672, 7578, 31439, 13672, 7578, 31439, 45595, 31845, 6024, 110, 7435, 26108, 10632, 45595, 31845, 6024, 110, 7435, 26108, 10632, 5296, 5016, 6027, 11296, 8032, 8592, 3660, 39894, 2655, 5172, 2655, 5172, 2655], "avg_logprob": -0.24080882922691457, "compression_ratio": 2.0833333333333335, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3519.48, "end": 3520.16, 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00:00:21,210 +concentration كيف ال stress برتفع عن مناطق ال + +5 +00:00:21,210 --> 00:00:25,750 +discontinuities برتفع عن ال nominal value بيصير ان + +6 +00:00:25,750 --> 00:00:29,830 +التركيز إجهادي اليوم هنحل مجموعة من الأمثلة عشان + +7 +00:00:29,830 --> 00:00:31,010 +نوضح الفكرة + +8 +00:00:33,500 --> 00:00:39,840 +المثال أمامكم في عندى thin plate عرض + +9 +00:00:39,840 --> 00:00:45,920 +من هنا اربعين ملي من هنا اربع تلاتين ملي في ثقب + +10 +00:00:45,920 --> 00:00:53,580 +هنا ال plate ثمكته اربع ملي وفي load ميت كيلو + +11 +00:00:53,580 --> 00:00:58,460 +نيوتن في فلت عندى هنا radiusها واحد ملي متر + +12 +00:01:06,590 --> 00:01:09,790 +it is desired to drill a hole through the center + +13 +00:01:09,790 --> 00:01:13,550 +of the forty millimeter face of the plate to allow + +14 +00:01:13,550 --> 00:01:21,210 +a cable to pass through it المطلوب نفتح ثقوب في + +15 +00:01:21,210 --> 00:01:29,570 +المنطقة هذه عشان أدخل منه cable a + +16 +00:01:29,570 --> 00:01:32,150 +four millimeter hole is sufficient for the cable + +17 +00:01:32,150 --> 00:01:43,400 +to fit ثقوب كترةأربعة ملي كافي لدخول الكابل بق + +18 +00:01:43,400 --> 00:01:46,800 +an eight millimeter drill is readily available لكن + +19 +00:01:46,800 --> 00:01:51,980 +القطعة هذه فيها already ثقوب موجود تمانية ملي فيها + +20 +00:01:51,980 --> 00:01:54,480 +already ثقوب موجود تمانية ملي لكن مطلوب أوي بكفي + +21 +00:01:54,480 --> 00:01:59,160 +أربعة ملي لكن هي في ثقوب موجود قطره تمانية ملي + +22 +00:02:03,640 --> 00:02:07,340 +will a crack be more likely to initiate at the + +23 +00:02:07,340 --> 00:02:11,820 +larger hole the smaller hole or at the fillet اذا + +24 +00:02:11,820 --> 00:02:18,080 +حيصير failure او يصير بداية تشقق هل حيصير عند ال + +25 +00:02:18,080 --> 00:02:24,020 +hole قطر أربع ملي او ال hole قطر تمانية ملي او عند + +26 +00:02:24,020 --> 00:02:29,040 +ال fillet خلّيني فحص عليه check + +27 +00:02:35,240 --> 00:02:40,920 +at the hall هذه + +28 +00:02:40,920 --> 00:02:46,760 +منطقة ال hall لو + +29 +00:02:46,760 --> 00:02:47,620 +أخدت section هنا + +30 +00:03:10,400 --> 00:03:16,040 +هذه thickness اللي + +31 +00:03:16,040 --> 00:03:20,760 +هي أربعة ملي متر هذه + +32 +00:03:20,760 --> 00:03:29,180 +كلها عرضها أربعين وهذه + +33 +00:03:29,180 --> 00:03:32,860 +تعتمد يا أربعة يا تمانية صح يعني المرة لو كنت + +34 +00:03:32,860 --> 00:03:37,760 +كتبون أربعة يعني المرة اللي هنشتغل على أربعة و + +35 +00:03:37,760 --> 00:03:40,600 +المرة اللي هنشتغل على تمانيةمرة على أربعة و مرة + +36 +00:03:40,600 --> 00:03:44,940 +على تمانية يعني عندي أربعة و تمانية عندي تمانية + +37 +00:03:44,940 --> 00:03:50,000 +خلّيني + +38 +00:03:50,000 --> 00:04:03,540 +أحكي ال هو واحد four millimeter hole هتكون + +39 +00:04:03,540 --> 00:04:06,300 +مساحة المقطع الصافي ال a + +40 +00:04:11,330 --> 00:04:19,510 +اللي هو هتكون أربعة في أربعين ناقص + +41 +00:04:19,510 --> 00:04:27,870 +أربعة في أربعة صح؟ يعني + +42 +00:04:27,870 --> 00:04:31,650 +هيكون مية و ستين ناقص ستاش مية و أربعة و أربعين + +43 +00:04:31,650 --> 00:04:32,970 +millimeter square + +44 +00:04:39,770 --> 00:04:43,050 +وانا بحسب ان نمو ال stress في المنطقة هذه ال sigma + +45 +00:04:43,050 --> 00:04:48,710 +o هتكون + +46 +00:04:48,710 --> 00:04:56,230 +الساعة اللي هي عشر تلاف نيوتن ع المساحة اللي هي + +47 +00:04:56,230 --> 00:05:01,390 +مية و أربع و أربعين تطنيها بالميجا باسكال هذا نحسب + +48 +00:05:01,390 --> 00:05:01,750 +ورايا + +49 +00:05:07,070 --> 00:05:10,550 +طيب الان نتيجة الثقوب في عندي تركيز إجهاد في عندي + +50 +00:05:10,550 --> 00:05:19,570 +stress concentration هروح ع بندكس A 15 1 6 + +51 +00:05:19,570 --> 00:05:24,710 +69 + +52 +00:05:24,710 --> 00:05:27,730 +.4 + +53 +00:05:27,730 --> 00:05:31,210 +ميجا + +54 +00:05:31,210 --> 00:05:31,730 +بسكال + +55 +00:05:37,090 --> 00:05:40,830 +طيب انا في عندى stress concentration هروح على + +56 +00:05:40,830 --> 00:05:45,090 +appendix A خمساش واحد في اخر الكتاب انا ماخد + +57 +00:05:45,090 --> 00:05:54,850 +الصورة جيبها من الكتاب appendix A ال thickness + +58 +00:05:54,850 --> 00:05:58,250 +اتنين + +59 +00:05:58,250 --> 00:06:05,190 +millimeter صحيح يعني هي دى thickness يعني عفرض + +60 +00:06:05,190 --> 00:06:11,630 +كانتاربع مليه خلي نكملها بتأثرش + +61 +00:06:11,630 --> 00:06:21,590 +على طبيعة المثلة بدها نخليها اتنين مين نخليها هنا + +62 +00:06:21,590 --> 00:06:28,130 +هتكون هنقسم على اتنين صح هنا + +63 +00:06:28,130 --> 00:06:36,560 +هتكون اربع اربع هنا عندي اتنيناين اتنين اتنين + +64 +00:06:36,560 --> 00:06:44,180 +وسبعين وعندي + +65 +00:06:44,180 --> 00:06:48,360 +هنا على + +66 +00:06:48,360 --> 00:06:53,660 +اتنين وسبعين ماجي + +67 +00:06:53,660 --> 00:06:54,740 +باسكار + +68 +00:07:00,570 --> 00:07:04,070 +هذا ال sigma هو فكان فينا stress concentration + +69 +00:07:04,070 --> 00:07:12,010 +بروح على pendex A خمستاش واحد + +70 +00:07:12,010 --> 00:07:19,470 +واحد دي + +71 +00:07:19,470 --> 00:07:26,950 +هي دي دي على W اللي + +72 +00:07:26,950 --> 00:07:27,730 +هي أربعة + +73 +00:07:30,240 --> 00:07:51,020 +w التي هي أربعين صح point one high point one منها + +74 +00:07:51,020 --> 00:07:55,800 +بطل الكاتي يعني + +75 +00:07:55,800 --> 00:08:04,030 +تقريبايعني اتنين point سبعة اقل شوية الكاتي + +76 +00:08:04,030 --> 00:08:13,450 +معناه في ال sigma max هتكون كاتي في ال sigma o + +77 +00:08:13,450 --> 00:08:19,470 +يعني اتنين point سبعة في مية و تمانية تلاتين point + +78 +00:08:19,470 --> 00:08:19,990 +تسعة + +79 +00:08:33,990 --> 00:08:38,790 +طيب هاد ال case الأولى ال case التانية اللي وعندي + +80 +00:08:38,790 --> 00:08:46,190 +eight millimeter hole منها تطلع البحث بال area + +81 +00:08:46,190 --> 00:08:53,130 +اللي هتكون ال area نفس الأشياء مش نفسه مش هتكون + +82 +00:08:53,130 --> 00:09:01,810 +اتنين في اربعين ناقص اتنين في تمانية يعني + +83 +00:09:01,810 --> 00:09:02,910 +اربع و ستين + +84 +00:09:09,130 --> 00:09:14,010 +الـ Sigma O هتكون + +85 +00:09:14,010 --> 00:09:18,470 +عشر تلاف على + +86 +00:09:18,470 --> 00:09:32,570 +أربعة ستين اللي + +87 +00:09:32,570 --> 00:09:38,700 +أنا بدي أحسب ال Sigma O هي أكبر من هذهلكن مش هتصرف + +88 +00:09:38,700 --> 00:09:42,400 +بدي اشوف ال stress concentration اللي انا عندي A + +89 +00:09:42,400 --> 00:09:52,100 +خمستاش واحد ال D على W تمانية على أربعين اللي هي + +90 +00:09:52,100 --> 00:10:04,000 +point اتنين و انا بطلع ال KT اتنين + +91 +00:10:04,000 --> 00:10:04,780 +point خمسة + +92 +00:10:07,800 --> 00:10:12,120 +معناته ال signal max هيكون + +93 +00:10:12,120 --> 00:10:19,460 +اتنين و نص في مية و ستة و خمسين point اتنين خمسة + +94 +00:10:19,460 --> 00:10:24,700 +تلت + +95 +00:10:24,700 --> 00:10:25,560 +مية وتسعين + +96 +00:10:36,880 --> 00:10:40,240 +يعني ال software mean critical اكتر التمانية ملي + +97 +00:10:40,240 --> 00:10:47,960 +ولا الأربعة ملي تمانية + +98 +00:10:47,960 --> 00:10:55,540 +مو ال critical معناته من ناحية stress الأربعة ملي + +99 +00:10:55,540 --> 00:11:02,260 +افضل من التمانية ملي الأن بدنا نفحص الحالة اللي هي + +100 +00:11:02,260 --> 00:11:02,940 +عند الفيلت + +101 +00:11:06,710 --> 00:11:15,370 +الـ fillet اللي هي case 3 and check at + +102 +00:11:15,370 --> 00:11:22,230 +the fillet هنروح + +103 +00:11:22,230 --> 00:11:29,250 +لل fillet طبعا ان ال fillet هنا ال cross section + +104 +00:11:29,250 --> 00:11:33,250 +اربعة تلاتين في اتنين معناته ال sigma ال nominal + +105 +00:11:37,380 --> 00:11:42,520 +بتساوي اللي هي عشر تلاف على + +106 +00:11:42,520 --> 00:11:57,260 +اربعة و تلاتين في اتنين مية + +107 +00:11:57,260 --> 00:12:08,040 +سبعة و اربعين غلط لأنه هذه صح مية سبعة و اربعينمية + +108 +00:12:08,040 --> 00:12:14,640 +و سبعة و اربعين ميجا + +109 +00:12:14,640 --> 00:12:29,360 +باسكال طيب في عندي stress concentration طيب + +110 +00:12:29,360 --> 00:12:33,120 +هنروح + +111 +00:12:33,120 --> 00:12:34,300 +على appendix + +112 +00:12:37,840 --> 00:12:46,400 +ا خمستاش خمسة ا خمستاش خمسة + +113 +00:12:46,400 --> 00:12:57,440 +بالزمن ا ر على ا ر على دي ا ر على دي بتساوي الارن + +114 +00:12:57,440 --> 00:13:01,540 +دي الفيلت واحد من اللي حلتنا على اربعة تلاتين + +115 +00:13:06,630 --> 00:13:11,230 +والزمن دي capital على + +116 +00:13:11,230 --> 00:13:24,490 +دي اللي اربعين على اربعة و تلاتين point + +117 +00:13:24,490 --> 00:13:33,850 +o تلاتة و ال دي capital على دي واحد point + +118 +00:13:36,970 --> 00:13:46,110 +1 8 يعني + +119 +00:13:46,110 --> 00:13:50,410 +أولش ناخد ال R على دي اللي هي point O تلاتة يعني + +120 +00:13:50,410 --> 00:13:52,290 +دي هين point O تقريبا تقريبا هنا + +121 +00:14:06,090 --> 00:14:14,750 +و ال D كبت على دي واحد تمانتاش يعني + +122 +00:14:14,750 --> 00:14:20,590 +عند + +123 +00:14:20,590 --> 00:14:24,190 +ال واحد تمانتاش جاب بين واحد point واحد والواحد + +124 +00:14:24,190 --> 00:14:30,110 +point خمسة يعني اتطلعت بالشكل هذا لاخدت بالشكل عند + +125 +00:14:30,110 --> 00:14:38,440 +اي نقطة عمودي عملت interpolationهتكون واحد point + +126 +00:14:38,440 --> 00:14:41,400 +تمانتاش المسافر هنا دي فادي اكم واحد و نص ناقص + +127 +00:14:41,400 --> 00:14:47,000 +واحد point واحد اكم point اربع point اربع يعني + +128 +00:14:47,000 --> 00:14:51,440 +هتكون عندى هنا واحد و نص ناقص واحد point تمانتاش + +129 +00:14:51,440 --> 00:14:54,960 +على point اربع تاكر ان انا احسبه اكم واحد و نص + +130 +00:14:54,960 --> 00:15:03,240 +ناقص واحد point تمانتاش point + +131 +00:15:03,240 --> 00:15:10,360 +تمانتاشاللي هي واحد point خمسة ناقص واحد point + +132 +00:15:10,360 --> 00:15:14,060 +تمانتاش بعدين اطلع النتيجة اقسمها على اربع من عشرة + +133 +00:15:14,060 --> 00:15:20,260 +point تمانية يعني point تمانية تقريبا لو قسمت هذه + +134 +00:15:20,260 --> 00:15:24,400 +عشر اقسم هي قسمين بعدين عندي + +135 +00:15:28,550 --> 00:15:36,510 +واحد اتنين تلاتة اربعة خمسة ستة سبعة تمانية تسعة + +136 +00:15:36,510 --> 00:15:41,110 +عشرة يعني الحاجة هنا ال curve curve حاجة في منطقة + +137 +00:15:41,110 --> 00:15:45,850 +التمانية من عشرة مظبوط معناته هيكون ال curve جاي + +138 +00:15:45,850 --> 00:15:55,070 +اشي زي هيك انا بقدر اعمل interpolation يعني هنكون + +139 +00:15:55,070 --> 00:15:56,150 +احنا في المنطقة هذه + +140 +00:15:59,880 --> 00:16:10,120 +يعني هدي هدي اتنين point تلاتة ال kitty سو + +141 +00:16:10,120 --> 00:16:18,980 +اتنين point تلاتة معناته ال sigma max هتكون + +142 +00:16:18,980 --> 00:16:24,760 +اتنين point تلاتة في مية و سبعة و اربعين point + +143 +00:16:24,760 --> 00:16:25,220 +واحد + +144 +00:16:41,850 --> 00:16:47,010 +ميجا باسكال انا + +145 +00:16:47,010 --> 00:16:53,330 +عندي هاي كيس واحد هاي + +146 +00:16:53,330 --> 00:16:59,930 +كيس اتنين وهاي + +147 +00:16:59,930 --> 00:17:00,870 +كيس تلاتة + +148 +00:17:06,640 --> 00:17:12,800 +لو بدت ارتبهم ترتيب من حيث التأثير او ارتفاع ال + +149 +00:17:12,800 --> 00:17:20,540 +stress هتكون هذه رقم واحد صح وهذه + +150 +00:17:20,540 --> 00:17:25,800 +رقم اتنين وهذه + +151 +00:17:25,800 --> 00:17:30,260 +رقم تلاتة معناته المصدر كريتيكا لما نكون الثقوب + +152 +00:17:30,260 --> 00:17:30,980 +تمانية ملة + +153 +00:17:34,060 --> 00:17:40,480 +يليه يليه الثقب أربع مليه بعده بيجي الفلت اللي هي + +154 +00:17:40,480 --> 00:17:45,820 +واحد مليه + +155 +00:17:45,820 --> 00:17:56,940 +هاي السؤال متوقع + +156 +00:17:56,940 --> 00:18:00,920 +يكسر على الفلت ولا على الثقبعالثقوب يعني stress + +157 +00:18:00,920 --> 00:18:06,060 +level أعلى، عالثقوب تمانية ملي احنا حكينا في + +158 +00:18:06,060 --> 00:18:11,000 +الحسابات ال stress فيانا ال stress و strength ال + +159 +00:18:11,000 --> 00:18:14,560 +stress مانهاش خاص في ال material ال stress اللي + +160 +00:18:14,560 --> 00:18:20,260 +خاص في ال loading و ال geometryو نضيف شغلة كمان ال + +161 +00:18:20,260 --> 00:18:23,340 +stress concentration loading جيومتري و stress + +162 +00:18:23,340 --> 00:18:27,120 +concentration ال strength بتاعة الحديد it is + +163 +00:18:27,120 --> 00:18:32,240 +strength قوة الحديد بغض نظر عن ال loading عشان كده + +164 +00:18:32,240 --> 00:18:35,120 +أنا بحس ب stress level و بقارنها بال strength + +165 +00:18:35,120 --> 00:18:38,020 +بتاعة ال material تحت الدراسة عشان أعرف ان في اندي + +166 +00:18:38,020 --> 00:18:44,380 +failure ولا مش failure ال strength + +167 +00:18:44,380 --> 00:18:46,840 +اللي علاقة بالجيومتري كيف؟ + +168 +00:18:52,560 --> 00:18:55,860 +أيوة ال stress level بيختلف باختلاف الجيومترية + +169 +00:18:55,860 --> 00:18:59,460 +كويس لأ ما هدك .. هدك مش strength تحكي عليها + +170 +00:18:59,460 --> 00:19:06,020 +stress فال stress level يرتفع أو ينخفض بتغير ال + +171 +00:19:06,020 --> 00:19:12,780 +loading أو تغير المقطع الجيومتري أو بوجود تركيز + +172 +00:19:12,780 --> 00:19:15,040 +إجهادي stress concentration + +173 +00:19:37,590 --> 00:19:41,430 +طيب ان خش على ال stress in pressurized cylinders + +174 +00:19:41,430 --> 00:19:47,570 +في الاستوانات المضغوطة انا حينها هارض عليكم + +175 +00:19:47,570 --> 00:19:51,990 +المعادلات مش مطلوب انكوا اشتقاقها فاندي السيلندر + +176 +00:19:51,990 --> 00:19:55,350 +القطر + +177 +00:19:55,350 --> 00:20:00,730 +الداخل ر ايه اللي هو inner radiusو القطر الخارج + +178 +00:20:00,730 --> 00:20:04,750 +لها RO اللي هو ال outside radius يعني في استوانة + +179 +00:20:04,750 --> 00:20:09,490 +مفقوقة لها قطر داخل ر اي و قطر خارج ر او ال + +180 +00:20:09,490 --> 00:20:11,810 +general case ان يكون في pressure جوا و pressure + +181 +00:20:11,810 --> 00:20:19,610 +برا pressure جوا و pressure برا من جوا ل pressure + +182 +00:20:19,610 --> 00:20:24,870 +جوا الاستوانة قيمته PI اللي هو inside pressure ال + +183 +00:20:24,870 --> 00:20:31,350 +pressure برا الاستوانة PO نتيجة ال pressureلو كان + +184 +00:20:31,350 --> 00:20:36,450 +برشه من جوه هتحاول استوانه ايش تفتح مظبوط مانعني + +185 +00:20:36,450 --> 00:20:39,910 +ان في عندي hoop او tangential stress لو أخدت + +186 +00:20:39,910 --> 00:20:49,150 +stress element يعني هكون + +187 +00:20:49,150 --> 00:20:56,790 +في عندي tangential stress وعندي + +188 +00:21:00,600 --> 00:21:07,820 +radial stress سيجما راديال ال tangential stress + +189 +00:21:07,820 --> 00:21:12,700 +موطني علاقة هادئ سيجما ال tangential في سواء P I R + +190 +00:21:12,700 --> 00:21:16,240 +I Square minus P O R O Square minus R I Square R O + +191 +00:21:16,240 --> 00:21:20,280 +Square في P O minus P I على R Square R هي ال R at + +192 +00:21:20,280 --> 00:21:22,480 +any location ال stress at any location at any + +193 +00:21:22,480 --> 00:21:27,400 +radial location R على R O تربيه minus R I تربيهو + +194 +00:21:27,400 --> 00:21:30,600 +ال radial stress is given by this equation P I R I + +195 +00:21:30,600 --> 00:21:36,280 +square minus P O R O square زائد اتنين R I square + +196 +00:21:36,280 --> 00:21:39,940 +R O square في P O minus P I على ارضي نفس المعادلة + +197 +00:21:39,940 --> 00:21:45,680 +بس لحظة اللي بيختلف بس ليش هذا minus هذا plus و + +198 +00:21:45,680 --> 00:21:55,000 +المقام نفس المقام R O تربية minus R I تربية طيب + +199 +00:21:55,000 --> 00:21:56,400 +هناخد special case + +200 +00:22:00,600 --> 00:22:03,460 +إنه مايوجد ضغط خارجي ضغط بس من جوا الأسطوانة + +201 +00:22:03,460 --> 00:22:11,560 +مايوجد ضغط خارجي يعني ال P O ال P O بالساوية Zero + +202 +00:22:11,560 --> 00:22:15,560 +مايوجد ضغط خارجي لما نعود في المعادلة عن P O + +203 +00:22:15,560 --> 00:22:25,040 +بالساوية Zero هدا هتروح هدا هروح ترم Zero هدا Zero + +204 +00:22:25,040 --> 00:22:30,220 +هدا أيش Zero هتصير ال Sigma تاني جان شال + +205 +00:22:33,040 --> 00:22:45,020 +بتساوي P I R I تربيع minus هتدخلين عندي minus + +206 +00:22:45,020 --> 00:22:53,980 +minus تصير plus plus R I تربيع + +207 +00:22:53,980 --> 00:23:09,470 +R O تربيع في P Iعلى ر تربيع على + +208 +00:23:09,470 --> 00:23:19,630 +ر او تربيع minus ر اي تربيع يعني اخدت مشترك بين + +209 +00:23:19,630 --> 00:23:31,170 +التلين بي اي ر اي تربيع حيصفي واحدهتبقى عندى P I + +210 +00:23:31,170 --> 00:23:36,170 +زائد R O تربيع على + +211 +00:23:36,170 --> 00:23:50,170 +R تربيع على R O تربيع minus R I تربيع ليه + +212 +00:23:50,170 --> 00:23:55,930 +هذه المعادلة R I تربيع P I على R O تربيع minus R I + +213 +00:23:55,930 --> 00:24:00,340 +تربيع في واحد زائد R O تربيع على R تربيعبنفس ال + +214 +00:24:00,340 --> 00:24:03,780 +logic بتطلع + +215 +00:24:03,780 --> 00:24:08,840 +عندي ال radial stress sigma r يعني هدول ال test + +216 +00:24:08,840 --> 00:24:16,240 +نفس الشي بس يختلف هذا plus هذا إيش minus لإن + +217 +00:24:16,240 --> 00:24:25,240 +لو بدى أجيب ال stress distribution على المقطع لإن + +218 +00:24:25,240 --> 00:24:30,920 +في عنديعندي ال two extreme conditions اللي هي ر + +219 +00:24:30,920 --> 00:24:40,760 +بيستوى ر I و ر بيستوى ر O لما ر بتستوى ر I تكون ال + +220 +00:24:40,760 --> 00:24:47,740 +ر O على ر I أكبر من واحد صح؟ لما ر أت + +221 +00:24:51,560 --> 00:25:01,020 +ر ر اي تربيع + +222 +00:25:01,020 --> 00:25:11,200 +في اي على ر او تربيع minus ر اي تربيع في واحد زائد + +223 +00:25:11,200 --> 00:25:16,900 +ر او تربيع على ر اي تربيع + +224 +00:25:23,680 --> 00:25:33,080 +طيب at r equal ro بيصير ال sigma tangential بيساوي + +225 +00:25:33,080 --> 00:25:41,460 +ر I تربيع في I على ر O تربيع minus ر I تربيع في + +226 +00:25:41,460 --> 00:25:47,600 +واحد زياد ايش؟ زياد واحد ال + +227 +00:25:47,600 --> 00:25:50,860 +term هذا ال ر O على ر I تربيع اكبر من واحد صح؟ + +228 +00:25:55,250 --> 00:25:58,910 +معناته ال stress level عند ال inner fiber بيكون + +229 +00:25:58,910 --> 00:26:03,230 +أعلى من ال stress level عند ال outer fiber معناته + +230 +00:26:03,230 --> 00:26:05,930 +هكون ال stress distribution high maximum عند ال + +231 +00:26:05,930 --> 00:26:17,410 +inner fiber و minimum عند ال outer fiber بالظبط + +232 +00:26:17,410 --> 00:26:20,790 +و + +233 +00:26:20,790 --> 00:26:31,260 +ال distribution is non linearفي حالة ال sigma r at + +234 +00:26:31,260 --> 00:26:38,740 +r equal ri بيصير + +235 +00:26:38,740 --> 00:26:48,580 +ال sigma ر عنده بتساوي اللي هي ri تربيع vi على ro + +236 +00:26:48,580 --> 00:26:52,740 +تربيع minus ri تربيع في واحد + +237 +00:26:58,150 --> 00:27:08,230 +-ro تربيع على ri تربيع هيكون الساوى ر ا ع بيصير + +238 +00:27:08,230 --> 00:27:11,810 +negative ال pressure الساوى negative ال pressure + +239 +00:27:11,810 --> 00:27:16,070 +لان انا هاخد ر ا ع تربيع مشتركبالسيران دي ر اي + +240 +00:27:16,070 --> 00:27:18,930 +تربيع معناس ر تربيع خدها السير بتطلع برا بتطلع ر + +241 +00:27:18,930 --> 00:27:22,470 +اي تربيع معناه تربيع و ال bus مع المقام بيستخدم + +242 +00:27:22,470 --> 00:27:28,370 +minus P I هذا منطقي لأن أول fiber متعرض للضغط + +243 +00:27:28,370 --> 00:27:36,110 +مباشر radially متعرض للضغط مباشر radially at R + +244 +00:27:36,110 --> 00:27:40,890 +بيستخدم ر او بتكون + +245 +00:27:40,890 --> 00:27:41,830 +دي ال sigma R + +246 +00:27:45,430 --> 00:27:52,890 +هتكون ر اي تربيع P I على ر او تربيع minus ر اي + +247 +00:27:52,890 --> 00:27:59,750 +تربيع في واحد minus ر او تربيع على ر او تربيع اللي + +248 +00:27:59,750 --> 00:28:09,450 +هي إيش؟ Zero.معناته ال pressure عند ال outer fiber + +249 +00:28:09,450 --> 00:28:12,870 +Zero و عند ال inner fiber تسوى minus ال P I + +250 +00:28:12,870 --> 00:28:13,570 +بالنجاتف + +251 +00:28:17,890 --> 00:28:20,030 +و ال distribution بين ال inner fiber و ال outer + +252 +00:28:20,030 --> 00:28:26,950 +fiber non-linear non + +253 +00:28:26,950 --> 00:28:33,390 +-linear طبعا + +254 +00:28:33,390 --> 00:28:41,570 +انت في حالة الضغط الخارج كان صفر اذا + +255 +00:28:41,570 --> 00:28:44,730 +كانت الاستوانة طبعا بفترض كل حسابات الاستوانة يشمل + +256 +00:28:44,730 --> 00:28:50,520 +على مفتوحةيعني كأنه خط غاز وماشي لما للنهاية لكن + +257 +00:28:50,520 --> 00:28:54,500 +لو كانت الاستوانة مغلقة من الطرفين اذا كانت مغلقة + +258 +00:28:54,500 --> 00:28:58,560 +من الطرفين هصير + +259 +00:28:58,560 --> 00:29:04,860 +stress component تالتة + +260 +00:29:04,860 --> 00:29:09,060 +عند هذه الاستوانة من جوا + +261 +00:29:18,260 --> 00:29:29,480 +هيكون فيه فرشة من كل الجهات هسي + +262 +00:29:29,480 --> 00:29:31,900 +لو أخدت مقطع بالاتجاه الطولي فهيعندي stress + +263 +00:29:31,900 --> 00:29:35,020 +بالاتجاه الطولي بهذا الاتجاه هيك يعني هذا الاتجاه + +264 +00:29:35,020 --> 00:29:41,540 +هكون sigma L المقطع + +265 +00:29:41,540 --> 00:29:57,650 +هذا sigma Lالنقطة هذه هي ر اي ر اي ر او + +266 +00:29:57,650 --> 00:30:00,570 +ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او + +267 +00:30:00,570 --> 00:30:01,090 +ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او + +268 +00:30:01,090 --> 00:30:01,170 +ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او + +269 +00:30:01,170 --> 00:30:02,390 +ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او + +270 +00:30:02,390 --> 00:30:04,750 +ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او + +271 +00:30:04,750 --> 00:30:05,290 +ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او + +272 +00:30:05,290 --> 00:30:16,100 +ر او ر او ر او ر او ر او ر او ر او ر او ر اوبي ر + +273 +00:30:16,100 --> 00:30:21,160 +اي تربيع عند المقطع هقعد هسير عندى stress level + +274 +00:30:21,160 --> 00:30:31,600 +sigma L بسواء في على ال area في بي ر اي تربيع على + +275 +00:30:31,600 --> 00:30:39,800 +ال area هيكون عندى بي ر او تربيع minus بي ر اي + +276 +00:30:39,800 --> 00:30:51,070 +تربيع يعني هتصفى بي اي تربيعفي ر اي تربيع على ر او + +277 +00:30:51,070 --> 00:30:58,930 +تربيع minus ر اي تربيع ليه + +278 +00:30:58,930 --> 00:31:09,470 +هذه المعادلة في حال + +279 +00:31:09,470 --> 00:31:11,710 +كانت النبوبة مغلقة + +280 +00:31:18,730 --> 00:31:24,670 +طبعا هذا السابق اللي هو thick cylinder theory يعني + +281 +00:31:24,670 --> 00:31:28,530 +بفترض انه ال .. ال .. ال .. ال cylinder خملتها + +282 +00:31:28,530 --> 00:31:34,550 +كبيرة في حالة كانت ال cylinder ثمكتها قليل ال thin + +283 +00:31:34,550 --> 00:31:41,430 +cylinder ممكن نعمل بعض التقريبات الان في حالة ال + +284 +00:31:41,430 --> 00:31:45,330 +pressure vessels with wall thickness + +285 +00:31:48,970 --> 00:31:57,610 +أقل أو يساوي واحد على عشرة ال mean radius بعتبرها + +286 +00:31:57,610 --> 00:32:05,050 +ياش thin wall بعتبرها thin wall في حالة thin wall + +287 +00:32:05,050 --> 00:32:13,310 +بيكون عند ال .. خلّيني أرجع للمعادلة الأصلية هنا + +288 +00:32:22,070 --> 00:32:27,310 +لو أخدت الـ Sigma Radial طبعا ال thickness هيكون + +289 +00:32:27,310 --> 00:32:40,050 +ايه ر او ماينس ر اي صح؟ اذا عند الصورة هنا هذا ر + +290 +00:32:40,050 --> 00:32:48,110 +اي و هذا ر او هذا هيكون ايه ال thickness ال + +291 +00:32:48,110 --> 00:32:53,090 +thickness هيكون سواء ر او ماينس ر ايالـ Sigma + +292 +00:32:53,090 --> 00:33:03,470 +Radial ستكون تساوي ر I تربيع P I على الـ ر O تربيع + +293 +00:33:03,470 --> 00:33:08,430 +مناسب الـ ر I تربيع ستكون + +294 +00:33:08,430 --> 00:33:16,730 +ر O مانس ر I في ر O زاد ر I ر O مانس ر I في ر O + +295 +00:33:16,730 --> 00:33:21,150 +زاد ر I + +296 +00:33:25,200 --> 00:33:40,820 +في واحد minus RO تربيع على R تربيع يعني + +297 +00:33:40,820 --> 00:33:48,540 +و ال .. يعني هتكون لسه ر I تربيع في I على ال + +298 +00:33:48,540 --> 00:33:52,680 +thickness ال RO زاد ال RI + +299 +00:33:56,610 --> 00:34:01,830 +الـ RO زاد ال RI لو حكيت ال R مين ال R مين هتكون + +300 +00:34:01,830 --> 00:34:11,270 +تستوياش ر او زاد ر اي على اتنين فهنا ال ر او زاد ر + +301 +00:34:11,270 --> 00:34:19,110 +اي هتستوياش في اتنين اه ال mean radius RM + +302 +00:34:25,110 --> 00:34:31,430 +في 1-r أو تربيه على r تربيه انا دي احاول اريكوا ان + +303 +00:34:31,430 --> 00:34:38,270 +ال stigma r هتكون اقل بكتير من اللي + +304 +00:34:38,270 --> 00:34:47,470 +هو بالظبط او ممكن تاخد ال limit limit + +305 +00:34:47,470 --> 00:34:52,330 +as r + +306 +00:34:56,650 --> 00:35:08,910 +طلع انت هنا يعني هدول ثابت هذا ثابت وهذا ثابت لحظة + +307 +00:35:08,910 --> 00:35:14,190 +ال ر او تربية لما تكون قريبة كتير من ال ر اي تربية + +308 +00:35:14,190 --> 00:35:22,250 +ال term هذا ايش معلومة بكبر بكبر بكبر كتير بكبر + +309 +00:35:22,250 --> 00:35:27,520 +معناه لو واحد ناقص الرقمبصغر كتير بيقرب من السفر + +310 +00:35:27,520 --> 00:35:33,580 +هي ان عندي plus يعني anyway هذا is insignificant + +311 +00:35:33,580 --> 00:35:36,780 +او هيكون insignificant بالنسبالي للواحد فبتصيرها + +312 +00:35:36,780 --> 00:35:40,480 +تقريبا واحد زائد هي تقريبا بيصير اتنين يعني هاد + +313 +00:35:40,480 --> 00:35:44,420 +بيصير قريب من الواحد واحد زائد واحد اتنين هاد قريب + +314 +00:35:44,420 --> 00:35:48,280 +من الواحد وانا طوأ يعني قريبة السفر هتكون ال sigma + +315 +00:35:48,280 --> 00:35:55,020 +R كل ما قلت السمكةبصير small compared بال + +316 +00:35:55,020 --> 00:36:02,960 +tangential stress طبعا هيكون دي still still ال + +317 +00:36:02,960 --> 00:36:09,560 +distribution is nonlinear بس + +318 +00:36:09,560 --> 00:36:12,100 +ال thickness بقى دي المكان اشي زيك هيصير اشي صغير + +319 +00:36:14,290 --> 00:36:20,090 +هتكون ايش ايه؟ صغير فهحسب اللي هو sigma average ال + +320 +00:36:20,090 --> 00:36:24,330 +average tangential stress ال sigma tangential + +321 +00:36:24,330 --> 00:36:28,410 +average طب هتعوض .. هتعوض ايه؟ هتعوض مرة R + +322 +00:36:28,410 --> 00:36:33,730 +بالستويه ر I و مرة R بالستويه ر O بقى انت تحكي + +323 +00:36:33,730 --> 00:36:36,650 +sigma average ال .. ال .. ال .. ال sigma + +324 +00:36:36,650 --> 00:36:44,290 +tangential I زي ال sigma tangential O على اتنينو + +325 +00:36:44,290 --> 00:36:49,230 +بعدين بتحول ال radius ل ال diameters يعني ال DI + +326 +00:36:49,230 --> 00:36:52,710 +بيستوى اتنين ال RI بيطلع عندى ال sigma tangential + +327 +00:36:52,710 --> 00:36:56,570 +average PDI على اتنين T P اللي هو ال pressure جوا + +328 +00:36:56,570 --> 00:36:59,350 +الاستوانة ال DI اللي هو ال inner diameter + +329 +00:36:59,350 --> 00:37:06,930 +للاستوانة و ال T thickness بتاع الاستوانة و ال + +330 +00:37:06,930 --> 00:37:10,670 +sigma T maximum ال maximum tangential stress هيكون + +331 +00:37:11,550 --> 00:37:19,510 +P DI زائد T على اتنين T الاسترس الطولي هيكون سيجم + +332 +00:37:19,510 --> 00:37:31,610 +ألو سواء PDI على أربع T PDI على أربع T تشوف + +333 +00:37:31,610 --> 00:37:32,050 +مثال + +334 +00:37:39,300 --> 00:37:44,000 +الألمنيوم اللاوي pressure vessel is made of tubing + +335 +00:37:44,000 --> 00:37:46,720 +having an outside diameter of eight inch and a + +336 +00:37:46,720 --> 00:37:52,940 +wall thickness of quarter inch عندي pressure + +337 +00:37:52,940 --> 00:38:00,460 +vessel خزان ضغط مصنوع من سبيكة ألمانيوم أو انبوب + +338 +00:38:00,460 --> 00:38:02,780 +ألمانيوم قطرها الخارجي تمانية انش + +339 +00:38:11,200 --> 00:38:17,380 +القطر الخارجي تمانية + +340 +00:38:17,380 --> 00:38:31,380 +انش والسماكة الانبوب ربع انش water + +341 +00:38:31,380 --> 00:38:35,480 +pressure can the cylinder carry؟ ايش في مطبخته + +342 +00:38:35,480 --> 00:38:40,240 +ممكن ال cylinder اتشيله؟F permissible tangential + +343 +00:38:40,240 --> 00:38:47,040 +stress sigma tangential permissible المسموح فيه + +344 +00:38:47,040 --> 00:38:57,120 +بتساوي اتناشر كيلو pound لكل square inch and + +345 +00:38:57,120 --> 00:39:00,380 +theory for thin walled vessels is assumed to apply + +346 +00:39:00,380 --> 00:39:03,660 +نظرية ال thin walled vessels thin walled cylinders + +347 +00:39:03,660 --> 00:39:08,970 +apply متأكد applies or not applyعند ال radius أكم + +348 +00:39:08,970 --> 00:39:16,910 +بيستوي ال ر او بيستوي + +349 +00:39:16,910 --> 00:39:27,310 +أربعة انش ال ر اي أكم بيستوي تلاتة + +350 +00:39:27,310 --> 00:39:36,820 +و خمسة سبعين و ال ر مين هكون تلاتةبنت يعني دي + +351 +00:39:36,820 --> 00:39:40,160 +خمستاش على اتنين سبعة و نص تلاتة point تمانية + +352 +00:39:40,160 --> 00:39:45,020 +اتنين خمسة مظبوط انش + +353 +00:39:45,020 --> 00:39:49,020 +يعني + +354 +00:39:49,020 --> 00:39:54,680 +ال RM على ال thickness سوى تلاتة point تمانية + +355 +00:39:54,680 --> 00:40:04,660 +اتنين خمسة على رباعيعني هتكون أكبر من عشرة أكبر من + +356 +00:40:04,660 --> 00:40:08,320 +عشرة يعني + +357 +00:40:08,320 --> 00:40:11,820 +تقريبا أربع في أربع ستاش حوالي الخمستاش point + +358 +00:40:11,820 --> 00:40:15,920 +something فواضح أنه ال thickness أقل من العشرة + +359 +00:40:15,920 --> 00:40:22,200 +بيعناته ممكن نستخدم ال thin wall cylinder theory + +360 +00:40:23,920 --> 00:40:28,480 +في حالة الـ thin walled cylinders theory ال sigma + +361 +00:40:28,480 --> 00:40:34,720 +tangential maximum اللي + +362 +00:40:34,720 --> 00:40:47,700 +هي بالساوية ال P في DI زائد T على 2T عند ال طبعا + +363 +00:40:47,700 --> 00:40:53,300 +هتساوي ال sigma tangential permissible + +364 +00:40:55,400 --> 00:41:04,020 +ال دي آي ال دي آي هتكون اتنين في تلاتة point سبعة + +365 +00:41:04,020 --> 00:41:12,900 +خمسة يعني سبعة و نص يعني + +366 +00:41:12,900 --> 00:41:21,820 +ال pressure هيكون sigma tangential permissible في + +367 +00:41:21,820 --> 00:41:31,670 +اتنين Tعلى DI زائد T يعني انا حاجز ساوي اتنين في + +368 +00:41:31,670 --> 00:41:35,970 +اتماش في + +369 +00:41:35,970 --> 00:41:41,090 +ال thickness ربع انش على + +370 +00:41:41,090 --> 00:41:49,050 +ال DI اللي هي سبعة و نص زائد ربع + +371 +00:41:50,510 --> 00:41:57,210 +يعني عندي ربع في اتنين و نص، في اتناش، ستة، أكم؟ + +372 +00:41:57,210 --> 00:42:05,410 +point سبعة سبعة أربعة point سبعة سبعة أربعة kilo + +373 +00:42:05,410 --> 00:42:10,880 +pound per square inchهذا الضغط اللي ممكن تشيله + +374 +00:42:10,880 --> 00:42:16,900 +استوانة إذا ال max ال permissible tangential + +375 +00:42:16,900 --> 00:42:19,560 +stress طبعا في بعض الكتب ما بيسموه tangential + +376 +00:42:19,560 --> 00:42:36,040 +بيسموه hoop stress hoop طيب + +377 +00:42:39,330 --> 00:42:44,010 +هذا المطبوق الأول on the basis of pressure found + +378 +00:42:44,010 --> 00:42:47,610 +in part a بناء على قيمة الضغط اللي حسبناها في + +379 +00:42:47,610 --> 00:42:54,770 +الجزء a compute stress components using stress for + +380 +00:42:54,770 --> 00:43:01,170 +thick walled cylinders احسب ال stresses بناء على + +381 +00:43:01,170 --> 00:43:05,450 +ال pressure اللي احنا عارفينه اعتماد على نظريتي ال + +382 +00:43:05,450 --> 00:43:11,020 +thick walls يعني هنستخدم المعادلة هذهالـ sigma + +383 +00:43:11,020 --> 00:43:15,820 +tangential هتكون طبقا للـ thick wall sigma + +384 +00:43:15,820 --> 00:43:22,340 +tangential maximum وين + +385 +00:43:22,340 --> 00:43:30,700 +هتكون عند ال R بيستوى ر I صح هتكون سواء ر I تربية + +386 +00:43:30,700 --> 00:43:40,270 +P I على ر O تربية minus ر I تربيةفي واحد زاد ro + +387 +00:43:40,270 --> 00:43:48,450 +تربيع على ri تربيع هتكون تساوي ال ri اللي هي تلاتة + +388 +00:43:48,450 --> 00:43:53,490 +bond سبعة خمسة تربيع + +389 +00:43:53,490 --> 00:44:03,490 +في bond سبعة أربعة على أربعة تربيع minus تلاتة + +390 +00:44:03,490 --> 00:44:13,530 +bond سبعة خمسةتربية في واحد زائد اربعة تربية ع + +391 +00:44:13,530 --> 00:44:24,290 +تلاتة point سبعة خمسة تربية اكم تطلع اتماش + +392 +00:44:24,290 --> 00:44:34,000 +point بس اكم سفر السفر سفر يعني واضح قريب كتيرمن + +393 +00:44:34,000 --> 00:44:38,020 +ال permissible معناته النظرية يعني is accurate + +394 +00:44:38,020 --> 00:44:44,660 +enough ال sigma radial طبعا ال sigma radial + +395 +00:44:44,660 --> 00:44:47,040 +maximum هتكون جوا هتكون minus P I في جدا احسب + +396 +00:44:47,040 --> 00:44:51,260 +sigma radial maximum + +397 +00:44:51,260 --> 00:44:58,400 +so minus P I اللي هي minus اتناشر كيلو pound بال + +398 +00:44:58,400 --> 00:45:05,580 +square inch فواضح انهفأفرض هذه الصح لإن هي ال more + +399 +00:45:05,580 --> 00:45:09,540 +accurate theory يعني + +400 +00:45:09,540 --> 00:45:15,660 +ال percentage difference هذا هو او percentage + +401 +00:45:15,660 --> 00:45:24,700 +difference ولا percentage error difference + +402 +00:45:24,700 --> 00:45:25,260 +ولا error + +403 +00:45:28,010 --> 00:45:30,530 +difference it's not error ال error ده يعني بيكون + +404 +00:45:30,530 --> 00:45:38,550 +ال true value minus ال observed value او ال .. ف + +405 +00:45:38,550 --> 00:45:43,810 +.. فاحنا مابنعرفش هد .. هد theory و هد theory it's + +406 +00:45:43,810 --> 00:45:48,910 +a mathematical model فانا قلتوا هد ممكن تكون اقرب + +407 +00:45:48,910 --> 00:45:52,550 +للاش لل true فانا قلت انا هحس ال difference + +408 +00:45:52,550 --> 00:45:57,120 +between this theory and this theoryالـ difference + +409 +00:45:57,120 --> 00:46:02,040 +هتكون 12.009 + +410 +00:46:02,040 --> 00:46:12,840 +-12 على 12.009 في المية سبوها + +411 +00:46:12,840 --> 00:46:18,520 +point 0 + +412 +00:46:18,520 --> 00:46:27,970 +.75 في المية يعني اختلاف بين ال thinأجيد ال بيغان + +413 +00:46:27,970 --> 00:46:35,450 +مش اتناش سبعمية و اربعة و سبعين ايش الوحدات بس كده + +414 +00:46:35,450 --> 00:46:40,910 +فيه أسئلة فيه أسئلة انا إيش كاتب هنا كيلو كيلو بقى + +415 +00:46:40,910 --> 00:46:43,430 +ده لازم تقويله لازم تقويله لازم تقويله لازم تقويله + +416 +00:46:43,430 --> 00:46:45,410 +لازم تقويله لازم تقويله لازم تقويله لازم تقويله + +417 +00:46:45,410 --> 00:46:46,370 +لازم تقويله لازم تقويله لازم تقويله لازم تقويله + +418 +00:46:46,370 --> 00:46:52,330 +لازم تقويله لازم تقويله لازم تقويله لاز + +419 +00:46:55,290 --> 00:47:03,350 +طبعا بالظبط صحيح سالب point seven سبعة أربعة kilo + +420 +00:47:03,350 --> 00:47:08,550 +pound per square inch صحيح طيب ال difference + +421 +00:47:08,550 --> 00:47:13,470 +between the two theories is not significant ليس ذو + +422 +00:47:13,470 --> 00:47:20,450 +أهمية الفرق point O سبعة خمسة ثلاثة في المية انا + +423 +00:47:20,450 --> 00:47:23,710 +قلت لو زد stress عام اتماشي + +424 +00:47:29,120 --> 00:47:33,920 +لأ انت مش مسموح لك تتخطى هذه يعني انت حاطط انت + +425 +00:47:33,920 --> 00:47:38,380 +كمصمم انت تحكي ال permissible بمعناته هذه حاطط + +426 +00:47:38,380 --> 00:47:41,080 +some factor of safety حاطط عنب الأمان مثلا انت + +427 +00:47:41,080 --> 00:47:43,460 +حاطط عنب الأمان على سبيل المثال احنا مش عارفين ال + +428 +00:47:43,460 --> 00:47:48,420 +material عنب الأمان مثلا انت حاطط مثلا اتنين اذا + +429 +00:47:48,420 --> 00:47:52,540 +زادت ال sigma عن اتناش بمعناته هينزل عن عنب الأمان + +430 +00:47:52,540 --> 00:47:56,370 +اللي انت حاططهينزل factor of safety هذا لا يعني ان + +431 +00:47:56,370 --> 00:48:01,110 +نصير failure لا يعني ايه نصير failure الا اذا كان + +432 +00:48:01,110 --> 00:48:04,950 +ال factor of safety مشو ساويه واحد فمش مهم اذا + +433 +00:48:04,950 --> 00:48:10,870 +جيتها احنا بيبقى بال stress على حسب ما اتكر بالعرض + +434 +00:48:10,870 --> 00:48:15,730 +بيختلف على طول صح ولا لا؟ كيف يعني؟ لأنه مرة جيت + +435 +00:48:15,730 --> 00:48:22,990 +بالوكالة ايه اما كنا بتجسس من ال diplomaعملنا + +436 +00:48:22,990 --> 00:48:28,570 +تحليل على اللي هو ال man hole .. اش هو .. لل + +437 +00:48:28,570 --> 00:48:33,410 +exhaust تبع ال .. تبع ال .. ال gas دروعين تمام؟ اه + +438 +00:48:33,410 --> 00:48:37,930 +ال man hole عملنا مرة بالعرض و مرة بالطوول ماشي + +439 +00:48:37,930 --> 00:48:41,430 +انا هيبقى احكيلك انت عندك الطوولة ال man hole او + +440 +00:48:41,430 --> 00:48:44,210 +هو اللي هو الطوولة اللي طالة منها ال exhaust gases + +441 +00:48:44,210 --> 00:48:49,370 +ما + +442 +00:48:49,370 --> 00:49:02,280 +هو بختلف اكيدعندك هاي الاستوانة ب 3D استوانة + +443 +00:49:02,280 --> 00:49:07,100 +مفتوحة تعبتها كنت ولا مسكرة مفتوحة يعني مافيه ضغط + +444 +00:49:07,100 --> 00:49:18,880 +جوا لأن فيها thickness كمان وفي + +445 +00:49:18,880 --> 00:49:19,460 +جوا ضغط + +446 +00:49:22,390 --> 00:49:25,430 +لو خدت stress element بس من جوا خدت stress element + +447 +00:49:25,430 --> 00:49:30,330 +يعني احتبت هذا المقطع خدت stress element هنا + +448 +00:49:30,330 --> 00:49:35,610 +stress + +449 +00:49:35,610 --> 00:49:46,810 +element هطلع برا هحكي هذا ال X هذا ال Y وهذا ال Z + +450 +00:49:46,810 --> 00:49:55,160 +ال stress element هرسمههذه الموازنة ال X axis وهذه + +451 +00:49:55,160 --> 00:50:10,640 +ال Y axis وهذه ال Z axis هذا + +452 +00:50:10,640 --> 00:50:18,140 +اللي لم اتكبرته هيكون + +453 +00:50:18,140 --> 00:50:19,740 +باتجاه ال Z + +454 +00:50:23,190 --> 00:50:29,150 +فى هندي فى sigma tangential اللى هى sigma z فى + +455 +00:50:29,150 --> 00:50:34,510 +الحلقة هذه فهو هندي هين اللى هو ده هو اللى هو ب + +456 +00:50:34,510 --> 00:50:39,970 +stress بيحاول يمزق الانبوب بشكل هذا وفى هندي لو + +457 +00:50:39,970 --> 00:50:46,250 +كأخدت هندي هندي هنحكوا انه هندي في ال Y sigma + +458 +00:50:46,250 --> 00:50:52,030 +R و sigma R الانبوب مفتوح + +459 +00:50:55,840 --> 00:51:00,220 +مفتوح مانعته الغازات المضغوطة بتطلع ماشي تطلع على + +460 +00:51:00,220 --> 00:51:04,140 +ال .. على الوين؟ على الهواء الخارجي مانعته ال + +461 +00:51:04,140 --> 00:51:09,560 +gauge pressure ايش ساعة؟ صفر فبتعملش stress بهذا + +462 +00:51:09,560 --> 00:51:16,520 +الاتجاه نظريابس هو في الواقعية ألا يكون في الحقب + +463 +00:51:16,520 --> 00:51:21,080 +أو عرض الواقع ألا يكون في صمم للمتل ال stress لأنه + +464 +00:51:21,080 --> 00:51:26,520 +في حرارة كمان لا تنساش في عنده حرارة ال + +465 +00:51:26,520 --> 00:51:30,480 +temperature distribution مش منتظم بيصير تمددات + +466 +00:51:30,480 --> 00:51:38,700 +طولية وقطرية التمددات ممكن تعمل إجهدات جوابتك على + +467 +00:51:38,700 --> 00:51:45,340 +سؤالك؟هو النفس الدكتورفي في design ال manhole نفسه + +468 +00:51:45,340 --> 00:51:49,560 +في أي .. في أي application، في أحيانا بعمل manhole + +469 +00:51:49,560 --> 00:51:56,750 +على شكل بيضاويبينجأ بشكل بيضاوي؟ انت بتحكي المنهول + +470 +00:51:56,750 --> 00:52:01,310 +اشي تاني اللي هو المنهول اللي هو المنهول اللي هو + +471 +00:52:01,310 --> 00:52:01,970 +المنهول اللي هو المنهول اللي هو المنهول اللي هو + +472 +00:52:01,970 --> 00:52:02,990 +المنهول اللي هو المنهول اللي هو المنهول اللي هو + +473 +00:52:02,990 --> 00:52:03,010 +المنهول اللي هو المنهول اللي هو المنهول اللي هو + +474 +00:52:03,010 --> 00:52:03,290 +المنهول اللي هو المنهول اللي هو المنهول اللي هو + +475 +00:52:03,290 --> 00:52:06,610 +المنهول اللي هو المنهول اللي هو المنهول اللي هو + +476 +00:52:06,610 --> 00:52:09,990 +المنهول + +477 +00:52:09,990 --> 00:52:13,790 +اللي هو المنه + +478 +00:52:26,070 --> 00:52:35,870 +بشكل بيضاوي واخدت ايه stress element هيكون + +479 +00:52:35,870 --> 00:52:41,490 +فيه two surfaces او عندنا هاي stress component + +480 +00:52:41,490 --> 00:52:49,290 +tension و stress component tension و في واحدة منهم + +481 +00:52:49,290 --> 00:52:54,790 +هتكون عاشيعني ممكن نعتبر هذه hoop stress و هذه + +482 +00:52:54,790 --> 00:52:57,790 +hoop stress بس في two directions two hoop stress + +483 +00:52:57,790 --> 00:53:01,090 +component هذه في حالة spherical coordinates + +484 +00:53:01,090 --> 00:53:06,410 +هتستخدم إحداثيات spherical + +485 +00:53:06,410 --> 00:53:16,270 +اه ال sigma r + +486 +00:53:16,270 --> 00:53:17,810 +اللي لان في اتجاه ال y + +487 +00:53:21,100 --> 00:53:25,080 +الـ Sigma Z هي بتحاول تفتحها بالشكل هذا فبصي تعمل + +488 +00:53:25,080 --> 00:53:28,840 +ايه؟ هو في stress او تنجلش ال stress Sigma تنجلشها + +489 +00:53:28,840 --> 00:53:34,780 +في الاتجاه الطولي مش مغلق انبوب بطلع مافيش ضغط + +490 +00:53:34,780 --> 00:53:37,180 +مافيش ضغط بهذا الاتجاه اللي يعمل stress بهذا + +491 +00:53:37,180 --> 00:53:43,860 +الاتجاه لكن في ضغط داخل هنا Sigma I باتجاه ال Y + +492 +00:53:43,860 --> 00:53:46,840 +axis طبعا المفروض انا اخد ال element اخده هنا + +493 +00:53:55,030 --> 00:54:03,230 +الشيء المهم في الـ inner fibre هي + +494 +00:54:03,230 --> 00:54:06,550 +الـ + +495 +00:54:06,550 --> 00:54:07,770 +sigma تنجنشال maximum + +496 +00:54:10,830 --> 00:54:15,870 +اللي هو ايش؟ sigma radial المفروض انا اعمل طبعا + +497 +00:54:15,870 --> 00:54:19,310 +لازم اخش تفاصيل بعد هيك المفروض اعمل اللي هو + +498 +00:54:19,310 --> 00:54:24,410 +الارثومار circle انا عارف sigma واحد اللي انا برتب + +499 +00:54:24,410 --> 00:54:27,390 +sigma واحد و sigma اتنين و sigma تلاتة بيحس ان + +500 +00:54:27,390 --> 00:54:29,970 +sigma واحد اكبر من sigma اتنين اكبر من sigma تلاتة + +501 +00:54:29,970 --> 00:54:32,130 +sigma اتنين في الحالة .. sigma واحد في الحالة + +502 +00:54:32,130 --> 00:54:35,770 +بتكون ايش؟ sigma اتنين general sigma اتنين بتكون + +503 +00:54:35,770 --> 00:54:38,770 +سواء صفر و sigma تلاتة اللي هي minus ال pressure + +504 +00:54:40,270 --> 00:54:43,370 +بعدين يا بستخدم الحصر الثيرو بستخدمها لو بدى + +505 +00:54:43,370 --> 00:54:47,030 +استخدم ال maximum share stress theory بحسب ال + +506 +00:54:47,030 --> 00:54:49,050 +maximum share stress اللى هو sigma واحد معناه + +507 +00:54:49,050 --> 00:54:53,770 +sigma تلت على اتنين اللى هتكون اللى هي sigma + +508 +00:54:53,770 --> 00:54:58,630 +tangential minus minus هتسير يعني هتكون sigma + +509 +00:54:58,630 --> 00:55:02,310 +tangential زاد ال PI على اتنين تحسر maximum share + +510 +00:55:02,310 --> 00:55:06,330 +ومن هنا بتكمل خيوا ما نستبقش الأمور هذا الكلام في + +511 +00:55:06,330 --> 00:55:07,870 +chapter 5 اللى بنحكي عنه + +512 +00:55:23,470 --> 00:55:27,610 +طيب ممكن نستخدم ال .. ال .. ال .. ال theory of + +513 +00:55:27,610 --> 00:55:31,930 +thick cylinder نطبقها بطريقة تانية في حالة عندي + +514 +00:55:31,930 --> 00:55:38,030 +rotating rings عندي ring rotating rings زي .. زي + +515 +00:55:38,030 --> 00:55:46,040 +ال fly wheels بتطور بسرعةال blowers شفتعة الهواء + +516 +00:55:46,040 --> 00:55:50,680 +زي ال discs بتكون دور نتيجة طرد .. نتيجة طرد اذا + +517 +00:55:50,680 --> 00:55:56,680 +عندى اي جسم بدور ديسك بشكل هذا بدور + +518 +00:55:56,680 --> 00:56:06,040 +بسرعة زي omega حسيه القوة طرد مركزه لبرا فحسيه + +519 +00:56:06,040 --> 00:56:10,320 +اللي عندى اياش stresses ال .. اذا بتلاحظوا + +520 +00:56:10,320 --> 00:56:20,350 +المولينكس القديمالمولنكس القديم شاف المولنكس هذه + +521 +00:56:20,350 --> 00:56:30,510 +الشفرات هنا هذا + +522 +00:56:30,510 --> 00:56:38,510 +الشاف وعندي FPG عندي + +523 +00:56:38,510 --> 00:56:40,010 +العمود + +524 +00:56:43,450 --> 00:56:49,190 +هو العمود جاي من مطار بيلف كانت تكون هذه ايش ال + +525 +00:56:49,190 --> 00:56:53,670 +material بتاعتها القديم + +526 +00:56:53,670 --> 00:57:00,190 +مطار لما بيدور هذه انت بدخله فيه فراغ لما بتدور + +527 +00:57:00,190 --> 00:57:09,130 +ايش تفتح بتسكر عن هذه تدور معها طبعا فتحت نتيجة + +528 +00:57:09,130 --> 00:57:13,780 +قوة الطرد المركزي في عندي normalأزاي الـ + +529 +00:57:13,780 --> 00:57:17,340 +centrifugal clutch بالظبط ازاي ال clutch ال + +530 +00:57:17,340 --> 00:57:23,820 +centrifugal فهذه بتفتح و بتمسك عليها فنفس الاشي + +531 +00:57:23,820 --> 00:57:28,980 +ديسكات يعني هذه بتلاحظوا يعني مجرد اذا بتشغل ال + +532 +00:57:28,980 --> 00:57:37,780 +motor بتبين عادة معاك يعني بتفتح نفس الفكرة في ال + +533 +00:57:37,780 --> 00:57:42,860 +discs انها تجد قوة الطرد المركزي بس عند a normalهي + +534 +00:57:42,860 --> 00:57:52,140 +omega square في R هذه المسافة R حاسس ان عندي كمان + +535 +00:57:52,140 --> 00:57:57,140 +force قوة طارد مركزي لبرا اللي هي بيكون سواء M + +536 +00:57:57,140 --> 00:58:02,240 +omega square في R اللي هي A normal في H في R + +537 +00:58:06,930 --> 00:58:10,730 +فنتيزة قوة الطرد المركزى هتصير عندى tangential + +538 +00:58:10,730 --> 00:58:14,610 +stresses و radial stresses فى ال disk او ال + +539 +00:58:14,610 --> 00:58:21,150 +flywheel او ال blower فهتصير عندى tangential و + +540 +00:58:21,150 --> 00:58:27,010 +radial stresses فبصير + +541 +00:58:27,010 --> 00:58:33,930 +كأنه اناI apply pressures زي نفس فكرة ال thick + +542 +00:58:33,930 --> 00:58:40,610 +walled pressure cylinders اللي بيختلف الاختلاف ان + +543 +00:58:40,610 --> 00:58:44,890 +ال pressure ناتج عن inertia forces في حالة ال + +544 +00:58:44,890 --> 00:58:48,110 +thick cylinders ال pressure ناتج عن غازات او سوائل + +545 +00:58:51,130 --> 00:58:55,030 +ال .. ال .. ال conditions outside radius is larger + +546 +00:58:55,030 --> 00:58:59,210 +.. large compared with thickness يعني هنا أساس أنه + +547 +00:58:59,210 --> 00:59:02,390 +ال thickness is constant المعادلات الجاية هشوفها + +548 +00:59:02,390 --> 00:59:06,050 +stresses are constant over the thickness الجهدات + +549 +00:59:06,050 --> 00:59:08,450 +هتكون ثابتة على ال thickness هذه الفرضيات + +550 +00:59:08,450 --> 00:59:15,190 +للمعادلات الجاية إذا عندي disk + +551 +00:59:15,190 --> 00:59:18,910 +.. disk هي disk مفتوح + +552 +00:59:20,450 --> 00:59:27,890 +يعني لديه radius داخلي راي لديه radius خارجي ر او + +553 +00:59:27,890 --> 00:59:38,330 +بدور بسرعة زاوية أميجا سيكون هناك stress + +554 +00:59:38,330 --> 00:59:44,830 +طولية سيجما تنجينشيل وسيجما + +555 +00:59:47,560 --> 00:59:51,560 +معطاب للعلاقة هذه sigma tangential rho omega + +556 +00:59:51,560 --> 00:59:54,500 +square اللي هي رو ال density للمaterial بتاعة ال + +557 +00:59:54,500 --> 00:59:58,680 +disk ال omega السرعة الذهب دورها ال disk في تلاتة + +558 +00:59:58,680 --> 01:00:03,540 +زي نيو على تمانية نيو اللي هي ال Poisson ratio في + +559 +01:00:03,540 --> 01:00:07,120 +ر I square زي ر أسكوير زي ر I square ر أسكوير على + +560 +01:00:07,120 --> 01:00:10,080 +ر أسكوير minus واحد زي تلاتة نيو على تلاتة زي نيو + +561 +01:00:10,080 --> 01:00:14,140 +في ر أسكويرنفس مش المعادلة هذه لل radial stresses + +562 +01:00:14,140 --> 01:00:21,080 +نفس المعادلة تختلف هذه plus minus بس ال term هذا و + +563 +01:00:21,080 --> 01:00:24,660 +ال term هذا مختلف عن هذا ال term يعني ال term + +564 +01:00:24,660 --> 01:00:27,460 +الأول و التاني نفس الأشياء ال term التالت نفس + +565 +01:00:27,460 --> 01:00:31,040 +الأشياء بس بختلف الإشارة مختلف ال term التالت قيمة + +566 +01:00:31,040 --> 01:00:36,730 +مختلفةفنتيجة الـ rotation عند سرعة عالية بـ + +567 +01:00:36,730 --> 01:00:39,450 +cylindrical tangential او radial stresses due to + +568 +01:00:39,450 --> 01:00:47,950 +inertial forces قوة القصور الذاتية الان + +569 +01:00:47,950 --> 01:00:54,170 +اذا عندي انا الموضوع التاني على ال press و ال + +570 +01:00:54,170 --> 01:01:00,450 +shrink fit ال + +571 +01:01:00,450 --> 01:01:07,760 +press fitانا بكون عندى shaft و hole ال shaft بكون + +572 +01:01:07,760 --> 01:01:11,360 +قطره اكبر من ال hole بحشره حشر في اياش ال hole فده + +573 +01:01:11,360 --> 01:01:19,580 +press fit by force ال shrink fit ببرد الشافت او و + +574 +01:01:19,580 --> 01:01:26,640 +بسخن اياش ال hole بتمدد لما نيبرد بيصير ضغط عليه + +575 +01:01:27,510 --> 01:01:29,730 +طبعا بتعمل ال friction يعني ال normal force بتعمل + +576 +01:01:29,730 --> 01:01:31,950 +ال friction ال force يعني بتقاوم ال torque بشكل + +577 +01:01:31,950 --> 01:01:37,230 +كبرجد معظم ال gear boxes حاليا معمولة اللي هو ال + +578 +01:01:37,230 --> 01:01:42,330 +gears مثبتة باستخدام shrink fit طبعا shrink fit + +579 +01:01:42,330 --> 01:01:48,410 +ميزته بيعطيني high torque capacity رقم واحد رقم + +580 +01:01:48,410 --> 01:01:53,670 +اتنين مش محتاج اعمل key ways مجارة المجارة تعمل + +581 +01:01:53,670 --> 01:01:57,640 +stress concentration بستغنى عنهاو التركيبة في ال + +582 +01:01:57,640 --> 01:02:04,140 +mass production أسرع و أسهل منها في حالة بدها مش + +583 +01:02:04,140 --> 01:02:08,920 +machining كتير على ال mechanical parts في عندي .. + +584 +01:02:08,920 --> 01:02:15,480 +عندي .. عندي .. عندي هاي shaft و عندي هاي hole ال + +585 +01:02:15,480 --> 01:02:22,280 +hole او الشافت .. هاي الشافت الشافت مثقوب فيه ثقوب + +586 +01:02:24,160 --> 01:02:32,040 +في له ر اي و في + +587 +01:02:32,040 --> 01:02:44,120 +له common radius ر كابيتال و في ال whole له ر او + +588 +01:02:49,650 --> 01:02:54,870 +الان نتيجة انه في تداخل بين ال shaft و ال hole في + +589 +01:02:54,870 --> 01:03:03,210 +تداخل بمقدار delta radial distance دلتا + +590 +01:03:05,970 --> 01:03:09,310 +وهذا اكمل هذا هصير pressure على ال shaft pressure + +591 +01:03:09,310 --> 01:03:14,910 +من برا وعلى ال pressure من جوا ال pressure سواء + +592 +01:03:14,910 --> 01:03:17,890 +كان حصل ايش تدرس انت اعتبره من برا او من جوا ال + +593 +01:03:17,890 --> 01:03:25,130 +pressure بين اتنين باعتمد على قيمة ايش delta وعلى + +594 +01:03:25,130 --> 01:03:29,520 +ال materialsلل both parts لل shaft و ال hole يعني + +595 +01:03:29,520 --> 01:03:33,820 +مبين اندي هي ال modulus of elasticity و باين ال + +596 +01:03:33,820 --> 01:03:37,280 +poison ratio فاهم فاهم اندي هاد ال E O ال modulus + +597 +01:03:37,280 --> 01:03:41,980 +of elasticity لل outer part و هاد ال modulus of + +598 +01:03:41,980 --> 01:03:45,740 +elasticity لل inner part هاد ال poison ratio لل + +599 +01:03:45,740 --> 01:03:50,460 +outside part هاد ال poison ratio لل inside part + +600 +01:03:53,110 --> 01:03:56,710 +فقيمة ال pressure بتزيد كل ما زاد ال interference + +601 +01:03:56,710 --> 01:04:01,930 +و بتعتمد برضه على ال material properties الموديلس + +602 +01:04:01,930 --> 01:04:05,290 +والاسيستي المدرس الموديلس والاسيستي بتمثل زمبراكية + +603 +01:04:05,290 --> 01:04:12,410 +المادة المادة كأنها زمبراك وضادة كل + +604 +01:04:12,410 --> 01:04:17,490 +ما كان الموديلس الاستعالج كتير كل ما كان ال + +605 +01:04:17,490 --> 01:04:22,600 +interference أصعبكل ما كان interference أصعب يعني + +606 +01:04:22,600 --> 01:04:27,260 +لو أنا بده أحشر shaft في قطعة مطات سهل أمغطها صح + +607 +01:04:27,260 --> 01:04:32,100 +لكن لو بده أضغط قطعة الحديد في حديد صعب كتير لأن + +608 +01:04:32,100 --> 01:04:34,880 +ال modulus velocity بتاعة الحديد أعلى كتير من + +609 +01:04:34,880 --> 01:04:36,980 +modulus velocity للمطات + +610 +01:04:43,190 --> 01:04:46,410 +طبعا في حالة خاصة اذا كان if both cylinders are of + +611 +01:04:46,410 --> 01:04:52,630 +the same material بتكون ال EI بيساوي ال EO و ال UO + +612 +01:04:52,630 --> 01:04:56,490 +بيساوي ال UI بيصير معادلة أبسط بيكون ال pressure + +613 +01:04:56,490 --> 01:05:00,690 +is given by this equation في حالة ان ال inner part + +614 +01:05:00,690 --> 01:05:03,450 +و ال outer part لهم نفس ال material + +615 +01:05:15,100 --> 01:05:19,520 +طبعا I will apply المعادلات + +616 +01:05:19,520 --> 01:05:26,900 +بتاعة ال thick cylinders في حالة عندي cylinder + +617 +01:05:26,900 --> 01:05:30,540 +عليها pressure from the outside pressure from the + +618 +01:05:30,540 --> 01:05:34,580 +inside في عندي tangential stress component و عندي + +619 +01:05:34,580 --> 01:05:36,980 +radial stress component موطنة اللي لقيتها دي رودي + +620 +01:05:36,980 --> 01:05:43,490 +حكينا عنها الان لو بدى اخدال inner part ال inner + +621 +01:05:43,490 --> 01:05:47,650 +part اللي هو الشفت الشفت متعرض لضغط من برا ولا من + +622 +01:05:47,650 --> 01:05:52,850 +جوا؟ outside يعني ال P I عليه شو يساوي؟ zero و ال + +623 +01:05:52,850 --> 01:05:59,790 +P O بيساوياش ال P P I بيساوي zero و P O بيساوي P و + +624 +01:05:59,790 --> 01:06:05,690 +ال most critical جاية في ال interface بين الشفت و + +625 +01:06:05,690 --> 01:06:10,300 +ال hole يعني عندعندنا من ال radius بيستوي R + +626 +01:06:10,300 --> 01:06:14,120 +كابيتال وبيكون في عندي قيمة ال pressure بيستوي P + +627 +01:06:14,120 --> 01:06:20,180 +يعني at R ال sigma تنجلش على ال inner member at R + +628 +01:06:20,180 --> 01:06:26,060 +بيستوي R كابيتال نعمل ال simplification بنعمل في + +629 +01:06:26,060 --> 01:06:33,180 +المعادلة السابقة اللي هي هذه بنحط ال P I بيستوي + +630 +01:06:33,180 --> 01:06:38,840 +Zeroيعني هذا ال term روح و هذا ال term بروح بنعوض + +631 +01:06:38,840 --> 01:06:43,380 +عن R ب R capital و بحسب ال sigma tangential + +632 +01:06:43,380 --> 01:06:50,860 +بالنسبة لل outer member عليه ضغط من جوا صح ال P O + +633 +01:06:50,860 --> 01:06:56,780 +بالساوية سفر و P و I الوقين بالساويات P برضه نفس + +634 +01:06:56,780 --> 01:07:00,320 +الاشي بيعوض عن R بالساوية R capital في معادة ال + +635 +01:07:00,320 --> 01:07:04,740 +sigma radialو بحسب اللي هي sigma radial عند ال + +636 +01:07:04,740 --> 01:07:07,740 +interference اللي هي P في RO square زي R square + +637 +01:07:07,740 --> 01:07:12,120 +على RO square minus R square بالطريقة هذه حسبت + +638 +01:07:12,120 --> 01:07:16,280 +tangential stress و radial stress at the + +639 +01:07:16,280 --> 01:07:19,180 +interference between the two mating parts اللي هو + +640 +01:07:19,180 --> 01:07:20,360 +الشافت و ال whole + +641 +01:07:35,040 --> 01:07:41,360 +طبعا طالما عرفت ال .. ال .. ال tangential stress + +642 +01:07:41,360 --> 01:07:47,640 +at the interference يعني ممكن احسب ال torque + +643 +01:07:47,640 --> 01:07:52,080 +capacity ال torque capacity لل .. لل assembly + +644 +01:07:52,080 --> 01:07:59,960 +torque capacity لل assembly ال torque capacity لل + +645 +01:07:59,960 --> 01:08:05,570 +assembly هتكونstress في إيش؟ tangential stress + +646 +01:08:05,570 --> 01:08:12,290 +هحاول يعمل moment في surface area تعطيني إيش؟ + +647 +01:08:12,290 --> 01:08:20,590 +force tangential force في radius إيش تعطيني؟ + +648 +01:08:20,590 --> 01:08:26,590 +تعطيني torque تعطيني torque جربوا فحصوه لحالكوا + +649 +01:08:27,580 --> 01:08:31,560 +تطلع على press and shrink fit torque capacity + +650 +01:08:31,560 --> 01:08:44,280 +calculation تطلع على torque capacity of + +651 +01:08:44,280 --> 01:08:49,960 +press and shrink fits + +652 +01:09:04,550 --> 01:09:16,890 +طيب هنحكي أخر إشي و نخلص المحاضرة الان + +653 +01:09:16,890 --> 01:09:21,610 +إذا فاني temperature effect some mechanical part و + +654 +01:09:21,610 --> 01:09:24,830 +سخنته هصيرله تمدد + +655 +01:09:27,530 --> 01:09:30,990 +التمدد أو الـ strain لكل واحدة الطول لكل واحدة + +656 +01:09:30,990 --> 01:09:34,030 +الطول أبسل X بالسواء أبسل Y بالسواء أبسل Z بالسواء + +657 +01:09:34,030 --> 01:09:37,830 +Alpha في Delta T Delta T الفرق داشرة الحرارة Alpha + +658 +01:09:37,830 --> 01:09:43,510 +معامل التمدد الطولي معامل + +659 +01:09:43,510 --> 01:09:51,050 +التمدد الحراري في جدول تلاتة تلاتة معطيني معامل + +660 +01:09:51,050 --> 01:09:52,910 +التمدد الحراري + +661 +01:09:54,810 --> 01:09:58,270 +لـ different materials عندك aluminium, brass, + +662 +01:09:58,430 --> 01:10:01,050 +carbon steel, cast iron, magnesium, nickel, + +663 +01:10:01,690 --> 01:10:06,230 +stainless steel, tungsten وعطينا بوحدات مختلفة + +664 +01:10:06,230 --> 01:10:14,030 +باستخدام السلسة scale او فيهرانهايت scale وعطينا + +665 +01:10:14,030 --> 01:10:20,010 +هذه القيم الألفة لأن طالما ال mechanical member + +666 +01:10:20,010 --> 01:10:25,910 +بسخنه is freeبتمدد بس مافيش فيه stresses لكن لو + +667 +01:10:25,910 --> 01:10:29,750 +جيت bar هاي + +668 +01:10:29,750 --> 01:10:42,070 +ال bar مسكته ثبته و بعدين سخنت بدي + +669 +01:10:42,070 --> 01:10:45,950 +أحاول أنا أيش؟ هيحاول اتمدد بس أنا معناه اتمدد ايش + +670 +01:10:45,950 --> 01:10:51,050 +بيصير عندي؟ بيصير stresses على فرض انه thick + +671 +01:10:51,050 --> 01:10:51,430 +enough + +672 +01:10:54,070 --> 01:10:59,110 +بصير في عنده stresses نتيجة بيحاول هو يتمدد بقيمة + +673 +01:10:59,110 --> 01:11:04,230 +epsilon x لكن انا مانعه لو كانت تمدد في ال elastic + +674 +01:11:04,230 --> 01:11:12,330 +regionيعني بقى ممكن أحسب أبسرن X اللي بيساوي Alpha + +675 +01:11:12,330 --> 01:11:21,450 +Delta T بعدين Sigma X بيساوي أبسرن X في E إذا كنا + +676 +01:11:21,450 --> 01:11:27,190 +في ال elastic region وكان معدن اللي هي هذه + +677 +01:11:27,190 --> 01:11:30,810 +المعادلة هايكون إيهاش إذا من المنطقى كل ال stress + +678 +01:11:30,810 --> 01:11:35,170 +هي compression ولا tension compression + +679 +01:11:35,170 --> 01:11:40,150 +هايكونلو انا mano فبحاول اتمدد هو مضغوط من الجهة + +680 +01:11:40,150 --> 01:11:43,390 +مضغوط هو بيصير اندي compression stress ال sigma + +681 +01:11:43,390 --> 01:11:47,690 +سواء minus E في epsilon minus alpha delta T في E + +682 +01:11:47,690 --> 01:12:01,330 +اذا كان عندي plate plate و ممسوك من الأطراف وعطيته + +683 +01:12:01,330 --> 01:12:08,260 +سخنته هحاول اتمدد بهذا الاتجاه وهذا الاتجاهطبعا + +684 +01:12:08,260 --> 01:12:13,900 +نتيجة الـ Poisson Ratio Effect هكون فيه اذا فاكرين + +685 +01:12:13,900 --> 01:12:20,280 +أبسرن + +686 +01:12:20,280 --> 01:12:24,060 +X سواحد + +687 +01:12:24,060 --> 01:12:32,280 +على E في سيجما X minus U في سيجما Y زائد سيجما Z + +688 +01:12:32,280 --> 01:12:43,910 +صح؟ و أبسرنو Y سواحدة ل E في Sigma Y minus U في + +689 +01:12:43,910 --> 01:12:55,890 +Sigma Z Sigma X زي Sigma Z بس + +690 +01:12:55,890 --> 01:13:00,640 +اختار علاقات هذهبنوجد علاقة الاسترس طبعا هيصير + +691 +01:13:00,640 --> 01:13:04,260 +متساوى بالاتجاه ال X وال Y في الحالة هذه ممسوك من + +692 +01:13:04,260 --> 01:13:09,660 +اجهتين هيكون ال sigma أساوي minus Alpha Delta T في + +693 +01:13:09,660 --> 01:13:15,260 +E على 1 minus Nu فدخلت ال poison ratio effect على + +694 +01:13:15,260 --> 01:13:15,740 +الخط + +695 +01:13:23,010 --> 01:13:27,950 +لحد هنا بنكون خلصنا المحاضرة المراجعة بنكمل تاكلوا + +696 +01:13:27,950 --> 01:13:28,310 +العافية + diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/zPhrosq6KF8_raw.json b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/zPhrosq6KF8_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..9bc72d6df1e1be7d4a3bdbc1d49fada84bbdb312 --- /dev/null +++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/zPhrosq6KF8_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 3186, "start": 5.38, "end": 31.86, "text": "السلام عليكم ورحمة الله وبركاته بسم الله الرحمن الرحيم اليوم هنستكمل chapter three اللي هو load and stress analysis اللي في المحاضرة الفاتتة غطينا ال bending and ال .. ال shear و ال bending moment diagrams حلينا بالطريقة التقليدية حددنا ال sign convention لل positive moment و ال sign convention لل positive and negative shear", 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موازية ال y عندي هين tau المستوهة ده عمودي على ال z موازية ال x axis", "tokens": [3615, 1863, 16254, 8032, 9957, 9673, 14851, 2407, 3224, 3660, 11778, 3224, 44650, 25957, 41891, 15844, 2423, 710, 10298, 6156, 3224, 1829, 44510, 10721, 17842, 710, 3714, 2407, 31377, 10632, 2423, 288, 18871, 16254, 8032, 9957, 17842, 9673, 14851, 2407, 3224, 3660, 11778, 3224, 6225, 2304, 2407, 16254, 15844, 2423, 710, 3714, 2407, 31377, 10632, 2423, 2031, 10298], "avg_logprob": -0.28522246368860793, "compression_ratio": 1.7391304347826086, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 305.22, "end": 305.66, "word": "عندي", "probability": 0.6912434895833334}, {"start": 305.66, "end": 306.04, "word": " هين", "probability": 0.5679931640625}, {"start": 306.04, "end": 308.82, "word": " المستوهة", "probability": 0.841796875}, {"start": 308.82, "end": 308.92, "word": " ده", "probability": 0.796142578125}, {"start": 308.92, "end": 309.32, "word": " متعمدة", "probability": 0.7931315104166666}, {"start": 309.32, "end": 309.46, "word": " على", "probability": 0.82763671875}, {"start": 309.46, "end": 309.58, "word": " ال", "probability": 0.6220703125}, {"start": 309.58, "end": 309.66, "word": " z", "probability": 0.38671875}, {"start": 309.66, "end": 310.14, "word": " axis", "probability": 0.77294921875}, {"start": 310.14, "end": 311.74, "word": " فهيبدأ", "probability": 0.8931640625}, {"start": 311.74, "end": 312.12, "word": " tau", "probability": 0.1422119140625}, {"start": 312.12, "end": 313.32, "word": " z", "probability": 0.89794921875}, {"start": 313.32, "end": 314.34, "word": " موازية", "probability": 0.767822265625}, {"start": 314.34, "end": 314.48, "word": " ال", "probability": 0.76025390625}, {"start": 314.48, "end": 314.72, "word": " y", "probability": 0.74560546875}, {"start": 314.72, "end": 316.32, "word": " عندي", "probability": 0.7347412109375}, {"start": 316.32, "end": 317.18, "word": " هين", "probability": 0.886474609375}, {"start": 317.18, "end": 318.04, "word": " tau", "probability": 0.394775390625}, {"start": 318.04, "end": 319.72, "word": " المستوهة", "probability": 0.87607421875}, {"start": 319.72, "end": 319.88, "word": " ده", "probability": 0.976318359375}, {"start": 319.88, "end": 320.46, "word": " عمودي", "probability": 0.8299560546875}, {"start": 320.46, "end": 320.68, "word": " على", "probability": 0.70703125}, {"start": 320.68, "end": 321.22, "word": " ال", "probability": 0.81298828125}, {"start": 321.22, "end": 321.44, "word": " z", "probability": 0.93896484375}, {"start": 321.44, "end": 323.12, "word": " موازية", "probability": 0.796142578125}, {"start": 323.12, "end": 323.24, "word": " ال", "probability": 0.83447265625}, {"start": 323.24, "end": 323.46, "word": " x", "probability": 0.95849609375}, {"start": 323.46, "end": 323.88, "word": " axis", "probability": 0.91748046875}], "temperature": 1.0}, {"id": 13, "seek": 35275, "start": 325.89, "end": 352.75, "text": "بالاضافة لـ Normal Stress Components اللي هو Sigma X و Sigma Y و Sigma Z هندرس الحالة اللي هي تمثل لـ Plain Stress Case", "tokens": [3555, 6027, 46958, 31845, 3660, 5296, 39184, 21277, 38258, 6620, 40496, 13672, 1829, 31439, 36595, 1783, 4032, 36595, 398, 4032, 36595, 1176, 8032, 1863, 3215, 2288, 3794, 21542, 6027, 3660, 13672, 1829, 39896, 46811, 12984, 1211, 5296, 39184, 2149, 491, 38258, 17791], "avg_logprob": -0.2681686004926992, "compression_ratio": 1.322314049586777, "no_speech_prob": 0.0, "words": [{"start": 325.89, "end": 326.45, "word": "بالاضافة", "probability": 0.93642578125}, {"start": 326.45, "end": 326.63, "word": " لـ", "probability": 0.453216552734375}, {"start": 326.63, "end": 326.91, "word": " Normal", "probability": 0.43115234375}, {"start": 326.91, "end": 327.27, "word": " Stress", "probability": 0.69140625}, {"start": 327.27, "end": 327.91, "word": " Components", "probability": 0.808837890625}, {"start": 327.91, "end": 328.31, "word": " اللي", "probability": 0.56396484375}, {"start": 328.31, "end": 328.55, "word": " هو", "probability": 0.9755859375}, {"start": 328.55, "end": 329.01, "word": " Sigma", "probability": 0.436279296875}, {"start": 329.01, "end": 329.55, "word": " X", "probability": 0.91845703125}, {"start": 329.55, "end": 331.39, "word": " و", "probability": 0.6923828125}, {"start": 331.39, "end": 331.87, "word": " Sigma", "probability": 0.92236328125}, {"start": 331.87, "end": 332.89, "word": " Y", "probability": 0.978515625}, {"start": 332.89, "end": 334.31, "word": " و", "probability": 0.9853515625}, {"start": 334.31, "end": 334.69, "word": " Sigma", "probability": 0.94189453125}, {"start": 334.69, "end": 337.25, "word": " Z", "probability": 0.982421875}, {"start": 337.25, "end": 349.57, "word": " هندرس", "probability": 0.788671875}, {"start": 349.57, "end": 349.97, "word": " الحالة", "probability": 0.98291015625}, {"start": 349.97, "end": 350.05, "word": " اللي", "probability": 0.937744140625}, {"start": 350.05, "end": 350.33, "word": " هي", "probability": 0.7958984375}, {"start": 350.33, "end": 351.05, "word": " تمثل", "probability": 0.8263346354166666}, {"start": 351.05, "end": 351.33, "word": " لـ", "probability": 0.609375}, {"start": 351.33, "end": 351.61, "word": " Plain", "probability": 0.708984375}, {"start": 351.61, "end": 352.15, "word": " Stress", "probability": 0.927734375}, {"start": 352.15, "end": 352.75, "word": " Case", "probability": 0.94873046875}], "temperature": 1.0}, {"id": 14, "seek": 38126, "start": 355.98, "end": 381.26, "text": "بكون عندى plan stress يعني stress في بعضين او في مستوى اذا كانت ال stresses on one surface are zero يعني هاي ال X Y Z لو كانت ال stresses على المستوى هذا المتعود على Z axis ال sigma Z والتوزيد X والتوزيد Y بتستوى Zero بعتبرها", "tokens": [3555, 30544, 43242, 7578, 1393, 4244, 37495, 22653, 4244, 8978, 45030, 11242, 9957, 1975, 2407, 8978, 3714, 14851, 2407, 7578, 1975, 15730, 25961, 2655, 2423, 27732, 322, 472, 3753, 366, 4018, 37495, 22653, 8032, 47302, 2423, 1783, 398, 1176, 45164, 25961, 2655, 2423, 27732, 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379.58, "end": 379.92, "word": " Zero", "probability": 0.544921875}, {"start": 379.92, "end": 381.26, "word": " بعتبرها", "probability": 0.8480224609375}], "temperature": 1.0}, {"id": 15, "seek": 39917, "start": 382.17, "end": 399.17, "text": "a case of planned stress ال case of planned stress عندى هاي ال x axis هاي ال y axis عندى sigma x sigma y tau xy tau xy tau xy tau xy", "tokens": [64, 1389, 295, 8589, 4244, 2423, 1389, 295, 8589, 4244, 43242, 7578, 8032, 47302, 2423, 2031, 10298, 8032, 47302, 2423, 288, 10298, 43242, 7578, 12771, 2031, 12771, 288, 17842, 2031, 88, 17842, 2031, 88, 17842, 2031, 88, 17842, 2031, 88], "avg_logprob": -0.25171495065456484, "compression_ratio": 1.7882352941176471, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 382.17, "end": 382.41, "word": "a", "probability": 0.18212890625}, {"start": 382.41, "end": 382.83, "word": " case", "probability": 0.93359375}, {"start": 382.83, "end": 383.25, "word": " of", "probability": 0.9833984375}, 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planes of maximum shear is plus or minus خمس و أربعين درجة اللي هي كجملة", "tokens": [1424, 21961, 781, 14952, 293, 14952, 295, 6674, 24082, 307, 1804, 420, 3175, 16490, 2304, 3794, 4032, 5551, 25513, 3615, 9957, 11778, 47341, 3660, 13672, 1829, 39896, 9122, 7435, 2304, 37977], "avg_logprob": -0.2993163950741291, "compression_ratio": 1.0727272727272728, "no_speech_prob": 0.0, "words": [{"start": 3048.91, "end": 3050.31, "word": "principle", "probability": 0.6319986979166666}, {"start": 3050.31, "end": 3050.91, "word": " planes", "probability": 0.2193603515625}, {"start": 3050.91, "end": 3054.35, "word": " and", "probability": 0.58349609375}, {"start": 3054.35, "end": 3056.15, "word": " planes", "probability": 0.87060546875}, {"start": 3056.15, "end": 3058.09, "word": " of", "probability": 0.9658203125}, {"start": 3058.09, "end": 3059.91, "word": " maximum", "probability": 0.9482421875}, {"start": 3059.91, "end": 3061.21, "word": " shear", "probability": 0.91748046875}, {"start": 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0.6229248046875}, {"start": 3441.43, "end": 3441.63, "word": " احنا", "probability": 0.8699544270833334}, {"start": 3441.63, "end": 3442.01, "word": " حكينا", "probability": 0.933349609375}], "temperature": 1.0}, {"id": 119, "seek": 347080, "start": 3443.48, "end": 3470.8, "text": "سيجما اكس زي السيجما واي على اتنين انا اتوم more circle هاي more circle هاي السيجما هاي التاو لو كنا نرسم more circle كنا نعرف التاو هاد مثلا هاد التاو مع ال X axis counter clockwise كنا نعرف ال counter clockwise موجة يعني هاد يقول بيعملوا ايش", "tokens": [3794, 1829, 7435, 15042, 1975, 4117, 3794, 30767, 1829, 21136, 1829, 7435, 15042, 36764, 1829, 15844, 1975, 2655, 1863, 9957, 1975, 8315, 1975, 2655, 20498, 544, 6329, 8032, 47302, 544, 6329, 8032, 47302, 21136, 1829, 7435, 15042, 8032, 47302, 16712, 995, 2407, 45164, 9122, 8315, 8717, 2288, 38251, 544, 6329, 9122, 8315, 8717, 3615, 28480, 16712, 995, 2407, 8032, 18513, 50113, 15040, 8032, 18513, 16712, 995, 2407, 20449, 2423, 1783, 10298, 5682, 35790, 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"word": " نرسم", "probability": 0.7108561197916666}, {"start": 3460.02, "end": 3460.3, "word": " more", "probability": 0.833984375}, {"start": 3460.3, "end": 3460.62, "word": " circle", "probability": 0.91015625}, {"start": 3460.62, "end": 3460.84, "word": " كنا", "probability": 0.869384765625}, {"start": 3460.84, "end": 3461.28, "word": " نعرف", "probability": 0.958984375}, {"start": 3461.28, "end": 3462.96, "word": " التاو", "probability": 0.77197265625}, {"start": 3462.96, "end": 3463.22, "word": " هاد", "probability": 0.2510986328125}, {"start": 3463.22, "end": 3463.44, "word": " مثلا", "probability": 0.6575927734375}, {"start": 3463.44, "end": 3463.74, "word": " هاد", "probability": 0.81201171875}, {"start": 3463.74, "end": 3464.54, "word": " التاو", "probability": 0.9383138020833334}, {"start": 3464.54, "end": 3464.7, "word": " مع", "probability": 0.97509765625}, {"start": 3464.7, "end": 3464.82, "word": " ال", "probability": 0.92919921875}, {"start": 3464.82, "end": 3464.96, "word": " X", "probability": 0.355224609375}, {"start": 3464.96, "end": 3465.3, "word": " axis", "probability": 0.461669921875}, {"start": 3465.3, "end": 3465.7, "word": " counter", "probability": 0.93212890625}, {"start": 3465.7, "end": 3466.16, "word": " clockwise", "probability": 0.7470703125}, {"start": 3466.16, "end": 3466.4, "word": " كنا", "probability": 0.931884765625}, {"start": 3466.4, "end": 3466.62, "word": " نعرف", "probability": 0.9874674479166666}, {"start": 3466.62, "end": 3466.76, "word": " ال", "probability": 0.67431640625}, {"start": 3466.76, "end": 3466.94, "word": " counter", "probability": 0.9658203125}, {"start": 3466.94, "end": 3467.5, "word": " clockwise", "probability": 0.89404296875}, {"start": 3467.5, "end": 3468.5, "word": " موجة", "probability": 0.9417317708333334}, {"start": 3468.5, "end": 3469.76, "word": " يعني", "probability": 0.9228515625}, {"start": 3469.76, "end": 3469.98, "word": " هاد", "probability": 0.744873046875}, {"start": 3469.98, "end": 3470.14, "word": " يقول", "probability": 0.6611328125}, {"start": 3470.14, "end": 3470.56, "word": " بيعملوا", "probability": 0.9421875}, {"start": 3470.56, "end": 3470.8, "word": " ايش", "probability": 0.7657877604166666}], "temperature": 1.0}, {"id": 120, "seek": 349794, "start": 3471.76, "end": 3497.94, "text": "بيعملوا ازدواج موجب عندي هنا تاو counter clockwise و هنا تاو clockwise طيب نيجي ل more circle هخلي المعادلة عشان تعرفوا كيف أجت", "tokens": [21292, 25957, 1211, 14407, 1975, 11622, 3215, 2407, 26108, 3714, 29245, 3555, 18871, 16254, 34105, 6055, 995, 2407, 5682, 35790, 4032, 34105, 6055, 995, 2407, 35790, 23032, 1829, 3555, 8717, 1829, 7435, 1829, 5296, 544, 6329, 8032, 9778, 20292, 9673, 3615, 18513, 37977, 6225, 8592, 7649, 37279, 28480, 14407, 9122, 33911, 5551, 7435, 2655], "avg_logprob": -0.2762784231792797, "compression_ratio": 1.3310810810810811, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3471.76, "end": 3472.34, "word": "بيعملوا", "probability": 0.776123046875}, {"start": 3472.34, "end": 3472.94, "word": " ازدواج", "probability": 0.869140625}, {"start": 3472.94, "end": 3473.68, "word": " موجب", "probability": 0.8898111979166666}, {"start": 3473.68, "end": 3475.48, "word": " عندي", "probability": 0.68994140625}, {"start": 3475.48, "end": 3475.68, "word": " هنا", "probability": 0.45458984375}, {"start": 3475.68, "end": 3476.18, "word": " تاو", "probability": 0.6817220052083334}, {"start": 3476.18, "end": 3477.8, "word": " counter", "probability": 0.86865234375}, {"start": 3477.8, "end": 3478.52, "word": " clockwise", "probability": 0.7490234375}, {"start": 3478.52, "end": 3479.38, "word": " و", "probability": 0.5234375}, {"start": 3479.38, "end": 3479.56, "word": " هنا", "probability": 0.71533203125}, {"start": 3479.56, "end": 3480.1, "word": " تاو", "probability": 0.8367513020833334}, {"start": 3480.1, "end": 3481.06, "word": " clockwise", "probability": 0.5888671875}, {"start": 3481.06, "end": 3486.24, "word": " طيب", "probability": 0.9319661458333334}, {"start": 3486.24, "end": 3486.52, "word": " نيجي", "probability": 0.8861083984375}, {"start": 3486.52, "end": 3486.6, "word": " ل", "probability": 0.763671875}, {"start": 3486.6, "end": 3486.78, "word": " more", "probability": 0.7548828125}, {"start": 3486.78, "end": 3487.36, "word": " circle", "probability": 0.94189453125}, {"start": 3487.36, "end": 3493.46, "word": " هخلي", "probability": 0.6531575520833334}, {"start": 3493.46, "end": 3493.96, "word": " المعادلة", "probability": 0.80963134765625}, {"start": 3493.96, "end": 3496.82, "word": " عشان", "probability": 0.7296142578125}, {"start": 3496.82, "end": 3497.3, "word": " تعرفوا", "probability": 0.9674479166666666}, {"start": 3497.3, "end": 3497.52, "word": " كيف", "probability": 0.974609375}, {"start": 3497.52, "end": 3497.94, "word": " أجت", "probability": 0.8527018229166666}], "temperature": 1.0}, {"id": 121, "seek": 352593, "start": 3500.21, "end": 3525.93, "text": "ال .. ال issue عند ال C سوى Sigma X زي Sigma Y على اتنين عند ال R بسوى جزر التربيع ل Sigma X minus Sigma Y على اتنين لكل تربيع زي تاو XY تربيع", "tokens": [6027, 4386, 2423, 2734, 43242, 2423, 383, 8608, 2407, 7578, 36595, 1783, 30767, 1829, 36595, 398, 15844, 1975, 2655, 1863, 9957, 43242, 2423, 497, 4724, 3794, 2407, 7578, 10874, 11622, 2288, 16712, 2288, 21292, 3615, 5296, 36595, 1783, 3175, 36595, 398, 15844, 1975, 2655, 1863, 9957, 5296, 28820, 6055, 2288, 21292, 3615, 30767, 1829, 6055, 995, 2407, 48826, 6055, 2288, 21292, 3615], "avg_logprob": -0.2636408635548183, "compression_ratio": 1.6030534351145038, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 3500.21, "end": 3500.63, "word": "ال", "probability": 0.73828125}, {"start": 3500.63, "end": 3500.71, "word": " ..", "probability": 0.082275390625}, {"start": 3500.71, "end": 3501.09, "word": " ال", "probability": 0.70703125}, {"start": 3501.09, "end": 3501.43, "word": " issue", "probability": 0.62646484375}, {"start": 3501.43, "end": 3506.27, "word": " عند", "probability": 0.93408203125}, {"start": 3506.27, "end": 3506.49, "word": " ال", "probability": 0.78857421875}, {"start": 3506.49, "end": 3506.83, "word": " C", "probability": 0.68017578125}, {"start": 3506.83, "end": 3508.85, "word": " سوى", "probability": 0.5337320963541666}, {"start": 3508.85, "end": 3509.17, "word": " Sigma", "probability": 0.47314453125}, {"start": 3509.17, "end": 3509.61, "word": " X", "probability": 0.91748046875}, {"start": 3509.61, "end": 3509.99, "word": " زي", "probability": 0.67138671875}, {"start": 3509.99, "end": 3510.37, "word": " Sigma", "probability": 0.89794921875}, {"start": 3510.37, "end": 3510.79, "word": " Y", "probability": 0.9833984375}, {"start": 3510.79, "end": 3511.79, "word": " على", "probability": 0.68896484375}, {"start": 3511.79, "end": 3512.33, "word": " اتنين", "probability": 0.83355712890625}, {"start": 3512.33, "end": 3513.11, "word": " عند", "probability": 0.8349609375}, {"start": 3513.11, "end": 3513.37, "word": " ال", "probability": 0.97900390625}, {"start": 3513.37, "end": 3513.81, "word": " R", "probability": 0.98193359375}, {"start": 3513.81, "end": 3515.19, "word": " بسوى", "probability": 0.7618408203125}, {"start": 3515.19, "end": 3515.51, "word": " جزر", "probability": 0.9329427083333334}, {"start": 3515.51, "end": 3516.07, "word": " التربيع", "probability": 0.731201171875}, {"start": 3516.07, "end": 3517.11, "word": " ل", "probability": 0.81298828125}, {"start": 3517.11, "end": 3517.47, "word": " Sigma", "probability": 0.88671875}, {"start": 3517.47, "end": 3517.99, "word": " X", "probability": 0.99267578125}, {"start": 3517.99, "end": 3518.71, "word": " minus", "probability": 0.7841796875}, {"start": 3518.71, "end": 3519.05, "word": " Sigma", "probability": 0.89404296875}, {"start": 3519.05, "end": 3519.41, "word": " Y", "probability": 0.99072265625}, {"start": 3519.41, "end": 3519.77, "word": " على", "probability": 0.85498046875}, {"start": 3519.77, "end": 3520.29, "word": " اتنين", "probability": 0.982666015625}, {"start": 3520.29, "end": 3521.03, "word": " لكل", "probability": 0.952880859375}, {"start": 3521.03, "end": 3521.69, "word": " تربيع", "probability": 0.9219970703125}, {"start": 3521.69, "end": 3522.79, "word": " زي", "probability": 0.88818359375}, {"start": 3522.79, "end": 3523.89, "word": " تاو", "probability": 0.6537272135416666}, {"start": 3523.89, "end": 3524.35, "word": " XY", "probability": 0.6708984375}, {"start": 3524.35, "end": 3525.93, "word": " تربيع", "probability": 0.9168701171875}], "temperature": 1.0}, {"id": 122, "seek": 355482, "start": 3533.12, "end": 3554.82, "text": "هي مرسيكا لان عندي محورين محور السيجما محور التاو عندي هنا تاو clockwise وهنا تاو counter clockwise عندي stress element sigma x", "tokens": [3224, 1829, 3714, 2288, 3794, 1829, 4117, 995, 5296, 7649, 18871, 16254, 3714, 5016, 13063, 9957, 3714, 5016, 13063, 21136, 1829, 7435, 15042, 3714, 5016, 13063, 16712, 995, 2407, 18871, 16254, 34105, 6055, 995, 2407, 35790, 37037, 8315, 6055, 995, 2407, 5682, 35790, 18871, 16254, 4244, 4478, 12771, 2031], "avg_logprob": -0.3990624922513962, "compression_ratio": 1.5365853658536586, "no_speech_prob": 0.0, "words": [{"start": 3533.12, "end": 3533.4, "word": "هي", "probability": 0.3792724609375}, {"start": 3533.4, "end": 3534.06, "word": " مرسيكا", "probability": 0.7318522135416666}, {"start": 3534.06, "end": 3534.26, "word": " لان", "probability": 0.5257568359375}, {"start": 3534.26, "end": 3534.66, "word": " عندي", "probability": 0.669189453125}, {"start": 3534.66, "end": 3536.04, "word": " محورين", "probability": 0.9144287109375}, {"start": 3536.04, "end": 3536.9, "word": " محور", "probability": 0.8932291666666666}, {"start": 3536.9, "end": 3537.4, "word": " السيجما", "probability": 0.6356201171875}, {"start": 3537.4, "end": 3539.24, "word": " محور", "probability": 0.8875325520833334}, {"start": 3539.24, "end": 3539.58, "word": " التاو", "probability": 0.7942708333333334}, {"start": 3539.58, "end": 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"seek": 391181, "start": 3882.73, "end": 3911.81, "text": "الشير ال stress بيكون زاوية zero طيب واضح ان sigma one بيساوي ال center زاد ال radius صح؟ sigma one بيساوي ال center", "tokens": [6027, 8592, 13546, 2423, 4244, 4724, 1829, 30544, 30767, 995, 2407, 10632, 4018, 23032, 1829, 3555, 4032, 46958, 5016, 16472, 12771, 472, 4724, 1829, 3794, 995, 45865, 2423, 3056, 30767, 18513, 2423, 15845, 20328, 5016, 22807, 12771, 472, 4724, 1829, 3794, 995, 45865, 2423, 3056], "avg_logprob": -0.2994225433339243, "compression_ratio": 1.4188034188034189, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3882.73, "end": 3883.09, "word": "الشير", "probability": 0.4817708333333333}, {"start": 3883.09, "end": 3883.19, "word": " ال", "probability": 0.475830078125}, {"start": 3883.19, "end": 3883.37, "word": " stress", "probability": 0.8203125}, {"start": 3883.37, "end": 3883.65, "word": " بيكون", "probability": 0.7779134114583334}, {"start": 3883.65, "end": 3884.13, "word": " زاوية", 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فاي principal لاحظوا ten ten طلعين اتنين ten اتنين في بي هيها هذه في بي", "tokens": [3224, 24192, 5296, 1211, 4244, 5296, 1211, 3800, 1975, 3224, 29538, 24976, 2710, 4244, 29538, 6024, 110, 995, 2407, 10632, 8032, 2655, 30544, 13672, 1829, 39896, 1975, 2655, 1863, 9957, 6156, 47302, 9716, 20193, 5016, 19913, 14407, 2064, 2064, 23032, 1211, 3615, 9957, 1975, 2655, 1863, 9957, 2064, 1975, 2655, 1863, 9957, 8978, 4724, 1829, 39896, 11296, 29538, 8978, 4724, 1829], "avg_logprob": -0.38306452862678037, "compression_ratio": 1.6571428571428573, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 3963.45, "end": 3963.45, "word": "هذه", "probability": 0.47491455078125}, {"start": 3963.45, "end": 3963.65, "word": " لل", "probability": 0.397705078125}, {"start": 3963.65, "end": 3963.65, "word": " stress", "probability": 0.364501953125}, {"start": 3963.65, "end": 3964.15, "word": " لل", "probability": 0.5030517578125}, {"start": 3964.15, "end": 3964.61, "word": " strength", "probability": 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4051.31, "end": 4078.35, "text": "هذه سيكون علي سيجما واحد وهذه سيجما واحد وهذه سيجما اتنين لأن الزرع بين سيجما واحد هنا وسيجما اتنين هنا الزرع بينهم 180 درجة معناته سيكون سيجما اتنين متعمد عليه", "tokens": [3224, 24192, 8608, 1829, 30544, 25894, 8608, 1829, 7435, 15042, 36764, 24401, 37037, 24192, 8608, 1829, 7435, 15042, 36764, 24401, 37037, 24192, 8608, 1829, 7435, 15042, 1975, 2655, 1863, 9957, 5296, 33456, 6024, 110, 2288, 3615, 49374, 8608, 1829, 7435, 15042, 36764, 24401, 34105, 4032, 3794, 1829, 7435, 15042, 1975, 2655, 1863, 9957, 34105, 6024, 110, 2288, 3615, 49374, 16095, 11971, 11778, 47341, 3660, 20449, 8315, 47395, 8608, 1829, 30544, 8608, 1829, 7435, 15042, 1975, 2655, 1863, 9957, 44650, 25957, 3215, 47356], "avg_logprob": -0.24529366895376917, "compression_ratio": 2.2325581395348837, "no_speech_prob": 0.0, "words": [{"start": 4051.31, "end": 4051.59, "word": "هذه", "probability": 0.630859375}, {"start": 4051.59, "end": 4051.77, "word": " سيكون", "probability": 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+00:00:25,870 --> 00:00:30,470 +alkanes و ال cycloalkanes زي ما بتعرفوا المرة + +3 +00:00:30,470 --> 00:00:37,030 +الماضية أعطينا فكرة عن ال alkanes من ناحية التسمية + +4 +00:00:37,030 --> 00:00:41,330 +و من ناحية بعض الخواص الفيزيائية و من ناحية + +5 +00:00:41,330 --> 00:00:51,110 +تركيبها بمعنى عدد ذرات ال carbon و ال hydrogenو + +6 +00:00:51,110 --> 00:00:57,310 +الصيغة العامة ربما بتذكروا حكينا للالكينز CNN H2N + +7 +00:00:57,310 --> 00:01:02,560 +Plus Twoالان من انواع ال hydrocarbons اللى بنقول + +8 +00:01:02,560 --> 00:01:07,080 +عنها مشبعة saturated ال cycle alkenes عشان ناخد + +9 +00:01:07,080 --> 00:01:12,600 +cycle alkenes او حتى بعد هيك alkenes بننطلق احنا + +10 +00:01:12,600 --> 00:01:17,220 +من ال alkenes يعني اتخيلوا هذا المركب اللى امامكم + +11 +00:01:17,220 --> 00:01:26,060 +هذا عبارة عن بروبين C3H8 واضح؟لو بدى انا اجعل هذا + +12 +00:01:26,060 --> 00:01:32,700 +المركب اشيل ذرتين هيدروجين و احط بدالهم رابطة يعني + +13 +00:01:32,700 --> 00:01:37,400 +هى ذرة هيدروجين و من جنبها تماما يعني عندك ذرتين + +14 +00:01:37,400 --> 00:01:41,240 +كربون متجاورات شيلت ذرة هيدروجين و حطيت رابطة + +15 +00:01:41,240 --> 00:01:48,270 +مكانهم بيصير عندى ال keenبصير عندى الكين اللى فيه + +16 +00:01:48,270 --> 00:01:52,210 +double bond لبروبيل الان لو سألت ال الكين ايش + +17 +00:01:52,210 --> 00:01:59,970 +الصيغة العامة له لاحظوا معاه C3H6 + +18 +00:02:01,060 --> 00:02:09,040 +C3H6 معنا ذلك الصيغة العامة للالكينز CNNH2N واضح + +19 +00:02:09,040 --> 00:02:15,540 +نقص كم هيدروجينة تنتين الان لو جربنا نشيل كمان + +20 +00:02:15,540 --> 00:02:19,180 +هيدروجين تان من جنب بعض و نحط رابطة مكانهم يعني + +21 +00:02:19,180 --> 00:02:24,060 +هاي كمان هيدروجين شيلتها و كمان هيدروجين و حطيت + +22 +00:02:24,060 --> 00:02:32,960 +رابطة صار عندى رابطةثلاثية ال kind صار عندي ال + +23 +00:02:32,960 --> 00:02:39,660 +kind هذا ال ال kind الصيغة العامة إيه له CNH2N-2 + +24 +00:02:39,660 --> 00:02:44,940 +يعني لما أقول C3H326 + +25 +00:02:44,940 --> 00:02:50,830 +-2 أربعة شايفين الأربعةفهذه الصيغة العامة لل + +26 +00:02:50,830 --> 00:02:56,690 +الkins لل الkinds لل الkins الآن خلّينا نرجع مرة + +27 +00:02:56,690 --> 00:03:01,890 +تانية لل الkins ونشوف طيب إيش الصيغة العامة لل + +28 +00:03:01,890 --> 00:03:06,370 +cycloalkins اللي الآن بدهم يمروا علينا ال + +29 +00:03:06,370 --> 00:03:11,050 +cycloalkins يعني لو بدي أعمل حلقة و كل الروابط + +30 +00:03:11,050 --> 00:03:17,770 +تبعت هذه الحلقة روابط إيش أحديةعشان اعمل حلقة + +31 +00:03:17,770 --> 00:03:24,250 +المفروض ان اشيل ذرتين هيدروجين لكن بشيلهم مش من + +32 +00:03:24,250 --> 00:03:28,810 +جنب بعض في هذه الحالة مثلا بشيلهم من الأطراف هشيلت + +33 +00:03:28,810 --> 00:03:33,990 +ذرة هيدروجين من هنا و ذرة هيدروجين تانية من + +34 +00:03:33,990 --> 00:03:41,210 +الأطراف و حطيت مكانها رابطة صار + +35 +00:03:41,210 --> 00:03:47,060 +عند مركب حلقهcycloalkane لأنه إجا من تلت كربونات + +36 +00:03:47,060 --> 00:03:53,100 +بروبيل، شو صرت أسميه؟ Cyclopropane طيب، الآن طالما + +37 +00:03:53,100 --> 00:03:58,100 +أنا شيلت هيدروجين تان، والواقع أيضا بأيد هالكلام + +38 +00:03:58,100 --> 00:04:00,400 +C3H + +39 +00:04:01,190 --> 00:04:08,670 +Six إذا ما الصيغة العامة للـ Cycloalkynes CNH2N + +40 +00:04:08,670 --> 00:04:15,810 +CNH2N لاحظوا معناه إن ال الكينز و ال Cycloalkynes + +41 +00:04:15,810 --> 00:04:19,990 +بينشأوا عنفق الذرتين هيدروجين ولذلك الطرفين اللي + +42 +00:04:19,990 --> 00:04:26,110 +همنفس الصيغة العامة لكن لو فقدوا ذرات الهيدروجين + +43 +00:04:26,110 --> 00:04:31,050 +من جانب بعض اعملنا رابطة مكانهم صار عند ال الكين + +44 +00:04:31,050 --> 00:04:35,450 +لو فقدوا من اماكن بعيدة و اعملنا رابطة صار عند + +45 +00:04:35,450 --> 00:04:40,370 +Cycloalkyn و لذلك ال Cycloalkyn و ال الكين هما + +46 +00:04:40,370 --> 00:04:46,750 +يمتلون نفس الفورمولة CNH2N + +47 +00:04:46,750 --> 00:04:52,900 +هذه النقطة الأولى اللى بدى احكيها في الموضوعالان + +48 +00:04:52,900 --> 00:04:57,960 +لو اتطلعنا اكثر على الـ Cyclopropane بدنا معلومات + +49 +00:04:57,960 --> 00:05:03,040 +اكثر عنه، لاحظوا ان تلت ذرات الكربون تبعون الـ + +50 +00:05:03,040 --> 00:05:09,830 +Cyclopropane في مستوى واحد، واضح؟و أي تلت ذرات في + +51 +00:05:09,830 --> 00:05:13,470 +الدنيا بالمناسبة بيكونوا في مستوى واحد يعني مش + +52 +00:05:13,470 --> 00:05:17,130 +ممكن تلاتة إلا يكونوا في مستوى واحد واحد اتنين + +53 +00:05:17,130 --> 00:05:22,070 +حطوا التالتة هذا في مستوى واحد ولذلك لو سألنا عن + +54 +00:05:22,070 --> 00:05:27,370 +الـcyclopropane إيش الشكل تبعه بدنا نقول planner + +55 +00:05:27,370 --> 00:05:34,230 +planner يعني في مستوى واحد مش بتلت أبعاد يعني لو + +56 +00:05:34,230 --> 00:05:39,070 +كنا بنحكي عن XY هذا في ال XYواضحة الفكرة؟ هذه + +57 +00:05:39,070 --> 00:05:41,870 +النقطة الثانية اللى بدنا ننبهها بالنسبة للـ + +58 +00:05:41,870 --> 00:05:48,610 +Cyclopropane الان نقطة تالتة كتير مهمة جدا عندنا + +59 +00:05:48,610 --> 00:05:55,510 +دائما في أي مركب نعرف أنواع ذرات الهيدروجيلعشان + +60 +00:05:55,510 --> 00:05:59,570 +لما بنعمل التفاعلات النواتج تتمد كم نوع ذرات + +61 +00:05:59,570 --> 00:06:04,410 +هيدروجين عندك يعني ربما المركب الأصلي اللى قبل ما + +62 +00:06:04,410 --> 00:06:08,230 +يكون Cyclopropane اللى هو البروبين لما حكينا المرة + +63 +00:06:08,230 --> 00:06:18,590 +الماضية CH3 CH2 CH3 كم نوع من ذرات الهيدروجين فيه + +64 +00:06:18,590 --> 00:06:24,250 +نوعين هدولة الستة زي بعض و هدولة التنتين زي بعض و + +65 +00:06:24,250 --> 00:06:27,630 +عشان ايه بعد شوية لو بدي اعمل عليه تفاعلات اقول طب + +66 +00:06:27,630 --> 00:06:32,530 +نشيل هيدروجينة نحط مركانها كلور لو شيلت من هان + +67 +00:06:32,530 --> 00:06:37,610 +بطلع عنده مركب بسميه one chlorobrobil لو شيلت من + +68 +00:06:37,610 --> 00:06:43,220 +هانبطلع مركّب تاني بسميه 2-chloropropane فبناء على + +69 +00:06:43,220 --> 00:06:47,240 +عدد أنواع الهيدروجين انا بقدر اعرف ايش اللي بيصير + +70 +00:06:47,240 --> 00:06:51,340 +عندى بالتفاعل طيب يا تورا لو مسكت ال cyclopropane + +71 +00:06:51,340 --> 00:06:59,720 +و سألت هدولة 6 ذرات هيدروجين كام نوع؟نوع واحد + +72 +00:06:59,720 --> 00:07:04,400 +بمعنى لو انا امسكت ذرة كلور خلّينا نفترض هذه لمخ + +73 +00:07:04,400 --> 00:07:08,520 +اللون الأخضر بدي اشيل اي هيدروجين و احط مكانها + +74 +00:07:08,520 --> 00:07:14,180 +كلور مش هذا تفاعل ابدال بدلنا هيدروجين بكلور الان + +75 +00:07:14,180 --> 00:07:20,460 +لو شيلت هذه و حطيت كلور هيطلع عندى مركببس بيصير + +76 +00:07:20,460 --> 00:07:25,920 +اسمه اكلورو سايكلو بروبين طب لو كنت بده احك مكان + +77 +00:07:25,920 --> 00:07:33,120 +هادي نفس الاشي واضح مكان هادي مكان هادي ف ست ذرات + +78 +00:07:33,120 --> 00:07:38,520 +الهيدروجين في هذا المركب they are equivalent يعني + +79 +00:07:38,520 --> 00:07:43,560 +لو كنا بنسألكم the six hydrogens of cyclopropane + +80 +00:07:43,560 --> 00:07:50,880 +areequivalent متكافئات واضحة الفكرة وعشان هيك + +81 +00:07:50,880 --> 00:07:56,440 +بنقدر نتبع هالكلام جملة تانية monochlorination of + +82 +00:07:56,440 --> 00:07:59,600 +cyclopropane معناه monochlorination إن أنا أبدل + +83 +00:07:59,600 --> 00:08:05,680 +هيدروجين واحدة بكلور واحدة شو بسمي العملية؟ mono + +84 +00:08:05,680 --> 00:08:11,120 +يعني أحادي monochlorination + +85 +00:08:11,120 --> 00:08:18,080 +إيش يعني chlorination؟تفاعل مع الكلور تفاعل الـ + +86 +00:08:18,080 --> 00:08:21,340 +Cyclopropane مع الكلور إبدال بذرة واحدة + +87 +00:08:21,340 --> 00:08:27,820 +Monochlorination of Cyclopropane produces only one + +88 +00:08:27,820 --> 00:08:34,880 +product بيطلع فقط ناتج واحد، شو سميته أنا؟ + +89 +00:08:34,880 --> 00:08:40,900 +Chlorocyclopropane واضح؟ + +90 +00:08:41,270 --> 00:08:48,910 +الان اذا بنستمر بنفس هذه الفكرة وبنقول ان انسان + +91 +00:08:48,910 --> 00:08:54,850 +عمل هذا التفاعل وصار عنده chlorocyclopropane وفكر + +92 +00:08:54,850 --> 00:09:00,570 +انه بده يعمل تفاعل تاني على ال cyclopropane ابدل + +93 +00:09:00,570 --> 00:09:06,850 +كمان هيدروجين لازم يكون عارف كم نوع من الهيدروجين + +94 +00:09:06,850 --> 00:09:15,380 +عنده في هذا المركب الانلا أكيد لا الان احنا بحاجة + +95 +00:09:15,380 --> 00:09:24,980 +إلى عمق في التفكير و في النظر الأمر مش سهل اكثر + +96 +00:09:24,980 --> 00:09:31,580 +من نوع يعني هذا لما بضحط chlorine تانية كان مركب + +97 +00:09:31,580 --> 00:09:38,640 +بينتج عندى فيه واضح؟في الحقيقة هنكتشف انهم اللي + +98 +00:09:38,640 --> 00:09:45,540 +بينتجوا تلت مركبات معناه ذلك عندنا تلت أنواع من + +99 +00:09:45,540 --> 00:09:49,220 +الهيدروجيل بنعملهم بال model و بعدين بنكتبهم + +100 +00:09:49,220 --> 00:09:53,680 +معادلة حتى نأكد المعلومة الآن لو إجت طالبة منكم + +101 +00:09:53,680 --> 00:09:59,240 +قالت بدي أشيل هذه الهيدروجيل اللي على نفس الكاربون + +102 +00:09:59,240 --> 00:10:05,020 +اللي حامله كلور و أحط محالها كلورطلعت مركّب حامل + +103 +00:10:05,020 --> 00:10:08,840 +ذرتين كلور على نفس الكربون هذا + +104 +00:10:08,840 --> 00:10:13,180 +Dichlorocyclopropane لكن التسمية بتشترط اني لازم + +105 +00:10:13,180 --> 00:10:17,680 +احدد الان مواقعهم وين موجودة هذه عن امر واحد و هذه + +106 +00:10:17,680 --> 00:10:23,680 +ع واحد اذا هذا لو كنت بدى اسميه هسميه one one + +107 +00:10:23,680 --> 00:10:28,540 +مرتين لازم اقول one يعني ذرة على one والتانية على + +108 +00:10:28,540 --> 00:10:32,600 +one one one dichlorocyclopropane + +109 +00:10:33,600 --> 00:10:39,640 +هذا مُركّب إجى مكان ذرّة الهيدروجين اللي هنا الان + +110 +00:10:39,640 --> 00:10:47,020 +لو إجيت طلعت على هدول الذرات نسبتهم لهذه واحد تنين + +111 +00:10:47,020 --> 00:10:56,580 +او واحد تنين واضح؟ الان لو شيلت هذه حطيت مكانها + +112 +00:10:56,580 --> 00:11:04,460 +اكلور هيطلع عند مُركّب جديدDichlorocyclopropane + +113 +00:11:04,460 --> 00:11:09,300 +قدرتين لكلور على موقعين متجاورين عشانك بقول one + +114 +00:11:09,300 --> 00:11:13,520 +two dichlorocyclopropane + +115 +00:11:13,520 --> 00:11:19,240 +one two dichlorocyclopropane هاي مركب تاني الان + +116 +00:11:19,240 --> 00:11:25,060 +ممكن واحدة منكم تفكر تقول طب خلينا نشيل هذه الذرعة + +117 +00:11:25,060 --> 00:11:30,880 +مش من نفس الجهة اللي هنا من الجهة المعاكسة ونحط + +118 +00:11:34,790 --> 00:11:40,130 +one two dichlorocyclopropane الان السؤال هل يا ترى + +119 +00:11:40,130 --> 00:11:44,950 +المركب اللى فى ذرتين لكلور على جهة واحدة زى اللى + +120 +00:11:44,950 --> 00:11:49,070 +فى ذرتين لكلور متعاكسة ممكن البعض يقول طب احنا + +121 +00:11:49,070 --> 00:11:54,190 +بنلف حوالين الرابط لو جربنا اللفتذكروا أن الدوران + +122 +00:11:54,190 --> 00:12:00,050 +ممنوع حول الحلقة مافيش إمكانية إذا هدول مركبين طيب + +123 +00:12:00,050 --> 00:12:04,210 +هذا اسمه one two و اللي كان ع جهة واحدة برضه اسمه + +124 +00:12:04,210 --> 00:12:07,510 +one two dichlorocyclopropane لو بدي أميزهم أكثر + +125 +00:12:07,510 --> 00:12:11,890 +بقول اه في عندي one two اللي على جهة واحدة و one + +126 +00:12:11,890 --> 00:12:19,170 +two اللي على جهتين متعاكستين هنا بدأنا نتكلم في ال + +127 +00:12:19,170 --> 00:12:24,460 +stereo chemistryانه صحيح الذرات موجودين على موقع + +128 +00:12:24,460 --> 00:12:28,440 +واحد و اتنين يعني same bonding لكن هنا على واحد و + +129 +00:12:28,440 --> 00:12:32,480 +اتنين على جهة واحدة و على واحد و اتنين على جهتين + +130 +00:12:32,480 --> 00:12:37,660 +متعاكستين الاسم في الحالتين one two + +131 +00:12:37,660 --> 00:12:42,770 +dichlorocyclopropane لكن بدي اضيف عليه مرة معو مرة + +132 +00:12:42,770 --> 00:12:49,450 +ضد لو كنا بنكتب بالعربي فعلا بيستعملوا مع كلمتين + +133 +00:12:49,450 --> 00:12:55,110 +مع على جهة واحدة و ضد على جهتين متعاكستين الآن + +134 +00:12:55,110 --> 00:12:58,550 +بالإنقليزي بيروحوا بيحطوا prefix ال prefix يعني + +135 +00:12:58,550 --> 00:13:03,690 +اشي في أول الكلام بادئة توضح هذا الكلام بيروحوا + +136 +00:13:03,690 --> 00:13:08,910 +بيضيفوا cis بمعنى على جهة واحدة و trans بمعنى على + +137 +00:13:08,910 --> 00:13:16,000 +جهتينSex و Trans يعني على جهة واحدة وعلى جهتين + +138 +00:13:16,000 --> 00:13:24,840 +خلينا هذا الكلام إذا بتسمحوا نتخيله بمعادلة ليش + +139 +00:13:24,840 --> 00:13:29,660 +لأنه دائما إنتوا لو بدكوا تكتبوا هتكتبوا معادلات + +140 +00:13:29,660 --> 00:13:31,780 +بمعنى هاي في عند أنا + +141 +00:13:36,020 --> 00:13:41,100 +Cyclopropane هذا Cyclopropane كام هيدروجين فيه؟ + +142 +00:13:41,100 --> 00:13:46,860 +ستة لو قلت بدي أعمل إيه له؟ إكلورينايشن CL2 في + +143 +00:13:46,860 --> 00:13:51,460 +البداية بدي أعمل مونوكلورينايشن أبدل ذرة واحدة شو + +144 +00:13:51,460 --> 00:13:57,400 +هينشاء عندى؟ إكلورو سايكلوبروبين على أي موقع ابنه + +145 +00:13:57,400 --> 00:14:03,840 +كتوبة ماعنداش مشكلة إكلورو سايكلوبروبين + +146 +00:14:03,840 --> 00:14:07,900 +هيك حاجة أسميهالان لو افترضت هذا ال + +147 +00:14:07,900 --> 00:14:14,440 +chlorocyclopropane بدي اعمله كمان chlorination + +148 +00:14:14,440 --> 00:14:20,000 +حيصير بالمجمل كم ذرة ال chlor أبدلت تنتين اه كمان + +149 +00:14:20,000 --> 00:14:25,720 +مرة chlorination حيصير عندي عدة احتمالات هذا + +150 +00:14:25,720 --> 00:14:29,140 +الاحتمال ان ذرة ال chlor تيجي على نفس الذرة اللي + +151 +00:14:29,140 --> 00:14:35,700 +حملة ال chlor الأولى ايش سمناهالأ اللي عملناه في + +152 +00:14:35,700 --> 00:14:42,520 +الأولى ال chlorine ال chlorine على نفس الذرة one + +153 +00:14:42,520 --> 00:14:45,880 +one one one one one one one one one one one one + +154 +00:14:45,880 --> 00:14:46,040 +one one one one one one one one one one one one + +155 +00:14:46,040 --> 00:14:46,060 +one one one one one one one one one one one one + +156 +00:14:46,060 --> 00:14:46,060 +one one one one one one one one one one one one + +157 +00:14:46,060 --> 00:14:53,560 +one one one one one one one one one one one one + +158 +00:14:53,560 --> 00:14:53,560 +one one one one one one one one one one one one + +159 +00:14:53,560 --> 00:14:53,560 +one one one one one one one one one one one one + +160 +00:14:53,560 --> 00:14:53,820 +one one one one one one one one one one one one + +161 +00:14:53,820 --> 00:14:54,180 +one one one one one one one one one one one one + +162 +00:14:54,180 --> 00:14:54,200 +one one one one one one one one one one one one + +163 +00:14:54,200 --> 00:14:54,200 +one one one one one one one one one one one one + +164 +00:14:54,200 --> 00:14:54,200 +one one one one one one one one one one one one + +165 +00:14:54,200 --> 00:14:54,300 +one one one one one one one one one one one one + +166 +00:14:54,300 --> 00:14:54,300 +one one one one one one one one one one one one + +167 +00:14:54,300 --> 00:14:54,300 +one one one one one one one one one one one one + +168 +00:14:54,300 --> 00:14:54,300 +one one one one one one one one one one one one + +169 +00:14:54,300 --> 00:14:54,300 +one one one one one one one one one one + +170 +00:15:10,380 --> 00:15:18,060 +الان يا تورا لو كنا بدنا نحط ذرة الكلور على الموقع + +171 +00:15:18,060 --> 00:15:24,020 +اتنين خلينا نحط واحد و اتنين هنا بهذا الشكل ممكن + +172 +00:15:24,020 --> 00:15:30,380 +يكون عنده ذرتين كلور على جهة واحدة او ذرتين كلور + +173 +00:15:30,380 --> 00:15:33,920 +على جهتين متعاكسات + +174 +00:15:35,440 --> 00:15:40,600 +واضح؟ الان هاي واحد اتنين تلاتة واحد اتنين تلاتة + +175 +00:15:40,600 --> 00:15:45,240 +اذا كل مركب من هدوله ايش اسمه one two + +176 +00:15:45,240 --> 00:15:56,340 +dichlorocyclopropane one two dichlorocyclopropane + +177 +00:15:56,340 --> 00:15:58,800 +لكن + +178 +00:16:05,080 --> 00:16:10,380 +لكن لما بدي اميز هدول المركبات هنا الديكلورو جايين + +179 +00:16:10,380 --> 00:16:16,680 +على جهة واحدة فهذا الاسم الكامل له شو حيصير SES + +180 +00:16:16,680 --> 00:16:22,200 +شرطة one two dichlorocyclopropane يعني لما بدي + +181 +00:16:22,200 --> 00:16:27,540 +اجيب هذا في الامتحان سموه هتكتبوا SES شرطة one two + +182 +00:16:27,540 --> 00:16:33,430 +dichlorocyclopropane لو كنت بدي اسمي هذاالترانس + +183 +00:16:33,430 --> 00:16:37,190 +شرطة one two dichlorocyclopropane طبعا اكيد الذره + +184 +00:16:37,190 --> 00:16:44,010 +التاني اللي هي ذره ايش ال hydrogenواضح؟ لاحظوا ان + +185 +00:16:44,010 --> 00:16:49,010 +هدول المركبين .. هدول المركبين من ناحية ال bonding + +186 +00:16:49,010 --> 00:16:53,170 +.. من ناحية ال bonding they have the same bonding + +187 +00:16:53,170 --> 00:16:57,230 +من أي ناحية؟ ان ذرة كلورة على موقع واحد و التاني + +188 +00:16:57,230 --> 00:17:00,690 +على موقع التاني على واحد على اتنين .. على واحد على + +189 +00:17:00,690 --> 00:17:06,310 +اتنين the same bonding لكن اين الاختلاف؟ بالشكل .. + +190 +00:17:06,310 --> 00:17:10,930 +بالشكل الفراغي they have the same bondingbut + +191 +00:17:10,930 --> 00:17:15,470 +different arrangement in space شكلهم بالفراغ مختلف + +192 +00:17:15,470 --> 00:17:19,010 +ان هدول الذرتين ع جهة واحدة و هدول الذرتين ع جهات + +193 +00:17:19,010 --> 00:17:22,850 +متعاكسة بس اتنين ع واحد اتنين هذا النوع اللي احنا + +194 +00:17:22,850 --> 00:17:29,250 +ايش سمنا stereo isomersهذا النوع اللي سمناه stereo + +195 +00:17:29,250 --> 00:17:32,910 +isomers لما حكينا على ال isomerism قلنا ال stereo + +196 +00:17:32,910 --> 00:17:37,630 +isomers they have the same bonding يعني لما أجي + +197 +00:17:37,630 --> 00:17:41,670 +أقول الكلور وين؟ ع واحد و التانية ع اتنين في + +198 +00:17:41,670 --> 00:17:45,870 +التاني الكلور وين؟ ع واحد و التانية ع اتنين اذا + +199 +00:17:45,870 --> 00:17:50,310 +they have the same bonding طب وين اختلفوا؟بشكل + +200 +00:17:50,310 --> 00:17:54,390 +برفرات اه هدول ع واحد و اتنين ع جهة واحدة على واحد + +201 +00:17:54,390 --> 00:17:57,630 +و اتنين ع جهتين مختلفتين هذه بنسميها different + +202 +00:17:57,630 --> 00:18:03,710 +arrangement in space اذا العلاقة بين هذا ال cis و + +203 +00:18:03,710 --> 00:18:12,070 +ال trans they are stereo isomers لاحظوا + +204 +00:18:12,070 --> 00:18:16,930 +لو قلتلكوا ما العلاقة بين هذا المركب و هذا المركب + +205 +00:18:16,930 --> 00:18:22,870 +في ال isomersهنا they have different bonding و + +206 +00:18:22,870 --> 00:18:29,140 +different namesذرتين الكلور على واحد و واحد وعشان + +207 +00:18:29,140 --> 00:18:33,980 +هيك سميته one one dichlorocyclopropane هنا ذرتين + +208 +00:18:33,980 --> 00:18:36,600 +الكلور على واحد و اتنين هذا ال same bonding ولا + +209 +00:18:36,600 --> 00:18:40,020 +different bonding different bonding ال different + +210 +00:18:40,020 --> 00:18:45,220 +bonding أدى إلى different names أنا لما حددت مواقع + +211 +00:18:45,220 --> 00:18:49,620 +الكلور قلت one one هنا قلت one two إذا هذا المركب + +212 +00:18:49,620 --> 00:18:50,860 +و هذا المركب + +213 +00:18:53,140 --> 00:18:58,280 +صحيح مكونين من نفس الذرات لكن فيهم different + +214 +00:18:58,280 --> 00:19:01,860 +bonding و different names فالعلاقة بين ال 11 + +215 +00:19:01,860 --> 00:19:06,420 +-dichlorocyclopropane و ال 12-dichlorocyclopropane + +216 +00:19:06,420 --> 00:19:11,480 +they are structural isomers و كذلك العلاقة بين هذا + +217 +00:19:11,480 --> 00:19:15,140 +و هذا لكن لو قلت العلاقة بين ال cis و ال trans + +218 +00:19:15,140 --> 00:19:19,120 +they are stereo isomers + +219 +00:19:21,810 --> 00:19:26,210 +Same bonding but different arrangement in space هي + +220 +00:19:26,210 --> 00:19:30,550 +تعريف الـ Stereoisomers نفس الإرتباط ولكن يختلف + +221 +00:19:30,550 --> 00:19:33,610 +فيه الشكل بالفراغ + +222 +00:19:37,910 --> 00:19:43,110 +لما قلنا لـ Stereoisomers قلنا نوعين نوع منهم + +223 +00:19:43,110 --> 00:19:48,150 +بنسميه Diastereomers هنتعلمه و نوع منهم بنسميه + +224 +00:19:48,150 --> 00:19:54,330 +Enantiomers الآن هدولة المركبين مثال لأحد أنواع + +225 +00:19:54,330 --> 00:19:59,290 +الـ Stereoisomers الاتنين مثال للـ Diastereomers + +226 +00:19:59,290 --> 00:20:02,050 +Diastereomers + +227 +00:20:03,170 --> 00:20:06,650 +يعني لما ناخد الاستيريو ايزو مارز ونقول يقسموا إلى + +228 +00:20:06,650 --> 00:20:12,590 +نوعين داياستيريو مارز وانانشو مارز الانانشو مارز + +229 +00:20:12,590 --> 00:20:17,370 +هندرسهم بأي فصل بالفصل الخامس الداياستيريو مارز + +230 +00:20:17,370 --> 00:20:22,520 +الآن بيمروا عليناطيب لو واحدة بده تيجي تقول طب إيش + +231 +00:20:22,520 --> 00:20:26,660 +يعني بالظبط diastereomers؟ إيش يعني بالظبط + +232 +00:20:26,660 --> 00:20:31,540 +diastereomers؟ بنقول ببساطة التعريف العام التعريف + +233 +00:20:31,540 --> 00:20:35,780 +العام ل diastereomers ال diastereomers they are + +234 +00:20:35,780 --> 00:20:41,360 +non mirror image stereoisomers يعني stereoisomers + +235 +00:20:41,360 --> 00:20:47,140 +ولكن مش صورة بعض في المرآة يعني لو تخيلت أنا أنه + +236 +00:20:47,140 --> 00:20:52,280 +بين واحد والتانيفي بينهم مرايا، هل الواحد منهم + +237 +00:20:52,280 --> 00:20:57,060 +صورة التالف في المرآة ولا لأ؟ يعني تخيلوا أن أنا + +238 +00:20:57,060 --> 00:21:03,800 +هنا حطيت مرآة، دائما و أبدا، أمام المرآة كل جسم له + +239 +00:21:03,800 --> 00:21:11,800 +صورة، والصورة في المرآة دائما معاكسة تماما لصورة + +240 +00:21:11,800 --> 00:21:16,740 +الجسميعني لو أنا وقفت زي المرأة .. أمام المرأة + +241 +00:21:16,740 --> 00:21:22,720 +بهذا الشكل كل النظر تبعي باتجاهكم الآن الصورة اللي + +242 +00:21:22,720 --> 00:21:28,960 +في المرأة بكل أبعادها يجب أن تكون معاكسة لصورة + +243 +00:21:28,960 --> 00:21:35,380 +الجسم دائما صورة المرأة معاكسة لصورة الجسم بكل + +244 +00:21:35,380 --> 00:21:41,560 +مكوناتهاالان لو اتيت يا تورا اتسألت هل هدولة من + +245 +00:21:41,560 --> 00:21:47,360 +الاساس صورة مرآه ولا مش صورة مرآه؟ لاحظوا يمكن هنا + +246 +00:21:47,360 --> 00:21:50,600 +تلاقي كلور متجه باتجاه هذه عكسها وهذه الهيدروجين + +247 +00:21:50,600 --> 00:21:55,600 +باتجاه هذه عكسها يعني لحد هذه النقطةمعاكسات لكن + +248 +00:21:55,600 --> 00:22:01,280 +هنا في chlorine إقبالها hydrogen تحت هنا في + +249 +00:22:01,280 --> 00:22:05,140 +chlorine إقبالها hydrogen هل هدولة بيصيروا صورة + +250 +00:22:05,140 --> 00:22:11,730 +مرآة إذا بطلوا صورة مرآةشرط صورة المرآة أن كل جزء + +251 +00:22:11,730 --> 00:22:16,930 +من الجزيئات هيكون بعكس الجثة الآخر هدولة فيهم + +252 +00:22:16,930 --> 00:22:19,910 +أشياء أساسا مش اقبال .. مش .. يعني هذه لا فوق، + +253 +00:22:19,910 --> 00:22:25,650 +كلور اقبالها هيدروجين، إذا هدولة الشكلين الcess + +254 +00:22:25,650 --> 00:22:30,730 +والترانس لما أنا بدي أحكي عنهم بقول they are non + +255 +00:22:30,730 --> 00:22:38,720 +mirrorimages، إيش يعني non-mirror images؟ مش صورة + +256 +00:22:38,720 --> 00:22:42,120 +بعض في المرأة، الأشياء اللي بتكون مش صورة بعض في + +257 +00:22:42,120 --> 00:22:47,960 +المرأة هي اللي تعرف ان اسمها diastereomers، وهذا + +258 +00:22:47,960 --> 00:22:53,760 +مثال عليها، ف ال cicatrans، isomers، they are + +259 +00:22:53,760 --> 00:22:55,720 +diastereomers + +260 +00:22:57,420 --> 00:23:00,580 +They are non-mirror image stereoisomers, so they + +261 +00:23:00,580 --> 00:23:06,520 +are diastereomers فكتصنيف من أنواع الاستيريو ايزو + +262 +00:23:06,520 --> 00:23:10,460 +مارز، they are diastereomers واضح؟ ولذلك لو + +263 +00:23:10,460 --> 00:23:14,080 +جيبنالكم سؤال صح و غلط Sistransisomers are + +264 +00:23:14,080 --> 00:23:21,360 +stereoisomers صحالان لو بدى اسأل اكثر عمقًا + +265 +00:23:21,360 --> 00:23:26,640 +Sistransisomers are diastereomers برضه صح ما هي + +266 +00:23:26,640 --> 00:23:31,080 +diastereomers نوع لكن لو قلنا Sistransisomers are + +267 +00:23:31,080 --> 00:23:36,000 +enantiomers لأ و هنتعلم ال enantiomers مستقبلا لو + +268 +00:23:36,000 --> 00:23:42,280 +قلنا Sistransisomers are structural isomersبرضه + +269 +00:23:42,280 --> 00:23:47,080 +غلط لأ مش structural .. ال structural بيختلفوا في + +270 +00:23:47,080 --> 00:23:49,580 +ال bonding هدولة they have the same bonding ع واحد + +271 +00:23:49,580 --> 00:23:56,120 +و اتنين ع واحد و اتنين واضح؟ لكن هذا المركب و هذا + +272 +00:23:56,120 --> 00:24:00,180 +they are structural isomers بس ال cis trans + +273 +00:24:00,180 --> 00:24:04,400 +isomers are stereoisomers أي نوع من ال + +274 +00:24:04,400 --> 00:24:10,050 +stereoisomers تحديدا ده يا stereomersتطلعوا معي + +275 +00:24:10,050 --> 00:24:14,650 +مرة تانية نرسم أحد هدولة أو نعمل model لأحد هدولة + +276 +00:24:14,650 --> 00:24:18,950 +المركبات اللي هم ال sis, trans, isomers واضح؟ هذا + +277 +00:24:18,950 --> 00:24:25,810 +أي مركب فيهم؟ ال sis والتاني لترانس متى توجد عندنا + +278 +00:24:25,810 --> 00:24:29,840 +ظاهرة ال sis و الترانس؟يعني في ناس بيقولوا وقتش + +279 +00:24:29,840 --> 00:24:33,660 +بدأ اقول ان في عندى cis و trans او لأ بنقول القاتل + +280 +00:24:33,660 --> 00:24:38,740 +ظاهرة ال cis و ال trans توجد في مكانين اما في + +281 +00:24:38,740 --> 00:24:45,400 +الحلقات او المكان التاني حول الروابط الزوجية صار + +282 +00:24:45,400 --> 00:24:50,320 +عندى نقطة كتير مهمة ناس بدهم يفهموا كل موضوع + +283 +00:24:53,400 --> 00:24:58,400 +كل موضوع ال sis و ال trans وين عمره يمر علي كلمة + +284 +00:24:58,400 --> 00:25:07,120 +sis و ال trans بنقول ال sis و ال trans هتشوفهم + +285 +00:25:07,120 --> 00:25:18,180 +بمكانين sis و ال trans اما في ال cycles او في ال + +286 +00:25:18,180 --> 00:25:23,160 +alkenesالالكينز اللي فيها روابط الزوجين هذا المكان + +287 +00:25:23,160 --> 00:25:29,940 +اللي بتشوفه فيه كلمة sis و trans في ال cycles مثل + +288 +00:25:29,940 --> 00:25:35,680 +المثال اللي احنا رسمنا زي ما قولنا هذا مثلا بهذا + +289 +00:25:35,680 --> 00:25:43,400 +الشكل sis و بهذا الشكل ال trans هاي بال cycle اللي + +290 +00:25:43,400 --> 00:25:48,970 +اتعرفنا عليه طيب حوالين ال double bondنفس الاشي لو + +291 +00:25:48,970 --> 00:25:52,810 +تخيل انه عندنا carbon double bond carbon حطينا + +292 +00:25:52,810 --> 00:25:59,310 +زرتين كلور بهذا الشكل وهنا carbon double bond + +293 +00:25:59,310 --> 00:26:07,670 +carbon حطينا زرتين كلور بهذا الشكل هذا + +294 +00:26:07,670 --> 00:26:12,890 +إثالين وهذا إثالين هذولة زرتين كلور على واحد + +295 +00:26:12,890 --> 00:26:20,030 +واتنين على جهة واحدةانا على واحد و اتنين و اتنين + +296 +00:26:20,030 --> 00:26:24,370 +على جهتين مختلفتين اذا الاتنين اسمه one two + +297 +00:26:24,370 --> 00:26:33,450 +dichloroethane طب كيف بدي اميزهم هدوله sis و هدوله + +298 +00:26:33,450 --> 00:26:38,010 +ال trans هدوله ال sis و هدوله ال trans فدائرة ال + +299 +00:26:38,010 --> 00:26:42,570 +sis و ال trans مكان وجودها في الدنيا مكانين ال + +300 +00:26:42,570 --> 00:26:44,790 +cycloalkenes و + +301 +00:26:46,730 --> 00:26:51,230 +الالكايز الالكينز عفوا ليش هذا الكلام بيتم لأنه + +302 +00:26:51,230 --> 00:26:56,390 +انا لو جربت في cycle الكل بدي ألوف هذا هيك أخلي + +303 +00:26:56,390 --> 00:27:00,470 +هدول يصيروا عكس بعض يعني ال 6 يصير ال trans لاحظوا + +304 +00:27:00,470 --> 00:27:05,210 +لأنه مربوط بالحلقة الدوران حول الحلقة ممنوع + +305 +00:27:05,210 --> 00:27:11,210 +الدوران حول الحلقة ممنوع الان طيب لو اتخيلتوا ان + +306 +00:27:11,210 --> 00:27:19,360 +انا في عندهالكين وهي مُركّب الـ CIS مش هذا + +307 +00:27:19,360 --> 00:27:25,900 +المُركّب اللي مرسوم CIS 1,2-dichloroethane الأن + +308 +00:27:25,900 --> 00:27:31,860 +لاحظوا لو بدى ألف و أخلي هدولة يصيروا عكس بعضبرضه + +309 +00:27:31,860 --> 00:27:35,500 +لأن الرابطة الزوجية رابطة قوية الدوران حولها + +310 +00:27:35,500 --> 00:27:43,500 +ممنوعة إذا العامل المشترك في هذا الموضوع ما بين + +311 +00:27:43,500 --> 00:27:51,800 +الحلقة و ما بين الألكين أنه في الحالتين الدوران + +312 +00:27:51,800 --> 00:27:57,040 +ممنوعة لذلك مقدرش أنا أعمل دوران أحول واحد للتاني + +313 +00:27:59,010 --> 00:28:05,410 +فكل واحد منهم بيصير مركّب منفصل بخواص منفصلة بمعنى + +314 +00:28:05,410 --> 00:28:10,150 +لو واحدة راحت تشتري مركّب كيميائي جالت بدّي one + +315 +00:28:10,150 --> 00:28:15,030 +two dichlorocyclopropane البياحة يقولها مافيش + +316 +00:28:15,030 --> 00:28:20,230 +عندى، في عندى؟two bottles مرتبانين واحد بكتب عليه + +317 +00:28:20,230 --> 00:28:26,170 +sis والتاني trans واضح الفكرة زي لما الواحدة + +318 +00:28:26,170 --> 00:28:31,510 +بيجيها مولود مافيش يكون عشوائي يا ولد يا بنت لو + +319 +00:28:31,510 --> 00:28:37,030 +قلنا مثلا one two dichloroethaneروحنا نشتريه، + +320 +00:28:37,030 --> 00:28:42,930 +مافيش، هتلاقوا عند البائع two bottles مرتبان CES 1 + +321 +00:28:42,930 --> 00:28:49,270 +,2-dichloroethane بقواص معينة و بظائف معينة في + +322 +00:28:49,270 --> 00:28:54,590 +الحياة و هتلاقوا مركب تاني مختلف ال Trans و زي ما + +323 +00:28:54,590 --> 00:28:59,520 +قلنا العلاقة بين هدولة VRDiastereomers they are + +324 +00:28:59,520 --> 00:29:04,740 +non mirror images كلام سليم ولا لأ؟ مش صورة بعض في + +325 +00:29:04,740 --> 00:29:10,720 +المرأة في الخصائص + +326 +00:29:10,720 --> 00:29:16,420 +الفيزيائية أكيد و الكيميائية بيختلفوا في كل شيء + +327 +00:29:16,420 --> 00:29:21,910 +صاروا مركبينواضح مركبين they have different + +328 +00:29:21,910 --> 00:29:24,810 +physical properties، واحد من نقطة غليانه مثلا + +329 +00:29:24,810 --> 00:29:29,970 +سبعين، التانه نقطة غليانه تسعين، يختلفوا، واضح + +330 +00:29:29,970 --> 00:29:37,080 +الفكرة؟الان البعض احيانا بيقول طيب وكتش انا ممكن + +331 +00:29:37,080 --> 00:29:42,040 +يكون عندى ظاهرة ال sesual trance وانتبه لها اكثر و + +332 +00:29:42,040 --> 00:29:47,880 +وكتش لأ يعني لما أخدنا هذا المركب اللى حطينا فيه + +333 +00:29:47,880 --> 00:29:53,180 +chlorine و chlorine هنا طبعا اكيد هنا في hydrogen + +334 +00:29:53,180 --> 00:29:59,760 +ماجيبناش سيرة sesual tranceجيبناه إيش صيرت Sis & + +335 +00:29:59,760 --> 00:30:05,580 +Trans؟ وسمناها one-one-dichlorocyclo + +336 +00:30:05,580 --> 00:30:11,080 +-propane كذلك الحالة لو أنا انطلقت من الاثيليل + +337 +00:30:11,080 --> 00:30:16,540 +وحطيت ذرتين كلور على ال carbon الأولى يعني كان + +338 +00:30:16,540 --> 00:30:19,600 +عندى هذا المركب carbon double bond carbon .. + +339 +00:30:22,850 --> 00:30:26,870 +لو كان عندى هذا المركب carbon double bond carbon + +340 +00:30:26,870 --> 00:30:32,450 +وحطيت ذرتين كلور على الموقع الأول وقلنا إيش هذا + +341 +00:30:32,450 --> 00:30:39,880 +بدنا نسميهone one dichloroethane one one + +342 +00:30:39,880 --> 00:30:44,680 +dichloroethane مظبوط ولا لأ الان جيبنا هانة صيرت + +343 +00:30:44,680 --> 00:30:50,740 +cis و trans هان اه هان اه طيب بيصير سؤال وكتش + +344 +00:30:50,740 --> 00:30:54,360 +بيكون عندى ظاهرة ال cis و ال trans كلها موجودة + +345 +00:30:54,360 --> 00:31:00,220 +وكتش لأ الجواب بسيطبطلّع على الطرفين اللي بيحملوا + +346 +00:31:00,220 --> 00:31:03,920 +الذرات اللي هم الطرفين ال double bond أو الطرفين + +347 +00:31:03,920 --> 00:31:08,760 +اللي هنا إذا كانت كل ذرة تحمل مجموعتين مختلفتين + +348 +00:31:08,760 --> 00:31:11,760 +بيكون عند السيس و ترانس يعني هاي ال double bond + +349 +00:31:11,760 --> 00:31:19,200 +هادي غير هادي إذا هدوله مختلفتان ولا لأ هادي غير + +350 +00:31:19,200 --> 00:31:24,910 +هادي هدول مختلفتان و هدول مختلفتانإذا في عندي أكيد + +351 +00:31:24,910 --> 00:31:28,970 +من هذا المركب sis و trans هذا ال sis كيف بدي أجيب + +352 +00:31:28,970 --> 00:31:36,230 +لل trans؟ بال rotation؟ خليني أقول لو جيبنا لكوا + +353 +00:31:36,230 --> 00:31:42,070 +سؤال كيف نحول مركب ال sis إلى ال trans؟ أو نقول + +354 +00:31:42,070 --> 00:31:46,070 +sis compounds can be converted to trans by + +355 +00:31:46,070 --> 00:31:50,810 +rotation هاي الدوران جادر يلوف؟ لأ طب لو بدي أخلي + +356 +00:31:50,810 --> 00:31:58,660 +هذا ال sis transbond breaking bond formation اذا + +357 +00:31:58,660 --> 00:32:03,740 +انا كيف بحول السسلة ل Trans بال bond breaking و + +358 +00:32:03,740 --> 00:32:07,220 +bond formation بكسر الروابط و بحطها من اول و جديد + +359 +00:32:07,220 --> 00:32:11,150 +بس الدوران لا يؤدي الى هذا الكلامهنا صرت ما أعطيكم + +360 +00:32:11,150 --> 00:32:15,190 +كمان معلومتين إضافيتين عن ظاهرة الـ sexual trance + +361 +00:32:15,190 --> 00:32:20,110 +عشان توجد كظاهرة لابد كل carbon من أطراف الـ + +362 +00:32:20,110 --> 00:32:26,170 +double bond تحمل مجموعتين مختلفتينواضح؟ و لو بدى + +363 +00:32:26,170 --> 00:32:32,790 +احول ال 6 والترانس لازم اعمل + +364 +00:32:32,790 --> 00:32:36,870 +bond breaking و bond formation هذا الكلام بينطبق + +365 +00:32:36,870 --> 00:32:40,550 +على ال alkenes اللي فيهم ظاهرة ال 6 والترانس و + +366 +00:32:40,550 --> 00:32:46,810 +بينطبق أيضا على ال cycloalkenes كل هذه مفاهيم + +367 +00:32:46,810 --> 00:32:54,970 +أساسية و مهمة جدا في فعلنا لهذه الظاهرةالـ + +368 +00:32:54,970 --> 00:32:58,130 +Stereoisomers أو الـ Diastereomers اللي هي ظاهرة + +369 +00:32:58,130 --> 00:33:02,910 +الـ cis والترانس مكان وجودها الـ Cycloalkynes و + +370 +00:33:02,910 --> 00:33:09,230 +الـ Alkenes شرط وجودها ان كل طرف من الأطراف تبعت + +371 +00:33:09,230 --> 00:33:14,670 +ال carbons المكونة للـ double bond بتحمل مجموعتين + +372 +00:33:14,670 --> 00:33:17,890 +مختلفتين عشان ايك لو حد انا بدي احكي عن ال cis + +373 +00:33:17,890 --> 00:33:22,420 +والترانس هذه ال carbon شو بتحمل؟نفس المجموعات، هذا + +374 +00:33:22,420 --> 00:33:26,000 +ال carbo شو بتحمل؟ هذا شو بتحمل؟ أنا مافيش عنده ال + +375 +00:33:26,000 --> 00:33:31,060 +cis و ال trans، خلاص هو مركّب واحد، واضح؟ شرط فكرة + +376 +00:33:31,060 --> 00:33:37,870 +ال cis و ال trans أنه يكون عندهع كل طرف من أطراف + +377 +00:33:37,870 --> 00:33:41,250 +ال carbon سواء في الحلقة أو في ال double bond + +378 +00:33:41,250 --> 00:33:45,510 +مجموعات مختلفة ولذلك لو سألنا مثلا يا ترى هذا + +379 +00:33:45,510 --> 00:33:49,210 +المركب ال carbon double bond carbon وحطين هنا CL و + +380 +00:33:49,210 --> 00:33:54,690 +هنا CL و هنا H و هنا CL هل هذا في منه cis و trans؟ + +381 +00:33:54,690 --> 00:34:02,790 +لأ هذا فقط مركب واحد لأن هنا HCL مختلفة لكن نفس + +382 +00:34:02,790 --> 00:34:12,160 +الشيءو شرط ال sis و ال trans مختلفة مختلفة غير هيك + +383 +00:34:12,160 --> 00:34:18,320 +ما بنتكلمش عن sis و trans سواء كنا بنحكي في ال ال + +384 +00:34:18,320 --> 00:34:25,600 +keys أو كنا بنحكي في الحلقات ال cyclo ال keys + +385 +00:34:30,680 --> 00:34:36,320 +أتعمقنا كثير في الـ Cyclopropane لكن أخدنا معلومات + +386 +00:34:36,320 --> 00:34:42,820 +كثير مهمة بخصوص ظاهرة بتتكرر معنا سواء الآن أو في + +387 +00:34:42,820 --> 00:34:48,060 +المستقبل لما ندرس ال الكينز الآن لو إجيت لمركب + +388 +00:34:48,060 --> 00:34:50,380 +الـcyclobutane + +389 +00:34:53,020 --> 00:34:57,300 +كم هيدروجين فيه؟ أربع كربونات كل كربون تو + +390 +00:34:57,300 --> 00:35:03,960 +هيدروجين؟ تمانية التمانية they are equivalent يعني + +391 +00:35:03,960 --> 00:35:09,020 +لو كنت أعمل عليه monochlorination بطلع بس مركب + +392 +00:35:09,020 --> 00:35:14,340 +واحد لكن لو قلنا نبدأ بالcyclobutane ونعمل + +393 +00:35:14,340 --> 00:35:20,260 +dichlorination هيطلع عندنا أكيد عدد أكبر من + +394 +00:35:20,260 --> 00:35:24,940 +المركباتواضح؟ يعني انتوا تخيلوا مش كل شي بدنا + +395 +00:35:24,940 --> 00:35:28,500 +نفصله بدنا نسيب شي انتوا تجربوه في البيت يعني هي + +396 +00:35:28,500 --> 00:35:33,360 +عندى ذرة الكلور الأولى و هنا فيه H لو بدى أحط كلور + +397 +00:35:33,360 --> 00:35:41,880 +تانية ممكن أحطها على الموقع الأول اعمل one one + +398 +00:35:41,880 --> 00:35:46,200 +dichlorocyclopropane صحيه ولا لأ؟ ممكن أحطها على + +399 +00:35:46,200 --> 00:35:53,330 +الموقع التانيأو Trans ممكن احطه على الموقع التالت + +400 +00:35:53,330 --> 00:35:59,030 +ايضا SIS او Trans بمعنى في الحلقة مش ضروري مش + +401 +00:35:59,030 --> 00:36:02,830 +ضروري ان ال SIS و ال Trans يكونوا جانب بعض يعني + +402 +00:36:02,830 --> 00:36:09,910 +هاي تخيلوا هذا Cyclobutane تجاوزا هاي ذرتين لكلور + +403 +00:36:09,910 --> 00:36:15,960 +خلينا نتخيلهم باللون الأحمر هذا المركب اي مركبone + +404 +00:36:15,960 --> 00:36:22,040 +one-dichlorocyclobutane، الآن هذا المركّب one two + +405 +00:36:22,040 --> 00:36:30,660 +-cis، هذا one two-trans، هذا one three-cis، هذا + +406 +00:36:30,660 --> 00:36:36,200 +one three-transواضح؟ يعني مش ضروري ان ال sis و ال + +407 +00:36:36,200 --> 00:36:39,360 +trans في الحلقة انهم يكونوا جانب بعض ممكن يكونوا + +408 +00:36:39,360 --> 00:36:42,480 +على واحد اتنين او على واحد تلات في الحلقات الأكبر + +409 +00:36:42,480 --> 00:36:47,980 +ممكن يكونوا أبعد كمان واضح؟ بتظهر نقطة الحقيقة في + +410 +00:36:47,980 --> 00:36:54,020 +موضوع ال cyclobutane ان هل يا ترى ال cyclobutane + +411 +00:36:54,020 --> 00:37:00,440 +بلانربهذا الشكل؟ الجواب لو كنا بنطلع على الزوايا + +412 +00:37:00,440 --> 00:37:04,940 +تبعته بشكل دقيق هو مش planner هو شوية بيقول عنه + +413 +00:37:04,940 --> 00:37:09,500 +puckered يعني مثني شوية لجوا الان بيشبه ايش بهذا + +414 +00:37:09,500 --> 00:37:16,000 +الشكل الفراشة ال butterflyواضح؟ فالـ cyclobutane + +415 +00:37:16,000 --> 00:37:21,580 +is not a planar molecule مش موجود بهذا الشكل في + +416 +00:37:21,580 --> 00:37:27,640 +مستوى واحد لأ من ثاني شوية للداخل عامل زي الفراشة + +417 +00:37:27,640 --> 00:37:34,760 +بتعرفوا أنتوا كيف عادة بترسموا الفراشة؟ فأنا لو + +418 +00:37:34,760 --> 00:37:39,140 +بدأ أرسم ال cyclobutane بهذا الشكل بارسمه واحد + +419 +00:37:39,140 --> 00:37:41,840 +اتنين تلاتة أربع هذه الأربع كربونات + +420 +00:37:44,220 --> 00:37:51,580 +cyclobutane is not a planar molecule الان تقريبا + +421 +00:37:51,580 --> 00:37:58,240 +المعلومات بتصير تتكرر هنا قولنا زي الاش زي ال + +422 +00:37:58,240 --> 00:38:03,900 +butter fly اللي هي الفراشة طب لو بدى احكي عن + +423 +00:38:03,900 --> 00:38:08,000 +الcyclobutane معلومات ال cis و ال trans و ال + +424 +00:38:08,000 --> 00:38:13,160 +substitution نفس الشيءممكن تعملوا على اكثر من موقع + +425 +00:38:13,160 --> 00:38:19,400 +لكن لو كنت بده احط اول كلور العشرة هيدروجين هم + +426 +00:38:19,400 --> 00:38:24,800 +اكويفلانت عشان ايه لما بده اعمل monochlorination + +427 +00:38:24,800 --> 00:38:28,960 +يعني بس one كلور بده يطلع عندى مركب بعدين لما بده + +428 +00:38:28,960 --> 00:38:32,740 +اعمل dichlorination بطلع عندى اكثر من مركب + +429 +00:38:32,740 --> 00:38:36,900 +بإمكانكوا تحسبوهم و تجمعوهم طب يا تورا لو حكيت عن + +430 +00:38:36,900 --> 00:38:42,220 +الشكل تبعه هل هو planner؟الجواب لأ مش planner طب + +431 +00:38:42,220 --> 00:38:45,920 +هى زى إيش بيعمل الآن تخيلوا هى الحلقة الخماسية + +432 +00:38:45,920 --> 00:38:50,420 +شايفينها هى دى اللى أمامكوا حلقة خماسية ولا لأ؟ + +433 +00:38:50,420 --> 00:38:57,600 +واحد تانين تلاتة أربعة خمسة هيك بتكون planner لكن + +434 +00:38:57,600 --> 00:39:03,100 +هى عاملة بهذا الشكل الآن هذا الشكل لو كنا نعطيه + +435 +00:39:03,100 --> 00:39:09,040 +اسمبنقول عنه non planner أكيد لكن إله اسم أمركوا + +436 +00:39:09,040 --> 00:39:17,720 +شفتوا ضرف مغلف رسالة مفتوح it is like an open + +437 +00:39:17,720 --> 00:39:23,380 +envelope فهذا الشكل لو قلنا لكوا عنه planner لأ + +438 +00:39:23,380 --> 00:39:29,640 +هتقولوا it is like an open envelope اللي هو ضرف + +439 +00:39:29,640 --> 00:39:37,370 +رسالة مفتوح لو كنتوا بتكونوا ترسموهبشكل فراغي open + +440 +00:39:37,370 --> 00:39:41,350 +envelope مش envelope ال .. الظرف تبع الرسالة و + +441 +00:39:41,350 --> 00:39:45,050 +الموضوع it is like an open envelope لو بدي ارسمه + +442 +00:39:45,050 --> 00:39:49,990 +بهذا الشكل بارسمه فال Cyclopropane is a planar + +443 +00:39:49,990 --> 00:39:56,970 +Cyclobutane لأ Cyclopentane لأ الان لو انتقلنا بعد + +444 +00:39:56,970 --> 00:40:00,980 +هيك لل Cyclohexaneلاحظوا ال Cyclohexane الكلام + +445 +00:40:00,980 --> 00:40:04,100 +اللي موجود عليه في الدنيا كتير جدا احنا بنعطيه + +446 +00:40:04,100 --> 00:40:09,880 +مختصر للمختصر عليه ليش؟ لأن عليه كلام كتير لو كان + +447 +00:40:09,880 --> 00:40:15,340 +بهذا الشكل بيكون planner هي حلقة سدسية شايفينها + +448 +00:40:15,340 --> 00:40:19,780 +الواقع ان ال Cyclohexane مش زي هيك لما نتعلم في + +449 +00:40:19,780 --> 00:40:25,100 +chapter 4 عن البنزين البنزين زي هيك plannerالبنزين + +450 +00:40:25,100 --> 00:40:33,820 +C6H6 بلانر لكن الـCyclohexane ليس مليكيوم بلانر مش + +451 +00:40:33,820 --> 00:40:38,520 +بلانر طب ها كيف بينوجد؟ ممكن ينوجد على أكثر من + +452 +00:40:38,520 --> 00:40:42,860 +هيئة هيئة بيقول عنها confirmation confirmation + +453 +00:40:42,860 --> 00:40:47,820 +هيئة بمعنى ممكن نمسكه بهذا الشكل لاحظوا نفس الحلقة + +454 +00:40:47,820 --> 00:40:52,200 +شايفين كيف أنا مسكها؟الان هذا الشكل اللي انا ماسكه + +455 +00:40:52,200 --> 00:40:59,000 +يشبه ماذا؟ القارب او الزورق بسمي انا هيئة القارب + +456 +00:40:59,000 --> 00:41:04,740 +boat confirmation boat confirmation موجود عندكم + +457 +00:41:04,740 --> 00:41:13,520 +ربما بهذا المكان شايفينه؟ + +458 +00:41:14,650 --> 00:41:19,050 +بهذا الشكل بيرسم بسهولة boat conformation يمكن أن + +459 +00:41:19,050 --> 00:41:26,830 +يكون على هيئة القارب بهذا الشكل و يمكن أن يكون على + +460 +00:41:26,830 --> 00:41:34,270 +هيئة الكرسي لو تخيلته زي هيك هي كأنه هذا كرسي هي + +461 +00:41:34,270 --> 00:41:37,910 +الرجلين وهي القاعدة اللي الناس بيجلس عليها وهي + +462 +00:41:37,910 --> 00:41:42,100 +الظهرطبعا هذا ال chair confirmation و ال boat + +463 +00:41:42,100 --> 00:41:46,020 +confirmation بيجلبه يعني هذا الشكل زي ما بتكون + +464 +00:41:46,020 --> 00:41:51,040 +تماما معاكم الشمسية ال umbrella في يوم عاصف كيف + +465 +00:41:51,040 --> 00:41:56,960 +بتكون؟ بتجلب للأمام و للخلف؟ هاد العملية بسميها + +466 +00:41:56,960 --> 00:42:03,200 +عشان flipping الشكل لما بيصير يجلب بهذا الشكل لفوق + +467 +00:42:03,200 --> 00:42:06,940 +لتحت زي الشمسية ما بتعمل بسمي العملية عشان + +468 +00:42:06,940 --> 00:42:07,540 +flipping + +469 +00:42:10,670 --> 00:42:17,390 +flipping الآن ممكن الـcyclohexane يكون بلحظة boat + +470 +00:42:17,390 --> 00:42:22,970 +هذه تجلب لتحت صار chair لحظة هذا ال chair هيظهر + +471 +00:42:22,970 --> 00:42:26,790 +للخلف و الأرجل للأمام ممكن تجلب هذه الأرجل تصير + +472 +00:42:26,790 --> 00:42:31,830 +بهذا الشكل و بهذا الشكل هو في حالة تقلب دائم يعني + +473 +00:42:31,830 --> 00:42:37,390 +الذرات في حالة تقلب دائما تماما مثل مثل إيش شمسية + +474 +00:42:37,390 --> 00:42:41,930 +في مهب الريحمثل مثل ال umbrella أو الشمسية في ماب + +475 +00:42:41,930 --> 00:42:47,450 +بالريح إذا هو يمكن أن يوجد على هيئة القارب ويمكن + +476 +00:42:47,450 --> 00:42:54,680 +أن يوجد على هيئةالكرسي لـ Chair Conformation أو + +477 +00:42:54,680 --> 00:43:00,120 +Boat Conformation واضح؟ زي ما حكيت، كثير فيه + +478 +00:43:00,120 --> 00:43:04,080 +تفاصيل للهيدروجينات و التركيبة لكن احنا بنتجاوز + +479 +00:43:04,080 --> 00:43:08,780 +هذا الكلام، بنقف ان الـCyclohexane ممكن يكون على + +480 +00:43:08,780 --> 00:43:12,500 +شكل الـChair Conformation وبيعمل flipping، بيقلب + +481 +00:43:13,380 --> 00:43:19,880 +مرة تانية انا اكد عادى الظاهر هيه بهذا الشكل بيكون + +482 +00:43:19,880 --> 00:43:23,500 +share و بيصير boat و بيرجع ت share و ت share بهذا + +483 +00:43:23,500 --> 00:43:27,040 +الشكل و ت share بهذا الشكل هو في حالة تقلب ايش + +484 +00:43:27,040 --> 00:43:32,860 +دائم الان اي الأشكال اثبت معنى اثبت هنا انه بيقضي + +485 +00:43:32,860 --> 00:43:37,380 +في وقت كتير ال share ولا ال boat ال share بنقول + +486 +00:43:37,380 --> 00:43:43,580 +عنه is more stable than the boatmore stable معناه + +487 +00:43:43,580 --> 00:43:48,360 +more stable أنه أنا لو بتطلع عليه و هو بيجلب هو + +488 +00:43:48,360 --> 00:43:53,440 +يتقلب بين هذه الأشكال لكن يبقى لفترة أطول على هيئة + +489 +00:43:53,440 --> 00:43:58,580 +إيش الكرسي يبقى لفترة أطول على هيئة الكرسي الآن + +490 +00:43:58,580 --> 00:44:04,040 +عملية أنهليش لفترة أطول على هيئة الكرسي؟ ليش هذا + +491 +00:44:04,040 --> 00:44:08,140 +أثبت؟ ما إلى ذلك؟ هذا الكلام لطلبة مختصين في + +492 +00:44:08,140 --> 00:44:12,600 +الكيميا فيه تفصيل كتير، يعني اللي الآن بنحكيه بخمس + +493 +00:44:12,600 --> 00:44:17,480 +دقائق، بنعمله فصل كامل لطالب الكيميا يتعمق فيه + +494 +00:44:17,480 --> 00:44:20,140 +بالcyclohexane، لكن احنا الآن اللي بنايعه + +495 +00:44:20,140 --> 00:44:25,480 +الcyclohexaneكلام بسيط ان هو non planar molecule + +496 +00:44:25,480 --> 00:44:30,700 +يوجد فيه اكتر من conformation هيئة منها ال boat + +497 +00:44:30,700 --> 00:44:35,420 +conformation و ال chair conformation واضح ال boat + +498 +00:44:35,420 --> 00:44:39,120 +conformation و ال chair conformation اكتر من هيك + +499 +00:44:39,120 --> 00:44:45,770 +مابدناش نتكلم عن هذا الموضوعطبعا الكلام اللي هو + +500 +00:44:45,770 --> 00:44:50,290 +حكيناه عن الـcis و الـtrans في الحلقات الخماسية + +501 +00:44:50,290 --> 00:44:54,790 +والسوداسية والسبعية والربعية والثلاثية كله موجود + +502 +00:44:54,790 --> 00:45:00,910 +واضح؟ كله موجود أخر شغلة بدنا نتكلمها اليوم إن شاء + +503 +00:45:00,910 --> 00:45:09,660 +الله تفاعلات الالكانز تفاعلات الالكانزقليلة جدا، + +504 +00:45:09,660 --> 00:45:12,880 +عشانيك احنا بنقول الالكينز they are generally + +505 +00:45:12,880 --> 00:45:17,220 +inert، ايش يعني inert؟ يعني قليلة التفاعلات، + +506 +00:45:17,220 --> 00:45:21,540 +عشانيك كل اشي inert يستعمل ك solvent، يعني يستعمل + +507 +00:45:21,540 --> 00:45:25,680 +كمثيب عضوي، لأن الأشياء بتكون في قلبه و بتفعلش + +508 +00:45:25,680 --> 00:45:32,220 +معها، في تفاعل مشهور جدا للالكينز، ان الالكينز لو + +509 +00:45:32,220 --> 00:45:36,840 +حرقناهم في وجود الأكسجين، بيعطونا ثانو أكسيد كربون + +510 +00:45:36,840 --> 00:45:42,940 +وماءوهذا التفاعل هو تفاعل حرق الغاز المنزلي لما + +511 +00:45:42,940 --> 00:45:47,660 +احنا بنشعل الغاز هو تفاعل حرق على سبيل المثال + +512 +00:45:47,660 --> 00:45:53,220 +الوقود البنزين والديزل في السيارات كله الكان + +513 +00:45:53,220 --> 00:45:58,180 +بنحرقه في وجود ال oxygen بنسمي العملية combustion + +514 +00:45:58,180 --> 00:46:03,200 +إيش يعني combustion burning in the presence of + +515 +00:46:03,200 --> 00:46:09,540 +oxygen burning يعني burningin the presence of + +516 +00:46:09,540 --> 00:46:17,980 +oxygen ايش بيعطيني؟ ثاني أكسيد كربون وماء بدون ما + +517 +00:46:17,980 --> 00:46:21,480 +ندخل بتفاصيل الأرقام كيف توزن المعادلة مش الموضوع + +518 +00:46:21,480 --> 00:46:26,400 +احنا بهمنا الآن النتيجة ان الالكينز بصير التفاعل + +519 +00:46:26,400 --> 00:46:32,700 +مع الأكسجين تعطيتانو أكسيد كربون و ماء زائد و ربما + +520 +00:46:32,700 --> 00:46:37,880 +أهم من الشغلتين بالنسبة لنا ال heat الحرارة عشان + +521 +00:46:37,880 --> 00:46:41,380 +هيك حرق الغاز و حرق البنزين اللي بيعطيني حرارة + +522 +00:46:41,380 --> 00:46:45,700 +بشغل عليها موقد الغاز بمشي عليها السيارة كل هذه + +523 +00:46:45,700 --> 00:46:50,130 +الأشياءالشغل التاني أو التفاعل التاني ال + +524 +00:46:50,130 --> 00:46:54,270 +halogenation هو التفاعل مع ال halogens الكلور و + +525 +00:46:54,270 --> 00:46:58,690 +البرومي بشكل أساسي عادة يتم هذا التفاعل في وجود + +526 +00:46:58,690 --> 00:47:01,210 +الحرارة أو الضوء + +527 +00:47:17,340 --> 00:47:22,460 +كم عدد النواتج اللي بتطلع؟ يعتمد على أنواع + +528 +00:47:22,460 --> 00:47:27,240 +الهيدروجين يعني لو كان المركب اللي عندكم هو + +529 +00:47:27,240 --> 00:47:32,340 +البروبين زي ما احنا حكينا وين + +530 +00:47:32,340 --> 00:47:38,040 +هيحط ال chlorine؟ يا ع موقع واحد و ال chlorine و + +531 +00:47:38,040 --> 00:47:40,400 +البروبين يا ع موقع اتنين اتنين اتنين اتنين اتنين + +532 +00:47:40,400 --> 00:47:40,820 +اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين + +533 +00:47:40,820 --> 00:47:41,480 +اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين + +534 +00:47:41,480 --> 00:47:41,500 +اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين + +535 +00:47:41,500 --> 00:47:46,500 +اتنين اتنين اتنين اتنين اتنين اتنين ااو ايزوبروبل + +536 +00:47:46,500 --> 00:47:49,900 +اكلورايد لو نفس المراكب بيقولنا بيعمله + +537 +00:47:49,900 --> 00:47:56,090 +دايكلوريلاشينوين ممكن احض دارتين لكلور؟ يا على + +538 +00:47:56,090 --> 00:47:59,750 +نمرة واحد واحد بيصير one one dichlorobropane يا + +539 +00:47:59,750 --> 00:48:07,150 +على واحد واثنين يا ع اتنين واثنين او ع واحد واثنين + +540 +00:48:07,150 --> 00:48:11,170 +او ع واحد تلاتة اذا لو انا قلتلكم dichlorination + +541 +00:48:11,170 --> 00:48:16,210 +of a propane produces come isomers كي بتكون تعمله + +542 +00:48:16,210 --> 00:48:22,960 +و تجربه بالورقة و الجلمتستفيدوا من كل المعلومات + +543 +00:48:22,960 --> 00:48:28,720 +اللي حكيناها بمعنى لو كان السؤال عندكم عن cycle + +544 +00:48:28,720 --> 00:48:33,000 +بتعرفوا تجاوبوه احنا اليوم جاوبناها لـcyclopropane + +545 +00:48:33,000 --> 00:48:37,220 +قولنا الـ monochlorination بيعطينا كام مركب؟ واحد + +546 +00:48:37,220 --> 00:48:43,300 +ال-dichlorination بيعطينا كام مركب؟ تلاتةسمناهم + +547 +00:48:43,300 --> 00:48:48,640 +one one و one two six و one two .. Trans مظبوط ولا + +548 +00:48:48,640 --> 00:48:53,860 +لأ؟ و هكذا دائما ممكن يجيكم أسئلة و ممكن الأن + +549 +00:48:53,860 --> 00:48:58,540 +ماعطيكم سؤالين أنتوا تحلوهم لوحدكم تتدربوا عليهم و + +550 +00:48:58,540 --> 00:49:03,980 +بننهي فيهم المحاضرة لو مثلا قلنالكوا اعملونا لمركب + +551 +00:49:03,980 --> 00:49:11,980 +لبيوتينمونو إكلورينايشن ودايكلورينايشن تعملوه و + +552 +00:49:11,980 --> 00:49:16,400 +تسلمونا إياه و لهذا المُركّب لو تخيلتوا إنه في + +553 +00:49:16,400 --> 00:49:23,000 +عندكم مثل سايكلوبروبين شايفينه + +554 +00:49:23,000 --> 00:49:29,160 +المُركّب؟ إيش اسمه؟ مثل سايكلوبروبين اعملوله مونو + +555 +00:49:29,160 --> 00:49:34,510 +إكلورينايشنوDichlorination وشوفوا كم ناتج بيطلع + +556 +00:49:34,510 --> 00:49:38,230 +عندكم طبعا بتكونوا تنتبهوا ان الchlorination ممكن + +557 +00:49:38,230 --> 00:49:43,330 +يجي على المثل او على الحلقة بدي كل النواتج الممكنة + +558 +00:49:43,330 --> 00:49:47,830 +وهنا كل النواتج الممكنة هذا بحاجة انكوا تتدربوا + +559 +00:49:47,830 --> 00:49:52,700 +بشكل جيدو تعرفوا أنواع الهيدروجينز اللي موجودة و + +560 +00:49:52,700 --> 00:49:56,040 +تحددوا كام ناتج بيطلع عندهم من ال monochlorination + +561 +00:49:56,040 --> 00:50:00,340 +و ال dichlorination ترسموهم بعد ما ترسموهم انتبهوا + +562 +00:50:00,340 --> 00:50:05,180 +إذا في أشكال متشابهة انه ما تكرروهاش وبهيك بننهي + +563 +00:50:05,180 --> 00:50:06,040 +اليوم ان شاء الله + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..3ac3e3633704cdcd6730373a7adc2e64ee2ff88c --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 2007, "start": 18.78, "end": 20.08, "text": "بسم الله الرحمن الرحيم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640], "avg_logprob": -0.03093261569738388, "compression_ratio": 1.0789473684210527, 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نعمل", "tokens": [41185, 16095, 1975, 46456, 15040, 5172, 8978, 2423, 29029, 12558, 36764, 24401, 9154, 16095, 36764, 24401, 9154, 16095, 8961, 1563, 1311, 541, 16070, 2655, 7649, 1829, 9154, 16095, 9861, 1563, 1311, 541, 6024, 48506, 13672, 1829, 39894, 8848, 37983, 14407, 20449, 8315, 12174, 12610, 8315, 1975, 5016, 8315, 16472, 2423, 8961, 4032, 2423, 9861, 37551, 4724, 9381, 13546, 14407, 5296, 15042, 8717, 3794, 37983, 1975, 34740, 5954, 13672, 1829, 8608, 2304, 8315, 11296, 2423, 364, 14301, 299, 5954, 4032, 8717, 25957, 1211], "avg_logprob": -0.21084337852087365, "compression_ratio": 1.6802030456852792, "no_speech_prob": 0.0, "words": [{"start": 123.47, "end": 123.85, "word": "فيهم", "probability": 0.85888671875}, {"start": 123.85, "end": 124.55, "word": " اختلاف", "probability": 0.9493408203125}, {"start": 124.55, "end": 125.01, "word": " في", "probability": 0.95458984375}, {"start": 125.01, "end": 125.11, "word": " ال", "probability": 0.88525390625}, {"start": 125.11, "end": 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فاتنين", "probability": 0.8660888671875}, {"start": 217.46, "end": 218.08, "word": " اتصلوا", "probability": 0.982421875}, {"start": 218.08, "end": 218.24, "word": " مع", "probability": 0.9951171875}, {"start": 218.24, "end": 218.74, "word": " بعض", "probability": 0.997314453125}, {"start": 218.74, "end": 219.12, "word": " من", "probability": 0.9931640625}, {"start": 219.12, "end": 219.54, "word": " خلال", "probability": 0.99462890625}, {"start": 219.54, "end": 220.16, "word": " موقع", "probability": 0.9879557291666666}, {"start": 220.16, "end": 221.32, "word": " اربعة", "probability": 0.8104654947916666}, {"start": 221.32, "end": 221.72, "word": " لما", "probability": 0.862060546875}, {"start": 221.72, "end": 222.06, "word": " ناخد", "probability": 0.9869791666666666}, {"start": 222.06, "end": 222.54, "word": " الترقيم", "probability": 0.975341796875}, {"start": 222.54, "end": 222.82, "word": " واحد", "probability": 0.74267578125}, {"start": 222.82, "end": 223.16, "word": " اتنين", 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746.83, "text": "بيتا واضح؟ اذا هذا بيتا عشانك هتلاقوا الاسم تبعه اعتبروا ان هذا هو الأصل وهذه هي الاش المجموعة اللي جاية على الأصل واضح؟ فهتلاحظوا بيتا دي فراكتو فيورانوزيل طبعا فيورانوزيل لأنه جاي ايش؟ مجموعة متحدة مع الف دي غلوكو", "tokens": [3555, 36081, 995, 4032, 46958, 5016, 22807, 1975, 15730, 23758, 4724, 36081, 995, 6225, 8592, 7649, 4117, 8032, 2655, 15040, 4587, 14407, 2423, 32277, 2304, 6055, 3555, 3615, 3224, 1975, 34268, 26890, 14407, 16472, 23758, 31439, 16247, 36520, 37037, 24192, 39896, 2423, 33599, 9673, 7435, 2304, 2407, 27884, 13672, 1829, 10874, 995, 10632, 15844, 16247, 36520, 4032, 46958, 5016, 22807, 6156, 3224, 2655, 15040, 5016, 19913, 14407, 4724, 36081, 995, 11778, 1829, 6156, 23557, 4117, 2655, 2407, 8978, 13063, 7649, 2407, 11622, 26895, 23032, 3555, 3615, 995, 8978, 13063, 7649, 2407, 11622, 26895, 5296, 33456, 3224, 10874, 47302, 1975, 1829, 8592, 22807, 3714, 7435, 2304, 2407, 27884, 44650, 24401, 3660, 20449, 2423, 5172, 11778, 1829, 32771, 1211, 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"end": 1492.84, "word": " يعني", "probability": 0.883544921875}, {"start": 1492.84, "end": 1493.46, "word": " الجولوكوز", "probability": 0.9373372395833334}, {"start": 1493.46, "end": 1493.88, "word": " units", "probability": 0.9228515625}, {"start": 1493.88, "end": 1494.26, "word": " اللى", "probability": 0.861083984375}, {"start": 1494.26, "end": 1494.46, "word": " في", "probability": 0.7919921875}, {"start": 1494.46, "end": 1495.16, "word": " عددها", "probability": 0.88330078125}, {"start": 1495.16, "end": 1495.94, "word": " اكبر", "probability": 0.8914388020833334}, {"start": 1495.94, "end": 1496.6, "word": " لكن", "probability": 0.8525390625}, {"start": 1496.6, "end": 1497.06, "word": " اهم", "probability": 0.957763671875}, {"start": 1497.06, "end": 1497.56, "word": " شغل", "probability": 0.7736002604166666}, {"start": 1497.56, "end": 1498.18, "word": " فيه", "probability": 0.723388671875}, {"start": 1498.18, "end": 1499.86, "word": " is", "probability": 0.55029296875}, {"start": 1499.86, "end": 1500.94, "word": " هايلبراجد", "probability": 0.5816243489583334}, {"start": 1500.94, "end": 1501.68, "word": " واضح", "probability": 0.8636067708333334}, {"start": 1501.68, "end": 1502.46, "word": " يعني", "probability": 0.693115234375}, {"start": 1502.46, "end": 1503.54, "word": " الاميلوز", "probability": 0.97587890625}, {"start": 1503.54, "end": 1504.8, "word": " سلسلة", "probability": 0.9918212890625}], "temperature": 1.0}, {"id": 64, "seek": 153058, "start": 1505.64, "end": 1530.58, "text": "الـ amylobectin في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300 إلى 5000 جولوكوز units is a highly branched molecule او highly branched molecule chains with consecutive one four links شوفنا كيف one four links الارتباط ال average يعني كل مجموعة حوالي خمسة وعشرين لتلاتين وحدة", "tokens": [6027, 39184, 669, 5088, 996, 557, 259, 8978, 6055, 5172, 2288, 3615, 9307, 37495, 22653, 6055, 4587, 16572, 3555, 995, 20193, 5016, 19913, 14407, 2423, 39184, 669, 5088, 541, 49374, 6641, 30731, 23777, 10874, 12610, 2407, 4117, 2407, 11622, 6815, 307, 257, 5405, 9819, 292, 15582, 1975, 2407, 5405, 9819, 292, 15582, 12626, 365, 30497, 472, 1451, 6123, 13412, 38688, 8315, 9122, 33911, 472, 1451, 6123, 2423, 9640, 2655, 3555, 41193, 2423, 4274, 37495, 22653, 28242, 3714, 7435, 2304, 2407, 27884, 11331, 2407, 6027, 1829, 16490, 2304, 3794, 3660, 4032, 3615, 46309, 9957, 5296, 2655, 1211, 9307, 9957, 4032, 24401, 3660], "avg_logprob": -0.2553615052910412, "compression_ratio": 1.5222672064777327, "no_speech_prob": 0.0, "words": [{"start": 1505.64, "end": 1505.94, "word": "الـ", "probability": 0.4827880859375}, {"start": 1505.94, "end": 1506.92, "word": " amylobectin", "probability": 0.76015625}, {"start": 1506.92, "end": 1507.82, "word": " في", "probability": 0.53759765625}, {"start": 1507.82, "end": 1508.86, "word": " تفرعات", "probability": 0.87353515625}, {"start": 1508.86, "end": 1509.34, "word": " يعني", "probability": 0.718017578125}, {"start": 1509.34, "end": 1510.14, "word": " تقريبا", "probability": 0.981640625}, {"start": 1510.14, "end": 1511.88, "word": " لاحظوا", "probability": 0.8411865234375}, {"start": 1511.88, "end": 1512.16, "word": " الـ", "probability": 0.52734375}, {"start": 1512.16, "end": 1512.7, "word": " amylose", "probability": 0.8053385416666666}, {"start": 1512.7, "end": 1512.94, "word": " بين", "probability": 0.89306640625}, {"start": 1512.94, "end": 1513.44, "word": " 300", "probability": 0.54052734375}, {"start": 1513.44, "end": 1513.78, "word": " إلى", "probability": 0.6484375}, {"start": 1513.78, "end": 1514.2, "word": " 5000", "probability": 0.84130859375}, {"start": 1514.2, "end": 1514.9, "word": " جولوكوز", "probability": 0.759033203125}, {"start": 1514.9, "end": 1515.24, "word": " units", "probability": 0.37255859375}, {"start": 1515.24, "end": 1515.86, "word": " is", "probability": 0.4345703125}, {"start": 1515.86, "end": 1516.26, "word": " a", "probability": 0.8994140625}, {"start": 1516.26, "end": 1516.56, "word": " highly", "probability": 0.87841796875}, {"start": 1516.56, "end": 1517.22, "word": " branched", "probability": 0.855224609375}, {"start": 1517.22, "end": 1517.74, "word": " molecule", "probability": 0.611328125}, {"start": 1517.74, "end": 1519.4, "word": " او", "probability": 0.658203125}, {"start": 1519.4, "end": 1519.7, "word": " highly", "probability": 0.75537109375}, {"start": 1519.7, "end": 1520.22, "word": " branched", "probability": 0.906494140625}, {"start": 1520.22, "end": 1520.54, "word": " molecule", "probability": 0.43115234375}, {"start": 1520.54, "end": 1521.1, "word": " chains", "probability": 0.6328125}, {"start": 1521.1, "end": 1521.66, "word": " with", "probability": 0.90673828125}, {"start": 1521.66, "end": 1522.28, "word": " consecutive", "probability": 0.94287109375}, {"start": 1522.28, "end": 1522.68, "word": " one", "probability": 0.431396484375}, {"start": 1522.68, "end": 1522.94, "word": " four", "probability": 0.56689453125}, {"start": 1522.94, "end": 1523.26, "word": " links", "probability": 0.79248046875}, {"start": 1523.26, "end": 1523.7, "word": " شوفنا", "probability": 0.7540690104166666}, {"start": 1523.7, "end": 1523.9, "word": " كيف", "probability": 0.961181640625}, {"start": 1523.9, "end": 1524.14, "word": " one", "probability": 0.76318359375}, {"start": 1524.14, "end": 1524.36, "word": " four", "probability": 0.93212890625}, {"start": 1524.36, "end": 1524.6, "word": " links", "probability": 0.9384765625}, {"start": 1524.6, "end": 1525.36, "word": " الارتباط", "probability": 0.8798828125}, {"start": 1525.36, "end": 1525.96, "word": " ال", "probability": 0.89990234375}, {"start": 1525.96, "end": 1526.6, "word": " average", "probability": 0.5234375}, {"start": 1526.6, "end": 1527.14, "word": " يعني", "probability": 0.985595703125}, {"start": 1527.14, "end": 1527.38, "word": " كل", "probability": 0.9609375}, {"start": 1527.38, "end": 1528.04, "word": " مجموعة", "probability": 0.94873046875}, {"start": 1528.04, "end": 1528.52, "word": " حوالي", "probability": 0.96630859375}, {"start": 1528.52, "end": 1528.84, "word": " خمسة", "probability": 0.7772216796875}, {"start": 1528.84, "end": 1529.32, "word": " وعشرين", "probability": 0.8521728515625}, {"start": 1529.32, "end": 1530.0, "word": " لتلاتين", "probability": 0.88154296875}, {"start": 1530.0, "end": 1530.58, "word": " وحدة", "probability": 0.8484700520833334}], "temperature": 1.0}, {"id": 65, "seek": 155705, "start": 1532.37, "end": 1557.05, "text": "و بعدين بيجي تفرع 25 ل 30 و تفرع بيصير الجزء أشماله highly branched واضح فواضح أن جزء ال amylobectin أكبر من ال amylose و بنفس الوقت اللي بيميزه التفرعات واضح فال amylose is a chain molecule", "tokens": [2407, 39182, 9957, 4724, 1829, 7435, 1829, 6055, 5172, 2288, 3615, 3552, 5296, 2217, 4032, 6055, 5172, 2288, 3615, 4724, 1829, 9381, 13546, 25724, 11622, 38207, 5551, 8592, 2304, 6027, 3224, 5405, 9819, 292, 4032, 46958, 5016, 6156, 2407, 46958, 5016, 14739, 10874, 11622, 38207, 2423, 669, 5088, 996, 557, 259, 5551, 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{"start": 1535.29, "end": 1535.87, "word": " تفرع", "probability": 0.980224609375}, {"start": 1535.87, "end": 1536.51, "word": " بيصير", "probability": 0.88720703125}, {"start": 1536.51, "end": 1537.01, "word": " الجزء", "probability": 0.7457682291666666}, {"start": 1537.01, "end": 1537.93, "word": " أشماله", "probability": 0.812548828125}, {"start": 1537.93, "end": 1539.45, "word": " highly", "probability": 0.429931640625}, {"start": 1539.45, "end": 1540.57, "word": " branched", "probability": 0.869384765625}, {"start": 1540.57, "end": 1541.11, "word": " واضح", "probability": 0.8714192708333334}, {"start": 1541.11, "end": 1543.13, "word": " فواضح", "probability": 0.81195068359375}, {"start": 1543.13, "end": 1543.37, "word": " أن", "probability": 0.463134765625}, {"start": 1543.37, "end": 1543.89, "word": " جزء", "probability": 0.9052734375}, {"start": 1543.89, "end": 1544.05, "word": " ال", "probability": 0.8408203125}, {"start": 1544.05, "end": 1545.19, "word": " amylobectin", "probability": 0.74677734375}, {"start": 1545.19, "end": 1546.21, "word": " أكبر", "probability": 0.9571940104166666}, {"start": 1546.21, "end": 1547.23, "word": " من", "probability": 0.98583984375}, {"start": 1547.23, "end": 1547.49, "word": " ال", "probability": 0.927734375}, {"start": 1547.49, "end": 1548.17, "word": " amylose", "probability": 0.8771158854166666}, {"start": 1548.17, "end": 1548.47, "word": " و", "probability": 0.8310546875}, {"start": 1548.47, "end": 1548.85, "word": " بنفس", "probability": 0.7275390625}, {"start": 1548.85, "end": 1549.51, "word": " الوقت", "probability": 0.9814453125}, {"start": 1549.51, "end": 1550.47, "word": " اللي", "probability": 0.885498046875}, {"start": 1550.47, "end": 1551.25, "word": " بيميزه", "probability": 0.947265625}, {"start": 1551.25, "end": 1553.07, "word": " التفرعات", "probability": 0.9775390625}, {"start": 1553.07, "end": 1553.77, "word": " واضح", "probability": 0.7765299479166666}, {"start": 1553.77, "end": 1554.37, "word": " فال", "probability": 0.82666015625}, {"start": 1554.37, "end": 1555.15, "word": " amylose", "probability": 0.8782552083333334}, {"start": 1555.15, "end": 1555.93, "word": " is", "probability": 0.8837890625}, {"start": 1555.93, "end": 1556.11, "word": " a", "probability": 0.62451171875}, {"start": 1556.11, "end": 1556.45, "word": " chain", "probability": 0.70361328125}, {"start": 1556.45, "end": 1557.05, "word": " molecule", "probability": 0.818359375}], "temperature": 1.0}, {"id": 66, "seek": 158206, "start": 1558.1, "end": 1582.06, "text": "الـ amylobectin هو جزئ عالي جزئ فيه تفرعات كتيرة طبعا هذه كل أشكال تقريبية بتوضح لنا كيف بيتكونوا هذول الجزيئات الأن لو جينا من ال amylose أيضا", "tokens": [6027, 39184, 669, 5088, 996, 557, 259, 31439, 10874, 11622, 19986, 6225, 6027, 1829, 10874, 11622, 19986, 8978, 3224, 6055, 5172, 2288, 3615, 9307, 9122, 2655, 48923, 23032, 3555, 3615, 995, 29538, 28242, 5551, 8592, 4117, 6027, 6055, 4587, 16572, 3555, 10632, 39894, 2407, 11242, 5016, 5296, 8315, 9122, 33911, 4724, 36081, 30544, 14407, 8032, 8848, 12610, 25724, 11622, 1829, 19986, 9307, 16247, 1863, 45164, 10874, 1829, 8315, 9154, 2423, 669, 5088, 541, 36632, 11242, 995], "avg_logprob": -0.34111202072787594, "compression_ratio": 1.4578313253012047, "no_speech_prob": 0.0, "words": [{"start": 1558.1, "end": 1558.54, "word": "الـ", "probability": 0.656494140625}, {"start": 1558.54, "end": 1559.6, "word": " amylobectin", "probability": 0.7111328125}, {"start": 1559.6, "end": 1560.32, "word": " هو", "probability": 0.360107421875}, {"start": 1560.32, "end": 1561.3, "word": " جزئ", "probability": 0.6035970052083334}, {"start": 1561.3, "end": 1561.5, "word": " عالي", "probability": 0.4833984375}, {"start": 1561.5, "end": 1562.22, "word": " جزئ", "probability": 0.5435384114583334}, {"start": 1562.22, "end": 1564.36, "word": " فيه", "probability": 0.5411376953125}, {"start": 1564.36, "end": 1565.08, "word": " تفرعات", "probability": 0.91865234375}, {"start": 1565.08, "end": 1565.58, "word": " كتيرة", "probability": 0.8229166666666666}, {"start": 1565.58, "end": 1566.64, "word": " طبعا", "probability": 0.93408203125}, {"start": 1566.64, "end": 1567.38, "word": " هذه", "probability": 0.391845703125}, {"start": 1567.38, "end": 1567.66, "word": " كل", "probability": 0.97021484375}, {"start": 1567.66, "end": 1568.1, "word": " أشكال", "probability": 0.9420166015625}, {"start": 1568.1, "end": 1568.98, "word": " تقريبية", "probability": 0.96083984375}, {"start": 1568.98, "end": 1571.52, "word": " بتوضح", "probability": 0.85791015625}, {"start": 1571.52, "end": 1571.86, "word": " لنا", "probability": 0.875}, {"start": 1571.86, "end": 1572.26, "word": " كيف", "probability": 0.974853515625}, {"start": 1572.26, "end": 1573.02, "word": " بيتكونوا", "probability": 0.63775634765625}, {"start": 1573.02, "end": 1573.5, "word": " هذول", "probability": 0.7300618489583334}, {"start": 1573.5, "end": 1574.42, "word": " الجزيئات", "probability": 0.74697265625}, {"start": 1574.42, "end": 1577.34, "word": " الأن", "probability": 0.6302490234375}, {"start": 1577.34, "end": 1579.32, "word": " لو", "probability": 0.93896484375}, {"start": 1579.32, "end": 1579.88, "word": " جينا", "probability": 0.7211100260416666}, {"start": 1579.88, "end": 1580.56, "word": " من", "probability": 0.970703125}, {"start": 1580.56, "end": 1580.72, "word": " ال", "probability": 0.89990234375}, {"start": 1580.72, "end": 1581.46, "word": " amylose", "probability": 0.5750325520833334}, {"start": 1581.46, "end": 1582.06, "word": " أيضا", "probability": 0.9630533854166666}], "temperature": 1.0}, {"id": 67, "seek": 160363, "start": 1583.21, "end": 1603.63, "text": "غير النشق بمكوينه يعني من الملتوز كان في عنده ال starch اللي هو مكوّن من amylose و mylobectin أيضًا من الملتوز في عنده الجليكوجين ال starch ما كان تخزين ال carbohydrates", "tokens": [17082, 13546, 28239, 8592, 4587, 4724, 2304, 4117, 2407, 9957, 3224, 37495, 22653, 9154, 2423, 42213, 2655, 2407, 11622, 25961, 8978, 43242, 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{"start": 1870.6, "end": 1870.86, "word": " beta", "probability": 0.76123046875}, {"start": 1870.86, "end": 1872.1, "word": " glycosidase", "probability": 0.834228515625}, {"start": 1872.1, "end": 1873.36, "word": " اللى", "probability": 0.9912109375}, {"start": 1873.36, "end": 1874.06, "word": " بتساعد", "probability": 0.98583984375}, {"start": 1874.06, "end": 1874.32, "word": " على", "probability": 0.7138671875}, {"start": 1874.32, "end": 1874.92, "word": " عملية", "probability": 0.98974609375}, {"start": 1874.92, "end": 1875.36, "word": " ايش", "probability": 0.6590169270833334}, {"start": 1875.36, "end": 1875.88, "word": " ان", "probability": 0.5068359375}, {"start": 1875.88, "end": 1876.34, "word": " تقدر", "probability": 0.7724609375}, {"start": 1876.34, "end": 1876.78, "word": " تهضم", "probability": 0.9630126953125}, {"start": 1876.78, "end": 1877.4, "word": " الخشب", "probability": 0.9845377604166666}, {"start": 1877.4, "end": 1878.22, "word": " وتستفيد", "probability": 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"probability": 0.9293619791666666}, {"start": 1889.54, "end": 1889.82, "word": " ايش", "probability": 0.76171875}, {"start": 1889.82, "end": 1890.16, "word": " هذا", "probability": 0.52392578125}], "temperature": 1.0}, {"id": 80, "seek": 190609, "start": 1891.33, "end": 1906.09, "text": "النزيم Oxidase و Redactase و glycosidase and they can hydrolyze يعني يفككوا ال cellulose فلو احنا قلنالكم ان ال humans can hydrolyze cellulose", "tokens": [6027, 1863, 11622, 32640, 16489, 327, 651, 4032, 4477, 578, 651, 4032, 22633, 6877, 327, 651, 293, 436, 393, 15435, 356, 1381, 37495, 22653, 7251, 5172, 4117, 4117, 14407, 2423, 2815, 425, 541, 6156, 1211, 2407, 1975, 5016, 8315, 12174, 1211, 8315, 23275, 2304, 16472, 2423, 6255, 393, 15435, 356, 1381, 2815, 425, 541], "avg_logprob": -0.2980113679712469, "compression_ratio": 1.3043478260869565, "no_speech_prob": 0.0, "words": [{"start": 1891.33, "end": 1891.91, "word": "النزيم", "probability": 0.440155029296875}, {"start": 1891.91, "end": 1893.39, "word": " Oxidase", "probability": 0.6379597981770834}, {"start": 1893.39, "end": 1893.51, "word": " و", "probability": 0.927734375}, {"start": 1893.51, "end": 1894.35, "word": " Redactase", "probability": 0.7019856770833334}, {"start": 1894.35, "end": 1894.57, "word": " و", "probability": 0.9736328125}, {"start": 1894.57, "end": 1895.81, "word": " glycosidase", "probability": 0.77606201171875}, {"start": 1895.81, "end": 1896.33, "word": " and", "probability": 0.341796875}, {"start": 1896.33, "end": 1896.57, "word": " they", "probability": 0.8798828125}, {"start": 1896.57, "end": 1896.81, "word": " can", "probability": 0.93798828125}, {"start": 1896.81, "end": 1897.87, "word": " hydrolyze", "probability": 0.78173828125}, {"start": 1897.87, "end": 1898.15, "word": " يعني", "probability": 0.9072265625}, {"start": 1898.15, "end": 1898.97, "word": " يفككوا", "probability": 0.93525390625}, {"start": 1898.97, "end": 1899.79, "word": " ال", "probability": 0.7333984375}, {"start": 1899.79, "end": 1900.41, "word": " cellulose", "probability": 0.8203125}, {"start": 1900.41, "end": 1901.27, "word": " فلو", "probability": 0.9322916666666666}, {"start": 1901.27, "end": 1901.45, "word": " احنا", "probability": 0.8689778645833334}, {"start": 1901.45, "end": 1902.25, "word": " قلنالكم", "probability": 0.8591796875}, {"start": 1902.25, "end": 1902.65, "word": " ان", "probability": 0.88671875}, {"start": 1902.65, "end": 1902.81, "word": " ال", "probability": 0.42138671875}, {"start": 1902.81, "end": 1903.35, "word": " humans", "probability": 0.61572265625}, {"start": 1903.35, "end": 1903.97, "word": " can", "probability": 0.83837890625}, {"start": 1903.97, "end": 1904.99, "word": " hydrolyze", "probability": 0.9344075520833334}, {"start": 1904.99, "end": 1906.09, "word": " cellulose", "probability": 0.9615885416666666}], "temperature": 1.0}, {"id": 81, "seek": 193717, "start": 1908.21, "end": 1937.17, "text": "واضح؟ لكن في بكتيريا كتير بتقدر تعمل هذا الكلام هذه موجودة في ال termites اللي هو النمل الأبيض و ال ruminants اللي هي الحيوانات المجترة اللي بتلاقوها مستعدة تاكل ال .. إيش؟ زي الجمل و زي .. أه اللي بتاكل الخشب فبكتيريا في معدتها بتقدر تدخل على هذا الخشب و تحلله لوحدات السكر بحيث أنه النمل الأبيض أو الحيوانات هذه المجترة تقدر تستفيد منه", "tokens": [2407, 46958, 5016, 22807, 44381, 8978, 4724, 4117, 2655, 13546, 25528, 9122, 2655, 13546, 39894, 28543, 2288, 6055, 25957, 1211, 23758, 2423, 28820, 10943, 29538, 3714, 29245, 23328, 3660, 8978, 2423, 1433, 3324, 13672, 1829, 31439, 28239, 42213, 16247, 21292, 11242, 4032, 2423, 367, 7112, 1719, 13672, 1829, 39896, 21542, 1829, 2407, 7649, 9307, 9673, 7435, 2655, 25720, 13672, 1829, 39894, 15040, 4587, 2407, 11296, 3714, 14851, 22488, 3660, 6055, 995, 28820, 2423, 4386, 11933, 1829, 8592, 22807, 30767, 1829, 25724, 42213, 4032, 30767, 1829, 4386, 5551, 3224, 13672, 1829, 39894, 995, 28820, 33962, 8592, 3555, 6156, 3555, 4117, 2655, 13546, 25528, 8978, 20449, 3215, 2655, 11296, 39894, 28543, 2288, 6055, 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"end": 1921.37, "word": " ..", "probability": 0.2412109375}, {"start": 1921.37, "end": 1921.73, "word": " إيش؟", "probability": 0.816650390625}, {"start": 1921.73, "end": 1921.93, "word": " زي", "probability": 0.958251953125}, {"start": 1921.93, "end": 1922.39, "word": " الجمل", "probability": 0.9326171875}, {"start": 1922.39, "end": 1922.55, "word": " و", "probability": 0.92822265625}, {"start": 1922.55, "end": 1922.69, "word": " زي", "probability": 0.9765625}, {"start": 1922.69, "end": 1923.05, "word": " ..", "probability": 0.91455078125}, {"start": 1923.05, "end": 1923.25, "word": " أه", "probability": 0.7457275390625}, {"start": 1923.25, "end": 1923.41, "word": " اللي", "probability": 0.975341796875}, {"start": 1923.41, "end": 1923.85, "word": " بتاكل", "probability": 0.9894205729166666}, {"start": 1923.85, "end": 1924.65, "word": " الخشب", "probability": 0.97802734375}, {"start": 1924.65, "end": 1925.87, "word": " فبكتيريا", "probability": 0.9515787760416666}, {"start": 1925.87, 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1932.33, "end": 1932.69, "word": " أنه", "probability": 0.688232421875}, {"start": 1932.69, "end": 1933.45, "word": " النمل", "probability": 0.86669921875}, {"start": 1933.45, "end": 1934.07, "word": " الأبيض", "probability": 0.9925130208333334}, {"start": 1934.07, "end": 1934.27, "word": " أو", "probability": 0.78515625}, {"start": 1934.27, "end": 1935.15, "word": " الحيوانات", "probability": 0.98515625}, {"start": 1935.15, "end": 1935.35, "word": " هذه", "probability": 0.880859375}, {"start": 1935.35, "end": 1935.83, "word": " المجترة", "probability": 0.986328125}, {"start": 1935.83, "end": 1936.21, "word": " تقدر", "probability": 0.9072265625}, {"start": 1936.21, "end": 1936.79, "word": " تستفيد", "probability": 0.9881591796875}, {"start": 1936.79, "end": 1937.17, "word": " منه", "probability": 0.994140625}], "temperature": 1.0}, {"id": 82, "seek": 196549, "start": 1938.13, "end": 1965.49, "text": "أو من السكر اللي موجود فيه لكن البني آدم مابيقدرش يخدمه أخر شغلة أخر شغلة بنحكيها بالنسبة لهذا الجزء أنه في عندى بعض ال sugars يمكن أن ينزع منها أكسجين هذه بتفيدنا لما بدنا ندرس ال nuclear acid اللي هي الأحماض النووية ومنها", "tokens": [10721, 2407, 9154, 21136, 37983, 13672, 1829, 3714, 29245, 23328, 8978, 3224, 44381, 29739, 22653, 19753, 40448, 3714, 16758, 1829, 28543, 2288, 8592, 7251, 9778, 40448, 3224, 5551, 34740, 13412, 17082, 37977, 5551, 34740, 13412, 17082, 37977, 44945, 5016, 4117, 1829, 11296, 20666, 1863, 35457, 3660, 46740, 15730, 25724, 11622, 38207, 14739, 3224, 8978, 43242, 7578, 45030, 11242, 2423, 37551, 7251, 43020, 14739, 7251, 1863, 11622, 3615, 9154, 11296, 5551, 4117, 3794, 7435, 9957, 29538, 39894, 5172, 25708, 8315, 5296, 15042, 47525, 8315, 8717, 3215, 2288, 3794, 2423, 8179, 8258, 13672, 1829, 39896, 16247, 35571, 46958, 28239, 2407, 2407, 10632, 4032, 27842, 11296], "avg_logprob": -0.17307692837829775, "compression_ratio": 1.72, "no_speech_prob": 0.0, "words": [{"start": 1938.13, "end": 1938.43, "word": "أو", "probability": 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"probability": 0.9375}, {"start": 1947.25, "end": 1948.01, "word": " أخر", "probability": 0.716064453125}, {"start": 1948.01, "end": 1948.31, "word": " شغلة", "probability": 0.9861653645833334}, {"start": 1948.31, "end": 1949.17, "word": " بنحكيها", "probability": 0.858984375}, {"start": 1949.17, "end": 1950.13, "word": " بالنسبة", "probability": 0.9925537109375}, {"start": 1950.13, "end": 1951.51, "word": " لهذا", "probability": 0.872314453125}, {"start": 1951.51, "end": 1952.07, "word": " الجزء", "probability": 0.9796549479166666}, {"start": 1952.07, "end": 1952.95, "word": " أنه", "probability": 0.5635986328125}, {"start": 1952.95, "end": 1953.09, "word": " في", "probability": 0.88916015625}, {"start": 1953.09, "end": 1953.69, "word": " عندى", "probability": 0.63671875}, {"start": 1953.69, "end": 1954.15, "word": " بعض", "probability": 0.97802734375}, {"start": 1954.15, "end": 1954.33, "word": " ال", "probability": 0.6494140625}, {"start": 1954.33, "end": 1954.81, "word": " sugars", 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{"start": 2090.87, "end": 2091.91, "word": " polysaccharides", "probability": 0.98828125}, {"start": 2091.91, "end": 2092.29, "word": " أن", "probability": 0.54248046875}, {"start": 2092.29, "end": 2092.69, "word": " هم", "probability": 0.77685546875}, {"start": 2092.69, "end": 2093.71, "word": " polymers", "probability": 0.849609375}], "temperature": 1.0}, {"id": 89, "seek": 211825, "start": 2094.61, "end": 2118.25, "text": "ماذا يعني polymers؟ يعني لما أقول النشا، إيش الوحدة تبعته؟ هتقولولي مالتوز البيسكريدي المالتوز، تمام؟ لو قولت مثلا السيللوز، بوليمر كبير، إيش الوحدة تبعته؟ السيلوبيوز، ولذلك ال polysaccharides", "tokens": [2304, 45636, 995, 37495, 22653, 6754, 18552, 22807, 37495, 22653, 5296, 15042, 5551, 39648, 28239, 8592, 995, 12399, 11933, 1829, 8592, 2423, 2407, 24401, 3660, 6055, 3555, 34268, 3224, 22807, 8032, 2655, 39648, 12610, 1829, 3714, 6027, 2655, 2407, 11622, 2423, 21292, 3794, 4117, 16572, 16254, 9673, 6027, 2655, 2407, 11622, 12399, 46811, 10943, 22807, 45164, 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البروتينات ليش؟ لأن ال polysaccharides عندي وحدة و بتتكرر يعني كأن الإنسان بيقدر يقول عنهم ان they are real polymers واضح؟ ال polymers مكون من إيش؟", "tokens": [32640, 19452, 16712, 3615, 10943, 1211, 20449, 11296, 7251, 30544, 5551, 3794, 3224, 1211, 9122, 2655, 13546, 9154, 16712, 3615, 10943, 1211, 20449, 2423, 26890, 35473, 9957, 9307, 32239, 8592, 22807, 5296, 33456, 2423, 6754, 82, 326, 7374, 1875, 18871, 16254, 4032, 24401, 3660, 4032, 39894, 2655, 37983, 2288, 37495, 22653, 9122, 33456, 33688, 1863, 3794, 7649, 4724, 1829, 28543, 2288, 7251, 39648, 18871, 16095, 16472, 436, 366, 957, 6754, 18552, 4032, 46958, 5016, 22807, 2423, 6754, 18552, 3714, 30544, 9154, 11933, 1829, 8592, 22807], "avg_logprob": -0.16151889032402703, "compression_ratio": 1.6082474226804124, "no_speech_prob": 0.0, "words": [{"start": 2119.23, "end": 2119.85, "word": "يمكن", "probability": 0.966552734375}, {"start": 2119.85, "end": 2120.67, "word": " التعامل", "probability": 0.993896484375}, {"start": 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"word": " منهم", "probability": 0.9873046875}, {"start": 2490.01, "end": 2490.49, "word": " إيش", "probability": 0.78564453125}, {"start": 2490.49, "end": 2492.65, "word": " polymers", "probability": 0.697021484375}, {"start": 2492.65, "end": 2493.71, "word": " they", "probability": 0.767578125}, {"start": 2493.71, "end": 2494.29, "word": " are", "probability": 0.96484375}, {"start": 2494.29, "end": 2495.41, "word": " macro", "probability": 0.9326171875}, {"start": 2495.41, "end": 2496.29, "word": " molecules", "probability": 0.80078125}, {"start": 2496.29, "end": 2497.13, "word": " أكثر", "probability": 0.9580078125}, {"start": 2497.13, "end": 2497.71, "word": " منهم", "probability": 0.99462890625}], "temperature": 1.0}, {"id": 106, "seek": 252169, "start": 2499.03, "end": 2521.69, "text": "بولمار طبعا فيهم نوعا ما شيء مشترك بيخلي بعض الناس يقولوا ممكن تجاوزا نعتبر ال protein بولمار ليش؟ لأنه لو أنا اتطلعت على الهيكل تبعه اللي بتكرر هلاحظ ان هو عبارة عن NCE", "tokens": [3555, 12610, 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"probability": 0.65673828125}, {"start": 2510.27, "end": 2511.81, "word": " بولمار", "probability": 0.8533935546875}, {"start": 2511.81, "end": 2513.13, "word": " ليش؟", "probability": 0.6341959635416666}, {"start": 2513.13, "end": 2513.77, "word": " لأنه", "probability": 0.859375}, {"start": 2513.77, "end": 2514.67, "word": " لو", "probability": 0.9716796875}, {"start": 2514.67, "end": 2514.95, "word": " أنا", "probability": 0.66015625}, {"start": 2514.95, "end": 2515.79, "word": " اتطلعت", "probability": 0.83837890625}, {"start": 2515.79, "end": 2516.47, "word": " على", "probability": 0.888671875}, {"start": 2516.47, "end": 2517.33, "word": " الهيكل", "probability": 0.886962890625}, {"start": 2517.33, "end": 2517.89, "word": " تبعه", "probability": 0.886474609375}, {"start": 2517.89, "end": 2518.03, "word": " اللي", "probability": 0.945556640625}, {"start": 2518.03, "end": 2518.81, "word": " بتكرر", "probability": 0.9513346354166666}, {"start": 2518.81, "end": 2519.63, "word": " هلاحظ", "probability": 0.865966796875}, {"start": 2519.63, "end": 2519.79, "word": " ان", "probability": 0.53564453125}, {"start": 2519.79, "end": 2520.01, "word": " هو", "probability": 0.83544921875}, {"start": 2520.01, "end": 2520.49, "word": " عبارة", "probability": 0.9896240234375}, {"start": 2520.49, "end": 2520.67, "word": " عن", "probability": 0.9755859375}, {"start": 2520.67, "end": 2521.69, "word": " NCE", "probability": 0.3619384765625}], "temperature": 1.0}, {"id": 107, "seek": 254069, "start": 2523.32, "end": 2540.7, "text": "الان هذه الوحدة بتتكرر في البروتين بعدها N C C double bond O بعدها N C C double bond O هتقولولي مش ناقص غير ايش تكتب هذولة to the N طب ليش مش قادر اكتبهم؟", "tokens": [6027, 7649, 29538, 2423, 2407, 24401, 3660, 39894, 2655, 37983, 2288, 8978, 2423, 26890, 35473, 9957, 39182, 11296, 426, 383, 383, 3834, 6086, 422, 39182, 11296, 426, 383, 383, 3834, 6086, 422, 8032, 2655, 39648, 12610, 1829, 37893, 8717, 995, 4587, 9381, 32771, 13546, 1975, 1829, 8592, 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0.89619140625}, {"start": 2533.8, "end": 2534.06, "word": " مش", "probability": 0.923828125}, {"start": 2534.06, "end": 2534.42, "word": " ناقص", "probability": 0.87060546875}, {"start": 2534.42, "end": 2534.66, "word": " غير", "probability": 0.988037109375}, {"start": 2534.66, "end": 2535.08, "word": " ايش", "probability": 0.7862141927083334}, {"start": 2535.08, "end": 2536.98, "word": " تكتب", "probability": 0.923583984375}, {"start": 2536.98, "end": 2537.46, "word": " هذولة", "probability": 0.67523193359375}, {"start": 2537.46, "end": 2537.6, "word": " to", "probability": 0.70751953125}, {"start": 2537.6, "end": 2537.78, "word": " the", "probability": 0.84912109375}, {"start": 2537.78, "end": 2538.58, "word": " N", "probability": 0.67236328125}, {"start": 2538.58, "end": 2539.22, "word": " طب", "probability": 0.753173828125}, {"start": 2539.22, "end": 2539.44, "word": " ليش", "probability": 0.93798828125}, {"start": 2539.44, "end": 2539.6, "word": " مش", "probability": 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المرة الماضية + +2 +00:00:24,830 --> 00:00:29,410 +عن السكريات المنفردة اتعرفنا عليها ال mono + +3 +00:00:29,410 --> 00:00:34,750 +-saccharides الان بدنا نتكلم عن ال di-saccharides + +4 +00:00:34,750 --> 00:00:39,930 +طبعا اللي بنقصده احنا ب di-saccharides انه جزيئين + +5 +00:00:39,930 --> 00:00:43,910 +من ال mono-saccharides يتحدوا مع بعض و بيعملوا + +6 +00:00:43,910 --> 00:00:51,360 +ايش؟ di-saccharide الان مش دائما مش دائمامش دائما + +7 +00:00:51,360 --> 00:00:54,820 +هدول الجزيئين اللي بدهم يتحدوا مع بعض بيكونوا زي + +8 +00:00:54,820 --> 00:01:00,140 +بعض يعني يوم بدأ احكي انا عن دايسا كرايد ممكن اجيب + +9 +00:01:00,140 --> 00:01:06,260 +نفس الجزيئين تماما بكل محتوياتهم طبعا بالتأكيد ال + +10 +00:01:06,260 --> 00:01:09,680 +stereo chemistry تكون نفس الشيء تماما و يعملوا + +11 +00:01:09,680 --> 00:01:14,040 +دايسا كرايد و ممكن اجيب جزيئين مختلفين و يعملوا + +12 +00:01:14,040 --> 00:01:19,820 +دايسا كرايد فمش ضروريمش ضروري ان الـ disaccharide + +13 +00:01:19,820 --> 00:01:26,240 +يكون مكوّن من الجزيئين نفسهم تماما، واضح؟ يعني + +14 +00:01:26,240 --> 00:01:30,560 +ممكن يكون فعلا من نفس الجزيئين مكوّن disaccharide + +15 +00:01:30,560 --> 00:01:36,920 +وممكن يكون من جزيئين مختلفين وهذا اللي هنشوفه لما + +16 +00:01:36,920 --> 00:01:45,550 +نستعرض بعض الـ disaccharides بشكل عام ويعني جداأول + +17 +00:01:45,550 --> 00:01:51,710 +دايسا كارايد بدنا نستعرضه المالتوز، واضح؟ + +18 +00:01:51,710 --> 00:01:57,970 +المالتوز، الآن هذا الديسا كارايد مكون من سكرين + +19 +00:01:57,970 --> 00:02:03,070 +جولوكوز، لكن فيهم اختلاف في ال stereo chemistry + +20 +00:02:03,470 --> 00:02:08,830 +فيهم اختلاف في ال stereo chemistry واحد منهم واحد + +21 +00:02:08,830 --> 00:02:14,730 +منهم alpha glucose والتاني منهم beta glucose الآن + +22 +00:02:14,730 --> 00:02:19,390 +اللي بتذكروا معنا قولنا احنا ان ال alpha و ال beta + +23 +00:02:19,390 --> 00:02:24,930 +sugars بصيروا لما نسكر اخر carbon اللي سمناها ال + +24 +00:02:24,930 --> 00:02:29,300 +anomeric carbon و نعملفي حالة السكريات هذه الميزات + +25 +00:02:29,300 --> 00:02:35,240 +الكربونات ال fifth chiral center فإذا ال OH كانت + +26 +00:02:35,240 --> 00:02:40,020 +للأسفل على هذا الكربون تحديدا بنقول هذا السكر + +27 +00:02:40,020 --> 00:02:46,120 +Alpha وإذا كانت للأعلى Beta الآن هذا ال maltose لو + +28 +00:02:46,120 --> 00:02:50,760 +بتطلع عليه أنا هيمكون من سكر متصل في ال anomeric + +29 +00:02:50,760 --> 00:02:54,560 +carbon لاحظوا أنا تركيزي على أي كربون ال anomeric + +30 +00:02:54,560 --> 00:02:59,820 +carbon نكون معلمينها إلى أساساهذه السكرين المتحدين + +31 +00:02:59,820 --> 00:03:07,180 +الآن اتطلعوا على واحد منهم ال oxygen فيه alpha + +32 +00:03:07,180 --> 00:03:18,840 +واضح التاني منهم ال oxygen فيه betaواضح فالملتوز + +33 +00:03:18,840 --> 00:03:24,740 +بيكون في هذه الحالة امكون من Alpha-Glucose مع Beta + +34 +00:03:24,740 --> 00:03:29,660 +-Glucose هى دول اتنين قبل ما يتصلوا مع بعض هذا + +35 +00:03:29,660 --> 00:03:35,440 +بهذا الشكل كان OH كان Alpha-Glucose هذا كان Beta + +36 +00:03:35,440 --> 00:03:41,320 +-Glucose فاتنين اتصلوا مع بعض من خلال موقع اربعة + +37 +00:03:41,320 --> 00:03:45,060 +لما ناخد الترقيم واحد اتنين تلاتة اربعة هذا الموقع + +38 +00:03:46,020 --> 00:03:49,540 +أربعة اتحدوا من خلال هذه ال Oxygenة اللي في موقع + +39 +00:03:49,540 --> 00:03:55,920 +أربعة عملوا رابطة واضح فصار عند المركب مكوّن من + +40 +00:03:55,920 --> 00:04:03,040 +Alpha و من Dبيتا جولوكوز وعشان هيك لما بدنا نسميه + +41 +00:04:03,040 --> 00:04:09,900 +ممكن انه نقرأ الاسم تبعه هتحسوا انه مش صعب هو ممكن + +42 +00:04:09,900 --> 00:04:15,120 +تتخيلوا مركب بيتا جولوكوز لو حطيت ع موقع اربعة مثل + +43 +00:04:15,120 --> 00:04:19,960 +شو كنتوا هتسموه four مثل بيتا جولوكوز + +44 +00:04:23,450 --> 00:04:29,690 +الاسم الـ Beta في آخر الكلام Beta-D-Glucobiranose + +45 +00:04:29,690 --> 00:04:35,170 +مش سمناه لأن جولوكوزم سكرة حلقة سداسية + +46 +00:04:35,170 --> 00:04:40,030 +Glucobiranose وD و Beta لأن هذه موجودة في الوضع + +47 +00:04:40,030 --> 00:04:45,410 +Beta الآن هذا على موقع أربعة هي على موقع أربعة من + +48 +00:04:45,410 --> 00:04:50,950 +خلال ال Oxygen متحد بإيش ب Alpha-D-Glucobiranose + +49 +00:04:51,620 --> 00:04:57,800 +واضح الفكرة؟ فيذكر الاسم العام على موقع أربعة من + +50 +00:04:57,800 --> 00:05:05,690 +هذا السكر، إيش موجود عنده على موقع أربعة؟الفا دي + +51 +00:05:05,690 --> 00:05:08,890 +جلوكو بايرانوس طبعا اتصاله من خلال ال O عشان هيك + +52 +00:05:08,890 --> 00:05:13,490 +كتبنا O فاللي بده يفهم الاسم الاسم مش صعب انه هاي + +53 +00:05:13,490 --> 00:05:18,290 +المركب اللي عندى بيتا جلوكو بايرانوس على موقع + +54 +00:05:18,290 --> 00:05:22,650 +اربعة منه ايش ايجا نعتبرها بين قوسينAlpha + +55 +00:05:22,650 --> 00:05:28,230 +Glucobiranose فهذا سكر الملتوز ببساطة هذه الأشياء + +56 +00:05:28,230 --> 00:05:34,030 +بيبقى تفهموا فيها الأفكار العامة فالملتوز من سكرين + +57 +00:05:34,030 --> 00:05:38,350 +جولوكوز لكن اتنين مش Alpha Alpha ولا Beta Beta + +58 +00:05:38,350 --> 00:05:46,590 +Alpha مع Betaالان بيجيني سكر تاني السيلو بيوز + +59 +00:05:46,590 --> 00:05:55,730 +السيلو بيوز متحد من سكرين متفقين تماما بيتا جلوكو + +60 +00:05:55,730 --> 00:06:00,550 +بيرانوز مع بيتا جلوكو بيرانوز واضح؟ ولذلك لو انا + +61 +00:06:00,550 --> 00:06:07,550 +بدأ اطلع على هذا السكر هذا بيتا ولا لا؟ بيتا وعلى + +62 +00:06:07,550 --> 00:06:14,780 +هذا السكرهذه أيضًا Beta فلما بنسميه نسبة لهذا Beta + +63 +00:06:14,780 --> 00:06:20,740 +D Glucopyranose متحد من موقع أربعةواحد اتنين تلاتة + +64 +00:06:20,740 --> 00:06:25,880 +اربعة متحد من موقع اربعة من خلال ال oxygen ال beta + +65 +00:06:25,880 --> 00:06:31,160 +D-glucobiranose واضح يعني هذا كأننا بنقول beta D + +66 +00:06:31,160 --> 00:06:36,660 +-glucobiranose يحمل على موقع اربعة beta D + +67 +00:06:36,660 --> 00:06:42,100 +-glucobiranose واضح الفكرة فال cellobiose بيكون من + +68 +00:06:42,100 --> 00:06:50,330 +سكرين متماثلينتماما، لاحظوا قداش نسبة الخلاف اللي + +69 +00:06:50,330 --> 00:06:56,450 +بتعمل يعني مركبات مختلفة، يعني انا بحكي عن + +70 +00:06:56,450 --> 00:07:02,330 +Glucopyranose و Glucopyranose و بحكي عن هذا Beta + +71 +00:07:02,330 --> 00:07:06,870 +في الحالتين، بس التاني مرة Beta و مرة ايش Alpha + +72 +00:07:07,710 --> 00:07:14,870 +خلاف بسيط جدا بس كايرال سنتر واحد، الآن بعد شوية + +73 +00:07:14,870 --> 00:07:19,770 +هتكتشفوا ان هذا الخلاف البسيط جدا في كايرال سنتر + +74 +00:07:19,770 --> 00:07:26,510 +الوحيد بيتبع خلاف كبير جدا جدا جدا في الخواص بعد + +75 +00:07:26,510 --> 00:07:31,760 +ذلك للمراكباتيعني لما ييجيوا الجزيئات الـ + +76 +00:07:31,760 --> 00:07:35,200 +disaccharides بدهم يعملوا polysaccharides هاي + +77 +00:07:35,200 --> 00:07:38,540 +disaccharide و خلّينا نعتبر هاي كمان disaccharide + +78 +00:07:38,540 --> 00:07:43,120 +هذا كان من Beta و Beta و هذا كان من Beta و Alpha + +79 +00:07:43,120 --> 00:07:47,660 +الان اللي كان من Alpha و Beta الملتوز بيعمل جزئ + +80 +00:07:47,660 --> 00:07:56,080 +كبير اسمه نشا او glycogenاللي هي تخزين أو أماكن + +81 +00:07:56,080 --> 00:07:59,380 +تخزين ال carbohydrates سواء في النبات أو في + +82 +00:07:59,380 --> 00:08:03,400 +الحيوان وهذه بتدوب في الميه وبيقدر البني آدم + +83 +00:08:03,400 --> 00:08:07,000 +يهضمها يعني البني آدم لما بياكل النشويات بيقدر + +84 +00:08:07,000 --> 00:08:12,180 +بسهولة يحللها للسكريات الأولية بتاعتها أكيد الآن + +85 +00:08:12,180 --> 00:08:16,060 +اللي مكوّن من ال beta و ال beta هيجي يعمل ال + +86 +00:08:16,060 --> 00:08:20,600 +cellulose هيعمل الخشب البني آدم بيقدرش يهضم الخشب + +87 +00:08:20,600 --> 00:08:27,570 +الآن هتيجي تقوله شو الفرق؟بين أساس الخشب و أساس + +88 +00:08:27,570 --> 00:08:33,270 +النشا أساس الخشب cellobiose و اتحد و أعطاني + +89 +00:08:33,270 --> 00:08:39,110 +cellulose و أساس النشا الملتوز و أعطاني starch + +90 +00:08:39,110 --> 00:08:46,230 +واضح فقط مختلفين هدول الاتنين بواحد من السكريات + +91 +00:08:46,230 --> 00:08:49,770 +جولوكوز جولوكوز صح جولوكوز جولوكوز بس هذا beta و + +92 +00:08:49,770 --> 00:08:55,240 +beta هذا beta و alphaمخيلوا كيف اختلاف بسيط في ال + +93 +00:08:55,240 --> 00:09:00,740 +stereochemistry بيقدر الاختلاف كبير بعد هيك في + +94 +00:09:00,740 --> 00:09:05,480 +الخواص و في الاستفادة من المركبات بيجينا سكر + +95 +00:09:05,480 --> 00:09:15,960 +الحليب ال lactoseاللاكتوز أيضا في جولوكوز لكن في + +96 +00:09:15,960 --> 00:09:20,900 +جالاكتوز يعني هدولا ال stereo chemical centers + +97 +00:09:20,900 --> 00:09:26,320 +اتغير فيهم اكتر كل الفروقات بينهم هي فروقات ايش + +98 +00:09:26,320 --> 00:09:30,500 +لحتى لها ال stereo chemistry يعني هذه الوحدة مش + +99 +00:09:30,500 --> 00:09:36,340 +بيتا جولوكوز في هذه الحالة الفا جولوكوز متحد مع + +100 +00:09:36,340 --> 00:09:42,300 +بيتا جالاكتوزعشانك لو ذكرنا الاسم العام هتلاحظوا + +101 +00:09:42,300 --> 00:09:47,260 +في الآخر Alpha D Glucopyranose هي ال Alpha D + +102 +00:09:47,260 --> 00:09:54,480 +Glucopyranose وشايفين أنها Alpha الآن متحد من موقع + +103 +00:09:54,480 --> 00:10:01,340 +أربعة ال Beta D Galactopyranose طبعا بنكتب Beta D + +104 +00:10:01,340 --> 00:10:07,450 +Galactopyranoseال YL اللي هي بصفته أصبح مجموعة زي + +105 +00:10:07,450 --> 00:10:14,330 +ما بقول مثل اثل بروبل ال YL لأنه أصبح مجموعة واضحة + +106 +00:10:14,330 --> 00:10:20,630 +الفكرة؟ هذا ال lactose طبعا بيجي صاحبنا، مين + +107 +00:10:20,630 --> 00:10:27,330 +صاحبنا؟السكاروز ماحدش اقول عن السكاروز العدو + +108 +00:10:27,330 --> 00:10:33,030 +تبعنا، يعني في ناس دائما متطرفين في الحكم على اللي + +109 +00:10:33,030 --> 00:10:37,090 +هي هذه الأشياء، كل هذه السكريات و كل حتى الدهون + +110 +00:10:37,090 --> 00:10:40,730 +بتلزم للإنسان، بس المشكلة مش أن الإنسان ياخد + +111 +00:10:40,730 --> 00:10:45,340 +سكريات و ياخد دهونالمشكلة أنه ياخدها بإفراط يعني + +112 +00:10:45,340 --> 00:10:49,160 +الإنسان بحاجة للسكريات، بحاجة للدهون بالتأكيد، + +113 +00:10:49,160 --> 00:10:53,940 +بحاجة للكلسترول، بحاجة لكل إشي لكن الإفراط في أي + +114 +00:10:53,940 --> 00:10:58,840 +شغل هو اللي بيعمل عندنا إيش المشكلة الآن لو إجينا + +115 +00:10:58,840 --> 00:11:02,640 +اتطلعنا على السكروز اللي هو السكر اللي إحنا + +116 +00:11:02,640 --> 00:11:07,540 +بنستعمله هتلاحظوا مرة تانية في عندى Alpha + +117 +00:11:07,540 --> 00:11:11,680 +-Glucopyranose هاي Alpha هذه شايفينها؟ + +118 +00:11:14,950 --> 00:11:19,930 +طالما لا أسفل إذا هذه إيش؟ Alpha لكن المرة هذه + +119 +00:11:19,930 --> 00:11:27,030 +الاتحاد تبعه مش من موقع أربعة هو متحد ب fractose + +120 +00:11:27,030 --> 00:11:33,390 +واضح؟ هو متحد ب fractose و ال fractose keto sugar + +121 +00:11:33,390 --> 00:11:38,370 +لما أخدنا السكريات قلنا إن في عندنا ال doses من ال + +122 +00:11:38,370 --> 00:11:43,920 +aldehydesو Ketosis لفراكتوز كيتو شوجار و لما بيسكر + +123 +00:11:43,920 --> 00:11:50,240 +بيسكر على السكر خماسي السكر الخماسي فيورانوز و من + +124 +00:11:50,240 --> 00:11:56,020 +الفيورانوز متحد من موقع ايش؟ واحد واضح؟ الان هذا + +125 +00:11:56,020 --> 00:12:04,630 +الفيورانوز لما بتطلع فيهبيتا واضح؟ اذا هذا بيتا + +126 +00:12:04,630 --> 00:12:09,270 +عشانك هتلاقوا الاسم تبعه اعتبروا ان هذا هو الأصل + +127 +00:12:09,270 --> 00:12:14,010 +وهذه هي الاش المجموعة اللي جاية على الأصل واضح؟ + +128 +00:12:14,010 --> 00:12:19,950 +فهتلاحظوا بيتا دي فراكتو فيورانوزيل طبعا + +129 +00:12:19,950 --> 00:12:26,210 +فيورانوزيل لأنه جاي ايش؟ مجموعة متحدة مع الف دي + +130 +00:12:26,210 --> 00:12:33,150 +غلوكوما كتبش هنا by rhinos، كتب by rhinocide، ليش؟ + +131 +00:12:33,150 --> 00:12:37,790 +لأن الاتحاد تم هنا من موقع واحد، لاحظوا في + +132 +00:12:37,790 --> 00:12:41,270 +السكريات اللي قبل شوية، لما كنا نيجع هذا السكر، + +133 +00:12:41,270 --> 00:12:45,150 +الاتحاد تم من أي موقع؟ أربعة، هنا الاتحاد تم من + +134 +00:12:45,150 --> 00:12:53,080 +موقع واحد، فإذا هذه الرابطة بطلت OH صارت O-Carbon + +135 +00:12:53,080 --> 00:12:58,340 +معنا ذلك هذه الرابطة ايش بدها تكون؟ Glycosidic + +136 +00:12:58,340 --> 00:13:02,280 +bond واضح؟ عشان Glycosidic bond عشان تكون + +137 +00:13:02,280 --> 00:13:08,400 +Glycoside هنحط ايش؟ Glucoburanoside لاحظته هنا + +138 +00:13:08,400 --> 00:13:12,640 +كلمة؟ Buranoside لو رجعتوا على الأسماء اللي قبل + +139 +00:13:12,640 --> 00:13:19,240 +كان حط Glucoburanose لأن هذه كانت تكون OHفي كل + +140 +00:13:19,240 --> 00:13:23,280 +اللي قبل هذه كانت OH غلوكو باي رانوس سواء كان + +141 +00:13:23,280 --> 00:13:28,860 +Alpha أو Beta لكن هنا بطلت OH صار الاتحاد من عندها + +142 +00:13:28,860 --> 00:13:33,420 +و عشان هيك صارت هذه الرابطة Glycosidic bond فقال + +143 +00:13:33,420 --> 00:13:38,300 +غلوكو باي رانوسايد غلوكو باي رانوسايد فالحقيقة + +144 +00:13:40,010 --> 00:13:46,150 +السكر اللى فيه two glycosidic bonds هو سكر ايش + +145 +00:13:46,150 --> 00:13:50,210 +السكروز انتبهوا لو كانوا بيسألكوا multiple choice + +146 +00:13:50,210 --> 00:13:58,670 +الان هذه الرابطة carbon و carbon هذى glycosidic + +147 +00:13:58,670 --> 00:14:04,230 +bond ولا لأ و هذا الرابطة glycosidic bond فلما + +148 +00:14:04,230 --> 00:14:10,320 +نيجي نطلع احنا حقيقة على السكروزكم جليكوسايدك بوند + +149 +00:14:10,320 --> 00:14:18,940 +فيه؟ تنتين لو رجعنا اتطلعنا على السكريات + +150 +00:14:18,940 --> 00:14:25,100 +اللي قبل هنا كم جليكوسايدك بوند؟ واحدة ماحدش يقول + +151 +00:14:25,100 --> 00:14:29,520 +هذه جليكوسايدك بوند ليش؟ لأن الجليكوسايدك بوند + +152 +00:14:29,520 --> 00:14:34,700 +اللي بتتكون على الكايرال سنتر الأخير على هذه مش + +153 +00:14:34,700 --> 00:14:40,650 +على هذا الموقع أربعةواضح؟ يعني مش اي او كربون + +154 +00:14:40,650 --> 00:14:47,850 +glycosidic bond ال glycosidic bond مرتبطة بأي بأي + +155 +00:14:47,850 --> 00:14:52,630 +كربون بال anomeric carbon اللي كانت أساسا الديهايد + +156 +00:14:52,630 --> 00:14:56,350 +واضح؟ ولذلك هذه glycosidic bond بس هذه مش + +157 +00:14:56,350 --> 00:15:01,390 +glycosidic bond واضح؟ فلو أنا اجيت على ال lactose + +158 +00:15:01,390 --> 00:15:08,540 +في one glycosidic bond لو رجعتعلى السيلو بيوز على + +159 +00:15:08,540 --> 00:15:13,640 +سبيل المثال برضه أي واحدة anomeric carbon كل سكر + +160 +00:15:13,640 --> 00:15:17,780 +فيه two anomeric carbon مظبوط ولا لأ هذه فيها + +161 +00:15:17,780 --> 00:15:24,200 +glycosidic bond هذه فيها لذلك في السيلو بيوز في + +162 +00:15:24,200 --> 00:15:30,950 +عنده one glycosidic bond هذه لأواضحة الفكرة؟ يعني + +163 +00:15:30,950 --> 00:15:34,970 +انا عندي two anomeric carbons مين فيهم glycosidic + +164 +00:15:34,970 --> 00:15:40,630 +bond؟ هذي ال O H glycosidic، هذي، اه واضحة الفكرة؟ + +165 +00:15:40,630 --> 00:15:44,950 +فدائما لما بدنا نعرف كام glycosidic bond، نرجع على + +166 +00:15:44,950 --> 00:15:53,670 +الملتوز مثلا، هذي ال anomeric carbons الآن لو + +167 +00:15:53,670 --> 00:15:57,690 +إجينا سألنا هذي glycosidic bond؟ O H، هذي + +168 +00:15:59,540 --> 00:16:07,100 +Glycosidic bond فالملتوز والسيلوبيوز واللاكتوز + +169 +00:16:07,100 --> 00:16:11,380 +هدولة فيهم و one glycosidic bond و التانية عادية + +170 +00:16:11,380 --> 00:16:16,740 +عشان ايه كنتوا تلاقوا؟ Glucopyranose عادي لكن لما + +171 +00:16:16,740 --> 00:16:23,340 +وصلنا للسكروز لو اجينا سألنا وين ال anomeric + +172 +00:16:23,340 --> 00:16:24,180 +carbons؟ + +173 +00:16:26,580 --> 00:16:31,440 +هي الانوميرك كاربونز الان هنا في جليكوسايدك بوند + +174 +00:16:31,440 --> 00:16:36,640 +فيه هنا في جليكوسايدك بوند فيه تنتين جليكوسايدك + +175 +00:16:36,640 --> 00:16:42,920 +بوند واضح؟ وعشان هيك هذا لما أنهينا اسمه أنهينا ب + +176 +00:16:42,920 --> 00:16:49,480 +side اللي هو alpha D-glucopyranoside زي ما اتعلمنا + +177 +00:16:49,480 --> 00:16:53,160 +لما أخدنا الجليكوسايدك بوند وقلنا بننهي بإيش؟ + +178 +00:16:53,160 --> 00:16:54,360 +جليكوسايد + +179 +00:16:57,360 --> 00:17:03,560 +هذا بالنسبة لبعض السكريات اللي هي بنستفيد منها ل + +180 +00:17:03,560 --> 00:17:08,700 +ال die saccharides الكلام يمكن يجيب بعضه أن القاسم + +181 +00:17:08,700 --> 00:17:16,810 +المشترك ربما في الأشياء المحلية طعم الحلوواضح؟ + +182 +00:17:16,810 --> 00:17:20,550 +يعني الإنسان بيفتش في النهاية عن إيش؟ الطعم كذلك + +183 +00:17:20,550 --> 00:17:24,450 +الحال يمكن تلاحظوه في العطور يعني مار علينا و إحنا + +184 +00:17:24,450 --> 00:17:31,410 +بنشرح بعض العطور العطور لا يوجد خليني أقول مجموعة + +185 +00:17:31,410 --> 00:17:35,810 +كيميائية تكون قاسم مشترك ما بين العطور ما القاسم + +186 +00:17:35,810 --> 00:17:41,920 +المشترك؟الرائحة الذكية، الرائحة الجيدة الآن العطر + +187 +00:17:41,920 --> 00:17:46,360 +ممكن مرة يكون Easter ممكن مرة يكون الديهيد ممكن + +188 +00:17:46,360 --> 00:17:50,440 +مرة يكون كيتون شوفنا الياسمون مثلا شوفنا .. + +189 +00:17:50,440 --> 00:17:53,940 +متذكرين الياسمين كان كيتون شوفنا ال Easter's قولنا + +190 +00:17:53,940 --> 00:17:58,040 +عنها مواد عطرية مافيش قاسم كيميائي مشترك القاسم + +191 +00:17:58,040 --> 00:18:03,310 +الكيميائي ما بين العطورهو الرائحة الجيدة الآن + +192 +00:18:03,310 --> 00:18:07,290 +القاسم الكيميائي ما بين ال sweeteners المحليات و + +193 +00:18:07,290 --> 00:18:12,970 +منها السكر هو الطعم الاش؟ الحلو ولذلك الآن في + +194 +00:18:12,970 --> 00:18:17,490 +سكريات اللي هي السكريات هذه الصناعية اللي بياخدوها + +195 +00:18:17,490 --> 00:18:21,430 +الناس اللي عندهم سكر و ما إلى ذلك لو اطلعت على + +196 +00:18:21,430 --> 00:18:25,590 +أنواعها المختلفة مش هتلاقيوا شيء مشترك في الشكل + +197 +00:18:25,590 --> 00:18:32,500 +بينها لكن هالمراكبات لما حضروهالاحظوا انه طعمها + +198 +00:18:32,500 --> 00:18:37,440 +حلو وبشكل عام آمن يعني كتير في مركبات طعمها حلو + +199 +00:18:37,440 --> 00:18:40,980 +لكن خطيرة جدا بيقدرش الإنسان يتعامل معايا + +200 +00:18:40,980 --> 00:18:45,440 +الكلوروفورم طعمه حلو لكن سامه carcinogenic لكن هذا + +201 +00:18:45,440 --> 00:18:50,040 +المركب مثلا بدون ما ناخد طرق تحضيره هو السكارين + +202 +00:18:50,040 --> 00:18:54,720 +سواء وجد ع شكل السكارين أو عشان يدوب بيسحبوا القدش + +203 +00:18:54,720 --> 00:18:58,580 +بيعملوا ال salt تبعه طبعا دائما لما نقول salt ال + +204 +00:18:58,580 --> 00:19:03,300 +salt ليش بنعمله احناعشان الذائبية تكون أعلى في + +205 +00:19:03,300 --> 00:19:08,740 +الميه فلو اطلعنا احنا هذا ال sodium سكارين اللي هو + +206 +00:19:08,740 --> 00:19:12,740 +اللي بنستعمله و بنحطه على الشاي مافيش علاقة بين + +207 +00:19:12,740 --> 00:19:20,080 +شكله وبين شكل السكاروز لكن يوضع بديل للسكاروز، + +208 +00:19:20,080 --> 00:19:25,780 +مظبوط ولا لأ؟ ليش يوضع بديل للسكاروز؟ بسبب الطعم + +209 +00:19:25,780 --> 00:19:30,730 +الحلو، الآن في سكريات تانية غير السكاروزالسكارين + +210 +00:19:30,730 --> 00:19:36,150 +تستعمل منها مثلا ال Aspartame و ال Cyclamates لو + +211 +00:19:36,150 --> 00:19:42,110 +فتشته Cyclamates لو فتشته على شكل ال Aspartame و + +212 +00:19:42,110 --> 00:19:46,030 +ال Cyclamate و السكارين هتلاقي كل واحد يمثل شكل + +213 +00:19:46,030 --> 00:19:52,410 +معين مافيش قاسم مشترك بينهم القاسم المشترك هو إيش؟ + +214 +00:19:52,410 --> 00:19:57,510 +الطعم الحلو القاسم المشترك هو الطعم الحلو يعني هاي + +215 +00:19:57,510 --> 00:20:02,700 +ال Aspartameطلعوا هذا شكل و هذا شكل بتلاحظوا فيه + +216 +00:20:02,700 --> 00:20:07,740 +شيء مشترك مع السكرين طب العسل بس زي محلق و بطعم + +217 +00:20:07,740 --> 00:20:12,060 +حلو؟ ايه هو؟ العسل؟ ما هو العسل فيه سكريات كتيرة + +218 +00:20:12,060 --> 00:20:17,120 +لأ لأ مش من هدولة من السكريات العادية اللي أخدناها + +219 +00:20:17,120 --> 00:20:23,000 +بس تركيبته عاد كبيرة في سكريات و فيتامينات و إشي + +220 +00:20:23,000 --> 00:20:31,540 +أكثر من شغلها الآنهذه الـ Disaccharides سواء كانت + +221 +00:20:31,540 --> 00:20:37,740 +سكريات مختلفة زي الملتوز اللي احنا قلنا عنه Alpha + +222 +00:20:37,740 --> 00:20:43,810 +و Beta الجلوكوز متحدين مع بعض أوالسيلو بيوز اللي + +223 +00:20:43,810 --> 00:20:47,710 +قلنا عنه بيتا و بيتا يعني خلينا نركز احنا على + +224 +00:20:47,710 --> 00:20:52,810 +الملتوز الملتوز كان من ألفة و بيتا جولوكوز مكون + +225 +00:20:52,810 --> 00:20:57,790 +واضح؟ و السيلو بيوز من بيتا و بيتا جولوكوز الآن + +226 +00:20:57,790 --> 00:21:02,470 +هدولة لما بيجوا بيعملوا بوليمار كبير لما بيعملوا + +227 +00:21:02,470 --> 00:21:06,750 +بوليمار كبير بيكون هم الوحدة الأساسية المتكررة في + +228 +00:21:06,750 --> 00:21:12,930 +البوليمار بيعطوناالـ starch أو النشا في حالة ما + +229 +00:21:12,930 --> 00:21:18,570 +نتكلم عن إيش؟ عن الملتوز، في حالة ما نتكلم عن + +230 +00:21:18,570 --> 00:21:22,990 +السيلوبايوز، بيعطينا السيليلوز، واضح؟ فالملتوز + +231 +00:21:22,990 --> 00:21:29,130 +بيعطيني إيش؟ النشا، starch، السيلوبايوز بيعطيني + +232 +00:21:29,130 --> 00:21:36,470 +السيليلوز، الخشب، واضح؟ بولمار كبير طبعاًلاحظوا + +233 +00:21:36,470 --> 00:21:40,990 +عاد حسب ال polymer اللي بتكون يعني يوم ما نحكي عن + +234 +00:21:40,990 --> 00:21:45,550 +polymer يعني عدد كبير من الشغلات هتلاحظوا في علم + +235 +00:21:45,550 --> 00:21:50,250 +ال polymerization هذا العدد ممكن يكون 300 وحدة + +236 +00:21:50,250 --> 00:21:56,200 +ممكن يكون الف ممكن يكون تلت تلافتمام؟ حسب طريقة + +237 +00:21:56,200 --> 00:21:59,420 +الارتباط اللى موجودة في هذا العدد وحسب عدد + +238 +00:21:59,420 --> 00:22:03,760 +الجزيئات او الوحدات المكونة له الآن وحدة ال stars + +239 +00:22:03,760 --> 00:22:08,300 +هي ايش؟ ال maltose هذه الوحدة اللى مكونة من سكرين + +240 +00:22:08,300 --> 00:22:13,160 +حسب كمية الأشياء المتصلة بيصير عند نوع ال polymer + +241 +00:22:13,160 --> 00:22:16,340 +عشانك انتوا بال plastic بتلاحظوا في عندكوا أنواع + +242 +00:22:16,340 --> 00:22:21,460 +كتيرةفي النيلون في عندكم أنواع كتيرة هذا بيصير + +243 +00:22:21,460 --> 00:22:25,860 +يدخل فيه جانب الصناعة انه قداش العدد اللي خلناه + +244 +00:22:25,860 --> 00:22:31,640 +يتحد تقريبا يعمل polymer هالخليه 300 جزء و وحدة ال + +245 +00:22:31,640 --> 00:22:37,640 +polymer 3000 2000 واضح الفكرة؟ الآن نفس الفكرة من + +246 +00:22:37,640 --> 00:22:43,350 +الملتوز هلاحظ ان في انهاالـ starch لو حللته + +247 +00:22:43,350 --> 00:22:47,990 +بيعطيني ملتوز، الملتوز لو حللته بيعطيني جولوكوز، + +248 +00:22:47,990 --> 00:22:52,830 +لكن جولوكوز Alpha + +249 +00:22:53,990 --> 00:22:58,410 +وبيتاجولوكوز لكن هذه الوحدة المتكررة وحدة الملتوز + +250 +00:22:58,410 --> 00:23:03,350 +اعملوا منها عدد كبير الان لاحظوا ان النشا مكون من + +251 +00:23:03,350 --> 00:23:08,230 +شغلتين من اميلوز بنسبة 20% والباقي تقريبا + +252 +00:23:08,230 --> 00:23:15,200 +اميلوبكتل ايش بيفرقوا هدولة الشغلتين؟بعدد الجزيئات + +253 +00:23:15,200 --> 00:23:19,980 +المكونة له بطريقة الاتحاد يعني ال amylose في + +254 +00:23:19,980 --> 00:23:25,840 +جولوكوز units عادة بيكون عددها ما يقارب بين خمسين + +255 +00:23:25,840 --> 00:23:30,260 +لتلتمية جولوكوز unit لكن أهم شيء بيميزها أن هي + +256 +00:23:30,260 --> 00:23:37,970 +موجودة في إيش؟بسلاسل بدون تفرعات، واضح؟ سلاسل بهذا + +257 +00:23:37,970 --> 00:23:42,830 +الشكل بدون ما يصير فيها تفرعات، العدد تبع ال + +258 +00:23:42,830 --> 00:23:47,410 +geolocose units بيكون ما بين خمسين إلى تلتمية + +259 +00:23:47,410 --> 00:23:52,770 +geolocose unit والاتحاد زي ما انتوا عارفين نمر + +260 +00:23:52,770 --> 00:23:58,270 +أربعة من هان وبتحد من واحد مع الجزء التانييعني + +261 +00:23:58,270 --> 00:24:02,190 +احنا لما كنا نتكلم عن ال مالتوز، كنا هنا في عنا + +262 +00:24:02,190 --> 00:24:07,550 +الاتحاد مع أربعة أو سابين واحد، أوقتش، الآن لما + +263 +00:24:07,550 --> 00:24:11,150 +بتعمل polymer، بيجيب التحد منها، يعني لو انتوا + +264 +00:24:11,150 --> 00:24:16,630 +تذكرتوا المالتوز، مش كانت هذه تكون فيهقواتش لما + +265 +00:24:16,630 --> 00:24:20,930 +نحكي عن الملتوز لوحده الآن بيصير يتحد من هذه + +266 +00:24:20,930 --> 00:24:23,690 +القواتش عشان يعمل ال polymer يعني القواتش اللي + +267 +00:24:23,690 --> 00:24:28,610 +كانت ماتروكة فاضية بيصير يتحد من خلالها مع موقع + +268 +00:24:28,610 --> 00:24:33,130 +أربعة من وحدة ملتوز تانية بطلع عنده جزء كبير + +269 +00:24:33,130 --> 00:24:34,210 +بنسميه إيش + +270 +00:24:37,020 --> 00:24:43,020 +الاميلوز الاميلوز هذا احد مكونات النشا الان النشا + +271 +00:24:43,020 --> 00:24:49,260 +في مكون تاني الاميلوبكتين الاميلوبكتين في ما بين + +272 +00:24:49,260 --> 00:24:53,460 +تلتمية الى خمستلاف جولوكوز units يعني الجولوكوز + +273 +00:24:53,460 --> 00:24:59,860 +units اللى في عددها اكبر لكن اهم شغل فيه is + +274 +00:24:59,860 --> 00:25:06,920 +هايلبراجد واضح يعني الاميلوز سلسلةالـ amylobectin + +275 +00:25:06,920 --> 00:25:13,440 +في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300 + +276 +00:25:13,440 --> 00:25:17,220 +إلى 5000 جولوكوز units is a highly branched + +277 +00:25:17,220 --> 00:25:21,660 +molecule او highly branched molecule chains with + +278 +00:25:21,660 --> 00:25:24,360 +consecutive one four links شوفنا كيف one four + +279 +00:25:24,360 --> 00:25:28,520 +links الارتباط ال average يعني كل مجموعة حوالي + +280 +00:25:28,520 --> 00:25:35,070 +خمسة وعشرين لتلاتين وحدةو بعدين بيجي تفرع 25 ل 30 + +281 +00:25:35,070 --> 00:25:41,110 +و تفرع بيصير الجزء أشماله highly branched واضح + +282 +00:25:41,110 --> 00:25:48,470 +فواضح أن جزء ال amylobectin أكبر من ال amylose و + +283 +00:25:48,470 --> 00:25:55,150 +بنفس الوقت اللي بيميزه التفرعات واضح فال amylose + +284 +00:25:55,150 --> 00:26:02,220 +is a chain moleculeالـ amylobectin هو جزئ عالي جزئ + +285 +00:26:02,220 --> 00:26:11,520 +فيه تفرعات كتيرة طبعا هذه كل أشكال تقريبية بتوضح + +286 +00:26:11,520 --> 00:26:20,720 +لنا كيف بيتكونوا هذول الجزيئات الأن لو جينا من ال + +287 +00:26:20,720 --> 00:26:30,470 +amylose أيضاغير النشق بمكوينه يعني من الملتوز كان + +288 +00:26:30,470 --> 00:26:35,130 +في عنده ال starch اللي هو مكوّن من amylose و + +289 +00:26:35,130 --> 00:26:40,470 +mylobectin أيضًا من الملتوز في عنده الجليكوجين ال + +290 +00:26:40,470 --> 00:26:45,470 +starch ما كان تخزين ال carbohydratesفي النبات + +291 +00:26:45,470 --> 00:26:49,410 +الجليكوجين مكان تخزين ال carbohydrates في + +292 +00:26:49,410 --> 00:26:55,750 +الحيوانات برضه هو فيه جولوكوز units لكن حوالي مائة + +293 +00:26:55,750 --> 00:27:00,590 +ألف جولوكوز unit لاحظوا العدد في الجليكوجين + +294 +00:27:00,590 --> 00:27:06,810 +جليكوجين بيزيد بشكل كبير وبرنشد يعني كل ما بين كل + +295 +00:27:06,810 --> 00:27:11,010 +تمانية ل 12 جولوكوز unit خلينا هيك نتخيل هتلاحظوا + +296 +00:27:11,010 --> 00:27:17,930 +ان في عندكم إيشالجزء هذا الجليكوجين بيكون أيضا + +297 +00:27:17,930 --> 00:27:24,090 +highly branched الآن الجليكوجين بيجي من الجلوكوز + +298 +00:27:24,090 --> 00:27:30,130 +اللي بيمتص من أمعاء produced from glucose that is + +299 +00:27:30,130 --> 00:27:35,930 +absorbed from intestines into the blood الآن إيش + +300 +00:27:35,930 --> 00:27:41,060 +وظيفته هذا الجليكوجين؟ يمكن مار عليكمبيولوجيا اللي + +301 +00:27:41,060 --> 00:27:45,260 +هو توازن السكر helps maintain the glucose balance + +302 +00:27:45,260 --> 00:27:49,660 +واضح يعني إذا في عندي جولوكوز ازيادة بيجي و بتخزن + +303 +00:27:49,660 --> 00:27:54,340 +وين في الجليكوجين بدخل ضمن البوليمار الآن إذا + +304 +00:27:54,340 --> 00:28:00,770 +الجسم نقص عليه الجولوكوزبصير هذا نفسه يفرز أو يعطي + +305 +00:28:00,770 --> 00:28:07,930 +الجسم وحدات جولوكوز واضح الفكرة؟ يعني هو كأنه هاي + +306 +00:28:07,930 --> 00:28:12,450 +جزيئات الجولوكوز بتقدروا تتخيلوها بتمطس من المعدة + +307 +00:28:12,450 --> 00:28:16,030 +المفروض لازم لحرق الأكل الناس اللي بياكلوا كتير + +308 +00:28:16,030 --> 00:28:21,510 +okay بنجمع هذه الجزيئات هيعملنا إيش؟جلايكوجين + +309 +00:28:21,510 --> 00:28:25,790 +وخزانة الان بعد هيك صار البني ادم عنده ناقص في + +310 +00:28:25,790 --> 00:28:31,010 +السكر جد ما فيه ناقص بيصير يطلع له جولوكوز واضح؟ + +311 +00:28:31,010 --> 00:28:36,090 +واضحة الفكرة العامة خليني اقول العامة جدا + +312 +00:28:36,090 --> 00:28:42,890 +لجلايكوجين الان لو طلعنا على ال cellulose ال + +313 +00:28:42,890 --> 00:28:48,830 +cellulose هو ال polymerاللي جاي من الـ cellobiose + +314 +00:28:48,830 --> 00:28:55,010 +اللي بيعمل الخشب يعني النشا والجليكوجين جايين من + +315 +00:28:55,010 --> 00:29:01,430 +وين؟ من الملتوز من الملتوز لكن ال cellulose جاي من + +316 +00:29:01,430 --> 00:29:03,410 +ال cellobiose + +317 +00:29:05,410 --> 00:29:11,210 +بيتا وبيتا sugar فالcellulose is an unbranched + +318 +00:29:11,210 --> 00:29:16,210 +polymer مستقيم مافيش فيه branches of glucose + +319 +00:29:16,210 --> 00:29:20,110 +joined by one four beta glycosidic bonds كل + +320 +00:29:20,110 --> 00:29:29,390 +هالكلام شفناه لاحظوا معي كيف فرق في الأساس بسيط + +321 +00:29:29,390 --> 00:29:37,500 +جدا انه هذا منسيلو بيوز هذا من مالتوز السيلو بيوز + +322 +00:29:37,500 --> 00:29:42,260 +و المالتوز متحدين في beta غلوكوز لكن السكر التاني + +323 +00:29:42,260 --> 00:29:46,820 +في كل واحدة واحد منهم واحد alpha واحد beta يعني + +324 +00:29:46,820 --> 00:29:51,120 +خلينا نقول هنا في عند بيتا و بيتا نفس الاشي في + +325 +00:29:51,120 --> 00:29:57,340 +السكرين الآن في المالتوز هذا alpha في السيلو بيوز + +326 +00:29:58,430 --> 00:30:03,590 +هذا beta فهذا alpha beta هذا beta beta الآن هذا + +327 +00:30:03,590 --> 00:30:07,690 +بيصير ملتوز و بيعملني نشا و glycogen هذا بيصير + +328 +00:30:07,690 --> 00:30:12,970 +cellulose و cellobiose و بيعمله ال cellulose الان + +329 +00:30:12,970 --> 00:30:16,990 +البني آدم بيقدر يهضم النشا بيقدر يهضم ال glycogen + +330 +00:30:16,990 --> 00:30:22,670 +بيقدرش يهضم ال cellulose ال cellulose واضح فال + +331 +00:30:22,670 --> 00:30:26,830 +humans and other animals they digest starch and + +332 +00:30:26,830 --> 00:30:32,880 +glycogenبيقدروا يهضموا النشق والجليكوجين، الآن + +333 +00:30:32,880 --> 00:30:37,360 +الحيوانات + +334 +00:30:37,360 --> 00:30:42,610 +والنمليمكن تقولوا النمل صار أقوى من البني آدم يعني + +335 +00:30:42,610 --> 00:30:46,550 +هو النمل بيقدر يخضم الخشب و البني آدم مابيقدرش + +336 +00:30:46,550 --> 00:30:52,030 +معنا ذلك النمل أقوى من البني آدم هي المشكلة انه + +337 +00:30:52,030 --> 00:30:57,150 +كمان مش النمل اللي بيخضم او مش الحيوانات المجترة + +338 +00:30:57,150 --> 00:31:01,570 +اللي بتخضم لأ بكتيريا موجودة جوا أمعاها هذه + +339 +00:31:01,570 --> 00:31:05,050 +البكتيريا اللي جوا أمعاها بتفرز اللي هو + +340 +00:31:08,560 --> 00:31:14,060 +الانزيمات اللى هى ال beta glycosidase اللى بتساعد + +341 +00:31:14,060 --> 00:31:19,960 +على عملية ايش ان تقدر تهضم الخشب وتستفيد منه واضح + +342 +00:31:19,960 --> 00:31:27,760 +فماني بكتيريا contain beta glycosidase دايما اذا + +343 +00:31:27,760 --> 00:31:33,510 +شفتوا هذه النهاية ايش هذاالنزيم Oxidase و + +344 +00:31:33,510 --> 00:31:37,870 +Redactase و glycosidase and they can hydrolyze + +345 +00:31:37,870 --> 00:31:42,810 +يعني يفككوا ال cellulose فلو احنا قلنالكم ان ال + +346 +00:31:42,810 --> 00:31:46,090 +humans can hydrolyze cellulose + +347 +00:31:48,210 --> 00:31:52,250 +واضح؟ لكن في بكتيريا كتير بتقدر تعمل هذا الكلام + +348 +00:31:52,250 --> 00:31:55,990 +هذه موجودة في ال termites اللي هو النمل الأبيض و + +349 +00:31:55,990 --> 00:31:59,510 +ال ruminants اللي هي الحيوانات المجترة اللي + +350 +00:31:59,510 --> 00:32:03,050 +بتلاقوها مستعدة تاكل ال .. إيش؟ زي الجمل و زي .. + +351 +00:32:03,050 --> 00:32:08,250 +أه اللي بتاكل الخشب فبكتيريا في معدتها بتقدر تدخل + +352 +00:32:08,250 --> 00:32:13,450 +على هذا الخشب و تحلله لوحدات السكر بحيث أنه النمل + +353 +00:32:13,450 --> 00:32:18,430 +الأبيض أو الحيوانات هذه المجترة تقدر تستفيد منهأو + +354 +00:32:18,430 --> 00:32:22,310 +من السكر اللي موجود فيه لكن البني آدم مابيقدرش + +355 +00:32:22,310 --> 00:32:26,730 +يخدمه أخر + +356 +00:32:26,730 --> 00:32:33,090 +شغلة أخر شغلة بنحكيها بالنسبة لهذا الجزء أنه في + +357 +00:32:33,090 --> 00:32:37,870 +عندى بعض ال sugars يمكن أن ينزع منها أكسجين هذه + +358 +00:32:37,870 --> 00:32:42,850 +بتفيدنا لما بدنا ندرس ال nuclear acid اللي هي + +359 +00:32:42,850 --> 00:32:49,090 +الأحماض النووية ومنهابصير اسمها deoxy sugars يعني + +360 +00:32:49,090 --> 00:32:53,470 +لاحظوا هذا ال sugar لما يكون فيه ال oxygen و سكر + +361 +00:32:53,470 --> 00:32:58,610 +من خمس كربونات tripose تمام لما نشيل منه oxygen + +362 +00:32:58,610 --> 00:33:02,870 +منها يعني في الأصل كان في عنده OH لو شيلنا منه + +363 +00:33:02,870 --> 00:33:09,490 +oxygen ايش بيصير اسمه؟ deoxy، deoxy يعني منزوعأه + +364 +00:33:09,490 --> 00:33:14,570 +لحظة ميزه .. ميزه رجاء في الكلمات، عشانك احنا + +365 +00:33:14,570 --> 00:33:22,080 +بنقول اتعبوا شوية، يعني لو اتينا قولنالكم ضايقزيدا + +366 +00:33:22,080 --> 00:33:27,800 +يعني اتنين اه لكن دي منزوعة زي ما كنا نقول + +367 +00:33:27,800 --> 00:33:31,760 +hydrogenation, dehydrogenation, hydration, + +368 +00:33:32,600 --> 00:33:38,260 +dehydrogenation, halogenation, dehydrogenation فال + +369 +00:33:38,260 --> 00:33:43,820 +دي بتاعنا اللي هو العكس فهذا ال beta دي دي + +370 +00:33:43,820 --> 00:33:48,860 +oxyribofuranose طب علشه فيورانوز لأنهمن حلقاء + +371 +00:33:48,860 --> 00:33:53,520 +خماسية هو ال sugar تبع ال DNA هو عبارة عن Ribose + +372 +00:33:53,520 --> 00:33:58,720 +نزعت منه ال Oxygen و لو كان ال Ribose اللي في ال + +373 +00:33:58,720 --> 00:34:05,400 +Oxygen بيعملنا ال RNA Ribonucleic Acid لما يكون ال + +374 +00:34:05,400 --> 00:34:09,800 +DNA Deoxyribonucleic Acid واضح؟ + +375 +00:34:12,560 --> 00:34:19,700 +الكلام عام عن اللي هي ال dice carats و عن ال + +376 +00:34:19,700 --> 00:34:26,210 +polymers اللي بتكونوا منهم خلينا يعني نبدأنعطي + +377 +00:34:26,210 --> 00:34:31,310 +فكرة عامة ليش أنا محتاجها الآن مقارنة مع + +378 +00:34:31,310 --> 00:34:37,050 +البروتينات اللي بدنا ناخدها في الفصل الأخير ان شاء + +379 +00:34:37,050 --> 00:34:41,910 +الله اللي هو ال amino acids و ال peptides و ال + +380 +00:34:41,910 --> 00:34:48,210 +proteins زي ما لاحظته يمكن أهم شغلة في ال + +381 +00:34:48,210 --> 00:34:52,290 +polysaccharides أهم شغلة في ال polysaccharides أن + +382 +00:34:52,290 --> 00:34:57,650 +هم polymersماذا يعني polymers؟ يعني لما أقول + +383 +00:34:57,650 --> 00:35:04,150 +النشا، إيش الوحدة تبعته؟ هتقولولي مالتوز + +384 +00:35:04,150 --> 00:35:10,390 +البيسكريدي المالتوز، تمام؟ لو قولت مثلا السيللوز، + +385 +00:35:10,390 --> 00:35:15,870 +بوليمر كبير، إيش الوحدة تبعته؟ السيلوبيوز، ولذلك + +386 +00:35:15,870 --> 00:35:23,490 +ال polysaccharidesيمكن التعامل معها يكون أسهل كتير + +387 +00:35:23,490 --> 00:35:28,790 +من التعامل مع البروتينات ليش؟ لأن ال + +388 +00:35:28,790 --> 00:35:32,930 +polysaccharides عندي وحدة و بتتكرر يعني كأن + +389 +00:35:32,930 --> 00:35:37,110 +الإنسان بيقدر يقول عنهم ان they are real polymers + +390 +00:35:37,110 --> 00:35:43,710 +واضح؟ ال polymers مكون من إيش؟مونومارز تتحد تصير + +391 +00:35:43,710 --> 00:35:47,910 +دايمارز، ترايمارز، تترامارز، في الآخر إيش؟ + +392 +00:35:47,910 --> 00:35:55,190 +بوليمارز، فالبوليمار من ناحية المبدأ وحدة متكررة، + +393 +00:35:55,190 --> 00:36:00,390 +البوليمار وحدة إيش مالها؟ متكررة، فلمّا أجي أقول + +394 +00:36:00,390 --> 00:36:05,990 +starch polymer ما وحدته المتكررة؟ الملتوز، انتهى + +395 +00:36:06,580 --> 00:36:13,060 +واضح؟ الآن لما بدي اجي .. لما بدي اجي اتكلم عن ال + +396 +00:36:13,060 --> 00:36:18,900 +proteins هلاحظ ان في عندي اختلاف أساسي ال proteins + +397 +00:36:18,900 --> 00:36:26,580 +عبارة عن amino acids وال amino acids مختلفين + +398 +00:36:27,350 --> 00:36:33,110 +واضح ال amino acids مختلفين ولذلك انا لما بدي اجي + +399 +00:36:33,110 --> 00:36:38,050 +اعمل مثلا نشا بقدر اقول بقدر اقول في حالة النشا او + +400 +00:36:38,050 --> 00:36:44,630 +ال amylose مالتوز تلاتين + +401 +00:36:44,630 --> 00:36:50,320 +وحدة مثلا او تلاتميت وحدةملتوز 300 وحدة واضح؟ + +402 +00:36:50,320 --> 00:36:56,520 +الملتوز مكرر كده؟ 300 مرة هاي صرت عامل مثلا اميلوز + +403 +00:36:56,520 --> 00:37:01,240 +لكن لو جيت بدي اعمل البروتين او الأصغر من البروتين + +404 +00:37:01,240 --> 00:37:04,720 +ال بيبتايد اللي هيمر علينا بعد شوية مابقدرش اعمل + +405 +00:37:04,720 --> 00:37:09,460 +مثل هذه المعادلة واضح؟ يعني هذه المعادلة ان اقول + +406 +00:37:09,460 --> 00:37:15,860 +انه is a real polymerاللي هي ال polysaccharides + +407 +00:37:15,860 --> 00:37:21,480 +مالتوز منه تلاتمية وحدة او منه مائة الف وحدة في ال + +408 +00:37:21,480 --> 00:37:26,640 +glycogen على سبيل المثال او ما إلى ذلك هي وحدة و + +409 +00:37:26,640 --> 00:37:32,680 +متكررة لما بدي اجي احكي عن ال protein + +410 +00:37:36,730 --> 00:37:43,590 +هلاحظ ان البروتين عبارة عن amino acids عدد كبير من + +411 +00:37:43,590 --> 00:37:49,190 +ال amino acids الان كل amino acid من ناحية المبدأ + +412 +00:37:49,190 --> 00:37:56,730 +بختلف عن التاني يعني خليني اتخيل ان هذا حقيقة بمثل + +413 +00:37:56,730 --> 00:38:03,490 +البروتين الان هذا بقدر احط عليه كذا to the N لأ طب + +414 +00:38:03,490 --> 00:38:10,740 +ايش المطلوب اعمله؟أعمله إيش التسلسل تبعه، يعني لو + +415 +00:38:10,740 --> 00:38:14,600 +اتخيلت أنا أن هذا بروتين صغير، يعني بيبتايد، بقول + +416 +00:38:14,600 --> 00:38:19,700 +لحظة معايا إيش التسلسل تبعه من amino acids، أسود، + +417 +00:38:19,700 --> 00:38:27,230 +أخضر، أحمر، أسود، أزرقتمام؟ الآن كل واحد شكل من + +418 +00:38:27,230 --> 00:38:29,870 +هدول، يعني هذا في الـ amino acids ممكن يكون + +419 +00:38:29,870 --> 00:38:36,990 +إجليسين، ألانين، سيستين، تريبتوفان، كذا، فما بقدرش + +420 +00:38:36,990 --> 00:38:38,830 +أصيغه بصيغة + +421 +00:38:41,480 --> 00:38:45,080 +amino acid و بعدين اقول عنه to the end فالان + +422 +00:38:45,080 --> 00:38:51,640 +تخيلوا لو كان في عندي مثلا protein من 300 amino + +423 +00:38:51,640 --> 00:38:58,780 +acid عشان اعرفه جيدا ايش المطلوب مني اعمل احدد ال + +424 +00:38:58,780 --> 00:39:04,200 +300 amino acid مرتبين هذا بيسموه ايش؟ sequence + +425 +00:39:04,200 --> 00:39:11,930 +يعني كيف هدول مرتبينأعمل التسلسل تبعه، الآن فكرة + +426 +00:39:11,930 --> 00:39:16,490 +ال sequence أو التسلسل غير موجودة في ال + +427 +00:39:16,490 --> 00:39:21,170 +polysaccharides، ال polysaccharides نفس الشغلة to + +428 +00:39:21,170 --> 00:39:28,380 +the Nمالتوز to the M خلصت واضح بينما في ال + +429 +00:39:28,380 --> 00:39:33,100 +proteins هتواجهنا صعوبة ان ال proteins وحدتهم + +430 +00:39:33,100 --> 00:39:37,660 +الأساسية amino acids ال amino acids عادة اللي + +431 +00:39:37,660 --> 00:39:41,720 +موجودين في ال protein عشرين amino acid الان لما + +432 +00:39:41,720 --> 00:39:50,400 +يكون عندى protein من تلتمية amino acid كويس + +433 +00:39:50,400 --> 00:39:56,960 +في أشياء مكررة لكنلابد من ال sequence هم اكيد هم + +434 +00:39:56,960 --> 00:40:00,580 +اكيد عشرين amino acid تقريبا اللي موجودين في ال + +435 +00:40:00,580 --> 00:40:07,180 +proteins لكن هدول العشرين لما بدي اخد منهم protein + +436 +00:40:07,180 --> 00:40:15,700 +من تلاتمية amino acid كيف هيكونوا؟ هيكونوا + +437 +00:40:15,700 --> 00:40:22,050 +مختلفين مافيش ان احك مثلا glycine to the Nعشان + +438 +00:40:22,050 --> 00:40:28,290 +اميز اي protein عن التاني لازم اعد ال 300 ولذلك ال + +439 +00:40:28,290 --> 00:40:32,950 +protein لو انا بدى اتكلم عنه انه هل هو real + +440 +00:40:32,950 --> 00:40:40,870 +polymer يعني حقيقي بمعنى الكلمة الجواب لأ ال real + +441 +00:40:40,870 --> 00:40:48,390 +polymer حقيقة ايش هو؟ monomerto the end زي ما + +442 +00:40:48,390 --> 00:40:52,770 +شوفنا ال polyethylene و ال PVC و حتى كمان ال + +443 +00:40:52,770 --> 00:40:57,750 +polysaccharides مونومر مكرر لكن هنا لما بدي أجي + +444 +00:40:57,750 --> 00:41:01,570 +أحكي عن ال protein هصير أجيب ال amino acids أقول + +445 +00:41:01,570 --> 00:41:07,910 +glycine, alanine, tryptophan, cysteine كذا كذا + +446 +00:41:07,910 --> 00:41:14,270 +هتلاحظوا أنه مطلوب منناانحدد الترتيب تبع ال amino + +447 +00:41:14,270 --> 00:41:17,690 +acids ولذلك ال proteins لو الإنسان بده يستعمل + +448 +00:41:17,690 --> 00:41:23,010 +الكلام بدقة أكثر they are macro molecules جزيئات + +449 +00:41:23,010 --> 00:41:30,490 +كبيرة macro molecules جزيئات كبيرة أكثر منهم إيش + +450 +00:41:30,490 --> 00:41:39,610 +polymers they are macro molecules أكثر منهمبولمار + +451 +00:41:39,610 --> 00:41:46,310 +طبعا فيهم نوعا ما شيء مشترك بيخلي بعض الناس يقولوا + +452 +00:41:46,310 --> 00:41:54,670 +ممكن تجاوزا نعتبر ال protein بولمار ليش؟ لأنه لو + +453 +00:41:54,670 --> 00:42:00,010 +أنا اتطلعت على الهيكل تبعه اللي بتكرر هلاحظ ان هو + +454 +00:42:00,010 --> 00:42:05,960 +عبارة عن NCEالان هذه الوحدة بتتكرر في البروتين + +455 +00:42:05,960 --> 00:42:12,760 +بعدها N C C double bond O بعدها N C C double bond + +456 +00:42:12,760 --> 00:42:19,220 +O هتقولولي مش ناقص غير ايش تكتب هذولة to the N طب + +457 +00:42:19,220 --> 00:42:25,870 +ليش مش قادر اكتبهم؟لأن كل amino acid فيها R group + +458 +00:42:25,870 --> 00:42:33,210 +مختلفة يعني هذه مرة H هذه مرة CH3 هذه مرة CH2SH + +459 +00:42:33,210 --> 00:42:40,430 +فلو بتطلع على الهيكل الأساسي للذرات لبروتين NCC + +460 +00:42:40,430 --> 00:42:45,870 +double bond O هو مكرر لكن لو طلعت على هذه المجموعة + +461 +00:42:46,670 --> 00:42:51,530 +مش مكررة بناء على ذلك لو هذا مثلا كان بيبتايد هذا + +462 +00:42:51,530 --> 00:42:55,810 +بيبتايد مكون من كام amino acid من تلاتة هتعلم أن + +463 +00:42:55,810 --> 00:43:00,570 +هذا اسمه إجليسين هذا اسمه ألانين هذا اسمه سيستين + +464 +00:43:00,570 --> 00:43:05,450 +حصير أقول هذاEglicin, Alanine, Cysteine هيكون بفرق + +465 +00:43:05,450 --> 00:43:08,390 +عن Alanine, Eglicin, Cysteine من نفس التلاتة + +466 +00:43:08,390 --> 00:43:14,810 +فانفعلكوا لما نصيح نحكي عن تلاتمية فالبروتين بوجهة + +467 +00:43:14,810 --> 00:43:19,870 +النظر اللي بده يتطلع الهيكل الأساسي هو كأنه بوليمر + +468 +00:43:19,870 --> 00:43:25,170 +امكرر في N, C, C double bond O N, C, C double bond + +469 +00:43:25,170 --> 00:43:28,950 +O لكن لما نيجي نلاحظ أن هذه المجموعة اللي هنا + +470 +00:43:28,950 --> 00:43:36,740 +اختلفتبطل polymer ولذلك ال polymer مابنعدش ال 300 + +471 +00:43:36,740 --> 00:43:40,680 +وحدة ولا ال 5000 وحدة تبعته بس ال protein بدي + +472 +00:43:40,680 --> 00:43:45,860 +أجهزة و بدي علم يوم أقول هذا protein كذا يذكر لل + +473 +00:43:45,860 --> 00:43:54,170 +5000 وحدة مرتبين و نفس الاشي هيتكرر معاكم مهمفي ال + +474 +00:43:54,170 --> 00:43:58,670 +nucleic acids عشان هيك في الشفرة الوراثية وغيرها + +475 +00:43:58,670 --> 00:44:02,570 +وغيراتها هتلاحظوا ان البني ادم بيختلف عن التاني و + +476 +00:44:02,570 --> 00:44:07,270 +الشغل بتختلف عن التاني انه بدي اذكر الأشياء مرتبة + +477 +00:44:08,550 --> 00:44:18,550 +كذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا + +478 +00:44:18,550 --> 00:44:19,230 +وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا + +479 +00:44:19,230 --> 00:44:19,250 +وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا + +480 +00:44:19,250 --> 00:44:19,450 +وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا + +481 +00:44:19,450 --> 00:44:22,470 +وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا + +482 +00:44:22,470 --> 00:44:25,070 +وكذا + +483 +00:44:25,690 --> 00:44:30,730 +جزيئات كبيرة اكثر من ان نسميها Polymers و نقدر + +484 +00:44:30,730 --> 00:44:35,170 +نكتب شغلته دي انا الان حيصير درسنا القادم سهل اللي + +485 +00:44:35,170 --> 00:44:39,730 +بده يدرس ال proteins ايش أساسهم اذا اول شئ بدنا + +486 +00:44:39,730 --> 00:44:45,310 +نتعلم على ال amino acids بعدين ال amino acids بتحد + +487 +00:44:45,310 --> 00:44:48,890 +و بيعملوا ال protein نتعلم كيف نوجد ال sequence و + +488 +00:44:48,890 --> 00:44:53,390 +كيف نحضر ال protein لو بدنايالكن حيكون ان شاء الله + +489 +00:44:53,390 --> 00:44:58,410 +درسنا القادم على الوحدة المكونة للبروتين اللي هي + +490 +00:44:58,410 --> 00:45:00,370 +عبارة عن ايش؟ الامام + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..d0f068143bbccb8c183919fb88088fb2f701e1e2 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4973, "start": 20.91, "end": 49.73, "text": "بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في تسمية ال aromatic compounds وركزنا على نقطة لما بيكون موجود عندنا اكثر من substituent نتبع المركب لأي مجموعة و القمر زي ما بتلاحظه بسيط من خلال انه اعطيناكم ترتيب معين من خلال انه اعطيناكم ترتيب معين يمكن في نقطة بدى انوحلها", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 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تكون عائلة فينول بتبطل عائلة بترجع هيدروكسي الكيتون مثلا هذه المجموعة لما تكون عائلة أسيتوفينون بطلت عائلة أسيتل", "tokens": [2407, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 6156, 28820, 44049, 38207, 11933, 15730, 19446, 41361, 8592, 31439, 18863, 16373, 37977, 47525, 3224, 7251, 47341, 3615, 5296, 28814, 1829, 8592, 22807, 5296, 32277, 2304, 3224, 46811, 10943, 995, 9673, 1829, 12984, 1211, 5296, 15042, 39894, 30544, 6225, 16373, 37977, 44945, 30544, 8717, 39648, 23032, 1211, 2407, 9957, 5296, 15042, 6055, 3555, 9566, 1211, 6225, 16373, 37977, 39894, 47341, 3615, 50113, 1211, 2423, 13931, 5296, 15042, 6055, 30544, 6225, 16373, 37977, 8978, 1863, 12610, 39894, 3555, 9566, 1211, 6225, 16373, 37977, 39894, 47341, 3615, 8032, 25708, 32887, 4117, 3794, 1829, 33251, 36081, 11536, 50113, 15040, 29538, 9673, 7435, 2304, 2407, 27884, 5296, 15042, 6055, 30544, 6225, 16373, 37977, 5551, 3794, 36081, 38688, 9957, 11536, 4724, 9566, 1211, 2655, 6225, 16373, 37977, 5551, 3794, 36081, 1211], 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50650, "start": 481.76, "end": 506.5, "text": "ال Formyl Benzaldehyde بطلت عائلة ترجع لإسم Formyl طبعا ربما البعض منكم يعرف أن Formyl أيضا جاية من هذه المجموعة اللي هي C double bond OH OH هذا اللي اسمه Formic Acid أبسط الأحماض العضوية", "tokens": [6027, 10126, 5088, 3964, 89, 304, 1479, 3495, 1479, 4724, 9566, 1211, 2655, 6225, 16373, 37977, 6055, 47341, 3615, 5296, 28814, 38251, 10126, 5088, 23032, 3555, 3615, 995, 12602, 3555, 15042, 29739, 3615, 11242, 9154, 24793, 37495, 28480, 14739, 10126, 5088, 36632, 11242, 995, 10874, 995, 10632, 9154, 29538, 9673, 7435, 2304, 2407, 27884, 13672, 1829, 39896, 383, 3834, 6086, 13931, 13931, 23758, 13672, 1829, 24525, 2304, 3224, 10126, 299, 5097, 327, 5551, 3555, 3794, 9566, 16247, 35571, 46958, 18863, 11242, 2407, 10632], "avg_logprob": -0.22302826653633798, "compression_ratio": 1.4467005076142132, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 481.76, "end": 482.06, "word": "ال", "probability": 0.69189453125}, {"start": 482.06, 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لوحدها كمجموعة عضوية ايش اسمها Formic اسمها Formic بالعربي هذا Formic Acid شو بيسموه حمض النمليك", "tokens": [10721, 3555, 3794, 9566, 16247, 35571, 46958, 18863, 11242, 2407, 10632, 13672, 1829, 8978, 3224, 389, 2423, 5097, 3532, 5097, 327, 8978, 3224, 50113, 1211, 6055, 7649, 1829, 11331, 2304, 11242, 6225, 11242, 45865, 44381, 5551, 3555, 3794, 9566, 36764, 24401, 8978, 16247, 35571, 46958, 18863, 11242, 2407, 10632, 13672, 1829, 24525, 2304, 3224, 1975, 1829, 8592, 10126, 299, 5097, 327, 16247, 16095, 9154, 3224, 29538, 9673, 7435, 2304, 2407, 27884, 45164, 24401, 11296, 9122, 2304, 7435, 2304, 2407, 27884, 6225, 11242, 2407, 10632, 1975, 1829, 8592, 24525, 2304, 11296, 10126, 299, 24525, 2304, 11296, 10126, 299, 20666, 3615, 2288, 21292, 23758, 10126, 299, 5097, 327, 13412, 2407, 4724, 1829, 38251, 2407, 3224, 11331, 2304, 11242, 28239, 2304, 20292, 4117], "avg_logprob": -0.1363636393192386, "compression_ratio": 2.0049261083743843, "no_speech_prob": 1.1920928955078125e-07, 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ال", "probability": 0.75146484375}, {"start": 698.26, "end": 698.66, "word": " يود", "probability": 0.732666015625}, {"start": 698.66, "end": 699.3, "word": " السالب", "probability": 0.9176432291666666}, {"start": 699.3, "end": 699.5, "word": " مع", "probability": 0.98583984375}, {"start": 699.5, "end": 700.48, "word": " الكتروناتو", "probability": 0.6834716796875}, {"start": 700.48, "end": 700.8, "word": " و", "probability": 0.91943359375}, {"start": 700.8, "end": 701.36, "word": " حطينا", "probability": 0.779541015625}, {"start": 701.36, "end": 702.8, "word": " الاسيتلايد", "probability": 0.84482421875}, {"start": 702.8, "end": 703.16, "word": " اخر", "probability": 0.884765625}, {"start": 703.16, "end": 703.7, "word": " تفاعل", "probability": 0.9423828125}, {"start": 703.7, "end": 703.84, "word": " في", "probability": 0.82421875}, {"start": 703.84, "end": 704.92, "word": " الاسيتليانز", "probability": 0.7977701822916666}, {"start": 704.92, "end": 705.38, "word": " قولنا", "probability": 0.6990559895833334}, {"start": 705.38, "end": 705.78, "word": " بنشيل", "probability": 0.9405924479166666}, {"start": 705.78, "end": 706.34, "word": " سالب", "probability": 0.9449869791666666}, {"start": 706.34, "end": 706.7, "word": " و", "probability": 0.8916015625}, {"start": 706.7, "end": 706.92, "word": " نحط", "probability": 0.7527669270833334}, {"start": 706.92, "end": 707.3, "word": " سالب", "probability": 0.98974609375}, {"start": 707.3, "end": 707.82, "word": " الان", "probability": 0.6552734375}, {"start": 707.82, "end": 708.22, "word": " لو", "probability": 0.9599609375}, {"start": 708.22, "end": 708.58, "word": " اجيت", "probability": 0.6455078125}, {"start": 708.58, "end": 709.16, "word": " قولتلكم", "probability": 0.83095703125}, {"start": 709.16, "end": 709.54, "word": " هذا", "probability": 0.96533203125}, {"start": 709.54, "end": 710.34, "word": " التفاعل", "probability": 0.9444580078125}, {"start": 710.34, "end": 710.58, "word": " شو", "probability": 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726.69, "word": " زوج", "probability": 0.982666015625}, {"start": 726.69, "end": 727.69, "word": " الإلكترونة،", "probability": 0.6643938337053571}, {"start": 727.69, "end": 728.21, "word": " تنتبهوا", "probability": 0.94658203125}, {"start": 728.21, "end": 729.07, "word": " معي", "probability": 0.95556640625}, {"start": 729.07, "end": 730.97, "word": " وجدت", "probability": 0.6897786458333334}, {"start": 730.97, "end": 731.23, "word": " بدي", "probability": 0.57525634765625}, {"start": 731.23, "end": 731.53, "word": " أجيب", "probability": 0.9722900390625}, {"start": 731.53, "end": 731.99, "word": " بدلها", "probability": 0.9195963541666666}, {"start": 731.99, "end": 732.53, "word": " موجب،", "probability": 0.9285888671875}, {"start": 732.53, "end": 733.03, "word": " نفترض", "probability": 0.982177734375}, {"start": 733.03, "end": 733.47, "word": " X", "probability": 0.91357421875}, {"start": 733.47, "end": 734.99, "word": " موجبة،", "probability": 0.8199462890625}, {"start": 734.99, "end": 735.23, "word": " CL", "probability": 0.406005859375}, {"start": 735.23, "end": 736.01, "word": " موجبة،", "probability": 0.8944091796875}, {"start": 736.01, "end": 736.31, "word": " شيلت", "probability": 0.9002278645833334}, {"start": 736.31, "end": 736.63, "word": " الاتش", "probability": 0.8395182291666666}, {"start": 736.63, "end": 737.65, "word": " الموجبة؟", "probability": 0.9791259765625}], "temperature": 1.0}, {"id": 33, "seek": 75368, "start": 738.16, "end": 753.68, "text": "حطيت ال X الموجبة هذه محصلة التفاعل إذا التفاعل إيش بيصير اسمه Electrophilic Aromatic Substitution ولذلك لو إحنا بنيجي بنسألكم مثلا aromatic compounds undergo addition reactions غلط", "tokens": [5016, 9566, 36081, 2423, 1783, 9673, 29245, 49401, 29538, 3714, 5016, 36520, 3660, 16712, 5172, 995, 30241, 11933, 15730, 16712, 5172, 995, 30241, 11933, 1829, 8592, 4724, 1829, 9381, 13546, 24525, 2304, 3224, 12575, 11741, 388, 299, 1587, 13143, 42090, 6518, 35525, 8848, 23275, 45164, 11933, 5016, 8315, 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"word": " aromatic", "probability": 0.272216796875}, {"start": 749.68, "end": 750.32, "word": " compounds", "probability": 0.908203125}, {"start": 750.32, "end": 750.9, "word": " undergo", "probability": 0.93603515625}, {"start": 750.9, "end": 751.66, "word": " addition", "probability": 0.8974609375}, {"start": 751.66, "end": 753.12, "word": " reactions", "probability": 0.69189453125}, {"start": 753.12, "end": 753.68, "word": " غلط", "probability": 0.7176106770833334}], "temperature": 1.0}, {"id": 34, "seek": 78413, "start": 754.33, "end": 784.13, "text": "Aromatic compounds undergo a nucleophilic aromatic substitution برضه غلط لليوكليوفال بيجربش عليها لأنها سالبة كثافة إلكترونية هنا فمين اللي بيقدر يجرب عليها الموجب فلمّا ينسقل الطالب سؤال عام حتى في مقابلة التوظيف لما الواحد بيسأل بهمش يخلي الطالب يعيد كل العلم بس ممكن يقوله ببساطة إيش التفاعل الأساسي لل aromatic compounds؟", "tokens": [10683, 13143, 21810, 26426, 257, 14962, 5317, 388, 299, 45831, 35827, 4724, 43042, 3224, 32771, 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771.83, "end": 772.45, "word": " ينسقل", "probability": 0.754638671875}, {"start": 772.45, "end": 772.97, "word": " الطالب", "probability": 0.9879557291666666}, {"start": 772.97, "end": 773.37, "word": " سؤال", "probability": 0.99462890625}, {"start": 773.37, "end": 773.75, "word": " عام", "probability": 0.998779296875}, {"start": 773.75, "end": 774.31, "word": " حتى", "probability": 0.7998046875}, {"start": 774.31, "end": 774.45, "word": " في", "probability": 0.85791015625}, {"start": 774.45, "end": 775.01, "word": " مقابلة", "probability": 0.9517822265625}, {"start": 775.01, "end": 775.59, "word": " التوظيف", "probability": 0.861572265625}, {"start": 775.59, "end": 775.79, "word": " لما", "probability": 0.78173828125}, {"start": 775.79, "end": 776.05, "word": " الواحد", "probability": 0.97265625}, {"start": 776.05, "end": 776.67, "word": " بيسأل", "probability": 0.98076171875}, {"start": 776.67, "end": 777.45, "word": " بهمش", "probability": 0.5625}, {"start": 777.45, "end": 777.89, 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b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..1b157970c11f1998963ad6b638431e622629faac --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-cZOKTp-RbM_raw.srt @@ -0,0 +1,2160 @@ +1 +00:00:20,910 --> 00:00:24,950 +بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في + +2 +00:00:24,950 --> 00:00:30,470 +تسمية ال aromatic compounds وركزنا على نقطة لما + +3 +00:00:30,470 --> 00:00:35,010 +بيكون موجود عندنا اكثر من substituent نتبع المركب + +4 +00:00:35,010 --> 00:00:42,550 +لأي مجموعة و القمر زي ما بتلاحظه بسيط من خلال انه + +5 +00:00:42,550 --> 00:00:45,890 +اعطيناكم ترتيب معين من خلال انه اعطيناكم ترتيب + +6 +00:00:45,890 --> 00:00:53,020 +معين يمكن في نقطة بدى انوحلهاحتى إذا واجهتكم ما + +7 +00:00:53,020 --> 00:00:59,260 +تتخربطوش فيها من خلال هذه المركبات لاحظوا مثلا هذا + +8 +00:00:59,260 --> 00:01:07,330 +المركب أعلى مجموعة في ال OH ولذلك سمناهفينول فينول + +9 +00:01:07,330 --> 00:01:15,130 +سمناها فينول واضح فبينت ال OH في نهاية المقطع بشكل + +10 +00:01:15,130 --> 00:01:21,290 +all الان السؤال لما ال OH ما تكونش هي المجموعة + +11 +00:01:21,290 --> 00:01:26,900 +اللي بدها تكون عائلة المركب تيجي عائلة أعلى منهاهي + +12 +00:01:26,900 --> 00:01:32,300 +إيش بده يصير فيها؟ بده ترجع لاسمها الأصل لما اتبعت + +13 +00:01:32,300 --> 00:01:37,740 +العائلة ولذلك في هذا المركب لما وجدت ال OH مع هذه + +14 +00:01:37,740 --> 00:01:42,820 +المجموعة الآن ال aldehyde أعلى من ال OH فالمركب + +15 +00:01:42,820 --> 00:01:49,280 +ساربينز الديهايد شو سميت ال OH؟ Hydroxy واضح؟ الآن + +16 +00:01:49,280 --> 00:01:54,820 +الكلام نفسه بتكرر لو أنا أعطيتكم مركب زي هذا مثلا + +17 +00:01:58,460 --> 00:02:04,760 +C double bond O CH3 و حطيت هنا CH3 الآن هنا في + +18 +00:02:04,760 --> 00:02:09,620 +عندك كيتون و الكلجروب العائلة الكيتون و هذا + +19 +00:02:09,620 --> 00:02:17,720 +الكيتون معروف اسمه أسيتوفينونواضح؟ أسيتوفينون فلما + +20 +00:02:17,720 --> 00:02:24,320 +أجي بدي أسم المركب بقول 4-methylacetophenone طيب + +21 +00:02:24,320 --> 00:02:30,580 +السؤال لو هذه المجموعة ماكنتش عائلة لو إجت مجموعة + +22 +00:02:30,580 --> 00:02:34,440 +أعلى منها و المجموعات الأعلى من الكيتون الالديهيد + +23 +00:02:34,440 --> 00:02:39,380 +أو الاسد أو ال Easter شو بيصير اسم هذه المجموعة؟ + +24 +00:02:40,130 --> 00:02:45,510 +واضح؟ يعني لو حطيت بمثل هذا المثال الآن هاي + +25 +00:02:45,510 --> 00:02:49,830 +الديهايد وهاي كيتون ال الديهايد أعلى من ال كيتون + +26 +00:02:49,830 --> 00:02:56,550 +إذا للجزء اللي عندي .. الجزء اللي عندي شو هو؟ بنز + +27 +00:02:56,550 --> 00:03:02,390 +الديهايد طب هذه المجموعة CH3C double bond O إيش + +28 +00:03:02,390 --> 00:03:07,800 +اسمها؟ الان بديكوا تعرفوا إن اسمها Acetylبنعرف إن + +29 +00:03:07,800 --> 00:03:13,000 +اسمها Acetyl الان هذه المجموعة جاية من وين أساساً + +30 +00:03:13,000 --> 00:03:18,360 +جاية من حمب ال Acetic Acid اللي هو حمب الخلق لو + +31 +00:03:18,360 --> 00:03:26,040 +احنا اتطلعنا على ال Acetic Acid CH3COOH + +32 +00:03:26,040 --> 00:03:33,870 +تمام الان مجموعة ال Acetyl هنا هي هذه المجموعةهذه + +33 +00:03:33,870 --> 00:03:37,050 +الاستيل وبنرمزلها عادة بالرمز + +34 +00:03:40,120 --> 00:03:45,720 +AC و لذلك لو كان عندكم مثلا مركب مكتوب عليه AC + +35 +00:03:45,720 --> 00:03:50,620 +بتكون تعرف ان هذه مجموعة ايش ال Acetal اللي هي + +36 +00:03:50,620 --> 00:03:57,860 +CH3C double bond O لوحدها الان مر علي مجموعة تانية + +37 +00:03:57,860 --> 00:04:04,800 +بتشبهها لو انا أخدت CH3C double bond O مع ال + +38 +00:04:04,800 --> 00:04:10,410 +Oxygenعرفت الآن الـ Acetyl فقط هذا الجزء طب يا + +39 +00:04:10,410 --> 00:04:17,150 +تورا لو أخدت هذه كمجموعة CH3C O O و عادة هذه تكون + +40 +00:04:17,150 --> 00:04:22,830 +minus ممكن يكون معها NA plus نتذكر هذه إيش اسمها + +41 +00:04:22,830 --> 00:04:30,590 +كلها كمجموعة هذه بتصير Acetateأيون سالب والأيونات + +42 +00:04:30,590 --> 00:04:35,870 +السالبة عادة بتنتهي بـ 8 زي ما بيقول سولفات نيترات + +43 +00:04:35,870 --> 00:04:40,810 +كاربونات أسيتات هذه مجموعة الخلات بنسميها بالعربي + +44 +00:04:40,810 --> 00:04:44,470 +ولذلك هذا بيصير Sodium Acetate بالإنجليزي أو + +45 +00:04:44,470 --> 00:04:51,110 +بالعربي خلات ال Sodium فهذه المجموعة بيكون أسيتات + +46 +00:04:51,110 --> 00:04:55,250 +الآن لو بدي أكتب مجموعة الأسيتات مختصرة كيف + +47 +00:04:55,250 --> 00:05:04,240 +بكتبها؟ACO- لأن هذه الواحدة AC A capital small c + +48 +00:05:04,240 --> 00:05:09,520 +الآن مع ال oxygen بتصير ACO- إذا صار عندي مجموعة + +49 +00:05:09,520 --> 00:05:17,620 +AC و مجموعة ACO واضح؟ الآن السؤال لو أجهكم مثلا + +50 +00:05:17,620 --> 00:05:20,260 +بتفاعل مكتوب عندكم ACOH + +51 +00:05:22,240 --> 00:05:29,940 +اش بده يكون ال acetic acid هاي AC و هاي O و هاي H + +52 +00:05:29,940 --> 00:05:36,180 +فال acetic acid ايش بنختصره ACOH هذا ال acetic + +53 +00:05:36,180 --> 00:05:42,810 +acidهذه الرموز عادة تتكرر معنا الاسيتك أسد الاسيتك + +54 +00:05:42,810 --> 00:05:45,430 +أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك + +55 +00:05:45,430 --> 00:05:47,770 +أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك + +56 +00:05:47,770 --> 00:05:48,710 +أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك + +57 +00:05:48,710 --> 00:05:49,470 +أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك + +58 +00:05:49,470 --> 00:05:52,670 +أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك + +59 +00:05:52,670 --> 00:05:54,150 +أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك + +60 +00:05:54,150 --> 00:06:00,430 +أسد الاسيتك أسد الاسيتك أسد الاسيتك أسد الاسيتك + +61 +00:06:00,430 --> 00:06:04,530 +أسإذا رجعت لأصلها في المركب اللي قبل شوية كتبناها + +62 +00:06:04,530 --> 00:06:09,070 +كان acetophenon كانت هي العائلة لما صارت فرد وفي + +63 +00:06:09,070 --> 00:06:14,390 +إيش أعلى منها بدرجة على إيش لأصلها أصلها اللي هو + +64 +00:06:14,390 --> 00:06:21,810 +ال acetyl كذلك الحال في هذا المركب acid و ketone + +65 +00:06:23,090 --> 00:06:28,410 +طبعا المركب بده يتبع ايش ال acid بنزويك acid هذي + +66 +00:06:28,410 --> 00:06:31,670 +ايش بتكون ال acid ال acid ال acid ال acid ال acid + +67 +00:06:31,670 --> 00:06:31,670 +ال acid ال acid ال acid ال acid ال acid ال acid ال + +68 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +69 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +70 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +71 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +72 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +73 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +74 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +75 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +76 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +77 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid ال + +78 +00:06:31,670 --> 00:06:31,670 +acid ال acid ال acid ال acid ال acid ال acid the + +79 +00:06:31,670 --> 00:06:40,410 +acid + +80 +00:06:40,410 --> 00:06:44,930 +the acid the acid the acid the acid the acid the + +81 +00:06:44,930 --> 00:06:46,150 +acid the acid the acid the acid the acid the acid + +82 +00:06:46,150 --> 00:06:50,190 +the acid the acid the acid the acid the acid the + +83 +00:06:50,190 --> 00:06:55,560 +acid the acid theهذا المثال مش موجود عندكم acid + +84 +00:06:55,560 --> 00:07:01,700 +and aldehyde من الأعلى ال acid ممتاز طيب هذا + +85 +00:07:01,700 --> 00:07:11,440 +بنزويك acid بنزويك acid الآن هذه المجموعة شو اسمها + +86 +00:07:11,440 --> 00:07:14,980 +formal + +87 +00:07:14,980 --> 00:07:21,020 +واضح وبالتالي هذا بيصير ايش for formal + +88 +00:07:22,970 --> 00:07:27,890 +For formal هذه المجموعة الـ C double bond O المتصل + +89 +00:07:27,890 --> 00:07:31,570 +بـ H formal و الـ C double bond O لو اتصلت ب مثل + +90 +00:07:31,570 --> 00:07:38,380 +بتصير كيتون أسيتل أخدناهاواضحة الفكرة؟ فكل شيء إذا + +91 +00:07:38,380 --> 00:07:42,680 +ماكانش هو العائلة بده يرجع لإيش؟ لاسمه تماما + +92 +00:07:42,680 --> 00:07:46,560 +الميثل لما بتكون عائلة بنكون نقول طلوين لما تبطل + +93 +00:07:46,560 --> 00:07:51,700 +عائلة بترجع مثل ال OH لما تكون عائلة فينول بتبطل + +94 +00:07:51,700 --> 00:07:56,500 +عائلة بترجع هيدروكسي الكيتون مثلا هذه المجموعة لما + +95 +00:07:56,500 --> 00:08:02,720 +تكون عائلة أسيتوفينون بطلت عائلة أسيتلال Formyl + +96 +00:08:02,720 --> 00:08:12,560 +Benzaldehyde بطلت عائلة ترجع لإسم Formyl طبعا ربما + +97 +00:08:12,560 --> 00:08:18,140 +البعض منكم يعرف أن Formyl أيضا جاية من هذه + +98 +00:08:18,140 --> 00:08:23,680 +المجموعة اللي هي C double bond OH OH هذا اللي اسمه + +99 +00:08:23,680 --> 00:08:28,760 +Formic Acid أبسط الأحماض العضويةأبسط الأحماض + +100 +00:08:28,760 --> 00:08:33,140 +العضوية اللي فيه H ال Acetic Acid فيه مثل تاني حمض + +101 +00:08:33,140 --> 00:08:37,500 +عضوي لكن أبسط واحد في الأحماض العضوية اللي اسمه + +102 +00:08:37,500 --> 00:08:44,280 +ايش Formic Acid الأهم منه هذه المجموعة لوحدها + +103 +00:08:44,280 --> 00:08:49,440 +كمجموعة عضوية ايش اسمها Formic اسمها Formic + +104 +00:08:49,440 --> 00:08:56,170 +بالعربي هذا Formic Acid شو بيسموه حمض النمليكلأ هو + +105 +00:08:56,170 --> 00:09:00,430 +ال formalin هو ال formaldehyde مدوب في مياه بمعنى + +106 +00:09:00,430 --> 00:09:05,050 +بعدين لكن هذا بنسميه بالعربي حمب النمليك لأن هذا + +107 +00:09:05,050 --> 00:09:09,720 +الحمب اللي النملة لما بتجرسبتحطه .. بتفرزه في + +108 +00:09:09,720 --> 00:09:13,760 +الإيد و بيسبب القلم الشديد اللي بتعرفه و حتى + +109 +00:09:13,760 --> 00:09:17,000 +باللغة الألمانية زي ما احنا بنسمي .. احنا بنسمي + +110 +00:09:17,000 --> 00:09:20,720 +النمليك و ما عنده من نمل Amazin فبسموه Amazin + +111 +00:09:20,720 --> 00:09:26,860 +Zörey حمض النمل Amazin Zörey واضح؟ فهذه ال form + +112 +00:09:26,860 --> 00:09:32,080 +اللي جاية من وين؟ من ال Formic أصل هذه النقطة حسيت + +113 +00:09:32,080 --> 00:09:35,820 +أنه ربما بيكون مفيد ان انا أكد عليها في موضوع + +114 +00:09:35,820 --> 00:09:40,730 +التسميةالان بالنسبة للتفاعلات لل aromatic + +115 +00:09:40,730 --> 00:09:45,910 +compounds اتفقنا احنا على شغلة ان ال aromatic + +116 +00:09:45,910 --> 00:09:50,130 +compounds او حلقة البنزين كثافة إلكترونية ولذلك + +117 +00:09:50,130 --> 00:09:54,290 +الذي يجب ان يهاجم عليها موجب هذه النقطة الأولى + +118 +00:09:54,290 --> 00:10:00,140 +النقطة الثانية انها لا تتفاعل بالاضافةو لذلك + +119 +00:10:00,140 --> 00:10:03,340 +لاحظوا ال double bonds هنا في كل التفاعلات حاطينهم + +120 +00:10:03,340 --> 00:10:07,160 +على شكل حلقة لأنه تعبير عن ال resonance و ما + +121 +00:10:07,160 --> 00:10:11,200 +بنغيرش فيهم طب ها إيش اللي بيصير في تفاعلات ال + +122 +00:10:11,200 --> 00:10:16,720 +aromatic compounds؟ تفاعل إبدال ماذا نفعل في هذا + +123 +00:10:16,720 --> 00:10:22,780 +تفاعل الإبدال؟ بنيجي بنشيل موجب و بنحط بدله موجب + +124 +00:10:22,780 --> 00:10:28,910 +تانيواضح؟ دائما الإبدال اللي بده يبدل شغلة بشغلة + +125 +00:10:28,910 --> 00:10:36,080 +بيبدل شغلةمن نفس الشغلة يعني لو بدأ أبدل موجب إذا + +126 +00:10:36,080 --> 00:10:40,500 +بدأ أشيل منه المركب موجب شو بدأ أحط بداله موجب + +127 +00:10:40,500 --> 00:10:45,500 +الآن هنا بسمي الإبدال Electrophilic Substitution + +128 +00:10:45,500 --> 00:10:49,960 +مرت معنى كلمة Electrophilic موجب مظبوط ولا لأ + +129 +00:10:49,960 --> 00:10:55,150 +ولذلك هتلاحظوا هنا إيش العنوانElectrophilic + +130 +00:10:55,150 --> 00:10:58,330 +Substitution معنى Electrophilic Substitution بدي + +131 +00:10:58,330 --> 00:11:05,410 +اشيل اشي موجد و احط مكانه اشي موجد مظبوط ولا لأ و + +132 +00:11:05,410 --> 00:11:11,890 +اللي بده يبدل سالبإيش بده يحط مكانه؟ سالب و لذلك + +133 +00:11:11,890 --> 00:11:17,070 +هيجعلنا في مكان تاني بل أمر علينا في أمثلة سابقة + +134 +00:11:17,070 --> 00:11:22,270 +لو كنتوا منتبهين in eucleophilic substitution إن + +135 +00:11:22,270 --> 00:11:26,990 +أشيل سالب أحط مكانه سالب أشيل موجب أحط مكانه موجب + +136 +00:11:26,990 --> 00:11:31,610 +لما المرة الماضية على سبيل المثال كنا الفاعل + +137 +00:11:32,860 --> 00:11:37,700 +الاسيتالايد انايون مع مركب فيه كلور او يود متذكرين + +138 +00:11:37,700 --> 00:11:41,360 +شيلنا ال يود السالب مع الكتروناتو و حطينا + +139 +00:11:41,360 --> 00:11:45,780 +الاسيتلايد اخر تفاعل في الاسيتليانز قولنا بنشيل + +140 +00:11:45,780 --> 00:11:50,340 +سالب و نحط سالب الان لو اجيت قولتلكم هذا التفاعل + +141 +00:11:50,340 --> 00:11:54,830 +شو بدي اسميهبدي أسميه الـ Eucleophilic + +142 +00:11:54,830 --> 00:12:00,390 +Substitution لأن أنا بدأت بالـ Eucleophile هنا وين + +143 +00:12:00,390 --> 00:12:06,690 +الموجب اللي بدي أشيله؟ الاتش هذه لوحدها بدون زوج + +144 +00:12:06,690 --> 00:12:12,530 +الإلكترونة، تنتبهوا معي وجدت بدي أجيب بدلها موجب، + +145 +00:12:12,530 --> 00:12:18,700 +نفترض X موجبة، CL موجبة، شيلت الاتش الموجبة؟حطيت + +146 +00:12:18,700 --> 00:12:22,720 +ال X الموجبة هذه محصلة التفاعل إذا التفاعل إيش + +147 +00:12:22,720 --> 00:12:26,520 +بيصير اسمه Electrophilic Aromatic Substitution + +148 +00:12:26,520 --> 00:12:29,680 +ولذلك لو إحنا بنيجي بنسألكم مثلا aromatic + +149 +00:12:29,680 --> 00:12:35,450 +compounds undergo addition reactions غلطAromatic + +150 +00:12:35,450 --> 00:12:38,990 +compounds undergo a nucleophilic aromatic + +151 +00:12:38,990 --> 00:12:42,530 +substitution برضه غلط لليوكليوفال بيجربش عليها + +152 +00:12:42,530 --> 00:12:48,630 +لأنها سالبة كثافة إلكترونية هنا فمين اللي بيقدر + +153 +00:12:48,630 --> 00:12:54,310 +يجرب عليها الموجب فلمّا ينسقل الطالب سؤال عام حتى + +154 +00:12:54,310 --> 00:12:57,890 +في مقابلة التوظيف لما الواحد بيسأل بهمش يخلي + +155 +00:12:57,890 --> 00:13:01,490 +الطالب يعيد كل العلم بس ممكن يقوله ببساطة إيش + +156 +00:13:01,490 --> 00:13:06,090 +التفاعل الأساسي لل aromatic compounds؟عشان يسمع + +157 +00:13:06,090 --> 00:13:10,710 +منه كلمة Electrophilic و Aromatic و Substitution + +158 +00:13:10,710 --> 00:13:14,310 +كمان سؤال زي هذا بنقول للطالب انت فاهم كيميا واضحة + +159 +00:13:14,310 --> 00:13:20,240 +الفكرة؟الان ايش اللى بدنا نبدله دائما اتش موجبة + +160 +00:13:20,240 --> 00:13:24,200 +ونحط بدالها اذا حطينا بدالها halogen بنسمي العملية + +161 +00:13:24,200 --> 00:13:28,740 +halogenation اذا حطينا بدالها نيترو بنسمي العملية + +162 +00:13:28,740 --> 00:13:32,520 +nitration اذا حطينا بدالها مجموعة ال sulphonic + +163 +00:13:32,520 --> 00:13:36,620 +acid sulphonation اذا حطينا مجموعة alkyl + +164 +00:13:36,620 --> 00:13:42,920 +alkylation اذا حطينا مجموعة acyl acylation يمكن + +165 +00:13:42,920 --> 00:13:48,110 +البعض يقول احنا هذه مجموعة acylما مرتش علينا احنا + +166 +00:13:48,110 --> 00:13:53,530 +مرت علينا افراد من مجموعة الاسل تاوي لسه انتبهوا + +167 +00:13:53,530 --> 00:13:58,970 +معي المجموعة بشكلها العام R C double bond O هذه + +168 +00:13:58,970 --> 00:14:03,690 +اسل لاحظوا زي ما بنقول الكل الكل اللي بيبين فيها + +169 +00:14:03,690 --> 00:14:09,930 +كلمة ايش؟ R هذه اسل اللي بيبين فيها R الان لو خلت + +170 +00:14:09,930 --> 00:14:11,670 +ال R تحديدا مثل + +171 +00:14:14,060 --> 00:14:18,700 +أيش صار اسم المجموعة؟ أسيتل توي أخدناها لو خلّيت + +172 +00:14:18,700 --> 00:14:26,040 +ال R تحديدًا H أيش صار اسم المجموعة؟ formal و هكذا + +173 +00:14:26,040 --> 00:14:31,840 +خلّيني أستكفى بهدول الأن أسيتل formal فالأسيتل و + +174 +00:14:31,840 --> 00:14:39,530 +ال formal are أسل groups أسل عائلةالاسيتل فرد زي + +175 +00:14:39,530 --> 00:14:44,090 +ما نقول الكل عائلة من افرادها مثل و اثل و بربل و + +176 +00:14:44,090 --> 00:14:48,250 +ايز و بربل الان الاس العائلة من افرادها اسيتل و + +177 +00:14:48,250 --> 00:14:52,770 +formal و روبانويل و كذا خلنا الان نضل على الاسيتل + +178 +00:14:52,770 --> 00:14:57,230 +و الformal فبنسمي العملية oscillation طب لو حد كتب + +179 +00:14:57,230 --> 00:15:01,970 +هنا CH3 و بده العملية بدقة وجد ايش هيسميها؟ + +180 +00:15:01,970 --> 00:15:07,300 +oscillationواضح فالacetylation عملية خاصة من + +181 +00:15:07,300 --> 00:15:11,400 +العملية العامة اللى هى اش اسمها acetylation طبعا + +182 +00:15:11,400 --> 00:15:15,660 +بيصير السؤال الأصعب انه كيف انا بدى يكون عندى + +183 +00:15:15,660 --> 00:15:21,660 +اكلور مثلا موجب كيف بدى يكون عندى NO2 موجبة كل + +184 +00:15:21,660 --> 00:15:27,080 +اللى موجود هنا لاحظين الموجب عليه ولا لأ هى معناه + +185 +00:15:27,080 --> 00:15:31,980 +Electrophilicكل اللي موجود حقيقة في لحظة التفاعل + +186 +00:15:31,980 --> 00:15:38,040 +بدو يكون ايش موجب الان لو بدنا نفصل كيف انا بصل + +187 +00:15:38,040 --> 00:15:43,980 +لاشياء موجبة كيف انا بصل لاشياء موجبة عادة هذا + +188 +00:15:43,980 --> 00:15:49,880 +ممكن يتم باكثر من طريقة لو افترضت مثلا بدي لكلور + +189 +00:15:49,880 --> 00:15:54,320 +الموجب اللي هي اول واحدة بعمل chlorination بدي + +190 +00:15:54,320 --> 00:15:59,150 +لكلور الموجب لكلور في الدنيا كيف بنباع؟لأ مش minus + +191 +00:15:59,150 --> 00:16:06,430 +CLCL CL2 أو NA plus CL minus على العلم الراسي ال + +192 +00:16:06,430 --> 00:16:11,590 +minus موجود و ال CLCL موجود لكن الموجب مش موجود + +193 +00:16:11,590 --> 00:16:16,110 +الآن بضيف catalyst عامل حفاظ عادة بنقوله Lewis + +194 +00:16:16,110 --> 00:16:21,950 +acid حسب تعريفات Lewis FE Cl3 لو بتلاحظوا ال FE + +195 +00:16:21,950 --> 00:16:27,570 +متصل بكم ذرة كلور يعني كام electrode حواليهستة + +196 +00:16:27,570 --> 00:16:33,730 +ثلاثة في اتنين وضعوا الطبيعي المتريح تمانية إذا + +197 +00:16:33,730 --> 00:16:39,510 +ينقصوا اتنين الآن هدول لما بحطهم مع بعض بيجي هذا + +198 +00:16:39,510 --> 00:16:43,570 +على طول بتحد مع هدول بإمكاننا نتخيله بهذا الشكل + +199 +00:16:43,570 --> 00:16:48,330 +هاي أخد CL مع إلكتروناتها عشان يصير FECL4 صار + +200 +00:16:48,330 --> 00:16:56,800 +تمانية شو ضال عندى؟ CL مجبة تتفاعلفلابد لإتمام هذا + +201 +00:16:56,800 --> 00:17:00,840 +التفاعل أنه لو أنا بدي أتمم الهالوجيناشن، إيش ال + +202 +00:17:00,840 --> 00:17:07,020 +agent اللي بدي أحطه؟ الـCl2 و الـFeCl3 ماحدش يجي + +203 +00:17:07,020 --> 00:17:13,560 +يقوله بحط الـCl2 لحاله، بتفعلشواضح؟ ما حد يقول بده + +204 +00:17:13,560 --> 00:17:21,180 +أحط Cl2 لحانه، بتفعلش اللي بده يتفعل Cl2 مع FeCl3 + +205 +00:17:21,180 --> 00:17:27,380 +لاحظوا، ثانية بس، بده أذكر شغلة أنه أنا لما أخدت + +206 +00:17:27,380 --> 00:17:30,740 +ال chlorination في ال اليفاتيك كومباونز زي ما كنت + +207 +00:17:30,740 --> 00:17:36,220 +أقول مثلا ميثين زائد هالوجين كنت أفعل إيش؟ Cl2 في + +208 +00:17:36,220 --> 00:17:43,330 +وجود الضوء أو الحرارةهذا التفاعل مختلف، يتفاعل على + +209 +00:17:43,330 --> 00:17:48,670 +الـ aliphatic carbon لما كنا نقول مثان CH4 و بعدين + +210 +00:17:48,670 --> 00:17:54,410 +Cl2 في وجود الضوء اللي بنعبر عليه frequency يعني + +211 +00:17:54,410 --> 00:18:00,030 +اللي هو تعبير عن الضوء، plant constant في التردد، + +212 +00:18:00,030 --> 00:18:04,110 +هذا طاقة الضوء أو heatمش هيك احنا عملنا ال + +213 +00:18:04,110 --> 00:18:09,390 +chlorineation Cl2 في وجود كذا كذا اه بيعطيني CH3Cl + +214 +00:18:09,390 --> 00:18:13,050 +هذا ابدال على ال aliphatic compounds لان لو هذا + +215 +00:18:13,050 --> 00:18:20,250 +الكلام اجيت اعمله على aromatic compound على بنزينة + +216 +00:18:20,250 --> 00:18:23,270 +مافيش + +217 +00:18:23,270 --> 00:18:29,300 +reactionإذا بدى أنتبه للشروط الشروط لما كنت بفعل + +218 +00:18:29,300 --> 00:18:32,980 +على الميثيل والإيثيل وكذا كنت بدي CL2 في وجود ضوء + +219 +00:18:32,980 --> 00:18:37,500 +أو حرارة لما بفعل على البنزين بدي CL2 في وجود ثم + +220 +00:18:37,500 --> 00:18:46,990 +فى CL3 الآن بيصير عندنا سؤال للأذكية أحيانابهذا + +221 +00:18:46,990 --> 00:18:52,070 +الشكل انه انا لو جبت المركب نفسه لو جبت المركب + +222 +00:18:52,070 --> 00:18:57,110 +نفسه و حطيت عليه جزء aromatic يعني ممكن يعمل ادالة + +223 +00:18:57,110 --> 00:19:03,530 +على الحلقة و كتبت هنا CH2 CH3 و بدى اعمله + +224 +00:19:03,530 --> 00:19:11,190 +halogenation اه بيصير اذا قلتلكم فعلوا مع CL2 في + +225 +00:19:11,190 --> 00:19:15,500 +وجود FECL3 اذا بتكون حطوا CL على الحلقةوإذا + +226 +00:19:15,500 --> 00:19:20,560 +قلتلكوا فعلوه مع CL2 في وجود الضوء أو الحرارة + +227 +00:19:20,560 --> 00:19:26,480 +بتحطوا CL2 وين؟ هنا، الآن هذه أو هذه كام ناتج ممكن + +228 +00:19:26,480 --> 00:19:31,320 +نعمل؟ اتنين، واضح؟ يعني هذا لما نيجي نقولكوا أكمل + +229 +00:19:31,320 --> 00:19:38,220 +المعادلة ونحط CL2 H frequency أو heat شو الناتج + +230 +00:19:38,220 --> 00:19:42,440 +اللي بدكم تكتبوه؟ نفس هذا إما تحطوا CL على هذه + +231 +00:19:42,440 --> 00:19:43,980 +الكربون أو على هذه + +232 +00:19:47,550 --> 00:19:55,570 +واضح؟ لكن لو كان الكلام CL2 مع FECL3 بدنا نحطه على + +233 +00:19:55,570 --> 00:19:58,950 +الحلقة و بعد شوية بيصير طبعا على أي موقع بدنا نحطه + +234 +00:19:58,950 --> 00:20:02,050 +على الحلقة بنتعلمه ان شاء الله اليوم المهم ان + +235 +00:20:02,050 --> 00:20:07,090 +التفاعل وين بيتم؟ على ال ring نتعلمه على ال ring + +236 +00:20:07,090 --> 00:20:16,120 +وضحت هذه الفكرة ال Rبنفس المنطق لما انا بدى اعمل + +237 +00:20:16,120 --> 00:20:25,300 +نيتريشن ال N O 2 برضه بالباعش لكن ممكن ان نعمل N O + +238 +00:20:25,300 --> 00:20:30,000 +2 من خلال انه بنضيف H N O 3 حمض النيتريك مع H 2 S + +239 +00:20:30,000 --> 00:20:35,900 +O 4 بدون تفاصيل هدول الاتنين بتطلعولي ايش N O 2 + +240 +00:20:35,900 --> 00:20:42,680 +Plus بتتفاعل محل ايش ال H Plusكذلك مثلا في ال + +241 +00:20:42,680 --> 00:20:50,820 +cellfonation بحط ال reagent اللي عندى SO3 مع H2SO4 + +242 +00:20:50,820 --> 00:20:57,990 +هدولة ايش بيطلعولي HSO3 plusيعني بعمل generation + +243 +00:20:57,990 --> 00:21:01,850 +توليد لجزء الموجب اللي بده يتفاعل في ال alkylation + +244 +00:21:01,850 --> 00:21:09,370 +لما بحط R من وين بده اجيب R ايضا بحط RCl مثلا مع + +245 +00:21:09,370 --> 00:21:18,470 +FeCl3 واضحة الفكرة؟ هدول ايش بيعطوا مع بعض؟R plus + +246 +00:21:18,470 --> 00:21:23,410 +هدولة مع بعض بيعطوا R plus طبعا بالظبط محل ما + +247 +00:21:23,410 --> 00:21:29,310 +بتكون ال R مشبوكة بالهالوجين محل ما بتكون تشبكها + +248 +00:21:29,310 --> 00:21:34,010 +بالبنزين خليني اوضحلكوا هذا الكلام يعني لو + +249 +00:21:34,010 --> 00:21:38,550 +افترضتوا ان عندكم بنزين بهذا الشكل و اجيت و قلت + +250 +00:21:38,550 --> 00:21:49,940 +لكم زائد Hyana CL و FE Cl3و اكتبوا الناتج الان هذه + +251 +00:21:49,940 --> 00:21:57,200 +مجموعة R CL مع في CL3 لما بدي اكتب هذه المجموعة + +252 +00:21:57,200 --> 00:22:04,700 +كام carbon؟ تلاتة من وين بدي اشبكها؟ محل ما هي + +253 +00:22:04,700 --> 00:22:09,020 +شابكة مع ال CL ماعيش اشبكها من هنا او من هنا عشان + +254 +00:22:09,020 --> 00:22:16,850 +هيك الناتج هنامحل ما كانت المجموعة متصلة هنا مع ال + +255 +00:22:16,850 --> 00:22:23,270 +CL محل ما بدى اشبكها في مثل ما ال CL خلاص طلعت مع + +256 +00:22:23,270 --> 00:22:29,050 +ال FECL3 ال CL السالبة زى ما قبل شوية عملنا انا + +257 +00:22:29,050 --> 00:22:33,590 +باخد بس ال R واضح انا باخد ال R + +258 +00:22:36,500 --> 00:22:43,020 +بعد هيك بتعود ال CL تفلت من ال FECL3 لكن طلع هنا H + +259 +00:22:43,020 --> 00:22:47,740 +موجب، شيلنا H موجب؟ ال H الموجب اللي طلعت مع ال CL + +260 +00:22:47,740 --> 00:22:53,780 +السالب اللي هنا شو هيعطينا؟ HCL و ال FECL3 هيرجع + +261 +00:22:53,780 --> 00:22:58,460 +زي ما هو، هي معنى catalyst واضح؟ + +262 +00:23:01,810 --> 00:23:06,650 +و كذلك الحال في عملية ال acetylation او ال + +263 +00:23:06,650 --> 00:23:13,510 +acetylation بدي استعمل R C double bond O Cl برضه + +264 +00:23:13,510 --> 00:23:17,930 +مع Fe Cl3 او Aluminium Cl3 نفس الفكرة الان هذا + +265 +00:23:17,930 --> 00:23:23,070 +بياخد ال Cl هيك بهذا الشكل ايش ضال عندى؟ R C + +266 +00:23:23,070 --> 00:23:28,310 +double bond O بتشبك من وين؟ من عند الكربون هذه + +267 +00:23:28,310 --> 00:23:34,170 +بتعطينا ال acetyl groupواضح؟ فالخلاصة أنه احنا + +268 +00:23:34,170 --> 00:23:39,330 +الأشياء الموجبة اللي بنفعلها تولد أثناء التفاعل + +269 +00:23:39,330 --> 00:23:43,210 +يعني مابيشتريش الواحد هذه ال reagents الموجبة عادة + +270 +00:23:43,210 --> 00:23:47,930 +بيخلق مادتين المادتين بيطلعوا الموجب هم لاحظين هنا + +271 +00:23:47,930 --> 00:23:53,640 +حطينا مادتينفي كل منطقة احنا بنخلط مادة اللى بتطلع + +272 +00:23:53,640 --> 00:23:57,440 +الشغل الموجبة اللى بتحل محل الهيدروجين الموجب هك + +273 +00:23:57,440 --> 00:24:01,320 +بتم ال electrophilic aromatic substitution + +274 +00:24:04,770 --> 00:24:09,750 +بصير سهل علينا الآن ان نكمل التفاعل يعني لو قلنا + +275 +00:24:09,750 --> 00:24:13,590 +لكوا اكمل المعادلة هاي هنا اللى بده تطلع ال CL + +276 +00:24:13,590 --> 00:24:17,850 +وهذه بده تضيف من هذه النقطة هنا هدولة التانية ايش + +277 +00:24:17,850 --> 00:24:24,570 +بيحطوا ن او اتو هدولة بتفعل هذا يمكن البعضأقول طب + +278 +00:24:24,570 --> 00:24:28,510 +ليش حطينا المجموعة هان؟ تنسوش أن الست مجموعات في + +279 +00:24:28,510 --> 00:24:32,810 +البنزين متكافئة يعني لما نقول هان أكمل المعادلة لو + +280 +00:24:32,810 --> 00:24:35,570 +واحدة كتبت الجواب هان والتاني هان والتالتة هان + +281 +00:24:35,570 --> 00:24:38,210 +والرابعة هان والخمسة هان والثالثة هان كله صح + +282 +00:24:38,210 --> 00:24:44,250 +الهيدروجينات الستة في البنزين متكافئة ولذلك بأي + +283 +00:24:44,250 --> 00:24:49,310 +نقطة حطوا الجواب يعني هذا اسمه أسيتوفينون طب لو + +284 +00:24:49,310 --> 00:24:56,080 +ارتسم هان أهانواضح؟ او لو افترضنا كان كلورو بنزين، + +285 +00:24:56,080 --> 00:25:02,740 +كلورو بنزين، واضح؟ فلو سألناكم the six hydrogens + +286 +00:25:02,740 --> 00:25:08,580 +of benzene are equivalent واضح الفكرة؟ وين ما بدكم + +287 +00:25:08,580 --> 00:25:13,980 +حطوا المجموعة، نفس الشيء تماما، نفس الشيء تماما + +288 +00:25:13,980 --> 00:25:18,480 +هذا الكلام الآن وين موجود اللي هو نظام ال + +289 +00:25:18,480 --> 00:25:24,850 +equivalent في البنزين؟البنزين ماعلهوش ولا إبدال + +290 +00:25:24,850 --> 00:25:29,810 +حطيت الإبدال الأول طيب لما الأن ننتقل للنقطة الأهم + +291 +00:25:29,810 --> 00:25:33,830 +في موضوعنا طب لو يا تورا جيبت substituted بنزين + +292 +00:25:33,830 --> 00:25:40,310 +عليه إبدال واحد أصلا يعني مثلا جيبنا هذا المركب + +293 +00:25:40,310 --> 00:25:44,270 +الطلوين و بدنا نعمل عليه تفاعل chlorineation أو + +294 +00:25:44,270 --> 00:25:50,740 +nitration أو أي تفاعلوين بدنا نحطهم؟ بيصير السؤال + +295 +00:25:50,740 --> 00:25:55,720 +يا ترى على الحلقة كم هيدروجينة موجود على الحلقة؟ + +296 +00:25:55,720 --> 00:26:00,440 +خمسة، واحد، اتنين، تلاتة، اربعة، خمسة، اللي على + +297 +00:26:00,440 --> 00:26:05,200 +الحلقة كم نوع الهيدروجينات اللي على الحلقة؟ تلاتة، + +298 +00:26:05,200 --> 00:26:07,380 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +299 +00:26:07,380 --> 00:26:09,720 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +300 +00:26:09,720 --> 00:26:11,280 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +301 +00:26:11,280 --> 00:26:20,240 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتو هذه نوع تالت إذا + +302 +00:26:20,240 --> 00:26:23,600 +هذولة تلت أنواع طبعا لو أنا كنت بسأل كام نوع + +303 +00:26:23,600 --> 00:26:26,500 +الهيدروجين اللي على الحلقة هتقوللي تلاتة اللي في + +304 +00:26:26,500 --> 00:26:31,500 +الجزيب المجمل أربعة هذا نوع رابع الآن لما أنا بعمل + +305 +00:26:31,500 --> 00:26:36,220 +التفاعلات ال aromatic ماليش بهذا اللي هان و هان و + +306 +00:26:36,220 --> 00:26:41,450 +هانطيب لو اعملت تفاعل نفترض ال chlorineation بيصير + +307 +00:26:41,450 --> 00:26:44,930 +السؤال اللى عندى وين بده احط ال chlorine على هذا + +308 +00:26:44,930 --> 00:26:48,270 +الموقع طبعا زى هذا او على هذا زى هذا او على هذا + +309 +00:26:48,270 --> 00:26:52,270 +كام احتمال بيصير عندى تلاتة لاحظوا الاحتمال الاول + +310 +00:26:52,270 --> 00:26:57,330 +لانه مباشر بنسميه Ortho واللي بعده Meta واللي بعده + +311 +00:26:57,330 --> 00:27:04,180 +Para كلام منطقي ولا .. و هذا ايضا و هذا Metaالان + +312 +00:27:04,180 --> 00:27:10,600 +المجموعة اللي صارت موجودة بتصير تتحكم هي بالتفاعل + +313 +00:27:10,600 --> 00:27:14,640 +مش المجموعة اللي بتيجي من برا اللي بتتحكم بالتفاعل + +314 +00:27:14,640 --> 00:27:19,340 +اليوم يوم ما بيجي ضيف عليكم مين اللي بتحكم وبيقول + +315 +00:27:19,340 --> 00:27:26,200 +للضيف اتفضل هان و هان صاحب البيت ولا الضيف صاحب + +316 +00:27:26,200 --> 00:27:30,220 +البيته عشان ذلك احنا المثل اللي عندنا بنقول الضيف + +317 +00:27:30,220 --> 00:27:36,730 +ايش؟أسير لمحلة، يعني زي ما بيقولوا إذا كان مثلا + +318 +00:27:36,730 --> 00:27:39,810 +هذا الضيف إنسان غريب شوية، ممكن تقولوله اتفضل على + +319 +00:27:39,810 --> 00:27:43,330 +غرفة الضيوف، إذا افترضنا نظيف خالكم، بتقولوله + +320 +00:27:43,330 --> 00:27:45,850 +اتفضل على الصالون، إذا مين اللي اتحكم وين يجيب + +321 +00:27:45,850 --> 00:27:52,070 +الضيف؟ صاحب البيت، الآن مين صاحب البيت هنا؟ هذه + +322 +00:27:52,070 --> 00:27:57,140 +المجموعةواضح؟ ولذلك هذه المجموعة اللي هنا إلها + +323 +00:27:57,140 --> 00:28:01,180 +تأثيرين التأثير الأول أنها تؤثر على التفاعل من + +324 +00:28:01,180 --> 00:28:05,260 +ناحية السرعة يعني بعض المجموعات بتزيد سرعة + +325 +00:28:05,260 --> 00:28:08,280 +التفاعلات وبعضها بتنقص هذا ال effect بنسميه + +326 +00:28:08,280 --> 00:28:14,060 +reactivity effect يعني لها تأثير بالسرعة زيادة أو + +327 +00:28:14,060 --> 00:28:18,160 +انقاصةهذا التأثير الأول ال reactivity effect + +328 +00:28:18,160 --> 00:28:23,500 +التأثير التاني بنسميه orientation effect لها تأثير + +329 +00:28:23,500 --> 00:28:27,280 +على أي موقع orientation موقع على أي موقع تقول + +330 +00:28:27,280 --> 00:28:30,440 +للمجموعة اللي جاي اتفضلي انت هان اتفضلي هان اتفضلي + +331 +00:28:30,440 --> 00:28:35,110 +هان من اللي بيقول اللي جاي ولا اللي موجودالموجود + +332 +00:28:35,110 --> 00:28:39,430 +ولذلك إلى التأثير التاني ال orientation أو بنسميه + +333 +00:28:39,430 --> 00:28:41,890 +مرات regiochemistry عارفين إيش يعني + +334 +00:28:41,890 --> 00:28:46,670 +regiochemistry؟ region موقع يعني أنها تحدد إلى أي + +335 +00:28:46,670 --> 00:28:49,990 +موقع تذهب المجموعة الجديدة هي معناه regiochemistry + +336 +00:28:50,830 --> 00:28:55,890 +الان المجموعات تصنف إلى نوعين في مجموعات منشطة + +337 +00:28:55,890 --> 00:29:00,030 +تزيد سرعة التفاعل بنسميها activating groups وفي + +338 +00:29:00,030 --> 00:29:05,150 +مجموعات مثبتة بنسميها ايش deactivating groups وهذه + +339 +00:29:05,150 --> 00:29:12,200 +بدنا نتعلمها الان المجموعات المنشطةأشهرها وأعلاها + +340 +00:29:12,200 --> 00:29:16,580 +زي ما هي مرتبة هنا في زيادة التنشيط ال H2 اللي في + +341 +00:29:16,580 --> 00:29:21,020 +الانالين بعدين ال OH بعدين ال OCH3 بعدين ال CH3 و + +342 +00:29:21,020 --> 00:29:24,600 +ال Alkyl هدولة سهلة اللي بنقدر نحفظهم هدولة + +343 +00:29:24,600 --> 00:29:30,440 +بنسميهم مجموعات إيش منشطة المجموعات المثبتة بتبدأ + +344 +00:29:30,440 --> 00:29:33,520 +من هذا الخط لاحظوا هذا الخط الهيدروجيني عن البنزين + +345 +00:29:33,520 --> 00:29:42,690 +اللي أعلى منهمنشط والأقل منه مثبت activating و + +346 +00:29:42,690 --> 00:29:46,290 +deactivating كل ما طلعت لفوق بزيد التنشيط كل ما + +347 +00:29:46,290 --> 00:29:51,350 +نزلت لتحت بزيد ال ash التفبيط ولذلك ال halogens + +348 +00:29:51,350 --> 00:29:56,670 +are deactivating ال nitro deactivating السيانو + +349 +00:29:56,670 --> 00:30:00,670 +deactivating الحامض deactivating يعني أن التفاعل + +350 +00:30:00,670 --> 00:30:06,120 +هيكون أقل من تفاعل ال ashالبنزين لوحده اللى لو + +351 +00:30:06,120 --> 00:30:10,220 +كانت هذه الار اتش المعنى انه لما بنحط هنا اللى + +352 +00:30:10,220 --> 00:30:13,620 +الار اتش اللى هي نقطة المرجع لو هذه اتش كان صرت + +353 +00:30:13,620 --> 00:30:18,620 +انا ايش البنزين فاللي فوق منها اسرع من البنزين + +354 +00:30:18,620 --> 00:30:23,940 +اللى تحتأبطأ من البنزين هذا بالنسبة للسرعة الآن + +355 +00:30:23,940 --> 00:30:27,080 +السرعة مش كتير بتفرج معاكم عارفين ليش؟ لأنه مش + +356 +00:30:27,080 --> 00:30:30,240 +كتير بنيجي نسألكوا مين أسرع ومين أبطأ لكن لما + +357 +00:30:30,240 --> 00:30:36,220 +نقولكوا أكمل المعادلة بيفرج معاكم على أي جهة تحطوا + +358 +00:30:36,220 --> 00:30:42,120 +ناتج ال orientation عندنا قاعدة بسيطة لل + +359 +00:30:42,120 --> 00:30:49,180 +orientation بشكل عام المجموعات المنشطةمضاف إليها + +360 +00:30:49,180 --> 00:30:52,920 +الهالوجينات يعني بيبقى الخط من عند هنا هذه بتودع + +361 +00:30:52,920 --> 00:30:57,440 +على موقع Orthopara والمجموعات ال .. ال + +362 +00:30:57,440 --> 00:31:02,320 +deactivating بتودع موقع Meta يعني لو كنت أنا بفعل + +363 +00:31:02,320 --> 00:31:08,980 +مثلا مع Toluene وبفعله مع CL2 وين هي يجي الناتج؟ + +364 +00:31:08,980 --> 00:31:15,420 +CL2 في وجود FECL3 على Orthopara الآن بحطش على نفس + +365 +00:31:15,420 --> 00:31:20,510 +الجزء Orthopara لأ بكتب ناتجينيعني مثل وعلى + +366 +00:31:20,510 --> 00:31:25,930 +Orthochlor و مثل وعلى Barachlor واضح؟ خليط من + +367 +00:31:25,930 --> 00:31:32,750 +ناتجين الاحتمالين لما بنفعل مع المجموعات اللي فوق + +368 +00:31:32,750 --> 00:31:37,270 +الخط اللي موجود عندنا الناتج خليط من المركبين ال + +369 +00:31:37,270 --> 00:31:43,770 +Ortho والBara الآن انتبهوا معي لخطأ شائع دائما + +370 +00:31:43,770 --> 00:31:49,590 +بيعملوه الطلاب رغم انه انا حكيت عليهأكام مرة؟ ألف + +371 +00:31:49,590 --> 00:31:54,370 +مرة اليوم ورغم هيك من خبرتنا تلاتين في المية من + +372 +00:31:54,370 --> 00:31:57,590 +الطلاب بيعملوا هذا الخطأ لاحظوا ال Nitro مجموعة + +373 +00:31:57,590 --> 00:32:04,990 +ايش؟ مثبتة وين بتودي؟ على ميتا اه الان طب شو هو + +374 +00:32:04,990 --> 00:32:08,710 +الخطأ اللي بيعمله الطلاب و مش عمال ابطله عنه ع مدى + +375 +00:32:08,710 --> 00:32:15,890 +السنين لما اجي اقول اكمل المعادلة وين + +376 +00:32:15,890 --> 00:32:17,070 +بده احط الجواب؟ + +377 +00:32:20,310 --> 00:32:27,470 +الحمد لله انه كغلطه لاحظوا معاك انا قلتلكوا اللي + +378 +00:32:27,470 --> 00:32:34,050 +بتحكم اللي هنا ع طول راح مخته هنا هذه لو هي موجودة + +379 +00:32:34,050 --> 00:32:37,630 +هنا بتودي ع ميتا اللي بتحكم في التفاعل المجموعة + +380 +00:32:37,630 --> 00:32:42,650 +الموجودة كم مرة حكيتها؟هذه الموجودة وين بتودّي + +381 +00:32:42,650 --> 00:32:47,790 +اللي جاي؟ وعشان هيك المفروض أنه قبل ما أكتب ماعيش + +382 +00:32:47,790 --> 00:32:52,230 +بتفعل، لو كتبت بس هيك و لسه قاعد بكمل، لسه ماكتبتش + +383 +00:32:52,230 --> 00:32:55,950 +ماعيش بده يتفعل، أنتوا تكونوا جاهزة الجواب، هذا + +384 +00:32:55,950 --> 00:33:01,590 +وين بده يودّي؟على اورثو بارا سواء اتفاعل مع مثليشن + +385 +00:33:01,590 --> 00:33:05,510 +تاني مع اتش مع floor مع halogen اللي بتحكم + +386 +00:33:05,510 --> 00:33:10,370 +بالتفاعل هذا ولذلك لما هنا بدي اكتب HNO3 H2SO4 + +387 +00:33:10,370 --> 00:33:16,150 +اللي بتحكم الأصلي الناتج هتكتبوه بهذا الشكل CH3 و + +388 +00:33:16,150 --> 00:33:24,150 +تحطوا هنا NO2 زائد هي على اورثو CH3 و تحطوا هنا + +389 +00:33:24,150 --> 00:33:26,970 +NO2 خليط + +390 +00:33:28,710 --> 00:33:33,650 +تكتبوا الاحتمالين لو انا كنت بادي مثلا بنايترو + +391 +00:33:33,650 --> 00:33:40,370 +بنزين وجهته بده يودي على ويت على ميته فهي المرة + +392 +00:33:40,370 --> 00:33:45,890 +العشرين اللي بتحكم بالتفاعل من؟ الموجودة أصلا وليس + +393 +00:33:45,890 --> 00:33:51,990 +الطريقة وكلام بتهيألي منطق مافيه ولا مشكلة واضحة + +394 +00:33:51,990 --> 00:33:57,730 +الأفكار؟ يكاد يكون معظم الأشياء اللي ضايلة عندنا + +395 +00:33:58,480 --> 00:34:05,680 +أشياء تطبيقية على هذه الفكرة خلّينا نشوف هاي هذا + +396 +00:34:05,680 --> 00:34:10,580 +الكلام بيجيب للي بيودوا Orthobara لحد ال halogens + +397 +00:34:10,580 --> 00:34:15,680 +لاحظوا ان ال halogens لو أنا بدى أصنفهم شو بدى + +398 +00:34:15,680 --> 00:34:20,620 +أقول عنهم من ناحية تأثيرهم activating ولا + +399 +00:34:20,620 --> 00:34:24,120 +deactivating دي activating لكن من ناحية التوجيه + +400 +00:34:26,320 --> 00:34:35,220 +الهالوجين دي اكتفت الهالوجين + +401 +00:34:35,220 --> 00:34:39,920 +دي اكتفت الهالوجين دي اكتفت الهالوجين دي اكتفت + +402 +00:34:39,920 --> 00:34:44,380 +الهالوجين دي اكتفت الهالوجين دي اكتفت الهالوجين دي + +403 +00:34:44,380 --> 00:34:48,040 +اكتفت الهالوجين دي اكتفت الهالوجين دي اكتفت + +404 +00:34:48,040 --> 00:34:48,980 +الهالوجين دي اكتفت الهالوجين دي اكتفت الهالوجين دي + +405 +00:34:48,980 --> 00:34:50,920 +اكتفت الهالوجين دي اكتفت الهالوجين دي اكتفت + +406 +00:34:50,920 --> 00:34:53,700 +الهالوجين دي اكتفت الهالوجين دي اكتفت الهالوجين دي + +407 +00:34:53,700 --> 00:34:54,390 +اكتفت الهالوجين دي اكتفت الهالوجين دي اواضحة + +408 +00:34:54,390 --> 00:35:02,190 +الفكرة؟ الهيدروجين بنزين خلاص نقطة التعادل، واضح؟ + +409 +00:35:02,190 --> 00:35:06,010 +ترجع بنزين و بيبطل فيه أورتو برا برجعله ست مواقع + +410 +00:35:06,010 --> 00:35:11,610 +متكافئة، واضح؟ الهيدروجين خلاص رجعه ست مواقع + +411 +00:35:11,610 --> 00:35:13,050 +متكافئة، بنزين + +412 +00:35:22,700 --> 00:35:26,600 +الان لاحظوا على أرض الواقع هاي أمثلة تطبيقية .. + +413 +00:35:26,600 --> 00:35:31,560 +هاي أمثلة تطبيقية .. هاي طلوين بتعمله نيترشل .. شو + +414 +00:35:31,560 --> 00:35:36,720 +النواتج اللي بتطلع .. هاي ال ortho .. جداش نسبته + +415 +00:35:36,720 --> 00:35:40,740 +.. تلاتة و ستين في المية .. هاي ال bara جداش نسبته + +416 +00:35:40,740 --> 00:35:44,380 +.. أربعة و تلاتين ..الان ال meet هذا طلع شوية + +417 +00:35:44,380 --> 00:35:49,840 +صغيرة .. تلاتة في المية .. تعتبر عدمهذا منطقي في + +418 +00:35:49,840 --> 00:35:54,420 +الدنيا بالمناسبة يعني احنا على سبيل المثال بنقول + +419 +00:35:54,420 --> 00:35:58,180 +انه الاصل في المسلمين انهم بيقتلوش و بيؤذوش الناس + +420 +00:35:58,180 --> 00:36:01,420 +لكن مالنجلناش اتنين تلاتة بيقتلوا و بيؤذوا الناس؟ + +421 +00:36:03,080 --> 00:36:08,200 +فمعنى ان انا بقول اورثوبارا اورثوبارا ان الناواتج + +422 +00:36:08,200 --> 00:36:12,600 +الأساسية اورثوبارا الان بطلعش شوية شدوث بطلع طلع + +423 +00:36:12,600 --> 00:36:17,520 +بالنسبة 3% واضح بس احنا في اكمال المعادلات مديش + +424 +00:36:17,520 --> 00:36:22,100 +تكتبواها 3% سامحكم هنا احنا بنجيب نتيجة تجربة + +425 +00:36:22,100 --> 00:36:25,900 +حقيقية لكن لو اكمل المعادلة بس اللي باجبله منكم + +426 +00:36:27,180 --> 00:36:31,160 +لسبب بسيط انه ماعندكوش انتوا الإجابات انتبهوا معي + +427 +00:36:31,160 --> 00:36:36,860 +ليش ال ortho يكاد يكون طلع ضعف الفارة؟ في واحدة + +428 +00:36:36,860 --> 00:36:42,800 +شاطرة تجاوبنا؟ لأنه في تنتين لأنه في احتمالين + +429 +00:36:42,800 --> 00:36:51,520 +البارة واحدة Ortho احتمالين هاي + +430 +00:36:51,520 --> 00:36:58,020 +مثال تاني تأكيديالسيانو هذي بتودي على ميتا لاحظوا + +431 +00:36:58,020 --> 00:37:02,680 +مركب الميتا جداش طلعت نسبته واحد تمانية في المية + +432 +00:37:02,680 --> 00:37:06,020 +هو الأساس الأن بتطلع شوية ارثو وشوية برة لكن + +433 +00:37:06,020 --> 00:37:09,780 +بنعتبره نسب قليلة فالجواب اللي بدنا نشوفه حقيقة + +434 +00:37:09,780 --> 00:37:17,920 +الميتا و بس واضح؟ + +435 +00:37:23,280 --> 00:37:29,840 +الان ع السريع و انا بدى اجف هنا اسكر على هدول عشان + +436 +00:37:29,840 --> 00:37:33,640 +نأكد انكوا فاهمين الكلام لما نقول هنا بدنا نكمل + +437 +00:37:33,640 --> 00:37:37,900 +المعادلة انتوا ع طول بدكوا تجاوب و بدون ما تعرفوا + +438 +00:37:37,900 --> 00:37:44,420 +ايش اللي موجود هنا بدكوا تقولوا ارتباط هذي مائة + +439 +00:37:44,420 --> 00:37:51,620 +هذي مائة و بعدين كملوا الجواب انتهى واضح الفكرة؟ + +440 +00:37:56,470 --> 00:38:00,070 +هذا بيحط brom هذا بيحط chlorine و هدول ال reagents + +441 +00:38:00,070 --> 00:38:08,810 +مع بعض بيحط يود من + +442 +00:38:08,810 --> 00:38:12,730 +الأسئلة المتكررة هنا و دائما يجب أن نسأل عنها + +443 +00:38:12,730 --> 00:38:18,150 +الطلاب أنه احنا بنجيب مركب فيه مجمعتين و بنقولكوا + +444 +00:38:18,150 --> 00:38:24,570 +يا تورا مبتدئا من البنزين كيف بتحضرولنا هذا المركب + +445 +00:38:26,240 --> 00:38:30,800 +انتبهوا معايا هاي مثلا هذا مركب الآن انا بقولكم + +446 +00:38:30,800 --> 00:38:35,920 +مبتدئا من البنزين كيف بدكم تحضروا هذا المركب + +447 +00:38:35,920 --> 00:38:42,840 +عارفين وين محور السؤال ها؟ محور السؤال ان انا عندي + +448 +00:38:42,840 --> 00:38:47,480 +مجموعتين يا تورا بدي اضيف هذه في الأول و بعدها هذه + +449 +00:38:47,480 --> 00:38:52,690 +و لا هذه في الأول و بعدها هذهبديش أنسى انا ان + +450 +00:38:52,690 --> 00:38:56,090 +المجموعة اللى بضيفها بالأول هي اللى تتحكم بالتفاعل + +451 +00:38:56,090 --> 00:38:59,870 +الان لو يا ترى ضيفت الميثل في الأول الميثل وين + +452 +00:38:59,870 --> 00:39:03,950 +بتودى ارتوبرا ارتوبرا يعني بتطلعلي هذا الناتج اه + +453 +00:39:03,950 --> 00:39:07,090 +طب لو ضيفت هذه في الأول ال acid اللى لو رجعنا + +454 +00:39:07,090 --> 00:39:11,830 +بتودى ميتا مش هتطلعلي الناتج ولذلك هذا لما باجي + +455 +00:39:11,830 --> 00:39:18,170 +بشتغل الان تنفيذة بقول CH3Cl مع ألمنيوم كلورايد + +456 +00:39:18,170 --> 00:39:26,120 +هيحط ايشالـ CH3 بعد هيك باجي بقول CH3C double bond + +457 +00:39:26,120 --> 00:39:30,020 +OCL مع الومليوم كلورايت لحظوا ان الكلام بتكون + +458 +00:39:30,020 --> 00:39:33,320 +تتدربوا ع كتابته احنا الآن محاضرة بتكون ترجعوا + +459 +00:39:33,320 --> 00:39:37,500 +تحضروا التصوير و تتدربوا و تحفظوا بيحط في اي موقع + +460 +00:39:37,500 --> 00:39:46,340 +ال Ortho زائد ال Vara احنا اللي مطلوب منها ايش + +461 +00:39:47,240 --> 00:39:53,540 +البارة وبنكتب هنا كمان زائد ال orthocompound صح؟ + +462 +00:39:53,540 --> 00:39:59,240 +بس هو طالب كيف بنحضر ال ortho البارة عفوا الان نفس + +463 +00:39:59,240 --> 00:40:11,060 +الأمثلة اللي عندكم سجلتوا؟ يلا سجلوا و + +464 +00:40:11,060 --> 00:40:17,360 +بكون سعيد ان انتوا تجاوبوا لو قلنالكواهذا المركب + +465 +00:40:17,360 --> 00:40:21,420 +كام مجموعة فيه؟ طب إذا بدأ أبدأ من البنزين هذه وين + +466 +00:40:21,420 --> 00:40:26,040 +بتودي؟ يالها أورتوبالا و هذه؟ ميتا العلاقة اللي + +467 +00:40:26,040 --> 00:40:31,580 +موجودة إذا المقش اللي لازم أبدأ فيها start by + +468 +00:40:31,580 --> 00:40:37,540 +nitration الآن هذه COCH3 + +469 +00:40:37,540 --> 00:40:44,480 +هذه اللي هي سيضة بالبند OCH3 هي كده ميتا و هذه؟ + +470 +00:40:48,050 --> 00:40:53,270 +العلاقة الموجودة اذا ايش اللي لازم ابدأ فيه ال + +471 +00:40:53,270 --> 00:40:53,730 +isolation + +472 +00:40:57,190 --> 00:41:01,690 +ميتا بتودى على ميتا position هذى وين بتودى + +473 +00:41:01,690 --> 00:41:06,750 +اورتوبارا اللى موجود عندى اذا ايش اللى لازم ابدأ + +474 +00:41:06,750 --> 00:41:10,850 +فيه هذا الكلام طبقه عد انتوا بالإيد واستمتعوا + +475 +00:41:10,850 --> 00:41:14,670 +بتطبيقه وأكيد لو دخلتوا على الامتحانات السابقة + +476 +00:41:14,670 --> 00:41:19,610 +هتلاقوا في كل امتحان سؤال من هذا النوع انه بنجيب + +477 +00:41:19,610 --> 00:41:24,550 +مركب ال two substituents و بنقولكواكيف بتحضر هذا + +478 +00:41:24,550 --> 00:41:33,290 +المركب من البنزين عشان نشوف كيف فهمته قصة + +479 +00:41:33,290 --> 00:41:39,710 +ال radiochemistry بضل عندى شغلتين صغار بتجيجتين + +480 +00:41:39,710 --> 00:41:45,910 +الحمد لله خلصناانه غير البنزين في عندى مراكبات + +481 +00:41:45,910 --> 00:41:51,390 +كتير فيها اكثر من حلقة بنزين تمام الان اذا + +482 +00:41:51,390 --> 00:41:59,550 +بتلاحظوا انتوا البنزين كان by electron كان فيه ستة + +483 +00:41:59,550 --> 00:42:07,140 +ستة بعد البنزين بيجيه من النفثالين جديش فيهأربعة + +484 +00:42:07,140 --> 00:42:09,800 +في اتنين اربعة في اتنين اربعة في اتنين اربعة في + +485 +00:42:09,800 --> 00:42:14,520 +اتنين اربعة + +486 +00:42:14,520 --> 00:42:18,000 +في اتنين اربعة في اتنين اربعة في اتنين اربعة في + +487 +00:42:18,000 --> 00:42:23,380 +اتنين اربعة في اتنين اربعة + +488 +00:42:23,380 --> 00:42:27,760 +في اتنين + +489 +00:42:27,760 --> 00:42:29,820 +اربعة في اتنين اربعة في اتنين اربعة في اتنين اربعة + +490 +00:42:29,820 --> 00:42:31,820 +في اتنين اربعة في اتنين اربعة في اتنين اربعة في + +491 +00:42:31,820 --> 00:42:32,120 +اتنين اربعة في اتنين اربعة في اتنين اربعة في اتنين + +492 +00:42:32,120 --> 00:42:33,280 +اربعة في اتنين اربعة في اتنين اربعة في اتنين اربعة + +493 +00:42:33,280 --> 00:42:34,400 +في اتنين اربعة في اتنين اربعة في اتنين اربعة في + +494 +00:42:34,400 --> 00:42:40,330 +اتنين اربعة في اتنينعشرين زاد اتنين اتنين و عشرين + +495 +00:42:40,330 --> 00:42:44,590 +الان عدد ال by electrons لازم يكون زي هيك اذا كان + +496 +00:42:44,590 --> 00:42:50,100 +زي هيك بيكون المركب اللي عندى ايش aromaticيعني + +497 +00:42:50,100 --> 00:42:52,880 +المركب عشان يكون aromatic بدوا يكون فيه by + +498 +00:42:52,880 --> 00:42:57,940 +electrons يا 6 يا 10 يا 14 يا 18 يا 22 لاحظوا هنا + +499 +00:42:57,940 --> 00:43:04,400 +قداش عددهم بالنفثالين عشرة هنا 2 4 6 8 10 12 14 + +500 +00:43:04,400 --> 00:43:09,520 +تلت حلقات بيصير اسمهم أنثراسين أو فنانثرين بهذا + +501 +00:43:09,520 --> 00:43:15,660 +الشكل الآن بعد هيك هذا المركب هذا المركب هي فيه ال + +502 +00:43:15,660 --> 00:43:20,480 +بيرين مع بنزينة عشان هيك إيش بيسموهبنزو ايه + +503 +00:43:20,480 --> 00:43:24,620 +بايرين؟ يعني هو damage من البنزين مع ال بايرين + +504 +00:43:24,620 --> 00:43:29,740 +فإيش سمناه؟ بنزو بايرين هذا المركب اللي موجود في + +505 +00:43:29,740 --> 00:43:36,560 +السجائر وبيسبب السرطان وموجود في الحرق، بيطلع من + +506 +00:43:36,560 --> 00:43:43,380 +الحرق سواء حرجنا كاكاو، بخور، سجائر، تبغ، شيشة، + +507 +00:43:43,380 --> 00:43:49,600 +معسلكل الحرق هذا دايما بيطلع ال بنزو A بايرين اللي + +508 +00:43:49,600 --> 00:43:53,720 +هو ال carcinogenic compound كل الحرق اللي هنا + +509 +00:43:53,720 --> 00:43:59,480 +بيطلع بنزو A بايرين اللي هو ايش؟ carcinogenic + +510 +00:43:59,480 --> 00:44:05,560 +compound مركب مسرطن حتى .. انتبهوا معي البخور مش + +511 +00:44:05,560 --> 00:44:10,880 +كتير تولعوه في الدور نفس الاشي بيطلع ال بنزو A + +512 +00:44:10,880 --> 00:44:15,630 +بايرينالكاكاو إذا الحرج كتير في الكيك أو ما إلى + +513 +00:44:15,630 --> 00:44:18,810 +ذلك كل المنطقة المحروجة بصير فيها بنزو اي بايرين + +514 +00:44:18,810 --> 00:44:23,010 +ماتاكلوش الاشي المحروج واضح؟ بيكون فيه ال بنزو اي + +515 +00:44:23,010 --> 00:44:30,030 +بايرين المركب الكارسينوجينب الخشب + +516 +00:44:30,030 --> 00:44:33,150 +بيطلع ثانو أكسيد كربونه أول أكسيد كربونه بيخنج + +517 +00:44:33,150 --> 00:44:43,110 +الناس اخر شغلة عشان أخلصهي عبارة عن اكتشاف حديث + +518 +00:44:43,110 --> 00:44:47,130 +يمكن لما حكيت عن الالوتروبز حكيت لكم ياه كرة + +519 +00:44:47,130 --> 00:44:51,050 +الكربون ستين كلكم بتعرفوا الكربون في الطبيعة موجود + +520 +00:44:51,050 --> 00:44:57,060 +على أي أشكالGraphite و Diamonds الآن بال ألف و + +521 +00:44:57,060 --> 00:45:01,540 +تسعمية و ثمانية و بعد لقوا صورة جديدة من ستين ذرة + +522 +00:45:01,540 --> 00:45:08,300 +كربون هذه الصورة سموها carbon sixty لأن هدولة + +523 +00:45:08,300 --> 00:45:14,930 +النقاط كم ذرةواللي حدد او ساعد تحديدها انسان اسمه + +524 +00:45:14,930 --> 00:45:17,630 +book monster fullero عشان هيك سماوه fullerine + +525 +00:45:17,630 --> 00:45:21,370 +الناس اللي اكتشفوا هذا الكلام اخدوا عليه جائزة + +526 +00:45:21,370 --> 00:45:24,490 +نوبل في الكيميا اخدوا عليه جائزة نوبل في الكيميا + +527 +00:45:24,490 --> 00:45:30,680 +بحدود 95 مش زمانواضح؟ اللي هو الفوليرين إيش اللي + +528 +00:45:30,680 --> 00:45:36,160 +قالوا؟ قالوا 60 ذرة موجودين على سطح كرة و الكرة + +529 +00:45:36,160 --> 00:45:43,280 +عبارة عن أشكال سداسية و خماسية 32 وجه ال 32 منهم + +530 +00:45:43,280 --> 00:45:49,900 +أظن 20 سداسي و 12 خماسي لو روحتوا أنتوا على البيت + +531 +00:45:49,900 --> 00:45:54,520 +و شوفتوا أي كرة موجودة عديتوا الوجوه اللي موجودة + +532 +00:45:54,520 --> 00:46:00,220 +عليها كتبتوا 1,2,3,4 هتلاقوهم كام وجه؟32 لو عديته + +533 +00:46:00,220 --> 00:46:03,800 +النقاط اللي هذا اللي تمثل ال carbon هتلاقوهم كام + +534 +00:46:03,800 --> 00:46:08,240 +نقطة؟ 60 نقطة ولذلك سمو هذا كرة الكربون وقيلها + +535 +00:46:08,240 --> 00:46:14,600 +تطبيقات كتيرة في الحياة هي أساسا بتشبه المراكبات + +536 +00:46:14,600 --> 00:46:19,170 +ال aromatic لكن علم خاص مش موضوعنا أنهاانه الآن + +537 +00:46:19,170 --> 00:46:23,150 +نحكي فيه اللي جابها اللي فيها الحلقات السداسية + +538 +00:46:23,150 --> 00:46:29,010 +اللي فيها الحلقات السداسية واكتشاف يعني جديد ويله + +539 +00:46:29,010 --> 00:46:33,830 +كثير من التطبيقات، ابهيك بننهي اليوم ونشكركوا على + +540 +00:46:33,830 --> 00:46:35,230 +حصن باسمنا + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1FUjIgJdwak_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1FUjIgJdwak_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..20f3b53de08d72b2831c157645f1d58fa3017dee --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1FUjIgJdwak_postprocess.srt @@ -0,0 +1,2060 @@ +1 +00:00:19,930 --> 00:00:24,470 +بسم الله الرحمن الرحيم المرة الماضية بدأنا في + +2 +00:00:24,470 --> 00:00:31,090 +موضوع ال alkyl halides ال RX يمكن أخذنا فكرة عن + +3 +00:00:31,090 --> 00:00:37,450 +المراكبات وتسميتها وربما البعض بيذكر قوة الرابط + +4 +00:00:37,450 --> 00:00:42,990 +اللي ما بين ال R و ال X وقلنا بشكل عام رابطة مع ال + +5 +00:00:42,990 --> 00:00:49,410 +fluorine رابطة قوية وبالتالي مابتمش عمليةكسر سهل + +6 +00:00:49,410 --> 00:00:54,410 +خلينا نقول لهذه الرابطة ما عدا ذلك اليود و البروم + +7 +00:00:54,410 --> 00:01:00,050 +و الكلور ممكن كسر الرابطة و أسهل ما تكون مع اليود + +8 +00:01:00,050 --> 00:01:06,630 +رابطة إيش معاها بعيفة فأتكلمنا قولنا إنه في ال + +9 +00:01:06,630 --> 00:01:11,450 +الكلهيليتز التفاعل الأساسي إما تفاعل إبدالي يعني + +10 +00:01:11,450 --> 00:01:15,610 +نشيل ال halogen و ال halogen في كل الأحوال بدأ + +11 +00:01:16,660 --> 00:01:21,680 +تنشال مع إلكتروناتها ونحط مكانها نيوكليوفايل مع + +12 +00:01:21,680 --> 00:01:26,740 +إلكتروناته يعني كأنه أبدلنا شيء سالب شيء سالب هذه + +13 +00:01:26,740 --> 00:01:32,340 +تقريبا أخر نقطة اتكلمنا عنها المرة الماضيةالان + +14 +00:01:32,340 --> 00:01:39,640 +بالنسبة لل nucleophiles اللى هى تمثل نص التفاعل + +15 +00:01:39,640 --> 00:01:44,060 +يعنى هذا التفاعل لو احنا بدنا نفهمه هو مكوّن من + +16 +00:01:44,060 --> 00:01:52,360 +شقين مكوّن من alkyl halide RX ومكوّن من اشمن الـ + +17 +00:01:52,360 --> 00:01:57,240 +nucleophile فالذي يفهم التفاعل جيدا يكون يعرف ال + +18 +00:01:57,240 --> 00:02:01,540 +الهيلايتز و أخذنا فكرة عنهم و عن أنواعهم و عن قوة + +19 +00:02:01,540 --> 00:02:05,420 +الرابط فيهم قلنا أسهل شيء التفاعل مع المراكبات + +20 +00:02:05,420 --> 00:02:10,200 +اللي فيها اليود أكثر من .. الآن بلزمنا أيضا نتعرف + +21 +00:02:10,200 --> 00:02:14,600 +على ال nucleophiles واضح؟ يعني لما بيكون في صراع + +22 +00:02:14,600 --> 00:02:17,850 +على سبيل المثال بين دولتينالذين يريدون أن يفهموا + +23 +00:02:17,850 --> 00:02:21,270 +الأمر جيدا يريدون أن يفهموا الدولتين وقوة + +24 +00:02:21,270 --> 00:02:24,150 +الدولتين، والذين يريدون أن يفهموا التفاعل جيدا + +25 +00:02:24,150 --> 00:02:28,530 +يريدون أن يكونوا عارف الـAlkyl Halides وخواصة وكيف + +26 +00:02:28,530 --> 00:02:34,310 +تتفاعل ويعرفلنيوكليوفايل احنا بدنا المرة الماضية + +27 +00:02:34,310 --> 00:02:37,810 +حكينا عن ال الكلهيلايت تصنيفاتها ل primary و + +28 +00:02:37,810 --> 00:02:42,170 +secondary و tertiary ان ال X ممكن تكون يودي برومي + +29 +00:02:42,170 --> 00:02:46,110 +كلور كل المعلومات هذه شرحناها بخصوص ال الكلهيلايت + +30 +00:02:46,110 --> 00:02:50,490 +اذا اليوم هيكون جزء من الكلام اللى هنبدأ فيه ان + +31 +00:02:50,490 --> 00:02:56,070 +نتعرف على نيوكليوفايل طبعا سبق اننا قلنا ايش معنى + +32 +00:02:56,070 --> 00:03:02,570 +نيوكليوفايل بكل الأحوال نيوكليوفايلعبارة عن جزء او + +33 +00:03:02,570 --> 00:03:08,490 +ايون مش مشكلة اهمه يميزه ايش زوج الالكترونات + +34 +00:03:08,490 --> 00:03:14,060 +لاحظوا انتوا قلتوا سالب انا ماقلتش سالبمش الزام + +35 +00:03:14,060 --> 00:03:20,500 +انه لليوكليوفايل يكون سالب لليوكليوفايل يميزه وجود + +36 +00:03:20,500 --> 00:03:25,240 +الزوج الإلكترونات غير الرابط واضح؟ أزواج + +37 +00:03:25,240 --> 00:03:30,000 +الإلكترونات الحرة هي اللي بتميزه الآن لليوكليوفايل + +38 +00:03:30,000 --> 00:03:35,720 +ضمن هذا التعريف يمكن أن يكون متعادلا ويمكن أن يكون + +39 +00:03:35,720 --> 00:03:39,880 +مشحونا إذا كان مشحون هيكون مشحون بشحنه سالبةيعني + +40 +00:03:39,880 --> 00:03:45,120 +مثلا ال O H في مركب زي ال N A O H يعني مافيش O H + +41 +00:03:45,120 --> 00:03:49,940 +minus بتلبع و بتنشر لحالها مافيش أيونات بتلبع و + +42 +00:03:49,940 --> 00:03:54,020 +بتنشر لحالها عادة المركبات ايش بتكون متعادلة يعني + +43 +00:03:54,020 --> 00:03:59,540 +يوم بقول O H minus كأن انا بقولن او اتش او + +44 +00:03:59,540 --> 00:04:04,460 +بوتاسيوم هيدروكسيد او اي شئ لكن انا مهتم الآن بال + +45 +00:04:04,460 --> 00:04:08,900 +O H جزء ال O H هو اللي هيتفاعل معاه الان هذا ال O + +46 +00:04:08,900 --> 00:04:13,060 +H هيتوزيع الالكتروني لو حسب الشحن على ال oxygen + +47 +00:04:13,060 --> 00:04:18,780 +بلاحظ انه minus وبناء على ذلك بقول ان ال O H minus + +48 +00:04:18,780 --> 00:04:24,440 +is a charged nucleophile نيوكليوفال مشحون كذلك + +49 +00:04:24,440 --> 00:04:29,300 +الحال ال CN minusتشارج الـ nucleophile بنبيع لحاله + +50 +00:04:29,300 --> 00:04:34,520 +أكيد لأ بنشتريه بنستعمله مثلا ع شكل potassium + +51 +00:04:34,520 --> 00:04:39,460 +cyanide واضح هذا المركب السام و الخطير اللي عادة + +52 +00:04:39,460 --> 00:04:44,140 +بنسمحش الناس تستعمله في المختبر بدون رقابة لأنه لو + +53 +00:04:44,140 --> 00:04:49,700 +طلع كميات صغيرة من ال HCN الناس اتعاملت معه تتسمم + +54 +00:04:49,700 --> 00:04:53,940 +و يؤدي إلى وفاة سريعة جدا يعني خلال دقيقة أو + +55 +00:04:53,940 --> 00:04:58,340 +دقيقتين فمستقبلكملو جيتوا تشتغلوا مع potassium + +56 +00:04:58,340 --> 00:05:02,640 +cyanide مع potassium cyanide بدكوا حذر بدوا ناس + +57 +00:05:02,640 --> 00:05:05,860 +يكونوا معاكوا في المختبر يعلموكوا كيف تشتغلوا + +58 +00:05:05,860 --> 00:05:10,240 +بخزانة أبخرة إنما واحدة حاطة potassium cyanide + +59 +00:05:10,240 --> 00:05:17,650 +وكبت عليه شوية HCl طلع HCl غاز شمتهبكون عندها + +60 +00:05:17,650 --> 00:05:20,830 +دقيقتين تتشاهد و تقول لا إله إلا الله مش أكثر من + +61 +00:05:20,830 --> 00:05:26,310 +هذا واضح النقطة فبدنا نلتبه الخلاصة في كل الأحوال + +62 +00:05:26,310 --> 00:05:32,750 +أن هذه الـcharged uq files عادة هي عبارة عن مركبات + +63 +00:05:32,750 --> 00:05:37,500 +أيونيةفيها ايون موجب و ايون سالب الان احنا اللي + +64 +00:05:37,500 --> 00:05:41,680 +بدى يتفاعل عندنا ايش الايون السالب و عشان هيك + +65 +00:05:41,680 --> 00:05:45,520 +بنذكره لحاله يعني عادة مابفرجش عندى لو كان هذا + +66 +00:05:45,520 --> 00:05:49,680 +potassium cyanide ولا sodium cyanide مثلا ولا ايش + +67 +00:05:49,680 --> 00:05:55,010 +ماكان يكون انا مهتمبالـ Ion الساني هذا بالنسبة + +68 +00:05:55,010 --> 00:05:57,950 +للنوع الأول من الـ nucleophiles اللي هو الـ + +69 +00:05:57,950 --> 00:06:02,010 +charged nucleophiles النوع التاني الـ neutral + +70 +00:06:02,010 --> 00:06:06,570 +nucleophiles الـ neutral nucleophiles مثلا الماء + +71 +00:06:06,570 --> 00:06:11,950 +شايفين فيه عادة رابطتين وزوجين من الإلكترونات إذا + +72 +00:06:11,950 --> 00:06:16,550 +ممكن يهاجم على الـ Alkyl Halide من خلال زوج + +73 +00:06:16,550 --> 00:06:21,830 +الإلكترونات هذا ويتفاعل معهبالتأكيد الماء هنا يمثل + +74 +00:06:21,830 --> 00:06:25,950 +الـ neutral الـ nucleophile الأمونيا على سبيل + +75 +00:06:25,950 --> 00:06:29,730 +المثال الـ neutral الـ nucleophile الان لو كان + +76 +00:06:29,730 --> 00:06:33,310 +عندي substituted أمونيا يعني بدل ما الثلاث ذرات + +77 +00:06:33,310 --> 00:06:37,530 +هدول كانوا هيدروجين لو واحدة منهم كانت مجموعة R + +78 +00:06:38,180 --> 00:06:42,160 +بيظلوا اليوكليوفايل و لا لأ اكيد و لو تنتين كانوا + +79 +00:06:42,160 --> 00:06:45,320 +مجموعة R بيظلوا اليوكليوفايل و لو التلاتة كانوا + +80 +00:06:45,320 --> 00:06:49,560 +مجموعة R هيظلوا اليوكليوفايل فحيصير الإنسان يتكلم + +81 +00:06:49,560 --> 00:06:53,680 +عن ال nitrogen اليوكليوفايل ال nitrogen + +82 +00:06:53,680 --> 00:06:58,760 +اليوكليوفايل واضح يعني مش ضروري بس ال ammoniaمش + +83 +00:06:58,760 --> 00:07:02,620 +ضروري بس الأمونيا بنحكي عن ال nitrogen نيوكليوفايل + +84 +00:07:02,620 --> 00:07:07,400 +سواء بتلاتة هيدروجين بدون ولا ار ار واحدة اتنين + +85 +00:07:07,400 --> 00:07:14,560 +تلاتة كل هذه تعتبر عبارة عن ايش النيوكليوفايل الان + +86 +00:07:14,560 --> 00:07:21,000 +بيفيدنا ان نعرف كيف النيوكليوفايل بيكون اقوى او + +87 +00:07:21,000 --> 00:07:25,320 +اضعف من النيوكليوفايل التاني اللي بنسميه احنا ال + +88 +00:07:25,320 --> 00:07:30,530 +strength of نيوكليوفايلو هذا أمر دائما بيسأل + +89 +00:07:30,530 --> 00:07:34,150 +الطالب عنه يعني بنقوله أي ال eucleophile أقوى ألف + +90 +00:07:34,150 --> 00:07:39,550 +ولا با هذا ولا هذا في عندنا قواعد عامة القاعدة + +91 +00:07:39,550 --> 00:07:46,240 +الأولى بتقول إذا أنا بأقارنتشارج النيوكليوفايل + +92 +00:07:46,240 --> 00:07:51,540 +يحمل شحنة سالبة بنيوترال نيوكليوفايل دائما و أبدا + +93 +00:07:51,540 --> 00:07:55,480 +تشارج النيوكليوفايل أقوى من النيوترال يعني مثلا + +94 +00:07:55,480 --> 00:08:02,600 +انقارن ال OH- مع الميه مين الأقوى؟ انقارن ال + +95 +00:08:02,600 --> 00:08:08,760 +ethanol O- مع الاثانول مين الأقوى؟الـ ethyl O-, + +96 +00:08:08,760 --> 00:08:15,980 +الـ NH2- مع الـ NH3 من الأقوى، إذا دائما الـ + +97 +00:08:15,980 --> 00:08:20,660 +nucleophile اللي بيحمل شحنة سالبة، الـ charged + +98 +00:08:20,660 --> 00:08:25,000 +nucleophile are stronger than neutral nucleophile + +99 +00:08:25,000 --> 00:08:29,880 +واضح هذا الكلام؟ charged nucleophile are stronger + +100 +00:08:29,880 --> 00:08:36,120 +than neutral nucleophileطيب بيجينا السؤال لو بقارن + +101 +00:08:36,120 --> 00:08:41,920 +انا enucleophile مشحون مع مشحون او متعادل مع + +102 +00:08:41,920 --> 00:08:46,180 +متعادل واضح الفكرة اذا انا بعمل مقارنة ل + +103 +00:08:46,180 --> 00:08:51,340 +enucleophile مشحونومشحون او متعادل و متعادل مين + +104 +00:08:51,340 --> 00:08:56,920 +بيكون الاقوى الان هنا بلزمنا نتذكر شوية الجدول + +105 +00:08:56,920 --> 00:09:00,580 +الدوري كيف العناصر مرتبة في الجدول الدوري في + +106 +00:09:00,580 --> 00:09:04,140 +الجدول الدوري كلكم عارفين المهمين عند الكاربون + +107 +00:09:04,140 --> 00:09:10,230 +نيتروجين اكسوجينfloricloribromide الان قوة + +108 +00:09:10,230 --> 00:09:17,530 +اليوكليوفايدز بتزيد حسب السهم بتزيد بهذا الاتجاه و + +109 +00:09:17,530 --> 00:09:22,670 +بتزيد بهذا الاتجاه واضح؟ + +110 +00:09:23,960 --> 00:09:28,600 +فلو أنا بدأ أعمل عدة مقارنات و الأسهم هذه موجودة + +111 +00:09:28,600 --> 00:09:33,240 +قدامي، على طول بقدر أتخذ قرار، يعني مثلا لو بدأ + +112 +00:09:33,240 --> 00:09:37,100 +أقارن الأمونيا طبعا فيها إلكترونات و الميه فيها + +113 +00:09:37,100 --> 00:09:41,860 +إلكترونات أزواج، الأمونيا مع الميه، الأمونيا ذرتها + +114 +00:09:41,860 --> 00:09:47,260 +النيتروجين، الميه الوكسوجين، which is stronger؟ + +115 +00:09:47,260 --> 00:09:52,760 +الأمونياواضح؟ لحظوا هذا neutral و هذا neutral طب + +116 +00:09:52,760 --> 00:09:57,560 +لو أخدت منهم ال charge يعني أخدت من هنا حذفت H + +117 +00:09:57,560 --> 00:10:01,080 +plus صار ال ion ال minus ال NH2 minus و من هنا + +118 +00:10:01,080 --> 00:10:06,720 +حذفت H plus صار ال OH minus مشحون مع مشحون أيضا + +119 +00:10:06,720 --> 00:10:10,500 +مين بده يكون الأقوى ال NH2 minus أقوى من ال OH + +120 +00:10:10,500 --> 00:10:17,460 +minus واضح؟ الآن طب لو مشينا حسب المجموعة تحت ال + +121 +00:10:17,460 --> 00:10:22,360 +oxygen إيش في عنده؟الـ Sulphur لو بدأ أقارن الـ + +122 +00:10:22,360 --> 00:10:27,560 +H2S مع الـ H2O هاي مركّب Sulphur مركّب واسمه الـ + +123 +00:10:27,560 --> 00:10:31,380 +H2S أقوى، هذا نيوترال، هذا نيوترال طب لو بدأ أقارن + +124 +00:10:31,380 --> 00:10:39,340 +الـ SH-, الأيون السالب من هذا مع الـ OH-, الـ SH-, + +125 +00:10:39,340 --> 00:10:43,540 +لو بدأ أقارن اليود مع البروم، بدأ أقارن البروم مع + +126 +00:10:43,540 --> 00:10:48,930 +الكلورو هكذا واضح فال strength of nucleophiles + +127 +00:10:48,930 --> 00:10:54,530 +بيكون له كام قاعدة تلاتة القاعدة الأولى المشحون + +128 +00:10:54,530 --> 00:10:58,290 +أقوى من المتعدل القاعدة التانية إذا كنا بنحكي عن + +129 +00:10:58,290 --> 00:11:02,850 +عناصر بنفس الدورة بدنا نمشي بهذا الاتجاه بيكون + +130 +00:11:02,850 --> 00:11:05,850 +أقوى لل nucleophile القاعدة التالتة إذا بحكي عن + +131 +00:11:05,850 --> 00:11:11,490 +عناصر بنفس المجموعة بدأ أمشي بهذا الاتجاه واضح + +132 +00:11:11,490 --> 00:11:11,970 +الكلام + +133 +00:11:16,040 --> 00:11:22,200 +بهيك بيصير عندنا فكرة عن ال alkyl halides لوحدها و + +134 +00:11:22,200 --> 00:11:27,560 +أنواعها و بيصير عندنا فكرة عن ال nucleophiles الان + +135 +00:11:27,560 --> 00:11:32,040 +بدنا نعمل تفاعل ما بين ال alkyl halide و ال + +136 +00:11:32,040 --> 00:11:38,970 +nucleophileخلّينا نحط فرضية ان احنا بدين ب general + +137 +00:11:38,970 --> 00:11:45,330 +reaction يعني نقول ال الهلايد بشكل عام RX هذا ال + +138 +00:11:45,330 --> 00:11:52,010 +RX شو بده يفقد؟الـ X الهالوجين النيكليوفايلز أنواع + +139 +00:11:52,010 --> 00:11:57,150 +كتيرة من أشهر أنواع النيكليوفايلز اللي بنسميها ال + +140 +00:11:57,150 --> 00:12:03,030 +oxygen نيكليوفايلز اللي فيها أكسوجين و ال أكسوجين + +141 +00:12:03,030 --> 00:12:10,410 +عادة إما بيكون متعادل أو مشحون بالمتعادل بيكون + +142 +00:12:10,410 --> 00:12:17,260 +عليه رابطتين و زوجين إلكترونات بالمشحونبيكون فيه + +143 +00:12:17,260 --> 00:12:22,220 +رابطة واحدة و تلت أزواج، إلكترونات زي ما أجي أقول + +144 +00:12:22,220 --> 00:12:29,140 +الميّه، لاحظوا الميّه، هاي ال Oxygen، H و H، كام + +145 +00:12:29,140 --> 00:12:34,710 +رابطة شايفين؟تنتين، كم زوج إلكترونات؟ إتنين، الآن + +146 +00:12:34,710 --> 00:12:40,150 +لو بدي منها المشحون، بتكون OH كام رابطة شايفين؟ + +147 +00:12:40,150 --> 00:12:44,950 +كام زوج إلكترونات هنا؟ تلاتة، في هذه الحالة، هذا + +148 +00:12:44,950 --> 00:12:51,430 +النيكليوفايل بيكون مشحونكذلك الحال مع الـ Nitrogen + +149 +00:12:51,430 --> 00:12:56,390 +الـ Nucleophile تلت روابط وزوج إلكترونات بيكون + +150 +00:12:56,390 --> 00:13:00,290 +عبارة عن الـ Neutral Nucleophile لو شيلنا منه + +151 +00:13:00,290 --> 00:13:04,450 +هيدروجينة و خلناها رابطتين و زوجين إلكترونات، + +152 +00:13:04,450 --> 00:13:10,100 +بيصير إيش؟Charged Nucleophile والسلفر زيه تماما زي + +153 +00:13:10,100 --> 00:13:16,200 +ال Oxygen الآن لما بنجي نعمل تفاعل ها اننا RX + +154 +00:13:16,200 --> 00:13:22,180 +اجينا نفعله مع ال OH- كيف بدنا نعمل المعادلة + +155 +00:13:22,180 --> 00:13:29,700 +تبعتنا بدنا ببساطة نشيل ال X مع إلكتروناتها ونحط + +156 +00:13:29,700 --> 00:13:37,550 +محلها ال OHواضح؟ بدنا نشيل ال X مع إلكتروناتها + +157 +00:13:37,550 --> 00:13:41,130 +ونحط محالة ال O H ولذلك لما أنا بفعل RX مع O H + +158 +00:13:41,130 --> 00:13:47,130 +minus إيش الناتج الأساسي ال organic product؟ R O H + +159 +00:13:47,130 --> 00:13:55,450 +طبعا أكيد طلع عندى ال X minus هل يا ترى ال X minus + +160 +00:13:55,450 --> 00:14:00,530 +بيضطر لتسبح بالفراغ لحالها؟ قامين تقولنا إيش بتعمل + +161 +00:14:00,530 --> 00:14:07,850 +ال X minus؟ما هو أنا أساسا ال OHK هذي في معها N A + +162 +00:14:07,850 --> 00:14:17,730 +N A plus R الان هتطلع N A plus Xواضح؟ يعني اللي + +163 +00:14:17,730 --> 00:14:22,570 +كان ايون موجة مرافق لل OH بيصير ايون موجة مرافق لل + +164 +00:14:22,570 --> 00:14:28,190 +X احنا بشكل عام الأشياء ما عدا ال organic products + +165 +00:14:28,190 --> 00:14:31,190 +مش مهمة عندنا يعني دائما لما نقولكوا أكمل معادلة + +166 +00:14:31,190 --> 00:14:35,030 +في الكيميا العضوية و اكتبولنا ناتج العضوية الأشياء + +167 +00:14:35,030 --> 00:14:40,390 +التانية تحصيل حاصل مش مهمة فبالان لو اجينا عملنا + +168 +00:14:40,390 --> 00:14:45,210 +التفاعل مع ميّه ايش بدو يكون الناتج نفس ال RX مع + +169 +00:14:45,210 --> 00:14:49,640 +الميّهلاحظوا الميه لما تتفاعل من خلال أحد أزواج + +170 +00:14:49,640 --> 00:14:53,740 +الإلكترونات أول ما تتفاعل هذا أزواج الإلكترونات + +171 +00:14:53,740 --> 00:15:01,540 +هيعمل رابطة هيصير عند R O H 2 لأن الميه H2O هيصير + +172 +00:15:01,540 --> 00:15:06,340 +عند R O H 2 لو حسبناها لشوحنا بتكون موجبة مباشرة + +173 +00:15:06,340 --> 00:15:18,740 +بتفقد H بلس بيصف الناتج R O Hإذا ناتج إضافة الميّه + +174 +00:15:18,740 --> 00:15:25,900 +زي ناتج إضافة الـ OH- تماماً و كل نيوترال + +175 +00:15:25,900 --> 00:15:30,260 +نيوكليوفايل .. الآن بنسجلها قاعدة .. كل نيوترال + +176 +00:15:30,260 --> 00:15:34,950 +نيوكليوفايل .. لما بنحط نتيجة تفاعلهبدو يكون فقط + +177 +00:15:34,950 --> 00:15:41,450 +ايش H plus يعني الميه H2O لما بتبين في الناتج شو + +178 +00:15:41,450 --> 00:15:46,150 +بيبين منها OH طيب لو كنا بنشتغل على أمونيا بعد + +179 +00:15:46,150 --> 00:15:52,980 +شوية and H3لما تبين في ناتج النهائي، شو هتبين؟ الـ + +180 +00:15:52,980 --> 00:16:00,420 +H2 و هكذا كل نيوترال نيوكليوفايل بيكون عليه H عادة + +181 +00:16:00,420 --> 00:16:06,820 +لما تحطه ناتجه النهائي، بتشيله منه H مثلا، لو كنا + +182 +00:16:06,820 --> 00:16:13,200 +بنحكي عن ROHطبعا وين مركز الـ nucleophile في الـ + +183 +00:16:13,200 --> 00:16:18,960 +ROH؟ أي ضربة الـ O اللي عليها أزواج إلكترونات هذه + +184 +00:16:18,960 --> 00:16:24,580 +الـ O هي نفسها اللي هتيجي تحل محل ال X وانتبهوا + +185 +00:16:24,580 --> 00:16:28,420 +معاه أي نقطة اللي بدها تهاجم اللي هي مركز ال + +186 +00:16:28,420 --> 00:16:34,340 +nucleophile وين بدها تيجي تحل بالظبط؟ محل ال X مش + +187 +00:16:34,340 --> 00:16:39,770 +if ما كان تاني خلينيأعطيكم الكلام بمثال لأن أحيانا + +188 +00:16:39,770 --> 00:16:44,250 +في التطبيق بنلاحظ أنه بيصير عندكم مشكلة يعني مثلا + +189 +00:16:44,250 --> 00:16:50,150 +لو أنتوا لاحظته أنه عندكم مركب زي هذا المركب وفيه + +190 +00:16:50,150 --> 00:16:56,050 +PR مركب زي هذا المركب وفيه PR وإجينا قلنالكم + +191 +00:16:56,050 --> 00:17:02,190 +فعلونا يا مع CH3 CH2 OH + +192 +00:17:05,070 --> 00:17:10,150 +واضح؟ ايش اللي بدنا نشيله؟ ايش اللي بدنا نحط محله؟ + +193 +00:17:10,150 --> 00:17:15,590 +هذا المركب لكن من وين بدنا نشبكه؟ من أزواج + +194 +00:17:15,590 --> 00:17:19,230 +الإلكترونات اللي على ال O هذا بصفته نيوترا للـ + +195 +00:17:19,230 --> 00:17:24,570 +nucleophile شو هيفقد؟ ال H إذا لما أنا بدى أرسم + +196 +00:17:24,570 --> 00:17:33,470 +هنا الناتج هيكون عندي O CH2 + +197 +00:17:36,880 --> 00:17:43,280 +CH3 واضح فال نيوكليوفايل الرأس تبعه اللي بتفاعل هو + +198 +00:17:43,280 --> 00:17:49,400 +ايش ال oxygen طالما هو neutral مباشرة بدنا نشيل + +199 +00:17:49,400 --> 00:17:57,100 +منه ال H لما بنكتب الجواب يعني نفس هذا المركب لو + +200 +00:17:57,100 --> 00:18:04,800 +كان بيتفاعل مع ال ammonia and H3 شو هتكتبوه؟ + +201 +00:18:08,390 --> 00:18:16,150 +بتبط من عند ال N و هيكون N H2 واضح؟ طبعا هتيجي و + +202 +00:18:16,150 --> 00:18:20,630 +تقولوا طب و ال H اللي طلعت وين راحت؟ ما هي ال H مع + +203 +00:18:20,630 --> 00:18:28,660 +ال PR هتعمل زي H PRواضح؟ يعني الـ H plus اللي طلعت + +204 +00:18:28,660 --> 00:18:33,180 +مع الـ PR minus اللي هنا هيطلع HPR احنا بشكل أساسي + +205 +00:18:33,180 --> 00:18:38,740 +دائما مهتمين بالنتج العضوي لاحظوا كيف انه احنا لما + +206 +00:18:38,740 --> 00:18:43,060 +بنكتب معادلة فيها neutral نيوكليوفايل سواء كان + +207 +00:18:43,060 --> 00:18:47,320 +Oxygen سواء كان Nitrogen سواء كان Sulphur يعني لو + +208 +00:18:47,320 --> 00:18:50,920 +افترضوا ان هنا كانت في عندكم H2S + +209 +00:18:53,150 --> 00:18:59,990 +شو هتكتبوا؟ S H من وين شابك؟ من السلفر و هكذا + +210 +00:18:59,990 --> 00:19:08,250 +واضح؟ الآن لو خلنا نفس هذا المثال و قولنا بدنا + +211 +00:19:08,250 --> 00:19:14,270 +نعمل التفاعل مع أيونات سالبة شو الايون السالب اللي + +212 +00:19:14,270 --> 00:19:21,970 +هنا بدنا نكون استعملناه؟ S H minusبطلع النتج شو + +213 +00:19:21,970 --> 00:19:30,390 +الايون السالب اللى هنا بدنا نكون استعملناه CH3 CH2 + +214 +00:19:30,390 --> 00:19:35,770 +O برابط واحدة و تلت أزواج إلكترونية يعني O minus + +215 +00:19:35,770 --> 00:19:42,150 +طبعا هذي ايش الايون المرافق عادة لها ال Sodium Na + +216 +00:19:42,150 --> 00:19:49,880 +Plus و المركب لو بدنا نسميه ايش بنسميهSodium + +217 +00:19:49,880 --> 00:19:55,160 +Ethoxide لحظة هذه إثل و بزام أكسوجين سالب + +218 +00:19:55,160 --> 00:19:59,460 +الأكسوجين السالب ايش متعودين طول عمرنا نقوله أكسيد + +219 +00:19:59,460 --> 00:20:03,720 +زي ما بنقول للأيون السالب كلورايد ايد النهاية ايد + +220 +00:20:03,720 --> 00:20:09,450 +برمايد ايودايد طب لو أكسوجين سالبأوكسايد لو + +221 +00:20:09,450 --> 00:20:16,190 +نيتروجين سالب نيترايد لو سلفر سالب سلفايد الان لو + +222 +00:20:16,190 --> 00:20:24,130 +اذا الاكسجين سالب اثوك اث اكس اي اث اكسايد عشان + +223 +00:20:24,130 --> 00:20:31,290 +كذا المركب بيكون اسمه صوديوم اث اكسايد لو + +224 +00:20:31,290 --> 00:20:37,610 +كتبنالكوا صوديوم اث اكسايد ايش بدكم تحطوه CH3لو + +225 +00:20:37,610 --> 00:20:42,670 +قلنا بروبوكسايد تلت + +226 +00:20:42,670 --> 00:20:48,970 +كربونات من البروبين و هكذا فال ايون بشكل عام بيكون + +227 +00:20:48,970 --> 00:20:54,390 +اسمه الكوكسايد ايش يعني الكو يعني في مجموعة الكل + +228 +00:20:54,390 --> 00:20:59,150 +يعني يوم ما بدي اقول ايون ر او ماينوس ايش اسم هذا + +229 +00:20:59,150 --> 00:21:05,000 +الايونلو جيبنا لكوا سؤال أكمل الفراغ R O minus is + +230 +00:21:05,000 --> 00:21:13,940 +called an alkoxide anion أنيون يعني أيون إيش؟ سالب + +231 +00:21:13,940 --> 00:21:18,980 +الكوكسايد أنيون + +232 +00:21:18,980 --> 00:21:25,340 +واضح؟ الكوكسايد أنيون إذا صار عندنا فكرة تماما كيف + +233 +00:21:25,340 --> 00:21:33,150 +نكمل معادلةبأيون سالب أو بمتعدل في كل الأحوال مكان + +234 +00:21:33,150 --> 00:21:37,650 +ما بتكون الهالوجين مكان ما بنحط ايش لنيوكليوفايل + +235 +00:21:37,650 --> 00:21:42,590 +ونعمل لنيوكليوفيليك substitution كل الجداول اللي + +236 +00:21:42,590 --> 00:21:52,050 +موجودة عندكم هي أمثلة على هذا الموضوع كل الجداول + +237 +00:21:52,050 --> 00:21:59,280 +يعني لاحظوا لنيوكليوفايل هنا OH-تشارج RO- تشارج + +238 +00:21:59,280 --> 00:22:07,280 +HOH تشارج ROH تشارج HOH تشارج HOH تشارج HOH تشارج + +239 +00:22:07,280 --> 00:22:08,700 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +240 +00:22:08,700 --> 00:22:09,060 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +241 +00:22:09,060 --> 00:22:09,680 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +242 +00:22:09,680 --> 00:22:09,740 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +243 +00:22:09,740 --> 00:22:11,520 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +244 +00:22:11,520 --> 00:22:16,780 +HOH تشهذا الأكسجين بتحول محل الـCl الـ Nitrogen + +245 +00:22:16,780 --> 00:22:22,280 +نيوكليوفايل مثلا نيوترال الأمونيا ومشتقاتها سواء + +246 +00:22:22,280 --> 00:22:26,260 +كان عنده R واحدة أو تنتين أو تلاتة في كل الأحوال + +247 +00:22:26,260 --> 00:22:32,390 +من وين بكيش بيك؟ من مكانالنيتروجين السلفر + +248 +00:22:32,390 --> 00:22:38,370 +النيوكليوفيل على سبيل المثال SH-, RS-, R2S من + +249 +00:22:38,370 --> 00:22:44,210 +أزواج الإلكترونات على السلفر الهالوجين + +250 +00:22:44,210 --> 00:22:49,410 +النيوكليوفيل الهالوجين عادة عليها أربع أزواج + +251 +00:22:49,410 --> 00:22:55,220 +إلكترونات و بتكون سالبةواضح؟ بديكوا تتذكروا نقطة + +252 +00:22:55,220 --> 00:22:58,300 +انه احنا قولنا ال halogens لما تحل محال بعضها + +253 +00:22:58,300 --> 00:23:05,620 +البعض اليود اقوى من ال brom اقوى من ال chlorine + +254 +00:23:05,620 --> 00:23:11,400 +بناء على ذلك لو عندى مركب RX فيه brom وفعلته مع + +255 +00:23:11,400 --> 00:23:15,620 +يود اليود بيحل محال ال brom ولا لأ؟ اه لكن ال brom + +256 +00:23:15,620 --> 00:23:22,380 +بيحلش محال اليوداليود بيحل محل بروم بمعنى لو كانت + +257 +00:23:22,380 --> 00:23:32,240 +المعادلة بهذا الشكل I minus زائد CH3PR وقلنا لك + +258 +00:23:32,240 --> 00:23:40,840 +اكمل المعادلة بيحل اليود محل بروم او محل كلور سواء + +259 +00:23:40,840 --> 00:23:44,980 +كان بروم او كلور بيصير هذا التفاعل بيصير شو الناتج + +260 +00:23:44,980 --> 00:23:48,080 +CH3I + +261 +00:23:51,470 --> 00:23:58,690 +زائد PR ماينوس أو CL ماينوس ايش السؤال PR مش كازم + +262 +00:23:58,690 --> 00:24:03,850 +ترتبط مثلا باش مهم مش مهم هو هذا NA plus بديش انا + +263 +00:24:03,850 --> 00:24:08,430 +اعيد الجملة مية مرة هذا NA plus I minus لما نشوفه + +264 +00:24:08,430 --> 00:24:14,170 +كتفاعل كامل NA plus I minus زائد CH3PR إجت ليه محل + +265 +00:24:14,170 --> 00:24:28,430 +ال PR شو طلع عندىCH3I PR- N A N A Plus واضح؟ + +266 +00:24:28,430 --> 00:24:34,770 +لو هذه المعادلة وجدت عندكم بشكل معاكس يعني إيجينا + +267 +00:24:34,770 --> 00:24:40,630 +قولنا لكم CL- CH3PR + +268 +00:24:43,400 --> 00:24:46,740 +الكلور لا يحل محل البروم، البروم يحل محل الكلور و + +269 +00:24:46,740 --> 00:24:54,000 +هكذا واضح الفكرة؟ من الـ nucleophiles أيضا ال + +270 +00:24:54,000 --> 00:24:58,320 +carbon nucleophiles منها ال CN اللي حكينا عنه و + +271 +00:24:58,320 --> 00:25:02,780 +قولنا موجود ع شكل CN minus ال carbon nucleophiles + +272 +00:25:02,780 --> 00:25:08,560 +بالمناسبة لا توجد متعادلة ليش ال carbon + +273 +00:25:08,560 --> 00:25:14,070 +nucleophiles لا توجد متعادلة؟لأن الكربون أول ما + +274 +00:25:14,070 --> 00:25:18,870 +تعلمنا الكيميا يقولنا بيعمل أربع روابط ولا يبقى + +275 +00:25:18,870 --> 00:25:25,010 +فيه أزواج إلكترونات الميّه رابطتين وزوجين + +276 +00:25:25,010 --> 00:25:28,470 +إلكترونات النيتروجين تلت روابط وزوج إلكترونات + +277 +00:25:28,470 --> 00:25:33,130 +الهالوجين تلت أزواج إلكترونات كلهم عليهم أزواج + +278 +00:25:33,130 --> 00:25:34,950 +إلكترونات لكن الكربون + +279 +00:25:37,240 --> 00:25:40,500 +الـ Carbon مافيش عليه أزواج إلكترونات وبناء على + +280 +00:25:40,500 --> 00:25:43,300 +ذلك في الوضع المتعادل مافيش عندي carbon + +281 +00:25:43,300 --> 00:25:48,620 +nucleophile لكن لو هذا فقد H لسبب ما بيصير ايون + +282 +00:25:48,620 --> 00:25:53,740 +ايش سالب من أمثلة الايونات السالب اللي فيها Carbon + +283 +00:25:53,740 --> 00:25:58,100 +ايون الـ C9 هاي C triple bond N وهنا شايفين في + +284 +00:25:58,100 --> 00:26:02,420 +عندكم زوج من الإلكترونات ولا لأ لاحظوا + +285 +00:26:03,550 --> 00:26:08,550 +لو واحدة شوية بتدقيق الكلام الـCN- في زوج + +286 +00:26:08,550 --> 00:26:12,530 +إلكترونات على الكربون و زوج إلكترونات على + +287 +00:26:12,530 --> 00:26:16,190 +النيتروجين يعني من ناحية المبدأ ممكن أي واحدة تفكر + +288 +00:26:16,190 --> 00:26:21,250 +إنه الكربون نفسه بيعمل الـNucleophile و النيتروجين + +289 +00:26:21,250 --> 00:26:25,590 +نفسه بيعمل الـNucleophile عشان هيك لو إجتها معادلة + +290 +00:26:25,590 --> 00:26:34,490 +اتكملها CH3 نفترض CLوبدأ اتفعلها مع ال NACN احنا + +291 +00:26:34,490 --> 00:26:38,530 +بدنا ندمج العلم عاد ال carbon ال nucleophile اقوى + +292 +00:26:38,530 --> 00:26:44,110 +من ال nitrogen لما حكينا قوة لل nucleophiles وبناء + +293 +00:26:44,110 --> 00:26:49,230 +على ذلك هذا لما بدأ افعله مع ال CN minus من وين + +294 +00:26:49,230 --> 00:26:57,110 +هييجي يتحد هنا اذا النتج هيكون CH3 اتصلت بال + +295 +00:26:57,110 --> 00:27:02,650 +cyanide من خلال carbonمن خلال الكربون مش + +296 +00:27:02,650 --> 00:27:07,910 +النيتروجين واضح؟ طبعا النيتروجين بيبقى عليها زوج + +297 +00:27:07,910 --> 00:27:13,590 +الالكترونات تبعها ف الـ CN- بتتحد مكان الهالوجين + +298 +00:27:13,590 --> 00:27:21,080 +من خلال الكربون مش النيتروجينخدوا في كمان ايون + +299 +00:27:21,080 --> 00:27:25,900 +اخدناه اخذنا تفاعله ل triple bond اللي بتكون + +300 +00:27:25,900 --> 00:27:31,440 +terminal جنبها H اتفقنا ان هذا الـH اسيدك يمكن ان + +301 +00:27:31,440 --> 00:27:37,460 +تفقد وتعمل ايون سالب على الكربون سمناه Acetylide + +302 +00:27:37,460 --> 00:27:43,820 +anion هذا اخدناه بتفاعل الالكاينز اخر تفاعل راجعوا + +303 +00:27:43,820 --> 00:27:47,980 +الان هذا ال Acetylide anion لو اجيناه فاعلناه مع + +304 +00:27:47,980 --> 00:27:58,410 +RXماذا سيفعل؟ سيأتي الكربون تهاجم وتطرد الـ X إذا + +305 +00:27:58,410 --> 00:28:05,850 +صار عندي A اللي موجودة هنا C triple bond CR فهيصير + +306 +00:28:05,850 --> 00:28:13,210 +إبدال لل X بالacetylide anion من خلال الكربون + +307 +00:28:13,210 --> 00:28:17,330 +النيوكليوفال كل هذه الأمثلة اللي انتوا شايفينها هي + +308 +00:28:17,330 --> 00:28:23,530 +عبارة عنsubstitution reactions كل الأمثلة اللي مرت + +309 +00:28:23,530 --> 00:28:27,930 +علينا substitution reactions استعرضناها بتوسع سواء + +310 +00:28:27,930 --> 00:28:33,470 +من ناحية neutral enucleophiles أو من ناحية charged + +311 +00:28:33,470 --> 00:28:34,870 +enucleophiles + +312 +00:28:38,920 --> 00:28:45,140 +بجينا تفاعل تاني وهذا التفاعل التاني بشكل عام + +313 +00:28:45,140 --> 00:28:50,920 +منافس لتفاعل الإبدال بمعنى التفاعلين بيصيروا مع + +314 +00:28:50,920 --> 00:28:58,200 +بعض يعني انا بكون بدي اعمل تفاعل إبدال بلاحظ انه + +315 +00:28:58,200 --> 00:29:04,380 +مع الإبدال بطلع عندى ناتج تاني حذف ايش هو تفاعل + +316 +00:29:04,380 --> 00:29:09,400 +الحذف؟ماذا هو بالظبط تفاعل الحذف؟ تفاعل الإبدال؟ + +317 +00:29:09,400 --> 00:29:14,420 +اعرفنا يعني لو الآن جيبنالكم أكمل المعادلة هذه CH3 + +318 +00:29:14,420 --> 00:29:20,320 +CHPR CH3 زائد NUH كل كسرته تتقن الإبدال شيل ال PR + +319 +00:29:20,320 --> 00:29:23,180 +حط مكانها هذا + +320 +00:29:25,930 --> 00:29:30,410 +Substitution طب إيش تفاعل الحذف اللي بيصير بنفس + +321 +00:29:30,410 --> 00:29:33,470 +الشروط عشان هيك لاحظوا نفس المُركّب مع الانيواتش + +322 +00:29:33,470 --> 00:29:38,550 +بدنا نكتب إنه بيطلع ناتج تاني إنه يعمل حذف + +323 +00:29:38,550 --> 00:29:44,930 +للهالوجين مع هيدروجين عن الكربون المجاورة إيش معنى + +324 +00:29:44,930 --> 00:29:51,830 +الحذف إن أشيل الهالوجين مع ذرة هيدروجين يعني كإن + +325 +00:29:51,830 --> 00:30:00,140 +اللي بدي أحذف أشههH و PR واضح الان وين ال hydrogen + +326 +00:30:00,140 --> 00:30:05,620 +اللى انا بدي اشيله معروف واحد مافيش غيره طب وين ال + +327 +00:30:05,620 --> 00:30:10,120 +hydrogens على الكربون المجاورة لو انا اتيت واطلعت + +328 +00:30:10,120 --> 00:30:13,400 +هذه الكربون اللى حاملة ال hydrogen فيه جنبها على + +329 +00:30:13,400 --> 00:30:20,400 +اليمين CH3 حاملة كم هيدروجينة تلاتة وفيه جنبها على + +330 +00:30:20,400 --> 00:30:28,550 +اليسارCH3 حاملة 3 تفاعل الحذف ان اشيل ال PR هذه مع + +331 +00:30:28,550 --> 00:30:33,790 +ال Hشطابتهم طبعا هذه الرابطه هتيجي تعمل double + +332 +00:30:33,790 --> 00:30:38,210 +bond هنا فبدل ما كان عندي رابطه أحدية بتصير رابطه + +333 +00:30:38,210 --> 00:30:43,730 +ثنائية بتكون الألكيد طيب الآن يا ترى بيفرق عندى في + +334 +00:30:43,730 --> 00:30:48,710 +هذا المركب لما أعمل الحذف بمساعدة الانقوات ان اعمل + +335 +00:30:48,710 --> 00:30:53,770 +الرابطة الزوجية هان او هان نفس المركب نفس المركب + +336 +00:30:53,770 --> 00:31:01,860 +في مرات معينة هلاحظ انهبيفرق عندنا بعمل مشكلة + +337 +00:31:01,860 --> 00:31:06,820 +بيصير عندى احتمالين يعني لو أخدتوا هذا المركب اللى + +338 +00:31:06,820 --> 00:31:13,540 +هو اسمه two bromobutane high carbon اتنين تلاتة + +339 +00:31:13,540 --> 00:31:20,820 +اربعة هذا ايش اسمه two bromobutane كل الذرات اللى + +340 +00:31:20,820 --> 00:31:27,210 +موجودين عندى عبارة عن ايشهيدروجينز الان انا لما + +341 +00:31:27,210 --> 00:31:33,130 +بدي اعمل الحذف بمساعدة ال OH- و لاحظوا كيف بالظبط + +342 +00:31:33,130 --> 00:31:38,990 +بتتم عملية الحذف يعني كيف ال OH- هذه بتيجي بتعمل + +343 +00:31:38,990 --> 00:31:45,690 +الحذف ال OH- بدها إيش بدها H بلس فبتيجي بتهجم + +344 +00:31:45,690 --> 00:31:50,650 +هينفترض هجمت على هذي ال H بلس هى ال OH- أخدت ال H + +345 +00:31:50,650 --> 00:31:57,150 +بلس طلعت على شكل جزء إيشماء فهمنا هذه الخطوة + +346 +00:31:57,150 --> 00:32:01,390 +الأولى في التفاعل أن الـ OH- هجمت على الـ H أخدتها + +347 +00:32:01,390 --> 00:32:08,930 +عملت مية طلعت الآن هذه الرابط اللي ضالة بتلوف بهذا + +348 +00:32:08,930 --> 00:32:13,590 +الاتجاه معقول أن يصير خمس روابط إذا إيش هيصير طلوع + +349 +00:32:13,590 --> 00:32:21,150 +جبالها للـ PR بتم التفاعل فالـ OH والـ H شو + +350 +00:32:21,150 --> 00:32:29,870 +هيعطوني؟H2O طب ال PR minus مع ال NA اللي هنا ما هي + +351 +00:32:29,870 --> 00:32:36,450 +ال OH فيه معها إيش NA مش هذه NA plus OH minus + +352 +00:32:36,450 --> 00:32:40,230 +Sodium hydroxide ال PR ال minus مع ال NA شو + +353 +00:32:40,230 --> 00:32:49,340 +بتعطيني NA PR ال OH مع ال HH2O وبتكون عندى الـ + +354 +00:32:49,340 --> 00:32:52,420 +Double bond عشانك لو رجعته مرة تانية بسرعة شوفتوا + +355 +00:32:52,420 --> 00:32:59,440 +المعادلة اللى هنا Double bond NABR H2O شوفنا كيف + +356 +00:32:59,440 --> 00:33:05,560 +بتكونوا هدول التلاتة الميه انه اجت ال OH أخدت H + +357 +00:33:05,560 --> 00:33:10,240 +طلعت ال PR minus ال PR minus لجت ال NA plus عملت + +358 +00:33:10,240 --> 00:33:17,130 +معه NABR و المركب العضوى صارDouble bond صار ال + +359 +00:33:17,130 --> 00:33:21,750 +keen طبعا انا اللي بهمني كنتيجة اكتر ما يمكن ايش + +360 +00:33:21,750 --> 00:33:26,110 +ال organic compound يعني هذه المركبات تحصيل حاصل + +361 +00:33:26,110 --> 00:33:33,550 +مافيش فيهامافيش فيها مشكلة الان لاحظوا معاك كلكوا + +362 +00:33:33,550 --> 00:33:37,010 +اتفقتوا انه ماناش في ال NA احنا قيلنا في ال OH + +363 +00:33:37,010 --> 00:33:42,130 +بدها H مجاورة على هذه ال carbon طب هذه ال OH يا + +364 +00:33:42,130 --> 00:33:45,550 +تورا لو بدل ما تيجي هنا وتاخد H من هدول اللي على + +365 +00:33:45,550 --> 00:33:52,990 +الشمال لو كانت من أهل اليمين اجت ال OH واخدت هذه + +366 +00:33:52,990 --> 00:34:01,220 +ال H وارد ولا لأ؟خلّينا نشطب هذا الكلام الأولاني + +367 +00:34:01,220 --> 00:34:06,860 +الـ OH بده اتش مجاورة واحدة شمال واحدة يمين إذا + +368 +00:34:06,860 --> 00:34:10,720 +أصطدمت بالشمال وين حيصير الالكين؟ على هذا الموقع، + +369 +00:34:10,720 --> 00:34:16,140 +حيطلع هذا النتج طب لو أخدت هذه الـ H هاي ميل، هذه + +370 +00:34:16,140 --> 00:34:19,820 +وين بده تيجي على طول؟ هان، بده يتكون عندي أي + +371 +00:34:19,820 --> 00:34:24,740 +ألكين؟ ألكين، تاني الـ two butane في الحالة + +372 +00:34:24,740 --> 00:34:29,550 +الأولى، الوان بيوتينإذا لو في عندي أكثر من + +373 +00:34:29,550 --> 00:34:33,690 +الهيدروجين مجاورة أو كانوا مختلفات متوقع يطلع عندي + +374 +00:34:33,690 --> 00:34:39,170 +أكثر من ال keen لو كانوا متشابهات زي المثال السابق + +375 +00:34:39,170 --> 00:34:46,290 +يعني هنا CH3 و CH3 زي بعض ناتج واحد لما اختلفوا + +376 +00:34:46,290 --> 00:34:53,190 +صار هنا CH3 و هنا CH2 و CH3 صارواتخيل لو هنا كان + +377 +00:34:53,190 --> 00:34:59,030 +في مجموعة تالتة اذا ممكن يطلع عندى كام ناتج تلاتة + +378 +00:34:59,030 --> 00:35:03,990 +ممكن يكون النواتج اللى عندى مش بس اتنين ممكن يطلع + +379 +00:35:03,990 --> 00:35:10,290 +عندى تلت نواتج حدث يعني لو تخيلتوا ان هى عندى Cبر + +380 +00:35:10,290 --> 00:35:15,750 +وحطيت على جهة منها CH3 وهي نوع من الهيدروجينز + +381 +00:35:15,750 --> 00:35:24,570 +وحطيت على الجهة التانية CH2 CH3 هي مجموعة تانية + +382 +00:35:24,570 --> 00:35:35,590 +وحطيت على الجهة التالتة CH2 CH2 CH2 CH3هي مركّب + +383 +00:35:35,590 --> 00:35:41,030 +الان الشيء الأكيد اللي بدى أحذفه انا شهو هو ال PR + +384 +00:35:41,030 --> 00:35:48,250 +هاي ال PR حذفناها و hydrogen من الكربون المجاورة + +385 +00:35:48,250 --> 00:35:52,470 +لو حذفت من هنا وين هتصير ال double bond؟ ع هذا + +386 +00:35:52,470 --> 00:35:55,890 +الموقع لو حذفت من هنا وين هتصير ال double bond؟ ع + +387 +00:35:55,890 --> 00:35:58,410 +هذا الموقع لو حذفت من هنا وين هتصير ال double + +388 +00:35:58,410 --> 00:36:02,270 +bond؟ ع هذا الموقع اذا كام ال keen هنا متوقع عندى؟ + +389 +00:36:02,270 --> 00:36:07,600 +تلاتةجربوا انكم اتكملوهم في البيت ال double bond + +390 +00:36:07,600 --> 00:36:12,740 +تتكون على هذا الموقع او هان او هان هدولة عبارة عن + +391 +00:36:12,740 --> 00:36:19,200 +كام ناتج تلت نواتج و لو نفذت هذا الحذف و طلعته في + +392 +00:36:19,200 --> 00:36:23,360 +المركبات او حتى سميتهم حتلاقوهم تلت مركبات مختلفة + +393 +00:36:23,360 --> 00:36:31,220 +اذا في عندي دائما في عملية الحذف اكثر من ايشأكتر + +394 +00:36:31,220 --> 00:36:36,340 +من احتمال الآن بيصير السؤال طيب هذا الكلام بالورقة + +395 +00:36:36,340 --> 00:36:40,160 +والجلم أكتر من احتمال one butene او two butene او + +396 +00:36:40,160 --> 00:36:42,600 +هان ال double bond على هذا الموقع او على هذا او + +397 +00:36:42,600 --> 00:36:49,380 +على هذا على العين والراس بالتجربة هل يا ترى في شيء + +398 +00:36:49,380 --> 00:36:53,880 +بيطلع اكتر من شيء يعني بمعنى اخر بيطلع ك major + +399 +00:36:53,880 --> 00:37:01,440 +product كناتج أساسيهل في شيء عنده بيطلع و بقدر + +400 +00:37:01,440 --> 00:37:06,080 +اعتبره ناتج أساسي بمعنى لو انا الآن هدول احتمالات + +401 +00:37:06,080 --> 00:37:11,640 +بالورقة والجلم مظبوطين لكن لو جبتلكوا هذا كسؤال في + +402 +00:37:11,640 --> 00:37:16,500 +الامتحان و قلتلكوا اكمل المعادلة two bromobutane + +403 +00:37:16,500 --> 00:37:24,410 +مع OH- اكتبوا ال الكيل اللي عادة بيطلعلاحظوا معي + +404 +00:37:24,410 --> 00:37:29,890 +هلاحظ أن اللي بيطلع عادة هذا مش هذا هتقولوا الآن + +405 +00:37:29,890 --> 00:37:36,960 +بدنا قاعدةبناء على إيش؟ بناء على إيش؟ شوية أنا + +406 +00:37:36,960 --> 00:37:43,580 +بعتقد أن الأمر بحاجة إلى تفصيل وهذه الشغلة لاحظوا + +407 +00:37:43,580 --> 00:37:48,440 +معين هذه عكس الشغل اللي كان بيشتغله Markovnikov + +408 +00:37:48,440 --> 00:37:53,320 +متذكرين إيش كان بيشتغل Markovnikov؟ Markovnikov + +409 +00:37:53,320 --> 00:37:57,100 +كان يجيب ال double bond يحولها إلى single bond + +410 +00:37:57,100 --> 00:38:02,360 +يقول وين نحط ال H؟وانا احط ال PR وقلنا في عندى + +411 +00:38:02,360 --> 00:38:05,880 +Markovnikov addition وانتي Markovnikov addition ال + +412 +00:38:05,880 --> 00:38:09,000 +addition ان ال double bond تصير single bond ال + +413 +00:38:09,000 --> 00:38:12,100 +single + +414 +00:38:12,100 --> 00:38:17,080 +bond تصير double bondإذا ال elimination عكس ال + +415 +00:38:17,080 --> 00:38:23,140 +addition الحدث عكس إيش؟ الإضافة الحدث عكس الإضافة + +416 +00:38:23,140 --> 00:38:26,940 +الآن اللي كان بيشتغل على الموضوع هذا مع + +417 +00:38:26,940 --> 00:38:32,540 +Markovnikov بنفس الجامعة بنفس الوقت عالم اسمه + +418 +00:38:32,540 --> 00:38:37,060 +Zaitsevيعني الاتنين كانوا بيشتغلوا بحدود سنة ألف و + +419 +00:38:37,060 --> 00:38:41,940 +تمانية و سبعين خمسة و سبعين في جامعة Kazan في + +420 +00:38:41,940 --> 00:38:47,000 +روسيا Markovnikov عمل قاعدة Markovnikov للإضافة + +421 +00:38:47,000 --> 00:38:53,580 +Zaitsev عمل قاعدة Zaitsev لإيش؟ للحدث يمكن أنا أنا + +422 +00:38:53,580 --> 00:38:58,180 +مش مركز عليها لكن لبأس نحكيلكوا يها بسرعة إيش + +423 +00:38:58,180 --> 00:39:01,760 +بتقول هذه قاعدة Zaitsev للحدث؟ + +424 +00:39:04,190 --> 00:39:09,270 +Zaitsev's rule بتكتب باكثر من طريقة لحقيقة Zaitsev + +425 +00:39:09,270 --> 00:39:13,810 +ببساطة بيقول انه في مثل هذا الحدث the more + +426 +00:39:13,810 --> 00:39:20,570 +substituted ال keen will form the more substituted + +427 +00:39:20,570 --> 00:39:27,010 +ال keen will form يعني بيتكون ال keen الأكثر + +428 +00:39:27,010 --> 00:39:35,550 +إبدالابدي يتكون الألكين الأكثر إبدالا مش انا عندي + +429 +00:39:35,550 --> 00:39:40,170 +one butane و two butane النواتج مين الأكثر إبدالا + +430 +00:39:40,170 --> 00:39:44,910 +فيهم؟ بدنا نعرف إيش معنى الألكين الأكثر إبدالا + +431 +00:39:44,910 --> 00:39:49,670 +اللي بدي يعرف معنى الألكين الأكثر إبدالا بدي ييجي + +432 +00:39:49,670 --> 00:39:54,810 +للألكين الأقل إبدالا يكون فاهمه أبسط ألكين في + +433 +00:39:54,810 --> 00:39:56,070 +الدنيا شو هو؟ + +434 +00:40:03,470 --> 00:40:06,010 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +435 +00:40:06,010 --> 00:40:07,090 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +436 +00:40:07,090 --> 00:40:07,810 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +437 +00:40:07,810 --> 00:40:10,050 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +438 +00:40:10,050 --> 00:40:10,510 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +439 +00:40:10,510 --> 00:40:10,830 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +440 +00:40:10,830 --> 00:40:11,270 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +441 +00:40:11,270 --> 00:40:17,890 +أربعة1 لو شيلت كمان قدش و خليتها R افدالين لو شيلت + +442 +00:40:17,890 --> 00:40:20,870 +كمان قدش و خليتها R افدالين لو شيلت كمان قدش و + +443 +00:40:20,870 --> 00:40:21,530 +خليتها R افدالين لو شيلت كمان قدش و خليتها R + +444 +00:40:21,530 --> 00:40:23,530 +افدالين افدالين افدالين افدالين افدالين افدالين + +445 +00:40:23,530 --> 00:40:25,170 +افدالين افدالين افدالين افدالين افدالين افدالين + +446 +00:40:25,170 --> 00:40:25,250 +افدالين افدالين افدالين افدالين افدالين افدالين + +447 +00:40:25,250 --> 00:40:28,010 +افدالين افدالين افدالين افدالين افدالين افدالين + +448 +00:40:28,010 --> 00:40:37,750 +افدالين افدالين افدالين افدالين + +449 +00:40:37,750 --> 00:40:44,260 +افدالالان اذا هذه لاتش نفترض كانت هذا المركب R + +450 +00:40:44,260 --> 00:40:49,020 +وهنا كان R قلتلكوا هذا كم substitution عليه اتنين + +451 +00:40:49,020 --> 00:40:54,860 +اذا مين more substituted هذا ولا الاتين هذا هذا + +452 +00:40:54,860 --> 00:40:59,000 +مافيش عليه ولا ابدال الاتين مافيش عليه ولا ابدال + +453 +00:40:59,000 --> 00:41:02,460 +ولا هيدروجينة ابدلة هذا كم ابدال عليه اتنين طيب لو + +454 +00:41:02,460 --> 00:41:08,450 +قلتلكوا هذا المركب ولا هذاهذا كام إبدال عليه اللي + +455 +00:41:08,450 --> 00:41:13,690 +جابله طب لو حطينا هنا كمان R أربعة which is more + +456 +00:41:13,690 --> 00:41:17,810 +substituted واضح الفكرة إيش معنى more substituted + +457 +00:41:17,810 --> 00:41:23,490 +كل ما صار عليه مجموعات R أكثر الآن لو إجينا و + +458 +00:41:23,490 --> 00:41:26,970 +اتطلعنا على هدول التلان فصلولي حوالين ال double + +459 +00:41:26,970 --> 00:41:30,610 +bond يعني قولوا هذه double bond هنا إيش موجود + +460 +00:41:30,610 --> 00:41:33,790 +عندكم إبدلات؟ لا + +461 +00:41:36,790 --> 00:41:43,570 +و هان H هذي اللي شطبناها و هان K إذا هذا لو بدكوا + +462 +00:41:43,570 --> 00:41:49,770 +تقارنوه بال إثليين كام إفدال عليه حقيقة؟ واحد لو + +463 +00:41:49,770 --> 00:41:54,550 +هذه تنشر و تصير H بيبطل مبدل إذا هذا كام إفدال + +464 +00:41:54,550 --> 00:41:58,970 +عليه؟ واحد طب لو إجيت على المركب التاني هاي ال + +465 +00:41:58,970 --> 00:42:05,590 +double bond هنا إيش في عندكم؟ H و هنا فصلتهم + +466 +00:42:06,370 --> 00:42:13,290 +وهنا تطلعوا إيش في عندكم؟ carbon إذا هذه مقدلة + +467 +00:42:13,290 --> 00:42:20,510 +وهنا carbon إذا هذا كام إبدال؟ اتنين which is more + +468 +00:42:20,510 --> 00:42:24,670 +substituted ال two butyl is more substituted than + +469 +00:42:24,670 --> 00:42:30,950 +one butyl فهذا اللي بيكون major product شوفته كيف؟ + +470 +00:42:31,530 --> 00:42:35,370 +الـ two butane is more substituted لأنه في + +471 +00:42:35,370 --> 00:42:38,810 +مجموعتين ألكل على ال double bond أنا بس بتطلع على + +472 +00:42:38,810 --> 00:42:42,610 +أطراف ال double bond و لحد الأقصى للإبدال جديش + +473 +00:42:42,610 --> 00:42:48,110 +أربعة هنا في عندى إبدال واحد هنا في عندى اتنين + +474 +00:42:48,710 --> 00:42:54,390 +ابدالين اذا this compound is more substituted than + +475 +00:42:54,390 --> 00:42:58,790 +this compound واضح الفكرة اللي more substituted هو + +476 +00:42:58,790 --> 00:43:04,510 +بيكون ال major product خليني اعطيكم سؤال homework + +477 +00:43:04,510 --> 00:43:08,730 +اتجربوا تعملوه و بننهي فيه لو يا ترى حطينا هذا + +478 +00:43:08,730 --> 00:43:14,690 +المركب و حطينا لكم ب ا حطينا هنا c H3 و حطينا هنا + +479 +00:43:14,690 --> 00:43:24,890 +عند اللزوم H و هنا حطينا CHCH3 وانا كمان حطينا CH3 + +480 +00:43:24,890 --> 00:43:33,170 +تانية الان اكتبولي نواتج الابدال و اقولولي اي واحد + +481 +00:43:33,170 --> 00:43:39,530 +فيهم ال major يعني هذا بدياه مع ال OH minus يعمل + +482 +00:43:39,530 --> 00:43:45,900 +ابدال elimination هو اكيد بيعملعفوا الحدث نواتج + +483 +00:43:45,900 --> 00:43:51,160 +الحدث اكتبولي نواتج الحدث الممكنة و اي واحد منهم + +484 +00:43:51,160 --> 00:43:58,080 +ال major product الان بالتأكيد مع الحدث فيه كمان + +485 +00:43:58,080 --> 00:44:03,980 +ايش ابدال يعني بمعنى ان هذا التفاعل لا يلفك دائما + +486 +00:44:03,980 --> 00:44:10,140 +بطلع فيه ناتج ابدالوناتج حذف بنسبة مختلفة حسب ظروف + +487 +00:44:10,140 --> 00:44:14,980 +التفاعل وحسب عوامل كتير بتأثر لكن احنا الآن سؤالنا + +488 +00:44:14,980 --> 00:44:21,260 +بد نواتج الحذف الممكن لهذا التفاعل واي ناتج من + +489 +00:44:21,260 --> 00:44:27,340 +هدول النواتج اللي هو يعتبرالـ major product ضايل + +490 +00:44:27,340 --> 00:44:31,260 +عندنا شغلتين صغار بدون دقيقتين عشان المرة الجاية + +491 +00:44:31,260 --> 00:44:35,840 +نبدأ المركب من أول و جديد هذه ال slides اللي عندكم + +492 +00:44:35,840 --> 00:44:42,280 +كلها مركبات تطبيقية لهنوجين compounds يعنيالـ + +493 +00:44:42,280 --> 00:44:44,700 +Methyl bromide يستعمل في الزراعة، الـ + +494 +00:44:44,700 --> 00:44:47,940 +Dichloromethane يستعمل solvent، الchloroform + +495 +00:44:47,940 --> 00:44:52,680 +solvent، التفلون مار عليكم، اتذكرينه ولا لأ؟ + +496 +00:44:52,680 --> 00:44:57,300 +المركبات اللي فيها كلور و فلورو كاربون بيستعملوها + +497 +00:44:57,300 --> 00:45:02,630 +غازات ثلاجات بنسميها chlorofluorocarbonsمن ضمنها + +498 +00:45:02,630 --> 00:45:07,610 +الفريون اللي بتدمر طبقة الأوزون لاحظوا الـCFC شو + +499 +00:45:07,610 --> 00:45:12,290 +معناها؟ اكلورو فلورو كاربون يعني هي كلور هي فلور + +500 +00:45:12,290 --> 00:45:16,750 +هي كاربون صار اسمها الـCFC فيها كلور و فلور مين + +501 +00:45:16,750 --> 00:45:21,930 +اللي طلع زعلان؟ كاربون لأ البروم الهالوجين الأساسي + +502 +00:45:21,930 --> 00:45:27,650 +شمه؟ كلور و فلور برومطب هذه المراكبات ال CFCs فيها + +503 +00:45:27,650 --> 00:45:32,770 +كلور و فلور فيها بروم؟ طب لو حطينا عليها بروم شو + +504 +00:45:32,770 --> 00:45:38,630 +بيصير اسمها؟ هالونز بيصير كلور و فلور و كاربونز و + +505 +00:45:38,630 --> 00:45:43,090 +فيهم بروم بيصيروا هالونز عارفين شو ال هالونز؟ + +506 +00:45:43,090 --> 00:45:46,630 +اتطلع على الطفاية اللى على باب القاعة اللى عادة + +507 +00:45:46,630 --> 00:45:50,570 +اللى غطى أخضر هذه طفيات بدي استعملها لإطفاء حرائق + +508 +00:45:50,570 --> 00:45:55,210 +الكهربا وغيرها طفاية الغازغازات اللى بتتعبى فى + +509 +00:45:55,210 --> 00:45:58,910 +الطفاية اسمهم إيه؟ hellons لو قولنا لكوا شو ال + +510 +00:45:58,910 --> 00:46:04,190 +hellons؟ ال chlorofluorocarbons حملين بروم يعنى + +511 +00:46:04,190 --> 00:46:07,270 +chlorofluorobromocarbons + +512 +00:46:07,270 --> 00:46:12,310 +واضح؟ وكتيرة وكل اسم اللى لها اسم تجارى بنباعه و + +513 +00:46:12,310 --> 00:46:16,610 +بنشره و بنعبى فى الطفاية ابهيك بننتهى من chapter + +514 +00:46:16,610 --> 00:46:19,710 +ال alkalites ان شاء الله المرة القادمة بنبتدى فى + +515 +00:46:19,710 --> 00:46:21,670 +موضوع ال algorithms + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1FUjIgJdwak_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1FUjIgJdwak_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..cbb08c41790002b9448287f524b5c17a0f0967a7 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1FUjIgJdwak_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4713, "start": 19.93, "end": 47.13, "text": "بسم الله 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"probability": 0.5906982421875}, {"start": 374.95, "end": 375.29, "word": " Alkyl", "probability": 0.597412109375}, {"start": 375.29, "end": 375.67, "word": " Halide", "probability": 0.748046875}, {"start": 375.67, "end": 375.85, "word": " من", "probability": 0.98388671875}, {"start": 375.85, "end": 376.23, "word": " خلال", "probability": 0.9933268229166666}, {"start": 376.23, "end": 376.55, "word": " زوج", "probability": 0.978759765625}, {"start": 376.55, "end": 377.49, "word": " الإلكترونات", "probability": 0.9491373697916666}, {"start": 377.49, "end": 377.79, "word": " هذا", "probability": 0.677734375}, {"start": 377.79, "end": 378.35, "word": " ويتفاعل", "probability": 0.93369140625}, {"start": 378.35, "end": 378.71, "word": " معه", "probability": 0.79052734375}], "temperature": 1.0}, {"id": 17, "seek": 39753, "start": 379.25, "end": 397.53, "text": "بالتأكيد الماء هنا يمثل الـ neutral الـ nucleophile الأمونيا على سبيل المثال الـ neutral الـ nucleophile الان لو كان عندي substituted أمونيا يعني بدل ما الثلاث ذرات هدول كانوا هيدروجين لو واحدة منهم كانت مجموعة R", "tokens": [3555, 6027, 2655, 10721, 4117, 25708, 9673, 16606, 34105, 7251, 2304, 12984, 1211, 2423, 39184, 10598, 2423, 39184, 14962, 49242, 16247, 2304, 11536, 25528, 15844, 8608, 21292, 1211, 9673, 12984, 6027, 2423, 39184, 10598, 2423, 39184, 14962, 49242, 2423, 7649, 45164, 25961, 18871, 16254, 26441, 4866, 5551, 2304, 11536, 25528, 37495, 22653, 47525, 1211, 19446, 6024, 104, 1211, 5718, 104, 29910, 2288, 9307, 8032, 3215, 12610, 25961, 14407, 8032, 25708, 2288, 29245, 9957, 45164, 36764, 24401, 3660, 9154, 16095, 25961, 2655, 3714, 7435, 2304, 2407, 27884, 497], "avg_logprob": -0.17720171182670377, "compression_ratio": 1.7222222222222223, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 379.25, "end": 379.99, "word": "بالتأكيد", "probability": 0.8762613932291666}, {"start": 379.99, "end": 380.83, "word": " الماء", "probability": 0.94580078125}, {"start": 380.83, "end": 381.11, "word": " 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الإنسان يتكلم عن ال nitrogen اليوكليوفايل ال nitrogen اليوكليوفايل واضح يعني مش ضروري بس ال ammonia", "tokens": [3555, 1829, 19913, 1211, 14407, 45595, 2407, 28820, 1829, 38688, 995, 26895, 4032, 20193, 5296, 10721, 1975, 4117, 25708, 4032, 45164, 6055, 29399, 9957, 25961, 14407, 3714, 7435, 2304, 2407, 27884, 497, 4724, 1829, 19913, 1211, 14407, 45595, 2407, 28820, 1829, 38688, 995, 26895, 4032, 45164, 16712, 1211, 9307, 3660, 25961, 14407, 3714, 7435, 2304, 2407, 27884, 497, 39896, 19913, 1211, 14407, 45595, 2407, 28820, 1829, 38688, 995, 26895, 6156, 5016, 1829, 9381, 13546, 33688, 1863, 3794, 7649, 7251, 2655, 4117, 19528, 18871, 2423, 17903, 45595, 2407, 28820, 1829, 38688, 995, 26895, 2423, 17903, 45595, 2407, 28820, 1829, 38688, 995, 26895, 4032, 46958, 5016, 37495, 22653, 37893, 48812, 2288, 13063, 1829, 4724, 3794, 2423, 46833], "avg_logprob": -0.15099676004771528, "compression_ratio": 2.289772727272727, "no_speech_prob": 0.0, "words": [{"start": 398.18, "end": 398.68, "word": 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"probability": 0.9146484375}, {"start": 403.44, "end": 404.2, "word": " اليوكليوفايل", "probability": 0.96875}, {"start": 404.2, "end": 404.3, "word": " و", "probability": 0.8046875}, {"start": 404.3, "end": 404.46, "word": " لو", "probability": 0.9736328125}, {"start": 404.46, "end": 405.02, "word": " التلاتة", "probability": 0.84808349609375}, {"start": 405.02, "end": 405.32, "word": " كانوا", "probability": 0.948974609375}, {"start": 405.32, "end": 405.74, "word": " مجموعة", "probability": 0.93857421875}, {"start": 405.74, "end": 405.9, "word": " R", "probability": 0.9794921875}, {"start": 405.9, "end": 406.36, "word": " هيظلوا", "probability": 0.81695556640625}, {"start": 406.36, "end": 407.2, "word": " اليوكليوفايل", "probability": 0.9850725446428571}, {"start": 407.2, "end": 408.16, "word": " فحيصير", "probability": 0.89794921875}, {"start": 408.16, "end": 408.98, "word": " الإنسان", "probability": 0.93994140625}, {"start": 408.98, "end": 409.56, "word": " يتكلم", "probability": 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0.987060546875}, {"start": 417.0, "end": 417.34, "word": " ال", "probability": 0.8134765625}, {"start": 417.34, "end": 417.92, "word": " ammonia", "probability": 0.921875}], "temperature": 1.0}, {"id": 19, "seek": 44722, "start": 418.46, "end": 447.22, "text": "مش ضروري بس الأمونيا بنحكي عن ال nitrogen نيوكليوفايل سواء بتلاتة هيدروجين بدون ولا ار ار واحدة اتنين تلاتة كل هذه تعتبر عبارة عن ايش النيوكليوفايل الان بيفيدنا ان نعرف كيف النيوكليوفايل بيكون اقوى او اضعف من النيوكليوفايل التاني اللي بنسميه احنا ال strength of نيوكليوفايل", "tokens": [2304, 8592, 48812, 2288, 13063, 1829, 4724, 3794, 16247, 2304, 11536, 25528, 44945, 5016, 4117, 1829, 18871, 2423, 17903, 8717, 1829, 2407, 4117, 20292, 38688, 995, 26895, 8608, 2407, 16606, 39894, 1211, 9307, 3660, 8032, 25708, 2288, 29245, 9957, 47525, 11536, 49429, 1975, 2288, 1975, 2288, 36764, 24401, 3660, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 28242, 29538, 6055, 34268, 26890, 6225, 3555, 9640, 3660, 18871, 1975, 1829, 8592, 2423, 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427.4, "word": " اتنين", "probability": 0.71514892578125}, {"start": 427.4, "end": 428.16, "word": " تلاتة", "probability": 0.9744873046875}, {"start": 428.16, "end": 428.76, "word": " كل", "probability": 0.68408203125}, {"start": 428.76, "end": 429.12, "word": " هذه", "probability": 0.68994140625}, {"start": 429.12, "end": 430.04, "word": " تعتبر", "probability": 0.9529622395833334}, {"start": 430.04, "end": 430.46, "word": " عبارة", "probability": 0.9893798828125}, {"start": 430.46, "end": 430.66, "word": " عن", "probability": 0.9873046875}, {"start": 430.66, "end": 431.1, "word": " ايش", "probability": 0.7501627604166666}, {"start": 431.1, "end": 433.28, "word": " النيوكليوفايل", "probability": 0.777130126953125}, {"start": 433.28, "end": 434.56, "word": " الان", "probability": 0.7005615234375}, {"start": 434.56, "end": 436.26, "word": " بيفيدنا", "probability": 0.8770751953125}, {"start": 436.26, "end": 437.26, "word": " ان", "probability": 0.828125}, {"start": 437.26, "end": 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{"start": 1196.38, "end": 1196.58, "word": " ايش", "probability": 0.6214599609375}, {"start": 1196.58, "end": 1197.08, "word": " متعودين", "probability": 0.92724609375}, {"start": 1197.08, "end": 1197.26, "word": " طول", "probability": 0.983642578125}, {"start": 1197.26, "end": 1197.56, "word": " عمرنا", "probability": 0.9527994791666666}, {"start": 1197.56, "end": 1198.24, "word": " نقوله", "probability": 0.763671875}, {"start": 1198.24, "end": 1199.46, "word": " أكسيد", "probability": 0.68048095703125}, {"start": 1199.46, "end": 1200.2, "word": " زي", "probability": 0.810302734375}, {"start": 1200.2, "end": 1200.28, "word": " ما", "probability": 0.96142578125}, {"start": 1200.28, "end": 1200.62, "word": " بنقول", "probability": 0.91455078125}, {"start": 1200.62, "end": 1201.0, "word": " للأيون", "probability": 0.770751953125}, {"start": 1201.0, "end": 1201.42, "word": " السالب", "probability": 0.9816080729166666}, {"start": 1201.42, "end": 1202.48, "word": " كلورايد", "probability": 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اسمه صوديوم اث اكسايد لو كتبنالكوا صوديوم اث اكسايد ايش بدكم تحطوه CH3", "tokens": [10721, 2407, 4117, 3794, 995, 25708, 45164, 8717, 36081, 2288, 29245, 9957, 8608, 6027, 3555, 8717, 36081, 23557, 25708, 45164, 8608, 46538, 2288, 8608, 6027, 3555, 8608, 46538, 995, 25708, 2423, 7649, 45164, 1975, 15730, 42963, 4117, 3794, 7435, 9957, 8608, 6027, 3555, 1975, 12984, 2407, 4117, 1975, 12984, 1975, 4117, 3794, 1975, 1829, 1975, 12984, 1975, 4117, 3794, 995, 25708, 6225, 8592, 7649, 9122, 15730, 9673, 31747, 3555, 4724, 1829, 30544, 24525, 2304, 3224, 20328, 2407, 16254, 20498, 1975, 12984, 1975, 4117, 3794, 995, 25708, 45164, 9122, 2655, 3555, 8315, 23275, 14407, 20328, 2407, 16254, 20498, 1975, 12984, 1975, 4117, 3794, 995, 25708, 1975, 1829, 8592, 47525, 24793, 6055, 5016, 9566, 2407, 3224, 5995, 18], "avg_logprob": -0.24866451972570175, "compression_ratio": 2.1265060240963853, "no_speech_prob": 0.0, "words": [{"start": 1208.25, "end": 1209.09, "word": "أوكسايد", "probability": 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{"start": 1617.11, "end": 1617.69, "word": " cyanide", "probability": 0.894775390625}, {"start": 1617.69, "end": 1617.85, "word": " من", "probability": 0.98681640625}, {"start": 1617.85, "end": 1618.51, "word": " خلال", "probability": 0.9930013020833334}, {"start": 1618.51, "end": 1619.77, "word": " carbon", "probability": 0.232666015625}], "temperature": 1.0}, {"id": 69, "seek": 163765, "start": 1621.01, "end": 1637.65, "text": "من خلال الكربون مش النيتروجين واضح؟ طبعا النيتروجين بيبقى عليها زوج الالكترونات تبعها ف الـ CN- بتتحد مكان الهالوجين من خلال الكربون مش النيتروجين", "tokens": [27842, 16490, 1211, 6027, 33251, 25513, 11536, 37893, 2423, 22653, 2655, 2288, 29245, 9957, 4032, 46958, 5016, 22807, 23032, 3555, 3615, 995, 2423, 22653, 2655, 2288, 29245, 9957, 4724, 1829, 3555, 4587, 7578, 25894, 11296, 30767, 29245, 2423, 6027, 4117, 2655, 2288, 11536, 9307, 6055, 3555, 3615, 11296, 6156, 2423, 39184, 14589, 12, 39894, 2655, 24401, 3714, 41361, 2423, 3224, 6027, 29245, 9957, 9154, 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"word": " عليها", "probability": 0.88134765625}, {"start": 1627.69, "end": 1627.91, "word": " زوج", "probability": 0.955078125}, {"start": 1627.91, "end": 1628.71, "word": " الالكترونات", "probability": 0.7455357142857143}, {"start": 1628.71, "end": 1629.35, "word": " تبعها", "probability": 0.65386962890625}, {"start": 1629.35, "end": 1629.55, "word": " ف", "probability": 0.8828125}, {"start": 1629.55, "end": 1629.67, "word": " الـ", "probability": 0.3199462890625}, {"start": 1629.67, "end": 1629.91, "word": " CN", "probability": 0.406982421875}, {"start": 1629.91, "end": 1630.53, "word": "-", "probability": 0.2186279296875}, {"start": 1630.53, "end": 1631.79, "word": " بتتحد", "probability": 0.8365885416666666}, {"start": 1631.79, "end": 1632.83, "word": " مكان", "probability": 0.983642578125}, {"start": 1632.83, "end": 1633.59, "word": " الهالوجين", "probability": 0.87685546875}, {"start": 1633.59, "end": 1633.79, "word": " من", "probability": 0.9853515625}, {"start": 1633.79, "end": 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اللي مرت علينا substitution reactions استعرضناها بتوسع سواء من ناحية neutral enucleophiles أو من ناحية charged enucleophiles", "tokens": [30131, 372, 6518, 12215, 28242, 16247, 2304, 12984, 37977, 13672, 1829, 3714, 43500, 25894, 8315, 35827, 12215, 44713, 3615, 43042, 8315, 11296, 39894, 41779, 3615, 8608, 2407, 16606, 9154, 8717, 39319, 10632, 10598, 465, 1311, 306, 5317, 4680, 34051, 9154, 8717, 39319, 10632, 11109, 465, 1311, 306, 5317, 4680], "avg_logprob": -0.2092187488079071, "compression_ratio": 1.4657534246575343, "no_speech_prob": 0.0, "words": [{"start": 1699.41, "end": 1700.51, "word": "substitution", "probability": 0.5983072916666666}, {"start": 1700.51, "end": 1701.41, "word": " reactions", "probability": 0.80419921875}, {"start": 1701.41, "end": 1702.03, "word": " كل", "probability": 0.419189453125}, {"start": 1702.03, "end": 1702.77, "word": " الأمثلة", "probability": 0.923583984375}, {"start": 1702.77, "end": 1703.27, "word": " اللي", "probability": 0.61767578125}, 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{"start": 2456.2, "end": 2457.82, "word": " الاتين", "probability": 0.9182942708333334}, {"start": 2457.82, "end": 2458.18, "word": " مافيش", "probability": 0.9117838541666666}, {"start": 2458.18, "end": 2458.38, "word": " عليه", "probability": 0.9892578125}, {"start": 2458.38, "end": 2458.6, "word": " ولا", "probability": 0.95654296875}, {"start": 2458.6, "end": 2459.0, "word": " ابدال", "probability": 0.9606119791666666}, {"start": 2459.0, "end": 2459.2, "word": " ولا", "probability": 0.88916015625}, {"start": 2459.2, "end": 2459.86, "word": " هيدروجينة", "probability": 0.8980305989583334}, {"start": 2459.86, "end": 2460.18, "word": " ابدلة", "probability": 0.7716471354166666}, {"start": 2460.18, "end": 2460.42, "word": " هذا", "probability": 0.87060546875}, {"start": 2460.42, "end": 2460.68, "word": " كم", "probability": 0.951416015625}, {"start": 2460.68, "end": 2461.08, "word": " ابدال", "probability": 0.873046875}, {"start": 2461.08, "end": 2461.44, "word": " عليه", "probability": 0.9775390625}, {"start": 2461.44, "end": 2461.94, "word": " اتنين", "probability": 0.80035400390625}, {"start": 2461.94, "end": 2462.32, "word": " طيب", "probability": 0.7801106770833334}, {"start": 2462.32, "end": 2462.46, "word": " لو", "probability": 0.96630859375}, {"start": 2462.46, "end": 2462.96, "word": " قلتلكوا", "probability": 0.96396484375}, {"start": 2462.96, "end": 2463.28, "word": " هذا", "probability": 0.9755859375}, {"start": 2463.28, "end": 2464.12, "word": " المركب", "probability": 0.9736328125}, {"start": 2464.12, "end": 2464.7, "word": " ولا", "probability": 0.9228515625}, {"start": 2464.7, "end": 2465.38, "word": " هذا", "probability": 0.9814453125}], "temperature": 1.0}, {"id": 104, "seek": 249379, "start": 2466.33, "end": 2493.79, "text": "هذا كام إبدال عليه اللي جابله طب لو حطينا هنا كمان R أربعة which is more substituted واضح الفكرة إيش معنى more substituted كل ما صار عليه مجموعات R أكثر الآن لو إجينا و اتطلعنا على هدول التلان فصلولي حوالين ال double bond يعني قولوا هذه double bond هنا إيش موجود عندكم إبدلات؟ لا", "tokens": [3224, 15730, 9122, 10943, 11933, 44510, 6027, 47356, 13672, 1829, 10874, 16758, 43761, 23032, 3555, 45164, 11331, 9566, 1829, 8315, 34105, 9122, 2304, 7649, 497, 5551, 25513, 27884, 597, 307, 544, 26441, 4866, 4032, 46958, 5016, 27188, 4117, 25720, 11933, 1829, 8592, 20449, 1863, 7578, 544, 26441, 4866, 28242, 19446, 20328, 9640, 47356, 3714, 7435, 2304, 45367, 9307, 497, 5551, 4117, 49115, 6024, 48506, 45164, 11933, 7435, 1829, 8315, 4032, 1975, 2655, 9566, 1211, 3615, 8315, 15844, 8032, 3215, 12610, 16712, 1211, 7649, 6156, 36520, 12610, 1829, 11331, 2407, 6027, 9957, 2423, 3834, 6086, 37495, 22653, 12174, 12610, 14407, 29538, 3834, 6086, 34105, 11933, 1829, 8592, 3714, 29245, 23328, 43242, 24793, 11933, 44510, 1211, 9307, 22807, 20193], "avg_logprob": -0.20828919819856095, "compression_ratio": 1.6893939393939394, "no_speech_prob": 0.0, "words": [{"start": 2466.33, "end": 2466.75, "word": "هذا", "probability": 0.864013671875}, {"start": 2466.75, "end": 2467.03, "word": " كام", "probability": 0.519287109375}, {"start": 2467.03, "end": 2467.37, "word": " إبدال", "probability": 0.6920572916666666}, {"start": 2467.37, "end": 2467.71, "word": " عليه", "probability": 0.697265625}, {"start": 2467.71, "end": 2468.45, "word": " اللي", "probability": 0.5419921875}, {"start": 2468.45, "end": 2468.91, "word": " جابله", "probability": 0.8974609375}, {"start": 2468.91, "end": 2469.95, "word": " طب", "probability": 0.763427734375}, {"start": 2469.95, "end": 2470.07, "word": " لو", "probability": 0.9892578125}, {"start": 2470.07, "end": 2470.53, "word": " حطينا", "probability": 0.928955078125}, {"start": 2470.53, "end": 2470.71, "word": " هنا", "probability": 0.95556640625}, {"start": 2470.71, "end": 2471.11, "word": " كمان", "probability": 0.86669921875}, {"start": 2471.11, "end": 2471.49, "word": " R", "probability": 0.69677734375}, {"start": 2471.49, "end": 2472.87, "word": " أربعة", 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"word": " ما", "probability": 0.96044921875}, {"start": 2479.25, "end": 2479.49, "word": " صار", "probability": 0.947998046875}, {"start": 2479.49, "end": 2479.71, "word": " عليه", "probability": 0.97265625}, {"start": 2479.71, "end": 2480.33, "word": " مجموعات", "probability": 0.9830078125}, {"start": 2480.33, "end": 2480.53, "word": " R", "probability": 0.88134765625}, {"start": 2480.53, "end": 2480.89, "word": " أكثر", "probability": 0.9254557291666666}, {"start": 2480.89, "end": 2481.79, "word": " الآن", "probability": 0.661376953125}, {"start": 2481.79, "end": 2482.43, "word": " لو", "probability": 0.95654296875}, {"start": 2482.43, "end": 2483.07, "word": " إجينا", "probability": 0.83837890625}, {"start": 2483.07, "end": 2483.49, "word": " و", "probability": 0.95947265625}, {"start": 2483.49, "end": 2484.05, "word": " اتطلعنا", "probability": 0.8405354817708334}, {"start": 2484.05, "end": 2484.25, "word": " على", "probability": 0.90234375}, {"start": 2484.25, "end": 2484.65, "word": " هدول", "probability": 0.91162109375}, {"start": 2484.65, "end": 2485.17, "word": " التلان", "probability": 0.5888671875}, {"start": 2485.17, "end": 2486.15, "word": " فصلولي", "probability": 0.7208251953125}, {"start": 2486.15, "end": 2486.63, "word": " حوالين", "probability": 0.9111328125}, {"start": 2486.63, "end": 2486.75, "word": " ال", "probability": 0.90478515625}, {"start": 2486.75, "end": 2486.97, "word": " double", "probability": 0.8330078125}, {"start": 2486.97, "end": 2487.25, "word": " bond", "probability": 0.87939453125}, {"start": 2487.25, "end": 2487.47, "word": " يعني", "probability": 0.891845703125}, {"start": 2487.47, "end": 2487.73, "word": " قولوا", "probability": 0.8180338541666666}, {"start": 2487.73, "end": 2487.97, "word": " هذه", "probability": 0.54833984375}, {"start": 2487.97, "end": 2488.29, "word": " double", "probability": 0.9287109375}, {"start": 2488.29, "end": 2489.11, "word": " bond", "probability": 0.953125}, {"start": 2489.11, "end": 2490.01, "word": " هنا", "probability": 0.87109375}, {"start": 2490.01, "end": 2490.23, "word": " إيش", "probability": 0.9669596354166666}, {"start": 2490.23, "end": 2490.61, "word": " موجود", "probability": 0.9874674479166666}, {"start": 2490.61, "end": 2491.23, "word": " عندكم", "probability": 0.9921875}, {"start": 2491.23, "end": 2493.29, "word": " إبدلات؟", "probability": 0.7486328125}, {"start": 2493.29, "end": 2493.79, "word": " لا", "probability": 0.6025390625}], "temperature": 1.0}, {"id": 105, "seek": 252559, "start": 2496.79, "end": 2525.59, "text": "و هان H هذي اللي شطبناها و هان K إذا هذا لو بدكوا تقارنوه بال إثليين كام إفدال عليه حقيقة؟ واحد لو هذه تنشر و تصير H بيبطل مبدل إذا هذا كام إفدال عليه؟ واحد طب لو إجيت على المركب التاني هاي ال double bond هنا إيش في عندكم؟ H و هنا فصلتهم", "tokens": [2407, 8032, 7649, 389, 8032, 8848, 1829, 13672, 1829, 13412, 9566, 3555, 8315, 11296, 4032, 8032, 7649, 591, 11933, 15730, 23758, 45164, 47525, 4117, 14407, 6055, 4587, 9640, 1863, 2407, 3224, 20666, 11933, 12984, 20292, 9957, 9122, 10943, 11933, 5172, 3215, 6027, 47356, 11331, 38436, 28671, 22807, 36764, 24401, 45164, 29538, 6055, 1863, 46309, 4032, 6055, 9381, 13546, 389, 4724, 1829, 3555, 9566, 1211, 3714, 44510, 1211, 11933, 15730, 23758, 9122, 10943, 11933, 5172, 3215, 6027, 47356, 22807, 36764, 24401, 23032, 3555, 45164, 11933, 7435, 36081, 15844, 9673, 31747, 3555, 16712, 7649, 1829, 8032, 47302, 2423, 3834, 6086, 34105, 11933, 1829, 8592, 8978, 43242, 24793, 22807, 389, 4032, 34105, 6156, 36520, 2655, 16095], "avg_logprob": -0.2812500028756627, "compression_ratio": 1.8133333333333332, "no_speech_prob": 0.0, "words": [{"start": 2496.79, "end": 2497.03, "word": "و", "probability": 0.82177734375}, {"start": 2497.03, "end": 2497.81, "word": " هان", "probability": 0.341796875}, {"start": 2497.81, "end": 2498.97, "word": " H", "probability": 0.59423828125}, {"start": 2498.97, "end": 2499.37, "word": " هذي", "probability": 0.563720703125}, {"start": 2499.37, "end": 2499.49, "word": " اللي", "probability": 0.954345703125}, {"start": 2499.49, "end": 2500.15, "word": " شطبناها", "probability": 0.97001953125}, {"start": 2500.15, "end": 2500.37, "word": " و", "probability": 0.7099609375}, {"start": 2500.37, "end": 2500.85, "word": " هان", "probability": 0.7802734375}, {"start": 2500.85, "end": 2501.93, "word": " K", "probability": 0.2235107421875}, {"start": 2501.93, "end": 2502.77, "word": " إذا", "probability": 0.6068115234375}, {"start": 2502.77, "end": 2503.13, "word": " هذا", "probability": 0.826171875}, {"start": 2503.13, "end": 2503.29, "word": " لو", "probability": 0.95654296875}, {"start": 2503.29, "end": 2503.57, "word": " بدكوا", "probability": 0.7752278645833334}, {"start": 2503.57, "end": 2504.07, "word": " تقارنوه", "probability": 0.8418986002604166}, {"start": 2504.07, "end": 2504.23, "word": " بال", "probability": 0.349609375}, {"start": 2504.23, "end": 2505.29, "word": " إثليين", "probability": 0.47015380859375}, {"start": 2505.29, "end": 2505.85, "word": " كام", "probability": 0.822998046875}, {"start": 2505.85, "end": 2506.29, "word": " إفدال", "probability": 0.9415283203125}, {"start": 2506.29, "end": 2506.57, "word": " عليه", "probability": 0.9765625}, {"start": 2506.57, "end": 2507.57, "word": " حقيقة؟", "probability": 0.7452392578125}, {"start": 2507.57, "end": 2507.91, "word": " واحد", "probability": 0.972900390625}, {"start": 2507.91, "end": 2509.77, "word": " لو", "probability": 0.5302734375}, {"start": 2509.77, "end": 2510.07, "word": " هذه", "probability": 0.56982421875}, {"start": 2510.07, "end": 2510.47, "word": " تنشر", "probability": 0.7688802083333334}, {"start": 2510.47, "end": 2510.59, "word": " و", "probability": 0.39453125}, {"start": 2510.59, "end": 2510.83, "word": " تصير", "probability": 0.9757486979166666}, {"start": 2510.83, "end": 2511.05, "word": " H", "probability": 0.9228515625}, {"start": 2511.05, "end": 2511.61, "word": " بيبطل", "probability": 0.91796875}, {"start": 2511.61, "end": 2512.15, "word": " مبدل", "probability": 0.8056640625}, {"start": 2512.15, "end": 2513.59, "word": " إذا", "probability": 0.91357421875}, {"start": 2513.59, "end": 2513.89, "word": " هذا", "probability": 0.9091796875}, {"start": 2513.89, "end": 2514.13, "word": " كام", "probability": 0.9765625}, {"start": 2514.13, "end": 2514.55, "word": " إفدال", "probability": 0.986083984375}, {"start": 2514.55, "end": 2515.41, "word": " عليه؟", "probability": 0.96240234375}, {"start": 2515.41, "end": 2516.07, "word": " واحد", "probability": 0.987060546875}, {"start": 2516.07, "end": 2516.55, "word": " طب", "probability": 0.867919921875}, {"start": 2516.55, "end": 2516.73, "word": " لو", "probability": 0.9892578125}, {"start": 2516.73, "end": 2517.11, "word": " إجيت", "probability": 0.7591959635416666}, {"start": 2517.11, "end": 2517.27, "word": " على", "probability": 0.51708984375}, {"start": 2517.27, "end": 2517.85, "word": " المركب", "probability": 0.7941080729166666}, {"start": 2517.85, "end": 2518.45, "word": " التاني", "probability": 0.9583333333333334}, {"start": 2518.45, "end": 2518.85, "word": " هاي", "probability": 0.4986572265625}, {"start": 2518.85, "end": 2518.97, "word": " ال", "probability": 0.9033203125}, {"start": 2518.97, "end": 2519.19, "word": " double", "probability": 0.78564453125}, {"start": 2519.19, "end": 2519.65, "word": " bond", "probability": 0.93994140625}, {"start": 2519.65, "end": 2520.29, "word": " هنا", "probability": 0.4375}, {"start": 2520.29, "end": 2520.53, "word": " إيش", "probability": 0.8525390625}, {"start": 2520.53, "end": 2520.67, "word": " في", "probability": 0.96533203125}, {"start": 2520.67, "end": 2522.05, "word": " عندكم؟", "probability": 0.9430338541666666}, {"start": 2522.05, "end": 2522.57, "word": " H", "probability": 0.76513671875}, {"start": 2522.57, "end": 2522.79, "word": " و", "probability": 0.59619140625}, {"start": 2522.79, "end": 2523.05, "word": " هنا", "probability": 0.84326171875}, {"start": 2523.05, "end": 2525.59, "word": " فصلتهم", "probability": 0.74749755859375}], "temperature": 1.0}, {"id": 106, "seek": 255094, "start": 2526.37, "end": 2550.95, "text": "وهنا تطلعوا إيش في عندكم؟ carbon إذا هذه مقدلة وهنا carbon إذا هذا كام إبدال؟ اتنين which is more substituted ال two butyl is more substituted than one butyl فهذا اللي بيكون major product شوفته كيف؟", "tokens": [2407, 3224, 8315, 6055, 9566, 1211, 3615, 14407, 11933, 1829, 8592, 8978, 43242, 24793, 22807, 5954, 11933, 15730, 29538, 3714, 28543, 37977, 4032, 3224, 8315, 5954, 11933, 15730, 23758, 9122, 10943, 11933, 44510, 6027, 22807, 1975, 2655, 1863, 9957, 597, 307, 544, 26441, 4866, 2423, 732, 457, 5088, 307, 544, 26441, 4866, 813, 472, 457, 5088, 6156, 3224, 15730, 13672, 1829, 4724, 1829, 30544, 2563, 1674, 13412, 38688, 47395, 9122, 33911, 22807], "avg_logprob": -0.2079409213915263, "compression_ratio": 1.4787234042553192, "no_speech_prob": 0.0, "words": [{"start": 2526.37, "end": 2527.09, "word": "وهنا", "probability": 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halides ال RX يمكن أخذنا فكرة عن + +3 +00:00:31,090 --> 00:00:37,450 +المراكبات وتسميتها وربما البعض بيذكر قوة الرابط + +4 +00:00:37,450 --> 00:00:42,990 +اللي ما بين ال R و ال X وقلنا بشكل عام رابطة مع ال + +5 +00:00:42,990 --> 00:00:49,410 +fluorine رابطة قوية وبالتالي مابتمش عمليةكسر سهل + +6 +00:00:49,410 --> 00:00:54,410 +خلينا نقول لهذه الرابطة ما عدا ذلك اليود و البروم + +7 +00:00:54,410 --> 00:01:00,050 +و الكلور ممكن كسر الرابطة و أسهل ما تكون مع اليود + +8 +00:01:00,050 --> 00:01:06,630 +رابطة إيش معاها بعيفة فأتكلمنا قولنا إنه في ال + +9 +00:01:06,630 --> 00:01:11,450 +الكلهيليتز التفاعل الأساسي إما تفاعل إبدالي يعني + +10 +00:01:11,450 --> 00:01:15,610 +نشيل ال halogen و ال halogen في كل الأحوال بدأ + +11 +00:01:16,660 --> 00:01:21,680 +تنشال مع إلكتروناتها ونحط مكانها نيوكليوفايل مع + +12 +00:01:21,680 --> 00:01:26,740 +إلكتروناته يعني كأنه أبدلنا شيء سالب شيء سالب هذه + +13 +00:01:26,740 --> 00:01:32,340 +تقريبا أخر نقطة اتكلمنا عنها المرة الماضيةالان + +14 +00:01:32,340 --> 00:01:39,640 +بالنسبة لل nucleophiles اللى هى تمثل نص التفاعل + +15 +00:01:39,640 --> 00:01:44,060 +يعنى هذا التفاعل لو احنا بدنا نفهمه هو مكوّن من + +16 +00:01:44,060 --> 00:01:52,360 +شقين مكوّن من alkyl halide RX ومكوّن من اشمن الـ + +17 +00:01:52,360 --> 00:01:57,240 +nucleophile فالذي يفهم التفاعل جيدا يكون يعرف ال + +18 +00:01:57,240 --> 00:02:01,540 +الهيلايتز و أخذنا فكرة عنهم و عن أنواعهم و عن قوة + +19 +00:02:01,540 --> 00:02:05,420 +الرابط فيهم قلنا أسهل شيء التفاعل مع المراكبات + +20 +00:02:05,420 --> 00:02:10,200 +اللي فيها اليود أكثر من .. الآن بلزمنا أيضا نتعرف + +21 +00:02:10,200 --> 00:02:14,600 +على ال nucleophiles واضح؟ يعني لما بيكون في صراع + +22 +00:02:14,600 --> 00:02:17,850 +على سبيل المثال بين دولتينالذين يريدون أن يفهموا + +23 +00:02:17,850 --> 00:02:21,270 +الأمر جيدا يريدون أن يفهموا الدولتين وقوة + +24 +00:02:21,270 --> 00:02:24,150 +الدولتين، والذين يريدون أن يفهموا التفاعل جيدا + +25 +00:02:24,150 --> 00:02:28,530 +يريدون أن يكونوا عارف الـAlkyl Halides وخواصة وكيف + +26 +00:02:28,530 --> 00:02:34,310 +تتفاعل ويعرفلنيوكليوفايل احنا بدنا المرة الماضية + +27 +00:02:34,310 --> 00:02:37,810 +حكينا عن ال الكلهيلايت تصنيفاتها ل primary و + +28 +00:02:37,810 --> 00:02:42,170 +secondary و tertiary ان ال X ممكن تكون يودي برومي + +29 +00:02:42,170 --> 00:02:46,110 +كلور كل المعلومات هذه شرحناها بخصوص ال الكلهيلايت + +30 +00:02:46,110 --> 00:02:50,490 +اذا اليوم هيكون جزء من الكلام اللى هنبدأ فيه ان + +31 +00:02:50,490 --> 00:02:56,070 +نتعرف على نيوكليوفايل طبعا سبق اننا قلنا ايش معنى + +32 +00:02:56,070 --> 00:03:02,570 +نيوكليوفايل بكل الأحوال نيوكليوفايلعبارة عن جزء او + +33 +00:03:02,570 --> 00:03:08,490 +ايون مش مشكلة اهمه يميزه ايش زوج الالكترونات + +34 +00:03:08,490 --> 00:03:14,060 +لاحظوا انتوا قلتوا سالب انا ماقلتش سالبمش الزام + +35 +00:03:14,060 --> 00:03:20,500 +انه لليوكليوفايل يكون سالب لليوكليوفايل يميزه وجود + +36 +00:03:20,500 --> 00:03:25,240 +الزوج الإلكترونات غير الرابط واضح؟ أزواج + +37 +00:03:25,240 --> 00:03:30,000 +الإلكترونات الحرة هي اللي بتميزه الآن لليوكليوفايل + +38 +00:03:30,000 --> 00:03:35,720 +ضمن هذا التعريف يمكن أن يكون متعادلا ويمكن أن يكون + +39 +00:03:35,720 --> 00:03:39,880 +مشحونا إذا كان مشحون هيكون مشحون بشحنه سالبةيعني + +40 +00:03:39,880 --> 00:03:45,120 +مثلا ال O H في مركب زي ال N A O H يعني مافيش O H + +41 +00:03:45,120 --> 00:03:49,940 +minus بتلبع و بتنشر لحالها مافيش أيونات بتلبع و + +42 +00:03:49,940 --> 00:03:54,020 +بتنشر لحالها عادة المركبات ايش بتكون متعادلة يعني + +43 +00:03:54,020 --> 00:03:59,540 +يوم بقول O H minus كأن انا بقولن او اتش او + +44 +00:03:59,540 --> 00:04:04,460 +بوتاسيوم هيدروكسيد او اي شئ لكن انا مهتم الآن بال + +45 +00:04:04,460 --> 00:04:08,900 +O H جزء ال O H هو اللي هيتفاعل معاه الان هذا ال O + +46 +00:04:08,900 --> 00:04:13,060 +H هيتوزيع الالكتروني لو حسب الشحن على ال oxygen + +47 +00:04:13,060 --> 00:04:18,780 +بلاحظ انه minus وبناء على ذلك بقول ان ال O H minus + +48 +00:04:18,780 --> 00:04:24,440 +is a charged nucleophile نيوكليوفال مشحون كذلك + +49 +00:04:24,440 --> 00:04:29,300 +الحال ال CN minusتشارج الـ nucleophile بنبيع لحاله + +50 +00:04:29,300 --> 00:04:34,520 +أكيد لأ بنشتريه بنستعمله مثلا ع شكل potassium + +51 +00:04:34,520 --> 00:04:39,460 +cyanide واضح هذا المركب السام و الخطير اللي عادة + +52 +00:04:39,460 --> 00:04:44,140 +بنسمحش الناس تستعمله في المختبر بدون رقابة لأنه لو + +53 +00:04:44,140 --> 00:04:49,700 +طلع كميات صغيرة من ال HCN الناس اتعاملت معه تتسمم + +54 +00:04:49,700 --> 00:04:53,940 +و يؤدي إلى وفاة سريعة جدا يعني خلال دقيقة أو + +55 +00:04:53,940 --> 00:04:58,340 +دقيقتين فمستقبلكملو جيتوا تشتغلوا مع potassium + +56 +00:04:58,340 --> 00:05:02,640 +cyanide مع potassium cyanide بدكوا حذر بدوا ناس + +57 +00:05:02,640 --> 00:05:05,860 +يكونوا معاكوا في المختبر يعلموكوا كيف تشتغلوا + +58 +00:05:05,860 --> 00:05:10,240 +بخزانة أبخرة إنما واحدة حاطة potassium cyanide + +59 +00:05:10,240 --> 00:05:17,650 +وكبت عليه شوية HCl طلع HCl غاز شمتهبكون عندها + +60 +00:05:17,650 --> 00:05:20,830 +دقيقتين تتشاهد و تقول لا إله إلا الله مش أكثر من + +61 +00:05:20,830 --> 00:05:26,310 +هذا واضح النقطة فبدنا نلتبه الخلاصة في كل الأحوال + +62 +00:05:26,310 --> 00:05:32,750 +أن هذه الـcharged uq files عادة هي عبارة عن مركبات + +63 +00:05:32,750 --> 00:05:37,500 +أيونيةفيها ايون موجب و ايون سالب الان احنا اللي + +64 +00:05:37,500 --> 00:05:41,680 +بدى يتفاعل عندنا ايش الايون السالب و عشان هيك + +65 +00:05:41,680 --> 00:05:45,520 +بنذكره لحاله يعني عادة مابفرجش عندى لو كان هذا + +66 +00:05:45,520 --> 00:05:49,680 +potassium cyanide ولا sodium cyanide مثلا ولا ايش + +67 +00:05:49,680 --> 00:05:55,010 +ماكان يكون انا مهتمبالـ Ion الساني هذا بالنسبة + +68 +00:05:55,010 --> 00:05:57,950 +للنوع الأول من الـ nucleophiles اللي هو الـ + +69 +00:05:57,950 --> 00:06:02,010 +charged nucleophiles النوع التاني الـ neutral + +70 +00:06:02,010 --> 00:06:06,570 +nucleophiles الـ neutral nucleophiles مثلا الماء + +71 +00:06:06,570 --> 00:06:11,950 +شايفين فيه عادة رابطتين وزوجين من الإلكترونات إذا + +72 +00:06:11,950 --> 00:06:16,550 +ممكن يهاجم على الـ Alkyl Halide من خلال زوج + +73 +00:06:16,550 --> 00:06:21,830 +الإلكترونات هذا ويتفاعل معهبالتأكيد الماء هنا يمثل + +74 +00:06:21,830 --> 00:06:25,950 +الـ neutral الـ nucleophile الأمونيا على سبيل + +75 +00:06:25,950 --> 00:06:29,730 +المثال الـ neutral الـ nucleophile الان لو كان + +76 +00:06:29,730 --> 00:06:33,310 +عندي substituted أمونيا يعني بدل ما الثلاث ذرات + +77 +00:06:33,310 --> 00:06:37,530 +هدول كانوا هيدروجين لو واحدة منهم كانت مجموعة R + +78 +00:06:38,180 --> 00:06:42,160 +بيظلوا اليوكليوفايل و لا لأ اكيد و لو تنتين كانوا + +79 +00:06:42,160 --> 00:06:45,320 +مجموعة R بيظلوا اليوكليوفايل و لو التلاتة كانوا + +80 +00:06:45,320 --> 00:06:49,560 +مجموعة R هيظلوا اليوكليوفايل فحيصير الإنسان يتكلم + +81 +00:06:49,560 --> 00:06:53,680 +عن ال nitrogen اليوكليوفايل ال nitrogen + +82 +00:06:53,680 --> 00:06:58,760 +اليوكليوفايل واضح يعني مش ضروري بس ال ammoniaمش + +83 +00:06:58,760 --> 00:07:02,620 +ضروري بس الأمونيا بنحكي عن ال nitrogen نيوكليوفايل + +84 +00:07:02,620 --> 00:07:07,400 +سواء بتلاتة هيدروجين بدون ولا ار ار واحدة اتنين + +85 +00:07:07,400 --> 00:07:14,560 +تلاتة كل هذه تعتبر عبارة عن ايش النيوكليوفايل الان + +86 +00:07:14,560 --> 00:07:21,000 +بيفيدنا ان نعرف كيف النيوكليوفايل بيكون اقوى او + +87 +00:07:21,000 --> 00:07:25,320 +اضعف من النيوكليوفايل التاني اللي بنسميه احنا ال + +88 +00:07:25,320 --> 00:07:30,530 +strength of نيوكليوفايلو هذا أمر دائما بيسأل + +89 +00:07:30,530 --> 00:07:34,150 +الطالب عنه يعني بنقوله أي ال eucleophile أقوى ألف + +90 +00:07:34,150 --> 00:07:39,550 +ولا با هذا ولا هذا في عندنا قواعد عامة القاعدة + +91 +00:07:39,550 --> 00:07:46,240 +الأولى بتقول إذا أنا بأقارنتشارج النيوكليوفايل + +92 +00:07:46,240 --> 00:07:51,540 +يحمل شحنة سالبة بنيوترال نيوكليوفايل دائما و أبدا + +93 +00:07:51,540 --> 00:07:55,480 +تشارج النيوكليوفايل أقوى من النيوترال يعني مثلا + +94 +00:07:55,480 --> 00:08:02,600 +انقارن ال OH- مع الميه مين الأقوى؟ انقارن ال + +95 +00:08:02,600 --> 00:08:08,760 +ethanol O- مع الاثانول مين الأقوى؟الـ ethyl O-, + +96 +00:08:08,760 --> 00:08:15,980 +الـ NH2- مع الـ NH3 من الأقوى، إذا دائما الـ + +97 +00:08:15,980 --> 00:08:20,660 +nucleophile اللي بيحمل شحنة سالبة، الـ charged + +98 +00:08:20,660 --> 00:08:25,000 +nucleophile are stronger than neutral nucleophile + +99 +00:08:25,000 --> 00:08:29,880 +واضح هذا الكلام؟ charged nucleophile are stronger + +100 +00:08:29,880 --> 00:08:36,120 +than neutral nucleophileطيب بيجينا السؤال لو بقارن + +101 +00:08:36,120 --> 00:08:41,920 +انا enucleophile مشحون مع مشحون او متعادل مع + +102 +00:08:41,920 --> 00:08:46,180 +متعادل واضح الفكرة اذا انا بعمل مقارنة ل + +103 +00:08:46,180 --> 00:08:51,340 +enucleophile مشحونومشحون او متعادل و متعادل مين + +104 +00:08:51,340 --> 00:08:56,920 +بيكون الاقوى الان هنا بلزمنا نتذكر شوية الجدول + +105 +00:08:56,920 --> 00:09:00,580 +الدوري كيف العناصر مرتبة في الجدول الدوري في + +106 +00:09:00,580 --> 00:09:04,140 +الجدول الدوري كلكم عارفين المهمين عند الكاربون + +107 +00:09:04,140 --> 00:09:10,230 +نيتروجين اكسوجينfloricloribromide الان قوة + +108 +00:09:10,230 --> 00:09:17,530 +اليوكليوفايدز بتزيد حسب السهم بتزيد بهذا الاتجاه و + +109 +00:09:17,530 --> 00:09:22,670 +بتزيد بهذا الاتجاه واضح؟ + +110 +00:09:23,960 --> 00:09:28,600 +فلو أنا بدأ أعمل عدة مقارنات و الأسهم هذه موجودة + +111 +00:09:28,600 --> 00:09:33,240 +قدامي، على طول بقدر أتخذ قرار، يعني مثلا لو بدأ + +112 +00:09:33,240 --> 00:09:37,100 +أقارن الأمونيا طبعا فيها إلكترونات و الميه فيها + +113 +00:09:37,100 --> 00:09:41,860 +إلكترونات أزواج، الأمونيا مع الميه، الأمونيا ذرتها + +114 +00:09:41,860 --> 00:09:47,260 +النيتروجين، الميه الوكسوجين، which is stronger؟ + +115 +00:09:47,260 --> 00:09:52,760 +الأمونياواضح؟ لحظوا هذا neutral و هذا neutral طب + +116 +00:09:52,760 --> 00:09:57,560 +لو أخدت منهم ال charge يعني أخدت من هنا حذفت H + +117 +00:09:57,560 --> 00:10:01,080 +plus صار ال ion ال minus ال NH2 minus و من هنا + +118 +00:10:01,080 --> 00:10:06,720 +حذفت H plus صار ال OH minus مشحون مع مشحون أيضا + +119 +00:10:06,720 --> 00:10:10,500 +مين بده يكون الأقوى ال NH2 minus أقوى من ال OH + +120 +00:10:10,500 --> 00:10:17,460 +minus واضح؟ الآن طب لو مشينا حسب المجموعة تحت ال + +121 +00:10:17,460 --> 00:10:22,360 +oxygen إيش في عنده؟الـ Sulphur لو بدأ أقارن الـ + +122 +00:10:22,360 --> 00:10:27,560 +H2S مع الـ H2O هاي مركّب Sulphur مركّب واسمه الـ + +123 +00:10:27,560 --> 00:10:31,380 +H2S أقوى، هذا نيوترال، هذا نيوترال طب لو بدأ أقارن + +124 +00:10:31,380 --> 00:10:39,340 +الـ SH-, الأيون السالب من هذا مع الـ OH-, الـ SH-, + +125 +00:10:39,340 --> 00:10:43,540 +لو بدأ أقارن اليود مع البروم، بدأ أقارن البروم مع + +126 +00:10:43,540 --> 00:10:48,930 +الكلورو هكذا واضح فال strength of nucleophiles + +127 +00:10:48,930 --> 00:10:54,530 +بيكون له كام قاعدة تلاتة القاعدة الأولى المشحون + +128 +00:10:54,530 --> 00:10:58,290 +أقوى من المتعدل القاعدة التانية إذا كنا بنحكي عن + +129 +00:10:58,290 --> 00:11:02,850 +عناصر بنفس الدورة بدنا نمشي بهذا الاتجاه بيكون + +130 +00:11:02,850 --> 00:11:05,850 +أقوى لل nucleophile القاعدة التالتة إذا بحكي عن + +131 +00:11:05,850 --> 00:11:11,490 +عناصر بنفس المجموعة بدأ أمشي بهذا الاتجاه واضح + +132 +00:11:11,490 --> 00:11:11,970 +الكلام + +133 +00:11:16,040 --> 00:11:22,200 +بهيك بيصير عندنا فكرة عن ال alkyl halides لوحدها و + +134 +00:11:22,200 --> 00:11:27,560 +أنواعها و بيصير عندنا فكرة عن ال nucleophiles الان + +135 +00:11:27,560 --> 00:11:32,040 +بدنا نعمل تفاعل ما بين ال alkyl halide و ال + +136 +00:11:32,040 --> 00:11:38,970 +nucleophileخلّينا نحط فرضية ان احنا بدين ب general + +137 +00:11:38,970 --> 00:11:45,330 +reaction يعني نقول ال الهلايد بشكل عام RX هذا ال + +138 +00:11:45,330 --> 00:11:52,010 +RX شو بده يفقد؟الـ X الهالوجين النيكليوفايلز أنواع + +139 +00:11:52,010 --> 00:11:57,150 +كتيرة من أشهر أنواع النيكليوفايلز اللي بنسميها ال + +140 +00:11:57,150 --> 00:12:03,030 +oxygen نيكليوفايلز اللي فيها أكسوجين و ال أكسوجين + +141 +00:12:03,030 --> 00:12:10,410 +عادة إما بيكون متعادل أو مشحون بالمتعادل بيكون + +142 +00:12:10,410 --> 00:12:17,260 +عليه رابطتين و زوجين إلكترونات بالمشحونبيكون فيه + +143 +00:12:17,260 --> 00:12:22,220 +رابطة واحدة و تلت أزواج، إلكترونات زي ما أجي أقول + +144 +00:12:22,220 --> 00:12:29,140 +الميّه، لاحظوا الميّه، هاي ال Oxygen، H و H، كام + +145 +00:12:29,140 --> 00:12:34,710 +رابطة شايفين؟تنتين، كم زوج إلكترونات؟ إتنين، الآن + +146 +00:12:34,710 --> 00:12:40,150 +لو بدي منها المشحون، بتكون OH كام رابطة شايفين؟ + +147 +00:12:40,150 --> 00:12:44,950 +كام زوج إلكترونات هنا؟ تلاتة، في هذه الحالة، هذا + +148 +00:12:44,950 --> 00:12:51,430 +النيكليوفايل بيكون مشحونكذلك الحال مع الـ Nitrogen + +149 +00:12:51,430 --> 00:12:56,390 +الـ Nucleophile تلت روابط وزوج إلكترونات بيكون + +150 +00:12:56,390 --> 00:13:00,290 +عبارة عن الـ Neutral Nucleophile لو شيلنا منه + +151 +00:13:00,290 --> 00:13:04,450 +هيدروجينة و خلناها رابطتين و زوجين إلكترونات، + +152 +00:13:04,450 --> 00:13:10,100 +بيصير إيش؟Charged Nucleophile والسلفر زيه تماما زي + +153 +00:13:10,100 --> 00:13:16,200 +ال Oxygen الآن لما بنجي نعمل تفاعل ها اننا RX + +154 +00:13:16,200 --> 00:13:22,180 +اجينا نفعله مع ال OH- كيف بدنا نعمل المعادلة + +155 +00:13:22,180 --> 00:13:29,700 +تبعتنا بدنا ببساطة نشيل ال X مع إلكتروناتها ونحط + +156 +00:13:29,700 --> 00:13:37,550 +محلها ال OHواضح؟ بدنا نشيل ال X مع إلكتروناتها + +157 +00:13:37,550 --> 00:13:41,130 +ونحط محالة ال O H ولذلك لما أنا بفعل RX مع O H + +158 +00:13:41,130 --> 00:13:47,130 +minus إيش الناتج الأساسي ال organic product؟ R O H + +159 +00:13:47,130 --> 00:13:55,450 +طبعا أكيد طلع عندى ال X minus هل يا ترى ال X minus + +160 +00:13:55,450 --> 00:14:00,530 +بيضطر لتسبح بالفراغ لحالها؟ قامين تقولنا إيش بتعمل + +161 +00:14:00,530 --> 00:14:07,850 +ال X minus؟ما هو أنا أساسا ال OHK هذي في معها N A + +162 +00:14:07,850 --> 00:14:17,730 +N A plus R الان هتطلع N A plus Xواضح؟ يعني اللي + +163 +00:14:17,730 --> 00:14:22,570 +كان ايون موجة مرافق لل OH بيصير ايون موجة مرافق لل + +164 +00:14:22,570 --> 00:14:28,190 +X احنا بشكل عام الأشياء ما عدا ال organic products + +165 +00:14:28,190 --> 00:14:31,190 +مش مهمة عندنا يعني دائما لما نقولكوا أكمل معادلة + +166 +00:14:31,190 --> 00:14:35,030 +في الكيميا العضوية و اكتبولنا ناتج العضوية الأشياء + +167 +00:14:35,030 --> 00:14:40,390 +التانية تحصيل حاصل مش مهمة فبالان لو اجينا عملنا + +168 +00:14:40,390 --> 00:14:45,210 +التفاعل مع ميّه ايش بدو يكون الناتج نفس ال RX مع + +169 +00:14:45,210 --> 00:14:49,640 +الميّهلاحظوا الميه لما تتفاعل من خلال أحد أزواج + +170 +00:14:49,640 --> 00:14:53,740 +الإلكترونات أول ما تتفاعل هذا أزواج الإلكترونات + +171 +00:14:53,740 --> 00:15:01,540 +هيعمل رابطة هيصير عند R O H 2 لأن الميه H2O هيصير + +172 +00:15:01,540 --> 00:15:06,340 +عند R O H 2 لو حسبناها لشوحنا بتكون موجبة مباشرة + +173 +00:15:06,340 --> 00:15:18,740 +بتفقد H بلس بيصف الناتج R O Hإذا ناتج إضافة الميّه + +174 +00:15:18,740 --> 00:15:25,900 +زي ناتج إضافة الـ OH- تماماً و كل نيوترال + +175 +00:15:25,900 --> 00:15:30,260 +نيوكليوفايل .. الآن بنسجلها قاعدة .. كل نيوترال + +176 +00:15:30,260 --> 00:15:34,950 +نيوكليوفايل .. لما بنحط نتيجة تفاعلهبدو يكون فقط + +177 +00:15:34,950 --> 00:15:41,450 +ايش H plus يعني الميه H2O لما بتبين في الناتج شو + +178 +00:15:41,450 --> 00:15:46,150 +بيبين منها OH طيب لو كنا بنشتغل على أمونيا بعد + +179 +00:15:46,150 --> 00:15:52,980 +شوية and H3لما تبين في ناتج النهائي، شو هتبين؟ الـ + +180 +00:15:52,980 --> 00:16:00,420 +H2 و هكذا كل نيوترال نيوكليوفايل بيكون عليه H عادة + +181 +00:16:00,420 --> 00:16:06,820 +لما تحطه ناتجه النهائي، بتشيله منه H مثلا، لو كنا + +182 +00:16:06,820 --> 00:16:13,200 +بنحكي عن ROHطبعا وين مركز الـ nucleophile في الـ + +183 +00:16:13,200 --> 00:16:18,960 +ROH؟ أي ضربة الـ O اللي عليها أزواج إلكترونات هذه + +184 +00:16:18,960 --> 00:16:24,580 +الـ O هي نفسها اللي هتيجي تحل محل ال X وانتبهوا + +185 +00:16:24,580 --> 00:16:28,420 +معاه أي نقطة اللي بدها تهاجم اللي هي مركز ال + +186 +00:16:28,420 --> 00:16:34,340 +nucleophile وين بدها تيجي تحل بالظبط؟ محل ال X مش + +187 +00:16:34,340 --> 00:16:39,770 +if ما كان تاني خلينيأعطيكم الكلام بمثال لأن أحيانا + +188 +00:16:39,770 --> 00:16:44,250 +في التطبيق بنلاحظ أنه بيصير عندكم مشكلة يعني مثلا + +189 +00:16:44,250 --> 00:16:50,150 +لو أنتوا لاحظته أنه عندكم مركب زي هذا المركب وفيه + +190 +00:16:50,150 --> 00:16:56,050 +PR مركب زي هذا المركب وفيه PR وإجينا قلنالكم + +191 +00:16:56,050 --> 00:17:02,190 +فعلونا يا مع CH3 CH2 OH + +192 +00:17:05,070 --> 00:17:10,150 +واضح؟ ايش اللي بدنا نشيله؟ ايش اللي بدنا نحط محله؟ + +193 +00:17:10,150 --> 00:17:15,590 +هذا المركب لكن من وين بدنا نشبكه؟ من أزواج + +194 +00:17:15,590 --> 00:17:19,230 +الإلكترونات اللي على ال O هذا بصفته نيوترا للـ + +195 +00:17:19,230 --> 00:17:24,570 +nucleophile شو هيفقد؟ ال H إذا لما أنا بدى أرسم + +196 +00:17:24,570 --> 00:17:33,470 +هنا الناتج هيكون عندي O CH2 + +197 +00:17:36,880 --> 00:17:43,280 +CH3 واضح فال نيوكليوفايل الرأس تبعه اللي بتفاعل هو + +198 +00:17:43,280 --> 00:17:49,400 +ايش ال oxygen طالما هو neutral مباشرة بدنا نشيل + +199 +00:17:49,400 --> 00:17:57,100 +منه ال H لما بنكتب الجواب يعني نفس هذا المركب لو + +200 +00:17:57,100 --> 00:18:04,800 +كان بيتفاعل مع ال ammonia and H3 شو هتكتبوه؟ + +201 +00:18:08,390 --> 00:18:16,150 +بتبط من عند ال N و هيكون N H2 واضح؟ طبعا هتيجي و + +202 +00:18:16,150 --> 00:18:20,630 +تقولوا طب و ال H اللي طلعت وين راحت؟ ما هي ال H مع + +203 +00:18:20,630 --> 00:18:28,660 +ال PR هتعمل زي H PRواضح؟ يعني الـ H plus اللي طلعت + +204 +00:18:28,660 --> 00:18:33,180 +مع الـ PR minus اللي هنا هيطلع HPR احنا بشكل أساسي + +205 +00:18:33,180 --> 00:18:38,740 +دائما مهتمين بالنتج العضوي لاحظوا كيف انه احنا لما + +206 +00:18:38,740 --> 00:18:43,060 +بنكتب معادلة فيها neutral نيوكليوفايل سواء كان + +207 +00:18:43,060 --> 00:18:47,320 +Oxygen سواء كان Nitrogen سواء كان Sulphur يعني لو + +208 +00:18:47,320 --> 00:18:50,920 +افترضوا ان هنا كانت في عندكم H2S + +209 +00:18:53,150 --> 00:18:59,990 +شو هتكتبوا؟ S H من وين شابك؟ من السلفر و هكذا + +210 +00:18:59,990 --> 00:19:08,250 +واضح؟ الآن لو خلنا نفس هذا المثال و قولنا بدنا + +211 +00:19:08,250 --> 00:19:14,270 +نعمل التفاعل مع أيونات سالبة شو الايون السالب اللي + +212 +00:19:14,270 --> 00:19:21,970 +هنا بدنا نكون استعملناه؟ S H minusبطلع النتج شو + +213 +00:19:21,970 --> 00:19:30,390 +الايون السالب اللى هنا بدنا نكون استعملناه CH3 CH2 + +214 +00:19:30,390 --> 00:19:35,770 +O برابط واحدة و تلت أزواج إلكترونية يعني O minus + +215 +00:19:35,770 --> 00:19:42,150 +طبعا هذي ايش الايون المرافق عادة لها ال Sodium Na + +216 +00:19:42,150 --> 00:19:49,880 +Plus و المركب لو بدنا نسميه ايش بنسميهSodium + +217 +00:19:49,880 --> 00:19:55,160 +Ethoxide لحظة هذه إثل و بزام أكسوجين سالب + +218 +00:19:55,160 --> 00:19:59,460 +الأكسوجين السالب ايش متعودين طول عمرنا نقوله أكسيد + +219 +00:19:59,460 --> 00:20:03,720 +زي ما بنقول للأيون السالب كلورايد ايد النهاية ايد + +220 +00:20:03,720 --> 00:20:09,450 +برمايد ايودايد طب لو أكسوجين سالبأوكسايد لو + +221 +00:20:09,450 --> 00:20:16,190 +نيتروجين سالب نيترايد لو سلفر سالب سلفايد الان لو + +222 +00:20:16,190 --> 00:20:24,130 +اذا الاكسجين سالب اثوك اث اكس اي اث اكسايد عشان + +223 +00:20:24,130 --> 00:20:31,290 +كذا المركب بيكون اسمه صوديوم اث اكسايد لو + +224 +00:20:31,290 --> 00:20:37,610 +كتبنالكوا صوديوم اث اكسايد ايش بدكم تحطوه CH3لو + +225 +00:20:37,610 --> 00:20:42,670 +قلنا بروبوكسايد تلت + +226 +00:20:42,670 --> 00:20:48,970 +كربونات من البروبين و هكذا فال ايون بشكل عام بيكون + +227 +00:20:48,970 --> 00:20:54,390 +اسمه الكوكسايد ايش يعني الكو يعني في مجموعة الكل + +228 +00:20:54,390 --> 00:20:59,150 +يعني يوم ما بدي اقول ايون ر او ماينوس ايش اسم هذا + +229 +00:20:59,150 --> 00:21:05,000 +الايونلو جيبنا لكوا سؤال أكمل الفراغ R O minus is + +230 +00:21:05,000 --> 00:21:13,940 +called an alkoxide anion أنيون يعني أيون إيش؟ سالب + +231 +00:21:13,940 --> 00:21:18,980 +الكوكسايد أنيون + +232 +00:21:18,980 --> 00:21:25,340 +واضح؟ الكوكسايد أنيون إذا صار عندنا فكرة تماما كيف + +233 +00:21:25,340 --> 00:21:33,150 +نكمل معادلةبأيون سالب أو بمتعدل في كل الأحوال مكان + +234 +00:21:33,150 --> 00:21:37,650 +ما بتكون الهالوجين مكان ما بنحط ايش لنيوكليوفايل + +235 +00:21:37,650 --> 00:21:42,590 +ونعمل لنيوكليوفيليك substitution كل الجداول اللي + +236 +00:21:42,590 --> 00:21:52,050 +موجودة عندكم هي أمثلة على هذا الموضوع كل الجداول + +237 +00:21:52,050 --> 00:21:59,280 +يعني لاحظوا لنيوكليوفايل هنا OH-تشارج RO- تشارج + +238 +00:21:59,280 --> 00:22:07,280 +HOH تشارج ROH تشارج HOH تشارج HOH تشارج HOH تشارج + +239 +00:22:07,280 --> 00:22:08,700 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +240 +00:22:08,700 --> 00:22:09,060 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +241 +00:22:09,060 --> 00:22:09,680 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +242 +00:22:09,680 --> 00:22:09,740 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +243 +00:22:09,740 --> 00:22:09,740 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +244 +00:22:09,740 --> 00:22:11,520 +HOH تشارج HOH تشارج HOH تشارج HOH تشارج HOH تشارج + +245 +00:22:11,520 --> 00:22:16,780 +HOH تشهذا الأكسجين بتحول محل الـCl الـ Nitrogen + +246 +00:22:16,780 --> 00:22:22,280 +نيوكليوفايل مثلا نيوترال الأمونيا ومشتقاتها سواء + +247 +00:22:22,280 --> 00:22:26,260 +كان عنده R واحدة أو تنتين أو تلاتة في كل الأحوال + +248 +00:22:26,260 --> 00:22:32,390 +من وين بكيش بيك؟ من مكانالنيتروجين السلفر + +249 +00:22:32,390 --> 00:22:38,370 +النيوكليوفيل على سبيل المثال SH-, RS-, R2S من + +250 +00:22:38,370 --> 00:22:44,210 +أزواج الإلكترونات على السلفر الهالوجين + +251 +00:22:44,210 --> 00:22:49,410 +النيوكليوفيل الهالوجين عادة عليها أربع أزواج + +252 +00:22:49,410 --> 00:22:55,220 +إلكترونات و بتكون سالبةواضح؟ بديكوا تتذكروا نقطة + +253 +00:22:55,220 --> 00:22:58,300 +انه احنا قولنا ال halogens لما تحل محال بعضها + +254 +00:22:58,300 --> 00:23:05,620 +البعض اليود اقوى من ال brom اقوى من ال chlorine + +255 +00:23:05,620 --> 00:23:11,400 +بناء على ذلك لو عندى مركب RX فيه brom وفعلته مع + +256 +00:23:11,400 --> 00:23:15,620 +يود اليود بيحل محال ال brom ولا لأ؟ اه لكن ال brom + +257 +00:23:15,620 --> 00:23:22,380 +بيحلش محال اليوداليود بيحل محل بروم بمعنى لو كانت + +258 +00:23:22,380 --> 00:23:32,240 +المعادلة بهذا الشكل I minus زائد CH3PR وقلنا لك + +259 +00:23:32,240 --> 00:23:40,840 +اكمل المعادلة بيحل اليود محل بروم او محل كلور سواء + +260 +00:23:40,840 --> 00:23:44,980 +كان بروم او كلور بيصير هذا التفاعل بيصير شو الناتج + +261 +00:23:44,980 --> 00:23:48,080 +CH3I + +262 +00:23:51,470 --> 00:23:58,690 +زائد PR ماينوس أو CL ماينوس ايش السؤال PR مش كازم + +263 +00:23:58,690 --> 00:24:03,850 +ترتبط مثلا باش مهم مش مهم هو هذا NA plus بديش انا + +264 +00:24:03,850 --> 00:24:08,430 +اعيد الجملة مية مرة هذا NA plus I minus لما نشوفه + +265 +00:24:08,430 --> 00:24:14,170 +كتفاعل كامل NA plus I minus زائد CH3PR إجت ليه محل + +266 +00:24:14,170 --> 00:24:28,430 +ال PR شو طلع عندىCH3I PR- N A N A Plus واضح؟ + +267 +00:24:28,430 --> 00:24:34,770 +لو هذه المعادلة وجدت عندكم بشكل معاكس يعني إيجينا + +268 +00:24:34,770 --> 00:24:40,630 +قولنا لكم CL- CH3PR + +269 +00:24:43,400 --> 00:24:46,740 +الكلور لا يحل محل البروم، البروم يحل محل الكلور و + +270 +00:24:46,740 --> 00:24:54,000 +هكذا واضح الفكرة؟ من الـ nucleophiles أيضا ال + +271 +00:24:54,000 --> 00:24:58,320 +carbon nucleophiles منها ال CN اللي حكينا عنه و + +272 +00:24:58,320 --> 00:25:02,780 +قولنا موجود ع شكل CN minus ال carbon nucleophiles + +273 +00:25:02,780 --> 00:25:08,560 +بالمناسبة لا توجد متعادلة ليش ال carbon + +274 +00:25:08,560 --> 00:25:14,070 +nucleophiles لا توجد متعادلة؟لأن الكربون أول ما + +275 +00:25:14,070 --> 00:25:18,870 +تعلمنا الكيميا يقولنا بيعمل أربع روابط ولا يبقى + +276 +00:25:18,870 --> 00:25:25,010 +فيه أزواج إلكترونات الميّه رابطتين وزوجين + +277 +00:25:25,010 --> 00:25:28,470 +إلكترونات النيتروجين تلت روابط وزوج إلكترونات + +278 +00:25:28,470 --> 00:25:33,130 +الهالوجين تلت أزواج إلكترونات كلهم عليهم أزواج + +279 +00:25:33,130 --> 00:25:34,950 +إلكترونات لكن الكربون + +280 +00:25:37,240 --> 00:25:40,500 +الـ Carbon مافيش عليه أزواج إلكترونات وبناء على + +281 +00:25:40,500 --> 00:25:43,300 +ذلك في الوضع المتعادل مافيش عندي carbon + +282 +00:25:43,300 --> 00:25:48,620 +nucleophile لكن لو هذا فقد H لسبب ما بيصير ايون + +283 +00:25:48,620 --> 00:25:53,740 +ايش سالب من أمثلة الايونات السالب اللي فيها Carbon + +284 +00:25:53,740 --> 00:25:58,100 +ايون الـ C9 هاي C triple bond N وهنا شايفين في + +285 +00:25:58,100 --> 00:26:02,420 +عندكم زوج من الإلكترونات ولا لأ لاحظوا + +286 +00:26:03,550 --> 00:26:08,550 +لو واحدة شوية بتدقيق الكلام الـCN- في زوج + +287 +00:26:08,550 --> 00:26:12,530 +إلكترونات على الكربون و زوج إلكترونات على + +288 +00:26:12,530 --> 00:26:16,190 +النيتروجين يعني من ناحية المبدأ ممكن أي واحدة تفكر + +289 +00:26:16,190 --> 00:26:21,250 +إنه الكربون نفسه بيعمل الـNucleophile و النيتروجين + +290 +00:26:21,250 --> 00:26:25,590 +نفسه بيعمل الـNucleophile عشان هيك لو إجتها معادلة + +291 +00:26:25,590 --> 00:26:34,490 +اتكملها CH3 نفترض CLوبدأ اتفعلها مع ال NACN احنا + +292 +00:26:34,490 --> 00:26:38,530 +بدنا ندمج العلم عاد ال carbon ال nucleophile اقوى + +293 +00:26:38,530 --> 00:26:44,110 +من ال nitrogen لما حكينا قوة لل nucleophiles وبناء + +294 +00:26:44,110 --> 00:26:49,230 +على ذلك هذا لما بدأ افعله مع ال CN minus من وين + +295 +00:26:49,230 --> 00:26:57,110 +هييجي يتحد هنا اذا النتج هيكون CH3 اتصلت بال + +296 +00:26:57,110 --> 00:27:02,650 +cyanide من خلال carbonمن خلال الكربون مش + +297 +00:27:02,650 --> 00:27:07,910 +النيتروجين واضح؟ طبعا النيتروجين بيبقى عليها زوج + +298 +00:27:07,910 --> 00:27:13,590 +الالكترونات تبعها ف الـ CN- بتتحد مكان الهالوجين + +299 +00:27:13,590 --> 00:27:21,080 +من خلال الكربون مش النيتروجينخدوا في كمان ايون + +300 +00:27:21,080 --> 00:27:25,900 +اخدناه اخذنا تفاعله ل triple bond اللي بتكون + +301 +00:27:25,900 --> 00:27:31,440 +terminal جنبها H اتفقنا ان هذا الـH اسيدك يمكن ان + +302 +00:27:31,440 --> 00:27:37,460 +تفقد وتعمل ايون سالب على الكربون سمناه Acetylide + +303 +00:27:37,460 --> 00:27:43,820 +anion هذا اخدناه بتفاعل الالكاينز اخر تفاعل راجعوا + +304 +00:27:43,820 --> 00:27:47,980 +الان هذا ال Acetylide anion لو اجيناه فاعلناه مع + +305 +00:27:47,980 --> 00:27:58,410 +RXماذا سيفعل؟ سيأتي الكربون تهاجم وتطرد الـ X إذا + +306 +00:27:58,410 --> 00:28:05,850 +صار عندي A اللي موجودة هنا C triple bond CR فهيصير + +307 +00:28:05,850 --> 00:28:13,210 +إبدال لل X بالacetylide anion من خلال الكربون + +308 +00:28:13,210 --> 00:28:17,330 +النيوكليوفال كل هذه الأمثلة اللي انتوا شايفينها هي + +309 +00:28:17,330 --> 00:28:23,530 +عبارة عنsubstitution reactions كل الأمثلة اللي مرت + +310 +00:28:23,530 --> 00:28:27,930 +علينا substitution reactions استعرضناها بتوسع سواء + +311 +00:28:27,930 --> 00:28:33,470 +من ناحية neutral enucleophiles أو من ناحية charged + +312 +00:28:33,470 --> 00:28:34,870 +enucleophiles + +313 +00:28:38,920 --> 00:28:45,140 +بجينا تفاعل تاني وهذا التفاعل التاني بشكل عام + +314 +00:28:45,140 --> 00:28:50,920 +منافس لتفاعل الإبدال بمعنى التفاعلين بيصيروا مع + +315 +00:28:50,920 --> 00:28:58,200 +بعض يعني انا بكون بدي اعمل تفاعل إبدال بلاحظ انه + +316 +00:28:58,200 --> 00:29:04,380 +مع الإبدال بطلع عندى ناتج تاني حذف ايش هو تفاعل + +317 +00:29:04,380 --> 00:29:09,400 +الحذف؟ماذا هو بالظبط تفاعل الحذف؟ تفاعل الإبدال؟ + +318 +00:29:09,400 --> 00:29:14,420 +اعرفنا يعني لو الآن جيبنالكم أكمل المعادلة هذه CH3 + +319 +00:29:14,420 --> 00:29:20,320 +CHPR CH3 زائد NUH كل كسرته تتقن الإبدال شيل ال PR + +320 +00:29:20,320 --> 00:29:23,180 +حط مكانها هذا + +321 +00:29:25,930 --> 00:29:30,410 +Substitution طب إيش تفاعل الحذف اللي بيصير بنفس + +322 +00:29:30,410 --> 00:29:33,470 +الشروط عشان هيك لاحظوا نفس المُركّب مع الانيواتش + +323 +00:29:33,470 --> 00:29:38,550 +بدنا نكتب إنه بيطلع ناتج تاني إنه يعمل حذف + +324 +00:29:38,550 --> 00:29:44,930 +للهالوجين مع هيدروجين عن الكربون المجاورة إيش معنى + +325 +00:29:44,930 --> 00:29:51,830 +الحذف إن أشيل الهالوجين مع ذرة هيدروجين يعني كإن + +326 +00:29:51,830 --> 00:30:00,140 +اللي بدي أحذف أشههH و PR واضح الان وين ال hydrogen + +327 +00:30:00,140 --> 00:30:05,620 +اللى انا بدي اشيله معروف واحد مافيش غيره طب وين ال + +328 +00:30:05,620 --> 00:30:10,120 +hydrogens على الكربون المجاورة لو انا اتيت واطلعت + +329 +00:30:10,120 --> 00:30:13,400 +هذه الكربون اللى حاملة ال hydrogen فيه جنبها على + +330 +00:30:13,400 --> 00:30:20,400 +اليمين CH3 حاملة كم هيدروجينة تلاتة وفيه جنبها على + +331 +00:30:20,400 --> 00:30:28,550 +اليسارCH3 حاملة 3 تفاعل الحذف ان اشيل ال PR هذه مع + +332 +00:30:28,550 --> 00:30:33,790 +ال Hشطابتهم طبعا هذه الرابطه هتيجي تعمل double + +333 +00:30:33,790 --> 00:30:38,210 +bond هنا فبدل ما كان عندي رابطه أحدية بتصير رابطه + +334 +00:30:38,210 --> 00:30:43,730 +ثنائية بتكون الألكيد طيب الآن يا ترى بيفرق عندى في + +335 +00:30:43,730 --> 00:30:48,710 +هذا المركب لما أعمل الحذف بمساعدة الانقوات ان اعمل + +336 +00:30:48,710 --> 00:30:53,770 +الرابطة الزوجية هان او هان نفس المركب نفس المركب + +337 +00:30:53,770 --> 00:31:01,860 +في مرات معينة هلاحظ انهبيفرق عندنا بعمل مشكلة + +338 +00:31:01,860 --> 00:31:06,820 +بيصير عندى احتمالين يعني لو أخدتوا هذا المركب اللى + +339 +00:31:06,820 --> 00:31:13,540 +هو اسمه two bromobutane high carbon اتنين تلاتة + +340 +00:31:13,540 --> 00:31:20,820 +اربعة هذا ايش اسمه two bromobutane كل الذرات اللى + +341 +00:31:20,820 --> 00:31:27,210 +موجودين عندى عبارة عن ايشهيدروجينز الان انا لما + +342 +00:31:27,210 --> 00:31:33,130 +بدي اعمل الحذف بمساعدة ال OH- و لاحظوا كيف بالظبط + +343 +00:31:33,130 --> 00:31:38,990 +بتتم عملية الحذف يعني كيف ال OH- هذه بتيجي بتعمل + +344 +00:31:38,990 --> 00:31:45,690 +الحذف ال OH- بدها إيش بدها H بلس فبتيجي بتهجم + +345 +00:31:45,690 --> 00:31:50,650 +هينفترض هجمت على هذي ال H بلس هى ال OH- أخدت ال H + +346 +00:31:50,650 --> 00:31:57,150 +بلس طلعت على شكل جزء إيشماء فهمنا هذه الخطوة + +347 +00:31:57,150 --> 00:32:01,390 +الأولى في التفاعل أن الـ OH- هجمت على الـ H أخدتها + +348 +00:32:01,390 --> 00:32:08,930 +عملت مية طلعت الآن هذه الرابط اللي ضالة بتلوف بهذا + +349 +00:32:08,930 --> 00:32:13,590 +الاتجاه معقول أن يصير خمس روابط إذا إيش هيصير طلوع + +350 +00:32:13,590 --> 00:32:21,150 +جبالها للـ PR بتم التفاعل فالـ OH والـ H شو + +351 +00:32:21,150 --> 00:32:29,870 +هيعطوني؟H2O طب ال PR minus مع ال NA اللي هنا ما هي + +352 +00:32:29,870 --> 00:32:36,450 +ال OH فيه معها إيش NA مش هذه NA plus OH minus + +353 +00:32:36,450 --> 00:32:40,230 +Sodium hydroxide ال PR ال minus مع ال NA شو + +354 +00:32:40,230 --> 00:32:49,340 +بتعطيني NA PR ال OH مع ال HH2O وبتكون عندى الـ + +355 +00:32:49,340 --> 00:32:52,420 +Double bond عشانك لو رجعته مرة تانية بسرعة شوفتوا + +356 +00:32:52,420 --> 00:32:59,440 +المعادلة اللى هنا Double bond NABR H2O شوفنا كيف + +357 +00:32:59,440 --> 00:33:05,560 +بتكونوا هدول التلاتة الميه انه اجت ال OH أخدت H + +358 +00:33:05,560 --> 00:33:10,240 +طلعت ال PR minus ال PR minus لجت ال NA plus عملت + +359 +00:33:10,240 --> 00:33:17,130 +معه NABR و المركب العضوى صارDouble bond صار ال + +360 +00:33:17,130 --> 00:33:21,750 +keen طبعا انا اللي بهمني كنتيجة اكتر ما يمكن ايش + +361 +00:33:21,750 --> 00:33:26,110 +ال organic compound يعني هذه المركبات تحصيل حاصل + +362 +00:33:26,110 --> 00:33:33,550 +مافيش فيهامافيش فيها مشكلة الان لاحظوا معاك كلكوا + +363 +00:33:33,550 --> 00:33:37,010 +اتفقتوا انه ماناش في ال NA احنا قيلنا في ال OH + +364 +00:33:37,010 --> 00:33:42,130 +بدها H مجاورة على هذه ال carbon طب هذه ال OH يا + +365 +00:33:42,130 --> 00:33:45,550 +تورا لو بدل ما تيجي هنا وتاخد H من هدول اللي على + +366 +00:33:45,550 --> 00:33:52,990 +الشمال لو كانت من أهل اليمين اجت ال OH واخدت هذه + +367 +00:33:52,990 --> 00:34:01,220 +ال H وارد ولا لأ؟خلّينا نشطب هذا الكلام الأولاني + +368 +00:34:01,220 --> 00:34:06,860 +الـ OH بده اتش مجاورة واحدة شمال واحدة يمين إذا + +369 +00:34:06,860 --> 00:34:10,720 +أصطدمت بالشمال وين حيصير الالكين؟ على هذا الموقع، + +370 +00:34:10,720 --> 00:34:16,140 +حيطلع هذا النتج طب لو أخدت هذه الـ H هاي ميل، هذه + +371 +00:34:16,140 --> 00:34:19,820 +وين بده تيجي على طول؟ هان، بده يتكون عندي أي + +372 +00:34:19,820 --> 00:34:24,740 +ألكين؟ ألكين، تاني الـ two butane في الحالة + +373 +00:34:24,740 --> 00:34:29,550 +الأولى، الوان بيوتينإذا لو في عندي أكثر من + +374 +00:34:29,550 --> 00:34:33,690 +الهيدروجين مجاورة أو كانوا مختلفات متوقع يطلع عندي + +375 +00:34:33,690 --> 00:34:39,170 +أكثر من ال keen لو كانوا متشابهات زي المثال السابق + +376 +00:34:39,170 --> 00:34:46,290 +يعني هنا CH3 و CH3 زي بعض ناتج واحد لما اختلفوا + +377 +00:34:46,290 --> 00:34:53,190 +صار هنا CH3 و هنا CH2 و CH3 صارواتخيل لو هنا كان + +378 +00:34:53,190 --> 00:34:59,030 +في مجموعة تالتة اذا ممكن يطلع عندى كام ناتج تلاتة + +379 +00:34:59,030 --> 00:35:03,990 +ممكن يكون النواتج اللى عندى مش بس اتنين ممكن يطلع + +380 +00:35:03,990 --> 00:35:10,290 +عندى تلت نواتج حدث يعني لو تخيلتوا ان هى عندى Cبر + +381 +00:35:10,290 --> 00:35:15,750 +وحطيت على جهة منها CH3 وهي نوع من الهيدروجينز + +382 +00:35:15,750 --> 00:35:24,570 +وحطيت على الجهة التانية CH2 CH3 هي مجموعة تانية + +383 +00:35:24,570 --> 00:35:35,590 +وحطيت على الجهة التالتة CH2 CH2 CH2 CH3هي مركّب + +384 +00:35:35,590 --> 00:35:41,030 +الان الشيء الأكيد اللي بدى أحذفه انا شهو هو ال PR + +385 +00:35:41,030 --> 00:35:48,250 +هاي ال PR حذفناها و hydrogen من الكربون المجاورة + +386 +00:35:48,250 --> 00:35:52,470 +لو حذفت من هنا وين هتصير ال double bond؟ ع هذا + +387 +00:35:52,470 --> 00:35:55,890 +الموقع لو حذفت من هنا وين هتصير ال double bond؟ ع + +388 +00:35:55,890 --> 00:35:58,410 +هذا الموقع لو حذفت من هنا وين هتصير ال double + +389 +00:35:58,410 --> 00:36:02,270 +bond؟ ع هذا الموقع اذا كام ال keen هنا متوقع عندى؟ + +390 +00:36:02,270 --> 00:36:07,600 +تلاتةجربوا انكم اتكملوهم في البيت ال double bond + +391 +00:36:07,600 --> 00:36:12,740 +تتكون على هذا الموقع او هان او هان هدولة عبارة عن + +392 +00:36:12,740 --> 00:36:19,200 +كام ناتج تلت نواتج و لو نفذت هذا الحذف و طلعته في + +393 +00:36:19,200 --> 00:36:23,360 +المركبات او حتى سميتهم حتلاقوهم تلت مركبات مختلفة + +394 +00:36:23,360 --> 00:36:31,220 +اذا في عندي دائما في عملية الحذف اكثر من ايشأكتر + +395 +00:36:31,220 --> 00:36:36,340 +من احتمال الآن بيصير السؤال طيب هذا الكلام بالورقة + +396 +00:36:36,340 --> 00:36:40,160 +والجلم أكتر من احتمال one butene او two butene او + +397 +00:36:40,160 --> 00:36:42,600 +هان ال double bond على هذا الموقع او على هذا او + +398 +00:36:42,600 --> 00:36:49,380 +على هذا على العين والراس بالتجربة هل يا ترى في شيء + +399 +00:36:49,380 --> 00:36:53,880 +بيطلع اكتر من شيء يعني بمعنى اخر بيطلع ك major + +400 +00:36:53,880 --> 00:37:01,440 +product كناتج أساسيهل في شيء عنده بيطلع و بقدر + +401 +00:37:01,440 --> 00:37:06,080 +اعتبره ناتج أساسي بمعنى لو انا الآن هدول احتمالات + +402 +00:37:06,080 --> 00:37:11,640 +بالورقة والجلم مظبوطين لكن لو جبتلكوا هذا كسؤال في + +403 +00:37:11,640 --> 00:37:16,500 +الامتحان و قلتلكوا اكمل المعادلة two bromobutane + +404 +00:37:16,500 --> 00:37:24,410 +مع OH- اكتبوا ال الكيل اللي عادة بيطلعلاحظوا معي + +405 +00:37:24,410 --> 00:37:29,890 +هلاحظ أن اللي بيطلع عادة هذا مش هذا هتقولوا الآن + +406 +00:37:29,890 --> 00:37:36,960 +بدنا قاعدةبناء على إيش؟ بناء على إيش؟ شوية أنا + +407 +00:37:36,960 --> 00:37:43,580 +بعتقد أن الأمر بحاجة إلى تفصيل وهذه الشغلة لاحظوا + +408 +00:37:43,580 --> 00:37:48,440 +معين هذه عكس الشغل اللي كان بيشتغله Markovnikov + +409 +00:37:48,440 --> 00:37:53,320 +متذكرين إيش كان بيشتغل Markovnikov؟ Markovnikov + +410 +00:37:53,320 --> 00:37:57,100 +كان يجيب ال double bond يحولها إلى single bond + +411 +00:37:57,100 --> 00:38:02,360 +يقول وين نحط ال H؟وانا احط ال PR وقلنا في عندى + +412 +00:38:02,360 --> 00:38:05,880 +Markovnikov addition وانتي Markovnikov addition ال + +413 +00:38:05,880 --> 00:38:09,000 +addition ان ال double bond تصير single bond ال + +414 +00:38:09,000 --> 00:38:12,100 +single + +415 +00:38:12,100 --> 00:38:17,080 +bond تصير double bondإذا ال elimination عكس ال + +416 +00:38:17,080 --> 00:38:23,140 +addition الحدث عكس إيش؟ الإضافة الحدث عكس الإضافة + +417 +00:38:23,140 --> 00:38:26,940 +الآن اللي كان بيشتغل على الموضوع هذا مع + +418 +00:38:26,940 --> 00:38:32,540 +Markovnikov بنفس الجامعة بنفس الوقت عالم اسمه + +419 +00:38:32,540 --> 00:38:37,060 +Zaitsevيعني الاتنين كانوا بيشتغلوا بحدود سنة ألف و + +420 +00:38:37,060 --> 00:38:41,940 +تمانية و سبعين خمسة و سبعين في جامعة Kazan في + +421 +00:38:41,940 --> 00:38:47,000 +روسيا Markovnikov عمل قاعدة Markovnikov للإضافة + +422 +00:38:47,000 --> 00:38:53,580 +Zaitsev عمل قاعدة Zaitsev لإيش؟ للحدث يمكن أنا أنا + +423 +00:38:53,580 --> 00:38:58,180 +مش مركز عليها لكن لبأس نحكيلكوا يها بسرعة إيش + +424 +00:38:58,180 --> 00:39:01,760 +بتقول هذه قاعدة Zaitsev للحدث؟ + +425 +00:39:04,190 --> 00:39:09,270 +Zaitsev's rule بتكتب باكثر من طريقة لحقيقة Zaitsev + +426 +00:39:09,270 --> 00:39:13,810 +ببساطة بيقول انه في مثل هذا الحدث the more + +427 +00:39:13,810 --> 00:39:20,570 +substituted ال keen will form the more substituted + +428 +00:39:20,570 --> 00:39:27,010 +ال keen will form يعني بيتكون ال keen الأكثر + +429 +00:39:27,010 --> 00:39:35,550 +إبدالابدي يتكون الألكين الأكثر إبدالا مش انا عندي + +430 +00:39:35,550 --> 00:39:40,170 +one butane و two butane النواتج مين الأكثر إبدالا + +431 +00:39:40,170 --> 00:39:44,910 +فيهم؟ بدنا نعرف إيش معنى الألكين الأكثر إبدالا + +432 +00:39:44,910 --> 00:39:49,670 +اللي بدي يعرف معنى الألكين الأكثر إبدالا بدي ييجي + +433 +00:39:49,670 --> 00:39:54,810 +للألكين الأقل إبدالا يكون فاهمه أبسط ألكين في + +434 +00:39:54,810 --> 00:39:56,070 +الدنيا شو هو؟ + +435 +00:40:03,470 --> 00:40:06,010 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +436 +00:40:06,010 --> 00:40:07,090 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +437 +00:40:07,090 --> 00:40:07,810 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +438 +00:40:07,810 --> 00:40:10,050 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +439 +00:40:10,050 --> 00:40:10,510 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +440 +00:40:10,510 --> 00:40:10,830 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +441 +00:40:10,830 --> 00:40:11,270 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +442 +00:40:11,270 --> 00:40:11,270 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +443 +00:40:11,270 --> 00:40:11,270 +أربعة أربعة أربعة أربعة أربعة أربعة أربعة أربعة + +444 +00:40:11,270 --> 00:40:17,890 +أربعة1 لو شيلت كمان قدش و خليتها R افدالين لو شيلت + +445 +00:40:17,890 --> 00:40:20,870 +كمان قدش و خليتها R افدالين لو شيلت كمان قدش و + +446 +00:40:20,870 --> 00:40:21,530 +خليتها R افدالين لو شيلت كمان قدش و خليتها R + +447 +00:40:21,530 --> 00:40:23,530 +افدالين افدالين افدالين افدالين افدالين افدالين + +448 +00:40:23,530 --> 00:40:25,170 +افدالين افدالين افدالين افدالين افدالين افدالين + +449 +00:40:25,170 --> 00:40:25,250 +افدالين افدالين افدالين افدالين افدالين افدالين + +450 +00:40:25,250 --> 00:40:28,010 +افدالين افدالين افدالين افدالين افدالين افدالين + +451 +00:40:28,010 --> 00:40:37,750 +افدالين افدالين افدالين افدالين + +452 +00:40:37,750 --> 00:40:44,260 +افدالالان اذا هذه لاتش نفترض كانت هذا المركب R + +453 +00:40:44,260 --> 00:40:49,020 +وهنا كان R قلتلكوا هذا كم substitution عليه اتنين + +454 +00:40:49,020 --> 00:40:54,860 +اذا مين more substituted هذا ولا الاتين هذا هذا + +455 +00:40:54,860 --> 00:40:59,000 +مافيش عليه ولا ابدال الاتين مافيش عليه ولا ابدال + +456 +00:40:59,000 --> 00:41:02,460 +ولا هيدروجينة ابدلة هذا كم ابدال عليه اتنين طيب لو + +457 +00:41:02,460 --> 00:41:08,450 +قلتلكوا هذا المركب ولا هذاهذا كام إبدال عليه اللي + +458 +00:41:08,450 --> 00:41:13,690 +جابله طب لو حطينا هنا كمان R أربعة which is more + +459 +00:41:13,690 --> 00:41:17,810 +substituted واضح الفكرة إيش معنى more substituted + +460 +00:41:17,810 --> 00:41:23,490 +كل ما صار عليه مجموعات R أكثر الآن لو إجينا و + +461 +00:41:23,490 --> 00:41:26,970 +اتطلعنا على هدول التلان فصلولي حوالين ال double + +462 +00:41:26,970 --> 00:41:30,610 +bond يعني قولوا هذه double bond هنا إيش موجود + +463 +00:41:30,610 --> 00:41:33,790 +عندكم إبدلات؟ لا + +464 +00:41:36,790 --> 00:41:43,570 +و هان H هذي اللي شطبناها و هان K إذا هذا لو بدكوا + +465 +00:41:43,570 --> 00:41:49,770 +تقارنوه بال إثليين كام إفدال عليه حقيقة؟ واحد لو + +466 +00:41:49,770 --> 00:41:54,550 +هذه تنشر و تصير H بيبطل مبدل إذا هذا كام إفدال + +467 +00:41:54,550 --> 00:41:58,970 +عليه؟ واحد طب لو إجيت على المركب التاني هاي ال + +468 +00:41:58,970 --> 00:42:05,590 +double bond هنا إيش في عندكم؟ H و هنا فصلتهم + +469 +00:42:06,370 --> 00:42:13,290 +وهنا تطلعوا إيش في عندكم؟ carbon إذا هذه مقدلة + +470 +00:42:13,290 --> 00:42:20,510 +وهنا carbon إذا هذا كام إبدال؟ اتنين which is more + +471 +00:42:20,510 --> 00:42:24,670 +substituted ال two butyl is more substituted than + +472 +00:42:24,670 --> 00:42:30,950 +one butyl فهذا اللي بيكون major product شوفته كيف؟ + +473 +00:42:31,530 --> 00:42:35,370 +الـ two butane is more substituted لأنه في + +474 +00:42:35,370 --> 00:42:38,810 +مجموعتين ألكل على ال double bond أنا بس بتطلع على + +475 +00:42:38,810 --> 00:42:42,610 +أطراف ال double bond و لحد الأقصى للإبدال جديش + +476 +00:42:42,610 --> 00:42:48,110 +أربعة هنا في عندى إبدال واحد هنا في عندى اتنين + +477 +00:42:48,710 --> 00:42:54,390 +ابدالين اذا this compound is more substituted than + +478 +00:42:54,390 --> 00:42:58,790 +this compound واضح الفكرة اللي more substituted هو + +479 +00:42:58,790 --> 00:43:04,510 +بيكون ال major product خليني اعطيكم سؤال homework + +480 +00:43:04,510 --> 00:43:08,730 +اتجربوا تعملوه و بننهي فيه لو يا ترى حطينا هذا + +481 +00:43:08,730 --> 00:43:14,690 +المركب و حطينا لكم ب ا حطينا هنا c H3 و حطينا هنا + +482 +00:43:14,690 --> 00:43:24,890 +عند اللزوم H و هنا حطينا CHCH3 وانا كمان حطينا CH3 + +483 +00:43:24,890 --> 00:43:33,170 +تانية الان اكتبولي نواتج الابدال و اقولولي اي واحد + +484 +00:43:33,170 --> 00:43:39,530 +فيهم ال major يعني هذا بدياه مع ال OH minus يعمل + +485 +00:43:39,530 --> 00:43:45,900 +ابدال elimination هو اكيد بيعملعفوا الحدث نواتج + +486 +00:43:45,900 --> 00:43:51,160 +الحدث اكتبولي نواتج الحدث الممكنة و اي واحد منهم + +487 +00:43:51,160 --> 00:43:58,080 +ال major product الان بالتأكيد مع الحدث فيه كمان + +488 +00:43:58,080 --> 00:44:03,980 +ايش ابدال يعني بمعنى ان هذا التفاعل لا يلفك دائما + +489 +00:44:03,980 --> 00:44:10,140 +بطلع فيه ناتج ابدالوناتج حذف بنسبة مختلفة حسب ظروف + +490 +00:44:10,140 --> 00:44:14,980 +التفاعل وحسب عوامل كتير بتأثر لكن احنا الآن سؤالنا + +491 +00:44:14,980 --> 00:44:21,260 +بد نواتج الحذف الممكن لهذا التفاعل واي ناتج من + +492 +00:44:21,260 --> 00:44:27,340 +هدول النواتج اللي هو يعتبرالـ major product ضايل + +493 +00:44:27,340 --> 00:44:31,260 +عندنا شغلتين صغار بدون دقيقتين عشان المرة الجاية + +494 +00:44:31,260 --> 00:44:35,840 +نبدأ المركب من أول و جديد هذه ال slides اللي عندكم + +495 +00:44:35,840 --> 00:44:42,280 +كلها مركبات تطبيقية لهنوجين compounds يعنيالـ + +496 +00:44:42,280 --> 00:44:44,700 +Methyl bromide يستعمل في الزراعة، الـ + +497 +00:44:44,700 --> 00:44:47,940 +Dichloromethane يستعمل solvent، الchloroform + +498 +00:44:47,940 --> 00:44:52,680 +solvent، التفلون مار عليكم، اتذكرينه ولا لأ؟ + +499 +00:44:52,680 --> 00:44:57,300 +المركبات اللي فيها كلور و فلورو كاربون بيستعملوها + +500 +00:44:57,300 --> 00:45:02,630 +غازات ثلاجات بنسميها chlorofluorocarbonsمن ضمنها + +501 +00:45:02,630 --> 00:45:07,610 +الفريون اللي بتدمر طبقة الأوزون لاحظوا الـCFC شو + +502 +00:45:07,610 --> 00:45:12,290 +معناها؟ اكلورو فلورو كاربون يعني هي كلور هي فلور + +503 +00:45:12,290 --> 00:45:16,750 +هي كاربون صار اسمها الـCFC فيها كلور و فلور مين + +504 +00:45:16,750 --> 00:45:21,930 +اللي طلع زعلان؟ كاربون لأ البروم الهالوجين الأساسي + +505 +00:45:21,930 --> 00:45:27,650 +شمه؟ كلور و فلور برومطب هذه المراكبات ال CFCs فيها + +506 +00:45:27,650 --> 00:45:32,770 +كلور و فلور فيها بروم؟ طب لو حطينا عليها بروم شو + +507 +00:45:32,770 --> 00:45:38,630 +بيصير اسمها؟ هالونز بيصير كلور و فلور و كاربونز و + +508 +00:45:38,630 --> 00:45:43,090 +فيهم بروم بيصيروا هالونز عارفين شو ال هالونز؟ + +509 +00:45:43,090 --> 00:45:46,630 +اتطلع على الطفاية اللى على باب القاعة اللى عادة + +510 +00:45:46,630 --> 00:45:50,570 +اللى غطى أخضر هذه طفيات بدي استعملها لإطفاء حرائق + +511 +00:45:50,570 --> 00:45:55,210 +الكهربا وغيرها طفاية الغازغازات اللى بتتعبى فى + +512 +00:45:55,210 --> 00:45:58,910 +الطفاية اسمهم إيه؟ hellons لو قولنا لكوا شو ال + +513 +00:45:58,910 --> 00:46:04,190 +hellons؟ ال chlorofluorocarbons حملين بروم يعنى + +514 +00:46:04,190 --> 00:46:07,270 +chlorofluorobromocarbons + +515 +00:46:07,270 --> 00:46:12,310 +واضح؟ وكتيرة وكل اسم اللى لها اسم تجارى بنباعه و + +516 +00:46:12,310 --> 00:46:16,610 +بنشره و بنعبى فى الطفاية ابهيك بننتهى من chapter + +517 +00:46:16,610 --> 00:46:19,710 +ال alkalites ان شاء الله المرة القادمة بنبتدى فى + +518 +00:46:19,710 --> 00:46:21,670 +موضوع ال algorithms + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..cb91c76f3bef52f8e11c70062c5254867c337a0d --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_postprocess.srt @@ -0,0 +1,2048 @@ +1 +00:00:19,570 --> 00:00:24,470 +بسم الله الرحمن الرحيم اليوم ان شاء الله بنشرح + +2 +00:00:24,470 --> 00:00:31,450 +معلومات ايضا مختصرة على موضوع ال carbohydrates جزء + +3 +00:00:31,450 --> 00:00:39,870 +من ال biochemistry طبعا ال carbohydrates هم اكثر + +4 +00:00:40,850 --> 00:00:46,930 +جزيئات يمكن موجودة في الطبيعة من الجزيئات الحيوية + +5 +00:00:46,930 --> 00:00:51,770 +يمكن البعض يستغرب لكن لما تفكروا بس قداش في + +6 +00:00:51,770 --> 00:00:57,810 +بالدنيا نباتات و النباتات بشكل أساسي cellulose و + +7 +00:00:57,810 --> 00:01:03,430 +ال cellulose هو عبارة عن carbohydrates هذا الكلام + +8 +00:01:03,430 --> 00:01:09,890 +يمكن يعطيكم إيش فكرةبشكل عام ال carbohydrates + +9 +00:01:09,890 --> 00:01:16,010 +الصيغة تبعتهم هي عبارة عن carbon مع مية مكررين + +10 +00:01:16,010 --> 00:01:21,890 +يعني CH2O to the N فمن هنا إجت فكرة carbohydrates + +11 +00:01:21,890 --> 00:01:29,250 +يعني ال carbons وبعدين الميةCarbons وميّه واضح + +12 +00:01:29,250 --> 00:01:34,130 +فعلى سبيل المثال يعني لو بدكوا تاخدوا أنتوا أبسط + +13 +00:01:34,130 --> 00:01:42,510 +سكر .. أبسط سكر اللي هو C6H12O6 + +14 +00:01:42,510 --> 00:01:51,010 +الآن بنقدر نقول هذا عبارة عن 6 في C وH2O + +15 +00:01:51,010 --> 00:01:58,700 +فهو مضاعف لل Carbon و الميّهواضح؟ C6H12O6 + +16 +00:01:58,700 --> 00:02:04,900 +واضح الفكرة؟ ومن هنا إجا الاسم carbohydrate لأنه + +17 +00:02:04,900 --> 00:02:11,740 +بشكل أساسي الصيغة البسيطة تبعته هي عبارة عن carbon + +18 +00:02:11,740 --> 00:02:17,700 +وميه واضح هذه الفكرة؟ يعني لما نيجي نسألكم أن ال + +19 +00:02:17,700 --> 00:02:20,660 +carbohydrates الصيغة الأساسية بتاعتهم carbon و + +20 +00:02:20,660 --> 00:02:25,540 +oxygen carbon و hydrogenلأ لو كربون و هيدروجين كال + +21 +00:02:25,540 --> 00:02:30,800 +سمناها hydrocarbon لكن carbohydrate يعني كربون و + +22 +00:02:30,800 --> 00:02:35,840 +مياه الآن ال carbohydrates ببساطة احنا بنقدر + +23 +00:02:35,840 --> 00:02:41,260 +نتخيلها اذا بنفهمها بالشكل القاتل هي عبارة عن + +24 +00:02:41,260 --> 00:02:47,540 +جزيئات في الغالب كبيرة يعني ممكن نتخيل ان هذا جزيئ + +25 +00:02:48,170 --> 00:02:55,070 +كبير أشبه ما تكون بوليمار تمام الآن هذه الجزيئات + +26 +00:02:55,070 --> 00:02:59,650 +الكبيرة بنسميها احنا polysaccharides يعني سكريات + +27 +00:02:59,650 --> 00:03:05,720 +اشمالها عديدة لو عملنا لها hydrolysisفي وجود حمض + +28 +00:03:05,720 --> 00:03:12,200 +ميه بتتكسر الى جزيئات اصغر من وحدتين او تلاتة هذه + +29 +00:03:12,200 --> 00:03:16,980 +الجزيئات الاصغر بنسميها oligosaccharides يعني هي + +30 +00:03:16,980 --> 00:03:21,780 +كانت الكبيرة polysaccharide اتكسرت الى + +31 +00:03:21,780 --> 00:03:26,720 +oligosaccharides سكريات بسيطة زى السكريات الثنائية + +32 +00:03:26,720 --> 00:03:31,770 +هتمر علينا الان لو كسرناها اكتربصير عندى + +33 +00:03:31,770 --> 00:03:37,150 +monosaccharides اللى هو السكر المنفرد فإحنا لما + +34 +00:03:37,150 --> 00:03:41,750 +بدنا ندرس الآن بهذا الفصل و نتعرف على السكريات + +35 +00:03:41,750 --> 00:03:47,110 +هيكون المحور تبعنا بسيط جدا هنبدأ نقول إيش والله + +36 +00:03:47,110 --> 00:03:53,090 +ال monosaccharidesالمنفرد بعد هيك من اكثر من + +37 +00:03:53,090 --> 00:03:57,690 +monosaccharide هنعمل disaccharide اللي هو نوع من + +38 +00:03:57,690 --> 00:04:01,970 +ال oligosaccharide هيطلع عند السكاروز والملتوز + +39 +00:04:01,970 --> 00:04:06,430 +والاشياء هذه اللي هيواضح؟ الآن من ال + +40 +00:04:06,430 --> 00:04:11,950 +oligosaccharides هنعمل الجزيئات الكبيرة بشكل أساسي + +41 +00:04:11,950 --> 00:04:17,870 +النشا ال starch و ال cellulose واضح؟ فاحنا هنمشي + +42 +00:04:17,870 --> 00:04:22,110 +بهذا التدريج أن نتعرف في البداية شو هي ال + +43 +00:04:22,110 --> 00:04:27,120 +monosaccharides شو معناه sugarمنفرد لوحده الآن بعد + +44 +00:04:27,120 --> 00:04:32,160 +هيك اتنين من الشجر المنفرد هيعملولي Dysaccharide + +45 +00:04:32,160 --> 00:04:36,280 +اللي هو يعتبر نوع من ال Oligosaccharides و بعدين + +46 +00:04:36,280 --> 00:04:41,180 +لو اتحدوا ال Dysaccharides بشكل كبير عدد كبير منهم + +47 +00:04:41,180 --> 00:04:46,140 +بيعطينا ال إيش ال polysaccharides على سبيل المثال + +48 +00:04:46,140 --> 00:04:52,890 +النشا polysaccharideالنشط بولي ساكرايد لو عملنا له + +49 +00:04:52,890 --> 00:04:58,510 +هيدروليسيز بيعطينا داي ساكرايد اللي هو الملتوز + +50 +00:04:58,510 --> 00:05:03,950 +فالملتوز أوليغو ساكرايد أو داي ساكرايد ما هو الداي + +51 +00:05:03,950 --> 00:05:08,910 +أحد أنواع الأوليغو ساكرايد الآن لو الملتوز كسرناه + +52 +00:05:08,910 --> 00:05:16,240 +للوحدات الأساسية هو مكون من وحدتين جولوكوزالملتوز + +53 +00:05:16,240 --> 00:05:21,220 +من وحدتين جولوكوز واضح الفكرة فالجولوكوز مونو + +54 +00:05:21,220 --> 00:05:27,760 +ساكرايد الملتوز داي ساكرايد الاسترش بوني ساكرايد + +55 +00:05:27,760 --> 00:05:34,260 +واضح طبعا اللي بده يبتدى الان يتعرف ايش هم المونو + +56 +00:05:34,260 --> 00:05:37,300 +ساكرايد ايش هم المونو ساكرايد + +57 +00:05:40,150 --> 00:05:45,650 +ال sugar بنعرفهم انهم polyhydroxyaldehydes او + +58 +00:05:45,650 --> 00:05:49,670 +polyhydroxyketones ال polyhydroxyaldehydes بنسميهم + +59 +00:05:49,670 --> 00:05:54,130 +ال doses و ال polyhydroxyketones كيتوزز بمعنى + +60 +00:05:54,130 --> 00:06:01,070 +الشجر لازم يكون فيه يا aldehyde يا كيتون مع + +61 +00:06:01,070 --> 00:06:09,170 +مجموعات OH كتيرة اكثر من مجموعة OHولذلك لو احنا + +62 +00:06:09,170 --> 00:06:13,850 +اتطلعنا مثلا على المركب اللى موجود عندنا هنا اللى + +63 +00:06:13,850 --> 00:06:19,570 +هو الجليسرال ديهايد هل يترى هذا يمكن انه يتصنف + +64 +00:06:19,570 --> 00:06:27,510 +بمنطق الكيميا ك sugar فى عندي هنا الديهايد وفى + +65 +00:06:27,510 --> 00:06:35,050 +عندي هنا مجموعاتOH إذا هذا بولي هيدروكسي الديهايد + +66 +00:06:35,050 --> 00:06:39,330 +يعني عديد هيدروكسي ال الديهايد ولذلك هذا بنقول عنه + +67 +00:06:39,330 --> 00:06:45,550 +إيش ال dose ال dose يعني sugar من ال الديهايد طيب + +68 +00:06:45,550 --> 00:06:50,570 +ال dye هيدروكسي أسيتون بتعرفوا ال أسيتون CH3C + +69 +00:06:50,570 --> 00:06:55,130 +double bond O CH3 شيلت H حطيت مكان هنا OH وكمان + +70 +00:06:55,130 --> 00:07:01,270 +هنا OH صارDihydroxy-13-Dihydroxyacetone الآن هذا + +71 +00:07:01,270 --> 00:07:08,050 +الـDihydroxyacetone فيه كيتون وفيه + +72 +00:07:08,050 --> 00:07:14,870 +مجموعات OH إذا هذا عبارة عن بوليهيدروكس كيتون + +73 +00:07:14,870 --> 00:07:20,010 +بوليهيدروكس كيتون إذا هذا sugar كيتوز + +74 +00:07:21,950 --> 00:07:27,190 +ليش؟ لأنه جاي من كيتون، الدوز من ال الديهايد، واضح + +75 +00:07:27,190 --> 00:07:34,110 +الفكرة؟ الآن لو اتطلعت على ال glycerol، ال + +76 +00:07:34,110 --> 00:07:37,950 +glycerol او ال glycerin، فيه بس ال O H's، مافيه + +77 +00:07:37,950 --> 00:07:43,190 +الديهايد او كيتون، فهل ال glycerin بنصنفه انه + +78 +00:07:43,190 --> 00:07:46,930 +sugar كيميائيا؟ لأواضحة الفكرة؟ يعني لما نيجي + +79 +00:07:46,930 --> 00:07:51,410 +نقولكم glycerol can be classified as a sugar او is + +80 +00:07:51,410 --> 00:07:54,630 +classified as a sugar، لأ، لو قلنالكوا + +81 +00:07:54,630 --> 00:08:01,810 +dihydroxyacetone is an aldose، فهمته؟ او لو + +82 +00:08:01,810 --> 00:08:07,390 +قلنالكوا glyceraldehyde is equitoseglial aldehyde + +83 +00:08:07,390 --> 00:08:11,630 +is an aldose, dihydroxyacetone is a ketose تفهمنا + +84 +00:08:11,630 --> 00:08:15,710 +بالظبط إذا إيش معنى sugar، إيش معنى aldose، إيش + +85 +00:08:15,710 --> 00:08:20,550 +معنى ketose، واضحة الفكرة؟ والشجر لازم ينوجد فيه + +86 +00:08:20,550 --> 00:08:26,790 +كام شغلة؟ شغلتين، يا الديهيد، يا كيتون، ومجموعات + +87 +00:08:26,790 --> 00:08:35,230 +الـOH، هذا اللي بدنا نصنفه sugarلو بدنا ننطلق من + +88 +00:08:35,230 --> 00:08:40,850 +ال glyceraldehyde، ال glyceraldehyde كم carbon كان + +89 +00:08:40,850 --> 00:08:47,710 +فيه؟ تلاتة، تلاتة، احنا بدنا نعلمكوا العد، تلاتة، + +90 +00:08:47,710 --> 00:08:49,670 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +91 +00:08:49,670 --> 00:08:51,370 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +92 +00:08:51,370 --> 00:08:58,720 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تهي الديهيد و + +93 +00:08:58,720 --> 00:09:02,360 +أكتر من جمعة أواتش هذا بنقول عنه تيتروز تيتروز + +94 +00:09:02,360 --> 00:09:09,430 +يعني سكر إيش من أربع كربونات طب لو كانوا خمسةبنتوز + +95 +00:09:09,430 --> 00:09:14,530 +لو كانوا ستة هكسوز طبعا هذه كلها اللي موجودة عندنا + +96 +00:09:14,530 --> 00:09:20,150 +لأن الجزء الأول فيها الديهيد they are all doses طب + +97 +00:09:20,150 --> 00:09:25,830 +لو كان فيها كيتون برضه هذا تتروز وبنتوز وهكسوز لكن + +98 +00:09:25,830 --> 00:09:31,590 +هذه ايش كيتوز واضح؟ الان كل واحد هياخد اسم تفصيلي + +99 +00:09:31,590 --> 00:09:36,490 +بس بشكل عام ممكن السكر يكون من تلات ذرات من أربعة + +100 +00:09:36,490 --> 00:09:41,610 +من خمسة من ستةيعني هدولة خلينا نقول الاش المشهورين + +101 +00:09:41,610 --> 00:09:48,410 +الآن لو بدنا نتطلع في ال sugars و اتطلعنا على أبسط + +102 +00:09:48,410 --> 00:09:54,770 +واحد فيهم ال glyceraldehyde ع طول هنلاحظ أن هذا ال + +103 +00:09:54,770 --> 00:10:00,310 +glyceraldehyde فيه chiral center يعني لو اتطلعنا + +104 +00:10:00,310 --> 00:10:03,210 +ال C double bond OH اللي هو جزء ال aldehyde هذا + +105 +00:10:03,210 --> 00:10:06,090 +مافيش فيه chiral center ال chiral center أربع + +106 +00:10:06,090 --> 00:10:12,980 +مجموعاتمختلفة، الآن ال CH2OH الأخيرة مافيها chiral + +107 +00:10:12,980 --> 00:10:19,460 +center، الكاربون الوسطني هاديفيها chiral center + +108 +00:10:19,460 --> 00:10:22,940 +الكربون الوسطاني اللي موجود عندنا فيها chiral + +109 +00:10:22,940 --> 00:10:28,920 +center الآن لاحظوا معي انه في ال sugars في ال + +110 +00:10:28,920 --> 00:10:34,760 +sugars هذه جزيئات شوية كبيرة وكل واحد ممكن يرسمها + +111 +00:10:34,760 --> 00:10:38,880 +بطريقة معينة يعني واحد ممكن يرسم واقف نايم مائل + +112 +00:10:38,880 --> 00:10:45,000 +عشان يسهلوا تبعون ال biochemistry على بعض المتابعة + +113 +00:10:45,000 --> 00:10:52,080 +اتفقواإنه يوحدوا طريقة الرسم، يعني ليش أضلني أتعب + +114 +00:10:52,080 --> 00:10:55,680 +الطالب مرة أحط مجموعة الالديهايد يمين، مرة شمال، + +115 +00:10:55,680 --> 00:10:59,820 +مرة فوق، مرة تحت، بره أرسم الجزء مائل، في كل لحظة + +116 +00:10:59,820 --> 00:11:04,670 +هو بيصير بحاجة إلىمزيد من التفكير و من الوقت عشان + +117 +00:11:04,670 --> 00:11:10,530 +يفهم إيش شكل الجزء فقالوا إيش المانع؟ إيش المانع؟ + +118 +00:11:10,530 --> 00:11:15,910 +إن نوحد طريقة الرسم لما نرسم ال sugars بدل ما كل + +119 +00:11:15,910 --> 00:11:18,650 +واحد يرسمه بطريقة معينة و نقعد نقول وين ال + +120 +00:11:18,650 --> 00:11:22,350 +aldehyde وين ال OHS وين ال chiral center ليش ما + +121 +00:11:22,350 --> 00:11:29,310 +نرسم بطريقة موحدة؟بنسهل على الناس تمام؟ طيب إيش + +122 +00:11:29,310 --> 00:11:33,910 +فكرة الرسم بالطريقة الموحدة؟ جال خلّي المجموعة + +123 +00:11:33,910 --> 00:11:37,210 +اللي هي الكبيرة ال carbon اللي حاملة أعلى إشي اللي + +124 +00:11:37,210 --> 00:11:42,630 +هي ال aldehyde تكون لفوق و ارسم بهذا الشكل العمودي + +125 +00:11:42,630 --> 00:11:46,950 +واضح؟ يعني نخلي مجموعة ال aldehyde أو ال keto اللي + +126 +00:11:46,950 --> 00:11:54,970 +وجدت لأعلى و بنرسم بشكل عموديطبعا اخر شئ هنا هيكون + +127 +00:11:54,970 --> 00:12:03,090 +عندى CH2OH الان ايش ضال عندى على الوسط OH OH ضال + +128 +00:12:03,090 --> 00:12:09,030 +عندى في الوسط OH OH هذه ال OH OH بالتأكيد طالما + +129 +00:12:09,030 --> 00:12:14,830 +هذا chiral center هيكون فيه الجزئ و صورتهفى + +130 +00:12:14,830 --> 00:12:18,490 +المراية حيكون عند الجزء و صورته فى المراية لو + +131 +00:12:18,490 --> 00:12:22,630 +جربنا ان نشوف ال configuration إيه لو جربنا نشوف + +132 +00:12:22,630 --> 00:12:29,390 +ال configuration إيه هتتذكروا ان هذه أقل مجموعة و + +133 +00:12:29,390 --> 00:12:33,570 +ال oxygen أعلى مجموعة بعدين الكاربون اللى متصل + +134 +00:12:33,570 --> 00:12:37,490 +مرتين بال oxygen بعدها بعدين الكاربون اللى متصل + +135 +00:12:37,490 --> 00:12:41,830 +مرة بال oxygen وبناء على ذلك لو أنا بدي أمشي هى + +136 +00:12:41,830 --> 00:12:50,270 +نمره واحدنمرة اتنين، نمرة تلاتة، مبينة كإنها S، + +137 +00:12:50,270 --> 00:12:54,830 +لكن لأن هذه المجموعة الصغيرة للأمام، بنعكس ال + +138 +00:12:54,830 --> 00:13:01,270 +configuration، إذن هذا Rوبالتجربة ال R طلع بلس + +139 +00:13:01,270 --> 00:13:04,390 +بتذكرين لما قولنا ال plus و ال minus هذا من قصة + +140 +00:13:04,390 --> 00:13:09,330 +بالتجربة بال بولاريمتر الآن هذا بالتأكيد ال + +141 +00:13:09,330 --> 00:13:13,490 +enantiomer التاني هو ال S فبناء على ذلك ال + +142 +00:13:13,490 --> 00:13:19,650 +glyceraldehyde طالما في one chiral center إذا في + +143 +00:13:19,650 --> 00:13:27,060 +منه كام مركب اتنين R و Sالان تابعون ال + +144 +00:13:27,060 --> 00:13:32,020 +biochemistry قالوا احنا بنحب الخصوصية مش حابين + +145 +00:13:32,020 --> 00:13:36,580 +نظلنا مربوطين في جماعة الكيميا طب ليش يا عم + +146 +00:13:36,580 --> 00:13:41,800 +بتزيدوا غلبتنا قال بهمش الطلاب بتحملونا ايش اللي + +147 +00:13:41,800 --> 00:13:48,740 +بدكمياه قال بدل ما نستعمل ال R و ال S نستعمل D و L + +148 +00:13:50,330 --> 00:13:54,210 +هما لو ضالوا على ال R و ال S العلم بيمشي لكن قرروا + +149 +00:13:54,210 --> 00:13:59,650 +انهم بيستعملوا D و L الآن ضمن هذا الشكل اللي رسمنا + +150 +00:13:59,650 --> 00:14:02,450 +فيه يعني المجموعة هذه ال الدياد أو ال keto اللي + +151 +00:14:02,450 --> 00:14:07,630 +فوق قالوا إذا كانت ال OH على ال carbon اللي هي قبل + +152 +00:14:07,630 --> 00:14:10,770 +الأخيرة منها يعني هي أخر carbon من تحتها دي اللي + +153 +00:14:10,770 --> 00:14:16,010 +قبلها إذا كانت ال OH على اليمين بنعطي للمركب الرمز + +154 +00:14:16,500 --> 00:14:22,460 +وإذا كانت الـ OH على الشمال بنعطي المركب الرمز L + +155 +00:14:22,460 --> 00:14:27,540 +فصيرنا نقول هذا دي إجليسرال ديهيد وهال و هذا + +156 +00:14:27,540 --> 00:14:33,000 +الإجليسرال ديهيد الآن هم ركزوا على أي كاربون + +157 +00:14:33,000 --> 00:14:38,980 +تحديدا حاملة الـ OHالـ OH اللي جابلي الأخيرة، ليش؟ + +158 +00:14:38,980 --> 00:14:42,820 +لأنه بعد شوية .. بعد شوية حيصير عندى أكثر من + +159 +00:14:42,820 --> 00:14:47,580 +Carbon بتحمل OH OH OH OH و أكثر من chiral center + +160 +00:14:47,580 --> 00:14:52,680 +مين فيهم اللي بدي أوصفه أنه D أو L؟ وين بدي أطلع؟ + +161 +00:14:52,680 --> 00:14:56,940 +بدي أطلع مش على آخر Carbon، آخر Carbon مش chiral + +162 +00:14:56,940 --> 00:15:02,660 +أول Carbon chiral من تحت، اللي هي نمرة 2، لأن هو + +163 +00:15:02,660 --> 00:15:08,570 +اللي مش chiralواضح فلما انا بدي بعد شوية اصير اطلع + +164 +00:15:08,570 --> 00:15:15,310 +هيك على شكله و اقول هذا D ولا L بدي اطلع وين من + +165 +00:15:15,310 --> 00:15:23,190 +التحت طبعا هنا في عندي scheme كيف ببدأ انا ازيد في + +166 +00:15:23,190 --> 00:15:28,070 +مجموعات ال OH يعني اول ما بدأت تلاتة بعد هيك ببدأ + +167 +00:15:28,070 --> 00:15:34,930 +ازيد واضح انه هذا ال scheme يمكناضعيف جدا و لذلك + +168 +00:15:34,930 --> 00:15:41,230 +انا حاولت ان اجزء هذا ال scheme لأشياء لعلها تكون + +169 +00:15:41,230 --> 00:15:47,490 +أوضح لاحظوا معي بالنسبة لل glyceral dehyd هي ال OH + +170 +00:15:47,490 --> 00:15:52,200 +هنا على اليمين اذا انا جيبت بس منه ايش؟الـ D + +171 +00:15:52,200 --> 00:15:57,540 +-Glyceraldehyde الان يا ترى لو بدى ازيد كربون تانى + +172 +00:15:57,540 --> 00:16:03,280 +على ال D-Glyceraldehyde وين بدى اجي احطها؟ بهذا + +173 +00:16:03,280 --> 00:16:14,060 +الموقع واضح؟ هذه الكربون حاملةوح وح وح + +174 +00:16:14,060 --> 00:16:16,620 +وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح + +175 +00:16:16,620 --> 00:16:16,900 +وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح + +176 +00:16:16,900 --> 00:16:21,200 +وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح + +177 +00:16:21,200 --> 00:16:25,800 +وح وح وح وح وح وح وح وح وح وح وح وح وح + +178 +00:16:25,800 --> 00:16:25,920 +وح وح وح وح وح وح وح وح وح وح وح + +179 +00:16:36,210 --> 00:16:40,270 +D لكن انا ال carbon اللي زيدتها في الوسط اللي الآن + +180 +00:16:40,270 --> 00:16:43,350 +بعلم عليها بالأحمر اللي هو ال chiral center التاني + +181 +00:16:43,350 --> 00:16:49,430 +مرة حطيت فيه ال OH علي اليمين و مرة حطيت فيه ال OH + +182 +00:16:49,430 --> 00:16:54,990 +علي الشمال بناء على ذلك لما انا زيدت من تلت ذرات + +183 +00:16:54,990 --> 00:17:01,630 +لاربع ذرات من ال D اعملت كام مركب اتنين طب لو + +184 +00:17:01,630 --> 00:17:07,900 +أخدنا الجزء التاني اللي هو ال Lهتكون ال OH هذه على + +185 +00:17:07,900 --> 00:17:11,820 +اليسار و هزيد واحدة مرة يمين و مرة شمال برضه هعمل + +186 +00:17:11,820 --> 00:17:19,400 +ايش؟ اتنين واضح؟ اذا كام مركب صار عندي من الاربع + +187 +00:17:19,400 --> 00:17:23,280 +ذرات كربون اللي هو two chiral centers؟ اربع احنا + +188 +00:17:23,280 --> 00:17:30,700 +أخدنا انهعدد الـ Stereoisomers 2 to the N فلما كان + +189 +00:17:30,700 --> 00:17:35,300 +عندي one chiral center كان عندي مركبين اللي هو الـ + +190 +00:17:35,300 --> 00:17:39,740 +D-glyceraldehyde و الـ L-glyceraldehyde طب الآن + +191 +00:17:39,740 --> 00:17:42,680 +لما زيدت كمان chiral center، one chiral center و + +192 +00:17:42,680 --> 00:17:47,170 +one chiral centerصار عندى كام مُركّب؟ أربعة شومة + +193 +00:17:47,170 --> 00:17:51,770 +الأربعة في عندى هذا المُركّب لأن هذه الـ OH أول + +194 +00:17:51,770 --> 00:17:57,210 +واحدة كيرال من تحت على اليمين دي بسميه D-erythrose + +195 +00:17:58,950 --> 00:18:03,570 +تمام؟ و لأن الـ OH هذه على الشمال بيصير مركّب تاني + +196 +00:18:03,570 --> 00:18:09,070 +طبعا هذه طالما علي اليمين هتعطيني كلمة إيش؟ D دي + +197 +00:18:09,070 --> 00:18:14,070 +هذا بسميه Ethreose فصار في عندي مركّب اسمه D + +198 +00:18:14,070 --> 00:18:20,410 +-Erythrose و مركّب اسمه D-Ethreose ال Erythrose زي + +199 +00:18:20,410 --> 00:18:24,570 +ما بتلاحظوا اللي موجودة فيه الـ OH التاني على + +200 +00:18:25,670 --> 00:18:31,110 +اليمين والثريوز اللي موجودة فيه هذه على اليسار طب + +201 +00:18:31,110 --> 00:18:36,720 +الأن وين المركبين التانيين؟الـ L اللي هم الـ L لما + +202 +00:18:36,720 --> 00:18:40,320 +بدي الـ L شو بدي أعمل بهدي؟ بدي أعكسها يعني أنا + +203 +00:18:40,320 --> 00:18:45,060 +هنا جايب نص الصورة جايب ال D زي ما فيه D بتاخدوا + +204 +00:18:45,060 --> 00:18:49,880 +نفس الجزيه تماما و بس بنعكس منه إيش الـ OH الـ OH + +205 +00:18:49,880 --> 00:18:55,720 +الخضرة أول واحدة كايرال من تحت طبعا هي بتكون تاني + +206 +00:18:55,720 --> 00:18:59,780 +واحدة لإن هذه مش كايرال هي أول واحدة كايرال من تحت + +207 +00:19:01,360 --> 00:19:06,880 +واضح الفكرة؟ الآن اتخيلوا من هدول الاتنين لو بدى + +208 +00:19:06,880 --> 00:19:12,040 +ازيد كمان ذرة carbon يعني اخليهم بدل اربعة خمسة + +209 +00:19:12,040 --> 00:19:20,280 +وين هازيد ذرة ال carbon هادي؟ هنا الان من هذه لما + +210 +00:19:20,280 --> 00:19:26,720 +بدى ازيد واحدة هنا وين هتيجي؟يا يمين، يا شمال، يا + +211 +00:19:26,720 --> 00:19:29,980 +شمال، + +212 +00:19:29,980 --> 00:19:37,580 +يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا + +213 +00:19:37,580 --> 00:19:42,640 +شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، + +214 +00:19:42,640 --> 00:19:45,500 +يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا + +215 +00:19:45,500 --> 00:19:46,080 +شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، + +216 +00:19:46,080 --> 00:19:52,290 +شمال، يا شمالتمانية اتنين اقصد تلاتة تمانية الان + +217 +00:19:52,290 --> 00:19:56,950 +لو بدنا نتعرف عليهم نتعرف على نصهم اللي هم جايين + +218 +00:19:56,950 --> 00:20:02,710 +من وين من ال D هاي المركب ال D اللي توي رسمناه + +219 +00:20:02,710 --> 00:20:09,850 +طالما هذي على اليمين اذا هذا D صحيح الان بدي ازيد + +220 +00:20:09,850 --> 00:20:17,330 +كمان هذا الرباعي لأ هذا صار الخماسي حط هذه وين مرة + +221 +00:20:18,610 --> 00:20:25,130 +يمين مرة شمال، الآن هذول أعطاهم أسماء، شو أعطاهم؟ + +222 +00:20:25,130 --> 00:20:31,490 +دي رايبوز وهذا دي أرابينوز، ليش دي؟ لأنه هذي + +223 +00:20:31,490 --> 00:20:36,690 +عاليمين، الآن بنصير نقول شو هو الرايبوز؟ الرايبوز + +224 +00:20:36,690 --> 00:20:40,790 +السكر الخماسي اللي تلت مجموعات ال OH في جين ع جهة + +225 +00:20:40,790 --> 00:20:46,690 +واحدةالان الارابينوز الشو هو السكر الخماسي اللى + +226 +00:20:46,690 --> 00:20:50,930 +هدولة بتنتنع جهة وادي على جهة تانية لحظوا قاعدة + +227 +00:20:50,930 --> 00:20:57,170 +بتكتر المراكبات عندى هذا خمس درات كربون واحد اتنين + +228 +00:20:57,170 --> 00:21:02,690 +تلاتة اربعة خمسة بكم chiral center تلاتة طالما + +229 +00:21:02,690 --> 00:21:07,410 +عندى تلاتة chiral center اذا كم مركب تمانية وين + +230 +00:21:07,410 --> 00:21:16,070 +التمانية4D و 4R بالظبط واضحة؟ + +231 +00:21:16,070 --> 00:21:22,770 +انا هنا بس أخدت الاريثروز و جسمته يتبعوا معاك هذا + +232 +00:21:22,770 --> 00:21:28,590 +بس اللي نتج من الاريثروز لما أجسم للثريوز بيعطيني + +233 +00:21:28,590 --> 00:21:35,410 +كمان اتنين اتنين و اتنين اربع اربع و هكذا واضح؟ + +234 +00:21:35,410 --> 00:21:36,430 +هاي للثريوز + +235 +00:21:40,860 --> 00:21:44,360 +خلّينا هذا اللي اتعودنا نقول عنه دي نخليه باللون + +236 +00:21:44,360 --> 00:21:48,780 +الأخضر هذا السكر التالي الاثريوز مش احنا قولنا + +237 +00:21:48,780 --> 00:21:57,060 +الاريثروز و الاثريوز الاريثروز بيقسم لاتنين هايهم + +238 +00:21:57,060 --> 00:22:01,760 +و الاثريوز بيقسم لاتنين تانين الان الاتنين اللي + +239 +00:22:01,760 --> 00:22:05,820 +بيقسملهم الاثريوز بياخدوا اسم اكزايلوز و لاكزوز + +240 +00:22:07,610 --> 00:22:13,030 +فصار المجموع من الخماسي اربعة D و اربعة L كده؟ + +241 +00:22:13,030 --> 00:22:19,030 +تمانية لو جينا اي واحد من هدولة بدنا نزيد له + +242 +00:22:19,030 --> 00:22:25,250 +chiral center هيقسم لإيش؟ لاتنين طالما وما تمانية + +243 +00:22:25,250 --> 00:22:29,290 +كل واحد يقسم لاتنين هيصير المجموع ستة عشر كلام + +244 +00:22:29,290 --> 00:22:32,650 +منطقي ليش؟ لأنه لما يصير عند اربعة chiral centers + +245 +00:22:32,650 --> 00:22:39,090 +اتنين اقص اربعة16 16 اتنين اقصى اربعة ستة عشر فلما + +246 +00:22:39,090 --> 00:22:43,230 +نيجي نتعرف عليهم لما نيجي نتعرف عليهم لو أخدنا + +247 +00:22:43,230 --> 00:22:49,250 +مثلا الريبوز هاي ال O H هذه العملة دي و زيدنا + +248 +00:22:49,250 --> 00:22:53,690 +كايرة ال center وين هنا + +249 +00:22:53,690 --> 00:23:01,730 +هذا هيعمل O H مرة يمين و مرة شمال + +250 +00:23:03,120 --> 00:23:07,240 +لو أخدنا الأرابينوز برضه وين بدنا نزيد الـ OH؟ + +251 +00:23:07,240 --> 00:23:14,580 +هنا، هتيجي مرة يمين و مرة شمال، الآن هدولة بنبدأ + +252 +00:23:14,580 --> 00:23:19,980 +نعطيهم أسماء اللي كلهم جايين زي بعض سموه ألوز، هذا + +253 +00:23:19,980 --> 00:23:25,360 +تلاتة و بعدين واحدة زي بعض ألتروز، هذا الجولوكوز + +254 +00:23:25,360 --> 00:23:31,300 +صاحبنا، اللي بدأ تحفظ الجولوكوزيعني منهم كلهم بدنا + +255 +00:23:31,300 --> 00:23:34,860 +نقولكوا بس احفظوا الجولوكوز كيف ترتيب مجموعاته + +256 +00:23:34,860 --> 00:23:39,960 +طبعا اللي بدها تحفظ الجولوكوز بدها تقولوا one and + +257 +00:23:39,960 --> 00:23:44,440 +six carbonate صحيح؟ الآن الـC double bond OH + +258 +00:23:44,440 --> 00:23:51,400 +الالديهيد هذه لفوق أكيد مافيها نقاش والـCH2OH هذه + +259 +00:23:51,400 --> 00:23:59,040 +لتحت أكيد ولا فيها نقاش؟ الآن لو قلنا Dجولوكوز، + +260 +00:23:59,040 --> 00:24:03,900 +إيش معناه دي؟ إنه هذه لازم تكون على اليمين، الآن + +261 +00:24:03,900 --> 00:24:08,080 +في دي جولوكوز، بعد ما نحط هذه على اليمين، ضال عنده + +262 +00:24:08,080 --> 00:24:16,960 +يمين شمال يمين، ولو كنا جايلين الجولوكوز، هتخلوا + +263 +00:24:16,960 --> 00:24:22,200 +هذه تيجي هنا والباقي زي ما هوواضح؟ يعني اللي بيغير + +264 +00:24:22,200 --> 00:24:25,660 +دي و قل هذه المجموعة، هذه يمين دي، لو قلتلكوا بدي + +265 +00:24:25,660 --> 00:24:31,560 +القل جولوكوز، خدوا هذا الـD و غيروا بس هذه، إذا + +266 +00:24:31,560 --> 00:24:36,520 +كانت هذه يمين، دي جولوكوزة، الآن الخلاصة بهذا + +267 +00:24:36,520 --> 00:24:44,240 +الشكل، كم sugar طلع عنده؟16 16 sugar و الكلام + +268 +00:24:44,240 --> 00:24:49,740 +منطقي ليش من ال 6 كربونات لأن ال 6 كربونات فيهم 4 + +269 +00:24:49,740 --> 00:24:55,760 +chiral centers و المركب مش symmetric 2 أس 4 16 + +270 +00:24:55,760 --> 00:25:02,220 +الان لو بدنا هدولا ال 16 ناخد أسماءهم هاي أربعة + +271 +00:25:02,220 --> 00:25:06,020 +منهم الألوز و الألتروز و الجولوكوز و المانوز و لو + +272 +00:25:06,020 --> 00:25:12,140 +أخدنا الأربعة التانين اللي في الأساس جوا منالثريوز + +273 +00:25:12,140 --> 00:25:16,660 +الجولوز والأيدوز والجالاكتوز والتالوز الآن هذول + +274 +00:25:16,660 --> 00:25:21,460 +تمانية ايش التمانية التانية كل هذول التمانية دي + +275 +00:25:21,460 --> 00:25:30,640 +التمانية التانية ال ال واضح فبصف عندى ست عشر مركب + +276 +00:25:30,640 --> 00:25:37,340 +لل C6 لاحظوا معايا هذول الست عشر مركباخذين بعين + +277 +00:25:37,340 --> 00:25:42,040 +الاعتبار ان الجولوكوز بهذا الشكل موجود على شكل + +278 +00:25:42,040 --> 00:25:48,300 +فاتح مش مسكّر بعد شوية هانيجي نعمل ال cyclic sugar + +279 +00:25:48,300 --> 00:25:51,940 +يعني نخليه يسكّر على بعضه كيف بده يسكّر على بعضه + +280 +00:25:51,940 --> 00:25:55,340 +احنا لما شرحنا ال aldehyde قولنا لكم في عندي OH + +281 +00:25:55,340 --> 00:25:59,980 +وفي عندي aldehyde الكحول بتفعل مع ال aldehyde + +282 +00:25:59,980 --> 00:26:04,790 +يعطيني hemiacetalأخدناها كمثال فبنخلّي هذه تسكّر + +283 +00:26:04,790 --> 00:26:10,310 +هنا لو هذه سكّرت هنا هنعمل ال Cairo Center الخامس + +284 +00:26:10,310 --> 00:26:14,930 +وقت كام ايزومار حيصير عندى اذا صاروا خمس Cairo + +285 +00:26:14,930 --> 00:26:22,010 +Centers اتنين اص خمسة ايش اتنين اص خمسة اتنين + +286 +00:26:22,010 --> 00:26:28,310 +وتلاتين ايزومار واضح اتنين وتلاتين ايزومار هيكون + +287 +00:26:28,310 --> 00:26:39,230 +عندكم من ال C6من 6 ذرات كربون لاحظوا كم هو استيريو + +288 +00:26:39,230 --> 00:26:42,870 +كيميستر مهم يعني حد ما درسش استيريو كيميستر عمره + +289 +00:26:42,870 --> 00:26:48,360 +ممكن يستوعب موضوعالـ sugars مستحيل وهذا الكلام + +290 +00:26:48,360 --> 00:26:51,940 +اللي تقريبا احنا كنا حاطينه في ال scheme العام كنا + +291 +00:26:51,940 --> 00:26:57,380 +حاطين لكم كيف الزيادة one chiral center تمام + +292 +00:26:57,380 --> 00:27:01,660 +بيكونوا تنين أخدت واحد منهم اعملتله زيادة chiral + +293 +00:27:01,660 --> 00:27:06,150 +صاروايعني هن واحد و في واحد تاني موجود يعني لو حد + +294 +00:27:06,150 --> 00:27:09,690 +بده يحط ال scheme كاملا بده يجد هذا ال scheme و + +295 +00:27:09,690 --> 00:27:12,310 +يحط واحد تاني ليش؟ لأنه انا هن بدت بال D + +296 +00:27:12,310 --> 00:27:17,870 +-Glyceraldehyde فيه زيه ال glyceraldehyde و بيقسم + +297 +00:27:17,870 --> 00:27:24,430 +بنفس الشكل و بياخد نفس الأسماء طبعا لاحظوا معي أن + +298 +00:27:24,430 --> 00:27:29,740 +الأسماء الأساسية الأسماء الأساسية كام اسمتمانية + +299 +00:27:29,740 --> 00:27:36,860 +الأسماء الأساسية تمانية اللي هي موجودين + +300 +00:27:36,860 --> 00:27:40,560 +عندكم الالوز والألتروز والجولوكوز والمانوز وكذا + +301 +00:27:40,560 --> 00:27:47,020 +كذا الآن كيف التمانية بيصيروا الست عاشر طبعا + +302 +00:27:47,020 --> 00:27:51,120 +هذا الكلام بإمكانكم أنتم تجلسوا تتدربوا عليه + +303 +00:27:51,120 --> 00:27:58,200 +تقرؤوا زي ما قلنا مش ضروري أننا بدنا نحفظهالان لسه + +304 +00:27:58,200 --> 00:28:03,880 +الكيميائيين ما شبعوش يعني وصلوكوا ل 16 مركب و بدهم + +305 +00:28:03,880 --> 00:28:11,550 +ايش؟وبدهم اكتر قالوا طالما ان السكر فيه OH وفيه + +306 +00:28:11,550 --> 00:28:16,050 +الديهايد يعني الكحول و الديهايد نرجع لكيمية ال + +307 +00:28:16,050 --> 00:28:20,790 +الديهايد ماش كنا نقول ان ال الديهايد بيعمل تفاعل + +308 +00:28:20,790 --> 00:28:26,050 +addition مع الكحولات وبيعطيني hemiacetal ال OH + +309 +00:28:26,050 --> 00:28:32,420 +بتهاجم علىالـ C double bond O تبعت ال الديهايد + +310 +00:28:32,420 --> 00:28:39,080 +بتخليها OH متذكرينه التفاعل ولا نذكر فيه الناس + +311 +00:28:39,080 --> 00:28:43,340 +اللي مش متذكرينه التفاعل نكتبها لما كنا نقول مثلا + +312 +00:28:43,340 --> 00:28:51,840 +Methanol مثل OH هي نرسمه بالأسود زائد CH3C double + +313 +00:28:51,840 --> 00:29:00,510 +bond OH هي الكحول وهي إيش؟الالديهيد هذه الكحول + +314 +00:29:00,510 --> 00:29:05,190 +وهذه الالديهيد لو قلنا لكوا في الامتحان اكمل هذه + +315 +00:29:05,190 --> 00:29:08,910 +المعادلة كيف بتفعل الكحول و الالديهيد مش هذا + +316 +00:29:08,910 --> 00:29:14,550 +نيوكليوفاين بيعمل addition بيجي بها جمهان وهذا + +317 +00:29:14,550 --> 00:29:22,690 +بتصير OH وبناء على ذلك هيكون الناتج CH3C + +318 +00:29:22,690 --> 00:29:29,250 +هذا صفية OH وهذا ال H الأصلية وإيجي عندنا من هناو + +319 +00:29:29,250 --> 00:29:34,870 +مثل هذا شو سمنا Himacetal Himacetal Himacetal + +320 +00:29:34,870 --> 00:29:39,790 +Himacetal + +321 +00:29:39,790 --> 00:29:44,810 +Himacetal Himacetal Himacetal Himacetal Himacetal + +322 +00:29:44,810 --> 00:29:45,610 +Himacetal Himacetal Himacetal Himacetal Himacetal + +323 +00:29:45,610 --> 00:29:45,770 +Himacetal Himacetal Himacetal Himacetal Himacetal + +324 +00:29:45,770 --> 00:29:45,810 +Himacetal Himacetal Himacetal Himacetal Himacetal + +325 +00:29:45,810 --> 00:29:45,890 +Himacetal Himacetal Himacetal Himacetal Himacetal + +326 +00:29:45,890 --> 00:29:47,790 +Himacetal Himacetal Himacetal Himacetal Himacetal + +327 +00:29:47,790 --> 00:29:55,530 +Himacetal Himacetal Himacetal + +328 +00:29:55,530 --> 00:30:07,430 +Himacetal HimacetHemiacetal OR و OR أسيتال، الآن + +329 +00:30:07,430 --> 00:30:12,770 +السكر فيه OH و فيه الديهايد، إيش المانع إنهم + +330 +00:30:12,770 --> 00:30:19,560 +يسكروا على بعض؟فيش مانع، وعشان هيك بيصير بيعمل + +331 +00:30:19,560 --> 00:30:23,580 +الشكل الحلقي، بنفس منطقة هذا التفاعل، يعني هذا + +332 +00:30:23,580 --> 00:30:28,440 +تفاعل تذكير كيف كان الكحول يتفاعل مع إيش؟ مع ال + +333 +00:30:28,440 --> 00:30:35,450 +الديهيد، الآن بدنا نرجع لهمفي السكر بدا نرجع للسكر + +334 +00:30:35,450 --> 00:30:41,710 +و نشوف كيف بتم هذا التفاعل هاي السكر بنرسمه بشكل + +335 +00:30:41,710 --> 00:30:46,070 +ملتوى خليكوا تطلعوا معنا هاي ال الديهايد C double + +336 +00:30:46,070 --> 00:30:50,430 +bond O و بعدين carbon حاملة OH و carbon حاملة OH و + +337 +00:30:50,430 --> 00:30:56,150 +carbon حاملة OH و هذه اللي هي ال carbon اللي كانت + +338 +00:30:56,150 --> 00:31:00,710 +معطية ال D اللي هي القبل الأخيرة + +339 +00:31:06,670 --> 00:31:14,590 +الان من ناحية المبدأ كل OH من هدوله ممكن تسكر على + +340 +00:31:14,590 --> 00:31:19,780 +ال الديهايديعني نظرياً هذه الـ OH ممكن تسكر على ال + +341 +00:31:19,780 --> 00:31:23,320 +الديهاد تعطينا حلقة ثلاثية، هذه ممكن تسكر على ال + +342 +00:31:23,320 --> 00:31:26,600 +الديهاد تعطينا حلقة رباعية، هذه ممكن تسكر على + +343 +00:31:26,600 --> 00:31:30,260 +الديهاد تعطينا حلقات خماسية، هذه ممكن تسكر تعطينا + +344 +00:31:30,260 --> 00:31:35,020 +حلقة سداسية، هذه ممكن تسكرتعطي حلقة سباعية لكن + +345 +00:31:35,020 --> 00:31:41,200 +أشهر إغلاق اللي بيعطي الحلقة السداسية فال OH اللي + +346 +00:31:41,200 --> 00:31:45,600 +بتسكر في حالة الجولوكوز هي ال OH اللي كانت تتحدد + +347 +00:31:45,600 --> 00:31:50,620 +ال D والL ال OH هذه اللي جاب للاخيرة الآن هذه بدأ + +348 +00:31:50,620 --> 00:31:56,400 +تيجي تسكر هناهيصير عندى كايرال سنتر جديد يعنى هذه + +349 +00:31:56,400 --> 00:32:01,420 +ال carbon هتعمل ايش كايرال سنتر جديد طب انا فى + +350 +00:32:01,420 --> 00:32:08,060 +الأساس كام كايرال سنتر عندى هى واحد اتنين تلاتة + +351 +00:32:08,060 --> 00:32:14,440 +اربعة ولمّا اجى اعمل هنا الإغلاق هيصيروا ايش خمسة + +352 +00:32:15,390 --> 00:32:20,530 +هيصيروا خمسة chiral centers وبناء على ذلك لاحظوا + +353 +00:32:20,530 --> 00:32:25,890 +معاه ان هدولة اللي هم ابعد عن التفاعل بيظلوا زي ما + +354 +00:32:25,890 --> 00:32:29,730 +هم لكن انا بدي اعمل generation لل chiral center + +355 +00:32:29,730 --> 00:32:33,830 +على هذا الكربون تحديدا بناء على ذلك لما بعمل + +356 +00:32:33,830 --> 00:32:37,490 +generation لل chiral center على هذا الكربون ايش + +357 +00:32:37,490 --> 00:32:43,330 +بيصير عندى؟ two enantiomersمظبوط ولا لأ؟ الان + +358 +00:32:43,330 --> 00:32:48,470 +هدولة لما بدهم يتموه طبعا مش two enantiomers أقفل + +359 +00:32:48,470 --> 00:32:51,450 +two diastereomers ليش؟ لأن أنا مش generation of + +360 +00:32:51,450 --> 00:32:55,860 +the first chiral centerاحنا قولنا two enantiomars + +361 +00:32:55,860 --> 00:33:00,960 +in equal ratios لو كان ايش؟ اول chiral center بس + +362 +00:33:00,960 --> 00:33:04,700 +هل هذا هو اول chiral center ولا نمرخمسة؟ نمرخمسة + +363 +00:33:04,700 --> 00:33:09,580 +نمرخمسة لما بنعمل chiral center اشديد second, + +364 +00:33:09,940 --> 00:33:13,600 +third, fourth, fifth chiral center شو كان يطلع + +365 +00:33:13,600 --> 00:33:18,860 +عندنا؟ اللي جيبناها سؤال في الامتحان unequal + +366 +00:33:18,860 --> 00:33:24,720 +mixture of diastereomersمتذكرينه؟ generation of a + +367 +00:33:24,720 --> 00:33:28,400 +second chiral center of a third of a fourth chiral + +368 +00:33:28,400 --> 00:33:31,640 +center produces an equal mixture of diastereomers + +369 +00:33:31,640 --> 00:33:35,320 +الألم هنا بدنا نشوف كيف هذا بده يصير chiral center + +370 +00:33:35,320 --> 00:33:41,720 +الـC ضبط هو بده تصير OH هذه الـOH مرة هتكون للأعلى + +371 +00:33:41,720 --> 00:33:50,080 +و مرة هتكون للأسفل هم + +372 +00:33:50,080 --> 00:33:54,910 +لاحظين؟هي ال chiral center مرة لفوق و مرة لتحت + +373 +00:33:54,910 --> 00:34:03,250 +واضح الفكرة؟ الآن في هذا الجزء صار عنده اللي هو ال + +374 +00:34:03,250 --> 00:34:07,930 +chiral center الخامس لحظة أنا بدأت بأي سكر؟ ال + +375 +00:34:07,930 --> 00:34:11,590 +جولوكوز ال D جولوكوز الآن ال D جولوكوز أعطاني كم + +376 +00:34:11,590 --> 00:34:18,270 +مركب؟ اتنين طب أنا كل السكريات اللي اتعرفت عليهم + +377 +00:34:18,270 --> 00:34:25,650 +قداش كانواكانوا ستة عشر تمانية D و تمانية L إذا ال + +378 +00:34:25,650 --> 00:34:30,410 +D جولوكوز أعطى اتنين الستة عشر كل واحد فيهم هيعطي + +379 +00:34:30,410 --> 00:34:34,950 +اتنين اتنين اتنين اتنين اتنين اتنين بستة عشر اتنين + +380 +00:34:34,950 --> 00:34:39,280 +و تلاتين هي الاتنين و التلاتين I زمرواضح؟ الان + +381 +00:34:39,280 --> 00:34:42,660 +هدولة اللي جدوا عندنا اجداد جايين من الجولوكوز و + +382 +00:34:42,660 --> 00:34:46,860 +جايين تحديدا من اي جولوكوز؟ من ال D جولوكوز لما + +383 +00:34:46,860 --> 00:34:50,280 +بدنا نميزهم عن بعض انتوا بتقدروا تميزهم تقولوا + +384 +00:34:50,280 --> 00:34:57,260 +واحد في ال OH لفوق واحد في ال OH لتحت الان بلغة + +385 +00:34:57,260 --> 00:35:01,880 +الكيميا بنقول اللي بيطلع بهذا الشكل و ال OH لفوق + +386 +00:35:01,880 --> 00:35:08,090 +بنسميه beta و بنحط الاسم القديممن وين هذا جاي؟ من + +387 +00:35:08,090 --> 00:35:12,070 +D جولوكوز، فصار ده Beta D جولوكوز، يعني ال Beta + +388 +00:35:12,070 --> 00:35:21,490 +اللي هي لفوق، اه، وإذا كانت لتحت؟ Alpha D جولوكوز، + +389 +00:35:21,490 --> 00:35:27,460 +واضح؟الان مرة تانية عشان تبعون ال biochemistry + +390 +00:35:27,460 --> 00:35:33,080 +اسهلوا على نفسهم هذه الحلقة السوداسية يمكن ان ترسم + +391 +00:35:33,080 --> 00:35:37,660 +بإيش بطرق كتير مختلفة يعني ممكن تخلوا ال oxygen + +392 +00:35:37,660 --> 00:35:42,380 +هان هان هان اعتادوا انهم يرسموها بهذا الشكل اللي + +393 +00:35:42,380 --> 00:35:47,920 +موجود أمامكم يعني بدكوا ترسموها حلقة سوداسية بهذا + +394 +00:35:47,920 --> 00:35:52,680 +الشكل وتجددوا انكوا تحطوا ال oxygen وين؟ع هذا + +395 +00:35:52,680 --> 00:35:58,660 +الموقع وبناء على ذلك واجتها بنقول ان الكاربون اللي + +396 +00:35:58,660 --> 00:36:03,320 +ماكنتش كايرال سنتر وصارت كايرال سنتر هي اي كاربون؟ + +397 +00:36:03,320 --> 00:36:09,600 +هذه عشان الناس مايتخربطوش بطريقة الرسم ترسم الحلقة + +398 +00:36:09,600 --> 00:36:14,140 +السوداسية عادة في ال biochemistry بهذا الشكل ال + +399 +00:36:14,140 --> 00:36:19,640 +oxygen اللي سكرت هي هان هذه الكاربون اللي كانت + +400 +00:36:20,700 --> 00:36:28,460 +الديهايد ماكنتش كايرال سنتر صارت كايرال سنتر واضح؟ + +401 +00:36:28,460 --> 00:36:33,560 +هيهانة قبل ما يسكركانت كايران ولا لأ؟ لأ كان + +402 +00:36:33,560 --> 00:36:37,960 +المركب .. كم كايرال سنتر فيه؟ كانوا أربعة و هذه + +403 +00:36:37,960 --> 00:36:41,940 +زادت .. هايهم الكايرال سنتر الأربعة و هذه زادت + +404 +00:36:41,940 --> 00:36:47,260 +صاروا كدهش؟ خمسة واضح؟ الآن هذه الكاربون اللي + +405 +00:36:47,260 --> 00:36:52,440 +ماكنتش كايرال سنتر كانت الديهايد و صارت كايرال + +406 +00:36:52,440 --> 00:36:57,560 +سنتر إلها اسم بنسميها Anomeric Carbon + +407 +00:36:59,780 --> 00:37:05,500 +انوميرك كاربون انوميرك كاربون انوميرك كاربون + +408 +00:37:05,500 --> 00:37:07,800 +انوميرك كاربون انوميرك كاربون انوميرك كاربون + +409 +00:37:07,800 --> 00:37:08,020 +انوميرك كاربون انوميرك كاربون انوميرك كاربون + +410 +00:37:08,020 --> 00:37:10,440 +انوميرك كاربون انوميرك كاربون انوميرك كاربون + +411 +00:37:10,440 --> 00:37:12,440 +انوميرك كاربون انوميرك كاربون انوميرك كاربون + +412 +00:37:12,440 --> 00:37:12,540 +انوميرك كاربون انوميرك كاربون انوميرك كاربون + +413 +00:37:12,540 --> 00:37:16,080 +انوميرك كاربونالكاربون اللي عملت الكايرال سنتر + +414 +00:37:16,080 --> 00:37:20,660 +الجديد كانوا أربعة صاروا إيش؟ خمسة، مين اللي عملت + +415 +00:37:20,660 --> 00:37:24,960 +الكايرال سنتر الجديد؟ هذه تبعت ال الديهايد بسميها + +416 +00:37:24,960 --> 00:37:30,100 +Anomeric Carbon، الآن إذا الكايرال سنتر هذا الجديد + +417 +00:37:30,730 --> 00:37:36,350 +أجت فيه مجموعة الـ OH لأعلى بقول هذا Beta Sugar + +418 +00:37:36,350 --> 00:37:41,070 +وإذا أجت لأسفل Alpha Alpha بيضلوا ماخد نفس الاسم + +419 +00:37:41,070 --> 00:37:45,630 +اللي هو الـ D والجولوكوز اللي هو يعبر عن كل + +420 +00:37:45,630 --> 00:37:52,230 +الترتيبات هذه واضح؟ الآن طالما كانوا 16 وكل واحد + +421 +00:37:52,230 --> 00:37:59,750 +بدأ أعمل منهAlpha و Beta قداش حيصيروا 32 طبعا + +422 +00:37:59,750 --> 00:38:04,570 +بتكونوا منتبهين أن الأسماء الأساسية في ال sugars + +423 +00:38:04,570 --> 00:38:11,990 +قداش تمانية واضحة الفكرة الأسماء الأساسية اللي هي + +424 +00:38:11,990 --> 00:38:16,330 +جولوكوز و جولاكتوز و ألوز و ما إلى ذلك كام اسم + +425 +00:38:16,330 --> 00:38:20,750 +تمان أسماء يعني خليني أوضحلكوا الصورة مرة أخيرة + +426 +00:38:24,310 --> 00:38:29,390 +تمان أسماء أساسية الان هدولة تمان أسماء أساسية كل + +427 +00:38:29,390 --> 00:38:35,690 +اسم فيه منه D و L و بعد هيك كل اسم بيصير ايش فيه + +428 +00:38:35,690 --> 00:38:44,130 +منه Alpha هذا بيكون Alpha D و Beta D و هذا بيصير + +429 +00:38:44,130 --> 00:38:51,510 +منه Alpha L و Beta L واضح؟ هي هذا كده صفة منه؟ + +430 +00:38:51,510 --> 00:38:58,660 +أربعةيعني لو قولنا من الجولوكوز الجولوكوز + +431 +00:38:58,660 --> 00:39:02,800 +واحد منهم في Alpha D جولوكوز و Beta D جولوكوز + +432 +00:39:02,800 --> 00:39:09,440 +Alpha L جولوكوز و Beta L جولوكوز و من كل واحد + +433 +00:39:09,440 --> 00:39:14,200 +موجودة نفسها للتقسيمة طالما تمان أسماء أساسية في + +434 +00:39:14,200 --> 00:39:23,300 +أربعرموز صفر العدد لكل جداش 32 سكر في حالة ما كان + +435 +00:39:23,300 --> 00:39:30,020 +السكر إيه اشماله؟ Cyclic لكن لو كان acyclic بس + +436 +00:39:30,020 --> 00:39:34,620 +بنصفة ال 16 لأنه ماعملناش ال chiral center الخامس + +437 +00:39:34,620 --> 00:39:39,100 +اللي هو ماهيكون جولوكوز D و L جلاكتوز D و L مانوز + +438 +00:39:39,100 --> 00:39:47,570 +D و L و هكذا إذا كان acyclicالسكر السداسي بيكون + +439 +00:39:47,570 --> 00:39:53,750 +العدد الكلي 16 وإذا كان Cyclic بيكون العدد الكلي + +440 +00:39:53,750 --> 00:40:00,490 +32 الآن في ال A Cyclic تمان أسماء كل واحد بيقسم D + +441 +00:40:00,490 --> 00:40:08,530 +و L في ال Cyclic كل D و كل L بتقسم إلى ألفة و بيتا + +442 +00:40:08,530 --> 00:40:12,550 +الان + +443 +00:40:12,550 --> 00:40:18,700 +انتبهوا معيقلنا احنا انه لما يتكون هذا الدياستيريو + +444 +00:40:18,700 --> 00:40:23,460 +مارس بيكونوا ب equal ratios ولا unequal ratios؟ + +445 +00:40:23,460 --> 00:40:30,200 +unequal ratios الان اللي طلع عندنا حقيقة ان ال + +446 +00:40:30,200 --> 00:40:37,520 +beta بيطلع بنسبة 64% و ال alpha من الجولوكوس بيطلع + +447 +00:40:37,520 --> 00:40:45,380 +بنسبة 36% واضح؟طبعا ال beta لحاله له زاوية دوران + +448 +00:40:45,380 --> 00:40:51,420 +plus 19 و ال alpha لحاله لو فصلوا له زاوية دوران + +449 +00:40:51,420 --> 00:40:59,120 +112 الان لو حطيت الخليط تبعهم بطلع زاوية بين + +450 +00:40:59,120 --> 00:41:02,700 +التنتين ماخدة نسبة بعين الاعتبار الخليط بطلع + +451 +00:41:02,700 --> 00:41:10,450 +زاويته حقيقة 52لاحظوا معي، الآن هذا كله اتزان، هذا + +452 +00:41:10,450 --> 00:41:15,750 +كله ايش؟ اتزان، بمعنى، لو أنا بدأت في هذا الـA + +453 +00:41:15,750 --> 00:41:21,390 +Cyclic و سبته في المحلول، بعد يوم، ايش هلاجيك؟ في + +454 +00:41:21,390 --> 00:41:27,090 +نسبة جليلة من الـCyclic ضايلة، سكر لهذا و لهذا، و + +455 +00:41:27,090 --> 00:41:34,670 +بنسبة 64% إلى 36%، و بخليط الزاوية تبعتهنتأكد منها + +456 +00:41:34,670 --> 00:41:47,210 +بالظبط قداش 52 52 اللي هو الاش ال mixture الخليط + +457 +00:41:47,210 --> 00:41:51,460 +اللي من هذا و من هذاالـ A Cyclic له زاوية تانية + +458 +00:41:51,460 --> 00:41:55,920 +مالنا و ماله بحكي عن الـ mixture اللي من هذا و من + +459 +00:41:55,920 --> 00:42:03,260 +هذا بيكون زاوية و قداش 52 طيب يا تورا لو حطينا الـ + +460 +00:42:03,260 --> 00:42:10,040 +A Cyclic هيسكر لإيش؟ لهدولة بنسبة 64 ل 36 طب لو + +461 +00:42:10,040 --> 00:42:16,880 +جيبنا هذا نقي و حطيناه لحاله و غيبنا عنه يوم إيش + +462 +00:42:16,880 --> 00:42:24,640 +بيعمل؟لا بيعمل اشي هذا في حالة اتزان مع الفاتح + +463 +00:42:24,640 --> 00:42:32,760 +الان نتيجة الاتزان بيفتح لما بيفتح بيسكر من اول و + +464 +00:42:32,760 --> 00:42:38,520 +جديد بالجهتين وبناء على ذلك لو اجينا حاطينا هذا + +465 +00:42:38,520 --> 00:42:43,480 +المسكر و سبناه يوم هو في اتزان مع الفاتح فتح سكر + +466 +00:42:43,480 --> 00:42:46,920 +اشمال يمين اشمال يمين بعد يوم بنلاقي ايش الناس + +467 +00:42:46,920 --> 00:42:53,530 +بصفيتوجود الاتنين ال alpha و ال beta بنفس النسبة + +468 +00:42:53,530 --> 00:43:01,190 +اللي هي ال 64 ل 36 طب لو جيبنا هذا المسكر و + +469 +00:43:01,190 --> 00:43:08,250 +دوّبناه في المحلول و سيبناه يوم يومين هذا هيفتح ل + +470 +00:43:08,250 --> 00:43:13,940 +ال a cyclic ال a cyclic هيسكر من أول و جديدشمال + +471 +00:43:13,940 --> 00:43:19,640 +ويمين شمال ويمين الى ان يصل الى الاتزان 64% الى 36 + +472 +00:43:19,640 --> 00:43:25,120 +% فسواء بدأت بال A cyclic و سبته في المحلول او + +473 +00:43:25,120 --> 00:43:27,880 +بدأت بهذا و سبته في المحلول او بدأت بهذا و سبته في + +474 +00:43:27,880 --> 00:43:33,760 +المحلول اصل لنفس الخليط نفس النتيجة هذه العملية + +475 +00:43:33,760 --> 00:43:39,670 +الحقيقة بيسموها mutarotationلحظة الميوتا روتيشن هي + +476 +00:43:39,670 --> 00:43:44,070 +التغيير في الروتيشن الأبطالي بسبب تغيير الانو مارس + +477 +00:43:44,070 --> 00:43:53,290 +هدولة .. هدولة التنين الجداد بنسميهم احنا ايش؟ انو + +478 +00:43:53,290 --> 00:43:58,300 +مارساللي جايين من ال anomeric carbon اللي اختلفوا + +479 +00:43:58,300 --> 00:44:03,420 +في one chiral center واضح؟ يعني ال anomer beta + +480 +00:44:03,420 --> 00:44:07,860 +بيصير ال anomer alpha و ال anomer alpha بيصير ال + +481 +00:44:07,860 --> 00:44:12,560 +anomer beta لو حطيت ال alpha بصف على اتزان من + +482 +00:44:12,560 --> 00:44:17,120 +alpha و betaو لو حطيت ال beta بصف على اتزان من + +483 +00:44:17,120 --> 00:44:21,080 +alpha و beta و بنفس النسبة هذه العملية اللي احنا + +484 +00:44:21,080 --> 00:44:24,420 +بنسميها ايش ال mutation rotation لما احط ال alpha + +485 +00:44:24,420 --> 00:44:27,300 +و اكون جسد في ال polarimeter راح لاحظ ان الزاوية + +486 +00:44:27,300 --> 00:44:32,680 +في أولها 146 بعد شوية بتجل بتجل بتجل اخر مابتصف + +487 +00:44:32,680 --> 00:44:40,550 +يداش 52 لو حطيت ال betaالزاوية 19 بضلني اديس معي + +488 +00:44:40,550 --> 00:44:46,990 +الزمن بتضل ازيد ازيد ازيد اخر ما بتصفح 52 هذا + +489 +00:44:46,990 --> 00:44:52,390 +التغير في ال rotation إلى أن يصل 52 يعني إذا بدأت + +490 +00:44:52,390 --> 00:44:57,960 +من هنا ستصل ل 52 وإذا بدأت من هنا ستصل ل 52هذا ايش + +491 +00:44:57,960 --> 00:45:03,260 +بنسميه احنا ميوتا روتيشن اللي هو نشوف ايش تعريفه + +492 +00:45:03,260 --> 00:45:06,920 +is the change in optical rotation التغيير في ال + +493 +00:45:06,920 --> 00:45:09,780 +optical rotation due to inter conversion of + +494 +00:45:09,780 --> 00:45:13,360 +animals ان ال alpha بتصير a cyclic و بترجع تصير + +495 +00:45:13,360 --> 00:45:17,540 +alpha و beta in solution it is explained by the + +496 +00:45:17,540 --> 00:45:22,980 +equilibriumبالفسيرة بإيش أنه في اتزان أنه ال beta + +497 +00:45:22,980 --> 00:45:26,080 +بيفتح و بسكر alpha و beta ال alpha بيفتح و بسكر + +498 +00:45:26,080 --> 00:45:31,560 +alpha و beta و بنفس إيش الإتزان طبعا بإمكانهم + +499 +00:45:31,560 --> 00:45:34,680 +يعملوا حسابات احنا مش موضوعنا الحسابات احنا + +500 +00:45:34,680 --> 00:45:38,840 +موضوعنا ببساطة الآن أنه في عندنا سواء بدأت ب alpha + +501 +00:45:38,840 --> 00:45:44,980 +أو beta بالمحلول هاصل إلى إيش إلى الاتزان هذا + +502 +00:45:44,980 --> 00:45:53,110 +الاتزان 64%Beta و 36% Alpha ايش معناه؟ معناه ان ال + +503 +00:45:53,110 --> 00:45:57,810 +.. which is more stable ال Beta ولا ال Alpha؟ ال + +504 +00:45:57,810 --> 00:46:03,190 +Beta طبعا هم بيفسروا على انه لو رسمنا السكر على + +505 +00:46:03,190 --> 00:46:08,310 +شكل الكرسي مش السكر Cyclohexane في النهاية بتكون + +506 +00:46:08,310 --> 00:46:14,250 +ال OH في ال Beta equatorial يعني غير مزدحمة واضح؟ + +507 +00:46:14,250 --> 00:46:18,690 +هذه ال OH لا تعاني ازدحام، لاحظوا هذه ال OHnot + +508 +00:46:18,690 --> 00:46:24,830 +crowded غير مزحمة الان هذه ال اواتش اللي طلع عليها + +509 +00:46:24,830 --> 00:46:33,450 +crowded مزحمة عشان هيك هو بفضل يكون في ال beta ولا + +510 +00:46:33,450 --> 00:46:39,170 +في ال alpha بالنسبة أعلى في ال beta بهيك بننهي + +511 +00:46:39,170 --> 00:46:43,430 +اليوم هذا الجزء و المرة اللي جاي ان شاء الله + +512 +00:46:43,430 --> 00:46:44,510 +بنستكمل + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..b2d29e36e6f8d02109402a5c468973c99093cb09 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_postprocess.srt @@ -0,0 +1,2104 @@ +1 +00:00:19,590 --> 00:00:24,930 +بسم الله الرحمن الرحيم في موضوع الفصل التاسع ال + +2 +00:00:24,930 --> 00:00:30,170 +aldehydes و ال ketones اعطينا المرة الماضيةمقدمة، + +3 +00:00:30,170 --> 00:00:34,890 +إيش معناه ال carbonyl compounds؟ ليش قسمناهم + +4 +00:00:34,890 --> 00:00:39,150 +لصنفين أساسيين؟ يعني ليش حاطينا ال aldehydes و ال + +5 +00:00:39,150 --> 00:00:44,330 +ketones لحال و الأحماض و مشتقاتها لحال؟ السبب يعود + +6 +00:00:44,330 --> 00:00:47,690 +لطبيعة التفاعل الكيميائي اللي هم ال aldehydes و ال + +7 +00:00:47,690 --> 00:00:51,890 +ketones بتفاعلوا بالإضافة، الأحماض و مشتقاتها + +8 +00:00:51,890 --> 00:00:58,000 +بتفاعلوابالإبدال حكينا عن الخواص الفيزيائية لل + +9 +00:00:58,000 --> 00:01:02,560 +الديهايد والكيتوز مقارنة بالالكوهولز مقارنة + +10 +00:01:02,560 --> 00:01:06,220 +بالالكينز هم حالة بين الالكوهولز والالكينز من + +11 +00:01:06,220 --> 00:01:09,820 +ناحية ال polarity و من ناحية ال boiling points + +12 +00:01:10,520 --> 00:01:15,120 +بعدين اتكلمنا عن التسمية قولنا ال aldehydes + +13 +00:01:15,120 --> 00:01:20,000 +بياخدوا نهاية ال و ال ketones بياخدوا نهاية on + +14 +00:01:20,000 --> 00:01:24,600 +طبعا بيميز ال aldehydes انه دائما هم على موقع واحد + +15 +00:01:24,600 --> 00:01:28,700 +فبلزمش نحط ترقيم لل ال يعني ال ال مابتكونش الا على + +16 +00:01:28,700 --> 00:01:35,440 +موقع واحد لكن لما بنبدأ نيجي على ال ketones ال + +17 +00:01:35,440 --> 00:01:41,230 +ketones بيكونوش على موقع واحد إلا نادراربما البعض + +18 +00:01:41,230 --> 00:01:47,830 +يعتقد انه نهائيا مش ممكن يكون كيتون على موقع واحد + +19 +00:01:47,830 --> 00:01:53,790 +لأ في حالات في حالات فيها كيتون على موقع واحد يعني + +20 +00:01:53,790 --> 00:01:58,870 +على سبيل المثال لو كنت بدى اشوف مركب زي هذا سيضة + +21 +00:01:58,870 --> 00:02:07,990 +بال bond O phenyl CH2 CH3هذا كيتون والـ C double + +22 +00:02:07,990 --> 00:02:12,790 +bond O تبعته جاية على موقع واحد ليش؟ لأنه أنا لما + +23 +00:02:12,790 --> 00:02:16,910 +أبدأ أسمي واحد، اتنين، تلاتة، شو بدأ أسمي هذا الـ + +24 +00:02:16,910 --> 00:02:21,910 +Ketone؟ Iprobanone على نمرة واحد ولا اتنين الـ C + +25 +00:02:21,910 --> 00:02:28,650 +double bond O؟ على واحد، اذا هذا one Iprobanone + +26 +00:02:35,810 --> 00:02:42,430 +مجموعة الفنل فبدي يصير one fennel one probanone + +27 +00:02:42,430 --> 00:02:47,330 +واضح؟ في حالات شبه بهذه الحالة ممكن يكون الكيتون + +28 +00:02:47,330 --> 00:02:53,390 +على موقع واحد بعد ذلك مثلا هنا في الاسيتون بنقول + +29 +00:02:53,390 --> 00:02:59,560 +probanone لاحظوا أكيد هتقولوا one two threeلكن + +30 +00:02:59,560 --> 00:03:04,020 +اختصرنا الاتنين لإيش؟ لأن لو جت على واحد هيصير + +31 +00:03:04,020 --> 00:03:14,560 +بروبانال و هذا المركب لبروبانون هو الاسيتون الان + +32 +00:03:14,560 --> 00:03:20,000 +هنا عندي اربع كربونات اذا بحكي انا عن بيوتانون ال + +33 +00:03:20,000 --> 00:03:23,820 +C double bond O جاية فيه على موقع اتنين من ناحية + +34 +00:03:23,820 --> 00:03:27,870 +المبدأ ايضا ممكن نختصرهالأنه مافيش غير two + +35 +00:03:27,870 --> 00:03:31,410 +butanone ضمن هذا الشكل لو إجت على موقع واحد إيش + +36 +00:03:31,410 --> 00:03:38,010 +هتصير butanane لكن مثلا ضرورية و لابد منها لو كان + +37 +00:03:38,010 --> 00:03:43,010 +عندي خمس درات كربون لإيش لأنه ممكن تكون هنا و يكون + +38 +00:03:43,010 --> 00:03:47,650 +two bentanone ممكن تكون هنا و يكون three bentanone + +39 +00:03:47,650 --> 00:03:52,050 +واضح فمن ال bentanone في عندي مركبين two bentanone + +40 +00:03:52,620 --> 00:03:57,080 +و 3 بنتانون هذا بالنسبة لل common nomenclature + +41 +00:03:57,080 --> 00:04:01,920 +الان بالنسبة لل common nomenclature هذا أبسط واحد + +42 +00:04:01,920 --> 00:04:05,340 +اسمه acetone بس بشكل عام ممكن نعمل ال common + +43 +00:04:05,340 --> 00:04:12,490 +nomenclature من خلال ان نحط نهايةketone تماما زى + +44 +00:04:12,490 --> 00:04:16,950 +ما كنا بال alcohols بنحط نهاية alcohol فكنا نذكر + +45 +00:04:16,950 --> 00:04:22,590 +المجموعة و بعدين نقول methyl alcohol إثل alcohol + +46 +00:04:22,590 --> 00:04:27,450 +بروبيل alcohol عيزو بيوتل alcohol and so on الأن + +47 +00:04:27,450 --> 00:04:32,250 +ال الديهايد مثلا كنا نقول بروبيونالديهايد + +48 +00:04:32,250 --> 00:04:36,170 +بيوتيرالديهايد يعني نحط كلمة الديهايد وين؟ في + +49 +00:04:36,170 --> 00:04:41,090 +الآخر أسيتلديهايد formaldehydeالعائلة في الآخر، طب + +50 +00:04:41,090 --> 00:04:45,310 +في ال ketones بنعمل هيك تسمية، الجواب وارد أيضا + +51 +00:04:45,310 --> 00:04:48,950 +أنه نكتب كلمة ketone في الآخر، الآن في ال ketone + +52 +00:04:48,950 --> 00:04:55,160 +عندي مش مجموعةمجموعتين ودول المجموعتين ممكن يكونوا + +53 +00:04:55,160 --> 00:05:00,680 +احيانا متشابهتين يعني هنا هذه المجموعة او هذه + +54 +00:05:00,680 --> 00:05:05,340 +المجموعة اثلو اثل اثل اثل اثل اثل اثل اثل اثل اثل + +55 +00:05:05,340 --> 00:05:11,060 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +56 +00:05:11,060 --> 00:05:13,240 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +57 +00:05:13,240 --> 00:05:14,360 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +58 +00:05:14,360 --> 00:05:16,580 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل ا + +59 +00:05:20,930 --> 00:05:26,730 +مثل مثل كيتون لاحظوا الكلام شبيه بتسمية إيش ال + +60 +00:05:26,730 --> 00:05:31,030 +ethers تسمية ال ethers يعني لو كانت هذه O كنا نقول + +61 +00:05:31,030 --> 00:05:34,570 +die ethyl ether لو كانت هذه O كنا نقول ethyl + +62 +00:05:34,570 --> 00:05:38,190 +methyl ether بنفس المنطقة ال common nomenclature + +63 +00:05:38,190 --> 00:05:43,150 +هذا ماخد أشهر أسيتون لكن in principle هل ممكن نقول + +64 +00:05:43,150 --> 00:05:48,730 +عنه die methyl ketone مافيش معنىلكن مش ماخد شهرة + +65 +00:05:48,730 --> 00:05:53,430 +يعني أشهر شئ اشتهر فيه اللي هي إيش أسيتون وبتاع + +66 +00:05:53,430 --> 00:05:56,110 +اللي كل لازم يكون عارف شكل الأسيتون يعني مفهوم + +67 +00:05:56,110 --> 00:06:01,140 +طالب في الجامعة ويقول مش عارف الأسيتونالان هذا + +68 +00:06:01,140 --> 00:06:06,820 +Cyclohexanone المرة الماضية نبهنا ان ال ketone و + +69 +00:06:06,820 --> 00:06:11,700 +ال alcohol بيجوا متصلين مباشرة بالحلقة لكن ال + +70 +00:06:11,700 --> 00:06:16,160 +dihyde و ال acid لأ بيجوا من خلال carbon و بالتالي + +71 +00:06:16,160 --> 00:06:20,780 +بياخد اسم مجموعة و لذلك هذا Cyclohexanone لو صار + +72 +00:06:20,780 --> 00:06:22,620 +OH كان صار Cyclo + +73 +00:06:43,740 --> 00:06:47,920 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +74 +00:06:47,920 --> 00:06:48,480 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +75 +00:06:48,480 --> 00:06:48,660 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +76 +00:06:48,660 --> 00:06:48,760 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +77 +00:06:48,760 --> 00:06:49,780 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +78 +00:06:49,780 --> 00:06:51,320 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +79 +00:06:51,320 --> 00:06:55,560 +هكسانول هكسانول هكسانكيتون إذا مثل فنل كيتون فلو + +80 +00:06:55,560 --> 00:07:02,660 +قلنا لكم أسيتوفينون is also called مثل فنل كيتون + +81 +00:07:02,660 --> 00:07:09,000 +هذا المركب ماخد اسم بنزوفينون اللي هو بنزنتين + +82 +00:07:09,000 --> 00:07:15,280 +وبينهم كيتون الآن لو بدي يا فنل وفنلدايفين الكيتون + +83 +00:07:15,280 --> 00:07:21,800 +دايفين الكيتون هو بنزوفينون دايفين الكيتون هو + +84 +00:07:21,800 --> 00:07:22,880 +بنزوفينون + +85 +00:07:28,220 --> 00:07:32,780 +ال IOPAC وبطريقة ال common nomenclature ولاحظوا زي + +86 +00:07:32,780 --> 00:07:36,540 +ما حكينالكم ان ال common nomenclature ليست دائما + +87 +00:07:36,540 --> 00:07:40,440 +يعني تأتي بشيء جديد، إلها نوع من ال trend خلينا + +88 +00:07:40,440 --> 00:07:44,220 +نقول يعني ال trend العام في ال common nomenclature + +89 +00:07:44,220 --> 00:07:48,740 +أن أذكر المجموعة في الأول و بعدين أذكر إيش؟ + +90 +00:07:48,740 --> 00:07:53,220 +العائلةهذا الكلام لاحظناه بال ethers فكنا نقول + +91 +00:07:53,220 --> 00:07:56,300 +ethyl او diethyl ether لاحظناه في ال alcohol كنا + +92 +00:07:56,300 --> 00:08:00,280 +نقول ethyl alcohol لاحظناه في ال aldehyde كنا نقول + +93 +00:08:00,280 --> 00:08:04,140 +مثلا أسيت لأن المجموع أسيت الأسيت الديهايد في + +94 +00:08:04,140 --> 00:08:07,500 +النهاية حطينا كلمة إيش الديهايد لاحظناه في ال + +95 +00:08:07,500 --> 00:08:16,470 +ketone, diethyl, ketone و هكذاالان لو المركبات + +96 +00:08:16,470 --> 00:08:22,770 +كبرت شوية وصار فيها اكتر من مجموعة وظيفية يعني بدأ + +97 +00:08:22,770 --> 00:08:27,590 +يلتقى في المركب الكين مع الكهول مع الديهايد مع + +98 +00:08:27,590 --> 00:08:32,920 +كيتونواجتلاع أي عائلة بدي أنسب المركب اللي عندي + +99 +00:08:32,920 --> 00:08:36,960 +حسب الأولويات اللي أخدناها في ال aromatic + +100 +00:08:36,960 --> 00:08:41,160 +compounds إذا متذكرين إنه ال alkanes أقل من ال + +101 +00:08:41,160 --> 00:08:45,420 +alkenes و ال alkynes in general أقل من ال OH أقل + +102 +00:08:45,420 --> 00:08:48,380 +من ال ketone أقل من ال aldehyde من ال acid من ال E + +103 +00:08:48,380 --> 00:08:52,880 +star فإذا طلعنا لمركبات فيها أكثر من مجموعة ربما + +104 +00:08:52,880 --> 00:08:56,830 +هذا المركب و هذا المركب بسيطينمش فيهم يعني هذا + +105 +00:08:56,830 --> 00:09:01,890 +واضح انه الديهاي واحة اتنين تلاتة اربع اذا بيوتنال + +106 +00:09:01,890 --> 00:09:06,930 +و بنذكر المجموعة الchloromethyl alphabetical و هذا + +107 +00:09:06,930 --> 00:09:11,370 +واضح انه كيتون واحد اتنين تلاتة اربع خمسة ستة اذا + +108 +00:09:11,370 --> 00:09:17,410 +هكسانون وعلى موقع تلاتة اقل ترقيم لكن مثلا هذا + +109 +00:09:17,410 --> 00:09:24,380 +المركب في كيتون وفي الكهولهيصير نهايته إيش؟ كيتون + +110 +00:09:24,380 --> 00:09:30,160 +ال alcohol وقتها بده ترجع لأصلها، إلها اسم في + +111 +00:09:30,160 --> 00:09:33,880 +الدنيا، إيش اسمها؟ Hydroxy الترقيم هيكون مع + +112 +00:09:33,880 --> 00:09:38,020 +الكيتون واحد اتنين إذا نادا two بنتانون على نمرة + +113 +00:09:38,020 --> 00:09:42,840 +أربعة موجود في مجموعة إيش؟ ال hydroxy four hydroxy + +114 +00:09:42,840 --> 00:09:47,580 +two bentanoneالان لو طلعنا على هذا المُركّب اللي + +115 +00:09:47,580 --> 00:09:51,740 +فيه تنتين C double bond O لاحظوا هذه الـ C double + +116 +00:09:51,740 --> 00:09:56,380 +bond O جنبها H الديهايد و هذه الـ C double bond O + +117 +00:09:56,380 --> 00:10:00,960 +بالكربونتين كيتون الان مين أعلى في الأولويات ال + +118 +00:10:00,960 --> 00:10:04,220 +الديهايد اذا انا هاي مُركّبي ماخد ترقيم عند ال + +119 +00:10:04,220 --> 00:10:08,020 +الديهايد واحد اتنين تلات اربعة هذه صارت مجموعة + +120 +00:10:08,020 --> 00:10:13,900 +الانيعني لو كانت هذه مش موجودة وقلنا سموا المراكب + +121 +00:10:13,900 --> 00:10:19,160 +حد سموه butanal ال .. لو سمحتوا .. butanal .. + +122 +00:10:19,160 --> 00:10:24,860 +butanal .. الان هذه السيطرة بال point O لما بتنوجد + +123 +00:10:24,860 --> 00:10:30,700 +كمجموعة بنعطيها اسم OXO واضح؟ طبعا أي واحدة اللي + +124 +00:10:30,700 --> 00:10:34,900 +أخدت OXO هذي .. هذي وين بيانت؟ بيانت في ال .. في + +125 +00:10:34,900 --> 00:10:42,800 +ال ..الديهايد وهذه فقط اللى أصبحت مجموعة كذلك + +126 +00:10:42,800 --> 00:10:46,340 +المثال اللى موجود عندنا هناك ايش المجمعتين اللى + +127 +00:10:46,340 --> 00:10:54,800 +موجودات فيه كيتونو ال keen مين أعلى في الأولوية ال + +128 +00:10:54,800 --> 00:10:58,440 +ketone أعلى في الأولوية و بناء على ذلك لما نرقم + +129 +00:10:58,440 --> 00:11:02,480 +واحد اتنين تلاتة اربعة خمسة ستة لحظة و ده هيصير + +130 +00:11:02,480 --> 00:11:09,620 +hexane on ال on على اي موقع على اتنين وال in على + +131 +00:11:09,620 --> 00:11:12,980 +تلاتة سواء كتبنا التلاتة في نص الإسم او كتبناها + +132 +00:11:12,980 --> 00:11:17,480 +قبل الإسم في نهاية كلنا فاهمين ان التلاتة تحدد + +133 +00:11:17,480 --> 00:11:25,550 +موقعالإين يعني لو حد كتب hex ثلاث إين two all صحيح + +134 +00:11:25,550 --> 00:11:35,550 +واضح هذه الأسماء في + +135 +00:11:35,550 --> 00:11:40,430 +هذه ال slide الحقيقة عندكم مجموعة كبيرة من + +136 +00:11:40,430 --> 00:11:45,550 +المركبات اللي بدكم تتعلموا كيف تسموها طبعا احنا + +137 +00:11:45,550 --> 00:11:51,060 +أخدنا أمثلة خلينا نقول كافيةفبنفيب هذه ال slide + +138 +00:11:51,060 --> 00:11:56,320 +على أساس إنكوا تدرسوها ربما أنابه فيها بس لشغلات + +139 +00:11:56,320 --> 00:12:01,720 +بسيطة أنه في ال IUPAC Nomenclature لما بنعمل احنا + +140 +00:12:01,720 --> 00:12:06,100 +الترقيم لما بنعمل الترقيم خلينا نفترض بال ال + +141 +00:12:06,100 --> 00:12:08,700 +الديهايتز وال الديهايتز بتكون ال c double bond o + +142 +00:12:08,700 --> 00:12:12,440 +تعيطة ع نمرة واحد الترقيم بيبدأ من نفس ال c double + +143 +00:12:12,440 --> 00:12:16,740 +bond oواضح يعني لما بيكون عندى الديهايد خليني + +144 +00:12:16,740 --> 00:12:21,600 +اوضحه بهذا الشكل هاي الديهايد رقم واحد وين بده + +145 +00:12:21,600 --> 00:12:28,040 +يكون هدي H هدا واحد هاي اثنين هاي تلاتة هاي اربعة + +146 +00:12:28,040 --> 00:12:34,920 +الان في نظم تسمية قديمة لما بيجوا بيحطوا نفترضها + +147 +00:12:34,920 --> 00:12:39,600 +نذرة بروم خليني نحطها نذرة بروم لو كنا بدنا نسمي + +148 +00:12:39,600 --> 00:12:39,800 +بال + +149 +00:12:43,000 --> 00:12:49,060 +على موقع اتنين هذا افترض وحطينا ذرة ايش برومين لما + +150 +00:12:49,060 --> 00:12:57,460 +ابدي اسمي بالايوبك شو هسمي المركب two bromobutanol + +151 +00:12:57,460 --> 00:13:03,780 +الان في نظام قديم لما يسموا هذا butyraldehyde اللي + +152 +00:13:03,780 --> 00:13:08,720 +هو ال common nomenclatureماشي لبيوتنال هو نفسه + +153 +00:13:08,720 --> 00:13:13,400 +بيوترالديهيد أخدناه في أول slides لما قلنا + +154 +00:13:13,400 --> 00:13:18,160 +بروبيونالديهيد وبيوتيرالديهيد الناس الشطرين اللي + +155 +00:13:18,160 --> 00:13:24,570 +بيحفظوا هاي بيوتنال بيوتيرالديهيدالان لو كنا بنسمي + +156 +00:13:24,570 --> 00:13:29,190 +فيه ال common nomenclature وبنعبر عن البروم هنا + +157 +00:13:29,190 --> 00:13:33,530 +بنعبرش بنظام الترقيم هذا لأ بنيجي بنقول والله + +158 +00:13:33,530 --> 00:13:39,150 +الموقع الأول بعد ال c double bond o بنعطيه alpha + +159 +00:13:39,150 --> 00:13:43,690 +الموقع اللي بعده beta الموقع اللي بعده gamma و + +160 +00:13:43,690 --> 00:13:48,570 +هكذا فلاحظوا ان الموقع alpha بالنسبة ل c double + +161 +00:13:48,570 --> 00:13:53,700 +bond o هو موقع ايشإتنين فلو هذا أنا بدي أسميه + +162 +00:13:53,700 --> 00:14:00,020 +butyraldehyde البرومو أين جاية عليه؟ على Alpha + +163 +00:14:00,020 --> 00:14:04,500 +فأنا بدي أجي أقول عنه Alpha Bromo يعني البرومو + +164 +00:14:04,500 --> 00:14:09,720 +جاية على موقع Alpha Butyraldehyde + +165 +00:14:09,720 --> 00:14:17,120 +واضح الفكرة؟فإذا استعملنا لوصف المواقع الجانب + +166 +00:14:17,120 --> 00:14:20,860 +السيضة بالـ bond O Alpha و Beta و Gamma أو كان + +167 +00:14:20,860 --> 00:14:24,220 +عندي أي شغل هان بقول هي بالنسبة للسيضة بال bond O + +168 +00:14:24,220 --> 00:14:29,900 +بنظام ال أيوبك على موقع اتنين بنظام ال common موقع + +169 +00:14:29,900 --> 00:14:35,440 +اتنين بيكون موقع Alpha مش Beta يعني مابنجيش نحط + +170 +00:14:35,440 --> 00:14:39,840 +Alpha هان و Beta هان لأ ال Alpha هي موقع اتنين + +171 +00:14:40,380 --> 00:14:45,300 +وبنمشي ولذلك هذا المركب مثلا واحد اتنين تلاتة حامل + +172 +00:14:45,300 --> 00:14:49,420 +OH بال .. بال IUPAC Nomenclature three + +173 +00:14:49,420 --> 00:14:57,130 +hydroxybutanol في اي مشكلة؟ three hydroxybutanolلو + +174 +00:14:57,130 --> 00:15:02,210 +كنا بدنا نسميه ايش هنسميه هى Alpha هى Beta Beta + +175 +00:15:02,210 --> 00:15:06,170 +-hydroxybutyraldehyde لاحظوا هذه اللى كتبناها EY + +176 +00:15:06,170 --> 00:15:12,910 +butyraldehyde Beta فموقع اتنين بيكون Alpha موقع + +177 +00:15:12,910 --> 00:15:18,330 +تلاتة بيكون Beta لو حد قرأ هالشغلة في يوم من + +178 +00:15:18,330 --> 00:15:21,890 +الأيام مايستغربش يعني مايفكرش ان واحد هيكون Alpha + +179 +00:15:21,890 --> 00:15:26,760 +اتنين Beta زى ما انتوا فاهمين لأ هو موقع اتنينفي + +180 +00:15:26,760 --> 00:15:32,080 +ال IUPAC بيكون Alpha في ال common nomenclature + +181 +00:15:32,080 --> 00:15:36,840 +طبعا بتيجي شغلات تانية، الان لو افترضتوا ان كان + +182 +00:15:36,840 --> 00:15:42,100 +عندكم ال ketone on طب لو صار عندكم اتنين C double + +183 +00:15:42,100 --> 00:15:49,830 +bond O ketone ايش هتستعمله؟ Dioneزي ما كان يكون ال + +184 +00:15:49,830 --> 00:15:55,330 +alcohol all كنا نستعمل die all و try all و تترا + +185 +00:15:55,330 --> 00:16:00,530 +all كذلك الحال لو كان عندنا تنتين كيتون الكيتون + +186 +00:16:00,530 --> 00:16:06,030 +الواحد on اتنين كيتون die on تلاتة كيتون try on + +187 +00:16:06,030 --> 00:16:13,030 +فهذا المركب مثلا سايكلو بنتان on ولا بنتان die on + +188 +00:16:13,030 --> 00:16:15,150 +هي on و on + +189 +00:16:18,010 --> 00:16:21,430 +Cyclopentane-dione ووجدت بلزم ان انا احط لهم ترقيم + +190 +00:16:21,430 --> 00:16:26,370 +اقل ترقيم وين موجودين اذا واحدة ع واحد التانية ع + +191 +00:16:26,370 --> 00:16:30,310 +تلاتة one three cyclopentane-dione وع نمره اتنين + +192 +00:16:30,310 --> 00:16:37,180 +حامل مثل وع اتنين حامل مثل بيصير هذا المركبتوتو + +193 +00:16:37,180 --> 00:16:43,720 +دايمثل وان ثري سايكلو بنتين دايون واضح الفكرة على + +194 +00:16:43,720 --> 00:16:48,480 +أي حال اتأملوا انتوا كتير في هذه الأسماء وفكروا + +195 +00:16:48,480 --> 00:16:52,380 +فيها لو تواجهتوا بأسئلة اسألوها ربما أحيانا + +196 +00:16:52,380 --> 00:17:00,560 +بتواجهكم مشكلة كمان في التسمية إذا وجد عندكم سلسلة + +197 +00:17:00,560 --> 00:17:07,440 +ألفتية مع حلقةلكن الأمر خلّيني أقول شبيه بالفكرة + +198 +00:17:07,440 --> 00:17:12,180 +اللي هو لو انوجد البنزين مع السلسلة الألفاتية هل + +199 +00:17:12,180 --> 00:17:21,520 +بدى أسمي نسبة للبنزين ولا نسبة للسلسلة حسب إيش + +200 +00:17:21,520 --> 00:17:26,140 +الأسهل كذلك الحال لو كان في عندى حلقة عادية مش + +201 +00:17:26,140 --> 00:17:31,650 +بنزين نفترض Cyclobutane ولا Cyclobropaneوعندي + +202 +00:17:31,650 --> 00:17:37,530 +سلسلة ألفاتية كيف أنا بدي أسمي المركب أكيد المركب + +203 +00:17:37,530 --> 00:17:45,050 +في هذه الحالة يحتمل تسميتين يعني خليني أعطيكم مثال + +204 +00:17:45,050 --> 00:17:54,610 +لو اتخيلنا هذا المثال وحطينا زي هيكوقلنالكم في + +205 +00:17:54,610 --> 00:17:59,770 +الامتحان سمي المركب التالي الان لاحظوا معي هذا + +206 +00:17:59,770 --> 00:18:07,050 +المركب فيه Cycle بروبين وفيه واحد اتنين تلاتة او + +207 +00:18:07,050 --> 00:18:13,290 +نخليهم اربعة احسن نخليهم اربعة مش مشكلة الان + +208 +00:18:13,290 --> 00:18:18,750 +بإمكاني اعمل تسميتين هل يا تورا لو سميته مشتق من + +209 +00:18:18,750 --> 00:18:31,620 +ال Cycle بروبينالمجموعة هذه إلها اسم .. + +210 +00:18:31,620 --> 00:18:38,140 +لاحظوا كل الناس .. كل الناس اللي قاعدين بعد كل + +211 +00:18:38,140 --> 00:18:43,520 +هالتعب و الشجر بيقولوا N و E هدولة من اللي بيتعبوا + +212 +00:18:43,520 --> 00:18:46,620 +القلب لسبب بسيط انه قلنا احنا من أول محاضرة + +213 +00:18:46,620 --> 00:18:52,680 +المجموعة تنتهي بنهاية YLمثل إثلبرو بالبيوت الأيزو + +214 +00:18:52,680 --> 00:18:57,020 +بيوت ال .. صح ولا لأ؟ ال .. فين ال .. المجموعة + +215 +00:18:57,020 --> 00:19:01,960 +بإيش بتنتهي؟ ب YL فكل جماعة بيوتين وبيوتين هدولة + +216 +00:19:01,960 --> 00:19:10,160 +جماعة غير مجتهدينالان مش هنيجي نحذر في القديم اللي + +217 +00:19:10,160 --> 00:19:13,800 +الناس مش متذاكرة قولنا اذا كانوا اربعة هي واحد + +218 +00:19:13,800 --> 00:19:17,960 +اتنين تلاتة اربعة والاتصال من موقع اتنين اسمها + +219 +00:19:17,960 --> 00:19:24,660 +secondary butyl ترجعوا عندكم بتلاحظوا secondary + +220 +00:19:24,660 --> 00:19:31,620 +butyl شايفين الناس اللي بدرسوش كتير secondary + +221 +00:19:31,620 --> 00:19:38,860 +butylاخدتوها بوضوح جدا سكندر بيوت الـ Cyclopropane + +222 +00:19:38,860 --> 00:19:45,020 +طيب الآن هنا اعتبرنا الأساس إيش؟ الـ Cyclopropane + +223 +00:19:45,020 --> 00:19:52,200 +هل يا تورا ممكن أننا نعتبر الأساس السلسلة؟ أكيد + +224 +00:19:52,200 --> 00:19:59,280 +لما نعتبر الأساس السلسلة، شو هنقول؟ البيوتين على + +225 +00:19:59,280 --> 00:20:04,020 +نمرأ اتنين من البيوتين، إيش عندكم؟ Cyclopropane + +226 +00:20:04,890 --> 00:20:09,350 +لحتى الآن مش عمال تقدروا تذكرواها بإنصيغة مجموعة + +227 +00:20:09,350 --> 00:20:15,030 +بزام Cyclopropane لما يصير مجموعة شو هيصير؟ + +228 +00:20:15,030 --> 00:20:21,290 +Cyclopropane اذا اتنين Cyclopropane + +229 +00:20:23,620 --> 00:20:30,420 +واضح؟ فالسكندري بيوت ال cyclopropane هو نفسه اتنين + +230 +00:20:30,420 --> 00:20:35,460 +cyclopropyl butane يعني انا لما اجيت اسميه .. انا + +231 +00:20:35,460 --> 00:20:39,800 +لما اجيت اسميه .. قولت يا تورا بدي اخلي مرجعيتي + +232 +00:20:39,800 --> 00:20:47,810 +الحلقة ولا اخلي مرجعيتي ايش؟السلسلة في هذا المركب + +233 +00:20:47,810 --> 00:20:52,470 +لأن هذه إلها اسم كمجموعة اسمها Cyclopropyl وهذه + +234 +00:20:52,470 --> 00:20:58,910 +إلها اسم secondary butyl فكانت تسميتين بالنسبة ليه + +235 +00:20:58,910 --> 00:21:05,570 +ممكنينفي هذه الحالة التسميتين بالنسبة له ممكنين بس + +236 +00:21:05,570 --> 00:21:10,990 +في مرات معينة بيكون فقط تسمية واحدة الممكنة + +237 +00:21:10,990 --> 00:21:13,950 +التسمية التانية بتصير مش ممكنة لان مافيش عنكم + +238 +00:21:13,950 --> 00:21:18,910 +مجموعات خلصنا من هذه الأشياء خليني أعطيكم مثال + +239 +00:21:18,910 --> 00:21:23,850 +مابتقدروش إلا تسموه بطريقة واحدة على نفس هذا + +240 +00:21:23,850 --> 00:21:31,670 +المثال لو إجيت يا تورا و حطيت هناأكلور و حطيت هنا + +241 +00:21:31,670 --> 00:21:44,170 +كمان بروم يعني هذه صارت إيش CH2BR و أجيتها مش + +242 +00:21:44,170 --> 00:21:48,590 +هتقدروا إلا تختاروا السلسلة ليش لأنه لو قلت + +243 +00:21:48,590 --> 00:21:56,340 +CycloPro بين الإسم طب هذه CH2BR CH CH CLالها اسم و + +244 +00:21:56,340 --> 00:22:00,800 +هتضطروا اضطرارا تختاروا ايش السلسلة الان ايش + +245 +00:22:00,800 --> 00:22:06,000 +السلسلة اللى عندكم بيوتين كام مجموعة بتحمل هذه + +246 +00:22:06,000 --> 00:22:13,560 +السلسلة بتحمل Cyclopropen بتحمل Brom بتحمل Chlor + +247 +00:22:13,560 --> 00:22:20,040 +بيحطوا مرتبين alphabetical واضح فهذه الحالة صرت + +248 +00:22:20,040 --> 00:22:26,420 +مضطر فقط ان اسمي على ايشالسلسلة او افترضوا مثلا لو + +249 +00:22:26,420 --> 00:22:38,460 +غيرنا هنا شوية خلينا هذه funnel لاحظوا + +250 +00:22:38,460 --> 00:22:41,920 +اللي بدى تفكر تسمي هذا المركب بالنسبة للبنزين + +251 +00:22:41,920 --> 00:22:49,050 +مستحيل ليش لأن هذهمالهاش اسم كمجموعة تفكر تسميه + +252 +00:22:49,050 --> 00:22:53,850 +بالنسبة للـcyclopropane صعب إيش أسهل نظام إذا تسمي + +253 +00:22:53,850 --> 00:22:58,170 +هذا المركب بالنسبة للسلسلة واحد اتنين تلاتة اربع + +254 +00:22:58,170 --> 00:23:01,930 +عليها تلات مجموعات وكل واحدة إيها اسم هذي بنعرف + +255 +00:23:01,930 --> 00:23:07,830 +اسمها Ibromo هذي بنعرف اسمها Phenyl هذي بنعرف + +256 +00:23:07,830 --> 00:23:17,100 +اسمها Cyclopropane إيش بيظل؟نذكرهم alphabetical + +257 +00:23:17,100 --> 00:23:21,120 +نذكرهم alphabetical شوفتوا كيف بنسمي هذا النوع من + +258 +00:23:21,120 --> 00:23:25,780 +المركبات إذا حيصير عندكم على سبيل المثال one + +259 +00:23:25,780 --> 00:23:32,700 +bromine two cyclopropane + +260 +00:23:32,700 --> 00:23:39,640 +three phenyl butane + +261 +00:23:43,880 --> 00:23:49,060 +واضحت الفكرة تماما + +262 +00:23:49,060 --> 00:23:57,740 +ولا فيها مشكلة الان طيب اذا هذا المثال دخل في ال + +263 +00:23:57,740 --> 00:24:03,920 +behind او كيتون يعني افترض انه خلته زي هي + +264 +00:24:13,410 --> 00:24:20,610 +ساعت بيكون بدي يكون واحد اتنين تلاتة اربعة بيوتنال + +265 +00:24:20,610 --> 00:24:27,570 +على نمرة اتنين Cyclopropyl على نمرة تلاتة فنل + +266 +00:24:27,570 --> 00:24:38,270 +وبنسميه كالديهيد او ككيتون اذا هذا بيوتنال وبنحط + +267 +00:24:38,270 --> 00:24:40,570 +two cyclopropyl + +268 +00:24:42,650 --> 00:24:49,870 +two cyclopropyl three phenyl كلمة واحدة ابيوتنال + +269 +00:24:49,870 --> 00:24:51,610 +واضح؟ + +270 +00:24:52,880 --> 00:24:56,800 +لاحظوا أن نظام التسمية .. نظام التسمية في الـ + +271 +00:24:56,800 --> 00:25:00,760 +organ الكميستري نظام systematic يعني اللي بيعود + +272 +00:25:00,760 --> 00:25:05,360 +نفسه عليه حتى لو الجزاء كبره و يمكن كان ما بتخيل + +273 +00:25:05,360 --> 00:25:09,480 +أنه كيف بدي أسمي هيك مركب مجرد بس أنه أفكر بأفكار + +274 +00:25:09,480 --> 00:25:14,500 +بسيطة أنه أنا عندي أطول سلسلة عندي عائلة أبحث عنها + +275 +00:25:14,500 --> 00:25:18,600 +و أسمي المركب بالنسبة إلها و بعد هيك عندي مجموعات + +276 +00:25:18,600 --> 00:25:24,980 +بيصير كل التسمية سهلةيعني كأنه نظام التسمية صار + +277 +00:25:24,980 --> 00:25:33,600 +بكلمات بسيطة أطول سلسلة منتهية باسمالعائلة فلو + +278 +00:25:33,600 --> 00:25:42,280 +كانت ال keen بتنتهي in ال keen in all ال on واضح؟ + +279 +00:25:42,280 --> 00:25:46,540 +وتوضع المجموعات أطول سلسلة منتهية باسم العائلة + +280 +00:25:46,540 --> 00:25:51,800 +ونضع المجموعات اللي بتطبق على هذا الكلام أي مركب + +281 +00:25:51,800 --> 00:25:54,700 +موجود عندها بتقدر تسميه شوفتوا كده سهل نظام + +282 +00:25:54,700 --> 00:25:59,300 +التسمية في ال organ ال chemistry أطول سلسلة منتهية + +283 +00:25:59,300 --> 00:26:07,310 +بإيش؟باسم العائلة والباقي مجموعات + +284 +00:26:07,310 --> 00:26:16,210 +عليها + +285 +00:26:16,210 --> 00:26:21,370 +الجميع الأمثل هذه يشوفوها الآن اخدنا احنا نفيه + +286 +00:26:21,370 --> 00:26:25,850 +مجموعات من الالكينز مثل اثلبروبل من الالكينز + +287 +00:26:27,730 --> 00:26:32,910 +Vinyl وقلل الان هل في من الـ Ketones و ال الديهيدس + +288 +00:26:32,910 --> 00:26:37,830 +مجموعات الجواب اه ال C double bond OH لو كانت + +289 +00:26:37,830 --> 00:26:44,710 +مجموعة بنسميها formal واضح ال C double bond O CH3 + +290 +00:26:44,710 --> 00:26:52,440 +Acetyl ال C double bond O فينيلبنزايل لأ لأ مش + +291 +00:26:52,440 --> 00:26:58,960 +بنزل بنزايل ليش لأنه احنا نبهنا ان الفن ال CH2 + +292 +00:26:58,960 --> 00:27:05,420 +بتهيألي سبق ان اعطينا هيك هلد هذه اسمها بنزل في + +293 +00:27:05,420 --> 00:27:09,940 +مجموعتين لو سمحتوا انتبهوا لهذه النقطة بنزل و + +294 +00:27:09,940 --> 00:27:19,620 +بنزايلتمام البنزول فنل CH2 و بناء + +295 +00:27:19,620 --> 00:27:25,680 +على ذلك لو افترضت مثلا ان انا حطيت هنا PR و حطيت + +296 +00:27:25,680 --> 00:27:32,060 +هنا PR و قلت بدأ اسمي هذا كمركب كامل هذا ايش بدأ + +297 +00:27:32,060 --> 00:27:40,510 +اسمي بنزول بروميد مجموعة و بعدين العائلةو هذا ايش + +298 +00:27:40,510 --> 00:27:50,510 +بده اسميه بنزلبروميد واضح فكلمة بنزل بتفرج عن + +299 +00:27:50,510 --> 00:27:53,890 +بنزول مرات كتير احنا لما نيجي نسألكوا السؤال في + +300 +00:27:53,890 --> 00:27:57,190 +الامتحان بنحطلكوا سهم بنكون بدنا ياكوا تكملوا + +301 +00:27:57,190 --> 00:28:00,490 +المعادلة لكي نتأكد نحطوا الأسماء فبحطلكوا على + +302 +00:28:00,490 --> 00:28:05,110 +السهم ان هذا اتفاعل مع ال بنزلبروميد الان اللي + +303 +00:28:05,110 --> 00:28:13,350 +مابتعرفش ترسم ال بنزلبروميد مش هتحلالمسألة واضحة + +304 +00:28:13,350 --> 00:28:20,870 +يعني ممكن اعطيكم ممكن اعطيكم مثال يعني تخيلوا انه + +305 +00:28:20,870 --> 00:28:28,170 +مثلا جيبنالكم سؤال CN minus مع الفينل كتبنا هنا لأ + +306 +00:28:28,170 --> 00:28:34,110 +بنزليبروميد بنزليبروميد + +307 +00:28:34,110 --> 00:28:37,370 +الان هذا السؤال على اي chapter + +308 +00:28:41,600 --> 00:28:46,040 +ع شبطر ستة لازم تيجوا تكونوا عارفين أن ال بنزيل + +309 +00:28:46,040 --> 00:28:53,300 +البروميد عبارة عن فينل CH2BR إذا هذا يعتبر + +310 +00:28:53,300 --> 00:29:00,980 +الكلهلايد مش ال PR متصل فيه بمجموعة إيش الكلهلايد + +311 +00:29:00,980 --> 00:29:05,020 +ماليش أنا في اللي بعدها هذا بتسماش ال الهلايد هذا + +312 +00:29:05,020 --> 00:29:07,820 +الكلهلايد أي نوع من ال الكلهلايد primary, + +313 +00:29:08,040 --> 00:29:13,690 +secondary, tertiaryPrimary طالما الـ PR متصلة بـ + +314 +00:29:13,690 --> 00:29:18,030 +CH2 إذا هذا الـ Primary Alkyl Halide فلو قلنا أكمل + +315 +00:29:18,030 --> 00:29:21,650 +هذه التفاعل ستقول الـ CNN تتفعل من الـ C أو من الـ + +316 +00:29:21,650 --> 00:29:30,110 +L؟ من الـ C تهاجم هنا تطرد الـ PR هي كلمة واحدة كل + +317 +00:29:30,110 --> 00:29:33,350 +اللي أخدناها في شبتر 6 أن الـ Alkyl Halide يصبح + +318 +00:29:33,350 --> 00:29:39,050 +عليهم إبدال إذا هنا النتيجة فين الـ CH2؟ + +319 +00:29:42,820 --> 00:29:48,920 +واضح؟فمثل هذه الأشياء اللي احنا بنحكيها بدكم رجاء + +320 +00:29:48,920 --> 00:29:54,540 +تتعلموا و تعودوا أنفسكم انكم تتدربوا و تكتبوا كتير + +321 +00:29:54,540 --> 00:30:00,640 +بمعنى اي طالبة هنا بنحكيه على الهواء مباشرة اي + +322 +00:30:00,640 --> 00:30:04,040 +طالبة بتسجل course organic و لاحظوا كم انا بستدعي + +323 +00:30:04,040 --> 00:30:07,920 +المعلومات السابقة و كم ال reaction اللي من عندكم + +324 +00:30:07,920 --> 00:30:13,770 +اي طالبة بتسجل course organicالاصل فيها بالنسبة لي + +325 +00:30:13,770 --> 00:30:20,950 +انه بذاك ال semester تكون وقفت ال facebook مافي + +326 +00:30:20,950 --> 00:30:26,010 +وقت لا لا ال facebook ولا لا مهندو نور ولا لا اي + +327 +00:30:26,010 --> 00:30:31,230 +اشي اللي بسجل course ال organic ولاحظوا ان تفاعلكم + +328 +00:30:31,230 --> 00:30:38,990 +معي بطيء جداليش؟ لأنه ليلة نهار .. ليلة نهار بدكم + +329 +00:30:38,990 --> 00:30:42,950 +تبقوا تعيدوا وترسموا فيها الأشياء وتحفظوها هذه + +330 +00:30:42,950 --> 00:30:46,710 +الجامعة و هذا العلم و اللي جابلكوا لما اتعلموا + +331 +00:30:46,710 --> 00:30:51,470 +تعبوا كتير و أنتوا الخيار بين أيديكم .. تتعبوا + +332 +00:30:51,470 --> 00:30:56,430 +كتير حتى لما الأستاذ بيحكي الكلمة أنتوا إيش؟ على + +333 +00:30:56,430 --> 00:31:00,670 +طول تتفاعلوا .. إذا شايفين هاي البنزل لو مثلا + +334 +00:31:00,670 --> 00:31:08,560 +قلنالكوا بدنا بنزل alcoholإيش هتحطوه؟ OH واضح؟ + +335 +00:31:08,560 --> 00:31:13,560 +بنزل ألكول، بدنا نحط OH لاحظوا إن هذه المجموعات + +336 +00:31:13,560 --> 00:31:19,180 +كلها بنسميها ASL، this is a general name اسم عائلة + +337 +00:31:19,180 --> 00:31:23,240 +عام ASL groups، الآن ال ASL groups أولادها + +338 +00:31:23,240 --> 00:31:28,560 +المشهورين مين؟ ال formal، ال acetal، ال benzoyl + +339 +00:31:29,530 --> 00:31:34,570 +وعشان هيك في هذه الأمثلة على سبيل المثال لاحظوا + +340 +00:31:34,570 --> 00:31:38,550 +هذا المركب اللي فيه SO3H اسمه sulfonic acid او + +341 +00:31:38,550 --> 00:31:43,910 +بنزين sulfonic acid على نمرة أربعة في واحد اتنين + +342 +00:31:43,910 --> 00:31:50,500 +تلاتة أربعة وجدت هذه المجموعة شو اسمها formalعشان + +343 +00:31:50,500 --> 00:31:56,660 +ايك بيصير four-formyl بنزين سالفونك أسد السالفونك + +344 +00:31:56,660 --> 00:32:02,240 +أسد أو بنزين سالفونك أسد ماخد الصيغة SO3H لو كنتوا + +345 +00:32:02,240 --> 00:32:05,080 +بتكونوا تفصلوها تفصيلي يعني S double bond O double + +346 +00:32:05,080 --> 00:32:13,140 +bond O OH هيك شكل مفصل طبعا ماحدش يسألنا ان السلفر + +347 +00:32:13,140 --> 00:32:19,830 +بياخد اتناشر إلكترون حواليه ست روابطاملاحظين انتوا + +348 +00:32:19,830 --> 00:32:26,190 +هنا ال sulfur كام رابطة حواليه؟ هايو قادرين + +349 +00:32:26,190 --> 00:32:32,150 +تعدوهم؟ ست روابط، كام إلكترون؟ ستة في اتنين، + +350 +00:32:32,150 --> 00:32:37,630 +اتنعاش، ابهيك بيكون متجاوز ال octet rule، بيصير + +351 +00:32:37,630 --> 00:32:40,770 +هذا الكلام في الكيميا؟ + +352 +00:32:42,680 --> 00:32:48,160 +لا مش من الشواذ بصير بسهولة طبعا انتبهوا معاه ان + +353 +00:32:48,160 --> 00:32:54,900 +ال octetrol بتشتغل على العناصر اللي في الدورة + +354 +00:32:54,900 --> 00:33:03,980 +التانية يعني carbon, nitrogen, oxygenلكن لما اتي + +355 +00:33:03,980 --> 00:33:08,680 +هنا مثلا الفوسفوراس تحت ال نيتروجين والسالفر هنا + +356 +00:33:08,680 --> 00:33:11,900 +تحت ال اكسوجين هدولة بيمشوش على ال اكترول هدولة + +357 +00:33:11,900 --> 00:33:15,600 +بياخدوا خمسة و بياخدوا عشرة يعني خمسة في اتنين + +358 +00:33:15,600 --> 00:33:20,180 +عشرة و بياخدوا اتماعش عشان هيك سهل ان نلاقي مثلا + +359 +00:33:20,180 --> 00:33:26,320 +مركب في الدنيا صيغته العامة BCL5 ايش هتسموه؟ + +360 +00:33:26,320 --> 00:33:31,200 +فوسفوراس؟Ventachloride بالـ General Chemistry اللي + +361 +00:33:31,200 --> 00:33:34,400 +أخدناها طب حطوا على الفوسفور خمس روابط و إلكترونين + +362 +00:33:34,400 --> 00:33:40,420 +عشرة فوسفوراس Ventachloride متجاوز الـ Octetrol + +363 +00:33:40,420 --> 00:33:45,320 +ولا لأ؟ متجاوزها ال Octetrol لهانا it's okay بس + +364 +00:33:45,320 --> 00:33:49,100 +فوسفور كابريت هدول على طول بتجاوز ال Octetrol و + +365 +00:33:49,100 --> 00:33:53,620 +هاي مثال و أشهر مثال الحمض اللي طول عمركوا عارفينه + +366 +00:33:53,620 --> 00:34:00,360 +من الإبتدائية ال sulphuric acidعارفينه؟ حمض + +367 +00:34:00,360 --> 00:34:03,760 +الكابريتيك لو قولنا لكوا إيش الشكل تبع الحمض + +368 +00:34:03,760 --> 00:34:10,640 +الكابريتيك H2SO4 لما نيجي نعمله شكل S double bond + +369 +00:34:10,640 --> 00:34:20,520 +O double bond O OH OH كام رابطة حوالين السلفر فهي + +370 +00:34:20,520 --> 00:34:27,330 +ال sulfuric acidطبعا لو بدنا نيجي نسأل سؤال للناس + +371 +00:34:27,330 --> 00:34:32,150 +الشاطرين ليش هدولة بتجاوزوش ال octet rule و هدولة + +372 +00:34:32,150 --> 00:34:33,890 +بتجاوزوا ال octet rule + +373 +00:34:37,930 --> 00:34:43,150 +ممتازة لأن هنا أنا عندى بس لحد ال B orbital و ال B + +374 +00:34:43,150 --> 00:34:46,930 +orbital سعة نهائية ثمانية هنا في عندى M T D + +375 +00:34:46,930 --> 00:34:51,150 +orbital التلاتة فيها D orbital ال D orbital لحاله + +376 +00:34:51,150 --> 00:34:54,770 +ممكن ياخد عشرة غير التعون ال B orbital فأي + +377 +00:34:54,770 --> 00:34:59,250 +إلكترونات زيادة تلت ال B orbital بتروح بتنحط وين؟ + +378 +00:34:59,250 --> 00:35:03,650 +في ال D orbitalالدورة التالتة فيها D-Orbital والـ + +379 +00:35:03,650 --> 00:35:07,790 +D-Orbital فيه 3D ولو أتيتوا توزعوا الإلكترونات لسه + +380 +00:35:07,790 --> 00:35:11,950 +ما زال 3D Zero فلو عملت روابط بزيادة كل + +381 +00:35:11,950 --> 00:35:16,090 +الإلكترونات أزايدة و أين هتروح؟ على الـ D-Orbital + +382 +00:35:16,090 --> 00:35:23,710 +الفاضي فيه واسع لكن هنا مافيش عندي وسع واضح؟ كذلك + +383 +00:35:23,710 --> 00:35:31,500 +الحالة لو بدنا نسمي مثلا هذا المركبcyclohexane على + +384 +00:35:31,500 --> 00:35:35,680 +نمرة واحد هذا الـcyclohexane شو بيحمل مجموعة هاي + +385 +00:35:35,680 --> 00:35:40,920 +واحد اتنين تلاتة اربعة خمسة ستة one cyclohexane + +386 +00:35:40,920 --> 00:35:47,280 +وعلى نمرة واحد بيحمل acetal هذا مثلا بنزويل حامل + +387 +00:35:47,280 --> 00:35:53,400 +اكلور شو بيكون بنزويل اكلورايد بنزويل اكلورايد + +388 +00:35:53,400 --> 00:35:59,680 +وحكينا هذا البنز الالكول عشان تميزه بنزويل عنبنزل + +389 +00:35:59,680 --> 00:36:07,500 +بس + +390 +00:36:07,500 --> 00:36:12,940 +هنا لإن انا عندي cycle مش عندياهم التانين في سلسلة + +391 +00:36:12,940 --> 00:36:18,920 +يعني لو التانين عندى في سلسلة واجيتها مابجيش انا + +392 +00:36:18,920 --> 00:36:23,600 +افكر بمجموعات راجعا هذه من الأخطاء من الأخطاء + +393 +00:36:23,600 --> 00:36:28,740 +الشائعة اللي أحيانا الناسممكن يقعوا فيها و اللي + +394 +00:36:28,740 --> 00:36:32,680 +نبهنا عليها من ايام ال alkanes ان لو عندى سلسلة + +395 +00:36:32,680 --> 00:36:38,520 +بفكرش نهائيا .. نهائيا بمجموعات قبل ما ابحث عن + +396 +00:36:38,520 --> 00:36:43,360 +اطول سلسلة و العائلة بمعنى ممكن طريقة كتابة السؤال + +397 +00:36:43,360 --> 00:36:47,740 +.. طريقة كتابة السؤال اتوجعكوا بالغلط يعني انا اجى + +398 +00:36:47,740 --> 00:36:51,820 +اطلب منكم تسمية المركبة التالية احطلكم c double + +399 +00:36:51,820 --> 00:37:00,150 +bond o ch3 و بعدينالان طالبة شوية صغيرة تعبة + +400 +00:37:00,150 --> 00:37:04,470 +اتذكرت يا الله سيضة بالبند OCH3 من طول الليل قاعد + +401 +00:37:04,470 --> 00:37:09,370 +بدرس انها مجموعة الاش ال Acetyl بناء على ذلك على + +402 +00:37:09,370 --> 00:37:15,150 +طول الحمد لله دراستنا جاوبت هاي ال Acetyl واحد + +403 +00:37:15,150 --> 00:37:23,610 +اتنين تلاتة one Acetyl ابروبينلأ بفكرش بمجموعة قبل + +404 +00:37:23,610 --> 00:37:27,930 +ما ابحث عن أطول سلسلة وعائلة الآن هذه صارت جزء من + +405 +00:37:27,930 --> 00:37:33,390 +إيش؟ سلسلة جزء من السلسلة بدي أرقم منها أن واحد + +406 +00:37:33,390 --> 00:37:40,150 +اتنين تلاتة أربعة خمسة هذا two بنتانون ماحدش يفكر + +407 +00:37:40,150 --> 00:37:44,470 +one acetyl أو في أي الدي هاي يطلع C double bond OH + +408 +00:37:44,470 --> 00:37:53,460 +يقول formal واضح؟ ما بنفكر؟بمسمى مجموعة إلا بعد ما + +409 +00:37:53,460 --> 00:37:58,020 +نبحث عن أطول سلسلة لأن إذا أطول سلسلة بتختارق هذه + +410 +00:37:58,020 --> 00:38:04,580 +المجموعة لازم تختارقها واضح الكلام تماما زي لما + +411 +00:38:04,580 --> 00:38:08,880 +كنا هنقولكم أنه في أي سلسلة طويلة كان ممكن تاخدوا + +412 +00:38:08,880 --> 00:38:12,700 +الطرف و تسموه مثل أو أول ذرتين تسموهم اثل بس هذا + +413 +00:38:12,700 --> 00:38:13,560 +الكلام بيصير + +414 +00:38:17,020 --> 00:38:22,540 +فهنا مش موجودين بشكل سلسلة الان + +415 +00:38:22,540 --> 00:38:26,140 +في عند بعض ال common aldehydes and ketones ال + +416 +00:38:26,140 --> 00:38:30,700 +aldehydes و ال ketones اللي مشهورة و بنحب نتعرف + +417 +00:38:30,700 --> 00:38:36,540 +عليها أكتر منها أبسط ال aldehyde ال formaldehyde + +418 +00:38:36,540 --> 00:38:42,700 +اللي هو ماخد CH2 double bond O الان لاحظوا ال + +419 +00:38:42,700 --> 00:38:47,830 +formaldehyde هو عبارة عن غازنقطة الغليان تبعه + +420 +00:38:47,830 --> 00:38:53,270 +تناقص واحد وعشرين درجة مئوية هذا + +421 +00:38:53,270 --> 00:38:57,730 +ال formaldehyde عادة بيحضروا بأكسدة الميثانول + +422 +00:38:57,730 --> 00:39:02,210 +بياخدوا ميثانول بيسخنوه هذا تحضير صناعي مع الفضة + +423 +00:39:02,210 --> 00:39:05,450 +ككتلة ستمية سبعمية درجة مئوية بيفقد اتش منها لو + +424 +00:39:05,450 --> 00:39:13,060 +اتش منها بيصير ايش؟يعني زي هيك هيو C O H و هذه + +425 +00:39:13,060 --> 00:39:17,660 +حاملة H وهي كمان H وهي كمان H لما بدنا نسخله بده + +426 +00:39:17,660 --> 00:39:21,640 +يفقد كام هيدروجينة؟ تنتين عشان هيك هذه بنقول عنها + +427 +00:39:21,640 --> 00:39:25,680 +أكسدة وهذه بتصير double bond هيه صار الديهايد + +428 +00:39:25,680 --> 00:39:31,400 +واضح؟ مشقولنا الأكسدة فقد هيدروجنتين متجاورتين أو + +429 +00:39:31,400 --> 00:39:34,420 +نقص في محتوى الهيدروجين أكسدة زيادة في محتوى + +430 +00:39:34,420 --> 00:39:40,090 +الهيدروجين اختزاننقص محتوى الهيدروجين اكسدا زيادة + +431 +00:39:40,090 --> 00:39:45,290 +محتوى الهيدروجين اختزال زيادة محتوى الاكسجين اكسدا + +432 +00:39:45,290 --> 00:39:53,290 +نقص محتوى الاكسجين اختزال واضح الفكرة ولا اوضحها + +433 +00:39:53,290 --> 00:39:59,570 +اكتر لحظة بس لو سمحت في مرات انا دايما المبادئ + +434 +00:39:59,570 --> 00:40:05,260 +الاساسية بحب ان اركز عليها اكتريعني هذا المُركّب + +435 +00:40:05,260 --> 00:40:10,660 +الالكول ليش بدي أركز الآن عليها لأنه هيجينا أكسدة + +436 +00:40:10,660 --> 00:40:15,920 +الكحولات واخدناها سابقاً و بعد الكحولات قلنا + +437 +00:40:15,920 --> 00:40:19,960 +بتتأكسد الالديهايت أو كيتون الآن لما نيجي ندرس + +438 +00:40:19,960 --> 00:40:22,980 +تفاعل الالديهايت أو كيتون هذا لما حدف + +439 +00:40:22,980 --> 00:40:28,890 +الهيدروجينتينبهذا الشكل وعملت double bond minus H2 + +440 +00:40:28,890 --> 00:40:38,030 +إيش صار؟ C double bond O H H الأن لاحظوا معي لما + +441 +00:40:38,030 --> 00:40:42,070 +أنا بيتعرف ال X ده بال organ ال chemistry بتعرفها + +442 +00:40:42,070 --> 00:40:48,270 +بتعرفين و التعرفين صحيحاتإذا قولت زيادة في الاتصال + +443 +00:40:48,270 --> 00:40:51,410 +بالأكسوجين يعني هنا الأكسوجين كان بين ال carbon و + +444 +00:40:51,410 --> 00:40:56,270 +ال oxygen كان مرابطة واحدة جداش صاروا تلتل فزيادة + +445 +00:40:56,270 --> 00:40:59,150 +في المحتوى الأكسوجين أو في الاتصال بالأكسوجين هذه + +446 +00:40:59,150 --> 00:41:04,920 +أكسدة أو نقص في المحتوى الهيدروجينيالان لما بدي + +447 +00:41:04,920 --> 00:41:09,460 +اجي اعرف الاختزال العملية المعاكسة يعني احنا في + +448 +00:41:09,460 --> 00:41:12,620 +شبتر سبعة أخدنا أكسدة الكحولات وبتصير ال aldehydes + +449 +00:41:12,620 --> 00:41:18,540 +و ال ketones في شبتر تسعة هنرجع ايش نقول اختزال ال + +450 +00:41:18,540 --> 00:41:21,560 +aldehydes و ال ketones يعني بصير بده اضيف عليهم + +451 +00:41:21,560 --> 00:41:28,580 +ايش هيدروجين زائد هيدروجينبصير زيادة في محتوى + +452 +00:41:28,580 --> 00:41:33,700 +الهيدروجين او نقص في محتوى الاكسجين هذا ايش اسمه + +453 +00:41:33,700 --> 00:41:37,180 +reduction الان تخيلوا ان كل هذا الكلام ممكن + +454 +00:41:37,180 --> 00:41:42,860 +نسألكوا اياها بسؤال صح و غلط يعني increasing the + +455 +00:41:42,860 --> 00:41:45,700 +content of hydrogen is + +456 +00:41:50,420 --> 00:41:54,460 +decreasing the content of hydrogen is oxidation + +457 +00:41:54,460 --> 00:41:58,120 +increasing the content of oxygen is oxidation + +458 +00:41:58,120 --> 00:42:04,540 +decreasing the content of oxygen isReduction، + +459 +00:42:04,540 --> 00:42:09,540 +واضحة الفكرة؟ عشان هيك، يعني أنا عوّدت، ركزت على + +460 +00:42:09,540 --> 00:42:14,540 +هذه النقطة فعملية تحويل الـ Methanol to + +461 +00:42:14,540 --> 00:42:17,780 +Formaldehyde، هذه العملية هي عملية Ash + +462 +00:42:20,380 --> 00:42:26,460 +Oxidation الآن هذا ال Formaldehyde عادة احنا بناخد + +463 +00:42:26,460 --> 00:42:30,800 +الغاز و بندوبه في الميه بيصير محلول اسمه Formalin + +464 +00:42:30,800 --> 00:42:35,720 +بدوب لحد 37% تماما زي الناس اللي بدكره من المدرسة + +465 +00:42:35,720 --> 00:42:41,600 +لما كنا ندوب غاز HCL في الميه ايش يعطينا؟ حمض + +466 +00:42:41,600 --> 00:42:47,080 +الهيدروكلوريك لما كنا ندوب غاز ال S O2 في الميه + +467 +00:42:47,080 --> 00:42:55,170 +ايش كان يعطينا؟حمد الكابريتوز بالعربي sulfuric + +468 +00:42:55,170 --> 00:42:58,790 +acid أي غاز اللي بندوبه في الميه بيعطينا حمد + +469 +00:42:58,790 --> 00:43:06,130 +الكابريتيك اه يعني لما نجيبلكم dissolving فراغ in + +470 +00:43:06,130 --> 00:43:13,060 +water produces sulfuric acidS O 3 في الميه بيعطي + +471 +00:43:13,060 --> 00:43:18,760 +حمض الكابريتيك S O 2 في الميه بيعطي حمض الكابريتوز + +472 +00:43:18,760 --> 00:43:23,940 +اللي هما اسمهم سالفاريك و سالفاراس و دايما ال اك + +473 +00:43:23,940 --> 00:43:31,080 +بتعني زيادة في الاكسجين اكتر من ال OUS سالفاريك + +474 +00:43:31,080 --> 00:43:40,800 +سالفاراس نيترس نيترس نيتريك حمض النيتريك ايشHMO3 + +475 +00:43:40,800 --> 00:43:49,820 +حمض النيتروز HMO2 كويس فهذا ال Formaldehyde بندوبه + +476 +00:43:49,820 --> 00:43:55,860 +في الميه بدوب بنسبة 37% بيعمل محلول بنسميه + +477 +00:43:55,860 --> 00:43:59,160 +Formalin و احنا عادة نتعامل بال Formalin هذا ال + +478 +00:43:59,160 --> 00:44:03,040 +Formalin هو اللي بيحطوا فيه الجثث اللي أثناء ما + +479 +00:44:03,040 --> 00:44:07,080 +بيكونوا بيشرحوا الأنسج اللي بدهم يحتفظوا فيهاالان + +480 +00:44:07,080 --> 00:44:10,520 +هذا بدكوا تهتموا كتير فيه عارفين ليش؟ جزء كبير + +481 +00:44:10,520 --> 00:44:14,920 +منكوا اللي بده يدرس تحليل هيضطر في لحظة من اللحظات + +482 +00:44:14,920 --> 00:44:19,200 +انه في عينات بده تنقل يعني نفترض انه من مريض معين + +483 +00:44:19,200 --> 00:44:23,540 +طاله عينة بيشكوا انه يمكن تكون هذه العينة فيها ورم + +484 +00:44:23,540 --> 00:44:28,250 +لازم نبعتها لمختبر ال NC جاي يحللهاالان يا ترى هال + +485 +00:44:28,250 --> 00:44:32,630 +دكتور اللي طال العينة في الجراحة استقصالها بده + +486 +00:44:32,630 --> 00:44:36,850 +يسيبها برا ولا يحطها بكيس نايلون و تاخدلها يومين + +487 +00:44:36,850 --> 00:44:40,770 +مع السواجين و مع الإسعاف و كذا لحد ما تصل للمختبر، + +488 +00:44:40,770 --> 00:44:45,390 +شو بيكون صار فيها؟ بتكون خربت، طب ها إيش الحال؟ + +489 +00:44:45,390 --> 00:44:50,010 +مجرد ما بده يطول العينة اللي بده يبعتها للمختبر + +490 +00:44:50,010 --> 00:44:55,070 +للتحليل، بده يحطها بمحلول فورماليواضح؟ بده يحطها + +491 +00:44:55,070 --> 00:45:00,590 +بمحلول Formalin .. تعون الطب لما بيدرسه تشريح + +492 +00:45:00,590 --> 00:45:05,790 +الجثث .. الجثة بيكون عندهم بانيو كامل ملان + +493 +00:45:05,790 --> 00:45:09,890 +Formalin .. بيحطوا الجثة فيه و بيغطوها .. وقت ما + +494 +00:45:09,890 --> 00:45:12,870 +بتلزمهم .. بيطولوا الجثة من ال Formalin .. بتطلعوا + +495 +00:45:12,870 --> 00:45:15,070 +.. بيشوفوا الأشياء اللي بدونيها .. بيعودوا يرجعوها + +496 +00:45:15,070 --> 00:45:19,090 +بال Formalinفسواء قلنا إننا بنستعمل ولا نوع من + +497 +00:45:19,090 --> 00:45:23,230 +التحنيط أو الحفظ أو الجثث، بدنا نكون عارفين بالظبط + +498 +00:45:23,230 --> 00:45:31,220 +إيش يعنيهالفورمالين من الأشياء أيضا ال الديهيد + +499 +00:45:31,220 --> 00:45:34,820 +التاني لبعد ال formaldehyde شو اسمه ال + +500 +00:45:34,820 --> 00:45:40,740 +acetaldehyde عادة بيعملو بال oxidation للإيثيلين + +501 +00:45:40,740 --> 00:45:45,460 +في وجود ال oxygen بالاديوم عند حرارة معينة بيصير + +502 +00:45:45,460 --> 00:45:51,040 +عند إيش؟الديهيد بيسموه Walker Synthesis يعني كأن + +503 +00:45:51,040 --> 00:45:55,060 +أضفنا الميه و بعدين حذفنا الهيدروجين هنا إفليل + +504 +00:45:55,060 --> 00:45:59,860 +بيصير أسيتال ديهيد هذا تحضير صناعي والأسيتال ديهيد + +505 +00:45:59,860 --> 00:46:02,780 +boiling point عشرين يعني بيزيد عن ال formal ديهيد + +506 +00:46:02,780 --> 00:46:08,260 +بكم درجة واحد واربعين درجة + +507 +00:46:10,430 --> 00:46:14,630 +المُركّب التالت المشهور الـ Acetone نفس الـ Walker + +508 +00:46:14,630 --> 00:46:17,310 +Synthesis على الـ Double Bond اللي هنا بنضيف + +509 +00:46:17,310 --> 00:46:22,070 +أكسجين في بلاديام كاربون لكن بيحط الأكسجين وين؟ + +510 +00:46:22,070 --> 00:46:25,710 +على الكاربون الوسطاني بيعطيني أسيتون كل هذه + +511 +00:46:25,710 --> 00:46:30,270 +التحذيرات تحذيرات في الصناعة يعني لو قلنا كيف + +512 +00:46:30,270 --> 00:46:35,190 +بنحضر الأسيتون في الصناعة بروبيليين مع أكسجين في + +513 +00:46:35,190 --> 00:46:41,080 +الشروط هذهطبعا ممكن الاسيتون كمان احضروه من + +514 +00:46:41,080 --> 00:46:45,200 +الكيومين هذا المركب ال isopropyl بنزين مين فيكم + +515 +00:46:45,200 --> 00:46:51,000 +اتذكر انه سمناه كيومين؟هذا الكيومين مع الـ Oxygen + +516 +00:46:51,000 --> 00:46:55,540 +و Sulphuric Acid بيكسل تفاعل كتير هذا مهم لسبب + +517 +00:46:55,540 --> 00:46:59,820 +بسيط انه بيعطي ناتجين مهمات مش ناتج واحد من هنا + +518 +00:46:59,820 --> 00:47:05,240 +بيكسل هذه بتصير CWO وهذه بتصير CWO الآن هذا الجزء + +519 +00:47:05,240 --> 00:47:13,100 +CH3 CH3 هو ايش ال Acetone هذا الجزء بيحول الى Enol + +520 +00:47:13,100 --> 00:47:19,790 +بيصير Phenolفتفاعل الكيومين مع الأكسجين وحمض + +521 +00:47:19,790 --> 00:47:25,110 +الكابريتيك إيش بيعطينا؟ Phenol and Acetone يعني لو + +522 +00:47:25,110 --> 00:47:28,910 +بدنا نسألكوا reaction of الكيومين with أكسجين و + +523 +00:47:28,910 --> 00:47:34,130 +presence of sulphuric acid بطريقة معينة produces + +524 +00:47:34,130 --> 00:47:40,050 +Phenol and Acetone و هدولة المركبين إيش مالهم؟ + +525 +00:47:40,050 --> 00:47:43,870 +مركبات مهمة جدا في ال organ الchemistry + +526 +00:47:46,550 --> 00:47:50,490 +لحد هنا بننهي اليوم ان شاء الله إلى اللقاء + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..724bf47123027def3013f8a5eac7b1a63d75da5f --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_raw.srt @@ -0,0 +1,2108 @@ +1 +00:00:19,590 --> 00:00:24,930 +بسم الله الرحمن الرحيم في موضوع الفصل التاسع ال + +2 +00:00:24,930 --> 00:00:30,170 +aldehydes و ال ketones اعطينا المرة الماضيةمقدمة، + +3 +00:00:30,170 --> 00:00:34,890 +إيش معناه ال carbonyl compounds؟ ليش قسمناهم + +4 +00:00:34,890 --> 00:00:39,150 +لصنفين أساسيين؟ يعني ليش حاطينا ال aldehydes و ال + +5 +00:00:39,150 --> 00:00:44,330 +ketones لحال و الأحماض و مشتقاتها لحال؟ السبب يعود + +6 +00:00:44,330 --> 00:00:47,690 +لطبيعة التفاعل الكيميائي اللي هم ال aldehydes و ال + +7 +00:00:47,690 --> 00:00:51,890 +ketones بتفاعلوا بالإضافة، الأحماض و مشتقاتها + +8 +00:00:51,890 --> 00:00:58,000 +بتفاعلوابالإبدال حكينا عن الخواص الفيزيائية لل + +9 +00:00:58,000 --> 00:01:02,560 +الديهايد والكيتوز مقارنة بالالكوهولز مقارنة + +10 +00:01:02,560 --> 00:01:06,220 +بالالكينز هم حالة بين الالكوهولز والالكينز من + +11 +00:01:06,220 --> 00:01:09,820 +ناحية ال polarity و من ناحية ال boiling points + +12 +00:01:10,520 --> 00:01:15,120 +بعدين اتكلمنا عن التسمية قولنا ال aldehydes + +13 +00:01:15,120 --> 00:01:20,000 +بياخدوا نهاية ال و ال ketones بياخدوا نهاية on + +14 +00:01:20,000 --> 00:01:24,600 +طبعا بيميز ال aldehydes انه دائما هم على موقع واحد + +15 +00:01:24,600 --> 00:01:28,700 +فبلزمش نحط ترقيم لل ال يعني ال ال مابتكونش الا على + +16 +00:01:28,700 --> 00:01:35,440 +موقع واحد لكن لما بنبدأ نيجي على ال ketones ال + +17 +00:01:35,440 --> 00:01:41,230 +ketones بيكونوش على موقع واحد إلا نادراربما البعض + +18 +00:01:41,230 --> 00:01:47,830 +يعتقد انه نهائيا مش ممكن يكون كيتون على موقع واحد + +19 +00:01:47,830 --> 00:01:53,790 +لأ في حالات في حالات فيها كيتون على موقع واحد يعني + +20 +00:01:53,790 --> 00:01:58,870 +على سبيل المثال لو كنت بدى اشوف مركب زي هذا سيضة + +21 +00:01:58,870 --> 00:02:07,990 +بال bond O phenyl CH2 CH3هذا كيتون والـ C double + +22 +00:02:07,990 --> 00:02:12,790 +bond O تبعته جاية على موقع واحد ليش؟ لأنه أنا لما + +23 +00:02:12,790 --> 00:02:16,910 +أبدأ أسمي واحد، اتنين، تلاتة، شو بدأ أسمي هذا الـ + +24 +00:02:16,910 --> 00:02:21,910 +Ketone؟ Iprobanone على نمرة واحد ولا اتنين الـ C + +25 +00:02:21,910 --> 00:02:28,650 +double bond O؟ على واحد، اذا هذا one Iprobanone + +26 +00:02:35,810 --> 00:02:42,430 +مجموعة الفنل فبدي يصير one fennel one probanone + +27 +00:02:42,430 --> 00:02:47,330 +واضح؟ في حالات شبه بهذه الحالة ممكن يكون الكيتون + +28 +00:02:47,330 --> 00:02:53,390 +على موقع واحد بعد ذلك مثلا هنا في الاسيتون بنقول + +29 +00:02:53,390 --> 00:02:59,560 +probanone لاحظوا أكيد هتقولوا one two threeلكن + +30 +00:02:59,560 --> 00:03:04,020 +اختصرنا الاتنين لإيش؟ لأن لو جت على واحد هيصير + +31 +00:03:04,020 --> 00:03:14,560 +بروبانال و هذا المركب لبروبانون هو الاسيتون الان + +32 +00:03:14,560 --> 00:03:20,000 +هنا عندي اربع كربونات اذا بحكي انا عن بيوتانون ال + +33 +00:03:20,000 --> 00:03:23,820 +C double bond O جاية فيه على موقع اتنين من ناحية + +34 +00:03:23,820 --> 00:03:27,870 +المبدأ ايضا ممكن نختصرهالأنه مافيش غير two + +35 +00:03:27,870 --> 00:03:31,410 +butanone ضمن هذا الشكل لو إجت على موقع واحد إيش + +36 +00:03:31,410 --> 00:03:38,010 +هتصير butanane لكن مثلا ضرورية و لابد منها لو كان + +37 +00:03:38,010 --> 00:03:43,010 +عندي خمس درات كربون لإيش لأنه ممكن تكون هنا و يكون + +38 +00:03:43,010 --> 00:03:47,650 +two bentanone ممكن تكون هنا و يكون three bentanone + +39 +00:03:47,650 --> 00:03:52,050 +واضح فمن ال bentanone في عندي مركبين two bentanone + +40 +00:03:52,620 --> 00:03:57,080 +و 3 بنتانون هذا بالنسبة لل common nomenclature + +41 +00:03:57,080 --> 00:04:01,920 +الان بالنسبة لل common nomenclature هذا أبسط واحد + +42 +00:04:01,920 --> 00:04:05,340 +اسمه acetone بس بشكل عام ممكن نعمل ال common + +43 +00:04:05,340 --> 00:04:12,490 +nomenclature من خلال ان نحط نهايةketone تماما زى + +44 +00:04:12,490 --> 00:04:16,950 +ما كنا بال alcohols بنحط نهاية alcohol فكنا نذكر + +45 +00:04:16,950 --> 00:04:22,590 +المجموعة و بعدين نقول methyl alcohol إثل alcohol + +46 +00:04:22,590 --> 00:04:27,450 +بروبيل alcohol عيزو بيوتل alcohol and so on الأن + +47 +00:04:27,450 --> 00:04:32,250 +ال الديهايد مثلا كنا نقول بروبيونالديهايد + +48 +00:04:32,250 --> 00:04:36,170 +بيوتيرالديهايد يعني نحط كلمة الديهايد وين؟ في + +49 +00:04:36,170 --> 00:04:41,090 +الآخر أسيتلديهايد formaldehydeالعائلة في الآخر، طب + +50 +00:04:41,090 --> 00:04:45,310 +في ال ketones بنعمل هيك تسمية، الجواب وارد أيضا + +51 +00:04:45,310 --> 00:04:48,950 +أنه نكتب كلمة ketone في الآخر، الآن في ال ketone + +52 +00:04:48,950 --> 00:04:55,160 +عندي مش مجموعةمجموعتين ودول المجموعتين ممكن يكونوا + +53 +00:04:55,160 --> 00:05:00,680 +احيانا متشابهتين يعني هنا هذه المجموعة او هذه + +54 +00:05:00,680 --> 00:05:05,340 +المجموعة اثلو اثل اثل اثل اثل اثل اثل اثل اثل اثل + +55 +00:05:05,340 --> 00:05:11,060 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +56 +00:05:11,060 --> 00:05:13,240 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +57 +00:05:13,240 --> 00:05:14,360 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل + +58 +00:05:14,360 --> 00:05:16,580 +اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل ا + +59 +00:05:20,930 --> 00:05:26,730 +مثل مثل كيتون لاحظوا الكلام شبيه بتسمية إيش ال + +60 +00:05:26,730 --> 00:05:31,030 +ethers تسمية ال ethers يعني لو كانت هذه O كنا نقول + +61 +00:05:31,030 --> 00:05:34,570 +die ethyl ether لو كانت هذه O كنا نقول ethyl + +62 +00:05:34,570 --> 00:05:38,190 +methyl ether بنفس المنطقة ال common nomenclature + +63 +00:05:38,190 --> 00:05:43,150 +هذا ماخد أشهر أسيتون لكن in principle هل ممكن نقول + +64 +00:05:43,150 --> 00:05:48,730 +عنه die methyl ketone مافيش معنىلكن مش ماخد شهرة + +65 +00:05:48,730 --> 00:05:53,430 +يعني أشهر شئ اشتهر فيه اللي هي إيش أسيتون وبتاع + +66 +00:05:53,430 --> 00:05:56,110 +اللي كل لازم يكون عارف شكل الأسيتون يعني مفهوم + +67 +00:05:56,110 --> 00:06:01,140 +طالب في الجامعة ويقول مش عارف الأسيتونالان هذا + +68 +00:06:01,140 --> 00:06:06,820 +Cyclohexanone المرة الماضية نبهنا ان ال ketone و + +69 +00:06:06,820 --> 00:06:11,700 +ال alcohol بيجوا متصلين مباشرة بالحلقة لكن ال + +70 +00:06:11,700 --> 00:06:16,160 +dihyde و ال acid لأ بيجوا من خلال carbon و بالتالي + +71 +00:06:16,160 --> 00:06:20,780 +بياخد اسم مجموعة و لذلك هذا Cyclohexanone لو صار + +72 +00:06:20,780 --> 00:06:22,620 +OH كان صار Cyclo + +73 +00:06:43,740 --> 00:06:47,920 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +74 +00:06:47,920 --> 00:06:48,480 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +75 +00:06:48,480 --> 00:06:48,480 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +76 +00:06:48,480 --> 00:06:48,660 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +77 +00:06:48,660 --> 00:06:48,760 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +78 +00:06:48,760 --> 00:06:49,780 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +79 +00:06:49,780 --> 00:06:51,320 +هكسانول هكسانول هكسانول هكسانول هكسانول هكسانول + +80 +00:06:51,320 --> 00:06:55,560 +هكسانول هكسانول هكسانكيتون إذا مثل فنل كيتون فلو + +81 +00:06:55,560 --> 00:07:02,660 +قلنا لكم أسيتوفينون is also called مثل فنل كيتون + +82 +00:07:02,660 --> 00:07:09,000 +هذا المركب ماخد اسم بنزوفينون اللي هو بنزنتين + +83 +00:07:09,000 --> 00:07:15,280 +وبينهم كيتون الآن لو بدي يا فنل وفنلدايفين الكيتون + +84 +00:07:15,280 --> 00:07:21,800 +دايفين الكيتون هو بنزوفينون دايفين الكيتون هو + +85 +00:07:21,800 --> 00:07:22,880 +بنزوفينون + +86 +00:07:28,220 --> 00:07:32,780 +ال IOPAC وبطريقة ال common nomenclature ولاحظوا زي + +87 +00:07:32,780 --> 00:07:36,540 +ما حكينالكم ان ال common nomenclature ليست دائما + +88 +00:07:36,540 --> 00:07:40,440 +يعني تأتي بشيء جديد، إلها نوع من ال trend خلينا + +89 +00:07:40,440 --> 00:07:44,220 +نقول يعني ال trend العام في ال common nomenclature + +90 +00:07:44,220 --> 00:07:48,740 +أن أذكر المجموعة في الأول و بعدين أذكر إيش؟ + +91 +00:07:48,740 --> 00:07:53,220 +العائلةهذا الكلام لاحظناه بال ethers فكنا نقول + +92 +00:07:53,220 --> 00:07:56,300 +ethyl او diethyl ether لاحظناه في ال alcohol كنا + +93 +00:07:56,300 --> 00:08:00,280 +نقول ethyl alcohol لاحظناه في ال aldehyde كنا نقول + +94 +00:08:00,280 --> 00:08:04,140 +مثلا أسيت لأن المجموع أسيت الأسيت الديهايد في + +95 +00:08:04,140 --> 00:08:07,500 +النهاية حطينا كلمة إيش الديهايد لاحظناه في ال + +96 +00:08:07,500 --> 00:08:16,470 +ketone, diethyl, ketone و هكذاالان لو المركبات + +97 +00:08:16,470 --> 00:08:22,770 +كبرت شوية وصار فيها اكتر من مجموعة وظيفية يعني بدأ + +98 +00:08:22,770 --> 00:08:27,590 +يلتقى في المركب الكين مع الكهول مع الديهايد مع + +99 +00:08:27,590 --> 00:08:32,920 +كيتونواجتلاع أي عائلة بدي أنسب المركب اللي عندي + +100 +00:08:32,920 --> 00:08:36,960 +حسب الأولويات اللي أخدناها في ال aromatic + +101 +00:08:36,960 --> 00:08:41,160 +compounds إذا متذكرين إنه ال alkanes أقل من ال + +102 +00:08:41,160 --> 00:08:45,420 +alkenes و ال alkynes in general أقل من ال OH أقل + +103 +00:08:45,420 --> 00:08:48,380 +من ال ketone أقل من ال aldehyde من ال acid من ال E + +104 +00:08:48,380 --> 00:08:52,880 +star فإذا طلعنا لمركبات فيها أكثر من مجموعة ربما + +105 +00:08:52,880 --> 00:08:56,830 +هذا المركب و هذا المركب بسيطينمش فيهم يعني هذا + +106 +00:08:56,830 --> 00:09:01,890 +واضح انه الديهاي واحة اتنين تلاتة اربع اذا بيوتنال + +107 +00:09:01,890 --> 00:09:06,930 +و بنذكر المجموعة الchloromethyl alphabetical و هذا + +108 +00:09:06,930 --> 00:09:11,370 +واضح انه كيتون واحد اتنين تلاتة اربع خمسة ستة اذا + +109 +00:09:11,370 --> 00:09:17,410 +هكسانون وعلى موقع تلاتة اقل ترقيم لكن مثلا هذا + +110 +00:09:17,410 --> 00:09:24,380 +المركب في كيتون وفي الكهولهيصير نهايته إيش؟ كيتون + +111 +00:09:24,380 --> 00:09:30,160 +ال alcohol وقتها بده ترجع لأصلها، إلها اسم في + +112 +00:09:30,160 --> 00:09:33,880 +الدنيا، إيش اسمها؟ Hydroxy الترقيم هيكون مع + +113 +00:09:33,880 --> 00:09:38,020 +الكيتون واحد اتنين إذا نادا two بنتانون على نمرة + +114 +00:09:38,020 --> 00:09:42,840 +أربعة موجود في مجموعة إيش؟ ال hydroxy four hydroxy + +115 +00:09:42,840 --> 00:09:47,580 +two bentanoneالان لو طلعنا على هذا المُركّب اللي + +116 +00:09:47,580 --> 00:09:51,740 +فيه تنتين C double bond O لاحظوا هذه الـ C double + +117 +00:09:51,740 --> 00:09:56,380 +bond O جنبها H الديهايد و هذه الـ C double bond O + +118 +00:09:56,380 --> 00:10:00,960 +بالكربونتين كيتون الان مين أعلى في الأولويات ال + +119 +00:10:00,960 --> 00:10:04,220 +الديهايد اذا انا هاي مُركّبي ماخد ترقيم عند ال + +120 +00:10:04,220 --> 00:10:08,020 +الديهايد واحد اتنين تلات اربعة هذه صارت مجموعة + +121 +00:10:08,020 --> 00:10:13,900 +الانيعني لو كانت هذه مش موجودة وقلنا سموا المراكب + +122 +00:10:13,900 --> 00:10:19,160 +حد سموه butanal ال .. لو سمحتوا .. butanal .. + +123 +00:10:19,160 --> 00:10:24,860 +butanal .. الان هذه السيطرة بال point O لما بتنوجد + +124 +00:10:24,860 --> 00:10:30,700 +كمجموعة بنعطيها اسم OXO واضح؟ طبعا أي واحدة اللي + +125 +00:10:30,700 --> 00:10:34,900 +أخدت OXO هذي .. هذي وين بيانت؟ بيانت في ال .. في + +126 +00:10:34,900 --> 00:10:42,800 +ال ..الديهايد وهذه فقط اللى أصبحت مجموعة كذلك + +127 +00:10:42,800 --> 00:10:46,340 +المثال اللى موجود عندنا هناك ايش المجمعتين اللى + +128 +00:10:46,340 --> 00:10:54,800 +موجودات فيه كيتونو ال keen مين أعلى في الأولوية ال + +129 +00:10:54,800 --> 00:10:58,440 +ketone أعلى في الأولوية و بناء على ذلك لما نرقم + +130 +00:10:58,440 --> 00:11:02,480 +واحد اتنين تلاتة اربعة خمسة ستة لحظة و ده هيصير + +131 +00:11:02,480 --> 00:11:09,620 +hexane on ال on على اي موقع على اتنين وال in على + +132 +00:11:09,620 --> 00:11:12,980 +تلاتة سواء كتبنا التلاتة في نص الإسم او كتبناها + +133 +00:11:12,980 --> 00:11:17,480 +قبل الإسم في نهاية كلنا فاهمين ان التلاتة تحدد + +134 +00:11:17,480 --> 00:11:25,550 +موقعالإين يعني لو حد كتب hex ثلاث إين two all صحيح + +135 +00:11:25,550 --> 00:11:35,550 +واضح هذه الأسماء في + +136 +00:11:35,550 --> 00:11:40,430 +هذه ال slide الحقيقة عندكم مجموعة كبيرة من + +137 +00:11:40,430 --> 00:11:45,550 +المركبات اللي بدكم تتعلموا كيف تسموها طبعا احنا + +138 +00:11:45,550 --> 00:11:51,060 +أخدنا أمثلة خلينا نقول كافيةفبنفيب هذه ال slide + +139 +00:11:51,060 --> 00:11:56,320 +على أساس إنكوا تدرسوها ربما أنابه فيها بس لشغلات + +140 +00:11:56,320 --> 00:12:01,720 +بسيطة أنه في ال IUPAC Nomenclature لما بنعمل احنا + +141 +00:12:01,720 --> 00:12:06,100 +الترقيم لما بنعمل الترقيم خلينا نفترض بال ال + +142 +00:12:06,100 --> 00:12:08,700 +الديهايتز وال الديهايتز بتكون ال c double bond o + +143 +00:12:08,700 --> 00:12:12,440 +تعيطة ع نمرة واحد الترقيم بيبدأ من نفس ال c double + +144 +00:12:12,440 --> 00:12:16,740 +bond oواضح يعني لما بيكون عندى الديهايد خليني + +145 +00:12:16,740 --> 00:12:21,600 +اوضحه بهذا الشكل هاي الديهايد رقم واحد وين بده + +146 +00:12:21,600 --> 00:12:28,040 +يكون هدي H هدا واحد هاي اثنين هاي تلاتة هاي اربعة + +147 +00:12:28,040 --> 00:12:34,920 +الان في نظم تسمية قديمة لما بيجوا بيحطوا نفترضها + +148 +00:12:34,920 --> 00:12:39,600 +نذرة بروم خليني نحطها نذرة بروم لو كنا بدنا نسمي + +149 +00:12:39,600 --> 00:12:39,800 +بال + +150 +00:12:43,000 --> 00:12:49,060 +على موقع اتنين هذا افترض وحطينا ذرة ايش برومين لما + +151 +00:12:49,060 --> 00:12:57,460 +ابدي اسمي بالايوبك شو هسمي المركب two bromobutanol + +152 +00:12:57,460 --> 00:13:03,780 +الان في نظام قديم لما يسموا هذا butyraldehyde اللي + +153 +00:13:03,780 --> 00:13:08,720 +هو ال common nomenclatureماشي لبيوتنال هو نفسه + +154 +00:13:08,720 --> 00:13:13,400 +بيوترالديهيد أخدناه في أول slides لما قلنا + +155 +00:13:13,400 --> 00:13:18,160 +بروبيونالديهيد وبيوتيرالديهيد الناس الشطرين اللي + +156 +00:13:18,160 --> 00:13:24,570 +بيحفظوا هاي بيوتنال بيوتيرالديهيدالان لو كنا بنسمي + +157 +00:13:24,570 --> 00:13:29,190 +فيه ال common nomenclature وبنعبر عن البروم هنا + +158 +00:13:29,190 --> 00:13:33,530 +بنعبرش بنظام الترقيم هذا لأ بنيجي بنقول والله + +159 +00:13:33,530 --> 00:13:39,150 +الموقع الأول بعد ال c double bond o بنعطيه alpha + +160 +00:13:39,150 --> 00:13:43,690 +الموقع اللي بعده beta الموقع اللي بعده gamma و + +161 +00:13:43,690 --> 00:13:48,570 +هكذا فلاحظوا ان الموقع alpha بالنسبة ل c double + +162 +00:13:48,570 --> 00:13:53,700 +bond o هو موقع ايشإتنين فلو هذا أنا بدي أسميه + +163 +00:13:53,700 --> 00:14:00,020 +butyraldehyde البرومو أين جاية عليه؟ على Alpha + +164 +00:14:00,020 --> 00:14:04,500 +فأنا بدي أجي أقول عنه Alpha Bromo يعني البرومو + +165 +00:14:04,500 --> 00:14:09,720 +جاية على موقع Alpha Butyraldehyde + +166 +00:14:09,720 --> 00:14:17,120 +واضح الفكرة؟فإذا استعملنا لوصف المواقع الجانب + +167 +00:14:17,120 --> 00:14:20,860 +السيضة بالـ bond O Alpha و Beta و Gamma أو كان + +168 +00:14:20,860 --> 00:14:24,220 +عندي أي شغل هان بقول هي بالنسبة للسيضة بال bond O + +169 +00:14:24,220 --> 00:14:29,900 +بنظام ال أيوبك على موقع اتنين بنظام ال common موقع + +170 +00:14:29,900 --> 00:14:35,440 +اتنين بيكون موقع Alpha مش Beta يعني مابنجيش نحط + +171 +00:14:35,440 --> 00:14:39,840 +Alpha هان و Beta هان لأ ال Alpha هي موقع اتنين + +172 +00:14:40,380 --> 00:14:45,300 +وبنمشي ولذلك هذا المركب مثلا واحد اتنين تلاتة حامل + +173 +00:14:45,300 --> 00:14:49,420 +OH بال .. بال IUPAC Nomenclature three + +174 +00:14:49,420 --> 00:14:57,130 +hydroxybutanol في اي مشكلة؟ three hydroxybutanolلو + +175 +00:14:57,130 --> 00:15:02,210 +كنا بدنا نسميه ايش هنسميه هى Alpha هى Beta Beta + +176 +00:15:02,210 --> 00:15:06,170 +-hydroxybutyraldehyde لاحظوا هذه اللى كتبناها EY + +177 +00:15:06,170 --> 00:15:12,910 +butyraldehyde Beta فموقع اتنين بيكون Alpha موقع + +178 +00:15:12,910 --> 00:15:18,330 +تلاتة بيكون Beta لو حد قرأ هالشغلة في يوم من + +179 +00:15:18,330 --> 00:15:21,890 +الأيام مايستغربش يعني مايفكرش ان واحد هيكون Alpha + +180 +00:15:21,890 --> 00:15:26,760 +اتنين Beta زى ما انتوا فاهمين لأ هو موقع اتنينفي + +181 +00:15:26,760 --> 00:15:32,080 +ال IUPAC بيكون Alpha في ال common nomenclature + +182 +00:15:32,080 --> 00:15:36,840 +طبعا بتيجي شغلات تانية، الان لو افترضتوا ان كان + +183 +00:15:36,840 --> 00:15:42,100 +عندكم ال ketone on طب لو صار عندكم اتنين C double + +184 +00:15:42,100 --> 00:15:49,830 +bond O ketone ايش هتستعمله؟ Dioneزي ما كان يكون ال + +185 +00:15:49,830 --> 00:15:55,330 +alcohol all كنا نستعمل die all و try all و تترا + +186 +00:15:55,330 --> 00:16:00,530 +all كذلك الحال لو كان عندنا تنتين كيتون الكيتون + +187 +00:16:00,530 --> 00:16:06,030 +الواحد on اتنين كيتون die on تلاتة كيتون try on + +188 +00:16:06,030 --> 00:16:13,030 +فهذا المركب مثلا سايكلو بنتان on ولا بنتان die on + +189 +00:16:13,030 --> 00:16:15,150 +هي on و on + +190 +00:16:18,010 --> 00:16:21,430 +Cyclopentane-dione ووجدت بلزم ان انا احط لهم ترقيم + +191 +00:16:21,430 --> 00:16:26,370 +اقل ترقيم وين موجودين اذا واحدة ع واحد التانية ع + +192 +00:16:26,370 --> 00:16:30,310 +تلاتة one three cyclopentane-dione وع نمره اتنين + +193 +00:16:30,310 --> 00:16:37,180 +حامل مثل وع اتنين حامل مثل بيصير هذا المركبتوتو + +194 +00:16:37,180 --> 00:16:43,720 +دايمثل وان ثري سايكلو بنتين دايون واضح الفكرة على + +195 +00:16:43,720 --> 00:16:48,480 +أي حال اتأملوا انتوا كتير في هذه الأسماء وفكروا + +196 +00:16:48,480 --> 00:16:52,380 +فيها لو تواجهتوا بأسئلة اسألوها ربما أحيانا + +197 +00:16:52,380 --> 00:17:00,560 +بتواجهكم مشكلة كمان في التسمية إذا وجد عندكم سلسلة + +198 +00:17:00,560 --> 00:17:07,440 +ألفتية مع حلقةلكن الأمر خلّيني أقول شبيه بالفكرة + +199 +00:17:07,440 --> 00:17:12,180 +اللي هو لو انوجد البنزين مع السلسلة الألفاتية هل + +200 +00:17:12,180 --> 00:17:21,520 +بدى أسمي نسبة للبنزين ولا نسبة للسلسلة حسب إيش + +201 +00:17:21,520 --> 00:17:26,140 +الأسهل كذلك الحال لو كان في عندى حلقة عادية مش + +202 +00:17:26,140 --> 00:17:31,650 +بنزين نفترض Cyclobutane ولا Cyclobropaneوعندي + +203 +00:17:31,650 --> 00:17:37,530 +سلسلة ألفاتية كيف أنا بدي أسمي المركب أكيد المركب + +204 +00:17:37,530 --> 00:17:45,050 +في هذه الحالة يحتمل تسميتين يعني خليني أعطيكم مثال + +205 +00:17:45,050 --> 00:17:54,610 +لو اتخيلنا هذا المثال وحطينا زي هيكوقلنالكم في + +206 +00:17:54,610 --> 00:17:59,770 +الامتحان سمي المركب التالي الان لاحظوا معي هذا + +207 +00:17:59,770 --> 00:18:07,050 +المركب فيه Cycle بروبين وفيه واحد اتنين تلاتة او + +208 +00:18:07,050 --> 00:18:13,290 +نخليهم اربعة احسن نخليهم اربعة مش مشكلة الان + +209 +00:18:13,290 --> 00:18:18,750 +بإمكاني اعمل تسميتين هل يا تورا لو سميته مشتق من + +210 +00:18:18,750 --> 00:18:31,620 +ال Cycle بروبينالمجموعة هذه إلها اسم .. + +211 +00:18:31,620 --> 00:18:38,140 +لاحظوا كل الناس .. كل الناس اللي قاعدين بعد كل + +212 +00:18:38,140 --> 00:18:43,520 +هالتعب و الشجر بيقولوا N و E هدولة من اللي بيتعبوا + +213 +00:18:43,520 --> 00:18:46,620 +القلب لسبب بسيط انه قلنا احنا من أول محاضرة + +214 +00:18:46,620 --> 00:18:52,680 +المجموعة تنتهي بنهاية YLمثل إثلبرو بالبيوت الأيزو + +215 +00:18:52,680 --> 00:18:57,020 +بيوت ال .. صح ولا لأ؟ ال .. فين ال .. المجموعة + +216 +00:18:57,020 --> 00:19:01,960 +بإيش بتنتهي؟ ب YL فكل جماعة بيوتين وبيوتين هدولة + +217 +00:19:01,960 --> 00:19:10,160 +جماعة غير مجتهدينالان مش هنيجي نحذر في القديم اللي + +218 +00:19:10,160 --> 00:19:13,800 +الناس مش متذاكرة قولنا اذا كانوا اربعة هي واحد + +219 +00:19:13,800 --> 00:19:17,960 +اتنين تلاتة اربعة والاتصال من موقع اتنين اسمها + +220 +00:19:17,960 --> 00:19:24,660 +secondary butyl ترجعوا عندكم بتلاحظوا secondary + +221 +00:19:24,660 --> 00:19:31,620 +butyl شايفين الناس اللي بدرسوش كتير secondary + +222 +00:19:31,620 --> 00:19:38,860 +butylاخدتوها بوضوح جدا سكندر بيوت الـ Cyclopropane + +223 +00:19:38,860 --> 00:19:45,020 +طيب الآن هنا اعتبرنا الأساس إيش؟ الـ Cyclopropane + +224 +00:19:45,020 --> 00:19:52,200 +هل يا تورا ممكن أننا نعتبر الأساس السلسلة؟ أكيد + +225 +00:19:52,200 --> 00:19:59,280 +لما نعتبر الأساس السلسلة، شو هنقول؟ البيوتين على + +226 +00:19:59,280 --> 00:20:04,020 +نمرأ اتنين من البيوتين، إيش عندكم؟ Cyclopropane + +227 +00:20:04,890 --> 00:20:09,350 +لحتى الآن مش عمال تقدروا تذكرواها بإنصيغة مجموعة + +228 +00:20:09,350 --> 00:20:15,030 +بزام Cyclopropane لما يصير مجموعة شو هيصير؟ + +229 +00:20:15,030 --> 00:20:21,290 +Cyclopropane اذا اتنين Cyclopropane + +230 +00:20:23,620 --> 00:20:30,420 +واضح؟ فالسكندري بيوت ال cyclopropane هو نفسه اتنين + +231 +00:20:30,420 --> 00:20:35,460 +cyclopropyl butane يعني انا لما اجيت اسميه .. انا + +232 +00:20:35,460 --> 00:20:39,800 +لما اجيت اسميه .. قولت يا تورا بدي اخلي مرجعيتي + +233 +00:20:39,800 --> 00:20:47,810 +الحلقة ولا اخلي مرجعيتي ايش؟السلسلة في هذا المركب + +234 +00:20:47,810 --> 00:20:52,470 +لأن هذه إلها اسم كمجموعة اسمها Cyclopropyl وهذه + +235 +00:20:52,470 --> 00:20:58,910 +إلها اسم secondary butyl فكانت تسميتين بالنسبة ليه + +236 +00:20:58,910 --> 00:21:05,570 +ممكنينفي هذه الحالة التسميتين بالنسبة له ممكنين بس + +237 +00:21:05,570 --> 00:21:10,990 +في مرات معينة بيكون فقط تسمية واحدة الممكنة + +238 +00:21:10,990 --> 00:21:13,950 +التسمية التانية بتصير مش ممكنة لان مافيش عنكم + +239 +00:21:13,950 --> 00:21:18,910 +مجموعات خلصنا من هذه الأشياء خليني أعطيكم مثال + +240 +00:21:18,910 --> 00:21:23,850 +مابتقدروش إلا تسموه بطريقة واحدة على نفس هذا + +241 +00:21:23,850 --> 00:21:31,670 +المثال لو إجيت يا تورا و حطيت هناأكلور و حطيت هنا + +242 +00:21:31,670 --> 00:21:44,170 +كمان بروم يعني هذه صارت إيش CH2BR و أجيتها مش + +243 +00:21:44,170 --> 00:21:48,590 +هتقدروا إلا تختاروا السلسلة ليش لأنه لو قلت + +244 +00:21:48,590 --> 00:21:56,340 +CycloPro بين الإسم طب هذه CH2BR CH CH CLالها اسم و + +245 +00:21:56,340 --> 00:22:00,800 +هتضطروا اضطرارا تختاروا ايش السلسلة الان ايش + +246 +00:22:00,800 --> 00:22:06,000 +السلسلة اللى عندكم بيوتين كام مجموعة بتحمل هذه + +247 +00:22:06,000 --> 00:22:13,560 +السلسلة بتحمل Cyclopropen بتحمل Brom بتحمل Chlor + +248 +00:22:13,560 --> 00:22:20,040 +بيحطوا مرتبين alphabetical واضح فهذه الحالة صرت + +249 +00:22:20,040 --> 00:22:26,420 +مضطر فقط ان اسمي على ايشالسلسلة او افترضوا مثلا لو + +250 +00:22:26,420 --> 00:22:38,460 +غيرنا هنا شوية خلينا هذه funnel لاحظوا + +251 +00:22:38,460 --> 00:22:41,920 +اللي بدى تفكر تسمي هذا المركب بالنسبة للبنزين + +252 +00:22:41,920 --> 00:22:49,050 +مستحيل ليش لأن هذهمالهاش اسم كمجموعة تفكر تسميه + +253 +00:22:49,050 --> 00:22:53,850 +بالنسبة للـcyclopropane صعب إيش أسهل نظام إذا تسمي + +254 +00:22:53,850 --> 00:22:58,170 +هذا المركب بالنسبة للسلسلة واحد اتنين تلاتة اربع + +255 +00:22:58,170 --> 00:23:01,930 +عليها تلات مجموعات وكل واحدة إيها اسم هذي بنعرف + +256 +00:23:01,930 --> 00:23:07,830 +اسمها Ibromo هذي بنعرف اسمها Phenyl هذي بنعرف + +257 +00:23:07,830 --> 00:23:17,100 +اسمها Cyclopropane إيش بيظل؟نذكرهم alphabetical + +258 +00:23:17,100 --> 00:23:21,120 +نذكرهم alphabetical شوفتوا كيف بنسمي هذا النوع من + +259 +00:23:21,120 --> 00:23:25,780 +المركبات إذا حيصير عندكم على سبيل المثال one + +260 +00:23:25,780 --> 00:23:32,700 +bromine two cyclopropane + +261 +00:23:32,700 --> 00:23:39,640 +three phenyl butane + +262 +00:23:43,880 --> 00:23:49,060 +واضحت الفكرة تماما + +263 +00:23:49,060 --> 00:23:57,740 +ولا فيها مشكلة الان طيب اذا هذا المثال دخل في ال + +264 +00:23:57,740 --> 00:24:03,920 +behind او كيتون يعني افترض انه خلته زي هي + +265 +00:24:13,410 --> 00:24:20,610 +ساعت بيكون بدي يكون واحد اتنين تلاتة اربعة بيوتنال + +266 +00:24:20,610 --> 00:24:27,570 +على نمرة اتنين Cyclopropyl على نمرة تلاتة فنل + +267 +00:24:27,570 --> 00:24:38,270 +وبنسميه كالديهيد او ككيتون اذا هذا بيوتنال وبنحط + +268 +00:24:38,270 --> 00:24:40,570 +two cyclopropyl + +269 +00:24:42,650 --> 00:24:49,870 +two cyclopropyl three phenyl كلمة واحدة ابيوتنال + +270 +00:24:49,870 --> 00:24:51,610 +واضح؟ + +271 +00:24:52,880 --> 00:24:56,800 +لاحظوا أن نظام التسمية .. نظام التسمية في الـ + +272 +00:24:56,800 --> 00:25:00,760 +organ الكميستري نظام systematic يعني اللي بيعود + +273 +00:25:00,760 --> 00:25:05,360 +نفسه عليه حتى لو الجزاء كبره و يمكن كان ما بتخيل + +274 +00:25:05,360 --> 00:25:09,480 +أنه كيف بدي أسمي هيك مركب مجرد بس أنه أفكر بأفكار + +275 +00:25:09,480 --> 00:25:14,500 +بسيطة أنه أنا عندي أطول سلسلة عندي عائلة أبحث عنها + +276 +00:25:14,500 --> 00:25:18,600 +و أسمي المركب بالنسبة إلها و بعد هيك عندي مجموعات + +277 +00:25:18,600 --> 00:25:24,980 +بيصير كل التسمية سهلةيعني كأنه نظام التسمية صار + +278 +00:25:24,980 --> 00:25:33,600 +بكلمات بسيطة أطول سلسلة منتهية باسمالعائلة فلو + +279 +00:25:33,600 --> 00:25:42,280 +كانت ال keen بتنتهي in ال keen in all ال on واضح؟ + +280 +00:25:42,280 --> 00:25:46,540 +وتوضع المجموعات أطول سلسلة منتهية باسم العائلة + +281 +00:25:46,540 --> 00:25:51,800 +ونضع المجموعات اللي بتطبق على هذا الكلام أي مركب + +282 +00:25:51,800 --> 00:25:54,700 +موجود عندها بتقدر تسميه شوفتوا كده سهل نظام + +283 +00:25:54,700 --> 00:25:59,300 +التسمية في ال organ ال chemistry أطول سلسلة منتهية + +284 +00:25:59,300 --> 00:26:07,310 +بإيش؟باسم العائلة والباقي مجموعات + +285 +00:26:07,310 --> 00:26:16,210 +عليها + +286 +00:26:16,210 --> 00:26:21,370 +الجميع الأمثل هذه يشوفوها الآن اخدنا احنا نفيه + +287 +00:26:21,370 --> 00:26:25,850 +مجموعات من الالكينز مثل اثلبروبل من الالكينز + +288 +00:26:27,730 --> 00:26:32,910 +Vinyl وقلل الان هل في من الـ Ketones و ال الديهيدس + +289 +00:26:32,910 --> 00:26:37,830 +مجموعات الجواب اه ال C double bond OH لو كانت + +290 +00:26:37,830 --> 00:26:44,710 +مجموعة بنسميها formal واضح ال C double bond O CH3 + +291 +00:26:44,710 --> 00:26:52,440 +Acetyl ال C double bond O فينيلبنزايل لأ لأ مش + +292 +00:26:52,440 --> 00:26:58,960 +بنزل بنزايل ليش لأنه احنا نبهنا ان الفن ال CH2 + +293 +00:26:58,960 --> 00:27:05,420 +بتهيألي سبق ان اعطينا هيك هلد هذه اسمها بنزل في + +294 +00:27:05,420 --> 00:27:09,940 +مجموعتين لو سمحتوا انتبهوا لهذه النقطة بنزل و + +295 +00:27:09,940 --> 00:27:19,620 +بنزايلتمام البنزول فنل CH2 و بناء + +296 +00:27:19,620 --> 00:27:25,680 +على ذلك لو افترضت مثلا ان انا حطيت هنا PR و حطيت + +297 +00:27:25,680 --> 00:27:32,060 +هنا PR و قلت بدأ اسمي هذا كمركب كامل هذا ايش بدأ + +298 +00:27:32,060 --> 00:27:40,510 +اسمي بنزول بروميد مجموعة و بعدين العائلةو هذا ايش + +299 +00:27:40,510 --> 00:27:50,510 +بده اسميه بنزلبروميد واضح فكلمة بنزل بتفرج عن + +300 +00:27:50,510 --> 00:27:53,890 +بنزول مرات كتير احنا لما نيجي نسألكوا السؤال في + +301 +00:27:53,890 --> 00:27:57,190 +الامتحان بنحطلكوا سهم بنكون بدنا ياكوا تكملوا + +302 +00:27:57,190 --> 00:28:00,490 +المعادلة لكي نتأكد نحطوا الأسماء فبحطلكوا على + +303 +00:28:00,490 --> 00:28:05,110 +السهم ان هذا اتفاعل مع ال بنزلبروميد الان اللي + +304 +00:28:05,110 --> 00:28:13,350 +مابتعرفش ترسم ال بنزلبروميد مش هتحلالمسألة واضحة + +305 +00:28:13,350 --> 00:28:20,870 +يعني ممكن اعطيكم ممكن اعطيكم مثال يعني تخيلوا انه + +306 +00:28:20,870 --> 00:28:28,170 +مثلا جيبنالكم سؤال CN minus مع الفينل كتبنا هنا لأ + +307 +00:28:28,170 --> 00:28:34,110 +بنزليبروميد بنزليبروميد + +308 +00:28:34,110 --> 00:28:37,370 +الان هذا السؤال على اي chapter + +309 +00:28:41,600 --> 00:28:46,040 +ع شبطر ستة لازم تيجوا تكونوا عارفين أن ال بنزيل + +310 +00:28:46,040 --> 00:28:53,300 +البروميد عبارة عن فينل CH2BR إذا هذا يعتبر + +311 +00:28:53,300 --> 00:29:00,980 +الكلهلايد مش ال PR متصل فيه بمجموعة إيش الكلهلايد + +312 +00:29:00,980 --> 00:29:05,020 +ماليش أنا في اللي بعدها هذا بتسماش ال الهلايد هذا + +313 +00:29:05,020 --> 00:29:07,820 +الكلهلايد أي نوع من ال الكلهلايد primary, + +314 +00:29:08,040 --> 00:29:13,690 +secondary, tertiaryPrimary طالما الـ PR متصلة بـ + +315 +00:29:13,690 --> 00:29:18,030 +CH2 إذا هذا الـ Primary Alkyl Halide فلو قلنا أكمل + +316 +00:29:18,030 --> 00:29:21,650 +هذه التفاعل ستقول الـ CNN تتفعل من الـ C أو من الـ + +317 +00:29:21,650 --> 00:29:30,110 +L؟ من الـ C تهاجم هنا تطرد الـ PR هي كلمة واحدة كل + +318 +00:29:30,110 --> 00:29:33,350 +اللي أخدناها في شبتر 6 أن الـ Alkyl Halide يصبح + +319 +00:29:33,350 --> 00:29:39,050 +عليهم إبدال إذا هنا النتيجة فين الـ CH2؟ + +320 +00:29:42,820 --> 00:29:48,920 +واضح؟فمثل هذه الأشياء اللي احنا بنحكيها بدكم رجاء + +321 +00:29:48,920 --> 00:29:54,540 +تتعلموا و تعودوا أنفسكم انكم تتدربوا و تكتبوا كتير + +322 +00:29:54,540 --> 00:30:00,640 +بمعنى اي طالبة هنا بنحكيه على الهواء مباشرة اي + +323 +00:30:00,640 --> 00:30:04,040 +طالبة بتسجل course organic و لاحظوا كم انا بستدعي + +324 +00:30:04,040 --> 00:30:07,920 +المعلومات السابقة و كم ال reaction اللي من عندكم + +325 +00:30:07,920 --> 00:30:13,770 +اي طالبة بتسجل course organicالاصل فيها بالنسبة لي + +326 +00:30:13,770 --> 00:30:20,950 +انه بذاك ال semester تكون وقفت ال facebook مافي + +327 +00:30:20,950 --> 00:30:26,010 +وقت لا لا ال facebook ولا لا مهندو نور ولا لا اي + +328 +00:30:26,010 --> 00:30:31,230 +اشي اللي بسجل course ال organic ولاحظوا ان تفاعلكم + +329 +00:30:31,230 --> 00:30:38,990 +معي بطيء جداليش؟ لأنه ليلة نهار .. ليلة نهار بدكم + +330 +00:30:38,990 --> 00:30:42,950 +تبقوا تعيدوا وترسموا فيها الأشياء وتحفظوها هذه + +331 +00:30:42,950 --> 00:30:46,710 +الجامعة و هذا العلم و اللي جابلكوا لما اتعلموا + +332 +00:30:46,710 --> 00:30:51,470 +تعبوا كتير و أنتوا الخيار بين أيديكم .. تتعبوا + +333 +00:30:51,470 --> 00:30:56,430 +كتير حتى لما الأستاذ بيحكي الكلمة أنتوا إيش؟ على + +334 +00:30:56,430 --> 00:31:00,670 +طول تتفاعلوا .. إذا شايفين هاي البنزل لو مثلا + +335 +00:31:00,670 --> 00:31:08,560 +قلنالكوا بدنا بنزل alcoholإيش هتحطوه؟ OH واضح؟ + +336 +00:31:08,560 --> 00:31:13,560 +بنزل ألكول، بدنا نحط OH لاحظوا إن هذه المجموعات + +337 +00:31:13,560 --> 00:31:19,180 +كلها بنسميها ASL، this is a general name اسم عائلة + +338 +00:31:19,180 --> 00:31:23,240 +عام ASL groups، الآن ال ASL groups أولادها + +339 +00:31:23,240 --> 00:31:28,560 +المشهورين مين؟ ال formal، ال acetal، ال benzoyl + +340 +00:31:29,530 --> 00:31:34,570 +وعشان هيك في هذه الأمثلة على سبيل المثال لاحظوا + +341 +00:31:34,570 --> 00:31:38,550 +هذا المركب اللي فيه SO3H اسمه sulfonic acid او + +342 +00:31:38,550 --> 00:31:43,910 +بنزين sulfonic acid على نمرة أربعة في واحد اتنين + +343 +00:31:43,910 --> 00:31:50,500 +تلاتة أربعة وجدت هذه المجموعة شو اسمها formalعشان + +344 +00:31:50,500 --> 00:31:56,660 +ايك بيصير four-formyl بنزين سالفونك أسد السالفونك + +345 +00:31:56,660 --> 00:32:02,240 +أسد أو بنزين سالفونك أسد ماخد الصيغة SO3H لو كنتوا + +346 +00:32:02,240 --> 00:32:05,080 +بتكونوا تفصلوها تفصيلي يعني S double bond O double + +347 +00:32:05,080 --> 00:32:13,140 +bond O OH هيك شكل مفصل طبعا ماحدش يسألنا ان السلفر + +348 +00:32:13,140 --> 00:32:19,830 +بياخد اتناشر إلكترون حواليه ست روابطاملاحظين انتوا + +349 +00:32:19,830 --> 00:32:26,190 +هنا ال sulfur كام رابطة حواليه؟ هايو قادرين + +350 +00:32:26,190 --> 00:32:32,150 +تعدوهم؟ ست روابط، كام إلكترون؟ ستة في اتنين، + +351 +00:32:32,150 --> 00:32:37,630 +اتنعاش، ابهيك بيكون متجاوز ال octet rule، بيصير + +352 +00:32:37,630 --> 00:32:40,770 +هذا الكلام في الكيميا؟ + +353 +00:32:42,680 --> 00:32:48,160 +لا مش من الشواذ بصير بسهولة طبعا انتبهوا معاه ان + +354 +00:32:48,160 --> 00:32:54,900 +ال octetrol بتشتغل على العناصر اللي في الدورة + +355 +00:32:54,900 --> 00:33:03,980 +التانية يعني carbon, nitrogen, oxygenلكن لما اتي + +356 +00:33:03,980 --> 00:33:08,680 +هنا مثلا الفوسفوراس تحت ال نيتروجين والسالفر هنا + +357 +00:33:08,680 --> 00:33:11,900 +تحت ال اكسوجين هدولة بيمشوش على ال اكترول هدولة + +358 +00:33:11,900 --> 00:33:15,600 +بياخدوا خمسة و بياخدوا عشرة يعني خمسة في اتنين + +359 +00:33:15,600 --> 00:33:20,180 +عشرة و بياخدوا اتماعش عشان هيك سهل ان نلاقي مثلا + +360 +00:33:20,180 --> 00:33:26,320 +مركب في الدنيا صيغته العامة BCL5 ايش هتسموه؟ + +361 +00:33:26,320 --> 00:33:31,200 +فوسفوراس؟Ventachloride بالـ General Chemistry اللي + +362 +00:33:31,200 --> 00:33:34,400 +أخدناها طب حطوا على الفوسفور خمس روابط و إلكترونين + +363 +00:33:34,400 --> 00:33:40,420 +عشرة فوسفوراس Ventachloride متجاوز الـ Octetrol + +364 +00:33:40,420 --> 00:33:45,320 +ولا لأ؟ متجاوزها ال Octetrol لهانا it's okay بس + +365 +00:33:45,320 --> 00:33:49,100 +فوسفور كابريت هدول على طول بتجاوز ال Octetrol و + +366 +00:33:49,100 --> 00:33:53,620 +هاي مثال و أشهر مثال الحمض اللي طول عمركوا عارفينه + +367 +00:33:53,620 --> 00:34:00,360 +من الإبتدائية ال sulphuric acidعارفينه؟ حمض + +368 +00:34:00,360 --> 00:34:03,760 +الكابريتيك لو قولنا لكوا إيش الشكل تبع الحمض + +369 +00:34:03,760 --> 00:34:10,640 +الكابريتيك H2SO4 لما نيجي نعمله شكل S double bond + +370 +00:34:10,640 --> 00:34:20,520 +O double bond O OH OH كام رابطة حوالين السلفر فهي + +371 +00:34:20,520 --> 00:34:27,330 +ال sulfuric acidطبعا لو بدنا نيجي نسأل سؤال للناس + +372 +00:34:27,330 --> 00:34:32,150 +الشاطرين ليش هدولة بتجاوزوش ال octet rule و هدولة + +373 +00:34:32,150 --> 00:34:33,890 +بتجاوزوا ال octet rule + +374 +00:34:37,930 --> 00:34:43,150 +ممتازة لأن هنا أنا عندى بس لحد ال B orbital و ال B + +375 +00:34:43,150 --> 00:34:46,930 +orbital سعة نهائية ثمانية هنا في عندى M T D + +376 +00:34:46,930 --> 00:34:51,150 +orbital التلاتة فيها D orbital ال D orbital لحاله + +377 +00:34:51,150 --> 00:34:54,770 +ممكن ياخد عشرة غير التعون ال B orbital فأي + +378 +00:34:54,770 --> 00:34:59,250 +إلكترونات زيادة تلت ال B orbital بتروح بتنحط وين؟ + +379 +00:34:59,250 --> 00:35:03,650 +في ال D orbitalالدورة التالتة فيها D-Orbital والـ + +380 +00:35:03,650 --> 00:35:07,790 +D-Orbital فيه 3D ولو أتيتوا توزعوا الإلكترونات لسه + +381 +00:35:07,790 --> 00:35:11,950 +ما زال 3D Zero فلو عملت روابط بزيادة كل + +382 +00:35:11,950 --> 00:35:16,090 +الإلكترونات أزايدة و أين هتروح؟ على الـ D-Orbital + +383 +00:35:16,090 --> 00:35:23,710 +الفاضي فيه واسع لكن هنا مافيش عندي وسع واضح؟ كذلك + +384 +00:35:23,710 --> 00:35:31,500 +الحالة لو بدنا نسمي مثلا هذا المركبcyclohexane على + +385 +00:35:31,500 --> 00:35:35,680 +نمرة واحد هذا الـcyclohexane شو بيحمل مجموعة هاي + +386 +00:35:35,680 --> 00:35:40,920 +واحد اتنين تلاتة اربعة خمسة ستة one cyclohexane + +387 +00:35:40,920 --> 00:35:47,280 +وعلى نمرة واحد بيحمل acetal هذا مثلا بنزويل حامل + +388 +00:35:47,280 --> 00:35:53,400 +اكلور شو بيكون بنزويل اكلورايد بنزويل اكلورايد + +389 +00:35:53,400 --> 00:35:59,680 +وحكينا هذا البنز الالكول عشان تميزه بنزويل عنبنزل + +390 +00:35:59,680 --> 00:36:07,500 +بس + +391 +00:36:07,500 --> 00:36:12,940 +هنا لإن انا عندي cycle مش عندياهم التانين في سلسلة + +392 +00:36:12,940 --> 00:36:18,920 +يعني لو التانين عندى في سلسلة واجيتها مابجيش انا + +393 +00:36:18,920 --> 00:36:23,600 +افكر بمجموعات راجعا هذه من الأخطاء من الأخطاء + +394 +00:36:23,600 --> 00:36:28,740 +الشائعة اللي أحيانا الناسممكن يقعوا فيها و اللي + +395 +00:36:28,740 --> 00:36:32,680 +نبهنا عليها من ايام ال alkanes ان لو عندى سلسلة + +396 +00:36:32,680 --> 00:36:38,520 +بفكرش نهائيا .. نهائيا بمجموعات قبل ما ابحث عن + +397 +00:36:38,520 --> 00:36:43,360 +اطول سلسلة و العائلة بمعنى ممكن طريقة كتابة السؤال + +398 +00:36:43,360 --> 00:36:47,740 +.. طريقة كتابة السؤال اتوجعكوا بالغلط يعني انا اجى + +399 +00:36:47,740 --> 00:36:51,820 +اطلب منكم تسمية المركبة التالية احطلكم c double + +400 +00:36:51,820 --> 00:37:00,150 +bond o ch3 و بعدينالان طالبة شوية صغيرة تعبة + +401 +00:37:00,150 --> 00:37:04,470 +اتذكرت يا الله سيضة بالبند OCH3 من طول الليل قاعد + +402 +00:37:04,470 --> 00:37:09,370 +بدرس انها مجموعة الاش ال Acetyl بناء على ذلك على + +403 +00:37:09,370 --> 00:37:15,150 +طول الحمد لله دراستنا جاوبت هاي ال Acetyl واحد + +404 +00:37:15,150 --> 00:37:23,610 +اتنين تلاتة one Acetyl ابروبينلأ بفكرش بمجموعة قبل + +405 +00:37:23,610 --> 00:37:27,930 +ما ابحث عن أطول سلسلة وعائلة الآن هذه صارت جزء من + +406 +00:37:27,930 --> 00:37:33,390 +إيش؟ سلسلة جزء من السلسلة بدي أرقم منها أن واحد + +407 +00:37:33,390 --> 00:37:40,150 +اتنين تلاتة أربعة خمسة هذا two بنتانون ماحدش يفكر + +408 +00:37:40,150 --> 00:37:44,470 +one acetyl أو في أي الدي هاي يطلع C double bond OH + +409 +00:37:44,470 --> 00:37:53,460 +يقول formal واضح؟ ما بنفكر؟بمسمى مجموعة إلا بعد ما + +410 +00:37:53,460 --> 00:37:58,020 +نبحث عن أطول سلسلة لأن إذا أطول سلسلة بتختارق هذه + +411 +00:37:58,020 --> 00:38:04,580 +المجموعة لازم تختارقها واضح الكلام تماما زي لما + +412 +00:38:04,580 --> 00:38:08,880 +كنا هنقولكم أنه في أي سلسلة طويلة كان ممكن تاخدوا + +413 +00:38:08,880 --> 00:38:12,700 +الطرف و تسموه مثل أو أول ذرتين تسموهم اثل بس هذا + +414 +00:38:12,700 --> 00:38:13,560 +الكلام بيصير + +415 +00:38:17,020 --> 00:38:22,540 +فهنا مش موجودين بشكل سلسلة الان + +416 +00:38:22,540 --> 00:38:26,140 +في عند بعض ال common aldehydes and ketones ال + +417 +00:38:26,140 --> 00:38:30,700 +aldehydes و ال ketones اللي مشهورة و بنحب نتعرف + +418 +00:38:30,700 --> 00:38:36,540 +عليها أكتر منها أبسط ال aldehyde ال formaldehyde + +419 +00:38:36,540 --> 00:38:42,700 +اللي هو ماخد CH2 double bond O الان لاحظوا ال + +420 +00:38:42,700 --> 00:38:47,830 +formaldehyde هو عبارة عن غازنقطة الغليان تبعه + +421 +00:38:47,830 --> 00:38:53,270 +تناقص واحد وعشرين درجة مئوية هذا + +422 +00:38:53,270 --> 00:38:57,730 +ال formaldehyde عادة بيحضروا بأكسدة الميثانول + +423 +00:38:57,730 --> 00:39:02,210 +بياخدوا ميثانول بيسخنوه هذا تحضير صناعي مع الفضة + +424 +00:39:02,210 --> 00:39:05,450 +ككتلة ستمية سبعمية درجة مئوية بيفقد اتش منها لو + +425 +00:39:05,450 --> 00:39:13,060 +اتش منها بيصير ايش؟يعني زي هيك هيو C O H و هذه + +426 +00:39:13,060 --> 00:39:17,660 +حاملة H وهي كمان H وهي كمان H لما بدنا نسخله بده + +427 +00:39:17,660 --> 00:39:21,640 +يفقد كام هيدروجينة؟ تنتين عشان هيك هذه بنقول عنها + +428 +00:39:21,640 --> 00:39:25,680 +أكسدة وهذه بتصير double bond هيه صار الديهايد + +429 +00:39:25,680 --> 00:39:31,400 +واضح؟ مشقولنا الأكسدة فقد هيدروجنتين متجاورتين أو + +430 +00:39:31,400 --> 00:39:34,420 +نقص في محتوى الهيدروجين أكسدة زيادة في محتوى + +431 +00:39:34,420 --> 00:39:40,090 +الهيدروجين اختزاننقص محتوى الهيدروجين اكسدا زيادة + +432 +00:39:40,090 --> 00:39:45,290 +محتوى الهيدروجين اختزال زيادة محتوى الاكسجين اكسدا + +433 +00:39:45,290 --> 00:39:53,290 +نقص محتوى الاكسجين اختزال واضح الفكرة ولا اوضحها + +434 +00:39:53,290 --> 00:39:59,570 +اكتر لحظة بس لو سمحت في مرات انا دايما المبادئ + +435 +00:39:59,570 --> 00:40:05,260 +الاساسية بحب ان اركز عليها اكتريعني هذا المُركّب + +436 +00:40:05,260 --> 00:40:10,660 +الالكول ليش بدي أركز الآن عليها لأنه هيجينا أكسدة + +437 +00:40:10,660 --> 00:40:15,920 +الكحولات واخدناها سابقاً و بعد الكحولات قلنا + +438 +00:40:15,920 --> 00:40:19,960 +بتتأكسد الالديهايت أو كيتون الآن لما نيجي ندرس + +439 +00:40:19,960 --> 00:40:22,980 +تفاعل الالديهايت أو كيتون هذا لما حدف + +440 +00:40:22,980 --> 00:40:28,890 +الهيدروجينتينبهذا الشكل وعملت double bond minus H2 + +441 +00:40:28,890 --> 00:40:38,030 +إيش صار؟ C double bond O H H الأن لاحظوا معي لما + +442 +00:40:38,030 --> 00:40:42,070 +أنا بيتعرف ال X ده بال organ ال chemistry بتعرفها + +443 +00:40:42,070 --> 00:40:48,270 +بتعرفين و التعرفين صحيحاتإذا قولت زيادة في الاتصال + +444 +00:40:48,270 --> 00:40:51,410 +بالأكسوجين يعني هنا الأكسوجين كان بين ال carbon و + +445 +00:40:51,410 --> 00:40:56,270 +ال oxygen كان مرابطة واحدة جداش صاروا تلتل فزيادة + +446 +00:40:56,270 --> 00:40:59,150 +في المحتوى الأكسوجين أو في الاتصال بالأكسوجين هذه + +447 +00:40:59,150 --> 00:41:04,920 +أكسدة أو نقص في المحتوى الهيدروجينيالان لما بدي + +448 +00:41:04,920 --> 00:41:09,460 +اجي اعرف الاختزال العملية المعاكسة يعني احنا في + +449 +00:41:09,460 --> 00:41:12,620 +شبتر سبعة أخدنا أكسدة الكحولات وبتصير ال aldehydes + +450 +00:41:12,620 --> 00:41:18,540 +و ال ketones في شبتر تسعة هنرجع ايش نقول اختزال ال + +451 +00:41:18,540 --> 00:41:21,560 +aldehydes و ال ketones يعني بصير بده اضيف عليهم + +452 +00:41:21,560 --> 00:41:28,580 +ايش هيدروجين زائد هيدروجينبصير زيادة في محتوى + +453 +00:41:28,580 --> 00:41:33,700 +الهيدروجين او نقص في محتوى الاكسجين هذا ايش اسمه + +454 +00:41:33,700 --> 00:41:37,180 +reduction الان تخيلوا ان كل هذا الكلام ممكن + +455 +00:41:37,180 --> 00:41:42,860 +نسألكوا اياها بسؤال صح و غلط يعني increasing the + +456 +00:41:42,860 --> 00:41:45,700 +content of hydrogen is + +457 +00:41:50,420 --> 00:41:54,460 +decreasing the content of hydrogen is oxidation + +458 +00:41:54,460 --> 00:41:58,120 +increasing the content of oxygen is oxidation + +459 +00:41:58,120 --> 00:42:04,540 +decreasing the content of oxygen isReduction، + +460 +00:42:04,540 --> 00:42:09,540 +واضحة الفكرة؟ عشان هيك، يعني أنا عوّدت، ركزت على + +461 +00:42:09,540 --> 00:42:14,540 +هذه النقطة فعملية تحويل الـ Methanol to + +462 +00:42:14,540 --> 00:42:17,780 +Formaldehyde، هذه العملية هي عملية Ash + +463 +00:42:20,380 --> 00:42:26,460 +Oxidation الآن هذا ال Formaldehyde عادة احنا بناخد + +464 +00:42:26,460 --> 00:42:30,800 +الغاز و بندوبه في الميه بيصير محلول اسمه Formalin + +465 +00:42:30,800 --> 00:42:35,720 +بدوب لحد 37% تماما زي الناس اللي بدكره من المدرسة + +466 +00:42:35,720 --> 00:42:41,600 +لما كنا ندوب غاز HCL في الميه ايش يعطينا؟ حمض + +467 +00:42:41,600 --> 00:42:47,080 +الهيدروكلوريك لما كنا ندوب غاز ال S O2 في الميه + +468 +00:42:47,080 --> 00:42:55,170 +ايش كان يعطينا؟حمد الكابريتوز بالعربي sulfuric + +469 +00:42:55,170 --> 00:42:58,790 +acid أي غاز اللي بندوبه في الميه بيعطينا حمد + +470 +00:42:58,790 --> 00:43:06,130 +الكابريتيك اه يعني لما نجيبلكم dissolving فراغ in + +471 +00:43:06,130 --> 00:43:13,060 +water produces sulfuric acidS O 3 في الميه بيعطي + +472 +00:43:13,060 --> 00:43:18,760 +حمض الكابريتيك S O 2 في الميه بيعطي حمض الكابريتوز + +473 +00:43:18,760 --> 00:43:23,940 +اللي هما اسمهم سالفاريك و سالفاراس و دايما ال اك + +474 +00:43:23,940 --> 00:43:31,080 +بتعني زيادة في الاكسجين اكتر من ال OUS سالفاريك + +475 +00:43:31,080 --> 00:43:40,800 +سالفاراس نيترس نيترس نيتريك حمض النيتريك ايشHMO3 + +476 +00:43:40,800 --> 00:43:49,820 +حمض النيتروز HMO2 كويس فهذا ال Formaldehyde بندوبه + +477 +00:43:49,820 --> 00:43:55,860 +في الميه بدوب بنسبة 37% بيعمل محلول بنسميه + +478 +00:43:55,860 --> 00:43:59,160 +Formalin و احنا عادة نتعامل بال Formalin هذا ال + +479 +00:43:59,160 --> 00:44:03,040 +Formalin هو اللي بيحطوا فيه الجثث اللي أثناء ما + +480 +00:44:03,040 --> 00:44:07,080 +بيكونوا بيشرحوا الأنسج اللي بدهم يحتفظوا فيهاالان + +481 +00:44:07,080 --> 00:44:10,520 +هذا بدكوا تهتموا كتير فيه عارفين ليش؟ جزء كبير + +482 +00:44:10,520 --> 00:44:14,920 +منكوا اللي بده يدرس تحليل هيضطر في لحظة من اللحظات + +483 +00:44:14,920 --> 00:44:19,200 +انه في عينات بده تنقل يعني نفترض انه من مريض معين + +484 +00:44:19,200 --> 00:44:23,540 +طاله عينة بيشكوا انه يمكن تكون هذه العينة فيها ورم + +485 +00:44:23,540 --> 00:44:28,250 +لازم نبعتها لمختبر ال NC جاي يحللهاالان يا ترى هال + +486 +00:44:28,250 --> 00:44:32,630 +دكتور اللي طال العينة في الجراحة استقصالها بده + +487 +00:44:32,630 --> 00:44:36,850 +يسيبها برا ولا يحطها بكيس نايلون و تاخدلها يومين + +488 +00:44:36,850 --> 00:44:40,770 +مع السواجين و مع الإسعاف و كذا لحد ما تصل للمختبر، + +489 +00:44:40,770 --> 00:44:45,390 +شو بيكون صار فيها؟ بتكون خربت، طب ها إيش الحال؟ + +490 +00:44:45,390 --> 00:44:50,010 +مجرد ما بده يطول العينة اللي بده يبعتها للمختبر + +491 +00:44:50,010 --> 00:44:55,070 +للتحليل، بده يحطها بمحلول فورماليواضح؟ بده يحطها + +492 +00:44:55,070 --> 00:45:00,590 +بمحلول Formalin .. تعون الطب لما بيدرسه تشريح + +493 +00:45:00,590 --> 00:45:05,790 +الجثث .. الجثة بيكون عندهم بانيو كامل ملان + +494 +00:45:05,790 --> 00:45:09,890 +Formalin .. بيحطوا الجثة فيه و بيغطوها .. وقت ما + +495 +00:45:09,890 --> 00:45:12,870 +بتلزمهم .. بيطولوا الجثة من ال Formalin .. بتطلعوا + +496 +00:45:12,870 --> 00:45:15,070 +.. بيشوفوا الأشياء اللي بدونيها .. بيعودوا يرجعوها + +497 +00:45:15,070 --> 00:45:19,090 +بال Formalinفسواء قلنا إننا بنستعمل ولا نوع من + +498 +00:45:19,090 --> 00:45:23,230 +التحنيط أو الحفظ أو الجثث، بدنا نكون عارفين بالظبط + +499 +00:45:23,230 --> 00:45:31,220 +إيش يعنيهالفورمالين من الأشياء أيضا ال الديهيد + +500 +00:45:31,220 --> 00:45:34,820 +التاني لبعد ال formaldehyde شو اسمه ال + +501 +00:45:34,820 --> 00:45:40,740 +acetaldehyde عادة بيعملو بال oxidation للإيثيلين + +502 +00:45:40,740 --> 00:45:45,460 +في وجود ال oxygen بالاديوم عند حرارة معينة بيصير + +503 +00:45:45,460 --> 00:45:51,040 +عند إيش؟الديهيد بيسموه Walker Synthesis يعني كأن + +504 +00:45:51,040 --> 00:45:55,060 +أضفنا الميه و بعدين حذفنا الهيدروجين هنا إفليل + +505 +00:45:55,060 --> 00:45:59,860 +بيصير أسيتال ديهيد هذا تحضير صناعي والأسيتال ديهيد + +506 +00:45:59,860 --> 00:46:02,780 +boiling point عشرين يعني بيزيد عن ال formal ديهيد + +507 +00:46:02,780 --> 00:46:08,260 +بكم درجة واحد واربعين درجة + +508 +00:46:10,430 --> 00:46:14,630 +المُركّب التالت المشهور الـ Acetone نفس الـ Walker + +509 +00:46:14,630 --> 00:46:17,310 +Synthesis على الـ Double Bond اللي هنا بنضيف + +510 +00:46:17,310 --> 00:46:22,070 +أكسجين في بلاديام كاربون لكن بيحط الأكسجين وين؟ + +511 +00:46:22,070 --> 00:46:25,710 +على الكاربون الوسطاني بيعطيني أسيتون كل هذه + +512 +00:46:25,710 --> 00:46:30,270 +التحذيرات تحذيرات في الصناعة يعني لو قلنا كيف + +513 +00:46:30,270 --> 00:46:35,190 +بنحضر الأسيتون في الصناعة بروبيليين مع أكسجين في + +514 +00:46:35,190 --> 00:46:41,080 +الشروط هذهطبعا ممكن الاسيتون كمان احضروه من + +515 +00:46:41,080 --> 00:46:45,200 +الكيومين هذا المركب ال isopropyl بنزين مين فيكم + +516 +00:46:45,200 --> 00:46:51,000 +اتذكر انه سمناه كيومين؟هذا الكيومين مع الـ Oxygen + +517 +00:46:51,000 --> 00:46:55,540 +و Sulphuric Acid بيكسل تفاعل كتير هذا مهم لسبب + +518 +00:46:55,540 --> 00:46:59,820 +بسيط انه بيعطي ناتجين مهمات مش ناتج واحد من هنا + +519 +00:46:59,820 --> 00:47:05,240 +بيكسل هذه بتصير CWO وهذه بتصير CWO الآن هذا الجزء + +520 +00:47:05,240 --> 00:47:13,100 +CH3 CH3 هو ايش ال Acetone هذا الجزء بيحول الى Enol + +521 +00:47:13,100 --> 00:47:19,790 +بيصير Phenolفتفاعل الكيومين مع الأكسجين وحمض + +522 +00:47:19,790 --> 00:47:25,110 +الكابريتيك إيش بيعطينا؟ Phenol and Acetone يعني لو + +523 +00:47:25,110 --> 00:47:28,910 +بدنا نسألكوا reaction of الكيومين with أكسجين و + +524 +00:47:28,910 --> 00:47:34,130 +presence of sulphuric acid بطريقة معينة produces + +525 +00:47:34,130 --> 00:47:40,050 +Phenol and Acetone و هدولة المركبين إيش مالهم؟ + +526 +00:47:40,050 --> 00:47:43,870 +مركبات مهمة جدا في ال organ الchemistry + +527 +00:47:46,550 --> 00:47:50,490 +لحد هنا بننهي اليوم ان شاء الله إلى اللقاء + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..aa25b61a0712e022c2403bc9cfd49df2a1c40792 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4225, "start": 19.51, "end": 42.25, "text": "بسم الله الرحمن الرحيم المرة الماضية بدأنا في 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{"start": 2317.54, "end": 2319.02, "word": " شغلة،", "probability": 0.93701171875}, {"start": 2319.02, "end": 2319.5, "word": " different", "probability": 0.94580078125}, {"start": 2319.5, "end": 2320.04, "word": " names", "probability": 0.9091796875}], "temperature": 1.0}, {"id": 99, "seek": 234091, "start": 2321.09, "end": 2340.91, "text": "واضح؟ عشان ايك، لاحظوا واحد كان اسمه glycerol بالميتو ستيرو أوليات، التاني glycerol ستيرو بالميتو أوليات، الآن هذول أخدوا different names ولا لأ؟ طالما different names، إذا they are structural isomers، ال stereo isomers كانوا ياخدوا نفس الاسم", "tokens": [2407, 46958, 5016, 22807, 6225, 8592, 7649, 1975, 1829, 4117, 12399, 20193, 5016, 19913, 14407, 36764, 24401, 25961, 24525, 2304, 3224, 22633, 1776, 401, 20666, 2304, 36081, 2407, 8608, 2655, 13546, 2407, 5551, 12610, 1829, 9307, 12399, 16712, 7649, 1829, 22633, 1776, 401, 8608, 2655, 13546, 2407, 20666, 2304, 36081, 2407, 5551, 12610, 1829, 9307, 12399, 6024, 48506, 8032, 8848, 12610, 5551, 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الإسم", "tokens": [33911, 2288, 4587, 14407, 4724, 3794, 8978, 29739, 18513, 28671, 8978, 2423, 7649, 7649, 8592, 2407, 3714, 9640, 11622, 497, 49429, 318, 49429, 9122, 15730, 4032, 41185, 2423, 16254, 995, 14851, 13546, 1829, 2407, 3714, 9640, 11622, 318, 34051, 6531, 34051, 1176, 34051, 462, 912, 1315, 4032, 41361, 14407, 7251, 47283, 3215, 14407, 819, 42585, 29739, 18513, 28671, 13672, 1829, 39894, 2407, 9381, 5172, 25124, 28820, 27188, 2288, 5718, 118, 1829, 37893, 8608, 2304, 1829, 8315, 11296, 42585, 29739, 18513, 28671, 2423, 497, 34051, 2423, 318, 34051, 2423, 1176, 34051, 2423, 462, 34051, 2423, 318, 34051, 2423, 6531, 44381, 11933, 1211, 16095, 8717, 36178, 2423, 33599, 8717, 36178, 33688, 38251], "avg_logprob": -0.18947071723035863, "compression_ratio": 1.9059829059829059, "no_speech_prob": 0.0, "words": [{"start": 2341.86, "end": 2342.58, "word": "يفرقوا", "probability": 0.68511962890625}, {"start": 2342.58, "end": 2342.94, "word": " بس", "probability": 0.964111328125}, 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detergents بشكل أساسي بدأنا + +3 +00:00:28,170 --> 00:00:33,130 +نتعرف على ال triglycerides و قلنا أن ال + +4 +00:00:33,130 --> 00:00:39,410 +triglycerides من شغلتين من إجليسرول اللي هو بيمثل + +5 +00:00:39,410 --> 00:00:44,310 +جزء ال alcohol و fatty acidواضح هدول لما بتحدوا مع + +6 +00:00:44,310 --> 00:00:49,490 +بعض بيعملوا عندنا إيش لـ triglycerides لو عملنا + +7 +00:00:49,490 --> 00:00:53,110 +hydrolysis تكسير لـ triglycerides ب Sodium + +8 +00:00:53,110 --> 00:00:58,650 +hydroxide بنحصل على إجليسرين و fatty acids الآن ال + +9 +00:00:58,650 --> 00:01:03,790 +fatty acids عرفناهم إنهم carboxylic acids عادية + +10 +00:01:03,790 --> 00:01:08,610 +يعني فيهم مجموعة COOH لكن السلسلة اللي موجودة فيهم + +11 +00:01:08,610 --> 00:01:15,130 +بشكل عامسلسلة طويلة و بذلك بيغلب عليهم جانب ال non + +12 +00:01:15,130 --> 00:01:21,410 +-polarity و بالتالي بيصيروا بيدوبوا في المذيبات + +13 +00:01:21,410 --> 00:01:27,910 +العضوية بشكل عامالان لو بدنا نتعرف اكتر على ال + +14 +00:01:27,910 --> 00:01:32,130 +fatty acids، بنقول ال fatty acids في منهم fatty + +15 +00:01:32,130 --> 00:01:37,850 +acids saturated، واضح؟ معنى saturated انه موجود + +16 +00:01:37,850 --> 00:01:41,330 +فيهم ولا double bond، مافيش فيهم double bonds، وفي + +17 +00:01:41,330 --> 00:01:45,670 +unsaturated فيهم double bond او اكتر، واضح؟ فيهم + +18 +00:01:45,670 --> 00:01:51,130 +double bond او اكترالان بشكل عام ال fatty acids + +19 +00:01:51,130 --> 00:01:55,630 +اللي موجودين في الزيوت و في الدهون بيكونوا عدد ال + +20 +00:01:55,630 --> 00:02:01,190 +carbons اللي فيهم عدد زوجييعني هتلاحظوا لما نتعرف + +21 +00:02:01,190 --> 00:02:08,450 +عليهم هنبدأ من 12، 14، 16، 18، 20، مش هنحكي عن 13، + +22 +00:02:08,450 --> 00:02:14,010 +مش هنحكي عن 15، واضح؟ هذا بيرجع حقيقة إلى فكرة + +23 +00:02:14,010 --> 00:02:17,630 +تحضيرهم في الجسم أنه هي فكرة مضاعفات اتنين، يعني + +24 +00:02:17,630 --> 00:02:21,870 +بيكون في عندى اتنينبيجيهم كمان اتنين بيصيروا اربعة + +25 +00:02:21,870 --> 00:02:24,730 +كمان اتنين بيصيروا ستة كمان اتنين بيصيروا تمانية + +26 +00:02:24,730 --> 00:02:29,050 +فزيادة اتنين اتنين اتنين ولذلك لو بدنا نقول انه + +27 +00:02:29,050 --> 00:02:33,530 +عدد ال carbons في ال fatty acids odd ولا even + +28 +00:02:33,530 --> 00:02:40,970 +الجواب even واضح؟الان المشهورين منهم .. المشهورين + +29 +00:02:40,970 --> 00:02:47,970 +منهم اللوريك أسد بنسميه اللي فيه اتناشر كاربون بعد + +30 +00:02:47,970 --> 00:02:54,670 +هيك ميريستك أسد اربعة عشر كاربون بالميتك أسد هذا + +31 +00:02:54,670 --> 00:03:00,210 +من البلم يعني زيت الاش النخيل بالميتك أسد ستة عشر + +32 +00:03:00,210 --> 00:03:07,250 +استيرك أسداللي هو حامض ضهني تمنتعش و arachidic + +33 +00:03:07,250 --> 00:03:12,830 +acid .. arachidic acid اللي هو إيش؟ عشرين يمكن لما + +34 +00:03:12,830 --> 00:03:19,110 +تسمعوا كلمة stearic تظل في مخكم تخربطلها مع كلمة + +35 +00:03:19,110 --> 00:03:27,970 +تانية مع حمض تاني citric acid مرات + +36 +00:03:27,970 --> 00:03:32,320 +اللي ..اللي بيكون مش متعود ع الكلام بيخلطوا + +37 +00:03:32,320 --> 00:03:36,720 +الكلمتين citric استيرك بيصير خربطهم citric acid + +38 +00:03:36,720 --> 00:03:45,100 +حمض اللمون حمض اللمون و citronel لمون واضح؟ الآن + +39 +00:03:45,100 --> 00:03:49,940 +استيرك حمض دهني ال citric acid حامض تاني بشكل معين + +40 +00:03:49,940 --> 00:03:54,500 +فيه تلت مجموعات carboxylic acids مش موضوعنا فلما + +41 +00:03:54,500 --> 00:04:00,350 +نقول citric غير عنstearic ولذلك انتوا لما تكونوا + +42 +00:04:00,350 --> 00:04:05,110 +تقرأوا المكونات ضالكوا ميزوا عن الشغلتين عن بعض + +43 +00:04:05,110 --> 00:04:12,250 +يعني لو بتقرأوا مثلا في مادة أخذية على سبيل المثال + +44 +00:04:12,250 --> 00:04:18,710 +مع شوية drops للزور لإشي زي هيك يمكن تلاقوا citric + +45 +00:04:18,710 --> 00:04:24,570 +acid حمض لمون لكن لو بتقرأوا في شامبوهات وغيرها + +46 +00:04:24,570 --> 00:04:30,350 +وغيراتها يمكن تلاقوا stearicفستيرك شيء وستريك شيء + +47 +00:04:30,350 --> 00:04:35,190 +الاستيرك أسد is a fatty is a saturated fatty acid + +48 +00:04:35,190 --> 00:04:40,550 +in fact containing 18 carbon atoms واضح الفكرة + +49 +00:04:40,550 --> 00:04:45,890 +الان لاحظوا لو اطلعتوا على ال melting point لهذه + +50 +00:04:45,890 --> 00:04:50,190 +المركبات اربعة واربعين تمانية وخمسين تلاتة وستين + +51 +00:04:50,190 --> 00:04:55,170 +يعني كلهم ايش solids in principle الان لو انتقلنا + +52 +00:04:55,170 --> 00:05:01,440 +علىالـ unsaturated acids اللي فيهم double bonds + +53 +00:05:01,440 --> 00:05:06,360 +لاحظوا لو اجينا في عندي double bond واحدة بتبدأ + +54 +00:05:06,360 --> 00:05:11,060 +على الموقع تسعة على carbon تسعة بيصير الحامض اسمه + +55 +00:05:11,060 --> 00:05:18,380 +oleic acid الأن لو في عندي تنتين double bonds بعد + +56 +00:05:18,380 --> 00:05:23,750 +هيك لينوليك أسدلو في عندى تلاتة double bonds + +57 +00:05:23,750 --> 00:05:29,910 +لينولينيك لينولينيك لينولينيك لينولينيك لينولينيك + +58 +00:05:29,910 --> 00:05:34,630 +واضح هنا double bond واحدة تلتين تلاتة + +59 +00:05:36,580 --> 00:05:40,760 +بالنظر إلى ال melting point لهدول المركبات لاحظوا + +60 +00:05:40,760 --> 00:05:44,700 +معايا اللي فيه .. اللي فيش فيه double bond يعني + +61 +00:05:44,700 --> 00:05:50,460 +هدول كلهم 18 carbon atom 18 .. 18 .. 18 .. و ال + +62 +00:05:50,460 --> 00:05:53,640 +stearic 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. + +63 +00:05:53,640 --> 00:05:55,780 +18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 + +64 +00:05:55,780 --> 00:05:58,060 +.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. + +65 +00:05:58,060 --> 00:06:01,660 +18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 + +66 +00:06:01,660 --> 00:06:04,200 +.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. + +67 +00:06:04,200 --> 00:06:06,040 +18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 + +68 +00:06:06,040 --> 00:06:06,040 +.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. + +69 +00:06:06,040 --> 00:06:06,040 +18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 + +70 +00:06:06,040 --> 00:06:06,040 +.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. + +71 +00:06:06,040 --> 00:06:06,200 +18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 + +72 +00:06:06,710 --> 00:06:12,510 +إذا خلصنا من السؤال كل ما زاد كلهم تمنتعش الآن + +73 +00:06:12,510 --> 00:06:18,390 +لاحظوا معاه هنا مافيش عندي double points بعد هيك + +74 +00:06:18,390 --> 00:06:23,590 +كانت ال melting point سبعين بعدك صار عندي one + +75 +00:06:23,590 --> 00:06:28,720 +double point نزلتلتلت عشر صار عندى تنتين double + +76 +00:06:28,720 --> 00:06:33,340 +points نزلت لناقص خمسة صار عندى تلاتة double + +77 +00:06:33,340 --> 00:06:39,320 +points نزلت لأكم لناقص احد عشر اذا بنقدر احنا + +78 +00:06:39,320 --> 00:06:45,180 +نستنتج انه كل ما بيزيدوا ال double points او as + +79 +00:06:45,180 --> 00:06:49,180 +the unsaturation increases يعني كل ما بيزيد عدم + +80 +00:06:49,180 --> 00:06:55,720 +التشبع ال melting point بتصير اقلكل ما بيزيد عدم + +81 +00:06:55,720 --> 00:06:59,920 +التشبع كل ما ال melting point لل fatty acid بتصير + +82 +00:06:59,920 --> 00:07:05,940 +ايش اقل طبعا هذا الكلام بحاجة الى تفسير ليش ال + +83 +00:07:05,940 --> 00:07:09,900 +saturated fatty acids in general اللي هو ال + +84 +00:07:09,900 --> 00:07:14,060 +melting point عالية ال unsaturated منخفضة لاحظوا + +85 +00:07:14,060 --> 00:07:17,960 +هنا السبعين معناه على حرارة الغرفة تبعتنا احنا + +86 +00:07:17,960 --> 00:07:22,740 +معدل حرارة الغرفة خمسة وعشرين تلاتين solidالان + +87 +00:07:22,740 --> 00:07:28,960 +التلتعش في الجو تبعنا اليوم هيكون سائل لأن الحرارة + +88 +00:07:28,960 --> 00:07:32,580 +خمسة و عشرين عندنا فهو لما بنصار عن التلتعش إن أنا + +89 +00:07:32,580 --> 00:07:36,180 +سائل، إن ناقص خمسة أكيد سائل، إن ناقص إحد أش سائل، + +90 +00:07:36,180 --> 00:07:40,640 +يعني كأنه بنقدر ناخد معلومة جديدة إن ال + +91 +00:07:40,640 --> 00:07:48,350 +unsaturated they are liquidsيعني انسهار أو انخفاض + +92 +00:07:48,350 --> 00:07:51,630 +نقطة الانسهار تبعهم تخلهم liquids ال saturated + +93 +00:07:51,630 --> 00:07:59,770 +they are solids الاناذي + +94 +00:07:59,770 --> 00:08:05,690 +القصة جديرة ان نكون احنا متوقفين عندها خلينا ناخد + +95 +00:08:05,690 --> 00:08:10,920 +اذا شوية معلومات تساعدنا نفسر هذا الكلامأول اشي + +96 +00:08:10,920 --> 00:08:14,600 +most fatty acids are unbranched يعني ال fatty + +97 +00:08:14,600 --> 00:08:19,080 +acids سلاسل غير متفرعة سلسلة طويلة واضحة مافيها + +98 +00:08:19,080 --> 00:08:24,690 +branchingand contain an even number of carbon + +99 +00:08:24,690 --> 00:08:29,890 +atoms فيهم عدد ال carbon atoms عدد إيش زوجة الان + +100 +00:08:29,890 --> 00:08:34,010 +ال unsaturated acids أول ما أبدأ أقول double bond + +101 +00:08:34,010 --> 00:08:39,410 +كلمة ال double bond ارتبطت الذهن بcis و trans او z + +102 +00:08:39,410 --> 00:08:46,090 +و e اه unsaturated acids usually have the cis or z + +103 +00:08:46,090 --> 00:08:50,720 +configurationالـ Unsaturated بيكون ال + +104 +00:08:50,720 --> 00:08:56,020 +configuration فيهم إيش زد يعني ال .. ال أتشز بيجوا + +105 +00:08:56,020 --> 00:09:01,420 +على جهة و ال carbons على جهة التانية الآن they + +106 +00:09:01,420 --> 00:09:03,720 +have lower boiling points than the corresponding + +107 +00:09:03,720 --> 00:09:08,260 +saturated ones شوفنا من خلال القيم أن ال + +108 +00:09:08,260 --> 00:09:13,860 +unsaturated نقاط الانسهار بتاعتهم أقل من إيش أقل + +109 +00:09:13,860 --> 00:09:17,060 +من ال saturated ممتاز + +110 +00:09:20,030 --> 00:09:24,490 +الان بنجي للسؤال الأول ليش هدولة solids والتانين + +111 +00:09:24,490 --> 00:09:31,420 +liquids اتطلعوا معايا لو اتخيلت انا هذا شكللـ + +112 +00:09:31,420 --> 00:09:35,200 +triglycerides يعني هذا الجزء الجليسرين و هذا الاشي + +113 +00:09:35,200 --> 00:09:39,720 +الزهري هو ال oxygen و بعد هيك في عندي تلت سلاسل + +114 +00:09:39,720 --> 00:09:45,560 +طويلة سلسلة تنتين تلاتة الان هذه السلاسل لما تكون + +115 +00:09:45,560 --> 00:09:50,340 +مشبعة لما تكون مشبعة بشكل عام بنتخيلها بهذا الشكل + +116 +00:09:50,340 --> 00:09:55,820 +المستقيم الان لاحظوا كيف شكل المركب هو شكل منتظم + +117 +00:09:56,070 --> 00:10:01,290 +قالم المركب الشكل تبعه منتظم معناه ذلك ان الجزيئات + +118 +00:10:01,290 --> 00:10:05,930 +بتيجي فوق بعضها بشكل جيد تترتب فوق بعضها في الحالة + +119 +00:10:05,930 --> 00:10:10,450 +الصلبة وهذا اللي بيخليها تكون ايه اش solids الان + +120 +00:10:10,450 --> 00:10:16,410 +لو فقط واحدة من هدولة صار فيها double bond يعني لو + +121 +00:10:16,410 --> 00:10:20,790 +كان عندى ال triglycerides مديش اقول التلاتة فيهم + +122 +00:10:20,790 --> 00:10:23,670 +double bonds خليني اقول هذه saturated و هذه + +123 +00:10:23,670 --> 00:10:28,530 +saturated واحدة بسقولت يكون فيها double bond و ال + +124 +00:10:28,530 --> 00:10:31,550 +double bond اللي بده تكون فيها إيش بده تكون sis + +125 +00:10:31,550 --> 00:10:35,990 +هتصير بهذا الشكل اتطلع من عندها هاي ال sis اللي + +126 +00:10:35,990 --> 00:10:40,750 +موجود فيها هاي ال double bond و هذا الجزء هاي أنا + +127 +00:10:40,750 --> 00:10:45,690 +carbon و أنا carbon على نفس الجهة هذا الشكل عمل + +128 +00:10:45,690 --> 00:10:53,030 +إيش فيها انتناقةواضح؟ الآن هذا الانفناق حافظ على + +129 +00:10:53,030 --> 00:10:58,750 +الشكل المنتظم للجزيء ولا بطل الجزيء منتظم؟ بطل + +130 +00:10:58,750 --> 00:11:02,830 +الجزيء منتظم ولذلك لما تيجي الجزيقات بتنحط فوق بعض + +131 +00:11:02,830 --> 00:11:07,130 +في solid lattice في الشبكة عشان تكون المركب الصلب + +132 +00:11:07,130 --> 00:11:11,450 +مابتبعدش فوق بعض جيدا، مابتكونش متراسة فوق بعض + +133 +00:11:11,450 --> 00:11:16,630 +البعض فالمادة بتحول إلى إيش؟ إلى liquid أو بتنخفض + +134 +00:11:16,630 --> 00:11:23,240 +نقاط انصحارهاولذلك هنا احنا انا شفنا ال space + +135 +00:11:23,240 --> 00:11:26,860 +filling and schematic model of glycerol التسمية + +136 +00:11:26,860 --> 00:11:30,380 +بناخدها tri-palmitate هذا من ال palmitic acid يعني + +137 +00:11:30,380 --> 00:11:35,380 +كام كربون؟ 16 اللي متذكرين هذا المشبع ايش ماله؟ + +138 +00:11:35,380 --> 00:11:41,520 +كان regular كان منتظم بينما لاحظوا معي هنا هذا + +139 +00:11:41,520 --> 00:11:46,680 +اللي فيه بس واحدغير مشبع، في double bond، راح + +140 +00:11:46,680 --> 00:11:50,220 +الانتظام، الآن اتخيلوا انه لو اكثر من واحد في + +141 +00:11:50,220 --> 00:11:53,480 +double bonds، اتخيل لو هذا فيه اكثر من double + +142 +00:11:53,480 --> 00:11:58,200 +bond، وكل double bond فيهم صار أشبه بإيش؟ + +143 +00:12:00,430 --> 00:12:05,610 +لأ صار أشبه حقيقة .. صار أشبه حقيقة بالفكرة اللي + +144 +00:12:05,610 --> 00:12:11,730 +أخدناها لما درسنا ال ال can's ال chain ال can's و + +145 +00:12:11,730 --> 00:12:15,610 +ال branch ال can's و قولنا أن ال chain they have + +146 +00:12:15,610 --> 00:12:20,810 +higherboiling point و melting point than ال branch + +147 +00:12:20,810 --> 00:12:25,610 +ليش؟ لأن ال branch أصبح شكلهم زي إيش؟ زي الكرة + +148 +00:12:25,610 --> 00:12:30,510 +بطلوا منتظمين فوق بعضهم البعض، واضح؟ لما أخدنا + +149 +00:12:30,510 --> 00:12:33,510 +قولنا مين، إله ال boiling point أعلى، ال chain ولا + +150 +00:12:33,510 --> 00:12:39,770 +ال branch؟لأن ال branch بطل شكله منتظم الفكرة + +151 +00:12:39,770 --> 00:12:43,890 +بالانتظام، الآن هذا اللي في double bonds نفس + +152 +00:12:43,890 --> 00:12:48,250 +الفكرة زي ال branch، يعني لاحظوا أنه لو كان هنا في + +153 +00:12:48,250 --> 00:12:52,990 +branch مش هتعمل هيك وتقضي على الانتظام اللي كان + +154 +00:12:52,990 --> 00:12:59,180 +موجود، الآن هذا الكلام اللي عملته double bondفال + +155 +00:12:59,180 --> 00:13:03,560 +branching بيقضي على الانتظام ووجود ال cyst double + +156 +00:13:03,560 --> 00:13:07,240 +bond بهذا الشكل ايضا قضى على الانتظام فالفكرة + +157 +00:13:07,240 --> 00:13:12,780 +العامة في الحالتين لما نقول ان ال kids بشكل عام + +158 +00:13:12,780 --> 00:13:16,060 +انه ال branch they have lower boiling points and + +159 +00:13:16,060 --> 00:13:20,150 +melting points because they are irregularالان هنا + +160 +00:13:20,150 --> 00:13:24,550 +الـ triglycerides that contain unsaturated fatty + +161 +00:13:24,550 --> 00:13:27,470 +acids they have lower boiling point and melting + +162 +00:13:27,470 --> 00:13:31,990 +point because they are irregular من وين اجت ال + +163 +00:13:31,990 --> 00:13:36,330 +irregularity اللي فيهم، عدم الانتظام من وجود ال + +164 +00:13:36,330 --> 00:13:39,370 +double bond و ال cis configuration اللي موجود + +165 +00:13:39,370 --> 00:13:44,450 +فيها، واضح؟ الان هذا الكلام بيفرق عندي وين؟ بيفرق + +166 +00:13:44,450 --> 00:13:49,870 +عندي وين؟ال oil however are liquid بيصير في عندى + +167 +00:13:49,870 --> 00:13:56,350 +اشي اسمه بالمطبخ خلينا نقول شغلتين بيصير في عندكم + +168 +00:13:56,350 --> 00:14:01,010 +زيت، زيت الجلي، زيت عباد الشمس، زيت الصوية اللي + +169 +00:14:01,010 --> 00:14:06,290 +بتسموه searage، هذا liquid و بيصير في عندكم صلب، + +170 +00:14:06,290 --> 00:14:11,260 +السمنة والزبدةملاحظين انتوا هدولة ماشي بيفرجوا + +171 +00:14:11,260 --> 00:14:17,240 +ببعض، السمنة والزبدة saturated، + +172 +00:14:17,240 --> 00:14:21,650 +الزيت اللي فيه ال double bondsالزيت اللي فيه ال + +173 +00:14:21,650 --> 00:14:25,130 +double bonds عشان هيك صار liquid, oils however are + +174 +00:14:25,130 --> 00:14:32,190 +liquids because they contain lower percentage of + +175 +00:14:32,190 --> 00:14:35,230 +unsaturated .. higher percentage عفوا .. higher + +176 +00:14:35,230 --> 00:14:38,490 +percentage of unsaturated fatty acids إذا لو + +177 +00:14:38,490 --> 00:14:43,310 +بيناقول مين اللي فيه ال double bonds؟ ال oil ولا + +178 +00:14:43,310 --> 00:14:48,010 +ال fat؟ السمنة والزبدة بيناقول عنهم fatsالزيت + +179 +00:14:48,010 --> 00:14:51,170 +والسيرش .. زيت الزتون والسيرش .. بنقول عنهم إيش؟ + +180 +00:14:51,170 --> 00:14:54,830 +Oil .. ال oil هو اللي فيه ال double bonds .. و ال + +181 +00:14:54,830 --> 00:14:59,150 +double bonds هي اللي خفضت إيش نقطة انسهاره .. الآن + +182 +00:14:59,150 --> 00:15:03,050 +لاحظوا معاك ان انتوا اتعلمتوا كيميا .. ان انتوا + +183 +00:15:03,050 --> 00:15:08,300 +اتعلمتوا كيميااتعلمتوا ان ال double bond ممكن + +184 +00:15:08,300 --> 00:15:14,140 +نعملها ايش؟ hydrogenation نعملها single bond الان + +185 +00:15:14,140 --> 00:15:21,060 +لو اعملت لهذا المركب hydrogenation هذا زيت اعملت + +186 +00:15:21,060 --> 00:15:25,300 +هدرجة اللي هو شو بيصير؟ بيصير solid بيصير سمنة + +187 +00:15:25,300 --> 00:15:30,830 +فالسمنة تنتج من هدرجة الزيوتبس حطوا هنا هيدروجين و + +188 +00:15:30,830 --> 00:15:37,190 +هيدروجين، هذا صار saturated فحولت ال oil إلى fat، + +189 +00:15:37,190 --> 00:15:42,750 +سر السمنة والزبدة واضح اذا وين؟ بتيجي بالظبط فكرة + +190 +00:15:42,750 --> 00:15:49,070 +الهدرجة، الهدرجة بتحول السائل إلى صلب، في ناس + +191 +00:15:49,070 --> 00:15:52,030 +بيحبوا الشغلات الصلبة، يتعاملوا معها، + +192 +00:15:52,030 --> 00:15:57,540 +hydrogenationواضح؟ اتعلمنا ان ال hydrogenation على + +193 +00:15:57,540 --> 00:16:01,060 +ال double bond بيحول ال double bond إلى single + +194 +00:16:01,060 --> 00:16:05,620 +bond هاي ال unsaturated صار saturated معناه ذلك ال + +195 +00:16:05,620 --> 00:16:11,520 +liquid صار solid لأنه غير المنتظم بسبب ال double + +196 +00:16:11,520 --> 00:16:15,840 +bond سيصبح منتظم بعد أن تذهب ال double bond واضحة + +197 +00:16:15,840 --> 00:16:16,480 +الفكرة؟ + +198 +00:16:18,930 --> 00:16:23,230 +ما بنعملش عملية عكسية العملية اللى موجودة ال هدرجة + +199 +00:16:23,230 --> 00:16:29,310 +مش العكسي السمنة لما بتكويها تصير سائل فاطوها على + +200 +00:16:29,310 --> 00:16:34,810 +النار سايحوها على النار هذا تسخين اسمه بس أنا بحكي + +201 +00:16:34,810 --> 00:16:41,230 +على هدرجة واضح؟ الآن هنا بتجيني مشكلة جديدة هنا + +202 +00:16:41,230 --> 00:16:46,630 +بتجيني مشكلة جديدة وانتبهوا لها جيدا انتبهوا لها + +203 +00:16:46,630 --> 00:16:52,820 +جيدا لأنها مشكلة خطيرةالان زي ما اتفقنا احنا ان + +204 +00:16:52,820 --> 00:16:57,480 +الزيوت بشكل عام فيها double bonds وال double bonds + +205 +00:16:57,480 --> 00:17:04,580 +ايش ال configuration فيها سيس الان لو يا ترىنتيجة + +206 +00:17:04,580 --> 00:17:09,440 +عمل كيميائي أو عمل إنساني أو تسخين زائد السس اتحول + +207 +00:17:09,440 --> 00:17:13,460 +ل Trans بالحرارة احنا قلنا بالوضع الطبيعي بتتحولش + +208 +00:17:13,460 --> 00:17:17,820 +يعني حرارة الغرفة بدون تفاعلات كيميائية بدون تسخين + +209 +00:17:17,820 --> 00:17:24,460 +السس Trans are not interconvertable easyب .. ب .. + +210 +00:17:24,460 --> 00:17:28,340 +ب .. ليش؟ لأن الدوران حوالين ال double bond صعب مش + +211 +00:17:28,340 --> 00:17:34,080 +سهل لكن بالتسخين أو بعوامل كيميائية ممكن تتم + +212 +00:17:34,080 --> 00:17:38,560 +العملية؟ ممكن، بالذات بالتسخين طب وين احنا بنسخن + +213 +00:17:38,560 --> 00:17:43,820 +اكتر اشيء؟ لما نجلي بال series الآن جاليا مرة + +214 +00:17:43,820 --> 00:17:49,210 +واحدةزي ما بتجلو بيضة مش مشكلة تحطوا زيت زاتون و + +215 +00:17:49,210 --> 00:17:53,670 +البيضة دقيقة وقال ماشي لكن الناس اللي بيجلو + +216 +00:17:53,670 --> 00:18:00,510 +بالسيرج عشر مرات البطاطا و الفلافل معناه ذلك ان + +217 +00:18:00,510 --> 00:18:05,090 +معها التسخين نسبة كبيرة جدا من ال ces ممكن تصير + +218 +00:18:05,090 --> 00:18:09,750 +ايش؟ Trans الان ال Trans compounds are + +219 +00:18:09,750 --> 00:18:15,660 +carcinogenic ال Trans مصارطنينهم لاحظين و لذلك + +220 +00:18:15,660 --> 00:18:22,820 +يحذر من القلي المتكرر في الزيوت يعني مش شطارة انه + +221 +00:18:22,820 --> 00:18:27,840 +رابط البيت والله بتجلي مرة مارتين تلاتة عشرة او + +222 +00:18:27,840 --> 00:18:32,700 +الناس اللي بيشتغلوا في الشوارع او المطاعم بيجلوا + +223 +00:18:32,700 --> 00:18:36,240 +عشر مرات ما هو كل ما احنا جاعدين بنسخن على السيرج + +224 +00:18:36,240 --> 00:18:40,520 +و كل ما بنجلي فيه بزيادة كل ما بنحول double bones + +225 +00:18:40,520 --> 00:18:46,130 +اكترنتيجة الحرارة من cis إلى trans كل ما بيصير + +226 +00:18:46,130 --> 00:18:50,350 +الإنسان طبعا هياخد مع الأشياء المجلية زيوت كمان و + +227 +00:18:50,350 --> 00:18:56,550 +هذه الأشياء fatty acids، انتبهوا معي، fatty acids + +228 +00:18:56,550 --> 00:19:03,430 +with trans bonds are carcinogenic، مسارتمينو لذلك + +229 +00:19:03,430 --> 00:19:08,350 +يعني اكثر من مرة و تانية ما اتجربوش تجلو انما انه + +230 +00:19:08,350 --> 00:19:13,910 +الزيت بينجل فيه ايام و ليالي كل هذا الكلام يعتبر + +231 +00:19:13,910 --> 00:19:18,430 +كلام إيش خاطر الآن لاحظوا معاك انه برضه عملية + +232 +00:19:18,430 --> 00:19:26,120 +الهدرجة برضه عملية الهدرجة عملية كيميائيةبنحول + +233 +00:19:26,120 --> 00:19:32,420 +فيها احنا نسبة كبيرة من ال double bonds إلى single + +234 +00:19:32,420 --> 00:19:36,140 +bonds يعني جاعدين احنا نحول double bond إلى single + +235 +00:19:36,140 --> 00:19:39,800 +bond هذه ال double bond اللي احنا بنحولها sis ولا + +236 +00:19:39,800 --> 00:19:44,680 +trans؟ sisالان هذه ال هدرجة لما بنحكي عن زيت مش زي + +237 +00:19:44,680 --> 00:19:49,440 +مركب كيميائي يعني مش عملية سهلة عادة ما بتتمش على + +238 +00:19:49,440 --> 00:19:53,840 +كل ال double bonds لكن بتعمل نسبة كبيرة منهم واضحة + +239 +00:19:53,840 --> 00:19:59,820 +الفكرة؟ الان في هذه الأثناء بعض ال six double + +240 +00:19:59,820 --> 00:20:03,000 +bonds بيظلهم six يعني ما بيصلهمش الدور انهم ايش + +241 +00:20:03,000 --> 00:20:08,240 +انه يصيرلهم هدرجة وبعض ال six منهم بتتحولوا إلى + +242 +00:20:08,240 --> 00:20:16,060 +transوبالتالي بتصير الهدرجة أيضا عاملة مشكلة مش من + +243 +00:20:16,060 --> 00:20:20,040 +منطقة ان هي حولت ال double bond إلى single bond + +244 +00:20:20,040 --> 00:20:25,580 +يعني لو ان هي بشكل نظيف ودقيق ومتقن حولت ال double + +245 +00:20:25,580 --> 00:20:29,320 +bonds إلى single bonds يعني حولت الزيت إلى سمنة + +246 +00:20:29,320 --> 00:20:35,410 +مافيش مشكلةلكن المشكلة ان هذه الهدرجة غالبا بتكون + +247 +00:20:35,410 --> 00:20:40,410 +غير كاملة لحد معين بيضل شوية SIS BONS ونتيجة + +248 +00:20:40,410 --> 00:20:45,750 +التفاعل الكيميائي بعض ال SISBONS بيصيروا Trans + +249 +00:20:45,750 --> 00:20:54,780 +واضح؟ ولذلك اليومصار يعني في دول معينة يجبروا + +250 +00:20:54,780 --> 00:20:59,920 +الشركات المصنعة انه تعمل فحوصات و انه على نفس + +251 +00:20:59,920 --> 00:21:05,920 +الزبدة و على نفس السمنة تكتب جداش نسبة لترانس فيها + +252 +00:21:06,870 --> 00:21:10,710 +والمواطن لازم يعرف اقل تقدير انتوا الان كمتعلمين + +253 +00:21:10,710 --> 00:21:16,130 +انه كل ما نسبة لل Trans بتزيد كل ما المركب بيكون + +254 +00:21:16,130 --> 00:21:22,750 +ايش اخطر كل ما المركب بيكون carcinogenic واضح؟ + +255 +00:21:22,750 --> 00:21:30,570 +الان بنيجي لكيف يا ترى بنسمي ال triglycerides + +256 +00:21:30,570 --> 00:21:37,170 +خلينا ننتبه لشغلةإنهم لـ triglycerides عبارة عن + +257 +00:21:37,170 --> 00:21:44,870 +glycerol صح؟ حامل كام fatty acid؟ تلاتة، الآن لـ + +258 +00:21:44,870 --> 00:21:49,570 +triglycerides نوعين، + +259 +00:21:49,570 --> 00:21:53,790 +ع طول، أي واحدة بتقدر تقولي شو النوعين، انتظر، + +260 +00:21:53,790 --> 00:21:59,250 +ممكن يكونوا متماثلين، يعني فيهم نفس ال fatty acid + +261 +00:22:00,450 --> 00:22:04,870 +واضح؟ يعني اربعتاش اربعتاش اربعتاش مشبه او ستاش + +262 +00:22:04,870 --> 00:22:10,890 +ستاش ستاش مشبه وممكن يكونوا غير متماثلين صارت + +263 +00:22:10,890 --> 00:22:13,830 +الأفكار شبيهة بأشياء أخدتها زي لما أخدنا ال ether + +264 +00:22:13,830 --> 00:22:18,250 +متماثل وغير متماثل زي ما أخدنا ال anhydride متماثل + +265 +00:22:18,250 --> 00:22:22,650 +وغير متماثل كمان ال triglycerides ممكن يكونوا + +266 +00:22:23,260 --> 00:22:28,120 +Simple يعني متماثلين أو Mixed Mixed يعني مخلطين + +267 +00:22:28,120 --> 00:22:32,680 +يعني يكون هذا 16 هذا 18 هذا 18 فيه double bond + +268 +00:22:32,680 --> 00:22:40,160 +واضح؟ الآن أكيد لما بدنا نسمي لو كانوا متماثلين + +269 +00:22:40,160 --> 00:22:46,220 +هنذكر اسم الفاتئاسد لمرة واحدة و لو كانوا غير + +270 +00:22:46,220 --> 00:22:51,530 +متماثلين بدنا نذكر إيش؟الثلاث أسماء اللي موجودة مش + +271 +00:22:51,530 --> 00:22:55,890 +هذه لازم تكون الفكرة العامة الآن بشكل عام ك common + +272 +00:22:55,890 --> 00:23:01,070 +name وخلينا نبدأ بال common name للمتماثلين لو كان + +273 +00:23:01,070 --> 00:23:07,970 +ال fatty acid ال 12 اللي هو اللوريك أسد تمام بنسمي + +274 +00:23:07,970 --> 00:23:10,630 +المركب Trilaurin + +275 +00:23:13,300 --> 00:23:19,580 +واضح؟ إذا من ال acid lauryl بحط إيش؟ lauryl tri + +276 +00:23:19,580 --> 00:23:27,660 +-lauryl طيب لو كان stearic tri-stearic يعني لاحظوا + +277 +00:23:27,660 --> 00:23:35,300 +معي كان ال acid الأصلي lauryl لما عملت منه ال tri + +278 +00:23:35,300 --> 00:23:41,860 +-glyceride ضفت كلمة trialهذه إجت جديدة اللورك + +279 +00:23:41,860 --> 00:23:50,100 +خلّيت منها لور و حطيت لها إيش؟ حطيت لها in بدل اك + +280 +00:23:50,100 --> 00:23:58,260 +in ال try لورن طيب من ال steerك المتماثل try + +281 +00:23:58,260 --> 00:24:06,150 +steering من الأوليك المتماثل try أولينواضح؟ + +282 +00:24:06,150 --> 00:24:10,870 +ترايقليا ولاحظوا على طول طبعا هيبين معاكم كيف + +283 +00:24:10,870 --> 00:24:14,890 +لتراي لاورين مثلا ال melting point له لأن كل ال + +284 +00:24:14,890 --> 00:24:20,510 +fatty acids تبعته مشبعة خمسة واربعين هذا + +285 +00:24:20,510 --> 00:24:27,490 +لترايستيرين واحد وسبعين الان لو سألت واحدة منكم لو + +286 +00:24:27,490 --> 00:24:31,650 +سألت واحدة منكم ليش لتراي لاورين خمسة واربعين و + +287 +00:24:31,650 --> 00:24:37,120 +لترايستيرين واحد وسبعينالسلسلة أطول، الموليكولا + +288 +00:24:37,120 --> 00:24:41,400 +رويت، الكلمتين صح، التنين مشبع، مشبع، بطل، التشبع + +289 +00:24:41,400 --> 00:24:47,300 +هو الفارق، فقط طول السلسلة، أه، لكن لما هنا أجيت + +290 +00:24:47,300 --> 00:24:53,430 +18 و 18و حطيت تلاتة double bonds يعني خصام ست + +291 +00:24:53,430 --> 00:24:56,410 +هيدروجينات مش المشكلة بفرق ال molecular weight + +292 +00:24:56,410 --> 00:25:00,290 +يعني ست وحدات في جزاء كبير زي هذا في ال molecular + +293 +00:25:00,290 --> 00:25:04,550 +weight ماسهمهم مش فرق لكن المشكلة حقيقة لما أنا + +294 +00:25:04,550 --> 00:25:11,450 +بنزل هذا 18 و هذا 18 قليل ال 18 في one double bond + +295 +00:25:11,450 --> 00:25:16,970 +لما بنزل من 71 ل 4 هذا مش فاتقش التغير في ال + +296 +00:25:16,970 --> 00:25:21,280 +molecular weightهذا نتيجة وجود ال double bonds، + +297 +00:25:21,280 --> 00:25:24,300 +ليش؟ لأن وجدت لو بدي أجي هنا، بدي أعمل هذه ال + +298 +00:25:24,300 --> 00:25:26,840 +double bonds زي هيك و زي هيك، بعدين هذه زي هيك و + +299 +00:25:26,840 --> 00:25:34,010 +زي هيك، بعدين هذه، صار إيش؟ زي الكرةالجزيق وجده + +300 +00:25:34,010 --> 00:25:39,090 +بده يصير زي كرة كيف بده يكون منتظم في solid state + +301 +00:25:39,090 --> 00:25:44,550 +واضح الفكرة فلما بده أقول ليش ال triolين لو بده + +302 +00:25:44,550 --> 00:25:49,710 +أجي أسألكم ال triolين have lower melting point + +303 +00:25:49,710 --> 00:25:54,770 +than tristerine because of the presence of the + +304 +00:25:54,770 --> 00:26:00,230 +double bonds or because it is unsaturated واضح + +305 +00:26:00,230 --> 00:26:05,250 +الفكرةو هذا وجود ال double bond أو ال unsaturation + +306 +00:26:05,250 --> 00:26:09,790 +خلّاه regular ولا irregular؟ irregular بطل منتظم + +307 +00:26:09,790 --> 00:26:14,070 +بطل زي .. زي حجار الطوب المنتظمة كيف بتصفق بعض + +308 +00:26:14,070 --> 00:26:18,870 +بشكل قوى بينما حجار مش منتظمة بتضل إيش؟ توجع أو + +309 +00:26:18,870 --> 00:26:26,600 +ألعاب الأطفال اللي بيسموها ال Legoالان موضوع + +310 +00:26:26,600 --> 00:26:30,780 +الهيدروجينيشن of vegetable oils حكينا قولنا ان + +311 +00:26:30,780 --> 00:26:36,420 +احنا ممكن ناخد ال oil ويصير زبدة او سمنة + +312 +00:26:36,420 --> 00:26:40,120 +بالهيدروجينيشن تحويل ال double bond الى single + +313 +00:26:40,120 --> 00:26:42,780 +bond هذا الكلام برفع ال melting point بيحول ال + +314 +00:26:42,780 --> 00:26:47,380 +liquid الى solid الهيدروجينيشن عادة بتنفي وجود + +315 +00:26:47,380 --> 00:26:52,360 +الهيدروجين و نكلكتاليست و heat لكن هناك خطورة + +316 +00:26:52,360 --> 00:26:54,420 +مصاحبة للهيدروجينيشن + +317 +00:26:56,690 --> 00:27:02,110 +تحويل بعض ال sis bonds إلى trans يعني التحويل من + +318 +00:27:02,110 --> 00:27:05,630 +sis إلى saturated أو من double bond إلى saturated + +319 +00:27:05,630 --> 00:27:10,750 +هذا مافيش فيه مشكلة لكن كتفاعل جانبي بعض ال sis + +320 +00:27:10,750 --> 00:27:15,450 +بصير trans هنا توجد المشكلة + +321 +00:27:16,590 --> 00:27:21,350 +الان مرة تانية نرجع لل simple and mixed + +322 +00:27:21,350 --> 00:27:25,210 +triglycerides اللي هي المتماثلة و غير المتماثلة + +323 +00:27:25,210 --> 00:27:32,490 +اتفقنا احنا ان المتماثل بنعطي اسم common name + +324 +00:27:32,490 --> 00:27:38,470 +trystyrian يعني هذا 18 اذا ايش الحامض تبعه؟ Styric + +325 +00:27:38,470 --> 00:27:44,190 +Styric Styric فالمركب trystyrian طيب لو كنا بنسمي + +326 +00:27:44,190 --> 00:27:51,210 +ايوبكيعني Triglycerides is a common name و أنا + +327 +00:27:51,210 --> 00:27:55,470 +مرات بجيبلكوا سؤال في الامتحان .. بجيبلكوا سؤال في + +328 +00:27:55,470 --> 00:28:00,810 +الامتحان ال Triglycerides is also called .. or the + +329 +00:28:00,810 --> 00:28:06,830 +Ayurvedic name of Triglycerides is .. الآن عشان + +330 +00:28:06,830 --> 00:28:11,650 +نجاوبه صح احنا قولنا ال Triglycerides they are + +331 +00:28:11,650 --> 00:28:18,550 +Easter'sEaster صح ولا لأ؟ كيف أنا كنت أسمي ال + +332 +00:28:18,550 --> 00:28:22,970 +Easter؟ خليني أتذكر كيف أنا كنت أسمي ال Easter، + +333 +00:28:22,970 --> 00:28:29,370 +هيني بدي أكتب Easter عشان واحدة تذكرني كيف، + +334 +00:28:29,370 --> 00:28:32,690 +هاي Easter، شايفينه اللي على اللوح؟ واحدة تسميه + +335 +00:28:32,690 --> 00:28:37,370 +جزء الكحول في الأول + +336 +00:28:40,150 --> 00:28:49,150 +مثل هاي جزء الكحول وبعدين جزء الحامض انتوا بتكونوا + +337 +00:28:49,150 --> 00:28:52,910 +شايفوني ومن جلة دراستكوا بنزويك أسد ال Easter + +338 +00:28:52,910 --> 00:28:58,130 +بنتهي بنزويت مثل بنزويت أسيتات بيوتانويت اه هذا + +339 +00:28:58,130 --> 00:29:04,970 +مثل ايش؟ بنزويت اذا تسمية ال Easterلعبوا لو أنكوا + +340 +00:29:04,970 --> 00:29:09,030 +بتحاولوا تحفظوا الكيميا كرموز بتتغلبوا لو أنكوا + +341 +00:29:09,030 --> 00:29:13,310 +حفظتوا الكيميا أنه تسمية ال Easter مجموعة الكحول + +342 +00:29:13,310 --> 00:29:18,690 +في الأول بعدين ال acid منتهي ب إيه؟ إثل أستيت مثل + +343 +00:29:18,690 --> 00:29:24,730 +بنزويت فين ال بيوتانويت صح ولا لأ؟ طيب الآن كويس + +344 +00:29:24,730 --> 00:29:31,770 +لو إجيت على هذا شو هو جزء الكحول فيه؟ ال glycerin + +345 +00:29:32,770 --> 00:29:38,250 +وشو الأحمض؟ الاستيرك أسد مش هذا الحامض و هذا + +346 +00:29:38,250 --> 00:29:44,590 +الكحول ولا لأ ايش اول اشي بنذكره؟ جزء الكحول + +347 +00:29:44,590 --> 00:29:53,350 +إجليسارين إجليساريل و الاستيرك أسدStraight لكن لأن + +348 +00:29:53,350 --> 00:29:58,330 +في عندي منه تلاتة بقول glycerol ال try straight + +349 +00:29:58,330 --> 00:30:03,290 +إذا أنا نفس المنطقة ده اسمها ال Easter الكحول في + +350 +00:30:03,290 --> 00:30:09,070 +الأول و بعدين النهاية eight و حطيت try لأن عندي كم + +351 +00:30:09,070 --> 00:30:16,160 +حامض تلاتةإذا هذا هي جزء الكحول اللي فيه في واحدة + +352 +00:30:16,160 --> 00:30:19,140 +منكم مالخومة كتير عشان الكحول مرسوم على اليمين مش + +353 +00:30:19,140 --> 00:30:22,660 +على الشمال المهم نذكر الكحول في الأول كيف نرسمه مش + +354 +00:30:22,660 --> 00:30:28,360 +مشكلة واضحة الفكرة ولا لأ؟ واضحات؟ يعني هذا لو كنت + +355 +00:30:28,360 --> 00:30:35,540 +راسمه بالعكس إيش برضه هسميه؟ واضح؟ شايف هي كناس + +356 +00:30:35,540 --> 00:30:40,360 +مرات بهمش بيغرجوا بشبهر ميه؟ + +357 +00:30:43,590 --> 00:30:46,990 +يعني اتعودتوا انتوا انه هذا نعمله زي هيك او يبدو + +358 +00:30:46,990 --> 00:30:53,130 +معكوس لان لما يرسم زي هيك وين جزء الكحول مثل وين + +359 +00:30:53,130 --> 00:30:57,250 +جزء الاسد مثل بنزويت مثل بنزويت خلاص يعني الفكرة + +360 +00:30:57,250 --> 00:31:01,950 +مش انه بدهم يبينوا هدولة معكوسين دائما لأ لأ مش + +361 +00:31:01,950 --> 00:31:06,890 +هذه الفكرة حسب طريقة الرسم يذكر جزء الكحول اولا ثم + +362 +00:31:06,890 --> 00:31:10,770 +جزء الحامض منتهي بالنهاية ايه ولذلك هذا هيك ايش + +363 +00:31:10,770 --> 00:31:14,780 +بدنا نسميهمثل؟ بنزوية + +364 +00:31:18,100 --> 00:31:22,640 +أكيد اكيد طبعا اه ليش مايجيكيش ارسمي نفسي كل هذان + +365 +00:31:22,640 --> 00:31:27,800 +الكربونات بترسم ترسم شو وراكم انتوا دافعين رسوم + +366 +00:31:27,800 --> 00:31:32,760 +بتكونوا بتتعلموا واضح تسمية ال easter تسمية ال + +367 +00:31:32,760 --> 00:31:37,840 +easter ببساطة انه تذكروا جزء الكحول بعدين جزء + +368 +00:31:37,840 --> 00:31:42,400 +الحامض المساهي بالنهاية ايش ات فهذا صار glycerol + +369 +00:31:42,400 --> 00:31:50,100 +tryStirate هذه فهمناها طيب لو كانوا الأحماض الآن + +370 +00:31:50,100 --> 00:31:56,200 +مختلفين يعني صار عنده اللي أنا بسميه إيش mixed + +371 +00:31:56,200 --> 00:32:02,760 +triglyceride مرة تانية هحط في الأول جزء الكحول إذا + +372 +00:32:02,760 --> 00:32:09,450 +هنا هذا الجزء الكحول هي الجزء اللي جاي من الكحولمش + +373 +00:32:09,450 --> 00:32:16,310 +بختلف عليه، الآن الأحماض بدي أذكرهم مرتبين، واحد، + +374 +00:32:16,310 --> 00:32:20,950 +اتنين، تلاتة، طبعا هتقولولي إذا عرفنا واحد، بعده + +375 +00:32:20,950 --> 00:32:24,270 +بنقول اتنين، تلاتة، يمكن تصير المشكلة عندكم أن هذا + +376 +00:32:24,270 --> 00:32:28,730 +واحد، بعدين اتنين، تلاتة، ولا هذا واحد، بعدين + +377 +00:32:28,730 --> 00:32:33,800 +اتنين، تلاتةواضح؟ يعني المشكلة أن أذكر واحد، بعد + +378 +00:32:33,800 --> 00:32:38,020 +ما أذكر واحد لازم أمشي فيهم إيش، امرتبين، الآن + +379 +00:32:38,020 --> 00:32:44,760 +ببساطة بنقول الأصغر والأكثر تشبعا هو اللي بنحطه + +380 +00:32:44,760 --> 00:32:49,940 +نمرة واحد يعني لما أنا بدأ أختار وين نمرة واحد، + +381 +00:32:49,940 --> 00:32:54,960 +بدأ أختار الأصغر منهم والأكثر تشبعايعني لو لجيت + +382 +00:32:54,960 --> 00:32:58,980 +هنا ستة عشر وهنا تمانت عشر مشبعين التنين مين بدي + +383 +00:32:58,980 --> 00:33:05,540 +أحطهم؟ ستة عشر الان لو لجيت هنا ستة عشر وهنا تمانت + +384 +00:33:05,540 --> 00:33:11,280 +عشر وكمان هذا مشبع الستة عشر الآن بعد ما أحط الستة + +385 +00:33:11,280 --> 00:33:16,280 +عشر مامشي فيهم بالترتيب واضح؟ ولذلك هدولة لو انا + +386 +00:33:16,280 --> 00:33:22,470 +اجيت اطلعت الستة عشر بال methic acidالـ 18 المشبع + +387 +00:33:22,470 --> 00:33:27,790 +استيرك الـ 18 اللي فيه double bond أوليك لما أنا + +388 +00:33:27,790 --> 00:33:32,150 +بدي أسميهم بقول glycerin بعدين بجعل بالميتو + +389 +00:33:32,150 --> 00:33:38,510 +بالميتو بعدين الاستيرك استيره بعدين على الأوليك + +390 +00:33:38,510 --> 00:33:45,490 +أولييت بحط ات في النهاية لاحظوا معي أن الأوليك أن + +391 +00:33:45,490 --> 00:33:46,390 +الأوليك + +392 +00:33:50,390 --> 00:33:58,870 +الـ O تبعته عليها إيش؟ نجوطين طبعا على الكمبيوتر + +393 +00:33:58,870 --> 00:34:03,230 +ممكن تلاقوا الـ O اللي عليها نجوطين و ممكن أنه + +394 +00:34:03,230 --> 00:34:06,430 +ماتلاقوهاش، الآن لو مالاجيتوهاش الـ O اللي عليها + +395 +00:34:06,430 --> 00:34:08,870 +نجوطين اكتبوها إيش؟ + +396 +00:34:10,720 --> 00:34:17,820 +والفظوها OE فهي O ممالة إلى الكسر يعني بمنطق + +397 +00:34:17,820 --> 00:34:24,480 +التجويد هي O ممالة للكسر و ال A اللي عليها نقطين A + +398 +00:34:24,480 --> 00:34:30,400 +ممالة للكسر و ال U اللي عليها نقطين ممالة للكسر + +399 +00:34:30,400 --> 00:34:38,300 +كمان ولذلك لما الألمان بيقرؤوا هذه الكلمة أول أول + +400 +00:34:39,500 --> 00:34:44,840 +لحظوا الفك كيف بنزل لتحت إمالة للكسر مار عليكم + +401 +00:34:44,840 --> 00:34:49,320 +الإمالات ولا لأ؟ + +402 +00:34:49,320 --> 00:34:55,740 +ولا في عندنا ولا إمالة في القرآن الكريم برواية حفظ + +403 +00:34:55,740 --> 00:35:02,450 +عن عاصرهي إمالة واحدة لكن روحوا على روايات تانية + +404 +00:35:02,450 --> 00:35:08,870 +زي مثلا الكساء وغير وغيرات كله إمالات واضح؟ أه في + +405 +00:35:08,870 --> 00:35:14,550 +القرآن الكريم وقال اركبوا فيها بسم الله مجريها ما + +406 +00:35:14,550 --> 00:35:19,490 +تقولوش مجريها هادفرة كسر كامل هي ألف ممالة للكسر + +407 +00:35:19,490 --> 00:35:26,690 +بسم الله مجريها ومرساها طبعاعند غير حفظة عن عاصم + +408 +00:35:26,690 --> 00:35:32,110 +معظم بيقرأوا باسم الله مجراها بيرجعوها مجراها و + +409 +00:35:32,110 --> 00:35:36,530 +مرساها بيحطوهم زي ما .. فهذه قول هذه قوليك قوليك + +410 +00:35:36,530 --> 00:35:44,270 +الفك يكون ميل للكسر او تقرأوها ايش اوأو نقرأها OE + +411 +00:35:44,270 --> 00:35:50,130 +إذا سهلة تسمية بدي أحط glycerin وإذا كانوا زي بعض + +412 +00:35:50,130 --> 00:35:55,330 +بحط ال tri و الحمض eight وإذا كانوا مش زي بعض بدي + +413 +00:35:55,330 --> 00:35:58,770 +أذكر التلاتة هقول مين بدي أبدأ واحد و بعدين اتنين + +414 +00:35:58,770 --> 00:36:04,210 +تلاتة الواحد هو الأصغر و الأكتر تشبعانيعني لو + +415 +00:36:04,210 --> 00:36:07,990 +إجينا اتطلعنا على هذا المثال نتطلع فيه عندنا + +416 +00:36:07,990 --> 00:36:13,210 +هاناستيرك أسد وهانا بالميتك أسد وهانا أوليك أسد + +417 +00:36:13,210 --> 00:36:17,630 +الآن أنا بأتطلع على الأطراف أنا مقارنتني من أين + +418 +00:36:17,630 --> 00:36:21,350 +بدي أبدأ من هذا الطرف و لا من هذا الطرف واضحة + +419 +00:36:21,350 --> 00:36:28,690 +الفكرة؟ الآن اتطلعوا من هذا الطرف أوليك 18 غير + +420 +00:36:28,690 --> 00:36:34,880 +مشبعاستيرك تمانتعش مشبع تمانتعش و تمانتعش مشبع و + +421 +00:36:34,880 --> 00:36:41,320 +غير مشبع من وين بدي أبدأ تمانتعش مشبع تمانتعش مشبع + +422 +00:36:41,320 --> 00:36:49,500 +و لذلك هذا المركب لما أنا بدي أسميه إجليساريل + +423 +00:36:49,500 --> 00:36:53,720 +بعدين بسيب فراغ مشبولنا في ال Easter بنسيب فراغ زي + +424 +00:36:53,720 --> 00:36:59,640 +إتل فراغ أستيتل إجليساريل فراغ استيرو بالميتو + +425 +00:37:02,340 --> 00:37:10,300 +واضح؟ الار اتخيلوا لو اجاكم سؤال اجليساريل بالميتو + +426 +00:37:10,300 --> 00:37:15,340 +استيروا قليل واجليساريل استيروا بالميتو قليل يعني + +427 +00:37:15,340 --> 00:37:20,300 +عكس التانين فيهم حطيت فيهم التلاتة هذا بيبدأ + +428 +00:37:20,300 --> 00:37:24,440 +بالميتو بعدين استيره بعدين قليل هذا بيبدأ استيره + +429 +00:37:24,440 --> 00:37:30,300 +بعدين بالميتو قليل هدول اش بيكون العلاقة بينهم؟We + +430 +00:37:30,300 --> 00:37:37,280 +are surely isomers فش نقاش إنهم isomers الآن أي + +431 +00:37:37,280 --> 00:37:41,840 +نوع من ال isomers؟ + +432 +00:37:41,840 --> 00:37:47,960 +الآن اطلعوا معي هايهم، تلاتة، واحدة تشوفهم ك .. + +433 +00:37:47,960 --> 00:37:50,820 +برا الكيميا، برا الكيميا مش هاي ال glycerol وهيو + +434 +00:37:50,820 --> 00:37:55,860 +حاملهم التلاتة، حاملهم التلاتة أزرق، أحمر، يعني + +435 +00:37:55,860 --> 00:38:01,600 +يجربوا بيصيروا زي أعلام فلسطينأزرق، أحمر، أصمر، + +436 +00:38:01,600 --> 00:38:11,200 +أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، + +437 +00:38:11,200 --> 00:38:11,220 +أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، + +438 +00:38:11,220 --> 00:38:11,240 +أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، + +439 +00:38:11,240 --> 00:38:11,720 +أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، + +440 +00:38:11,720 --> 00:38:13,520 +أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، + +441 +00:38:13,520 --> 00:38:16,920 +أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، + +442 +00:38:16,920 --> 00:38:22,200 +أحمرمواقع الارتباط اتغيرت، هذا كان شابق في أول + +443 +00:38:22,200 --> 00:38:25,980 +كاربون الأزرق والأحمر في التانية، الأحمر صار في + +444 +00:38:25,980 --> 00:38:30,540 +الأولى والأزرق في التانية، different bonding، بزن + +445 +00:38:30,540 --> 00:38:35,820 +different bonding، اذا structural isomers، + +446 +00:38:35,820 --> 00:38:40,040 +different bonding تبعها كمان شغلة، different names + +447 +00:38:41,090 --> 00:38:44,950 +واضح؟ عشان ايك، لاحظوا واحد كان اسمه glycerol + +448 +00:38:44,950 --> 00:38:48,350 +بالميتو ستيرو أوليات، التاني glycerol ستيرو + +449 +00:38:48,350 --> 00:38:51,150 +بالميتو أوليات، الآن هذول أخدوا different names + +450 +00:38:51,150 --> 00:38:54,230 +ولا لأ؟ طالما different names، إذا they are + +451 +00:38:54,230 --> 00:38:59,470 +structural isomers، ال stereo isomers كانوا ياخدوا + +452 +00:38:59,470 --> 00:39:05,780 +نفس الاسميفرقوا بس في البادقة في الانانشو مارز R + +453 +00:39:05,780 --> 00:39:11,680 +ولا S ولا كذا وفي الدياستيريو مارز S أو Trans أو Z + +454 +00:39:11,680 --> 00:39:16,340 +أو E same name وكانوا ياخدوا different descriptive + +455 +00:39:16,340 --> 00:39:20,680 +البادقة اللي بتوصف الشكل الفراغي مش سميناها + +456 +00:39:20,680 --> 00:39:25,520 +descriptive البادقة ال R أو ال S أو ال Z أو ال E + +457 +00:39:25,520 --> 00:39:30,460 +أو ال S أو ال Trans لكن إلهم نفس الاش نفس الإسم + +458 +00:39:31,530 --> 00:39:35,470 +الان لاحظوا معاه لو قلنا لكم draw this structure + +459 +00:39:35,470 --> 00:39:41,210 +for glyceryl trimeristate اللي هو meristic acid ال + +460 +00:39:41,210 --> 00:39:48,210 +14 موجود عندكم بدكوا تحطوهربما من الأخطاء اللي + +461 +00:39:48,210 --> 00:39:50,450 +كتير الطلاب بيخطئوها + +462 +00:40:19,820 --> 00:40:23,880 +تطلعوا كيف الشكل الصحيح ال O هان هذا جزء الكحول + +463 +00:40:23,880 --> 00:40:29,400 +هذا جزء الحامض ال glycerin هو المتصل بال O العادية + +464 +00:40:29,400 --> 00:40:33,400 +single bond بعدين ال C double bond O مش العكس هذا + +465 +00:40:33,400 --> 00:40:36,340 +من الأخطاء الشائعة لما نقول للطلبة ارسمولنا + +466 +00:40:36,340 --> 00:40:41,640 +triglyceride بيروحوا بيرسموليا معكوس واضح؟ + +467 +00:40:44,360 --> 00:40:49,780 +على أي حال، بهيك تقريبا بننهي اليوم بكرا إجازة عيد + +468 +00:40:49,780 --> 00:40:54,740 +العمال، ماعرفش وقتاش بيكون عيد الطلاب، عيدنا يوم + +469 +00:40:54,740 --> 00:40:57,280 +نجاحنا + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..fb6d6837eba461ceaaca22b71b32343165a6d781 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_postprocess.srt @@ -0,0 +1,1884 @@ +1 +00:00:19,520 --> 00:00:23,540 +بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في + +2 +00:00:23,540 --> 00:00:28,820 +موضوع ال acidity و عرفنا بالظبط ايش معنى الأحمار و + +3 +00:00:28,820 --> 00:00:35,360 +وضحنا انه مهم جدا نعرف ايش معنى ال BKAال acidity + +4 +00:00:35,360 --> 00:00:39,820 +constant و قولنا كل ما ال PKA قلة كل ما الحامض + +5 +00:00:39,820 --> 00:00:45,000 +بيكون ايش اقوى بعد هي طرحنا سؤال و أعطينا عليه + +6 +00:00:45,000 --> 00:00:49,940 +إجابة عامة بدون ما ندخل بأنفلة تفصيلية كان السؤال + +7 +00:00:49,940 --> 00:00:54,540 +لما بدأ قارن حامض مع حامض تاني من الأقوى و من + +8 +00:00:54,540 --> 00:00:59,250 +الأقل بدأ اعتمد على ايشلما بقارن الأحماض في قوتها + +9 +00:00:59,250 --> 00:01:05,270 +بدي أنظر لل أيون السالب اللي بتكون نتيجة اللي هو + +10 +00:01:05,270 --> 00:01:10,430 +تحلل الحمض بالماء هذا ال أيون السالب بدي الشحنة + +11 +00:01:10,430 --> 00:01:14,110 +تبعته تكون أقل ما يمكن هذا اللي بنسميه إيش احنا ال + +12 +00:01:14,110 --> 00:01:18,470 +stability ل ال negative أيون معنى ال stability أن + +13 +00:01:18,470 --> 00:01:21,710 +الشحنة تكون أقل ما يمكن الآن إيش اللي بيقلل + +14 +00:01:21,710 --> 00:01:27,060 +الشحنة؟تلات تأثيرات ممكن الحجم اللي بيحمل الشحنة + +15 +00:01:27,060 --> 00:01:30,920 +وممكن شيء نسميه ال inductive effect اللي هو تأثير + +16 +00:01:30,920 --> 00:01:36,180 +المساعدة وممكن شيء نسميه ال resonance effect + +17 +00:01:36,180 --> 00:01:42,660 +أعطينا بعض الأمثلة لكن خلينا نأكد الآن مثلا لو + +18 +00:01:42,660 --> 00:01:48,420 +أجينا نقارن ال phenolsمع الالكوهولز العادية + +19 +00:01:48,420 --> 00:01:54,480 +الاليفاتك الالكوهولز بمعنى انا بدي اقارن ROH مع + +20 +00:01:54,480 --> 00:01:59,320 +فنل OH لاحظوا المقطة الأولى انه لما ايجي يعمل + +21 +00:01:59,320 --> 00:02:04,680 +المقارنة ويفهم المقارنة سابه هو من الحامض ايش كتب؟ + +22 +00:02:04,680 --> 00:02:10,760 +الايون السالد يعني كتب أنا R O minus وفنل O minus + +23 +00:02:10,760 --> 00:02:17,990 +فالحكم هوالـ Ion السالب الان هذا الـ RO- الشحن + +24 +00:02:17,990 --> 00:02:22,450 +اللي موجود عليه ثابت على ال oxygen مافيش فيها حركة + +25 +00:02:22,450 --> 00:02:25,970 +مافيش فيها resonance ال oxygen ذرة صغيرة يعني + +26 +00:02:25,970 --> 00:02:29,710 +بيقول it cannot carry the negative charge صعب + +27 +00:02:29,710 --> 00:02:33,250 +عليها تحمل ال negative charge ولذلك ال Ion كله + +28 +00:02:33,250 --> 00:02:37,050 +بيكون unstable فلاحظوا الكلام ان ال charge is + +29 +00:02:37,050 --> 00:02:43,570 +localized يعني محمولة على موقع واحد مش عملهاتتنجل + +30 +00:02:43,570 --> 00:02:48,730 +localized متموضعة محمولة في موضع واحد عكسها ايش؟ + +31 +00:02:48,730 --> 00:02:53,410 +delocalized فبصير عندي كلمتين localized اشي على + +32 +00:02:53,410 --> 00:02:57,550 +موضع واحد delocalized زي ما انا اجي احمل هذا هيك + +33 +00:02:57,550 --> 00:03:01,550 +بس عن ايد هذه و فقط لا غير هيك بيكون هذا الحمل + +34 +00:03:01,550 --> 00:03:07,590 +localized الآن لو كنت بنجلهبيكون De-localized واضح + +35 +00:03:07,590 --> 00:03:13,210 +فإذا بنلاحظ أنه بالفينول الشحنة السالبة في أحد ال + +36 +00:03:13,210 --> 00:03:16,350 +resonance structures على ال oxygen لكن لو عملنا + +37 +00:03:16,350 --> 00:03:20,450 +حركة إلكترونات زوج من الإلكترونات بهذا الشكل و + +38 +00:03:20,450 --> 00:03:23,710 +حركنا ال bond هنلاحظ أنها ممكن تصير على ال carbon + +39 +00:03:23,710 --> 00:03:26,510 +اللي موجودة هنا بحركة تانية على ال carbon اللي + +40 +00:03:26,510 --> 00:03:29,750 +موجودة هنا بحركة تالتة على ال carbon لاحظوا أنه + +41 +00:03:29,750 --> 00:03:34,460 +بطلت الشحنةمحمولة على مكان واحد بطلت localized + +42 +00:03:34,460 --> 00:03:39,000 +صارت delocalized هذا resonance واضح او + +43 +00:03:39,000 --> 00:03:42,400 +delocalization يعني بيستعملوا كلمة resonance او + +44 +00:03:42,400 --> 00:03:46,900 +delocalization بنفس المعنى واضح ف because of the + +45 +00:03:46,900 --> 00:03:52,360 +delocalization of the charge in phenoxide and ion + +46 +00:03:52,360 --> 00:03:56,540 +or anion لحظوا ال phenyl O minus شو بنسميه + +47 +00:03:58,860 --> 00:04:02,960 +فينوكسايد انا يعني يمكن سابقا حكينالكم هي اللي لو + +48 +00:04:02,960 --> 00:04:09,300 +كانت هذه مثل O minus مثوكسايد مثل O minus إثوكسايد + +49 +00:04:09,300 --> 00:04:16,880 +HO minusHydroxide هيدروكسايد هيدروكسايد + +50 +00:04:16,880 --> 00:04:17,360 +هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد + +51 +00:04:17,360 --> 00:04:20,000 +هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد + +52 +00:04:20,000 --> 00:04:20,660 +هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد + +53 +00:04:20,660 --> 00:04:22,780 +هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد + +54 +00:04:22,780 --> 00:04:27,020 +هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد + +55 +00:04:27,020 --> 00:04:30,260 +هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد + +56 +00:04:30,260 --> 00:04:37,420 +هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد + +57 +00:04:37,420 --> 00:04:43,720 +هيدروكسايد هيدروحوالي ست عشر، خمس عشر و نص و خمس + +58 +00:04:43,720 --> 00:04:47,340 +عشر و تسعة فلما نيجي نسأل ليش ال phenols are more + +59 +00:04:47,340 --> 00:04:51,140 +acidic than alcohols الجواب because of resonance + +60 +00:04:51,140 --> 00:04:56,460 +or because of delocalization of its chargeطبعا لو + +61 +00:04:56,460 --> 00:05:02,800 +صار عندى Nitrophenol ال delocalization بزيد يعني + +62 +00:05:02,800 --> 00:05:07,600 +الشحنة السالبة بالاضافة لإنها ممكن تنوجد على مواضع + +63 +00:05:07,600 --> 00:05:12,500 +كثيرة كمان بصير بإمكانها تنوجد على ذرات ال oxygen + +64 +00:05:12,500 --> 00:05:15,260 +بتاعون ال Nitro فبصير + +65 +00:05:17,450 --> 00:05:22,290 +الـ Delocalization للـ negative charge ايش ماله + +66 +00:05:22,290 --> 00:05:27,270 +اكتر بيصير عندي more delocalization يعني الشحنة + +67 +00:05:27,270 --> 00:05:31,350 +موزعة زي حمل بيحملوا اتنين اتريحوا شوية طب لو + +68 +00:05:31,350 --> 00:05:36,630 +حملوا تلاتة افضل لو حملوا اربعة أسهل واضح الفكرة + +69 +00:05:36,630 --> 00:05:42,650 +فبالنيتروفينول عندي more delocalization ولذلك نزل + +70 +00:05:42,650 --> 00:05:48,190 +النيتروفينول لقداشلسبعة و اتنين من عشرة ال BKA اذا + +71 +00:05:48,190 --> 00:05:52,510 +which is more acidic ال Nitrophenol is more acidic + +72 +00:05:52,510 --> 00:05:57,290 +لانه فيه more resonance طب لو صارت Trinitrophenol + +73 +00:05:57,290 --> 00:06:02,970 +more and more فهيصل ل point two five وبناء على ذلك + +74 +00:06:02,970 --> 00:06:08,670 +سمنا ايش احنا بكريك اسد ل Trinitrophenolهذه كلها + +75 +00:06:08,670 --> 00:06:12,850 +أمثلة على الـ Resonance Effect الآن لو كنت بدي + +76 +00:06:12,850 --> 00:06:17,290 +أمثلة على ال Inductive Effect لو بدأت بالإيثانول + +77 +00:06:17,290 --> 00:06:24,150 +فيه تلت مجموعات هيدروجين CH2OH CH3 طيب لو حطيت + +78 +00:06:24,150 --> 00:06:28,830 +واحدة من الهيدروجين زي كلور بتبدأ هذه الكلور تسحب + +79 +00:06:28,830 --> 00:06:30,210 +جزء من الشحنة + +80 +00:06:32,900 --> 00:06:36,200 +افترضوا ان كلهم فيهم شحنة سالبة قللت الشحنة + +81 +00:06:36,200 --> 00:06:41,580 +السالبة هذا ال effect سحب الشحنة with drawing of + +82 +00:06:41,580 --> 00:06:47,930 +the chargeأو إعطاء شحنة إيش بنسميه إحنا Inductive + +83 +00:06:47,930 --> 00:06:51,050 +Effect فال Inductive Effect هو سحب الشحنة أو + +84 +00:06:51,050 --> 00:06:55,470 +إعطائها مش نقلها لأ الشحنة موجودة هنا لكن افترض + +85 +00:06:55,470 --> 00:07:00,090 +الشحنة هنا عشر وحدات سحبنا منها واحدتين ال CL اللي + +86 +00:07:00,090 --> 00:07:05,050 +أنا بتحب السالب سحبت واحدتين جديش صفية بدل عشرة + +87 +00:07:05,050 --> 00:07:11,820 +تمانية واضح؟ الآن لو حطيت انتين CLصار عندى more + +88 +00:07:11,820 --> 00:07:17,220 +and more with the drawing لو حطيت تلاتة CL كلهم + +89 +00:07:17,220 --> 00:07:22,160 +بيسحبوا الشحنة السالبة بناء على ذلك ال effect هنا + +90 +00:07:22,160 --> 00:07:25,480 +لما انا بقول ان ال trichloroethanol is more acidic + +91 +00:07:25,480 --> 00:07:28,240 +than dichloroethanol than chloroethanol than + +92 +00:07:28,240 --> 00:07:32,340 +ethanol هذا ايش اللي بنسميه احنا inductive effect + +93 +00:07:32,340 --> 00:07:39,750 +واضح؟لمّا قررنا الـ RSH و الـ ROH مين اللي قلنا + +94 +00:07:39,750 --> 00:07:45,010 +فيهم أقوى كأسس؟ RSH طب الآن بنقول الـ RSH أقوى من + +95 +00:07:45,010 --> 00:07:51,310 +الـ ROH، why؟ because of the size، إذن هاي نعرفه + +96 +00:07:51,310 --> 00:08:00,410 +طيب، لو بدأجي أقول الـ ARSH مع الـ ROH، مين أقوى؟ + +97 +00:08:02,130 --> 00:08:06,990 +because of the size لحظوا ال AR هنا و ال AR هنا + +98 +00:08:06,990 --> 00:08:11,890 +فيهم resonance فبطل ال resonance هو السبب يعني ال + +99 +00:08:11,890 --> 00:08:16,150 +aromatic او البنزينة هنا و البنزينة هنا فينول و + +100 +00:08:16,150 --> 00:08:22,040 +ثيوفينول ال AR عامل مشتركاللي بيعمل resonance بناء + +101 +00:08:22,040 --> 00:08:25,900 +على ذلك لو حد .. لو بدنا نجيب سؤال arsh is more + +102 +00:08:25,900 --> 00:08:30,240 +acidic than aroh due to resonance غلط لأنه هنا فيه + +103 +00:08:30,240 --> 00:08:33,680 +resonance و هنا فيه resonance طب هاش المختلف + +104 +00:08:33,680 --> 00:08:41,950 +sulfur و oxygen اذا because of the sizeلكن لو اجيت + +105 +00:08:41,950 --> 00:08:49,470 +قلتلكم بدأ اقارن ARSH و RSH، لاحظوا ال sulphur، + +106 +00:08:49,470 --> 00:08:53,990 +sulphur the same size، اذا وين صار الفرق؟ AR ولا + +107 +00:08:53,990 --> 00:09:00,310 +R؟ اذا why؟ because of resonance + +108 +00:09:04,470 --> 00:09:11,150 +لو كنت بدأ اقارن A R O H مع R O H ال O و ال O نفس + +109 +00:09:11,150 --> 00:09:16,870 +ال size اللي اتغير R و A R إذا مين أعلى؟ A R + +110 +00:09:16,870 --> 00:09:23,650 +because of resonance بضحك الفكرة لما بنعمل مقارنة + +111 +00:09:23,650 --> 00:09:29,630 +الآن لو إجيت على هدولة كلهم و قولت بدأ أسطب كل + +112 +00:09:29,630 --> 00:09:37,500 +الكلاموبلغة عربية بسيطة جدا بدي أقول من الأقوى ومن + +113 +00:09:37,500 --> 00:09:44,240 +الأضعف في الأربعة ال A R S H هو أقوى حاجة ال A R S + +114 +00:09:44,240 --> 00:09:51,560 +H هو الأقوى the strongest وال R O H هو الأضعف + +115 +00:09:54,370 --> 00:10:00,150 +يعني لو بقارن ال alcohols و ال thyols و ال phenols + +116 +00:10:00,150 --> 00:10:04,330 +و ال thyophenols أقوى واحد فيهم ال thyophenol و + +117 +00:10:04,330 --> 00:10:08,710 +أضعف واحد فيهم بالحمضية اللي هو إيش ال alcohol هذا + +118 +00:10:08,710 --> 00:10:14,970 +الكلام بينعكس على التفاعلات الكيميائيةهذا الكلام + +119 +00:10:14,970 --> 00:10:19,170 +الآن ان هذا الأضعف بنعكس على التفاعلات الكيميائية + +120 +00:10:19,170 --> 00:10:22,990 +وين بنعكس على التفاعلات الكيميائية مش احنا قاعدين + +121 +00:10:22,990 --> 00:10:28,010 +نقول هدولة أحماط مظبوط ولا لأ طول عمرنا بنعرف + +122 +00:10:28,010 --> 00:10:35,170 +الجملة الشهيرة حمض زاد قاعدة ملح زاد ماء بناء على + +123 +00:10:35,170 --> 00:10:40,570 +ذلك لو اجيت أفاعل هدولة مثلا مع قاعدة قوية زي ال N + +124 +00:10:40,570 --> 00:10:53,890 +A O Hزائد NaOH كلهم مش هم زائد قاعدة اه هلاحظ ان + +125 +00:10:53,890 --> 00:10:57,670 +تلاتة منهم بتفاعل وبيعطوا ملح زائد ماء واحد + +126 +00:10:57,670 --> 00:11:05,990 +مابتفعلش الا مابتفعلش هذا هذا بتفعل هذا بتفعل هذا + +127 +00:11:05,990 --> 00:11:11,040 +بتفعلواضح؟ طبعا لو قولنا لكم اكتبوا المعادلة، + +128 +00:11:11,040 --> 00:11:17,080 +عندنا مثال، لو أخدنا هذا ال R O H زي N A O H، إيش + +129 +00:11:17,080 --> 00:11:24,600 +كتبنا؟ No reaction لكن لو قولنا R S H زي N A O H، + +130 +00:11:24,600 --> 00:11:29,770 +ال H مع ال O H، إيش بيعملوا؟ ميّهطول عمره و ال RS + +131 +00:11:29,770 --> 00:11:36,350 +minus مع ال NA NA plus RS minus و بنفس الطريقة + +132 +00:11:36,350 --> 00:11:45,830 +بإمكانكم تكتبوا إيش كل الأشياء RSH + +133 +00:11:45,830 --> 00:11:46,050 +مع + +134 +00:11:57,410 --> 00:12:03,230 +فاهم الان دائما اذا وجد عندك مش سؤال مش سؤالك هذا + +135 +00:12:03,230 --> 00:12:08,170 +ال specific مش سؤالك هذا ال specific لأ اذا اي + +136 +00:12:08,170 --> 00:12:15,110 +شغلة حطيت فيها متغيرين معناه ذلك مش هيكون عندك ثقة + +137 +00:12:15,110 --> 00:12:20,110 +كاملة انك بتقدر تاخد الجواب مباشرة الا من التجربة + +138 +00:12:20,110 --> 00:12:27,210 +و من قيمة اش بتطلع التجربة ال BKAإذا صار عندك + +139 +00:12:27,210 --> 00:12:31,910 +متغيرين سؤالك انا بعتبره جيد انه انت غيرتي هنا ال + +140 +00:12:31,910 --> 00:12:37,970 +ar و r و هنا ال o و ال s و سألت مين الأقوى فيهم + +141 +00:12:37,970 --> 00:12:44,250 +كام متغير عندك اتنين الحل انك تبحثي تعمل التجربة و + +142 +00:12:44,250 --> 00:12:48,550 +تشوف ال bk ايه لهذا و ال bk لهذا و تعمل المقارنة + +143 +00:12:48,550 --> 00:12:54,180 +ولذلك في العلم دائما لما بتعملوا المقارنةبتثبتوا + +144 +00:12:54,180 --> 00:12:59,600 +جميع المتغيرات ما عدا متغير واحد بيصير بإمكانكوا + +145 +00:12:59,600 --> 00:13:03,420 +تعملوله مقارنة و تعملوله قوانين يمكن هذا الكلام + +146 +00:13:03,420 --> 00:13:08,780 +أكثر شيء مر عليكم في منطقة الغازات ليش؟ لأن + +147 +00:13:08,780 --> 00:13:13,500 +الغازات لها أكتر من متغير الضغط والحجم وعدد + +148 +00:13:13,500 --> 00:13:19,790 +المولات ودرجة الحرارةأربع متغيرات في الغازات واضح؟ + +149 +00:13:19,790 --> 00:13:23,810 +الآن الغازات في النهاية كانت بتنجمع بمعادلة B في V + +150 +00:13:23,810 --> 00:13:28,570 +بساوي N في R في T pressure في volume بساوي number + +151 +00:13:28,570 --> 00:13:32,610 +of moles في R تابع الغازات في ال temperature الآن + +152 +00:13:32,610 --> 00:13:36,770 +لما كنت قادش أقول بدي أقارن ال volume مع ال + +153 +00:13:36,770 --> 00:13:43,210 +temperature كنت أحط لنفس الكمية من الغاز عندنفس + +154 +00:13:43,210 --> 00:13:49,550 +الضغط واضح بعد ذلك تصبح المقارنة أصعب تعمل تجربة + +155 +00:13:49,550 --> 00:13:55,930 +الان هنا ال O و O مشتركات ال R و AR مختلفات سهل + +156 +00:13:55,930 --> 00:14:01,650 +علي أعطي جواب واضح الفكرة؟ لكن هنا ال S أفضل من ال + +157 +00:14:01,650 --> 00:14:07,940 +O و ال AR أفضل من ال Rإيش النتيجة؟ التجربة + +158 +00:14:07,940 --> 00:14:14,040 +المجموعة التجربة واضح؟ يعني مافيش عندك جواب هذي + +159 +00:14:14,040 --> 00:14:16,880 +أفضل من هذي و هذي أفضل من هذي طب هذي أفضل من هذي + +160 +00:14:16,880 --> 00:14:20,440 +بقدش و هذي أفضل من هذي بقدش عشان يطلع عندي جواب؟ + +161 +00:14:20,440 --> 00:14:29,160 +لأ بدك تعمل التجربة واضح؟ سؤال جيد الآن لاحظوا معي + +162 +00:14:29,160 --> 00:14:32,340 +هل يا ترى الكيميائي + +163 +00:14:33,600 --> 00:14:38,120 +بيستسلم؟ لأ، يعني سبحان الله زي ما بتقول آية كريمة + +164 +00:14:38,120 --> 00:14:44,820 +وفوق كل ذي علم عليم واضح؟ يعني احنا قولنا الكحول + +165 +00:14:44,820 --> 00:14:52,580 +هذا زائد N A O H لا يتفاعل طب ال N A O H كان تصنيف + +166 +00:14:52,580 --> 00:15:00,380 +strong baseقاعدة قوية الان ال N A O H is a strong + +167 +00:15:00,380 --> 00:15:05,360 +base مركب ايوني و قاعدة قوية طب حبيل غصب عنه + +168 +00:15:05,360 --> 00:15:11,000 +الكحول الفاعله ايش بنعمله بنجيبله very strong base + +169 +00:15:11,000 --> 00:15:16,460 +يعني بنجيبله قاعدة تكون اقوى من ال N A O H موجود + +170 +00:15:16,460 --> 00:15:20,860 +يعني بدل ما اجي افعله مع ال N A O H اللي strong + +171 +00:15:20,860 --> 00:15:26,490 +base ممكن افعله مع N A Hهذا المركب اسمه Sodium + +172 +00:15:26,490 --> 00:15:33,110 +Hydride الجزء القاعد فيه ايون H- الهيدرايد H- + +173 +00:15:33,110 --> 00:15:40,510 +واضح؟ ايش بنسمي هذا Sodium Hydride لاحظوا ال I + +174 +00:15:40,510 --> 00:15:47,390 +نهاية ايون سالف يعني هذا NA plus H- ويمكن كلكم + +175 +00:15:47,390 --> 00:15:54,470 +بتعرفوا او سبق مر عليكم ان ال H لهاتلت حلق ال H + +176 +00:15:54,470 --> 00:15:58,910 +ممكن تتخيلوها بتلت حلق ال H لحالها اللي فيها + +177 +00:15:58,910 --> 00:16:04,010 +إلكترون و ال H اللي فقدت الإلكترون و ال H لو + +178 +00:16:04,010 --> 00:16:09,010 +اكتسبت كمان إلكترون يعني ذرة الهيدروجين هي الذرة + +179 +00:16:09,010 --> 00:16:12,430 +اللي فيها إلكترون و بروتون فهذا ال H اللي فيها + +180 +00:16:12,430 --> 00:16:17,810 +إلكترون و بروتون هيدروجين أتم الآن لو فقدت + +181 +00:16:18,700 --> 00:16:25,900 +الإلكترون شو بنسميها بروتون بروتون ما انتوا تخيلوا + +182 +00:16:25,900 --> 00:16:31,020 +الذرة اتخيلوها بالذرة مش عندى نواة موجبة في كل + +183 +00:16:31,020 --> 00:16:38,060 +الأحوال و هالنواة الموجبة حواليهاالألكترون صارت + +184 +00:16:38,060 --> 00:16:41,660 +هيدروجين أتم الهيدروجين أتم نوال موجبة حوالها + +185 +00:16:41,660 --> 00:16:47,140 +إلكترون طيب لو صارت هيك وشيلنا الإلكترون شو الصفة + +186 +00:16:47,140 --> 00:16:55,280 +عندي النوال موجبة بس لبروتون واضح؟ الآن لو اكتسبت + +187 +00:16:55,280 --> 00:17:00,620 +كمان إلكترون تاني بتصير هيدرايد أنيون فهذه + +188 +00:17:00,620 --> 00:17:09,330 +هيدروجين أتمهذا البروتون وهذا الهيدرايد أنيون ال H + +189 +00:17:09,330 --> 00:17:14,810 +minus هيدرايد أنيون كتبنا هناك هيدرايد هذا دايما + +190 +00:17:14,810 --> 00:17:20,320 +البروتون اش بنسمي احنا او ال H plusبروتون ال H بلس + +191 +00:17:20,320 --> 00:17:25,400 +بروتون ولذلك الأحماض لما بنوصفها مثلا بنقول ال + +192 +00:17:25,400 --> 00:17:31,020 +HNO3 بنقول عنه في بروتون واحد monobrotic acid ال + +193 +00:17:31,020 --> 00:17:38,640 +H2SO4 بنقول dibrotic acid ال H3BO4 بنقول عنه + +194 +00:17:38,640 --> 00:17:43,100 +tribrotic acid واضح؟ اللي جابنا عن هالكلام كلمة + +195 +00:17:43,100 --> 00:17:51,800 +إيش؟السوديوم هايدرايد هو مصدر + +196 +00:17:51,800 --> 00:17:57,080 +قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى + +197 +00:17:57,080 --> 00:17:57,100 +قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى + +198 +00:17:57,100 --> 00:18:01,200 +قوى قوى قوى قوى قوى قوى قوى + +199 +00:18:02,990 --> 00:18:06,750 +اللي هو لو كنا بناخده مع الاثانول مثلا Sodium + +200 +00:18:06,750 --> 00:18:11,870 +Ethoxide كذلك الحال لو فعلنا مع ال metal نفسه NA + +201 +00:18:11,870 --> 00:18:19,010 +Sodium Metal Sodium Metal كmetal لوحده أقوى كقاعدة + +202 +00:18:19,010 --> 00:18:24,350 +من ال NAOH يعني بإمكانه يتفاعل ال ROH مع ال NA + +203 +00:18:24,350 --> 00:18:29,290 +ويعطينا RO minus في الحالتين ال بيكتمل التفاعل انه + +204 +00:18:29,290 --> 00:18:35,630 +بيطلع غاز هيدروجينفصحيح ان ال R O H بتفعلش مع ال N + +205 +00:18:35,630 --> 00:18:40,290 +A O H ولكنه يتفاعل مع ال sodium hydrate او ال + +206 +00:18:40,290 --> 00:18:46,090 +sodium metal وبيعطينا ال R O minus N A plus واضح + +207 +00:18:46,090 --> 00:18:54,450 +هذه الفكرة لان هذه تعتبر كقواعد اقوى من ال N A O H + +208 +00:18:56,180 --> 00:19:01,080 +بهيك بيكفي في موضوع ال acidity لو اجينا على ال + +209 +00:19:01,080 --> 00:19:07,040 +preparation of alcohol الحقيقة هتلاحظ انه بشكل عام + +210 +00:19:07,040 --> 00:19:14,260 +ال preparation of alcohol مر معنا طب وين مر معنا؟ + +211 +00:19:14,260 --> 00:19:21,040 +في مكانين المكان الأول لما كنا ناخد double bond و + +212 +00:19:21,040 --> 00:19:24,440 +نعمل عليها addition of water in presence of acid + +213 +00:19:25,200 --> 00:19:31,800 +إيش كانت الضيف؟ H و OH إذا إنها تيش كحول، واضح؟ + +214 +00:19:31,800 --> 00:19:37,680 +فإضافة الماء للالكينز هذه الطريقة ولذلك الإثانول + +215 +00:19:37,680 --> 00:19:42,800 +مثلا بنحضره بإضافة الماء للإثيلين + +216 +00:19:44,070 --> 00:19:48,550 +طبعا إله شغل عملي و ال yield جليل لكن بيعيدوا + +217 +00:19:48,550 --> 00:19:51,810 +التفاعل أكتر من مرة لحد ما يمشوا التفاعل يعني + +218 +00:19:51,810 --> 00:19:57,110 +الفكرة العلمية أنه بتفاعل و بيضيف واضح صناعيا أكيد + +219 +00:19:57,110 --> 00:20:01,690 +إله أجهزة أو إله متابعة صناعية كذلك الحال اللي + +220 +00:20:01,690 --> 00:20:06,230 +بتذكر ال alkenes و إضافة الميه لازم يظلوا متذكر + +221 +00:20:06,230 --> 00:20:06,710 +إيش + +222 +00:20:09,640 --> 00:20:12,940 +Markovnikov وAntimarkovnikov addition يعني انا لما + +223 +00:20:12,940 --> 00:20:18,520 +كنت على البروبين اضيف الماء في وجود H بلس وين كنت + +224 +00:20:18,520 --> 00:20:23,700 +احط الهيدروجين هان ال O-H هان اطلع البروبان to all + +225 +00:20:23,700 --> 00:20:27,780 +او to probanol او ايزو برو بالالكول ماكانش يطلع + +226 +00:20:27,780 --> 00:20:34,200 +هذا طب لو بدنا هذا شو كنا نعمل Antimarkovnikov + +227 +00:20:36,400 --> 00:20:40,420 +كنا نستعمل طريقة ال boron ال bh3 و توابعها + +228 +00:20:40,420 --> 00:20:46,540 +بترجعوها واضح؟ إذا الكحولات يمكن أن تحضر و أخدنا + +229 +00:20:46,540 --> 00:20:51,000 +هذا الكلام بالتفصيل من خلال إضافة الماء على ال + +230 +00:20:51,000 --> 00:20:56,860 +alkyls برضه طريقة تانية أخدناها لتحضير الكحولات + +231 +00:20:56,860 --> 00:20:59,440 +مين اتذكرنا فيها؟ + +232 +00:21:04,290 --> 00:21:10,270 +الـ RX زائد الماء أو الـ OH ماينوس مش كنا ناخد هذه + +233 +00:21:10,270 --> 00:21:18,110 +المعادلة RX زائد H2O in general R OH لنيوكليوفيليك + +234 +00:21:18,110 --> 00:21:23,710 +سبستيوشن على ال الكلهيلايت شبتر ستة سواء كنا نفعله + +235 +00:21:23,710 --> 00:21:27,940 +مع نيوترال نيوكليوفايل او معit charged the + +236 +00:21:27,940 --> 00:21:32,680 +nucleophile واضح ال substitution إذا الطرق العامة + +237 +00:21:32,680 --> 00:21:38,340 +لتحضير الكحولات يا إما من ال RX بالإبدال يا إما من + +238 +00:21:38,340 --> 00:21:45,840 +ال alkenes بتفاعل إيش بنسميه الإضافة ما هو مع + +239 +00:21:45,840 --> 00:21:53,100 +الميه تفاعل إضافة addition reaction واضح الآن لو + +240 +00:21:53,100 --> 00:22:00,470 +إجينا بعد هيك على تفاعلاتالكحولات تفاعلات الكحولات + +241 +00:22:00,470 --> 00:22:05,210 +طبعا في زميلة لكم بس عشان يعني ما نغمطهاش حقها ان + +242 +00:22:05,210 --> 00:22:10,530 +هي منتبهة جالت من ال evoxides كلامها سليم يعني لما + +243 +00:22:10,530 --> 00:22:14,950 +كان يكون عندكم الالكين و اضيف عليه ال oxygen أعمل + +244 +00:22:14,950 --> 00:22:22,050 +منه evoxide و بعد هيك لو عملنا ring opening + +245 +00:22:22,050 --> 00:22:28,320 +باستعمال ال nucleophile كنا نقول CCOH و يجي + +246 +00:22:28,320 --> 00:22:32,640 +لنكليوفايل this is an alcohol كلامها سليم ماكنش + +247 +00:22:32,640 --> 00:22:39,500 +فيه غلط واضح لكن منطلقوا ايش الالكين برضه منطلقنا + +248 +00:22:39,500 --> 00:22:43,860 +الالكين اعملنا ابوكسايد و عملنا ring opening هذا + +249 +00:22:43,860 --> 00:22:48,780 +الكلام ماكن ان شاء الله الان لو اجينا على موضوع ال + +250 +00:22:48,780 --> 00:22:56,650 +reactions of alcoholsمن تفاعلات ال alcohols تفاعل + +251 +00:22:56,650 --> 00:23:01,390 +ال dehydration معنى ال dehydration او acidic + +252 +00:23:01,390 --> 00:23:08,500 +dehydration نزع الماء في وجود الحامضنزع الماء في + +253 +00:23:08,500 --> 00:23:12,660 +وجود الحامض هذا ايش اسمه dehydration حدف الماء في + +254 +00:23:12,660 --> 00:23:17,280 +وجود الحامض الآن بدنا ننتبه هنا لنقطة انه احنا + +255 +00:23:17,280 --> 00:23:22,940 +ممكن نعمل هذا التفاعل بطريقتين تؤدي الى ناتجين + +256 +00:23:22,940 --> 00:23:28,280 +مختلفين ممكن من نفس الكحول يعني لو أخدنا الاثانول + +257 +00:23:28,280 --> 00:23:31,240 +كمثال ننزع من هنا OH + +258 +00:23:34,460 --> 00:23:40,300 +OH من carbon مجاورة هنا رفعنا ايش؟ مية لما بنشيل + +259 +00:23:40,300 --> 00:23:48,100 +OH مع اتش شو ممكن نعمل؟ الالكين الحد في عكس ايش؟ + +260 +00:23:48,100 --> 00:23:53,400 +الاضافة اضافة الماء على الالكين بتاعة الالكول حد + +261 +00:23:53,400 --> 00:23:58,520 +في ال ..إضافة الماء على الالكين تعطي الالكول وحذف + +262 +00:23:58,520 --> 00:24:03,620 +الماء من الالكول ممكن يعطي الالكين هذا أحد النواتج + +263 +00:24:03,620 --> 00:24:09,120 +الناتج التاني انه يتفاعلوا جزيئين من الالكول مع + +264 +00:24:09,120 --> 00:24:15,040 +بعضواضح؟ يعملول ال ether يعني هذا ال ethanol مع + +265 +00:24:15,040 --> 00:24:19,740 +ethanol تاني CH3CH2OH + +266 +00:24:19,740 --> 00:24:24,020 +يعني طبعا من و ال ethanol التاني ما انا حاطط ال + +267 +00:24:24,020 --> 00:24:29,380 +ethanol ملايين الجزيئات فجزيئ بتفاعل ايش؟ مع جزيئ + +268 +00:24:29,380 --> 00:24:35,200 +لاحظوا لما يعمل ال ether CH3CH2OCH2CH3 + +269 +00:24:35,200 --> 00:24:41,990 +ايش حُدف من هدول الجزيئين؟مية O H من واحد O H من + +270 +00:24:41,990 --> 00:24:46,490 +واحد يعني كأنه بالظبط اللي بده يصير هنا أن هذه ال + +271 +00:24:46,490 --> 00:24:51,630 +O بدها تهاجم هنا على الكربون وتترد ال O H الآن و + +272 +00:24:51,630 --> 00:24:53,230 +هذه ال O شو هتخسر؟ + +273 +00:24:57,940 --> 00:25:01,920 +هي لما هذه هاجمت من خلال الـ Oxygen كان يوكليوفايل + +274 +00:25:01,920 --> 00:25:06,880 +طردت الـ OH والنيوترال يوكليوفايل دايما بيخسر ايش؟ + +275 +00:25:06,880 --> 00:25:11,740 +H اتفقنا على هذا الكلام هذه خسرت الـ H والـ OH ايش + +276 +00:25:11,740 --> 00:25:19,280 +عملوه؟ H2O يعني هنا زائد H2O وهنا زائد H2O لكن هنا + +277 +00:25:19,280 --> 00:25:23,780 +ما حُدفت من جزء واحد اعطت الالكين لو حُدفت من + +278 +00:25:23,780 --> 00:25:31,820 +التفاعل بين جزيين بتعطي ايش؟الـ Ether الـ ROR هو + +279 +00:25:31,820 --> 00:25:36,780 +الـ Ether طبعاً بيصير السؤال يا ترى أي التفاعلات + +280 +00:25:36,780 --> 00:25:42,640 +بيمشي بيعتمد على عدة عوامل من أهمها درجة الحرارة + +281 +00:25:42,640 --> 00:25:47,580 +زائد العوامل الحفازة اللي بيستعملوها للتفاعل خلينا + +282 +00:25:47,580 --> 00:25:51,260 +نكون مركزين على درجة الحرارة لو هذا التفاعل عملناه + +283 +00:25:51,260 --> 00:25:56,280 +عند 140 درجة مئوية هيعطينا بشكل أساس الـ Etherو لو + +284 +00:25:56,280 --> 00:26:00,740 +عملناها عند 180 درجة مئوية هيعطينا بشكل أساسي + +285 +00:26:00,740 --> 00:26:06,220 +الالكيد لكن بقولكوا أن التفاعل صناعيا له شغلات + +286 +00:26:06,220 --> 00:26:11,300 +تانية و بيستعمله catalyst معينة اللي مع الحرارة + +287 +00:26:11,300 --> 00:26:16,960 +تفضل هذا أو هذا يعني بعض العوامل الحفازة مع حرارة + +288 +00:26:16,960 --> 00:26:21,760 +أعلى من 180 ع 250 ممكن تخلي التفاعل يعطي بس ال + +289 +00:26:21,760 --> 00:26:27,030 +الكيد و بعض العوامل الحفازةعلى مية و اربعين، مية و + +290 +00:26:27,030 --> 00:26:34,050 +خمسين، ممكن تخليه يعطي بس إيش؟الإيثر الآن بدناش + +291 +00:26:34,050 --> 00:26:37,510 +ندخل في التفصيل الممل احنا بنقول انه تسخين + +292 +00:26:37,510 --> 00:26:42,030 +الاثانول في وجود الحامض 140 هيعطيني ال ether و 180 + +293 +00:26:42,030 --> 00:26:47,950 +هيعطيني ال alkene و القمر لما يصير في الصناعة اكيد + +294 +00:26:47,950 --> 00:26:52,310 +اللي بيشتغلوا فيه يعني عندهم انتباه لأشياء إضافية + +295 +00:26:52,310 --> 00:26:56,290 +و لعوامل حفازة اللي يتحكموا ايش الناتج اللي بيطلع + +296 +00:26:56,290 --> 00:26:56,670 +عندهم + +297 +00:26:59,310 --> 00:27:04,610 +الان لو أخدنا مثال تاني لو أخدنا ال tertiary butyl + +298 +00:27:04,610 --> 00:27:08,770 +alcohol عارفينه ال tertiary butyl alcohol اللي هو + +299 +00:27:08,770 --> 00:27:12,470 +ال carbon اللي حامله تلت مجموعات مثل يعني لو رسمته + +300 +00:27:12,470 --> 00:27:22,330 +انا OH CH3 CH3 CH3 و سخناه في وجود حامض بالتأكيد + +301 +00:27:22,330 --> 00:27:31,490 +هيفقدالـ OH و هيفقد معها H من كاربون مجاورة الآن + +302 +00:27:31,490 --> 00:27:35,770 +التلت ذرات اللي هنا متكافئات ولا لأ؟ والتسع + +303 +00:27:35,770 --> 00:27:39,150 +هيدروجينات متكافئات عشان ايه؟ لو بدأ أقولكوا هذا + +304 +00:27:39,150 --> 00:27:42,990 +الحذف أو هذا ال dehydrationيعني جيكوا اك سؤال + +305 +00:27:42,990 --> 00:27:46,930 +dehydration of tertiary-butanol او tertiary-butyl + +306 +00:27:46,930 --> 00:27:51,770 +alcohol produces how many products؟ one يعني لو + +307 +00:27:51,770 --> 00:27:55,970 +شال H من هان زي هان زي هان بدون ما ندخل في + +308 +00:27:55,970 --> 00:27:59,250 +الميكانيزم لو رسمتوا double bond هان او رسمتوها + +309 +00:27:59,250 --> 00:28:03,230 +هان او رسمتوها هان هو ايش؟ نفس المركب هنا مثلا + +310 +00:28:03,230 --> 00:28:09,230 +رسمنا الـOH هذه مع H من هدولة هي الناتج ايش اسمه؟ + +311 +00:28:09,230 --> 00:28:15,840 +ISOبيوتين مار عليكم ايزو بيوتين او لو بتكوينها بال + +312 +00:28:15,840 --> 00:28:22,300 +ايوبك one two three وعنمرة اتنين حامل ايش مثل اذا + +313 +00:28:22,300 --> 00:28:27,660 +two مثل بروبين two مثل بروبين هو نفس ال ايزو + +314 +00:28:27,660 --> 00:28:32,300 +بيوتين الان لاحظوا معايا ان انتوا صارت عندكم + +315 +00:28:32,300 --> 00:28:39,490 +الفكرة انه بتحذف OHو Hydrogen مجاورة لحسن الحظ في + +316 +00:28:39,490 --> 00:28:43,830 +ال tertiary butanol التلاتة زي بعض طلع بيطلع عندى + +317 +00:28:43,830 --> 00:28:49,330 +كام ناتج طب لو التلاتة مختلفات هيعطينى كام ناتج + +318 +00:28:49,330 --> 00:28:55,080 +اعملتوا مثال شبيه جدا بس لما كنتوا تحلفوا ايشمش ال + +319 +00:28:55,080 --> 00:29:01,400 +H O H ال H C L و سلمتوه homeware الحد في الميه زي + +320 +00:29:01,400 --> 00:29:06,420 +حد في ال H C L طب حد في ال H C L متذاكرين قاعدة + +321 +00:29:06,420 --> 00:29:14,280 +أخدتوها عشان اتقولكوا أي نواتج أفضل ال more + +322 +00:29:14,280 --> 00:29:18,740 +substituted زي سفرول ولذلك لو مثلا أخدتوا ال two + +323 +00:29:18,740 --> 00:29:25,870 +butanol أكيد بدنا نحدفالـ OH لكن يا تراب نحذف H من + +324 +00:29:25,870 --> 00:29:32,670 +هنا و لا H من هنا إذا حذفنا هذه ال H بنطلع هذا و + +325 +00:29:32,670 --> 00:29:36,350 +إذا حذفنا هذه ال H بنطلع هذا which is more + +326 +00:29:36,350 --> 00:29:41,780 +substitutedفي حد في ال alkalites زيها تماما ال + +327 +00:29:41,780 --> 00:29:45,020 +alcohols هذا more substituted بيكون ال major + +328 +00:29:45,020 --> 00:29:50,780 +product ال less substituted ال minor product واضح؟ + +329 +00:29:50,780 --> 00:29:56,640 +كذلك الحالة بهذا المثال هيبدأ احذف ال OH تأكيد مش + +330 +00:29:56,640 --> 00:30:03,450 +فيها نقاش بس بدي Hمجاورة هنا في اتش وهذا المثل + +331 +00:30:03,450 --> 00:30:08,030 +كمان فيها اتش لو حذفت هذا الاتش اللي هنا بيطلع + +332 +00:30:08,030 --> 00:30:12,110 +الناتج التاني و لو حذفت الاتش من هنا او اتش او اتش + +333 +00:30:12,110 --> 00:30:17,050 +بيطلع هذا نتطلع عليهم which is more substituted + +334 +00:30:17,050 --> 00:30:21,470 +اكيد هذا more substituted ال major ال minor نفس + +335 +00:30:21,470 --> 00:30:24,610 +الكلام كنا نجيب السؤال بس بدل ما نكون كاتبين OH + +336 +00:30:24,610 --> 00:30:31,410 +نكون كاتبين CL او PRاللي عملناه لما كان دا يكون CL + +337 +00:30:31,410 --> 00:30:35,170 +او PR في chapter ال elimination في ال alkalites هو + +338 +00:30:35,170 --> 00:30:40,270 +نفسه بنطبقه على ال alcohol ف ال dehydration of + +339 +00:30:40,270 --> 00:30:46,530 +alcohol بيعطي نتائج موازية تماما ل ال + +340 +00:30:46,530 --> 00:30:51,100 +dehydrohalogenation of alcoholAlkyl Halides لاحظوا + +341 +00:30:51,100 --> 00:30:55,720 +في ال alcohols شو سمينا العملية؟ dehydration نزع + +342 +00:30:55,720 --> 00:31:00,780 +الماء OH وH طب لو كانت هذه بيه R او halogen X وH + +343 +00:31:00,780 --> 00:31:05,380 +ايش قولنا عنها؟ dehydrohalogenation + +344 +00:31:05,380 --> 00:31:11,600 +واضح؟ يعني لو هذه كانت X, hydro و halogen فصارت + +345 +00:31:11,600 --> 00:31:15,280 +dehydrohalogenation + +346 +00:31:15,280 --> 00:31:22,830 +لما H و OHdehydration و سبق أن وضحت لكم إيش معناه + +347 +00:31:22,830 --> 00:31:26,710 +الإضافات و النزع hydrogenation, dehydrogenation, + +348 +00:31:26,850 --> 00:31:30,290 +hydration, dehydration, hydrogenation, + +349 +00:31:30,410 --> 00:31:36,990 +dehydrogenation هذه المصطلحات لازم تكون واضحة لازم + +350 +00:31:36,990 --> 00:31:44,750 +تكون واضحة عندكم من تفاعلات ال alcohols التفاعل مع + +351 +00:31:44,750 --> 00:31:49,670 +ال hydrogen halidesالان هذا التفاعل سبق اننا + +352 +00:31:49,670 --> 00:31:54,870 +شرحناه لكن بنعيد نأكد عليه مرة ثانية ال alcohol مع + +353 +00:31:54,870 --> 00:32:00,370 +ال hydrogen halide بيبدل ال OH ب X بيعطيني RX زائد + +354 +00:32:00,370 --> 00:32:06,290 +H2O الان لو اتيت انا اتطلعت على ال alcohol ايش + +355 +00:32:06,290 --> 00:32:10,900 +ممكن يكون ال alcohol ممكن يكون tertiaryو secondary + +356 +00:32:10,900 --> 00:32:14,800 +و primary افضل اش هيتفاعل مع ال tertiary ال + +357 +00:32:14,800 --> 00:32:24,040 +hydrogen halides ممكن تكون يود و بروم و كلور واضح؟ + +358 +00:32:25,040 --> 00:32:28,740 +الـ hydrogen halides يا يود يا بروم يا كلور، مين + +359 +00:32:28,740 --> 00:32:32,420 +أحسن واحدة بتتفعل؟ أفضل من البروم، أفضل من الكلور + +360 +00:32:32,420 --> 00:32:36,580 +والالكهول تيرتشري أفضل من سكندريا، أفضل من إيش؟ ال + +361 +00:32:36,580 --> 00:32:41,280 +primary بناء على ذلك، لو أنا أجي اتفعلت أي ألكهول + +362 +00:32:41,280 --> 00:32:47,660 +من هدولة مع يود أو بروم، يعني مع HI أو HPR، هيتفعل + +363 +00:32:47,660 --> 00:32:53,360 +بدون مشاكل ويعمل إبدالهتصير المشكلة وين؟ لو بدأ + +364 +00:32:53,360 --> 00:32:59,060 +ضقة فاعل، الأضعف هان مع الأضعف هان، بتمشي التفاعل + +365 +00:33:00,250 --> 00:33:05,650 +بشكل عام يعني لو أخدت ال primary alkyl halide مع + +366 +00:33:05,650 --> 00:33:10,450 +HCl مش هيعمل إبدال يعني لو أخدت ال ethanol مع ال + +367 +00:33:10,450 --> 00:33:16,090 +HCl إيثانول مع HCl بيعمل إبدال إيثانول primary HCl + +368 +00:33:16,090 --> 00:33:20,250 +للأضعف بيعملش إبدال بعد ذلك خدوا على سبيل المثال + +369 +00:33:20,250 --> 00:33:25,890 +high tertiary alkyl halide ملاحظين انتوا؟ مع HCl + +370 +00:33:25,890 --> 00:33:29,070 +عمل + +371 +00:33:29,070 --> 00:33:34,250 +إبدالTertiary Alkylide مع HCl عمل إبدالة اللي ما + +372 +00:33:34,250 --> 00:33:42,010 +بيعملش أي واحد ال primary مع ال HCl يمكن هنا مرات + +373 +00:33:42,010 --> 00:33:45,270 +التفاعل بيكون إيش قوي زي التانين يعني حطوله + +374 +00:33:45,270 --> 00:33:50,670 +catalyst zinc chloride ما بضرش مش مشكلة بس بيمشي + +375 +00:33:50,670 --> 00:33:57,220 +في الآخر واضح؟ بيمشيحتى لو أخدت secondary alcohol + +376 +00:33:57,220 --> 00:34:01,200 +ماقعدش CL في وجود ذنك كلورادي و شوية تسخين بمشي + +377 +00:34:01,200 --> 00:34:06,560 +لكن مين اللي فيه المشكلة ال primary؟ اه مع ال FCL + +378 +00:34:06,560 --> 00:34:12,580 +لاحظوا هنا عشان هيك بنلاقي حلول بديلة لما يصير عند + +379 +00:34:12,580 --> 00:34:17,340 +primary لو قلتلكوا ماقعدش CL إيش الجواب؟ نوريا + +380 +00:34:20,520 --> 00:34:24,140 +بدّو البني آدم هيك هيك لازم يحوّل الـ OH لـCl + +381 +00:34:24,140 --> 00:34:28,180 +بيغير ال reagent يعني لو استعمل ال primary مع ال + +382 +00:34:28,180 --> 00:34:35,080 +BCL3 فوسفوراس الـ Trichloride بيعمل تفاعل واضح؟ + +383 +00:34:35,080 --> 00:34:38,780 +يعني ال primary الكهول مع فوسفوراس ال Trichloride + +384 +00:34:38,780 --> 00:34:43,080 +بتفاعل بيبدّي ال OH بCL لكن مع ال HCL لأ بتفاعل + +385 +00:34:43,080 --> 00:34:47,320 +وغير الفوسفوراس ال Trichloride أخدنا كمان reagent + +386 +00:34:47,320 --> 00:34:56,800 +SOCL2 هذا مشهور بيسميه ثيونيليكلورايد واضح؟ برضه + +387 +00:34:56,800 --> 00:35:02,920 +هذا ايش بيعمل؟ بتفاعل و بيبدل ال OH ل ال primary + +388 +00:35:02,920 --> 00:35:08,880 +بCL فسواء استعملت الفوسفوراس ال trichloride او + +389 +00:35:08,880 --> 00:35:12,380 +الثيونيليكلورايد بقدر اعمل التفاعل لكن لو استعملت + +390 +00:35:12,380 --> 00:35:19,650 +ال HCl بمشيش التفاعلطبعا ما عدا ذلك مع اليود و مع + +391 +00:35:19,650 --> 00:35:23,730 +البروم بيمشي مع كله تيرتشاري .. سكندر .. برايماري + +392 +00:35:23,730 --> 00:35:29,370 +.. يعني المشكلة حقيقة بين ال primary و ال hcl في + +393 +00:35:29,370 --> 00:35:32,150 +حلول بديلة ولا لأ؟ كم حل؟ + +394 +00:35:40,460 --> 00:35:46,160 +هي هنا على سبيل المثال ال primary مع ال SOCl2 + +395 +00:35:46,160 --> 00:35:51,480 +بتفاعل مية في المية الان لاحظوا ان هذا التفاعل + +396 +00:35:51,480 --> 00:35:57,100 +تفاعل إبدال ال OH ب X خاص بال alcohol يعني ال + +397 +00:35:57,100 --> 00:36:03,950 +phenols لا يتم عليها إبداليعني لو قلنا لكوا ال A R + +398 +00:36:03,950 --> 00:36:16,610 +O H مع HBR مع HCL مع BCL3 مع SOCL2 بكل لغات الأرض + +399 +00:36:16,610 --> 00:36:25,460 +لا تتفاعل مافيش إبدال علىالاروماتيك كومباونز لإيش؟ + +400 +00:36:25,460 --> 00:36:29,400 +لأنه أنا هنا بدي أجيب سالب الـ nucleophile سالب و + +401 +00:36:29,400 --> 00:36:32,740 +أخليه يهاجم على البنزينة و احنا من البداية اتفقنا + +402 +00:36:32,740 --> 00:36:36,080 +انه الإبدال اللي على البنزين Electrophilic + +403 +00:36:36,080 --> 00:36:39,460 +Substitution in general واضح؟ يعني انا لو اجيت + +404 +00:36:39,460 --> 00:36:43,740 +افعل مع هدولة في النهاية هاجيب PR minus او I minus + +405 +00:36:43,740 --> 00:36:47,960 +minus على minus بيصير و لذلك الإبدالات اللي هنا + +406 +00:36:47,960 --> 00:36:53,940 +كلها اللي أخدناها هي متعلقةبالكحولات بال R O H لكن + +407 +00:36:53,940 --> 00:36:58,440 +لو صارت A R O H بنزينة أو حملة O H و قلتلكوا + +408 +00:36:58,440 --> 00:37:03,740 +بدلوها ب C L و ب R لأواضح؟ هنا مافيش substitution + +409 +00:37:03,740 --> 00:37:07,840 +في ال aromatic compounds ال substitution في إيش؟ + +410 +00:37:07,840 --> 00:37:12,200 +في ال aliphatic compounds تبوا هذا الكلام ممكن + +411 +00:37:12,200 --> 00:37:16,440 +نسألكوا يا صح و غلط aromatic alcohols undergo + +412 +00:37:16,440 --> 00:37:22,540 +substitution in uneasy manner مثلا ولا .. no they + +413 +00:37:22,540 --> 00:37:26,320 +don't undergo substitution + +414 +00:37:30,300 --> 00:37:34,040 +ما هو الـ Electrophilic Substitution بيبطل في هذه + +415 +00:37:34,040 --> 00:37:38,420 +الحالة للـ OH بيصير في مكان تاني على البنزينة + +416 +00:37:38,420 --> 00:37:44,520 +بيختلف التفاعل يعني زي ما تجيب فينول و بدك تعمل + +417 +00:37:44,520 --> 00:37:50,200 +مثلا مع الchlor FeCl3 على سبيل المثال أو تاخد O + +418 +00:37:50,200 --> 00:37:57,880 +Methyl بتصير تبدل هنا بتبدل Hydrogens مش بتبدلطبعا + +419 +00:37:57,880 --> 00:38:01,320 +المشكلة ان الفينول نفسه بعارض مع ال FEC الاتنين + +420 +00:38:01,320 --> 00:38:05,420 +افترض او مثل مثلا بتبدليش ال او مثل بتبدلي ايش + +421 +00:38:05,420 --> 00:38:11,540 +بتبدلي على الحلقة هيدروجينات بتبدلي هيدروجينات على + +422 +00:38:11,540 --> 00:38:20,140 +الحلقة الان ال alcohol من تفاعلاتها الشهيرة تفاعل + +423 +00:38:20,140 --> 00:38:25,720 +ال oxidation خليني اقول ايش معنى ال oxidationال + +424 +00:38:25,720 --> 00:38:29,920 +Oxidation بلغة الكيميا ما انا عارف ترجمتها انه + +425 +00:38:29,920 --> 00:38:34,900 +افقد ال H تبعت ال OH يعني لو انا اطلعت على المركب + +426 +00:38:34,900 --> 00:38:41,420 +CHOH زي هيك و ايش ما كان يكون عندى هنا ان افقد + +427 +00:38:41,420 --> 00:38:47,910 +جزئها هيدروجينأفقد الـ H اللي على الأكسجين و H على + +428 +00:38:47,910 --> 00:38:52,310 +الكربون المتسقة بها الأكسجين مباشرة الآن هدولة لو + +429 +00:38:52,310 --> 00:38:56,550 +فقدوا زي هيك على شكل جزء هيدروجين هذه إيش بنتيجة + +430 +00:38:56,550 --> 00:39:02,950 +تعمل هنا double bond طالما عملت double bond شو + +431 +00:39:02,950 --> 00:39:09,330 +هيصير النتج الديهايد أو كيتونباعتمد على هدول + +432 +00:39:09,330 --> 00:39:13,130 +المجموعتين خلّينا نكون في البداية فاهمين قصة + +433 +00:39:13,130 --> 00:39:18,950 +الأكسدة الأكسدة معناها ان ال COH بيصير C double + +434 +00:39:18,950 --> 00:39:24,090 +bond O طالما C double bond O صارت اذا صارت الجهاي + +435 +00:39:24,090 --> 00:39:29,870 +او كيتون هتفقد ال H تعطي ال OH OH عن الكربون اللي + +436 +00:39:29,870 --> 00:39:35,790 +هنا اول سؤال هيجيكم طب يا ترى لو فيش هنا H + +437 +00:39:38,560 --> 00:39:43,880 +يعني لو هذه كانت R و R و R فى عندي OH مستعدة تفقد + +438 +00:39:43,880 --> 00:39:48,860 +ال H بس فىش هنا H يعني صار إيش نوع ال alcohol? + +439 +00:39:50,620 --> 00:39:55,800 +tertiary واضحة؟ يعني افترضوا هذه كانت C وهذه C + +440 +00:39:55,800 --> 00:40:02,370 +وهذه C CH3 CH3 CH3 هنا فى H هنا مافيش Hبدوا يتم + +441 +00:40:02,370 --> 00:40:07,270 +الأكسدة؟ إذا على طول هنطلع قاعدة أن الـ tertiary + +442 +00:40:07,270 --> 00:40:11,070 +alcohols اللي مافيش عليهم هيدروجينة هنا بتأكسدوش + +443 +00:40:11,070 --> 00:40:17,150 +إذا التأكسد خاص بماذا؟ ال primary و ال secondary + +444 +00:40:17,150 --> 00:40:22,090 +التيرتشاري مابصله أكسدة ليش؟ لأن الأكسد بدأ أفقد + +445 +00:40:22,090 --> 00:40:25,130 +من ال OH هيدروجينة و من الكربون اللي حامله + +446 +00:40:25,130 --> 00:40:27,850 +هيدروجينة طب الكربون اللي حامله مش حامله هيدروجينة + +447 +00:40:28,820 --> 00:40:33,540 +إذا الأكسدة لا تتم مع إيش؟ مع ال tertiary + +448 +00:40:33,540 --> 00:40:37,860 +alcohols، الآن مع ال primary وال secondary؟ بالتم، + +449 +00:40:37,860 --> 00:40:44,160 +شو بدها تعطيني؟الديهايد او كيتون وقت ايش بتعطي + +450 +00:40:44,160 --> 00:40:49,760 +الديهايد و وقت ايش بتعطي كيتون ال primary ببساطة + +451 +00:40:49,760 --> 00:40:55,480 +بيعطي الديهايد و ال secondary بيعطي كيتون واضح؟ + +452 +00:40:55,480 --> 00:40:59,380 +اذا كأنه لو الانسان بده يلخص الكلام ان ال alcohol + +453 +00:40:59,380 --> 00:41:03,920 +في كام نوع؟ primary secondary و tertiary ال + +454 +00:41:03,920 --> 00:41:11,080 +tertiaryكفى الله المؤمنين القتال ..مش فيها كلمة شر + +455 +00:41:11,080 --> 00:41:17,300 +..وكفى الله المؤمنين القتال ال tertiary بتأكسدش ال + +456 +00:41:17,300 --> 00:41:22,400 +primary لما يتأكسد شو هيعطيني ال dihyde ال + +457 +00:41:22,400 --> 00:41:28,130 +secondary لما يتأكسد شو هيعطيني كيتونلحظته هيك + +458 +00:41:28,130 --> 00:41:34,290 +بيصير العلم ايش ماله؟ سهل انه ال alcohols تلاتة ال + +459 +00:41:34,290 --> 00:41:38,630 +primary او ال secondary او ال tertiary ال primary + +460 +00:41:38,630 --> 00:41:44,560 +هيعطيني aldehyde ال secondary كيتون ال tertiaryمش + +461 +00:41:44,560 --> 00:41:50,320 +حيت أكسد الان المرة الجاية بتجيجتين هنوضح ايش + +462 +00:41:50,320 --> 00:41:54,440 +العامل المؤكسد اللي بتتم فيه العملية يعني نبدأ من + +463 +00:41:54,440 --> 00:41:58,820 +هذه بنشرحها بتجيجتين وننتبه ان ال الديهايد ممكن + +464 +00:41:58,820 --> 00:42:06,400 +بعدين يعمل تفاعل تاني يصير أسد هذه زيادة واضح؟ لكن + +465 +00:42:06,400 --> 00:42:12,560 +الأكسد الأساسية الأولى ال primary شو بيصير؟الـ + +466 +00:42:12,560 --> 00:42:17,640 +secondary الـ tertiary لا يتأكسد الان ال primary + +467 +00:42:17,640 --> 00:42:22,200 +بعد ما يصير الديهاي ممكن لو العامل المؤكسد قوي + +468 +00:42:22,200 --> 00:42:28,660 +يمشي كمان مرحلة يصير أسد لو ضعيف بيظل زي ما هو إذا + +469 +00:42:28,660 --> 00:42:32,340 +بتصير قصتنا إيش العامل المؤكسد اللي استعملنا هان و + +470 +00:42:32,340 --> 00:42:37,340 +هان هان من الأساس مافيش أكسدة من هذه المقطة ان شاء + +471 +00:42:37,340 --> 00:42:40,120 +الله بنبدأ المرة الجاية + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..6ae450446c2170e5564f2dbcfff8d6b0d1cb84a8 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 3386, "start": 19.52, "end": 33.86, "text": "بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في موضوع ال acidity و عرفنا بالظبط ايش معنى الأحمار و وضحنا انه مهم جدا نعرف ايش معنى ال BKA", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 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هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد هيدرو", "tokens": [39, 6655, 340, 34454, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 8032, 25708, 32887, 4117, 3794, 995, 25708, 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نسأل ليش ال phenols are more acidic than alcohols الجواب because of resonance or because of delocalization of its charge", "tokens": [5016, 2407, 6027, 1829, 8608, 2655, 6225, 46309, 12399, 16490, 2304, 3794, 6225, 46309, 4032, 8717, 9381, 4032, 16490, 2304, 3794, 6225, 46309, 4032, 6055, 3794, 27884, 6156, 1211, 15042, 8717, 1829, 7435, 1829, 8717, 3794, 10721, 1211, 32239, 8592, 2423, 7279, 19385, 366, 544, 39514, 813, 7658, 82, 25724, 14407, 3555, 570, 295, 30944, 420, 570, 295, 1103, 36483, 2144, 295, 1080, 4602], "avg_logprob": -0.2127403846153846, "compression_ratio": 1.387878787878788, "no_speech_prob": 0.0, "words": [{"start": 280.38, "end": 281.02, "word": "حوالي", "probability": 0.856689453125}, {"start": 281.02, "end": 281.3, "word": " ست", "probability": 0.685791015625}, {"start": 281.3, "end": 282.12, "word": " عشر،", "probability": 0.4912923177083333}, {"start": 282.12, "end": 282.74, "word": " خمس", "probability": 0.9274088541666666}, {"start": 282.74, "end": 283.04, 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0.95947265625}, {"start": 486.99, "end": 487.29, "word": " فيهم", "probability": 0.936279296875}, {"start": 487.29, "end": 487.95, "word": " resonance", "probability": 0.91796875}, {"start": 487.95, "end": 489.43, "word": " فبطل", "probability": 0.89892578125}, {"start": 489.43, "end": 489.57, "word": " ال", "probability": 0.896484375}, {"start": 489.57, "end": 490.03, "word": " resonance", "probability": 0.98046875}, {"start": 490.03, "end": 490.31, "word": " هو", "probability": 0.953125}, {"start": 490.31, "end": 490.91, "word": " السبب", "probability": 0.99072265625}, {"start": 490.91, "end": 491.75, "word": " يعني", "probability": 0.867919921875}, {"start": 491.75, "end": 491.89, "word": " ال", "probability": 0.94873046875}, {"start": 491.89, "end": 492.41, "word": " aromatic", "probability": 0.970703125}, {"start": 492.41, "end": 492.77, "word": " او", "probability": 0.80029296875}, {"start": 492.77, "end": 493.47, "word": " البنزينة", "probability": 0.903125}, {"start": 493.47, 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.. لو بدنا نجيب سؤال arsh is more acidic than aroh due to resonance غلط لأنه هنا فيه resonance و هنا فيه resonance طب هاش المختلف sulfur و oxygen اذا because of the size", "tokens": [6027, 20292, 4724, 1829, 25957, 1211, 30944, 44945, 16606, 15844, 29910, 23275, 45164, 11331, 3215, 4386, 45164, 47525, 8315, 8717, 7435, 1829, 3555, 8608, 33604, 6027, 594, 2716, 307, 544, 39514, 813, 594, 1445, 3462, 281, 30944, 32771, 1211, 9566, 5296, 33456, 3224, 34105, 8978, 3224, 30944, 4032, 34105, 8978, 3224, 30944, 23032, 3555, 8032, 33599, 9673, 46456, 46538, 33831, 4032, 9169, 1975, 15730, 570, 295, 264, 2744], "avg_logprob": -0.2545289785965629, "compression_ratio": 1.4314720812182742, "no_speech_prob": 0.0, "words": [{"start": 499.8, "end": 500.12, "word": "اللي", "probability": 0.859375}, {"start": 500.12, "end": 500.74, "word": " بيعمل", "probability": 0.9769287109375}, {"start": 500.74, "end": 501.4, "word": " resonance", "probability": 0.90380859375}, {"start": 501.4, "end": 502.04, "word": " بناء", "probability": 0.629150390625}, {"start": 502.04, "end": 502.24, "word": " على", "probability": 0.61767578125}, {"start": 502.24, "end": 502.64, "word": " ذلك", "probability": 0.99267578125}, {"start": 502.64, "end": 502.84, "word": " لو", "probability": 0.89501953125}, {"start": 502.84, "end": 503.14, "word": " حد", "probability": 0.47412109375}, {"start": 503.14, "end": 503.18, "word": " ..", "probability": 0.59521484375}, {"start": 503.18, "end": 503.32, "word": " لو", "probability": 0.97705078125}, {"start": 503.32, "end": 503.58, "word": " بدنا", "probability": 0.6802978515625}, {"start": 503.58, "end": 503.76, "word": " نجيب", "probability": 0.9957275390625}, {"start": 503.76, "end": 504.18, "word": " سؤال", "probability": 0.9915364583333334}, {"start": 504.18, "end": 505.24, "word": " arsh", "probability": 0.4432373046875}, {"start": 505.24, "end": 505.5, "word": " is", "probability": 0.94091796875}, {"start": 505.5, "end": 505.9, "word": " more", "probability": 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519.04, "word": " the", "probability": 0.78564453125}, {"start": 519.04, "end": 519.56, "word": " size", "probability": 0.80419921875}], "temperature": 1.0}, {"id": 23, "seek": 54030, "start": 520.37, "end": 540.31, "text": "لكن لو اجيت قلتلكم بدأ اقارن ARSH و RSH، لاحظوا ال sulphur، sulphur the same size، اذا وين صار الفرق؟ AR ولا R؟ اذا why؟ because of resonance", "tokens": [1211, 19452, 45164, 1975, 7435, 36081, 12174, 1211, 2655, 23275, 2304, 47525, 10721, 1975, 4587, 9640, 1863, 8943, 17308, 4032, 497, 17308, 12399, 20193, 5016, 19913, 14407, 2423, 47286, 374, 12399, 47286, 374, 264, 912, 2744, 12399, 1975, 15730, 4032, 9957, 20328, 9640, 27188, 2288, 4587, 22807, 8943, 49429, 497, 22807, 1975, 15730, 983, 22807, 570, 295, 30944], "avg_logprob": -0.3437500040409929, "compression_ratio": 1.251572327044025, "no_speech_prob": 0.0, "words": [{"start": 520.37, "end": 520.97, "word": "لكن", "probability": 0.928466796875}, {"start": 520.97, "end": 521.57, "word": " لو", "probability": 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{"start": 2200.3, "end": 2200.4, "word": " في", "probability": 0.65576171875}, {"start": 2200.4, "end": 2200.7, "word": " النهاية", "probability": 0.91015625}, {"start": 2200.7, "end": 2201.38, "word": " هاجيب", "probability": 0.82080078125}, {"start": 2201.38, "end": 2201.96, "word": " PR", "probability": 0.493896484375}, {"start": 2201.96, "end": 2202.66, "word": " minus", "probability": 0.5068359375}, {"start": 2202.66, "end": 2202.92, "word": " او", "probability": 0.881103515625}, {"start": 2202.92, "end": 2203.14, "word": " I", "probability": 0.9853515625}, {"start": 2203.14, "end": 2203.74, "word": " minus", "probability": 0.97216796875}, {"start": 2203.74, "end": 2204.4, "word": " minus", "probability": 0.361328125}, {"start": 2204.4, "end": 2204.7, "word": " على", "probability": 0.8388671875}, {"start": 2204.7, "end": 2205.08, "word": " minus", "probability": 0.98583984375}, {"start": 2205.08, "end": 2205.62, "word": " بيصير", "probability": 0.8370361328125}, {"start": 2205.62, 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"end": 2239.88, "word": " uneasy", "probability": 0.669921875}, {"start": 2239.88, "end": 2240.32, "word": " manner", "probability": 0.9033203125}, {"start": 2240.32, "end": 2240.82, "word": " مثلا", "probability": 0.97314453125}, {"start": 2240.82, "end": 2241.06, "word": " ولا", "probability": 0.85546875}, {"start": 2241.06, "end": 2242.02, "word": " ..", "probability": 0.72998046875}, {"start": 2242.02, "end": 2242.3, "word": " no", "probability": 0.537109375}, {"start": 2242.3, "end": 2242.54, "word": " they", "probability": 0.74658203125}, {"start": 2242.54, "end": 2243.44, "word": " don't", "probability": 0.97509765625}, {"start": 2243.44, "end": 2244.14, "word": " undergo", "probability": 0.974609375}, {"start": 2244.14, "end": 2246.32, "word": " substitution", "probability": 0.95751953125}], "temperature": 1.0}, {"id": 95, "seek": 227644, "start": 2250.3, "end": 2276.44, "text": "ما هو الـ Electrophilic Substitution بيبطل في هذه الحالة للـ OH بيصير في مكان تاني على البنزينة بيختلف التفاعل يعني زي ما تجيب فينول و بدك تعمل مثلا مع الchlor FeCl3 على سبيل المثال أو تاخد O Methyl بتصير تبدل هنا بتبدل Hydrogens مش بتبدل", "tokens": [15042, 31439, 2423, 39184, 12575, 11741, 388, 299, 42090, 6518, 4724, 1829, 3555, 9566, 1211, 8978, 29538, 21542, 6027, 3660, 24976, 39184, 13931, 4724, 1829, 9381, 13546, 8978, 3714, 41361, 6055, 7649, 1829, 15844, 29739, 1863, 11622, 9957, 3660, 4724, 1829, 46456, 46538, 16712, 5172, 995, 30241, 37495, 22653, 30767, 1829, 19446, 6055, 7435, 1829, 3555, 8978, 1863, 12610, 4032, 47525, 4117, 6055, 25957, 1211, 50113, 15040, 20449, 2423, 11439, 284, 3697, 9966, 18, 15844, 8608, 21292, 1211, 9673, 12984, 6027, 34051, 6055, 47283, 3215, 422, 48602, 5088, 39894, 9381, 13546, 6055, 44510, 1211, 34105, 39894, 44510, 1211, 24231, 6675, 694, 37893, 39894, 44510, 1211], "avg_logprob": -0.20120872641509435, "compression_ratio": 1.5406504065040652, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2250.3, "end": 2250.54, "word": 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oxidation خليني اقول ايش معنى ال oxidation", "tokens": [9566, 3555, 3615, 995, 9673, 8592, 28820, 3660, 16472, 27188, 9957, 12610, 8717, 36178, 3224, 45030, 9640, 11242, 20449, 2423, 479, 8140, 2423, 9307, 1863, 9957, 1975, 5172, 2655, 43042, 1975, 2407, 50113, 1211, 50113, 15040, 39894, 44510, 20292, 8592, 2423, 1975, 2407, 50113, 1211, 39894, 44510, 20292, 1975, 1829, 8592, 39894, 44510, 20292, 15844, 21542, 1211, 28671, 8032, 25708, 2288, 29245, 1829, 8315, 2655, 39894, 44510, 20292, 8032, 25708, 2288, 29245, 1829, 8315, 2655, 15844, 21542, 1211, 28671, 2423, 7649, 2423, 7658, 9154, 6055, 5172, 995, 30241, 9307, 11296, 25124, 3224, 48923, 6055, 5172, 995, 30241, 2423, 36767, 16490, 1211, 9957, 1829, 1975, 39648, 1975, 1829, 8592, 20449, 1863, 7578, 2423, 36767], "avg_logprob": -0.18873355106303566, "compression_ratio": 2.0386473429951693, "no_speech_prob": 0.0, "words": [{"start": 2277.36, "end": 2277.88, "word": "طبعا", "probability": 0.8502197265625}, {"start": 2277.88, "end": 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خلّينا نكون في البداية فاهمين قصة الأكسدة الأكسدة معناها ان ال COH بيصير C double bond O طالما C double bond O صارت اذا صارت الجهاي او كيتون هتفقد ال H تعطي ال OH OH عن الكربون اللي هنا اول سؤال هيجيكم طب يا ترى لو فيش هنا H", "tokens": [3555, 995, 34268, 2304, 3215, 15844, 8032, 3215, 12610, 9673, 7435, 2304, 2407, 34268, 9957, 16490, 1211, 11703, 9957, 995, 8717, 30544, 8978, 29739, 28259, 10632, 6156, 995, 16095, 9957, 12174, 9381, 3660, 16247, 4117, 3794, 41891, 16247, 4117, 3794, 41891, 20449, 8315, 11296, 16472, 2423, 383, 31187, 4724, 1829, 9381, 13546, 383, 3834, 6086, 422, 23032, 6027, 15042, 383, 3834, 6086, 422, 20328, 9640, 2655, 1975, 15730, 20328, 9640, 2655, 25724, 3224, 47302, 1975, 2407, 9122, 36081, 11536, 8032, 2655, 5172, 28543, 2423, 389, 37279, 9566, 1829, 2423, 13931, 13931, 18871, 33251, 25513, 11536, 13672, 1829, 34105, 1975, 12610, 8608, 33604, 6027, 39896, 7435, 1829, 24793, 23032, 3555, 35186, 6055, 2288, 7578, 45164, 8978, 8592, 34105, 389], "avg_logprob": 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"end": 2361.59, "word": " C", "probability": 0.72119140625}, {"start": 2361.59, "end": 2361.77, "word": " double", "probability": 0.8173828125}, {"start": 2361.77, "end": 2362.09, "word": " bond", "probability": 0.96923828125}, {"start": 2362.09, "end": 2362.25, "word": " O", "probability": 0.92431640625}, {"start": 2362.25, "end": 2362.77, "word": " صارت", "probability": 0.9015299479166666}, {"start": 2362.77, "end": 2362.95, "word": " اذا", "probability": 0.6683349609375}, {"start": 2362.95, "end": 2363.39, "word": " صارت", "probability": 0.82763671875}, {"start": 2363.39, "end": 2364.09, "word": " الجهاي", "probability": 0.4748738606770833}, {"start": 2364.09, "end": 2365.45, "word": " او", "probability": 0.77880859375}, {"start": 2365.45, "end": 2365.95, "word": " كيتون", "probability": 0.9376627604166666}, {"start": 2365.95, "end": 2367.01, "word": " هتفقد", "probability": 0.903564453125}, {"start": 2367.01, "end": 2367.23, "word": " ال", "probability": 0.9208984375}, {"start": 2367.23, "end": 2367.47, "word": " H", "probability": 0.8681640625}, {"start": 2367.47, "end": 2367.81, "word": " تعطي", "probability": 0.8717447916666666}, {"start": 2367.81, "end": 2367.93, "word": " ال", "probability": 0.966796875}, {"start": 2367.93, "end": 2368.35, "word": " OH", "probability": 0.75341796875}, {"start": 2368.35, "end": 2368.71, "word": " OH", "probability": 0.26171875}, {"start": 2368.71, "end": 2369.09, "word": " عن", "probability": 0.974609375}, {"start": 2369.09, "end": 2369.69, "word": " الكربون", "probability": 0.7747395833333334}, {"start": 2369.69, "end": 2369.87, "word": " اللي", "probability": 0.874267578125}, {"start": 2369.87, "end": 2370.15, "word": " هنا", "probability": 0.5751953125}, {"start": 2370.15, "end": 2370.91, "word": " اول", "probability": 0.786376953125}, {"start": 2370.91, "end": 2371.33, "word": " سؤال", "probability": 0.9947916666666666}, {"start": 2371.33, "end": 2372.31, "word": " هيجيكم", "probability": 0.8743896484375}, {"start": 2372.31, "end": 2373.01, "word": " طب", "probability": 0.750244140625}, {"start": 2373.01, "end": 2373.25, "word": " يا", "probability": 0.9580078125}, {"start": 2373.25, "end": 2373.93, "word": " ترى", "probability": 0.8291015625}, {"start": 2373.93, "end": 2374.85, "word": " لو", "probability": 0.96142578125}, {"start": 2374.85, "end": 2375.15, "word": " فيش", "probability": 0.688720703125}, {"start": 2375.15, "end": 2375.41, "word": " هنا", "probability": 0.364013671875}, {"start": 2375.41, "end": 2375.79, "word": " H", "probability": 0.80859375}], "temperature": 1.0}, {"id": 100, "seek": 240036, "start": 2378.56, "end": 2400.36, "text": "يعني لو هذه كانت R و R و R فى عندي OH مستعدة تفقد ال H بس فىش هنا H يعني صار إيش نوع ال alcohol? tertiary واضحة؟ يعني افترضوا هذه كانت C وهذه C وهذه C CH3 CH3 CH3 هنا فى H هنا مافيش H", "tokens": [40228, 22653, 45164, 29538, 25961, 2655, 497, 4032, 497, 4032, 497, 6156, 7578, 18871, 16254, 13931, 3714, 14851, 22488, 3660, 6055, 5172, 28543, 2423, 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0.5703125}, {"start": 2394.12, "end": 2394.58, "word": " كانت", "probability": 0.98583984375}, {"start": 2394.58, "end": 2394.9, "word": " C", "probability": 0.9892578125}, {"start": 2394.9, "end": 2395.58, "word": " وهذه", "probability": 0.6287841796875}, {"start": 2395.58, "end": 2395.8, "word": " C", "probability": 0.9599609375}, {"start": 2395.8, "end": 2396.16, "word": " وهذه", "probability": 0.88134765625}, {"start": 2396.16, "end": 2396.36, "word": " C", "probability": 0.97509765625}, {"start": 2396.36, "end": 2397.02, "word": " CH3", "probability": 0.44879150390625}, {"start": 2397.02, "end": 2397.64, "word": " CH3", "probability": 0.931640625}, {"start": 2397.64, "end": 2398.36, "word": " CH3", "probability": 0.94482421875}, {"start": 2398.36, "end": 2398.92, "word": " هنا", "probability": 0.72802734375}, {"start": 2398.92, "end": 2399.18, "word": " فى", "probability": 0.85546875}, {"start": 2399.18, "end": 2399.44, "word": " H", "probability": 0.9794921875}, {"start": 2399.44, "end": 2399.66, "word": " هنا", "probability": 0.744140625}, {"start": 2399.66, "end": 2400.04, "word": " مافيش", "probability": 0.82861328125}, {"start": 2400.04, "end": 2400.36, "word": " H", "probability": 0.98828125}], "temperature": 1.0}, {"id": 101, "seek": 242785, "start": 2401.77, "end": 2427.85, "text": "بدوا يتم الأكسدة؟ إذا على طول هنطلع قاعدة أن الـ tertiary alcohols اللي مافيش عليهم هيدروجينة هنا بتأكسدوش إذا التأكسد خاص بماذا؟ ال primary و ال secondary التيرتشاري مابصله أكسدة ليش؟ لأن الأكسد بدأ أفقد من ال OH هيدروجينة و من الكربون اللي حامله هيدروجينة طب الكربون اللي حامله مش حامله هيدروجينة", "tokens": [44510, 14407, 7251, 39237, 16247, 4117, 3794, 41891, 22807, 11933, 15730, 15844, 23032, 12610, 8032, 1863, 9566, 1211, 3615, 12174, 995, 22488, 3660, 14739, 2423, 39184, 38726, 29104, 7658, 82, 13672, 1829, 19446, 41185, 8592, 25894, 16095, 8032, 25708, 2288, 29245, 9957, 3660, 34105, 39894, 10721, 4117, 3794, 3215, 2407, 8592, 11933, 15730, 16712, 10721, 4117, 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0.68017578125}, {"start": 2404.01, "end": 2404.23, "word": " على", "probability": 0.425537109375}, {"start": 2404.23, "end": 2404.43, "word": " طول", "probability": 0.9716796875}, {"start": 2404.43, "end": 2404.95, "word": " هنطلع", "probability": 0.8826171875}, {"start": 2404.95, "end": 2405.61, "word": " قاعدة", "probability": 0.9774169921875}, {"start": 2405.61, "end": 2406.09, "word": " أن", "probability": 0.34521484375}, {"start": 2406.09, "end": 2406.63, "word": " الـ", "probability": 0.4345703125}, {"start": 2406.63, "end": 2407.27, "word": " tertiary", "probability": 0.7734375}, {"start": 2407.27, "end": 2408.21, "word": " alcohols", "probability": 0.802490234375}, {"start": 2408.21, "end": 2408.55, "word": " اللي", "probability": 0.9052734375}, {"start": 2408.55, "end": 2408.91, "word": " مافيش", "probability": 0.9269205729166666}, {"start": 2408.91, "end": 2409.25, "word": " عليهم", "probability": 0.94677734375}, {"start": 2409.25, "end": 2409.91, "word": " هيدروجينة", "probability": 0.9031575520833334}, {"start": 2409.91, "end": 2410.05, "word": " هنا", "probability": 0.6103515625}, {"start": 2410.05, "end": 2411.07, "word": " بتأكسدوش", "probability": 0.8785574776785714}, {"start": 2411.07, "end": 2411.81, "word": " إذا", "probability": 0.797607421875}, {"start": 2411.81, "end": 2412.49, "word": " التأكسد", "probability": 0.97099609375}, {"start": 2412.49, "end": 2412.83, "word": " خاص", "probability": 0.986328125}, {"start": 2412.83, "end": 2414.03, "word": " بماذا؟", "probability": 0.90615234375}, {"start": 2414.03, "end": 2414.73, "word": " ال", "probability": 0.88623046875}, {"start": 2414.73, "end": 2415.43, "word": " primary", "probability": 0.80029296875}, {"start": 2415.43, "end": 2416.43, "word": " و", "probability": 0.348876953125}, {"start": 2416.43, "end": 2416.59, "word": " ال", "probability": 0.7822265625}, {"start": 2416.59, "end": 2417.15, "word": " secondary", "probability": 0.96142578125}, {"start": 2417.15, "end": 2418.73, "word": " التيرتشاري", "probability": 0.7449951171875}, {"start": 2418.73, "end": 2419.29, "word": " مابصله", "probability": 0.59210205078125}, {"start": 2419.29, "end": 2419.79, "word": " أكسدة", "probability": 0.97265625}, {"start": 2419.79, "end": 2420.69, "word": " ليش؟", "probability": 0.8333333333333334}, {"start": 2420.69, "end": 2420.87, "word": " لأن", "probability": 0.87939453125}, {"start": 2420.87, "end": 2421.41, "word": " الأكسد", "probability": 0.9454345703125}, {"start": 2421.41, "end": 2421.69, "word": " بدأ", "probability": 0.6500244140625}, {"start": 2421.69, "end": 2422.09, "word": " أفقد", "probability": 0.8771158854166666}, {"start": 2422.09, "end": 2422.41, "word": " من", "probability": 0.994140625}, {"start": 2422.41, "end": 2422.55, "word": " ال", "probability": 0.93701171875}, {"start": 2422.55, "end": 2422.91, "word": " OH", "probability": 0.354736328125}, {"start": 2422.91, "end": 2423.83, "word": " هيدروجينة", "probability": 0.9423828125}, {"start": 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64.41, "word": " أنه", "probability": 0.65673828125}, {"start": 64.41, "end": 64.51, "word": " في", "probability": 0.86474609375}, {"start": 64.51, "end": 64.97, "word": " أشياء", "probability": 0.9703369140625}, {"start": 64.97, "end": 66.03, "word": " متخصصة", "probability": 0.9935546875}, {"start": 66.03, "end": 66.29, "word": " لكن", "probability": 0.85693359375}, {"start": 66.29, "end": 66.79, "word": " دائما", "probability": 0.9373372395833334}, {"start": 66.79, "end": 67.39, "word": " الطالب", "probability": 0.990234375}, {"start": 67.39, "end": 68.05, "word": " أول", "probability": 0.823486328125}, {"start": 68.05, "end": 68.29, "word": " شيء", "probability": 0.68994140625}, {"start": 68.29, "end": 68.59, "word": " يجب", "probability": 0.98681640625}, {"start": 68.59, "end": 68.75, "word": " أن", "probability": 0.7099609375}, {"start": 68.75, "end": 68.99, "word": " يكون", "probability": 0.924560546875}, {"start": 68.99, "end": 69.39, "word": " عنده", "probability": 0.9443359375}, {"start": 69.39, "end": 69.73, "word": " يعني", "probability": 0.7210693359375}, {"start": 69.73, "end": 70.15, "word": " قناع", "probability": 0.7500813802083334}, {"start": 70.15, "end": 70.27, "word": " أن", "probability": 0.75341796875}, {"start": 70.27, "end": 70.43, "word": " هو", "probability": 0.7236328125}, {"start": 70.43, "end": 70.87, "word": " فاهم", "probability": 0.9871419270833334}, {"start": 70.87, "end": 71.43, "word": " الاشي", "probability": 0.65087890625}, {"start": 71.43, "end": 72.33, "word": " الأفكار", "probability": 0.9637451171875}, {"start": 72.33, "end": 72.75, "word": " العامة", "probability": 0.9938151041666666}, {"start": 72.75, "end": 73.35, "word": " ولذلك", "probability": 0.9070638020833334}, {"start": 73.35, "end": 74.19, "word": " ربما", "probability": 0.9886067708333334}, {"start": 74.19, "end": 74.77, "word": " تلاحظوا", "probability": 0.9685546875}, {"start": 74.77, "end": 75.35, "word": " أنه", "probability": 0.863037109375}, {"start": 75.35, "end": 75.85, "word": " يعني", "probability": 0.980712890625}, {"start": 75.85, "end": 76.55, "word": " لو", "probability": 0.97265625}, {"start": 76.55, "end": 76.73, "word": " أنا", "probability": 0.720703125}, {"start": 76.73, "end": 76.97, "word": " بدأ", "probability": 0.7269287109375}, {"start": 76.97, "end": 77.65, "word": " أصنف", "probability": 0.954345703125}, {"start": 77.65, "end": 78.49, "word": " الأسئلة", "probability": 0.995849609375}, {"start": 78.49, "end": 78.71, "word": " مش", "probability": 0.9150390625}, {"start": 78.71, "end": 78.89, "word": " في", "probability": 0.94287109375}, {"start": 78.89, "end": 79.11, "word": " هذا", "probability": 0.95947265625}, {"start": 79.11, "end": 79.75, "word": " الامتحان", "probability": 0.962109375}, {"start": 79.75, "end": 80.17, "word": " في", "probability": 0.82373046875}, {"start": 80.17, "end": 80.63, "word": " معظم", "probability": 0.9871419270833334}, {"start": 80.63, "end": 81.65, "word": " الامتحانات", "probability": 0.9720865885416666}, {"start": 81.65, "end": 82.85, "word": " هنكتشف", "probability": 0.947265625}, {"start": 82.85, "end": 83.39, "word": " أنه", "probability": 0.833740234375}, {"start": 83.39, "end": 83.75, "word": " هي", "probability": 0.89453125}, {"start": 83.75, "end": 84.45, "word": " عنوين", "probability": 0.9423828125}], "temperature": 1.0}, {"id": 4, "seek": 11295, "start": 85.47, "end": 112.95, "text": "يعني هي عنوين لأشياء احنا درسناها خلينا نشوف هذا الكلام من خلال التطبيق الآن في هذا الامتحان اللي أمامنا في عندنا مجموعة من الجمال هذه المجموعة من الجمال بدنا نكمل الفراغ فيها complete the following السؤال أول مثلا بيسألنا الدياستيريو مارزهاف و بيحكي عن ال physical properties", "tokens": [40228, 22653, 39896, 18871, 2407, 9957, 5296, 10721, 8592, 1829, 16606, 1975, 5016, 8315, 11778, 2288, 3794, 8315, 11296, 16490, 1211, 9957, 995, 8717, 8592, 38688, 23758, 2423, 28820, 10943, 9154, 16490, 1211, 6027, 16712, 9566, 21292, 4587, 6024, 48506, 8978, 23758, 2423, 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0.8640950520833334}, {"start": 87.55, "end": 88.31, "word": " درسناها", "probability": 0.96259765625}, {"start": 88.31, "end": 89.49, "word": " خلينا", "probability": 0.8192138671875}, {"start": 89.49, "end": 90.03, "word": " نشوف", "probability": 0.99169921875}, {"start": 90.03, "end": 90.25, "word": " هذا", "probability": 0.97265625}, {"start": 90.25, "end": 90.73, "word": " الكلام", "probability": 0.9615885416666666}, {"start": 90.73, "end": 90.87, "word": " من", "probability": 0.9970703125}, {"start": 90.87, "end": 91.39, "word": " خلال", "probability": 0.9947916666666666}, {"start": 91.39, "end": 92.35, "word": " التطبيق", "probability": 0.980224609375}, {"start": 92.35, "end": 93.45, "word": " الآن", "probability": 0.6680908203125}, {"start": 93.45, "end": 94.47, "word": " في", "probability": 0.921875}, {"start": 94.47, "end": 94.79, "word": " هذا", "probability": 0.95556640625}, {"start": 94.79, "end": 95.51, "word": " الامتحان", "probability": 0.97373046875}, {"start": 95.51, "end": 95.71, "word": " اللي", "probability": 0.93798828125}, {"start": 95.71, "end": 96.43, "word": " أمامنا", "probability": 0.9483642578125}, {"start": 96.43, "end": 97.25, "word": " في", "probability": 0.57861328125}, {"start": 97.25, "end": 97.67, "word": " عندنا", "probability": 0.959716796875}, {"start": 97.67, "end": 98.33, "word": " مجموعة", "probability": 0.9568359375}, {"start": 98.33, "end": 98.69, "word": " من", "probability": 0.9892578125}, {"start": 98.69, "end": 99.83, "word": " الجمال", "probability": 0.7607421875}, {"start": 99.83, "end": 100.61, "word": " هذه", "probability": 0.65234375}, {"start": 100.61, "end": 101.19, "word": " المجموعة", "probability": 0.89345703125}, {"start": 101.19, "end": 101.35, "word": " من", "probability": 0.984375}, {"start": 101.35, "end": 101.87, "word": " الجمال", "probability": 0.9088541666666666}, {"start": 101.87, "end": 102.33, "word": " بدنا", "probability": 0.9365234375}, {"start": 102.33, "end": 103.05, "word": " نكمل", "probability": 0.9957682291666666}, {"start": 103.05, "end": 103.71, "word": " الفراغ", "probability": 0.985107421875}, {"start": 103.71, "end": 104.27, "word": " فيها", "probability": 0.9931640625}, {"start": 104.27, "end": 105.67, "word": " complete", "probability": 0.546875}, {"start": 105.67, "end": 106.45, "word": " the", "probability": 0.9130859375}, {"start": 106.45, "end": 107.15, "word": " following", "probability": 0.900390625}, {"start": 107.15, "end": 108.65, "word": " السؤال", "probability": 0.9835611979166666}, {"start": 108.65, "end": 108.91, "word": " أول", "probability": 0.806396484375}, {"start": 108.91, "end": 109.21, "word": " مثلا", "probability": 0.9794921875}, {"start": 109.21, "end": 109.67, "word": " بيسألنا", "probability": 0.956298828125}, {"start": 109.67, "end": 110.45, "word": " الدياستيريو", "probability": 0.7172502790178571}, {"start": 110.45, "end": 111.23, "word": " مارزهاف", "probability": 0.6673828125}, {"start": 111.23, "end": 111.41, "word": " و", "probability": 0.56201171875}, {"start": 111.41, "end": 111.73, "word": " بيحكي", "probability": 0.857958984375}, {"start": 111.73, "end": 111.87, "word": " عن", "probability": 0.98828125}, {"start": 111.87, "end": 111.97, "word": " ال", "probability": 0.935546875}, {"start": 111.97, "end": 112.29, "word": " physical", "probability": 0.8466796875}, {"start": 112.29, "end": 112.95, "word": " properties", "probability": 0.143798828125}], "temperature": 1.0}, {"id": 5, "seek": 14309, "start": 114.07, "end": 143.09, "text": "الان كان واضح تماما ان ال بيستيريو مارز هيف different physical properties واضح الان السؤال التاني addition of HBr H plus to isobutene produces لاحظوا هنا السؤال هذا في فكرتين ان الطالب لازم في الأول يعرف ايش هو ال isobutene", "tokens": [6027, 7649, 25961, 4032, 46958, 5016, 46811, 10943, 995, 16472, 2423, 4724, 1829, 14851, 13546, 1829, 2407, 3714, 9640, 11622, 8032, 33911, 819, 4001, 7221, 4032, 46958, 5016, 2423, 7649, 21136, 33604, 6027, 16712, 7649, 1829, 4500, 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"word": " مارز", "probability": 0.806640625}, {"start": 117.33, "end": 117.91, "word": " هيف", "probability": 0.16851806640625}, {"start": 117.91, "end": 118.97, "word": " different", "probability": 0.318359375}, {"start": 118.97, "end": 122.39, "word": " physical", "probability": 0.38134765625}, {"start": 122.39, "end": 123.07, "word": " properties", "probability": 0.81689453125}, {"start": 123.07, "end": 124.43, "word": " واضح", "probability": 0.7909342447916666}, {"start": 124.43, "end": 127.39, "word": " الان", "probability": 0.6256103515625}, {"start": 127.39, "end": 128.23, "word": " السؤال", "probability": 0.9890950520833334}, {"start": 128.23, "end": 128.77, "word": " التاني", "probability": 0.9269205729166666}, {"start": 128.77, "end": 129.21, "word": " addition", "probability": 0.60009765625}, {"start": 129.21, "end": 129.55, "word": " of", "probability": 0.9794921875}, {"start": 129.55, "end": 130.67, "word": " HBr", "probability": 0.5208740234375}, {"start": 130.67, "end": 131.27, "word": " H", "probability": 0.398193359375}, {"start": 131.27, "end": 131.83, "word": " plus", "probability": 0.1407470703125}, {"start": 131.83, "end": 132.11, "word": " to", "probability": 0.8505859375}, {"start": 132.11, "end": 133.33, "word": " isobutene", "probability": 0.75128173828125}, {"start": 133.33, "end": 134.39, "word": " produces", "probability": 0.92919921875}, {"start": 134.39, "end": 135.69, "word": " لاحظوا", "probability": 0.95068359375}, {"start": 135.69, "end": 136.03, "word": " هنا", "probability": 0.97265625}, {"start": 136.03, "end": 137.11, "word": " السؤال", "probability": 0.9851888020833334}, {"start": 137.11, "end": 137.41, "word": " هذا", "probability": 0.90185546875}, {"start": 137.41, "end": 137.85, "word": " في", "probability": 0.90673828125}, {"start": 137.85, "end": 138.59, "word": " فكرتين", "probability": 0.8720703125}, {"start": 138.59, "end": 138.83, "word": " ان", "probability": 0.6201171875}, {"start": 138.83, "end": 139.31, "word": " الطالب", "probability": 0.9853515625}, {"start": 139.31, "end": 139.67, "word": " لازم", "probability": 0.94873046875}, {"start": 139.67, "end": 139.79, "word": " في", "probability": 0.89794921875}, {"start": 139.79, "end": 140.09, "word": " الأول", "probability": 0.8466796875}, {"start": 140.09, "end": 140.85, "word": " يعرف", "probability": 0.770263671875}, {"start": 140.85, "end": 141.37, "word": " ايش", "probability": 0.7532552083333334}, {"start": 141.37, "end": 141.73, "word": " هو", "probability": 0.93310546875}, {"start": 141.73, "end": 142.07, "word": " ال", "probability": 0.79150390625}, {"start": 142.07, "end": 143.09, "word": " isobutene", "probability": 0.9185791015625}], "temperature": 1.0}, {"id": 6, "seek": 16407, "start": 144.57, "end": 164.07, "text": "هذا ال isobutene واضح بعد هيك إضافة ال HBR H plus معناه ذلك هذه إضافة حسب Markov-Nikov addition يعني هذه بدها تروح يجي عند هنا H و يجي عند هنا CL او PR و بنحكي عن PR", "tokens": [3224, 15730, 2423, 307, 996, 325, 1450, 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"word": " تلاتة", "probability": 0.971923828125}, {"start": 738.81, "end": 739.45, "word": " اربعة", "probability": 0.9485677083333334}, {"start": 739.45, "end": 740.61, "word": " على", "probability": 0.705078125}, {"start": 740.61, "end": 740.95, "word": " نمرة", "probability": 0.7752278645833334}, {"start": 740.95, "end": 741.39, "word": " واحد", "probability": 0.9912109375}, {"start": 741.39, "end": 742.03, "word": " اكلور", "probability": 0.6166178385416666}, {"start": 742.03, "end": 742.57, "word": " وعلى", "probability": 0.90576171875}, {"start": 742.57, "end": 742.93, "word": " نمرة", "probability": 0.94921875}, {"start": 742.93, "end": 743.97, "word": " تلاتة", "probability": 0.969482421875}, {"start": 743.97, "end": 744.63, "word": " فنل", "probability": 0.7361653645833334}, {"start": 744.63, "end": 746.87, "word": " والترقيم", "probability": 0.8038330078125}, {"start": 746.87, "end": 747.17, "word": " منها", "probability": 0.980224609375}, {"start": 747.17, "end": 747.43, "word": " لان", "probability": 0.6712646484375}, {"start": 747.43, "end": 747.63, "word": " لو", "probability": 0.8984375}, {"start": 747.63, "end": 748.09, "word": " رقمتي", "probability": 0.8365478515625}, {"start": 748.09, "end": 748.29, "word": " منها", "probability": 0.96875}, {"start": 748.29, "end": 748.73, "word": " هيصيروا", "probability": 0.731201171875}, {"start": 748.73, "end": 748.85, "word": " على", "probability": 0.353271484375}, {"start": 748.85, "end": 749.11, "word": " اتنين", "probability": 0.978759765625}, {"start": 749.11, "end": 749.77, "word": " واربعة", "probability": 0.900390625}, {"start": 749.77, "end": 750.51, "word": " بدي", "probability": 0.6087646484375}, {"start": 750.51, "end": 750.59, "word": " ال", "probability": 0.63720703125}, {"start": 750.59, "end": 750.97, "word": " lower", "probability": 0.57666015625}, {"start": 750.97, "end": 751.95, "word": " numbering", "probability": 0.917236328125}, {"start": 751.95, "end": 752.47, "word": " اذا", "probability": 0.876220703125}, {"start": 752.47, "end": 752.97, "word": " هذا", "probability": 0.97607421875}], "temperature": 1.0}, {"id": 31, "seek": 77883, "start": 753.65, "end": 778.83, "text": "one chloro three phenyl بيوتين الان في chiral center ال chiral center هنا ال H أقل مجموعة أكيد البنزينة نمرة واحد الكاربون هذه نمرة اتنين وال CH3 نمرة تلاتة", "tokens": [546, 18178, 78, 1045, 7279, 5088, 4724, 1829, 35473, 9957, 2423, 7649, 8978, 23782, 304, 3056, 2423, 23782, 304, 3056, 34105, 2423, 389, 5551, 4587, 1211, 3714, 7435, 2304, 2407, 27884, 5551, 4117, 25708, 29739, 1863, 11622, 9957, 3660, 8717, 2304, 25720, 36764, 24401, 33251, 9640, 3555, 11536, 29538, 8717, 2304, 25720, 1975, 2655, 1863, 9957, 16070, 5995, 18, 8717, 2304, 25720, 6055, 1211, 9307, 3660], "avg_logprob": -0.20872201403575158, "compression_ratio": 1.4390243902439024, "no_speech_prob": 0.0, "words": [{"start": 753.65, "end": 754.07, "word": "one", "probability": 0.796875}, {"start": 754.07, "end": 755.51, "word": " chloro", "probability": 0.4886474609375}, {"start": 755.51, "end": 758.51, "word": " three", "probability": 0.7939453125}, {"start": 758.51, "end": 760.83, "word": " phenyl", "probability": 0.808837890625}, {"start": 760.83, "end": 762.95, "word": " بيوتين", "probability": 0.7935791015625}, {"start": 762.95, "end": 764.15, "word": " الان", "probability": 0.6888427734375}, {"start": 764.15, "end": 764.49, "word": " في", "probability": 0.95703125}, {"start": 764.49, "end": 765.09, "word": " chiral", "probability": 0.6055908203125}, {"start": 765.09, "end": 765.63, "word": " center", "probability": 0.8720703125}, {"start": 765.63, "end": 766.87, "word": " ال", "probability": 0.4013671875}, {"start": 766.87, "end": 767.33, "word": " chiral", "probability": 0.904541015625}, {"start": 767.33, "end": 767.69, "word": " center", "probability": 0.96728515625}, {"start": 767.69, "end": 768.09, "word": " هنا", "probability": 0.87744140625}, {"start": 768.09, "end": 768.75, "word": " ال", "probability": 0.9345703125}, {"start": 768.75, "end": 769.19, "word": " H", "probability": 0.87060546875}, {"start": 769.19, "end": 770.19, "word": " أقل", "probability": 0.9290364583333334}, {"start": 770.19, "end": 771.23, "word": " مجموعة", "probability": 0.95126953125}, {"start": 771.23, "end": 771.77, "word": " أكيد", "probability": 0.814208984375}, {"start": 771.77, "end": 772.57, "word": " البنزينة", "probability": 0.93720703125}, {"start": 772.57, "end": 772.85, "word": " نمرة", "probability": 0.7630208333333334}, {"start": 772.85, "end": 773.37, "word": " واحد", "probability": 0.989501953125}, {"start": 773.37, "end": 774.15, "word": " الكاربون", "probability": 0.8902587890625}, {"start": 774.15, "end": 774.65, "word": " هذه", "probability": 0.5029296875}, {"start": 774.65, "end": 775.89, "word": " نمرة", "probability": 0.9339192708333334}, {"start": 775.89, "end": 776.45, "word": " اتنين", "probability": 0.9635009765625}, {"start": 776.45, "end": 777.09, "word": " وال", 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ولا ال alcohol؟ ال ketone، الآن هذا المُركّب إيش اسمه؟ أسيتوفينون، نكتب small letter", "tokens": [45340, 10859, 31747, 11703, 3555, 13672, 1829, 39182, 3224, 45831, 8978, 3224, 3714, 7435, 2304, 45367, 2655, 9957, 12399, 20449, 8315, 29910, 23275, 21136, 33604, 6027, 36145, 3224, 3714, 9957, 5551, 3615, 23942, 8978, 16247, 12610, 2407, 10632, 6225, 8592, 7649, 5551, 38251, 3224, 11933, 1829, 3224, 22807, 2423, 14979, 546, 49429, 2423, 7658, 22807, 2423, 14979, 546, 12399, 6024, 48506, 23758, 9673, 10859, 31747, 11703, 3555, 11933, 1829, 8592, 24525, 2304, 3224, 22807, 5551, 3794, 36081, 38688, 9957, 11536, 12399, 8717, 4117, 2655, 3555, 1359, 5063], "avg_logprob": -0.2283380734310909, "compression_ratio": 1.5858585858585859, "no_speech_prob": 0.0, "words": [{"start": 795.3, "end": 796.06, "word": "المُركّب", "probability": 0.7750244140625}, {"start": 796.06, "end": 796.28, "word": " اللي", "probability": 0.8466796875}, {"start": 796.28, "end": 796.82, "word": " بعده", "probability": 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{"start": 803.04, "end": 803.56, "word": " أسمه", "probability": 0.6729736328125}, {"start": 803.56, "end": 803.82, "word": " إيه؟", "probability": 0.68682861328125}, {"start": 803.82, "end": 804.02, "word": " ال", "probability": 0.85595703125}, {"start": 804.02, "end": 804.64, "word": " ketone", "probability": 0.493316650390625}, {"start": 804.64, "end": 804.94, "word": " ولا", "probability": 0.8525390625}, {"start": 804.94, "end": 805.12, "word": " ال", "probability": 0.8720703125}, {"start": 805.12, "end": 806.28, "word": " alcohol؟", "probability": 0.66845703125}, {"start": 806.28, "end": 806.4, "word": " ال", "probability": 0.93212890625}, {"start": 806.4, "end": 806.96, "word": " ketone،", "probability": 0.7674153645833334}, {"start": 806.96, "end": 807.2, "word": " الآن", "probability": 0.8291015625}, {"start": 807.2, "end": 807.6, "word": " هذا", "probability": 0.95947265625}, {"start": 807.6, "end": 808.26, "word": " المُركّب", "probability": 0.9857421875}, {"start": 808.26, 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{"start": 817.05, "end": 817.21, "word": " على", "probability": 0.5302734375}, {"start": 817.21, "end": 817.79, "word": " أصلها", "probability": 0.9375}, {"start": 817.79, "end": 818.87, "word": " ال", "probability": 0.2374267578125}, {"start": 818.87, "end": 819.17, "word": " three", "probability": 0.51806640625}, {"start": 819.17, "end": 820.03, "word": " one", "probability": 0.595703125}, {"start": 820.03, "end": 820.37, "word": " two", "probability": 0.86572265625}, {"start": 820.37, "end": 820.93, "word": " three", "probability": 0.94580078125}, {"start": 820.93, "end": 821.21, "word": " ال", "probability": 0.5361328125}, {"start": 821.21, "end": 821.41, "word": " three", "probability": 0.896484375}, {"start": 821.41, "end": 821.67, "word": " أو", "probability": 0.603515625}, {"start": 821.67, "end": 822.31, "word": " ميتا", "probability": 0.75634765625}, {"start": 822.31, "end": 823.87, "word": " هيدروكسي", "probability": 0.7496337890625}, {"start": 823.87, "end": 824.47, "word": " الشغلتين", "probability": 0.92490234375}, {"start": 824.47, "end": 824.85, "word": " صح", "probability": 0.98095703125}, {"start": 824.85, "end": 825.71, "word": " ال", "probability": 0.93212890625}, {"start": 825.71, "end": 825.91, "word": " three", "probability": 0.931640625}, {"start": 825.91, "end": 826.57, "word": " هيدروكسي", "probability": 0.9275716145833334}, {"start": 826.57, "end": 827.35, "word": " أسيتوفينون", "probability": 0.7801920572916666}, {"start": 827.35, "end": 827.73, "word": " كلمة", "probability": 0.8232421875}, {"start": 827.73, "end": 828.75, "word": " واحدة", "probability": 0.9873046875}, {"start": 828.75, "end": 829.73, "word": " واضح", "probability": 0.96826171875}, {"start": 829.73, "end": 830.33, "word": " ال", "probability": 0.314453125}, {"start": 830.33, "end": 830.47, "word": " three", "probability": 0.91943359375}, {"start": 830.47, "end": 831.17, "word": " هيدروكسي", "probability": 0.9423828125}, {"start": 831.17, "end": 833.05, "word": " أسيتوفينون", "probability": 0.935302734375}, {"start": 833.05, "end": 834.51, "word": " بتيعني", "probability": 0.6443684895833334}, {"start": 834.51, "end": 834.97, "word": " كل", "probability": 0.966796875}, {"start": 834.97, "end": 835.37, "word": " هذه", "probability": 0.91796875}, {"start": 835.37, "end": 836.05, "word": " من", "probability": 0.99365234375}, {"start": 836.05, "end": 836.35, "word": " ضمن", "probability": 0.98291015625}, {"start": 836.35, "end": 837.03, "word": " الأفكار", "probability": 0.987060546875}, {"start": 837.03, "end": 837.93, "word": " العامة", "probability": 0.9959309895833334}, {"start": 837.93, "end": 839.61, "word": " الأساسية", "probability": 0.970947265625}, {"start": 839.61, "end": 839.97, "word": " اللي", "probability": 0.88232421875}, {"start": 839.97, "end": 840.29, "word": " احنا", "probability": 0.8986002604166666}, {"start": 840.29, "end": 841.61, "word": " درسناكم", "probability": 0.94267578125}], "temperature": 1.0}, {"id": 35, "seek": 88296, "start": 858.38, "end": 882.96, "text": "الان بعد ذلك عندى اكمال معادلات هذا المركب مثل Cyclopropane مثل Cyclopropane وحطينا لكوا بدنا نشوف all structural isomers يعني مش مركز انا على ال stereo isomers او اعمله monochlorination يعني احط one chlorine atom", "tokens": [6027, 7649, 39182, 29910, 23275, 43242, 7578, 1975, 24793, 6027, 20449, 18513, 1211, 9307, 23758, 9673, 31747, 3555, 50113, 1211, 49173, 404, 1513, 1929, 50113, 1211, 49173, 404, 1513, 1929, 4032, 5016, 9566, 1829, 8315, 5296, 4117, 14407, 47525, 8315, 8717, 8592, 38688, 439, 15067, 307, 298, 433, 37495, 22653, 37893, 3714, 31747, 11622, 1975, 8315, 15844, 2423, 29029, 307, 298, 433, 1975, 2407, 1975, 25957, 43761, 1108, 8997, 6746, 2486, 37495, 22653, 1975, 5016, 9566, 472, 39888, 12018], "avg_logprob": -0.23476562593132258, "compression_ratio": 1.5353535353535352, "no_speech_prob": 0.0, "words": [{"start": 858.38, "end": 859.06, "word": "الان", "probability": 0.72998046875}, {"start": 859.06, "end": 859.56, "word": " بعد", "probability": 0.6396484375}, {"start": 859.56, "end": 859.8, "word": " ذلك", "probability": 0.6285400390625}, {"start": 859.8, "end": 860.14, "word": " عندى", "probability": 0.4578857421875}, {"start": 860.14, "end": 860.6, "word": " اكمال", "probability": 0.8963216145833334}, {"start": 860.6, "end": 861.76, "word": " معادلات", "probability": 0.9244384765625}, {"start": 861.76, "end": 864.12, "word": " هذا", "probability": 0.63916015625}, {"start": 864.12, "end": 864.92, "word": " المركب", "probability": 0.8600260416666666}, {"start": 864.92, "end": 865.58, "word": " مثل", "probability": 0.9375}, {"start": 865.58, "end": 867.32, "word": " Cyclopropane", "probability": 0.75738525390625}, {"start": 867.32, "end": 868.32, "word": " مثل", "probability": 0.69775390625}, {"start": 868.32, "end": 869.94, "word": " Cyclopropane", "probability": 0.951171875}, {"start": 869.94, "end": 871.12, "word": " وحطينا", "probability": 0.763037109375}, {"start": 871.12, "end": 871.66, 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stereo", "probability": 0.63525390625}, {"start": 877.76, "end": 878.58, "word": " isomers", "probability": 0.97119140625}, {"start": 878.58, "end": 878.8, "word": " او", "probability": 0.60107421875}, {"start": 878.8, "end": 879.24, "word": " اعمله", "probability": 0.93359375}, {"start": 879.24, "end": 880.46, "word": " monochlorination", "probability": 0.77618408203125}, {"start": 880.46, "end": 880.72, "word": " يعني", "probability": 0.90234375}, {"start": 880.72, "end": 881.24, "word": " احط", "probability": 0.8933919270833334}, {"start": 881.24, "end": 881.78, "word": " one", "probability": 0.61572265625}, {"start": 881.78, "end": 882.48, "word": " chlorine", "probability": 0.94482421875}, {"start": 882.48, "end": 882.96, "word": " atom", "probability": 0.88330078125}], "temperature": 1.0}, {"id": 36, "seek": 90354, "start": 884.4, "end": 903.54, "text": "واضح؟ وين بده احط هذه ال chlorine طبعا هنبدأ نرسم اكثر من شكل مش عارف تلاتة اربعة بنجرب احنا الان اكيد ال chlorine بإمكانها 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"text": "واضحة الفكرة؟ كيف هذي بتعمل ring opening؟ بيكونوا سن ولا أنتي؟ مجموعات ال OHS ال ring opening من البرأس الانتي", "tokens": [2407, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 9122, 33911, 8032, 8848, 1829, 39894, 25957, 1211, 4875, 5193, 22807, 4724, 1829, 30544, 14407, 8608, 1863, 49429, 14739, 31371, 22807, 3714, 7435, 2304, 45367, 9307, 2423, 422, 12527, 2423, 4875, 5193, 9154, 2423, 26890, 10721, 3794, 2423, 7649, 31371], "avg_logprob": -0.2968750097313706, "compression_ratio": 1.3134328358208955, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 955.78, "end": 956.3, "word": "واضحة", "probability": 0.876220703125}, {"start": 956.3, "end": 957.38, "word": " الفكرة؟", "probability": 0.880126953125}, {"start": 957.38, "end": 957.64, "word": " كيف", "probability": 0.94482421875}, {"start": 957.64, "end": 957.88, "word": " هذي", "probability": 0.532470703125}, {"start": 957.88, "end": 958.28, "word": " بتعمل", "probability": 0.98046875}, {"start": 958.28, "end": 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0.984619140625}, {"start": 982.35, "end": 983.53, "word": " أخدناهم", "probability": 0.93408203125}, {"start": 983.53, "end": 984.09, "word": " بيعملوا", "probability": 0.95712890625}, {"start": 984.09, "end": 984.37, "word": " sin", "probability": 0.90234375}, {"start": 984.37, "end": 984.81, "word": " addition", "probability": 0.96875}, {"start": 984.81, "end": 985.61, "word": " لمجموعتين", "probability": 0.93603515625}, {"start": 985.61, "end": 985.99, "word": " OH", "probability": 0.90087890625}, {"start": 985.99, "end": 986.67, "word": " لكن", "probability": 0.9013671875}, {"start": 986.67, "end": 987.59, "word": " بهذه", "probability": 0.829833984375}, {"start": 987.59, "end": 988.11, "word": " الطريقة", "probability": 0.97509765625}, {"start": 988.11, "end": 988.71, "word": " بنطلع", "probability": 0.897216796875}, {"start": 988.71, "end": 988.87, "word": " ال", "probability": 0.9853515625}, {"start": 988.87, "end": 989.19, "word": " Anti", "probability": 0.1318359375}, {"start": 989.19, "end": 990.23, "word": " product", "probability": 0.416015625}, {"start": 990.23, "end": 990.59, "word": " اللي", "probability": 0.727294921875}, {"start": 990.59, "end": 990.83, "word": " كان", "probability": 0.96337890625}, {"start": 990.83, "end": 991.25, "word": " واضح", "probability": 0.9581705729166666}, {"start": 991.25, "end": 991.89, "word": " تماما", "probability": 0.9933268229166666}, {"start": 991.89, "end": 992.29, "word": " يعني", "probability": 0.90185546875}, {"start": 992.29, "end": 992.57, "word": " بدكوا", "probability": 0.760986328125}, {"start": 992.57, "end": 993.03, "word": " تحطوا", "probability": 0.9813232421875}, {"start": 993.03, "end": 993.27, "word": " OH", "probability": 0.95068359375}, {"start": 993.27, "end": 993.75, "word": " على", "probability": 0.82568359375}, {"start": 993.75, "end": 994.39, "word": " جهة", "probability": 0.9596354166666666}, {"start": 994.39, "end": 995.47, "word": " و", "probability": 0.9375}, {"start": 995.47, 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بعدين نعمل ring opening في الميه هذا محصلته في الدماغ بيحط مجمعتين OH انتي انتي طبعا الان لما نضيف H2 في وجود platinum", "tokens": [3224, 1829, 10721, 7435, 14407, 1975, 8592, 2304, 6027, 16095, 16472, 31371, 23032, 3555, 3615, 995, 1975, 1829, 36764, 24401, 3660, 44650, 15730, 4117, 25720, 10874, 25708, 995, 37893, 48812, 2288, 13063, 1829, 6055, 5172, 37983, 6055, 25957, 1211, 30767, 1829, 39896, 4117, 16490, 1211, 33546, 31439, 2423, 6949, 8258, 4032, 39182, 9957, 8717, 25957, 1211, 4875, 5193, 8978, 9673, 1829, 3224, 23758, 3714, 5016, 36520, 47395, 8978, 32748, 2304, 5718, 118, 4724, 1829, 5016, 9566, 3714, 7435, 2304, 34268, 9957, 13931, 16472, 31371, 16472, 31371, 23032, 3555, 3615, 995, 2423, 7649, 5296, 15042, 8717, 11242, 33911, 389, 17, 8978, 49610, 23328, 37475], "avg_logprob": -0.19771634672696775, "compression_ratio": 1.5570175438596492, "no_speech_prob": 0.0, "words": [{"start": 1001.38, "end": 1001.98, "word": "هيأجوا", "probability": 0.83115234375}, {"start": 1001.98, 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"probability": 0.7154541015625}, {"start": 1025.06, "end": 1025.54, "word": " لما", "probability": 0.94580078125}, {"start": 1025.54, "end": 1025.9, "word": " نضيف", "probability": 0.9890950520833334}, {"start": 1025.9, "end": 1026.74, "word": " H2", "probability": 0.91943359375}, {"start": 1026.74, "end": 1027.68, "word": " في", "probability": 0.92919921875}, {"start": 1027.68, "end": 1028.42, "word": " وجود", "probability": 0.94775390625}, {"start": 1028.42, "end": 1029.12, "word": " platinum", "probability": 0.6923828125}], "temperature": 1.0}, {"id": 42, "seek": 106034, "start": 1040.03, "end": 1060.35, "text": "هذا المُركّب اللي فيه ال PR لحظة انا هنا حاططلكم KOH و جايلكم ان انا بدي ال major elimination product كأني بقول انو حطوا double bond هان او هان واضح انه كتير ركزنا معاكم انه the more substituted ال keen", "tokens": [3224, 15730, 9673, 10859, 31747, 11703, 3555, 13672, 1829, 8978, 3224, 2423, 11568, 5296, 5016, 19913, 3660, 1975, 8315, 34105, 11331, 41193, 9566, 23275, 2304, 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"end": 1044.79, "word": " لحظة", "probability": 0.7196044921875}, {"start": 1044.79, "end": 1044.99, "word": " انا", "probability": 0.7088623046875}, {"start": 1044.99, "end": 1045.17, "word": " هنا", "probability": 0.55859375}, {"start": 1045.17, "end": 1045.79, "word": " حاططلكم", "probability": 0.632666015625}, {"start": 1045.79, "end": 1046.49, "word": " KOH", "probability": 0.5164794921875}, {"start": 1046.49, "end": 1046.71, "word": " و", "probability": 0.6630859375}, {"start": 1046.71, "end": 1047.13, "word": " جايلكم", "probability": 0.818359375}, {"start": 1047.13, "end": 1047.27, "word": " ان", "probability": 0.8798828125}, {"start": 1047.27, "end": 1047.45, "word": " انا", "probability": 0.815185546875}, {"start": 1047.45, "end": 1047.87, "word": " بدي", "probability": 0.6905517578125}, {"start": 1047.87, "end": 1048.17, "word": " ال", "probability": 0.57080078125}, {"start": 1048.17, "end": 1048.57, "word": " major", "probability": 0.8173828125}, {"start": 1048.57, "end": 1049.29, "word": " elimination", "probability": 0.927734375}, {"start": 1049.29, "end": 1050.07, "word": " product", "probability": 0.9716796875}, {"start": 1050.07, "end": 1051.41, "word": " كأني", "probability": 0.599853515625}, {"start": 1051.41, "end": 1051.69, "word": " بقول", "probability": 0.9306640625}, {"start": 1051.69, "end": 1051.99, "word": " انو", "probability": 0.5533447265625}, {"start": 1051.99, "end": 1052.31, "word": " حطوا", "probability": 0.7151692708333334}, {"start": 1052.31, "end": 1052.55, "word": " double", "probability": 0.5888671875}, {"start": 1052.55, "end": 1052.85, "word": " bond", "probability": 0.67041015625}, {"start": 1052.85, "end": 1053.19, "word": " هان", "probability": 0.4813232421875}, {"start": 1053.19, "end": 1053.45, "word": " او", "probability": 0.945068359375}, {"start": 1053.45, "end": 1053.95, "word": " هان", "probability": 0.944580078125}, {"start": 1053.95, "end": 1055.89, "word": " واضح", "probability": 0.978515625}, {"start": 1055.89, "end": 1056.65, "word": " انه", "probability": 0.77392578125}, {"start": 1056.65, "end": 1057.25, "word": " كتير", "probability": 0.69970703125}, {"start": 1057.25, "end": 1057.83, "word": " ركزنا", "probability": 0.9752197265625}, {"start": 1057.83, "end": 1058.13, "word": " معاكم", "probability": 0.8447265625}, {"start": 1058.13, "end": 1058.43, "word": " انه", "probability": 0.721435546875}, {"start": 1058.43, "end": 1058.55, "word": " the", "probability": 0.371826171875}, {"start": 1058.55, "end": 1058.87, "word": " more", "probability": 0.9443359375}, {"start": 1058.87, "end": 1059.75, "word": " substituted", "probability": 0.874755859375}, {"start": 1059.75, "end": 1060.01, "word": " ال", "probability": 0.6513671875}, {"start": 1060.01, "end": 1060.35, "word": " keen", "probability": 0.392333984375}], "temperature": 1.0}, {"id": 43, "seek": 109010, "start": 1061.37, "end": 1090.11, "text": "والـ Form حسب قاعدة Zaitsev إذا هنا بدو ييجي ال الـ K واضح؟ مش هتيجي ال PR مع هذه ال H لأن هذا less substituted ال K هذا ال more substituted الآن بعد هيك هذا المركب بدنا نضيف عليه ميا في وجود H plus هذا إضافة Markovnikov لحظة هنا في carbon تحمل H و هذه ال carbon لأ تحملش H إذا", "tokens": [2407, 6027, 39184, 10126, 11331, 35457, 12174, 995, 22488, 3660, 1176, 1001, 405, 85, 11933, 15730, 34105, 47525, 2407, 7251, 1829, 7435, 1829, 2423, 2423, 39184, 591, 4032, 46958, 5016, 22807, 37893, 8032, 31371, 7435, 1829, 2423, 11568, 20449, 29538, 2423, 389, 5296, 33456, 23758, 1570, 26441, 4866, 2423, 591, 23758, 2423, 544, 26441, 4866, 6024, 48506, 39182, 39896, 4117, 23758, 9673, 31747, 3555, 47525, 8315, 8717, 11242, 33911, 47356, 3714, 25528, 8978, 49610, 23328, 389, 1804, 23758, 11933, 11242, 31845, 3660, 3934, 5179, 13123, 5179, 5296, 5016, 19913, 3660, 34105, 8978, 5954, 6055, 35571, 1211, 389, 4032, 29538, 2423, 5954, 5296, 10721, 6055, 35571, 1211, 8592, 389, 11933, 15730], "avg_logprob": -0.33699323196668884, "compression_ratio": 1.6264591439688716, "no_speech_prob": 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" بدكوا", "probability": 0.5686848958333334}, {"start": 1370.07, "end": 1370.53, "word": " تقولوا", "probability": 0.9864908854166666}, {"start": 1370.53, "end": 1370.75, "word": " يا", "probability": 0.5771484375}, {"start": 1370.75, "end": 1371.13, "word": " تنتين", "probability": 0.9947916666666666}, {"start": 1371.13, "end": 1371.35, "word": " double", "probability": 0.90869140625}, {"start": 1371.35, "end": 1371.79, "word": " bonds", "probability": 0.8994140625}, {"start": 1371.79, "end": 1372.69, "word": " يا", "probability": 0.93359375}, {"start": 1372.69, "end": 1373.11, "word": " تنتين", "probability": 0.9944661458333334}, {"start": 1373.11, "end": 1373.83, "word": " حلقات", "probability": 0.99072265625}, {"start": 1373.83, "end": 1374.25, "word": " يا", "probability": 0.93017578125}, {"start": 1374.25, "end": 1374.51, "word": " double", "probability": 0.9541015625}, {"start": 1374.51, "end": 1374.79, "word": " bond", "probability": 0.9443359375}, {"start": 1374.79, "end": 1375.27, "word": " وحلقة", "probability": 0.851318359375}, {"start": 1375.27, "end": 1375.97, "word": " طبعا", "probability": 0.97119140625}, {"start": 1375.97, "end": 1376.25, "word": " ال", "probability": 0.9609375}, {"start": 1376.25, "end": 1377.29, "word": " C3H4", "probability": 0.901611328125}, {"start": 1377.29, "end": 1377.45, "word": " ما", "probability": 0.61572265625}, {"start": 1377.45, "end": 1378.25, "word": " بتحتمل", "probability": 0.8601888020833334}], "temperature": 1.0}, {"id": 55, "seek": 140350, "start": 1379.5, "end": 1403.5, "text": "تلتين حلقات يعني كلها كم ذرة هي تلاتة بناء على ذلك لو أنا فكرت أني بدأ أعمل منهم حلقة حلقة واحدة لازم ألاحقها بكمان ايش double bond لاحظوا لو هنا اتيتوا تكملوا ال hydrogens هتطلع الفورموله صح اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش", "tokens": [2655, 1211, 2655, 9957, 11331, 1211, 4587, 9307, 37495, 22653, 28242, 11296, 9122, 2304, 29910, 25720, 39896, 6055, 1211, 9307, 3660, 44945, 16606, 15844, 29910, 23275, 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{"start": 1380.54, "end": 1380.7, "word": " يعني", "probability": 0.82080078125}, {"start": 1380.7, "end": 1381.04, "word": " كلها", "probability": 0.8388671875}, {"start": 1381.04, "end": 1381.24, "word": " كم", "probability": 0.760009765625}, {"start": 1381.24, "end": 1381.6, "word": " ذرة", "probability": 0.788818359375}, {"start": 1381.6, "end": 1381.9, "word": " هي", "probability": 0.595703125}, {"start": 1381.9, "end": 1383.5, "word": " تلاتة", "probability": 0.8892822265625}, {"start": 1383.5, "end": 1384.08, "word": " بناء", "probability": 0.88916015625}, {"start": 1384.08, "end": 1384.32, "word": " على", "probability": 0.7607421875}, {"start": 1384.32, "end": 1384.72, "word": " ذلك", "probability": 0.989013671875}, {"start": 1384.72, "end": 1384.88, "word": " لو", "probability": 0.7841796875}, {"start": 1384.88, "end": 1385.12, "word": " أنا", "probability": 0.517578125}, {"start": 1385.12, "end": 1385.58, "word": " فكرت", "probability": 0.9376627604166666}, {"start": 1385.58, "end": 1385.7, "word": " أني", "probability": 0.62060546875}, {"start": 1385.7, "end": 1385.86, "word": " بدأ", "probability": 0.4005126953125}, {"start": 1385.86, "end": 1386.1, "word": " أعمل", "probability": 0.9137369791666666}, {"start": 1386.1, "end": 1386.4, "word": " منهم", "probability": 0.987548828125}, {"start": 1386.4, "end": 1387.02, "word": " حلقة", "probability": 0.9768880208333334}, {"start": 1387.02, "end": 1387.48, "word": " حلقة", "probability": 0.7574055989583334}, {"start": 1387.48, "end": 1388.0, "word": " واحدة", "probability": 0.9415690104166666}, {"start": 1388.0, "end": 1388.8, "word": " لازم", "probability": 0.9791666666666666}, {"start": 1388.8, "end": 1389.36, "word": " ألاحقها", "probability": 0.67578125}, {"start": 1389.36, "end": 1389.8, "word": " بكمان", "probability": 0.7864583333333334}, {"start": 1389.8, "end": 1390.22, "word": " ايش", "probability": 0.7027587890625}, {"start": 1390.22, "end": 1391.16, "word": " double", "probability": 0.42919921875}, {"start": 1391.16, "end": 1391.6, "word": " bond", "probability": 0.953125}, {"start": 1391.6, "end": 1393.5, "word": " لاحظوا", "probability": 0.8880615234375}, {"start": 1393.5, "end": 1393.66, "word": " لو", "probability": 0.9130859375}, {"start": 1393.66, "end": 1393.92, "word": " هنا", "probability": 0.57763671875}, {"start": 1393.92, "end": 1394.32, "word": " اتيتوا", "probability": 0.672607421875}, {"start": 1394.32, "end": 1394.7, "word": " تكملوا", "probability": 0.96240234375}, {"start": 1394.7, "end": 1394.76, "word": " ال", "probability": 0.9658203125}, {"start": 1394.76, "end": 1395.32, "word": " hydrogens", "probability": 0.7184244791666666}, {"start": 1395.32, "end": 1395.76, "word": " هتطلع", "probability": 0.93203125}, {"start": 1395.76, "end": 1396.3, "word": " الفورموله", "probability": 0.7787109375}, {"start": 1396.3, "end": 1397.58, "word": " صح", "probability": 0.968994140625}, {"start": 1397.58, "end": 1398.54, "word": " اتش", "probability": 0.55029296875}, {"start": 1398.54, "end": 1399.56, "word": " اتش", "probability": 0.8714192708333334}, {"start": 1399.56, "end": 1399.94, "word": " اتش", "probability": 0.8165690104166666}, {"start": 1399.94, "end": 1400.12, "word": " اتش", "probability": 0.7626139322916666}, {"start": 1400.12, "end": 1400.42, "word": " اتش", "probability": 0.7862141927083334}, {"start": 1400.42, "end": 1400.72, "word": " اتش", "probability": 0.8253580729166666}, {"start": 1400.72, "end": 1400.96, "word": " اتش", "probability": 0.8621419270833334}, {"start": 1400.96, "end": 1400.96, "word": " اتش", "probability": 0.8932291666666666}, {"start": 1400.96, "end": 1401.02, "word": " اتش", "probability": 0.9122721354166666}, {"start": 1401.02, "end": 1401.26, "word": " اتش", "probability": 0.9275716145833334}, {"start": 1401.26, "end": 1401.26, "word": " اتش", "probability": 0.9371744791666666}, {"start": 1401.26, "end": 1401.32, "word": " اتش", "probability": 0.943359375}, {"start": 1401.32, "end": 1401.32, "word": " اتش", "probability": 0.9488932291666666}, {"start": 1401.32, "end": 1401.86, "word": " اتش", "probability": 0.9521484375}, {"start": 1401.86, "end": 1403.5, "word": " اتش", "probability": 0.955078125}], "temperature": 1.0}, {"id": 56, "seek": 143551, "start": 1406.93, "end": 1435.51, "text": "هذا الاحتمال اللى فيه حلقات الان بعد هيك ممكن اعمل التنتين bubble bonds اعتبرهم ال kind triple bond يعني احط C triple bond C و هنا CH3 CH3 و هذه H هدولة بمثابة تنتين bubble bonds هاي CH3", "tokens": [3224, 15730, 42963, 33753, 2304, 6027, 13672, 7578, 8978, 3224, 11331, 1211, 4587, 9307, 2423, 7649, 39182, 39896, 4117, 3714, 43020, 1975, 25957, 1211, 16712, 29399, 9957, 12212, 14713, 1975, 34268, 26890, 16095, 2423, 733, 15508, 6086, 37495, 22653, 1975, 5016, 9566, 383, 15508, 6086, 383, 4032, 34105, 5995, 18, 5995, 18, 4032, 29538, 389, 8032, 3215, 12610, 3660, 4724, 2304, 12984, 16758, 3660, 6055, 29399, 9957, 12212, 14713, 8032, 47302, 5995, 18], "avg_logprob": -0.26689190276571223, "compression_ratio": 1.5649717514124293, "no_speech_prob": 0.0, "words": [{"start": 1406.93, "end": 1407.25, "word": "هذا", "probability": 0.857177734375}, {"start": 1407.25, "end": 1407.93, "word": " الاحتمال", "probability": 0.9124755859375}, {"start": 1407.93, "end": 1408.43, "word": " اللى", "probability": 0.51171875}, {"start": 1408.43, "end": 1408.69, "word": " فيه", "probability": 0.772705078125}, {"start": 1408.69, "end": 1409.33, "word": " حلقات", "probability": 0.9813232421875}, {"start": 1409.33, "end": 1409.89, "word": " الان", "probability": 0.6224365234375}, {"start": 1409.89, "end": 1410.17, "word": " بعد", "probability": 0.95556640625}, {"start": 1410.17, "end": 1410.79, "word": " هيك", "probability": 0.895263671875}, {"start": 1410.79, "end": 1411.55, "word": " ممكن", "probability": 0.9658203125}, {"start": 1411.55, "end": 1412.27, "word": " اعمل", "probability": 0.9617513020833334}, {"start": 1412.27, "end": 1413.55, "word": " التنتين", "probability": 0.7355143229166666}, {"start": 1413.55, "end": 1413.81, "word": " bubble", "probability": 0.7890625}, {"start": 1413.81, "end": 1414.37, "word": " bonds", "probability": 0.8076171875}, {"start": 1414.37, "end": 1415.01, "word": " اعتبرهم", "probability": 0.8380126953125}, {"start": 1415.01, "end": 1415.21, "word": " ال", "probability": 0.6845703125}, {"start": 1415.21, "end": 1415.63, "word": " kind", "probability": 0.64404296875}, {"start": 1415.63, "end": 1417.31, "word": " triple", "probability": 0.26953125}, {"start": 1417.31, "end": 1417.87, "word": " bond", "probability": 0.85986328125}, {"start": 1417.87, "end": 1418.65, "word": " يعني", "probability": 0.82568359375}, {"start": 1418.65, "end": 1419.05, "word": " احط", "probability": 0.9345703125}, {"start": 1419.05, "end": 1419.41, "word": " C", "probability": 0.42626953125}, {"start": 1419.41, "end": 1420.31, "word": " triple", "probability": 0.52197265625}, {"start": 1420.31, "end": 1420.77, "word": " bond", "probability": 0.96484375}, {"start": 1420.77, "end": 1421.27, "word": " C", "probability": 0.78173828125}, {"start": 1421.27, "end": 1421.75, "word": " و", "probability": 0.493408203125}, {"start": 1421.75, "end": 1422.09, "word": " هنا", "probability": 0.54541015625}, {"start": 1422.09, "end": 1424.27, "word": " CH3", "probability": 0.884765625}, {"start": 1424.27, "end": 1428.13, "word": " CH3", "probability": 0.915771484375}, {"start": 1428.13, "end": 1428.45, "word": " و", "probability": 0.6767578125}, {"start": 1428.45, "end": 1428.89, "word": " هذه", "probability": 0.454345703125}, {"start": 1428.89, "end": 1430.31, "word": " H", "probability": 0.9453125}, {"start": 1430.31, "end": 1433.25, "word": " هدولة", "probability": 0.779296875}, {"start": 1433.25, "end": 1433.89, "word": " بمثابة", "probability": 0.96767578125}, {"start": 1433.89, "end": 1434.29, "word": " تنتين", "probability": 0.8538411458333334}, {"start": 1434.29, "end": 1434.51, "word": " bubble", "probability": 0.9599609375}, {"start": 1434.51, "end": 1434.81, "word": " bonds", "probability": 0.56103515625}, {"start": 1434.81, "end": 1435.01, "word": " هاي", "probability": 0.4658203125}, {"start": 1435.01, "end": 1435.51, "word": " CH3", "probability": 0.7900390625}], "temperature": 1.0}, {"id": 57, "seek": 145591, "start": 1437.13, "end": 1455.91, "text": "ممكن احط تنتين double bonds جانب بعض carbon double bond carbon double bond carbon وهنا بدو يكون عندكم CH2 CH2 في غير هيك؟", "tokens": [2304, 43020, 1975, 5016, 9566, 6055, 29399, 9957, 3834, 14713, 10874, 7649, 3555, 45030, 11242, 5954, 3834, 6086, 5954, 3834, 6086, 5954, 37037, 8315, 47525, 2407, 7251, 30544, 43242, 24793, 5995, 17, 5995, 17, 8978, 32771, 13546, 39896, 4117, 22807], "avg_logprob": -0.2530487863028922, "compression_ratio": 1.3524590163934427, "no_speech_prob": 0.0, "words": [{"start": 1437.1299999999999, "end": 1438.05, "word": "ممكن", "probability": 0.780517578125}, {"start": 1438.05, "end": 1438.63, "word": " احط", "probability": 0.8828125}, {"start": 1438.63, "end": 1439.33, "word": " تنتين", "probability": 0.79541015625}, {"start": 1439.33, "end": 1439.57, "word": " double", "probability": 0.66943359375}, {"start": 1439.57, "end": 1439.95, "word": " bonds", "probability": 0.64306640625}, {"start": 1439.95, "end": 1440.41, "word": " جانب", "probability": 0.7574869791666666}, {"start": 1440.41, "end": 1440.81, "word": " بعض", "probability": 0.864013671875}, {"start": 1440.81, "end": 1442.45, "word": " carbon", "probability": 0.273681640625}, {"start": 1442.45, "end": 1442.77, "word": " double", "probability": 0.7353515625}, {"start": 1442.77, "end": 1443.11, "word": " bond", "probability": 0.93359375}, {"start": 1443.11, "end": 1443.53, "word": " carbon", "probability": 0.876953125}, {"start": 1443.53, "end": 1443.87, "word": " double", "probability": 0.91162109375}, {"start": 1443.87, "end": 1444.23, "word": " bond", "probability": 0.974609375}, {"start": 1444.23, "end": 1445.19, "word": " carbon", "probability": 0.9521484375}, {"start": 1445.19, "end": 1446.29, "word": " وهنا", "probability": 0.6065673828125}, {"start": 1446.29, "end": 1446.53, "word": " بدو", "probability": 0.57373046875}, {"start": 1446.53, "end": 1446.77, "word": " يكون", "probability": 0.983642578125}, {"start": 1446.77, "end": 1447.49, "word": " عندكم", "probability": 0.96630859375}, {"start": 1447.49, "end": 1449.95, "word": " CH2", "probability": 0.927734375}, {"start": 1449.95, "end": 1454.49, "word": " CH2", "probability": 0.905029296875}, {"start": 1454.49, "end": 1455.01, "word": " في", "probability": 0.666015625}, {"start": 1455.01, "end": 1455.29, "word": " غير", "probability": 0.93505859375}, {"start": 1455.29, "end": 1455.91, "word": " هيك؟", "probability": 0.9034830729166666}], "temperature": 1.0}, {"id": 58, "seek": 148737, "start": 1459.31, "end": 1487.37, "text": "أهم شيء اللى بنى عليها هذا السؤال انه نفهم احنا ان الصيغة المشبعة تماما لل C3 هي H8 الان مقابل كل هيدروجينتين بخصومهم بدي اعمل double bond او حلقة واضح فخصمت هيدروجنتين على كام مرة امرتين اربعة تقسيم اتنين اتنين فهنا عملت حلقة و double bond هنا عملت تنتين by bonds هنا عملت تنتين double bonds", "tokens": [10721, 16095, 44049, 38207, 13672, 7578, 44945, 7578, 25894, 11296, 23758, 21136, 33604, 6027, 16472, 3224, 8717, 5172, 16095, 1975, 5016, 8315, 16472, 31767, 1829, 17082, 3660, 9673, 8592, 3555, 27884, 46811, 10943, 995, 24976, 383, 18, 39896, 389, 23, 2423, 7649, 3714, 4587, 16758, 1211, 28242, 8032, 25708, 2288, 29245, 9957, 2655, 9957, 4724, 9778, 9381, 20498, 16095, 4724, 16254, 1975, 25957, 1211, 3834, 6086, 1975, 2407, 11331, 1211, 28671, 4032, 46958, 5016, 6156, 9778, 9381, 2304, 2655, 8032, 25708, 2288, 29245, 29399, 9957, 15844, 9122, 10943, 3714, 25720, 1975, 29973, 2655, 9957, 1975, 25513, 27884, 6055, 4587, 3794, 32640, 1975, 2655, 1863, 9957, 1975, 2655, 1863, 9957, 6156, 3224, 8315, 6225, 42213, 2655, 11331, 1211, 28671, 4032, 3834, 6086, 34105, 6225, 42213, 2655, 6055, 29399, 9957, 538, 14713, 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{"start": 1472.27, "end": 1472.81, "word": " بخصومهم", "probability": 0.8689453125}, {"start": 1472.81, "end": 1473.01, "word": " بدي", "probability": 0.644287109375}, {"start": 1473.01, "end": 1473.53, "word": " اعمل", "probability": 0.90234375}, {"start": 1473.53, "end": 1474.39, "word": " double", "probability": 0.6923828125}, {"start": 1474.39, "end": 1474.69, "word": " bond", "probability": 0.9375}, {"start": 1474.69, "end": 1475.15, "word": " او", "probability": 0.877197265625}, {"start": 1475.15, "end": 1475.99, "word": " حلقة", "probability": 0.9739583333333334}, {"start": 1475.99, "end": 1477.15, "word": " واضح", "probability": 0.9060872395833334}, {"start": 1477.15, "end": 1478.11, "word": " فخصمت", "probability": 0.9255859375}, {"start": 1478.11, "end": 1478.83, "word": " هيدروجنتين", "probability": 0.9129231770833334}, {"start": 1478.83, "end": 1479.01, "word": " على", "probability": 0.74462890625}, {"start": 1479.01, "end": 1479.33, "word": " كام", "probability": 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100% ولا لأ؟", "tokens": [12610, 15042, 6055, 24793, 1211, 14407, 25124, 28820, 9122, 32640, 1829, 16373, 25528, 13412, 28820, 8608, 20292, 2304, 2319, 4, 49429, 5296, 10721, 22807], "avg_logprob": -0.30140625, "compression_ratio": 1.135135135135135, "no_speech_prob": 0.0, "words": [{"start": 1489.12, "end": 1489.64, "word": "ولما", "probability": 0.4176025390625}, {"start": 1489.64, "end": 1490.26, "word": " تكملوا", "probability": 0.8001708984375}, {"start": 1490.26, "end": 1490.84, "word": " الشكل", "probability": 0.841064453125}, {"start": 1490.84, "end": 1491.58, "word": " كيميائيا", "probability": 0.841796875}, {"start": 1491.58, "end": 1491.98, "word": " شكل", "probability": 0.6253662109375}, {"start": 1491.98, "end": 1492.46, "word": " سليم", "probability": 0.89501953125}, {"start": 1492.46, "end": 1492.6, "word": " 100", "probability": 0.6318359375}, {"start": 1492.6, "end": 1492.98, "word": "%", "probability": 0.90234375}, {"start": 1492.98, "end": 1493.18, "word": " ولا", 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"word": " بيحل", "probability": 0.76617431640625}, {"start": 2177.01, "end": 2177.45, "word": " محل", "probability": 0.89697265625}, {"start": 2177.45, "end": 2178.05, "word": " كلور", "probability": 0.8323567708333334}, {"start": 2178.05, "end": 2178.67, "word": " هذه", "probability": 0.615234375}, {"start": 2178.67, "end": 2179.25, "word": " المعلومة", "probability": 0.9912109375}, {"start": 2179.25, "end": 2179.87, "word": " أخدناها", "probability": 0.9578125}, {"start": 2179.87, "end": 2180.09, "word": " ولا", "probability": 0.7265625}, {"start": 2180.09, "end": 2180.53, "word": " لأ", "probability": 0.88525390625}, {"start": 2180.53, "end": 2183.67, "word": " اليود", "probability": 0.80859375}, {"start": 2183.67, "end": 2184.01, "word": " بيحل", "probability": 0.9925537109375}, {"start": 2184.01, "end": 2184.33, "word": " محل", "probability": 0.9903971354166666}, {"start": 2184.33, "end": 2184.65, "word": " كلور", "probability": 0.9563802083333334}, {"start": 2184.65, "end": 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سكندر بيوت الالكهول طبعا ال dehydration يا ال OH من هنا او من هنا اخدنا انه حسب قاعدة زي سف الحذف و more substituted product will form اذا ال one butane ولا ال two butane انا كاتبينلكم بشكل أساسي one butane اذا خطأ", "tokens": [3615, 23942, 23758, 9673, 30543, 3615, 37037, 15730, 5296, 15042, 7251, 35571, 1211, 13931, 8608, 19452, 3215, 2288, 4724, 1829, 35473, 2423, 6027, 4117, 3224, 12610, 23032, 3555, 3615, 995, 2423, 32102, 2405, 35186, 2423, 13931, 9154, 34105, 1975, 2407, 9154, 34105, 1975, 9778, 3215, 8315, 16472, 3224, 11331, 35457, 12174, 995, 22488, 3660, 30767, 1829, 8608, 5172, 21542, 8848, 5172, 4032, 544, 26441, 4866, 1674, 486, 1254, 1975, 15730, 2423, 472, 457, 1929, 49429, 2423, 732, 457, 1929, 1975, 8315, 9122, 9307, 3555, 9957, 23275, 2304, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 472, 457, 1929, 1975, 15730, 16490, 9566, 10721], "avg_logprob": -0.21374393174949202, "compression_ratio": 1.5854700854700854, "no_speech_prob": 1.1920928955078125e-07, "words": 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0.572265625}, {"start": 2410.62, "end": 2411.24, "word": " بيوتين", "probability": 0.9364013671875}, {"start": 2411.24, "end": 2414.26, "word": " خليني", "probability": 0.582733154296875}, {"start": 2414.26, "end": 2414.66, "word": " اخد", "probability": 0.7508138020833334}, {"start": 2414.66, "end": 2414.84, "word": " ال", "probability": 0.810546875}, {"start": 2414.84, "end": 2415.14, "word": " سيس", "probability": 0.6696573893229166}, {"start": 2415.14, "end": 2415.38, "word": " تو", "probability": 0.7734375}, {"start": 2415.38, "end": 2415.98, "word": " بيوتين", "probability": 0.983642578125}, {"start": 2415.98, "end": 2417.9, "word": " ارسمه", "probability": 0.762939453125}, {"start": 2417.9, "end": 2418.28, "word": " هان", "probability": 0.66455078125}, {"start": 2418.28, "end": 2419.28, "word": " هاي", "probability": 0.5850830078125}, {"start": 2419.28, "end": 2419.44, "word": " ال", "probability": 0.85546875}, {"start": 2419.44, "end": 2419.62, "word": " سيس", "probability": 0.8143717447916666}, {"start": 2419.62, "end": 2419.86, "word": " تو", "probability": 0.90185546875}, {"start": 2419.86, "end": 2420.28, "word": " بيوتين", "probability": 0.990478515625}, {"start": 2420.28, "end": 2420.48, "word": " بدي", "probability": 0.613037109375}, {"start": 2420.48, "end": 2420.98, "word": " اكسره", "probability": 0.8626953125}, {"start": 2420.98, "end": 2421.12, "word": " من", "probability": 0.986328125}, {"start": 2421.12, "end": 2421.5, "word": " هان", "probability": 0.766845703125}, {"start": 2421.5, "end": 2422.16, "word": " C", "probability": 0.285888671875}, {"start": 2422.16, "end": 2422.36, "word": " double", "probability": 0.3046875}, {"start": 2422.36, "end": 2422.72, "word": " bond", "probability": 0.92626953125}, {"start": 2422.72, "end": 2423.08, "word": " O", "probability": 0.87255859375}, {"start": 2423.08, "end": 2423.56, "word": " وهذه", "probability": 0.4080810546875}, {"start": 2423.56, "end": 2423.88, "word": " H", "probability": 0.68701171875}, {"start": 2423.88, "end": 2424.64, "word": " بالتأكيد", "probability": 0.92607421875}], "temperature": 1.0}, {"id": 93, "seek": 245340, "start": 2426.66, "end": 2453.4, "text": "هذا C double bond OH CH3 Acetaldehyde هذا C double bond OH CH3 Acetaldehyde و لل Trans هاي CH3H و هنا CH3H الان اكسروا هذا من هنا و اكسروا هذا من هنا و حطوا ايش Oxygen Oxygen Oxygen Oxygen", "tokens": [3224, 15730, 383, 3834, 6086, 13931, 5995, 18, 5097, 302, 304, 1479, 3495, 1479, 23758, 383, 3834, 6086, 13931, 5995, 18, 5097, 302, 304, 1479, 3495, 1479, 4032, 24976, 6531, 8032, 47302, 5995, 18, 39, 4032, 34105, 5995, 18, 39, 2423, 7649, 1975, 4117, 3794, 2288, 14407, 23758, 9154, 34105, 4032, 1975, 4117, 3794, 2288, 14407, 23758, 9154, 34105, 4032, 11331, 9566, 14407, 1975, 1829, 8592, 16489, 8647, 16489, 8647, 16489, 8647, 16489, 8647], "avg_logprob": -0.22458333730697633, "compression_ratio": 1.8846153846153846, "no_speech_prob": 0.0, "words": [{"start": 2426.66, "end": 2427.18, "word": "هذا", "probability": 0.93359375}, {"start": 2427.18, "end": 2427.74, "word": " C", "probability": 0.106201171875}, {"start": 2427.74, "end": 2427.96, "word": " double", "probability": 0.42138671875}, {"start": 2427.96, "end": 2428.28, "word": " bond", "probability": 0.94775390625}, {"start": 2428.28, "end": 2428.86, "word": " OH", "probability": 0.92236328125}, {"start": 2428.86, "end": 2429.52, "word": " CH3", "probability": 0.716552734375}, {"start": 2429.52, "end": 2430.38, "word": " Acetaldehyde", "probability": 0.8251953125}, {"start": 2430.38, "end": 2430.66, "word": " هذا", "probability": 0.447998046875}, {"start": 2430.66, "end": 2431.38, "word": " C", "probability": 0.89697265625}, {"start": 2431.38, "end": 2431.56, "word": " double", "probability": 0.869140625}, {"start": 2431.56, "end": 2431.88, "word": " bond", "probability": 0.97021484375}, {"start": 2431.88, "end": 2432.3, "word": " OH", "probability": 0.96875}, {"start": 2432.3, "end": 2433.22, "word": " CH3", "probability": 0.971923828125}, {"start": 2433.22, "end": 2434.14, "word": " Acetaldehyde", "probability": 0.9671223958333334}, {"start": 2434.14, "end": 2434.5, "word": " و", "probability": 0.560546875}, {"start": 2434.5, "end": 2434.68, "word": " لل", "probability": 0.354736328125}, {"start": 2434.68, "end": 2435.22, "word": " Trans", "probability": 0.345947265625}, {"start": 2435.22, "end": 2438.4, "word": " هاي", "probability": 0.653564453125}, {"start": 2438.4, "end": 2439.94, "word": " CH3H", "probability": 0.9697265625}, {"start": 2439.94, "end": 2440.78, "word": " و", "probability": 0.78076171875}, {"start": 2440.78, "end": 2441.06, "word": " هنا", "probability": 0.77734375}, {"start": 2441.06, "end": 2443.38, "word": " CH3H", "probability": 0.9918619791666666}, {"start": 2443.38, "end": 2444.32, "word": " الان", "probability": 0.61572265625}, {"start": 2444.32, "end": 2445.04, "word": " اكسروا", "probability": 0.95634765625}, {"start": 2445.04, "end": 2445.32, "word": " هذا", "probability": 0.916015625}, {"start": 2445.32, "end": 2445.56, "word": " من", "probability": 0.9873046875}, {"start": 2445.56, "end": 2445.9, "word": " هنا", "probability": 0.93212890625}, {"start": 2445.9, "end": 2447.16, "word": " و", "probability": 0.55810546875}, {"start": 2447.16, "end": 2447.64, "word": " اكسروا", "probability": 0.9751953125}, {"start": 2447.64, "end": 2447.88, "word": " هذا", "probability": 0.9833984375}, {"start": 2447.88, "end": 2448.14, "word": " من", "probability": 0.9892578125}, {"start": 2448.14, "end": 2448.5, "word": " هنا", "probability": 0.9658203125}, {"start": 2448.5, "end": 2448.78, "word": " و", "probability": 0.9794921875}, {"start": 2448.78, "end": 2449.18, "word": " حطوا", "probability": 0.8522135416666666}, {"start": 2449.18, "end": 2449.52, "word": " ايش", "probability": 0.8619791666666666}, {"start": 2449.52, "end": 2451.12, "word": " Oxygen", "probability": 0.720703125}, {"start": 2451.12, "end": 2451.96, "word": " Oxygen", "probability": 0.81591796875}, {"start": 2451.96, "end": 2452.74, "word": " Oxygen", "probability": 0.95361328125}, {"start": 2452.74, "end": 2453.4, "word": " Oxygen", "probability": 0.972412109375}], "temperature": 1.0}, {"id": 94, "seek": 247496, "start": 2453.98, "end": 2474.96, "text": "كل النواتج ايش؟ أسيتلديهيد بيعطي نفس الناتج produces only أسيتلديهيد أو إيثانال أسيتلديهيد CH3SH is more acidic than CH3OH due to size", "tokens": [28820, 28239, 2407, 9307, 7435, 1975, 1829, 8592, 22807, 5551, 3794, 36081, 1211, 16254, 3224, 25708, 4724, 40228, 9566, 1829, 8717, 36178, 28239, 9307, 7435, 14725, 787, 5551, 3794, 36081, 1211, 16254, 3224, 25708, 34051, 11933, 1829, 12984, 7649, 6027, 5551, 3794, 36081, 1211, 16254, 3224, 25708, 5995, 18, 17308, 307, 544, 39514, 813, 5995, 18, 31187, 3462, 281, 2744], "avg_logprob": -0.25909324161341935, "compression_ratio": 1.3513513513513513, "no_speech_prob": 0.0, "words": [{"start": 2453.98, "end": 2454.34, "word": "كل", "probability": 0.771484375}, {"start": 2454.34, "end": 2455.02, "word": " النواتج", "probability": 0.8031005859375}, {"start": 2455.02, "end": 2455.5, "word": " ايش؟", "probability": 0.706787109375}, {"start": 2455.5, "end": 2457.06, "word": " أسيتلديهيد", "probability": 0.6798270089285714}, {"start": 2457.06, "end": 2458.52, "word": " بيعطي", "probability": 0.78363037109375}, {"start": 2458.52, "end": 2458.8, "word": " نفس", "probability": 0.989990234375}, {"start": 2458.8, "end": 2459.48, "word": " الناتج", "probability": 0.9140625}, {"start": 2459.48, "end": 2460.38, "word": " produces", "probability": 0.2047119140625}, {"start": 2460.38, "end": 2461.22, "word": " only", "probability": 0.83349609375}, {"start": 2461.22, "end": 2463.4, "word": " أسيتلديهيد", "probability": 0.9464285714285714}, {"start": 2463.4, "end": 2463.64, "word": " أو", "probability": 0.5859375}, {"start": 2463.64, "end": 2464.52, "word": " إيثانال", "probability": 0.735986328125}, {"start": 2464.52, "end": 2467.0, "word": " أسيتلديهيد", "probability": 0.8905901227678571}, {"start": 2467.0, "end": 2469.96, "word": " CH3SH", "probability": 0.88720703125}, {"start": 2469.96, "end": 2470.4, "word": " is", "probability": 0.818359375}, {"start": 2470.4, "end": 2470.66, "word": " more", "probability": 0.9541015625}, {"start": 2470.66, "end": 2471.12, "word": " acidic", "probability": 0.98388671875}, {"start": 2471.12, "end": 2471.5, "word": " than", "probability": 0.90478515625}, {"start": 2471.5, "end": 2472.62, "word": " CH3OH", "probability": 0.98291015625}, {"start": 2472.62, "end": 2473.04, "word": " due", "probability": 0.8017578125}, {"start": 2473.04, "end": 2473.82, "word": " to", "probability": 0.98291015625}, {"start": 2473.82, "end": 2474.96, "word": " size", "probability": 0.21044921875}], "temperature": 1.0}, {"id": 95, "seek": 249844, "start": 2477.52, "end": 2498.44, "text": "سلفر مع اكسجين ايش العامل المحدد في ال acidity ال size ال due to size الان ارسموا المراكبات التالية بدي بيوتين", "tokens": [3794, 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{"start": 2481.04, "end": 2481.14, "word": " ال", "probability": 0.89990234375}, {"start": 2481.14, "end": 2481.84, "word": " acidity", "probability": 0.7132568359375}, {"start": 2481.84, "end": 2482.56, "word": " ال", "probability": 0.333984375}, {"start": 2482.56, "end": 2483.04, "word": " size", "probability": 0.29345703125}, {"start": 2483.04, "end": 2483.74, "word": " ال", "probability": 0.5029296875}, {"start": 2483.74, "end": 2483.96, "word": " due", "probability": 0.54296875}, {"start": 2483.96, "end": 2484.24, "word": " to", "probability": 0.94580078125}, {"start": 2484.24, "end": 2487.82, "word": " size", "probability": 0.5068359375}, {"start": 2487.82, "end": 2494.74, "word": " الان", "probability": 0.684326171875}, {"start": 2494.74, "end": 2495.44, "word": " ارسموا", "probability": 0.841796875}, {"start": 2495.44, "end": 2496.3, "word": " المراكبات", "probability": 0.90615234375}, {"start": 2496.3, "end": 2497.0, "word": " التالية", "probability": 0.9913736979166666}, {"start": 2497.0, "end": 2497.54, "word": " بدي", "probability": 0.6263427734375}, {"start": 2497.54, "end": 2498.44, "word": " بيوتين", "probability": 0.939208984375}], "temperature": 1.0}, {"id": 96, "seek": 252202, "start": 2499.56, "end": 2522.02, "text": "يعني carbon تنتين تلاتة أربعة على لمرة اتنين ايش موجود عندكم؟ فينوكسي يعني O phenyl OH OHANA CH3 CH2 CH3 الآن انا برسم المركب بعدين بشوفه اذا طلع R كان بيها ماطلعش R", "tokens": [40228, 22653, 5954, 6055, 29399, 9957, 6055, 1211, 9307, 3660, 5551, 25513, 27884, 15844, 32767, 25720, 1975, 2655, 1863, 9957, 1975, 1829, 8592, 3714, 29245, 23328, 43242, 24793, 22807, 8978, 1863, 2407, 4117, 3794, 1829, 37495, 22653, 422, 7279, 5088, 13931, 13931, 21429, 5995, 18, 5995, 17, 5995, 18, 6024, 48506, 1975, 8315, 4724, 2288, 38251, 9673, 31747, 3555, 39182, 9957, 4724, 8592, 38688, 3224, 1975, 15730, 23032, 1211, 3615, 497, 25961, 4724, 1829, 11296, 19446, 9566, 1211, 3615, 8592, 497], "avg_logprob": -0.263338401186757, "compression_ratio": 1.4126984126984128, "no_speech_prob": 0.0, "words": [{"start": 2499.56, "end": 2499.96, "word": "يعني", "probability": 0.93994140625}, {"start": 2499.96, "end": 2500.66, "word": " carbon", "probability": 0.55859375}, {"start": 2500.66, "end": 2501.7, "word": " تنتين", "probability": 0.7813313802083334}, {"start": 2501.7, "end": 2502.56, "word": " تلاتة", "probability": 0.9219970703125}, {"start": 2502.56, "end": 2503.2, "word": " أربعة", "probability": 0.8445638020833334}, {"start": 2503.2, "end": 2503.8, "word": " على", "probability": 0.765625}, {"start": 2503.8, "end": 2504.18, "word": " لمرة", "probability": 0.6177978515625}, {"start": 2504.18, "end": 2504.82, "word": " اتنين", "probability": 0.824462890625}, {"start": 2504.82, "end": 2505.6, "word": " ايش", "probability": 0.7565104166666666}, {"start": 2505.6, "end": 2506.06, "word": " موجود", "probability": 0.9786783854166666}, {"start": 2506.06, "end": 2506.82, "word": " عندكم؟", "probability": 0.7901204427083334}, {"start": 2506.82, "end": 2508.24, "word": " فينوكسي", "probability": 0.751220703125}, {"start": 2508.24, "end": 2508.52, "word": " يعني", "probability": 0.76904296875}, {"start": 2508.52, "end": 2508.88, "word": " O", "probability": 0.595703125}, {"start": 2508.88, "end": 2509.58, "word": " phenyl", "probability": 0.5126953125}, {"start": 2509.58, "end": 2511.12, "word": " OH", "probability": 0.740234375}, {"start": 2511.12, "end": 2512.08, "word": " OHANA", "probability": 0.49072265625}, {"start": 2512.08, "end": 2513.62, "word": " CH3", "probability": 0.91162109375}, {"start": 2513.62, "end": 2514.68, "word": " CH2", "probability": 0.90185546875}, {"start": 2514.68, "end": 2515.82, "word": " CH3", "probability": 0.964111328125}, {"start": 2515.82, "end": 2516.9, "word": " الآن", "probability": 0.7003173828125}, {"start": 2516.9, "end": 2517.1, "word": " انا", "probability": 0.7178955078125}, {"start": 2517.1, "end": 2517.5, "word": " برسم", "probability": 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هذي تلاتة مبين اس و هذي على الجانب اذا هذا فعلا الار ايزو مار عندي سايكلو بنتين هاي السايكلو بنتين خليني ارسمه بهذا الشكل", "tokens": [3555, 3615, 4117, 3794, 1975, 1829, 3714, 7435, 2304, 45367, 6055, 7649, 1829, 42963, 45164, 10874, 36081, 6055, 9566, 1211, 34268, 47356, 9122, 33911, 3714, 3555, 9957, 8032, 8848, 1829, 36764, 24401, 8032, 8848, 1829, 1975, 2655, 1863, 9957, 8032, 8848, 1829, 6055, 1211, 9307, 3660, 3714, 3555, 9957, 24525, 4032, 8032, 8848, 1829, 15844, 25724, 7649, 3555, 1975, 15730, 23758, 6156, 3615, 15040, 2423, 9640, 1975, 1829, 11622, 2407, 3714, 9640, 18871, 16254, 8608, 47302, 28820, 2407, 4724, 29399, 9957, 8032, 47302, 21136, 47302, 28820, 2407, 4724, 29399, 9957, 16490, 1211, 9957, 1829, 1975, 2288, 38251, 3224, 39627, 15730, 25124, 28820], "avg_logprob": -0.307949022760669, "compression_ratio": 1.9883720930232558, "no_speech_prob": 0.0, "words": [{"start": 2522.81, "end": 2523.41, "word": "بعكس", "probability": 0.74102783203125}, {"start": 2523.41, "end": 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{"start": 2533.11, "end": 2533.55, "word": " فعلا", "probability": 0.9742838541666666}, {"start": 2533.55, "end": 2534.93, "word": " الار", "probability": 0.5101318359375}, {"start": 2534.93, "end": 2535.43, "word": " ايزو", "probability": 0.5032958984375}, {"start": 2535.43, "end": 2535.65, "word": " مار", "probability": 0.781005859375}, {"start": 2535.65, "end": 2538.59, "word": " عندي", "probability": 0.6463623046875}, {"start": 2538.59, "end": 2539.41, "word": " سايكلو", "probability": 0.65557861328125}, {"start": 2539.41, "end": 2540.47, "word": " بنتين", "probability": 0.94189453125}, {"start": 2540.47, "end": 2542.33, "word": " هاي", "probability": 0.522216796875}, {"start": 2542.33, "end": 2542.93, "word": " السايكلو", "probability": 0.79852294921875}, {"start": 2542.93, "end": 2543.43, "word": " بنتين", "probability": 0.9261067708333334}, {"start": 2543.43, "end": 2543.81, "word": " خليني", "probability": 0.8211669921875}, {"start": 2543.81, "end": 2544.31, "word": " ارسمه", "probability": 0.8828125}, {"start": 2544.31, "end": 2544.77, "word": " بهذا", "probability": 0.96826171875}, {"start": 2544.77, "end": 2545.29, "word": " الشكل", "probability": 0.989990234375}], "temperature": 1.0}, {"id": 98, "seek": 257217, "start": 2546.13, "end": 2572.17, "text": "cyclopentane واحد اتنين تلاتة اربعة خمسة على نمرة تلاتة واربعة شو بدي احط كلور وكلور بالزويك أسد C double bond O OH وهنا ال formal C double bond OH هذا ميتا", "tokens": [1344, 66, 752, 22786, 1929, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 15844, 8717, 2304, 25720, 6055, 1211, 9307, 3660, 4032, 9640, 3555, 27884, 13412, 2407, 4724, 16254, 1975, 5016, 9566, 9122, 1211, 13063, 4032, 28820, 13063, 20666, 11622, 45865, 4117, 5551, 3794, 3215, 383, 3834, 6086, 422, 13931, 37037, 8315, 2423, 9860, 383, 3834, 6086, 13931, 23758, 3714, 36081, 995], "avg_logprob": -0.3111979245311684, "compression_ratio": 1.4451219512195121, "no_speech_prob": 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" بدي", "probability": 0.7281494140625}, {"start": 2552.21, "end": 2552.63, "word": " احط", "probability": 0.9226888020833334}, {"start": 2552.63, "end": 2554.27, "word": " كلور", "probability": 0.6844889322916666}, {"start": 2554.27, "end": 2554.93, "word": " وكلور", "probability": 0.742919921875}, {"start": 2554.93, "end": 2558.95, "word": " بالزويك", "probability": 0.649169921875}, {"start": 2558.95, "end": 2559.91, "word": " أسد", "probability": 0.7569986979166666}, {"start": 2559.91, "end": 2562.09, "word": " C", "probability": 0.293701171875}, {"start": 2562.09, "end": 2562.35, "word": " double", "probability": 0.31201171875}, {"start": 2562.35, "end": 2562.69, "word": " bond", "probability": 0.92041015625}, {"start": 2562.69, "end": 2563.23, "word": " O", "probability": 0.88671875}, {"start": 2563.23, "end": 2564.51, "word": " OH", "probability": 0.5947265625}, {"start": 2564.51, "end": 2564.97, "word": " وهنا", "probability": 0.666259765625}, {"start": 2564.97, "end": 2565.15, "word": " ال", "probability": 0.74853515625}, {"start": 2565.15, "end": 2565.71, "word": " formal", "probability": 0.55517578125}, {"start": 2565.71, "end": 2566.19, "word": " C", "probability": 0.63916015625}, {"start": 2566.19, "end": 2567.01, "word": " double", "probability": 0.89404296875}, {"start": 2567.01, "end": 2567.35, "word": " bond", "probability": 0.97119140625}, {"start": 2567.35, "end": 2568.29, "word": " OH", "probability": 0.67138671875}, {"start": 2568.29, "end": 2571.11, "word": " هذا", "probability": 0.84228515625}, {"start": 2571.11, "end": 2572.17, "word": " ميتا", "probability": 0.585205078125}], "temperature": 1.0}, {"id": 99, "seek": 260216, "start": 2573.4, "end": 2602.16, "text": "ميتا أو بارا هذا موضوع بسيط هذا المركب Cyclopentane شو هذه المجموعة؟ Isobutyl Isobutyl Cyclopentane هذا كحول ألكين من وين الترقيم؟ من عند الكحول يعني هذا", "tokens": [2304, 36081, 995, 34051, 4724, 9640, 995, 23758, 3714, 2407, 11242, 45367, 4724, 3794, 1829, 9566, 23758, 9673, 31747, 3555, 49173, 404, 317, 1929, 13412, 2407, 29538, 9673, 7435, 2304, 2407, 27884, 22807, 286, 539, 5955, 5088, 286, 539, 5955, 5088, 49173, 404, 317, 1929, 23758, 9122, 5016, 12610, 5551, 1211, 4117, 9957, 9154, 4032, 9957, 16712, 2288, 4587, 32640, 22807, 9154, 43242, 33251, 5016, 12610, 37495, 22653, 23758], "avg_logprob": -0.24575893240315574, "compression_ratio": 1.50625, "no_speech_prob": 0.0, "words": [{"start": 2573.4, "end": 2573.98, "word": "ميتا", "probability": 0.6168619791666666}, {"start": 2573.98, "end": 2574.14, "word": " أو", "probability": 0.76025390625}, {"start": 2574.14, "end": 2574.4, "word": " بارا", "probability": 0.9529622395833334}, {"start": 2574.4, "end": 2574.62, "word": " هذا", "probability": 0.74560546875}, {"start": 2574.62, "end": 2575.02, "word": " موضوع", "probability": 0.9725341796875}, {"start": 2575.02, "end": 2575.56, "word": " بسيط", "probability": 0.9918212890625}, {"start": 2575.56, "end": 2577.62, "word": " هذا", "probability": 0.728515625}, {"start": 2577.62, "end": 2581.02, "word": " المركب", "probability": 0.84326171875}, {"start": 2581.02, "end": 2583.64, "word": " Cyclopentane", "probability": 0.616943359375}, {"start": 2583.64, "end": 2583.84, "word": " شو", "probability": 0.714111328125}, {"start": 2583.84, "end": 2584.04, "word": " هذه", "probability": 0.4111328125}, {"start": 2584.04, "end": 2586.0, "word": " المجموعة؟", "probability": 0.851806640625}, {"start": 2586.0, "end": 2587.66, "word": " Isobutyl", "probability": 0.7889404296875}, {"start": 2587.66, "end": 2590.12, "word": " Isobutyl", "probability": 0.837646484375}, {"start": 2590.12, "end": 2592.52, "word": " Cyclopentane", "probability": 0.813232421875}, {"start": 2592.52, "end": 2595.68, "word": " هذا", "probability": 0.92578125}, {"start": 2595.68, "end": 2596.26, "word": " كحول", "probability": 0.97314453125}, {"start": 2596.26, "end": 2596.94, "word": " ألكين", "probability": 0.55242919921875}, {"start": 2596.94, "end": 2597.38, "word": " من", "probability": 0.837890625}, {"start": 2597.38, "end": 2597.6, "word": " وين", "probability": 0.84228515625}, {"start": 2597.6, "end": 2599.1, "word": " الترقيم؟", "probability": 0.95791015625}, {"start": 2599.1, "end": 2600.08, "word": " من", "probability": 0.96826171875}, {"start": 2600.08, "end": 2600.28, "word": " عند", "probability": 0.98828125}, {"start": 2600.28, "end": 2601.02, "word": " الكحول", "probability": 0.9951171875}, {"start": 2601.02, "end": 2601.64, "word": " يعني", "probability": 0.873779296875}, {"start": 2601.64, "end": 2602.16, "word": " هذا", "probability": 0.935546875}], "temperature": 1.0}, {"id": 100, "seek": 263175, "start": 2605.67, "end": 2631.75, "text": "بيوتين بيوت two in one all و إيش بيحمل بعد هى two bromo فيه زده E لحظوا هنا ال brom و هنا الميثل ال brom أعلى من الكربون و الميثل أعلى من ال H إذا هذا E هذا أسيتوفينون", "tokens": [21292, 35473, 9957, 4724, 1829, 35473, 732, 294, 472, 439, 4032, 11933, 1829, 8592, 4724, 1829, 35571, 1211, 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{"start": 2613.07, "end": 2613.45, "word": " و", "probability": 0.65576171875}, {"start": 2613.45, "end": 2613.69, "word": " إيش", "probability": 0.63427734375}, {"start": 2613.69, "end": 2614.23, "word": " بيحمل", "probability": 0.98291015625}, {"start": 2614.23, "end": 2614.55, "word": " بعد", "probability": 0.705078125}, {"start": 2614.55, "end": 2615.35, "word": " هى", "probability": 0.5159912109375}, {"start": 2615.35, "end": 2616.29, "word": " two", "probability": 0.50927734375}, {"start": 2616.29, "end": 2617.11, "word": " bromo", "probability": 0.5076904296875}, {"start": 2617.11, "end": 2617.83, "word": " فيه", "probability": 0.4443359375}, {"start": 2617.83, "end": 2618.49, "word": " زده", "probability": 0.9029947916666666}, {"start": 2618.49, "end": 2618.81, "word": " E", "probability": 0.62451171875}, {"start": 2618.81, "end": 2620.69, "word": " لحظوا", "probability": 0.7293701171875}, {"start": 2620.69, "end": 2620.89, "word": " هنا", "probability": 0.78955078125}, {"start": 2620.89, "end": 2621.05, "word": " ال", "probability": 0.83154296875}, {"start": 2621.05, "end": 2621.39, "word": " brom", "probability": 0.919921875}, {"start": 2621.39, "end": 2621.77, "word": " و", "probability": 0.51611328125}, {"start": 2621.77, "end": 2622.07, "word": " هنا", "probability": 0.8076171875}, {"start": 2622.07, "end": 2623.09, "word": " الميثل", "probability": 0.72314453125}, {"start": 2623.09, "end": 2623.71, "word": " ال", "probability": 0.87451171875}, {"start": 2623.71, "end": 2623.97, "word": " brom", "probability": 0.97216796875}, {"start": 2623.97, "end": 2624.31, "word": " أعلى", "probability": 0.9651692708333334}, {"start": 2624.31, "end": 2624.49, "word": " من", "probability": 0.99560546875}, {"start": 2624.49, "end": 2625.07, "word": " الكربون", "probability": 0.735595703125}, {"start": 2625.07, "end": 2625.21, "word": " و", "probability": 0.8193359375}, {"start": 2625.21, "end": 2625.55, "word": " الميثل", "probability": 0.973876953125}, {"start": 2625.55, "end": 2625.85, "word": " أعلى", "probability": 0.9697265625}, {"start": 2625.85, "end": 2626.09, "word": " من", "probability": 0.99609375}, {"start": 2626.09, "end": 2626.29, "word": " ال", "probability": 0.9150390625}, {"start": 2626.29, "end": 2626.55, "word": " H", "probability": 0.8544921875}, {"start": 2626.55, "end": 2626.85, "word": " إذا", "probability": 0.81005859375}, {"start": 2626.85, "end": 2627.27, "word": " هذا", "probability": 0.447509765625}, {"start": 2627.27, "end": 2628.01, "word": " E", "probability": 0.75439453125}, {"start": 2628.01, "end": 2630.47, "word": " هذا", "probability": 0.77734375}, {"start": 2630.47, "end": 2631.75, "word": " أسيتوفينون", "probability": 0.8053385416666666}], "temperature": 1.0}, {"id": 101, "seek": 266127, "start": 2654.25, "end": 2661.27, "text": "مش كتير معنا وقت ان شاء الله بخمس دقائق نمشي أسرع بدنا خمس دقائق نمشي أسرع شوية", "tokens": [2304, 8592, 9122, 2655, 13546, 20449, 8315, 4032, 38149, 16472, 13412, 16606, 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"ar", "language_probability": 1.0, "duration": 3059.972, "duration_after_vad": 2821.7949999999896} \ No newline at end of file diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..e5bf93dcb8a75119f849750f6e18ea73977c01cd --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_postprocess.srt @@ -0,0 +1,1440 @@ +1 +00:00:21,240 --> 00:00:26,260 +بسم الله الرحمن الرحيم موضوعنا اليوم عن ال + +2 +00:00:26,260 --> 00:00:31,560 +stereochemistry ربما يعني انتوا اتشوقتوا اليها لان + +3 +00:00:31,560 --> 00:00:37,220 +احنا من اول محاضرة لما اتكلمنا عن المتشكلات او ال + +4 +00:00:37,220 --> 00:00:43,960 +isomers قسمناهم وقلنا هم نوعين اساسيين structural + +5 +00:00:43,960 --> 00:00:48,920 +isomers او constitutional isomers سمناهم و stereo + +6 +00:00:48,920 --> 00:00:54,250 +isomersالان هذا التصنيف اللى بنشوفه باللوحة + +7 +00:00:54,250 --> 00:01:01,030 +التصنيف العام ل .. خلينا نقول ال isomers أخدنا جزء + +8 +00:01:01,030 --> 00:01:06,510 +منه اللى هو إيش معنى isomers بشكل عام المركبات + +9 +00:01:06,510 --> 00:01:10,750 +اللى لها نفس الصيغة الجزائية ولكن بتختلف في الشكل + +10 +00:01:10,750 --> 00:01:16,070 +الان قسمت إلى نوعين النوع الأول ال structural + +11 +00:01:16,070 --> 00:01:21,770 +isomers المركباتاللي بتختلف في مواقع ارتباط الذرات + +12 +00:01:21,770 --> 00:01:25,310 +يعني فيها different bonding وقولنا هذا different + +13 +00:01:25,310 --> 00:01:29,350 +bonding بيقدر إلى انه يكون لها different names ولو + +14 +00:01:29,350 --> 00:01:33,430 +على اقل تقدير في الرقم اللي بيحدد مثلا Substituent + +15 +00:01:33,430 --> 00:01:37,470 +يعني على سبيل المثال لما نقول بروبين امكون من تلت + +16 +00:01:37,470 --> 00:01:41,750 +ذرات الآن على الموقع الأول Clor أو على الموقع + +17 +00:01:41,750 --> 00:01:45,430 +التاني Clorهذا صار different bonding يعني أي حد + +18 +00:01:45,430 --> 00:01:49,670 +يقول هدولة شو بيفرقوا على البعض، هيقول هذا بروبين + +19 +00:01:49,670 --> 00:01:52,990 +تلت ذرات على الموقع الأول كلور صار اسمه one + +20 +00:01:52,990 --> 00:01:57,190 +chloroborbine التاني على الموقع اتنين two + +21 +00:01:57,190 --> 00:02:03,100 +chloroborbine هدولة اسمين مختلفينالان الشيء التاني + +22 +00:02:03,100 --> 00:02:07,900 +في ال isomers اللى حتى ايضا بدنا فيه اللى هو ال + +23 +00:02:07,900 --> 00:02:12,900 +stereo isomers المركبات اللى بتكون لها نفس + +24 +00:02:12,900 --> 00:02:17,840 +الارتباط ولكن اختلاف في شكلها بالفراغ ولذلك احنا + +25 +00:02:17,840 --> 00:02:21,400 +قولنا ال stereo isomers ال atoms they have the + +26 +00:02:21,400 --> 00:02:26,970 +same constitutiondifferent arrangement in space + +27 +00:02:26,970 --> 00:02:31,590 +بدأنا فيهم الحقيقة لما احنا أخدنا مراكبات ال sis + +28 +00:02:31,590 --> 00:02:36,990 +والترانس يعني مثلا عندنا اثين على موقع واحد كلور + +29 +00:02:36,990 --> 00:02:40,890 +هاي اثين جزئي ب double bond على موقع واحد كلور + +30 +00:02:40,890 --> 00:02:45,030 +وعلى موقع اتنين كلور وبناء على ذلك شو هيصير اسمه + +31 +00:02:45,030 --> 00:02:51,130 +one two dichloro ethaneSame bondage الآن يا تورا + +32 +00:02:51,130 --> 00:02:57,650 +هدولة ذرتين لchlor جايين على جهة واحدة ولا جايين + +33 +00:02:57,650 --> 00:03:01,770 +على جهتين متعاكستين صيرنا نضيف ال prefix أو + +34 +00:03:01,770 --> 00:03:08,130 +البادئة اللي هي cis وtrans فالcis وtrans هنا ما + +35 +00:03:08,130 --> 00:03:13,470 +بتعني مواقع الذرات مواقع الذرات حدد one two ع ذرة + +36 +00:03:13,470 --> 00:03:18,420 +واحد وع ذرة اتنينSame bonding, same name المركب + +37 +00:03:18,420 --> 00:03:22,420 +اسمه one two dichloroethane لكن الفرق ال + +38 +00:03:22,420 --> 00:03:28,600 +arrangement in space مع بعض و لا ضد بعض و عرفنا ان + +39 +00:03:28,600 --> 00:03:34,040 +احنا بنستعمل كلمة cess او الأعام منها z للتعبير عن + +40 +00:03:34,040 --> 00:03:40,260 +معنى مع بعض و ال transاو ايه؟ ضد بعض واضح هذا + +41 +00:03:40,260 --> 00:03:43,860 +الكلام؟ الان لما أخذنا ال sis و ال trans قولنا + +42 +00:03:43,860 --> 00:03:47,840 +هدوله نوع او احد انواع ال stereo isomers اللي + +43 +00:03:47,840 --> 00:03:52,700 +سمناهم ايش؟ they are stereomersالان شو يعني + +44 +00:03:52,700 --> 00:03:56,980 +diastereomers ال diastereomers ببساطة قلنا عنهم + +45 +00:03:56,980 --> 00:04:00,660 +non mirror image stereoisomers يعني stereoisomers + +46 +00:04:00,660 --> 00:04:04,820 +لو حطيت واحد جبال التاني و تخيلت انه في امرأة + +47 +00:04:04,820 --> 00:04:09,460 +بينهم بيكونوا مش صورة بعض في المرأة non mirror + +48 +00:04:09,460 --> 00:04:14,500 +image stereoisomers الان موضوعنا في هذا الفصل على + +49 +00:04:14,500 --> 00:04:19,930 +النوع التاني يعني كل الكلام اللي اتكلمتهمقدمة لكن + +50 +00:04:19,930 --> 00:04:24,570 +موضوعنا على النوع التاني اللي اسمه enantiomers + +51 +00:04:24,570 --> 00:04:28,750 +النوع التاني اللي اسمه enantiomers ال enantiomers + +52 +00:04:28,750 --> 00:04:34,970 +قبل ما تكون ظاهرة موجودة في الكيميا و في ال stereo + +53 +00:04:34,970 --> 00:04:40,530 +isomers هي ظاهرة موجودة في الحياة ربما من تبهينها + +54 +00:04:40,530 --> 00:04:46,580 +الناس او لأالله أعلم لكن لما نذكرها و نفهمها + +55 +00:04:46,580 --> 00:04:51,200 +بالحياة بعد هيك بنقدر نفهمها بالكيميا يعني اللي + +56 +00:04:51,200 --> 00:04:56,280 +بده يفهم إيش معناه in and sumars بدوش يظن أن هذه + +57 +00:04:56,280 --> 00:05:00,840 +الكلمة هي كلمة كيميائية لأ كلمة in and sumars هي + +58 +00:05:00,840 --> 00:05:06,840 +كلمة حياتية يعني ممكن في الامتحان أرسمه to in and + +59 +00:05:06,840 --> 00:05:12,620 +sumarsمن الحياة لا بد يبين فيها روابط ولا بد يبين + +60 +00:05:12,620 --> 00:05:17,300 +فيها ذرات ولا جزيئات ولا ما يحزنون ال enantiomers + +61 +00:05:17,300 --> 00:05:22,700 +ظاهرة حياتية ايش اصل هذه الظاهرة اصل هذه الظاهرة + +62 +00:05:22,700 --> 00:05:29,710 +تنطلق من الإيدينلحظوا الإيد اليمين والإيد الشمال، + +63 +00:05:29,710 --> 00:05:34,930 +لو أنا حطيت هدول الاتين بهذا الشكل أقبال بعض، + +64 +00:05:34,930 --> 00:05:40,900 +هلاحظ أن هدول الاتين صورت بعض في المرقاةواضح؟ يعني + +65 +00:05:40,900 --> 00:05:44,920 +لو هنا في مراية بدل الإيد الشمال، إيش اللي هيبين + +66 +00:05:44,920 --> 00:05:49,960 +فيها؟ نفس هذه، لو كنت حاطط لشمال، لو في مراية، إيش + +67 +00:05:49,960 --> 00:05:54,160 +هيبين فيها نفس هذه؟ الآن صورة المرأة اللي احنا + +68 +00:05:54,160 --> 00:06:01,510 +سمناها mirror image سابقاإيش بتمتاز؟ إن كل نقطة + +69 +00:06:01,510 --> 00:06:06,910 +فيها عكس التاني عكس الأصل يعني أنا لما بحط الإيد + +70 +00:06:06,910 --> 00:06:12,290 +اتطلع على الكف اللي موجود عنده بأي اتجاه؟ بهذا + +71 +00:06:12,290 --> 00:06:17,830 +الاتجاه واضح؟ الآن هذا صورته في المرأة لوين؟ + +72 +00:06:17,830 --> 00:06:21,710 +بالاتجاه المعاكس ولذلك لما الإنسان نفسه كمان بيقف + +73 +00:06:21,710 --> 00:06:27,710 +قدام المراية بشوف صورتهمعنى ذلك إن كل ما في المرأة + +74 +00:06:27,710 --> 00:06:32,450 +عكس الوضع اللي هو واقف الإنسان فيه، واضح؟ الآن إنه + +75 +00:06:32,450 --> 00:06:36,330 +ملقتين mirror image هذا أمر طبيعي، لأ وأمر طبيعي + +76 +00:06:36,330 --> 00:06:41,770 +أكثر إن كل شيء في الدنيا كل شيء في الدنيا له + +77 +00:06:41,770 --> 00:06:45,850 +mirror image، يعني هذا مش موضوع خلافي إطلاقا، يعني + +78 +00:06:45,850 --> 00:06:52,470 +لو جيبنا قدام المرايا حجرأو كرة أو أرنب أو بني آدم + +79 +00:06:52,470 --> 00:06:58,710 +أو ملك أو فقير وقفناه قدام المراية له mirror image + +80 +00:06:58,710 --> 00:07:03,470 +يعني بنقدر نصيغي الكلام for every object there is + +81 +00:07:03,470 --> 00:07:07,530 +a mirror imageكل جسم في الدنيا له mirror image + +82 +00:07:07,530 --> 00:07:11,890 +تمام؟ إذا بيصير وين الجديد؟ إذا كل إشي في الدنيا + +83 +00:07:11,890 --> 00:07:16,770 +له mirror image الآن بيجي الشيء الجديد اللي بينبني + +84 +00:07:16,770 --> 00:07:21,670 +عليه فهمنا لهذا ال chapter هل يا تورا الصورة في + +85 +00:07:21,670 --> 00:07:27,490 +المرآة تنطبق على الأصل ولا لأ؟يعني لو أنا إجيت + +86 +00:07:27,490 --> 00:07:32,170 +قولت ال .. ال tail هدولة they are mirror images هل + +87 +00:07:32,170 --> 00:07:37,430 +يا ترى هذه الإيد بتنطبق على هذه الإيد ولا لأ؟ معنى + +88 +00:07:37,430 --> 00:07:45,030 +تنطبق على super imposible super imposible + +89 +00:07:46,690 --> 00:07:51,710 +واضح؟ هل يا تورا الإيد اليمين و الإيد الشمال + +90 +00:07:51,710 --> 00:07:56,250 +بينطبقوا على بعض من بعض ولا لأ؟ إيش إنتوا رأيكم من + +91 +00:07:56,250 --> 00:08:03,770 +خبرتكوا الحياتية؟ كويس، الآن لاحظوا الشعب + +92 +00:08:03,770 --> 00:08:12,170 +الفلسطيني لأنه عاش طفولة صعبةلم يقدر له أن يستمتع + +93 +00:08:12,170 --> 00:08:19,410 +بطفولته ولذلك لم يستطع أن يجيب على سؤال بسيط مثل + +94 +00:08:19,410 --> 00:08:29,270 +هذا السؤال لو استمتعتنا بطفولتي كنا لعرفتنا إيش + +95 +00:08:29,270 --> 00:08:34,350 +أنه لما بنيجي نركب العروسة الصغيرة إلها التين + +96 +00:08:34,350 --> 00:08:40,380 +ماقدرش أحط هذه محل هذهالعروسة الصغيرة معمولة بتنفك + +97 +00:08:40,380 --> 00:08:44,940 +الاتين والرجلتين ولا لأ؟ لما بتيجوا تركبوها هذه + +98 +00:08:44,940 --> 00:08:48,220 +العروسة الصغيرة جسم اللي بيلعبوا فيها الأطفال + +99 +00:08:48,220 --> 00:08:53,900 +ويلها إيد وإيد ورجل ورجل هل يا تورا عمركوا جربتوا + +100 +00:08:53,900 --> 00:08:58,300 +وهي مفكوكة تركبوها تاني؟ هل بتيجي الإيد لشمال محل + +101 +00:08:58,300 --> 00:09:03,130 +اليمين؟ لأبالتأكيد لأ بنعكس الأصبع الآن تخيلوا أن + +102 +00:09:03,130 --> 00:09:06,950 +هذه الإيد اللي عندى اليمين لو أنا بدأ أحط الشمال + +103 +00:09:06,950 --> 00:09:10,790 +مكانها تماما و الكف لجوه بده يكون هاي بدأ أجيب + +104 +00:09:10,790 --> 00:09:15,270 +الشمال لحظوا هذا الأصبع وين رايح هذا الأصبع وين + +105 +00:09:15,270 --> 00:09:20,310 +رايح ولذلك لا يمكن لو إجيتوا تركبوا الرجلين محال + +106 +00:09:20,310 --> 00:09:26,130 +بعض هتلاحظوا أن رجل للأمام و رجل للخلف فالاتين + +107 +00:09:27,470 --> 00:09:31,670 +و كل كوا عندكم لسه ما زال من بقايا الطفولة شيء على + +108 +00:09:31,670 --> 00:09:38,280 +أرض الواقع أو في الذاكرة فجربوا .. فجربواالان .. + +109 +00:09:38,280 --> 00:09:43,500 +هذه الان بتصبح أساس لظاهرة .. بتصبح أساس لظاهرة + +110 +00:09:43,500 --> 00:09:50,020 +أنه في أحيانا الصورة في المرأة و الأصل يكونوا غير + +111 +00:09:50,020 --> 00:09:54,020 +متطابقين طبعا ممكن الصورة و الأصل تكون متطابقة + +112 +00:09:54,020 --> 00:10:00,380 +يعني لو إنسان مثلا جاب هذا القلمحطه هنا الصورة + +113 +00:10:00,380 --> 00:10:05,560 +تبعته جلم تاني هذه صورة هذا أصل ينطبق على بعض لو + +114 +00:10:05,560 --> 00:10:12,020 +الإنسان جاب كرةأيه كويس؟ حطها أمام المرآة، شو + +115 +00:10:12,020 --> 00:10:16,820 +هيشوف؟ كرة، الكورتين ينطبقوا مكان بعض، بمعنى آخر + +116 +00:10:16,820 --> 00:10:21,020 +لو كان فيه قالب محطوطة في الكورة هذه و قالب محطوطة + +117 +00:10:21,020 --> 00:10:23,800 +في الكورة الثانية، بقدر أحط هذه محل هذه و بقدر أحط + +118 +00:10:23,800 --> 00:10:29,000 +هذه محل هذه، لكن تخيلوا معي لو كان الإنسان بيشتري + +119 +00:10:29,000 --> 00:10:33,660 +عروسة صغيرة اللي بيلعبوا فيها، والاتنين محطوطين في + +120 +00:10:33,660 --> 00:10:39,730 +الجالب الكلكل المفحورهذه للإيد اليمين مفحورة جوا، + +121 +00:10:39,730 --> 00:10:44,410 +هذه للإيد التانية أرفع هذه الإيد، بيقدر يحط هذه + +122 +00:10:44,410 --> 00:10:48,690 +مكانها؟ مش ممكن، لحظوا هذه الفحر وين الأصبع جاي + +123 +00:10:48,690 --> 00:10:52,810 +فيها؟ بهذا الاتجاه، طبعا ما تحطوهاش بالعكس، معنى + +124 +00:10:52,810 --> 00:10:57,630 +التطابق أن كل نقطة تنطبق محل إيش؟ التانية، واضح؟ + +125 +00:10:57,630 --> 00:11:02,060 +هل بنقدر نحط هذه محل هذه؟بنقدرش نحطهم محال بعض + +126 +00:11:02,060 --> 00:11:08,400 +الان هذه الظاهرة .. هذه الظاهرة لأنها أساس لأشياء + +127 +00:11:08,400 --> 00:11:12,980 +كتيرة أعطوها اسم في الكيميا سموها ظاهرة ايش ال + +128 +00:11:12,980 --> 00:11:21,380 +handedness ظاهرة ال handedness ظاهرة ال handedness + +129 +00:11:21,380 --> 00:11:28,200 +اللي هي عدم تطابق الأصل مع الصورة الان لو بدنا + +130 +00:11:28,200 --> 00:11:35,620 +أنصيهاباللغة الإنقليزية بدنا نقول بيكون عند non + +131 +00:11:35,620 --> 00:11:40,020 +-superimposable mirror image stereoisomers لاحظوا + +132 +00:11:40,020 --> 00:11:44,500 +معي non-superimposable غير متطابق non + +133 +00:11:44,500 --> 00:11:47,720 +-superimposable mirror image stereoisomers يعني + +134 +00:11:47,720 --> 00:11:53,760 +صور في المرأة غير متطابقة الأصل والصورة ايش ماله + +135 +00:11:53,760 --> 00:11:57,520 +غير متطابق non-superimposable غير متطابق mirror + +136 +00:11:57,520 --> 00:12:04,920 +imageصورة مع الأصل واضح الصورة لا تنطبق على الأصل + +137 +00:12:04,920 --> 00:12:12,060 +الان كل ما كان مثل الإيدين بنطبق عليه الظاهرة الان + +138 +00:12:12,060 --> 00:12:16,500 +كل شغلتين مثل الإيدين اعطوهم اسم سموهم enantiomers + +139 +00:12:16,500 --> 00:12:23,690 +فالاتين enantiomersواضح؟ فعلاقة الانانشومارز بلغة + +140 +00:12:23,690 --> 00:12:29,710 +بسيطة هي أصل وصورة في المرآة ولكنهم غير متطابقين + +141 +00:12:29,710 --> 00:12:33,790 +non superimposable mirror images أو mirror images + +142 +00:12:33,790 --> 00:12:40,350 +stereo isomers الآن أعطوني عد أمثلة من الحياة غير + +143 +00:12:40,350 --> 00:12:49,130 +الإتين الرجلتين صح الرجلتين برضه مش متطابقين وكمان + +144 +00:12:50,730 --> 00:12:54,870 +ابواب السيارة، لاحظوا لما بيخرب مثلا الباب الأمامي + +145 +00:12:54,870 --> 00:12:58,150 +في السيارة، الواحد بيروح باشتري باب، أول سؤال + +146 +00:12:58,150 --> 00:13:04,330 +بينسأله من البيبيع، بدك الباب شمال ولا يمين؟ + +147 +00:13:04,330 --> 00:13:09,790 +كمان، إمريتين السيارة، الإمريات اللي على الجانب، + +148 +00:13:09,790 --> 00:13:12,870 +بيركبوا، في واحدة شمال، في واحدة يمين، مابيجيوش + +149 +00:13:12,870 --> 00:13:17,150 +التنتين محال بعض، كمان، لودان + +150 +00:13:18,370 --> 00:13:24,490 +واضح؟ كمان إذا شلحت هذه النضارة تخيلوا لو انت جزء + +151 +00:13:24,490 --> 00:13:29,200 +منكم درس بصريات طبية انت علوم صحة الآن صح؟هذه + +152 +00:13:29,200 --> 00:13:36,180 +النضارة مفكوكة هيكون عنده إيد و إيد و عدسة و عدسة + +153 +00:13:36,180 --> 00:13:41,000 +و هذا الجسم الصغير إله اسم انتعون النضارات تمام لو + +154 +00:13:41,000 --> 00:13:45,820 +فكتوهم و إجيتوا تركبوهم يعني بس بمفك صغير اشتغلتوا + +155 +00:13:45,820 --> 00:13:49,160 +على هذه النضارة هيصير عندكم من هذه قطعتين من هذه + +156 +00:13:49,160 --> 00:13:54,780 +قطعتين من هذه قطعتين تعالوا ركبوهم لو جربتوا تحطوا + +157 +00:13:54,780 --> 00:14:01,140 +هذه محل هذه و تركبوهم صح تطلع هذه لفوقواضح؟ و هاد + +158 +00:14:01,140 --> 00:14:04,600 +هتطلع على فوق، مش هيظبطه، لو جربتوا تحطوا العدسة + +159 +00:14:04,600 --> 00:14:08,580 +محل العدسة، مش هيظبط، لو جربتوا هاد محل هاد، مش + +160 +00:14:08,580 --> 00:14:13,400 +هيظبط، إذا كل هدولة، رغم إن أنا لو حطيت مرقابي هذا + +161 +00:14:13,400 --> 00:14:19,480 +الشكل، هذا الجزء و هذا الجزء، إيش معلهم؟صورة بعض + +162 +00:14:19,480 --> 00:14:23,660 +في المرأة صحيح صورة بعض في المرأة ولكنها غير + +163 +00:14:23,660 --> 00:14:28,820 +متطابقة إذا كل مكونات النضارة بيخضعوا لظاهرة إيش + +164 +00:14:28,820 --> 00:14:32,500 +ال handedness ال handedness كل مكونات النضارة in + +165 +00:14:32,500 --> 00:14:36,300 +anchomers يعني لو أنا جبتلكوا في الامتحان صورة إيد + +166 +00:14:36,300 --> 00:14:39,240 +النضارة هذه والإيد التانية وقلتلكوا ما العلاقة + +167 +00:14:39,240 --> 00:14:43,750 +بينهم بتقولولي they are anchomersواضح؟ they are + +168 +00:14:43,750 --> 00:14:49,850 +enantiomers الأحذية شو رأيكم فيهم؟ لاحظوا فكرة + +169 +00:14:49,850 --> 00:14:53,750 +الأحذية فكرة يعني مهمة عارفين ليش؟ لأن ال + +170 +00:14:53,750 --> 00:14:58,670 +enantiomers ببساطة للوهلة الأولى صعب أنكم تتميزوهم + +171 +00:14:58,670 --> 00:15:01,630 +وممكن تغلطوا فيهم أول ما بدنا أن تغلطوا في + +172 +00:15:01,630 --> 00:15:07,430 +الإيدين، مظبوط ولا لأ؟ الآن في المستقبل سواء + +173 +00:15:07,430 --> 00:15:10,750 +قابلته أو قابته + +174 +00:15:12,820 --> 00:15:17,720 +هتلاحظوا انه عشان الطفل الصغير اول ما بيبدأ يستعمل + +175 +00:15:17,720 --> 00:15:22,320 +الحذاء يفهم هذه الظاهرة بتضله حوالي اربع خمس ست + +176 +00:15:22,320 --> 00:15:24,540 +سنين لما هو بيجي يلبس الحذاء و انتوا قاعدينه + +177 +00:15:24,540 --> 00:15:28,600 +تقولوله شماله يمين طب هم اذا كانوا نفس الاشي ليش + +178 +00:15:28,600 --> 00:15:31,940 +مغلبين حالكوا و منشفين ريجها الطفل الصغير و + +179 +00:15:31,940 --> 00:15:39,080 +بتقولوله شماله يمين مؤمن الغلطان الطفل ولا انتوا + +180 +00:15:41,020 --> 00:15:45,120 +احنا بدنا نفهم الطفل لما بيجي بيلبس الحذاء مش ليه + +181 +00:15:45,120 --> 00:15:48,400 +لنهار الأب و الأم لأ هذي شمال، هذي يمين أول ما + +182 +00:15:48,400 --> 00:15:54,440 +بيبدأ؟ إذا عندكم قناعة أنه هذي و هذي مابيجوش مع + +183 +00:15:54,440 --> 00:16:02,740 +بعض، واضح؟ إذا الأحذية انان شمارز، الأحذية انان + +184 +00:16:02,740 --> 00:16:08,160 +شمارز أيضا، والجوارب انان شمارز، والشاطر اللي + +185 +00:16:08,160 --> 00:16:15,450 +بيعرف إيشيلبسهم صحي الظاهرة اشمالها كبيرة لاحظوا + +186 +00:16:15,450 --> 00:16:21,210 +معي وين بيبين اكثر اشي وين بيبين اكثر اشي ال + +187 +00:16:21,210 --> 00:16:26,970 +enantiomers عارفين وين لما ييجوا ال enantiomers + +188 +00:16:26,970 --> 00:16:31,430 +يتعاملوا مع enantiomers تاني وهذه فكرة كتير اساسية + +189 +00:16:31,430 --> 00:16:36,720 +في الكيميا يعني انتوا قلتوا القدمينEnhance + +190 +00:16:36,720 --> 00:16:40,440 +Shoemers يعني القدم اليمين و القدم الشمال صورة بعض + +191 +00:16:40,440 --> 00:16:44,960 +في المرأة ولكنها غير متطابقة صح ولا لأ؟ و الحذائن + +192 +00:16:44,960 --> 00:16:50,580 +Enhance Shoemers الآن أن الحذائن ممكن يستعملوا + +193 +00:16:50,580 --> 00:16:56,460 +استعمالات كتيرة مايفرجوش نهائيا يعني لو افترضنا + +194 +00:16:56,460 --> 00:17:01,100 +إنسان مثلا بيشتري خردة على الميزان بلاستيك عشان + +195 +00:17:01,100 --> 00:17:06,100 +يعملوا recyclingبيفرج معه إن هذا شمال ولا هذا + +196 +00:17:06,100 --> 00:17:13,800 +يمين؟ لأ، مظبوط ولا لأ؟ لو افترضنا إن إنسان بده + +197 +00:17:13,800 --> 00:17:20,440 +يستعمل الحذاء ليضرب به أعداء الله، صارت في + +198 +00:17:20,440 --> 00:17:25,440 +التاريخ، بيفرج معه إنه شمال ولا يمين؟ ولا جنب + +199 +00:17:25,440 --> 00:17:31,260 +الواجب؟جانب الواجب طيب السؤال عاد لو افترضنا انه + +200 +00:17:31,260 --> 00:17:36,480 +انسان بده يحط الرجلتين في الحذائل بيفرق معه ولا + +201 +00:17:36,480 --> 00:17:42,120 +لأ؟ وين افرقت؟ لما جبت انان شومارز مع انان شومارز + +202 +00:17:42,120 --> 00:17:45,960 +هذا الكلام بعد شوية وين هيجي يفرق معكم؟ لما ابدأ + +203 +00:17:45,960 --> 00:17:53,100 +انا اقول ان الجسم في أشياء مواد مستقبلات موجود + +204 +00:17:53,100 --> 00:17:59,210 +منها اتنينو الدواء موجود منه اتنين الان اذا اللي + +205 +00:17:59,210 --> 00:18:02,510 +في الجسم واحد هيجي على التنين اللي في الدواء اللي + +206 +00:18:02,510 --> 00:18:08,570 +هيتفق مع واحد و يختلف مع التاني هيكون اكثر تطبيق + +207 +00:18:08,570 --> 00:18:14,470 +لهذه المنطقة في ال biological system في الجسم لانه + +208 +00:18:14,470 --> 00:18:18,570 +هتبدو تلاحظوا ان الجزيئات الانزمات الكذا في منها + +209 +00:18:18,570 --> 00:18:23,390 +اتنينإنانشومارز والأدوية في منها إنانشومارز الآن + +210 +00:18:23,390 --> 00:18:28,790 +أي إنانشومارز أعطيه عشان يتفق مع اللي في الجسم هنا + +211 +00:18:28,790 --> 00:18:35,610 +بيصير إيش؟ بيصير الانتباه وأول ما الناس بتبدأ تغلط + +212 +00:18:35,610 --> 00:18:44,340 +مباشرة بتعمل إيش؟ مشكلة وصارت مشاكلضخمة جدا بل + +213 +00:18:44,340 --> 00:18:51,440 +مقاسي خليني في الأول أفرجيكم خلال فترة صغيرة كيف + +214 +00:18:51,440 --> 00:18:54,160 +هذه الظاهرة نفسها اللي قلنا ربع ساعة بنحكي عنها في + +215 +00:18:54,160 --> 00:18:57,900 +الحياة يمكن أن توجد في الكيميا وبعدين بنفرجيكم + +216 +00:18:57,900 --> 00:19:02,360 +المقاسي اللي موجودة من الخطأ في هذه الظاهرة في + +217 +00:19:02,360 --> 00:19:07,550 +المجال الطبي وغيرهالان هذه الظاهرة في الكيميا + +218 +00:19:07,550 --> 00:19:14,470 +بتوجد إذا كان في عندي جزيء في ذرة carbon تحمل أربع + +219 +00:19:14,470 --> 00:19:20,190 +مجموعات مختلفة واضح؟ يعني شرطها أن توجد carbon، + +220 +00:19:20,190 --> 00:19:25,730 +هاي ال carbon عندي تحمل كام مجموعة مختلفة؟ تحمل + +221 +00:19:25,730 --> 00:19:30,790 +أربع مجموعات مختلفة إذا وجدت، بعمل جزيء و صورته + +222 +00:19:30,790 --> 00:19:36,140 +خليني أتخيل، هاي carbonوبدي اعمل تحمل اربع مجموعات + +223 +00:19:36,140 --> 00:19:41,300 +مختلفة الان شايفينها بالالوان ولا لأ عشان نسهل على + +224 +00:19:41,300 --> 00:19:45,720 +حالنا و نفهم الموضوع ببساطة خليني اتخيل ان هذا + +225 +00:19:45,720 --> 00:19:52,200 +الكربون بتحمل يود ايش لون اليود في الدنيا ازرق و + +226 +00:19:52,200 --> 00:20:00,660 +كلور اخضر اخضر مصفر مظبوط ولا لأ و برومأحمر + +227 +00:20:00,660 --> 00:20:06,780 +بورتقالي أحمر بورتقالي إذا هذا الأزرق يود والأخضر + +228 +00:20:06,780 --> 00:20:11,920 +أكلور والأحمر إبروم اتخيلنا كأنا جزء الآن وهذا + +229 +00:20:11,920 --> 00:20:17,620 +هيدروجين طب الآن لو قلت لواحدة لو سمحت سمينا + +230 +00:20:17,620 --> 00:20:25,820 +المركب هذا اللي أنا ماسكه بإيدي شو هتسميه ذرد + +231 +00:20:25,820 --> 00:20:33,810 +كاربون واحدة بسرعةميتين؟ شو بتحمل؟مافيش غير الواحد + +232 +00:20:33,810 --> 00:20:41,350 +ما تقولوهوش إبرومو كلورو أيودو ميثيل و بنذكرهم + +233 +00:20:41,350 --> 00:20:45,530 +alphabetical مش هذي الف باقي التسمية يعني هذا + +234 +00:20:45,530 --> 00:20:50,690 +الجزيء لما تجيب الكياشو اسمه إبرومو كلورو أيودو + +235 +00:20:50,690 --> 00:20:55,550 +ميثيل في مشكلة لحد الآن؟ الآن لو عملت صورته في + +236 +00:20:55,550 --> 00:21:00,330 +المرقاة يعني مسكته زي هيك و جيبت كمان إبرومو + +237 +00:21:00,330 --> 00:21:01,170 +هيدروجيل + +238 +00:21:04,280 --> 00:21:09,440 +وعملت انتبهوا معي هدول التنين تماما صورة بعض في + +239 +00:21:09,440 --> 00:21:16,020 +المرأة ولا لأ واضح صورة بعض في المرأة مية في المية + +240 +00:21:16,020 --> 00:21:20,260 +طب لو قولنا له ده سميناها ده ده سميناها انت سميها + +241 +00:21:20,260 --> 00:21:21,320 +ده + +242 +00:21:26,260 --> 00:21:29,560 +برومو، كلورو، ايود وميثين برومو، كلورو، ايود + +243 +00:21:29,560 --> 00:21:33,660 +وميثين لاحظوا معي إجت الجملة العامة في تعريف ال + +244 +00:21:33,660 --> 00:21:36,900 +stereo isomers they have the same bonding يعني لو + +245 +00:21:36,900 --> 00:21:39,800 +واحدة هنا بتوصف هذا الجزء و واحدة هنا بتوصف هذا + +246 +00:21:39,800 --> 00:21:43,880 +الجزء هتقول carbon متصل في برومو، كلورو، يودو، + +247 +00:21:43,880 --> 00:21:48,490 +هيدروجين و اللي هناcarbon متصل فيه برومو كلورو + +248 +00:21:48,490 --> 00:21:53,250 +يودو هيدروجين اذا same bonding ولا لأ الان يا تورا + +249 +00:21:53,250 --> 00:21:57,550 +لو سألنا نفسنا السؤال هدول بينطبقوا على بعض ولا لأ + +250 +00:22:01,090 --> 00:22:08,270 +الخمسة درّات بدهم يجوا فوق بعض، الخمسة و لا في جنس + +251 +00:22:08,270 --> 00:22:11,130 +ال resonance، هذا وين ال resonance اللي فيه؟ ال + +252 +00:22:11,130 --> 00:22:15,270 +resonance حركة إلكترونات مافي أي resonance إطلاقا + +253 +00:22:16,410 --> 00:22:21,330 +الان معناه الانطباق انهم الخمس ذرات يجوا على بعض + +254 +00:22:21,330 --> 00:22:25,870 +خليني اجرب بده احط الكربون على الكربون زي هيك + +255 +00:22:25,870 --> 00:22:29,770 +خليني اجرب الان لاحظوا هاي الكربون اجت على الكربون + +256 +00:22:29,770 --> 00:22:39,510 +الكلور الهيدروجين اليو دولبروم شمالهم بالعكس اذا + +257 +00:22:39,510 --> 00:22:43,530 +لان مشكلتي باليو دولبروم بصلحها خليني اظبط اليو + +258 +00:22:43,530 --> 00:22:51,020 +دولبرومهيدروجين و هيدروجين هدولة + +259 +00:22:51,020 --> 00:22:54,220 +انطبقوا على بعض هدولة انطبقوا على بعض هدولة + +260 +00:22:54,220 --> 00:22:58,400 +انطبقوا على بعض صح؟ الان هدولة تنتيل كلورو + +261 +00:22:58,400 --> 00:23:06,920 +هيدروجين كلورو هيدروجين بينطبقوا؟ لا بينطبقواتمام؟ + +262 +00:23:06,920 --> 00:23:11,060 +لو أعطناكم ياهم homework في البيت، هدول الجزيئين، + +263 +00:23:11,060 --> 00:23:15,780 +ضلينا نقولكوا معاكم عشر سنين، خليهم ينطبقوا على + +264 +00:23:15,780 --> 00:23:22,450 +بعض، لا ينطبقواواضح؟ إذا بدأت أكسر رابطتين و + +265 +00:23:22,450 --> 00:23:26,490 +أبدلهم هيصيروا نفس الجزء، هيبطلوا صورة بعض في + +266 +00:23:26,490 --> 00:23:31,370 +المرآة، هيصيروا نفس الجزء، واضح؟ لكن طالما هم صورة + +267 +00:23:31,370 --> 00:23:36,330 +بعض في المرآة، فغير متطابقين، إذا هذول أول مثال في + +268 +00:23:36,330 --> 00:23:40,110 +الكيميا على ال enantiomers و ال enantiomers بتوجد + +269 +00:23:40,110 --> 00:23:45,670 +لما يكون عند ذرة carbon تحمل أربع مجموعات مختلفة + +270 +00:23:46,540 --> 00:23:51,900 +واضح؟ إذا متى تصبح هذه الظاهرة موجودة في الكيمياء؟ + +271 +00:23:51,900 --> 00:23:55,460 +إذا وجد عندي ذرّة كاربون تحمل أربع مجموعات مختلفة + +272 +00:23:55,460 --> 00:24:01,160 +الآن هذه الكاربون بنسميها كايرالكاربون إيش + +273 +00:24:01,160 --> 00:24:12,080 +بنسميها؟ كايرالكاربون أو stereogenic center أو + +274 +00:24:12,080 --> 00:24:19,630 +أحيانا كايرالسنتريعني هو يا مركز المشكلة أو مركز + +275 +00:24:19,630 --> 00:24:23,410 +الـ Stereochemistry بأي من هذه الأسماء شفتوها سواء + +276 +00:24:23,410 --> 00:24:26,910 +شفتوها chiral carbon أو chiral center أو + +277 +00:24:26,910 --> 00:24:33,290 +stereogenic center الفكرة فيها أن الكربون تحمل + +278 +00:24:33,290 --> 00:24:39,000 +أربع مجموعات مختلفةلحظة أنا بحبش أني أتعبكم في + +279 +00:24:39,000 --> 00:24:42,180 +صياغات لغوية the carbon carries four different + +280 +00:24:42,180 --> 00:24:46,780 +groups البفروض بس تفهموا كلمة إيش أربعة و بعدين زي + +281 +00:24:46,780 --> 00:24:51,340 +ما بيقول الشاعر و بكل لغات الأرض عبروا عنها المهم + +282 +00:24:51,340 --> 00:24:57,180 +إيش ذرة الكربون تحمل أربع مجموعات مختلفة فبصير + +283 +00:24:57,180 --> 00:25:02,620 +الشكل و صورته في المرأة غير متطابقين في هذه الحالة + +284 +00:25:02,620 --> 00:25:11,710 +صاروا إيشانانشومارز بدنا نميزهم عن بعض الان كل شيء + +285 +00:25:11,710 --> 00:25:18,910 +غير متطابق بلزم اننا ايش نميزه عن بعض بالمناسبة لو + +286 +00:25:18,910 --> 00:25:26,300 +انا سألت هذه ايش هتقولولي يدصح؟ وهذه يد، الان اليد + +287 +00:25:26,300 --> 00:25:33,880 +و اليد غير متطابقات، ايش ضفتلهم؟ كلمة يمنا و يسرا، + +288 +00:25:33,880 --> 00:25:40,110 +هذه عشان توضحهم بالفراغكيف بيجوا الان هذول + +289 +00:25:40,110 --> 00:25:47,090 +المركبين غير متطابقين اذا انا بحاجة لان اميزهم عن + +290 +00:25:47,090 --> 00:25:51,650 +بعضهم البعض يعني لو مجرد ان انا خربطته مع بعض كنت + +291 +00:25:51,650 --> 00:25:56,090 +حامل هذا المركب و خربطته مع بعض قلتلكوا اي مركب + +292 +00:25:56,090 --> 00:26:01,820 +كنت حامله باليمين و اي واحد بالاشمالهتعرفوه؟ اذا + +293 +00:26:01,820 --> 00:26:06,840 +لابد من طريقة لتمييزهم الان كيف بيميزوهم كيميائيا؟ + +294 +00:26:06,840 --> 00:26:10,840 +بيقولوا تذكروا القواعد اللي أخدناها للأولويات في + +295 +00:26:10,840 --> 00:26:14,340 +المجموعات اللي أخدناها بالسلسة ال Trans ال يكان + +296 +00:26:14,340 --> 00:26:18,480 +انجلد بريلوج رولز اللي بتعتمد على ال atomic number + +297 +00:26:18,480 --> 00:26:21,500 +لما كنا نقول عند ال double bond مين أعلى؟ هذه ولا + +298 +00:26:21,500 --> 00:26:28,280 +هذه؟واضح الفكرة؟ الان صنف المجموعات اللى موجودة + +299 +00:26:28,280 --> 00:26:33,300 +حسب هذه القواعد من الأعلى للأقل في ال atomic + +300 +00:26:33,300 --> 00:26:39,320 +numbers الان تذكروا اللى عندي هيدروجين و كلور و + +301 +00:26:39,320 --> 00:26:45,440 +بروميود من أعلى واحدة؟بعدها البروم وبعدها الكلور + +302 +00:26:45,440 --> 00:26:49,400 +وبعدها الهيدروجين كلكوا متذكرين انه كان عنده ال + +303 +00:26:49,400 --> 00:26:53,300 +floriclor, البروم, اليود و الهيدروجين هان في + +304 +00:26:53,300 --> 00:26:55,880 +الجدول الدوري اذا اليود اعلى من البروم اعلى من + +305 +00:26:55,880 --> 00:27:00,760 +الكلور اعلى من الهيدروجين هذا في خلاف ولا لأ؟ لأ + +306 +00:27:00,760 --> 00:27:06,160 +الان بمسك الجزء بهذا الشكل بخلي المجموعة الأقل + +307 +00:27:06,160 --> 00:27:11,680 +الخلفالان انا هنا خلّيت المجموع الأقل للخلف منكم و + +308 +00:27:11,680 --> 00:27:16,840 +مني كمان ايش المجموع الأقل الهيدروجين خلوها للخلف + +309 +00:27:16,840 --> 00:27:28,460 +و اتحركوا من الأعلى للأقل للأقل واحدة تتحرك كيف + +310 +00:27:28,460 --> 00:27:35,820 +تكون الحركة مع قرب الساعة clockwise طب لو عملت + +311 +00:27:35,820 --> 00:27:41,800 +الكلام في الجزء التانييعني خلّيت أقل مجموعة + +312 +00:27:41,800 --> 00:27:49,780 +الهيدروجين للخلف و تحركوا يود .. عكس عقارة عكس + +313 +00:27:49,780 --> 00:27:58,660 +عقارة بالساعة صار في فرق بين التلات كيف؟ + +314 +00:28:03,590 --> 00:28:11,830 +الان صار المطلوب يهدى ان هذا الجزء ابرومو كلورو + +315 +00:28:11,830 --> 00:28:17,630 +ايودو ميثين اللى معه قريب الساعةاتبهي معاك و هذا + +316 +00:28:17,630 --> 00:28:23,730 +الجزء برومو كلورو ايودو ميثين اللي ضد عقارب الساعة + +317 +00:28:23,730 --> 00:28:28,010 +الان شوف الكيميائيين جداش لطيفين و محترمين و سهلين + +318 +00:28:28,010 --> 00:28:32,910 +بدل ما ييجي يقولك كبشة كلامها الجد اجبال الاسم + +319 +00:28:32,910 --> 00:28:39,230 +اللي مع عقارب الساعة كام كلمة اربعة استبدالهم بحرف + +320 +00:28:39,230 --> 00:28:40,810 +جال اكتبله R + +321 +00:28:44,120 --> 00:28:50,200 +و هذا اللي ضد عقارب الساعة استبدله بحرف جال و + +322 +00:28:50,200 --> 00:28:54,280 +اكتبله S R + +323 +00:28:54,280 --> 00:29:03,400 +capital R و capital ايش S صار عندي R و S ال R + +324 +00:29:03,400 --> 00:29:10,200 +معناها clockwise و ال S counter clockwise + +325 +00:29:14,800 --> 00:29:20,020 +يعني مع و ضد عقارب الساعة هدول جايين من اللاتيني + +326 +00:29:20,020 --> 00:29:26,520 +rectus و sinister يعني أصل ال R من rectus + +327 +00:29:26,520 --> 00:29:31,380 +اللاتينية يعني يمين هيك مع عقارب و هذه sinister + +328 +00:29:31,380 --> 00:29:39,520 +يعني أصل الكلمة من إيش من اللاتيني الآن صار الإسم + +329 +00:29:39,520 --> 00:29:43,260 +الكامل لهذا لو جبته في الامتحان الإسم الكامل + +330 +00:29:43,260 --> 00:29:48,720 +الصحيحأي واحد في يوميك أخلطهم أخلطهم أنتوا مش + +331 +00:29:48,720 --> 00:29:52,640 +شايفين إشي و بعد ما خلطت و اتعبت قولتلها واحدة + +332 +00:29:52,640 --> 00:29:59,780 +سميلي هذا المركب طبعا هي عشان تاخد الأربع علامات + +333 +00:29:59,780 --> 00:30:02,460 +من خمسة في الأول بتجيب اسم الكيميا العادى + +334 +00:30:06,770 --> 00:30:09,690 +Ibromochloroiodomethane الان اخدت اربعة او تلاتة + +335 +00:30:09,690 --> 00:30:14,150 +من خمسة بعدين اربع مجموعات مختلفة اذا يجب مباشرة + +336 +00:30:14,150 --> 00:30:19,190 +انها تتحول على ال R و ال S اتطلع عليه سكنه اليود + +337 +00:30:19,190 --> 00:30:26,970 +Ibromichlor عكس اذا هذا صار اسمه الكامل S Ibrom و + +338 +00:30:26,970 --> 00:30:32,960 +هذا صار اسمه الكامل R فال S و ال Rهي بادئة لتوضيح + +339 +00:30:32,960 --> 00:30:37,800 +إيش؟ الشكل الفراغي تماما زي ما كان عندى في + +340 +00:30:37,800 --> 00:30:42,940 +الدياستيريو مارز إيش ال sis و ال trans و ال z و ال + +341 +00:30:42,940 --> 00:30:47,320 +E متذكرين لما احنا كنا نقول one two dichloroethane + +342 +00:30:47,320 --> 00:30:51,340 +و التاني نفس الاسم بدي أميزهم في الدياستيريو مارز + +343 +00:30:51,340 --> 00:31:00,320 +شو كنت بستعمل؟Sis و Trans او Z و E هذه البادئات + +344 +00:31:00,320 --> 00:31:07,340 +ايش بتوضح ليه؟ شكل فراغي الان في الانانشو مارز ROS + +345 +00:31:07,340 --> 00:31:14,980 +واضح؟ في الانانشو مارز ROS شوية في ال biochemistry + +346 +00:31:14,980 --> 00:31:18,900 +هيستعملوا مصطلحات تانية مبنية على نفس الفكرة + +347 +00:31:18,900 --> 00:31:21,180 +هتصيروا تشوفوا DOL + +348 +00:31:23,400 --> 00:31:28,660 +لما ابتصلوا لل biochemistry للبروتينات و الأشياء + +349 +00:31:28,660 --> 00:31:33,200 +اللي زي هيك هتلاحظوا و ال sugars بستعملوا D و L + +350 +00:31:33,200 --> 00:31:37,440 +بديل عن R و S تاريخيا لكن نفس الفكرة في حينه + +351 +00:31:37,440 --> 00:31:42,380 +بتدرسوها ف ال D و L أو ال R و ال S طبعا الأساس + +352 +00:31:42,380 --> 00:31:46,990 +الأعم و الأشمل و الأصل في الكيميا اللي هو إيش؟الـR + +353 +00:31:46,990 --> 00:31:49,170 +والـS يعني دي والأول استعمالات شويه في ال + +354 +00:31:49,170 --> 00:31:53,710 +biochemistry الـR والـS يستعملوا لتمييز ال + +355 +00:31:53,710 --> 00:31:57,910 +enantiomers عن بعضها البعض والعملية البسيطة + +356 +00:31:57,910 --> 00:32:04,900 +المجموعة الأقل أين توجدللخلف المجموع الأقل للخلف + +357 +00:32:04,900 --> 00:32:10,660 +وباقي المجموعات بنتحرك فيها من الأعلى للأقل حسب + +358 +00:32:10,660 --> 00:32:14,420 +قواعد الأولويات اللي أخدناها لإي اسمها Ken Ingold + +359 +00:32:14,420 --> 00:32:19,760 +Prelog Rules وبالتالي يحدد المركب هل هو R أو هو + +360 +00:32:19,760 --> 00:32:25,260 +إيش S وإلى لقاء آخر + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..e5bf93dcb8a75119f849750f6e18ea73977c01cd --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/7aZWDTxPij4_raw.srt @@ -0,0 +1,1440 @@ +1 +00:00:21,240 --> 00:00:26,260 +بسم الله الرحمن الرحيم موضوعنا اليوم عن ال + +2 +00:00:26,260 --> 00:00:31,560 +stereochemistry ربما يعني انتوا اتشوقتوا اليها لان + +3 +00:00:31,560 --> 00:00:37,220 +احنا من اول محاضرة لما اتكلمنا عن المتشكلات او ال + +4 +00:00:37,220 --> 00:00:43,960 +isomers قسمناهم وقلنا هم نوعين اساسيين structural + +5 +00:00:43,960 --> 00:00:48,920 +isomers او constitutional isomers سمناهم و stereo + +6 +00:00:48,920 --> 00:00:54,250 +isomersالان هذا التصنيف اللى بنشوفه باللوحة + +7 +00:00:54,250 --> 00:01:01,030 +التصنيف العام ل .. خلينا نقول ال isomers أخدنا جزء + +8 +00:01:01,030 --> 00:01:06,510 +منه اللى هو إيش معنى isomers بشكل عام المركبات + +9 +00:01:06,510 --> 00:01:10,750 +اللى لها نفس الصيغة الجزائية ولكن بتختلف في الشكل + +10 +00:01:10,750 --> 00:01:16,070 +الان قسمت إلى نوعين النوع الأول ال structural + +11 +00:01:16,070 --> 00:01:21,770 +isomers المركباتاللي بتختلف في مواقع ارتباط الذرات + +12 +00:01:21,770 --> 00:01:25,310 +يعني فيها different bonding وقولنا هذا different + +13 +00:01:25,310 --> 00:01:29,350 +bonding بيقدر إلى انه يكون لها different names ولو + +14 +00:01:29,350 --> 00:01:33,430 +على اقل تقدير في الرقم اللي بيحدد مثلا Substituent + +15 +00:01:33,430 --> 00:01:37,470 +يعني على سبيل المثال لما نقول بروبين امكون من تلت + +16 +00:01:37,470 --> 00:01:41,750 +ذرات الآن على الموقع الأول Clor أو على الموقع + +17 +00:01:41,750 --> 00:01:45,430 +التاني Clorهذا صار different bonding يعني أي حد + +18 +00:01:45,430 --> 00:01:49,670 +يقول هدولة شو بيفرقوا على البعض، هيقول هذا بروبين + +19 +00:01:49,670 --> 00:01:52,990 +تلت ذرات على الموقع الأول كلور صار اسمه one + +20 +00:01:52,990 --> 00:01:57,190 +chloroborbine التاني على الموقع اتنين two + +21 +00:01:57,190 --> 00:02:03,100 +chloroborbine هدولة اسمين مختلفينالان الشيء التاني + +22 +00:02:03,100 --> 00:02:07,900 +في ال isomers اللى حتى ايضا بدنا فيه اللى هو ال + +23 +00:02:07,900 --> 00:02:12,900 +stereo isomers المركبات اللى بتكون لها نفس + +24 +00:02:12,900 --> 00:02:17,840 +الارتباط ولكن اختلاف في شكلها بالفراغ ولذلك احنا + +25 +00:02:17,840 --> 00:02:21,400 +قولنا ال stereo isomers ال atoms they have the + +26 +00:02:21,400 --> 00:02:26,970 +same constitutiondifferent arrangement in space + +27 +00:02:26,970 --> 00:02:31,590 +بدأنا فيهم الحقيقة لما احنا أخدنا مراكبات ال sis + +28 +00:02:31,590 --> 00:02:36,990 +والترانس يعني مثلا عندنا اثين على موقع واحد كلور + +29 +00:02:36,990 --> 00:02:40,890 +هاي اثين جزئي ب double bond على موقع واحد كلور + +30 +00:02:40,890 --> 00:02:45,030 +وعلى موقع اتنين كلور وبناء على ذلك شو هيصير اسمه + +31 +00:02:45,030 --> 00:02:51,130 +one two dichloro ethaneSame bondage الآن يا تورا + +32 +00:02:51,130 --> 00:02:57,650 +هدولة ذرتين لchlor جايين على جهة واحدة ولا جايين + +33 +00:02:57,650 --> 00:03:01,770 +على جهتين متعاكستين صيرنا نضيف ال prefix أو + +34 +00:03:01,770 --> 00:03:08,130 +البادئة اللي هي cis وtrans فالcis وtrans هنا ما + +35 +00:03:08,130 --> 00:03:13,470 +بتعني مواقع الذرات مواقع الذرات حدد one two ع ذرة + +36 +00:03:13,470 --> 00:03:18,420 +واحد وع ذرة اتنينSame bonding, same name المركب + +37 +00:03:18,420 --> 00:03:22,420 +اسمه one two dichloroethane لكن الفرق ال + +38 +00:03:22,420 --> 00:03:28,600 +arrangement in space مع بعض و لا ضد بعض و عرفنا ان + +39 +00:03:28,600 --> 00:03:34,040 +احنا بنستعمل كلمة cess او الأعام منها z للتعبير عن + +40 +00:03:34,040 --> 00:03:40,260 +معنى مع بعض و ال transاو ايه؟ ضد بعض واضح هذا + +41 +00:03:40,260 --> 00:03:43,860 +الكلام؟ الان لما أخذنا ال sis و ال trans قولنا + +42 +00:03:43,860 --> 00:03:47,840 +هدوله نوع او احد انواع ال stereo isomers اللي + +43 +00:03:47,840 --> 00:03:52,700 +سمناهم ايش؟ they are stereomersالان شو يعني + +44 +00:03:52,700 --> 00:03:56,980 +diastereomers ال diastereomers ببساطة قلنا عنهم + +45 +00:03:56,980 --> 00:04:00,660 +non mirror image stereoisomers يعني stereoisomers + +46 +00:04:00,660 --> 00:04:04,820 +لو حطيت واحد جبال التاني و تخيلت انه في امرأة + +47 +00:04:04,820 --> 00:04:09,460 +بينهم بيكونوا مش صورة بعض في المرأة non mirror + +48 +00:04:09,460 --> 00:04:14,500 +image stereoisomers الان موضوعنا في هذا الفصل على + +49 +00:04:14,500 --> 00:04:19,930 +النوع التاني يعني كل الكلام اللي اتكلمتهمقدمة لكن + +50 +00:04:19,930 --> 00:04:24,570 +موضوعنا على النوع التاني اللي اسمه enantiomers + +51 +00:04:24,570 --> 00:04:28,750 +النوع التاني اللي اسمه enantiomers ال enantiomers + +52 +00:04:28,750 --> 00:04:34,970 +قبل ما تكون ظاهرة موجودة في الكيميا و في ال stereo + +53 +00:04:34,970 --> 00:04:40,530 +isomers هي ظاهرة موجودة في الحياة ربما من تبهينها + +54 +00:04:40,530 --> 00:04:46,580 +الناس او لأالله أعلم لكن لما نذكرها و نفهمها + +55 +00:04:46,580 --> 00:04:51,200 +بالحياة بعد هيك بنقدر نفهمها بالكيميا يعني اللي + +56 +00:04:51,200 --> 00:04:56,280 +بده يفهم إيش معناه in and sumars بدوش يظن أن هذه + +57 +00:04:56,280 --> 00:05:00,840 +الكلمة هي كلمة كيميائية لأ كلمة in and sumars هي + +58 +00:05:00,840 --> 00:05:06,840 +كلمة حياتية يعني ممكن في الامتحان أرسمه to in and + +59 +00:05:06,840 --> 00:05:12,620 +sumarsمن الحياة لا بد يبين فيها روابط ولا بد يبين + +60 +00:05:12,620 --> 00:05:17,300 +فيها ذرات ولا جزيئات ولا ما يحزنون ال enantiomers + +61 +00:05:17,300 --> 00:05:22,700 +ظاهرة حياتية ايش اصل هذه الظاهرة اصل هذه الظاهرة + +62 +00:05:22,700 --> 00:05:29,710 +تنطلق من الإيدينلحظوا الإيد اليمين والإيد الشمال، + +63 +00:05:29,710 --> 00:05:34,930 +لو أنا حطيت هدول الاتين بهذا الشكل أقبال بعض، + +64 +00:05:34,930 --> 00:05:40,900 +هلاحظ أن هدول الاتين صورت بعض في المرقاةواضح؟ يعني + +65 +00:05:40,900 --> 00:05:44,920 +لو هنا في مراية بدل الإيد الشمال، إيش اللي هيبين + +66 +00:05:44,920 --> 00:05:49,960 +فيها؟ نفس هذه، لو كنت حاطط لشمال، لو في مراية، إيش + +67 +00:05:49,960 --> 00:05:54,160 +هيبين فيها نفس هذه؟ الآن صورة المرأة اللي احنا + +68 +00:05:54,160 --> 00:06:01,510 +سمناها mirror image سابقاإيش بتمتاز؟ إن كل نقطة + +69 +00:06:01,510 --> 00:06:06,910 +فيها عكس التاني عكس الأصل يعني أنا لما بحط الإيد + +70 +00:06:06,910 --> 00:06:12,290 +اتطلع على الكف اللي موجود عنده بأي اتجاه؟ بهذا + +71 +00:06:12,290 --> 00:06:17,830 +الاتجاه واضح؟ الآن هذا صورته في المرأة لوين؟ + +72 +00:06:17,830 --> 00:06:21,710 +بالاتجاه المعاكس ولذلك لما الإنسان نفسه كمان بيقف + +73 +00:06:21,710 --> 00:06:27,710 +قدام المراية بشوف صورتهمعنى ذلك إن كل ما في المرأة + +74 +00:06:27,710 --> 00:06:32,450 +عكس الوضع اللي هو واقف الإنسان فيه، واضح؟ الآن إنه + +75 +00:06:32,450 --> 00:06:36,330 +ملقتين mirror image هذا أمر طبيعي، لأ وأمر طبيعي + +76 +00:06:36,330 --> 00:06:41,770 +أكثر إن كل شيء في الدنيا كل شيء في الدنيا له + +77 +00:06:41,770 --> 00:06:45,850 +mirror image، يعني هذا مش موضوع خلافي إطلاقا، يعني + +78 +00:06:45,850 --> 00:06:52,470 +لو جيبنا قدام المرايا حجرأو كرة أو أرنب أو بني آدم + +79 +00:06:52,470 --> 00:06:58,710 +أو ملك أو فقير وقفناه قدام المراية له mirror image + +80 +00:06:58,710 --> 00:07:03,470 +يعني بنقدر نصيغي الكلام for every object there is + +81 +00:07:03,470 --> 00:07:07,530 +a mirror imageكل جسم في الدنيا له mirror image + +82 +00:07:07,530 --> 00:07:11,890 +تمام؟ إذا بيصير وين الجديد؟ إذا كل إشي في الدنيا + +83 +00:07:11,890 --> 00:07:16,770 +له mirror image الآن بيجي الشيء الجديد اللي بينبني + +84 +00:07:16,770 --> 00:07:21,670 +عليه فهمنا لهذا ال chapter هل يا تورا الصورة في + +85 +00:07:21,670 --> 00:07:27,490 +المرآة تنطبق على الأصل ولا لأ؟يعني لو أنا إجيت + +86 +00:07:27,490 --> 00:07:32,170 +قولت ال .. ال tail هدولة they are mirror images هل + +87 +00:07:32,170 --> 00:07:37,430 +يا ترى هذه الإيد بتنطبق على هذه الإيد ولا لأ؟ معنى + +88 +00:07:37,430 --> 00:07:45,030 +تنطبق على super imposible super imposible + +89 +00:07:46,690 --> 00:07:51,710 +واضح؟ هل يا تورا الإيد اليمين و الإيد الشمال + +90 +00:07:51,710 --> 00:07:56,250 +بينطبقوا على بعض من بعض ولا لأ؟ إيش إنتوا رأيكم من + +91 +00:07:56,250 --> 00:08:03,770 +خبرتكوا الحياتية؟ كويس، الآن لاحظوا الشعب + +92 +00:08:03,770 --> 00:08:12,170 +الفلسطيني لأنه عاش طفولة صعبةلم يقدر له أن يستمتع + +93 +00:08:12,170 --> 00:08:19,410 +بطفولته ولذلك لم يستطع أن يجيب على سؤال بسيط مثل + +94 +00:08:19,410 --> 00:08:29,270 +هذا السؤال لو استمتعتنا بطفولتي كنا لعرفتنا إيش + +95 +00:08:29,270 --> 00:08:34,350 +أنه لما بنيجي نركب العروسة الصغيرة إلها التين + +96 +00:08:34,350 --> 00:08:40,380 +ماقدرش أحط هذه محل هذهالعروسة الصغيرة معمولة بتنفك + +97 +00:08:40,380 --> 00:08:44,940 +الاتين والرجلتين ولا لأ؟ لما بتيجوا تركبوها هذه + +98 +00:08:44,940 --> 00:08:48,220 +العروسة الصغيرة جسم اللي بيلعبوا فيها الأطفال + +99 +00:08:48,220 --> 00:08:53,900 +ويلها إيد وإيد ورجل ورجل هل يا تورا عمركوا جربتوا + +100 +00:08:53,900 --> 00:08:58,300 +وهي مفكوكة تركبوها تاني؟ هل بتيجي الإيد لشمال محل + +101 +00:08:58,300 --> 00:09:03,130 +اليمين؟ لأبالتأكيد لأ بنعكس الأصبع الآن تخيلوا أن + +102 +00:09:03,130 --> 00:09:06,950 +هذه الإيد اللي عندى اليمين لو أنا بدأ أحط الشمال + +103 +00:09:06,950 --> 00:09:10,790 +مكانها تماما و الكف لجوه بده يكون هاي بدأ أجيب + +104 +00:09:10,790 --> 00:09:15,270 +الشمال لحظوا هذا الأصبع وين رايح هذا الأصبع وين + +105 +00:09:15,270 --> 00:09:20,310 +رايح ولذلك لا يمكن لو إجيتوا تركبوا الرجلين محال + +106 +00:09:20,310 --> 00:09:26,130 +بعض هتلاحظوا أن رجل للأمام و رجل للخلف فالاتين + +107 +00:09:27,470 --> 00:09:31,670 +و كل كوا عندكم لسه ما زال من بقايا الطفولة شيء على + +108 +00:09:31,670 --> 00:09:38,280 +أرض الواقع أو في الذاكرة فجربوا .. فجربواالان .. + +109 +00:09:38,280 --> 00:09:43,500 +هذه الان بتصبح أساس لظاهرة .. بتصبح أساس لظاهرة + +110 +00:09:43,500 --> 00:09:50,020 +أنه في أحيانا الصورة في المرأة و الأصل يكونوا غير + +111 +00:09:50,020 --> 00:09:54,020 +متطابقين طبعا ممكن الصورة و الأصل تكون متطابقة + +112 +00:09:54,020 --> 00:10:00,380 +يعني لو إنسان مثلا جاب هذا القلمحطه هنا الصورة + +113 +00:10:00,380 --> 00:10:05,560 +تبعته جلم تاني هذه صورة هذا أصل ينطبق على بعض لو + +114 +00:10:05,560 --> 00:10:12,020 +الإنسان جاب كرةأيه كويس؟ حطها أمام المرآة، شو + +115 +00:10:12,020 --> 00:10:16,820 +هيشوف؟ كرة، الكورتين ينطبقوا مكان بعض، بمعنى آخر + +116 +00:10:16,820 --> 00:10:21,020 +لو كان فيه قالب محطوطة في الكورة هذه و قالب محطوطة + +117 +00:10:21,020 --> 00:10:23,800 +في الكورة الثانية، بقدر أحط هذه محل هذه و بقدر أحط + +118 +00:10:23,800 --> 00:10:29,000 +هذه محل هذه، لكن تخيلوا معي لو كان الإنسان بيشتري + +119 +00:10:29,000 --> 00:10:33,660 +عروسة صغيرة اللي بيلعبوا فيها، والاتنين محطوطين في + +120 +00:10:33,660 --> 00:10:39,730 +الجالب الكلكل المفحورهذه للإيد اليمين مفحورة جوا، + +121 +00:10:39,730 --> 00:10:44,410 +هذه للإيد التانية أرفع هذه الإيد، بيقدر يحط هذه + +122 +00:10:44,410 --> 00:10:48,690 +مكانها؟ مش ممكن، لحظوا هذه الفحر وين الأصبع جاي + +123 +00:10:48,690 --> 00:10:52,810 +فيها؟ بهذا الاتجاه، طبعا ما تحطوهاش بالعكس، معنى + +124 +00:10:52,810 --> 00:10:57,630 +التطابق أن كل نقطة تنطبق محل إيش؟ التانية، واضح؟ + +125 +00:10:57,630 --> 00:11:02,060 +هل بنقدر نحط هذه محل هذه؟بنقدرش نحطهم محال بعض + +126 +00:11:02,060 --> 00:11:08,400 +الان هذه الظاهرة .. هذه الظاهرة لأنها أساس لأشياء + +127 +00:11:08,400 --> 00:11:12,980 +كتيرة أعطوها اسم في الكيميا سموها ظاهرة ايش ال + +128 +00:11:12,980 --> 00:11:21,380 +handedness ظاهرة ال handedness ظاهرة ال handedness + +129 +00:11:21,380 --> 00:11:28,200 +اللي هي عدم تطابق الأصل مع الصورة الان لو بدنا + +130 +00:11:28,200 --> 00:11:35,620 +أنصيهاباللغة الإنقليزية بدنا نقول بيكون عند non + +131 +00:11:35,620 --> 00:11:40,020 +-superimposable mirror image stereoisomers لاحظوا + +132 +00:11:40,020 --> 00:11:44,500 +معي non-superimposable غير متطابق non + +133 +00:11:44,500 --> 00:11:47,720 +-superimposable mirror image stereoisomers يعني + +134 +00:11:47,720 --> 00:11:53,760 +صور في المرأة غير متطابقة الأصل والصورة ايش ماله + +135 +00:11:53,760 --> 00:11:57,520 +غير متطابق non-superimposable غير متطابق mirror + +136 +00:11:57,520 --> 00:12:04,920 +imageصورة مع الأصل واضح الصورة لا تنطبق على الأصل + +137 +00:12:04,920 --> 00:12:12,060 +الان كل ما كان مثل الإيدين بنطبق عليه الظاهرة الان + +138 +00:12:12,060 --> 00:12:16,500 +كل شغلتين مثل الإيدين اعطوهم اسم سموهم enantiomers + +139 +00:12:16,500 --> 00:12:23,690 +فالاتين enantiomersواضح؟ فعلاقة الانانشومارز بلغة + +140 +00:12:23,690 --> 00:12:29,710 +بسيطة هي أصل وصورة في المرآة ولكنهم غير متطابقين + +141 +00:12:29,710 --> 00:12:33,790 +non superimposable mirror images أو mirror images + +142 +00:12:33,790 --> 00:12:40,350 +stereo isomers الآن أعطوني عد أمثلة من الحياة غير + +143 +00:12:40,350 --> 00:12:49,130 +الإتين الرجلتين صح الرجلتين برضه مش متطابقين وكمان + +144 +00:12:50,730 --> 00:12:54,870 +ابواب السيارة، لاحظوا لما بيخرب مثلا الباب الأمامي + +145 +00:12:54,870 --> 00:12:58,150 +في السيارة، الواحد بيروح باشتري باب، أول سؤال + +146 +00:12:58,150 --> 00:13:04,330 +بينسأله من البيبيع، بدك الباب شمال ولا يمين؟ + +147 +00:13:04,330 --> 00:13:09,790 +كمان، إمريتين السيارة، الإمريات اللي على الجانب، + +148 +00:13:09,790 --> 00:13:12,870 +بيركبوا، في واحدة شمال، في واحدة يمين، مابيجيوش + +149 +00:13:12,870 --> 00:13:17,150 +التنتين محال بعض، كمان، لودان + +150 +00:13:18,370 --> 00:13:24,490 +واضح؟ كمان إذا شلحت هذه النضارة تخيلوا لو انت جزء + +151 +00:13:24,490 --> 00:13:29,200 +منكم درس بصريات طبية انت علوم صحة الآن صح؟هذه + +152 +00:13:29,200 --> 00:13:36,180 +النضارة مفكوكة هيكون عنده إيد و إيد و عدسة و عدسة + +153 +00:13:36,180 --> 00:13:41,000 +و هذا الجسم الصغير إله اسم انتعون النضارات تمام لو + +154 +00:13:41,000 --> 00:13:45,820 +فكتوهم و إجيتوا تركبوهم يعني بس بمفك صغير اشتغلتوا + +155 +00:13:45,820 --> 00:13:49,160 +على هذه النضارة هيصير عندكم من هذه قطعتين من هذه + +156 +00:13:49,160 --> 00:13:54,780 +قطعتين من هذه قطعتين تعالوا ركبوهم لو جربتوا تحطوا + +157 +00:13:54,780 --> 00:14:01,140 +هذه محل هذه و تركبوهم صح تطلع هذه لفوقواضح؟ و هاد + +158 +00:14:01,140 --> 00:14:04,600 +هتطلع على فوق، مش هيظبطه، لو جربتوا تحطوا العدسة + +159 +00:14:04,600 --> 00:14:08,580 +محل العدسة، مش هيظبط، لو جربتوا هاد محل هاد، مش + +160 +00:14:08,580 --> 00:14:13,400 +هيظبط، إذا كل هدولة، رغم إن أنا لو حطيت مرقابي هذا + +161 +00:14:13,400 --> 00:14:19,480 +الشكل، هذا الجزء و هذا الجزء، إيش معلهم؟صورة بعض + +162 +00:14:19,480 --> 00:14:23,660 +في المرأة صحيح صورة بعض في المرأة ولكنها غير + +163 +00:14:23,660 --> 00:14:28,820 +متطابقة إذا كل مكونات النضارة بيخضعوا لظاهرة إيش + +164 +00:14:28,820 --> 00:14:32,500 +ال handedness ال handedness كل مكونات النضارة in + +165 +00:14:32,500 --> 00:14:36,300 +anchomers يعني لو أنا جبتلكوا في الامتحان صورة إيد + +166 +00:14:36,300 --> 00:14:39,240 +النضارة هذه والإيد التانية وقلتلكوا ما العلاقة + +167 +00:14:39,240 --> 00:14:43,750 +بينهم بتقولولي they are anchomersواضح؟ they are + +168 +00:14:43,750 --> 00:14:49,850 +enantiomers الأحذية شو رأيكم فيهم؟ لاحظوا فكرة + +169 +00:14:49,850 --> 00:14:53,750 +الأحذية فكرة يعني مهمة عارفين ليش؟ لأن ال + +170 +00:14:53,750 --> 00:14:58,670 +enantiomers ببساطة للوهلة الأولى صعب أنكم تتميزوهم + +171 +00:14:58,670 --> 00:15:01,630 +وممكن تغلطوا فيهم أول ما بدنا أن تغلطوا في + +172 +00:15:01,630 --> 00:15:07,430 +الإيدين، مظبوط ولا لأ؟ الآن في المستقبل سواء + +173 +00:15:07,430 --> 00:15:10,750 +قابلته أو قابته + +174 +00:15:12,820 --> 00:15:17,720 +هتلاحظوا انه عشان الطفل الصغير اول ما بيبدأ يستعمل + +175 +00:15:17,720 --> 00:15:22,320 +الحذاء يفهم هذه الظاهرة بتضله حوالي اربع خمس ست + +176 +00:15:22,320 --> 00:15:24,540 +سنين لما هو بيجي يلبس الحذاء و انتوا قاعدينه + +177 +00:15:24,540 --> 00:15:28,600 +تقولوله شماله يمين طب هم اذا كانوا نفس الاشي ليش + +178 +00:15:28,600 --> 00:15:31,940 +مغلبين حالكوا و منشفين ريجها الطفل الصغير و + +179 +00:15:31,940 --> 00:15:39,080 +بتقولوله شماله يمين مؤمن الغلطان الطفل ولا انتوا + +180 +00:15:41,020 --> 00:15:45,120 +احنا بدنا نفهم الطفل لما بيجي بيلبس الحذاء مش ليه + +181 +00:15:45,120 --> 00:15:48,400 +لنهار الأب و الأم لأ هذي شمال، هذي يمين أول ما + +182 +00:15:48,400 --> 00:15:54,440 +بيبدأ؟ إذا عندكم قناعة أنه هذي و هذي مابيجوش مع + +183 +00:15:54,440 --> 00:16:02,740 +بعض، واضح؟ إذا الأحذية انان شمارز، الأحذية انان + +184 +00:16:02,740 --> 00:16:08,160 +شمارز أيضا، والجوارب انان شمارز، والشاطر اللي + +185 +00:16:08,160 --> 00:16:15,450 +بيعرف إيشيلبسهم صحي الظاهرة اشمالها كبيرة لاحظوا + +186 +00:16:15,450 --> 00:16:21,210 +معي وين بيبين اكثر اشي وين بيبين اكثر اشي ال + +187 +00:16:21,210 --> 00:16:26,970 +enantiomers عارفين وين لما ييجوا ال enantiomers + +188 +00:16:26,970 --> 00:16:31,430 +يتعاملوا مع enantiomers تاني وهذه فكرة كتير اساسية + +189 +00:16:31,430 --> 00:16:36,720 +في الكيميا يعني انتوا قلتوا القدمينEnhance + +190 +00:16:36,720 --> 00:16:40,440 +Shoemers يعني القدم اليمين و القدم الشمال صورة بعض + +191 +00:16:40,440 --> 00:16:44,960 +في المرأة ولكنها غير متطابقة صح ولا لأ؟ و الحذائن + +192 +00:16:44,960 --> 00:16:50,580 +Enhance Shoemers الآن أن الحذائن ممكن يستعملوا + +193 +00:16:50,580 --> 00:16:56,460 +استعمالات كتيرة مايفرجوش نهائيا يعني لو افترضنا + +194 +00:16:56,460 --> 00:17:01,100 +إنسان مثلا بيشتري خردة على الميزان بلاستيك عشان + +195 +00:17:01,100 --> 00:17:06,100 +يعملوا recyclingبيفرج معه إن هذا شمال ولا هذا + +196 +00:17:06,100 --> 00:17:13,800 +يمين؟ لأ، مظبوط ولا لأ؟ لو افترضنا إن إنسان بده + +197 +00:17:13,800 --> 00:17:20,440 +يستعمل الحذاء ليضرب به أعداء الله، صارت في + +198 +00:17:20,440 --> 00:17:25,440 +التاريخ، بيفرج معه إنه شمال ولا يمين؟ ولا جنب + +199 +00:17:25,440 --> 00:17:31,260 +الواجب؟جانب الواجب طيب السؤال عاد لو افترضنا انه + +200 +00:17:31,260 --> 00:17:36,480 +انسان بده يحط الرجلتين في الحذائل بيفرق معه ولا + +201 +00:17:36,480 --> 00:17:42,120 +لأ؟ وين افرقت؟ لما جبت انان شومارز مع انان شومارز + +202 +00:17:42,120 --> 00:17:45,960 +هذا الكلام بعد شوية وين هيجي يفرق معكم؟ لما ابدأ + +203 +00:17:45,960 --> 00:17:53,100 +انا اقول ان الجسم في أشياء مواد مستقبلات موجود + +204 +00:17:53,100 --> 00:17:59,210 +منها اتنينو الدواء موجود منه اتنين الان اذا اللي + +205 +00:17:59,210 --> 00:18:02,510 +في الجسم واحد هيجي على التنين اللي في الدواء اللي + +206 +00:18:02,510 --> 00:18:08,570 +هيتفق مع واحد و يختلف مع التاني هيكون اكثر تطبيق + +207 +00:18:08,570 --> 00:18:14,470 +لهذه المنطقة في ال biological system في الجسم لانه + +208 +00:18:14,470 --> 00:18:18,570 +هتبدو تلاحظوا ان الجزيئات الانزمات الكذا في منها + +209 +00:18:18,570 --> 00:18:23,390 +اتنينإنانشومارز والأدوية في منها إنانشومارز الآن + +210 +00:18:23,390 --> 00:18:28,790 +أي إنانشومارز أعطيه عشان يتفق مع اللي في الجسم هنا + +211 +00:18:28,790 --> 00:18:35,610 +بيصير إيش؟ بيصير الانتباه وأول ما الناس بتبدأ تغلط + +212 +00:18:35,610 --> 00:18:44,340 +مباشرة بتعمل إيش؟ مشكلة وصارت مشاكلضخمة جدا بل + +213 +00:18:44,340 --> 00:18:51,440 +مقاسي خليني في الأول أفرجيكم خلال فترة صغيرة كيف + +214 +00:18:51,440 --> 00:18:54,160 +هذه الظاهرة نفسها اللي قلنا ربع ساعة بنحكي عنها في + +215 +00:18:54,160 --> 00:18:57,900 +الحياة يمكن أن توجد في الكيميا وبعدين بنفرجيكم + +216 +00:18:57,900 --> 00:19:02,360 +المقاسي اللي موجودة من الخطأ في هذه الظاهرة في + +217 +00:19:02,360 --> 00:19:07,550 +المجال الطبي وغيرهالان هذه الظاهرة في الكيميا + +218 +00:19:07,550 --> 00:19:14,470 +بتوجد إذا كان في عندي جزيء في ذرة carbon تحمل أربع + +219 +00:19:14,470 --> 00:19:20,190 +مجموعات مختلفة واضح؟ يعني شرطها أن توجد carbon، + +220 +00:19:20,190 --> 00:19:25,730 +هاي ال carbon عندي تحمل كام مجموعة مختلفة؟ تحمل + +221 +00:19:25,730 --> 00:19:30,790 +أربع مجموعات مختلفة إذا وجدت، بعمل جزيء و صورته + +222 +00:19:30,790 --> 00:19:36,140 +خليني أتخيل، هاي carbonوبدي اعمل تحمل اربع مجموعات + +223 +00:19:36,140 --> 00:19:41,300 +مختلفة الان شايفينها بالالوان ولا لأ عشان نسهل على + +224 +00:19:41,300 --> 00:19:45,720 +حالنا و نفهم الموضوع ببساطة خليني اتخيل ان هذا + +225 +00:19:45,720 --> 00:19:52,200 +الكربون بتحمل يود ايش لون اليود في الدنيا ازرق و + +226 +00:19:52,200 --> 00:20:00,660 +كلور اخضر اخضر مصفر مظبوط ولا لأ و برومأحمر + +227 +00:20:00,660 --> 00:20:06,780 +بورتقالي أحمر بورتقالي إذا هذا الأزرق يود والأخضر + +228 +00:20:06,780 --> 00:20:11,920 +أكلور والأحمر إبروم اتخيلنا كأنا جزء الآن وهذا + +229 +00:20:11,920 --> 00:20:17,620 +هيدروجين طب الآن لو قلت لواحدة لو سمحت سمينا + +230 +00:20:17,620 --> 00:20:25,820 +المركب هذا اللي أنا ماسكه بإيدي شو هتسميه ذرد + +231 +00:20:25,820 --> 00:20:33,810 +كاربون واحدة بسرعةميتين؟ شو بتحمل؟مافيش غير الواحد + +232 +00:20:33,810 --> 00:20:41,350 +ما تقولوهوش إبرومو كلورو أيودو ميثيل و بنذكرهم + +233 +00:20:41,350 --> 00:20:45,530 +alphabetical مش هذي الف باقي التسمية يعني هذا + +234 +00:20:45,530 --> 00:20:50,690 +الجزيء لما تجيب الكياشو اسمه إبرومو كلورو أيودو + +235 +00:20:50,690 --> 00:20:55,550 +ميثيل في مشكلة لحد الآن؟ الآن لو عملت صورته في + +236 +00:20:55,550 --> 00:21:00,330 +المرقاة يعني مسكته زي هيك و جيبت كمان إبرومو + +237 +00:21:00,330 --> 00:21:01,170 +هيدروجيل + +238 +00:21:04,280 --> 00:21:09,440 +وعملت انتبهوا معي هدول التنين تماما صورة بعض في + +239 +00:21:09,440 --> 00:21:16,020 +المرأة ولا لأ واضح صورة بعض في المرأة مية في المية + +240 +00:21:16,020 --> 00:21:20,260 +طب لو قولنا له ده سميناها ده ده سميناها انت سميها + +241 +00:21:20,260 --> 00:21:21,320 +ده + +242 +00:21:26,260 --> 00:21:29,560 +برومو، كلورو، ايود وميثين برومو، كلورو، ايود + +243 +00:21:29,560 --> 00:21:33,660 +وميثين لاحظوا معي إجت الجملة العامة في تعريف ال + +244 +00:21:33,660 --> 00:21:36,900 +stereo isomers they have the same bonding يعني لو + +245 +00:21:36,900 --> 00:21:39,800 +واحدة هنا بتوصف هذا الجزء و واحدة هنا بتوصف هذا + +246 +00:21:39,800 --> 00:21:43,880 +الجزء هتقول carbon متصل في برومو، كلورو، يودو، + +247 +00:21:43,880 --> 00:21:48,490 +هيدروجين و اللي هناcarbon متصل فيه برومو كلورو + +248 +00:21:48,490 --> 00:21:53,250 +يودو هيدروجين اذا same bonding ولا لأ الان يا تورا + +249 +00:21:53,250 --> 00:21:57,550 +لو سألنا نفسنا السؤال هدول بينطبقوا على بعض ولا لأ + +250 +00:22:01,090 --> 00:22:08,270 +الخمسة درّات بدهم يجوا فوق بعض، الخمسة و لا في جنس + +251 +00:22:08,270 --> 00:22:11,130 +ال resonance، هذا وين ال resonance اللي فيه؟ ال + +252 +00:22:11,130 --> 00:22:15,270 +resonance حركة إلكترونات مافي أي resonance إطلاقا + +253 +00:22:16,410 --> 00:22:21,330 +الان معناه الانطباق انهم الخمس ذرات يجوا على بعض + +254 +00:22:21,330 --> 00:22:25,870 +خليني اجرب بده احط الكربون على الكربون زي هيك + +255 +00:22:25,870 --> 00:22:29,770 +خليني اجرب الان لاحظوا هاي الكربون اجت على الكربون + +256 +00:22:29,770 --> 00:22:39,510 +الكلور الهيدروجين اليو دولبروم شمالهم بالعكس اذا + +257 +00:22:39,510 --> 00:22:43,530 +لان مشكلتي باليو دولبروم بصلحها خليني اظبط اليو + +258 +00:22:43,530 --> 00:22:51,020 +دولبرومهيدروجين و هيدروجين هدولة + +259 +00:22:51,020 --> 00:22:54,220 +انطبقوا على بعض هدولة انطبقوا على بعض هدولة + +260 +00:22:54,220 --> 00:22:58,400 +انطبقوا على بعض صح؟ الان هدولة تنتيل كلورو + +261 +00:22:58,400 --> 00:23:06,920 +هيدروجين كلورو هيدروجين بينطبقوا؟ لا بينطبقواتمام؟ + +262 +00:23:06,920 --> 00:23:11,060 +لو أعطناكم ياهم homework في البيت، هدول الجزيئين، + +263 +00:23:11,060 --> 00:23:15,780 +ضلينا نقولكوا معاكم عشر سنين، خليهم ينطبقوا على + +264 +00:23:15,780 --> 00:23:22,450 +بعض، لا ينطبقواواضح؟ إذا بدأت أكسر رابطتين و + +265 +00:23:22,450 --> 00:23:26,490 +أبدلهم هيصيروا نفس الجزء، هيبطلوا صورة بعض في + +266 +00:23:26,490 --> 00:23:31,370 +المرآة، هيصيروا نفس الجزء، واضح؟ لكن طالما هم صورة + +267 +00:23:31,370 --> 00:23:36,330 +بعض في المرآة، فغير متطابقين، إذا هذول أول مثال في + +268 +00:23:36,330 --> 00:23:40,110 +الكيميا على ال enantiomers و ال enantiomers بتوجد + +269 +00:23:40,110 --> 00:23:45,670 +لما يكون عند ذرة carbon تحمل أربع مجموعات مختلفة + +270 +00:23:46,540 --> 00:23:51,900 +واضح؟ إذا متى تصبح هذه الظاهرة موجودة في الكيمياء؟ + +271 +00:23:51,900 --> 00:23:55,460 +إذا وجد عندي ذرّة كاربون تحمل أربع مجموعات مختلفة + +272 +00:23:55,460 --> 00:24:01,160 +الآن هذه الكاربون بنسميها كايرالكاربون إيش + +273 +00:24:01,160 --> 00:24:12,080 +بنسميها؟ كايرالكاربون أو stereogenic center أو + +274 +00:24:12,080 --> 00:24:19,630 +أحيانا كايرالسنتريعني هو يا مركز المشكلة أو مركز + +275 +00:24:19,630 --> 00:24:23,410 +الـ Stereochemistry بأي من هذه الأسماء شفتوها سواء + +276 +00:24:23,410 --> 00:24:26,910 +شفتوها chiral carbon أو chiral center أو + +277 +00:24:26,910 --> 00:24:33,290 +stereogenic center الفكرة فيها أن الكربون تحمل + +278 +00:24:33,290 --> 00:24:39,000 +أربع مجموعات مختلفةلحظة أنا بحبش أني أتعبكم في + +279 +00:24:39,000 --> 00:24:42,180 +صياغات لغوية the carbon carries four different + +280 +00:24:42,180 --> 00:24:46,780 +groups البفروض بس تفهموا كلمة إيش أربعة و بعدين زي + +281 +00:24:46,780 --> 00:24:51,340 +ما بيقول الشاعر و بكل لغات الأرض عبروا عنها المهم + +282 +00:24:51,340 --> 00:24:57,180 +إيش ذرة الكربون تحمل أربع مجموعات مختلفة فبصير + +283 +00:24:57,180 --> 00:25:02,620 +الشكل و صورته في المرأة غير متطابقين في هذه الحالة + +284 +00:25:02,620 --> 00:25:11,710 +صاروا إيشانانشومارز بدنا نميزهم عن بعض الان كل شيء + +285 +00:25:11,710 --> 00:25:18,910 +غير متطابق بلزم اننا ايش نميزه عن بعض بالمناسبة لو + +286 +00:25:18,910 --> 00:25:26,300 +انا سألت هذه ايش هتقولولي يدصح؟ وهذه يد، الان اليد + +287 +00:25:26,300 --> 00:25:33,880 +و اليد غير متطابقات، ايش ضفتلهم؟ كلمة يمنا و يسرا، + +288 +00:25:33,880 --> 00:25:40,110 +هذه عشان توضحهم بالفراغكيف بيجوا الان هذول + +289 +00:25:40,110 --> 00:25:47,090 +المركبين غير متطابقين اذا انا بحاجة لان اميزهم عن + +290 +00:25:47,090 --> 00:25:51,650 +بعضهم البعض يعني لو مجرد ان انا خربطته مع بعض كنت + +291 +00:25:51,650 --> 00:25:56,090 +حامل هذا المركب و خربطته مع بعض قلتلكوا اي مركب + +292 +00:25:56,090 --> 00:26:01,820 +كنت حامله باليمين و اي واحد بالاشمالهتعرفوه؟ اذا + +293 +00:26:01,820 --> 00:26:06,840 +لابد من طريقة لتمييزهم الان كيف بيميزوهم كيميائيا؟ + +294 +00:26:06,840 --> 00:26:10,840 +بيقولوا تذكروا القواعد اللي أخدناها للأولويات في + +295 +00:26:10,840 --> 00:26:14,340 +المجموعات اللي أخدناها بالسلسة ال Trans ال يكان + +296 +00:26:14,340 --> 00:26:18,480 +انجلد بريلوج رولز اللي بتعتمد على ال atomic number + +297 +00:26:18,480 --> 00:26:21,500 +لما كنا نقول عند ال double bond مين أعلى؟ هذه ولا + +298 +00:26:21,500 --> 00:26:28,280 +هذه؟واضح الفكرة؟ الان صنف المجموعات اللى موجودة + +299 +00:26:28,280 --> 00:26:33,300 +حسب هذه القواعد من الأعلى للأقل في ال atomic + +300 +00:26:33,300 --> 00:26:39,320 +numbers الان تذكروا اللى عندي هيدروجين و كلور و + +301 +00:26:39,320 --> 00:26:45,440 +بروميود من أعلى واحدة؟بعدها البروم وبعدها الكلور + +302 +00:26:45,440 --> 00:26:49,400 +وبعدها الهيدروجين كلكوا متذكرين انه كان عنده ال + +303 +00:26:49,400 --> 00:26:53,300 +floriclor, البروم, اليود و الهيدروجين هان في + +304 +00:26:53,300 --> 00:26:55,880 +الجدول الدوري اذا اليود اعلى من البروم اعلى من + +305 +00:26:55,880 --> 00:27:00,760 +الكلور اعلى من الهيدروجين هذا في خلاف ولا لأ؟ لأ + +306 +00:27:00,760 --> 00:27:06,160 +الان بمسك الجزء بهذا الشكل بخلي المجموعة الأقل + +307 +00:27:06,160 --> 00:27:11,680 +الخلفالان انا هنا خلّيت المجموع الأقل للخلف منكم و + +308 +00:27:11,680 --> 00:27:16,840 +مني كمان ايش المجموع الأقل الهيدروجين خلوها للخلف + +309 +00:27:16,840 --> 00:27:28,460 +و اتحركوا من الأعلى للأقل للأقل واحدة تتحرك كيف + +310 +00:27:28,460 --> 00:27:35,820 +تكون الحركة مع قرب الساعة clockwise طب لو عملت + +311 +00:27:35,820 --> 00:27:41,800 +الكلام في الجزء التانييعني خلّيت أقل مجموعة + +312 +00:27:41,800 --> 00:27:49,780 +الهيدروجين للخلف و تحركوا يود .. عكس عقارة عكس + +313 +00:27:49,780 --> 00:27:58,660 +عقارة بالساعة صار في فرق بين التلات كيف؟ + +314 +00:28:03,590 --> 00:28:11,830 +الان صار المطلوب يهدى ان هذا الجزء ابرومو كلورو + +315 +00:28:11,830 --> 00:28:17,630 +ايودو ميثين اللى معه قريب الساعةاتبهي معاك و هذا + +316 +00:28:17,630 --> 00:28:23,730 +الجزء برومو كلورو ايودو ميثين اللي ضد عقارب الساعة + +317 +00:28:23,730 --> 00:28:28,010 +الان شوف الكيميائيين جداش لطيفين و محترمين و سهلين + +318 +00:28:28,010 --> 00:28:32,910 +بدل ما ييجي يقولك كبشة كلامها الجد اجبال الاسم + +319 +00:28:32,910 --> 00:28:39,230 +اللي مع عقارب الساعة كام كلمة اربعة استبدالهم بحرف + +320 +00:28:39,230 --> 00:28:40,810 +جال اكتبله R + +321 +00:28:44,120 --> 00:28:50,200 +و هذا اللي ضد عقارب الساعة استبدله بحرف جال و + +322 +00:28:50,200 --> 00:28:54,280 +اكتبله S R + +323 +00:28:54,280 --> 00:29:03,400 +capital R و capital ايش S صار عندي R و S ال R + +324 +00:29:03,400 --> 00:29:10,200 +معناها clockwise و ال S counter clockwise + +325 +00:29:14,800 --> 00:29:20,020 +يعني مع و ضد عقارب الساعة هدول جايين من اللاتيني + +326 +00:29:20,020 --> 00:29:26,520 +rectus و sinister يعني أصل ال R من rectus + +327 +00:29:26,520 --> 00:29:31,380 +اللاتينية يعني يمين هيك مع عقارب و هذه sinister + +328 +00:29:31,380 --> 00:29:39,520 +يعني أصل الكلمة من إيش من اللاتيني الآن صار الإسم + +329 +00:29:39,520 --> 00:29:43,260 +الكامل لهذا لو جبته في الامتحان الإسم الكامل + +330 +00:29:43,260 --> 00:29:48,720 +الصحيحأي واحد في يوميك أخلطهم أخلطهم أنتوا مش + +331 +00:29:48,720 --> 00:29:52,640 +شايفين إشي و بعد ما خلطت و اتعبت قولتلها واحدة + +332 +00:29:52,640 --> 00:29:59,780 +سميلي هذا المركب طبعا هي عشان تاخد الأربع علامات + +333 +00:29:59,780 --> 00:30:02,460 +من خمسة في الأول بتجيب اسم الكيميا العادى + +334 +00:30:06,770 --> 00:30:09,690 +Ibromochloroiodomethane الان اخدت اربعة او تلاتة + +335 +00:30:09,690 --> 00:30:14,150 +من خمسة بعدين اربع مجموعات مختلفة اذا يجب مباشرة + +336 +00:30:14,150 --> 00:30:19,190 +انها تتحول على ال R و ال S اتطلع عليه سكنه اليود + +337 +00:30:19,190 --> 00:30:26,970 +Ibromichlor عكس اذا هذا صار اسمه الكامل S Ibrom و + +338 +00:30:26,970 --> 00:30:32,960 +هذا صار اسمه الكامل R فال S و ال Rهي بادئة لتوضيح + +339 +00:30:32,960 --> 00:30:37,800 +إيش؟ الشكل الفراغي تماما زي ما كان عندى في + +340 +00:30:37,800 --> 00:30:42,940 +الدياستيريو مارز إيش ال sis و ال trans و ال z و ال + +341 +00:30:42,940 --> 00:30:47,320 +E متذكرين لما احنا كنا نقول one two dichloroethane + +342 +00:30:47,320 --> 00:30:51,340 +و التاني نفس الاسم بدي أميزهم في الدياستيريو مارز + +343 +00:30:51,340 --> 00:31:00,320 +شو كنت بستعمل؟Sis و Trans او Z و E هذه البادئات + +344 +00:31:00,320 --> 00:31:07,340 +ايش بتوضح ليه؟ شكل فراغي الان في الانانشو مارز ROS + +345 +00:31:07,340 --> 00:31:14,980 +واضح؟ في الانانشو مارز ROS شوية في ال biochemistry + +346 +00:31:14,980 --> 00:31:18,900 +هيستعملوا مصطلحات تانية مبنية على نفس الفكرة + +347 +00:31:18,900 --> 00:31:21,180 +هتصيروا تشوفوا DOL + +348 +00:31:23,400 --> 00:31:28,660 +لما ابتصلوا لل biochemistry للبروتينات و الأشياء + +349 +00:31:28,660 --> 00:31:33,200 +اللي زي هيك هتلاحظوا و ال sugars بستعملوا D و L + +350 +00:31:33,200 --> 00:31:37,440 +بديل عن R و S تاريخيا لكن نفس الفكرة في حينه + +351 +00:31:37,440 --> 00:31:42,380 +بتدرسوها ف ال D و L أو ال R و ال S طبعا الأساس + +352 +00:31:42,380 --> 00:31:46,990 +الأعم و الأشمل و الأصل في الكيميا اللي هو إيش؟الـR + +353 +00:31:46,990 --> 00:31:49,170 +والـS يعني دي والأول استعمالات شويه في ال + +354 +00:31:49,170 --> 00:31:53,710 +biochemistry الـR والـS يستعملوا لتمييز ال + +355 +00:31:53,710 --> 00:31:57,910 +enantiomers عن بعضها البعض والعملية البسيطة + +356 +00:31:57,910 --> 00:32:04,900 +المجموعة الأقل أين توجدللخلف المجموع الأقل للخلف + +357 +00:32:04,900 --> 00:32:10,660 +وباقي المجموعات بنتحرك فيها من الأعلى للأقل حسب + +358 +00:32:10,660 --> 00:32:14,420 +قواعد الأولويات اللي أخدناها لإي اسمها Ken Ingold + +359 +00:32:14,420 --> 00:32:19,760 +Prelog Rules وبالتالي يحدد المركب هل هو R أو هو + +360 +00:32:19,760 --> 00:32:25,260 +إيش S وإلى لقاء آخر + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..3bed0200f45e90bb165e6da87325547b7cef2042 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/D9wF84ICB3s_postprocess.srt @@ -0,0 +1,1944 @@ +1 +00:00:19,640 --> 00:00:24,180 +بسم الله الرحمن الرحيم موضوعنا اليوم عن عائلة + +2 +00:00:24,180 --> 00:00:28,620 +كيميائية جديدة مجموعة وظيفية جديدة اللي هي ال + +3 +00:00:28,620 --> 00:00:34,460 +aethers طبعا على طول عدد كبير منكم هيتذكر ان ال + +4 +00:00:34,460 --> 00:00:40,460 +aethers اللي هم الصيغة العامة ROR يعني Oxygen + +5 +00:00:40,460 --> 00:00:47,150 +محصورة بين ذرتينأو Oxygen بين مجموعتين R وكلكم + +6 +00:00:47,150 --> 00:00:53,550 +اتذكرين ان ال Oxygen رابطتين وزوجين إيش؟ إلكترونات + +7 +00:00:53,550 --> 00:00:59,950 +ولذلك احنا غير ال ethers مر علينا شغلتين أبسط من + +8 +00:00:59,950 --> 00:01:04,390 +ال ethers مر علينا شغلتين أبسط من ال ethers شو هم + +9 +00:01:04,390 --> 00:01:11,100 +الآن؟ مين يذكرنا فيهم؟ الماءوالكحول الان الماء + +10 +00:01:11,100 --> 00:01:16,260 +اكسوجينة ايضا و الكحول اكسوجينة و ال ether برضه + +11 +00:01:16,260 --> 00:01:21,080 +ذرة اكسوجين و زوجين الالكترونات هدوله مافيش مفار + +12 +00:01:21,080 --> 00:01:31,320 +منهم لكن الميه كانت H H H الكحول R و H يعني مازال + +13 +00:01:31,320 --> 00:01:37,840 +فيه H ال ether R و Rالان لاحظوا بمنطق ال hydrogen + +14 +00:01:37,840 --> 00:01:43,740 +bonding الان الميه تنتين hydrogen bonding الكحول + +15 +00:01:43,740 --> 00:01:48,080 +من جهة واحدة بتقدر تعمل hydrogen bonding ال ether + +16 +00:01:48,080 --> 00:01:52,660 +مافيش hydrogen bonding وبناء على ذلك الان لو بدنا + +17 +00:01:52,660 --> 00:01:57,660 +نحكي بمنطق ال polarity من اعلى polarity فيهم الميه + +18 +00:01:57,660 --> 00:02:02,080 +بعدها الكحول بعدها ال ether الان ال polarity + +19 +00:02:02,080 --> 00:02:07,340 +مباشرة بتنعكس على ايشعلى أي خاصية فيزيائية؟ على + +20 +00:02:07,340 --> 00:02:11,460 +درجة الغليان ولذلك على الضغط العادى الميه درجة + +21 +00:02:11,460 --> 00:02:17,640 +غليانها 100 الكحول 78 ال ether لو افترضنا اثل و + +22 +00:02:17,640 --> 00:02:22,080 +اثل حوالي 37 + +23 +00:02:23,430 --> 00:02:30,190 +لاحظوا كيف تناسب نقاط الغليان مع القطبية و لو كان + +24 +00:02:30,190 --> 00:02:33,950 +ال ether die مثل ether يعني مثل او مثل بيصير غاز + +25 +00:02:33,950 --> 00:02:38,930 +يعني درجة غليانه أقل بكتير ولذلك على حرارة الغرفة + +26 +00:02:38,930 --> 00:02:45,510 +غلي و خلص وصار ايش موجود على شكلغاز الآن ربما من + +27 +00:02:45,510 --> 00:02:48,790 +أشهر ال ether هذا ال ether ال ethyl o ethyl اللي + +28 +00:02:48,790 --> 00:02:53,670 +هو ال diethyl ether واضح؟ ليش هذا يستعمل ك solvent + +29 +00:02:53,670 --> 00:02:58,670 +مدير سابقا استعمل في التخدير لما كانوا مثلا + +30 +00:02:58,670 --> 00:03:01,850 +بيخدروا حيوانات صغيرة بيعملوا تجارب في المختبرات + +31 +00:03:01,850 --> 00:03:06,930 +فال ether they have been used as anesthetics الآن + +32 +00:03:06,930 --> 00:03:11,720 +لوبدنا ننسى هدول الأشياء اللى احنا سبق اننا + +33 +00:03:11,720 --> 00:03:17,820 +أخدناهم ونضلنا امركزين حالنا في ال aethers وهى + +34 +00:03:17,820 --> 00:03:22,980 +المثال عنهم اللى هو diethyl ether وممكن نسميه + +35 +00:03:22,980 --> 00:03:26,540 +ethyl ether يعني لو لغينا كلمة ethyl، die، بمشي + +36 +00:03:26,540 --> 00:03:32,140 +يعني diethyl ether وethyl ether نفس الاشي لحظوا + +37 +00:03:32,140 --> 00:03:36,440 +لما بنقول من خواصه much less polar than alcohols + +38 +00:03:37,210 --> 00:03:40,210 +الكلام صحيح ولا لأ؟ مافيش فيه hydrogen bonding + +39 +00:03:40,210 --> 00:03:44,130 +بالمرة لما نقول من خواصه not soluble in water + +40 +00:03:44,130 --> 00:03:49,430 +مافيش فيه solubility لأن هذه are groups كلها مافيش + +41 +00:03:49,430 --> 00:03:52,510 +فيه hydrogen bonding اللي يصير polar و like، + +42 +00:03:52,510 --> 00:03:56,730 +dissolves، like، له lower melting point و boiling + +43 +00:03:56,730 --> 00:04:01,130 +point أو boiling temperatures than alcohol اكيد صح + +44 +00:04:03,220 --> 00:04:08,200 +كمان بضيف عليه شغلة chemically inert يعني خامل + +45 +00:04:08,200 --> 00:04:14,940 +كيميائيا تفاعلاته قليلة جدا ولذلك ان شاء الله بأمل + +46 +00:04:14,940 --> 00:04:18,900 +كل أمل ان نخلص كل ال chapter اليوم لانه لما نحكي + +47 +00:04:18,900 --> 00:04:21,560 +عن ال kings و ال quills بنحكي على عشرين تفاعل على + +48 +00:04:21,560 --> 00:04:28,180 +ال ethers بنحكي على تفاعل واحد واضح؟لأنه مافيش من + +49 +00:04:28,180 --> 00:04:32,340 +خلال MH و لا OH و لا C double bond O و لا double + +50 +00:04:32,340 --> 00:04:35,760 +bond هذي المجموعات اللي بنسميها active groups اللي + +51 +00:04:35,760 --> 00:04:39,460 +بتيم عليها تفاعلات كتيرة هذا الكلام مش متوفر وين + +52 +00:04:39,460 --> 00:04:44,380 +في الethers يضاف إلى ذلك all are very flammable + +53 +00:04:45,250 --> 00:04:50,010 +يعني باشتعلوا بشكل سريع جدا زي بنزين السيارات و + +54 +00:04:50,010 --> 00:04:54,950 +وقود السيارات أو ربما كمان اكثر ولذلك ادمجوا + +55 +00:04:54,950 --> 00:05:00,090 +الشغلتين مع بعض ان هو له نقطة غليان منخفضة يعني + +56 +00:05:00,090 --> 00:05:07,230 +بتبخر بسهولة و قابل الاشتعال بشكل كبيرواضح؟ و لذلك + +57 +00:05:07,230 --> 00:05:11,770 +يمثل خطر في المختبر يعني نفترض ان حد عنده بنزين + +58 +00:05:11,770 --> 00:05:15,630 +burner مولعه هنا و قاعد بيشتغل و هنا فيه وعاء فيه + +59 +00:05:15,630 --> 00:05:19,610 +ether مفتوح ال ether نفسه بتبخر سبعة و تلاتين احنا + +60 +00:05:19,610 --> 00:05:23,170 +مرات في غزة الحرارة سبعة و تلاتين طبعا هو بتبخر + +61 +00:05:23,170 --> 00:05:27,030 +على كل الدرجات و كل ما ارتفعت الحرارة بتزيد التبخر + +62 +00:05:27,030 --> 00:05:32,020 +و لذلك ممكن و ال ether هنا و فيناعرف مكان تانيit + +63 +00:05:32,020 --> 00:05:36,000 +can catch fire زي ما بيسموه يعني ممكن يشتعل و يعمل + +64 +00:05:36,000 --> 00:05:41,060 +حريقة فالتعامل مع ال ether بحاجة إلى حذر لأن هو + +65 +00:05:41,060 --> 00:05:46,440 +very flammable و له نقطة غليان منخفضة يعني بينوجد + +66 +00:05:46,440 --> 00:05:51,500 +.. بيتبخر واضح؟ تماما زي التعامل مع وقود السيارات + +67 +00:05:51,500 --> 00:05:56,240 +أو مع التنر هذه المراكبات الكيميائية بحاجة إلى نوع + +68 +00:05:56,240 --> 00:06:04,050 +من الحذر الشديدالان كيف بنسمي ال ethers؟ في إنا + +69 +00:06:04,050 --> 00:06:08,670 +نظامين للتسمية نظام الشائع ال common nomenclature + +70 +00:06:08,670 --> 00:06:12,710 +إن أنا أذكر المجموعات و دائما المجموعة بتاخد + +71 +00:06:12,710 --> 00:06:17,990 +النهاية YL مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +72 +00:06:17,990 --> 00:06:20,470 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +73 +00:06:20,470 --> 00:06:26,330 +مثل مثل مثل مثل مثل مثل + +74 +00:06:26,330 --> 00:06:26,970 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +75 +00:06:26,970 --> 00:06:30,750 +مثل مثل مثل مثل مثل مثبقول die ethyl ether وممكن + +76 +00:06:30,750 --> 00:06:35,210 +تلاقوها ethyl ether يعني تختصر ال die مثل و مثل، + +77 +00:06:35,210 --> 00:06:41,030 +die مثل ether فنل و فنل، die فنل ether الان طب لو + +78 +00:06:41,030 --> 00:06:44,450 +كان هذا ال ether اللاحظه اللي زي بعض المجموعتين + +79 +00:06:44,450 --> 00:06:48,110 +يعني نتخيله زي هيك هي هذه ال oxygena وهنا + +80 +00:06:48,110 --> 00:06:53,920 +المجموعتين زي بعضهذا بنسميه Symmetric Ether متماثل + +81 +00:06:53,920 --> 00:06:59,700 +طب لو يختلفوا Unsymmetric Ether الأن واجهت أذكر + +82 +00:06:59,700 --> 00:07:04,840 +المجموعتين alphabetically يعني Ether فيه إثل و مثل + +83 +00:07:04,840 --> 00:07:13,080 +إيش هسميه إثل مثل إثر إبروبل مثلا و تيرتشار بيوتل + +84 +00:07:14,280 --> 00:07:27,560 +ترتشير بيوتل بروبل إيثار ترتشير + +85 +00:07:27,560 --> 00:07:28,240 +بيوتل بروبل إيثار ترتشير بيوتل بروبل إيثار ترتشير + +86 +00:07:28,240 --> 00:07:33,600 +بيوتل بروبل إيثار ترتشير بيوتل بروبل إيثار + +87 +00:07:39,540 --> 00:07:45,680 +بتكونش تعجزوا ال ether معناه ذرّة أكسوجين طالع + +88 +00:07:45,680 --> 00:07:49,940 +منها رابطة تل لكن الشطارة في اللي بيكون حفظ + +89 +00:07:49,940 --> 00:07:57,840 +المجفوعات الآن ال tertiary butylcarbon عليها تلاتة + +90 +00:07:57,840 --> 00:08:04,700 +مثل أخذناها وال isopropyl carbon CH متصلة باتنين + +91 +00:08:04,700 --> 00:08:11,280 +مثل زي هيكالمحافظة على هذه الشغلة من الأول هذا + +92 +00:08:11,280 --> 00:08:18,320 +دلبو واضح فهي tertiary butyl isopropyl ether احنا + +93 +00:08:18,320 --> 00:08:22,560 +قلنا تيرتشاري بيوتل بنعملها على حرف ال بي هذا لما + +94 +00:08:22,560 --> 00:08:27,140 +شرحنا المجموعات اذا شفنا كيف بنعمل ال ethers كذلك + +95 +00:08:27,140 --> 00:08:31,380 +الحالة لو قلنا الكوفينيل مثلا ايش بدنا نحط البنزين + +96 +00:08:31,380 --> 00:08:32,300 +المخصوم منها + +97 +00:08:42,010 --> 00:08:47,110 +وهاي هذه أمثلة die methyl ether اثل مثل اثر زي ما + +98 +00:08:47,110 --> 00:08:50,810 +قولت مرات بيحطهم مش مرتبين alphabetical لكن الأصح + +99 +00:08:50,810 --> 00:08:55,090 +تحطهم alphabetical يعني زي هذا الأصح تكتبوه اثل + +100 +00:08:55,090 --> 00:09:00,110 +مثل اثر خلو ال E قبل ال M هذا ال ether هذه ال + +101 +00:09:00,110 --> 00:09:07,410 +CH2Cl اسمها كلوروميثل CH2Cl كلوروميثل وهنا اثل اثل + +102 +00:09:07,410 --> 00:09:15,930 +اثلEther وهكذا هذه التسمية هي ال common + +103 +00:09:15,930 --> 00:09:21,070 +nomenclature الان لاحظوا معاك شرط هذه التسمية شرط + +104 +00:09:21,070 --> 00:09:24,730 +هذه التسمية ان المجموع اللي هان و اللي هان يكون + +105 +00:09:24,730 --> 00:09:28,010 +لهم اسماء معروفة بالنسبة لنا و المجموعات اللي + +106 +00:09:28,010 --> 00:09:31,810 +أخدناها ايجليلا مثل ايثلبروبل ايزوبروبل تيرتشر + +107 +00:09:31,810 --> 00:09:38,800 +بيوتل لحجناها انا بكلورو مثل .. بنل مثلا ب ..أقل + +108 +00:09:38,800 --> 00:09:46,290 +ال ether لو قلنا لكم اعملوه يعني شغلات ايشمعروفة + +109 +00:09:46,290 --> 00:09:51,030 +طيب الان لو المركب كبر وفي ايثر ايثر معناه + +110 +00:09:51,030 --> 00:09:55,610 +اكسوجينة بين كربونتين واجيتها بدي ارجع اسم المركب + +111 +00:09:55,610 --> 00:10:02,770 +كأنه ال cane عادي ابحث عن اطول سلسلة اطول سلسلة + +112 +00:10:02,770 --> 00:10:08,310 +تلاتة مركبة بروبين اربعة بيوتين خمسة بنتين و هكذا + +113 +00:10:08,310 --> 00:10:13,780 +طيب بعد ما اطول اطول سلسلة يعني هاي هذا مركبلاحظوا + +114 +00:10:13,780 --> 00:10:17,180 +هنا في carbon تنتين تلاتة لبروبل و هنا carbon + +115 +00:10:17,180 --> 00:10:21,920 +واحدة ايش أطول السلسلة لبروبل الآن تخيل لو هذا + +116 +00:10:21,920 --> 00:10:26,580 +الأزرق اللي هنا كانت Cl لكلور اللي على موقع واحد + +117 +00:10:26,580 --> 00:10:33,420 +ايش هتسموه المركب وان كلورو بروبل بدكوا تحددوا + +118 +00:10:33,420 --> 00:10:38,620 +الرقم الان اللي على موقع واحد مش كلور او مثل ال او + +119 +00:10:38,620 --> 00:10:40,780 +مثل اللي لها اسم مثوكسي + +120 +00:10:43,660 --> 00:10:52,760 +مثل ا ا مثوكسي طب لو كانت ا اثل اثوكسي لو كانت ا + +121 +00:10:52,760 --> 00:10:57,660 +فنل مثوكسي + +122 +00:10:57,660 --> 00:11:04,080 +مثل ا اثوكسي اثل + +123 +00:11:04,080 --> 00:11:10,420 +افنوكسي فنل افروبوكسي + +124 +00:11:13,650 --> 00:11:22,270 +هيبروبيل او ابيوتكسي ابيوتل او and so on واضح + +125 +00:11:22,270 --> 00:11:27,350 +فبنطول أطول سلسلة وبعدين المجموعات بنسميها يعني + +126 +00:11:27,350 --> 00:11:31,190 +مثلا هذا المركب هاي كاربون تنتين أطول سلسلة إذا + +127 +00:11:31,190 --> 00:11:37,540 +المركب إيش إيثان على نمرة واحد إيش عليه؟أو مثل + +128 +00:11:37,540 --> 00:11:43,040 +مثوكسي و إيش عليه كمان اكلور إذا هذا one chloro + +129 +00:11:43,040 --> 00:11:49,840 +one methoxy اثان هاي هذا المركب carbon 234 بيوتين + +130 +00:11:49,840 --> 00:11:56,560 +على نمره اتنين إيش عليه تلت ذرات معه بروبوكسي + +131 +00:11:56,560 --> 00:12:02,810 +بروبوكسي تلت ذرات معه هذا المركبلاحظوا إيثانول ال + +132 +00:12:02,810 --> 00:12:07,230 +alcohol أقوى من ال ether هنقول عنه واحد اتنين + +133 +00:12:07,230 --> 00:12:12,330 +تلاتة أربعة إذا هذا أي مركب واند يوتانول ضال على + +134 +00:12:12,330 --> 00:12:17,990 +نمرة تلاتة شو المجموعة اللي حملها؟مش اتوكسي كلور و + +135 +00:12:17,990 --> 00:12:23,730 +اتوكسي تمام حملة كلور الان الكلور هذه محمولة على + +136 +00:12:23,730 --> 00:12:27,510 +الكربون هذه ولا هذه تعون ال organic بيحطوها بين + +137 +00:12:27,510 --> 00:12:31,550 +جسين و بيقولوا الكلور على الكربون رقم اتنين لاحظوا + +138 +00:12:31,550 --> 00:12:36,490 +اتنين يعني كأنه كل هذه انحطت ايش بين جسين صار كام + +139 +00:12:36,490 --> 00:12:40,410 +نظام ترقيم عندى نظامين النظام الاصلي واحد اتنين + +140 +00:12:40,410 --> 00:12:43,890 +تلاتة اربعة و هنا الكلور لو اجتها انا بدي اقول one + +141 +00:12:43,890 --> 00:12:49,570 +primeإكلورو إيثوكس لو إجت هنا two prime إكلورو + +142 +00:12:49,570 --> 00:12:52,890 +إيثوكس و مرات بتلاحظون ممكن يختصروا ال prime لكن + +143 +00:12:52,890 --> 00:12:59,190 +الأحسن إذا الإنسان استعمل أكثر من نظام ترقيم أنه + +144 +00:12:59,190 --> 00:13:05,070 +يحط إيش ل prime واضح هذه الفكرة بدي أركز معاكوا + +145 +00:13:05,070 --> 00:13:12,140 +عليها فكرة أن الإنسان يستعملأكثر من نظام ترقيم في + +146 +00:13:12,140 --> 00:13:15,980 +نفس المُركّب خلّيني أعطيكوا عليها مثالين عند + +147 +00:13:15,980 --> 00:13:20,460 +اللزوم ممكن مثال من موضوعنا الـEthers ومثال من + +148 +00:13:20,460 --> 00:13:27,920 +موضوع الـH تاني يعني الترقيم ممكن نستعمل أكثر من + +149 +00:13:27,920 --> 00:13:35,300 +نظام ترقيم لو يا تورا أعطيتكم المُركّب هذا و + +150 +00:13:35,300 --> 00:13:44,270 +كتبت هنا OH و كتبت هنا Zوحطينا هنا PR نفترض هذا + +151 +00:13:44,270 --> 00:13:50,710 +المركب جاينا سمى المركب التالي الآن هذا أفضل شيء + +152 +00:13:50,710 --> 00:13:57,590 +أسميه كالكين واضح؟ أطول سلسلة و أطول سلسلة حاملة + +153 +00:13:57,590 --> 00:14:06,330 +OHإذا هكسانول الان ال all عشان تكون أقل ترقيم 1,2 + +154 +00:14:06,330 --> 00:14:12,190 +,3,4,5,6 إذا هذا لو ماكنش عليه هذه الإضافة اللي + +155 +00:14:12,190 --> 00:14:20,110 +موجودة هنا إيش هتسموه two hexanol واضح؟ الآن ال + +156 +00:14:20,110 --> 00:14:27,310 +two تاب على ترقيم إيش؟طب على ترقيم السلسلة لو هذه + +157 +00:14:27,310 --> 00:14:33,870 +إجت بنزينة كان كل كشاطرين four phenyl two hexanol + +158 +00:14:33,870 --> 00:14:39,030 +مش هتتغلبوا فيها لو هذه بنزينة هي four phenyl two + +159 +00:14:39,030 --> 00:14:45,010 +hexanol الآن إجت عليها بروم طبعا هذه موجودة وين؟ + +160 +00:14:45,010 --> 00:14:48,150 +على four وهي ال four هذا اللي هو الرقم اللي هنا + +161 +00:14:48,150 --> 00:14:57,370 +لكن هي بالظبطاه اعملوا ترقيم تاني three + +162 +00:14:57,370 --> 00:15:03,090 +bromophenyl صارت واضحة الفكرة؟ اه three + +163 +00:15:03,090 --> 00:15:06,270 +bromophenyl + +164 +00:15:06,270 --> 00:15:09,470 +three + +165 +00:15:09,470 --> 00:15:14,580 +bromophenyl two hexanolالان بهذا المثال كم نظام + +166 +00:15:14,580 --> 00:15:18,780 +ترقيم استعملت حتى ممكن بالألوان تشايفينهم كيف + +167 +00:15:18,780 --> 00:15:22,820 +صاروا واضحين هذا ال four تبقى لهان ان المجموعة + +168 +00:15:22,820 --> 00:15:26,300 +اللتي بين القوسين موجودة على الموقع أربعة على + +169 +00:15:26,300 --> 00:15:32,460 +السنسلة لكن هذا ترقيم تاني عشان هيك الأنسب لهذا + +170 +00:15:32,460 --> 00:15:37,000 +الترقيم التاني اللي كنت كاتبه بالأزرقإن أحطله إيش + +171 +00:15:37,000 --> 00:15:44,720 +الـ prime طبعا هذا بيمنعش أنه بزام فيه تاني ممكن + +172 +00:15:44,720 --> 00:15:50,520 +يصير كمان تالت و باجيتها ممكن أحطله double prime + +173 +00:15:50,520 --> 00:15:56,720 +وارد بتصير الأمور أصعب لكن المبدأ بأمل أنه صار إيش + +174 +00:15:56,720 --> 00:15:58,440 +واضح عندكم + +175 +00:16:04,790 --> 00:16:11,250 +لو طلبنا منكم تسمولنا + +176 +00:16:11,250 --> 00:16:27,510 +هذا المركب على سبيل المثال جاكوا + +177 +00:16:27,510 --> 00:16:32,870 +هذا في الامتحان هو زيكك BJ الآن + +178 +00:16:32,870 --> 00:16:37,720 +هتفكروا بإيش؟بأطول سلسلة ما تشوفوش تفكروا بال إيثا + +179 +00:16:37,720 --> 00:16:41,220 +لإن لو قلت هذه مثل طب وش كلها المجموعة التانية؟ + +180 +00:16:41,220 --> 00:16:44,320 +مالهاش اسم و لو قلت هذه فنل شو المجموعة التانية؟ + +181 +00:16:44,320 --> 00:16:50,400 +مالهاش اسم لكن ان نقول في سلسلة و هذه يا مسهلها + +182 +00:16:50,400 --> 00:16:57,960 +مثوكسي و في سلسلة و هذه يا مسهلها فينوكسي القمر + +183 +00:16:57,960 --> 00:17:04,070 +بيكون إيش؟سهل الان اطول سلسلة فيها double bond اذا + +184 +00:17:04,070 --> 00:17:09,690 +المركبة ال keen ال keen واحد اتنين تلاتة اربعة + +185 +00:17:09,690 --> 00:17:19,310 +خمسة ستة سبعة two heptane واضح two heptane الان + +186 +00:17:19,310 --> 00:17:26,250 +عليه ع موقع تلاتة methoxy وع موقع ستة phenoxy + +187 +00:17:26,250 --> 00:17:34,940 +بالترتيبthree methoxy six phenoxy + +188 +00:17:34,940 --> 00:17:42,280 +two heptane وكفى + +189 +00:17:42,280 --> 00:17:45,740 +الله المؤمنين القتال بس اللى بتسمى زيك بنحطله + +190 +00:17:45,740 --> 00:17:54,320 +تمانية من عشرة لسه موصلناش للعشرة من عشرة ليش ضايل + +191 +00:17:54,320 --> 00:18:00,650 +في التسمية ماجيبتهوشDouble bond اول ما نشوف double + +192 +00:18:00,650 --> 00:18:05,370 +bond فاكره ب Z و E و S و Trans و اول ما نشوف + +193 +00:18:05,370 --> 00:18:08,890 +chiral center فاكره بال R و S الان ايه double bond + +194 +00:18:08,890 --> 00:18:13,350 +ايش عليها اتشوميثل مختلفتان و هذا ال double bond + +195 +00:18:13,350 --> 00:18:19,250 +ايش عليها اوميثل و carbon مختلفتان اذا هذا المركب + +196 +00:18:19,250 --> 00:18:23,310 +منه واحد ولا اتنين اتنين اتنين لو قلتلكوا ارسموا + +197 +00:18:23,310 --> 00:18:27,810 +العيزو مرة تانية ايش أسهل طريقةلأ خدوه نحط ال اتش + +198 +00:18:27,810 --> 00:18:34,190 +تحت و الميثل فوق الان اتش و ميثل من الأعلى الميثل + +199 +00:18:34,190 --> 00:18:38,770 +الميثل لحظه هذه اللي ماتروه كهيك ميثل مش اتش انا + +200 +00:18:38,770 --> 00:18:43,030 +متعمد اتروه كهيك عشان أبقوا منتبهين لها ميثل اه هي + +201 +00:18:43,030 --> 00:18:51,270 +هذه الأعلى O و Carbon من الأعلى الان الأعلى على + +202 +00:18:51,270 --> 00:19:00,660 +جهة واحدة اذا هذا المركب Zهذا الاسم الكامل هذا دخل + +203 +00:19:00,660 --> 00:19:04,640 +فيه جزء من ال الكينز وجزء من ال الكينز وجزء من ال + +204 +00:19:04,640 --> 00:19:09,660 +ethers وهكذا العلم يصبح تجميعي لكل شيء درسناه + +205 +00:19:09,660 --> 00:19:15,960 +واتعلمناه اذا Z ثريميثوكسي سيكس فينوكسي توهيبتين + +206 +00:19:15,960 --> 00:19:18,140 +بهذا الشكل بنسمي المركب + +207 +00:19:22,520 --> 00:19:25,900 +طبعا ممكن تكون chiral center على طول بلاحظ R ولا S + +208 +00:19:25,900 --> 00:19:30,640 +هنا في chiral center لكن انا مش مركز عليه دايما + +209 +00:19:30,640 --> 00:19:34,340 +يعني ال chiral center اذا رسمته زي هيك معناه ذلك + +210 +00:19:34,340 --> 00:19:40,300 +انا طالبه منكم بس هنا بالتأكيد في chiral center لو + +211 +00:19:40,300 --> 00:19:43,800 +بدى افترض ان هدول بهذا الشكل المبينين وجهته بتكون + +212 +00:19:43,800 --> 00:19:49,150 +حددهدائما الكايرال سنتر إذا رسمناه كيا زي الصليب + +213 +00:19:49,150 --> 00:19:53,210 +معنا ذلك إحنا مركزين عليه مع ذلك تركينه بس هو أكيد + +214 +00:19:53,210 --> 00:19:59,350 +يا R يا S بس معرفين كوا ان كوا اتجاوبوا واضحة + +215 +00:19:59,350 --> 00:20:03,270 +الفكرة يعني يوم ما بدي الكايرال سنتر لو كنت بدي + +216 +00:20:03,270 --> 00:20:07,690 +بالتأكيد الكايرال سنتر هنا هتلاقوني رسمت الكيا زي + +217 +00:20:07,690 --> 00:20:17,330 +هيك O فنل CH3 H ال Aهنا بالتأكيد في عندكم chiral + +218 +00:20:17,330 --> 00:20:20,990 +center و المفروض تقدروا تعملوه و تقدروا تقولوا انه + +219 +00:20:20,990 --> 00:20:26,570 +أقل حاجة ال H ال O أعلى اشي بعدين الكربون المتصلة + +220 +00:20:26,570 --> 00:20:33,990 +بكربونات بعدين هذه S إذا chiral center واحد بلزمش + +221 +00:20:33,990 --> 00:20:40,170 +أحط له رقم إذا أكثر ممكن أحدد وين موقعه واضح؟ كل + +222 +00:20:40,170 --> 00:20:42,210 +شيء ممكن أدخله في الاسم + +223 +00:21:04,730 --> 00:21:09,810 +الان بالنسبة لل ethers استعملوا سابقا كمواد مخدرة + +224 +00:21:09,810 --> 00:21:14,670 +anesthetics والان بعض المشتقات منها زي هذا المركب + +225 +00:21:14,670 --> 00:21:17,450 +اللي فيه ذرات floro و chloro بناهاش نحفظه اسمه + +226 +00:21:17,450 --> 00:21:20,790 +penanthrene او هذا اللي فيه floro و chloro + +227 +00:21:20,790 --> 00:21:25,810 +enanthrene تستعمل في التخدير الطبي ال halogenated + +228 +00:21:25,810 --> 00:21:28,970 +ethers they are common anesthetics anesthetics + +229 +00:21:28,970 --> 00:21:33,650 +يعني مواد تستخدم في التخدير الطبيبدنا ننتبه لنقطة + +230 +00:21:33,650 --> 00:21:37,830 +كتير مهمة مش هنفصل فيها لكن الآن بنحكيها اللي ال + +231 +00:21:37,830 --> 00:21:42,410 +ether إذا خزنا لفترة طويلة بالذات بعد ما نفتح ال + +232 +00:21:42,410 --> 00:21:49,650 +bottle و يتعرض لل oxygenبيعمل مادة متفجرة peroxide + +233 +00:21:49,650 --> 00:21:54,530 +وبالتالي ممكن الشخص يجي يسخله طبعا مش عليها مباشرة + +234 +00:21:54,530 --> 00:21:59,950 +على سخان كهربائي مغلق اللي بنسميه tablet يكون فيه + +235 +00:21:59,950 --> 00:22:04,380 +المواد المتفجرة يروح ينفجر فيهالان هذه المواد + +236 +00:22:04,380 --> 00:22:08,320 +المتفجرة أشهر إيثر عادة بيستخدم اللي هو الـ + +237 +00:22:08,320 --> 00:22:13,800 +Diethyl Ether الان هذا لو انخزن لفترة طويلة بتفعل + +238 +00:22:13,800 --> 00:22:18,600 +مع الأكسجين بيعمله مركب زي هذا بيروكسايد هذا + +239 +00:22:18,600 --> 00:22:23,680 +البروكسايد ايش ماله؟Explosive الآن حسب كمية + +240 +00:22:23,680 --> 00:22:28,280 +الخزانة لو اتخزن كتير في جو سيء ممكن يعمل peroxide + +241 +00:22:28,280 --> 00:22:32,640 +ويترسب و تشوفوا بعينكم ان في قلب البوتل ال ether + +242 +00:22:32,640 --> 00:22:37,260 +مادة صلبة لو كانت بكمية صغيرة ممكن تكون دايب وما + +243 +00:22:37,260 --> 00:22:41,610 +تشوفوش بالعينينفي كل الأحوال لما بتحولوا لجزء عملي + +244 +00:22:41,610 --> 00:22:44,650 +أو بتاخدوا في يوم من الأيام جزء عملي المفروض + +245 +00:22:44,650 --> 00:22:48,530 +تفاصيل كيف نفحص ال ether كيف نتأكد منه قبل ما + +246 +00:22:48,530 --> 00:22:53,690 +نشتغل عليه هذا الأمر بتتعلموه الان لو في المستقبل + +247 +00:22:54,160 --> 00:22:58,620 +أشتغلت بكالوريوس، ماجستير، باحث في إيثر تسخين، في + +248 +00:22:58,620 --> 00:23:02,740 +هذه اللحظة خدوا كلمة واحدة إن الإيثر في منه خطر أن + +249 +00:23:02,740 --> 00:23:06,820 +يكون مواد متفجرة يوم ما يطلب منكوا حقيقة تشتغلوا و + +250 +00:23:06,820 --> 00:23:10,820 +تسخنوا بالإيثر ارجعوا لهذه المعلومة في كل كتب + +251 +00:23:10,820 --> 00:23:16,130 +العمل بدلكم بتفاصيل أكتر كيف تتأكدواإنه هالمادة + +252 +00:23:16,130 --> 00:23:19,850 +موجودة ولا لأ و لو موجودة كيف تتخلصوا منها و كل + +253 +00:23:19,850 --> 00:23:23,350 +الأشياء التفصيلية هذه لكن خلوا في ذهنكوا ان ال + +254 +00:23:23,350 --> 00:23:27,950 +ether مع سوق التخزين و في وجود ال oxygen بيعمل إيش + +255 +00:23:27,950 --> 00:23:36,090 +explosivematerials الان كيف بنحضر ال ethers اخدنا + +256 +00:23:36,090 --> 00:23:42,310 +احنا تحضير لل ethers لما درسنا ال alkenes و ال + +257 +00:23:42,310 --> 00:23:48,250 +alcohols قولنا ان ال alcohol لو سخناه عند 180 درجة + +258 +00:23:48,250 --> 00:23:54,460 +مئوية كان يعمل حذف للميه و يعطيناالالكين و عند 140 + +259 +00:23:54,460 --> 00:23:59,520 +درجة مئوية بيعطينا ال ether متذكرين هذه المعادلة + +260 +00:23:59,520 --> 00:24:03,300 +في كيمية ال alcohols اذا ال ethers they can be + +261 +00:24:03,300 --> 00:24:07,000 +prepared from alcohols طبعا انا لما بحكي عن ether + +262 +00:24:07,000 --> 00:24:11,450 +هنا بحكي عن ال symmetrical ethersماذا؟ إن إيثانول + +263 +00:24:11,450 --> 00:24:15,450 +يهاجم على إيثانول ويفقد ميّه وهذه المعادلة سابق + +264 +00:24:15,450 --> 00:24:20,190 +وضحتها إيها إيثانول زي إيثانول يخص منهم ميّه يعني + +265 +00:24:20,190 --> 00:24:24,770 +هذه المعادلة لو أريدها موزنة، ماذا أكتب هنا؟ H2O + +266 +00:24:24,770 --> 00:24:29,110 +واضح؟ جزء يهاجم على التانى ويطلع ميّه ويكون له + +267 +00:24:29,110 --> 00:24:34,880 +إيثرالان هذا الـ symmetrical ether ان الاثانول + +268 +00:24:34,880 --> 00:24:39,720 +اتفعل مع نفسه طيب يا تورا الان بيجيني السؤال لو + +269 +00:24:39,720 --> 00:24:45,320 +بدي un symmetrical ether يعني بدي ether في اثل و + +270 +00:24:45,320 --> 00:24:51,400 +مثل ايش اول شيء ممكن يخطر ع بالكم يعني لو بدي انا + +271 +00:24:51,400 --> 00:24:56,000 +دايم في ال ether شو اللي بسخنه مع الحامض؟ميثانول + +272 +00:24:56,000 --> 00:24:59,760 +لو بدى داي إثل إيثار شو اللى بسخنه مع الحامض + +273 +00:24:59,760 --> 00:25:05,540 +إثانول طيب لو بدى مثل إثل إيثار شو بدى أسخن مع + +274 +00:25:05,540 --> 00:25:09,500 +الحامض واضحة + +275 +00:25:09,500 --> 00:25:17,160 +الفكرة لو بدى مثل إثل إيثارأو إثل مثل إيثار الأن + +276 +00:25:17,160 --> 00:25:22,520 +انتبهوا معي أي واحدة ممكن تبدأ التفكير في مثل إثل + +277 +00:25:22,520 --> 00:25:28,400 +إيثار تقول باخد ال two alcohols يعني باخد مثل OH + +278 +00:25:28,400 --> 00:25:40,120 +زائد إثل OH بده يطلع لمثل OH إيش رأيكوا بهذا + +279 +00:25:40,120 --> 00:25:40,780 +الكلام؟ + +280 +00:25:43,190 --> 00:25:47,830 +بطلع لكن هنا في مشكلة انه انا لما بخلط بخلطش جزئ و + +281 +00:25:47,830 --> 00:25:52,030 +جزئ بخلط عدد كبير يعني لو خلطت mall و mall يعني + +282 +00:25:52,030 --> 00:25:55,990 +انا خلطت 6 في 10 او 23 من هذا مع 6 في 10 او 23 من + +283 +00:25:55,990 --> 00:26:00,290 +هذا الان كلهم موجودين خليني اعملها على النطاق + +284 +00:26:00,290 --> 00:26:06,110 +البسيط لو على نطاق جزيئين هذا ال ethanol و هذا ال + +285 +00:26:06,110 --> 00:26:09,600 +methanol و خلطتهم و قلتلهم يلا اتفاعلواأيش + +286 +00:26:09,600 --> 00:26:13,600 +الاحتمالات؟ هم بتفعلوا، سمعين؟ الان ممكن يلتقي + +287 +00:26:13,600 --> 00:26:20,260 +الاثل مع الاثل بي اثل اثر ممكن يلتقي المثل مع + +288 +00:26:20,260 --> 00:26:27,420 +المثل بي مثل اثر ممكن يلتقي الاثل مع المثل اثر مثل + +289 +00:26:27,420 --> 00:26:35,740 +اثر اذا هنا كم ناتج نتوقع؟ تلاتة مثل او مثل اثل او + +290 +00:26:35,740 --> 00:26:41,970 +اثلأو إثل أو ميثل بيطلع لكن مع اتنين تانين يعني + +291 +00:26:41,970 --> 00:26:46,310 +بيطلع خليط من تلت مراكبات و هات وفصلهم هل هذا + +292 +00:26:46,310 --> 00:26:51,890 +الكلام الكيميائي بيحبه؟ اطلاقا لا ولذلك اي حد + +293 +00:26:51,890 --> 00:26:56,590 +بيقول انه تحضير الإثل مثل إيثر بخلط الكحولينوهي + +294 +00:26:56,590 --> 00:27:00,530 +طلع الجواب بنقوله غلط لأنك طلعت تلت نواتج وبعدين + +295 +00:27:00,530 --> 00:27:05,170 +بدنا نشتغل نعمل انفصل وتقطير، هذه عملية إيش مالها؟ + +296 +00:27:05,170 --> 00:27:09,610 +متعبة ولذلك بنحول على طريقة تانية في تحضير الـ + +297 +00:27:09,610 --> 00:27:15,160 +Unsymmetrical ethos أيضا بنبتدأ فيها من وين؟من + +298 +00:27:15,160 --> 00:27:20,340 +الكحولات الان الكحولات واحد منهم وبشكل عام اللي + +299 +00:27:20,340 --> 00:27:25,520 +بيكون primary بنخليه يصير chloride يعني هذا لو + +300 +00:27:25,520 --> 00:27:32,900 +فعلناه مع ال BCl3 ايش هيصير CH3 CH2 بدل ما هو OH + +301 +00:27:32,900 --> 00:27:39,020 +Cl حولته ل chloride والتالي بحوله ل O minus كيف + +302 +00:27:39,020 --> 00:27:43,010 +الكحول بيصير O minus؟بالتفاعل مع السوديوم + +303 +00:27:43,010 --> 00:27:48,290 +هيدروكسايد؟ قلنا لأ بالتفاعل مع السوديوم أو + +304 +00:27:48,290 --> 00:27:51,890 +السوديوم هيدرايد هدولة التنين اللي بيصيروا يعني + +305 +00:27:51,890 --> 00:27:57,750 +هذا لو فعلته مع السوديوم بيصير مثل O minus and A + +306 +00:27:57,750 --> 00:28:04,840 +plusهيو ب فلاسك لحاله و هذا ب فلاسك لحاله لسه + +307 +00:28:04,840 --> 00:28:09,360 +ماخلطتهمش يعني إيجي إنسان أعطاكم هاي إيثانول و هاي + +308 +00:28:09,360 --> 00:28:13,420 +ميثانول هذا بالفلاسك واحد منهم بخليه ايش O minus + +309 +00:28:13,420 --> 00:28:19,900 +والتاني اكلورايد بعدين بضيف التانين على بعض بعدين + +310 +00:28:19,900 --> 00:28:23,600 +بضيف ايش التانين على بعض لو بضيف هذا على هذا هذا + +311 +00:28:23,600 --> 00:28:30,490 +ال O وين هتهاجم؟و إيش هتطرد؟ ال CL تفاعل الإقدال + +312 +00:28:30,490 --> 00:28:37,590 +اللي أخدناه ب chapter 6 لاحظوا إيش الناتج CH3 CH2O + +313 +00:28:37,590 --> 00:28:45,960 +مثل أو CH3 بس مركب واحدإذا أنا لما بدي ال un + +314 +00:28:45,960 --> 00:28:51,060 +symmetrical ethers لأخلط الكحولين مع بعض لأ واحد + +315 +00:28:51,060 --> 00:28:56,240 +منهم بحاوله ل O minus و واحد منهم بحاوله الى + +316 +00:28:56,240 --> 00:29:00,000 +chloride او bromide و بعدين بضيفهم مع بعض بطلعولي + +317 +00:29:00,000 --> 00:29:04,780 +فقط ناتج واحد هذه الطريقة في التحضير اسمها طريقة + +318 +00:29:04,780 --> 00:29:10,230 +السيد William Sun William Sun's synthesisWilliam + +319 +00:29:10,230 --> 00:29:14,410 +Sun's synthesis موجودة عندكم في ال slides وهين + +320 +00:29:14,410 --> 00:29:18,770 +وضحت بطريقة تانية انه مانخلطش الكحولين مع بعض + +321 +00:29:18,770 --> 00:29:24,090 +اطلاقا اطلاقا هذا الكلام مابيصيرش واضح الفكرة؟ + +322 +00:29:30,200 --> 00:29:34,580 +نشوف مرة تانية الـ Williamson's synthesis هاي مثلا + +323 +00:29:34,580 --> 00:29:40,500 +ROH مع ن إيه؟ شو أعطاني؟ R O minus هذا الـ charged + +324 +00:29:40,500 --> 00:29:45,300 +nucleophile و R X كوّنتها أساسا من الكحول لما أضيف + +325 +00:29:45,300 --> 00:29:50,800 +الـ R O minus على الـ R X أي تفاعل بعمل؟ الإبدال + +326 +00:29:50,800 --> 00:29:53,380 +ROR + +327 +00:29:54,350 --> 00:29:59,510 +الان اتخيلوا لو اتيكم how can you prepare this + +328 +00:29:59,510 --> 00:30:09,870 +ether فنل O CH2 CH3 الفكرة ان واحد منهم بدي اخليه + +329 +00:30:09,870 --> 00:30:15,330 +يعني انا بدي ابدأ من فنل OH و F OHلكن مين منهم بدي + +330 +00:30:15,330 --> 00:30:20,830 +أخليه O- ومين منهم بدي أخليه CL الان أنا قولت اللي + +331 +00:30:20,830 --> 00:30:25,610 +باخليه CL ال primary أو ال مثل إذا وجدت ما هو ال + +332 +00:30:25,610 --> 00:30:28,790 +مثل أفضل من ال primary يا ال primary يا المثل + +333 +00:30:28,790 --> 00:30:34,720 +وبناء على ذلك الفن ال OHهذا بخليه ايش مع ال sodium + +334 +00:30:34,720 --> 00:30:37,980 +او مع ال sodium hydroxide بيمشي اساسا لان الفينول + +335 +00:30:37,980 --> 00:30:41,800 +بتفاعل مع ال sodium hydroxide بيصير فينيل O minus + +336 +00:30:41,800 --> 00:30:48,620 +هي ال nucleophile فينيل O minus وهذا ال ethanol + +337 +00:30:48,620 --> 00:30:55,540 +بقدر انا اخليه من خلال التفاعل مع ال BCL3 CH3 + +338 +00:30:55,540 --> 00:31:03,380 +CH2CL اكيدالان لو فعلت هذا ال phenoxide هنا بيطرد + +339 +00:31:03,380 --> 00:31:09,330 +ال X و بيعطينا المركب المطلوب ولا لأ؟واضح؟ فالفكرة + +340 +00:31:09,330 --> 00:31:13,150 +في هذا النوع .. الفكرة في هذا النوع من الأسئلة لما + +341 +00:31:13,150 --> 00:31:17,150 +أجيبلكوا ether معين و أقولكوا كيف تحضروه أنكم + +342 +00:31:17,150 --> 00:31:20,450 +تعرفوا مين اللي بدي أخليه منه O minus مين اللي بدي + +343 +00:31:20,450 --> 00:31:24,270 +أخليه chloride الآن اللي بدي أخليه ال chloride يا + +344 +00:31:24,270 --> 00:31:29,630 +ال methyl يا ال primary هاي مسألة هنا شايفينها + +345 +00:31:29,630 --> 00:31:37,760 +تيرتشاريب بيوتلبروبل إيثار كيف يمكنك تجهيزه بدأ من + +346 +00:31:37,760 --> 00:31:44,680 +الكحول ارسم الانتوا الكحول احفظوا انتوا ايش + +347 +00:31:44,680 --> 00:31:52,260 +المطلوب تيرتشار بيوتل بروبل إيثار يعني كأنه عندكم + +348 +00:31:52,260 --> 00:32:01,200 +انتوا معطى هاي ال تيرتشار بيوتل وهاي البروبانول + +349 +00:32:01,200 --> 00:32:06,700 +هاي الانتوا الكحولالان ما طريقة التحضير واحد منهم + +350 +00:32:06,700 --> 00:32:15,000 +O- والتاني CL مين اللي بدي أخليه CL ال primary هذا + +351 +00:32:15,000 --> 00:32:20,300 +ال alcohol tertiary هذا ال alcohol ال primary إذا + +352 +00:32:20,300 --> 00:32:27,880 +هذا بعمله مع ال BCL3 هيوصار CL وهذا بعمله مع ال NA + +353 +00:32:27,880 --> 00:32:36,510 +هيوصار O-الان اخلطوا هادولا التانين مع بعض ايش + +354 +00:32:36,510 --> 00:32:40,910 +النتيجة؟ + +355 +00:32:40,910 --> 00:32:47,640 +هادي هتهاجم هان و تطردالـ CL المُركّب المطلوب مرات + +356 +00:32:47,640 --> 00:32:51,860 +لما يقولوا المُركّب المطلوب بيحطوا رمز TM مر عليكم + +357 +00:32:51,860 --> 00:32:55,620 +إيش يعني الـTM؟ زي ما في الهندس لما بتخلصوا الشغلة + +358 +00:32:55,620 --> 00:33:00,020 +بتقولوا هو المطلوب إثباته الآن TM يعني ال target + +359 +00:33:00,020 --> 00:33:05,020 +molecule يعني الجزء المطلوب target إيش target؟ + +360 +00:33:05,020 --> 00:33:11,520 +molecule الجزء المطلوب يعنييعني الـTM بلغة الكيميا + +361 +00:33:11,520 --> 00:33:15,820 +وهو المطلوب طبعاً هيكون زي هيك O وهي واحد، اتنين، + +362 +00:33:15,820 --> 00:33:21,100 +تلاتة واضحات؟ + +363 +00:33:21,100 --> 00:33:24,580 +الان لو واحدة عكست عملت هذا ال chloride وهذا الـO + +364 +00:33:24,580 --> 00:33:29,760 +minus بطلعش عندها يعني لو السؤال عليه عشر علامات + +365 +00:33:29,760 --> 00:33:35,900 +مجاملة نحط لها تلاتة او تنين لأنه + +366 +00:33:35,900 --> 00:33:42,040 +عملياً مابصيرشواضح؟ عملياً ما بيصيرش افهمنا هذه + +367 +00:33:42,040 --> 00:33:59,680 +الفكرة بوليام سانس سينتيسيز الان + +368 +00:33:59,680 --> 00:34:06,640 +ال ethers اتكونت طيب يا تورا ممكن تنكسبممكن تتفاعل + +369 +00:34:06,640 --> 00:34:10,900 +إلا بس تفاعل واحد فقط اللي هو الـ cleavage of + +370 +00:34:10,900 --> 00:34:16,020 +ether يعني ممكن ينكسر نص سيلة كيف بتم ال cleavage + +371 +00:34:16,020 --> 00:34:23,220 +of ether باستعمال الحامض القوي HI الـ HI بيهاجم + +372 +00:34:23,220 --> 00:34:30,020 +عادة في اليود وهذا هيو ماشي وين بده يروحالـ W مع + +373 +00:34:30,020 --> 00:34:33,200 +.. لأ على الـ Carbon اللي جنب الـ O الـ U السالب + +374 +00:34:33,200 --> 00:34:36,080 +.. الـ O السالب على الـ Carbon من بين الموجبات الـ + +375 +00:34:36,080 --> 00:34:39,360 +principal يعني هنا هذه الـ Carbon الموجبة و هذه + +376 +00:34:39,360 --> 00:34:43,860 +الموجبة هذه السالبة جزئياً لما بده يروح .. وين بده + +377 +00:34:43,860 --> 00:34:47,880 +يروح؟ على الموجب .. الآن لاحظوا معي لما بده يروح + +378 +00:34:47,880 --> 00:34:52,820 +على الموجب هيو ماشي ورايح على الموجب اليمين و لا + +379 +00:34:52,820 --> 00:34:58,480 +الموجب الشمالي افهمتوا وين السؤال؟ الآن على الـ + +380 +00:34:58,480 --> 00:35:05,900 +Primaryهذا المحور الان وين ال primary هان؟ وين ال + +381 +00:35:05,900 --> 00:35:12,420 +primary هان؟ ولذلك لما تطلع النتيجة هذا الجزء اللي + +382 +00:35:12,420 --> 00:35:18,340 +بيبقى معه ال O هياخد ال H هيصير فين ال O؟ H هياخد + +383 +00:35:18,340 --> 00:35:25,180 +ال H وهذا الجزء CH3 CH2 هيصير ايش؟Iodide شوفنا كيف + +384 +00:35:25,180 --> 00:35:29,780 +الـ cleavage الان هذا ماشي هنا ايه هنا؟ هيعطيني + +385 +00:35:29,780 --> 00:35:37,660 +CH3 CH2 CH2 I هذا معلوم CH3 CH2 CH2 I و هذا اللي + +386 +00:35:37,660 --> 00:35:43,380 +ضلت معه ال O شو هيصير OH هذا اللي هو ال cleavage + +387 +00:35:43,380 --> 00:35:50,680 +of ether هذا اللي هو ال cleavage of ether + +388 +00:35:52,990 --> 00:35:58,330 +باستعمال الـ HI غير هيك مش مشهور تفاعلات لل إيثارز + +389 +00:35:58,330 --> 00:36:03,310 +يعني هو تفاعل واحد الـ cleavage الكسر الآن في + +390 +00:36:03,310 --> 00:36:08,450 +إيثارز حلقية اسمها الـ Epoxides أخدتها بالتفصيل هي + +391 +00:36:08,450 --> 00:36:12,990 +و تفاعلاتها ولا لأ لما أخدنا تفاعلات الالكين و + +392 +00:36:12,990 --> 00:36:16,990 +قلنا الكين مع pear acid Epoxides وأخدتوا كمان + +393 +00:36:16,990 --> 00:36:21,670 +الحلقة بتفتح هنا واضحة + +394 +00:36:21,670 --> 00:36:26,890 +الفكرةأخدتوا كيف الحلقة بتفتح و كل هذا الكلام كل + +395 +00:36:26,890 --> 00:36:32,530 +هذه ال slides نفسها أخدناها الآن بيجينا آخر slide + +396 +00:36:32,530 --> 00:36:37,090 +اليوم عندنا هل ال cyclic ethers بس الحلقات + +397 +00:36:37,090 --> 00:36:43,430 +الثلاثية لأ طبعا في cyclic ethers حلقات أكبر يعني + +398 +00:36:43,430 --> 00:36:49,540 +مثلا الحلقة الخماسية هذا ether ORRcyclic ether + +399 +00:36:49,540 --> 00:36:54,820 +اسمه tetrahydrofuran باختصار THF هذا solvent مشهور + +400 +00:36:54,820 --> 00:37:02,360 +طب هذه الحلقة اسمها tetrahydropyrene هذا في ether + +401 +00:37:02,360 --> 00:37:08,060 +و ether دي ether ORR و ORR اسمه ديوكسين مركب + +402 +00:37:08,060 --> 00:37:14,300 +كارسينوجينيك مركب كارسينوجينيك وسام في مركبات حلوة + +403 +00:37:14,300 --> 00:37:19,260 +طلع عليها منظرها حلو ولا لأو دايما الاشي المنظرة + +404 +00:37:19,260 --> 00:37:23,980 +حلو بيحاولوا يعطوا اسم ايش اسم حلو يعني العلماء + +405 +00:37:23,980 --> 00:37:28,160 +لما بيعملوا اختراع لشغل مرات بيعملوا مسابق مين + +406 +00:37:28,160 --> 00:37:32,640 +يخترعلها اسم حلو و لو بتفتشوا مثلا لما اكتشفوا + +407 +00:37:32,640 --> 00:37:39,640 +نايلون كشيء جميل ليش في النهاية سموه نايلون؟اسم + +408 +00:37:39,640 --> 00:37:44,360 +حلو عملوا مسابقات لحد ما حد اخترع لهم اسم جميل زي + +409 +00:37:44,360 --> 00:37:47,520 +اللي بده يفتح بوتيك ولا اشي مش بيحاول يلاجيله اسم + +410 +00:37:47,520 --> 00:37:52,380 +حلو هدول عشانهم حلوين شو صموهم ال crown ethers + +411 +00:37:52,380 --> 00:37:58,020 +هدول اكتشفوهم مش زمان يعني بعد ال 1980 تقريبا + +412 +00:37:58,020 --> 00:38:02,460 +واللي اكتشفوهم أخدوا عليهم جائزة نوبل في الكيميا + +413 +00:38:02,460 --> 00:38:09,600 +بال 1987 اسمهم ايش ال crown ethersإيش قصته ما دول + +414 +00:38:09,600 --> 00:38:15,220 +ال crown ethers؟ أكسجين بعدين CH2 CH2 بعدين أكسجين + +415 +00:38:15,220 --> 00:38:19,980 +CH2 CH2 بعدين أكسجين هم لاحظين أكثر من ether في + +416 +00:38:19,980 --> 00:38:23,820 +بعض طب لما بدهم يسموهم قالوا كيف بدنا نسميهم؟ هاي + +417 +00:38:23,820 --> 00:38:29,780 +واحدة و هادي أكبر و هادي أكبر قال بسيطة استعملوا + +418 +00:38:29,780 --> 00:38:34,140 +اسم ال crown okay crown قالوا قبل ال crown عدوا كل + +419 +00:38:34,140 --> 00:38:39,130 +الذرات المحيطة يعني لو بديت أعد من هنا واحدأتنين + +420 +00:38:39,130 --> 00:38:43,550 +تلاتة أربعة خمسة لفتهم كلهم بلاحظ انه العدد الكل + +421 +00:38:43,550 --> 00:38:48,390 +اتنائش فبروح بكتب ال twelve يعني العدد الكل قداش + +422 +00:38:48,390 --> 00:38:53,730 +اتنائش ال crown كام اكسوجينة عندكم اربعة twelve + +423 +00:38:53,730 --> 00:38:59,930 +crown four الان هذا العدد الكل خمس عشر خمس + +424 +00:38:59,930 --> 00:39:05,790 +اكسوجينات شو حيصير fifteen crown five هذا + +425 +00:39:10,900 --> 00:39:17,000 +واضح؟طيب فى ناس لسه مقتنعوش بيقولوا يعنى ليش أخدوا + +426 +00:39:17,000 --> 00:39:21,760 +جائزة نوبل على شغل زى هذه يعنى سويانا الان لاحظوا + +427 +00:39:21,760 --> 00:39:26,100 +هدولة فى اللهم تجويف هنا عارفين التجويف شو بيسموه + +428 +00:39:26,100 --> 00:39:31,160 +بالإنقليزي cavity ممتازين جدا اللهم cavity ال + +429 +00:39:31,160 --> 00:39:34,520 +cavity هذه ممكن يدخل ضيف عليها يعنى هم يكونوا + +430 +00:39:34,520 --> 00:39:40,390 +المضيف ايش معناه المضيف hostممكن ييجي guest يدخل + +431 +00:39:40,390 --> 00:39:44,290 +جوا زي ما البني آدم عنده قوضة لضيوف و بيجي ضيف + +432 +00:39:44,290 --> 00:39:48,010 +يدخل فيها طب لو بدنا نجيب ضيف يدخل هنا، إيش بده + +433 +00:39:48,010 --> 00:39:53,650 +يكون هذا الضيف؟ اطلعولي إن ال oxygen يحمل أزواج + +434 +00:39:53,650 --> 00:39:54,850 +إلكترونات + +435 +00:39:57,510 --> 00:40:00,990 +و بدو يجي يضيفي بوسط هالسحابة الإلكترونية، شو بدو + +436 +00:40:00,990 --> 00:40:07,330 +يكون؟ موجب، ايش أشهر الموجب؟ الـmetal ions، Sodium + +437 +00:40:07,330 --> 00:40:13,330 +Plus, Potassium Plus, Cesium Plus و هكذا، اذا هنا + +438 +00:40:13,330 --> 00:40:19,440 +لما بدو يدخل، ايش هيدخل؟ Metal Plusلأن الجو العام + +439 +00:40:19,440 --> 00:40:25,160 +كله سالب اللي بدو يجي يدخل إيش؟ معدن موجب طب الآن + +440 +00:40:25,160 --> 00:40:29,000 +اتطلعولي على ال cavities ال cavities هذه إلها + +441 +00:40:29,000 --> 00:40:33,320 +أحجام ولا كلها نفس الحجم؟ أحجام طب و آيونات + +442 +00:40:33,320 --> 00:40:40,860 +المعادن مش في الجدول الدوري عندكم ن إيه؟ بوتاسيوم؟ + +443 +00:40:40,860 --> 00:40:47,450 +سيزيوم؟الان هذا حجمه صغير، هذا أكبر، هذا أكبر، إذا + +444 +00:40:47,450 --> 00:40:53,590 +هل كل Ion بيجي على كل cavity ولا فيه تناسو؟ Ion + +445 +00:40:53,590 --> 00:40:58,650 +معين بيدخل ب cavity معينة Ion معين بيدخل بcavity + +446 +00:40:58,650 --> 00:41:03,730 +معينة يعني مثلا هذا المركب ال 18 crown 6 لما جاسوا + +447 +00:41:03,730 --> 00:41:08,230 +حجم ال cavity تبعتهبين اتنين و ستة من عشرة لتلاتة + +448 +00:41:08,230 --> 00:41:12,030 +و اتنين من عشرة أنجسترون طب حجم ايون الصوديوم واحد + +449 +00:41:12,030 --> 00:41:15,510 +و تسعة واحد و تسعة لو حطناه من هنا إيش بيعمل + +450 +00:41:15,510 --> 00:41:21,490 +الفتحة كبيرة عليه بيجع منها ال cesium تلاتة و + +451 +00:41:21,490 --> 00:41:27,550 +تلاتة أكبر من الفتحة بيدخلش مين اللي بتناسب معها + +452 +00:41:27,550 --> 00:41:31,990 +اتنين و ستة و ستين وهذه اتنين و ستة لتلاتة و اتنين + +453 +00:41:32,930 --> 00:41:37,910 +البوتاسيوم إذا لو حطينا ال crown الآن و جيبنا + +454 +00:41:37,910 --> 00:41:42,650 +التلت أيونات معادن هو فيه cavity الان ال cavity + +455 +00:41:42,650 --> 00:41:50,330 +واحد صغير بيدخل منها بيوقع والتاني كبير ما بيجيش + +456 +00:41:50,330 --> 00:41:54,970 +والتالت المتناسب مين اللي هيقعد في قلب ال cavity؟ + +457 +00:41:55,610 --> 00:42:01,130 +البوتاسيوم اذا هذا ال crown صار لو حطناله التلاتة + +458 +00:42:01,130 --> 00:42:05,390 +صاد منهم البوتاسيوم و ساب التانين التانين عارفين + +459 +00:42:05,390 --> 00:42:09,990 +الفكرة زي ايش؟ زي الشبكة تبعت صيادين السمك صياد + +460 +00:42:09,990 --> 00:42:13,530 +السمك عنده اكتر من شبكة لكل موسم كل شبكة فيها حجم + +461 +00:42:13,530 --> 00:42:19,110 +اليوم لما بدو يصيد البوري عنده حجم معين بيمسك سمكة + +462 +00:42:19,110 --> 00:42:24,200 +البوري طب و السردين؟في شبكة البوري بيدخل و بيطلع + +463 +00:42:24,200 --> 00:42:27,320 +قدامه هو مش ناوي يصيده بيدخل و بيطلع أو السمك + +464 +00:42:27,320 --> 00:42:30,460 +الصغير لما بديه يصيد السردين شو بديه يستعمل إلها؟ + +465 +00:42:30,460 --> 00:42:35,000 +شبكة أصغر أفهمتوا إيش الفكرة هنا في ال host و ال + +466 +00:42:35,000 --> 00:42:39,840 +guest؟ إنه ال guest الضيف اللي بديه ييجي هنا اللي + +467 +00:42:39,840 --> 00:42:44,560 +هو المثل هذا ال guest لازم يكون حجمه متناسب مع + +468 +00:42:44,560 --> 00:42:51,240 +إيش؟ مع ال cavity وهذا الكلام له حتى تطبيقات في + +469 +00:42:51,240 --> 00:42:56,940 +وين؟في المجال الطبي في الأدوية يعني آخر slide الآن + +470 +00:42:56,940 --> 00:43:03,220 +عندنا هاي هذا المركب في نفس الفكرة بطريقة أو باخره + +471 +00:43:03,220 --> 00:43:10,380 +و في cavity هناhigh cavity هذه الكفتي تبعته افتسع + +472 +00:43:10,380 --> 00:43:16,300 +البوتاسيوم يعني لما يكون فيه نا بلس وبوتاسيوم بلس + +473 +00:43:16,300 --> 00:43:20,980 +في جسم الإنسان من اللي بيدخل في الكفتي البوتاسيوم + +474 +00:43:20,980 --> 00:43:25,940 +الآن هذا المضاد الحيوي بدخل جوا الخلية لما يدخل + +475 +00:43:25,940 --> 00:43:31,500 +بدخل بما حمل إذا إيش جدر يدخل جوا الخلية؟ + +476 +00:43:32,150 --> 00:43:37,190 +البوتاسيوم ايش صاب برا الخلية الصوديوم بنسمي هذه + +477 +00:43:37,190 --> 00:43:43,630 +العملية ايش selective transport يعني هو دخل واحد + +478 +00:43:43,630 --> 00:43:50,770 +من اتنين هي الخلية هي جدارها هذه هي الخلية المضاد + +479 +00:43:50,770 --> 00:43:55,560 +بيقدر يدخل في جلب الخليةو بيقدر يحمل واحد من + +480 +00:43:55,560 --> 00:43:58,620 +الاتنين، مين اللي بيقدر يحمله؟ ال potassium + +481 +00:43:58,620 --> 00:44:01,920 +المتناسب مع حجم ال cavity بناء على ذلك هو في الأول + +482 +00:44:01,920 --> 00:44:05,500 +بيحمل ال potassium، بعدين هو بما حمله بيدخل جوا + +483 +00:44:05,500 --> 00:44:11,000 +الخلية بزامو دخل، نجل ال potassium من برا لجوا + +484 +00:44:11,700 --> 00:44:15,900 +فاهمتوا أين الجمال بفكرة crown ethers يعني بسرها + +485 +00:44:15,900 --> 00:44:21,900 +انعكاس على واقع التطبيق الطبي بهك بنكون أنهينا هذا + +486 +00:44:21,900 --> 00:44:24,140 +ال chapter اللي اسمه ال ethers + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/DfMI5-FZy7w_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/DfMI5-FZy7w_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..f934fe6825f721f4346367742641468b6914e900 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/DfMI5-FZy7w_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4227, "start": 19.71, "end": 42.27, "text": "بسم الله الرحمن الرحيم المرة الماضية اخر شئ اتكلمنا فيه عن تحضير ال carboxylic acids وربما يعني كلكم ملاحظين ان عنوان الفصل هذا carboxylic acids and their derivatives لاحظوا لما اقول derivative يعني مشتقة يعني بنجيبها من إيش؟", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 1975, 34740, 13412, 19986, 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اللاكتون؟ اسمها lactam يعني زي ما في لاكتون في إيش lactam الآن لو قولنا إيش ال lactams lactams are cyclic amides يعني لو كررنا", "tokens": [12610, 18513, 6225, 2304, 13672, 995, 4117, 2655, 11536, 23032, 3555, 3615, 995, 3714, 9957, 49429, 3215, 6225, 2304, 13672, 995, 4117, 2655, 11536, 22807, 11933, 1829, 8592, 24525, 2304, 11296, 18863, 26895, 3660, 13672, 1829, 4724, 1829, 30544, 14407, 49429, 3215, 6225, 2304, 13672, 995, 4117, 2655, 11536, 22807, 24525, 2304, 11296, 34042, 335, 37495, 22653, 30767, 1829, 19446, 8978, 5296, 995, 4117, 2655, 11536, 8978, 11933, 1829, 8592, 34042, 335, 6024, 48506, 45164, 12174, 12610, 8315, 11933, 1829, 8592, 2423, 34042, 4070, 34042, 4070, 366, 38154, 1050, 669, 1875, 37495, 22653, 45164, 9122, 2288, 2288, 8315], "avg_logprob": -0.16445707341637275, "compression_ratio": 1.9479768786127167, "no_speech_prob": 0.0, "words": [{"start": 1861.5, "end": 1862.04, "word": "ولاد", "probability": 0.95947265625}, {"start": 1862.04, "end": 1862.4, "word": " 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R C double bond O and H2 إذا ال E stars بتتفاعل مع ال ammonia بتعطيني ايش أمد هذا التفاعل شو بنسمي احنا Ammonosis of E stars ف E stars زائد ammonia أمد هاي E star تاني مثل Benzoate لما فعلوا مع ال ammonia شو اللي بدأت تتردد؟", "tokens": [6027, 39184, 19654, 2423, 39184, 19654, 8032, 2655, 9381, 13546, 13931, 8032, 1829, 9566, 1211, 3615, 48779, 41850, 4724, 16095, 1863, 2423, 8315, 2655, 7435, 16247, 3794, 32277, 1829, 16247, 2304, 3215, 497, 383, 3834, 6086, 422, 293, 389, 17, 11933, 15730, 2423, 462, 6105, 39894, 2655, 5172, 995, 30241, 20449, 2423, 46833, 39894, 3615, 9566, 9957, 1829, 1975, 1829, 8592, 5551, 2304, 3215, 23758, 16712, 5172, 995, 30241, 13412, 2407, 44945, 38251, 1829, 1975, 5016, 8315, 2012, 3317, 8211, 295, 462, 6105, 6156, 462, 6105, 30767, 16373, 3215, 46833, 5551, 2304, 3215, 8032, 47302, 462, 3543, 6055, 7649, 1829, 50113, 1211, 3964, 89, 78, 473, 5296, 15042, 6156, 30241, 14407, 20449, 2423, 46833, 13412, 2407, 13672, 1829, 47525, 10721, 2655, 6055, 2655, 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هذا", "probability": 0.9765625}, {"start": 2334.99, "end": 2337.21, "word": " واضح؟", "probability": 0.8778076171875}, {"start": 2337.21, "end": 2337.57, "word": " هذا", "probability": 0.9677734375}, {"start": 2337.57, "end": 2338.17, "word": " الأمد", "probability": 0.9847005208333334}, {"start": 2338.17, "end": 2338.43, "word": " شو", "probability": 0.93896484375}, {"start": 2338.43, "end": 2339.95, "word": " هو؟", "probability": 0.902587890625}, {"start": 2339.95, "end": 2340.71, "word": " لاحظوا", "probability": 0.94677734375}, {"start": 2340.71, "end": 2341.65, "word": " بنيجي", "probability": 0.8541259765625}, {"start": 2341.65, "end": 2342.61, "word": " للحمض", "probability": 0.7890625}, {"start": 2342.61, "end": 2343.55, "word": " الأساسي", "probability": 0.9827880859375}, {"start": 2343.55, "end": 2344.19, "word": " المكون", "probability": 0.671142578125}], "temperature": 1.0}, {"id": 98, "seek": 237203, "start": 2345.45, "end": 2372.03, "text": "الفنل سي دابل بوند او او ات شو 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السؤال هيك form أمد اللي هتفكروا فيه إيش هو ال formic acid", "tokens": [326, 327, 5551, 2304, 3215, 4032, 46958, 5016, 6156, 6027, 10721, 2304, 3215, 44945, 7435, 1829, 3555, 3224, 9154, 2423, 8258, 4724, 28814, 44510, 6027, 1975, 2407, 4117, 5551, 3794, 3215, 4724, 28814, 1829, 8592, 4724, 10721, 2304, 3215, 23032, 3555, 45164, 12174, 1211, 8315, 5296, 4117, 14407, 47525, 8315, 1254, 5551, 2304, 3215, 11933, 1829, 3224, 10874, 995, 4117, 14407, 21136, 33604, 6027, 39896, 4117, 1254, 5551, 2304, 3215, 13672, 1829, 8032, 2655, 5172, 37983, 14407, 8978, 3224, 11933, 1829, 8592, 31439, 2423, 1254, 299, 8258], "avg_logprob": -0.22904829494655132, "compression_ratio": 1.6459627329192548, "no_speech_prob": 0.0, "words": [{"start": 2374.65, "end": 2375.49, "word": "acid", "probability": 0.4541015625}, {"start": 2375.49, "end": 2376.61, "word": " أمد", "probability": 0.7205403645833334}, {"start": 2376.61, "end": 2378.31, "word": " واضح", "probability": 0.8260091145833334}, {"start": 2378.31, 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file diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/DfMI5-FZy7w_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/DfMI5-FZy7w_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..0384d3e3287b544821819ed91f02e1bb81535d63 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/DfMI5-FZy7w_raw.srt @@ -0,0 +1,1760 @@ +1 +00:00:19,710 --> 00:00:23,950 +بسم الله الرحمن الرحيم المرة الماضية اخر شئ + +2 +00:00:23,950 --> 00:00:28,510 +اتكلمنا فيه عن تحضير ال carboxylic acids وربما + +3 +00:00:28,510 --> 00:00:33,890 +يعني كلكم ملاحظين ان عنوان الفصل هذا carboxylic + +4 +00:00:33,890 --> 00:00:38,130 +acids and their derivatives لاحظوا لما اقول + +5 +00:00:38,130 --> 00:00:42,860 +derivative يعني مشتقة يعني بنجيبها من إيش؟من + +6 +00:00:42,860 --> 00:00:48,100 +الكربوكسيلك أسد ولذلك لو بنطلع على slide واحد + +7 +00:00:48,100 --> 00:00:53,500 +وبنحط هنا الكربوكسيلك أسد وبنفعله وقلنا احنا ان + +8 +00:00:53,500 --> 00:00:58,460 +التفاعل الأساسي هو تفاعل الإبدال يعني بدنا نطلع + +9 +00:00:58,460 --> 00:01:04,220 +هذا ال OH ونحط شغلة مكانها واضح فلو فعلنا مع + +10 +00:01:04,220 --> 00:01:08,380 +الثيون الكلوريد على سبيل المثال في وجود base بنحط + +11 +00:01:08,380 --> 00:01:13,070 +ال CL بدل ال OH صار عند ال acid chlorideالاسد + +12 +00:01:13,070 --> 00:01:20,810 +كلورايد الاسد + +13 +00:01:20,810 --> 00:01:25,950 +كلورايد الاسد كلورايد الاسد كلورايد الاسد كلورايد + +14 +00:01:25,950 --> 00:01:25,950 +الاسد كلورايد الاسد كلورايد الاسد كلورايد الاسد + +15 +00:01:25,950 --> 00:01:26,130 +كلورايد الاسد كلورايد الاسد كلورايد الاسد كلورايد + +16 +00:01:26,130 --> 00:01:26,530 +الاسد كلورايد الاسد كلورايد الاسد كلورايد الاسد + +17 +00:01:26,530 --> 00:01:27,970 +كلورايد الاسد كلورايد الاسد كلورايد الاسد كلورايد + +18 +00:01:27,970 --> 00:01:28,210 +الاسد كلورايد الاسد كلورايد الاسد كلورايد الاسد + +19 +00:01:28,210 --> 00:01:31,050 +كلورايد الاسد كلورايد الاسد كلورايد الاسد كلورايد + +20 +00:01:31,050 --> 00:01:34,650 +الاسد كلورايد الاسد كلورايد + +21 +00:01:38,040 --> 00:01:42,160 +هذا الجزء و من الحامض التاني اللى بتفعل كان + +22 +00:01:42,160 --> 00:01:45,700 +يوكليوفايل كان يوكليوفايل اللى بيجينا R C double + +23 +00:01:45,700 --> 00:01:51,060 +bond O O واضح الحامض التاني اصلا كان OH و + +24 +00:01:51,060 --> 00:01:54,840 +لليوكليوفايل لما يكون neutral بيفقد H الان هذا + +25 +00:01:54,840 --> 00:01:59,020 +الشكل العام C double bond O O C double bond O هو + +26 +00:01:59,020 --> 00:02:05,760 +اللى بنسمي احنا ايش acid anhydrideunhydrate اذا + +27 +00:02:05,760 --> 00:02:10,080 +بالتفاعل اول حضرنا ال acid chloride او الهيلايد + +28 +00:02:10,080 --> 00:02:15,720 +بالتفاعل التاني حضرنا ال unhydrate الان لو فعلنا + +29 +00:02:15,720 --> 00:02:19,440 +مع الكحول النيكليوفال اللى بده تهاجم ال O تحت ال + +30 +00:02:19,440 --> 00:02:24,700 +OH هيصير عندنا R C double bond O O R prime طبعا + +31 +00:02:24,700 --> 00:02:29,120 +هذا ال E star و + +32 +00:02:29,120 --> 00:02:35,150 +لو فعلنا مع ammonia derivativeسواء NH3 ولا NH2R + +33 +00:02:35,150 --> 00:02:40,310 +ولا NHR2 المهم نيتروجين النيتروجين بتهاجم مكان ال + +34 +00:02:40,310 --> 00:02:45,770 +OH في هذه الحالة بده يطلع عندك الأمد سيضة بال bond + +35 +00:02:45,770 --> 00:02:53,310 +ON هذه الأمد سواء كانت NH2 ولا NHR ولا NR2 كل هذا + +36 +00:02:53,310 --> 00:03:02,240 +الكلام ممكن إذا بهذا الشكل بنكون حضرناالامد هدولة + +37 +00:03:02,240 --> 00:03:07,020 +بشكل أساسي هم ال derivatives بتاع الكربوكسيلك أسد + +38 +00:03:07,020 --> 00:03:11,360 +فزي ما بنلاحظ ان كل هذه ال derivatives للكربوكسيلك + +39 +00:03:11,360 --> 00:03:16,680 +أسد من وان حضرناها من نفس الكربوكسيلك أسد ربما + +40 +00:03:16,680 --> 00:03:21,680 +التفاعل الأخير اللي بتشوفوه تفاعل مختلف شوية مش + +41 +00:03:21,680 --> 00:03:26,620 +تفاعل إبدال لأ هو تفاعل أسد مع base يعني تخيلوا ال + +42 +00:03:26,620 --> 00:03:32,480 +base اللي هنا مثلا NaOHزي ما نفعل ال acetic acid + +43 +00:03:32,480 --> 00:03:35,740 +مع ال sodium hydroxide بسرعة تفاعل ال + +44 +00:03:35,740 --> 00:03:41,920 +neutralization بمعنى ال OH هتاخد ال H فقط منها مش + +45 +00:03:41,920 --> 00:03:49,940 +هتشيل ال OH, OH مع H هتعطيناالماية H2O والنا هنا + +46 +00:03:49,940 --> 00:03:56,020 +بيصير ايون موجب زي ما بتلاحظوا انتوا ان هنا صار حم + +47 +00:03:56,020 --> 00:04:01,580 +زائد قاعدة ملح زائد ماء لو افترضنا ان الحمض acidic + +48 +00:04:01,580 --> 00:04:08,000 +acid زائد NaOH بتصير sodium acetate لما هذه تكون + +49 +00:04:08,000 --> 00:04:15,440 +خلينا نحط مثال حقيقي CH3C double bond OOH الان + +50 +00:04:15,440 --> 00:04:21,940 +تفاعل ال neutralization ان ال OH مع ال H هذي + +51 +00:04:21,940 --> 00:04:28,540 +هيعملوا عندنا الميه صارها ايون سالب هذا ايون موجب + +52 +00:04:28,540 --> 00:04:30,980 +صوديوم استيت + +53 +00:04:33,070 --> 00:04:38,010 +CH3 هذا neutralization reaction اخر تفاعل اذا + +54 +00:04:38,010 --> 00:04:44,610 +تفاعلات الأحمض بشكل عام يا اما تفاعلات ابدال تبدل + +55 +00:04:44,610 --> 00:04:50,450 +فيها ال OH كاملة يا اما تفاعلات neutralization او + +56 +00:04:50,450 --> 00:04:55,750 +معادلة neutralization + +57 +00:04:57,520 --> 00:05:01,640 +أنه تفاعل ال neutralization الأخير التفاعلات + +58 +00:05:01,640 --> 00:05:03,240 +الأربع الأولانيين + +59 +00:05:05,900 --> 00:05:10,580 +substitution واضح يعني ضلكم اتذاكرين هذه الكلمة + +60 +00:05:10,580 --> 00:05:14,840 +لما نقولكم reaction of acids with alcohols is a + +61 +00:05:14,840 --> 00:05:18,100 +substitution reaction with ammonia or amine + +62 +00:05:18,100 --> 00:05:21,460 +derivative is a substitution with other acids with + +63 +00:05:21,460 --> 00:05:25,400 +thionyl chloride لكن reaction of acids with sodium + +64 +00:05:25,400 --> 00:05:31,740 +hydroxide is a neutralization reaction تفاعلمعادلة + +65 +00:05:31,740 --> 00:05:38,760 +حم زائد قاعدة ملح زائد ماء واضح؟ إذ هيك بنكون مش + +66 +00:05:38,760 --> 00:05:44,800 +بس احنا أخدنا تفاعلات الأحماض لأ أخدنا طرق تحضير + +67 +00:05:44,800 --> 00:05:48,400 +جميع العائلات يعني يوم ما بنيجي نقول والله كيف + +68 +00:05:48,400 --> 00:05:54,620 +بنحضر ال Easter على سبيل المثال هنقول حم زائد كحول + +69 +00:05:55,200 --> 00:05:59,940 +حمزايد كحول ولذلك هنا لو بدنا نيجي نركز أكتر على + +70 +00:05:59,940 --> 00:06:06,660 +ال Easter ال Easter دائما بيتكون من حامض و كحول + +71 +00:06:06,660 --> 00:06:12,480 +ولذلك ماعرفش إذا هذه الصورة يمكن مش كثيرواضحة لأ + +72 +00:06:12,480 --> 00:06:18,400 +بس بنعملها بوضوح احنا لو أخدنا مثلا ابروبانووك أسد + +73 +00:06:18,400 --> 00:06:26,520 +خليني أخد المعادلة المعادلة كاملة CH3 CH2 CH2 CH2 + +74 +00:06:26,520 --> 00:06:26,660 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +75 +00:06:26,660 --> 00:06:35,240 +CH2 CH2 CH2 CH2 + +76 +00:06:35,240 --> 00:06:38,400 +CH2 + +77 +00:06:38,400 --> 00:06:41,080 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +78 +00:06:41,080 --> 00:06:41,100 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +79 +00:06:41,100 --> 00:06:41,120 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +80 +00:06:41,120 --> 00:06:41,120 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +81 +00:06:41,120 --> 00:06:41,120 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +82 +00:06:41,120 --> 00:06:41,120 +CH2 CH2 CH2 CH + +83 +00:06:52,770 --> 00:06:57,670 +بناء على ذلك لو كنا بدنا نشوف الناتج CH3 + +84 +00:07:00,330 --> 00:07:06,310 +CH2 CH2 C double bond O هذا الجزء اتيه من حمض من + +85 +00:07:06,310 --> 00:07:09,850 +الحمض من الحمض من الحمض من الحمض من الحمض من الحمض + +86 +00:07:09,850 --> 00:07:09,990 +من الحمض من الحمض من الحمض من الحمض من الحمض من + +87 +00:07:09,990 --> 00:07:10,550 +الحمض من الحمض من الحمض من الحمض من الحمض من الحمض + +88 +00:07:10,550 --> 00:07:10,950 +من الحمض من الحمض من الحمض من الحمض من الحمض من + +89 +00:07:10,950 --> 00:07:11,550 +الحمض من الحمض من الحمض من الحمض من الحمض من الحمض + +90 +00:07:11,550 --> 00:07:13,550 +من الحمض من الحمض من الحمض من الحمض من الحمض من + +91 +00:07:13,550 --> 00:07:17,130 +الحمض من الحمض من الحمض من الحمض من الحمض من الحمض + +92 +00:07:17,130 --> 00:07:17,130 +من الحمض من الحمض من الحمض من الحمض من الحمض من + +93 +00:07:17,130 --> 00:07:23,390 +الحمض من الحمض من الحمض من الحمض من الحمض من الحمض + +94 +00:07:23,390 --> 00:07:32,300 +من الحمض منال Easter هو عبارة عن خليط من جزئين جزء + +95 +00:07:32,300 --> 00:07:35,500 +من الحامض اللى فيه ال C double bond O و جزء من + +96 +00:07:35,500 --> 00:07:42,680 +الكحول اللى متصلبالـ O العادية الان لما بنيجي نسمي + +97 +00:07:42,680 --> 00:07:48,720 +هذا المركب لما بنيجي نسمي هذا المركب كيف بنسمي مثل + +98 +00:07:48,720 --> 00:07:53,540 +هذا المركب بنجيب في الأول الجزء تبع الكحول هذا + +99 +00:07:53,540 --> 00:07:58,680 +بنحطه في الأول بعدين الجزء تبع الحامض بنحطه بعدين + +100 +00:07:58,680 --> 00:08:04,080 +الان من جزء الكحول باخد المجموعة المجموعة كام + +101 +00:08:04,080 --> 00:08:11,820 +carbon؟تلاتة، تلاتة كربونات، شو هما؟ بروبل مش + +102 +00:08:11,820 --> 00:08:16,160 +لليوم بدنا نضل نقول بروبان، بروبان المركب المجموعة + +103 +00:08:16,160 --> 00:08:24,080 +بروبل واضح؟ بروبل وجزء الحامض باخده بس بنهيب ده + +104 +00:08:24,080 --> 00:08:30,780 +هاية eight فbutanoic acid بدو يصير ايش؟ بيوتانويت + +105 +00:08:30,780 --> 00:08:32,880 +بيوتانويت + +106 +00:08:33,880 --> 00:08:38,560 +ليش جزء الحامض انا انهيته بالنهاية ايه لانه انا + +107 +00:08:38,560 --> 00:08:43,660 +تخيلته مع ال O هذه صار كأنه سيضب البند O O minus + +108 +00:08:43,660 --> 00:08:49,140 +الان كأنه ايون سالب يعني لو تخيلته بدل الاثل كان + +109 +00:08:49,140 --> 00:08:55,880 +عندكم صوديوم ايش هتسموا المركب صوديوم بيوتانويت لو + +110 +00:08:55,880 --> 00:09:02,270 +بوتاسيوم بوتاسيوم بيوتانويت لو اثلethyl butanoate + +111 +00:09:02,270 --> 00:09:08,130 +فدائما هذا الشكل من الاسم هو اسم ال Easter جزء + +112 +00:09:08,130 --> 00:09:12,390 +الكحول في الأول مذكورة المجموعة لحظة بيقول بس + +113 +00:09:12,390 --> 00:09:17,380 +propyl ماحدش يقول propoxyباخد بس ال الكلي جروب + +114 +00:09:17,380 --> 00:09:21,840 +بربل و من الحامض لان اعتبرت كأنه جايب c double + +115 +00:09:21,840 --> 00:09:26,580 +bond o o minus اعتبرت كأنه ايون سالب بيوتانوويت + +116 +00:09:26,580 --> 00:09:32,680 +الان هذه التسمية هنشوف عليها عدة أنثلة لحد ما + +117 +00:09:32,680 --> 00:09:38,920 +نتأكد لحد ما نتأكد تماما انه أصبح واضح تسمية ال + +118 +00:09:38,920 --> 00:09:45,470 +easters في ذهنكم دائما و أبدالما بنشوف شكل ال + +119 +00:09:45,470 --> 00:09:50,710 +Easter C double bond O OR إذا هذا Easter الإسم + +120 +00:09:50,710 --> 00:09:57,370 +العام تبعه إيش؟ مجموعة الكل و نهاية eight الآن هنا + +121 +00:09:57,370 --> 00:10:02,310 +شو مجموعة الكل؟ مثل إذا لازم يجيني في الأول مثل + +122 +00:10:02,310 --> 00:10:09,650 +الحامض اللي من كربونتين acidic acidطالما أسيتك أسد + +123 +00:10:09,650 --> 00:10:14,490 +إذا نحن حنحط أسيتيت طب لو ناس سموه بال أيوبك + +124 +00:10:14,490 --> 00:10:21,210 +ايثانويك أسيد ايثانويت فالميثل أسيتيت هي الميثل + +125 +00:10:21,210 --> 00:10:26,010 +ايثانويت لسبب بسيط أنه الأسيتك أسيد هو نفسه ال + +126 +00:10:26,010 --> 00:10:31,110 +ايثانويك أسيدواضح ال Acetic Acid اللي من كربونتين + +127 +00:10:31,110 --> 00:10:36,570 +هو نفسه ال Ethanoic Acid زي ما كمان ال Formic Acid + +128 +00:10:36,570 --> 00:10:41,150 +هو نفسه ال ايش ال Methanoic Acid هذا الكلام حكيناه + +129 +00:10:41,150 --> 00:10:44,150 +فدائما انظروا ل ال Alkyl group و اذكرواها في الأول + +130 +00:10:44,150 --> 00:10:48,510 +الآن هذا المركب اللي هنا شو ال Alkyl group اللي + +131 +00:10:48,510 --> 00:10:54,390 +موجودة فيه اثل و طالما انكوا two carbons اذا اثل + +132 +00:10:55,120 --> 00:11:05,440 +اسيتيت او اثل اثانويت هذا المركب ايش المجموعة مثل + +133 +00:11:05,440 --> 00:11:13,260 +مثل اربع كربوناتبيوتانويت مثل بيوتانويت الان + +134 +00:11:13,260 --> 00:11:17,720 +لاحظوا هذا المركب و هذا المركب بتشوفهم بيشبهوا بعض + +135 +00:11:17,720 --> 00:11:21,820 +حقيقة لو اي حد اتطلع they are structural isomers + +136 +00:11:21,820 --> 00:11:26,640 +بس بيختلفوا بمواقع الارتباط مرة هنا ال O مرتبطة + +137 +00:11:26,640 --> 00:11:30,780 +بالفنل و ال C double bond O بالمثل مرة ال O بالمثل + +138 +00:11:30,780 --> 00:11:35,500 +و ال C double bond O بالفنللكن لو كنا بنسميهم الآن + +139 +00:11:35,500 --> 00:11:40,280 +هذا الجزء يجب أن يُذكر في الأول شو هذا الجزء؟ فنل + +140 +00:11:40,280 --> 00:11:46,020 +و Carbontene أسيتيت أو إيثانويت الآن لو بدأ أسمي + +141 +00:11:46,020 --> 00:11:52,540 +هذا المُركّب مثل .. هذا من أي حامض جاية؟ بنزويك + +142 +00:11:52,540 --> 00:12:01,300 +أسد بنزويك أسد بنزويت مثل بنزويت واضح؟لاحظوا كثير + +143 +00:12:01,300 --> 00:12:05,940 +مرات بيمروا معاكم بالعربي بنزوات السوديوم و مرة + +144 +00:12:05,940 --> 00:12:10,860 +سألنا .. قولنا للطلاب ارسموا شكل السوديوم بنزويت + +145 +00:12:10,860 --> 00:12:19,860 +كيف بدنا نعمله؟ بتقولوا هاي البنزويت فنل سيضة + +146 +00:12:19,860 --> 00:12:25,420 +بالبند O O minus هذه البنزويت تلحق معها السوديوم + +147 +00:12:27,810 --> 00:12:33,650 +Sodium Benzoate مثل Benzoate بنفس المنطق تماما + +148 +00:12:36,540 --> 00:12:41,060 +يعني تسمية ال salt شبيهة بتسمية ال easter سوديوم + +149 +00:12:41,060 --> 00:12:46,640 +بنزويت مثل بنزويت الان كل هدول عبارة عن easters + +150 +00:12:46,640 --> 00:12:52,620 +ضلكم الذاكرين شغلة ان ال easter في الاولويات جايب + +151 +00:12:52,620 --> 00:12:55,800 +اعلى الاولويات يعني اعلى من ال aldehyde و من ال + +152 +00:12:55,800 --> 00:12:59,520 +alcohol و من ال ketone و من ال carboxylic acid + +153 +00:12:59,520 --> 00:13:05,810 +ولذلك لو كنا بدنا نعطيأمثلة بتحتوي على أكثر من + +154 +00:13:05,810 --> 00:13:12,010 +مجموعة وظيفية بدنا ال Easter يكون في الأول، واضح؟ + +155 +00:13:12,010 --> 00:13:15,550 +يعني بناخد جزء ال Easter في الأول، بنعتبر هذه + +156 +00:13:15,550 --> 00:13:20,210 +المجموعة الوظيفية زايدة، الآن رغم أنه الكلام الآن + +157 +00:13:20,210 --> 00:13:23,910 +عشان تكون الأمور واضحة عندكم، رغم أنه الكلام الآن + +158 +00:13:23,910 --> 00:13:32,750 +بيبدو بسيطلكن واقع التجربة بيقول ان نسبة 95% منكم + +159 +00:13:32,750 --> 00:13:38,190 +لانه مابكتبوش كتير ومابعدوش كتير ومابتعبوش كتير لا + +160 +00:13:38,190 --> 00:13:43,840 +يجيبوا سؤال تسمية ال Easter صحالتجربة جديش بتقول + +161 +00:13:43,840 --> 00:13:52,040 +95% مابيجاوبوش صح رغم انه الكلام واضح ليش؟ بيبدأ + +162 +00:13:52,040 --> 00:13:55,880 +يخربطوا بيبدأ يقولوا هذا الديهايد حامل على موقع + +163 +00:13:55,880 --> 00:14:02,860 +واحد اثوكسي مثلا لأ هي السيطة بال bond O OR كلها E + +164 +00:14:02,860 --> 00:14:07,980 +star خلاص بتنتهي أحيانا بيسمي اثل بعدين بيجي يقول + +165 +00:14:07,980 --> 00:14:13,830 +one oxoكله دخل الـ C double bond O و الـ O ethyl + +166 +00:14:13,830 --> 00:14:18,570 +يعني الأصل في هذا المُركّب انه تتطلع على الهيكل + +167 +00:14:18,570 --> 00:14:23,570 +العام هذا ماعدل ذلك هدول إيش اللي موجودين عليه + +168 +00:14:23,570 --> 00:14:28,770 +Substitutes الآن هنا في عندي C double bond O و O + +169 +00:14:28,770 --> 00:14:32,770 +ethyl إذا المُركّب E star فلو أنا كنت بدي أسمي بدي + +170 +00:14:32,770 --> 00:14:39,420 +أحط في البدايةEthane و في اخر الاسم اعد الكربونات + +171 +00:14:39,420 --> 00:14:43,860 +الان واحد اتنين تلاتة اربعة اذا هذا المركب حقيقة + +172 +00:14:43,860 --> 00:14:51,960 +اثن ايش بيوتانو ويتethyl butanoate الان هذا ال + +173 +00:14:51,960 --> 00:14:55,760 +ethyl butanoate بيحمل مجموعات شو المجموعات اللي + +174 +00:14:55,760 --> 00:15:00,100 +بيحملها بنذكرها alphabetically على الأتنين كلورو و + +175 +00:15:00,100 --> 00:15:04,680 +على التلاتة أوكزو هذا كيتون رجع لأصله لما يكون مش + +176 +00:15:04,680 --> 00:15:09,180 +هو العائلة شو بده أسميه أوكزو إذا هذا إثل و دائما + +177 +00:15:09,180 --> 00:15:14,900 +بنسيب فراغ بين مجموعة القلقل و باقي الإسم فبصير + +178 +00:15:14,900 --> 00:15:26,150 +إثلتنين كلورو نكتب لتنين اثلتو كلورو ثري اكزو + +179 +00:15:26,150 --> 00:15:32,090 +بيوتانويت اثلتو كلورو ثري اكزو بيوتانويت هذه كلمة + +180 +00:15:32,090 --> 00:15:39,430 +واحدة اثلتو كلورو ثري اكزو بيوتانويت واضحة الفكرة + +181 +00:15:39,430 --> 00:15:45,300 +فدائما لما بتكون تسمه E startسيبكوا من التفرعات + +182 +00:15:45,300 --> 00:15:49,600 +خدوا السلسلة الأساسية حطوا جزء الكحول في البداية + +183 +00:15:49,600 --> 00:15:55,260 +وجزء الحامض الأساسي في النهاية وبعدين بتدخلوا + +184 +00:15:55,260 --> 00:16:02,240 +الأشياء اللي هي substituents أيا كانت خلينا إذا + +185 +00:16:02,240 --> 00:16:06,420 +خلصته هذا نشوف كل الأمثلة اللي موجودة + +186 +00:16:11,880 --> 00:16:18,340 +الان هذا المثال في alcohol علين والرأس OH و في C + +187 +00:16:18,340 --> 00:16:24,000 +double bond OOR إذا المثال اللى موجود عندى حقيقة + +188 +00:16:24,000 --> 00:16:30,740 +Easter لازم أطلع وين المجموعة اللى مرتبطة بال .. + +189 +00:16:30,740 --> 00:16:35,920 +بال C double bond OOR شو هذه ال R؟ بنا نكون + +190 +00:16:35,920 --> 00:16:40,780 +حافظينها هذه isopropyl + +191 +00:16:42,590 --> 00:16:47,430 +الان بعدين بدي جزء ال acid اجيبه من عند ال CWO و + +192 +00:16:47,430 --> 00:16:55,630 +اعده للاخر واحد اتنين تلاتة اربعة خمسة CH3HUN او + +193 +00:16:55,630 --> 00:17:05,430 +CH3HUN ستة اذا hexane hexane weightهدولة مكونات ال + +194 +00:17:05,430 --> 00:17:10,230 +Easter الان ايش اللي زاد عنهم؟ ماحدش يجي يدخلها دي + +195 +00:17:10,230 --> 00:17:13,230 +السيطة و البندقوة هذي جزء من ال Easter ال Easter + +196 +00:17:13,230 --> 00:17:21,030 +سيطة و البندقوة اوها لكن اللي زايدين حقيقة و المثل + +197 +00:17:21,030 --> 00:17:28,150 +و المثل هدولة لما بدنا ندخلهم هيكونوا four Hydroxy + +198 +00:17:32,780 --> 00:17:44,780 +3,5-dimethyl 4-hydroxy-3,5-dimethylhexanoate واضح + +199 +00:17:44,780 --> 00:17:50,720 +فدائما لما تسموا Easter انظروا إلى الطرفين اكتبوهم + +200 +00:17:50,720 --> 00:17:57,660 +في الأول و بعدين بتحطوا الأشياء الزايدة واضح هى + +201 +00:17:57,660 --> 00:18:03,170 +عندى هنا كمان Easterبالاضافة لل Easter سيضا بالبند + +202 +00:18:03,170 --> 00:18:08,430 +O O مثل ايش في عندي مجموعة وظيفية ال keen واضح + +203 +00:18:08,430 --> 00:18:12,030 +طبعا ال Easter اعلى من ال ال keen اذا هذا لم ابدا + +204 +00:18:12,030 --> 00:18:16,570 +اسميه شو المجموعة اللي هنا مثل هتكون في البداية + +205 +00:18:16,570 --> 00:18:23,350 +مثل الآن نعد واحد اتنين تلاتة اربعة + +206 +00:18:26,330 --> 00:18:31,750 +طبعا لأنه بيوتان بدون double bond في ال double + +207 +00:18:31,750 --> 00:18:40,310 +bond شو بيصير بيوتين فبنحطه بيوتين و wait واضح + +208 +00:18:40,310 --> 00:18:44,690 +يعني لما يكون في double bond هنكتبه بيوتين لو كله + +209 +00:18:44,690 --> 00:18:49,530 +single bonds بيوتان لو كان في triple bond بيوتين + +210 +00:18:49,530 --> 00:18:58,730 +الان وين نقطة بداية الين هنا اتنينفهذا بيصير مثل + +211 +00:18:58,730 --> 00:19:04,330 +two butenoate ف ال in موقعها إيش؟ two يعني ال two + +212 +00:19:04,330 --> 00:19:09,550 +هنا بتوضح موقع ال in مثل two butenoate + +213 +00:19:26,770 --> 00:19:31,190 +الان واحدة منكم تعطينا المركب اللي بعده كأنها + +214 +00:19:31,190 --> 00:19:40,930 +بتشرح تقول شو اللي موجود وكذا اتفضل ايش + +215 +00:19:40,930 --> 00:19:47,670 +اللي موجود عندى انا ايش المجموعات الوظيفية C + +216 +00:19:47,670 --> 00:19:52,430 +double bond O O Finnel او OR او AR هذا Easter هذا + +217 +00:19:52,430 --> 00:19:56,950 +كله Easterالان هذه السيطة بالبوند او الطرفية + +218 +00:19:56,950 --> 00:20:02,470 +الديهايد بيضلوا من الأعلى ال a star اذا هابدأ + +219 +00:20:02,470 --> 00:20:10,750 +بالمجموعة اللي مع ال او ال final الان الجزء الأخير + +220 +00:20:15,460 --> 00:20:19,900 +بروبان انا بحبش طريقتك في التسمية تاني مرة ترفعيش + +221 +00:20:19,900 --> 00:20:24,760 +إيدك أنا بحب تجيبيلي الأشياء الأساسية لأنه انا لو + +222 +00:20:24,760 --> 00:20:28,500 +بدي أصلح السؤال من خمس علامات هحط أربع على حدان و + +223 +00:20:28,500 --> 00:20:32,520 +بعدين قلتي بال أجزة و بالمجموعة الزايدة دائما و + +224 +00:20:32,520 --> 00:20:37,140 +أبدا الإنسان بيحط الهيكل الأساسي في الإسم واضح؟ + +225 +00:20:37,440 --> 00:20:41,880 +ماتهوش في الأشياء البسيطة يعني اللي بتشتغل زيك فنل + +226 +00:20:41,880 --> 00:20:46,440 +بروبانويت و عنده ميت شغلة متفارعة كلهم بنسامح فيهم + +227 +00:20:46,440 --> 00:20:52,140 +لكن أهم شيء إن كنت شوفنا الهيكل الأساسي للاسم هو + +228 +00:20:52,140 --> 00:20:56,740 +فنل بروبانويت الآن هذا الفنل بروبانويت إيجي على + +229 +00:20:56,740 --> 00:21:05,070 +نمرة تلاتة منهأجزو صار اثري أجزو في نل او في نل + +230 +00:21:05,070 --> 00:21:13,310 +اثري أجزو بربا نويت واضح؟ اتفضلي اثل اول مجموع اسم + +231 +00:21:13,310 --> 00:21:18,470 +بعدها بنت .. بنتاي و ايه؟ الان هنا في عند اثل هي + +232 +00:21:18,470 --> 00:21:24,290 +جزء ال Easter عدت واحد اتنين تلاتة اربعة خمسة + +233 +00:21:24,290 --> 00:21:27,690 +فقالت بنتاي + +234 +00:21:29,570 --> 00:21:38,250 +بنتين و ويت واضح الآن هذه البنتين الأين وين بتبدأ + +235 +00:21:38,250 --> 00:21:45,190 +اذا اثن اتو بنتين و ويت لاحظوا انا مابنحطش قبلها + +236 +00:21:45,190 --> 00:21:50,510 +شرطة لأن هذه كلمة مفصولة عن هدولفي تسمية ال + +237 +00:21:50,510 --> 00:21:54,870 +Easter's ال Easter's زي ما بتسموه Sodium فراغ + +238 +00:21:54,870 --> 00:21:59,690 +Hydroxide Sodium فراغ Acetate في فراغ هنا مش شرطة + +239 +00:21:59,690 --> 00:22:05,490 +مش كلمة واحدة بتيألي يعني هذه المجموعة من الأمثلة + +240 +00:22:05,490 --> 00:22:10,990 +ل Easter مع مجموعات وظيفية مختلفة يعني كافية + +241 +00:22:10,990 --> 00:22:14,590 +لتوضيح طريقة تسمية هذه المركبات + +242 +00:22:17,340 --> 00:22:23,060 +الان هنا تأكيد طبعا كيف بنكون ال Easter هاي كمان + +243 +00:22:23,060 --> 00:22:30,100 +معادلتين تأكيديات حمض زائد كحول حمض زائد كحول و + +244 +00:22:30,100 --> 00:22:34,680 +دائما بالكوتيجو الكحول يتخلو يحل محل ال OH و الاسم + +245 +00:22:34,680 --> 00:22:41,000 +من جزئين يعني هذا اثل استيت او اثانويت هذا مثل + +246 +00:22:41,000 --> 00:22:51,250 +واحداتنين تلاتة بروبانويت و هكذاالان هذه ال + +247 +00:22:51,250 --> 00:23:00,070 +easters مشهور عنها ان ذات رائحة جميلة ولذلك احيانا + +248 +00:23:00,070 --> 00:23:04,170 +تستخدم في المراكبات العطرية لكن اكثر تستخدم + +249 +00:23:04,170 --> 00:23:10,450 +كاضافات للاطعمة وهي حقيقة اللي بتعطي الروائح + +250 +00:23:10,450 --> 00:23:16,610 +المميزة .. الروائح المميزة لكثير من الفواكه + +251 +00:23:16,940 --> 00:23:20,280 +فبتلاحظوا أنه الريحة المميزة للواحد لما بيشم + +252 +00:23:20,280 --> 00:23:27,320 +الفراولة بيشم المشمش في رائحة مميزة له الآن هذه + +253 +00:23:27,320 --> 00:23:31,500 +الرائحة المميزة من ال easters so easters are + +254 +00:23:31,500 --> 00:23:38,340 +smelly stuffs يعني مواد رائحة بالمجمل جيدة فعلى + +255 +00:23:38,340 --> 00:23:43,060 +سبيل المثال هذا ال easter الأول مثل من ال butanoic + +256 +00:23:43,060 --> 00:23:48,790 +acid مثل ال butanoateهذا اللي بيعطي ريحة الطفاح + +257 +00:23:48,790 --> 00:23:55,450 +الابل فالريحة تبعت الطفاح مثل ال butanoid هو اللي + +258 +00:23:55,450 --> 00:24:01,030 +بيعطي ريحة الطفاح الان يبدو ال butanoic acid متكرر + +259 +00:24:01,030 --> 00:24:07,230 +كتير يعني لو بدل ال مثل حطينا sh3 صار مثل فيومثل + +260 +00:24:07,230 --> 00:24:17,950 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +261 +00:24:17,950 --> 00:24:18,530 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +262 +00:24:18,530 --> 00:24:24,570 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +263 +00:24:24,570 --> 00:24:27,430 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +264 +00:24:27,430 --> 00:24:31,650 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +265 +00:24:31,650 --> 00:24:32,870 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +266 +00:24:32,870 --> 00:24:33,370 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +267 +00:24:33,370 --> 00:24:33,390 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +268 +00:24:33,390 --> 00:24:33,390 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +269 +00:24:33,390 --> 00:24:38,310 +مثل مثل مثو الاثل مثل بيوتانويت هذا اثل بيوتانويت + +270 +00:24:38,310 --> 00:24:43,290 +لما يصير اثل بيوتانويت بيصير رائحة الفني بالز + +271 +00:24:43,290 --> 00:24:50,930 +عارفينه الاناناس الاناناس اه الان لو صار بنتل يعني + +272 +00:24:50,930 --> 00:24:58,030 +خمس كربونات بنتل بيوتانويت مختلفين على الاناناس + +273 +00:24:58,030 --> 00:25:06,540 +اناناسبنت الابيوتانويت هذا ريحة الابريكوت المشمش + +274 +00:25:06,540 --> 00:25:13,620 +مش الخوخ الابريكوت مشمش apricosen بالالماني الخوخ + +275 +00:25:13,620 --> 00:25:19,620 +فريشي أو هات إشي الآن + +276 +00:25:19,620 --> 00:25:24,580 +في النهاية كيف بنجيب ال E star؟ + +277 +00:25:26,760 --> 00:25:31,860 +كحول اتطلعوا معاه، كحول هي كحول جيبنا كحول من San + +278 +00:25:31,860 --> 00:25:36,220 +Salvador و acid من Honolulu شبكناهم شو اعطونا + +279 +00:25:36,220 --> 00:25:42,840 +Easter طيب السؤال عاد لو يا تورا الكحول و الحامض + +280 +00:25:42,840 --> 00:25:46,260 +كانوا بجزء واحد ممكن يتفاعلوا؟ + +281 +00:25:48,950 --> 00:25:54,490 +يعني على طرف الجزيء حامض و على الطرف التاني كحول، + +282 +00:25:54,490 --> 00:25:57,750 +بتفاعلوا ولا بتفاعلوش؟ واجده إيش بيكون اسمه + +283 +00:25:57,750 --> 00:26:04,910 +التفاعل؟لأ إله اسم إذا فعلت جزيئين مفصولين عن بعض + +284 +00:26:04,910 --> 00:26:07,670 +زي هيك وعمله مركّب إيش قولنا هذا التفاعل + +285 +00:26:07,670 --> 00:26:12,870 +Intermolecular إذا جبت الجزيئين شبكت + +286 +00:26:12,870 --> 00:26:17,110 +Intermolecular reaction خلّينا نشوف إنه بنقدر إحنا + +287 +00:26:17,110 --> 00:26:24,710 +فعلا نحطبنقدر نحط حامض على أحد الأطراف و كحول على + +288 +00:26:24,710 --> 00:26:28,490 +الطرف التالي و نخليهم يتفاعلوا يعني زي ما نيجي + +289 +00:26:28,490 --> 00:26:33,710 +تماما نقول هنا C double bond O OH هذا إيش؟ حامض + +290 +00:26:33,710 --> 00:26:42,190 +CH2 CH2 CH2 CH2 خلينا هنا نحط OH الآن في هذا + +291 +00:26:42,190 --> 00:26:50,500 +المركب إيش موجود عندكم؟ acid و alcohol عادةالكحول + +292 +00:26:50,500 --> 00:26:57,200 +بتفاعل مع الحامض كان يوكليوفايل وبيطرد يعني هذه + +293 +00:26:57,200 --> 00:27:05,220 +بدأ تيجي ها و تطرد ايش ال OH واضح نفس التفاعل هو + +294 +00:27:05,220 --> 00:27:09,460 +لو كانوا مفصلين مجرد ان انا هذا ممكن اكون كاتب CH3 + +295 +00:27:09,460 --> 00:27:13,280 +و هذا CH3OH كيف كنت اكمله يعني تخيلوا ال + +296 +00:27:13,280 --> 00:27:17,940 +Intermolecular reaction لو هذا زي هيككيف كنتوا + +297 +00:27:17,940 --> 00:27:23,060 +تكملوا؟ من هنا يهاجم و من هنا يطرد الان هذولة + +298 +00:27:23,060 --> 00:27:28,940 +كانوا ضمن جزء واحد ايش المانع؟ مش ولا مانع الان + +299 +00:27:28,940 --> 00:27:37,320 +الناتج C double bond O واحد و هنا O بهذا الشكل + +300 +00:27:37,320 --> 00:27:46,020 +طبعا ال O H مع ال Hالان لاحظوا الناتج المتكول لو + +301 +00:27:46,020 --> 00:27:51,800 +بدى اعطيه وصف هو عبارة عن ايش؟ Cyclic Easter هو + +302 +00:27:51,800 --> 00:27:57,860 +عبارة عن C double bond OOR لكن موجودين بحلقة فهذا + +303 +00:27:57,860 --> 00:28:05,580 +الناتج هو عبارة عن Cyclic Easterواضح؟ الان ال + +304 +00:28:05,580 --> 00:28:13,220 +cyclic esters اللي هم اسم عام بنسميهم lactones ال + +305 +00:28:13,220 --> 00:28:22,000 +cyclic esters بنسميهم lactones الان + +306 +00:28:22,000 --> 00:28:28,140 +لو جينا قولنالكم lactones are cyclic amides or + +307 +00:28:28,140 --> 00:28:38,140 +cyclic anhydridesاللاكتونز are cyclic esters طبعا + +308 +00:28:38,140 --> 00:28:44,980 +مرات عشان يوضحوا كده كبر الحلقة تبعت هذا ال cyclic + +309 +00:28:44,980 --> 00:28:49,570 +esters يعني هذه الحلقة الآن خماسيةلو كانت ال + +310 +00:28:49,570 --> 00:28:52,770 +oxygen على هذه الكربون نشبكناها كانت ممكن تكون + +311 +00:28:52,770 --> 00:28:56,110 +حلقة رباعية لو ال oxygen هنا نشبكناها ممكن تكون + +312 +00:28:56,110 --> 00:29:01,250 +حلقة ثلاثية ولذلك مرات بيستعملوا الرموز اللاتينية + +313 +00:29:01,250 --> 00:29:04,890 +بيقولوا خلينا نيجي جنب السيضة بال bond O ونبدأ + +314 +00:29:04,890 --> 00:29:11,830 +نقول AlphaBeta Gamma الآن ال Oxygen اللي عملت ال + +315 +00:29:11,830 --> 00:29:17,210 +Easter محمولة على أي Carbon Gamma ولذلك هذا مرات + +316 +00:29:17,210 --> 00:29:22,770 +كتير بيقولوا عنه Gamma Lactone طبعا بيصير سهل + +317 +00:29:22,770 --> 00:29:27,630 +عليكم انه تعرفوا ان ال Gamma Lactone هو تبع الحلقة + +318 +00:29:27,630 --> 00:29:33,950 +الخمسية واضح؟ اللي فيه ال Oxygen محمولة على الموقع + +319 +00:29:35,010 --> 00:29:39,230 +Gamma طب لو كانت ال Oxygen على الموقع Beta وقتها + +320 +00:29:39,230 --> 00:29:45,630 +شو بده يصير الحلقة رباعية Beta Lactone يعني لو + +321 +00:29:45,630 --> 00:29:51,030 +احنا اتينا الآن بعد ما خلصنا هذا و جيبنالكم سؤال + +322 +00:29:51,030 --> 00:29:55,410 +ارسمولنا في الامتحان Beta Lactone + +323 +00:30:04,170 --> 00:30:08,410 +Draw a general structure زي هي جايكم of a beta + +324 +00:30:08,410 --> 00:30:13,410 +-lactone الآن اللي شاطرة بتعرف اللي هو ال beta + +325 +00:30:13,410 --> 00:30:19,470 +-lactone Cyclic Eastern يعني هتبدأ هنا سيضة بال + +326 +00:30:19,470 --> 00:30:24,830 +bond O وتقول هاي ال carbon Alpha هاي ال carbon + +327 +00:30:24,830 --> 00:30:30,530 +Beta على ال beta حط ال oxygen هاي Alpha وهاي Beta + +328 +00:30:32,930 --> 00:30:39,230 +هي ال beta-lactone واضح؟ على موقع بيتا حط الأكسجين + +329 +00:30:39,230 --> 00:30:47,250 +و سكر الإيستر طبعا ال lactones مركبات مهمة لكن + +330 +00:30:47,250 --> 00:30:54,530 +اللي أهم منها في الدنيا بكتير مين؟ + +331 +00:30:54,530 --> 00:31:02,400 +مين اللي أهم من ال lactone؟ أولاد عمهمولاد عم + +332 +00:31:02,400 --> 00:31:05,960 +اللاكتون طبعا مين ولاد عم اللاكتون؟ إيش اسمها + +333 +00:31:05,960 --> 00:31:10,560 +العيلة اللي بيكونوا ولاد عم اللاكتون؟ اسمها lactam + +334 +00:31:10,560 --> 00:31:16,340 +يعني زي ما في لاكتون في إيش lactam الآن لو قولنا + +335 +00:31:16,340 --> 00:31:21,620 +إيش ال lactams lactams are cyclic amides يعني لو + +336 +00:31:21,620 --> 00:31:22,580 +كررنا + +337 +00:31:24,870 --> 00:31:29,030 +نفس المعادلة اللى كانت عندنا قبل شوية C double + +338 +00:31:29,030 --> 00:31:34,050 +bond O OH وحطينا carbon تنتين تلاتة وهنا كنا حاطين + +339 +00:31:34,050 --> 00:31:41,470 +NH2 النيوكليوفايل وقلنا لهذا المركب سكر ايش اللى + +340 +00:31:41,470 --> 00:31:47,330 +بده يصير ال nitrogen بده تهاجم هنا تترد ال OH + +341 +00:31:47,330 --> 00:31:49,970 +لاحظوا شو النتج اللى هيتكون عندكم + +342 +00:32:08,570 --> 00:32:14,610 +cyclic amides are called lactams + +343 +00:32:15,920 --> 00:32:23,080 +إذا صار في علتين في Cyclic Esters اسمهم Lactones + +344 +00:32:23,080 --> 00:32:28,900 +وفي Cyclic Amides اسمهم Lactams إذا في عندي + +345 +00:32:28,900 --> 00:32:34,000 +Lactones و Lactams طبعا هذا لو قولت أي Lactam هاي + +346 +00:32:34,000 --> 00:32:40,360 +Alpha Beta Gamma هذا Gamma Lactam فالGamma Lactam + +347 +00:32:40,360 --> 00:32:47,480 +كم الحلقة تبعته؟خماسية طب لو كنت بده ال beta + +348 +00:32:47,480 --> 00:32:59,780 +lactam رباعية واضح نرسم + +349 +00:32:59,780 --> 00:33:00,700 +beta lactam + +350 +00:33:06,300 --> 00:33:12,300 +هي عندنا C double bond O carbon تنتين تلاتة هنا + +351 +00:33:12,300 --> 00:33:20,340 +نيتروجين هذه عبارة عن ايش هاي الفا + +352 +00:33:20,340 --> 00:33:27,560 +هاي بيتا هذه عبارة عن بيتا لكتب + +353 +00:33:30,900 --> 00:33:35,860 +تمام؟ الآن .. الآن بنحط الألاجة لاحظوا معايا .. + +354 +00:33:35,860 --> 00:33:40,220 +يمكن أنا من وجهة نظري .. يمكن أنا من وجهة نظري أن + +355 +00:33:40,220 --> 00:33:47,360 +أهم .. خدوها و أنتم غامضين .. يمكن أهم مركبات في + +356 +00:33:47,360 --> 00:33:52,640 +الكيميا اكتشفت و اشتغل عليها في القرن الماضي كله + +357 +00:33:52,640 --> 00:33:59,500 +ربما تكون ال beta lactams شوف لحد وين مهمةأهم + +358 +00:33:59,500 --> 00:34:06,380 +مركبات ممكن و من أهم اكتشافات القرن الماضي كله ال + +359 +00:34:06,380 --> 00:34:11,300 +beta-lactams ليش؟ + +360 +00:34:11,300 --> 00:34:18,840 +ليش ال beta-lactams؟ عشان نظلنا متذكرينهم وين السر + +361 +00:34:18,840 --> 00:34:26,650 +اللي فيهم؟هما تعون المضادات الحيوية البنسالين وكل + +362 +00:34:26,650 --> 00:34:32,130 +مشتقاته beta lactams ال antibiotics طبعا في مضادات + +363 +00:34:32,130 --> 00:34:36,450 +غير ال beta lactams البنسالين بشكل عام هو عبارة عن + +364 +00:34:36,450 --> 00:34:41,550 +الحلقة الرابعية هذه مع حلقة خماسية و عليهم شوية + +365 +00:34:41,550 --> 00:34:46,650 +شغلات بيصير البنسالين واضح؟ + +366 +00:34:48,010 --> 00:34:54,730 +اللي اكتشف تقريبا في الـ 1928 البنسالين الآن + +367 +00:34:54,730 --> 00:35:00,270 +المضادات الحيوية جديش بتعالج الأطفال يوميا الناس + +368 +00:35:00,270 --> 00:35:03,690 +جاعدة بتاخد مضادات حيوية والأطفال بياخدوا مضادات + +369 +00:35:03,690 --> 00:35:09,170 +حيوية وفيات الأطفال انخفضت من الاتهابات إلى ما + +370 +00:35:09,170 --> 00:35:13,590 +يقارب الصفريعني لو رجعتوا قبل خمسين، ستين، سبعين + +371 +00:35:13,590 --> 00:35:20,410 +سنة كان معدل كل أم وكل أب تقول بوضع طبيعي جدا أنا + +372 +00:35:20,410 --> 00:35:24,150 +ماتلي ولدين، أنا ماتلي تلت أولاد، أنا ماتلي أربع + +373 +00:35:24,150 --> 00:35:28,530 +.. كان الولد بيسخن بيموتاليوم بيصير السخونة مع + +374 +00:35:28,530 --> 00:35:32,310 +الأطفال و ربما بتلاحظوا عند أخوتكوا وجرايبكوا و ما + +375 +00:35:32,310 --> 00:35:37,130 +إلى ذلك على الدكتورها المضادات الحيوية و بيروحوا + +376 +00:35:37,130 --> 00:35:41,170 +الاتهاب مظبوط ولا لأ أساس هذه المضادات أول ما + +377 +00:35:41,170 --> 00:35:45,070 +اكتشفوا كانت من البنسليل و بعدين اتطورت كتير حسب + +378 +00:35:45,070 --> 00:35:47,990 +ال substitute ones اللي هان و هان و هان و هان و + +379 +00:35:47,990 --> 00:35:52,850 +حتى بعدين لما درسوا هذه المضادات الحيوية لاحظوا أن + +380 +00:35:52,850 --> 00:35:57,890 +الأساس فيهاوجود الحلقة الرباعية يعني الحلقة + +381 +00:35:57,890 --> 00:36:02,230 +الخماسية ليست أساس يعني بعض المضادات الحيوية اللي + +382 +00:36:02,230 --> 00:36:06,030 +اشتقوها ليش؟ لأنه بيشتقوا مضادات حتى يظلوا يقاوموا + +383 +00:36:06,030 --> 00:36:11,470 +البكتيريا اللي بتتأقلم على المضادات يعني كانت بدون + +384 +00:36:11,470 --> 00:36:16,630 +حلقة مشيت طبعا جيل كامل من المضادات الحيوية بدل + +385 +00:36:16,630 --> 00:36:20,510 +الحلقة الخماسية ده حضر تحضير خلوها حلقة سداسية + +386 +00:36:20,510 --> 00:36:25,160 +صارت عائلة جديدة cephalosporins وما إلى ذلكيعني + +387 +00:36:25,160 --> 00:36:30,140 +أساس البنساليل كمادة من الفقر حلقة رباعية مع + +388 +00:36:30,140 --> 00:36:34,500 +الخماسية لكن سر القوة تبع البنساليل في الحلقة + +389 +00:36:34,500 --> 00:36:38,640 +الرباعية ولا الخماسية؟ في ال beta-lactam ولذلك + +390 +00:36:38,640 --> 00:36:43,020 +العنوان بيصير أن المضادات الحيوية بيسموها beta + +391 +00:36:43,020 --> 00:36:48,940 +-lactam antibioticsيعني عنوين كتب كاملة هتدرسوها + +392 +00:36:48,940 --> 00:36:53,620 +بس اسمها beta lactam antibiotics بنسالين A بنسالين + +393 +00:36:53,620 --> 00:36:59,460 +B بنسالين G سفالوس بورين كذا بتقرأوا أسماء كثيرة + +394 +00:36:59,460 --> 00:37:04,280 +ومشتقات كثيرة الآن هي اللي بتستعمل في علاج + +395 +00:37:04,280 --> 00:37:10,300 +الالتهابات واضحة الفكرة فهذه ال cyclic amides الآن + +396 +00:37:10,300 --> 00:37:16,980 +شو سمناها؟Lactams و الـ Cyclic E stars Lactones + +397 +00:37:16,980 --> 00:37:27,980 +فما اتخربتوا ال Lactam بال Lactone طبعا + +398 +00:37:27,980 --> 00:37:35,060 +ال Amides كيف بتتكونمن تفاعل الأمونيا مع الحامض، + +399 +00:37:35,060 --> 00:37:40,900 +هذا عارفينه، واضح؟ أمونيا بتحل محل الحامض، الـ OH + +400 +00:37:40,900 --> 00:37:45,100 +طب يا تورا مع ال Easter لو فعلت الأمونيا مع ال + +401 +00:37:45,100 --> 00:37:53,000 +Easter مش مع الحامض؟بتحل محل ايش ال OR اذا الأمد + +402 +00:37:53,000 --> 00:37:56,500 +انا ممكن احضره و هذه ميزة في كل هذه العائلة لأن + +403 +00:37:56,500 --> 00:38:00,060 +كلها بتتحضر من بعضها يعني كلها بتعمل ابدالات يعني + +404 +00:38:00,060 --> 00:38:03,260 +لو جبت الحامض مع الأمونيا فارجينا أكل معادلة أمد + +405 +00:38:03,260 --> 00:38:08,620 +طب لو جبته مع ال Easter بده ييجي هنا و يطردالـ OR + +406 +00:38:08,620 --> 00:38:12,280 +الـ OR هتصير OH هيطلع Alcohol أنا بهمن الناتج + +407 +00:38:12,280 --> 00:38:17,360 +الأساسي الأمد R C double bond O and H2 إذا ال E + +408 +00:38:17,360 --> 00:38:23,880 +stars بتتفاعل مع ال ammonia بتعطيني ايش أمد هذا + +409 +00:38:23,880 --> 00:38:29,420 +التفاعل شو بنسمي احنا Ammonosis of E stars ف E + +410 +00:38:29,420 --> 00:38:33,340 +stars زائد ammonia أمد هاي E star تاني مثل + +411 +00:38:33,340 --> 00:38:36,420 +Benzoate لما فعلوا مع ال ammonia شو اللي بدأت + +412 +00:38:36,420 --> 00:38:44,010 +تتردد؟ال OR شو بتيجي محلها؟ الأمد طبعا لحتى الآن + +413 +00:38:44,010 --> 00:38:49,050 +احنا بنسمي هذا أمد باسم العائلة هذا بنسميه أمد + +414 +00:38:49,050 --> 00:38:52,830 +باسم العائلة الآن بدنا بعد شوية لما نبدأ في الأمد + +415 +00:38:52,830 --> 00:39:00,710 +نقول أي أمد هذا واضح؟ هذا الأمد شو هو؟ لاحظوا + +416 +00:39:00,710 --> 00:39:07,530 +بنيجي للحمض الأساسي المكونالفنل سي دابل بوند او او + +417 +00:39:07,530 --> 00:39:13,170 +ات شو اسمه اصلا بنزويك اسد بنشيل ال اوك اسد و بنحط + +418 +00:39:13,170 --> 00:39:19,570 +امد فطالما من ال بنزويك اسد بدنا نكتب بنز امد طب + +419 +00:39:19,570 --> 00:39:28,090 +لو من ال acidic acid بمعنى لو هذه كانت CH3 من + +420 +00:39:28,090 --> 00:39:32,030 +acidic acid شو هيطلع عندك؟ أسيت + +421 +00:39:34,650 --> 00:39:43,090 +acid أمد واضح فالأمد بنجيبه من ال acid بإبدال اوك + +422 +00:39:43,090 --> 00:39:50,670 +أسد بإيش بأمد طب لو قلنا لكوا بدنا form أمد إيه + +423 +00:39:50,670 --> 00:39:58,750 +جاكوا السؤال هيك form أمد اللي هتفكروا فيه إيش هو + +424 +00:39:58,750 --> 00:40:05,620 +ال formic acidاه هاي ال formic acid C double bond + +425 +00:40:05,620 --> 00:40:14,260 +O H OH ما هو اللي مابيعرفش يرسم ال formic acid + +426 +00:40:14,260 --> 00:40:18,060 +مليون فالمية مش هيعرف يرسم ال form amide لإن ال + +427 +00:40:18,060 --> 00:40:22,900 +form amide جاي من إيش؟ من ال formic acid الآن لما + +428 +00:40:22,900 --> 00:40:26,160 +ال acid بدى أحوله ل amide شو بدى أعمل؟ بدى يكون + +429 +00:40:26,160 --> 00:40:30,460 +معي مساحة أشيل جزء ال acid و أحط + +430 +00:40:34,180 --> 00:40:42,620 +صار form amide بال OH formic acid بال NH2 form + +431 +00:40:42,620 --> 00:40:49,080 +amide اذا بنختم ال amonolesis of E stars produces + +432 +00:40:49,080 --> 00:40:56,210 +amides بنعرف نسمي ال amideكيف بنسميه؟ بنجيب اسم + +433 +00:40:56,210 --> 00:41:01,950 +الحامض الأصلي وبنشيل oic acid بنكتب بدالها Amid + +434 +00:41:01,950 --> 00:41:08,470 +ولذلك اللي بده يعرف يسمي سواء Easter سواء Amid أو + +435 +00:41:08,470 --> 00:41:13,130 +غيره لازم يكون عارف يسمي الحامض الأصلي لأنه برضه + +436 +00:41:13,130 --> 00:41:17,450 +ال Easter من وين جبته؟من الحامض لما اقول مثل + +437 +00:41:17,450 --> 00:41:22,710 +أسيتيت اللي مش عارف أسيتك أسد مش هتعرف أسيت أمد + +438 +00:41:22,710 --> 00:41:29,090 +فورم أمد بنز أمد كله منطلق من أسيتك أسد فورمك أسد + +439 +00:41:29,090 --> 00:41:35,830 +بنزوك أسد لأن هدولة كلهم derivatives of أسد بننهي + +440 +00:41:35,830 --> 00:41:37,450 +ان شاء الله لحد هذه المنطقة + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..10ee73ccab3ffb810f29e6df781d986b3bcba1e6 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_raw.srt @@ -0,0 +1,1872 @@ +1 +00:00:24,690 --> 00:00:29,550 +الحدي عشر في جزء الكيميا الرجوية العادى قبل ما + +2 +00:00:29,550 --> 00:00:35,290 +ننتقل لمقدمة البيت الاسطي اللى هو بعنوان amines + +3 +00:00:35,290 --> 00:00:43,010 +amines يعني مركبات ال nitrogen المركبات اللى فيها + +4 +00:00:43,010 --> 00:00:49,250 +ال nitrogen طبعا كلنا عارفين ان ال amine او ال + +5 +00:00:49,250 --> 00:00:49,810 +nitrogen + +6 +00:01:07,020 --> 00:01:13,380 +الان هذول ال ثلاث روابط في أبسط المركبات على + +7 +00:01:13,380 --> 00:01:18,940 +الإطلاق تبع ال نيتروجيز لما بيكونوا إيش هيدروجيز + +8 +00:01:18,940 --> 00:01:26,200 +بيكون عنده جزء الأمونيا يعني أبسط مركب للنيتروجيز + +9 +00:01:26,200 --> 00:01:30,640 +هو جزء الأمونيا الآن الأمونيا ممكن ما نعتبرهاش + +10 +00:01:30,640 --> 00:01:31,220 +مركبة + +11 +00:01:45,690 --> 00:01:47,650 +إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا + +12 +00:01:47,650 --> 00:01:48,170 +نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال + +13 +00:01:48,170 --> 00:01:48,250 +إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا + +14 +00:01:48,250 --> 00:01:49,730 +نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال + +15 +00:01:49,730 --> 00:01:51,150 +إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا + +16 +00:01:51,150 --> 00:01:51,170 +نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال + +17 +00:01:51,170 --> 00:01:51,170 +إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا + +18 +00:01:51,170 --> 00:01:51,390 +نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال + +19 +00:01:51,390 --> 00:02:01,170 +إبدال إذا بدنا نعمل إبدال إبدال إذا + +20 +00:02:01,170 --> 00:02:03,150 +بدنا نعمل إ + +21 +00:02:16,910 --> 00:02:20,930 +هذا بنسميه primary amine يعني نيتوجن متصل فيه بكام + +22 +00:02:20,930 --> 00:02:26,630 +carbon واحدة الآن لو بدّرنا التانية صار انتزلتين R + +23 +00:02:26,630 --> 00:02:33,370 +صار secondary amine لو بدّرنا التالتة صار tertiary + +24 +00:02:33,370 --> 00:02:37,310 +amine فال amines المشهورة ال primary و ال + +25 +00:02:37,310 --> 00:02:42,370 +secondary و ال tertiary الآن هل يا ترى ممكن نعمل + +26 +00:02:42,370 --> 00:02:49,030 +كمان R رابعة؟في مرات معينة لو جيبنا R موجبة فعنا + +27 +00:02:49,030 --> 00:02:53,970 +مع هذا زوج الإلكترونات بيعمل رابط بهذا الشكل + +28 +00:02:53,970 --> 00:02:58,650 +وبيعمل الـR الرابعة لكن في هذه الحالة لو حسبنا + +29 +00:02:58,650 --> 00:03:04,910 +الـformal charge عن الـNitrogen بتصير موجبة واضح؟ + +30 +00:03:04,910 --> 00:03:11,290 +فبصير عنده صوت يعني طالما فيه موجب إذا في مرافق له + +31 +00:03:13,270 --> 00:03:18,630 +واضح طالما فيه موجب إذا فيه إله مرافق سارق تماما + +32 +00:03:18,630 --> 00:03:22,270 +زي لما كنتوا تاخدوا المركب المشهور مثلا ال + +33 +00:03:22,270 --> 00:03:26,430 +ammonium chloride كنتوا توصلوا على ال nitrogen + +34 +00:03:26,430 --> 00:03:34,990 +أربع روابط تحطوا على ال nitrogen اتش تدين تلاتة + +35 +00:03:34,990 --> 00:03:39,690 +أربعة رحزوج الإلكترونات و واحد منها دولة الارش هذا + +36 +00:03:39,690 --> 00:03:40,330 +الشكل ال + +37 +00:03:44,910 --> 00:03:52,370 +الأيون الموجة دائما بنتهيأ باسم ايش ات الايون + +38 +00:03:52,370 --> 00:03:57,030 +السالب كربونيت نيتريت سولفيت هذه الايونات السالبة + +39 +00:03:57,030 --> 00:04:02,470 +الايونات الموجة بنهيتها اونيوم امونيوم هيدرونيوم + +40 +00:04:02,470 --> 00:04:07,730 +اكزونيوم فوسفونيوم وضع ولذلك هذا ايش كان يتسمى + +41 +00:04:07,730 --> 00:04:08,470 +المركب + +42 +00:04:18,250 --> 00:04:23,590 +هذه النهاية onium نستعملها لأيون الموجة عشان ايه + +43 +00:04:23,590 --> 00:04:26,970 +لو بنيجي نسألكم the ending onium is used for + +44 +00:04:26,970 --> 00:04:31,210 +negative ions it's for the positive ions واضح + +45 +00:04:31,210 --> 00:04:36,670 +onium امونيوم اوزونيوم وهكذا الان هذا لما يكون + +46 +00:04:36,670 --> 00:04:40,350 +عليه مجموعات R بيقول فهذه الحالة + +47 +00:04:46,500 --> 00:04:50,560 +يعني عليها كام رابطة؟ أربع فبصير عندك ال + +48 +00:04:50,560 --> 00:04:54,200 +quaternary ammonium salts اللي هي R for N positive + +49 +00:04:54,200 --> 00:04:57,780 +أكيد طالما عندكوا N positive لازم يكون فيه معها + +50 +00:04:57,780 --> 00:05:04,580 +إيش؟ X سالبة واضح أكيد هيكون معها X سالبة وهذه + +51 +00:05:04,580 --> 00:05:08,560 +موجودة كثير الآن التشكيل العالمي ال nitrogen + +52 +00:05:08,560 --> 00:05:14,080 +compounds they are very importantin chemistry and + +53 +00:05:14,080 --> 00:05:19,060 +in biology يعني ال amino acids أساسي فيهم ال + +54 +00:05:19,060 --> 00:05:24,680 +nitrogen ال DNA ال RNA فيهم ال basis واضح ال + +55 +00:05:24,680 --> 00:05:29,920 +nitrogen basis اسمها ال alkaloids اللي هي المركبات + +56 +00:05:29,920 --> 00:05:32,300 +ال natural product اللي بتكون عادة + +57 +00:05:38,200 --> 00:05:44,760 +النيتروجين هو السبب ال basicity و لذلك بنسميها ال + +58 +00:05:44,760 --> 00:05:49,460 +caloids، ال caloids جاي من القالي، القالي يعني + +59 +00:05:49,460 --> 00:05:49,980 +قلوي + +60 +00:05:53,060 --> 00:05:59,080 +الان طبعا بالنسبة لخلاص ال amines كنا بنتذكر ان ال + +61 +00:05:59,080 --> 00:06:02,200 +nitrogen من أعلى السليبيات يعني ال hydrogen + +62 +00:06:02,200 --> 00:06:07,540 +bonding أساسا لما بنعرفه احنا بنربطه بتلت ذرات + +63 +00:06:07,540 --> 00:06:13,580 +أساسية إذا اتصلت ال hydrogen مع ال fluorine أو ال + +64 +00:06:13,580 --> 00:06:19,280 +oxygen أو ال nitrogen فهو أحد التلاتة اللي بيعملوا + +65 +00:06:19,280 --> 00:06:22,750 +hydrogen bondingواضح؟ ليش؟ لأن الـ + +66 +00:06:22,750 --> 00:06:26,650 +electronegativity للنيتروجين عالية حوالي تلاتة + +67 +00:06:26,650 --> 00:06:30,570 +فالـ unatched bond is very polar تعمل hydrogen + +68 +00:06:30,570 --> 00:06:33,710 +bonding is possible طالما في عندي hydrogen + +69 +00:06:33,710 --> 00:06:37,130 +bonding، إذا ال boiling points للأمين يفترض أن + +70 +00:06:37,130 --> 00:06:41,710 +تكون إيش؟ مرتفعة وزي ما قلنا طالما في عندي أزواج + +71 +00:06:41,710 --> 00:06:46,710 +إلكترونية على النيتروجين، إذا الـ nitrogen's are + +72 +00:06:46,710 --> 00:06:55,660 +basesالـ A كيف بنسمي ال Amines؟ ال Amines تسميتها + +73 +00:06:55,660 --> 00:07:01,720 +في ال IUPAC system سهلة مابنعطيهاش اسم عائلة + +74 +00:07:01,720 --> 00:07:07,680 +بنعتبرها substitute فبصير + +75 +00:07:07,680 --> 00:07:13,220 +أصل الاسم للألكين يعني زي ما الألكين على سبيل + +76 +00:07:13,220 --> 00:07:19,370 +المثال بنرسمه سلسلة من ستة، شو بنسميها؟هكسين لو + +77 +00:07:19,370 --> 00:07:23,370 +عليها على موقع اتنين كلور شو بيصير المقارنة two + +78 +00:07:23,370 --> 00:07:27,310 +chloro hexane الان لو عليها على موقع اتنين NH2 + +79 +00:07:27,310 --> 00:07:34,830 +بنسميها two amino hexane فاحنا بنسمي المركبات ال + +80 +00:07:34,830 --> 00:07:40,250 +amines كأنها ال cans و بنستعمل ايش NH2 + +81 +00:07:41,530 --> 00:07:47,430 +بنسميها إيش؟ قمائم الان يمكن هنا .. يمكن هنا البعض + +82 +00:07:47,430 --> 00:07:52,870 +يقول طب لو كانت مش هنقدش توقف، يعني هاي عندى .. + +83 +00:07:52,870 --> 00:07:58,310 +نفترض سلسلة بهذا الشكل، جدري نشوفها كام carbon؟ + +84 +00:07:58,310 --> 00:08:01,970 +واحد، اتنين، تلاتة، اربعة، خمسة، ستة، ستة، ستة + +85 +00:08:01,970 --> 00:08:07,630 +الان لو افترضنا أن عندكم على هذا الموقع برومماذا + +86 +00:08:07,630 --> 00:08:12,850 +سنذكره إبراهيم إبراهيم طيب لو افترضنا الآن إنه على + +87 +00:08:12,850 --> 00:08:22,190 +هذا الموقع إجا عنده ال H2 امينو إيش هسميه امينو + +88 +00:08:22,190 --> 00:08:26,490 +امينو و بعدين هسمي الاسم طيب لو افترضت إنه اللي + +89 +00:08:26,490 --> 00:08:32,350 +إجت عنده مش NH2 NHCH3 + +90 +00:08:39,710 --> 00:08:43,470 +هذا الشبكة بهذا الشكل من خلال الـ Nitrogen هذي إيش + +91 +00:08:43,470 --> 00:08:50,890 +اسمها؟ Amino طب لو كان الشبكة مجموعة NHCH3 ميثل + +92 +00:08:50,890 --> 00:08:59,150 +امايو طب لو الشبكة ن تنتل CH3 داي ميثل امايو، + +93 +00:08:59,150 --> 00:09:06,710 +واضح؟ إذن هذه المجموعة الـNH2 اسمها امايو الـNH + +94 +00:09:06,710 --> 00:09:07,570 +لحملة ميثل امايو + +95 +00:09:13,190 --> 00:09:20,990 +والألهج اللي حملة الدين مثل دايمثل + +96 +00:09:20,990 --> 00:09:32,110 +امايو و لذلك لو احنا بنانيجي نتطلع تكون عندنا مركب + +97 +00:09:43,560 --> 00:09:50,920 +تلاتة برومود اتنين تلاتة اربعة خمسة ستة تلاتة + +98 +00:09:50,920 --> 00:09:56,160 +برومود اتنين تلاتة اربعة خمسة ستة تلاتة برومود + +99 +00:09:56,160 --> 00:10:01,680 +اتنين تلاتة اربعة خمسة ستة اتنين تلاتة برومود + +100 +00:10:01,680 --> 00:10:02,240 +اتنين تلاتة برومود اتنين تلاتة برومود اتنين تلاتة + +101 +00:10:02,240 --> 00:10:02,460 +برومود اتنين تلاتة برومود اتنين تلاتة برومود اتنين + +102 +00:10:02,460 --> 00:10:02,460 +تلاتة برومود اتنين تلاتة برومود اتنين تلاتة برومود + +103 +00:10:02,460 --> 00:10:02,680 +اتنين تلاتة برومود اتنين تلاتة برومود اتنين تلاتة + +104 +00:10:02,680 --> 00:10:03,440 +برومود ات + +105 +00:10:09,470 --> 00:10:13,950 +واضحين to dimethylaminohexane + +106 +00:10:58,850 --> 00:11:05,550 +الان بدنا نبحث عن أطول سلسلة ألفاتية أطول سلسلة + +107 +00:11:05,550 --> 00:11:08,750 +ألفاتية من 1،2،3،4 + +108 +00:11:13,720 --> 00:11:19,620 +طبعا واحد اتنين تلاتة اربعة خمسة ستة بناء على ذلك + +109 +00:11:19,620 --> 00:11:25,680 +المركب اللي عندنا شو اسمه اكسين اكسين اكسين اكسين + +110 +00:11:25,680 --> 00:11:31,980 +اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين + +111 +00:11:31,980 --> 00:11:36,300 +اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين + +112 +00:11:36,300 --> 00:11:41,440 +اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين + +113 +00:11:41,440 --> 00:11:43,640 +اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين + +114 +00:11:43,640 --> 00:11:43,640 +اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين + +115 +00:11:43,640 --> 00:11:43,640 +اكسين اكس + +116 +00:11:47,630 --> 00:11:54,130 +الكلام في موازاة ولا لأ اثل مع ال oxygen اثل مع ال + +117 +00:11:54,130 --> 00:11:59,830 +nitrogen اثل امينو الآن لما بنشوفه من بين اليوتيوب + +118 +00:11:59,830 --> 00:12:11,510 +أولا تلاتة اثل امينو هذه مجموعة اتنين اثوكسي + +119 +00:12:11,510 --> 00:12:18,910 +علمناها اكسير واضح؟يعني مش بس الأمور بتقف عند مثل + +120 +00:12:18,910 --> 00:12:23,370 +أمينو ضاي مثل أمينو ممكن يكون عندكم إثل أمينو ضاي + +121 +00:12:23,370 --> 00:12:28,670 +إثل أمينو بروبل أمينو مثلا ضاي بروبل أمينو وممكن + +122 +00:12:28,670 --> 00:12:31,870 +كمان اللي يكونوا على الأمينو يكونوا مجمعتين + +123 +00:12:31,870 --> 00:12:36,310 +مختلفتين بأذكر التنتين بأسمعهم يعني لو أقول إثل و + +124 +00:12:36,310 --> 00:12:41,210 +مثل شو هسمي المجموعة إثل مثل أمينو + +125 +00:12:43,590 --> 00:12:47,870 +يعني اللي اتعلم organic كويس خلاص بصير تحل المشاكل + +126 +00:12:47,870 --> 00:12:52,050 +اللي بتواجهه لوحده طب لو ذكرنا ال ethoxy قبل ال + +127 +00:12:52,050 --> 00:12:58,710 +ethyl اشتغل alphabetical لما حرف الأول مايمشيش + +128 +00:12:58,710 --> 00:13:02,710 +معاك امشي على اللي بعده واضح؟ إذا لاجيت أن ال + +129 +00:13:02,710 --> 00:13:08,230 +ethoxy سابق في ال alphabetical سبجيها واضح؟ يعني + +130 +00:13:08,230 --> 00:13:11,790 +ارجعوا للي كتبنا مين سابق ethyl ولا ethoxy + +131 +00:13:18,030 --> 00:13:24,370 +اللي بيشتغل براحته يرتب الأمور Alpha Beta, إيش ما + +132 +00:13:24,370 --> 00:13:27,630 +بتكون المجموعات، بمشي حرف حرفة، واضحة فيك + +133 +00:13:34,790 --> 00:13:39,210 +طبعا لاحظوا هنا مثلا إيجا مع كثول، ضال الأساس + +134 +00:13:39,210 --> 00:13:42,650 +الكثول، يعني واحد، اتنين، تلاتة، أربعة، هذا + +135 +00:13:42,650 --> 00:13:45,650 +بيوتالول، وانت بيوتالول، على نبرة اتنين، ابروم، + +136 +00:13:45,650 --> 00:13:51,190 +مثلا على نبرة أربعة، أمين، واضح الفكرة؟ لو كان مع + +137 +00:13:51,190 --> 00:13:54,270 +الديهيد أو كيتون، نفس الأشياء، لو مع carboxylic + +138 +00:13:54,270 --> 00:14:00,110 +acid، نفس الأشياء، ومن هنا هتبدأ تلاقوا مثلا ال + +139 +00:14:00,110 --> 00:14:02,190 +amino acids + +140 +00:14:03,900 --> 00:14:08,120 +لما ندرس البروتينات، البروتينات من إيش بشكل أساسي + +141 +00:14:08,120 --> 00:14:14,100 +متكونة؟ من ال amino acids فلما نيجي نسمي، لما نيجي + +142 +00:14:14,100 --> 00:14:19,920 +نسمي، حق نعتبر أنه إحنا في عندنا ال acid زي هيك + +143 +00:14:19,920 --> 00:14:28,140 +مثلا، سي ده بيكون OH لو بيجينا هنا CH وحطينا هنا + +144 +00:14:28,140 --> 00:14:31,960 +NH2 CH2 + +145 +00:14:53,340 --> 00:14:57,800 +الان في البيو كيميستر اذا بدنا نعطي اسم glycine + +146 +00:14:57,800 --> 00:15:00,340 +بيصير اسم شهرة تاني + +147 +00:15:06,760 --> 00:15:12,160 +هذه بدأت تسمى a mind أو أسمي للكيتون أو للالدهاي + +148 +00:15:12,160 --> 00:15:13,880 +أو للالكوبول + +149 +00:15:29,090 --> 00:15:33,330 +واضح؟ هاي أمثلة إضافية، هاي أطول سلسلة تلاتة + +150 +00:15:33,330 --> 00:15:38,630 +بروبين، على نجرة واحد أماين، one a minor بروبين، + +151 +00:15:38,630 --> 00:15:45,200 +هذا بروبينto aminopropane واضح؟ الان لاحظوا معاك + +152 +00:15:45,200 --> 00:15:49,420 +طب لو كنا بيجينا ال common nomenclature ال common + +153 +00:15:49,420 --> 00:15:53,880 +nomenclature وعطيناها قاعدة عامة كلنا بنذكر اسم + +154 +00:15:53,880 --> 00:15:58,760 +المجموعة و بعدها عائلة يعني لو كان أنا كله كنا + +155 +00:15:58,760 --> 00:16:02,500 +نسميه propane، نسميه chloride لو بروم، نسميه + +156 +00:16:02,500 --> 00:16:06,080 +propane، نسميه bromide لو و أش، نسميه propane، + +157 +00:16:06,080 --> 00:16:06,560 +نسميه alcohol + +158 +00:16:09,400 --> 00:16:18,860 +هذا البروبل هو اسم المجموعة و بعدين امين هذا + +159 +00:16:18,860 --> 00:16:24,500 +البروبل هو ايزو بروبل + +160 +00:16:33,510 --> 00:16:37,930 +و هكذا واضح طبعا هذه ال common nouns هتكون في + +161 +00:16:37,930 --> 00:16:43,490 +المركبات اللي هي المجموعات اللي اتعلمناها مثل اثر + +162 +00:16:43,490 --> 00:16:47,310 +بربل ايزو بربل ايزو بيوتل تيرتشير بيوتل المجموعات + +163 +00:16:47,310 --> 00:16:50,510 +اللي اتعلمناها في أشياء مااخدنا لاش اس المجموعات + +164 +00:16:50,510 --> 00:16:54,310 +مش هتاخد ال common nomenclature هذا مثلا ستة على + +165 +00:16:54,310 --> 00:16:59,190 +بوضع اتنين امين اتنين امين او اكسين مش هتلاقي انه + +166 +00:16:59,190 --> 00:17:05,670 +اخدنا اس المجموعةواضح؟ طبعا فى ناس ممكن يقولوا عنه + +167 +00:17:05,670 --> 00:17:09,930 +two hex الأمين لإنه سهل شوية لكن بعد هيك لو هانصر + +168 +00:17:09,930 --> 00:17:15,010 +شغلة و شغلة خلاص بتسموه إيش؟ أيوبة بتسموه أيوبة + +169 +00:17:15,010 --> 00:17:19,450 +تمام واضحة فكرة ال أيوبة ال nomenclature و ال + +170 +00:17:19,450 --> 00:17:21,890 +common nomenclature ال common nomenclature أيضا + +171 +00:17:21,890 --> 00:17:28,090 +إلها trait العائلة المجموعة تسمى إيش؟ العائلة + +172 +00:17:28,090 --> 00:17:29,530 +واضح؟ + +173 +00:17:31,820 --> 00:17:36,060 +هذا المُركّب لو بجنب عليه وأطول سلسلة فيه + +174 +00:17:39,800 --> 00:17:44,360 +إذا هذا problem على مين راح واحد حامل كل هذه + +175 +00:17:44,360 --> 00:17:48,640 +المجموعة؟ مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +176 +00:17:48,640 --> 00:17:49,660 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +177 +00:17:49,660 --> 00:17:51,140 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +178 +00:17:51,140 --> 00:17:54,640 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +179 +00:17:54,640 --> 00:17:57,260 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +180 +00:17:57,260 --> 00:17:57,260 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +181 +00:17:57,260 --> 00:17:57,260 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +182 +00:17:57,260 --> 00:17:57,600 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +183 +00:17:57,600 --> 00:18:04,580 +مثل مثل مثل مثل مثل مثل مثل + +184 +00:18:05,720 --> 00:18:11,160 +هك بيصير أسهل لكم one methyl aminopropane لكن لو + +185 +00:18:11,160 --> 00:18:15,180 +شفتواها مكتوبة بطريقة تانية مثل هذه الطريقة ال مثل + +186 +00:18:15,180 --> 00:18:20,580 +معناها أن المثل متصلة بإيش بالنيتروجين و كأنه هذا + +187 +00:18:20,580 --> 00:18:23,340 +one aminopropane + +188 +00:18:33,770 --> 00:18:36,790 +Dimethyl Amino Cyclohexane + +189 +00:19:11,700 --> 00:19:20,220 +الان CH2 CH3 الان عند سلسلة اتل و سلسلة اتل بتاخد + +190 +00:19:20,220 --> 00:19:24,120 +واحدة منهم خليني افترض ان هذا الاساس اللي بنيت + +191 +00:19:24,120 --> 00:19:30,260 +الاسم عليه واحد اتنين هذا عبارة عن ايش عبارة عن + +192 +00:19:30,260 --> 00:19:37,000 +اتل لو بتاخدوا هذه السلسلة CH2 CH3 اذا تمركب ايش + +193 +00:19:37,520 --> 00:19:44,480 +Ethane هذا الـ Ethane على ممر واحد شو بيحمل؟ + +194 +00:19:44,480 --> 00:19:49,300 +بس one substitute كل هذه عبارة عن one substitute + +195 +00:19:49,300 --> 00:19:56,700 +انا اصلا المركب Ethane CH3 CH3 شيلت H وحطيت كل هذا + +196 +00:19:56,700 --> 00:20:01,320 +الكلام الآن بيصير هذه المجموعة بدي اسميها هذا + +197 +00:20:01,320 --> 00:20:09,940 +Ethane مثل Amineإثل مثل أمينو عشان تسمها إثل مثل + +198 +00:20:09,940 --> 00:20:14,880 +أمينو أو ضعف من عنده أن إثل يعني أنه اتبعوا إن + +199 +00:20:14,880 --> 00:20:20,980 +الإثل برسمة وين عن أن أن مثل و أين موجود هذا كله + +200 +00:20:20,980 --> 00:20:25,500 +على دمر واحد ولا اتنين هو واحد طبعا لو ماحطش + +201 +00:20:25,500 --> 00:20:29,320 +الواحد لما تكون إثل مافيش مشكلة لأن مافيش فيها إلا + +202 +00:20:29,320 --> 00:20:35,440 +تكون واحد لكن لو كبرت لازم واضح واضحفزي هيك بتسمو + +203 +00:20:35,440 --> 00:20:40,840 +ايش بتكتبوه يكون صحيح لو كتبتوا one أساس طريقة + +204 +00:20:40,840 --> 00:20:48,700 +أيكم ايش بتكتبوه one مثل مثل أمينو أمينو هذي + +205 +00:20:48,700 --> 00:20:54,240 +المجموعة اللي بالأحمر one و أمينو سن المجموعة مثل + +206 +00:20:54,240 --> 00:20:56,140 +أمينو و كله عبارة عن + +207 +00:21:00,110 --> 00:21:05,370 +واضح حتى لو لغينا ال one هنا ابتفها بس بالخاص انه + +208 +00:21:05,370 --> 00:21:08,490 +حد يروح يحطلنا ال ethyl و ال methyl باماكن تانية + +209 +00:21:08,490 --> 00:21:13,110 +عشان نحاول ايش نوضحهم او مرات خوف لو واحد ييجي + +210 +00:21:13,110 --> 00:21:17,370 +يصير و يحط ethyl و methyl هنا بيضيفوا كلمة ايش أن + +211 +00:21:17,370 --> 00:21:22,390 +انه يعني تأكيدا في انه ماتغلطوش يعني ان ال ethyl + +212 +00:21:22,390 --> 00:21:24,430 +على ال nitrogen ال methyl على + +213 +00:21:31,700 --> 00:21:35,460 +لو اتينا هنا بروبين على نمرة واحد امينو على نمرة + +214 +00:21:35,460 --> 00:21:42,140 +اتنين امينو، شو هيكون؟ هذا المركب واحد اتنين تلاتة + +215 +00:21:42,140 --> 00:21:47,100 +اربعة two-butanol على نمرة تلاتة امينو على نمرة + +216 +00:21:47,100 --> 00:21:51,920 +تلاتة مثل اي واحد اتنين تلاتة اربعة، ليش الترقيم + +217 +00:21:51,920 --> 00:21:58,930 +حببنا هنا؟ عشان القول تكون أفضل ما يمكن العائلةالـ + +218 +00:21:58,930 --> 00:22:02,370 +All بتكون أقل ما يمكن، هذا الـ Core، أساسه الـ + +219 +00:22:02,370 --> 00:22:06,250 +Core، واضح؟ فبدي أنا الـ OH تكون أقل ما يمكن، لو + +220 +00:22:06,250 --> 00:22:10,730 +ملقمت منها أنا الـ OH هتطلع على لبرة تلاتة، واضح؟ + +221 +00:22:10,730 --> 00:22:14,770 +فهو عبارة عن الـ Good على لبرة تلاتة حامل أمينو + +222 +00:22:14,770 --> 00:22:16,410 +وعلى لبرة تلاتة حامل + +223 +00:22:25,780 --> 00:22:29,800 +طبعا زي ما حكينا بالنسبة ل ال common nomenclature + +224 +00:22:29,800 --> 00:22:35,480 +عادة بنذكر اسم المجموعة و بعدها بنحط ايش امين و + +225 +00:22:35,480 --> 00:22:44,420 +لذلك هذه CH3 and H2 مثل امين، هذي دايمثل امين، + +226 +00:22:44,420 --> 00:22:49,680 +الامين حملة كام مثل؟ تنتهي المجموعة دايمثل امين في + +227 +00:22:49,680 --> 00:22:52,400 +ممكن يكون ال try مثل امين + +228 +00:23:00,290 --> 00:23:02,170 +كله اسمه amine باسم مُركّب + +229 +00:23:02,170 --> 00:23:28,830 +نيتروجينكتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناترام + +230 +00:23:29,650 --> 00:23:35,910 +إنه هذه ethyl و ethyl و ethyl و ethyl و ethyl و + +231 +00:23:35,910 --> 00:23:41,010 +ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و + +232 +00:23:41,010 --> 00:23:43,710 +ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و + +233 +00:23:43,710 --> 00:23:44,510 +ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و + +234 +00:23:44,510 --> 00:23:45,090 +ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و + +235 +00:23:45,090 --> 00:23:45,670 +ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و + +236 +00:23:45,670 --> 00:23:45,670 +ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و + +237 +00:23:45,670 --> 00:23:45,670 +ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و + +238 +00:23:45,670 --> 00:23:51,290 +ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و + +239 +00:23:51,290 --> 00:23:54,950 +ethyl و ethyl و + +240 +00:23:59,000 --> 00:24:03,700 +بتذكرهم alphabetical اثل مثل امين الافضل + +241 +00:24:03,700 --> 00:24:11,320 +alphabetical يعني اثل مثل اثل مثل امين الخلاصة انه + +242 +00:24:11,320 --> 00:24:15,740 +التسمية بال common nomenclature التسمية بال common + +243 +00:24:15,740 --> 00:24:19,860 +nomenclature بنذكر فيها اسم المجموعة و بعدين بننهي + +244 +00:24:19,860 --> 00:24:26,770 +بالنهاية امين اللي هي العائلة واضح؟فزي ما بتلاحظوا + +245 +00:24:26,770 --> 00:24:30,890 +الأمينز أكتر من تسمية لهم أشهر نظام الـ Iopaque + +246 +00:24:30,890 --> 00:24:34,350 +أنه نعتبرهم ألكين وهي أمثلة إضافية حتى أنه + +247 +00:24:34,350 --> 00:24:39,310 +اترجعوها ال Iopaque بنذكرهم ألكينزي ال common + +248 +00:24:39,310 --> 00:24:46,450 +بنذكر المجموعة ثم العائلة الأهم في نظام تسمية تالت + +249 +00:24:46,450 --> 00:24:47,850 +حسب ال chemical abstract + +250 +00:25:06,820 --> 00:25:13,020 +بس لما بيسميه بيسميش طبعا مركب رباع بيوت الأمين لأ + +251 +00:25:13,020 --> 00:25:21,000 +بيسميه بيوتان أمينبعرفش إذا دي واضحة ولا بنزم أني + +252 +00:25:21,000 --> 00:25:27,160 +أوضحها أكتر لكم يعني خليني + +253 +00:25:27,160 --> 00:25:35,080 +أخد هذا المركب و أحط هنا OH عشان أنتوا تنتبهوا لما + +254 +00:25:35,080 --> 00:25:41,600 +أنا كنت أسمي هذا بيوتان + +255 +00:25:48,620 --> 00:25:56,180 +و أحطله one هذا ال IOPAC منه الان لما كنت أسميه + +256 +00:25:56,180 --> 00:26:04,600 +بال common nominative شو كنت أسميه؟ butyl و أحط + +257 +00:26:04,600 --> 00:26:12,820 +العائلة alcohol butyl alcohol okay butyl alcohol + +258 +00:26:12,820 --> 00:26:17,360 +الان الناس اللي بيعملوا على نظام تسمية تالف + +259 +00:26:21,690 --> 00:26:28,830 +عندي nh2، بدي أعطي العائلة أمين، يعني نغير هذه + +260 +00:26:28,830 --> 00:26:36,910 +نخليها nh2، فبصير بيوتان أمين، طب وهذا بيوت + +261 +00:26:36,910 --> 00:26:43,790 +الأمين، واضح تلاحظين أنه الفرق ما بينبيوتان و + +262 +00:26:43,790 --> 00:26:47,870 +بيوتين في كل الأحوال هذا النظام مابتيش يقتصر معالي + +263 +00:26:47,870 --> 00:26:51,730 +لكن مرات بنذكر أشياء اللي لو قرأتوها ماتحسوش + +264 +00:26:51,730 --> 00:26:54,790 +باستغراب احنا اللي بدنا نسمي عليه the iopac + +265 +00:26:54,790 --> 00:27:00,230 +nomenclature ان مراكبات ال amines بتتبع الalkenes + +266 +00:27:00,230 --> 00:27:04,490 +هي مشتقات للalkenes و لو كنا بتناقلكم ال common + +267 +00:27:04,490 --> 00:27:07,730 +nomenclatures تبعها فبنكتم المجموعة و بعدين ال + +268 +00:27:07,730 --> 00:27:14,400 +amine لكن لو قرأتوا اشي تانيما تستمر مش واضح؟ + +269 +00:27:14,400 --> 00:27:19,940 +باختصار المركبات تبعت ال amines تتبع عائلة ال + +270 +00:27:19,940 --> 00:27:23,720 +alkanes يعني نهيتها إيفين بروبين بيوتين هكسل + +271 +00:27:23,720 --> 00:27:29,140 +whatever طبعا مركبات ال amines في الدنيا كتيرة + +272 +00:27:29,140 --> 00:27:33,700 +كلها مركبات في الكيميا الحلقية مش بطلب نحفظها بس + +273 +00:27:33,700 --> 00:27:38,100 +حتى تحسوا كدهش موضوع ال nitrogen موضوع واسع يعني + +274 +00:27:38,100 --> 00:27:43,010 +يمكن تقوله ربع الكيميا العضوية المركبات معاهواضح؟ + +275 +00:27:43,010 --> 00:27:47,110 +البُركّب هذا الوحيد يمكن يعرفي أنه البنزينة اللي + +276 +00:27:47,110 --> 00:27:54,630 +عليها الأن H2O هي عبارة عن أنيليا الأن بالنسبة للـ + +277 +00:27:54,630 --> 00:27:59,010 +physical properties of amines بشكل عام احنا بيقول + +278 +00:27:59,010 --> 00:28:03,680 +أن ال physical properties ofhydrogen bonding + +279 +00:28:03,680 --> 00:28:10,440 +وبالتالي من ناحية من ناحية من ناحية مقارنة ال + +280 +00:28:10,440 --> 00:28:14,340 +boiling point تبعتهم يفترض انها ليش تكون عالية + +281 +00:28:14,340 --> 00:28:18,820 +مرتفعة طبعا اللي بده يعمل المقارنة ويفهمها جيدا + +282 +00:28:18,820 --> 00:28:24,120 +بده يقارن مع إشي مافيش فيه hydrogen bonding يعني + +283 +00:28:24,120 --> 00:28:26,640 +إشي فيه hydrogen bonding وإشي مافيه hydrogen + +284 +00:28:26,640 --> 00:28:29,200 +bonding وبده يوحد العوامل التانية + +285 +00:28:38,870 --> 00:28:42,670 +طب هذا ليش مرتفع كتير اكتر من هذا؟ بطل ال + +286 +00:28:42,670 --> 00:28:46,450 +molecular weight هو السبب و قداش بديكون السبب ال + +287 +00:28:46,450 --> 00:28:52,910 +hydrogen بدي ولذلك هلأ اعمللكم مثال كتير جميل أخد + +288 +00:28:52,910 --> 00:28:58,830 +من ال alkanes ال ethane و لاحظوا عندى ال ethane ال + +289 +00:28:58,830 --> 00:29:03,540 +molecular weight تبعه قداش تلاتينكامهم كامهم 12, + +290 +00:29:03,640 --> 00:29:09,400 +12, 24, 26 هيدروجين تلاتين و أخد الميث الأمين + +291 +00:29:09,400 --> 00:29:15,520 +الميث الأمين لو حسبنا ال molecular weight 31 هذا + +292 +00:29:15,520 --> 00:29:21,160 +أمين هذا الكلب و أخد الميثانول ال alcohol ال + +293 +00:29:21,160 --> 00:29:28,740 +molecular weight تبعه 32تجاوزا او تقريبا التلاتين + +294 +00:29:28,740 --> 00:29:31,640 +في ال molecular weight زي الواحد و التلاتين زي + +295 +00:29:31,640 --> 00:29:36,260 +الاتنين و التلاتين إذا هدولة التلات مراكبات equal + +296 +00:29:36,260 --> 00:29:39,040 +بالنسبالي .. اللي هم equal molecular weight فلو + +297 +00:29:39,040 --> 00:29:43,380 +اختلفوا بال boiling point هيكون اختلاف بسبب ال + +298 +00:29:43,380 --> 00:29:47,920 +molecular weight لأ لأ بنفتش على إشي تاني الآن لو + +299 +00:29:47,920 --> 00:29:53,480 +إجهنا اتطلعنا على قداش ال boiling point اللي هو + +300 +00:29:55,080 --> 00:30:04,760 +هنلاحظ ان الاثان ناقص 88 المثل أمين ناقص 6 جديش + +301 +00:30:04,760 --> 00:30:12,340 +زاد المثل أمين عن الاثان من ناقص 88 لناقص 6 82 + +302 +00:30:12,340 --> 00:30:20,660 +درجة82 درجة هذا زيادة من وين نجوله الـ 82 درجة من + +303 +00:30:20,660 --> 00:30:26,940 +الهيدروجين البونديني الان الميثانول 65 جداش زاد + +304 +00:30:26,940 --> 00:30:34,560 +الميثانول عن الميثين احسبوا 88 و 65 حوالي 140 درجة + +305 +00:30:34,560 --> 00:30:39,320 +من وين نجول 140 درجة من الهيدروجين البونديني طبعا + +306 +00:30:39,320 --> 00:30:43,160 +ممكن واحدة تيجي تتساءل ما هو مش كل هيدروجين + +307 +00:30:43,160 --> 00:30:49,270 +بوندينيزي بعضه، يعني مع ال مثل أمين زادت ال + +308 +00:30:49,270 --> 00:30:53,230 +boiling point، لكن كده زادت؟ تمانين درجة، مع + +309 +00:30:53,230 --> 00:30:56,970 +الميثانول زادت ال boiling point، كده زادت؟ مية و + +310 +00:30:56,970 --> 00:31:00,690 +أربعين درجة، اه ما احنا بنعرف أن ال oxygen + +311 +00:31:00,690 --> 00:31:07,780 +السليلية تبعته أعلى من ال nitrogenواضح؟ ولذلك الـ + +312 +00:31:07,780 --> 00:31:11,140 +hydrogen bonding اللي موجود في حالات ال oxygen + +313 +00:31:11,140 --> 00:31:14,980 +أكتر من اللي في ال nitrogen فارتفاع رخطة الغليان + +314 +00:31:14,980 --> 00:31:18,900 +لمركب في oxygen بيكون أكتر من اللي مركب في + +315 +00:31:18,900 --> 00:31:23,320 +nitrogen في كل الأحوال .. في كل الأحوال المركبين + +316 +00:31:23,320 --> 00:31:25,780 +أشمالهم مرتفعين + +317 +00:31:27,590 --> 00:31:33,390 +عشان اقولك انه في عندك ناقص 88 للإيثين وقاعدة + +318 +00:31:33,390 --> 00:31:38,970 +بتزيد الحرارة لما صارت مثل الامين ناقص 6 ولا .. + +319 +00:31:38,970 --> 00:31:47,650 +ناقص 6 ارتفاع 80 درجة لما قولت ميثانون زائد 65 هذا + +320 +00:31:47,650 --> 00:31:51,510 +ارتفاع و هذا ارتفاع لكن الارتفاع الناشئ عن + +321 +00:31:51,510 --> 00:31:52,470 +الأكسجين + +322 +00:31:55,140 --> 00:31:59,080 +النيتروجين انا مابتش انسى ان الـ electronegativity + +323 +00:31:59,080 --> 00:32:01,840 +للأكسجين تلاتة و نص ال electronegativity + +324 +00:32:01,840 --> 00:32:07,480 +للنيتروجين تلاتة فلأنه السليبية لأن الأكسجين أعلى + +325 +00:32:07,480 --> 00:32:09,520 +فال hydrogen bonding اللي فيه + +326 +00:32:13,840 --> 00:32:17,520 +الارتفاع ارتفاع وهيدروجين bonding هيدروجين bonding + +327 +00:32:17,520 --> 00:32:22,320 +واضح لكن لو جيت بتهاجأت أسألكوا تحديدًا ليش + +328 +00:32:22,320 --> 00:32:26,460 +الميثانول أعلى من الميث الأمين؟ هنال أكسجين؟ اه + +329 +00:32:26,460 --> 00:32:30,000 +مالكشنش يقولولي هيدروجين bonding أنا فيه هيدروجين + +330 +00:32:30,000 --> 00:32:33,920 +bonding وانا فيه هيدروجين bonding لأن السالبية + +331 +00:32:33,920 --> 00:32:38,000 +للأكسجين أعلى فالهيدروجين bonding تبعه أقل + +332 +00:32:47,850 --> 00:32:55,250 +المقارنة نفسها تماما بس تختلف القيامة، واضح؟ فال + +333 +00:32:55,250 --> 00:33:00,110 +alcohol بتكون أعلى من ال amines أعلى كتير كتير من + +334 +00:33:00,110 --> 00:33:09,370 +ال alkyls، والسبب الhydrogen bonyالان كيف بنحضر ال + +335 +00:33:09,370 --> 00:33:14,330 +amines؟ نسبة من هذه الطرق اللي هي طرق تحضير ال + +336 +00:33:14,330 --> 00:33:19,830 +amines مرت معنا على سبيل المثال المرة الماضية لما + +337 +00:33:19,830 --> 00:33:25,130 +درسنا ال amides أخدنا أن ال production of amides + +338 +00:33:25,130 --> 00:33:29,490 +produces amine، produces amine، ان هذا ال c double + +339 +00:33:29,490 --> 00:33:36,270 +point هو تشفت CHOإذا إحدى طرق تحضير الأمين + +340 +00:33:36,270 --> 00:33:41,230 +reduction of amides واضح؟ reduction of amides + +341 +00:33:41,230 --> 00:33:47,290 +produces amines طبعا الناس الشطرين ما بدهم يشيفوا + +342 +00:33:47,290 --> 00:33:52,010 +عند هذه النقطة بيقدروا يرجعوا لورا كام خطوة جد ما + +343 +00:33:52,010 --> 00:33:59,390 +بدهم بمعنى الأمد من وين جاي؟ من الاسد والاسد إيه + +344 +00:33:59,390 --> 00:34:00,650 +طرق تحضيره؟ + +345 +00:34:02,750 --> 00:34:07,250 +كان في عنده طرق تساوي و طرق زيادة و .. كل هذا + +346 +00:34:07,250 --> 00:34:12,890 +الكلام بدي أنتبهله يعني لو أنا طلبت بيكم amines من + +347 +00:34:12,890 --> 00:34:20,710 +ال amide فهذا هو السؤال السهل، الآن ممكن أرجعه بال + +348 +00:34:20,710 --> 00:34:28,330 +amine من ال acid؟ طب ال acid من إيش؟ مثلا من + +349 +00:34:28,330 --> 00:34:35,080 +الكحول، طريقة التساويأو الـ Dehydrate بطريقة + +350 +00:34:35,080 --> 00:34:40,600 +التساوي أو RX و بزيد عليها CO2 ولا بزيد عليها + +351 +00:34:40,600 --> 00:34:48,320 +Greenium CN أو من الكيل والكيل بحط عليه بعد هيك + +352 +00:34:48,320 --> 00:34:52,660 +Alcohol أو بحط عليه بيئة بمعنى كل الكيميا اللي قبل + +353 +00:34:52,660 --> 00:34:57,450 +اللي أعطينا عليها أمثلة كيف تحضروا ال acidبتصير + +354 +00:34:57,450 --> 00:35:02,530 +بعد هيك تلقاء الأسد بيصير أمد و الأمد بيصير أمين + +355 +00:35:02,530 --> 00:35:07,670 +فمش ضروري أنه هنا بتصير اللي هو الناس الشطريين + +356 +00:35:07,670 --> 00:35:11,270 +اللي بدوا يقعدوا بينهم بين نفسهم يفكروا لمدة نص + +357 +00:35:11,270 --> 00:35:15,350 +ساعة ساعة يتخيلوا كيف ممكن ينسقلوا في هذه المنطقة + +358 +00:35:15,350 --> 00:35:21,270 +مش بس يقولوا أنه والله الأمين من الأمد، كويس، و + +359 +00:35:21,270 --> 00:35:27,880 +الأمد من الأسد، و الأسدراجعوا الخمس طرق تبعونه + +360 +00:35:27,880 --> 00:35:32,840 +الان كل نقطة بداية بيحطل الإنسان يقولكم كيف منها + +361 +00:35:32,840 --> 00:35:39,440 +بتحضروا amines إذا الطالب ماعملش هالكلام لوحده + +362 +00:35:39,440 --> 00:35:45,660 +باستمتاع واجع ما نبدأ به لل acid و بعدين ال acid و + +363 +00:35:45,660 --> 00:35:49,940 +بعدين ال amide و بعدين ال amine مش هيتعلم واضحة + +364 +00:35:49,940 --> 00:35:55,760 +الفكرة؟ الان بيجينا ال aromatic amineاللي هو + +365 +00:35:55,760 --> 00:36:00,440 +الأليلين الآن لاحظوا من الأخطاء الشائعة دايما لما + +366 +00:36:00,440 --> 00:36:05,240 +نقول حضرونا الأليلين أنه أي حد فيكم بالذات إذا كنا + +367 +00:36:05,240 --> 00:36:10,640 +الأليلين من البنزين how can you prepare أليلين + +368 +00:36:10,640 --> 00:36:18,080 +starting from بنزين أكبر غلطة ممكن تعملوا عندكوا + +369 +00:36:18,080 --> 00:36:21,020 +تقولوا زي هيك و تيشوا تكتبوا لأنهاتين three + +370 +00:36:24,650 --> 00:36:30,170 +طبعا ليش هذه أكبر غلطة في الدنيا لأنه احنا اتفقنا + +371 +00:36:30,170 --> 00:36:36,770 +ان البنزين عبارة عن سحابة إلكترونية سالب السالب لا + +372 +00:36:36,770 --> 00:36:43,130 +يستطيع ان يهاجم عليه سالب ولذلك لا يمكن ان نيجي + +373 +00:36:43,130 --> 00:36:47,430 +نقول بدنا نجيب الأمونيا السالبة على البنزين السالب + +374 +00:36:47,430 --> 00:36:48,610 +ونحضر هذا الكلام + +375 +00:36:52,670 --> 00:36:56,730 +بنقول حضرولنا الانيلين من البنزين ماحدش يقول بنزين + +376 +00:36:56,730 --> 00:37:01,630 +زايد أمونيا أنيلين إيش من يجلبوا الأمونيا هنا إما + +377 +00:37:01,630 --> 00:37:05,450 +إذا كنتوا أقطام المغناطيس اللي زي بعض الشمالي + +378 +00:37:05,450 --> 00:37:09,650 +والشمالي بتاعون ألعاب الأطفال جربوهم مع بعض كيف + +379 +00:37:09,650 --> 00:37:15,530 +بيكونوا جاعدين نفس الشي هذا سهل وسهلعمرهم هيقدروا + +380 +00:37:15,530 --> 00:37:19,850 +يجربوا على بعض؟ لأ، إذا هذه الطريقة غير سليمة + +381 +00:37:19,850 --> 00:37:24,950 +إطلاقا لإنه محضر من خلالها الأدلين طب ها إيش + +382 +00:37:24,950 --> 00:37:29,310 +الطريقة السليمة؟ الطريقة السليمة إنه إحنا محضر + +383 +00:37:29,310 --> 00:37:34,230 +الـNitro Benzene هذا من الـHNO3 و الـH2SO4 + +384 +00:37:34,230 --> 00:37:40,210 +اتعلمناه بعدين الـNitro Benzene الـNitro Benzene + +385 +00:37:40,210 --> 00:37:46,490 +بال reductionبنضيف عليها هيدروجين reduction + +386 +00:37:46,490 --> 00:37:52,470 +بالهيدروجين هيدروجينونيكل مثلا بتحول إلى إيش؟ + +387 +00:37:52,470 --> 00:37:59,090 +الانيلين إذا الانيلين من البنزين يمر تأكيدا عبر + +388 +00:37:59,090 --> 00:38:04,390 +النيترو بنزين لما نقول بدنا انيلين من البنزين + +389 +00:38:04,390 --> 00:38:12,070 +بتكون قولولي المسار بنزين نيترو بنزين انيلين + +390 +00:38:14,070 --> 00:38:20,930 +وقع الفكرة هذا هو المسار بنزين نايترو بنزين قليل + +391 +00:38:20,930 --> 00:38:29,950 +الآن لبس ان انا اضيفلكم هنا كمان معلومة كتير مهمة + +392 +00:38:29,950 --> 00:38:32,990 +مر + +393 +00:38:32,990 --> 00:38:40,250 +علينا طبعا هنا قلنا HRO3H2O4 مر علينا الفيلول + +394 +00:38:41,480 --> 00:38:46,700 +بتعرفوا ال phenol؟ اه لو اتينا و قولنالكم how can + +395 +00:38:46,700 --> 00:38:52,560 +you prepare phenol يعني + +396 +00:38:52,560 --> 00:39:00,160 +هنا OH starting from بنزين كيف + +397 +00:39:00,160 --> 00:39:05,780 +تحضر ال phenol من البنزين؟ الآن أكبر غلط ممكن + +398 +00:39:05,780 --> 00:39:08,820 +الواحد يعمله إيش؟ يقول بنزين + +399 +00:39:17,390 --> 00:39:24,350 +- أزواج إلكترونال ليش؟ لأن هذا السالب لا يهاجم على + +400 +00:39:24,350 --> 00:39:30,770 +هذا السالب إذن مش ممكن أقول البنزين .. مش ممكن + +401 +00:39:30,770 --> 00:39:34,290 +أقول البنزين فعله مع الـ OH بيعطينا فينول أول ما + +402 +00:39:34,290 --> 00:39:40,830 +جالبهم OH على بنزين بتنافر واضح؟ إذن لابد من طريقة + +403 +00:39:40,830 --> 00:39:46,880 +تانيةلتحضير الفينول هذه الطريقة التالية لتحضير + +404 +00:39:46,880 --> 00:39:51,680 +الفينول بتمشي عبر هذا المسار تمام عبر هذا المسار + +405 +00:39:51,680 --> 00:39:58,820 +بيقول بنزين نيترو بنزين أنيلين و بعدين بدي كمان + +406 +00:39:58,820 --> 00:40:05,440 +reactions هنا بحط نمرة واحد NKF2 صوديوم نيترايت + +407 +00:40:05,440 --> 00:40:09,980 +تمام و نمرة اتنين بحط H2O + +408 +00:40:13,640 --> 00:40:22,220 +أش فبصير الفيلول من البنزين سلسله أطول كمان بنزين + +409 +00:40:22,220 --> 00:40:30,200 +نيترو بنزين أنيلين فيلول واضح؟ فأي تحضير الأنيلين + +410 +00:40:30,200 --> 00:40:34,640 +من البنزين عبر نيترو بنزين؟ وتحضير الفيلول من + +411 +00:40:34,640 --> 00:40:39,700 +البنزين عبر نيترو بنزين أنيلين فيلول هانا ال + +412 +00:40:39,700 --> 00:40:41,640 +reduction دايما باستعمال أش + +413 +00:40:44,660 --> 00:40:51,720 +مع metal زي ال nickel او ما شبه و هذا كثير مرات + +414 +00:40:51,720 --> 00:40:56,020 +بتجيبوا .. بتجيبوا يا سؤال صح و غلط اكمل معادلة + +415 +00:40:56,020 --> 00:40:59,440 +فيلون can be prepared from the reaction مثلا of + +416 +00:40:59,440 --> 00:41:04,260 +بنزين والسوديوم هيدروكسايد هو السوديوم هيدروكسايد + +417 +00:41:04,260 --> 00:41:13,990 +COH- خطأ خطأ خطأ إلو إيش سلسلة متتاليةزي سلاسل + +418 +00:41:13,990 --> 00:41:19,530 +الرواد في علم الحديث، عارفينها؟ سلسلة ذهبية وسلسلة + +419 +00:41:19,530 --> 00:41:26,410 +كذا، وراوة النعمان وعنمان السماء، كيف يروي مالك عن + +420 +00:41:26,410 --> 00:41:32,590 +أنسى طيب، + +421 +00:41:32,590 --> 00:41:37,820 +كام طريقة هيك منكون أخدنا لتحضير الأمينس؟Tintin من + +422 +00:41:37,820 --> 00:41:41,980 +الـ Amides وتحضير الـ aromatic amines من الـ + +423 +00:41:41,980 --> 00:41:47,620 +Nitrobenzene الآن في عندى طريقة تالتة reduction of + +424 +00:41:47,620 --> 00:41:53,120 +cyanide يعني الـCN هذه هي عبارة عن إيش لو إحنا + +425 +00:41:53,120 --> 00:42:02,680 +طلعنا عليها C driven on Nلو طفنا عليها هيدروجين + +426 +00:42:02,680 --> 00:42:08,860 +هيكتبلكوا 4H طبعا 4H هذي بتيجينا غالبا من Lithium + +427 +00:42:08,860 --> 00:42:12,600 +Aluminum Hydride الهيدروجين مش هذا مصدق ده + +428 +00:42:12,600 --> 00:42:19,040 +هيدروجين، هتنقضوا بالبند وتحطوا H وH و تنقضوا كمان + +429 +00:42:19,040 --> 00:42:21,800 +بند وتحطوا H وH + +430 +00:42:23,770 --> 00:42:29,050 +صارت عبارة عن أميل، إذا ال reduction of nitro + +431 +00:42:29,050 --> 00:42:32,410 +compounds في الغضب لل triple bonds البايبل دي + +432 +00:42:32,410 --> 00:42:38,310 +الأولى والبايبل دي التانية بنتهي CH2NH2 هل كانت CE + +433 +00:42:38,310 --> 00:42:42,830 +N؟ ضيفنا H وH وH وH وH وH وH وH وH وH وH وH وH وH + +434 +00:42:42,830 --> 00:42:45,870 +وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH + +435 +00:42:45,870 --> 00:42:46,050 +وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH + +436 +00:42:46,050 --> 00:42:46,310 +وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH + +437 +00:42:46,310 --> 00:42:50,930 +وH وH وH وH وH وH وH وH وH وH وH وH وH وH وبترجع + +438 +00:42:50,930 --> 00:43:00,150 +خطوة لبرا هذه مثلا كانت CH3CL مع CL minus بالإبدال + +439 +00:43:00,150 --> 00:43:10,390 +بتحل ال CL محل ال CL بتحل ال CL محل ال CL إذا من + +440 +00:43:10,390 --> 00:43:16,250 +ال highlights كنا نبدل ال CL و ال PR بCL بعد هيك + +441 +00:43:16,250 --> 00:43:19,430 +ال CL بنضيف عليها هيدروجين نعملها reduction + +442 +00:43:28,380 --> 00:43:34,500 +أخر طريقة أخدناها عشان يكب نذكرها بدقيقة لما أخدنا + +443 +00:43:34,500 --> 00:43:38,820 +chapter ال Rx لو قلنا لكم أكمل المعادلة لغاية كل + +444 +00:43:38,820 --> 00:43:42,660 +هدول اللي قدامكم بس عشان تتأكدوا أن احنا أخدناها + +445 +00:43:42,660 --> 00:43:52,500 +قلنا لكم CH3 CH2PR هذا عبارة عن إيش الكلهلان زائد + +446 +00:43:52,500 --> 00:43:59,100 +NH3 ال Euclidean 5كيف كنتوا تكملوا هذه المعادلة؟ + +447 +00:43:59,100 --> 00:44:04,820 +امير او اموريا مع هالك اللي lied الـ eucleophilic + +448 +00:44:04,820 --> 00:44:13,260 +substitution اللي بدأ بوضوع شبطة ستة CH3 CH2 و هذا + +449 +00:44:13,260 --> 00:44:16,560 +ال neutral ال eucleophil دائما بيفقد H + +450 +00:44:21,410 --> 00:44:26,030 +أي مشتقة أمونيا المهم يكون فيها على أقل تقدير أتش + +451 +00:44:26,030 --> 00:44:29,450 +يعني المهم + +452 +00:44:29,450 --> 00:44:34,330 +يكون عندكم إيش أتش عشان الأتش تفقد أمين زي الأكل + +453 +00:44:34,330 --> 00:44:40,790 +هلاي بعمل إبداع وهذا حلنا عليه مسائل كتير في الفصل + +454 +00:44:40,790 --> 00:44:47,330 +السادسهذه أيضًا طريقة و عليها مثالين توضحيين + +455 +00:44:47,330 --> 00:44:52,970 +عندكم، اللي هي طريقة إبدال على ال الكلهيلات، طريقة + +456 +00:44:52,970 --> 00:44:57,510 +الإبدال على ال الكلهيلات، يعني لاحظوا هذا ال + +457 +00:44:57,510 --> 00:45:03,850 +الكلهيلات وينه؟ المثل أيضاري، بجيب بداله الأمين، + +458 +00:45:03,850 --> 00:45:05,850 +هذه الأمين، اتجه الآن + +459 +00:45:09,910 --> 00:45:15,350 +لأ هو بهذا المثال هاي ال kilohydride هاي ال PR إيش + +460 +00:45:15,350 --> 00:45:18,790 +في عنده هنا ال unatomobiles ال unatomobiles خلّى + +461 +00:45:18,790 --> 00:45:25,250 +الآن نتاجر تجربة ال PR و إذا بتعمل إيش حلقات صار + +462 +00:45:25,250 --> 00:45:30,470 +عندى مركب النكوتين هذا المركب النكوتين كيف نحطه + +463 +00:45:30,470 --> 00:45:35,190 +نكوتين السجاني في كل الأحوال ال unat + +464 +00:45:39,910 --> 00:45:43,910 +الـ PR أو الـ CL ابتفعوا الإدالة، فطرق تحضير + +465 +00:45:43,910 --> 00:45:49,370 +الأمين استلخيصا من الـ Amides، من الـ CL، من + +466 +00:45:49,370 --> 00:45:52,690 +الإدالة محل الـ Halogens، والـ Aromatic أمين + +467 +00:45:52,690 --> 00:45:58,190 +باختزال الـ Nitrobenzene، واضحة الفكرة؟ إن شاء + +468 +00:45:58,190 --> 00:45:58,290 +الله + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..b344b12558113f1c099150885e0f357cd351567a --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_postprocess.srt @@ -0,0 +1,1912 @@ +1 +00:00:19,740 --> 00:00:25,800 +بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في ال + +2 +00:00:25,800 --> 00:00:30,360 +dry glycerides و ال fats and oils يمكن لاحقته + +3 +00:00:30,360 --> 00:00:36,240 +انتوا شغلة ان فيهم شيء مشترك الشيء المشترك اللي + +4 +00:00:36,240 --> 00:00:43,090 +فيهم هو ال glycerol واضح؟الان فيهم بعد هيك أشياء + +5 +00:00:43,090 --> 00:00:49,130 +مختلفة، الأشياء المختلفة هي ال fatty acids، يعني + +6 +00:00:49,130 --> 00:00:53,450 +احنا اتفقنا ان الـ triglycerides، ال glycerol متصل + +7 +00:00:53,450 --> 00:00:58,920 +فيه تلاتة fatty acids عاملين E starsهدولة التلات + +8 +00:00:58,920 --> 00:01:03,240 +شغلات بيختلفوا يعني ال glycerol واحد مش فيه خلافة + +9 +00:01:03,240 --> 00:01:08,440 +لكن هل يتر هدولة تلات فات أسيتس من نفس النوع بداية + +10 +00:01:08,440 --> 00:01:13,460 +بيكون simply triglycerides او مختلفين بيكون mixed + +11 +00:01:13,460 --> 00:01:14,540 +triglycerides + +12 +00:01:17,790 --> 00:01:22,530 +ايش الاحتمالات انهم يكونوا موجودين saturated كلهم + +13 +00:01:22,530 --> 00:01:27,870 +ولا unsaturated ولا بنسب مختلفة الان هذا الاختلاف + +14 +00:01:27,870 --> 00:01:33,390 +في التلاتة fatty acids اللي موجودين هو اللي بسبب + +15 +00:01:33,390 --> 00:01:38,210 +اختلاف بين انه المركب نفسه او المادة نفسها تكون + +16 +00:01:38,210 --> 00:01:44,110 +fat يعني بحالة صلبة او تكون oil وحتى لما تكون oil + +17 +00:01:44,110 --> 00:01:50,030 +ما بين زيت وزيتأو ما بين fat و fat أيضا في ايش + +18 +00:01:50,030 --> 00:01:54,930 +عندنا؟ في اختلاف هذا الاختلاف مرده لإيش؟ مرده + +19 +00:01:54,930 --> 00:01:59,790 +لاختلاف أنواع و نسب ال fatty acids اللي موجودين + +20 +00:01:59,790 --> 00:02:05,790 +يعني مثلا بشكل عام بنقدر نقول ان الزيوت تحتوي على + +21 +00:02:05,790 --> 00:02:10,270 +نسبة أكثر من ال saturated ولا ال unsaturated fatty + +22 +00:02:10,270 --> 00:02:14,130 +acidsالـ Unsaturated و هم اللي بيخلوها Liquid و + +23 +00:02:14,130 --> 00:02:18,310 +عشان هيك لو بدنا نتطلع مثلا على ال olive oil على + +24 +00:02:18,310 --> 00:02:23,930 +زيت الزتون هلاحظ انه في من ال unsaturated acids 83 + +25 +00:02:23,930 --> 00:02:29,710 +من ال oleic acid اللي في double bond واحدة 83% و 7 + +26 +00:02:29,710 --> 00:02:33,950 +% من ال linoleic acid اللي فيه تنتين double bonds + +27 +00:02:33,950 --> 00:02:40,390 +بمعنى مجموع ال unsaturated في زيت الزتون كدهش 90% + +28 +00:02:41,360 --> 00:02:46,620 +إذا معظم الزيت المجموع اللي فيه جديش 90% لو طلعنا + +29 +00:02:46,620 --> 00:02:53,220 +على زيت النخل بنلاحظ النسبة 51% على زيت الدرة 80% + +30 +00:02:53,220 --> 00:03:02,280 +هنا زيت ال peanut اللي هي الصوية 85% يعني الزيوتي + +31 +00:03:02,280 --> 00:03:05,960 +بشكل عام بنقدر نقوله هذه الجملة اللي بنضال + +32 +00:03:05,960 --> 00:03:10,150 +متذاكرينها بيكون فيها higherpercentage of + +33 +00:03:10,150 --> 00:03:14,430 +saturated ولا unsaturated .. unsaturated fatty + +34 +00:03:14,430 --> 00:03:20,090 +acids الآن بالنسبة للأشياء التانية اللي بتصير fat + +35 +00:03:20,090 --> 00:03:24,110 +يعني نوعا ما صلب يعني على سبيل المثال الزبدة لو + +36 +00:03:24,110 --> 00:03:27,010 +بنتطلع على الزبدة قداش فيها unsaturated fatty + +37 +00:03:27,010 --> 00:03:31,110 +acids من اللي وليك و اللي نوليك ستة و عشرين و + +38 +00:03:31,110 --> 00:03:39,300 +اتنين28 بينما معظمها مخلوط فيها عدة أنواع من ال + +39 +00:03:39,300 --> 00:03:45,300 +saturated fatty acids سواء كانت اللي هي ال C10 اقل + +40 +00:03:45,300 --> 00:03:50,480 +من C10 .. C12 اللورك، الميرستك، البلمتك، الاستيرك، + +41 +00:03:50,480 --> 00:03:57,220 +كلهم موجودين إيش؟كنسب من الـ saturated fatty acids + +42 +00:03:57,220 --> 00:04:02,120 +فبشكل عام احنا بيقول ان ال fats بيكون فيهم ال + +43 +00:04:02,120 --> 00:04:08,060 +higher percentage من ال ايش؟ ال higher من ال + +44 +00:04:08,060 --> 00:04:13,810 +saturated fatty acidsمن ال unsaturated لكن ما بين + +45 +00:04:13,810 --> 00:04:17,130 +زيت و زيت ليش بيختلفوا الزيوت في الطعم يعني مش كل + +46 +00:04:17,130 --> 00:04:21,150 +الزيت واحد و مش كل الفات واحد لما نيجي نقول والله + +47 +00:04:21,150 --> 00:04:27,990 +زيت الزتون ولا زيت الصوية على سبيل المثالبختلفه كل + +48 +00:04:27,990 --> 00:04:32,490 +واحد فيه نسبة معينة بتعطي طعم معين ولذلك بشكل عام + +49 +00:04:32,490 --> 00:04:36,630 +احنا متعودين اكتر ان زيت الزيتون نستعمله باستعمال + +50 +00:04:36,630 --> 00:04:41,710 +معين زيت الصيام يمكن للجالي باستعمال تاني هذا فقط + +51 +00:04:41,710 --> 00:04:47,930 +على اختلاف نسبة ايش ال fatty acids وانواعهم واضح + +52 +00:04:47,930 --> 00:04:51,670 +الفكرة هذا اللي بيميز الزيوت و الدون عن بعض نسب ال + +53 +00:04:51,670 --> 00:04:59,210 +fatty acids وانواعها الآنمن سواء قلنا الدهون او + +54 +00:04:59,210 --> 00:05:04,550 +الزيوت بنعمل احنا ايش تفاعل بنسميه soapification + +55 +00:05:04,550 --> 00:05:09,130 +تفاعل تحلل لها وهو التفاعل اللي من خلاله بنحضر + +56 +00:05:09,130 --> 00:05:12,850 +احنا الصابون اللي احنا عارفين يعني عادة الصابون + +57 +00:05:12,850 --> 00:05:18,270 +تحضيرها الصابون العادي البلدي من زيت الزتون انه + +58 +00:05:18,270 --> 00:05:23,130 +انا باخد ال triglycerides مثلاTriglyceride معين اي + +59 +00:05:23,130 --> 00:05:26,650 +زيت زتون انا ماخد زيت عادي من زيت النخل على سبيل + +60 +00:05:26,650 --> 00:05:31,150 +المثال وبعد هيك بالفعل مع ال sodium hydroxide + +61 +00:05:31,150 --> 00:05:37,730 +بيصيرله تحلل بناخد جزء لجليسرين وجزء لجليسرين خلاص + +62 +00:05:37,730 --> 00:05:41,590 +مابناشي يا ابن فصله الان الجزء التاني بيصير على + +63 +00:05:41,590 --> 00:05:47,380 +شكل حامضتلات أحماض و الحامض في وجود ال sodium + +64 +00:05:47,380 --> 00:05:52,340 +hydroxide هيكون على شكل إيش؟ الملح تبعه، الأن لما + +65 +00:05:52,340 --> 00:05:56,940 +صار الحامض على شكل الملح، هذا ملح الحامض هو + +66 +00:05:56,940 --> 00:06:03,200 +الصابون يعني اللبنانيش يقولكم إيش ببساطة الصابون؟ + +67 +00:06:03,200 --> 00:06:11,290 +الجواب بيكون salt إيش هو ال salt؟ Saltملح يعني + +68 +00:06:11,290 --> 00:06:15,430 +طرفه C double bond O O minus نفترض مع ال A plus + +69 +00:06:15,430 --> 00:06:22,650 +Salt of fatty acid هو ملح الفاتي أسد Salt of fatty + +70 +00:06:22,650 --> 00:06:26,570 +acid بنحضره من خلال إن انفاع الزيوت أو الدهون ل + +71 +00:06:26,570 --> 00:06:30,790 +Triglycerides مع Sodium hydroxide طبعا هتلاحظوا + +72 +00:06:30,790 --> 00:06:36,790 +انتوا ان هذا الصابون بيمتاز بإيش بيمتاز بوجود طرف + +73 +00:06:37,690 --> 00:06:43,630 +ننقل إلى السلسلة يعني هذا مثلا من ال بالميتك أسد + +74 +00:06:43,630 --> 00:06:48,630 +يعني ستة عشر كاربون وعشانك بيسموه سوديوم بالميتيت + +75 +00:06:48,630 --> 00:06:53,050 +زي اللي من الاسيتك أسد كنا نسميه سوديوم أسيتيت + +76 +00:06:53,050 --> 00:06:57,310 +الآن هاي عندي ستة عشر كاربون هذه السلسلة اللي هي + +77 +00:06:57,310 --> 00:07:04,970 +الالفتك وعلى طرفها C double bond O O minusالان صار + +78 +00:07:04,970 --> 00:07:08,390 +الصابوني مكون من شغلتين polar part + +79 +00:07:13,350 --> 00:07:17,870 +واضح؟ طبعا ال non-polar part في الصابون هو جزء + +80 +00:07:17,870 --> 00:07:23,890 +كبير ولذلك الصابون يستخدم لغسل ايش؟ الدهون لأن + +81 +00:07:23,890 --> 00:07:28,190 +الدهون non-polar و هذا الجزء non-polar فالدهون لما + +82 +00:07:28,190 --> 00:07:32,650 +احنا بنغسل الأيدان بالصابون بتدوب في أي جزء في ال + +83 +00:07:32,650 --> 00:07:38,310 +non-polar يعني هذا الجزء بيصير ادوب الدهونواضح؟ + +84 +00:07:38,310 --> 00:07:42,070 +هذا الجزء الـ non-polar هو اللي بدوّب الدهون عن + +85 +00:07:42,070 --> 00:07:45,790 +إيد الإنسان لما بيعمل الغسل باستعمال .. إيش؟ + +86 +00:07:45,790 --> 00:07:53,090 +الصابون، الآن لاحظوا معنى، الزيوت غالية وإلى + +87 +00:07:53,090 --> 00:07:57,940 +استعمالات لازمة للناس في الأكل وغيره وغيراتهمظبوط + +88 +00:07:57,940 --> 00:08:02,840 +ولا لأ؟ يعني مثلا زيت الزتون اليوم صار غالي جدا + +89 +00:08:02,840 --> 00:08:06,600 +زمان يمكن كان متوفر والناس جلال وبالتالي كانوا + +90 +00:08:06,600 --> 00:08:10,760 +ياخدوا زيت زتون ويعملوا صابونة اليوم لو بدنا نلاحق + +91 +00:08:10,760 --> 00:08:14,860 +عن ناس صابون كل زيت الزتون ماحدش هيكله كله هنحاوله + +92 +00:08:14,860 --> 00:08:19,860 +لإيش؟ لصابون ولذلك بدأت الفكرة انه لأ ليش ما نعمل + +93 +00:08:19,860 --> 00:08:26,020 +احنا صابونصناعي من غير زيت الزتون الآن اللي بيعمل + +94 +00:08:26,020 --> 00:08:29,840 +صابون صناعي بيقول ما هي الفكرة العامة للصابون + +95 +00:08:29,840 --> 00:08:36,960 +الفكرة العامة للصابون polar مع non polar تمام؟ + +96 +00:08:36,960 --> 00:08:42,140 +جيبهم من أي جهة كانت في الدنيا بتطلع شبيه الصابون + +97 +00:08:42,140 --> 00:08:47,100 +ليش؟ لأن ال non polar هيدوب الدهون اللي هي non + +98 +00:08:47,100 --> 00:08:52,630 +polar وبناء على ذلك صار عندناالاشياء اللي بنسميها + +99 +00:08:52,630 --> 00:08:55,970 +احنا ال synthetic detergents يعني المنظفات + +100 +00:08:55,970 --> 00:09:02,850 +الصناعية او Sidnets لاحظوا كيف انطلقوا بالفكرة هم + +101 +00:09:02,850 --> 00:09:06,790 +جالوا هاي الصابون مثلا من الاستيرك اسد عندي لزوم + +102 +00:09:06,790 --> 00:09:11,690 +Sodium Sterate لو قلالكم اي سؤال في الامتحان + +103 +00:09:11,690 --> 00:09:18,290 +Sodium Sterate او Sodium Palmitateهو سلطة استيريت + +104 +00:09:18,290 --> 00:09:25,010 +بلمتات ميرستات كل هذه صوابين الآن فيها جزء بولا + +105 +00:09:25,010 --> 00:09:34,010 +وجزء نان بولالكن هذا مأخوذ من الزيت الزتون، الآن + +106 +00:09:34,010 --> 00:09:38,890 +كيميائيا قالوا خلينا نجيب جزء non-polar من الكيميا + +107 +00:09:38,890 --> 00:09:42,410 +من عندنا، جابوا سلسلة طويلة وكمان فيها حلقة بنزين، + +108 +00:09:42,410 --> 00:09:46,350 +في كل الأحوال هذه السلسلة إيش مالها؟ non-polar، + +109 +00:09:46,350 --> 00:09:51,800 +وشبكوا معها شيء ما polarمرة تانية مرة تالتة لاحظوا + +110 +00:09:51,800 --> 00:09:57,020 +معي كلمة بولر أهم شيء يكون لها قطب الان ان القطب + +111 +00:09:57,020 --> 00:10:01,580 +يكون موجب او سالب او حتى شيء قطبي مافيش فيه موجب + +112 +00:10:01,580 --> 00:10:06,300 +او سالب بس زي OH بيمشي ولذلك في الصوابين الصناعية + +113 +00:10:06,300 --> 00:10:10,080 +هتلاحظوا ان هذا الجزء مثلا ممكن يكون S double bond + +114 +00:10:10,080 --> 00:10:14,830 +O double bond O O minusسالب عشان هيك بنقول عن هذا + +115 +00:10:14,830 --> 00:10:20,650 +الصابون anionic detergent لأن ال ion هنا سالب ممكن + +116 +00:10:20,650 --> 00:10:26,590 +نحطه موجب السالب قطب والموجب قطب يعني مش إلزام أن + +117 +00:10:26,590 --> 00:10:31,590 +القطب يكون سالب ولذلك لو حطينا ammonium salt هنا + +118 +00:10:31,590 --> 00:10:37,690 +هذا موجب الموجب برضه قطب أو شي قطبة ممكن نحطه شي + +119 +00:10:37,690 --> 00:10:43,370 +متعادل لكن فيه مجموعة قطبية زي ال OHفبصير عندى + +120 +00:10:43,370 --> 00:10:49,110 +ايش؟ non-ionic فالجزء البولر مش الزام انه يكون + +121 +00:10:49,110 --> 00:10:54,950 +سالب لأ ممكن يكون سالب بنقول عنه المنظفات anionic + +122 +00:10:54,950 --> 00:10:58,730 +detergents ممكن يكون موجب بنقول عنها cationic + +123 +00:10:58,730 --> 00:11:03,370 +detergents وممكن يكون لا موجب ولا سالب يعني متعادل + +124 +00:11:03,370 --> 00:11:08,090 +نيوترال او non-ionic detergents و هذه السلاسل + +125 +00:11:08,090 --> 00:11:13,260 +بنحطها من عندنا في الكيمياالكيميا فيها مركبات و + +126 +00:11:13,260 --> 00:11:17,900 +تحضيرات سلسلة كل هذا بتصير عبارة عن ايش؟ Synthetic + +127 +00:11:17,900 --> 00:11:22,060 +detergents أخذت من الصبون فكرته الأساسية اللي هي + +128 +00:11:22,060 --> 00:11:27,280 +بولر و نانبولر وغيرت شو هو البولر وغيرت شو هو ال + +129 +00:11:27,280 --> 00:11:31,620 +نانبولر كمان يعني لاحظوا هنا البولر متغير و ال + +130 +00:11:31,620 --> 00:11:38,500 +نانبولر متغير لكن الفكرة العامة بولر مع نانبولر ما + +131 +00:11:38,500 --> 00:11:39,760 +زالت موجودة + +132 +00:11:42,300 --> 00:11:47,360 +الان ابهيك بنكون خلصنا الـ triglycerides الـ + +133 +00:11:47,360 --> 00:11:53,000 +triglycerides الحقيقة مشتق منهم ال phospholipids + +134 +00:11:53,000 --> 00:11:58,420 +واضح؟ ال triglycerides مشتق منهم ال phospholipids + +135 +00:11:58,420 --> 00:12:02,260 +لو انا بنفس المنطق اللي تو اتكلمت فيه عن ال + +136 +00:12:02,260 --> 00:12:05,660 +triglycerides بدي اقول شومة ال triglycerides عشان + +137 +00:12:05,660 --> 00:12:10,700 +انتقل منهم لل phospholipids كان عندى إجليسرولو + +138 +00:12:10,700 --> 00:12:17,140 +fatty acid أول و fatty acid تاني و fatty acid تالت + +139 +00:12:17,140 --> 00:12:22,810 +مظبوط ولا لأ؟ الآن ال phospholipids بنحافظ فيهمعلى + +140 +00:12:22,810 --> 00:12:27,350 +ال aglycerol وعلى اتنين من ال fatty acids هدول + +141 +00:12:27,350 --> 00:12:31,790 +بيخليهم زي ما هم معناه تالت fatty acid بنشيله بنحط + +142 +00:12:31,790 --> 00:12:36,590 +عليه مجموعة فوسفات مع مجموعة ماء صغيرة معروفة + +143 +00:12:36,590 --> 00:12:40,510 +بالكيميا بيصير اسمه ايش؟ phospholipid لأنه هنا اجى + +144 +00:12:40,510 --> 00:12:46,320 +عندىمجموعة ال .. ال .. ال .. ال .. PO4 فالشئ + +145 +00:12:46,320 --> 00:12:50,540 +المشترك ما بين ال triglycerides و ال phospholipids + +146 +00:12:50,540 --> 00:12:56,690 +هو ال glycerolو اتنين من ال fatty acids واحد من ال + +147 +00:12:56,690 --> 00:13:03,110 +fatty acids بيحولوا الى مجموعة فوسفات مع جزيق صغير + +148 +00:13:03,110 --> 00:13:09,650 +طبعا بشكل عام غير ال glycerol يعني هل كل ال lipids + +149 +00:13:09,650 --> 00:13:15,090 +مبنية على glycerol اللي هو التلاتة carbon يعني هذا + +150 +00:13:15,090 --> 00:13:23,060 +ال glycerol كام carbon؟تلاتة CH2 CH CH2 و بستكمل + +151 +00:13:23,060 --> 00:13:27,360 +من هنا ال limits هدولة اللي مبنيين على ال glycerol + +152 +00:13:27,360 --> 00:13:34,420 +بنسميهم احنا ايش ال tri glycerides الان في عنبنوع + +153 +00:13:34,420 --> 00:13:38,880 +تاني من ال limits يمكن ما جيبناش سيرته مبني على + +154 +00:13:38,880 --> 00:13:44,220 +اربع ذرات كربون بنسميه ايش sphingothenes + +155 +00:13:45,050 --> 00:13:49,150 +السفينجوسينز بدل الجليسيرين بحب انا شبه في + +156 +00:13:49,150 --> 00:13:55,930 +الجليسيرين بالمناسبة CH2OH بعدين CHNH2 بعدين CHOH + +157 +00:13:55,930 --> 00:13:59,530 +بعدين CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH + +158 +00:13:59,530 --> 00:14:00,270 +CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH + +159 +00:14:00,270 --> 00:14:01,230 +CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH + +160 +00:14:01,230 --> 00:14:02,590 +CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH + +161 +00:14:02,590 --> 00:14:05,810 +CH CH CH CH CH CH CH + +162 +00:14:05,810 --> 00:14:07,610 +CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH + +163 +00:14:07,610 --> 00:14:09,590 +CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH + +164 +00:14:09,590 --> 00:14:12,710 +CH CH CH CH CH CH CH CH CH CH CH CH CH CH + +165 +00:14:12,710 --> 00:14:20,690 +CH CH CHتلاتة O H's هنا صار عندى تنتين O H's و + +166 +00:14:20,690 --> 00:14:26,850 +واحدة N H2 بناء على ذلك ال O H's بيعملوا إيش؟ E + +167 +00:14:26,850 --> 00:14:33,290 +star و ال N H2 بيعملوا أمد فالسفينجوسين موجود في E + +168 +00:14:33,290 --> 00:14:38,190 +stars و أمد يعني اتنين E stars و واحد أمد بينما + +169 +00:14:38,190 --> 00:14:43,930 +للـ triglycerides في تلاتة E starsهذا نوع من الـ + +170 +00:14:43,930 --> 00:14:49,730 +lipids و هذا نوع من الـ triglycerides في كل + +171 +00:14:49,730 --> 00:14:54,230 +الأحوال سواء كان البناء الأساسي اللي أنا مبني عندي + +172 +00:14:54,230 --> 00:15:00,930 +على غليسرول بثلاث أواتش أو على الاسفينجوسين بتنتين + +173 +00:15:00,930 --> 00:15:08,310 +أواتش واحدة مجموعة الفاتككل هدولة لو اجينا شبكنا + +174 +00:15:08,310 --> 00:15:12,050 +مع واحدة منهم مجموعة ال phosphoric acid او + +175 +00:15:12,050 --> 00:15:16,270 +الفوسفات و جزء صغير زي ال ethanol امين او زي + +176 +00:15:16,270 --> 00:15:20,530 +الكولين هيدروكسايد بيصير عند ال ايش ال + +177 +00:15:20,530 --> 00:15:25,850 +phospholipids و بناء على ذلك لو احنا بنشوف منظر ال + +178 +00:15:25,850 --> 00:15:30,480 +phospholipidsهتلاحظوا بالشكل القاتل هي + +179 +00:15:30,480 --> 00:15:35,160 +phospholipids من ال glycerol CH2O C double bond O + +180 +00:15:35,160 --> 00:15:38,780 +هذا الجزء زي ما هو زي ما هو في ال tri glycerides E + +181 +00:15:38,780 --> 00:15:45,660 +star وكمان CO O C double bond O whatever هذا نفسه + +182 +00:15:45,660 --> 00:15:49,020 +fatty acid على الموقع التالت ايش حطينا + +183 +00:16:02,680 --> 00:16:04,080 +وبووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو + +184 +00:16:19,850 --> 00:16:23,830 +اللي هو ال phospholipids وبناء على ذلك مرات لما + +185 +00:16:23,830 --> 00:16:27,070 +بييجوا بيختصروا ال phospholipids طبعا هنا مجموعة + +186 +00:16:27,070 --> 00:16:32,090 +الفوسفات مع هذا الجزء بيعملوا طرف منفصل طرف بولر + +187 +00:16:32,090 --> 00:16:36,130 +عشانك مرات لما بيختصروا ال phospholipids بيروحوا + +188 +00:16:36,130 --> 00:16:40,530 +بيعملوا هيك سلسلتين هدول السلسلتين بيقصروا فيهم + +189 +00:16:40,530 --> 00:16:46,070 +الاتنين fatty acids اللي ضالهم إيش موجودينمش احنا + +190 +00:16:46,070 --> 00:16:51,090 +قولنا في تلاتة fatty acids اتنين ضالوا موجودين و + +191 +00:16:51,090 --> 00:16:55,750 +التالت صار phosphate بعلمه بإيش؟ أو ionic بكرة + +192 +00:16:55,750 --> 00:17:02,070 +زرقاء أو برأس أزرق فهي التلاتة fatty acid و الأزرق + +193 +00:17:02,070 --> 00:17:07,100 +هذا إيش؟ phosphate فبصير هذا المنظر العاميعني يمثل + +194 +00:17:07,100 --> 00:17:11,600 +اختصار للإيش؟ لل phospholipid الآن لاحظوا هذا + +195 +00:17:11,600 --> 00:17:16,760 +الجزء مرة تانية polar هذا الجزء non polar فصار + +196 +00:17:16,760 --> 00:17:22,860 +كأنه ال phospholipid polar و non polarواضح؟ هذه + +197 +00:17:22,860 --> 00:17:27,500 +الصفات انه يكون polar و non-polar ع طول بتدخل في + +198 +00:17:27,500 --> 00:17:32,000 +إيش؟ في الوظيفة تبعته يعني ال phospholipid بشكل + +199 +00:17:32,000 --> 00:17:36,820 +أساسي زي ما انتوا شايفين في ال slide السابقة بشكل + +200 +00:17:36,820 --> 00:17:42,900 +جداش؟ 40% من ال cell membrane يعني الجدار .. + +201 +00:17:42,900 --> 00:17:47,620 +الجدار تبع الخلية بنسبة كبيرة منه بيكون عبارة عن + +202 +00:17:47,620 --> 00:17:52,270 +إيش؟phospholipids وعرفنا الـ phospholipids الآن + +203 +00:17:52,270 --> 00:17:58,310 +حسب ترتيب الـ phospholipids بهذا الشكل لو وضعناهم + +204 +00:17:58,310 --> 00:18:04,850 +او لو لفناهم على شكل زي كرة بيسموها ليبوزوم لاحظوا + +205 +00:18:04,850 --> 00:18:09,290 +بيكون في عندى جزء بولر الجزء البولر بتلتصق فيه ايش + +206 +00:18:09,290 --> 00:18:14,570 +الميه اكيواس بيكون و هذا الجزء الخارجي بولر برضه + +207 +00:18:14,570 --> 00:18:19,110 +اكيواس فصار عندى هنا اكيواس interiorو aqueous + +208 +00:18:19,110 --> 00:18:23,390 +exterior aqueous interior و aqueous exterior ليش؟ + +209 +00:18:23,390 --> 00:18:27,230 +لأن هذا الجزء هو الجزء ال إيش ال polar الجزء ال + +210 +00:18:27,230 --> 00:18:30,910 +non polar وين موجود؟ في النص، هذي بيسموها + +211 +00:18:30,910 --> 00:18:35,130 +liposomes بتعني يمكن هي ك aggregates aggregate + +212 +00:18:35,130 --> 00:18:41,100 +يعني تجمع مرت معاكوا في ال biology أوىفي الأحياء + +213 +00:18:41,100 --> 00:18:45,680 +بيمور معاكم أكتر هذا الكلام يعني فقط في منطقة + +214 +00:18:45,680 --> 00:18:50,880 +الكيميا بهمنا أننا نعرفكوا الشكل الكيميائي لكن بعد + +215 +00:18:50,880 --> 00:18:54,940 +هيك إيش وظيفته وكيف بيدخل في الخلية وكيف بيساعد + +216 +00:18:54,940 --> 00:18:58,760 +فيها كل هذا منطقة Biology يعني لما بنجرب على ال + +217 +00:18:58,760 --> 00:19:04,150 +biochemistry بشكل عام بنعطيكوا إيش؟الشكل الكيميائي + +218 +00:19:04,150 --> 00:19:07,270 +ان نكون فاهمين بالظبط ايش ال phospholipids الان + +219 +00:19:07,270 --> 00:19:09,990 +افهمنا انه في اتنين fatty acids دلوا زي ما هم + +220 +00:19:09,990 --> 00:19:14,030 +مجموعة phosphate مع كذا صار في جزء polar جزء non + +221 +00:19:14,030 --> 00:19:17,530 +polar ما إلى ذلك الان بعد ذلك لما تروحوا على ال + +222 +00:19:17,530 --> 00:19:20,930 +biology ينحكوا قدامكوا phospholipids ويبدوا + +223 +00:19:20,930 --> 00:19:29,370 +يعطوكوا تفاصيل اكثر you have an idea واضح غير + +224 +00:19:29,370 --> 00:19:34,760 +ال phospholipidsالـ waxes احنا بتيالي حكينا عنها + +225 +00:19:34,760 --> 00:19:40,500 +قولنا E stars فيها aliphatic chain طويل يمين و + +226 +00:19:40,500 --> 00:19:44,260 +شمال وهذه ال aliphatic chain هي اللي بتتفاعل مع ال + +227 +00:19:44,260 --> 00:19:50,360 +oxygen بتعطيني CO2 زائد H2O زائد ال heat أو ال + +228 +00:19:50,360 --> 00:19:54,060 +light الحرارة اللي احنا بنشوفها وعشانك بنحرق الشمع + +229 +00:19:54,060 --> 00:20:01,450 +فاحنا لما نحرق الشمع بنحرق حقيقةالسلاسل الألفاتية + +230 +00:20:01,450 --> 00:20:07,590 +اللي موجودة على طرفي هذا ال Easter اتكلمنا عن ال + +231 +00:20:07,590 --> 00:20:14,830 +waxes مافيش فيه فكرة اكتر بنجي لنوع تاني من ال + +232 +00:20:14,830 --> 00:20:18,810 +lipids اللي هم ال terbenes و من ال terbenes هنكتشف + +233 +00:20:18,810 --> 00:20:26,150 +انه مشتقة بعدين ل ال steroidsال تيربينز يمكن أكبر + +234 +00:20:26,150 --> 00:20:30,590 +عائلة في ال natural products الطبيعية بتطلعها + +235 +00:20:30,590 --> 00:20:35,570 +النباتات وغيرها وغيراتها، هذه العائلة بتمتاز إنها + +236 +00:20:35,570 --> 00:20:40,250 +مكونة من وحدة أساسية، هذه الوحدة الأساسية هي ال + +237 +00:20:40,250 --> 00:20:44,930 +isopentaneالأيزو بنتين الان هنا بيسموها ايزو brain + +238 +00:20:44,930 --> 00:20:48,850 +unit فالأيزو brain unit هي الأيزو بنتين، لاحظوا، + +239 +00:20:48,850 --> 00:20:52,950 +واحد، اتنين، تلاتة، بهذا الشكل، قولنا هذه ايزو، + +240 +00:20:52,950 --> 00:20:57,710 +العدد الكل، أربعة، خمسة، ايزو، بنتين، لو كانت بس + +241 +00:20:57,710 --> 00:21:00,670 +تلاتة، شابكا، من هنا، كنا نقول ايزو بروبين، مع + +242 +00:21:00,670 --> 00:21:05,650 +أربع ايزو بنتين، بيوتين، ايزو بنتين، ايزو هكسين، + +243 +00:21:05,650 --> 00:21:11,590 +هذه الوحدة الـبنتين او ال isoprene unit من اليوم + +244 +00:21:11,590 --> 00:21:17,050 +الطالع بنسميها بتتجمع مع بعضها بتعمل جزيئات + +245 +00:21:17,050 --> 00:21:20,770 +بنسميها ايش ال turbines فهتلاحظوا القاعدة مباشرة + +246 +00:21:20,770 --> 00:21:25,050 +ان ال turbines هتكون مضاعفات عددها لكل مضاعفات ال + +247 +00:21:25,050 --> 00:21:30,970 +ايش الخامسة يعني ممكن يجتمعوا جزيئين من ال + +248 +00:21:30,970 --> 00:21:34,590 +isoprene unit يعني خمسة و خمسة لما بيجتمع two + +249 +00:21:34,590 --> 00:21:40,520 +isoprene units هيصير عندى كام carbonعشرة تمام هذا + +250 +00:21:40,520 --> 00:21:47,200 +اللي فيه اجتماع جزيئين من ال isoprene units بنسميه + +251 +00:21:47,200 --> 00:21:51,440 +mono turbine ممكن يجتمعوا تلت جزيئات بيصير المجموع + +252 +00:21:51,440 --> 00:21:55,960 +الكل خمستاشر بنسميه cis-q turbines ممكن يجتمعوا + +253 +00:21:55,960 --> 00:22:01,740 +اربع جزيئات بنسميه di turbines اربعة في خمسةعشرين + +254 +00:22:01,740 --> 00:22:05,680 +خمس جزيات خمسة بخمسة خمسة وعشرين sister turbines + +255 +00:22:05,680 --> 00:22:10,160 +ممكن يجتمعوا ست جزيات بنسميها tri turbines ممكن + +256 +00:22:10,160 --> 00:22:16,680 +تمان جزيات tetra turbines فلاحظوا دائما لما تشوفوا + +257 +00:22:16,680 --> 00:22:20,520 +هنا تمانية onygenous alcohol isobarine units هذا + +258 +00:22:20,520 --> 00:22:23,920 +أي نوع من ال turbines ايه اسمه على اتنين التمانية + +259 +00:22:23,920 --> 00:22:27,940 +tetra turbines الستة tri turbines الأربعة + +260 +00:22:30,300 --> 00:22:37,060 +مونو تربين و بيكونوا هدولة جزيئات مختلفة لاحظوا + +261 +00:22:37,060 --> 00:22:41,880 +مثلا هاي جزيئ انتوا بتطلع عليه كأنه جزيئ عادي لكن + +262 +00:22:41,880 --> 00:22:52,320 +لو احنا اتينا اتطلعنا و قسمنا بهذا الشكل هذا + +263 +00:22:52,320 --> 00:22:56,780 +الجزيئ من عشر كربونات عدوا الآن من هنا هاي وحدة ال + +264 +00:22:56,780 --> 00:23:02,700 +ISOطلعوا هاي carbon اتنين تلاتة هاذي ال ISO ولا لأ + +265 +00:23:02,700 --> 00:23:11,000 +اربعة خمسة هاي الخمس درات هاي isoprene unit ونش + +266 +00:23:11,000 --> 00:23:16,240 +نطلع كمان مرة هاي واحد اتنين تلاتة هاي ال ISO + +267 +00:23:16,240 --> 00:23:19,640 +اربعة خمسة + +268 +00:23:21,670 --> 00:23:25,150 +هي isoprene unit و isoprene unit طبعاً لما بتحدوا + +269 +00:23:25,150 --> 00:23:29,190 +بيزيد عليهم مجموعات بيعملوا روابط ثنائية غيره لكن + +270 +00:23:29,190 --> 00:23:34,570 +العدد الكلي لل carbons عشرة، خمسة في اتنين، اذا + +271 +00:23:34,570 --> 00:23:39,830 +هذا اي نوع من التربين، mono-terbine، إله اسم طبعاً + +272 +00:23:40,860 --> 00:23:45,120 +هذا نفس الفكرة لو إجينا نقسمه من هنا أحيانا + +273 +00:23:45,120 --> 00:23:49,820 +المركبات زي هذه بتبين يعني مابخترش على بالك أن هي + +274 +00:23:49,820 --> 00:23:56,060 +فعلا مكونة من الخمستين لكن لو إحنا إجينا أخدناها + +275 +00:23:56,060 --> 00:24:05,940 +بهذا الشكل واضح؟ خلينا نتطلع هاي واحد اتنين تلاتة + +276 +00:24:05,940 --> 00:24:12,720 +هي ال ISO أربعةخمسة هذي isoprene unit ولا لأ اه لو + +277 +00:24:12,720 --> 00:24:20,420 +اتينا واطلعنا منها واحد اتنين تلاتة اربعة خمسة + +278 +00:24:20,420 --> 00:24:26,060 +isoprene unit ولا لأ واضح و بيصير مركبات ماخدة + +279 +00:24:26,060 --> 00:24:29,860 +اسماء كتيرة في الدنيا الآن افهمنا ايش معنى + +280 +00:24:29,860 --> 00:24:34,600 +turbines مش مطلوب مننا نحفظ ولا مركب لكن لما نسمع + +281 +00:24:34,600 --> 00:24:40,130 +turbines they are compounds formed fromIsobrane + +282 +00:24:40,130 --> 00:24:44,210 +units الان لو قلنا لكم الـ Monoturbine كم Isobrane + +283 +00:24:44,210 --> 00:24:51,390 +unit؟ الـ Diterbine، الـ Triterbine، التتراتربين، + +284 +00:24:51,390 --> 00:24:55,510 +وقيتا لو جينا قلنا لكم كم carbon atom التتراتربين + +285 +00:24:58,300 --> 00:25:02,120 +تمانية في خمسة مش تمانية ايزوبرين يونيتز تمانية في + +286 +00:25:02,120 --> 00:25:07,040 +خمسة اربعين هذه السؤال مرات بتجيكوا اكمل الفراغ و + +287 +00:25:07,040 --> 00:25:11,220 +صح و غلط يعني نيجي نقولكوا تتراتيربينز contain 30 + +288 +00:25:11,220 --> 00:25:17,160 +carbon atoms او 3 ايزوبرين يونيتز او 7 ايزوبرين + +289 +00:25:17,160 --> 00:25:24,800 +يونيتز واضح الفكرة اقل التقدير احفظولي ايش يسمى ال + +290 +00:25:24,800 --> 00:25:30,670 +monoوالداي و الاتراي و التترا بلاش تحفظوا الإسمين + +291 +00:25:30,670 --> 00:25:35,170 +اللي تقعدوا فيهم سيسكيو تيربينز و سيستر تيربينز + +292 +00:25:35,830 --> 00:25:42,250 +مونو، داي، تراي، تترا، واضح؟ فلو نسألنا عن عدد ال + +293 +00:25:42,250 --> 00:25:45,670 +isoprene units أو عن عدد ال carbon atoms اللي + +294 +00:25:45,670 --> 00:25:50,690 +موجودة فيهم، نكون إيش؟ عارفين طبعا اكتر في منهم + +295 +00:25:50,690 --> 00:25:55,330 +أحيانا البعض حتى من مصدر حيوان بيسموه squalene هذا + +296 +00:25:55,330 --> 00:26:01,060 +في أزل تلاتين6 isoprene units 30 carbon atoms + +297 +00:26:01,060 --> 00:26:06,420 +لاحظوا معنى ال beta carotene ال beta carotene اللي + +298 +00:26:06,420 --> 00:26:10,240 +موجود في الجزر و اللي بيعطي الجزر اللون الأصفر + +299 +00:26:10,240 --> 00:26:17,380 +تبعه برضه هذا لو اجينا جسمناه هلاحظ انه عبارة عن + +300 +00:26:17,380 --> 00:26:22,930 +ايشتربين من عدة isobrain units هذا ال beta + +301 +00:26:22,930 --> 00:26:28,310 +-carotene لما الإنسان بياخده في ال enzymes بيكسر + +302 +00:26:28,310 --> 00:26:32,150 +من النص يعني اتخيلوا هذا الشكل العام بدون تفاصيل + +303 +00:26:32,150 --> 00:26:38,690 +كسرناه من النص من هنا نصه اتطلع عليه هذا النص + +304 +00:26:38,690 --> 00:26:45,480 +المشترك منههو عبارة عن ايش؟ vitamin A بناء على ذلك + +305 +00:26:45,480 --> 00:26:51,560 +البني آدم اللي بياكل جزر كتير اللي بياكل جزر كتير + +306 +00:26:51,560 --> 00:26:59,440 +بإمكانكوا تتخيلوا ان الجزر بهذا الشكل تمام؟ ان + +307 +00:26:59,440 --> 00:27:04,880 +الجزر بهذا الشكل الان vitamin A هو هذا الجزء + +308 +00:27:05,720 --> 00:27:08,920 +Vitamin A هو هذا الجزر الآن اللي أخد ال beta + +309 +00:27:08,920 --> 00:27:14,460 +-carotene من الجزر بعملية كسر من نص ال beta + +310 +00:27:14,460 --> 00:27:17,920 +-carotene بيطلع عنده ال vitamin A تخيلوا أن حد ما + +311 +00:27:17,920 --> 00:27:23,960 +أخدش ال beta-carotene وقعد يكوّن هذا من مكوناته + +312 +00:27:23,960 --> 00:27:29,910 +الأولية فأسهل أشياء البني آدم يأكل الجزرالجزر فيه + +313 +00:27:29,910 --> 00:27:34,710 +ال beta-carotene الكامل بعملية تكسور بسيطة صار في + +314 +00:27:34,710 --> 00:27:39,950 +عنده vitamin A و vitamin A طبعا اللي لما تدرسوا + +315 +00:27:39,950 --> 00:27:42,710 +عملية الإبصار بالذات الناس اللي هيدرسوا بصريات + +316 +00:27:42,710 --> 00:27:48,510 +طبية في رابطة cis بتصير trans اسمه retinol + +317 +00:27:48,510 --> 00:27:52,310 +بالأكسجين بيصير له أكسدة مع isomerization cis + +318 +00:27:52,310 --> 00:27:57,260 +trans بيصير cis-retinalهذا الانتقال بعد ذلك بين + +319 +00:27:57,260 --> 00:28:00,640 +الـ cis والـ trans مع انتصاص الضوء هو اللي بيبقى + +320 +00:28:00,640 --> 00:28:05,570 +مسئول عن كل عملية الإبصاريعني هذا ال 11-cis + +321 +00:28:05,570 --> 00:28:09,890 +-retinal اللي فيها دي موجودة الرابطة cis ومع + +322 +00:28:09,890 --> 00:28:13,070 +امتصاص الضوء بتصير ال Trans بعدين بتعود تفقد الضوء + +323 +00:28:13,070 --> 00:28:17,350 +بترجع cis هذه الإشارات الضوئية كلها هي اللي بتنقل + +324 +00:28:17,350 --> 00:28:22,190 +للمخ و بتعمل إيش الصورة فكل عملية الإبصار معتمد + +325 +00:28:22,190 --> 00:28:26,730 +على إيش؟ على ال 11-cis-retinal 11 طبعا على موقع + +326 +00:28:26,730 --> 00:28:31,170 +الرابطة الزوجية هنا 11 11-cis-retinal طب 11-cis + +327 +00:28:31,170 --> 00:28:35,380 +-retinal من وين جبناها؟من vitamin A، طب vitamin A + +328 +00:28:35,380 --> 00:28:39,800 +من وين جيبناه؟ من الجزر، إذا المادة الأساسية + +329 +00:28:39,800 --> 00:28:43,860 +للإبصار ال 11th-seretinal إجت من vitamin A، إجت من + +330 +00:28:43,860 --> 00:28:50,780 +الجزر، فالناس اعترافا بالأصل، إيش بيقولوا؟ الجزر + +331 +00:28:50,780 --> 00:28:54,510 +بيقوى النظر، بيقولوش vitamin A بيقوى النظرقولوا + +332 +00:28:54,510 --> 00:29:00,710 +الجزر بجوّل نظر لأن الجزر هو مصدر ايش؟ vitamin A و + +333 +00:29:00,710 --> 00:29:04,970 +vitamin A هو اللي عمل لهذا واضح؟ ولذلك لو سألنا أي + +334 +00:29:04,970 --> 00:29:10,470 +بني آدم من الأصل تبعك ممكن يقول الأب بس بنفس الوقت + +335 +00:29:10,470 --> 00:29:15,990 +ممكن يقول ايش؟ الجد فالعرب لما كانوا بيتباهوا + +336 +00:29:15,990 --> 00:29:21,910 +كانوا بيتباهوا بإيش مرات كتيرة؟ بالأجدادمظبوط ولا + +337 +00:29:21,910 --> 00:29:28,350 +لأ؟ لما الفرزق كان بيتباهى بأجداده وببيته وبعيلته + +338 +00:29:28,350 --> 00:29:34,070 +ويقول بيت بناه لنا المليك وما بنى حكم السماء فإنه + +339 +00:29:34,070 --> 00:29:40,270 +لا ينقض بيت زرارة محتبن بفنائه ومجاشع وابو الفوارس + +340 +00:29:40,270 --> 00:29:45,870 +نحشله، هدول أجداده، الآن مين جد السسر تنال؟ الجزر + +341 +00:29:47,990 --> 00:29:52,570 +احنا مابنقولش عاد انتبهوا معناه احنا لما نرجع خطوة + +342 +00:29:52,570 --> 00:29:57,830 +خطوة للخلف بالكيميا بنقول ال beta-carotene الان + +343 +00:29:57,830 --> 00:30:00,230 +واحدة منكم بدها تروح تقول عند إمها ال beta + +344 +00:30:00,230 --> 00:30:03,110 +-carotene ولا بتقول اهو ال beta-carotene نفسه من + +345 +00:30:03,110 --> 00:30:09,510 +وين من الجزر اه فبنقول في الآخر الجزر بجوّر نظر + +346 +00:30:09,510 --> 00:30:13,250 +الان السلسلة جزر beta-carotene، vitamin A، S، + +347 +00:30:13,250 --> 00:30:17,470 +ريتينال افهمنا كيف بتيجي السلسلة؟ + +348 +00:30:21,760 --> 00:30:29,200 +الآن من هذه الـ Isobrane units أيضا بتكون مركبات + +349 +00:30:29,200 --> 00:30:35,760 +من أربع حلقات تلت حلقات سداسيات و حلقة خماسية بهذا + +350 +00:30:35,760 --> 00:30:39,880 +الشكل هذول أفلا كمان جايين من ال Isobrane units + +351 +00:30:39,880 --> 00:30:46,620 +بنسميهم إيش؟ Steroids فال Steroids ببساطة هم عبارة + +352 +00:30:46,620 --> 00:30:52,330 +عن Lipidsمن أربع حلقات تلت حلقات سداسية و حلقة + +353 +00:30:52,330 --> 00:30:56,570 +خمسية بالشكل هذا يعني ما نحطهم مش بشكل مستقيم لأ + +354 +00:30:56,570 --> 00:31:02,050 +لهم شكل خلاص بينطبع إيش صورة في ذهن الإنسان طبعا + +355 +00:31:02,050 --> 00:31:07,430 +هدول الأربع حلقات فيهم مجموعات في أماكن مختلفة حسب + +356 +00:31:07,430 --> 00:31:12,770 +اختلاف المجموعات تبعتهم بيصيروا يطلعولنا إيشأنواع + +357 +00:31:12,770 --> 00:31:17,470 +من الجزيئات و من الهرمونات و ما إلى ذلك ال + +358 +00:31:17,470 --> 00:31:22,510 +backbone تبعهم اللي هو الهيكل الأساسي تبعهم الأربع + +359 +00:31:22,510 --> 00:31:27,990 +حلقات لكن الاختلاف في المجموعات اللي موجودة عليهم + +360 +00:31:27,990 --> 00:31:35,160 +فمن أشهرهم على سبيل المثال الكوليسترونواضح؟ + +361 +00:31:35,160 --> 00:31:41,360 +الكوليسترول في النهاية بيصف من 27 carbon atom محضر + +362 +00:31:41,360 --> 00:31:48,100 +من الانوستيرول موجود في ال animal cells بشكل أساسي + +363 +00:31:48,100 --> 00:31:54,490 +بتركز في ال brain و في الحبل الشوكةSpinal cord هو + +364 +00:31:54,490 --> 00:31:59,450 +المكون الأساسي للجاليستون الجاليستون يعني حصوة + +365 +00:31:59,450 --> 00:32:04,290 +المرارة طبعا الناس اللي منكوا حدرسوا الحصوات سبق + +366 +00:32:04,290 --> 00:32:08,070 +أنه مرات اتكلمنا عن الحصوات اللي من الأملاح في + +367 +00:32:08,070 --> 00:32:14,970 +الكيلية وقلنا انها الشرر الاش؟ مين متذكرة؟الـ + +368 +00:32:14,970 --> 00:32:19,070 +Oxalic Acid Salts لما حكينا عن ال Oxalic Acid و + +369 +00:32:19,070 --> 00:32:23,090 +قلتلكوا احفظوا شكل ال Oxalic Acid ال Oxalic Acid + +370 +00:32:23,090 --> 00:32:27,070 +Salts متذكرينه؟ اقول لكوا فيه فوسفات و فيه من ال + +371 +00:32:27,070 --> 00:32:31,610 +Oxalic Acid، ال Oxalic Acid هذا الحامض اللي مكون + +372 +00:32:31,610 --> 00:32:39,440 +من كم؟ Carbon, Diacid, Oxalic AcidOxalic acid لما + +373 +00:32:39,440 --> 00:32:43,040 +يعمل salts من هنا هذه ال salts بتعمل حصوات إيش + +374 +00:32:43,040 --> 00:32:47,680 +الكيلية؟ حصوات الكيلية حجار stones يعني لما ناس + +375 +00:32:47,680 --> 00:32:52,280 +أحيانا حد منهم بيعمل عملية الحصوة و بيطلق .. + +376 +00:32:52,280 --> 00:32:56,900 +بيحطوها بالشكوش بيكسروها حصوة إيش؟ حجار بينما + +377 +00:32:56,900 --> 00:33:03,850 +حصوات المرارة حصوات مطاطيةيعني دهنية بتنجص بإش + +378 +00:33:03,850 --> 00:33:08,790 +بالسكينة بتنجص بالسكينة هذه حصوات المرارة من الإش + +379 +00:33:08,790 --> 00:33:17,120 +مكونها الأساسي هوالكلسترول واضح مكونها الأساسي هو + +380 +00:33:17,120 --> 00:33:24,020 +الكلسترول طبعا الكلسترول بيضلوا يرتبط في الذهن هو + +381 +00:33:24,020 --> 00:33:29,500 +الكلسترول واحد الكلسترول واحد كليسترول كيميائيا + +382 +00:33:29,500 --> 00:33:35,580 +كلسترول لكن مرات ربما تصيروا تسمعوا والان بحكي + +383 +00:33:35,580 --> 00:33:40,390 +بشكل عام كثقافة عامة جداو بتعود تتوسع فيه اكيد في + +384 +00:33:40,390 --> 00:33:47,430 +ال biology بتسمع كوليسترول سيء و كوليسترولحميد او + +385 +00:33:47,430 --> 00:33:55,970 +مفيد اه اللي هي ال HDL و LDL high density + +386 +00:33:55,970 --> 00:34:00,210 +lipoprotein و low density lipoprotein الان بيصير + +387 +00:34:00,210 --> 00:34:04,610 +الكوليسترول نفسه هذا يعني الكوليسترول واحد لكن هذا + +388 +00:34:04,610 --> 00:34:13,300 +الكوليسترول لما نقول انه في عنده HDLو LDL و هذا ال + +389 +00:34:13,300 --> 00:34:16,900 +LDL هو اللي بيقولوا عنه الكوليسترول ايش السيء اللي + +390 +00:34:16,900 --> 00:34:21,200 +بيعمل ترسبات وجلطات هذا الكوليسترول نفسه بيصير + +391 +00:34:21,200 --> 00:34:27,630 +محمول هيكا في قلب بروتين معينالان البروتين انواع + +392 +00:34:27,630 --> 00:34:31,510 +يعني خلينا نتخيل انه ممكن البروتين الأحمر و ممكن + +393 +00:34:31,510 --> 00:34:36,350 +بروتين تاني أخضر يحمله فحسب نوع البروتين الان + +394 +00:34:36,350 --> 00:34:40,090 +الكلسترول نفترض اللي محمول في البروتين الأحمر + +395 +00:34:40,090 --> 00:34:46,590 +بيكون كثافته أقل شوية صغيرة من الكلسترول إذا كان + +396 +00:34:46,590 --> 00:34:52,510 +محمول في بروتين تاني في بروتين تاني هيك نفترضههذا + +397 +00:34:52,510 --> 00:34:57,190 +البروتين الأخضر فبصير بالمجموع في عنده low density + +398 +00:34:57,190 --> 00:35:02,730 +lipoprotein و high density lipoprotein طبعا واحد + +399 +00:35:02,730 --> 00:35:09,420 +منهمدار والثاني مفيد اللي داره بيحب ان نسبته تكون + +400 +00:35:09,420 --> 00:35:12,680 +دائما قليلة ومحددة بتاخدوها في التحاليل الطبية + +401 +00:35:12,680 --> 00:35:16,600 +اللي هو ال low density ال high density حتى لما + +402 +00:35:16,600 --> 00:35:21,140 +بيزيد بيكون ايش بيكون كويس في كل الأحوال مش ال + +403 +00:35:21,140 --> 00:35:26,650 +cholesterol نوعينلأ الكوليسترول ككلسترول نوع واحد + +404 +00:35:26,650 --> 00:35:31,670 +هو هذا الجزء كوليسترول جزء محدد لكن الكوليسترول + +405 +00:35:31,670 --> 00:35:38,140 +محمول في أي بروتينصار نوعين يعني الكوليسترول مع + +406 +00:35:38,140 --> 00:35:42,720 +بروتين ألف صار نوع بكثافة منخفضة الكوليسترول مع + +407 +00:35:42,720 --> 00:35:47,900 +بروتين با صار نوع تاني بكثافة مرتفعة لكن + +408 +00:35:47,900 --> 00:35:54,440 +الكوليسترول نوع واحد الكوليسترول كجزء كيميائي كجزء + +409 +00:35:54,440 --> 00:35:59,140 +كيميائي نوع واحد لكن هذا الكوليسترول محمول في أي + +410 +00:35:59,140 --> 00:36:06,910 +بروتين هنا بيصير إيش الخلاف واضح؟فعشان هيك حيصير + +411 +00:36:06,910 --> 00:36:13,070 +عندكم HDL و LDL و لما تصيروا تحللوا بعدها + +412 +00:36:13,070 --> 00:36:19,330 +كوليسترول بتصيروا و الله تبحثوا عن total كوليسترول + +413 +00:36:19,330 --> 00:36:23,690 +و لا تقعدوا تفصلوا فيه بدي أشوف جديش ال HDL و جديش + +414 +00:36:23,690 --> 00:36:28,390 +ال LDL بصير هذا جزء من العلم اللي هتاخدوه بالتفصيل + +415 +00:36:29,230 --> 00:36:34,110 +بس احنا الآن بناخد الشكل العام للكلسترول وقلنا عنه + +416 +00:36:34,110 --> 00:36:38,110 +مكون أساسي لحصوة المرارة وقلنا عنه انه مكون من أكم + +417 +00:36:38,110 --> 00:36:45,910 +حلقة؟ أربع حلقات وهي هنا شكل حصوة المرارة الان + +418 +00:36:45,910 --> 00:36:50,910 +لاحظوا ان الكوليسترول أساسي في الهرمونات الجنسية + +419 +00:36:51,910 --> 00:36:57,310 +سواء كانت الهرمونات الجنسية الذكورية أو الأنثوية + +420 +00:36:57,310 --> 00:37:01,930 +الهرمونات الأنثوية بيسموها Astrogens ال Astrogens + +421 +00:37:01,930 --> 00:37:06,730 +اللي هي ال Female Hormones والهرمونات بتاع ال Male + +422 +00:37:06,730 --> 00:37:11,270 +Hormones إيش بيسموهم؟ Androgens من أشهرهم بتاع ال + +423 +00:37:11,270 --> 00:37:16,810 +females ال Estradiol و ال Progesteroneلمّا نطلع + +424 +00:37:16,810 --> 00:37:21,110 +عليهم، إيش الوظائف تبعتهم؟ وظائفهم تنظيم الصفات + +425 +00:37:21,110 --> 00:37:25,930 +الجنسية، خشونة .. نعومة الصوت عند الإناف مثلا، + +426 +00:37:25,930 --> 00:37:30,010 +خشونة الصوت عند الرجال، الشعر، بعدين بتدخلوا في + +427 +00:37:30,010 --> 00:37:33,590 +الدورة الشهرية عند النساء، كل هذا الكلام بيمنعوا + +428 +00:37:33,590 --> 00:37:37,310 +التبويض في مرحلة معينة لما بيصير الحمل، بييجي في + +429 +00:37:37,310 --> 00:37:40,850 +التبويض، كل هذا الكلام، مين اللي بيقوم فيه؟ اللي + +430 +00:37:40,850 --> 00:37:44,710 +هي ال Astrogens استرديولوبروجسترون + +431 +00:37:45,920 --> 00:37:51,480 +عند الرجال الهرمون او عند الذكور ايش تستوستيرون و + +432 +00:37:51,480 --> 00:37:56,740 +أندروستيرون الان لو اجينا تطلعنا عليهم كلهم ايش + +433 +00:37:56,740 --> 00:38:01,120 +استيرويد انا عملتلهم صورة مكبرة شوية تطلعوا + +434 +00:38:01,120 --> 00:38:07,100 +استيرويد استيرويد استيرويداستيرويد طب وين الاختلاف + +435 +00:38:07,100 --> 00:38:12,180 +بينهم؟ في المجموعات الوظيفية يعني لو اجيت انا + +436 +00:38:12,180 --> 00:38:18,660 +لليبروجيستيرون مثلا والتيستيستيرون اشهر هرمون عند + +437 +00:38:18,660 --> 00:38:22,140 +الاناث دائما بيكونوا ايش يقولوا؟ ليبروجيستيرون عند + +438 +00:38:22,140 --> 00:38:26,280 +الذكور؟ التيستيستيرون ابدوا واتأملوا في الشكلين + +439 +00:38:26,280 --> 00:38:31,980 +تبعونهم ابدوا من عندها الـ C double bond O و + +440 +00:38:31,980 --> 00:38:38,570 +الحلقةو CH3 و لاحظوا كيف ال stereochemistry مهمة + +441 +00:38:38,570 --> 00:38:43,310 +جدا .. ال stereochemistry .. الأن منها .. منها .. + +442 +00:38:43,310 --> 00:38:48,790 +منها .. في الآخر ماصفش غير هذا الفرق .. Acetyl + +443 +00:38:48,790 --> 00:38:53,630 +group و لا OH group .. بتخلي واحد هرمون أنثوي و + +444 +00:38:53,630 --> 00:38:59,440 +بتخلي الثاني هرمون ذكوريلاحظوا كم التغير البسيط .. + +445 +00:38:59,440 --> 00:39:04,180 +التغير البسيط في مجموعة كيميائية جاعت بعكس الوظائف + +446 +00:39:04,180 --> 00:39:07,680 +احنا شوفنا اكتر من هيك احنا شوفنا كمان في ال + +447 +00:39:07,680 --> 00:39:11,580 +stereo chemistry انه تغير شكل المجموعات بيحول + +448 +00:39:11,580 --> 00:39:15,980 +المركب من سام إلى مفيده عشان هيك انا لاحظوا كم + +449 +00:39:15,980 --> 00:39:19,460 +عندي stereo chemistry هانو هانو هانو كل هذا الكلام + +450 +00:39:19,460 --> 00:39:25,280 +مدروس بشكل كامل عند العلماء فهذه ال six hormones + +451 +00:39:25,280 --> 00:39:31,280 +they arein general استيرويدز بينقسموا زي ما اتفقنا + +452 +00:39:31,280 --> 00:39:35,620 +إلى كام نوع استروجينز اللي هي ال female hormones و + +453 +00:39:35,620 --> 00:39:39,420 +أندروجينز و في منها أنواع و أشكال مش مطلوب نحفظ + +454 +00:39:39,420 --> 00:39:44,620 +بالتأكيد ولا شكل بس يكون فاهمين الفكرة أن كلهم + +455 +00:39:44,620 --> 00:39:49,800 +استيرويدز و أن الشبه بينهم كبير جدا لكن اختلاف + +456 +00:39:49,800 --> 00:39:55,400 +مجموعة يؤدي إلى اختلاف كبير في الوظيفةطبعا من + +457 +00:39:55,400 --> 00:40:00,960 +هدولة بيصير عندي أشياء اللي هي بنطلع منهم أدوية + +458 +00:40:00,960 --> 00:40:10,870 +على سبيل المثال الدواء اللي هيالأقراس منع الحمل هي + +459 +00:40:10,870 --> 00:40:17,290 +أقراس شبيهة بهذه الهرمونات مثلا هنا دوة هي بيشبه + +460 +00:40:17,290 --> 00:40:22,530 +ال استيرويد برضه هذا بيساعد على الإجهاد بدون + +461 +00:40:22,530 --> 00:40:26,590 +عمليات جراحية في مراحل معينة مقارنة في أوروبا + +462 +00:40:26,590 --> 00:40:31,150 +وغيرها لو بدنا نشوف ال cortisone اللي بيستعملوه + +463 +00:40:31,150 --> 00:40:35,770 +لالتهاب المفاصل و للناس اللي عندهم تكسر في ال + +464 +00:40:35,770 --> 00:40:41,090 +plateletsفي التجلط هذا ال Cortisone الناس اللي + +465 +00:40:41,090 --> 00:40:46,150 +بياخدوه بتشوفوهم كيف بينتفخوا اه هاي ال Cortisone + +466 +00:40:46,150 --> 00:40:52,230 +استيرويدز بالنسبة شبه .. بالنسبة شبه كبيرة في ال + +467 +00:40:52,230 --> 00:40:56,630 +sex hormone يستعمل بشكل أساسي in the treatment of + +468 +00:40:56,630 --> 00:41:05,210 +arthritis التي هي إيش؟ التهاب المفاصلالمفاصل والـ + +469 +00:41:05,210 --> 00:41:09,890 +platelets فالخلاصة انه هيرمونات كتير مأخوذ منها + +470 +00:41:09,890 --> 00:41:14,950 +كمان أدوية كتير كلها في طبيعتها ايش بنسميها؟ + +471 +00:41:14,950 --> 00:41:19,270 +استيرويدال وعشان هيك هتصيروا تلاقوا في الأدوية وفي + +472 +00:41:19,270 --> 00:41:23,850 +المضادات الحيوية انه تلاقوا استيرويدال drugs يعني + +473 +00:41:23,850 --> 00:41:26,830 +أدوية من الاستيرويدس ايش يعني أدوية من + +474 +00:41:26,830 --> 00:41:27,810 +الاستيرويدس؟ + +475 +00:41:32,390 --> 00:41:36,590 +اربع حلقات حتى لو زعلوا جماعة رابعة مش موضوع احنا + +476 +00:41:36,590 --> 00:41:44,430 +بنقول ايش اربع حلقات الاستيرويد اربع حلقات ابهيك + +477 +00:41:44,430 --> 00:41:50,350 +بننتهي من اعطاء فكرة عامة عن موضوع ال labels و الى + +478 +00:41:50,350 --> 00:41:51,710 +لقاء قادم ان شاء الله + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..3da6303a3fdf287cd8940d3417be8d341f32092e --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 3944, "start": 19.74, "end": 39.44, "text": "بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في ال dry glycerides و ال fats and oils يمكن لاحقته انتوا شغلة ان فيهم شيء مشترك الشيء المشترك اللي فيهم هو ال glycerol واضح؟", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 1975, 2655, 4117, 19528, 8315, 8978, 2423, 4016, 22633, 1776, 1875, 4032, 2423, 29885, 293, 22177, 7251, 43020, 20193, 5016, 4587, 47395, 16472, 2655, 14407, 13412, 17082, 37977, 16472, 8978, 16095, 44049, 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{"start": 378.71, "end": 379.19, "word": " ملح", "probability": 0.9811197916666666}, {"start": 379.19, "end": 379.79, "word": " الفاتي", "probability": 0.8680013020833334}, {"start": 379.79, "end": 380.25, "word": " أسد", "probability": 0.7648111979166666}, {"start": 380.25, "end": 382.17, "word": " Salt", "probability": 0.68994140625}, {"start": 382.17, "end": 382.39, "word": " of", "probability": 0.974609375}, {"start": 382.39, "end": 382.65, "word": " fatty", "probability": 0.86328125}, {"start": 382.65, "end": 382.97, "word": " acid", "probability": 0.951171875}, {"start": 382.97, "end": 383.77, "word": " بنحضره", "probability": 0.95380859375}, {"start": 383.77, "end": 383.91, "word": " من", "probability": 0.99365234375}, {"start": 383.91, "end": 384.27, "word": " خلال", "probability": 0.99560546875}, {"start": 384.27, "end": 384.45, "word": " إن", "probability": 0.276123046875}, {"start": 384.45, "end": 384.91, "word": " انفاع", "probability": 0.688720703125}, {"start": 384.91, 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Triterbine، التتراتربين، وقيتا لو جينا قلنا لكم كم carbon atom التتراتربين", "tokens": [40, 539, 1443, 1929, 6815, 2423, 7649, 45164, 12174, 1211, 8315, 5296, 24793, 2423, 39184, 4713, 310, 16659, 533, 9122, 2304, 286, 539, 1443, 1929, 4985, 22807, 2423, 39184, 413, 1681, 65, 533, 12399, 2423, 39184, 1765, 1681, 65, 533, 12399, 16712, 2655, 2288, 9307, 25513, 9957, 12399, 4032, 4587, 36081, 995, 45164, 10874, 1829, 8315, 12174, 1211, 8315, 5296, 24793, 9122, 2304, 5954, 12018, 16712, 2655, 2288, 9307, 25513, 9957], "avg_logprob": -0.4587673731148243, "compression_ratio": 1.6838235294117647, "no_speech_prob": 0.0, "words": [{"start": 1479.21, "end": 1480.13, "word": "Isobrane", "probability": 0.6043548583984375}, {"start": 1480.13, "end": 1480.81, "word": " units", "probability": 0.55908203125}, {"start": 1480.81, "end": 1481.35, "word": " الان", "probability": 0.257659912109375}, {"start": 1481.35, "end": 1481.47, "word": " لو", "probability": 0.79150390625}, {"start": 1481.47, "end": 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بتعمل إيش الصورة فكل عملية الإبصار معتمد على إيش؟ على ال 11-cis-retinal 11 طبعا على موقع الرابطة الزوجية هنا 11 11-cis-retinal طب 11-cis-retinal من وين جبناها؟", "tokens": [40228, 22653, 23758, 2423, 2975, 12, 26720, 12, 1505, 2071, 13672, 1829, 8978, 11296, 11778, 1829, 3714, 29245, 23328, 3660, 34892, 16758, 9566, 3660, 37847, 4032, 2304, 3615, 1975, 2304, 2655, 9381, 33546, 6024, 114, 2407, 38207, 39894, 9381, 13546, 2423, 6531, 39182, 9957, 39894, 3615, 23328, 6055, 5172, 28543, 6024, 114, 2407, 38207, 39894, 47341, 3615, 37847, 29538, 33688, 8592, 9640, 9307, 6024, 114, 2407, 19986, 10632, 28242, 11296, 39896, 13672, 1829, 39894, 1863, 4587, 1211, 5296, 19528, 9778, 4032, 39894, 25957, 1211, 11933, 1829, 8592, 31767, 13063, 3660, 6156, 28820, 6225, 42213, 10632, 33688, 3555, 9381, 9640, 20449, 39237, 3215, 15844, 11933, 1829, 8592, 22807, 15844, 2423, 2975, 12, 26720, 12, 1505, 2071, 2975, 23032, 3555, 3615, 995, 15844, 3714, 30543, 3615, 34892, 16758, 9566, 3660, 6024, 110, 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لما نعمل + +6 +00:00:43,740 --> 00:00:47,560 +generation of a chiral center بيطلع عندى racemic + +7 +00:00:47,560 --> 00:00:50,400 +mixture equal mixture of enantiomers و هذا بده + +8 +00:00:50,400 --> 00:00:54,830 +غلبة و بده فصل و ما إلى ذلكوالان بيحاولوا انهم + +9 +00:00:54,830 --> 00:00:59,250 +يتغلبوا على هذا الكلام من خلال تقنيات حديثة في + +10 +00:00:59,250 --> 00:01:04,390 +التحضير بيسموها asymmetric synthesis هذا التفاعل + +11 +00:01:04,390 --> 00:01:10,030 +الأولالتفاعل التاني، لو أنا يا تورا بعمل تفاعل + +12 +00:01:10,030 --> 00:01:15,450 +بعيدا عن ال chiral center، الآن إيش معنى بعيدا عن + +13 +00:01:15,450 --> 00:01:21,310 +ال chiral center؟ بمعنى لأكسر رابطة متصلة بال + +14 +00:01:21,310 --> 00:01:25,330 +chiral center، يعني الأربع روابط المتصلين بال + +15 +00:01:25,330 --> 00:01:30,950 +chiral center بكسرهم مشكل ما بعد ذلك يعتبر ايش؟ + +16 +00:01:30,950 --> 00:01:35,230 +تفاعل بعيد عن الـ Chiral Center واضح الفكرة؟ يعني + +17 +00:01:35,230 --> 00:01:39,110 +مثلا في هذا المركب، عندي هنا أنا Chiral Center + +18 +00:01:39,110 --> 00:01:45,010 +متصل بـ Methyl و بـ Ethyl و COH و بH، الآن هذا الـ + +19 +00:01:45,010 --> 00:01:50,240 +Chiral Center عليه كام رابطةأربع روابط لو أنا بدي + +20 +00:01:50,240 --> 00:01:55,460 +أبدل مجموعة ال O H هنا اللي هي ال acidic O H + +21 +00:01:55,460 --> 00:02:01,200 +مجموعة ال O H الحامضية هذه كلها بمجموعة O Ethyl + +22 +00:02:01,200 --> 00:02:06,420 +بمعنى في الكيميا هذا التفاعل هنتعلمه بنبدل فيه ال + +23 +00:02:06,420 --> 00:02:12,340 +acid ل E starباستعمال التفاعل مع الكحول شيلت الـ + +24 +00:02:12,340 --> 00:02:19,240 +OH و خلتها ايش؟ O Ethan الان هذه الأربع رواضة كسرت + +25 +00:02:19,240 --> 00:02:25,380 +جزء منها؟ لأ وبناء على ذلكالجيومتري حوالين + +26 +00:02:25,380 --> 00:02:28,640 +الكايرال كاربون الشكل اللذس حوالين الكايرال كاربون + +27 +00:02:28,640 --> 00:02:33,620 +بيضل زي ما هو فأنا كأن بعمل عملية ايش نسخ و لصق + +28 +00:02:33,620 --> 00:02:38,960 +بلغة الكمبيوتر يعني باجي بعمل نسخ لهذا بكل موابط و + +29 +00:02:38,960 --> 00:02:43,740 +لاحظوا ال H باتجاه ال CO باتجاه ال CH3 ال إثل بحطه + +30 +00:02:43,740 --> 00:02:48,120 +هنا و بعمل التغيير اللي عندهو بناء على ذلك بنقول + +31 +00:02:48,120 --> 00:02:52,740 +انه تم عنده retention of configuration يعني الشكل + +32 +00:02:52,740 --> 00:02:58,360 +ضل زي ما هو اتجاه الاربع روابط اللي محيطين بال + +33 +00:02:58,360 --> 00:03:03,440 +chiral center ضالهم ايش زي ما هو لو انا بدي اعطيكم + +34 +00:03:03,440 --> 00:03:07,700 +مثال يعني تخيلوا مثلا انا بهذا الشكل هينعمل chiral + +35 +00:03:07,700 --> 00:03:12,260 +center من اربع شغلاتوأتيت أعمل التفاعل هنا كان + +36 +00:03:12,260 --> 00:03:15,900 +مافيش في إيدي جلم امسكت جلم هل غيرت في اتجاه + +37 +00:03:15,900 --> 00:03:19,480 +الأربع روابط ولا في عند retention of configuration + +38 +00:03:19,480 --> 00:03:23,760 +في عند retention of configuration إذا التفاعل + +39 +00:03:23,760 --> 00:03:28,720 +بعيدا عن ال chiral center بتم في retention of + +40 +00:03:28,720 --> 00:03:31,660 +configuration معنى retention of configuration أن + +41 +00:03:31,660 --> 00:03:36,600 +اتجاهات الروابط الأربع تبقى كما هي لم نكسر شيء + +42 +00:03:36,600 --> 00:03:42,300 +حولهاكذلك الحال هنا احنا حاطين مثال تاني لو فعلنا + +43 +00:03:42,300 --> 00:03:47,740 +هذا المركب يعلن الكايرال سنتر بدلنا هذه ال O H + +44 +00:03:47,740 --> 00:03:51,740 +خلناها C double bond O باستعمال اكسدة ابعام + +45 +00:03:51,740 --> 00:03:53,620 +المؤكسل عادة بنسميه + +46 +00:03:56,470 --> 00:04:01,290 +الان هذول الاربع روابط صار عندهم تغيير و لا تغيير + +47 +00:04:01,290 --> 00:04:06,390 +بعد الكايرالسينفاق بعد اذا كل الاتجاهات تبقى كما + +48 +00:04:06,390 --> 00:04:13,840 +هي CLH CH2 CH3 الـC هادىالتغير بعدها ما كسرت روابط + +49 +00:04:13,840 --> 00:04:16,660 +بالتصيلة بال chiral center مرة تانية في عندي + +50 +00:04:16,660 --> 00:04:20,280 +retention of configuration إذا ال reaction away + +51 +00:04:20,280 --> 00:04:23,160 +from a chiral center results in retention of + +52 +00:04:23,160 --> 00:04:30,000 +configuration الآن بهمني أعطي بس ملاحظة خفيفةالـ + +53 +00:04:30,000 --> 00:04:34,600 +retention of configuration معناه أن الأربع روابط + +54 +00:04:34,600 --> 00:04:39,720 +تبقى في اتجاهاتها ليس له علاقة .. ليس له علاقة + +55 +00:04:39,720 --> 00:04:46,100 +بكلمة R و S أنا هنا و أنا بشتغل كتبت R ولا S ولا + +56 +00:04:46,100 --> 00:04:50,380 +شفت أن ال R دلت R ولا ال S دلت S؟ ماجبتش سيرة + +57 +00:04:50,380 --> 00:04:55,100 +هالكلام، ليش؟ لأنه أنا لما بغير مجموعة هنا أو هنا + +58 +00:04:55,100 --> 00:05:02,890 +ممكن الأولويات تتغير؟ أكيدأكيد حتى لو غيرت مجموعة + +59 +00:05:02,890 --> 00:05:06,790 +بعيد ممكن يصير فيه تغيير بالأولويات و لذلك ممكن R + +60 +00:05:06,790 --> 00:05:11,430 +عند الضل R ممكن R تصير S ممكن S تصير R ممكن S تظل + +61 +00:05:11,430 --> 00:05:16,370 +S أو تتقلب إلى R هذا موضوع ما درسته انا اطلاقا انا + +62 +00:05:16,370 --> 00:05:21,650 +بدرس الأربع روابط في اتجاهاتهم فيهم تغيير ولا لأ + +63 +00:05:21,650 --> 00:05:26,020 +هى معناه retention of configuration الان R و Sمن + +64 +00:05:26,020 --> 00:05:31,160 +أول و جديد في عندكم اشي اسمه قواعد ترتيب المجموعات + +65 +00:05:31,160 --> 00:05:36,320 +حسب الأولويات واحد اتنين تلاتة اربعة بنرتبهم ضلت + +66 +00:05:36,320 --> 00:05:41,460 +الارار صارت اسم مش مشيء بالنسبة الي واضح الفكرة + +67 +00:05:41,460 --> 00:05:47,200 +فكلمة retention of configurationلا تعني اطلاقا .. + +68 +00:05:47,200 --> 00:05:52,700 +لا تعني اطلاقا ان ال R دلت R او ال S دلت S لأ تعني + +69 +00:05:52,700 --> 00:05:58,520 +ان الأربع روابط ضالهم باتجاههم ال R و ال S اولويات + +70 +00:05:58,520 --> 00:06:01,420 +اللي بيحسب اولويات يشوف حسب المثال اللي عنده + +71 +00:06:01,420 --> 00:06:05,480 +هتلاقوا مثال بتم فيه تغيير مثال بتم مش فيه تغيير + +72 +00:06:05,480 --> 00:06:09,460 +حسب هالمجموعة اللي طلعت و المجموعة اللي اجت هذا + +73 +00:06:09,460 --> 00:06:15,200 +موضوع تاني واضح الفكرة؟وهذا كثير بنسألكم بمعناه + +74 +00:06:15,200 --> 00:06:19,280 +انه هالمعنى كلمة retention of configuration means + +75 +00:06:19,280 --> 00:06:24,420 +are must be are in the product لأ مش ضروري ممكن + +76 +00:06:24,420 --> 00:06:29,400 +تظل ممكن تتغير هذا موضوع و هذا موضوع تاني + +77 +00:06:33,710 --> 00:06:39,030 +هذه تفاعلات بناخدها بعدين بس بنعطيها كأمثلة يعني + +78 +00:06:39,030 --> 00:06:43,710 +هذا تأكسد كحول إلى aldehyde لما ندرس chapter + +79 +00:06:43,710 --> 00:06:49,410 +الكحولات ب chapter 7 بنشرحه الآن بديش أنا أسمي لا + +80 +00:06:49,410 --> 00:06:52,750 +كحول ولا aldehyde أنا قلت ال Canada دي CO single + +81 +00:06:52,750 --> 00:06:57,840 +bond صارت CO double bond غيرت هان ولا لأ؟تستعجلوش + +82 +00:06:57,840 --> 00:07:02,880 +العلم هذا تحول حامض إلى Easter بدلت ال OH ب Oethel + +83 +00:07:02,880 --> 00:07:08,140 +بدرسه ب Chapter 10 مش هو موضوعي غيرت بدي ألغي كل + +84 +00:07:08,140 --> 00:07:13,060 +اللي كاتبه و أكتب XY عشان اترايحيني أعصابي خلت XY + +85 +00:07:13,060 --> 00:07:14,980 +واضح؟ + +86 +00:07:16,500 --> 00:07:21,120 +دائما تتعبوش أنفسكم في الفكرة غير الأساسية بدلت X + +87 +00:07:21,120 --> 00:07:26,760 +بY إيش التفاعل مش مشكلة مش X صارت Y تفاعل general + +88 +00:07:26,760 --> 00:07:31,520 +بدلته بعيدا عن ال chiral center إيش بيظل عنده + +89 +00:07:31,520 --> 00:07:37,960 +retention إنما هدولا التفاعلين كتفصيل بناخدهم في + +90 +00:07:37,960 --> 00:07:43,160 +chapter 7 أو chapter 10 لكن استعانا فيهم كأمثلة + +91 +00:07:45,090 --> 00:07:50,130 +التفاعل التالت generation of a second chiral + +92 +00:07:50,130 --> 00:07:54,370 +center يعني لاحظوا احنا اول مرة قولنا ماكنش لنا + +93 +00:07:54,370 --> 00:07:57,390 +chiral center نهائي و عملنا له generation، شو طلع + +94 +00:07:57,390 --> 00:08:04,840 +عندى؟ رسمic mixtureتاني تفاعل لما اعملت تفاعل بعيد + +95 +00:08:04,840 --> 00:08:08,320 +عن الكايرال سنتر شو صار عندى retention of + +96 +00:08:08,320 --> 00:08:13,880 +configuration طيب الآن لو كان في عندى كايرال سنتر + +97 +00:08:13,880 --> 00:08:19,160 +اول و بدى اعمل كايرال سنتر تاني شو بده يصير عندى؟ + +98 +00:08:19,160 --> 00:08:25,120 +خلّينا نشوف مثال هذه مثال لو طلعنا على هذا المركب + +99 +00:08:25,120 --> 00:08:29,880 +الآن هذه الكاربون اللى موجودة هنا بتحمل مثل + +100 +00:08:29,880 --> 00:08:33,970 +وchloro Hو المجموعة اللي فيها double bond كايرال + +101 +00:08:33,970 --> 00:08:39,290 +سنتر ولا لأ كايرال سنتر انا مش موضوعي اطلاقا هذه + +102 +00:08:39,290 --> 00:08:42,770 +ال carbon بدي اعمل التفاعل على ال double bond يعني + +103 +00:08:42,770 --> 00:08:48,160 +على ال double bond بدي اجي اضيف hbr في وجودH plus + +104 +00:08:48,160 --> 00:08:53,940 +هذه أخدناها إضافة Markovnikov يعني بدأ أحط ال H + +105 +00:08:53,940 --> 00:09:00,080 +هنا في الأول أبدأ تفاعل بإضافة ال H هنا وبعدين + +106 +00:09:00,080 --> 00:09:06,260 +أكمل ال PR على هذا الموقع لاحظوا إيش اللي بدو يصير + +107 +00:09:06,260 --> 00:09:12,060 +عندي لما أضيف ال H على هذا الموقع كام رابط هيظل + +108 +00:09:12,060 --> 00:09:20,250 +على هذه النقطة تلت روابط تلت روابطحاولوا تستحضروا + +109 +00:09:20,250 --> 00:09:24,510 +الشكل مع الهيدروجين المحذوف مع الهيدروجين المحذوف + +110 +00:09:24,510 --> 00:09:30,210 +أعطيكم H هاي + +111 +00:09:30,210 --> 00:09:35,830 +الشكل الكامل واضح؟ لما أضيف هنا H هذا الكربون بدل + +112 +00:09:35,830 --> 00:09:41,630 +ما يكون CH2 ماذا سيحصل؟ CH3 سيحصل CH3 و ال double + +113 +00:09:41,630 --> 00:09:48,850 +bond هذه ستذهب علىأساس أنه هيجي يخجم عندي هنا PR + +114 +00:09:48,850 --> 00:09:53,270 +في الخطوة التالية الآن لاحظوا معي لو اتطلعنا على + +115 +00:09:53,270 --> 00:09:58,450 +هذا الجزء هذا الجزء يا ترى هل احنا بنشتغل قريب عنه + +116 +00:09:58,450 --> 00:10:04,430 +ولا بالنسبة له بنشتغل reaction away from a chiral + +117 +00:10:04,430 --> 00:10:08,290 +center away from a chiral center وعشانك بنحطه زي + +118 +00:10:08,290 --> 00:10:10,630 +ما هو لاحظوا إيش معناه retention of configuration + +119 +00:10:10,630 --> 00:10:14,750 +المثل اللي فوق ال CL على اليمين ال H على الشمالهذا + +120 +00:10:14,750 --> 00:10:19,010 +retention of configuration ولا لأ؟ الآن هذه النقطة + +121 +00:10:19,010 --> 00:10:27,690 +هي النقطة اللي هنا ال CH2 شو صارت؟ CH3 و هذه ما + +122 +00:10:27,690 --> 00:10:35,090 +زالت H و الآن أنا بانتظار ال PR لما نيجي نطلع + +123 +00:10:35,090 --> 00:10:38,130 +حوالين هذه ال carbon ايش الشكل؟ + +124 +00:10:40,850 --> 00:10:46,950 +بناء على ذلك بنتوقع ان ال PR بإمكانها تهجم من + +125 +00:10:46,950 --> 00:10:51,010 +الجهتين زي ما أخذنا في أول مرة لما درسنا ال + +126 +00:10:51,010 --> 00:10:53,950 +generation of a chiral center بمعنى ال PR ممكن + +127 +00:10:53,950 --> 00:10:58,830 +تيجي من هنا و ال PR ممكن تيجي تهاجي من هنا إذا كام + +128 +00:10:58,830 --> 00:11:03,070 +ناتج بدو يطلع عندى هى ال PR إذا إجت من هذا الاتجاه + +129 +00:11:03,070 --> 00:11:09,380 +و هى ال PR إذا إجت من الاتجاه التالفزي لما درسنا + +130 +00:11:09,380 --> 00:11:12,600 +اول مرة الـ Chiral Center تقولنا عندنا بلانر + +131 +00:11:12,600 --> 00:11:18,100 +انترميديت تم التفاعل من ايه؟ من الجهتين الان هنا + +132 +00:11:18,100 --> 00:11:22,180 +في عند بلانر انترميديت اتكونت نتيجة انه ضفت اتش + +133 +00:11:22,180 --> 00:11:29,780 +لغية ال bubble bond التفاعل بإمكانه تم من الجهتينو + +134 +00:11:29,780 --> 00:11:35,340 +بناء على ذلك كام ناتج يطلع عنده؟ اتنين بيفرق عن + +135 +00:11:35,340 --> 00:11:40,880 +المثال الأول بشغل واحدة انه هل يترى الاحتمالات + +136 +00:11:40,880 --> 00:11:44,860 +متساوية ان هذا ييجي عن اليمين او عن الشمال في + +137 +00:11:44,860 --> 00:11:48,960 +generation of a first chiral center كنا نقول + +138 +00:11:48,960 --> 00:11:54,000 +الاحتمالات بتكون متساوية و بناء على ذلك يطلع عنده + +139 +00:11:55,740 --> 00:12:01,120 +الان بسبب وجود الكايرال سنتر الاول اللى بيخل + +140 +00:12:01,120 --> 00:12:06,400 +الفراغات حوالين هذا الكاربون غير متساوية مابيكونوش + +141 +00:12:06,400 --> 00:12:13,720 +الاحتمالين بنفس المقدار فبتم صحيح هجوم من الجهتين + +142 +00:12:13,720 --> 00:12:20,570 +ولكن ليسبنسب متساوية يعني مابيجيش 50% من التفاعل + +143 +00:12:20,570 --> 00:12:24,430 +من هنا و 50% من التفاعل من هنا ليش هذا الكلام + +144 +00:12:24,430 --> 00:12:30,240 +امتنع؟بسبب وجود ال chiral center اللي بيخلي جهة + +145 +00:12:30,240 --> 00:12:35,240 +أحيانا مغلقة أكتر من الجهة التانية بيصير فيه فرق + +146 +00:12:35,240 --> 00:12:40,180 +بالوسع زي إنسان كان عنده مسارين متساويين تماما + +147 +00:12:40,180 --> 00:12:44,520 +بيمكنه يمشي من هنا و من هنا الآن إجا شيء سكر جزء + +148 +00:12:44,520 --> 00:12:50,520 +من مسار معين بيضلوا يمشي بنفس النسبة ولا غالبا + +149 +00:12:50,520 --> 00:12:55,530 +بيروح على المسار الأكتر يعني ساعة و فراغواضح + +150 +00:12:55,530 --> 00:13:00,610 +الفكرة؟ الآن شو اللي خلّى عدم التساوي؟ الكايرال + +151 +00:13:00,610 --> 00:13:04,450 +سنتر الأول الكايرال سنتر الأول بيخلّى عدم تساوي + +152 +00:13:04,450 --> 00:13:08,890 +إذا لو أنا اتطلعت الآن على هدول الناتجين اللي + +153 +00:13:08,890 --> 00:13:13,610 +طلعوا بنسب متساوي ولا غير متساوية؟ غير متساوية غير + +154 +00:13:13,610 --> 00:13:17,690 +متساوية in unequal amounts وسألت يا تورا ما + +155 +00:13:17,690 --> 00:13:24,530 +العلاقة بين هدول المركبين اللي طلعوا عندهم؟لاحظوا + +156 +00:13:24,530 --> 00:13:30,570 +هذا الجزء و هذا الجزء ايش مالهم صورة بعض في المرأة + +157 +00:13:30,570 --> 00:13:36,450 +و متعاكسة طب و هذا و هذا نفس الشيء إذا المركب كله + +158 +00:13:36,450 --> 00:13:42,110 +صورة بعض و لا لأ إذا بدكم تعملوا باستعمال الرموز + +159 +00:13:42,110 --> 00:13:49,370 +بإمكانكم تعملوا R و S بمعنى نلغي هذه ال edge هعندي + +160 +00:13:49,370 --> 00:13:55,180 +واحد اتنين تلاتة هذه البيانة Rهذه S الانهان ما + +161 +00:13:55,180 --> 00:14:00,540 +اتغيرت ضلت زي ما هي هالكلور و بعدين كربون حملة + +162 +00:14:00,540 --> 00:14:06,460 +برون بعدين اذا هذه ايش S طيب لو اتيت و طلعت هنا + +163 +00:14:06,460 --> 00:14:09,900 +واحد + +164 +00:14:09,900 --> 00:14:14,640 +اتنين R + +165 +00:14:14,640 --> 00:14:21,860 +S هذه واحد اتنين R S + +166 +00:14:24,660 --> 00:14:31,600 +مكتوبها R رجعوهم بهدوء ال R شيء متعاكس وشيء متساوي + +167 +00:14:31,600 --> 00:14:37,740 +اذا هدوله ايش ديستريو مارس ف ال generation of a + +168 +00:14:37,740 --> 00:14:42,920 +second chiral center المحاصلة تبعته it results in + +169 +00:14:42,920 --> 00:14:46,560 +diastereomeric products at different rates بسرعة + +170 +00:14:46,560 --> 00:14:53,300 +مختلفة الأهم منها and inunequal amounts يعني لو + +171 +00:14:53,300 --> 00:14:56,520 +أنا باسألكوا سؤال صح و غلط generation of a second + +172 +00:14:56,520 --> 00:15:00,580 +chiral center results in the stereomeric mixture + +173 +00:15:00,580 --> 00:15:06,440 +or products in equal amounts and unequal amounts + +174 +00:15:06,590 --> 00:15:10,050 +طبعا ليش صار الـ unequal amount؟ because of the + +175 +00:15:10,050 --> 00:15:14,750 +presence of the first chiral center وجود ال chiral + +176 +00:15:14,750 --> 00:15:19,390 +center الأول خلّى احتمالات الهجوم من الجهتين غير + +177 +00:15:19,390 --> 00:15:22,770 +متساوي يعني الوسع اللي موجود من الجهة بختلف عن + +178 +00:15:22,770 --> 00:15:25,370 +الوسع اللي موجود من الجهة التانية الآن ذرة بدأت + +179 +00:15:25,370 --> 00:15:29,370 +تتفاعل التفاعل هو هجوم، ذرة ماشية و بدأت تيجي الآن + +180 +00:15:29,370 --> 00:15:31,850 +دايما اللي بدو يروح، يروح من المنطقة الواسعة ولا + +181 +00:15:31,850 --> 00:15:39,690 +الديقة؟ من المنطقة الواسعة، واضح؟هذا المحصلة + +182 +00:15:39,690 --> 00:15:44,370 +بالنسبة لعملية generation of a chiral center وزي + +183 +00:15:44,370 --> 00:15:48,650 +ما لاحظته ان هذا التفاعل بيدمج التفاعلين السابقين + +184 +00:15:48,650 --> 00:15:53,490 +يعني بالنسبة لهذا هو تفاعل بعيد عنه ولذلك هذا + +185 +00:15:53,490 --> 00:15:58,870 +الجزء ايش ماله؟ ضال في retention of configuration + +186 +00:15:58,870 --> 00:16:04,250 +وال generation of a chiral center تمهن ولكن بنسبة + +187 +00:16:04,250 --> 00:16:05,990 +غير متساوية + +188 +00:16:07,980 --> 00:16:11,920 +بهيك احنا بننتهي من chapter ال stereochemistry في + +189 +00:16:11,920 --> 00:16:15,120 +عندكم slide عن resolution of enantiomers اتكلمنا + +190 +00:16:15,120 --> 00:16:19,500 +عنها اللي هي فصل ال enantiomers لو حضرناهم كخليط + +191 +00:16:19,500 --> 00:16:24,060 +متساوي وقولنا ان هذه العملية بكل الأحوال مش عملية + +192 +00:16:24,060 --> 00:16:30,580 +سهلة يمكن ان تعمل بعدة طرق فنية في المختبرات لكن + +193 +00:16:30,580 --> 00:16:36,120 +بتاخد وقت ومش عملية سهلة والافضل من resolution of + +194 +00:16:36,120 --> 00:16:42,550 +enantiomersأما أن أخد المركب نقي من الطبيعة أو + +195 +00:16:42,550 --> 00:16:46,930 +الاحتمال التاني لو و لابد في المختبر ان اعمل + +196 +00:16:46,930 --> 00:16:51,710 +asymmetric synthesis انتبهوا معي لو بدأ اقول ايش + +197 +00:16:51,710 --> 00:16:58,110 +افضل اشي للوصول للمركبات النقية نمرة واحد من ال + +198 +00:16:58,110 --> 00:17:04,230 +nature الطبيعة بتعطينا مركبات نقية نمرة اتنين ان + +199 +00:17:04,230 --> 00:17:10,070 +اعملasymmetric synthesis يعني أعمل synthesis + +200 +00:17:10,070 --> 00:17:18,670 +يعطيني واحد أكتر من التاني نمرة تلاتة أن أعمل ال + +201 +00:17:18,670 --> 00:17:21,950 +synthesis اللي حكينا اللي بيطلعوا التنين متساويات + +202 +00:17:21,950 --> 00:17:26,890 +في اللي إيش اسمه symmetric synthesis لكن ال + +203 +00:17:26,890 --> 00:17:31,650 +symmetric synthesis إيش بدوا يتبعوه؟Symmetric + +204 +00:17:31,650 --> 00:17:36,050 +Synthesis هذا يجب ان يتبع Resolution لان افصلهم + +205 +00:17:36,050 --> 00:17:41,430 +بتجارب صعبة الانزيمات + +206 +00:17:41,430 --> 00:17:48,760 +في ال nature ال catalystsبمواصفات معينة عادة كيرال + +207 +00:17:48,760 --> 00:17:53,500 +كتاليست في الطريقة التانية يعني اللي بيساعد على ان + +208 +00:17:53,500 --> 00:17:57,920 +انا احصل على المركب النقي في ال nature اللي هو ال + +209 +00:17:57,920 --> 00:18:02,820 +enzymes الان اللي بيساعد على ان احصل على ال + +210 +00:18:02,820 --> 00:18:05,880 +asymmetric synthesis يعني يطلعوا مش بنسبة متساوية + +211 +00:18:05,880 --> 00:18:09,280 +واحد اكثر من التاني الى درجة اقترب من النقاوة + +212 +00:18:09,280 --> 00:18:14,360 +احيانا ان انا باستعملكتاليست والكتاليست بيكون + +213 +00:18:14,360 --> 00:18:21,260 +كايرة الكتاليست عادة واضح؟ الان هذه طرق وقاية ليش + +214 +00:18:21,260 --> 00:18:25,000 +بعملها؟ عشان ما اجعش انه طلع عندى خليطه اتغلب + +215 +00:18:25,000 --> 00:18:28,640 +بفاصله لو مامشيش بهذه الطريقة او بهذه الطريقة + +216 +00:18:28,640 --> 00:18:33,220 +اعملت symmetric synthesis خليط متساوي من الاتنين و + +217 +00:18:33,220 --> 00:18:37,980 +اجت بدأ اجع في مشكلة ايش؟فصل الخليط يعني الخليط + +218 +00:18:37,980 --> 00:18:42,560 +اللى عندى نفترض R و S بدأ ادخل على عملية الفصل شو + +219 +00:18:42,560 --> 00:18:47,640 +بنسميها الفصل resolution هذه يمكن أن تتم باكثر من + +220 +00:18:47,640 --> 00:18:52,720 +طريقة كيميائية لكن بكل الأوقات ما تفكروش أنها + +221 +00:18:52,720 --> 00:18:57,080 +طريقة سهلة طريقة صعبة يعني أحيانا انتوا بيكونوا + +222 +00:18:57,080 --> 00:19:02,860 +التخيل عندكمانه شغلة صعبة يعني بدي اخد مختبر بدل + +223 +00:19:02,860 --> 00:19:07,300 +ما يكون ساعتين يكون تلت ساعات وانتهي ان انا فصلت + +224 +00:19:07,300 --> 00:19:11,020 +المادة لأ لما انا بقول ال resolution of + +225 +00:19:11,020 --> 00:19:15,520 +enhancements عملية صعبة يعني واحد باحث بيشتغل وطلع + +226 +00:19:15,520 --> 00:19:20,340 +عنده mix chart و بده يبدأ يفصل فيه ممكن الأمور معه + +227 +00:19:20,340 --> 00:19:23,640 +اذا بدأ من نقطة الصفر وماعندهش اي فكرة على الموضوع + +228 +00:19:23,640 --> 00:19:28,770 +يبدأ تجارب تاخد سنةمش بحكي عن ساعتين و تلاتة و + +229 +00:19:28,770 --> 00:19:34,410 +أربعة لأ بحكي عن سنة و أكتر كمان من سنة ليست عملية + +230 +00:19:34,410 --> 00:19:50,430 +سهلة في الوضع الطبيعي ابهيك + +231 +00:19:50,430 --> 00:19:54,930 +بنكون طبعا خلصنا هذا ال chapter اللي اسمه + +232 +00:19:58,800 --> 00:20:04,620 +استيريو كيميستري وبننتقل + +233 +00:20:04,620 --> 00:20:11,960 +مباشرة الى فصل اخر هذا الفصل الاخر بدنا ناخده نوعا + +234 +00:20:11,960 --> 00:20:19,910 +ما باختصار .. نوعا ما باختصار عنوانه الكلهيلايزو + +235 +00:20:19,910 --> 00:20:24,950 +طبعا ال الكلهليتز المجموعة هذه من المركبات لها + +236 +00:20:24,950 --> 00:20:30,870 +تفاعلين substitution and elimination تفاعل الإبدال + +237 +00:20:30,870 --> 00:20:37,980 +وتفاعل الحدث بالنسبة ل الكلاعرفنا إيش يعني الكل؟ + +238 +00:20:37,980 --> 00:20:44,860 +مجموعة الكل مثل و إثل و بربل و كل شيء مأخوذ من ال + +239 +00:20:44,860 --> 00:20:50,260 +الكلس سواء له اسم و لا مالوش اسم و الهيليدز متصل + +240 +00:20:50,260 --> 00:20:57,300 +بهالوجين كلور بروم يود فلور أحيانا فال الكلهيليدز + +241 +00:20:57,300 --> 00:21:03,750 +ببساطة هم ال الكلس المتصلين بهالوجينيعني لو اجينا + +242 +00:21:03,750 --> 00:21:08,130 +و قولنا هذا المركب يا تورا و كتبنا هنا PR عبارة عن + +243 +00:21:08,130 --> 00:21:14,170 +إيش الكل هيلايد لأن هذا الجزء الكن و هذا الجزء + +244 +00:21:14,170 --> 00:21:18,250 +الهالوجين و عشان ذلك مرات بيسموها أي معنى الكل + +245 +00:21:18,250 --> 00:21:22,030 +هيلايد في جزء الكن و جزء الهالوجين عشان ذلك مرات + +246 +00:21:22,030 --> 00:21:28,870 +بيسموهم الهالوجينو الكنز الكل هيلايد او الهالوجينو + +247 +00:21:28,870 --> 00:21:32,490 +الكنز نفس الفكرة تماما + +248 +00:21:38,950 --> 00:21:43,570 +الان زي ما حكيت ال الكلهيلايتز بيسموهم مرات + +249 +00:21:43,570 --> 00:21:48,410 +الهالوجينوالكينز او هالوالكينز فسواء قرأنا العنوان + +250 +00:21:48,410 --> 00:21:53,170 +الكلهيلايتز او هالوجينوالكينز او هالوالكينز هو ال + +251 +00:21:53,170 --> 00:21:58,300 +cane حاملالهالوجين البساطة مش مشكلة كبيرة فال + +252 +00:21:58,300 --> 00:22:02,040 +الهالوجين محتوى الهالوجين اتوم و الهالوجين اتوم + +253 +00:22:02,040 --> 00:22:06,020 +معروفين بالنسبة لنا فلورين و كلورين و برومين و + +254 +00:22:06,020 --> 00:22:08,620 +ايودين متصلين ب الهالوجروم + +255 +00:22:11,830 --> 00:22:16,410 +الالكالهيلايتز ممكن ان نصنفهم احنا الى primary و + +256 +00:22:16,410 --> 00:22:19,890 +secondary و tertiary الكلهيلايتز هذا المصطلح + +257 +00:22:19,890 --> 00:22:23,770 +بيفيدنا اثناء ما بنشرح عن الموضوع ايش بنقصد احنا + +258 +00:22:23,770 --> 00:22:27,490 +بال primary و ال secondary و ال tertiary او باللغة + +259 +00:22:27,490 --> 00:22:32,170 +العربية اولي و ثانوي و ثالثي ال primary و ال + +260 +00:22:32,170 --> 00:22:35,790 +secondary و ال tertiary الكلهيلايتز باجي انا على + +261 +00:22:35,790 --> 00:22:39,430 +ذرة الكربون اللى حاملة ال halogen يعني هذا الكربون + +262 +00:22:39,430 --> 00:22:45,830 +اللى حاملة ال halogenمتصلة بكم كاربون؟ اذا متصلة + +263 +00:22:45,830 --> 00:22:50,610 +بكاربون واحدة بقول عنها primary لحظة ايه الكاربون + +264 +00:22:50,610 --> 00:22:54,950 +اللي حاملة الهالوجين متصلة بكم كاربون واحدة اذا + +265 +00:22:54,950 --> 00:22:58,170 +بقول عنها primary طبعا الناس الشاطرين بيصيروا + +266 +00:22:58,170 --> 00:23:02,530 +يفهموها يعني بشكل سهل بيقولوا لو الكاربون اللي + +267 +00:23:02,530 --> 00:23:08,540 +حاملة الهالوجين كانت CH2لاحظوا CH2 و ال PR هي تلات + +268 +00:23:08,540 --> 00:23:13,000 +روابط إذا كده يظل متصلة مع واحدة هذا ال primary + +269 +00:23:13,000 --> 00:23:19,140 +فاللي بيميز ال primary وجود ال CH2 هالوجينالان ال + +270 +00:23:19,140 --> 00:23:24,540 +secondary الكربون اللى حامله ال halogen هى هى هذه + +271 +00:23:24,540 --> 00:23:27,380 +الكربون اللى حامله ال halogen متصلة بكم كربون؟ + +272 +00:23:27,380 --> 00:23:31,000 +تنتين تنتين بقول عنها ال secondary الان ايش بيكون + +273 +00:23:31,000 --> 00:23:36,600 +موجود فيها؟ CH يعني كأنه ال primary CH2 halogen ال + +274 +00:23:36,600 --> 00:23:43,960 +secondary CH halogen لو اجيت على ال tertiaryC + +275 +00:23:43,960 --> 00:23:49,220 +متصلة بالهالوجين طب و التلاتة روابط التانية متصلين + +276 +00:23:49,220 --> 00:23:54,600 +بالكاربون هاي C متصلة بالهالوجين و بعد هيك رابطة + +277 +00:23:54,600 --> 00:23:58,120 +تنتين تلاتة متصلة بالكاربون هذا النوع من ال + +278 +00:23:58,120 --> 00:24:02,340 +الكلهيلايتش شو بسمي انا tertiary alkyl halides + +279 +00:24:02,340 --> 00:24:06,040 +فإذا قلنا او رسمنا اي الكلهيلايت و قلنا عنه + +280 +00:24:06,040 --> 00:24:09,400 +primary او secondary او tertiary بفترض ان هذه + +281 +00:24:09,400 --> 00:24:17,540 +الشغلة تكون واضحةعشان نفهم الـ Alkyl Halides محور + +282 +00:24:17,540 --> 00:24:22,220 +الـ Alkyl Halides هو رابطة الـ Carbon-Halogen يعني + +283 +00:24:22,220 --> 00:24:27,180 +بين الـ Carbon والـ X الـ Halogen في عنده رابطة + +284 +00:24:28,310 --> 00:24:32,150 +الان بدي افهم هذه الرابطة جيدا لان التفاعلات + +285 +00:24:32,150 --> 00:24:37,330 +هيعتمد على هذه الرابطة ال carbon halogen bond جزء + +286 +00:24:37,330 --> 00:24:41,990 +من فهم هذا الموضوع ان اشوف فرق السالبية هنا هل + +287 +00:24:41,990 --> 00:24:47,310 +يترى هذه الرابطة polar ولا non polar عشان اشوف + +288 +00:24:47,310 --> 00:24:53,550 +الرابطة جيدا بدي اشوف ايش السالبية للكربون الكربون + +289 +00:24:53,550 --> 00:24:58,350 +سالبيته اتنين ونصال carbon ايش السالبية تبعته + +290 +00:24:58,350 --> 00:25:05,330 +اتنين و نص الان ال halogens كم واحد اه لاحظوا + +291 +00:25:05,330 --> 00:25:16,670 +floor سالبيته قداش اربعة و بروم تلاتة floor + +292 +00:25:16,670 --> 00:25:19,750 +تلاتة + +293 +00:25:19,750 --> 00:25:21,590 +بروم + +294 +00:25:23,000 --> 00:25:29,680 +2.8 و اليود 2.5 لاحظوا اليود و الكربون فيهم فرق + +295 +00:25:29,680 --> 00:25:34,620 +سالبية إذا الرابطة بشكل عام non polar مافيش فرق + +296 +00:25:34,620 --> 00:25:40,320 +سالبية الكربون 2.5 و اليود 2.5 لكن بعد ذلك مع + +297 +00:25:40,320 --> 00:25:45,140 +البروم و الكلور و الفلور في فرق سالبية لمصلحة + +298 +00:25:45,140 --> 00:25:50,080 +الهالوجين إذا بشكل عام مع هذول الذرات كيف بنتوقع + +299 +00:25:50,080 --> 00:25:57,150 +ال polarity للرابطة تكونإن الكربون تكون موجبة + +300 +00:25:57,150 --> 00:26:05,090 +والهالوجين سالبة واضح؟ أكبر فرق وين موجود؟ مع ال + +301 +00:26:05,090 --> 00:26:11,910 +floor أقل فرق العدم مع اليود الأن لاحظوا معي كل ما + +302 +00:26:11,910 --> 00:26:16,390 +كان الفرق كبير كل ما جربت الرابط تشبه الرابط + +303 +00:26:16,390 --> 00:26:20,890 +الأيونية بمعنى أخر بتصير أقوىو بناء على ذلك لو انا + +304 +00:26:20,890 --> 00:26:25,270 +بدى اشوف قوة هذه الروابط اللى هى مع ال flour و ال + +305 +00:26:25,270 --> 00:26:29,330 +brom و ال chlor و ال iod هلاحظ انه و اقارنها بقوة + +306 +00:26:29,330 --> 00:26:32,750 +رابطة ال carbon-H اللى هى تعتبر بلغة الكيميا رابطة + +307 +00:26:32,750 --> 00:26:38,930 +قوية و مش سائل تنقصت ال carbon-H 413 كيلوجول لكل + +308 +00:26:38,930 --> 00:26:42,910 +مول بدى عشان اكسر هذه الرابطة الان ال carbon-flour + +309 +00:26:42,910 --> 00:26:48,150 +اقوى منهاليش؟ لأن فرق ال polarity عالي صارت تشبه + +310 +00:26:48,150 --> 00:26:52,990 +رابطة ايونية قوية ال carboniclor 346 ال + +311 +00:26:52,990 --> 00:26:59,910 +carboniclor 290 ال carboniclor 228 أقوى واحدة فيهم + +312 +00:26:59,910 --> 00:27:06,670 +مين؟ مع ال fluor الآن جزء أساسي في بناء الكيميا + +313 +00:27:06,670 --> 00:27:09,850 +تبع ال alkyl halides ان انا بدي أكسر الرابطة هذه + +314 +00:27:09,850 --> 00:27:15,000 +اللي بين ال carbon و ال halogenيعني سواء في تفاعل + +315 +00:27:15,000 --> 00:27:20,020 +الإبدال أو الحذف، هذه الرابطة بدها تنكسر طيب ال + +316 +00:27:20,020 --> 00:27:23,480 +floor رابطته قوية؟ صعب، صعب، صعب، صعب، صعب، صعب، + +317 +00:27:23,480 --> 00:27:24,200 +صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، + +318 +00:27:24,200 --> 00:27:24,620 +صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، + +319 +00:27:24,620 --> 00:27:24,820 +صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، + +320 +00:27:24,820 --> 00:27:33,340 +صعب، صعب، صعب، صعب، صعب، صعب، + +321 +00:27:33,340 --> 00:27:41,060 +صعب، صعب، صعب، + +322 +00:27:41,060 --> 00:27:45,880 +صوبناء على ذلك عندما أعمل إبدال و أخد أمثلة على + +323 +00:27:45,880 --> 00:27:50,360 +الإبدال و أعمل حذف و في التفاعلين الإبدال و الحذف + +324 +00:27:50,360 --> 00:27:56,800 +تكسر فيه رابطة الأمثلة اللي هشوفها كلور بروم يود + +325 +00:27:56,800 --> 00:28:01,880 +مش هشوف أمثلة على ال floor لأن ال floor رابطة قوية + +326 +00:28:01,880 --> 00:28:06,380 +صعب كسرها وبناء على ذلك تفاعلات الإبدال و الحذف + +327 +00:28:06,380 --> 00:28:11,010 +مرتبطة بدول التلاتة ال floor برا الموضوعواضح + +328 +00:28:11,010 --> 00:28:17,150 +الفكرة؟ الآن + +329 +00:28:17,150 --> 00:28:22,890 +طالما احنا بنقول بدنا نكسر الرابط مع ال halogen + +330 +00:28:22,890 --> 00:28:28,230 +أني أضعف رابط فيهم اليود بناء على ذلك لو انا بعمل + +331 +00:28:28,230 --> 00:28:33,530 +تفاعل مع اليود بيكون سهل ولا صعب؟ سهل جداالبروم + +332 +00:28:33,530 --> 00:28:37,350 +بقعده في السهولة الكلور بقعده وعشان هيك لو انا بدى + +333 +00:28:37,350 --> 00:28:40,990 +اشوف ال rate of reaction لو كنت بفعل يود وبروم + +334 +00:28:40,990 --> 00:28:46,270 +وكلور مقارنة بعض و بالبعض أسرع تفاعل مع اليود أسرع + +335 +00:28:46,270 --> 00:28:51,580 +من البروم أسرع من الكلورلكلور والسبب قوة الرابطة + +336 +00:28:51,580 --> 00:28:56,100 +لأن هنا في رابطة ضعيفة بتنكسر بسهولة واضح الرابطة + +337 +00:28:56,100 --> 00:29:00,340 +مع اليود رابطة ضعيفة بتنكسر بسهولة يمكن هذا الكلام + +338 +00:29:00,340 --> 00:29:04,100 +حتى في الحياة العملية بتلاحظوا حتى في الحياة + +339 +00:29:04,100 --> 00:29:09,320 +العملية بتلاحظوا كثير من الأدوية مثلا موجود مكون + +340 +00:29:09,320 --> 00:29:15,660 +أساسي منها اليود هذه الأدوية لو اتعرضت لشوية حرارة + +341 +00:29:15,660 --> 00:29:20,980 +بسيطة أو لضوء الشمسبتنكسر الرابطة اللي معاليه طبعا + +342 +00:29:20,980 --> 00:29:24,240 +كنا انكسرت الرابطة إذا الدواء كله إيش صار فيه؟ خير + +343 +00:29:24,240 --> 00:29:28,680 +وعشان هيك هنلاحظ أن هذا النوع من الأدوية بيحطوه في + +344 +00:29:28,680 --> 00:29:33,800 +جزايز غامقة لونها بني وغالبا بيحفظوه بعيدا عن + +345 +00:29:33,800 --> 00:29:38,930 +الضوء و الحرارة و أحيانا في حرارة باردةيعني شوف + +346 +00:29:38,930 --> 00:29:43,690 +كيف لما مراتب تقرأ على شيء معين يحفظ بعيدا عن + +347 +00:29:43,690 --> 00:29:46,730 +الضوء و الحرارة ليش؟ بيكون هذا الشيء المعين فيه + +348 +00:29:46,730 --> 00:29:52,790 +روابط ضعيفة حتى حرارة الجو حتى على ضو الشمس ممكن + +349 +00:29:52,790 --> 00:29:58,410 +تتكسر فبنصير نحط مثلا جزاز بن يمنع أنه يدخل الضوء + +350 +00:29:58,410 --> 00:30:02,030 +بشكل كبير بنقبل حطه بعيد عن الضوء و عن الحرارة + +351 +00:30:02,030 --> 00:30:06,870 +ممكن يحتفظ فيهبالتلاجة على سبيل المثال كل هذا + +352 +00:30:06,870 --> 00:30:12,670 +نتيجة فهم قوة الروابط الكيميائية و دائما انتوا + +353 +00:30:12,670 --> 00:30:16,630 +يعني جزء منكوا في علوم الصحة و جزء في غيرها لحتى + +354 +00:30:16,630 --> 00:30:20,190 +تتعاملوا مع أدوى او اشياء اول ما بدكوا تمسكوا اي + +355 +00:30:20,190 --> 00:30:28,090 +عبو الدواء شغلتين الشيء الاول صحتكماقرأوا الكلام + +356 +00:30:28,090 --> 00:30:33,550 +اللي عليها، ضار، سام، يجوز أن نشمه، لا يجوز، كل + +357 +00:30:33,550 --> 00:30:38,050 +هذا الكلام مكتوب على العبوة ويله إشارات معينة، + +358 +00:30:38,050 --> 00:30:42,230 +بيحرق كوروسف مثلا زي أحماض إذا انكبت على الإيد + +359 +00:30:42,230 --> 00:30:46,200 +بتحرقها، إذا انكبت على الملابس بتحرقهامنفعش + +360 +00:30:46,200 --> 00:30:49,400 +الإنسان يتعامل مع أشياء و هو مش عارفها يكون + +361 +00:30:49,400 --> 00:30:55,240 +بيتعامل مع سم و بيسيبه ينكب على إيده و مابيغسلش و + +362 +00:30:55,240 --> 00:31:00,040 +مابياخدش احتياطات ولا بيلبس gloves ولا أي شيء و + +363 +00:31:00,040 --> 00:31:06,940 +شغلت تانية بيكون مكتوب عندكم كلمة storeاحفظه وانت + +364 +00:31:06,940 --> 00:31:12,160 +احفظه طبعا شغل اضافية بيكون عندكوا expire date انه + +365 +00:31:12,160 --> 00:31:16,120 +هذا بعد فترة معينة ما تفتحوه بيخرب بالذات كتير + +366 +00:31:16,120 --> 00:31:20,800 +مركبات بيكون مسكر عليها بشكل محكم لكن لما تفتحوها + +367 +00:31:20,800 --> 00:31:26,970 +تتفعل مع oxygen الهواءممكن تتفاعل مع الهوى نفسه أو + +368 +00:31:26,970 --> 00:31:31,370 +تمتص رطوبة من الهوى وبناء على ذلك تخرب فهتلاحظوا + +369 +00:31:31,370 --> 00:31:35,990 +بعض المراكبات مكتوب عليها لا يستعمل بعد أسبوع أو + +370 +00:31:35,990 --> 00:31:41,050 +أسبوعين من فتح العبوة كل إنسان بدي يتعامل بأدوية + +371 +00:31:41,050 --> 00:31:45,050 +أو pre agents بدي يكون منتبه لهذه الأمور وإلا + +372 +00:31:45,050 --> 00:31:47,470 +بيجعل بإيش؟ بالغلط + +373 +00:31:51,720 --> 00:31:57,640 +الان لو اجينا على التفاعلات تبعت ال alkyl halides + +374 +00:31:57,640 --> 00:32:04,320 +ممكن البعض يقول طب احنا ما أعطيناش التسمية مشعلة + +375 +00:32:04,320 --> 00:32:09,760 +جديدة مرت عليكم لما أخدنا ال alkenes يعني لو انا + +376 +00:32:09,760 --> 00:32:15,600 +جبتلكوا هذا المركب هذا + +377 +00:32:15,600 --> 00:32:22,830 +ال alkyl halide مين تسميه؟احد اتنين تلاتة اربعة + +378 +00:32:22,830 --> 00:32:30,340 +خمسة بنتين اثنان كلورو اثنان مثل بنتينأخدنا + +379 +00:32:30,340 --> 00:32:36,180 +التسمية ولا لأ؟ أخدنا التسمية طيب واحدة بتقول ماشي + +380 +00:32:36,180 --> 00:32:40,800 +التسمية أخدناها طيب و ال preparation التحضير هو + +381 +00:32:40,800 --> 00:32:45,220 +احنا عادة لما بندرس عائلة كيميائية اول اشي بنتعرف + +382 +00:32:45,220 --> 00:32:49,420 +على العائلة بعدين بناخد ال nomenclature التسمية + +383 +00:32:49,420 --> 00:32:54,500 +بعدين التحضير بعدين التفاعلات احنا عمال جاعدين + +384 +00:32:54,500 --> 00:33:00,060 +بنفض جزءالتسمية وشوفنا أننا أخدناها طب و جزء + +385 +00:33:00,060 --> 00:33:04,800 +التحضير أخدناها + +386 +00:33:04,800 --> 00:33:09,420 +من أكثر من طريقة أخدناها بأكثر من طريقة لما كنا + +387 +00:33:09,420 --> 00:33:13,220 +نيجي نقولكم مثلا ابرو بيل و اعملوله chlorination + +388 +00:33:13,220 --> 00:33:20,960 +شو كنتوا تطلعوا؟One Chloro, Two Chloro مش هذي + +389 +00:33:20,960 --> 00:33:25,680 +Alkyl Halides إذا ال Direct Halogenation طريقة من + +390 +00:33:25,680 --> 00:33:30,500 +طرق التحضير ولا لأ و حلينا عليها أمثلة تأكيد .. + +391 +00:33:30,500 --> 00:33:36,120 +تأكيد لما كنا .. هاي أول طريقة ال Halogenation طب + +392 +00:33:36,120 --> 00:33:42,440 +لو أعطيناكوا هذا المركب و قولنا لكم ضيفوا عليه HBR + +393 +00:33:46,050 --> 00:33:50,770 +هتقولولي مع Markovnikov ولا أنت Markovnikov؟ إذا + +394 +00:33:50,770 --> 00:33:55,510 +Markovnikov بيجي H و PR to Bromo وإذا أنت + +395 +00:33:55,510 --> 00:34:01,390 +Markovnikov H و PR و لا Bromo هذه المركبات مش ال + +396 +00:34:01,390 --> 00:34:06,230 +الهيليتز اللي نتجت الطريقة إذا أخدناها فإيش طروب + +397 +00:34:06,230 --> 00:34:12,210 +تحضير ال الهيليتز؟ نمرة واحد ال halogenation of + +398 +00:34:12,210 --> 00:34:20,960 +alkenesالـ Halogenation طب نمره اتنين ال addition + +399 +00:34:20,960 --> 00:34:29,660 +of HX to الكيين أو الكايين كمان لما كنا نضيف على + +400 +00:34:29,660 --> 00:34:37,360 +الكاين مرتين واضح؟ في طرق تالتة أخدناها في طريق + +401 +00:34:37,360 --> 00:34:42,920 +تالت لو هنا إجينا ضفنا على نفس هذا المركب PR2 + +402 +00:34:46,320 --> 00:34:50,940 +أيش كان يعطيني؟ كان يعمل لي إضافة two PR atoms + +403 +00:34:50,940 --> 00:34:56,800 +بسين ولا ب Anti-addition؟ Anti-addition هيعمل لي + +404 +00:34:56,800 --> 00:35:03,020 +dihalo compound هذه طريقة الإبوكسايد رينج لو + +405 +00:35:03,020 --> 00:35:07,020 +فتحناها برضه بتصير طريقة إذا إحنا أخدنا الحقيقة + +406 +00:35:07,020 --> 00:35:14,730 +أكثر من طريقة لتحضيرالـ Halo Compounds في طريقة + +407 +00:35:14,730 --> 00:35:17,890 +إضافية + +408 +00:35:17,890 --> 00:35:23,610 +غير التلات طرق هدول اللي هم ال ال ال ال ال ال ال + +409 +00:35:23,610 --> 00:35:24,970 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +410 +00:35:24,970 --> 00:35:25,010 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +411 +00:35:25,010 --> 00:35:28,170 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +412 +00:35:28,170 --> 00:35:28,990 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +413 +00:35:28,990 --> 00:35:29,570 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +414 +00:35:29,570 --> 00:35:29,610 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +415 +00:35:29,610 --> 00:35:29,610 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +416 +00:35:29,610 --> 00:35:29,610 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +417 +00:35:29,610 --> 00:35:29,610 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +418 +00:35:29,610 --> 00:35:29,610 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +419 +00:35:29,610 --> 00:35:33,550 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +420 +00:35:33,550 --> 00:35:33,550 +ال ال + +421 +00:35:39,410 --> 00:35:46,970 +بتفاعلها ما عدش X أخليها RX يعني تحويل الكحول إلى + +422 +00:35:46,970 --> 00:35:51,810 +الكلهلايت هذه الطريقة لها تفاصيل كتير لما ندرس + +423 +00:35:51,810 --> 00:35:55,630 +chapter الكحولات بندرس كتفاعل على الكحول يعني + +424 +00:35:55,630 --> 00:36:00,290 +بإمكاننا ندرسها الأن كطريقة للتحضير و بإمكاننا + +425 +00:36:00,290 --> 00:36:05,900 +ندرسها في chapter الكحولات كتفاعل على الكحولواضح؟ + +426 +00:36:05,900 --> 00:36:10,640 +هذا كحول، هذا الكلهلايت، بالنسبة للكحول هي تفاعل، + +427 +00:36:10,640 --> 00:36:14,980 +بالنسبة لالكلهلايت هي طريقة تحضير، لما ندرس + +428 +00:36:14,980 --> 00:36:19,720 +الكحولات و تفاعلاتها، هيكون عندنا تفاعل أساسي + +429 +00:36:19,720 --> 00:36:27,560 +تحويلالكحول إلى ال alkyl halides بمجموعة من + +430 +00:36:27,560 --> 00:36:31,440 +التفاصيل بندرسها بوقته، هاي بتصير كمان طريقة + +431 +00:36:31,440 --> 00:36:39,390 +إضافية لتحضير ال alkyl halidesكام طريقة؟ اربعة مين + +432 +00:36:39,390 --> 00:36:44,790 +تقول اليوم باختصار اتفضلي ال direct halogenation + +433 +00:36:44,790 --> 00:36:48,330 +في وجود الضوء او الحرارة لل ال alkenes اضافة ال X2 + +434 +00:36:48,330 --> 00:36:56,190 +لل ال alkenes او اضافة ال HX + +435 +00:36:56,190 --> 00:37:01,620 +لل ال alkenes او لل ال alkynesو بعدين من الكحولات + +436 +00:37:01,620 --> 00:37:05,900 +في وجود HX او reagents تانية بندرسها في chapter + +437 +00:37:05,900 --> 00:37:10,860 +الكحولات هيصيرنا ذاكرينكوا كم طريقة اربع طرق + +438 +00:37:10,860 --> 00:37:15,380 +لتحضير ال alkyl halides تلاتة أخدتهم و طريقة + +439 +00:37:15,380 --> 00:37:24,180 +بندرسها في chapter الكحولات الآن التفاعل الأساسي + +440 +00:37:24,180 --> 00:37:30,380 +لل alkyl halides هو تفاعلالإبدال التفاعل الأساسي + +441 +00:37:30,380 --> 00:37:34,860 +لـ alkalites هو تفاعل الإبدال لو أنا أتي أتطلع طيب + +442 +00:37:34,860 --> 00:37:38,920 +إيش اللي بده أبدله؟ وكيف بده يتم الإبدال اللي + +443 +00:37:38,920 --> 00:37:44,480 +عندي؟ اتطلعوا هاي عندي carbon حاملة نفترض PR وهنا + +444 +00:37:44,480 --> 00:37:49,400 +في تلت روابط، بلاش نركز عليهم شو هما الآن إيش + +445 +00:37:49,400 --> 00:37:55,520 +اتفقنا على الرابط اللي موجود هنا؟قول لعنها بولا + +446 +00:37:55,520 --> 00:38:02,180 +يعني هذه موجبة وهذه سالبة بناء على ذلك هلاحظ أن + +447 +00:38:02,180 --> 00:38:06,720 +التفاعل الأساسي عندنا لما بناجي المرة الجاية اللي + +448 +00:38:06,720 --> 00:38:10,500 +اتكلم أنه بيجي نيوكليوفايل لإن نيوكليوفايل حامل + +449 +00:38:10,500 --> 00:38:15,840 +إلكترونات وين بيهاجم؟ على الكاربون الموجب يعني هذا + +450 +00:38:15,840 --> 00:38:22,560 +سالب للنيوكليوفايل سالب بيجي إيش بيطلعك باله؟ سالب + +451 +00:38:23,370 --> 00:38:27,830 +السالب هاجم على الكربون الموجب، طرد سالب إجا سالب، + +452 +00:38:27,830 --> 00:38:33,550 +طرد سالب، إجا موجب، طرد موجب أخدنا في البنزين + +453 +00:38:33,550 --> 00:38:38,190 +الإبدال إيش كان؟ موجب مكان موجب، سميناها + +454 +00:38:38,190 --> 00:38:41,950 +Electrophilic Substitution الآن هنا بدو ييجي سالب + +455 +00:38:41,950 --> 00:38:47,030 +مكان سالب، يعني إيش اللي بدو يطرد؟ ال X مع + +456 +00:38:47,030 --> 00:38:52,340 +إلكتروناته، شو اللي بدو يهاجم؟لنيوكليوفايل و بناء + +457 +00:38:52,340 --> 00:38:56,880 +على ذلك بيصير المفروض فينا نتذكر ايش معنى + +458 +00:38:56,880 --> 00:39:01,040 +النيوكليوفايل اللي بدو يهاجم هنا و يحل محل ال X + +459 +00:39:01,040 --> 00:39:06,220 +ولذلك المرة القادمة هنبدأ من كلمة ايش الـ + +460 +00:39:06,220 --> 00:39:11,190 +Eucleophilic Substitution يعني نبدأ نتعرف علىللـ + +461 +00:39:11,190 --> 00:39:14,950 +nucleophile اللي بده يهاجم ويبدأ التفاعل لأن الـ + +462 +00:39:14,950 --> 00:39:18,790 +nucleophile هو السالب اللي بده يهاجم ويحل محل + +463 +00:39:18,790 --> 00:39:23,630 +الهالوجين السالبة يعمل عملية الإبدال شكرا + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..4bf39b1db011da894261ebc4a8aa5e7acc88bb80 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs_postprocess.srt @@ -0,0 +1,2140 @@ +1 +00:00:21,410 --> 00:00:26,010 +بسم الله الرحمن الرحيم بدأنا احنا في محاضرات ماضية + +2 +00:00:26,010 --> 00:00:31,390 +في تفاعلات ال alkanes ويمكن لاحظنا ان الأمر في هذه + +3 +00:00:31,390 --> 00:00:36,690 +المنطقة هو أمر سهل جدا مافيش فيه مشاكل الرابطة + +4 +00:00:36,690 --> 00:00:41,450 +الزوجية من خلال تفاعل الإضافة بتصير رابطة أحدية + +5 +00:00:42,020 --> 00:00:45,740 +الاشياء المتعلقة بهذا التفاعل اللى اتكلمنا عنها + +6 +00:00:45,740 --> 00:00:50,220 +كانت طبيعة ال الكين و طبيعة ال reagent هل ال الكين + +7 +00:00:50,220 --> 00:00:54,400 +symmetric هل ال reagent symmetric و هذا الكلام أدى + +8 +00:00:54,400 --> 00:00:58,140 +إلى انه مرات بيكون في عندنا اضافات حسب قاعدة + +9 +00:00:58,140 --> 00:01:01,760 +Markovnikov او عكس قاعدة Markovnikov حسب طبيعة + +10 +00:01:02,350 --> 00:01:05,850 +التفاعل اللى بنعمله اخر شغل انتهينا عنده في + +11 +00:01:05,850 --> 00:01:11,030 +المحاضرة الماضية انه احنا ايضا ممكن نضيف oxygen + +12 +00:01:11,030 --> 00:01:16,050 +على ال double bond من خلال تفاعل ال alkenes مع ال + +13 +00:01:16,050 --> 00:01:20,030 +bare acids بيعطونا ال epoxides اللى هى الحلقات + +14 +00:01:20,030 --> 00:01:25,510 +الثلاثية اتعلمنا تسميتها بطريقتين سواء ان نسميها + +15 +00:01:25,510 --> 00:01:30,300 +من خلال ان نقولالكين اكسايد نذكر اسم الالكين + +16 +00:01:30,300 --> 00:01:34,720 +الأصلي اللى نتجت منه او من خلال اننا نعتبر ال + +17 +00:01:34,720 --> 00:01:37,360 +parent ring يعني الحلقة الأساسية اللى كلها + +18 +00:01:37,360 --> 00:01:43,720 +هيدروجين اسمها oxirane و الرقم من عند ال oxygen و + +19 +00:01:43,720 --> 00:01:51,200 +نذكر أسماء ال substituents اللى موجودةأيضا ركزنا + +20 +00:01:51,200 --> 00:01:55,660 +على نقطة أن هذه الحلقة الثلاثية هي حلقة مضغوطة is + +21 +00:01:55,660 --> 00:02:00,560 +a strained ring ليش؟ لأن الزوايا فيها ضغطت إلى + +22 +00:02:00,560 --> 00:02:04,720 +الستين الوضع المريح لزاوية ال carbon carbon carbon + +23 +00:02:04,720 --> 00:02:10,020 +او ما شابه مية وتسعة و نص ولذلك أسهل تفاعل فيها + +24 +00:02:10,020 --> 00:02:14,440 +اللي هو تفاعل ال ring opening فاحنا صح بنكون + +25 +00:02:14,440 --> 00:02:20,350 +الحلقةلكن الحلقة strain فلما تتجه تعمل ring + +26 +00:02:20,350 --> 00:02:26,250 +-opening فكرة ال ring-opening كانت مبنية على انه + +27 +00:02:26,250 --> 00:02:31,670 +اذا اتذكرنا احنا ان الاكسجين electronegative اكثر + +28 +00:02:31,670 --> 00:02:35,830 +من الكربون يعني الاكسجين partially negative ال two + +29 +00:02:35,830 --> 00:02:42,210 +carbons هيكونوابارشالة positive فانا لو جبت اي شيء + +30 +00:02:42,210 --> 00:02:46,250 +بده يتفاعل مع الموجب والاصل يكون سالم سمينا + +31 +00:02:46,250 --> 00:02:51,230 +نيوكليوفايل هاجم هنا النتيجة انه هيكسر هذه الرابطة + +32 +00:02:51,230 --> 00:02:55,970 +مش هيصير عنده خمس روابط فلما ييجي اي نيوكليوفايل + +33 +00:02:57,150 --> 00:03:02,150 +هاجم على هذا الكرمون هتنكسر الرابط أزواج + +34 +00:03:02,150 --> 00:03:08,050 +الألكترونات هيكون مع الـ O O minus بياخد H غالبا + +35 +00:03:08,050 --> 00:03:12,890 +الـ H هذه بتكون مع الـ nucleophile فهيصف ايش O H + +36 +00:03:12,890 --> 00:03:17,230 +او احنا بنعمل catalysis للتفاعل بـ H plus يعني + +37 +00:03:17,230 --> 00:03:22,690 +مثلا الميه فيها جزء ايه لو تشوفوا محصلة التفاعل O + +38 +00:03:22,690 --> 00:03:31,120 +H اللي هي تمثللنكليوفاي و في اتش فهذا لنكليوفاي لو + +39 +00:03:31,120 --> 00:03:38,130 +اتفعل من هنا وصف في الآخر انه حط OHL شو ضال عندكH + +40 +00:03:38,130 --> 00:03:42,870 +هتيجي وين؟ على هذه الـ O أو لو أنا كنت عامل acid + +41 +00:03:42,870 --> 00:03:47,530 +catalysis الـ H تبعت ال acid في الأساس هي اللي + +42 +00:03:47,530 --> 00:03:52,410 +بتيجي و بيطلع بدلها H plus لكن كمحصلة كمعادلة + +43 +00:03:52,410 --> 00:03:57,370 +موزونة كمعادلة موزونة لو بتتطلع على هذا المركب لو + +44 +00:03:57,370 --> 00:04:02,580 +بتتطلع على هذا المركباللي أنا بادى فيه وهذا المركب + +45 +00:04:02,580 --> 00:04:07,140 +اللى طلع عندى هتلاحظوا هى ال OH اللى اجت من الميه + +46 +00:04:07,140 --> 00:04:12,700 +وهىالـ H هيصل في ميّه إذا المعادلة بهذا الشكل + +47 +00:04:12,700 --> 00:04:17,460 +موصولة ولا لأ تماما كاربون كاربون أكسوجين وإيجي + +48 +00:04:17,460 --> 00:04:23,800 +عنده من الميّه الـ OH والـ H في كل الأحوال تفاعل + +49 +00:04:23,800 --> 00:04:28,500 +ال ring opening سهل جدا أن نطبقه بدنا نقول أن هذه + +50 +00:04:28,500 --> 00:04:35,720 +الحلقة بدأ تصير CCOH بما تحملهيعني لو كانت هنا + +51 +00:04:35,720 --> 00:04:40,080 +بتحمل H2 وهنا H2، بيظلوا زي ما هما، H و مثل وهنا + +52 +00:04:40,080 --> 00:04:43,820 +H2، بيظلوا زي ما هما، إيش ما بتحمل هنا، هدولة مش + +53 +00:04:43,820 --> 00:04:47,760 +موقع تفاعل، ما بتغيروش، أيًا كانوا، إيش ما + +54 +00:04:47,760 --> 00:04:51,200 +بيكونوا، هدول المجموعات بتغيروش، اللي بيصير عنده C + +55 +00:04:53,120 --> 00:04:58,840 +OH وهنا بدو ييجي عنده لنيوكليوفايل طبعا إذا كان + +56 +00:04:58,840 --> 00:05:05,100 +المتفاعل الماء لنيوكليوفايل OH طب إذا المتفاعل HX + +57 +00:05:05,100 --> 00:05:13,240 +لنيوكليوفايل X إذا المتفاعل RO- هيكون RO وبتيجي H + +58 +00:05:13,240 --> 00:05:18,020 +من هنا بهذا الشكل إذا الشيء المشترك هنا الشيء + +59 +00:05:18,020 --> 00:05:22,580 +المشترك هنا أنه هتشوفوا هذه القطعة + +60 +00:05:25,740 --> 00:05:37,660 +CCOH CCOH CCOH CCOH CCOH + +61 +00:05:37,660 --> 00:05:44,900 +CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH + +62 +00:05:44,900 --> 00:05:49,920 +CCOHأي مجموعات كانت موجودة عليهم اصلا يعني لو كنت + +63 +00:05:49,920 --> 00:05:53,760 +بدي انا في ال parent compound يعني هذه CH2 CH2 + +64 +00:05:53,760 --> 00:06:01,540 +هتكون النتيجة OH CH2 CH2 OH لو هدولة C مثل 2 مثل 2 + +65 +00:06:01,540 --> 00:06:09,100 +هيكون OH C مثل 2 C مثل 2 و هكذا واضح؟ بهذا الشكل + +66 +00:06:09,100 --> 00:06:15,230 +بتم التفاعد ولذلك مرات كتير لما بنشوف عندنالما + +67 +00:06:15,230 --> 00:06:20,510 +بنشوف إنه في تفاعلات موجود CH2 CH2 OH ممكن نفكر إن + +68 +00:06:20,510 --> 00:06:27,150 +هدولة إجوا من حلقة إيش Oxirane حلقة Oxirane CH2 + +69 +00:06:27,150 --> 00:06:31,190 +CH2 OH اتفاعلت مع نيوكليوفايل بيضطر نيوكليوفايل + +70 +00:06:31,190 --> 00:06:39,600 +CH2 CH2واضح؟ طبعا في حالات ممكن المجموعات اللى + +71 +00:06:39,600 --> 00:06:43,480 +موجودة على ال carbon في هدولة النقطين تكون مختلفة + +72 +00:06:43,480 --> 00:06:49,780 +يعني ممكن مثلا تلاحظوا ان هذه تكونسي أتش تو وهنا + +73 +00:06:49,780 --> 00:06:53,700 +سي أتش و سي أتش ثري و بتكون تيجي تفعله الماء + +74 +00:06:53,700 --> 00:06:57,560 +لاحظوا هتصيروا متحيرين هل يا ترى النيوكليوفايل + +75 +00:06:57,560 --> 00:07:01,540 +هتخلوه يتفعل على هذا الكربون و لا على هذا الكربون + +76 +00:07:01,540 --> 00:07:04,600 +من ناحية المبدأ هذا موجبة و هذا موجبة دائما + +77 +00:07:04,600 --> 00:07:08,560 +النيوكليوفايل هتفعل على الكربون اللي بتحمل الكربون + +78 +00:07:08,560 --> 00:07:14,230 +أكثرتعرفوا تصنيفات ال carbon primary و secondary و + +79 +00:07:14,230 --> 00:07:18,090 +tertiary حسب ما بيحمل carbons فالتفاعل على ال + +80 +00:07:18,090 --> 00:07:21,930 +carbon اللي بتحمي ال carbons أكثر بيكون مفضل يعني + +81 +00:07:21,930 --> 00:07:25,090 +في هذه الحالة لو كنا بنفعل ميه هل يا ترى ال O + +82 +00:07:25,090 --> 00:07:28,550 +هتيجي تهاجم على هذا ال carbon ولا هذا ال carbon و + +83 +00:07:28,550 --> 00:07:35,650 +هنا هيصير أن ال O أتش هذا لو مر علينامثال بهذا + +84 +00:07:35,650 --> 00:07:41,150 +الشكل طبعا في كل الأحوال لأن هذه حلقة لأن هذه حلقة + +85 +00:07:41,150 --> 00:07:46,430 +هنلاحظ ان النيوكليوفايل هيجي من جهة و ال OH هتكون + +86 +00:07:46,430 --> 00:07:51,390 +من الجهة المعاكزة واضح ان هذا بيأثر على النواتج او + +87 +00:07:51,390 --> 00:07:56,510 +لا هذا موضوع ثاني لكن الإضافة هنا بتكون sin ولا + +88 +00:07:56,510 --> 00:08:02,550 +anti additionبتكون Anti-Addition الإضافة هنا بتكون + +89 +00:08:02,550 --> 00:08:05,750 +Anti-Addition يعني الـ Nucleophile بيجي من الجهة + +90 +00:08:05,750 --> 00:08:10,270 +المعاكسة لجهة تكوّن الـ OH ملاحظين منهم Anti + +91 +00:08:10,270 --> 00:08:13,690 +-Addition؟ + +92 +00:08:13,690 --> 00:08:19,970 +الآن لاحظوا لو فكرنا مثلا أنه بدنا نضيف مجمعتين OH + +93 +00:08:21,270 --> 00:08:26,050 +من جهة واحدة يعني هذه الطريقة انه حولنا الالكين ل + +94 +00:08:26,050 --> 00:08:32,730 +ابوكسايد وفتحنا الحلقة اعطتنا مجموعتين OHمن جهتين + +95 +00:08:32,730 --> 00:08:37,370 +متعاكستين طب لو فكرنا انه بدنا نضيف المجموعتين من + +96 +00:08:37,370 --> 00:08:42,710 +جهة واحدة في عندنا تفاعل تاني ممكن نعمله مباشرة + +97 +00:08:42,710 --> 00:08:48,130 +على ال الكين و بضيف مجموعتين OH من جهة واحدة هذا + +98 +00:08:48,130 --> 00:08:54,170 +التفاعل ان نفعل ال الكين سواء مع مركب ال Osmium O4 + +99 +00:08:54,170 --> 00:08:59,340 +في وجود هذه الأشياءكتاليست او مع مركب كيامان O4 + +100 +00:08:59,340 --> 00:09:03,540 +بيرمانجانات البوتاسيوم سواء قلنا أزوميام الأزوميام + +101 +00:09:03,540 --> 00:09:08,320 +عنصر معدن ثقيل تقريبا هو أثقل العناصر يعني كثافته + +102 +00:09:08,320 --> 00:09:14,300 +أعلى حتى من الدهب واشي فوق العشرين جرام لكل سنتمتر + +103 +00:09:14,300 --> 00:09:21,180 +مكعبواضح؟ سواء قلنا Osmium O4 او KMnO4 انا بحكي عن + +104 +00:09:21,180 --> 00:09:27,520 +معدل مثل ال مثل Osmium او مانجانيز وهذا متصل بكم + +105 +00:09:27,520 --> 00:09:32,990 +مجموعة Oهيبقى أربعة، الآن لما بديجي يتفاعل مع + +106 +00:09:32,990 --> 00:09:36,310 +double bond لما بديجي يتفاعل مع double bond هي + +107 +00:09:36,310 --> 00:09:40,650 +double bond أكيد هيتفاعل من خلال أكسجنتين موجودات + +108 +00:09:40,650 --> 00:09:45,630 +على جهة واحدة و بعد هيك تنكسر هذه الرابطة مع + +109 +00:09:45,630 --> 00:09:51,530 +المعدنتم التفاعل بهذا الشكل هذي هتاخد من مجمل + +110 +00:09:51,530 --> 00:09:58,130 +التفاعل HOOH أكيد أجه من جهة واحدة فالتفاعل هذا + +111 +00:09:58,130 --> 00:10:02,150 +بتتم من جهة واحدة لأنه بإمكانكوا ببساطة تتخيلوا + +112 +00:10:02,150 --> 00:10:08,050 +الكيامان O4 زي هيك هاي .. هاي الأربع ذرات أكسوجين + +113 +00:10:08,050 --> 00:10:12,680 +اللي موجودين فيه الآن بدو يهاجم ع double bondبيقدر + +114 +00:10:12,680 --> 00:10:17,060 +يهاجم من جهتين؟ لأ بالتاكيد هيهاجم من هنا و من هنا + +115 +00:10:17,060 --> 00:10:22,500 +حذرتين أكسجين من جهة واحدة فإضافة مجموعات ال OH + +116 +00:10:22,500 --> 00:10:28,220 +باستعمال ال Osmium O4 أو الكيامان O4 في وجود طبعا + +117 +00:10:28,220 --> 00:10:32,000 +ما basic medium كل الأشياء اللي أمامكم هو عبارة عن + +118 +00:10:32,000 --> 00:10:37,040 +sin ولا anti addition؟ sin addition ابهيك بنذكر + +119 +00:10:37,040 --> 00:10:40,580 +إيش الأشياء اللي بتصيروا ماخدينها sin addition؟ + +120 +00:10:42,290 --> 00:10:49,270 +إضافة الـ hydrogen و إضافة مجموعات ال OH باستعمال + +121 +00:10:49,270 --> 00:10:54,710 +ال Osmium O4 أو الكيامان O4 لما أخدنا إضافة ال PR2 + +122 +00:10:54,710 --> 00:11:00,150 +أخدناها Anti addition لما أخدنا إضافة ال PR2 + +123 +00:11:00,150 --> 00:11:06,290 +أخدناها Anti addition مش Sin addition واضح؟ ولذلك + +124 +00:11:06,290 --> 00:11:12,720 +لو مثلا جيبنا لكم مركب زي هذاخلنا ناخد مثال + +125 +00:11:12,720 --> 00:11:17,540 +Cyclopentane + +126 +00:11:17,540 --> 00:11:26,060 +طبعا ك Cyclopentane شو عليها؟H وH وسألناكم سؤال + +127 +00:11:26,060 --> 00:11:31,280 +قلنا لكم كيف ممكن تحضروا من هذا Cyclobentane + +128 +00:11:31,280 --> 00:11:37,540 +Cyclobentadiol يعني Cyclobentane شيلنا منه ال + +129 +00:11:37,540 --> 00:11:40,900 +double bond و حاطينا مجموعتين OH يعني بدل ال + +130 +00:11:40,900 --> 00:11:44,780 +double bond مجموعتين OH مرة يكونوا ال cis و مرة + +131 +00:11:44,780 --> 00:11:49,600 +يكونوا ال trans كأنه بيصير السؤال انه كيف بدي احضر + +132 +00:11:49,600 --> 00:11:59,490 +منههذا المُركّب اللي فيه مجموعتين الـ OH على جهة + +133 +00:11:59,490 --> 00:12:06,270 +واحدة و بدي أحضر منه أيضا المُركّب اللي فيه + +134 +00:12:06,270 --> 00:12:11,930 +مجموعتين الـ OH على جهتين متعاكستين اللي هم الـ + +135 +00:12:11,930 --> 00:12:13,330 +CIS والـ Trans + +136 +00:12:18,820 --> 00:12:21,820 +واضح؟ how can you prepare this is and + +137 +00:12:21,820 --> 00:12:27,060 +transcyclobentane diol starting from cyclobentene + +138 +00:12:27,060 --> 00:12:32,960 +الان في الحالة الأولى الجواب مباشر في الحالة + +139 +00:12:32,960 --> 00:12:37,040 +الأولى الجواب مباشر بدى استعمل اما طريقة ال + +140 +00:12:37,040 --> 00:12:41,760 +ozomium o4 او ال camon o4 نفس الشيء خلنا نقول مثلا + +141 +00:12:41,760 --> 00:12:49,610 +camon o4 فيباسيك ميديام في وجود الماء ألاحظوا + +142 +00:12:49,610 --> 00:12:54,210 +انتبهوا جيدا لو سمحتوا الكيامان اوفور عشان تعمل + +143 +00:12:54,210 --> 00:12:57,910 +هذا التفاعل و تضيف من جهتين بدا تكون في basic + +144 +00:12:57,910 --> 00:13:02,550 +medium في وجود OH- هذه بديكوا تركزوا عليها لسبب + +145 +00:13:02,550 --> 00:13:06,590 +بسيط انه في تفاعلات تانية سواء درسناها او + +146 +00:13:06,590 --> 00:13:10,850 +مادرسناهاش تفاعل الكيامان اوفور في acidic medium + +147 +00:13:10,850 --> 00:13:16,780 +بيعطيني أشياء تانيةواضح فركزوا ان هذا التفاعل بتم + +148 +00:13:16,780 --> 00:13:22,320 +في basic و medium الان لو قولنا المركب التاني كيف + +149 +00:13:22,320 --> 00:13:30,080 +بدنا نحضره على خطوتين اذا + +150 +00:13:30,080 --> 00:13:34,740 +انا في الاول بدي اجي اقول bare acid مثلا فينيل + +151 +00:13:34,740 --> 00:13:39,580 +COOOH و + +152 +00:13:39,580 --> 00:13:44,720 +استعمل و يعطيني ال ابوكسايدو بعدين بوجود ال .. + +153 +00:13:44,720 --> 00:13:49,480 +بساط حمضي مع .. هاي ال Evoxide واضح؟ أخدنا هذا + +154 +00:13:49,480 --> 00:13:54,440 +التفاعل بيصير Cyclopentene + +155 +00:13:54,440 --> 00:14:01,080 +Oxide و بعد هيك لما أجي أفعله مع ال H2O H plus + +156 +00:14:01,080 --> 00:14:05,300 +بيعمل ring opening O H بتيجي من هنا O Hواحدة من + +157 +00:14:05,300 --> 00:14:08,600 +التحت وواحدة من الفوق إذا هذا التفاعل بتتم على + +158 +00:14:08,600 --> 00:14:12,860 +خطوة ولا على خطوة إيه؟ على خطوة إيه؟ هذا التفاعل + +159 +00:14:12,860 --> 00:14:24,220 +على خطوة واحدة واضح + +160 +00:14:24,220 --> 00:14:24,960 +المثال؟ + +161 +00:14:48,060 --> 00:14:52,220 +من التفاعلات اللى بدنا ندرسها ايضا لل Alkanes + +162 +00:14:52,220 --> 00:14:59,040 +تفاعل جديد الان مش تفاعل اضافة تفاعل bond cleavage + +163 +00:14:59,040 --> 00:15:03,480 +بمعنى بيكسر ال double bond نصين يعني اتطلعوا معاه + +164 +00:15:03,480 --> 00:15:07,000 +هذي ال double bond التفاعل اللى بدنا ندرسه الان + +165 +00:15:07,000 --> 00:15:11,800 +بدوش يضيف حوله من double ل single كل ما درسناه كان + +166 +00:15:11,800 --> 00:15:16,180 +addition reactions لحد الان كل ما درسناه كان + +167 +00:15:16,180 --> 00:15:19,970 +addition double bondتصير single bond الآن بدنا + +168 +00:15:19,970 --> 00:15:23,590 +ناخد نوع تاني من تفاعلات ال double bond اللي هو + +169 +00:15:23,590 --> 00:15:27,030 +cleavage reaction ان اجعل double bond و اكسرها + +170 +00:15:27,030 --> 00:15:32,950 +نصين هذا التفاعل بنسميه ozonolysis of alkenes وزي + +171 +00:15:32,950 --> 00:15:38,750 +ما قلت هو تفاعل ايشCleavage تفاعل كسر بيكسر ال + +172 +00:15:38,750 --> 00:15:43,010 +double bond نصين بتم هذا التفاعل من خلال التفاعل + +173 +00:15:43,010 --> 00:15:48,210 +مع ال ozone بتعرفوا ال ozone الأكسجل في الطبيعة O2 + +174 +00:15:48,210 --> 00:15:52,810 +وإله ألوتروب بنسميها أو صورة تقاصلية تانية يعني + +175 +00:15:52,810 --> 00:15:58,070 +صورة فيزيائية تانية اسمها ايش ozone زي ما الكربون + +176 +00:15:58,070 --> 00:16:02,960 +في الطبيعة بنوجد على شكلGraphite و Diamond و + +177 +00:16:02,960 --> 00:16:09,080 +Carbon-60 او زي ما الفوسفور مثلا في الطبيعة فوسفور + +178 +00:16:09,080 --> 00:16:13,220 +أبيض فوسفور أحمد هذه صورة فيزيائية للمادة لنفس + +179 +00:16:13,220 --> 00:16:17,840 +المادة الآن ال Oxygen في الطبيعة ممكن ينوجد على + +180 +00:16:17,840 --> 00:16:22,860 +شكل Oxygen عادي O2 و ممكن ينوجد على شكل Ozone اللي + +181 +00:16:22,860 --> 00:16:27,540 +عادة موجود في الاطسفير في طبقات الجو العليا و + +182 +00:16:27,540 --> 00:16:33,380 +بعدينبتعرف مشكلة الأوزون لو فعلنا هذا المُركّب مع + +183 +00:16:33,380 --> 00:16:39,220 +الأوزون بداية وبعدين مع زنك في وجود حامض بيكوّنلنا + +184 +00:16:39,220 --> 00:16:42,440 +مُركّب وسيط مش كثير محتم أننا نحفظه أوزونويت + +185 +00:16:42,440 --> 00:16:48,260 +بنسميه هذه الأوزون التلاتة وبعد هيك بتكسر الرابطة + +186 +00:16:48,260 --> 00:16:53,710 +اللي هي بين الكاربون والكاربون هذهDouble bond + +187 +00:16:53,710 --> 00:16:57,470 +بتصير هنا C double bond O وهذه بتصير C double bond + +188 +00:16:57,470 --> 00:17:04,250 +O يعني الكسر من وين هيتملما نجي نفذ الناتج مش كل + +189 +00:17:04,250 --> 00:17:07,350 +مرة بدنا نكون عارفين ال intermediate ناخدها لمرة + +190 +00:17:07,350 --> 00:17:11,650 +واحدة لكن أنا بدي أنفذ أكتب الناتج بدي أجي أتخيل + +191 +00:17:11,650 --> 00:17:16,290 +أنه معي مساحة كسرت الرابطة من هنا هذه هتصير C + +192 +00:17:16,290 --> 00:17:22,690 +double bond O وهذه هتصير C double bond O هيعطيني + +193 +00:17:22,690 --> 00:17:25,570 +تنتين C double bond O لاحظوا الناتج هنا هذه + +194 +00:17:25,570 --> 00:17:32,150 +البنزينة وحملة CH وإيش صارتC double bond O وهنا + +195 +00:17:32,150 --> 00:17:38,270 +عندكم CH2 إيش صارت كمان C double bond O ولو مش + +196 +00:17:38,270 --> 00:17:45,930 +واضحين الروابط فببساطة تفاعل مع الأوزون و بعده + +197 +00:17:45,930 --> 00:17:51,830 +زنكمية هو حقيقة بيحول لل carbon carbon double bond + +198 +00:17:51,830 --> 00:17:57,800 +لتنتين C double bond O يعني بديكوا تتخيلوابهذا + +199 +00:17:57,800 --> 00:18:02,640 +الشكل كان عندكم carbons بغض النظر إيش موجود عندي + +200 +00:18:02,640 --> 00:18:08,460 +هنا ممكن اتش اتش اتش مثل فلل إيش مكان يكون بتخلوه + +201 +00:18:08,460 --> 00:18:12,400 +زي ما هو مش موضوعكم افترضوا قلنالكوا بدنا ناتج ال + +202 +00:18:12,400 --> 00:18:16,860 +ozonolesis لهذا التفاعل إيش أسهل طريقة عشان تنفذوا + +203 +00:18:16,860 --> 00:18:24,160 +الجواب تتخيلوا أنه كسرنا هذه الرابطة واضح؟ و هنا + +204 +00:18:24,160 --> 00:18:28,590 +حطينا O و هناأو نتيجة + +205 +00:18:31,420 --> 00:18:37,520 +هك انا بعمل ناتج ال ozoneolysis الان انه اكون عندى + +206 +00:18:37,520 --> 00:18:41,560 +اى مجموعة هنا مابفرقش عندى لكن بكل الاحوال لو + +207 +00:18:41,560 --> 00:18:45,920 +افترضت عندى carbon و carbon هيطلع عندى كيتون لو + +208 +00:18:45,920 --> 00:18:49,580 +افترضت عندى carbon و hydrogen او تنتين هيدروجين + +209 +00:18:49,580 --> 00:18:54,000 +هيطلع عندى الديهيد اذا هذا تفاعل ال ozoneolysis في + +210 +00:18:54,000 --> 00:18:59,340 +النهاية لو بدأ اقولكوا شو احتمالات نواتجهالديهيد + +211 +00:18:59,340 --> 00:19:04,280 +او كيتون او + +212 +00:19:04,280 --> 00:19:10,200 +كيتون + +213 +00:19:10,200 --> 00:19:12,040 +او كيتون او كيتون او كيتون او كيتون او كيتون او + +214 +00:19:12,040 --> 00:19:12,140 +او كيتون او كيتون او كيتون او كيتون او كيتون او + +215 +00:19:12,140 --> 00:19:12,600 +كيتون او كيتون او كيتون او كيتون او كيتون او كيتون + +216 +00:19:12,600 --> 00:19:13,180 +او كيتون او كيتون او كيتون او كيتون او كيتون او + +217 +00:19:13,180 --> 00:19:13,220 +كيتون او كيتون او كيتون او كيتون او كيتون او كيتون + +218 +00:19:13,220 --> 00:19:15,260 +او كيتون او كيتون او كيتون او كيتون او كيتون او + +219 +00:19:15,260 --> 00:19:21,580 +كيتون او كيتون او كيتون او كيتونأيضا الديهايد + +220 +00:19:21,580 --> 00:19:25,860 +الديهايد يعرف ب H واحدة و أبسط الديهايد في الدنيا + +221 +00:19:25,860 --> 00:19:29,660 +ال form الديهايد اللي فيه H و H تنتيل فوجود H + +222 +00:19:29,660 --> 00:19:34,320 +واحدة بيخل المركب إيش اسمه الديهايد الآن التانية + +223 +00:19:34,320 --> 00:19:38,120 +تكون H بيكون أبسط الديهايد التانية تكون مثل إثل + +224 +00:19:38,120 --> 00:19:43,820 +فنل بروبل أي مجموعة بيظلواالديهيد ايضا فنتج ال + +225 +00:19:43,820 --> 00:19:49,580 +اوزونوليسيس بيعطي الديهيد او كيتون باستخدام + +226 +00:19:49,580 --> 00:19:55,380 +الاشتراكات على الدبل بوند اعتمادا على الاشتراكات + +227 +00:19:55,380 --> 00:19:58,600 +على الدبل بوند الان هي هذا على طول لما واحدة بتطلع + +228 +00:19:58,600 --> 00:20:03,500 +هتلاحظ ايش اعطانا هنا الديهيد اكيد لان الدبل بوند + +229 +00:20:03,500 --> 00:20:08,910 +عليها اتش وهنا نور على نور الدبل بوند عليهاتنتين H + +230 +00:20:08,910 --> 00:20:13,670 +إذا أيضا بالتأكيد الديهايد وإن كان أبسط الديهايد + +231 +00:20:13,670 --> 00:20:17,890 +لكن لو أي طرف عليه تنتين كاربون من عند هذا الطرف + +232 +00:20:17,890 --> 00:20:25,070 +هيعطيه كيتون هاي أمثلة عندنا تطلع عليها في كل + +233 +00:20:25,070 --> 00:20:32,450 +الأحوال من أين ستكسر الرابط من + +234 +00:20:32,450 --> 00:20:38,340 +النص الرابط بنكسرها من النصبدون ما نتطلع على + +235 +00:20:38,340 --> 00:20:41,860 +الجواب لو إجينا سألنا هذا الناتج بيعطي إيش + +236 +00:20:41,860 --> 00:20:46,840 +الديهايد الكربون هذي حملة H at least و هذا + +237 +00:20:46,840 --> 00:20:53,920 +الديهايد و الديهايد هنا T ليش المخفي شو هو؟ بديش + +238 +00:20:53,920 --> 00:21:01,300 +أبقى أتعب معكم كل ما لم يكتب فهو H طيب إذا من هذه + +239 +00:21:01,300 --> 00:21:07,430 +الجهة شو بيعطيه؟ و من هذه الجهةكيتون هذه كل رأس + +240 +00:21:07,430 --> 00:21:12,850 +يعتبر carbon الان هذه بنكسرها ايضا من النص بتصير + +241 +00:21:12,850 --> 00:21:17,590 +هنا C double bond O وهنا C double bond O اكيد هذه + +242 +00:21:17,590 --> 00:21:23,170 +كيتون وهنا فيه H مخفية كيتون + +243 +00:21:23,170 --> 00:21:27,250 +والدايت لاحظوا هذا ماعطاش جزي ايه لكن كسر الرابط + +244 +00:21:27,250 --> 00:21:34,720 +بنفس المنطق هذا نفس الشي تماما لاحظوا هنا فيهأتش و + +245 +00:21:34,720 --> 00:21:38,160 +هنا فيه اتش خلو ادي سيضه بالبندقه و ادي سيضه + +246 +00:21:38,160 --> 00:21:42,200 +بالبندقه بس هو بعد هيك بدل ما الجزيئ يكتبوا عامل + +247 +00:21:42,200 --> 00:21:51,680 +زي هيك فرضه اعطاه نفس حرام يعني هذا بمش هو احنا + +248 +00:21:51,680 --> 00:21:54,940 +ليش بنعلمكوا ان الجزيئات بتتغير زي ما البني ادم + +249 +00:21:54,940 --> 00:21:58,340 +بياخد ميت صورة يعني هذا لو كان بدوا يكتبوا + +250 +00:21:58,340 --> 00:22:00,420 +بالطريقة اللي انتوا فاهمينها + +251 +00:22:03,590 --> 00:22:09,470 +عمل هيك و هيك زي هيك مبين سهل و اين كسرت الرابطة + +252 +00:22:09,470 --> 00:22:16,030 +الان بعد هيك انفرض زي ما الجنيل بيكون متكور في بطن + +253 +00:22:16,030 --> 00:22:25,570 +امه هذا هو هداك هذا المركب هو هذا المركب اليوم + +254 +00:22:25,570 --> 00:22:30,250 +انا باعطي ناتج تفاعل طالما الديهايد او كيتون موطعه + +255 +00:22:30,250 --> 00:22:35,750 +شبتر 9عشان أسميهم، مش اليوم، واضح؟ في طريقة + +256 +00:22:35,750 --> 00:22:44,970 +لتسميتهم ما سُكِت عنه يُصبر عليه، واضح؟ + +257 +00:22:44,970 --> 00:22:51,710 +الآن + +258 +00:22:51,710 --> 00:22:58,890 +من أمثلة ومن تفاعلاتالالكينز أيضا تفاعل مهم جدا في + +259 +00:22:58,890 --> 00:23:02,110 +الحياة التطبيقية العملية وفي الحياة الصناعية + +260 +00:23:02,110 --> 00:23:06,190 +بنسميه احنا free radical polymerization of + +261 +00:23:06,190 --> 00:23:10,290 +ethylene ايش احنا اللي بنقصده في polymerization + +262 +00:23:10,290 --> 00:23:16,030 +بتعرف بيكون عندنا جزء واحد من المادة هذا الجزء + +263 +00:23:16,030 --> 00:23:23,180 +الواحد من المادة ممكن نسميه احنا monomerمونومر جزء + +264 +00:23:23,180 --> 00:23:29,500 +واحد الان لو عملت اتنين بيصير دايمر اتنين دايمر + +265 +00:23:29,500 --> 00:23:37,760 +تلاتة اترايمر اربعة تترامر تلت اربع مية تلت اربع + +266 +00:23:37,760 --> 00:23:45,410 +تلاف وقتها بوليمرطب مش من أولها polymer لأ إذا + +267 +00:23:45,410 --> 00:23:50,130 +إحنا لو كنا بنقول الجزء الواحد إيش بنقوله؟ monomer + +268 +00:23:50,130 --> 00:23:58,750 +اتنين دايمر تلاتة ترايمر أربعة تترامر + +269 +00:24:02,660 --> 00:24:08,120 +بوليمر يعني البوليمر بيكون تلت اربعميت جزيء خمسمية + +270 +00:24:08,120 --> 00:24:11,960 +احيانا تلت تلاف احيانا حسب طبيعة المواد خمسين الف + +271 +00:24:11,960 --> 00:24:15,680 +ميت الف بيكونوا كلهم مار بعض هذا اللي بنسميه + +272 +00:24:15,680 --> 00:24:20,420 +بوليمر مش تلاتة واربعة واضح فالواحد والاتنين + +273 +00:24:20,420 --> 00:24:24,770 +والتلاتة دول علهم أسماء لكن لما بيكون كبيربصير + +274 +00:24:24,770 --> 00:24:30,390 +عنده الـ Polymer الان إذا تخيلتوا ان هذا جزء + +275 +00:24:30,390 --> 00:24:36,310 +إيثالين إيثالين والإيثالين غاز و إجينا على هذا + +276 +00:24:36,310 --> 00:24:45,400 +الإيثالين و حطناه معبروكسايد تحت ضغط مرتفع جدا جدا + +277 +00:24:45,400 --> 00:24:51,160 +جدا الف أتمسفير عشان تخافوا من كلمة الف أتمسفير + +278 +00:24:51,160 --> 00:24:56,300 +يعني تقدروا تتخيلوا شوها الضغط الكبير بس تذكروا أن + +279 +00:24:56,300 --> 00:25:00,400 +طنجرة الضغط اللي بتطبخوا فيها و اللي بتكون تصفروا + +280 +00:25:00,400 --> 00:25:06,620 +و بتخوف الضغط فيها اتنين أتمسفير فقط + +281 +00:25:07,930 --> 00:25:12,510 +الضغط فيها دي طنجرة الضغط اتنين atmosphere فانا + +282 +00:25:12,510 --> 00:25:16,650 +لما بحكي عن الف atmosphere بيمكنكم تخيلوا الضغط + +283 +00:25:16,650 --> 00:25:21,410 +طبعا اكيد هذا التفاعل مابنعملش بجزاز ولا بحديد + +284 +00:25:21,410 --> 00:25:25,050 +بسيط بيكون عندكوا اوعية stainless steel الوعاء + +285 +00:25:25,050 --> 00:25:28,450 +يمكن عرضه اتنين تلاتة سانت stainless steel ومكابس + +286 +00:25:28,450 --> 00:25:34,820 +هيدروليكية هذا شغل صناعةمش شغل مختبر، الآن بيجيبوا + +287 +00:25:34,820 --> 00:25:42,310 +الغاز، بنحطه غاز، بنحط عليه ال ..البروكسايتز هذه + +288 +00:25:42,310 --> 00:25:46,030 +عند ألف أتمسفير وبنسخن عند مئة درجة مئوية بنضغط + +289 +00:25:46,030 --> 00:25:50,210 +الغاز بندخل جزيئات الغاز، لاحظوا غاز، بندخل + +290 +00:25:50,210 --> 00:25:55,970 +جزيئاته في بعضها طالما كبر المركب، هيتحول لإيش؟ + +291 +00:25:55,970 --> 00:26:00,110 +لصلب، مش بزيادة ال molecular weight كنا نتحول من + +292 +00:26:00,110 --> 00:26:03,930 +غاز لسائل لصلب، هيتحول ل polymer، هذا ال polymer + +293 +00:26:03,930 --> 00:26:08,470 +هو plasticهو نوع من ال plastic اللي احنا بنستعمله + +294 +00:26:08,470 --> 00:26:14,410 +بنسميه polyethylene فال ethylene بكل هذه الشروط + +295 +00:26:14,410 --> 00:26:18,450 +بيصير CH2 CH2 to the N لحظة لغية ال double bond + +296 +00:26:18,450 --> 00:26:23,570 +خلتها single bond لغية ال double bond و خلتها + +297 +00:26:23,570 --> 00:26:30,530 +single bond في هذه الحالة صارالإيثالين بولي + +298 +00:26:30,530 --> 00:26:34,570 +إيثالين طبعا في ميكانيزم للتفاعل مش كتير بتفرج + +299 +00:26:34,570 --> 00:26:38,910 +عنده البولي إيثالين هو البلاستيك الأبيض إذا دخلتوا + +300 +00:26:38,910 --> 00:26:42,050 +على المختبرات بتلاحظوا في عندكم جلانات بنعب فيها + +301 +00:26:42,050 --> 00:26:46,330 +ميا ديستيلد ووتر wash bottles أشياء كل هذه عبارة + +302 +00:26:46,330 --> 00:26:49,490 +عن بولي إيثالين الأوعية اللى بنحط فيها هيدروكسيد + +303 +00:26:49,490 --> 00:26:53,050 +الصوديوم بتشوفوا ال .. ال bottle اللى بنكون معبينه + +304 +00:26:53,050 --> 00:27:00,100 +محلولا كل هذه عبارة عن إيش بولي إيثالينالان بنفس + +305 +00:27:00,100 --> 00:27:03,820 +المنطق، شوفوا كيف العلم بتطور، يعني أول ما بدأنا + +306 +00:27:03,820 --> 00:27:07,280 +عملنا Polymer عملنا إيش؟ الـ Ethylene و عملنا له + +307 +00:27:07,280 --> 00:27:12,200 +Polymerization إلى Polyethylene طيب هم قالوا لازم + +308 +00:27:12,200 --> 00:27:16,400 +هدول الأربعة يكونوا Hydrogen و Hydrogen يعني CH2 + +309 +00:27:16,400 --> 00:27:22,400 +CH2 لو يا ترى بدلنا واحدة منهمبكلور هنا هنا شيلنا + +310 +00:27:22,400 --> 00:27:28,860 +واحدة بالغلط صار CH CH2CL وكان double bond وعملنا + +311 +00:27:28,860 --> 00:27:33,800 +منه ال polymer هتصير single bond طب هذا المركب + +312 +00:27:33,800 --> 00:27:42,680 +الأصلي CH2 double bond CHCL أخدنا اسمه vinyl + +313 +00:27:42,680 --> 00:27:47,480 +chloride هذه مجموعة ال vinylVinyl chloride اللي + +314 +00:27:47,480 --> 00:27:51,760 +قال لو اعملت منه بوليمار بنفس المنطق تبع الاثيلين + +315 +00:27:51,760 --> 00:27:58,640 +الغط بابل بوند و اكتبه to the end طالما هذا Vinyl + +316 +00:27:58,640 --> 00:28:03,960 +chloride Vinyl chloride شو هيصير البوليمار تبعه + +317 +00:28:03,960 --> 00:28:08,320 +بولي و Vinyl chloride اتخيلوا لو بدنا نختصر اسم + +318 +00:28:08,320 --> 00:28:14,300 +البوليمار تبعه BVC + +319 +00:28:15,850 --> 00:28:23,430 +مين ما بعرفش ال PVC؟ كل شناتكم PVC، كل بلاستيك + +320 +00:28:23,430 --> 00:28:27,310 +المحووتكم PVC، كل المواسير اللي بتشوفوها اللي + +321 +00:28:27,310 --> 00:28:30,810 +بنستعملها لتمديدات الصرف الصحي، المواسير + +322 +00:28:30,810 --> 00:28:35,750 +البردجانية والسكنية، لو جربت عليها، مكتوب عليها + +323 +00:28:35,750 --> 00:28:36,230 +PVC + +324 +00:28:39,480 --> 00:28:43,960 +Polyvinyl chloride اللي بيعملوها أرضيات أحيانا + +325 +00:28:43,960 --> 00:28:48,820 +بيغطوا فيها البلاط ممكن تشوفوها أحيانا في صالونات + +326 +00:28:48,820 --> 00:28:53,200 +لحلاجة في المستشفى أرضية بلاستيك و بيلزجوها فوق كل + +327 +00:28:53,200 --> 00:28:59,900 +بلاط الغرفة هذه PVC فال PVC موجود وبشكل كبير في + +328 +00:28:59,900 --> 00:29:05,640 +الحياة التطبيقيةزي وزي البولي إيثالين الآن لاحظوا + +329 +00:29:05,640 --> 00:29:09,540 +إذا صارت القصة إن أغير واحدة من الهيدروجين وحطيت + +330 +00:29:09,540 --> 00:29:14,960 +كلور لما كانت هيدروجين بولي إيثالين لما كانت كلور + +331 +00:29:14,960 --> 00:29:21,020 +PVC أو بولي فينيلي كلورايت طب لو خلناها بنزينة + +332 +00:29:22,360 --> 00:29:28,720 +المُركّب الأصلي سيكون CH2 double bond CH حملة + +333 +00:29:28,720 --> 00:29:34,920 +بنزينة أو phenyl اسمه styrene اسمه styrene لما + +334 +00:29:34,920 --> 00:29:41,130 +أعمل منه polymerإيش بده يصير؟ Polystyrene لما أعمل + +335 +00:29:41,130 --> 00:29:45,690 +منه polymer هيصير polystyrene إذا التفاعل مش بس + +336 +00:29:45,690 --> 00:29:50,390 +خاص بال إيثيلين لأ اتطور على مواد تانية و كل هذه + +337 +00:29:50,390 --> 00:29:54,310 +عبارة عن أنواع من ال plastic موجودة في السوق و + +338 +00:29:54,310 --> 00:29:59,950 +بتلباع و بتعامل فيها الناس و أفرجناكوا تطبيقيا وين + +339 +00:29:59,950 --> 00:30:02,430 +بتستعمل واضحة هذه الفكرة؟ + +340 +00:30:05,100 --> 00:30:09,380 +إذا هاي كمان تفاعل تاني لل ال keys يعني كأنها + +341 +00:30:09,380 --> 00:30:14,560 +بنصير كتفاعلات أساسية أخدنا الإضافة أخدنا ال + +342 +00:30:14,560 --> 00:30:18,340 +cleavage اللي هو ال ozoneolysis و أخدنا ال + +343 +00:30:18,340 --> 00:30:24,690 +polymerization أنه بيعمل polymer كبيرطبعا الله + +344 +00:30:24,690 --> 00:30:29,510 +يعطيكوا العافية بالنسباله ال Alkenes طب لو انتقلنا + +345 +00:30:29,510 --> 00:30:35,130 +لل Alkynes هتلاحظوا أنه بشكل أساسي تفاعلات شبيهة + +346 +00:30:35,130 --> 00:30:41,710 +الأساس فيها الإضافة ولكن لاحظوا معي لما أبدأ أحكي + +347 +00:30:41,710 --> 00:30:47,590 +عن ال Alkynes ال Alkynes تلت روابط carbon ال + +348 +00:30:47,590 --> 00:30:52,230 +triple bond carbon إذا لو بده يبدأ يضيف إيش + +349 +00:30:52,230 --> 00:30:56,740 +هيتحول؟لـ carbon double bond carbon وكمان خطوة + +350 +00:30:56,740 --> 00:31:02,560 +carbon single bond carbon إذا الإضافة هنا يمكن أن + +351 +00:31:02,560 --> 00:31:07,820 +تتم على مراحل يعني ال triple bond تصير double bond + +352 +00:31:07,820 --> 00:31:12,020 +تصير single bond مرات حسب شروط التفاعل وهذا اللي + +353 +00:31:12,020 --> 00:31:15,820 +بتكون تنتبهوله ممكن نخل التفاعل يجف لهنا بنص + +354 +00:31:15,820 --> 00:31:19,700 +الطريق يعني ال triple تصير double و يجف التفاعل + +355 +00:31:19,700 --> 00:31:26,830 +مرات بيستمرمرات ما بنقدرش نفصل المركب اللي بالوسط + +356 +00:31:26,830 --> 00:31:31,150 +يعني مجرد ما نحط عليه المادة التانية بيصير double + +357 +00:31:31,150 --> 00:31:36,450 +bond و بسرعة كبيرة بيظلوا محول لإيش ل single bond + +358 +00:31:36,450 --> 00:31:40,070 +بعمل إضافة تانية طبعا هنا كام إضافة بيصير لو قلت + +359 +00:31:40,070 --> 00:31:46,750 +من triple ل single bond إضافتين إضافتين يعني لو + +360 +00:31:46,750 --> 00:31:53,720 +قعد بضيف HCl مش لغاية double bond شو حطيت؟ Hطب + +361 +00:31:53,720 --> 00:31:56,880 +هدولة كيف بدي أضيفهم؟ حسب قاعدة Markov Nikov ولا + +362 +00:31:56,880 --> 00:32:00,720 +ضد؟ إذا كانوا مع ال H Plus حسب قاعدة Markov Nikov + +363 +00:32:00,720 --> 00:32:06,340 +يعني اتخيلتوا هذه H وهذه CH3 وين هتيجي ال H؟ على + +364 +00:32:06,340 --> 00:32:13,940 +الحاملة ال H أكتر وين هتيجي التانية؟ واضح؟ أه بعد + +365 +00:32:13,940 --> 00:32:18,780 +هيك لو بدي أضيف كمان مرة سرادة ال K أخدنا كيف بضيف + +366 +00:32:18,780 --> 00:32:24,780 +ال K على هذا؟ هتيجي ال H هنا؟و ال CL هنا وجدت كأنه + +367 +00:32:24,780 --> 00:32:30,020 +ضفت التنتين هيدروجين على نفس الكربون وهي + +368 +00:32:30,020 --> 00:32:36,120 +الهيدروجين الأصلية والتنتين CL على نفس الكربون وهي + +369 +00:32:36,120 --> 00:32:42,660 +CH3 خلّينا الطول الأصلية إذا التفاعل هنا تم على + +370 +00:32:42,660 --> 00:32:48,600 +مرحلة ولا مرحلتين؟ ع مرحلتين كل مرحلة منهم تمت حسب + +371 +00:32:48,600 --> 00:32:54,750 +قاعدة Markov-Nikov لما أضيف HCL في وجودالـ H plus + +372 +00:32:54,750 --> 00:33:00,150 +واضح؟ كل مرحلة منهم بتتم حسب قاعدة ماركو بيه + +373 +00:33:00,150 --> 00:33:05,190 +خلّينا نشوف هذا الكلام بالتفصيل بعض الإضافات بعض + +374 +00:33:05,190 --> 00:33:09,850 +تفاؤلات الإضافة للالكينز لاحظوا هاي أول مثال + +375 +00:33:09,850 --> 00:33:18,490 +addition of HX to alkynes هاي عندي كاربون بتحمل H + +376 +00:33:18,490 --> 00:33:25,510 +وكاربون بتحمل إيش H وضفت ال HClضعفين كيف هيكون + +377 +00:33:25,510 --> 00:33:30,630 +الناتج الأخير انه هضيف مرتين ال H هنا و هنا و + +378 +00:33:30,630 --> 00:33:33,590 +مرتين ال CL هنا و هنا هذه الناتج الأخيرة بس + +379 +00:33:33,590 --> 00:33:39,030 +بالتأكيد اول ما بيبدأ اضيف الإضافة الأولى إجت هنا + +380 +00:33:39,030 --> 00:33:44,270 +H و إجت هنا CL و الإضافة التانية إجت هنا كمان H و + +381 +00:33:44,270 --> 00:33:52,640 +هنا كمان CL واضح فمرتين حسب قاعدةماركوف نيكوف + +382 +00:33:52,640 --> 00:33:56,380 +اديشن الان + +383 +00:33:56,380 --> 00:34:04,360 +لو كنت بدى اضيف لبروم لبروم بضيف Anti addition + +384 +00:34:04,360 --> 00:34:11,540 +المرة الأولى هين اضفت PR و PR عكس بعضه اعطانى + +385 +00:34:11,540 --> 00:34:18,660 +الالكيل كمان مرة يعني كأنه هى ال PR 2 الأول وهىالـ + +386 +00:34:18,660 --> 00:34:23,020 +PR2 التالي كمان مرة حديث من هنا و من هنا صار عندى + +387 +00:34:23,020 --> 00:34:27,420 +أربع ذرات إبروم فلاحظوا لو أنا كنت كاتب زيكوا و + +388 +00:34:27,420 --> 00:34:34,380 +كاتبلكوا 2PR2 شو ناتج النهاية اللى بدى أكتبه ال + +389 +00:34:34,380 --> 00:34:39,700 +كان أو ال كان ال كان ال كان بالإنجليزي ال كان + +390 +00:34:39,700 --> 00:34:45,890 +بالعربي ال كان بالإنجليزي ماختلفناهاش كتيرالان من + +391 +00:34:45,890 --> 00:34:52,230 +التفاعلات المهمة ايضا تفاعل اضافة الميه بس اضافة + +392 +00:34:52,230 --> 00:35:02,070 +الميه شوية في فكرة جديدة لو انا اجيت وضفت الميهH2O + +393 +00:35:02,070 --> 00:35:06,210 +في وجود H بلس يعني كأني بقول H3O plus و عادة + +394 +00:35:06,210 --> 00:35:14,230 +بنستعمل catalyst الذئبق ايون ذئبق HG2 plus فلما + +395 +00:35:14,230 --> 00:35:19,610 +بنعمل هذا الكلام بتضيف الميه حسب قاعدة Markovnikov + +396 +00:35:19,610 --> 00:35:24,210 +بمعنى هنا بدأ تيجي ال H وهنا بدأ تيجي ال OH هاي + +397 +00:35:24,210 --> 00:35:29,360 +الميه اللي ضفناهاهذه إضافة حسب قاعدة ماركوف نيكوف + +398 +00:35:29,360 --> 00:35:33,960 +و لا لأ الآن لاحظوا لو اتطلعت على المركب اللي + +399 +00:35:33,960 --> 00:35:39,880 +اتكون عندى هذا مركب يحتوي على مجموعتين وظيفيتين + +400 +00:35:39,880 --> 00:35:44,040 +المجموعة الوظيفة الوظيفية الأولى ال ال keen + +401 +00:35:45,140 --> 00:35:51,700 +والتانية ال alcohol all فهذا فيه in و فيه all + +402 +00:35:51,700 --> 00:35:55,920 +شايفينهم هذه ال double bond مش بتاخد نهاية in و + +403 +00:35:55,920 --> 00:36:02,620 +هذه all فهذا المركب بنسميه in all لأنه متكون من + +404 +00:36:02,620 --> 00:36:08,420 +هدول الشغلتين in all ال OH متصلة مباشرة جنب ال + +405 +00:36:08,420 --> 00:36:13,950 +double bond هذه المركباتللأسف الشديد انه في الوضع + +406 +00:36:13,950 --> 00:36:18,530 +الطبيعي في الاليفاتيك كومباونز they are unstable + +407 +00:36:18,530 --> 00:36:25,690 +مركبات غير ثابتة بتعمل تحول بتتحول هذه المركبات شو + +408 +00:36:25,690 --> 00:36:29,390 +التحول اللي بتعمله بتخلي ال double bond هذي تيجي + +409 +00:36:29,390 --> 00:36:33,030 +هنا تصير هذي C double bond O و ال H تنتقل هنا + +410 +00:36:33,030 --> 00:36:38,650 +لاحظوا تغيرين اللي بيصير فيها انتقال إلكترونات و + +411 +00:36:38,650 --> 00:36:46,940 +انتقالزرات لما نعمل هذا الكلام هذه ال C شو صارت؟ C + +412 +00:36:46,940 --> 00:36:54,740 +double bond O و هذه ال CH2 شو صارت؟ CH3 إذا إيش + +413 +00:36:54,740 --> 00:37:00,160 +انتقل عنده؟ فقط إلكترونات ولا إلكترونات و ذرات؟ + +414 +00:37:00,160 --> 00:37:04,040 +إلكترونات و ذرات و الذرة تحديدا ذرة الهيدروجين هذه + +415 +00:37:04,040 --> 00:37:09,070 +العمليةاللي بتتم فيها انتقال إلكترونات و ذرات + +416 +00:37:09,070 --> 00:37:13,930 +بتختلف عن عملية ال resonance اللي كانت فقط انتقال + +417 +00:37:13,930 --> 00:37:20,310 +إلكترونات متذاكرين ال resonance؟ ال resonance لما + +418 +00:37:20,310 --> 00:37:26,150 +اتكلمنا عنه و أعطيناه أي سهم ال double headed + +419 +00:37:26,150 --> 00:37:29,930 +straight arrow كان ال resonance movement + +420 +00:37:33,520 --> 00:37:39,820 +movement of electrons only طب لو صارت ال movement + +421 +00:37:39,820 --> 00:37:47,940 +electrons زائد H هذه العملية بسميها Tautomerism + +422 +00:37:47,940 --> 00:37:54,620 +تختلف عن ال resonance بسميها Tautomerismالتوتو + +423 +00:37:54,620 --> 00:38:00,440 +ميريزم ليست فقط حركة إلكترونات حركة إلكترونات و + +424 +00:38:00,440 --> 00:38:04,040 +ذرات و الذرة تحديدا أو غالبا اللي هي ذرة ال إيش + +425 +00:38:04,040 --> 00:38:07,960 +الهيدروجين بيصير عندي توتو ميريزم الآن البعض هيقول + +426 +00:38:07,960 --> 00:38:13,660 +لي شو سهم التوتو ميريزم بنقول سهم التوتو ميريزم + +427 +00:38:13,660 --> 00:38:19,500 +سهم التوتو ميريزم هو سهم الإتزان بهذا الشكلانسى + +428 +00:38:19,500 --> 00:38:23,560 +السهم المرسوم هذا هو الشكل السليم سهم التوتوميرزم + +429 +00:38:23,560 --> 00:38:28,540 +هو سهم الاتزام اذا احنا بنقدر نقول الان لو كنا + +430 +00:38:28,540 --> 00:38:33,320 +بنسألكوا صح و غلط توتوميرزم is an equilibrium + +431 +00:38:33,320 --> 00:38:37,720 +reaction صح طالما equilibrium reaction في ال + +432 +00:38:37,720 --> 00:38:43,980 +equilibrium reaction ايش بينوجد الشغلتين بنسب + +433 +00:38:43,980 --> 00:38:51,040 +معينة الان هذا الشكل اللى اتكون كيتونهذا E0 عشان + +434 +00:38:51,040 --> 00:38:56,400 +هيك هذا التوتمريزم يسمونه كيتو E0 التوتمريزم + +435 +00:38:56,400 --> 00:39:00,660 +التنقل بين التنين لكن مين اللي ينجد بنسبة أكبر + +436 +00:39:00,660 --> 00:39:06,440 +الكيتو يعني لو افترضنا ان هذا كان 99.9% هذا بيكون + +437 +00:39:06,440 --> 00:39:13,050 +بس بنسبة 1.10%يعني في هذا التوتوميريزم ال keto + +438 +00:39:13,050 --> 00:39:17,090 +-enol توتوميريزم ال predominant عارفين كلمة + +439 +00:39:17,090 --> 00:39:23,690 +predominant؟ ال predominant + +440 +00:39:23,690 --> 00:39:27,610 +مين فيها؟ بيكون ال ketone ولا ال enol؟ ال ketone + +441 +00:39:27,610 --> 00:39:31,330 +هو اللي موجود بنسبة كبيرة و ال enol بيكون بنسبة + +442 +00:39:31,330 --> 00:39:35,930 +قليلة طبعا هذا في الaliphatic compoundsلما نيجي + +443 +00:39:35,930 --> 00:39:42,610 +نتعلم في ال aromatic compounds هتلاحظوا العكس في + +444 +00:39:42,610 --> 00:39:49,570 +ال aromatic اللي بينوجد بنسبة أكبر ال enol وعشان + +445 +00:39:49,570 --> 00:39:53,670 +هيك كل كلانة بتقدروا تتذكروا و تشوفوا كيف أصل + +446 +00:39:53,670 --> 00:39:59,190 +الإسم لو اطلعتوا على هذا المركب مين تسمينا إياه؟ + +447 +00:39:59,190 --> 00:40:09,580 +Phenolفينول أنا بدي أسميه زي هيك في إين أول تطلعوا + +448 +00:40:09,580 --> 00:40:15,020 +معاه الفي لأنه عندي بنزينة الفنل الفنل البنزينة و + +449 +00:40:15,020 --> 00:40:20,880 +إين هي الإين و all هي + +450 +00:40:20,880 --> 00:40:25,980 +ال all هذا الشكل الثابت منه و بنقدر نعطيكوا + +451 +00:40:25,980 --> 00:40:29,240 +homework ان جولكوا ارسمونا ال ketone تبعه + +452 +00:40:42,070 --> 00:40:47,610 +ما هو الشكل الثابت في الاروماتيك كومباوتز الموجودة + +453 +00:40:47,610 --> 00:40:52,520 +بالنسبة أعلى؟الـ Enol في الالفاتيك كومباونز اللي + +454 +00:40:52,520 --> 00:40:57,200 +موجود بنسبة أعلى الـ Ketone وهذه التوتوماريزم زي + +455 +00:40:57,200 --> 00:41:01,320 +ما اتفقنا هي عبارة عن عملية equilibrium فالسهم + +456 +00:41:01,320 --> 00:41:08,350 +اللي بيستعمللهاأي سهم؟ الـ straight arrow او two + +457 +00:41:08,350 --> 00:41:12,270 +straight arrows with half heads اللي هو السهمين + +458 +00:41:12,270 --> 00:41:16,070 +اللي موجودين كل واحد بنصف رأس زي ما انتوا شايفينه + +459 +00:41:16,070 --> 00:41:20,610 +هنا واللي اتفقنا ان هذا يستعمل الاتزان وعملية + +460 +00:41:20,610 --> 00:41:25,830 +التوتوماريزم هي حقيقة عملية اتزان عملية + +461 +00:41:25,830 --> 00:41:29,490 +التوتوماريزم هي حقيقة عملية اتزان + +462 +00:41:34,870 --> 00:41:39,810 +التفاعلات أيضا لو كنت أنا بضيف الميه عكس قاعدة + +463 +00:41:39,810 --> 00:41:45,070 +Markov Nikov باستعمال ال boron لاحظوا هنا في عندكم + +464 +00:41:45,070 --> 00:41:50,310 +H هذا نفس المثال السابق بس في اللحظة الأولى اللي + +465 +00:41:50,310 --> 00:41:54,510 +حطيت فيها H و OH طالما بضيف باستعمال ال boron هل + +466 +00:41:54,510 --> 00:41:59,110 +هضيف حسب قاعدة Markov Nikov ولا عكسها عكسها بناء + +467 +00:41:59,110 --> 00:42:04,860 +على ذلك حطيت ال H على اللي حامله H أقلو ال O H على + +468 +00:42:04,860 --> 00:42:08,900 +اللي حامله H هذا إضافة عكس Markovnikov مرة تانية + +469 +00:42:08,900 --> 00:42:18,180 +صار عندى in all هذا ال in all بحوله إلى ال keto + +470 +00:42:18,180 --> 00:42:23,560 +form بمعنى هذا ال double bond تيجي هنا و ال H + +471 +00:42:23,560 --> 00:42:29,500 +تنتقل مكان ما إجت ال double bondكل هذا الكلام + +472 +00:42:29,500 --> 00:42:33,320 +طبقوا بإيدكم عشان تتدربوا عليه، إذا نفس + +473 +00:42:33,320 --> 00:42:37,380 +التوتوميرزم، لكن في هذه الحالة بدل ما أحصل على + +474 +00:42:37,380 --> 00:42:42,560 +كيتون حصلت على الديهايد، في المرة الأولى، ليش حصلت + +475 +00:42:42,560 --> 00:42:48,100 +على كيتون؟ لأن ال OH إجت على الكاربون الداخليةفلما + +476 +00:42:48,100 --> 00:42:51,380 +صارت C double bond O صفية متصلة بكاربون و بكاربون + +477 +00:42:51,380 --> 00:42:55,480 +كيتون في المرة التانية لما أضيف عكس قاعدة + +478 +00:42:55,480 --> 00:42:58,800 +Markovnikov و أعمل التوتوميرزم ال OH جت على + +479 +00:42:58,800 --> 00:43:04,720 +الكاربون الطرفية ولذلك حصلت على الديهيد اذا انا + +480 +00:43:04,720 --> 00:43:10,100 +ممكن احصل من هذا التفاعل على الديهيد او كيتون + +481 +00:43:10,100 --> 00:43:13,840 +اعتمادا على الطريقة اللي انا ببدأ فيها اذا ضفت + +482 +00:43:13,840 --> 00:43:19,760 +الماء بقاعدة Markovnikovبحصل على كيتون وإذا ضيفت + +483 +00:43:19,760 --> 00:43:24,300 +الماء عنتي ماركوفنيكوف بحصل على الديهايد وهذا + +484 +00:43:24,300 --> 00:43:27,360 +الكلام لما انتوا تتدربوا و تطبقوا بيدكم هتلاحظوا + +485 +00:43:27,360 --> 00:43:32,900 +انه بيطلع بشكل تلقائي النتيجة هذه تطلع معاكم بشكل + +486 +00:43:32,900 --> 00:43:42,700 +تلقائي تقريبا الشغلة الأخيرة في هذا الموضوع إضافة + +487 +00:43:42,700 --> 00:43:43,680 +الهيدروجين + +488 +00:43:45,820 --> 00:43:52,880 +أخرناها كثير إضافة الهيدروجين للـ triple bond لها + +489 +00:43:52,880 --> 00:43:57,780 +عدة حالاتإذا ضيفت الهيدروجين في وجود معدن زي + +490 +00:43:57,780 --> 00:44:02,380 +البلاديم والكربون أو مثلا ال nickel أو ال platinum + +491 +00:44:02,380 --> 00:44:08,060 +أي واحد من هدول بلاديم نيكل platinum عادة معدن + +492 +00:44:08,060 --> 00:44:13,680 +البلاديم بيكون مخلوط بكربون بودرة تمام فبتتحول لل + +493 +00:44:13,680 --> 00:44:18,820 +triple bond إلى single bond مباشرة بدون مأمورأو + +494 +00:44:18,820 --> 00:44:20,940 +بمر في الـ double bond بدون ما أفصل الـ double + +495 +00:44:20,940 --> 00:44:26,760 +bond يعني بضيف هيدروجين و كمان هيدروجين فالالكاين + +496 +00:44:26,760 --> 00:44:31,760 +إذا فعلنا مع الهيدروجين في وجود متل بيصير الكين + +497 +00:44:31,760 --> 00:44:35,340 +يعني لما نيجي نقولكم reaction of alkynes with + +498 +00:44:35,340 --> 00:44:40,270 +hydrogen in presence of metals شو بيعطيناالكينز + +499 +00:44:40,270 --> 00:44:46,010 +الان طيب لو جيبت الكاين زي هذا وفعلته مع هيدروجين + +500 +00:44:46,010 --> 00:44:51,030 +في وجود مادة اسمها لند لارز كتاليست يمكن بالكتابة + +501 +00:44:51,030 --> 00:44:55,170 +ناقص حرف ال L لند لارز كتاليست لند لارز كتاليست + +502 +00:44:55,170 --> 00:44:57,530 +لند لارز كتاليست لند لارز كتاليست لند لارز كتاليست + +503 +00:44:57,530 --> 00:45:02,890 +لند لارز كتاليست بضيف بهذه الحالة الهيدروجين من + +504 +00:45:02,890 --> 00:45:10,320 +جهة واحدة وبيعطينيالالكين بيجي في نص الطريق بس إيش + +505 +00:45:10,320 --> 00:45:17,260 +نوع إضافة الهيدروجين في وجود الليندلار + +506 +00:45:17,260 --> 00:45:18,700 +كاتاليست الهيدروجين الهيدروجين الهيدروجين + +507 +00:45:18,700 --> 00:45:20,760 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +508 +00:45:20,760 --> 00:45:21,100 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +509 +00:45:21,100 --> 00:45:21,420 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +510 +00:45:21,420 --> 00:45:21,440 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +511 +00:45:21,440 --> 00:45:24,080 +الهيدروجين الهيدروجين الهيدروجينسيس كومباوند في + +512 +00:45:24,080 --> 00:45:26,840 +حالة تانية ممكن لأ يعني لو كانت هذه قدش و قدش مش + +513 +00:45:26,840 --> 00:45:30,900 +هيقد لسيس كومباوند أهم شيء عندنا ان الهيدروجين + +514 +00:45:30,900 --> 00:45:36,100 +بيضيف بسين اديشن اذا كانت اضافته في وجود لندلار + +515 +00:45:36,100 --> 00:45:39,320 +كتاليست و بيقف عن نص الطريق بيقف في وين؟ عند + +516 +00:45:39,320 --> 00:45:44,500 +الألكيد طب يا تورا هل ممكن نضيف الهيدروجين انت + +517 +00:45:44,500 --> 00:45:51,300 +اديشن يعني على نفس هذا المركب و نطلعالهيدروجين + +518 +00:45:51,300 --> 00:45:55,020 +Anti-addition بمعنى إيصير عندي double bond أخلي + +519 +00:45:55,020 --> 00:46:03,960 +البنزنتين على جهتين والهيدروجين على جهتين هذا Anti + +520 +00:46:03,960 --> 00:46:09,880 +-addition واضح؟ ممكن لو أعملنا التفاعل في وجود + +521 +00:46:09,880 --> 00:46:19,310 +ليثيان مع liquid ammoniaواضح؟ اذا انا بإمكاني اضيف + +522 +00:46:19,310 --> 00:46:24,470 +الهيدروجين بطريقة معينة يعملي sin addition و + +523 +00:46:24,470 --> 00:46:29,630 +بطريقة تانية يعملي anti addition و ممكن اضيفه على + +524 +00:46:29,630 --> 00:46:36,970 +مرتين في وجود الهيدروجين و البلاديم او ال nickel + +525 +00:46:36,970 --> 00:46:41,990 +او ال platinum ثانية + +526 +00:46:41,990 --> 00:46:46,060 +بس لو سمحتواLindlar's catalyst هو عبارة عن خليط من + +527 +00:46:46,060 --> 00:46:49,800 +البلاديم مع الكالسيوم كربونيت مع ليد أسيتيت مع + +528 +00:46:49,800 --> 00:46:54,360 +كوينولين بهمنيش نحفظ شكله ماخد اسم، إيش اسمه؟ + +529 +00:46:54,360 --> 00:46:57,000 +Lindlar's catalyst + +530 +00:47:00,060 --> 00:47:04,660 +في عندكم طبعا عدة أمثلة عشان انتوا تدرسوها هي + +531 +00:47:04,660 --> 00:47:10,100 +تطبيق مباشر على هذا الموضوع بيظل عندنا للمرة + +532 +00:47:10,100 --> 00:47:14,100 +الجاية فقط slide واحدة بنحكيها بدقيقتين في موضوع + +533 +00:47:14,100 --> 00:47:17,920 +ال kinds و بننتقل لل chapter الرابع اللي هو + +534 +00:47:17,920 --> 00:47:23,020 +chapter ال aromatic compounds يعني فقط ضايل عندنا + +535 +00:47:23,020 --> 00:47:26,780 +slide واحدة ان شاء الله المرة القادمة بنشرح + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..c39819b59314f271e575c40fdf0907bc2d70979a --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/Mr5OFkzyiYs_raw.srt @@ -0,0 +1,2152 @@ +1 +00:00:21,410 --> 00:00:26,010 +بسم الله الرحمن الرحيم بدأنا احنا في محاضرات ماضية + +2 +00:00:26,010 --> 00:00:31,390 +في تفاعلات ال alkanes ويمكن لاحظنا ان الأمر في هذه + +3 +00:00:31,390 --> 00:00:36,690 +المنطقة هو أمر سهل جدا مافيش فيه مشاكل الرابطة + +4 +00:00:36,690 --> 00:00:41,450 +الزوجية من خلال تفاعل الإضافة بتصير رابطة أحدية + +5 +00:00:42,020 --> 00:00:45,740 +الاشياء المتعلقة بهذا التفاعل اللى اتكلمنا عنها + +6 +00:00:45,740 --> 00:00:50,220 +كانت طبيعة ال الكين و طبيعة ال reagent هل ال الكين + +7 +00:00:50,220 --> 00:00:54,400 +symmetric هل ال reagent symmetric و هذا الكلام أدى + +8 +00:00:54,400 --> 00:00:58,140 +إلى انه مرات بيكون في عندنا اضافات حسب قاعدة + +9 +00:00:58,140 --> 00:01:01,760 +Markovnikov او عكس قاعدة Markovnikov حسب طبيعة + +10 +00:01:02,350 --> 00:01:05,850 +التفاعل اللى بنعمله اخر شغل انتهينا عنده في + +11 +00:01:05,850 --> 00:01:11,030 +المحاضرة الماضية انه احنا ايضا ممكن نضيف oxygen + +12 +00:01:11,030 --> 00:01:16,050 +على ال double bond من خلال تفاعل ال alkenes مع ال + +13 +00:01:16,050 --> 00:01:20,030 +bare acids بيعطونا ال epoxides اللى هى الحلقات + +14 +00:01:20,030 --> 00:01:25,510 +الثلاثية اتعلمنا تسميتها بطريقتين سواء ان نسميها + +15 +00:01:25,510 --> 00:01:30,300 +من خلال ان نقولالكين اكسايد نذكر اسم الالكين + +16 +00:01:30,300 --> 00:01:34,720 +الأصلي اللى نتجت منه او من خلال اننا نعتبر ال + +17 +00:01:34,720 --> 00:01:37,360 +parent ring يعني الحلقة الأساسية اللى كلها + +18 +00:01:37,360 --> 00:01:43,720 +هيدروجين اسمها oxirane و الرقم من عند ال oxygen و + +19 +00:01:43,720 --> 00:01:51,200 +نذكر أسماء ال substituents اللى موجودةأيضا ركزنا + +20 +00:01:51,200 --> 00:01:55,660 +على نقطة أن هذه الحلقة الثلاثية هي حلقة مضغوطة is + +21 +00:01:55,660 --> 00:02:00,560 +a strained ring ليش؟ لأن الزوايا فيها ضغطت إلى + +22 +00:02:00,560 --> 00:02:04,720 +الستين الوضع المريح لزاوية ال carbon carbon carbon + +23 +00:02:04,720 --> 00:02:10,020 +او ما شابه مية وتسعة و نص ولذلك أسهل تفاعل فيها + +24 +00:02:10,020 --> 00:02:14,440 +اللي هو تفاعل ال ring opening فاحنا صح بنكون + +25 +00:02:14,440 --> 00:02:20,350 +الحلقةلكن الحلقة strain فلما تتجه تعمل ring + +26 +00:02:20,350 --> 00:02:26,250 +-opening فكرة ال ring-opening كانت مبنية على انه + +27 +00:02:26,250 --> 00:02:31,670 +اذا اتذكرنا احنا ان الاكسجين electronegative اكثر + +28 +00:02:31,670 --> 00:02:35,830 +من الكربون يعني الاكسجين partially negative ال two + +29 +00:02:35,830 --> 00:02:42,210 +carbons هيكونوابارشالة positive فانا لو جبت اي شيء + +30 +00:02:42,210 --> 00:02:46,250 +بده يتفاعل مع الموجب والاصل يكون سالم سمينا + +31 +00:02:46,250 --> 00:02:51,230 +نيوكليوفايل هاجم هنا النتيجة انه هيكسر هذه الرابطة + +32 +00:02:51,230 --> 00:02:55,970 +مش هيصير عنده خمس روابط فلما ييجي اي نيوكليوفايل + +33 +00:02:57,150 --> 00:03:02,150 +هاجم على هذا الكرمون هتنكسر الرابط أزواج + +34 +00:03:02,150 --> 00:03:08,050 +الألكترونات هيكون مع الـ O O minus بياخد H غالبا + +35 +00:03:08,050 --> 00:03:12,890 +الـ H هذه بتكون مع الـ nucleophile فهيصف ايش O H + +36 +00:03:12,890 --> 00:03:17,230 +او احنا بنعمل catalysis للتفاعل بـ H plus يعني + +37 +00:03:17,230 --> 00:03:22,690 +مثلا الميه فيها جزء ايه لو تشوفوا محصلة التفاعل O + +38 +00:03:22,690 --> 00:03:31,120 +H اللي هي تمثللنكليوفاي و في اتش فهذا لنكليوفاي لو + +39 +00:03:31,120 --> 00:03:38,130 +اتفعل من هنا وصف في الآخر انه حط OHL شو ضال عندكH + +40 +00:03:38,130 --> 00:03:42,870 +هتيجي وين؟ على هذه الـ O أو لو أنا كنت عامل acid + +41 +00:03:42,870 --> 00:03:47,530 +catalysis الـ H تبعت ال acid في الأساس هي اللي + +42 +00:03:47,530 --> 00:03:52,410 +بتيجي و بيطلع بدلها H plus لكن كمحصلة كمعادلة + +43 +00:03:52,410 --> 00:03:57,370 +موزونة كمعادلة موزونة لو بتتطلع على هذا المركب لو + +44 +00:03:57,370 --> 00:04:02,580 +بتتطلع على هذا المركباللي أنا بادى فيه وهذا المركب + +45 +00:04:02,580 --> 00:04:07,140 +اللى طلع عندى هتلاحظوا هى ال OH اللى اجت من الميه + +46 +00:04:07,140 --> 00:04:12,700 +وهىالـ H هيصل في ميّه إذا المعادلة بهذا الشكل + +47 +00:04:12,700 --> 00:04:17,460 +موصولة ولا لأ تماما كاربون كاربون أكسوجين وإيجي + +48 +00:04:17,460 --> 00:04:23,800 +عنده من الميّه الـ OH والـ H في كل الأحوال تفاعل + +49 +00:04:23,800 --> 00:04:28,500 +ال ring opening سهل جدا أن نطبقه بدنا نقول أن هذه + +50 +00:04:28,500 --> 00:04:35,720 +الحلقة بدأ تصير CCOH بما تحملهيعني لو كانت هنا + +51 +00:04:35,720 --> 00:04:40,080 +بتحمل H2 وهنا H2، بيظلوا زي ما هما، H و مثل وهنا + +52 +00:04:40,080 --> 00:04:43,820 +H2، بيظلوا زي ما هما، إيش ما بتحمل هنا، هدولة مش + +53 +00:04:43,820 --> 00:04:47,760 +موقع تفاعل، ما بتغيروش، أيًا كانوا، إيش ما + +54 +00:04:47,760 --> 00:04:51,200 +بيكونوا، هدول المجموعات بتغيروش، اللي بيصير عنده C + +55 +00:04:53,120 --> 00:04:58,840 +OH وهنا بدو ييجي عنده لنيوكليوفايل طبعا إذا كان + +56 +00:04:58,840 --> 00:05:05,100 +المتفاعل الماء لنيوكليوفايل OH طب إذا المتفاعل HX + +57 +00:05:05,100 --> 00:05:13,240 +لنيوكليوفايل X إذا المتفاعل RO- هيكون RO وبتيجي H + +58 +00:05:13,240 --> 00:05:18,020 +من هنا بهذا الشكل إذا الشيء المشترك هنا الشيء + +59 +00:05:18,020 --> 00:05:22,580 +المشترك هنا أنه هتشوفوا هذه القطعة + +60 +00:05:25,740 --> 00:05:37,660 +CCOH CCOH CCOH CCOH CCOH + +61 +00:05:37,660 --> 00:05:44,900 +CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH + +62 +00:05:44,900 --> 00:05:49,920 +CCOHأي مجموعات كانت موجودة عليهم اصلا يعني لو كنت + +63 +00:05:49,920 --> 00:05:53,760 +بدي انا في ال parent compound يعني هذه CH2 CH2 + +64 +00:05:53,760 --> 00:06:01,540 +هتكون النتيجة OH CH2 CH2 OH لو هدولة C مثل 2 مثل 2 + +65 +00:06:01,540 --> 00:06:09,100 +هيكون OH C مثل 2 C مثل 2 و هكذا واضح؟ بهذا الشكل + +66 +00:06:09,100 --> 00:06:15,230 +بتم التفاعد ولذلك مرات كتير لما بنشوف عندنالما + +67 +00:06:15,230 --> 00:06:20,510 +بنشوف إنه في تفاعلات موجود CH2 CH2 OH ممكن نفكر إن + +68 +00:06:20,510 --> 00:06:27,150 +هدولة إجوا من حلقة إيش Oxirane حلقة Oxirane CH2 + +69 +00:06:27,150 --> 00:06:31,190 +CH2 OH اتفاعلت مع نيوكليوفايل بيضطر نيوكليوفايل + +70 +00:06:31,190 --> 00:06:39,600 +CH2 CH2واضح؟ طبعا في حالات ممكن المجموعات اللى + +71 +00:06:39,600 --> 00:06:43,480 +موجودة على ال carbon في هدولة النقطين تكون مختلفة + +72 +00:06:43,480 --> 00:06:49,780 +يعني ممكن مثلا تلاحظوا ان هذه تكونسي أتش تو وهنا + +73 +00:06:49,780 --> 00:06:53,700 +سي أتش و سي أتش ثري و بتكون تيجي تفعله الماء + +74 +00:06:53,700 --> 00:06:57,560 +لاحظوا هتصيروا متحيرين هل يا ترى النيوكليوفايل + +75 +00:06:57,560 --> 00:07:01,540 +هتخلوه يتفعل على هذا الكربون و لا على هذا الكربون + +76 +00:07:01,540 --> 00:07:04,600 +من ناحية المبدأ هذا موجبة و هذا موجبة دائما + +77 +00:07:04,600 --> 00:07:08,560 +النيوكليوفايل هتفعل على الكربون اللي بتحمل الكربون + +78 +00:07:08,560 --> 00:07:14,230 +أكثرتعرفوا تصنيفات ال carbon primary و secondary و + +79 +00:07:14,230 --> 00:07:18,090 +tertiary حسب ما بيحمل carbons فالتفاعل على ال + +80 +00:07:18,090 --> 00:07:21,930 +carbon اللي بتحمي ال carbons أكثر بيكون مفضل يعني + +81 +00:07:21,930 --> 00:07:25,090 +في هذه الحالة لو كنا بنفعل ميه هل يا ترى ال O + +82 +00:07:25,090 --> 00:07:28,550 +هتيجي تهاجم على هذا ال carbon ولا هذا ال carbon و + +83 +00:07:28,550 --> 00:07:35,650 +هنا هيصير أن ال O أتش هذا لو مر علينامثال بهذا + +84 +00:07:35,650 --> 00:07:41,150 +الشكل طبعا في كل الأحوال لأن هذه حلقة لأن هذه حلقة + +85 +00:07:41,150 --> 00:07:46,430 +هنلاحظ ان النيوكليوفايل هيجي من جهة و ال OH هتكون + +86 +00:07:46,430 --> 00:07:51,390 +من الجهة المعاكزة واضح ان هذا بيأثر على النواتج او + +87 +00:07:51,390 --> 00:07:56,510 +لا هذا موضوع ثاني لكن الإضافة هنا بتكون sin ولا + +88 +00:07:56,510 --> 00:08:02,550 +anti additionبتكون Anti-Addition الإضافة هنا بتكون + +89 +00:08:02,550 --> 00:08:05,750 +Anti-Addition يعني الـ Nucleophile بيجي من الجهة + +90 +00:08:05,750 --> 00:08:10,270 +المعاكسة لجهة تكوّن الـ OH ملاحظين منهم Anti + +91 +00:08:10,270 --> 00:08:13,690 +-Addition؟ + +92 +00:08:13,690 --> 00:08:19,970 +الآن لاحظوا لو فكرنا مثلا أنه بدنا نضيف مجمعتين OH + +93 +00:08:21,270 --> 00:08:26,050 +من جهة واحدة يعني هذه الطريقة انه حولنا الالكين ل + +94 +00:08:26,050 --> 00:08:32,730 +ابوكسايد وفتحنا الحلقة اعطتنا مجموعتين OHمن جهتين + +95 +00:08:32,730 --> 00:08:37,370 +متعاكستين طب لو فكرنا انه بدنا نضيف المجموعتين من + +96 +00:08:37,370 --> 00:08:42,710 +جهة واحدة في عندنا تفاعل تاني ممكن نعمله مباشرة + +97 +00:08:42,710 --> 00:08:48,130 +على ال الكين و بضيف مجموعتين OH من جهة واحدة هذا + +98 +00:08:48,130 --> 00:08:54,170 +التفاعل ان نفعل ال الكين سواء مع مركب ال Osmium O4 + +99 +00:08:54,170 --> 00:08:59,340 +في وجود هذه الأشياءكتاليست او مع مركب كيامان O4 + +100 +00:08:59,340 --> 00:09:03,540 +بيرمانجانات البوتاسيوم سواء قلنا أزوميام الأزوميام + +101 +00:09:03,540 --> 00:09:08,320 +عنصر معدن ثقيل تقريبا هو أثقل العناصر يعني كثافته + +102 +00:09:08,320 --> 00:09:14,300 +أعلى حتى من الدهب واشي فوق العشرين جرام لكل سنتمتر + +103 +00:09:14,300 --> 00:09:21,180 +مكعبواضح؟ سواء قلنا Osmium O4 او KMnO4 انا بحكي عن + +104 +00:09:21,180 --> 00:09:27,520 +معدل مثل ال مثل Osmium او مانجانيز وهذا متصل بكم + +105 +00:09:27,520 --> 00:09:32,990 +مجموعة Oهيبقى أربعة، الآن لما بديجي يتفاعل مع + +106 +00:09:32,990 --> 00:09:36,310 +double bond لما بديجي يتفاعل مع double bond هي + +107 +00:09:36,310 --> 00:09:40,650 +double bond أكيد هيتفاعل من خلال أكسجنتين موجودات + +108 +00:09:40,650 --> 00:09:45,630 +على جهة واحدة و بعد هيك تنكسر هذه الرابطة مع + +109 +00:09:45,630 --> 00:09:51,530 +المعدنتم التفاعل بهذا الشكل هذي هتاخد من مجمل + +110 +00:09:51,530 --> 00:09:58,130 +التفاعل HOOH أكيد أجه من جهة واحدة فالتفاعل هذا + +111 +00:09:58,130 --> 00:10:02,150 +بتتم من جهة واحدة لأنه بإمكانكوا ببساطة تتخيلوا + +112 +00:10:02,150 --> 00:10:08,050 +الكيامان O4 زي هيك هاي .. هاي الأربع ذرات أكسوجين + +113 +00:10:08,050 --> 00:10:12,680 +اللي موجودين فيه الآن بدو يهاجم ع double bondبيقدر + +114 +00:10:12,680 --> 00:10:17,060 +يهاجم من جهتين؟ لأ بالتاكيد هيهاجم من هنا و من هنا + +115 +00:10:17,060 --> 00:10:22,500 +حذرتين أكسجين من جهة واحدة فإضافة مجموعات ال OH + +116 +00:10:22,500 --> 00:10:28,220 +باستعمال ال Osmium O4 أو الكيامان O4 في وجود طبعا + +117 +00:10:28,220 --> 00:10:32,000 +ما basic medium كل الأشياء اللي أمامكم هو عبارة عن + +118 +00:10:32,000 --> 00:10:37,040 +sin ولا anti addition؟ sin addition ابهيك بنذكر + +119 +00:10:37,040 --> 00:10:40,580 +إيش الأشياء اللي بتصيروا ماخدينها sin addition؟ + +120 +00:10:42,290 --> 00:10:49,270 +إضافة الـ hydrogen و إضافة مجموعات ال OH باستعمال + +121 +00:10:49,270 --> 00:10:54,710 +ال Osmium O4 أو الكيامان O4 لما أخدنا إضافة ال PR2 + +122 +00:10:54,710 --> 00:11:00,150 +أخدناها Anti addition لما أخدنا إضافة ال PR2 + +123 +00:11:00,150 --> 00:11:06,290 +أخدناها Anti addition مش Sin addition واضح؟ ولذلك + +124 +00:11:06,290 --> 00:11:12,720 +لو مثلا جيبنا لكم مركب زي هذاخلنا ناخد مثال + +125 +00:11:12,720 --> 00:11:17,540 +Cyclopentane + +126 +00:11:17,540 --> 00:11:26,060 +طبعا ك Cyclopentane شو عليها؟H وH وسألناكم سؤال + +127 +00:11:26,060 --> 00:11:31,280 +قلنا لكم كيف ممكن تحضروا من هذا Cyclobentane + +128 +00:11:31,280 --> 00:11:37,540 +Cyclobentadiol يعني Cyclobentane شيلنا منه ال + +129 +00:11:37,540 --> 00:11:40,900 +double bond و حاطينا مجموعتين OH يعني بدل ال + +130 +00:11:40,900 --> 00:11:44,780 +double bond مجموعتين OH مرة يكونوا ال cis و مرة + +131 +00:11:44,780 --> 00:11:49,600 +يكونوا ال trans كأنه بيصير السؤال انه كيف بدي احضر + +132 +00:11:49,600 --> 00:11:59,490 +منههذا المُركّب اللي فيه مجموعتين الـ OH على جهة + +133 +00:11:59,490 --> 00:12:06,270 +واحدة و بدي أحضر منه أيضا المُركّب اللي فيه + +134 +00:12:06,270 --> 00:12:11,930 +مجموعتين الـ OH على جهتين متعاكستين اللي هم الـ + +135 +00:12:11,930 --> 00:12:13,330 +CIS والـ Trans + +136 +00:12:18,820 --> 00:12:21,820 +واضح؟ how can you prepare this is and + +137 +00:12:21,820 --> 00:12:27,060 +transcyclobentane diol starting from cyclobentene + +138 +00:12:27,060 --> 00:12:32,960 +الان في الحالة الأولى الجواب مباشر في الحالة + +139 +00:12:32,960 --> 00:12:37,040 +الأولى الجواب مباشر بدى استعمل اما طريقة ال + +140 +00:12:37,040 --> 00:12:41,760 +ozomium o4 او ال camon o4 نفس الشيء خلنا نقول مثلا + +141 +00:12:41,760 --> 00:12:49,610 +camon o4 فيباسيك ميديام في وجود الماء ألاحظوا + +142 +00:12:49,610 --> 00:12:54,210 +انتبهوا جيدا لو سمحتوا الكيامان اوفور عشان تعمل + +143 +00:12:54,210 --> 00:12:57,910 +هذا التفاعل و تضيف من جهتين بدا تكون في basic + +144 +00:12:57,910 --> 00:13:02,550 +medium في وجود OH- هذه بديكوا تركزوا عليها لسبب + +145 +00:13:02,550 --> 00:13:06,590 +بسيط انه في تفاعلات تانية سواء درسناها او + +146 +00:13:06,590 --> 00:13:10,850 +مادرسناهاش تفاعل الكيامان اوفور في acidic medium + +147 +00:13:10,850 --> 00:13:16,780 +بيعطيني أشياء تانيةواضح فركزوا ان هذا التفاعل بتم + +148 +00:13:16,780 --> 00:13:22,320 +في basic و medium الان لو قولنا المركب التاني كيف + +149 +00:13:22,320 --> 00:13:30,080 +بدنا نحضره على خطوتين اذا + +150 +00:13:30,080 --> 00:13:34,740 +انا في الاول بدي اجي اقول bare acid مثلا فينيل + +151 +00:13:34,740 --> 00:13:39,580 +COOOH و + +152 +00:13:39,580 --> 00:13:44,720 +استعمل و يعطيني ال ابوكسايدو بعدين بوجود ال .. + +153 +00:13:44,720 --> 00:13:49,480 +بساط حمضي مع .. هاي ال Evoxide واضح؟ أخدنا هذا + +154 +00:13:49,480 --> 00:13:54,440 +التفاعل بيصير Cyclopentene + +155 +00:13:54,440 --> 00:14:01,080 +Oxide و بعد هيك لما أجي أفعله مع ال H2O H plus + +156 +00:14:01,080 --> 00:14:05,300 +بيعمل ring opening O H بتيجي من هنا O Hواحدة من + +157 +00:14:05,300 --> 00:14:08,600 +التحت وواحدة من الفوق إذا هذا التفاعل بتتم على + +158 +00:14:08,600 --> 00:14:12,860 +خطوة ولا على خطوة إيه؟ على خطوة إيه؟ هذا التفاعل + +159 +00:14:12,860 --> 00:14:24,220 +على خطوة واحدة واضح + +160 +00:14:24,220 --> 00:14:24,960 +المثال؟ + +161 +00:14:48,060 --> 00:14:52,220 +من التفاعلات اللى بدنا ندرسها ايضا لل Alkanes + +162 +00:14:52,220 --> 00:14:59,040 +تفاعل جديد الان مش تفاعل اضافة تفاعل bond cleavage + +163 +00:14:59,040 --> 00:15:03,480 +بمعنى بيكسر ال double bond نصين يعني اتطلعوا معاه + +164 +00:15:03,480 --> 00:15:07,000 +هذي ال double bond التفاعل اللى بدنا ندرسه الان + +165 +00:15:07,000 --> 00:15:11,800 +بدوش يضيف حوله من double ل single كل ما درسناه كان + +166 +00:15:11,800 --> 00:15:16,180 +addition reactions لحد الان كل ما درسناه كان + +167 +00:15:16,180 --> 00:15:19,970 +addition double bondتصير single bond الآن بدنا + +168 +00:15:19,970 --> 00:15:23,590 +ناخد نوع تاني من تفاعلات ال double bond اللي هو + +169 +00:15:23,590 --> 00:15:27,030 +cleavage reaction ان اجعل double bond و اكسرها + +170 +00:15:27,030 --> 00:15:32,950 +نصين هذا التفاعل بنسميه ozonolysis of alkenes وزي + +171 +00:15:32,950 --> 00:15:38,750 +ما قلت هو تفاعل ايشCleavage تفاعل كسر بيكسر ال + +172 +00:15:38,750 --> 00:15:43,010 +double bond نصين بتم هذا التفاعل من خلال التفاعل + +173 +00:15:43,010 --> 00:15:48,210 +مع ال ozone بتعرفوا ال ozone الأكسجل في الطبيعة O2 + +174 +00:15:48,210 --> 00:15:52,810 +وإله ألوتروب بنسميها أو صورة تقاصلية تانية يعني + +175 +00:15:52,810 --> 00:15:58,070 +صورة فيزيائية تانية اسمها ايش ozone زي ما الكربون + +176 +00:15:58,070 --> 00:16:02,960 +في الطبيعة بنوجد على شكلGraphite و Diamond و + +177 +00:16:02,960 --> 00:16:09,080 +Carbon-60 او زي ما الفوسفور مثلا في الطبيعة فوسفور + +178 +00:16:09,080 --> 00:16:13,220 +أبيض فوسفور أحمد هذه صورة فيزيائية للمادة لنفس + +179 +00:16:13,220 --> 00:16:17,840 +المادة الآن ال Oxygen في الطبيعة ممكن ينوجد على + +180 +00:16:17,840 --> 00:16:22,860 +شكل Oxygen عادي O2 و ممكن ينوجد على شكل Ozone اللي + +181 +00:16:22,860 --> 00:16:27,540 +عادة موجود في الاطسفير في طبقات الجو العليا و + +182 +00:16:27,540 --> 00:16:33,380 +بعدينبتعرف مشكلة الأوزون لو فعلنا هذا المُركّب مع + +183 +00:16:33,380 --> 00:16:39,220 +الأوزون بداية وبعدين مع زنك في وجود حامض بيكوّنلنا + +184 +00:16:39,220 --> 00:16:42,440 +مُركّب وسيط مش كثير محتم أننا نحفظه أوزونويت + +185 +00:16:42,440 --> 00:16:48,260 +بنسميه هذه الأوزون التلاتة وبعد هيك بتكسر الرابطة + +186 +00:16:48,260 --> 00:16:53,710 +اللي هي بين الكاربون والكاربون هذهDouble bond + +187 +00:16:53,710 --> 00:16:57,470 +بتصير هنا C double bond O وهذه بتصير C double bond + +188 +00:16:57,470 --> 00:17:04,250 +O يعني الكسر من وين هيتملما نجي نفذ الناتج مش كل + +189 +00:17:04,250 --> 00:17:07,350 +مرة بدنا نكون عارفين ال intermediate ناخدها لمرة + +190 +00:17:07,350 --> 00:17:11,650 +واحدة لكن أنا بدي أنفذ أكتب الناتج بدي أجي أتخيل + +191 +00:17:11,650 --> 00:17:16,290 +أنه معي مساحة كسرت الرابطة من هنا هذه هتصير C + +192 +00:17:16,290 --> 00:17:22,690 +double bond O وهذه هتصير C double bond O هيعطيني + +193 +00:17:22,690 --> 00:17:25,570 +تنتين C double bond O لاحظوا الناتج هنا هذه + +194 +00:17:25,570 --> 00:17:32,150 +البنزينة وحملة CH وإيش صارتC double bond O وهنا + +195 +00:17:32,150 --> 00:17:38,270 +عندكم CH2 إيش صارت كمان C double bond O ولو مش + +196 +00:17:38,270 --> 00:17:45,930 +واضحين الروابط فببساطة تفاعل مع الأوزون و بعده + +197 +00:17:45,930 --> 00:17:51,830 +زنكمية هو حقيقة بيحول لل carbon carbon double bond + +198 +00:17:51,830 --> 00:17:57,800 +لتنتين C double bond O يعني بديكوا تتخيلوابهذا + +199 +00:17:57,800 --> 00:18:02,640 +الشكل كان عندكم carbons بغض النظر إيش موجود عندي + +200 +00:18:02,640 --> 00:18:08,460 +هنا ممكن اتش اتش اتش مثل فلل إيش مكان يكون بتخلوه + +201 +00:18:08,460 --> 00:18:12,400 +زي ما هو مش موضوعكم افترضوا قلنالكوا بدنا ناتج ال + +202 +00:18:12,400 --> 00:18:16,860 +ozonolesis لهذا التفاعل إيش أسهل طريقة عشان تنفذوا + +203 +00:18:16,860 --> 00:18:24,160 +الجواب تتخيلوا أنه كسرنا هذه الرابطة واضح؟ و هنا + +204 +00:18:24,160 --> 00:18:28,590 +حطينا O و هناأو نتيجة + +205 +00:18:31,420 --> 00:18:37,520 +هك انا بعمل ناتج ال ozoneolysis الان انه اكون عندى + +206 +00:18:37,520 --> 00:18:41,560 +اى مجموعة هنا مابفرقش عندى لكن بكل الاحوال لو + +207 +00:18:41,560 --> 00:18:45,920 +افترضت عندى carbon و carbon هيطلع عندى كيتون لو + +208 +00:18:45,920 --> 00:18:49,580 +افترضت عندى carbon و hydrogen او تنتين هيدروجين + +209 +00:18:49,580 --> 00:18:54,000 +هيطلع عندى الديهيد اذا هذا تفاعل ال ozoneolysis في + +210 +00:18:54,000 --> 00:18:59,340 +النهاية لو بدأ اقولكوا شو احتمالات نواتجهالديهيد + +211 +00:18:59,340 --> 00:19:04,280 +او كيتون او + +212 +00:19:04,280 --> 00:19:10,200 +كيتون + +213 +00:19:10,200 --> 00:19:12,040 +او كيتون او كيتون او كيتون او كيتون او كيتون او + +214 +00:19:12,040 --> 00:19:12,040 +كيتون او كيتون او كيتون او كيتون او كيتون او كيتون + +215 +00:19:12,040 --> 00:19:12,140 +او كيتون او كيتون او كيتون او كيتون او كيتون او + +216 +00:19:12,140 --> 00:19:12,600 +كيتون او كيتون او كيتون او كيتون او كيتون او كيتون + +217 +00:19:12,600 --> 00:19:13,180 +او كيتون او كيتون او كيتون او كيتون او كيتون او + +218 +00:19:13,180 --> 00:19:13,220 +كيتون او كيتون او كيتون او كيتون او كيتون او كيتون + +219 +00:19:13,220 --> 00:19:15,260 +او كيتون او كيتون او كيتون او كيتون او كيتون او + +220 +00:19:15,260 --> 00:19:21,580 +كيتون او كيتون او كيتون او كيتونأيضا الديهايد + +221 +00:19:21,580 --> 00:19:25,860 +الديهايد يعرف ب H واحدة و أبسط الديهايد في الدنيا + +222 +00:19:25,860 --> 00:19:29,660 +ال form الديهايد اللي فيه H و H تنتيل فوجود H + +223 +00:19:29,660 --> 00:19:34,320 +واحدة بيخل المركب إيش اسمه الديهايد الآن التانية + +224 +00:19:34,320 --> 00:19:38,120 +تكون H بيكون أبسط الديهايد التانية تكون مثل إثل + +225 +00:19:38,120 --> 00:19:43,820 +فنل بروبل أي مجموعة بيظلواالديهيد ايضا فنتج ال + +226 +00:19:43,820 --> 00:19:49,580 +اوزونوليسيس بيعطي الديهيد او كيتون باستخدام + +227 +00:19:49,580 --> 00:19:55,380 +الاشتراكات على الدبل بوند اعتمادا على الاشتراكات + +228 +00:19:55,380 --> 00:19:58,600 +على الدبل بوند الان هي هذا على طول لما واحدة بتطلع + +229 +00:19:58,600 --> 00:20:03,500 +هتلاحظ ايش اعطانا هنا الديهيد اكيد لان الدبل بوند + +230 +00:20:03,500 --> 00:20:08,910 +عليها اتش وهنا نور على نور الدبل بوند عليهاتنتين H + +231 +00:20:08,910 --> 00:20:13,670 +إذا أيضا بالتأكيد الديهايد وإن كان أبسط الديهايد + +232 +00:20:13,670 --> 00:20:17,890 +لكن لو أي طرف عليه تنتين كاربون من عند هذا الطرف + +233 +00:20:17,890 --> 00:20:25,070 +هيعطيه كيتون هاي أمثلة عندنا تطلع عليها في كل + +234 +00:20:25,070 --> 00:20:32,450 +الأحوال من أين ستكسر الرابط من + +235 +00:20:32,450 --> 00:20:38,340 +النص الرابط بنكسرها من النصبدون ما نتطلع على + +236 +00:20:38,340 --> 00:20:41,860 +الجواب لو إجينا سألنا هذا الناتج بيعطي إيش + +237 +00:20:41,860 --> 00:20:46,840 +الديهايد الكربون هذي حملة H at least و هذا + +238 +00:20:46,840 --> 00:20:53,920 +الديهايد و الديهايد هنا T ليش المخفي شو هو؟ بديش + +239 +00:20:53,920 --> 00:21:01,300 +أبقى أتعب معكم كل ما لم يكتب فهو H طيب إذا من هذه + +240 +00:21:01,300 --> 00:21:07,430 +الجهة شو بيعطيه؟ و من هذه الجهةكيتون هذه كل رأس + +241 +00:21:07,430 --> 00:21:12,850 +يعتبر carbon الان هذه بنكسرها ايضا من النص بتصير + +242 +00:21:12,850 --> 00:21:17,590 +هنا C double bond O وهنا C double bond O اكيد هذه + +243 +00:21:17,590 --> 00:21:23,170 +كيتون وهنا فيه H مخفية كيتون + +244 +00:21:23,170 --> 00:21:27,250 +والدايت لاحظوا هذا ماعطاش جزي ايه لكن كسر الرابط + +245 +00:21:27,250 --> 00:21:34,720 +بنفس المنطق هذا نفس الشي تماما لاحظوا هنا فيهأتش و + +246 +00:21:34,720 --> 00:21:38,160 +هنا فيه اتش خلو ادي سيضه بالبندقه و ادي سيضه + +247 +00:21:38,160 --> 00:21:42,200 +بالبندقه بس هو بعد هيك بدل ما الجزيئ يكتبوا عامل + +248 +00:21:42,200 --> 00:21:51,680 +زي هيك فرضه اعطاه نفس حرام يعني هذا بمش هو احنا + +249 +00:21:51,680 --> 00:21:54,940 +ليش بنعلمكوا ان الجزيئات بتتغير زي ما البني ادم + +250 +00:21:54,940 --> 00:21:58,340 +بياخد ميت صورة يعني هذا لو كان بدوا يكتبوا + +251 +00:21:58,340 --> 00:22:00,420 +بالطريقة اللي انتوا فاهمينها + +252 +00:22:03,590 --> 00:22:09,470 +عمل هيك و هيك زي هيك مبين سهل و اين كسرت الرابطة + +253 +00:22:09,470 --> 00:22:16,030 +الان بعد هيك انفرض زي ما الجنيل بيكون متكور في بطن + +254 +00:22:16,030 --> 00:22:25,570 +امه هذا هو هداك هذا المركب هو هذا المركب اليوم + +255 +00:22:25,570 --> 00:22:30,250 +انا باعطي ناتج تفاعل طالما الديهايد او كيتون موطعه + +256 +00:22:30,250 --> 00:22:35,750 +شبتر 9عشان أسميهم، مش اليوم، واضح؟ في طريقة + +257 +00:22:35,750 --> 00:22:44,970 +لتسميتهم ما سُكِت عنه يُصبر عليه، واضح؟ + +258 +00:22:44,970 --> 00:22:51,710 +الآن + +259 +00:22:51,710 --> 00:22:58,890 +من أمثلة ومن تفاعلاتالالكينز أيضا تفاعل مهم جدا في + +260 +00:22:58,890 --> 00:23:02,110 +الحياة التطبيقية العملية وفي الحياة الصناعية + +261 +00:23:02,110 --> 00:23:06,190 +بنسميه احنا free radical polymerization of + +262 +00:23:06,190 --> 00:23:10,290 +ethylene ايش احنا اللي بنقصده في polymerization + +263 +00:23:10,290 --> 00:23:16,030 +بتعرف بيكون عندنا جزء واحد من المادة هذا الجزء + +264 +00:23:16,030 --> 00:23:23,180 +الواحد من المادة ممكن نسميه احنا monomerمونومر جزء + +265 +00:23:23,180 --> 00:23:29,500 +واحد الان لو عملت اتنين بيصير دايمر اتنين دايمر + +266 +00:23:29,500 --> 00:23:37,760 +تلاتة اترايمر اربعة تترامر تلت اربع مية تلت اربع + +267 +00:23:37,760 --> 00:23:45,410 +تلاف وقتها بوليمرطب مش من أولها polymer لأ إذا + +268 +00:23:45,410 --> 00:23:50,130 +إحنا لو كنا بنقول الجزء الواحد إيش بنقوله؟ monomer + +269 +00:23:50,130 --> 00:23:58,750 +اتنين دايمر تلاتة ترايمر أربعة تترامر + +270 +00:24:02,660 --> 00:24:08,120 +بوليمر يعني البوليمر بيكون تلت اربعميت جزيء خمسمية + +271 +00:24:08,120 --> 00:24:11,960 +احيانا تلت تلاف احيانا حسب طبيعة المواد خمسين الف + +272 +00:24:11,960 --> 00:24:15,680 +ميت الف بيكونوا كلهم مار بعض هذا اللي بنسميه + +273 +00:24:15,680 --> 00:24:20,420 +بوليمر مش تلاتة واربعة واضح فالواحد والاتنين + +274 +00:24:20,420 --> 00:24:24,770 +والتلاتة دول علهم أسماء لكن لما بيكون كبيربصير + +275 +00:24:24,770 --> 00:24:30,390 +عنده الـ Polymer الان إذا تخيلتوا ان هذا جزء + +276 +00:24:30,390 --> 00:24:36,310 +إيثالين إيثالين والإيثالين غاز و إجينا على هذا + +277 +00:24:36,310 --> 00:24:45,400 +الإيثالين و حطناه معبروكسايد تحت ضغط مرتفع جدا جدا + +278 +00:24:45,400 --> 00:24:51,160 +جدا الف أتمسفير عشان تخافوا من كلمة الف أتمسفير + +279 +00:24:51,160 --> 00:24:56,300 +يعني تقدروا تتخيلوا شوها الضغط الكبير بس تذكروا أن + +280 +00:24:56,300 --> 00:25:00,400 +طنجرة الضغط اللي بتطبخوا فيها و اللي بتكون تصفروا + +281 +00:25:00,400 --> 00:25:06,620 +و بتخوف الضغط فيها اتنين أتمسفير فقط + +282 +00:25:07,930 --> 00:25:12,510 +الضغط فيها دي طنجرة الضغط اتنين atmosphere فانا + +283 +00:25:12,510 --> 00:25:16,650 +لما بحكي عن الف atmosphere بيمكنكم تخيلوا الضغط + +284 +00:25:16,650 --> 00:25:21,410 +طبعا اكيد هذا التفاعل مابنعملش بجزاز ولا بحديد + +285 +00:25:21,410 --> 00:25:25,050 +بسيط بيكون عندكوا اوعية stainless steel الوعاء + +286 +00:25:25,050 --> 00:25:28,450 +يمكن عرضه اتنين تلاتة سانت stainless steel ومكابس + +287 +00:25:28,450 --> 00:25:34,820 +هيدروليكية هذا شغل صناعةمش شغل مختبر، الآن بيجيبوا + +288 +00:25:34,820 --> 00:25:42,310 +الغاز، بنحطه غاز، بنحط عليه ال ..البروكسايتز هذه + +289 +00:25:42,310 --> 00:25:46,030 +عند ألف أتمسفير وبنسخن عند مئة درجة مئوية بنضغط + +290 +00:25:46,030 --> 00:25:50,210 +الغاز بندخل جزيئات الغاز، لاحظوا غاز، بندخل + +291 +00:25:50,210 --> 00:25:55,970 +جزيئاته في بعضها طالما كبر المركب، هيتحول لإيش؟ + +292 +00:25:55,970 --> 00:26:00,110 +لصلب، مش بزيادة ال molecular weight كنا نتحول من + +293 +00:26:00,110 --> 00:26:03,930 +غاز لسائل لصلب، هيتحول ل polymer، هذا ال polymer + +294 +00:26:03,930 --> 00:26:08,470 +هو plasticهو نوع من ال plastic اللي احنا بنستعمله + +295 +00:26:08,470 --> 00:26:14,410 +بنسميه polyethylene فال ethylene بكل هذه الشروط + +296 +00:26:14,410 --> 00:26:18,450 +بيصير CH2 CH2 to the N لحظة لغية ال double bond + +297 +00:26:18,450 --> 00:26:23,570 +خلتها single bond لغية ال double bond و خلتها + +298 +00:26:23,570 --> 00:26:30,530 +single bond في هذه الحالة صارالإيثالين بولي + +299 +00:26:30,530 --> 00:26:34,570 +إيثالين طبعا في ميكانيزم للتفاعل مش كتير بتفرج + +300 +00:26:34,570 --> 00:26:38,910 +عنده البولي إيثالين هو البلاستيك الأبيض إذا دخلتوا + +301 +00:26:38,910 --> 00:26:42,050 +على المختبرات بتلاحظوا في عندكم جلانات بنعب فيها + +302 +00:26:42,050 --> 00:26:46,330 +ميا ديستيلد ووتر wash bottles أشياء كل هذه عبارة + +303 +00:26:46,330 --> 00:26:49,490 +عن بولي إيثالين الأوعية اللى بنحط فيها هيدروكسيد + +304 +00:26:49,490 --> 00:26:53,050 +الصوديوم بتشوفوا ال .. ال bottle اللى بنكون معبينه + +305 +00:26:53,050 --> 00:27:00,100 +محلولا كل هذه عبارة عن إيش بولي إيثالينالان بنفس + +306 +00:27:00,100 --> 00:27:03,820 +المنطق، شوفوا كيف العلم بتطور، يعني أول ما بدأنا + +307 +00:27:03,820 --> 00:27:07,280 +عملنا Polymer عملنا إيش؟ الـ Ethylene و عملنا له + +308 +00:27:07,280 --> 00:27:12,200 +Polymerization إلى Polyethylene طيب هم قالوا لازم + +309 +00:27:12,200 --> 00:27:16,400 +هدول الأربعة يكونوا Hydrogen و Hydrogen يعني CH2 + +310 +00:27:16,400 --> 00:27:22,400 +CH2 لو يا ترى بدلنا واحدة منهمبكلور هنا هنا شيلنا + +311 +00:27:22,400 --> 00:27:28,860 +واحدة بالغلط صار CH CH2CL وكان double bond وعملنا + +312 +00:27:28,860 --> 00:27:33,800 +منه ال polymer هتصير single bond طب هذا المركب + +313 +00:27:33,800 --> 00:27:42,680 +الأصلي CH2 double bond CHCL أخدنا اسمه vinyl + +314 +00:27:42,680 --> 00:27:47,480 +chloride هذه مجموعة ال vinylVinyl chloride اللي + +315 +00:27:47,480 --> 00:27:51,760 +قال لو اعملت منه بوليمار بنفس المنطق تبع الاثيلين + +316 +00:27:51,760 --> 00:27:58,640 +الغط بابل بوند و اكتبه to the end طالما هذا Vinyl + +317 +00:27:58,640 --> 00:28:03,960 +chloride Vinyl chloride شو هيصير البوليمار تبعه + +318 +00:28:03,960 --> 00:28:08,320 +بولي و Vinyl chloride اتخيلوا لو بدنا نختصر اسم + +319 +00:28:08,320 --> 00:28:14,300 +البوليمار تبعه BVC + +320 +00:28:15,850 --> 00:28:23,430 +مين ما بعرفش ال PVC؟ كل شناتكم PVC، كل بلاستيك + +321 +00:28:23,430 --> 00:28:27,310 +المحووتكم PVC، كل المواسير اللي بتشوفوها اللي + +322 +00:28:27,310 --> 00:28:30,810 +بنستعملها لتمديدات الصرف الصحي، المواسير + +323 +00:28:30,810 --> 00:28:35,750 +البردجانية والسكنية، لو جربت عليها، مكتوب عليها + +324 +00:28:35,750 --> 00:28:36,230 +PVC + +325 +00:28:39,480 --> 00:28:43,960 +Polyvinyl chloride اللي بيعملوها أرضيات أحيانا + +326 +00:28:43,960 --> 00:28:48,820 +بيغطوا فيها البلاط ممكن تشوفوها أحيانا في صالونات + +327 +00:28:48,820 --> 00:28:53,200 +لحلاجة في المستشفى أرضية بلاستيك و بيلزجوها فوق كل + +328 +00:28:53,200 --> 00:28:59,900 +بلاط الغرفة هذه PVC فال PVC موجود وبشكل كبير في + +329 +00:28:59,900 --> 00:29:05,640 +الحياة التطبيقيةزي وزي البولي إيثالين الآن لاحظوا + +330 +00:29:05,640 --> 00:29:09,540 +إذا صارت القصة إن أغير واحدة من الهيدروجين وحطيت + +331 +00:29:09,540 --> 00:29:14,960 +كلور لما كانت هيدروجين بولي إيثالين لما كانت كلور + +332 +00:29:14,960 --> 00:29:21,020 +PVC أو بولي فينيلي كلورايت طب لو خلناها بنزينة + +333 +00:29:22,360 --> 00:29:28,720 +المُركّب الأصلي سيكون CH2 double bond CH حملة + +334 +00:29:28,720 --> 00:29:34,920 +بنزينة أو phenyl اسمه styrene اسمه styrene لما + +335 +00:29:34,920 --> 00:29:41,130 +أعمل منه polymerإيش بده يصير؟ Polystyrene لما أعمل + +336 +00:29:41,130 --> 00:29:45,690 +منه polymer هيصير polystyrene إذا التفاعل مش بس + +337 +00:29:45,690 --> 00:29:50,390 +خاص بال إيثيلين لأ اتطور على مواد تانية و كل هذه + +338 +00:29:50,390 --> 00:29:54,310 +عبارة عن أنواع من ال plastic موجودة في السوق و + +339 +00:29:54,310 --> 00:29:59,950 +بتلباع و بتعامل فيها الناس و أفرجناكوا تطبيقيا وين + +340 +00:29:59,950 --> 00:30:02,430 +بتستعمل واضحة هذه الفكرة؟ + +341 +00:30:05,100 --> 00:30:09,380 +إذا هاي كمان تفاعل تاني لل ال keys يعني كأنها + +342 +00:30:09,380 --> 00:30:14,560 +بنصير كتفاعلات أساسية أخدنا الإضافة أخدنا ال + +343 +00:30:14,560 --> 00:30:18,340 +cleavage اللي هو ال ozoneolysis و أخدنا ال + +344 +00:30:18,340 --> 00:30:24,690 +polymerization أنه بيعمل polymer كبيرطبعا الله + +345 +00:30:24,690 --> 00:30:29,510 +يعطيكوا العافية بالنسباله ال Alkenes طب لو انتقلنا + +346 +00:30:29,510 --> 00:30:35,130 +لل Alkynes هتلاحظوا أنه بشكل أساسي تفاعلات شبيهة + +347 +00:30:35,130 --> 00:30:41,710 +الأساس فيها الإضافة ولكن لاحظوا معي لما أبدأ أحكي + +348 +00:30:41,710 --> 00:30:47,590 +عن ال Alkynes ال Alkynes تلت روابط carbon ال + +349 +00:30:47,590 --> 00:30:52,230 +triple bond carbon إذا لو بده يبدأ يضيف إيش + +350 +00:30:52,230 --> 00:30:56,740 +هيتحول؟لـ carbon double bond carbon وكمان خطوة + +351 +00:30:56,740 --> 00:31:02,560 +carbon single bond carbon إذا الإضافة هنا يمكن أن + +352 +00:31:02,560 --> 00:31:07,820 +تتم على مراحل يعني ال triple bond تصير double bond + +353 +00:31:07,820 --> 00:31:12,020 +تصير single bond مرات حسب شروط التفاعل وهذا اللي + +354 +00:31:12,020 --> 00:31:15,820 +بتكون تنتبهوله ممكن نخل التفاعل يجف لهنا بنص + +355 +00:31:15,820 --> 00:31:19,700 +الطريق يعني ال triple تصير double و يجف التفاعل + +356 +00:31:19,700 --> 00:31:26,830 +مرات بيستمرمرات ما بنقدرش نفصل المركب اللي بالوسط + +357 +00:31:26,830 --> 00:31:31,150 +يعني مجرد ما نحط عليه المادة التانية بيصير double + +358 +00:31:31,150 --> 00:31:36,450 +bond و بسرعة كبيرة بيظلوا محول لإيش ل single bond + +359 +00:31:36,450 --> 00:31:40,070 +بعمل إضافة تانية طبعا هنا كام إضافة بيصير لو قلت + +360 +00:31:40,070 --> 00:31:46,750 +من triple ل single bond إضافتين إضافتين يعني لو + +361 +00:31:46,750 --> 00:31:53,720 +قعد بضيف HCl مش لغاية double bond شو حطيت؟ Hطب + +362 +00:31:53,720 --> 00:31:56,880 +هدولة كيف بدي أضيفهم؟ حسب قاعدة Markov Nikov ولا + +363 +00:31:56,880 --> 00:32:00,720 +ضد؟ إذا كانوا مع ال H Plus حسب قاعدة Markov Nikov + +364 +00:32:00,720 --> 00:32:06,340 +يعني اتخيلتوا هذه H وهذه CH3 وين هتيجي ال H؟ على + +365 +00:32:06,340 --> 00:32:13,940 +الحاملة ال H أكتر وين هتيجي التانية؟ واضح؟ أه بعد + +366 +00:32:13,940 --> 00:32:18,780 +هيك لو بدي أضيف كمان مرة سرادة ال K أخدنا كيف بضيف + +367 +00:32:18,780 --> 00:32:24,780 +ال K على هذا؟ هتيجي ال H هنا؟و ال CL هنا وجدت كأنه + +368 +00:32:24,780 --> 00:32:30,020 +ضفت التنتين هيدروجين على نفس الكربون وهي + +369 +00:32:30,020 --> 00:32:36,120 +الهيدروجين الأصلية والتنتين CL على نفس الكربون وهي + +370 +00:32:36,120 --> 00:32:42,660 +CH3 خلّينا الطول الأصلية إذا التفاعل هنا تم على + +371 +00:32:42,660 --> 00:32:48,600 +مرحلة ولا مرحلتين؟ ع مرحلتين كل مرحلة منهم تمت حسب + +372 +00:32:48,600 --> 00:32:54,750 +قاعدة Markov-Nikov لما أضيف HCL في وجودالـ H plus + +373 +00:32:54,750 --> 00:33:00,150 +واضح؟ كل مرحلة منهم بتتم حسب قاعدة ماركو بيه + +374 +00:33:00,150 --> 00:33:05,190 +خلّينا نشوف هذا الكلام بالتفصيل بعض الإضافات بعض + +375 +00:33:05,190 --> 00:33:09,850 +تفاؤلات الإضافة للالكينز لاحظوا هاي أول مثال + +376 +00:33:09,850 --> 00:33:18,490 +addition of HX to alkynes هاي عندي كاربون بتحمل H + +377 +00:33:18,490 --> 00:33:25,510 +وكاربون بتحمل إيش H وضفت ال HClضعفين كيف هيكون + +378 +00:33:25,510 --> 00:33:30,630 +الناتج الأخير انه هضيف مرتين ال H هنا و هنا و + +379 +00:33:30,630 --> 00:33:33,590 +مرتين ال CL هنا و هنا هذه الناتج الأخيرة بس + +380 +00:33:33,590 --> 00:33:39,030 +بالتأكيد اول ما بيبدأ اضيف الإضافة الأولى إجت هنا + +381 +00:33:39,030 --> 00:33:44,270 +H و إجت هنا CL و الإضافة التانية إجت هنا كمان H و + +382 +00:33:44,270 --> 00:33:52,640 +هنا كمان CL واضح فمرتين حسب قاعدةماركوف نيكوف + +383 +00:33:52,640 --> 00:33:56,380 +اديشن الان + +384 +00:33:56,380 --> 00:34:04,360 +لو كنت بدى اضيف لبروم لبروم بضيف Anti addition + +385 +00:34:04,360 --> 00:34:11,540 +المرة الأولى هين اضفت PR و PR عكس بعضه اعطانى + +386 +00:34:11,540 --> 00:34:18,660 +الالكيل كمان مرة يعني كأنه هى ال PR 2 الأول وهىالـ + +387 +00:34:18,660 --> 00:34:23,020 +PR2 التالي كمان مرة حديث من هنا و من هنا صار عندى + +388 +00:34:23,020 --> 00:34:27,420 +أربع ذرات إبروم فلاحظوا لو أنا كنت كاتب زيكوا و + +389 +00:34:27,420 --> 00:34:34,380 +كاتبلكوا 2PR2 شو ناتج النهاية اللى بدى أكتبه ال + +390 +00:34:34,380 --> 00:34:39,700 +كان أو ال كان ال كان ال كان بالإنجليزي ال كان + +391 +00:34:39,700 --> 00:34:45,890 +بالعربي ال كان بالإنجليزي ماختلفناهاش كتيرالان من + +392 +00:34:45,890 --> 00:34:52,230 +التفاعلات المهمة ايضا تفاعل اضافة الميه بس اضافة + +393 +00:34:52,230 --> 00:35:02,070 +الميه شوية في فكرة جديدة لو انا اجيت وضفت الميهH2O + +394 +00:35:02,070 --> 00:35:06,210 +في وجود H بلس يعني كأني بقول H3O plus و عادة + +395 +00:35:06,210 --> 00:35:14,230 +بنستعمل catalyst الذئبق ايون ذئبق HG2 plus فلما + +396 +00:35:14,230 --> 00:35:19,610 +بنعمل هذا الكلام بتضيف الميه حسب قاعدة Markovnikov + +397 +00:35:19,610 --> 00:35:24,210 +بمعنى هنا بدأ تيجي ال H وهنا بدأ تيجي ال OH هاي + +398 +00:35:24,210 --> 00:35:29,360 +الميه اللي ضفناهاهذه إضافة حسب قاعدة ماركوف نيكوف + +399 +00:35:29,360 --> 00:35:33,960 +و لا لأ الآن لاحظوا لو اتطلعت على المركب اللي + +400 +00:35:33,960 --> 00:35:39,880 +اتكون عندى هذا مركب يحتوي على مجموعتين وظيفيتين + +401 +00:35:39,880 --> 00:35:44,040 +المجموعة الوظيفة الوظيفية الأولى ال ال keen + +402 +00:35:45,140 --> 00:35:51,700 +والتانية ال alcohol all فهذا فيه in و فيه all + +403 +00:35:51,700 --> 00:35:55,920 +شايفينهم هذه ال double bond مش بتاخد نهاية in و + +404 +00:35:55,920 --> 00:36:02,620 +هذه all فهذا المركب بنسميه in all لأنه متكون من + +405 +00:36:02,620 --> 00:36:08,420 +هدول الشغلتين in all ال OH متصلة مباشرة جنب ال + +406 +00:36:08,420 --> 00:36:13,950 +double bond هذه المركباتللأسف الشديد انه في الوضع + +407 +00:36:13,950 --> 00:36:18,530 +الطبيعي في الاليفاتيك كومباونز they are unstable + +408 +00:36:18,530 --> 00:36:25,690 +مركبات غير ثابتة بتعمل تحول بتتحول هذه المركبات شو + +409 +00:36:25,690 --> 00:36:29,390 +التحول اللي بتعمله بتخلي ال double bond هذي تيجي + +410 +00:36:29,390 --> 00:36:33,030 +هنا تصير هذي C double bond O و ال H تنتقل هنا + +411 +00:36:33,030 --> 00:36:38,650 +لاحظوا تغيرين اللي بيصير فيها انتقال إلكترونات و + +412 +00:36:38,650 --> 00:36:46,940 +انتقالزرات لما نعمل هذا الكلام هذه ال C شو صارت؟ C + +413 +00:36:46,940 --> 00:36:54,740 +double bond O و هذه ال CH2 شو صارت؟ CH3 إذا إيش + +414 +00:36:54,740 --> 00:37:00,160 +انتقل عنده؟ فقط إلكترونات ولا إلكترونات و ذرات؟ + +415 +00:37:00,160 --> 00:37:04,040 +إلكترونات و ذرات و الذرة تحديدا ذرة الهيدروجين هذه + +416 +00:37:04,040 --> 00:37:09,070 +العمليةاللي بتتم فيها انتقال إلكترونات و ذرات + +417 +00:37:09,070 --> 00:37:13,930 +بتختلف عن عملية ال resonance اللي كانت فقط انتقال + +418 +00:37:13,930 --> 00:37:20,310 +إلكترونات متذاكرين ال resonance؟ ال resonance لما + +419 +00:37:20,310 --> 00:37:26,150 +اتكلمنا عنه و أعطيناه أي سهم ال double headed + +420 +00:37:26,150 --> 00:37:29,930 +straight arrow كان ال resonance movement + +421 +00:37:33,520 --> 00:37:39,820 +movement of electrons only طب لو صارت ال movement + +422 +00:37:39,820 --> 00:37:47,940 +electrons زائد H هذه العملية بسميها Tautomerism + +423 +00:37:47,940 --> 00:37:54,620 +تختلف عن ال resonance بسميها Tautomerismالتوتو + +424 +00:37:54,620 --> 00:38:00,440 +ميريزم ليست فقط حركة إلكترونات حركة إلكترونات و + +425 +00:38:00,440 --> 00:38:04,040 +ذرات و الذرة تحديدا أو غالبا اللي هي ذرة ال إيش + +426 +00:38:04,040 --> 00:38:07,960 +الهيدروجين بيصير عندي توتو ميريزم الآن البعض هيقول + +427 +00:38:07,960 --> 00:38:13,660 +لي شو سهم التوتو ميريزم بنقول سهم التوتو ميريزم + +428 +00:38:13,660 --> 00:38:19,500 +سهم التوتو ميريزم هو سهم الإتزان بهذا الشكلانسى + +429 +00:38:19,500 --> 00:38:23,560 +السهم المرسوم هذا هو الشكل السليم سهم التوتوميرزم + +430 +00:38:23,560 --> 00:38:28,540 +هو سهم الاتزام اذا احنا بنقدر نقول الان لو كنا + +431 +00:38:28,540 --> 00:38:33,320 +بنسألكوا صح و غلط توتوميرزم is an equilibrium + +432 +00:38:33,320 --> 00:38:37,720 +reaction صح طالما equilibrium reaction في ال + +433 +00:38:37,720 --> 00:38:43,980 +equilibrium reaction ايش بينوجد الشغلتين بنسب + +434 +00:38:43,980 --> 00:38:51,040 +معينة الان هذا الشكل اللى اتكون كيتونهذا E0 عشان + +435 +00:38:51,040 --> 00:38:56,400 +هيك هذا التوتمريزم يسمونه كيتو E0 التوتمريزم + +436 +00:38:56,400 --> 00:39:00,660 +التنقل بين التنين لكن مين اللي ينجد بنسبة أكبر + +437 +00:39:00,660 --> 00:39:06,440 +الكيتو يعني لو افترضنا ان هذا كان 99.9% هذا بيكون + +438 +00:39:06,440 --> 00:39:13,050 +بس بنسبة 1.10%يعني في هذا التوتوميريزم ال keto + +439 +00:39:13,050 --> 00:39:17,090 +-enol توتوميريزم ال predominant عارفين كلمة + +440 +00:39:17,090 --> 00:39:23,690 +predominant؟ ال predominant + +441 +00:39:23,690 --> 00:39:27,610 +مين فيها؟ بيكون ال ketone ولا ال enol؟ ال ketone + +442 +00:39:27,610 --> 00:39:31,330 +هو اللي موجود بنسبة كبيرة و ال enol بيكون بنسبة + +443 +00:39:31,330 --> 00:39:35,930 +قليلة طبعا هذا في الaliphatic compoundsلما نيجي + +444 +00:39:35,930 --> 00:39:42,610 +نتعلم في ال aromatic compounds هتلاحظوا العكس في + +445 +00:39:42,610 --> 00:39:49,570 +ال aromatic اللي بينوجد بنسبة أكبر ال enol وعشان + +446 +00:39:49,570 --> 00:39:53,670 +هيك كل كلانة بتقدروا تتذكروا و تشوفوا كيف أصل + +447 +00:39:53,670 --> 00:39:59,190 +الإسم لو اطلعتوا على هذا المركب مين تسمينا إياه؟ + +448 +00:39:59,190 --> 00:40:09,580 +Phenolفينول أنا بدي أسميه زي هيك في إين أول تطلعوا + +449 +00:40:09,580 --> 00:40:15,020 +معاه الفي لأنه عندي بنزينة الفنل الفنل البنزينة و + +450 +00:40:15,020 --> 00:40:20,880 +إين هي الإين و all هي + +451 +00:40:20,880 --> 00:40:25,980 +ال all هذا الشكل الثابت منه و بنقدر نعطيكوا + +452 +00:40:25,980 --> 00:40:29,240 +homework ان جولكوا ارسمونا ال ketone تبعه + +453 +00:40:42,070 --> 00:40:47,610 +ما هو الشكل الثابت في الاروماتيك كومباوتز الموجودة + +454 +00:40:47,610 --> 00:40:52,520 +بالنسبة أعلى؟الـ Enol في الالفاتيك كومباونز اللي + +455 +00:40:52,520 --> 00:40:57,200 +موجود بنسبة أعلى الـ Ketone وهذه التوتوماريزم زي + +456 +00:40:57,200 --> 00:41:01,320 +ما اتفقنا هي عبارة عن عملية equilibrium فالسهم + +457 +00:41:01,320 --> 00:41:08,350 +اللي بيستعمللهاأي سهم؟ الـ straight arrow او two + +458 +00:41:08,350 --> 00:41:12,270 +straight arrows with half heads اللي هو السهمين + +459 +00:41:12,270 --> 00:41:16,070 +اللي موجودين كل واحد بنصف رأس زي ما انتوا شايفينه + +460 +00:41:16,070 --> 00:41:20,610 +هنا واللي اتفقنا ان هذا يستعمل الاتزان وعملية + +461 +00:41:20,610 --> 00:41:25,830 +التوتوماريزم هي حقيقة عملية اتزان عملية + +462 +00:41:25,830 --> 00:41:29,490 +التوتوماريزم هي حقيقة عملية اتزان + +463 +00:41:34,870 --> 00:41:39,810 +التفاعلات أيضا لو كنت أنا بضيف الميه عكس قاعدة + +464 +00:41:39,810 --> 00:41:45,070 +Markov Nikov باستعمال ال boron لاحظوا هنا في عندكم + +465 +00:41:45,070 --> 00:41:50,310 +H هذا نفس المثال السابق بس في اللحظة الأولى اللي + +466 +00:41:50,310 --> 00:41:54,510 +حطيت فيها H و OH طالما بضيف باستعمال ال boron هل + +467 +00:41:54,510 --> 00:41:59,110 +هضيف حسب قاعدة Markov Nikov ولا عكسها عكسها بناء + +468 +00:41:59,110 --> 00:42:04,860 +على ذلك حطيت ال H على اللي حامله H أقلو ال O H على + +469 +00:42:04,860 --> 00:42:08,900 +اللي حامله H هذا إضافة عكس Markovnikov مرة تانية + +470 +00:42:08,900 --> 00:42:18,180 +صار عندى in all هذا ال in all بحوله إلى ال keto + +471 +00:42:18,180 --> 00:42:23,560 +form بمعنى هذا ال double bond تيجي هنا و ال H + +472 +00:42:23,560 --> 00:42:29,500 +تنتقل مكان ما إجت ال double bondكل هذا الكلام + +473 +00:42:29,500 --> 00:42:33,320 +طبقوا بإيدكم عشان تتدربوا عليه، إذا نفس + +474 +00:42:33,320 --> 00:42:37,380 +التوتوميرزم، لكن في هذه الحالة بدل ما أحصل على + +475 +00:42:37,380 --> 00:42:42,560 +كيتون حصلت على الديهايد، في المرة الأولى، ليش حصلت + +476 +00:42:42,560 --> 00:42:48,100 +على كيتون؟ لأن ال OH إجت على الكاربون الداخليةفلما + +477 +00:42:48,100 --> 00:42:51,380 +صارت C double bond O صفية متصلة بكاربون و بكاربون + +478 +00:42:51,380 --> 00:42:55,480 +كيتون في المرة التانية لما أضيف عكس قاعدة + +479 +00:42:55,480 --> 00:42:58,800 +Markovnikov و أعمل التوتوميرزم ال OH جت على + +480 +00:42:58,800 --> 00:43:04,720 +الكاربون الطرفية ولذلك حصلت على الديهيد اذا انا + +481 +00:43:04,720 --> 00:43:10,100 +ممكن احصل من هذا التفاعل على الديهيد او كيتون + +482 +00:43:10,100 --> 00:43:13,840 +اعتمادا على الطريقة اللي انا ببدأ فيها اذا ضفت + +483 +00:43:13,840 --> 00:43:19,760 +الماء بقاعدة Markovnikovبحصل على كيتون وإذا ضيفت + +484 +00:43:19,760 --> 00:43:24,300 +الماء عنتي ماركوفنيكوف بحصل على الديهايد وهذا + +485 +00:43:24,300 --> 00:43:27,360 +الكلام لما انتوا تتدربوا و تطبقوا بيدكم هتلاحظوا + +486 +00:43:27,360 --> 00:43:32,900 +انه بيطلع بشكل تلقائي النتيجة هذه تطلع معاكم بشكل + +487 +00:43:32,900 --> 00:43:42,700 +تلقائي تقريبا الشغلة الأخيرة في هذا الموضوع إضافة + +488 +00:43:42,700 --> 00:43:43,680 +الهيدروجين + +489 +00:43:45,820 --> 00:43:52,880 +أخرناها كثير إضافة الهيدروجين للـ triple bond لها + +490 +00:43:52,880 --> 00:43:57,780 +عدة حالاتإذا ضيفت الهيدروجين في وجود معدن زي + +491 +00:43:57,780 --> 00:44:02,380 +البلاديم والكربون أو مثلا ال nickel أو ال platinum + +492 +00:44:02,380 --> 00:44:08,060 +أي واحد من هدول بلاديم نيكل platinum عادة معدن + +493 +00:44:08,060 --> 00:44:13,680 +البلاديم بيكون مخلوط بكربون بودرة تمام فبتتحول لل + +494 +00:44:13,680 --> 00:44:18,820 +triple bond إلى single bond مباشرة بدون مأمورأو + +495 +00:44:18,820 --> 00:44:20,940 +بمر في الـ double bond بدون ما أفصل الـ double + +496 +00:44:20,940 --> 00:44:26,760 +bond يعني بضيف هيدروجين و كمان هيدروجين فالالكاين + +497 +00:44:26,760 --> 00:44:31,760 +إذا فعلنا مع الهيدروجين في وجود متل بيصير الكين + +498 +00:44:31,760 --> 00:44:35,340 +يعني لما نيجي نقولكم reaction of alkynes with + +499 +00:44:35,340 --> 00:44:40,270 +hydrogen in presence of metals شو بيعطيناالكينز + +500 +00:44:40,270 --> 00:44:46,010 +الان طيب لو جيبت الكاين زي هذا وفعلته مع هيدروجين + +501 +00:44:46,010 --> 00:44:51,030 +في وجود مادة اسمها لند لارز كتاليست يمكن بالكتابة + +502 +00:44:51,030 --> 00:44:55,170 +ناقص حرف ال L لند لارز كتاليست لند لارز كتاليست + +503 +00:44:55,170 --> 00:44:57,530 +لند لارز كتاليست لند لارز كتاليست لند لارز كتاليست + +504 +00:44:57,530 --> 00:45:02,890 +لند لارز كتاليست بضيف بهذه الحالة الهيدروجين من + +505 +00:45:02,890 --> 00:45:10,320 +جهة واحدة وبيعطينيالالكين بيجي في نص الطريق بس إيش + +506 +00:45:10,320 --> 00:45:17,260 +نوع إضافة الهيدروجين في وجود الليندلار + +507 +00:45:17,260 --> 00:45:18,700 +كاتاليست الهيدروجين الهيدروجين الهيدروجين + +508 +00:45:18,700 --> 00:45:20,760 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +509 +00:45:20,760 --> 00:45:21,100 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +510 +00:45:21,100 --> 00:45:21,420 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +511 +00:45:21,420 --> 00:45:21,420 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +512 +00:45:21,420 --> 00:45:21,440 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +513 +00:45:21,440 --> 00:45:21,440 +الهيدروجين الهيدروجين الهيدروجين الهيدروجين + +514 +00:45:21,440 --> 00:45:24,080 +الهيدروجين الهيدروجين الهيدروجينسيس كومباوند في + +515 +00:45:24,080 --> 00:45:26,840 +حالة تانية ممكن لأ يعني لو كانت هذه قدش و قدش مش + +516 +00:45:26,840 --> 00:45:30,900 +هيقد لسيس كومباوند أهم شيء عندنا ان الهيدروجين + +517 +00:45:30,900 --> 00:45:36,100 +بيضيف بسين اديشن اذا كانت اضافته في وجود لندلار + +518 +00:45:36,100 --> 00:45:39,320 +كتاليست و بيقف عن نص الطريق بيقف في وين؟ عند + +519 +00:45:39,320 --> 00:45:44,500 +الألكيد طب يا تورا هل ممكن نضيف الهيدروجين انت + +520 +00:45:44,500 --> 00:45:51,300 +اديشن يعني على نفس هذا المركب و نطلعالهيدروجين + +521 +00:45:51,300 --> 00:45:55,020 +Anti-addition بمعنى إيصير عندي double bond أخلي + +522 +00:45:55,020 --> 00:46:03,960 +البنزنتين على جهتين والهيدروجين على جهتين هذا Anti + +523 +00:46:03,960 --> 00:46:09,880 +-addition واضح؟ ممكن لو أعملنا التفاعل في وجود + +524 +00:46:09,880 --> 00:46:19,310 +ليثيان مع liquid ammoniaواضح؟ اذا انا بإمكاني اضيف + +525 +00:46:19,310 --> 00:46:24,470 +الهيدروجين بطريقة معينة يعملي sin addition و + +526 +00:46:24,470 --> 00:46:29,630 +بطريقة تانية يعملي anti addition و ممكن اضيفه على + +527 +00:46:29,630 --> 00:46:36,970 +مرتين في وجود الهيدروجين و البلاديم او ال nickel + +528 +00:46:36,970 --> 00:46:41,990 +او ال platinum ثانية + +529 +00:46:41,990 --> 00:46:46,060 +بس لو سمحتواLindlar's catalyst هو عبارة عن خليط من + +530 +00:46:46,060 --> 00:46:49,800 +البلاديم مع الكالسيوم كربونيت مع ليد أسيتيت مع + +531 +00:46:49,800 --> 00:46:54,360 +كوينولين بهمنيش نحفظ شكله ماخد اسم، إيش اسمه؟ + +532 +00:46:54,360 --> 00:46:57,000 +Lindlar's catalyst + +533 +00:47:00,060 --> 00:47:04,660 +في عندكم طبعا عدة أمثلة عشان انتوا تدرسوها هي + +534 +00:47:04,660 --> 00:47:10,100 +تطبيق مباشر على هذا الموضوع بيظل عندنا للمرة + +535 +00:47:10,100 --> 00:47:14,100 +الجاية فقط slide واحدة بنحكيها بدقيقتين في موضوع + +536 +00:47:14,100 --> 00:47:17,920 +ال kinds و بننتقل لل chapter الرابع اللي هو + +537 +00:47:17,920 --> 00:47:23,020 +chapter ال aromatic compounds يعني فقط ضايل عندنا + +538 +00:47:23,020 --> 00:47:26,780 +slide واحدة ان شاء الله المرة القادمة بنشرح + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..541778672a8c30813817e5cc129232b4a41f5111 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_postprocess.srt @@ -0,0 +1,2060 @@ +1 +00:00:20,860 --> 00:00:25,560 +بسم الله الرحمن الرحيم اليوم موضوعنا ان شاء الله + +2 +00:00:25,560 --> 00:00:29,680 +هيكون في الفصل الرابع ال aromatic compounds لكن + +3 +00:00:29,680 --> 00:00:36,220 +ضال علينا شغلة صغيرة انا بعتقد انها مهمة من الفصل + +4 +00:00:36,220 --> 00:00:41,640 +الثالث من تفاعلات ال alkynes فخلينا نشوف هذه + +5 +00:00:41,640 --> 00:00:47,680 +النقطة بسرعة و بعدين ننتقل لموضوعنا الأساسي اللي + +6 +00:00:47,680 --> 00:00:53,620 +هو ال aromatic compoundsالنقطة اللى ضالت علينا انه + +7 +00:00:53,620 --> 00:01:00,580 +احنا لما بننظر لل Alkynes اذا كان على احد أطرافهم + +8 +00:01:00,580 --> 00:01:06,020 +على اقل تقدير او ممكن على الطرفين ذرّة هيدروجين + +9 +00:01:06,020 --> 00:01:11,400 +يعني ال Alkyne ممكن يكون R C triple bond C وR تاني + +10 +00:01:11,400 --> 00:01:16,040 +يعني مثل و مثل او فلل و فلل و ممكن يكون R C triple + +11 +00:01:16,040 --> 00:01:22,690 +bond C وموجودزرّة هيدروجين الالكاين اللي بهذا + +12 +00:01:22,690 --> 00:01:27,670 +الشكل اللي في أحد أطرافه زرّة هيدروجين بنسميه احنا + +13 +00:01:27,670 --> 00:01:32,350 +terminal الكاين يعني الكاين الطرفي اللي في أحد + +14 +00:01:32,350 --> 00:01:39,440 +أطرافه ايش فيها terminal الكاينهذه النقطة الأولى + +15 +00:01:39,440 --> 00:01:43,300 +إذا عرفنا إيش معناه Terminal Alkyne اللي على طرف + +16 +00:01:43,300 --> 00:01:49,960 +من الرابط الزوجية فيه موجود عنده ذرة هيدروجين الآن + +17 +00:01:49,960 --> 00:01:54,960 +بنضيف معلومة جديدة بنقول ال terminal alkynes are + +18 +00:01:54,960 --> 00:02:00,680 +acidic ال terminal alkynes are acidic إيش يعني + +19 +00:02:00,680 --> 00:02:07,200 +acidic؟حامضي الان لو انا اجيت اتذكر تعريف الحامض + +20 +00:02:07,200 --> 00:02:10,980 +ممكن ناخد في هذه المرحلة تعريف الوري برونستيد الـ + +21 +00:02:10,980 --> 00:02:19,780 +acid proton donor بيعطي بروتونات بيفقد بروتون الان + +22 +00:02:19,780 --> 00:02:24,660 +اي بروتون حامضي في هذا المركب يعني لحظوا انا لما + +23 +00:02:24,660 --> 00:02:29,460 +رسمت هنا مركب في عندي هنا حلقة Cyclohexane و عليها + +24 +00:02:29,460 --> 00:02:34,030 +هيدروجينأو في مجموعات الميثل والإثل والبروبل + +25 +00:02:34,030 --> 00:02:38,430 +الالكينز كلها ملانة هيدروجين كل هذه الهيدروجينات + +26 +00:02:38,430 --> 00:02:42,730 +اللي في الالكينز و اللي في الالكينز هيدروجينات غير + +27 +00:02:42,730 --> 00:02:46,590 +حامضية ايش معنى هيدروجين غير حامضي انه لا يفقد + +28 +00:02:46,590 --> 00:02:51,370 +بسهولة عند التفاعل مع قاعدةالهيدروجين الحامضي + +29 +00:02:51,370 --> 00:02:56,150 +هيدروجين يفقد بسهولة إذا تم التفاعل مع القاعدة + +30 +00:02:56,150 --> 00:03:00,930 +ولذلك لما نتطلع على مركب عضوي هنلاحظ أنه دائما + +31 +00:03:00,930 --> 00:03:04,330 +المركب العضوي في نوعين من الهيدروجين يعني خليني + +32 +00:03:04,330 --> 00:03:12,190 +أخد مثلا حمض الخل كمثال بسيط حمض الخل CH3COO + +33 +00:03:13,740 --> 00:03:19,780 +OH الآن في عندى نوعين من الهيدروجين هنا هدول التلت + +34 +00:03:19,780 --> 00:03:24,400 +هيدروجينات هيدروجينات عادية لو انا كنت بفاعل مع + +35 +00:03:24,400 --> 00:03:28,820 +قاعدة لا يفقدوا مع القاعدة they are non acidic مش + +36 +00:03:28,820 --> 00:03:34,580 +هيدروجين حامضى الان الهيدروجين اللى متصل بال OH في + +37 +00:03:34,580 --> 00:03:39,320 +الحامض هذا هيدروجين حامضى هذا اللى بيفقد لما انا + +38 +00:03:39,320 --> 00:03:44,630 +باجى بعمل تفاعل مع baseفصار في عندى acidic + +39 +00:03:44,630 --> 00:03:49,530 +hydrogen و non acidic hydrogen او بيكون على اقل + +40 +00:03:49,530 --> 00:03:54,370 +تقدير اضعف المسألة مسألة ضعف و قوة يعنى هذه + +41 +00:03:54,370 --> 00:03:58,770 +الهيدروجينة حمضية بشكل كبير تفقد بسهولة هذه حمضية + +42 +00:03:58,770 --> 00:04:04,270 +بشكل قليل جدا تفقد بصعوبةممكن لو جيبنا base قوي + +43 +00:04:04,270 --> 00:04:08,810 +جدا جدا عود نفقدها لكن على base عادي مثلا خلّيني + +44 +00:04:08,810 --> 00:04:12,410 +أقول Sodium Hydroxide أو حتى Sodium Carbonate + +45 +00:04:12,410 --> 00:04:17,490 +قاعدة عادية بدي أفعلها أي هيدروجين اللي بدي تفقد + +46 +00:04:17,490 --> 00:04:22,450 +الـ acidic هيدروجين عشان ذلك بكل كوب تذكروا + +47 +00:04:22,450 --> 00:04:28,470 +التفاعل زائد MAالـ OH هي الـ base of Sodium + +48 +00:04:28,470 --> 00:04:32,670 +Hydroxide الأن الـ OH هي الـ base مع هذه الـ H + +49 +00:04:32,670 --> 00:04:39,830 +كنتوا متعودين تقولوا بيكون عندك ماء حمض زائد قاعدة + +50 +00:04:39,830 --> 00:04:44,650 +ملح زائد ماء لما هذه الـ H تفقد على شكل H plus + +51 +00:04:44,650 --> 00:04:49,880 +هتظل إلكتروناتالرابطة بتاعتها بالاضافة لزوجين + +52 +00:04:49,880 --> 00:04:54,700 +الأساسيات الاساسيات حيصير عليكم CH3C double bond O + +53 +00:04:54,700 --> 00:05:00,100 +O كم زوج إلكترونات عليها تلاتة أصلا زوجين + +54 +00:05:00,100 --> 00:05:04,220 +إلكترونات و رابطتين فقدت ال H لواحدها بدون + +55 +00:05:04,220 --> 00:05:10,000 +إلكتروناتها عشان ال H plus ال OH minus أخدت إيش ال + +56 +00:05:10,000 --> 00:05:18,210 +H plus شو صفية هذه minus مع ال NAplus صار sodium + +57 +00:05:18,210 --> 00:05:23,650 +acetate خلات الصوديوم acidic acid زايد NaOH Sodium + +58 +00:05:23,650 --> 00:05:30,450 +acetate زايد H2O حمض زايد قاعدة ملح زايد ماء هذا + +59 +00:05:30,450 --> 00:05:35,090 +تذكير خلينا نقول بمفهوم الحمض والقاعدة الآن لو + +60 +00:05:35,090 --> 00:05:40,690 +اجينا نطبق بنفس المنطق على ال terminal الكاين و + +61 +00:05:40,690 --> 00:05:47,550 +اتخيلنا ان هذا ال terminal الكاين عبارة عنacid وين + +62 +00:05:47,550 --> 00:05:53,450 +ال acidic hydrogen اللي فيه هادف الان نتخيل انه + +63 +00:05:53,450 --> 00:05:57,910 +عندنا رابطة بين الكربون و الهيدروجين لاحظوا معي + +64 +00:05:57,910 --> 00:06:03,350 +الكربون لا يحمل اي زوج إلكترونات حرة فيه اربع + +65 +00:06:03,350 --> 00:06:08,190 +روابط و لذلك حتى الكربون بشكله الطبيعي كان بيصلح + +66 +00:06:08,190 --> 00:06:14,950 +اللأ تذكروا المرات الماضية قلنا ان ال oxygen في + +67 +00:06:14,950 --> 00:06:18,370 +رابطتين و زوجين إلكترونات من خلال أزواج + +68 +00:06:18,370 --> 00:06:22,940 +الإلكترونات بيعمل ال UQ fileالنيتروجين في تلت + +69 +00:06:22,940 --> 00:06:28,060 +روابط وزوج إلكترونات أيضا بيعمل الـ eucleophile من + +70 +00:06:28,060 --> 00:06:33,720 +خلال زوج الإلكترونات الهالوجين في رابطة تلت أزواج + +71 +00:06:33,720 --> 00:06:37,020 +إلكترونات أيضا ممكن يعمل الـ eucleophile من خلال + +72 +00:06:37,020 --> 00:06:42,850 +أزواج الإلكترونات الكاربونفي أربع روابط فبالوضع + +73 +00:06:42,850 --> 00:06:47,850 +الطبيعي هل ال carbon بيعمل ال nucleophile لأ واضح + +74 +00:06:47,850 --> 00:06:52,490 +الان لو اتيت لهذا المركب فعالته مع strong base + +75 +00:06:52,490 --> 00:06:59,410 +NaNH2 هذه موازية تماما لل NaOH يعني كلكم بتعرفوا ك + +76 +00:06:59,410 --> 00:07:08,630 +base NaOH شو كنا نسميها Sodium Hydroxide الان + +77 +00:07:08,630 --> 00:07:17,130 +NaNH2 شبه بها تماما بنسميها Sodium Amide وهذه + +78 +00:07:17,130 --> 00:07:20,670 +قاعدة + +79 +00:07:20,670 --> 00:07:25,250 +قوية اقوى من Sodium Hydroxide اقوى من Sodium + +80 +00:07:25,250 --> 00:07:31,110 +Hydroxide لما نيجي نتخيل ان هذا الحمد وهذه القاعدة + +81 +00:07:31,860 --> 00:07:37,260 +هتيجي ال N H2 تتفاعل مع ال H Plus لوحدها شو + +82 +00:07:37,260 --> 00:07:44,800 +هتعطيني N H3 زي ما كانت ال O H minus تاخد ال H ال + +83 +00:07:44,800 --> 00:07:52,600 +N H2 minus بتاخد ال H O H مع H H2O N H2 minus مع H + +84 +00:07:52,600 --> 00:07:59,980 +N H3 نفس التفاعل الآن لما فقدت هذه ال H شو دل على + +85 +00:07:59,980 --> 00:08:07,790 +الكربون؟تلات روابط و إلكترونين إلكترونين قصدكم زوج + +86 +00:08:07,790 --> 00:08:11,930 +إلكترونات واحد تلات روابط و إلكترونين هاي واضحها + +87 +00:08:11,930 --> 00:08:17,070 +تلات روابط و إلكترونين الآن لو إجينا حسبنا ال + +88 +00:08:17,070 --> 00:08:23,130 +formal charge على هذه ال carbon أربعةالكربون ناقص + +89 +00:08:23,130 --> 00:08:28,370 +تلات روابط ناقص إلكترونين minus one صارت الكربون + +90 +00:08:28,370 --> 00:08:34,070 +minus والصوديوم plus هذا بنسميه صوديوم أستيلايد زي + +91 +00:08:34,070 --> 00:08:37,370 +ما مثلا مع ال hcl بنقول صوديوم كلورايد وصوديوم + +92 +00:08:37,370 --> 00:08:41,710 +برومايد في التفاعلات الآن لاحظوا إيش اللي نشأ عندى + +93 +00:08:41,710 --> 00:08:48,050 +الآنIon سالب carbon nucleophile صار في عندي carbon + +94 +00:08:48,050 --> 00:08:52,550 +عليه أزواج إلكترونات يعني لو روحت بدي أخد هذا ال + +95 +00:08:52,550 --> 00:08:58,170 +Ion اللي نتج عنده و أفعله أي تفاعل كان nucleophile + +96 +00:08:58,170 --> 00:09:03,330 +بتفعل ولا لأ بتفعل فهذه المركبات اللي عادة بنعطيها + +97 +00:09:03,330 --> 00:09:10,390 +اسم العام Acetylides they are in fact carbon + +98 +00:09:10,390 --> 00:09:14,670 +nucleophilesيعني لو قلنا ال Acetylates ايش ممكن + +99 +00:09:14,670 --> 00:09:21,470 +نعتبرها؟ Carbon Enucleophile الان لاحظوا انه ال + +100 +00:09:21,470 --> 00:09:25,290 +carbon بالوضع الطبيعي كان سهل يكون عامل carbon + +101 +00:09:25,290 --> 00:09:30,070 +enucleophile لأ بعملش لكن انا لما فقدت بروتون منه + +102 +00:09:30,070 --> 00:09:33,870 +و خلت زوجي الإلكترونات صار هذا زوجي الإلكترونات + +103 +00:09:33,870 --> 00:09:39,090 +اللي على ال carbon يمثل carbon enucleophile طالما + +104 +00:09:39,090 --> 00:09:44,920 +انه اتكون عندي carbon enucleophileبقدر يتفاعل الـ + +105 +00:09:44,920 --> 00:09:49,900 +nucleophile مثلا لو اتي اتفاعلته مع مثل ايودايد + +106 +00:09:49,900 --> 00:09:55,160 +ممكن يعمل تفاعل ابدال ان هذا زوج الالكتروناتي هاجم + +107 +00:09:55,160 --> 00:09:59,600 +على الكربون و يطرد اليود مع زوج الالكتروناتي هذا + +108 +00:09:59,600 --> 00:10:04,190 +ايش اسم التفاعل؟Substitution Reaction أو تفاعل + +109 +00:10:04,190 --> 00:10:10,450 +إحلال الـ Eucleophil بيحل محل الـ Eucleophil بيجي + +110 +00:10:10,450 --> 00:10:14,690 +الكربون مع زوج الإلكترونات اللي معه بيحل محل اليود + +111 +00:10:14,690 --> 00:10:19,150 +و بيطلع اليود مع زوج الإلكترونات بدل ما كان عنده + +112 +00:10:19,150 --> 00:10:24,120 +أنا Sodium Acetylide هيطلع عندى في النهايةSodium + +113 +00:10:24,120 --> 00:10:29,920 +Iodide يعني كأنه هذا تفاعل تبادل مزدوج اللي مار + +114 +00:10:29,920 --> 00:10:36,540 +عليكم واضح ففائدة هذا التفاعل ان هو وفر لي ال + +115 +00:10:36,540 --> 00:10:40,520 +carbon nucleophile اللي بالوضع المتعادل عادة مش + +116 +00:10:40,520 --> 00:10:43,920 +متوفر وانا بعد هيك باستفيد من ال carbon + +117 +00:10:43,920 --> 00:10:49,780 +nucleophile في تفاعلات الإبدال وغيرها ممكن الآننجي + +118 +00:10:49,780 --> 00:10:56,760 +نختبر معلوماتكم احنا المرة الماضية أخدنا عن تفاعل + +119 +00:10:56,760 --> 00:11:02,980 +كنا بنستعمل فيه الـUQ5 مين تتذكر شو هو التفاعل الـ + +120 +00:11:02,980 --> 00:11:08,430 +Epoxide كان يعمل ring openingمع اليوكليوفايل لما + +121 +00:11:08,430 --> 00:11:12,430 +أخدنا تفاعل الابوكسايد المعادلة العامة اللى + +122 +00:11:12,430 --> 00:11:18,270 +كتبناها كنا نقول اليوكليوفايل عليه أزواج إلكترونات + +123 +00:11:18,270 --> 00:11:24,510 +زائد الابوكسايد كان بيفتح الحلقة بيعطينا CH2 إذا + +124 +00:11:24,510 --> 00:11:33,010 +افترضنا هذه CH2 OH و بيجي هنا بتفاعل إيشلنكليوفايل + +125 +00:11:33,010 --> 00:11:36,950 +هى ال ring opening اللى أخدناه لل Epoxides الان + +126 +00:11:36,950 --> 00:11:41,250 +بدنا نيجي نعوض بدل كلمة نكليوفايل زى ما تعون + +127 +00:11:41,250 --> 00:11:46,850 +الرياضيات بيكتب X و Y للمجهيل بدنا نجيب لنكليوفايل + +128 +00:11:46,850 --> 00:11:55,250 +تبعنا الacetylide يعنىCH3C triple bond C ويحمل زوج + +129 +00:11:55,250 --> 00:12:00,730 +إلكترونات صار إيش minus و الفاعل هذا مع هدف شو + +130 +00:12:00,730 --> 00:12:07,430 +بتتوقع بده يكون الناتج بده يشبك من + +131 +00:12:07,430 --> 00:12:11,530 +خلال زوج الإلكترونات هذا إذا أنا لما بحط الناتج + +132 +00:12:11,530 --> 00:12:16,070 +هنا ممكن أحطه باللون الأحمر هيكون بهذا الشكل C + +133 +00:12:16,070 --> 00:12:18,190 +triple bond C + +134 +00:12:22,290 --> 00:12:27,350 +هذه الاسيتيلايد اتفاعل كان يوكليوفايل هاجم على + +135 +00:12:27,350 --> 00:12:33,490 +الكربون وعمل ring opening و تم التفاعل بشكل كامل + +136 +00:12:33,490 --> 00:12:34,770 +واضح؟ + +137 +00:12:38,830 --> 00:12:43,190 +فهمنا اذا هذه النقطة اللى كانت ضايلة عندنا من ال + +138 +00:12:43,190 --> 00:12:47,570 +chapter تلاتة انه نفهم ايش معنى terminal alkynes + +139 +00:12:47,570 --> 00:12:51,390 +نمرة واحد، نمرة اتنين ان نقول ان terminal alkynes + +140 +00:12:51,390 --> 00:12:56,110 +are acidic when reacted with bases they form + +141 +00:12:56,110 --> 00:13:00,170 +carbon enucleophiles الآن ال carbon enucleophiles + +142 +00:13:00,170 --> 00:13:02,810 +are like any nucleophile they can undergo + +143 +00:13:02,810 --> 00:13:06,590 +substitution reactions or any enucleophilic + +144 +00:13:06,590 --> 00:13:07,150 +reaction + +145 +00:13:11,320 --> 00:13:17,460 +بهيك بننتهي من الفصل التالت في عندكم بالتأكيد + +146 +00:13:17,460 --> 00:13:21,660 +تدريبات موجودة و احيانا محلولة اكمال المعادلات و + +147 +00:13:21,660 --> 00:13:27,320 +ما إلى ذلك بعتقد انه بيكون جزء من المطلوب منكم ان + +148 +00:13:27,320 --> 00:13:36,660 +تجتهدوا في تحضيرها و فاهمها بننتقل مباشرة ل الفصل + +149 +00:13:36,660 --> 00:13:43,940 +الرابع و الفصل الرابع بعنوانAromatic compoundsربما + +150 +00:13:43,940 --> 00:13:47,500 +ال aromatic compounds لو بدنا نشوف موقعها من + +151 +00:13:47,500 --> 00:13:52,720 +الإعراب في ال hydrocarbons they are unsaturated + +152 +00:13:52,720 --> 00:13:56,700 +hydrocarbons احنا درسنا ال الكينز ال cycloalkyns + +153 +00:13:56,700 --> 00:14:00,160 +ال الكينز ال alkynes ضال علينا ال aromatic + +154 +00:14:00,160 --> 00:14:03,540 +compounds الآن أبسط تعريف ممكن نعطيله ال aromatic + +155 +00:14:03,540 --> 00:14:07,520 +compounds they are بنزين like compounds المركبات + +156 +00:14:07,520 --> 00:14:14,170 +اللي زي البنزين بمعنى فيهم الحلقة و فيهمأزواج + +157 +00:14:14,170 --> 00:14:20,550 +الألكترونات أو الروابط الزوجية بشكل معين وبعدد + +158 +00:14:20,550 --> 00:14:26,730 +معين الان في نقطة كتير مهمة يمكن كل هذا ال slide + +159 +00:14:26,730 --> 00:14:33,530 +أخدناها ماعدا نقطة واحدة اللي هو ايش طول الرابط في + +160 +00:14:33,530 --> 00:14:37,930 +البنزينما هو bond order في البنزين وما هو طول + +161 +00:14:37,930 --> 00:14:41,230 +الرابط في البنزين احنا أخدنا معلومات عن الرابط + +162 +00:14:41,230 --> 00:14:45,910 +الأحدية والثنائية والثلاثية طبعا كلكوا انتوا + +163 +00:14:45,910 --> 00:14:49,950 +متذكرين البنزين ومتذكرين ال resonance structures + +164 +00:14:49,950 --> 00:15:01,270 +اللي بيعملها بهذا الشكل و بهذا الشكل الان لو اتيت + +165 +00:15:01,270 --> 00:15:06,210 +طلعت على رابط معين خليني اقول هذه الرابطةهذه + +166 +00:15:06,210 --> 00:15:11,810 +الرابطة هنا تبدو إيش؟ أحدية هذه الرابطة هنا تبدو + +167 +00:15:11,810 --> 00:15:16,850 +أحدية هذه الرابطة هنا تبدو ثنائية الآن احنا بنقول + +168 +00:15:16,850 --> 00:15:20,770 +البنزيل in resonance structure يعني بين هذه وبين + +169 +00:15:20,770 --> 00:15:25,970 +هذه بناء على ذلك لو بدي أجي أسأل ال bond order في + +170 +00:15:25,970 --> 00:15:31,130 +البنزيل قداشر هل هو يا ترى أحدى ولا ثنائي؟ هو قاعد + +171 +00:15:31,130 --> 00:15:36,830 +بتقلببين الواحد والاتنين بال average ايش هتطلع ال + +172 +00:15:36,830 --> 00:15:41,510 +bond order واحد و نص و ال bond order ممكن تيجي كسب + +173 +00:15:41,510 --> 00:15:45,350 +و لذلك لو اجيت سألت ايش ال bond order في البنزين + +174 +00:15:45,350 --> 00:15:53,590 +واحد و نص هذه الكلمة مهمة جدا جدا هذه الكلمة مهمة + +175 +00:15:53,590 --> 00:15:59,790 +جدا جدا عارفين ليش لأنه انا درست الرابط الاوحدية + +176 +00:15:59,790 --> 00:16:05,520 +في chapter الالكينزو تفاعلاتها و درست الرابط + +177 +00:16:05,520 --> 00:16:09,560 +الثنائية في chapter ال alkanes و تفاعلاتها اللي هي + +178 +00:16:09,560 --> 00:16:17,570 +بشكل أساس تفاعلات الإضافة ال A بجعل ال aromaticلو + +179 +00:16:17,570 --> 00:16:20,710 +ان هذه الرابطة احدية كان كل معلومات ال الكينز + +180 +00:16:20,710 --> 00:16:24,770 +منطبق على البنزين لو انها ثنائية كان كل معلومات ال + +181 +00:16:24,770 --> 00:16:29,450 +الكينز منطبق على البنزين الان الرابطة لا احدية ولا + +182 +00:16:29,450 --> 00:16:34,710 +ثنائية واحد و نص ولذلك ولا تفاعل من تفاعلات ال + +183 +00:16:34,710 --> 00:16:39,110 +الكينز ولا تفاعل من تفاعلات ال الكينز منطبق على + +184 +00:16:39,110 --> 00:16:43,430 +البنزين بنلاحظ ان البنزين هيصير له كيميا خاصة فيه + +185 +00:16:44,110 --> 00:16:48,990 +لأنه لا هو رابطة أحدية ولا هو رابطة ثنائية لا هو + +186 +00:16:48,990 --> 00:16:54,770 +الكل ولا هو الكل واضح هذا النقطة هذا الكلام يتبع + +187 +00:16:54,770 --> 00:16:58,710 +كمان شغلة أنه لو أنا بدي أتي أحكي عن ال bond + +188 +00:16:58,710 --> 00:17:03,310 +length قلنا احنا أنه رابطة الأحدية طويلة الرابطة + +189 +00:17:03,310 --> 00:17:10,160 +الثنائية قصيرة الآن رابطة البنزينوين هتكون؟ بين + +190 +00:17:10,160 --> 00:17:14,740 +بين وبين + +191 +00:17:14,740 --> 00:17:15,160 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +192 +00:17:15,160 --> 00:17:15,760 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +193 +00:17:15,760 --> 00:17:20,320 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +194 +00:17:20,320 --> 00:17:20,380 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +195 +00:17:20,380 --> 00:17:20,540 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +196 +00:17:20,540 --> 00:17:21,340 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +197 +00:17:21,340 --> 00:17:27,820 +وبين وبين وبين وبين وبين + +198 +00:17:27,820 --> 00:17:35,990 +وبين وبينفلا هي رابطة ثنائية ولا هي رابطة وحدية + +199 +00:17:35,990 --> 00:17:39,650 +ربما احنا اللي بهمنا اكثر النقطة اللي انا ركزت + +200 +00:17:39,650 --> 00:17:43,810 +عليها النقطة اللي انا ركزت عليها ان البنزين مش + +201 +00:17:43,810 --> 00:17:50,730 +هيعمل تفاعلاتالالكينز بشكل أساسي يعني ربما أنه أول + +202 +00:17:50,730 --> 00:17:55,630 +ما نعطي شبتري البنزين و نيجي نرسم بنزينة تفكر + +203 +00:17:55,630 --> 00:17:59,910 +طالبة اجتهدت في موضوع الالكينز بهذا الشكل و هي + +204 +00:17:59,910 --> 00:18:07,930 +شايفة الروابط و نقولها H2OH plus تيجي أول ما تفكر + +205 +00:18:07,930 --> 00:18:15,490 +اضيف H2OH بهاي double bond هنا بيكون إيش عندهخطأ + +206 +00:18:15,490 --> 00:18:19,190 +كبير يعني أنا خايف أكتب و لحظة يتسجل علي في اللوحة + +207 +00:18:19,190 --> 00:18:23,590 +اني كتبت انه بضيف H OH إياكم تفكروا بهذا الشكل + +208 +00:18:23,590 --> 00:18:28,210 +البنزين لا يتعامل كالكيل صح انتوا شايفين تلاتة + +209 +00:18:28,210 --> 00:18:32,990 +double bonds لكن على أرض الواقع لا يتعامل إطلاقا + +210 +00:18:32,990 --> 00:18:36,390 +بتفاعلات الالكيل واضح هذه النقطة؟ + +211 +00:18:44,190 --> 00:18:50,570 +خلّينا نقول كنظرة تاريخية كنظرة تاريخية البنزين + +212 +00:18:50,570 --> 00:18:55,670 +أول ما اكتشف مركب سائل و تم الاكتشاف سنة الف و + +213 +00:18:55,670 --> 00:19:00,390 +تمانمية و خمسة و عشرين من خلال العالم الإنجليزي + +214 +00:19:00,390 --> 00:19:07,990 +Faraday وحتى البنزين اللي هو يعني قطره و حضرهكمية + +215 +00:19:07,990 --> 00:19:12,410 +صغيرة منه ما زالت موجودة لليوم في متحف بريطانيا + +216 +00:19:12,410 --> 00:19:17,170 +نفس السائل البنزين اللي هو فصله فرديه و بيعتزوا + +217 +00:19:17,170 --> 00:19:21,910 +فيه يعني بيعتبروه شئ كبير هذا أول مفصل الآن لما + +218 +00:19:21,910 --> 00:19:26,150 +فصلوا بدوا يعملوا تحليل شو هالمركب لقوا أن الصيغة + +219 +00:19:26,150 --> 00:19:30,830 +الجزائية للبنزين C6H6 + +220 +00:19:31,830 --> 00:19:35,790 +هذه الصيغة الجزائية، لكن يا ترى إيش الصيغة + +221 +00:19:35,790 --> 00:19:41,790 +البنائية؟ الآن صار عندكم خبرة إن صيغة جزائية واحدة + +222 +00:19:41,790 --> 00:19:47,710 +يمكن أن يكون لها عدد كبير من الصيغ البنائيةمظبوط + +223 +00:19:47,710 --> 00:19:52,610 +ولا لأ اللي هي ال structural isomers او حتى ال + +224 +00:19:52,610 --> 00:19:58,190 +stereo isomers فسهل انهم يعرفوا الصيغة الجزائية + +225 +00:19:58,190 --> 00:20:02,590 +بيومين بيعرفوا انه مركب جديد الفصل صيغته الجزائية + +226 +00:20:02,590 --> 00:20:08,830 +C6H6 لكن يا تورا الصيغة البنائية للبنزين 6 ذرات + +227 +00:20:08,830 --> 00:20:13,950 +كربون و 6 ذرات هيدروجين كيف هدول موجودين بأي شكل + +228 +00:20:14,810 --> 00:20:20,350 +هذه العملية معرفة الصيغة البنائية للبنزين أخدت .. + +229 +00:20:20,350 --> 00:20:25,450 +نرجع للتاريخ أن الأجهزة مش متقدمة و العلوم صعبة + +230 +00:20:25,450 --> 00:20:32,510 +أخدت أربعين سنة أربعين سنة لما قدروا يقولوا أن + +231 +00:20:32,510 --> 00:20:38,070 +صيغة C6H6 في النهاية هي صيغة البنزين بهذا الشكل + +232 +00:20:38,690 --> 00:20:43,370 +اللي اقترحها العالم Kekuli الآن أثناءها الأربعين + +233 +00:20:43,370 --> 00:20:49,350 +سنة اقترحت صياغ كثيرة و أخدت أسماء و أحيانا درست + +234 +00:20:49,350 --> 00:20:53,490 +للطلاب لأن اللي كانوا بيقترحوه علماء كبار يعني كل + +235 +00:20:53,490 --> 00:20:57,750 +هذه الصياغ فيها Carbons و Hydrogens و لو كملتوا ال + +236 +00:20:57,750 --> 00:21:02,510 +Hydrogens حسب ما احنا اتعلمنا هتلاحظوا ان هذه + +237 +00:21:02,510 --> 00:21:08,270 +الصياغ كلها او هذه المركبات بأشكالها المختلفة C6H6 + +238 +00:21:08,780 --> 00:21:14,940 +يعني هذا مثلا هي carbon اتنين تلاتة اربعة خمسة ستة + +239 +00:21:14,940 --> 00:21:20,360 +هنا في hydrogen تنتين تلاتة اربعة خمسة ستة C6H6 + +240 +00:21:21,030 --> 00:21:25,570 +واخد اسم و لذلك بنلاحظ ان بعض هذه المراكبات على + +241 +00:21:25,570 --> 00:21:29,570 +سبيل المثال هذا المراكب كان اسمه Dewar Benzin هذا + +242 +00:21:29,570 --> 00:21:33,210 +المراكب اسمه Huckel Benzin و هدول علماء كيميا كبار + +243 +00:21:33,210 --> 00:21:39,250 +هذا Ladenburg Benzin يمكن الكلام هنا بالالماني + +244 +00:21:39,250 --> 00:21:46,010 +Klaus Benzinعلماء كبار حطوا أشكال و درست لفترة و + +245 +00:21:46,010 --> 00:21:49,950 +هذا الكلام بده يخلي عندكم دائما الشعور أن العلم + +246 +00:21:49,950 --> 00:21:54,930 +متطور و ممكن أشياء الإنسان يكون بيدرسها و بعدين + +247 +00:21:54,930 --> 00:21:58,710 +يكتشف أنها خطأ أكبر شغلة كل المختارات اللي احنا + +248 +00:21:58,710 --> 00:22:03,950 +بنعيشها أول ما بتطلع بنهلللها بشكل كبير و بعد هيك + +249 +00:22:03,950 --> 00:22:08,670 +بنلاحظ أن كل العالم يسعى لمنع هذه المختارات اللي + +250 +00:22:08,670 --> 00:22:13,100 +احنا هللنا لها كتيرومن أمثلتها على سبيل المثال + +251 +00:22:13,100 --> 00:22:17,420 +الفريون الغاز تبع التلاجات اللى كانوا يحطوه فى + +252 +00:22:17,420 --> 00:22:21,000 +علاب الريح عشان يعمل ال spraying ال answer نقول + +253 +00:22:21,000 --> 00:22:27,610 +هذه ال chlorofluorocarbons تدمر طبقة ال ozoneواضح؟ + +254 +00:22:27,610 --> 00:22:33,690 +من ضمنها مثلا المبيد الزراعي ال DDT هذا ممتاز + +255 +00:22:33,690 --> 00:22:38,130 +بيقتل الحشرات بيقتل ممتاز جدا لكن المشكلة بيأثر + +256 +00:22:38,130 --> 00:22:44,170 +على البشر ولذلك حتى بعد منعه المزارعين ما زالوا + +257 +00:22:44,170 --> 00:22:48,290 +بيحصلوه بالسوق السوداء و بيستعملوه لأنه بيجيبلهم + +258 +00:22:48,290 --> 00:22:53,540 +محصول لكن هو بنفس الوقت بيفكرش بإيشبفكرش في البشر + +259 +00:22:53,540 --> 00:22:57,900 +اللي بده يؤذيهم فهذه المنطقة في العلم انضال من + +260 +00:22:57,900 --> 00:23:04,380 +تبهين لها انه ممكن نكتشف أشياء نعتقد انها جيدة + +261 +00:23:04,380 --> 00:23:10,620 +وبعد هيك نتفاجأ انها عملت مشاكل بالفصل الخامس ان + +262 +00:23:10,620 --> 00:23:17,330 +شاء الله هنحكيلكم عن دوةنزل على السوق و بعد هيك + +263 +00:23:17,330 --> 00:23:22,410 +عمل مأساة كبيرة يمكن البعض منكوا لما نتكلم عنها و + +264 +00:23:22,410 --> 00:23:25,870 +نحط المأساة بالصور ايش عمل في البشر ممكن البعض + +265 +00:23:25,870 --> 00:23:35,030 +يبكي مع العلم انه دوى و سوق و أخدون ناس ابحينه انا + +266 +00:23:35,030 --> 00:23:39,540 +مش كل اشي بيعملون دراسة قبل ما ينهاركل إشي .. كل + +267 +00:23:39,540 --> 00:23:44,720 +إشي بيعملوله دراسة لكن في النهاية بتيجي دراسة أدق + +268 +00:23:44,720 --> 00:23:49,460 +من دراسة، شيء إحنا مش منتبهينله، يعني مابندناش + +269 +00:23:49,460 --> 00:23:56,540 +ناخد كل شيء إن هو قطعي تماما، بيحاولوا، بيجتهدوا، + +270 +00:23:56,540 --> 00:24:03,730 +طبعا أصعب شيء إذا دخلتالتجارة والصناعة في البحث + +271 +00:24:03,730 --> 00:24:08,230 +العلمي أثرت على حيادية النتيجة العلمية يعني أن + +272 +00:24:08,230 --> 00:24:13,510 +الشركة تخفي معلومات بخصوص منتوجها عشان تبيعه كل + +273 +00:24:13,510 --> 00:24:18,670 +شيء وارد .. كل شيء وارد والأمثلة لا تعد ولا تحصر + +274 +00:24:18,670 --> 00:24:24,650 +يعني خدوا على سبيل المثال صبغات الشعراللي استعملت + +275 +00:24:24,650 --> 00:24:28,170 +كثير و بشكل أساسي صفغات مُركّبات بسمها الـ + +276 +00:24:28,170 --> 00:24:32,030 +Pyrosols الان كلها انتهت من السوق في آخر عشر أو + +277 +00:24:32,030 --> 00:24:36,230 +خمس عشر سنة استعملته على المدى البعيد بدأ يبين + +278 +00:24:36,230 --> 00:24:40,950 +آثار سلبية لها الان بيخترعوا شغلات جديدة أول ما + +279 +00:24:40,950 --> 00:24:43,690 +بيخترعوا شغلة جديدة بيجوا و بيقولوا عملنا لها + +280 +00:24:43,690 --> 00:24:50,260 +فحوصات و ثبت إنها آمنة و أفضل ربمابعد 15-20 سنة + +281 +00:24:50,260 --> 00:24:54,960 +يكتشفوا أضرار معينة إلها ويعود اللي سمع محاضرة عن + +282 +00:24:54,960 --> 00:24:59,680 +فضل هذه الأشياء مثلا صبغات التترازينس يسمع محاضرة + +283 +00:24:59,680 --> 00:25:04,740 +جديدة بعد 15-20 سنة عن أضرار هذه المادةفالإنسان في + +284 +00:25:04,740 --> 00:25:10,160 +هذه المنطقة بصراحة تبقى منطقة علم وليس منطقة تأكد + +285 +00:25:10,160 --> 00:25:16,700 +في التشخيص شخصه غلط وهذا أمر طبيعي وفي النهاية + +286 +00:25:16,700 --> 00:25:22,440 +بنقدر نقول بالتأكيد ومن خلال أشعة X من ال 1865 + +287 +00:25:22,440 --> 00:25:27,200 +لليوم ماحدش بيجادل إطلاقا بخصوص شكل البنزين بهذا + +288 +00:25:27,200 --> 00:25:32,270 +الشكليعني احنا بنقدر نقول بنسبة كبيرة بس احتراما + +289 +00:25:32,270 --> 00:25:37,490 +لمبدأ ان العلم متغير ممكن يقول بنسبة 100% بس ممكن + +290 +00:25:37,490 --> 00:25:44,050 +يقول بنسبة 99.9% ان البنزين بهذا الشكل واضح؟ ومن + +291 +00:25:44,050 --> 00:25:49,350 +ال 1865 لليوم لأ ما اجهز شكل جديد درس البنزين بهذا + +292 +00:25:49,350 --> 00:25:56,750 +الشكلهذا كيكولي الان حكينا عن ال resonance وهذا + +293 +00:25:56,750 --> 00:26:02,590 +بيعمل orbitals بحيث انه بتعمل فوق البنزين و تحت + +294 +00:26:02,590 --> 00:26:05,010 +البنزين سحابة إلكترونية + +295 +00:26:07,750 --> 00:26:11,830 +فكرة وجود سحابة إلكترونية يعني لما أنا أتخيل أن + +296 +00:26:11,830 --> 00:26:17,670 +هذا هو البنزين أن هذا هو البنزين و فوقه إلكترونات + +297 +00:26:17,670 --> 00:26:21,230 +و تحته إلكترونات جايين من ال بي أوربيتالز يعني + +298 +00:26:21,230 --> 00:26:25,450 +كتلة إلكترونات بناء على ذلك هذا الكلام هيفيدني في + +299 +00:26:25,450 --> 00:26:30,630 +التفاعلات شو اللي بيقدر يجرب من البنزين عشان + +300 +00:26:30,630 --> 00:26:36,830 +يتفاعل معه إيش لازم يكون موجب موجبElectrophile + +301 +00:26:36,830 --> 00:26:43,390 +يعني مش ممكن يقدر بالوضع الطبيعي الـ Eucleophile + +302 +00:26:43,390 --> 00:26:49,310 +يجرب على البنزين لأن طبيعة الدنيا أن السالب يتنافر + +303 +00:26:49,310 --> 00:26:53,610 +مع السالب انا هنا عندي إلكترونات .. أنا هنا عندي + +304 +00:26:53,610 --> 00:27:01,590 +إلكترونات أجيب عليها شيء سالبسالب على سالب بيصير و + +305 +00:27:01,590 --> 00:27:05,550 +لذلك من أكبر الأخطاء من أكبر الأخطاء اللي + +306 +00:27:05,550 --> 00:27:09,270 +بيرتكبوها الطلاب ان احنا مرات لما نيجي نقولهم و + +307 +00:27:09,270 --> 00:27:14,550 +الله كيف بتحضروا الفينول الان الطالب اللي مادرسش + +308 +00:27:14,550 --> 00:27:18,390 +روح الكيميا و مبادئ الكيميا بيقول يالا بتمشي هاد + +309 +00:27:18,390 --> 00:27:23,830 +معايا بيروح برسوملنا بنزين و بيقول في وجود ال OH + +310 +00:27:23,830 --> 00:27:33,430 +minus بتبدل H من هنابال OH صرفيلون هذه مشكلة ليش؟ + +311 +00:27:33,430 --> 00:27:39,570 +لأن هنا إلكترونات وهذه سالبة ممكن هذا الكلام عمره + +312 +00:27:39,570 --> 00:27:47,310 +يصير؟ مش ممكنولذلك التفاعل الأساسي لل aromatic + +313 +00:27:47,310 --> 00:27:52,230 +compounds هو ال electrophilic substitution زي ما + +314 +00:27:52,230 --> 00:27:56,430 +هيمر علينا انه اللي بده يهاجم بده يكون موجب لأنه + +315 +00:27:56,430 --> 00:28:01,450 +البنزين عبارة عن سحابة إلكترونية فوق وتحت الجزيرة + +316 +00:28:01,450 --> 00:28:03,350 +كذا بده يجي يهاجم سالب ع سالب + +317 +00:28:11,350 --> 00:28:15,070 +الان قبل ما ناخد التفاعلات ناخد تسمية الـ aromatic + +318 +00:28:15,070 --> 00:28:21,050 +compounds بالنسبة للتسمية في عندنا مركبات أخدت + +319 +00:28:21,050 --> 00:28:24,710 +شهرة عبر الزمن هذه بتصير جزء من التسمية و لازم + +320 +00:28:24,710 --> 00:28:29,570 +نحفظها و في تسمية اشتقاقية الان في البداية + +321 +00:28:29,570 --> 00:28:34,530 +المركبات اللي أخدت شهرة و لازم نحفظها زي ما هي على + +322 +00:28:34,530 --> 00:28:40,810 +رأسهاالبنزين يعني احنا سابقا قلنا ان البنزين كان + +323 +00:28:40,810 --> 00:28:46,620 +ممكن نسميه Cyclohexatrieneلأن الـ Cyclohexane فيه + +324 +00:28:46,620 --> 00:28:51,380 +تلاتة إيل لكن هذا الكلام غير جائز ما بنسميه + +325 +00:28:51,380 --> 00:28:56,760 +Cyclohexatriene شو بنسميه؟ بنزين إذا أخد مجموعة + +326 +00:28:56,760 --> 00:29:04,120 +CH3 بصير طلوين إذا أخد مجموعة isopropyl اللي هو ال + +327 +00:29:04,120 --> 00:29:08,720 +isopropyl بنزين بصير كيومين حكينا عنه سابقا اللي + +328 +00:29:08,720 --> 00:29:16,090 +قلنا عنه في الكمونإذا أخد مجموعة الـ vinyl CH + +329 +00:29:16,090 --> 00:29:20,790 +double bond CH2 متذاكرينها ال vinyl؟ اه بنقول عنه + +330 +00:29:20,790 --> 00:29:27,210 +ال styrene لاحظوا معاه ان هذه المجموعات لها أسماء + +331 +00:29:27,210 --> 00:29:32,570 +درسناها لكن ما بنسميه هنا تسمية اشتقاطية يعني + +332 +00:29:32,570 --> 00:29:37,800 +مابنفعش ديجي نقول هذا مثل بنزين لأطولوين هذا + +333 +00:29:37,800 --> 00:29:44,420 +ايزوبروب البنزين لأ اكيومين هذا فينيل بنزين لأ + +334 +00:29:44,420 --> 00:29:50,260 +استيرين هذا هيدروكسي بنزين لأ فينول هذا مثلا + +335 +00:29:50,260 --> 00:29:56,360 +مثوكسي بنزين او مثل مثوكسي مجموعة ال او مثل لوحدها + +336 +00:29:56,360 --> 00:30:02,640 +لها اسم شو بنسميها مثوكسي لكن ما بنسميه مثوكسي + +337 +00:30:02,640 --> 00:30:08,550 +بنزين شو بنسميه أنيزوللو كان في مجموعة ال الديهيد + +338 +00:30:08,550 --> 00:30:13,610 +بنسميه بنزالديهيد لو كان في مجموعة ال C double + +339 +00:30:13,610 --> 00:30:20,170 +bond OCH3 بنسميه أسيتوفينون لو كان في مجموعة + +340 +00:30:20,170 --> 00:30:26,610 +الحامض C double bond OOH بنسميه بنزويك أسيد لو في + +341 +00:30:26,610 --> 00:30:32,170 +ال NH2 أنيلين بنقولوش أمينو بنزين، شو بنقوله؟ + +342 +00:30:32,170 --> 00:30:38,070 +أنيلينالان هذه الأسماء مع الخبرة بالتأكيد لازم + +343 +00:30:38,070 --> 00:30:41,650 +تحفظوها يعني لو جيبنا لك ارسم تفاعل ال benz + +344 +00:30:41,650 --> 00:30:44,490 +aldehyde او اكتب تفاعل ال benz aldehyde مع كذا + +345 +00:30:44,490 --> 00:30:47,510 +ماحدش يجي يقول مش حافظ ال benz aldehyde لأ كل شيء + +346 +00:30:47,510 --> 00:30:52,050 +موجود هنا صار جزء من التسمي اللي لازم طالب بتعلم + +347 +00:30:52,050 --> 00:30:57,670 +في الجامعة يعرفهامعد ذلك .. معد ذلك بنصير نسمي + +348 +00:30:57,670 --> 00:31:01,730 +تسمية اشتقاقية في التسمية الاشتقاقية بنجيب + +349 +00:31:01,730 --> 00:31:06,890 +المجموعة اللي موجودة بننهيها غالبا بال O و بنكتب + +350 +00:31:06,890 --> 00:31:12,770 +بنزين يعني هنا بروم بصير بروم و بنزين هنا نيترو .. + +351 +00:31:12,770 --> 00:31:19,680 +نيترو بنزين هنا اثلإيه في البنزين بروبل بروبل + +352 +00:31:19,680 --> 00:31:23,960 +بنزين هذه تسمية اشتقاقية في التسمية الاشتقاقية ايش + +353 +00:31:23,960 --> 00:31:30,070 +اللي بيكون موجود عندك أصل البنزينطبعا هنا بدكوا + +354 +00:31:30,070 --> 00:31:34,730 +تنتبهوا لنقطة كتير مهمة ان تكون المجموعة اللى + +355 +00:31:34,730 --> 00:31:39,130 +موجودة عند إلها اسم و إلا بتغلب يعني لما طلعت هنا + +356 +00:31:39,130 --> 00:31:43,890 +كلنا عارفين إنه هذا إثل ولا لأ فكان سهل علي أقول + +357 +00:31:43,890 --> 00:31:48,090 +إثل بنزيل كلنا عارفين إنه هذا بروبل ولا لأ سهل إن + +358 +00:31:48,090 --> 00:31:52,550 +أقول بروبل بنزيل أحيانا بتواجهكوا مشكلة كيف بدكم + +359 +00:31:52,550 --> 00:31:58,390 +تحلوها يعني مثلا لو أنا رسمت هذا المركب و حطيت هنا + +360 +00:32:00,820 --> 00:32:08,100 +حلقة بنزين وحطيت هنا CL الأن انتبهوا معي لو واحدة + +361 +00:32:08,100 --> 00:32:13,740 +بدت تقول هذه المجموعة بنزين المشكلة هي لم تدرس اسم + +362 +00:32:13,740 --> 00:32:19,380 +لهذه المجموعة وفعلا مالهاش اسم وجيتها بحول بعرفنه + +363 +00:32:19,380 --> 00:32:24,720 +كالكانبعمله كالكين بقول طب خليني لما عامله كالكين + +364 +00:32:24,720 --> 00:32:30,640 +هاي سلسلة كربون واحد اتنين تلاتة اربعة خمسة هاي + +365 +00:32:30,640 --> 00:32:35,880 +اطول سلسلة كربون حسب ما احنا اتعلمنا اذا هذا + +366 +00:32:35,880 --> 00:32:45,140 +بينتين وعلى اقل ترقيم واحد اتنين تلاتة اربعة خمسة + +367 +00:32:45,140 --> 00:32:50,970 +صار three cloroوهذه المجموعة البنزين نفسها فنل + +368 +00:32:50,970 --> 00:32:59,270 +اتنين فنل بنتين بيمشي الحال حلنا المشكلة تبعتنا + +369 +00:33:00,360 --> 00:33:05,220 +يعني مش ملزمين كل ما نشوف حلقة بنزين إننا لازم + +370 +00:33:05,220 --> 00:33:10,460 +ننهي الإسم تبعنا بنزين لأ إذا المجموعة إلها إسم + +371 +00:33:10,460 --> 00:33:15,300 +بسيط okay بنسمي بنزين إذا مالهاش هي نفس حلقة + +372 +00:33:15,300 --> 00:33:22,100 +البنزين كمجموعة اسمها إيش؟ فنل و بنعمل المركب على + +373 +00:33:22,100 --> 00:33:26,300 +إنه الكن و بيك منكون حلنا مشكلتنا + +374 +00:33:28,600 --> 00:33:35,240 +فنل بالظبط المجموعة اللى هو C6H6 لما بفقد H بصير + +375 +00:33:35,240 --> 00:33:42,480 +C6H5 اسمه فنل واضح؟ وعشان ايه سابقا بتذكر وقلتلكوا + +376 +00:33:42,480 --> 00:33:48,400 +ميزوا كلمة فنل عن فنل لإن الفنل شيء الفنل هي هذه + +377 +00:33:48,400 --> 00:33:53,090 +المجموعةلكن هذا ماسميناهوش فينيل لإنه ماخد اسم + +378 +00:33:53,090 --> 00:33:56,350 +شهرة الستايرين و أخدناله كمان البوليمار اللي + +379 +00:33:56,350 --> 00:34:00,110 +بيعمله شو سمينا البوليمار تبعه بوليستايرين + +380 +00:34:00,110 --> 00:34:03,270 +البوليمار سميناه بوليستايرين + +381 +00:34:10,410 --> 00:34:16,170 +الان لحتى الان اللي احنا سمنا مركبات بنزين فيها + +382 +00:34:16,170 --> 00:34:20,470 +one substituent يعني بس ابدلت فيها هيدروجينة واحدة + +383 +00:34:20,470 --> 00:34:28,310 +الان طيب يا ترى لو صار عندى ابدال اكثر من مجموعةلو + +384 +00:34:28,310 --> 00:34:33,210 +صار عندى إبدال أكثر من مجموعة هنا الحقيقة بيصير + +385 +00:34:33,210 --> 00:34:37,730 +عندنا نقطتين بدنا ننتبه لهم لما بيصير عندى إبدال + +386 +00:34:37,730 --> 00:34:44,230 +أكثر من مجموعة خليني أرسم مركب بشكل يعني هيك شوية + +387 +00:34:44,230 --> 00:34:53,530 +عشوائي لو كتبت هنا CH3 مثلا و هنا Pro هاي صار عليه + +388 +00:34:53,530 --> 00:34:59,680 +مجموع تانيهل يا تورا .. هل يا تورا بدي اعتبر ان + +389 +00:34:59,680 --> 00:35:04,880 +المركب الاصلي اللي عندى هو هذا اللى كان اسمه طلوين + +390 +00:35:04,880 --> 00:35:09,220 +و اقول ع موقع واحد اتنين تلاتة بيحمل بروم اسميه + +391 +00:35:09,220 --> 00:35:14,540 +three bromotolwinأو اعتبر المركب الأساسي اللي عندي + +392 +00:35:14,540 --> 00:35:20,520 +هو هذا برومو بنزين وع موقع واحد اتنين تلاتة اقول + +393 +00:35:20,520 --> 00:35:26,900 +three مثل برومو بنزين بيصير لإيش بدي أنسب المركب + +394 +00:35:26,900 --> 00:35:31,680 +تبعي بمعنى انا بدي اعمل عائلة للمركبهل يا ترى + +395 +00:35:31,680 --> 00:35:35,300 +العائلة بدت تكون تابعة المثل وبالتالي اخر الاسم + +396 +00:35:35,300 --> 00:35:39,420 +اللى بده يبين عندى هيكون تلوين ولا بدت تتبع البروم + +397 +00:35:39,420 --> 00:35:43,200 +وبالتالي اخر الاسم اللى بده يبين عندى بده يكون + +398 +00:35:43,200 --> 00:35:50,900 +برومو بنزين او مثلا مثال زى هذا لو حطيت هنا c + +399 +00:35:50,900 --> 00:35:58,210 +double bond o hالان اذا واحدة اتطلعت بهذا الشكل + +400 +00:35:58,210 --> 00:36:02,470 +هتقول طلوين يحمل على نمرة أربعة هذه المجموعة طب + +401 +00:36:02,470 --> 00:36:07,710 +اذا واحدة اتطلعت بهذا الشكل هتقول بنزالديهيد يحمل + +402 +00:36:07,710 --> 00:36:11,970 +على نمرة أربعة هذه المجموعة الان نهاية المركب تبع + +403 +00:36:11,970 --> 00:36:19,910 +عائلته هل هي يا ترى طلوين ولا بنزالديهيدهذا احنا + +404 +00:36:19,910 --> 00:36:24,670 +بحاجة انه تصبروا علينا شوية بهدوء حتى نتعلموا الان + +405 +00:36:24,670 --> 00:36:29,010 +اذا اتعلمنا ايش العائلة الأساسية اللي موجودة عندنا + +406 +00:36:29,010 --> 00:36:33,390 +بعد هيك الأمور بتصير سهلة يعني افترضوا جدلا انه + +407 +00:36:33,390 --> 00:36:38,810 +قولنا العائلة الأساسية تتبع هذه المجموعة اذا + +408 +00:36:38,810 --> 00:36:43,510 +المركب ايش Benzaldehyde ده المركب الأصلي باجي بقول + +409 +00:36:43,510 --> 00:36:47,430 +اذا والله وجدت مجموعة على هذا الموقع ببدأ ترقيمي + +410 +00:36:47,430 --> 00:36:55,460 +من هنا1 2 3 4 إذا وجدت مجموعة هذا الموقع بقول two + +411 +00:36:55,460 --> 00:37:02,340 +whatever بنزل دي هايت إذا كانتها three بنزل دي + +412 +00:37:02,340 --> 00:37:07,500 +هايت إذا كانتها four بنزل دي هايت الآن بدل ال two + +413 +00:37:07,500 --> 00:37:14,840 +ممكن أكتب ortho يعني يا بكتب two يا بكتب ايش ortho + +414 +00:37:14,840 --> 00:37:21,580 +small o بدل التلاتةميتا بدل الأربعة بارا فالان + +415 +00:37:21,580 --> 00:37:25,660 +بهذا المنطق انتبهوا معي هذه من الأخطاء الشائعة جدا + +416 +00:37:25,660 --> 00:37:30,220 +عن طلاب الكيميا ان هم بتخيلوا قصة اورتو ميتا و + +417 +00:37:30,220 --> 00:37:35,560 +بارا ان انا عندى شكل زى ما احنا كاتبينه هنا ان هذا + +418 +00:37:35,560 --> 00:37:41,360 +المكان اورتو هذا المكان ميتا هذا المكان بارابارا + +419 +00:37:41,360 --> 00:37:48,560 +لأ ما تفكروش بهذا الشكل فكروا بمجموعة موجودة أصلا + +420 +00:37:48,560 --> 00:37:54,140 +اللي بيكون بالنسبة لها على موقع اتنين ايش بدو يكون + +421 +00:37:54,140 --> 00:37:59,840 +اورتو اللي على موقع تلاتة ميتا اللي على موقع أربعة + +422 +00:37:59,840 --> 00:38:06,720 +بارا يعني لو أنا رسمت مركب بهذا الشكل وحطيت هنا OH + +423 +00:38:06,720 --> 00:38:10,690 +وخليني أقول اعتبرها هي الأساساللي بدأ اسمه يعني + +424 +00:38:10,690 --> 00:38:19,210 +مركب ايش؟ فينول الان اتيت و حطيت هنا كلور وجدت ايش + +425 +00:38:19,210 --> 00:38:23,850 +بدأ اسم هذا المركب طبعا طالما الاساس هذا اذا هي + +426 +00:38:23,850 --> 00:38:31,410 +الواحد اما بدأ اقول two chlorofenol + +427 +00:38:31,410 --> 00:38:37,370 +او ممكن ال two استبدلها ب orthoأنا مش كتير بحب ال + +428 +00:38:37,370 --> 00:38:40,650 +Orth والميتا والبارا، يعني أنا بنصحكم أكتبوا + +429 +00:38:40,650 --> 00:38:46,270 +أرقام، أكتبوا أرقام منطلقين أنه نقطة البداية هي + +430 +00:38:46,270 --> 00:38:51,960 +العائلة اللي حتى الآن مااتفقناش كيف نعرفهالحد الآن + +431 +00:38:51,960 --> 00:38:56,000 +ماحكيناش كيف نعرف العائلة، لكن احنا بنكتب أرقام، + +432 +00:38:56,000 --> 00:38:59,700 +الآن بعد ما نسمي، إذا واحدة بتحب هذه الرموز، تروح + +433 +00:38:59,700 --> 00:39:03,000 +تشتب الإتنين، تحط مكانها Orth أو تشتب التلاتة، + +434 +00:39:03,000 --> 00:39:06,160 +مكانها ميتا أو تشتب الأربعة، مكانها بارا، يحرق، + +435 +00:39:06,160 --> 00:39:11,360 +ماعملتش، و من هنا لحد ما خلصت الكورس معنا، ولا مرة + +436 +00:39:11,360 --> 00:39:14,660 +كتبت بإيدها Orth و ميتا و بارا، كتبت اتنين و تلاتة + +437 +00:39:14,660 --> 00:39:21,460 +و أربعة، هي بتشتغل شغلصحيح و بالمناسبة قصة الارثو + +438 +00:39:21,460 --> 00:39:26,400 +والنيتا والبارا هي قصة بس بتنوجد لو عندي two + +439 +00:39:26,400 --> 00:39:30,420 +substituents بمعنى لو كان عندي هذا المركب و خليني + +440 +00:39:30,420 --> 00:39:34,760 +اقول ما زلت مصير ان العائلة تبعت ال OH و اجيت و + +441 +00:39:34,760 --> 00:39:44,680 +حطيت هنا CH3 و هنا PR و بدي اسميه الان قولة واحدة + +442 +00:39:44,680 --> 00:39:50,540 +ان انا بستعمل الأرقاممافي امكانية ان اقعد تلاتة + +443 +00:39:50,540 --> 00:39:56,300 +اربعة خمسة ستة واتفقت انه مركب ايش؟ Phenol الان + +444 +00:39:56,300 --> 00:40:01,560 +هنا فقط باستعمل نظام الأرقام بدي اقول five bromo + +445 +00:40:01,560 --> 00:40:06,600 +two cloro three مثل ال alphabetical ذكرتهم + +446 +00:40:06,600 --> 00:40:19,750 +ماتبهين؟ five bromo two cloro threeمثل فينول اذا + +447 +00:40:19,750 --> 00:40:24,810 +لو زادوا ال substituents اللى عندى عن تنتين اكيد + +448 +00:40:24,810 --> 00:40:29,350 +بستعمل الأرقام لو كانوا تنتين ربما نقول الأفضل + +449 +00:40:29,350 --> 00:40:33,550 +نستعمل الأرقام و نسيبنا من قصة ارثه ميته برة الان + +450 +00:40:33,550 --> 00:40:36,570 +اذا اي واحدة بدأ تيجي بدل رقم اتنين لما بيكون two + +451 +00:40:36,570 --> 00:40:40,730 +substituents تحط ارثه بدل تلاتة ميته و بدل اربعة + +452 +00:40:40,730 --> 00:40:46,920 +برة مافيش عندنا مشكلةمثلا هذا المركب + +453 +00:40:46,920 --> 00:40:52,060 +Orthodiachlorobenzene هذا ميتا دايمثلبنزين لكن + +454 +00:40:52,060 --> 00:40:58,080 +دايمثلبنزين بياخد اسم شهرة إكزايلينولذلك مرة سئلنا + +455 +00:40:58,080 --> 00:41:01,580 +الطلاب في الامتحان ارسمولنا بار اكزايلين احنا + +456 +00:41:01,580 --> 00:41:05,260 +بنقول اكزايلين اللي فيه مجمعتين مثل اذا كانوا جانب + +457 +00:41:05,260 --> 00:41:10,400 +بعض واحد اتنين اورث اكزايلين اذا واحد تلاتة مائة + +458 +00:41:10,400 --> 00:41:14,800 +اكزايلين طب لو يجي واحد اربعة بار اكزايلين واضح + +459 +00:41:14,800 --> 00:41:20,540 +الفكرة هذا المركب مثلاواضح انه في كلورو الديهايد + +460 +00:41:20,540 --> 00:41:25,700 +وانه اعتبر العائلة ال الديهايد ورقم من عندها فجال + +461 +00:41:25,700 --> 00:41:30,360 +المركب بنزل ديهايد وحطله بارا كلورو بنزل ديهايد او + +462 +00:41:30,360 --> 00:41:34,440 +four كلورو بنزل ديهايد لكن السؤال اللي حتى الآن ما + +463 +00:41:34,440 --> 00:41:42,400 +جوابناهوش ليش قلنا العائلة ال الديهايد مش لكلور او + +464 +00:41:42,400 --> 00:41:51,490 +ال OHالـ OH مش الكلور ولا الميثل ولا البروم هذا + +465 +00:41:51,490 --> 00:41:57,850 +السؤال مهم ان نشوفه الان ببساطة امرتبين ال + +466 +00:41:57,850 --> 00:42:01,530 +constituents بترتيب اللي موجود في اعلى بنعتبره + +467 +00:42:01,530 --> 00:42:09,890 +العائلة اول شئ ال halogens هدول اقل مجموعة اقل من + +468 +00:42:09,890 --> 00:42:15,330 +ال alkanesالان ابدأوا تلاحظوا لو وجدت .. و زي الـ + +469 +00:42:15,330 --> 00:42:19,750 +halogens الـ Nitro، الآن الـ O2 لو وجدت ال halogen + +470 +00:42:19,750 --> 00:42:25,450 +مع ال cane، يعني كلور مع مثل، من العائلة؟ المثل لو + +471 +00:42:25,450 --> 00:42:31,630 +وجدت Nitro مع مثل، من العائلة؟ المثل، واضح؟ أقل من + +472 +00:42:31,630 --> 00:42:40,100 +ال alkenes لو وجدت ال cane و ال caneمن العائلة ال + +473 +00:42:40,100 --> 00:42:45,100 +الكين الان لاحظوا هي العائلة ال الكين هذا إيه اسمه + +474 +00:42:45,100 --> 00:42:51,980 +استيرين حيصير واحد اتنين تلاتة ال three مثل + +475 +00:42:51,980 --> 00:42:57,640 +استيرين هذا إيه اسمه طلوين حيصير ال three نيترو + +476 +00:42:57,640 --> 00:43:05,060 +طلوين طبعا ال الكين أقل من ال amines أقل من ال OH + +477 +00:43:06,510 --> 00:43:10,790 +ولذلك لو وجدت مثلًا OH مع الـCl مين العائلة؟ OH + +478 +00:43:10,790 --> 00:43:15,910 +إذا مُركّبة فينول؟ فينول لاحظوا إحنا قلنا ال + +479 +00:43:15,910 --> 00:43:23,170 +الكينز أقل من إيش؟ النيترو اتطلعوا معاه هاي الكين + +480 +00:43:23,170 --> 00:43:28,810 +طلوين و تلاتة نيترو بعتبر إن الترقيم إنها واحد، + +481 +00:43:28,810 --> 00:43:32,870 +اتنين، تلاتة، أربعة، خمسة، ستة إذا صار عند اتنين، + +482 +00:43:32,870 --> 00:43:36,890 +أربعة، ستة، تري، نيترو، طلوينهذا مُركّب الـ TNT + +483 +00:43:36,890 --> 00:43:46,230 +المتفجر لو وجد كيتون أكتر من الـ OH والألديهيد + +484 +00:43:46,230 --> 00:43:51,650 +أعلى من الكيتون والأسد أعلى منهم كلهم وال إيستر + +485 +00:43:51,650 --> 00:43:56,710 +أعلى وأعلى ولذلك هنا لدي ألديهيد و OH من العائلة + +486 +00:43:58,000 --> 00:44:03,540 +الالديهايد اذا بنزالديهايد عند الديهايد وكيتون من + +487 +00:44:03,540 --> 00:44:10,980 +العائلة الديهايد عند الاسد وكيتون الاسد عند + +488 +00:44:10,980 --> 00:44:18,240 +الالكول ونيترو و أتش ونيترو و أتش + +489 +00:44:18,240 --> 00:44:23,930 +واضح؟لو كان عندى halogens بينهم وبين بعض مش مشكلة + +490 +00:44:23,930 --> 00:44:28,250 +بنكتبهم alphabetical يعني ال brom قبل ال chlorine + +491 +00:44:28,250 --> 00:44:32,250 +ال alkyn + +492 +00:44:32,250 --> 00:44:40,430 +زى ال alkene بيكون أعلى من ال alkene ال eastern + +493 +00:44:40,430 --> 00:44:49,760 +من المشتقات الحامض هندرسه السيدة بالمندق OORعائلة + +494 +00:44:49,760 --> 00:44:52,840 +بناخدها بعدين، الآن احنا بنحط الصورة الكلية، + +495 +00:44:52,840 --> 00:44:56,040 +بتهيألي ضمن هذه الصورة الكلية بيصير موضوع التسمية + +496 +00:44:56,040 --> 00:45:01,870 +أصبح واضح لكمالـ slide اللي بننهي عندها انه هذه + +497 +00:45:01,870 --> 00:45:05,650 +بتتدربوا طبعا انتوا على التسمية و لو روحتوا على + +498 +00:45:05,650 --> 00:45:09,910 +الأمثلة اللي معاكم في امتحانات سابقة هتلاحظوا + +499 +00:45:09,910 --> 00:45:12,730 +دائما جايبيني اللي كنت اسمها aromatic compounds + +500 +00:45:12,730 --> 00:45:17,210 +بتفتشوا مين أعلى في المجموعات و تنسبوا إليها زي + +501 +00:45:17,210 --> 00:45:20,810 +الأمثلة الكتيرة اللي عرضناها الآن آخر نقطة بنحكيها + +502 +00:45:20,810 --> 00:45:25,330 +انه هذه ال aromatic compounds في نهاية مش رموزهي + +503 +00:45:25,330 --> 00:45:29,930 +مركبات على أرض الواقع يستفيد الإنسان منها والدليل + +504 +00:45:29,930 --> 00:45:34,130 +على هيك هاي بعض ال aromatic compounds اللي في صميم + +505 +00:45:34,130 --> 00:45:38,310 +الحياة تبع الإنسان يعني هذا المركب aromatic ولا + +506 +00:45:38,310 --> 00:45:43,070 +لأ؟ هذا اسمه Aspirin ال Aspirin اللي أنتوا بتاخدوه + +507 +00:45:43,070 --> 00:45:47,010 +تمام؟ تلت ارباع الناس بعد حصة ال organic يا + +508 +00:45:47,010 --> 00:45:53,190 +Aspirin يا Trophin تعرفولي Trophin أربع .. هايو ال + +509 +00:45:53,190 --> 00:45:59,260 +Ibuprofenواذا روحوا ع البيت و بدهم ياكلوا بدهم كيك + +510 +00:45:59,260 --> 00:46:03,780 +و الكيك بده فانيلا و الفانيلا من الفانيليل من + +511 +00:46:03,780 --> 00:46:08,640 +الفانيليل هي الفانيلا واضح فإحنا مش بنحكي عن رموز + +512 +00:46:08,640 --> 00:46:12,500 +بقدر ما بنحكي حقيقة عن مركبات في واقع الاستعمال + +513 +00:46:12,500 --> 00:46:16,860 +الحياتي و الطب و لذلك بندرس ال organ ال chemistry + +514 +00:46:16,860 --> 00:46:21,340 +و ان شاء الله المرة القادمة بكون موضوعنا تفاعلات + +515 +00:46:21,340 --> 00:46:22,940 +ال aromatic compounds + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..316e8aa7b72162b27a0a545834eeb8539b8fef9c --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/NgHapSfukYs_raw.srt @@ -0,0 +1,2076 @@ +1 +00:00:20,860 --> 00:00:25,560 +بسم الله الرحمن الرحيم اليوم موضوعنا ان شاء الله + +2 +00:00:25,560 --> 00:00:29,680 +هيكون في الفصل الرابع ال aromatic compounds لكن + +3 +00:00:29,680 --> 00:00:36,220 +ضال علينا شغلة صغيرة انا بعتقد انها مهمة من الفصل + +4 +00:00:36,220 --> 00:00:41,640 +الثالث من تفاعلات ال alkynes فخلينا نشوف هذه + +5 +00:00:41,640 --> 00:00:47,680 +النقطة بسرعة و بعدين ننتقل لموضوعنا الأساسي اللي + +6 +00:00:47,680 --> 00:00:53,620 +هو ال aromatic compoundsالنقطة اللى ضالت علينا انه + +7 +00:00:53,620 --> 00:01:00,580 +احنا لما بننظر لل Alkynes اذا كان على احد أطرافهم + +8 +00:01:00,580 --> 00:01:06,020 +على اقل تقدير او ممكن على الطرفين ذرّة هيدروجين + +9 +00:01:06,020 --> 00:01:11,400 +يعني ال Alkyne ممكن يكون R C triple bond C وR تاني + +10 +00:01:11,400 --> 00:01:16,040 +يعني مثل و مثل او فلل و فلل و ممكن يكون R C triple + +11 +00:01:16,040 --> 00:01:22,690 +bond C وموجودزرّة هيدروجين الالكاين اللي بهذا + +12 +00:01:22,690 --> 00:01:27,670 +الشكل اللي في أحد أطرافه زرّة هيدروجين بنسميه احنا + +13 +00:01:27,670 --> 00:01:32,350 +terminal الكاين يعني الكاين الطرفي اللي في أحد + +14 +00:01:32,350 --> 00:01:39,440 +أطرافه ايش فيها terminal الكاينهذه النقطة الأولى + +15 +00:01:39,440 --> 00:01:43,300 +إذا عرفنا إيش معناه Terminal Alkyne اللي على طرف + +16 +00:01:43,300 --> 00:01:49,960 +من الرابط الزوجية فيه موجود عنده ذرة هيدروجين الآن + +17 +00:01:49,960 --> 00:01:54,960 +بنضيف معلومة جديدة بنقول ال terminal alkynes are + +18 +00:01:54,960 --> 00:02:00,680 +acidic ال terminal alkynes are acidic إيش يعني + +19 +00:02:00,680 --> 00:02:07,200 +acidic؟حامضي الان لو انا اجيت اتذكر تعريف الحامض + +20 +00:02:07,200 --> 00:02:10,980 +ممكن ناخد في هذه المرحلة تعريف الوري برونستيد الـ + +21 +00:02:10,980 --> 00:02:19,780 +acid proton donor بيعطي بروتونات بيفقد بروتون الان + +22 +00:02:19,780 --> 00:02:24,660 +اي بروتون حامضي في هذا المركب يعني لحظوا انا لما + +23 +00:02:24,660 --> 00:02:29,460 +رسمت هنا مركب في عندي هنا حلقة Cyclohexane و عليها + +24 +00:02:29,460 --> 00:02:34,030 +هيدروجينأو في مجموعات الميثل والإثل والبروبل + +25 +00:02:34,030 --> 00:02:38,430 +الالكينز كلها ملانة هيدروجين كل هذه الهيدروجينات + +26 +00:02:38,430 --> 00:02:42,730 +اللي في الالكينز و اللي في الالكينز هيدروجينات غير + +27 +00:02:42,730 --> 00:02:46,590 +حامضية ايش معنى هيدروجين غير حامضي انه لا يفقد + +28 +00:02:46,590 --> 00:02:51,370 +بسهولة عند التفاعل مع قاعدةالهيدروجين الحامضي + +29 +00:02:51,370 --> 00:02:56,150 +هيدروجين يفقد بسهولة إذا تم التفاعل مع القاعدة + +30 +00:02:56,150 --> 00:03:00,930 +ولذلك لما نتطلع على مركب عضوي هنلاحظ أنه دائما + +31 +00:03:00,930 --> 00:03:04,330 +المركب العضوي في نوعين من الهيدروجين يعني خليني + +32 +00:03:04,330 --> 00:03:12,190 +أخد مثلا حمض الخل كمثال بسيط حمض الخل CH3COO + +33 +00:03:13,740 --> 00:03:19,780 +OH الآن في عندى نوعين من الهيدروجين هنا هدول التلت + +34 +00:03:19,780 --> 00:03:24,400 +هيدروجينات هيدروجينات عادية لو انا كنت بفاعل مع + +35 +00:03:24,400 --> 00:03:28,820 +قاعدة لا يفقدوا مع القاعدة they are non acidic مش + +36 +00:03:28,820 --> 00:03:34,580 +هيدروجين حامضى الان الهيدروجين اللى متصل بال OH في + +37 +00:03:34,580 --> 00:03:39,320 +الحامض هذا هيدروجين حامضى هذا اللى بيفقد لما انا + +38 +00:03:39,320 --> 00:03:44,630 +باجى بعمل تفاعل مع baseفصار في عندى acidic + +39 +00:03:44,630 --> 00:03:49,530 +hydrogen و non acidic hydrogen او بيكون على اقل + +40 +00:03:49,530 --> 00:03:54,370 +تقدير اضعف المسألة مسألة ضعف و قوة يعنى هذه + +41 +00:03:54,370 --> 00:03:58,770 +الهيدروجينة حمضية بشكل كبير تفقد بسهولة هذه حمضية + +42 +00:03:58,770 --> 00:04:04,270 +بشكل قليل جدا تفقد بصعوبةممكن لو جيبنا base قوي + +43 +00:04:04,270 --> 00:04:08,810 +جدا جدا عود نفقدها لكن على base عادي مثلا خلّيني + +44 +00:04:08,810 --> 00:04:12,410 +أقول Sodium Hydroxide أو حتى Sodium Carbonate + +45 +00:04:12,410 --> 00:04:17,490 +قاعدة عادية بدي أفعلها أي هيدروجين اللي بدي تفقد + +46 +00:04:17,490 --> 00:04:22,450 +الـ acidic هيدروجين عشان ذلك بكل كوب تذكروا + +47 +00:04:22,450 --> 00:04:28,470 +التفاعل زائد MAالـ OH هي الـ base of Sodium + +48 +00:04:28,470 --> 00:04:32,670 +Hydroxide الأن الـ OH هي الـ base مع هذه الـ H + +49 +00:04:32,670 --> 00:04:39,830 +كنتوا متعودين تقولوا بيكون عندك ماء حمض زائد قاعدة + +50 +00:04:39,830 --> 00:04:44,650 +ملح زائد ماء لما هذه الـ H تفقد على شكل H plus + +51 +00:04:44,650 --> 00:04:49,880 +هتظل إلكتروناتالرابطة بتاعتها بالاضافة لزوجين + +52 +00:04:49,880 --> 00:04:54,700 +الأساسيات الاساسيات حيصير عليكم CH3C double bond O + +53 +00:04:54,700 --> 00:05:00,100 +O كم زوج إلكترونات عليها تلاتة أصلا زوجين + +54 +00:05:00,100 --> 00:05:04,220 +إلكترونات و رابطتين فقدت ال H لواحدها بدون + +55 +00:05:04,220 --> 00:05:10,000 +إلكتروناتها عشان ال H plus ال OH minus أخدت إيش ال + +56 +00:05:10,000 --> 00:05:18,210 +H plus شو صفية هذه minus مع ال NAplus صار sodium + +57 +00:05:18,210 --> 00:05:23,650 +acetate خلات الصوديوم acidic acid زايد NaOH Sodium + +58 +00:05:23,650 --> 00:05:30,450 +acetate زايد H2O حمض زايد قاعدة ملح زايد ماء هذا + +59 +00:05:30,450 --> 00:05:35,090 +تذكير خلينا نقول بمفهوم الحمض والقاعدة الآن لو + +60 +00:05:35,090 --> 00:05:40,690 +اجينا نطبق بنفس المنطق على ال terminal الكاين و + +61 +00:05:40,690 --> 00:05:47,550 +اتخيلنا ان هذا ال terminal الكاين عبارة عنacid وين + +62 +00:05:47,550 --> 00:05:53,450 +ال acidic hydrogen اللي فيه هادف الان نتخيل انه + +63 +00:05:53,450 --> 00:05:57,910 +عندنا رابطة بين الكربون و الهيدروجين لاحظوا معي + +64 +00:05:57,910 --> 00:06:03,350 +الكربون لا يحمل اي زوج إلكترونات حرة فيه اربع + +65 +00:06:03,350 --> 00:06:08,190 +روابط و لذلك حتى الكربون بشكله الطبيعي كان بيصلح + +66 +00:06:08,190 --> 00:06:14,950 +اللأ تذكروا المرات الماضية قلنا ان ال oxygen في + +67 +00:06:14,950 --> 00:06:18,370 +رابطتين و زوجين إلكترونات من خلال أزواج + +68 +00:06:18,370 --> 00:06:22,940 +الإلكترونات بيعمل ال UQ fileالنيتروجين في تلت + +69 +00:06:22,940 --> 00:06:28,060 +روابط وزوج إلكترونات أيضا بيعمل الـ eucleophile من + +70 +00:06:28,060 --> 00:06:33,720 +خلال زوج الإلكترونات الهالوجين في رابطة تلت أزواج + +71 +00:06:33,720 --> 00:06:37,020 +إلكترونات أيضا ممكن يعمل الـ eucleophile من خلال + +72 +00:06:37,020 --> 00:06:42,850 +أزواج الإلكترونات الكاربونفي أربع روابط فبالوضع + +73 +00:06:42,850 --> 00:06:47,850 +الطبيعي هل ال carbon بيعمل ال nucleophile لأ واضح + +74 +00:06:47,850 --> 00:06:52,490 +الان لو اتيت لهذا المركب فعالته مع strong base + +75 +00:06:52,490 --> 00:06:59,410 +NaNH2 هذه موازية تماما لل NaOH يعني كلكم بتعرفوا ك + +76 +00:06:59,410 --> 00:07:08,630 +base NaOH شو كنا نسميها Sodium Hydroxide الان + +77 +00:07:08,630 --> 00:07:17,130 +NaNH2 شبه بها تماما بنسميها Sodium Amide وهذه + +78 +00:07:17,130 --> 00:07:20,670 +قاعدة + +79 +00:07:20,670 --> 00:07:25,250 +قوية اقوى من Sodium Hydroxide اقوى من Sodium + +80 +00:07:25,250 --> 00:07:31,110 +Hydroxide لما نيجي نتخيل ان هذا الحمد وهذه القاعدة + +81 +00:07:31,860 --> 00:07:37,260 +هتيجي ال N H2 تتفاعل مع ال H Plus لوحدها شو + +82 +00:07:37,260 --> 00:07:44,800 +هتعطيني N H3 زي ما كانت ال O H minus تاخد ال H ال + +83 +00:07:44,800 --> 00:07:52,600 +N H2 minus بتاخد ال H O H مع H H2O N H2 minus مع H + +84 +00:07:52,600 --> 00:07:59,980 +N H3 نفس التفاعل الآن لما فقدت هذه ال H شو دل على + +85 +00:07:59,980 --> 00:08:07,790 +الكربون؟تلات روابط و إلكترونين إلكترونين قصدكم زوج + +86 +00:08:07,790 --> 00:08:11,930 +إلكترونات واحد تلات روابط و إلكترونين هاي واضحها + +87 +00:08:11,930 --> 00:08:17,070 +تلات روابط و إلكترونين الآن لو إجينا حسبنا ال + +88 +00:08:17,070 --> 00:08:23,130 +formal charge على هذه ال carbon أربعةالكربون ناقص + +89 +00:08:23,130 --> 00:08:28,370 +تلات روابط ناقص إلكترونين minus one صارت الكربون + +90 +00:08:28,370 --> 00:08:34,070 +minus والصوديوم plus هذا بنسميه صوديوم أستيلايد زي + +91 +00:08:34,070 --> 00:08:37,370 +ما مثلا مع ال hcl بنقول صوديوم كلورايد وصوديوم + +92 +00:08:37,370 --> 00:08:41,710 +برومايد في التفاعلات الآن لاحظوا إيش اللي نشأ عندى + +93 +00:08:41,710 --> 00:08:48,050 +الآنIon سالب carbon nucleophile صار في عندي carbon + +94 +00:08:48,050 --> 00:08:52,550 +عليه أزواج إلكترونات يعني لو روحت بدي أخد هذا ال + +95 +00:08:52,550 --> 00:08:58,170 +Ion اللي نتج عنده و أفعله أي تفاعل كان nucleophile + +96 +00:08:58,170 --> 00:09:03,330 +بتفعل ولا لأ بتفعل فهذه المركبات اللي عادة بنعطيها + +97 +00:09:03,330 --> 00:09:10,390 +اسم العام Acetylides they are in fact carbon + +98 +00:09:10,390 --> 00:09:14,670 +nucleophilesيعني لو قلنا ال Acetylates ايش ممكن + +99 +00:09:14,670 --> 00:09:21,470 +نعتبرها؟ Carbon Enucleophile الان لاحظوا انه ال + +100 +00:09:21,470 --> 00:09:25,290 +carbon بالوضع الطبيعي كان سهل يكون عامل carbon + +101 +00:09:25,290 --> 00:09:30,070 +enucleophile لأ بعملش لكن انا لما فقدت بروتون منه + +102 +00:09:30,070 --> 00:09:33,870 +و خلت زوجي الإلكترونات صار هذا زوجي الإلكترونات + +103 +00:09:33,870 --> 00:09:39,090 +اللي على ال carbon يمثل carbon enucleophile طالما + +104 +00:09:39,090 --> 00:09:44,920 +انه اتكون عندي carbon enucleophileبقدر يتفاعل الـ + +105 +00:09:44,920 --> 00:09:49,900 +nucleophile مثلا لو اتي اتفاعلته مع مثل ايودايد + +106 +00:09:49,900 --> 00:09:55,160 +ممكن يعمل تفاعل ابدال ان هذا زوج الالكتروناتي هاجم + +107 +00:09:55,160 --> 00:09:59,600 +على الكربون و يطرد اليود مع زوج الالكتروناتي هذا + +108 +00:09:59,600 --> 00:10:04,190 +ايش اسم التفاعل؟Substitution Reaction أو تفاعل + +109 +00:10:04,190 --> 00:10:10,450 +إحلال الـ Eucleophil بيحل محل الـ Eucleophil بيجي + +110 +00:10:10,450 --> 00:10:14,690 +الكربون مع زوج الإلكترونات اللي معه بيحل محل اليود + +111 +00:10:14,690 --> 00:10:19,150 +و بيطلع اليود مع زوج الإلكترونات بدل ما كان عنده + +112 +00:10:19,150 --> 00:10:24,120 +أنا Sodium Acetylide هيطلع عندى في النهايةSodium + +113 +00:10:24,120 --> 00:10:29,920 +Iodide يعني كأنه هذا تفاعل تبادل مزدوج اللي مار + +114 +00:10:29,920 --> 00:10:36,540 +عليكم واضح ففائدة هذا التفاعل ان هو وفر لي ال + +115 +00:10:36,540 --> 00:10:40,520 +carbon nucleophile اللي بالوضع المتعادل عادة مش + +116 +00:10:40,520 --> 00:10:43,920 +متوفر وانا بعد هيك باستفيد من ال carbon + +117 +00:10:43,920 --> 00:10:49,780 +nucleophile في تفاعلات الإبدال وغيرها ممكن الآننجي + +118 +00:10:49,780 --> 00:10:56,760 +نختبر معلوماتكم احنا المرة الماضية أخدنا عن تفاعل + +119 +00:10:56,760 --> 00:11:02,980 +كنا بنستعمل فيه الـUQ5 مين تتذكر شو هو التفاعل الـ + +120 +00:11:02,980 --> 00:11:08,430 +Epoxide كان يعمل ring openingمع اليوكليوفايل لما + +121 +00:11:08,430 --> 00:11:12,430 +أخدنا تفاعل الابوكسايد المعادلة العامة اللى + +122 +00:11:12,430 --> 00:11:18,270 +كتبناها كنا نقول اليوكليوفايل عليه أزواج إلكترونات + +123 +00:11:18,270 --> 00:11:24,510 +زائد الابوكسايد كان بيفتح الحلقة بيعطينا CH2 إذا + +124 +00:11:24,510 --> 00:11:33,010 +افترضنا هذه CH2 OH و بيجي هنا بتفاعل إيشلنكليوفايل + +125 +00:11:33,010 --> 00:11:36,950 +هى ال ring opening اللى أخدناه لل Epoxides الان + +126 +00:11:36,950 --> 00:11:41,250 +بدنا نيجي نعوض بدل كلمة نكليوفايل زى ما تعون + +127 +00:11:41,250 --> 00:11:46,850 +الرياضيات بيكتب X و Y للمجهيل بدنا نجيب لنكليوفايل + +128 +00:11:46,850 --> 00:11:55,250 +تبعنا الacetylide يعنىCH3C triple bond C ويحمل زوج + +129 +00:11:55,250 --> 00:12:00,730 +إلكترونات صار إيش minus و الفاعل هذا مع هدف شو + +130 +00:12:00,730 --> 00:12:07,430 +بتتوقع بده يكون الناتج بده يشبك من + +131 +00:12:07,430 --> 00:12:11,530 +خلال زوج الإلكترونات هذا إذا أنا لما بحط الناتج + +132 +00:12:11,530 --> 00:12:16,070 +هنا ممكن أحطه باللون الأحمر هيكون بهذا الشكل C + +133 +00:12:16,070 --> 00:12:18,190 +triple bond C + +134 +00:12:22,290 --> 00:12:27,350 +هذه الاسيتيلايد اتفاعل كان يوكليوفايل هاجم على + +135 +00:12:27,350 --> 00:12:33,490 +الكربون وعمل ring opening و تم التفاعل بشكل كامل + +136 +00:12:33,490 --> 00:12:34,770 +واضح؟ + +137 +00:12:38,830 --> 00:12:43,190 +فهمنا اذا هذه النقطة اللى كانت ضايلة عندنا من ال + +138 +00:12:43,190 --> 00:12:47,570 +chapter تلاتة انه نفهم ايش معنى terminal alkynes + +139 +00:12:47,570 --> 00:12:51,390 +نمرة واحد، نمرة اتنين ان نقول ان terminal alkynes + +140 +00:12:51,390 --> 00:12:56,110 +are acidic when reacted with bases they form + +141 +00:12:56,110 --> 00:13:00,170 +carbon enucleophiles الآن ال carbon enucleophiles + +142 +00:13:00,170 --> 00:13:02,810 +are like any nucleophile they can undergo + +143 +00:13:02,810 --> 00:13:06,590 +substitution reactions or any enucleophilic + +144 +00:13:06,590 --> 00:13:07,150 +reaction + +145 +00:13:11,320 --> 00:13:17,460 +بهيك بننتهي من الفصل التالت في عندكم بالتأكيد + +146 +00:13:17,460 --> 00:13:21,660 +تدريبات موجودة و احيانا محلولة اكمال المعادلات و + +147 +00:13:21,660 --> 00:13:27,320 +ما إلى ذلك بعتقد انه بيكون جزء من المطلوب منكم ان + +148 +00:13:27,320 --> 00:13:36,660 +تجتهدوا في تحضيرها و فاهمها بننتقل مباشرة ل الفصل + +149 +00:13:36,660 --> 00:13:43,940 +الرابع و الفصل الرابع بعنوانAromatic compoundsربما + +150 +00:13:43,940 --> 00:13:47,500 +ال aromatic compounds لو بدنا نشوف موقعها من + +151 +00:13:47,500 --> 00:13:52,720 +الإعراب في ال hydrocarbons they are unsaturated + +152 +00:13:52,720 --> 00:13:56,700 +hydrocarbons احنا درسنا ال الكينز ال cycloalkyns + +153 +00:13:56,700 --> 00:14:00,160 +ال الكينز ال alkynes ضال علينا ال aromatic + +154 +00:14:00,160 --> 00:14:03,540 +compounds الآن أبسط تعريف ممكن نعطيله ال aromatic + +155 +00:14:03,540 --> 00:14:07,520 +compounds they are بنزين like compounds المركبات + +156 +00:14:07,520 --> 00:14:14,170 +اللي زي البنزين بمعنى فيهم الحلقة و فيهمأزواج + +157 +00:14:14,170 --> 00:14:20,550 +الألكترونات أو الروابط الزوجية بشكل معين وبعدد + +158 +00:14:20,550 --> 00:14:26,730 +معين الان في نقطة كتير مهمة يمكن كل هذا ال slide + +159 +00:14:26,730 --> 00:14:33,530 +أخدناها ماعدا نقطة واحدة اللي هو ايش طول الرابط في + +160 +00:14:33,530 --> 00:14:37,930 +البنزينما هو bond order في البنزين وما هو طول + +161 +00:14:37,930 --> 00:14:41,230 +الرابط في البنزين احنا أخدنا معلومات عن الرابط + +162 +00:14:41,230 --> 00:14:45,910 +الأحدية والثنائية والثلاثية طبعا كلكوا انتوا + +163 +00:14:45,910 --> 00:14:49,950 +متذكرين البنزين ومتذكرين ال resonance structures + +164 +00:14:49,950 --> 00:15:01,270 +اللي بيعملها بهذا الشكل و بهذا الشكل الان لو اتيت + +165 +00:15:01,270 --> 00:15:06,210 +طلعت على رابط معين خليني اقول هذه الرابطةهذه + +166 +00:15:06,210 --> 00:15:11,810 +الرابطة هنا تبدو إيش؟ أحدية هذه الرابطة هنا تبدو + +167 +00:15:11,810 --> 00:15:16,850 +أحدية هذه الرابطة هنا تبدو ثنائية الآن احنا بنقول + +168 +00:15:16,850 --> 00:15:20,770 +البنزيل in resonance structure يعني بين هذه وبين + +169 +00:15:20,770 --> 00:15:25,970 +هذه بناء على ذلك لو بدي أجي أسأل ال bond order في + +170 +00:15:25,970 --> 00:15:31,130 +البنزيل قداشر هل هو يا ترى أحدى ولا ثنائي؟ هو قاعد + +171 +00:15:31,130 --> 00:15:36,830 +بتقلببين الواحد والاتنين بال average ايش هتطلع ال + +172 +00:15:36,830 --> 00:15:41,510 +bond order واحد و نص و ال bond order ممكن تيجي كسب + +173 +00:15:41,510 --> 00:15:45,350 +و لذلك لو اجيت سألت ايش ال bond order في البنزين + +174 +00:15:45,350 --> 00:15:53,590 +واحد و نص هذه الكلمة مهمة جدا جدا هذه الكلمة مهمة + +175 +00:15:53,590 --> 00:15:59,790 +جدا جدا عارفين ليش لأنه انا درست الرابط الاوحدية + +176 +00:15:59,790 --> 00:16:05,520 +في chapter الالكينزو تفاعلاتها و درست الرابط + +177 +00:16:05,520 --> 00:16:09,560 +الثنائية في chapter ال alkanes و تفاعلاتها اللي هي + +178 +00:16:09,560 --> 00:16:17,570 +بشكل أساس تفاعلات الإضافة ال A بجعل ال aromaticلو + +179 +00:16:17,570 --> 00:16:20,710 +ان هذه الرابطة احدية كان كل معلومات ال الكينز + +180 +00:16:20,710 --> 00:16:24,770 +منطبق على البنزين لو انها ثنائية كان كل معلومات ال + +181 +00:16:24,770 --> 00:16:29,450 +الكينز منطبق على البنزين الان الرابطة لا احدية ولا + +182 +00:16:29,450 --> 00:16:34,710 +ثنائية واحد و نص ولذلك ولا تفاعل من تفاعلات ال + +183 +00:16:34,710 --> 00:16:39,110 +الكينز ولا تفاعل من تفاعلات ال الكينز منطبق على + +184 +00:16:39,110 --> 00:16:43,430 +البنزين بنلاحظ ان البنزين هيصير له كيميا خاصة فيه + +185 +00:16:44,110 --> 00:16:48,990 +لأنه لا هو رابطة أحدية ولا هو رابطة ثنائية لا هو + +186 +00:16:48,990 --> 00:16:54,770 +الكل ولا هو الكل واضح هذا النقطة هذا الكلام يتبع + +187 +00:16:54,770 --> 00:16:58,710 +كمان شغلة أنه لو أنا بدي أتي أحكي عن ال bond + +188 +00:16:58,710 --> 00:17:03,310 +length قلنا احنا أنه رابطة الأحدية طويلة الرابطة + +189 +00:17:03,310 --> 00:17:10,160 +الثنائية قصيرة الآن رابطة البنزينوين هتكون؟ بين + +190 +00:17:10,160 --> 00:17:14,740 +بين وبين + +191 +00:17:14,740 --> 00:17:15,160 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +192 +00:17:15,160 --> 00:17:15,760 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +193 +00:17:15,760 --> 00:17:20,320 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +194 +00:17:20,320 --> 00:17:20,380 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +195 +00:17:20,380 --> 00:17:20,540 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +196 +00:17:20,540 --> 00:17:20,540 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +197 +00:17:20,540 --> 00:17:20,540 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +198 +00:17:20,540 --> 00:17:20,540 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +199 +00:17:20,540 --> 00:17:20,540 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +200 +00:17:20,540 --> 00:17:21,340 +وبين وبين وبين وبين وبين وبين وبين وبين وبين وبين + +201 +00:17:21,340 --> 00:17:27,820 +وبين وبين وبين وبين وبين + +202 +00:17:27,820 --> 00:17:35,990 +وبين وبينفلا هي رابطة ثنائية ولا هي رابطة وحدية + +203 +00:17:35,990 --> 00:17:39,650 +ربما احنا اللي بهمنا اكثر النقطة اللي انا ركزت + +204 +00:17:39,650 --> 00:17:43,810 +عليها النقطة اللي انا ركزت عليها ان البنزين مش + +205 +00:17:43,810 --> 00:17:50,730 +هيعمل تفاعلاتالالكينز بشكل أساسي يعني ربما أنه أول + +206 +00:17:50,730 --> 00:17:55,630 +ما نعطي شبتري البنزين و نيجي نرسم بنزينة تفكر + +207 +00:17:55,630 --> 00:17:59,910 +طالبة اجتهدت في موضوع الالكينز بهذا الشكل و هي + +208 +00:17:59,910 --> 00:18:07,930 +شايفة الروابط و نقولها H2OH plus تيجي أول ما تفكر + +209 +00:18:07,930 --> 00:18:15,490 +اضيف H2OH بهاي double bond هنا بيكون إيش عندهخطأ + +210 +00:18:15,490 --> 00:18:19,190 +كبير يعني أنا خايف أكتب و لحظة يتسجل علي في اللوحة + +211 +00:18:19,190 --> 00:18:23,590 +اني كتبت انه بضيف H OH إياكم تفكروا بهذا الشكل + +212 +00:18:23,590 --> 00:18:28,210 +البنزين لا يتعامل كالكيل صح انتوا شايفين تلاتة + +213 +00:18:28,210 --> 00:18:32,990 +double bonds لكن على أرض الواقع لا يتعامل إطلاقا + +214 +00:18:32,990 --> 00:18:36,390 +بتفاعلات الالكيل واضح هذه النقطة؟ + +215 +00:18:44,190 --> 00:18:50,570 +خلّينا نقول كنظرة تاريخية كنظرة تاريخية البنزين + +216 +00:18:50,570 --> 00:18:55,670 +أول ما اكتشف مركب سائل و تم الاكتشاف سنة الف و + +217 +00:18:55,670 --> 00:19:00,390 +تمانمية و خمسة و عشرين من خلال العالم الإنجليزي + +218 +00:19:00,390 --> 00:19:07,990 +Faraday وحتى البنزين اللي هو يعني قطره و حضرهكمية + +219 +00:19:07,990 --> 00:19:12,410 +صغيرة منه ما زالت موجودة لليوم في متحف بريطانيا + +220 +00:19:12,410 --> 00:19:17,170 +نفس السائل البنزين اللي هو فصله فرديه و بيعتزوا + +221 +00:19:17,170 --> 00:19:21,910 +فيه يعني بيعتبروه شئ كبير هذا أول مفصل الآن لما + +222 +00:19:21,910 --> 00:19:26,150 +فصلوا بدوا يعملوا تحليل شو هالمركب لقوا أن الصيغة + +223 +00:19:26,150 --> 00:19:30,830 +الجزائية للبنزين C6H6 + +224 +00:19:31,830 --> 00:19:35,790 +هذه الصيغة الجزائية، لكن يا ترى إيش الصيغة + +225 +00:19:35,790 --> 00:19:41,790 +البنائية؟ الآن صار عندكم خبرة إن صيغة جزائية واحدة + +226 +00:19:41,790 --> 00:19:47,710 +يمكن أن يكون لها عدد كبير من الصيغ البنائيةمظبوط + +227 +00:19:47,710 --> 00:19:52,610 +ولا لأ اللي هي ال structural isomers او حتى ال + +228 +00:19:52,610 --> 00:19:58,190 +stereo isomers فسهل انهم يعرفوا الصيغة الجزائية + +229 +00:19:58,190 --> 00:20:02,590 +بيومين بيعرفوا انه مركب جديد الفصل صيغته الجزائية + +230 +00:20:02,590 --> 00:20:08,830 +C6H6 لكن يا تورا الصيغة البنائية للبنزين 6 ذرات + +231 +00:20:08,830 --> 00:20:13,950 +كربون و 6 ذرات هيدروجين كيف هدول موجودين بأي شكل + +232 +00:20:14,810 --> 00:20:20,350 +هذه العملية معرفة الصيغة البنائية للبنزين أخدت .. + +233 +00:20:20,350 --> 00:20:25,450 +نرجع للتاريخ أن الأجهزة مش متقدمة و العلوم صعبة + +234 +00:20:25,450 --> 00:20:32,510 +أخدت أربعين سنة أربعين سنة لما قدروا يقولوا أن + +235 +00:20:32,510 --> 00:20:38,070 +صيغة C6H6 في النهاية هي صيغة البنزين بهذا الشكل + +236 +00:20:38,690 --> 00:20:43,370 +اللي اقترحها العالم Kekuli الآن أثناءها الأربعين + +237 +00:20:43,370 --> 00:20:49,350 +سنة اقترحت صياغ كثيرة و أخدت أسماء و أحيانا درست + +238 +00:20:49,350 --> 00:20:53,490 +للطلاب لأن اللي كانوا بيقترحوه علماء كبار يعني كل + +239 +00:20:53,490 --> 00:20:57,750 +هذه الصياغ فيها Carbons و Hydrogens و لو كملتوا ال + +240 +00:20:57,750 --> 00:21:02,510 +Hydrogens حسب ما احنا اتعلمنا هتلاحظوا ان هذه + +241 +00:21:02,510 --> 00:21:08,270 +الصياغ كلها او هذه المركبات بأشكالها المختلفة C6H6 + +242 +00:21:08,780 --> 00:21:14,940 +يعني هذا مثلا هي carbon اتنين تلاتة اربعة خمسة ستة + +243 +00:21:14,940 --> 00:21:20,360 +هنا في hydrogen تنتين تلاتة اربعة خمسة ستة C6H6 + +244 +00:21:21,030 --> 00:21:25,570 +واخد اسم و لذلك بنلاحظ ان بعض هذه المراكبات على + +245 +00:21:25,570 --> 00:21:29,570 +سبيل المثال هذا المراكب كان اسمه Dewar Benzin هذا + +246 +00:21:29,570 --> 00:21:33,210 +المراكب اسمه Huckel Benzin و هدول علماء كيميا كبار + +247 +00:21:33,210 --> 00:21:39,250 +هذا Ladenburg Benzin يمكن الكلام هنا بالالماني + +248 +00:21:39,250 --> 00:21:46,010 +Klaus Benzinعلماء كبار حطوا أشكال و درست لفترة و + +249 +00:21:46,010 --> 00:21:49,950 +هذا الكلام بده يخلي عندكم دائما الشعور أن العلم + +250 +00:21:49,950 --> 00:21:54,930 +متطور و ممكن أشياء الإنسان يكون بيدرسها و بعدين + +251 +00:21:54,930 --> 00:21:58,710 +يكتشف أنها خطأ أكبر شغلة كل المختارات اللي احنا + +252 +00:21:58,710 --> 00:22:03,950 +بنعيشها أول ما بتطلع بنهلللها بشكل كبير و بعد هيك + +253 +00:22:03,950 --> 00:22:08,670 +بنلاحظ أن كل العالم يسعى لمنع هذه المختارات اللي + +254 +00:22:08,670 --> 00:22:13,100 +احنا هللنا لها كتيرومن أمثلتها على سبيل المثال + +255 +00:22:13,100 --> 00:22:17,420 +الفريون الغاز تبع التلاجات اللى كانوا يحطوه فى + +256 +00:22:17,420 --> 00:22:21,000 +علاب الريح عشان يعمل ال spraying ال answer نقول + +257 +00:22:21,000 --> 00:22:27,610 +هذه ال chlorofluorocarbons تدمر طبقة ال ozoneواضح؟ + +258 +00:22:27,610 --> 00:22:33,690 +من ضمنها مثلا المبيد الزراعي ال DDT هذا ممتاز + +259 +00:22:33,690 --> 00:22:38,130 +بيقتل الحشرات بيقتل ممتاز جدا لكن المشكلة بيأثر + +260 +00:22:38,130 --> 00:22:44,170 +على البشر ولذلك حتى بعد منعه المزارعين ما زالوا + +261 +00:22:44,170 --> 00:22:48,290 +بيحصلوه بالسوق السوداء و بيستعملوه لأنه بيجيبلهم + +262 +00:22:48,290 --> 00:22:53,540 +محصول لكن هو بنفس الوقت بيفكرش بإيشبفكرش في البشر + +263 +00:22:53,540 --> 00:22:57,900 +اللي بده يؤذيهم فهذه المنطقة في العلم انضال من + +264 +00:22:57,900 --> 00:23:04,380 +تبهين لها انه ممكن نكتشف أشياء نعتقد انها جيدة + +265 +00:23:04,380 --> 00:23:10,620 +وبعد هيك نتفاجأ انها عملت مشاكل بالفصل الخامس ان + +266 +00:23:10,620 --> 00:23:17,330 +شاء الله هنحكيلكم عن دوةنزل على السوق و بعد هيك + +267 +00:23:17,330 --> 00:23:22,410 +عمل مأساة كبيرة يمكن البعض منكوا لما نتكلم عنها و + +268 +00:23:22,410 --> 00:23:25,870 +نحط المأساة بالصور ايش عمل في البشر ممكن البعض + +269 +00:23:25,870 --> 00:23:35,030 +يبكي مع العلم انه دوى و سوق و أخدون ناس ابحينه انا + +270 +00:23:35,030 --> 00:23:39,540 +مش كل اشي بيعملون دراسة قبل ما ينهاركل إشي .. كل + +271 +00:23:39,540 --> 00:23:44,720 +إشي بيعملوله دراسة لكن في النهاية بتيجي دراسة أدق + +272 +00:23:44,720 --> 00:23:49,460 +من دراسة، شيء إحنا مش منتبهينله، يعني مابندناش + +273 +00:23:49,460 --> 00:23:56,540 +ناخد كل شيء إن هو قطعي تماما، بيحاولوا، بيجتهدوا، + +274 +00:23:56,540 --> 00:24:03,730 +طبعا أصعب شيء إذا دخلتالتجارة والصناعة في البحث + +275 +00:24:03,730 --> 00:24:08,230 +العلمي أثرت على حيادية النتيجة العلمية يعني أن + +276 +00:24:08,230 --> 00:24:13,510 +الشركة تخفي معلومات بخصوص منتوجها عشان تبيعه كل + +277 +00:24:13,510 --> 00:24:18,670 +شيء وارد .. كل شيء وارد والأمثلة لا تعد ولا تحصر + +278 +00:24:18,670 --> 00:24:24,650 +يعني خدوا على سبيل المثال صبغات الشعراللي استعملت + +279 +00:24:24,650 --> 00:24:28,170 +كثير و بشكل أساسي صفغات مُركّبات بسمها الـ + +280 +00:24:28,170 --> 00:24:32,030 +Pyrosols الان كلها انتهت من السوق في آخر عشر أو + +281 +00:24:32,030 --> 00:24:36,230 +خمس عشر سنة استعملته على المدى البعيد بدأ يبين + +282 +00:24:36,230 --> 00:24:40,950 +آثار سلبية لها الان بيخترعوا شغلات جديدة أول ما + +283 +00:24:40,950 --> 00:24:43,690 +بيخترعوا شغلة جديدة بيجوا و بيقولوا عملنا لها + +284 +00:24:43,690 --> 00:24:50,260 +فحوصات و ثبت إنها آمنة و أفضل ربمابعد 15-20 سنة + +285 +00:24:50,260 --> 00:24:54,960 +يكتشفوا أضرار معينة إلها ويعود اللي سمع محاضرة عن + +286 +00:24:54,960 --> 00:24:59,680 +فضل هذه الأشياء مثلا صبغات التترازينس يسمع محاضرة + +287 +00:24:59,680 --> 00:25:04,740 +جديدة بعد 15-20 سنة عن أضرار هذه المادةفالإنسان في + +288 +00:25:04,740 --> 00:25:10,160 +هذه المنطقة بصراحة تبقى منطقة علم وليس منطقة تأكد + +289 +00:25:10,160 --> 00:25:16,700 +في التشخيص شخصه غلط وهذا أمر طبيعي وفي النهاية + +290 +00:25:16,700 --> 00:25:22,440 +بنقدر نقول بالتأكيد ومن خلال أشعة X من ال 1865 + +291 +00:25:22,440 --> 00:25:27,200 +لليوم ماحدش بيجادل إطلاقا بخصوص شكل البنزين بهذا + +292 +00:25:27,200 --> 00:25:32,270 +الشكليعني احنا بنقدر نقول بنسبة كبيرة بس احتراما + +293 +00:25:32,270 --> 00:25:37,490 +لمبدأ ان العلم متغير ممكن يقول بنسبة 100% بس ممكن + +294 +00:25:37,490 --> 00:25:44,050 +يقول بنسبة 99.9% ان البنزين بهذا الشكل واضح؟ ومن + +295 +00:25:44,050 --> 00:25:49,350 +ال 1865 لليوم لأ ما اجهز شكل جديد درس البنزين بهذا + +296 +00:25:49,350 --> 00:25:56,750 +الشكلهذا كيكولي الان حكينا عن ال resonance وهذا + +297 +00:25:56,750 --> 00:26:02,590 +بيعمل orbitals بحيث انه بتعمل فوق البنزين و تحت + +298 +00:26:02,590 --> 00:26:05,010 +البنزين سحابة إلكترونية + +299 +00:26:07,750 --> 00:26:11,830 +فكرة وجود سحابة إلكترونية يعني لما أنا أتخيل أن + +300 +00:26:11,830 --> 00:26:17,670 +هذا هو البنزين أن هذا هو البنزين و فوقه إلكترونات + +301 +00:26:17,670 --> 00:26:21,230 +و تحته إلكترونات جايين من ال بي أوربيتالز يعني + +302 +00:26:21,230 --> 00:26:25,450 +كتلة إلكترونات بناء على ذلك هذا الكلام هيفيدني في + +303 +00:26:25,450 --> 00:26:30,630 +التفاعلات شو اللي بيقدر يجرب من البنزين عشان + +304 +00:26:30,630 --> 00:26:36,830 +يتفاعل معه إيش لازم يكون موجب موجبElectrophile + +305 +00:26:36,830 --> 00:26:43,390 +يعني مش ممكن يقدر بالوضع الطبيعي الـ Eucleophile + +306 +00:26:43,390 --> 00:26:49,310 +يجرب على البنزين لأن طبيعة الدنيا أن السالب يتنافر + +307 +00:26:49,310 --> 00:26:53,610 +مع السالب انا هنا عندي إلكترونات .. أنا هنا عندي + +308 +00:26:53,610 --> 00:27:01,590 +إلكترونات أجيب عليها شيء سالبسالب على سالب بيصير و + +309 +00:27:01,590 --> 00:27:05,550 +لذلك من أكبر الأخطاء من أكبر الأخطاء اللي + +310 +00:27:05,550 --> 00:27:09,270 +بيرتكبوها الطلاب ان احنا مرات لما نيجي نقولهم و + +311 +00:27:09,270 --> 00:27:14,550 +الله كيف بتحضروا الفينول الان الطالب اللي مادرسش + +312 +00:27:14,550 --> 00:27:18,390 +روح الكيميا و مبادئ الكيميا بيقول يالا بتمشي هاد + +313 +00:27:18,390 --> 00:27:23,830 +معايا بيروح برسوملنا بنزين و بيقول في وجود ال OH + +314 +00:27:23,830 --> 00:27:33,430 +minus بتبدل H من هنابال OH صرفيلون هذه مشكلة ليش؟ + +315 +00:27:33,430 --> 00:27:39,570 +لأن هنا إلكترونات وهذه سالبة ممكن هذا الكلام عمره + +316 +00:27:39,570 --> 00:27:47,310 +يصير؟ مش ممكنولذلك التفاعل الأساسي لل aromatic + +317 +00:27:47,310 --> 00:27:52,230 +compounds هو ال electrophilic substitution زي ما + +318 +00:27:52,230 --> 00:27:56,430 +هيمر علينا انه اللي بده يهاجم بده يكون موجب لأنه + +319 +00:27:56,430 --> 00:28:01,450 +البنزين عبارة عن سحابة إلكترونية فوق وتحت الجزيرة + +320 +00:28:01,450 --> 00:28:03,350 +كذا بده يجي يهاجم سالب ع سالب + +321 +00:28:11,350 --> 00:28:15,070 +الان قبل ما ناخد التفاعلات ناخد تسمية الـ aromatic + +322 +00:28:15,070 --> 00:28:21,050 +compounds بالنسبة للتسمية في عندنا مركبات أخدت + +323 +00:28:21,050 --> 00:28:24,710 +شهرة عبر الزمن هذه بتصير جزء من التسمية و لازم + +324 +00:28:24,710 --> 00:28:29,570 +نحفظها و في تسمية اشتقاقية الان في البداية + +325 +00:28:29,570 --> 00:28:34,530 +المركبات اللي أخدت شهرة و لازم نحفظها زي ما هي على + +326 +00:28:34,530 --> 00:28:40,810 +رأسهاالبنزين يعني احنا سابقا قلنا ان البنزين كان + +327 +00:28:40,810 --> 00:28:46,620 +ممكن نسميه Cyclohexatrieneلأن الـ Cyclohexane فيه + +328 +00:28:46,620 --> 00:28:51,380 +تلاتة إيل لكن هذا الكلام غير جائز ما بنسميه + +329 +00:28:51,380 --> 00:28:56,760 +Cyclohexatriene شو بنسميه؟ بنزين إذا أخد مجموعة + +330 +00:28:56,760 --> 00:29:04,120 +CH3 بصير طلوين إذا أخد مجموعة isopropyl اللي هو ال + +331 +00:29:04,120 --> 00:29:08,720 +isopropyl بنزين بصير كيومين حكينا عنه سابقا اللي + +332 +00:29:08,720 --> 00:29:16,090 +قلنا عنه في الكمونإذا أخد مجموعة الـ vinyl CH + +333 +00:29:16,090 --> 00:29:20,790 +double bond CH2 متذاكرينها ال vinyl؟ اه بنقول عنه + +334 +00:29:20,790 --> 00:29:27,210 +ال styrene لاحظوا معاه ان هذه المجموعات لها أسماء + +335 +00:29:27,210 --> 00:29:32,570 +درسناها لكن ما بنسميه هنا تسمية اشتقاطية يعني + +336 +00:29:32,570 --> 00:29:37,800 +مابنفعش ديجي نقول هذا مثل بنزين لأطولوين هذا + +337 +00:29:37,800 --> 00:29:44,420 +ايزوبروب البنزين لأ اكيومين هذا فينيل بنزين لأ + +338 +00:29:44,420 --> 00:29:50,260 +استيرين هذا هيدروكسي بنزين لأ فينول هذا مثلا + +339 +00:29:50,260 --> 00:29:56,360 +مثوكسي بنزين او مثل مثوكسي مجموعة ال او مثل لوحدها + +340 +00:29:56,360 --> 00:30:02,640 +لها اسم شو بنسميها مثوكسي لكن ما بنسميه مثوكسي + +341 +00:30:02,640 --> 00:30:08,550 +بنزين شو بنسميه أنيزوللو كان في مجموعة ال الديهيد + +342 +00:30:08,550 --> 00:30:13,610 +بنسميه بنزالديهيد لو كان في مجموعة ال C double + +343 +00:30:13,610 --> 00:30:20,170 +bond OCH3 بنسميه أسيتوفينون لو كان في مجموعة + +344 +00:30:20,170 --> 00:30:26,610 +الحامض C double bond OOH بنسميه بنزويك أسيد لو في + +345 +00:30:26,610 --> 00:30:32,170 +ال NH2 أنيلين بنقولوش أمينو بنزين، شو بنقوله؟ + +346 +00:30:32,170 --> 00:30:38,070 +أنيلينالان هذه الأسماء مع الخبرة بالتأكيد لازم + +347 +00:30:38,070 --> 00:30:41,650 +تحفظوها يعني لو جيبنا لك ارسم تفاعل ال benz + +348 +00:30:41,650 --> 00:30:44,490 +aldehyde او اكتب تفاعل ال benz aldehyde مع كذا + +349 +00:30:44,490 --> 00:30:47,510 +ماحدش يجي يقول مش حافظ ال benz aldehyde لأ كل شيء + +350 +00:30:47,510 --> 00:30:52,050 +موجود هنا صار جزء من التسمي اللي لازم طالب بتعلم + +351 +00:30:52,050 --> 00:30:57,670 +في الجامعة يعرفهامعد ذلك .. معد ذلك بنصير نسمي + +352 +00:30:57,670 --> 00:31:01,730 +تسمية اشتقاقية في التسمية الاشتقاقية بنجيب + +353 +00:31:01,730 --> 00:31:06,890 +المجموعة اللي موجودة بننهيها غالبا بال O و بنكتب + +354 +00:31:06,890 --> 00:31:12,770 +بنزين يعني هنا بروم بصير بروم و بنزين هنا نيترو .. + +355 +00:31:12,770 --> 00:31:19,680 +نيترو بنزين هنا اثلإيه في البنزين بروبل بروبل + +356 +00:31:19,680 --> 00:31:23,960 +بنزين هذه تسمية اشتقاقية في التسمية الاشتقاقية ايش + +357 +00:31:23,960 --> 00:31:30,070 +اللي بيكون موجود عندك أصل البنزينطبعا هنا بدكوا + +358 +00:31:30,070 --> 00:31:34,730 +تنتبهوا لنقطة كتير مهمة ان تكون المجموعة اللى + +359 +00:31:34,730 --> 00:31:39,130 +موجودة عند إلها اسم و إلا بتغلب يعني لما طلعت هنا + +360 +00:31:39,130 --> 00:31:43,890 +كلنا عارفين إنه هذا إثل ولا لأ فكان سهل علي أقول + +361 +00:31:43,890 --> 00:31:48,090 +إثل بنزيل كلنا عارفين إنه هذا بروبل ولا لأ سهل إن + +362 +00:31:48,090 --> 00:31:52,550 +أقول بروبل بنزيل أحيانا بتواجهكوا مشكلة كيف بدكم + +363 +00:31:52,550 --> 00:31:58,390 +تحلوها يعني مثلا لو أنا رسمت هذا المركب و حطيت هنا + +364 +00:32:00,820 --> 00:32:08,100 +حلقة بنزين وحطيت هنا CL الأن انتبهوا معي لو واحدة + +365 +00:32:08,100 --> 00:32:13,740 +بدت تقول هذه المجموعة بنزين المشكلة هي لم تدرس اسم + +366 +00:32:13,740 --> 00:32:19,380 +لهذه المجموعة وفعلا مالهاش اسم وجيتها بحول بعرفنه + +367 +00:32:19,380 --> 00:32:24,720 +كالكانبعمله كالكين بقول طب خليني لما عامله كالكين + +368 +00:32:24,720 --> 00:32:30,640 +هاي سلسلة كربون واحد اتنين تلاتة اربعة خمسة هاي + +369 +00:32:30,640 --> 00:32:35,880 +اطول سلسلة كربون حسب ما احنا اتعلمنا اذا هذا + +370 +00:32:35,880 --> 00:32:45,140 +بينتين وعلى اقل ترقيم واحد اتنين تلاتة اربعة خمسة + +371 +00:32:45,140 --> 00:32:50,970 +صار three cloroوهذه المجموعة البنزين نفسها فنل + +372 +00:32:50,970 --> 00:32:59,270 +اتنين فنل بنتين بيمشي الحال حلنا المشكلة تبعتنا + +373 +00:33:00,360 --> 00:33:05,220 +يعني مش ملزمين كل ما نشوف حلقة بنزين إننا لازم + +374 +00:33:05,220 --> 00:33:10,460 +ننهي الإسم تبعنا بنزين لأ إذا المجموعة إلها إسم + +375 +00:33:10,460 --> 00:33:15,300 +بسيط okay بنسمي بنزين إذا مالهاش هي نفس حلقة + +376 +00:33:15,300 --> 00:33:22,100 +البنزين كمجموعة اسمها إيش؟ فنل و بنعمل المركب على + +377 +00:33:22,100 --> 00:33:26,300 +إنه الكن و بيك منكون حلنا مشكلتنا + +378 +00:33:28,600 --> 00:33:35,240 +فنل بالظبط المجموعة اللى هو C6H6 لما بفقد H بصير + +379 +00:33:35,240 --> 00:33:42,480 +C6H5 اسمه فنل واضح؟ وعشان ايه سابقا بتذكر وقلتلكوا + +380 +00:33:42,480 --> 00:33:48,400 +ميزوا كلمة فنل عن فنل لإن الفنل شيء الفنل هي هذه + +381 +00:33:48,400 --> 00:33:53,090 +المجموعةلكن هذا ماسميناهوش فينيل لإنه ماخد اسم + +382 +00:33:53,090 --> 00:33:56,350 +شهرة الستايرين و أخدناله كمان البوليمار اللي + +383 +00:33:56,350 --> 00:34:00,110 +بيعمله شو سمينا البوليمار تبعه بوليستايرين + +384 +00:34:00,110 --> 00:34:03,270 +البوليمار سميناه بوليستايرين + +385 +00:34:10,410 --> 00:34:16,170 +الان لحتى الان اللي احنا سمنا مركبات بنزين فيها + +386 +00:34:16,170 --> 00:34:20,470 +one substituent يعني بس ابدلت فيها هيدروجينة واحدة + +387 +00:34:20,470 --> 00:34:28,310 +الان طيب يا ترى لو صار عندى ابدال اكثر من مجموعةلو + +388 +00:34:28,310 --> 00:34:33,210 +صار عندى إبدال أكثر من مجموعة هنا الحقيقة بيصير + +389 +00:34:33,210 --> 00:34:37,730 +عندنا نقطتين بدنا ننتبه لهم لما بيصير عندى إبدال + +390 +00:34:37,730 --> 00:34:44,230 +أكثر من مجموعة خليني أرسم مركب بشكل يعني هيك شوية + +391 +00:34:44,230 --> 00:34:53,530 +عشوائي لو كتبت هنا CH3 مثلا و هنا Pro هاي صار عليه + +392 +00:34:53,530 --> 00:34:59,680 +مجموع تانيهل يا تورا .. هل يا تورا بدي اعتبر ان + +393 +00:34:59,680 --> 00:35:04,880 +المركب الاصلي اللي عندى هو هذا اللى كان اسمه طلوين + +394 +00:35:04,880 --> 00:35:09,220 +و اقول ع موقع واحد اتنين تلاتة بيحمل بروم اسميه + +395 +00:35:09,220 --> 00:35:14,540 +three bromotolwinأو اعتبر المركب الأساسي اللي عندي + +396 +00:35:14,540 --> 00:35:20,520 +هو هذا برومو بنزين وع موقع واحد اتنين تلاتة اقول + +397 +00:35:20,520 --> 00:35:26,900 +three مثل برومو بنزين بيصير لإيش بدي أنسب المركب + +398 +00:35:26,900 --> 00:35:31,680 +تبعي بمعنى انا بدي اعمل عائلة للمركبهل يا ترى + +399 +00:35:31,680 --> 00:35:35,300 +العائلة بدت تكون تابعة المثل وبالتالي اخر الاسم + +400 +00:35:35,300 --> 00:35:39,420 +اللى بده يبين عندى هيكون تلوين ولا بدت تتبع البروم + +401 +00:35:39,420 --> 00:35:43,200 +وبالتالي اخر الاسم اللى بده يبين عندى بده يكون + +402 +00:35:43,200 --> 00:35:50,900 +برومو بنزين او مثلا مثال زى هذا لو حطيت هنا c + +403 +00:35:50,900 --> 00:35:58,210 +double bond o hالان اذا واحدة اتطلعت بهذا الشكل + +404 +00:35:58,210 --> 00:36:02,470 +هتقول طلوين يحمل على نمرة أربعة هذه المجموعة طب + +405 +00:36:02,470 --> 00:36:07,710 +اذا واحدة اتطلعت بهذا الشكل هتقول بنزالديهيد يحمل + +406 +00:36:07,710 --> 00:36:11,970 +على نمرة أربعة هذه المجموعة الان نهاية المركب تبع + +407 +00:36:11,970 --> 00:36:19,910 +عائلته هل هي يا ترى طلوين ولا بنزالديهيدهذا احنا + +408 +00:36:19,910 --> 00:36:24,670 +بحاجة انه تصبروا علينا شوية بهدوء حتى نتعلموا الان + +409 +00:36:24,670 --> 00:36:29,010 +اذا اتعلمنا ايش العائلة الأساسية اللي موجودة عندنا + +410 +00:36:29,010 --> 00:36:33,390 +بعد هيك الأمور بتصير سهلة يعني افترضوا جدلا انه + +411 +00:36:33,390 --> 00:36:38,810 +قولنا العائلة الأساسية تتبع هذه المجموعة اذا + +412 +00:36:38,810 --> 00:36:43,510 +المركب ايش Benzaldehyde ده المركب الأصلي باجي بقول + +413 +00:36:43,510 --> 00:36:47,430 +اذا والله وجدت مجموعة على هذا الموقع ببدأ ترقيمي + +414 +00:36:47,430 --> 00:36:55,460 +من هنا1 2 3 4 إذا وجدت مجموعة هذا الموقع بقول two + +415 +00:36:55,460 --> 00:37:02,340 +whatever بنزل دي هايت إذا كانتها three بنزل دي + +416 +00:37:02,340 --> 00:37:07,500 +هايت إذا كانتها four بنزل دي هايت الآن بدل ال two + +417 +00:37:07,500 --> 00:37:14,840 +ممكن أكتب ortho يعني يا بكتب two يا بكتب ايش ortho + +418 +00:37:14,840 --> 00:37:21,580 +small o بدل التلاتةميتا بدل الأربعة بارا فالان + +419 +00:37:21,580 --> 00:37:25,660 +بهذا المنطق انتبهوا معي هذه من الأخطاء الشائعة جدا + +420 +00:37:25,660 --> 00:37:30,220 +عن طلاب الكيميا ان هم بتخيلوا قصة اورتو ميتا و + +421 +00:37:30,220 --> 00:37:35,560 +بارا ان انا عندى شكل زى ما احنا كاتبينه هنا ان هذا + +422 +00:37:35,560 --> 00:37:41,360 +المكان اورتو هذا المكان ميتا هذا المكان بارابارا + +423 +00:37:41,360 --> 00:37:48,560 +لأ ما تفكروش بهذا الشكل فكروا بمجموعة موجودة أصلا + +424 +00:37:48,560 --> 00:37:54,140 +اللي بيكون بالنسبة لها على موقع اتنين ايش بدو يكون + +425 +00:37:54,140 --> 00:37:59,840 +اورتو اللي على موقع تلاتة ميتا اللي على موقع أربعة + +426 +00:37:59,840 --> 00:38:06,720 +بارا يعني لو أنا رسمت مركب بهذا الشكل وحطيت هنا OH + +427 +00:38:06,720 --> 00:38:10,690 +وخليني أقول اعتبرها هي الأساساللي بدأ اسمه يعني + +428 +00:38:10,690 --> 00:38:19,210 +مركب ايش؟ فينول الان اتيت و حطيت هنا كلور وجدت ايش + +429 +00:38:19,210 --> 00:38:23,850 +بدأ اسم هذا المركب طبعا طالما الاساس هذا اذا هي + +430 +00:38:23,850 --> 00:38:31,410 +الواحد اما بدأ اقول two chlorofenol + +431 +00:38:31,410 --> 00:38:37,370 +او ممكن ال two استبدلها ب orthoأنا مش كتير بحب ال + +432 +00:38:37,370 --> 00:38:40,650 +Orth والميتا والبارا، يعني أنا بنصحكم أكتبوا + +433 +00:38:40,650 --> 00:38:46,270 +أرقام، أكتبوا أرقام منطلقين أنه نقطة البداية هي + +434 +00:38:46,270 --> 00:38:51,960 +العائلة اللي حتى الآن مااتفقناش كيف نعرفهالحد الآن + +435 +00:38:51,960 --> 00:38:56,000 +ماحكيناش كيف نعرف العائلة، لكن احنا بنكتب أرقام، + +436 +00:38:56,000 --> 00:38:59,700 +الآن بعد ما نسمي، إذا واحدة بتحب هذه الرموز، تروح + +437 +00:38:59,700 --> 00:39:03,000 +تشتب الإتنين، تحط مكانها Orth أو تشتب التلاتة، + +438 +00:39:03,000 --> 00:39:06,160 +مكانها ميتا أو تشتب الأربعة، مكانها بارا، يحرق، + +439 +00:39:06,160 --> 00:39:11,360 +ماعملتش، و من هنا لحد ما خلصت الكورس معنا، ولا مرة + +440 +00:39:11,360 --> 00:39:14,660 +كتبت بإيدها Orth و ميتا و بارا، كتبت اتنين و تلاتة + +441 +00:39:14,660 --> 00:39:21,460 +و أربعة، هي بتشتغل شغلصحيح و بالمناسبة قصة الارثو + +442 +00:39:21,460 --> 00:39:26,400 +والنيتا والبارا هي قصة بس بتنوجد لو عندي two + +443 +00:39:26,400 --> 00:39:30,420 +substituents بمعنى لو كان عندي هذا المركب و خليني + +444 +00:39:30,420 --> 00:39:34,760 +اقول ما زلت مصير ان العائلة تبعت ال OH و اجيت و + +445 +00:39:34,760 --> 00:39:44,680 +حطيت هنا CH3 و هنا PR و بدي اسميه الان قولة واحدة + +446 +00:39:44,680 --> 00:39:50,540 +ان انا بستعمل الأرقاممافي امكانية ان اقعد تلاتة + +447 +00:39:50,540 --> 00:39:56,300 +اربعة خمسة ستة واتفقت انه مركب ايش؟ Phenol الان + +448 +00:39:56,300 --> 00:40:01,560 +هنا فقط باستعمل نظام الأرقام بدي اقول five bromo + +449 +00:40:01,560 --> 00:40:06,600 +two cloro three مثل ال alphabetical ذكرتهم + +450 +00:40:06,600 --> 00:40:19,750 +ماتبهين؟ five bromo two cloro threeمثل فينول اذا + +451 +00:40:19,750 --> 00:40:24,810 +لو زادوا ال substituents اللى عندى عن تنتين اكيد + +452 +00:40:24,810 --> 00:40:29,350 +بستعمل الأرقام لو كانوا تنتين ربما نقول الأفضل + +453 +00:40:29,350 --> 00:40:33,550 +نستعمل الأرقام و نسيبنا من قصة ارثه ميته برة الان + +454 +00:40:33,550 --> 00:40:36,570 +اذا اي واحدة بدأ تيجي بدل رقم اتنين لما بيكون two + +455 +00:40:36,570 --> 00:40:40,730 +substituents تحط ارثه بدل تلاتة ميته و بدل اربعة + +456 +00:40:40,730 --> 00:40:46,920 +برة مافيش عندنا مشكلةمثلا هذا المركب + +457 +00:40:46,920 --> 00:40:52,060 +Orthodiachlorobenzene هذا ميتا دايمثلبنزين لكن + +458 +00:40:52,060 --> 00:40:58,080 +دايمثلبنزين بياخد اسم شهرة إكزايلينولذلك مرة سئلنا + +459 +00:40:58,080 --> 00:41:01,580 +الطلاب في الامتحان ارسمولنا بار اكزايلين احنا + +460 +00:41:01,580 --> 00:41:05,260 +بنقول اكزايلين اللي فيه مجمعتين مثل اذا كانوا جانب + +461 +00:41:05,260 --> 00:41:10,400 +بعض واحد اتنين اورث اكزايلين اذا واحد تلاتة مائة + +462 +00:41:10,400 --> 00:41:14,800 +اكزايلين طب لو يجي واحد اربعة بار اكزايلين واضح + +463 +00:41:14,800 --> 00:41:20,540 +الفكرة هذا المركب مثلاواضح انه في كلورو الديهايد + +464 +00:41:20,540 --> 00:41:25,700 +وانه اعتبر العائلة ال الديهايد ورقم من عندها فجال + +465 +00:41:25,700 --> 00:41:30,360 +المركب بنزل ديهايد وحطله بارا كلورو بنزل ديهايد او + +466 +00:41:30,360 --> 00:41:34,440 +four كلورو بنزل ديهايد لكن السؤال اللي حتى الآن ما + +467 +00:41:34,440 --> 00:41:42,400 +جوابناهوش ليش قلنا العائلة ال الديهايد مش لكلور او + +468 +00:41:42,400 --> 00:41:51,490 +ال OHالـ OH مش الكلور ولا الميثل ولا البروم هذا + +469 +00:41:51,490 --> 00:41:57,850 +السؤال مهم ان نشوفه الان ببساطة امرتبين ال + +470 +00:41:57,850 --> 00:42:01,530 +constituents بترتيب اللي موجود في اعلى بنعتبره + +471 +00:42:01,530 --> 00:42:09,890 +العائلة اول شئ ال halogens هدول اقل مجموعة اقل من + +472 +00:42:09,890 --> 00:42:15,330 +ال alkanesالان ابدأوا تلاحظوا لو وجدت .. و زي الـ + +473 +00:42:15,330 --> 00:42:19,750 +halogens الـ Nitro، الآن الـ O2 لو وجدت ال halogen + +474 +00:42:19,750 --> 00:42:25,450 +مع ال cane، يعني كلور مع مثل، من العائلة؟ المثل لو + +475 +00:42:25,450 --> 00:42:31,630 +وجدت Nitro مع مثل، من العائلة؟ المثل، واضح؟ أقل من + +476 +00:42:31,630 --> 00:42:40,100 +ال alkenes لو وجدت ال cane و ال caneمن العائلة ال + +477 +00:42:40,100 --> 00:42:45,100 +الكين الان لاحظوا هي العائلة ال الكين هذا إيه اسمه + +478 +00:42:45,100 --> 00:42:51,980 +استيرين حيصير واحد اتنين تلاتة ال three مثل + +479 +00:42:51,980 --> 00:42:57,640 +استيرين هذا إيه اسمه طلوين حيصير ال three نيترو + +480 +00:42:57,640 --> 00:43:05,060 +طلوين طبعا ال الكين أقل من ال amines أقل من ال OH + +481 +00:43:06,510 --> 00:43:10,790 +ولذلك لو وجدت مثلًا OH مع الـCl مين العائلة؟ OH + +482 +00:43:10,790 --> 00:43:15,910 +إذا مُركّبة فينول؟ فينول لاحظوا إحنا قلنا ال + +483 +00:43:15,910 --> 00:43:23,170 +الكينز أقل من إيش؟ النيترو اتطلعوا معاه هاي الكين + +484 +00:43:23,170 --> 00:43:28,810 +طلوين و تلاتة نيترو بعتبر إن الترقيم إنها واحد، + +485 +00:43:28,810 --> 00:43:32,870 +اتنين، تلاتة، أربعة، خمسة، ستة إذا صار عند اتنين، + +486 +00:43:32,870 --> 00:43:36,890 +أربعة، ستة، تري، نيترو، طلوينهذا مُركّب الـ TNT + +487 +00:43:36,890 --> 00:43:46,230 +المتفجر لو وجد كيتون أكتر من الـ OH والألديهيد + +488 +00:43:46,230 --> 00:43:51,650 +أعلى من الكيتون والأسد أعلى منهم كلهم وال إيستر + +489 +00:43:51,650 --> 00:43:56,710 +أعلى وأعلى ولذلك هنا لدي ألديهيد و OH من العائلة + +490 +00:43:58,000 --> 00:44:03,540 +الالديهايد اذا بنزالديهايد عند الديهايد وكيتون من + +491 +00:44:03,540 --> 00:44:10,980 +العائلة الديهايد عند الاسد وكيتون الاسد عند + +492 +00:44:10,980 --> 00:44:18,240 +الالكول ونيترو و أتش ونيترو و أتش + +493 +00:44:18,240 --> 00:44:23,930 +واضح؟لو كان عندى halogens بينهم وبين بعض مش مشكلة + +494 +00:44:23,930 --> 00:44:28,250 +بنكتبهم alphabetical يعني ال brom قبل ال chlorine + +495 +00:44:28,250 --> 00:44:32,250 +ال alkyn + +496 +00:44:32,250 --> 00:44:40,430 +زى ال alkene بيكون أعلى من ال alkene ال eastern + +497 +00:44:40,430 --> 00:44:49,760 +من المشتقات الحامض هندرسه السيدة بالمندق OORعائلة + +498 +00:44:49,760 --> 00:44:52,840 +بناخدها بعدين، الآن احنا بنحط الصورة الكلية، + +499 +00:44:52,840 --> 00:44:56,040 +بتهيألي ضمن هذه الصورة الكلية بيصير موضوع التسمية + +500 +00:44:56,040 --> 00:45:01,870 +أصبح واضح لكمالـ slide اللي بننهي عندها انه هذه + +501 +00:45:01,870 --> 00:45:05,650 +بتتدربوا طبعا انتوا على التسمية و لو روحتوا على + +502 +00:45:05,650 --> 00:45:09,910 +الأمثلة اللي معاكم في امتحانات سابقة هتلاحظوا + +503 +00:45:09,910 --> 00:45:12,730 +دائما جايبيني اللي كنت اسمها aromatic compounds + +504 +00:45:12,730 --> 00:45:17,210 +بتفتشوا مين أعلى في المجموعات و تنسبوا إليها زي + +505 +00:45:17,210 --> 00:45:20,810 +الأمثلة الكتيرة اللي عرضناها الآن آخر نقطة بنحكيها + +506 +00:45:20,810 --> 00:45:25,330 +انه هذه ال aromatic compounds في نهاية مش رموزهي + +507 +00:45:25,330 --> 00:45:29,930 +مركبات على أرض الواقع يستفيد الإنسان منها والدليل + +508 +00:45:29,930 --> 00:45:34,130 +على هيك هاي بعض ال aromatic compounds اللي في صميم + +509 +00:45:34,130 --> 00:45:38,310 +الحياة تبع الإنسان يعني هذا المركب aromatic ولا + +510 +00:45:38,310 --> 00:45:43,070 +لأ؟ هذا اسمه Aspirin ال Aspirin اللي أنتوا بتاخدوه + +511 +00:45:43,070 --> 00:45:47,010 +تمام؟ تلت ارباع الناس بعد حصة ال organic يا + +512 +00:45:47,010 --> 00:45:53,190 +Aspirin يا Trophin تعرفولي Trophin أربع .. هايو ال + +513 +00:45:53,190 --> 00:45:59,260 +Ibuprofenواذا روحوا ع البيت و بدهم ياكلوا بدهم كيك + +514 +00:45:59,260 --> 00:46:03,780 +و الكيك بده فانيلا و الفانيلا من الفانيليل من + +515 +00:46:03,780 --> 00:46:08,640 +الفانيليل هي الفانيلا واضح فإحنا مش بنحكي عن رموز + +516 +00:46:08,640 --> 00:46:12,500 +بقدر ما بنحكي حقيقة عن مركبات في واقع الاستعمال + +517 +00:46:12,500 --> 00:46:16,860 +الحياتي و الطب و لذلك بندرس ال organ ال chemistry + +518 +00:46:16,860 --> 00:46:21,340 +و ان شاء الله المرة القادمة بكون موضوعنا تفاعلات + +519 +00:46:21,340 --> 00:46:22,940 +ال aromatic compounds + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..9aee87ba94507bcee2819ad5f54f16926cba4c71 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_raw.srt @@ -0,0 +1,1892 @@ +1 +00:00:19,780 --> 00:00:23,920 +بسم الله الرحمن الرحيم المرة الماضية اتكلمنا على + +2 +00:00:23,920 --> 00:00:28,440 +أكسدة الكحولات عرفنا ايش اللي بنقصده في الأكسدة + +3 +00:00:28,440 --> 00:00:34,660 +تحويل ال OH إلى C double bond O من خلال فقط ذاتين + +4 +00:00:34,660 --> 00:00:40,740 +هيدروجين ولذلك احنا قلنا ان ال primary alcohol + +5 +00:00:40,740 --> 00:00:46,000 +بتأكسد و بصير ال aldehydes و ال secondary alcohol + +6 +00:00:46,000 --> 00:00:51,060 +بتأكسد و بصير ال ketonesالـ tertiary alcohols مش + +7 +00:00:51,060 --> 00:00:55,540 +عندهم إمكانية انهم يتأكسدوا ربما ضالت شغلة صغيرة + +8 +00:00:55,540 --> 00:00:59,580 +ان نحكي شو هو العامل المؤكسد اللي احنا بنستعمله + +9 +00:00:59,580 --> 00:01:06,160 +عادة لأكسدة ال primary alcohols بحيث تقف الأكسدة + +10 +00:01:06,160 --> 00:01:12,340 +عند ال aldehyde بنستعمل reagent بنعطيه رمز BCC + +11 +00:01:12,340 --> 00:01:17,380 +بريدينيام كلورو كروميت البريدينيام كلورو كروميت + +12 +00:01:18,050 --> 00:01:22,050 +بيحذف هيدروجينتين بيحوّل ال primary alcohol إلى + +13 +00:01:22,050 --> 00:01:27,230 +الديهيد يعني لاحظوا هاي إيثانون primary alcohol + +14 +00:01:27,230 --> 00:01:30,950 +هيفقد الهيدروجينتين هنا بدها دي تصير double bond + +15 +00:01:30,950 --> 00:01:34,670 +صار الديهيد إذا لو قلنا شو العامل المؤكسد اللي + +16 +00:01:34,670 --> 00:01:40,180 +استعملناه هناBCC باكسد ال primary alcohol ال + +17 +00:01:40,180 --> 00:01:46,340 +الديهايد الان ربما احنا نوحنا المرة الماضية ان ال + +18 +00:01:46,340 --> 00:01:51,420 +الديهايد ممكن يصير عليه اكسدة إضافية بإضافة + +19 +00:01:51,690 --> 00:01:55,830 +أكسوجينة بدل الهيدروجين يعني عملية إبدال يعني هذا + +20 +00:01:55,830 --> 00:02:00,330 +ال الديهايد بعد ما يتكون لو استعملتله عامل مؤكسد + +21 +00:02:00,330 --> 00:02:07,170 +أقوى ممكن أن أحوله أخليه بدل ما هو CH3COOH يعني + +22 +00:02:07,170 --> 00:02:11,070 +متصل مرتين بالأكسوجين أبدل ال H و أخليه H يعني + +23 +00:02:11,070 --> 00:02:17,090 +أخليه إيش يصير Carboxylic Acid يصفةسي أتش ثري سي + +24 +00:02:17,090 --> 00:02:21,750 +دبل بوند او الان عملية الأكسدة الإضافية تحويل هذه + +25 +00:02:21,750 --> 00:02:31,690 +ال H إلى OH واضح فال primary alcohol بالأكسدة + +26 +00:02:31,690 --> 00:02:35,030 +خلّينا نقول الضعيفة بيصير الديهايد و بيجف عند ال + +27 +00:02:35,030 --> 00:02:35,890 +الديهايد + +28 +00:02:39,060 --> 00:02:44,500 +اذا احنا كملنا بعد هيك في موضوع ال .. الاكسدة اذا + +29 +00:02:44,500 --> 00:02:49,040 +احنا كملنا بعد هيك في موضوع الاكسدة بحيث استعملنا + +30 +00:02:49,040 --> 00:02:52,500 +عامل مؤكسد اقوى و عادة العامل المؤكسد الاقوى هو + +31 +00:02:52,500 --> 00:02:57,260 +احد العوامل المؤكسدة اللي موجودة عندكم هنا كمان او + +32 +00:02:57,260 --> 00:03:01,440 +فور بيرمانجانات البوتاسيوم + +33 +00:03:02,970 --> 00:03:10,210 +بوتاسيوم بيرمانجانيت كتو كروميام 2 O7 بوتاسيوم + +34 +00:03:10,210 --> 00:03:11,050 +بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم + +35 +00:03:11,050 --> 00:03:11,050 +بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم + +36 +00:03:11,050 --> 00:03:11,270 +بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم + +37 +00:03:11,270 --> 00:03:12,210 +بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم + +38 +00:03:12,210 --> 00:03:12,890 +بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم + +39 +00:03:12,890 --> 00:03:13,030 +بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم + +40 +00:03:13,030 --> 00:03:14,450 +بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم + +41 +00:03:14,450 --> 00:03:17,470 +بوتاسيوم + +42 +00:03:17,470 --> 00:03:24,750 +بوتاسيوم بوتاسيوم بوتاسيوم بفال أكسدة هنا على + +43 +00:03:24,750 --> 00:03:29,470 +مرحلة ولا على مرحلتين؟ على مرحلتين بيجي السؤال طب + +44 +00:03:29,470 --> 00:03:35,070 +يا تورا لو استعملنا العامل المؤكسد القوي هذا مع ال + +45 +00:03:35,070 --> 00:03:42,210 +alcohol مع ال primary alcohol إيش هيعمل؟هيعمل + +46 +00:03:42,210 --> 00:03:47,030 +عمليتين الأكسدة هيمر بال الديهايد وبسرعة يظل مستمر + +47 +00:03:47,030 --> 00:03:50,730 +لإيش؟ للكربوكسيلك أسد يعني لو استعملت هذا العامل + +48 +00:03:50,730 --> 00:03:55,030 +المؤكسد من خلاله اعملت الأكسدة هاحصل على + +49 +00:03:55,030 --> 00:03:59,990 +الكربوكسيلك أسد واضح؟ فهيصير عندكم أن ال primary + +50 +00:03:59,990 --> 00:04:05,390 +alcohol بعامل مؤكسد قوي واحد من هدول التلاتة + +51 +00:04:05,390 --> 00:04:12,000 +نتيجته نهائيةCarboxylic Acid فهمان بمخنا بنقول مر + +52 +00:04:12,000 --> 00:04:16,860 +بمرحلة ال الديهايد واتحول بسرعة لاش ل Acid فإذا + +53 +00:04:16,860 --> 00:04:20,680 +استعمل عامل قوي النتيجة نهائية ال Acid إذا استعمل + +54 +00:04:20,680 --> 00:04:25,620 +عامل ضعيف النتيجة نهائية ال الديهايد لو حد بعد هيك + +55 +00:04:25,620 --> 00:04:30,380 +بده يحول ال الديهايد ل Acid يرود يستعمل مرة تانية + +56 +00:04:30,380 --> 00:04:35,770 +العامل المؤكسد القويلاحظوا هذه الأكسدة .. هذه + +57 +00:04:35,770 --> 00:04:41,150 +الأكسدة أكسدة كثير مهمة و كثير شهيرة يعني ماضلش + +58 +00:04:41,150 --> 00:04:45,970 +بعدها انتبهوا معي ال carbon في ال primary alcohol + +59 +00:04:45,970 --> 00:04:49,990 +بكم رابطة متصلة مع ال oxygen؟ واحدة .. واحدة .. + +60 +00:04:49,990 --> 00:04:51,690 +واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. واحدة + +61 +00:04:51,690 --> 00:04:51,690 +.. واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. + +62 +00:04:51,690 --> 00:04:51,850 +واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. واحدة + +63 +00:04:51,850 --> 00:04:51,850 +.. واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. + +64 +00:04:51,850 --> 00:04:51,910 +واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. واحدة + +65 +00:04:51,910 --> 00:04:52,170 +.. واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. + +66 +00:04:52,170 --> 00:05:00,650 +واحدة .. واحدة .. واحدة .. واحدة .. واحد + +67 +00:05:02,850 --> 00:05:07,930 +الاربعة بيبطل في إمكانية للاربعة من ناحية المبدأ + +68 +00:05:07,930 --> 00:05:13,610 +فيه أعلى مراتب الأكسدة أنه يصير CO2 تاني أكسيد + +69 +00:05:13,610 --> 00:05:17,650 +الكربون تطلعوا + +70 +00:05:17,650 --> 00:05:20,770 +هنا من ضمن الاتحاد مع الأكسجين بنصير فاهمين + +71 +00:05:20,770 --> 00:05:25,370 +الأكسدة بالمفهوم البسيط القديم اتحاد مرة مع + +72 +00:05:25,370 --> 00:05:31,970 +الأكسجين مرتينتلاتة الأربع روابط صاروا متحدين مع + +73 +00:05:31,970 --> 00:05:37,150 +الأكسجين فأعلى مرحلة في الأكسجين ده أنه يصل لثاني + +74 +00:05:37,150 --> 00:05:38,290 +أكسيد الكربون + +75 +00:05:43,190 --> 00:05:48,650 +هذه الأكسادات حقيقة بتتم في التطبيق العملي و بتتم + +76 +00:05:48,650 --> 00:05:53,530 +كمان في جسم الإنسان يعني في التطبيق العملي لما + +77 +00:05:53,530 --> 00:05:58,970 +بيصنعوا الخمر هم بيجيبوا السكريات بيخمروها بتصير + +78 +00:05:58,970 --> 00:06:04,830 +إيثانول يعني لما بنفكر إنه عندنا sugar السكر + +79 +00:06:04,830 --> 00:06:11,730 +بالتخمير شو بيصير إيثانوللذلك بيخمروا العناب + +80 +00:06:11,730 --> 00:06:18,630 +الليزبي بالطمر يصير إيثانول يصير الخمرة طيب و كذلك + +81 +00:06:18,630 --> 00:06:23,290 +الفواكه الانجاس والتفاح وما إلى ذلك طب لو خمروه + +82 +00:06:23,290 --> 00:06:27,650 +لفترة أطول بظروف معينة يعرفها الناس اللي بيشتغلوا + +83 +00:06:27,650 --> 00:06:34,950 +بهذه الأمور هيتحول لإيش؟ لخل و لذلك الخل هو مرحلة + +84 +00:06:34,950 --> 00:06:37,690 +بعد الخمر + +85 +00:06:39,360 --> 00:06:42,740 +يعني لما بتم عملية التخمر أول اشي بيصير عند ال + +86 +00:06:42,740 --> 00:06:46,780 +ethanol الخمر وبعد هيك ال ethanol نفسه بتحول لخل + +87 +00:06:46,780 --> 00:06:55,480 +لاحظوا معنى ان الخمر محرم وناجس و الخل محرمحلال + +88 +00:06:55,480 --> 00:07:01,340 +وطاهر وفي الحديث افضل ادامكم الخل .. من افضل الأكل + +89 +00:07:01,340 --> 00:07:05,140 +اللي ممكن الانسان ياكله يستفيد منه حتى من ناحية + +90 +00:07:05,140 --> 00:07:08,800 +بيو كيميسترا يستعمل في تصنيع الجزيئات الأكبر منه + +91 +00:07:08,800 --> 00:07:15,790 +الخلالان طب الخمر هذا النجس لما بتحول لخل ايش + +92 +00:07:15,790 --> 00:07:21,210 +بيصير فيه؟ يطهر الفقاء ايش بيقولوا عنه؟ يطهر + +93 +00:07:21,210 --> 00:07:26,830 +بالتحول يعني إذا تحول النجس من حالته الكيميائية + +94 +00:07:26,830 --> 00:07:31,550 +إلى حالة أخرى فإنهم يصبحوا طاهرا ولذلك هذا الخمر + +95 +00:07:31,550 --> 00:07:41,490 +حرام هذا الخل حلالواضح؟ إذا تحول النجس إلى طاهر + +96 +00:07:41,490 --> 00:07:45,670 +فإنه يطهر، إذا تحول إلى مادة تانية، بيسموها إيش + +97 +00:07:45,670 --> 00:07:51,610 +هذه الشغلة؟ التطهير بالتحول، لأنه تحول من المادة + +98 +00:07:51,610 --> 00:07:55,870 +النجسة إلى مادة جديدة، فالمادة الجديدة هذه طالما + +99 +00:07:55,870 --> 00:07:59,270 +اختلفت في خواصة عن المادة الأولى فهي مادة إشمالها + +100 +00:07:59,270 --> 00:08:03,940 +طاهرةالان طيب الناس اللي بيشربوا الخمر إيش بيصير + +101 +00:08:03,940 --> 00:08:08,500 +بجسمهم؟ ما هو الخمر بيأثر على العقل بيشرب البني + +102 +00:08:08,500 --> 00:08:12,060 +آدم الخمر و بيروح عقله و كل الأشياء الأعراض السكر + +103 +00:08:12,060 --> 00:08:15,600 +اللي أنتوا بتعرفوها بعد سبع تمان ساعات تسعة ساعات + +104 +00:08:15,600 --> 00:08:19,980 +بيرجع إنسان طبيعي ولا لأ طب كيف الجسم اتخلص من + +105 +00:08:19,980 --> 00:08:23,360 +الخمر إذا؟ ما هو الجسم أخد إيثانول هو اللي عمل + +106 +00:08:23,360 --> 00:08:27,360 +عنده كل المشاكل كل هذه العمليات بتصير جوا الجسم + +107 +00:08:28,560 --> 00:08:33,780 +بالانزيمات المرة هذه إيثانول بيصير الديهايد بيصير + +108 +00:08:33,780 --> 00:08:40,070 +acid بيصير ثانو أكسيد الكربون بيطلع مع الزفيريعني + +109 +00:08:40,070 --> 00:08:44,390 +في النهاية الخمر كيف البني آدم بده يطلعه على شكل + +110 +00:08:44,390 --> 00:08:48,370 +carbon dioxide كل هذه العمليات عمليات الأكسدة + +111 +00:08:48,370 --> 00:08:52,890 +حقيقة بالتم في الجسم و زي ما انتوا شايفين بالتم + +112 +00:08:52,890 --> 00:08:57,990 +أيضا في الحياة العملية و في الصناعة صناعة الخل هي + +113 +00:08:57,990 --> 00:09:02,170 +عبارة عن أكسدة في النهاية هي عبارة عن أكسدة + +114 +00:09:06,160 --> 00:09:11,080 +هذا الكلام اللى موجود عندنا هنا الان لو كنا بنعمل + +115 +00:09:11,080 --> 00:09:14,900 +ال اكسدة ل secondary alcohol شو اتفقنا عليه بيصير + +116 +00:09:14,900 --> 00:09:19,320 +كيتون الان العامل المؤكسد احد العوامل المؤكسدة + +117 +00:09:19,320 --> 00:09:24,320 +القوية يعني كيعمل او 4 كي 2 كروميوم 2 او 7 كروميوم + +118 +00:09:24,320 --> 00:09:28,920 +او 3 عادة ب sulfuric acid يعني عشان احول ال + +119 +00:09:28,920 --> 00:09:34,520 +secondary alcohol الى كيتون بدي استعمل احد العوامل + +120 +00:09:34,520 --> 00:09:40,170 +المؤكسدةالقوية التيرتشاري الالكول زي ما اتفقنا مش + +121 +00:09:40,170 --> 00:09:45,890 +فيه هيدروجين تفقد ولذلك لا يتأكد بهذا تقريبا بنكون + +122 +00:09:45,890 --> 00:09:51,840 +أنهينا موضوعأكسدت الكحولات و دائما بنصحكم ما + +123 +00:09:51,840 --> 00:09:55,820 +تحفظوش كأشكال كيميائية لإحفظوه كأفكار ان ال + +124 +00:09:55,820 --> 00:09:58,460 +primary alcohol بيصير الديهايد و ممكن ال middle + +125 +00:09:58,460 --> 00:10:02,120 +acid حسب قوة العامل مؤكسد ال secondary alcohol + +126 +00:10:02,120 --> 00:10:06,140 +بيصير ال ketone و ال tertiary alcohol لايتأكسدش + +127 +00:10:06,140 --> 00:10:13,460 +الديهايد بتكون من أول .. احنا من أين يعني جيناها؟ + +128 +00:10:13,460 --> 00:10:17,120 +هي من نفس التفاعل؟اي O ما هي ال alcohol اللي أنا + +129 +00:10:17,120 --> 00:10:21,780 +بادي فيه لأ ال O هذه معناها oxidizing agent + +130 +00:10:21,780 --> 00:10:26,920 +احفظوها هذا الرمز ال O اللي مكتوبة بجثين مربعين + +131 +00:10:26,920 --> 00:10:31,340 +معناها oxidizing agent بس هو ماحددوش يعني لما + +132 +00:10:31,340 --> 00:10:38,420 +تقرؤوا على سهم محطوطة ال O زي هيك معناها بالاكسدة + +133 +00:10:39,160 --> 00:10:43,060 +هو مش بواجهة انه يذكر العامل المؤكسد بس وين + +134 +00:10:43,060 --> 00:10:47,880 +بتقراوها هذا رمز يعني تفاعل أكسدة باستعمال عامل + +135 +00:10:47,880 --> 00:10:50,960 +مؤكسد الآن العوامل المؤكسدة شرحنالكوا إياها اللي + +136 +00:10:50,960 --> 00:10:56,480 +في المختبر وقولنالكوا في الجسم في انزيمات عادة + +137 +00:10:56,480 --> 00:11:03,200 +Oxidase بتسمى و بتقوم بهذه العملية واضح فهذه ال O + +138 +00:11:03,200 --> 00:11:09,350 +اللي مكتوبة بالجسم ربع منها عامل مؤكسدالان ال + +139 +00:11:09,350 --> 00:11:15,030 +polyhydroxy compounds هي مركبات تحتوي على اكثر من + +140 +00:11:15,030 --> 00:11:19,530 +مجموعة OH و طبعا طالما انه بتحتوي على اكثر من + +141 +00:11:19,530 --> 00:11:23,270 +مجموعة OH شو بنتوقع احنا في ال boiling point لهذه + +142 +00:11:23,270 --> 00:11:28,150 +المركبات؟ بده تزيد يعني لو عملنا مقارنة مع المركب + +143 +00:11:28,150 --> 00:11:31,670 +اللي فيه كربنتين و مجمعتين OH اللي هو ال ethanol + +144 +00:11:31,670 --> 00:11:39,330 +CH3 CH2 OH جديش كانت ال boiling point تبعته؟78 لو + +145 +00:11:39,330 --> 00:11:45,410 +صاروا مجمعتين OH بتصير يداش 198 لو صاروا تلاتة OH + +146 +00:11:45,410 --> 00:11:52,530 +متين وتسعين لو صاروا ستة OH بتحول لصلب بيصير مادة + +147 +00:11:52,530 --> 00:11:57,450 +صلبة الها melting point 110 ل 112 واضح؟ وكل هذه + +148 +00:11:57,450 --> 00:12:02,210 +المركبات اللي بالذات اللي فيها OH اللي أمامكم عادة + +149 +00:12:02,210 --> 00:12:08,120 +بتكون water soluble بتدوب في الميه إيش السبب؟لأنها + +150 +00:12:08,120 --> 00:12:12,400 +polar و like dissolves like الآن المركب اللي فيه + +151 +00:12:12,400 --> 00:12:16,540 +مجموعتين OH بنسميه احنا إيثالين جليكول لو بدنا + +152 +00:12:16,540 --> 00:12:21,480 +يابل ايو باك بزامتين تين OH بدل all دايول حيصير + +153 +00:12:21,480 --> 00:12:25,080 +one two اثان دايول اللي فيه تلاتة OH هو ال + +154 +00:12:25,080 --> 00:12:30,060 +glycerinاللي بنعمل فيه الإيدين أو ال glycerol one + +155 +00:12:30,060 --> 00:12:36,000 +two three بروبان ال triol اللي فيه ستة O H's ال + +156 +00:12:36,000 --> 00:12:40,580 +sorbitol المطهر اللي عادة بيستعمله لتطهير الإيدين + +157 +00:12:40,580 --> 00:12:43,860 +و الأرضيات اللي هو one two three four five six + +158 +00:12:43,860 --> 00:12:53,560 +hexane hexaol ربما بيفيد هنا نقطةتظلوا دائما + +159 +00:12:53,560 --> 00:12:59,400 +متذكرينها لأنه ممكن تسألوا عنها ان المركبات عديدة + +160 +00:12:59,400 --> 00:13:04,960 +ال O H ليست السكريات طيب السكريات ايش بتكون + +161 +00:13:04,960 --> 00:13:09,060 +السكريات او sugars و هنعود ناخد هذا الكلام في ال + +162 +00:13:09,060 --> 00:13:14,540 +biochemistry هي مركبات عديدة ال O H لكن بينوجد + +163 +00:13:14,540 --> 00:13:18,940 +فيها مجموعة واحدة بالاضافة لل O H الديهيد او كيتون + +164 +00:13:19,910 --> 00:13:25,290 +فعشان المُركّب يكون سُكر ضمن تصنيف الكيميائي من + +165 +00:13:25,290 --> 00:13:29,250 +السُكريات بدوا يكون فيه مجموعات أوقاتش كتير بس + +166 +00:13:29,250 --> 00:13:34,790 +بدوا يكون فيه واحدة الديهايد او كيتون يعني مثلا لو + +167 +00:13:34,790 --> 00:13:40,680 +هذه كانت كيتونهذا بلغة الكيميا بيصير إيش؟ sugar لو + +168 +00:13:40,680 --> 00:13:44,940 +هذه نفترض كانت الديهيد هذا بلغة الكيميا بيصير + +169 +00:13:44,940 --> 00:13:51,980 +sugar فال sugars تعريفها بوليهيدروكسي صح بس مش + +170 +00:13:51,980 --> 00:13:57,520 +بوليهيدروكسي compounds لأ بوليهيدروكسي الديهيد أو + +171 +00:13:57,520 --> 00:14:04,270 +كيتون واضح؟شوفنا إيش بيفرغوا السكريات عن ال + +172 +00:14:04,270 --> 00:14:07,810 +polyhydroxy compounds ال polyhydroxy compounds بس + +173 +00:14:07,810 --> 00:14:13,690 +مجموعات OH لو مع مجموعات ال OH إيجي عندى aldehyde + +174 +00:14:13,690 --> 00:14:18,050 +أو كيتون وقتها بيصيروا المراكبات إيش sugars ال + +175 +00:14:18,050 --> 00:14:22,410 +polyhydroxy aldehydes هنتعلم إنه اسمهم ال doses و + +176 +00:14:22,410 --> 00:14:26,690 +ال polyhydroxy ketones هنتعلم إنه اسمهم ketoses + +177 +00:14:26,690 --> 00:14:32,120 +واضح؟فنضل متذكرين هذه المعلومة ان السكر الديهيد او + +178 +00:14:32,120 --> 00:14:39,220 +كيتون مع مجموعات O H اكتار واضح الديهيد او كيتون + +179 +00:14:39,220 --> 00:14:44,480 +لحاله مش Sugar مجموعات O H لحالهابرضه مش sugar + +180 +00:14:44,480 --> 00:14:50,940 +واضح ال sugar ال dehydrate او كيتون ومعه مجموعات + +181 +00:14:50,940 --> 00:14:57,400 +OH اكتر طبعا في مركبات تانية ربما اخليكوا تعرفوا + +182 +00:14:57,400 --> 00:15:01,460 +واحد منها بس aromatic compounds عليهم اكتر من ال + +183 +00:15:01,460 --> 00:15:04,480 +OH و بيمروا مرات معاكم في ال biology او ال + +184 +00:15:04,480 --> 00:15:08,560 +biochemistry مثلا المركب اللي فيه تنتين OH على ال + +185 +00:15:08,560 --> 00:15:13,560 +ortho position اسمه catecholاكتير هتظل تقرأ + +186 +00:15:13,560 --> 00:15:17,580 +كاتيكول و ما إلى ذلك و هذا المركب resource .. + +187 +00:15:17,580 --> 00:15:23,800 +resource in all هذا hydroquinone هذا بيرو .. بيرو + +188 +00:15:23,800 --> 00:15:29,510 +غالول الآن خلّينا اليوميعني إذا بدنا بالتأكيد + +189 +00:15:29,510 --> 00:15:32,210 +تكونوا حافظين مركّب تعرفوا الـ hydroquinone + +190 +00:15:32,210 --> 00:15:37,850 +الهيدروكوينون المركّب اللي فيه بارا دايهيدروكسي + +191 +00:15:37,850 --> 00:15:41,390 +بنزين واضح؟ هذا إيش اسمه؟ + +192 +00:15:43,500 --> 00:15:49,240 +الان الـ Hydroquinone عادة بيعمل أكسدة و زي ما + +193 +00:15:49,240 --> 00:15:54,300 +قلنا احنا محصلة الأكسدة فقد ذرتين الهيدروجين و + +194 +00:15:54,300 --> 00:15:57,820 +تكوين رابطة لو انا اطلعت على هذا الجزء الـ + +195 +00:15:57,820 --> 00:16:03,300 +Hydroquinone هاي رابطة تنتين تلاتة طب لو فقدت هذه + +196 +00:16:03,300 --> 00:16:08,540 +الـ H و هذه الـ Hهعمل كمان رابط اي كداش حيصير + +197 +00:16:08,540 --> 00:16:12,840 +مجموع الروابط الزوجية اربعة حيصير بهذا الشكل شكل + +198 +00:16:12,840 --> 00:16:17,240 +المركب الان هذا بنسمي احنا Benzoquinone او 1,4 + +199 +00:16:17,240 --> 00:16:21,600 +-benzoquinone لاحظوا ان هذه العملية تمت في وجود + +200 +00:16:21,600 --> 00:16:28,870 +عاملمؤكسد فالفينول تتأكسد + +201 +00:16:28,870 --> 00:16:34,710 +و تصبح تحديدا منها الهيدروكوينون بيصبح بالزوكوينون + +202 +00:16:34,710 --> 00:16:39,270 +و كل الفينول بشكل عام عادة ما بتتم عليها تأكسد + +203 +00:16:39,270 --> 00:16:43,810 +بطريقة او باخره هذا الكلام بيحولنا لتطبيق كتير مهم + +204 +00:16:43,810 --> 00:16:48,430 +ان فيه مركبات احنا في الدنيا بنسميها antioxidants + +205 +00:16:48,430 --> 00:16:51,790 +يعني مركبات + +206 +00:16:53,530 --> 00:17:00,090 +بديش اقول عنها انا مضادة ربما الترجمة مرات تحتاج + +207 +00:17:00,090 --> 00:17:06,950 +إلى نوع من الدقة تماما زي ما بنترجم احنا كلمة + +208 +00:17:06,950 --> 00:17:11,900 +مانعة الصواعقتمام؟ اكتر ربما مر عليكم انه باللغة + +209 +00:17:11,900 --> 00:17:17,280 +العربية بيستعمله مانعة الصواعق الحقيقة الصاعقة من + +210 +00:17:17,280 --> 00:17:21,020 +ربنا سبحانه وتعالى هذا العمود الحديد اللي احنا + +211 +00:17:21,020 --> 00:17:27,650 +بنحقه هيك هل يا ترى يمنع الصاعقة أن تحدث؟أه إذا هو + +212 +00:17:27,650 --> 00:17:32,290 +إيش بيعمل هو يمطس الصائقة و لا يمنع الصائقة و لذلك + +213 +00:17:32,290 --> 00:17:36,870 +الصائقة كهربا كبيرة جدا لو نزلت على المبنى بتحرج + +214 +00:17:36,870 --> 00:17:40,030 +أو بتحرك شبكات الكهربا اللي فيه لما يحطوا هذه + +215 +00:17:40,030 --> 00:17:44,130 +الحديدة كل الكهربا اللي نازلة من الصائقة بتدخل في + +216 +00:17:44,130 --> 00:17:48,390 +الحديدة موصولة بسلك في الأرض بتتفرج في الأرض بتتوه + +217 +00:17:48,390 --> 00:17:54,170 +بدل ما تنزل على الأجهزة و على المبنى فبهذا المفهوم + +218 +00:17:54,170 --> 00:17:59,390 +الصائقة صائقة لم تمنعلكن ايش اللي صار عنده؟ تم + +219 +00:17:59,390 --> 00:18:05,690 +انتصاص للصواقة ولذلك ربما يكون أدق انها تتسمى مش + +220 +00:18:05,690 --> 00:18:12,310 +مانعة الصواقر، ماصة الصواقر، واضح؟ كذلك الحال في + +221 +00:18:12,310 --> 00:18:16,110 +المركبات اللي اسمها antioxidants و اللي احنا عادة + +222 +00:18:16,110 --> 00:18:24,150 +بنضيفها على الأطعمةتسميتها بمضادات الأكسدة وكأنها + +223 +00:18:24,150 --> 00:18:30,510 +تمنع الأكسدة ليست تسمية أو ليست ترجمة دقيقة لهذا + +224 +00:18:30,510 --> 00:18:36,830 +المصطلح الأصل أن نقول عنها مركبات ماصة للأكسدة + +225 +00:18:36,830 --> 00:18:43,530 +بمعنى إذا احنا عملنا مثلا علبة معلباتأو مرتاديلة + +226 +00:18:43,530 --> 00:18:47,990 +أو ما إلى ذلك وضفنا عليها هذه المادة ودخل عليها .. + +227 +00:18:47,990 --> 00:18:52,510 +دخل عليها شوية أكسوجين وهي مغلقة هذا الأكسوجين أو + +228 +00:18:52,510 --> 00:18:56,510 +أي مادة مؤكسدة هيك هيك وظيفته هيجوم فيها هيعمل + +229 +00:18:56,510 --> 00:19:01,190 +أكسدة لكن اللي بيصير .. اللي بيصير بالظبط .. اللي + +230 +00:19:01,190 --> 00:19:06,190 +بيصير بالظبط في فكرة الـ Antioxidants اتخيلوها + +231 +00:19:06,190 --> 00:19:11,680 +انتوا بهذا الشكل ان انا هيعندي علبة معلباتواضح؟ + +232 +00:19:11,680 --> 00:19:19,280 +هذه معلبة لحمة الان هذه المعلبة اللحمة فيها اللحوم + +233 +00:19:19,280 --> 00:19:25,440 +خلينا نقول الحمراء وفيها بنسبة قليلة جدا جدا + +234 +00:19:25,440 --> 00:19:34,360 +antioxidant المادة هذه اللي بنقول عنهاالان اتيت + +235 +00:19:34,360 --> 00:19:41,620 +اكساد او اكسوجين او اكساد اكساد اكساد اكساد اكساد + +236 +00:19:41,620 --> 00:19:50,450 +اكساد اكسادإذا أكسدت اللحوم هتطلع مواد سامة برائحة + +237 +00:19:50,450 --> 00:19:55,870 +سيئة اللي هو فساد اللحمة، الآن في احتمال تاني إنها + +238 +00:19:55,870 --> 00:20:00,290 +ت أكسد ال antioxidant اللي أنا حطيته، بشكل عام + +239 +00:20:00,290 --> 00:20:04,490 +ميزة ال antioxidant إنه أسهل في الأكسدة، وبناء على + +240 +00:20:04,490 --> 00:20:10,290 +ذلك لما هذه بتتيجي إيش المادة الأسهل أن تتأكسد ال + +241 +00:20:10,290 --> 00:20:16,220 +antioxidant؟واضح؟ فالعمل المؤكسد هي كيك بيأكسد + +242 +00:20:16,220 --> 00:20:24,440 +فبيأكسد ال antioxid يعني مرة تانية نرجع نقول أن + +243 +00:20:24,440 --> 00:20:31,560 +اللحوم دلت زي ما هي ماصارش عليها إشي الآن ال + +244 +00:20:31,560 --> 00:20:35,100 +antioxid اتغيرت صارت أشياء جديدة + +245 +00:20:38,120 --> 00:20:43,060 +فعملية ال Oxidation حولت ال antioxidant لمادة + +246 +00:20:43,060 --> 00:20:46,620 +تانية الآن انتبهوا للناس اللي بيشتغلوا في الأغذية + +247 +00:20:46,620 --> 00:20:51,280 +شرط عندهم أن هذه المادة اللي أنا بستعملها + +248 +00:20:51,280 --> 00:20:56,320 +antioxidant تكون آمنة وغير سامة، مظبوط ولا لأ؟ ما + +249 +00:20:56,320 --> 00:21:01,730 +أنا ضيفة على الأكل، إذا هذه لازم تكون إيش؟ Safeو + +250 +00:21:01,730 --> 00:21:07,190 +ناتج أكسادتها أيضا هيضلوا في الأكل برضه لازم ايش + +251 +00:21:07,190 --> 00:21:15,490 +يكون safeفهل يا ترى عملية ال Axa ده مُنِعت ولا + +252 +00:21:15,490 --> 00:21:21,110 +تمت؟ تمت لكن تمت على إيش؟ على ال antioxidant مش + +253 +00:21:21,110 --> 00:21:24,730 +على اللحوم وال antioxidant تحول إلى مادة غير ضارة + +254 +00:21:24,730 --> 00:21:28,190 +وبالتالي ماصارش تأثير هذه فكرة بالظبط ال + +255 +00:21:28,190 --> 00:21:32,010 +antioxidants الآن من المواد اللي بتستعمل + +256 +00:21:32,010 --> 00:21:36,050 +antioxidants اللي هي ال phenolsيعني لو بتكون + +257 +00:21:36,050 --> 00:21:39,370 +تبحثوا في google search مثلا اكتبوا antioxidant + +258 +00:21:39,370 --> 00:21:43,350 +بتلاقوه بيكمل الكوفينول و آلاف الأبحاث و المواد + +259 +00:21:43,350 --> 00:21:50,710 +بعضها طبيعي و بعضها صناعي يعني مثلا هذا vitamin E + +260 +00:21:50,710 --> 00:21:55,070 +لاحظوا فيه هنا مجموعة الفينول ولا لأ + +261 +00:21:57,730 --> 00:22:02,250 +شكل كبير ماله و ماله لكن الجزء الفعال فيه جزء + +262 +00:22:02,250 --> 00:22:08,450 +الفينول ولذلك vitamin E بنقول عنه natural phenolic + +263 +00:22:08,450 --> 00:22:13,090 +antioxidant يعني مضاد للأكسدة أو مواصل الأكسدة + +264 +00:22:13,090 --> 00:22:19,100 +خلينا هيك اتفقنا عليه من مصادرطبيعية الآن في مواد + +265 +00:22:19,100 --> 00:22:22,740 +من مصادر صناعية يعني صنعوها في المختبر و بيضفوها و + +266 +00:22:22,740 --> 00:22:26,460 +هذه مشهورة كل علب المرتدلة و البندورة و البصاريش + +267 +00:22:26,460 --> 00:22:30,880 +بيضفو عليها منها هذه المراكبات أهم شي انتبهوا فيها + +268 +00:22:30,880 --> 00:22:38,020 +مجموعة ال ايش ال O H's الان هذه المراكبات مشتقات + +269 +00:22:38,020 --> 00:22:43,900 +أنيزول متذكرين الانيزول البنزينة اللي عليها O مثل + +270 +00:22:43,900 --> 00:22:49,510 +هذه اسمها أنيزوللما أخدنا ال aromatic compounds + +271 +00:22:49,510 --> 00:22:54,070 +أنيزول بنزين عليها O مثل عشان هيك هذا بنقول عنه + +272 +00:22:54,070 --> 00:22:58,350 +butylated لإنه هذا المجموعه butyl اربع كربونات + +273 +00:22:58,350 --> 00:23:05,130 +هيدروكسي لإنه فيه OH والاصل أنيزول شوفتوا الاسم من + +274 +00:23:05,130 --> 00:23:08,990 +كام قطعة مكوّن بيوتل و هيدروكسي و أنيزول هاي ال + +275 +00:23:08,990 --> 00:23:11,270 +butyl انعلمه بالأحمر + +276 +00:23:13,790 --> 00:23:21,090 +بيوتليتد هيدروكسي أنيزول الان ايش بيختصروه BHA + +277 +00:23:21,090 --> 00:23:26,630 +وهذا زيه بيوتليتد هيدروكسي أنيزول طيب لو الحلقة + +278 +00:23:26,630 --> 00:23:35,090 +الأصلية كانت طلوين هي بيوتلأيضا اكثر من مجموعة في + +279 +00:23:35,090 --> 00:23:41,510 +هذا المُركّب بيوتل وهيدروكسي وطولوين بيوتلاتد + +280 +00:23:41,510 --> 00:23:46,990 +هيدروكسي طولوين بيوتلاتد + +281 +00:23:46,990 --> 00:23:51,140 +هيدروكسي طولوينو عادة بتاخد رموز يعني بتلاقوها + +282 +00:23:51,140 --> 00:23:58,080 +بكتبوا BHA و BHT فالـ BHA و BHT اللي هي butylated + +283 +00:23:58,080 --> 00:24:01,240 +hydroxy anisole و butylated hydroxy toluene are + +284 +00:24:01,240 --> 00:24:06,840 +synthetic antioxidants عارفين إيش يعني synthetic + +285 +00:24:07,620 --> 00:24:13,500 +يعني مصنعة في المعمل، synthetic، هذه natural من + +286 +00:24:13,500 --> 00:24:17,420 +الطبيعة، في أشياء في الطبيعة و في أشياء بنصنعها + +287 +00:24:17,420 --> 00:24:26,180 +احنا و بنضيفها على الأطعمة هذا بالنسبة لموضوع الـ + +288 +00:24:26,180 --> 00:24:27,560 +Antioxidants + +289 +00:24:31,430 --> 00:24:36,590 +المُركّب أنيزول، المُركّب أنيزول، المُركّب أنيزول، + +290 +00:24:36,590 --> 00:24:43,090 +أما هي methoxy، methoxy، مش فيها خلافبنجي للعائلة + +291 +00:24:43,090 --> 00:24:48,550 +المشتقة من ال alcohols اللي قُبضلت فيها مجموعة ال + +292 +00:24:48,550 --> 00:24:55,330 +OH ب SH هذه العائلة شو بنسميها؟ Thyol فبدل ما يصير + +293 +00:24:55,330 --> 00:24:59,750 +نهاية المُركّب All بيصير نهاية المُركّب Thyol + +294 +00:24:59,750 --> 00:25:04,510 +ولذلك هذا مثلا كنا نسميه بال OH مثال All بيصير + +295 +00:25:04,510 --> 00:25:12,160 +مثالثيول هذا ابروبانول بيصير ابروبانثيول او عفوا + +296 +00:25:12,160 --> 00:25:16,520 +بيوتان اربعة بيوتانثيول طبعا لازم نحدد الموقع ولا + +297 +00:25:16,520 --> 00:25:23,080 +لأ ابيوتانثيول هذا بدل فينول شو بنسميه؟ ثيوفينول + +298 +00:25:23,080 --> 00:25:27,640 +ال OH فينول بال سالفر ثيوفينول الآن متذكرين لما + +299 +00:25:27,640 --> 00:25:32,960 +كان انا يكون OH شو كنت اسمي المركب؟ مثل ال alcohol + +300 +00:25:34,340 --> 00:25:40,120 +أو بيوت ال alcohol بال common name ال common name + +301 +00:25:40,120 --> 00:25:45,660 +بذكر المجموعة ثم العائلة مثل مثل alcohol هذا + +302 +00:25:45,660 --> 00:25:48,920 +common name المجموعة في العائلة بيوت ال alcohol و + +303 +00:25:48,920 --> 00:25:53,460 +هكذا الآن العائلة الموازية لكلمة alcohol في + +304 +00:25:53,460 --> 00:26:00,020 +الكبريت مركبتان فهذا بيصير مثلمركبتان هذا بيصير + +305 +00:26:00,020 --> 00:26:06,180 +بيوتل مركبتان هذا بيصير فنل مركبتان فمركبتان هي + +306 +00:26:06,180 --> 00:26:12,360 +العائلة الموازية لكلمة إيش؟ Alcohol زي ما كنت أقول + +307 +00:26:12,360 --> 00:26:15,400 +مثل ألكول، إثل ألكول، برو بالألكول، لو قلتلكوا + +308 +00:26:15,400 --> 00:26:19,720 +أرسموا مثل مركبتان، إثل مركبتان، بيوتل مركبتان، + +309 +00:26:19,720 --> 00:26:23,420 +ايزو بيوتل مركبتان، بتكون تشيلوا بدل أو أتش و + +310 +00:26:23,420 --> 00:26:29,570 +تحطوا الالكول، واضح؟طبعا وين انتوا بتشوفوا كلمة + +311 +00:26:29,570 --> 00:26:33,430 +mercapto او ثيو اعرفوا ان انتوا أمام مركب فيه + +312 +00:26:33,430 --> 00:26:37,290 +cabret يعني مركبات الكابريت دائما يا هتلاقوا فيها + +313 +00:26:37,290 --> 00:26:42,350 +ثيو زي ما شوفته هنا يا mercapto مثلا هذا حمض الخل + +314 +00:26:42,350 --> 00:26:49,930 +بس حولنا فيه بدل ما كانت OH أسيتك أسن CH3C double + +315 +00:26:49,930 --> 00:26:55,450 +bond O OH أسيتك أسن طب لو شيلت ال O خلتها S صار + +316 +00:26:55,450 --> 00:27:04,380 +ثيونacetic acid واضح هذا مثلا sulphide السلفر + +317 +00:27:04,380 --> 00:27:12,420 +المتصل فيها مجموعتين R إثل و إثل داي إثل sulphide + +318 +00:27:12,420 --> 00:27:16,100 +و الداي مرات تختصر يعني بنقدر نسميه الداي إثل و + +319 +00:27:16,100 --> 00:27:20,280 +بنقدر نسميه إثل يعني لما نقول إثل sulphide أو داي + +320 +00:27:20,280 --> 00:27:24,560 +إثل sulphide الإسمين صحيحين + +321 +00:27:25,800 --> 00:27:29,720 +الان لو اجينا عليها هذه العائلة قولنا يا تورا هذه + +322 +00:27:29,720 --> 00:27:33,800 +عائلة التيورس كيف بنحضرها ال R X أخدناها في + +323 +00:27:33,800 --> 00:27:37,700 +chapter 6 بال nucleophilic substitution فعلوها مع + +324 +00:27:37,700 --> 00:27:42,440 +S H minus charged nucleophile بيهاجم على ال R و + +325 +00:27:42,440 --> 00:27:48,580 +بيطرد ال X هذا الإبدال اللي أخدناه في chapter 6 + +326 +00:27:48,580 --> 00:27:57,270 +مشحون مكان مشحون فال R X بتصيرRSH اذا هى هذا اللى + +327 +00:27:57,270 --> 00:28:03,070 +هو how to prepare thyols by reaction of RX يصيروا + +328 +00:28:03,070 --> 00:28:08,710 +RSH الان بدى يكون عندكم شوية كيميا كبيرة فى مخكم + +329 +00:28:08,710 --> 00:28:13,490 +بمعنى لو انا يا تورا قلتلكم كيف بدكم تحضروا thyol + +330 +00:28:13,490 --> 00:28:16,970 +من الالكول الthyol انتوا عامال عندكم من وين بنحضره + +331 +00:28:16,970 --> 00:28:25,170 +من ال RX طب لو انا بديلكم ب ROHأخدت طريقة تحوّل ال + +332 +00:28:25,170 --> 00:28:32,310 +R OH ل R X تكون متذكرينها طيب ممكن كمان أبدأ من ال + +333 +00:28:32,310 --> 00:28:37,290 +كيم أخدت طريقة تحوّل ال ال كيم ل R X ولا لأ إضافة + +334 +00:28:37,290 --> 00:28:47,070 +HX فبصير مطلوب منكوا أن تدمجوا أكثر من معلومة في + +335 +00:28:47,070 --> 00:28:53,260 +الكيمياأخدنا احنا ان الثيولز are stronger acids + +336 +00:28:53,260 --> 00:28:58,520 +than alcohols، والسبب ايش حكينا؟ ال size، ال size، + +337 +00:28:58,520 --> 00:29:01,660 +ولذلك الثيولز بتفاعلوا مع ال sodium hydroxide + +338 +00:29:01,660 --> 00:29:07,170 +وبيعطوا ملح وماء، هذه المعادلة أخدناهامن أهم + +339 +00:29:07,170 --> 00:29:12,450 +التفاعلات تبعت الـthiols أنه بيتم عليهم أكسدة + +340 +00:29:12,450 --> 00:29:16,650 +جزيئين thiol بيفقدوا هيدروجين ماشيلنا ساعة بيقول + +341 +00:29:16,650 --> 00:29:20,790 +الأكسدة بيدا تفقد ذاتين هيدروجين الأن بنجيب جزيئين + +342 +00:29:20,790 --> 00:29:25,830 +thiol RSH بنسبة اتنين مثلا بالأكسدة بيفقدوا + +343 +00:29:25,830 --> 00:29:32,760 +هيدروجينيعني ماينوس اكشت و الاكس ده بيصير RSSR هذا + +344 +00:29:32,760 --> 00:29:37,940 +صار اسمه داي سالفايد لما عندي سالفار واحدة سالفايد + +345 +00:29:37,940 --> 00:29:41,940 +لما عندي تنتين داي سالفايد لو افترضنا هنا اثل و + +346 +00:29:41,940 --> 00:29:48,040 +اثل شو بدا اسم المركب داي اثل داي سالفايد طب لو + +347 +00:29:48,040 --> 00:29:52,600 +مثل و مثل داي مثل داي سالفايد لو هذه المجموعة اللي + +348 +00:29:52,600 --> 00:29:59,580 +مرة أخدناهاالألل اللى موجودة فيه التومة داي ألل + +349 +00:29:59,580 --> 00:30:06,300 +داي سالفايد واضح فالثيول هم اكسيدز لثيول داي + +350 +00:30:06,300 --> 00:30:11,040 +سالفايد الان لو ضفنا عليهم هيدروجين يعملنا التفاعل + +351 +00:30:11,040 --> 00:30:17,820 +العكسى ال داي سالفايد ايش بيرجعوا ثيول اذا هذه + +352 +00:30:17,820 --> 00:30:23,900 +عمليةبتمشي باتجاهين بحق في الهيدروجين الثيول بيصير + +353 +00:30:23,900 --> 00:30:27,600 +داي سالفايد هذه أكسه ده بإضافة الهيدروجين ال داي + +354 +00:30:27,600 --> 00:30:33,160 +سالفايد بترجع لإيش؟لثيول الان هذه العملية .. هذه + +355 +00:30:33,160 --> 00:30:37,900 +العملية الحقيقة عملية في ال biology و في الأحياء + +356 +00:30:37,900 --> 00:30:42,340 +كتير مهمة ليش؟ لأنه في النهاية البروتينات لما + +357 +00:30:42,340 --> 00:30:47,540 +بتتماسك مع بعض لبعض فيها مجموعات الثيول و تحديدا + +358 +00:30:47,540 --> 00:30:51,920 +جاية من ال amino acid السيستين فتخيلوا ان عندكم + +359 +00:30:51,920 --> 00:30:57,060 +مثلا سلسلتين و في النهاية فيهم SH من البروتين هذا + +360 +00:30:57,060 --> 00:31:05,700 +بالأكسدةيفقد الهيدروجنتين و يعمل رابطة، بهيك صار + +361 +00:31:05,700 --> 00:31:11,320 +البروتين امسك بشكل قوي ولا لأ؟ بيصير البروتين امسك + +362 +00:31:11,320 --> 00:31:18,040 +بشكل قوي، الآن من أمثلة البروتينات اللي فيها الـ + +363 +00:31:18,040 --> 00:31:24,390 +disulfides الشعرو عشان هيك الشعر لاحظه أنه أحيانا + +364 +00:31:24,390 --> 00:31:28,350 +لما الإنسان إيده بتقترب من النار أو بينحرق شعره + +365 +00:31:28,350 --> 00:31:34,090 +بيشم رائحة سيئة رائحة حرق الشعر سيئة شو السبب؟ أن + +366 +00:31:34,090 --> 00:31:42,430 +الشعر فيه كبريت الآن هذا الشعر الناس للأسف الشديد + +367 +00:31:42,430 --> 00:31:48,730 +مش عاجبها حالها كل من هو بده يغير إيش شكله امتثالا + +368 +00:31:51,390 --> 00:31:58,310 +لما قولت الشيطان ثم لأمرنهم فلا يغيرن خلق الله + +369 +00:31:58,310 --> 00:32:03,850 +يعني اللي في أفريقيا الشعر عندهم لو لو بيعمل بده + +370 +00:32:03,850 --> 00:32:07,510 +يفرده و اللي في أوروبا ربنا ماعطيهم الشعر العدل + +371 +00:32:07,510 --> 00:32:13,930 +بتشوفهم كيف بدهم يعملوا الوف الان هذا بالانجليزي + +372 +00:32:13,930 --> 00:32:20,920 +احنا بنقوله curly الشعرالمجاعد المجاعد أو straight + +373 +00:32:20,920 --> 00:32:24,780 +الشعر المستقيم الشعر المستقيم الان ابتاع ال + +374 +00:32:24,780 --> 00:32:28,920 +straight بدو يصير مجاعد وابتاع المجاعد بدو يصير + +375 +00:32:28,920 --> 00:32:33,240 +straight ماحدش عاجبه حاله هذه العملية سواء تمت + +376 +00:32:33,240 --> 00:32:38,210 +بهذا الاتجاه او بهذا الاتجاه هي عملية كيميائيةهي + +377 +00:32:38,210 --> 00:32:41,170 +عملية كيميائية، يعني هذه العملية اللي بتنعمل في + +378 +00:32:41,170 --> 00:32:47,250 +صالونات لحلاجة وعند الكوفيرات الحقيقة هي عملية + +379 +00:32:47,250 --> 00:32:51,330 +كيميائية الفكرة فيها وين؟ انه احنا بنقدر نتخيل + +380 +00:32:51,330 --> 00:32:57,170 +الشعر بروتين وهذا البروتين ممسك بـ disulfide bonds + +381 +00:32:57,170 --> 00:33:05,450 +ملاحظين هنا؟هذه بتقدروا تتخيلوها شعرة، الان كونوا + +382 +00:33:05,450 --> 00:33:10,470 +الشعر في الـ disulfide bond هذه، بيصير الشعر قوي + +383 +00:33:10,470 --> 00:33:15,830 +ولا لأ؟ بالنسبة لخيط، بالنسبة لخيط يعتبر الشعر + +384 +00:33:15,830 --> 00:33:23,200 +قوي، سبب القوة تبعته وجود إيش؟ وجود؟الـ disulfide + +385 +00:33:23,200 --> 00:33:29,060 +bond الان كيف يتحول + +386 +00:33:29,060 --> 00:33:34,800 +الشعر من شكل إلى آخر خلينا نعملها ربما بالجلم + +387 +00:33:34,800 --> 00:33:44,260 +بتحبوا نبدأ بإيش؟ بشعر straight ونخليه curly الان + +388 +00:33:44,260 --> 00:33:52,020 +هذه الشعره straight هذه الشعره إيش فيها روابط؟SS + +389 +00:33:52,020 --> 00:33:58,460 +نعمل رابطتين او تلاتة الان هذه الروابط بيخليها + +390 +00:33:58,460 --> 00:34:03,660 +عدلة طب لو انا بدي اتنيها شعره جوية ايش لازم اعمل + +391 +00:34:03,660 --> 00:34:08,800 +في الاول اكسر هدوله عشان هيك بييجوا بيعملوا عملية + +392 +00:34:08,800 --> 00:34:14,830 +ايش reductionيعني بيحطوا مادة ع الشعر و بيفركوه + +393 +00:34:14,830 --> 00:34:19,670 +بتدخل هذه المادة جوا الشعر فبتضعف الشعره بتصير + +394 +00:34:19,670 --> 00:34:23,690 +عملية reduction الان ال reduction لاحظوا معي شو + +395 +00:34:23,690 --> 00:34:33,170 +عمل؟ كسر ال di-sulfate خلاها SH SH SH SH و هكذا + +396 +00:34:33,170 --> 00:34:43,400 +الان هذه كانت شعره قويةصارت شعرة ضعيفة الآن الشعرة + +397 +00:34:43,400 --> 00:34:49,800 +الضعيفة بالمشط مع شوية استشوار ممكن نتنيها واضح؟ + +398 +00:34:49,800 --> 00:34:57,820 +لأنها ضعيفة وعشان هيك ممكن نخليها بهذا الشكل طبعا + +399 +00:34:57,820 --> 00:35:05,960 +أسأتش أسأتش تمت المهمة ولا لأ؟ تمت، هذه الشعرة + +400 +00:35:05,960 --> 00:35:12,520 +اللي كانتعدلة إيش صارت؟ إضعيفة بس هذه في الأجارة + +401 +00:35:12,520 --> 00:35:19,320 +بتستهلش ميت شكل تستهل بس قداشر؟ + +402 +00:35:19,320 --> 00:35:26,740 +اشرين تلاتين شكل ليش؟ لأنه إضعيفة بتعاود تعدل ما + +403 +00:35:26,740 --> 00:35:31,060 +هو اللي بيعمل منكر بده يكمله إذا إيش الحل عشان + +404 +00:35:31,060 --> 00:35:38,820 +نكمل هالقصة؟ إننا نرد بشكل جديد نجويهاعشان بتكون + +405 +00:35:38,820 --> 00:35:44,440 +تدفعوا مصارى، بتقولش الواحد الشعر يكون طويل، يصاب، + +406 +00:35:44,440 --> 00:35:50,640 +املولو، بعدين روح قدر لجارجع زي ما هو، املاحظين + +407 +00:35:50,640 --> 00:35:54,360 +انتوا؟ عشان هيك هذى بيعملولها كمان عملية كيميائية، + +408 +00:35:54,360 --> 00:35:58,380 +شو العملية الكيميائية؟ أكسدة مرة تانية ع الشكل + +409 +00:35:58,380 --> 00:36:08,260 +الجديد عشان ترجع جوية، لإن هذى ضعيفةهذه ضعيفة، + +410 +00:36:08,260 --> 00:36:13,300 +بدنا نحافظ على الشكل الجديد اللي عملناه وعشان هيك + +411 +00:36:13,300 --> 00:36:17,440 +اللي انتوا مرات بتسموه مثبت أو غيره ميتي الأكسجين + +412 +00:36:17,440 --> 00:36:26,800 +اللي بتبحط اه H2O2 أكسدا فلاحظوا + +413 +00:36:26,800 --> 00:36:34,040 +عملية تحويل الشعر من شعر straight إلى curly بتمر + +414 +00:36:34,040 --> 00:36:40,610 +بكم عملية؟عمليتين العملية + +415 +00:36:40,610 --> 00:36:44,150 +الأولى reduction صارت الشعر القوى ضعيفة + +416 +00:36:46,370 --> 00:36:51,770 +ملفوفة بشكل معين وبعدين رديت أكسادتها إذا رجعتها + +417 +00:36:51,770 --> 00:36:56,570 +لشكل إيش القوي عشان هيك بتثبت بالشكل الجديد + +418 +00:36:56,570 --> 00:37:01,710 +فعمليتين بتتموا على الشعرة عشان تتحول هذا التحول + +419 +00:37:01,710 --> 00:37:06,850 +عملية reduction وعملية oxidation الآن لو سألنا أي + +420 +00:37:06,850 --> 00:37:14,850 +واحدة فيكم طيب ناس من أفريقيا مثلاشعرهم مجعد، بدهم + +421 +00:37:14,850 --> 00:37:19,870 +يخلوه عدل، بدهم يعكسوا كل هذه الدائرة، بدهم يبدأوا + +422 +00:37:19,870 --> 00:37:25,430 +بال reduction عكس ال oxidation، reduction، تصير + +423 +00:37:25,430 --> 00:37:30,410 +زيك ضعيفة، بعدين بيعدلوها بالاستشوار والنار، بتصير + +424 +00:37:30,410 --> 00:37:38,250 +عدلة، فرحوا، بعدين بيأكسدوها، بتصير قوية بالشكل + +425 +00:37:38,250 --> 00:37:44,070 +الجديدشوفتوا كيف هذه العملية كلها اذا عمليات قصة + +426 +00:37:44,070 --> 00:37:49,010 +الشعر هذه عمليات ايش مالها كيميائية الان هذا تطبيق + +427 +00:37:49,010 --> 00:37:54,590 +Biology بس انا بهمش لو سمحتوا خلال دقيقتين هحكيلكم + +428 +00:37:54,590 --> 00:38:00,070 +على تطبيق اهم كتير منه كمان يعني هذا تطبيق ترفي + +429 +00:38:00,070 --> 00:38:04,770 +لكن في تطبيق في الحياة و بالذات بعض الناس منكم + +430 +00:38:04,770 --> 00:38:09,790 +يمكن يتخصصوا في البصريات الطبيةتطبيق كتير مهم + +431 +00:38:09,790 --> 00:38:19,290 +بتعرفوا الخشب اللي موجود اليوم ال MDF وغيره لو كان + +432 +00:38:19,290 --> 00:38:22,650 +محطوط على الأرض و بيصير أحيانا رطوبة في الأرض و + +433 +00:38:22,650 --> 00:38:28,070 +بتشطفه اشي زي هيك شو بيصيله؟ بينفش عارفين هذه + +434 +00:38:28,070 --> 00:38:32,350 +الشغلة؟ يعني انه بيكون عندكم الخشبة كأنها طبقات زي + +435 +00:38:32,350 --> 00:38:35,810 +هيك مع الرطوبة كيف بتصير؟ + +436 +00:38:38,140 --> 00:38:43,600 +بتنفش، هذه الفكرة عارفينها؟ كويس، الآن في فكرة + +437 +00:38:43,600 --> 00:38:47,960 +موازية لها، في فكرة موازية لها تماما، انه احنا + +438 +00:38:47,960 --> 00:38:54,350 +عندنا في القرنية تبعت العلم، هذه تحدوبهايعني كما + +439 +00:38:54,350 --> 00:38:59,790 +قال الله تعالى وكل شي عنده بمقدار مش المفروض يختل + +440 +00:38:59,790 --> 00:39:04,090 +يعني اتخيلوها انتوا و الامر schematic و تفصيله عند + +441 +00:39:04,090 --> 00:39:08,510 +الإخوة التعون البصرية تتخيلوها مثلا بهذا الشكل + +442 +00:39:08,510 --> 00:39:13,870 +الآن هذا التحدب خلاص لازم نظلنا ايش احنا ملتزمين + +443 +00:39:13,870 --> 00:39:19,800 +فيه هذا في عند انا disulfide bondsيعني أس .. أس .. + +444 +00:39:19,800 --> 00:39:26,420 +أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس + +445 +00:39:26,420 --> 00:39:26,420 +.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. + +446 +00:39:26,420 --> 00:39:26,820 +أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس + +447 +00:39:26,820 --> 00:39:29,340 +.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. + +448 +00:39:29,340 --> 00:39:29,920 +أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس + +449 +00:39:29,920 --> 00:39:32,400 +.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. + +450 +00:39:32,400 --> 00:39:33,340 +أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس + +451 +00:39:33,340 --> 00:39:33,680 +.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. + +452 +00:39:33,680 --> 00:39:44,760 +أس .. أس .. أس .. أس + +453 +00:39:44,760 --> 00:39:52,110 +..زي الخشب اللي نفش املاحظين؟ تماما، بهذه الحالة + +454 +00:39:52,110 --> 00:39:56,150 +صارت مشكلة في الإبصار ولا لأ؟ صار مشكلة في الإبصار + +455 +00:39:56,150 --> 00:40:00,430 +طيب يا تورا لو بدنا نعالج هذه المشكلة في الإبصار، + +456 +00:40:00,430 --> 00:40:07,310 +شو بدنا نعمل؟ بمنطق الكيميا بدأ + +457 +00:40:07,310 --> 00:40:12,490 +أعمل أكسدةبدي أرجح هذه لهذه بدي أكوّن الـ + +458 +00:40:12,490 --> 00:40:17,450 +disulfide bonds ولذلك أنا لما بدي أعالج هاي حالة + +459 +00:40:17,450 --> 00:40:21,850 +المرض و هاي حالة السليم لما بدي أعالج المريض أرجعه + +460 +00:40:21,850 --> 00:40:26,990 +لسليم إيش بدي أعمل؟ Oxidation هذه من العمليات + +461 +00:40:26,990 --> 00:40:30,410 +الحديثة اللي تجرى و كمان تجرى في غزة غالبا بتاعة + +462 +00:40:30,410 --> 00:40:33,890 +اللي بيستعملوا ال ozone كعمل مؤكسد مع أشياء تقنية + +463 +00:40:33,890 --> 00:40:39,230 +كاملة بس الإنسان يكون فاهم إيشال general idea + +464 +00:40:39,230 --> 00:40:43,670 +الفكرة العامة الفكرة العامة انه داي سالفايد بتصير + +465 +00:40:43,670 --> 00:40:49,230 +ايش ثيول بطل الشكل المنتظم القرنية و ما إلى ذلك + +466 +00:40:49,230 --> 00:40:54,390 +لما ارد أعمل الأكسة ده بيرجع الثيول إلى داي + +467 +00:40:54,390 --> 00:40:59,830 +سالفايد رجعتهازي ما كانت، فالأفكار البسيطة اللي + +468 +00:40:59,830 --> 00:41:05,430 +أحيانا بتمر عليكم يعني ربما أول ما الإنسان بيشرح + +469 +00:41:05,430 --> 00:41:08,230 +لما تشوفوا كلمة آسيول + +470 +00:41:11,410 --> 00:41:16,530 +ثيول يصير داي سالفايد okay فكرة كيميا لكن الجميل + +471 +00:41:16,530 --> 00:41:21,210 +دائما بفكرة الكيميا انها بتتحول لفكرة ايش لفكرة + +472 +00:41:21,210 --> 00:41:27,970 +تطبيق ولا فكرة حياة بهيك بننهي chapter ال alcohols + +473 +00:41:27,970 --> 00:41:32,430 +ان شاء الله المرة القادمة بنبدأ في موضوع ال ethers + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..f4724512519cfb0d5581d5113ba9777260665efc --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_postprocess.srt @@ -0,0 +1,1892 @@ +1 +00:00:19,760 --> 00:00:25,420 +بسم الله الرحمن الرحيم نستمر اليوم في موضوع ال + +2 +00:00:25,420 --> 00:00:29,040 +carboxylic acids and their derivatives ربما المرة + +3 +00:00:29,040 --> 00:00:34,360 +الأخيرة اتكلمنا على تحضير ال acid anhydrides + +4 +00:00:34,360 --> 00:00:38,900 +وصنفناهم ل symmetrical anhydride و unsymmetrical + +5 +00:00:38,900 --> 00:00:45,240 +anhydrideبالنسبة لتفاعلاتهم، لا يخرجوا عن الإطار + +6 +00:00:45,240 --> 00:00:48,380 +العام لتفاعلات الأحماض ومشتقاتها، اللي هو + +7 +00:00:48,380 --> 00:00:54,060 +substitution reaction، واضح؟ فعلى سبيل المثال، هذا + +8 +00:00:54,060 --> 00:01:00,550 +الـ anhydrideلو اجينا نفعله مثلا مع الميه الميه + +9 +00:01:00,550 --> 00:01:04,470 +هتكون ال يوكليوفايل ييجي تهاجم هنا و ينكسر من هذا + +10 +00:01:04,470 --> 00:01:09,670 +المكان الان هذا الجزء هيصير acid لو فعلنا مع الميه + +11 +00:01:09,670 --> 00:01:13,330 +و هذا الجزء ايضا هياخد الاتش يصير acid بناء على + +12 +00:01:13,330 --> 00:01:18,450 +ذلك تفاعل الانهيدريد مع الميه بيرجع الى ايش الى + +13 +00:01:18,450 --> 00:01:26,440 +حامضين لو اجينا مثلا نفعل كحولهذا الجزء هيجي عليه + +14 +00:01:26,440 --> 00:01:34,340 +بدل OH في حالة الكحون OR هيصير Easter وهذا بيطلع + +15 +00:01:34,340 --> 00:01:40,220 +على شكل acid لو جينا الفاعل مع ammonia هذا الجزء + +16 +00:01:40,220 --> 00:01:45,870 +هيصير amineان اتش تو مثلا او ان اتش ار هيصير امين + +17 +00:01:45,870 --> 00:01:50,310 +وهذا بيطلع على شكل حامض فزي ما بتلاحظوا انه دائما + +18 +00:01:50,310 --> 00:01:55,650 +في عندى جزء معين بيطلع على شكل حامض وهذا الجزء + +19 +00:01:55,650 --> 00:02:00,910 +اللى هجم عليه النيكليوفايل من الميه لنيكليوفايل OH + +20 +00:02:00,910 --> 00:02:05,550 +من الكحول لنيكليوفايل OR من الأمونيا لنيكليوفايل + +21 +00:02:05,550 --> 00:02:12,930 +NH2 وبالتالي ممكن ارجعلل acid ل ال E star ل الأمد + +22 +00:02:12,930 --> 00:02:18,710 +و هكذا هذا مثال تطبيقي اللي موجود عندنا هنا كيف + +23 +00:02:18,710 --> 00:02:25,210 +نحضر الأسبيرين واضح؟ كيف نحضر الأسبيرين ربما سبق + +24 +00:02:25,210 --> 00:02:29,010 +مار معنا ان احنا بننطلق من ال salicylic acid + +25 +00:02:29,750 --> 00:02:34,110 +الساليسليك أسد اللى هو الحامض ال بنزويك أسد اللى + +26 +00:02:34,110 --> 00:02:40,950 +على موقع ألفا منه OH فهو على موقع أورثو منه OH فهو + +27 +00:02:40,950 --> 00:02:46,430 +أورثو هيدروكسي بنزويك أسد واسمه ساليسليك أسد وزي + +28 +00:02:46,430 --> 00:02:50,970 +ما اتفقنا لازم تكونوا عارفينه سواء قولنا أورثو + +29 +00:02:50,970 --> 00:02:58,920 +هيدروكسي بنزويك أسدهذا ال name ايوبك الان لو بدكم + +30 +00:02:58,920 --> 00:03:03,420 +ال common name تبعه ايش salicylic acid الان هذا + +31 +00:03:03,420 --> 00:03:09,140 +فيه OH اللي هي تعتبر الكهور من ناحية المبدأ هذا ال + +32 +00:03:09,140 --> 00:03:14,040 +OH لما اتهاجل على ال acid anhydride عادة بيفعله مع + +33 +00:03:14,040 --> 00:03:18,900 +ال acetic anhydride فهتكسر + +34 +00:03:18,900 --> 00:03:25,570 +من هنا الحامضزي كل الأمثلة السابقة وهذا الجزء + +35 +00:03:25,570 --> 00:03:30,610 +هييجي اللي هو ممثلا للكحول فكأنه في النهاية اللي + +36 +00:03:30,610 --> 00:03:38,410 +صار عندى Easter حقيقة راحظوا R C double bond O O R + +37 +00:03:38,410 --> 00:03:43,270 +or A R هذا Easter هذا هو ال Aspirin الآن ال + +38 +00:03:43,270 --> 00:03:47,470 +Aspirin عادة بنسميه احنا لأنه حاطينا في هذا + +39 +00:03:47,470 --> 00:03:53,740 +المجموع ال acetinAcetyl Salicylic Acid أو أسيتو + +40 +00:03:53,740 --> 00:03:56,740 +سالي سيليك أسد هذا اللي بياخد اسم الشهراء + +41 +00:03:56,740 --> 00:04:03,080 +الأسبيرين أسيتل أو أسيتو و جزء السالي سيليك أسد + +42 +00:04:03,080 --> 00:04:07,260 +فالأسبيرين أسيتل سالي سيليك أسد فانتوا لما بتقرأوا + +43 +00:04:07,260 --> 00:04:12,800 +على علب الأدويةسواء كان بتركيز خمسمية ميلي جرام + +44 +00:04:12,800 --> 00:04:17,740 +الحبة أو بتركيز المية اللى بيسموها ال baby aspirin + +45 +00:04:17,740 --> 00:04:20,640 +اللى بياخدوها الناس اللى عندهم الجلطات و أحيانا + +46 +00:04:20,640 --> 00:04:25,740 +الان صاروا يصنعوا منها اعتمدوا تركيز واحد و تمانين + +47 +00:04:25,740 --> 00:04:29,300 +لل baby aspirin يعني بدل ما يعملوا ميت ميلي جرام + +48 +00:04:29,300 --> 00:04:32,860 +في ال tablet في الحبة لأ بيعملوها واحد و تمانين + +49 +00:04:33,360 --> 00:04:37,580 +تمام هتقرؤوا واحد و تمانين ميلي جرام او ميت ميلي + +50 +00:04:37,580 --> 00:04:41,620 +جرام Acetyl Salicylic Acid او Acetosalicylic Acid + +51 +00:04:41,620 --> 00:04:46,320 +فمعنى ذلك انه فيها هذا المقدار من دوة الاشه + +52 +00:04:46,320 --> 00:04:56,140 +الاسبريل من دوة الاسبريل بفر + +53 +00:04:56,140 --> 00:04:58,440 +اسبريل بفر اسبريل + +54 +00:05:00,950 --> 00:05:06,170 +لأ هو بس بيحاولوا يخففوا من مشاكل تأثيره على + +55 +00:05:06,170 --> 00:05:10,370 +المعدة من خلال أنه بيكون مخلوط بنظام ال buffer هو + +56 +00:05:10,370 --> 00:05:17,730 +مشكلة الأسبيرين حقيقة أنه الجزء الفعال فيه اللي هو + +57 +00:05:17,730 --> 00:05:22,750 +ال salicylic acid نفسه لكن ال salicylic acid نفسه + +58 +00:05:22,750 --> 00:05:28,170 +يعني شديد على المعدةفبناء على ذلك هم بيحولوا ل + +59 +00:05:28,170 --> 00:05:32,750 +acid ال salicylic acid فلما يمر في المعدة بيمر على + +60 +00:05:32,750 --> 00:05:36,130 +شكل acid ال salicylic acid لما ينزل على القمعة في + +61 +00:05:36,130 --> 00:05:40,570 +الوسط القلوي بتروح تكسر هادي و بيرجع ل salicylic + +62 +00:05:40,570 --> 00:05:45,550 +acidفكل الفكرة و المشاكل اللي يعني مرتبطة في ال + +63 +00:05:45,550 --> 00:05:50,590 +Aspirin هي مشاكل التأثير على المعدة، فلما يعملوا + +64 +00:05:50,590 --> 00:05:54,990 +coated بنظام معين ولا buffer Aspirin، كله على أساس + +65 +00:05:54,990 --> 00:05:58,570 +يخففوا تأثيره على إيش المعدة، بالذات اللي عندهم + +66 +00:05:58,570 --> 00:06:02,780 +يعني قرحة متهيجة، مابقدروش ياخدوا ال Aspirinاللي + +67 +00:06:02,780 --> 00:06:07,840 +عندهم قرحة متهيجة وغلبة عندهم إشكالية إنهم ياخدوا + +68 +00:06:07,840 --> 00:06:11,760 +ال Aspirin فبيحاولوا عاد يعملوا الجرعات الخفيفة + +69 +00:06:11,760 --> 00:06:15,000 +ويعملوه coated مثلا في Aspirin بسموه Aspirin + +70 +00:06:15,000 --> 00:06:21,140 +Cartia، buffer Aspirin، كل هذا لتقليل إيش؟ تأثيره + +71 +00:06:21,140 --> 00:06:22,080 +على المهدة + +72 +00:06:24,930 --> 00:06:30,750 +الجزء الأخير في مشتقات الأحماض ال Amides طبعا سبق + +73 +00:06:30,750 --> 00:06:34,250 +أنه إحنا عرفنا ال Amides قولنا ال C double bond O + +74 +00:06:34,250 --> 00:06:39,770 +اللي جنبها نيتروجين، الآن بهمش، بدناش نظل نقول + +75 +00:06:39,770 --> 00:06:44,660 +اللي جنبها ال H2لأ بدنا نغير كلامنا شوية نقول اللي + +76 +00:06:44,660 --> 00:06:51,140 +جنبها nitrogen اللي جنبها nitrogen تمام؟ الآن هذه + +77 +00:06:51,140 --> 00:06:56,020 +ال nitrogen غير إن أنا متصلة بصيدة بال bond O عادة + +78 +00:06:56,020 --> 00:07:00,940 +كام رابطة بتعمل؟ تلاتة، تلاتة، تلاتة، تلاتة، + +79 +00:07:00,940 --> 00:07:02,120 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +80 +00:07:02,120 --> 00:07:02,440 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +81 +00:07:02,440 --> 00:07:05,140 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +82 +00:07:05,140 --> 00:07:05,920 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +83 +00:07:06,140 --> 00:07:10,760 +بناء على ذلك هدولة ممكن يكونوا H وH ونقول جنبها N + +84 +00:07:10,760 --> 00:07:16,380 +H2 ممكن يكونوا H وR وممكن يكونوا R وR يعني مايكونش + +85 +00:07:16,380 --> 00:07:21,700 +هيدروجين بالمرة فالأمد سيضة بال point O جنبها N ال + +86 +00:07:21,700 --> 00:07:30,660 +N ال N حاملة 2 H بصير الأمد حاملة واحدة H واحدة R + +87 +00:07:31,670 --> 00:07:39,450 +برضه بيصير الأمد حاملة تنتين R برضه بيصير واضحة + +88 +00:07:39,450 --> 00:07:45,510 +الفكرة؟ الآن ضمن هذا المنطق بيصير في عنده تصنيف + +89 +00:07:45,510 --> 00:07:50,590 +لأنواع الأمد بيصير عنده تصنيف لأنواع الأمد يعني + +90 +00:07:50,590 --> 00:07:54,750 +لاحظوا ال nitrogen هنا متصلة بكم كاربون لما تكون + +91 +00:07:54,750 --> 00:08:00,250 +حاملة H وH؟ بكاربون واحدة إذا هذا الأمد الأخضر إيش + +92 +00:08:00,250 --> 00:08:04,480 +بنقول عنه؟primary amide متصلة ب one carbon + +93 +00:08:04,480 --> 00:08:10,840 +النيتروجين لو صرت متصلة ب H و ب R يعني ب carbon و + +94 +00:08:10,840 --> 00:08:16,410 +من هنا ب carbon ايش بده تكون secondaryوالـ + +95 +00:08:16,410 --> 00:08:22,870 +Nitrogen لو كانت متصلة بـ R و بـ R .. بـ Carbon و + +96 +00:08:22,870 --> 00:08:26,170 +بـ Carbon و هنا الطبيعة الحالي بـ Carbon هتكون + +97 +00:08:26,170 --> 00:08:31,670 +ايش؟ Tertiary بناء على ذلك الأمد بيصير تلت أنواع + +98 +00:08:32,490 --> 00:08:38,090 +والأمد بيصير تعريفه العام C double bond O متصلة + +99 +00:08:38,090 --> 00:08:44,530 +بإيش؟ بنيتروجين هالنيتروجين هذه تكون NH2 primary + +100 +00:08:44,530 --> 00:08:51,150 +أمد NHR secondary أمد NR2 tertiary أمد واضح هذه + +101 +00:08:51,150 --> 00:08:56,710 +الفكرة؟ الآن هذه الفكرة طالما احنا وقفنا عندها + +102 +00:08:56,710 --> 00:09:04,890 +هتجيبنا لنقطة كتير مهمةالعمل ممكن يعمل hydrogen + +103 +00:09:04,890 --> 00:09:11,210 +bonding وممكن مايعملش وممكن يعمل بشكل كبير وممكن + +104 +00:09:11,210 --> 00:09:13,830 +يعمل بشكل اقل عارفين انتوا ال hydrogen bonding + +105 +00:09:13,830 --> 00:09:18,370 +بيصير لما يكون عندى hydrogen متطابط يا بنيتروجين + +106 +00:09:18,370 --> 00:09:23,730 +يا باكسوجين يا بفلورين الان لو اجيت على المركب + +107 +00:09:23,730 --> 00:09:31,510 +اللى هو ال primary amine فيه MHو تنتين مش واحدة + +108 +00:09:31,510 --> 00:09:36,350 +تمام اذا ال primary amide ممكن يعمل hydrogen + +109 +00:09:36,350 --> 00:09:40,430 +bonding ولا لأ و ممكن يعمل كام hydrogen bonding + +110 +00:09:40,430 --> 00:09:44,730 +طالما فيه تنتين hydrogen ممكن يعمل two hydrogen + +111 +00:09:44,730 --> 00:09:52,550 +bonding الان لو اجيت على ال secondary amide في كام + +112 +00:09:52,550 --> 00:09:58,690 +هيدروجينةوحدة إذا ممكن يعمل one hydrogen bonding + +113 +00:09:58,690 --> 00:10:04,590 +لو إجيت على ال tertiary amide مش فيه hydrogen إذا + +114 +00:10:04,590 --> 00:10:09,030 +بيعملش hydrogen bonding واضحة الفكرة إذا لو أنا + +115 +00:10:09,030 --> 00:10:11,450 +بدي أجي أشوف ال amides من ناحية ال hydrogen + +116 +00:10:11,450 --> 00:10:17,910 +bonding مين أكثر واحد بيعمل hydrogen bonding بعده + +117 +00:10:18,450 --> 00:10:23,970 +بعده tertiary ع طول مباشرة ال hydrogen bonding + +118 +00:10:23,970 --> 00:10:29,970 +بنعكس على أي خاصية على ال boiling point بناء على + +119 +00:10:29,970 --> 00:10:34,330 +ذلك لما انا بدي اجي احكي عن ال boiling point مين + +120 +00:10:34,330 --> 00:10:40,870 +هيكون اعلى boiling point ال primary اعلى من ال + +121 +00:10:40,870 --> 00:10:47,330 +secondary اعلى من ال tertiaryالان لو قلنا لكوا ليش + +122 +00:10:47,330 --> 00:10:51,010 +ال primary أعلى من ال secondary لأن ال primary فيه + +123 +00:10:51,010 --> 00:10:54,250 +تنين هيدروجين bonding السكندرية واحدة ليش + +124 +00:10:54,250 --> 00:10:57,710 +السكندرية أعلى من ال tertiary السكندرية فيه + +125 +00:10:57,710 --> 00:11:01,430 +إمكانية لوان هيدروجين bonding الترتشيري مافيش فيه + +126 +00:11:01,430 --> 00:11:05,450 +إمكانية للهيدروجين bonding فالأمر في ال boiling + +127 +00:11:05,450 --> 00:11:10,590 +point ما بين ال primary والسكندرية والترتشيريهو + +128 +00:11:10,590 --> 00:11:15,310 +إلى إمكانية تكوين الـ hydrogen bonding واضحة هذه + +129 +00:11:15,310 --> 00:11:20,410 +الفكرة كتصنيف amides و كنقاط غليان لاحظوا هذه + +130 +00:11:20,410 --> 00:11:28,020 +الفكرة نفسها موجودة هنا مثلالو انا اتطلعت على + +131 +00:11:28,020 --> 00:11:31,760 +الامد و كلكم اتذكرين انه احنا بالنسبة للامد لما + +132 +00:11:31,760 --> 00:11:35,920 +سبق المرة الماضية اتكلمنا عن تسميته قولنا بنيجي + +133 +00:11:35,920 --> 00:11:40,380 +بنشوف ايش اسم الحامض الاصلي و بنشيل oic acid و + +134 +00:11:40,380 --> 00:11:45,140 +بنكتب بدالها امد يعني هذا الحمض واحد اتنين تلاتة + +135 +00:11:45,140 --> 00:11:51,860 +كان بروبانوك اسد بيصير بروبان امد هذا الحمض لما + +136 +00:11:51,860 --> 00:11:58,300 +يكون OH بنزوك اسد بيصير بنز امدحمد و هكذا واضح + +137 +00:11:58,300 --> 00:12:03,540 +الفكرة؟ الأن لو مثلا اتيت على هذا المركب C double + +138 +00:12:03,540 --> 00:12:08,160 +bond O اللي حامل H هذا أبسط حامد في الدنيا لإن لو + +139 +00:12:08,160 --> 00:12:13,020 +هذه كانت OH بيكون Formic Acid بناء على ذلك من + +140 +00:12:13,020 --> 00:12:18,500 +Formic Acid من Formic Acid لما أعمل حامد Primer شو + +141 +00:12:18,500 --> 00:12:25,940 +هسميه؟ Formamideطيب يا ترى لو إجيت شيلت واحدة من + +142 +00:12:25,940 --> 00:12:30,820 +الهيدروجينات و بدلتها بمثل يعني عملت هيك C double + +143 +00:12:30,820 --> 00:12:38,420 +bond OH و هذه N خليت عليها هيدروجين و الهيدروجين + +144 +00:12:38,420 --> 00:12:41,320 +التاني ايه شو خليتها CH3 + +145 +00:12:46,710 --> 00:12:51,830 +هذا امد جاي من ال form امد لكن هذا form امد صار + +146 +00:12:51,830 --> 00:12:58,870 +بيحمل ايش مثل اذا بسمي انا مثل form امد لاحظوا + +147 +00:12:58,870 --> 00:13:05,390 +form امد ال primary لان لما حمل مثل واحدة ايش صار + +148 +00:13:05,390 --> 00:13:13,610 +مثل form امد اللي هو secondary امدالآن، لو بعدك + +149 +00:13:13,610 --> 00:13:18,290 +حملتوا مثل مجموعات، فهي تصبح دائمة في الـ + +150 +00:13:18,290 --> 00:13:22,980 +Formamentواضح؟ إذا ممكن يكون form amide بدون ولا + +151 +00:13:22,980 --> 00:13:28,160 +مثل بمثل واحدة مثل form amide ب two methyl groups + +152 +00:13:28,160 --> 00:13:33,660 +ضاي مثل form amide الان لأن هالمثل بتحمل على ال + +153 +00:13:33,660 --> 00:13:39,640 +nitrogen مرات بيضيفوا و مرات لأ الحرف capital N + +154 +00:13:39,640 --> 00:13:43,980 +يعني هنا بيكتبوا أن مثل form amide إيش معناها؟ + +155 +00:13:43,980 --> 00:13:47,880 +معناها أن المثل محمول على ذرة ال nitrogen هاي + +156 +00:13:47,880 --> 00:13:53,630 +معناه أنواضح؟ طبعا هذا اللي فيه مجموعتين مثل على + +157 +00:13:53,630 --> 00:13:59,210 +ذرة النيتروجين شو هسميه؟ N فاصلة N + +158 +00:13:59,210 --> 00:14:03,570 +-dimethylformamide يعني المثل الأولى والمثل + +159 +00:14:03,570 --> 00:14:08,010 +التانية محمولات على ذرة إيش؟ النيتروجين الآن + +160 +00:14:08,010 --> 00:14:12,170 +لاحظوا كيف التدرج ال primary amyl formamide ال + +161 +00:14:12,170 --> 00:14:16,800 +secondary مثلا المثل formamide ال tertiaryالداي + +162 +00:14:16,800 --> 00:14:22,500 +مثل فورماميل، مين بنتوقعه أعلى boiling point + +163 +00:14:22,500 --> 00:14:28,400 +لبرايماري، لاحظوا ال boiling point تبعته 210، الآن + +164 +00:14:28,400 --> 00:14:33,960 +مين أقل boiling point؟ ال boiling point تبعته 153 + +165 +00:14:35,590 --> 00:14:39,390 +ال secondary where بيجي؟ في النص حيجي حوالي مية و + +166 +00:14:39,390 --> 00:14:43,190 +سبعين، مية و تمانين، شغل زي هيك، شفتوا التدرج؟ + +167 +00:14:43,190 --> 00:14:46,730 +ميتين و عشرة، مية و سبعين، مية و تمانين، مية و + +168 +00:14:46,730 --> 00:14:50,290 +تلاتة و خمسين، ال primary؟ بتنين هيدروجين بولنج، + +169 +00:14:50,290 --> 00:14:53,570 +ال secondary one؟ تير شر بدون هيدروجين بولنج، + +170 +00:14:53,570 --> 00:14:58,000 +واضحة؟نفس الاشي مثلا هذا ال acetamide ال primary + +171 +00:14:58,000 --> 00:15:01,540 +ال di-methyl acetamide او ال un-di-methyl + +172 +00:15:01,540 --> 00:15:06,300 +acetamide ال tertiary مش رسمي هنا ال secondary هذا + +173 +00:15:06,300 --> 00:15:11,020 +ال primary مائتين و اتنين و عشرين الآن ال tertiary + +174 +00:15:11,020 --> 00:15:15,060 +مائة و خمس و ستين ال primary اعلى من ال tertiary + +175 +00:15:15,060 --> 00:15:22,190 +لأنه فيه تنتين هيدروجين bonded واضح؟طبعا لو أنا + +176 +00:15:22,190 --> 00:15:28,510 +إجيت سألكم أسئلة لو إجيت سألكوا أسئلة ليش ال + +177 +00:15:28,510 --> 00:15:32,830 +formament أعلى من ال diameter ال formament because + +178 +00:15:32,830 --> 00:15:40,970 +it can formتو هيدروجين بوندين لإيش الاسيتاميد أعلى + +179 +00:15:40,970 --> 00:15:45,010 +من الديمثلاسيتاميد because it can form hydrogen + +180 +00:15:45,010 --> 00:15:50,670 +bonding الآن لو إجيت عملت سؤال مقارنة قلتلكم ال + +181 +00:15:50,670 --> 00:16:00,130 +form أمد والاسيت أمد هذا 222 هذا 210 مين الأعلى؟ + +182 +00:16:00,130 --> 00:16:08,030 +وليش؟طبعا الأعلى الأسئ تمت 222 أعلى من 210 + +183 +00:16:10,530 --> 00:16:15,330 +أه الآن هنا في عندي اشتراك في الـ hydrogen bonding + +184 +00:16:15,330 --> 00:16:19,450 +هنا في عندي two hydrogen bonding و هنا في عندي two + +185 +00:16:19,450 --> 00:16:23,810 +hydrogen bonding بطل ال hydrogen bonding هو الحكم + +186 +00:16:23,810 --> 00:16:28,990 +أصبحت الصيغة الجزائية هي الحكم أن هذا أكبر من هذا + +187 +00:16:28,990 --> 00:16:32,870 +و كل ما ارتفعنا احنا بالصيغة الجزائية مع توحيد + +188 +00:16:32,870 --> 00:16:37,120 +الصفات التانية كل ما بتزيد ايش ال boiling pointزي + +189 +00:16:37,120 --> 00:16:42,320 +لما كنا نحكي الكينز كلهم مافيهم bonding كنا نقول + +190 +00:16:42,320 --> 00:16:48,680 +الميثين أقل واحد لما يصير إيثين بيرتفع البروبين + +191 +00:16:48,680 --> 00:16:53,980 +بيرتفع البيوتين بيرتفع كذلك الأحماض مثلا ال formic + +192 +00:16:53,980 --> 00:16:59,980 +acid أقل حامل بعده ال acetic acid بعده ال borbenic + +193 +00:16:59,980 --> 00:17:03,520 +acid هدول كلهم مشتركين بال hydrogen bonding كلهم + +194 +00:17:03,520 --> 00:17:08,170 +نفس العيلة إيش الإختلاف إذا اللي بينهم؟بصيغة + +195 +00:17:08,170 --> 00:17:12,670 +جزيئية فهدولة بنسميهم أفراد من ال homologous + +196 +00:17:12,670 --> 00:17:16,710 +series اللي هي السلسلة المتتالية من نفس العيلة في + +197 +00:17:16,710 --> 00:17:20,530 +الكحولات كلهم فيهم hydrogel bonding فكل ما زاد ال + +198 +00:17:20,530 --> 00:17:23,190 +molecular weight بتزيد ال boiling point في الأحمض + +199 +00:17:23,190 --> 00:17:27,870 +نفس الاشياء الآن في ال amides بس بشرط لما أعمل + +200 +00:17:27,870 --> 00:17:33,490 +المقارنة إذا بقارن أقارن primary مع primary أو + +201 +00:17:33,490 --> 00:17:38,300 +مثلاTertiary مع tertiary لاحظوا التيرتشاري هنا + +202 +00:17:38,300 --> 00:17:42,300 +مافيش فيه hydrogen bonding 165 التيرتشاري هنا + +203 +00:17:42,300 --> 00:17:47,620 +مافيه hydrogen bonding 153 إذا ماسبب الفرق بال + +204 +00:17:47,620 --> 00:17:50,220 +molecular weight واضحة الفكرة؟ + +205 +00:18:00,170 --> 00:18:04,390 +طبعا تحضير ال amides مفهوم اللي هو ال ammonia او + +206 +00:18:04,390 --> 00:18:08,870 +مشتقاتها يعني ال ammonia لما بيفعلها مع الحامض + +207 +00:18:08,870 --> 00:18:15,510 +بتعطيني اي amide ل primary الان لو كان هنا NH2R + +208 +00:18:15,510 --> 00:18:20,410 +هيعطيني اي amide secondary لانه يحمل R واحدة لو + +209 +00:18:20,410 --> 00:18:22,490 +كان NHR2 + +210 +00:18:25,290 --> 00:18:29,190 +فلا بد إلا يكون عنده أقل تقدير H ممكن يكونوا تلاتة + +211 +00:18:29,190 --> 00:18:31,870 +ممكن يكونوا تنتين ممكن يكونوا واحدة وباقى + +212 +00:18:31,870 --> 00:18:35,410 +المجموعات R فبصير بإمكان أحضر ال primary secondary + +213 +00:18:35,410 --> 00:18:39,990 +tertiary ال primary بحضره من إيش؟ من ال ammonia ال + +214 +00:18:39,990 --> 00:18:46,830 +primary من ال ammonia الآن ال amides علشان يريحون + +215 +00:18:46,830 --> 00:18:54,810 +فيهم ميزة جميلةبنسميها الامد resonance وهذه بتأثر + +216 +00:18:54,810 --> 00:19:01,210 +على reactivity of الامد الامد نفسه مكوّن من جزئين + +217 +00:19:01,210 --> 00:19:06,830 +مكوّن من سيظة بال bond O اللي هي كربونيلي جروب + +218 +00:19:06,830 --> 00:19:15,120 +ومكوّن من ال NH2 الامين صح ولا لأ؟ امينو Carbonyl + +219 +00:19:15,120 --> 00:19:20,340 +C double bond O الان لاحظوا معايا كل واحدة منهم + +220 +00:19:20,340 --> 00:19:26,580 +منفردة very reactive يعني ال Carbonyl group لوحدها + +221 +00:19:26,580 --> 00:19:31,520 +very reactive و احنا قلنا تقريبا تلت اسابيع اربعة + +222 +00:19:31,520 --> 00:19:34,900 +بس بندرس ال Carbonyl groups ال C double bond O في + +223 +00:19:34,900 --> 00:19:37,600 +ال aldehydes في ال ketones في ال acids في ال E + +224 +00:19:37,600 --> 00:19:42,610 +stars very reactive واضح؟والـ Nitrogen لواحدة الـ + +225 +00:19:42,610 --> 00:19:48,870 +NH2 و الـ NH8 برضه very reactive و هندرس عليها + +226 +00:19:48,870 --> 00:19:55,510 +شبتر 11 فالـ C double bond O very reactive و درسنا + +227 +00:19:55,510 --> 00:19:57,990 +عليها شبتر ال aldehydes و ال ketones و ال acids + +228 +00:19:57,990 --> 00:20:00,990 +شبتر 9 و 10 كله مع ال C double bond O من كتر مية + +229 +00:20:00,990 --> 00:20:06,470 +reactive الـ NH very reactive ندرس عليها شبتر 11 + +230 +00:20:06,470 --> 00:20:13,290 +ال amines الآن يوم ما بنحطالـ c double point o ال + +231 +00:20:13,290 --> 00:20:19,710 +very reactive مع ال n h ال very reactive بنحصل + +232 +00:20:19,710 --> 00:20:24,250 +منهم على very + +233 +00:20:24,250 --> 00:20:31,490 +very reactive ولا إيش رأيكم؟ بنحصل منهم على + +234 +00:20:31,490 --> 00:20:36,970 +unreactive بنحصل + +235 +00:20:36,970 --> 00:20:39,610 +منهم على unreactive + +236 +00:20:41,050 --> 00:20:48,450 +الـ A يمكن تستغربه كيف ال reactive و ال reactive + +237 +00:20:48,450 --> 00:20:50,130 +بيعطوا + +238 +00:20:51,590 --> 00:20:58,010 +unreactive لكن اللي بيفهم الدنيا بيقدر يفهم هذا + +239 +00:20:58,010 --> 00:21:01,790 +الأمر جيدا اللي بيفهم الدنيا بيقدر يفهم هذا الأمر + +240 +00:21:01,790 --> 00:21:08,590 +جيدا ال reactivity ال reactivity معناها تفاعل مع + +241 +00:21:08,590 --> 00:21:14,540 +الخارج ال reactivity تفاعل مع الخارج تماميعني + +242 +00:21:14,540 --> 00:21:20,100 +الأمة العربية .. الأمة العربية كان ممكن تكون + +243 +00:21:20,100 --> 00:21:27,210 +reactive بس بشرط reactive ضد مينضد أعداءها الأمة + +244 +00:21:27,210 --> 00:21:30,730 +العربية ممكن تكون reactive و very reactive ضد + +245 +00:21:30,730 --> 00:21:35,810 +أعداءها اليوم لما صارت الأمة العربية في كل دولة + +246 +00:21:35,810 --> 00:21:40,390 +فيها و ما بين الدول بعد هيك في كل دولة في شق + +247 +00:21:40,390 --> 00:21:45,550 +reactive و شق reactive هدول الشقين طبق تالف بعض + +248 +00:21:45,550 --> 00:21:53,710 +كيف صفيه مع الخارج? unreactive يعني في اليمنجدّاش + +249 +00:21:53,710 --> 00:21:57,550 +بتجتلوا في بعض هو هذا الاقتلا والجبال الإسرائيل + +250 +00:21:57,550 --> 00:22:02,290 +ماجدرتش عليهم بس المشكلة ان ال reactivity مش مع + +251 +00:22:02,290 --> 00:22:08,950 +الخارج reactivity ايش داخلية فما بالكوا لما نجيبها + +252 +00:22:08,950 --> 00:22:15,410 +ايديك ايش نقول اليمن و السعودية تبقوا معاه هنا في + +253 +00:22:15,410 --> 00:22:18,510 +reactivity و هنا في reactivity ايش هت مع بعض دمرت + +254 +00:22:18,510 --> 00:22:24,610 +بعض طب مع الخارجضد الأعداء الحقيقيين، إيش بنصفة؟ + +255 +00:22:24,610 --> 00:22:29,650 +Unreactive ولذلك لما جمعنا هنا ال reactive و ال + +256 +00:22:29,650 --> 00:22:35,350 +reactive صاروا إيش؟ يتقاتلوا مع بعض فمع الخارج + +257 +00:22:35,350 --> 00:22:41,230 +بطلوا reactive الآن هذا الكلام بدنا نفهمه أكتر من + +258 +00:22:41,230 --> 00:22:47,910 +ناحية إيش؟ الكيميا بدنا نقول وين سر قوة شمشوم + +259 +00:22:47,910 --> 00:22:53,530 +الجبارعارفينه شمشوم الجباب؟ اللي في الأسطورة بطل + +260 +00:22:53,530 --> 00:23:00,670 +غزة اللي كان سر قوته في شعره و لما اكتشفوا سر قوته + +261 +00:23:00,670 --> 00:23:06,230 +بيكسر المباني و بيعمل .. حلقوله شعره راح فقد قوته، + +262 +00:23:06,230 --> 00:23:10,470 +تمام؟ الآن لو اجينا على ال الديهيد و الكيتون، وين + +263 +00:23:10,470 --> 00:23:15,530 +سر قوتهم اللي لنا تلت أسابيع نشتغل عليه؟ الكربون + +264 +00:23:15,530 --> 00:23:16,770 +المجاباة + +265 +00:23:18,720 --> 00:23:22,220 +الـ Carbon الموجبة مشغول من التفاعلات الـ + +266 +00:23:22,220 --> 00:23:25,220 +Eucleophilic Addition أو Substitution، الـ + +267 +00:23:25,220 --> 00:23:28,980 +Eucleophile إجراء بيجي وين؟ على الـ Carbon + +268 +00:23:28,980 --> 00:23:34,440 +الموجبة، هاي سر قوتهم، وعشان يقم لما ييجي الـ + +269 +00:23:34,440 --> 00:23:39,490 +Eucleophile من الخارجيحمل أزواج إلكتروناتي جراي + +270 +00:23:39,490 --> 00:23:43,550 +بيجي بتفعل معاهم صاروا reactive معاه ولا لأ؟ صاروا + +271 +00:23:43,550 --> 00:23:51,130 +reactive طيب لو أجينا للـ nitrogen وين سر قوتها؟ + +272 +00:23:51,130 --> 00:23:55,950 +زوج الإلكترونات هنا + +273 +00:23:55,950 --> 00:24:02,920 +في عندي على ال nitrogen زوج إلكتروناتهذا سير قوتها + +274 +00:24:02,920 --> 00:24:07,940 +أول ما بيلاقي أي موجة بجزئه بروح بتفاعل معاه ولا + +275 +00:24:07,940 --> 00:24:12,600 +لأ هاي سير قوة ال nitrogen زوج الإلكترونات يعني + +276 +00:24:12,600 --> 00:24:20,480 +مثلا أذكر لما كنا نقول فعله المركبين القاتين RNH2 + +277 +00:24:20,480 --> 00:24:26,620 +زائد CH3 نكتبها زي هيك + +278 +00:24:37,980 --> 00:24:45,440 +النيتروجين عليها زوج إلكتروناتصح و ال carbon و + +279 +00:24:45,440 --> 00:24:50,320 +اليود مين فيهم موجب و مين سالب ال carbon الموجبة + +280 +00:24:50,320 --> 00:24:55,280 +ال a التفاعل موجب مع سالب إجراء هذا زوج + +281 +00:24:55,280 --> 00:24:59,620 +الإلكترونات بييجي بيهاجمها و بيطرد اليود صار سر + +282 +00:24:59,620 --> 00:25:05,240 +عندك CH3 NHR + +283 +00:25:05,240 --> 00:25:13,880 +مظبوط ولا لأ فهي سر القوةزوج الالكترونات هذا سير + +284 +00:25:13,880 --> 00:25:18,200 +قوته الموجب الموجب مع السالب هاي التفاعلات هاي + +285 +00:25:18,200 --> 00:25:23,760 +الكيميا موجب وسالب واضح فالان النيتروجين سير قوته + +286 +00:25:23,760 --> 00:25:27,860 +السالب او زوج الالكترونات والكربون سير قوته الموجب + +287 +00:25:27,860 --> 00:25:35,790 +لما قعدوا في نفس الجزءبدل ما يروحوا يتفاعلوا ال + +288 +00:25:35,790 --> 00:25:40,330 +nitrogen برا يكون reactive برا وال carbon برا يكون + +289 +00:25:40,330 --> 00:25:45,050 +reactive برا قال انت سالب شو بدك؟ وانت موجب شو + +290 +00:25:45,050 --> 00:25:52,320 +بدك؟ طب هيوموجودين جانب بعض بناء على ذلك إجراء هذا + +291 +00:25:52,320 --> 00:25:57,760 +السالب إجا قالوا هاي المجاب شو بدك؟ قالوا أنا + +292 +00:25:57,760 --> 00:26:03,160 +السالب اتفضل أعطاه الإلكترونات تبعه طبعا معقول إنه + +293 +00:26:03,160 --> 00:26:08,160 +هنا يصير في عندي خمس روابط على الكربون على طول هذه + +294 +00:26:08,160 --> 00:26:13,740 +إيش هتصير؟ تلوف الإلكترونات تصير O minus صار بهذا + +295 +00:26:13,740 --> 00:26:18,830 +الشكل الرزوناسيالان اتطلعوا على هذا الجزء هل + +296 +00:26:18,830 --> 00:26:24,250 +ياترال كاربول ضال عليها موجب؟ هل ال نيتروجين ضال + +297 +00:26:24,250 --> 00:26:29,250 +عليها زوج إلكترونات؟ راحوا القوتين ولذلك بيصف + +298 +00:26:29,250 --> 00:26:34,750 +القامد او ال reactif لأنه اتفاعل مع نفسه يعني زي + +299 +00:26:34,750 --> 00:26:38,410 +اللي في داخل الأمة جاتلوا مع بعض قدام الناس إيش + +300 +00:26:38,410 --> 00:26:44,710 +بيطلعوا؟ ولا إشيقدام الغروب، شو بيطلعوا؟ ولا إشي، + +301 +00:26:44,710 --> 00:26:48,630 +هم خلاص اتفاعلوا مع بعضهم، اتقاتلوا مع بعضهم، + +302 +00:26:48,630 --> 00:26:54,070 +واضحة الفكرة؟ ولذلك السبب إن الامد unreactive هو + +303 +00:26:54,070 --> 00:26:59,230 +إيش؟ الامد resonance، لا ضال هذا السالب سالب ولا + +304 +00:26:59,230 --> 00:27:04,250 +ضال هذا الموجب موجبفسر القوة للتانين انتهى، راحوا، + +305 +00:27:04,250 --> 00:27:08,770 +بطلوا، سالب و موجب، الآن خليني أسأل عادي السؤال من + +306 +00:27:08,770 --> 00:27:14,910 +زاوية تانية، هل يترى الأمد لما بيكون unreactive؟ + +307 +00:27:14,910 --> 00:27:20,490 +يعتبر الأمر شيء إيجابي ولا شيء سلبي؟ + +308 +00:27:22,790 --> 00:27:29,350 +أحنا اتفقنا القامت unreactive هل يعتبر سلبي ولا + +309 +00:27:29,350 --> 00:27:36,410 +إيجابي؟ فينا زملائكوا بيقولوا كل شيء زي السكينة + +310 +00:27:36,410 --> 00:27:43,570 +ممكن تكون كويسة وممكن تكون مش كويسة حسب الاستخدام + +311 +00:27:43,570 --> 00:27:49,430 +زي ال internetممكن يكون مفيد، ممكن يكون إيش، بقى + +312 +00:27:49,430 --> 00:27:54,330 +حسب الاستخدام، يعني على سبيل المثال النيلون + +313 +00:27:56,280 --> 00:28:01,240 +عبارة عن أمد، هنشوف كيف بتحضر، بس الآن أقل تقدير + +314 +00:28:01,240 --> 00:28:06,620 +نعرف إن النيلون إيش أمد، وبناء على ذلك النيلون + +315 +00:28:06,620 --> 00:28:11,760 +reactive ولا unreactive؟ النيلون unreactive، الآن + +316 +00:28:11,760 --> 00:28:15,260 +كون النيلون unreactive، هذا الأمر يعتبر موجب ولا + +317 +00:28:15,260 --> 00:28:22,900 +ثاني؟يحتمل الأمرين، يعني لما النيلون بيكون عبارة + +318 +00:28:22,900 --> 00:28:27,900 +عن قمامة و بدنا نتخلص منها لو دفنناها أو ما إلى + +319 +00:28:27,900 --> 00:28:33,540 +ذلك، بتتحلل ولا بتظل زي ما هي بالأرض؟ بتظل زي ما + +320 +00:28:33,540 --> 00:28:38,320 +هي بالأرض، مابتتحللشخدوا مثلا فضلات النبات غير + +321 +00:28:38,320 --> 00:28:41,500 +غيرها، ادفنوها في الأرض، بتتحللوا، بتروح، ادفنوا + +322 +00:28:41,500 --> 00:28:45,180 +نيلون في الأرض، بتتحللش، وبناء على ذلك، كونوا + +323 +00:28:45,180 --> 00:28:49,040 +الـnylon unreactive من هذه الزاوية، من زاوية + +324 +00:28:49,040 --> 00:28:56,590 +كفضلاتيعتبر الأمر غير جيد، يعتبر الأمر سلبي، لكن + +325 +00:28:56,590 --> 00:29:01,530 +نفس النيلون هذا، نفس النيلون هذا، لو أنا كنت بدي + +326 +00:29:01,530 --> 00:29:06,890 +فعلا يظل في الرمل وما يخربش، يعني على سبيل المثال، + +327 +00:29:06,890 --> 00:29:11,910 +الحمامات الزراعية مش بيعملوها بنيلون، النيلون هذا + +328 +00:29:11,910 --> 00:29:17,750 +تحت، بطم فوقه رمل ولا لأ؟بعد شهر، شهرين، تلاتة، + +329 +00:29:17,750 --> 00:29:22,170 +أربعة، بدوب النيلون ولا بيظله موجود؟ اتخيل لو هذا + +330 +00:29:22,170 --> 00:29:29,670 +كان ورق، ورق وحطينا فوقه رمل، رمل وميه، بعد كدهش + +331 +00:29:29,670 --> 00:29:36,030 +بنتهي؟ بعد ساعة، النيلون الآن أنا بديه يظلهلما + +332 +00:29:36,030 --> 00:29:39,510 +ظلوا بهذا الشكل وكانوا unreactive، كان يعتبر أمر + +333 +00:29:39,510 --> 00:29:43,950 +إيش؟ إيجابي بالنسبة لي، ولذلك مثلا لما بيعملوا + +334 +00:29:43,950 --> 00:29:49,400 +كوابل الكهربا مدفونة في الأرضبيجوا فوق الكابل بنص + +335 +00:29:49,400 --> 00:29:52,880 +متر، يعني افترض الكابل مدفون على عمق متر، فوق + +336 +00:29:52,880 --> 00:29:56,860 +الكابل بنص متر، بيجيبوا شريط نايلون و بيحطوه في + +337 +00:29:56,860 --> 00:30:01,200 +الأرض، هذا الشريط مكتوب عليه احذر خطر الكهرباء، + +338 +00:30:01,200 --> 00:30:05,540 +احذر خطر الكهرباء، ليش؟ لو اجوا ناس يجرفوا، بعد + +339 +00:30:05,540 --> 00:30:09,680 +شوية الجرفة تخبط في كابل كهربا مدفون في الأرضبناء + +340 +00:30:09,680 --> 00:30:13,620 +على ذلك بيحطولهم نايلون أصفر و مكتوب عليه شريط فوق + +341 +00:30:13,620 --> 00:30:17,560 +الكابل احذر على عمق متر فيه عندك قطر كربا هذا + +342 +00:30:17,560 --> 00:30:23,210 +بيقعد عشر خمس عشر سنة وأكترالان هذا استعمال إيجابى + +343 +00:30:23,210 --> 00:30:27,970 +ولا سلبى لل unreactivity تبعته استعمال إيجابى + +344 +00:30:27,970 --> 00:30:32,470 +ففكرة ال unreactivity أو ال reactivity يمكن ان + +345 +00:30:32,470 --> 00:30:38,030 +ينظر إليها من زاويتين و كذلك ال nylon لما بقول عنه + +346 +00:30:38,030 --> 00:30:42,050 +عبارة عن أمد و unreactive مرات انا بدي اكون + +347 +00:30:42,050 --> 00:30:45,850 +unreactive باستفيد من كونه unreactive ان ال nylon + +348 +00:30:45,850 --> 00:30:50,450 +مابخربش و بحمل فيه الغرابو عند اللزوم اليوم اللي + +349 +00:30:50,450 --> 00:30:55,970 +بيشتريوا الأشتال الصغيرة كلها محطوطة بإيش؟ بكياس + +350 +00:30:55,970 --> 00:31:00,650 +نيلون ولا بكياس ورق؟الان هذا استعمال إيجابي ولا + +351 +00:31:00,650 --> 00:31:04,670 +سلبي؟ استعمال إيجابي، انه unreactive، انه ماخربش + +352 +00:31:04,670 --> 00:31:09,350 +من الميه والحرارة، واضح؟ لكن أنا لما بحط قمامة و + +353 +00:31:09,350 --> 00:31:12,690 +بدي أدفنها و بديها تتحول إلى سماد عضوى، و أجي + +354 +00:31:12,690 --> 00:31:16,390 +ألاقي النيلول زي ما هو، و أبدأ أضطر أروح أحرجه و + +355 +00:31:16,390 --> 00:31:20,970 +أطلع منه مواد ضارة، و أجي تبكي و أروح اتعلق؟السلبي + +356 +00:31:20,970 --> 00:31:25,290 +من أن الامد إيش ماله؟ Unreactive فهمنا إذا فكرة ال + +357 +00:31:25,290 --> 00:31:29,190 +reactivity of امد في كل الأحوال لما احنا بنقول إشي + +358 +00:31:29,190 --> 00:31:34,690 +unreactive مش معناه صيرنا جايبين سيرة النيلون شو + +359 +00:31:34,690 --> 00:31:40,110 +هو النيلون؟ النيلون عبارة عن امد بوليمر بسيط جدا + +360 +00:31:40,110 --> 00:31:47,680 +بحط هذا المركب اللي فيه C double bond OCLو ست + +361 +00:31:47,680 --> 00:31:53,040 +كربونات يعني كربون تنتين تلاتة أربعة خمسة ستة الان + +362 +00:31:53,040 --> 00:31:57,840 +هذا أصلا حامض داي أسد من ست كربونات بتذكرين قولنا + +363 +00:31:57,840 --> 00:32:02,680 +إيش اسمه اديبك أسد المرة الماضية الحمض اللي هو + +364 +00:32:02,680 --> 00:32:07,250 +الدي أسد من ست كربونات لو فعلنا معك لوربدو يصير + +365 +00:32:07,250 --> 00:32:10,810 +أديبويل كلورايد زي ما قولنا المرة الماضية + +366 +00:32:10,810 --> 00:32:15,010 +بروبانويل كلورايد وكذا كذا كذا الآن هي أديبويل + +367 +00:32:15,010 --> 00:32:19,710 +كلورايد يمين و أديبويل كلورايد الشمال بجيب أمين + +368 +00:32:19,710 --> 00:32:27,210 +NH2 6 كربونات و كمان NH2 لما أعمل تفاعل بينهم ال + +369 +00:32:27,210 --> 00:32:35,210 +nitrogen هذا ايش بدي اعمل احل محلالكلور هيعمل عندى + +370 +00:32:35,210 --> 00:32:43,770 +C double bond O and H واضح الفكرة و هكذا و من هنا + +371 +00:32:43,770 --> 00:32:47,670 +هيصير عندى كمان C double bond O and H هيصير عندى + +372 +00:32:47,670 --> 00:32:50,610 +polymer يعني هى ست كربونات جايين من الادبويل + +373 +00:32:50,610 --> 00:32:55,640 +الكلوراي ستة جايين من إيش؟من الداي أمين الأمين من + +374 +00:32:55,640 --> 00:32:58,640 +الجهتين والأدي بويل الكلورايد من الجهتين بيظلوا + +375 +00:32:58,640 --> 00:33:03,300 +ميشبكوا مع بعض ولا لأ عملوا معي بوليمر الآن هذا + +376 +00:33:03,300 --> 00:33:08,620 +البوليمر موصول من وين من خلال رابطة أمد لإن عندي + +377 +00:33:08,620 --> 00:33:15,480 +ال C double bond O and H لاحظوا هنا كام كربونا ستة + +378 +00:33:16,560 --> 00:33:21,040 +مع ال سيطة بالبوند او التنتين و CH2 الستة و هنا كم + +379 +00:33:21,040 --> 00:33:26,500 +كربونا غير ال نيتروجين اذا انا عندى رابطة الامد و + +380 +00:33:26,500 --> 00:33:34,960 +ست كربونات و بعدين رابطة امد تانية و ست كربونات و + +381 +00:33:34,960 --> 00:33:41,020 +هلما طالما ستة امد ستة امد ستة امد ستة امد هذا + +382 +00:33:41,020 --> 00:33:46,610 +النيلون ايش هنسميه في هذه الحالةنيلون بوليمر طبعا + +383 +00:33:46,610 --> 00:33:56,050 +بيسموه نيلون 6 6 لأن هنا 6 كربونات أمد و 6 كربونات + +384 +00:33:56,050 --> 00:34:01,740 +من الأمينستة من الاديبويل الكلورايت و ستة من + +385 +00:34:01,740 --> 00:34:06,540 +الأمين و بينهم رابطة ايش امل فنيلون سيكس سيكس الان + +386 +00:34:06,540 --> 00:34:10,180 +بيصير السؤال لو يا ترى استعملوا الأمين ب تمان + +387 +00:34:10,180 --> 00:34:17,150 +كربونات ايش هيصير النيلون six eightلأ مش الانتين + +388 +00:34:17,150 --> 00:34:22,530 +استعملهم تمانية خلوا هذا ستة و هدول تمانية ممكن + +389 +00:34:22,530 --> 00:34:27,470 +نعمل زي هيك و بناء على ذلك النيلون نفسه بيصير مصنف + +390 +00:34:27,470 --> 00:34:33,410 +six six ممكن six eight ممكن six ten ممكن واضح؟ و + +391 +00:34:33,410 --> 00:34:37,650 +هذا بيعمل اللي هي الأنواع المختلفة في النيلون من + +392 +00:34:37,650 --> 00:34:42,310 +ناحية القوام والشكل والصلابة لكن أشهر نيلون الأبيض + +393 +00:34:42,310 --> 00:34:47,270 +الشفافة اللي بنعرفه هو نيلون إيش؟6 6 6 ذرات من + +394 +00:34:47,270 --> 00:34:51,710 +الاديبويل الكلورايد و 6 من الأمين و عامل بوليمار + +395 +00:34:51,710 --> 00:34:58,350 +واضح الفكرة هذا هو النيلون + +396 +00:34:58,350 --> 00:35:02,310 +الان + +397 +00:35:02,310 --> 00:35:07,870 +مش معناه ان الامد غير مفاعل انه مابتفعلش ولا تفاعل + +398 +00:35:07,870 --> 00:35:16,500 +لأ انه تفاعلين خفاف التفاعل الأول ان الامدمع الميه + +399 +00:35:16,500 --> 00:35:21,720 +والحامض او القاعدة بتسخين لفترة طويلة لحظو انا ايش + +400 +00:35:21,720 --> 00:35:26,600 +انا كاتب Prolonged heating يعني ممكن يومين تلاتة + +401 +00:35:26,600 --> 00:35:32,720 +اظلني اسخن فيه بتسخين لفترة طويلة بينكسر وبرجع + +402 +00:35:32,720 --> 00:35:37,020 +للحامض اذا القامد ممكن ال O-H تهاجم عليه ويراجع + +403 +00:35:37,020 --> 00:35:43,030 +للحامض بس بشرطإن أسخنه مع حمض أو قاعدة و لفترة + +404 +00:35:43,030 --> 00:35:48,750 +طويلة جدا هذا التفاعل عادة بيصير وين لما نعمل + +405 +00:35:48,750 --> 00:35:54,370 +تحليل للبروتينات لأن البروتينات عبارة عن amides + +406 +00:35:54,370 --> 00:35:58,010 +فلما ابتدي أحليل ال amino acids تبعونهم بجيب + +407 +00:35:58,010 --> 00:36:02,390 +اللحمة أو البروتين و بحطه و بضلني أغليه يوم يومين + +408 +00:36:02,390 --> 00:36:07,570 +لحد ما فكفك الوحدات تبعته واضح؟ في البروتين + +409 +00:36:07,570 --> 00:36:13,090 +analysis هيمر معكمالتفاعل التاني للأمد ان انا ممكن + +410 +00:36:13,090 --> 00:36:17,530 +اعمله reduction الأمد لما بعمله reduction بليثيوم + +411 +00:36:17,530 --> 00:36:22,390 +ألومنوم هيدرايك ببساطة كبيرة جدا السيطة بال bond O + +412 +00:36:22,390 --> 00:36:25,870 +تبعت الأمد هتصير CH2 + +413 +00:36:28,130 --> 00:36:33,790 +واضح؟ فإذا كان عندى R C double bond O NH2 بتصير R + +414 +00:36:33,790 --> 00:36:40,310 +CH2 NH2، بهذه الحالة الأمد أصبح عبارة عن إيش؟ + +415 +00:36:40,310 --> 00:36:46,370 +أمين، هذه هتصير طريقة لتحضير الأمين، اللي هي موضوع + +416 +00:36:46,370 --> 00:36:54,010 +شبطريح دعش، يعني لما نيجي نقول تحضير الأمينبالـ + +417 +00:36:54,010 --> 00:36:58,530 +reduction of amides شبيه بهذا التفاعل عشان تعملوا + +418 +00:36:58,530 --> 00:37:04,510 +المقارنة انه كان ال Easter ال R سيضا بالبند OOR + +419 +00:37:04,510 --> 00:37:08,410 +بالليثيام ألومنوم هيدرايد بال reduction شو كان + +420 +00:37:08,410 --> 00:37:16,170 +يعطيني ال primary alcohol كان يعطيني RCH2OH لاحظوا + +421 +00:37:16,170 --> 00:37:21,370 +المعادلتين هدولةبيشيوا ببعض و لازم نكون عارفينهم + +422 +00:37:21,370 --> 00:37:27,110 +ال reduction of amide produces primary amines ال + +423 +00:37:27,110 --> 00:37:32,790 +reduction of ester produces primary alcohols ال C + +424 +00:37:32,790 --> 00:37:37,880 +double bond O في الحالتين إيش بتصيب؟CH2 هدى طبعا + +425 +00:37:37,880 --> 00:37:41,940 +ال OR بتصير OH وهنا ال NH2 بتظل زى ما هي ف ال + +426 +00:37:41,940 --> 00:37:45,880 +amides بيصيروا primary amines و ال esters بيصيروا + +427 +00:37:45,880 --> 00:37:50,260 +primary alcohol بال reduction دايما اللى بيحفظ + +428 +00:37:50,260 --> 00:37:54,080 +الأشياء يحفظها بالإيش مقارنة reduction of amides و + +429 +00:37:54,080 --> 00:37:58,380 +reduction of esters primary amines و primary + +430 +00:37:58,380 --> 00:38:07,200 +alcoholكما يبدو انه بعد هي قصة طويلة .. بعد هي قصة + +431 +00:38:07,200 --> 00:38:12,500 +طويلة بيصير مستاهل ان الواحد ايش؟ اريح راسه من + +432 +00:38:12,500 --> 00:38:16,060 +الصداع تبع الامدس وغيره وغيراته، الان اللي بده + +433 +00:38:16,060 --> 00:38:21,240 +يريح راسه، ايش بده يعمل؟ بده يشوف أنثلة تطبيقية + +434 +00:38:21,240 --> 00:38:26,520 +على الموضوع، يا بده ياخدله حبة أسبيرين، الأسبيرين + +435 +00:38:26,520 --> 00:38:32,420 +Easteracetosalicylic acid يا حبة إيش لو اتطلعنا + +436 +00:38:32,420 --> 00:38:37,620 +معظمكم معاكم اللي احنا بنسميه الacamol الacamol + +437 +00:38:37,620 --> 00:38:44,060 +هشكله هذا الacamol اللي احنا بنستعمله للصداع و + +438 +00:38:44,060 --> 00:38:50,830 +للسخونة antibiotic إيش معنى antibioticحطوا هنا R + +439 +00:38:50,830 --> 00:38:57,150 +Antipyretic مضاد للسخونة Pyretic حراري مضاد + +440 +00:38:57,150 --> 00:39:04,990 +للحرارة و Analgesic مضاد للصدع او ضد الصدع الان لو + +441 +00:39:04,990 --> 00:39:09,490 +اتيت قلتلكوا ال Acetosalicylic acid is an .. + +442 +00:39:09,490 --> 00:39:13,090 +اتطلعوله على المجموعة الوظيفية الأساسية تبعته E + +443 +00:39:13,090 --> 00:39:15,630 +star الان ال Acamol + +444 +00:39:23,230 --> 00:39:28,290 +الأكمون ممكن تلاقوه باسمين ممكن تلاقوه مكتوب على + +445 +00:39:28,290 --> 00:39:33,310 +علب الأدوية باسمين احد دول الاسمين انه انا لو اتيت + +446 +00:39:33,310 --> 00:39:35,150 +اطلعت هذه المجموعة ايش + +447 +00:39:40,820 --> 00:39:45,280 +فينول وبناء على ذلك ممكن تلاقوه ينكتب تحت عائلة + +448 +00:39:45,280 --> 00:39:54,580 +عامة أسيت أمينوفين لاحظوا أسيت أمينوفين من الأسيتل + +449 +00:39:54,580 --> 00:40:00,980 +والأمينو والفينول أسيت أمينوفين واضحة أسيت + +450 +00:40:00,980 --> 00:40:05,980 +أمينوفين بس اللي منكم اتذكره أكتر دائما على بكية + +451 +00:40:05,980 --> 00:40:11,210 +الأكامول بيكون مكتوب خمسمية ملي جرام إشبراسيتامول + +452 +00:40:11,210 --> 00:40:20,090 +برا سيتامول الان لو اجينا نطبق ال بارا أسيتامول + +453 +00:40:20,090 --> 00:40:28,350 +على نفس شكل الأكامول بارا لأن هدولة جايين بالنسبة + +454 +00:40:28,350 --> 00:40:41,230 +لبعضهم بارا صح ولا لأ أسيت لأن هايالـ Acetamol هى + +455 +00:40:41,230 --> 00:40:52,370 +الأمين وهى الأول بارا + +456 +00:40:52,370 --> 00:40:57,570 +أسيتامول + +457 +00:40:57,570 --> 00:41:03,130 +فبتلاحظوا أن عندكم 500 ميلي جرام براسيتامول بحبة + +458 +00:41:03,130 --> 00:41:09,150 +الدواءواضحة الفكرة براستامول الان لو غيروا فيه + +459 +00:41:09,150 --> 00:41:13,310 +البراستامول ذرة صغيرة بدل ما دي O H صارت O ethyl + +460 +00:41:13,310 --> 00:41:18,610 +بيصير في ناسي تين برضه انا الجسك بيشبه الأكامول + +461 +00:41:18,610 --> 00:41:22,330 +لكن المشهور أكثر الأكامول وإن كان التوصي أن + +462 +00:41:22,330 --> 00:41:26,710 +الأكامول برضه بيغلب مع الكلية التخلص منه يعني بدون + +463 +00:41:26,710 --> 00:41:31,460 +سبب مايكونش كل يوم حبتين أكاموليعني فقط لحالات + +464 +00:41:31,460 --> 00:41:35,460 +الصداع و بإشراف طبي ممكن تتعاملوا معاه أما ناس + +465 +00:41:35,460 --> 00:41:38,360 +يقولوا و الله كل ما بدنا ندروا الصفحتين بدنا ناخد + +466 +00:41:38,360 --> 00:41:42,580 +جماله و نحطين أكامول بيخربوا الكلية تاعتهم واضح؟ + +467 +00:41:42,580 --> 00:41:47,920 +يعني نفس الأكامول أو البراسيتامول ماتاخدهوش بدون + +468 +00:41:47,920 --> 00:41:53,020 +إيش بدون وصفة طبية و بدون لزوم إنما على الحامل على + +469 +00:41:53,020 --> 00:41:55,480 +البارد كل ما بدنا ندروا الصفحة نروح ناخدلنا حبة + +470 +00:41:55,480 --> 00:42:00,700 +أكامول هذه تعتبر مأساةطبعاً في أشياء تانية فرمونات + +471 +00:42:00,700 --> 00:42:04,260 +بنسميها برضه أشياء تطبيقية على ال e-stars و ال + +472 +00:42:04,260 --> 00:42:08,220 +emits بهيك بننهي اليوم و ان شاء الله المرة القادمة + +473 +00:42:08,220 --> 00:42:12,280 +بنبدأ في chapter ال emits + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..f4724512519cfb0d5581d5113ba9777260665efc --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_raw.srt @@ -0,0 +1,1892 @@ +1 +00:00:19,760 --> 00:00:25,420 +بسم الله الرحمن الرحيم نستمر اليوم في موضوع ال + +2 +00:00:25,420 --> 00:00:29,040 +carboxylic acids and their derivatives ربما المرة + +3 +00:00:29,040 --> 00:00:34,360 +الأخيرة اتكلمنا على تحضير ال acid anhydrides + +4 +00:00:34,360 --> 00:00:38,900 +وصنفناهم ل symmetrical anhydride و unsymmetrical + +5 +00:00:38,900 --> 00:00:45,240 +anhydrideبالنسبة لتفاعلاتهم، لا يخرجوا عن الإطار + +6 +00:00:45,240 --> 00:00:48,380 +العام لتفاعلات الأحماض ومشتقاتها، اللي هو + +7 +00:00:48,380 --> 00:00:54,060 +substitution reaction، واضح؟ فعلى سبيل المثال، هذا + +8 +00:00:54,060 --> 00:01:00,550 +الـ anhydrideلو اجينا نفعله مثلا مع الميه الميه + +9 +00:01:00,550 --> 00:01:04,470 +هتكون ال يوكليوفايل ييجي تهاجم هنا و ينكسر من هذا + +10 +00:01:04,470 --> 00:01:09,670 +المكان الان هذا الجزء هيصير acid لو فعلنا مع الميه + +11 +00:01:09,670 --> 00:01:13,330 +و هذا الجزء ايضا هياخد الاتش يصير acid بناء على + +12 +00:01:13,330 --> 00:01:18,450 +ذلك تفاعل الانهيدريد مع الميه بيرجع الى ايش الى + +13 +00:01:18,450 --> 00:01:26,440 +حامضين لو اجينا مثلا نفعل كحولهذا الجزء هيجي عليه + +14 +00:01:26,440 --> 00:01:34,340 +بدل OH في حالة الكحون OR هيصير Easter وهذا بيطلع + +15 +00:01:34,340 --> 00:01:40,220 +على شكل acid لو جينا الفاعل مع ammonia هذا الجزء + +16 +00:01:40,220 --> 00:01:45,870 +هيصير amineان اتش تو مثلا او ان اتش ار هيصير امين + +17 +00:01:45,870 --> 00:01:50,310 +وهذا بيطلع على شكل حامض فزي ما بتلاحظوا انه دائما + +18 +00:01:50,310 --> 00:01:55,650 +في عندى جزء معين بيطلع على شكل حامض وهذا الجزء + +19 +00:01:55,650 --> 00:02:00,910 +اللى هجم عليه النيكليوفايل من الميه لنيكليوفايل OH + +20 +00:02:00,910 --> 00:02:05,550 +من الكحول لنيكليوفايل OR من الأمونيا لنيكليوفايل + +21 +00:02:05,550 --> 00:02:12,930 +NH2 وبالتالي ممكن ارجعلل acid ل ال E star ل الأمد + +22 +00:02:12,930 --> 00:02:18,710 +و هكذا هذا مثال تطبيقي اللي موجود عندنا هنا كيف + +23 +00:02:18,710 --> 00:02:25,210 +نحضر الأسبيرين واضح؟ كيف نحضر الأسبيرين ربما سبق + +24 +00:02:25,210 --> 00:02:29,010 +مار معنا ان احنا بننطلق من ال salicylic acid + +25 +00:02:29,750 --> 00:02:34,110 +الساليسليك أسد اللى هو الحامض ال بنزويك أسد اللى + +26 +00:02:34,110 --> 00:02:40,950 +على موقع ألفا منه OH فهو على موقع أورثو منه OH فهو + +27 +00:02:40,950 --> 00:02:46,430 +أورثو هيدروكسي بنزويك أسد واسمه ساليسليك أسد وزي + +28 +00:02:46,430 --> 00:02:50,970 +ما اتفقنا لازم تكونوا عارفينه سواء قولنا أورثو + +29 +00:02:50,970 --> 00:02:58,920 +هيدروكسي بنزويك أسدهذا ال name ايوبك الان لو بدكم + +30 +00:02:58,920 --> 00:03:03,420 +ال common name تبعه ايش salicylic acid الان هذا + +31 +00:03:03,420 --> 00:03:09,140 +فيه OH اللي هي تعتبر الكهور من ناحية المبدأ هذا ال + +32 +00:03:09,140 --> 00:03:14,040 +OH لما اتهاجل على ال acid anhydride عادة بيفعله مع + +33 +00:03:14,040 --> 00:03:18,900 +ال acetic anhydride فهتكسر + +34 +00:03:18,900 --> 00:03:25,570 +من هنا الحامضزي كل الأمثلة السابقة وهذا الجزء + +35 +00:03:25,570 --> 00:03:30,610 +هييجي اللي هو ممثلا للكحول فكأنه في النهاية اللي + +36 +00:03:30,610 --> 00:03:38,410 +صار عندى Easter حقيقة راحظوا R C double bond O O R + +37 +00:03:38,410 --> 00:03:43,270 +or A R هذا Easter هذا هو ال Aspirin الآن ال + +38 +00:03:43,270 --> 00:03:47,470 +Aspirin عادة بنسميه احنا لأنه حاطينا في هذا + +39 +00:03:47,470 --> 00:03:53,740 +المجموع ال acetinAcetyl Salicylic Acid أو أسيتو + +40 +00:03:53,740 --> 00:03:56,740 +سالي سيليك أسد هذا اللي بياخد اسم الشهراء + +41 +00:03:56,740 --> 00:04:03,080 +الأسبيرين أسيتل أو أسيتو و جزء السالي سيليك أسد + +42 +00:04:03,080 --> 00:04:07,260 +فالأسبيرين أسيتل سالي سيليك أسد فانتوا لما بتقرأوا + +43 +00:04:07,260 --> 00:04:12,800 +على علب الأدويةسواء كان بتركيز خمسمية ميلي جرام + +44 +00:04:12,800 --> 00:04:17,740 +الحبة أو بتركيز المية اللى بيسموها ال baby aspirin + +45 +00:04:17,740 --> 00:04:20,640 +اللى بياخدوها الناس اللى عندهم الجلطات و أحيانا + +46 +00:04:20,640 --> 00:04:25,740 +الان صاروا يصنعوا منها اعتمدوا تركيز واحد و تمانين + +47 +00:04:25,740 --> 00:04:29,300 +لل baby aspirin يعني بدل ما يعملوا ميت ميلي جرام + +48 +00:04:29,300 --> 00:04:32,860 +في ال tablet في الحبة لأ بيعملوها واحد و تمانين + +49 +00:04:33,360 --> 00:04:37,580 +تمام هتقرؤوا واحد و تمانين ميلي جرام او ميت ميلي + +50 +00:04:37,580 --> 00:04:41,620 +جرام Acetyl Salicylic Acid او Acetosalicylic Acid + +51 +00:04:41,620 --> 00:04:46,320 +فمعنى ذلك انه فيها هذا المقدار من دوة الاشه + +52 +00:04:46,320 --> 00:04:56,140 +الاسبريل من دوة الاسبريل بفر + +53 +00:04:56,140 --> 00:04:58,440 +اسبريل بفر اسبريل + +54 +00:05:00,950 --> 00:05:06,170 +لأ هو بس بيحاولوا يخففوا من مشاكل تأثيره على + +55 +00:05:06,170 --> 00:05:10,370 +المعدة من خلال أنه بيكون مخلوط بنظام ال buffer هو + +56 +00:05:10,370 --> 00:05:17,730 +مشكلة الأسبيرين حقيقة أنه الجزء الفعال فيه اللي هو + +57 +00:05:17,730 --> 00:05:22,750 +ال salicylic acid نفسه لكن ال salicylic acid نفسه + +58 +00:05:22,750 --> 00:05:28,170 +يعني شديد على المعدةفبناء على ذلك هم بيحولوا ل + +59 +00:05:28,170 --> 00:05:32,750 +acid ال salicylic acid فلما يمر في المعدة بيمر على + +60 +00:05:32,750 --> 00:05:36,130 +شكل acid ال salicylic acid لما ينزل على القمعة في + +61 +00:05:36,130 --> 00:05:40,570 +الوسط القلوي بتروح تكسر هادي و بيرجع ل salicylic + +62 +00:05:40,570 --> 00:05:45,550 +acidفكل الفكرة و المشاكل اللي يعني مرتبطة في ال + +63 +00:05:45,550 --> 00:05:50,590 +Aspirin هي مشاكل التأثير على المعدة، فلما يعملوا + +64 +00:05:50,590 --> 00:05:54,990 +coated بنظام معين ولا buffer Aspirin، كله على أساس + +65 +00:05:54,990 --> 00:05:58,570 +يخففوا تأثيره على إيش المعدة، بالذات اللي عندهم + +66 +00:05:58,570 --> 00:06:02,780 +يعني قرحة متهيجة، مابقدروش ياخدوا ال Aspirinاللي + +67 +00:06:02,780 --> 00:06:07,840 +عندهم قرحة متهيجة وغلبة عندهم إشكالية إنهم ياخدوا + +68 +00:06:07,840 --> 00:06:11,760 +ال Aspirin فبيحاولوا عاد يعملوا الجرعات الخفيفة + +69 +00:06:11,760 --> 00:06:15,000 +ويعملوه coated مثلا في Aspirin بسموه Aspirin + +70 +00:06:15,000 --> 00:06:21,140 +Cartia، buffer Aspirin، كل هذا لتقليل إيش؟ تأثيره + +71 +00:06:21,140 --> 00:06:22,080 +على المهدة + +72 +00:06:24,930 --> 00:06:30,750 +الجزء الأخير في مشتقات الأحماض ال Amides طبعا سبق + +73 +00:06:30,750 --> 00:06:34,250 +أنه إحنا عرفنا ال Amides قولنا ال C double bond O + +74 +00:06:34,250 --> 00:06:39,770 +اللي جنبها نيتروجين، الآن بهمش، بدناش نظل نقول + +75 +00:06:39,770 --> 00:06:44,660 +اللي جنبها ال H2لأ بدنا نغير كلامنا شوية نقول اللي + +76 +00:06:44,660 --> 00:06:51,140 +جنبها nitrogen اللي جنبها nitrogen تمام؟ الآن هذه + +77 +00:06:51,140 --> 00:06:56,020 +ال nitrogen غير إن أنا متصلة بصيدة بال bond O عادة + +78 +00:06:56,020 --> 00:07:00,940 +كام رابطة بتعمل؟ تلاتة، تلاتة، تلاتة، تلاتة، + +79 +00:07:00,940 --> 00:07:02,120 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +80 +00:07:02,120 --> 00:07:02,440 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +81 +00:07:02,440 --> 00:07:05,140 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +82 +00:07:05,140 --> 00:07:05,920 +تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، + +83 +00:07:06,140 --> 00:07:10,760 +بناء على ذلك هدولة ممكن يكونوا H وH ونقول جنبها N + +84 +00:07:10,760 --> 00:07:16,380 +H2 ممكن يكونوا H وR وممكن يكونوا R وR يعني مايكونش + +85 +00:07:16,380 --> 00:07:21,700 +هيدروجين بالمرة فالأمد سيضة بال point O جنبها N ال + +86 +00:07:21,700 --> 00:07:30,660 +N ال N حاملة 2 H بصير الأمد حاملة واحدة H واحدة R + +87 +00:07:31,670 --> 00:07:39,450 +برضه بيصير الأمد حاملة تنتين R برضه بيصير واضحة + +88 +00:07:39,450 --> 00:07:45,510 +الفكرة؟ الآن ضمن هذا المنطق بيصير في عنده تصنيف + +89 +00:07:45,510 --> 00:07:50,590 +لأنواع الأمد بيصير عنده تصنيف لأنواع الأمد يعني + +90 +00:07:50,590 --> 00:07:54,750 +لاحظوا ال nitrogen هنا متصلة بكم كاربون لما تكون + +91 +00:07:54,750 --> 00:08:00,250 +حاملة H وH؟ بكاربون واحدة إذا هذا الأمد الأخضر إيش + +92 +00:08:00,250 --> 00:08:04,480 +بنقول عنه؟primary amide متصلة ب one carbon + +93 +00:08:04,480 --> 00:08:10,840 +النيتروجين لو صرت متصلة ب H و ب R يعني ب carbon و + +94 +00:08:10,840 --> 00:08:16,410 +من هنا ب carbon ايش بده تكون secondaryوالـ + +95 +00:08:16,410 --> 00:08:22,870 +Nitrogen لو كانت متصلة بـ R و بـ R .. بـ Carbon و + +96 +00:08:22,870 --> 00:08:26,170 +بـ Carbon و هنا الطبيعة الحالي بـ Carbon هتكون + +97 +00:08:26,170 --> 00:08:31,670 +ايش؟ Tertiary بناء على ذلك الأمد بيصير تلت أنواع + +98 +00:08:32,490 --> 00:08:38,090 +والأمد بيصير تعريفه العام C double bond O متصلة + +99 +00:08:38,090 --> 00:08:44,530 +بإيش؟ بنيتروجين هالنيتروجين هذه تكون NH2 primary + +100 +00:08:44,530 --> 00:08:51,150 +أمد NHR secondary أمد NR2 tertiary أمد واضح هذه + +101 +00:08:51,150 --> 00:08:56,710 +الفكرة؟ الآن هذه الفكرة طالما احنا وقفنا عندها + +102 +00:08:56,710 --> 00:09:04,890 +هتجيبنا لنقطة كتير مهمةالعمل ممكن يعمل hydrogen + +103 +00:09:04,890 --> 00:09:11,210 +bonding وممكن مايعملش وممكن يعمل بشكل كبير وممكن + +104 +00:09:11,210 --> 00:09:13,830 +يعمل بشكل اقل عارفين انتوا ال hydrogen bonding + +105 +00:09:13,830 --> 00:09:18,370 +بيصير لما يكون عندى hydrogen متطابط يا بنيتروجين + +106 +00:09:18,370 --> 00:09:23,730 +يا باكسوجين يا بفلورين الان لو اجيت على المركب + +107 +00:09:23,730 --> 00:09:31,510 +اللى هو ال primary amine فيه MHو تنتين مش واحدة + +108 +00:09:31,510 --> 00:09:36,350 +تمام اذا ال primary amide ممكن يعمل hydrogen + +109 +00:09:36,350 --> 00:09:40,430 +bonding ولا لأ و ممكن يعمل كام hydrogen bonding + +110 +00:09:40,430 --> 00:09:44,730 +طالما فيه تنتين hydrogen ممكن يعمل two hydrogen + +111 +00:09:44,730 --> 00:09:52,550 +bonding الان لو اجيت على ال secondary amide في كام + +112 +00:09:52,550 --> 00:09:58,690 +هيدروجينةوحدة إذا ممكن يعمل one hydrogen bonding + +113 +00:09:58,690 --> 00:10:04,590 +لو إجيت على ال tertiary amide مش فيه hydrogen إذا + +114 +00:10:04,590 --> 00:10:09,030 +بيعملش hydrogen bonding واضحة الفكرة إذا لو أنا + +115 +00:10:09,030 --> 00:10:11,450 +بدي أجي أشوف ال amides من ناحية ال hydrogen + +116 +00:10:11,450 --> 00:10:17,910 +bonding مين أكثر واحد بيعمل hydrogen bonding بعده + +117 +00:10:18,450 --> 00:10:23,970 +بعده tertiary ع طول مباشرة ال hydrogen bonding + +118 +00:10:23,970 --> 00:10:29,970 +بنعكس على أي خاصية على ال boiling point بناء على + +119 +00:10:29,970 --> 00:10:34,330 +ذلك لما انا بدي اجي احكي عن ال boiling point مين + +120 +00:10:34,330 --> 00:10:40,870 +هيكون اعلى boiling point ال primary اعلى من ال + +121 +00:10:40,870 --> 00:10:47,330 +secondary اعلى من ال tertiaryالان لو قلنا لكوا ليش + +122 +00:10:47,330 --> 00:10:51,010 +ال primary أعلى من ال secondary لأن ال primary فيه + +123 +00:10:51,010 --> 00:10:54,250 +تنين هيدروجين bonding السكندرية واحدة ليش + +124 +00:10:54,250 --> 00:10:57,710 +السكندرية أعلى من ال tertiary السكندرية فيه + +125 +00:10:57,710 --> 00:11:01,430 +إمكانية لوان هيدروجين bonding الترتشيري مافيش فيه + +126 +00:11:01,430 --> 00:11:05,450 +إمكانية للهيدروجين bonding فالأمر في ال boiling + +127 +00:11:05,450 --> 00:11:10,590 +point ما بين ال primary والسكندرية والترتشيريهو + +128 +00:11:10,590 --> 00:11:15,310 +إلى إمكانية تكوين الـ hydrogen bonding واضحة هذه + +129 +00:11:15,310 --> 00:11:20,410 +الفكرة كتصنيف amides و كنقاط غليان لاحظوا هذه + +130 +00:11:20,410 --> 00:11:28,020 +الفكرة نفسها موجودة هنا مثلالو انا اتطلعت على + +131 +00:11:28,020 --> 00:11:31,760 +الامد و كلكم اتذكرين انه احنا بالنسبة للامد لما + +132 +00:11:31,760 --> 00:11:35,920 +سبق المرة الماضية اتكلمنا عن تسميته قولنا بنيجي + +133 +00:11:35,920 --> 00:11:40,380 +بنشوف ايش اسم الحامض الاصلي و بنشيل oic acid و + +134 +00:11:40,380 --> 00:11:45,140 +بنكتب بدالها امد يعني هذا الحمض واحد اتنين تلاتة + +135 +00:11:45,140 --> 00:11:51,860 +كان بروبانوك اسد بيصير بروبان امد هذا الحمض لما + +136 +00:11:51,860 --> 00:11:58,300 +يكون OH بنزوك اسد بيصير بنز امدحمد و هكذا واضح + +137 +00:11:58,300 --> 00:12:03,540 +الفكرة؟ الأن لو مثلا اتيت على هذا المركب C double + +138 +00:12:03,540 --> 00:12:08,160 +bond O اللي حامل H هذا أبسط حامد في الدنيا لإن لو + +139 +00:12:08,160 --> 00:12:13,020 +هذه كانت OH بيكون Formic Acid بناء على ذلك من + +140 +00:12:13,020 --> 00:12:18,500 +Formic Acid من Formic Acid لما أعمل حامد Primer شو + +141 +00:12:18,500 --> 00:12:25,940 +هسميه؟ Formamideطيب يا ترى لو إجيت شيلت واحدة من + +142 +00:12:25,940 --> 00:12:30,820 +الهيدروجينات و بدلتها بمثل يعني عملت هيك C double + +143 +00:12:30,820 --> 00:12:38,420 +bond OH و هذه N خليت عليها هيدروجين و الهيدروجين + +144 +00:12:38,420 --> 00:12:41,320 +التاني ايه شو خليتها CH3 + +145 +00:12:46,710 --> 00:12:51,830 +هذا امد جاي من ال form امد لكن هذا form امد صار + +146 +00:12:51,830 --> 00:12:58,870 +بيحمل ايش مثل اذا بسمي انا مثل form امد لاحظوا + +147 +00:12:58,870 --> 00:13:05,390 +form امد ال primary لان لما حمل مثل واحدة ايش صار + +148 +00:13:05,390 --> 00:13:13,610 +مثل form امد اللي هو secondary امدالآن، لو بعدك + +149 +00:13:13,610 --> 00:13:18,290 +حملتوا مثل مجموعات، فهي تصبح دائمة في الـ + +150 +00:13:18,290 --> 00:13:22,980 +Formamentواضح؟ إذا ممكن يكون form amide بدون ولا + +151 +00:13:22,980 --> 00:13:28,160 +مثل بمثل واحدة مثل form amide ب two methyl groups + +152 +00:13:28,160 --> 00:13:33,660 +ضاي مثل form amide الان لأن هالمثل بتحمل على ال + +153 +00:13:33,660 --> 00:13:39,640 +nitrogen مرات بيضيفوا و مرات لأ الحرف capital N + +154 +00:13:39,640 --> 00:13:43,980 +يعني هنا بيكتبوا أن مثل form amide إيش معناها؟ + +155 +00:13:43,980 --> 00:13:47,880 +معناها أن المثل محمول على ذرة ال nitrogen هاي + +156 +00:13:47,880 --> 00:13:53,630 +معناه أنواضح؟ طبعا هذا اللي فيه مجموعتين مثل على + +157 +00:13:53,630 --> 00:13:59,210 +ذرة النيتروجين شو هسميه؟ N فاصلة N + +158 +00:13:59,210 --> 00:14:03,570 +-dimethylformamide يعني المثل الأولى والمثل + +159 +00:14:03,570 --> 00:14:08,010 +التانية محمولات على ذرة إيش؟ النيتروجين الآن + +160 +00:14:08,010 --> 00:14:12,170 +لاحظوا كيف التدرج ال primary amyl formamide ال + +161 +00:14:12,170 --> 00:14:16,800 +secondary مثلا المثل formamide ال tertiaryالداي + +162 +00:14:16,800 --> 00:14:22,500 +مثل فورماميل، مين بنتوقعه أعلى boiling point + +163 +00:14:22,500 --> 00:14:28,400 +لبرايماري، لاحظوا ال boiling point تبعته 210، الآن + +164 +00:14:28,400 --> 00:14:33,960 +مين أقل boiling point؟ ال boiling point تبعته 153 + +165 +00:14:35,590 --> 00:14:39,390 +ال secondary where بيجي؟ في النص حيجي حوالي مية و + +166 +00:14:39,390 --> 00:14:43,190 +سبعين، مية و تمانين، شغل زي هيك، شفتوا التدرج؟ + +167 +00:14:43,190 --> 00:14:46,730 +ميتين و عشرة، مية و سبعين، مية و تمانين، مية و + +168 +00:14:46,730 --> 00:14:50,290 +تلاتة و خمسين، ال primary؟ بتنين هيدروجين بولنج، + +169 +00:14:50,290 --> 00:14:53,570 +ال secondary one؟ تير شر بدون هيدروجين بولنج، + +170 +00:14:53,570 --> 00:14:58,000 +واضحة؟نفس الاشي مثلا هذا ال acetamide ال primary + +171 +00:14:58,000 --> 00:15:01,540 +ال di-methyl acetamide او ال un-di-methyl + +172 +00:15:01,540 --> 00:15:06,300 +acetamide ال tertiary مش رسمي هنا ال secondary هذا + +173 +00:15:06,300 --> 00:15:11,020 +ال primary مائتين و اتنين و عشرين الآن ال tertiary + +174 +00:15:11,020 --> 00:15:15,060 +مائة و خمس و ستين ال primary اعلى من ال tertiary + +175 +00:15:15,060 --> 00:15:22,190 +لأنه فيه تنتين هيدروجين bonded واضح؟طبعا لو أنا + +176 +00:15:22,190 --> 00:15:28,510 +إجيت سألكم أسئلة لو إجيت سألكوا أسئلة ليش ال + +177 +00:15:28,510 --> 00:15:32,830 +formament أعلى من ال diameter ال formament because + +178 +00:15:32,830 --> 00:15:40,970 +it can formتو هيدروجين بوندين لإيش الاسيتاميد أعلى + +179 +00:15:40,970 --> 00:15:45,010 +من الديمثلاسيتاميد because it can form hydrogen + +180 +00:15:45,010 --> 00:15:50,670 +bonding الآن لو إجيت عملت سؤال مقارنة قلتلكم ال + +181 +00:15:50,670 --> 00:16:00,130 +form أمد والاسيت أمد هذا 222 هذا 210 مين الأعلى؟ + +182 +00:16:00,130 --> 00:16:08,030 +وليش؟طبعا الأعلى الأسئ تمت 222 أعلى من 210 + +183 +00:16:10,530 --> 00:16:15,330 +أه الآن هنا في عندي اشتراك في الـ hydrogen bonding + +184 +00:16:15,330 --> 00:16:19,450 +هنا في عندي two hydrogen bonding و هنا في عندي two + +185 +00:16:19,450 --> 00:16:23,810 +hydrogen bonding بطل ال hydrogen bonding هو الحكم + +186 +00:16:23,810 --> 00:16:28,990 +أصبحت الصيغة الجزائية هي الحكم أن هذا أكبر من هذا + +187 +00:16:28,990 --> 00:16:32,870 +و كل ما ارتفعنا احنا بالصيغة الجزائية مع توحيد + +188 +00:16:32,870 --> 00:16:37,120 +الصفات التانية كل ما بتزيد ايش ال boiling pointزي + +189 +00:16:37,120 --> 00:16:42,320 +لما كنا نحكي الكينز كلهم مافيهم bonding كنا نقول + +190 +00:16:42,320 --> 00:16:48,680 +الميثين أقل واحد لما يصير إيثين بيرتفع البروبين + +191 +00:16:48,680 --> 00:16:53,980 +بيرتفع البيوتين بيرتفع كذلك الأحماض مثلا ال formic + +192 +00:16:53,980 --> 00:16:59,980 +acid أقل حامل بعده ال acetic acid بعده ال borbenic + +193 +00:16:59,980 --> 00:17:03,520 +acid هدول كلهم مشتركين بال hydrogen bonding كلهم + +194 +00:17:03,520 --> 00:17:08,170 +نفس العيلة إيش الإختلاف إذا اللي بينهم؟بصيغة + +195 +00:17:08,170 --> 00:17:12,670 +جزيئية فهدولة بنسميهم أفراد من ال homologous + +196 +00:17:12,670 --> 00:17:16,710 +series اللي هي السلسلة المتتالية من نفس العيلة في + +197 +00:17:16,710 --> 00:17:20,530 +الكحولات كلهم فيهم hydrogel bonding فكل ما زاد ال + +198 +00:17:20,530 --> 00:17:23,190 +molecular weight بتزيد ال boiling point في الأحمض + +199 +00:17:23,190 --> 00:17:27,870 +نفس الاشياء الآن في ال amides بس بشرط لما أعمل + +200 +00:17:27,870 --> 00:17:33,490 +المقارنة إذا بقارن أقارن primary مع primary أو + +201 +00:17:33,490 --> 00:17:38,300 +مثلاTertiary مع tertiary لاحظوا التيرتشاري هنا + +202 +00:17:38,300 --> 00:17:42,300 +مافيش فيه hydrogen bonding 165 التيرتشاري هنا + +203 +00:17:42,300 --> 00:17:47,620 +مافيه hydrogen bonding 153 إذا ماسبب الفرق بال + +204 +00:17:47,620 --> 00:17:50,220 +molecular weight واضحة الفكرة؟ + +205 +00:18:00,170 --> 00:18:04,390 +طبعا تحضير ال amides مفهوم اللي هو ال ammonia او + +206 +00:18:04,390 --> 00:18:08,870 +مشتقاتها يعني ال ammonia لما بيفعلها مع الحامض + +207 +00:18:08,870 --> 00:18:15,510 +بتعطيني اي amide ل primary الان لو كان هنا NH2R + +208 +00:18:15,510 --> 00:18:20,410 +هيعطيني اي amide secondary لانه يحمل R واحدة لو + +209 +00:18:20,410 --> 00:18:22,490 +كان NHR2 + +210 +00:18:25,290 --> 00:18:29,190 +فلا بد إلا يكون عنده أقل تقدير H ممكن يكونوا تلاتة + +211 +00:18:29,190 --> 00:18:31,870 +ممكن يكونوا تنتين ممكن يكونوا واحدة وباقى + +212 +00:18:31,870 --> 00:18:35,410 +المجموعات R فبصير بإمكان أحضر ال primary secondary + +213 +00:18:35,410 --> 00:18:39,990 +tertiary ال primary بحضره من إيش؟ من ال ammonia ال + +214 +00:18:39,990 --> 00:18:46,830 +primary من ال ammonia الآن ال amides علشان يريحون + +215 +00:18:46,830 --> 00:18:54,810 +فيهم ميزة جميلةبنسميها الامد resonance وهذه بتأثر + +216 +00:18:54,810 --> 00:19:01,210 +على reactivity of الامد الامد نفسه مكوّن من جزئين + +217 +00:19:01,210 --> 00:19:06,830 +مكوّن من سيظة بال bond O اللي هي كربونيلي جروب + +218 +00:19:06,830 --> 00:19:15,120 +ومكوّن من ال NH2 الامين صح ولا لأ؟ امينو Carbonyl + +219 +00:19:15,120 --> 00:19:20,340 +C double bond O الان لاحظوا معايا كل واحدة منهم + +220 +00:19:20,340 --> 00:19:26,580 +منفردة very reactive يعني ال Carbonyl group لوحدها + +221 +00:19:26,580 --> 00:19:31,520 +very reactive و احنا قلنا تقريبا تلت اسابيع اربعة + +222 +00:19:31,520 --> 00:19:34,900 +بس بندرس ال Carbonyl groups ال C double bond O في + +223 +00:19:34,900 --> 00:19:37,600 +ال aldehydes في ال ketones في ال acids في ال E + +224 +00:19:37,600 --> 00:19:42,610 +stars very reactive واضح؟والـ Nitrogen لواحدة الـ + +225 +00:19:42,610 --> 00:19:48,870 +NH2 و الـ NH8 برضه very reactive و هندرس عليها + +226 +00:19:48,870 --> 00:19:55,510 +شبتر 11 فالـ C double bond O very reactive و درسنا + +227 +00:19:55,510 --> 00:19:57,990 +عليها شبتر ال aldehydes و ال ketones و ال acids + +228 +00:19:57,990 --> 00:20:00,990 +شبتر 9 و 10 كله مع ال C double bond O من كتر مية + +229 +00:20:00,990 --> 00:20:06,470 +reactive الـ NH very reactive ندرس عليها شبتر 11 + +230 +00:20:06,470 --> 00:20:13,290 +ال amines الآن يوم ما بنحطالـ c double point o ال + +231 +00:20:13,290 --> 00:20:19,710 +very reactive مع ال n h ال very reactive بنحصل + +232 +00:20:19,710 --> 00:20:24,250 +منهم على very + +233 +00:20:24,250 --> 00:20:31,490 +very reactive ولا إيش رأيكم؟ بنحصل منهم على + +234 +00:20:31,490 --> 00:20:36,970 +unreactive بنحصل + +235 +00:20:36,970 --> 00:20:39,610 +منهم على unreactive + +236 +00:20:41,050 --> 00:20:48,450 +الـ A يمكن تستغربه كيف ال reactive و ال reactive + +237 +00:20:48,450 --> 00:20:50,130 +بيعطوا + +238 +00:20:51,590 --> 00:20:58,010 +unreactive لكن اللي بيفهم الدنيا بيقدر يفهم هذا + +239 +00:20:58,010 --> 00:21:01,790 +الأمر جيدا اللي بيفهم الدنيا بيقدر يفهم هذا الأمر + +240 +00:21:01,790 --> 00:21:08,590 +جيدا ال reactivity ال reactivity معناها تفاعل مع + +241 +00:21:08,590 --> 00:21:14,540 +الخارج ال reactivity تفاعل مع الخارج تماميعني + +242 +00:21:14,540 --> 00:21:20,100 +الأمة العربية .. الأمة العربية كان ممكن تكون + +243 +00:21:20,100 --> 00:21:27,210 +reactive بس بشرط reactive ضد مينضد أعداءها الأمة + +244 +00:21:27,210 --> 00:21:30,730 +العربية ممكن تكون reactive و very reactive ضد + +245 +00:21:30,730 --> 00:21:35,810 +أعداءها اليوم لما صارت الأمة العربية في كل دولة + +246 +00:21:35,810 --> 00:21:40,390 +فيها و ما بين الدول بعد هيك في كل دولة في شق + +247 +00:21:40,390 --> 00:21:45,550 +reactive و شق reactive هدول الشقين طبق تالف بعض + +248 +00:21:45,550 --> 00:21:53,710 +كيف صفيه مع الخارج? unreactive يعني في اليمنجدّاش + +249 +00:21:53,710 --> 00:21:57,550 +بتجتلوا في بعض هو هذا الاقتلا والجبال الإسرائيل + +250 +00:21:57,550 --> 00:22:02,290 +ماجدرتش عليهم بس المشكلة ان ال reactivity مش مع + +251 +00:22:02,290 --> 00:22:08,950 +الخارج reactivity ايش داخلية فما بالكوا لما نجيبها + +252 +00:22:08,950 --> 00:22:15,410 +ايديك ايش نقول اليمن و السعودية تبقوا معاه هنا في + +253 +00:22:15,410 --> 00:22:18,510 +reactivity و هنا في reactivity ايش هت مع بعض دمرت + +254 +00:22:18,510 --> 00:22:24,610 +بعض طب مع الخارجضد الأعداء الحقيقيين، إيش بنصفة؟ + +255 +00:22:24,610 --> 00:22:29,650 +Unreactive ولذلك لما جمعنا هنا ال reactive و ال + +256 +00:22:29,650 --> 00:22:35,350 +reactive صاروا إيش؟ يتقاتلوا مع بعض فمع الخارج + +257 +00:22:35,350 --> 00:22:41,230 +بطلوا reactive الآن هذا الكلام بدنا نفهمه أكتر من + +258 +00:22:41,230 --> 00:22:47,910 +ناحية إيش؟ الكيميا بدنا نقول وين سر قوة شمشوم + +259 +00:22:47,910 --> 00:22:53,530 +الجبارعارفينه شمشوم الجباب؟ اللي في الأسطورة بطل + +260 +00:22:53,530 --> 00:23:00,670 +غزة اللي كان سر قوته في شعره و لما اكتشفوا سر قوته + +261 +00:23:00,670 --> 00:23:06,230 +بيكسر المباني و بيعمل .. حلقوله شعره راح فقد قوته، + +262 +00:23:06,230 --> 00:23:10,470 +تمام؟ الآن لو اجينا على ال الديهيد و الكيتون، وين + +263 +00:23:10,470 --> 00:23:15,530 +سر قوتهم اللي لنا تلت أسابيع نشتغل عليه؟ الكربون + +264 +00:23:15,530 --> 00:23:16,770 +المجاباة + +265 +00:23:18,720 --> 00:23:22,220 +الـ Carbon الموجبة مشغول من التفاعلات الـ + +266 +00:23:22,220 --> 00:23:25,220 +Eucleophilic Addition أو Substitution، الـ + +267 +00:23:25,220 --> 00:23:28,980 +Eucleophile إجراء بيجي وين؟ على الـ Carbon + +268 +00:23:28,980 --> 00:23:34,440 +الموجبة، هاي سر قوتهم، وعشان يقم لما ييجي الـ + +269 +00:23:34,440 --> 00:23:39,490 +Eucleophile من الخارجيحمل أزواج إلكتروناتي جراي + +270 +00:23:39,490 --> 00:23:43,550 +بيجي بتفعل معاهم صاروا reactive معاه ولا لأ؟ صاروا + +271 +00:23:43,550 --> 00:23:51,130 +reactive طيب لو أجينا للـ nitrogen وين سر قوتها؟ + +272 +00:23:51,130 --> 00:23:55,950 +زوج الإلكترونات هنا + +273 +00:23:55,950 --> 00:24:02,920 +في عندي على ال nitrogen زوج إلكتروناتهذا سير قوتها + +274 +00:24:02,920 --> 00:24:07,940 +أول ما بيلاقي أي موجة بجزئه بروح بتفاعل معاه ولا + +275 +00:24:07,940 --> 00:24:12,600 +لأ هاي سير قوة ال nitrogen زوج الإلكترونات يعني + +276 +00:24:12,600 --> 00:24:20,480 +مثلا أذكر لما كنا نقول فعله المركبين القاتين RNH2 + +277 +00:24:20,480 --> 00:24:26,620 +زائد CH3 نكتبها زي هيك + +278 +00:24:37,980 --> 00:24:45,440 +النيتروجين عليها زوج إلكتروناتصح و ال carbon و + +279 +00:24:45,440 --> 00:24:50,320 +اليود مين فيهم موجب و مين سالب ال carbon الموجبة + +280 +00:24:50,320 --> 00:24:55,280 +ال a التفاعل موجب مع سالب إجراء هذا زوج + +281 +00:24:55,280 --> 00:24:59,620 +الإلكترونات بييجي بيهاجمها و بيطرد اليود صار سر + +282 +00:24:59,620 --> 00:25:05,240 +عندك CH3 NHR + +283 +00:25:05,240 --> 00:25:13,880 +مظبوط ولا لأ فهي سر القوةزوج الالكترونات هذا سير + +284 +00:25:13,880 --> 00:25:18,200 +قوته الموجب الموجب مع السالب هاي التفاعلات هاي + +285 +00:25:18,200 --> 00:25:23,760 +الكيميا موجب وسالب واضح فالان النيتروجين سير قوته + +286 +00:25:23,760 --> 00:25:27,860 +السالب او زوج الالكترونات والكربون سير قوته الموجب + +287 +00:25:27,860 --> 00:25:35,790 +لما قعدوا في نفس الجزءبدل ما يروحوا يتفاعلوا ال + +288 +00:25:35,790 --> 00:25:40,330 +nitrogen برا يكون reactive برا وال carbon برا يكون + +289 +00:25:40,330 --> 00:25:45,050 +reactive برا قال انت سالب شو بدك؟ وانت موجب شو + +290 +00:25:45,050 --> 00:25:52,320 +بدك؟ طب هيوموجودين جانب بعض بناء على ذلك إجراء هذا + +291 +00:25:52,320 --> 00:25:57,760 +السالب إجا قالوا هاي المجاب شو بدك؟ قالوا أنا + +292 +00:25:57,760 --> 00:26:03,160 +السالب اتفضل أعطاه الإلكترونات تبعه طبعا معقول إنه + +293 +00:26:03,160 --> 00:26:08,160 +هنا يصير في عندي خمس روابط على الكربون على طول هذه + +294 +00:26:08,160 --> 00:26:13,740 +إيش هتصير؟ تلوف الإلكترونات تصير O minus صار بهذا + +295 +00:26:13,740 --> 00:26:18,830 +الشكل الرزوناسيالان اتطلعوا على هذا الجزء هل + +296 +00:26:18,830 --> 00:26:24,250 +ياترال كاربول ضال عليها موجب؟ هل ال نيتروجين ضال + +297 +00:26:24,250 --> 00:26:29,250 +عليها زوج إلكترونات؟ راحوا القوتين ولذلك بيصف + +298 +00:26:29,250 --> 00:26:34,750 +القامد او ال reactif لأنه اتفاعل مع نفسه يعني زي + +299 +00:26:34,750 --> 00:26:38,410 +اللي في داخل الأمة جاتلوا مع بعض قدام الناس إيش + +300 +00:26:38,410 --> 00:26:44,710 +بيطلعوا؟ ولا إشيقدام الغروب، شو بيطلعوا؟ ولا إشي، + +301 +00:26:44,710 --> 00:26:48,630 +هم خلاص اتفاعلوا مع بعضهم، اتقاتلوا مع بعضهم، + +302 +00:26:48,630 --> 00:26:54,070 +واضحة الفكرة؟ ولذلك السبب إن الامد unreactive هو + +303 +00:26:54,070 --> 00:26:59,230 +إيش؟ الامد resonance، لا ضال هذا السالب سالب ولا + +304 +00:26:59,230 --> 00:27:04,250 +ضال هذا الموجب موجبفسر القوة للتانين انتهى، راحوا، + +305 +00:27:04,250 --> 00:27:08,770 +بطلوا، سالب و موجب، الآن خليني أسأل عادي السؤال من + +306 +00:27:08,770 --> 00:27:14,910 +زاوية تانية، هل يترى الأمد لما بيكون unreactive؟ + +307 +00:27:14,910 --> 00:27:20,490 +يعتبر الأمر شيء إيجابي ولا شيء سلبي؟ + +308 +00:27:22,790 --> 00:27:29,350 +أحنا اتفقنا القامت unreactive هل يعتبر سلبي ولا + +309 +00:27:29,350 --> 00:27:36,410 +إيجابي؟ فينا زملائكوا بيقولوا كل شيء زي السكينة + +310 +00:27:36,410 --> 00:27:43,570 +ممكن تكون كويسة وممكن تكون مش كويسة حسب الاستخدام + +311 +00:27:43,570 --> 00:27:49,430 +زي ال internetممكن يكون مفيد، ممكن يكون إيش، بقى + +312 +00:27:49,430 --> 00:27:54,330 +حسب الاستخدام، يعني على سبيل المثال النيلون + +313 +00:27:56,280 --> 00:28:01,240 +عبارة عن أمد، هنشوف كيف بتحضر، بس الآن أقل تقدير + +314 +00:28:01,240 --> 00:28:06,620 +نعرف إن النيلون إيش أمد، وبناء على ذلك النيلون + +315 +00:28:06,620 --> 00:28:11,760 +reactive ولا unreactive؟ النيلون unreactive، الآن + +316 +00:28:11,760 --> 00:28:15,260 +كون النيلون unreactive، هذا الأمر يعتبر موجب ولا + +317 +00:28:15,260 --> 00:28:22,900 +ثاني؟يحتمل الأمرين، يعني لما النيلون بيكون عبارة + +318 +00:28:22,900 --> 00:28:27,900 +عن قمامة و بدنا نتخلص منها لو دفنناها أو ما إلى + +319 +00:28:27,900 --> 00:28:33,540 +ذلك، بتتحلل ولا بتظل زي ما هي بالأرض؟ بتظل زي ما + +320 +00:28:33,540 --> 00:28:38,320 +هي بالأرض، مابتتحللشخدوا مثلا فضلات النبات غير + +321 +00:28:38,320 --> 00:28:41,500 +غيرها، ادفنوها في الأرض، بتتحللوا، بتروح، ادفنوا + +322 +00:28:41,500 --> 00:28:45,180 +نيلون في الأرض، بتتحللش، وبناء على ذلك، كونوا + +323 +00:28:45,180 --> 00:28:49,040 +الـnylon unreactive من هذه الزاوية، من زاوية + +324 +00:28:49,040 --> 00:28:56,590 +كفضلاتيعتبر الأمر غير جيد، يعتبر الأمر سلبي، لكن + +325 +00:28:56,590 --> 00:29:01,530 +نفس النيلون هذا، نفس النيلون هذا، لو أنا كنت بدي + +326 +00:29:01,530 --> 00:29:06,890 +فعلا يظل في الرمل وما يخربش، يعني على سبيل المثال، + +327 +00:29:06,890 --> 00:29:11,910 +الحمامات الزراعية مش بيعملوها بنيلون، النيلون هذا + +328 +00:29:11,910 --> 00:29:17,750 +تحت، بطم فوقه رمل ولا لأ؟بعد شهر، شهرين، تلاتة، + +329 +00:29:17,750 --> 00:29:22,170 +أربعة، بدوب النيلون ولا بيظله موجود؟ اتخيل لو هذا + +330 +00:29:22,170 --> 00:29:29,670 +كان ورق، ورق وحطينا فوقه رمل، رمل وميه، بعد كدهش + +331 +00:29:29,670 --> 00:29:36,030 +بنتهي؟ بعد ساعة، النيلون الآن أنا بديه يظلهلما + +332 +00:29:36,030 --> 00:29:39,510 +ظلوا بهذا الشكل وكانوا unreactive، كان يعتبر أمر + +333 +00:29:39,510 --> 00:29:43,950 +إيش؟ إيجابي بالنسبة لي، ولذلك مثلا لما بيعملوا + +334 +00:29:43,950 --> 00:29:49,400 +كوابل الكهربا مدفونة في الأرضبيجوا فوق الكابل بنص + +335 +00:29:49,400 --> 00:29:52,880 +متر، يعني افترض الكابل مدفون على عمق متر، فوق + +336 +00:29:52,880 --> 00:29:56,860 +الكابل بنص متر، بيجيبوا شريط نايلون و بيحطوه في + +337 +00:29:56,860 --> 00:30:01,200 +الأرض، هذا الشريط مكتوب عليه احذر خطر الكهرباء، + +338 +00:30:01,200 --> 00:30:05,540 +احذر خطر الكهرباء، ليش؟ لو اجوا ناس يجرفوا، بعد + +339 +00:30:05,540 --> 00:30:09,680 +شوية الجرفة تخبط في كابل كهربا مدفون في الأرضبناء + +340 +00:30:09,680 --> 00:30:13,620 +على ذلك بيحطولهم نايلون أصفر و مكتوب عليه شريط فوق + +341 +00:30:13,620 --> 00:30:17,560 +الكابل احذر على عمق متر فيه عندك قطر كربا هذا + +342 +00:30:17,560 --> 00:30:23,210 +بيقعد عشر خمس عشر سنة وأكترالان هذا استعمال إيجابى + +343 +00:30:23,210 --> 00:30:27,970 +ولا سلبى لل unreactivity تبعته استعمال إيجابى + +344 +00:30:27,970 --> 00:30:32,470 +ففكرة ال unreactivity أو ال reactivity يمكن ان + +345 +00:30:32,470 --> 00:30:38,030 +ينظر إليها من زاويتين و كذلك ال nylon لما بقول عنه + +346 +00:30:38,030 --> 00:30:42,050 +عبارة عن أمد و unreactive مرات انا بدي اكون + +347 +00:30:42,050 --> 00:30:45,850 +unreactive باستفيد من كونه unreactive ان ال nylon + +348 +00:30:45,850 --> 00:30:50,450 +مابخربش و بحمل فيه الغرابو عند اللزوم اليوم اللي + +349 +00:30:50,450 --> 00:30:55,970 +بيشتريوا الأشتال الصغيرة كلها محطوطة بإيش؟ بكياس + +350 +00:30:55,970 --> 00:31:00,650 +نيلون ولا بكياس ورق؟الان هذا استعمال إيجابي ولا + +351 +00:31:00,650 --> 00:31:04,670 +سلبي؟ استعمال إيجابي، انه unreactive، انه ماخربش + +352 +00:31:04,670 --> 00:31:09,350 +من الميه والحرارة، واضح؟ لكن أنا لما بحط قمامة و + +353 +00:31:09,350 --> 00:31:12,690 +بدي أدفنها و بديها تتحول إلى سماد عضوى، و أجي + +354 +00:31:12,690 --> 00:31:16,390 +ألاقي النيلول زي ما هو، و أبدأ أضطر أروح أحرجه و + +355 +00:31:16,390 --> 00:31:20,970 +أطلع منه مواد ضارة، و أجي تبكي و أروح اتعلق؟السلبي + +356 +00:31:20,970 --> 00:31:25,290 +من أن الامد إيش ماله؟ Unreactive فهمنا إذا فكرة ال + +357 +00:31:25,290 --> 00:31:29,190 +reactivity of امد في كل الأحوال لما احنا بنقول إشي + +358 +00:31:29,190 --> 00:31:34,690 +unreactive مش معناه صيرنا جايبين سيرة النيلون شو + +359 +00:31:34,690 --> 00:31:40,110 +هو النيلون؟ النيلون عبارة عن امد بوليمر بسيط جدا + +360 +00:31:40,110 --> 00:31:47,680 +بحط هذا المركب اللي فيه C double bond OCLو ست + +361 +00:31:47,680 --> 00:31:53,040 +كربونات يعني كربون تنتين تلاتة أربعة خمسة ستة الان + +362 +00:31:53,040 --> 00:31:57,840 +هذا أصلا حامض داي أسد من ست كربونات بتذكرين قولنا + +363 +00:31:57,840 --> 00:32:02,680 +إيش اسمه اديبك أسد المرة الماضية الحمض اللي هو + +364 +00:32:02,680 --> 00:32:07,250 +الدي أسد من ست كربونات لو فعلنا معك لوربدو يصير + +365 +00:32:07,250 --> 00:32:10,810 +أديبويل كلورايد زي ما قولنا المرة الماضية + +366 +00:32:10,810 --> 00:32:15,010 +بروبانويل كلورايد وكذا كذا كذا الآن هي أديبويل + +367 +00:32:15,010 --> 00:32:19,710 +كلورايد يمين و أديبويل كلورايد الشمال بجيب أمين + +368 +00:32:19,710 --> 00:32:27,210 +NH2 6 كربونات و كمان NH2 لما أعمل تفاعل بينهم ال + +369 +00:32:27,210 --> 00:32:35,210 +nitrogen هذا ايش بدي اعمل احل محلالكلور هيعمل عندى + +370 +00:32:35,210 --> 00:32:43,770 +C double bond O and H واضح الفكرة و هكذا و من هنا + +371 +00:32:43,770 --> 00:32:47,670 +هيصير عندى كمان C double bond O and H هيصير عندى + +372 +00:32:47,670 --> 00:32:50,610 +polymer يعني هى ست كربونات جايين من الادبويل + +373 +00:32:50,610 --> 00:32:55,640 +الكلوراي ستة جايين من إيش؟من الداي أمين الأمين من + +374 +00:32:55,640 --> 00:32:58,640 +الجهتين والأدي بويل الكلورايد من الجهتين بيظلوا + +375 +00:32:58,640 --> 00:33:03,300 +ميشبكوا مع بعض ولا لأ عملوا معي بوليمر الآن هذا + +376 +00:33:03,300 --> 00:33:08,620 +البوليمر موصول من وين من خلال رابطة أمد لإن عندي + +377 +00:33:08,620 --> 00:33:15,480 +ال C double bond O and H لاحظوا هنا كام كربونا ستة + +378 +00:33:16,560 --> 00:33:21,040 +مع ال سيطة بالبوند او التنتين و CH2 الستة و هنا كم + +379 +00:33:21,040 --> 00:33:26,500 +كربونا غير ال نيتروجين اذا انا عندى رابطة الامد و + +380 +00:33:26,500 --> 00:33:34,960 +ست كربونات و بعدين رابطة امد تانية و ست كربونات و + +381 +00:33:34,960 --> 00:33:41,020 +هلما طالما ستة امد ستة امد ستة امد ستة امد هذا + +382 +00:33:41,020 --> 00:33:46,610 +النيلون ايش هنسميه في هذه الحالةنيلون بوليمر طبعا + +383 +00:33:46,610 --> 00:33:56,050 +بيسموه نيلون 6 6 لأن هنا 6 كربونات أمد و 6 كربونات + +384 +00:33:56,050 --> 00:34:01,740 +من الأمينستة من الاديبويل الكلورايت و ستة من + +385 +00:34:01,740 --> 00:34:06,540 +الأمين و بينهم رابطة ايش امل فنيلون سيكس سيكس الان + +386 +00:34:06,540 --> 00:34:10,180 +بيصير السؤال لو يا ترى استعملوا الأمين ب تمان + +387 +00:34:10,180 --> 00:34:17,150 +كربونات ايش هيصير النيلون six eightلأ مش الانتين + +388 +00:34:17,150 --> 00:34:22,530 +استعملهم تمانية خلوا هذا ستة و هدول تمانية ممكن + +389 +00:34:22,530 --> 00:34:27,470 +نعمل زي هيك و بناء على ذلك النيلون نفسه بيصير مصنف + +390 +00:34:27,470 --> 00:34:33,410 +six six ممكن six eight ممكن six ten ممكن واضح؟ و + +391 +00:34:33,410 --> 00:34:37,650 +هذا بيعمل اللي هي الأنواع المختلفة في النيلون من + +392 +00:34:37,650 --> 00:34:42,310 +ناحية القوام والشكل والصلابة لكن أشهر نيلون الأبيض + +393 +00:34:42,310 --> 00:34:47,270 +الشفافة اللي بنعرفه هو نيلون إيش؟6 6 6 ذرات من + +394 +00:34:47,270 --> 00:34:51,710 +الاديبويل الكلورايد و 6 من الأمين و عامل بوليمار + +395 +00:34:51,710 --> 00:34:58,350 +واضح الفكرة هذا هو النيلون + +396 +00:34:58,350 --> 00:35:02,310 +الان + +397 +00:35:02,310 --> 00:35:07,870 +مش معناه ان الامد غير مفاعل انه مابتفعلش ولا تفاعل + +398 +00:35:07,870 --> 00:35:16,500 +لأ انه تفاعلين خفاف التفاعل الأول ان الامدمع الميه + +399 +00:35:16,500 --> 00:35:21,720 +والحامض او القاعدة بتسخين لفترة طويلة لحظو انا ايش + +400 +00:35:21,720 --> 00:35:26,600 +انا كاتب Prolonged heating يعني ممكن يومين تلاتة + +401 +00:35:26,600 --> 00:35:32,720 +اظلني اسخن فيه بتسخين لفترة طويلة بينكسر وبرجع + +402 +00:35:32,720 --> 00:35:37,020 +للحامض اذا القامد ممكن ال O-H تهاجم عليه ويراجع + +403 +00:35:37,020 --> 00:35:43,030 +للحامض بس بشرطإن أسخنه مع حمض أو قاعدة و لفترة + +404 +00:35:43,030 --> 00:35:48,750 +طويلة جدا هذا التفاعل عادة بيصير وين لما نعمل + +405 +00:35:48,750 --> 00:35:54,370 +تحليل للبروتينات لأن البروتينات عبارة عن amides + +406 +00:35:54,370 --> 00:35:58,010 +فلما ابتدي أحليل ال amino acids تبعونهم بجيب + +407 +00:35:58,010 --> 00:36:02,390 +اللحمة أو البروتين و بحطه و بضلني أغليه يوم يومين + +408 +00:36:02,390 --> 00:36:07,570 +لحد ما فكفك الوحدات تبعته واضح؟ في البروتين + +409 +00:36:07,570 --> 00:36:13,090 +analysis هيمر معكمالتفاعل التاني للأمد ان انا ممكن + +410 +00:36:13,090 --> 00:36:17,530 +اعمله reduction الأمد لما بعمله reduction بليثيوم + +411 +00:36:17,530 --> 00:36:22,390 +ألومنوم هيدرايك ببساطة كبيرة جدا السيطة بال bond O + +412 +00:36:22,390 --> 00:36:25,870 +تبعت الأمد هتصير CH2 + +413 +00:36:28,130 --> 00:36:33,790 +واضح؟ فإذا كان عندى R C double bond O NH2 بتصير R + +414 +00:36:33,790 --> 00:36:40,310 +CH2 NH2، بهذه الحالة الأمد أصبح عبارة عن إيش؟ + +415 +00:36:40,310 --> 00:36:46,370 +أمين، هذه هتصير طريقة لتحضير الأمين، اللي هي موضوع + +416 +00:36:46,370 --> 00:36:54,010 +شبطريح دعش، يعني لما نيجي نقول تحضير الأمينبالـ + +417 +00:36:54,010 --> 00:36:58,530 +reduction of amides شبيه بهذا التفاعل عشان تعملوا + +418 +00:36:58,530 --> 00:37:04,510 +المقارنة انه كان ال Easter ال R سيضا بالبند OOR + +419 +00:37:04,510 --> 00:37:08,410 +بالليثيام ألومنوم هيدرايد بال reduction شو كان + +420 +00:37:08,410 --> 00:37:16,170 +يعطيني ال primary alcohol كان يعطيني RCH2OH لاحظوا + +421 +00:37:16,170 --> 00:37:21,370 +المعادلتين هدولةبيشيوا ببعض و لازم نكون عارفينهم + +422 +00:37:21,370 --> 00:37:27,110 +ال reduction of amide produces primary amines ال + +423 +00:37:27,110 --> 00:37:32,790 +reduction of ester produces primary alcohols ال C + +424 +00:37:32,790 --> 00:37:37,880 +double bond O في الحالتين إيش بتصيب؟CH2 هدى طبعا + +425 +00:37:37,880 --> 00:37:41,940 +ال OR بتصير OH وهنا ال NH2 بتظل زى ما هي ف ال + +426 +00:37:41,940 --> 00:37:45,880 +amides بيصيروا primary amines و ال esters بيصيروا + +427 +00:37:45,880 --> 00:37:50,260 +primary alcohol بال reduction دايما اللى بيحفظ + +428 +00:37:50,260 --> 00:37:54,080 +الأشياء يحفظها بالإيش مقارنة reduction of amides و + +429 +00:37:54,080 --> 00:37:58,380 +reduction of esters primary amines و primary + +430 +00:37:58,380 --> 00:38:07,200 +alcoholكما يبدو انه بعد هي قصة طويلة .. بعد هي قصة + +431 +00:38:07,200 --> 00:38:12,500 +طويلة بيصير مستاهل ان الواحد ايش؟ اريح راسه من + +432 +00:38:12,500 --> 00:38:16,060 +الصداع تبع الامدس وغيره وغيراته، الان اللي بده + +433 +00:38:16,060 --> 00:38:21,240 +يريح راسه، ايش بده يعمل؟ بده يشوف أنثلة تطبيقية + +434 +00:38:21,240 --> 00:38:26,520 +على الموضوع، يا بده ياخدله حبة أسبيرين، الأسبيرين + +435 +00:38:26,520 --> 00:38:32,420 +Easteracetosalicylic acid يا حبة إيش لو اتطلعنا + +436 +00:38:32,420 --> 00:38:37,620 +معظمكم معاكم اللي احنا بنسميه الacamol الacamol + +437 +00:38:37,620 --> 00:38:44,060 +هشكله هذا الacamol اللي احنا بنستعمله للصداع و + +438 +00:38:44,060 --> 00:38:50,830 +للسخونة antibiotic إيش معنى antibioticحطوا هنا R + +439 +00:38:50,830 --> 00:38:57,150 +Antipyretic مضاد للسخونة Pyretic حراري مضاد + +440 +00:38:57,150 --> 00:39:04,990 +للحرارة و Analgesic مضاد للصدع او ضد الصدع الان لو + +441 +00:39:04,990 --> 00:39:09,490 +اتيت قلتلكوا ال Acetosalicylic acid is an .. + +442 +00:39:09,490 --> 00:39:13,090 +اتطلعوله على المجموعة الوظيفية الأساسية تبعته E + +443 +00:39:13,090 --> 00:39:15,630 +star الان ال Acamol + +444 +00:39:23,230 --> 00:39:28,290 +الأكمون ممكن تلاقوه باسمين ممكن تلاقوه مكتوب على + +445 +00:39:28,290 --> 00:39:33,310 +علب الأدوية باسمين احد دول الاسمين انه انا لو اتيت + +446 +00:39:33,310 --> 00:39:35,150 +اطلعت هذه المجموعة ايش + +447 +00:39:40,820 --> 00:39:45,280 +فينول وبناء على ذلك ممكن تلاقوه ينكتب تحت عائلة + +448 +00:39:45,280 --> 00:39:54,580 +عامة أسيت أمينوفين لاحظوا أسيت أمينوفين من الأسيتل + +449 +00:39:54,580 --> 00:40:00,980 +والأمينو والفينول أسيت أمينوفين واضحة أسيت + +450 +00:40:00,980 --> 00:40:05,980 +أمينوفين بس اللي منكم اتذكره أكتر دائما على بكية + +451 +00:40:05,980 --> 00:40:11,210 +الأكامول بيكون مكتوب خمسمية ملي جرام إشبراسيتامول + +452 +00:40:11,210 --> 00:40:20,090 +برا سيتامول الان لو اجينا نطبق ال بارا أسيتامول + +453 +00:40:20,090 --> 00:40:28,350 +على نفس شكل الأكامول بارا لأن هدولة جايين بالنسبة + +454 +00:40:28,350 --> 00:40:41,230 +لبعضهم بارا صح ولا لأ أسيت لأن هايالـ Acetamol هى + +455 +00:40:41,230 --> 00:40:52,370 +الأمين وهى الأول بارا + +456 +00:40:52,370 --> 00:40:57,570 +أسيتامول + +457 +00:40:57,570 --> 00:41:03,130 +فبتلاحظوا أن عندكم 500 ميلي جرام براسيتامول بحبة + +458 +00:41:03,130 --> 00:41:09,150 +الدواءواضحة الفكرة براستامول الان لو غيروا فيه + +459 +00:41:09,150 --> 00:41:13,310 +البراستامول ذرة صغيرة بدل ما دي O H صارت O ethyl + +460 +00:41:13,310 --> 00:41:18,610 +بيصير في ناسي تين برضه انا الجسك بيشبه الأكامول + +461 +00:41:18,610 --> 00:41:22,330 +لكن المشهور أكثر الأكامول وإن كان التوصي أن + +462 +00:41:22,330 --> 00:41:26,710 +الأكامول برضه بيغلب مع الكلية التخلص منه يعني بدون + +463 +00:41:26,710 --> 00:41:31,460 +سبب مايكونش كل يوم حبتين أكاموليعني فقط لحالات + +464 +00:41:31,460 --> 00:41:35,460 +الصداع و بإشراف طبي ممكن تتعاملوا معاه أما ناس + +465 +00:41:35,460 --> 00:41:38,360 +يقولوا و الله كل ما بدنا ندروا الصفحتين بدنا ناخد + +466 +00:41:38,360 --> 00:41:42,580 +جماله و نحطين أكامول بيخربوا الكلية تاعتهم واضح؟ + +467 +00:41:42,580 --> 00:41:47,920 +يعني نفس الأكامول أو البراسيتامول ماتاخدهوش بدون + +468 +00:41:47,920 --> 00:41:53,020 +إيش بدون وصفة طبية و بدون لزوم إنما على الحامل على + +469 +00:41:53,020 --> 00:41:55,480 +البارد كل ما بدنا ندروا الصفحة نروح ناخدلنا حبة + +470 +00:41:55,480 --> 00:42:00,700 +أكامول هذه تعتبر مأساةطبعاً في أشياء تانية فرمونات + +471 +00:42:00,700 --> 00:42:04,260 +بنسميها برضه أشياء تطبيقية على ال e-stars و ال + +472 +00:42:04,260 --> 00:42:08,220 +emits بهيك بننهي اليوم و ان شاء الله المرة القادمة + +473 +00:42:08,220 --> 00:42:12,280 +بنبدأ في chapter ال emits + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..d95dd93f77dde0b3faa58bc5545f755e70b8649f --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/UZrkW5alTIE_postprocess.srt @@ -0,0 +1,1504 @@ +1 +00:00:19,940 --> 00:00:25,100 +بسم الله الرحمن الرحيم اليوم بنبتدأ في الفصل + +2 +00:00:25,100 --> 00:00:29,820 +المكمل خلينا نقول للالديهيدس والكيتونز اللي هو ال + +3 +00:00:29,820 --> 00:00:33,940 +carboxylic acids and their derivatives طبعا ليش + +4 +00:00:33,940 --> 00:00:38,900 +احنا قولنا الفصل المكمل لأن كل هذه المجموعة من + +5 +00:00:38,900 --> 00:00:42,240 +المركبات هي ال carbonyl containing compounds + +6 +00:00:42,240 --> 00:00:46,980 +المركبات يعني اللي فيها مجموعة السيضة بال bond O + +7 +00:00:47,750 --> 00:00:51,810 +صنفنا ال الديهيدز والكيتونز لوحدنا وقلنا هدولة + +8 +00:00:51,810 --> 00:00:56,810 +جماعة ال addition او الإضافة الآن بيجي عند + +9 +00:00:56,810 --> 00:01:01,330 +الكاربوكسيليك أسدوبنقول عن المراكبات التانية + +10 +00:01:01,330 --> 00:01:04,290 +derivatives of carboxylic acids مشتقة من ال + +11 +00:01:04,290 --> 00:01:08,770 +carboxylic acids بمعنى تبدل فيها مجموعة ال OH + +12 +00:01:08,770 --> 00:01:14,770 +بمجموعة تانية فإذا أبدلت ب OR بيصير Easter إذا + +13 +00:01:14,770 --> 00:01:20,190 +أبدلت ب NH2 و لا NHR بيصير Amid إذا أبدلت بCL أو + +14 +00:01:20,190 --> 00:01:24,310 +بR بيصير Acid Halide Acid chloride or bromide إذا + +15 +00:01:24,310 --> 00:01:27,490 +أبدلت بOC double bond O بيصير Acid anhydride + +16 +00:01:27,490 --> 00:01:34,570 +فبنقول إحناCarboxylic Acids and their derivatives + +17 +00:01:34,570 --> 00:01:40,630 +و لذلك لو أتينا مثلا سألناكوا السؤال E stars are + +18 +00:01:40,630 --> 00:01:45,450 +Carboxylic Acid derivatives صح Acid chlorides are + +19 +00:01:45,450 --> 00:01:48,070 +Carboxylic Acid derivatives صح لكن لو مثلا + +20 +00:01:48,070 --> 00:01:51,870 +قلنالكوا E stars are Carboxylic Acid derivatives + +21 +00:01:51,870 --> 00:01:57,050 +no aldehydes or ketones or alcohol واضح فاللي + +22 +00:01:57,050 --> 00:02:04,490 +بنقصده بال derivative كم نوعأربعة أستر أمد أسد + +23 +00:02:04,490 --> 00:02:12,370 +كلورايد و أسد أنهايدرايد الأسد + +24 +00:02:12,370 --> 00:02:15,950 +أنهايدرايد الأسد أنهايدرايد ماخد الصيغة العامة + +25 +00:02:15,950 --> 00:02:18,730 +الاتية R C double bond O + +26 +00:02:34,410 --> 00:02:35,810 +وووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو + +27 +00:02:50,150 --> 00:02:56,550 +طبعا دائما اول ما بنبدأ بنبدأ باش بتسمية العائلات + +28 +00:02:56,550 --> 00:03:01,890 +و احنا اتفقنا ان التسمية في النظام ال IUPAC تسمية + +29 +00:03:01,890 --> 00:03:07,630 +سهلة اهم فيها معرفة اطول سلسلة و نعرف ايش العائلة + +30 +00:03:07,630 --> 00:03:11,410 +بناء على الترتيبات اللي اتعلمناها سابقا الان لما + +31 +00:03:11,410 --> 00:03:17,230 +تكون العائلة الأحماض بنحط النهاية oic acid واضح + +32 +00:03:17,230 --> 00:03:22,830 +فالنهاية اللي بدنا نضيفها شو هيoic acid يعني لو + +33 +00:03:22,830 --> 00:03:29,270 +كان مع carbon واحدة إيش هنقول المركب مثال oic acid + +34 +00:03:29,270 --> 00:03:34,930 +carbon 2 إيثانويك أسد بروبانويك أسد بيوتانويك أسد + +35 +00:03:34,930 --> 00:03:39,730 +and so on ولذلك هذا المركب مثلا و العاد دائما + +36 +00:03:39,730 --> 00:03:43,730 +بيكون من عند ال acid ال acid دائما موجود على نمرة + +37 +00:03:43,730 --> 00:03:48,670 +واحد ولذلك مابنكتبش one oic acid لأ بس acid يعني + +38 +00:03:48,670 --> 00:03:54,420 +مثلا هذا المركبواحد، اتنين، تلاتة، اربعة، خمسة، + +39 +00:03:54,420 --> 00:03:58,900 +ستة دائما الحاجة اللي مكتوبة بين قسيل معناه انه + +40 +00:03:58,900 --> 00:04:03,860 +هذه معلجة واضح؟ يعني لما انا اكون هنا كاتب CH بين + +41 +00:04:03,860 --> 00:04:10,990 +قسيل CH3 معناه ذلك هذه ال CH3 معلجة هناواضح ايش + +42 +00:04:10,990 --> 00:04:14,050 +تفسيرها لما بكتبها بين قوسين بس لإن انا بكتب على + +43 +00:04:14,050 --> 00:04:19,410 +السطر بقدرش ا في برنامج الطباعة اطلع خط زي هيك و + +44 +00:04:19,410 --> 00:04:24,430 +ارسم زي هيك فبحط بين قوسين و بكتب CH3 فاللي موجودة + +45 +00:04:24,430 --> 00:04:27,910 +في داخل السلسلة بين قوسين يعني معلجة على المجموعة + +46 +00:04:27,910 --> 00:04:34,350 +اللي قبلها الان هذا المركب اكيد hexanoic acid على + +47 +00:04:34,350 --> 00:04:40,340 +نمرة تلاتة ال hexanoic acid شو بيحمل؟مثل فبصير + +48 +00:04:40,340 --> 00:04:44,040 +three methyl hexanoic acid + +49 +00:04:49,490 --> 00:04:54,850 +زي ما اتفقنا احنا ان الأحماض بالتدريج هتمشي مثانوك + +50 +00:04:54,850 --> 00:04:58,770 +ايثانوك بروبانوك بيوتانوك بنتانوك هكسانوك هبتانوك + +51 +00:04:58,770 --> 00:05:05,670 +اكتانوك نونا نوك ديكانوك ديكان يعني عشرة الان هذه + +52 +00:05:05,670 --> 00:05:10,910 +الأحماض لها أسماء شهرة هذه الأحماض لها أسماء شهرة + +53 +00:05:10,910 --> 00:05:15,890 +أقل تقدير نسمع فيها لمرة و نعرف أبسط اتنين او + +54 +00:05:15,890 --> 00:05:21,470 +تلاتة منهاالحمض اللي من كاربون واحدة formic acid + +55 +00:05:21,470 --> 00:05:27,310 +واضح؟ اللي من تنتين acidic acid اللي في مجموعة ال + +56 +00:05:27,310 --> 00:05:32,390 +acid اللي أخدناها تلاتة probionic بنقولش probionic + +57 +00:05:32,390 --> 00:05:38,470 +بروبانوك الاربعة بيوتانوك بيوتاريكبيوتاريك أسد + +58 +00:05:38,470 --> 00:05:42,390 +بعدين بيجي الخامسة Valeric و بعدين Caproic, + +59 +00:05:42,510 --> 00:05:46,950 +Enanthic, Caprylic, Pelargonic, Capric طبعا مش + +60 +00:05:46,950 --> 00:05:50,870 +ضرور نحفظها الأسماء لكن أقل تقدير يكون اسمعناها + +61 +00:05:50,870 --> 00:05:54,650 +مرة يعني لو في يوم من الأيام لجينا انه اخلط ال + +62 +00:05:54,650 --> 00:05:59,070 +Valeric acidنجي نتذكر شو ال valeric acid نفتح + +63 +00:05:59,070 --> 00:06:02,830 +الكتاب أو ال net نتذكر أن ال valeric acid هو ال + +64 +00:06:02,830 --> 00:06:06,730 +pentanoic acid واضح؟ بس أكيد أقل تقدير لما نقول + +65 +00:06:06,730 --> 00:06:11,850 +ethanoic acid هو ال acetic acid, methanoic acid هو + +66 +00:06:11,850 --> 00:06:15,630 +ال formic acid اللي أساسا جاي من وين ال formic + +67 +00:06:15,630 --> 00:06:20,930 +acid؟ من ال antsاللي هي باللاتيني formica يعني من + +68 +00:06:20,930 --> 00:06:25,770 +النمل هو الحمب اللي النملة لما بتجرس بتحطه بالإيد + +69 +00:06:25,770 --> 00:06:31,150 +عشان هيك القرص بيكون مؤلم واضح؟ يعني النملة لما + +70 +00:06:31,150 --> 00:06:37,170 +بتعمل قرص للبني آدم بتبخ شوية formic acid هذا اللي + +71 +00:06:37,170 --> 00:06:43,630 +بيسبب القلم عند الإنسان واضح؟ + +72 +00:06:45,960 --> 00:06:49,860 +هذه أمثلة إضافية على تسمية ال assets واضح أنه + +73 +00:06:49,860 --> 00:06:53,960 +الأساس البحث عن أطول سلسة و الترقيم من عند ال c + +74 +00:06:53,960 --> 00:06:57,640 +double bond o يعني نمرة واحد هي إيش ال c double + +75 +00:06:57,640 --> 00:07:03,020 +bond o الآن انتبهوا لخطأ شائع بصره الطلاب جد ما + +76 +00:07:03,020 --> 00:07:06,420 +بتعد معهم إنهم يخطئوا فيه إنه أول ما يشوفوا c + +77 +00:07:06,420 --> 00:07:11,700 +double bond oبياخدوا هذا الجزء و بيقولوا CWO على + +78 +00:07:11,700 --> 00:07:16,040 +الطرف إذا هذا الديهايد و الديهايد على نمر واحد + +79 +00:07:16,040 --> 00:07:19,600 +حامل مجموعة هيدروكسي فبيجوا يقولون one + +80 +00:07:19,600 --> 00:07:26,660 +hydroxybutanol طبعا إذا التقت ال CWO مع ال OH خلاص + +81 +00:07:26,660 --> 00:07:33,030 +أصبحت المجموعة الوظيفية هي هذه كاملةو كلها كاملة + +82 +00:07:33,030 --> 00:07:37,170 +بتعطي نهاية ايش اوك اسد لما اجي اقول واحد اتنين + +83 +00:07:37,170 --> 00:07:40,250 +تلاتة اربعة اربعة اربعة اربعة اربعة اربعة اربعة + +84 +00:07:40,250 --> 00:07:46,130 +اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة + +85 +00:07:46,130 --> 00:07:51,210 +اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة + +86 +00:07:51,210 --> 00:07:52,450 +اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة + +87 +00:07:52,450 --> 00:07:53,030 +اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة + +88 +00:07:53,030 --> 00:07:53,550 +اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة + +89 +00:07:53,550 --> 00:07:56,910 +اربعة اربعة اربعة اربعة اربعة اربعة اربEthyl to + +90 +00:07:56,910 --> 00:08:02,530 +Ethyl butanoic acid هنا مثلا بالزويك أسد حامل + +91 +00:08:02,530 --> 00:08:07,890 +الكلور علىال بارا position أو ال four position مر + +92 +00:08:07,890 --> 00:08:12,870 +علينا مثل هذا المركب لحظو هنا عندنا مجموعة وظيفية + +93 +00:08:12,870 --> 00:08:18,110 +واحدة اللي هي مجموعة الاش ال acid لكن لو انتقل ال + +94 +00:08:18,110 --> 00:08:21,430 +acid مع ال الديهايد او ال كيتون او كذا مين اللي + +95 +00:08:21,430 --> 00:08:25,630 +الاولوية ال acid اعلى من ال الديهايد اعلى من ال + +96 +00:08:25,630 --> 00:08:31,430 +كيتون اعلى من ال alcohol كل شيء هينسبلهالان لو يا + +97 +00:08:31,430 --> 00:08:37,270 +ترى كان عندى اكثر من acid لو كان عندى اكثر من acid + +98 +00:08:37,270 --> 00:08:41,790 +ممكن على السلسلة على الطرفين يكون على هذا الطرف + +99 +00:08:41,790 --> 00:08:46,230 +مجموعة acid وعلى هذا الطرف مجموعة acid واضح؟ ممكن + +100 +00:08:46,230 --> 00:08:52,770 +يكون اكثر من مجموعتين كمان اكيد لو كان عندى تفرعات + +101 +00:08:52,770 --> 00:08:57,590 +يعني لو كان عندى مثل هذا مثل هذه السلسلة ممكن + +102 +00:08:57,590 --> 00:09:04,870 +احطها لمجموعة acidc double bond o o h ممكن احط هنا + +103 +00:09:04,870 --> 00:09:11,170 +مجموعة acid ممكن احط هنا مجموعة acid واضح يعني + +104 +00:09:11,170 --> 00:09:16,150 +ممكن مجموعة مجموعتين تلاتة اربعة لو صار عندى + +105 +00:09:16,150 --> 00:09:20,550 +تفارعات كله وارد طب الآن لما بيصير عندى اكثر من + +106 +00:09:20,550 --> 00:09:26,750 +مجموعة ايش بدي اسمه بدل ما بدي اقول awake لما + +107 +00:09:26,750 --> 00:09:35,110 +يصيروا تنتين die awakeDioic acid فهنا لما يكونوا + +108 +00:09:35,110 --> 00:09:38,510 +carbon 2 هل ممكن ع carbon واحدة نحط two acids + +109 +00:09:38,510 --> 00:09:46,230 +مستحيل فأبسط حامض diacid هو اللي ع carbon 2 بيكون + +110 +00:09:46,230 --> 00:09:52,250 +اسمه ethanedioic acid ethanedioic acid هذا ماخد + +111 +00:09:52,250 --> 00:09:58,230 +اسم الشهرة oxalic acid لو صاروا تلاتةيعني هي ع + +112 +00:09:58,230 --> 00:10:03,710 +الطرف وع الطرف مجموعة حامض بيصير إيش بروبان ديويك + +113 +00:10:03,710 --> 00:10:08,690 +أسد ماخد اسم شورا مالونك أسد بعدين بيوتان ديويك + +114 +00:10:08,690 --> 00:10:14,940 +أسد ساكسينك بنتان هكسان هبتينDioic acid، glutaric، + +115 +00:10:14,940 --> 00:10:19,920 +adibic بملك، أسماء شهراء كثيرة موجودة، أقل تقدير + +116 +00:10:19,920 --> 00:10:23,980 +خلّينا نعرف ال aiobacnine، ال aiobacnine بستعمل + +117 +00:10:23,980 --> 00:10:30,960 +كلمة إيش؟ Dioic acid، بستعمل كلمة Dioic acid، و + +118 +00:10:30,960 --> 00:10:35,470 +أبسط Dioic acid زي ما قولنا إيش؟ال oxalic acid .. + +119 +00:10:35,470 --> 00:10:40,250 +ال oxalic acid كويس تعرفوه يعني طالما .. طالما + +120 +00:10:40,250 --> 00:10:47,010 +انتوا تحاليل طبية لما تبدأوا تدرسوا في ال urine في + +121 +00:10:47,010 --> 00:10:52,530 +ال bowl الأملاح وبعد هيك الأملاح هذه بدأت تعمل + +122 +00:10:52,530 --> 00:10:58,110 +حصوات في الكيليةهتلاحظوا ان جزء أساسي ان الحصوات + +123 +00:10:58,110 --> 00:11:03,550 +اما بده تكون صلبة جدا من ال oxalic acids او من ال + +124 +00:11:03,550 --> 00:11:08,850 +oxalic acid salts او من ال phosphates واضح فلما + +125 +00:11:08,850 --> 00:11:14,950 +نيجي نقول حصوات من ال oxalic acids او من ال salts + +126 +00:11:14,950 --> 00:11:21,180 +طبعا ال salt هيكون O minusالان هذه ال salts جزء من + +127 +00:11:21,180 --> 00:11:24,780 +أبيعمال حصواته و لذلك هتصيروا تقولوا oxalic acid + +128 +00:11:24,780 --> 00:11:29,760 +salts أملاح ال oxalic acid بتشوفوا بلوراتها تحت + +129 +00:11:29,760 --> 00:11:33,320 +الميكروسكوب فلما تكونوا تسمعوا oxalic acid و أنتوا + +130 +00:11:33,320 --> 00:11:37,160 +قاعدين بتحلله و بتحددوا شنوع الأملاح اللي عاملة + +131 +00:11:37,160 --> 00:11:42,100 +الحصوات و إشي أقل تقدير يضالوا في بالكوا انه مار + +132 +00:11:42,100 --> 00:11:49,980 +عليكم ال oxalic acid is a dyeواضح؟ من كم كربون؟ من + +133 +00:11:49,980 --> 00:11:56,060 +كربون تاني هنا + +134 +00:11:56,060 --> 00:12:01,260 +زى ما قلنا بيوتين ديويك أسد طيب لو صار عندى ال + +135 +00:12:01,260 --> 00:12:06,920 +triple bondلاحظوا هنا أصبح أكتر من مجموعة وظيفية + +136 +00:12:06,920 --> 00:12:12,120 +اويك أسد فى عندى منه تانين و triple bond اذا هنا + +137 +00:12:12,120 --> 00:12:17,640 +هنعد العدد لكل واحد اتنين تلاتة اربعة بيوتاين + +138 +00:12:17,640 --> 00:12:21,940 +دايويك أسد لاحظوا ان ال triple bond عبّرت عنها + +139 +00:12:21,940 --> 00:12:29,020 +بإيش ب I بيوتاين دايويك أسد طبعا لما بيكون عندى + +140 +00:12:29,020 --> 00:12:35,180 +triple bond مافيش عندى قصة إيشالسيس والترانس لانقص + +141 +00:12:35,180 --> 00:12:38,780 +السيس والترانس موجودة في ال double bonds او في + +142 +00:12:38,780 --> 00:12:44,740 +الحلقات وبناء على ذلك لو اتيت على بيوتين ديويك اسد + +143 +00:12:44,740 --> 00:12:50,120 +high carbon تنتين تلاتة اربعة اذا حطيت مجموعتين ال + +144 +00:12:50,120 --> 00:12:56,920 +acid على جهة واحدة هذا السيس واحد اتنين تلاتة + +145 +00:12:56,920 --> 00:13:02,180 +اربعة اتو بيوتين ديويك اسد ماخد اسم malic acid + +146 +00:13:02,830 --> 00:13:07,910 +ماليك لاحظوا ما بنقرأش مالك لأنه الملك أسد حامض + +147 +00:13:07,910 --> 00:13:19,010 +تاني بدون ال E ماليك هذه ال E تبعت ال الكيل ماليك + +148 +00:13:19,670 --> 00:13:24,190 +الـ E تبعت الالكيد الان لو هذول المجمعتين في ال + +149 +00:13:24,190 --> 00:13:28,790 +بيوتينويك أسد اجوا عكس بعض ال trans يعني كان + +150 +00:13:28,790 --> 00:13:31,830 +المركب واحد اتنين تلات اربع ال trans to + +151 +00:13:31,830 --> 00:13:37,370 +بيوتيندايويك أسد و اجت ايش بنسميه فيوماريك أسد + +152 +00:13:37,370 --> 00:13:41,890 +فيوماريك أسد هذه أحماض مشهورة المفروض تحفظوها يعني + +153 +00:13:41,890 --> 00:13:46,530 +لو قلنالكم ماليك أسد و فيوماريك أسد المفروض تكونوا + +154 +00:13:46,530 --> 00:13:51,620 +عارفين من فيهم السس الماليكمن ال Trans الفيومارك + +155 +00:13:51,620 --> 00:13:55,240 +واحد منهم بيجيبوه من التفاح والتاني بيجيبوه من + +156 +00:13:55,240 --> 00:14:01,140 +الحيوانات من الأغنام ويمكن عشان هيك لو بتطلعوا على + +157 +00:14:01,140 --> 00:14:07,080 +غلاف الكتاب غلاف كتاب heart بتلاحظوا في صورة تفاحة + +158 +00:14:07,080 --> 00:14:13,160 +خضرة اذا بعض الناس انتبهوا للغلاف هذا واحد من + +159 +00:14:13,160 --> 00:14:16,500 +الأحماض انسيت المليك او الفيومارك من التفاح + +160 +00:14:16,500 --> 00:14:22,180 +بتقولوا واضح؟الان لو يا ترى البنزينة كان عليها + +161 +00:14:22,180 --> 00:14:26,820 +اكثر من ascent يعني + +162 +00:14:26,820 --> 00:14:32,240 +die ascent كام احتمال ممكن يكون ممكن اتنين يكونوا + +163 +00:14:32,240 --> 00:14:36,460 +جانب بعض يعني one two die substituted بنزين ممكن + +164 +00:14:36,460 --> 00:14:39,820 +يكونوا واحد اتنين تلاتة وممكن يكونوا واحد اتنين + +165 +00:14:39,820 --> 00:14:44,200 +تلاتة اربعة اذا المجموعتين حامض على البنزينة ممكن + +166 +00:14:44,200 --> 00:14:49,390 +تكون علاقة بينهم one twoاو one three او one four + +167 +00:14:49,390 --> 00:14:54,970 +الان كل واحد من هدوله له اسم ال one two بنسميه + +168 +00:14:54,970 --> 00:14:59,450 +ifthalic acid و ال one three isophthalic acid و ال + +169 +00:14:59,450 --> 00:15:04,470 +one four teraphthalic acid اقل تقدير بدكوا تحفظه + +170 +00:15:04,470 --> 00:15:09,790 +لانه يعود يتكرر معنا ال ifthalic acidواضح؟ لأنه + +171 +00:15:09,790 --> 00:15:13,250 +منه هنعمل phthalic anhydride المليك أسد منه هنعمل + +172 +00:15:13,250 --> 00:15:17,530 +مليك أنهيدريد يعني هيعود مر معنى لما ندرس + +173 +00:15:17,530 --> 00:15:21,810 +الانهيدريد مليك أنهيدريد و phthalic anhydride + +174 +00:15:21,810 --> 00:15:26,570 +فالمليك أسد الأربعة اللي فيهم دابل بوند و سيس + +175 +00:15:26,570 --> 00:15:32,270 +الفثالك أسد داي أسد على البنزين أورثو جايين + +176 +00:15:32,270 --> 00:15:35,630 +المجموعتين to each other يعني العلاقة بينهم one + +177 +00:15:35,630 --> 00:15:42,670 +twoالان ال physical properties of carboxylic acids + +178 +00:15:42,670 --> 00:15:50,310 +الكلام يشبه الكحولات لكن خلنا نقول يعني في + +179 +00:15:50,310 --> 00:15:53,990 +hydrogen bonding في ال acids ال hydrogen bonding + +180 +00:15:53,990 --> 00:15:57,990 +في ال acids بيعمل solubility in water لكن بيضل + +181 +00:15:57,990 --> 00:16:05,090 +بشكل عام ان الحامض هو عبارة عن R وC double bond O + +182 +00:16:06,090 --> 00:16:12,950 +OH بمعنى زي ما كان الكحول ايش كان الكحول خلينا + +183 +00:16:12,950 --> 00:16:19,170 +نقول CH2OH الآن في الكحول اتفقنا انه في جزء polar + +184 +00:16:19,170 --> 00:16:24,990 +و في جزء non polar الآن الحامض نفس الاشي جزء polar + +185 +00:16:24,990 --> 00:16:31,760 +و جزء non polarnon-polar اللي هي ال R و لذلك لو + +186 +00:16:31,760 --> 00:16:35,600 +اجيلا نحكي عن ال solubility in water ال solubility + +187 +00:16:35,600 --> 00:16:39,160 +in water بنقول ان ال low alcohols are water + +188 +00:16:39,160 --> 00:16:43,260 +soluble كل ما ال R كبرت بتقلل ال solubility الان + +189 +00:16:43,260 --> 00:16:48,700 +نفس الجملة بنكررها ال low acids are water soluble + +190 +00:16:48,700 --> 00:16:51,620 +معناه low acids يعني اللي فيهم ال R صغيرة كربونا + +191 +00:16:51,620 --> 00:16:55,380 +تنتين تلاتة هدول بيدوبوا في الميه يعني مثلا ال + +192 +00:16:55,380 --> 00:17:00,290 +acetic acid كام كربونا بالمجملتلتين ال .. ال + +193 +00:17:00,290 --> 00:17:05,290 +acetic acid الخل بدوب في الميه عمرا واحد عملة مخلل + +194 +00:17:05,290 --> 00:17:11,310 +مش بتحطوا شوية خل عليها هو ال acetic acid حتى الخل + +195 +00:17:11,310 --> 00:17:14,870 +اللي بتشتريوه من السوق هو عبارة عن ال acetic acid + +196 +00:17:14,870 --> 00:17:20,710 +مدوب في الميه بنسبة بسيطة 4-5% واضح؟ فبنقول احنا + +197 +00:17:20,710 --> 00:17:25,610 +ان ال acids و ال alcohols both are polarو بناء على + +198 +00:17:25,610 --> 00:17:28,770 +ذلك الـ low acids and low alcohols are water + +199 +00:17:28,770 --> 00:17:32,850 +soluble كلما ال chain كبرت كلما ال solubility + +200 +00:17:32,850 --> 00:17:38,710 +اشمالها بتقل الان وجود ال OH بتعمل hydrogen + +201 +00:17:38,710 --> 00:17:43,630 +bonding وبناء على ذلك الأحماض والكحولات بشكل عام + +202 +00:17:43,630 --> 00:17:48,630 +نقاط غليانهم اشمالها مرتفعة لأن هان و هان في عنده + +203 +00:17:49,330 --> 00:17:53,990 +hydrogen bonding يعني تطلعوا انتوا مثلا ال acetic + +204 +00:17:53,990 --> 00:17:59,490 +acid كربونتين ال boiling point تبعته كده؟ مية و + +205 +00:17:59,490 --> 00:18:05,030 +تمانتاش عالية جدا ال ethanol كان تمانية و سبعين ال + +206 +00:18:05,030 --> 00:18:07,750 +probionic acid مية و واحد و اربعين ال butanoic + +207 +00:18:07,750 --> 00:18:11,290 +acid مية و اربعة و ستين بعد هيك الأحماض بتبدأ + +208 +00:18:11,290 --> 00:18:17,410 +تقترب تصير solidواضح الفكرة فالارتفاع في ال + +209 +00:18:17,410 --> 00:18:21,230 +boiling point النسبي و اكيد في ال melting point هو + +210 +00:18:21,230 --> 00:18:28,130 +سببه ال hydrogen bonding الان بتجينا صفة تانية + +211 +00:18:28,130 --> 00:18:34,050 +اللي هي ال acidity ال acidity متعلقة بإيش؟بال اتش + +212 +00:18:34,050 --> 00:18:38,190 +الموجودة على ال oxygen يعني هذه الاتش انها تفقد + +213 +00:18:38,190 --> 00:18:42,150 +ويتكون هنا عندي ايون سالم او تفقد هنا ويتكون عندي + +214 +00:18:42,150 --> 00:18:46,350 +هنا ايون سالم قلنا احنا ان ال alcohols they are in + +215 +00:18:46,350 --> 00:18:52,150 +general acidic و ال carboxylic acid acidic لكن جدش + +216 +00:18:52,150 --> 00:18:56,850 +ال bk ايه لل alcohol اذا انتم متذكرين تقريبا ال + +217 +00:18:56,850 --> 00:19:01,970 +alcohols العادية مثانول اثانولكانت خمس طائش، ست + +218 +00:19:01,970 --> 00:19:07,790 +طائش، الآن ال carboxylic acids أقوى كتير ال BKA + +219 +00:19:07,790 --> 00:19:12,770 +تبعتهم حوالي أربع على خمسة مين أقوى كتير ال + +220 +00:19:12,770 --> 00:19:16,430 +carboxylic acids ولا الكحولات المناظرة أو الكحولات + +221 +00:19:16,430 --> 00:19:22,410 +بشكل عام؟ ال carboxylic acids، إيش السبب؟ حكيناها + +222 +00:19:25,810 --> 00:19:29,770 +الـ H فقدت الله يرحمها، ضال الايون السالب لما + +223 +00:19:29,770 --> 00:19:33,710 +اتكلمنا عن ال acidity of acids قلنا بدنا ننظر + +224 +00:19:33,710 --> 00:19:39,510 +لثبات الايون السالب ال resonance هنا في resonance + +225 +00:19:39,510 --> 00:19:45,620 +مش هذا السالب ممكن يكون هناأه إذا ال acids they + +226 +00:19:45,620 --> 00:19:49,820 +are more acidic than alcohols or they have a lower + +227 +00:19:49,820 --> 00:19:55,460 +pka because of resonance ال charge in alcohol is + +228 +00:19:55,460 --> 00:20:01,940 +ايش وصفناها ثابتة في محلها مابتتنقلش حد يقوللي شو + +229 +00:20:01,940 --> 00:20:04,720 +الكلمة اللي استعملناها لهذه الشحنة اللي ثابتة في + +230 +00:20:04,720 --> 00:20:09,640 +محلها مابتتنقل لاحظوا اللي مابدرسوش مابحفظوش + +231 +00:20:09,640 --> 00:20:15,140 +المصطلحات localizedin its location ايش يعني + +232 +00:20:15,140 --> 00:20:20,420 +location في موقعها localized يعني ثابتة بموقعها + +233 +00:20:20,420 --> 00:20:26,470 +متمركزة localizedجاعدة بمحلة الانهاد اللي جاعدة + +234 +00:20:26,470 --> 00:20:31,970 +بتتنجل مرة هان و مرة هان و يعملالها resonance إيش + +235 +00:20:31,970 --> 00:20:39,450 +بنسميها؟ delocalized مرة هان و مرة هان و مرة هان و + +236 +00:20:39,450 --> 00:20:44,570 +مرة هان واضح؟ إذا وين ال charge localized و وين ال + +237 +00:20:44,570 --> 00:20:49,330 +delocalized؟localized في ال alcohols لأن مافيش + +238 +00:20:49,330 --> 00:20:53,570 +فيهم resonance delocalized قاعدة بتنقل شمال ويمين + +239 +00:20:53,570 --> 00:20:58,350 +في ال carboxylic acids لأن في جنبها C double bond + +240 +00:20:58,350 --> 00:21:04,130 +O فممكن يتم انتقال ال bond و الشحنة مرة بتكون هنا + +241 +00:21:04,130 --> 00:21:07,890 +و مرة بتكون هنا انا بتقول كل هذا ال resonance سبق + +242 +00:21:07,890 --> 00:21:12,130 +ان اوضحناه بشكل كامل لما حكينا ال alcohol بحاجة + +243 +00:21:12,130 --> 00:21:17,400 +لإنكم تتبعوه فال resonance هو سببالحمضية الزايدة + +244 +00:21:17,400 --> 00:21:22,700 +للاسدس ولذلك الكربوكسليك اسدس الآن بنقدرش نسيبهم + +245 +00:21:22,700 --> 00:21:27,920 +ينكبوا على أيدنا يعني الكحولات ال BKA بتاعتهم 15 + +246 +00:21:27,920 --> 00:21:31,280 +-16 زي الميه مش مشكلة لو اجوا على أيدنا و غسلنا + +247 +00:21:31,280 --> 00:21:36,100 +فيهم و بيوتلوا البكتيريا بس ماحدش عمره يجرب يغسل + +248 +00:21:36,100 --> 00:21:41,160 +بمحلول حتى كربوكسليك اسدس و لو بنسميها weakيعني في + +249 +00:21:41,160 --> 00:21:46,200 +نهاية أحمار ضعيفة بالنسبة لل HCl وبالنسبة لل H2SO4 + +250 +00:21:46,200 --> 00:21:52,120 +لكن بتظهر أقوى كتير من الكحولات وبتظهر تحرق + +251 +00:21:52,120 --> 00:21:57,700 +الإيدين واضح؟ طيب + +252 +00:22:04,580 --> 00:22:08,520 +كل موضوع ال acidity و كتاب الثابت ال acidity و ما + +253 +00:22:08,520 --> 00:22:12,800 +إلى ذلك اتعلمناه و اننا نتطلع على ال BKA لاحظوا + +254 +00:22:12,800 --> 00:22:17,100 +لما نتطلع على ال BKA اتطلعوا مثلا ال formic acid + +255 +00:22:17,100 --> 00:22:20,560 +تلاتة و ستة ال acetic acid اربعة و سبعة ال + +256 +00:22:20,560 --> 00:22:24,480 +probionic acid اربعة و تمانية زي ما حكينا تقريبا + +257 +00:22:24,480 --> 00:22:29,740 +معظم هدول ال acids في منطقة ال ايش التلاتة اربعة + +258 +00:22:29,740 --> 00:22:35,390 +خمسةواضح؟ معظم هدول ال acid في 3,4,5 لاحظوا ال + +259 +00:22:35,390 --> 00:22:41,950 +alcohol عمل مقارنة هنا هاي كل ال acid تتطلع عليها + +260 +00:22:41,950 --> 00:22:49,750 +ال PKA تعتها قليلة 3,4 لكن ال phenol عشرة واخدنا + +261 +00:22:49,750 --> 00:22:53,790 +ليش ال phenol كانت ال acidity شوية مرتفعة تبعته + +262 +00:22:53,790 --> 00:22:59,460 +بسبب ال resonanceيا ريتنا خلناه في الامتحان + +263 +00:22:59,460 --> 00:23:05,440 +chapter 7 سبب ال resonance ال ethanol والميه + +264 +00:23:05,440 --> 00:23:14,240 +تقريبا ال BKA تبعهم زي بعض 16 15.5 منخفض الان في + +265 +00:23:14,240 --> 00:23:18,820 +جوا الأحماض او في جوا الكحولات لما نيجي نقول حامض + +266 +00:23:18,820 --> 00:23:25,950 +اقوى من حامضوقلنا بنفتش على السبب كام سبب طرحناهم + +267 +00:23:25,950 --> 00:23:32,650 +تلاتة يا ال resonance يا ال size يا ال inductive + +268 +00:23:32,650 --> 00:23:36,030 +effect الان تطلعوا هنا بتلاقوا هاي حامض سبحان الله + +269 +00:23:36,030 --> 00:23:42,590 +صار إيش ماله قوى أقوى كتير وهذا مشتاق من ال acetic + +270 +00:23:42,590 --> 00:23:50,360 +acid خلينا نرسمه هناسي دبل بوند او اتش اتراي كلور + +271 +00:23:50,360 --> 00:23:55,800 +و أسيتك أسل اه هذا أسيتك أسل حامل تلت مجموعات كلور + +272 +00:23:55,800 --> 00:23:59,440 +تخيلوا + +273 +00:23:59,440 --> 00:24:06,870 +انه لما بيصير ال ionization بتصير هذه O minusماذا + +274 +00:24:06,870 --> 00:24:11,930 +يحدث لدي هنا اي effect؟ Inductive effect ان هذه + +275 +00:24:11,930 --> 00:24:16,930 +الكلور تسحب جزء من الشحنة السالبة وهذه تسحب جزء من + +276 +00:24:16,930 --> 00:24:18,610 +الشحنة السالبة وهذه تسحب جزء من الشحنة السالبة هذا + +277 +00:24:18,610 --> 00:24:23,090 +ال effect Inductive فال Trichloroacetic acid is + +278 +00:24:23,090 --> 00:24:28,830 +stronger than اكيد ال Dichloro لاحظوا ال Dichloro + +279 +00:24:28,830 --> 00:24:37,560 +في تن تل بيسحبوا ال Trichloro الكلور واحدةالاسيتك + +280 +00:24:37,560 --> 00:24:43,220 +أسد مفيش عشان هيك شوفوا التدريج الاسيتك أسد ال PKA + +281 +00:24:43,220 --> 00:24:51,480 +74% لو حطينا له وان كلورين صار كداش 82 لو حطينا + +282 +00:24:51,480 --> 00:24:56,870 +تنتينواحد و تلاتة من عشرة لو حطينا تلاتة point + +283 +00:24:56,870 --> 00:25:01,030 +seven الكلام منطقي ولا لأ inductive effect بيزيد + +284 +00:25:01,030 --> 00:25:04,930 +اعلى اشي بيصير لما يكونوا تلاتة اقل لو كانوا تلتين + +285 +00:25:04,930 --> 00:25:09,470 +اقل لو كانوا واحدة كل هذا الكلام في تفصيل ال + +286 +00:25:09,470 --> 00:25:14,050 +acidity الحقيقة موازي تماما للكلام اللي انا اخدناه + +287 +00:25:14,680 --> 00:25:18,540 +في الكحولات موازي تماما للكلام اللي أخدناه في + +288 +00:25:18,540 --> 00:25:22,480 +الكحولات ال resonance effect و ال inductive effect + +289 +00:25:22,480 --> 00:25:28,800 +و طبعا لأن ال BKA عالية في نهاية الأحماض بتتفاعل + +290 +00:25:28,800 --> 00:25:37,130 +مع ال NiOH حمض زي قاعدة ملح زي دماغ واضح؟هي الحامض + +291 +00:25:37,130 --> 00:25:41,090 +زاد الاني و اتش ال او اتش مع ال اتش هتعمل H2O و + +292 +00:25:41,090 --> 00:25:46,130 +هيصير عندى ملح الحامض و اتعلمنا الاصل كيف بنسميهم + +293 +00:25:46,130 --> 00:25:53,310 +يعني لو بدنا ناخد كمثال حقيقي ال acetic acid لو + +294 +00:25:53,310 --> 00:25:57,510 +بدنا ناخد كمثال حقيقي اللى عادة بتعملوله titration + +295 +00:25:57,510 --> 00:26:06,280 +فى التجارب العملية اللى هوC H 3 C O O H زائد N A O + +296 +00:26:06,280 --> 00:26:13,580 +H مين اتنجلنا شو بدي اكتب المعادلة وقتها C H 3 C O + +297 +00:26:13,580 --> 00:26:25,460 +O O خلينا نقول هيك N A Plus زائد H 2 O الآن هذا + +298 +00:26:25,460 --> 00:26:27,900 +الناتج لما بدي اسميه كيف بسميه + +299 +00:26:33,060 --> 00:26:38,000 +صوديوم والمجموع اللى جاى من ال acetic acid اذا من + +300 +00:26:38,000 --> 00:26:43,560 +ال formic acid فورميت اذا من ال probionic acid + +301 +00:26:43,560 --> 00:26:48,220 +بروبانويت من ال butanoic acid بيوتانويت اذا + +302 +00:26:48,220 --> 00:26:52,360 +النهاية ات زى ما كنتوا تقولوا صلفيت و كربونيت و + +303 +00:26:52,360 --> 00:26:59,010 +نيتريت نهاية ات هي نهاية ال acid اذا صوديومacetate + +304 +00:26:59,010 --> 00:27:05,770 +فانا شيلت ال اك او ال او اك اسد و حطيت بدلها ايش + +305 +00:27:05,770 --> 00:27:11,880 +ات فال ات هذهنهاية الايون السالب Sodium Acetate + +306 +00:27:11,880 --> 00:27:16,340 +وسبق ان وضحنا لكم ايش معنى ال Acetyl group و ال + +307 +00:27:16,340 --> 00:27:20,180 +Acetate group و ال Acetic Acid قولنا لكم ان هذه + +308 +00:27:20,180 --> 00:27:25,700 +المجموعة لحالة شو اسمها AC Acetate لو حطينا لل O + +309 +00:27:25,700 --> 00:27:32,030 +صارت Acetate لو حطينا لل Hأسيتك أسد فالأسيتك أسد + +310 +00:27:32,030 --> 00:27:41,030 +اختصارا a-c-o-h واضح أسيتل أسيتيت مع الأكسجين + +311 +00:27:41,030 --> 00:27:42,330 +أسيتك أسد + +312 +00:28:02,030 --> 00:28:03,610 +اشمع له الجهاز + +313 +00:28:28,050 --> 00:28:34,830 +كيف بنحضر ال carboxylic acids زي ما بتلاحظوا في + +314 +00:28:34,830 --> 00:28:40,830 +عندنا مجموعة كبيرة من الطرق لتحضير ال carboxylic + +315 +00:28:40,830 --> 00:28:46,910 +acids ممكن نبدأ نستعرض بعضها الحقيقة البعض منها مر + +316 +00:28:46,910 --> 00:28:53,000 +علينا البعض منها مر علينا وبعضهاعبارة عن أشياء + +317 +00:28:53,000 --> 00:28:57,720 +جديدة اليوم احنا بناخد الشغلتين الخفاف اللي مروا + +318 +00:28:57,720 --> 00:29:02,000 +علينا و الأشياء الجديدة بنسيبهم للمرة القادمة + +319 +00:29:02,000 --> 00:29:06,780 +الشغلتين اللي مروا علينا لما أخدنا أكسدة ال + +320 +00:29:06,780 --> 00:29:13,540 +primary alcohols مين تذكرني إياها بجملة بسيطة جدا؟ + +321 +00:29:13,540 --> 00:29:19,870 +إيش حكينا في أكسدة ال primary alcohols؟قلنا اكسدت + +322 +00:29:19,870 --> 00:29:24,790 +ال primary alcohol بعمل مؤكسد خفيف بتعطيني ال + +323 +00:29:24,790 --> 00:29:30,330 +aldehyde واضح شو العمل المؤكسد الخفيف اللي بيحول + +324 +00:29:30,330 --> 00:29:36,310 +ال primary alcohol ل aldehyde بي سي سي الان طيب لو + +325 +00:29:36,310 --> 00:29:45,200 +ال primary alcohol استعملتله عامل مؤكسد قويبتحول ل + +326 +00:29:45,200 --> 00:29:48,540 +الديهايد و بيضلوا ماشي عدل ل ايش ل carboxylic + +327 +00:29:48,540 --> 00:29:52,420 +acids اذا ممكن انا اتحرك من ال primary alcohol ل + +328 +00:29:52,420 --> 00:29:57,960 +carboxylic acid باستعمال اي عامل مؤكسد كيامان او + +329 +00:29:57,960 --> 00:30:00,300 +فور و كيامان او فور و كيامان او فور و كيامان او + +330 +00:30:00,300 --> 00:30:00,880 +فور و كيامان او فور و كيامان او فور و كيامان او + +331 +00:30:00,880 --> 00:30:01,180 +فور و كيامان او فور و كيامان او فور و كيامان او + +332 +00:30:01,180 --> 00:30:01,660 +فور و كيامان او فور و كيامان او فور و كيامان او + +333 +00:30:01,660 --> 00:30:08,120 +فور و كيامان او فور و كيامان او فور و كيامان او + +334 +00:30:08,120 --> 00:30:14,380 +فور و كيامان او فور و كيامان ابيصيروا alcohol + +335 +00:30:14,380 --> 00:30:18,360 +مباشرة طبعا اكيد مرورا بال الديهيدز الان في شبطر + +336 +00:30:18,360 --> 00:30:23,960 +ال الديهيدز و ال ketones اخدنا ان ال الديهيدز ايضا + +337 +00:30:23,960 --> 00:30:32,190 +بتأكسد لاش ل acids و ال ketones بتأكسدوشواضح؟ + +338 +00:30:32,190 --> 00:30:37,030 +لاحظوا الخطأ الشائع بهمش .. خلّي كل العالم يسمع + +339 +00:30:37,030 --> 00:30:40,930 +الخطأ الشائع عند الطلاب أنه يوما بلتهيوا بامتحان + +340 +00:30:40,930 --> 00:30:44,950 +بنسوا المواد التانية و لذلك بنصير إحنا نحكي معهم و + +341 +00:30:44,950 --> 00:30:49,970 +هم خارج ال rhythm تماما يعني أكسدت ال aldehydes ل + +342 +00:30:49,970 --> 00:30:53,010 +carboxylic acids في المحاضرة السابقة هذه من + +343 +00:30:53,010 --> 00:30:56,110 +الأخطاء الشائعة اللي بيرتكبوها الطلاب أنه بيضالوا + +344 +00:30:56,110 --> 00:31:01,240 +يحطوا شغلة بدل شغلة مافيش عندهم اتزانفي الدراسة من + +345 +00:31:01,240 --> 00:31:06,060 +البداية يعني بيموتوا مادة او مادتيلة مدة اسبوعين و + +346 +00:31:06,060 --> 00:31:09,920 +بيغيبوا عن محاضراتها و بيلتهيوا لمادة الامتحان + +347 +00:31:09,920 --> 00:31:13,300 +عملوها بيجوا بيلاجوا عندهم مشكلة في المادة التانية + +348 +00:31:13,300 --> 00:31:18,720 +و هكذا دائما حافظوا على انه تظلوا متزينين في جميع + +349 +00:31:18,720 --> 00:31:22,900 +المواد يعني بيزعل المدرس لما ييجي يحكيلكوا انه + +350 +00:31:22,900 --> 00:31:26,080 +اكسدت ال primary alcohols ل acids و اكسدت ال + +351 +00:31:26,080 --> 00:31:30,660 +aldehydes ل acidsو تعب كتير في الكلام و يلاقي أنكم + +352 +00:31:30,660 --> 00:31:35,760 +مش متفاعلين طبعا ليش أنا نوّهت لهذا الكلام لأن + +353 +00:31:35,760 --> 00:31:39,720 +انتوا في النهاية لسه سنة أولى طبيعة الحياة أنه + +354 +00:31:39,720 --> 00:31:46,960 +هيطلب منكم عشر شغلات في يوم واحد الآن مش ممكن أن + +355 +00:31:46,960 --> 00:31:52,430 +البني آدم يعيش و هو بيموت شغلة على حساب شغلةلازم + +356 +00:31:52,430 --> 00:31:56,590 +يعمل كل شيء يعني طبيعة الحياة بعد شوية أنه بده + +357 +00:31:56,590 --> 00:32:02,630 +يكون عندكم عمل بدكم تعمله طفل بدكم اتربيه بيت بدكم + +358 +00:32:02,630 --> 00:32:06,570 +تديروا بالك عليه زوج بدكم تديروا بالك عليه الآن + +359 +00:32:06,570 --> 00:32:10,550 +اتخيلوا لو واحدة من هذه الأربعة طغت على التانية + +360 +00:32:10,550 --> 00:32:14,370 +فقط فكرتوا بالعمل الولد الصغير بيسخن و بيموت و + +361 +00:32:14,370 --> 00:32:18,330 +أنتم مش دارين على حالكم فقط فكرتوا بالولد الصغير + +362 +00:32:19,120 --> 00:32:23,340 +الجوز بيبطل عنكوا وانتوا مش دارين عن حالكوا ولذلك + +363 +00:32:23,340 --> 00:32:28,320 +لما تكتر الأعمال عند الإنسان من الأخطاء الشائعة + +364 +00:32:28,320 --> 00:32:34,910 +جدا انه يقوم بعمل ويهمل تلت أعمالاليوم في الحياة + +365 +00:32:34,910 --> 00:32:40,870 +العملية الجواب لأ لازم تجوم بكل الأعمال و تقسم + +366 +00:32:40,870 --> 00:32:45,570 +وقتك على كل الأعمال و كذلك انتوا كطلاب لازم تدرسوا + +367 +00:32:45,570 --> 00:32:49,730 +لكل المواد مش اذا اجاكوا امتحان اتحدد بعد أسبوعين + +368 +00:32:49,730 --> 00:32:53,590 +ع مدى الأسبوعين بندرس للامتحان و بنغيب عن المواد و + +369 +00:32:53,590 --> 00:33:00,740 +مابنفتحاش و بتضل ايشيصير عندكم التراكم هذه نصيحة + +370 +00:33:00,740 --> 00:33:05,180 +جيد مش بس انتوا تسمعوها وكمان الناس اللي بيحضروا + +371 +00:33:05,180 --> 00:33:10,300 +المحاضرات حتى لو كانوا من خارج الجامعة يسمعوا هذا + +372 +00:33:10,300 --> 00:33:15,540 +الكلام انه الإنسان أعماله كثيرة لازم يوازن بين + +373 +00:33:15,540 --> 00:33:21,600 +أعماله بس مش صح اطلاقا انه يعمل عمل على حساب عمل + +374 +00:33:21,600 --> 00:33:27,400 +ابهيك بنكون أخدنا طريقتين لتحضيرالاحماد من + +375 +00:33:27,400 --> 00:33:30,980 +الكحولات و من ال الدي هايتز في طرق ثانية ان شاء + +376 +00:33:30,980 --> 00:33:34,840 +الله المرة القادمة بنكمل فيها و بننهي لحد ذلك + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..9a0185aa2e353e621c340faa972cb1c0c484ed4f --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_postprocess.srt @@ -0,0 +1,1708 @@ +1 +00:00:18,360 --> 00:00:22,720 +بسم الله الرحمن الرحيم المرة الماضية بدنا نتكلم في + +2 +00:00:22,720 --> 00:00:29,780 +موضوع البروتينات وكان الأساس ان نتعرف على الأحماض + +3 +00:00:29,780 --> 00:00:34,200 +الأمينية ال amino acids اتعرفنا عليهم و اتعرفنا + +4 +00:00:34,200 --> 00:00:38,560 +طبعا كيف بيكونوا بالوسط الحامض أو القاعدى كيف + +5 +00:00:38,560 --> 00:00:44,280 +بتتأثر الشحنة تبعتهمبال بي اتش وهذا الكلام بيدى + +6 +00:00:44,280 --> 00:00:49,560 +الى طريقة عملية لفصلهم عن بعضهم البعض اعتمادا على + +7 +00:00:49,560 --> 00:00:54,380 +اختلاف ال بي اتش اللى هي فكرة ال Electrophoresis + +8 +00:00:54,380 --> 00:01:01,420 +الان اذا بنستمر في الموضوع لو اجينا بدنا نتكلم على + +9 +00:01:01,420 --> 00:01:07,460 +تفاعلات الأحماض الأمينية طبعا اذا قلنا amino acids + +10 +00:01:07,460 --> 00:01:13,680 +كلمتين aminoاللي هي الـ Amines اللي أخدناهم في + +11 +00:01:13,680 --> 00:01:20,720 +الفصل شبطر 11 و Assets الأحمد اللي أخدناهم في شبطر + +12 +00:01:20,720 --> 00:01:26,640 +10 إذا تفاعلاتهم هي تفاعلات الـ Amines و الأحمد + +13 +00:01:26,640 --> 00:01:34,030 +يعني أي تفاعل كنا بناخده للأمينفي السابق في ال + +14 +00:01:34,030 --> 00:01:37,850 +organic العادية هيتفاعل ال amino acids فيه من خلال + +15 +00:01:37,850 --> 00:01:42,820 +ال amino group أي تفاعل كنا بناخده لل acidهيكون + +16 +00:01:42,820 --> 00:01:48,060 +نفس الاشي مع ال amino acids يعني مثلا عندكوا جملة + +17 +00:01:48,060 --> 00:01:54,600 +عامة انه acid زائد alcohol ايش بيعطينا Easter بناء + +18 +00:01:54,600 --> 00:01:59,420 +على ذلك ال amino acids فيهم acids حتى لو كانوا على + +19 +00:01:59,420 --> 00:02:04,180 +شكل ال soul تبعهم بيظلوا acids هذا ال acid لو اجت + +20 +00:02:04,180 --> 00:02:09,140 +فعلته مع alcohol هاي جزء ال acid هاي ال alcohol + +21 +00:02:10,310 --> 00:02:16,150 +ماذا سيعطيني إيستار سيصبح C double bond O OR أو + +22 +00:02:16,150 --> 00:02:22,830 +CO2 R إذا هذا مثال على أنه تفاعل كحامض أسد زائد + +23 +00:02:22,830 --> 00:02:28,430 +ألكوهول إيستار ليس هناك شيء جديد كذلك الحالة لو + +24 +00:02:28,430 --> 00:02:32,110 +إحنا جينا على ال amino group حتى لو كنا كاتبينها + +25 +00:02:32,110 --> 00:02:36,590 +على شكل NH3 بلس إحنا مجرد ما نفعله مع base ترجع + +26 +00:02:36,590 --> 00:02:37,710 +نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو + +27 +00:02:37,830 --> 00:02:41,930 +عادية لو اتش هنا قولنا هذا في النهاية ان اتش توحت + +28 +00:02:41,930 --> 00:02:46,970 +صفة بدنا نفعلها مع acid chloride او مع ايستر او مع + +29 +00:02:46,970 --> 00:02:50,330 +acid anhydride كيف كان الأمين يتفاعل مع ال acid + +30 +00:02:50,330 --> 00:02:57,310 +chloride بالإبدال بهذا الشكل و يعمل عملية إبدال في + +31 +00:02:57,310 --> 00:03:03,030 +هذه الحالة هيعطيني أميدفهذه الحالة هيعطيني amide + +32 +00:03:03,030 --> 00:03:09,170 +واضح هاي ال amide N H C double bond O واضح ففكرة + +33 +00:03:09,170 --> 00:03:14,510 +التفاعلات ال amino acids هي فكرة بسيطة للي فيهم + +34 +00:03:14,510 --> 00:03:18,830 +سابقا تفاعلات ال amines ولي فيهم سابقا تفاعلات ال + +35 +00:03:18,830 --> 00:03:24,410 +acids يمكن أخدتوا انتوا ان ammonia او amine زائد + +36 +00:03:24,410 --> 00:03:31,370 +acid شو كان بيعطيني بشكل عامأمد تمام وبناء على ذلك + +37 +00:03:31,370 --> 00:03:37,690 +هذه الفكرة أيضا ممكن ناخدها لكن من خلال أن الفاعل + +38 +00:03:37,690 --> 00:03:44,640 +جزيئين من ال amino acids مع بعض و من بعضجزء ناخد + +39 +00:03:44,640 --> 00:03:51,320 +منه جزء ناخد منه مجموعة الـ nitrogen الـ NH2 و جزء + +40 +00:03:51,320 --> 00:03:56,860 +ناخد منه جزء ال acid واضح فلما نيجي نقول NH2 زي ال + +41 +00:03:56,860 --> 00:04:02,840 +acid اتفاعلوا شو هيعطوني امد اذا two amino acids + +42 +00:04:02,840 --> 00:04:08,640 +react with each other to form amides واضح هذا + +43 +00:04:08,640 --> 00:04:13,510 +الكلام اللي موجود هنايعني لو أنا اتطلعت على هذا + +44 +00:04:13,510 --> 00:04:18,770 +المركب اللي بيطلع عندى هذا أصلا كان NH2 Amino Acid + +45 +00:04:18,770 --> 00:04:22,970 +و هذا ال Amino Acid التانى هذا Amino Acid و هذا + +46 +00:04:22,970 --> 00:04:28,850 +Amino Acid كان إيش؟ C double bond O OH لما ال NH2 + +47 +00:04:28,850 --> 00:04:36,760 +إجت اتفاعلت هنا شو عملت؟ طردت؟الـ OH وانخصم من هنا + +48 +00:04:36,760 --> 00:04:43,800 +H OH مع H اذا صفينا على هذا الشكل هاي ال two amino + +49 +00:04:43,800 --> 00:04:49,500 +acids اتحدوا مع بعض عملوا قمد C double bond O NH + +50 +00:04:49,500 --> 00:04:53,520 +وين الرابطة الجديدة اللي اتكونت بين ال two amino + +51 +00:04:53,520 --> 00:05:05,080 +acids؟ هذه هذا كان نهاية الجزء الأولان اتش تو وكان + +52 +00:05:05,080 --> 00:05:09,220 +هذا الجزء نهايته سيضا بالبوند او او اتش الان اتش + +53 +00:05:09,220 --> 00:05:12,220 +اتصلت بالسيضا بالبوند او او اتش اذا هذه الرابطة + +54 +00:05:12,220 --> 00:05:16,800 +اللي اتكونت اللي هي الاميد بوند الان لأنه هنا انا + +55 +00:05:16,800 --> 00:05:21,820 +بابدأ ادمج amino acids مع بعضهم البعض لتكوين + +56 +00:05:21,820 --> 00:05:25,580 +بيبتايد هذه رابطة هنا اتكونت و رابط هنا اتكونت هذه + +57 +00:05:25,580 --> 00:05:30,860 +الاميد بوند بنصير احنا نعطيها اسم بيبتايد بوندواضح + +58 +00:05:30,860 --> 00:05:36,140 +فلما نقول ال peptide bond هي حقيقة ال amide bond + +59 +00:05:36,140 --> 00:05:40,760 +واضح لكن لأنه انا لما بفعل two amino acids او + +60 +00:05:40,760 --> 00:05:46,680 +three amino acids بكون ايش؟ peptide و لو كبروا + +61 +00:05:46,680 --> 00:05:52,080 +كتير بصيروا ايش؟ protein واضح فال peptides و ال + +62 +00:05:52,080 --> 00:05:57,060 +proteins فيهم ال amide bond واضح او بنسميها في هذه + +63 +00:05:57,060 --> 00:06:02,470 +الحالة تخصيصاببتايت بوند فلو قلنا مثلا سؤال ببتايت + +64 +00:06:02,470 --> 00:06:06,330 +بوند is an amide bond طبعا هي امد see double bond + +65 +00:06:06,330 --> 00:06:13,090 +O and H طبعا هيكون فيها كل خواص الامدز انه هتكون + +66 +00:06:13,090 --> 00:06:18,490 +هذه المنطقة كامد reactive ولا unreactive + +67 +00:06:18,490 --> 00:06:23,850 +unreactive احنا قلنا الكلمة الأساسية المميزة + +68 +00:06:23,850 --> 00:06:29,670 +للامدز they are unreactiveو بناء على ذلك حتى ال + +69 +00:06:29,670 --> 00:06:34,830 +hydrolysis تبعهم بيكون سهل ولا صعبصعب و لذلك بعد + +70 +00:06:34,830 --> 00:06:38,130 +شوية لما تيجوا تاخدوا protein على سبيل المثال + +71 +00:06:38,130 --> 00:06:43,290 +امكون من amino acids و اقول بدي احلل هذا ال + +72 +00:06:43,290 --> 00:06:49,490 +protein لالمفردات تبعته بيكون الجواب و الله اغليه + +73 +00:06:49,490 --> 00:06:56,110 +في وسط حامض مركز مثلا لمدة 24 ساعة و هو يغلي عشان + +74 +00:06:56,110 --> 00:07:02,230 +تقدر تكسر ال ايش ال amides bonds هذي شروط سهلة ولا + +75 +00:07:02,230 --> 00:07:08,990 +صعبة؟شروط صعبة الان لما احنا بنعمل اتحاد ل two + +76 +00:07:08,990 --> 00:07:13,490 +amino acids بنكون ال peptide bond ممكن نحط كمان + +77 +00:07:13,490 --> 00:07:18,050 +amino acid ها بالتأكيد ممكن كمان نستمر نجيب مجموعة + +78 +00:07:18,050 --> 00:07:24,370 +amino و هكذا الان ال peptide عادة لما احنا بنكونه + +79 +00:07:24,370 --> 00:07:32,070 +بنلاحظ انه في شيء مشترك في هيكل عام MCC double + +80 +00:07:32,070 --> 00:07:37,540 +bond Oهذا الهيكل العام إيش ماله؟ متكرر يعني هاي في + +81 +00:07:37,540 --> 00:07:44,780 +عندى هنا N C C double bond O بعد شو بيجيني كمان + +82 +00:07:44,780 --> 00:07:53,670 +مرة؟ NC C double bond O لو عملت كمان شو هيجيني N C + +83 +00:07:53,670 --> 00:07:59,630 +C double bond O و هكذا واضحة هذه النقطة فهذا شيء + +84 +00:07:59,630 --> 00:08:04,910 +مشترك في ال peptides الان اللي بيكون عادة على + +85 +00:08:04,910 --> 00:08:10,890 +الإيد الشمال بالنسبة لكمبنبدأ منه بنقول ان هذا + +86 +00:08:10,890 --> 00:08:16,670 +الجزء بيمثل ال unterminal of the peptide يعني + +87 +00:08:16,670 --> 00:08:21,290 +الطرف اللي فيه نيتروجين من ال peptide بنرسمه زيكي + +88 +00:08:21,290 --> 00:08:27,000 +عشان الكلاش يفهم مع بعضهوهذا الجزء الأخير بيكون اي + +89 +00:08:27,000 --> 00:08:33,700 +terminal ال carbon terminal فانا لما بدي اعمل + +90 +00:08:33,700 --> 00:08:38,120 +peptide سواء مكون من واحد او اتنين او تلاتة او + +91 +00:08:38,120 --> 00:08:44,800 +اربعة او خمسة amino acids سهل جدا عليا بدي اعمل N + +92 +00:08:44,800 --> 00:08:50,000 +terminal و بدي اعمل C terminal الان ما الوحدة + +93 +00:08:50,000 --> 00:08:59,730 +المتكررةماذا المختلف؟ ال R بناء + +94 +00:08:59,730 --> 00:09:04,870 +على ذلك لو انا الان باجي بقولكم والله انا بدي + +95 +00:09:04,870 --> 00:09:12,740 +بيبتايد من اربعة amino acids ارسمولياممكن هجيبلكوا + +96 +00:09:12,740 --> 00:09:16,520 +سؤال زيك في الامتحان أرسموني ال بيبتايد اللي من + +97 +00:09:16,520 --> 00:09:22,560 +أربعة amino acids اللي هم مثلا بهذا الشكل إجليسين + +98 +00:09:22,560 --> 00:09:32,270 +ألانين سيستين وفينل ألانينهتيجيوا تقولولا احنا + +99 +00:09:32,270 --> 00:09:37,010 +بنكون حافظين هدولة؟ احنا اتفقنا معكم ان الـR group + +100 +00:09:37,010 --> 00:09:40,870 +في الـGlycine H بتكون تحفظوها وفي الالانين مثل + +101 +00:09:40,870 --> 00:09:46,810 +بتكون تحفظوها وفي الستين CH2SH بتكون تعرفوها بالفن + +102 +00:09:46,810 --> 00:09:51,650 +الالانين CH2 فن اللي بعطيكوا بس بعطيكوا الـR الان + +103 +00:09:51,650 --> 00:09:57,750 +لو كان الكلام ارسم هذا الـpeptideكيف بدى ارسم هذا + +104 +00:09:57,750 --> 00:10:03,090 +البيبتايد؟ بدى اجي احط الهيكل تبع البيبتايد الهيكل + +105 +00:10:03,090 --> 00:10:07,270 +تبع البيبتايد اربع وحدات الان هيكونوا بهذا الشكل N + +106 +00:10:07,270 --> 00:10:14,270 +C C double bond O هى اول وحدة amino acid بعدين N C + +107 +00:10:14,270 --> 00:10:22,920 +C double bond O بعدين N C C double bond O بعدينN C + +108 +00:10:22,920 --> 00:10:27,040 +C double bond O الان هى صار عندى أربع وحدات + +109 +00:10:27,040 --> 00:10:36,060 +تتخيلوهم هذه وحدة تنتين تلاتة أربعة واضحة الفكرة + +110 +00:10:36,060 --> 00:10:43,100 +الان ايش بيظل عند المجموعة ال R اللى بتجينه من ال + +111 +00:10:43,100 --> 00:10:48,160 +glycine H و + +112 +00:10:48,160 --> 00:10:54,070 +ايش ال R اللى من القلانين مثلو إيش ال R اللي من + +113 +00:10:54,070 --> 00:11:01,770 +الستين؟ CH2SH و إيش ال R اللي من الفن الألانين؟ + +114 +00:11:01,770 --> 00:11:08,730 +CH2 فنل واضح؟ لحظوا إذا أنا مجرد معرفتي الهيكل + +115 +00:11:08,730 --> 00:11:13,830 +بكرره بعد هيك أن أستكمل الكلام إنه هذه مثلا NH2، + +116 +00:11:13,830 --> 00:11:20,010 +إنه هذه CH إنه هذه NH1، إنه هذه CH، إنه هذه NH، + +117 +00:11:20,010 --> 00:11:25,760 +هذه CHعشان يكتمل الشكل العام بتاع الـ OH + +118 +00:11:30,660 --> 00:11:35,880 +واضح؟ OH أسد تيرمينال لاحظوا بهذا الشكل بإمكاني + +119 +00:11:35,880 --> 00:11:41,740 +أرسم أي بيبتايد فالبيبتايد معروف فيه هيكل كربوني + +120 +00:11:41,740 --> 00:11:48,460 +متكرر الهيكل الكربوني مع النيتروجين اللي هو NCCOO + +121 +00:11:48,460 --> 00:11:57,450 +NCCOO NCCOO NCCOO الاختلاف وين؟بال R groups طبعا + +122 +00:11:57,450 --> 00:12:02,570 +هذا الاختلاف بيخلي ال peptides و ال proteins + +123 +00:12:02,570 --> 00:12:09,050 +مايكونوش polymers حقيقيين لابد من معرفة إيش ال + +124 +00:12:09,050 --> 00:12:14,070 +sequence لهم لابد من معرفة ال sequence إيش تسلسلهم + +125 +00:12:14,070 --> 00:12:18,670 +الآن لو إجيت جبتلكوا سؤال مثلا قلتلكوا والله هذا + +126 +00:12:18,670 --> 00:12:24,710 +ال peptide يجلسين قلانين سستين فين القلانين؟مع هذا + +127 +00:12:24,710 --> 00:12:31,490 +الـpeptide جلبت أي شيء فيه ألانين إيجليسين سيستين + +128 +00:12:31,490 --> 00:12:35,670 +فين الألانين؟ غيرت أي شيء ما العلاقة بينهم؟ they + +129 +00:12:35,670 --> 00:12:39,470 +are structural isomers اختلفوا في مواقع الارتباط + +130 +00:12:39,470 --> 00:12:44,810 +كانت هنا مثلا اللي فيها المثل أعلى تاني وحدة صارت + +131 +00:12:44,810 --> 00:12:46,690 +اللي فيها المثل على الأولى و اللي فيها الأتش على + +132 +00:12:46,690 --> 00:12:51,670 +التانيةهذا تغير في الارتباط ولا لأ؟ اذا they are + +133 +00:12:51,670 --> 00:12:56,830 +structural isomers واضح؟ they are structural + +134 +00:12:56,830 --> 00:13:08,190 +isomers هذه الـ + +135 +00:13:08,190 --> 00:13:13,190 +N-terminal وهذه الـ C-terminalكل بيبتايد إله + +136 +00:13:13,190 --> 00:13:18,250 +unterminal وإله c-terminal لما ببدأ أكتب بكتب بهذا + +137 +00:13:18,250 --> 00:13:23,350 +الشكل واضح؟ إذا ذكرنا بيبتايد بهذا الشكل أي واحدة + +138 +00:13:23,350 --> 00:13:26,230 +كان بإمكانها تخلي c-terminal هان وunterminal هان + +139 +00:13:26,230 --> 00:13:29,290 +بس مش متعودين نشتغل زي هيك في ال biochemistry عشان + +140 +00:13:29,290 --> 00:13:32,210 +الكل يفهم على بعضه + +141 +00:13:49,240 --> 00:13:54,780 +لحظوا معاه هذا الكلام بيعمل شغل كتير مهمة لو أنا + +142 +00:13:54,780 --> 00:14:00,160 +مثلا جبت بس two amino acids و بدي أخليهم يتحدوا مع + +143 +00:14:00,160 --> 00:14:06,160 +بعض يعني glycine و alanine ممكن أخليهم يتحدوا يكون + +144 +00:14:06,160 --> 00:14:11,610 +ل glycine في الأولوالألانين بعده ال glycine اللي + +145 +00:14:11,610 --> 00:14:16,390 +فيه H والألانين اللي فيه مثل أو أخلي الألانين في + +146 +00:14:16,390 --> 00:14:20,790 +الأول وال glycine بعده في هذه الحالة لو أنا بدي + +147 +00:14:20,790 --> 00:14:26,450 +أسمي Hannah ببطاي بشكل دقيق بقول الأساس تبعه الجزء + +148 +00:14:26,450 --> 00:14:31,630 +الأخر اللي هو الألانين متصل في إيش ال glycine + +149 +00:14:31,630 --> 00:14:36,980 +بعتبره على شكل مجموعة بسميه glycineألانين مرات هذه + +150 +00:14:36,980 --> 00:14:43,860 +التسمية بنختصرها بنعملها بهذا الشكل إجلاي ألا خلاص + +151 +00:14:43,860 --> 00:14:49,040 +بنمشي بنقبلها لكن لو بدنا نحكي بشكل دقيق إجلاي سل + +152 +00:14:49,040 --> 00:14:55,020 +ألانين أو إجلاي ألا الآن هذا إيش أول إشي ببدأ فيه + +153 +00:14:55,020 --> 00:15:02,930 +ببدأ هيك و بضلني ماشي ألانين إجلاي سلفلو انا بدى + +154 +00:15:02,930 --> 00:15:08,690 +اعمل اتحاد بينهم اتنين مختلفين صار عندى مش ببتايد + +155 +00:15:08,690 --> 00:15:15,170 +واحد صار عندى اتنين هل يا ترى هذا لجليسي القلانين + +156 +00:15:15,170 --> 00:15:23,270 +هو نفسه القلانيل الجليسين اتأملوا فيه هنا مثلا ال + +157 +00:15:23,270 --> 00:15:29,270 +CH3 جنب مجموعة الحامضهنا الـ H جنب مجموعة الحامض، + +158 +00:15:29,270 --> 00:15:32,570 +هذا اختلاف في ال bonding ولا لا؟ هنا الـ H جنب + +159 +00:15:32,570 --> 00:15:37,770 +الأمين، هنا ال CH3 جنب الأمين، إذا هذولا + +160 +00:15:37,770 --> 00:15:41,410 +المجموعتين، يعني لو كنا متخيلين أن هذه H، انعكسوا + +161 +00:15:41,410 --> 00:15:47,460 +ولا لأ؟أذن هدولة Structural isomers فلو إجينا + +162 +00:15:47,460 --> 00:15:47,960 +سئلنا + +163 +00:16:13,350 --> 00:16:23,530 +الـ Glycine واضحة هذه النقطة؟ الآن نرجع للقصة + +164 +00:16:23,530 --> 00:16:30,750 +القديمة تبعتنا لو يا تورا إجينا و خلطنا + +165 +00:16:34,170 --> 00:16:39,470 +الجليسين مع الانين احنا بنخلط جزء واحد ولا عدد + +166 +00:16:39,470 --> 00:16:44,070 +كبير من الجزيئات عدد كبير من الجزيئات وقلنا لهم + +167 +00:16:44,070 --> 00:16:48,610 +يلا اتفاعلوا مع بعض و اعملولنا peptides كام ناتج + +168 +00:16:48,610 --> 00:16:49,810 +بنتوقع؟ + +169 +00:16:51,890 --> 00:16:56,790 +اتذكروا لما كنا نخلط .. لما كنا نخلط على سبيل + +170 +00:16:56,790 --> 00:17:03,670 +المثال Methanol مع Ethanol عشان نحضر ال ether كام + +171 +00:17:03,670 --> 00:17:10,390 +ناتج كنا نطلع؟ تلاتة لما كنا نخلط Acetic acid مثلا + +172 +00:17:10,390 --> 00:17:15,930 +مع Benzoic acid عشان نطلع ال anhydride كام ناتج + +173 +00:17:15,930 --> 00:17:22,340 +بنطلع؟ تلاتةتلاتة طيب لما نيجي نخلط ألانين مع + +174 +00:17:22,340 --> 00:17:26,960 +إجلايسين و نقولهم اتفاعلوا كام ناتج بنطلع تلاتة .. + +175 +00:17:26,960 --> 00:17:32,040 +تلاتة .. تلاتة .. تلاتة .. تلاتة + +176 +00:17:32,040 --> 00:17:36,140 +.. تلاتة + +177 +00:17:36,140 --> 00:17:39,780 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +178 +00:17:39,780 --> 00:17:40,140 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +179 +00:17:40,140 --> 00:17:40,800 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +180 +00:17:40,800 --> 00:17:40,880 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +181 +00:17:40,880 --> 00:17:44,240 +تلاتة .. تلاتة .. تلطبعا هيبدأ يصير عندكوا استغراب + +182 +00:17:44,240 --> 00:17:50,520 +ليش .. ليش انا في الميثانول لما عملت ال ether لما + +183 +00:17:50,520 --> 00:17:56,040 +عملت ال ether طلع عندى بس تلت أشكال لما خلطت + +184 +00:17:56,040 --> 00:18:00,000 +ميثانول و إيثانول و لما خلطت أسيتك أسد مثلا مع + +185 +00:18:00,000 --> 00:18:04,060 +بنزويك أسد أعمل الانهيدريد طلع عندى برضه تلت أشكال + +186 +00:18:04,060 --> 00:18:10,300 +لكن لو بخلط ألانينمع إجلايسين على سبيل المثال عشان + +187 +00:18:10,300 --> 00:18:14,200 +أعمل بيبتايد هيطلع عندى أربع أشكال + +188 +00:18:20,420 --> 00:18:25,940 +شوفوا المجموعة الوظيفية المجموعة الوظيفية تبعت ال + +189 +00:18:25,940 --> 00:18:30,940 +ether تبعت ال ether و تبعت ال anhydride + +190 +00:18:30,940 --> 00:18:35,840 +symmetrical بفرق اش معها تيجي اي مجموعة على اليمين + +191 +00:18:35,840 --> 00:18:42,640 +و على الاشمال يعني خلينا نشوف ال ether لو بده احط + +192 +00:18:42,640 --> 00:18:49,650 +مثل و اثلأحط مثل يمين و لا مثل الشمال أو العكس + +193 +00:18:49,650 --> 00:18:56,570 +مجموعة الاثر عبارة عن إيش O بدا + +194 +00:18:56,570 --> 00:19:03,370 +تتحد من الجهتين مجموعة الانهيدريد عبارة عن إيشC O + +195 +00:19:03,370 --> 00:19:12,310 +O C O O الآن هدول المجمعتين اللي هم بدو ييجي جنبهم + +196 +00:19:12,310 --> 00:19:18,070 +مثل او اثل بفرقش اذا ايجت هنا مثل وهنا اثل او هنا + +197 +00:19:18,070 --> 00:19:23,030 +مثل وهنا اثل لان هدول متماثلاتكذلك الحال في ال + +198 +00:19:23,030 --> 00:19:26,690 +unhydrate لو حطيت هنا methyl وهنا phenyl يعني + +199 +00:19:26,690 --> 00:19:30,730 +acidic بنزوك او حطيت هنا phenyl وهنا methyl نفس + +200 +00:19:30,730 --> 00:19:34,270 +الاشي هذه المجموعة متماثلة فأي واحد احط يمين او + +201 +00:19:34,270 --> 00:19:40,250 +شمال مابفرقش الان لو اجيت اعتبرت ان انا بدي اشتغل + +202 +00:19:40,250 --> 00:19:42,150 +على الامد + +203 +00:19:43,880 --> 00:19:49,080 +و اشوف اللي هي ال peptide bond هل يا تورا في عندي + +204 +00:19:49,080 --> 00:19:53,380 +تماثل ولا لأ لما باجي بشتغل اتذكروا ان احنا قولنا + +205 +00:19:53,380 --> 00:20:02,210 +بنشتغل N C C double bond او و بعدها بنشتغل N CC + +206 +00:20:02,210 --> 00:20:06,550 +double bond O لما نضع الاتنين اللي موجودين الان + +207 +00:20:06,550 --> 00:20:11,490 +هذا بيصير يفرج ان انا بضع هنا ال H و هنا المثل + +208 +00:20:11,490 --> 00:20:16,410 +بتصير هذه ال H قريبة من ايش او هذه ال H بتصير بين + +209 +00:20:16,410 --> 00:20:21,950 +C double bond O و N H2 هنا لو اجيت بضع المجموعة + +210 +00:20:21,950 --> 00:20:26,210 +التانية بتكون عند C double bond O OH مع N H واحدة + +211 +00:20:26,390 --> 00:20:30,150 +فهل هدولة بيكونوا بنفس ال environment لأ لكن انا + +212 +00:20:30,150 --> 00:20:34,030 +لو حطيتها مثل و مثل ايش بوصف مثل بقول جانبه و مثل + +213 +00:20:34,030 --> 00:20:39,410 +جانبه لو حطيتها مثل و مثل مثل مثل مثل مثل مثل مثل + +214 +00:20:39,410 --> 00:20:41,430 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +215 +00:20:41,430 --> 00:20:41,830 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +216 +00:20:41,830 --> 00:20:43,950 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +217 +00:20:43,950 --> 00:20:43,970 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +218 +00:20:43,970 --> 00:20:51,250 +مثل + +219 +00:20:51,250 --> 00:20:54,740 +مثل مثلتلاتة products بدوا يطلع عندى أربعة + +220 +00:20:54,740 --> 00:20:59,900 +products خلّينا نشوفهم خلّينا نشوفهم هاي ال + +221 +00:20:59,900 --> 00:21:06,640 +glycine و ال alanine و خلطناهم مع بعض طبعا افترضوا + +222 +00:21:06,640 --> 00:21:12,960 +ال alanine الأزرق و ال glycine الأحمر زى ما احنا + +223 +00:21:12,960 --> 00:21:17,750 +عاملينهمش احنا ميزينهم ال glycine أحمر و ال + +224 +00:21:17,750 --> 00:21:22,410 +alanine أزرق هذه جزيئات كتيرة ممكن يتحد عندى + +225 +00:21:22,410 --> 00:21:27,290 +glycine مع glycine يعطوني بيبتايد بده يكون إيش هو + +226 +00:21:27,290 --> 00:21:35,270 +glycine glycine هذي H هذي H NCC double bond O NCC + +227 +00:21:35,270 --> 00:21:39,910 +double bond O وH وH يعني glycine مع glycine ممكن + +228 +00:21:39,910 --> 00:21:48,260 +يتحد عندى alanine مع alanineNCCWO NCCWO مثل و مثل + +229 +00:21:48,260 --> 00:21:54,040 +واضح هذا يكون أي بيبتايل ألانين ألانين ممكن يتحد + +230 +00:21:54,040 --> 00:22:01,180 +الآن إجليسين مع الألانين بهذا الشكل إجليسين ألانين + +231 +00:22:01,180 --> 00:22:10,550 +NCCWO NCCWO الهيكلة هذا إجليسين H هذا ألانينالان + +232 +00:22:10,550 --> 00:22:13,470 +الاتحاد يتم بطريقة تانية + +233 +00:22:20,780 --> 00:22:28,840 +يكون بهذا الشكل NCCWO NCCWO CH3HANA و N HANA هذا + +234 +00:22:28,840 --> 00:22:34,860 +إيش بده يكون الانين غلايسين ال بيبتايد الآن اتطلع + +235 +00:22:34,860 --> 00:22:40,840 +عليهم بالتأمل هل فيهم أشياء بتشبه بعض طبعا لو + +236 +00:22:40,840 --> 00:22:44,760 +سألتكوا ما العلاقة بين غلايسين غلايسين و الانين + +237 +00:22:44,760 --> 00:22:50,520 +انا الانينthey are .. استعملولي كلمات كيميائية + +238 +00:22:50,520 --> 00:22:56,040 +they are different compounds مراكبات مختلفة، لأن + +239 +00:22:56,040 --> 00:22:59,500 +أنا اتش و اتش و انا مثل و مثلها، دي مراكبات مختلفة + +240 +00:22:59,500 --> 00:23:03,700 +إجليسين إجليسين و ألانين ألانين they are different + +241 +00:23:03,700 --> 00:23:07,620 +compounds لو قلتلكوا ما العلاقة بين إجليسين + +242 +00:23:07,620 --> 00:23:11,950 +إجليسين و إجليسين ألانين؟they are different + +243 +00:23:11,950 --> 00:23:14,570 +compounds هان اتش و اتش و هان اتش و مثل صيغة + +244 +00:23:14,570 --> 00:23:18,850 +مختلفة كذلك الحال لو بدأ اقول الالانين الالانين و + +245 +00:23:18,850 --> 00:23:19,950 +الالانين الالانين الالانين الالانين الالانين + +246 +00:23:19,950 --> 00:23:20,490 +الالانين الالانين الالانين الالانين الالانين + +247 +00:23:20,490 --> 00:23:22,850 +الالانين الالانين الالانين الالانين الالانين + +248 +00:23:22,850 --> 00:23:25,270 +الالانين الالانين الالانين الالانين الالانين + +249 +00:23:25,270 --> 00:23:29,230 +الالانين الالانين الالانين الالانين الالانين + +250 +00:23:29,230 --> 00:23:30,250 +الالانين الالانين الالانين الالانين الالانين + +251 +00:23:30,250 --> 00:23:30,610 +الالانين الالانين الالانين الالانين الالانين + +252 +00:23:30,610 --> 00:23:36,470 +الالانين الالانين الالانين الالان + +253 +00:23:36,500 --> 00:23:40,040 +الذرات تماما يعني لو حسبنا على الكمبيوتر ال + +254 +00:23:40,040 --> 00:23:43,420 +molecular weight لهذا و لهذا same number of atoms + +255 +00:23:43,420 --> 00:23:46,980 +same molecular weight بس الفكرة الاختلاف ان هنا + +256 +00:23:46,980 --> 00:23:49,920 +اجت ال H و هنا ال مثل هنا اجت ال مثل و هنا ال H + +257 +00:23:49,920 --> 00:23:54,400 +واضح ان they are different compounds يعني هذه ال H + +258 +00:23:54,400 --> 00:23:58,280 +محصورة بين C double bond O و N H 2 و المثل بين + +259 +00:23:58,280 --> 00:24:04,700 +acid و N H هنا ال H بين acid و N Hواضح الاختلاف + +260 +00:24:04,700 --> 00:24:09,420 +بناء على ذلك لو سألنا ان mixing two amino acids + +261 +00:24:09,420 --> 00:24:16,620 +together in fact will produce fourproducts تمام؟ + +262 +00:24:16,620 --> 00:24:23,300 +هيعطي أربع نواتج طبعا هتصير عندنا مشكلة هتصير + +263 +00:24:23,300 --> 00:24:27,640 +عندنا مشكلة يعني لو الناس كانوا بدهم لجليسين + +264 +00:24:27,640 --> 00:24:31,660 +جليسين هيسخنوا الجليسين مع نفسه بظروف تفاعل يتفاعل + +265 +00:24:31,660 --> 00:24:37,220 +بدي ألانين ألانين نفس الفكرة لكن لو كنت بدي أحضر + +266 +00:24:37,220 --> 00:24:44,260 +جليسين ألانينبدي طريقة معينة الان هذه الطريقة مش + +267 +00:24:44,260 --> 00:24:48,380 +مقبولة كيميائيا اصدقائك بتقولوا اخلطوهم وافصلوهم + +268 +00:24:48,380 --> 00:24:52,460 +اول اش اذا خلطناهم هنطلع مش ناتجين اربعة اربعة + +269 +00:24:52,460 --> 00:24:57,660 +الان في كيميائي بيحط حاله يقعد يفصل اربعة + +270 +00:24:57,660 --> 00:25:01,240 +compounds عن بعض اللي بيدخل المختبر وبيعرف غلبة + +271 +00:25:01,240 --> 00:25:05,420 +الشغل لايمكن يعملها لايمكن يعملها وبناء على ذلك + +272 +00:25:05,420 --> 00:25:14,780 +انا فعلا فعلا بدي طريقةفقط اطلع لي ناتج واحد يعني + +273 +00:25:14,780 --> 00:25:22,380 +هاي هدول المركباتفكروا معي قداش الكيميا منطقها هو + +274 +00:25:22,380 --> 00:25:28,260 +منطق إيش؟ هو منطق حياة .. منطق حياة شايفين؟ هدولة + +275 +00:25:28,260 --> 00:25:32,040 +المركبات الأربعة أنا خلطهم و افترضوا أخلط من هذا + +276 +00:25:32,040 --> 00:25:35,420 +مليون جزيئة و من هذا مليون جزيئة بدي أفعلهم أي + +277 +00:25:35,420 --> 00:25:39,460 +واحد اللي بدكم إياه أنتم يطلع إجلايسين ألانين يعني + +278 +00:25:39,460 --> 00:25:45,380 +اللي زي هيك و فقط واضح؟أنا بدي أفرجيكوا كيف بدي + +279 +00:25:45,380 --> 00:25:52,120 +أعملها كإنها لعبة برا ما أحكي عن إيش عن الكيميا + +280 +00:25:52,120 --> 00:25:56,980 +يعني أنا بدي أتعامل معها كإنها لعبة بدي أعطي لشخص + +281 +00:25:56,980 --> 00:26:00,680 +معين هدول أقوله اخلط بحيث أنه لما تيجي تشبكهم في + +282 +00:26:00,680 --> 00:26:04,660 +بعض ما يطلعش إلا هذا المركب اللي أنتوا طلبته + +283 +00:26:04,660 --> 00:26:09,440 +الأحمر و الأزرق تمام؟ كل هذا الكلام ممكن نعمله + +284 +00:26:09,440 --> 00:26:13,600 +بورقة clinics صغيرة إيش رأيكوا؟ + +285 +00:26:16,190 --> 00:26:21,210 +ورقة كلينكس الصغيرة ايش اللي بدنا نعمله احنا بنيجي + +286 +00:26:21,210 --> 00:26:26,590 +هذا بنعمله protection من هنا بنعمله حماية من هنا + +287 +00:26:26,590 --> 00:26:30,910 +ممنوع انت تتفعل بدنا ياك تتفعل من ال nitrogen + +288 +00:26:30,910 --> 00:26:34,090 +سكرنا مجموعة الحامض عشان مايجيش هذا يتفعل معاه من + +289 +00:26:34,090 --> 00:26:39,510 +هنا لاحظوا هذا الغلبان جاي يتفعل معاه راضي يتفعل؟ + +290 +00:26:39,510 --> 00:26:43,950 +شوفوا قبل ال protection قبل الحماية لو هذا إيجي + +291 +00:26:43,950 --> 00:26:50,400 +يتفعلكان بتفاعل، الآن بعد ما عملت الـ protection + +292 +00:26:50,400 --> 00:26:57,800 +إجا اتفاعلمش قادر يتفاعل سكرت هذا الجزء إذا بجعل + +293 +00:26:57,800 --> 00:27:02,880 +كل هدولة بعمل protection لل acid بإضافة مجموعة + +294 +00:27:02,880 --> 00:27:07,460 +كيميائية اتسكر هذا الجزء هذا بطل يتفاعل من هنا + +295 +00:27:07,460 --> 00:27:13,820 +ممتاز لسه عندي خوف ان هدول يتفاعلوا مع بعض الان + +296 +00:27:13,820 --> 00:27:18,800 +هدول هدين يتفاعلوا مع بعض انا منعت نص المشكلة الان + +297 +00:27:18,800 --> 00:27:23,530 +هذا من وين بدي امنعه يتفاعل؟من ال nitrogen باجي + +298 +00:27:23,530 --> 00:27:27,350 +بعمله protection من الطرف التاني عشان مايقدرش + +299 +00:27:27,350 --> 00:27:35,050 +يتفاعل منها أنا بنعمله شوية protection برضه هاي + +300 +00:27:35,050 --> 00:27:40,270 +بأمل أنها تكون عمليتها ال protection هذه زبطت + +301 +00:27:40,270 --> 00:27:41,670 +استعمل + +302 +00:27:46,120 --> 00:27:51,860 +بهمش انتوا في النهاية تصللكوا الفكرة ان الكيميائي + +303 +00:27:51,860 --> 00:27:57,980 +والبني آدم والطبيب لما بده يفكر بحالة مشكلة بده + +304 +00:27:57,980 --> 00:28:01,620 +يكون عنده أصول العلم لكن بده يفكر بمنطق الدنيا + +305 +00:28:01,620 --> 00:28:06,320 +بمنطق الدنيا يعني إليزاروف إليزاروف لما عمل + +306 +00:28:06,320 --> 00:28:11,040 +العملية الجراحية تبعته اللي بطول فيها عظام الساق + +307 +00:28:11,040 --> 00:28:15,320 +الناس اللي عندهم ساق أكثر من التانيةاللي فكر فيه + +308 +00:28:15,320 --> 00:28:20,420 +انه ايجي على العضمة جشرها و حط حديد هان و هان و + +309 +00:28:20,420 --> 00:28:25,040 +صار كل ساعتين اطول نص مل نص مل لانه مقدرش يسحب كل + +310 +00:28:25,040 --> 00:28:29,780 +شيء عظامه اعصابه اشي مرة واحدة عمدا أسبوعين بيضلوا + +311 +00:28:29,780 --> 00:28:34,020 +يسحب يسحب او بيطول العضمة كده؟ سبعة تمانية سانتي + +312 +00:28:34,020 --> 00:28:40,840 +بيعمل مسوافر عملية شهيرة جدا ال الازاروفالان + +313 +00:28:40,840 --> 00:28:45,720 +الظروف شاب تبع البسكليتات كيف بيشتغلوا بعمل العجال + +314 +00:28:45,720 --> 00:28:51,380 +واخذ منه فكرة كيف يعمل العملية واضحة الفكرة؟ الان + +315 +00:28:51,380 --> 00:28:58,120 +هاي انا عملت protection هنا لل acid part وهنا لل + +316 +00:28:58,120 --> 00:29:03,320 +amino part انه مش قادر يتفاعل من عند ال nitrogen + +317 +00:29:03,320 --> 00:29:09,740 +الان بدي اخلطهم و اقولوا متفاعلوا زي ما بدكمهيجي + +318 +00:29:09,740 --> 00:29:14,060 +يتفاعلوا اول اشي هذا هيجي يتفاعل من هنا هيلاجي ايش + +319 +00:29:14,060 --> 00:29:18,880 +امسكّر ال nitrogen تبعته من هنا امسكّر ال nitrogen + +320 +00:29:18,880 --> 00:29:24,180 +هذا هيجي يتفاعل مع هذا امسكّر ال CO هذا يتفاعل مع + +321 +00:29:24,180 --> 00:29:29,620 +هذا امسكّر ال CO لغاية كل هذه التفاعلات الان هذا + +322 +00:29:29,620 --> 00:29:36,820 +بيجي يتفاعل مع هذا امسكّر هذا بيجي يتفاعل مع هذا + +323 +00:29:38,200 --> 00:29:45,500 +طلعت one product شوف كيف .. هايوة one product هيك + +324 +00:29:45,500 --> 00:29:50,500 +ممكن .. الآن هيكمش ممكن اتنين زرق مش ممكن اتنين + +325 +00:29:50,500 --> 00:29:55,500 +حمر مش ممكن هذه الفكرة هي اللي عملوها الان كل اللي + +326 +00:29:55,500 --> 00:29:59,500 +بدنا نعمله اننا بدنا نكتب في المعادلة حطوا هنا حرف + +327 +00:29:59,500 --> 00:30:04,520 +بي بي ايش يعني بي يعني protecting group لما تكونوا + +328 +00:30:04,520 --> 00:30:08,000 +اعملوا هذا protected او اعملوا هذا protected لما + +329 +00:30:08,000 --> 00:30:12,140 +تشوفوا ال بي يعني من هنا ممنوع تتفاعلمجموعة + +330 +00:30:12,140 --> 00:30:16,120 +كيميائية صغيرة بنضيفها بتخلي هذا مثبت مابتفعلش مش + +331 +00:30:16,120 --> 00:30:21,980 +هندخل بتفاصيل أكتر من هي وجدها ماعندي إلا هذه + +332 +00:30:21,980 --> 00:30:25,780 +الإمكانية تشتغل هذا مش هيقدر يتفعل مع نفسه ولا هذا + +333 +00:30:25,780 --> 00:30:29,400 +هيتفعل مع نفسه هذا هيتفعل مع هذا بس one product + +334 +00:30:29,400 --> 00:30:37,260 +طلعت ال glycine ألانين واضحة الفكرة وهذا هو اللي + +335 +00:30:37,260 --> 00:30:38,220 +موجود يمكن + +336 +00:30:40,820 --> 00:30:45,960 +في ال slide يمكن متأخرة عندكم اربع خمسة slides + +337 +00:30:45,960 --> 00:30:52,520 +لاحظوا هاي جاب amino acid one سماه وعمل protection + +338 +00:30:52,520 --> 00:30:58,740 +لمجموعة معينة و جاب ال amino acid two وعمل + +339 +00:30:58,740 --> 00:31:02,620 +protection لمجموعة تانية نفس الفكرة اللي احنا + +340 +00:31:02,620 --> 00:31:06,280 +حكيناها الآن هذا بطل يتفعل من هنا هذا بتفعلش من + +341 +00:31:06,280 --> 00:31:10,850 +هنا مافيش غير هذا الجزءمع هذا الجزء بده يتفاعل + +342 +00:31:10,850 --> 00:31:17,010 +فبدل ما أطلع four different compounds بطلع one + +343 +00:31:17,010 --> 00:31:22,230 +طبعا في هذه الحالة هين طلعت بيبتايد الآن بعد ما + +344 +00:31:22,230 --> 00:31:26,090 +طلعته بتفاعل كيميائي بسيط بقدر أشيل هذا ال + +345 +00:31:26,090 --> 00:31:30,730 +protection أو هذا ال protection الآن تخيلوا لو كنا + +346 +00:31:30,730 --> 00:31:35,910 +بدنا نطول ال peptide يعني مش بس اتنين بد من هنا ما + +347 +00:31:35,910 --> 00:31:41,370 +يتفاعلشبخلّي هذا الـ protection بدي من هنا يتفاعل + +348 +00:31:41,370 --> 00:31:50,370 +بشيل هذا و بجيبله amino acid ال nitrogen تبعته not + +349 +00:31:50,370 --> 00:31:53,430 +protected و ال acid protected عشان مايتفعلش مع + +350 +00:31:53,430 --> 00:31:58,150 +بعضه اللي جاي جديد بيجي يتفعل هنا واحد اتنين تلاتة + +351 +00:31:58,150 --> 00:32:03,270 +اربعة ممكن في الآخر يتحضروا خمسة عشر و عشرين و + +352 +00:32:03,270 --> 00:32:09,540 +تلاتين جد ما بدكم و بالترتيببالترتيب بتحضره تمام + +353 +00:32:09,540 --> 00:32:13,220 +هذا + +354 +00:32:13,220 --> 00:32:20,160 +الكلام كله موجود ثانية أخدها لحظوا + +355 +00:32:20,160 --> 00:32:27,460 +على سبيل المثال هاي مركب اتخيلوا هذا عملوله + +356 +00:32:27,460 --> 00:32:28,100 +sequencing + +357 +00:32:31,070 --> 00:32:35,610 +عرفوا تفاصيله هنشوف طبعا كيف بعد شوية بنحلل المركب + +358 +00:32:35,610 --> 00:32:39,050 +نعرف ال amino acids إيجليسين إليوسين فالين + +359 +00:32:39,050 --> 00:32:44,870 +إيجلوتاميكاس وهكذا هذا الانسولين هذا الانسولين + +360 +00:32:44,870 --> 00:32:51,030 +سلسلتين من ال إيش ال peptides بيحللوه بيعرفوه واحد + +361 +00:32:51,030 --> 00:32:58,130 +واحد لاحظوا مابنقدرش زي السكر نعمل إيش شغلة to the + +362 +00:32:58,130 --> 00:33:02,700 +end لأ في إيش اسمهسيكوانس في ال .. بيبتايتز و في + +363 +00:33:02,700 --> 00:33:08,000 +الأمان هاي هذا مركّب الراجل اللي حضره أخد عليه + +364 +00:33:08,000 --> 00:33:13,600 +جائزة نوبل في الكيميا سنة الخمسة و خمسين هذا + +365 +00:33:13,600 --> 00:33:22,780 +Vincent de Vignod أخد عليه جائزة نوبل هذا هرمون من + +366 +00:33:22,780 --> 00:33:29,310 +تسعةأمينو أسد حضرهم من مرتبين سيستين تايروسين + +367 +00:33:29,310 --> 00:33:33,030 +إليوسين كذا أسبرتك أسستين برولين ليوسين إجلايسين + +368 +00:33:33,030 --> 00:33:37,750 +أعدهم واحد اتنين تلاتة أربعة خمس ستة سبعة تمانية + +369 +00:33:37,750 --> 00:33:42,970 +تسعة هنا في أس و أس ارتبطوا مع بعض مش موضوعنا ناخد + +370 +00:33:42,970 --> 00:33:46,630 +الديس الفايدمون بس هدول كام أمينو أسد في المحصلة + +371 +00:33:46,630 --> 00:33:52,590 +واحد اتنين تلاتة أربعة خمسة ستة سبعة تمانية تسعة + +372 +00:33:52,590 --> 00:33:59,330 +حضرهم من مرتبينبهذه الطريقة واضح؟ هذا عبارة عن + +373 +00:33:59,330 --> 00:34:05,790 +هرمون اسمه oxytocin مار عليكم؟ هرمون السعادة الله + +374 +00:34:05,790 --> 00:34:11,380 +يسعدكمالناس بيسموه هرمون السعادة فعلا، ليش؟ لأنهم + +375 +00:34:11,380 --> 00:34:14,640 +انتبعون علم النفس وغيره، بيقولوا هذا اللي بتتحكم + +376 +00:34:14,640 --> 00:34:19,440 +بالانفعالات وقصص السعادة والحب وكل إشي برتوب هذا + +377 +00:34:19,440 --> 00:34:24,160 +الهرمون طبعا إله تطبيقات تانية .. إله تطبيقات + +378 +00:34:24,160 --> 00:34:28,720 +تانية هو في الأصل بيطلع من ال posterior pituitary + +379 +00:34:28,720 --> 00:34:33,060 +gland يمكن بتسموها الغضب الكذرية ولا إيش .. هذا + +380 +00:34:33,060 --> 00:34:40,320 +بتحكم في القبضات الرحم في لحظة الولادةit regulates + +381 +00:34:40,320 --> 00:34:46,560 +uterine contraction and lactation وفي الرضاعة may + +382 +00:34:46,560 --> 00:34:49,360 +be administered .. إيش معنى administered في لغة + +383 +00:34:49,360 --> 00:34:54,800 +العلم الطبي؟ يُعطى كعلاج أو يوصف واضح؟ when it is + +384 +00:34:54,800 --> 00:34:58,440 +necessary to induce labor at childbirth يعني عشان + +385 +00:34:58,440 --> 00:35:03,750 +يزيد الطلجواضح؟ وبنفس الوقت زي ما حكينا إيه له + +386 +00:35:03,750 --> 00:35:09,670 +علاقة بالانفعالات الآن لاحظوا بيبتعد وحضر أول إشي + +387 +00:35:09,670 --> 00:35:13,570 +قبل ما يحضر إيش كان لازم نفصله من مصدره الطبيعي + +388 +00:35:13,570 --> 00:35:19,210 +ونعرف إيش ال sequence تبعته بعد ما نعرف ال + +389 +00:35:19,210 --> 00:35:23,230 +sequence ال road نقدر نعملها إذا صار عند أنا في + +390 +00:35:23,230 --> 00:35:27,850 +المنطقة شغلتين معرفة ال sequence و التحضير يمكن + +391 +00:35:27,850 --> 00:35:32,610 +احنا بدأنا الآنبفكرة التحضير لكن لسه ماحكيناش عن + +392 +00:35:32,610 --> 00:35:37,950 +فكرة إيش ال sequence فكرة ال sequence فكرة طويلة و + +393 +00:35:37,950 --> 00:35:46,110 +أخدت وقت طبعا من العلماء لكن + +394 +00:35:46,110 --> 00:35:50,170 +خلينا نضل ماشيين مع ال slides شوفنا قصة ال + +395 +00:35:50,170 --> 00:35:54,570 +protection خلصنا منها الآن من الروابط اللي + +396 +00:35:54,570 --> 00:36:00,840 +بتواجهنافي الـpeptides و بتمسكها مع بعض اللي هي + +397 +00:36:00,840 --> 00:36:04,180 +الـdisulfide bonds طبعا في hydrogen bonding أكيد + +398 +00:36:04,180 --> 00:36:08,740 +هيمر علينا لكن الـdisulfide bonds and all amino + +399 +00:36:08,740 --> 00:36:13,540 +acid اللي فيه الـsulfur ممكن يعمل الـdisulfide + +400 +00:36:13,540 --> 00:36:20,870 +bondال سيستين اللي قلتلكوا احفظوه اللي فيه CH2SH + +401 +00:36:20,870 --> 00:36:27,970 +فلو التقى سيستين مع سيستين SH وSH أخدنا في الثيول + +402 +00:36:27,970 --> 00:36:31,510 +شوفوا كيف العلم مبني على بعضه لما أخدنا الثيول + +403 +00:36:31,510 --> 00:36:35,530 +متذكرين قولنا الثيول بال Oxidation بعمل Di + +404 +00:36:35,530 --> 00:36:40,030 +-sulphide bond و بال reduction برجع لثيول و كان من + +405 +00:36:40,030 --> 00:36:46,770 +أمثلتها الشعر و قرنية العين و غيرهافهدولة لو اجينا + +406 +00:36:46,770 --> 00:36:51,650 +مثلا في بيبتايد طويل في طرف معين منه فيه 16 فيه + +407 +00:36:51,650 --> 00:36:58,590 +CH2SH و بطرف تاني 16 فيه CH2SH ممكن الـSH مع الـSH + +408 +00:36:58,590 --> 00:37:02,410 +يعملوا ايش دايس الفايدبوند هذا الكلام وين توي + +409 +00:37:02,410 --> 00:37:07,150 +شوفناه احنا؟ في الـOxytocin + +410 +00:37:08,650 --> 00:37:13,970 +تطلعوا معي هاي ال oxytocin ال amino acid نمرا واحد + +411 +00:37:13,970 --> 00:37:20,610 +16 يعني CH2SH وال amino acid واحد اتنين تلاتة + +412 +00:37:20,610 --> 00:37:27,430 +اربعة خمسة ستة السادس CH2SH + +413 +00:37:27,430 --> 00:37:34,110 +الآن ال SH مع ال SH عملوا oxidation عملوا ايش ال + +414 +00:37:34,110 --> 00:37:38,470 +di-sulfide bond فصار مبين هذا كأنه في حلقةعشان هيك + +415 +00:37:38,470 --> 00:37:40,930 +لما عدينا ال amino acids عديناهم تسعة، واحد، + +416 +00:37:40,930 --> 00:37:44,090 +اتنين، تلات، اربع، خمس، ستة، سبعة، تمانية، تسعة بس + +417 +00:37:44,090 --> 00:37:50,490 +الأول والسادس فيهم CH2SH CH2SH CH2SH CH2SH CH2SH + +418 +00:37:50,490 --> 00:37:51,550 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH + +419 +00:37:51,550 --> 00:37:52,730 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH + +420 +00:37:52,730 --> 00:37:54,930 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH + +421 +00:37:54,930 --> 00:38:03,630 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2الان + +422 +00:38:03,630 --> 00:38:10,910 +واضح تماما انه صعب في نهاية المحاضرة ان نبدأ نحكي + +423 +00:38:10,910 --> 00:38:15,270 +عن ال protein وكيف نعمل ال sequence هيلزمنا ان شاء + +424 +00:38:15,270 --> 00:38:20,970 +الله محاضرة إضافية نحكي فيها كيف نتعرف على ال + +425 +00:38:20,970 --> 00:38:24,830 +sequence لل amino acids وإذا عرفنا ال sequence + +426 +00:38:24,830 --> 00:38:29,250 +شوفنا كيف الآن بنحضرهم بعد هيك أشكال ال protein + +427 +00:38:29,250 --> 00:38:31,530 +المختلفة فان شاء الله إلى لقاء + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..24f87d661cfc52e7037ffd82aaf3ae6e0264bcb8 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/V8hlE7JcPsU_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4056, "start": 18.36, "end": 40.56, "text": "بسم الله الرحمن الرحيم المرة الماضية بدنا نتكلم في موضوع البروتينات وكان الأساس ان نتعرف على الأحماض الأمينية ال amino acids اتعرفنا عليهم و اتعرفنا طبعا كيف بيكونوا بالوسط الحامض أو القاعدى كيف بتتأثر الشحنة تبعتهم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 8315, 8717, 2655, 4117, 19528, 8978, 3714, 2407, 11242, 45367, 2423, 26890, 35473, 9957, 9307, 4032, 41361, 16247, 3794, 32277, 16472, 8717, 2655, 3615, 28480, 15844, 16247, 35571, 46958, 16247, 2304, 9957, 10632, 2423, 24674, 21667, 1975, 2655, 3615, 28480, 8315, 25894, 16095, 4032, 1975, 2655, 3615, 28480, 8315, 23032, 3555, 3615, 995, 9122, 33911, 4724, 1829, 30544, 14407, 20666, 41779, 9566, 21542, 10943, 11242, 34051, 25062, 995, 22488, 7578, 9122, 33911, 39894, 2655, 10721, 49115, 25124, 5016, 1863, 3660, 6055, 3555, 34268, 16095], "avg_logprob": -0.09726562812924384, 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356.72, "end": 356.88, "word": " في", "probability": 0.8671875}, {"start": 356.88, "end": 357.06, "word": " هذه", "probability": 0.947265625}, {"start": 357.06, "end": 357.46, "word": " الحالة", "probability": 0.9890950520833334}, {"start": 357.46, "end": 358.32, "word": " تخصيصا", "probability": 0.9881184895833334}], "temperature": 1.0}, {"id": 15, "seek": 38717, "start": 359.05, "end": 387.17, "text": "ببتايت بوند فلو قلنا مثلا سؤال ببتايت بوند is an amide bond طبعا هي امد see double bond O and H طبعا هيكون فيها كل خواص الامدز انه هتكون هذه المنطقة كامد reactive ولا unreactive unreactive احنا قلنا الكلمة الأساسية المميزة للامدز they are unreactive", "tokens": [3555, 3555, 2655, 995, 36081, 4724, 11536, 3215, 6156, 1211, 2407, 12174, 1211, 8315, 50113, 15040, 8608, 33604, 6027, 4724, 3555, 2655, 995, 36081, 4724, 11536, 3215, 307, 364, 669, 482, 6086, 23032, 3555, 3615, 995, 39896, 1975, 2304, 3215, 536, 3834, 6086, 422, 293, 389, 23032, 3555, 3615, 995, 39896, 30544, 8978, 11296, 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"seek": 48769, "start": 467.45, "end": 487.69, "text": "C C double bond O لو عملت كمان شو هيجيني N C C double bond O و هكذا واضحة هذه النقطة فهذا شيء مشترك في ال peptides الان اللي بيكون عادة على الإيد الشمال بالنسبة لكم", "tokens": [34, 383, 3834, 6086, 422, 45164, 6225, 42213, 2655, 9122, 2304, 7649, 13412, 2407, 39896, 7435, 9957, 1829, 426, 383, 383, 3834, 6086, 422, 4032, 8032, 4117, 15730, 4032, 46958, 5016, 3660, 29538, 28239, 47432, 3660, 6156, 3224, 15730, 44049, 38207, 37893, 2655, 31747, 8978, 2423, 41781, 1875, 2423, 7649, 13672, 1829, 4724, 1829, 30544, 6225, 18513, 3660, 15844, 33688, 25708, 25124, 2304, 6027, 20666, 1863, 35457, 3660, 5296, 24793], "avg_logprob": -0.25814260815230894, "compression_ratio": 1.4659090909090908, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 467.45, "end": 467.99, "word": "C", "probability": 0.12115478515625}, {"start": 467.99, "end": 469.15, "word": " C", "probability": 0.281005859375}, {"start": 469.15, "end": 469.39, 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المتكررة", "tokens": [2407, 3224, 15730, 25724, 11622, 38207, 16247, 9778, 13546, 4724, 1829, 30544, 1975, 1829, 14709, 2423, 5954, 14709, 6156, 7649, 995, 5296, 15042, 4724, 16254, 1975, 25957, 1211, 41781, 482, 8608, 2407, 16606, 3714, 30544, 9154, 36764, 24401, 1975, 2407, 1975, 2655, 1863, 9957, 1975, 2407, 6055, 1211, 9307, 3660, 1975, 2407, 1975, 25513, 27884, 1975, 2407, 16490, 2304, 3794, 3660, 24674, 21667, 8608, 3224, 1211, 10874, 28259, 11203, 25528, 4724, 16254, 1975, 25957, 1211, 426, 14709, 4032, 4724, 16254, 1975, 25957, 1211, 383, 14709, 2423, 7649, 19446, 2423, 2407, 24401, 3660, 9673, 2655, 37983, 25720], "avg_logprob": -0.18218427835051546, "compression_ratio": 1.7227722772277227, "no_speech_prob": 0.0, "words": [{"start": 504.22, "end": 504.9, "word": "وهذا", "probability": 0.7513020833333334}, {"start": 504.9, "end": 505.36, "word": " الجزء", "probability": 0.9718424479166666}, {"start": 505.36, "end": 505.86, "word": " الأخير", "probability": 0.81982421875}, 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"probability": 0.96240234375}, {"start": 648.6, "end": 648.8, "word": " R", "probability": 0.951171875}, {"start": 648.8, "end": 648.98, "word": " اللى", "probability": 0.968994140625}, {"start": 648.98, "end": 649.16, "word": " من", "probability": 0.99072265625}, {"start": 649.16, "end": 649.94, "word": " القلانين", "probability": 0.8160400390625}, {"start": 649.94, "end": 650.92, "word": " مثل", "probability": 0.97900390625}], "temperature": 1.0}, {"id": 28, "seek": 68089, "start": 652.55, "end": 680.89, "text": "و إيش ال R اللي من الستين؟ CH2SH و إيش ال R اللي من الفن الألانين؟ CH2 فنل واضح؟ لحظوا إذا أنا مجرد معرفتي الهيكل بكرره بعد هيك أن أستكمل الكلام إنه هذه مثلا NH2، إنه هذه CH إنه هذه NH1، إنه هذه CH، إنه هذه NH، هذه CH", "tokens": [2407, 11933, 1829, 8592, 2423, 497, 13672, 1829, 9154, 2423, 14851, 9957, 22807, 5995, 17, 17308, 4032, 11933, 1829, 8592, 2423, 497, 13672, 1829, 9154, 27188, 1863, 16247, 1211, 7649, 9957, 22807, 5995, 17, 6156, 1863, 1211, 4032, 46958, 5016, 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"end": 654.91, "word": " الستين؟", "probability": 0.57818603515625}, {"start": 654.91, "end": 657.77, "word": " CH2SH", "probability": 0.8053385416666666}, {"start": 657.77, "end": 658.53, "word": " و", "probability": 0.76220703125}, {"start": 658.53, "end": 658.81, "word": " إيش", "probability": 0.9129231770833334}, {"start": 658.81, "end": 658.97, "word": " ال", "probability": 0.96728515625}, {"start": 658.97, "end": 659.17, "word": " R", "probability": 0.97705078125}, {"start": 659.17, "end": 659.35, "word": " اللي", "probability": 0.97412109375}, {"start": 659.35, "end": 659.53, "word": " من", "probability": 0.9931640625}, {"start": 659.53, "end": 659.87, "word": " الفن", "probability": 0.85986328125}, {"start": 659.87, "end": 661.77, "word": " الألانين؟", "probability": 0.7559326171875}, {"start": 661.77, "end": 662.93, "word": " CH2", "probability": 0.97998046875}, {"start": 662.93, "end": 664.19, "word": " فنل", "probability": 0.6944580078125}, {"start": 664.19, "end": 665.77, "word": " واضح؟", "probability": 0.8427734375}, {"start": 665.77, "end": 666.47, "word": " لحظوا", "probability": 0.7430419921875}, {"start": 666.47, "end": 667.03, "word": " إذا", "probability": 0.6845703125}, {"start": 667.03, "end": 667.29, "word": " أنا", "probability": 0.85205078125}, {"start": 667.29, "end": 667.73, "word": " مجرد", "probability": 0.9912109375}, {"start": 667.73, "end": 668.21, "word": " معرفتي", "probability": 0.9220377604166666}, {"start": 668.21, "end": 668.73, "word": " الهيكل", "probability": 0.8974609375}, {"start": 668.73, "end": 669.41, "word": " بكرره", "probability": 0.92578125}, {"start": 669.41, "end": 669.97, "word": " بعد", "probability": 0.86962890625}, {"start": 669.97, "end": 670.31, "word": " هيك", "probability": 0.94921875}, {"start": 670.31, "end": 670.49, "word": " أن", "probability": 0.58056640625}, {"start": 670.49, "end": 671.21, "word": " أستكمل", "probability": 0.8914794921875}, {"start": 671.21, "end": 671.69, "word": " الكلام", "probability": 0.96337890625}, {"start": 671.69, "end": 671.93, "word": " إنه", "probability": 0.4627685546875}, {"start": 671.93, "end": 672.17, "word": " هذه", "probability": 0.50341796875}, {"start": 672.17, "end": 672.71, "word": " مثلا", "probability": 0.926513671875}, {"start": 672.71, "end": 673.83, "word": " NH2،", "probability": 0.5883382161458334}, {"start": 673.83, "end": 673.95, "word": " إنه", "probability": 0.813720703125}, {"start": 673.95, "end": 674.19, "word": " هذه", "probability": 0.80810546875}, {"start": 674.19, "end": 674.77, "word": " CH", "probability": 0.880859375}, {"start": 674.77, "end": 675.39, "word": " إنه", "probability": 0.6851806640625}, {"start": 675.39, "end": 675.61, "word": " هذه", "probability": 0.88525390625}, {"start": 675.61, "end": 676.85, "word": " NH1،", "probability": 0.8014322916666666}, {"start": 676.85, "end": 676.99, "word": " إنه", "probability": 0.942138671875}, {"start": 676.99, "end": 677.23, "word": " هذه", "probability": 0.9375}, {"start": 677.23, "end": 677.99, "word": " CH،", "probability": 0.9228515625}, {"start": 677.99, "end": 678.13, "word": " إنه", "probability": 0.947265625}, {"start": 678.13, "end": 678.33, "word": " هذه", "probability": 0.93408203125}, {"start": 678.33, "end": 680.01, "word": " NH،", "probability": 0.916015625}, {"start": 680.01, "end": 680.27, "word": " هذه", "probability": 0.446533203125}, {"start": 680.27, "end": 680.89, "word": " CH", "probability": 0.970703125}], "temperature": 1.0}, {"id": 29, "seek": 68576, "start": 681.26, "end": 685.76, "text": "عشان يكتمل الشكل العام بتاع الـ OH", "tokens": [3615, 8592, 7649, 7251, 4117, 39237, 1211, 25124, 28820, 18863, 10943, 39894, 45761, 2423, 39184, 13931], "avg_logprob": -0.35546875, "compression_ratio": 1.0169491525423728, "no_speech_prob": 0.0, "words": [{"start": 681.26, "end": 681.72, "word": "عشان", "probability": 0.9217122395833334}, {"start": 681.72, "end": 682.98, "word": " يكتمل", "probability": 0.8670654296875}, {"start": 682.98, "end": 684.58, "word": " الشكل", "probability": 0.9345703125}, {"start": 684.58, "end": 685.0, "word": " العام", "probability": 0.97900390625}, {"start": 685.0, "end": 685.26, "word": " بتاع", "probability": 0.7900390625}, {"start": 685.26, "end": 685.48, "word": " الـ", "probability": 0.44970703125}, {"start": 685.48, "end": 685.76, "word": " OH", "probability": 0.1915283203125}], "temperature": 1.0}, {"id": 30, "seek": 71494, "start": 690.66, "end": 714.94, "text": "واضح؟ OH أسد تيرمينال لاحظوا بهذا الشكل بإمكاني أرسم أي بيبتايد فالبيبتايد معروف فيه هيكل كربوني متكرر الهيكل الكربوني مع النيتروجين اللي هو NCCOO NCCOO NCCOO NCCOO الاختلاف وين؟", "tokens": [2407, 46958, 5016, 22807, 13931, 5551, 3794, 3215, 6055, 13546, 2304, 9957, 6027, 20193, 5016, 19913, 14407, 39627, 15730, 25124, 28820, 4724, 28814, 2304, 41361, 1829, 5551, 2288, 38251, 36632, 4724, 1829, 3555, 2655, 995, 25708, 6156, 6027, 21292, 3555, 2655, 995, 25708, 20449, 32887, 5172, 8978, 3224, 39896, 28820, 9122, 25513, 11536, 1829, 44650, 37983, 2288, 2423, 3224, 1829, 28820, 33251, 25513, 11536, 1829, 20449, 2423, 22653, 2655, 2288, 29245, 9957, 13672, 1829, 31439, 426, 11717, 46, 46, 426, 11717, 46, 46, 426, 11717, 46, 46, 426, 11717, 46, 46, 2423, 47283, 2655, 15040, 5172, 4032, 9957, 22807], "avg_logprob": -0.244687502682209, "compression_ratio": 1.7485714285714287, "no_speech_prob": 0.0, "words": [{"start": 690.66, "end": 691.6, "word": "واضح؟", "probability": 0.82049560546875}, {"start": 691.6, "end": 691.84, "word": " OH", "probability": 0.6298828125}, {"start": 691.84, "end": 692.36, "word": " أسد", "probability": 0.4862060546875}, {"start": 692.36, "end": 692.82, "word": " تيرمينال", "probability": 0.83564453125}, {"start": 692.82, "end": 693.68, "word": " لاحظوا", "probability": 0.7554931640625}, {"start": 693.68, "end": 694.46, "word": " بهذا", "probability": 0.944580078125}, {"start": 694.46, "end": 695.02, "word": " الشكل", "probability": 0.993896484375}, {"start": 695.02, "end": 695.88, "word": " بإمكاني", "probability": 0.97138671875}, {"start": 695.88, "end": 696.24, "word": " أرسم", "probability": 0.7589518229166666}, {"start": 696.24, "end": 696.46, "word": " أي", "probability": 0.6572265625}, {"start": 696.46, "end": 697.4, "word": " بيبتايد", "probability": 0.8871256510416666}, {"start": 697.4, "end": 698.66, "word": " فالبيبتايد", "probability": 0.8793247767857143}, {"start": 698.66, "end": 699.4, "word": " معروف", "probability": 0.98388671875}, {"start": 699.4, "end": 700.28, "word": " فيه", "probability": 0.56591796875}, {"start": 700.28, "end": 700.74, "word": " هيكل", "probability": 0.955078125}, {"start": 700.74, "end": 701.74, "word": " كربوني", "probability": 0.9619140625}, {"start": 701.74, "end": 703.04, "word": " متكرر", "probability": 0.9734700520833334}, {"start": 703.04, "end": 704.04, "word": " الهيكل", "probability": 0.8443603515625}, {"start": 704.04, "end": 704.7, "word": " الكربوني", "probability": 0.982177734375}, {"start": 704.7, "end": 704.84, "word": " مع", "probability": 0.99462890625}, {"start": 704.84, "end": 705.58, "word": " النيتروجين", "probability": 0.778564453125}, {"start": 705.58, "end": 705.72, "word": " اللي", "probability": 0.5888671875}, {"start": 705.72, "end": 705.96, "word": " هو", "probability": 0.9755859375}, {"start": 705.96, "end": 708.46, "word": " NCCOO", "probability": 0.4517822265625}, {"start": 708.46, "end": 710.2, "word": " NCCOO", "probability": 0.75567626953125}, {"start": 710.2, "end": 711.74, "word": " NCCOO", "probability": 0.863525390625}, {"start": 711.74, "end": 713.1, "word": " NCCOO", "probability": 0.82220458984375}, {"start": 713.1, "end": 714.34, "word": " الاختلاف", "probability": 0.871337890625}, {"start": 714.34, "end": 714.94, "word": " وين؟", "probability": 0.72412109375}], "temperature": 1.0}, {"id": 31, "seek": 74277, "start": 715.75, "end": 742.77, "text": "بال R groups طبعا هذا الاختلاف بيخلي ال peptides و ال proteins مايكونوش polymers حقيقيين لابد من معرفة إيش ال sequence لهم لابد من معرفة ال sequence إيش تسلسلهم الآن لو إجيت جبتلكوا سؤال مثلا قلتلكوا والله هذا ال peptide يجلسين قلانين سستين فين القلانين؟", "tokens": [3555, 6027, 497, 3935, 23032, 3555, 3615, 995, 23758, 2423, 47283, 2655, 15040, 5172, 4724, 1829, 9778, 20292, 2423, 41781, 1875, 4032, 2423, 15577, 19446, 1829, 30544, 2407, 8592, 6754, 18552, 11331, 38436, 38436, 9957, 5296, 16758, 3215, 9154, 20449, 28480, 3660, 11933, 1829, 8592, 2423, 8310, 5296, 16095, 5296, 16758, 3215, 9154, 20449, 28480, 3660, 2423, 8310, 11933, 1829, 8592, 6055, 3794, 1211, 3794, 1211, 16095, 6024, 48506, 45164, 11933, 7435, 36081, 10874, 3555, 2655, 23275, 14407, 8608, 33604, 6027, 50113, 15040, 12174, 1211, 2655, 23275, 14407, 16070, 43761, 23758, 2423, 41781, 482, 7251, 7435, 1211, 3794, 9957, 12174, 1211, 7649, 9957, 8608, 14851, 9957, 8978, 1863, 25062, 1211, 7649, 9957, 22807], "avg_logprob": -0.2150493367460736, "compression_ratio": 1.7521367521367521, "no_speech_prob": 0.0, "words": 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723.77, "word": " مايكونوش", "probability": 0.89765625}, {"start": 723.77, "end": 724.51, "word": " polymers", "probability": 0.7098388671875}, {"start": 724.51, "end": 725.51, "word": " حقيقيين", "probability": 0.9407958984375}, {"start": 725.51, "end": 726.47, "word": " لابد", "probability": 0.9158528645833334}, {"start": 726.47, "end": 726.67, "word": " من", "probability": 0.98974609375}, {"start": 726.67, "end": 727.29, "word": " معرفة", "probability": 0.99560546875}, {"start": 727.29, "end": 727.77, "word": " إيش", "probability": 0.7760416666666666}, {"start": 727.77, "end": 729.05, "word": " ال", "probability": 0.888671875}, {"start": 729.05, "end": 729.85, "word": " sequence", "probability": 0.97216796875}, {"start": 729.85, "end": 730.53, "word": " لهم", "probability": 0.7330322265625}, {"start": 730.53, "end": 731.43, "word": " لابد", "probability": 0.8655598958333334}, {"start": 731.43, "end": 731.57, "word": " من", "probability": 0.9921875}, {"start": 731.57, "end": 732.15, "word": " معرفة", "probability": 0.9967447916666666}, {"start": 732.15, "end": 732.57, "word": " ال", "probability": 0.78173828125}, {"start": 732.57, "end": 733.05, "word": " sequence", "probability": 0.98974609375}, {"start": 733.05, "end": 733.29, "word": " إيش", "probability": 0.93017578125}, {"start": 733.29, "end": 734.07, "word": " تسلسلهم", "probability": 0.951171875}, {"start": 734.07, "end": 734.89, "word": " الآن", "probability": 0.6968994140625}, {"start": 734.89, "end": 735.29, "word": " لو", "probability": 0.9677734375}, {"start": 735.29, "end": 735.59, "word": " إجيت", "probability": 0.6018880208333334}, {"start": 735.59, "end": 736.09, "word": " جبتلكوا", "probability": 0.88505859375}, {"start": 736.09, "end": 736.59, "word": " سؤال", "probability": 0.9881184895833334}, {"start": 736.59, "end": 737.13, "word": " مثلا", "probability": 0.99169921875}, {"start": 737.13, "end": 737.93, "word": " قلتلكوا", "probability": 0.8181640625}, {"start": 737.93, "end": 738.25, 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اللي فيها المثل على الأولى و اللي فيها الأتش على التانية", "tokens": [2304, 3615, 23758, 2423, 39184, 494, 662, 482, 10874, 46152, 2655, 36632, 44049, 38207, 8978, 3224, 5551, 1211, 7649, 9957, 11933, 1829, 7435, 20292, 3794, 9957, 8608, 1829, 14851, 9957, 8978, 1863, 16247, 1211, 7649, 9957, 22807, 32771, 13546, 2655, 36632, 44049, 38207, 19446, 18863, 15040, 28671, 49374, 16095, 22807, 436, 366, 15067, 307, 298, 433, 1975, 46456, 46538, 14407, 8978, 3714, 14407, 4587, 3615, 2423, 9640, 2655, 3555, 41193, 25961, 2655, 34105, 50113, 15040, 13672, 1829, 8978, 11296, 9673, 12984, 1211, 5551, 3615, 23942, 6055, 7649, 1829, 4032, 24401, 3660, 20328, 9640, 2655, 13672, 1829, 8978, 11296, 9673, 12984, 1211, 15844, 16247, 12610, 7578, 4032, 13672, 1829, 8978, 11296, 16247, 2655, 8592, 15844, 16712, 7649, 10632], "avg_logprob": -0.20934851278187866, "compression_ratio": 1.8855932203389831, "no_speech_prob": 0.0, "words": [{"start": 743.81, "end": 744.33, "word": "مع", "probability": 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وهنا اثل لان هدول متماثلات", "tokens": [34, 422, 422, 383, 422, 422, 6024, 48506, 8032, 3215, 12610, 9673, 7435, 2304, 34268, 9957, 13672, 1829, 8032, 2304, 47525, 2407, 7251, 1829, 7435, 1829, 10874, 1863, 3555, 16095, 50113, 1211, 1975, 2407, 1975, 12984, 1211, 4724, 5172, 2288, 4587, 8592, 1975, 15730, 1975, 1829, 7435, 2655, 34105, 50113, 1211, 37037, 8315, 1975, 12984, 1211, 1975, 2407, 34105, 50113, 1211, 37037, 8315, 1975, 12984, 1211, 5296, 7649, 8032, 3215, 12610, 44650, 2304, 5718, 104, 1211, 9307], "avg_logprob": -0.2542067426137435, "compression_ratio": 1.8203125, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1142.33, "end": 1142.85, "word": "C", "probability": 0.59814453125}, {"start": 1142.85, "end": 1143.37, "word": " O", "probability": 0.2763671875}, {"start": 1143.37, "end": 1145.07, "word": " O", "probability": 0.91796875}, {"start": 1145.07, "end": 1146.05, "word": " C", "probability": 0.77197265625}, {"start": 1146.05, "end": 1146.27, "word": " O", 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اثل", "probability": 0.9012044270833334}, {"start": 1153.95, "end": 1154.99, "word": " بفرقش", "probability": 0.7689453125}, {"start": 1154.99, "end": 1155.27, "word": " اذا", "probability": 0.556396484375}, {"start": 1155.27, "end": 1155.69, "word": " ايجت", "probability": 0.74884033203125}, {"start": 1155.69, "end": 1155.93, "word": " هنا", "probability": 0.9306640625}, {"start": 1155.93, "end": 1156.47, "word": " مثل", "probability": 0.865478515625}, {"start": 1156.47, "end": 1156.77, "word": " وهنا", "probability": 0.767578125}, {"start": 1156.77, "end": 1157.39, "word": " اثل", "probability": 0.9768880208333334}, {"start": 1157.39, "end": 1157.81, "word": " او", "probability": 0.955078125}, {"start": 1157.81, "end": 1158.07, "word": " هنا", "probability": 0.88818359375}, {"start": 1158.07, "end": 1158.51, "word": " مثل", "probability": 0.72607421875}, {"start": 1158.51, "end": 1158.77, "word": " وهنا", "probability": 0.824951171875}, {"start": 1158.77, "end": 1159.09, "word": " اثل", "probability": 0.9715169270833334}, {"start": 1159.09, "end": 1159.33, "word": " لان", "probability": 0.687744140625}, {"start": 1159.33, "end": 1159.61, "word": " هدول", "probability": 0.8917643229166666}, {"start": 1159.61, "end": 1160.75, "word": " متماثلات", "probability": 0.8643391927083334}], "temperature": 1.0}, {"id": 50, "seek": 118215, "start": 1161.91, "end": 1182.15, "text": "كذلك الحال في ال unhydrate لو حطيت هنا methyl وهنا phenyl يعني acidic بنزوك او حطيت هنا phenyl وهنا methyl نفس الاشي هذه المجموعة متماثلة فأي واحد احط يمين او شمال مابفرقش الان لو اجيت اعتبرت ان انا بدي اشتغل على الامد", "tokens": [4117, 8848, 23275, 21542, 6027, 8978, 2423, 517, 21591, 4404, 45164, 11331, 9566, 36081, 34105, 48441, 37037, 8315, 7279, 5088, 37495, 22653, 39514, 44945, 11622, 2407, 4117, 1975, 2407, 11331, 9566, 36081, 34105, 7279, 5088, 37037, 8315, 48441, 8717, 36178, 2423, 33599, 1829, 29538, 9673, 7435, 2304, 2407, 27884, 44650, 2304, 5718, 104, 37977, 6156, 10721, 1829, 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1200.54, "text": "و اشوف اللي هي ال peptide bond هل يا تورا في عندي تماثل ولا لأ لما باجي بشتغل اتذكروا ان احنا قولنا بنشتغل N C C double bond او و بعدها بنشتغل N C", "tokens": [2407, 1975, 8592, 38688, 13672, 1829, 39896, 2423, 41781, 482, 6086, 8032, 1211, 35186, 6055, 13063, 995, 8978, 18871, 16254, 46811, 5718, 104, 1211, 49429, 5296, 10721, 5296, 15042, 4724, 26108, 1829, 4724, 8592, 2655, 17082, 1211, 1975, 2655, 8848, 37983, 14407, 16472, 1975, 5016, 8315, 12174, 12610, 8315, 44945, 8592, 2655, 17082, 1211, 426, 383, 383, 3834, 6086, 1975, 2407, 4032, 39182, 11296, 44945, 8592, 2655, 17082, 1211, 426, 383], "avg_logprob": -0.23697916294137636, "compression_ratio": 1.4935897435897436, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1183.88, "end": 1184.08, "word": "و", "probability": 0.8310546875}, {"start": 1184.08, "end": 1184.78, "word": " اشوف", "probability": 0.745849609375}, {"start": 1184.78, "end": 1185.18, "word": " اللي", "probability": 0.633056640625}, 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اتعرفنا + +4 +00:00:34,200 --> 00:00:38,560 +طبعا كيف بيكونوا بالوسط الحامض أو القاعدى كيف + +5 +00:00:38,560 --> 00:00:44,280 +بتتأثر الشحنة تبعتهمبال بي اتش وهذا الكلام بيدى + +6 +00:00:44,280 --> 00:00:49,560 +الى طريقة عملية لفصلهم عن بعضهم البعض اعتمادا على + +7 +00:00:49,560 --> 00:00:54,380 +اختلاف ال بي اتش اللى هي فكرة ال Electrophoresis + +8 +00:00:54,380 --> 00:01:01,420 +الان اذا بنستمر في الموضوع لو اجينا بدنا نتكلم على + +9 +00:01:01,420 --> 00:01:07,460 +تفاعلات الأحماض الأمينية طبعا اذا قلنا amino acids + +10 +00:01:07,460 --> 00:01:13,680 +كلمتين aminoاللي هي الـ Amines اللي أخدناهم في + +11 +00:01:13,680 --> 00:01:20,720 +الفصل شبطر 11 و Assets الأحمد اللي أخدناهم في شبطر + +12 +00:01:20,720 --> 00:01:26,640 +10 إذا تفاعلاتهم هي تفاعلات الـ Amines و الأحمد + +13 +00:01:26,640 --> 00:01:34,030 +يعني أي تفاعل كنا بناخده للأمينفي السابق في ال + +14 +00:01:34,030 --> 00:01:37,850 +organic العادية هيتفاعل ال amino acids فيه من خلال + +15 +00:01:37,850 --> 00:01:42,820 +ال amino group أي تفاعل كنا بناخده لل acidهيكون + +16 +00:01:42,820 --> 00:01:48,060 +نفس الاشي مع ال amino acids يعني مثلا عندكوا جملة + +17 +00:01:48,060 --> 00:01:54,600 +عامة انه acid زائد alcohol ايش بيعطينا Easter بناء + +18 +00:01:54,600 --> 00:01:59,420 +على ذلك ال amino acids فيهم acids حتى لو كانوا على + +19 +00:01:59,420 --> 00:02:04,180 +شكل ال soul تبعهم بيظلوا acids هذا ال acid لو اجت + +20 +00:02:04,180 --> 00:02:09,140 +فعلته مع alcohol هاي جزء ال acid هاي ال alcohol + +21 +00:02:10,310 --> 00:02:16,150 +ماذا سيعطيني إيستار سيصبح C double bond O OR أو + +22 +00:02:16,150 --> 00:02:22,830 +CO2 R إذا هذا مثال على أنه تفاعل كحامض أسد زائد + +23 +00:02:22,830 --> 00:02:28,430 +ألكوهول إيستار ليس هناك شيء جديد كذلك الحالة لو + +24 +00:02:28,430 --> 00:02:32,110 +إحنا جينا على ال amino group حتى لو كنا كاتبينها + +25 +00:02:32,110 --> 00:02:36,590 +على شكل NH3 بلس إحنا مجرد ما نفعله مع base ترجع + +26 +00:02:36,590 --> 00:02:37,710 +نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو + +27 +00:02:37,710 --> 00:02:37,710 +نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو + +28 +00:02:37,710 --> 00:02:37,710 +نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نحو نح + +29 +00:02:37,830 --> 00:02:41,930 +عادية لو اتش هنا قولنا هذا في النهاية ان اتش توحت + +30 +00:02:41,930 --> 00:02:46,970 +صفة بدنا نفعلها مع acid chloride او مع ايستر او مع + +31 +00:02:46,970 --> 00:02:50,330 +acid anhydride كيف كان الأمين يتفاعل مع ال acid + +32 +00:02:50,330 --> 00:02:57,310 +chloride بالإبدال بهذا الشكل و يعمل عملية إبدال في + +33 +00:02:57,310 --> 00:03:03,030 +هذه الحالة هيعطيني أميدفهذه الحالة هيعطيني amide + +34 +00:03:03,030 --> 00:03:09,170 +واضح هاي ال amide N H C double bond O واضح ففكرة + +35 +00:03:09,170 --> 00:03:14,510 +التفاعلات ال amino acids هي فكرة بسيطة للي فيهم + +36 +00:03:14,510 --> 00:03:18,830 +سابقا تفاعلات ال amines ولي فيهم سابقا تفاعلات ال + +37 +00:03:18,830 --> 00:03:24,410 +acids يمكن أخدتوا انتوا ان ammonia او amine زائد + +38 +00:03:24,410 --> 00:03:31,370 +acid شو كان بيعطيني بشكل عامأمد تمام وبناء على ذلك + +39 +00:03:31,370 --> 00:03:37,690 +هذه الفكرة أيضا ممكن ناخدها لكن من خلال أن الفاعل + +40 +00:03:37,690 --> 00:03:44,640 +جزيئين من ال amino acids مع بعض و من بعضجزء ناخد + +41 +00:03:44,640 --> 00:03:51,320 +منه جزء ناخد منه مجموعة الـ nitrogen الـ NH2 و جزء + +42 +00:03:51,320 --> 00:03:56,860 +ناخد منه جزء ال acid واضح فلما نيجي نقول NH2 زي ال + +43 +00:03:56,860 --> 00:04:02,840 +acid اتفاعلوا شو هيعطوني امد اذا two amino acids + +44 +00:04:02,840 --> 00:04:08,640 +react with each other to form amides واضح هذا + +45 +00:04:08,640 --> 00:04:13,510 +الكلام اللي موجود هنايعني لو أنا اتطلعت على هذا + +46 +00:04:13,510 --> 00:04:18,770 +المركب اللي بيطلع عندى هذا أصلا كان NH2 Amino Acid + +47 +00:04:18,770 --> 00:04:22,970 +و هذا ال Amino Acid التانى هذا Amino Acid و هذا + +48 +00:04:22,970 --> 00:04:28,850 +Amino Acid كان إيش؟ C double bond O OH لما ال NH2 + +49 +00:04:28,850 --> 00:04:36,760 +إجت اتفاعلت هنا شو عملت؟ طردت؟الـ OH وانخصم من هنا + +50 +00:04:36,760 --> 00:04:43,800 +H OH مع H اذا صفينا على هذا الشكل هاي ال two amino + +51 +00:04:43,800 --> 00:04:49,500 +acids اتحدوا مع بعض عملوا قمد C double bond O NH + +52 +00:04:49,500 --> 00:04:53,520 +وين الرابطة الجديدة اللي اتكونت بين ال two amino + +53 +00:04:53,520 --> 00:05:05,080 +acids؟ هذه هذا كان نهاية الجزء الأولان اتش تو وكان + +54 +00:05:05,080 --> 00:05:09,220 +هذا الجزء نهايته سيضا بالبوند او او اتش الان اتش + +55 +00:05:09,220 --> 00:05:12,220 +اتصلت بالسيضا بالبوند او او اتش اذا هذه الرابطة + +56 +00:05:12,220 --> 00:05:16,800 +اللي اتكونت اللي هي الاميد بوند الان لأنه هنا انا + +57 +00:05:16,800 --> 00:05:21,820 +بابدأ ادمج amino acids مع بعضهم البعض لتكوين + +58 +00:05:21,820 --> 00:05:25,580 +بيبتايد هذه رابطة هنا اتكونت و رابط هنا اتكونت هذه + +59 +00:05:25,580 --> 00:05:30,860 +الاميد بوند بنصير احنا نعطيها اسم بيبتايد بوندواضح + +60 +00:05:30,860 --> 00:05:36,140 +فلما نقول ال peptide bond هي حقيقة ال amide bond + +61 +00:05:36,140 --> 00:05:40,760 +واضح لكن لأنه انا لما بفعل two amino acids او + +62 +00:05:40,760 --> 00:05:46,680 +three amino acids بكون ايش؟ peptide و لو كبروا + +63 +00:05:46,680 --> 00:05:52,080 +كتير بصيروا ايش؟ protein واضح فال peptides و ال + +64 +00:05:52,080 --> 00:05:57,060 +proteins فيهم ال amide bond واضح او بنسميها في هذه + +65 +00:05:57,060 --> 00:06:02,470 +الحالة تخصيصاببتايت بوند فلو قلنا مثلا سؤال ببتايت + +66 +00:06:02,470 --> 00:06:06,330 +بوند is an amide bond طبعا هي امد see double bond + +67 +00:06:06,330 --> 00:06:13,090 +O and H طبعا هيكون فيها كل خواص الامدز انه هتكون + +68 +00:06:13,090 --> 00:06:18,490 +هذه المنطقة كامد reactive ولا unreactive + +69 +00:06:18,490 --> 00:06:23,850 +unreactive احنا قلنا الكلمة الأساسية المميزة + +70 +00:06:23,850 --> 00:06:29,670 +للامدز they are unreactiveو بناء على ذلك حتى ال + +71 +00:06:29,670 --> 00:06:34,830 +hydrolysis تبعهم بيكون سهل ولا صعبصعب و لذلك بعد + +72 +00:06:34,830 --> 00:06:38,130 +شوية لما تيجوا تاخدوا protein على سبيل المثال + +73 +00:06:38,130 --> 00:06:43,290 +امكون من amino acids و اقول بدي احلل هذا ال + +74 +00:06:43,290 --> 00:06:49,490 +protein لالمفردات تبعته بيكون الجواب و الله اغليه + +75 +00:06:49,490 --> 00:06:56,110 +في وسط حامض مركز مثلا لمدة 24 ساعة و هو يغلي عشان + +76 +00:06:56,110 --> 00:07:02,230 +تقدر تكسر ال ايش ال amides bonds هذي شروط سهلة ولا + +77 +00:07:02,230 --> 00:07:08,990 +صعبة؟شروط صعبة الان لما احنا بنعمل اتحاد ل two + +78 +00:07:08,990 --> 00:07:13,490 +amino acids بنكون ال peptide bond ممكن نحط كمان + +79 +00:07:13,490 --> 00:07:18,050 +amino acid ها بالتأكيد ممكن كمان نستمر نجيب مجموعة + +80 +00:07:18,050 --> 00:07:24,370 +amino و هكذا الان ال peptide عادة لما احنا بنكونه + +81 +00:07:24,370 --> 00:07:32,070 +بنلاحظ انه في شيء مشترك في هيكل عام MCC double + +82 +00:07:32,070 --> 00:07:37,540 +bond Oهذا الهيكل العام إيش ماله؟ متكرر يعني هاي في + +83 +00:07:37,540 --> 00:07:44,780 +عندى هنا N C C double bond O بعد شو بيجيني كمان + +84 +00:07:44,780 --> 00:07:53,670 +مرة؟ NC C double bond O لو عملت كمان شو هيجيني N C + +85 +00:07:53,670 --> 00:07:59,630 +C double bond O و هكذا واضحة هذه النقطة فهذا شيء + +86 +00:07:59,630 --> 00:08:04,910 +مشترك في ال peptides الان اللي بيكون عادة على + +87 +00:08:04,910 --> 00:08:10,890 +الإيد الشمال بالنسبة لكمبنبدأ منه بنقول ان هذا + +88 +00:08:10,890 --> 00:08:16,670 +الجزء بيمثل ال unterminal of the peptide يعني + +89 +00:08:16,670 --> 00:08:21,290 +الطرف اللي فيه نيتروجين من ال peptide بنرسمه زيكي + +90 +00:08:21,290 --> 00:08:27,000 +عشان الكلاش يفهم مع بعضهوهذا الجزء الأخير بيكون اي + +91 +00:08:27,000 --> 00:08:33,700 +terminal ال carbon terminal فانا لما بدي اعمل + +92 +00:08:33,700 --> 00:08:38,120 +peptide سواء مكون من واحد او اتنين او تلاتة او + +93 +00:08:38,120 --> 00:08:44,800 +اربعة او خمسة amino acids سهل جدا عليا بدي اعمل N + +94 +00:08:44,800 --> 00:08:50,000 +terminal و بدي اعمل C terminal الان ما الوحدة + +95 +00:08:50,000 --> 00:08:59,730 +المتكررةماذا المختلف؟ ال R بناء + +96 +00:08:59,730 --> 00:09:04,870 +على ذلك لو انا الان باجي بقولكم والله انا بدي + +97 +00:09:04,870 --> 00:09:12,740 +بيبتايد من اربعة amino acids ارسمولياممكن هجيبلكوا + +98 +00:09:12,740 --> 00:09:16,520 +سؤال زيك في الامتحان أرسموني ال بيبتايد اللي من + +99 +00:09:16,520 --> 00:09:22,560 +أربعة amino acids اللي هم مثلا بهذا الشكل إجليسين + +100 +00:09:22,560 --> 00:09:32,270 +ألانين سيستين وفينل ألانينهتيجيوا تقولولا احنا + +101 +00:09:32,270 --> 00:09:37,010 +بنكون حافظين هدولة؟ احنا اتفقنا معكم ان الـR group + +102 +00:09:37,010 --> 00:09:40,870 +في الـGlycine H بتكون تحفظوها وفي الالانين مثل + +103 +00:09:40,870 --> 00:09:46,810 +بتكون تحفظوها وفي الستين CH2SH بتكون تعرفوها بالفن + +104 +00:09:46,810 --> 00:09:51,650 +الالانين CH2 فن اللي بعطيكوا بس بعطيكوا الـR الان + +105 +00:09:51,650 --> 00:09:57,750 +لو كان الكلام ارسم هذا الـpeptideكيف بدى ارسم هذا + +106 +00:09:57,750 --> 00:10:03,090 +البيبتايد؟ بدى اجي احط الهيكل تبع البيبتايد الهيكل + +107 +00:10:03,090 --> 00:10:07,270 +تبع البيبتايد اربع وحدات الان هيكونوا بهذا الشكل N + +108 +00:10:07,270 --> 00:10:14,270 +C C double bond O هى اول وحدة amino acid بعدين N C + +109 +00:10:14,270 --> 00:10:22,920 +C double bond O بعدين N C C double bond O بعدينN C + +110 +00:10:22,920 --> 00:10:27,040 +C double bond O الان هى صار عندى أربع وحدات + +111 +00:10:27,040 --> 00:10:36,060 +تتخيلوهم هذه وحدة تنتين تلاتة أربعة واضحة الفكرة + +112 +00:10:36,060 --> 00:10:43,100 +الان ايش بيظل عند المجموعة ال R اللى بتجينه من ال + +113 +00:10:43,100 --> 00:10:48,160 +glycine H و + +114 +00:10:48,160 --> 00:10:54,070 +ايش ال R اللى من القلانين مثلو إيش ال R اللي من + +115 +00:10:54,070 --> 00:11:01,770 +الستين؟ CH2SH و إيش ال R اللي من الفن الألانين؟ + +116 +00:11:01,770 --> 00:11:08,730 +CH2 فنل واضح؟ لحظوا إذا أنا مجرد معرفتي الهيكل + +117 +00:11:08,730 --> 00:11:13,830 +بكرره بعد هيك أن أستكمل الكلام إنه هذه مثلا NH2، + +118 +00:11:13,830 --> 00:11:20,010 +إنه هذه CH إنه هذه NH1، إنه هذه CH، إنه هذه NH، + +119 +00:11:20,010 --> 00:11:25,760 +هذه CHعشان يكتمل الشكل العام بتاع الـ OH + +120 +00:11:30,660 --> 00:11:35,880 +واضح؟ OH أسد تيرمينال لاحظوا بهذا الشكل بإمكاني + +121 +00:11:35,880 --> 00:11:41,740 +أرسم أي بيبتايد فالبيبتايد معروف فيه هيكل كربوني + +122 +00:11:41,740 --> 00:11:48,460 +متكرر الهيكل الكربوني مع النيتروجين اللي هو NCCOO + +123 +00:11:48,460 --> 00:11:57,450 +NCCOO NCCOO NCCOO الاختلاف وين؟بال R groups طبعا + +124 +00:11:57,450 --> 00:12:02,570 +هذا الاختلاف بيخلي ال peptides و ال proteins + +125 +00:12:02,570 --> 00:12:09,050 +مايكونوش polymers حقيقيين لابد من معرفة إيش ال + +126 +00:12:09,050 --> 00:12:14,070 +sequence لهم لابد من معرفة ال sequence إيش تسلسلهم + +127 +00:12:14,070 --> 00:12:18,670 +الآن لو إجيت جبتلكوا سؤال مثلا قلتلكوا والله هذا + +128 +00:12:18,670 --> 00:12:24,710 +ال peptide يجلسين قلانين سستين فين القلانين؟مع هذا + +129 +00:12:24,710 --> 00:12:31,490 +الـpeptide جلبت أي شيء فيه ألانين إيجليسين سيستين + +130 +00:12:31,490 --> 00:12:35,670 +فين الألانين؟ غيرت أي شيء ما العلاقة بينهم؟ they + +131 +00:12:35,670 --> 00:12:39,470 +are structural isomers اختلفوا في مواقع الارتباط + +132 +00:12:39,470 --> 00:12:44,810 +كانت هنا مثلا اللي فيها المثل أعلى تاني وحدة صارت + +133 +00:12:44,810 --> 00:12:46,690 +اللي فيها المثل على الأولى و اللي فيها الأتش على + +134 +00:12:46,690 --> 00:12:51,670 +التانيةهذا تغير في الارتباط ولا لأ؟ اذا they are + +135 +00:12:51,670 --> 00:12:56,830 +structural isomers واضح؟ they are structural + +136 +00:12:56,830 --> 00:13:08,190 +isomers هذه الـ + +137 +00:13:08,190 --> 00:13:13,190 +N-terminal وهذه الـ C-terminalكل بيبتايد إله + +138 +00:13:13,190 --> 00:13:18,250 +unterminal وإله c-terminal لما ببدأ أكتب بكتب بهذا + +139 +00:13:18,250 --> 00:13:23,350 +الشكل واضح؟ إذا ذكرنا بيبتايد بهذا الشكل أي واحدة + +140 +00:13:23,350 --> 00:13:26,230 +كان بإمكانها تخلي c-terminal هان وunterminal هان + +141 +00:13:26,230 --> 00:13:29,290 +بس مش متعودين نشتغل زي هيك في ال biochemistry عشان + +142 +00:13:29,290 --> 00:13:32,210 +الكل يفهم على بعضه + +143 +00:13:49,240 --> 00:13:54,780 +لحظوا معاه هذا الكلام بيعمل شغل كتير مهمة لو أنا + +144 +00:13:54,780 --> 00:14:00,160 +مثلا جبت بس two amino acids و بدي أخليهم يتحدوا مع + +145 +00:14:00,160 --> 00:14:06,160 +بعض يعني glycine و alanine ممكن أخليهم يتحدوا يكون + +146 +00:14:06,160 --> 00:14:11,610 +ل glycine في الأولوالألانين بعده ال glycine اللي + +147 +00:14:11,610 --> 00:14:16,390 +فيه H والألانين اللي فيه مثل أو أخلي الألانين في + +148 +00:14:16,390 --> 00:14:20,790 +الأول وال glycine بعده في هذه الحالة لو أنا بدي + +149 +00:14:20,790 --> 00:14:26,450 +أسمي Hannah ببطاي بشكل دقيق بقول الأساس تبعه الجزء + +150 +00:14:26,450 --> 00:14:31,630 +الأخر اللي هو الألانين متصل في إيش ال glycine + +151 +00:14:31,630 --> 00:14:36,980 +بعتبره على شكل مجموعة بسميه glycineألانين مرات هذه + +152 +00:14:36,980 --> 00:14:43,860 +التسمية بنختصرها بنعملها بهذا الشكل إجلاي ألا خلاص + +153 +00:14:43,860 --> 00:14:49,040 +بنمشي بنقبلها لكن لو بدنا نحكي بشكل دقيق إجلاي سل + +154 +00:14:49,040 --> 00:14:55,020 +ألانين أو إجلاي ألا الآن هذا إيش أول إشي ببدأ فيه + +155 +00:14:55,020 --> 00:15:02,930 +ببدأ هيك و بضلني ماشي ألانين إجلاي سلفلو انا بدى + +156 +00:15:02,930 --> 00:15:08,690 +اعمل اتحاد بينهم اتنين مختلفين صار عندى مش ببتايد + +157 +00:15:08,690 --> 00:15:15,170 +واحد صار عندى اتنين هل يا ترى هذا لجليسي القلانين + +158 +00:15:15,170 --> 00:15:23,270 +هو نفسه القلانيل الجليسين اتأملوا فيه هنا مثلا ال + +159 +00:15:23,270 --> 00:15:29,270 +CH3 جنب مجموعة الحامضهنا الـ H جنب مجموعة الحامض، + +160 +00:15:29,270 --> 00:15:32,570 +هذا اختلاف في ال bonding ولا لا؟ هنا الـ H جنب + +161 +00:15:32,570 --> 00:15:37,770 +الأمين، هنا ال CH3 جنب الأمين، إذا هذولا + +162 +00:15:37,770 --> 00:15:41,410 +المجموعتين، يعني لو كنا متخيلين أن هذه H، انعكسوا + +163 +00:15:41,410 --> 00:15:47,460 +ولا لأ؟أذن هدولة Structural isomers فلو إجينا + +164 +00:15:47,460 --> 00:15:47,960 +سئلنا + +165 +00:16:13,350 --> 00:16:23,530 +الـ Glycine واضحة هذه النقطة؟ الآن نرجع للقصة + +166 +00:16:23,530 --> 00:16:30,750 +القديمة تبعتنا لو يا تورا إجينا و خلطنا + +167 +00:16:34,170 --> 00:16:39,470 +الجليسين مع الانين احنا بنخلط جزء واحد ولا عدد + +168 +00:16:39,470 --> 00:16:44,070 +كبير من الجزيئات عدد كبير من الجزيئات وقلنا لهم + +169 +00:16:44,070 --> 00:16:48,610 +يلا اتفاعلوا مع بعض و اعملولنا peptides كام ناتج + +170 +00:16:48,610 --> 00:16:49,810 +بنتوقع؟ + +171 +00:16:51,890 --> 00:16:56,790 +اتذكروا لما كنا نخلط .. لما كنا نخلط على سبيل + +172 +00:16:56,790 --> 00:17:03,670 +المثال Methanol مع Ethanol عشان نحضر ال ether كام + +173 +00:17:03,670 --> 00:17:10,390 +ناتج كنا نطلع؟ تلاتة لما كنا نخلط Acetic acid مثلا + +174 +00:17:10,390 --> 00:17:15,930 +مع Benzoic acid عشان نطلع ال anhydride كام ناتج + +175 +00:17:15,930 --> 00:17:22,340 +بنطلع؟ تلاتةتلاتة طيب لما نيجي نخلط ألانين مع + +176 +00:17:22,340 --> 00:17:26,960 +إجلايسين و نقولهم اتفاعلوا كام ناتج بنطلع تلاتة .. + +177 +00:17:26,960 --> 00:17:32,040 +تلاتة .. تلاتة .. تلاتة .. تلاتة + +178 +00:17:32,040 --> 00:17:36,140 +.. تلاتة + +179 +00:17:36,140 --> 00:17:39,780 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +180 +00:17:39,780 --> 00:17:40,140 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +181 +00:17:40,140 --> 00:17:40,800 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +182 +00:17:40,800 --> 00:17:40,880 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +183 +00:17:40,880 --> 00:17:40,880 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +184 +00:17:40,880 --> 00:17:44,240 +تلاتة .. تلاتة .. تلطبعا هيبدأ يصير عندكوا استغراب + +185 +00:17:44,240 --> 00:17:50,520 +ليش .. ليش انا في الميثانول لما عملت ال ether لما + +186 +00:17:50,520 --> 00:17:56,040 +عملت ال ether طلع عندى بس تلت أشكال لما خلطت + +187 +00:17:56,040 --> 00:18:00,000 +ميثانول و إيثانول و لما خلطت أسيتك أسد مثلا مع + +188 +00:18:00,000 --> 00:18:04,060 +بنزويك أسد أعمل الانهيدريد طلع عندى برضه تلت أشكال + +189 +00:18:04,060 --> 00:18:10,300 +لكن لو بخلط ألانينمع إجلايسين على سبيل المثال عشان + +190 +00:18:10,300 --> 00:18:14,200 +أعمل بيبتايد هيطلع عندى أربع أشكال + +191 +00:18:20,420 --> 00:18:25,940 +شوفوا المجموعة الوظيفية المجموعة الوظيفية تبعت ال + +192 +00:18:25,940 --> 00:18:30,940 +ether تبعت ال ether و تبعت ال anhydride + +193 +00:18:30,940 --> 00:18:35,840 +symmetrical بفرق اش معها تيجي اي مجموعة على اليمين + +194 +00:18:35,840 --> 00:18:42,640 +و على الاشمال يعني خلينا نشوف ال ether لو بده احط + +195 +00:18:42,640 --> 00:18:49,650 +مثل و اثلأحط مثل يمين و لا مثل الشمال أو العكس + +196 +00:18:49,650 --> 00:18:56,570 +مجموعة الاثر عبارة عن إيش O بدا + +197 +00:18:56,570 --> 00:19:03,370 +تتحد من الجهتين مجموعة الانهيدريد عبارة عن إيشC O + +198 +00:19:03,370 --> 00:19:12,310 +O C O O الآن هدول المجمعتين اللي هم بدو ييجي جنبهم + +199 +00:19:12,310 --> 00:19:18,070 +مثل او اثل بفرقش اذا ايجت هنا مثل وهنا اثل او هنا + +200 +00:19:18,070 --> 00:19:23,030 +مثل وهنا اثل لان هدول متماثلاتكذلك الحال في ال + +201 +00:19:23,030 --> 00:19:26,690 +unhydrate لو حطيت هنا methyl وهنا phenyl يعني + +202 +00:19:26,690 --> 00:19:30,730 +acidic بنزوك او حطيت هنا phenyl وهنا methyl نفس + +203 +00:19:30,730 --> 00:19:34,270 +الاشي هذه المجموعة متماثلة فأي واحد احط يمين او + +204 +00:19:34,270 --> 00:19:40,250 +شمال مابفرقش الان لو اجيت اعتبرت ان انا بدي اشتغل + +205 +00:19:40,250 --> 00:19:42,150 +على الامد + +206 +00:19:43,880 --> 00:19:49,080 +و اشوف اللي هي ال peptide bond هل يا تورا في عندي + +207 +00:19:49,080 --> 00:19:53,380 +تماثل ولا لأ لما باجي بشتغل اتذكروا ان احنا قولنا + +208 +00:19:53,380 --> 00:20:02,210 +بنشتغل N C C double bond او و بعدها بنشتغل N CC + +209 +00:20:02,210 --> 00:20:06,550 +double bond O لما نضع الاتنين اللي موجودين الان + +210 +00:20:06,550 --> 00:20:11,490 +هذا بيصير يفرج ان انا بضع هنا ال H و هنا المثل + +211 +00:20:11,490 --> 00:20:16,410 +بتصير هذه ال H قريبة من ايش او هذه ال H بتصير بين + +212 +00:20:16,410 --> 00:20:21,950 +C double bond O و N H2 هنا لو اجيت بضع المجموعة + +213 +00:20:21,950 --> 00:20:26,210 +التانية بتكون عند C double bond O OH مع N H واحدة + +214 +00:20:26,390 --> 00:20:30,150 +فهل هدولة بيكونوا بنفس ال environment لأ لكن انا + +215 +00:20:30,150 --> 00:20:34,030 +لو حطيتها مثل و مثل ايش بوصف مثل بقول جانبه و مثل + +216 +00:20:34,030 --> 00:20:39,410 +جانبه لو حطيتها مثل و مثل مثل مثل مثل مثل مثل مثل + +217 +00:20:39,410 --> 00:20:41,430 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +218 +00:20:41,430 --> 00:20:41,830 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +219 +00:20:41,830 --> 00:20:43,950 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +220 +00:20:43,950 --> 00:20:43,950 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +221 +00:20:43,950 --> 00:20:43,950 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +222 +00:20:43,950 --> 00:20:43,970 +مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل + +223 +00:20:43,970 --> 00:20:51,250 +مثل + +224 +00:20:51,250 --> 00:20:54,740 +مثل مثلتلاتة products بدوا يطلع عندى أربعة + +225 +00:20:54,740 --> 00:20:59,900 +products خلّينا نشوفهم خلّينا نشوفهم هاي ال + +226 +00:20:59,900 --> 00:21:06,640 +glycine و ال alanine و خلطناهم مع بعض طبعا افترضوا + +227 +00:21:06,640 --> 00:21:12,960 +ال alanine الأزرق و ال glycine الأحمر زى ما احنا + +228 +00:21:12,960 --> 00:21:17,750 +عاملينهمش احنا ميزينهم ال glycine أحمر و ال + +229 +00:21:17,750 --> 00:21:22,410 +alanine أزرق هذه جزيئات كتيرة ممكن يتحد عندى + +230 +00:21:22,410 --> 00:21:27,290 +glycine مع glycine يعطوني بيبتايد بده يكون إيش هو + +231 +00:21:27,290 --> 00:21:35,270 +glycine glycine هذي H هذي H NCC double bond O NCC + +232 +00:21:35,270 --> 00:21:39,910 +double bond O وH وH يعني glycine مع glycine ممكن + +233 +00:21:39,910 --> 00:21:48,260 +يتحد عندى alanine مع alanineNCCWO NCCWO مثل و مثل + +234 +00:21:48,260 --> 00:21:54,040 +واضح هذا يكون أي بيبتايل ألانين ألانين ممكن يتحد + +235 +00:21:54,040 --> 00:22:01,180 +الآن إجليسين مع الألانين بهذا الشكل إجليسين ألانين + +236 +00:22:01,180 --> 00:22:10,550 +NCCWO NCCWO الهيكلة هذا إجليسين H هذا ألانينالان + +237 +00:22:10,550 --> 00:22:13,470 +الاتحاد يتم بطريقة تانية + +238 +00:22:20,780 --> 00:22:28,840 +يكون بهذا الشكل NCCWO NCCWO CH3HANA و N HANA هذا + +239 +00:22:28,840 --> 00:22:34,860 +إيش بده يكون الانين غلايسين ال بيبتايد الآن اتطلع + +240 +00:22:34,860 --> 00:22:40,840 +عليهم بالتأمل هل فيهم أشياء بتشبه بعض طبعا لو + +241 +00:22:40,840 --> 00:22:44,760 +سألتكوا ما العلاقة بين غلايسين غلايسين و الانين + +242 +00:22:44,760 --> 00:22:50,520 +انا الانينthey are .. استعملولي كلمات كيميائية + +243 +00:22:50,520 --> 00:22:56,040 +they are different compounds مراكبات مختلفة، لأن + +244 +00:22:56,040 --> 00:22:59,500 +أنا اتش و اتش و انا مثل و مثلها، دي مراكبات مختلفة + +245 +00:22:59,500 --> 00:23:03,700 +إجليسين إجليسين و ألانين ألانين they are different + +246 +00:23:03,700 --> 00:23:07,620 +compounds لو قلتلكوا ما العلاقة بين إجليسين + +247 +00:23:07,620 --> 00:23:11,950 +إجليسين و إجليسين ألانين؟they are different + +248 +00:23:11,950 --> 00:23:14,570 +compounds هان اتش و اتش و هان اتش و مثل صيغة + +249 +00:23:14,570 --> 00:23:18,850 +مختلفة كذلك الحال لو بدأ اقول الالانين الالانين و + +250 +00:23:18,850 --> 00:23:19,950 +الالانين الالانين الالانين الالانين الالانين + +251 +00:23:19,950 --> 00:23:20,490 +الالانين الالانين الالانين الالانين الالانين + +252 +00:23:20,490 --> 00:23:22,850 +الالانين الالانين الالانين الالانين الالانين + +253 +00:23:22,850 --> 00:23:25,270 +الالانين الالانين الالانين الالانين الالانين + +254 +00:23:25,270 --> 00:23:29,230 +الالانين الالانين الالانين الالانين الالانين + +255 +00:23:29,230 --> 00:23:30,250 +الالانين الالانين الالانين الالانين الالانين + +256 +00:23:30,250 --> 00:23:30,250 +الالانين الالانين الالانين الالانين الالانين + +257 +00:23:30,250 --> 00:23:30,610 +الالانين الالانين الالانين الالانين الالانين + +258 +00:23:30,610 --> 00:23:36,470 +الالانين الالانين الالانين الالان + +259 +00:23:36,500 --> 00:23:40,040 +الذرات تماما يعني لو حسبنا على الكمبيوتر ال + +260 +00:23:40,040 --> 00:23:43,420 +molecular weight لهذا و لهذا same number of atoms + +261 +00:23:43,420 --> 00:23:46,980 +same molecular weight بس الفكرة الاختلاف ان هنا + +262 +00:23:46,980 --> 00:23:49,920 +اجت ال H و هنا ال مثل هنا اجت ال مثل و هنا ال H + +263 +00:23:49,920 --> 00:23:54,400 +واضح ان they are different compounds يعني هذه ال H + +264 +00:23:54,400 --> 00:23:58,280 +محصورة بين C double bond O و N H 2 و المثل بين + +265 +00:23:58,280 --> 00:24:04,700 +acid و N H هنا ال H بين acid و N Hواضح الاختلاف + +266 +00:24:04,700 --> 00:24:09,420 +بناء على ذلك لو سألنا ان mixing two amino acids + +267 +00:24:09,420 --> 00:24:16,620 +together in fact will produce fourproducts تمام؟ + +268 +00:24:16,620 --> 00:24:23,300 +هيعطي أربع نواتج طبعا هتصير عندنا مشكلة هتصير + +269 +00:24:23,300 --> 00:24:27,640 +عندنا مشكلة يعني لو الناس كانوا بدهم لجليسين + +270 +00:24:27,640 --> 00:24:31,660 +جليسين هيسخنوا الجليسين مع نفسه بظروف تفاعل يتفاعل + +271 +00:24:31,660 --> 00:24:37,220 +بدي ألانين ألانين نفس الفكرة لكن لو كنت بدي أحضر + +272 +00:24:37,220 --> 00:24:44,260 +جليسين ألانينبدي طريقة معينة الان هذه الطريقة مش + +273 +00:24:44,260 --> 00:24:48,380 +مقبولة كيميائيا اصدقائك بتقولوا اخلطوهم وافصلوهم + +274 +00:24:48,380 --> 00:24:52,460 +اول اش اذا خلطناهم هنطلع مش ناتجين اربعة اربعة + +275 +00:24:52,460 --> 00:24:57,660 +الان في كيميائي بيحط حاله يقعد يفصل اربعة + +276 +00:24:57,660 --> 00:25:01,240 +compounds عن بعض اللي بيدخل المختبر وبيعرف غلبة + +277 +00:25:01,240 --> 00:25:05,420 +الشغل لايمكن يعملها لايمكن يعملها وبناء على ذلك + +278 +00:25:05,420 --> 00:25:14,780 +انا فعلا فعلا بدي طريقةفقط اطلع لي ناتج واحد يعني + +279 +00:25:14,780 --> 00:25:22,380 +هاي هدول المركباتفكروا معي قداش الكيميا منطقها هو + +280 +00:25:22,380 --> 00:25:28,260 +منطق إيش؟ هو منطق حياة .. منطق حياة شايفين؟ هدولة + +281 +00:25:28,260 --> 00:25:32,040 +المركبات الأربعة أنا خلطهم و افترضوا أخلط من هذا + +282 +00:25:32,040 --> 00:25:35,420 +مليون جزيئة و من هذا مليون جزيئة بدي أفعلهم أي + +283 +00:25:35,420 --> 00:25:39,460 +واحد اللي بدكم إياه أنتم يطلع إجلايسين ألانين يعني + +284 +00:25:39,460 --> 00:25:45,380 +اللي زي هيك و فقط واضح؟أنا بدي أفرجيكوا كيف بدي + +285 +00:25:45,380 --> 00:25:52,120 +أعملها كإنها لعبة برا ما أحكي عن إيش عن الكيميا + +286 +00:25:52,120 --> 00:25:56,980 +يعني أنا بدي أتعامل معها كإنها لعبة بدي أعطي لشخص + +287 +00:25:56,980 --> 00:26:00,680 +معين هدول أقوله اخلط بحيث أنه لما تيجي تشبكهم في + +288 +00:26:00,680 --> 00:26:04,660 +بعض ما يطلعش إلا هذا المركب اللي أنتوا طلبته + +289 +00:26:04,660 --> 00:26:09,440 +الأحمر و الأزرق تمام؟ كل هذا الكلام ممكن نعمله + +290 +00:26:09,440 --> 00:26:13,600 +بورقة clinics صغيرة إيش رأيكوا؟ + +291 +00:26:16,190 --> 00:26:21,210 +ورقة كلينكس الصغيرة ايش اللي بدنا نعمله احنا بنيجي + +292 +00:26:21,210 --> 00:26:26,590 +هذا بنعمله protection من هنا بنعمله حماية من هنا + +293 +00:26:26,590 --> 00:26:30,910 +ممنوع انت تتفعل بدنا ياك تتفعل من ال nitrogen + +294 +00:26:30,910 --> 00:26:34,090 +سكرنا مجموعة الحامض عشان مايجيش هذا يتفعل معاه من + +295 +00:26:34,090 --> 00:26:39,510 +هنا لاحظوا هذا الغلبان جاي يتفعل معاه راضي يتفعل؟ + +296 +00:26:39,510 --> 00:26:43,950 +شوفوا قبل ال protection قبل الحماية لو هذا إيجي + +297 +00:26:43,950 --> 00:26:50,400 +يتفعلكان بتفاعل، الآن بعد ما عملت الـ protection + +298 +00:26:50,400 --> 00:26:57,800 +إجا اتفاعلمش قادر يتفاعل سكرت هذا الجزء إذا بجعل + +299 +00:26:57,800 --> 00:27:02,880 +كل هدولة بعمل protection لل acid بإضافة مجموعة + +300 +00:27:02,880 --> 00:27:07,460 +كيميائية اتسكر هذا الجزء هذا بطل يتفاعل من هنا + +301 +00:27:07,460 --> 00:27:13,820 +ممتاز لسه عندي خوف ان هدول يتفاعلوا مع بعض الان + +302 +00:27:13,820 --> 00:27:18,800 +هدول هدين يتفاعلوا مع بعض انا منعت نص المشكلة الان + +303 +00:27:18,800 --> 00:27:23,530 +هذا من وين بدي امنعه يتفاعل؟من ال nitrogen باجي + +304 +00:27:23,530 --> 00:27:27,350 +بعمله protection من الطرف التاني عشان مايقدرش + +305 +00:27:27,350 --> 00:27:35,050 +يتفاعل منها أنا بنعمله شوية protection برضه هاي + +306 +00:27:35,050 --> 00:27:40,270 +بأمل أنها تكون عمليتها ال protection هذه زبطت + +307 +00:27:40,270 --> 00:27:41,670 +استعمل + +308 +00:27:46,120 --> 00:27:51,860 +بهمش انتوا في النهاية تصللكوا الفكرة ان الكيميائي + +309 +00:27:51,860 --> 00:27:57,980 +والبني آدم والطبيب لما بده يفكر بحالة مشكلة بده + +310 +00:27:57,980 --> 00:28:01,620 +يكون عنده أصول العلم لكن بده يفكر بمنطق الدنيا + +311 +00:28:01,620 --> 00:28:06,320 +بمنطق الدنيا يعني إليزاروف إليزاروف لما عمل + +312 +00:28:06,320 --> 00:28:11,040 +العملية الجراحية تبعته اللي بطول فيها عظام الساق + +313 +00:28:11,040 --> 00:28:15,320 +الناس اللي عندهم ساق أكثر من التانيةاللي فكر فيه + +314 +00:28:15,320 --> 00:28:20,420 +انه ايجي على العضمة جشرها و حط حديد هان و هان و + +315 +00:28:20,420 --> 00:28:25,040 +صار كل ساعتين اطول نص مل نص مل لانه مقدرش يسحب كل + +316 +00:28:25,040 --> 00:28:29,780 +شيء عظامه اعصابه اشي مرة واحدة عمدا أسبوعين بيضلوا + +317 +00:28:29,780 --> 00:28:34,020 +يسحب يسحب او بيطول العضمة كده؟ سبعة تمانية سانتي + +318 +00:28:34,020 --> 00:28:40,840 +بيعمل مسوافر عملية شهيرة جدا ال الازاروفالان + +319 +00:28:40,840 --> 00:28:45,720 +الظروف شاب تبع البسكليتات كيف بيشتغلوا بعمل العجال + +320 +00:28:45,720 --> 00:28:51,380 +واخذ منه فكرة كيف يعمل العملية واضحة الفكرة؟ الان + +321 +00:28:51,380 --> 00:28:58,120 +هاي انا عملت protection هنا لل acid part وهنا لل + +322 +00:28:58,120 --> 00:29:03,320 +amino part انه مش قادر يتفاعل من عند ال nitrogen + +323 +00:29:03,320 --> 00:29:09,740 +الان بدي اخلطهم و اقولوا متفاعلوا زي ما بدكمهيجي + +324 +00:29:09,740 --> 00:29:14,060 +يتفاعلوا اول اشي هذا هيجي يتفاعل من هنا هيلاجي ايش + +325 +00:29:14,060 --> 00:29:18,880 +امسكّر ال nitrogen تبعته من هنا امسكّر ال nitrogen + +326 +00:29:18,880 --> 00:29:24,180 +هذا هيجي يتفاعل مع هذا امسكّر ال CO هذا يتفاعل مع + +327 +00:29:24,180 --> 00:29:29,620 +هذا امسكّر ال CO لغاية كل هذه التفاعلات الان هذا + +328 +00:29:29,620 --> 00:29:36,820 +بيجي يتفاعل مع هذا امسكّر هذا بيجي يتفاعل مع هذا + +329 +00:29:38,200 --> 00:29:45,500 +طلعت one product شوف كيف .. هايوة one product هيك + +330 +00:29:45,500 --> 00:29:50,500 +ممكن .. الآن هيكمش ممكن اتنين زرق مش ممكن اتنين + +331 +00:29:50,500 --> 00:29:55,500 +حمر مش ممكن هذه الفكرة هي اللي عملوها الان كل اللي + +332 +00:29:55,500 --> 00:29:59,500 +بدنا نعمله اننا بدنا نكتب في المعادلة حطوا هنا حرف + +333 +00:29:59,500 --> 00:30:04,520 +بي بي ايش يعني بي يعني protecting group لما تكونوا + +334 +00:30:04,520 --> 00:30:08,000 +اعملوا هذا protected او اعملوا هذا protected لما + +335 +00:30:08,000 --> 00:30:12,140 +تشوفوا ال بي يعني من هنا ممنوع تتفاعلمجموعة + +336 +00:30:12,140 --> 00:30:16,120 +كيميائية صغيرة بنضيفها بتخلي هذا مثبت مابتفعلش مش + +337 +00:30:16,120 --> 00:30:21,980 +هندخل بتفاصيل أكتر من هي وجدها ماعندي إلا هذه + +338 +00:30:21,980 --> 00:30:25,780 +الإمكانية تشتغل هذا مش هيقدر يتفعل مع نفسه ولا هذا + +339 +00:30:25,780 --> 00:30:29,400 +هيتفعل مع نفسه هذا هيتفعل مع هذا بس one product + +340 +00:30:29,400 --> 00:30:37,260 +طلعت ال glycine ألانين واضحة الفكرة وهذا هو اللي + +341 +00:30:37,260 --> 00:30:38,220 +موجود يمكن + +342 +00:30:40,820 --> 00:30:45,960 +في ال slide يمكن متأخرة عندكم اربع خمسة slides + +343 +00:30:45,960 --> 00:30:52,520 +لاحظوا هاي جاب amino acid one سماه وعمل protection + +344 +00:30:52,520 --> 00:30:58,740 +لمجموعة معينة و جاب ال amino acid two وعمل + +345 +00:30:58,740 --> 00:31:02,620 +protection لمجموعة تانية نفس الفكرة اللي احنا + +346 +00:31:02,620 --> 00:31:06,280 +حكيناها الآن هذا بطل يتفعل من هنا هذا بتفعلش من + +347 +00:31:06,280 --> 00:31:10,850 +هنا مافيش غير هذا الجزءمع هذا الجزء بده يتفاعل + +348 +00:31:10,850 --> 00:31:17,010 +فبدل ما أطلع four different compounds بطلع one + +349 +00:31:17,010 --> 00:31:22,230 +طبعا في هذه الحالة هين طلعت بيبتايد الآن بعد ما + +350 +00:31:22,230 --> 00:31:26,090 +طلعته بتفاعل كيميائي بسيط بقدر أشيل هذا ال + +351 +00:31:26,090 --> 00:31:30,730 +protection أو هذا ال protection الآن تخيلوا لو كنا + +352 +00:31:30,730 --> 00:31:35,910 +بدنا نطول ال peptide يعني مش بس اتنين بد من هنا ما + +353 +00:31:35,910 --> 00:31:41,370 +يتفاعلشبخلّي هذا الـ protection بدي من هنا يتفاعل + +354 +00:31:41,370 --> 00:31:50,370 +بشيل هذا و بجيبله amino acid ال nitrogen تبعته not + +355 +00:31:50,370 --> 00:31:53,430 +protected و ال acid protected عشان مايتفعلش مع + +356 +00:31:53,430 --> 00:31:58,150 +بعضه اللي جاي جديد بيجي يتفعل هنا واحد اتنين تلاتة + +357 +00:31:58,150 --> 00:32:03,270 +اربعة ممكن في الآخر يتحضروا خمسة عشر و عشرين و + +358 +00:32:03,270 --> 00:32:09,540 +تلاتين جد ما بدكم و بالترتيببالترتيب بتحضره تمام + +359 +00:32:09,540 --> 00:32:13,220 +هذا + +360 +00:32:13,220 --> 00:32:20,160 +الكلام كله موجود ثانية أخدها لحظوا + +361 +00:32:20,160 --> 00:32:27,460 +على سبيل المثال هاي مركب اتخيلوا هذا عملوله + +362 +00:32:27,460 --> 00:32:28,100 +sequencing + +363 +00:32:31,070 --> 00:32:35,610 +عرفوا تفاصيله هنشوف طبعا كيف بعد شوية بنحلل المركب + +364 +00:32:35,610 --> 00:32:39,050 +نعرف ال amino acids إيجليسين إليوسين فالين + +365 +00:32:39,050 --> 00:32:44,870 +إيجلوتاميكاس وهكذا هذا الانسولين هذا الانسولين + +366 +00:32:44,870 --> 00:32:51,030 +سلسلتين من ال إيش ال peptides بيحللوه بيعرفوه واحد + +367 +00:32:51,030 --> 00:32:58,130 +واحد لاحظوا مابنقدرش زي السكر نعمل إيش شغلة to the + +368 +00:32:58,130 --> 00:33:02,700 +end لأ في إيش اسمهسيكوانس في ال .. بيبتايتز و في + +369 +00:33:02,700 --> 00:33:08,000 +الأمان هاي هذا مركّب الراجل اللي حضره أخد عليه + +370 +00:33:08,000 --> 00:33:13,600 +جائزة نوبل في الكيميا سنة الخمسة و خمسين هذا + +371 +00:33:13,600 --> 00:33:22,780 +Vincent de Vignod أخد عليه جائزة نوبل هذا هرمون من + +372 +00:33:22,780 --> 00:33:29,310 +تسعةأمينو أسد حضرهم من مرتبين سيستين تايروسين + +373 +00:33:29,310 --> 00:33:33,030 +إليوسين كذا أسبرتك أسستين برولين ليوسين إجلايسين + +374 +00:33:33,030 --> 00:33:37,750 +أعدهم واحد اتنين تلاتة أربعة خمس ستة سبعة تمانية + +375 +00:33:37,750 --> 00:33:42,970 +تسعة هنا في أس و أس ارتبطوا مع بعض مش موضوعنا ناخد + +376 +00:33:42,970 --> 00:33:46,630 +الديس الفايدمون بس هدول كام أمينو أسد في المحصلة + +377 +00:33:46,630 --> 00:33:52,590 +واحد اتنين تلاتة أربعة خمسة ستة سبعة تمانية تسعة + +378 +00:33:52,590 --> 00:33:59,330 +حضرهم من مرتبينبهذه الطريقة واضح؟ هذا عبارة عن + +379 +00:33:59,330 --> 00:34:05,790 +هرمون اسمه oxytocin مار عليكم؟ هرمون السعادة الله + +380 +00:34:05,790 --> 00:34:11,380 +يسعدكمالناس بيسموه هرمون السعادة فعلا، ليش؟ لأنهم + +381 +00:34:11,380 --> 00:34:14,640 +انتبعون علم النفس وغيره، بيقولوا هذا اللي بتتحكم + +382 +00:34:14,640 --> 00:34:19,440 +بالانفعالات وقصص السعادة والحب وكل إشي برتوب هذا + +383 +00:34:19,440 --> 00:34:24,160 +الهرمون طبعا إله تطبيقات تانية .. إله تطبيقات + +384 +00:34:24,160 --> 00:34:28,720 +تانية هو في الأصل بيطلع من ال posterior pituitary + +385 +00:34:28,720 --> 00:34:33,060 +gland يمكن بتسموها الغضب الكذرية ولا إيش .. هذا + +386 +00:34:33,060 --> 00:34:40,320 +بتحكم في القبضات الرحم في لحظة الولادةit regulates + +387 +00:34:40,320 --> 00:34:46,560 +uterine contraction and lactation وفي الرضاعة may + +388 +00:34:46,560 --> 00:34:49,360 +be administered .. إيش معنى administered في لغة + +389 +00:34:49,360 --> 00:34:54,800 +العلم الطبي؟ يُعطى كعلاج أو يوصف واضح؟ when it is + +390 +00:34:54,800 --> 00:34:58,440 +necessary to induce labor at childbirth يعني عشان + +391 +00:34:58,440 --> 00:35:03,750 +يزيد الطلجواضح؟ وبنفس الوقت زي ما حكينا إيه له + +392 +00:35:03,750 --> 00:35:09,670 +علاقة بالانفعالات الآن لاحظوا بيبتعد وحضر أول إشي + +393 +00:35:09,670 --> 00:35:13,570 +قبل ما يحضر إيش كان لازم نفصله من مصدره الطبيعي + +394 +00:35:13,570 --> 00:35:19,210 +ونعرف إيش ال sequence تبعته بعد ما نعرف ال + +395 +00:35:19,210 --> 00:35:23,230 +sequence ال road نقدر نعملها إذا صار عند أنا في + +396 +00:35:23,230 --> 00:35:27,850 +المنطقة شغلتين معرفة ال sequence و التحضير يمكن + +397 +00:35:27,850 --> 00:35:32,610 +احنا بدأنا الآنبفكرة التحضير لكن لسه ماحكيناش عن + +398 +00:35:32,610 --> 00:35:37,950 +فكرة إيش ال sequence فكرة ال sequence فكرة طويلة و + +399 +00:35:37,950 --> 00:35:46,110 +أخدت وقت طبعا من العلماء لكن + +400 +00:35:46,110 --> 00:35:50,170 +خلينا نضل ماشيين مع ال slides شوفنا قصة ال + +401 +00:35:50,170 --> 00:35:54,570 +protection خلصنا منها الآن من الروابط اللي + +402 +00:35:54,570 --> 00:36:00,840 +بتواجهنافي الـpeptides و بتمسكها مع بعض اللي هي + +403 +00:36:00,840 --> 00:36:04,180 +الـdisulfide bonds طبعا في hydrogen bonding أكيد + +404 +00:36:04,180 --> 00:36:08,740 +هيمر علينا لكن الـdisulfide bonds and all amino + +405 +00:36:08,740 --> 00:36:13,540 +acid اللي فيه الـsulfur ممكن يعمل الـdisulfide + +406 +00:36:13,540 --> 00:36:20,870 +bondال سيستين اللي قلتلكوا احفظوه اللي فيه CH2SH + +407 +00:36:20,870 --> 00:36:27,970 +فلو التقى سيستين مع سيستين SH وSH أخدنا في الثيول + +408 +00:36:27,970 --> 00:36:31,510 +شوفوا كيف العلم مبني على بعضه لما أخدنا الثيول + +409 +00:36:31,510 --> 00:36:35,530 +متذكرين قولنا الثيول بال Oxidation بعمل Di + +410 +00:36:35,530 --> 00:36:40,030 +-sulphide bond و بال reduction برجع لثيول و كان من + +411 +00:36:40,030 --> 00:36:46,770 +أمثلتها الشعر و قرنية العين و غيرهافهدولة لو اجينا + +412 +00:36:46,770 --> 00:36:51,650 +مثلا في بيبتايد طويل في طرف معين منه فيه 16 فيه + +413 +00:36:51,650 --> 00:36:58,590 +CH2SH و بطرف تاني 16 فيه CH2SH ممكن الـSH مع الـSH + +414 +00:36:58,590 --> 00:37:02,410 +يعملوا ايش دايس الفايدبوند هذا الكلام وين توي + +415 +00:37:02,410 --> 00:37:07,150 +شوفناه احنا؟ في الـOxytocin + +416 +00:37:08,650 --> 00:37:13,970 +تطلعوا معي هاي ال oxytocin ال amino acid نمرا واحد + +417 +00:37:13,970 --> 00:37:20,610 +16 يعني CH2SH وال amino acid واحد اتنين تلاتة + +418 +00:37:20,610 --> 00:37:27,430 +اربعة خمسة ستة السادس CH2SH + +419 +00:37:27,430 --> 00:37:34,110 +الآن ال SH مع ال SH عملوا oxidation عملوا ايش ال + +420 +00:37:34,110 --> 00:37:38,470 +di-sulfide bond فصار مبين هذا كأنه في حلقةعشان هيك + +421 +00:37:38,470 --> 00:37:40,930 +لما عدينا ال amino acids عديناهم تسعة، واحد، + +422 +00:37:40,930 --> 00:37:44,090 +اتنين، تلات، اربع، خمس، ستة، سبعة، تمانية، تسعة بس + +423 +00:37:44,090 --> 00:37:50,490 +الأول والسادس فيهم CH2SH CH2SH CH2SH CH2SH CH2SH + +424 +00:37:50,490 --> 00:37:50,490 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH + +425 +00:37:50,490 --> 00:37:51,550 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH + +426 +00:37:51,550 --> 00:37:51,550 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH + +427 +00:37:51,550 --> 00:37:52,730 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH + +428 +00:37:52,730 --> 00:37:54,930 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH + +429 +00:37:54,930 --> 00:38:03,630 +CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2الان + +430 +00:38:03,630 --> 00:38:10,910 +واضح تماما انه صعب في نهاية المحاضرة ان نبدأ نحكي + +431 +00:38:10,910 --> 00:38:15,270 +عن ال protein وكيف نعمل ال sequence هيلزمنا ان شاء + +432 +00:38:15,270 --> 00:38:20,970 +الله محاضرة إضافية نحكي فيها كيف نتعرف على ال + +433 +00:38:20,970 --> 00:38:24,830 +sequence لل amino acids وإذا عرفنا ال sequence + +434 +00:38:24,830 --> 00:38:29,250 +شوفنا كيف الآن بنحضرهم بعد هيك أشكال ال protein + +435 +00:38:29,250 --> 00:38:31,530 +المختلفة فان شاء الله إلى لقاء + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..428486a9f8fb99bdcb2377917d9f4e20ac18b1a3 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_postprocess.srt @@ -0,0 +1,1172 @@ +1 +00:00:19,460 --> 00:00:24,620 +بسم الله الرحمن الرحيم بدأنا احنا المرة الماضية في + +2 +00:00:24,620 --> 00:00:28,220 +موضوع الأحماض الكربوكسيلية الـ carboxylic acids + +3 +00:00:28,220 --> 00:00:35,460 +واستعرضنا طبعا تسميتها و الحامضية لها و بدأنا في + +4 +00:00:35,460 --> 00:00:40,840 +موضوع تحضير الـ carboxylic acids قلنا طبعا ان في + +5 +00:00:40,840 --> 00:00:47,130 +عندنا اكثر من طريقة لتحضير الـ carboxylic acidsلو + +6 +00:00:47,130 --> 00:00:53,190 +بدنا احنا نيجي ببساطة نتخيل هالطرق هذه لتحضير ال + +7 +00:00:53,190 --> 00:00:59,430 +carboxylic acids بإمكانكوا تنظروا ل الأقلام اللي + +8 +00:00:59,430 --> 00:01:04,590 +أنا حاملهم هدولة كام قلم؟ تلاتة .. تلاتة .. تلاتة + +9 +00:01:04,590 --> 00:01:05,090 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +10 +00:01:05,090 --> 00:01:06,070 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +11 +00:01:06,070 --> 00:01:06,150 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +12 +00:01:06,150 --> 00:01:12,410 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +13 +00:01:12,410 --> 00:01:19,640 +.. تلاتة .. تيعني أبدأ بتلات ذرات عند اللزوم كحول + +14 +00:01:19,640 --> 00:01:24,020 +أو aldehyde و يطلع عندى حامض من تلات ذرات يعني + +15 +00:01:24,020 --> 00:01:28,520 +أبدأ بتلاته و يطلع عندى تلاته و كان هذه الطريقة + +16 +00:01:28,520 --> 00:01:32,480 +طريقة التساوي هي الطريقة الأولى اللى بدأنا نشرحها + +17 +00:01:32,480 --> 00:01:36,180 +لما اتكلمنا المرة الماضية عن الكحولات و عن ال + +18 +00:01:36,180 --> 00:01:40,550 +aldehydesلما اتكلمنا المرة الماضية عن الكحولات و + +19 +00:01:40,550 --> 00:01:45,950 +عن ال aldehydes هذه الطريقة طريقة ايش تساوي يعني + +20 +00:01:45,950 --> 00:01:52,330 +قداش في عندى عدد كربونات في الكحول او في ال + +21 +00:01:52,330 --> 00:01:56,290 +aldehyde قداش بيكونوا في ال essence يعني لو الكحول + +22 +00:01:56,290 --> 00:02:03,000 +كانوا تلاتة معنى ذلك هيكون اسم تبعه فيه propaneأو + +23 +00:02:03,000 --> 00:02:06,880 +ال الديهايد كانوا تلاتة الاسم تبعه برضه هيكون فيه + +24 +00:02:06,880 --> 00:02:12,760 +بروفان تلاتة الآن ال acid اللي هيطلع برضه هيكون + +25 +00:02:12,760 --> 00:02:19,560 +تلاتة لا هيزيد ولا هينقص خلينا نشوف هذا الكلام + +26 +00:02:19,560 --> 00:02:24,120 +يعني مثلا لو أخدنا CH3 CH2 + +27 +00:02:26,930 --> 00:02:35,710 +هذا ايش؟ كحول من كام كربونة؟ ثلاثة اسمه بروبان + +28 +00:02:35,710 --> 00:02:41,810 +البروبان بتعبر عن العدد all الان لو بدنا اكسدة + +29 +00:02:41,810 --> 00:02:49,430 +بسيطة في ال BCC عند اللزوم حيصير CH3 CH2 C double + +30 +00:02:49,430 --> 00:02:59,080 +bond OH كام ذرة؟تلاتة هذا اللي اتكون شو اسمه? + +31 +00:03:02,720 --> 00:03:08,000 +Ibrobanol إذا هل تغير عدد الذرات؟ لأ لو امشينا في + +32 +00:03:08,000 --> 00:03:12,020 +الأكسدة بالكيامان O4 عند اللزوم أو من البداية + +33 +00:03:12,020 --> 00:03:20,960 +بدينا بالكيامان O4 CH3 CH2 Cضم البند O OH كم ذرة + +34 +00:03:20,960 --> 00:03:25,500 +كربون؟ اه هذا إيش بدو يصير؟ Ibrobanol + +35 +00:03:28,860 --> 00:03:35,200 +وبهيك بيصير واضح معاه أن الأفكار المتعلقة بالأكسد، + +36 +00:03:35,200 --> 00:03:40,920 +أكسدة الكحول، الالدهاي، الاسد، لتغير عدد درات + +37 +00:03:40,920 --> 00:03:46,350 +الكربونواضح الفكرة؟ ولذلك هذه الطريقة .. طريقة إيش + +38 +00:03:46,350 --> 00:03:51,930 +بنسميها؟ طريقة تساوي .. إنه أنا عندي تلت ذرات + +39 +00:03:51,930 --> 00:03:56,030 +carbon .. إنه أنا عندي تلت ذرات carbon .. هدولة + +40 +00:03:56,030 --> 00:03:58,570 +تلت ذرات carbon .. كانوا تلاتة .. ضالوا تلاتة .. + +41 +00:03:58,570 --> 00:04:04,070 +ضالوا تلاتة .. واضح الفكرة؟ طبعا للناس اللي بيحبوا + +42 +00:04:04,070 --> 00:04:07,890 +انزيد شوية في الكلام و في المعلومات .. أنا ممكن + +43 +00:04:07,890 --> 00:04:12,990 +أبدأ من التلاتةبطريقة شوية صغيرة مختلفة يعني + +44 +00:04:12,990 --> 00:04:20,290 +مابداش بالكحول مابداش بالكحول يا ترى لو مثلا بدأت + +45 +00:04:20,290 --> 00:04:27,810 +بهذا المركب لو بدأت بهذا المركب CH3 CH double bond + +46 +00:04:27,810 --> 00:04:35,520 +CH2جبتلكم سؤال كيف من الابروب برضه ابروب ملاحظين + +47 +00:04:35,520 --> 00:04:40,880 +تلاتة ابروبين how can you prepare aerobic acid + +48 +00:04:40,880 --> 00:04:46,340 +starting from aerobin تلاتة تلاتة تلاتة تلاتة اه + +49 +00:04:46,340 --> 00:04:51,720 +هتيجي واحدة تتذكر ان انا هنا بدي اضيف الميه مع ولا + +50 +00:04:51,720 --> 00:04:56,220 +عكس قاعدة Markovnikov طبعا عكس عكس + +51 +00:05:05,320 --> 00:05:10,460 +واضح الفكرة فتلاتة ما زالوا تلاتة ما زالوا تلاتة + +52 +00:05:10,460 --> 00:05:11,320 +ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما + +53 +00:05:11,320 --> 00:05:11,500 +ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما + +54 +00:05:11,500 --> 00:05:13,440 +زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا + +55 +00:05:13,440 --> 00:05:15,280 +تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة + +56 +00:05:15,280 --> 00:05:19,440 +ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما + +57 +00:05:19,440 --> 00:05:28,330 +زالوا تلاتة ما زالوا تبصير acid واضح؟ الأن في هذه + +58 +00:05:28,330 --> 00:05:33,990 +الحالة مافيش عندى تغير في عدد ذرات الكربون فالطرق + +59 +00:05:33,990 --> 00:05:39,310 +المنطلقة من الأكسة ده مافيش فيها تغير بيكون بيوتان + +60 +00:05:39,310 --> 00:05:44,910 +بيوتانوك بيوتانول بيوتانال لكن عدد ذرات الكربون + +61 +00:05:44,910 --> 00:05:48,430 +إيش ماله؟ ثابت حتى لو قلت بيوتين كمان + +62 +00:05:55,150 --> 00:06:03,190 +الان في طرق تانية .. في طرق تانية ممكن أنه نتعامل + +63 +00:06:03,190 --> 00:06:09,570 +معها .. ممكن نشتغل على طريقة اسمها طريقة النقص .. + +64 +00:06:09,570 --> 00:06:16,000 +يعني أبدأ بتلاتةو أكسر من التلاتة هدولة و أجد + +65 +00:06:16,000 --> 00:06:21,820 +أبطلع بإيش نفترض ب 2 و ب 1 أكسر التلاتة أو أبدأ ب + +66 +00:06:21,820 --> 00:06:28,140 +4 و أكسر الأربعة ل 2 و 2 أو ل 3 و 1 هذه طريقة إيش + +67 +00:06:28,140 --> 00:06:33,400 +نقص أنه أنا يكون عند السلسلة الكلية السلسلة الكلية + +68 +00:06:33,400 --> 00:06:39,040 +أربع كربونات أطول منها 3 أو 2 أو 1 يعني أقل من إيش + +69 +00:06:39,560 --> 00:06:44,440 +أقل من الأربعة صارت هذه الطريقة طريقة ايش نقص طبعا + +70 +00:06:44,440 --> 00:06:48,660 +ايش بيظل عندنا انه ممكن تكون طريقة زيادة يعني + +71 +00:06:48,660 --> 00:06:53,920 +افترضوا انه سلسلة عندى أربعة وطلبت + +72 +00:06:53,920 --> 00:06:56,600 +منكوا تحضروا لي حمض بخمس كربونات + +73 +00:07:01,280 --> 00:07:08,760 +أنا قلت لكم ببساطة مبتدئا من البيوتانول البيوتانول + +74 +00:07:08,760 --> 00:07:14,680 +كام كربونا؟ أربعة حضرولي بنتانوك أسد الآن إذا + +75 +00:07:14,680 --> 00:07:19,720 +واحدة مش منتبهة تقول all oic acid تروح تعمل أكسدة + +76 +00:07:19,720 --> 00:07:26,520 +أه بس البيوتانول بيصير بيوتانوك أسدبزيدش Carbona + +77 +00:07:26,520 --> 00:07:30,960 +الان لو كنت بداجي اسألكم والله من ال Butanol + +78 +00:07:30,960 --> 00:07:37,890 +حضرولي Pentanoic acid زدتوا Carbonaإذا أنا بحاجة + +79 +00:07:37,890 --> 00:07:43,030 +إلى طريقة وبناء على ذلك للي بدوا يفهم طرق تحضير + +80 +00:07:43,030 --> 00:07:47,130 +الأحماض بشكل عام بنقول أن طرق تحضير الأحماض بدكوا + +81 +00:07:47,130 --> 00:07:51,870 +تنتبهوا تماما ممكن تكون طريقة التساوي وهذه موجودة + +82 +00:07:51,870 --> 00:07:55,130 +في شغل الأكسد أو الكلام اللي شرحنا الآن ممكن تكون + +83 +00:07:55,130 --> 00:08:01,250 +طريقة تكسير أو نقص وممكن تكون طريقة إيش؟ زيادة + +84 +00:08:01,250 --> 00:08:09,000 +واضحة الفكرة؟ الآن خلينا نيجيلاطرق التكثير خلّينا + +85 +00:08:09,000 --> 00:08:15,340 +نيجي لطرق التكثير بشكل عام نسبة من طرق التكثير مرت + +86 +00:08:15,340 --> 00:08:19,980 +معنا بطريقة أو باخرى ليش؟ لأنه احنا أخدنا ال + +87 +00:08:19,980 --> 00:08:27,460 +ozoneolysis ال ozoneolysis عادة بيكسر المركب لإيش؟ + +88 +00:08:28,390 --> 00:08:33,650 +لأldehyde او كيتون ايه كويس الال بعد ما + +89 +00:08:33,650 --> 00:08:38,370 +الأوزونوليس يعني هيك انا بده اقول الكين والالكاين + +90 +00:08:38,370 --> 00:08:46,370 +زي الالكين بالمناسبة الكين ممكن يعطيني ايش كيتون + +91 +00:08:49,540 --> 00:08:53,540 +الديهايد هذا الكلام اتعلمناه ولا لأ ان الالكين + +92 +00:08:53,540 --> 00:08:57,600 +بيصير كيتون او الديهايد الان الكيتون اتعلمناه انه + +93 +00:08:57,600 --> 00:09:05,060 +لا يتأكسد اكسدة اضافية لكن ال الديهايد بتأكسد ولا + +94 +00:09:05,060 --> 00:09:09,860 +لأ ال الديهايد بتأكسد اكسدة اضافية بيصير ايش acid + +95 +00:09:09,860 --> 00:09:14,440 +الان بكل الأحوال هذا ال الديهايد هيكون اصغر من ال + +96 +00:09:14,440 --> 00:09:20,010 +الكين او من ال الكاين ولا لأبالتأكيد هنا هيلزمني + +97 +00:09:20,010 --> 00:09:25,750 +كام عملية يتموا ورا بعض عمليتين العملية الأولى ال + +98 +00:09:25,750 --> 00:09:31,630 +ozoneolysis و العملية التانية ال oxidation خلّيني + +99 +00:09:31,630 --> 00:09:35,990 +أعبّر عنها ب O بين جثين Oxidation عملية أكسدة عادة + +100 +00:09:35,990 --> 00:09:41,430 +بيستعملونها H2O2 الهيدروجين بيروكسايد هذه كمان + +101 +00:09:41,430 --> 00:09:49,310 +خلّوها H2O2أذن اوزونوليسيز followed by H2O2 يمكن + +102 +00:09:49,310 --> 00:09:55,050 +أن يؤدي إلى أحماض لكن أكيد هتكون أصغر من إيش؟ أصغر + +103 +00:09:55,050 --> 00:10:02,090 +من الألكين اللي أنا ابتدأت فيه الآن خلينا ناخد + +104 +00:10:02,090 --> 00:10:06,910 +مثال حقيقي ناخد مثال حقيقي لو يا ترى أخدنا هذا + +105 +00:10:06,910 --> 00:10:16,980 +الألكينسواء قلنا عنه CES و لا TRANS CH3 CH3H + +106 +00:10:16,980 --> 00:10:26,200 +CH3H و قلنا اكمل نمر واحد O3 Ozonolysis و نمر + +107 +00:10:26,200 --> 00:10:31,060 +اتنين H2O2 H2O2 Hydrogen Peroxide هو العامل + +108 +00:10:31,060 --> 00:10:39,210 +المؤكسد الان بدنا لما ننفذ نفهم الشغل الاولىكسر + +109 +00:10:39,210 --> 00:10:47,350 +يعني C double bond O H و CH3 زائد C double bond OH + +110 +00:10:47,350 --> 00:10:55,750 +و CH3 هذا ال ozonolases طب و ال acid هذا إيش؟ + +111 +00:10:55,750 --> 00:11:00,830 +الديهايد الآن هذا ال الديهايد بال H2O2 اللي ضفناها + +112 +00:11:00,830 --> 00:11:08,760 +إيش حيصير؟ C double bond O OHCH3 وجدت حصلنا على + +113 +00:11:08,760 --> 00:11:14,980 +الاسيتك أسد الاسيتك أسد كده؟ كربون 2 يعني كأنه انا + +114 +00:11:14,980 --> 00:11:18,820 +بال اوزونوليسيز اتيت كصرت الأربعة هدولة اتنين و + +115 +00:11:18,820 --> 00:11:23,400 +اتنين طلعوا عندي ألديهيد الآن كملت أكسدت الألديهيد + +116 +00:11:23,400 --> 00:11:29,060 +صار اسيتك أسد فمن الأربعة حصلت على حامض من كام + +117 +00:11:29,060 --> 00:11:37,890 +كربون؟ تنتين واضحة الفكرة؟ طبعا الآناللي ممكن + +118 +00:11:37,890 --> 00:11:44,390 +يفكروا انه نتعمق معهم بمثل هذه الفكرة ممكن نيجي + +119 +00:11:44,390 --> 00:11:49,910 +نسألهم، مانقول هم مش مبتدئان من ال 2 بيوتين، لو + +120 +00:11:49,910 --> 00:11:55,930 +بدأت من ال one بيوتين، هيطلع عند أحمد واحد و تلاتة + +121 +00:11:56,580 --> 00:12:00,520 +لأن هذه هتكسر كربونا و هدول يكونوا تلاتة لكن لو + +122 +00:12:00,520 --> 00:12:07,080 +انا اجيت و قولتلكم والله من مركب زي هذا CH3 CH2 CH + +123 +00:12:07,080 --> 00:12:15,560 +سواء حطيت هنا CL او OH اتخيلوا ان انا اجي اقولكم + +124 +00:12:15,560 --> 00:12:23,720 +من two chlorobutane حضروا لي acidic acid واضح او + +125 +00:12:23,720 --> 00:12:28,880 +من two butanolبتكون تعملوا elimination الان ال CL + +126 +00:12:28,880 --> 00:12:32,320 +و ال H بيروحوا و بيعطينا ال more substituted + +127 +00:12:32,320 --> 00:12:37,280 +باستعمال ايش طلعت + +128 +00:12:37,280 --> 00:12:44,240 +انا ال alkyd و بعدين كسرت ال alkyd هذه الطرق و مع + +129 +00:12:44,240 --> 00:12:47,020 +ال triple bond نفس الاشي زي ال double bond هذه + +130 +00:12:47,020 --> 00:12:52,180 +الطرق تعتبر طرق ايشانقاس يعني كان عندى اربع + +131 +00:12:52,180 --> 00:12:56,720 +كربونات اعملت حامض من كربونتين اعملت حامض من تلات + +132 +00:12:56,720 --> 00:13:02,840 +كربونات حسب موقع ايش ال bubble bond بس بشرط انه + +133 +00:13:02,840 --> 00:13:06,660 +يكون من نتائج ال ozonosis انه بتكون aldehyde ليش؟ + +134 +00:13:06,660 --> 00:13:10,820 +لأن اللى بيكمل وبيتأكسد ال aldehyde الكيتون بقولنا + +135 +00:13:10,820 --> 00:13:16,140 +فيه إله أكسدة إضافية؟ لأ واضحة الفكرة؟ اللى بيكمل + +136 +00:13:16,140 --> 00:13:21,210 +وبيتأكسد هو مين؟الالديهايد وهذا الكلام أخدناه في + +137 +00:13:21,210 --> 00:13:24,090 +أكسدة الالديهايد والكيتونز قلنا الالديهايد بتصير + +138 +00:13:24,090 --> 00:13:30,430 +أحمار الكيتونز لاتت أكسد أكسدة إضافية واضحة الفكرة + +139 +00:13:30,430 --> 00:13:37,150 +طيب + +140 +00:13:37,150 --> 00:13:45,300 +إذا عرفنا طريقة المساواة وطريقةالنقص ايش ضال + +141 +00:13:45,300 --> 00:13:51,140 +عندنا؟ طريقة الزيادة بمعنى لو انا اجيت وقلتلكم لو + +142 +00:13:51,140 --> 00:13:56,240 +سمحتوا من تلت كربونات بدي احضر حامض من اربع + +143 +00:13:56,240 --> 00:14:03,000 +كربونات عادة الزيادة اللي احنا بنعملها زيادة سهلة + +144 +00:14:03,480 --> 00:14:07,900 +ليه؟ كربونة واحدة هي اللي بتتم بسهولة يعني التلاتة + +145 +00:14:07,900 --> 00:14:13,160 +يصيروا أربعة، الأربعة يصيروا خمسة، الخمسة يصيروا + +146 +00:14:13,160 --> 00:14:17,680 +ستة كيف هذا الكلام .. كيف هذا الكلام بتم؟ هذا + +147 +00:14:17,680 --> 00:14:26,500 +الكلام عادة بتتممنطلقين فيه من ال الكل هلاي من ال + +148 +00:14:26,500 --> 00:14:33,040 +one chloro compound واضح يعني بدي مركب سلسلة يكون + +149 +00:14:33,040 --> 00:14:39,300 +على موقع واحد فيها إيش إكلور بدي سلسلة على موقع + +150 +00:14:39,300 --> 00:14:47,340 +واحد فيها إكلور يعني مثلا زي ما اقول CH3 CH2 CH2 + +151 +00:14:47,340 --> 00:14:56,390 +CLالان الكلور هانا وين؟ على موقع واحد هذا الكلور + +152 +00:14:56,390 --> 00:15:00,050 +مكانه بدي ازيد كربونا اللي هي بده تكون حاملة + +153 +00:15:00,050 --> 00:15:06,320 +مجموعة الاسم عدد الكربونات الكل يعني قداشتلاتة بدي + +154 +00:15:06,320 --> 00:15:11,720 +أحضر من هذا butanoic acid يعني كام كربونا؟ أربعة + +155 +00:15:11,720 --> 00:15:16,640 +في عندى طريقتين ممكنين في عندى طريقتين ممكنين + +156 +00:15:16,640 --> 00:15:22,920 +الطريقة الأولى أنه أنا هذا أجي أفعله مع CN minus + +157 +00:15:22,920 --> 00:15:28,140 +والطريقة التانية أنه أنا هذا أفعله مع green yard + +158 +00:15:28,140 --> 00:15:34,560 +reagentمار عليكم المغنيسيا من اللي بيعطي RMGX طيب + +159 +00:15:34,560 --> 00:15:38,720 +لو فعلنا مع ال cyanide شو بده يصير هذا؟ بده يصير + +160 +00:15:38,720 --> 00:15:49,220 +CH3 CH2 CH2 و هنا بده تيجي مجموعة ال CN لاحظوا هنا + +161 +00:15:49,220 --> 00:15:54,120 +بينت الكربون الرابعة ولا لأ هيصاروا كام كربونة؟ + +162 +00:15:55,060 --> 00:16:02,160 +أربعة بدل تلاتة الان ال cyanide بشكل عام لو عملتله + +163 +00:16:02,160 --> 00:16:11,340 +hydrolysis يا إما ب H3O plus بيمشي الحال أو ب N-A + +164 +00:16:11,340 --> 00:16:15,840 +-O-H و بعدين H plus يعني يا إما بهذا ال reagent يا + +165 +00:16:15,840 --> 00:16:20,100 +إما بهذا ال reagent بأي واحد منهم بيمشي بصير أسلوب + +166 +00:16:20,870 --> 00:16:24,310 +يعني ال cyanide بيعملها hydrolysis ال acid و بعدها + +167 +00:16:24,310 --> 00:16:34,310 +شو هيصير CH3 CH2 CH2 و هذه ال C هي اللي ضالت هتصير + +168 +00:16:34,310 --> 00:16:41,610 +C double bond O OH اذا انا ال chlorine حولتها ل CN + +169 +00:16:41,610 --> 00:16:48,530 +و ال CN ع طول بتصير COOHهذه طريقة معروفة وجيدة + +170 +00:16:48,530 --> 00:16:53,750 +لعمل هذا المُركّب طيب الطريقة التانية .. بدأ أزيد + +171 +00:16:53,750 --> 00:16:58,310 +كربونا لسه .. أنا لو فعلت مع المغنيسيوم .. هذا إيش + +172 +00:16:58,310 --> 00:17:04,750 +هيعطيني؟ الـ Grignard Reagent .. كلكم اتذكرينه؟CH3 + +173 +00:17:04,750 --> 00:17:13,470 +CH2 CH2 وقلنا هذه اهم اشي فيها MgCl هاي Green Yard + +174 +00:17:13,470 --> 00:17:18,630 +Ray Agent إبروبيل مغنيسيا ميكلورايد صح؟ الآن هذا + +175 +00:17:18,630 --> 00:17:25,330 +ال Green Yard Ray Agent بفعله مع نمرة واحد CO2 + +176 +00:17:25,330 --> 00:17:28,250 +لاحظوا هاي ال C double bond O double bond O ثاني + +177 +00:17:28,250 --> 00:17:29,030 +أكسيد كربون + +178 +00:17:31,920 --> 00:17:38,840 +واضح؟ ونمر اتنين خليني ال CO2 ارسمه بالاحمر بفعله + +179 +00:17:38,840 --> 00:17:43,220 +مع ال CO2 يعني C double bond O double bond O ونمر + +180 +00:17:43,220 --> 00:17:49,000 +اتنين مع H بلس بيعطيني الحامض اللي هتقولولي من وين + +181 +00:17:49,000 --> 00:17:54,710 +اجت الكربونة؟هي من الـ CO2 مش الـ C حاملة انتن + +182 +00:17:54,710 --> 00:17:59,370 +أكسجين وهنا إيش زاد عندي؟ C double bond O OH + +183 +00:17:59,370 --> 00:18:06,590 +ببساطة هذا نيوكليوفايل بيهاجم هنا بيهاجم على + +184 +00:18:06,590 --> 00:18:09,990 +الكربون الموجبة مش الكربون بتاع تاني أكسيد الكربون + +185 +00:18:09,990 --> 00:18:15,050 +الموجبة لأنه جنبها مجموعتين سالبات لما يهاجم هذا + +186 +00:18:15,050 --> 00:18:20,250 +بتصير O minus ومن ال H plus بتاخد H إيش بتصير؟ OH + +187 +00:18:21,350 --> 00:18:27,040 +إذا هنا مصدر الكربونة الجديدة إيش بيكون؟الـ CO2 + +188 +00:18:27,040 --> 00:18:31,720 +إذا أنا لما بدي أعمل الزيادة بدي مصدر للكربونة + +189 +00:18:31,720 --> 00:18:36,540 +الجديدة مصدر الكربونة الجديدة يا بدي يكون ال CN و + +190 +00:18:36,540 --> 00:18:39,340 +بعدين أعمل ال hydrolysis يا بعمل ال green yard + +191 +00:18:39,340 --> 00:18:43,280 +reagent و الكربونة الجديدة بجيبها من وين؟ من ال + +192 +00:18:43,280 --> 00:18:50,340 +CO2 واضح الفكرة؟ الآن مرة تانية مش ضروري تكون نقطة + +193 +00:18:50,340 --> 00:18:57,860 +البداية اللي عندى هي هذا المركب الكلوريممكن تكون + +194 +00:18:57,860 --> 00:19:02,180 +نقطة البداية الكحول الان الكحول بقدر اخليك low + +195 +00:19:02,180 --> 00:19:07,140 +right في الخطوة الأولى بالإبدال كحول مع O H minus + +196 +00:19:07,140 --> 00:19:17,960 +بيعمل إبدال ممكن تكون نقطة البداية الالكين هذه + +197 +00:19:17,960 --> 00:19:19,900 +الالكين بتلت كربونات + +198 +00:19:29,710 --> 00:19:35,570 +واضحة الفكرة فهذه + +199 +00:19:35,570 --> 00:19:41,830 +طرق الزيادة اللى عادة بنستعملها من خلال ال CN أو + +200 +00:19:41,830 --> 00:19:42,630 +ال CO2 + +201 +00:19:52,800 --> 00:19:54,940 +هنا على السلسلة هذه + +202 +00:20:03,960 --> 00:20:08,640 +لأ لأ لأ لأ لأ ال chlorineation ال chlorineation + +203 +00:20:08,640 --> 00:20:13,260 +على السلسلة أخدناها ب CL2 في وجود ضوء أو حرارة أو + +204 +00:20:13,260 --> 00:20:16,560 +من خلال الإضافة ع ال double bond يعني ال chlorine + +205 +00:20:16,560 --> 00:20:20,600 +مع ال FeCl3 هذا على ال aromatic compounds هذا على + +206 +00:20:20,600 --> 00:20:28,580 +ال aromatic compounds تمام بضل في عندى ال benzoic + +207 +00:20:28,580 --> 00:20:35,710 +acidعارفين البنزويك أسد؟ كيف ممكن نحضر البنزويك + +208 +00:20:35,710 --> 00:20:40,970 +أسد؟ و مرات ممكن نسأل كيف ممكن تحضروا البنزويك أسد + +209 +00:20:40,970 --> 00:20:44,370 +من البنزين هاي البنزويك أسد + +210 +00:20:53,780 --> 00:20:59,240 +سهلة ان لو انا عندى cyanobenzene بصير benzoic acid + +211 +00:20:59,240 --> 00:21:05,480 +هذه الطريقة خلينى نقول ايش مالها سهلة CN اذا عندى + +212 +00:21:05,480 --> 00:21:11,740 +cyanobenzene في وجود H plus او NaOH نمرة واحد و + +213 +00:21:11,740 --> 00:21:15,320 +نمرة اتنين H plus زى ما حكينا قبل شوية ال + +214 +00:21:15,320 --> 00:21:21,420 +cyanobenzene بصير acid فيها مشكلةطبعا هيصير السؤال + +215 +00:21:21,420 --> 00:21:26,080 +كيف يتحضر السيانو بنزين .. سيانو بنزين في شبطر 11 + +216 +00:21:26,080 --> 00:21:31,510 +بنتعلم تحضيرهبيجيش مباشر بقتش CN لأ اللي طريقة + +217 +00:21:31,510 --> 00:21:37,250 +التفافية ال CN و البنزين بيجيش بشكل مباشر بتحضرش + +218 +00:21:37,250 --> 00:21:41,630 +بشكل مباشر انه بنزين ماقتش CN ليش؟ لإن ال CN minus + +219 +00:21:41,630 --> 00:21:45,590 +و البنزين حاملة إلكترونات بيهاجمش minus على minus + +220 +00:21:45,590 --> 00:21:51,270 +طمام الطريقة التانية انه لو احنا أخدنا .. نخلص من + +221 +00:21:51,270 --> 00:21:56,770 +هذه الطريقة و نمحاها لو احنا أخدنا أي بنزين بيحمل + +222 +00:21:56,770 --> 00:22:02,490 +ال kilogramإيش في بنزين بيحمل الكل جروب؟ الطلوين + +223 +00:22:02,490 --> 00:22:05,670 +صح؟ + +224 +00:22:05,670 --> 00:22:13,890 +CH3 إيش ممكن كمان؟ ال F البنزين CH2 CH3 إيش كمان + +225 +00:22:13,890 --> 00:22:26,110 +ممكن؟ القيومين CH CH3 CH3 كل هدولة بيحملوهالكلي + +226 +00:22:26,110 --> 00:22:29,950 +جروبز ممكن حد يفكر كمان بال تيرتشار بيوت البنزين + +227 +00:22:29,950 --> 00:22:36,610 +ممكن حد يفكر بال تيرتشار بيوت البنزين الآن بنقول + +228 +00:22:36,610 --> 00:22:43,230 +القاتل لو استعملنا عام المؤكسد بشكل عام ال KMnO4 + +229 +00:22:43,230 --> 00:22:48,710 +برمجانات البوتاسيوم مع أي ألكل بنزين مع أي ألكل + +230 +00:22:48,710 --> 00:22:54,480 +بنزين بس بشرطالكربون المتصل على البنزين مباشرة + +231 +00:22:54,480 --> 00:22:59,040 +تحتوي على ذرة هيدروجين على اقل تقدير الان هذه + +232 +00:22:59,040 --> 00:23:03,540 +الكربون .. كم هيدروجين بتحمل؟ تلاتة .. هذه .. هذه + +233 +00:23:03,540 --> 00:23:08,000 +.. هذه .. ولا واحدة .. اذا هدولة التلاتة بيمشي + +234 +00:23:08,000 --> 00:23:14,540 +حالهمأى واحدة من هدول بالأكسدة بكامان of four + +235 +00:23:14,540 --> 00:23:18,820 +بتعطينا بنزويك أسل الان انتبهوا معي لنقطة كتير + +236 +00:23:18,820 --> 00:23:26,100 +مهمة انه بغض النظر عن طول السلسلة هنطلع بس بنزويك + +237 +00:23:26,100 --> 00:23:30,960 +أسل يعني لو كان هنا مثل او اثل او بروبل او بيوتل + +238 +00:23:30,960 --> 00:23:34,760 +كربونة او تنتين او تلاتة او اربعة او خمسة او عشرة + +239 +00:23:35,740 --> 00:23:40,220 +بس هطلعوا إيش ال benzoic acid مرات كتير لما بنيجي + +240 +00:23:40,220 --> 00:23:44,620 +بنسأل الطلاب بنقولهم الله أعملونا أكسدة بنزين حامل + +241 +00:23:44,620 --> 00:23:47,340 +تلت كربونات بيروحوا بيخلوا الكربونتين و بيعملوا + +242 +00:23:47,340 --> 00:23:51,640 +الأكسدة على التالتة افهمتوا الغلطة اللي بحكيها ولا + +243 +00:23:51,640 --> 00:24:00,600 +أوضحها أكتر لما أجي أرسملهم مركب زي هذا CH2 CH2 + +244 +00:24:00,600 --> 00:24:07,120 +CH3 و أقولهم بالكمان O4الآن الغلطة اللي بيعملوه + +245 +00:24:07,120 --> 00:24:11,900 +بيعملوا ال acid هانا و بيخلوها دولة الجواب الصحيح + +246 +00:24:11,900 --> 00:24:15,620 +انه سواء كانوا دول واحدة او تنتين او تلاتة او + +247 +00:24:15,620 --> 00:24:20,720 +اربعة او عشرة بس بتكون عند هانا مجموعة ال acid + +248 +00:24:20,720 --> 00:24:27,240 +COOHبمعنى أنا بشرحش ميكانيزم متفق انه بدنيش ادخل + +249 +00:24:27,240 --> 00:24:31,180 +كتير بتفاصيل يعني خليني في النتائج بمعنى لو انا + +250 +00:24:31,180 --> 00:24:38,120 +اجيت سألتكم و قولتلكم انه تفاعل الطلوين والاكيومين + +251 +00:24:38,120 --> 00:24:42,120 +اه انتبهوا معاك الطلوين والاكيومين مع الكيامة ال + +252 +00:24:42,120 --> 00:24:47,990 +O4 both produces benzoic acid صحبينما لو كان + +253 +00:24:47,990 --> 00:24:52,390 +السؤال تفاعل الطلوين والـ tertiary بيوت البنزين + +254 +00:24:52,390 --> 00:24:56,490 +هذا لأ لأن هذا مافيش عليه هيدروجينة على الكاربون + +255 +00:24:56,490 --> 00:25:03,190 +المتصلة مباشرة بالبنزينة واضحة الفكرة؟ فعشان اتم + +256 +00:25:03,190 --> 00:25:06,810 +هذا النوع من الأكسدة هذا بنسميه oxidation of the + +257 +00:25:06,810 --> 00:25:12,290 +aliphatic sided chain مش هذه سلسلة معلقة على + +258 +00:25:12,290 --> 00:25:18,730 +البنزينولذلك هذا التفاعل اسمه أكسدت السلسلة + +259 +00:25:18,730 --> 00:25:24,110 +المعلقة على البنزين، مهما كبرت ومهما عظمت، ايش + +260 +00:25:24,110 --> 00:25:31,750 +بتعطيني؟ acid، بس، بغض النظر عن طولهاواضح؟ + +261 +00:25:31,750 --> 00:25:36,530 +Oxidation of the aliphatic sided chain attached to + +262 +00:25:36,530 --> 00:25:41,330 +benzene واضحة الفكرة؟ هذه طريقة لتحضير ال benzoic + +263 +00:25:41,330 --> 00:25:46,570 +acid طبعا احنا جيبنا طريقة تانية باستعمال إيش؟ ال + +264 +00:25:46,570 --> 00:25:54,040 +CN إذا هي كام طريقة صيرنا ذاكرين لكم؟طريقة السيانة + +265 +00:25:54,040 --> 00:26:00,060 +جيبناها ولا لأ؟ طيب خلينا نمحا كل هالكلام ونقول لو + +266 +00:26:00,060 --> 00:26:05,320 +إجاكم السؤال في الامتحان ابتلى الطرق حضرولي ال + +267 +00:26:05,320 --> 00:26:08,440 +benzoic acid هتقولوا ال aliphatic side chain هذه + +268 +00:26:08,440 --> 00:26:12,620 +كلها طريقة حتى لو من البنزين بقول بنزين طلوين + +269 +00:26:13,730 --> 00:26:17,930 +بنزويك أسد واضح؟ لما أقولكوا بدي بنزويك أسد من + +270 +00:26:17,930 --> 00:26:23,090 +البنزين، شو هانمشي؟ بنزين طول وين؟ بنزويك أسد + +271 +00:26:23,090 --> 00:26:28,750 +صعبة؟ من السيان و بنزين؟ ابنعملها طب لو قولنا بدنا + +272 +00:26:28,750 --> 00:26:33,090 +طريقة تالتة من البنزين + +273 +00:26:39,040 --> 00:26:48,920 +طريقة تالتة بد بنزويك أسد من البنزين واضحة + +274 +00:26:48,920 --> 00:26:58,260 +الفكرة هي بنزين بد يصير بنزويك أسد حسب ما اتعلمنا + +275 +00:26:58,260 --> 00:27:03,900 +لاحظوا ما بين البنزين + +276 +00:27:03,900 --> 00:27:09,650 +و بنزويك أسد زيادة كربونةولذلك .. و لذلك احنا قلنا + +277 +00:27:09,650 --> 00:27:17,870 +بطريقة ما هذه لما صارت سيانو اقدرنا + +278 +00:27:17,870 --> 00:27:21,330 +نحولها ل acid بس مااخدناش الطريقة اللي بتخليها + +279 +00:27:21,330 --> 00:27:24,970 +سيانو لحتى الان الان ما طريقة الزيادة التانية + +280 +00:27:24,970 --> 00:27:34,830 +اللتي تعلمناها اغرينيا اذا هذا يصير اكلوروبنزين + +281 +00:27:34,830 --> 00:27:40,590 +هذه تعلمناها ولا لأالكلورو بنزين لو فعلناه معي + +282 +00:27:40,590 --> 00:27:47,050 +green yard مع Mg شو بيصير؟ + +283 +00:27:47,050 --> 00:27:56,270 +MgCl ال MgCl بإيش بيزيد كربونا؟ بتاني أكسيد + +284 +00:27:56,270 --> 00:28:03,890 +الكربون وحمد إذا بنزين كلورو بنزين طبعا كلكوا + +285 +00:28:03,890 --> 00:28:06,470 +عارفين ال reaction اللي هو Cl2 + +286 +00:28:13,200 --> 00:28:26,560 +بنزين بيصير بنزويك أسد بنزين بيصير + +287 +00:28:26,560 --> 00:28:30,080 +طلوين + +288 +00:28:30,080 --> 00:28:36,360 +بنزويك أسدو بعدين كيامان افور بالكيامان افور اذا + +289 +00:28:36,360 --> 00:28:40,460 +هى البنزويك اسد بتلات طرق اللى بده يحفظهم اول شى + +290 +00:28:40,460 --> 00:28:47,160 +يقول بنزين طلوين بنزويك اسد بنزين سيانو بنزين + +291 +00:28:47,160 --> 00:28:52,720 +بنزويك اسد بنزين كلورو بنزين بنزين جرينيارد بنزويك + +292 +00:28:52,720 --> 00:28:57,180 +اسد كل هذه طرق لتحضير البنزويك اسد ولا لأ كان + +293 +00:28:57,180 --> 00:29:02,480 +طريقة تلاتة واضح وبهيك بننهي اليوم + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..5a45e0f04000a7e67d6378c275e089dfdfedf37f --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.srt @@ -0,0 +1,1184 @@ +1 +00:00:19,460 --> 00:00:24,620 +بسم الله الرحمن الرحيم بدأنا احنا المرة الماضية في + +2 +00:00:24,620 --> 00:00:28,220 +موضوع الأحماض الكربوكسيلية الـ carboxylic acids + +3 +00:00:28,220 --> 00:00:35,460 +واستعرضنا طبعا تسميتها و الحامضية لها و بدأنا في + +4 +00:00:35,460 --> 00:00:40,840 +موضوع تحضير الـ carboxylic acids قلنا طبعا ان في + +5 +00:00:40,840 --> 00:00:47,130 +عندنا اكثر من طريقة لتحضير الـ carboxylic acidsلو + +6 +00:00:47,130 --> 00:00:53,190 +بدنا احنا نيجي ببساطة نتخيل هالطرق هذه لتحضير ال + +7 +00:00:53,190 --> 00:00:59,430 +carboxylic acids بإمكانكوا تنظروا ل الأقلام اللي + +8 +00:00:59,430 --> 00:01:04,590 +أنا حاملهم هدولة كام قلم؟ تلاتة .. تلاتة .. تلاتة + +9 +00:01:04,590 --> 00:01:05,090 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +10 +00:01:05,090 --> 00:01:06,070 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +11 +00:01:06,070 --> 00:01:06,150 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. + +12 +00:01:06,150 --> 00:01:06,150 +تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +13 +00:01:06,150 --> 00:01:12,410 +.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة + +14 +00:01:12,410 --> 00:01:19,640 +.. تلاتة .. تيعني أبدأ بتلات ذرات عند اللزوم كحول + +15 +00:01:19,640 --> 00:01:24,020 +أو aldehyde و يطلع عندى حامض من تلات ذرات يعني + +16 +00:01:24,020 --> 00:01:28,520 +أبدأ بتلاته و يطلع عندى تلاته و كان هذه الطريقة + +17 +00:01:28,520 --> 00:01:32,480 +طريقة التساوي هي الطريقة الأولى اللى بدأنا نشرحها + +18 +00:01:32,480 --> 00:01:36,180 +لما اتكلمنا المرة الماضية عن الكحولات و عن ال + +19 +00:01:36,180 --> 00:01:40,550 +aldehydesلما اتكلمنا المرة الماضية عن الكحولات و + +20 +00:01:40,550 --> 00:01:45,950 +عن ال aldehydes هذه الطريقة طريقة ايش تساوي يعني + +21 +00:01:45,950 --> 00:01:52,330 +قداش في عندى عدد كربونات في الكحول او في ال + +22 +00:01:52,330 --> 00:01:56,290 +aldehyde قداش بيكونوا في ال essence يعني لو الكحول + +23 +00:01:56,290 --> 00:02:03,000 +كانوا تلاتة معنى ذلك هيكون اسم تبعه فيه propaneأو + +24 +00:02:03,000 --> 00:02:06,880 +ال الديهايد كانوا تلاتة الاسم تبعه برضه هيكون فيه + +25 +00:02:06,880 --> 00:02:12,760 +بروفان تلاتة الآن ال acid اللي هيطلع برضه هيكون + +26 +00:02:12,760 --> 00:02:19,560 +تلاتة لا هيزيد ولا هينقص خلينا نشوف هذا الكلام + +27 +00:02:19,560 --> 00:02:24,120 +يعني مثلا لو أخدنا CH3 CH2 + +28 +00:02:26,930 --> 00:02:35,710 +هذا ايش؟ كحول من كام كربونة؟ ثلاثة اسمه بروبان + +29 +00:02:35,710 --> 00:02:41,810 +البروبان بتعبر عن العدد all الان لو بدنا اكسدة + +30 +00:02:41,810 --> 00:02:49,430 +بسيطة في ال BCC عند اللزوم حيصير CH3 CH2 C double + +31 +00:02:49,430 --> 00:02:59,080 +bond OH كام ذرة؟تلاتة هذا اللي اتكون شو اسمه? + +32 +00:03:02,720 --> 00:03:08,000 +Ibrobanol إذا هل تغير عدد الذرات؟ لأ لو امشينا في + +33 +00:03:08,000 --> 00:03:12,020 +الأكسدة بالكيامان O4 عند اللزوم أو من البداية + +34 +00:03:12,020 --> 00:03:20,960 +بدينا بالكيامان O4 CH3 CH2 Cضم البند O OH كم ذرة + +35 +00:03:20,960 --> 00:03:25,500 +كربون؟ اه هذا إيش بدو يصير؟ Ibrobanol + +36 +00:03:28,860 --> 00:03:35,200 +وبهيك بيصير واضح معاه أن الأفكار المتعلقة بالأكسد، + +37 +00:03:35,200 --> 00:03:40,920 +أكسدة الكحول، الالدهاي، الاسد، لتغير عدد درات + +38 +00:03:40,920 --> 00:03:46,350 +الكربونواضح الفكرة؟ ولذلك هذه الطريقة .. طريقة إيش + +39 +00:03:46,350 --> 00:03:51,930 +بنسميها؟ طريقة تساوي .. إنه أنا عندي تلت ذرات + +40 +00:03:51,930 --> 00:03:56,030 +carbon .. إنه أنا عندي تلت ذرات carbon .. هدولة + +41 +00:03:56,030 --> 00:03:58,570 +تلت ذرات carbon .. كانوا تلاتة .. ضالوا تلاتة .. + +42 +00:03:58,570 --> 00:04:04,070 +ضالوا تلاتة .. واضح الفكرة؟ طبعا للناس اللي بيحبوا + +43 +00:04:04,070 --> 00:04:07,890 +انزيد شوية في الكلام و في المعلومات .. أنا ممكن + +44 +00:04:07,890 --> 00:04:12,990 +أبدأ من التلاتةبطريقة شوية صغيرة مختلفة يعني + +45 +00:04:12,990 --> 00:04:20,290 +مابداش بالكحول مابداش بالكحول يا ترى لو مثلا بدأت + +46 +00:04:20,290 --> 00:04:27,810 +بهذا المركب لو بدأت بهذا المركب CH3 CH double bond + +47 +00:04:27,810 --> 00:04:35,520 +CH2جبتلكم سؤال كيف من الابروب برضه ابروب ملاحظين + +48 +00:04:35,520 --> 00:04:40,880 +تلاتة ابروبين how can you prepare aerobic acid + +49 +00:04:40,880 --> 00:04:46,340 +starting from aerobin تلاتة تلاتة تلاتة تلاتة اه + +50 +00:04:46,340 --> 00:04:51,720 +هتيجي واحدة تتذكر ان انا هنا بدي اضيف الميه مع ولا + +51 +00:04:51,720 --> 00:04:56,220 +عكس قاعدة Markovnikov طبعا عكس عكس + +52 +00:05:05,320 --> 00:05:10,460 +واضح الفكرة فتلاتة ما زالوا تلاتة ما زالوا تلاتة + +53 +00:05:10,460 --> 00:05:11,320 +ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما + +54 +00:05:11,320 --> 00:05:11,320 +زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا + +55 +00:05:11,320 --> 00:05:11,320 +تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة + +56 +00:05:11,320 --> 00:05:11,500 +ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما + +57 +00:05:11,500 --> 00:05:13,440 +زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا + +58 +00:05:13,440 --> 00:05:15,280 +تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة + +59 +00:05:15,280 --> 00:05:19,440 +ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما + +60 +00:05:19,440 --> 00:05:28,330 +زالوا تلاتة ما زالوا تبصير acid واضح؟ الأن في هذه + +61 +00:05:28,330 --> 00:05:33,990 +الحالة مافيش عندى تغير في عدد ذرات الكربون فالطرق + +62 +00:05:33,990 --> 00:05:39,310 +المنطلقة من الأكسة ده مافيش فيها تغير بيكون بيوتان + +63 +00:05:39,310 --> 00:05:44,910 +بيوتانوك بيوتانول بيوتانال لكن عدد ذرات الكربون + +64 +00:05:44,910 --> 00:05:48,430 +إيش ماله؟ ثابت حتى لو قلت بيوتين كمان + +65 +00:05:55,150 --> 00:06:03,190 +الان في طرق تانية .. في طرق تانية ممكن أنه نتعامل + +66 +00:06:03,190 --> 00:06:09,570 +معها .. ممكن نشتغل على طريقة اسمها طريقة النقص .. + +67 +00:06:09,570 --> 00:06:16,000 +يعني أبدأ بتلاتةو أكسر من التلاتة هدولة و أجد + +68 +00:06:16,000 --> 00:06:21,820 +أبطلع بإيش نفترض ب 2 و ب 1 أكسر التلاتة أو أبدأ ب + +69 +00:06:21,820 --> 00:06:28,140 +4 و أكسر الأربعة ل 2 و 2 أو ل 3 و 1 هذه طريقة إيش + +70 +00:06:28,140 --> 00:06:33,400 +نقص أنه أنا يكون عند السلسلة الكلية السلسلة الكلية + +71 +00:06:33,400 --> 00:06:39,040 +أربع كربونات أطول منها 3 أو 2 أو 1 يعني أقل من إيش + +72 +00:06:39,560 --> 00:06:44,440 +أقل من الأربعة صارت هذه الطريقة طريقة ايش نقص طبعا + +73 +00:06:44,440 --> 00:06:48,660 +ايش بيظل عندنا انه ممكن تكون طريقة زيادة يعني + +74 +00:06:48,660 --> 00:06:53,920 +افترضوا انه سلسلة عندى أربعة وطلبت + +75 +00:06:53,920 --> 00:06:56,600 +منكوا تحضروا لي حمض بخمس كربونات + +76 +00:07:01,280 --> 00:07:08,760 +أنا قلت لكم ببساطة مبتدئا من البيوتانول البيوتانول + +77 +00:07:08,760 --> 00:07:14,680 +كام كربونا؟ أربعة حضرولي بنتانوك أسد الآن إذا + +78 +00:07:14,680 --> 00:07:19,720 +واحدة مش منتبهة تقول all oic acid تروح تعمل أكسدة + +79 +00:07:19,720 --> 00:07:26,520 +أه بس البيوتانول بيصير بيوتانوك أسدبزيدش Carbona + +80 +00:07:26,520 --> 00:07:30,960 +الان لو كنت بداجي اسألكم والله من ال Butanol + +81 +00:07:30,960 --> 00:07:37,890 +حضرولي Pentanoic acid زدتوا Carbonaإذا أنا بحاجة + +82 +00:07:37,890 --> 00:07:43,030 +إلى طريقة وبناء على ذلك للي بدوا يفهم طرق تحضير + +83 +00:07:43,030 --> 00:07:47,130 +الأحماض بشكل عام بنقول أن طرق تحضير الأحماض بدكوا + +84 +00:07:47,130 --> 00:07:51,870 +تنتبهوا تماما ممكن تكون طريقة التساوي وهذه موجودة + +85 +00:07:51,870 --> 00:07:55,130 +في شغل الأكسد أو الكلام اللي شرحنا الآن ممكن تكون + +86 +00:07:55,130 --> 00:08:01,250 +طريقة تكسير أو نقص وممكن تكون طريقة إيش؟ زيادة + +87 +00:08:01,250 --> 00:08:09,000 +واضحة الفكرة؟ الآن خلينا نيجيلاطرق التكثير خلّينا + +88 +00:08:09,000 --> 00:08:15,340 +نيجي لطرق التكثير بشكل عام نسبة من طرق التكثير مرت + +89 +00:08:15,340 --> 00:08:19,980 +معنا بطريقة أو باخرى ليش؟ لأنه احنا أخدنا ال + +90 +00:08:19,980 --> 00:08:27,460 +ozoneolysis ال ozoneolysis عادة بيكسر المركب لإيش؟ + +91 +00:08:28,390 --> 00:08:33,650 +لأldehyde او كيتون ايه كويس الال بعد ما + +92 +00:08:33,650 --> 00:08:38,370 +الأوزونوليس يعني هيك انا بده اقول الكين والالكاين + +93 +00:08:38,370 --> 00:08:46,370 +زي الالكين بالمناسبة الكين ممكن يعطيني ايش كيتون + +94 +00:08:49,540 --> 00:08:53,540 +الديهايد هذا الكلام اتعلمناه ولا لأ ان الالكين + +95 +00:08:53,540 --> 00:08:57,600 +بيصير كيتون او الديهايد الان الكيتون اتعلمناه انه + +96 +00:08:57,600 --> 00:09:05,060 +لا يتأكسد اكسدة اضافية لكن ال الديهايد بتأكسد ولا + +97 +00:09:05,060 --> 00:09:09,860 +لأ ال الديهايد بتأكسد اكسدة اضافية بيصير ايش acid + +98 +00:09:09,860 --> 00:09:14,440 +الان بكل الأحوال هذا ال الديهايد هيكون اصغر من ال + +99 +00:09:14,440 --> 00:09:20,010 +الكين او من ال الكاين ولا لأبالتأكيد هنا هيلزمني + +100 +00:09:20,010 --> 00:09:25,750 +كام عملية يتموا ورا بعض عمليتين العملية الأولى ال + +101 +00:09:25,750 --> 00:09:31,630 +ozoneolysis و العملية التانية ال oxidation خلّيني + +102 +00:09:31,630 --> 00:09:35,990 +أعبّر عنها ب O بين جثين Oxidation عملية أكسدة عادة + +103 +00:09:35,990 --> 00:09:41,430 +بيستعملونها H2O2 الهيدروجين بيروكسايد هذه كمان + +104 +00:09:41,430 --> 00:09:49,310 +خلّوها H2O2أذن اوزونوليسيز followed by H2O2 يمكن + +105 +00:09:49,310 --> 00:09:55,050 +أن يؤدي إلى أحماض لكن أكيد هتكون أصغر من إيش؟ أصغر + +106 +00:09:55,050 --> 00:10:02,090 +من الألكين اللي أنا ابتدأت فيه الآن خلينا ناخد + +107 +00:10:02,090 --> 00:10:06,910 +مثال حقيقي ناخد مثال حقيقي لو يا ترى أخدنا هذا + +108 +00:10:06,910 --> 00:10:16,980 +الألكينسواء قلنا عنه CES و لا TRANS CH3 CH3H + +109 +00:10:16,980 --> 00:10:26,200 +CH3H و قلنا اكمل نمر واحد O3 Ozonolysis و نمر + +110 +00:10:26,200 --> 00:10:31,060 +اتنين H2O2 H2O2 Hydrogen Peroxide هو العامل + +111 +00:10:31,060 --> 00:10:39,210 +المؤكسد الان بدنا لما ننفذ نفهم الشغل الاولىكسر + +112 +00:10:39,210 --> 00:10:47,350 +يعني C double bond O H و CH3 زائد C double bond OH + +113 +00:10:47,350 --> 00:10:55,750 +و CH3 هذا ال ozonolases طب و ال acid هذا إيش؟ + +114 +00:10:55,750 --> 00:11:00,830 +الديهايد الآن هذا ال الديهايد بال H2O2 اللي ضفناها + +115 +00:11:00,830 --> 00:11:08,760 +إيش حيصير؟ C double bond O OHCH3 وجدت حصلنا على + +116 +00:11:08,760 --> 00:11:14,980 +الاسيتك أسد الاسيتك أسد كده؟ كربون 2 يعني كأنه انا + +117 +00:11:14,980 --> 00:11:18,820 +بال اوزونوليسيز اتيت كصرت الأربعة هدولة اتنين و + +118 +00:11:18,820 --> 00:11:23,400 +اتنين طلعوا عندي ألديهيد الآن كملت أكسدت الألديهيد + +119 +00:11:23,400 --> 00:11:29,060 +صار اسيتك أسد فمن الأربعة حصلت على حامض من كام + +120 +00:11:29,060 --> 00:11:37,890 +كربون؟ تنتين واضحة الفكرة؟ طبعا الآناللي ممكن + +121 +00:11:37,890 --> 00:11:44,390 +يفكروا انه نتعمق معهم بمثل هذه الفكرة ممكن نيجي + +122 +00:11:44,390 --> 00:11:49,910 +نسألهم، مانقول هم مش مبتدئان من ال 2 بيوتين، لو + +123 +00:11:49,910 --> 00:11:55,930 +بدأت من ال one بيوتين، هيطلع عند أحمد واحد و تلاتة + +124 +00:11:56,580 --> 00:12:00,520 +لأن هذه هتكسر كربونا و هدول يكونوا تلاتة لكن لو + +125 +00:12:00,520 --> 00:12:07,080 +انا اجيت و قولتلكم والله من مركب زي هذا CH3 CH2 CH + +126 +00:12:07,080 --> 00:12:15,560 +سواء حطيت هنا CL او OH اتخيلوا ان انا اجي اقولكم + +127 +00:12:15,560 --> 00:12:23,720 +من two chlorobutane حضروا لي acidic acid واضح او + +128 +00:12:23,720 --> 00:12:28,880 +من two butanolبتكون تعملوا elimination الان ال CL + +129 +00:12:28,880 --> 00:12:32,320 +و ال H بيروحوا و بيعطينا ال more substituted + +130 +00:12:32,320 --> 00:12:37,280 +باستعمال ايش طلعت + +131 +00:12:37,280 --> 00:12:44,240 +انا ال alkyd و بعدين كسرت ال alkyd هذه الطرق و مع + +132 +00:12:44,240 --> 00:12:47,020 +ال triple bond نفس الاشي زي ال double bond هذه + +133 +00:12:47,020 --> 00:12:52,180 +الطرق تعتبر طرق ايشانقاس يعني كان عندى اربع + +134 +00:12:52,180 --> 00:12:56,720 +كربونات اعملت حامض من كربونتين اعملت حامض من تلات + +135 +00:12:56,720 --> 00:13:02,840 +كربونات حسب موقع ايش ال bubble bond بس بشرط انه + +136 +00:13:02,840 --> 00:13:06,660 +يكون من نتائج ال ozonosis انه بتكون aldehyde ليش؟ + +137 +00:13:06,660 --> 00:13:10,820 +لأن اللى بيكمل وبيتأكسد ال aldehyde الكيتون بقولنا + +138 +00:13:10,820 --> 00:13:16,140 +فيه إله أكسدة إضافية؟ لأ واضحة الفكرة؟ اللى بيكمل + +139 +00:13:16,140 --> 00:13:21,210 +وبيتأكسد هو مين؟الالديهايد وهذا الكلام أخدناه في + +140 +00:13:21,210 --> 00:13:24,090 +أكسدة الالديهايد والكيتونز قلنا الالديهايد بتصير + +141 +00:13:24,090 --> 00:13:30,430 +أحمار الكيتونز لاتت أكسد أكسدة إضافية واضحة الفكرة + +142 +00:13:30,430 --> 00:13:37,150 +طيب + +143 +00:13:37,150 --> 00:13:45,300 +إذا عرفنا طريقة المساواة وطريقةالنقص ايش ضال + +144 +00:13:45,300 --> 00:13:51,140 +عندنا؟ طريقة الزيادة بمعنى لو انا اجيت وقلتلكم لو + +145 +00:13:51,140 --> 00:13:56,240 +سمحتوا من تلت كربونات بدي احضر حامض من اربع + +146 +00:13:56,240 --> 00:14:03,000 +كربونات عادة الزيادة اللي احنا بنعملها زيادة سهلة + +147 +00:14:03,480 --> 00:14:07,900 +ليه؟ كربونة واحدة هي اللي بتتم بسهولة يعني التلاتة + +148 +00:14:07,900 --> 00:14:13,160 +يصيروا أربعة، الأربعة يصيروا خمسة، الخمسة يصيروا + +149 +00:14:13,160 --> 00:14:17,680 +ستة كيف هذا الكلام .. كيف هذا الكلام بتم؟ هذا + +150 +00:14:17,680 --> 00:14:26,500 +الكلام عادة بتتممنطلقين فيه من ال الكل هلاي من ال + +151 +00:14:26,500 --> 00:14:33,040 +one chloro compound واضح يعني بدي مركب سلسلة يكون + +152 +00:14:33,040 --> 00:14:39,300 +على موقع واحد فيها إيش إكلور بدي سلسلة على موقع + +153 +00:14:39,300 --> 00:14:47,340 +واحد فيها إكلور يعني مثلا زي ما اقول CH3 CH2 CH2 + +154 +00:14:47,340 --> 00:14:56,390 +CLالان الكلور هانا وين؟ على موقع واحد هذا الكلور + +155 +00:14:56,390 --> 00:15:00,050 +مكانه بدي ازيد كربونا اللي هي بده تكون حاملة + +156 +00:15:00,050 --> 00:15:06,320 +مجموعة الاسم عدد الكربونات الكل يعني قداشتلاتة بدي + +157 +00:15:06,320 --> 00:15:11,720 +أحضر من هذا butanoic acid يعني كام كربونا؟ أربعة + +158 +00:15:11,720 --> 00:15:16,640 +في عندى طريقتين ممكنين في عندى طريقتين ممكنين + +159 +00:15:16,640 --> 00:15:22,920 +الطريقة الأولى أنه أنا هذا أجي أفعله مع CN minus + +160 +00:15:22,920 --> 00:15:28,140 +والطريقة التانية أنه أنا هذا أفعله مع green yard + +161 +00:15:28,140 --> 00:15:34,560 +reagentمار عليكم المغنيسيا من اللي بيعطي RMGX طيب + +162 +00:15:34,560 --> 00:15:38,720 +لو فعلنا مع ال cyanide شو بده يصير هذا؟ بده يصير + +163 +00:15:38,720 --> 00:15:49,220 +CH3 CH2 CH2 و هنا بده تيجي مجموعة ال CN لاحظوا هنا + +164 +00:15:49,220 --> 00:15:54,120 +بينت الكربون الرابعة ولا لأ هيصاروا كام كربونة؟ + +165 +00:15:55,060 --> 00:16:02,160 +أربعة بدل تلاتة الان ال cyanide بشكل عام لو عملتله + +166 +00:16:02,160 --> 00:16:11,340 +hydrolysis يا إما ب H3O plus بيمشي الحال أو ب N-A + +167 +00:16:11,340 --> 00:16:15,840 +-O-H و بعدين H plus يعني يا إما بهذا ال reagent يا + +168 +00:16:15,840 --> 00:16:20,100 +إما بهذا ال reagent بأي واحد منهم بيمشي بصير أسلوب + +169 +00:16:20,870 --> 00:16:24,310 +يعني ال cyanide بيعملها hydrolysis ال acid و بعدها + +170 +00:16:24,310 --> 00:16:34,310 +شو هيصير CH3 CH2 CH2 و هذه ال C هي اللي ضالت هتصير + +171 +00:16:34,310 --> 00:16:41,610 +C double bond O OH اذا انا ال chlorine حولتها ل CN + +172 +00:16:41,610 --> 00:16:48,530 +و ال CN ع طول بتصير COOHهذه طريقة معروفة وجيدة + +173 +00:16:48,530 --> 00:16:53,750 +لعمل هذا المُركّب طيب الطريقة التانية .. بدأ أزيد + +174 +00:16:53,750 --> 00:16:58,310 +كربونا لسه .. أنا لو فعلت مع المغنيسيوم .. هذا إيش + +175 +00:16:58,310 --> 00:17:04,750 +هيعطيني؟ الـ Grignard Reagent .. كلكم اتذكرينه؟CH3 + +176 +00:17:04,750 --> 00:17:13,470 +CH2 CH2 وقلنا هذه اهم اشي فيها MgCl هاي Green Yard + +177 +00:17:13,470 --> 00:17:18,630 +Ray Agent إبروبيل مغنيسيا ميكلورايد صح؟ الآن هذا + +178 +00:17:18,630 --> 00:17:25,330 +ال Green Yard Ray Agent بفعله مع نمرة واحد CO2 + +179 +00:17:25,330 --> 00:17:28,250 +لاحظوا هاي ال C double bond O double bond O ثاني + +180 +00:17:28,250 --> 00:17:29,030 +أكسيد كربون + +181 +00:17:31,920 --> 00:17:38,840 +واضح؟ ونمر اتنين خليني ال CO2 ارسمه بالاحمر بفعله + +182 +00:17:38,840 --> 00:17:43,220 +مع ال CO2 يعني C double bond O double bond O ونمر + +183 +00:17:43,220 --> 00:17:49,000 +اتنين مع H بلس بيعطيني الحامض اللي هتقولولي من وين + +184 +00:17:49,000 --> 00:17:54,710 +اجت الكربونة؟هي من الـ CO2 مش الـ C حاملة انتن + +185 +00:17:54,710 --> 00:17:59,370 +أكسجين وهنا إيش زاد عندي؟ C double bond O OH + +186 +00:17:59,370 --> 00:18:06,590 +ببساطة هذا نيوكليوفايل بيهاجم هنا بيهاجم على + +187 +00:18:06,590 --> 00:18:09,990 +الكربون الموجبة مش الكربون بتاع تاني أكسيد الكربون + +188 +00:18:09,990 --> 00:18:15,050 +الموجبة لأنه جنبها مجموعتين سالبات لما يهاجم هذا + +189 +00:18:15,050 --> 00:18:20,250 +بتصير O minus ومن ال H plus بتاخد H إيش بتصير؟ OH + +190 +00:18:21,350 --> 00:18:27,040 +إذا هنا مصدر الكربونة الجديدة إيش بيكون؟الـ CO2 + +191 +00:18:27,040 --> 00:18:31,720 +إذا أنا لما بدي أعمل الزيادة بدي مصدر للكربونة + +192 +00:18:31,720 --> 00:18:36,540 +الجديدة مصدر الكربونة الجديدة يا بدي يكون ال CN و + +193 +00:18:36,540 --> 00:18:39,340 +بعدين أعمل ال hydrolysis يا بعمل ال green yard + +194 +00:18:39,340 --> 00:18:43,280 +reagent و الكربونة الجديدة بجيبها من وين؟ من ال + +195 +00:18:43,280 --> 00:18:50,340 +CO2 واضح الفكرة؟ الآن مرة تانية مش ضروري تكون نقطة + +196 +00:18:50,340 --> 00:18:57,860 +البداية اللي عندى هي هذا المركب الكلوريممكن تكون + +197 +00:18:57,860 --> 00:19:02,180 +نقطة البداية الكحول الان الكحول بقدر اخليك low + +198 +00:19:02,180 --> 00:19:07,140 +right في الخطوة الأولى بالإبدال كحول مع O H minus + +199 +00:19:07,140 --> 00:19:17,960 +بيعمل إبدال ممكن تكون نقطة البداية الالكين هذه + +200 +00:19:17,960 --> 00:19:19,900 +الالكين بتلت كربونات + +201 +00:19:29,710 --> 00:19:35,570 +واضحة الفكرة فهذه + +202 +00:19:35,570 --> 00:19:41,830 +طرق الزيادة اللى عادة بنستعملها من خلال ال CN أو + +203 +00:19:41,830 --> 00:19:42,630 +ال CO2 + +204 +00:19:52,800 --> 00:19:54,940 +هنا على السلسلة هذه + +205 +00:20:03,960 --> 00:20:08,640 +لأ لأ لأ لأ لأ ال chlorineation ال chlorineation + +206 +00:20:08,640 --> 00:20:13,260 +على السلسلة أخدناها ب CL2 في وجود ضوء أو حرارة أو + +207 +00:20:13,260 --> 00:20:16,560 +من خلال الإضافة ع ال double bond يعني ال chlorine + +208 +00:20:16,560 --> 00:20:20,600 +مع ال FeCl3 هذا على ال aromatic compounds هذا على + +209 +00:20:20,600 --> 00:20:28,580 +ال aromatic compounds تمام بضل في عندى ال benzoic + +210 +00:20:28,580 --> 00:20:35,710 +acidعارفين البنزويك أسد؟ كيف ممكن نحضر البنزويك + +211 +00:20:35,710 --> 00:20:40,970 +أسد؟ و مرات ممكن نسأل كيف ممكن تحضروا البنزويك أسد + +212 +00:20:40,970 --> 00:20:44,370 +من البنزين هاي البنزويك أسد + +213 +00:20:53,780 --> 00:20:59,240 +سهلة ان لو انا عندى cyanobenzene بصير benzoic acid + +214 +00:20:59,240 --> 00:21:05,480 +هذه الطريقة خلينى نقول ايش مالها سهلة CN اذا عندى + +215 +00:21:05,480 --> 00:21:11,740 +cyanobenzene في وجود H plus او NaOH نمرة واحد و + +216 +00:21:11,740 --> 00:21:15,320 +نمرة اتنين H plus زى ما حكينا قبل شوية ال + +217 +00:21:15,320 --> 00:21:21,420 +cyanobenzene بصير acid فيها مشكلةطبعا هيصير السؤال + +218 +00:21:21,420 --> 00:21:26,080 +كيف يتحضر السيانو بنزين .. سيانو بنزين في شبطر 11 + +219 +00:21:26,080 --> 00:21:31,510 +بنتعلم تحضيرهبيجيش مباشر بقتش CN لأ اللي طريقة + +220 +00:21:31,510 --> 00:21:37,250 +التفافية ال CN و البنزين بيجيش بشكل مباشر بتحضرش + +221 +00:21:37,250 --> 00:21:41,630 +بشكل مباشر انه بنزين ماقتش CN ليش؟ لإن ال CN minus + +222 +00:21:41,630 --> 00:21:45,590 +و البنزين حاملة إلكترونات بيهاجمش minus على minus + +223 +00:21:45,590 --> 00:21:51,270 +طمام الطريقة التانية انه لو احنا أخدنا .. نخلص من + +224 +00:21:51,270 --> 00:21:56,770 +هذه الطريقة و نمحاها لو احنا أخدنا أي بنزين بيحمل + +225 +00:21:56,770 --> 00:22:02,490 +ال kilogramإيش في بنزين بيحمل الكل جروب؟ الطلوين + +226 +00:22:02,490 --> 00:22:05,670 +صح؟ + +227 +00:22:05,670 --> 00:22:13,890 +CH3 إيش ممكن كمان؟ ال F البنزين CH2 CH3 إيش كمان + +228 +00:22:13,890 --> 00:22:26,110 +ممكن؟ القيومين CH CH3 CH3 كل هدولة بيحملوهالكلي + +229 +00:22:26,110 --> 00:22:29,950 +جروبز ممكن حد يفكر كمان بال تيرتشار بيوت البنزين + +230 +00:22:29,950 --> 00:22:36,610 +ممكن حد يفكر بال تيرتشار بيوت البنزين الآن بنقول + +231 +00:22:36,610 --> 00:22:43,230 +القاتل لو استعملنا عام المؤكسد بشكل عام ال KMnO4 + +232 +00:22:43,230 --> 00:22:48,710 +برمجانات البوتاسيوم مع أي ألكل بنزين مع أي ألكل + +233 +00:22:48,710 --> 00:22:54,480 +بنزين بس بشرطالكربون المتصل على البنزين مباشرة + +234 +00:22:54,480 --> 00:22:59,040 +تحتوي على ذرة هيدروجين على اقل تقدير الان هذه + +235 +00:22:59,040 --> 00:23:03,540 +الكربون .. كم هيدروجين بتحمل؟ تلاتة .. هذه .. هذه + +236 +00:23:03,540 --> 00:23:08,000 +.. هذه .. ولا واحدة .. اذا هدولة التلاتة بيمشي + +237 +00:23:08,000 --> 00:23:14,540 +حالهمأى واحدة من هدول بالأكسدة بكامان of four + +238 +00:23:14,540 --> 00:23:18,820 +بتعطينا بنزويك أسل الان انتبهوا معي لنقطة كتير + +239 +00:23:18,820 --> 00:23:26,100 +مهمة انه بغض النظر عن طول السلسلة هنطلع بس بنزويك + +240 +00:23:26,100 --> 00:23:30,960 +أسل يعني لو كان هنا مثل او اثل او بروبل او بيوتل + +241 +00:23:30,960 --> 00:23:34,760 +كربونة او تنتين او تلاتة او اربعة او خمسة او عشرة + +242 +00:23:35,740 --> 00:23:40,220 +بس هطلعوا إيش ال benzoic acid مرات كتير لما بنيجي + +243 +00:23:40,220 --> 00:23:44,620 +بنسأل الطلاب بنقولهم الله أعملونا أكسدة بنزين حامل + +244 +00:23:44,620 --> 00:23:47,340 +تلت كربونات بيروحوا بيخلوا الكربونتين و بيعملوا + +245 +00:23:47,340 --> 00:23:51,640 +الأكسدة على التالتة افهمتوا الغلطة اللي بحكيها ولا + +246 +00:23:51,640 --> 00:24:00,600 +أوضحها أكتر لما أجي أرسملهم مركب زي هذا CH2 CH2 + +247 +00:24:00,600 --> 00:24:07,120 +CH3 و أقولهم بالكمان O4الآن الغلطة اللي بيعملوه + +248 +00:24:07,120 --> 00:24:11,900 +بيعملوا ال acid هانا و بيخلوها دولة الجواب الصحيح + +249 +00:24:11,900 --> 00:24:15,620 +انه سواء كانوا دول واحدة او تنتين او تلاتة او + +250 +00:24:15,620 --> 00:24:20,720 +اربعة او عشرة بس بتكون عند هانا مجموعة ال acid + +251 +00:24:20,720 --> 00:24:27,240 +COOHبمعنى أنا بشرحش ميكانيزم متفق انه بدنيش ادخل + +252 +00:24:27,240 --> 00:24:31,180 +كتير بتفاصيل يعني خليني في النتائج بمعنى لو انا + +253 +00:24:31,180 --> 00:24:38,120 +اجيت سألتكم و قولتلكم انه تفاعل الطلوين والاكيومين + +254 +00:24:38,120 --> 00:24:42,120 +اه انتبهوا معاك الطلوين والاكيومين مع الكيامة ال + +255 +00:24:42,120 --> 00:24:47,990 +O4 both produces benzoic acid صحبينما لو كان + +256 +00:24:47,990 --> 00:24:52,390 +السؤال تفاعل الطلوين والـ tertiary بيوت البنزين + +257 +00:24:52,390 --> 00:24:56,490 +هذا لأ لأن هذا مافيش عليه هيدروجينة على الكاربون + +258 +00:24:56,490 --> 00:25:03,190 +المتصلة مباشرة بالبنزينة واضحة الفكرة؟ فعشان اتم + +259 +00:25:03,190 --> 00:25:06,810 +هذا النوع من الأكسدة هذا بنسميه oxidation of the + +260 +00:25:06,810 --> 00:25:12,290 +aliphatic sided chain مش هذه سلسلة معلقة على + +261 +00:25:12,290 --> 00:25:18,730 +البنزينولذلك هذا التفاعل اسمه أكسدت السلسلة + +262 +00:25:18,730 --> 00:25:24,110 +المعلقة على البنزين، مهما كبرت ومهما عظمت، ايش + +263 +00:25:24,110 --> 00:25:31,750 +بتعطيني؟ acid، بس، بغض النظر عن طولهاواضح؟ + +264 +00:25:31,750 --> 00:25:36,530 +Oxidation of the aliphatic sided chain attached to + +265 +00:25:36,530 --> 00:25:41,330 +benzene واضحة الفكرة؟ هذه طريقة لتحضير ال benzoic + +266 +00:25:41,330 --> 00:25:46,570 +acid طبعا احنا جيبنا طريقة تانية باستعمال إيش؟ ال + +267 +00:25:46,570 --> 00:25:54,040 +CN إذا هي كام طريقة صيرنا ذاكرين لكم؟طريقة السيانة + +268 +00:25:54,040 --> 00:26:00,060 +جيبناها ولا لأ؟ طيب خلينا نمحا كل هالكلام ونقول لو + +269 +00:26:00,060 --> 00:26:05,320 +إجاكم السؤال في الامتحان ابتلى الطرق حضرولي ال + +270 +00:26:05,320 --> 00:26:08,440 +benzoic acid هتقولوا ال aliphatic side chain هذه + +271 +00:26:08,440 --> 00:26:12,620 +كلها طريقة حتى لو من البنزين بقول بنزين طلوين + +272 +00:26:13,730 --> 00:26:17,930 +بنزويك أسد واضح؟ لما أقولكوا بدي بنزويك أسد من + +273 +00:26:17,930 --> 00:26:23,090 +البنزين، شو هانمشي؟ بنزين طول وين؟ بنزويك أسد + +274 +00:26:23,090 --> 00:26:28,750 +صعبة؟ من السيان و بنزين؟ ابنعملها طب لو قولنا بدنا + +275 +00:26:28,750 --> 00:26:33,090 +طريقة تالتة من البنزين + +276 +00:26:39,040 --> 00:26:48,920 +طريقة تالتة بد بنزويك أسد من البنزين واضحة + +277 +00:26:48,920 --> 00:26:58,260 +الفكرة هي بنزين بد يصير بنزويك أسد حسب ما اتعلمنا + +278 +00:26:58,260 --> 00:27:03,900 +لاحظوا ما بين البنزين + +279 +00:27:03,900 --> 00:27:09,650 +و بنزويك أسد زيادة كربونةولذلك .. و لذلك احنا قلنا + +280 +00:27:09,650 --> 00:27:17,870 +بطريقة ما هذه لما صارت سيانو اقدرنا + +281 +00:27:17,870 --> 00:27:21,330 +نحولها ل acid بس مااخدناش الطريقة اللي بتخليها + +282 +00:27:21,330 --> 00:27:24,970 +سيانو لحتى الان الان ما طريقة الزيادة التانية + +283 +00:27:24,970 --> 00:27:34,830 +اللتي تعلمناها اغرينيا اذا هذا يصير اكلوروبنزين + +284 +00:27:34,830 --> 00:27:40,590 +هذه تعلمناها ولا لأالكلورو بنزين لو فعلناه معي + +285 +00:27:40,590 --> 00:27:47,050 +green yard مع Mg شو بيصير؟ + +286 +00:27:47,050 --> 00:27:56,270 +MgCl ال MgCl بإيش بيزيد كربونا؟ بتاني أكسيد + +287 +00:27:56,270 --> 00:28:03,890 +الكربون وحمد إذا بنزين كلورو بنزين طبعا كلكوا + +288 +00:28:03,890 --> 00:28:06,470 +عارفين ال reaction اللي هو Cl2 + +289 +00:28:13,200 --> 00:28:26,560 +بنزين بيصير بنزويك أسد بنزين بيصير + +290 +00:28:26,560 --> 00:28:30,080 +طلوين + +291 +00:28:30,080 --> 00:28:36,360 +بنزويك أسدو بعدين كيامان افور بالكيامان افور اذا + +292 +00:28:36,360 --> 00:28:40,460 +هى البنزويك اسد بتلات طرق اللى بده يحفظهم اول شى + +293 +00:28:40,460 --> 00:28:47,160 +يقول بنزين طلوين بنزويك اسد بنزين سيانو بنزين + +294 +00:28:47,160 --> 00:28:52,720 +بنزويك اسد بنزين كلورو بنزين بنزين جرينيارد بنزويك + +295 +00:28:52,720 --> 00:28:57,180 +اسد كل هذه طرق لتحضير البنزويك اسد ولا لأ كان + +296 +00:28:57,180 --> 00:29:02,480 +طريقة تلاتة واضح وبهيك بننهي اليوم + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..9d2fb105496c2e5f407052827cf5060045d9898c --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_postprocess.srt @@ -0,0 +1,2132 @@ +1 +00:00:19,470 --> 00:00:24,730 +بسم الله الرحمن الرحيم بدأنا من محاضرة او محاضرتين + +2 +00:00:24,730 --> 00:00:28,470 +في موضوع ال الديهيدس والكيتونز اتعرفنا عليهم ليش + +3 +00:00:28,470 --> 00:00:34,430 +اتصنفوا مع بعض تسمية ال الديهيدس والكيتونز طرق + +4 +00:00:34,430 --> 00:00:38,690 +صناعية لتحضير اشهر ال الديهيدس والكيتونز كان اخر + +5 +00:00:38,690 --> 00:00:44,270 +شيء اتكلمنا عنه الان في المختبر الطرق العامة + +6 +00:00:44,270 --> 00:00:49,420 +لتحضير ال الديهيدس والكيتونزإذا بنستعرضها مع بعض + +7 +00:00:49,420 --> 00:00:53,560 +بنلاحظ أن هذه الأشياء مرت علينا الحقيقة يعني + +8 +00:00:53,560 --> 00:00:58,080 +الطريقة الأولى لتحضير ال aldehydes و ال ketones من + +9 +00:00:58,080 --> 00:01:03,300 +أجسدة الكحولات لما أخدنا ال alcohols قلنا أن ال + +10 +00:01:03,300 --> 00:01:06,880 +alcohols they are either primary, secondary or + +11 +00:01:06,880 --> 00:01:13,120 +tertiary وقلنا أن ال primaryبصيروا باستعمال ال BCC + +12 +00:01:13,120 --> 00:01:16,960 +الديهيدز و ممكن يمدوا اكتر لو كان العامل مؤاكسد + +13 +00:01:16,960 --> 00:01:20,660 +اقوى بصيروا acids هذا مش الموضوع هنا ال secondary + +14 +00:01:20,660 --> 00:01:26,500 +alcohol باستعمال كيامانو 4 او كيتو كروميون 2 + +15 +00:01:27,340 --> 00:01:33,400 +برمجانات البوتاسيوم كيتو كروميوم 207 بوتاسيوم داي + +16 +00:01:33,400 --> 00:01:37,940 +كروميت أو كروميك أكسيد بيصيروا كيتون فهذا أكسد + +17 +00:01:37,940 --> 00:01:42,720 +بالالكوهولز هي طريقة في انها لتحضير ال الديهايد + +18 +00:01:42,720 --> 00:01:45,520 +والكيتون من ال primer بناخد ال الديهايد ومن + +19 +00:01:45,520 --> 00:01:50,730 +السكندر بناخدالكيتون هذه طريقة مرت علينا سابقا + +20 +00:01:50,730 --> 00:01:58,450 +الاروماتيك كيتون أخدناهم كنا انحضر الاسيتوفينون + +21 +00:01:58,450 --> 00:02:06,640 +مثلا من استعمال ال acid halidesR-C-O-C-L هذي C-O + +22 +00:02:06,640 --> 00:02:10,700 +معناها C double bond و C-L في وجود ألومنيوم + +23 +00:02:10,700 --> 00:02:14,400 +الكلورايد الألومنيوم الكلورايد بيسحب الكلور و + +24 +00:02:14,400 --> 00:02:18,280 +بيعمل عندنا الايون الموجب و بيصير Electrophilic + +25 +00:02:18,280 --> 00:02:22,920 +Substitution اللي سمناه Friedel Crafts Acylation + +26 +00:02:22,920 --> 00:02:26,700 +واضح سمناه Friedel Crafts Acylation أخدنا Friedel + +27 +00:02:26,700 --> 00:02:30,720 +Crafts Alkylation و Acylation في شبطر الاروماتيك + +28 +00:02:31,490 --> 00:02:38,470 +from alkynes اخدنا احنا ان ال alkynes بيضيفوا مية + +29 +00:02:38,470 --> 00:02:42,090 +المية اللى بيضيفوها ممكن تكون حسب قاعدة + +30 +00:02:42,090 --> 00:02:46,390 +Markovnikov يضيف HOO يصير اندي double bond او Anti + +31 +00:02:46,390 --> 00:02:51,070 +Markovnikov HOH و في كل الأحوال لما يصير اندي in + +32 +00:02:51,070 --> 00:02:55,810 +all يعني هذا ال alkyne لو ضفنا عليه HOOH بدو يصير + +33 +00:02:55,810 --> 00:03:03,290 +double bondInol أخدنا أن Inol يعمل توتوميريزم + +34 +00:03:03,290 --> 00:03:08,550 +لكيتون أو لالديهيد سمناها keto inol توتوميريزم + +35 +00:03:08,550 --> 00:03:12,050 +يعني بهذا المثال لما نضيف الميه في وجود الحامض + +36 +00:03:12,050 --> 00:03:17,090 +فالإضافة بمرحلتها الأولى Markov-Nikov addition لما + +37 +00:03:17,090 --> 00:03:21,850 +نعمل التوتوميريزم ال COH بتصير C double bond O + +38 +00:03:21,850 --> 00:03:25,830 +يعني هذا بنرجع في الفصل التالت هذا بنرجع في الفصل + +39 +00:03:25,830 --> 00:03:30,800 +الرابع هذا بنرجع في الفصلالسابق كل هذه طرق تحضير + +40 +00:03:30,800 --> 00:03:36,580 +الالديهيد والكيتون مرت معناه وهذه الميزة الحقيقة + +41 +00:03:36,580 --> 00:03:41,540 +موجودة في ال organ ال chemistry انه انا في اندي شي + +42 +00:03:41,540 --> 00:03:45,300 +اسمه functional group interconvergent يعني اتحول + +43 +00:03:45,300 --> 00:03:51,180 +من شغلة لشغلة من كحول لالديهيد من كحول الى كيتون + +44 +00:03:51,180 --> 00:03:57,130 +من الكاين الى كيتونالان طالما صار عندى مسميين + +45 +00:03:57,130 --> 00:04:01,670 +طالما صار عندى مسميين اذا الشغل هتمر عندى مرتين + +46 +00:04:01,670 --> 00:04:04,150 +يعني لما انا بقول ان انا عندى كحول بده يصير + +47 +00:04:04,150 --> 00:04:07,530 +aldehyde او كيتون هتلاقوا انحنا نذكرها لما بنحكي + +48 +00:04:07,530 --> 00:04:10,990 +عن ال alcohol كتفاعل و نذكرها لما بنحكي عن ال + +49 +00:04:10,990 --> 00:04:15,290 +aldehydes و ال ketones كطريقة للتحضير بعد شوية + +50 +00:04:15,290 --> 00:04:18,690 +هنيجي على ال aldehydes و ال ketones طالما هذه + +51 +00:04:18,690 --> 00:04:25,320 +العملية أكسدة طب لو رجعنا فيها رجوعهتصير تفاعل لل + +52 +00:04:25,320 --> 00:04:28,060 +الديهيد والكيتون هلاحظ ان ال reduction of + +53 +00:04:28,060 --> 00:04:31,700 +aldehydes and ketones produces ايش؟ alcohol + +54 +00:04:31,700 --> 00:04:36,960 +فالعملية عملية متعاكسة وعشان كده الكلام بنشوفه + +55 +00:04:36,960 --> 00:04:41,820 +باكثر من مكان alcohol صار الديهيد او كيتون بالاكسة + +56 +00:04:41,820 --> 00:04:48,000 +ده الآن طب الديهيد او كيتونبالاختصار هيرجع ايش؟ + +57 +00:04:48,000 --> 00:04:53,740 +هيرجع لالكول وسبق احنا انه وضحنا معنى الأكسادة ان + +58 +00:04:53,740 --> 00:05:00,020 +هي في النهاية اما انها زيادة في المحتوى الاكسوجيني + +59 +00:05:00,020 --> 00:05:05,940 +او نقص في محتوى الهيدروجينيالان هذه ال aldehydes و + +60 +00:05:05,940 --> 00:05:10,920 +ال ketones خلينا نقول في النهاية هي و كل الكيميا + +61 +00:05:10,920 --> 00:05:15,680 +لازم نفهمها من منطق التطبيق العملي يعني هي بتبدأ + +62 +00:05:15,680 --> 00:05:19,680 +معناه ربوز لكن في النهاية بواقع الحياة بتنتهي انها + +63 +00:05:19,680 --> 00:05:25,170 +مركباتالها وجود في الحياة العملية، الها تطبيق على + +64 +00:05:25,170 --> 00:05:28,790 +سبيل المثال ال Benzaldehyde هذا Aldehyde + +65 +00:05:28,790 --> 00:05:33,670 +Benzaldehyde هذا هو عبارة عن ال oil of almonds هو + +66 +00:05:33,670 --> 00:05:39,600 +زيت اللوزواضح؟ في زيت مشهور اسمه زيت اللوز لو + +67 +00:05:39,600 --> 00:05:43,740 +أسرنا اللوز بيطلع منه زيت اللي هو ال benz aldehyde + +68 +00:05:43,740 --> 00:05:49,140 +هذا ال aldehyde اللي شايفينه C double bond OH مع + +69 +00:05:49,140 --> 00:05:54,000 +حلقة بنزين و double bond هذا مركب كامل هذا اسمه + +70 +00:05:54,000 --> 00:05:58,880 +cinnamaldehyde cinnamaldehyde جاية من ال cinnamon + +71 +00:05:58,880 --> 00:06:05,880 +cinnamon يعني جرفةواضح؟ فهو المركب الأساسي اللي + +72 +00:06:05,880 --> 00:06:10,360 +بيعطي الجرفة الريحة تبعتها لأن الجرفة اسمها + +73 +00:06:10,360 --> 00:06:16,560 +cinnamon هو سموه إيش؟cinnamaldehyde مثلا بالالماني + +74 +00:06:16,560 --> 00:06:22,480 +الجرفة اسمها zimt فبيسموه zimt aldehyde واضح zimt + +75 +00:06:22,480 --> 00:06:27,300 +aldehyde هنا cinnamon cinnamaldehyde واضح فهذه + +76 +00:06:27,300 --> 00:06:31,620 +الجرفة اللي احنا بنتناولها في النهاية هي aldehyde + +77 +00:06:31,620 --> 00:06:36,180 +مر علينا سابقا ان الفانيلة هي عبارة عن aromatic + +78 +00:06:36,180 --> 00:06:40,600 +aldehyde عليه مجموعة هيدروكسي وميثوكسي الفانيلين + +79 +00:06:41,300 --> 00:06:47,120 +الان كتير ناس بيحبوا زيت النعناع sperminate oil + +80 +00:06:47,120 --> 00:06:51,220 +اللى بدخل فى مشتقات كتيرة و لعلاج الزور هذا عبارة + +81 +00:06:51,220 --> 00:06:54,680 +عن كيتون هى فيه ال C double bond O اللى بنسميه + +82 +00:06:54,680 --> 00:06:59,960 +carbonالمركب الكيميائي carbon لكن هذا ال carbon هو + +83 +00:06:59,960 --> 00:07:05,500 +ال sperm in it oil هو زيت النعمة واضح هذا المركب + +84 +00:07:05,500 --> 00:07:08,960 +لاحظوا بتلاحظوه مركب كبير لكن انا بهمن المجموعة + +85 +00:07:08,960 --> 00:07:12,280 +الوظيفية في نهاية المجموعة الوظيفية ايش فيه C + +86 +00:07:12,280 --> 00:07:17,240 +double bond O كيتون finally كيتون هذا ال camphor + +87 +00:07:17,240 --> 00:07:21,720 +الكفور واضح اللي بيستعملوه لعلاج الرجلين و ما إلى + +88 +00:07:21,720 --> 00:07:28,840 +ذلك الآن مش ضايل عندنا غير مينغير البحتري عاد + +89 +00:07:28,840 --> 00:07:34,560 +الربيع الى الدنيا بموقبه فزينت واكتست بالسندس + +90 +00:07:34,560 --> 00:07:38,580 +الشجر اه الياسمين الياسمين خلال أسبوعين اللي عندهم + +91 +00:07:38,580 --> 00:07:44,570 +ياسمينة هيلاحظوا كل الياسمينة إيش تصيربيضة من إيش؟ + +92 +00:07:44,570 --> 00:07:50,590 +أه هي الياسمون كيتو واضح؟ ملاحظين مركب معين هذا + +93 +00:07:50,590 --> 00:07:56,910 +اللي هو الياسمون من ال oil of ياسمين من زيت + +94 +00:07:56,910 --> 00:08:01,190 +الياسمين بنطول هذا المركب الأساسي اللي بيعطيها + +95 +00:08:01,190 --> 00:08:04,790 +الريحة الكويسة سواء عملنا منه أطور أو الناس حتى + +96 +00:08:04,790 --> 00:08:11,500 +بيشموها و هي على الشجر ريحة جيدةفهذه المراكبات + +97 +00:08:11,500 --> 00:08:16,860 +الحقيقة يعني إلها مجال كبير في التطبيق طبعا أكيد + +98 +00:08:16,860 --> 00:08:20,060 +إلها مجالات في أشياء كتيرة غير هيك في أدوية في + +99 +00:08:20,060 --> 00:08:24,280 +الصناعة ولذلك إحنا بندرسها بعنق و بنتعرف عليها + +100 +00:08:24,280 --> 00:08:31,560 +الآن لو بدنا نيجي بعد هيك لتفاعلات ال aldehydes و + +101 +00:08:31,560 --> 00:08:38,080 +ال ketones قلنا بشكل عام الأمر مختصر فيهكلمة واحدة + +102 +00:08:38,080 --> 00:08:43,900 +اللي هي addition واضح طبعا لو اجينا بدنا ندقق في + +103 +00:08:43,900 --> 00:08:48,540 +كلمة ال addition in eucleophilic addition بمعنى + +104 +00:08:48,540 --> 00:08:54,820 +المهاجم لازم يكون ايش؟اليوكليوفايل ليش المهاجم + +105 +00:08:54,820 --> 00:08:59,660 +لازم يكون اليوكليوفايل لأن الالدهايد والكيتون فيهم + +106 +00:08:59,660 --> 00:09:03,060 +السيضة بالبوند او اللي موجودة لو اتطلعنا علي اي + +107 +00:09:03,060 --> 00:09:07,040 +مكان ارسمها بشكل اوضح السيضة بالبوند او لو اتطلع + +108 +00:09:07,040 --> 00:09:10,420 +السلبية هذا الطرف partially positive هذا partially + +109 +00:09:10,420 --> 00:09:16,870 +negative الان اللي بدو يهاجم عادةاليوكليوفايل واضح + +110 +00:09:16,870 --> 00:09:21,210 +اللي بيهاجم عادة نيوكليوفايل لما يهاجم هنا زوج + +111 +00:09:21,210 --> 00:09:25,430 +الإلكترونات هذا بتتحرك بيصف النتيجة ان هي carbon + +112 +00:09:25,430 --> 00:09:33,470 +OH نيوكليوفايل الان في عند اصلا مجموعتين تانين هنا + +113 +00:09:33,470 --> 00:09:37,350 +مش رسموهم دولة مافيش عليهم أي تغيير + +114 +00:09:38,710 --> 00:09:42,830 +الخلاصة أن التفاعل الأساسي لـ aldehydes و لـ + +115 +00:09:42,830 --> 00:09:48,430 +ketones كان هناك double bond و أصبحت تنتين single + +116 +00:09:48,430 --> 00:09:53,550 +bond واحدة OH واحدة نيوكليوفايل بكل الأحوال هنا + +117 +00:09:53,550 --> 00:09:57,690 +عدد الروابط أربعة و هنا عدد الروابط أربعة فال + +118 +00:09:57,690 --> 00:10:04,000 +double bond O تصبحوبصير عنده رابطة جديدة مع ال + +119 +00:10:04,000 --> 00:10:09,580 +file واضح الفكرة هذا هو التفاعل اللي هيظل يتكرر + +120 +00:10:09,580 --> 00:10:17,260 +بناء على ذلك بصير الان كل هذه المحاضرةهتحكي شغلة + +121 +00:10:17,260 --> 00:10:21,260 +واحدة بسيطة اللي بيفهمها بيقدر إذا مستعجل يروح + +122 +00:10:21,260 --> 00:10:24,640 +يمشي إنه إيش أنواع الـ nucleophile اللي بتهاجم + +123 +00:10:24,640 --> 00:10:28,140 +أعطونا أمثلة بنقول نمروا واحد الميّه، نمروا اتنين + +124 +00:10:28,140 --> 00:10:31,260 +الكحول، نمروا تلاتة الـCr، نمروا أربعة الـH-, + +125 +00:10:31,260 --> 00:10:36,000 +نمروا خمسة كذا، نمروا ستة كذا فبكل المحاضرة هذه + +126 +00:10:36,000 --> 00:10:40,880 +فقط احنا بدنا نحتفظ بهذا ال frame إن هدول + +127 +00:10:40,880 --> 00:10:44,200 +المجموعتين في الأساس ماتغيروش الـC double bond O + +128 +00:10:44,200 --> 00:10:51,110 +صارت OHانغيّر هذه المجموعة واضحة الفكرة؟ بمعنى لو + +129 +00:10:51,110 --> 00:10:55,370 +انا الآن بقولكوا ان النيوكليوفايل كان ميّه ايش + +130 +00:10:55,370 --> 00:11:01,110 +هنحط هنا؟ OH بيصير عائلة اسمها الهيدريت اللي فيها + +131 +00:11:01,110 --> 00:11:04,010 +كاربون حاملة انت نواتش بحكي بالتفصيل ماتستعجلوش + +132 +00:11:04,010 --> 00:11:11,350 +الآن طب لو ضفنا كحول؟ OR بيصير عائلة جديدة اسمها + +133 +00:11:11,350 --> 00:11:15,570 +سيانهيدريل شوف كيف البساطة طب لو ضفنا CM؟ + +134 +00:11:18,510 --> 00:11:26,090 +لحظة لو سمحتوا لو ضفنا OR بيصير عندنا عائلة اسمها + +135 +00:11:26,090 --> 00:11:29,570 +hemacetal انا قلت cyanohedrin hemacetal طيب لو + +136 +00:11:29,570 --> 00:11:37,070 +ضفنا CN cyanohedrin بيسموها لو ضفنا H minus هذه + +137 +00:11:37,070 --> 00:11:46,110 +عملية الاختزال H برجعلك كحول واضح؟ لو ضفنا Amin + +138 +00:11:46,860 --> 00:11:53,400 +أمونيا انا H2 متعودين انتوا لنيوترا ليوكليوفايل شو + +139 +00:11:53,400 --> 00:12:01,380 +هيصير هيفقد H و هكذا فكل الأمثلة اللي هنحكيها + +140 +00:12:01,380 --> 00:12:05,020 +هتكون ماخدة هذا الإطار العام كل الأمثلة اللي + +141 +00:12:05,020 --> 00:12:08,700 +هنحكيها هتاخد هذا الإطار العام البسيط + +142 +00:12:11,390 --> 00:12:18,850 +بفيد شغلة أن هذا التفاعل بشكل عام بتم له catalysis + +143 +00:12:18,850 --> 00:12:23,970 +يعني تسريع بإضافة H plus عشان هيك في معظم الحالات + +144 +00:12:23,970 --> 00:12:29,910 +هتلاحظوا على سهم التفاعل موجود عنده في وجود إيشأتش + +145 +00:12:29,910 --> 00:12:37,090 +بلس وظيفتها أن تعمل تسريع للتفاعل لاحظوا لو أنا + +146 +00:12:37,090 --> 00:12:40,710 +كان عندي الديهيد او كيتون وضفت عليه أتش بلس الأتش + +147 +00:12:40,710 --> 00:12:46,140 +بلس وين هتروح على الموجة ولا على الأكسجين السالبع + +148 +00:12:46,140 --> 00:12:51,580 +الأكسجل موجب على سالب هتصير بهذا الشكل و لو حركنا + +149 +00:12:51,580 --> 00:12:54,860 +زوج الألكترونات تعملنا resonance هلاحظ أنه أنا + +150 +00:12:54,860 --> 00:12:59,720 +بصير عند الكاربون موجبة full positive charge الآن + +151 +00:12:59,720 --> 00:13:03,880 +قبل شوية لما رسمنا احنا كنا نقول هنا إيش شحنة إيش + +152 +00:13:03,880 --> 00:13:11,060 +مالها partial charge ال acidلما اجى اضاف ال H plus + +153 +00:13:11,060 --> 00:13:16,060 +هنا خلى هذا ال carbon موجب كامل الان ال + +154 +00:13:16,060 --> 00:13:22,200 +nucleophile انه افضل له اهاجم على موجب جزء ولا على + +155 +00:13:22,200 --> 00:13:26,900 +موجب كامل اهاجم على موجب كامل التجادب ايش بيكون + +156 +00:13:26,900 --> 00:13:31,320 +اقوى والتفاعل اسرع هاي بالظبط اللي بيعملوا ال acid + +157 +00:13:31,320 --> 00:13:37,720 +الان الناتج النهائي مافيش فيه خلافالناتج النهائي + +158 +00:13:37,720 --> 00:13:42,280 +هو نفس الناتج لكن دائما لما بتقرأوا التفاعل + +159 +00:13:42,280 --> 00:13:45,840 +هتلاحظوا انه على السهم في عندكم ايش اتش بلس اتش + +160 +00:13:45,840 --> 00:13:50,520 +بلس هذه الاتش بلس عبارة عن catalyst بتسرع ايش + +161 +00:13:50,520 --> 00:13:57,040 +التفاعل بالطريقة اللي حكيناها الان لو بدأنا ناخد + +162 +00:13:57,040 --> 00:14:01,220 +امثلة هاي هذه ال carbon في ال aldehyde موجبة اجت + +163 +00:14:01,220 --> 00:14:07,400 +الميه تهاجمأول الـ Eucalyptus ناخد الميّه الـ C + +164 +00:14:07,400 --> 00:14:13,760 +double bond O شو بتصير؟ OH نحطها بالأخضر و الميّه + +165 +00:14:13,760 --> 00:14:16,280 +هتضيف + +166 +00:14:17,080 --> 00:14:23,100 +OH في النهاية واضح هاي صار عندنا استيظة بال bond O + +167 +00:14:23,100 --> 00:14:27,960 +صارت OH والمية كان يوكليوفال بتضيف OH الان هنا + +168 +00:14:27,960 --> 00:14:34,580 +اتكون عندى مركب على نفس ذرة الكربون تبعته كام OH؟ + +169 +00:14:34,580 --> 00:14:40,480 +تلتين هذه المركبات اللى على نفس ذرة الكربون فيها + +170 +00:14:40,480 --> 00:14:47,840 +تلتين OH بنعطيها اسم hydratesواضح فال hydrate لو + +171 +00:14:47,840 --> 00:14:52,800 +قلتلكوا ارسمولي شكل عام لل hydrate معنى ذلك تحطوا + +172 +00:14:52,800 --> 00:14:59,420 +carbon على نفس ال carbon تنتين O H's يمكن انتوا + +173 +00:14:59,420 --> 00:15:05,340 +سابقا مر عليكم انه يكون عندى في المركب تنتين O H's + +174 +00:15:05,340 --> 00:15:12,440 +على ذرات متجاورة زي هيك هذا المركب لما انا كنت + +175 +00:15:12,440 --> 00:15:20,400 +اسميهماذا كنت أسميه؟ داي أول داي أول و لأنه + +176 +00:15:20,400 --> 00:15:29,620 +كربونتين اثان داي أولواضح إيثان دايول على نمرة + +177 +00:15:29,620 --> 00:15:32,360 +واحد وعن نمرة اتنين ممكن تكتبوا one two إيثان + +178 +00:15:32,360 --> 00:15:37,980 +دايول تمام لكن لما يكونوا مجموعتين ال OH على نفس + +179 +00:15:37,980 --> 00:15:41,860 +ال carbon بنسمي عائلة جديدة هذه العائلة إيش + +180 +00:15:41,860 --> 00:15:47,620 +بنسميها hydrate الان المركب نفسه بنسميه نسبة ال + +181 +00:15:47,620 --> 00:15:51,140 +aldehyde الأصلي يعني هذا ال aldehyde الأصلي الآن + +182 +00:15:51,140 --> 00:15:55,620 +formaldehydeبتذكروا لما قلنا ال formaldehyde غاز + +183 +00:15:55,620 --> 00:16:00,400 +ملدوبه في الميه عملية اذابته في الميه هي ان الميه + +184 +00:16:00,400 --> 00:16:04,880 +تتفاعل عليه تعمل هان OH و تخلص سيضا من البند OH + +185 +00:16:04,880 --> 00:16:11,560 +هذا ال formaldehyde هيدريت طب لو كان acetaldehyde + +186 +00:16:11,560 --> 00:16:16,700 +واحدة من دول ال حزب ده تصير CH3 و هكذا الان لاحظوا + +187 +00:16:16,700 --> 00:16:22,380 +معي ان ال hydrate تفاعل تكوينه متفاعل ايش + +188 +00:16:23,760 --> 00:16:28,200 +Equilibrium reaction يعني لا يتم بشكل كامل بيكون + +189 +00:16:28,200 --> 00:16:34,020 +موجود ال الديهيد مع الميه مع الهيدرين بنسبة معينة + +190 +00:16:34,020 --> 00:16:40,200 +الان في حالة ال formaldehyde بيصل لإن هذا يتفاعل + +191 +00:16:40,200 --> 00:16:45,550 +بنسبة 37% عشان ايه بيصير لكم الفورمالينهو نفس الـ + +192 +00:16:45,550 --> 00:16:48,910 +Formal Dehydrate الـ Formalin اللي أخدنا بنستعمله + +193 +00:16:48,910 --> 00:16:53,390 +لحفظ الأنسجة وغيرها هو نفسه ال Formal Dehydrate + +194 +00:16:53,390 --> 00:16:56,730 +اللي هو ال Formal Dehydrate اتدوب في الميه عمل هذا + +195 +00:16:56,730 --> 00:17:01,790 +الشكل ال Formalin واضح الفكرة؟ وهذا التفاعل زي ما + +196 +00:17:01,790 --> 00:17:07,950 +قلنا عنه تفاعل عكسي الآن هل يترا في كل ال ال + +197 +00:17:07,950 --> 00:17:12,300 +Dehydrates و ال Ketones ممكن يتكون هيدريتز؟من + +198 +00:17:12,300 --> 00:17:17,260 +ناحية نظرية بالورقة والقلم اه يعني انا بقدر + +199 +00:17:17,260 --> 00:17:21,260 +اقولكوا اي aldehyde في الدنيا ارسموله hydrate + +200 +00:17:21,260 --> 00:17:26,620 +الاصل انكم تعرفوا تعملوا hydrate له مثلا لو اجاكم + +201 +00:17:26,620 --> 00:17:32,020 +في الامتحان ارسمولنا benz aldehyde hydrate المنطلق + +202 +00:17:32,020 --> 00:17:38,630 +تبعكم لازم تكونوا عارفين ال benz aldehydeهي ال + +203 +00:17:38,630 --> 00:17:44,210 +benz aldehyde C double bond O H الان احنا اتفقنا + +204 +00:17:44,210 --> 00:17:49,230 +لما بدى يعمل hydrate هدول المجمعتين مافيش فيهم + +205 +00:17:49,230 --> 00:17:56,450 +تغيير طب ها شو بدى يصير ال C double bond O بتصير O + +206 +00:17:56,450 --> 00:18:05,030 +H والمية بتضيف O H هذا بتصير benz aldehyde hydrate + +207 +00:18:05,890 --> 00:18:11,750 +و هكذا يعني بنفس هذه الطريقة ممكن نرسم لأي ألديهيد + +208 +00:18:11,750 --> 00:18:15,850 +أو كيتون هيدريت لو قولنا أسيتون هيدريت أسيتالديهيد + +209 +00:18:15,850 --> 00:18:21,210 +هيدريت لكن الحقيقة معظم الهيدريت بشكل عام they are + +210 +00:18:21,210 --> 00:18:26,930 +unstable يعني في حالة الإتزان اللي بيوجد بشكل أكبر + +211 +00:18:26,930 --> 00:18:33,280 +كتير جدا هو الألديهيدو لذلك هذا التفاعل بيصير نوعا + +212 +00:18:33,280 --> 00:18:37,200 +ما تفاعل نظري مش تفاعل عملي يعني بيكون هذا ال + +213 +00:18:37,200 --> 00:18:42,160 +الديهيد او ال ketone موجود بالنسبة 99.9% و هذا + +214 +00:18:42,160 --> 00:18:46,780 +موجود بالنسبة قليلة جدا و لذلك معظم ال الديهيد و + +215 +00:18:46,780 --> 00:18:50,820 +ال ketones بيكون ال position of equilibrium اتجاه + +216 +00:18:50,820 --> 00:18:54,580 +الاتزان فيها هل هو باتجاه ال hydrate و لا باتجاه + +217 +00:18:54,580 --> 00:18:56,040 +ال الديهيد او ال ketone + +218 +00:18:58,860 --> 00:19:04,840 +واضح الفكرة؟ لكن نظريا كل شيء له hydrate الان مثلا + +219 +00:19:04,840 --> 00:19:10,420 +هذا المركب تطلع عليه carbon حملة تين و H إذا هذا + +220 +00:19:10,420 --> 00:19:15,120 +hydrate ولا لأ؟ Hydrate طب الآن لو قلت لواحدة + +221 +00:19:15,120 --> 00:19:22,520 +فيكوا هذا ال hydrate من أي الديهيد جاي كيف + +222 +00:19:22,520 --> 00:19:28,900 +بدى تعمل؟ بدى تخلي الرابطتين اللي موجودات ال Hو ال + +223 +00:19:28,900 --> 00:19:34,800 +C اللي حاملة تلاتة كلور يعني CCLCLCL و تحط هنا + +224 +00:19:34,800 --> 00:19:41,420 +double bond O هذا مركب موازل ال acetaldehyde لكن + +225 +00:19:41,420 --> 00:19:46,160 +ابدلت تلت ذرات الهيدروجين فيه بكلور فبصير اسمه ايش + +226 +00:19:46,160 --> 00:19:53,340 +اكلورال اكلورال لما اعمل من ال اكلورال هيدريت + +227 +00:19:53,340 --> 00:20:01,450 +باضافة الميهبيصير ايش اسمه اكلورال هايدريت فانا ال + +228 +00:20:01,450 --> 00:20:05,770 +الديهايدي اللي عندي اكلورال لما اعمله اضافة ميه + +229 +00:20:05,770 --> 00:20:10,950 +بيصير اكلورال هايدريت واضح لما اعمله اضافة ميه + +230 +00:20:10,950 --> 00:20:15,530 +بيصير اكلورال هايدريت هذا ال اكلورال هايدريت مادة + +231 +00:20:15,530 --> 00:20:19,650 +تستعمل في التخدير و عادة في التخدير في الطب + +232 +00:20:19,650 --> 00:20:24,090 +البيطري يعني لما يعملوا عمليات جراحية للحيوانات + +233 +00:20:24,090 --> 00:20:28,860 +الكبيرة الضخمةبيعطوها chloral hydrate كمخدر فيلو + +234 +00:20:28,860 --> 00:20:36,660 +ما إلى ذلك واضح؟ فهذا بالنسبة لل hydrate الأن كتير + +235 +00:20:36,660 --> 00:20:40,160 +مرات بنيجي بنقول للطالب في الامتحان النهار or some + +236 +00:20:40,160 --> 00:20:44,420 +general structure of hydrate بشكل عام شو بده يحط + +237 +00:20:44,420 --> 00:20:53,080 +الليه؟ carbon حاملة تنتلؤ أدشز واضح؟طيب لو اتينا ل + +238 +00:20:53,080 --> 00:20:59,680 +ال alcohol كيف بتتفاعل برضه إضافة الآن على طول + +239 +00:20:59,680 --> 00:21:05,140 +السيباب البندقوس شو هتصير OH و ال nucleophile اللي + +240 +00:21:05,140 --> 00:21:12,520 +هيهاجم OR لاحظوا هنا صار عندى ذرة carbon بتحمل مش + +241 +00:21:12,520 --> 00:21:21,470 +تنتين OHOH و OR يعني كأن هذا المركب هو عبارة عن + +242 +00:21:21,470 --> 00:21:28,230 +كحول و إيثر بنفس الوقت كاربون بتحمل OH هذا ألكوهول + +243 +00:21:28,960 --> 00:21:36,180 +و carbon OR هذا ether واضح فهذا المركب كأنه كحول و + +244 +00:21:36,180 --> 00:21:40,680 +ether و هذه العملية إضافة ليش إضافة هذه العملية + +245 +00:21:40,680 --> 00:21:44,200 +لأن ال double bond صارت single bond هذه الإضافة + +246 +00:21:44,200 --> 00:21:47,900 +ببساطة ال double bond single bond إضافة خلصنا الآن + +247 +00:21:47,900 --> 00:21:53,240 +هذا اللي فيه ال carbon بتحمل OH و OR بنسميه + +248 +00:21:53,240 --> 00:22:00,690 +hemiacetalيعني إيش؟ نص أسيتال مش أسيتال كامل، الآن + +249 +00:22:00,690 --> 00:22:06,190 +لما أي شغل نقول هذا نص أسيتال حيصير التفكير عندكم + +250 +00:22:06,190 --> 00:22:12,030 +طب هو إيش الأسيتال؟ الكامل، إذا في بالدنيا نص + +251 +00:22:12,030 --> 00:22:17,430 +أسيتال، إذا أكيد في الدنيا في إيش؟ أسيتال كامل، + +252 +00:22:17,430 --> 00:22:21,750 +hemacetal نص أسيتال، طب وإيش الأسيتال الكامل؟ + +253 +00:22:24,180 --> 00:22:32,080 +إتنين إيثر لو هذا المركب نفسه الـ hemacetal فعلناه + +254 +00:22:32,080 --> 00:22:37,480 +مع زيادة من الكحول فعلناه مع زيادة من الكحول الآن + +255 +00:22:37,480 --> 00:22:41,960 +مرة تانية بيجي الكحول في هذه الحالة بيعمل تفاعل + +256 +00:22:41,960 --> 00:22:46,800 +تاني بيهاجم على الكربون الموجبة وبيطرد الـ OH الآن + +257 +00:22:46,800 --> 00:22:51,180 +هذا التفاعل مجموعة داخلة مجموعة طالعة شو بنسمي + +258 +00:22:51,180 --> 00:22:51,920 +احنا substitution + +259 +00:22:55,450 --> 00:22:58,630 +substitution هذا التفاعل double bond صارت single + +260 +00:22:58,630 --> 00:23:04,590 +bond شو كنا مسمينه addition الان بدلنا ال OH ب OR + +261 +00:23:04,590 --> 00:23:11,090 +شو صار موجود عندك على الكربون تنتين + +262 +00:23:11,090 --> 00:23:18,370 +OR داي إيثر هذا الأسيتال الكامل واضح هذا هو + +263 +00:23:18,370 --> 00:23:25,730 +الأسيتال الكامل اللي هو كربون بتحملTentenor و + +264 +00:23:25,730 --> 00:23:31,770 +التفاعل لتكوين الاسيتال يتم من خلال الهيمياسيتال + +265 +00:23:31,770 --> 00:23:36,870 +مع مزيد من الكحول فالتفاعل في هذه الحالة + +266 +00:23:36,870 --> 00:23:41,850 +substitution لاحظوا انا الان كم عائلة جديدة اتعرفت + +267 +00:23:41,850 --> 00:23:47,490 +عليها خدوهم بالتدريج Carbon Carbon Carbon Carbon + +268 +00:23:47,490 --> 00:23:48,990 +حاملة Tentenor + +269 +00:23:51,050 --> 00:23:57,350 +أه carbon حاملة OH و OR همي أسيتال carbon حاملة OR + +270 +00:23:57,350 --> 00:24:06,530 +و OR أسيتال شفتم كيف بالمقارنة hydrate أسيتال وهذا + +271 +00:24:06,530 --> 00:24:12,720 +اللي بين بينهيمي أسيتال هيدريت وهذا أسيتال وهذا + +272 +00:24:12,720 --> 00:24:18,320 +هيمي أسيتال الآن لو أجينا نسألكم الهيدريت كيف + +273 +00:24:18,320 --> 00:24:25,440 +بيتكون من إضافة الماء على ال الديهيد أو الكيتون + +274 +00:24:25,440 --> 00:24:29,300 +لحظوا الكلمات اللي باستعملها لما نفجر نسأل هيدريت + +275 +00:24:29,300 --> 00:24:30,260 +هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت + +276 +00:24:30,260 --> 00:24:31,960 +هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت + +277 +00:24:31,960 --> 00:24:32,140 +هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت + +278 +00:24:32,140 --> 00:24:34,240 +هيدريت هيدريت هيدريت هيدريت هيدby addition + +279 +00:24:34,240 --> 00:24:40,000 +reaction الـ hemacetal is formed also by addition + +280 +00:24:40,000 --> 00:24:43,760 +reaction على ال الديهيد والكيتون ال acetal + +281 +00:24:43,760 --> 00:24:51,340 +substitution reaction على ال hemacetal واضح ال + +282 +00:24:51,340 --> 00:24:55,480 +acetal هو عبارة عن عملية إبدال ال OH اللي موجودة + +283 +00:24:55,480 --> 00:25:00,120 +في ال hemacetal واضح هذه التفاعلات والعائلات + +284 +00:25:00,120 --> 00:25:01,740 +الجديدة والمسميات + +285 +00:25:07,510 --> 00:25:14,790 +الان هذا الحقيقة تفاعل الاسيتال والهيمياسيتال + +286 +00:25:14,790 --> 00:25:22,070 +تفاعل مهم جدا ممكن ايضا طالما المكونات تبعته كحول + +287 +00:25:22,070 --> 00:25:27,670 +بيهاجم على ايش الديهايد او كيتون الان لو انا + +288 +00:25:27,670 --> 00:25:31,150 +اتخيلت هي الديهايد او كيتون كحول هاجم عليه شو + +289 +00:25:31,150 --> 00:25:36,710 +الناتج؟Hemiacetal طيب السؤال لو ال الديهايد و ال + +290 +00:25:36,710 --> 00:25:40,930 +alcohol بنفس الجزئ يعني تخيلنا هيك جزئ سلسلة على + +291 +00:25:40,930 --> 00:25:46,330 +أحد أطرافها الديهايد و على الطرف التاني OH و إجت + +292 +00:25:46,330 --> 00:25:52,170 +فاعل هذه هاجمتها و السيطة بالبندق شو صارت OH هذا + +293 +00:25:52,170 --> 00:25:56,370 +التفاعل بنسميه Intermolecular ولا Intramolecular + +294 +00:25:57,570 --> 00:26:00,950 +Intramolecular شو يعني Intramolecular تفاعل بين + +295 +00:26:00,950 --> 00:26:06,430 +جزئين مفصولين تماما هذا جزء و هذا جزء جاء الجزئين + +296 +00:26:06,430 --> 00:26:10,150 +المفصولين تماما يتفاعلوا مع بعض هذا Intermolecular + +297 +00:26:10,150 --> 00:26:15,510 +بين جزئين مفصولين الان لو هذا الجزء و هذا الجزء + +298 +00:26:15,510 --> 00:26:21,430 +ممسكين بنفس السلسلة زي هذا المثال لاحظوا هذه سلسلة + +299 +00:26:21,430 --> 00:26:28,570 +واضح على أحد أطرافهاالديهايد وعلى الطرف الثاني + +300 +00:26:28,570 --> 00:26:32,790 +كحول فالجزئين اللي بدهم يتفاعلوا موجودين بنفس + +301 +00:26:32,790 --> 00:26:36,830 +المركب مش بمركبين مختلفين في هذه الحالة إذا + +302 +00:26:36,830 --> 00:26:40,730 +الجزئين اللي بتفاعلوا بنفس المركب على طول التفاعل + +303 +00:26:40,730 --> 00:26:47,380 +إيش أنا بأوصفه Intramolecular reactionفالـ + +304 +00:26:47,380 --> 00:26:51,120 +Intramolecular معناه ذلك أن الجزئين اللي بتفعلوا + +305 +00:26:51,120 --> 00:26:55,860 +بنفس الجزئ لكن الـ Intermolecular لأ جزئين مفصلين + +306 +00:26:55,860 --> 00:27:00,780 +و بيجوا يتفعلوا مع بعض واضح؟ هذا الأمر موجود كتير + +307 +00:27:00,780 --> 00:27:05,620 +الآن خلّيت الكحول و الالدهايد بنفس الجزئ التفاعل + +308 +00:27:05,620 --> 00:27:10,540 +أكيد إضافة الكحول بده يهاجم هنا و هاد السيطة بالـ + +309 +00:27:10,540 --> 00:27:16,270 +Bond O شو بده تصيرOH احنا قلنا في كل الأحوال دائما + +310 +00:27:16,270 --> 00:27:20,310 +ال C double bond O بتصير OH يمكن في كل الأمثلة + +311 +00:27:20,310 --> 00:27:25,690 +السابقة رسمناها بالأخضر و ال nucleophile هاجم بهذا + +312 +00:27:25,690 --> 00:27:32,110 +الشكل الآن هذا المركب اللي متكون عنده أيضا + +313 +00:27:32,110 --> 00:27:37,370 +hemacetal ولا لأ؟ أكيد لأن high carbon حاملة OH + +314 +00:27:41,220 --> 00:27:45,560 +هذا Hemacetal لكن التفاعل بهذه الحالة + +315 +00:27:45,560 --> 00:27:52,000 +Intramolecular reaction الان هذا التفاعل جزء من + +316 +00:27:52,000 --> 00:27:58,390 +أهميته انه في ال biochemistryإذا عندكم فكرة خفيفة + +317 +00:27:58,390 --> 00:28:03,190 +أو هيمر عليكم لما بناخد السكريات ال sugars احنا + +318 +00:28:03,190 --> 00:28:08,150 +قولنا ال sugars they are polyhydroxy aldehydes او + +319 +00:28:08,150 --> 00:28:12,890 +كيتون هى عبارة عن الديهيد او كيتون مع مجموعات + +320 +00:28:12,890 --> 00:28:17,510 +اوقاتش كبيرة الديهيد لحاله بيعملش sugar ومجموعات + +321 +00:28:17,510 --> 00:28:21,490 +اوقاتش كتيرة لحالها بتعملش ايش sugar فال sugar + +322 +00:28:21,490 --> 00:28:26,130 +عبارة عن ايشموجود فيه يا الديهايد يا كيتون + +323 +00:28:26,130 --> 00:28:31,290 +ومجموعات OH's الآن طالما وجد فيه على جهة معينة + +324 +00:28:31,290 --> 00:28:34,950 +الديهايد او كيتون هي C double bond او نتخيل هيك وع + +325 +00:28:34,950 --> 00:28:40,980 +الجهة التانيةأو أتشز ممكن هذه ال أو أتشز تسكر على + +326 +00:28:40,980 --> 00:28:45,600 +ال الديهايد أو ال كيتون أكيد بتعمل في هذه الحالة + +327 +00:28:45,600 --> 00:28:49,520 +hemeacetal بس لما تسكر بدل ما ال sugar كان عامل + +328 +00:28:49,520 --> 00:28:54,480 +سلسلة بهذا الشكل ال chain بيصير إيش in the cyclic + +329 +00:28:54,480 --> 00:28:58,440 +form كل كمار عليكوا أن السكر بيكون في ال chain + +330 +00:28:58,440 --> 00:29:06,430 +formكسلسلة و بيكون بـ Cyclic Form كحلقة الآن عملية + +331 +00:29:06,430 --> 00:29:12,090 +إغلاق السكر هي عملية تفاعل Hemacetal Formation + +332 +00:29:12,090 --> 00:29:17,890 +Hemacetal Formation هاي السكر اللي مسكر الجلوكوز + +333 +00:29:17,890 --> 00:29:22,650 +هذا منظر الجلوكوز اللي مسكر لاحظوا هذه ال carbon + +334 +00:29:22,650 --> 00:29:32,570 +تحديدا اللي هنا هي فيها OHو OR اللى هو alcohol و + +335 +00:29:32,570 --> 00:29:36,910 +ether طب لو قولنا لأى حد اذكرنا كيف هذه كانت قبل + +336 +00:29:36,910 --> 00:29:43,250 +التفاعل قبل ما يسكر كانت هذه C double bond O وكانت + +337 +00:29:43,250 --> 00:29:52,240 +هذه OH وماكنش فيه رابطةكانت هذه C double bond O L + +338 +00:29:52,240 --> 00:29:57,780 +D I و هذه O H فهذه ال O H سكرت هنا و C double bond + +339 +00:29:57,780 --> 00:30:05,240 +O صارتOH بهذا الشكل فلو اجينا سألناكوا سؤال + +340 +00:30:05,240 --> 00:30:10,260 +وقلنالكم cyclic glucose انتبهوا معايا هاي ال + +341 +00:30:10,260 --> 00:30:14,480 +glucose اللي مسكرة تكونوا فاهمين العائلات كويسة + +342 +00:30:14,480 --> 00:30:20,420 +cyclic glucose is a hydrate يعني في تنتين OH على + +343 +00:30:20,420 --> 00:30:21,140 +الكربون + +344 +00:30:25,890 --> 00:30:30,950 +cyclic glucose is a hydrate no cyclic glucose is + +345 +00:30:30,950 --> 00:30:38,450 +an acetal في تنتين OR برضه false cyclic glucose is + +346 +00:30:38,450 --> 00:30:48,340 +a hemacetal في OH و OR واضحة الفكرةالان ممكن نسأل + +347 +00:30:48,340 --> 00:30:54,180 +السؤال بطريقة تانية Cyclic glucose is formed by a + +348 +00:30:54,180 --> 00:30:55,960 +substitution reaction + +349 +00:30:58,930 --> 00:31:03,610 +by an addition reaction شوف كيف اللي بيفهم شغلة + +350 +00:31:03,610 --> 00:31:07,770 +بيحس انه ممكن نسأل عن الشغلة بقالف طريق أنا مش + +351 +00:31:07,770 --> 00:31:10,610 +الفكرة ان اخوفكم من الأسئلة و الانتحانات بقدر ما + +352 +00:31:10,610 --> 00:31:16,130 +اني بركز المعلومة عندكم ان هذه فعلا كانت C double + +353 +00:31:16,130 --> 00:31:20,430 +bond O و هذه فعلا كانت OH هذا alcohol و هذا + +354 +00:31:20,430 --> 00:31:23,750 +aldehyde الآن ال alcohol و ال aldehyde بيتفاعلوا + +355 +00:31:23,750 --> 00:31:31,560 +تفاعل ايش اضافة بكونه hemiacetalواضح؟ الآن بعد ما + +356 +00:31:31,560 --> 00:31:37,160 +اتكون الـ hemacetal هذا وصار هنا في OR و OH ممكن + +357 +00:31:37,160 --> 00:31:44,040 +يصير تفاعل تاني تبدل في ال OH ل OR مع كحول تاني + +358 +00:31:44,040 --> 00:31:48,260 +خارجي يعني افترضوا ناس جابوا ميثانول وفعلوا مع هذا + +359 +00:31:48,260 --> 00:31:55,530 +شو هيعمل الميثانول؟هيشيل ال OH يخليها OR صار عندكم + +360 +00:31:55,530 --> 00:32:01,890 +OR OR أسيتال بس ب substitution reaction تاني واضح + +361 +00:32:01,890 --> 00:32:06,350 +انما ال cyclic glucose في نص الطريق هو عبارة عن + +362 +00:32:06,350 --> 00:32:11,500 +ايش؟Hemiacetal Cyclic Glucose is Hemiacetal ممكن + +363 +00:32:11,500 --> 00:32:15,920 +تحويله ل Acetal بالتفاعل مع الكحول أكيد لأن احنا + +364 +00:32:15,920 --> 00:32:20,820 +قلنا التفاعل ع مرحلتين إضافة ثم إبدال أنا لما وصلت + +365 +00:32:20,820 --> 00:32:24,900 +ل Hemacetal عملت الإضافة الآن إذا الإنسان بيجيب + +366 +00:32:24,900 --> 00:32:30,860 +كحول و حامض و بيسخنه ممكن يعمل إيش الإبدال و يحوله + +367 +00:32:30,860 --> 00:32:37,360 +إلى Acetal كاملهنا في عندى على هذه النقطة كمان + +368 +00:32:37,360 --> 00:32:46,320 +مثال جميل انه انا جبت ال Acetone كيتون مع Ethylene + +369 +00:32:46,320 --> 00:32:51,740 +Glycol او اللى سميناه Ethanediol هذا المركب كام OH + +370 +00:32:51,740 --> 00:32:58,200 +فيهTintin يعني كأنه هذا Dialcohol الان لما فعلنا + +371 +00:32:58,200 --> 00:33:03,200 +اعطانا هذا المركب المغلق يمكن واحدة تقول طب كيف تم + +372 +00:33:03,200 --> 00:33:08,600 +هذا التفاعل؟ بنقول بهدوء ممكن نفهم كيف تم الان + +373 +00:33:08,600 --> 00:33:13,540 +نتعامل مع هذا كيتون و مع هذا الكهول كيف الكهول + +374 +00:33:13,540 --> 00:33:17,700 +بتفاعل على الكيتون او على الديهايد بال addition + +375 +00:33:17,700 --> 00:33:24,310 +هذه بتيجي تضيف هنا و هذه بتصيرOH إذا لو قلنا شو + +376 +00:33:24,310 --> 00:33:32,770 +الناتج اللي في هذه الحالة بيصير C OH CH3 CH3 هذا + +377 +00:33:32,770 --> 00:33:37,590 +الجزء اللي كان أسيتون والجزء التاني هو عبارة عن O + +378 +00:33:37,590 --> 00:33:48,890 +CH2 CH2 OH هاي كحول اتفاعل مع كيتون ال C double + +379 +00:33:48,890 --> 00:33:54,500 +bond O صارتOH والكحول اتفاعل هنا الان الكحول نفسه + +380 +00:33:54,500 --> 00:34:00,220 +في داخله OH تاني يعني كأن الكحول كحولين في بعض في + +381 +00:34:00,220 --> 00:34:04,740 +مجموعتين OH هذا المركب اللي هنا carbon حاملة OH و + +382 +00:34:04,740 --> 00:34:10,660 +OR شو عبارة عن ايش Himacetal الان ممكن يعمل كمان + +383 +00:34:10,660 --> 00:34:16,680 +تفاعل ان هذه تهاجم هنا و تحل محل هذه ابدال + +384 +00:34:17,800 --> 00:34:21,920 +و انت بتطلع عندى هذا المركب لحظة هذا المركب carbon + +385 +00:34:21,920 --> 00:34:27,680 +حاملة OR و OR اذا هذا عبارة عن ايش + +386 +00:34:30,910 --> 00:34:36,990 +Hemiacetal لاحظوا هنا اعملت التفاعل على مرتين لكن + +387 +00:34:36,990 --> 00:34:42,970 +مش من كحولين مفصلين لأ الكحولين موجودين بإيش؟ بنفس + +388 +00:34:42,970 --> 00:34:47,330 +الجزء نفس الجزء فيه تن تن و اتش يعني كأنه الجزء زي + +389 +00:34:47,330 --> 00:34:53,410 +ما بيقولوا اليوم في الدعايات إيش؟ two in oneطالما + +390 +00:34:53,410 --> 00:34:58,470 +في اتنين OH اذا صار عبارة عن كحولين في نفس الجزء + +391 +00:34:58,470 --> 00:35:03,710 +طالما مجمعتين OH الكحول OH هذا في OH OH صار كحولين + +392 +00:35:03,710 --> 00:35:09,650 +اتفاعل في المرة الأولى بالاضافة و في المرة الثانية + +393 +00:35:09,650 --> 00:35:15,380 +بالابدالةشوفنا كيف ادول التفاعلين تموا addition + +394 +00:35:15,380 --> 00:35:19,640 +followed by substitution الان هذا المركب اتجه من + +395 +00:35:19,640 --> 00:35:23,360 +الاسيتون و من الاثيلين جليكول عشان يسموه اسيتون + +396 +00:35:23,360 --> 00:35:28,820 +اثيلين جليكول لاحظوا ايش استعمله اسيتال منطق + +397 +00:35:28,820 --> 00:35:32,480 +اسيتال لانه OR و OR اسيتال + +398 +00:35:42,600 --> 00:35:48,900 +الان من التفاعلات انه نستعمل نيكليوفايل مجموعة ال + +399 +00:35:48,900 --> 00:35:52,680 +CNI و بتذكروا احنا لما أخدنا ال CNI تقولنا بتتفاعل + +400 +00:35:52,680 --> 00:35:56,460 +من اي طرف من الكربون ولا من ال نيتروجين من الكربون + +401 +00:35:56,460 --> 00:36:01,200 +كل اللي مطلوب انه ال CN تهاجم هنا و الصيدة بال + +402 +00:36:01,200 --> 00:36:06,580 +bond O تصير OH الان صار عندى عائلة جديدة على + +403 +00:36:06,580 --> 00:36:13,040 +الكربون ايش المجمعتين اللي موجودين CNN و OHو OH + +404 +00:36:13,040 --> 00:36:20,700 +لاحظوا C و تلتين OH هيدريت OH و OR هيمي أسيتال OR + +405 +00:36:20,700 --> 00:36:27,340 +و OR أسيتال الان OH و CNN بسميها سيانو هيدرين + +406 +00:36:27,340 --> 00:36:37,760 +بسميها سيانو هيدرين واضح سيانو هيدرين الان + +407 +00:36:39,440 --> 00:36:43,880 +لو عملنا التفاعل مع الاسيتالديهيد هذا المركب شو + +408 +00:36:43,880 --> 00:36:51,320 +هسميه اسيتالديهيد سيانوهيدرين لو عملت التفاعل مع + +409 +00:36:51,320 --> 00:36:57,100 +الاسيتون هذا المركب ايش هسميه اسيتون هاي جزء + +410 +00:36:57,100 --> 00:37:05,520 +الاسيتون مش الاسيتون عبارة عن CH3CCH3 بدون ال + +411 +00:37:05,520 --> 00:37:10,950 +oxygen اسيتونCyanohedron لو عملتم مع الـ + +412 +00:37:10,950 --> 00:37:16,250 +Cyclohexanone هذي الـ C double bond O إيش هتصير؟ + +413 +00:37:16,250 --> 00:37:21,650 +OH وهي الـ Cl شو هسميه؟ Cyclohexanone + +414 +00:37:21,650 --> 00:37:23,470 +Cyclohexanone Cyclohexanone Cyclohexanone + +415 +00:37:23,470 --> 00:37:23,530 +Cyclohexanone Cyclohexanone Cyclohexanone + +416 +00:37:23,530 --> 00:37:23,810 +Cyclohexanone Cyclohexanone Cyclohexanone + +417 +00:37:23,810 --> 00:37:24,510 +Cyclohexanone Cyclohexanone Cyclohexanone + +418 +00:37:24,510 --> 00:37:26,930 +Cyclohexanone Cyclohexanone Cyclohexanone + +419 +00:37:26,930 --> 00:37:27,010 +Cyclohexanone Cyclohexanone Cyclohexanone + +420 +00:37:27,010 --> 00:37:31,690 +Cyclohexanone + +421 +00:37:31,690 --> 00:37:37,790 +Cyclohexanone Cyclohexanone + +422 +00:37:40,220 --> 00:37:47,620 +الدهايد بنزالدهايد سيانو هيدرل يعني لو قلنا لأي + +423 +00:37:47,620 --> 00:37:53,440 +واحدة أرسمينا بنزالدهايد سيانو هيدرل في الامتحان + +424 +00:37:53,440 --> 00:37:58,360 +بدا تيجي تفكر تتخيل بسهولة ماتاخدش وقت منكوا + +425 +00:37:58,360 --> 00:38:05,530 +ببساطة هاي ال بنزالدهايد صح ولا لألازم في الأصل + +426 +00:38:05,530 --> 00:38:09,390 +تكون عارفة الـ Benzaldehyde مجرد ما نقولها سيانو + +427 +00:38:09,390 --> 00:38:17,490 +هيدرين الـ C بابل بوند O OH OHIJNQCN مش عملية صعبة + +428 +00:38:17,490 --> 00:38:23,090 +Benzaldehyde cyanohydrin واضح الفكرة؟ لاحظوا أنا + +429 +00:38:23,090 --> 00:38:27,650 +كاتب له common name نفس + +430 +00:38:27,650 --> 00:38:30,830 +الـ Benzaldehyde cyanohydrin له common name + +431 +00:38:30,830 --> 00:38:33,330 +Manbilonitride + +432 +00:38:34,290 --> 00:38:42,750 +mandilo mandel بالالماني يعني لوز انتوا بتذاكرين + +433 +00:38:42,750 --> 00:38:46,750 +قبل شوية لما أخدنا ال benzaldehyde قولنا oil of + +434 +00:38:46,750 --> 00:38:54,170 +almond اللوز بالانجليزي بالالماني mandel ومن هنا + +435 +00:38:54,170 --> 00:38:58,950 +استعمل mandilo nitral mandel من اللوز يعني كتير من + +436 +00:38:58,950 --> 00:39:04,150 +ال common name علاقة في إيشفي أصل المركب من أي + +437 +00:39:04,150 --> 00:39:08,130 +منطقة نباتية اشتهر ان هذا المركب انفصل + +438 +00:39:08,130 --> 00:39:12,990 +فالمنديلونيترال هو ال benzaldehyde cyanohydrin + +439 +00:39:12,990 --> 00:39:14,370 +واضح الفكرة؟ + +440 +00:39:20,340 --> 00:39:24,120 +اتخيلوا عاد كيف الطالب لما بيبعد عن الكلام احنا + +441 +00:39:24,120 --> 00:39:28,320 +مرة جيبناله سؤال في الامتحان ارسم العائلة العامة و + +442 +00:39:28,320 --> 00:39:33,940 +كتبناله Hydrate, Hemacetal, Acetal وCyanohydrin + +443 +00:39:33,940 --> 00:39:37,420 +انا بدي احط هدوله و هنا يعمل شرط اما يكتبليش اشي + +444 +00:39:37,420 --> 00:39:42,240 +يعني في مجبوعتين صعبة ولا سهلة؟ سهلة جدا .. سهلة + +445 +00:39:42,240 --> 00:39:45,020 +جدا .. الآن + +446 +00:39:46,660 --> 00:39:53,640 +بنجي لنيكليوفايل جديد هذا النيكليوفايل الجديد هو H + +447 +00:39:53,640 --> 00:40:01,080 +- متذكرين انتوا انه احنا لما حكينا عن الهيدروجين، + +448 +00:40:01,080 --> 00:40:07,580 +قولنا الهيدروجين بيدا تمر علينا بكم شكل؟ تلت أشكال + +449 +00:40:07,580 --> 00:40:10,700 +H plus وH + +450 +00:40:14,320 --> 00:40:19,580 +و أعطناهم أسماء الـ H بلس شو قلنا عنها البروتون + +451 +00:40:19,580 --> 00:40:25,480 +اللي بيفقد الحامض و الـ H هيدروجين أتم الـ H minus + +452 +00:40:25,480 --> 00:40:30,880 +هيدرايد أنيون الان مين في هدولة التلاتة + +453 +00:40:30,880 --> 00:40:38,080 +نيوكليوفاين الهيدرايد أنيون طيب انتهت الكلام طالما + +454 +00:40:38,080 --> 00:40:44,480 +الهيدرايد أنيوناليوكليوفايل لو أخدت الديهيد زي هذا + +455 +00:40:44,480 --> 00:40:48,040 +خلّيني أقول ال Acetaldehyde وهي ال H وحملة ال + +456 +00:40:48,040 --> 00:40:52,860 +minus وقلتلكوا أكمل المعادلة ال hydride بدو يتفعل + +457 +00:40:52,860 --> 00:40:59,320 +مع هذا شو هيعمل ال C double bond O هتصير O H هي + +458 +00:40:59,320 --> 00:41:03,480 +باللون الأخضر واليوكليوفايل بهذه الحالة هو عبارة + +459 +00:41:03,480 --> 00:41:12,270 +عن إيش ال Hما العائلة الجديدة اللتي تكونت هنا؟كحول + +460 +00:41:12,270 --> 00:41:17,650 +هذه عملية الاختزال الار بيصير السؤال هو بالدنيا + +461 +00:41:17,650 --> 00:41:23,870 +بينباع H- لحاله؟ لأ بينباع على شكل المراكبات + +462 +00:41:23,870 --> 00:41:29,970 +المراكبات اللي بتكون مصدر للhydride anion موجود + +463 +00:41:29,970 --> 00:41:33,930 +منها وتستعمل كعوامل مختزلة لحظوا هذه العملية + +464 +00:41:33,930 --> 00:41:38,410 +اختزال لأن C double bond O صارت OH واحدة نقص في + +465 +00:41:38,410 --> 00:41:44,610 +محتوىالأكسوجين وزيادة في محتوى الهيدروجين أنا زيدت + +466 +00:41:44,610 --> 00:41:49,430 +هنا H وزيدت هنا H هايهم تنتين هذا الاختزال بعينه + +467 +00:41:49,430 --> 00:41:54,690 +مظبوط ولا لأ الآن العوامل المختزلة عادة بتكون + +468 +00:41:54,690 --> 00:41:58,410 +هيدرايد أو ممكن الإنسان يعملها بإضافة الهيدروجين + +469 +00:41:58,410 --> 00:42:02,120 +هنا إحنا إيش اللي بنستعمله الهيدرايدلحظوا من + +470 +00:42:02,120 --> 00:42:06,320 +الهيدرايتز اللي مشهورة جدا هذا المركّب الليثيام + +471 +00:42:06,320 --> 00:42:12,340 +والألمنيوم اللي متصل ب 4H- لحظوا الألمنيوم بوضعه + +472 +00:42:12,340 --> 00:42:18,880 +الطبيعي بيكون ايش تلاتة موجة حطوا عليه 4H- كل ال + +473 +00:42:18,880 --> 00:42:23,920 +ايون شو هيصفاه minus عشان يطلع الجزية متعادلة + +474 +00:42:23,920 --> 00:42:31,420 +بحطله lithium plusهذا بيصير Lithium Tetrahydride + +475 +00:42:31,420 --> 00:42:39,180 +Aluminate طبعا الات هي نهاية إيش؟ الايون السالب مش + +476 +00:42:39,180 --> 00:42:43,440 +أخدنا احنا الايونات السالبة سولفات، كربونات، + +477 +00:42:43,440 --> 00:42:50,230 +نيترات، أسيتات، الآن هنا قولنا إيش؟ Aluminateكل + +478 +00:42:50,230 --> 00:42:57,290 +عمره بنقول سلفيت SO4 minus minus نيتريت NO3 minus + +479 +00:42:57,290 --> 00:43:03,170 +فال eight نهاية ال ايش ال ايون السالب الان هذا + +480 +00:43:03,170 --> 00:43:07,050 +الجزء متعادل لان عندي ليثيام plus والالمنيوم تلاتة + +481 +00:43:07,050 --> 00:43:12,770 +plus هاي أربعة موجب وال H أربعة minus صف الجزء كله + +482 +00:43:12,770 --> 00:43:18,190 +ايش ليثيام تترا هيدرايدو ألمينيت أو هذا من البورون + +483 +00:43:18,950 --> 00:43:26,130 +Sodium Tetrahydride من البرون بوريت مش من البروم + +484 +00:43:26,130 --> 00:43:31,350 +البرون لما تمشوا في أول الجدول الدوري العنصر + +485 +00:43:31,350 --> 00:43:35,890 +الخامس يعني تطلعوا على عناصر الجدول الدوري H بعدين + +486 +00:43:35,890 --> 00:43:41,590 +helium بعدين lithium بعدين beryllium بعدين boron + +487 +00:43:41,590 --> 00:43:48,520 +واضح؟ اه ال boronSodium tetrahydride borate الان + +488 +00:43:48,520 --> 00:43:52,160 +هذول الحقيقة بياخدوا كمان اسماء تانية لو سمعتهم + +489 +00:43:52,160 --> 00:43:55,700 +بأي اسمين هذول من أشهر العوامل المختز ل ال + +490 +00:43:55,700 --> 00:44:02,140 +hydrides هم ببساطة مصدر ل إيش ل H minus يعني احنا + +491 +00:44:02,140 --> 00:44:06,840 +بنفهمه مصدر ل H minus هذا بيسموه ال lithium + +492 +00:44:06,840 --> 00:44:13,460 +tetrahydride aluminate بيسموه lithium aluminum + +493 +00:44:13,460 --> 00:44:20,740 +hydrideالومينوم هايدرايد يعني نفسه ممكن تلاقوه تحت + +494 +00:44:20,740 --> 00:44:24,840 +اسم ليثيام ألومينوم هايدرايد أو ليثيام تيترا + +495 +00:44:24,840 --> 00:44:29,260 +هايدرايد و ألومينيت وهذا بيسموه صوديوم بورو + +496 +00:44:29,260 --> 00:44:35,230 +هايدرايد مش بورونBorohydride فإذا سمعتوا Sodium + +497 +00:44:35,230 --> 00:44:38,770 +Borohydride أو Sodium Tetrahydride و Borate نفس + +498 +00:44:38,770 --> 00:44:43,330 +الاسم Lithium Tetrahydride و Aluminate أو Lithium + +499 +00:44:43,330 --> 00:44:47,690 +Aluminum Hydride نفس الاسم و مرات كتير حتى الاسم + +500 +00:44:47,690 --> 00:44:52,530 +هذا Sodium Borohydride و عادة مش هيكونوا عاملينه + +501 +00:44:52,530 --> 00:44:57,310 +زيك هتلاعظوا على السهم مكتوب عندكم NABH4 + +502 +00:44:58,940 --> 00:45:05,980 +وهنا هتلاحظوا Lithium Aluminum H4 اذا شفتوا هذا او + +503 +00:45:05,980 --> 00:45:09,780 +هذا هذا Sodium Borohydride Lithium Aluminum + +504 +00:45:09,780 --> 00:45:16,560 +Hydride شوفوا مثلها Sodium Borohydride Lithium + +505 +00:45:16,560 --> 00:45:21,220 +Aluminum Hydride هدوله الشرعوه المختزلة هم في + +506 +00:45:21,220 --> 00:45:27,990 +النهاية مصدر لإيش؟لل H- الان ال H- لما هاجم على ال + +507 +00:45:27,990 --> 00:45:34,850 +aldehyde عملوا ايش؟ كحول وهذه عملية الاختزال عكس + +508 +00:45:34,850 --> 00:45:40,150 +عملية ايش؟ الاكسادة هذه عملية الاختزال عكس عملية + +509 +00:45:40,150 --> 00:45:47,190 +الاكسادة هي reducing agents طبعا لو ال H- هاجم على + +510 +00:45:47,190 --> 00:45:53,490 +كيتون هيعملوا ايش؟secondary alcohol اذا انتبهوا + +511 +00:45:53,490 --> 00:45:59,030 +معي جيدا انه لما الهجوم تم على ال الديهايد عادي + +512 +00:45:59,030 --> 00:46:06,550 +اتكول اه اذا هل جيتها بنصير نكتب reduction عشان + +513 +00:46:06,550 --> 00:46:11,950 +تكون واضحة الأمور معاكم قبل الديهايدs produces + +514 +00:46:11,950 --> 00:46:19,070 +primary alcoholreduction of aldehydes produces + +515 +00:46:19,070 --> 00:46:23,950 +primary alcohols الان تحتها هيصير reduction of + +516 +00:46:23,950 --> 00:46:28,890 +كيتون ايش + +517 +00:46:28,890 --> 00:46:35,050 +produces secondary alcohols هو كل درسنا aldehydes + +518 +00:46:35,050 --> 00:46:40,240 +او كيتون ولا في غيرهم؟أذا بدنا نكون عارفين ان ال + +519 +00:46:40,240 --> 00:46:45,240 +الديهايد لما بنعمله reduction بالهيدرايد بده يصير + +520 +00:46:45,240 --> 00:46:50,080 +عنده primary alcohol و ال ketone لما بنعمله + +521 +00:46:50,080 --> 00:46:54,240 +reduction بال الديهايد بده يصير عنده secondary + +522 +00:46:54,240 --> 00:46:58,940 +alcohol لاحظوا هذا الكلام بفيدكم سواء بجمل صح و + +523 +00:46:58,940 --> 00:47:03,820 +غلط بأكمل معادلة او حتى لو احنا سألناكوا سؤال how + +524 +00:47:03,820 --> 00:47:09,210 +can you prepare the following compoundواضح؟ لما + +525 +00:47:09,210 --> 00:47:12,610 +تشوفوا أن الناتج اللي عندكم primary alcohol إذا + +526 +00:47:12,610 --> 00:47:16,530 +بتقدروا تفكروا أنه ممكن يكون إيجا من وين لما + +527 +00:47:16,530 --> 00:47:19,930 +تشوفوا الناتج اللي عندكم secondary alcohol إذا + +528 +00:47:19,930 --> 00:47:25,430 +ممكن يكون إيجا من وين من كيتون واضح الفكرة؟ بنقف + +529 +00:47:25,430 --> 00:47:29,510 +عند هذه النقطة المرة القادمة إن شاء الله بنحكي عن + +530 +00:47:29,510 --> 00:47:34,690 +تفاعل الديهيدس والكيتون مع متفاعل اسمه green yard + +531 +00:47:34,690 --> 00:47:39,740 +reagent عمرنا حكينا عنه؟بنعرفه المرة الجاية وبنشوف + +532 +00:47:39,740 --> 00:47:44,440 +كيف بتفاعل ال الديهيد والكيتون مع ال green yard + +533 +00:47:44,440 --> 00:47:46,220 +reagent شكرا + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..2d2500e2cf61da81dd0b1492154023e34a6e6059 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_postprocess.srt @@ -0,0 +1,2056 @@ +1 +00:00:20,280 --> 00:00:26,570 +بسم الله الرحمن الرحيمفي موضوع ال alcohols اللى + +2 +00:00:26,570 --> 00:00:29,970 +بدأنا فيه المرة الماضية موضوع ال acidity of + +3 +00:00:29,970 --> 00:00:37,870 +alcohols او حمضية الكحولات هو موضوع مهم جدا الان + +4 +00:00:37,870 --> 00:00:43,130 +يمكن موضوع ال acidity كمان يمر علينا باكثر من موقع + +5 +00:00:43,130 --> 00:00:48,110 +في ال organ chemistry ربما بشكل أساسي في ال + +6 +00:00:48,110 --> 00:00:53,030 +carboxylic acids يمر علينا موضوع ال acidityربما + +7 +00:00:53,030 --> 00:00:57,330 +المشكلة اللى بتتواجهنا أكثر شيء في الموضوع إذا + +8 +00:00:57,330 --> 00:01:02,410 +الطلاب من الأساس .. إذا الطلاب من الأساس ماعندهمش + +9 +00:01:02,410 --> 00:01:08,670 +فكرة صحيحة وسليمة عن إيش معنى الحامضية بناء على + +10 +00:01:08,670 --> 00:01:13,010 +ذلك أي مفهوم متطور في الموضوع بده البني أدم يحكي + +11 +00:01:13,010 --> 00:01:20,150 +فيه بدون وجود الأصل عند الطالب هيكون بيمثلمشكلة + +12 +00:01:20,150 --> 00:01:25,570 +لأنه ماعندوش أصل يبني عليه ولذلك شوية بدأ أتجاوز + +13 +00:01:25,570 --> 00:01:32,170 +هذا ال slide أعطي نوعا ما مقدمة صغيرة تذكيرية في + +14 +00:01:32,170 --> 00:01:37,730 +الجزء المهم بالنسبة لنا في موضوع الحمضية في الجزء + +15 +00:01:37,730 --> 00:01:43,500 +المهم بالنسبة لنا في موضوع الحمضيةالنقطة الأولى + +16 +00:01:43,500 --> 00:01:48,380 +يمكن اللى بتواجهكم في موضوع الأحماض أنه مر عليكم + +17 +00:01:48,380 --> 00:01:55,770 +أكثرمن تعريف مار عليكم أكتر من تعريف للحمض شو هو + +18 +00:01:55,770 --> 00:02:01,510 +الحمض و شو القلوي ربما حسب التدرج اللي اتعلمته في + +19 +00:02:01,510 --> 00:02:05,830 +المدارس أول ما بيمر على الناس ال Arrhenius + +20 +00:02:05,830 --> 00:02:10,250 +definition تعريف Arrhenius للحمض و القلوي خلنا + +21 +00:02:10,250 --> 00:02:16,730 +نشوفه ال Arrhenius definition من خلال مثال + +22 +00:02:17,780 --> 00:02:23,240 +المثال المشهور جدا لو انا كنت باخد ال HCL زائد ال + +23 +00:02:23,240 --> 00:02:31,120 +NAOH و متعودين تكملوا المعادلة NACL + +24 +00:02:31,120 --> 00:02:37,240 +زائدH2O الآن ضمن هذا التعريف كان أرهينياس بيقول + +25 +00:02:37,240 --> 00:02:42,180 +الحامض ببساطة هو المادة اللي بتتأين و بتعطي H plus + +26 +00:02:42,180 --> 00:02:49,000 +والقاعدة هي المادة اللي بتتأين و بتعطي OH minus + +27 +00:02:49,000 --> 00:02:53,820 +واضح؟ هذه أول تعريف، إذا الحامض المادة اللي بتتأين + +28 +00:02:53,820 --> 00:02:57,000 +في الميّه بيبقى تعطيني H plus والقاعدة بيبقى + +29 +00:02:57,000 --> 00:03:04,640 +تعطيني OH minus هذا التعريف تعريف أرهينياسالان اجى + +30 +00:03:04,640 --> 00:03:13,060 +لوري برونستيد نظر للموضوع شوية من زاوية تانية يعني + +31 +00:03:13,060 --> 00:03:17,820 +لاحظوا هنا الحامض ايش بيطلع كل ال HCL القاعدة شو + +32 +00:03:17,820 --> 00:03:25,980 +بتطلع كل ال NaOH اذا خليني اعمل الحامض حسب تعريف + +33 +00:03:25,980 --> 00:03:32,200 +Arrhenius هحوطه بالازرع هي الحامض القاعدةهي + +34 +00:03:32,200 --> 00:03:38,160 +القاعدة الان لوري برونستيد نظر وممكن لنفس المعادلة + +35 +00:03:38,160 --> 00:03:45,060 +نظرة شوية فيها تخصص بمعنى وين المركز الفاعل وين + +36 +00:03:45,060 --> 00:03:50,580 +المركز الفاعل اللي موجود لكن للأسف يمكن نظر + +37 +00:03:50,580 --> 00:03:55,640 +للقاعدة فقط مانظرش للحمض فخلى تعريف الحامض خلى + +38 +00:03:55,640 --> 00:04:03,220 +تعريف الحامض هاي التعريف التاني لوري برونستيدخلّى + +39 +00:04:03,220 --> 00:04:07,960 +تعريف الحامض زى ما هو اللى بيعطى H بلس فى التأيون + +40 +00:04:07,960 --> 00:04:12,440 +واضح فالحامض عند لوري برويستن شو بيعطينى H بلس + +41 +00:04:12,440 --> 00:04:17,600 +وبناء على ذلك وين بده يكون الحمض الـHCl كله عنده + +42 +00:04:17,600 --> 00:04:23,820 +حامضالـ HCl كله عند لوري برونستيد ما زال حامض، + +43 +00:04:23,820 --> 00:04:29,520 +الآن إجا للقاعدة، قال هي القاعدة سرها في الـ NaOH + +44 +00:04:29,520 --> 00:04:33,740 +يعني لو افترضنا أنها كانت KOH مثلا، بوتاسيوم + +45 +00:04:33,740 --> 00:04:37,930 +هيدروكسايدأو كالسيوم هيدروكسايد أو ألمنيوم + +46 +00:04:37,930 --> 00:04:43,670 +هيدروكسايد إفراج كتير؟ لأ إذا سير قوة القاعدة مش + +47 +00:04:43,670 --> 00:04:48,950 +فيها كلها لأ في ال O H و بناء على ذلك خلى القاعدة + +48 +00:04:48,950 --> 00:04:54,910 +هي ال O H minus مش ال N A O H شوفتوا القاعدة إيش + +49 +00:04:54,910 --> 00:05:00,770 +صار فيها؟ اختلفت و قال الحامض بيعطي H plus القاعدة + +50 +00:05:00,770 --> 00:05:07,010 +بتكتسب H plusهذه لما بدأت اكتسب الـ OH-, الـ H بلس + +51 +00:05:07,010 --> 00:05:11,550 +اللي فقدت هنا هي اللي هتعطيني الميه طبعا الايونات + +52 +00:05:11,550 --> 00:05:16,910 +المرافقة بيبقى مرافقة فصار عندي شوية اختلاف في + +53 +00:05:16,910 --> 00:05:25,350 +التعريف صار بيعطي H بلس بيكتسبH plus و بناء على + +54 +00:05:25,350 --> 00:05:31,770 +ذلك سرنا أي مادة .. سرنا أي مادة يمكن أن تكتسب H + +55 +00:05:31,770 --> 00:05:36,930 +plus نقدر نعتبرها قاعدة يعني بطلت القاعدة بس بال O + +56 +00:05:36,930 --> 00:05:41,350 +H بال hydroxides يعني بمعنى لو انا اجيت فعلت مع ال + +57 +00:05:41,350 --> 00:05:44,530 +ammonia ما هي ال ammonia بتكتسب H plus بتعطينا + +58 +00:05:44,530 --> 00:05:49,240 +ايون ال ammonium برضه تعتبر baseفكل ما يكتسب ال H + +59 +00:05:49,240 --> 00:05:54,140 +plus يعتبره قاعدة و كل ما يعطي ال H plus يعتبره + +60 +00:05:54,140 --> 00:06:00,860 +base الان لاحظوا ان هو نظر هنا نظر هنا على ال N E + +61 +00:06:00,860 --> 00:06:04,880 +O H و جال مركز قوتها ايش ال O H ماله و مالي الان + +62 +00:06:04,880 --> 00:06:10,490 +ايه فصارت ال base عنده ال O H او اي شيء يكتسبH + +63 +00:06:10,490 --> 00:06:15,370 +Plus لكن ما إجهاش تطلع هنا بنظرة تفصيلية طب يا + +64 +00:06:15,370 --> 00:06:22,530 +تورا لو كان هذا مش HCL لو كان هذا HPR بيفرق ولا HI + +65 +00:06:22,530 --> 00:06:28,670 +إذا لو أنا بدأ أطلع كمان بنظرة تفصيلية أكتر وين + +66 +00:06:28,670 --> 00:06:34,610 +مركز القوة حقيقة في ال HCL هو ال H Plus وعشان هيك + +67 +00:06:34,610 --> 00:06:41,220 +إجى Lewis في تعريفهزي ما أتيت هنا وأخدت مركز القوة + +68 +00:06:41,220 --> 00:06:44,920 +هذا تعالي ناخد مركز القوة الـ H Plus + +69 +00:06:49,960 --> 00:06:55,420 +الـ OH- فكأنه أخلت من هذا الجزء الأساسي فيه ومن + +70 +00:06:55,420 --> 00:06:59,180 +هذا الجزء الأساسي فيه اللي هي حقيقة الـ net ionic + +71 +00:06:59,180 --> 00:07:02,220 +equation يعني هذه لو عملت لها net ionic equation + +72 +00:07:02,220 --> 00:07:06,120 +الـ Na والـ Cl كلهم من شطبه هي عبارة عن H بلس زائد + +73 +00:07:06,120 --> 00:07:13,860 +OH- بتعطينا H2O وبناء على ذلك ال acid عند Lewis هو + +74 +00:07:13,860 --> 00:07:20,530 +H بلسو الـ base عنده الـ OH- الان نظر طب ايش اللي + +75 +00:07:20,530 --> 00:07:26,290 +بيميز هدوله قال اه هو كل التفاعل انه هذه ال OH- لو + +76 +00:07:26,290 --> 00:07:32,710 +انا اعملتلها توزيع إلكتروني عليها هنا تلت أزواج من + +77 +00:07:32,710 --> 00:07:35,630 +الإلكترونات عشان هيك صارت minus هدفش عليه + +78 +00:07:35,630 --> 00:07:42,560 +إلكترونات هذا موجب و هذهسالبة الموجة بدي تفعل مع + +79 +00:07:42,560 --> 00:07:46,920 +السالب هذا بدي يعطي إلكترونات هنا وبناء على ذلك + +80 +00:07:46,920 --> 00:07:52,860 +جانب ال acid electron acceptor بده إلكترونات وال + +81 +00:07:52,860 --> 00:08:00,240 +base electron donorوصار هذا تعريف عام الآن أن أي + +82 +00:08:00,240 --> 00:08:06,440 +إش بيعطي إلكترونات base و أي إش بيكتسب إلكترونات + +83 +00:08:06,440 --> 00:08:11,100 +acid إذا صار حسب تعريف Lewis الموضوع مش متطلع إيش + +84 +00:08:11,100 --> 00:08:14,580 +تكون هذه و إيش تكون هذه يعني لو كتبت الآن بعيدا عن + +85 +00:08:14,580 --> 00:08:20,200 +ال H plus وعن ال OH minus لو كتبت A plus زائد مثلا + +86 +00:08:20,200 --> 00:08:21,580 +X minus + +87 +00:08:23,870 --> 00:08:26,950 +هذا بيعطي إلكترونات إذا هذا بيحصل هذا بيكتسب + +88 +00:08:26,950 --> 00:08:33,530 +إلكترونات إذا هذا أسد واضح و لذلك إذا بتذكروا لما + +89 +00:08:33,530 --> 00:08:37,390 +أخدنا على سبيل المثال في chapter ال aromatic + +90 +00:08:37,390 --> 00:08:43,950 +compounds مركب زي ال FECL3 قلنا إن ال FECL3 كام + +91 +00:08:43,950 --> 00:08:50,420 +إلكترون كان حوله6 electron sextant الوضع الطبيعي + +92 +00:08:50,420 --> 00:08:57,760 +كم يكون 8 و بناء على ذلك اعتبرنا Lewis acid فلما + +93 +00:08:57,760 --> 00:09:00,820 +نيجي نقول له ال aromatic compounds كيف كانوا + +94 +00:09:00,820 --> 00:09:07,760 +يتفاعلوا من خلال انه ييجي على سبيل المثال ال CL2 + +95 +00:09:07,760 --> 00:09:12,530 +يتفاعل مع هذا الآن ال CL2 كان يعطيسيال مع + +96 +00:09:12,530 --> 00:09:16,930 +إلكتروناتها كأنه هذه ال base هو بيكتسب السيال مع + +97 +00:09:16,930 --> 00:09:21,290 +إلكتروناتها بيصير تمان إلكترونات حوله بدل ستة فهذا + +98 +00:09:21,290 --> 00:09:26,770 +acid وهذا الجزء كأنه تعامل ك base وعشان تقولنا أن + +99 +00:09:26,770 --> 00:09:31,270 +ال aromatic reactionsبتم في وجود ال FECL3 أو + +100 +00:09:31,270 --> 00:09:35,130 +الألمنيوم الكلوريد الآن الإنسان مابدوش يكتب FECL3 + +101 +00:09:35,130 --> 00:09:38,870 +أو الألمنيوم الكلوريد بيقول ببساطة the + +102 +00:09:38,870 --> 00:09:43,230 +chlorination of aromatic compounds occurs by using + +103 +00:09:43,230 --> 00:09:49,770 +Cl2 with a Lewis acidسواء قولنا FECL3 ألمنيوم CL3 + +104 +00:09:49,770 --> 00:09:54,590 +واطفر هو في النهاية Lewis acid يعني مش الفكرة فيه + +105 +00:09:54,590 --> 00:10:00,270 +بمسماك مركب لأ هي الفكرة فيه بمسماء النوعي أن هو + +106 +00:10:00,270 --> 00:10:08,350 +Lewis acid فصار كل شيء electron donor هو عبارة عن + +107 +00:10:08,350 --> 00:10:14,020 +base وكل شيء electron acceptorهو عبارة عن ايش؟ + +108 +00:10:14,020 --> 00:10:21,680 +acid الان لاحظوا انا نفس المركبات طبقت عليها + +109 +00:10:21,680 --> 00:10:28,460 +التلات تعريفات ولكن هي نظرة اكثر تخصصية يعني هنا + +110 +00:10:28,460 --> 00:10:33,860 +كنت اطلع على المركب كلهأطلع على المُركّب كله و + +111 +00:10:33,860 --> 00:10:38,600 +أقول والله هذا المُركّب كله هو الحامض، الآن إجا + +112 +00:10:38,600 --> 00:10:42,000 +لوري برونز تدعم نفس الطريق، قالوا طب وين مركز + +113 +00:10:42,000 --> 00:10:45,980 +القوة في القاعدة؟ الـ OH خلّال الـ OH القاعدة، لكن + +114 +00:10:45,980 --> 00:10:50,320 +ماتطلعش على مركز القوة وين؟في الحمض ايه جالي ويس؟ + +115 +00:10:50,320 --> 00:10:53,200 +جلطب هو مركز القوة زي ما انت شوفت انه هو مركز + +116 +00:10:53,200 --> 00:10:57,700 +القوة الـ OH شوف انه هو مركز القوة الـ H plus و + +117 +00:10:57,700 --> 00:11:01,380 +اعمل تعريفك عليه و بعدين نظرله من ناحية + +118 +00:11:01,380 --> 00:11:05,580 +الإلكترونات نظرله من ناحية الإلكترونات فواضح ان + +119 +00:11:05,580 --> 00:11:11,070 +التلات تعريف ليست متناقضةالتلات تعريف ليست متناقضة + +120 +00:11:11,070 --> 00:11:18,710 +ولكنها تمثل نظرة اكثر تخصصية نظرة اكثر ايش؟ تخصصية + +121 +00:11:18,710 --> 00:11:24,390 +واضح؟ هذا بالنسبة لتعريف الأحمد الآن لما انا بدي + +122 +00:11:24,390 --> 00:11:29,970 +اجي على قوة الحامض في المحليل اللي عندنا احنا عادة + +123 +00:11:29,970 --> 00:11:35,630 +بنستعملفي ال alcohols تحديدا و ال acids بنفضل + +124 +00:11:35,630 --> 00:11:38,590 +نستعمل اللوري برونس لدفنيشي لاحظوا الناس بيستعملوا + +125 +00:11:38,590 --> 00:11:44,370 +اي تعريف بما يخدم الغرض تبعهم الان لما بدي اجي + +126 +00:11:44,370 --> 00:11:48,570 +اقول ان انا بدي اتعرف على حامض كيف بيتأين و كيف + +127 +00:11:48,570 --> 00:11:54,200 +بيعطي ال ايونات خلينا نتخيل ان الحامض اللي عندناH + +128 +00:11:54,200 --> 00:12:00,500 +A هذا الـ H A عادة تأيّن كيف بتم في الميّه زائد H + +129 +00:12:00,500 --> 00:12:07,380 +2 O كلكم عارفين المعادلة H 3 O plus مثلا زائد A + +130 +00:12:07,380 --> 00:12:13,020 +minus لأن هذه المعادلة العامة و كل ما بيزيد + +131 +00:12:13,020 --> 00:12:16,660 +التأيّن الحامض أقوى لأن هذه المعادلة لها ثابت + +132 +00:12:16,660 --> 00:12:23,410 +اتزان لو احنا بدنا ثابت الاتزان تبعها ال Kهي ساوي + +133 +00:12:23,410 --> 00:12:34,730 +الـ H3O Plus في الـ A Minus على الـ HA في تركيز + +134 +00:12:34,730 --> 00:12:39,750 +الميّه النواتج + +135 +00:12:39,750 --> 00:12:43,070 +على + +136 +00:12:43,070 --> 00:12:50,300 +المتفائلات الان اعتادوا الناس ان اي تركيز ثابتما + +137 +00:12:50,300 --> 00:12:55,000 +يخلّوهاش شيء فالماء تركيزه ثابت الماء تركيزه ثابت + +138 +00:12:55,000 --> 00:13:00,760 +و لو أخدنا احنا جديش عادة في اللتر ميه الف جرام + +139 +00:13:00,760 --> 00:13:05,000 +قسمناه على ال molecular weight تبع ال .. تبع الميه + +140 +00:13:05,000 --> 00:13:08,240 +تمانتعش الف على تمانتعش بطلع لنا حوالي خمسة و + +141 +00:13:08,240 --> 00:13:12,100 +خمسين و كسر هذا موجود في اللتر و بناء على ذلك + +142 +00:13:12,100 --> 00:13:16,100 +التركيز الثابت للميه حوالي خمسة و خمسين و كسر الآن + +143 +00:13:16,100 --> 00:13:21,700 +طالما هذا التركيز ثابت و هذا ثابتبنضرب الثابتين في + +144 +00:13:21,700 --> 00:13:25,800 +بعضهم البعض بنضرب الثابتين في بعضهم البعض فبصير + +145 +00:13:25,800 --> 00:13:32,520 +عند K مضروب في تركيز ال H2O هدولة بعمللهم تعريف + +146 +00:13:32,520 --> 00:13:38,300 +جديد بقول هدولة سميهم K A فال K A مش هو ثابت + +147 +00:13:38,300 --> 00:13:43,620 +الإتزان واضح؟ ال K A شيء و ثابت الإتزان شيء هذا ال + +148 +00:13:43,620 --> 00:13:48,740 +K equilibrium constant هذا ال K A acidity constant + +149 +00:13:50,110 --> 00:13:53,330 +لحظوا ميزوا بينهم equilibrium constant is + +150 +00:13:53,330 --> 00:13:56,650 +something and acidity constant is another thing ال + +151 +00:13:56,650 --> 00:14:01,630 +K a هذه هي عبارة عن ثابت الاتزان مضروب في تركيز ال + +152 +00:14:01,630 --> 00:14:06,910 +H2O اللي ثابت الان لو اتيت على ال K a هيصير ربما + +153 +00:14:06,910 --> 00:14:12,250 +التعبير اللي حضرتكم بتعرفوه H3O plus في A minus + +154 +00:14:12,250 --> 00:14:22,130 +علىهذا تعبير إيش ال K A اللي بنسميه احنا acidity + +155 +00:14:22,130 --> 00:14:30,050 +constant يعني ثابت الحامض الآن ال acidity constant + +156 +00:14:31,960 --> 00:14:37,420 +و كل مكان أعلى كل مكان الحامض بتأيين أكثر والحامض + +157 +00:14:37,420 --> 00:14:41,740 +اللي بتأيين أكثر بالتعريف والحامض الاش الأقوى بناء + +158 +00:14:41,740 --> 00:14:46,780 +على ذلك لو أنا بدي أعمل مقارنة لحامضين مين اللي + +159 +00:14:46,780 --> 00:14:54,730 +بدي يكون أقوى اللي له K A أعلىإذا القاعدة بتقول as + +160 +00:14:54,730 --> 00:15:01,970 +KA increases as KA increases the acidity increases + +161 +00:15:01,970 --> 00:15:08,840 +كل ما زادت ال KA كل ما كان الحامض اشماله أقوىكل ما + +162 +00:15:08,840 --> 00:15:13,280 +الـ Ka بتكون أعلى في القيمة كل ما الحامض بيكون + +163 +00:15:13,280 --> 00:15:17,480 +أقوى فأنا لو أعطيتكم مثلا حامضين هي Ka لهذا وKa + +164 +00:15:17,480 --> 00:15:21,440 +لهذا بتقدروا على طول تقولولي مين الحامض الأقوى + +165 +00:15:21,440 --> 00:15:27,400 +فيهم اللي إله ال Ka أعلى خلينا نجرب نعمل هذا + +166 +00:15:27,400 --> 00:15:31,900 +الكلام خلينا نجرب نعمل هذا الكلام لو إجينا + +167 +00:15:31,900 --> 00:15:40,990 +أعطيناكم حامض HAو حامض HB وهي حامضين و خلّيني أقول + +168 +00:15:40,990 --> 00:15:48,170 +ال K A لهدول الحامضين يعني K A H A نفترض هنا 1.8 + +169 +00:15:48,170 --> 00:15:55,910 +في 10 أقص ناقص خمسة و نفترض هنا 1.3 في 10 أقص ناقص + +170 +00:15:55,910 --> 00:16:04,140 +تلاتةمن الأقوى ال HB، ليش؟ لأن هذا المقدار أكبر من + +171 +00:16:04,140 --> 00:16:09,060 +هذا المقدار، إذا احنا هنا اتفقنا أن هذا الأقوى، + +172 +00:16:09,060 --> 00:16:13,360 +الآن لما اتفقنا أن هذا الأقوى، لو سألنا طالب، ليش + +173 +00:16:13,360 --> 00:16:20,180 +هذا أقوى؟هنتعبها مجرد .. مجرد الأمر تجميلي و ليس + +174 +00:16:20,180 --> 00:16:24,900 +أكثر هنتعبها في الحكي هتيجي تحكي و تفكر و تطلع + +175 +00:16:24,900 --> 00:16:28,460 +تاخدلها ثانيتين تفكير احنا بنختصر عليها ثانية بس + +176 +00:16:28,460 --> 00:16:32,900 +هتقول ال one point three في عشر أقص ناقص تلاتة + +177 +00:16:32,900 --> 00:16:36,900 +أكبر من ال one point eight في عشر أقص ناقص خمسة + +178 +00:16:36,900 --> 00:16:41,680 +وبناء على ذلك هذا كحمض أقوىأقولكوا أعطيتوا الجواب + +179 +00:16:41,680 --> 00:16:46,340 +الصحيح كلامكوا سليم 100% لكن أخذ منكم ثانية أو + +180 +00:16:46,340 --> 00:16:50,380 +ثانيتين تفكير الآن العلماء قالوا بنقدر نوفر على + +181 +00:16:50,380 --> 00:16:55,400 +طلابنا ثانية تفكير يعني لو الأمر بياخد منهم + +182 +00:16:55,400 --> 00:17:00,240 +ثانيتين تفكير عشان يقارنوا يتطلعوا على رقم كبير + +183 +00:17:00,240 --> 00:17:03,120 +مجرد معانكوا تكملوا جراية هذا و جراية هذا بتاخد + +184 +00:17:03,120 --> 00:17:07,200 +ثانيتين فالعلماء قالوا يا تورا بنقدر نختصر على + +185 +00:17:07,200 --> 00:17:13,080 +الطلاب ثانية من التفكيرقال و ممكن كيف؟ قال بدل ما + +186 +00:17:13,080 --> 00:17:17,640 +نتعامل مع الأرقام اللي مش حلوة خلينا نتعامل مع + +187 +00:17:17,640 --> 00:17:24,960 +أشياء أحلى نعرف مقدار جديد نقوله PKA و نقول ال PKA + +188 +00:17:24,960 --> 00:17:31,240 +بتساوي minus logarithm ال KA minus logarithm ال KA + +189 +00:17:32,640 --> 00:17:36,920 +الان لو انا جيبت ال calculator بدل ما تغلبوني قولت + +190 +00:17:36,920 --> 00:17:39,820 +one point eight في عشر أقص خمسة بال minus وال + +191 +00:17:39,820 --> 00:17:43,780 +logarithm تبعها لاحظ ناقص اربعة و سبعة اذا ال BKA + +192 +00:17:43,780 --> 00:17:51,660 +هنقاش اربعة و سبعة طيب لو اجيت اعملت للتاني قولت + +193 +00:17:51,660 --> 00:17:55,100 +one point three في عشر أقص تلاتة بال minus وال + +194 +00:17:55,100 --> 00:17:57,660 +logarithm تبعها اتنين وتسعة + +195 +00:18:02,040 --> 00:18:06,980 +أتنين وتسعة الان لاحظوا انا عارف الأقوى اللي اتيان + +196 +00:18:06,980 --> 00:18:11,940 +اكثر هذا طيب من ناحية ال BKA الحامض الأقوى شو + +197 +00:18:11,940 --> 00:18:18,820 +بتلاحظوا عليه اللي له BKA أقلواضح؟ اللي إله PKA + +198 +00:18:18,820 --> 00:18:23,700 +أقل إذا بدي أنا دائما .. الآن أنا هو أسهل للإنسان + +199 +00:18:23,700 --> 00:18:28,560 +لما يصير حافظ لغرض مقارنة الأحماط الأقل أقوى و + +200 +00:18:28,560 --> 00:18:33,060 +دائما أعطي قيم PKA جداش بياخد منكم .. لما أفرجيكم + +201 +00:18:33,060 --> 00:18:37,810 +رقمين زي هيك أقولكم مين الأقوىثانية لما أفرجيكوا + +202 +00:18:37,810 --> 00:18:42,110 +يفهموا زيكي بياخد ثانيتين إذا هذا ال BKA كل فكرتها + +203 +00:18:42,110 --> 00:18:48,530 +هي فكرة تجميلية لتسهيل النظر والتفكير بالنتيجة + +204 +00:18:48,530 --> 00:18:53,660 +والمقارنة لا تحمل معنى علمي جديدومدلها تماما + +205 +00:18:53,660 --> 00:18:58,860 +بالمناسبة الـ pH اللى بتتعرف minus logarithm تركيز + +206 +00:18:58,860 --> 00:19:01,700 +ال H plus طب هو لو الناس أخدوا تركيز ال H plus + +207 +00:19:01,700 --> 00:19:06,280 +وقارنوا بيقدروا يعني لو أنه في العلم ماعملوش + +208 +00:19:06,280 --> 00:19:12,100 +نهائيا تعريف ال pH و تعريف ال PKA كانوا بيقدروا + +209 +00:19:12,100 --> 00:19:16,180 +برضه يشرحوا كل العلم بدون مشاكل لإيش؟ بيقارنوا + +210 +00:19:16,180 --> 00:19:19,100 +اعتمادا على ال PA بس لما بيقارنوا بذكروا أرقام + +211 +00:19:19,100 --> 00:19:25,820 +شوية غلسةواضح؟ فكل فكرة ال BKA فلسفيا خلّيني أقول + +212 +00:19:25,820 --> 00:19:33,140 +على أقل تقدير هي تسهيل النظر للأرقام الآن لما باجي + +213 +00:19:33,140 --> 00:19:38,760 +انا بعطيكم جدول في قوة لكذا حامض اقولكوا من الأقوى + +214 +00:19:38,760 --> 00:19:43,460 +انتوا خلال الدقيقة راح تتطلعوا أقل واحد أقل BKA + +215 +00:19:46,600 --> 00:19:53,160 +أو لو أعطيتكواها بال .. بال Ka أعلى Ka هي الأقوى + +216 +00:19:53,160 --> 00:19:56,540 +لكن هنا عشان تشوفوا الأعلى عملية بتكون تطلع على + +217 +00:19:56,540 --> 00:20:03,500 +الكسر و على الأسل هنا بتبين ايش أسهل كتير هذه + +218 +00:20:03,500 --> 00:20:09,580 +العملية واضح فقط لغاية طبعا هنا هتيجيكوا مقارنة + +219 +00:20:09,580 --> 00:20:13,720 +دائما ضالكوا متذاكروها متذاكرينها ان ال strength + +220 +00:20:13,720 --> 00:20:21,750 +of acidلو سؤلنا عنه من ناحية ال K A و من ناحية ال + +221 +00:20:21,750 --> 00:20:29,350 +BKA من ناحية ال BK .. ال K A ال higher كل ما كانت + +222 +00:20:29,350 --> 00:20:34,230 +K A أعلى كل ما الحامض أقوى من ناحية ال BKA ال + +223 +00:20:34,230 --> 00:20:40,410 +lower كل ما كانت ال BKA أقل كل ما كان الحامض أقوى + +224 +00:20:40,410 --> 00:20:48,680 +واضح هذه المفاهيم؟الان هذه تقريبا مقدمة خلنا نقول + +225 +00:20:48,680 --> 00:20:55,520 +تذكير بشكل عام في مفاهيم الأحماض الان لما نيجي + +226 +00:20:55,520 --> 00:21:01,100 +نتكلم عن ال alcohols هل يا ترى الكحول ممكن يكون + +227 +00:21:01,100 --> 00:21:09,370 +حامض ولا لأ؟زي و زي الميه انا لما بدي اجي اقول رو + +228 +00:21:09,370 --> 00:21:14,410 +اتش عنده امكانية يفقد هذه الاتش المتصلة بالاكسجين + +229 +00:21:14,410 --> 00:21:19,850 +يعني نقول زائد اتش to او باتزان رو ماينوس + +230 +00:21:22,320 --> 00:21:29,240 +زائد H3O plus إذا هو يمكن أن يفقد هذه ال H وبناء + +231 +00:21:29,240 --> 00:21:34,940 +على ذلك ممكن أنه يكون حامض هي الميه نفسها ممكن + +232 +00:21:34,940 --> 00:21:40,140 +تكون حامض طبعا الميه لما كنا نقول عنها كحامض هي + +233 +00:21:40,140 --> 00:21:46,470 +مجرد HOHيعني لو أخدت نفس هذه المعادلة المية كحمض H + +234 +00:21:46,470 --> 00:21:50,410 +O H لاحظوا لما المرة الماضية قلتلكوا أن المية + +235 +00:21:50,410 --> 00:21:56,890 +فلسفيا ممكن اعتبرها كأن أبسط كحول هنا قلت H O R + +236 +00:21:56,890 --> 00:22:03,490 +وهنا H O H يعني كأن ال R هذه H عشان هي أبسط إيش + +237 +00:22:04,620 --> 00:22:10,680 +أبسط الكحولات فلسفيا زائد H2O هيعطينا HO minus + +238 +00:22:10,680 --> 00:22:20,720 +زائد H3O plus وهذا تفاعل اتزار معروف بالنسبة لنا + +239 +00:22:20,720 --> 00:22:25,260 +في كتب الكيميا اذا H2O كأن واحد منها اتعمل كحمض + +240 +00:22:25,260 --> 00:22:31,740 +فقد H plus التاني اتعمل ك base اكتسب H plus واضح + +241 +00:22:31,740 --> 00:22:36,400 +الفكرة؟و عشان هيك بنقول الميه حامض و الكحول حامض، + +242 +00:22:36,400 --> 00:22:41,660 +الآن طيب لو بدي أجي أقول مين أقوى كحامضية؟ هاد + +243 +00:22:41,660 --> 00:22:45,180 +السؤال كتير مهم، الكحول ولا الميه؟ لأنه بعد شوية + +244 +00:22:45,180 --> 00:22:52,040 +لما بنيجي نقول أن الكحول مطهربدنا نغسل إيدينا فيه + +245 +00:22:52,040 --> 00:22:56,520 +هل يا تورا إذا غسلنا إيدينا في الكحول بدهم ينشعتوا + +246 +00:22:56,520 --> 00:23:01,720 +وينحرجوا بالإيثانول ولا لأ الآن هذا الجواب بنشوفه + +247 +00:23:01,720 --> 00:23:07,520 +من وين احنا من قيم ال BKA اتطلعوا انتوا على الماء + +248 +00:23:07,520 --> 00:23:12,900 +كحمض ال BKA له خمس طعش وسبعة اتطلعوا على الميثانول + +249 +00:23:12,900 --> 00:23:17,700 +خمس طعش وخمسة اتطلعوا على الإيثانول خمس طعش وتسعة + +250 +00:23:18,410 --> 00:23:25,030 +الان كل هذه القيم من ناحية المبدأ تكاد تكون + +251 +00:23:25,030 --> 00:23:31,650 +متساوية اذا حمضية الكحول مثل حمضية الميه والميه + +252 +00:23:31,650 --> 00:23:35,810 +متعودين نقول عنها weak acid عشان هيك لما بتعملوا + +253 +00:23:35,810 --> 00:23:39,130 +في المستقبل مزرعة بكتيريا وصار على إيديكوا جراثيم + +254 +00:23:39,130 --> 00:23:44,910 +و بعدها بدكوا تغسلوا تطهروا إيديكم بالكحولاللي + +255 +00:23:44,910 --> 00:23:48,250 +موجود واتوكلوا على الله مش هيعمل فيكوا إشي ولا + +256 +00:23:48,250 --> 00:23:53,230 +تفكروا إنه هيحرجلكوا إيديكوا من ناحية ال acidity + +257 +00:23:53,230 --> 00:23:59,430 +ال ethanol زي و زي الميه الآن اتخيلوا لو كنتوا + +258 +00:23:59,430 --> 00:24:04,030 +بتتعاملوا مع phenol اللي هو ال aromatic alcohol + +259 +00:24:04,030 --> 00:24:12,340 +نزل لعشرات إذا صارحامض اكتر عشان هيك الفينول اذا + +260 +00:24:12,340 --> 00:24:20,000 +كب ع اديكو هيعلم هيعمل لون هيحرق الايد واضح طبعا + +261 +00:24:20,000 --> 00:24:24,420 +لو بدي اجي على مركب زي ال Nitro Phenol سبعة و + +262 +00:24:24,420 --> 00:24:29,900 +اتنين اقوى و اقوى طب لو اجيتلى مركب زي ال Tri + +263 +00:24:29,900 --> 00:24:36,320 +Nitro Phenol point two fiveقوي جدا لدرجة انه + +264 +00:24:36,320 --> 00:24:40,240 +بيغيروا اسمه بدل ما يسموه phenol اعطوه اسم acid + +265 +00:24:40,240 --> 00:24:45,260 +بيكريك أسد حامض أصفر غامق بيكريك أسد مرات + +266 +00:24:45,260 --> 00:24:49,040 +بتستعملوه في بعض التحاليل لاحظوا شو اللي خلاهم رغم + +267 +00:24:49,040 --> 00:24:52,900 +انه في مجموعة ال O H يعني من ناحية اللي متعودين + +268 +00:24:52,900 --> 00:24:57,820 +على ال acids بال organ ال chemistry C double bond + +269 +00:24:57,820 --> 00:25:04,020 +OOHمش بس هم ال acids هم لما بيفقدوا ال H plus + +270 +00:25:04,020 --> 00:25:07,320 +بيكونوا acids بالعكس ال acetic acid .. ال acetic + +271 +00:25:07,320 --> 00:25:13,880 +acid لو بتكن تتطلع عليه CH3COOOH + +272 +00:25:13,880 --> 00:25:20,530 +هذا ال BKA له أربعة وسبعة بالعشرةيعني اللي احنا + +273 +00:25:20,530 --> 00:25:24,750 +ماعطينه اسم acid أربعة أو سبعة من عشرة الآن لما + +274 +00:25:24,750 --> 00:25:27,850 +تقوله هذا أربعة أو سبعة من عشرة مقارنة ب point two + +275 +00:25:27,850 --> 00:25:32,510 +five لل بيكريك أسد مين أقوى ميت مرة و بيحرق الجلد + +276 +00:25:32,510 --> 00:25:37,990 +ميت مرة ال بيكريك أسد رغم أنه هذا alcohol in + +277 +00:25:37,990 --> 00:25:41,870 +principle أو فينول واضح؟ رغم أن هذا alcohol أو + +278 +00:25:41,870 --> 00:25:47,210 +فينول فالفكرة بقيم ال BKA مش في النهاية حتى بال + +279 +00:25:47,210 --> 00:25:52,610 +structure الكيميائيطبعا بيصير السؤال يا تورا لحظه + +280 +00:25:52,610 --> 00:25:55,550 +انا مثلا لو جينا اتطلعنا على مركب two two two + +281 +00:25:55,550 --> 00:26:00,790 +trifluoroethanol جداش ال acidity تبعته؟ ماعشه + +282 +00:26:00,790 --> 00:26:05,630 +اربعة اذا لو انا بالاثانول بدال ال تلت هيدروجينات + +283 +00:26:05,630 --> 00:26:12,440 +لflour الحمضية بتزيد ولا بتجيل؟ بتزيدبصير السؤال + +284 +00:26:12,440 --> 00:26:17,060 +عاد .. بصير السؤال اللي بدنا نفهمه ليش يا تورا .. + +285 +00:26:17,060 --> 00:26:23,600 +ليش يا تورا الفينول كحمض أقوى من الإيثانول؟ ليش يا + +286 +00:26:23,600 --> 00:26:28,980 +تورا ال acetic acid أقوى من الإيثانول بكتير؟ يعني + +287 +00:26:28,980 --> 00:26:33,260 +ال acetic acid لو حطيناه على إيدنا، بده يحرج إيدنا + +288 +00:26:34,380 --> 00:26:38,400 +واضح؟ احنا مراتب بنستعمل الخل و بنشرب، لكن هذا خل + +289 +00:26:38,400 --> 00:26:43,260 +مخفف بنسبة أقل من خمسة في المية، خفيف كتير، لكن لو + +290 +00:26:43,260 --> 00:26:49,130 +حد بده يحط الخل النقيالصافي مش المدوّب في الميّه + +291 +00:26:49,130 --> 00:26:53,430 +اللي بنباع في السوق ال vinegar هذا خل أقل من 5% + +292 +00:26:53,430 --> 00:26:57,490 +ممكن تفوته على السلطة ممكن تشرب معلجة منه أو تخففه + +293 +00:26:57,490 --> 00:27:01,150 +بميه و تشرب معلجة منه لكن الخل نفسه لو بده أخده + +294 +00:27:01,150 --> 00:27:05,530 +كحامق بدون ما يكون مخفف بالميه هيحرج الإيدانواضح؟ + +295 +00:27:05,530 --> 00:27:09,070 +ليش الخل اقوى من الاثانول؟ ليش ال try + +296 +00:27:09,070 --> 00:27:13,150 +fluoroethanol اقوى من الاثانول؟ ليش الفينول اقوى + +297 +00:27:13,150 --> 00:27:17,690 +من الاثانول؟ ليش ال nitrophenol اقوى من الفينول؟ + +298 +00:27:17,690 --> 00:27:22,290 +ليش ال try nitrophenol اقوى من ال nitrophenol؟ + +299 +00:27:22,290 --> 00:27:29,730 +الان كل هذه دراساتمقارنة يعني لما بدأ اقارن حامضين + +300 +00:27:29,730 --> 00:27:34,610 +لما بدأ اقارن حامضين و اجي اقول ان في عندى حامض + +301 +00:27:34,610 --> 00:27:42,270 +اقوى من حامض السؤال ليش تمام خلينا نفهم الأمور + +302 +00:27:42,270 --> 00:27:50,470 +شوية بهدوء و بشكل خلينا اقول منطقي اللي يخدمني لكل + +303 +00:27:50,470 --> 00:27:55,430 +الحالات اللي موجودة كل حالة بالمناسبة لها سببيعني + +304 +00:27:55,430 --> 00:28:00,950 +هنا مش سبب واحد اللي موجود لأ هي أكتر من سبب فرعي + +305 +00:28:00,950 --> 00:28:05,390 +لكن اللي بديه يفهم الموضوع ناخد الموضوع بشكل عام + +306 +00:28:05,390 --> 00:28:09,790 +لو بدنا نحكي على مقارنة حامضين خليني أجي أتخيل أني + +307 +00:28:09,790 --> 00:28:18,080 +بدي أقارن ال HCL و ال HBRكأحمار تمام و اقول انا + +308 +00:28:18,080 --> 00:28:23,700 +انه hcl و استعمل aq عارفين aq؟ aqs يعني بمية هذا + +309 +00:28:23,700 --> 00:28:28,540 +الكلام بيصير عشان ما نتغلبش h plus aqs يعني كأنها + +310 +00:28:28,540 --> 00:28:36,160 +h3o زائد cl minus و لو انا اجيت قولت hbr aqs برضه + +311 +00:28:36,160 --> 00:28:45,330 +h plus aqs زائد br minus كل هذا الكلام ايش؟في + +312 +00:28:45,330 --> 00:28:51,270 +محلول معين كل هذا الكلام محلول معين الان ال HBR + +313 +00:28:51,270 --> 00:28:56,030 +بالتجربة اقوى من ال HCL ال HBR بالتجربة اقوى من ال + +314 +00:28:56,030 --> 00:29:00,750 +HCL لو انا بدي اجي اقول يا تورا ايش السبب لاحظوا + +315 +00:29:00,750 --> 00:29:06,270 +لو فكرنا بمنطقة ال H plus لو فكرنا بمنطقة ال H + +316 +00:29:06,270 --> 00:29:11,610 +plus هذا بيعطي H plus وهذا بيعطي H plus اذا الحكم + +317 +00:29:11,610 --> 00:29:17,570 +مش ال H plusالحكم مش الـ H plus المشترك عمره ما + +318 +00:29:17,570 --> 00:29:22,470 +بيفرق شغلتين اللي بيفرق هو إيش؟ المختلف بناء على + +319 +00:29:22,470 --> 00:29:30,020 +ذلك ال PR minus وال CL minus هم السبب هم السببفي + +320 +00:29:30,020 --> 00:29:34,300 +انه حامض اقوى من حامض هم السبب في انه حامض اقوى من + +321 +00:29:34,300 --> 00:29:39,240 +حامض الان احنا بنقول الايون السالب النظر اليه هو + +322 +00:29:39,240 --> 00:29:42,220 +محور التفكير يوم افدياليس اللي اش حامض اقوى من + +323 +00:29:42,220 --> 00:29:46,100 +حامض على ايش بدأ اطلع على الايون السالب لان كله + +324 +00:29:46,100 --> 00:29:52,360 +هياطلق اتش بلس بنقول كل ما كان الايون السالب اثبت + +325 +00:29:52,360 --> 00:29:58,140 +كل ما كان الحامض اقوى واضح؟يعني كل ما هذا الايون + +326 +00:29:58,140 --> 00:30:02,940 +السالب أثبت الحامض أقوى و ربما هذا الكلام يكون + +327 +00:30:02,940 --> 00:30:08,260 +بحاجة شوية إلى تفسير شو يعني ان الايون السالب أثبت + +328 +00:30:08,260 --> 00:30:18,910 +المقصود بالثبات أن يحمل شحنة أقلالثبات كلما زادت + +329 +00:30:18,910 --> 00:30:25,410 +الشحنة قل الثبات و كلما قلت الشحنة زاد الثبات إذا + +330 +00:30:25,410 --> 00:30:30,190 +الثبات مرتبط بإيش؟ بالشحنة لما بتزيد بيبطل فيه + +331 +00:30:30,190 --> 00:30:34,250 +ثبات لما بتقل بيصير فيه ثبات فاللي بده يثبت أي شغل + +332 +00:30:34,250 --> 00:30:38,650 +بده يقل شحنتها لاحظوا هذا الكلام مش خاص في الأحماط + +333 +00:30:38,650 --> 00:30:43,630 +بس حتى في البشر يعني على سبيل المثال الغضب .. + +334 +00:30:43,630 --> 00:30:51,830 +الغضب إيش تعريفه؟الغضب شُحنة وهذه الشُحنة تظهر حتى + +335 +00:30:51,830 --> 00:30:56,430 +على الطاقة ال energy تظهر حتى على وش الإنسان وعلى + +336 +00:30:56,430 --> 00:31:00,650 +خدوده تشوف كيف عينيه يطلعوا لبرا الإنسان الغضبان + +337 +00:31:00,650 --> 00:31:04,370 +وخدوده حمر الرسول عليه الصلاة والسلام ايش بيقول + +338 +00:31:04,370 --> 00:31:11,460 +أما رأيتم إلى انتفاخ أوداجه وحمرار عينيهليش؟ لأنه + +339 +00:31:11,460 --> 00:31:16,120 +بيحمل شحنة غضب كتيرة هذا الغضبان كتير بيكون stable + +340 +00:31:16,120 --> 00:31:20,740 +ولا unstable؟ بيكون unstable اليوم لاحظوا لما أنا + +341 +00:31:20,740 --> 00:31:25,020 +بدي أضيع الغضب منه عند اللزوم بغسله بالمية مش ممكن + +342 +00:31:25,020 --> 00:31:29,700 +جد ما يكون الإنسان غضبان مولّع نار لو حاطيته تحت + +343 +00:31:29,700 --> 00:31:36,160 +دوش مية هي energy طاقة المية الباردة هذه هتسحب ال + +344 +00:31:36,160 --> 00:31:43,300 +energy منه هيقلل الغضبكل ما قلت الشحنة كل ما اش + +345 +00:31:43,300 --> 00:31:47,860 +عندى صار زادى الثبات اذا انا لما بدى اقارن شغلة + +346 +00:31:47,860 --> 00:31:52,380 +اثبت من شغلة بدى اطلع على الشحنة السالبة و اشوف + +347 +00:31:52,380 --> 00:31:58,800 +ايش اللى بيخليها اقل بدى يصير الان سؤالنا ايش طرق + +348 +00:31:58,800 --> 00:32:05,620 +تقليل الشحنة السالبة كيف ممكن الشحنة السالبة تكون + +349 +00:32:05,620 --> 00:32:15,250 +ايش اقلواضح؟ كيف ممكن أقلل أنا الشحنة؟ بشكل عام، + +350 +00:32:15,250 --> 00:32:23,890 +الشحنة حمل إمصيبة، عدم ثبات، كيف بدي أقللها؟ أنا + +351 +00:32:23,890 --> 00:32:29,060 +بحبش الكيمياأنا الكيميا دي مابحبهاش بالمرة أنا بحب + +352 +00:32:29,060 --> 00:32:34,820 +نفهم الموضوع من الحياة نفهم الموضوع كيف من الحياة + +353 +00:32:34,820 --> 00:32:39,080 +انتبهوا معايا لو اتخيلتوا الآن لو اتخيلتوا الآن + +354 +00:32:39,080 --> 00:32:45,440 +انسان راح على السوقو حمل اشترى خمسة كيلو من شغلة + +355 +00:32:45,440 --> 00:32:51,460 +معينة هدول يمثلوا شحنة ولا حمل ولا لأ؟ و حملهم هذا + +356 +00:32:51,460 --> 00:32:56,400 +الإنسان حمل خمسة كيلو بمثله ثقل عليه وعدم ثبات ولا + +357 +00:32:56,400 --> 00:33:02,940 +لأ؟ الآن بدنا نساعد هذا البني آدم نقلل الحمل اللي + +358 +00:33:02,940 --> 00:33:08,670 +عليهفي عندى اكثر من طريقة الطريقة الاولى تخيلوا لو + +359 +00:33:08,670 --> 00:33:14,310 +الخمسة كيلو دولة حملهم طفل صغير عمره اربع سنين ولا + +360 +00:33:14,310 --> 00:33:19,410 +حملهم شاب عمره عشرين سنة مين بيكون اثبت ومتريح + +361 +00:33:19,410 --> 00:33:26,050 +اكتر اذا كل ما بيزيد الحجملما أحط عليه حمل معين، + +362 +00:33:26,050 --> 00:33:30,330 +نفس الحمل، الخمسة كيلو على ابن أربع سنين لصغير ولا + +363 +00:33:30,330 --> 00:33:34,770 +على ابن عشرين سنة، مين اللي بيحمل أكثر؟ إذا صار + +364 +00:33:34,770 --> 00:33:39,630 +عند أول تأثير ممكن نفكر فيه تأثير إيش؟ الحجم، إنه + +365 +00:33:39,630 --> 00:33:45,070 +كل ما الحجم كبر، الإش بنحمل أسهل وعشان هيك الشاب + +366 +00:33:45,070 --> 00:33:50,860 +الكبير بيحمل الخمسة كيلو أسهل من إشمن الولد الصغير + +367 +00:33:50,860 --> 00:33:56,060 +طب لو إجينا لشاب كبير و قولنا له هدولة الخمسة كيلو + +368 +00:33:56,060 --> 00:34:02,340 +كيف ممكن كمان أقلل الحمل عنده بييجي شخص تاني + +369 +00:34:02,340 --> 00:34:05,960 +بيقوله أساعد معاك الان لما الشخص التاني بيقوله + +370 +00:34:05,960 --> 00:34:10,900 +أساعد معاك نفترض أن هدولة الخمسة كيلو هاي هذا ماسك + +371 +00:34:10,900 --> 00:34:15,880 +من هنا والتاني ماسك معاه صار الحمل محمول من إيش؟ + +372 +00:34:15,880 --> 00:34:24,270 +من طرفيناتوزع الحمل واضح؟ صار في شخص مساعد هذا + +373 +00:34:24,270 --> 00:34:28,570 +الكلام نفسه ممكن يتكرر في الكيميا بنسميه إيش احنا؟ + +374 +00:34:28,570 --> 00:34:32,890 +inductive effect يعني تأثير المساعدة من شيء قريب + +375 +00:34:32,890 --> 00:34:37,770 +إنه حد يساعد معاك طيب نفترض في طريقه مافيش ولا حد + +376 +00:34:37,770 --> 00:34:44,930 +يساعد هذا الإنسان هو حامل الخمسة كيلو إيش هيعمل؟ + +377 +00:34:45,770 --> 00:34:48,850 +هذه الإيد بتتعب بتلاحظوا لو صورته + +378 +00:34:52,190 --> 00:34:57,270 +بصير يعمل تبديل هذا التبديل إيش بنسميه resonance + +379 +00:34:57,270 --> 00:35:02,710 +إذا هو خفف عن نفسه الحمل بإيش بال resonance لحظو + +380 +00:35:02,710 --> 00:35:08,250 +كام طريقة الأن صرت أنا حاكي لتخفيف الحمل تلت طرق + +381 +00:35:08,250 --> 00:35:14,350 +الطريقة الأولى زيادة الحجم الطريقة التانية طريقة + +382 +00:35:14,350 --> 00:35:17,930 +ال inductive effect ليه المساعدة و الطريقة التالتة + +383 +00:35:17,930 --> 00:35:21,930 +طريقة ال resonanceهذه الطرق اللي من خلالها انا + +384 +00:35:21,930 --> 00:35:26,970 +ممكن اقلل الشحنة الان لو بدأنا نتطلع على زيادة + +385 +00:35:26,970 --> 00:35:33,010 +الحجم حسب الجدول الدوري مين اكبر لبروم ولا لكلور؟ + +386 +00:35:33,010 --> 00:35:39,250 +لبروم اتطلع معنا لبروم تحت في الجدول الدوري يعني + +387 +00:35:39,250 --> 00:35:44,390 +كأنه هاي لبروم و كأنه هاي لكلور الان عليهم نفس + +388 +00:35:44,390 --> 00:35:50,320 +الحمل شحنة سالبة و شحنة سالبةمين اقدر على حمل + +389 +00:35:50,320 --> 00:35:54,640 +الشحنة السالبة؟ الحجم الكبير طبعا لو بدأ اقارن + +390 +00:35:54,640 --> 00:36:00,460 +اليود اكبر منهم كلهم الان عليهم نفس الشحنة السالبة + +391 +00:36:00,460 --> 00:36:05,400 +من الاقدر على حمل الشحنة؟ اليود وبناء على ذلك لما + +392 +00:36:05,400 --> 00:36:13,100 +انا بدأ اجي افسر ليش ال hi اقوى من ال hbr اقوى من + +393 +00:36:13,100 --> 00:36:20,720 +ال hcl بدأ اقول السبب هو ايش ال sizeالـ Sizeبكلمة + +394 +00:36:20,720 --> 00:36:24,460 +واحدة ال size انه الحجم الكبير بيقدر يحمل نفس + +395 +00:36:24,460 --> 00:36:30,300 +الشحنة السالبة واضح السبب هو ايش ال size الان هاي + +396 +00:36:30,300 --> 00:36:34,500 +فهمنا التأثير الاول طب نجيبله مثال من الأشياء اللي + +397 +00:36:34,500 --> 00:36:39,520 +بدنا ندرسها متذكرين ان احنا شبترنا ال alcohols و + +398 +00:36:39,520 --> 00:36:43,220 +الthiols و متذكرين اللي هو ال oxygen و ال sulfur + +399 +00:36:43,220 --> 00:36:51,610 +تحت بعض طب لو بدي اجي اقول roh ولا rshالاتنين + +400 +00:36:51,610 --> 00:36:57,370 +هيفقدوا ايش ال H أنا قولت بدها تطلع على السالب + +401 +00:36:57,370 --> 00:37:02,170 +اللي بده يقارن حمضية بده يطلع على السالب هذا فقد و + +402 +00:37:02,170 --> 00:37:07,150 +هيحمل سالب وهذا فقد و يحمل سالب هو مين أكبر ال O + +403 +00:37:07,150 --> 00:37:13,750 +ولا ال S؟ ال S وبناء على ذلك بيصير ال RSH أقوى من + +404 +00:37:13,750 --> 00:37:19,980 +ال R O attributeSize و كذلك الحالة لو كنت أقولكم + +405 +00:37:19,980 --> 00:37:28,600 +ARSH و AROH من الأقوى؟ ال ARSH يعني طالما أنا موحد + +406 +00:37:28,600 --> 00:37:31,840 +كل إشي بس مفرج ال sulfur و ال oxygen طب ما هي ال + +407 +00:37:31,840 --> 00:37:40,410 +sulfur؟أكبر من ال Oxygen فهي أكبر على حمل الشحنة + +408 +00:37:40,410 --> 00:37:46,110 +السلبية إذا هذا ال size فصّال لي ليش ال RSH أقوى + +409 +00:37:46,110 --> 00:37:56,410 +من ال ROH و ليش ال ARSH أقوى من ال AROH ال size + +410 +00:37:56,410 --> 00:38:01,560 +اللي فصّال ليها الحجمالحجم الكبير أقدر على حمل + +411 +00:38:01,560 --> 00:38:09,620 +الشحنة الحجم الكبير أقدر على حمل الشحنة الآن خليني + +412 +00:38:09,620 --> 00:38:14,500 +أجي لل resonance و بدي أقارن أنا الاثانول مع حمض + +413 +00:38:14,500 --> 00:38:24,010 +الخلق لاحظوا الاثانول إيش صيبته؟CH3 CH2 OH وحمض + +414 +00:38:24,010 --> 00:38:33,550 +الخلب CH3 C O OH الآن اتفقنا انه لما بدنا نقارن ال + +415 +00:38:33,550 --> 00:38:39,690 +H Plus مش لازماني بدي اشيلها و بده اقارن ال Ion + +416 +00:38:39,690 --> 00:38:45,650 +السالب و Ion السالب واضح؟ + +417 +00:38:46,870 --> 00:38:51,470 +الان هتلاحظوا هنا ال ايون السالب هذا موجود على ال + +418 +00:38:51,470 --> 00:38:55,430 +oxygen مش قادر يتحرك يعني هذا أشبه البني ادم معه + +419 +00:38:55,430 --> 00:39:00,170 +حمل بس إيده التانية مقطوعة طول الطريق هيضله إيش؟ + +420 +00:39:00,170 --> 00:39:05,670 +حامل الشحن السالب على هذا ال oxygen هذا لأ له اتين + +421 +00:39:06,690 --> 00:39:10,570 +بناء على ذلك هذا ممكن يعمل resonance بمعنى أن هذه + +422 +00:39:10,570 --> 00:39:15,050 +تتحرك هنا وهذه تيجي هنا لاحظوا هذا ال resonance + +423 +00:39:15,050 --> 00:39:21,670 +حركة الإلكترونات متذكرين لما أخدناها CH3 سيصبح CH3 + +424 +00:39:21,670 --> 00:39:26,150 +وهذه تصبح double bond O وهنا ال O minus إذا ال + +425 +00:39:26,150 --> 00:39:31,850 +minus أين صارت محمولة مرة على ال oxygen هذه ومرة + +426 +00:39:31,850 --> 00:39:36,350 +على هذهعملة resonance وعشان هيك مرات بتلاقوهم + +427 +00:39:36,350 --> 00:39:43,950 +كتبوها بهذا الشكل للأيون CH3COO وعملوا + +428 +00:39:43,950 --> 00:39:48,310 +ال minus مشترك بينهم جاعت بتنجل هذا تأثير ايش + +429 +00:39:48,310 --> 00:39:53,510 +resonance هذا تأثير resonance عشان هيك ال acetic + +430 +00:39:53,510 --> 00:39:57,490 +acid لو بتكون قارنوه بالإيثانول اربعة وسبعة ال BKA + +431 +00:39:57,490 --> 00:40:03,880 +مقارنة بخمستاعش تسعةالملاحظين قديش ال acetic acid + +432 +00:40:03,880 --> 00:40:09,580 +أقوى من ال ethanol كتير جدا مافيش مقارنة بينهم و + +433 +00:40:09,580 --> 00:40:13,720 +السبب لما نقول ال acetic acid is stronger than + +434 +00:40:13,720 --> 00:40:19,990 +ethanol الجواب يوتوresonance due to resonance بعد + +435 +00:40:19,990 --> 00:40:24,470 +شوية هتلاحظوا انه لما اجي اقارن الفينول بالاثانول + +436 +00:40:24,470 --> 00:40:29,330 +تاومت زكريه لما قولنا الفينول عشرة والاثانول خمساش + +437 +00:40:29,330 --> 00:40:32,930 +ستاش هتلاحظوا ان الفينول بعمل resonance للاثانول + +438 +00:40:32,930 --> 00:40:33,270 +لأ + +439 +00:40:37,470 --> 00:40:43,210 +الفكرة العامة وصلت انه هذا التأثير هو تأثير ايش؟ + +440 +00:40:43,210 --> 00:40:47,110 +resonance نيجي للتأثير التالت ال inductive effect + +441 +00:40:47,110 --> 00:40:51,190 +انه ييجي حد يساعد يقول خليني اساعد معاك يعني + +442 +00:40:51,190 --> 00:40:55,490 +الشحنة مكانها زي الحمل ما زال باليد هادى مانتجلش + +443 +00:40:55,490 --> 00:41:01,550 +لكن بيجي حد ايش؟ بساعد اضافى لو انا اجيت اطلعت على + +444 +00:41:01,550 --> 00:41:07,470 +ال ethanol مرة تانيةCH3 CH2 بدي أخد منه على طول بس + +445 +00:41:07,470 --> 00:41:12,110 +ال ion السالب هيو مسكين حامل شحنة سالبة متغلب فيها + +446 +00:41:12,110 --> 00:41:17,310 +ولا لأ؟ متغلب جدا عارفين ليش؟ لأن ال oxygen صغيرة + +447 +00:41:17,310 --> 00:41:21,670 +مش قدرت تحمل شحنة سالبة ال oxygen مش قادرة تحمل + +448 +00:41:21,670 --> 00:41:25,550 +الشحنة السالبة الآن هذا يا تورا لو كنت بدي أقارنه + +449 +00:41:25,550 --> 00:41:29,110 +بالمركب اللي فيه تلت ذرات floor بسم الله ما شاء + +450 +00:41:29,110 --> 00:41:29,330 +الله + +451 +00:41:32,590 --> 00:41:38,790 +و هاي ال O و هاي عليها ال minus لاحظوا + +452 +00:41:38,790 --> 00:41:43,910 +ال floor ايش ماله ال electronegative ال + +453 +00:41:43,910 --> 00:41:48,090 +electronegative شو بعمل في الشحنة السالبة بسحب جزء + +454 +00:41:48,090 --> 00:41:53,030 +منها بحمل جزء منها بناء على ذلك هذه الشحنة السالبة + +455 +00:41:53,030 --> 00:41:59,650 +فى ناس مساعدين يساعدوا بحملها لأ الآن هنا هاي ال + +456 +00:41:59,650 --> 00:42:05,290 +floorElectronegative بيسحق جزء و ال floor التاني + +457 +00:42:05,290 --> 00:42:09,510 +كمان جزء و ال floor التالت يعني كأنه حمل أكم واحد + +458 +00:42:09,510 --> 00:42:14,050 +إيجي يساعد بحمله كمان تلاتة زي ناس حاملين شغلة + +459 +00:42:14,050 --> 00:42:18,790 +كبيرة و إجوا كمان تلاتة يساعدوا بحملها مش بتحمل + +460 +00:42:18,790 --> 00:42:24,270 +أسهل لو إجوا اتنينأصعب شوية لو إيجي واحد إذا .. لو + +461 +00:42:24,270 --> 00:42:27,770 +أنا بدي أقارن مركّب عليه تلت ذرات floor مع مركّب + +462 +00:42:27,770 --> 00:42:30,930 +عليه تنتين مع مركّب عليه واحدة مين بدي يكون فيهم + +463 +00:42:30,930 --> 00:42:34,270 +الحامض الأقوى؟ اللي تلاتة لأن في تلاتة جاعدين + +464 +00:42:34,270 --> 00:42:39,610 +بيساعدوا بحمل الشحنة السالبة واضح؟ لحظوا هذه أفكار + +465 +00:42:39,610 --> 00:42:43,290 +.. هذا هو ال inductive effect هذا ال effect هو إيش + +466 +00:42:43,290 --> 00:42:46,890 +بنسميه إحنا؟ ال inductive effect يعني تأثير + +467 +00:42:46,890 --> 00:42:55,350 +المساعدةمن خلال مجموعات ساحبة للإلكترونات طبعا هذا + +468 +00:42:55,350 --> 00:42:59,930 +ممكن يصير بالنسبة لي سؤال بالصح والغلط أنه يا ترى + +469 +00:42:59,930 --> 00:43:04,810 +المجموعة الساحبة للإلكترونات ماذا تعمل بالشحنة + +470 +00:43:04,810 --> 00:43:10,690 +السالبة تنقصها إذا تزيد الثبات وتزيد الحامضية طب + +471 +00:43:10,690 --> 00:43:16,710 +تخيلوا بقدرة جادر لو بني آدم زي ما بيقول المثل إيه + +472 +00:43:16,710 --> 00:43:23,500 +جاي كحلهاعماها بدل ما يحط تلت مجموعات مساعدة تحمل + +473 +00:43:23,500 --> 00:43:28,100 +حط تلاتة تزيد الحمل عارفين زي إيش؟ زي الأم الصغيرة + +474 +00:43:28,100 --> 00:43:30,780 +اللي شارية شغلة من السوق الأم اللي شارية شغلة من + +475 +00:43:30,780 --> 00:43:34,380 +السوق وتعبانة بحملها ومعها تلت ولادة وكل ولد بيحط + +476 +00:43:34,380 --> 00:43:41,320 +تجله على إيدها بتصير مش جارة الشغلة الشغلة و التلت + +477 +00:43:41,320 --> 00:43:45,480 +ولادة بتشوفوا كيف مهدودة وجه تسار التأثير إيش + +478 +00:43:45,480 --> 00:43:52,360 +ماله؟ عكسييعني لو هذه المجموعة بطلت ساحبة صارت + +479 +00:43:52,360 --> 00:43:57,060 +مجموعة معطية للإلكترونات وجدت إيش بدها تعمل + +480 +00:43:57,060 --> 00:44:00,400 +بالشحنة السالبة؟ بدها تزيدها، شو بتتوقع يصير في + +481 +00:44:00,400 --> 00:44:05,420 +الحامضية؟ اتقل، عشان هيك لو اطلعت مثلا هذا المثال + +482 +00:44:05,420 --> 00:44:06,680 +اللي فيه CH3 + +483 +00:44:09,570 --> 00:44:13,210 +CH3O- اللي جاي من ال tertiary butyl alcohol + +484 +00:44:13,210 --> 00:44:16,690 +اتطلعوا في الجدول كداش ال tertiary butyl alcohol + +485 +00:44:16,690 --> 00:44:27,270 +عندكم محتوى 18 اقل اقل في الحمضية ولا لأ ايش السبب + +486 +00:44:27,270 --> 00:44:34,680 +ان هذه المجموعاتبتعطي إلكترونات electron donating + +487 +00:44:34,680 --> 00:44:40,080 +مش electron with a drawing الكلور بسبب سليبيته + +488 +00:44:40,080 --> 00:44:48,280 +بيسحب إلكترونات واضح المثل بيعطي إلكترونات وعشان + +489 +00:44:48,280 --> 00:44:52,640 +هيك هذا المركب يعني خلينا نعمل مرجعيتنا الاثانول + +490 +00:44:52,640 --> 00:45:02,070 +مشجولة حوالي 15.9 هذا المركب 18 أضعف هذا المركب12 + +491 +00:45:02,070 --> 00:45:09,070 +أقوى واضح كيف التأثير انه انا لو اجيت اقارن هذه + +492 +00:45:09,070 --> 00:45:13,630 +المركبات المتشابهة هنا عندي تقليل الشحنة السالبة + +493 +00:45:13,630 --> 00:45:19,650 +معناها زيادة حمضية هنا عندي تركيز او intensifying + +494 +00:45:19,650 --> 00:45:25,720 +او زيادة الشحنة السالبة معناهاتقليل حمضية هذا ال + +495 +00:45:25,720 --> 00:45:28,920 +inductive effect بوجهينه ما هو ايه؟ في ناس + +496 +00:45:28,920 --> 00:45:33,820 +بيساعدوا بالموجب و في ناس بيساعدوا بالسالب واضح؟ + +497 +00:45:33,820 --> 00:45:36,320 +تماما زي المثال الحكيناه، ناس بيجوا بيساعدوه و + +498 +00:45:36,320 --> 00:45:40,760 +بيحملوا مع البني آدم و ناس .. جيبناك يا عبد المعين + +499 +00:45:40,760 --> 00:45:47,160 +اتعين لجناك بدك؟ معين واضح؟ هنا التأثير سلبي، هنا + +500 +00:45:47,160 --> 00:45:54,420 +التأثير إيجابيواضح الفكرة؟ اذا اخر شيء باختم اليوم + +501 +00:45:54,420 --> 00:45:57,660 +بعدك بتصير الأمثلة كل اللي في ال slides اللي + +502 +00:45:57,660 --> 00:46:02,960 +بنحكيه بتجيجتين خلاص فينا المبادئ مفهوم الحامضية + +503 +00:46:02,960 --> 00:46:06,600 +مرتبط بالشحنة السالبة إنها تجل الشحنة السالبة اللي + +504 +00:46:06,600 --> 00:46:12,500 +بيجللها تلت أشياء ال size الأكبر ال resonance + +505 +00:46:12,500 --> 00:46:19,240 +الأكتر وال inductive effect الساحبلاحظوا عند كلمة + +506 +00:46:19,240 --> 00:46:24,260 +ال inductive effect ال inductive effect نوعين فى + +507 +00:46:24,260 --> 00:46:28,200 +inductive effect ساحب و inductive effect معطى ال + +508 +00:46:28,200 --> 00:46:33,100 +inductive effect الساحب هو اللى بيزيد الحامضية ال + +509 +00:46:33,100 --> 00:46:37,760 +inductive effect المعطى هو اللى بيقلل الحامضية إذا + +510 +00:46:37,760 --> 00:46:42,040 +صار عندى electron إيش معنى ساحب بالإنقليزة with a + +511 +00:46:42,040 --> 00:46:49,840 +drawing يسحب و إيش معنى معطىdonating donation + +512 +00:46:49,840 --> 00:46:56,080 +اعطار أو releasing electron donating electron + +513 +00:46:56,080 --> 00:47:00,240 +releasing هذا بيقلل الحمضية electron withdrawing + +514 +00:47:00,240 --> 00:47:04,740 +بيزيد الحمضية بنختم عند هذه اللحظة + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/di-xbM-HbNU_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/di-xbM-HbNU_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..113e6db8580a7a6a78dd7c4cdb91328115f59e55 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/di-xbM-HbNU_postprocess.srt @@ -0,0 +1,2096 @@ +1 +00:00:18,700 --> 00:00:22,900 +بسم الله الرحمن الرحيم، اليوم ان شاء الله هنبتدأ + +2 +00:00:22,900 --> 00:00:28,300 +الفصل الأخير في ال course اللي بأمل أن نكون يعني + +3 +00:00:28,300 --> 00:00:32,740 +استفدنا منه واستمتعنا فيه على مدى ثلاث أو أربع + +4 +00:00:32,740 --> 00:00:38,220 +شهور course الكيمياء الأضوية العامة والكيمياء يعني + +5 +00:00:38,220 --> 00:00:43,140 +مقدمة في الكيمياء الحيوية العامةالفصل هذا بعنوان + +6 +00:00:43,140 --> 00:00:49,360 +amino acids, peptides and proteins، طبعا هو مش تلت + +7 +00:00:49,360 --> 00:00:56,860 +عنوين، لأهي ال amino acids الأحماض الأمينية الوحدة + +8 +00:00:56,860 --> 00:01:02,640 +البسيطة إذا اتحد عندي عدد قليل من ال amino acids + +9 +00:01:02,640 --> 00:01:07,080 +بيعملوا ال peptides يعني أربعة، خمسة، عشرة، خمس، + +10 +00:01:07,080 --> 00:01:12,280 +تعش هدولة بيعملوا ال peptides الآن إذا صاروا بال + +11 +00:01:12,280 --> 00:01:17,880 +آلاف وأحيانا بعشرات الآلاف بصير الجزء كبير جدا + +12 +00:01:17,880 --> 00:01:23,530 +بنسمي إيش ال proteinفالبروتين الان كبير جدا لو بده + +13 +00:01:23,530 --> 00:01:28,690 +يتكسر بالعكس هيتكسر لpeptides و ال peptides لو + +14 +00:01:28,690 --> 00:01:34,670 +بدها تتكسر هتتكسر ل amino acids فالوحدة الأساسية + +15 +00:01:34,670 --> 00:01:42,480 +هتكون ال aminoو لذلك أمر طبيعي جدا ان نبدأ الفصل + +16 +00:01:42,480 --> 00:01:47,900 +هذا ان نتعرف على ال amino acids معنى amino acids + +17 +00:01:47,900 --> 00:01:54,220 +أحماض عضوية عادية لكن فيها مجموعة الأمين بشكل عام + +18 +00:01:54,220 --> 00:02:01,940 +مجموعة ال NH2 الآن من الناحية النظرية البحثة لو + +19 +00:02:01,940 --> 00:02:08,870 +انا بحكي عن حامض عضويوفي مجموعة امين معنا ذلك بقدر + +20 +00:02:08,870 --> 00:02:14,250 +اتوقع ان يكون عندى عدد لا نهائى من ال amino acids + +21 +00:02:14,250 --> 00:02:20,070 +واضح يعني لو بدى اقول قداش العدد النظري المتوقع من + +22 +00:02:20,070 --> 00:02:23,910 +ال amino acids لما انا اجي اقول هاي مجموعة الحامض + +23 +00:02:23,910 --> 00:02:29,470 +سيضة بال bond O OH و بعدين احط هنا carbons + +24 +00:02:31,380 --> 00:02:36,140 +الان حسب ما يكون في عندى و الله اذا في هنا مجموعة + +25 +00:02:36,140 --> 00:02:40,920 +amino ممكن يكون هنا مجموعة amino هنا هنا لاحظوا + +26 +00:02:40,920 --> 00:02:44,000 +معنى بتيجي نقطة كتير مهمه ان انا لما بحط amino + +27 +00:02:44,000 --> 00:02:50,200 +بكون في عندي كمان R groups واضح فنظريا ال amino + +28 +00:02:50,200 --> 00:02:56,730 +acids اكترالان بنجيب نتطلع وين مجموعة الأمين + +29 +00:02:56,730 --> 00:03:02,030 +مجموعة ال N H2 والله إذا كانت هذه مجموعة الأمين + +30 +00:03:02,030 --> 00:03:06,470 +على أول carbon بعد ال C double bond O احنا اتعلمنا + +31 +00:03:06,470 --> 00:03:11,090 +ان هذا ال carbon هي ال alpha carbon لكن بالتأكيد + +32 +00:03:11,090 --> 00:03:14,410 +ممكن ماتكونش على أول carbon ممكن تكون على ثاني + +33 +00:03:14,410 --> 00:03:20,940 +carbonوأجد عن إيش هنحكي؟ Beta Amino Acids على اللي + +34 +00:03:20,940 --> 00:03:26,940 +بعدها Gamma Delta فال Amino Acids ال Amino Acids + +35 +00:03:26,940 --> 00:03:33,780 +بهذا المنطق اكتار الآن اللي موجودين في البروتينات + +36 +00:03:41,580 --> 00:03:45,360 +اللي موجودين في البروتينات تحديدا هم ال alpha + +37 +00:03:45,360 --> 00:03:50,400 +amino acids يعني اللي فيهم مجموعة الأمين على ال + +38 +00:03:50,400 --> 00:03:54,000 +carbon alpha و احنا سبق عرفنا ال carbon alpha بال + +39 +00:03:54,000 --> 00:03:57,220 +acids و بال aldehydes و بال ketones قلنا هي ال + +40 +00:03:57,220 --> 00:04:01,400 +carbon المجاورة لل seed of the bond O لو كنا بنعد + +41 +00:04:01,400 --> 00:04:05,280 +بال ayobac بتكون ال alpha carbon هي ال carbon رقم + +42 +00:04:05,280 --> 00:04:09,320 +اتنين لأن احنا بنعد في ال ayobac من ال seed of the + +43 +00:04:09,320 --> 00:04:15,360 +bond Oيعني فال amino group موجودة على ال carbon + +44 +00:04:15,360 --> 00:04:19,800 +رقم اتنين او على ال carbon الفة هذا الكلام في وين؟ + +45 +00:04:19,800 --> 00:04:23,940 +في ال amino acids اللي موجودين في البروتينات لكن + +46 +00:04:23,940 --> 00:04:30,660 +لو قلنا لطالب في الامتحان الدروق general structure + +47 +00:04:30,660 --> 00:04:37,620 +for a beta amino acidهذا جيبنا سؤال مرة اوكي هي + +48 +00:04:37,620 --> 00:04:43,080 +انها C double bond O OH بنمشي بهذا الشكل هي alpha + +49 +00:04:43,080 --> 00:04:50,820 +هي beta اذا نحط ال amino group على ال carbon beta + +50 +00:04:50,820 --> 00:04:54,740 +هذا beta amino acid لو قلنا لغاها مابدوا يحطوا على + +51 +00:04:54,740 --> 00:04:59,400 +اللي بعدها واضح لكن اللي موجودين في البروتينات اي + +52 +00:04:59,400 --> 00:05:05,440 +نوع ال alpha amino acidsواضح؟ زي ما حكينا احنا ان + +53 +00:05:05,440 --> 00:05:10,080 +ال peptides عدت amino acids مع بعض و ال proteins + +54 +00:05:10,080 --> 00:05:16,040 +many amino acids مع بعض الان لما نيجي نكسر ال + +55 +00:05:16,040 --> 00:05:18,740 +protein زي ما قلنا ممكن يعطينا peptide و ال + +56 +00:05:18,740 --> 00:05:22,720 +peptide ممكن يكسره الوحدات الاولية هنصف بال ايش؟ + +57 +00:05:22,720 --> 00:05:26,700 +بال amino acids الان هذه ال amino acids ايش + +58 +00:05:26,700 --> 00:05:30,960 +مواصفاتها؟ المواصفة الاولى ان كلهم الف amino acids + +59 +00:05:31,860 --> 00:05:36,960 +الشغل التاني ان ال amino acids اللي بيطلعوا عندنا + +60 +00:05:36,960 --> 00:05:41,840 +they are optically active يعني فيهم chiral center + +61 +00:05:41,840 --> 00:05:46,140 +ما عدا واحد بيكونوا فيه المجموعتين زي بعض يعني + +62 +00:05:46,140 --> 00:05:50,480 +مافيش فيه أربع مجموعات مختلفة هذا الواحد اللي + +63 +00:05:50,480 --> 00:05:54,940 +هنتعرف عليه هو ال glycine فباقي ال amino acids + +64 +00:05:54,940 --> 00:05:59,880 +كلهم they areoptically active they contain chiral + +65 +00:05:59,880 --> 00:06:05,380 +centers فيهم chiral centers الآن بيجينا شغلة طالما + +66 +00:06:05,380 --> 00:06:09,380 +بدنا نقول chiral center متذكرين لما اتكلمنا عن ال + +67 +00:06:09,380 --> 00:06:13,620 +sugars واستبدلنا المصطلح يعني في ال biochemistry + +68 +00:06:13,620 --> 00:06:19,940 +ال R و ال S ب D و L فلما اتكلمنا عن ال sugars احنا + +69 +00:06:19,940 --> 00:06:25,630 +اتفقنا ان نحط اعلى مجموعة للأعلى اللي هي مجموعةالـ + +70 +00:06:25,630 --> 00:06:29,650 +aldehyde بعدين ال sugars بيميزها على الكربون اللى + +71 +00:06:29,650 --> 00:06:33,630 +باقى ده H و OH و بعدين بنحط rest of the molecule + +72 +00:06:33,630 --> 00:06:40,090 +الآن إذا حطينا ال OH على اليمين كنا نقول في عندنا + +73 +00:06:40,090 --> 00:06:45,150 +D و إذا حطينا على الشمال كنا نقول في عندنا L الآن + +74 +00:06:45,150 --> 00:06:49,450 +بنفس المنطق بنعمل ال amino acids لكن شو المجموعة + +75 +00:06:49,450 --> 00:06:55,600 +اللى بنحطها لأعلى؟بدل ال الديهايد مجموعة الحامض + +76 +00:06:55,600 --> 00:06:59,860 +يعني ال amino acids في حامض برسم المجموعة الحامض + +77 +00:06:59,860 --> 00:07:04,420 +هذه لأعلى الآن بعد مجموعة الحامض ال carbon Alpha + +78 +00:07:04,420 --> 00:07:11,080 +متصلة ب H و متصلة ب NH2 و متصلة ب R group تاني + +79 +00:07:11,080 --> 00:07:14,960 +يعني هي بتميز و بتخلي عدد ال amino acids infinity + +80 +00:07:14,960 --> 00:07:19,780 +ليش أنا بقول العدد infinity يعني هذا الجزء CO2 H + +81 +00:07:19,780 --> 00:07:25,700 +ثابتالـ H ثابتة، الآن الـ H2 ثابتة، الآن الـ Amino + +82 +00:07:25,700 --> 00:07:30,600 +acid عن التاني بتغيره بإيش؟ بالـ R طالما في عندي + +83 +00:07:30,600 --> 00:07:36,110 +متغيّد، الـ R ممكن تكون عدد لا نهائيواضح ال R ممكن + +84 +00:07:36,110 --> 00:07:40,210 +تكون عدد لا نهاية الان احنا بنيجي بنرسم بهذا الشكل + +85 +00:07:40,210 --> 00:07:44,470 +عشان الكل يفهم على بعضه اذا حطينا ال N H2 على + +86 +00:07:44,470 --> 00:07:49,230 +اليمين بنقول هذا D Amino Acid اذا حطينا ال N H2 + +87 +00:07:49,230 --> 00:07:54,890 +على اليسار بنقول هذا ايش ال Amino Acids الان ال + +88 +00:07:54,890 --> 00:07:59,770 +Amino Acids اللي بيطلعوا من ال proteins كلهم L مش + +89 +00:07:59,770 --> 00:08:07,980 +D هذا خلق اللههك ربنا خلقهم يعني لاحظوا أنه لما + +90 +00:08:07,980 --> 00:08:11,020 +بنيجي الحل للبروتين بنلاحظ أنه كل ال amino acids + +91 +00:08:11,020 --> 00:08:14,600 +اللي طلع عندنا Alpha amino acids وكل ال amino + +92 +00:08:14,600 --> 00:08:20,080 +acids اللي طلع عندنا ال amino acids واضح؟ الآن + +93 +00:08:20,080 --> 00:08:28,500 +بنيجي لنقطة تانية أنه طالما أن هذا ال R متغير + +94 +00:08:29,120 --> 00:08:32,920 +ممكن تاخد أي إشي أتش مثل إثالبروبيل إيزوبروبيل و + +95 +00:08:32,920 --> 00:08:37,160 +كبرو زي ما بدكم معناه ذلك من الناحية النظرية كده + +96 +00:08:37,160 --> 00:08:44,680 +اندي أمينو أسيد حتى ألفةعدد لانهائي لكن بالواقع + +97 +00:08:44,680 --> 00:08:48,680 +التجريبي لما بيعملوا hydrolysis ل ال proteins + +98 +00:08:48,680 --> 00:08:53,380 +وبيفصلوا ال amino acids اللي نشأت من تميق ال + +99 +00:08:53,380 --> 00:08:57,200 +protein و تكسره لوحدته الأولية لاحظوا ان في عندنا + +100 +00:08:57,200 --> 00:09:02,620 +عشرين amino acid هذا الكلام بسهل الشغل علينا يعني + +101 +00:09:02,620 --> 00:09:06,980 +تخيل لو كانوا الف و كل واحد بده تشخيص مشكلة لكن + +102 +00:09:08,010 --> 00:09:13,070 +بشكل عام كل بروتينات ملفة حوالين ال 20 amino acids + +103 +00:09:13,070 --> 00:09:20,010 +هدولة اللي بشكل عام موجودين في البروتينات الان من + +104 +00:09:20,010 --> 00:09:24,450 +هدولة ال amino acids العشرينعلى خلاف بسيط من + +105 +00:09:24,450 --> 00:09:29,330 +العلماء مش مشكلة خلّيني أتزم بالكلام في 12 amino + +106 +00:09:29,330 --> 00:09:33,530 +acid ممكن يتحضروا في الجسم يعني الإنسان ممكن + +107 +00:09:33,530 --> 00:09:38,390 +يحضرهم من نقطة السفر وفي 8 amino acids الجسم + +108 +00:09:38,390 --> 00:09:43,450 +بيحضرهمش طب هدولة اللي بيحضرهمش الجسم لازم ياخدهم + +109 +00:09:43,450 --> 00:09:48,890 +جاهزين من برا من وين هياخدهم؟ من الغذابةأنواع من + +110 +00:09:48,890 --> 00:09:52,750 +الغذاء فيها هذه ال amino acids الآن هدولة التمانية + +111 +00:09:52,750 --> 00:09:56,790 +amino acids that cannot be synthesized in the body + +112 +00:09:56,790 --> 00:10:00,610 +they are called essential amino acids الأحماض + +113 +00:10:00,610 --> 00:10:05,350 +الأمينية الأساسية فلما نقول إيش معنى essential + +114 +00:10:05,350 --> 00:10:09,730 +amino acids the amino acids that cannot be + +115 +00:10:09,730 --> 00:10:13,830 +synthesized in the body and must be obtained from + +116 +00:10:13,830 --> 00:10:18,390 +the dietin the form of protein لازم ناخدها من + +117 +00:10:18,390 --> 00:10:22,290 +الغذاء على شكل البروتينات، الغذاء الحيواني اللي + +118 +00:10:22,290 --> 00:10:25,850 +بنتغدأه، والغذاء النباتي، بروتينات حيوانية أو + +119 +00:10:25,850 --> 00:10:32,460 +نباتيةهدول ال amino acids العشرين بدنا نتعرف عليهم + +120 +00:10:32,460 --> 00:10:37,440 +جيدا، طبعا كل واحد له اسم، و دائما الناس بيحبوا + +121 +00:10:37,440 --> 00:10:41,920 +إيش؟ يختصروا الأسماء، يعني هيمروا علينا glycine, + +122 +00:10:41,980 --> 00:10:46,880 +alanine, cysteine, tryptophan, saline, valineاكتار + +123 +00:10:46,880 --> 00:10:52,960 +واضح؟ الان فى لهم نوعين من الاختصار فى اختصار لهم + +124 +00:10:52,960 --> 00:10:58,240 +بتلت حروف وفى اختصار لهم بحرف واحد بنسميه three + +125 +00:10:58,240 --> 00:11:03,100 +letter abbreviation اختصار الاسم لتلت حروف وفى + +126 +00:11:03,100 --> 00:11:08,140 +اننا نختصره لحرف واحد one letter abbreviation بشكل + +127 +00:11:08,140 --> 00:11:13,830 +عام اذا انا كنتربما المحاضرة السابقة قلتلكوا مشكلة + +128 +00:11:13,830 --> 00:11:20,310 +البروتينات ان they are not polymers فلازم اعمللهم + +129 +00:11:20,310 --> 00:11:24,650 +ايش؟ sequence ترتيب مين جاي اول واحد التاني التالت + +130 +00:11:24,650 --> 00:11:30,070 +الرابع الان اذا انا بدي ارسم peptide صغير يعني ال + +131 +00:11:30,070 --> 00:11:34,470 +peptide بيكون عادة تمانية تسعة عشرة خمستاشر amino + +132 +00:11:34,470 --> 00:11:39,920 +acid بستعمل three letter abbreviation واضح؟وإذا + +133 +00:11:39,920 --> 00:11:43,660 +بدى استعمل البروتين لبروتين بالمئات اللي لم يكن + +134 +00:11:43,660 --> 00:11:47,460 +بالألاف بستعمل ال one letter abbreviation فاللي + +135 +00:11:47,460 --> 00:11:52,320 +بدى يرسم ببتايد عادة بيستعمل اختصار تلت حروف اللي + +136 +00:11:52,320 --> 00:11:59,080 +بدى يرسم البروتين بيستخدم اختصار الحرف الواحد الان + +137 +00:11:59,080 --> 00:12:05,320 +لو اجينا بدنا نتعرف على هدول ال amino acids لاحظوا + +138 +00:12:05,320 --> 00:12:12,100 +ان احنا اتفقنا ان ال amino acidsفيهم أكتر من شيء + +139 +00:12:12,100 --> 00:12:16,080 +مشترك يعني مجموعة ال acid مشتركة ال carbon اللي + +140 +00:12:16,080 --> 00:12:20,960 +جنبها مشتركة و غالبا بتحمل H و أنا H2 و يمكن معادة + +141 +00:12:20,960 --> 00:12:25,420 +أمينو أسد واحد بيظل عندنا الاختلاف وين؟ في ال R + +142 +00:12:25,420 --> 00:12:30,100 +group بيظل عندنا الاختلاف في ال R group الآن بنيجي + +143 +00:12:30,100 --> 00:12:33,300 +إذا كانت ال R أبسط شيء عندنا في ال organ ال + +144 +00:12:33,300 --> 00:12:38,350 +chemistry اللي هي ال Hتمام؟ ال amino acid بيكون هو + +145 +00:12:38,350 --> 00:12:44,670 +ال glycine واضح؟ بياخد اختصارين ال gly او ال j + +146 +00:12:44,670 --> 00:12:50,930 +واضح؟ الان لاحظوا معي ال glycine تحديدا لو طلعنا + +147 +00:12:50,930 --> 00:12:55,110 +على ال carbon اللي هنا هذا ال carbon + +148 +00:12:58,040 --> 00:13:03,760 +في H و H مافيش في عليه four different groups عشان + +149 +00:13:03,760 --> 00:13:08,020 +هيك ال glycine does not contain a chiral center so + +150 +00:13:08,020 --> 00:13:12,620 +it is not a chiral molecule مش chiral optically + +151 +00:13:12,620 --> 00:13:20,990 +inactive مع ده ال glycine كلهم هيكونواthey contain + +152 +00:13:20,990 --> 00:13:24,670 +chiral centers and they are optically active الآن + +153 +00:13:24,670 --> 00:13:30,450 +نمشي بسرعة لو بدنا نشوف الحامض الأميني لبعده اللي + +154 +00:13:30,450 --> 00:13:35,850 +في مجموعة المثل أبسط المجموعات المثل بيصير اسمه + +155 +00:13:35,850 --> 00:13:38,590 +الانين لاحظوا ما تقولوش أنين + +156 +00:13:41,140 --> 00:13:45,340 +حاجة تانية في الـ aromatic compounds الانين الانين + +157 +00:13:45,340 --> 00:13:51,120 +بياخد الاختصار ال أو ا في مجموعة المثل لو كان في + +158 +00:13:51,120 --> 00:13:56,480 +مجموعة ال isopropyl بيصير اسمه valine لو كان في + +159 +00:13:56,480 --> 00:14:01,820 +مجموعة ال isobutyl بيصير اسمه ليوسين طبعا هذا ايه + +160 +00:14:01,820 --> 00:14:06,900 +الاختصار value في ال EU إذا كان في مجموعة ال + +161 +00:14:06,900 --> 00:14:13,600 +secondary butyl بيصير اسمه isoleucineواضح؟ لاحظوا + +162 +00:14:13,600 --> 00:14:17,100 +كل هذه المجموعات in principle they are simple + +163 +00:14:17,100 --> 00:14:20,560 +alkyl groups يعني كلها مرت علينا لما أخدنا ال + +164 +00:14:20,560 --> 00:14:25,240 +alkyl groups مثل بروبل مثل ايزو بروبل ايزو بيوتل + +165 +00:14:25,240 --> 00:14:29,540 +سكندر بيوتل they are simple alkyl groups هذه + +166 +00:14:29,540 --> 00:14:34,970 +المجموعة الأولى من ال amino acidsالان بعد هيك في + +167 +00:14:34,970 --> 00:14:40,950 +عندي amino acids ال R تبعتهم بتحمل OH يعني غير ال + +168 +00:14:40,950 --> 00:14:48,000 +amino و غير ال acid فيهم alcohol واضح؟فيهم ال + +169 +00:14:48,000 --> 00:14:52,160 +amino أكيد موجودة وال acid أكيد موجود هذا لا خلاف + +170 +00:14:52,160 --> 00:14:56,600 +فيه لكن يضاف اللي هو منه على ال R group في عنده + +171 +00:14:56,600 --> 00:15:04,400 +إيش ال alcohol فمنهم السيرين CH2OH ومنهم الثريونين + +172 +00:15:04,400 --> 00:15:13,350 +CHOHCH3 تمام؟بعد هيك بيجيني مجموعات فيهم كبريت + +173 +00:15:13,350 --> 00:15:21,230 +sulfur فيهم كبريت منهم الستين CH2SH ومنهم + +174 +00:15:21,230 --> 00:15:26,570 +الميثيونين CH2CH2SCH3 + +175 +00:15:26,570 --> 00:15:34,250 +طبعا هتقولوا هدولةاكتار هل يا تورا مطلوب نحفظ كلها + +176 +00:15:34,250 --> 00:15:39,850 +ال amino acids؟ لأ لكن انا بقدر اطلب منكم اي amino + +177 +00:15:39,850 --> 00:15:42,530 +acid يعني انا ممكن بعديك اجي اقولكوا ارسموا + +178 +00:15:42,530 --> 00:15:47,330 +بيبتايد من خمسة amino acids هنكون اتعلمنا انه في + +179 +00:15:47,330 --> 00:15:52,940 +هيكل مشترك و ان الاختلاف فقطفي الـ R group فلو + +180 +00:15:52,940 --> 00:15:57,740 +أتيت قلتلكوا مثلا الانين بين جثين الـR بتساوي مثل + +181 +00:15:57,740 --> 00:16:02,840 +خلاص ان عرف لإن الاختلاف بينهم بس بإيش بالمثل او + +182 +00:16:02,840 --> 00:16:09,660 +مثلا فالين R بتساوي isopropyl الأصل أنه يقدر + +183 +00:16:09,660 --> 00:16:14,960 +الإنسان يرسمه لكن على أقل تقدير على أقل تقدير بدنا + +184 +00:16:14,960 --> 00:16:21,130 +تكونوا بالتأكيد تعرفوا ال glycineالأول H الالانين + +185 +00:16:21,130 --> 00:16:31,050 +اللي هو المثل الستينالـ CH2SH الستين بالذات لأنه + +186 +00:16:31,050 --> 00:16:35,390 +بعد هيك هنلاحظ أنه له أهمية كبيرة في شكل البروتين + +187 +00:16:35,390 --> 00:16:39,610 +بيعمل داي سالفايد بونتز متذاكرين لما أخدنا الثيولز + +188 +00:16:39,610 --> 00:16:43,390 +كانوا يعملوا داي سالفايد بونتز الآن اللي مطلوبين + +189 +00:16:43,390 --> 00:16:47,530 +يعني ممكن أقولكوا أرسمولي ألانين سستين أو اعملولي + +190 +00:16:47,530 --> 00:16:51,290 +بيبتايد من السستين بدون ما أعطيكوا المجموعة خلاص + +191 +00:16:51,290 --> 00:16:54,030 +نكون عارفين أن السستين هو اللي فيه مجموعة + +192 +00:16:57,230 --> 00:17:05,070 +الألانين في مثل لجليسين في H ما عدا ذلك لو بدنا أي + +193 +00:17:05,070 --> 00:17:09,670 +شيء بس بنعطيكوا بين جثين ال R group بتقدروا تكملوا + +194 +00:17:09,670 --> 00:17:17,090 +رسم ال amino acidالآن بجينة حامض اسمه إبرولين هذا + +195 +00:17:17,090 --> 00:17:23,750 +شوية صغيرة بختلف عنهم انه مافيش فيه NH2 هو CH NH + +196 +00:17:23,750 --> 00:17:28,700 +ومسكر على ال NH2 يعني عامل حلقةيعني كل ال amino + +197 +00:17:28,700 --> 00:17:34,760 +acids لما ترسموهم هترسم مجموعة الحامض و بعدين CH و + +198 +00:17:34,760 --> 00:17:39,960 +NH2 مع ذا هذا البرولين بتكون ال NH مسكرة على باقى + +199 +00:17:39,960 --> 00:17:47,580 +الجزء بالشكل اللى موجود الان هذا البرولين ماخد + +200 +00:17:47,580 --> 00:17:51,860 +الاختصار برو او بي بجينة الفينلالانين + +201 +00:17:53,330 --> 00:17:58,250 +لاحظوا لو هذه كانت CH3، إيش اسم ال amino acid؟ + +202 +00:17:58,250 --> 00:18:03,070 +الالانين، شيلنا منها H و حطينا فينل، صار فينل + +203 +00:18:03,070 --> 00:18:08,230 +الالانين، واضح؟ يعني برضه ال فينل الالانين، لإنه + +204 +00:18:08,230 --> 00:18:13,940 +مختصر من الالانين، بصير مطلوب منهانعرفه، ليش؟ لأن + +205 +00:18:13,940 --> 00:18:18,720 +اللي عرف الألانين أن الـR تبعته CH3 لما أنا أقول + +206 +00:18:18,720 --> 00:18:23,380 +له فنل ألانين، بشيل H و بحط مجموعة الفنل، صار + +207 +00:18:23,380 --> 00:18:27,440 +الفنل ألانين، فاللي عرف الألانين وعارف من الكيميا + +208 +00:18:27,440 --> 00:18:35,530 +العامة مجموعة الفنل، بقدر يعرف الفنل ألانينبيجينا + +209 +00:18:35,530 --> 00:18:39,310 +الـ Tyrosine في هذه المجموعة CH2 في الـ OH لـ + +210 +00:18:39,310 --> 00:18:44,950 +tryptophan في حلقة كبيرة بنسميها Endol مع CH2 مش + +211 +00:18:44,950 --> 00:18:53,640 +مطموض نحفظهم طبعا، الآن في مجموعة أحماض فيهممجموعة + +212 +00:18:53,640 --> 00:18:58,660 +حمب تانية يعني غير ال acid group و ال amino group + +213 +00:18:58,660 --> 00:19:02,400 +اللي هم أساسيات هدولة لاحظوا اللي رسمينهم بالأزرق + +214 +00:19:02,400 --> 00:19:06,600 +في كل الرسمات يعني هدولة مشتركين بيجي في ال R + +215 +00:19:06,600 --> 00:19:11,460 +group نفسها مجموعة حمب تانية يعني غير هذه CO2H + +216 +00:19:11,460 --> 00:19:15,080 +تبعت ال amino acid في هنا كمان مجموعة تانية يعني + +217 +00:19:15,080 --> 00:19:19,380 +صار CH2COOH فصار في another + +218 +00:19:22,610 --> 00:19:28,750 +هدولة منهم الحمض الأول CH2COH اسمه Aspartic Acid و + +219 +00:19:28,750 --> 00:19:34,900 +لو كان مجمعتين CH ورا بعض بيصير Glutamic Acidلو + +220 +00:19:34,900 --> 00:19:39,280 +كان مشتق من الأحماض تذكروا لما أخدنا الأحماض قولنا + +221 +00:19:39,280 --> 00:19:43,580 +assets and their derivatives و منها الأمد و ما إلى + +222 +00:19:43,580 --> 00:19:49,060 +ذلك فلو كان بهذا الشكل ماخد شكل الأمد بيكون اسمه + +223 +00:19:49,060 --> 00:19:55,460 +أسبارجين و لو كان أمد بزيادة CH2 يعني بيصير + +224 +00:19:55,460 --> 00:20:00,700 +glutamine بيصير glutamine لحظةبتقدروا تشوفوا ال + +225 +00:20:00,700 --> 00:20:05,160 +glutamic acid كربونتين CH2 CH2 وبعدين حامض ل + +226 +00:20:05,160 --> 00:20:10,080 +glutamine CH2 CH2 وبعدين الأمد تبعه لذلك إيش سموه + +227 +00:20:10,080 --> 00:20:16,680 +glutamine إله اختصار الآن في أحماض تانية فيهم غير + +228 +00:20:16,680 --> 00:20:23,230 +ال NH2 هذه مجموعة NH2 تانية مش أمد أمينلحظوا الـ + +229 +00:20:23,230 --> 00:20:27,650 +NH2 الأمد بتخلف عن الأمين يعني هذه أمد وقلنا عنها + +230 +00:20:27,650 --> 00:20:33,050 +unreactive group متذكرين لما أخدنا الأمد قلنا انه + +231 +00:20:33,050 --> 00:20:38,230 +unreactive لأ في بيكون فيهم أمين عادية NH2 تانية + +232 +00:20:38,230 --> 00:20:44,640 +منهم اللايسين بالشكل اللي موجود منهم الارجينينفيه + +233 +00:20:44,640 --> 00:20:49,380 +أكثر من NH ومنهم الهستيدين هي أنا بتلاحظوا برضه + +234 +00:20:49,380 --> 00:20:58,080 +فيه NH NH NH أو NH2 هذي كلها amino acids فزي ما + +235 +00:20:58,080 --> 00:21:02,680 +بتلاحظوا انه بتصنيف ال amino acids التركيز على + +236 +00:21:02,680 --> 00:21:06,220 +إيش؟ على ال R group يعني ال R ممكن تكون simple + +237 +00:21:06,220 --> 00:21:10,960 +alkyl groupممكن تحتوي على OH ممكن تحتوي على + +238 +00:21:10,960 --> 00:21:16,680 +مجموعات aromatic ممكن تحتوي على مجموعة حمضية تانية + +239 +00:21:16,680 --> 00:21:22,480 +ممكن تحتوي على مجموعة قاعدية تانية واضح هذا + +240 +00:21:22,480 --> 00:21:31,670 +بالنسبة للتعريف بال amino acids بشكل عامالان لو + +241 +00:21:31,670 --> 00:21:36,310 +اجينا بدينا في ال acid-base properties لل amino + +242 +00:21:36,310 --> 00:21:45,450 +acids ال amino acids هم خليط من حمض و قاعدة ماشي + +243 +00:21:45,450 --> 00:21:51,850 +ال amino group is a basic group لما درسناها و أبسط + +244 +00:21:51,850 --> 00:21:57,700 +basic group منها ال ammoniaتحمل زوج إلكترونات + +245 +00:21:57,700 --> 00:22:05,040 +وجاهز إنها تستقبل إيش بروتون والأحماض acids الآن + +246 +00:22:05,040 --> 00:22:12,340 +لو أنا بشكل منفصل إجيت قلتلكم حمض زائد قاعدة يعني + +247 +00:22:12,340 --> 00:22:20,860 +HCL زائد أمونيا أو acetic acid زائد أمونياماشي + +248 +00:22:20,860 --> 00:22:26,360 +الحمض مع القاعدة بتفاعل وش بيعطوني ملح و ماء ممتاز + +249 +00:22:26,360 --> 00:22:32,060 +جدا الان في ال amino acids الحمض و القاعدة نوجدوا + +250 +00:22:32,060 --> 00:22:39,960 +في جزء واحد واضح ال amino group basic و ال COOH + +251 +00:22:39,960 --> 00:22:48,510 +acidic ال amino group بتحب تكتسببروتون هاي معناه + +252 +00:22:48,510 --> 00:22:54,950 +base و COH بتفقد بروتون طب هدول اتنين انحطوا في + +253 +00:22:54,950 --> 00:23:02,350 +جزء واحد اذا بالوضع الطبيعي تلقائيا بيعملوا تفاعل + +254 +00:23:02,350 --> 00:23:06,870 +داخلي طالما انه انوجد ال acidic group و ال basic + +255 +00:23:06,870 --> 00:23:11,110 +group بنفس الجزء بيعملوا التفاعل بينهم و بين بعض + +256 +00:23:11,110 --> 00:23:17,010 +المجموعة الحامضية بتفقد ال H و مين بيكتسبهالقاعدة + +257 +00:23:17,010 --> 00:23:24,310 +و لذلك بالوضع الطبيعي هذا الحامض بدل ما يكون C + +258 +00:23:24,310 --> 00:23:30,930 +double bond O OH بيفقد ال H بيصير CO2 minus يعني C + +259 +00:23:30,930 --> 00:23:35,870 +double bond O O minus لأن ال H اللي فقدها هنا مين + +260 +00:23:35,870 --> 00:23:42,730 +بده يتسبها القاعدة بدل ما هي NH2 بتصير NH3 plus + +261 +00:23:43,440 --> 00:23:49,180 +واضح؟ وبناء على ذلك في الوضع الطبيعي المتعدل ال + +262 +00:23:49,180 --> 00:23:56,460 +amino acids ما برسموهش بهذا الشكل يعني RCHC + +263 +00:23:56,460 --> 00:24:03,800 +double bond O OH هنا ال N H2بنرسمه مش زيك، بنقول + +264 +00:24:03,800 --> 00:24:08,220 +هذا حامض بده يفقد، هذه قاعدة بده تكتسب، وقاعدين + +265 +00:24:08,220 --> 00:24:11,920 +جان بعض، شو اللي بيمنعهم يفقدوا ويكتسبوا؟ بناء على + +266 +00:24:11,920 --> 00:24:17,380 +ذلك، بيتم إنه هذه بتفقد منها، وبتيجي وين؟ على هذا + +267 +00:24:17,380 --> 00:24:21,560 +الوضع، ففي ال neutral form حقيقة ما بنوجدش ال + +268 +00:24:21,560 --> 00:24:25,720 +amino acids بهذا الشكل، لأ بنوجد بهذا الشكل، فقد + +269 +00:24:25,720 --> 00:24:31,940 +لبروتون منها، واكتسبته إيش؟الـ Base واضح؟ و الآن + +270 +00:24:31,940 --> 00:24:37,460 +هذا الشكل بنقول عنه احنا Dipolar Ionic Form يعني + +271 +00:24:37,460 --> 00:24:43,820 +شكل فيه قطبين و بياخد اسم تاني جاي من الألماني + +272 +00:24:43,820 --> 00:24:47,900 +Zwitter Ionic Zwitter اش يعني Zwitter؟ + +273 +00:24:51,140 --> 00:24:57,060 +سفيتر ionic form هذا المصطلح بيمر معاكم كتير سفيتر + +274 +00:24:57,060 --> 00:25:04,310 +من svay svay بالالماني معناها إيش؟اتنين, zwei يعني + +275 +00:25:04,310 --> 00:25:08,630 +اتنين يعني لما احنا بنعد بالعرب ايش بنقول؟ واحد, + +276 +00:25:08,690 --> 00:25:12,970 +اتنين, تلاتة, اربعة و بالانجليزي one, two, three, + +277 +00:25:13,170 --> 00:25:17,870 +four بالالماني eins, zwei, drei, vier, fünf, + +278 +00:25:18,030 --> 00:25:22,690 +sechs, sieben, acht, neun, zehn ف zwei يعني اتنين + +279 +00:25:22,690 --> 00:25:29,300 +فمنها ايجاZwitter Ionic لحظة دي بتنقرق Z و هذه ال + +280 +00:25:29,300 --> 00:25:37,440 +W V مش Zwitter لأ Zwitter واضح ال W الألمان شو + +281 +00:25:37,440 --> 00:25:44,760 +بيقرؤوها V و ال V إيش بيقرؤوها F عشان هيك اللي + +282 +00:25:44,760 --> 00:25:47,760 +عندهم السيارة هذه ال Volkswagen + +283 +00:25:50,020 --> 00:25:53,000 +إذا بدهم يقرؤوها بلغة الإنجليز بدهم يقرؤوا + +284 +00:25:53,000 --> 00:25:59,240 +Volkswagen بس هي باللغة الألمانية Volkswagen ال V + +285 +00:25:59,240 --> 00:26:06,880 +تقرأ F و ال W V Volkswagen Volkswagen يعني سيارة و + +286 +00:26:06,880 --> 00:26:10,240 +Volkswagen شعب + +287 +00:26:10,240 --> 00:26:15,080 +يعني تاكس الشعب سيارة الشعب سيارة البسيطة عارفينهم + +288 +00:26:15,080 --> 00:26:19,870 +ال Volkswagen اللي منهم الباصات و ال ..هذه + +289 +00:26:19,870 --> 00:26:23,650 +السيارات الكتيرة Volkswagen هذي svitar ionic + +290 +00:26:23,650 --> 00:26:30,430 +structure فلو سألناكم ان ال amino acids are better + +291 +00:26:30,430 --> 00:26:35,710 +represented by a dipolar ion structure معناه + +292 +00:26:35,710 --> 00:26:39,970 +dipolar ion structure svitar ionic structure عرفنا + +293 +00:26:39,970 --> 00:26:43,610 +ايش معناه هذا المصطلح؟ بتكرر كتير معكم بالمناسبة + +294 +00:26:44,390 --> 00:26:49,590 +تمام هذا الوضع في الـ neutral form طيب لو اجينا ال + +295 +00:26:49,590 --> 00:26:54,550 +amino acid احنا حطينا عليه H plus يعني زدناله H + +296 +00:26:54,550 --> 00:27:00,050 +plus من الخارج يعني بدون ما نحطله لا H plus ولا OH + +297 +00:27:00,050 --> 00:27:05,510 +minus يعني نسيبه زي ما هو هو حل مشكلته لحاله فقد H + +298 +00:27:05,510 --> 00:27:10,170 +من جهة و حطه بجهة تانية واضح؟و هذا الكلام كله في + +299 +00:27:10,170 --> 00:27:13,190 +الـ neutral form ماضفناش عليه إش بالبرا طب لو ضفنا + +300 +00:27:13,190 --> 00:27:19,450 +له H plus إضافية وين هتروح الـ H plus؟ على ال O + +301 +00:27:19,450 --> 00:27:24,490 +minus و لذلك لو ضفنا H plus هيصير بهذا الشكل الآن + +302 +00:27:24,490 --> 00:27:29,250 +لاحظوا لما أنا ضفت له H plus هذا متعادل ليش؟ لأنه + +303 +00:27:29,250 --> 00:27:34,110 +في موجب و سالب جد بعض الآن متعادل زاد H plus + +304 +00:27:34,110 --> 00:27:40,700 +متعادل زاد موجبأيش المحصلة موجب فهي لما فعلنا إجت + +305 +00:27:40,700 --> 00:27:45,580 +ال H plus اللي ضفناها هنا H plus عدلة ال O minus + +306 +00:27:45,580 --> 00:27:51,640 +دلوا موجب فبال acidic form بيكون ال amino acids + +307 +00:27:52,780 --> 00:27:57,480 +موجبة إيش شحنتها موجبة لاحظوا هذه الأسئلة اللي + +308 +00:27:57,480 --> 00:28:00,980 +بتكونوا تسألوها انتوا بالصح و الغلط in acidic + +309 +00:28:00,980 --> 00:28:09,320 +medium the amino acids are positive واضح amino + +310 +00:28:09,320 --> 00:28:14,530 +acid at low pH ال low pH معناهاacidic ايش بيكونوا؟ + +311 +00:28:14,530 --> 00:28:19,170 +positive الان لو افترضنا هذا ال amino acid بعد ما + +312 +00:28:19,170 --> 00:28:23,670 +حطينا عليه حامض بزيادة وصار موجب اجينا بدينا بدنا + +313 +00:28:23,670 --> 00:28:28,510 +نسحب منه ال Hات كيف بنسحبهم؟ شو اللي بيسحب ال H + +314 +00:28:28,510 --> 00:28:33,870 +plus؟ OH minus فلو فعلت أنا مع OH minus هتيجي تسحب + +315 +00:28:33,870 --> 00:28:39,950 +هذه اللي اجت OH minus مع ال H؟ هتعطيني H2O و هيرجع + +316 +00:28:39,950 --> 00:28:49,700 +للوضع؟المتعادل طب لو زته كمان OH minus هياخد هذه + +317 +00:28:50,900 --> 00:28:55,760 +هياخد القدش اللي زي دهانة، شو هيصير؟ سالب فبناء + +318 +00:28:55,760 --> 00:29:01,180 +على ذلك بيصير عند أنا قاعدة بسيطة كتير ان ال amino + +319 +00:29:01,180 --> 00:29:08,940 +acids في الوسط الحامضي بيكونوا مجابين، في الوسط + +320 +00:29:08,940 --> 00:29:17,250 +القاعدي بيكونوا سالبين، واضح؟ سالبو طبعا بدون ما + +321 +00:29:17,250 --> 00:29:21,550 +نضيف عليهم من برا لا حمض ولا قاعدة بيكونوا إيش؟ + +322 +00:29:21,550 --> 00:29:30,150 +neutral بس في zwitterionic form واضح؟ في شكل ثنائي + +323 +00:29:30,150 --> 00:29:33,050 +القطبية، هاي معناه zwitterionic form + +324 +00:29:38,320 --> 00:29:43,320 +هي هنا كمان مثال تأكيدي تماما للمثال السابق هو + +325 +00:29:43,320 --> 00:29:50,620 +أعطاني amino acid موجة طبعا بدناش ننسا احنا شغلة + +326 +00:29:50,620 --> 00:29:54,440 +انه فيش اشي في الدنيا .. فيش اشي في الدنيا بنباع + +327 +00:29:55,130 --> 00:29:59,910 +موجب أو سالب يعني لما هنا كنا نقولكوا اضيفوا H + +328 +00:29:59,910 --> 00:30:04,390 +plus مافيش H plus بتنجب لحالها و بتلبعها عادة لما + +329 +00:30:04,390 --> 00:30:08,230 +نقول اضيف H plus من وين بنجيبها؟ من HCL يعني كان + +330 +00:30:08,230 --> 00:30:13,210 +في معاه CL minus وبناء على ذلك لما هذه عملة الايون + +331 +00:30:13,210 --> 00:30:20,210 +الموجب كل هذا الجزء الموجب كان فيله CL minus مرافق + +332 +00:30:21,300 --> 00:30:27,000 +واضح؟ لكن أنا كنت مختصر الـCl- كده لأن أنا مهتم + +333 +00:30:27,000 --> 00:30:30,860 +بجزء الـ amino acid مش بالجزء التاني، واضح؟ بس + +334 +00:30:30,860 --> 00:30:34,460 +مافيش H بلس في الكون بتلبع لحالها، يعني الـH بلس + +335 +00:30:34,460 --> 00:30:38,100 +جاية من وين؟ من acid، خلّيني أقول HCl، فلو كنت + +336 +00:30:38,100 --> 00:30:44,560 +أعطي الـHCl، حيكون هذا موجة ومعه Cl ثالث، الآن لو + +337 +00:30:44,560 --> 00:30:49,620 +أخدنا مثل، هاي الـ amino acid الالانينفى nh3 plus + +338 +00:30:49,620 --> 00:30:54,560 +cl minus لما نيجى نفعله مع ال N A O H شو اللى بدى + +339 +00:30:54,560 --> 00:31:03,480 +يصير ال O H minus بدى تاخد ال H شو عملت ليه H 2 O + +340 +00:31:03,480 --> 00:31:06,680 +ال N A plus مع ال C L minus + +341 +00:31:11,850 --> 00:31:20,330 +الحمض يبقى في وضعه نيوترال وليس جابوسالد الاسفتر + +342 +00:31:20,330 --> 00:31:25,170 +ايونيك نيوترال الان هذا نفسه نيوترال لو اجينا كمان + +343 +00:31:25,170 --> 00:31:34,480 +مرة زدناله NAOH شو حيصير ال OH- هتاخدوحدة من هدولة + +344 +00:31:34,480 --> 00:31:41,100 +ال H's هتعطيني H2O هيصير بناء على ذلك هذي أنا H2 + +345 +00:31:41,100 --> 00:31:45,860 +متعادلة بس أنا في عندى minus ال minus بالزمعيون + +346 +00:31:45,860 --> 00:31:46,620 +مرافق + +347 +00:31:50,390 --> 00:31:54,910 +فهذه المعادلات الحقيقة بلزم انكوا تتدربوا عليها + +348 +00:31:54,910 --> 00:31:58,710 +كيف ان ال amino acid بيكتسب بروتون كيف بيفقد + +349 +00:31:58,710 --> 00:32:02,870 +بروتون من خلال التفاعل مع حامض بيكتسب بروتونات من + +350 +00:32:02,870 --> 00:32:07,070 +خلال التفاعل مع القاعدة بيفقد بروتونات ما لم + +351 +00:32:07,070 --> 00:32:10,670 +تكتبوا و تتدربوا بهدوء على هذه المعادلات مش + +352 +00:32:10,670 --> 00:32:14,830 +هتتقنوا يعني مرات بنجيبلكوا أكمل المعادلات زي هيك + +353 +00:32:14,830 --> 00:32:20,270 +حطيلكوا amino acidع شكل Salt يعني كنا ضايفينله + +354 +00:32:20,270 --> 00:32:26,030 +أساسا HCL فعلوه مع NUH مرة أو مرتين يعني بنسبة + +355 +00:32:26,030 --> 00:32:31,490 +واحد او بنسبة اتنين اول NUH بتواصلنا لهنا تاني + +356 +00:32:31,490 --> 00:32:38,510 +فاعل واضح هذا الكلام وظيفة الطالب انه يتدرب عليه + +357 +00:32:38,510 --> 00:32:46,720 +الانمن الكلام هذا كله هنيجي لمحصلة مهمة جدا + +358 +00:32:46,720 --> 00:32:50,640 +المحصلة المهمة جدا احنا قلنا انه في ال acidic + +359 +00:32:50,640 --> 00:32:54,440 +condition + +360 +00:32:54,440 --> 00:33:00,560 +يعني في موضع حامض ال amino acid شو بيكون موجب و في + +361 +00:33:00,560 --> 00:33:09,680 +basic condition سالب طبعا معنى acidic low pHالان + +362 +00:33:09,680 --> 00:33:15,940 +كون ال amino acid صار ممكن يكون موجود + +363 +00:33:17,410 --> 00:33:22,230 +متعادل الـ zwitterionic يعني فيه الموجب والسالب أو + +364 +00:33:22,230 --> 00:33:28,450 +بس فيه كأمينو أسد الموجب أو بس فيه كأمينو أسد + +365 +00:33:28,450 --> 00:33:34,790 +السالب هذا الكلام بيوفرلي تقنية لفصل إيش ال amino + +366 +00:33:34,790 --> 00:33:41,670 +acids قبل ما نصل لهذا الكلام خلينا نقول ان ال BH + +367 +00:33:45,180 --> 00:33:50,480 +اللي بيكون عندها ال amino acid neutral سبعة .. + +368 +00:33:50,480 --> 00:33:54,360 +بنسميها .. لأ مش سبعة مختلفة .. مختلفة لأن ال + +369 +00:33:54,360 --> 00:33:59,320 +amino acid نفسه في مجموعات بتخليه acidic و basic + +370 +00:33:59,320 --> 00:34:04,060 +إضافية ال BH اللي بيكون عندها neutral ال amino + +371 +00:34:04,060 --> 00:34:08,120 +acid خلينا نقول هيك ال BH اللي بيكون عندها ال + +372 +00:34:08,120 --> 00:34:13,390 +amino acid إيش؟الـ neutral بتقول عنها الـ + +373 +00:34:13,390 --> 00:34:18,830 +isoelectric point واضح فال isoelectric point اللي + +374 +00:34:18,830 --> 00:34:24,550 +هي ال pH اللي بيكون عندها ال amino acid متعدل + +375 +00:34:24,550 --> 00:34:30,990 +isoelectric point الان كل amino acid له + +376 +00:34:30,990 --> 00:34:37,130 +isoelectric point خاصة فيه لكل ال amino acids + +377 +00:34:38,900 --> 00:34:43,840 +هتلاحظوا ان الـ isoelectric point تبعتهم موجودة في + +378 +00:34:43,840 --> 00:34:50,100 +الجدوة المحطوطة بين جثين يعني اتطلعوا للجليسين وين + +379 +00:34:50,100 --> 00:34:54,840 +بيكون ال amino acid متعادل بالسفتر ايونك and BH؟ + +380 +00:34:54,840 --> 00:35:01,320 +ستة للالانين ستة للفالين ستة للسيرين مثلا خمسة + +381 +00:35:01,320 --> 00:35:09,930 +وسبعة للستين خمسةمجيوسة الان لاحظوا لما يكون عند + +382 +00:35:09,930 --> 00:35:14,930 +انا بعض ال amino acids فيهم مجموعة حمضية تانية + +383 +00:35:14,930 --> 00:35:20,330 +بتصير ال isoelectric point منخفضة بتصير تلاتة يعني + +384 +00:35:20,330 --> 00:35:23,550 +بيقاتش تلاتة بيكونوا متعادلين لما يكون فيهم مجموعة + +385 +00:35:23,550 --> 00:35:27,350 +قاعدية تانية بتصير ال isoelectric point عقلهم عالي + +386 +00:35:27,350 --> 00:35:33,490 +عند تسعة وعند عشرة تقريبا واضح فكل amino acid الان + +387 +00:35:34,530 --> 00:35:39,990 +بنفهم ان هو له isoelectric point ال بي اتش اللى + +388 +00:35:39,990 --> 00:35:46,430 +بيكون عندها متعادل الان اقل من ال isoelectric + +389 +00:35:46,430 --> 00:35:54,210 +point هذه ال بي اتش ايش بيصير موجب اعلى منها سالب + +390 +00:35:54,210 --> 00:35:58,810 +يعني صار في عند انا ال isoelectric point لل amino + +391 +00:35:58,810 --> 00:36:08,130 +acid ال isoelectric pointالآن هذه neutral أقل منها + +392 +00:36:08,130 --> 00:36:17,310 +موجب أعلى منها سالف واضح؟ وبناء على ذلك لو أنا جيت + +393 +00:36:17,310 --> 00:36:22,750 +سألت مثلا للستين شو ال isoelectric point قبل شوية + +394 +00:36:22,750 --> 00:36:29,560 +حكيناها ستةلسستين ستة الان لو سألتكم و قولتلكم + +395 +00:36:29,560 --> 00:36:35,880 +السستين عند بي اتش اربعة شو بيكون موجب السستين عند + +396 +00:36:35,880 --> 00:36:41,620 +بي اتش تسعة او تمانية سالب واضحهذه معناه الكلام + +397 +00:36:41,620 --> 00:36:49,000 +يعني BH6 الستين ال neutral بيكون + +398 +00:36:49,000 --> 00:36:55,120 +موجب ال BH أعلى بيكون H سالب الآن هذا الموضوع أن + +399 +00:36:55,120 --> 00:37:00,200 +ال amino acid ممكن نتحكم فيه يعني الستين أنا + +400 +00:37:00,200 --> 00:37:05,620 +بتغيير ال BH قاعد بقدر أخليه مرة يكون موجب مرة + +401 +00:37:05,620 --> 00:37:10,240 +يكون متعادل مرة يكون سالب ولا لأأنا اللي بتحكم في + +402 +00:37:10,240 --> 00:37:13,400 +ال بي أتش كيف الواحد بتحكم في ال بي أتش بيحط حمض + +403 +00:37:13,400 --> 00:37:17,540 +أو قاعدة أو بزيدها أو بنجسها يعني قمر سهل عمليا + +404 +00:37:17,540 --> 00:37:24,940 +فكأنه ال بي أتش صار إلها إشي تابع إنه يكونموجب أو + +405 +00:37:24,940 --> 00:37:29,820 +سالب الآن جثة الموجب والسالب كتير بتفرج معناه ليش؟ + +406 +00:37:29,820 --> 00:37:35,560 +لأنه أخدوا منها .. من فكرتها تقنية عامة لفصل ال + +407 +00:37:35,560 --> 00:37:41,380 +amino acids عن بعضهم البعض الموجبلو حطيته في مجال + +408 +00:37:41,380 --> 00:37:45,780 +كهربائي، في موجة بوسالب، هيروح وين؟ على السالب، + +409 +00:37:45,780 --> 00:37:51,400 +والسالب هيروح وين؟ على الموجب، وبناء على ذلك هذا + +410 +00:37:51,400 --> 00:37:55,500 +الكلام بيصير أساس لطريقة، لفصل + +411 +00:37:58,240 --> 00:38:01,600 +الأمينو أسد هي أنا تعريف ال isoelectric point بس + +412 +00:38:01,600 --> 00:38:06,220 +عشان تكونوا متذكرينها is the pH at which the amino + +413 +00:38:06,220 --> 00:38:09,520 +acid will be dipolar and have in it its charge + +414 +00:38:09,520 --> 00:38:14,780 +equal to zero الأن لما يكون ديبولر و شحنته سفر لو + +415 +00:38:14,780 --> 00:38:18,920 +حطيته بوسط كهربا يعني حاطيت قطبين كهربا موجب و + +416 +00:38:18,920 --> 00:38:23,710 +سالبو ال بي اتش تبعته ع ال isoelectric point يعني + +417 +00:38:23,710 --> 00:38:28,710 +هو متعادل بيروح يمين ولا شمال ولا بيقعد مكانه الان + +418 +00:38:28,710 --> 00:38:34,550 +لو كانت ال بي اتش قليلة بمعنى كان موجب و وجدت وين + +419 +00:38:34,550 --> 00:38:38,830 +هيروح الموجب؟ على السالب على ال cathode و لو كانت + +420 +00:38:38,830 --> 00:38:43,990 +ال بي اتش عالية كان سالب وين هيروح السالب؟ على ال + +421 +00:38:43,990 --> 00:38:49,960 +anode مش ال anode هو القطبالموجب والكثود هو القطب + +422 +00:38:49,960 --> 00:38:55,600 +السالق وبناء على ذلك بتصير هذه طريقة يمكن من + +423 +00:38:55,600 --> 00:39:01,120 +خلالها ان نفصل ال amino acids عن بعض بنسميها ال ال + +424 +00:39:01,120 --> 00:39:03,260 +Electrophoresis + +425 +00:39:04,140 --> 00:39:07,140 +و هذه طريقة أساسية للناس اللي بيشتغلوا في الكيميا + +426 +00:39:07,140 --> 00:39:10,780 +في البروتينات و في ال amino acids بفصلوا من خلالها + +427 +00:39:10,780 --> 00:39:15,880 +هي فصل ال amino acids و فصل لبروتينات كهربيا + +428 +00:39:15,880 --> 00:39:22,080 +اعتمادا على ايش على شحنتهم الان شحنتهم تعتمد على + +429 +00:39:22,080 --> 00:39:28,540 +ال BH اذا انا بقدر اقول هو فصل كهربي لل amino + +430 +00:39:28,540 --> 00:39:33,400 +acids او لبروتينات اعتمادا على ال BH في المحصلة + +431 +00:39:34,600 --> 00:39:38,380 +واضح؟ هو الفصل اعتمادا على الشحنة انه يروح اشمال + +432 +00:39:38,380 --> 00:39:47,160 +او يمين، لكن الشحنة معتمدة على الـ BH ناخد مثالهذا + +433 +00:39:47,160 --> 00:39:50,120 +اللي سمناه الـ Electrophoresis is a method for + +434 +00:39:50,120 --> 00:39:53,620 +separating amino acids and proteins based on their + +435 +00:39:53,620 --> 00:39:58,380 +charge differences طبعا الـ isoelectric point عادة + +436 +00:39:58,380 --> 00:40:02,980 +بيعتور رمز بي لو قلنا ال isoelectric point + +437 +00:40:02,980 --> 00:40:10,460 +للأسبارتك أسد تلاتة تمام؟ الآن دائما جربوا أنتوا + +438 +00:40:10,460 --> 00:40:17,020 +ارسموا زي خط الأعدادتمام؟ الآن هذه الـ isoelectric + +439 +00:40:17,020 --> 00:40:24,380 +point للأسبارتك أسد اللي تلاتة عند BH تلاتة شو + +440 +00:40:24,380 --> 00:40:29,380 +بيكون الأسبارتك أسد؟ neutral بناء على ذلك لو حطينا + +441 +00:40:29,380 --> 00:40:35,640 +الأسبارتك أسد على BH3 و في وسطكهربائي كسودوانوت + +442 +00:40:35,640 --> 00:40:40,880 +هيتحرك؟ لأ هو الان بيجي بيسألني بيقول يا تورا على + +443 +00:40:40,880 --> 00:40:47,360 +BH5 وين هيروح؟ على الموجة الان انتبهوا معاه إيش + +444 +00:40:47,360 --> 00:40:51,840 +اللي عملوا قال طيب لو مخلوط عندي حامضين أسبارتك + +445 +00:40:51,840 --> 00:40:57,240 +أسد خلينا هيك نقول هذا الأسبارتك أسد ال BH ال + +446 +00:40:57,240 --> 00:41:02,900 +isoelectric point تبعته تلاتة مخلوط مع الألانين + +447 +00:41:05,540 --> 00:41:09,620 +القلانين عارفينه القلانين؟ قداش للقلانين ال + +448 +00:41:09,620 --> 00:41:18,120 +isoelectric point؟ ستة من الجدول ستة واضح؟ شفتوها؟ + +449 +00:41:19,750 --> 00:41:25,710 +الالانين عند ستة بيكون متعادل، بتفرج على حاله، صح؟ + +450 +00:41:25,710 --> 00:41:31,530 +والاسبارتك أسد عند تلاتة بيكون متعادل، بتفرج على + +451 +00:41:31,530 --> 00:41:36,390 +حاله، الآن لو إجيت قلت أطلع الاسبارتك أسد لوحده، + +452 +00:41:36,390 --> 00:41:43,230 +فوق التلاتة، شو بيكون؟ سالد، تحت التلاتة؟ موجب، لو + +453 +00:41:43,230 --> 00:41:45,250 +إجيت على الالانين + +454 +00:41:49,340 --> 00:41:56,080 +لو إجيت على الأنانين تحت الستة موجب فوق الستة سالب + +455 +00:41:56,080 --> 00:42:01,580 +الآن لو إجيت هدول الاتنين بدي أفصلهم عن بعض بضلني + +456 +00:42:01,580 --> 00:42:09,040 +أغير ال bh تغيير ذكي خليني أقول وصلت ال bh لخمسة + +457 +00:42:09,040 --> 00:42:15,340 +صار كل المحلول ال bh تبعته خمسة الآن قولولي أنتوا + +458 +00:42:15,340 --> 00:42:21,310 +عند خمسة شو بده يكون ال aspartic acid؟سالب فوق + +459 +00:42:21,310 --> 00:42:29,710 +التلاتة سالب واضح هيك موجب و عند ستة شو بده يكون + +460 +00:42:29,710 --> 00:42:34,150 +القلانين متعادل + +461 +00:42:34,150 --> 00:42:39,950 +عند ستة أقل من ستة موجب أعلى من ستة سالب الآن لما + +462 +00:42:39,950 --> 00:42:47,400 +أجي أقولكوا عند الخمسة هناتطلعوا معي الألانين موجب + +463 +00:42:47,400 --> 00:42:52,300 +الأسبارتك أسد سالب بناء على ذلك هذا الخليط لو + +464 +00:42:52,300 --> 00:42:56,500 +اتحكمت في ال بي اتش تبعته خليتها خمسة و حطيت له + +465 +00:42:56,500 --> 00:43:01,580 +قطبين كهربا وين هيروح الأسبارتك أسد على قطب الموجب + +466 +00:43:01,580 --> 00:43:05,700 +وين هيروح الألانين على قطب السالب انفصلوا عن بعض + +467 +00:43:05,700 --> 00:43:12,460 +ولا لأبنفصله طالما طلع هنا مختلف إذا بينفصله طيب + +468 +00:43:12,460 --> 00:43:17,780 +الآن انتبهوا معي جيدا حتى نفهم الطريقة بالظبط طبعا + +469 +00:43:17,780 --> 00:43:20,460 +احنا قولنا ال aspartic acid فوق التلاتة إيه شو بده + +470 +00:43:20,460 --> 00:43:26,040 +يكون؟ تلاتة و ال alanine تحت الستة شو بده يكون؟ + +471 +00:43:26,040 --> 00:43:32,160 +موجة موجة الآن الإنسان اللي مش ذكي و بده يفصل هدول + +472 +00:43:32,160 --> 00:43:42,040 +عن بعضبنقوله اخترنا بي اتش مناسبة للفصل اذا حد اجى + +473 +00:43:42,040 --> 00:43:46,600 +جال انا والله بدي اخلي ال بي اتش تبعتهم اتنين ايش + +474 +00:43:46,600 --> 00:43:51,020 +رأيكوا؟ اتطلعوا + +475 +00:43:51,020 --> 00:43:54,780 +عما عند التنين، التنين موجبين، مش هيفصلوا + +476 +00:43:57,210 --> 00:44:01,510 +الان لو اجه واحد قال لأ و الله انا بدي افصلهم عند + +477 +00:44:01,510 --> 00:44:07,370 +BH تمانية اتنين سالب اذا اللي بده يختار ال BH + +478 +00:44:07,370 --> 00:44:12,850 +المناسبة لفصلهم لازم يختارها بين إيش؟ في المنطقة + +479 +00:44:12,850 --> 00:44:16,620 +اللي بيختلفوا فيهاشفتوا كيف لما بنفصل two amino + +480 +00:44:16,620 --> 00:44:23,400 +acids عن بعض بحط خط الأعداد باجلة الأول بعمل موجب + +481 +00:44:23,400 --> 00:44:27,940 +أقل من ال isoelectric point سالب أكتر باجلة التاني + +482 +00:44:27,940 --> 00:44:32,700 +نفس الاشي هاي ال isoelectric point أقل منها موجب + +483 +00:44:32,700 --> 00:44:38,500 +أكتر منها سالب الآن ال BH اللي بتفصل اللي بيختلفوا + +484 +00:44:38,500 --> 00:44:45,010 +فيهايعني أي BH بين التلاتة والستة بيكون فيها هذا + +485 +00:44:45,010 --> 00:44:49,890 +سالب وبيكون فيها هذا موجب تصبح للفصل لكن لو قولت + +486 +00:44:49,890 --> 00:44:53,550 +أقل من التلاتة التانين موجبين لو قولت أعلى من + +487 +00:44:53,550 --> 00:44:59,590 +الستة التانين سالبين ولذلك لما نعطي مثال ونقول + +488 +00:44:59,590 --> 00:45:04,470 +choose the appropriate BH for separating this + +489 +00:45:04,470 --> 00:45:12,380 +mixtureبدي أرسم خط الأعداد بيصير الأمر سهل جدا، + +490 +00:45:12,380 --> 00:45:20,280 +واضح؟ خلّيني أخد مثال تاني، هذا المثال التاني قال + +491 +00:45:20,280 --> 00:45:27,840 +بدنا تفصلونا ل glycine و lycine، طبعا أنا أسهل إشي + +492 +00:45:27,840 --> 00:45:33,390 +عندىان اعمل خط الاعداد اتخيل اني بدي احط ال + +493 +00:45:33,390 --> 00:45:39,210 +glycine مثلا هنا وال glycine هنا الان هيلزمني من + +494 +00:45:39,210 --> 00:45:45,830 +الجداول جداش ال isoelectric point لل glycine احنا + +495 +00:45:45,830 --> 00:45:54,610 +احفظنا لل glycine 6 ممتاز طب لل glycine مين شفتلنا + +496 +00:45:54,610 --> 00:45:56,290 +إياها 9.7 + +497 +00:46:00,380 --> 00:46:05,780 +هذه تسعة و سبعة واضح؟ ارسموا بهذا الشكل و تحلوا + +498 +00:46:05,780 --> 00:46:08,860 +المسألة معاكم سهولة هاي ال glycine له ال + +499 +00:46:08,860 --> 00:46:12,480 +isoelectric point ستة ال glycine تسعة و سبعة الآن + +500 +00:46:12,480 --> 00:46:18,780 +بعد هيك هذه النقطة اللي بيكون عندها neutral أقل + +501 +00:46:18,780 --> 00:46:26,500 +منها أعلى منها سالم واضح؟ الآن بالنسبة لل glycine + +502 +00:46:26,500 --> 00:46:30,750 +هذه النقطة اللي بيكون عندها neutralneutral اقل + +503 +00:46:30,750 --> 00:46:35,030 +منها موجب + +504 +00:46:35,030 --> 00:46:42,010 +اعلى منها سالم الان لما اجي انا اقول لو انا بدي + +505 +00:46:42,010 --> 00:46:48,390 +افصلهم اي BH بتنفع معاه السبعة ممتازة التمانية + +506 +00:46:48,390 --> 00:46:54,440 +ممتازة بين الستةو التسعة و سبعة بين ال isoelectric + +507 +00:46:54,440 --> 00:46:59,160 +points تبعتهم واضح لكن لو أخدت أقل من الستة + +508 +00:46:59,160 --> 00:47:03,020 +التانين في موجبين مش هيفصلوا التانين موجب يعني + +509 +00:47:03,020 --> 00:47:06,380 +التانين هيروحوا على ال cathode و لو أخدت أكتر من + +510 +00:47:06,380 --> 00:47:09,660 +التسعة و سبعة تانين سالم التانين هيروحوا على ال + +511 +00:47:09,660 --> 00:47:13,190 +anode مع بعض مش هيفصلوافانا بتطلع وين بيكونوا + +512 +00:47:13,190 --> 00:47:17,670 +مختلفين باخد I BH مناسبة عادة بياخدوها ال between + +513 +00:47:17,670 --> 00:47:21,850 +الناس اللي بيشتغلوا طبعا بهذه الطريقة ممكن نفصل + +514 +00:47:21,850 --> 00:47:26,400 +كمان مش بس اتنيناكتر من اتنين تلاتة او اربعة او + +515 +00:47:26,400 --> 00:47:31,740 +خمسة احيانا لما بيعملوا الفصل بيفصلوا واحد بيودوه + +516 +00:47:31,740 --> 00:47:34,980 +على السالب و اتنين مع بعض على الموجة بعد ذلك + +517 +00:47:34,980 --> 00:47:39,000 +الاتنين اللي ودوه مع الموجة يعيدوا الفصل انا مش + +518 +00:47:39,000 --> 00:47:43,120 +هنحول احنا الى ايش الى مختبر يعني احنا بيكفينا + +519 +00:47:43,120 --> 00:47:47,860 +الفكرة العامة بتاعة الفكرة العامة صارت واضحة شهو + +520 +00:47:47,860 --> 00:47:52,640 +ال ال Electrophoresis هو طريقة لفصل ال amino acids + +521 +00:47:52,640 --> 00:47:59,580 +و البروتيناتاعتمادا على ال بي اتش ال بي اتش هي + +522 +00:47:59,580 --> 00:48:07,020 +اللي بتغير ايش الشحنات و بتوجه كل واحد باتجاه مجال + +523 +00:48:07,020 --> 00:48:12,640 +كهربي محدد ابهيك بننهي المرة اللي جاي بنبدأ في + +524 +00:48:12,640 --> 00:48:14,880 +تفاعلات ال amino acids + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..ceb55e18286175388f27d17e343d2fabc5771085 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_postprocess.srt @@ -0,0 +1,1836 @@ +1 +00:00:19,620 --> 00:00:25,000 +بسم الله الرحمن الرحيممازلنا احنا بنتكلم في موضوع + +2 +00:00:25,000 --> 00:00:28,880 +الأحماض ومشتقاتها المرة الماضية اتكلمنا عن ال E + +3 +00:00:28,880 --> 00:00:34,940 +-stars وطرق تحضيرهم وبدأنا في موضوع تفاعلات ال E + +4 +00:00:34,940 --> 00:00:40,040 +-stars قولنا أول شيء أن التفاعل الأساسي اللي + +5 +00:00:40,040 --> 00:00:44,520 +هيتكرر معنا في كل هذا الفصل للأحماض وجميع مشتقاتها + +6 +00:00:44,520 --> 00:00:49,020 +وتفاعل الإجدال فكان أول تفاعل أخدناه عن ال E-stars + +7 +00:00:49,020 --> 00:00:54,430 +ال ammonolysis يعني أن نبدل ال ORب نيتروجين + +8 +00:00:54,430 --> 00:01:00,210 +وبالتالي بيطلع عندنا أمد وشوفنا كيف مثلا اتكون ال + +9 +00:01:00,210 --> 00:01:03,870 +بنز أمد الأسيتامد ما إلى ذلك في نهاية + +10 +00:01:03,870 --> 00:01:09,210 +اليوكليوفيليك substitution الآن من التفاعلات + +11 +00:01:09,210 --> 00:01:15,190 +التانية من التفاعلات التانية لل E starsالريدكشن + +12 +00:01:15,190 --> 00:01:20,230 +الريدكشن بالليثيوم الومنوم هايدرايد سبق احنا + +13 +00:01:20,230 --> 00:01:24,810 +اتعرفنا حقيقة على الليثيوم الومنوم هايدرايد قولنا + +14 +00:01:24,810 --> 00:01:30,980 +الاساس اللي فيه الاساس اللي فيه هو ال H-يعني انا + +15 +00:01:30,980 --> 00:01:35,320 +اللى بدى استفيده من ال high drive H minus الان + +16 +00:01:35,320 --> 00:01:41,260 +بدكوا تتخيلوا ان ال H minus بدها تهاجم على هذا ال + +17 +00:01:41,260 --> 00:01:45,120 +Easter بدها تهاجم على هذا ال Easter شو بدها تعمل + +18 +00:01:45,120 --> 00:01:51,680 +ابدا مكان ال OR بناء على ذلك الناتج اللى بده يطلع + +19 +00:01:51,680 --> 00:01:57,460 +عندكم بالدرجة الأولى R C double bond O H + +20 +00:02:00,330 --> 00:02:06,850 +واضح؟ شيلنا ال OR و حطينا ال H طبعا إذا بتلاحظوا + +21 +00:02:06,850 --> 00:02:12,330 +هذا ال ناتج اللي اتكون عندى هو عبارة عن ال الديهيد + +22 +00:02:12,330 --> 00:02:17,570 +احنا أخدنا في chapter ال الديهيد و ال ketones ان + +23 +00:02:17,570 --> 00:02:22,310 +ال الديهيد و ال ketones بيتفاعلوا مع ال hydride + +24 +00:02:22,890 --> 00:02:27,170 +الالديهيدز بتعطيني ال primary alcohol و ال ketone + +25 +00:02:27,170 --> 00:02:30,890 +ال secondary alcohol بناء على ذلك هذا ال الديهيدز + +26 +00:02:30,890 --> 00:02:36,670 +اللي اتكون هنا مرة تانية لو اجت فاعل مع ال H minus + +27 +00:02:36,670 --> 00:02:42,290 +الان هذا كان E star ال E star ايش تفاعله المميز + +28 +00:02:42,290 --> 00:02:44,250 +Substitution + +29 +00:02:46,570 --> 00:02:50,930 +لما عملت substitution صار ال الديهايد ال الديهايد + +30 +00:02:50,930 --> 00:02:56,990 +شو تفاعله addition هم الكلمتين تحكوليش غيرهم فقط + +31 +00:02:56,990 --> 00:03:01,890 +بسمع هنا substitution وهنا بسمع addition طالما هذا + +32 +00:03:01,890 --> 00:03:06,770 +الديهايد addition طبعا هتيجي H و سيضة بال bond O + +33 +00:03:06,770 --> 00:03:11,090 +شو تصير O H هذا التفاعل سبق أخدنا الديهايد مع ال + +34 +00:03:11,090 --> 00:03:16,990 +hydride بيعمل addition والنتيجة هتكون إيشprimary + +35 +00:03:16,990 --> 00:03:22,810 +alcohol إذا لو أنا أخدت التفاعل بالمجمل تفاعل ال + +36 +00:03:22,810 --> 00:03:28,750 +eastern مع ال hydride بينتهي في النهاية ب primary + +37 +00:03:28,750 --> 00:03:33,090 +alcohol لكن ننتبه أنه مرورا بال aldehyde الآن هذا + +38 +00:03:33,090 --> 00:03:38,110 +ال aldehyde لا يفصلواضح؟ يعني بنفعل بتكون ال + +39 +00:03:38,110 --> 00:03:41,990 +الديهايد ع طول بلاجة اتش تانية يتفعل معاها بيصفى + +40 +00:03:41,990 --> 00:03:46,650 +primary alcohol عشان هيك هذا الكلام حتى نكون + +41 +00:03:46,650 --> 00:03:50,910 +فاهمين بالظبط إيش اللي صار معنا لكن بدل المرة ألف + +42 +00:03:50,910 --> 00:03:55,410 +بقول لو قلتلكوا أكمل المعادلة أكمل الفراغ بدي + +43 +00:03:55,410 --> 00:04:00,640 +Easterمع hydride في النهاية انا بده اشوف ال + +44 +00:04:00,640 --> 00:04:03,620 +primary alcohol ربما لهذا السبب انتوا شايفين + +45 +00:04:03,620 --> 00:04:07,580 +المعادلة في نهايتها ايش؟ primary alcohol لكن هي في + +46 +00:04:07,580 --> 00:04:13,440 +تفصيلها كام خطوة؟ خطوتين هي في تفصيلها خطوتين + +47 +00:04:13,440 --> 00:04:18,980 +إبدال كون ال aldehyde و بعدين إضافة كونت ال + +48 +00:04:18,980 --> 00:04:25,150 +primary alcohol واضحة الفكرة؟الان زى هذا التفاعل + +49 +00:04:25,150 --> 00:04:31,970 +تماما زى هذا التفاعل تماما لو يا تورا اجينا فعلنا + +50 +00:04:31,970 --> 00:04:35,890 +و هذا مش مكتوب عندكوا لكن بنضيفه عليكم لو اجينا + +51 +00:04:35,890 --> 00:04:42,590 +فعلنا ال Easter مش مع H minus مع R minus طبعا اللى + +52 +00:04:42,590 --> 00:04:47,890 +بنقصده في R بهدى الحالة ايش ال green yard reagent + +53 +00:04:47,890 --> 00:04:59,080 +ال Rمجي اكس مصدر لل R مينوس مظبوط ولا لأ هيحط R + +54 +00:04:59,080 --> 00:05:05,220 +مرتين فى المرة الأولى شو هيحط هنا R كوّن لك + +55 +00:05:05,220 --> 00:05:13,140 +الكيتون الان كمان مرة R تانية نشيل هدول ال chain + +56 +00:05:13,140 --> 00:05:18,820 +اللى كانوا من ال high drive نحط R وR + +57 +00:05:20,670 --> 00:05:26,770 +إذا في هذه الحالة التفاعل مع جرينيارد شو بيعطيني + +58 +00:05:26,770 --> 00:05:32,210 +تيرتشاري ألكول لأن R كانت أصلا من ال Easter وتنتين + +59 +00:05:32,210 --> 00:05:35,210 +متشابهات اتجوا من الجرينيارد يعني لو افترضنا مثلا + +60 +00:05:35,210 --> 00:05:39,990 +أن هذه كانت فنل وفعلت + +61 +00:05:39,990 --> 00:05:44,130 +مع إيثل ماجنيسيا مبروماي على مرتين أول مرة هيحق + +62 +00:05:44,130 --> 00:05:51,170 +إيثل و تاني مرة كمان إيثل إذا ال Easterفي المحصلة + +63 +00:05:51,170 --> 00:05:59,510 +مع الـ Greenyard reagent بدوا يعطيني تيرتشاريه + +64 +00:05:59,510 --> 00:06:05,710 +الكهول تماما نفس التفاعل اللي مع الهيدرايد لكن بدل + +65 +00:06:05,710 --> 00:06:10,210 +ما كنت بضيف H- مرتين يعني مرة بالإبدال و مرة + +66 +00:06:10,210 --> 00:06:21,410 +بالإضافة بحط R- مرتين واضح بحط ال R- مرتينلاحظوا + +67 +00:06:21,410 --> 00:06:27,030 +معي للناس اللي بيحاولوا يفهموا الأمور بصورتها + +68 +00:06:27,030 --> 00:06:31,730 +الكلية للناس اللي بيحاولوا يفهموا الأمور بصورتها + +69 +00:06:31,730 --> 00:06:38,410 +الكلية السهلة مش بالمسميات الضيقة الآن هذا Easter + +70 +00:06:38,410 --> 00:06:43,130 +اعملتله انا تفاعلين و اتعمت لما عرفتهم التفاعل + +71 +00:06:43,130 --> 00:06:43,670 +الأول + +72 +00:06:47,190 --> 00:06:51,550 +الـ Hydrides و أعطاني Primary Alcohols و التفاعل + +73 +00:06:51,550 --> 00:06:54,790 +التالي معي Green Yard Reagent و أعطاني Tertiary + +74 +00:06:54,790 --> 00:06:59,530 +Alcohol مرورا بالكيتون في هذه الحالة الآن هذه + +75 +00:06:59,530 --> 00:07:07,070 +المجموعة الـ OR مجموعة إيه شمالها؟مطرودة طردت جيبت + +76 +00:07:07,070 --> 00:07:14,170 +سيرتها لأ طيب يا تورا لو بعد شوية أخدنا ال acid + +77 +00:07:14,170 --> 00:07:19,090 +halides بمعنى ماكناش نبدأ ب E star و المجموعة + +78 +00:07:19,090 --> 00:07:23,670 +المطرودة OR كان عندنا acid halide كان تادي CL أو + +79 +00:07:23,670 --> 00:07:32,570 +PR و إجيت قولت تفاعل ال acid halide مع ال hydrides + +80 +00:07:32,570 --> 00:07:40,530 +شو هيعطيلي؟نفس الكلام تماماً لأنه طردت OR أو طردت + +81 +00:07:40,530 --> 00:07:45,310 +CL وباقي الناتج زي ما هو ال primary alcohol تفاعل + +82 +00:07:45,310 --> 00:07:50,170 +acid halide مع grignard reagent tertiary alcohol + +83 +00:07:50,170 --> 00:07:54,890 +واضح؟ شو بديفرق التفاعل إذا كانت المجموعة اللي + +84 +00:07:54,890 --> 00:07:59,810 +طردت OR و أخدت H طلعت على شكل alcohol ولا CL minus + +85 +00:07:59,810 --> 00:08:06,360 +و أخدت H طلعت على HCLواضح؟ وعشان هيك اللي بيعرف + +86 +00:08:06,360 --> 00:08:10,240 +أنه ال Easter بتفاعل مع ال hydrates ومع greenery + +87 +00:08:10,240 --> 00:08:15,880 +agent بطريقة معينة بنقوله كمان و ال acid chlorides + +88 +00:08:15,880 --> 00:08:21,970 +بتفاعلوا مع ال hydrates ومع greenery agentبنفس + +89 +00:08:21,970 --> 00:08:27,090 +الطريقة تماما مافرجش انه يكونش المجموعة المطرودة + +90 +00:08:27,090 --> 00:08:31,710 +هي OR ولا CL هذه مجموعة مطرودة لكن الجزء ال + +91 +00:08:31,710 --> 00:08:36,870 +organic اللي عندى جزء اشماله ثابت واضح الفكرة + +92 +00:08:49,670 --> 00:08:55,890 +الان بننتقل ل ال acid halides ال acid halides قلنا + +93 +00:08:55,890 --> 00:09:00,290 +عنهم مشتقات ايضا من الأحماض و لما اتكلمنا عن + +94 +00:09:00,290 --> 00:09:06,030 +تفاعلات الأحماض اتكلمنا عن تحضيرهم قلنا اذا أخدنا + +95 +00:09:06,030 --> 00:09:10,990 +ال organic acid مع ال phosphorus trichloride او ال + +96 +00:09:10,990 --> 00:09:20,920 +SOCl2 يهدي يهدي بيشيل ال OH و بيحطلهCL فال acid + +97 +00:09:20,920 --> 00:09:25,480 +بتحول الى acid chlorides طريقة التحضير طريقة ايش + +98 +00:09:25,480 --> 00:09:31,600 +سهلة الان لو اجينا للتسمية كيف بنسمي ال acid + +99 +00:09:31,600 --> 00:09:39,190 +halides احنا كان هنا في عندنا OECacid الآن بدنا + +100 +00:09:39,190 --> 00:09:44,930 +نغير كلمة acid بكلمة halide بدنا نغير كلمة acid + +101 +00:09:44,930 --> 00:09:49,790 +بكلمة halide و ال oic بنخليها oil يعني لو أخدنا + +102 +00:09:49,790 --> 00:09:56,510 +ethanoic acid اللي هو الحامض اللي من carbon 10 بدو + +103 +00:09:56,510 --> 00:10:02,350 +يصير ethanoic chloride لو هنا bromالبروميد لو + +104 +00:10:02,350 --> 00:10:07,770 +أخدنا ال common name تبعه acidic acid بس بنشيل ايش + +105 +00:10:07,770 --> 00:10:13,490 +كلمة acid و بنحط chloride فهذا المركب ايش بيصير + +106 +00:10:13,490 --> 00:10:19,750 +Acetyl لأ بنرجع للمجموعة YL Acetic منها Acetyl + +107 +00:10:19,750 --> 00:10:27,400 +واضح لأن هذه اتعرفنا عليها Acetylمتذكرينها؟ أسيتل + +108 +00:10:27,400 --> 00:10:33,560 +و بنكتب إيش؟ أكلورايد فالفكرة بدنا نشيل هذا جزء + +109 +00:10:33,560 --> 00:10:39,000 +الأسيتل و ننهب وي الهلايد أسيتل أكلورايد و منها + +110 +00:10:39,000 --> 00:10:43,380 +كمان سبق إن اتعرفنا على مجموعة ال بنزويل من وين + +111 +00:10:43,380 --> 00:10:48,920 +بنجيب ال بنزويل أكلورايد؟ لو أجينا سألناكم بنزويل + +112 +00:10:48,920 --> 00:10:54,300 +أكلورايد بدنا نجيبه من؟ + +113 +00:10:55,720 --> 00:11:03,440 +البنزويك أسد C double bond O OH في ال BCL3 أو أي + +114 +00:11:03,440 --> 00:11:07,640 +حاجة C + +115 +00:11:07,640 --> 00:11:14,360 +double bond O Cl هذا إيش بده يصير بنزويل لإن هذه + +116 +00:11:14,360 --> 00:11:19,900 +مجموعة البنزويل فنل C double bond O بنزويل + +117 +00:11:19,900 --> 00:11:29,870 +إكلورايدوالبنزول كمجموعة مرات بتختصر بي زد هيك + +118 +00:11:29,870 --> 00:11:35,250 +بنزول إكلورايد فإذا قرأته كلمة بي زد هذا اختصار + +119 +00:11:35,250 --> 00:11:40,330 +إيش بنزول بنزول إكلورايد واللي علمكوا ال بنزول + +120 +00:11:40,330 --> 00:11:45,230 +جالكوا تذكروا أنه في إلها بنت عم بتشبهها في + +121 +00:11:45,230 --> 00:11:49,510 +الكتابة اللي هي بنزل إكلورايد بس ال بنزل إكلورايد + +122 +00:11:49,510 --> 00:11:57,190 +عبارة عنفين ال CH2 نفترض CH2 فين ال CH2 هذه مجموعة + +123 +00:11:57,190 --> 00:12:06,230 +البنزل مش بنزايل بنزل طبعا لو جيت سألكوا البنزل + +124 +00:12:06,230 --> 00:12:11,650 +كلورايد كهيلايد أي نوع من الهيلايد primary + +125 +00:12:11,650 --> 00:12:12,890 +alkalihilide + +126 +00:12:16,310 --> 00:12:21,030 +الكل واضح ماحدش ييجي يشوف هنا ال aromatic ويقول + +127 +00:12:21,030 --> 00:12:24,630 +عنه aromatic halide لأ هو ال aromatic halide لو + +128 +00:12:24,630 --> 00:12:29,370 +كانت ال CL متصلة مباشرة بالحلقة لكن طالما ال CL + +129 +00:12:29,370 --> 00:12:34,930 +متصلة ب CH2 إذا هذا الكل halide وبناء على ذلك بتيم + +130 +00:12:34,930 --> 00:12:37,970 +عليكوا التفاعلات الإبدال اللي درسناها في شبتر 6 + +131 +00:12:37,970 --> 00:12:42,070 +ولا لأ اه فهذا بنزل chloride + +132 +00:12:43,690 --> 00:12:47,390 +فبفرق بنزل الكلورايد عن بنزول الكلورايد وبنزل الى + +133 +00:12:47,390 --> 00:12:52,650 +اختصار بيختصرها BN واضح + +134 +00:12:52,650 --> 00:13:01,050 +بيختصرها BN بنزل فننتبه لهدول المجموعتين هذا ال + +135 +00:13:01,050 --> 00:13:07,150 +بنزول الكلورايد يعني إذا بدنا نوصفه بنقول عنه انه + +136 +00:13:07,150 --> 00:13:16,970 +إيش انه لعينليش بنوصف بهذا الوصف القاسي؟ لأن هذا + +137 +00:13:16,970 --> 00:13:22,430 +اللي هو عادة يستعمل كغاز مسيل للدموع يعني بتعرفوا + +138 +00:13:22,430 --> 00:13:27,630 +الغازات اللي في المظاهرات وغيرها، الغازات المسيلة + +139 +00:13:27,630 --> 00:13:34,930 +للدموع، معظمها acid halides، ومن ضمنهاالبنزول + +140 +00:13:34,930 --> 00:13:40,230 +الكلورايد من ضمنها البنزول الكلورايد طبعا لو اجينا + +141 +00:13:40,230 --> 00:13:45,850 +نقول ايش السبب ايش السبب ان هذا البنزول الكلورايد + +142 +00:13:45,850 --> 00:13:53,110 +يستعمل كغاز مسيل للدموع ناخد احنا بشكل عام + +143 +00:13:53,110 --> 00:13:58,330 +الكلورايد و تفاعلاتها ناخد بشكل عام الكلورايد و + +144 +00:13:58,330 --> 00:14:03,550 +تفاعلاتها طبعا مرتان تفاعلات الكلورايد هي تفاعلات + +145 +00:14:05,010 --> 00:14:09,570 +الإبدال يعني ال acid chloride مجرد ما بديه يتعرض + +146 +00:14:09,570 --> 00:14:14,410 +للميه مجرد ما بديه يتعرض للميه بديه يفقد ال CL و + +147 +00:14:14,410 --> 00:14:21,470 +يحط ال OH رجع لإيش؟ لل carboxylic acid واضح؟من حد + +148 +00:14:21,470 --> 00:14:25,590 +ما يتعرض للميه برجع ل acid لو فعلنا مع ال ethanol + +149 +00:14:25,590 --> 00:14:32,050 +بدو يشيل ال CL ويحط O-ethyl برجع ل E-star لو فعلنا + +150 +00:14:32,050 --> 00:14:37,890 +مع ال ammonia بدو يشيل ال CL ويحط NH2 بصير أمل فزي + +151 +00:14:37,890 --> 00:14:41,770 +ما اتفقنا أنه من واحد بنحضر التاني الآن خلينا على + +152 +00:14:41,770 --> 00:14:47,480 +المعادلة الأولىخلّينا على المعادلة الأولى و نتخيل + +153 +00:14:47,480 --> 00:14:52,020 +مثلا أنه إحنا اللي بدين فيه ال benzoyl chloride + +154 +00:14:52,020 --> 00:14:54,920 +اللي هو إيش موجود فيه بدل ال acetyl chloride هنا + +155 +00:14:55,790 --> 00:15:00,610 +فنل سيبا بالبوند OCL هذا البيزويل الكلوري + +156 +00:15:00,610 --> 00:15:06,190 +بيستعملوه كغاز مصير للدموع الآن السؤال هل هو غاز + +157 +00:15:06,190 --> 00:15:13,310 +أصلا لأ هو مادة زيتية يعني مادة + +158 +00:15:15,850 --> 00:15:22,150 +بحرارة غليان فوق المية درجة مئوية لكن لما بيرموه + +159 +00:15:22,150 --> 00:15:27,130 +في الجو بيطلع على شكل .. بيطلع على شكل رذاذ صغير + +160 +00:15:27,130 --> 00:15:31,350 +فبييجي على الناس بيبدو الناس يشموه بييجي على وجههم + +161 +00:15:31,350 --> 00:15:37,250 +يعني عملية قذفهفي الجو بيخليه يطلع على شكل إيش؟ + +162 +00:15:37,250 --> 00:15:42,470 +رذاذ، رذاذ صغير، الآن هذا الرذاذ الصغير اللي طلع + +163 +00:15:42,470 --> 00:15:49,750 +لو دخل على جسم الإنسان، هيدخل على الزور، هيجي على + +164 +00:15:49,750 --> 00:15:56,450 +العنين، شكل أساسي، الآن الزور و العنين فيهم مياه + +165 +00:15:57,990 --> 00:16:03,730 +إذا وجدت أنا هأعمل تفاعل البنزويلي كلوراي مع الميه + +166 +00:16:03,730 --> 00:16:09,590 +هطلع بنزويك أسد البنزويك أسد حمضه ضعيف مش منه + +167 +00:16:09,590 --> 00:16:16,350 +المشكلة لكن المشكلة أكتر من ال HCL ال HCL هو اللي + +168 +00:16:16,350 --> 00:16:22,950 +هيسبب الحرقان في العينين وفي الزور واضح ال HCL + +169 +00:16:22,950 --> 00:16:31,010 +الآن هذا نفسه لو إجه على الجلدمافيش منه مشكلة إذا + +170 +00:16:31,010 --> 00:16:34,350 +الجلد جافلكن بتعرفوا الناس اللي بيكونوا في + +171 +00:16:34,350 --> 00:16:39,010 +المظاهرات مرات بيكونوا عرقانين اه لو اجى معي العرق + +172 +00:16:39,010 --> 00:16:43,630 +و اجي اتعمل HCL بيصير الجلد يحرج لو افترضنا ان + +173 +00:16:43,630 --> 00:16:49,310 +البني ادم اللي كان في المظاهرة اجى عليه هو عبارة + +174 +00:16:49,310 --> 00:16:53,070 +عن سائل على الوجه على الجسم مافيش عنده مشكلة + +175 +00:16:53,070 --> 00:16:56,790 +ماحسشه مشاكل كتير غير في العنان و الزور لكن بعد + +176 +00:16:56,790 --> 00:17:02,630 +هيك لو راح يتوضى بالميةيغسل الإيدان و يغسل الوجه + +177 +00:17:02,630 --> 00:17:06,650 +بكمية ميه صغيرة بصير وشه و إيديه زي النار ليش؟ لإن + +178 +00:17:06,650 --> 00:17:14,530 +هو بحط ميه على رذاف بالزويل الكلورايفبتفعلوا بيطلع + +179 +00:17:14,530 --> 00:17:18,690 +إيش ال HCL و لذلك البني آدم اللي بده يمر بهذه + +180 +00:17:18,690 --> 00:17:24,670 +الظروف المفروض أنه بده يغير ملابسه بده يغسل بميه و + +181 +00:17:24,670 --> 00:17:29,870 +صابونة و كمية كبيرة جدا عشان يشيل هذه المادة ما + +182 +00:17:29,870 --> 00:17:34,450 +احنا قولنا مادة زيتية سائلة لو كان غاز كان اتبخر + +183 +00:17:34,450 --> 00:17:40,550 +في الهواء مع السلامة لكن هم بيرشوه و هم عارفينإنه + +184 +00:17:40,550 --> 00:17:43,850 +أنا بديش إياه يطير معي الهواء، إياه يظل ملزج في + +185 +00:17:43,850 --> 00:17:50,630 +الإنسان وفي الوجه ما هدوله اسمه فن إيش الإذاء اللي + +186 +00:17:50,630 --> 00:17:55,090 +بديه يرشي الغاز المسيل اللي قدوموه بديه يضر الناس + +187 +00:17:55,090 --> 00:17:59,790 +كذلك الحال بالمناسبة في موضوع غازات الأعصاب اللي + +188 +00:17:59,790 --> 00:18:06,700 +بتتدخل على الأعصاب أقوى الغازات أقلها تطيراهي كلها + +189 +00:18:06,700 --> 00:18:12,760 +سوائل بيسموها غازات تجاوزا، لكن ليش بيسموها غازات؟ + +190 +00:18:12,760 --> 00:18:16,800 +لأنه بينشروها على شكل رذاذ زي الميه لما بتنشرها + +191 +00:18:16,800 --> 00:18:21,220 +على شكل رذاذ أو ال spray العطر لما بتنشره على شكل + +192 +00:18:21,220 --> 00:18:28,440 +رذاذ، واضح الفكرة؟أكثرها تبخرا، أقلها تبخرا، لأنها + +193 +00:18:28,440 --> 00:18:32,660 +تبقى ملازقة في الأواعي، ملازقة في الأرض، ملازقة + +194 +00:18:32,660 --> 00:18:36,880 +على الحيطان، على السيارات، على الشجر وبهدوء تتبخر + +195 +00:18:36,880 --> 00:18:42,960 +وبتطلع كميات الغاز وبتضر البني آدم، بينما أكثرها + +196 +00:18:42,960 --> 00:18:50,180 +تبخرابيجي الهواء بياخده، بالتالي خطورته إيش؟ بتخف، + +197 +00:18:50,180 --> 00:18:55,220 +فالغازات الأعصاب مشهور منها غاز A، غاز B، غاز + +198 +00:18:55,220 --> 00:19:04,890 +بيسموه C في Novichok في VX، مسميات كثيرةاختارها + +199 +00:19:04,890 --> 00:19:11,070 +اقلها ايش؟ تبخرا، بيسموها nerve gases هذه الغازات + +200 +00:19:11,070 --> 00:19:17,150 +تبعت الدموع شو بيسموها؟ tear gases، tear يعني دموع + +201 +00:19:18,030 --> 00:19:22,610 +Tear gases او لكريماتر لكريماتر الغاز المثيل + +202 +00:19:22,610 --> 00:19:28,490 +للدموع او tear gas فالبنزويل الكلورايد is لكريماتر + +203 +00:19:28,490 --> 00:19:33,950 +or is a tear gas الفكرة الأساسية منه ان هو بتطلع + +204 +00:19:33,950 --> 00:19:40,320 +hcl اللي بيسبب ايشالحرقان طبعا في المجتمع الدولي + +205 +00:19:40,320 --> 00:19:44,260 +اللي موجود اليوم المجتمع الشيطاني البنزويل + +206 +00:19:44,260 --> 00:19:51,060 +الكلورايد هو حقيقة أرحم ما يمكن أن يُقذَف على + +207 +00:19:51,060 --> 00:19:54,820 +الناس اليوم بيستعملوا غازات أعصاب و بيستعملوا + +208 +00:19:54,820 --> 00:20:00,520 +غازات دموع مخلوطة بغازات أعصاب بنسب قليلة و كلها + +209 +00:20:00,520 --> 00:20:05,440 +أشد تأثيرا من البنزويل الكلورايد يعني أشرف غازات + +210 +00:20:05,440 --> 00:20:12,460 +للمظاهراتالبنزوليكلوريد وما عداها أكثر شدة وأكثر + +211 +00:20:12,460 --> 00:20:16,960 +إجراما وعشان ذلك لاحظوا أننا لما حكينا على + +212 +00:20:16,960 --> 00:20:20,620 +الخواصلة ال acid helites in general قلنا noxious + +213 +00:20:20,620 --> 00:20:27,580 +يعني مهيجة irritating بتعمل إصابات أو جروح react + +214 +00:20:27,580 --> 00:20:33,660 +violently with water بتتفاعل بقوة مع الميه معطية + +215 +00:20:33,660 --> 00:20:41,830 +الحامض الأصلي زائدالـ HCL نيجي + +216 +00:20:41,830 --> 00:20:47,760 +للعائلة اللي بعدهامن ال derivatives اللي هي ال + +217 +00:20:47,760 --> 00:20:53,660 +acid anhydrides ال acid anhydrides بتيجي من تفاعل + +218 +00:20:53,660 --> 00:20:59,940 +جزيئين من الحامض مع بعضهم البعض لاحظوا في موضوع ال + +219 +00:20:59,940 --> 00:21:04,500 +acid anhydrides من ناحية المبدأ من ناحية المبدأ + +220 +00:21:04,500 --> 00:21:12,330 +هناك شبه الطالب المنتبه بموضوع ال etherبموضوع إيش + +221 +00:21:12,330 --> 00:21:17,470 +ال ether إذا بتتذكروا لما كنا نتكلم عن ال ether + +222 +00:21:17,470 --> 00:21:21,390 +قسمنا ال ethers إلى نوعين قلنا في عندنا + +223 +00:21:21,390 --> 00:21:28,510 +symmetrical ethers و unsymmetrical ethersإذا كانت + +224 +00:21:28,510 --> 00:21:33,090 +الـR و الـR زي بعض هذا سمنا إيش؟ symmetrical ether + +225 +00:21:33,090 --> 00:21:38,030 +و لذلك لما كنا مثلا بدنا نضاي إيثل إيثر كنا ناخد + +226 +00:21:38,030 --> 00:21:42,370 +الكحول مش الحامض في النهاية في OH اللي هو على سبيل + +227 +00:21:42,370 --> 00:21:50,450 +المثال لو أخدنا الإيثانول بنسبة 2 مع H plus هو نفس + +228 +00:21:50,450 --> 00:21:58,660 +الفكرة تماما إيش كان هذا يعطينا؟ إيثل أوDiethyl + +229 +00:21:58,660 --> 00:22:03,100 +ether من + +230 +00:22:03,100 --> 00:22:09,660 +الكحول و Diethyl ether is symmetrical ether رور + +231 +00:22:11,320 --> 00:22:14,800 +شوف نقاش ال symmetrical فالكحول بيتفاعل مع نفسه + +232 +00:22:14,800 --> 00:22:19,800 +جوزيق بيهاجم على التاني و بيطرده مية و بتفاعله + +233 +00:22:19,800 --> 00:22:25,960 +الان الكلام نفسه بتم مع ال unhydrates لكن في هذه + +234 +00:22:25,960 --> 00:22:32,280 +الحالة الحامض بيتفاعل مع نفسهواضح؟ في هذه الحالة + +235 +00:22:32,280 --> 00:22:36,680 +الحامض يتفاعل مع نفسه يعني احنا اليوم موضوعنا ال + +236 +00:22:36,680 --> 00:22:41,000 +unhydrates لو بدأ اركز اكثر عليها بدأ اقول تخيلوا + +237 +00:22:41,000 --> 00:22:47,120 +ان هذا جزيق حامض بدأ افعله مع ايش؟ مع جزيق تاني + +238 +00:22:47,120 --> 00:22:54,980 +اللي هو OH سيضة بال bond Oنفترض CH3 هاي Acetic + +239 +00:22:54,980 --> 00:23:00,040 +Acid جزئ و هاي Acetic Acid كمان جزئ هاي الجزئين + +240 +00:23:00,040 --> 00:23:04,740 +خلصنا واضح؟ الآن هذا بده ييجي من خلال الـ OH اللي + +241 +00:23:04,740 --> 00:23:10,620 +هي الـ nucleophile إهاجمها يطرد الـ OH هذا تفاعل + +242 +00:23:10,620 --> 00:23:15,380 +الإبدال ولا لأ؟ هذا تفاعل الإبدال بناء على ذلك لما + +243 +00:23:15,380 --> 00:23:18,920 +تطرد الـ OH من هنا مع الـ H هذه + +244 +00:23:21,660 --> 00:23:29,940 +الجزء الأول اللي مبين بالأسود هي CH3COO + +245 +00:23:29,940 --> 00:23:35,100 +والجزء التاني OCOO + +246 +00:23:36,520 --> 00:23:42,080 +CH3 هيتكون عندى الـ Symmetrical Anhydride اتكون + +247 +00:23:42,080 --> 00:23:46,840 +عندى الـ Symmetrical Anhydride لاحظوا انه مجموعة + +248 +00:23:46,840 --> 00:23:52,840 +الانهيدريد كمجموعة عبارة عن ايش C double bond O O + +249 +00:23:52,840 --> 00:23:57,580 +C double bond O يعني لو بدى اقول ال ether كانت O + +250 +00:23:57,580 --> 00:24:03,620 +متصلة بتنتين R طيب الانهيدريد هى + +251 +00:24:06,590 --> 00:24:13,350 +هذه ثابتة C double bond O O C double bond O هذه + +252 +00:24:13,350 --> 00:24:17,670 +مجموعة الانهيدريد الآن لما فعلت الحامض مع نفسه + +253 +00:24:17,670 --> 00:24:23,890 +صارت هذه ال R و هذه ال R زي بعض ولذلك سميت هذا + +254 +00:24:23,890 --> 00:24:28,530 +symmetrical anhydride الآن السؤال طب لو خلت هذه + +255 +00:24:28,530 --> 00:24:33,690 +مثل وهذه اثلبتصير Unsymmetrical لو خلّيت فينيل و + +256 +00:24:33,690 --> 00:24:40,130 +إثل Unsymmetrical طبعا بيلزمنا نسمي و نحضر ال + +257 +00:24:40,130 --> 00:24:43,210 +symmetrical anhydride و الunsymmetrical anhydride + +258 +00:24:43,210 --> 00:24:47,050 +تماما زي ما عملنا مع ال aether احنا قولنا ال + +259 +00:24:47,050 --> 00:24:49,870 +aether كان الكحول مع نفسه أعطاني symmetrical + +260 +00:24:49,870 --> 00:24:54,350 +aether الآن ال symmetrical anhydride الحامض مع + +261 +00:24:54,350 --> 00:24:57,350 +نفسه بنسخنه في وجود حمض + +262 +00:25:00,190 --> 00:25:06,170 +بش ان مش واضح بنسخنه في وجود حمض و طبعا بنتخلي + +263 +00:25:06,170 --> 00:25:09,610 +شروط التفاعل تسحب الميه للخارج ليش؟ لأن هذا + +264 +00:25:09,610 --> 00:25:13,510 +التفاعل ما عدا ذلك عكس بترد الميه تهاجمها و ترجع + +265 +00:25:13,510 --> 00:25:17,230 +لحمضين ولذلك اللي بيعمل unhydrate بيكون عنده طريقة + +266 +00:25:17,230 --> 00:25:22,160 +يسحب فيها الميه لوينل الخارج يتخلص منها طب الآن + +267 +00:25:22,160 --> 00:25:27,640 +هذا كيف بدي أسميه على اسم الحامض بشيل كلمة acid و + +268 +00:25:27,640 --> 00:25:32,880 +بكتب unhydrate يعني هذا لو سمناه ethanoic acid ال + +269 +00:25:32,880 --> 00:25:37,700 +unhydrate تبعه إيش بدي يصير ethanoic unhydrate طب + +270 +00:25:37,700 --> 00:25:43,820 +لو سمناه بال common name acetic acid إيش بدي يتسمى + +271 +00:25:44,770 --> 00:25:53,230 +acetic anhydride فالتسمية إن نشيل كلمة + +272 +00:25:53,230 --> 00:25:59,850 +acid ونحط anhydride واضح التسمية إن نشيل كلمة acid + +273 +00:25:59,850 --> 00:26:04,250 +ونحط إيش anhydride الحامض اللي فيه المثل هو + +274 +00:26:04,250 --> 00:26:12,990 +الaceticالان لو اجينا وقلنالكم لو سمحتوا ارسمولنا + +275 +00:26:12,990 --> 00:26:20,510 +المركب القاتل بنزوك unhydrate بنزوك + +276 +00:26:20,510 --> 00:26:29,870 +unhydrate اول اشي ع طول بدكم تحطولي ايش هي مجموعة + +277 +00:26:29,870 --> 00:26:35,670 +ال unhydrate مجموعة ال unhydrate C double bond O O + +278 +00:26:37,550 --> 00:26:42,130 +خلّينا نعملها هيك C double bond O تابع هذه مجموعة + +279 +00:26:42,130 --> 00:26:47,810 +الانهيدريد الآن إذا كانت بنزوك فنل معناه ذلك سأضع + +280 +00:26:47,810 --> 00:26:55,250 +على الجهتين مجموعة الفنل فنل و فنل هذه بنزوك + +281 +00:26:55,250 --> 00:27:00,350 +انهيدريد لما نقول أسيتك مثل و مثل المجموعة تبع + +282 +00:27:00,350 --> 00:27:02,550 +الأسيتك أسيتك بروبانوك + +283 +00:27:07,410 --> 00:27:12,490 +بدوا يكون المجموع تلاتة اه انتبهوا معاك خلصنا من + +284 +00:27:12,490 --> 00:27:20,310 +ال benzoic اه اه لو اتيتكن اتكتبلكم بروبانوك لأنه + +285 +00:27:20,310 --> 00:27:25,810 +مرات بيغلطوا الطلاب بهذه النقطة بروبانوك unhydrate + +286 +00:27:25,810 --> 00:27:33,950 +بدي الكربونات تلاتة هذه واحدة منهمهذه واحدة و لذلك + +287 +00:27:33,950 --> 00:27:38,310 +لما كان عند ال E ثانوك كنت بس حاطط ال CH3 المجموع + +288 +00:27:38,310 --> 00:27:45,430 +تنتين لما بدل بربانوك بدأ اكتب CH2 CH3 المجموع + +289 +00:27:45,430 --> 00:27:54,830 +تلاتة و هنا CH2 CH3 واضح فالمجموع تلاتة بربانوك و + +290 +00:27:54,830 --> 00:28:01,830 +مثلها بيوتانوك واضحةطيب الآن يا تورا الكلام شوفوا + +291 +00:28:01,830 --> 00:28:08,370 +كيف ما أسهل الكيميا ولا أمتعها بتفهم لحالها لو + +292 +00:28:08,370 --> 00:28:19,610 +إجيت و روحت كتبتلكم هنا CH3 و كتبتلكم هنا فنل و + +293 +00:28:19,610 --> 00:28:21,810 +قلتلكوا سموا هذا المركب + +294 +00:28:27,020 --> 00:28:34,240 +هذا مكون من كام حامض؟ هذا الحامض شو هو؟ + +295 +00:28:42,280 --> 00:28:47,600 +جيد جيد هذا التردد .. هذا التردد بحل مشكلتك الناس + +296 +00:28:47,600 --> 00:28:50,380 +اللي سألوني عن الامتحان لأ في الامتحان مش عامليني + +297 +00:28:50,380 --> 00:28:55,120 +كويس لإن مصيرين ما تسمعوش نصيحتي إن إذا في الكيميا + +298 +00:28:55,120 --> 00:29:00,400 +ما طبقتوش و ما كتبتوش الجملة ألف مرة لن تتعلموا + +299 +00:29:00,400 --> 00:29:05,340 +كيميا تمام؟ لن تتعلموا كيميا هذا اللي فيه تنتين + +300 +00:29:05,340 --> 00:29:12,810 +اثانوك و بال common أسيتكمظبوط ولا لأ؟ هذا كحمد + +301 +00:29:12,810 --> 00:29:19,010 +CH3C double bond O إيش ماله؟ Acetic و هذا الفنل C + +302 +00:29:19,010 --> 00:29:23,430 +double bond O بنزوك و خلّيني أحطهم alphabetical + +303 +00:29:23,430 --> 00:29:28,190 +مين بيجي قبل ال Acetic ولا ال بنزوك؟ Acetic بنزوك + +304 +00:29:28,190 --> 00:29:29,850 +Unhydrate + +305 +00:29:31,620 --> 00:29:35,840 +واضح؟ بذكر اسم الحامضين و بحطه ممرتبين + +306 +00:29:35,840 --> 00:29:40,520 +alphabetically فبكون هيك اقدرت اسمي ال + +307 +00:29:40,520 --> 00:29:47,620 +unsymmetrical .. unhydrite .. واضح؟أسيتك بنزوك + +308 +00:29:47,620 --> 00:29:51,080 +أنهايدرايد طبعا واحدة ممكن تقول ممكن نسميه إيثانوك + +309 +00:29:51,080 --> 00:29:56,060 +ممكن موادة كاربون تنتيل إيثانوك و أجي تبدأ تكتب + +310 +00:29:56,060 --> 00:30:01,740 +بنزوك إيثانوك أنهايدرايد عشان تحط ال B قبل ال E + +311 +00:30:01,740 --> 00:30:06,920 +alphabeticalإذا إعرفنا كيف بنسمي الـ unsymmetrical + +312 +00:30:06,920 --> 00:30:12,680 +anhydride بذكر الحامضين alphabetically وإضافة + +313 +00:30:12,680 --> 00:30:18,860 +النهاية anhydride الآن إذا هذا الكلام إعرفنا كيف + +314 +00:30:18,860 --> 00:30:26,860 +نسميه، ضال كيف؟ انحضروه، ضال كيف انحضروه اللي + +315 +00:30:26,860 --> 00:30:34,400 +فاهمين الethers، إيش كنا نعمل فيهم؟نفس الفكرة + +316 +00:30:34,400 --> 00:30:39,520 +تماما اللي اتذكره William Sun William Sun's + +317 +00:30:39,520 --> 00:30:44,320 +synthesis of ethers هل يا تورا كنت بقدر انا اجي + +318 +00:30:44,320 --> 00:30:55,280 +اقول Methanol زائد Ethanol بالحرارة و الحامض هذا + +319 +00:30:55,280 --> 00:31:01,790 +كام مركب كام Ether كان يعطيليكان يعطيني تلاتة مثل + +320 +00:31:01,790 --> 00:31:11,130 +او مثل او اثل او اثل او مثل او اثل طب هتقول هذا ال + +321 +00:31:11,130 --> 00:31:16,610 +synthesis مقبول ولا لأ مرفوض في ال ethers مرفوض + +322 +00:31:16,610 --> 00:31:19,650 +لان انا بدي اطلع تلاتة و اقعد افصلهم طب كيف كنا + +323 +00:31:19,650 --> 00:31:24,810 +نعمل كنا نقول خلي واحد منهم يصير مثل او minus + +324 +00:31:24,810 --> 00:31:33,920 +التاني يصير اثل CLCH3 CH2 CL نبدل ال OH بCL مثلا + +325 +00:31:33,920 --> 00:31:39,000 +من PCL3 و بعدين نفعل هدول التنين مع بعض كانوا + +326 +00:31:39,000 --> 00:31:45,980 +بيعطوني بس المثل O Ethan واضح؟ + +327 +00:31:45,980 --> 00:31:52,720 +واحد نخليه O minus والتاني نخليه CL و نخلطهم هيك + +328 +00:31:52,720 --> 00:32:00,300 +بيعطيني فقطناتج واحد لا غير بضحك الفكرة؟ هذه إيش + +329 +00:32:00,300 --> 00:32:06,500 +كان اسمها؟ طريقة William Sun لتحضير ال ether الآن + +330 +00:32:06,500 --> 00:32:13,220 +لما بدي أحضر ال un-symmetrical unhydride نفسها + +331 +00:32:13,220 --> 00:32:19,520 +تماما 100% لكن بدل ما أنا مبتدئ بكحول في ال + +332 +00:32:19,520 --> 00:32:25,140 +unhydride بدي أبتدئ من إيش؟من الـ Acid خلّيني أقول + +333 +00:32:25,140 --> 00:32:29,460 +بدي مثلا الـ Acetic Benzoic Anhydrate إذا إيش + +334 +00:32:29,460 --> 00:32:37,300 +الحامضين اللي بدي أبتدأ منهم Acetic Acid هاي CH3C + +335 +00:32:37,300 --> 00:32:44,280 +double bond O OH زائد Benzoic Acid Phenyl C double + +336 +00:32:44,280 --> 00:32:53,200 +bond O OH الآن لو خلطناهم بـ H Plus و Heatكم ناتج + +337 +00:32:53,200 --> 00:32:58,880 +الـ three products بنفع هذا الكلام مقبول اللي بعمل + +338 +00:32:58,880 --> 00:33:03,060 +زي هيك ايش بيكون بيشتغل غلط ال three products + +339 +00:33:03,060 --> 00:33:07,580 +موازية تماما لفكرة ال ethers الان واحد منهم بدنا + +340 +00:33:07,580 --> 00:33:11,220 +نخلي O minus نفترض هذا + +341 +00:33:13,840 --> 00:33:19,860 +CH3C double bond O O minus والتاني بدنا نخلي CL + +342 +00:33:19,860 --> 00:33:26,220 +فنل C double bond O CL هدولة لما نخلطهم بده يطلع + +343 +00:33:26,220 --> 00:33:33,700 +عندنا ناتج واحد فقط نرسمها CH3C double bond O O C + +344 +00:33:33,700 --> 00:33:41,680 +double bond O فنل على أساس أن هذه بتهاجمها و بتطرد + +345 +00:33:42,840 --> 00:33:48,240 +الـ Cl واضح؟ طبعا ممكن حد يقول كيف هذا بنحول ال + +346 +00:33:48,240 --> 00:33:54,840 +acid ال acid ل O minus بالتفاعل مع N A O H حمزاد + +347 +00:33:54,840 --> 00:33:55,680 +قاعدة + +348 +00:33:59,270 --> 00:34:03,890 +NA قدش كتير عليه دائما مستعمل أقل شغلة مع ال NA + +349 +00:34:03,890 --> 00:34:08,170 +هياعمل حريقة هيكون التفاعل violent مع ال NA و لا + +350 +00:34:08,170 --> 00:34:14,470 +مع ال NA او ال NA قدش كتير عليه هيعمل حريقةمع ال N + +351 +00:34:14,470 --> 00:34:17,470 +A و N A H ماشي الحمض يتفاعل مع ال N A و N A H + +352 +00:34:17,470 --> 00:34:21,570 +الكحول هداج زنبه ع جنبه مكانش يتفاعل مع ال N A و N + +353 +00:34:21,570 --> 00:34:26,970 +A H ولذلك استعملتله N A و N A H لكن الحمض بتفاعل + +354 +00:34:26,970 --> 00:34:31,670 +مع ال N A و N A H ولا لأ بتفاعل و هذا بي سي ال + +355 +00:34:31,670 --> 00:34:37,050 +اثنين اذا حامض طبعا واحدة ممكن تسأل انواع نخلي O + +356 +00:34:37,050 --> 00:34:42,970 +minus وانواع C L مش فارقفى ال ethers كان فارق ال + +357 +00:34:42,970 --> 00:34:48,330 +CL بنا نخليه ال primary هنا مش فارق واحد بخليه O + +358 +00:34:48,330 --> 00:34:55,210 +minus والتانى بخليه CL و بعدين بفعلهم هيطلع عندى + +359 +00:34:55,210 --> 00:35:01,650 +ال unsymmetrical anhydride + +360 +00:35:01,650 --> 00:35:10,810 +واضحة الفكرةوهي طريقة تحضير الـ Acidic Benzoic + +361 +00:35:10,810 --> 00:35:16,290 +Anhydride فيه أوضح من هيك؟ مرة جيبناها سؤال هذا + +362 +00:35:16,290 --> 00:35:20,230 +المركب، قولنا للطلاب سمي المركب التالي واذكر طريقة + +363 +00:35:20,230 --> 00:35:27,250 +تحضيره، ما جوابوش عشرة في المية، بتصدقوا؟ ليش؟لأنه + +364 +00:35:27,250 --> 00:35:31,370 +مابيطبقوش مابيعدوش الكتابة خمس مرات لحد ما إيدهم + +365 +00:35:31,370 --> 00:35:36,830 +تتعود على الكيميا ولذلك لو بدكوا تطلعوا على سبيل + +366 +00:35:36,830 --> 00:35:42,270 +المثال هذا الكلام جيد إنه الكل يسمعوا حتى الناس + +367 +00:35:42,270 --> 00:35:46,470 +اللي بيشاهدوا الفيديو الطالب اللي مابيكتب كيميا + +368 +00:35:46,470 --> 00:35:53,090 +كتيرما بيكتب كيميا كتير هذا فن بحاجة إلى تدريب + +369 +00:35:53,090 --> 00:36:00,310 +ولذلك قد تستغربوا انه لما جيبنالكم بنزين وقلنا + +370 +00:36:00,310 --> 00:36:06,890 +حطوا عليها بس مجموعة إثل زي هيك يعني كتبنا CH3 + +371 +00:36:06,890 --> 00:36:15,070 +CH2Cl في وجود الـFeCl3 تمام؟ + +372 +00:36:16,720 --> 00:36:24,060 +الآن بنسبة 70% منكم عندهم فهم ولكن عندهم خطأ في + +373 +00:36:24,060 --> 00:36:28,300 +التنفيذ لأنهم مادربوش إيديهم يكتبوا كان الجواب + +374 +00:36:28,300 --> 00:36:40,280 +اللي كتب بهذا الشكل الان + +375 +00:36:40,280 --> 00:36:44,720 +انتوا بتحكوا لكن انا عندى إحصائيةأنا بعمل إحصائية + +376 +00:36:44,720 --> 00:36:49,560 +كيف بتكتبوا، 70% منكم كتبوا بهذا الشكل، لا هذه ال + +377 +00:36:49,560 --> 00:36:53,780 +carbon أربع روابط ولا هذه أربع روابط ولا محل مكانة + +378 +00:36:53,780 --> 00:36:59,280 +ال CL عملوا التفاعل كل هذه الأشياء ليش؟ لأنه مافيش + +379 +00:36:59,280 --> 00:37:05,900 +تطبيق، الأصل أنه هنا نكون كاتبين CH2 CH3 + +380 +00:37:07,280 --> 00:37:14,480 +الان لما جيبنالكم فاعله مع CH3CWOCL الاصل بدكوا + +381 +00:37:14,480 --> 00:37:23,960 +تحطه من هنا من محل ال CL يعني تحطه CWOCL + +382 +00:37:23,960 --> 00:37:31,560 +ربما خمسين في المية منكم حطوا هنا CWO وحطوا هنا + +383 +00:37:31,560 --> 00:37:40,360 +CH3 بهذا الشكل بهذا الشكللا تحزروا روسكو و إلا + +384 +00:37:40,360 --> 00:37:44,380 +بجيب الورق و بفرجيكوا إياه ليش؟ لأنه ماصارش عندكم + +385 +00:37:44,380 --> 00:37:49,140 +تطبيق اللي بيدخل على كلية علمية جامعية بده يتعب و + +386 +00:37:49,140 --> 00:37:54,980 +هو بيطبق و يكتب كتير و يتعب كتير عشان يشتغل صح لكن + +387 +00:37:54,980 --> 00:37:59,020 +هذا الكلام خمسين في المية يمكن كتبوه من الطالبات و + +388 +00:37:59,020 --> 00:38:02,440 +هذا الكلام اللي كان تول سبعين في المية من الطالبات + +389 +00:38:02,440 --> 00:38:07,760 +كتبوه ليش؟ لأنهم بدهم يقرؤوا ال organic قراءة + +390 +00:38:08,820 --> 00:38:14,640 +أدبيات الرافعي الرافعي يقرأ استلقاء و ال organic + +391 +00:38:14,640 --> 00:38:28,580 +تقرأ كتابة و تطبيقا واضحة الفكرة هاي + +392 +00:38:28,580 --> 00:38:36,210 +ال acid anhydride الان لاحظوا من الأحماضاللي + +393 +00:38:36,210 --> 00:38:42,090 +درسناها ال die acids يعني يكون عندى حامضين في نفس + +394 +00:38:42,090 --> 00:38:49,250 +الجزء أخدنا لما يكون عندى أربع ذرات كربون الحامض + +395 +00:38:49,250 --> 00:38:53,750 +اللى بيكون بال sis form اسمه malic acid و اللى بال + +396 +00:38:53,750 --> 00:39:01,690 +transform يهودا ايوة اللى بال transform زى هذا شو + +397 +00:39:01,690 --> 00:39:02,450 +اسمه؟ + +398 +00:39:15,400 --> 00:39:21,740 +لاحظوا أفضل واحدة فيكم برضه نتيجة عدم التطبيق جابت + +399 +00:39:21,740 --> 00:39:26,200 +زرع من الإسم وأكيد لو كانت متحة هيكون خطأ جالت + +400 +00:39:26,200 --> 00:39:31,680 +فورمك لكن تأكيدا والمحاضرات ابتشرت عليكم اسمه + +401 +00:39:31,680 --> 00:39:39,850 +fumaric acidmalic acid و fumaric acid شوفتوا كيف + +402 +00:39:39,850 --> 00:39:44,830 +التطبيق بيفرق عندنا أكيد لو ارجعنا أول ما أخدنا ال + +403 +00:39:44,830 --> 00:39:49,130 +die acids حكيناهم و قولنا واحد بناخده من التفاح و + +404 +00:39:49,130 --> 00:39:54,650 +التاني من الأغنام و كل هذا الكلام لكن كم مرة كتبت + +405 +00:39:54,650 --> 00:39:58,990 +أنا شكل ال malic acid و ال fumaric acid ولا مرة + +406 +00:39:58,990 --> 00:40:05,280 +كيف بدي أتذكرهممش هتذكرهم الان لاحظوا معي المالية + +407 +00:40:05,280 --> 00:40:12,040 +كان SIS الفيومارك كانت Trans يعني كان في مجمعتين + +408 +00:40:12,040 --> 00:40:18,810 +ال OHSمجمعتين ال acid بعاد عن بعض الان هذا مركب ال + +409 +00:40:18,810 --> 00:40:24,370 +cess لو سخنته انا عند 135 حامض بتفعلها حامض هذه + +410 +00:40:24,370 --> 00:40:29,210 +بتيجي هان و بتطرد ال OH بتعطيني unhydrate لما بدي + +411 +00:40:29,210 --> 00:40:34,930 +اسميه شو هسميه مليك unhydrate مليك قولنا كمان و + +412 +00:40:34,930 --> 00:40:38,410 +أكدنا انه بنستعمل ال E اللي هي تعبير على ال alkyl + +413 +00:40:38,410 --> 00:40:45,220 +وقولنا الملكحمض تاني بدون ال E حامض تاني ملك acid + +414 +00:40:45,220 --> 00:40:52,660 +موجود ومليك acid موجود واضح؟ الان لو اجت واحدة + +415 +00:40:52,660 --> 00:40:59,880 +سخنت هذا الحامض بالحرارة ايش رأيكوا هيصير؟ هيعمل + +416 +00:40:59,880 --> 00:41:04,540 +unhydrate مع نفسه؟ + +417 +00:41:04,540 --> 00:41:09,720 +يعني هذه تهاجم هنا؟ ليش؟ + +418 +00:41:10,730 --> 00:41:16,310 +لأن هم بعاد .. لأن هم بعاد .. طيب بتقولون ما بتلف + +419 +00:41:16,310 --> 00:41:21,030 +حوالين ال double bond .. الدوران حوالين ال double + +420 +00:41:21,030 --> 00:41:28,300 +bond .. ممنوع .. ولذلك تسخين الماليك أسدبيعمل + +421 +00:41:28,300 --> 00:41:33,920 +unhydrate تسخين لثيوميرك أسد بيعملش unhydrate فلو + +422 +00:41:33,920 --> 00:41:37,920 +انتوا اتطلعتوا في كاتالوجي الكيميا بتلاقوا مركب + +423 +00:41:37,920 --> 00:41:42,580 +اسمه مليك unhydrate بس بتلاقوش مركب اسمه ثيوميرك + +424 +00:41:42,580 --> 00:41:49,100 +unhydrate لأن مجمعتين ال OHS ابعاد عن بعضهم البعض + +425 +00:41:49,100 --> 00:41:54,890 +واضح فمش هيصل يتفاعلوا مع بعضهم البعضالان نفس + +426 +00:41:54,890 --> 00:42:01,430 +الفكرة تماما لو اجيت على مجموعتين acid موجودات على + +427 +00:42:01,430 --> 00:42:09,450 +بنزينة قولت هدول المجموعتين كيف يمكن ان يوجدوا يا + +428 +00:42:09,450 --> 00:42:16,170 +اما واحد اتنين اورثو يا واحد تلاتة ميتا يا واحد + +429 +00:42:16,170 --> 00:42:21,520 +اربعة باراتمام يعني غير هذا اللي موجود المجموعتين + +430 +00:42:21,520 --> 00:42:26,580 +على واحد اتنين ايضا موجود انه يكونوا مجموعتين ال + +431 +00:42:26,580 --> 00:42:34,900 +acid COOH و COOH على نمرة واحد واحد اتنين تلاتة + +432 +00:42:34,900 --> 00:42:40,860 +وموجود كمان انهم يكونوا على نمرة واحد واربعة COOH + +433 +00:42:40,860 --> 00:42:48,750 +مثلا و COOH واحد اتنين تلاتة اربعةهدولة التلت + +434 +00:42:48,750 --> 00:42:54,170 +أحماض موجودين و سمناهم اللي على ال Ortho سمناه + +435 +00:42:54,170 --> 00:43:00,950 +Phthalic Acid و اللي على ال NETA Isophthalic Acid + +436 +00:43:00,950 --> 00:43:05,910 +و اللي على البارا Terephthalic Acid و قولنالكوا + +437 +00:43:05,910 --> 00:43:11,010 +احفظوهم الآن لو يا ترى إجينا نسخن هدولة التلاتة + +438 +00:43:11,010 --> 00:43:17,070 +مين فكركوا منهم اللي ممكن يعمل Unhydrate؟الأورثو + +439 +00:43:17,070 --> 00:43:22,990 +ولا النيتا ولا البارا بس الأورثو لأن هدول بعاد عن + +440 +00:43:22,990 --> 00:43:29,090 +بعض مابيجوش فهذا بيعملش أنهيدريد ال isothelic acid + +441 +00:43:29,090 --> 00:43:33,010 +و ال teraphthalic acid بيعملش أنهيدريد هذا بيعمل + +442 +00:43:33,010 --> 00:43:39,150 +أنهيدريد لو قلنالكوا أرسم الانهيدريد الناتجهي + +443 +00:43:39,150 --> 00:43:45,690 +البنزينة عندى C double bond O و هنا C double bond + +444 +00:43:45,690 --> 00:43:52,570 +O و بينهم O هى مجموعة الانهيدريد C double bond O O + +445 +00:43:52,570 --> 00:43:58,850 +C double bond O و هذا بيصير ايش اسمه افثالك + +446 +00:43:58,850 --> 00:44:01,810 +انهيدريد + +447 +00:44:04,120 --> 00:44:12,560 +أفثالك أنهايدرايد واضح طبعا + +448 +00:44:12,560 --> 00:44:16,960 +هذه ال mix انهايدرايد حكينا عنها كيف بتتحضر واحد O + +449 +00:44:16,960 --> 00:44:20,520 +minus والتاني CL وهي تسميتهم acidic benzoic + +450 +00:44:20,520 --> 00:44:22,060 +anhydride حكينا عنه + +451 +00:44:29,520 --> 00:44:36,740 +طبعا لو كنا بدنا ندرس تفاعلات الانهيدريد واحدة + +452 +00:44:36,740 --> 00:44:40,340 +تختصر تفاعلات الانهيدريد بكلمة شو هتقول عنهم + +453 +00:44:40,340 --> 00:44:47,660 +substitution reaction طبعا ال substitution بده يتم + +454 +00:44:47,660 --> 00:44:56,020 +هان و نطرد كل هذه المجموعة بتخرج على شكل إيشحمض مع + +455 +00:44:56,020 --> 00:45:00,360 +الأموليا بيعطيني أمد مثلا مع الكحول بيعطيني Easter + +456 +00:45:00,360 --> 00:45:05,240 +مع الميه بيعطيني ال acid التاني و هكذا من هذه + +457 +00:45:05,240 --> 00:45:09,960 +النقطة ان شاء الله المرة القادمة بنبدأ بنأكد عليها + +458 +00:45:09,960 --> 00:45:14,960 +بس بتكونوا تدربتوا عليها تفاعلات ال acid + +459 +00:45:14,960 --> 00:45:18,000 +anhydrides بال substitution بالإبدال + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..ceb55e18286175388f27d17e343d2fabc5771085 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_raw.srt @@ -0,0 +1,1836 @@ +1 +00:00:19,620 --> 00:00:25,000 +بسم الله الرحمن الرحيممازلنا احنا بنتكلم في موضوع + +2 +00:00:25,000 --> 00:00:28,880 +الأحماض ومشتقاتها المرة الماضية اتكلمنا عن ال E + +3 +00:00:28,880 --> 00:00:34,940 +-stars وطرق تحضيرهم وبدأنا في موضوع تفاعلات ال E + +4 +00:00:34,940 --> 00:00:40,040 +-stars قولنا أول شيء أن التفاعل الأساسي اللي + +5 +00:00:40,040 --> 00:00:44,520 +هيتكرر معنا في كل هذا الفصل للأحماض وجميع مشتقاتها + +6 +00:00:44,520 --> 00:00:49,020 +وتفاعل الإجدال فكان أول تفاعل أخدناه عن ال E-stars + +7 +00:00:49,020 --> 00:00:54,430 +ال ammonolysis يعني أن نبدل ال ORب نيتروجين + +8 +00:00:54,430 --> 00:01:00,210 +وبالتالي بيطلع عندنا أمد وشوفنا كيف مثلا اتكون ال + +9 +00:01:00,210 --> 00:01:03,870 +بنز أمد الأسيتامد ما إلى ذلك في نهاية + +10 +00:01:03,870 --> 00:01:09,210 +اليوكليوفيليك substitution الآن من التفاعلات + +11 +00:01:09,210 --> 00:01:15,190 +التانية من التفاعلات التانية لل E starsالريدكشن + +12 +00:01:15,190 --> 00:01:20,230 +الريدكشن بالليثيوم الومنوم هايدرايد سبق احنا + +13 +00:01:20,230 --> 00:01:24,810 +اتعرفنا حقيقة على الليثيوم الومنوم هايدرايد قولنا + +14 +00:01:24,810 --> 00:01:30,980 +الاساس اللي فيه الاساس اللي فيه هو ال H-يعني انا + +15 +00:01:30,980 --> 00:01:35,320 +اللى بدى استفيده من ال high drive H minus الان + +16 +00:01:35,320 --> 00:01:41,260 +بدكوا تتخيلوا ان ال H minus بدها تهاجم على هذا ال + +17 +00:01:41,260 --> 00:01:45,120 +Easter بدها تهاجم على هذا ال Easter شو بدها تعمل + +18 +00:01:45,120 --> 00:01:51,680 +ابدا مكان ال OR بناء على ذلك الناتج اللى بده يطلع + +19 +00:01:51,680 --> 00:01:57,460 +عندكم بالدرجة الأولى R C double bond O H + +20 +00:02:00,330 --> 00:02:06,850 +واضح؟ شيلنا ال OR و حطينا ال H طبعا إذا بتلاحظوا + +21 +00:02:06,850 --> 00:02:12,330 +هذا ال ناتج اللي اتكون عندى هو عبارة عن ال الديهيد + +22 +00:02:12,330 --> 00:02:17,570 +احنا أخدنا في chapter ال الديهيد و ال ketones ان + +23 +00:02:17,570 --> 00:02:22,310 +ال الديهيد و ال ketones بيتفاعلوا مع ال hydride + +24 +00:02:22,890 --> 00:02:27,170 +الالديهيدز بتعطيني ال primary alcohol و ال ketone + +25 +00:02:27,170 --> 00:02:30,890 +ال secondary alcohol بناء على ذلك هذا ال الديهيدز + +26 +00:02:30,890 --> 00:02:36,670 +اللي اتكون هنا مرة تانية لو اجت فاعل مع ال H minus + +27 +00:02:36,670 --> 00:02:42,290 +الان هذا كان E star ال E star ايش تفاعله المميز + +28 +00:02:42,290 --> 00:02:44,250 +Substitution + +29 +00:02:46,570 --> 00:02:50,930 +لما عملت substitution صار ال الديهايد ال الديهايد + +30 +00:02:50,930 --> 00:02:56,990 +شو تفاعله addition هم الكلمتين تحكوليش غيرهم فقط + +31 +00:02:56,990 --> 00:03:01,890 +بسمع هنا substitution وهنا بسمع addition طالما هذا + +32 +00:03:01,890 --> 00:03:06,770 +الديهايد addition طبعا هتيجي H و سيضة بال bond O + +33 +00:03:06,770 --> 00:03:11,090 +شو تصير O H هذا التفاعل سبق أخدنا الديهايد مع ال + +34 +00:03:11,090 --> 00:03:16,990 +hydride بيعمل addition والنتيجة هتكون إيشprimary + +35 +00:03:16,990 --> 00:03:22,810 +alcohol إذا لو أنا أخدت التفاعل بالمجمل تفاعل ال + +36 +00:03:22,810 --> 00:03:28,750 +eastern مع ال hydride بينتهي في النهاية ب primary + +37 +00:03:28,750 --> 00:03:33,090 +alcohol لكن ننتبه أنه مرورا بال aldehyde الآن هذا + +38 +00:03:33,090 --> 00:03:38,110 +ال aldehyde لا يفصلواضح؟ يعني بنفعل بتكون ال + +39 +00:03:38,110 --> 00:03:41,990 +الديهايد ع طول بلاجة اتش تانية يتفعل معاها بيصفى + +40 +00:03:41,990 --> 00:03:46,650 +primary alcohol عشان هيك هذا الكلام حتى نكون + +41 +00:03:46,650 --> 00:03:50,910 +فاهمين بالظبط إيش اللي صار معنا لكن بدل المرة ألف + +42 +00:03:50,910 --> 00:03:55,410 +بقول لو قلتلكوا أكمل المعادلة أكمل الفراغ بدي + +43 +00:03:55,410 --> 00:04:00,640 +Easterمع hydride في النهاية انا بده اشوف ال + +44 +00:04:00,640 --> 00:04:03,620 +primary alcohol ربما لهذا السبب انتوا شايفين + +45 +00:04:03,620 --> 00:04:07,580 +المعادلة في نهايتها ايش؟ primary alcohol لكن هي في + +46 +00:04:07,580 --> 00:04:13,440 +تفصيلها كام خطوة؟ خطوتين هي في تفصيلها خطوتين + +47 +00:04:13,440 --> 00:04:18,980 +إبدال كون ال aldehyde و بعدين إضافة كونت ال + +48 +00:04:18,980 --> 00:04:25,150 +primary alcohol واضحة الفكرة؟الان زى هذا التفاعل + +49 +00:04:25,150 --> 00:04:31,970 +تماما زى هذا التفاعل تماما لو يا تورا اجينا فعلنا + +50 +00:04:31,970 --> 00:04:35,890 +و هذا مش مكتوب عندكوا لكن بنضيفه عليكم لو اجينا + +51 +00:04:35,890 --> 00:04:42,590 +فعلنا ال Easter مش مع H minus مع R minus طبعا اللى + +52 +00:04:42,590 --> 00:04:47,890 +بنقصده في R بهدى الحالة ايش ال green yard reagent + +53 +00:04:47,890 --> 00:04:59,080 +ال Rمجي اكس مصدر لل R مينوس مظبوط ولا لأ هيحط R + +54 +00:04:59,080 --> 00:05:05,220 +مرتين فى المرة الأولى شو هيحط هنا R كوّن لك + +55 +00:05:05,220 --> 00:05:13,140 +الكيتون الان كمان مرة R تانية نشيل هدول ال chain + +56 +00:05:13,140 --> 00:05:18,820 +اللى كانوا من ال high drive نحط R وR + +57 +00:05:20,670 --> 00:05:26,770 +إذا في هذه الحالة التفاعل مع جرينيارد شو بيعطيني + +58 +00:05:26,770 --> 00:05:32,210 +تيرتشاري ألكول لأن R كانت أصلا من ال Easter وتنتين + +59 +00:05:32,210 --> 00:05:35,210 +متشابهات اتجوا من الجرينيارد يعني لو افترضنا مثلا + +60 +00:05:35,210 --> 00:05:39,990 +أن هذه كانت فنل وفعلت + +61 +00:05:39,990 --> 00:05:44,130 +مع إيثل ماجنيسيا مبروماي على مرتين أول مرة هيحق + +62 +00:05:44,130 --> 00:05:51,170 +إيثل و تاني مرة كمان إيثل إذا ال Easterفي المحصلة + +63 +00:05:51,170 --> 00:05:59,510 +مع الـ Greenyard reagent بدوا يعطيني تيرتشاريه + +64 +00:05:59,510 --> 00:06:05,710 +الكهول تماما نفس التفاعل اللي مع الهيدرايد لكن بدل + +65 +00:06:05,710 --> 00:06:10,210 +ما كنت بضيف H- مرتين يعني مرة بالإبدال و مرة + +66 +00:06:10,210 --> 00:06:21,410 +بالإضافة بحط R- مرتين واضح بحط ال R- مرتينلاحظوا + +67 +00:06:21,410 --> 00:06:27,030 +معي للناس اللي بيحاولوا يفهموا الأمور بصورتها + +68 +00:06:27,030 --> 00:06:31,730 +الكلية للناس اللي بيحاولوا يفهموا الأمور بصورتها + +69 +00:06:31,730 --> 00:06:38,410 +الكلية السهلة مش بالمسميات الضيقة الآن هذا Easter + +70 +00:06:38,410 --> 00:06:43,130 +اعملتله انا تفاعلين و اتعمت لما عرفتهم التفاعل + +71 +00:06:43,130 --> 00:06:43,670 +الأول + +72 +00:06:47,190 --> 00:06:51,550 +الـ Hydrides و أعطاني Primary Alcohols و التفاعل + +73 +00:06:51,550 --> 00:06:54,790 +التالي معي Green Yard Reagent و أعطاني Tertiary + +74 +00:06:54,790 --> 00:06:59,530 +Alcohol مرورا بالكيتون في هذه الحالة الآن هذه + +75 +00:06:59,530 --> 00:07:07,070 +المجموعة الـ OR مجموعة إيه شمالها؟مطرودة طردت جيبت + +76 +00:07:07,070 --> 00:07:14,170 +سيرتها لأ طيب يا تورا لو بعد شوية أخدنا ال acid + +77 +00:07:14,170 --> 00:07:19,090 +halides بمعنى ماكناش نبدأ ب E star و المجموعة + +78 +00:07:19,090 --> 00:07:23,670 +المطرودة OR كان عندنا acid halide كان تادي CL أو + +79 +00:07:23,670 --> 00:07:32,570 +PR و إجيت قولت تفاعل ال acid halide مع ال hydrides + +80 +00:07:32,570 --> 00:07:40,530 +شو هيعطيلي؟نفس الكلام تماماً لأنه طردت OR أو طردت + +81 +00:07:40,530 --> 00:07:45,310 +CL وباقي الناتج زي ما هو ال primary alcohol تفاعل + +82 +00:07:45,310 --> 00:07:50,170 +acid halide مع grignard reagent tertiary alcohol + +83 +00:07:50,170 --> 00:07:54,890 +واضح؟ شو بديفرق التفاعل إذا كانت المجموعة اللي + +84 +00:07:54,890 --> 00:07:59,810 +طردت OR و أخدت H طلعت على شكل alcohol ولا CL minus + +85 +00:07:59,810 --> 00:08:06,360 +و أخدت H طلعت على HCLواضح؟ وعشان هيك اللي بيعرف + +86 +00:08:06,360 --> 00:08:10,240 +أنه ال Easter بتفاعل مع ال hydrates ومع greenery + +87 +00:08:10,240 --> 00:08:15,880 +agent بطريقة معينة بنقوله كمان و ال acid chlorides + +88 +00:08:15,880 --> 00:08:21,970 +بتفاعلوا مع ال hydrates ومع greenery agentبنفس + +89 +00:08:21,970 --> 00:08:27,090 +الطريقة تماما مافرجش انه يكونش المجموعة المطرودة + +90 +00:08:27,090 --> 00:08:31,710 +هي OR ولا CL هذه مجموعة مطرودة لكن الجزء ال + +91 +00:08:31,710 --> 00:08:36,870 +organic اللي عندى جزء اشماله ثابت واضح الفكرة + +92 +00:08:49,670 --> 00:08:55,890 +الان بننتقل ل ال acid halides ال acid halides قلنا + +93 +00:08:55,890 --> 00:09:00,290 +عنهم مشتقات ايضا من الأحماض و لما اتكلمنا عن + +94 +00:09:00,290 --> 00:09:06,030 +تفاعلات الأحماض اتكلمنا عن تحضيرهم قلنا اذا أخدنا + +95 +00:09:06,030 --> 00:09:10,990 +ال organic acid مع ال phosphorus trichloride او ال + +96 +00:09:10,990 --> 00:09:20,920 +SOCl2 يهدي يهدي بيشيل ال OH و بيحطلهCL فال acid + +97 +00:09:20,920 --> 00:09:25,480 +بتحول الى acid chlorides طريقة التحضير طريقة ايش + +98 +00:09:25,480 --> 00:09:31,600 +سهلة الان لو اجينا للتسمية كيف بنسمي ال acid + +99 +00:09:31,600 --> 00:09:39,190 +halides احنا كان هنا في عندنا OECacid الآن بدنا + +100 +00:09:39,190 --> 00:09:44,930 +نغير كلمة acid بكلمة halide بدنا نغير كلمة acid + +101 +00:09:44,930 --> 00:09:49,790 +بكلمة halide و ال oic بنخليها oil يعني لو أخدنا + +102 +00:09:49,790 --> 00:09:56,510 +ethanoic acid اللي هو الحامض اللي من carbon 10 بدو + +103 +00:09:56,510 --> 00:10:02,350 +يصير ethanoic chloride لو هنا bromالبروميد لو + +104 +00:10:02,350 --> 00:10:07,770 +أخدنا ال common name تبعه acidic acid بس بنشيل ايش + +105 +00:10:07,770 --> 00:10:13,490 +كلمة acid و بنحط chloride فهذا المركب ايش بيصير + +106 +00:10:13,490 --> 00:10:19,750 +Acetyl لأ بنرجع للمجموعة YL Acetic منها Acetyl + +107 +00:10:19,750 --> 00:10:27,400 +واضح لأن هذه اتعرفنا عليها Acetylمتذكرينها؟ أسيتل + +108 +00:10:27,400 --> 00:10:33,560 +و بنكتب إيش؟ أكلورايد فالفكرة بدنا نشيل هذا جزء + +109 +00:10:33,560 --> 00:10:39,000 +الأسيتل و ننهب وي الهلايد أسيتل أكلورايد و منها + +110 +00:10:39,000 --> 00:10:43,380 +كمان سبق إن اتعرفنا على مجموعة ال بنزويل من وين + +111 +00:10:43,380 --> 00:10:48,920 +بنجيب ال بنزويل أكلورايد؟ لو أجينا سألناكم بنزويل + +112 +00:10:48,920 --> 00:10:54,300 +أكلورايد بدنا نجيبه من؟ + +113 +00:10:55,720 --> 00:11:03,440 +البنزويك أسد C double bond O OH في ال BCL3 أو أي + +114 +00:11:03,440 --> 00:11:07,640 +حاجة C + +115 +00:11:07,640 --> 00:11:14,360 +double bond O Cl هذا إيش بده يصير بنزويل لإن هذه + +116 +00:11:14,360 --> 00:11:19,900 +مجموعة البنزويل فنل C double bond O بنزويل + +117 +00:11:19,900 --> 00:11:29,870 +إكلورايدوالبنزول كمجموعة مرات بتختصر بي زد هيك + +118 +00:11:29,870 --> 00:11:35,250 +بنزول إكلورايد فإذا قرأته كلمة بي زد هذا اختصار + +119 +00:11:35,250 --> 00:11:40,330 +إيش بنزول بنزول إكلورايد واللي علمكوا ال بنزول + +120 +00:11:40,330 --> 00:11:45,230 +جالكوا تذكروا أنه في إلها بنت عم بتشبهها في + +121 +00:11:45,230 --> 00:11:49,510 +الكتابة اللي هي بنزل إكلورايد بس ال بنزل إكلورايد + +122 +00:11:49,510 --> 00:11:57,190 +عبارة عنفين ال CH2 نفترض CH2 فين ال CH2 هذه مجموعة + +123 +00:11:57,190 --> 00:12:06,230 +البنزل مش بنزايل بنزل طبعا لو جيت سألكوا البنزل + +124 +00:12:06,230 --> 00:12:11,650 +كلورايد كهيلايد أي نوع من الهيلايد primary + +125 +00:12:11,650 --> 00:12:12,890 +alkalihilide + +126 +00:12:16,310 --> 00:12:21,030 +الكل واضح ماحدش ييجي يشوف هنا ال aromatic ويقول + +127 +00:12:21,030 --> 00:12:24,630 +عنه aromatic halide لأ هو ال aromatic halide لو + +128 +00:12:24,630 --> 00:12:29,370 +كانت ال CL متصلة مباشرة بالحلقة لكن طالما ال CL + +129 +00:12:29,370 --> 00:12:34,930 +متصلة ب CH2 إذا هذا الكل halide وبناء على ذلك بتيم + +130 +00:12:34,930 --> 00:12:37,970 +عليكوا التفاعلات الإبدال اللي درسناها في شبتر 6 + +131 +00:12:37,970 --> 00:12:42,070 +ولا لأ اه فهذا بنزل chloride + +132 +00:12:43,690 --> 00:12:47,390 +فبفرق بنزل الكلورايد عن بنزول الكلورايد وبنزل الى + +133 +00:12:47,390 --> 00:12:52,650 +اختصار بيختصرها BN واضح + +134 +00:12:52,650 --> 00:13:01,050 +بيختصرها BN بنزل فننتبه لهدول المجموعتين هذا ال + +135 +00:13:01,050 --> 00:13:07,150 +بنزول الكلورايد يعني إذا بدنا نوصفه بنقول عنه انه + +136 +00:13:07,150 --> 00:13:16,970 +إيش انه لعينليش بنوصف بهذا الوصف القاسي؟ لأن هذا + +137 +00:13:16,970 --> 00:13:22,430 +اللي هو عادة يستعمل كغاز مسيل للدموع يعني بتعرفوا + +138 +00:13:22,430 --> 00:13:27,630 +الغازات اللي في المظاهرات وغيرها، الغازات المسيلة + +139 +00:13:27,630 --> 00:13:34,930 +للدموع، معظمها acid halides، ومن ضمنهاالبنزول + +140 +00:13:34,930 --> 00:13:40,230 +الكلورايد من ضمنها البنزول الكلورايد طبعا لو اجينا + +141 +00:13:40,230 --> 00:13:45,850 +نقول ايش السبب ايش السبب ان هذا البنزول الكلورايد + +142 +00:13:45,850 --> 00:13:53,110 +يستعمل كغاز مسيل للدموع ناخد احنا بشكل عام + +143 +00:13:53,110 --> 00:13:58,330 +الكلورايد و تفاعلاتها ناخد بشكل عام الكلورايد و + +144 +00:13:58,330 --> 00:14:03,550 +تفاعلاتها طبعا مرتان تفاعلات الكلورايد هي تفاعلات + +145 +00:14:05,010 --> 00:14:09,570 +الإبدال يعني ال acid chloride مجرد ما بديه يتعرض + +146 +00:14:09,570 --> 00:14:14,410 +للميه مجرد ما بديه يتعرض للميه بديه يفقد ال CL و + +147 +00:14:14,410 --> 00:14:21,470 +يحط ال OH رجع لإيش؟ لل carboxylic acid واضح؟من حد + +148 +00:14:21,470 --> 00:14:25,590 +ما يتعرض للميه برجع ل acid لو فعلنا مع ال ethanol + +149 +00:14:25,590 --> 00:14:32,050 +بدو يشيل ال CL ويحط O-ethyl برجع ل E-star لو فعلنا + +150 +00:14:32,050 --> 00:14:37,890 +مع ال ammonia بدو يشيل ال CL ويحط NH2 بصير أمل فزي + +151 +00:14:37,890 --> 00:14:41,770 +ما اتفقنا أنه من واحد بنحضر التاني الآن خلينا على + +152 +00:14:41,770 --> 00:14:47,480 +المعادلة الأولىخلّينا على المعادلة الأولى و نتخيل + +153 +00:14:47,480 --> 00:14:52,020 +مثلا أنه إحنا اللي بدين فيه ال benzoyl chloride + +154 +00:14:52,020 --> 00:14:54,920 +اللي هو إيش موجود فيه بدل ال acetyl chloride هنا + +155 +00:14:55,790 --> 00:15:00,610 +فنل سيبا بالبوند OCL هذا البيزويل الكلوري + +156 +00:15:00,610 --> 00:15:06,190 +بيستعملوه كغاز مصير للدموع الآن السؤال هل هو غاز + +157 +00:15:06,190 --> 00:15:13,310 +أصلا لأ هو مادة زيتية يعني مادة + +158 +00:15:15,850 --> 00:15:22,150 +بحرارة غليان فوق المية درجة مئوية لكن لما بيرموه + +159 +00:15:22,150 --> 00:15:27,130 +في الجو بيطلع على شكل .. بيطلع على شكل رذاذ صغير + +160 +00:15:27,130 --> 00:15:31,350 +فبييجي على الناس بيبدو الناس يشموه بييجي على وجههم + +161 +00:15:31,350 --> 00:15:37,250 +يعني عملية قذفهفي الجو بيخليه يطلع على شكل إيش؟ + +162 +00:15:37,250 --> 00:15:42,470 +رذاذ، رذاذ صغير، الآن هذا الرذاذ الصغير اللي طلع + +163 +00:15:42,470 --> 00:15:49,750 +لو دخل على جسم الإنسان، هيدخل على الزور، هيجي على + +164 +00:15:49,750 --> 00:15:56,450 +العنين، شكل أساسي، الآن الزور و العنين فيهم مياه + +165 +00:15:57,990 --> 00:16:03,730 +إذا وجدت أنا هأعمل تفاعل البنزويلي كلوراي مع الميه + +166 +00:16:03,730 --> 00:16:09,590 +هطلع بنزويك أسد البنزويك أسد حمضه ضعيف مش منه + +167 +00:16:09,590 --> 00:16:16,350 +المشكلة لكن المشكلة أكتر من ال HCL ال HCL هو اللي + +168 +00:16:16,350 --> 00:16:22,950 +هيسبب الحرقان في العينين وفي الزور واضح ال HCL + +169 +00:16:22,950 --> 00:16:31,010 +الآن هذا نفسه لو إجه على الجلدمافيش منه مشكلة إذا + +170 +00:16:31,010 --> 00:16:34,350 +الجلد جافلكن بتعرفوا الناس اللي بيكونوا في + +171 +00:16:34,350 --> 00:16:39,010 +المظاهرات مرات بيكونوا عرقانين اه لو اجى معي العرق + +172 +00:16:39,010 --> 00:16:43,630 +و اجي اتعمل HCL بيصير الجلد يحرج لو افترضنا ان + +173 +00:16:43,630 --> 00:16:49,310 +البني ادم اللي كان في المظاهرة اجى عليه هو عبارة + +174 +00:16:49,310 --> 00:16:53,070 +عن سائل على الوجه على الجسم مافيش عنده مشكلة + +175 +00:16:53,070 --> 00:16:56,790 +ماحسشه مشاكل كتير غير في العنان و الزور لكن بعد + +176 +00:16:56,790 --> 00:17:02,630 +هيك لو راح يتوضى بالميةيغسل الإيدان و يغسل الوجه + +177 +00:17:02,630 --> 00:17:06,650 +بكمية ميه صغيرة بصير وشه و إيديه زي النار ليش؟ لإن + +178 +00:17:06,650 --> 00:17:14,530 +هو بحط ميه على رذاف بالزويل الكلورايفبتفعلوا بيطلع + +179 +00:17:14,530 --> 00:17:18,690 +إيش ال HCL و لذلك البني آدم اللي بده يمر بهذه + +180 +00:17:18,690 --> 00:17:24,670 +الظروف المفروض أنه بده يغير ملابسه بده يغسل بميه و + +181 +00:17:24,670 --> 00:17:29,870 +صابونة و كمية كبيرة جدا عشان يشيل هذه المادة ما + +182 +00:17:29,870 --> 00:17:34,450 +احنا قولنا مادة زيتية سائلة لو كان غاز كان اتبخر + +183 +00:17:34,450 --> 00:17:40,550 +في الهواء مع السلامة لكن هم بيرشوه و هم عارفينإنه + +184 +00:17:40,550 --> 00:17:43,850 +أنا بديش إياه يطير معي الهواء، إياه يظل ملزج في + +185 +00:17:43,850 --> 00:17:50,630 +الإنسان وفي الوجه ما هدوله اسمه فن إيش الإذاء اللي + +186 +00:17:50,630 --> 00:17:55,090 +بديه يرشي الغاز المسيل اللي قدوموه بديه يضر الناس + +187 +00:17:55,090 --> 00:17:59,790 +كذلك الحال بالمناسبة في موضوع غازات الأعصاب اللي + +188 +00:17:59,790 --> 00:18:06,700 +بتتدخل على الأعصاب أقوى الغازات أقلها تطيراهي كلها + +189 +00:18:06,700 --> 00:18:12,760 +سوائل بيسموها غازات تجاوزا، لكن ليش بيسموها غازات؟ + +190 +00:18:12,760 --> 00:18:16,800 +لأنه بينشروها على شكل رذاذ زي الميه لما بتنشرها + +191 +00:18:16,800 --> 00:18:21,220 +على شكل رذاذ أو ال spray العطر لما بتنشره على شكل + +192 +00:18:21,220 --> 00:18:28,440 +رذاذ، واضح الفكرة؟أكثرها تبخرا، أقلها تبخرا، لأنها + +193 +00:18:28,440 --> 00:18:32,660 +تبقى ملازقة في الأواعي، ملازقة في الأرض، ملازقة + +194 +00:18:32,660 --> 00:18:36,880 +على الحيطان، على السيارات، على الشجر وبهدوء تتبخر + +195 +00:18:36,880 --> 00:18:42,960 +وبتطلع كميات الغاز وبتضر البني آدم، بينما أكثرها + +196 +00:18:42,960 --> 00:18:50,180 +تبخرابيجي الهواء بياخده، بالتالي خطورته إيش؟ بتخف، + +197 +00:18:50,180 --> 00:18:55,220 +فالغازات الأعصاب مشهور منها غاز A، غاز B، غاز + +198 +00:18:55,220 --> 00:19:04,890 +بيسموه C في Novichok في VX، مسميات كثيرةاختارها + +199 +00:19:04,890 --> 00:19:11,070 +اقلها ايش؟ تبخرا، بيسموها nerve gases هذه الغازات + +200 +00:19:11,070 --> 00:19:17,150 +تبعت الدموع شو بيسموها؟ tear gases، tear يعني دموع + +201 +00:19:18,030 --> 00:19:22,610 +Tear gases او لكريماتر لكريماتر الغاز المثيل + +202 +00:19:22,610 --> 00:19:28,490 +للدموع او tear gas فالبنزويل الكلورايد is لكريماتر + +203 +00:19:28,490 --> 00:19:33,950 +or is a tear gas الفكرة الأساسية منه ان هو بتطلع + +204 +00:19:33,950 --> 00:19:40,320 +hcl اللي بيسبب ايشالحرقان طبعا في المجتمع الدولي + +205 +00:19:40,320 --> 00:19:44,260 +اللي موجود اليوم المجتمع الشيطاني البنزويل + +206 +00:19:44,260 --> 00:19:51,060 +الكلورايد هو حقيقة أرحم ما يمكن أن يُقذَف على + +207 +00:19:51,060 --> 00:19:54,820 +الناس اليوم بيستعملوا غازات أعصاب و بيستعملوا + +208 +00:19:54,820 --> 00:20:00,520 +غازات دموع مخلوطة بغازات أعصاب بنسب قليلة و كلها + +209 +00:20:00,520 --> 00:20:05,440 +أشد تأثيرا من البنزويل الكلورايد يعني أشرف غازات + +210 +00:20:05,440 --> 00:20:12,460 +للمظاهراتالبنزوليكلوريد وما عداها أكثر شدة وأكثر + +211 +00:20:12,460 --> 00:20:16,960 +إجراما وعشان ذلك لاحظوا أننا لما حكينا على + +212 +00:20:16,960 --> 00:20:20,620 +الخواصلة ال acid helites in general قلنا noxious + +213 +00:20:20,620 --> 00:20:27,580 +يعني مهيجة irritating بتعمل إصابات أو جروح react + +214 +00:20:27,580 --> 00:20:33,660 +violently with water بتتفاعل بقوة مع الميه معطية + +215 +00:20:33,660 --> 00:20:41,830 +الحامض الأصلي زائدالـ HCL نيجي + +216 +00:20:41,830 --> 00:20:47,760 +للعائلة اللي بعدهامن ال derivatives اللي هي ال + +217 +00:20:47,760 --> 00:20:53,660 +acid anhydrides ال acid anhydrides بتيجي من تفاعل + +218 +00:20:53,660 --> 00:20:59,940 +جزيئين من الحامض مع بعضهم البعض لاحظوا في موضوع ال + +219 +00:20:59,940 --> 00:21:04,500 +acid anhydrides من ناحية المبدأ من ناحية المبدأ + +220 +00:21:04,500 --> 00:21:12,330 +هناك شبه الطالب المنتبه بموضوع ال etherبموضوع إيش + +221 +00:21:12,330 --> 00:21:17,470 +ال ether إذا بتتذكروا لما كنا نتكلم عن ال ether + +222 +00:21:17,470 --> 00:21:21,390 +قسمنا ال ethers إلى نوعين قلنا في عندنا + +223 +00:21:21,390 --> 00:21:28,510 +symmetrical ethers و unsymmetrical ethersإذا كانت + +224 +00:21:28,510 --> 00:21:33,090 +الـR و الـR زي بعض هذا سمنا إيش؟ symmetrical ether + +225 +00:21:33,090 --> 00:21:38,030 +و لذلك لما كنا مثلا بدنا نضاي إيثل إيثر كنا ناخد + +226 +00:21:38,030 --> 00:21:42,370 +الكحول مش الحامض في النهاية في OH اللي هو على سبيل + +227 +00:21:42,370 --> 00:21:50,450 +المثال لو أخدنا الإيثانول بنسبة 2 مع H plus هو نفس + +228 +00:21:50,450 --> 00:21:58,660 +الفكرة تماما إيش كان هذا يعطينا؟ إيثل أوDiethyl + +229 +00:21:58,660 --> 00:22:03,100 +ether من + +230 +00:22:03,100 --> 00:22:09,660 +الكحول و Diethyl ether is symmetrical ether رور + +231 +00:22:11,320 --> 00:22:14,800 +شوف نقاش ال symmetrical فالكحول بيتفاعل مع نفسه + +232 +00:22:14,800 --> 00:22:19,800 +جوزيق بيهاجم على التاني و بيطرده مية و بتفاعله + +233 +00:22:19,800 --> 00:22:25,960 +الان الكلام نفسه بتم مع ال unhydrates لكن في هذه + +234 +00:22:25,960 --> 00:22:32,280 +الحالة الحامض بيتفاعل مع نفسهواضح؟ في هذه الحالة + +235 +00:22:32,280 --> 00:22:36,680 +الحامض يتفاعل مع نفسه يعني احنا اليوم موضوعنا ال + +236 +00:22:36,680 --> 00:22:41,000 +unhydrates لو بدأ اركز اكثر عليها بدأ اقول تخيلوا + +237 +00:22:41,000 --> 00:22:47,120 +ان هذا جزيق حامض بدأ افعله مع ايش؟ مع جزيق تاني + +238 +00:22:47,120 --> 00:22:54,980 +اللي هو OH سيضة بال bond Oنفترض CH3 هاي Acetic + +239 +00:22:54,980 --> 00:23:00,040 +Acid جزئ و هاي Acetic Acid كمان جزئ هاي الجزئين + +240 +00:23:00,040 --> 00:23:04,740 +خلصنا واضح؟ الآن هذا بده ييجي من خلال الـ OH اللي + +241 +00:23:04,740 --> 00:23:10,620 +هي الـ nucleophile إهاجمها يطرد الـ OH هذا تفاعل + +242 +00:23:10,620 --> 00:23:15,380 +الإبدال ولا لأ؟ هذا تفاعل الإبدال بناء على ذلك لما + +243 +00:23:15,380 --> 00:23:18,920 +تطرد الـ OH من هنا مع الـ H هذه + +244 +00:23:21,660 --> 00:23:29,940 +الجزء الأول اللي مبين بالأسود هي CH3COO + +245 +00:23:29,940 --> 00:23:35,100 +والجزء التاني OCOO + +246 +00:23:36,520 --> 00:23:42,080 +CH3 هيتكون عندى الـ Symmetrical Anhydride اتكون + +247 +00:23:42,080 --> 00:23:46,840 +عندى الـ Symmetrical Anhydride لاحظوا انه مجموعة + +248 +00:23:46,840 --> 00:23:52,840 +الانهيدريد كمجموعة عبارة عن ايش C double bond O O + +249 +00:23:52,840 --> 00:23:57,580 +C double bond O يعني لو بدى اقول ال ether كانت O + +250 +00:23:57,580 --> 00:24:03,620 +متصلة بتنتين R طيب الانهيدريد هى + +251 +00:24:06,590 --> 00:24:13,350 +هذه ثابتة C double bond O O C double bond O هذه + +252 +00:24:13,350 --> 00:24:17,670 +مجموعة الانهيدريد الآن لما فعلت الحامض مع نفسه + +253 +00:24:17,670 --> 00:24:23,890 +صارت هذه ال R و هذه ال R زي بعض ولذلك سميت هذا + +254 +00:24:23,890 --> 00:24:28,530 +symmetrical anhydride الآن السؤال طب لو خلت هذه + +255 +00:24:28,530 --> 00:24:33,690 +مثل وهذه اثلبتصير Unsymmetrical لو خلّيت فينيل و + +256 +00:24:33,690 --> 00:24:40,130 +إثل Unsymmetrical طبعا بيلزمنا نسمي و نحضر ال + +257 +00:24:40,130 --> 00:24:43,210 +symmetrical anhydride و الunsymmetrical anhydride + +258 +00:24:43,210 --> 00:24:47,050 +تماما زي ما عملنا مع ال aether احنا قولنا ال + +259 +00:24:47,050 --> 00:24:49,870 +aether كان الكحول مع نفسه أعطاني symmetrical + +260 +00:24:49,870 --> 00:24:54,350 +aether الآن ال symmetrical anhydride الحامض مع + +261 +00:24:54,350 --> 00:24:57,350 +نفسه بنسخنه في وجود حمض + +262 +00:25:00,190 --> 00:25:06,170 +بش ان مش واضح بنسخنه في وجود حمض و طبعا بنتخلي + +263 +00:25:06,170 --> 00:25:09,610 +شروط التفاعل تسحب الميه للخارج ليش؟ لأن هذا + +264 +00:25:09,610 --> 00:25:13,510 +التفاعل ما عدا ذلك عكس بترد الميه تهاجمها و ترجع + +265 +00:25:13,510 --> 00:25:17,230 +لحمضين ولذلك اللي بيعمل unhydrate بيكون عنده طريقة + +266 +00:25:17,230 --> 00:25:22,160 +يسحب فيها الميه لوينل الخارج يتخلص منها طب الآن + +267 +00:25:22,160 --> 00:25:27,640 +هذا كيف بدي أسميه على اسم الحامض بشيل كلمة acid و + +268 +00:25:27,640 --> 00:25:32,880 +بكتب unhydrate يعني هذا لو سمناه ethanoic acid ال + +269 +00:25:32,880 --> 00:25:37,700 +unhydrate تبعه إيش بدي يصير ethanoic unhydrate طب + +270 +00:25:37,700 --> 00:25:43,820 +لو سمناه بال common name acetic acid إيش بدي يتسمى + +271 +00:25:44,770 --> 00:25:53,230 +acetic anhydride فالتسمية إن نشيل كلمة + +272 +00:25:53,230 --> 00:25:59,850 +acid ونحط anhydride واضح التسمية إن نشيل كلمة acid + +273 +00:25:59,850 --> 00:26:04,250 +ونحط إيش anhydride الحامض اللي فيه المثل هو + +274 +00:26:04,250 --> 00:26:12,990 +الaceticالان لو اجينا وقلنالكم لو سمحتوا ارسمولنا + +275 +00:26:12,990 --> 00:26:20,510 +المركب القاتل بنزوك unhydrate بنزوك + +276 +00:26:20,510 --> 00:26:29,870 +unhydrate اول اشي ع طول بدكم تحطولي ايش هي مجموعة + +277 +00:26:29,870 --> 00:26:35,670 +ال unhydrate مجموعة ال unhydrate C double bond O O + +278 +00:26:37,550 --> 00:26:42,130 +خلّينا نعملها هيك C double bond O تابع هذه مجموعة + +279 +00:26:42,130 --> 00:26:47,810 +الانهيدريد الآن إذا كانت بنزوك فنل معناه ذلك سأضع + +280 +00:26:47,810 --> 00:26:55,250 +على الجهتين مجموعة الفنل فنل و فنل هذه بنزوك + +281 +00:26:55,250 --> 00:27:00,350 +انهيدريد لما نقول أسيتك مثل و مثل المجموعة تبع + +282 +00:27:00,350 --> 00:27:02,550 +الأسيتك أسيتك بروبانوك + +283 +00:27:07,410 --> 00:27:12,490 +بدوا يكون المجموع تلاتة اه انتبهوا معاك خلصنا من + +284 +00:27:12,490 --> 00:27:20,310 +ال benzoic اه اه لو اتيتكن اتكتبلكم بروبانوك لأنه + +285 +00:27:20,310 --> 00:27:25,810 +مرات بيغلطوا الطلاب بهذه النقطة بروبانوك unhydrate + +286 +00:27:25,810 --> 00:27:33,950 +بدي الكربونات تلاتة هذه واحدة منهمهذه واحدة و لذلك + +287 +00:27:33,950 --> 00:27:38,310 +لما كان عند ال E ثانوك كنت بس حاطط ال CH3 المجموع + +288 +00:27:38,310 --> 00:27:45,430 +تنتين لما بدل بربانوك بدأ اكتب CH2 CH3 المجموع + +289 +00:27:45,430 --> 00:27:54,830 +تلاتة و هنا CH2 CH3 واضح فالمجموع تلاتة بربانوك و + +290 +00:27:54,830 --> 00:28:01,830 +مثلها بيوتانوك واضحةطيب الآن يا تورا الكلام شوفوا + +291 +00:28:01,830 --> 00:28:08,370 +كيف ما أسهل الكيميا ولا أمتعها بتفهم لحالها لو + +292 +00:28:08,370 --> 00:28:19,610 +إجيت و روحت كتبتلكم هنا CH3 و كتبتلكم هنا فنل و + +293 +00:28:19,610 --> 00:28:21,810 +قلتلكوا سموا هذا المركب + +294 +00:28:27,020 --> 00:28:34,240 +هذا مكون من كام حامض؟ هذا الحامض شو هو؟ + +295 +00:28:42,280 --> 00:28:47,600 +جيد جيد هذا التردد .. هذا التردد بحل مشكلتك الناس + +296 +00:28:47,600 --> 00:28:50,380 +اللي سألوني عن الامتحان لأ في الامتحان مش عامليني + +297 +00:28:50,380 --> 00:28:55,120 +كويس لإن مصيرين ما تسمعوش نصيحتي إن إذا في الكيميا + +298 +00:28:55,120 --> 00:29:00,400 +ما طبقتوش و ما كتبتوش الجملة ألف مرة لن تتعلموا + +299 +00:29:00,400 --> 00:29:05,340 +كيميا تمام؟ لن تتعلموا كيميا هذا اللي فيه تنتين + +300 +00:29:05,340 --> 00:29:12,810 +اثانوك و بال common أسيتكمظبوط ولا لأ؟ هذا كحمد + +301 +00:29:12,810 --> 00:29:19,010 +CH3C double bond O إيش ماله؟ Acetic و هذا الفنل C + +302 +00:29:19,010 --> 00:29:23,430 +double bond O بنزوك و خلّيني أحطهم alphabetical + +303 +00:29:23,430 --> 00:29:28,190 +مين بيجي قبل ال Acetic ولا ال بنزوك؟ Acetic بنزوك + +304 +00:29:28,190 --> 00:29:29,850 +Unhydrate + +305 +00:29:31,620 --> 00:29:35,840 +واضح؟ بذكر اسم الحامضين و بحطه ممرتبين + +306 +00:29:35,840 --> 00:29:40,520 +alphabetically فبكون هيك اقدرت اسمي ال + +307 +00:29:40,520 --> 00:29:47,620 +unsymmetrical .. unhydrite .. واضح؟أسيتك بنزوك + +308 +00:29:47,620 --> 00:29:51,080 +أنهايدرايد طبعا واحدة ممكن تقول ممكن نسميه إيثانوك + +309 +00:29:51,080 --> 00:29:56,060 +ممكن موادة كاربون تنتيل إيثانوك و أجي تبدأ تكتب + +310 +00:29:56,060 --> 00:30:01,740 +بنزوك إيثانوك أنهايدرايد عشان تحط ال B قبل ال E + +311 +00:30:01,740 --> 00:30:06,920 +alphabeticalإذا إعرفنا كيف بنسمي الـ unsymmetrical + +312 +00:30:06,920 --> 00:30:12,680 +anhydride بذكر الحامضين alphabetically وإضافة + +313 +00:30:12,680 --> 00:30:18,860 +النهاية anhydride الآن إذا هذا الكلام إعرفنا كيف + +314 +00:30:18,860 --> 00:30:26,860 +نسميه، ضال كيف؟ انحضروه، ضال كيف انحضروه اللي + +315 +00:30:26,860 --> 00:30:34,400 +فاهمين الethers، إيش كنا نعمل فيهم؟نفس الفكرة + +316 +00:30:34,400 --> 00:30:39,520 +تماما اللي اتذكره William Sun William Sun's + +317 +00:30:39,520 --> 00:30:44,320 +synthesis of ethers هل يا تورا كنت بقدر انا اجي + +318 +00:30:44,320 --> 00:30:55,280 +اقول Methanol زائد Ethanol بالحرارة و الحامض هذا + +319 +00:30:55,280 --> 00:31:01,790 +كام مركب كام Ether كان يعطيليكان يعطيني تلاتة مثل + +320 +00:31:01,790 --> 00:31:11,130 +او مثل او اثل او اثل او مثل او اثل طب هتقول هذا ال + +321 +00:31:11,130 --> 00:31:16,610 +synthesis مقبول ولا لأ مرفوض في ال ethers مرفوض + +322 +00:31:16,610 --> 00:31:19,650 +لان انا بدي اطلع تلاتة و اقعد افصلهم طب كيف كنا + +323 +00:31:19,650 --> 00:31:24,810 +نعمل كنا نقول خلي واحد منهم يصير مثل او minus + +324 +00:31:24,810 --> 00:31:33,920 +التاني يصير اثل CLCH3 CH2 CL نبدل ال OH بCL مثلا + +325 +00:31:33,920 --> 00:31:39,000 +من PCL3 و بعدين نفعل هدول التنين مع بعض كانوا + +326 +00:31:39,000 --> 00:31:45,980 +بيعطوني بس المثل O Ethan واضح؟ + +327 +00:31:45,980 --> 00:31:52,720 +واحد نخليه O minus والتاني نخليه CL و نخلطهم هيك + +328 +00:31:52,720 --> 00:32:00,300 +بيعطيني فقطناتج واحد لا غير بضحك الفكرة؟ هذه إيش + +329 +00:32:00,300 --> 00:32:06,500 +كان اسمها؟ طريقة William Sun لتحضير ال ether الآن + +330 +00:32:06,500 --> 00:32:13,220 +لما بدي أحضر ال un-symmetrical unhydride نفسها + +331 +00:32:13,220 --> 00:32:19,520 +تماما 100% لكن بدل ما أنا مبتدئ بكحول في ال + +332 +00:32:19,520 --> 00:32:25,140 +unhydride بدي أبتدئ من إيش؟من الـ Acid خلّيني أقول + +333 +00:32:25,140 --> 00:32:29,460 +بدي مثلا الـ Acetic Benzoic Anhydrate إذا إيش + +334 +00:32:29,460 --> 00:32:37,300 +الحامضين اللي بدي أبتدأ منهم Acetic Acid هاي CH3C + +335 +00:32:37,300 --> 00:32:44,280 +double bond O OH زائد Benzoic Acid Phenyl C double + +336 +00:32:44,280 --> 00:32:53,200 +bond O OH الآن لو خلطناهم بـ H Plus و Heatكم ناتج + +337 +00:32:53,200 --> 00:32:58,880 +الـ three products بنفع هذا الكلام مقبول اللي بعمل + +338 +00:32:58,880 --> 00:33:03,060 +زي هيك ايش بيكون بيشتغل غلط ال three products + +339 +00:33:03,060 --> 00:33:07,580 +موازية تماما لفكرة ال ethers الان واحد منهم بدنا + +340 +00:33:07,580 --> 00:33:11,220 +نخلي O minus نفترض هذا + +341 +00:33:13,840 --> 00:33:19,860 +CH3C double bond O O minus والتاني بدنا نخلي CL + +342 +00:33:19,860 --> 00:33:26,220 +فنل C double bond O CL هدولة لما نخلطهم بده يطلع + +343 +00:33:26,220 --> 00:33:33,700 +عندنا ناتج واحد فقط نرسمها CH3C double bond O O C + +344 +00:33:33,700 --> 00:33:41,680 +double bond O فنل على أساس أن هذه بتهاجمها و بتطرد + +345 +00:33:42,840 --> 00:33:48,240 +الـ Cl واضح؟ طبعا ممكن حد يقول كيف هذا بنحول ال + +346 +00:33:48,240 --> 00:33:54,840 +acid ال acid ل O minus بالتفاعل مع N A O H حمزاد + +347 +00:33:54,840 --> 00:33:55,680 +قاعدة + +348 +00:33:59,270 --> 00:34:03,890 +NA قدش كتير عليه دائما مستعمل أقل شغلة مع ال NA + +349 +00:34:03,890 --> 00:34:08,170 +هياعمل حريقة هيكون التفاعل violent مع ال NA و لا + +350 +00:34:08,170 --> 00:34:14,470 +مع ال NA او ال NA قدش كتير عليه هيعمل حريقةمع ال N + +351 +00:34:14,470 --> 00:34:17,470 +A و N A H ماشي الحمض يتفاعل مع ال N A و N A H + +352 +00:34:17,470 --> 00:34:21,570 +الكحول هداج زنبه ع جنبه مكانش يتفاعل مع ال N A و N + +353 +00:34:21,570 --> 00:34:26,970 +A H ولذلك استعملتله N A و N A H لكن الحمض بتفاعل + +354 +00:34:26,970 --> 00:34:31,670 +مع ال N A و N A H ولا لأ بتفاعل و هذا بي سي ال + +355 +00:34:31,670 --> 00:34:37,050 +اثنين اذا حامض طبعا واحدة ممكن تسأل انواع نخلي O + +356 +00:34:37,050 --> 00:34:42,970 +minus وانواع C L مش فارقفى ال ethers كان فارق ال + +357 +00:34:42,970 --> 00:34:48,330 +CL بنا نخليه ال primary هنا مش فارق واحد بخليه O + +358 +00:34:48,330 --> 00:34:55,210 +minus والتانى بخليه CL و بعدين بفعلهم هيطلع عندى + +359 +00:34:55,210 --> 00:35:01,650 +ال unsymmetrical anhydride + +360 +00:35:01,650 --> 00:35:10,810 +واضحة الفكرةوهي طريقة تحضير الـ Acidic Benzoic + +361 +00:35:10,810 --> 00:35:16,290 +Anhydride فيه أوضح من هيك؟ مرة جيبناها سؤال هذا + +362 +00:35:16,290 --> 00:35:20,230 +المركب، قولنا للطلاب سمي المركب التالي واذكر طريقة + +363 +00:35:20,230 --> 00:35:27,250 +تحضيره، ما جوابوش عشرة في المية، بتصدقوا؟ ليش؟لأنه + +364 +00:35:27,250 --> 00:35:31,370 +مابيطبقوش مابيعدوش الكتابة خمس مرات لحد ما إيدهم + +365 +00:35:31,370 --> 00:35:36,830 +تتعود على الكيميا ولذلك لو بدكوا تطلعوا على سبيل + +366 +00:35:36,830 --> 00:35:42,270 +المثال هذا الكلام جيد إنه الكل يسمعوا حتى الناس + +367 +00:35:42,270 --> 00:35:46,470 +اللي بيشاهدوا الفيديو الطالب اللي مابيكتب كيميا + +368 +00:35:46,470 --> 00:35:53,090 +كتيرما بيكتب كيميا كتير هذا فن بحاجة إلى تدريب + +369 +00:35:53,090 --> 00:36:00,310 +ولذلك قد تستغربوا انه لما جيبنالكم بنزين وقلنا + +370 +00:36:00,310 --> 00:36:06,890 +حطوا عليها بس مجموعة إثل زي هيك يعني كتبنا CH3 + +371 +00:36:06,890 --> 00:36:15,070 +CH2Cl في وجود الـFeCl3 تمام؟ + +372 +00:36:16,720 --> 00:36:24,060 +الآن بنسبة 70% منكم عندهم فهم ولكن عندهم خطأ في + +373 +00:36:24,060 --> 00:36:28,300 +التنفيذ لأنهم مادربوش إيديهم يكتبوا كان الجواب + +374 +00:36:28,300 --> 00:36:40,280 +اللي كتب بهذا الشكل الان + +375 +00:36:40,280 --> 00:36:44,720 +انتوا بتحكوا لكن انا عندى إحصائيةأنا بعمل إحصائية + +376 +00:36:44,720 --> 00:36:49,560 +كيف بتكتبوا، 70% منكم كتبوا بهذا الشكل، لا هذه ال + +377 +00:36:49,560 --> 00:36:53,780 +carbon أربع روابط ولا هذه أربع روابط ولا محل مكانة + +378 +00:36:53,780 --> 00:36:59,280 +ال CL عملوا التفاعل كل هذه الأشياء ليش؟ لأنه مافيش + +379 +00:36:59,280 --> 00:37:05,900 +تطبيق، الأصل أنه هنا نكون كاتبين CH2 CH3 + +380 +00:37:07,280 --> 00:37:14,480 +الان لما جيبنالكم فاعله مع CH3CWOCL الاصل بدكوا + +381 +00:37:14,480 --> 00:37:23,960 +تحطه من هنا من محل ال CL يعني تحطه CWOCL + +382 +00:37:23,960 --> 00:37:31,560 +ربما خمسين في المية منكم حطوا هنا CWO وحطوا هنا + +383 +00:37:31,560 --> 00:37:40,360 +CH3 بهذا الشكل بهذا الشكللا تحزروا روسكو و إلا + +384 +00:37:40,360 --> 00:37:44,380 +بجيب الورق و بفرجيكوا إياه ليش؟ لأنه ماصارش عندكم + +385 +00:37:44,380 --> 00:37:49,140 +تطبيق اللي بيدخل على كلية علمية جامعية بده يتعب و + +386 +00:37:49,140 --> 00:37:54,980 +هو بيطبق و يكتب كتير و يتعب كتير عشان يشتغل صح لكن + +387 +00:37:54,980 --> 00:37:59,020 +هذا الكلام خمسين في المية يمكن كتبوه من الطالبات و + +388 +00:37:59,020 --> 00:38:02,440 +هذا الكلام اللي كان تول سبعين في المية من الطالبات + +389 +00:38:02,440 --> 00:38:07,760 +كتبوه ليش؟ لأنهم بدهم يقرؤوا ال organic قراءة + +390 +00:38:08,820 --> 00:38:14,640 +أدبيات الرافعي الرافعي يقرأ استلقاء و ال organic + +391 +00:38:14,640 --> 00:38:28,580 +تقرأ كتابة و تطبيقا واضحة الفكرة هاي + +392 +00:38:28,580 --> 00:38:36,210 +ال acid anhydride الان لاحظوا من الأحماضاللي + +393 +00:38:36,210 --> 00:38:42,090 +درسناها ال die acids يعني يكون عندى حامضين في نفس + +394 +00:38:42,090 --> 00:38:49,250 +الجزء أخدنا لما يكون عندى أربع ذرات كربون الحامض + +395 +00:38:49,250 --> 00:38:53,750 +اللى بيكون بال sis form اسمه malic acid و اللى بال + +396 +00:38:53,750 --> 00:39:01,690 +transform يهودا ايوة اللى بال transform زى هذا شو + +397 +00:39:01,690 --> 00:39:02,450 +اسمه؟ + +398 +00:39:15,400 --> 00:39:21,740 +لاحظوا أفضل واحدة فيكم برضه نتيجة عدم التطبيق جابت + +399 +00:39:21,740 --> 00:39:26,200 +زرع من الإسم وأكيد لو كانت متحة هيكون خطأ جالت + +400 +00:39:26,200 --> 00:39:31,680 +فورمك لكن تأكيدا والمحاضرات ابتشرت عليكم اسمه + +401 +00:39:31,680 --> 00:39:39,850 +fumaric acidmalic acid و fumaric acid شوفتوا كيف + +402 +00:39:39,850 --> 00:39:44,830 +التطبيق بيفرق عندنا أكيد لو ارجعنا أول ما أخدنا ال + +403 +00:39:44,830 --> 00:39:49,130 +die acids حكيناهم و قولنا واحد بناخده من التفاح و + +404 +00:39:49,130 --> 00:39:54,650 +التاني من الأغنام و كل هذا الكلام لكن كم مرة كتبت + +405 +00:39:54,650 --> 00:39:58,990 +أنا شكل ال malic acid و ال fumaric acid ولا مرة + +406 +00:39:58,990 --> 00:40:05,280 +كيف بدي أتذكرهممش هتذكرهم الان لاحظوا معي المالية + +407 +00:40:05,280 --> 00:40:12,040 +كان SIS الفيومارك كانت Trans يعني كان في مجمعتين + +408 +00:40:12,040 --> 00:40:18,810 +ال OHSمجمعتين ال acid بعاد عن بعض الان هذا مركب ال + +409 +00:40:18,810 --> 00:40:24,370 +cess لو سخنته انا عند 135 حامض بتفعلها حامض هذه + +410 +00:40:24,370 --> 00:40:29,210 +بتيجي هان و بتطرد ال OH بتعطيني unhydrate لما بدي + +411 +00:40:29,210 --> 00:40:34,930 +اسميه شو هسميه مليك unhydrate مليك قولنا كمان و + +412 +00:40:34,930 --> 00:40:38,410 +أكدنا انه بنستعمل ال E اللي هي تعبير على ال alkyl + +413 +00:40:38,410 --> 00:40:45,220 +وقولنا الملكحمض تاني بدون ال E حامض تاني ملك acid + +414 +00:40:45,220 --> 00:40:52,660 +موجود ومليك acid موجود واضح؟ الان لو اجت واحدة + +415 +00:40:52,660 --> 00:40:59,880 +سخنت هذا الحامض بالحرارة ايش رأيكوا هيصير؟ هيعمل + +416 +00:40:59,880 --> 00:41:04,540 +unhydrate مع نفسه؟ + +417 +00:41:04,540 --> 00:41:09,720 +يعني هذه تهاجم هنا؟ ليش؟ + +418 +00:41:10,730 --> 00:41:16,310 +لأن هم بعاد .. لأن هم بعاد .. طيب بتقولون ما بتلف + +419 +00:41:16,310 --> 00:41:21,030 +حوالين ال double bond .. الدوران حوالين ال double + +420 +00:41:21,030 --> 00:41:28,300 +bond .. ممنوع .. ولذلك تسخين الماليك أسدبيعمل + +421 +00:41:28,300 --> 00:41:33,920 +unhydrate تسخين لثيوميرك أسد بيعملش unhydrate فلو + +422 +00:41:33,920 --> 00:41:37,920 +انتوا اتطلعتوا في كاتالوجي الكيميا بتلاقوا مركب + +423 +00:41:37,920 --> 00:41:42,580 +اسمه مليك unhydrate بس بتلاقوش مركب اسمه ثيوميرك + +424 +00:41:42,580 --> 00:41:49,100 +unhydrate لأن مجمعتين ال OHS ابعاد عن بعضهم البعض + +425 +00:41:49,100 --> 00:41:54,890 +واضح فمش هيصل يتفاعلوا مع بعضهم البعضالان نفس + +426 +00:41:54,890 --> 00:42:01,430 +الفكرة تماما لو اجيت على مجموعتين acid موجودات على + +427 +00:42:01,430 --> 00:42:09,450 +بنزينة قولت هدول المجموعتين كيف يمكن ان يوجدوا يا + +428 +00:42:09,450 --> 00:42:16,170 +اما واحد اتنين اورثو يا واحد تلاتة ميتا يا واحد + +429 +00:42:16,170 --> 00:42:21,520 +اربعة باراتمام يعني غير هذا اللي موجود المجموعتين + +430 +00:42:21,520 --> 00:42:26,580 +على واحد اتنين ايضا موجود انه يكونوا مجموعتين ال + +431 +00:42:26,580 --> 00:42:34,900 +acid COOH و COOH على نمرة واحد واحد اتنين تلاتة + +432 +00:42:34,900 --> 00:42:40,860 +وموجود كمان انهم يكونوا على نمرة واحد واربعة COOH + +433 +00:42:40,860 --> 00:42:48,750 +مثلا و COOH واحد اتنين تلاتة اربعةهدولة التلت + +434 +00:42:48,750 --> 00:42:54,170 +أحماض موجودين و سمناهم اللي على ال Ortho سمناه + +435 +00:42:54,170 --> 00:43:00,950 +Phthalic Acid و اللي على ال NETA Isophthalic Acid + +436 +00:43:00,950 --> 00:43:05,910 +و اللي على البارا Terephthalic Acid و قولنالكوا + +437 +00:43:05,910 --> 00:43:11,010 +احفظوهم الآن لو يا ترى إجينا نسخن هدولة التلاتة + +438 +00:43:11,010 --> 00:43:17,070 +مين فكركوا منهم اللي ممكن يعمل Unhydrate؟الأورثو + +439 +00:43:17,070 --> 00:43:22,990 +ولا النيتا ولا البارا بس الأورثو لأن هدول بعاد عن + +440 +00:43:22,990 --> 00:43:29,090 +بعض مابيجوش فهذا بيعملش أنهيدريد ال isothelic acid + +441 +00:43:29,090 --> 00:43:33,010 +و ال teraphthalic acid بيعملش أنهيدريد هذا بيعمل + +442 +00:43:33,010 --> 00:43:39,150 +أنهيدريد لو قلنالكوا أرسم الانهيدريد الناتجهي + +443 +00:43:39,150 --> 00:43:45,690 +البنزينة عندى C double bond O و هنا C double bond + +444 +00:43:45,690 --> 00:43:52,570 +O و بينهم O هى مجموعة الانهيدريد C double bond O O + +445 +00:43:52,570 --> 00:43:58,850 +C double bond O و هذا بيصير ايش اسمه افثالك + +446 +00:43:58,850 --> 00:44:01,810 +انهيدريد + +447 +00:44:04,120 --> 00:44:12,560 +أفثالك أنهايدرايد واضح طبعا + +448 +00:44:12,560 --> 00:44:16,960 +هذه ال mix انهايدرايد حكينا عنها كيف بتتحضر واحد O + +449 +00:44:16,960 --> 00:44:20,520 +minus والتاني CL وهي تسميتهم acidic benzoic + +450 +00:44:20,520 --> 00:44:22,060 +anhydride حكينا عنه + +451 +00:44:29,520 --> 00:44:36,740 +طبعا لو كنا بدنا ندرس تفاعلات الانهيدريد واحدة + +452 +00:44:36,740 --> 00:44:40,340 +تختصر تفاعلات الانهيدريد بكلمة شو هتقول عنهم + +453 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{"start": 518.99, "end": 519.29, "word": " نمرة", "probability": 0.6041666666666666}, {"start": 519.29, "end": 519.63, "word": " اتنين", "probability": 0.84521484375}, {"start": 519.63, "end": 519.97, "word": " يمكن", "probability": 0.9794921875}, {"start": 519.97, "end": 520.15, "word": " أن", "probability": 0.8759765625}, {"start": 520.15, "end": 520.61, "word": " تنشأ", "probability": 0.9906005859375}, {"start": 520.61, "end": 520.95, "word": " عن", "probability": 0.9951171875}, {"start": 520.95, "end": 521.89, "word": " ال", "probability": 0.97021484375}, {"start": 521.89, "end": 522.33, "word": " rotation", "probability": 0.984375}, {"start": 522.33, "end": 523.15, "word": " الدوران", "probability": 0.8660481770833334}], "temperature": 1.0}, {"id": 22, "seek": 52779, "start": 524.27, "end": 527.79, "text": "فيكون المُركّب مُركّب واحد", "tokens": [41185, 30544, 9673, 10859, 31747, 11703, 3555, 3714, 10859, 31747, 11703, 3555, 36764, 24401], "avg_logprob": -0.21575520237286885, 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"probability": 0.88232421875}, {"start": 707.15, "end": 707.89, "word": " كربونات", "probability": 0.8625}, {"start": 707.89, "end": 708.61, "word": " متتالية", "probability": 0.9776611328125}, {"start": 708.61, "end": 708.91, "word": " لكن", "probability": 0.88037109375}, {"start": 708.91, "end": 709.65, "word": " كلها", "probability": 0.808349609375}, {"start": 709.65, "end": 710.07, "word": " روابط", "probability": 0.9627685546875}, {"start": 710.07, "end": 710.63, "word": " أحدية", "probability": 0.8512369791666666}, {"start": 710.63, "end": 711.43, "word": " والجزء", "probability": 0.86114501953125}, {"start": 711.43, "end": 711.61, "word": " في", "probability": 0.97119140625}, {"start": 711.61, "end": 712.45, "word": " رابطة", "probability": 0.9139404296875}, {"start": 712.45, "end": 714.31, "word": " ثنائية", "probability": 0.986083984375}], "temperature": 1.0}, {"id": 31, "seek": 73815, "start": 715.99, "end": 738.15, "text": "يجب أن تحتوي أطول سلسلة على رابطة ثنائية ممكن أعطيكم مثال حتى التطبيق يكون واضح ممكن نعطي مثال يعني لو أعطينا فقط نرسم ذرات ال carbon وحاطينا carbon 2 ثلاثة carbon 2 ثلاثة", "tokens": [1829, 7435, 3555, 14739, 6055, 33753, 45865, 5551, 9566, 12610, 8608, 1211, 3794, 37977, 15844, 12602, 16758, 9566, 3660, 38637, 1863, 16373, 10632, 3714, 43020, 5551, 3615, 9566, 1829, 24793, 50113, 6027, 11331, 49975, 16712, 9566, 21292, 4587, 7251, 30544, 4032, 46958, 5016, 3714, 43020, 8717, 3615, 9566, 1829, 50113, 6027, 37495, 22653, 45164, 5551, 3615, 9566, 1829, 8315, 6156, 47432, 8717, 2288, 38251, 29910, 2288, 9307, 2423, 5954, 4032, 5016, 41193, 1829, 8315, 5954, 568, 38637, 1211, 5718, 104, 3660, 5954, 568, 38637, 1211, 5718, 104, 3660], "avg_logprob": -0.13948384697517652, "compression_ratio": 1.695906432748538, "no_speech_prob": 0.0, "words": [{"start": 715.99, "end": 716.59, "word": "يجب", "probability": 0.91064453125}, {"start": 716.59, "end": 716.83, "word": " أن", "probability": 0.55810546875}, {"start": 716.83, "end": 717.43, 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"word": " و", "probability": 0.619140625}, {"start": 1173.81, "end": 1174.03, "word": " هذه", "probability": 0.50439453125}, {"start": 1174.03, "end": 1174.19, "word": " لو", "probability": 0.994140625}, {"start": 1174.19, "end": 1174.73, "word": " كملناها", "probability": 0.973388671875}, {"start": 1174.73, "end": 1175.09, "word": " كمان", "probability": 0.9225260416666666}, {"start": 1175.09, "end": 1175.71, "word": " مثل", "probability": 0.98974609375}, {"start": 1175.71, "end": 1177.65, "word": " CH3", "probability": 0.880126953125}], "temperature": 1.0}, {"id": 51, "seek": 120468, "start": 1178.9, "end": 1204.68, "text": "فالاسم الصحيح لهذا المركب شو هيكون؟ two two three اتراي مثل بنتين واضح؟ فما تفكروا نهائيا بمجموعات قبل ما تحددوا أطول سلسلة و اتعلموها ما زاد عن أطول سلسلة شوفوا إيش اسمه فكيف تبدأ التسمية؟", "tokens": [5172, 6027, 32277, 2304, 31767, 5016, 1829, 5016, 46740, 15730, 9673, 31747, 3555, 13412, 2407, 39896, 30544, 22807, 732, 732, 1045, 1975, 2655, 23557, 1829, 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"end": 1200.06, "word": " سلسلة", "probability": 0.9940185546875}, {"start": 1200.06, "end": 1200.6, "word": " شوفوا", "probability": 0.9080403645833334}, {"start": 1200.6, "end": 1200.8, "word": " إيش", "probability": 0.8470052083333334}, {"start": 1200.8, "end": 1201.72, "word": " اسمه", "probability": 0.9140625}, {"start": 1201.72, "end": 1203.22, "word": " فكيف", "probability": 0.9332682291666666}, {"start": 1203.22, "end": 1203.7, "word": " تبدأ", "probability": 0.9876302083333334}, {"start": 1203.7, "end": 1204.68, "word": " التسمية؟", "probability": 0.9691162109375}], "temperature": 1.0}, {"id": 52, "seek": 121688, "start": 1205.6, "end": 1216.88, "text": "بأطول سلسلة مش أشوف أن هذه مجموعة و هذه مجموعة و التنتين موجودات كجزء من أطول سلسلة واضحة الفكرة؟", "tokens": [3555, 10721, 9566, 12610, 8608, 1211, 3794, 37977, 37893, 5551, 8592, 38688, 14739, 29538, 3714, 7435, 2304, 2407, 27884, 4032, 29538, 3714, 7435, 2304, 2407, 27884, 4032, 16712, 29399, 9957, 3714, 29245, 23328, 9307, 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{"start": 1208.74, "end": 1209.36, "word": " مجموعة", "probability": 0.9619140625}, {"start": 1209.36, "end": 1209.7, "word": " و", "probability": 0.61181640625}, {"start": 1209.7, "end": 1210.32, "word": " التنتين", "probability": 0.90673828125}, {"start": 1210.32, "end": 1211.24, "word": " موجودات", "probability": 0.942626953125}, {"start": 1211.24, "end": 1213.48, "word": " كجزء", "probability": 0.97265625}, {"start": 1213.48, "end": 1213.68, "word": " من", "probability": 0.99462890625}, {"start": 1213.68, "end": 1214.14, "word": " أطول", "probability": 0.9879557291666666}, {"start": 1214.14, "end": 1215.0, "word": " سلسلة", "probability": 0.993408203125}, {"start": 1215.0, "end": 1216.22, "word": " واضحة", "probability": 0.78662109375}, {"start": 1216.22, "end": 1216.88, "word": " الفكرة؟", "probability": 0.94091796875}], "temperature": 1.0}, {"id": 53, "seek": 125941, "start": 1236.77, "end": 1259.41, "text": "وعشان هيك لا بأس ان اعطيكم مسألة تانية تفكروا فيها تعملوها homework على هذا الموضوع تحديدا مسألة جميلة جدا", "tokens": [45367, 8592, 7649, 39896, 4117, 20193, 4724, 10721, 3794, 16472, 1975, 3615, 9566, 1829, 24793, 47524, 10721, 37977, 6055, 7649, 10632, 6055, 5172, 37983, 14407, 8978, 11296, 6055, 25957, 1211, 2407, 11296, 14578, 15844, 23758, 9673, 2407, 11242, 45367, 6055, 5016, 16254, 28259, 47524, 10721, 37977, 10874, 2304, 26895, 3660, 10874, 28259], "avg_logprob": -0.10333136736222033, "compression_ratio": 1.4090909090909092, "no_speech_prob": 0.0, "words": [{"start": 1236.77, "end": 1237.33, "word": "وعشان", "probability": 0.8126627604166666}, {"start": 1237.33, "end": 1237.99, "word": " هيك", "probability": 0.982666015625}, {"start": 1237.99, "end": 1238.27, "word": " لا", "probability": 0.6318359375}, {"start": 1238.27, "end": 1238.81, "word": " بأس", "probability": 0.9664713541666666}, {"start": 1238.81, "end": 1239.05, "word": " ان", "probability": 0.4375}, {"start": 1239.05, "end": 1239.93, "word": " اعطيكم", "probability": 0.97041015625}, 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بقول فينل في حرف ال V هذه فينل فلو حملت ال chlorine بتصير vinyl chloride ليش رفضنا؟", "tokens": [28814, 11622, 42213, 2655, 4117, 14407, 4724, 43042, 3224, 8608, 2304, 34268, 22653, 9122, 19528, 3660, 37893, 3714, 19913, 3555, 2407, 9566, 3660, 10874, 6027, 2655, 8978, 1863, 1211, 41850, 4724, 39648, 8978, 1863, 1211, 8978, 11331, 28480, 2423, 691, 29538, 8978, 1863, 1211, 6156, 1211, 2407, 11331, 42213, 2655, 2423, 39888, 39894, 9381, 13546, 25226, 35434, 32239, 8592, 12602, 5172, 11242, 8315, 22807], "avg_logprob": -0.28076923076923077, "compression_ratio": 1.4038461538461537, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1359.08, "end": 1359.94, "word": "إزملتكوا", "probability": 0.6207682291666666}, {"start": 1359.94, "end": 1360.26, "word": " برضه", "probability": 0.9493815104166666}, {"start": 1360.26, "end": 1360.96, "word": " سمعتني", "probability": 0.814697265625}, {"start": 1360.96, "end": 1361.34, "word": " كلمة", "probability": 0.904296875}, {"start": 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كلور محل الهيدروجينة هنا تحديدا محل منحفة ال H على CH صار اسم المركب ألل كلورايد", "tokens": [5462, 37037, 8315, 5995, 17, 10874, 40294, 11622, 3660, 14739, 6055, 2655, 5172, 995, 30241, 20449, 44049, 38207, 6055, 7649, 1829, 10874, 40294, 11622, 3660, 6055, 2655, 5172, 995, 30241, 20449, 44049, 38207, 6055, 7649, 1829, 29538, 9673, 7435, 2304, 2407, 27884, 44945, 38251, 1829, 11296, 5551, 1211, 1211, 11933, 1829, 8592, 44945, 38251, 1829, 11296, 22807, 5551, 1211, 1211, 6156, 1211, 2407, 11331, 9566, 36081, 1829, 28242, 13063, 3714, 5016, 1211, 2423, 3224, 25708, 2288, 29245, 9957, 3660, 34105, 6055, 5016, 16254, 28259, 3714, 5016, 1211, 9154, 5016, 5172, 3660, 2423, 389, 15844, 5995, 20328, 9640, 24525, 2304, 9673, 31747, 3555, 5551, 1211, 1211, 9122, 1211, 13063, 995, 25708], "avg_logprob": -0.24169481820888347, "compression_ratio": 1.8709677419354838, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1573.73, "end": 1574.23, "word": "CH", "probability": 0.36181640625}, 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هيكون عنده من أربع ذرّات كربون أنا هنا ماسك التلاتة ممكن واحدة تقول بسيطة حطوا هنا الكربون هنا", "tokens": [5172, 37983, 14407, 20449, 1863, 7578, 5551, 9957, 3714, 43020, 8717, 5016, 9566, 33251, 25513, 11536, 33688, 11242, 31845, 10632, 4724, 2304, 3615, 1863, 7578, 9122, 2304, 3714, 31747, 11703, 3555, 2423, 39184, 42, 2030, 8032, 1829, 30544, 43242, 3224, 9154, 5551, 25513, 3615, 29910, 2288, 11703, 9307, 9122, 25513, 11536, 41850, 34105, 19446, 3794, 4117, 16712, 1211, 9307, 3660, 3714, 43020, 36764, 24401, 3660, 6055, 39648, 4724, 3794, 1829, 9566, 3660, 11331, 9566, 14407, 34105, 33251, 25513, 11536, 34105], "avg_logprob": -0.2824073956336504, "compression_ratio": 1.7048192771084338, "no_speech_prob": 0.0, "words": [{"start": 1834.53, "end": 1835.15, "word": "فكروا", "probability": 0.8717447916666666}, {"start": 1835.15, "end": 1835.57, "word": " معنى", "probability": 0.7037760416666666}, {"start": 1835.57, "end": 1835.73, "word": " أين", "probability": 0.64404296875}, {"start": 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2007.76, "end": 2009.1, "word": " والترانس", "probability": 0.710888671875}, {"start": 2009.1, "end": 2010.2, "word": " الان", "probability": 0.52593994140625}, {"start": 2010.2, "end": 2011.42, "word": " لسه", "probability": 0.9248046875}, {"start": 2011.42, "end": 2012.24, "word": " ما", "probability": 0.63134765625}, {"start": 2012.24, "end": 2013.14, "word": " خلصناش", "probability": 0.8435546875}, {"start": 2013.14, "end": 2013.54, "word": " نشوف", "probability": 0.98486328125}, {"start": 2013.54, "end": 2013.86, "word": " كل", "probability": 0.95947265625}, {"start": 2013.86, "end": 2014.88, "word": " المُركّبات", "probability": 0.97802734375}, {"start": 2014.88, "end": 2015.92, "word": " الان", "probability": 0.834228515625}, {"start": 2015.92, "end": 2016.66, "word": " لاحظوا", "probability": 0.98291015625}, {"start": 2016.66, "end": 2017.1, "word": " معناه", "probability": 0.8009440104166666}, {"start": 2017.1, "end": 2017.3, "word": " ايش", "probability": 0.6263834635416666}, {"start": 2017.3, "end": 2017.46, "word": " اللي", "probability": 0.940673828125}, {"start": 2017.46, "end": 2017.86, "word": " عملنا", "probability": 0.9744466145833334}, {"start": 2017.86, "end": 2018.2, "word": " احنا", "probability": 0.9772135416666666}, {"start": 2018.2, "end": 2018.96, "word": " تحديدا", "probability": 0.86376953125}, {"start": 2018.96, "end": 2019.64, "word": " لما", "probability": 0.7724609375}, {"start": 2019.64, "end": 2020.14, "word": " شوفنا", "probability": 0.9309895833333334}, {"start": 2020.14, "end": 2020.94, "word": " أنواع", "probability": 0.8662109375}, {"start": 2020.94, "end": 2021.68, "word": " المُركّبات", "probability": 0.9851888020833334}, {"start": 2021.68, "end": 2021.94, "word": " قولنا", "probability": 0.7277018229166666}, {"start": 2021.94, "end": 2022.32, "word": " بنشيل", "probability": 0.91455078125}, {"start": 2022.32, "end": 2022.86, "word": " الهيدروجين", "probability": 0.880859375}, {"start": 2022.86, "end": 2022.98, "word": " من", "probability": 0.9833984375}, {"start": 2022.98, "end": 2023.12, "word": " هنا", "probability": 0.8818359375}, {"start": 2023.12, "end": 2023.68, "word": " وكملنا", "probability": 0.855712890625}, {"start": 2023.68, "end": 2023.98, "word": " طلع", "probability": 0.8544921875}, {"start": 2023.98, "end": 2024.22, "word": " وانا", "probability": 0.768798828125}, {"start": 2024.22, "end": 2024.76, "word": " butane", "probability": 0.77490234375}, {"start": 2024.76, "end": 2025.54, "word": " اجينا", "probability": 0.7706298828125}, {"start": 2025.54, "end": 2025.9, "word": " نشيل", "probability": 0.9861653645833334}, {"start": 2025.9, "end": 2026.36, "word": " هذه", "probability": 0.857421875}], "temperature": 1.0}, {"id": 87, "seek": 204896, "start": 2027.22, "end": 2048.96, "text": "أعملنا sis to butyl شيلنا هذه و حطينا مثل أعملنا trans to butyl طب يا تورا لو شيلنا هذه و حطينا مثل هنطلع في المركب المتفرع اتطلع على شكله بدأ يغلبني", "tokens": [10721, 25957, 1211, 8315, 26288, 281, 457, 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هذه", "probability": 0.66796875}, {"start": 2030.04, "end": 2030.14, "word": " و", "probability": 0.98681640625}, {"start": 2030.14, "end": 2030.52, "word": " حطينا", "probability": 0.81048583984375}, {"start": 2030.52, "end": 2030.98, "word": " مثل", "probability": 0.994140625}, {"start": 2030.98, "end": 2031.8, "word": " أعملنا", "probability": 0.84466552734375}, {"start": 2031.8, "end": 2032.36, "word": " trans", "probability": 0.77783203125}, {"start": 2032.36, "end": 2032.62, "word": " to", "probability": 0.95947265625}, {"start": 2032.62, "end": 2033.12, "word": " butyl", "probability": 0.960693359375}, {"start": 2033.12, "end": 2033.6, "word": " طب", "probability": 0.73291015625}, {"start": 2033.6, "end": 2033.74, "word": " يا", "probability": 0.90966796875}, {"start": 2033.74, "end": 2034.0, "word": " تورا", "probability": 0.6666666666666666}, {"start": 2034.0, "end": 2034.2, "word": " لو", "probability": 0.97412109375}, {"start": 2034.2, "end": 2034.66, "word": " شيلنا", "probability": 0.85693359375}, {"start": 2034.66, "end": 2035.04, "word": " هذه", "probability": 0.88671875}, {"start": 2035.04, "end": 2035.18, "word": " و", "probability": 0.99267578125}, {"start": 2035.18, "end": 2035.72, "word": " حطينا", "probability": 0.94140625}, {"start": 2035.72, "end": 2036.04, "word": " مثل", "probability": 0.98583984375}, {"start": 2036.04, "end": 2039.2, "word": " هنطلع", "probability": 0.7451904296875}, {"start": 2039.2, "end": 2039.36, "word": " في", "probability": 0.931640625}, {"start": 2039.36, "end": 2039.98, "word": " المركب", "probability": 0.9332682291666666}, {"start": 2039.98, "end": 2041.5, "word": " المتفرع", "probability": 0.97939453125}, {"start": 2041.5, "end": 2046.68, "word": " اتطلع", "probability": 0.749609375}, {"start": 2046.68, "end": 2046.92, "word": " على", "probability": 0.89599609375}, {"start": 2046.92, "end": 2047.54, "word": " شكله", "probability": 0.99072265625}, {"start": 2047.54, "end": 2048.42, "word": " بدأ", "probability": 0.682861328125}, {"start": 2048.42, "end": 2048.96, "word": " يغلبني", "probability": 0.965576171875}], "temperature": 1.0}, {"id": 88, "seek": 207567, "start": 2053.2, "end": 2075.68, "text": "الثلاثة اللي اتفرع منهم واحد واحد اتنين تلاتة اتفرع لما كان في ال ال كيرز ال double bond سمينا ايزو بيوتين هنا ايش هنسميه ايزو بيوتين ايزو بيوتين طب لو قلت لو واحد اسميه بال ايو باكنيم هايوا قدام عينيكم اطول سلسلة فيه", "tokens": [6027, 12984, 1211, 5718, 104, 3660, 13672, 1829, 1975, 2655, 5172, 2288, 3615, 9154, 16095, 36764, 24401, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 2655, 5172, 2288, 3615, 5296, 15042, 25961, 8978, 2423, 2423, 9122, 13546, 11622, 2423, 3834, 6086, 8608, 2304, 1829, 8315, 1975, 1829, 11622, 2407, 4724, 1829, 35473, 9957, 34105, 1975, 1829, 8592, 8032, 1863, 38251, 1829, 3224, 1975, 1829, 11622, 2407, 4724, 1829, 35473, 9957, 1975, 1829, 11622, 2407, 4724, 1829, 35473, 9957, 23032, 3555, 45164, 12174, 1211, 2655, 45164, 36764, 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"end": 2056.98, "word": " اتفرع", "probability": 0.98017578125}, {"start": 2056.98, "end": 2057.9, "word": " لما", "probability": 0.87939453125}, {"start": 2057.9, "end": 2058.12, "word": " كان", "probability": 0.990234375}, {"start": 2058.12, "end": 2058.28, "word": " في", "probability": 0.89697265625}, {"start": 2058.28, "end": 2058.4, "word": " ال", "probability": 0.8974609375}, {"start": 2058.4, "end": 2058.56, "word": " ال", "probability": 0.44873046875}, {"start": 2058.56, "end": 2058.92, "word": " كيرز", "probability": 0.48455810546875}, {"start": 2058.92, "end": 2059.04, "word": " ال", "probability": 0.3935546875}, {"start": 2059.04, "end": 2059.22, "word": " double", "probability": 0.47265625}, {"start": 2059.22, "end": 2059.48, "word": " bond", "probability": 0.65380859375}, {"start": 2059.48, "end": 2059.88, "word": " سمينا", "probability": 0.8243408203125}, {"start": 2059.88, "end": 2060.34, "word": " ايزو", "probability": 0.75579833984375}, {"start": 2060.34, "end": 2061.04, "word": " بيوتين", "probability": 0.88623046875}, {"start": 2061.04, "end": 2061.82, "word": " هنا", "probability": 0.386474609375}, {"start": 2061.82, "end": 2062.1, "word": " ايش", "probability": 0.8857421875}, {"start": 2062.1, "end": 2062.86, "word": " هنسميه", "probability": 0.912109375}, {"start": 2062.86, "end": 2064.02, "word": " ايزو", "probability": 0.87646484375}, {"start": 2064.02, "end": 2065.18, "word": " بيوتين", "probability": 0.9627685546875}, {"start": 2065.18, "end": 2065.86, "word": " ايزو", "probability": 0.9227294921875}, {"start": 2065.86, "end": 2066.38, "word": " بيوتين", "probability": 0.9891357421875}, {"start": 2066.38, "end": 2066.86, "word": " طب", "probability": 0.86767578125}, {"start": 2066.86, "end": 2067.04, "word": " لو", "probability": 0.9892578125}, {"start": 2067.04, "end": 2067.34, "word": " قلت", "probability": 0.6685384114583334}, {"start": 2067.34, "end": 2067.48, "word": " لو", "probability": 0.87109375}, {"start": 2067.48, "end": 2067.66, "word": " واحد", "probability": 0.6591796875}, {"start": 2067.66, "end": 2068.18, "word": " اسميه", "probability": 0.83203125}, {"start": 2068.18, "end": 2068.34, "word": " بال", "probability": 0.7568359375}, {"start": 2068.34, "end": 2068.82, "word": " ايو", "probability": 0.5703938802083334}, {"start": 2068.82, "end": 2069.64, "word": " باكنيم", "probability": 0.830322265625}, {"start": 2069.64, "end": 2071.68, "word": " هايوا", "probability": 0.5369466145833334}, {"start": 2071.68, "end": 2072.0, "word": " قدام", "probability": 0.8684895833333334}, {"start": 2072.0, "end": 2072.64, "word": " عينيكم", "probability": 0.9266357421875}, {"start": 2072.64, "end": 2074.72, "word": " اطول", "probability": 0.8465169270833334}, {"start": 2074.72, "end": 2075.3, "word": " سلسلة", "probability": 0.982177734375}, {"start": 2075.3, "end": 2075.68, "word": " فيه", "probability": 0.9814453125}], "temperature": 1.0}, {"id": 89, "seek": 210596, "start": 2077.6, "end": 2105.96, "text": "One Ibropine وعن إمرأتين يحمل مثل إذا ال isobutene اسمه two مثل و one ibropine بناء على ذلك هذه الصيغة العامة C4H8 كم ألكين منها؟ C4H8 كم ألكين؟", "tokens": [15426, 40790, 1513, 533, 4032, 3615, 1863, 11933, 29973, 10721, 2655, 9957, 7251, 35571, 1211, 50113, 1211, 11933, 15730, 2423, 307, 996, 325, 1450, 24525, 2304, 3224, 732, 50113, 1211, 4032, 472, 39073, 1513, 533, 44945, 16606, 15844, 29910, 23275, 29538, 31767, 1829, 17082, 3660, 18863, 10943, 3660, 383, 19, 39, 23, 9122, 2304, 5551, 1211, 4117, 9957, 9154, 11296, 22807, 383, 19, 39, 23, 9122, 2304, 5551, 1211, 4117, 9957, 22807], "avg_logprob": -0.29708905415992215, "compression_ratio": 1.3773584905660377, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2077.6, "end": 2078.04, "word": "One", "probability": 0.07373046875}, {"start": 2078.04, "end": 2078.86, "word": " Ibropine", "probability": 0.5654296875}, {"start": 2078.86, "end": 2081.12, "word": " وعن", "probability": 0.6410319010416666}, {"start": 2081.12, "end": 2081.62, "word": " إمرأتين", "probability": 0.71552734375}, {"start": 2081.62, "end": 2082.2, "word": " يحمل", "probability": 0.97705078125}, {"start": 2082.2, "end": 2083.5, "word": " مثل", "probability": 0.86767578125}, {"start": 2083.5, "end": 2084.3, "word": " إذا", "probability": 0.681884765625}, {"start": 2084.3, "end": 2085.14, "word": " ال", "probability": 0.544921875}, {"start": 2085.14, "end": 2086.6, "word": " isobutene", "probability": 0.72686767578125}, {"start": 2086.6, "end": 2087.28, "word": " اسمه", "probability": 0.9554036458333334}, {"start": 2087.28, "end": 2088.18, "word": " two", "probability": 0.368408203125}, {"start": 2088.18, "end": 2088.7, "word": " مثل", "probability": 0.870361328125}, {"start": 2088.7, "end": 2089.0, "word": " و", "probability": 0.493896484375}, {"start": 2089.0, "end": 2089.14, "word": " one", "probability": 0.4853515625}, {"start": 2089.14, "end": 2089.72, "word": " ibropine", "probability": 0.7479654947916666}, {"start": 2089.72, "end": 2090.7, "word": " بناء", "probability": 0.932861328125}, {"start": 2090.7, "end": 2091.02, "word": " على", "probability": 0.8544921875}, {"start": 2091.02, "end": 2091.76, "word": " ذلك", "probability": 0.9921875}, {"start": 2091.76, "end": 2092.9, "word": " هذه", "probability": 0.57958984375}, {"start": 2092.9, "end": 2093.4, "word": " الصيغة", "probability": 0.97802734375}, {"start": 2093.4, "end": 2094.04, "word": " العامة", "probability": 0.99169921875}, {"start": 2094.04, "end": 2096.56, "word": " C4H8", "probability": 0.786834716796875}, {"start": 2096.56, "end": 2098.48, "word": " كم", "probability": 0.838623046875}, {"start": 2098.48, "end": 2099.14, "word": " ألكين", "probability": 0.765869140625}, {"start": 2099.14, "end": 2100.48, "word": " منها؟", "probability": 0.7765299479166666}, {"start": 2100.48, "end": 2104.48, "word": " C4H8", "probability": 0.9195556640625}, {"start": 2104.48, "end": 2105.2, "word": " كم", "probability": 0.888427734375}, {"start": 2105.2, "end": 2105.96, "word": " ألكين؟", "probability": 0.93447265625}], "temperature": 1.0}, {"id": 90, "seek": 213164, "start": 2108.36, "end": 2131.64, "text": "عدوهم أربعة أربعة شفتهم يعني لو بدى يكون عندكوا سؤال draw all the possible alkenes that have the formula C4H8 one butane, cistobutane, trans-tobutane, isobutane إذا كام ألكين؟ أربعة الآن انتبهوا معي سؤال دقيق جدا", "tokens": [3615, 3215, 2407, 16095, 5551, 25513, 27884, 5551, 25513, 27884, 13412, 5172, 2655, 16095, 37495, 22653, 45164, 47525, 7578, 7251, 30544, 43242, 4117, 14407, 8608, 33604, 6027, 2642, 439, 264, 1944, 37688, 25973, 300, 362, 264, 8513, 383, 19, 39, 23, 472, 457, 1929, 11, 269, 468, 996, 325, 1929, 11, 1145, 12, 83, 996, 325, 1929, 11, 307, 996, 325, 1929, 11933, 15730, 9122, 10943, 5551, 1211, 4117, 9957, 22807, 5551, 25513, 27884, 6024, 48506, 16472, 2655, 3555, 3224, 14407, 20449, 1829, 8608, 33604, 6027, 11778, 38436, 4587, 10874, 28259], "avg_logprob": -0.28311821267656656, "compression_ratio": 1.400943396226415, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2108.36, "end": 2108.88, "word": "عدوهم", "probability": 0.78662109375}, {"start": 2108.88, "end": 2109.68, "word": " أربعة", "probability": 0.6930745442708334}, {"start": 2109.68, "end": 2110.26, "word": " أربعة", "probability": 0.7486165364583334}, {"start": 2110.26, "end": 2111.9, "word": " شفتهم", "probability": 0.73388671875}, {"start": 2111.9, "end": 2113.12, "word": " يعني", "probability": 0.7333984375}, {"start": 2113.12, "end": 2113.2, "word": " لو", "probability": 0.912109375}, {"start": 2113.2, "end": 2113.36, "word": " بدى", "probability": 0.5087890625}, {"start": 2113.36, "end": 2113.52, "word": " يكون", "probability": 0.943603515625}, {"start": 2113.52, "end": 2113.84, "word": " عندكوا", "probability": 0.7902018229166666}, {"start": 2113.84, "end": 2114.34, "word": " سؤال", "probability": 0.9866536458333334}, {"start": 2114.34, "end": 2114.96, "word": " draw", "probability": 0.56201171875}, {"start": 2114.96, "end": 2115.78, "word": " all", "probability": 0.92333984375}, {"start": 2115.78, "end": 2116.04, "word": " the", "probability": 0.7451171875}, {"start": 2116.04, "end": 2116.52, "word": " possible", "probability": 0.94384765625}, {"start": 2116.52, "end": 2117.28, "word": " alkenes", "probability": 0.641357421875}, {"start": 2117.28, "end": 2117.6, "word": " that", "probability": 0.92041015625}, {"start": 2117.6, "end": 2117.88, "word": " have", "probability": 0.94482421875}, {"start": 2117.88, "end": 2118.06, "word": " the", "probability": 0.65869140625}, {"start": 2118.06, "end": 2118.52, "word": " formula", "probability": 0.89306640625}, {"start": 2118.52, "end": 2119.74, "word": " C4H8", "probability": 0.93408203125}, {"start": 2119.74, "end": 2120.22, "word": " one", "probability": 0.51123046875}, {"start": 2120.22, "end": 2120.82, "word": " butane,", "probability": 0.70654296875}, {"start": 2121.22, "end": 2122.16, "word": " cistobutane,", "probability": 0.68994140625}, {"start": 2122.46, "end": 2122.82, "word": " trans", "probability": 0.36376953125}, {"start": 2122.82, "end": 2123.56, "word": "-tobutane,", "probability": 0.7286865234375}, {"start": 2124.18, "end": 2125.08, "word": " isobutane", "probability": 0.9412841796875}, {"start": 2125.08, "end": 2125.32, "word": " إذا", "probability": 0.556640625}, {"start": 2125.32, "end": 2125.6, "word": " كام", "probability": 0.727294921875}, {"start": 2125.6, "end": 2126.58, "word": " ألكين؟", "probability": 0.74921875}, {"start": 2126.58, "end": 2127.48, "word": " أربعة", "probability": 0.9640299479166666}, {"start": 2127.48, "end": 2128.52, "word": " الآن", "probability": 0.54608154296875}, {"start": 2128.52, "end": 2129.08, "word": " انتبهوا", "probability": 0.95830078125}, {"start": 2129.08, "end": 2129.94, "word": " معي", "probability": 0.929931640625}, {"start": 2129.94, "end": 2130.76, "word": " سؤال", "probability": 0.9451497395833334}, {"start": 2130.76, "end": 2131.22, "word": " دقيق", "probability": 0.9964192708333334}, {"start": 2131.22, "end": 2131.64, "word": " جدا", "probability": 0.991455078125}], "temperature": 1.0}, {"id": 91, "seek": 215686, "start": 2133.12, "end": 2156.86, "text": "لو أنا سألتكم draw all the possible compounds المركبات أنا قولت ال keys انتبهوا جيدا draw all the possible compounds كل المركبات that have the formula C4H8 كيف بدكوا تبدأوا تفكروا تفضلي", "tokens": [1211, 2407, 41850, 8608, 10721, 1211, 2655, 24793, 2642, 439, 264, 1944, 21810, 9673, 31747, 3555, 9307, 41850, 12174, 12610, 2655, 2423, 9317, 16472, 2655, 3555, 3224, 14407, 10874, 25708, 995, 2642, 439, 264, 1944, 21810, 28242, 9673, 31747, 3555, 9307, 300, 362, 264, 8513, 383, 19, 39, 23, 9122, 33911, 47525, 4117, 14407, 6055, 44510, 10721, 14407, 6055, 5172, 37983, 14407, 6055, 5172, 11242, 20292], "avg_logprob": -0.2237639956509889, "compression_ratio": 1.5146198830409356, "no_speech_prob": 0.0, "words": [{"start": 2133.12, "end": 2133.4, "word": "لو", "probability": 0.82421875}, {"start": 2133.4, "end": 2133.62, "word": " أنا", "probability": 0.7177734375}, {"start": 2133.62, "end": 2134.48, "word": " سألتكم", "probability": 0.91748046875}, {"start": 2134.48, "end": 2135.18, "word": " draw", "probability": 0.5390625}, {"start": 2135.18, "end": 2136.46, "word": " all", "probability": 0.94677734375}, {"start": 2136.46, "end": 2136.78, "word": " the", "probability": 0.8154296875}, {"start": 2136.78, "end": 2137.3, "word": " possible", "probability": 0.90625}, {"start": 2137.3, "end": 2138.9, "word": " compounds", "probability": 0.9453125}, {"start": 2138.9, "end": 2140.7, "word": " المركبات", "probability": 0.793701171875}, {"start": 2140.7, "end": 2140.88, "word": " أنا", "probability": 0.451416015625}, {"start": 2140.88, "end": 2141.4, "word": " قولت", "probability": 0.8048502604166666}, {"start": 2141.4, "end": 2141.66, "word": " ال", "probability": 0.87451171875}, {"start": 2141.66, "end": 2142.22, "word": " keys", "probability": 0.07635498046875}, {"start": 2142.22, "end": 2142.96, "word": " انتبهوا", "probability": 0.823681640625}, {"start": 2142.96, "end": 2143.64, "word": " جيدا", "probability": 0.98583984375}, {"start": 2143.64, "end": 2144.34, "word": " draw", "probability": 0.4375}, {"start": 2144.34, "end": 2144.74, "word": " all", "probability": 0.955078125}, {"start": 2144.74, "end": 2145.0, "word": " the", "probability": 0.84619140625}, {"start": 2145.0, "end": 2145.38, "word": " possible", "probability": 0.92724609375}, {"start": 2145.38, "end": 2146.12, "word": " compounds", "probability": 0.90576171875}, {"start": 2146.12, "end": 2146.6, "word": " كل", "probability": 0.7841796875}, {"start": 2146.6, "end": 2147.92, "word": " المركبات", "probability": 0.9730224609375}, {"start": 2147.92, "end": 2148.54, "word": " that", "probability": 0.830078125}, {"start": 2148.54, "end": 2148.98, "word": " have", "probability": 0.9541015625}, {"start": 2148.98, "end": 2149.24, "word": " the", "probability": 0.712890625}, {"start": 2149.24, "end": 2149.82, "word": " formula", "probability": 0.8955078125}, {"start": 2149.82, "end": 2151.32, "word": " C4H8", "probability": 0.8968505859375}, {"start": 2151.32, "end": 2152.98, "word": " كيف", "probability": 0.94677734375}, {"start": 2152.98, "end": 2153.32, "word": " بدكوا", "probability": 0.639404296875}, {"start": 2153.32, "end": 2153.84, "word": " تبدأوا", "probability": 0.9801025390625}, {"start": 2153.84, "end": 2154.78, "word": " تفكروا", "probability": 0.9263916015625}, {"start": 2154.78, "end": 2156.86, "word": " تفضلي", "probability": 0.77740478515625}], "temperature": 1.0}, {"id": 92, "seek": 217592, "start": 2158.83, "end": 2175.93, "text": "أه احنا قلنا الصيغة المشبعة C4H10 خصمنا منها اتنين يالا تكوين ال double bond يالا تكوين حلقة المركبات الحلقية أيضا صيغتها العامة CNH2N", "tokens": [10721, 3224, 1975, 5016, 8315, 12174, 1211, 8315, 31767, 1829, 17082, 3660, 9673, 8592, 3555, 27884, 383, 19, 39, 3279, 16490, 9381, 2304, 8315, 9154, 11296, 1975, 2655, 1863, 9957, 7251, 6027, 995, 6055, 4117, 2407, 9957, 2423, 3834, 6086, 7251, 6027, 995, 6055, 4117, 2407, 9957, 11331, 1211, 28671, 9673, 31747, 3555, 9307, 21542, 1211, 4587, 10632, 36632, 11242, 995, 20328, 1829, 17082, 2655, 11296, 18863, 10943, 3660, 383, 45, 39, 17, 45], "avg_logprob": -0.16270833651224773, "compression_ratio": 1.4966887417218544, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 2158.83, "end": 2159.65, "word": "أه", "probability": 0.45941162109375}, {"start": 2159.65, "end": 2160.05, "word": " احنا", "probability": 0.8311360677083334}, {"start": 2160.05, "end": 2160.45, "word": " قلنا", "probability": 0.8260091145833334}, {"start": 2160.45, "end": 2161.09, "word": " الصيغة", "probability": 0.978271484375}, {"start": 2161.09, "end": 2161.79, "word": " المشبعة", "probability": 0.9766845703125}, {"start": 2161.79, "end": 2163.09, "word": " C4H10", "probability": 0.821044921875}, {"start": 2163.09, "end": 2163.85, "word": " خصمنا", "probability": 0.8714599609375}, {"start": 2163.85, "end": 2164.15, "word": " منها", "probability": 0.978759765625}, {"start": 2164.15, "end": 2164.53, "word": " اتنين", "probability": 0.9576416015625}, {"start": 2164.53, "end": 2165.35, "word": " يالا", "probability": 0.7556966145833334}, {"start": 2165.35, "end": 2165.81, "word": " تكوين", "probability": 0.89892578125}, {"start": 2165.81, "end": 2165.93, "word": " ال", "probability": 0.71826171875}, {"start": 2165.93, "end": 2166.19, "word": " double", "probability": 0.353271484375}, {"start": 2166.19, "end": 2166.67, "word": " bond", "probability": 0.90625}, {"start": 2166.67, "end": 2167.23, "word": " يالا", "probability": 0.8639322916666666}, {"start": 2167.23, "end": 2168.27, "word": " تكوين", "probability": 0.864013671875}, {"start": 2168.27, "end": 2168.79, "word": " حلقة", "probability": 0.93603515625}, {"start": 2168.79, "end": 2170.01, "word": " المركبات", "probability": 0.91845703125}, {"start": 2170.01, "end": 2170.99, "word": " الحلقية", "probability": 0.9815673828125}, {"start": 2170.99, "end": 2171.89, "word": " أيضا", "probability": 0.8372395833333334}, {"start": 2171.89, "end": 2172.61, "word": " صيغتها", "probability": 0.98701171875}, {"start": 2172.61, "end": 2173.61, "word": " العامة", "probability": 0.9934895833333334}, {"start": 2173.61, "end": 2175.93, "word": " CNH2N", "probability": 0.767626953125}], "temperature": 1.0}, {"id": 93, "seek": 220584, "start": 2177.5, "end": 2205.84, "text": "المُركّبات الحلقية صيغتها العامة أيضًا CNN H2N بناءً على ذلك بدي أشوف كم حلقة بقدر أعمل من أربع كربونات عطولي أعطوني الجواب كم حلقة بيعمل إنسان من أربع كربونات؟ غلط، غلط، برضه غلط أربع كربونات كم حلقة بعمل منهم؟ حرام عليكي تمانية", "tokens": [45340, 10859, 31747, 11703, 3555, 9307, 21542, 1211, 4587, 10632, 20328, 1829, 17082, 2655, 11296, 18863, 10943, 3660, 36632, 11242, 14111, 995, 24859, 389, 17, 45, 44945, 16606, 14111, 15844, 29910, 23275, 4724, 16254, 5551, 8592, 38688, 9122, 2304, 11331, 1211, 28671, 4724, 28543, 2288, 5551, 25957, 1211, 9154, 5551, 25513, 3615, 9122, 25513, 2407, 8315, 2655, 6225, 9566, 12610, 1829, 5551, 3615, 9566, 11536, 1829, 25724, 14407, 3555, 9122, 2304, 11331, 1211, 28671, 4724, 1829, 25957, 1211, 36145, 3794, 7649, 9154, 5551, 25513, 3615, 9122, 25513, 2407, 8315, 2655, 22807, 32771, 1211, 9566, 12399, 32771, 1211, 9566, 12399, 4724, 43042, 3224, 32771, 1211, 9566, 5551, 25513, 3615, 9122, 25513, 2407, 8315, 2655, 9122, 2304, 11331, 1211, 28671, 4724, 25957, 1211, 9154, 16095, 22807, 11331, 2288, 10943, 25894, 4117, 1829, 46811, 7649, 10632], "avg_logprob": -0.19018190220665576, "compression_ratio": 1.947867298578199, "no_speech_prob": 0.0, "words": [{"start": 2177.5, "end": 2178.34, "word": "المُركّبات", "probability": 0.836181640625}, {"start": 2178.34, "end": 2179.0, "word": " الحلقية", "probability": 0.9764404296875}, {"start": 2179.0, "end": 2179.52, "word": " صيغتها", "probability": 0.74326171875}, {"start": 2179.52, "end": 2179.94, "word": " العامة", "probability": 0.9928385416666666}, {"start": 2179.94, "end": 2180.4, "word": " أيضًا", "probability": 0.919677734375}, {"start": 2180.4, "end": 2181.32, "word": " CNN", "probability": 0.1710205078125}, {"start": 2181.32, "end": 2182.72, "word": " H2N", "probability": 0.6330973307291666}, {"start": 2182.72, "end": 2183.14, "word": " بناءً", "probability": 0.8400065104166666}, {"start": 2183.14, "end": 2183.3, "word": " على", "probability": 0.62255859375}, {"start": 2183.3, "end": 2183.5, "word": " ذلك", "probability": 0.994873046875}, {"start": 2183.5, "end": 2183.68, "word": " بدي", "probability": 0.3050537109375}, {"start": 2183.68, "end": 2183.96, "word": " أشوف", "probability": 0.9248046875}, {"start": 2183.96, "end": 2184.22, "word": " كم", "probability": 0.76123046875}, {"start": 2184.22, "end": 2184.64, "word": " حلقة", "probability": 0.9807942708333334}, {"start": 2184.64, "end": 2185.06, "word": " بقدر", "probability": 0.93701171875}, {"start": 2185.06, "end": 2185.4, "word": " أعمل", "probability": 0.9723307291666666}, {"start": 2185.4, "end": 2185.56, "word": " من", "probability": 0.99169921875}, {"start": 2185.56, "end": 2185.94, "word": " أربع", "probability": 0.8577473958333334}, {"start": 2185.94, "end": 2186.76, "word": " كربونات", "probability": 0.86376953125}, {"start": 2186.76, "end": 2187.64, "word": " عطولي", "probability": 0.639404296875}, {"start": 2187.64, "end": 2187.98, "word": " أعطوني", "probability": 0.8587890625}, {"start": 2187.98, "end": 2188.3, "word": " الجواب", "probability": 0.900390625}, {"start": 2188.3, "end": 2188.56, "word": " كم", "probability": 0.851806640625}, {"start": 2188.56, "end": 2188.86, "word": " حلقة", "probability": 0.9910481770833334}, {"start": 2188.86, "end": 2189.22, "word": " بيعمل", "probability": 0.93896484375}, {"start": 2189.22, "end": 2189.52, "word": " إنسان", "probability": 0.8818359375}, {"start": 2189.52, "end": 2189.68, "word": " من", "probability": 0.99169921875}, {"start": 2189.68, "end": 2189.98, "word": " أربع", "probability": 0.9666341145833334}, {"start": 2189.98, "end": 2190.76, "word": " كربونات؟", "probability": 0.884765625}, {"start": 2190.76, "end": 2193.48, "word": " غلط،", "probability": 0.69244384765625}, {"start": 2193.48, "end": 2194.54, "word": " غلط،", "probability": 0.7874755859375}, {"start": 2194.54, "end": 2195.78, "word": " برضه", "probability": 0.9176432291666666}, {"start": 2195.78, "end": 2197.16, "word": " غلط", "probability": 0.99560546875}, {"start": 2197.16, "end": 2200.8, "word": " أربع", "probability": 0.8997395833333334}, {"start": 2200.8, "end": 2201.36, "word": " كربونات", "probability": 0.9880859375}, {"start": 2201.36, "end": 2201.6, "word": " كم", "probability": 0.83740234375}, {"start": 2201.6, "end": 2201.96, "word": " حلقة", "probability": 0.9921875}, {"start": 2201.96, "end": 2202.4, "word": " بعمل", "probability": 0.7931315104166666}, {"start": 2202.4, "end": 2203.74, "word": " منهم؟", "probability": 0.9490559895833334}, {"start": 2203.74, "end": 2204.94, "word": " حرام", "probability": 0.9695638020833334}, {"start": 2204.94, "end": 2205.4, "word": " عليكي", "probability": 0.76513671875}, {"start": 2205.4, "end": 2205.84, "word": " تمانية", "probability": 0.8570963541666666}], "temperature": 1.0}, {"id": 94, "seek": 222630, "start": 2213.6, "end": 2226.3, "text": "يا باخد الاربعة زي هيك CH2 CH2 CH2 CH2 يا باخد تلاتة و بطلع منهم مجموعة CH3", "tokens": [25528, 4724, 47283, 3215, 2423, 9640, 3555, 27884, 30767, 1829, 39896, 4117, 5995, 17, 5995, 17, 5995, 17, 5995, 17, 35186, 4724, 47283, 3215, 6055, 1211, 9307, 3660, 4032, 4724, 9566, 1211, 3615, 9154, 16095, 3714, 7435, 2304, 2407, 27884, 5995, 18], "avg_logprob": -0.2570857502693354, "compression_ratio": 1.3522727272727273, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 2213.6, "end": 2215.0, "word": "يا", "probability": 0.0458984375}, {"start": 2215.0, "end": 2216.4, "word": " باخد", "probability": 0.789306640625}, {"start": 2216.4, "end": 2217.1, "word": " الاربعة", "probability": 0.685546875}, {"start": 2217.1, "end": 2217.44, "word": " زي", "probability": 0.839599609375}, {"start": 2217.44, "end": 2218.4, "word": " هيك", "probability": 0.6898193359375}, {"start": 2218.4, "end": 2218.94, "word": " CH2", "probability": 0.77490234375}, {"start": 2218.94, "end": 2219.46, "word": " CH2", "probability": 0.84765625}, {"start": 2219.46, "end": 2219.96, "word": " CH2", "probability": 0.95263671875}, {"start": 2219.96, "end": 2220.94, "word": " CH2", "probability": 0.8994140625}, {"start": 2220.94, "end": 2221.68, "word": " يا", "probability": 0.5615234375}, {"start": 2221.68, "end": 2222.22, "word": " باخد", "probability": 0.9912109375}, {"start": 2222.22, "end": 2223.06, "word": " تلاتة", "probability": 0.926513671875}, {"start": 2223.06, "end": 2224.04, "word": " و", "probability": 0.5341796875}, {"start": 2224.04, "end": 2224.54, "word": " بطلع", "probability": 0.9510498046875}, {"start": 2224.54, 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{"start": 2434.27, "end": 2434.63, "word": " واحد،", "probability": 0.7989908854166666}, {"start": 2434.63, "end": 2434.99, "word": " اتنين", "probability": 0.9344482421875}, {"start": 2434.99, "end": 2435.59, "word": " إجت", "probability": 0.72509765625}, {"start": 2435.59, "end": 2435.75, "word": " ال", "probability": 0.53857421875}, {"start": 2435.75, "end": 2436.03, "word": " مثل", "probability": 0.953369140625}, {"start": 2436.03, "end": 2436.19, "word": " الآن", "probability": 0.6629638671875}, {"start": 2436.19, "end": 2436.39, "word": " على", "probability": 0.9453125}, {"start": 2436.39, "end": 2436.95, "word": " أكم؟", "probability": 0.7727864583333334}], "temperature": 1.0}, {"id": 103, "seek": 245523, "start": 2437.41, "end": 2455.23, "text": "تلاتة لو واحدة رقمت من هنا واحد اتنين هتقول تلاتة اربعة هتخل ال مثل على خمسة ان هو الأصحى اذا من هنا برقم واحد اتنين تلاتة اربعة خمسة ال three مثل Cyclopentane المركب اللي بعده", "tokens": [2655, 1211, 9307, 3660, 45164, 36764, 24401, 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"word": " تريين", "probability": 0.8313802083333334}, {"start": 2525.53, "end": 2525.61, "word": " و", "probability": 0.5263671875}, {"start": 2525.61, "end": 2526.57, "word": " بتحطوا", "probability": 0.865966796875}, {"start": 2526.57, "end": 2528.99, "word": " الأرقام", "probability": 0.947265625}, {"start": 2528.99, "end": 2529.13, "word": " و", "probability": 0.8125}, {"start": 2529.13, "end": 2529.99, "word": " بتنتبهولها", "probability": 0.898193359375}, {"start": 2529.99, "end": 2530.47, "word": " لو", "probability": 0.607421875}, {"start": 2530.47, "end": 2531.03, "word": " أربعة", "probability": 0.9026692708333334}, {"start": 2531.03, "end": 2531.33, "word": " double", "probability": 0.923828125}, {"start": 2531.33, "end": 2531.77, "word": " bonds", "probability": 0.923828125}], "temperature": 1.0}, {"id": 107, "seek": 255437, "start": 2533.63, "end": 2554.37, "text": "تتراين و هكذا واضح؟ لكن هنا يجب أن ننوح لأمر لحظة ال Cyclohexane هذا ايش اسمه؟ Cyclohexane هذا تنتين", 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عشرين زمان، قبل متين سنة، أخد اسم بنزين فما بنسميه إطلاقا Cyclohexatriene ف Cyclohexatriene is not a correct name، شو ال correct name؟ بنزين", "tokens": [3224, 15730, 9673, 31747, 3555, 5551, 9778, 3215, 24525, 2304, 13412, 3224, 25720, 6225, 26890, 16712, 9640, 1829, 9778, 9154, 1975, 1829, 10943, 19446, 6156, 36520, 14407, 18863, 45340, 6156, 2288, 3215, 3224, 8978, 2423, 4386, 7251, 43020, 27188, 34683, 27842, 2304, 10632, 49429, 1975, 8592, 1829, 30767, 1829, 39896, 4117, 12399, 16490, 2304, 3794, 3660, 4032, 6225, 46309, 9957, 30767, 2304, 7649, 12399, 12174, 36150, 44650, 9957, 8608, 1863, 3660, 12399, 5551, 9778, 3215, 24525, 2304, 44945, 11622, 9957, 6156, 15042, 44945, 38251, 1829, 3224, 11933, 9566, 15040, 4587, 995, 10295, 66, 752, 675, 87, 31674, 1450, 6156, 10295, 66, 752, 675, 87, 31674, 1450, 307, 406, 257, 3006, 1315, 12399, 13412, 2407, 2423, 3006, 1315, 22807, 44945, 11622, 9957], "avg_logprob": -0.1790471243076637, "compression_ratio": 1.639344262295082, 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+اسمهاالكربونيل containing compounds يعني المركبات + +7 +00:00:53,230 --> 00:00:56,870 +اللى بتحتوي على مجموعة الكربونيل الان ايش مجموعة + +8 +00:00:56,870 --> 00:01:02,490 +الكربونيل مجموعة الكربونيل هي ال C double bond O + +9 +00:01:02,490 --> 00:01:08,130 +واضح ال C double bond O هي المجموعة اللى اسمها ايش + +10 +00:01:08,130 --> 00:01:15,110 +كربونيلالان كتير في مراكبات .. كتير في مراكبات + +11 +00:01:15,110 --> 00:01:19,530 +فيهم هذه المجموعة الـ C double bond O يعني من هدول + +12 +00:01:19,530 --> 00:01:23,910 +المراكبات الـ aldehydes لما يكون عند الـ C double + +13 +00:01:23,910 --> 00:01:28,970 +bond O مجموعة R وH على الجهة التانية منهم الـ + +14 +00:01:28,970 --> 00:01:32,110 +ketones لما تكون الـ C double bond O محشورة بين + +15 +00:01:32,110 --> 00:01:36,990 +مجمعتين Rمنهم الـ Carboxylic Acids الـ C double + +16 +00:01:36,990 --> 00:01:41,750 +bond O متصلة بـ OH الان المراكبات اللي ضايلة + +17 +00:01:41,750 --> 00:01:46,030 +بنسميها مشتقات من الـ Carboxylic Acids منها الـ E + +18 +00:01:46,030 --> 00:01:49,970 +star C double bond O OR منها الامد C double bond O + +19 +00:01:49,970 --> 00:01:57,970 +NH2 منها ال Acid C double bond OCL وفي كمان مركب + +20 +00:01:57,970 --> 00:02:03,030 +أيضا موجود ومشهور ولو مش مكتوب هنا R C double bond + +21 +00:02:03,030 --> 00:02:09,150 +O O C double bond O R تانية هذا بنسميه acid + +22 +00:02:09,150 --> 00:02:15,610 +anhydride بنسميه acid anhydride + +23 +00:02:17,770 --> 00:02:23,130 +الان اللى بتطلع على هذه العائلة الكبيرة كتير خلينا + +24 +00:02:23,130 --> 00:02:27,630 +نسميه عائلة ال carbonyl compounds هيلحظ انه احنا + +25 +00:02:27,630 --> 00:02:31,890 +صارنا بنحكي عن عائلات فرعية موجودة فيها واحد اتنين + +26 +00:02:31,890 --> 00:02:38,890 +تلاتة اربع خمسة ستةسبعة يعني عدد كبير من العائلات + +27 +00:02:38,890 --> 00:02:42,710 +الفرعية جوا العائلة العاملة هي عائلة الاش ال + +28 +00:02:42,710 --> 00:02:46,390 +carbonyl compounds المركبات اللي بتحتوي على مجموعة + +29 +00:02:46,390 --> 00:02:53,690 +ال C double bond O لحسن الحظ ان هدول العائلات + +30 +00:02:54,350 --> 00:03:01,030 +يقسموا أو يجمعوا إلى عائلتين ال الديهيدس والكيتونز + +31 +00:03:01,030 --> 00:03:04,790 +في كل كتب الكيميا العضوية بتلاقوهم محطوطين مع بعض + +32 +00:03:04,790 --> 00:03:11,170 +في شبتر واحد والأحماض ومشتقاتها بنسميها assets and + +33 +00:03:11,170 --> 00:03:15,710 +their derivatives ال acid derivatives يعني هدولة + +34 +00:03:15,710 --> 00:03:19,290 +derivatives لل acid مشتقات derivative يعني إيش؟ + +35 +00:03:19,970 --> 00:03:25,510 +الاسد ديريفاتيف لو قلنا لكم شو هم الاستر الامد + +36 +00:03:25,510 --> 00:03:32,190 +الاسد هيلايد والاسد انهيدريد هدولة الخمسة بنحط + +37 +00:03:32,190 --> 00:03:38,330 +بعيلة واحدةلاحظوا صار عندى تقسيم بدل ما هو ل سبع + +38 +00:03:38,330 --> 00:03:43,370 +عائلات كلها مختلفة حاطناهم بإيش؟ بعائلتين فقط + +39 +00:03:43,370 --> 00:03:48,850 +الهيتز و الفيتون عائلة الاسيتز و مصادرهم كلهم دول + +40 +00:03:48,850 --> 00:03:53,290 +عائلة و لذلك عادة في الكيميا العضوية في غالب الكتب + +41 +00:03:53,290 --> 00:03:56,630 +هتلاقي انه بنعمل عن كل هذه المركبات chapter يعني + +42 +00:03:56,630 --> 00:04:01,490 +فاصلين هدول بنحطه بفصل لحالهم و هدول بنحطه بفصل + +43 +00:04:01,490 --> 00:04:02,710 +لحالهم + +44 +00:04:05,560 --> 00:04:10,240 +لسه بإمكاننا نبسط الموضوع بإمكاننا نبسط الموضوع + +45 +00:04:10,240 --> 00:04:16,230 +أكثر كثير من هيكنقول ليش هذه التقسيمة و كيف أنا + +46 +00:04:16,230 --> 00:04:20,450 +الاشي الكتير بدي أسهل التعامل معه بنقول هذه + +47 +00:04:20,450 --> 00:04:26,050 +التقسيمة قائمة على كلمتين فقط كلمتين اللي بيفهم + +48 +00:04:26,050 --> 00:04:31,150 +دول الكلمتين بنقدر نقول عنه أنه فيهم ست إلى سبع + +49 +00:04:31,150 --> 00:04:36,090 +محاضرات للأمام هنضلنا نعيد و نزيد فيهم بنفس + +50 +00:04:36,090 --> 00:04:42,790 +الكلمتينواضح؟ صعب على البني آدم يفهم كلمتين كان + +51 +00:04:42,790 --> 00:04:48,130 +زمان برنامج بالتلفزيون بالإذاعة اسمه كلمتين و بس + +52 +00:04:48,130 --> 00:04:52,630 +خلوه و ميرك معاكم مين اللي كان يقدم هذا البرنامج + +53 +00:04:52,630 --> 00:04:58,330 +زمان اسأله الآباء والأجداد المهم ايش الكلمتين + +54 +00:04:58,330 --> 00:05:06,290 +المرتبطات بكل هذه العائلات الكلمة الأولىخاصة بأهم + +55 +00:05:06,290 --> 00:05:12,070 +تفاعل أساسي لهدول المركبات اللي هم ال aldehydes و + +56 +00:05:12,070 --> 00:05:19,630 +ال ketones بيتفاعلوا تفاعل ال addition الإضافة ال + +57 +00:05:19,630 --> 00:05:24,730 +addition و الكلمة التانية لهدول الخمسة اللي ضايقين + +58 +00:05:24,730 --> 00:05:29,750 +معهم ال unhydrate اللي شطبناه بتفاعلوا تفاعل ال + +59 +00:05:29,750 --> 00:05:32,930 +substitution الإبدال تمام؟ + +60 +00:05:37,060 --> 00:05:43,120 +إذن سبب تقسيم هدول السبع مركبات إلى عائلات يعني + +61 +00:05:43,120 --> 00:05:46,440 +أحيانا الإنسان كان ممكن يسأل إذا السبعة بدنا + +62 +00:05:46,440 --> 00:05:50,180 +نعملهم عيلتين أو شبترين كان خلينا أربعة في شبتر + +63 +00:05:50,180 --> 00:05:56,620 +وتلاتة في شبتر تاني ليش خلينا اتنين وخمسة تمام؟ لأ + +64 +00:05:56,620 --> 00:06:03,470 +التقسيم مش تقسيم عددي التقسيم تقسيم وظيفي بمعنىإيش + +65 +00:06:03,470 --> 00:06:10,370 +التفاعل الأساسي لهذه العائلة هو تفاعل الإضافة؟ إيش + +66 +00:06:10,370 --> 00:06:16,450 +التفاعل الأساسي لهذه العائلة هو تفاعل الإبدال؟ + +67 +00:06:16,450 --> 00:06:21,310 +ولذلك لو أي طالب organic chemistry بده يدخل مقابل + +68 +00:06:21,310 --> 00:06:25,510 +التوظيف، مانعش يمسك ورق و جلم و يكتب، لكن أبسط + +69 +00:06:25,510 --> 00:06:29,510 +سؤال بده يسأله ببساطة إيش التفاعل الأساسي + +70 +00:06:29,510 --> 00:06:33,660 +للالدهايتز والكيتونز؟ماعرفش يجاوب ايش التفاعل + +71 +00:06:33,660 --> 00:06:38,720 +الأساسي لل assets ومش رقاتها ماعرفش يجاوب نراكم في + +72 +00:06:38,720 --> 00:06:43,750 +السنة القادمةبالزمش يكون دراسة organic واضح اهتموا + +73 +00:06:43,750 --> 00:06:48,950 +كتير بهدول الكلمتين اللي بيفهموهم جيدا بيكونوا + +74 +00:06:48,950 --> 00:06:53,530 +فاهموا سبع عائلات اللي بيفهموا دول الكلمتين جيدا + +75 +00:06:53,530 --> 00:06:58,350 +بيكونوا فاهموا ايش سبع عائلات ولذلك خلينا نتعمق + +76 +00:06:58,350 --> 00:07:03,070 +اكتر بفهم هدول الكلمتين خلينا نتعمق اكتر بفهم هدول + +77 +00:07:03,070 --> 00:07:07,280 +الكلمتين الان احنا قولنا ايش ال carbonyl groupالـ + +78 +00:07:07,280 --> 00:07:11,960 +C double bond O طب لو كتبنا تحت الكربونيل C double + +79 +00:07:11,960 --> 00:07:17,120 +bond O ورجعنا للكلام اللي بنعرفه بخصوص السالبية + +80 +00:07:17,120 --> 00:07:22,640 +مين أكثر سالبية؟ ال oxygen مين أقل سالبية؟ ال + +81 +00:07:22,640 --> 00:07:26,880 +carbon إذا هذه ال carbon partially positive و هذه + +82 +00:07:26,880 --> 00:07:32,180 +ال oxygen partially negative واضح؟ الآن المحور + +83 +00:07:32,180 --> 00:07:36,410 +الأساسيفي فهم الكيميا كاملة تبعتي السبع عائلات + +84 +00:07:36,410 --> 00:07:43,210 +هدولة بينطلق من انه ال carbon موجبة يعني يمكن أهم + +85 +00:07:43,210 --> 00:07:49,530 +كلمة في فهم هذه العائلات السبعة كلها مجتمعة يعني + +86 +00:07:49,530 --> 00:07:54,250 +في فهم ال two chapters ان نقول ان هذا ال carbon + +87 +00:07:54,250 --> 00:07:59,030 +هاي بدنا نعلمها فيهم كلهم باللون الأحمر اشمالها + +88 +00:07:59,030 --> 00:08:07,920 +موجبةالان من باب تحصيل الحاصل الموجب لما يتفاعل .. + +89 +00:08:07,920 --> 00:08:14,280 +بنفتح بس على واحدة منهم الموجب لما يتفاعل ايش بده؟ + +90 +00:08:14,280 --> 00:08:20,460 +بلغة الكيميا ال يوكليوفالالموجب لما يتفاعل بده + +91 +00:08:20,460 --> 00:08:24,980 +سالب بده نيوكليوفايل بناء على ذلك طالما جميعهم + +92 +00:08:24,980 --> 00:08:29,260 +عندهم ال carbon الموجبة إذا جميعهم تفاعلهم الأساسي + +93 +00:08:29,260 --> 00:08:33,580 +بيستنوا نيوكليوفايل واضح؟ يعني بدي أجيب ان + +94 +00:08:33,580 --> 00:08:40,360 +نيوكليوفايل و هذا عليه زوجمن الالكترونات زي ما + +95 +00:08:40,360 --> 00:08:43,500 +انتوا عارفين سواء كان مشحون او متعادل مش موضوعنا + +96 +00:08:43,500 --> 00:08:47,480 +.. وين بده يروح يجري يهاجم ال nucleophile على ال + +97 +00:08:47,480 --> 00:08:52,420 +carbon نفس ال nucleophile .. نفس ال nucleophile + +98 +00:08:52,420 --> 00:08:59,670 +على ال carbonالان هذا الـ nucleophile لما بيهاجم + +99 +00:08:59,670 --> 00:09:04,370 +على الكربون مرة هيعمل تفاعل إضافة في الحالتين + +100 +00:09:04,370 --> 00:09:08,870 +الأولانيات و في باقى الحالات هيعمل تفاعل إبدال إذا + +101 +00:09:08,870 --> 00:09:13,530 +لو جينا سألناكم قولنا لكم ال aldehydes بيعملوا + +102 +00:09:13,530 --> 00:09:19,150 +addition بتقولوا صحو ال acids و المشتقاتة بيعملوا + +103 +00:09:19,150 --> 00:09:24,510 +substitution صح لو سألنا هل يا ترى ال eucleophilic + +104 +00:09:24,510 --> 00:09:27,850 +addition و ال eucleophilic substitution ولا ال + +105 +00:09:27,850 --> 00:09:30,630 +electrophilic addition و ال electrophilic + +106 +00:09:30,630 --> 00:09:35,440 +substitution؟ ال eucleophilicإذن الآن بنقدر نزيد + +107 +00:09:35,440 --> 00:09:40,440 +كلمة إن ال الديهايدز تفاعلهم الأساسي اللي بديها + +108 +00:09:40,440 --> 00:09:45,340 +بالظبط الـ Eucleophilic addition وفهمنا ليش؟ ال + +109 +00:09:45,340 --> 00:09:50,460 +Eucleophilic addition و الأحماض و مشتقاتها تفاعلهم + +110 +00:09:50,460 --> 00:09:56,390 +الأساسي ال Eucleophilic substitution واضح؟لحد الآن + +111 +00:09:56,390 --> 00:10:02,230 +تمام الان بيصير ايش الناتج اللى بده يتكون عندى ايش + +112 +00:10:02,230 --> 00:10:06,510 +الناتج اللى بده يتكون في حالة ما كنا بنحكي عن ال + +113 +00:10:06,510 --> 00:10:10,870 +aldehydes و ال ketones addition معناه ان ال C + +114 +00:10:10,870 --> 00:10:15,070 +double bond O او ال double bond تصير single bondمش + +115 +00:10:15,070 --> 00:10:18,050 +هيك احنا قولنا ال addition يعني مجرد ماذا ال + +116 +00:10:18,050 --> 00:10:21,830 +nucleophile يهاجم هنا ويعمل رابطة هل معقول يصير + +117 +00:10:21,830 --> 00:10:26,290 +عندي خمس روابط؟ لأ، إذا هذه الرابطة بتتحرك تصبح O + +118 +00:10:26,290 --> 00:10:31,470 +minus بتصفح OH بتاخد H من اللي ال nucleophile أو + +119 +00:10:31,470 --> 00:10:36,310 +من ال solvent إذا الناتج اللي هيصير عندي ناتج ال + +120 +00:10:36,310 --> 00:10:40,310 +addition ببساطة إنه سيضة بال bond O تبعت ال ketone + +121 +00:10:40,310 --> 00:10:43,830 +أو تبعت ال aldehyde شو بده تصير؟ OH + +122 +00:10:46,820 --> 00:10:50,500 +شوفت وين ال addition هنا تم ال addition double + +123 +00:10:50,500 --> 00:10:56,980 +single إضافة شو هو ال addition تحويل ال double + +124 +00:10:56,980 --> 00:11:00,520 +bond إلى single bond إذا في ال aldehydes و ال + +125 +00:11:00,520 --> 00:11:05,060 +ketones ال C double bond O هتصير OH طبّاق + +126 +00:11:05,060 --> 00:11:12,240 +المجموعات R زي ما هي H أو R زي ما هي و اللي إجه + +127 +00:11:12,240 --> 00:11:14,900 +هنا ال nucleophile + +128 +00:11:17,240 --> 00:11:20,840 +مشهور الـ nucleophile اللي هاجمه عام الرابط إذا + +129 +00:11:20,840 --> 00:11:26,440 +هذا الشكل العام تبع نتيجة تفاعل ال الديهيد أو ال + +130 +00:11:26,440 --> 00:11:30,400 +ketones يعني لو إجينا قولنا مثلا لل nucleophile + +131 +00:11:30,400 --> 00:11:32,900 +H2O + +132 +00:11:35,400 --> 00:11:39,820 +ماذا سيحصل؟ هذه في كل الأحوال ستصبح OH مع كل أنواع + +133 +00:11:39,820 --> 00:11:44,040 +الـ nucleophiles لكن الـ H2O ماذا تضع هنا؟ OH + +134 +00:11:44,040 --> 00:11:48,140 +دائما الـ nucleophile المتعدد سنخصه من OH ولو قلنا + +135 +00:11:48,140 --> 00:11:53,420 +لـ nucleophile OH-, سيضع أيضًا OH و بعد ذلك نضع + +136 +00:11:53,420 --> 00:11:57,880 +acid ستصبح هذه OH إذا لو لـ nucleophile H2O أو H-, + +137 +00:11:57,880 --> 00:12:02,700 +سيصبح عندكم على الكربون OH من الألديهيد الأصلي و + +138 +00:12:02,700 --> 00:12:10,190 +OHالمهاجمة لو النيوكليوفايل الكهول شوف دي جهانة OR + +139 +00:12:10,190 --> 00:12:17,210 +هذه OH لا خلافة فيها ثابتة هذه ثابتة اللي هي ال C + +140 +00:12:17,210 --> 00:12:20,290 +double bond O لكن أنا بقول النيوكليوفايل الميا + +141 +00:12:20,290 --> 00:12:29,950 +بتحط OH الكحول بيحط OR ال HCl بيحط Cl و هكذا واضحة + +142 +00:12:29,950 --> 00:12:36,010 +الفكرة؟هي هذا الشكل العام تبع تفاعل إضافة وهو الذي + +143 +00:12:36,010 --> 00:12:41,130 +يميز جميع تفاعلات ال device و ال ketones و هناخد + +144 +00:12:41,130 --> 00:12:46,210 +أمثلة تصير كلها تكرار نضل نعيد يقول بيعمل إضافة و + +145 +00:12:46,210 --> 00:12:52,290 +بس في كل الأمثلة اللي بناخدها إيش بتصير القصة؟هنا + +146 +00:12:52,290 --> 00:12:55,470 +نقول ايه شو هو لليوكليوفايل؟ اذا كان ليوكليوفايل + +147 +00:12:55,470 --> 00:12:58,450 +ماء فهذه كذا، اذا كان الكول هذه كذا، اذا كان + +148 +00:12:58,450 --> 00:13:02,870 +سياناد كذا، اذا كان هايدرايد هذه كذا، يعني فقط هذا + +149 +00:13:02,870 --> 00:13:07,450 +المتغير الوحيد حيصفى عندكم شو هو ليوكليوفايل؟ + +150 +00:13:07,450 --> 00:13:13,950 +واضح؟ الان لو اجينا وقلنا نفس ليوكليوفايل بده + +151 +00:13:13,950 --> 00:13:20,770 +يهاجم علىالكيتون على الكربون الحمراء عفوا على + +152 +00:13:20,770 --> 00:13:24,870 +الاسد لأ ما هو الكيتون زي الألدياد خلصنا منه على + +153 +00:13:24,870 --> 00:13:31,630 +الاسد أو مشتقاته إيش بيكون التفاعل؟ هذا بيجي هنا و + +154 +00:13:31,630 --> 00:13:38,020 +يطرد المجموعة هذهواضح؟ طبعا O H minus لما تترد + +155 +00:13:38,020 --> 00:13:43,920 +تاخد H من برا شو هتصير؟ O R minus لما تترد تاخد H + +156 +00:13:43,920 --> 00:13:51,460 +R O H كحول N H 2 لما تترد N H 3 C L minus لما يترد + +157 +00:13:51,460 --> 00:13:57,140 +C L اذا صار عندى هذه المجموعة هي اللتي تستبدل اللى + +158 +00:13:57,140 --> 00:14:03,380 +جنب ايش اللى جنب الصيغة بال bond O بناء على ذلك + +159 +00:14:03,380 --> 00:14:09,940 +الناتج ايش هيكون؟R C double bond O هذه ما زالت زي + +160 +00:14:09,940 --> 00:14:15,140 +ما هي لكن بدل ال OH او ال OR او ال NH2 whatever + +161 +00:14:15,140 --> 00:14:21,120 +whatever صار إبدال enucleophile نيو ن أيه صوديوم + +162 +00:14:21,120 --> 00:14:25,480 +نيوكليوفايل واضح يعني شيلنا هذه المجموعة و حطينا + +163 +00:14:25,480 --> 00:14:29,880 +مكانها إيش نيوكليوفايل هذا substitution ولا لأ + +164 +00:14:29,880 --> 00:14:35,430 +مجموعة جاية مجموعة طالعةواضحك الفكرة و الجزء اللي + +165 +00:14:35,430 --> 00:14:39,390 +طلع بياخد H بطلع على شكل ماء على شكل أمونيا على + +166 +00:14:39,390 --> 00:14:45,380 +شكل كحول على شكل HClهذا الكلام بتلاقوه بتكرر في كل + +167 +00:14:45,380 --> 00:14:50,660 +عائلات الأحماض ومشتقاتها إذا لو احنا كنا حتى + +168 +00:14:50,660 --> 00:14:55,280 +chapter 9 هذا اللي بدنا نبدأ فيه بدنا نعطيه عنوان + +169 +00:14:55,280 --> 00:14:59,820 +جديد ال dehydes and ketones بين قصين إيش بدنا نكتب + +170 +00:14:59,820 --> 00:15:04,300 +ال eucleophilic addition لو كنا في chapter 10 بدنا + +171 +00:15:04,300 --> 00:15:08,460 +نقول acids and their derivatives بين قصين ال + +172 +00:15:08,460 --> 00:15:12,910 +eucleophilic substitutionاللي فهموا هدولا الكلمتين + +173 +00:15:12,910 --> 00:15:19,430 +جيدا واتدربوا عليهم بيقدروا يتريحوا أربع أو خمس + +174 +00:15:19,430 --> 00:15:24,370 +محاضرات جاية خلاص بيصيروا بس بتذكروا الكلام اللي + +175 +00:15:24,370 --> 00:15:29,230 +قاله الشاعر الجاهلي ما ترانا نقوله إلا معادا من + +176 +00:15:29,230 --> 00:15:36,720 +قولنا .. إيش؟ مكرورةبس بنبقى بنقول addition of + +177 +00:15:36,720 --> 00:15:42,640 +chapter يعني هتشبعه من كلمة addition of chapter + +178 +00:15:43,830 --> 00:15:47,630 +وتشبعوا من كلمة substitution in chapter واضحة + +179 +00:15:47,630 --> 00:15:53,230 +الفكرة ما عدا ذلك بيصير كله بالنسبة لنا رتوش بسيطة + +180 +00:15:53,230 --> 00:15:56,390 +يعني كيف نسمي ال aldehydes ال ketones إيش أشهر ما + +181 +00:15:56,390 --> 00:16:00,590 +هو موجود فيها إيش تطبيقاتها كله تعتبر أشياء بسيطة + +182 +00:16:00,590 --> 00:16:06,110 +الفكرة الأساسية لعبلة التصنيف هي متعلقة بطبيعة + +183 +00:16:06,110 --> 00:16:13,100 +التفاعل الأساسي لكل عائلة واضحة هذه الفكرةالان لو + +184 +00:16:13,100 --> 00:16:18,580 +اتينا مثلا لخواص ال aldehydes و ال ketones بشكل + +185 +00:16:18,580 --> 00:16:24,580 +عام لاحظوا كتب عنهم moderately polar يعني متوسطي + +186 +00:16:24,580 --> 00:16:30,840 +القطبية الان هو يقارن بين ايش؟ بين شغلتين بين ال R + +187 +00:16:30,840 --> 00:16:35,140 +اللي هي ال alkanes لحالها اللي فيها ال London + +188 +00:16:35,140 --> 00:16:44,180 +forces و بين ال alcohols اللي فيها ال OHواضح؟ ال + +189 +00:16:44,180 --> 00:16:48,480 +alcohols اللي فيها ال OH هيدروجين bonding واضحة + +190 +00:16:48,480 --> 00:16:53,080 +الفكرة؟ هنا إيش نوع ال bonding؟ هيدروجين bonding + +191 +00:16:53,080 --> 00:17:01,480 +ممتاز وفي ال alkanes لندن forces طب في الألدهات و + +192 +00:17:01,480 --> 00:17:03,780 +ال ketones اللي إلها partial positive و partial + +193 +00:17:03,780 --> 00:17:08,280 +negative Dipole-dipole attraction اللي تيجي in + +194 +00:17:08,280 --> 00:17:16,870 +between Dipole-dipole اللي هيبالظبطواللي ال + +195 +00:17:16,870 --> 00:17:20,510 +hydrogen bonding أقوى أنواعها وبناء على ذلك هم + +196 +00:17:20,510 --> 00:17:24,610 +أصبحوا moderately polar الان كونهم moderately + +197 +00:17:24,610 --> 00:17:28,890 +polar هذا الكلام على طول بنعكس على ايش؟ على نقطة + +198 +00:17:28,890 --> 00:17:34,290 +الغليان على نقطة الغليان يعني مثلا لو احنا بدنا + +199 +00:17:34,290 --> 00:17:39,270 +نيجي نعمل مقارنة بدنا نيجي نعمل مقارنة بين أشياء + +200 +00:17:39,270 --> 00:17:46,320 +شبه متساوية شبه متساوية في الوزن الجزائييعني خدوا + +201 +00:17:46,320 --> 00:17:55,400 +على سبيل المثال الميثانول ايش صيغته العامة CH3OH + +202 +00:17:55,400 --> 00:18:07,020 +خدوا على سبيل المثال ال formaldehyde CH3OH + +203 +00:18:07,020 --> 00:18:08,000 +CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH + +204 +00:18:08,000 --> 00:18:11,180 +CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH + +205 +00:18:11,180 --> 00:18:12,160 +CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH + +206 +00:18:12,160 --> 00:18:12,260 +CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH + +207 +00:18:12,260 --> 00:18:12,260 +CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH + +208 +00:18:12,260 --> 00:18:12,260 +CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH + +209 +00:18:12,260 --> 00:18:12,260 +CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH + +210 +00:18:12,260 --> 00:18:18,210 +CH3OH CH3OH CH3CH3 CH3 هدول التلت مركبات يكاف + +211 +00:18:18,210 --> 00:18:22,910 +يكونوا متساويين في إيش؟ في الوزن الجزية لو حسبته + +212 +00:18:22,910 --> 00:18:29,330 +هنا اتناش و تلاتة خمستاش و ستاش و ستاش، كدش هنا + +213 +00:18:29,330 --> 00:18:34,170 +الوزن؟ اتنين و تلاتين لو أجينا على ال formaldehyde + +214 +00:18:34,170 --> 00:18:42,130 +ستاش و اتناش و اتنينتلاتين لو اجينا على هذا خمستعش + +215 +00:18:42,130 --> 00:18:46,430 +خمستعش تلاتين يعني يكاد يكون ال molecular weight + +216 +00:18:46,430 --> 00:18:54,350 +لهم ايش ماله متساوي لكن لو اجينا لو اجينا ل .. ال + +217 +00:18:54,350 --> 00:18:58,570 +boiling point لهم التلاتة مين اعلى واحد هيكون + +218 +00:18:58,570 --> 00:19:05,490 +الكحول الكحول boiling point خمسة وستينالميثانول + +219 +00:19:05,490 --> 00:19:14,670 +هذا الاثانول بيعلق بيصير قداش تقريبا 78 اه الان لو + +220 +00:19:14,670 --> 00:19:19,750 +اجينا على ال formaldehyde ال formaldehyde غاز لكن + +221 +00:19:19,750 --> 00:19:23,710 +مش كتير منخفضة نقطة غليانه يعني قوله مثلا ناقص + +222 +00:19:23,710 --> 00:19:27,370 +عشرين انا مش متأكد بإمكانكوا تبحثوا عنها او نجيبها + +223 +00:19:27,370 --> 00:19:32,290 +مرة تانية تعالوا على الاثانهتلاقو ناجس 100 ولا + +224 +00:19:32,290 --> 00:19:38,130 +ناجس 120 تقريبا هانا بحثوا تطلعوا كيف ال boiling + +225 +00:19:38,130 --> 00:19:41,970 +point بتتغير إذا ال boiling point مرتبطة بإيش + +226 +00:19:41,970 --> 00:19:46,350 +مرتبطة بالقطبية بس هذه القيم خليني أقول تقريبية + +227 +00:19:46,350 --> 00:19:51,190 +ممكن مرة تانية نجيب القيم الدقيقة واضحة الفكرة ف + +228 +00:19:51,190 --> 00:19:57,930 +ال polarity أطول إلى انعكاس علىالقطبية الان طيب و + +229 +00:19:57,930 --> 00:20:03,370 +الان عكس على شغل تاني البولاريكي شو هي الذائبية و + +230 +00:20:03,370 --> 00:20:09,470 +القاعدة العامة في الموضوع ايش like dissolves like + +231 +00:20:09,470 --> 00:20:15,950 +الان اكتر حاجة فيها قطبية ايش الكحولات اللي فيها O + +232 +00:20:15,950 --> 00:20:20,190 +H's و بتذكروا حتى لما قلنا عن الكحولات قلنا + +233 +00:20:20,190 --> 00:20:26,280 +مابدناش ننسى ان الكحولفي المجمعتين في الجزء القطبي + +234 +00:20:26,280 --> 00:20:33,200 +ال R والجزء القطبي ال OH والجزء غير القطبي ال R + +235 +00:20:33,200 --> 00:20:37,020 +وبناء على ذلك ال lower alcohols كانت water soluble + +236 +00:20:37,020 --> 00:20:42,000 +وال higher alcohols كانت water solubleتذكرين هذه + +237 +00:20:42,000 --> 00:20:46,180 +المعلومة؟ الكلام نفسه بتكرر وين؟ في ال ketones + +238 +00:20:46,180 --> 00:20:50,400 +برضه ال ketones فيهم جزء قطبة ال C double bond O و + +239 +00:20:50,400 --> 00:20:54,780 +فيهم ال R لما تصير ال R هذه كبيرة بيبطلوا يدوبوا + +240 +00:20:54,780 --> 00:20:57,840 +في الميه بس R صغيرة يعني مثل و مثل بيصير ال + +241 +00:20:57,840 --> 00:21:03,660 +acetone ال acetone بدوب في الميهلكن خلوها إثل و + +242 +00:21:03,660 --> 00:21:07,760 +إثل، إبروبل و إبروبل، فينل و إثل، كبرت، بتبطل + +243 +00:21:07,760 --> 00:21:12,140 +الدوب في المياه، واضح؟ فال lower molecular weight + +244 +00:21:12,140 --> 00:21:14,540 +species، يعني الأشياء اللي ال molecular weight + +245 +00:21:14,540 --> 00:21:18,560 +فيها إجليل في الأذيهات والكيتونز، بتكون إيش؟ water + +246 +00:21:18,560 --> 00:21:23,320 +soluble، كل ما ال R كبرت، بتبطل، يعني زي زي إيش؟ + +247 +00:21:23,320 --> 00:21:27,720 +الكحولاتفمن ال الديهيدس اللي بيدوبوا في الميا بشكل + +248 +00:21:27,720 --> 00:21:30,600 +عام ال formaldehyde بيدوب في الميا بيعطي ال + +249 +00:21:30,600 --> 00:21:34,340 +formalin ال acetaldehyde نسبيا بيدوب بعد هيك بيبطل + +250 +00:21:34,340 --> 00:21:38,000 +يدوب من ال ketones ال acetone بيدوب في الميا بعد + +251 +00:21:38,000 --> 00:21:43,270 +هيكلما يكبروا ببطله يدوبوا واضح فال low molecular + +252 +00:21:43,270 --> 00:21:45,830 +weight species are soluble in water and the + +253 +00:21:45,830 --> 00:21:50,270 +solubility decreases بتنقص as the R chain gets + +254 +00:21:50,270 --> 00:21:54,570 +longer كل ما كبرت ال R كل ما قلت التأبية وهذا + +255 +00:21:54,570 --> 00:21:58,710 +الكلام أيضا في الكحولات لاحظنا واضح الفكرة هذا + +256 +00:21:58,710 --> 00:22:02,710 +الكلام أيضا لاحظنا في الكحولات + +257 +00:22:06,830 --> 00:22:09,910 +طيب كيف بنسمي ال الديهايد و ال ketones؟ احنا قولنا + +258 +00:22:09,910 --> 00:22:14,510 +أساسا كل نظام التسمية في الكيميا العضوية نظام سهل + +259 +00:22:14,510 --> 00:22:20,230 +ليش سهل؟ لأنه مبني على ذكر طول السلسلة منتهي برمز + +260 +00:22:20,230 --> 00:22:28,770 +للمجموعة الوظيفية ال ال K نهايته L E I O للكحول ال + +261 +00:22:28,770 --> 00:22:35,330 +L ل ال الديهايد L و ل ال ketone Oوالذلك ال الديهيد + +262 +00:22:35,330 --> 00:22:40,670 +اللى متكون من كربونة واحدة بنقول مثانال مثانال + +263 +00:22:40,670 --> 00:22:45,130 +ماخد common name formaldehyde الان لو صاروا + +264 +00:22:45,130 --> 00:22:51,120 +كربونتينإيه ثانال؟ أسيتالديهيد الكمونومتينام لو + +265 +00:22:51,120 --> 00:22:56,400 +صاروا تلاتة بروبانال بروبيونالديهيد لو صاروا أربعة + +266 +00:22:56,400 --> 00:23:01,860 +بيوتانال بيوتيرالديهيد بيوتيرالديهيد الآن لاحظوا + +267 +00:23:01,860 --> 00:23:07,320 +هتلاحظوا الفرقبين ال aldehydes و الكحولات يعني في + +268 +00:23:07,320 --> 00:23:11,520 +الكحول كنا نقول ethanol, methanol, ethanol, + +269 +00:23:11,620 --> 00:23:15,320 +propanol, butanol وهنا بنقول methanol, ethanol, + +270 +00:23:15,440 --> 00:23:20,740 +propanol, butanol وين الفرق؟ لأ في فرق تاني أنا + +271 +00:23:20,740 --> 00:23:24,760 +عارف ال all و ال al هذه الفرق لكن في فرق تاني + +272 +00:23:24,760 --> 00:23:32,360 +الاسم كامل هنافي الكحولات لما أجي أقول بروبانول + +273 +00:23:32,360 --> 00:23:36,440 +بكفي؟ + +274 +00:23:36,440 --> 00:23:42,640 +آه الكحول تلت ذرات كربون الآن هل يتر الأو اتش فيه + +275 +00:23:42,640 --> 00:23:47,480 +على واحد؟ one probanol و لا على اتنين؟ two + +276 +00:23:47,480 --> 00:23:52,360 +probanol واضح؟ إذا البروبانول في الكحولات منه + +277 +00:23:52,360 --> 00:23:59,290 +اتنين و البيوتانول كمان لو صار هذه اربع كربوناتهل + +278 +00:23:59,290 --> 00:24:05,490 +الكحول هنا one بيوتانول + +279 +00:24:05,490 --> 00:24:10,050 +ولا two بيوتانول ولا two بيوتانول من هنا مش تلاتة + +280 +00:24:10,050 --> 00:24:18,590 +ال بيوتانول منه كم الكحول واضح؟ لتشين المتسلسل + +281 +00:24:18,590 --> 00:24:23,430 +يعني لو اجاكوا سؤال في الامتحان انه لتشين بيوتانول + +282 +00:24:23,430 --> 00:24:30,280 +اللي زي هيك كم كحول بالمجمل منه اتنينهك هتكون + +283 +00:24:30,280 --> 00:24:34,660 +جوابته غلط واضح؟ + +284 +00:24:34,660 --> 00:24:41,060 +ليش؟ مين تقول لي ليش الغلط؟ + +285 +00:24:41,060 --> 00:24:47,860 +لحظة أنا قلت المتسلسل، بعرف أنه في ISO و في + +286 +00:24:47,860 --> 00:24:53,750 +tertiary، هذه قصة تانيةما بدكوا تظلوا تعودوا اه ال + +287 +00:24:53,750 --> 00:24:55,910 +chiral center مش ال cis و ال trans ال cis و ال + +288 +00:24:55,910 --> 00:24:58,910 +trans كل ما يلي علاقة بالضبط بالبونس و بالحلقات ال + +289 +00:24:58,910 --> 00:25:03,870 +chiral center لما بيصير هذا هنا و بحط O H و H ع + +290 +00:25:03,870 --> 00:25:08,510 +طول صار عندى ROS من ال two butanol ال two butanol + +291 +00:25:08,510 --> 00:25:12,390 +منه ROS ال one butanol مافيش فيه chiral center one + +292 +00:25:12,390 --> 00:25:18,170 +butanolواضح؟ طبعا ما بننساش أنه فيه isobutanol و + +293 +00:25:18,170 --> 00:25:22,790 +tertiarybutanol كل هدول الأشياء لازم تكونوا + +294 +00:25:22,790 --> 00:25:27,470 +عارفينها الان ال aldehydes اللي جابنا للكلام ال + +295 +00:25:27,470 --> 00:25:32,190 +aldehydes لأ مافيش منها واحد و اتنين لأن مجموعة ال + +296 +00:25:32,190 --> 00:25:36,730 +aldehydes لا تكون الا على نمرة واحد و لانها لا + +297 +00:25:36,730 --> 00:25:41,310 +تكون الا على نمرة واحد بنحط ال hash رقميعني ما + +298 +00:25:41,310 --> 00:25:46,110 +إجيناش كتبنا إيثان وان قالب روبان وان قالب يوتان + +299 +00:25:46,110 --> 00:25:49,510 +وان قالب لأنها لا تكون إلا على واحد فالاشي اللي + +300 +00:25:49,510 --> 00:25:54,830 +معروف ضلنا بلزم نكتبه واضح؟ ومثل ال الديهايد + +301 +00:25:54,830 --> 00:25:59,210 +بالمناسبة اللي ما بيكونش إلا على نمرة واحد وفقط + +302 +00:25:59,210 --> 00:26:07,770 +على واحد ال acid الحامض الحامض ما بيكون إلا على + +303 +00:26:07,770 --> 00:26:09,370 +الطرف + +304 +00:26:11,040 --> 00:26:15,620 +هيو زي هيو ولا ممكن يكون c double bond o o h في + +305 +00:26:15,620 --> 00:26:21,440 +النص مستحيل طب الحامض لو اجيت رقمت من هنا واحد + +306 +00:26:21,440 --> 00:26:25,500 +اتنين تلاتة اربعة و بدي اسميه طبعا هقول اكيد + +307 +00:26:25,500 --> 00:26:30,580 +بيوتان مافيش فيها لقاش هتقولي اللي هو الحامض ايش + +308 +00:26:30,580 --> 00:26:39,300 +نهايته اوك اسدأوك أسد بيوتانووك أسد الان هل يا ترى + +309 +00:26:39,300 --> 00:26:44,360 +بنحط بيوتان وان أوك أسد لأ لأ لأ لأ لأ لأ لأ لأ لأ + +310 +00:26:44,360 --> 00:26:45,200 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +311 +00:26:45,200 --> 00:26:46,700 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +312 +00:26:46,700 --> 00:26:47,880 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +313 +00:26:47,880 --> 00:26:48,340 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ + +314 +00:26:48,340 --> 00:26:52,440 +لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ ل + +315 +00:26:55,860 --> 00:27:00,100 +لأ ممكن يكون على موقع اتنين او تلاتة او اكتر يعني + +316 +00:27:00,100 --> 00:27:03,900 +في ال ketone بعد شوية هتلاحظوا لو كان عندنا خمس + +317 +00:27:03,900 --> 00:27:11,720 +ذرات كربون او ستة كم ذرة اللي رسمناهم واحد + +318 +00:27:11,720 --> 00:27:17,200 +اتنين تلاتة اربعة خمسة ستة سبعة و اجينا قولنا من + +319 +00:27:17,200 --> 00:27:24,440 +هذا المركب كسلسلة كم ketone بقدر اطلعلو قولت كام + +320 +00:27:24,440 --> 00:27:29,620 +الديهايد بقدر أعمل منه؟ واحد اسمه Heptanal و الـ C + +321 +00:27:29,620 --> 00:27:33,140 +double bond هو Hannah و Jamal لو قولت كام Acid + +322 +00:27:33,140 --> 00:27:39,020 +بقدر أطلع؟ Acid، واحد Heptanoic Acid لو قولت كام + +323 +00:27:39,020 --> 00:27:43,500 +كيتون؟ إذا إجت Hannah، two Heptanon وإذا إجت + +324 +00:27:43,500 --> 00:27:47,880 +Hannah، three Heptanon وإذا إجت Hannah، four + +325 +00:27:47,880 --> 00:27:56,330 +Heptanon one, twotwo عفوا واحد اتنين تلات عفوا two + +326 +00:27:56,330 --> 00:28:01,070 +و three و four اذا صار عندى two هبتانون و three + +327 +00:28:01,070 --> 00:28:05,490 +هبتانون و four هبتانون الا لو اجت هنا بتصير three + +328 +00:28:05,490 --> 00:28:08,470 +هبتانون من الجهة التانية او لو اجت هنا two هبتانون + +329 +00:28:08,470 --> 00:28:12,490 +من الجهة التانية اذا من هذا صار عندى اكتر من كيتون + +330 +00:28:12,490 --> 00:28:16,930 +فالكيتون يحتاج الى ترقيم لما بيلزم بينما ال + +331 +00:28:16,930 --> 00:28:22,270 +الديهايد لا يكون الا على موقع واحدوأبعد الفكرة + +332 +00:28:22,270 --> 00:28:27,970 +ومثل الديهيد ال acid ومثل ال ketone ال alcohol إذا + +333 +00:28:27,970 --> 00:28:32,990 +الأشياء اللي احنا بنسمي بلزم نحطلها أرقام اللي أنا + +334 +00:28:32,990 --> 00:28:35,750 +خدوها كلها مين يذكرنا في الأشياء اللي بلزمها + +335 +00:28:35,750 --> 00:28:42,450 +أرقامه الأشياء اللي مابلزمها ال alkeneيلزموا أرقام + +336 +00:28:42,450 --> 00:28:47,310 +انتبهوا معايا هاي سبع كاربونات لو كنت بعمل الكيل + +337 +00:28:47,310 --> 00:28:52,670 +ممكن يكون هنا او هنا او هنا اذا ال الكيل بيلزموا + +338 +00:28:52,670 --> 00:28:59,370 +أرقام ال الكاين one-heptane, two-heptane, three + +339 +00:28:59,370 --> 00:29:05,030 +-heptane يلزموا أرقام ال alcohol one-heptanol, two + +340 +00:29:05,030 --> 00:29:08,690 +-heptanol, three-heptanol, four-heptanol يلزموا + +341 +00:29:08,690 --> 00:29:14,920 +أرقامالكيتون two-heptanone، three-heptanone، four + +342 +00:29:14,920 --> 00:29:20,340 +-heptanone يلزم أرقام، إذا الالكيل والالكايد + +343 +00:29:20,340 --> 00:29:25,760 +والالكول والكيتون هدولة بلزمهم أرقام، لكن لو كنت + +344 +00:29:25,760 --> 00:29:30,960 +بحكي عن الديهيد، لأ، هبتنال فقط عن إمرأة واحدة + +345 +00:29:31,450 --> 00:29:36,250 +acid, heptanoic acid فالالدهاد والاسد ما بيكونوا + +346 +00:29:36,250 --> 00:29:54,710 +غير على موقع واحد واضحة تاني الفكرة حابين + +347 +00:29:54,710 --> 00:30:02,640 +تسمعوا الجوابلا بأس السؤال اللي سألته زملتكم أنه + +348 +00:30:02,640 --> 00:30:07,460 +لو كان في عندها رابطة ثلاثية و رابطة ثنائية كيف + +349 +00:30:07,460 --> 00:30:12,600 +بدي أسم المركب؟ تمام؟ لو عندي رابطة ثلاثية و رابطة + +350 +00:30:12,600 --> 00:30:16,800 +ثنائية كيف بدي أسم المركب؟ المركب بدي يكون في ال + +351 +00:30:16,800 --> 00:30:23,190 +keen و ال kind، الآن alphabeticalال E قبل ال I، + +352 +00:30:23,190 --> 00:30:26,570 +يعني لو كان بسبع ذرات، في double bond و triple + +353 +00:30:26,570 --> 00:30:32,170 +bond، إيش هيتسمى؟ هبتين I، يعني بتكونوا تتخيلوه، + +354 +00:30:32,170 --> 00:30:37,410 +سبع ذرات بهذا الشكل، بتأكدوا حيكون لإنه سبعة جاب + +355 +00:30:37,410 --> 00:30:43,720 +كلمة إيش؟ هبتسبع ذرات إيش هيجيبه؟ Hept لما يكون في + +356 +00:30:43,720 --> 00:30:48,960 +double bond ال double bond إيش هيجيبه؟ En لما يكون + +357 +00:30:48,960 --> 00:30:56,120 +في triple bond ل triple bond إيش هيجيبه؟ Ein زي + +358 +00:30:56,120 --> 00:31:01,490 +هيك لازم اسمه يبينحاجة بتعبر عن العدد بعدين عن + +359 +00:31:01,490 --> 00:31:05,650 +الألكين بعدين عن الألكاين هذا الكلام هذا الكلام + +360 +00:31:05,650 --> 00:31:12,530 +ككتابة اسم و كذكر مجموعات لكن بيجي سؤال لما بدي + +361 +00:31:12,530 --> 00:31:19,920 +أرقم أحدد وين موقع ال E وين موقع ال Iهذه لها جثة + +362 +00:31:19,920 --> 00:31:25,080 +تانية و الموقع ال ال و الموقع ال I هذه لها جثة + +363 +00:31:25,080 --> 00:31:28,680 +تانية الآن القصة بتقول القات يعني خليني أعمل سبعة + +364 +00:31:28,680 --> 00:31:35,560 +واحد اتنين تلاتة اربع خمسة ستة سبعة و حطيت هذه زي + +365 +00:31:35,560 --> 00:31:37,300 +هيك و حطيت هنا triple bond + +366 +00:31:40,170 --> 00:31:44,050 +هذا heaped in I الان من وان بده ارقمه من هنا ولا + +367 +00:31:44,050 --> 00:31:50,230 +من هناك بنقول بنرقمه من الأقرب لأحد الأطراف يعني + +368 +00:31:50,230 --> 00:31:53,430 +تكون سواء double او triple اقرب يعني هنا لو عديت + +369 +00:31:53,430 --> 00:31:56,130 +واحد اتنين اول multiple point بتقابلني هنا عن + +370 +00:31:56,130 --> 00:31:59,930 +امرأة كم؟ تلاتة اول واحدة بتقابلني عن امرأة ايش؟ + +371 +00:31:59,930 --> 00:32:04,110 +واحد وبناء على ذلك هرقم واحد اتنين تلاتة اربعة + +372 +00:32:04,110 --> 00:32:14,600 +خمسة ستة سبعة فهذا هيكون heapedone in أربعة I هبت + +373 +00:32:14,600 --> 00:32:23,520 +one in four I واضح طبعا لو انعكس سجلوا هذا الشغل ب + +374 +00:32:23,520 --> 00:32:31,160 +ثانية بقول برقم من الأقرب لأحد الأطراف الأقرب + +375 +00:32:31,160 --> 00:32:35,760 +بشتغل عليه تمام يعني هذا المركب .. بصوا بري ثانية + +376 +00:32:35,760 --> 00:32:41,500 +يا هودايعني هذا المركب نفسه الآن لو كان زي هيك ايش + +377 +00:32:41,500 --> 00:32:45,740 +رأيكم؟ هيظلوا على نفس الترقيم؟ اه .. اه .. اه .. + +378 +00:32:45,740 --> 00:32:45,840 +اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه + +379 +00:32:45,840 --> 00:32:46,020 +.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. + +380 +00:32:46,020 --> 00:32:47,260 +اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه + +381 +00:32:47,260 --> 00:32:47,540 +.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. + +382 +00:32:47,540 --> 00:32:48,040 +اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه + +383 +00:32:48,040 --> 00:32:48,460 +.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. + +384 +00:32:48,460 --> 00:32:52,340 +اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. ا + +385 +00:32:53,210 --> 00:32:58,710 +يعني مافيش تسمية نهائية تكون I'm in هذه ضد ال + +386 +00:32:58,710 --> 00:33:01,910 +alphabetical دائما الاتقاء ال double و ال triple + +387 +00:33:01,910 --> 00:33:06,210 +bond يجب أن تكون إيش؟ in I'm مافيش إشي في الكون + +388 +00:33:06,210 --> 00:33:11,990 +اسمه I'm in ضد ال alphabetical واضح؟ الآن الترقيم + +389 +00:33:11,990 --> 00:33:16,190 +هلجيته؟ هذي جاي ع نمره واحد لو بتعد من هنا بتجي ع + +390 +00:33:16,190 --> 00:33:19,770 +نمره واحد اتنين تلاتة إذا هذا الترقيم الصح وجدت + +391 +00:33:19,770 --> 00:33:22,470 +هذا المركب لما بده يتسمى مرة تانية + +392 +00:33:26,270 --> 00:33:34,090 +لاحظوا in و i عشان يتقارنوا المركبين الان هذا ال + +393 +00:33:34,090 --> 00:33:40,250 +in تبع وين اربعة و ال i تبع واحد خلصنا من المركب + +394 +00:33:40,250 --> 00:33:46,310 +اللي قبله ماناش فيه هذا بيصير اسمه four in one i + +395 +00:33:46,310 --> 00:33:51,450 +فتسمية ال double و ال triple bond إذا التقوا مع + +396 +00:33:51,450 --> 00:33:57,650 +بعضيجب أن يُذكروا in I ويجب أن يكون الترقيم من + +397 +00:33:57,650 --> 00:34:01,910 +الأقرب إلى أحد الأطراف الآن بيجوا الناس الاش + +398 +00:34:01,910 --> 00:34:09,090 +الملولوين عارفين هم؟ اه دول تعون لو بيقولوا طيب يا + +399 +00:34:09,090 --> 00:34:14,470 +تورا لو كانوا التنتين على نفس البعد يعني لو حطيت + +400 +00:34:14,470 --> 00:34:20,920 +هنا نشطب هدول احنا الآن مش عارفينأه لو كانوا + +401 +00:34:20,920 --> 00:34:25,600 +التنتين على نفس البعد حطيتها الرابطة و هالرابطة + +402 +00:34:25,600 --> 00:34:30,900 +جيت هنا عديت واحد هاي أول ما بلجي واحدة منه مع + +403 +00:34:30,900 --> 00:34:36,320 +نمرقاش اتنين و هنا واحد اتنين على اليمين اتنين و + +404 +00:34:36,320 --> 00:34:39,300 +على الشمال اتنين و أكتب نعطي الأولوية لا إيش في + +405 +00:34:39,300 --> 00:34:43,880 +الترخيم للتنائية إذا تساوإذا تساوى الأولوي + +406 +00:34:43,880 --> 00:34:48,900 +للثنائية فمثل هذا المركب برضه هيكون hip و in و I + +407 +00:34:48,900 --> 00:34:53,160 +ان هذا مما لا خلافة فيه كلمة in و I الآن الترقيم + +408 +00:34:53,160 --> 00:34:59,180 +لأ بنخليه إذا تساوى المرور على الرابطة الثنائية + +409 +00:34:59,180 --> 00:35:08,100 +قبل الرابطة الثلاثية إذا هذا بيكون two in five + +410 +00:35:08,100 --> 00:35:15,930 +I واضح الفكرةفهذا الكلام لو انتقى رابطة ثنائية أو + +411 +00:35:15,930 --> 00:35:22,750 +ثلاثية يذكره قولا واحدا in I الترقيم من الأقرب + +412 +00:35:22,750 --> 00:35:26,610 +لأحد الأطراف بغض النظر كرابطة زوجية أو ثنائية إلا + +413 +00:35:26,610 --> 00:35:32,130 +إذا تساووا فالأفضلية هتكون لإيش ال in بتكون مفضلة + +414 +00:35:32,130 --> 00:35:37,070 +على ال I احنا هذه المعلومة كنا مختصرينها طالما + +415 +00:35:37,070 --> 00:35:40,410 +سألت زمنكوا فيها فصرنا ضايفينها + +416 +00:35:44,460 --> 00:35:48,380 +لاحظوا معي ال الديهايد لما تيجي على ال aromatic + +417 +00:35:48,380 --> 00:35:54,960 +compounds أخدنا تسميتها يعني هذا benzaldehyde هنا + +418 +00:35:54,960 --> 00:35:59,520 +التقاء الديهايد مع الكهول ال الديهايد أقوى من + +419 +00:35:59,520 --> 00:36:08,220 +الكهول وعشان هيصير two-hydroxy benzaldehyde + +420 +00:36:08,220 --> 00:36:09,540 +شوف الحرف ال بيه رايح + +421 +00:36:12,860 --> 00:36:17,280 +2-hydroxybenzaldehyde اللي هو اسمه salicyldehyde + +422 +00:36:17,280 --> 00:36:20,720 +يمكن مار عليك انتوا salicylic acid لما تكون هذه OH + +423 +00:36:20,720 --> 00:36:25,560 +و هذا acid لو كان الديهايد salicyldehyde مثلا هذا + +424 +00:36:25,560 --> 00:36:29,940 +المركب في الديهايد و OH او مثل من اعلى واحدة ال + +425 +00:36:29,940 --> 00:36:36,840 +الديهايد اذا مركبي كله هذا اسمهبنزالدهيد ايش بيحمل + +426 +00:36:36,840 --> 00:36:42,320 +على نمرة أربعة؟ هيدروكسي وع نمرة تلاتة؟ ميثوكسي + +427 +00:36:42,320 --> 00:36:46,860 +إذا هذا لو بدأ أسميه اسم كامل، إيش هقول؟ four + +428 +00:36:46,860 --> 00:36:55,780 +-hydroxy three-methoxy، بنستعمل بهرة وميتا؟ four + +429 +00:36:55,780 --> 00:37:01,280 +-hydroxy، three-methoxy، benzaldehyde، اللي هو + +430 +00:37:01,280 --> 00:37:08,950 +مركب إيش؟الفانيلا يعني الفانيلا هي نفس الاسم تبعها + +431 +00:37:08,950 --> 00:37:16,070 +4-hydroxy-3-methoxy-benzaldehyde الآن أخر شغلة بدي + +432 +00:37:16,070 --> 00:37:23,250 +أحكيها لو يا ترى إجا الكحول أو الالديهايد أو + +433 +00:37:23,250 --> 00:37:29,710 +الكيتون على حلقة لاحظوا معي بدي أخد دراسة مقارنة + +434 +00:37:29,710 --> 00:37:38,320 +للثلاثة كحولالديهاي كيتون ييجوا على حلقة نفترض على + +435 +00:37:38,320 --> 00:37:46,280 +سايكلوبنتين خلّينا نتطلع بالشكل القاتل هنعمل هنعمل + +436 +00:37:46,280 --> 00:37:51,220 +تلت مرات الكلام الآن هي السايكلوبنتين عملناها مرة + +437 +00:37:51,220 --> 00:38:02,620 +مرتين تلاتة في مرة حطينا عليها إيش مجموعة OH هذا + +438 +00:38:02,620 --> 00:38:08,930 +إيشكحول و في المرة حاطينا عليها C double bond O + +439 +00:38:08,930 --> 00:38:13,730 +هذا كيتون في المرة التالتة اجينا نحط عليهم + +440 +00:38:13,730 --> 00:38:18,170 +الديهايد ال الديهايد شو هو كيف بقدر احط انا هنا + +441 +00:38:18,170 --> 00:38:23,920 +الديهايد جربوامافيش غير ان كل مجموعة ال الديهايد + +442 +00:38:23,920 --> 00:38:29,900 +اطلعها برا يعني اطلع برا C double bond O H شوفتوا + +443 +00:38:29,900 --> 00:38:33,660 +الفرق بينهم كيف ان انا هنا حطيت O مشبوكة مباشرة + +444 +00:38:33,660 --> 00:38:37,680 +بالحلقة هنا حطيت C double bond O مشبوكة مباشرة + +445 +00:38:37,680 --> 00:38:41,960 +بالحلقة هنا مافيش طريقة ان اطلع الديهايد ال oxygen + +446 +00:38:41,960 --> 00:38:46,100 +فيه مشبوكة مباشرة بالحلقة فبطلع كل مجموعة ال + +447 +00:38:46,100 --> 00:38:53,320 +الديهايد براواضح؟ اللي هي مع Carbon هذي زادت عن + +448 +00:38:53,320 --> 00:38:57,620 +هذي بإيش؟ ب Carbon ولذلك هذا لما بدنا نسميه + +449 +00:38:57,620 --> 00:39:02,560 +Cyclopentanol + +450 +00:39:02,560 --> 00:39:08,340 +تان و بنضيف النهاية تبعته All Cyclopentanol خلصنا + +451 +00:39:08,340 --> 00:39:16,050 +هذا لما بدنا نسميه نفس الفكرة Cycloبنتان وبنحطله + +452 +00:39:16,050 --> 00:39:23,250 +نهاية ال ketone بنتانون وخلصنا هذا لما بدي اسميه + +453 +00:39:23,250 --> 00:39:30,330 +.. لأ بسميهوش cycle بالتنالليش؟ لأنه إجي عليه + +454 +00:39:30,330 --> 00:39:33,690 +مجموعة كاملة خارجية، إجي عليه كمان carbon، C + +455 +00:39:33,690 --> 00:39:39,350 +double bond OH، بنسميه Cyclopenten-carb-aldehyde + +456 +00:39:39,350 --> 00:39:43,410 +لأنه إجت carbon زيادة عن اللي جابله، ولذلك هذا إيش + +457 +00:39:43,410 --> 00:39:50,910 +بده يتسمى؟ Cyclopenten-carb-aldehyde + +458 +00:39:53,820 --> 00:39:58,780 +ملاحظين الفرق بينهم؟ أنه أنا مابقدرش أشبك أكسوجين + +459 +00:39:58,780 --> 00:40:02,560 +الالديهايد مباشرة بالحلقة إلا من خلال ذرة كربون + +460 +00:40:02,560 --> 00:40:07,620 +ولذلك بنسميه Cyclopentane Carbaldehyde شفتوا الفرق + +461 +00:40:07,620 --> 00:40:11,500 +بين الكحول والكيتون والالديهايد لو يجي على حلقة؟ + +462 +00:40:12,310 --> 00:40:16,630 +الان لو واحدة فيكم شاطرة بعد ما نختم المحاضرة بذكر + +463 +00:40:16,630 --> 00:40:20,210 +الله اتقولي كمان اخر مثال عشان نسكر هذه النقطة + +464 +00:40:20,210 --> 00:40:26,510 +المفروض يلحق هدولة كلهم ايش هيكون ال acid ال acid + +465 +00:40:26,510 --> 00:40:32,070 +لو بده ييجي على الحلقة كيف بده ييجي زي ال aldehyde + +466 +00:40:32,070 --> 00:40:37,150 +ال acid لو بده ييجي على الحلقة بده ييجي كله معلج + +467 +00:40:37,150 --> 00:40:38,010 +على الحلقة + +468 +00:40:42,740 --> 00:40:46,200 +ماقدرش أحطه على نفس الحلقة الأكسجينة المتصلة ولذلك + +469 +00:40:46,200 --> 00:40:49,820 +لما بدي أسميه بدي أسميه بشكل موازن لنظام ال + +470 +00:40:49,820 --> 00:40:57,680 +الديهايد إيش وجدت حاجة أقول عنه؟ Cyclo .. بنتين .. + +471 +00:40:57,680 --> 00:41:03,300 +Carboxylic acid كمان Carboxylic acid + +472 +00:41:05,250 --> 00:41:09,150 +شوفتوا كيف مقارنة الأمور بتيجي الكحول والكيتون + +473 +00:41:09,150 --> 00:41:11,750 +بيجيوا مباشرة على الحلقة فبنقول cyclopentanol + +474 +00:41:11,750 --> 00:41:16,090 +وcyclopentanol ال aldehyde لأ cyclopentane وcarb + +475 +00:41:16,090 --> 00:41:20,670 +aldehyde ال acid cyclopentane وcarboxylic acid + +476 +00:41:20,670 --> 00:41:26,650 +واضحة الفكرة وبهيك بننهي المحاضرة اليوم المرة اللي + +477 +00:41:26,650 --> 00:41:29,970 +جاي بنستمر في موضوع التسمية وموضوع ال aldehydes + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..4a075348eece73c87e077b423cbeb4fa63de7f1f --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_postprocess.srt @@ -0,0 +1,1924 @@ +1 +00:00:19,490 --> 00:00:24,290 +بسم الله الرحمن الرحيم المرة الماضية بدينا في + +2 +00:00:24,290 --> 00:00:28,130 +موضوع ال carbohydrates بدينا في موضوع ال + +3 +00:00:28,130 --> 00:00:34,450 +carbohydrates وقولنا انه امكوانين من carbon و ما + +4 +00:00:34,450 --> 00:00:41,130 +.. و بعدين طبعا بدينا في ال sugarsقولنا ال sugars + +5 +00:00:41,130 --> 00:00:45,030 +في النهاية هما ال الديهيدز او كيتونز لكن فيهم + +6 +00:00:45,030 --> 00:00:48,670 +مجموعات اوقاتش كثيرة بوليهيدروكسي الديهيدز او + +7 +00:00:48,670 --> 00:00:55,050 +بوليهيدروكسي كيتونز طبعا بسبب وجود ال chiral + +8 +00:00:55,050 --> 00:01:00,910 +centersبصير عندنا عدد ال isomers للصيغة الواحدة + +9 +00:01:00,910 --> 00:01:06,330 +كتير و اتدرجنا طبعا من أبسط مركب في one chiral + +10 +00:01:06,330 --> 00:01:11,690 +center اللي هو ال glycerol dihyde و رسمنا بطرق + +11 +00:01:11,690 --> 00:01:22,940 +مختلفة شوفنا كيف المركبات هذه ممكن تكونD أو L في + +12 +00:01:22,940 --> 00:01:25,300 +المرحلة الأولى و لو قلنا لو عندنا one chiral + +13 +00:01:25,300 --> 00:01:30,540 +center بيصير في عندنا مركبين بعد هيك قصة ال D و L + +14 +00:01:30,540 --> 00:01:34,580 +بتستمر بزيادة ال chiral center و بيبدأ العدد يزيد + +15 +00:01:34,580 --> 00:01:43,040 +فبناء على ذلك بناء على ذلك فبموضوع + +16 +00:01:43,040 --> 00:01:46,140 +ال sugars + +17 +00:01:47,420 --> 00:01:52,440 +قلنا أساسي جدا نتطلع على ال chiral centers و نتذكر + +18 +00:01:52,440 --> 00:01:55,620 +كل الكلام اللي حكيناه في chiral centers في chapter + +19 +00:01:55,620 --> 00:01:59,460 +4 إذا عندنا one chiral center بنتوقع مركبين two + +20 +00:01:59,460 --> 00:02:04,480 +chiral centers بنتوقع أربعة و هكذا بدأنا بالتدريج + +21 +00:02:04,480 --> 00:02:09,980 +و أخر شيء انتهينا عنده احنا لما كان في عندنا ست + +22 +00:02:09,980 --> 00:02:17,870 +ذرات كربون طبعا لما بيكون عندى ست ذرات كربونعلى + +23 +00:02:17,870 --> 00:02:22,090 +حسب ما بنرسم احنا ال sugar بالطريقة اللي اتعلمناها + +24 +00:02:22,090 --> 00:02:27,370 +الذرة الأولى من فوق الديهايد وبناء على ذلك هذا مش + +25 +00:02:27,370 --> 00:02:32,550 +chiral center والذرة الأخيرة من تحت CH2OH مش + +26 +00:02:32,550 --> 00:02:36,970 +chiral center واجتها لو رسمنا الشكل اللي بنسميه + +27 +00:02:36,970 --> 00:02:42,950 +الacyclic structure بيكون فينا كام isomer كام + +28 +00:02:42,950 --> 00:02:50,800 +chiral center أربعة بيقدروا إلىالان طالما ان السكر + +29 +00:02:50,800 --> 00:02:55,840 +عبارة عن الكهول و الديهايد لو جربنا نجعل الكهول + +30 +00:02:55,840 --> 00:03:00,640 +يسكر على الديهايد هيعمل a new chiral center هيصير + +31 +00:03:00,640 --> 00:03:07,080 +اندفعخمسة كايرال سنترز وجدت بنتوقع انه لسكر مكون + +32 +00:03:07,080 --> 00:03:11,460 +من ست ذرات كربون بهذا الشكل يكون عنده اتنين و + +33 +00:03:11,460 --> 00:03:17,320 +تلاتين ايزومات طبعا لما تمت عملية الاغلاق لما تمت + +34 +00:03:17,320 --> 00:03:23,040 +عملية اغلاق الالكول على ال الديهايدبهذا الشكل + +35 +00:03:23,040 --> 00:03:28,100 +اتكون عندى هنا ال new chiral center وقولنا + +36 +00:03:28,100 --> 00:03:30,920 +الكاربون هذه اللى بتعمل ال new chiral center شو + +37 +00:03:30,920 --> 00:03:35,460 +بنسميها احنا انوميرك كاربون الان معنى new chiral + +38 +00:03:35,460 --> 00:03:40,060 +center ان هو ال OH هذى بنسميها اما لأعلىوإما لأسفل + +39 +00:03:40,060 --> 00:03:44,460 +وقلنا إذا بتكون لأسفل بنقول هذا Alpha compound + +40 +00:03:44,460 --> 00:03:48,740 +وإذا بتكون لأعلى بيقول هذا Beta الآن طالما أنه في + +41 +00:03:48,740 --> 00:03:52,560 +أربعة chiral centers كان عنده 16 مركب كل واحد فيهم + +42 +00:03:52,560 --> 00:03:55,840 +لما بده يسكر بده يقسم Alpha Beta Alpha Beta معنا + +43 +00:03:55,840 --> 00:04:01,820 +ذلك المجموع صار إيش 32 مركب هذا تقريبا أخر شيء + +44 +00:04:01,820 --> 00:04:08,390 +انتهينا فيه الآن اللي بدي أنبهلهطيب الآن قلنا في + +45 +00:04:08,390 --> 00:04:15,210 +عندنا شكل a cyclic و أشكال cyclic لأ هذا السكر ال + +46 +00:04:15,210 --> 00:04:21,450 +a cyclic يترى بأي نسبة عادة موجود في المحلول و ال + +47 +00:04:21,450 --> 00:04:26,860 +cyclic بأي نسبة موجودين في المحلولالصحيح أن الـ + +48 +00:04:26,860 --> 00:04:33,080 +acyclic في محلول مائي يوجد بنسبة قليلة جدا جدا جدا + +49 +00:04:33,080 --> 00:04:37,000 +يعني معظم السكر بينوجد على شكل الحلقة النسبة اللي + +50 +00:04:37,000 --> 00:04:43,460 +بينوجد فيها ال acyclic في محلول مائي هي 0.003 + +51 +00:04:43,460 --> 00:04:50,780 +بيرزة تلاتة من ألف يعني أكاد يكون مش موجود إذا + +52 +00:04:50,780 --> 00:04:57,310 +كأنه كل السكربسكر واضح كأنه كل السكر بيسكر لما + +53 +00:04:57,310 --> 00:05:01,290 +نقول هذه النسبة قليلة جدا اللى بينوجد فيها الـA + +54 +00:05:01,290 --> 00:05:05,630 +Cycle طيب كل السكر بيسكر بيسكر على ايش Alpha و + +55 +00:05:05,630 --> 00:05:10,550 +Beta هل بيكونوا بنفس النسبة اتعودنا او حكينا انه + +56 +00:05:10,550 --> 00:05:16,930 +لأ بيكون ال Beta بالمعدل حوالي 64والألف حوالي 36 + +57 +00:05:16,930 --> 00:05:24,030 +او هنا 35.5 يمكن هناك 64.5 و هنا 35.5 لو بدنا نسيب + +58 +00:05:24,030 --> 00:05:31,860 +شوية دقيقة واضح يمكن البعض يقولطب كيف جدروا يفصلوا + +59 +00:05:31,860 --> 00:05:36,080 +هذا لوحده يعني طالما انه هذا اتزان ما بين ال alpha + +60 +00:05:36,080 --> 00:05:40,540 +و ال beta يعني دايما المخلوط موجود فيه التنين كيف + +61 +00:05:40,540 --> 00:05:43,940 +يتعرفوا على ال alpha لحاله اذا انا بحط في المحلول + +62 +00:05:43,940 --> 00:05:48,560 +المائي بينوجدوا التنين الجواب اه في المحلول المائي + +63 +00:05:48,560 --> 00:05:53,160 +بينوجدوا التنين فعلالكن لو اعملنا للمركب + +64 +00:05:53,160 --> 00:05:59,460 +crystallization تبلر من محلول Methanol فقط بيطلع + +65 +00:05:59,460 --> 00:06:04,300 +عند ال alpha نقي يعني انا في غير الميه بقدر احصل + +66 +00:06:04,300 --> 00:06:10,400 +ال alpha نقي ال alpha ال pure alpha وين بشوفه + +67 +00:06:10,400 --> 00:06:15,440 +بمحلول ايش؟الميثانول فلو عملنا crystallization + +68 +00:06:15,440 --> 00:06:19,180 +للسكر هذا ال جولوكوز بمحلول الميثانول باخد ال + +69 +00:06:19,180 --> 00:06:23,320 +alpha لوحده واضح الفكرة؟ الان لو عملت + +70 +00:06:23,320 --> 00:06:30,020 +crystallization بال acidic acid بحصل على ال beta + +71 +00:06:30,020 --> 00:06:38,760 +لوحده فقط ايش؟ ال beta ال pure betaواضح؟ الان لو + +72 +00:06:38,760 --> 00:06:42,760 +اجيت اخدت انا صار في عندى alpha pure يعني صار في + +73 +00:06:42,760 --> 00:06:47,100 +عندى بوتل في alpha pure بوتل تاني في beta pure ال + +74 +00:06:47,100 --> 00:06:51,590 +alpha pure من وين باخده؟من خلال الميثانول ال beta + +75 +00:06:51,590 --> 00:06:55,910 +pure من ال acetic acid الآن لو جبت ال alpha pure + +76 +00:06:55,910 --> 00:07:01,750 +حطيته في الميه في محلول الميه بيصير يعمل التحول + +77 +00:07:01,750 --> 00:07:05,730 +لacyclic و برد سكر alpha beta إلى أن يصل إلى + +78 +00:07:05,730 --> 00:07:10,410 +الاتزان اللى اتفقنا عليه ال 36 و64 فهذا الاتزان + +79 +00:07:10,410 --> 00:07:16,370 +وين بيكون موجود في ال aqueous solutionفي المحلول + +80 +00:07:16,370 --> 00:07:21,370 +المائي لو بدأت بالألفة النقي هيصل لهذا الاتزان و + +81 +00:07:21,370 --> 00:07:26,730 +لو بدأت بالبيتا النقي أيضا هيصل لهذا الاتزان واضح؟ + +82 +00:07:26,730 --> 00:07:31,510 +إذا بالإمكان إن أنا أفصل ألفة نقي ب solvent غير + +83 +00:07:31,510 --> 00:07:35,870 +الميه وبيتا نقي ب solvent غير الميه لكن في الميه + +84 +00:07:35,870 --> 00:07:41,270 +لو بدأت بأي واحد فهيحصل الاتزان اللي هو بين ألفة + +85 +00:07:41,270 --> 00:07:48,250 +وبيتابنسبة 36 ل 64 هذا الكلام بيعني شغلة بيعني ان + +86 +00:07:48,250 --> 00:07:53,770 +which is more stable ال alpha ولا ال beta ال beta + +87 +00:07:53,770 --> 00:07:58,870 +اللي موجود بنسبة اكبر هو اللي بيكون more stable + +88 +00:07:58,870 --> 00:08:01,490 +واضح هذه الفكرة + +89 +00:08:05,630 --> 00:08:10,350 +بعد هيك بدنا ننتبه لنقطة أنه لما بتم الإغلاق ال + +90 +00:08:10,350 --> 00:08:15,130 +الديهايد مجموعة واحدة مش موضوع خلافي لكن ال OHS + +91 +00:08:17,200 --> 00:08:25,520 +أكتار زي ما اتكلمنا هذه OH ممكن تسكرها و إغلاق + +92 +00:08:25,520 --> 00:08:29,580 +أي OH يعطي حلقة بحجم مختلف يعني لو أغلقت من هنا + +93 +00:08:29,580 --> 00:08:35,060 +ستكون حلقة ثلاثية لو هيك سكرت ربعية لو هذه سكرت + +94 +00:08:35,060 --> 00:08:40,980 +خمسية هذه اللي سكرت السداسية هذه سبعية هل يترا + +95 +00:08:40,980 --> 00:08:47,530 +ممكن أن يتم إغلاقات لغير الحلقة السداسية؟اللي + +96 +00:08:47,530 --> 00:08:53,130 +مشهور حقيقة انه بتم اغلاق من ال OH اللي موجودة هنا + +97 +00:08:53,130 --> 00:08:59,730 +وبيعطيني حلقة خماسية لكن قداش نسبة السكر اللي + +98 +00:08:59,730 --> 00:09:05,970 +بيكون كحلقة خماسية واحد في المية يعني لاحظوا لو + +99 +00:09:05,970 --> 00:09:09,930 +انا بدي اجي على المحلول بالمجمل هقول في عندي واحد + +100 +00:09:09,930 --> 00:09:15,870 +في المية حلقة خماسية في عندي تلاتة بالألف إيه + +101 +00:09:15,870 --> 00:09:23,200 +صايفلك؟فاتح والباقي حلقة سداسية بتكون النسبة بين + +102 +00:09:23,200 --> 00:09:31,200 +مكوناتها 64 إلى 36 واضح فالمحلول هيكون فيه اكثر من + +103 +00:09:31,200 --> 00:09:36,100 +شغلة هيكون فيه محلول الجولوكوز الacyclic بنسبة + +104 +00:09:36,770 --> 00:09:43,010 +تلاتة في الألف المسكّر على حلقة خماسية بيكون بنسبة + +105 +00:09:43,010 --> 00:09:46,370 +واحد في المية الاناليبيكي اللي هو التسعة وتسعين في + +106 +00:09:46,370 --> 00:09:51,050 +المية كيف بتكون مقصومة اربعة وستين في المية منها + +107 +00:09:51,050 --> 00:09:55,410 +بيتا ستة و تلاتين في المية منها الفة واضح الفكرة + +108 +00:10:01,460 --> 00:10:06,660 +طبعا احنا قولنا كلمة و وضحناها المرة الماضية ان ال + +109 +00:10:06,660 --> 00:10:10,860 +beta is more stable than the alpha لان لو رسمنا + +110 +00:10:10,860 --> 00:10:14,920 +الحلقة السوداسية على الشكل اللى عادة بتكون موجودة + +111 +00:10:14,920 --> 00:10:18,420 +فيه و يمكن مار علينا لما أخدنا الحلقات السوداسية + +112 +00:10:18,420 --> 00:10:21,140 +نقطين وجد على شكل both + +113 +00:10:23,360 --> 00:10:27,920 +أو chair which is more stable chair conformation + +114 +00:10:27,920 --> 00:10:31,620 +الان لو حطيتها على هيئة الكرسي في ال chair + +115 +00:10:31,620 --> 00:10:37,480 +conformation ال OH ممكن تكون بشكل أفقي بهذا الشكل + +116 +00:10:37,480 --> 00:10:43,460 +بنقول عنها equatorial equatorial يعني بشكل أفقي + +117 +00:10:43,460 --> 00:10:48,040 +يعني لما نتخيل أنه الشكل العام للحلقات بهذا الشكل + +118 +00:10:48,040 --> 00:10:55,070 +هي بتكون زي هيكهذه equatorial الان ممكن تكون في + +119 +00:10:55,070 --> 00:11:01,830 +شكل تاني axial رأس عمودي هيك equatorial هيك axial + +120 +00:11:01,830 --> 00:11:09,740 +الان بالشكل هذا بتكون ايش؟أكسيال طبعا ال + +121 +00:11:09,740 --> 00:11:13,820 +equatorial الفراغ اللي حواليها أفضل من الفراغ اللي + +122 +00:11:13,820 --> 00:11:18,180 +حواليه الأكسيال الأكسيال crowded لاحظوا فيها + +123 +00:11:18,180 --> 00:11:21,600 +steric hindrance فيها ممانعة فراغية مالهاش واسعة + +124 +00:11:21,600 --> 00:11:26,840 +واضحالـ equatorial مترايحة أكثر ولذلك هذا الشكل ال + +125 +00:11:26,840 --> 00:11:31,200 +equatorial هو ال beta هذا الشكل ال axial هو ال + +126 +00:11:31,200 --> 00:11:35,900 +alpha عشان هيك ال beta بيكون more stable لأن ال OH + +127 +00:11:35,900 --> 00:11:39,820 +اللي موجودة فيه ال new chiral center لأنميرك كربون + +128 +00:11:39,820 --> 00:11:43,860 +بتكون مترايحة من الناحية الفرغية مافيش حد مضايقها + +129 +00:11:43,860 --> 00:11:48,440 +واضح؟ لحظوا هذه ال OH الجديدة اللي اتكونت عندىالان + +130 +00:11:48,440 --> 00:11:52,740 +في ال equatorial form هي مترايحة في ال axial form + +131 +00:11:52,740 --> 00:11:57,160 +مش مترايحة في جنبها مجموعات تانية بتعمل ازدحام + +132 +00:11:57,160 --> 00:12:02,240 +فراغي فلما نكون بدنا نفسر ليش ال beta موجودة اكثر + +133 +00:12:02,240 --> 00:12:08,020 +من ال alpha بنقول because the beta o h is found in + +134 +00:12:08,020 --> 00:12:13,140 +the equatorial position لان موجودة في ال + +135 +00:12:13,140 --> 00:12:16,960 +equatorial ال equatorial is not a crowded position + +136 +00:12:17,870 --> 00:12:24,070 +واضح فسبب الثبات ل ال beta ان ال OH الجديدة هذه + +137 +00:12:24,070 --> 00:12:28,650 +اللي اتكونت عندي هنا لو رسمت الشكل على هيئة الكرسي + +138 +00:12:28,650 --> 00:12:32,330 +بتكون موجودة وين؟ في ال axial ولا في ال + +139 +00:12:32,330 --> 00:12:36,070 +equatorial؟ في ال equatorial ال equatorial is not + +140 +00:12:36,070 --> 00:12:39,350 +a sterically hindered molecule + +141 +00:12:41,870 --> 00:12:44,730 +طبعا الـ mutarotation حكينا عنه برضه المرة + +142 +00:12:44,730 --> 00:12:49,450 +الماضية، قلنا لو بدنا من أي واحد، حيصل لإيش؟ + +143 +00:12:49,450 --> 00:12:50,310 +للإتزان + +144 +00:12:52,690 --> 00:12:57,850 +ال بيرانوز and فيرانوز structures الموضوع بسيط + +145 +00:12:57,850 --> 00:13:02,650 +فيهم انه احنا قلنا السكر اشهر الإغلاقات تبعته اما + +146 +00:13:02,650 --> 00:13:08,630 +على حلقة سداسية او على حلقة خماسية الان في ال + +147 +00:13:08,630 --> 00:13:12,610 +heterocyclic chemistry الحلقة السداسية اللى فيها + +148 +00:13:12,610 --> 00:13:18,190 +ال oxygen بهذا الشكل اسمها بيرينواضح؟ هذه الحلقة + +149 +00:13:18,190 --> 00:13:22,910 +اللي فيها ال oxygen اسمها بيرين والحلقة الخماسية + +150 +00:13:22,910 --> 00:13:28,290 +اللي فيها ال oxygen اسمها إيش؟ فيوران بناء على ذلك + +151 +00:13:28,290 --> 00:13:33,530 +السكر لما بيسكر على حلقة سداسية صاروا ينسبوا لل + +152 +00:13:33,530 --> 00:13:37,290 +بيرين فكل السكريات اللي مسكرة على حلقة سداسية + +153 +00:13:37,290 --> 00:13:42,190 +بيصيروا يقولوا عنها بيرانوزز بيرانوزز يعني مسكر + +154 +00:13:42,190 --> 00:13:46,210 +على حلقة سداسية لما بيشوف بيرين بدي أقول أن الحلقة + +155 +00:13:46,740 --> 00:13:53,340 +لو كان مسكر على حلقة خماسية نسبة إلى الفيوران + +156 +00:13:53,340 --> 00:13:58,360 +الخماسي بقول عنه ايش؟ فيرانوز فبنصير من الآن + +157 +00:13:58,360 --> 00:14:01,700 +نستعمل كلمتين اجداد انه لما نحكي عن الحلقة + +158 +00:14:01,700 --> 00:14:07,020 +السوداسية بنستعمل كلمة بيرانوز فالجولوكوز اللى + +159 +00:14:07,020 --> 00:14:12,620 +مسكر على حلقة سوداسية الآن بيقول عنه جلوكو بيرانوز + +160 +00:14:13,420 --> 00:14:17,300 +معنى Glucopyranose أنه جولوكوز مسكّر على حلقة + +161 +00:14:17,300 --> 00:14:23,400 +سدسية طب لو سكّر على حلقة خماسية Glucofuranose فمن + +162 +00:14:23,400 --> 00:14:28,200 +الآن و طالع هنصير نشوف اسمين Glucopyranose و + +163 +00:14:28,200 --> 00:14:32,320 +Glucofuranose لما نقول لحد إيش يعني Glucopyranose؟ + +164 +00:14:33,530 --> 00:14:40,490 +جولوكوز مسكر على حلقة صداسية إيش معناه؟ جولوكوز + +165 +00:14:40,490 --> 00:14:42,830 +مسكر على حلقة خمسية، جولوكوز مسكر على حلقة خمسية، + +166 +00:14:42,830 --> 00:14:42,870 +جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر على حلقة + +167 +00:14:42,870 --> 00:14:43,730 +خمسية، جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر + +168 +00:14:43,730 --> 00:14:44,790 +على حلقة خمسية، جولوكوز مسكر على حلقة خمسية، + +169 +00:14:44,790 --> 00:14:49,350 +جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر على حلقة + +170 +00:14:49,350 --> 00:14:57,390 +خمسية، جولوكوز مسكر على حلقة خمسية، جولوكوز + +171 +00:14:57,390 --> 00:15:04,480 +مسكر على حلقة خمسية، جولوكوز مسكر على حلقة خممرتبط + +172 +00:15:04,480 --> 00:15:09,620 +فيها اسم Byronose واسم Furanose عشان نعرف هو مسكر + +173 +00:15:09,620 --> 00:15:13,840 +على أي نوع من الحلقات هتبدأوا الآن لما تشوفوا + +174 +00:15:13,840 --> 00:15:19,900 +الأسماء تقرؤوا هذا الكلام لاحظوا مثلا لفراكتوز لو + +175 +00:15:19,900 --> 00:15:25,200 +سكر على حلقة خمسية شو بدي أسميه فراكتوفيرانوز + +176 +00:15:25,200 --> 00:15:29,260 +فيرانوز عفوا فراكتوفيرانوز هي هذا شكل لفراكتوز + +177 +00:15:29,260 --> 00:15:34,340 +لفراكتوز نتذكر أن هو keto sugarالفراكتوز سكر + +178 +00:15:34,340 --> 00:15:38,060 +العناب بتكون السيضة بالبندقوفي ع موقع اتنين هو + +179 +00:15:38,060 --> 00:15:42,060 +كيتون مش الديهايد فلما تيجي هذه ال O H تسكر هنا + +180 +00:15:42,060 --> 00:15:48,580 +وتعمل chiral center هنا يعني تصير ال Ketone هذه O + +181 +00:15:48,580 --> 00:15:55,480 +H يا بده تكون ال O H لفوق يا بده تكون ال O H لتحت + +182 +00:15:55,480 --> 00:16:01,060 +إذا كانت لفوق معنا ذلك أنا بوصفهبيتا وإذا كانت + +183 +00:16:01,060 --> 00:16:07,240 +لاتحت أنا بوصفه ألفة الآن وصفنا كل الكلام وحسب ما + +184 +00:16:07,240 --> 00:16:11,340 +هو اسمه افراكتوز لأنه سكر على حلقة خمسية شو بدي + +185 +00:16:11,340 --> 00:16:16,880 +أقول عنه افراكتو فيورانوسو ال D و ال Alpha فاهمين + +186 +00:16:16,880 --> 00:16:20,940 +هو ال D من ال Stereochemistry لباقي المجموعات + +187 +00:16:20,940 --> 00:16:26,100 +تحديدا للمجموعة اللي قبل الأخيرة، واضح؟ فلما نقرأ + +188 +00:16:26,100 --> 00:16:29,740 +هذه الأسماء ما نستغرب عشان نكون عارفين معنى كل + +189 +00:16:29,740 --> 00:16:33,600 +مفردة بالمفردات يعني لما بتيجوا تقرؤوا اسم Sugar + +190 +00:16:33,600 --> 00:16:41,100 +هتلاقوا حالكوا بتقرؤوا بيتا دي إجلوكو بيرانوسالان + +191 +00:16:41,100 --> 00:16:47,260 +لما نيجي نسأل اي واحدة فيكم ايش يعني بيتا و دي و + +192 +00:16:47,260 --> 00:16:51,400 +جلوكو و بيرانوز كل هذا الكلام معناه اي هذا مركب + +193 +00:16:51,400 --> 00:16:59,320 +مثلا بيتا دي جلوكو بيرانوز البيتا معنا ذلك لما سكر + +194 +00:16:59,320 --> 00:17:06,020 +السكر كانت ال OH لفوق ولا لتحت لفوق ال Dلما نرسم + +195 +00:17:06,020 --> 00:17:11,060 +ال acyclic structure ال O H اللي قبل الأخيرة اللي + +196 +00:17:11,060 --> 00:17:17,680 +هي بتكون على اليمين طبعا لما نعمله بشكل حلقي بتكون + +197 +00:17:17,680 --> 00:17:22,280 +مرسومة بشكل معين ال glucose السكر اللي عندى + +198 +00:17:22,280 --> 00:17:29,460 +جولوكوز بيرانوز نسكر على حلقة سداسية واضح الفكرة؟ + +199 +00:17:30,180 --> 00:17:35,240 +فكل هذه المفردات الحقيقة بتلزمنا الان لو اجينا + +200 +00:17:35,240 --> 00:17:42,600 +بدنا نحكي عن تفاعلات ال sugars الان في المحصلة + +201 +00:17:42,600 --> 00:17:49,840 +السكر ايش هو تعريفه البسيط polyhydroxy + +202 +00:17:49,840 --> 00:17:54,880 +aldehyde او كيتولhydroxy يعني الكهول الديهايد او + +203 +00:17:54,880 --> 00:17:59,040 +كيتون معروف بناء على ذلك لما انا بدي اخد تفاعلات + +204 +00:17:59,040 --> 00:18:04,540 +ال sugars معنى ذلك هي تفاعلات الكحولات وتفاعلات + +205 +00:18:04,540 --> 00:18:10,800 +الكيتونات يا بدي افعله على الكحول يا على ال C + +206 +00:18:10,800 --> 00:18:15,900 +double bond O تبع ال الديهايد او الكيتون خلينا + +207 +00:18:15,900 --> 00:18:22,180 +ناخد مثال لو اخدنا مثلا السكر المسكراللي قلنا عنه + +208 +00:18:22,180 --> 00:18:27,000 +بيتا دي جلوكو بيرانوز وين رسمينه على هيئة الكرسي + +209 +00:18:27,000 --> 00:18:33,300 +هل هذا لما سكر لما صار بيرانوز ضال فيه الديهايد؟ + +210 +00:18:33,780 --> 00:18:38,000 +ولا اتحولت ل New Cairo Center اتحولت ل New Cairo + +211 +00:18:38,000 --> 00:18:43,880 +Center اذا انا اول ما بدي اقرأ اسم Byranose او + +212 +00:18:43,880 --> 00:18:48,160 +اقرأ اسم Furanose لو بدي اخده لوحده بدون الاتزان + +213 +00:18:48,160 --> 00:18:52,380 +مافيش فيه Aldehyde لكن لو بدي اخده ضمن ان هو في + +214 +00:18:52,380 --> 00:18:56,620 +اتزان مع الفاتح الفاتح فيه Aldehyde واضح؟ خلينا + +215 +00:18:56,620 --> 00:19:00,380 +ناخد ال glucobyranose لوحده مجموعة ال aldehyde + +216 +00:19:00,380 --> 00:19:04,090 +اللي كانت فيه سارةأو أتش يعني هنا في أو أتش تنتين + +217 +00:19:04,090 --> 00:19:09,490 +تلاتة أربعة خمسة يعني هذا بدل ما يكون كحول هو + +218 +00:19:09,490 --> 00:19:15,650 +عبارة عن خمس كحولات مش في خمس أو أتش كل أو أتش + +219 +00:19:15,650 --> 00:19:21,810 +عبارة عن كحول الآن لو إجيت قلتلكوا بدي أفاعل كحول + +220 +00:19:21,810 --> 00:19:29,390 +مع unhydrate شو بيعطيني من الكيميا العادية كحول + +221 +00:19:29,390 --> 00:19:30,730 +زاد unhydrate + +222 +00:19:33,300 --> 00:19:37,060 +يعني نجيبلكوا سؤال أكمل الفرق ال reaction of + +223 +00:19:37,060 --> 00:19:43,280 +alcohol with anhydrides produces كلمة واحدة أستر + +224 +00:19:43,280 --> 00:19:50,340 +أستر الناس اللي بيدرسوا بنتبهوا كلمة سهلة جدا لما + +225 +00:19:50,340 --> 00:19:54,580 +أخدنا تفاعل الكحول مع ال acids بيعطينا أستر مع ال + +226 +00:19:54,580 --> 00:19:59,690 +acid chloride بيعطينا أستر مع ال anhydrideبيعطينا + +227 +00:19:59,690 --> 00:20:03,310 +Easter، مظبوط ولا لأ؟ طب لو بدنا نفعل الكحول مع ال + +228 +00:20:03,310 --> 00:20:08,510 +Easter، شو بيعطينا؟ + +229 +00:20:08,510 --> 00:20:15,450 +كحول + +230 +00:20:15,450 --> 00:20:20,330 +مع Easter كحول + +231 +00:20:20,330 --> 00:20:30,950 +مع Easter إيش رأيكوا؟ Easterطبعا ي start تاني من + +232 +00:20:30,950 --> 00:20:34,710 +سير الإنسان بالعملية trans esterification لأن + +233 +00:20:34,710 --> 00:20:41,750 +متابعتك اضعيفة شوية في الموضوع اللي أخدناه سابقا و + +234 +00:20:41,750 --> 00:20:47,210 +اللي احنا محتاجينه مضطر ان اعمل شوية ايش شوية + +235 +00:20:47,210 --> 00:20:48,250 +مراجعة معكم + +236 +00:20:50,980 --> 00:20:59,460 +نعمل شوية المراجعة هى نحط كحول ميثانول كويس و + +237 +00:20:59,460 --> 00:21:01,320 +نعمله بأى لون الميثانول + +238 +00:21:04,970 --> 00:21:11,590 +CH3OH زائد فعلوه مع الاسد ايه صيغة الاسد اي اسد + +239 +00:21:11,590 --> 00:21:17,070 +ناخد ال بنزويك اسد ال بنزويك اسد فنل C double bond + +240 +00:21:17,070 --> 00:21:23,330 +O OH فعلوه مع ال بنزويل كلورايد الاسد كلورايد فنل + +241 +00:21:23,330 --> 00:21:31,340 +C double bond O Cl فعلوه معالبنزويت كان هيدرايد + +242 +00:21:31,340 --> 00:21:38,900 +فانل C double bond O O C double bond O فانل فعلوه + +243 +00:21:38,900 --> 00:21:46,680 +كمان مع الاثل بنزويت فانل C double bond O O اثلهي + +244 +00:21:46,680 --> 00:21:50,860 +الكحول بتفعل مع الحمض أو مع ال acid chloride أو مع + +245 +00:21:50,860 --> 00:21:55,600 +ال acid anhydride أو حتى مع ال E star الألم بده + +246 +00:21:55,600 --> 00:22:01,340 +يعطيني في كل الأحوال هو تفاعل واحد إبدال هذي بده + +247 +00:22:01,340 --> 00:22:09,200 +تخرج ييجي بدالها مثل هذي لين يفعل اللي بده يهاجم و + +248 +00:22:09,200 --> 00:22:16,980 +هذي تخرج هذي بده تخرج هذي بده تخرجو بناء على ذلك + +249 +00:22:16,980 --> 00:22:23,660 +الناتج من كل هدولة هيكون نفس ال Easter اللي هو + +250 +00:22:23,660 --> 00:22:30,220 +Phenyl C double bond O O Methyl بدل المجموعة + +251 +00:22:30,220 --> 00:22:34,440 +المغادرة هذه الآن بعد ذلك أنه هنا بطلع H مع ال OH + +252 +00:22:34,440 --> 00:22:39,340 +زائد ميه زائد HCl زائد Benzoic acid زائد Ethanol + +253 +00:22:39,340 --> 00:22:45,200 +مش مشكلةفتفاعل الكحول مع أي واحد من الأحماض + +254 +00:22:45,200 --> 00:22:50,040 +ومشتقاتها بيعطيني إيه؟ Easter كحول مع أسد، كحول مع + +255 +00:22:50,040 --> 00:22:53,600 +أسد كلورايت، كحول مع أنهايدرايت، كحول مع Easter، + +256 +00:22:53,600 --> 00:22:59,050 +يمكن أنا تقوله يا الله Easter أعطىEaster تاني اه + +257 +00:22:59,050 --> 00:23:04,630 +بس هذا ال Easter كان فنل C double bond O او اثل + +258 +00:23:04,630 --> 00:23:11,370 +صار فنل C double bond O او مثل اذا بدلت ال Easter + +259 +00:23:11,370 --> 00:23:17,010 +ولا لأ عشان هيك بنسميه ال Transesterification ايش + +260 +00:23:17,010 --> 00:23:22,610 +يعني ال Trans تحويل بتعرفوا Trans الكهربا كيف + +261 +00:23:22,610 --> 00:23:27,910 +بيحول بتعرفوا معناه Transformationبتعرفوا كلمة + +262 +00:23:27,910 --> 00:23:33,390 +Transport انه بننجل البني .. اه ف Trans لما + +263 +00:23:33,390 --> 00:23:37,550 +بتيجيكوا في أول الكلام شو معناها؟ تحويل، الآن كان + +264 +00:23:37,550 --> 00:23:42,210 +ال Easter، C double bond O، O-ethyl خلت ال Easter، + +265 +00:23:42,210 --> 00:23:47,930 +C double bond O، O-methyl فالكحول مع Easter بيبدل، + +266 +00:23:47,930 --> 00:23:52,270 +بيعمل Transesterification بدل ما كان O-ethyl صار O + +267 +00:23:52,270 --> 00:23:55,250 +-methyl هذه العملية شو بنسميها اللي هنا؟ + +268 +00:24:02,320 --> 00:24:05,640 +transesterification واضح الفكرة؟ إذا مابدوش + +269 +00:24:05,640 --> 00:24:10,000 +يتغلبوني لما أقولكوا الكحول مع ال acid chloride و + +270 +00:24:10,000 --> 00:24:14,040 +لا مع ال anhydride، شو بده يعطيني؟ شو بده يعطي + +271 +00:24:14,040 --> 00:24:19,880 +الكحول مع ال anhydride؟ إيستر واضح؟ و مع ال + +272 +00:24:19,880 --> 00:24:25,230 +chloride إيستر؟ مع كلهم إيسترو .. الآن إذا الكلام + +273 +00:24:25,230 --> 00:24:31,790 +هذا كله صار واضح عندكم بدي أجي أرجع للسكر السكر + +274 +00:24:31,790 --> 00:24:40,010 +اللي مسكر عبارة عن كحول ال sugar عبارة عن كحول هذا + +275 +00:24:40,010 --> 00:24:45,230 +الكحول لو فعلته مع ال unhydrate شو هيعطيلي Easter + +276 +00:24:45,230 --> 00:24:54,480 +كل OH بده تصيرهذه الـ O H تهاجم هنا O CH3 أعمل + +277 +00:24:54,480 --> 00:25:00,260 +واحدة منهم واضحة O CH3 الآن الـ C double bond O + +278 +00:25:00,260 --> 00:25:05,680 +CH3 شو أخدنا اسمها الـ Acetyl group فالخمسة O H + +279 +00:25:05,680 --> 00:25:10,140 +بيصيروا كلهم O Acetyl طبعا تطلعوا معي هذا Easter + +280 +00:25:10,140 --> 00:25:19,280 +ولا لأ R C double bond O OR Easterفالسكر مع + +281 +00:25:19,280 --> 00:25:24,100 +الانهيدريد بيعطيني Easter طيب لو جبنالكوا السؤال + +282 +00:25:24,100 --> 00:25:26,940 +قولنا لكوا طب لو فعلنا ال sugar مع ال acid + +283 +00:25:26,940 --> 00:25:31,060 +chloride برضه Easter برضه Easter المهم انه في ما + +284 +00:25:31,060 --> 00:25:37,820 +.. طب لو فعلنا مع ال .. مع Easter برضه Easter تاني + +285 +00:25:38,910 --> 00:25:42,570 +نفس المثال اللي هناك هذا الكلام إذا ما بتتدربوش + +286 +00:25:42,570 --> 00:25:47,430 +عليه ما بتتقنوه الخمسة OHS كلهم اللي موجودين + +287 +00:25:47,430 --> 00:25:52,790 +بيصيروا Easter اتنين تلاتة اربعة خمسة فتفاعل ال + +288 +00:25:52,790 --> 00:25:58,070 +sugar مع ال acid unhydrated بيعطيني Easter خلصنا + +289 +00:25:58,070 --> 00:26:04,170 +من هذه النقطة؟ كويس لاحظوا كده بتفيدني الكيميا + +290 +00:26:04,170 --> 00:26:10,900 +العاديةوهي مقدمة ايش؟ ال biochemistry يعني مش ممكن + +291 +00:26:10,900 --> 00:26:14,100 +حد يجي يدرس biochemistry و نشرحله هذا التفاعل هو + +292 +00:26:14,100 --> 00:26:17,500 +مش عارف الكحول و ال anhydride و الaster و كيف + +293 +00:26:17,500 --> 00:26:21,500 +بتفاعلوا مع بعض و مع البعض فكل تفاعل بمر معنها + +294 +00:26:21,500 --> 00:26:27,930 +عشان تفهمه بسهولة لازم يكون المخ يرجع وين؟للـ + +295 +00:26:27,930 --> 00:26:31,630 +Organic Chemistry العادية اللي استعلمته فيها هو + +296 +00:26:31,630 --> 00:26:35,910 +اللي بيرجع يمر علينا هنا يعني لو مثلا أخدنا هذا + +297 +00:26:35,910 --> 00:26:49,170 +التفاعل R O H زائد CH3I هاي التفاعل العادي Alkyl + +298 +00:26:49,170 --> 00:26:49,790 +Halide + +299 +00:26:52,600 --> 00:26:55,880 +النيوكليوفايل ايش بيعمل النيوكليوفايل بالالكي + +300 +00:26:55,880 --> 00:27:04,160 +الهيلايد؟ هذا الشبطر ايش؟ ستة بيهاجر، بيحل محل و + +301 +00:27:04,160 --> 00:27:08,460 +النيوترال نيوكليوفايل اللي بيفقد؟ H إذا هنا إيش + +302 +00:27:08,460 --> 00:27:16,980 +بده يصير عندكم؟ R O CH3 إذا كحول مع الالكي + +303 +00:27:16,980 --> 00:27:19,500 +الهيلايد، شو بيعطيني؟ إيثر + +304 +00:27:22,220 --> 00:27:30,660 +ROR Ether الآن ال sugar عبارة عن كحول ولا خمس + +305 +00:27:30,660 --> 00:27:34,940 +كحولات في بعض؟ خمس كحولات فعلوه مع المثل Iodide + +306 +00:27:35,670 --> 00:27:41,650 +هيعطيني كم إيثر؟ خمس إيثرات مثل او كاربون مثل او + +307 +00:27:41,650 --> 00:27:45,070 +كاربون مثل او كاربون مثل او كاربون مثل او كاربون + +308 +00:27:45,070 --> 00:27:49,570 +واضح الفكرة؟ هو نفس هذا التفاعل البسيط أن الكحول + +309 +00:27:49,570 --> 00:27:55,450 +بيحل محل اليود ولذلك ملخص هدول التنتين أن الكحول + +310 +00:27:55,450 --> 00:28:00,950 +مع الانهيدريد بيعطيني إيثر للشجر والكحول مع ال مثل + +311 +00:28:00,950 --> 00:28:07,890 +أيودايد بيعطيني إيثرلل sugar و طالما انه موجود من + +312 +00:28:07,890 --> 00:28:12,230 +الكحول خمس مجموعات اذا كم Easter و كم Ether هيتكون + +313 +00:28:12,230 --> 00:28:20,020 +عندى اذا بعد ما أخدنا تفاعلالشجر بصفته alcohol مع + +314 +00:28:20,020 --> 00:28:23,620 +ال unhydrate قولنا بيعطي ether مع ال alkyl halide + +315 +00:28:23,620 --> 00:28:27,800 +زي ال methyl iodide قولنا بيعطي ether بدنا ناخد + +316 +00:28:27,800 --> 00:28:33,380 +تفاعل تاني للشجر أيضا مر علينا هذا التفاعل لو + +317 +00:28:33,380 --> 00:28:38,500 +أجينا بدنا نعمل reduction للشجر هنحتاج جملة من + +318 +00:28:38,500 --> 00:28:43,420 +الكيميا القديمة نقول reduction of aldehyde + +319 +00:28:43,420 --> 00:28:49,910 +produces ايشprimary الكوكبوس تمام هتقول هو ال + +320 +00:28:49,910 --> 00:28:55,390 +sugar ال dehyde احنا بنقول ال sugar موجود أساسا + +321 +00:28:55,390 --> 00:29:03,790 +بشكل acyclic او بشكل cyclic و بينهم اتزان ان هو + +322 +00:29:03,790 --> 00:29:08,390 +اللي موجود بنسبة أكبر ال cyclic ولا ال acyclic ال + +323 +00:29:08,390 --> 00:29:13,310 +cyclic هذا موجود بنسبة قليلة جدا قولنا بنسبة ايش + +324 +00:29:13,310 --> 00:29:19,430 +تلاتة بال ألفنسبة قليلة جدا المهم هذا الشكل في + +325 +00:29:19,430 --> 00:29:23,390 +الديهيد لو جيت اعمله reduction بالهيدروجين في وجود + +326 +00:29:23,390 --> 00:29:28,130 +كتاليست ال الديهيد شو بده يصير ال primary alcohol + +327 +00:29:28,130 --> 00:29:34,270 +طبعا الان بيصير السؤال reduction of sugars + +328 +00:29:34,270 --> 00:29:38,650 +produces primary alcohol طبعا طالما كل هدولة أساسا + +329 +00:29:38,650 --> 00:29:44,940 +OH كان في الديهيد واحدة وصارت OHصار Polyhydroxy + +330 +00:29:44,940 --> 00:29:49,740 +Alcohol اللي هو مار عليكم الـ Sorbitol اللي فيه ست + +331 +00:29:49,740 --> 00:29:54,060 +مجموعات OH بطل في ال الديهيد هو كان خمسة OH و + +332 +00:29:54,060 --> 00:29:55,840 +واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال + +333 +00:29:55,840 --> 00:29:56,120 +الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و + +334 +00:29:56,120 --> 00:29:57,620 +واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال + +335 +00:29:57,620 --> 00:29:57,880 +الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و + +336 +00:29:57,880 --> 00:29:59,140 +واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال + +337 +00:29:59,140 --> 00:30:01,540 +الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و + +338 +00:30:01,540 --> 00:30:05,260 +واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال + +339 +00:30:05,260 --> 00:30:11,460 +الديهيد و واحدة ال الديهيد و واحدة ال ال + +340 +00:30:13,000 --> 00:30:19,980 +أمنا و اتحول و أصار الكهول طب و اللي ضايل هنا إيش + +341 +00:30:19,980 --> 00:30:20,680 +رأيكوا فيه؟ + +342 +00:30:24,980 --> 00:30:29,960 +كل ما هذا جزء منه صار alcohol بعوضه جزء من هذا + +343 +00:30:29,960 --> 00:30:34,760 +بيعمل ring opening في نهاية التفاعل ايش بتتوقعوا + +344 +00:30:34,760 --> 00:30:40,960 +نشوف ان هذا كله هينتهي يعني كل ما هذا بتحول بيروح + +345 +00:30:40,960 --> 00:30:45,780 +المسكر بيفتح كل ما هذا بتحول المسكر بيفتح هذه + +346 +00:30:45,780 --> 00:30:50,200 +القاعدة في الاتزان من اذكرنا ايش اسمها مرت عليكم + +347 +00:30:52,610 --> 00:30:56,330 +إعادة الإتزان، إنه الإتزان يعود إلى وضعه الطبيعي، + +348 +00:30:56,330 --> 00:31:01,290 +يعني دول الاتنين في اتزان، سحبنا هذا، فعلناه، + +349 +00:31:01,290 --> 00:31:04,710 +بيرود هذا يعمل اتزان من أول لجديد، سحبنا هذا، + +350 +00:31:04,710 --> 00:31:11,850 +بيرود هذا يفتح، لتشكله principalواضح؟ وبناء على + +351 +00:31:11,850 --> 00:31:17,210 +ذلك لو احنا جيبنالكوا سؤال في الامتحان قولنا هذا و + +352 +00:31:17,210 --> 00:31:22,150 +هذا في حالة اتزان اكملوا المعادلة هتكملونهان طيب + +353 +00:31:22,150 --> 00:31:26,930 +يا ترى لو اجينا سألناكوا ماحطيناش هذا من الأساس + +354 +00:31:26,930 --> 00:31:32,710 +كتبنالكوا بس هذا و reduction ايش هتعملونه؟ هتقولوا + +355 +00:31:32,710 --> 00:31:39,630 +مفهوم ضمنهإن هذا متزل مع الفاتح وبناء على ذلك + +356 +00:31:39,630 --> 00:31:43,710 +سيعمل reduction ويعطي هذا يعني لو رسمت أنا بس هذا + +357 +00:31:43,710 --> 00:31:49,070 +وقلت لكم H2و Catalyst في نهاية هذه الجوابلكن للفهم + +358 +00:31:49,070 --> 00:31:53,250 +كيف هذا الكلام بيصير بيقول ال .. ال cyclic صار إيه + +359 +00:31:53,250 --> 00:31:57,350 +ال cyclic؟ وصار إله reduction وكل ما هذا صار إله + +360 +00:31:57,350 --> 00:32:02,450 +reduction كل ما ال cyclic من أول و جديد بيفتح إلى + +361 +00:32:02,450 --> 00:32:08,840 +أن يتحول كل ال cyclic اللي موجود هنا إلىالى الكحول + +362 +00:32:08,840 --> 00:32:13,320 +اللى هو sorbitol واضح؟ لاحظوا معنا احنا الان + +363 +00:32:13,320 --> 00:32:20,360 +استفدنا من ايش؟ من مجموعة ال aldehyde الناس + +364 +00:32:20,360 --> 00:32:24,280 +اللى متذكرين كويس معنا لما شرحنا ال aldehyde قولنا + +365 +00:32:24,280 --> 00:32:28,180 +ال aldehyde واقف على نص السلم ايش يعني ال aldehyde + +366 +00:32:28,180 --> 00:32:34,900 +واقف على نص السلم او في نص الطريقالديهايد ممكن + +367 +00:32:34,900 --> 00:32:42,320 +تنزل لالكهول زي ما عملت هنا بال reduction و بنفس + +368 +00:32:42,320 --> 00:32:52,120 +الوقت ممكن تطلع فوق ل acid بال oxidation واضح؟ + +369 +00:32:52,120 --> 00:32:58,320 +ماشي الترتيب اللي عندى ال alcohol الديهايد + +370 +00:32:59,060 --> 00:33:06,000 +acid أكسدة الكحول تعطي الديهايد أكسدة الديهايد + +371 +00:33:06,000 --> 00:33:11,020 +تعطي acid اختزال الكحول بيصير alcohol اختزال + +372 +00:33:11,020 --> 00:33:15,520 +الديهايد بيصير alcohol أكسدة الديهايد بيصير acid + +373 +00:33:15,520 --> 00:33:19,820 +الآن احنا التفاعل اللي موجود عندنا اختزال الديهايد + +374 +00:33:19,820 --> 00:33:25,990 +رجع لإيش؟ لالكحول طب لو عملنا أكسدة للديهايدهيصير + +375 +00:33:25,990 --> 00:33:30,990 +acid واضح الفكرة المشكلة في الموضوع كالقاتل انه + +376 +00:33:30,990 --> 00:33:35,470 +احنا قولنا اكسدة ال الديهيد بال oxidation بيصير + +377 +00:33:35,470 --> 00:33:40,150 +acid و اكسدة الكحول بعمل مؤكسد قوي برضه بيصير ايش + +378 +00:33:40,150 --> 00:33:44,410 +acid متذكرين لما أخدنا oxidation و في primary + +379 +00:33:44,410 --> 00:33:50,330 +alcohol حسب نوع المؤكسد تمام طيب هذا ال sugar ايش + +380 +00:33:50,330 --> 00:33:57,020 +موجود فيه في الديهيدو في كحولات بالذات ال primary + +381 +00:33:57,020 --> 00:34:01,540 +alcohol بناء على ذلك هتلاحظوا لما نيجي ندرس ال + +382 +00:34:01,540 --> 00:34:05,900 +acid ده انه هيمروا معناه حالتين ممكن عامل مؤكسد + +383 +00:34:05,900 --> 00:34:10,560 +نستعمله فقط acid ال aldehyde ل acid يعني يصير عندى + +384 +00:34:10,560 --> 00:34:15,240 +على الطرف هذا ايش acid عامل مؤكسد تاني اقوى منه ب + +385 +00:34:15,240 --> 00:34:19,400 +acid ال aldehyde و ب acid ال primary alcohol بيصير + +386 +00:34:19,400 --> 00:34:23,780 +عندى ايش dye acid انشوف هذا الكلام + +387 +00:34:26,870 --> 00:34:31,270 +لو أخدنا Sugar مع عامل مؤكسد خلّينا نقول ضعيف + +388 +00:34:31,270 --> 00:34:36,330 +لبرومين ميّه أو فضّه مع انحاس خلّينا نركز برومين + +389 +00:34:36,330 --> 00:34:41,670 +ووتر ب أكسد ال الديهايد بدل ما هو CHO بصير سيضه + +390 +00:34:41,670 --> 00:34:46,490 +بالموند OOH صار أسد، إذا لبرومين ووتر كام أكسدة + +391 +00:34:46,490 --> 00:34:51,010 +عمل عندى؟ أكسدة واحدة، بس أكسد ال الديهايد خلّاه + +392 +00:34:51,010 --> 00:34:55,250 +أيش أسد؟ الآن وقت الديجلوكوز بنقول عنه بصير + +393 +00:34:55,250 --> 00:35:00,030 +gluconic acidفال gluconic acid يحتوي على كام + +394 +00:35:00,030 --> 00:35:05,630 +مجموعة حمضية؟ واحدة عشانك لو انا اجيت سألتكم + +395 +00:35:05,630 --> 00:35:12,150 +gluconic acids contain one ولا two acidic groups؟ + +396 +00:35:12,150 --> 00:35:20,130 +oneone الان نفس هذا المركب لو جبتله عامل مؤكسد قوي + +397 +00:35:20,130 --> 00:35:25,890 +أقوى من هذا بيروح ب أكسد الألديهيد والألكوهول وجدت + +398 +00:35:25,890 --> 00:35:32,790 +بده يعطيني كام أسد اتنين بيصير اتنين هذه الأكسدات + +399 +00:35:32,790 --> 00:35:36,730 +اللي بتصير الان ايش العامل المؤكسد الأقوى ال + +400 +00:35:36,730 --> 00:35:41,170 +nitric acid الألديهيد بيصير أسد وال primary + +401 +00:35:41,170 --> 00:35:47,740 +alcohol بتصير أسدصار عنده ايش؟ داي أسد وجدتها الدي + +402 +00:35:47,740 --> 00:35:53,080 +جلوكوز بيصير دي جلوكارك أسد لاحظوا الأول ايش كان + +403 +00:35:53,080 --> 00:35:58,580 +اسمه؟ جلوكونك جلوكونك يعني في one acidic group + +404 +00:35:58,580 --> 00:36:05,540 +جلوكارك يعني في two acidic groups أكسدنا في جزء ال + +405 +00:36:05,540 --> 00:36:10,950 +الديهايد وأكسدنا في جزء الكحولفبناء على العامل + +406 +00:36:10,950 --> 00:36:15,990 +المؤكسد ممكن نعمل أكسدة لجزء واحد بيصير عنده + +407 +00:36:15,990 --> 00:36:20,010 +glucanic acid اللي بأكسد جزء واحد هو ال bromine + +408 +00:36:20,010 --> 00:36:26,410 +water إذا استعملت نيترك أسد بأكسد ال aldehyde و + +409 +00:36:26,410 --> 00:36:31,550 +بأكسد ال primary alcohol بيصير عنده داي أسد + +410 +00:36:35,990 --> 00:36:41,490 +لأ في التجربة هي اللي بتأكسده واضح؟ هدول هو نظريا + +411 +00:36:41,490 --> 00:36:45,370 +لو بدى تأكسد حصير كيتون لأنه secondary alcohol بس + +412 +00:36:45,370 --> 00:36:50,550 +بالتجربة هدول اللي بتأكسده أخر + +413 +00:36:50,550 --> 00:36:59,330 +تفاعل ممكن امر علينا لو فعلناهذا الكحول تحديدا مع + +414 +00:36:59,330 --> 00:37:05,190 +.. أو هذا ال sugar عفوا Beta D-Glucobiranose مع + +415 +00:37:05,190 --> 00:37:10,210 +الميثانولاحنا فعلنا مع ال acid anhydride أعطانا + +416 +00:37:10,210 --> 00:37:14,470 +ester فعلنا مع ال acid halide أعطانا ether فعلنا + +417 +00:37:14,470 --> 00:37:17,830 +مع ال bromine أعطانا acid واحد فعلنا مع ال nitric + +418 +00:37:17,830 --> 00:37:22,370 +acid أعطانا two acids لو فعلنا مع الكحول في وجود + +419 +00:37:22,370 --> 00:37:27,830 +الميه شو بيعمل؟ بيشيل واحدة من ال OHS بنتقيها + +420 +00:37:27,830 --> 00:37:31,610 +انتقاءطبعا في ميكانيزم تفسر على الكلام لكن مش + +421 +00:37:31,610 --> 00:37:35,390 +موضوعنا و بيحل محلها ال o-methyl يعني بيشيل ال OH + +422 +00:37:35,390 --> 00:37:40,090 +و بيحط مكانها ايش o-methyl الان اي OH اللي بدو + +423 +00:37:40,090 --> 00:37:43,770 +يشيلها ال OH الجديدة اللي ع ال anomeric carbon + +424 +00:37:43,770 --> 00:37:47,110 +متذاكرين هذه اللي كانت مش chiral سمنها anomeric + +425 +00:37:47,110 --> 00:37:51,530 +carbon فالتفاعل مع الكحول زي ال methanol بيشيل هذه + +426 +00:37:51,530 --> 00:37:57,970 +ال OH بيشيل هذه ال OH و بيحط بدالها ايش o-methyl + +427 +00:37:58,410 --> 00:38:01,650 +طبعا هل يا ترى بيحط ال O مثل على ال Alpha ولا على + +428 +00:38:01,650 --> 00:38:05,370 +ال Beta؟ هيعمل خليط .. هيعمل خليط من الاتنين، احنا + +429 +00:38:05,370 --> 00:38:09,170 +راسمين واحد منهم واضح بيحطوا على ال Alpha و ال + +430 +00:38:09,170 --> 00:38:13,410 +Beta لما تكون ال O مثل ال A4، هذا Beta، لو كانت + +431 +00:38:13,410 --> 00:38:19,070 +لتحت Alpha الآن هذه المركبات اللي بدل ما كانت ال + +432 +00:38:19,070 --> 00:38:25,110 +Oxygen على ال Anomeric Carbon OH صارت OR بنسميها + +433 +00:38:25,110 --> 00:38:31,310 +احنا ايش؟ Glycosidesفلو إجينا سألنا شو هم ال + +434 +00:38:31,310 --> 00:38:37,230 +glycosides؟ ال glycosides هم السكريات اللي قبدلت + +435 +00:38:37,230 --> 00:38:45,850 +فيهم ال OH صارت OR واضح؟بدل ما كانت او متصلة ب اتش + +436 +00:38:45,850 --> 00:38:52,390 +صارت او متصلة بار بنسميهم glycosides طبعا في أمثلة + +437 +00:38:52,390 --> 00:38:55,930 +هتمروا معاكم بعدين في أماكن تانية أنه يا تورا لو + +438 +00:38:55,930 --> 00:39:01,690 +حطينا هنا ال متصلة باربنصير نقول عنها + +439 +00:39:01,690 --> 00:39:06,150 +anoglycosides يعني غلايكو سايتس بس من خلال ذرة إيش + +440 +00:39:06,150 --> 00:39:11,130 +نيتروجين بس إذا قولنا كلمة غلايكو سايتس عادية معنى + +441 +00:39:11,130 --> 00:39:15,750 +ذلك أنا بدي سكر و مرسوم عليه على هذا الموقع تحديدا + +442 +00:39:15,750 --> 00:39:20,670 +OR لاحظوا أن التفاعل مع الميثانول ما بيغير هدول ال + +443 +00:39:20,670 --> 00:39:26,420 +OHSفقط بيغير ال OH اللي ع ال anomeric carbon + +444 +00:39:26,420 --> 00:39:31,220 +بيخليها ايش OR والمركبات اللي فيها OR ع ال + +445 +00:39:31,220 --> 00:39:36,080 +anomeric carbon بنقول عنها glycosides هذه الرابطة + +446 +00:39:36,080 --> 00:39:38,720 +اللي بين ال anomeric carbon و ال oxygen اللي هي + +447 +00:39:38,720 --> 00:39:43,760 +carbon O مثل او carbon OR بنسميها glycosidic bond + +448 +00:39:43,760 --> 00:39:49,740 +هذه الرابطة الجديدة اللي كانت متصلةمع ال OH صارت + +449 +00:39:49,740 --> 00:39:55,840 +متصلة مع ايش؟ مع ال OR شو بنسميها؟ Glycosidic bond + +450 +00:39:55,840 --> 00:40:03,080 +موجودة ويلها أهمية جزء كبير من أهمية هذه المنطقة + +451 +00:40:03,080 --> 00:40:07,660 +أنه لما بعدك السكريات بدهم يبدوا يعملوا dimers مع + +452 +00:40:07,660 --> 00:40:11,560 +بعض يتحدوا هنلاحظ فائدة هذه ال glycosidic bond + +453 +00:40:11,560 --> 00:40:15,000 +لأنه بربطوا من خلالها واضح؟ يربطوا مع بعض من + +454 +00:40:15,000 --> 00:40:22,700 +خلالهالو اجينا رسمنالكم مركب هذا sugar من + +455 +00:40:22,700 --> 00:40:27,900 +الجولوكوز هل هذا يا تورا فيه glycosidic bond ولا + +456 +00:40:27,900 --> 00:40:38,380 +لأ تطلع عليه هاي carbon اوCarbon اذا هذا المركب + +457 +00:40:38,380 --> 00:40:43,600 +اللى اسمه ساليسين من شجر الصفصاف لما كانوا بيغلو + +458 +00:40:43,600 --> 00:40:47,140 +شجر الصفصاف بيطلع هذا المركب كانوا ياخدوله الصداع + +459 +00:40:47,140 --> 00:40:52,440 +الناس الزمان فيه glycosidic bond لاحظوا اللى + +460 +00:40:52,440 --> 00:40:58,900 +بتتأمل فيه بشكل بشكل قوى هتلاحظ ان هذا بيشبه ايش + +461 +00:40:58,900 --> 00:41:02,040 +الاسميرين + +462 +00:41:03,920 --> 00:41:10,960 +تذكروا الاسبيرين كان بنزينة و COOH و CH2O و بعدين + +463 +00:41:10,960 --> 00:41:15,500 +أوهانة OH نخليها OCOC double bond Oacetyl يعني + +464 +00:41:15,500 --> 00:41:20,020 +وجود البنزينة و ال orthoposition هذا بشبه أي دوة؟ + +465 +00:41:20,020 --> 00:41:25,580 +بشبه الاسبيرين هذا مثلا منتج طبيعي فيه glycosidic + +466 +00:41:25,580 --> 00:41:30,170 +bond ولا لأ؟ هيهالما تكون هذه الرابطة اللي هنا مش + +467 +00:41:30,170 --> 00:41:36,350 +OH OR بنقول هذا إيش المركب glycoside و ال bond إيش + +468 +00:41:36,350 --> 00:41:43,650 +بنوصفها؟ بنقول عنها glycosidic bond الآن زي ما + +469 +00:41:43,650 --> 00:41:48,330 +اتفقنا أن ال glycosides وين بيفيدوني كتير أنا؟لما + +470 +00:41:48,330 --> 00:41:53,550 +بدى ادمج سكارين مع بعض لما بدى ادمج سكارين مع بعض + +471 +00:41:53,550 --> 00:41:57,390 +هاجي على هذه ال oxygen و اصير اربط من خلالها الان + +472 +00:41:57,390 --> 00:42:01,410 +دمج سكارين مع بعض قصة طويلة اش السكارين و اش + +473 +00:42:01,410 --> 00:42:06,370 +السكارتونة اللى بده يطلع عندى هو ملتوز سكاروز سيلو + +474 +00:42:06,370 --> 00:42:11,490 +بيوز كذا كذا موضوع كبير بحاجة الى ان نفردله ان شاء + +475 +00:42:11,490 --> 00:42:17,580 +الله محاضرة كاملة بس لاحظوا مباشرةهتلاحظوا أنه أول + +476 +00:42:17,580 --> 00:42:22,580 +ما بدي أحكي عن سكارين دمجتهم هاي رابط هانا تطلعوا + +477 +00:42:22,580 --> 00:42:27,980 +عليها carbon او carbon ال glycosidic bond ولا لأ + +478 +00:42:27,980 --> 00:42:33,520 +عشانك احنا أخدنا ال glycosides لأنه في ال + +479 +00:42:33,520 --> 00:42:37,620 +disaccharides هتلاقوا عندي ال glycosidic bond طبعا + +480 +00:42:37,620 --> 00:42:41,760 +إيش السكارين اللي بيندمجوا و إيش السكر ثناء اللي + +481 +00:42:41,760 --> 00:42:46,920 +بيطلع هذا بيكون موضوعالمحاضرة القادمة ان شاء الله + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..116e4d974f39798aa5fe6c580fd38cdfc58ca610 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E_postprocess.srt @@ -0,0 +1,1844 @@ +1 +00:00:20,790 --> 00:00:24,970 +بسم الله الرحمن الرحيم اليوم ان شاء الله في + +2 +00:00:24,970 --> 00:00:30,390 +المحاضرة الأخيرة بدنا نحاول نراجع بعض الامتحانات + +3 +00:00:30,390 --> 00:00:35,430 +نشوف كيف بتيجي الصورة الكلية في الامتحانات على هذه + +4 +00:00:35,430 --> 00:00:39,630 +المادة في عندنا هذا الامتحان هذا الامتحان كان في + +5 +00:00:39,630 --> 00:00:45,330 +الفصل الأول الماضي لطلاب السنة الأولى في كلية الطب + +6 +00:00:45,910 --> 00:00:50,190 +نحاول مع بعض نمر عليه، بنلاحظ أن الأسئلة طبعا + +7 +00:00:50,190 --> 00:00:55,750 +منوعة، في أسئلة صح و غلط، أكمل الفراغ، سم المركب، + +8 +00:00:55,750 --> 00:01:01,760 +كيف تحضر مركب، أكمل المعادلة، كل هذه الأشياءنشوف + +9 +00:01:01,760 --> 00:01:07,800 +الأشياء بالترتيب في أسئلة الصح والغلط بيسألنا سؤال + +10 +00:01:07,800 --> 00:01:13,160 +بيقولنا الـpeptide لجليسين ألانين ألانين و + +11 +00:01:13,160 --> 00:01:16,380 +الـpeptide ألانين جليسين جليسين are structural + +12 +00:01:16,380 --> 00:01:20,920 +isomers ايش رأيكم؟ they are not isomers لأن ال + +13 +00:01:20,920 --> 00:01:26,140 +isomers لازم يكونوا مكونين من نفس الأشياء يعني هذا + +14 +00:01:26,140 --> 00:01:29,120 +اتنين ألانين واحد جليسين هذا اتنين جليسين واحد + +15 +00:01:29,120 --> 00:01:32,700 +ألانين they are not isomersthey are different + +16 +00:01:32,700 --> 00:01:43,140 +compounds a glucofuranose is an aldobentose واضح؟ + +17 +00:01:43,140 --> 00:01:49,340 +إيش رأيكم؟ + +18 +00:01:49,340 --> 00:01:54,760 +الفيورانوز خمسة + +19 +00:01:54,760 --> 00:02:01,200 +لكن الجلوكوز ستة الجلوكوز + +20 +00:02:04,860 --> 00:02:11,080 +لأ لما نقول جولوكوز، الجولوكوز مر علينا وين؟ في + +21 +00:02:11,080 --> 00:02:16,500 +الالدوهيكسوزز؟ + +22 +00:02:16,500 --> 00:02:17,700 +لأ هذا world + +23 +00:02:29,910 --> 00:02:36,410 +الجلوكوز نفسه ست كربونات ولا خمسة؟ ستة، الان لما + +24 +00:02:36,410 --> 00:02:41,470 +أنا هنا بقول خمسة، إذا هذا الكلام صح ولا غلط؟ غلط، + +25 +00:02:41,470 --> 00:02:46,810 +لأنه الجلوكوز ستة مش خمسة، واضحة الفكرة؟ الجلوكوز + +26 +00:02:46,810 --> 00:02:50,910 +ستة دلات كربون، مش خمسة The peptide bond is longer + +27 +00:02:50,910 --> 00:02:57,830 +than normal C double bond N أو C N double bond، + +28 +00:02:57,830 --> 00:03:03,110 +إيش رأيكوا؟هل الـpeptide أطول من الـC double bond + +29 +00:03:03,110 --> 00:03:06,190 +N؟ طبعا انتوا بتكونوا تتذكروا ان الـamide bond + +30 +00:03:06,190 --> 00:03:11,990 +الـamide bond اللي هي الـCN كأنها رابط و نص مع + +31 +00:03:11,990 --> 00:03:15,850 +الـresonance ليش؟ لأنه انا في الـamide bond عندي C + +32 +00:03:15,850 --> 00:03:20,590 +double bond ON هذه single bond في الوضع الطبيعي + +33 +00:03:20,590 --> 00:03:27,510 +الآن لو صارت هنا C double bond N وهنا الـO minus + +34 +00:03:27,510 --> 00:03:28,530 +صارت + +35 +00:03:30,900 --> 00:03:35,480 +Double bond فهل ال peptide او الأمد double ولا + +36 +00:03:35,480 --> 00:03:42,220 +single؟ لأ هي واحد و نص في النهايةمش احنا حكينا في + +37 +00:03:42,220 --> 00:03:46,880 +عندنا امد resonance الامد بيعمل resonance معنى + +38 +00:03:46,880 --> 00:03:51,580 +resonance هذه اللي بتكون مرة double single bond في + +39 +00:03:51,580 --> 00:03:54,800 +المرة التانية شو بتكون double bond شو متوسط ال + +40 +00:03:54,800 --> 00:03:58,640 +double و ال single واحد و نص الان الواحد و نص + +41 +00:03:58,640 --> 00:04:03,600 +كرابطة الواحد و نص كرابطة مقارنة بالواحد ايه اطول + +42 +00:04:03,600 --> 00:04:09,920 +رابطةالواحد ال single الأقصر ال double ال and ال + +43 +00:04:09,920 --> 00:04:16,160 +واحد و نص بينهم فهي أقصر من ال single و أطول من ال + +44 +00:04:16,160 --> 00:04:21,140 +double واضح ال رابطة لما تكون ب resonance يعني + +45 +00:04:21,140 --> 00:04:24,240 +كأنها واحد و نص هي أقصر من ال single bond و أطول + +46 +00:04:24,240 --> 00:04:29,460 +من ال double bond احنا ايش كاتبين is longer than c + +47 +00:04:29,460 --> 00:04:35,250 +double bond and اذا هذه الجملة صحواضح الفكرة؟ هذه + +48 +00:04:35,250 --> 00:04:38,630 +بتعتمد على فهمكم للأمد resonance .. بتعتمد على + +49 +00:04:38,630 --> 00:04:42,130 +فهمكم للأمد resonance Hydrolysis of starch + +50 +00:04:42,130 --> 00:04:49,350 +produces only beta-glucopyranosis ال starch من أي + +51 +00:04:49,350 --> 00:04:53,110 +سكة؟ + +52 +00:04:53,110 --> 00:05:00,710 +من؟ كويس من أي ديساكراي؟ ملتوز .. الملتوز من إيش؟ + +53 +00:05:02,010 --> 00:05:08,890 +أي جولوكوز ألف وأو بيتا ألف وأو بيتا الأن هنا إيش + +54 +00:05:08,890 --> 00:05:16,130 +كاتبين إحنا only بيتا لأن الملتوز ألف وأو بيتا + +55 +00:05:16,130 --> 00:05:19,950 +ملتوز ألف وأو بيتا the OH of the anomeric carbon + +56 +00:05:19,950 --> 00:05:23,690 +of beta-glucobyranose is found in the equatorial + +57 +00:05:23,690 --> 00:05:29,870 +position هذه أخدناها صحيحة + +58 +00:05:31,370 --> 00:05:36,890 +مشقولنا انه ليش بيكون ال beta نسبته اعلى من ال + +59 +00:05:36,890 --> 00:05:40,270 +alpha لأنه ال beta في ال equatorial position مافيش + +60 +00:05:40,270 --> 00:05:45,650 +عليها steric hindrance داي تيربين are composed of + +61 +00:05:45,650 --> 00:05:52,710 +twenty carbon atoms الان ال mono terbin اكم ايزو + +62 +00:05:52,710 --> 00:05:57,110 +برين unit تنتين الداي تيربين اكم ايزو برين unit + +63 +00:05:57,110 --> 00:05:58,910 +اربع اربع في خمسة + +64 +00:06:02,460 --> 00:06:09,860 +hydrogenation of oils is a saponification reaction + +65 +00:06:09,860 --> 00:06:12,880 +هدرجة + +66 +00:06:12,880 --> 00:06:18,280 +الزيوت بتحول ال double bond إلى single bond بتحول + +67 +00:06:18,280 --> 00:06:22,820 +ال oil إلى fat ال saponification reaction بيعمل + +68 +00:06:22,820 --> 00:06:29,770 +hydrolysis فهدرجة الزيوت مش تفاعلسابونفكاشن + +69 +00:06:29,770 --> 00:06:34,250 +السابونفكاشن ان اخد الـ triglyceride احوله الى + +70 +00:06:34,250 --> 00:06:41,190 +soap الى salt of the fatty acid واضح ان احول الزيت + +71 +00:06:41,190 --> 00:06:45,690 +الى سابون ان اعمل hydrolysis الان هل ال + +72 +00:06:45,690 --> 00:06:48,970 +hydrogenation عمل hydrolysis ولا تحويل double bond + +73 +00:06:48,970 --> 00:06:52,610 +ل single bond اه اذا ال hydrogenation is + +74 +00:06:52,610 --> 00:06:58,270 +سابونفكاشن reaction غلطالهيدروجينيشن تحويل بابل + +75 +00:06:58,270 --> 00:07:03,710 +بوند لسينجل بوند مش تحويل إيستر لملح The polar R + +76 +00:07:03,710 --> 00:07:08,990 +groups in hair proteins طبعا ال hair fibrous + +77 +00:07:08,990 --> 00:07:15,750 +protein are located outside الفيبرس + +78 +00:07:15,750 --> 00:07:22,450 +وين موجودة ال R groups تبعتهم؟جوا مش برا ال fibers + +79 +00:07:22,450 --> 00:07:27,350 +ال proteins ال R groups تبعتهم موجودة للداخل ولذلك + +80 +00:07:27,350 --> 00:07:34,390 +هذه الجملة غلط واضح الان complete the following + +81 +00:07:34,390 --> 00:07:38,450 +statements نرفع شوية + +82 +00:07:45,750 --> 00:07:49,630 +الدياستيريوم الذين يختلفون فقط في مركز واحد كيرال + +83 +00:07:49,630 --> 00:08:02,610 +يسمون ابيمارز ابيمارز اسم الكيميائي لاسبيرين اسيتل + +84 +00:08:02,610 --> 00:08:07,130 +ساليسينك + +85 +00:08:07,130 --> 00:08:12,830 +أسد باراسيتامول + +86 +00:08:12,830 --> 00:08:14,170 +أيضا يسمون + +87 +00:08:18,000 --> 00:08:24,020 +اسيتامينوفين متذاكرين هالكلام؟ اسيتامينوفين + +88 +00:08:24,020 --> 00:08:30,000 +دايسالفايد بونتز ان البروتينز ريزولت من اكسيدشن اي + +89 +00:08:30,000 --> 00:08:35,520 +امينواسد اللي بيعمل دايسالفايد بونت؟ سيستين + +90 +00:08:44,950 --> 00:08:49,250 +أكسيدات الجولوكوز باستخدام نيترك أسد تنتج + +91 +00:08:49,250 --> 00:08:58,410 +إجلوكاريك إجلوكاريك أسد اللي هو يعني فيه مجموعتين + +92 +00:08:58,410 --> 00:09:08,350 +حامض إجلوكاريك أسد إجلوكاريك أسد التغيير + +93 +00:09:08,350 --> 00:09:11,870 +في حركة العيون بسبب التعاون بين الحيوانات + +94 +00:09:11,870 --> 00:09:18,880 +والمواصلةميوتا روتيشن + +95 +00:09:18,880 --> 00:09:24,080 +البروجيستيرون + +96 +00:09:24,080 --> 00:09:33,800 +هم 6 هرمون مع مصادر استيرويدال استيرويدال + +97 +00:09:33,800 --> 00:09:38,360 +مصادر استيرويدال تقوم بالتقليل من الشغر + +98 +00:09:43,220 --> 00:09:49,820 +السكريات المختزلة بيصيرلها oxidation reactions + +99 +00:09:49,820 --> 00:09:59,420 +واضح؟ oxidation لأنه هي الديهيد بيصيرلها أكسدة + +100 +00:09:59,420 --> 00:10:05,540 +واضح؟ reducing sugars undergo oxidation reactions + +101 +00:10:13,590 --> 00:10:19,570 +name the following compounds اول مركب ايش شايفين + +102 +00:10:19,570 --> 00:10:25,010 +فيه مجموعات وظيفية الديهايد و كيتون و double bond + +103 +00:10:25,010 --> 00:10:29,530 +شو لازم يصير الديهايد اعلى او لو يالا الديهايد + +104 +00:10:29,530 --> 00:10:34,630 +واحد اتنين تلاتة اربعة خمسة اذا هذا هيكون + +105 +00:10:56,440 --> 00:10:59,240 +توبنتينال توبنتينال + +106 +00:11:02,160 --> 00:11:06,800 +واضح؟ الآن تطلع على المركب اللي بعده أهم شغل تعرفه + +107 +00:11:06,800 --> 00:11:13,440 +المجموعة الوظيفية تبعت المركب ال acid ال acid ال + +108 +00:11:13,440 --> 00:11:21,160 +acid إذا هقول انا واحد اتنين تلاتة أربعة هاي الجزء + +109 +00:11:21,160 --> 00:11:27,620 +الأساسي في المركب الآن هذا الجزء شو اسمه بيوتانويك + +110 +00:11:27,620 --> 00:11:30,660 +بيوتانويك + +111 +00:11:31,760 --> 00:11:40,640 +acid ايش بيحمل على نمرة تلاتة three cyclobentyl + +112 +00:11:40,640 --> 00:11:50,520 +وشو بيحمل على نمرة اربعة four dimethylamino + +113 +00:11:50,520 --> 00:11:55,560 +three cyclobentyl + +114 +00:11:55,560 --> 00:12:00,380 +four dimethylamino butanoic acid واضح؟ + +115 +00:12:02,250 --> 00:12:07,430 +3-cyclopentel-4-dimethylamino-butanoic acid اخر + +116 +00:12:07,430 --> 00:12:14,490 +مركب شو مجموعته الوظيفية امد من + +117 +00:12:14,490 --> 00:12:22,450 +كام كربونا مكوّن بالاساس يعني جاي من اي حامض من ال + +118 +00:12:22,450 --> 00:12:31,330 +acetic acid اذا هذا أسيت امد او لو قولنا اثانوك + +119 +00:12:31,330 --> 00:12:31,810 +اسد + +120 +00:12:35,670 --> 00:12:43,650 +الان ايش بيحمل هذا على نمره اتنين فنل فنل فنل فنل + +121 +00:12:43,650 --> 00:12:48,190 +فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل + +122 +00:12:48,190 --> 00:12:48,470 +فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل + +123 +00:12:48,470 --> 00:12:51,550 +فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل + +124 +00:12:51,550 --> 00:12:51,670 +فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل + +125 +00:12:51,670 --> 00:13:02,030 +فنل فنل فنل فنل + +126 +00:13:02,030 --> 00:13:02,570 +فن + +127 +00:13:08,520 --> 00:13:13,160 +الان هانا بدنا ياكوا ترسمون لبعض المركبات بأشكالها + +128 +00:13:13,160 --> 00:13:17,340 +العامة لو قولنا أسيتوفينون مين مابتعرفش + +129 +00:13:17,340 --> 00:13:21,440 +الأسيتوفينون CH3 + +130 +00:13:21,440 --> 00:13:29,480 +فينيل C double bond O الان لما بدي هيدرازون بدو + +131 +00:13:29,480 --> 00:13:34,110 +يصير C double bond Nن اتش احنا ايش حاطين على + +132 +00:13:34,110 --> 00:13:39,890 +الهيدرازون أسيتل لو كانت مثل بنحط مثل فينال فينال + +133 +00:13:39,890 --> 00:13:44,950 +أسيتل C + +134 +00:13:44,950 --> 00:13:53,750 +double bond O CH3 أسيتوفينون هيدرازون أسيتل + +135 +00:13:53,750 --> 00:13:57,960 +هيدرازونأسيتوفينون لو فينيل كان قولنا فينيل + +136 +00:13:57,960 --> 00:14:01,600 +هيدرازون مثل مثل هيدرازون اثل هيدرازون أسيت + +137 +00:14:01,600 --> 00:14:08,860 +الهيدرازون ال glyceraldehyde ال glyceraldehyde في + +138 +00:14:08,860 --> 00:14:18,560 +هنا الديهيد و بعدين كايرال سنتر واحد شوفي هنا + +139 +00:14:18,560 --> 00:14:19,740 +الكايرالسنتر + +140 +00:14:22,340 --> 00:14:31,660 +H و OH و أنا هاي + +141 +00:14:31,660 --> 00:14:39,620 +ال glycerol دي و لو كان دي ناقص بنزل to بيوتاي + +142 +00:14:39,620 --> 00:14:45,160 +نويت بنخلص + +143 +00:14:45,160 --> 00:14:47,020 +هدول خلصناهم + +144 +00:14:49,020 --> 00:14:54,540 +الان طبعا بنبدأ الرسم من الآخر معناه ا و ات يعني + +145 +00:14:54,540 --> 00:15:00,480 +عندى P stop يعني عندى C double bond O O الان شو + +146 +00:15:00,480 --> 00:15:09,180 +الجزء ال alcohol اللى هنا بنزل شو البنزل CH2 + +147 +00:15:09,180 --> 00:15:15,960 +فنل CH2 فنل هى البنزل بنزل بيوتين و ات هى كربونة + +148 +00:15:15,960 --> 00:15:17,340 +كام كربون بيضل عندى + +149 +00:15:26,230 --> 00:15:32,970 +اربعة الان فى عندى ال triple bond على نمرة اتنين + +150 +00:15:32,970 --> 00:15:42,690 +اذا واحد اتنين تلاتة وهدى شو بيخليها CH3 وهدى + +151 +00:15:42,690 --> 00:15:51,050 +رقم واحد يعنىلحظة بنزل فنل CH2 بنزل ال Easter C W + +152 +00:15:51,050 --> 00:15:55,870 +bond O O R واضح بيوتين واحة اتنين تلاتة اربعة two + +153 +00:15:55,870 --> 00:16:02,170 +بيوتين و اتنين هذا المركب بهدوء بنمشي فيه خطوة + +154 +00:16:02,170 --> 00:16:07,330 +خطوة بنرسمه Cyclopentane كيف ال Cyclopentane؟ في + +155 +00:16:07,330 --> 00:16:14,590 +حد بعرفهش؟ بدنا نعمل فيهالديهيد سايكلوبنتين + +156 +00:16:14,590 --> 00:16:21,070 +كربلديهيد كيف الكربلديهيد C double bond O H هاي + +157 +00:16:21,070 --> 00:16:26,090 +السايكلوبنتين كربلديهيد هذا السايكلوبنتين + +158 +00:16:26,090 --> 00:16:30,910 +كربلديهيد الان لما بتعمل أكزيم بدي أشيل ال O + +159 +00:16:30,910 --> 00:16:35,670 +أخليها N OH + +160 +00:16:38,800 --> 00:16:43,560 +حولت الالديهيد إلى أكزيم سايكلوبنتين كربالديهيد + +161 +00:16:43,560 --> 00:16:49,820 +أكزيم Beta + +162 +00:16:49,820 --> 00:16:57,100 +to deoxifuranose متذكرين الفيورانوز؟ بده general + +163 +00:16:57,100 --> 00:17:05,120 +structure له أهم شيء انه على موقع اتنين في عنده + +164 +00:17:07,970 --> 00:17:14,750 +بهمنيش ال O H بهمني ال two دي أوكزي هنا في oxygen + +165 +00:17:14,750 --> 00:17:25,410 +و الموقع اتنين هنا هذا + +166 +00:17:25,410 --> 00:17:29,550 +الموقع واضح مار عليكوا ولا نفرجيكوا معاه + +167 +00:17:40,850 --> 00:17:47,390 +نذكركوا فيه لو سمحتوا في ال .. في ال + +168 +00:17:47,390 --> 00:17:54,990 +carbohydrates، هذا ال carbohydrates؟ لأ + +169 +00:18:08,950 --> 00:18:12,190 +Clothes Clothes Clothes Clothes Clothes Clothes + +170 +00:18:12,190 --> 00:18:18,910 +Clothes Clothes + +171 +00:18:18,910 --> 00:18:19,190 +Clothes Clothes Clothes Clothes Clothes Clothes + +172 +00:18:19,190 --> 00:18:19,210 +Clothes Clothes Clothes Clothes Clothes Clothes + +173 +00:18:19,210 --> 00:18:19,390 +Clothes Clothes Clothes Clothes Clothes Clothes + +174 +00:18:19,390 --> 00:18:19,510 +Clothes Clothes Clothes Clothes Clothes Clothes + +175 +00:18:19,510 --> 00:18:19,830 +Clothes Clothes Clothes Clothes Clothes Clothes + +176 +00:18:19,830 --> 00:18:20,630 +Clothes Clothes Clothes Clothes Clothes Clothes + +177 +00:18:20,630 --> 00:18:20,750 +Clothes Clothes + +178 +00:18:33,500 --> 00:18:36,800 +oxygen ديش هيكوا تحفظوا الواتشز لوين بس أهم إشي + +179 +00:18:36,800 --> 00:18:43,460 +تنتبهوه لإنه موقع اتنين دي oxy sugar واضح موقع + +180 +00:18:43,460 --> 00:18:50,040 +اتنين دي oxy sugar مافيش عليه إيش واتشز موقع اتنين + +181 +00:18:50,040 --> 00:18:58,580 +مافيش عليه واتشز ماليك انهيدريد متذكرين الماليك + +182 +00:18:58,580 --> 00:19:08,650 +انهيدريد سيبقى بالبنت او اوC double bond O ماليك + +183 +00:19:08,650 --> 00:19:16,430 +أنهايدرايد مار + +184 +00:19:16,430 --> 00:19:22,790 +عندكم نفتالك أنهايدرايد والماليك أنهايدرايد الآن + +185 +00:19:22,790 --> 00:19:28,750 +لما نجيبلكوا أكمل معادلات المحور الأساسي هنا إيش + +186 +00:19:28,750 --> 00:19:31,430 +هو الديهايد + +187 +00:19:32,840 --> 00:19:39,380 +الديهايد، واضح؟ يعني بدنا نتذكر كيمية ال الديهايد + +188 +00:19:39,380 --> 00:19:47,480 +الان ال الديهايد بال أكسدة، شو بيصير؟ acid ال + +189 +00:19:47,480 --> 00:19:53,040 +الديهايد بال أكسدة، acid و بال reduction؟ alcohol، + +190 +00:19:53,040 --> 00:19:57,890 +مشغولنا احنا ال الديهايدفي نص الطريق يتأكسد لحامض + +191 +00:19:57,890 --> 00:20:04,330 +و يختزل لكحول هي رجعته كحول او خلته حامض واضح + +192 +00:20:04,330 --> 00:20:12,610 +الفكرة؟ الان ال الديهايد بال HCN شو بيعمل؟ + +193 +00:20:12,610 --> 00:20:18,350 +سيانوهيدرين سيانوهيدرين اذا هذه بدأ تصير OHH و هنا + +194 +00:20:18,350 --> 00:20:28,230 +CN بال إثالينيج لايكولمتذكرين الاسيتال؟ هاي زي هيك + +195 +00:20:28,230 --> 00:20:34,810 +عند هذه بدو + +196 +00:20:34,810 --> 00:20:41,630 +يصير عندكم O تتدربوا + +197 +00:20:41,630 --> 00:20:44,430 +عليها اللي هي الاسيتال اللي من ال إيثالينيج لايكون + +198 +00:20:44,430 --> 00:20:49,710 +ابهيك أخدنا كام تفاعل للالديهايد؟ أربعة الأن + +199 +00:20:49,710 --> 00:20:54,570 +لاحظوا مع الالديهايد هنا صح؟acid يعني بدي تفاعله + +200 +00:20:54,570 --> 00:21:01,510 +الأحمار حمض زائد قاعدة يعني هذا هيصير C double + +201 +00:21:01,510 --> 00:21:09,130 +bond O O minus عند اللزوم K plus حمض هذا مع الثيون + +202 +00:21:09,130 --> 00:21:14,270 +الاخلورايد حمض زائد ثيون الاخلورايد او BCL3 acid + +203 +00:21:14,270 --> 00:21:19,010 +chloride تفاعله الحمض هذا الكحول + +204 +00:21:21,550 --> 00:21:29,390 +كحول مع بنزويك أسد كحول زاد حمض Easter إذا هاي ال + +205 +00:21:29,390 --> 00:21:35,470 +بنزويك أسد فنل C double bond O و جزء الكحول O + +206 +00:21:35,470 --> 00:21:40,010 +Cyclobentel + +207 +00:21:40,010 --> 00:21:47,170 +واضحة الفكرة؟ هاي جزء الكحول أنا في أشقنة CH2 كمان + +208 +00:21:47,170 --> 00:21:48,730 +نحتفظ فيها + +209 +00:21:55,050 --> 00:22:00,270 +Ester كحول زاد حامض هاي جزء ال بنزويك أسد وهذا جزء + +210 +00:22:00,270 --> 00:22:11,530 +الكحول كحول مع حامض بيعطينا Easter واضح + +211 +00:22:11,530 --> 00:22:15,710 +الفكرة؟ الآن لما نقولكوا هذا بدنا نفعله مع one + +212 +00:22:15,710 --> 00:22:19,350 +equivalent acetaldehyde كيف شكلوا ال acetaldehyde؟ + +213 +00:22:22,540 --> 00:22:27,940 +CH3COH كحول مع الديهيد شو بيعطيني؟ Hemacetal + +214 +00:22:27,940 --> 00:22:33,480 +Hemacetal يعني هذه بتاتيجي هنا وهذه تصير OH لاحظوا + +215 +00:22:33,480 --> 00:22:38,760 +كملنا ال Acetal ولا قولنا بس Hemacetal Hemacetal + +216 +00:22:38,760 --> 00:22:42,520 +يعني هذه تصير CH3COHH + +217 +00:22:42,520 --> 00:22:47,600 +و الجزء الخارجي هذا OCH2 + +218 +00:22:51,690 --> 00:22:58,670 +cyclopentel كحول زي الديهيد هيمي أسيتال كحول زي + +219 +00:22:58,670 --> 00:23:04,550 +الديهيد هيمي أسيتال كحول زي الحمر إيستار طبعا لازم + +220 +00:23:04,550 --> 00:23:08,830 +الإيد تكون متدربة أنها تطبق هذا الكلام تعمله يعني + +221 +00:23:08,830 --> 00:23:12,510 +الأفكار العامة دائما احفظوها قبل ما تقولوا رمز + +222 +00:23:12,510 --> 00:23:18,550 +كونوا فاهمين إيش المطلوب كحول مع حامضطبقه على هذا + +223 +00:23:18,550 --> 00:23:24,890 +الكلام الفكرة خلصت الان كحول مع الديهايد hemacetal + +224 +00:23:24,890 --> 00:23:31,410 +الديهايد بالاختزال كحول الديهايد بالأكسدة حم حم + +225 +00:23:31,410 --> 00:23:37,710 +زاد قاعدة ملح حم زاد ثيونيلي كلورايد أسد كلورايد + +226 +00:23:37,710 --> 00:23:43,790 +الديهايد مع السيانو هدرين الديايد مع الاتلينيج + +227 +00:23:43,790 --> 00:23:49,110 +لايكول أسيتال وبعدين بيصير انه جديش الإنسان متدرب + +228 +00:23:49,110 --> 00:23:51,430 +يكتب ويطبق هذا الكلام + +229 +00:24:07,890 --> 00:24:14,030 +الآن هى فى عندنا سؤال تانى إيش المنطلق اللى عندنا + +230 +00:24:14,030 --> 00:24:17,970 +فيه أسد كلورايد أسد كلورايد بتكون تتذكروا كيمية + +231 +00:24:17,970 --> 00:24:24,910 +الأسد كلورايد أسد كلورايد مع كحول أستر أستر كل إشي + +232 +00:24:24,910 --> 00:24:29,610 +بخليه زى ما هو و بحطها نقوه أسلف أستر ممتاز أسد + +233 +00:24:29,610 --> 00:24:36,730 +كلورايد مع أمين أمد أمد unatched + +234 +00:24:36,730 --> 00:24:46,530 +twoالان acid chloride مع green yard reagent تير + +235 +00:24:46,530 --> 00:24:52,510 +تشيري ألكول هاي ال C هادي هادي هادي بتصير OH يجيني + +236 +00:24:54,100 --> 00:24:58,100 +مجمعتين فنل على مرتين هيتفاعل أول اشي بيعطيني ال + +237 +00:24:58,100 --> 00:25:01,800 +ketone أول ما تاجم الفنل هنا محل ال CL بيعطيني ال + +238 +00:25:01,800 --> 00:25:06,480 +ketone و بكمل ل tertiary alcohol أخدنا ال Easter و + +239 +00:25:06,480 --> 00:25:10,580 +ال acid chloride مع Greenyard شو بيعطوني؟ tertiary + +240 +00:25:10,580 --> 00:25:16,200 +alcohol و بال reduction؟ primary alcohol الان + +241 +00:25:21,250 --> 00:25:25,850 +هذا الـ Acid chloride مع Sodium Benzoyate بدنا + +242 +00:25:25,850 --> 00:25:31,190 +واحدة شاطرة تقولنا كيف شكل Sodium Benzoyate فنل C + +243 +00:25:31,190 --> 00:25:38,410 +double bond O O minus N A plus لاحظوا هنا لما قلت + +244 +00:25:38,410 --> 00:25:44,730 +O minus و هذا Acid chloride صار تحضير ايش الـ + +245 +00:25:44,730 --> 00:25:49,930 +Unsymmetrical anhydride ان هذه تهاجمهاهذا + +246 +00:25:49,930 --> 00:25:55,350 +نيوكليوفايل يترد الـCl إيه هاجمانه يترد الـCl + +247 +00:25:55,350 --> 00:25:58,810 +عشانك هيصير هذا تحضير الـ Unsymmetrical Unhydrate + +248 +00:25:58,810 --> 00:26:05,670 +هاي هذا الجزء والجزء التاني O C double bond O + +249 +00:26:05,670 --> 00:26:11,170 +Phenyl فعلا هذا Unhydrate ولا لأ؟ C double bond O + +250 +00:26:11,170 --> 00:26:18,440 +O C double bond O Unhydrate هاي احناأخدنا أربع + +251 +00:26:18,440 --> 00:26:22,780 +تفاعلات للـ Acid Chloride باختصار Acid Chloride مع + +252 +00:26:22,780 --> 00:26:27,300 +كحول Easter Acid Chloride مع أمونيا Amid Acid + +253 +00:26:27,300 --> 00:26:31,000 +Chloride مع Greenyard Tertiary Alcohol Acid + +254 +00:26:31,000 --> 00:26:37,160 +Chloride مع أنيون Unhydrate Unsymmetrical + +255 +00:26:37,160 --> 00:26:40,020 +Unhydrate طريقة تحضير الـ Unsymmetrical Unhydrate + +256 +00:26:40,020 --> 00:26:44,560 +الأن دول خلصناهم صار في عندي Easter بدي أخد لل + +257 +00:26:44,560 --> 00:26:49,240 +Easter كام تفاعل؟تفاعلين وصار في اندي أمد بتاخد + +258 +00:26:49,240 --> 00:26:53,420 +للأمد كام تفاعل؟ تفاعلين هو احنا كل اللي اتعلمناهم + +259 +00:26:53,420 --> 00:27:01,100 +للأمد كام تفاعل؟ يا هيدروليسز يعني هذا يصير acid + +260 +00:27:01,100 --> 00:27:13,240 +بهذا الشكل يا اما reduction ان هذا يصير CH2 + +261 +00:27:14,120 --> 00:27:22,280 +ان اتش امد امد امد امد امد امد امد امد امد امد امد + +262 +00:27:22,280 --> 00:27:25,100 +امد امد امد امد امد امد امد امد امد امد امد امد + +263 +00:27:25,100 --> 00:27:25,980 +امد امد امد امد امد امد امد امد امد امد امد امد + +264 +00:27:25,980 --> 00:27:30,000 +امد امد امد امد امد امد امد امد امد امد امد امد + +265 +00:27:30,000 --> 00:27:31,420 +امد امد امد امد امد امد امد امد امد امد امد امد + +266 +00:27:31,420 --> 00:27:31,460 +امد امد امد امد امد امد امد امد امد امد امد امد + +267 +00:27:31,460 --> 00:27:39,960 +امد امد ا + +268 +00:27:43,000 --> 00:27:47,720 +الإيستار بالريدكشن الاسد الكلورايد والإيستار + +269 +00:27:47,720 --> 00:27:51,240 +بالريدكشن شو بيصيروا ال primary alcohol يعني هذه + +270 +00:27:51,240 --> 00:27:56,400 +بيصير CH2OH + +271 +00:27:56,400 --> 00:28:04,700 +والجزء هذا نفسه طيب الإيستار مع الهيدرازين يمكن + +272 +00:28:04,700 --> 00:28:10,790 +مامرش عليكم هذا التفاعلكتفاعل خاص لكن لما تقولوا + +273 +00:28:10,790 --> 00:28:16,190 +الهيدرازين نيوكليوفايل شو بده يعمل؟ بده يهاجم هنا + +274 +00:28:16,190 --> 00:28:22,410 +و يطرد ال O-ethyl، حطوا الناتج بهذا الشكل، إذا + +275 +00:28:22,410 --> 00:28:30,510 +حاسين عندكم؟ C double bond O وهنا إيش بده يصير؟ NH + +276 +00:28:30,510 --> 00:28:35,630 +NH2 هيدرازايد + +277 +00:28:35,630 --> 00:28:42,800 +بيسموهزي تفاعل الأمد، زي لو كنتوا بفعلينه مع ناتشي + +278 +00:28:42,800 --> 00:28:48,460 +ثري، مش كان تيجي ناتشي ثري تحل محل هادى، واضح؟ نفس + +279 +00:28:48,460 --> 00:28:53,900 +الفكرة تماما، + +280 +00:28:53,900 --> 00:28:54,620 +واضحة؟ + +281 +00:29:13,900 --> 00:29:19,260 +لاحظوا بسؤال بسيط راجعنا كام كيميا ال acid halides + +282 +00:29:19,260 --> 00:29:25,720 +و ال e stars و ال amides و ال acids هذا + +283 +00:29:25,720 --> 00:29:34,430 +الجزء في عندكممجموعة النيترو ومجموعة ال سيانو على + +284 +00:29:34,430 --> 00:29:43,070 +بنزين الان النيترو بال reduction شو بتصير ان + +285 +00:29:43,070 --> 00:29:47,670 +اتشتو ان اتشتو امين مشقول ان هذه طريقة تحضير + +286 +00:29:47,670 --> 00:29:53,970 +الانيلين يعني هذه تصير ان اتشتو هنا سيان + +287 +00:29:56,170 --> 00:30:02,250 +Reduction بيشتغل الـ Nitro تصير NH2 الآن السيانو + +288 +00:30:02,250 --> 00:30:06,470 +أخدنا بالهيدروليسيز في تحضير الأحمار، شو بتصير؟ + +289 +00:30:06,470 --> 00:30:12,030 +أسد، أذن هنا، بدي أسيبني من الـNitro زي ما هي، + +290 +00:30:12,030 --> 00:30:20,810 +وهذه إيش تصير؟ C double bond O تفاعل + +291 +00:30:20,810 --> 00:30:26,980 +السيانو لأسد، مر معنا ولا لأ؟وتفاعل الـ Nitro هي + +292 +00:30:26,980 --> 00:30:32,060 +مصدر الانيلين مرمعنا ولا لأ افتح دي للأمين؟ بس هم + +293 +00:30:32,060 --> 00:30:38,640 +راحون دخلوش في بعض في هنا الـNa الـO2 بتحولها إلى + +294 +00:30:38,640 --> 00:30:45,260 +الـOX اه هنا اول فكرة الـH2 بهمش انتبع شوية الـH2 + +295 +00:30:45,260 --> 00:30:49,640 +مع البلاتينام بيعطيني الانيلين الآن اذا بعد هيك + +296 +00:30:49,640 --> 00:30:54,880 +فعلناها مع Sodium Nitrite وH3O Plus بيصير ايش؟ + +297 +00:30:55,940 --> 00:31:00,660 +الفينول مر علينا طريقة تحضير الفينول يعني أنا كان + +298 +00:31:00,660 --> 00:31:06,060 +جوابي بس للجزء الأول إذا بعدك فعلته مع الصوديوم + +299 +00:31:06,060 --> 00:31:08,640 +نايترايت حامل دايزونيوم سولت ماعدش three of plus + +300 +00:31:08,640 --> 00:31:15,280 +بصير فينول يعني لو أجينا بس لحدها أنيلين + +301 +00:31:15,280 --> 00:31:22,520 +لو كملناالانهيلين بنحوله إلى فينول حسب ما يجي + +302 +00:31:22,520 --> 00:31:25,980 +السؤال يعني لحد ال reduction انهيلين زدنا عن ال + +303 +00:31:25,980 --> 00:31:33,480 +reduction فينول ممتازة + +304 +00:31:33,480 --> 00:31:34,020 +الان + +305 +00:31:45,510 --> 00:31:50,110 +جينا سؤال كيف بدنا نحضر ال Acetic Acid بتعرفوا ال + +306 +00:31:50,110 --> 00:31:56,750 +Acetic Acid؟ CH3COOH + +307 +00:31:56,750 --> 00:32:02,870 +من إيش بدنا نحضره؟ من التوبيوتانون واحد اتنين هاي + +308 +00:32:02,870 --> 00:32:07,530 +توبيوتانون طبعا + +309 +00:32:07,530 --> 00:32:14,580 +الكلام يبدوشوية غريب جدا لكن لو اي حد بيفكر شوية + +310 +00:32:14,580 --> 00:32:20,720 +بعمق بيفكر شوية بعمق ال acetic acid كاربونتين وال + +311 +00:32:20,720 --> 00:32:30,460 +two-butanone اربعة يعني الأربعة لو كسروا لو كسروا + +312 +00:32:30,460 --> 00:32:34,360 +بيصيروا اتنين و اتنين اذا انا لو كنت بدي اجي برجوع + +313 +00:32:34,360 --> 00:32:36,540 +من ورا هذا ايش ممكن يكون + +314 +00:32:39,320 --> 00:32:47,400 +الالكين هذا نمرة واحد O3 نمرة اتنين H2O2 كان + +315 +00:32:47,400 --> 00:32:53,300 +بيعطيني زي هيك ولا لأ؟ + +316 +00:32:53,300 --> 00:32:58,660 +أنا كملت بالأكسدة الإضافية أوزون وبعدين أكسدة + +317 +00:32:58,660 --> 00:33:07,580 +بيصير حامض أوزون وبعدين أكسدة بيصير حامضواضح؟ الآن + +318 +00:33:07,580 --> 00:33:13,140 +هذا من إيش ممكن ييجي؟ من كحول يعني خلّينا هيك + +319 +00:33:13,140 --> 00:33:19,540 +نتخيل هي OH الآن أنا ماعنديش كحول عشان أعمل حدث + +320 +00:33:19,540 --> 00:33:24,380 +باستعمال ال KOH بيعطينا Alkene بس أنا ماعنديش كحول + +321 +00:33:24,380 --> 00:33:33,360 +أنا عنده Ketone ال Ketone يختزل آه + +322 +00:33:33,960 --> 00:33:41,740 +اذا كيتون كحول الكين و اوزونوليس اتبع اكسيداشيا او + +323 +00:33:41,740 --> 00:33:46,960 +ممكن تستعمل كمان او فور برضه اتش بلس بتعمل نفس + +324 +00:33:46,960 --> 00:33:52,700 +الشي واضح هذا في طريقة تحضير الأحمار لما قولنا كيف + +325 +00:33:52,700 --> 00:33:57,200 +بنكسر ال double bond او ال triple bond كمان ممكن + +326 +00:33:57,200 --> 00:34:00,700 +نكسرها و اش تعطينا حامض + +327 +00:34:02,030 --> 00:34:06,050 +طبعا لأن هنا في عندي H وهنا H أول ما بيكسر زي ما + +328 +00:34:06,050 --> 00:34:09,470 +حكت زميلتكوا فعلا ل 12-dihydes ال 12-dihydes + +329 +00:34:09,470 --> 00:34:17,010 +بتأكسدوا لإيش لacetic acid 12-dihydes بتأكسدوا + +330 +00:34:17,010 --> 00:34:24,610 +لacetic acid أخر + +331 +00:34:24,610 --> 00:34:29,770 +سؤال كان draw the structure of the peptide alanine + +332 +00:34:29,770 --> 00:34:35,490 +cysteineالان بدي قلانين الستين هو ال بيبتايد ايش + +333 +00:34:35,490 --> 00:34:44,710 +NCCO وكمان NCCO الان هاي بيبتايد من شغلتين + +334 +00:34:44,710 --> 00:34:49,910 +القلانين شو المجموعة اللي هنا CH3 وهي ال amino + +335 +00:34:49,910 --> 00:34:55,650 +terminal وهنا بدو يكون عندكم NH الستين شو المجموعة + +336 +00:34:55,650 --> 00:34:59,930 +CH2SH + +337 +00:34:59,930 --> 00:35:05,970 +وهنا بدو يكونالـ Acid Terminal فلاحظوا الـ peptide + +338 +00:35:05,970 --> 00:35:10,190 +لما بدي أرسم بدي أبدأ بالهيكل تبعه N C C double + +339 +00:35:10,190 --> 00:35:14,770 +bond O و N C C double bond O الآن إذا بحكي عن + +340 +00:35:14,770 --> 00:35:22,150 +الانين بدي أحط مثل بحكي عن سيستين بدي أحط CH2SH + +341 +00:35:23,240 --> 00:35:26,540 +واضح الفكرة؟ هى صار عند ال بيبتايد و amino + +342 +00:35:26,540 --> 00:35:32,260 +terminal و acid terminal الآن بدنا نيجي بعد هيك + +343 +00:35:32,260 --> 00:35:40,180 +نقول هذا ال بيبتايد خلينا نفعله مع ال methanol و H + +344 +00:35:40,180 --> 00:35:44,220 +plus لاحظوا + +345 +00:35:44,220 --> 00:35:49,980 +ال بيبتايد إله acid terminal ولا لأ؟ acid .. acid + +346 +00:35:49,980 --> 00:35:51,320 +زاد alcohol + +347 +00:35:53,810 --> 00:35:59,050 +أسد زائد ألكوهول إيستر إذا أنا بدي أجيب كل هذا + +348 +00:35:59,050 --> 00:36:02,970 +بلاش نقعد نوضح فيه و نقول C double bond O و من + +349 +00:36:02,970 --> 00:36:09,110 +الميثانول شو هيحط اوميثيل كل ال بيبتايد زي ما هو + +350 +00:36:09,110 --> 00:36:12,530 +كاملة C double bond O اوميثيل + +351 +00:36:18,040 --> 00:36:22,160 +الان ال بيبتايد مع ال two four داينيترو فلورو + +352 +00:36:22,160 --> 00:36:29,680 +بنزين هذا اللي أخدناه وسمناه ايش floor zanger + +353 +00:36:29,680 --> 00:36:39,340 +method وان او اتو وان اتو ايش بيعمل بالتحت مكان ال + +354 +00:36:39,340 --> 00:36:45,360 +floor اذا انا هيكون عندى ان اتش و ال بيبتايد كله و + +355 +00:36:45,360 --> 00:36:56,410 +بعدين هنابنزينة بنيترو و نيترو كل ال بيبتايد يتحد + +356 +00:36:56,410 --> 00:37:05,110 +من عند ال N الان + +357 +00:37:05,110 --> 00:37:12,030 +لو اجينا فعلنا هذا مع ال etheracetate OH- ال + +358 +00:37:12,030 --> 00:37:19,040 +etheracetate يستر بنقدر نرسمهCH3C double bond O O + +359 +00:37:19,040 --> 00:37:26,040 +-ethyl ايش اللي بنتوقع ميثل بيبتايد موجود ال amino + +360 +00:37:26,040 --> 00:37:33,640 +group النيكليوفايل وين ممكن يتهاجم تطرد + +361 +00:37:33,640 --> 00:37:41,160 +ال O-ethyl اذا هيكون الناتج اللي عندى ال N-H مع كل + +362 +00:37:41,160 --> 00:37:50,600 +ال بيبتايد و ايش هيحط عندى هناC double bond O CH3 + +363 +00:37:50,600 --> 00:37:56,320 +الأمين + +364 +00:37:56,320 --> 00:38:00,080 +بتفاعل مع ال Easter مش الأسد بتفاعل مع ال Easter + +365 +00:38:00,080 --> 00:38:11,130 +أمين زائد Easter أمد أمين زائد Easterامد مش هذه + +366 +00:38:11,130 --> 00:38:18,410 +المعادلة العامة هذي امين وهذا اي ستار امين زائد اي + +367 +00:38:18,410 --> 00:38:28,950 +ستار بيعطينا ايش امد الان طب ال HCL بدو يتحلل اه + +368 +00:38:28,950 --> 00:38:32,930 +بالاساس مش بنعمل هيدرونيسز احنا لل بيبتايدز يعني + +369 +00:38:32,930 --> 00:38:43,130 +بدو يعطينا NH CHC double bond O OHزائد طبعا nh2 + +370 +00:38:43,130 --> 00:38:50,470 +كمان nh2 CH16 CH2SH مشغولا بيعملوا hydrolysis ال + +371 +00:38:50,470 --> 00:38:58,230 +peptides واضح؟ hydrolysis peptide hydrolysis بدو + +372 +00:38:58,230 --> 00:39:02,530 +يتكسر ضايق الاشياء؟ + +373 +00:39:22,160 --> 00:39:25,980 +نشوف الامتحان التاني حاولوا تشوفون اللي بدوبوها لو + +374 +00:39:25,980 --> 00:39:26,600 +سمحتوا + +375 +00:39:55,080 --> 00:40:10,380 +هذا الامتحان التاني اللي عندكم بمش + +376 +00:40:10,380 --> 00:40:15,860 +نمشي فيه أسرع شوية نمشي + +377 +00:40:15,860 --> 00:40:20,280 +فيه أسرع شوية يعني الحل بدون شرح و بتقلق الآن ال + +378 +00:40:20,280 --> 00:40:23,220 +carboxylic acids نكبر هذه بس + +379 +00:40:27,990 --> 00:40:32,070 +خلّيكم معايا Carboxylic acids react with aniline + +380 +00:40:32,070 --> 00:40:36,070 +producing amides حمض زائد أمين أمد هذي الجملة صح + +381 +00:40:36,070 --> 00:40:43,210 +اجليسرال ترايستيريت is a simple triglyceride صح + +382 +00:40:45,730 --> 00:40:50,250 +A large percentage of unsaturated acids غلط of + +383 +00:40:50,250 --> 00:40:54,630 +saturated reaction of hemacetals with alcohol is a + +384 +00:40:54,630 --> 00:40:58,290 +substitution reaction Hemacetal مع الالكول + +385 +00:40:58,290 --> 00:41:02,870 +substitution صحيحة Ibomars are enantiomars that + +386 +00:41:02,870 --> 00:41:06,230 +differ only in one chiral center لأ ال Ibomars are + +387 +00:41:06,230 --> 00:41:10,600 +diastereomarsالغلط إيجا من كلمة enantiomers الـ + +388 +00:41:10,600 --> 00:41:16,360 +epimers are the stereomers ال acid halides are + +389 +00:41:16,360 --> 00:41:22,450 +reduced to primary alcohols صح؟Aniline can be + +390 +00:41:22,450 --> 00:41:25,770 +prepared from the reaction of benzene with ammonia + +391 +00:41:25,770 --> 00:41:29,910 +هذا قلنا لأ من ال nitrobenzene بنحضر ال aniline + +392 +00:41:29,910 --> 00:41:34,290 +متذكرين؟ ال aniline من إيش بنحضره؟ Nitrobenzene + +393 +00:41:34,290 --> 00:41:37,790 +heating acidic acid with benzoic acid in presence + +394 +00:41:37,790 --> 00:41:42,570 +of H plus produces three possible products اللي هي + +395 +00:41:42,570 --> 00:41:45,750 +ال anhydrides مش four possible anhydrides، three + +396 +00:41:45,750 --> 00:41:57,500 +هذا بالنسبة لجزءالصح والغلط الآن + +397 +00:41:57,500 --> 00:42:02,480 +الـ isoelectric point is the point at which the pH + +398 +00:42:02,480 --> 00:42:09,160 +is the isoelectric point is the pH at which the + +399 +00:42:09,160 --> 00:42:15,470 +compound has a zero charge مش هيك؟الـ pH اللي + +400 +00:42:15,470 --> 00:42:19,790 +بتكون عنده ال charge كده؟ سفر، أخدناها، صيغوها بأي + +401 +00:42:19,790 --> 00:42:25,910 +صياغة الـ polar R-groups in fibrous proteins are + +402 +00:42:25,910 --> 00:42:32,690 +located inside essential + +403 +00:42:32,690 --> 00:42:40,950 +amino acids are obtained fromDiet او are not + +404 +00:42:40,950 --> 00:42:45,010 +synthesized in the body الأحماض الأمريكية الأساسية + +405 +00:42:45,010 --> 00:42:48,890 +اللي بناخدها من الغداء بيحضرهاش الجسم بأي صياغة + +406 +00:42:48,890 --> 00:42:56,710 +مثل MgBr react with acetone producing لاحظوا هاي + +407 +00:42:56,710 --> 00:43:02,410 +ال ketone ال acetone مع مثل MgBr بيجيب مثل T جهان + +408 +00:43:02,410 --> 00:43:08,210 +وهذا تصير OH إذا أنا producersTertiary Alcohol لو + +409 +00:43:08,210 --> 00:43:15,370 +واحدة بتسميه بالظبط tertiary butanol produces + +410 +00:43:15,370 --> 00:43:19,910 +tertiary butanol أو tertiary alcohol as a general + +411 +00:43:19,910 --> 00:43:33,150 +family Acetophenon is also called مثل كيتون + +412 +00:43:33,500 --> 00:43:38,020 +اسيتوفينون هو أيضا مسمى مثلفنالكليتون الاستيريو + +413 +00:43:38,020 --> 00:43:42,980 +مارز اللي مختلف فقط في مركز استيريوجينيكي مسمى ابي + +414 +00:43:42,980 --> 00:43:48,940 +مارز ابي مارز مونو + +415 +00:43:48,940 --> 00:43:53,720 +تيربينز مجتمع من عشر كربون او عشر كربون او عشر + +416 +00:43:53,720 --> 00:43:54,460 +كربون او عشر كربون او عشر كربون او عشر كربون او + +417 +00:43:54,460 --> 00:44:01,000 +عشر كربون او عشر كربون او عشر كربون او + +418 +00:44:01,000 --> 00:44:01,540 +عشر كربون او عشر كربون او عشر كربون او عشر كربون + +419 +00:44:01,540 --> 00:44:11,350 +عشر كربون او عشر كرببولي هيدروكسي ألديهيدز ال + +420 +00:44:11,350 --> 00:44:21,670 +doses are بولي هيدروكسي ألديهيدز و + +421 +00:44:21,670 --> 00:44:27,930 +ال ketosis بولي هيدروكسي + +422 +00:44:39,600 --> 00:44:45,480 +السؤال اللي بعده شو العائلة لهذا المركب؟ لاحظوا ما + +423 +00:44:45,480 --> 00:44:48,880 +قلتلكم مش ساموه المركب كاملا بس قولولي أي عائلة + +424 +00:44:48,880 --> 00:44:57,760 +هذه سيان مع او اتش سيانو هدرين سايكليك إيستر + +425 +00:44:57,760 --> 00:45:01,080 +لاكتون هذا + +426 +00:45:04,520 --> 00:45:11,040 +فيورانوز فيورانوز سكر خماسي فيورانوز ال N-H-C-W-O + +427 +00:45:11,040 --> 00:45:13,480 +-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O + +428 +00:45:13,480 --> 00:45:14,500 +-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O + +429 +00:45:14,500 --> 00:45:23,220 +-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O + +430 +00:45:23,220 --> 00:45:32,970 +-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-OCarbazone + +431 +00:45:32,970 --> 00:45:36,490 +Semicarbazone + +432 +00:45:36,490 --> 00:45:41,130 +ارسموا + +433 +00:45:41,130 --> 00:45:45,690 +شكل المراكبات الآتية من الـ Benzoic acid Sodium + +434 +00:45:45,690 --> 00:45:52,410 +Benzoate كيف هيكون؟ C double bond O O minus K plus + +435 +00:45:52,410 --> 00:45:59,210 +Potassium Benzoate Potassium Benzoate Benzamide + +436 +00:45:59,210 --> 00:46:06,580 +كيف ال Benzamide؟بنزين C double bond O N هاي الأمد + +437 +00:46:06,580 --> 00:46:15,400 +بده على ال N إيش؟ CH3 و CH3 دا يمثل بنزامد four + +438 +00:46:15,400 --> 00:46:22,460 +benzyl two hexenol طالما قال إذا إيش أنا عنده؟ + +439 +00:46:22,460 --> 00:46:27,580 +واحد اتنين تلاتة أربعة خمسة ستة هاي ال aldehyde C + +440 +00:46:27,580 --> 00:46:35,290 +double bond OH على نمرة اتنين واحد اتنين double + +441 +00:46:35,290 --> 00:46:41,850 +bond ع نمرة اربعة واحد اتنين تلاتة اربعة بنزل اللي + +442 +00:46:41,850 --> 00:46:51,050 +هي CH2 فنل مجموعة CH2 فنل بنزل مجموعة CH2 فنل بنزل + +443 +00:46:51,050 --> 00:46:54,450 +واضح؟ + +444 +00:46:54,450 --> 00:46:59,190 +هاي الال والإين والبنزل + +445 +00:47:09,280 --> 00:47:13,420 +سم المركبات التالية هذا إيش مجموعته الوظيفية إيه + +446 +00:47:13,420 --> 00:47:19,180 +إيه استر إذا لازم أحط في الأول إثل و في الآخر واحد + +447 +00:47:19,180 --> 00:47:28,360 +اتنين تلاتة أربعة خمسة بنتين و ويت ال E وين موقعها + +448 +00:47:28,360 --> 00:47:34,700 +إثل توبنتين و ويت إيش ده الحامل هذا المركب four + +449 +00:47:34,700 --> 00:47:35,120 +hydroxy + +450 +00:47:37,970 --> 00:47:44,350 +اذا هذا صار اثل فور هيدروكسي توبنتينويت اثل فور + +451 +00:47:44,350 --> 00:47:51,350 +هيدروكسي توبنتينويت واضح؟ نسمي اخر اتنين ونخلص بعد + +452 +00:47:51,350 --> 00:47:56,750 +عشر ثواني هذا المركب اللي شايفينه عبارة عن ايش؟ + +453 +00:47:56,750 --> 00:48:03,810 +كيتون واحد اتنين تلاتة اربعة خمسة ستة اذا هذا + +454 +00:48:03,810 --> 00:48:10,520 +عبارة عن threeهكسانون شو بيحمل ال three hexanone + +455 +00:48:10,520 --> 00:48:17,940 +مثل و دايمثل بيحط مواقعهم يعني two مثل و six + +456 +00:48:17,940 --> 00:48:23,020 +daimethylamino هذي إيش اسمها الآن مثل مثل six + +457 +00:48:23,020 --> 00:48:28,140 +daimethylamino المركب الأخير هذا مر علينا في ال + +458 +00:48:28,140 --> 00:48:36,240 +unhydrate افتلك unhydrate + +459 +00:48:37,520 --> 00:48:42,140 +على اي حال بيكفي لهذا الجزء الباقي عبارة عن + +460 +00:48:42,140 --> 00:48:46,860 +معادلات شبيهة بالامثلة التانية، بننهي الآن و + +461 +00:48:46,860 --> 00:48:48,720 +بنتمنى لكم التوفيق + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..b5357d128cf3182a46feaf57b85ed601ef8bab6d --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/kc7SLz2Zt8E_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4533, "start": 20.79, "end": 45.33, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله في 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0.97802734375}, {"start": 49.71, "end": 50.19, "word": " طبعا", "probability": 0.9615478515625}, {"start": 50.19, "end": 51.79, "word": " منوعة،", "probability": 0.802490234375}, {"start": 51.79, "end": 51.89, "word": " في", "probability": 0.85791015625}, {"start": 51.89, "end": 52.35, "word": " أسئلة", "probability": 0.9617919921875}, {"start": 52.35, "end": 52.67, "word": " صح", "probability": 0.9873046875}, {"start": 52.67, "end": 52.77, "word": " و", "probability": 0.91162109375}, {"start": 52.77, "end": 53.25, "word": " غلط،", "probability": 0.9520263671875}, {"start": 53.25, "end": 53.61, "word": " أكمل", "probability": 0.9676106770833334}, {"start": 53.61, "end": 54.53, "word": " الفراغ،", "probability": 0.9662109375}, {"start": 54.53, "end": 54.77, "word": " سم", "probability": 0.900390625}, {"start": 54.77, "end": 55.75, "word": " المركب،", "probability": 0.82666015625}, {"start": 55.75, "end": 55.97, "word": " كيف", "probability": 0.956787109375}, {"start": 55.97, "end": 56.51, "word": " تحضر", "probability": 0.9884033203125}, {"start": 56.51, "end": 57.97, "word": " مركب،", "probability": 0.9190673828125}, {"start": 57.97, "end": 58.47, "word": " أكمل", "probability": 0.9794921875}, {"start": 58.47, "end": 59.67, "word": " المعادلة،", "probability": 0.9734375}, {"start": 59.67, "end": 59.85, "word": " كل", "probability": 0.884765625}, {"start": 59.85, "end": 60.07, "word": " هذه", "probability": 0.98193359375}, {"start": 60.07, "end": 60.61, "word": " الأشياء", "probability": 0.9959716796875}], "temperature": 1.0}, {"id": 3, "seek": 9100, "start": 61.24, "end": 91.0, "text": "نشوف الأشياء بالترتيب في أسئلة الصح والغلط بيسألنا سؤال بيقولنا الـpeptide لجليسين ألانين ألانين و الـpeptide ألانين جليسين جليسين are structural isomers ايش رأيكم؟ they are not isomers لأن ال isomers لازم يكونوا مكونين من نفس الأشياء يعني هذا اتنين ألانين واحد جليسين هذا اتنين جليسين واحد ألانين they are not isomers", "tokens": [1863, 8592, 38688, 16247, 8592, 1829, 16606, 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0.78857421875}, {"start": 71.26, "end": 71.8, "word": " ألانين", "probability": 0.7891845703125}, {"start": 71.8, "end": 72.54, "word": " ألانين", "probability": 0.985595703125}, {"start": 72.54, "end": 73.16, "word": " و", "probability": 0.7568359375}, {"start": 73.16, "end": 73.82, "word": " الـpeptide", "probability": 0.80380859375}, {"start": 73.82, "end": 74.34, "word": " ألانين", "probability": 0.983154296875}, {"start": 74.34, "end": 74.98, "word": " جليسين", "probability": 0.958740234375}, {"start": 74.98, "end": 75.54, "word": " جليسين", "probability": 0.965576171875}, {"start": 75.54, "end": 75.74, "word": " are", "probability": 0.76220703125}, {"start": 75.74, "end": 76.38, "word": " structural", "probability": 0.79833984375}, {"start": 76.38, "end": 77.36, "word": " isomers", "probability": 0.9755859375}, {"start": 77.36, "end": 77.92, "word": " ايش", "probability": 0.675048828125}, {"start": 77.92, "end": 79.16, "word": " رأيكم؟", "probability": 0.87001953125}, {"start": 79.16, "end": 79.3, "word": " they", "probability": 0.69775390625}, {"start": 79.3, "end": 79.5, "word": " are", "probability": 0.94140625}, {"start": 79.5, "end": 79.78, "word": " not", "probability": 0.962890625}, {"start": 79.78, "end": 80.5, "word": " isomers", "probability": 0.9889322916666666}, {"start": 80.5, "end": 80.78, "word": " لأن", "probability": 0.87451171875}, {"start": 80.78, "end": 80.92, "word": " ال", "probability": 0.85205078125}, {"start": 80.92, "end": 81.66, "word": " isomers", "probability": 0.9002278645833334}, {"start": 81.66, "end": 82.06, "word": " لازم", "probability": 0.984375}, {"start": 82.06, "end": 82.4, "word": " يكونوا", "probability": 0.96923828125}, {"start": 82.4, "end": 83.02, "word": " مكونين", "probability": 0.8099609375}, {"start": 83.02, "end": 83.2, "word": " من", "probability": 0.99365234375}, {"start": 83.2, "end": 83.64, "word": " نفس", "probability": 0.997802734375}, {"start": 83.64, "end": 84.9, "word": " الأشياء", "probability": 0.992431640625}, {"start": 84.9, "end": 85.88, "word": " يعني", "probability": 0.918701171875}, {"start": 85.88, "end": 86.14, "word": " هذا", "probability": 0.51806640625}, {"start": 86.14, "end": 86.52, "word": " اتنين", "probability": 0.937744140625}, {"start": 86.52, "end": 86.94, "word": " ألانين", "probability": 0.985107421875}, {"start": 86.94, "end": 87.2, "word": " واحد", "probability": 0.7763671875}, {"start": 87.2, "end": 87.72, "word": " جليسين", "probability": 0.972412109375}, {"start": 87.72, "end": 87.92, "word": " هذا", "probability": 0.38525390625}, {"start": 87.92, "end": 88.26, "word": " اتنين", "probability": 0.974853515625}, {"start": 88.26, "end": 88.8, "word": " جليسين", "probability": 0.9827880859375}, {"start": 88.8, "end": 89.12, "word": " واحد", "probability": 0.95703125}, {"start": 89.12, "end": 89.62, "word": " ألانين", "probability": 0.9892578125}, {"start": 89.62, "end": 89.8, "word": " they", "probability": 0.86767578125}, {"start": 89.8, "end": 89.94, "word": " are", "probability": 0.95751953125}, {"start": 89.94, "end": 90.2, "word": " not", "probability": 0.96044921875}, {"start": 90.2, "end": 91.0, "word": " isomers", "probability": 0.9886067708333334}], "temperature": 1.0}, {"id": 4, "seek": 12120, "start": 92.02, "end": 121.2, "text": "they are different compounds a glucofuranose is an aldobentose واضح؟ إيش رأيكم؟ الفيورانوز خمسة لكن الجلوكوز ستة الجلوكوز", "tokens": [13162, 366, 819, 21810, 257, 19636, 2670, 12125, 541, 307, 364, 16798, 996, 317, 541, 4032, 46958, 5016, 22807, 11933, 1829, 8592, 12602, 10721, 1829, 24793, 22807, 27188, 1829, 13063, 7649, 2407, 11622, 16490, 2304, 3794, 3660, 44381, 25724, 1211, 2407, 4117, 2407, 11622, 8608, 2655, 3660, 25724, 1211, 2407, 4117, 2407, 11622], "avg_logprob": -0.25520834216365107, "compression_ratio": 1.2481751824817517, "no_speech_prob": 0.0, "words": [{"start": 92.02, "end": 92.24, "word": "they", "probability": 0.060302734375}, {"start": 92.24, "end": 92.36, "word": " are", "probability": 0.896484375}, {"start": 92.36, "end": 92.7, "word": " different", "probability": 0.931640625}, {"start": 92.7, "end": 93.3, "word": " compounds", "probability": 0.56884765625}, {"start": 93.3, "end": 93.98, "word": " a", "probability": 0.11572265625}, {"start": 93.98, "end": 95.76, "word": " glucofuranose", "probability": 0.9083251953125}, {"start": 95.76, "end": 96.38, "word": " is", "probability": 0.90673828125}, {"start": 96.38, "end": 96.78, "word": " an", "probability": 0.837890625}, {"start": 96.78, "end": 99.64, "word": " aldobentose", "probability": 0.78240966796875}, {"start": 99.64, "end": 103.14, "word": " واضح؟", "probability": 0.8182373046875}, {"start": 103.14, "end": 103.42, "word": " إيش", "probability": 0.7740071614583334}, {"start": 103.42, "end": 109.34, "word": " رأيكم؟", "probability": 0.9435546875}, {"start": 109.34, "end": 111.74, "word": " الفيورانوز", "probability": 0.8079020182291666}, {"start": 111.74, "end": 114.76, "word": " خمسة", "probability": 0.9283447265625}, {"start": 114.76, "end": 116.34, "word": " لكن", "probability": 0.78662109375}, {"start": 116.34, "end": 118.18, "word": " الجلوكوز", "probability": 0.8878580729166666}, {"start": 118.18, "end": 119.48, "word": " ستة", "probability": 0.9658203125}, {"start": 119.48, "end": 121.2, "word": " الجلوكوز", "probability": 0.9183756510416666}], "temperature": 1.0}, {"id": 5, "seek": 13769, "start": 124.86, "end": 137.7, "text": "لأ لما نقول جولوكوز، الجولوكوز مر علينا وين؟ في الالدوهيكسوزز؟ لأ هذا world", "tokens": [1211, 10721, 5296, 15042, 8717, 39648, 10874, 12610, 2407, 4117, 2407, 11622, 12399, 25724, 12610, 2407, 4117, 2407, 11622, 3714, 2288, 25894, 8315, 4032, 9957, 22807, 8978, 2423, 6027, 3215, 2407, 3224, 1829, 4117, 3794, 2407, 11622, 11622, 22807, 5296, 10721, 23758, 1002], "avg_logprob": -0.22514205087314954, "compression_ratio": 1.303921568627451, "no_speech_prob": 0.0, "words": [{"start": 124.86, "end": 125.46, "word": "لأ", "probability": 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"temperature": 1.0}, {"id": 6, "seek": 17855, "start": 149.91, "end": 178.55, "text": "الجلوكوز نفسه ست كربونات ولا خمسة؟ ستة، الان لما أنا هنا بقول خمسة، إذا هذا الكلام صح ولا غلط؟ غلط، لأنه الجلوكوز ستة مش خمسة، واضحة الفكرة؟ الجلوكوز ستة دلات كربون، مش خمسة The peptide bond is longer than normal C double bond N أو C N double bond، إيش رأيكوا؟", "tokens": [6027, 7435, 1211, 2407, 4117, 2407, 11622, 8717, 36178, 3224, 8608, 2655, 9122, 25513, 2407, 8315, 2655, 49429, 16490, 2304, 3794, 3660, 22807, 8608, 2655, 3660, 12399, 2423, 7649, 5296, 15042, 41850, 34105, 4724, 39648, 16490, 2304, 3794, 3660, 12399, 11933, 15730, 23758, 2423, 28820, 10943, 20328, 5016, 49429, 32771, 1211, 9566, 22807, 32771, 1211, 9566, 12399, 5296, 33456, 3224, 25724, 1211, 2407, 4117, 2407, 11622, 8608, 2655, 3660, 37893, 16490, 2304, 3794, 3660, 12399, 4032, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 25724, 1211, 2407, 4117, 2407, 11622, 8608, 2655, 3660, 11778, 1211, 9307, 9122, 25513, 11536, 12399, 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{"start": 206.51, "end": 206.89, "word": " الـO", "probability": 0.9296875}, {"start": 206.89, "end": 207.51, "word": " minus", "probability": 0.72900390625}, {"start": 207.51, "end": 208.53, "word": " صارت", "probability": 0.97509765625}], "temperature": 1.0}, {"id": 8, "seek": 22018, "start": 210.9, "end": 220.18, "text": "Double bond فهل ال peptide او الأمد double ولا single؟ لأ هي واحد و نص في النهاية", "tokens": [35, 33147, 6086, 6156, 3224, 1211, 2423, 41781, 482, 1975, 2407, 16247, 2304, 3215, 3834, 49429, 2167, 22807, 5296, 10721, 39896, 36764, 24401, 4032, 8717, 9381, 8978, 28239, 11296, 10632], "avg_logprob": -0.30695563362490746, "compression_ratio": 1.1359223300970873, "no_speech_prob": 0.0, "words": [{"start": 210.9, "end": 211.3, "word": "Double", "probability": 0.6458740234375}, {"start": 211.3, "end": 211.66, "word": " bond", "probability": 0.8193359375}, {"start": 211.66, "end": 212.2, "word": " فهل", "probability": 0.900390625}, {"start": 212.2, "end": 212.34, "word": " ال", "probability": 0.92919921875}, {"start": 212.34, "end": 213.02, "word": " peptide", "probability": 0.553955078125}, {"start": 213.02, "end": 214.04, "word": " او", "probability": 0.784423828125}, {"start": 214.04, "end": 214.52, "word": " الأمد", "probability": 0.6692708333333334}, {"start": 214.52, "end": 215.02, "word": " double", "probability": 0.6015625}, {"start": 215.02, "end": 215.48, "word": " ولا", "probability": 0.89892578125}, {"start": 215.48, "end": 217.26, "word": " single؟", "probability": 0.6490478515625}, {"start": 217.26, "end": 218.78, "word": " لأ", "probability": 0.803466796875}, {"start": 218.78, "end": 218.92, "word": " هي", "probability": 0.55078125}, {"start": 218.92, "end": 219.22, "word": " واحد", "probability": 0.89208984375}, {"start": 219.22, "end": 219.34, "word": " و", "probability": 0.98486328125}, {"start": 219.34, "end": 219.56, "word": " نص", "probability": 0.909423828125}, {"start": 219.56, "end": 219.7, "word": " في", "probability": 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264.24, "end": 264.52, "word": " من", "probability": 0.99755859375}, {"start": 264.52, "end": 264.88, "word": " ال", "probability": 0.9150390625}, {"start": 264.88, "end": 265.22, "word": " double", "probability": 0.96484375}, {"start": 265.22, "end": 265.52, "word": " bond", "probability": 0.97705078125}, {"start": 265.52, "end": 265.76, "word": " احنا", "probability": 0.8902994791666666}, {"start": 265.76, "end": 265.94, "word": " ايش", "probability": 0.8025716145833334}, {"start": 265.94, "end": 266.5, "word": " كاتبين", "probability": 0.97021484375}, {"start": 266.5, "end": 267.68, "word": " is", "probability": 0.66748046875}, {"start": 267.68, "end": 268.0, "word": " longer", "probability": 0.94775390625}, {"start": 268.0, "end": 268.76, "word": " than", "probability": 0.93896484375}, {"start": 268.76, "end": 269.46, "word": " c", "probability": 0.320556640625}, {"start": 269.46, "end": 269.74, "word": " double", "probability": 0.91259765625}, {"start": 269.74, "end": 270.08, "word": " bond", "probability": 0.95556640625}, {"start": 270.08, "end": 270.3, "word": " and", "probability": 0.90283203125}, {"start": 270.3, "end": 270.52, "word": " اذا", "probability": 0.661376953125}, {"start": 270.52, "end": 270.8, "word": " هذه", "probability": 0.7958984375}, {"start": 270.8, "end": 271.3, "word": " الجملة", "probability": 0.9576822916666666}, {"start": 271.3, "end": 272.48, "word": " صح", "probability": 0.98779296875}], "temperature": 1.0}, {"id": 11, "seek": 30070, "start": 273.53, "end": 300.71, "text": "واضح الفكرة؟ هذه بتعتمد على فهمكم للأمد resonance .. بتعتمد على فهمكم للأمد resonance Hydrolysis of starch produces only beta-glucopyranosis ال starch من أي سكة؟ من؟ كويس من أي ديساكراي؟ ملتوز .. الملتوز من إيش؟", "tokens": [2407, 46958, 5016, 27188, 4117, 25720, 22807, 29538, 39894, 34268, 2304, 3215, 15844, 6156, 16095, 4117, 2304, 24976, 10721, 2304, 3215, 30944, 4386, 39894, 34268, 2304, 3215, 15844, 6156, 16095, 24793, 24976, 10721, 2304, 3215, 30944, 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"probability": 0.73046875}, {"start": 277.37, "end": 277.87, "word": " resonance", "probability": 0.40576171875}, {"start": 277.87, "end": 277.99, "word": " ..", "probability": 0.08880615234375}, {"start": 277.99, "end": 278.49, "word": " بتعتمد", "probability": 0.897216796875}, {"start": 278.49, "end": 278.63, "word": " على", "probability": 0.89697265625}, {"start": 278.63, "end": 279.09, "word": " فهمكم", "probability": 0.8953450520833334}, {"start": 279.09, "end": 279.55, "word": " للأمد", "probability": 0.97412109375}, {"start": 279.55, "end": 280.01, "word": " resonance", "probability": 0.92626953125}, {"start": 280.01, "end": 281.17, "word": " Hydrolysis", "probability": 0.655548095703125}, {"start": 281.17, "end": 281.47, "word": " of", "probability": 0.96533203125}, {"start": 281.47, "end": 282.13, "word": " starch", "probability": 0.9130859375}, {"start": 282.13, "end": 282.95, "word": " produces", "probability": 0.826171875}, {"start": 282.95, "end": 283.99, "word": " only", 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وأو", "probability": 0.85205078125}, {"start": 315.33, "end": 316.13, "word": " بيتا", "probability": 0.9752604166666666}, {"start": 316.13, "end": 316.79, "word": " ملتوز", "probability": 0.8182861328125}, {"start": 316.79, "end": 317.01, "word": " ألف", "probability": 0.966064453125}, {"start": 317.01, "end": 317.15, "word": " وأو", "probability": 0.77197265625}, {"start": 317.15, "end": 317.65, "word": " بيتا", "probability": 0.98046875}, {"start": 317.65, "end": 318.15, "word": " the", "probability": 0.29150390625}, {"start": 318.15, "end": 318.61, "word": " OH", "probability": 0.85791015625}, {"start": 318.61, "end": 318.89, "word": " of", "probability": 0.71435546875}, {"start": 318.89, "end": 319.03, "word": " the", "probability": 0.8525390625}, {"start": 319.03, "end": 319.59, "word": " anomeric", "probability": 0.7791341145833334}, {"start": 319.59, "end": 319.95, "word": " carbon", "probability": 0.9599609375}, {"start": 319.95, "end": 320.25, "word": " of", "probability": 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"text": "مشقولنا انه ليش بيكون ال beta نسبته اعلى من ال alpha لأنه ال beta في ال equatorial position مافيش عليها steric hindrance داي تيربين are composed of twenty carbon atoms الان ال mono terbin اكم ايزو برين unit تنتين الداي تيربين اكم ايزو برين unit اربع اربع في خمسة", "tokens": [2304, 8592, 39648, 8315, 16472, 3224, 32239, 8592, 4724, 1829, 30544, 2423, 9861, 8717, 35457, 47395, 1975, 3615, 23942, 9154, 2423, 8961, 5296, 33456, 3224, 2423, 9861, 8978, 2423, 45544, 831, 2535, 19446, 41185, 8592, 25894, 11296, 18924, 299, 20138, 32493, 11778, 47302, 6055, 13546, 3555, 9957, 366, 18204, 295, 7699, 5954, 16871, 2423, 7649, 2423, 35624, 1796, 13496, 1975, 24793, 1975, 1829, 11622, 2407, 4724, 16572, 1863, 4985, 6055, 29399, 9957, 32748, 47302, 6055, 13546, 3555, 9957, 1975, 24793, 1975, 1829, 11622, 2407, 4724, 16572, 1863, 4985, 1975, 25513, 3615, 1975, 25513, 3615, 8978, 16490, 2304, 3794, 3660], "avg_logprob": -0.314999994635582, "compression_ratio": 1.6754385964912282, 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{"start": 358.35, "end": 358.91, "word": " خمسة", "probability": 0.96923828125}], "temperature": 1.0}, {"id": 14, "seek": 38728, "start": 362.46, "end": 387.28, "text": "hydrogenation of oils is a saponification reaction هدرجة الزيوت بتحول ال double bond إلى single bond بتحول ال oil إلى fat ال saponification reaction بيعمل hydrolysis فهدرجة الزيوت مش تفاعل", "tokens": [21591, 7747, 399, 295, 22177, 307, 257, 18985, 266, 3774, 5480, 8032, 3215, 47341, 3660, 6024, 110, 1829, 35473, 39894, 5016, 12610, 2423, 3834, 6086, 30731, 2167, 6086, 39894, 5016, 12610, 2423, 3184, 30731, 4046, 2423, 18985, 266, 3774, 5480, 4724, 1829, 25957, 1211, 15435, 356, 17122, 6156, 3224, 3215, 47341, 3660, 6024, 110, 1829, 35473, 37893, 6055, 5172, 995, 30241], "avg_logprob": -0.1902721815051571, "compression_ratio": 1.5806451612903225, "no_speech_prob": 0.0, "words": [{"start": 362.46, "end": 363.48, "word": "hydrogenation", "probability": 0.779296875}, {"start": 363.48, "end": 363.7, "word": " of", "probability": 0.94970703125}, {"start": 363.7, "end": 364.52, "word": " oils", "probability": 0.77880859375}, {"start": 364.52, "end": 367.3, "word": " is", "probability": 0.426025390625}, {"start": 367.3, "end": 367.58, "word": " a", "probability": 0.75341796875}, {"start": 367.58, "end": 368.52, "word": " saponification", "probability": 0.8250325520833334}, {"start": 368.52, "end": 369.86, "word": " reaction", "probability": 0.8876953125}, {"start": 369.86, "end": 372.88, "word": " هدرجة", "probability": 0.81134033203125}, {"start": 372.88, "end": 373.48, "word": " الزيوت", "probability": 0.947021484375}, {"start": 373.48, "end": 374.38, "word": " بتحول", "probability": 0.9235026041666666}, {"start": 374.38, "end": 374.94, "word": " ال", "probability": 0.7490234375}, {"start": 374.94, "end": 375.22, "word": " double", "probability": 0.281005859375}, {"start": 375.22, "end": 375.72, "word": " bond", "probability": 0.90087890625}, {"start": 375.72, "end": 376.14, "word": " إلى", "probability": 0.63037109375}, {"start": 376.14, "end": 377.26, "word": " single", "probability": 0.91650390625}, {"start": 377.26, "end": 377.6, "word": " bond", "probability": 0.9560546875}, {"start": 377.6, "end": 378.28, "word": " بتحول", "probability": 0.8257649739583334}, {"start": 378.28, "end": 378.82, "word": " ال", "probability": 0.775390625}, {"start": 378.82, "end": 379.36, "word": " oil", "probability": 0.96630859375}, {"start": 379.36, "end": 379.9, "word": " إلى", "probability": 0.962890625}, {"start": 379.9, "end": 380.78, "word": " fat", "probability": 0.4716796875}, {"start": 380.78, "end": 381.16, "word": " ال", "probability": 0.419189453125}, {"start": 381.16, "end": 381.92, "word": " saponification", "probability": 0.9189453125}, {"start": 381.92, "end": 382.38, "word": " reaction", "probability": 0.9111328125}, {"start": 382.38, "end": 382.82, "word": " بيعمل", "probability": 0.9129638671875}, {"start": 382.82, "end": 383.86, "word": " hydrolysis", "probability": 0.8328450520833334}, {"start": 383.86, "end": 385.42, "word": " فهدرجة", "probability": 0.9048828125}, {"start": 385.42, "end": 386.06, "word": " الزيوت", "probability": 0.9676513671875}, {"start": 386.06, "end": 386.52, "word": " مش", "probability": 0.98828125}, {"start": 386.52, "end": 387.28, "word": " تفاعل", "probability": 0.9696044921875}], "temperature": 1.0}, {"id": 15, "seek": 41615, "start": 388.81, "end": 416.15, "text": "سابونفكاشن السابونفكاشن ان اخد الـ triglyceride احوله الى soap الى salt of the fatty acid واضح ان احول الزيت الى سابون ان اعمل hydrolysis الان هل ال hydrogenation عمل hydrolysis ولا تحويل double bond ل single bond اه اذا ال hydrogenation is سابونفكاشن reaction غلط", "tokens": [3794, 16758, 11536, 5172, 4117, 33599, 1863, 21136, 16758, 11536, 5172, 4117, 33599, 1863, 16472, 1975, 9778, 3215, 2423, 39184, 35386, 356, 1776, 482, 1975, 5016, 12610, 3224, 2423, 7578, 14587, 2423, 7578, 5139, 295, 264, 24898, 8258, 4032, 46958, 5016, 16472, 1975, 5016, 12610, 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0.8438720703125}, {"start": 393.19, "end": 393.79, "word": " احوله", "probability": 0.8685302734375}, {"start": 393.79, "end": 394.25, "word": " الى", "probability": 0.6905517578125}, {"start": 394.25, "end": 394.73, "word": " soap", "probability": 0.13525390625}, {"start": 394.73, "end": 395.15, "word": " الى", "probability": 0.86328125}, {"start": 395.15, "end": 395.57, "word": " salt", "probability": 0.34033203125}, {"start": 395.57, "end": 395.87, "word": " of", "probability": 0.9560546875}, {"start": 395.87, "end": 396.09, "word": " the", "probability": 0.8935546875}, {"start": 396.09, "end": 396.39, "word": " fatty", "probability": 0.9306640625}, {"start": 396.39, "end": 397.01, "word": " acid", "probability": 0.93212890625}, {"start": 397.01, "end": 397.91, "word": " واضح", "probability": 0.93017578125}, {"start": 397.91, "end": 399.99, "word": " ان", "probability": 0.6845703125}, {"start": 399.99, "end": 400.47, "word": " احول", "probability": 0.939453125}, {"start": 400.47, "end": 401.19, "word": " الزيت", "probability": 0.8806966145833334}, {"start": 401.19, "end": 401.89, "word": " الى", "probability": 0.935302734375}, {"start": 401.89, "end": 403.03, "word": " سابون", "probability": 0.9366861979166666}, {"start": 403.03, "end": 403.43, "word": " ان", "probability": 0.86328125}, {"start": 403.43, "end": 403.77, "word": " اعمل", "probability": 0.98876953125}, {"start": 403.77, "end": 404.73, "word": " hydrolysis", "probability": 0.7613118489583334}, {"start": 404.73, "end": 405.37, "word": " الان", "probability": 0.76513671875}, {"start": 405.37, "end": 405.59, "word": " هل", "probability": 0.962158203125}, {"start": 405.59, "end": 405.69, "word": " ال", "probability": 0.9833984375}, {"start": 405.69, "end": 406.49, "word": " hydrogenation", "probability": 0.7578125}, {"start": 406.49, "end": 406.79, "word": " عمل", "probability": 0.965087890625}, {"start": 406.79, "end": 407.63, "word": " hydrolysis", "probability": 0.8889973958333334}, {"start": 407.63, "end": 408.05, "word": " ولا", "probability": 0.716796875}, {"start": 408.05, "end": 408.45, "word": " تحويل", "probability": 0.9189453125}, {"start": 408.45, "end": 408.71, "word": " double", "probability": 0.78564453125}, {"start": 408.71, "end": 408.97, "word": " bond", "probability": 0.93408203125}, {"start": 408.97, "end": 409.13, "word": " ل", "probability": 0.974609375}, {"start": 409.13, "end": 409.47, "word": " single", "probability": 0.92626953125}, {"start": 409.47, "end": 409.93, "word": " bond", "probability": 0.95166015625}, {"start": 409.93, "end": 411.31, "word": " اه", "probability": 0.4609375}, {"start": 411.31, "end": 411.45, "word": " اذا", "probability": 0.7646484375}, {"start": 411.45, "end": 411.57, "word": " ال", "probability": 0.576171875}, {"start": 411.57, "end": 412.31, "word": " hydrogenation", "probability": 0.92138671875}, {"start": 412.31, "end": 412.61, "word": " is", "probability": 0.431396484375}, {"start": 412.61, "end": 414.25, "word": " 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23557, 2423, 25252, 2423, 15577, 2423, 497, 3935, 6055, 3555, 34268, 16095, 3714, 29245, 23328, 3660, 24976, 3215, 47283, 1211, 35525, 8848, 23275, 29538, 25724, 2304, 37977, 32771, 1211, 9566, 4032, 46958, 5016, 2423, 7649, 3566, 264, 3480, 12363, 8717, 28480, 3615, 13412, 2407, 10632], "avg_logprob": -0.208750002682209, "compression_ratio": 1.2732919254658386, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 439.71, "end": 440.33, "word": "جوا", "probability": 0.4991455078125}, {"start": 440.33, "end": 441.31, "word": " مش", "probability": 0.69580078125}, {"start": 441.31, "end": 441.73, "word": " برا", "probability": 0.962646484375}, {"start": 441.73, "end": 442.07, "word": " ال", "probability": 0.87548828125}, {"start": 442.07, "end": 442.45, "word": " fibers", "probability": 0.1954345703125}, {"start": 442.45, "end": 442.81, "word": " ال", "probability": 0.744140625}, {"start": 442.81, "end": 443.39, "word": " proteins", "probability": 0.93408203125}, {"start": 443.39, "end": 444.01, "word": " ال", "probability": 0.78466796875}, {"start": 444.01, "end": 444.23, "word": " R", "probability": 0.7353515625}, {"start": 444.23, "end": 444.59, "word": " groups", "probability": 0.58056640625}, {"start": 444.59, "end": 445.29, "word": " تبعتهم", "probability": 0.8408203125}, {"start": 445.29, "end": 446.23, "word": " موجودة", "probability": 0.9705810546875}, {"start": 446.23, "end": 446.89, "word": " للداخل", "probability": 0.9632568359375}, {"start": 446.89, "end": 447.35, "word": " ولذلك", "probability": 0.8177083333333334}, {"start": 447.35, "end": 447.61, "word": " هذه", "probability": 0.91259765625}, {"start": 447.61, "end": 448.11, "word": " الجملة", "probability": 0.9615885416666666}, {"start": 448.11, "end": 449.33, "word": " غلط", "probability": 0.9851888020833334}, {"start": 449.33, "end": 450.57, "word": " واضح", "probability": 0.8810221354166666}, {"start": 450.57, "end": 452.97, "word": " الان", "probability": 0.6429443359375}, {"start": 452.97, "end": 453.45, "word": " complete", "probability": 0.728515625}, {"start": 453.45, "end": 454.01, "word": " the", "probability": 0.85888671875}, {"start": 454.01, "end": 454.39, "word": " following", "probability": 0.87353515625}, {"start": 454.39, "end": 455.37, "word": " statements", "probability": 0.8740234375}, {"start": 455.37, "end": 457.93, "word": " نرفع", "probability": 0.9353841145833334}, {"start": 457.93, "end": 458.45, "word": " شوية", "probability": 0.9230143229166666}], "temperature": 1.0}, {"id": 18, "seek": 49417, "start": 465.75, "end": 494.17, "text": "الدياستيريوم الذين يختلفون فقط في مركز واحد كيرال يسمون ابيمارز ابيمارز اسم الكيميائي لاسبيرين اسيتل ساليسينك أسد باراسيتامول أيضا يسمون", "tokens": [6027, 16254, 995, 14851, 13546, 1829, 20498, 2423, 8848, 9957, 7251, 46456, 46538, 11536, 6156, 47432, 8978, 3714, 31747, 11622, 36764, 24401, 9122, 13546, 6027, 7251, 38251, 11536, 48127, 32640, 9640, 11622, 48127, 32640, 9640, 11622, 24525, 2304, 33251, 32640, 1829, 16373, 1829, 5296, 32277, 3555, 13546, 9957, 24525, 36081, 1211, 8608, 6027, 1829, 3794, 9957, 4117, 5551, 3794, 3215, 4724, 9640, 32277, 36081, 10943, 12610, 36632, 11242, 995, 7251, 38251, 11536], "avg_logprob": -0.5706335747078674, "compression_ratio": 1.7943262411347518, "no_speech_prob": 0.0, "words": [{"start": 465.75, "end": 466.65, "word": "الدياستيريوم", "probability": 0.58740234375}, {"start": 466.65, "end": 467.05, "word": " الذين", "probability": 0.4650065104166667}, {"start": 467.05, "end": 467.55, "word": " يختلفون", "probability": 0.795166015625}, {"start": 467.55, "end": 468.55, "word": " فقط", "probability": 0.77294921875}, {"start": 468.55, "end": 468.85, "word": " في", "probability": 0.91552734375}, {"start": 468.85, "end": 468.95, "word": " مركز", "probability": 0.6446126302083334}, {"start": 468.95, "end": 469.09, "word": " واحد", "probability": 0.6318359375}, {"start": 469.09, "end": 469.63, "word": " كيرال", "probability": 0.4683024088541667}, {"start": 469.63, 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Cyclopentane كيف ال Cyclopentane؟ في حد بعرفهش؟ بدنا نعمل فيه", "tokens": [1211, 5016, 19913, 3660, 44945, 11622, 1211, 6156, 1863, 1211, 5995, 17, 44945, 11622, 1211, 2423, 9403, 383, 343, 6086, 422, 422, 497, 4032, 46958, 5016, 4724, 1829, 35473, 9957, 4032, 5718, 255, 3660, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 732, 4724, 1829, 35473, 9957, 4032, 1975, 2655, 1863, 9957, 23758, 9673, 31747, 3555, 39627, 3215, 2407, 38207, 44945, 2304, 8592, 1829, 8978, 3224, 16490, 9566, 2407, 3660, 16490, 9566, 2407, 3660, 44945, 2288, 38251, 3224, 49173, 404, 317, 1929, 9122, 33911, 2423, 49173, 404, 317, 1929, 22807, 8978, 11331, 3215, 45030, 28480, 3224, 8592, 22807, 47525, 8315, 8717, 25957, 1211, 8978, 3224], "avg_logprob": -0.28612385430467235, "compression_ratio": 1.5970873786407767, "no_speech_prob": 0.0, "words": [{"start": 945.21, "end": 946.09, "word": "لحظة", "probability": 0.691650390625}, {"start": 946.09, "end": 946.97, "word": " بنزل", "probability": 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8032, 995, 16254, 8032, 995, 16254, 39894, 9381, 13546, 13931, 7251, 7435, 9957, 1829], "avg_logprob": -0.5554687768220902, "compression_ratio": 1.194915254237288, "no_speech_prob": 0.0, "words": [{"start": 1478.37, "end": 1478.97, "word": "الان", "probability": 0.656982421875}, {"start": 1478.97, "end": 1479.61, "word": " acid", "probability": 0.236328125}, {"start": 1479.61, "end": 1480.47, "word": " chloride", "probability": 0.9697265625}, {"start": 1480.47, "end": 1481.03, "word": " مع", "probability": 0.45263671875}, {"start": 1481.03, "end": 1481.43, "word": " green", "probability": 0.121826171875}, {"start": 1481.43, "end": 1481.85, "word": " yard", "probability": 0.285888671875}, {"start": 1481.85, "end": 1483.19, "word": " reagent", "probability": 0.6807861328125}, {"start": 1483.19, "end": 1486.53, "word": " تير", "probability": 0.4322509765625}, {"start": 1486.53, "end": 1487.03, "word": " تشيري", "probability": 0.64923095703125}, {"start": 1487.03, "end": 1487.57, "word": " ألكول", "probability": 0.5675455729166666}, {"start": 1487.57, "end": 1487.85, "word": " هاي", "probability": 0.482666015625}, {"start": 1487.85, "end": 1488.03, "word": " ال", "probability": 0.89208984375}, {"start": 1488.03, "end": 1488.23, "word": " C", "probability": 0.38525390625}, {"start": 1488.23, "end": 1488.69, "word": " هادي", "probability": 0.7032063802083334}, {"start": 1488.69, "end": 1489.13, "word": " هادي", "probability": 0.9609375}, {"start": 1489.13, "end": 1489.57, "word": " هادي", "probability": 0.84375}, {"start": 1489.57, "end": 1490.53, "word": " بتصير", "probability": 0.72900390625}, {"start": 1490.53, "end": 1491.79, "word": " OH", "probability": 0.334228515625}, {"start": 1491.79, "end": 1492.51, "word": " يجيني", "probability": 0.690704345703125}], "temperature": 1.0}, {"id": 55, "seek": 151620, "start": 1494.1, "end": 1516.2, "text": "مجمعتين فنل على مرتين هيتفاعل أول اشي بيعطيني ال ketone أول ما تاجم الفنل هنا محل ال CL بيعطيني ال ketone و بكمل ل tertiary alcohol أخدنا ال Easter و ال acid chloride مع Greenyard شو بيعطوني؟ tertiary alcohol و بال reduction؟ primary alcohol الان", "tokens": [2304, 7435, 2304, 34268, 9957, 6156, 1863, 1211, 15844, 3714, 43500, 9957, 8032, 36081, 5172, 995, 30241, 5551, 12610, 1975, 8592, 1829, 4724, 40228, 9566, 1829, 22653, 2423, 14979, 546, 5551, 12610, 19446, 6055, 26108, 2304, 27188, 1863, 1211, 34105, 3714, 5016, 1211, 2423, 12855, 4724, 40228, 9566, 1829, 22653, 2423, 14979, 546, 4032, 4724, 24793, 1211, 5296, 38726, 29104, 7658, 5551, 9778, 3215, 8315, 2423, 9403, 4032, 2423, 8258, 35434, 20449, 6969, 13862, 13412, 2407, 4724, 40228, 9566, 11536, 1829, 22807, 38726, 29104, 7658, 4032, 20666, 11004, 22807, 6194, 7658, 2423, 7649], "avg_logprob": -0.2588098442300837, "compression_ratio": 1.6619718309859155, "no_speech_prob": 0.0, "words": [{"start": 1494.1, "end": 1495.02, "word": "مجمعتين", "probability": 0.87568359375}, {"start": 1495.02, "end": 1495.4, "word": " فنل", "probability": 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"probability": 0.9493815104166666}, {"start": 1500.18, "end": 1500.44, "word": " هنا", "probability": 0.70263671875}, {"start": 1500.44, "end": 1500.78, "word": " محل", "probability": 0.91845703125}, {"start": 1500.78, "end": 1500.94, "word": " ال", "probability": 0.96484375}, {"start": 1500.94, "end": 1501.18, "word": " CL", "probability": 0.48046875}, {"start": 1501.18, "end": 1501.68, "word": " بيعطيني", "probability": 0.90185546875}, {"start": 1501.68, "end": 1501.8, "word": " ال", "probability": 0.8701171875}, {"start": 1501.8, "end": 1502.44, "word": " ketone", "probability": 0.9091796875}, {"start": 1502.44, "end": 1502.84, "word": " و", "probability": 0.72265625}, {"start": 1502.84, "end": 1503.34, "word": " بكمل", "probability": 0.8712565104166666}, {"start": 1503.34, "end": 1503.46, "word": " ل", "probability": 0.5458984375}, {"start": 1503.46, "end": 1503.98, "word": " tertiary", "probability": 0.874755859375}, {"start": 1503.98, "end": 1504.46, "word": " alcohol", "probability": 0.86572265625}, {"start": 1504.46, "end": 1505.22, "word": " أخدنا", "probability": 0.9481201171875}, {"start": 1505.22, "end": 1505.44, "word": " ال", "probability": 0.9140625}, {"start": 1505.44, "end": 1505.9, "word": " Easter", "probability": 0.372314453125}, {"start": 1505.9, "end": 1506.48, "word": " و", "probability": 0.86376953125}, {"start": 1506.48, "end": 1506.64, "word": " ال", "probability": 0.95263671875}, {"start": 1506.64, "end": 1506.92, "word": " acid", "probability": 0.78515625}, {"start": 1506.92, "end": 1507.54, "word": " chloride", "probability": 0.97265625}, {"start": 1507.54, "end": 1507.78, "word": " مع", "probability": 0.9833984375}, {"start": 1507.78, "end": 1508.48, "word": " Greenyard", "probability": 0.4671630859375}, {"start": 1508.48, "end": 1508.66, "word": " شو", "probability": 0.810546875}, {"start": 1508.66, "end": 1510.02, "word": " بيعطوني؟", "probability": 0.8420003255208334}, {"start": 1510.02, "end": 1510.58, "word": " tertiary", "probability": 0.935791015625}, {"start": 1510.58, "end": 1511.16, "word": " alcohol", "probability": 0.892578125}, {"start": 1511.16, "end": 1511.56, "word": " و", "probability": 0.8720703125}, {"start": 1511.56, "end": 1511.72, "word": " بال", "probability": 0.97900390625}, {"start": 1511.72, "end": 1513.22, "word": " reduction؟", "probability": 0.7275390625}, {"start": 1513.22, "end": 1514.36, "word": " primary", "probability": 0.477783203125}, {"start": 1514.36, "end": 1515.22, "word": " alcohol", "probability": 0.87939453125}, {"start": 1515.22, "end": 1516.2, "word": " الان", "probability": 0.5887451171875}], "temperature": 1.0}, {"id": 56, "seek": 154831, "start": 1521.25, "end": 1548.31, "text": "هذا الـ Acid chloride مع Sodium Benzoyate بدنا واحدة شاطرة تقولنا كيف شكل Sodium Benzoyate فنل C double bond O O minus N A plus لاحظوا هنا لما قلت O minus و هذا Acid chloride صار تحضير ايش الـ Unsymmetrical anhydride ان هذه تهاجمها", "tokens": [3224, 15730, 2423, 39184, 5097, 327, 35434, 20449, 42059, 2197, 3964, 89, 939, 473, 47525, 8315, 36764, 24401, 3660, 13412, 41193, 25720, 6055, 39648, 8315, 9122, 33911, 13412, 28820, 42059, 2197, 3964, 89, 939, 473, 6156, 1863, 1211, 383, 3834, 6086, 422, 422, 3175, 426, 316, 1804, 20193, 5016, 19913, 14407, 34105, 5296, 15042, 12174, 1211, 2655, 422, 3175, 4032, 23758, 5097, 327, 35434, 20328, 9640, 6055, 5016, 11242, 13546, 1975, 1829, 8592, 2423, 39184, 1156, 3187, 2174, 32283, 364, 21591, 25502, 16472, 29538, 6055, 3224, 26108, 2304, 11296], "avg_logprob": -0.3321180684698953, "compression_ratio": 1.4292237442922375, "no_speech_prob": 0.0, "words": [{"start": 1521.25, "end": 1521.85, "word": "هذا", "probability": 0.86376953125}, {"start": 1521.85, "end": 1523.05, "word": " الـ", "probability": 0.482421875}, {"start": 1523.05, "end": 1523.37, "word": " Acid", "probability": 0.56396484375}, {"start": 1523.37, "end": 1523.73, "word": " chloride", "probability": 0.62060546875}, {"start": 1523.73, "end": 1524.09, "word": " مع", "probability": 0.94140625}, {"start": 1524.09, "end": 1524.59, "word": " Sodium", "probability": 0.845947265625}, {"start": 1524.59, "end": 1525.35, "word": " Benzoyate", "probability": 0.692138671875}, {"start": 1525.35, "end": 1525.85, "word": " بدنا", "probability": 0.56268310546875}, {"start": 1525.85, "end": 1526.19, "word": " واحدة", "probability": 0.9261067708333334}, {"start": 1526.19, "end": 1526.53, "word": " شاطرة", "probability": 0.9122721354166666}, {"start": 1526.53, "end": 1526.87, "word": " تقولنا", "probability": 0.9684244791666666}, {"start": 1526.87, "end": 1527.05, "word": " كيف", "probability": 0.968994140625}, {"start": 1527.05, "end": 1527.33, "word": " شكل", "probability": 0.9921875}, {"start": 1527.33, "end": 1527.85, "word": " Sodium", "probability": 0.77783203125}, {"start": 1527.85, "end": 1528.47, "word": " Benzoyate", "probability": 0.9093017578125}, {"start": 1528.47, "end": 1530.01, "word": " فنل", "probability": 0.6074625651041666}, {"start": 1530.01, "end": 1531.19, "word": " C", "probability": 0.296142578125}, {"start": 1531.19, "end": 1531.53, "word": " double", "probability": 0.330078125}, {"start": 1531.53, "end": 1531.93, "word": " bond", "probability": 0.892578125}, {"start": 1531.93, "end": 1532.35, "word": " O", "probability": 0.87548828125}, {"start": 1532.35, "end": 1533.75, "word": " O", "probability": 0.6396484375}, {"start": 1533.75, "end": 1534.37, "word": " minus", "probability": 0.71142578125}, {"start": 1534.37, "end": 1535.89, "word": " N", "probability": 0.2056884765625}, {"start": 1535.89, "end": 1536.15, "word": " A", "probability": 0.75927734375}, {"start": 1536.15, "end": 1536.81, "word": " plus", "probability": 0.60791015625}, {"start": 1536.81, "end": 1537.47, "word": " لاحظوا", "probability": 0.85626220703125}, {"start": 1537.47, "end": 1537.71, "word": " هنا", "probability": 0.6220703125}, {"start": 1537.71, "end": 1537.99, "word": " لما", "probability": 0.803955078125}, {"start": 1537.99, "end": 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"word": " Ketone", "probability": 0.80029296875}, {"start": 2006.8, "end": 2008.14, "word": " ال", "probability": 0.75048828125}, {"start": 2008.14, "end": 2008.56, "word": " Ketone", "probability": 0.791015625}, {"start": 2008.56, "end": 2009.88, "word": " يختزل", "probability": 0.966064453125}, {"start": 2009.88, "end": 2013.36, "word": " آه", "probability": 0.6495361328125}], "temperature": 1.0}, {"id": 74, "seek": 204070, "start": 2013.96, "end": 2040.7, "text": "اذا كيتون كحول الكين و اوزونوليس اتبع اكسيداشيا او ممكن تستعمل كمان او فور برضه اتش بلس بتعمل نفس الشي واضح هذا في طريقة تحضير الأحمار لما قولنا كيف بنكسر ال double bond او ال triple bond كمان ممكن نكسرها و اش تعطينا حامض", "tokens": [45636, 995, 9122, 36081, 11536, 9122, 5016, 12610, 2423, 4117, 9957, 4032, 1975, 2407, 11622, 11536, 12610, 1829, 3794, 1975, 2655, 3555, 3615, 1975, 4117, 3794, 25708, 33599, 25528, 1975, 2407, 3714, 43020, 6055, 14851, 25957, 1211, 9122, 2304, 7649, 1975, 2407, 6156, 13063, 4724, 43042, 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شغلتين القلانين شو المجموعة اللي هنا CH3 وهي ال amino terminal وهنا بدو يكون عندكم NH الستين شو المجموعة CH2SH وهنا بدو يكون", "tokens": [6027, 7649, 4724, 16254, 12174, 1211, 7649, 9957, 2423, 14851, 9957, 31439, 2423, 4724, 1829, 3555, 2655, 995, 25708, 1975, 1829, 8592, 426, 11717, 46, 4032, 24793, 7649, 426, 11717, 46, 2423, 7649, 8032, 47302, 4724, 1829, 3555, 2655, 995, 25708, 9154, 13412, 17082, 1211, 2655, 9957, 25062, 1211, 7649, 9957, 13412, 2407, 9673, 7435, 2304, 2407, 27884, 13672, 1829, 34105, 5995, 18, 37037, 1829, 2423, 24674, 14709, 37037, 8315, 47525, 2407, 7251, 30544, 43242, 24793, 31118, 2423, 14851, 9957, 13412, 2407, 9673, 7435, 2304, 2407, 27884, 5995, 17, 17308, 37037, 8315, 47525, 2407, 7251, 30544], "avg_logprob": -0.28237756748789367, "compression_ratio": 1.8764044943820224, "no_speech_prob": 0.0, "words": [{"start": 2072.05, "end": 2072.43, "word": "الان", "probability": 0.848876953125}, {"start": 2072.43, "end": 2072.67, "word": " بدي", "probability": 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"word": "الـ", "probability": 0.3760986328125}, {"start": 2102.39, "end": 2102.73, "word": " Acid", "probability": 0.5343017578125}, {"start": 2102.73, "end": 2103.41, "word": " Terminal", "probability": 0.78271484375}, {"start": 2103.41, "end": 2105.43, "word": " فلاحظوا", "probability": 0.90546875}, {"start": 2105.43, "end": 2105.57, "word": " الـ", "probability": 0.51904296875}, {"start": 2105.57, "end": 2105.97, "word": " peptide", "probability": 0.824951171875}, {"start": 2105.97, "end": 2106.13, "word": " لما", "probability": 0.843017578125}, {"start": 2106.13, "end": 2106.35, "word": " بدي", "probability": 0.6580810546875}, {"start": 2106.35, "end": 2106.67, "word": " أرسم", "probability": 0.7623697916666666}, {"start": 2106.67, "end": 2106.91, "word": " بدي", "probability": 0.6563720703125}, {"start": 2106.91, "end": 2107.25, "word": " أبدأ", "probability": 0.9567057291666666}, {"start": 2107.25, "end": 2107.75, "word": " بالهيكل", "probability": 0.903564453125}, {"start": 2107.75, "end": 2108.23, "word": " تبعه", "probability": 0.875244140625}, {"start": 2108.23, "end": 2108.61, "word": " N", "probability": 0.276611328125}, {"start": 2108.61, "end": 2109.41, "word": " C", "probability": 0.11859130859375}, {"start": 2109.41, "end": 2109.97, "word": " C", "probability": 0.64111328125}, {"start": 2109.97, "end": 2110.19, "word": " double", "probability": 0.347412109375}, {"start": 2110.19, "end": 2110.49, "word": " bond", "probability": 0.91748046875}, {"start": 2110.49, "end": 2110.73, "word": " O", "probability": 0.9580078125}, {"start": 2110.73, "end": 2111.17, "word": " و", "probability": 0.7158203125}, {"start": 2111.17, "end": 2111.49, "word": " N", "probability": 0.67822265625}, {"start": 2111.49, "end": 2112.07, "word": " C", "probability": 0.96337890625}, {"start": 2112.07, "end": 2112.51, "word": " C", "probability": 0.95458984375}, {"start": 2112.51, "end": 2112.75, "word": " double", "probability": 0.89013671875}, {"start": 2112.75, "end": 2113.05, "word": " bond", "probability": 0.9736328125}, {"start": 2113.05, "end": 2113.35, "word": " O", "probability": 0.98583984375}, {"start": 2113.35, "end": 2113.85, "word": " الآن", "probability": 0.56689453125}, {"start": 2113.85, "end": 2114.07, "word": " إذا", "probability": 0.9130859375}, {"start": 2114.07, "end": 2114.51, "word": " بحكي", "probability": 0.9613037109375}, {"start": 2114.51, "end": 2114.77, "word": " عن", "probability": 0.98486328125}, {"start": 2114.77, "end": 2115.33, "word": " الانين", "probability": 0.7244873046875}, {"start": 2115.33, "end": 2115.57, "word": " بدي", "probability": 0.654052734375}, {"start": 2115.57, "end": 2115.77, "word": " أحط", "probability": 0.7593587239583334}, {"start": 2115.77, "end": 2116.23, "word": " مثل", "probability": 0.990234375}, {"start": 2116.23, "end": 2116.89, "word": " بحكي", "probability": 0.9471435546875}, {"start": 2116.89, "end": 2117.11, "word": " عن", "probability": 0.97509765625}, {"start": 2117.11, "end": 2118.07, "word": " سيستين", "probability": 0.7730712890625}, {"start": 2118.07, "end": 2119.39, "word": " بدي", "probability": 0.876708984375}, {"start": 2119.39, "end": 2120.45, "word": " أحط", "probability": 0.953125}, {"start": 2120.45, "end": 2122.15, "word": " CH2SH", "probability": 0.890625}], "temperature": 1.0}, {"id": 78, "seek": 215132, "start": 2123.24, "end": 2151.32, "text": "واضح الفكرة؟ هى صار عند ال بيبتايد و amino terminal و acid terminal الآن بدنا نيجي بعد هيك نقول هذا ال بيبتايد خلينا نفعله مع ال methanol و H plus لاحظوا ال بيبتايد إله acid terminal ولا لأ؟ acid .. acid زاد alcohol", "tokens": [2407, 46958, 5016, 27188, 4117, 25720, 22807, 8032, 7578, 20328, 9640, 43242, 2423, 4724, 1829, 3555, 2655, 995, 25708, 4032, 24674, 14709, 4032, 8258, 14709, 6024, 48506, 47525, 8315, 8717, 1829, 7435, 1829, 39182, 39896, 4117, 8717, 39648, 23758, 2423, 4724, 1829, 3555, 2655, 995, 25708, 16490, 1211, 9957, 995, 8717, 5172, 30241, 3224, 20449, 2423, 1131, 35735, 4032, 389, 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نوضح فيه و نقول C double bond O و من الميثانول شو هيحط اوميثيل كل ال بيبتايد زي ما هو كاملة C double bond O اوميثيل", "tokens": [10721, 3794, 3215, 30767, 16373, 3215, 5551, 23275, 2407, 3224, 12610, 11933, 1829, 14851, 2288, 11933, 15730, 41850, 4724, 16254, 5551, 7435, 1829, 3555, 28242, 23758, 4724, 1211, 33599, 8717, 4587, 22488, 8717, 2407, 11242, 5016, 8978, 3224, 4032, 8717, 39648, 383, 3834, 6086, 422, 4032, 9154, 9673, 1829, 12984, 7649, 12610, 13412, 2407, 39896, 5016, 9566, 1975, 20498, 1829, 12984, 26895, 28242, 2423, 4724, 1829, 3555, 2655, 995, 25708, 30767, 1829, 19446, 31439, 9122, 10943, 37977, 383, 3834, 6086, 422, 1975, 20498, 1829, 12984, 26895], "avg_logprob": -0.3008261418890679, "compression_ratio": 1.5810055865921788, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 2153.8099999999995, "end": 2154.5699999999997, "word": "أسد", "probability": 0.46978759765625}, {"start": 2154.5699999999997, "end": 2155.33, "word": " زائد", "probability": 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"word": " حاولوا", "probability": 0.89501953125}, {"start": 2364.4, "end": 2365.0, "word": " تشوفون", "probability": 0.9195556640625}, {"start": 2365.0, "end": 2365.16, "word": " اللي", "probability": 0.865234375}, {"start": 2365.16, "end": 2365.8, "word": " بدوبوها", "probability": 0.6217041015625}, {"start": 2365.8, "end": 2365.98, "word": " لو", "probability": 0.765625}, {"start": 2365.98, "end": 2366.6, "word": " سمحتوا", "probability": 0.9488525390625}], "temperature": 1.0}, {"id": 87, "seek": 242321, "start": 2395.08, "end": 2423.22, "text": "هذا الامتحان التاني اللي عندكم بمش نمشي فيه أسرع شوية نمشي فيه أسرع شوية يعني الحل بدون شرح و بتقلق الآن ال carboxylic acids نكبر هذه بس", "tokens": [3224, 15730, 2423, 10943, 2655, 5016, 7649, 16712, 7649, 1829, 13672, 1829, 43242, 24793, 4724, 2304, 8592, 8717, 2304, 8592, 1829, 8978, 3224, 5551, 3794, 2288, 3615, 13412, 2407, 10632, 8717, 2304, 8592, 1829, 8978, 3224, 5551, 3794, 2288, 3615, 13412, 2407, 10632, 37495, 22653, 21542, 1211, 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"probability": 0.7646484375}, {"start": 2465.41, "end": 2465.53, "word": " ال", "probability": 0.626953125}, {"start": 2465.53, "end": 2466.07, "word": " Ibomars", "probability": 0.80584716796875}, {"start": 2466.07, "end": 2466.23, "word": " are", "probability": 0.354248046875}, {"start": 2466.23, "end": 2467.19, "word": " diastereomars", "probability": 0.86064453125}], "temperature": 1.0}, {"id": 90, "seek": 248080, "start": 2467.86, "end": 2480.8, "text": "الغلط إيجا من كلمة enantiomers الـ epimers are the stereomers ال acid halides are reduced to primary alcohols صح؟", "tokens": [6027, 17082, 1211, 9566, 11933, 1829, 7435, 995, 9154, 9122, 19528, 3660, 465, 11520, 298, 433, 2423, 39184, 2388, 332, 433, 366, 264, 12730, 298, 433, 2423, 8258, 7523, 1875, 366, 9212, 281, 6194, 7658, 82, 20328, 5016, 22807], "avg_logprob": -0.43085937201976776, "compression_ratio": 1.1239669421487604, "no_speech_prob": 0.0, "words": [{"start": 2467.86, "end": 2468.48, "word": "الغلط", "probability": 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الله في + +2 +00:00:24,970 --> 00:00:30,390 +المحاضرة الأخيرة بدنا نحاول نراجع بعض الامتحانات + +3 +00:00:30,390 --> 00:00:35,430 +نشوف كيف بتيجي الصورة الكلية في الامتحانات على هذه + +4 +00:00:35,430 --> 00:00:39,630 +المادة في عندنا هذا الامتحان هذا الامتحان كان في + +5 +00:00:39,630 --> 00:00:45,330 +الفصل الأول الماضي لطلاب السنة الأولى في كلية الطب + +6 +00:00:45,910 --> 00:00:50,190 +نحاول مع بعض نمر عليه، بنلاحظ أن الأسئلة طبعا + +7 +00:00:50,190 --> 00:00:55,750 +منوعة، في أسئلة صح و غلط، أكمل الفراغ، سم المركب، + +8 +00:00:55,750 --> 00:01:01,760 +كيف تحضر مركب، أكمل المعادلة، كل هذه الأشياءنشوف + +9 +00:01:01,760 --> 00:01:07,800 +الأشياء بالترتيب في أسئلة الصح والغلط بيسألنا سؤال + +10 +00:01:07,800 --> 00:01:13,160 +بيقولنا الـpeptide لجليسين ألانين ألانين و + +11 +00:01:13,160 --> 00:01:16,380 +الـpeptide ألانين جليسين جليسين are structural + +12 +00:01:16,380 --> 00:01:20,920 +isomers ايش رأيكم؟ they are not isomers لأن ال + +13 +00:01:20,920 --> 00:01:26,140 +isomers لازم يكونوا مكونين من نفس الأشياء يعني هذا + +14 +00:01:26,140 --> 00:01:29,120 +اتنين ألانين واحد جليسين هذا اتنين جليسين واحد + +15 +00:01:29,120 --> 00:01:32,700 +ألانين they are not isomersthey are different + +16 +00:01:32,700 --> 00:01:43,140 +compounds a glucofuranose is an aldobentose واضح؟ + +17 +00:01:43,140 --> 00:01:49,340 +إيش رأيكم؟ + +18 +00:01:49,340 --> 00:01:54,760 +الفيورانوز خمسة + +19 +00:01:54,760 --> 00:02:01,200 +لكن الجلوكوز ستة الجلوكوز + +20 +00:02:04,860 --> 00:02:11,080 +لأ لما نقول جولوكوز، الجولوكوز مر علينا وين؟ في + +21 +00:02:11,080 --> 00:02:16,500 +الالدوهيكسوزز؟ + +22 +00:02:16,500 --> 00:02:17,700 +لأ هذا world + +23 +00:02:29,910 --> 00:02:36,410 +الجلوكوز نفسه ست كربونات ولا خمسة؟ ستة، الان لما + +24 +00:02:36,410 --> 00:02:41,470 +أنا هنا بقول خمسة، إذا هذا الكلام صح ولا غلط؟ غلط، + +25 +00:02:41,470 --> 00:02:46,810 +لأنه الجلوكوز ستة مش خمسة، واضحة الفكرة؟ الجلوكوز + +26 +00:02:46,810 --> 00:02:50,910 +ستة دلات كربون، مش خمسة The peptide bond is longer + +27 +00:02:50,910 --> 00:02:57,830 +than normal C double bond N أو C N double bond، + +28 +00:02:57,830 --> 00:03:03,110 +إيش رأيكوا؟هل الـpeptide أطول من الـC double bond + +29 +00:03:03,110 --> 00:03:06,190 +N؟ طبعا انتوا بتكونوا تتذكروا ان الـamide bond + +30 +00:03:06,190 --> 00:03:11,990 +الـamide bond اللي هي الـCN كأنها رابط و نص مع + +31 +00:03:11,990 --> 00:03:15,850 +الـresonance ليش؟ لأنه انا في الـamide bond عندي C + +32 +00:03:15,850 --> 00:03:20,590 +double bond ON هذه single bond في الوضع الطبيعي + +33 +00:03:20,590 --> 00:03:27,510 +الآن لو صارت هنا C double bond N وهنا الـO minus + +34 +00:03:27,510 --> 00:03:28,530 +صارت + +35 +00:03:30,900 --> 00:03:35,480 +Double bond فهل ال peptide او الأمد double ولا + +36 +00:03:35,480 --> 00:03:42,220 +single؟ لأ هي واحد و نص في النهايةمش احنا حكينا في + +37 +00:03:42,220 --> 00:03:46,880 +عندنا امد resonance الامد بيعمل resonance معنى + +38 +00:03:46,880 --> 00:03:51,580 +resonance هذه اللي بتكون مرة double single bond في + +39 +00:03:51,580 --> 00:03:54,800 +المرة التانية شو بتكون double bond شو متوسط ال + +40 +00:03:54,800 --> 00:03:58,640 +double و ال single واحد و نص الان الواحد و نص + +41 +00:03:58,640 --> 00:04:03,600 +كرابطة الواحد و نص كرابطة مقارنة بالواحد ايه اطول + +42 +00:04:03,600 --> 00:04:09,920 +رابطةالواحد ال single الأقصر ال double ال and ال + +43 +00:04:09,920 --> 00:04:16,160 +واحد و نص بينهم فهي أقصر من ال single و أطول من ال + +44 +00:04:16,160 --> 00:04:21,140 +double واضح ال رابطة لما تكون ب resonance يعني + +45 +00:04:21,140 --> 00:04:24,240 +كأنها واحد و نص هي أقصر من ال single bond و أطول + +46 +00:04:24,240 --> 00:04:29,460 +من ال double bond احنا ايش كاتبين is longer than c + +47 +00:04:29,460 --> 00:04:35,250 +double bond and اذا هذه الجملة صحواضح الفكرة؟ هذه + +48 +00:04:35,250 --> 00:04:38,630 +بتعتمد على فهمكم للأمد resonance .. بتعتمد على + +49 +00:04:38,630 --> 00:04:42,130 +فهمكم للأمد resonance Hydrolysis of starch + +50 +00:04:42,130 --> 00:04:49,350 +produces only beta-glucopyranosis ال starch من أي + +51 +00:04:49,350 --> 00:04:53,110 +سكة؟ + +52 +00:04:53,110 --> 00:05:00,710 +من؟ كويس من أي ديساكراي؟ ملتوز .. الملتوز من إيش؟ + +53 +00:05:02,010 --> 00:05:08,890 +أي جولوكوز ألف وأو بيتا ألف وأو بيتا الأن هنا إيش + +54 +00:05:08,890 --> 00:05:16,130 +كاتبين إحنا only بيتا لأن الملتوز ألف وأو بيتا + +55 +00:05:16,130 --> 00:05:19,950 +ملتوز ألف وأو بيتا the OH of the anomeric carbon + +56 +00:05:19,950 --> 00:05:23,690 +of beta-glucobyranose is found in the equatorial + +57 +00:05:23,690 --> 00:05:29,870 +position هذه أخدناها صحيحة + +58 +00:05:31,370 --> 00:05:36,890 +مشقولنا انه ليش بيكون ال beta نسبته اعلى من ال + +59 +00:05:36,890 --> 00:05:40,270 +alpha لأنه ال beta في ال equatorial position مافيش + +60 +00:05:40,270 --> 00:05:45,650 +عليها steric hindrance داي تيربين are composed of + +61 +00:05:45,650 --> 00:05:52,710 +twenty carbon atoms الان ال mono terbin اكم ايزو + +62 +00:05:52,710 --> 00:05:57,110 +برين unit تنتين الداي تيربين اكم ايزو برين unit + +63 +00:05:57,110 --> 00:05:58,910 +اربع اربع في خمسة + +64 +00:06:02,460 --> 00:06:09,860 +hydrogenation of oils is a saponification reaction + +65 +00:06:09,860 --> 00:06:12,880 +هدرجة + +66 +00:06:12,880 --> 00:06:18,280 +الزيوت بتحول ال double bond إلى single bond بتحول + +67 +00:06:18,280 --> 00:06:22,820 +ال oil إلى fat ال saponification reaction بيعمل + +68 +00:06:22,820 --> 00:06:29,770 +hydrolysis فهدرجة الزيوت مش تفاعلسابونفكاشن + +69 +00:06:29,770 --> 00:06:34,250 +السابونفكاشن ان اخد الـ triglyceride احوله الى + +70 +00:06:34,250 --> 00:06:41,190 +soap الى salt of the fatty acid واضح ان احول الزيت + +71 +00:06:41,190 --> 00:06:45,690 +الى سابون ان اعمل hydrolysis الان هل ال + +72 +00:06:45,690 --> 00:06:48,970 +hydrogenation عمل hydrolysis ولا تحويل double bond + +73 +00:06:48,970 --> 00:06:52,610 +ل single bond اه اذا ال hydrogenation is + +74 +00:06:52,610 --> 00:06:58,270 +سابونفكاشن reaction غلطالهيدروجينيشن تحويل بابل + +75 +00:06:58,270 --> 00:07:03,710 +بوند لسينجل بوند مش تحويل إيستر لملح The polar R + +76 +00:07:03,710 --> 00:07:08,990 +groups in hair proteins طبعا ال hair fibrous + +77 +00:07:08,990 --> 00:07:15,750 +protein are located outside الفيبرس + +78 +00:07:15,750 --> 00:07:22,450 +وين موجودة ال R groups تبعتهم؟جوا مش برا ال fibers + +79 +00:07:22,450 --> 00:07:27,350 +ال proteins ال R groups تبعتهم موجودة للداخل ولذلك + +80 +00:07:27,350 --> 00:07:34,390 +هذه الجملة غلط واضح الان complete the following + +81 +00:07:34,390 --> 00:07:38,450 +statements نرفع شوية + +82 +00:07:45,750 --> 00:07:49,630 +الدياستيريوم الذين يختلفون فقط في مركز واحد كيرال + +83 +00:07:49,630 --> 00:08:02,610 +يسمون ابيمارز ابيمارز اسم الكيميائي لاسبيرين اسيتل + +84 +00:08:02,610 --> 00:08:07,130 +ساليسينك + +85 +00:08:07,130 --> 00:08:12,830 +أسد باراسيتامول + +86 +00:08:12,830 --> 00:08:14,170 +أيضا يسمون + +87 +00:08:18,000 --> 00:08:24,020 +اسيتامينوفين متذاكرين هالكلام؟ اسيتامينوفين + +88 +00:08:24,020 --> 00:08:30,000 +دايسالفايد بونتز ان البروتينز ريزولت من اكسيدشن اي + +89 +00:08:30,000 --> 00:08:35,520 +امينواسد اللي بيعمل دايسالفايد بونت؟ سيستين + +90 +00:08:44,950 --> 00:08:49,250 +أكسيدات الجولوكوز باستخدام نيترك أسد تنتج + +91 +00:08:49,250 --> 00:08:58,410 +إجلوكاريك إجلوكاريك أسد اللي هو يعني فيه مجموعتين + +92 +00:08:58,410 --> 00:09:08,350 +حامض إجلوكاريك أسد إجلوكاريك أسد التغيير + +93 +00:09:08,350 --> 00:09:11,870 +في حركة العيون بسبب التعاون بين الحيوانات + +94 +00:09:11,870 --> 00:09:18,880 +والمواصلةميوتا روتيشن + +95 +00:09:18,880 --> 00:09:24,080 +البروجيستيرون + +96 +00:09:24,080 --> 00:09:33,800 +هم 6 هرمون مع مصادر استيرويدال استيرويدال + +97 +00:09:33,800 --> 00:09:38,360 +مصادر استيرويدال تقوم بالتقليل من الشغر + +98 +00:09:43,220 --> 00:09:49,820 +السكريات المختزلة بيصيرلها oxidation reactions + +99 +00:09:49,820 --> 00:09:59,420 +واضح؟ oxidation لأنه هي الديهيد بيصيرلها أكسدة + +100 +00:09:59,420 --> 00:10:05,540 +واضح؟ reducing sugars undergo oxidation reactions + +101 +00:10:13,590 --> 00:10:19,570 +name the following compounds اول مركب ايش شايفين + +102 +00:10:19,570 --> 00:10:25,010 +فيه مجموعات وظيفية الديهايد و كيتون و double bond + +103 +00:10:25,010 --> 00:10:29,530 +شو لازم يصير الديهايد اعلى او لو يالا الديهايد + +104 +00:10:29,530 --> 00:10:34,630 +واحد اتنين تلاتة اربعة خمسة اذا هذا هيكون + +105 +00:10:56,440 --> 00:10:59,240 +توبنتينال توبنتينال + +106 +00:11:02,160 --> 00:11:06,800 +واضح؟ الآن تطلع على المركب اللي بعده أهم شغل تعرفه + +107 +00:11:06,800 --> 00:11:13,440 +المجموعة الوظيفية تبعت المركب ال acid ال acid ال + +108 +00:11:13,440 --> 00:11:21,160 +acid إذا هقول انا واحد اتنين تلاتة أربعة هاي الجزء + +109 +00:11:21,160 --> 00:11:27,620 +الأساسي في المركب الآن هذا الجزء شو اسمه بيوتانويك + +110 +00:11:27,620 --> 00:11:30,660 +بيوتانويك + +111 +00:11:31,760 --> 00:11:40,640 +acid ايش بيحمل على نمرة تلاتة three cyclobentyl + +112 +00:11:40,640 --> 00:11:50,520 +وشو بيحمل على نمرة اربعة four dimethylamino + +113 +00:11:50,520 --> 00:11:55,560 +three cyclobentyl + +114 +00:11:55,560 --> 00:12:00,380 +four dimethylamino butanoic acid واضح؟ + +115 +00:12:02,250 --> 00:12:07,430 +3-cyclopentel-4-dimethylamino-butanoic acid اخر + +116 +00:12:07,430 --> 00:12:14,490 +مركب شو مجموعته الوظيفية امد من + +117 +00:12:14,490 --> 00:12:22,450 +كام كربونا مكوّن بالاساس يعني جاي من اي حامض من ال + +118 +00:12:22,450 --> 00:12:31,330 +acetic acid اذا هذا أسيت امد او لو قولنا اثانوك + +119 +00:12:31,330 --> 00:12:31,810 +اسد + +120 +00:12:35,670 --> 00:12:43,650 +الان ايش بيحمل هذا على نمره اتنين فنل فنل فنل فنل + +121 +00:12:43,650 --> 00:12:48,190 +فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل + +122 +00:12:48,190 --> 00:12:48,470 +فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل + +123 +00:12:48,470 --> 00:12:51,550 +فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل + +124 +00:12:51,550 --> 00:12:51,550 +فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل + +125 +00:12:51,550 --> 00:12:51,670 +فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل + +126 +00:12:51,670 --> 00:13:02,030 +فنل فنل فنل فنل + +127 +00:13:02,030 --> 00:13:02,570 +فن + +128 +00:13:08,520 --> 00:13:13,160 +الان هانا بدنا ياكوا ترسمون لبعض المركبات بأشكالها + +129 +00:13:13,160 --> 00:13:17,340 +العامة لو قولنا أسيتوفينون مين مابتعرفش + +130 +00:13:17,340 --> 00:13:21,440 +الأسيتوفينون CH3 + +131 +00:13:21,440 --> 00:13:29,480 +فينيل C double bond O الان لما بدي هيدرازون بدو + +132 +00:13:29,480 --> 00:13:34,110 +يصير C double bond Nن اتش احنا ايش حاطين على + +133 +00:13:34,110 --> 00:13:39,890 +الهيدرازون أسيتل لو كانت مثل بنحط مثل فينال فينال + +134 +00:13:39,890 --> 00:13:44,950 +أسيتل C + +135 +00:13:44,950 --> 00:13:53,750 +double bond O CH3 أسيتوفينون هيدرازون أسيتل + +136 +00:13:53,750 --> 00:13:57,960 +هيدرازونأسيتوفينون لو فينيل كان قولنا فينيل + +137 +00:13:57,960 --> 00:14:01,600 +هيدرازون مثل مثل هيدرازون اثل هيدرازون أسيت + +138 +00:14:01,600 --> 00:14:08,860 +الهيدرازون ال glyceraldehyde ال glyceraldehyde في + +139 +00:14:08,860 --> 00:14:18,560 +هنا الديهيد و بعدين كايرال سنتر واحد شوفي هنا + +140 +00:14:18,560 --> 00:14:19,740 +الكايرالسنتر + +141 +00:14:22,340 --> 00:14:31,660 +H و OH و أنا هاي + +142 +00:14:31,660 --> 00:14:39,620 +ال glycerol دي و لو كان دي ناقص بنزل to بيوتاي + +143 +00:14:39,620 --> 00:14:45,160 +نويت بنخلص + +144 +00:14:45,160 --> 00:14:47,020 +هدول خلصناهم + +145 +00:14:49,020 --> 00:14:54,540 +الان طبعا بنبدأ الرسم من الآخر معناه ا و ات يعني + +146 +00:14:54,540 --> 00:15:00,480 +عندى P stop يعني عندى C double bond O O الان شو + +147 +00:15:00,480 --> 00:15:09,180 +الجزء ال alcohol اللى هنا بنزل شو البنزل CH2 + +148 +00:15:09,180 --> 00:15:15,960 +فنل CH2 فنل هى البنزل بنزل بيوتين و ات هى كربونة + +149 +00:15:15,960 --> 00:15:17,340 +كام كربون بيضل عندى + +150 +00:15:26,230 --> 00:15:32,970 +اربعة الان فى عندى ال triple bond على نمرة اتنين + +151 +00:15:32,970 --> 00:15:42,690 +اذا واحد اتنين تلاتة وهدى شو بيخليها CH3 وهدى + +152 +00:15:42,690 --> 00:15:51,050 +رقم واحد يعنىلحظة بنزل فنل CH2 بنزل ال Easter C W + +153 +00:15:51,050 --> 00:15:55,870 +bond O O R واضح بيوتين واحة اتنين تلاتة اربعة two + +154 +00:15:55,870 --> 00:16:02,170 +بيوتين و اتنين هذا المركب بهدوء بنمشي فيه خطوة + +155 +00:16:02,170 --> 00:16:07,330 +خطوة بنرسمه Cyclopentane كيف ال Cyclopentane؟ في + +156 +00:16:07,330 --> 00:16:14,590 +حد بعرفهش؟ بدنا نعمل فيهالديهيد سايكلوبنتين + +157 +00:16:14,590 --> 00:16:21,070 +كربلديهيد كيف الكربلديهيد C double bond O H هاي + +158 +00:16:21,070 --> 00:16:26,090 +السايكلوبنتين كربلديهيد هذا السايكلوبنتين + +159 +00:16:26,090 --> 00:16:30,910 +كربلديهيد الان لما بتعمل أكزيم بدي أشيل ال O + +160 +00:16:30,910 --> 00:16:35,670 +أخليها N OH + +161 +00:16:38,800 --> 00:16:43,560 +حولت الالديهيد إلى أكزيم سايكلوبنتين كربالديهيد + +162 +00:16:43,560 --> 00:16:49,820 +أكزيم Beta + +163 +00:16:49,820 --> 00:16:57,100 +to deoxifuranose متذكرين الفيورانوز؟ بده general + +164 +00:16:57,100 --> 00:17:05,120 +structure له أهم شيء انه على موقع اتنين في عنده + +165 +00:17:07,970 --> 00:17:14,750 +بهمنيش ال O H بهمني ال two دي أوكزي هنا في oxygen + +166 +00:17:14,750 --> 00:17:25,410 +و الموقع اتنين هنا هذا + +167 +00:17:25,410 --> 00:17:29,550 +الموقع واضح مار عليكوا ولا نفرجيكوا معاه + +168 +00:17:40,850 --> 00:17:47,390 +نذكركوا فيه لو سمحتوا في ال .. في ال + +169 +00:17:47,390 --> 00:17:54,990 +carbohydrates، هذا ال carbohydrates؟ لأ + +170 +00:18:08,950 --> 00:18:12,190 +Clothes Clothes Clothes Clothes Clothes Clothes + +171 +00:18:12,190 --> 00:18:18,910 +Clothes Clothes + +172 +00:18:18,910 --> 00:18:18,910 +Clothes Clothes Clothes Clothes Clothes Clothes + +173 +00:18:18,910 --> 00:18:18,910 +Clothes Clothes Clothes Clothes Clothes Clothes + +174 +00:18:18,910 --> 00:18:18,910 +Clothes Clothes Clothes Clothes Clothes Clothes + +175 +00:18:18,910 --> 00:18:18,910 +Clothes Clothes Clothes Clothes Clothes Clothes + +176 +00:18:18,910 --> 00:18:18,910 +Clothes Clothes Clothes Clothes Clothes Clothes + +177 +00:18:18,910 --> 00:18:18,910 +Clothes Clothes Clothes Clothes Clothes Clothes + +178 +00:18:18,910 --> 00:18:19,190 +Clothes Clothes Clothes Clothes Clothes Clothes + +179 +00:18:19,190 --> 00:18:19,210 +Clothes Clothes Clothes Clothes Clothes Clothes + +180 +00:18:19,210 --> 00:18:19,210 +Clothes Clothes Clothes Clothes Clothes Clothes + +181 +00:18:19,210 --> 00:18:19,210 +Clothes Clothes Clothes Clothes Clothes Clothes + +182 +00:18:19,210 --> 00:18:19,390 +Clothes Clothes Clothes Clothes Clothes Clothes + +183 +00:18:19,390 --> 00:18:19,390 +Clothes Clothes Clothes Clothes Clothes Clothes + +184 +00:18:19,390 --> 00:18:19,510 +Clothes Clothes Clothes Clothes Clothes Clothes + +185 +00:18:19,510 --> 00:18:19,510 +Clothes Clothes Clothes Clothes Clothes Clothes + +186 +00:18:19,510 --> 00:18:19,830 +Clothes Clothes Clothes Clothes Clothes Clothes + +187 +00:18:19,830 --> 00:18:20,630 +Clothes Clothes Clothes Clothes Clothes Clothes + +188 +00:18:20,630 --> 00:18:20,630 +Clothes Clothes Clothes Clothes Clothes Clothes + +189 +00:18:20,630 --> 00:18:20,750 +Clothes Clothes + +190 +00:18:33,500 --> 00:18:36,800 +oxygen ديش هيكوا تحفظوا الواتشز لوين بس أهم إشي + +191 +00:18:36,800 --> 00:18:43,460 +تنتبهوه لإنه موقع اتنين دي oxy sugar واضح موقع + +192 +00:18:43,460 --> 00:18:50,040 +اتنين دي oxy sugar مافيش عليه إيش واتشز موقع اتنين + +193 +00:18:50,040 --> 00:18:58,580 +مافيش عليه واتشز ماليك انهيدريد متذكرين الماليك + +194 +00:18:58,580 --> 00:19:08,650 +انهيدريد سيبقى بالبنت او اوC double bond O ماليك + +195 +00:19:08,650 --> 00:19:16,430 +أنهايدرايد مار + +196 +00:19:16,430 --> 00:19:22,790 +عندكم نفتالك أنهايدرايد والماليك أنهايدرايد الآن + +197 +00:19:22,790 --> 00:19:28,750 +لما نجيبلكوا أكمل معادلات المحور الأساسي هنا إيش + +198 +00:19:28,750 --> 00:19:31,430 +هو الديهايد + +199 +00:19:32,840 --> 00:19:39,380 +الديهايد، واضح؟ يعني بدنا نتذكر كيمية ال الديهايد + +200 +00:19:39,380 --> 00:19:47,480 +الان ال الديهايد بال أكسدة، شو بيصير؟ acid ال + +201 +00:19:47,480 --> 00:19:53,040 +الديهايد بال أكسدة، acid و بال reduction؟ alcohol، + +202 +00:19:53,040 --> 00:19:57,890 +مشغولنا احنا ال الديهايدفي نص الطريق يتأكسد لحامض + +203 +00:19:57,890 --> 00:20:04,330 +و يختزل لكحول هي رجعته كحول او خلته حامض واضح + +204 +00:20:04,330 --> 00:20:12,610 +الفكرة؟ الان ال الديهايد بال HCN شو بيعمل؟ + +205 +00:20:12,610 --> 00:20:18,350 +سيانوهيدرين سيانوهيدرين اذا هذه بدأ تصير OHH و هنا + +206 +00:20:18,350 --> 00:20:28,230 +CN بال إثالينيج لايكولمتذكرين الاسيتال؟ هاي زي هيك + +207 +00:20:28,230 --> 00:20:34,810 +عند هذه بدو + +208 +00:20:34,810 --> 00:20:41,630 +يصير عندكم O تتدربوا + +209 +00:20:41,630 --> 00:20:44,430 +عليها اللي هي الاسيتال اللي من ال إيثالينيج لايكون + +210 +00:20:44,430 --> 00:20:49,710 +ابهيك أخدنا كام تفاعل للالديهايد؟ أربعة الأن + +211 +00:20:49,710 --> 00:20:54,570 +لاحظوا مع الالديهايد هنا صح؟acid يعني بدي تفاعله + +212 +00:20:54,570 --> 00:21:01,510 +الأحمار حمض زائد قاعدة يعني هذا هيصير C double + +213 +00:21:01,510 --> 00:21:09,130 +bond O O minus عند اللزوم K plus حمض هذا مع الثيون + +214 +00:21:09,130 --> 00:21:14,270 +الاخلورايد حمض زائد ثيون الاخلورايد او BCL3 acid + +215 +00:21:14,270 --> 00:21:19,010 +chloride تفاعله الحمض هذا الكحول + +216 +00:21:21,550 --> 00:21:29,390 +كحول مع بنزويك أسد كحول زاد حمض Easter إذا هاي ال + +217 +00:21:29,390 --> 00:21:35,470 +بنزويك أسد فنل C double bond O و جزء الكحول O + +218 +00:21:35,470 --> 00:21:40,010 +Cyclobentel + +219 +00:21:40,010 --> 00:21:47,170 +واضحة الفكرة؟ هاي جزء الكحول أنا في أشقنة CH2 كمان + +220 +00:21:47,170 --> 00:21:48,730 +نحتفظ فيها + +221 +00:21:55,050 --> 00:22:00,270 +Ester كحول زاد حامض هاي جزء ال بنزويك أسد وهذا جزء + +222 +00:22:00,270 --> 00:22:11,530 +الكحول كحول مع حامض بيعطينا Easter واضح + +223 +00:22:11,530 --> 00:22:15,710 +الفكرة؟ الآن لما نقولكوا هذا بدنا نفعله مع one + +224 +00:22:15,710 --> 00:22:19,350 +equivalent acetaldehyde كيف شكلوا ال acetaldehyde؟ + +225 +00:22:22,540 --> 00:22:27,940 +CH3COH كحول مع الديهيد شو بيعطيني؟ Hemacetal + +226 +00:22:27,940 --> 00:22:33,480 +Hemacetal يعني هذه بتاتيجي هنا وهذه تصير OH لاحظوا + +227 +00:22:33,480 --> 00:22:38,760 +كملنا ال Acetal ولا قولنا بس Hemacetal Hemacetal + +228 +00:22:38,760 --> 00:22:42,520 +يعني هذه تصير CH3COHH + +229 +00:22:42,520 --> 00:22:47,600 +و الجزء الخارجي هذا OCH2 + +230 +00:22:51,690 --> 00:22:58,670 +cyclopentel كحول زي الديهيد هيمي أسيتال كحول زي + +231 +00:22:58,670 --> 00:23:04,550 +الديهيد هيمي أسيتال كحول زي الحمر إيستار طبعا لازم + +232 +00:23:04,550 --> 00:23:08,830 +الإيد تكون متدربة أنها تطبق هذا الكلام تعمله يعني + +233 +00:23:08,830 --> 00:23:12,510 +الأفكار العامة دائما احفظوها قبل ما تقولوا رمز + +234 +00:23:12,510 --> 00:23:18,550 +كونوا فاهمين إيش المطلوب كحول مع حامضطبقه على هذا + +235 +00:23:18,550 --> 00:23:24,890 +الكلام الفكرة خلصت الان كحول مع الديهايد hemacetal + +236 +00:23:24,890 --> 00:23:31,410 +الديهايد بالاختزال كحول الديهايد بالأكسدة حم حم + +237 +00:23:31,410 --> 00:23:37,710 +زاد قاعدة ملح حم زاد ثيونيلي كلورايد أسد كلورايد + +238 +00:23:37,710 --> 00:23:43,790 +الديهايد مع السيانو هدرين الديايد مع الاتلينيج + +239 +00:23:43,790 --> 00:23:49,110 +لايكول أسيتال وبعدين بيصير انه جديش الإنسان متدرب + +240 +00:23:49,110 --> 00:23:51,430 +يكتب ويطبق هذا الكلام + +241 +00:24:07,890 --> 00:24:14,030 +الآن هى فى عندنا سؤال تانى إيش المنطلق اللى عندنا + +242 +00:24:14,030 --> 00:24:17,970 +فيه أسد كلورايد أسد كلورايد بتكون تتذكروا كيمية + +243 +00:24:17,970 --> 00:24:24,910 +الأسد كلورايد أسد كلورايد مع كحول أستر أستر كل إشي + +244 +00:24:24,910 --> 00:24:29,610 +بخليه زى ما هو و بحطها نقوه أسلف أستر ممتاز أسد + +245 +00:24:29,610 --> 00:24:36,730 +كلورايد مع أمين أمد أمد unatched + +246 +00:24:36,730 --> 00:24:46,530 +twoالان acid chloride مع green yard reagent تير + +247 +00:24:46,530 --> 00:24:52,510 +تشيري ألكول هاي ال C هادي هادي هادي بتصير OH يجيني + +248 +00:24:54,100 --> 00:24:58,100 +مجمعتين فنل على مرتين هيتفاعل أول اشي بيعطيني ال + +249 +00:24:58,100 --> 00:25:01,800 +ketone أول ما تاجم الفنل هنا محل ال CL بيعطيني ال + +250 +00:25:01,800 --> 00:25:06,480 +ketone و بكمل ل tertiary alcohol أخدنا ال Easter و + +251 +00:25:06,480 --> 00:25:10,580 +ال acid chloride مع Greenyard شو بيعطوني؟ tertiary + +252 +00:25:10,580 --> 00:25:16,200 +alcohol و بال reduction؟ primary alcohol الان + +253 +00:25:21,250 --> 00:25:25,850 +هذا الـ Acid chloride مع Sodium Benzoyate بدنا + +254 +00:25:25,850 --> 00:25:31,190 +واحدة شاطرة تقولنا كيف شكل Sodium Benzoyate فنل C + +255 +00:25:31,190 --> 00:25:38,410 +double bond O O minus N A plus لاحظوا هنا لما قلت + +256 +00:25:38,410 --> 00:25:44,730 +O minus و هذا Acid chloride صار تحضير ايش الـ + +257 +00:25:44,730 --> 00:25:49,930 +Unsymmetrical anhydride ان هذه تهاجمهاهذا + +258 +00:25:49,930 --> 00:25:55,350 +نيوكليوفايل يترد الـCl إيه هاجمانه يترد الـCl + +259 +00:25:55,350 --> 00:25:58,810 +عشانك هيصير هذا تحضير الـ Unsymmetrical Unhydrate + +260 +00:25:58,810 --> 00:26:05,670 +هاي هذا الجزء والجزء التاني O C double bond O + +261 +00:26:05,670 --> 00:26:11,170 +Phenyl فعلا هذا Unhydrate ولا لأ؟ C double bond O + +262 +00:26:11,170 --> 00:26:18,440 +O C double bond O Unhydrate هاي احناأخدنا أربع + +263 +00:26:18,440 --> 00:26:22,780 +تفاعلات للـ Acid Chloride باختصار Acid Chloride مع + +264 +00:26:22,780 --> 00:26:27,300 +كحول Easter Acid Chloride مع أمونيا Amid Acid + +265 +00:26:27,300 --> 00:26:31,000 +Chloride مع Greenyard Tertiary Alcohol Acid + +266 +00:26:31,000 --> 00:26:37,160 +Chloride مع أنيون Unhydrate Unsymmetrical + +267 +00:26:37,160 --> 00:26:40,020 +Unhydrate طريقة تحضير الـ Unsymmetrical Unhydrate + +268 +00:26:40,020 --> 00:26:44,560 +الأن دول خلصناهم صار في عندي Easter بدي أخد لل + +269 +00:26:44,560 --> 00:26:49,240 +Easter كام تفاعل؟تفاعلين وصار في اندي أمد بتاخد + +270 +00:26:49,240 --> 00:26:53,420 +للأمد كام تفاعل؟ تفاعلين هو احنا كل اللي اتعلمناهم + +271 +00:26:53,420 --> 00:27:01,100 +للأمد كام تفاعل؟ يا هيدروليسز يعني هذا يصير acid + +272 +00:27:01,100 --> 00:27:13,240 +بهذا الشكل يا اما reduction ان هذا يصير CH2 + +273 +00:27:14,120 --> 00:27:22,280 +ان اتش امد امد امد امد امد امد امد امد امد امد امد + +274 +00:27:22,280 --> 00:27:25,100 +امد امد امد امد امد امد امد امد امد امد امد امد + +275 +00:27:25,100 --> 00:27:25,980 +امد امد امد امد امد امد امد امد امد امد امد امد + +276 +00:27:25,980 --> 00:27:30,000 +امد امد امد امد امد امد امد امد امد امد امد امد + +277 +00:27:30,000 --> 00:27:31,420 +امد امد امد امد امد امد امد امد امد امد امد امد + +278 +00:27:31,420 --> 00:27:31,460 +امد امد امد امد امد امد امد امد امد امد امد امد + +279 +00:27:31,460 --> 00:27:39,960 +امد امد ا + +280 +00:27:43,000 --> 00:27:47,720 +الإيستار بالريدكشن الاسد الكلورايد والإيستار + +281 +00:27:47,720 --> 00:27:51,240 +بالريدكشن شو بيصيروا ال primary alcohol يعني هذه + +282 +00:27:51,240 --> 00:27:56,400 +بيصير CH2OH + +283 +00:27:56,400 --> 00:28:04,700 +والجزء هذا نفسه طيب الإيستار مع الهيدرازين يمكن + +284 +00:28:04,700 --> 00:28:10,790 +مامرش عليكم هذا التفاعلكتفاعل خاص لكن لما تقولوا + +285 +00:28:10,790 --> 00:28:16,190 +الهيدرازين نيوكليوفايل شو بده يعمل؟ بده يهاجم هنا + +286 +00:28:16,190 --> 00:28:22,410 +و يطرد ال O-ethyl، حطوا الناتج بهذا الشكل، إذا + +287 +00:28:22,410 --> 00:28:30,510 +حاسين عندكم؟ C double bond O وهنا إيش بده يصير؟ NH + +288 +00:28:30,510 --> 00:28:35,630 +NH2 هيدرازايد + +289 +00:28:35,630 --> 00:28:42,800 +بيسموهزي تفاعل الأمد، زي لو كنتوا بفعلينه مع ناتشي + +290 +00:28:42,800 --> 00:28:48,460 +ثري، مش كان تيجي ناتشي ثري تحل محل هادى، واضح؟ نفس + +291 +00:28:48,460 --> 00:28:53,900 +الفكرة تماما، + +292 +00:28:53,900 --> 00:28:54,620 +واضحة؟ + +293 +00:29:13,900 --> 00:29:19,260 +لاحظوا بسؤال بسيط راجعنا كام كيميا ال acid halides + +294 +00:29:19,260 --> 00:29:25,720 +و ال e stars و ال amides و ال acids هذا + +295 +00:29:25,720 --> 00:29:34,430 +الجزء في عندكممجموعة النيترو ومجموعة ال سيانو على + +296 +00:29:34,430 --> 00:29:43,070 +بنزين الان النيترو بال reduction شو بتصير ان + +297 +00:29:43,070 --> 00:29:47,670 +اتشتو ان اتشتو امين مشقول ان هذه طريقة تحضير + +298 +00:29:47,670 --> 00:29:53,970 +الانيلين يعني هذه تصير ان اتشتو هنا سيان + +299 +00:29:56,170 --> 00:30:02,250 +Reduction بيشتغل الـ Nitro تصير NH2 الآن السيانو + +300 +00:30:02,250 --> 00:30:06,470 +أخدنا بالهيدروليسيز في تحضير الأحمار، شو بتصير؟ + +301 +00:30:06,470 --> 00:30:12,030 +أسد، أذن هنا، بدي أسيبني من الـNitro زي ما هي، + +302 +00:30:12,030 --> 00:30:20,810 +وهذه إيش تصير؟ C double bond O تفاعل + +303 +00:30:20,810 --> 00:30:26,980 +السيانو لأسد، مر معنا ولا لأ؟وتفاعل الـ Nitro هي + +304 +00:30:26,980 --> 00:30:32,060 +مصدر الانيلين مرمعنا ولا لأ افتح دي للأمين؟ بس هم + +305 +00:30:32,060 --> 00:30:38,640 +راحون دخلوش في بعض في هنا الـNa الـO2 بتحولها إلى + +306 +00:30:38,640 --> 00:30:45,260 +الـOX اه هنا اول فكرة الـH2 بهمش انتبع شوية الـH2 + +307 +00:30:45,260 --> 00:30:49,640 +مع البلاتينام بيعطيني الانيلين الآن اذا بعد هيك + +308 +00:30:49,640 --> 00:30:54,880 +فعلناها مع Sodium Nitrite وH3O Plus بيصير ايش؟ + +309 +00:30:55,940 --> 00:31:00,660 +الفينول مر علينا طريقة تحضير الفينول يعني أنا كان + +310 +00:31:00,660 --> 00:31:06,060 +جوابي بس للجزء الأول إذا بعدك فعلته مع الصوديوم + +311 +00:31:06,060 --> 00:31:08,640 +نايترايت حامل دايزونيوم سولت ماعدش three of plus + +312 +00:31:08,640 --> 00:31:15,280 +بصير فينول يعني لو أجينا بس لحدها أنيلين + +313 +00:31:15,280 --> 00:31:22,520 +لو كملناالانهيلين بنحوله إلى فينول حسب ما يجي + +314 +00:31:22,520 --> 00:31:25,980 +السؤال يعني لحد ال reduction انهيلين زدنا عن ال + +315 +00:31:25,980 --> 00:31:33,480 +reduction فينول ممتازة + +316 +00:31:33,480 --> 00:31:34,020 +الان + +317 +00:31:45,510 --> 00:31:50,110 +جينا سؤال كيف بدنا نحضر ال Acetic Acid بتعرفوا ال + +318 +00:31:50,110 --> 00:31:56,750 +Acetic Acid؟ CH3COOH + +319 +00:31:56,750 --> 00:32:02,870 +من إيش بدنا نحضره؟ من التوبيوتانون واحد اتنين هاي + +320 +00:32:02,870 --> 00:32:07,530 +توبيوتانون طبعا + +321 +00:32:07,530 --> 00:32:14,580 +الكلام يبدوشوية غريب جدا لكن لو اي حد بيفكر شوية + +322 +00:32:14,580 --> 00:32:20,720 +بعمق بيفكر شوية بعمق ال acetic acid كاربونتين وال + +323 +00:32:20,720 --> 00:32:30,460 +two-butanone اربعة يعني الأربعة لو كسروا لو كسروا + +324 +00:32:30,460 --> 00:32:34,360 +بيصيروا اتنين و اتنين اذا انا لو كنت بدي اجي برجوع + +325 +00:32:34,360 --> 00:32:36,540 +من ورا هذا ايش ممكن يكون + +326 +00:32:39,320 --> 00:32:47,400 +الالكين هذا نمرة واحد O3 نمرة اتنين H2O2 كان + +327 +00:32:47,400 --> 00:32:53,300 +بيعطيني زي هيك ولا لأ؟ + +328 +00:32:53,300 --> 00:32:58,660 +أنا كملت بالأكسدة الإضافية أوزون وبعدين أكسدة + +329 +00:32:58,660 --> 00:33:07,580 +بيصير حامض أوزون وبعدين أكسدة بيصير حامضواضح؟ الآن + +330 +00:33:07,580 --> 00:33:13,140 +هذا من إيش ممكن ييجي؟ من كحول يعني خلّينا هيك + +331 +00:33:13,140 --> 00:33:19,540 +نتخيل هي OH الآن أنا ماعنديش كحول عشان أعمل حدث + +332 +00:33:19,540 --> 00:33:24,380 +باستعمال ال KOH بيعطينا Alkene بس أنا ماعنديش كحول + +333 +00:33:24,380 --> 00:33:33,360 +أنا عنده Ketone ال Ketone يختزل آه + +334 +00:33:33,960 --> 00:33:41,740 +اذا كيتون كحول الكين و اوزونوليس اتبع اكسيداشيا او + +335 +00:33:41,740 --> 00:33:46,960 +ممكن تستعمل كمان او فور برضه اتش بلس بتعمل نفس + +336 +00:33:46,960 --> 00:33:52,700 +الشي واضح هذا في طريقة تحضير الأحمار لما قولنا كيف + +337 +00:33:52,700 --> 00:33:57,200 +بنكسر ال double bond او ال triple bond كمان ممكن + +338 +00:33:57,200 --> 00:34:00,700 +نكسرها و اش تعطينا حامض + +339 +00:34:02,030 --> 00:34:06,050 +طبعا لأن هنا في عندي H وهنا H أول ما بيكسر زي ما + +340 +00:34:06,050 --> 00:34:09,470 +حكت زميلتكوا فعلا ل 12-dihydes ال 12-dihydes + +341 +00:34:09,470 --> 00:34:17,010 +بتأكسدوا لإيش لacetic acid 12-dihydes بتأكسدوا + +342 +00:34:17,010 --> 00:34:24,610 +لacetic acid أخر + +343 +00:34:24,610 --> 00:34:29,770 +سؤال كان draw the structure of the peptide alanine + +344 +00:34:29,770 --> 00:34:35,490 +cysteineالان بدي قلانين الستين هو ال بيبتايد ايش + +345 +00:34:35,490 --> 00:34:44,710 +NCCO وكمان NCCO الان هاي بيبتايد من شغلتين + +346 +00:34:44,710 --> 00:34:49,910 +القلانين شو المجموعة اللي هنا CH3 وهي ال amino + +347 +00:34:49,910 --> 00:34:55,650 +terminal وهنا بدو يكون عندكم NH الستين شو المجموعة + +348 +00:34:55,650 --> 00:34:59,930 +CH2SH + +349 +00:34:59,930 --> 00:35:05,970 +وهنا بدو يكونالـ Acid Terminal فلاحظوا الـ peptide + +350 +00:35:05,970 --> 00:35:10,190 +لما بدي أرسم بدي أبدأ بالهيكل تبعه N C C double + +351 +00:35:10,190 --> 00:35:14,770 +bond O و N C C double bond O الآن إذا بحكي عن + +352 +00:35:14,770 --> 00:35:22,150 +الانين بدي أحط مثل بحكي عن سيستين بدي أحط CH2SH + +353 +00:35:23,240 --> 00:35:26,540 +واضح الفكرة؟ هى صار عند ال بيبتايد و amino + +354 +00:35:26,540 --> 00:35:32,260 +terminal و acid terminal الآن بدنا نيجي بعد هيك + +355 +00:35:32,260 --> 00:35:40,180 +نقول هذا ال بيبتايد خلينا نفعله مع ال methanol و H + +356 +00:35:40,180 --> 00:35:44,220 +plus لاحظوا + +357 +00:35:44,220 --> 00:35:49,980 +ال بيبتايد إله acid terminal ولا لأ؟ acid .. acid + +358 +00:35:49,980 --> 00:35:51,320 +زاد alcohol + +359 +00:35:53,810 --> 00:35:59,050 +أسد زائد ألكوهول إيستر إذا أنا بدي أجيب كل هذا + +360 +00:35:59,050 --> 00:36:02,970 +بلاش نقعد نوضح فيه و نقول C double bond O و من + +361 +00:36:02,970 --> 00:36:09,110 +الميثانول شو هيحط اوميثيل كل ال بيبتايد زي ما هو + +362 +00:36:09,110 --> 00:36:12,530 +كاملة C double bond O اوميثيل + +363 +00:36:18,040 --> 00:36:22,160 +الان ال بيبتايد مع ال two four داينيترو فلورو + +364 +00:36:22,160 --> 00:36:29,680 +بنزين هذا اللي أخدناه وسمناه ايش floor zanger + +365 +00:36:29,680 --> 00:36:39,340 +method وان او اتو وان اتو ايش بيعمل بالتحت مكان ال + +366 +00:36:39,340 --> 00:36:45,360 +floor اذا انا هيكون عندى ان اتش و ال بيبتايد كله و + +367 +00:36:45,360 --> 00:36:56,410 +بعدين هنابنزينة بنيترو و نيترو كل ال بيبتايد يتحد + +368 +00:36:56,410 --> 00:37:05,110 +من عند ال N الان + +369 +00:37:05,110 --> 00:37:12,030 +لو اجينا فعلنا هذا مع ال etheracetate OH- ال + +370 +00:37:12,030 --> 00:37:19,040 +etheracetate يستر بنقدر نرسمهCH3C double bond O O + +371 +00:37:19,040 --> 00:37:26,040 +-ethyl ايش اللي بنتوقع ميثل بيبتايد موجود ال amino + +372 +00:37:26,040 --> 00:37:33,640 +group النيكليوفايل وين ممكن يتهاجم تطرد + +373 +00:37:33,640 --> 00:37:41,160 +ال O-ethyl اذا هيكون الناتج اللي عندى ال N-H مع كل + +374 +00:37:41,160 --> 00:37:50,600 +ال بيبتايد و ايش هيحط عندى هناC double bond O CH3 + +375 +00:37:50,600 --> 00:37:56,320 +الأمين + +376 +00:37:56,320 --> 00:38:00,080 +بتفاعل مع ال Easter مش الأسد بتفاعل مع ال Easter + +377 +00:38:00,080 --> 00:38:11,130 +أمين زائد Easter أمد أمين زائد Easterامد مش هذه + +378 +00:38:11,130 --> 00:38:18,410 +المعادلة العامة هذي امين وهذا اي ستار امين زائد اي + +379 +00:38:18,410 --> 00:38:28,950 +ستار بيعطينا ايش امد الان طب ال HCL بدو يتحلل اه + +380 +00:38:28,950 --> 00:38:32,930 +بالاساس مش بنعمل هيدرونيسز احنا لل بيبتايدز يعني + +381 +00:38:32,930 --> 00:38:43,130 +بدو يعطينا NH CHC double bond O OHزائد طبعا nh2 + +382 +00:38:43,130 --> 00:38:50,470 +كمان nh2 CH16 CH2SH مشغولا بيعملوا hydrolysis ال + +383 +00:38:50,470 --> 00:38:58,230 +peptides واضح؟ hydrolysis peptide hydrolysis بدو + +384 +00:38:58,230 --> 00:39:02,530 +يتكسر ضايق الاشياء؟ + +385 +00:39:22,160 --> 00:39:25,980 +نشوف الامتحان التاني حاولوا تشوفون اللي بدوبوها لو + +386 +00:39:25,980 --> 00:39:26,600 +سمحتوا + +387 +00:39:55,080 --> 00:40:10,380 +هذا الامتحان التاني اللي عندكم بمش + +388 +00:40:10,380 --> 00:40:15,860 +نمشي فيه أسرع شوية نمشي + +389 +00:40:15,860 --> 00:40:20,280 +فيه أسرع شوية يعني الحل بدون شرح و بتقلق الآن ال + +390 +00:40:20,280 --> 00:40:23,220 +carboxylic acids نكبر هذه بس + +391 +00:40:27,990 --> 00:40:32,070 +خلّيكم معايا Carboxylic acids react with aniline + +392 +00:40:32,070 --> 00:40:36,070 +producing amides حمض زائد أمين أمد هذي الجملة صح + +393 +00:40:36,070 --> 00:40:43,210 +اجليسرال ترايستيريت is a simple triglyceride صح + +394 +00:40:45,730 --> 00:40:50,250 +A large percentage of unsaturated acids غلط of + +395 +00:40:50,250 --> 00:40:54,630 +saturated reaction of hemacetals with alcohol is a + +396 +00:40:54,630 --> 00:40:58,290 +substitution reaction Hemacetal مع الالكول + +397 +00:40:58,290 --> 00:41:02,870 +substitution صحيحة Ibomars are enantiomars that + +398 +00:41:02,870 --> 00:41:06,230 +differ only in one chiral center لأ ال Ibomars are + +399 +00:41:06,230 --> 00:41:10,600 +diastereomarsالغلط إيجا من كلمة enantiomers الـ + +400 +00:41:10,600 --> 00:41:16,360 +epimers are the stereomers ال acid halides are + +401 +00:41:16,360 --> 00:41:22,450 +reduced to primary alcohols صح؟Aniline can be + +402 +00:41:22,450 --> 00:41:25,770 +prepared from the reaction of benzene with ammonia + +403 +00:41:25,770 --> 00:41:29,910 +هذا قلنا لأ من ال nitrobenzene بنحضر ال aniline + +404 +00:41:29,910 --> 00:41:34,290 +متذكرين؟ ال aniline من إيش بنحضره؟ Nitrobenzene + +405 +00:41:34,290 --> 00:41:37,790 +heating acidic acid with benzoic acid in presence + +406 +00:41:37,790 --> 00:41:42,570 +of H plus produces three possible products اللي هي + +407 +00:41:42,570 --> 00:41:45,750 +ال anhydrides مش four possible anhydrides، three + +408 +00:41:45,750 --> 00:41:57,500 +هذا بالنسبة لجزءالصح والغلط الآن + +409 +00:41:57,500 --> 00:42:02,480 +الـ isoelectric point is the point at which the pH + +410 +00:42:02,480 --> 00:42:09,160 +is the isoelectric point is the pH at which the + +411 +00:42:09,160 --> 00:42:15,470 +compound has a zero charge مش هيك؟الـ pH اللي + +412 +00:42:15,470 --> 00:42:19,790 +بتكون عنده ال charge كده؟ سفر، أخدناها، صيغوها بأي + +413 +00:42:19,790 --> 00:42:25,910 +صياغة الـ polar R-groups in fibrous proteins are + +414 +00:42:25,910 --> 00:42:32,690 +located inside essential + +415 +00:42:32,690 --> 00:42:40,950 +amino acids are obtained fromDiet او are not + +416 +00:42:40,950 --> 00:42:45,010 +synthesized in the body الأحماض الأمريكية الأساسية + +417 +00:42:45,010 --> 00:42:48,890 +اللي بناخدها من الغداء بيحضرهاش الجسم بأي صياغة + +418 +00:42:48,890 --> 00:42:56,710 +مثل MgBr react with acetone producing لاحظوا هاي + +419 +00:42:56,710 --> 00:43:02,410 +ال ketone ال acetone مع مثل MgBr بيجيب مثل T جهان + +420 +00:43:02,410 --> 00:43:08,210 +وهذا تصير OH إذا أنا producersTertiary Alcohol لو + +421 +00:43:08,210 --> 00:43:15,370 +واحدة بتسميه بالظبط tertiary butanol produces + +422 +00:43:15,370 --> 00:43:19,910 +tertiary butanol أو tertiary alcohol as a general + +423 +00:43:19,910 --> 00:43:33,150 +family Acetophenon is also called مثل كيتون + +424 +00:43:33,500 --> 00:43:38,020 +اسيتوفينون هو أيضا مسمى مثلفنالكليتون الاستيريو + +425 +00:43:38,020 --> 00:43:42,980 +مارز اللي مختلف فقط في مركز استيريوجينيكي مسمى ابي + +426 +00:43:42,980 --> 00:43:48,940 +مارز ابي مارز مونو + +427 +00:43:48,940 --> 00:43:53,720 +تيربينز مجتمع من عشر كربون او عشر كربون او عشر + +428 +00:43:53,720 --> 00:43:54,460 +كربون او عشر كربون او عشر كربون او عشر كربون او + +429 +00:43:54,460 --> 00:44:01,000 +عشر كربون او عشر كربون او عشر كربون او + +430 +00:44:01,000 --> 00:44:01,540 +عشر كربون او عشر كربون او عشر كربون او عشر كربون + +431 +00:44:01,540 --> 00:44:01,540 +او عشر كربون او عشر كربون او عشر كربون او عشر + +432 +00:44:01,540 --> 00:44:01,540 +كربون او عشر كربون او عشر كربون او عشر كربون او + +433 +00:44:01,540 --> 00:44:11,350 +عشر كربون او عشر كرببولي هيدروكسي ألديهيدز ال + +434 +00:44:11,350 --> 00:44:21,670 +doses are بولي هيدروكسي ألديهيدز و + +435 +00:44:21,670 --> 00:44:27,930 +ال ketosis بولي هيدروكسي + +436 +00:44:39,600 --> 00:44:45,480 +السؤال اللي بعده شو العائلة لهذا المركب؟ لاحظوا ما + +437 +00:44:45,480 --> 00:44:48,880 +قلتلكم مش ساموه المركب كاملا بس قولولي أي عائلة + +438 +00:44:48,880 --> 00:44:57,760 +هذه سيان مع او اتش سيانو هدرين سايكليك إيستر + +439 +00:44:57,760 --> 00:45:01,080 +لاكتون هذا + +440 +00:45:04,520 --> 00:45:11,040 +فيورانوز فيورانوز سكر خماسي فيورانوز ال N-H-C-W-O + +441 +00:45:11,040 --> 00:45:13,480 +-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O + +442 +00:45:13,480 --> 00:45:14,500 +-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O + +443 +00:45:14,500 --> 00:45:23,220 +-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O + +444 +00:45:23,220 --> 00:45:32,970 +-N-H-C-W-O-N-H-C-W-O-N-H-C-W-O-N-H-C-W-OCarbazone + +445 +00:45:32,970 --> 00:45:36,490 +Semicarbazone + +446 +00:45:36,490 --> 00:45:41,130 +ارسموا + +447 +00:45:41,130 --> 00:45:45,690 +شكل المراكبات الآتية من الـ Benzoic acid Sodium + +448 +00:45:45,690 --> 00:45:52,410 +Benzoate كيف هيكون؟ C double bond O O minus K plus + +449 +00:45:52,410 --> 00:45:59,210 +Potassium Benzoate Potassium Benzoate Benzamide + +450 +00:45:59,210 --> 00:46:06,580 +كيف ال Benzamide؟بنزين C double bond O N هاي الأمد + +451 +00:46:06,580 --> 00:46:15,400 +بده على ال N إيش؟ CH3 و CH3 دا يمثل بنزامد four + +452 +00:46:15,400 --> 00:46:22,460 +benzyl two hexenol طالما قال إذا إيش أنا عنده؟ + +453 +00:46:22,460 --> 00:46:27,580 +واحد اتنين تلاتة أربعة خمسة ستة هاي ال aldehyde C + +454 +00:46:27,580 --> 00:46:35,290 +double bond OH على نمرة اتنين واحد اتنين double + +455 +00:46:35,290 --> 00:46:41,850 +bond ع نمرة اربعة واحد اتنين تلاتة اربعة بنزل اللي + +456 +00:46:41,850 --> 00:46:51,050 +هي CH2 فنل مجموعة CH2 فنل بنزل مجموعة CH2 فنل بنزل + +457 +00:46:51,050 --> 00:46:54,450 +واضح؟ + +458 +00:46:54,450 --> 00:46:59,190 +هاي الال والإين والبنزل + +459 +00:47:09,280 --> 00:47:13,420 +سم المركبات التالية هذا إيش مجموعته الوظيفية إيه + +460 +00:47:13,420 --> 00:47:19,180 +إيه استر إذا لازم أحط في الأول إثل و في الآخر واحد + +461 +00:47:19,180 --> 00:47:28,360 +اتنين تلاتة أربعة خمسة بنتين و ويت ال E وين موقعها + +462 +00:47:28,360 --> 00:47:34,700 +إثل توبنتين و ويت إيش ده الحامل هذا المركب four + +463 +00:47:34,700 --> 00:47:35,120 +hydroxy + +464 +00:47:37,970 --> 00:47:44,350 +اذا هذا صار اثل فور هيدروكسي توبنتينويت اثل فور + +465 +00:47:44,350 --> 00:47:51,350 +هيدروكسي توبنتينويت واضح؟ نسمي اخر اتنين ونخلص بعد + +466 +00:47:51,350 --> 00:47:56,750 +عشر ثواني هذا المركب اللي شايفينه عبارة عن ايش؟ + +467 +00:47:56,750 --> 00:48:03,810 +كيتون واحد اتنين تلاتة اربعة خمسة ستة اذا هذا + +468 +00:48:03,810 --> 00:48:10,520 +عبارة عن threeهكسانون شو بيحمل ال three hexanone + +469 +00:48:10,520 --> 00:48:17,940 +مثل و دايمثل بيحط مواقعهم يعني two مثل و six + +470 +00:48:17,940 --> 00:48:23,020 +daimethylamino هذي إيش اسمها الآن مثل مثل six + +471 +00:48:23,020 --> 00:48:28,140 +daimethylamino المركب الأخير هذا مر علينا في ال + +472 +00:48:28,140 --> 00:48:36,240 +unhydrate افتلك unhydrate + +473 +00:48:37,520 --> 00:48:42,140 +على اي حال بيكفي لهذا الجزء الباقي عبارة عن + +474 +00:48:42,140 --> 00:48:46,860 +معادلات شبيهة بالامثلة التانية، بننهي الآن و + +475 +00:48:46,860 --> 00:48:48,720 +بنتمنى لكم التوفيق + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..923a15123444b2c8f031deafe7bfd3ce1eb1b3c9 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_postprocess.srt @@ -0,0 +1,1892 @@ +1 +00:00:21,450 --> 00:00:26,690 +بسم الله الرحمن الرحيم طبعا سعاداء ان احنا نلتقي + +2 +00:00:26,690 --> 00:00:31,710 +فيكم في المحاضرة الأولى في هذا المساق هذا مساق + +3 +00:00:31,710 --> 00:00:38,510 +كيميا عضوية أو كيميا عضوية و حيوية يدرس عادةبأرقام + +4 +00:00:38,510 --> 00:00:43,510 +مختلفة في الجامعة لأكثر من تخصص يعني لطلبة العلوم + +5 +00:00:43,510 --> 00:00:49,690 +الصحية احنا بندرسه بالرقم Bioc 1301 لطلبة كلية + +6 +00:00:49,690 --> 00:00:55,770 +الطب بندرسه بالرقم Medic 1310 ولطلبة العلوم + +7 +00:00:55,770 --> 00:00:59,390 +الحياتية البيولوجيا والبيئة وما إلى ذلك برضه + +8 +00:00:59,390 --> 00:01:07,060 +بندرسه برقم Chem 2311 فكل هؤلاء الطلبةبنشاء الله + +9 +00:01:07,060 --> 00:01:10,700 +بيستطيعوا أنهم يستفيدوا من هذا المساق و اللي يعني + +10 +00:01:10,700 --> 00:01:15,900 +ان شاء الله سيكون مسجل حتى يعني يمكنكم تدارك أي + +11 +00:01:15,900 --> 00:01:19,760 +معلومات نقصت عليكم أثناء يعني سماع المحاضرة + +12 +00:01:19,760 --> 00:01:24,960 +الأصلية، مسموح طبعا أنه يكون في نقاش علمي هادق و + +13 +00:01:24,960 --> 00:01:29,280 +بيظهر في التصويرانتوا كلكم كمان واضحين أمام + +14 +00:01:29,280 --> 00:01:35,120 +الكاميرات ومناقشاتكوا هتكون يعني مثرية لتدريس هذا + +15 +00:01:35,120 --> 00:01:40,020 +المسابق ان شاء الله الكتاب + +16 +00:01:40,020 --> 00:01:45,600 +المقرر هو كتاب مشهور جدا في مجاله كتاب organic + +17 +00:01:45,600 --> 00:01:50,540 +chemistry للمؤلف heart and heart هذا الكتاب طبعا + +18 +00:01:50,540 --> 00:01:55,700 +مع المحتويات الإلكترونية كلها موفرة لكم ان شاء + +19 +00:01:55,700 --> 00:02:01,560 +اللهالجزء الأول من المساقى اللى هندرسه مقدمة في + +20 +00:02:01,560 --> 00:02:06,220 +الكيمياء العضوية بنتعرف جيد على المجموعات الوظيفية + +21 +00:02:06,220 --> 00:02:10,420 +على أنواع المركبات العضوية هذه المقدمة في الكيمياء + +22 +00:02:10,420 --> 00:02:16,400 +العضوية حوالى 11 فاصل لما تصير موجودة عندنا بشكل + +23 +00:02:16,400 --> 00:02:21,960 +جيد بصير بإمكاننا أنه نعطي بعدها مقدمة في الكيمياء + +24 +00:02:21,960 --> 00:02:28,080 +الحيوية باربع فصولان شاء الله بهيك بيكون يعني ال + +25 +00:02:28,080 --> 00:02:32,660 +course اكتملت مكوناته مقدمة في الكيمياع العضوية و + +26 +00:02:32,660 --> 00:02:36,220 +بعد هيك الجزء الثاني من ال course مقدمة في + +27 +00:02:36,220 --> 00:02:43,110 +الكيمياع الحيويةطبعا بدنا نبدأ مباشرة مابضيقش وقت + +28 +00:02:43,110 --> 00:02:47,830 +الفصل الأول في المقدمة في الكيمياء الأضوية مفاهيم + +29 +00:02:47,830 --> 00:02:51,750 +عامة بالذات أنه يعني أنتوا أخدتوا شغلتين أخدتوا + +30 +00:02:51,750 --> 00:02:56,730 +كيمياء عامة في الجامعة و أخدتوا أشياء مختلفة من + +31 +00:02:56,730 --> 00:03:02,090 +الكيمياء في المدارس بعضها أحيانا أو جزء خفيف في + +32 +00:03:02,090 --> 00:03:06,830 +الكيمياء الأضويةهذه الاساسية المبادئ الأساسية + +33 +00:03:06,830 --> 00:03:11,710 +بتساعدكم في انكم تتعاملوا مع مساق الكيميا الأضوية + +34 +00:03:11,710 --> 00:03:19,130 +هذا الفصل اللي في المقدمة هنتكلم فيه عن الارتباط + +35 +00:03:19,130 --> 00:03:22,990 +والتشكل bonding and isomerism يعني طالما انه احنا + +36 +00:03:22,990 --> 00:03:28,650 +بنحكي عن مركبات في الكيميا الأضوية اكيد ذرات معينة + +37 +00:03:28,650 --> 00:03:34,950 +هترتبط تعطيمركب bonding الان هذه الذرات اللى + +38 +00:03:34,950 --> 00:03:40,550 +بترتبط يمكن ان ترتبط بطرق مختلفة وبالتالي يمكن ان + +39 +00:03:40,550 --> 00:03:46,910 +تعطي اكثر من مركب اكثر من شكل او متشكل تماما زى ما + +40 +00:03:46,910 --> 00:03:51,360 +انا هتعامل مع هذه الاقلامهنا بقدر اعمل ارتباط + +41 +00:03:51,360 --> 00:03:54,920 +بينهم كإني عملت مُركّب يعني لو تخيلتوا ان هدولة + +42 +00:03:54,920 --> 00:03:58,840 +تلت ذرات مثلا Carbon, Hydrogen, Oxygen عملوا + +43 +00:03:58,840 --> 00:04:03,820 +مُركّب بطريقة معينة الآن لو غيرت ترتيب هدول الذرات + +44 +00:04:04,600 --> 00:04:10,560 +بكون عملت بكون عملت مركب تاني واضح لو غيرت هدول + +45 +00:04:10,560 --> 00:04:14,760 +الذرات بكون عملت مركب تاني الآن المركب الأول و + +46 +00:04:14,760 --> 00:04:19,540 +المركب الثاني ما العلاقة بينهم هدول المركبين + +47 +00:04:19,540 --> 00:04:25,180 +بنسميهم ايش احنا isomers يعني لما بنقول المركب A و + +48 +00:04:25,180 --> 00:04:31,360 +المركب B they are isomers متشكلاتالآن الظاهرة كلها + +49 +00:04:31,360 --> 00:04:37,980 +إيش بنسميها isomerism، ظاهرة التشكل، و هنتعمق في + +50 +00:04:37,980 --> 00:04:43,280 +هذا الموضوع بالتأكيد أثناء دراستنا، نتعمق في هذا + +51 +00:04:43,280 --> 00:04:48,510 +الموضوع أثناءدراستنا الآن إذا بدنا نبدأ في موضوع + +52 +00:04:48,510 --> 00:04:53,950 +ال bonding طبعا مر عليكم أنواع الروابط مر عليكم + +53 +00:04:53,950 --> 00:04:57,770 +أنواع الروابط اللي بتكون في داخل الجزيئة ارجو + +54 +00:04:57,770 --> 00:05:01,390 +انكوا تنتبهوا اللي بقصده انا في ال bonding اللي + +55 +00:05:01,390 --> 00:05:06,270 +بقصده في ال bonding مش الروابط بين الجزيئات اللي + +56 +00:05:06,270 --> 00:05:11,070 +اسمها intermolecular forces لأ الروابط في داخل + +57 +00:05:11,070 --> 00:05:16,720 +الجزيئةالروابط في داخل الجزيئ يعني في روابط بين + +58 +00:05:16,720 --> 00:05:22,520 +الجزيئات مش هي المقصودة هنا يعني افترضوا مثلا جزيئ + +59 +00:05:22,520 --> 00:05:31,420 +الميّه H2O الان هذا جزيئ هذه جزيئ ميّه تاني HOO + +60 +00:05:33,470 --> 00:05:38,730 +الان هذه الروابط اللى فى داخل الجزئ هي اللى انا + +61 +00:05:38,730 --> 00:05:44,650 +بقصدها فى الكيميا بنعطيها اسم بنقول عنها intra + +62 +00:05:44,650 --> 00:05:49,650 +molecular bonds يعنى روابط within the molecule جوا + +63 +00:05:49,650 --> 00:05:54,030 +الجزئ يعنى هذه الروابط شو بيقول عنها intra + +64 +00:05:56,090 --> 00:06:01,750 +موليكيولار بوندي انترا يعني روابط جوه الجزيه الان + +65 +00:06:01,750 --> 00:06:04,550 +اذا اجيت بعد هيك بقول مثلا في عندى روابط + +66 +00:06:04,550 --> 00:06:09,620 +هيدروجينية بين ال اكسجون و الهيدروجينهذه روابط بين + +67 +00:06:09,620 --> 00:06:15,160 +الجزيئات Intermolecular forces فميزوا الكلمتين + +68 +00:06:15,160 --> 00:06:20,940 +Intramolecular اللي هي الروابط الأصلية القوية اللي + +69 +00:06:20,940 --> 00:06:25,720 +في داخل الجزيئ بينما الروابط بين الجزيئات between + +70 +00:06:25,720 --> 00:06:31,070 +molecules شو بسميها أنا؟Intermolecular forces + +71 +00:06:31,070 --> 00:06:37,790 +الأقوى نوع في الـ Intermolecular forces هذه قوته + +72 +00:06:37,790 --> 00:06:42,230 +مابتيجيش خمسة لعشرة في المية من قوة هذه الروابط + +73 +00:06:42,230 --> 00:06:47,250 +بمعنى لو أنا بدي أكسر الروابط من اللي سهل أني + +74 +00:06:47,250 --> 00:06:53,210 +أكسره ال Intermolecular forces تماما زي ما نتخيل + +75 +00:06:53,210 --> 00:06:59,070 +اتنين بيجوا بيسلموا على بعضفي رابطة أصلية .. رابطة + +76 +00:06:59,070 --> 00:07:04,750 +هذا الكف مع الجسم .. هذي Intramolecular وفي رابطة + +77 +00:07:04,750 --> 00:07:08,010 +بين التنين اللي بيسلموا مع بعض .. هذي + +78 +00:07:08,010 --> 00:07:13,110 +Intermolecular الأن لو ولدين صغار سلموا مع بعض و + +79 +00:07:13,110 --> 00:07:16,550 +الام كل واحدة بدها تسحب ابنها و تمشي في طريقها .. + +80 +00:07:16,550 --> 00:07:22,030 +بيسحبوا الولد أن هي اللي بتنكسر .. هذي الرابطة ولا + +81 +00:07:22,030 --> 00:07:26,400 +هذي الرابطة؟هذه الرابطة الـ Intermolecular Forces + +82 +00:07:26,400 --> 00:07:29,500 +فالـ Intermolecular Forces اللي منها الـ London + +83 +00:07:29,500 --> 00:07:32,740 +Forces و الـ Dipole-Dipole Attractions و الـ + +84 +00:07:32,740 --> 00:07:37,780 +Hydrogen Bonding هذه روابط ضعيفة بين الجزيئات + +85 +00:07:37,780 --> 00:07:41,500 +بتأثر بشكل كبير على الخواص الفيزيائية لكن لما انا + +86 +00:07:41,500 --> 00:07:46,600 +بدأ ادرس تفاعلات و اقول ان التفاعل الكيميائي بعد + +87 +00:07:46,600 --> 00:07:52,500 +شوية كسر وتكوين روابط انا لا اتكلم اطلاقا عن هذه + +88 +00:07:52,500 --> 00:07:57,340 +الروابطأنا بتكلم عن الروابط within the molecule + +89 +00:07:57,340 --> 00:08:02,640 +الـ Intramolecular forces و لما الآن بنصنف أنواع + +90 +00:08:02,640 --> 00:08:07,860 +هذه الروابط و بنحكي ionic bonds و covalent bonds و + +91 +00:08:07,860 --> 00:08:11,680 +coordinate covalent bonds بنكون بنحكي عن الروابط + +92 +00:08:11,680 --> 00:08:18,580 +اللي في جوة الجزء الـ Intramolecularواضح؟ اللي + +93 +00:08:18,580 --> 00:08:24,020 +بتكون الجزء نفسه الان من هذه الروابط زي ما سبق + +94 +00:08:24,020 --> 00:08:27,540 +انكم اتعلمتوا من هذه الروابط زي ما سبق انكم + +95 +00:08:27,540 --> 00:08:33,020 +اتعلمتوا ال ionic bonds ال ionic bonds بتنشأ لما + +96 +00:08:33,020 --> 00:08:37,680 +بيتكون عند أيونات في عناصر معينة عندها إلكترونات + +97 +00:08:37,680 --> 00:08:42,080 +زيادة عادة بتكون موجودة في أول الجدول الدوري على + +98 +00:08:42,080 --> 00:08:47,840 +اليساربنسميها electropositive atoms زي الصوديوم + +99 +00:08:47,840 --> 00:08:51,240 +على سبيل المثال وكلكوا عارفين تركيبه الإلكتروني + +100 +00:08:51,240 --> 00:08:57,780 +1s2 2s2 2b6 3s1 لإن عنده إلكتروني زيادة لو فقدوا + +101 +00:08:57,780 --> 00:09:02,600 +بيصل ال octet structure واضح لكن لما بيفقدوا هيصير + +102 +00:09:02,600 --> 00:09:08,580 +عبارة عن ايونموجة في عند ذرات بنقول عنها electro + +103 +00:09:08,580 --> 00:09:13,000 +negative atoms هدولة نقصهم إلكترون عشان يصلوا لل + +104 +00:09:13,000 --> 00:09:18,480 +octet structures هدولة لو اكتسبوا لو اكتسبوا هذا + +105 +00:09:18,480 --> 00:09:25,500 +الإلكترون بيصيروا ايوناتسالبة زي الكلور مثلا 1s2 + +106 +00:09:25,500 --> 00:09:32,320 +2s2 2b6 بعدين بيصير عندي 3s2 3b5 هذا ال 3b5 ما زال + +107 +00:09:32,320 --> 00:09:37,660 +عنده وسع لإيش لإلكترون واحد لو اكتسب هذا الإلكترون + +108 +00:09:37,660 --> 00:09:42,890 +طبعا هيكتسب أي إلكترون اللي فقط الصوديومهيصير كلور + +109 +00:09:42,890 --> 00:09:47,990 +سالب اذا هنا صار في عندك صوديوم موجب و صار عندك + +110 +00:09:47,990 --> 00:09:51,490 +كلور سالب هدول ال ايونات لما بيعملوا ال attraction + +111 +00:09:51,490 --> 00:09:57,690 +مع بعض بيكونوا ليه ال ionic bond واضح طبعا ممكن + +112 +00:09:57,690 --> 00:10:02,250 +بعض العناصر اللي في المجموعة الثانية يفقدوا + +113 +00:10:02,250 --> 00:10:07,880 +إلكترونين و بيكونواIon موجب اتنين ممكن يفقدوا + +114 +00:10:07,880 --> 00:10:11,240 +تلاتة مثلا زي الالمنيون موجب تلاتة كل هذا الكلام + +115 +00:10:11,240 --> 00:10:16,360 +بتاعي اللي عرفته وكيف نكتب صيغة مركب ايوني هذا + +116 +00:10:16,360 --> 00:10:20,720 +الكلام كله بيمور وين عندنا في الكيمياء العامة + +117 +00:10:20,720 --> 00:10:29,460 +بالنسبة ل ال covalent compounds بيفرقوا بشغلة انه + +118 +00:10:30,790 --> 00:10:35,610 +الروابط اللي بتتكون تتكون نتيجة مشاركة في + +119 +00:10:35,610 --> 00:10:39,210 +الإلكترونات يعني هذه عندها إلكترونات معينة هذه + +120 +00:10:39,210 --> 00:10:43,990 +عندها إلكترونات بيعملوا sharing للإلكترون فكل ذرة + +121 +00:10:43,990 --> 00:10:48,370 +بتصل للتركيب اللي هو المستقر إذا كنا بنحكي عن + +122 +00:10:48,370 --> 00:10:51,710 +هيدروجين كل ذرة بتصير اتنين و اتنين زي مثلا ما + +123 +00:10:51,710 --> 00:10:56,330 +نتخيل هيدروجين فيه إلكترونهذا مش يبين وهيدروجين + +124 +00:10:56,330 --> 00:11:00,050 +فيه إلكترون هيعملوا جزء الهيدروجين كأنه الآن كل + +125 +00:11:00,050 --> 00:11:03,590 +ذرة هيدروجين عندها كام إلكترون اتنين هذا التركيب + +126 +00:11:03,590 --> 00:11:09,840 +ثابت أو الكلور مثلا مداره الأخيرفي سبع إلكترونات + +127 +00:11:09,840 --> 00:11:14,460 +الـ valence shell اللى موجود فيه الآن لما أنا بحكي + +128 +00:11:14,460 --> 00:11:18,940 +عن سبع إلكترونات لو صار مشاركة في هدول الإلكترونات + +129 +00:11:18,940 --> 00:11:23,780 +صارت كل ذرّة كلور كام إلكترون حولها تمانية إذا + +130 +00:11:23,780 --> 00:11:29,240 +عملنا covalent compound كذلك لو بدى أخد H مع CL + +131 +00:11:29,240 --> 00:11:36,830 +برضه الرابط أيش بتكون covalent bondالـ bonds هذه + +132 +00:11:36,830 --> 00:11:42,130 +الـ bonds هذه في إلها إشي بنسميه bond energy هذا + +133 +00:11:42,130 --> 00:11:47,530 +تعبير عن قوة الروابط ال bond energy هو الطاقة + +134 +00:11:47,530 --> 00:11:54,570 +اللازمة لكسر روابط واحد مول من الروابط الواحد مول + +135 +00:11:54,570 --> 00:11:59,410 +عرفينه عدد مضاعف عدد ال 26 من الف في عشر أقصى + +136 +00:11:59,410 --> 00:12:04,030 +تلاتة وعشرينالان عشان اكسر هذه الروابط .. هاي + +137 +00:12:04,030 --> 00:12:08,590 +رابطة .. لما اقول بدي اكسر الرابطة .. ايش بدي؟بدي + +138 +00:12:08,590 --> 00:12:14,870 +طاقة دايما معروف عندنا انه كسر الرابطة عملية بحاجة + +139 +00:12:14,870 --> 00:12:21,590 +الى طاقة بقول عنها endothermic process بينما تكوين + +140 +00:12:21,590 --> 00:12:26,810 +الرابطة عملية طاردة للطاقة بقول عنها exothermic + +141 +00:12:26,810 --> 00:12:31,930 +process فال bond energy هي الطاقة اللي لازم الكسر + +142 +00:12:31,930 --> 00:12:36,170 +روابط او واحد مول من الروابط من ال covalent bonds + +143 +00:12:36,170 --> 00:12:41,180 +كذلكفي عندى إيش اسمه ال bond length ال bond length + +144 +00:12:41,180 --> 00:12:48,660 +هو المسافة المتوسطة ما بين ذرتين ليش مسافة متوسطة + +145 +00:12:48,660 --> 00:12:54,420 +لأنه الرابطة هي عبارة عن مسافة بالفراغ ليست ثابتة + +146 +00:12:54,420 --> 00:12:58,260 +يعني ذرتين بينهم مسافة معينة في الفراغ بنقول هدول + +147 +00:12:58,260 --> 00:13:03,240 +الذرتين بينهم إيش رابطة الآن هذه المسافة تزيد + +148 +00:13:03,240 --> 00:13:08,500 +وتقصرليست ثابتة تماما و لذلك احنا بناخد المسافة + +149 +00:13:08,500 --> 00:13:12,000 +المتوسطة بيصير عندنا ال bond length الآن ال bond + +150 +00:13:12,000 --> 00:13:17,660 +length يقاس عادة بال angstrom اللي هو واحد في عشر + +151 +00:13:17,660 --> 00:13:22,300 +أقص ناقص عشرة من المتر او بنقيسه في ال picometer + +152 +00:13:22,300 --> 00:13:28,140 +اللي هو واحد في عشر أقص ناقص اتنائش من المتر واضح + +153 +00:13:28,140 --> 00:13:34,010 +طبعا لما انقيس ال bond lengthبال بيكميتر هتطلع + +154 +00:13:34,010 --> 00:13:39,330 +أطوال الروابط عندنا سهلة الملاحظة وسهلة الحفظ يعني + +155 +00:13:39,330 --> 00:13:44,630 +خليني أفرجيكم كيف هي أنا بعطيكم مقارنة بين الرابطة + +156 +00:13:44,630 --> 00:13:49,590 +الأحادية هذه الرابطة اللي أنا بقصدها الأحادية + +157 +00:13:49,590 --> 00:13:52,890 +والثنائية والرابطة + +158 +00:13:54,550 --> 00:14:01,830 +الثلاثية الان لاحظوا ان عدد الروابط بيزيد احدية + +159 +00:14:01,830 --> 00:14:07,970 +ثنائية ثلاثية هذا احنا بنسميه ال bond order ايش ال + +160 +00:14:07,970 --> 00:14:11,490 +bond order ال bond order is the number of chemical + +161 +00:14:11,490 --> 00:14:15,850 +bonds between a pair of atoms عدد الروابط ما بين + +162 +00:14:15,850 --> 00:14:22,270 +ذرتين هل يترى هدول الروابط منها ذرتين احديةثنائية + +163 +00:14:22,270 --> 00:14:28,490 +ثلاثية ايش بسمي انا ال bond order الان انتبهوا معي + +164 +00:14:28,490 --> 00:14:31,970 +as the bond order increases يعني كل ما بزيد من + +165 +00:14:31,970 --> 00:14:36,150 +الرابط احدية لا ثنائية لا ثلاثية بقول the bond + +166 +00:14:36,150 --> 00:14:43,810 +will be stronger and shorter بتصير اقوى و اقصر + +167 +00:14:43,810 --> 00:14:48,270 +ليش؟ لان الرابط الاحدية هي عبارة عن sigma bond + +168 +00:14:49,600 --> 00:14:56,440 +الرابطة الثلاثية هي عبارة عن سيجما و باي و لذلك + +169 +00:14:56,440 --> 00:14:57,900 +أصبحت أقوى + +170 +00:15:06,370 --> 00:15:10,150 +بتخيلوها الأيام بتصير سهلة الفهم، هذه sigma bond + +171 +00:15:10,150 --> 00:15:15,350 +فقط، هذه sigma و by bond، هذه sigma و by و by، مين + +172 +00:15:15,350 --> 00:15:20,730 +أكتر واحدة فيها قوة؟ الرابطة الثلاثية، هذا الكلام + +173 +00:15:20,730 --> 00:15:25,930 +بنعكس وين؟ بنعكس على أمركتير مهم في الكيميا قوة + +174 +00:15:25,930 --> 00:15:31,430 +الرابط لان الرابط الثلاثية قوية اللى هى هل يترى + +175 +00:15:31,430 --> 00:15:36,950 +يمكن ان يصير دوران حول الرابط ولا لأ ولذلك اذا + +176 +00:15:36,950 --> 00:15:41,950 +احنا بدنا نيجي نتخيل انه باستعمال ال models نتخيل + +177 +00:15:41,950 --> 00:15:49,350 +انه احنا باستعمال ال models بدنا نعملروابط معينة + +178 +00:15:49,350 --> 00:15:54,030 +نعمل رابطة أحادية هاي رابطة أحادية لو بتطلع علي + +179 +00:15:54,030 --> 00:15:59,270 +هدولة في عندى إمكانية للدوران حول الرابطة الأحادية + +180 +00:15:59,270 --> 00:16:03,990 +رابطة ضعيفة ممكن الأشياء اللى موجودة هنا يكون فيها + +181 +00:16:03,990 --> 00:16:10,710 +دوران الان لو خلتها رابطة ثنائية بهذا الشكل وجربت + +182 +00:16:10,710 --> 00:16:16,490 +أني بدي ألف بيصير عندى ال rotationRestricted + +183 +00:16:16,490 --> 00:16:28,370 +rotation رابطة + +184 +00:16:28,370 --> 00:16:36,390 +ضعيفة رابطة ثنائية Restricted + +185 +00:16:36,390 --> 00:16:42,650 +rotationيعني دوران ممنوع forbidden rotation الان + +186 +00:16:42,650 --> 00:16:51,790 +لو خلتها رابطة ثلاثية بدت تصير اقوى و اقوى اطلاقا + +187 +00:16:51,790 --> 00:16:57,150 +مش ممكن يصير فيه دوران حول الرابطة الثلاثية او + +188 +00:16:57,150 --> 00:17:01,690 +ثنائية صعب جدا واضح هى اللى احنا بدنا نستفيده ان + +189 +00:17:01,690 --> 00:17:07,690 +الرابطة كل ما البند order تبعها زاد بتصير ايش اقوى + +190 +00:17:08,210 --> 00:17:13,710 +وبنفس الوقت الرابطة القوية بتكون رابطة أكثر الذرات + +191 +00:17:13,710 --> 00:17:17,690 +بيصيروا جراب من بعض فلو احنا بدنا نشوف طول الرابطة + +192 +00:17:17,690 --> 00:17:23,190 +في ال بيكوميتر لاحظوا الرابطة الأحدية 154 بيكوميتر + +193 +00:17:23,190 --> 00:17:31,270 +لما بتصير ثنائية 134 بيكوميتر لما بتصير أحدية 121 + +194 +00:17:31,270 --> 00:17:39,100 +بيكوميتر فمين أكثر رابطة الرابطةالتلافية واضحة هذه + +195 +00:17:39,100 --> 00:17:44,440 +النقطة فهذا الكلام بناخده كقاعدة as the bond order + +196 +00:17:44,440 --> 00:17:50,000 +increases the bond will be stronger and shorter + +197 +00:17:50,000 --> 00:17:53,120 +بتصير الرابطة أقوى وأقصى + +198 +00:17:56,880 --> 00:18:01,980 +الان احنا بنعمل روابط بين ذرات مختلفة لعناصر + +199 +00:18:01,980 --> 00:18:06,240 +مختلفة في الكيميا العضوية في الكيميا العضوية ربما + +200 +00:18:06,240 --> 00:18:11,140 +اهم العناصر اللى بيعملوا عندنا الروابط ال carbon و + +201 +00:18:11,140 --> 00:18:14,940 +ال hydrogen ال oxygen ال nitrogen و ال halogens + +202 +00:18:16,050 --> 00:18:20,890 +واضح؟ الان يا ترى كل عنصر من هدول العناصر كام + +203 +00:18:20,890 --> 00:18:25,810 +رابطة بيعمل عندنا لازم نكون عارفين و هذا الكلام + +204 +00:18:25,810 --> 00:18:29,210 +هتلاحظوا يعني لو فتحتوا كتاب الكيميا العضوية من + +205 +00:18:29,210 --> 00:18:35,190 +أول صفحة لآخر صفحة هتلاقوا ان الكربون بيعمل أربع + +206 +00:18:35,190 --> 00:18:42,350 +روابط مش هتلاقوا ولا مركب ولا مركب في الكربون بخمس + +207 +00:18:42,350 --> 00:18:49,240 +روابط واضح النقطة؟مافيش في كل علم الكيميا العضوية + +208 +00:18:49,240 --> 00:18:53,600 +على طوله و عرضه مش هتلاقيه مركب الكربون فيه بخمس + +209 +00:18:53,600 --> 00:18:56,880 +روابط أثناء التفاعل بيكون قاعد بفقد رابطة بيعمل + +210 +00:18:56,880 --> 00:19:01,420 +رابطة هذه حالات أثناء التفاعل بتكون ناشطة و بترجع + +211 +00:19:01,420 --> 00:19:05,620 +للإيش للاربع اللي بيدرسم شكل مركب بيدرسم الكربون + +212 +00:19:05,620 --> 00:19:12,310 +بكام رابطة؟ باربع الأن في ورقة الامتحانحدث ولا حرج + +213 +00:19:12,310 --> 00:19:16,810 +بتعملوا على ال carbon خمس روابط و ست روابط و عشر + +214 +00:19:16,810 --> 00:19:25,420 +روابط كله ايش؟كله غلط مش كله ماشي اربع روابط الآن + +215 +00:19:25,420 --> 00:19:29,820 +خلّينا نطلع على هذه العناصر الأساسية الهيدروجين + +216 +00:19:29,820 --> 00:19:35,340 +عادة بيعمل رابطة واحدة فقط الكاربون بيعمل اربع + +217 +00:19:35,340 --> 00:19:42,090 +روابط النيتروجين بيعمل تلت روابط وبيبقى عليهزوج من + +218 +00:19:42,090 --> 00:19:45,270 +الإلكترونات يعني بيظل على ال nitrogen غير التلات + +219 +00:19:45,270 --> 00:19:50,250 +روابط زوج من الإلكترونات ال oxygen مشهور بنقول عنه + +220 +00:19:50,250 --> 00:19:55,870 +بيعمل رابطتين و يبقى عليه زوجان من الإلكترونات ال + +221 +00:19:55,870 --> 00:19:59,510 +halogens اللي هي الفلور و الكلور و البروم و اليود + +222 +00:19:59,510 --> 00:20:03,330 +اللي هم المجموعة السابعة في الجدول الدوري هدولة + +223 +00:20:03,330 --> 00:20:07,890 +بيعملوا رابطة واحدة و بيبقى عليهم كام زوج من + +224 +00:20:07,890 --> 00:20:13,190 +الإلكتروناتثلاث أزواج، واضح؟ الآن هي أنا راسم + +225 +00:20:13,190 --> 00:20:20,730 +مركّب كبيرلو بتتطلع عليه، كل رأس في هذا المركب + +226 +00:20:20,730 --> 00:20:25,770 +يمثل ذرة كربون إذا لاقيتوا إشي ناقص في أعداد + +227 +00:20:25,770 --> 00:20:30,270 +الروابط، معناه ذلك هذا الشيء اللي ناقص هو عبارة عن + +228 +00:20:30,270 --> 00:20:34,910 +هيدروجين اختصر في الكتابة لأنه إحنا عندنا شيء + +229 +00:20:34,910 --> 00:20:38,530 +بنسميه abbreviated structure اللي هو شكل مختصر + +230 +00:20:38,530 --> 00:20:43,590 +يعني اللي بينفهم ضمنه مرات مابنكتبهشواضح؟ اللي + +231 +00:20:43,590 --> 00:20:47,930 +بينفهم ضمنها مرات مابنكتبوش فلاحظوا مثلا هاي ذرات + +232 +00:20:47,930 --> 00:20:53,830 +ال carbon هذه carbon هذه carbon carbon كل هذه + +233 +00:20:53,830 --> 00:20:59,630 +الذرات كل رأس هنا في الرسم يعتبر ذرة carbon و هاي + +234 +00:20:59,630 --> 00:21:04,470 +كمان carbon لو بنطلع عليهم كلهم كلهم عليهم أربع + +235 +00:21:04,470 --> 00:21:08,610 +روابط إذا في إشي مبين أقل معنا ذلك هذا فيه + +236 +00:21:08,610 --> 00:21:15,600 +هيدروجين اختصراكتابة يعني هذه CH3EC مبينين أربع + +237 +00:21:15,600 --> 00:21:19,720 +روابط هنا يمكن تطلع كربون متصلة بكربون و كربون إذا + +238 +00:21:19,720 --> 00:21:24,240 +ما المختصر هنا ذرتين هيدروجين بتكون تفهموهم يعني + +239 +00:21:24,240 --> 00:21:27,600 +لما نقول إقرأوا إيش فيه هنا بتقولوا هذه عبارة عن + +240 +00:21:27,600 --> 00:21:33,180 +CH2مختصر من hydrogen و hydrogen كتابة هذه من بين + +241 +00:21:33,180 --> 00:21:37,380 +أربع روابط هذه من بين أربعة هذه carbon رابطة تنتين + +242 +00:21:37,380 --> 00:21:41,480 +و تنتين مع ال oxygen سليمة ال oxygen كم رابطة + +243 +00:21:41,480 --> 00:21:48,000 +تنتين ال oxygen هنا بطريقة تانيةرابطتين بمعنى انه + +244 +00:21:48,000 --> 00:21:51,600 +ممكن يكونوا رابطة ثنائية في نهاية العدد تنتين او + +245 +00:21:51,600 --> 00:21:56,540 +رابطتين احديتين مافيش مشكلة كذلك مع ال carbon ممكن + +246 +00:21:56,540 --> 00:22:01,580 +يكونوا اربع روابط احدية ممكن يكون رابطة ثنائية و + +247 +00:22:01,580 --> 00:22:07,200 +رابطتين احديات ممكن تلت روابط يعني رابطة ثلاثية و + +248 +00:22:07,200 --> 00:22:10,360 +رابطة احدية المهم المجموع يكون في النهاية ايش + +249 +00:22:10,360 --> 00:22:13,900 +اربعة المهم المجموع يكون في النهاية اربعة لاحظوا + +250 +00:22:13,900 --> 00:22:19,500 +ال halogen هنارابطة واحدة بيكون أكيد عليه أزواج + +251 +00:22:19,500 --> 00:22:23,580 +إلكترونات لو كنا محتاجين إيه لفهم تفاعل بنكتبها مش + +252 +00:22:23,580 --> 00:22:28,240 +محتاجين عادة مابنكتبهاش يعني لو كنت بدي أكمل أزواج + +253 +00:22:28,240 --> 00:22:33,000 +الإلكترونات هنا أكيد ال oxygen عليه زوجين أكيد ال + +254 +00:22:33,000 --> 00:22:36,100 +nitrogen عليه زوج أكيد ال halogen عليه تلاتة + +255 +00:22:36,100 --> 00:22:42,740 +بالمناسبةبالنسبة لموضوع الروابط رسم الأشكال زي ما + +256 +00:22:42,740 --> 00:22:47,440 +هتلاحظوا ربما بعد two or three slides انه احنا + +257 +00:22:47,440 --> 00:22:54,900 +بنرسم الأشكال بأكثر من طريقة بمعنى ممكن احنا نرسم + +258 +00:22:54,900 --> 00:23:01,620 +شكل مركب بتفصيل كامل يعني نبيّن فيهكل ذرة من + +259 +00:23:01,620 --> 00:23:05,500 +الذرات ممكن نبين في المراكب كل ذرة من الذرات زي ما + +260 +00:23:05,500 --> 00:23:14,600 +احنا رسمين هنا CH3 CH2 CH2 OH هذا قواعد الروابط + +261 +00:23:14,600 --> 00:23:18,740 +كلها بتنطبق عليه سليم الان لو هذا كنت بدي اكتبه + +262 +00:23:18,740 --> 00:23:26,880 +بطريقة الكتابة العادية هاكتبهCH3 CH2 CH2 OH لو بدى + +263 +00:23:26,880 --> 00:23:32,540 +اختصره باستعمال برامج الرسم هارسمه بهذا الشكل واحد + +264 +00:23:32,540 --> 00:23:36,860 +اتنين تلاتة الان هدوله اش يفهموا كرر رأس يفهم + +265 +00:23:37,630 --> 00:23:44,750 +carbon كرر اس يفهم carbon فانا لو شفت هذا المركب و + +266 +00:23:44,750 --> 00:23:51,110 +قلت لطالب اقرأ هذا الشكل المفروض هي تقرأه CH3 CH2 + +267 +00:23:51,110 --> 00:23:58,260 +CH2 OH او مثلا لو شفت مركب زي هذاكل رأس carbon + +268 +00:23:58,260 --> 00:24:03,060 +يعني كم carbon عندى في هذا المركب خمس ذرات carbon + +269 +00:24:03,060 --> 00:24:09,500 +فيقرأ CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +270 +00:24:09,500 --> 00:24:09,800 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +271 +00:24:09,800 --> 00:24:10,480 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +272 +00:24:10,480 --> 00:24:10,520 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +273 +00:24:10,520 --> 00:24:14,220 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +274 +00:24:14,220 --> 00:24:14,280 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +275 +00:24:14,280 --> 00:24:15,020 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +276 +00:24:15,020 --> 00:24:21,380 +CH2 CH2 CH2بدنا نكون متعودين على معرفة الصيغة + +277 +00:24:21,380 --> 00:24:27,240 +الجزائية للمراكبات و حسابها و الروابط المختصرة على + +278 +00:24:27,240 --> 00:24:33,120 +طول احنا بمخنا ايش نعمل نجيبها و نحطها خليني + +279 +00:24:33,120 --> 00:24:40,450 +اعطيكمخليني أعطيكم مثال إضافي أعطيكم مثال إضافي + +280 +00:24:40,450 --> 00:24:49,190 +يعني لو على السريع جربنا مثلا أنه نرسم جزئ زي هيك + +281 +00:24:49,190 --> 00:25:02,150 +و هذا الجزئ عملنا فيه ناخد + +282 +00:25:02,150 --> 00:25:03,990 +ثانية في الرسم مش مشكلة + +283 +00:25:25,060 --> 00:25:30,720 +الان يا تورا هى عندكم جزيق و خلينا نكبره عشان + +284 +00:25:30,720 --> 00:25:36,720 +انتوا كلكم تشوفوه لو سألنا هذا الجزيق اللى موجود + +285 +00:25:36,720 --> 00:25:41,380 +قدامكم ايش صيغته الجزيقية؟ ايش اللى مبينه؟ ايش + +286 +00:25:41,380 --> 00:25:46,250 +اللى مختصر فيه؟واحدة تقولنا إيه صيغته الجزائية، + +287 +00:25:46,250 --> 00:25:54,630 +يعني كام carbon يوجد عندى في هذا الجزء؟ carbon؟ + +288 +00:25:54,630 --> 00:25:57,270 +كل رأس بالنسبة ليه carbon؟ + +289 +00:26:00,180 --> 00:26:05,660 +هذا اللي هنا Carbon، إذاً هذا صيرته الجزائية C5، + +290 +00:26:05,660 --> 00:26:12,800 +الان الأصعب شوية كم هيدروجين عندى في هذا الجزء + +291 +00:26:16,380 --> 00:26:21,680 +كل شي بتكون تكمله حسب ما اتفقنا الكربون لأربع + +292 +00:26:21,680 --> 00:26:28,320 +روابط النيتروجين لثلاثة الأكسجل لرابطتين كل ما هو + +293 +00:26:28,320 --> 00:26:36,020 +محدوث عبارة عن هيدروجين يعني هنا موجود عندي + +294 +00:26:36,020 --> 00:26:43,670 +هيدروجين هنا هيدروجين هنا هيدروجين هناتنتين + +295 +00:26:43,670 --> 00:26:47,530 +هيدروجين هنا عشان يصير الكاربون أربع هذه + +296 +00:26:47,530 --> 00:26:52,010 +النيتروجين كام رابط مابين عليها تنتين تنتين اذا + +297 +00:26:52,010 --> 00:27:04,070 +ينقصها عشان تصير تلت روابط هذه كاربون عدوهم + +298 +00:27:04,070 --> 00:27:10,460 +واحد اتنينأنا أكيد بقول الناس اللي بيقولوا رقم + +299 +00:27:10,460 --> 00:27:15,700 +مفرد هم الكلام الصح و قدوا انتوا اربع ستة تمانية + +300 +00:27:15,700 --> 00:27:26,900 +عشرة احداشر اذا ن ا واضحهي عدد الروابط و بالمناسبة + +301 +00:27:26,900 --> 00:27:30,920 +برنامج الرسم بإمكانه يحسب إن الصيغة تبعت هذا + +302 +00:27:30,920 --> 00:27:34,780 +المركب يعني لو علمناه كيميستر كالكوليت موليكيلار + +303 +00:27:34,780 --> 00:27:39,460 +فاليوز و كالكوليت و قلنا له لزجلنا إياهم هاي + +304 +00:27:39,460 --> 00:27:46,920 +الصيغة إيش حسبها البرنامج اقرأوا C5H11NO + +305 +00:27:46,920 --> 00:27:52,010 +زي ما احنا كتبناها ولا لأ زي ما احنا كتبناهاواضح؟ + +306 +00:27:52,010 --> 00:27:57,110 +فعندكم انتوا برنامج الرسم موجود بإمكانكوا ترسموا + +307 +00:27:57,110 --> 00:28:02,770 +جزيئات زي ما بدكم بإمكانكوا ترسموا جزيئات زي ما + +308 +00:28:02,770 --> 00:28:08,110 +بدكم والبرنامج بحسبها وبالتالي بتقدروا تراجعوا + +309 +00:28:08,110 --> 00:28:12,110 +لنفسكم يعني حتى لو اجت طالبة قالت انا بدي بدل ما + +310 +00:28:12,110 --> 00:28:16,690 +هذه هيدروجين تكون زي هيك الان هذه ايش تصبح؟ carbon + +311 +00:28:20,260 --> 00:28:25,990 +هذا الآن تصبح carbon، كل رأس اسمه carbonهذه من + +312 +00:28:25,990 --> 00:28:29,530 +الأخطاء الشائعة جدا راجعنا نتبهولها ان احنا لما + +313 +00:28:29,530 --> 00:28:32,550 +بنحط رأس زي هيك زي هذا او زي هذا بتيجي الطالب + +314 +00:28:32,550 --> 00:28:36,630 +بتكتب عليه hydrogen لأ هذا الرأس يفهم على انه + +315 +00:28:36,630 --> 00:28:41,370 +carbon مش hydrogen و بالمناسبة لو بدكم تغلطوا + +316 +00:28:41,370 --> 00:28:46,570 +برامج الرسم عادة شاطرة و بتفهمكم يعني لو اجيتوا + +317 +00:28:46,570 --> 00:28:49,470 +تحطوا هنا على ال oxygen رابطة ثالثة يعني هذه + +318 +00:28:49,470 --> 00:28:54,070 +الرابطة نعص و نحط كمان رابطةلاحظوا إيش كتبلكوا + +319 +00:28:54,070 --> 00:28:59,650 +جملة؟ Valence exceeded on atoms زاد الإرتباط على + +320 +00:28:59,650 --> 00:29:04,390 +الذرّار، ليش؟ لأنه أنا قاعد بدأ أحط رابطتين هنا و + +321 +00:29:04,390 --> 00:29:09,690 +رابطة، قداش المجموع بيصير على ال oxygen، تلاتة + +322 +00:29:10,240 --> 00:29:15,300 +بالفعل ولذلك اعطاني اشارة تنبيه انه عدد الارتباط + +323 +00:29:15,300 --> 00:29:19,960 +زاد فانتوا في البيت اتعودوا ان عندكم برامج رسم + +324 +00:29:19,960 --> 00:29:24,480 +معينة او هذا البرنامج ايضا موجود عندكم بترسموا فيه + +325 +00:29:24,480 --> 00:29:28,700 +بتتدربوا كل ما رسمتوا اكتر اتعبتوا اكتربتتدربوا + +326 +00:29:28,700 --> 00:29:33,600 +أكتر على إنكوا تفهموا الأشكال بالشكل السليم، وهذه + +327 +00:29:33,600 --> 00:29:38,460 +مشكلة للمن مابتدربش وبيتعب من البداية، بيتغلب + +328 +00:29:38,460 --> 00:29:41,020 +أثناء دراسته للمسار + +329 +00:29:50,540 --> 00:29:55,560 +هذا بالنسبة للأشكال و كيف نرسمها بأكثر من طريقة و + +330 +00:29:55,560 --> 00:30:00,800 +احنا دائما في الكيميا بنفضل اي طرق الطريقة + +331 +00:30:00,800 --> 00:30:08,170 +المختصرة و انتوا بتكملوا الحساب في اللي هينكمالان + +332 +00:30:08,170 --> 00:30:14,050 +بيجينا برضه من المراجعات شيء متعلق في قطبية + +333 +00:30:14,050 --> 00:30:19,890 +الروابط متى تكون الرابطة قطبية و متى يكون الجزء + +334 +00:30:19,890 --> 00:30:25,870 +قطبيا، الرابطة بتكون قطبية يعني لها قطب موجب و قطب + +335 +00:30:25,870 --> 00:30:31,210 +سالبإذا اختلفت السالبية الـ electronegativity بين + +336 +00:30:31,210 --> 00:30:36,450 +الذرتين تعون الرابطة طبعا الذرة الأكثر سالبية تصبح + +337 +00:30:36,450 --> 00:30:42,290 +كأنها طرف سالب والأقل سالبية تصبح كأنها طرف موجب + +338 +00:30:42,290 --> 00:30:48,770 +وبنعبر عن هذا الكلام بوضع إشارة الشحنةالجزائية + +339 +00:30:48,770 --> 00:30:52,930 +بالحق partial positive أو partial negative في + +340 +00:30:52,930 --> 00:30:57,110 +عندنا احنا جدول للسالبية اعلى السالبيات اللي هي + +341 +00:30:57,110 --> 00:31:02,290 +سالبية الفلورين اربعة فمثلا لو كان عندكوا رابطة + +342 +00:31:02,290 --> 00:31:08,530 +بين الكاربون والفلورين بهذا الشكل هي كاربون الفلور + +343 +00:31:09,820 --> 00:31:14,040 +مين اللي سالبيتها أعلى؟ الـFloor الـFloor، إذا أي + +344 +00:31:14,040 --> 00:31:17,760 +طرف هيكون سالب؟ الـFloor أي طرف هيكون موجب؟ + +345 +00:31:17,760 --> 00:31:23,060 +الـCarbon وقتها بنحط إشارة القطبية إما بهذا الشكل + +346 +00:31:23,060 --> 00:31:28,140 +يفهم إن هذا هو الطرف السالب وهذا هو الطرف الموجب + +347 +00:31:28,140 --> 00:31:33,820 +أو بنحطها بإشارة إن الـFloor بنقول عنه partially + +348 +00:31:33,820 --> 00:31:40,020 +negative والـCarbon partially positiveهذا بالنسبة + +349 +00:31:40,020 --> 00:31:43,820 +لقطبية الروابط الـ polarity of bonds it depends on + +350 +00:31:43,820 --> 00:31:46,820 +the electronegativity difference of the atoms + +351 +00:31:46,820 --> 00:31:52,560 +forming this bond بيعتمدوا على فرق السلبية لكن لو + +352 +00:31:52,560 --> 00:32:00,860 +مثلا قلنا جزء مثل البرومهل يا ترى هذا الجزء .. هذا + +353 +00:32:00,860 --> 00:32:05,900 +الرابط عفوا بين البروم و البروم بتكون قطبية؟ ليش؟ + +354 +00:32:05,900 --> 00:32:09,780 +لأن هذه السلبية زي هذه السلبية فما بيكون في عنده + +355 +00:32:09,780 --> 00:32:17,650 +قطبية بين ذرتين مثل بعضهم تماماو هاي أمثلة كتير + +356 +00:32:17,650 --> 00:32:22,010 +بين الهيدروجين والكلور قطبية تعبر عنها بهذا الشكل + +357 +00:32:22,010 --> 00:32:25,250 +أو بهذا أو بهذا ال carbon و ال nitrogen ال carbon + +358 +00:32:25,250 --> 00:32:29,370 +و ال oxygen كل هذه أمثلة بإمكانكوا ترجعوها واضح أن + +359 +00:32:29,370 --> 00:32:34,630 +الذرتين لمكونات للرابطة مختلفات واحدة سلبيتها أكثر + +360 +00:32:34,630 --> 00:32:38,490 +هتكون هي الطرف السالب والتانية أقل هتكون هي الطرف + +361 +00:32:38,490 --> 00:32:44,270 +الموجبهذا الكلام بينقلنا لقطبية الجزائي الجزائي + +362 +00:32:44,270 --> 00:32:49,310 +يتكون من عدة روابط هل الجزائي بمجمله يكون قطبي ولا + +363 +00:32:49,310 --> 00:32:55,030 +لأ هذا الكلام بيعتمد على إن نجد المحاصلة لهذه + +364 +00:32:55,030 --> 00:33:01,210 +الروابط طبعا أي إنسان بده يوجد محاصلة لازم يفهم + +365 +00:33:01,210 --> 00:33:05,950 +الشكل يعني لو أنا قلتلكم هذه الطاولة بيأثر عليها + +366 +00:33:05,950 --> 00:33:12,210 +قوتين ما المحاصلة؟هتقولولي مباشرة احكيلنا كيف شكل + +367 +00:33:12,210 --> 00:33:15,610 +القوتين، والله إذا القوتين كانوا من هذه الجهة + +368 +00:33:15,610 --> 00:33:20,690 +بيدغطوا، الطاولة هتمشي، هتنجمع القوة الأولى مع + +369 +00:33:20,690 --> 00:33:24,150 +القوة التانية، لو القوتين واحدة بهذا الشكل، واحدة + +370 +00:33:24,150 --> 00:33:29,930 +من اتجاه المعاكسهيسطبوا بعض إذا لكي أعرف المحصلة + +371 +00:33:29,930 --> 00:33:34,130 +لابد إلا أن أعرف الشكل الهندسي والأصل إن هذا موضوع + +372 +00:33:34,130 --> 00:33:38,530 +بتتعلموه في الكيميا العامة مش مجالنا الآن إننا + +373 +00:33:38,530 --> 00:33:42,350 +ناخد ال geometrical structures لكن خلّيني أخد عدة + +374 +00:33:42,350 --> 00:33:46,990 +أمثلة مثلا درسنا إحنا إن الشكل الهندسي لثاني أكسيد + +375 +00:33:46,990 --> 00:33:51,810 +الكربون ليليا الآن الأكسجين عندها قطبية أكتر من + +376 +00:33:51,810 --> 00:33:56,260 +الكربونبناء ع ذلك لو بدأ احكي عن carbon oxygen + +377 +00:33:56,260 --> 00:34:01,840 +bond لها قطبية بهذا الشكلوهذه كمان القطمية بهذا + +378 +00:34:01,840 --> 00:34:05,800 +الشكل ايش بتلاعبوا في القطميتين؟ شطبوا بعض فالجزء + +379 +00:34:05,800 --> 00:34:09,860 +صار non-polar ال carbon dioxide لايه non-polar + +380 +00:34:09,860 --> 00:34:14,460 +بينما لو اجيت للميه، الميه الشكل تبعها ايش ماله؟ V + +381 +00:34:14,460 --> 00:34:19,120 +-shaped او bent، منثني الآن، فيه اندهانة قطمية + +382 +00:34:19,120 --> 00:34:23,900 +بهذا الشكل وبهذا الشكل هدول قوتين جايين بزاوية + +383 +00:34:23,900 --> 00:34:31,010 +المحصلة بتاعتهم وين بتكون؟ بينهمزي هيك هيصف محصلة + +384 +00:34:31,010 --> 00:34:39,000 +الجزاء فجزاء الماء يصبح جزاء قطبة واضح؟لو أخدنا + +385 +00:34:39,000 --> 00:34:43,200 +جزء الميثين اللي مكوّن من أربع روابط و هناخد تفصيل + +386 +00:34:43,200 --> 00:34:47,420 +الشكل تبعه اللي هو tetrahedral structure بإمكاننا + +387 +00:34:47,420 --> 00:34:55,480 +الآن على السريع نعمل شكل لجزء الميثين حتى نتأكد أن + +388 +00:34:55,480 --> 00:35:01,380 +هذا الجزء يترى قطبي ولا غير قطبي هاي عندنا جزء + +389 +00:35:01,380 --> 00:35:09,510 +الميثين بالشكل ال tetrahedral رباع الأوجهو هدولة + +390 +00:35:09,510 --> 00:35:13,690 +اللونهم بوردجاني اللي هم كأنهم بيمثلوا إيش ال + +391 +00:35:13,690 --> 00:35:19,570 +hydrogens الآن بهذا الشكل يكون جزء الميثين لو أنا + +392 +00:35:19,570 --> 00:35:24,550 +إجيت اطلعت كل الروابط قطبية يعني هذا الجزء في أربع + +393 +00:35:24,550 --> 00:35:29,250 +روابط قطبية لكن هذه و هذه لو بدي أعمل له محاصلة + +394 +00:35:29,250 --> 00:35:35,310 +هندسية هذه محاصلتهم الهندسية واضح؟ إذا كأن أنا إيش + +395 +00:35:35,310 --> 00:35:40,170 +عملت لغيت هدولة التنتينوهي المحصلة تبعتهم + +396 +00:35:40,170 --> 00:35:44,110 +الهندسية، طيب في عندي كمان تنتين لورا، وين + +397 +00:35:44,110 --> 00:35:48,250 +محصلتهم؟ بينهم، هي حاطيت محصلة + +398 +00:35:51,050 --> 00:35:55,790 +صار عندى محاصيلتين عكس بعض فجزء الميثين في هذه + +399 +00:35:55,790 --> 00:36:00,070 +الحالة بيكون polar او non-polar؟ non-polar وكذلك + +400 +00:36:00,070 --> 00:36:05,550 +لو كان مثلا carbon tetrachloride يعني carbon متصل + +401 +00:36:05,550 --> 00:36:10,310 +بكمكلور يعني لو بدل هدول ال hydrogen كانوا كلهم + +402 +00:36:10,310 --> 00:36:16,160 +كلورينأربع روابط قطبية أه لكن محصلتها سفر هذا + +403 +00:36:16,160 --> 00:36:19,480 +الأمر مش مستغرب يعني لو انتوا اتيتوا مثلا على هذه + +404 +00:36:19,480 --> 00:36:23,660 +الطاولة جيبتوا أربع رجال أشداء كل واحد عنده قوة + +405 +00:36:23,660 --> 00:36:27,400 +واحد بيضغط بهذا الشكل واحد بهذا الشكل واحد بهذا + +406 +00:36:27,400 --> 00:36:32,400 +الشكل واحد بهذا الشكل هل ستتحرك الطاولة؟ في عندى + +407 +00:36:32,400 --> 00:36:38,280 +أربع قوة لكن محصلتها إيش؟ سفرواضح هذه الفكرة، إذا + +408 +00:36:38,280 --> 00:36:45,540 +قطبية الجزيئات تعتمد على شكلها الهندسي، على محصلة + +409 +00:36:45,540 --> 00:36:47,500 +قطبية الروابط + +410 +00:36:50,510 --> 00:36:55,770 +ما فهمنا احنا الآن ظاهرة ال isomerism او تكون ال + +411 +00:36:55,770 --> 00:37:00,550 +isomers سبق انه احنا قلنا ان ال isomers يمكن هذه + +412 +00:37:00,550 --> 00:37:05,510 +ال slide شوية صغيرة خليني انا اعمل نسخة اكبر منها + +413 +00:37:05,510 --> 00:37:09,730 +شوية ال isomers they are different compounds that + +414 +00:37:09,730 --> 00:37:14,130 +have the same molecular formula اكثر من مركب لهم + +415 +00:37:14,130 --> 00:37:17,750 +نفس الصيغة الجزائية زي ما عملنا في البداية هاي + +416 +00:37:17,750 --> 00:37:22,700 +مثلا مركب بصيغة جزائيةأسود أزرق أحمر هاي مركب + +417 +00:37:22,700 --> 00:37:28,060 +بصيغة جزائية تانية الان المركب الأول و المركب + +418 +00:37:28,060 --> 00:37:32,640 +الثاني شو أنا بسميهم isomers فال isomers they are + +419 +00:37:32,640 --> 00:37:35,840 +different compounds that have the same molecular + +420 +00:37:35,840 --> 00:37:40,320 +formula الان طالما the same molecular formula لو + +421 +00:37:40,320 --> 00:37:44,780 +ناس قالوا the same number of atoms ما هي ال + +422 +00:37:44,780 --> 00:37:49,740 +molecular formulaعدد ذرات لو ناس قالوا the same + +423 +00:37:49,740 --> 00:37:54,700 +molecular weightكله تعبير عن نفس الفكرة طالما نفس + +424 +00:37:54,700 --> 00:38:01,700 +العدد من الذرات إذا نفس الوزن فكل من هذه التعريف + +425 +00:38:01,700 --> 00:38:04,380 +يجوز لنا الناس تعمله different compounds that have + +426 +00:38:04,380 --> 00:38:07,260 +the same molecular formula the same number of + +427 +00:38:07,260 --> 00:38:11,040 +atoms the same molecular weight كل هذا الكلام + +428 +00:38:11,040 --> 00:38:16,240 +بيمشي كتعريف لل isomers الآن ال isomers بشكل عام + +429 +00:38:16,240 --> 00:38:22,710 +تقسم إلى نوعيننوع بنسميه constitutional isomers + +430 +00:38:22,710 --> 00:38:29,010 +وبياخد اسم تاني structural isomersStructural يعني + +431 +00:38:29,010 --> 00:38:34,490 +بنائي و نوع بنسميه stereo isomers فراغي إذا في + +432 +00:38:34,490 --> 00:38:42,170 +عندى متشكلات بنائية و متشكلات فراغية المتشكلات + +433 +00:38:42,170 --> 00:38:45,690 +البنائية ال structural أو ال constitutional + +434 +00:38:45,690 --> 00:38:50,910 +isomers بتكون الذرات نفسها مرتبطة مع بعض البعض + +435 +00:38:50,910 --> 00:38:56,760 +بطرق مختلفةيعني لو افترضت عندى تلت ذرات تنتين + +436 +00:38:56,760 --> 00:39:01,940 +Carbon و واحدة Oxygen هل يا ترى هدولة مربوطين + +437 +00:39:01,940 --> 00:39:07,760 +Carbon Carbon Oxygen ولا Carbon Oxygen Carbon و + +438 +00:39:07,760 --> 00:39:13,180 +بعدين نكمل الهيدروجينات هنا عندى different bonding + +439 +00:39:14,310 --> 00:39:19,050 +واضح؟ carbon carbon oxygen غير عن carbon oxygen + +440 +00:39:19,050 --> 00:39:23,590 +carbon فلو انا اجيت كملت المراكبات هاي المراكبة ده + +441 +00:39:23,590 --> 00:39:29,110 +carbon carbon oxygen CH3 CH2 OH صار عندي مراكب + +442 +00:39:29,110 --> 00:39:38,470 +اسمه الاثانون لو اجيت قولت CH3 OCH3 صار عندي مراكب + +443 +00:39:38,470 --> 00:39:47,340 +تاني اسمه dye مثل etherثنائي مثل ال ether فهذا + +444 +00:39:47,340 --> 00:39:50,760 +اللي بيميز ال structural isomers they have + +445 +00:39:50,760 --> 00:39:55,840 +different bonding different names طالما الارتباط + +446 +00:39:55,840 --> 00:40:01,060 +اختلف اذا كمان الاسماء هتصير ايش مختلفة فاول ما + +447 +00:40:01,060 --> 00:40:05,800 +بنقول احنا structural isomers بدنا نتذكر ان هدولة + +448 +00:40:05,800 --> 00:40:11,850 +فيهم ارتباط مختلف ولهم اسماء مختلفةالنوع التاني من + +449 +00:40:11,850 --> 00:40:17,450 +ال isomers نوع أصعب شوية ولذلك بندرسه احنا ب + +450 +00:40:17,450 --> 00:40:21,730 +chapter منفصل اللي هو الفصل الخامس من المادة هذه + +451 +00:40:21,730 --> 00:40:27,130 +بنسميه stereo isomers ال stereo isomers الذرات + +452 +00:40:27,130 --> 00:40:31,790 +بتكون لها نفس الارتباط يعني هنا أنا قولت same + +453 +00:40:31,790 --> 00:40:35,270 +different bonding في ال stereo isomers على طول + +454 +00:40:35,270 --> 00:40:40,850 +بقول sameconstitution أو same bonding نفس الارتباط + +455 +00:40:40,850 --> 00:40:46,410 +طب نفس الارتباط هوين بيختلفوا؟ بالشكل بالفراغ ممكن + +456 +00:40:46,410 --> 00:40:51,410 +أشياء يكون لها نفس الارتباط وتختلف بالشكل بالفراغ + +457 +00:40:51,410 --> 00:40:55,690 +الجواب أه بدي أعطيكم مثال من برا الكيميا لما + +458 +00:40:55,690 --> 00:41:00,430 +الطلاب في المدرسة بيجفوا بطابور الصبح هي إيد وجسمه + +459 +00:41:00,430 --> 00:41:06,270 +إيد هذا الارتباط إيش هو؟إيد وجسم وإيد، طب لو عملوا + +460 +00:41:06,270 --> 00:41:12,350 +هيك، هذا الشكل، لو عملوا هيك، هذا الشكل، الآن هل + +461 +00:41:12,350 --> 00:41:16,630 +تغير شيء في الإرتباط؟ إيد وجسم إيد + +462 +00:41:19,410 --> 00:41:22,950 +لو عملوا هيك، طب هدول الأشكال التلاتة، لو أخدت + +463 +00:41:22,950 --> 00:41:27,910 +تلات صور و حاطيتهم قدام الطالب وسألته ما العلاقة + +464 +00:41:27,910 --> 00:41:31,990 +بين هدول التلات صور، هيقول لي ال same bonding، + +465 +00:41:31,990 --> 00:41:36,150 +مافكتش ولا إيد من إيدين البني آدم، نفس الإرتباط، + +466 +00:41:36,150 --> 00:41:40,720 +طب أين الاختلاف؟بالشكل الفراغي إذا اللي بيميز ال + +467 +00:41:40,720 --> 00:41:45,060 +stereo isomers ال atoms have the same bonding the + +468 +00:41:45,060 --> 00:41:48,400 +same constitution بط different arrangement in + +469 +00:41:48,400 --> 00:41:52,320 +space لكن شكلهم بالفراغ بختلف طبعا هنتوسع فيهم + +470 +00:41:52,320 --> 00:41:56,220 +نلاحظ أنه في منهم نوع اسمه اناشو مارس و نوع اسمه + +471 +00:41:56,220 --> 00:42:01,340 +استيريو مارس كل هذا التوسع بيكون بفصل كامل اللي هو + +472 +00:42:01,340 --> 00:42:07,570 +الفصلالخامس ابهيك ابننهي اليوم و إلى لقاء آخر ان + +473 +00:42:07,570 --> 00:42:07,950 +شاء الله + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..43833ac798b205762d287a5321a52381a9fa029b --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pFcXHJf6vU8_raw.srt @@ -0,0 +1,1896 @@ +1 +00:00:21,450 --> 00:00:26,690 +بسم الله الرحمن الرحيم طبعا سعاداء ان احنا نلتقي + +2 +00:00:26,690 --> 00:00:31,710 +فيكم في المحاضرة الأولى في هذا المساق هذا مساق + +3 +00:00:31,710 --> 00:00:38,510 +كيميا عضوية أو كيميا عضوية و حيوية يدرس عادةبأرقام + +4 +00:00:38,510 --> 00:00:43,510 +مختلفة في الجامعة لأكثر من تخصص يعني لطلبة العلوم + +5 +00:00:43,510 --> 00:00:49,690 +الصحية احنا بندرسه بالرقم Bioc 1301 لطلبة كلية + +6 +00:00:49,690 --> 00:00:55,770 +الطب بندرسه بالرقم Medic 1310 ولطلبة العلوم + +7 +00:00:55,770 --> 00:00:59,390 +الحياتية البيولوجيا والبيئة وما إلى ذلك برضه + +8 +00:00:59,390 --> 00:01:07,060 +بندرسه برقم Chem 2311 فكل هؤلاء الطلبةبنشاء الله + +9 +00:01:07,060 --> 00:01:10,700 +بيستطيعوا أنهم يستفيدوا من هذا المساق و اللي يعني + +10 +00:01:10,700 --> 00:01:15,900 +ان شاء الله سيكون مسجل حتى يعني يمكنكم تدارك أي + +11 +00:01:15,900 --> 00:01:19,760 +معلومات نقصت عليكم أثناء يعني سماع المحاضرة + +12 +00:01:19,760 --> 00:01:24,960 +الأصلية، مسموح طبعا أنه يكون في نقاش علمي هادق و + +13 +00:01:24,960 --> 00:01:29,280 +بيظهر في التصويرانتوا كلكم كمان واضحين أمام + +14 +00:01:29,280 --> 00:01:35,120 +الكاميرات ومناقشاتكوا هتكون يعني مثرية لتدريس هذا + +15 +00:01:35,120 --> 00:01:40,020 +المسابق ان شاء الله الكتاب + +16 +00:01:40,020 --> 00:01:45,600 +المقرر هو كتاب مشهور جدا في مجاله كتاب organic + +17 +00:01:45,600 --> 00:01:50,540 +chemistry للمؤلف heart and heart هذا الكتاب طبعا + +18 +00:01:50,540 --> 00:01:55,700 +مع المحتويات الإلكترونية كلها موفرة لكم ان شاء + +19 +00:01:55,700 --> 00:02:01,560 +اللهالجزء الأول من المساقى اللى هندرسه مقدمة في + +20 +00:02:01,560 --> 00:02:06,220 +الكيمياء العضوية بنتعرف جيد على المجموعات الوظيفية + +21 +00:02:06,220 --> 00:02:10,420 +على أنواع المركبات العضوية هذه المقدمة في الكيمياء + +22 +00:02:10,420 --> 00:02:16,400 +العضوية حوالى 11 فاصل لما تصير موجودة عندنا بشكل + +23 +00:02:16,400 --> 00:02:21,960 +جيد بصير بإمكاننا أنه نعطي بعدها مقدمة في الكيمياء + +24 +00:02:21,960 --> 00:02:28,080 +الحيوية باربع فصولان شاء الله بهيك بيكون يعني ال + +25 +00:02:28,080 --> 00:02:32,660 +course اكتملت مكوناته مقدمة في الكيمياع العضوية و + +26 +00:02:32,660 --> 00:02:36,220 +بعد هيك الجزء الثاني من ال course مقدمة في + +27 +00:02:36,220 --> 00:02:43,110 +الكيمياع الحيويةطبعا بدنا نبدأ مباشرة مابضيقش وقت + +28 +00:02:43,110 --> 00:02:47,830 +الفصل الأول في المقدمة في الكيمياء الأضوية مفاهيم + +29 +00:02:47,830 --> 00:02:51,750 +عامة بالذات أنه يعني أنتوا أخدتوا شغلتين أخدتوا + +30 +00:02:51,750 --> 00:02:56,730 +كيمياء عامة في الجامعة و أخدتوا أشياء مختلفة من + +31 +00:02:56,730 --> 00:03:02,090 +الكيمياء في المدارس بعضها أحيانا أو جزء خفيف في + +32 +00:03:02,090 --> 00:03:06,830 +الكيمياء الأضويةهذه الاساسية المبادئ الأساسية + +33 +00:03:06,830 --> 00:03:11,710 +بتساعدكم في انكم تتعاملوا مع مساق الكيميا الأضوية + +34 +00:03:11,710 --> 00:03:19,130 +هذا الفصل اللي في المقدمة هنتكلم فيه عن الارتباط + +35 +00:03:19,130 --> 00:03:22,990 +والتشكل bonding and isomerism يعني طالما انه احنا + +36 +00:03:22,990 --> 00:03:28,650 +بنحكي عن مركبات في الكيميا الأضوية اكيد ذرات معينة + +37 +00:03:28,650 --> 00:03:34,950 +هترتبط تعطيمركب bonding الان هذه الذرات اللى + +38 +00:03:34,950 --> 00:03:40,550 +بترتبط يمكن ان ترتبط بطرق مختلفة وبالتالي يمكن ان + +39 +00:03:40,550 --> 00:03:46,910 +تعطي اكثر من مركب اكثر من شكل او متشكل تماما زى ما + +40 +00:03:46,910 --> 00:03:51,360 +انا هتعامل مع هذه الاقلامهنا بقدر اعمل ارتباط + +41 +00:03:51,360 --> 00:03:54,920 +بينهم كإني عملت مُركّب يعني لو تخيلتوا ان هدولة + +42 +00:03:54,920 --> 00:03:58,840 +تلت ذرات مثلا Carbon, Hydrogen, Oxygen عملوا + +43 +00:03:58,840 --> 00:04:03,820 +مُركّب بطريقة معينة الآن لو غيرت ترتيب هدول الذرات + +44 +00:04:04,600 --> 00:04:10,560 +بكون عملت بكون عملت مركب تاني واضح لو غيرت هدول + +45 +00:04:10,560 --> 00:04:14,760 +الذرات بكون عملت مركب تاني الآن المركب الأول و + +46 +00:04:14,760 --> 00:04:19,540 +المركب الثاني ما العلاقة بينهم هدول المركبين + +47 +00:04:19,540 --> 00:04:25,180 +بنسميهم ايش احنا isomers يعني لما بنقول المركب A و + +48 +00:04:25,180 --> 00:04:31,360 +المركب B they are isomers متشكلاتالآن الظاهرة كلها + +49 +00:04:31,360 --> 00:04:37,980 +إيش بنسميها isomerism، ظاهرة التشكل، و هنتعمق في + +50 +00:04:37,980 --> 00:04:43,280 +هذا الموضوع بالتأكيد أثناء دراستنا، نتعمق في هذا + +51 +00:04:43,280 --> 00:04:48,510 +الموضوع أثناءدراستنا الآن إذا بدنا نبدأ في موضوع + +52 +00:04:48,510 --> 00:04:53,950 +ال bonding طبعا مر عليكم أنواع الروابط مر عليكم + +53 +00:04:53,950 --> 00:04:57,770 +أنواع الروابط اللي بتكون في داخل الجزيئة ارجو + +54 +00:04:57,770 --> 00:05:01,390 +انكوا تنتبهوا اللي بقصده انا في ال bonding اللي + +55 +00:05:01,390 --> 00:05:06,270 +بقصده في ال bonding مش الروابط بين الجزيئات اللي + +56 +00:05:06,270 --> 00:05:11,070 +اسمها intermolecular forces لأ الروابط في داخل + +57 +00:05:11,070 --> 00:05:16,720 +الجزيئةالروابط في داخل الجزيئ يعني في روابط بين + +58 +00:05:16,720 --> 00:05:22,520 +الجزيئات مش هي المقصودة هنا يعني افترضوا مثلا جزيئ + +59 +00:05:22,520 --> 00:05:31,420 +الميّه H2O الان هذا جزيئ هذه جزيئ ميّه تاني HOO + +60 +00:05:33,470 --> 00:05:38,730 +الان هذه الروابط اللى فى داخل الجزئ هي اللى انا + +61 +00:05:38,730 --> 00:05:44,650 +بقصدها فى الكيميا بنعطيها اسم بنقول عنها intra + +62 +00:05:44,650 --> 00:05:49,650 +molecular bonds يعنى روابط within the molecule جوا + +63 +00:05:49,650 --> 00:05:54,030 +الجزئ يعنى هذه الروابط شو بيقول عنها intra + +64 +00:05:56,090 --> 00:06:01,750 +موليكيولار بوندي انترا يعني روابط جوه الجزيه الان + +65 +00:06:01,750 --> 00:06:04,550 +اذا اجيت بعد هيك بقول مثلا في عندى روابط + +66 +00:06:04,550 --> 00:06:09,620 +هيدروجينية بين ال اكسجون و الهيدروجينهذه روابط بين + +67 +00:06:09,620 --> 00:06:15,160 +الجزيئات Intermolecular forces فميزوا الكلمتين + +68 +00:06:15,160 --> 00:06:20,940 +Intramolecular اللي هي الروابط الأصلية القوية اللي + +69 +00:06:20,940 --> 00:06:25,720 +في داخل الجزيئ بينما الروابط بين الجزيئات between + +70 +00:06:25,720 --> 00:06:31,070 +molecules شو بسميها أنا؟Intermolecular forces + +71 +00:06:31,070 --> 00:06:37,790 +الأقوى نوع في الـ Intermolecular forces هذه قوته + +72 +00:06:37,790 --> 00:06:42,230 +مابتيجيش خمسة لعشرة في المية من قوة هذه الروابط + +73 +00:06:42,230 --> 00:06:47,250 +بمعنى لو أنا بدي أكسر الروابط من اللي سهل أني + +74 +00:06:47,250 --> 00:06:53,210 +أكسره ال Intermolecular forces تماما زي ما نتخيل + +75 +00:06:53,210 --> 00:06:59,070 +اتنين بيجوا بيسلموا على بعضفي رابطة أصلية .. رابطة + +76 +00:06:59,070 --> 00:07:04,750 +هذا الكف مع الجسم .. هذي Intramolecular وفي رابطة + +77 +00:07:04,750 --> 00:07:08,010 +بين التنين اللي بيسلموا مع بعض .. هذي + +78 +00:07:08,010 --> 00:07:13,110 +Intermolecular الأن لو ولدين صغار سلموا مع بعض و + +79 +00:07:13,110 --> 00:07:16,550 +الام كل واحدة بدها تسحب ابنها و تمشي في طريقها .. + +80 +00:07:16,550 --> 00:07:22,030 +بيسحبوا الولد أن هي اللي بتنكسر .. هذي الرابطة ولا + +81 +00:07:22,030 --> 00:07:26,400 +هذي الرابطة؟هذه الرابطة الـ Intermolecular Forces + +82 +00:07:26,400 --> 00:07:29,500 +فالـ Intermolecular Forces اللي منها الـ London + +83 +00:07:29,500 --> 00:07:32,740 +Forces و الـ Dipole-Dipole Attractions و الـ + +84 +00:07:32,740 --> 00:07:37,780 +Hydrogen Bonding هذه روابط ضعيفة بين الجزيئات + +85 +00:07:37,780 --> 00:07:41,500 +بتأثر بشكل كبير على الخواص الفيزيائية لكن لما انا + +86 +00:07:41,500 --> 00:07:46,600 +بدأ ادرس تفاعلات و اقول ان التفاعل الكيميائي بعد + +87 +00:07:46,600 --> 00:07:52,500 +شوية كسر وتكوين روابط انا لا اتكلم اطلاقا عن هذه + +88 +00:07:52,500 --> 00:07:57,340 +الروابطأنا بتكلم عن الروابط within the molecule + +89 +00:07:57,340 --> 00:08:02,640 +الـ Intramolecular forces و لما الآن بنصنف أنواع + +90 +00:08:02,640 --> 00:08:07,860 +هذه الروابط و بنحكي ionic bonds و covalent bonds و + +91 +00:08:07,860 --> 00:08:11,680 +coordinate covalent bonds بنكون بنحكي عن الروابط + +92 +00:08:11,680 --> 00:08:18,580 +اللي في جوة الجزء الـ Intramolecularواضح؟ اللي + +93 +00:08:18,580 --> 00:08:24,020 +بتكون الجزء نفسه الان من هذه الروابط زي ما سبق + +94 +00:08:24,020 --> 00:08:27,540 +انكم اتعلمتوا من هذه الروابط زي ما سبق انكم + +95 +00:08:27,540 --> 00:08:33,020 +اتعلمتوا ال ionic bonds ال ionic bonds بتنشأ لما + +96 +00:08:33,020 --> 00:08:37,680 +بيتكون عند أيونات في عناصر معينة عندها إلكترونات + +97 +00:08:37,680 --> 00:08:42,080 +زيادة عادة بتكون موجودة في أول الجدول الدوري على + +98 +00:08:42,080 --> 00:08:47,840 +اليساربنسميها electropositive atoms زي الصوديوم + +99 +00:08:47,840 --> 00:08:51,240 +على سبيل المثال وكلكوا عارفين تركيبه الإلكتروني + +100 +00:08:51,240 --> 00:08:57,780 +1s2 2s2 2b6 3s1 لإن عنده إلكتروني زيادة لو فقدوا + +101 +00:08:57,780 --> 00:09:02,600 +بيصل ال octet structure واضح لكن لما بيفقدوا هيصير + +102 +00:09:02,600 --> 00:09:08,580 +عبارة عن ايونموجة في عند ذرات بنقول عنها electro + +103 +00:09:08,580 --> 00:09:13,000 +negative atoms هدولة نقصهم إلكترون عشان يصلوا لل + +104 +00:09:13,000 --> 00:09:18,480 +octet structures هدولة لو اكتسبوا لو اكتسبوا هذا + +105 +00:09:18,480 --> 00:09:25,500 +الإلكترون بيصيروا ايوناتسالبة زي الكلور مثلا 1s2 + +106 +00:09:25,500 --> 00:09:32,320 +2s2 2b6 بعدين بيصير عندي 3s2 3b5 هذا ال 3b5 ما زال + +107 +00:09:32,320 --> 00:09:37,660 +عنده وسع لإيش لإلكترون واحد لو اكتسب هذا الإلكترون + +108 +00:09:37,660 --> 00:09:42,890 +طبعا هيكتسب أي إلكترون اللي فقط الصوديومهيصير كلور + +109 +00:09:42,890 --> 00:09:47,990 +سالب اذا هنا صار في عندك صوديوم موجب و صار عندك + +110 +00:09:47,990 --> 00:09:51,490 +كلور سالب هدول ال ايونات لما بيعملوا ال attraction + +111 +00:09:51,490 --> 00:09:57,690 +مع بعض بيكونوا ليه ال ionic bond واضح طبعا ممكن + +112 +00:09:57,690 --> 00:10:02,250 +بعض العناصر اللي في المجموعة الثانية يفقدوا + +113 +00:10:02,250 --> 00:10:07,880 +إلكترونين و بيكونواIon موجب اتنين ممكن يفقدوا + +114 +00:10:07,880 --> 00:10:11,240 +تلاتة مثلا زي الالمنيون موجب تلاتة كل هذا الكلام + +115 +00:10:11,240 --> 00:10:16,360 +بتاعي اللي عرفته وكيف نكتب صيغة مركب ايوني هذا + +116 +00:10:16,360 --> 00:10:20,720 +الكلام كله بيمور وين عندنا في الكيمياء العامة + +117 +00:10:20,720 --> 00:10:29,460 +بالنسبة ل ال covalent compounds بيفرقوا بشغلة انه + +118 +00:10:30,790 --> 00:10:35,610 +الروابط اللي بتتكون تتكون نتيجة مشاركة في + +119 +00:10:35,610 --> 00:10:39,210 +الإلكترونات يعني هذه عندها إلكترونات معينة هذه + +120 +00:10:39,210 --> 00:10:43,990 +عندها إلكترونات بيعملوا sharing للإلكترون فكل ذرة + +121 +00:10:43,990 --> 00:10:48,370 +بتصل للتركيب اللي هو المستقر إذا كنا بنحكي عن + +122 +00:10:48,370 --> 00:10:51,710 +هيدروجين كل ذرة بتصير اتنين و اتنين زي مثلا ما + +123 +00:10:51,710 --> 00:10:56,330 +نتخيل هيدروجين فيه إلكترونهذا مش يبين وهيدروجين + +124 +00:10:56,330 --> 00:11:00,050 +فيه إلكترون هيعملوا جزء الهيدروجين كأنه الآن كل + +125 +00:11:00,050 --> 00:11:03,590 +ذرة هيدروجين عندها كام إلكترون اتنين هذا التركيب + +126 +00:11:03,590 --> 00:11:09,840 +ثابت أو الكلور مثلا مداره الأخيرفي سبع إلكترونات + +127 +00:11:09,840 --> 00:11:14,460 +الـ valence shell اللى موجود فيه الآن لما أنا بحكي + +128 +00:11:14,460 --> 00:11:18,940 +عن سبع إلكترونات لو صار مشاركة في هدول الإلكترونات + +129 +00:11:18,940 --> 00:11:23,780 +صارت كل ذرّة كلور كام إلكترون حولها تمانية إذا + +130 +00:11:23,780 --> 00:11:29,240 +عملنا covalent compound كذلك لو بدى أخد H مع CL + +131 +00:11:29,240 --> 00:11:36,830 +برضه الرابط أيش بتكون covalent bondالـ bonds هذه + +132 +00:11:36,830 --> 00:11:42,130 +الـ bonds هذه في إلها إشي بنسميه bond energy هذا + +133 +00:11:42,130 --> 00:11:47,530 +تعبير عن قوة الروابط ال bond energy هو الطاقة + +134 +00:11:47,530 --> 00:11:54,570 +اللازمة لكسر روابط واحد مول من الروابط الواحد مول + +135 +00:11:54,570 --> 00:11:59,410 +عرفينه عدد مضاعف عدد ال 26 من الف في عشر أقصى + +136 +00:11:59,410 --> 00:12:04,030 +تلاتة وعشرينالان عشان اكسر هذه الروابط .. هاي + +137 +00:12:04,030 --> 00:12:08,590 +رابطة .. لما اقول بدي اكسر الرابطة .. ايش بدي؟بدي + +138 +00:12:08,590 --> 00:12:14,870 +طاقة دايما معروف عندنا انه كسر الرابطة عملية بحاجة + +139 +00:12:14,870 --> 00:12:21,590 +الى طاقة بقول عنها endothermic process بينما تكوين + +140 +00:12:21,590 --> 00:12:26,810 +الرابطة عملية طاردة للطاقة بقول عنها exothermic + +141 +00:12:26,810 --> 00:12:31,930 +process فال bond energy هي الطاقة اللي لازم الكسر + +142 +00:12:31,930 --> 00:12:36,170 +روابط او واحد مول من الروابط من ال covalent bonds + +143 +00:12:36,170 --> 00:12:41,180 +كذلكفي عندى إيش اسمه ال bond length ال bond length + +144 +00:12:41,180 --> 00:12:48,660 +هو المسافة المتوسطة ما بين ذرتين ليش مسافة متوسطة + +145 +00:12:48,660 --> 00:12:54,420 +لأنه الرابطة هي عبارة عن مسافة بالفراغ ليست ثابتة + +146 +00:12:54,420 --> 00:12:58,260 +يعني ذرتين بينهم مسافة معينة في الفراغ بنقول هدول + +147 +00:12:58,260 --> 00:13:03,240 +الذرتين بينهم إيش رابطة الآن هذه المسافة تزيد + +148 +00:13:03,240 --> 00:13:08,500 +وتقصرليست ثابتة تماما و لذلك احنا بناخد المسافة + +149 +00:13:08,500 --> 00:13:12,000 +المتوسطة بيصير عندنا ال bond length الآن ال bond + +150 +00:13:12,000 --> 00:13:17,660 +length يقاس عادة بال angstrom اللي هو واحد في عشر + +151 +00:13:17,660 --> 00:13:22,300 +أقص ناقص عشرة من المتر او بنقيسه في ال picometer + +152 +00:13:22,300 --> 00:13:28,140 +اللي هو واحد في عشر أقص ناقص اتنائش من المتر واضح + +153 +00:13:28,140 --> 00:13:34,010 +طبعا لما انقيس ال bond lengthبال بيكميتر هتطلع + +154 +00:13:34,010 --> 00:13:39,330 +أطوال الروابط عندنا سهلة الملاحظة وسهلة الحفظ يعني + +155 +00:13:39,330 --> 00:13:44,630 +خليني أفرجيكم كيف هي أنا بعطيكم مقارنة بين الرابطة + +156 +00:13:44,630 --> 00:13:49,590 +الأحادية هذه الرابطة اللي أنا بقصدها الأحادية + +157 +00:13:49,590 --> 00:13:52,890 +والثنائية والرابطة + +158 +00:13:54,550 --> 00:14:01,830 +الثلاثية الان لاحظوا ان عدد الروابط بيزيد احدية + +159 +00:14:01,830 --> 00:14:07,970 +ثنائية ثلاثية هذا احنا بنسميه ال bond order ايش ال + +160 +00:14:07,970 --> 00:14:11,490 +bond order ال bond order is the number of chemical + +161 +00:14:11,490 --> 00:14:15,850 +bonds between a pair of atoms عدد الروابط ما بين + +162 +00:14:15,850 --> 00:14:22,270 +ذرتين هل يترى هدول الروابط منها ذرتين احديةثنائية + +163 +00:14:22,270 --> 00:14:28,490 +ثلاثية ايش بسمي انا ال bond order الان انتبهوا معي + +164 +00:14:28,490 --> 00:14:31,970 +as the bond order increases يعني كل ما بزيد من + +165 +00:14:31,970 --> 00:14:36,150 +الرابط احدية لا ثنائية لا ثلاثية بقول the bond + +166 +00:14:36,150 --> 00:14:43,810 +will be stronger and shorter بتصير اقوى و اقصر + +167 +00:14:43,810 --> 00:14:48,270 +ليش؟ لان الرابط الاحدية هي عبارة عن sigma bond + +168 +00:14:49,600 --> 00:14:56,440 +الرابطة الثلاثية هي عبارة عن سيجما و باي و لذلك + +169 +00:14:56,440 --> 00:14:57,900 +أصبحت أقوى + +170 +00:15:06,370 --> 00:15:10,150 +بتخيلوها الأيام بتصير سهلة الفهم، هذه sigma bond + +171 +00:15:10,150 --> 00:15:15,350 +فقط، هذه sigma و by bond، هذه sigma و by و by، مين + +172 +00:15:15,350 --> 00:15:20,730 +أكتر واحدة فيها قوة؟ الرابطة الثلاثية، هذا الكلام + +173 +00:15:20,730 --> 00:15:25,930 +بنعكس وين؟ بنعكس على أمركتير مهم في الكيميا قوة + +174 +00:15:25,930 --> 00:15:31,430 +الرابط لان الرابط الثلاثية قوية اللى هى هل يترى + +175 +00:15:31,430 --> 00:15:36,950 +يمكن ان يصير دوران حول الرابط ولا لأ ولذلك اذا + +176 +00:15:36,950 --> 00:15:41,950 +احنا بدنا نيجي نتخيل انه باستعمال ال models نتخيل + +177 +00:15:41,950 --> 00:15:49,350 +انه احنا باستعمال ال models بدنا نعملروابط معينة + +178 +00:15:49,350 --> 00:15:54,030 +نعمل رابطة أحادية هاي رابطة أحادية لو بتطلع علي + +179 +00:15:54,030 --> 00:15:59,270 +هدولة في عندى إمكانية للدوران حول الرابطة الأحادية + +180 +00:15:59,270 --> 00:16:03,990 +رابطة ضعيفة ممكن الأشياء اللى موجودة هنا يكون فيها + +181 +00:16:03,990 --> 00:16:10,710 +دوران الان لو خلتها رابطة ثنائية بهذا الشكل وجربت + +182 +00:16:10,710 --> 00:16:16,490 +أني بدي ألف بيصير عندى ال rotationRestricted + +183 +00:16:16,490 --> 00:16:28,370 +rotation رابطة + +184 +00:16:28,370 --> 00:16:36,390 +ضعيفة رابطة ثنائية Restricted + +185 +00:16:36,390 --> 00:16:42,650 +rotationيعني دوران ممنوع forbidden rotation الان + +186 +00:16:42,650 --> 00:16:51,790 +لو خلتها رابطة ثلاثية بدت تصير اقوى و اقوى اطلاقا + +187 +00:16:51,790 --> 00:16:57,150 +مش ممكن يصير فيه دوران حول الرابطة الثلاثية او + +188 +00:16:57,150 --> 00:17:01,690 +ثنائية صعب جدا واضح هى اللى احنا بدنا نستفيده ان + +189 +00:17:01,690 --> 00:17:07,690 +الرابطة كل ما البند order تبعها زاد بتصير ايش اقوى + +190 +00:17:08,210 --> 00:17:13,710 +وبنفس الوقت الرابطة القوية بتكون رابطة أكثر الذرات + +191 +00:17:13,710 --> 00:17:17,690 +بيصيروا جراب من بعض فلو احنا بدنا نشوف طول الرابطة + +192 +00:17:17,690 --> 00:17:23,190 +في ال بيكوميتر لاحظوا الرابطة الأحدية 154 بيكوميتر + +193 +00:17:23,190 --> 00:17:31,270 +لما بتصير ثنائية 134 بيكوميتر لما بتصير أحدية 121 + +194 +00:17:31,270 --> 00:17:39,100 +بيكوميتر فمين أكثر رابطة الرابطةالتلافية واضحة هذه + +195 +00:17:39,100 --> 00:17:44,440 +النقطة فهذا الكلام بناخده كقاعدة as the bond order + +196 +00:17:44,440 --> 00:17:50,000 +increases the bond will be stronger and shorter + +197 +00:17:50,000 --> 00:17:53,120 +بتصير الرابطة أقوى وأقصى + +198 +00:17:56,880 --> 00:18:01,980 +الان احنا بنعمل روابط بين ذرات مختلفة لعناصر + +199 +00:18:01,980 --> 00:18:06,240 +مختلفة في الكيميا العضوية في الكيميا العضوية ربما + +200 +00:18:06,240 --> 00:18:11,140 +اهم العناصر اللى بيعملوا عندنا الروابط ال carbon و + +201 +00:18:11,140 --> 00:18:14,940 +ال hydrogen ال oxygen ال nitrogen و ال halogens + +202 +00:18:16,050 --> 00:18:20,890 +واضح؟ الان يا ترى كل عنصر من هدول العناصر كام + +203 +00:18:20,890 --> 00:18:25,810 +رابطة بيعمل عندنا لازم نكون عارفين و هذا الكلام + +204 +00:18:25,810 --> 00:18:29,210 +هتلاحظوا يعني لو فتحتوا كتاب الكيميا العضوية من + +205 +00:18:29,210 --> 00:18:35,190 +أول صفحة لآخر صفحة هتلاقوا ان الكربون بيعمل أربع + +206 +00:18:35,190 --> 00:18:42,350 +روابط مش هتلاقوا ولا مركب ولا مركب في الكربون بخمس + +207 +00:18:42,350 --> 00:18:49,240 +روابط واضح النقطة؟مافيش في كل علم الكيميا العضوية + +208 +00:18:49,240 --> 00:18:53,600 +على طوله و عرضه مش هتلاقيه مركب الكربون فيه بخمس + +209 +00:18:53,600 --> 00:18:56,880 +روابط أثناء التفاعل بيكون قاعد بفقد رابطة بيعمل + +210 +00:18:56,880 --> 00:19:01,420 +رابطة هذه حالات أثناء التفاعل بتكون ناشطة و بترجع + +211 +00:19:01,420 --> 00:19:05,620 +للإيش للاربع اللي بيدرسم شكل مركب بيدرسم الكربون + +212 +00:19:05,620 --> 00:19:12,310 +بكام رابطة؟ باربع الأن في ورقة الامتحانحدث ولا حرج + +213 +00:19:12,310 --> 00:19:16,810 +بتعملوا على ال carbon خمس روابط و ست روابط و عشر + +214 +00:19:16,810 --> 00:19:25,420 +روابط كله ايش؟كله غلط مش كله ماشي اربع روابط الآن + +215 +00:19:25,420 --> 00:19:29,820 +خلّينا نطلع على هذه العناصر الأساسية الهيدروجين + +216 +00:19:29,820 --> 00:19:35,340 +عادة بيعمل رابطة واحدة فقط الكاربون بيعمل اربع + +217 +00:19:35,340 --> 00:19:42,090 +روابط النيتروجين بيعمل تلت روابط وبيبقى عليهزوج من + +218 +00:19:42,090 --> 00:19:45,270 +الإلكترونات يعني بيظل على ال nitrogen غير التلات + +219 +00:19:45,270 --> 00:19:50,250 +روابط زوج من الإلكترونات ال oxygen مشهور بنقول عنه + +220 +00:19:50,250 --> 00:19:55,870 +بيعمل رابطتين و يبقى عليه زوجان من الإلكترونات ال + +221 +00:19:55,870 --> 00:19:59,510 +halogens اللي هي الفلور و الكلور و البروم و اليود + +222 +00:19:59,510 --> 00:20:03,330 +اللي هم المجموعة السابعة في الجدول الدوري هدولة + +223 +00:20:03,330 --> 00:20:07,890 +بيعملوا رابطة واحدة و بيبقى عليهم كام زوج من + +224 +00:20:07,890 --> 00:20:13,190 +الإلكتروناتثلاث أزواج، واضح؟ الآن هي أنا راسم + +225 +00:20:13,190 --> 00:20:20,730 +مركّب كبيرلو بتتطلع عليه، كل رأس في هذا المركب + +226 +00:20:20,730 --> 00:20:25,770 +يمثل ذرة كربون إذا لاقيتوا إشي ناقص في أعداد + +227 +00:20:25,770 --> 00:20:30,270 +الروابط، معناه ذلك هذا الشيء اللي ناقص هو عبارة عن + +228 +00:20:30,270 --> 00:20:34,910 +هيدروجين اختصر في الكتابة لأنه إحنا عندنا شيء + +229 +00:20:34,910 --> 00:20:38,530 +بنسميه abbreviated structure اللي هو شكل مختصر + +230 +00:20:38,530 --> 00:20:43,590 +يعني اللي بينفهم ضمنه مرات مابنكتبهشواضح؟ اللي + +231 +00:20:43,590 --> 00:20:47,930 +بينفهم ضمنها مرات مابنكتبوش فلاحظوا مثلا هاي ذرات + +232 +00:20:47,930 --> 00:20:53,830 +ال carbon هذه carbon هذه carbon carbon كل هذه + +233 +00:20:53,830 --> 00:20:59,630 +الذرات كل رأس هنا في الرسم يعتبر ذرة carbon و هاي + +234 +00:20:59,630 --> 00:21:04,470 +كمان carbon لو بنطلع عليهم كلهم كلهم عليهم أربع + +235 +00:21:04,470 --> 00:21:08,610 +روابط إذا في إشي مبين أقل معنا ذلك هذا فيه + +236 +00:21:08,610 --> 00:21:15,600 +هيدروجين اختصراكتابة يعني هذه CH3EC مبينين أربع + +237 +00:21:15,600 --> 00:21:19,720 +روابط هنا يمكن تطلع كربون متصلة بكربون و كربون إذا + +238 +00:21:19,720 --> 00:21:24,240 +ما المختصر هنا ذرتين هيدروجين بتكون تفهموهم يعني + +239 +00:21:24,240 --> 00:21:27,600 +لما نقول إقرأوا إيش فيه هنا بتقولوا هذه عبارة عن + +240 +00:21:27,600 --> 00:21:33,180 +CH2مختصر من hydrogen و hydrogen كتابة هذه من بين + +241 +00:21:33,180 --> 00:21:37,380 +أربع روابط هذه من بين أربعة هذه carbon رابطة تنتين + +242 +00:21:37,380 --> 00:21:41,480 +و تنتين مع ال oxygen سليمة ال oxygen كم رابطة + +243 +00:21:41,480 --> 00:21:48,000 +تنتين ال oxygen هنا بطريقة تانيةرابطتين بمعنى انه + +244 +00:21:48,000 --> 00:21:51,600 +ممكن يكونوا رابطة ثنائية في نهاية العدد تنتين او + +245 +00:21:51,600 --> 00:21:56,540 +رابطتين احديتين مافيش مشكلة كذلك مع ال carbon ممكن + +246 +00:21:56,540 --> 00:22:01,580 +يكونوا اربع روابط احدية ممكن يكون رابطة ثنائية و + +247 +00:22:01,580 --> 00:22:07,200 +رابطتين احديات ممكن تلت روابط يعني رابطة ثلاثية و + +248 +00:22:07,200 --> 00:22:10,360 +رابطة احدية المهم المجموع يكون في النهاية ايش + +249 +00:22:10,360 --> 00:22:13,900 +اربعة المهم المجموع يكون في النهاية اربعة لاحظوا + +250 +00:22:13,900 --> 00:22:19,500 +ال halogen هنارابطة واحدة بيكون أكيد عليه أزواج + +251 +00:22:19,500 --> 00:22:23,580 +إلكترونات لو كنا محتاجين إيه لفهم تفاعل بنكتبها مش + +252 +00:22:23,580 --> 00:22:28,240 +محتاجين عادة مابنكتبهاش يعني لو كنت بدي أكمل أزواج + +253 +00:22:28,240 --> 00:22:33,000 +الإلكترونات هنا أكيد ال oxygen عليه زوجين أكيد ال + +254 +00:22:33,000 --> 00:22:36,100 +nitrogen عليه زوج أكيد ال halogen عليه تلاتة + +255 +00:22:36,100 --> 00:22:42,740 +بالمناسبةبالنسبة لموضوع الروابط رسم الأشكال زي ما + +256 +00:22:42,740 --> 00:22:47,440 +هتلاحظوا ربما بعد two or three slides انه احنا + +257 +00:22:47,440 --> 00:22:54,900 +بنرسم الأشكال بأكثر من طريقة بمعنى ممكن احنا نرسم + +258 +00:22:54,900 --> 00:23:01,620 +شكل مركب بتفصيل كامل يعني نبيّن فيهكل ذرة من + +259 +00:23:01,620 --> 00:23:05,500 +الذرات ممكن نبين في المراكب كل ذرة من الذرات زي ما + +260 +00:23:05,500 --> 00:23:14,600 +احنا رسمين هنا CH3 CH2 CH2 OH هذا قواعد الروابط + +261 +00:23:14,600 --> 00:23:18,740 +كلها بتنطبق عليه سليم الان لو هذا كنت بدي اكتبه + +262 +00:23:18,740 --> 00:23:26,880 +بطريقة الكتابة العادية هاكتبهCH3 CH2 CH2 OH لو بدى + +263 +00:23:26,880 --> 00:23:32,540 +اختصره باستعمال برامج الرسم هارسمه بهذا الشكل واحد + +264 +00:23:32,540 --> 00:23:36,860 +اتنين تلاتة الان هدوله اش يفهموا كرر رأس يفهم + +265 +00:23:37,630 --> 00:23:44,750 +carbon كرر اس يفهم carbon فانا لو شفت هذا المركب و + +266 +00:23:44,750 --> 00:23:51,110 +قلت لطالب اقرأ هذا الشكل المفروض هي تقرأه CH3 CH2 + +267 +00:23:51,110 --> 00:23:58,260 +CH2 OH او مثلا لو شفت مركب زي هذاكل رأس carbon + +268 +00:23:58,260 --> 00:24:03,060 +يعني كم carbon عندى في هذا المركب خمس ذرات carbon + +269 +00:24:03,060 --> 00:24:09,500 +فيقرأ CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +270 +00:24:09,500 --> 00:24:09,800 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +271 +00:24:09,800 --> 00:24:10,480 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +272 +00:24:10,480 --> 00:24:10,480 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +273 +00:24:10,480 --> 00:24:10,520 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +274 +00:24:10,520 --> 00:24:14,220 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +275 +00:24:14,220 --> 00:24:14,280 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +276 +00:24:14,280 --> 00:24:15,020 +CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 + +277 +00:24:15,020 --> 00:24:21,380 +CH2 CH2 CH2بدنا نكون متعودين على معرفة الصيغة + +278 +00:24:21,380 --> 00:24:27,240 +الجزائية للمراكبات و حسابها و الروابط المختصرة على + +279 +00:24:27,240 --> 00:24:33,120 +طول احنا بمخنا ايش نعمل نجيبها و نحطها خليني + +280 +00:24:33,120 --> 00:24:40,450 +اعطيكمخليني أعطيكم مثال إضافي أعطيكم مثال إضافي + +281 +00:24:40,450 --> 00:24:49,190 +يعني لو على السريع جربنا مثلا أنه نرسم جزئ زي هيك + +282 +00:24:49,190 --> 00:25:02,150 +و هذا الجزئ عملنا فيه ناخد + +283 +00:25:02,150 --> 00:25:03,990 +ثانية في الرسم مش مشكلة + +284 +00:25:25,060 --> 00:25:30,720 +الان يا تورا هى عندكم جزيق و خلينا نكبره عشان + +285 +00:25:30,720 --> 00:25:36,720 +انتوا كلكم تشوفوه لو سألنا هذا الجزيق اللى موجود + +286 +00:25:36,720 --> 00:25:41,380 +قدامكم ايش صيغته الجزيقية؟ ايش اللى مبينه؟ ايش + +287 +00:25:41,380 --> 00:25:46,250 +اللى مختصر فيه؟واحدة تقولنا إيه صيغته الجزائية، + +288 +00:25:46,250 --> 00:25:54,630 +يعني كام carbon يوجد عندى في هذا الجزء؟ carbon؟ + +289 +00:25:54,630 --> 00:25:57,270 +كل رأس بالنسبة ليه carbon؟ + +290 +00:26:00,180 --> 00:26:05,660 +هذا اللي هنا Carbon، إذاً هذا صيرته الجزائية C5، + +291 +00:26:05,660 --> 00:26:12,800 +الان الأصعب شوية كم هيدروجين عندى في هذا الجزء + +292 +00:26:16,380 --> 00:26:21,680 +كل شي بتكون تكمله حسب ما اتفقنا الكربون لأربع + +293 +00:26:21,680 --> 00:26:28,320 +روابط النيتروجين لثلاثة الأكسجل لرابطتين كل ما هو + +294 +00:26:28,320 --> 00:26:36,020 +محدوث عبارة عن هيدروجين يعني هنا موجود عندي + +295 +00:26:36,020 --> 00:26:43,670 +هيدروجين هنا هيدروجين هنا هيدروجين هناتنتين + +296 +00:26:43,670 --> 00:26:47,530 +هيدروجين هنا عشان يصير الكاربون أربع هذه + +297 +00:26:47,530 --> 00:26:52,010 +النيتروجين كام رابط مابين عليها تنتين تنتين اذا + +298 +00:26:52,010 --> 00:27:04,070 +ينقصها عشان تصير تلت روابط هذه كاربون عدوهم + +299 +00:27:04,070 --> 00:27:10,460 +واحد اتنينأنا أكيد بقول الناس اللي بيقولوا رقم + +300 +00:27:10,460 --> 00:27:15,700 +مفرد هم الكلام الصح و قدوا انتوا اربع ستة تمانية + +301 +00:27:15,700 --> 00:27:26,900 +عشرة احداشر اذا ن ا واضحهي عدد الروابط و بالمناسبة + +302 +00:27:26,900 --> 00:27:30,920 +برنامج الرسم بإمكانه يحسب إن الصيغة تبعت هذا + +303 +00:27:30,920 --> 00:27:34,780 +المركب يعني لو علمناه كيميستر كالكوليت موليكيلار + +304 +00:27:34,780 --> 00:27:39,460 +فاليوز و كالكوليت و قلنا له لزجلنا إياهم هاي + +305 +00:27:39,460 --> 00:27:46,920 +الصيغة إيش حسبها البرنامج اقرأوا C5H11NO + +306 +00:27:46,920 --> 00:27:52,010 +زي ما احنا كتبناها ولا لأ زي ما احنا كتبناهاواضح؟ + +307 +00:27:52,010 --> 00:27:57,110 +فعندكم انتوا برنامج الرسم موجود بإمكانكوا ترسموا + +308 +00:27:57,110 --> 00:28:02,770 +جزيئات زي ما بدكم بإمكانكوا ترسموا جزيئات زي ما + +309 +00:28:02,770 --> 00:28:08,110 +بدكم والبرنامج بحسبها وبالتالي بتقدروا تراجعوا + +310 +00:28:08,110 --> 00:28:12,110 +لنفسكم يعني حتى لو اجت طالبة قالت انا بدي بدل ما + +311 +00:28:12,110 --> 00:28:16,690 +هذه هيدروجين تكون زي هيك الان هذه ايش تصبح؟ carbon + +312 +00:28:20,260 --> 00:28:25,990 +هذا الآن تصبح carbon، كل رأس اسمه carbonهذه من + +313 +00:28:25,990 --> 00:28:29,530 +الأخطاء الشائعة جدا راجعنا نتبهولها ان احنا لما + +314 +00:28:29,530 --> 00:28:32,550 +بنحط رأس زي هيك زي هذا او زي هذا بتيجي الطالب + +315 +00:28:32,550 --> 00:28:36,630 +بتكتب عليه hydrogen لأ هذا الرأس يفهم على انه + +316 +00:28:36,630 --> 00:28:41,370 +carbon مش hydrogen و بالمناسبة لو بدكم تغلطوا + +317 +00:28:41,370 --> 00:28:46,570 +برامج الرسم عادة شاطرة و بتفهمكم يعني لو اجيتوا + +318 +00:28:46,570 --> 00:28:49,470 +تحطوا هنا على ال oxygen رابطة ثالثة يعني هذه + +319 +00:28:49,470 --> 00:28:54,070 +الرابطة نعص و نحط كمان رابطةلاحظوا إيش كتبلكوا + +320 +00:28:54,070 --> 00:28:59,650 +جملة؟ Valence exceeded on atoms زاد الإرتباط على + +321 +00:28:59,650 --> 00:29:04,390 +الذرّار، ليش؟ لأنه أنا قاعد بدأ أحط رابطتين هنا و + +322 +00:29:04,390 --> 00:29:09,690 +رابطة، قداش المجموع بيصير على ال oxygen، تلاتة + +323 +00:29:10,240 --> 00:29:15,300 +بالفعل ولذلك اعطاني اشارة تنبيه انه عدد الارتباط + +324 +00:29:15,300 --> 00:29:19,960 +زاد فانتوا في البيت اتعودوا ان عندكم برامج رسم + +325 +00:29:19,960 --> 00:29:24,480 +معينة او هذا البرنامج ايضا موجود عندكم بترسموا فيه + +326 +00:29:24,480 --> 00:29:28,700 +بتتدربوا كل ما رسمتوا اكتر اتعبتوا اكتربتتدربوا + +327 +00:29:28,700 --> 00:29:33,600 +أكتر على إنكوا تفهموا الأشكال بالشكل السليم، وهذه + +328 +00:29:33,600 --> 00:29:38,460 +مشكلة للمن مابتدربش وبيتعب من البداية، بيتغلب + +329 +00:29:38,460 --> 00:29:41,020 +أثناء دراسته للمسار + +330 +00:29:50,540 --> 00:29:55,560 +هذا بالنسبة للأشكال و كيف نرسمها بأكثر من طريقة و + +331 +00:29:55,560 --> 00:30:00,800 +احنا دائما في الكيميا بنفضل اي طرق الطريقة + +332 +00:30:00,800 --> 00:30:08,170 +المختصرة و انتوا بتكملوا الحساب في اللي هينكمالان + +333 +00:30:08,170 --> 00:30:14,050 +بيجينا برضه من المراجعات شيء متعلق في قطبية + +334 +00:30:14,050 --> 00:30:19,890 +الروابط متى تكون الرابطة قطبية و متى يكون الجزء + +335 +00:30:19,890 --> 00:30:25,870 +قطبيا، الرابطة بتكون قطبية يعني لها قطب موجب و قطب + +336 +00:30:25,870 --> 00:30:31,210 +سالبإذا اختلفت السالبية الـ electronegativity بين + +337 +00:30:31,210 --> 00:30:36,450 +الذرتين تعون الرابطة طبعا الذرة الأكثر سالبية تصبح + +338 +00:30:36,450 --> 00:30:42,290 +كأنها طرف سالب والأقل سالبية تصبح كأنها طرف موجب + +339 +00:30:42,290 --> 00:30:48,770 +وبنعبر عن هذا الكلام بوضع إشارة الشحنةالجزائية + +340 +00:30:48,770 --> 00:30:52,930 +بالحق partial positive أو partial negative في + +341 +00:30:52,930 --> 00:30:57,110 +عندنا احنا جدول للسالبية اعلى السالبيات اللي هي + +342 +00:30:57,110 --> 00:31:02,290 +سالبية الفلورين اربعة فمثلا لو كان عندكوا رابطة + +343 +00:31:02,290 --> 00:31:08,530 +بين الكاربون والفلورين بهذا الشكل هي كاربون الفلور + +344 +00:31:09,820 --> 00:31:14,040 +مين اللي سالبيتها أعلى؟ الـFloor الـFloor، إذا أي + +345 +00:31:14,040 --> 00:31:17,760 +طرف هيكون سالب؟ الـFloor أي طرف هيكون موجب؟ + +346 +00:31:17,760 --> 00:31:23,060 +الـCarbon وقتها بنحط إشارة القطبية إما بهذا الشكل + +347 +00:31:23,060 --> 00:31:28,140 +يفهم إن هذا هو الطرف السالب وهذا هو الطرف الموجب + +348 +00:31:28,140 --> 00:31:33,820 +أو بنحطها بإشارة إن الـFloor بنقول عنه partially + +349 +00:31:33,820 --> 00:31:40,020 +negative والـCarbon partially positiveهذا بالنسبة + +350 +00:31:40,020 --> 00:31:43,820 +لقطبية الروابط الـ polarity of bonds it depends on + +351 +00:31:43,820 --> 00:31:46,820 +the electronegativity difference of the atoms + +352 +00:31:46,820 --> 00:31:52,560 +forming this bond بيعتمدوا على فرق السلبية لكن لو + +353 +00:31:52,560 --> 00:32:00,860 +مثلا قلنا جزء مثل البرومهل يا ترى هذا الجزء .. هذا + +354 +00:32:00,860 --> 00:32:05,900 +الرابط عفوا بين البروم و البروم بتكون قطبية؟ ليش؟ + +355 +00:32:05,900 --> 00:32:09,780 +لأن هذه السلبية زي هذه السلبية فما بيكون في عنده + +356 +00:32:09,780 --> 00:32:17,650 +قطبية بين ذرتين مثل بعضهم تماماو هاي أمثلة كتير + +357 +00:32:17,650 --> 00:32:22,010 +بين الهيدروجين والكلور قطبية تعبر عنها بهذا الشكل + +358 +00:32:22,010 --> 00:32:25,250 +أو بهذا أو بهذا ال carbon و ال nitrogen ال carbon + +359 +00:32:25,250 --> 00:32:29,370 +و ال oxygen كل هذه أمثلة بإمكانكوا ترجعوها واضح أن + +360 +00:32:29,370 --> 00:32:34,630 +الذرتين لمكونات للرابطة مختلفات واحدة سلبيتها أكثر + +361 +00:32:34,630 --> 00:32:38,490 +هتكون هي الطرف السالب والتانية أقل هتكون هي الطرف + +362 +00:32:38,490 --> 00:32:44,270 +الموجبهذا الكلام بينقلنا لقطبية الجزائي الجزائي + +363 +00:32:44,270 --> 00:32:49,310 +يتكون من عدة روابط هل الجزائي بمجمله يكون قطبي ولا + +364 +00:32:49,310 --> 00:32:55,030 +لأ هذا الكلام بيعتمد على إن نجد المحاصلة لهذه + +365 +00:32:55,030 --> 00:33:01,210 +الروابط طبعا أي إنسان بده يوجد محاصلة لازم يفهم + +366 +00:33:01,210 --> 00:33:05,950 +الشكل يعني لو أنا قلتلكم هذه الطاولة بيأثر عليها + +367 +00:33:05,950 --> 00:33:12,210 +قوتين ما المحاصلة؟هتقولولي مباشرة احكيلنا كيف شكل + +368 +00:33:12,210 --> 00:33:15,610 +القوتين، والله إذا القوتين كانوا من هذه الجهة + +369 +00:33:15,610 --> 00:33:20,690 +بيدغطوا، الطاولة هتمشي، هتنجمع القوة الأولى مع + +370 +00:33:20,690 --> 00:33:24,150 +القوة التانية، لو القوتين واحدة بهذا الشكل، واحدة + +371 +00:33:24,150 --> 00:33:29,930 +من اتجاه المعاكسهيسطبوا بعض إذا لكي أعرف المحصلة + +372 +00:33:29,930 --> 00:33:34,130 +لابد إلا أن أعرف الشكل الهندسي والأصل إن هذا موضوع + +373 +00:33:34,130 --> 00:33:38,530 +بتتعلموه في الكيميا العامة مش مجالنا الآن إننا + +374 +00:33:38,530 --> 00:33:42,350 +ناخد ال geometrical structures لكن خلّيني أخد عدة + +375 +00:33:42,350 --> 00:33:46,990 +أمثلة مثلا درسنا إحنا إن الشكل الهندسي لثاني أكسيد + +376 +00:33:46,990 --> 00:33:51,810 +الكربون ليليا الآن الأكسجين عندها قطبية أكتر من + +377 +00:33:51,810 --> 00:33:56,260 +الكربونبناء ع ذلك لو بدأ احكي عن carbon oxygen + +378 +00:33:56,260 --> 00:34:01,840 +bond لها قطبية بهذا الشكلوهذه كمان القطمية بهذا + +379 +00:34:01,840 --> 00:34:05,800 +الشكل ايش بتلاعبوا في القطميتين؟ شطبوا بعض فالجزء + +380 +00:34:05,800 --> 00:34:09,860 +صار non-polar ال carbon dioxide لايه non-polar + +381 +00:34:09,860 --> 00:34:14,460 +بينما لو اجيت للميه، الميه الشكل تبعها ايش ماله؟ V + +382 +00:34:14,460 --> 00:34:19,120 +-shaped او bent، منثني الآن، فيه اندهانة قطمية + +383 +00:34:19,120 --> 00:34:23,900 +بهذا الشكل وبهذا الشكل هدول قوتين جايين بزاوية + +384 +00:34:23,900 --> 00:34:31,010 +المحصلة بتاعتهم وين بتكون؟ بينهمزي هيك هيصف محصلة + +385 +00:34:31,010 --> 00:34:39,000 +الجزاء فجزاء الماء يصبح جزاء قطبة واضح؟لو أخدنا + +386 +00:34:39,000 --> 00:34:43,200 +جزء الميثين اللي مكوّن من أربع روابط و هناخد تفصيل + +387 +00:34:43,200 --> 00:34:47,420 +الشكل تبعه اللي هو tetrahedral structure بإمكاننا + +388 +00:34:47,420 --> 00:34:55,480 +الآن على السريع نعمل شكل لجزء الميثين حتى نتأكد أن + +389 +00:34:55,480 --> 00:35:01,380 +هذا الجزء يترى قطبي ولا غير قطبي هاي عندنا جزء + +390 +00:35:01,380 --> 00:35:09,510 +الميثين بالشكل ال tetrahedral رباع الأوجهو هدولة + +391 +00:35:09,510 --> 00:35:13,690 +اللونهم بوردجاني اللي هم كأنهم بيمثلوا إيش ال + +392 +00:35:13,690 --> 00:35:19,570 +hydrogens الآن بهذا الشكل يكون جزء الميثين لو أنا + +393 +00:35:19,570 --> 00:35:24,550 +إجيت اطلعت كل الروابط قطبية يعني هذا الجزء في أربع + +394 +00:35:24,550 --> 00:35:29,250 +روابط قطبية لكن هذه و هذه لو بدي أعمل له محاصلة + +395 +00:35:29,250 --> 00:35:35,310 +هندسية هذه محاصلتهم الهندسية واضح؟ إذا كأن أنا إيش + +396 +00:35:35,310 --> 00:35:40,170 +عملت لغيت هدولة التنتينوهي المحصلة تبعتهم + +397 +00:35:40,170 --> 00:35:44,110 +الهندسية، طيب في عندي كمان تنتين لورا، وين + +398 +00:35:44,110 --> 00:35:48,250 +محصلتهم؟ بينهم، هي حاطيت محصلة + +399 +00:35:51,050 --> 00:35:55,790 +صار عندى محاصيلتين عكس بعض فجزء الميثين في هذه + +400 +00:35:55,790 --> 00:36:00,070 +الحالة بيكون polar او non-polar؟ non-polar وكذلك + +401 +00:36:00,070 --> 00:36:05,550 +لو كان مثلا carbon tetrachloride يعني carbon متصل + +402 +00:36:05,550 --> 00:36:10,310 +بكمكلور يعني لو بدل هدول ال hydrogen كانوا كلهم + +403 +00:36:10,310 --> 00:36:16,160 +كلورينأربع روابط قطبية أه لكن محصلتها سفر هذا + +404 +00:36:16,160 --> 00:36:19,480 +الأمر مش مستغرب يعني لو انتوا اتيتوا مثلا على هذه + +405 +00:36:19,480 --> 00:36:23,660 +الطاولة جيبتوا أربع رجال أشداء كل واحد عنده قوة + +406 +00:36:23,660 --> 00:36:27,400 +واحد بيضغط بهذا الشكل واحد بهذا الشكل واحد بهذا + +407 +00:36:27,400 --> 00:36:32,400 +الشكل واحد بهذا الشكل هل ستتحرك الطاولة؟ في عندى + +408 +00:36:32,400 --> 00:36:38,280 +أربع قوة لكن محصلتها إيش؟ سفرواضح هذه الفكرة، إذا + +409 +00:36:38,280 --> 00:36:45,540 +قطبية الجزيئات تعتمد على شكلها الهندسي، على محصلة + +410 +00:36:45,540 --> 00:36:47,500 +قطبية الروابط + +411 +00:36:50,510 --> 00:36:55,770 +ما فهمنا احنا الآن ظاهرة ال isomerism او تكون ال + +412 +00:36:55,770 --> 00:37:00,550 +isomers سبق انه احنا قلنا ان ال isomers يمكن هذه + +413 +00:37:00,550 --> 00:37:05,510 +ال slide شوية صغيرة خليني انا اعمل نسخة اكبر منها + +414 +00:37:05,510 --> 00:37:09,730 +شوية ال isomers they are different compounds that + +415 +00:37:09,730 --> 00:37:14,130 +have the same molecular formula اكثر من مركب لهم + +416 +00:37:14,130 --> 00:37:17,750 +نفس الصيغة الجزائية زي ما عملنا في البداية هاي + +417 +00:37:17,750 --> 00:37:22,700 +مثلا مركب بصيغة جزائيةأسود أزرق أحمر هاي مركب + +418 +00:37:22,700 --> 00:37:28,060 +بصيغة جزائية تانية الان المركب الأول و المركب + +419 +00:37:28,060 --> 00:37:32,640 +الثاني شو أنا بسميهم isomers فال isomers they are + +420 +00:37:32,640 --> 00:37:35,840 +different compounds that have the same molecular + +421 +00:37:35,840 --> 00:37:40,320 +formula الان طالما the same molecular formula لو + +422 +00:37:40,320 --> 00:37:44,780 +ناس قالوا the same number of atoms ما هي ال + +423 +00:37:44,780 --> 00:37:49,740 +molecular formulaعدد ذرات لو ناس قالوا the same + +424 +00:37:49,740 --> 00:37:54,700 +molecular weightكله تعبير عن نفس الفكرة طالما نفس + +425 +00:37:54,700 --> 00:38:01,700 +العدد من الذرات إذا نفس الوزن فكل من هذه التعريف + +426 +00:38:01,700 --> 00:38:04,380 +يجوز لنا الناس تعمله different compounds that have + +427 +00:38:04,380 --> 00:38:07,260 +the same molecular formula the same number of + +428 +00:38:07,260 --> 00:38:11,040 +atoms the same molecular weight كل هذا الكلام + +429 +00:38:11,040 --> 00:38:16,240 +بيمشي كتعريف لل isomers الآن ال isomers بشكل عام + +430 +00:38:16,240 --> 00:38:22,710 +تقسم إلى نوعيننوع بنسميه constitutional isomers + +431 +00:38:22,710 --> 00:38:29,010 +وبياخد اسم تاني structural isomersStructural يعني + +432 +00:38:29,010 --> 00:38:34,490 +بنائي و نوع بنسميه stereo isomers فراغي إذا في + +433 +00:38:34,490 --> 00:38:42,170 +عندى متشكلات بنائية و متشكلات فراغية المتشكلات + +434 +00:38:42,170 --> 00:38:45,690 +البنائية ال structural أو ال constitutional + +435 +00:38:45,690 --> 00:38:50,910 +isomers بتكون الذرات نفسها مرتبطة مع بعض البعض + +436 +00:38:50,910 --> 00:38:56,760 +بطرق مختلفةيعني لو افترضت عندى تلت ذرات تنتين + +437 +00:38:56,760 --> 00:39:01,940 +Carbon و واحدة Oxygen هل يا ترى هدولة مربوطين + +438 +00:39:01,940 --> 00:39:07,760 +Carbon Carbon Oxygen ولا Carbon Oxygen Carbon و + +439 +00:39:07,760 --> 00:39:13,180 +بعدين نكمل الهيدروجينات هنا عندى different bonding + +440 +00:39:14,310 --> 00:39:19,050 +واضح؟ carbon carbon oxygen غير عن carbon oxygen + +441 +00:39:19,050 --> 00:39:23,590 +carbon فلو انا اجيت كملت المراكبات هاي المراكبة ده + +442 +00:39:23,590 --> 00:39:29,110 +carbon carbon oxygen CH3 CH2 OH صار عندي مراكب + +443 +00:39:29,110 --> 00:39:38,470 +اسمه الاثانون لو اجيت قولت CH3 OCH3 صار عندي مراكب + +444 +00:39:38,470 --> 00:39:47,340 +تاني اسمه dye مثل etherثنائي مثل ال ether فهذا + +445 +00:39:47,340 --> 00:39:50,760 +اللي بيميز ال structural isomers they have + +446 +00:39:50,760 --> 00:39:55,840 +different bonding different names طالما الارتباط + +447 +00:39:55,840 --> 00:40:01,060 +اختلف اذا كمان الاسماء هتصير ايش مختلفة فاول ما + +448 +00:40:01,060 --> 00:40:05,800 +بنقول احنا structural isomers بدنا نتذكر ان هدولة + +449 +00:40:05,800 --> 00:40:11,850 +فيهم ارتباط مختلف ولهم اسماء مختلفةالنوع التاني من + +450 +00:40:11,850 --> 00:40:17,450 +ال isomers نوع أصعب شوية ولذلك بندرسه احنا ب + +451 +00:40:17,450 --> 00:40:21,730 +chapter منفصل اللي هو الفصل الخامس من المادة هذه + +452 +00:40:21,730 --> 00:40:27,130 +بنسميه stereo isomers ال stereo isomers الذرات + +453 +00:40:27,130 --> 00:40:31,790 +بتكون لها نفس الارتباط يعني هنا أنا قولت same + +454 +00:40:31,790 --> 00:40:35,270 +different bonding في ال stereo isomers على طول + +455 +00:40:35,270 --> 00:40:40,850 +بقول sameconstitution أو same bonding نفس الارتباط + +456 +00:40:40,850 --> 00:40:46,410 +طب نفس الارتباط هوين بيختلفوا؟ بالشكل بالفراغ ممكن + +457 +00:40:46,410 --> 00:40:51,410 +أشياء يكون لها نفس الارتباط وتختلف بالشكل بالفراغ + +458 +00:40:51,410 --> 00:40:55,690 +الجواب أه بدي أعطيكم مثال من برا الكيميا لما + +459 +00:40:55,690 --> 00:41:00,430 +الطلاب في المدرسة بيجفوا بطابور الصبح هي إيد وجسمه + +460 +00:41:00,430 --> 00:41:06,270 +إيد هذا الارتباط إيش هو؟إيد وجسم وإيد، طب لو عملوا + +461 +00:41:06,270 --> 00:41:12,350 +هيك، هذا الشكل، لو عملوا هيك، هذا الشكل، الآن هل + +462 +00:41:12,350 --> 00:41:16,630 +تغير شيء في الإرتباط؟ إيد وجسم إيد + +463 +00:41:19,410 --> 00:41:22,950 +لو عملوا هيك، طب هدول الأشكال التلاتة، لو أخدت + +464 +00:41:22,950 --> 00:41:27,910 +تلات صور و حاطيتهم قدام الطالب وسألته ما العلاقة + +465 +00:41:27,910 --> 00:41:31,990 +بين هدول التلات صور، هيقول لي ال same bonding، + +466 +00:41:31,990 --> 00:41:36,150 +مافكتش ولا إيد من إيدين البني آدم، نفس الإرتباط، + +467 +00:41:36,150 --> 00:41:40,720 +طب أين الاختلاف؟بالشكل الفراغي إذا اللي بيميز ال + +468 +00:41:40,720 --> 00:41:45,060 +stereo isomers ال atoms have the same bonding the + +469 +00:41:45,060 --> 00:41:48,400 +same constitution بط different arrangement in + +470 +00:41:48,400 --> 00:41:52,320 +space لكن شكلهم بالفراغ بختلف طبعا هنتوسع فيهم + +471 +00:41:52,320 --> 00:41:56,220 +نلاحظ أنه في منهم نوع اسمه اناشو مارس و نوع اسمه + +472 +00:41:56,220 --> 00:42:01,340 +استيريو مارس كل هذا التوسع بيكون بفصل كامل اللي هو + +473 +00:42:01,340 --> 00:42:07,570 +الفصلالخامس ابهيك ابننهي اليوم و إلى لقاء آخر ان + +474 +00:42:07,570 --> 00:42:07,950 +شاء الله + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..6f43cfbb6d243533290d25e595034f5494115967 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_postprocess.srt @@ -0,0 +1,2188 @@ +1 +00:00:19,570 --> 00:00:26,370 +بسم الله الرحمن الرحيم اليوم ضيلنا أشياء بسيطة في + +2 +00:00:26,370 --> 00:00:30,890 +موضوع ال amines قبل ما ننتقل لجزء ال biochemistry + +3 +00:00:30,890 --> 00:00:36,850 +طبعا اتفقنا المرة الماضية أن ال amines هم مراكبات + +4 +00:00:36,850 --> 00:00:43,470 +ال nitrogen من أهم الأشياء اللي بتميزهم هو وجود + +5 +00:00:43,470 --> 00:00:47,730 +إيشالـ lone pair of electrons اللي موجودة على الـ + +6 +00:00:47,730 --> 00:00:52,910 +Nitrogens طالما في عليهم lone pair of electrons و + +7 +00:00:52,910 --> 00:00:56,150 +ال base is electron donor يعني ال base هي اللي + +8 +00:00:56,150 --> 00:01:02,370 +بتعطي إلكترونات فال amines arebasis واضح سبب أنه + +9 +00:01:02,370 --> 00:01:06,730 +بالأمينز قواعد هو وجود أزواج الإلكترونات فهم + +10 +00:01:06,730 --> 00:01:11,010 +كقاعدة بيعطوا أزواج إلكترونات هذا ضمن تعريف إيش + +11 +00:01:11,010 --> 00:01:19,710 +Lewis definition الآن لو إجالهم H plus عندي زوج + +12 +00:01:19,710 --> 00:01:23,270 +إلكترونات والـ H مش حاملة إلكترونات شو هيعملوا + +13 +00:01:23,270 --> 00:01:28,420 +فيها؟هيتفاعلوا معها هتصير الرابط المتكونة + +14 +00:01:28,420 --> 00:01:31,840 +Coordinated Covalent bond بمعنى ان زوجين + +15 +00:01:31,840 --> 00:01:37,940 +الالكترونات من النيتروجين والـ H بلس لما تتفاعل + +16 +00:01:37,940 --> 00:01:43,340 +معها بتكون مش حاملة الالكترونات ولذلك مثلا هنا + +17 +00:01:43,340 --> 00:01:48,380 +ارسملكوا كيف الأمونيا لو اتفاعل معها H بلس لاحظوا + +18 +00:01:48,380 --> 00:01:52,990 +الأمونيا الأن H3أساساً الـNitrogen في مداره + +19 +00:01:52,990 --> 00:01:57,070 +الخارجي خمس إلكترونات، فلو تخيلتم اللي كانوا + +20 +00:01:57,070 --> 00:02:00,470 +باللون الأزرق، تلاتة منهم عملوا روابط مع + +21 +00:02:00,470 --> 00:02:03,670 +الـHydrogen، فهذه الرابطة مع الـHydrogen في + +22 +00:02:03,670 --> 00:02:07,510 +الأمونيا أصلاً، إلكترون من الـNitrogen وإلكترون من + +23 +00:02:07,510 --> 00:02:11,040 +الـHydrogen، اللي بيانه بالأخضركذلك الرابط الثاني + +24 +00:02:11,040 --> 00:02:15,520 +والرابط الثالثة بقى عندي زوج إلكترونات إجاله H من + +25 +00:02:15,520 --> 00:02:21,180 +الخارج الـH إجت بدون إلكترونات بناء على ذلك الرابط + +26 +00:02:21,180 --> 00:02:24,560 +اللي هنا إيش بده تصير Coordinate Covalent bond + +27 +00:02:24,560 --> 00:02:29,460 +بمعنى أصلها أنه two electrons from the nitrogen + +28 +00:02:29,460 --> 00:02:35,300 +and no electron from hydrogen طبعا هذا بيخلي برضه + +29 +00:02:35,300 --> 00:02:41,700 +ال aminesباسيز بمفهوم لوري برونستيد definition + +30 +00:02:41,700 --> 00:02:47,240 +ليش؟ لأنه بمفهومه إن الحامض هو اللي بيعطي H plus + +31 +00:02:47,240 --> 00:02:53,180 +والباس هي اللي بتكتسب H plus الآن هذه اكتسبت H + +32 +00:02:53,180 --> 00:02:57,600 +plus ولا لأ؟ إذا أيضا ضمن تعريف لوري برونستيد + +33 +00:02:57,600 --> 00:03:03,860 +definition بتكون هذه base لكن لاحظوا ضمن تعريف + +34 +00:03:03,860 --> 00:03:09,080 +Arrheniusإن الـ base لازم يكون فيها OH- الأمونية + +35 +00:03:09,080 --> 00:03:13,420 +ما انحسبتش base و لذلك اتدرجوا في تعريفية الأحماض + +36 +00:03:13,420 --> 00:03:17,740 +يعني كان أقدم تعريف Arrhenius depression كان حاصر + +37 +00:03:17,740 --> 00:03:22,280 +ال bases في المواد ال hydroxides اللي بيعطوا ال OH + +38 +00:03:22,280 --> 00:03:29,060 +- بعد إكسرنا نقول لأ هو كل حاجة بتكتسب H plus يمكن + +39 +00:03:29,060 --> 00:03:33,960 +أننا نعتبرها base أساسا ال OH- كانت تكتسب H plus و + +40 +00:03:33,960 --> 00:03:39,160 +تعمل ميهواضح طب ما الأن H3 كمان بتكتسب جعب H plus + +41 +00:03:39,160 --> 00:03:47,280 +واضح الفكرة وإجا اللي هو Lewis definition أكتر + +42 +00:03:47,280 --> 00:03:51,440 +تخصيصا وقال أن ال base اللي فيه أزواج إلكترونات + +43 +00:03:51,440 --> 00:03:55,340 +مافيش تناقض ما بين التعريفات لكن فيه نظرة أكتر + +44 +00:03:55,340 --> 00:04:00,790 +تخصيصيةالان عشانك لو حطينا ال ammonia مع الميه + +45 +00:04:00,790 --> 00:04:05,510 +طبعا الميه هنا حاطين ال H3O plus كلكوا عارفين ان + +46 +00:04:05,510 --> 00:04:11,070 +الميه ايش هي أساسا H2O لكن هو اتخيل نسبة التأيون + +47 +00:04:11,070 --> 00:04:17,430 +اللي هي بسيطة جدا اللي درستها في الميه ان H2O زائد + +48 +00:04:17,430 --> 00:04:23,450 +H2O بتفاعل اتزان بطلع نسبة بسيطة جدا من H3O plus + +49 +00:04:23,450 --> 00:04:30,600 +زائد OH minusعشان يك هو لما هنا بيكتب h3o plus + +50 +00:04:30,600 --> 00:04:36,820 +هالنسبة البسيطة جدا اللي اتكونت من يعني تفاعل + +51 +00:04:36,820 --> 00:04:41,950 +الميه مع بعضها، اذا هنا ايش بتفترض انه موجود؟هو H + +52 +00:04:41,950 --> 00:04:46,770 +minus كمان ولذلك لما تيجي الأمونيا من الميه هدم ال + +53 +00:04:46,770 --> 00:04:52,590 +H3O plus تاخد ال H plus تعمل ان H4 plus زاد H2O هو + +54 +00:04:52,590 --> 00:04:57,370 +أساسا في ايون موجب بكل حاله لأ هو الموجب كان معاه + +55 +00:04:57,370 --> 00:05:02,330 +سالب الآن لما صارت الأمونيوم ايون هانا موجب ايش + +56 +00:05:02,330 --> 00:05:07,500 +صار معاه؟سالم و لذلك احنا سنقول ان الامونيا لما + +57 +00:05:07,500 --> 00:05:14,600 +ندوبها في الميه بتعطي امونيوم هيدروكسيد واضح؟ الكل + +58 +00:05:14,600 --> 00:05:19,220 +بيعرف ان احنا بندوب الامونيا في الميه بتعطي ايش؟ + +59 +00:05:19,220 --> 00:05:23,750 +امونيوم هيدروكسيدكذلك الحالة لو دوبنا ال ammonia + +60 +00:05:23,750 --> 00:05:29,390 +مثلا في ال HCl ال ammonia هتاخد H من هنا هصير عندى + +61 +00:05:29,390 --> 00:05:34,510 +ammonium ion مع ال Cl minus ammonium chloride يمكن + +62 +00:05:34,510 --> 00:05:39,130 +هذا ما معاكم في المدرسة انه بإمكاننا احنا نجيب + +63 +00:05:39,130 --> 00:05:44,180 +نقطةمن ال ammonia من محلول ال ammonia نحطها هنا + +64 +00:05:44,180 --> 00:05:49,760 +نقطة من ال HCl نحطه هنا و نسيبهم جانب بعض بتتبخر + +65 +00:05:49,760 --> 00:05:53,860 +.. بتتبخر ال ammonia بتتبخر ال HCl لما يلتجوا مع + +66 +00:05:53,860 --> 00:05:57,620 +بعض ال ammonia مع ال HCl شو هيعملوا؟ ammonium + +67 +00:05:57,620 --> 00:06:02,660 +chloride ال ammonium chloride إيش لونه؟ + +68 +00:06:02,660 --> 00:06:08,310 +تذكروا شغل المدرسة؟أبيض و لذلك كنا نقول أنه ال + +69 +00:06:08,310 --> 00:06:12,810 +ammonia مع ال HCl بيعطوا سحب بيضاء من ال ammonium + +70 +00:06:12,810 --> 00:06:18,820 +chloride بهذا النص مرت عليكم في المدرسة ولا لأ؟سحب + +71 +00:06:18,820 --> 00:06:23,780 +.. سحب بيضاء أو بقعة بيضة هم عادة بيعملوها .. عادة + +72 +00:06:23,780 --> 00:06:28,660 +بيعملوا هذه الشغلة كتجربة .. كتجربة بيجيبوا انبوبة + +73 +00:06:28,660 --> 00:06:32,500 +بهذا الشكل بيجيبوا انبوبة زجاجية مفتوحة الطرفين + +74 +00:06:32,500 --> 00:06:38,270 +بهذا الشكل بيحطوا هنا نقطة أمونياو بيحطوا هان طبعا + +75 +00:06:38,270 --> 00:06:41,090 +أمونيا البعض هيقوللي غاز أمونيا مدور باب ميه + +76 +00:06:41,090 --> 00:06:44,970 +أمونيا ميكروفسيت بيطلع أمونيا واضح؟ و بيحطوا هنا + +77 +00:06:44,970 --> 00:06:49,430 +HCl الآن بيمشوا بتبخر الغازين هذا بتبخر و هذا + +78 +00:06:49,430 --> 00:06:53,570 +بتبخر و سرعته بتعتمد على ال molecular weight تبعه + +79 +00:06:53,570 --> 00:06:58,050 +اللي ال molecular weight تبعه الجيل بيمشي إيش بطيء + +80 +00:06:58,050 --> 00:07:00,890 +فهذا بيمشي له شوية هنا هذا بيمشي له شوية هنا لما + +81 +00:07:00,890 --> 00:07:05,280 +بيلتقواإيش بدهم يعملوه اموريو ميكلورايت فجأة + +82 +00:07:05,280 --> 00:07:09,640 +بيصيروا الناس يشوفوا هنا إيش ابخرة بيضاء واضح + +83 +00:07:09,640 --> 00:07:15,310 +بيصيروا يشوفوا ابخرة بيضاء هذه الأبخرة هيالأمونيوم + +84 +00:07:15,310 --> 00:07:19,250 +كلورايت لو انتوا بتاخدوا معمل general chemistry + +85 +00:07:19,250 --> 00:07:22,410 +بتكون تجربة بتعملواها بتجيبوا الأنبوبة و بتحطوهم + +86 +00:07:22,410 --> 00:07:27,450 +بتشوفوا بعينكم و عشان دائما بنقول التعليم الجامعي + +87 +00:07:27,450 --> 00:07:32,150 +لا يجب أن ينفصل بحال من الأحوال اللي عاملة عن + +88 +00:07:32,150 --> 00:07:36,290 +الجزء النظري في أي خطة تدريسية + +89 +00:07:40,010 --> 00:07:45,710 +طالما قلنا ان ال amines are bases معناه ذلك زي ما + +90 +00:07:45,710 --> 00:07:50,130 +ال acids كنا نقول عنهم acids ويلهم BKA ال amines + +91 +00:07:50,130 --> 00:07:57,350 +بيكونيلهم BKB واضح؟ BKB وقلنا كل ما كانت في ال + +92 +00:07:57,350 --> 00:08:02,150 +acids ال BKA أقل كل ما كان الحامض أقوى الآن في ال + +93 +00:08:02,150 --> 00:08:07,530 +bases بنقول كل ما ال BKB بتكون أقل كل ما القاعدة + +94 +00:08:07,530 --> 00:08:12,460 +أيضا بتكون أقوى واضح؟الجدول اللى موجود عندنا حقيقة + +95 +00:08:12,460 --> 00:08:22,240 +مش كاتبنا ال BKB كاتب ال BKA ل ال conjugate acid + +96 +00:08:22,240 --> 00:08:26,700 +conjugate acid يعني الحمض المرافق عادة بين ال acid + +97 +00:08:26,700 --> 00:08:32,620 +و ال base المرافقة بيكون الفرق إيش؟هيدروجين يعني + +98 +00:08:32,620 --> 00:08:38,560 +انا لما بدي اقول nh4 plus هذا الاسل ال base + +99 +00:08:38,560 --> 00:08:45,500 +المرافقة nh3 و هكذا بناء على ذلك هدولة اللي بيكي + +100 +00:08:45,500 --> 00:08:53,100 +ايه و بيكي بيه كلنا عارفين ان بيكي ايهزائد ال BKB + +101 +00:08:53,100 --> 00:08:59,420 +بساوي 14 بناء على ذلك لو احنا كنا لهذه المجموعة من + +102 +00:08:59,420 --> 00:09:07,300 +ال Amines بدنا نشوف ال BKB بدنا نطرح من 14 يعني + +103 +00:09:07,300 --> 00:09:13,900 +مثلا لل Ammonia ال BKB أربعة و سبعة للميث الأمين + +104 +00:09:15,270 --> 00:09:21,390 +تلاتة و أربعة بالعشرة نفترض للضايف مثل أميل تلاتة + +105 +00:09:21,390 --> 00:09:25,870 +و تلاتة بالعشرة لو أجينا مقارنة مثلا مع الأنليل + +106 +00:09:25,870 --> 00:09:34,290 +حوالي تسعة و أربعة بالعشرةالان لو اجينا للان مثل + +107 +00:09:34,290 --> 00:09:40,410 +الأللين ايضا حوالي تسعة و اتنين بالعشرة الان + +108 +00:09:40,410 --> 00:09:46,010 +لاحظوا ع طول ملاحظة الأمينز اللي في الأول مثل أمين + +109 +00:09:46,010 --> 00:09:51,890 +ضاي مثل أمين و لحد الأللين هنا صار عندى تغير كتير + +110 +00:09:51,890 --> 00:09:57,550 +يعني لحد هدولة كلهمكانت ال بي كي بي قليلة تلاتة + +111 +00:09:57,550 --> 00:10:03,130 +تلاتة أربعة لما صرت فيه الانليل و التوابع صرت تسعة + +112 +00:10:03,130 --> 00:10:09,030 +الان هدول ايش بيفرقوا عن بعض لحد هذا الخط هدول + +113 +00:10:09,030 --> 00:10:14,510 +اللي فوق aliphatic amines اللي تحت aromatic amines + +114 +00:10:14,510 --> 00:10:22,190 +واضح؟ اذا هذه منطقاتالالفاتك أمين هذي منطقة ال + +115 +00:10:22,190 --> 00:10:27,870 +aromatic amines لو إجينا سألنا مين بيكونوا ك basis + +116 +00:10:27,870 --> 00:10:33,430 +أقوى الالفاتك أمين ولا ال aromatic amines؟ + +117 +00:10:33,430 --> 00:10:40,000 +الالفاتك أمينليش؟ لأنه كل ما ال BKB بتكون أقل كل + +118 +00:10:40,000 --> 00:10:45,500 +ما كانت القاعدة أقوى، إذا ال aliphatic amines are + +119 +00:10:45,500 --> 00:10:50,460 +stronger bases than aromatic amines، يعني لما نجيب + +120 +00:10:50,460 --> 00:10:54,740 +ال QA سؤال صح و غلط ال aliphatic amines are فراغ + +121 +00:10:54,740 --> 00:11:00,120 +bases than aromatic amines، they arestronger basis + +122 +00:11:00,120 --> 00:11:05,660 +هذا عرفناها، الآن بعد كمان ممكن نكمل لكم، نقولكم + +123 +00:11:05,660 --> 00:11:14,120 +إيش ال due to بسبب إيش؟ ليش بدنا نحكي غلط؟ بدنا + +124 +00:11:14,120 --> 00:11:19,180 +نحكي غلط؟ ليش ال aliphatic a means + +125 +00:11:22,420 --> 00:11:27,220 +أقوى كقواعد من ال aromatic amines بهمش بدي أعلق + +126 +00:11:27,220 --> 00:11:32,260 +على الخطأ اللي عملته بدي أعلق على الخطأ اللي عملته + +127 +00:11:32,260 --> 00:11:38,140 +عشان ما تكرروهش رجاء انا لما بقول انه بسبب فواحدة + +128 +00:11:38,140 --> 00:11:44,020 +جالتلي ع طول بسبب ال BKB هذا الكلام غير بقبول منكم + +129 +00:11:44,020 --> 00:11:48,400 +انا لما قرأت ال BKB + +130 +00:11:50,390 --> 00:11:54,430 +لقيت هذه جليلة و هذه عالية قولت ال aromatic amines + +131 +00:11:54,430 --> 00:12:00,510 +أقوى من ال aromatic amines زي ما أجي على اتنين بني + +132 +00:12:00,510 --> 00:12:04,830 +أدمين أطفال against طولهم هذا طوله متر و هذا طوله + +133 +00:12:04,830 --> 00:12:10,750 +سبعين الآن اللي طوله متر بقول عنه أطول من اللي + +134 +00:12:10,750 --> 00:12:15,230 +طوله سبعين الان لما أقولكم ليش ماحدش يقوللي أنه + +135 +00:12:15,230 --> 00:12:20,930 +طوله مترthis is nonsense ممكن تقولولي لأنه في + +136 +00:12:20,930 --> 00:12:25,730 +العمر أكبر يمكن يكون هذا السبب هذا بيصير سبب لو + +137 +00:12:25,730 --> 00:12:29,670 +اتنين بنفس العمر ممكن تقولولي وراثيا هذا كل أسر + +138 +00:12:29,670 --> 00:12:33,750 +تطويل هذا أسر .. هيك بيصير سبب بس إن أجيب لقياسه + +139 +00:12:33,750 --> 00:12:38,410 +وأقول عنه سبب بسبب ال BKB لو أنا أساسا استنتجت أن + +140 +00:12:38,410 --> 00:12:43,790 +هذا أقوى من هذا لأن ال BKB هنا أقل من هنا إذا هذا + +141 +00:12:43,790 --> 00:12:44,270 +أقوى + +142 +00:12:47,630 --> 00:12:55,650 +بدي كلام إيش؟ بدي كلام كيمية طبعا معنى بيس إنه + +143 +00:12:55,650 --> 00:12:59,650 +بتعطي إلكترونات إذا للسبب شيء يمنع من إعطاء + +144 +00:12:59,650 --> 00:13:06,400 +الإلكترونات أو يقلل إعطاء الإلكترونات، واضح؟السبب + +145 +00:13:06,400 --> 00:13:10,740 +شيء يمنع أو يقلل من إعطاء الإلكترونات هذا السبب + +146 +00:13:10,740 --> 00:13:14,400 +فعلا ممكن يكون inductive effect و فعلا ممكن يكون + +147 +00:13:14,400 --> 00:13:18,980 +resonance effect في حالة ال aliphatic amines وهي + +148 +00:13:18,980 --> 00:13:23,820 +بالقاري المركبين بيشيبوا بعض القليلين مثلا ال BKA + +149 +00:13:23,820 --> 00:13:27,740 +تبعت الحامض المرافق له أربعة و ستة يعني ال BKB + +150 +00:13:27,740 --> 00:13:33,980 +تبعته جداشتسعة وأربعة هانا لل .. لل Cyclohex + +151 +00:13:33,980 --> 00:13:39,400 +الأمين، هذا ألفتك، مافي double bonds، Cyclic + +152 +00:13:39,400 --> 00:13:43,700 +alkanes are ألفتك، هذا كدهش؟ أربعة واتنين، مين + +153 +00:13:43,700 --> 00:13:48,730 +كباس أقوى؟ ال Cyclohex الأمين ولا الألليين؟الـ + +154 +00:13:48,730 --> 00:13:53,770 +Cyclohexane الأمين أقوى الآن السبب أن هذا زوج + +155 +00:13:53,770 --> 00:13:58,830 +الإلكترونات بدل ما يكون جاهز يطلع برا و يتفاعل برا + +156 +00:13:58,830 --> 00:14:04,310 +قاعد بيعمل resonance جوا الجزء هذا زوج الإلكترونات + +157 +00:14:04,310 --> 00:14:09,660 +بيطلع للخارججاهز إنه يُعطى للخارج و ال base هي + +158 +00:14:09,660 --> 00:14:15,220 +اللي بتعطي إيش إلكترونات فهذا بدل ما يروح للخارج و + +159 +00:14:15,220 --> 00:14:20,640 +يظهر قوة المركب ك base قاعد بيجي بلوف هنا و بيعمل + +160 +00:14:20,640 --> 00:14:24,360 +resonance .. resonance تاني بيصير مرة minus على ال + +161 +00:14:24,360 --> 00:14:26,420 +carbon مرة على ال carbon التاني مرة على ال carbon + +162 +00:14:26,420 --> 00:14:32,020 +التالتة إذا هو قاعد المجهود تبع وين؟ جوا الجزء + +163 +00:14:32,020 --> 00:14:37,990 +فبالنسبة للخارجهو لا يعطي إلكترونات هو قاعد بيعمل + +164 +00:14:37,990 --> 00:14:41,990 +resonance جوا الجزئ فما بيعطي إلكترونات للخارج ال + +165 +00:14:41,990 --> 00:14:46,870 +basic اللي بتعطي إلكترونات لمن؟ للخارج هذا إذا + +166 +00:14:46,870 --> 00:14:51,650 +بيكون سبب .. هذا بيكون سبب اللي هو ليش ال alphatic + +167 +00:14:51,650 --> 00:14:54,850 +amines are more basic than aromatic amines because + +168 +00:14:54,850 --> 00:15:01,710 +of resonance تمام؟ الآن البعض منكم اتكلم كلمة جيدة + +169 +00:15:01,710 --> 00:15:08,080 +قال ال inductive effectممكن يكون في مكان تاني غير + +170 +00:15:08,080 --> 00:15:12,840 +هذا الان حتى نفهم ال inductive effect حتى نفهم ال + +171 +00:15:12,840 --> 00:15:18,200 +inductive effect جيدا انتوا بتكونوا تتخيلوا + +172 +00:15:18,200 --> 00:15:26,720 +نيتروجين و عليها زوج إلكترونات و تلت روابط تمام؟ + +173 +00:15:26,720 --> 00:15:32,040 +إيش اللي ممكن يزيد القاعدية تبعتها و إيش اللي ممكن + +174 +00:15:32,040 --> 00:15:41,510 +ينجس؟أي مجموعة تقدر تقدر تقدر تقدر تقدر تقدر تقدر + +175 +00:15:41,510 --> 00:15:48,750 +تقدر تقدر تقدر + +176 +00:15:48,750 --> 00:15:49,430 +تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر + +177 +00:15:49,430 --> 00:15:49,450 +تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر + +178 +00:15:49,450 --> 00:15:49,570 +تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر + +179 +00:15:49,570 --> 00:15:49,690 +تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر + +180 +00:15:49,690 --> 00:15:49,710 +تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر + +181 +00:15:49,710 --> 00:15:53,850 +تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر + +182 +00:15:53,850 --> 00:16:02,860 +تقدر تقدر تincreases basicity لأنه زدت كمية + +183 +00:16:02,860 --> 00:16:12,420 +الإلكترونات increases او increase basicity الان لو + +184 +00:16:12,420 --> 00:16:18,380 +كان عندى electron with drawing groups with drawing + +185 +00:16:18,380 --> 00:16:24,220 +مجموعات ساحبة للإلكترونات يعني إذا أنا عندى كمية + +186 +00:16:24,220 --> 00:16:28,740 +الإلكترونات إجت أشياء ساحبتهاإيش هيعمله في ال + +187 +00:16:28,740 --> 00:16:37,240 +basicity؟ decrease basicity واضحة الفكرة المجموعات + +188 +00:16:37,240 --> 00:16:41,300 +المعطية للإلكترونات بتزيد كمية الإلكترونات بتزيد + +189 +00:16:41,300 --> 00:16:46,080 +الإعقاء بتزيد القاعدية المجموعات الساحبة تقلل كمية + +190 +00:16:46,080 --> 00:16:50,640 +الإلكترونات تقلل ما يُعطى للخارج وبالتالي تقلل + +191 +00:16:50,640 --> 00:16:55,480 +إيش؟ القاعدية واضحة هذه الفكرة؟ واضحة؟ + +192 +00:17:01,610 --> 00:17:06,190 +طبعا هتلاحظوا القمر هنا عكس ايش ال acidity للناس + +193 +00:17:06,190 --> 00:17:12,530 +اللي بدهم ينتبهوا ويعملوا مقارنة خلينا نعطي مثال + +194 +00:17:12,530 --> 00:17:21,590 +لو اجيت انا اعطيت هدولة المثالين F الأمين لاحظوا + +195 +00:17:21,590 --> 00:17:27,020 +هاي ال F الأمين وين زوج ال electronic اللي عليهعلى + +196 +00:17:27,020 --> 00:17:35,580 +الـ Nitrogen و أعطيت Chloroethelamine هاي + +197 +00:17:35,580 --> 00:17:41,040 +أنا فيه الاتنين Aliphatic واضح بطلت الفكرة + +198 +00:17:41,040 --> 00:17:44,800 +Aliphatic و Aromatic الاتنين إيش مالهم؟ Aliphatic + +199 +00:17:44,800 --> 00:17:50,160 +مين بدو يكون stronger base بالتجربة الـ Ethelamine + +200 +00:17:50,160 --> 00:17:57,430 +أقوى من الchloroethelamine الآن إيش السبب؟اه هنا + +201 +00:17:57,430 --> 00:18:03,010 +في عندى CL، إيش بتعمل ال CL في الإلكترونات؟ بتسحب + +202 +00:18:03,010 --> 00:18:06,810 +الإلكترونات، يعني لو افترضتوا كانت كمية + +203 +00:18:06,810 --> 00:18:10,870 +الإلكترونات كرقم عشوائي، هنا عشرة، ال CL سحبت إلى + +204 +00:18:10,870 --> 00:18:14,190 +منهم اتنين، صف يوجد إيش؟ تمانية، إذا وين + +205 +00:18:14,190 --> 00:18:20,630 +الإلكترونات أكثر؟أه بينما لاحظ لو إجيت أنا حطيت + +206 +00:18:20,630 --> 00:18:24,730 +مثل و مثل بيعطوا إلكترونات شو بده يصير لل BCCT؟ + +207 +00:18:24,730 --> 00:18:31,290 +بده يزيد إذا المجموعات الساحبة تقلل القاعدية + +208 +00:18:31,290 --> 00:18:36,530 +والمجموعات المعطية تزيد القاعدية طبعا بشرط إنكوا + +209 +00:18:36,530 --> 00:18:40,550 +لما تعملوا المقارنات قارنوا أشياء متحدة من جوانب + +210 +00:18:40,550 --> 00:18:44,210 +أخرى يعني أنا لما عملت هذه المقارنة ساحب ومعطي + +211 +00:18:44,210 --> 00:18:49,850 +قارنت ألفتكممكن اكرر العملية اقارن aromatic مع + +212 +00:18:49,850 --> 00:18:56,350 +aromatic يعني لو اخدت الانيلين والنيتروانيلين + +213 +00:18:56,350 --> 00:19:02,830 +والميثلانيلين اللي هو البراتوليدين اسمه الآن هدول + +214 +00:19:02,830 --> 00:19:06,150 +التلاتة فيهم resonance إذا ال resonance مش هيكون + +215 +00:19:06,150 --> 00:19:10,030 +هو السبب وهدول التلاتة القاعدية تبعتهم من ناحية + +216 +00:19:10,030 --> 00:19:12,550 +المبدأ قليلة + +217 +00:19:13,930 --> 00:19:17,630 +ليش؟ لأنه فيهم resonance لكن في القاعدية القليلة + +218 +00:19:17,630 --> 00:19:20,850 +واحد منهم أقل من التاني أقل من التالت يعني التلاتة + +219 +00:19:20,850 --> 00:19:27,310 +ك basis إضعاف لكن في واحد أفضل من التاني أفضل من + +220 +00:19:27,310 --> 00:19:31,970 +التالت الآن خلّينا نيجي نتطلع المثل كمجموعة شو + +221 +00:19:31,970 --> 00:19:37,890 +بتعمل؟ بتعطي إلكترونات إذا معنا الإلكترونات بـ 0 + +222 +00:19:37,890 --> 00:19:44,130 +الـ H نعتبرها متعادلة الـ Nitroبتسحب، إذا وين أعلى + +223 +00:19:44,130 --> 00:19:51,430 +الإلكترونات؟ في الميثلانيلين، بعده الانيلين، بعده + +224 +00:19:51,430 --> 00:19:57,870 +النيترو، فك basis الميثلانيلين أعلى من الانيلين، + +225 +00:19:57,870 --> 00:20:02,350 +أعلى من النيتروانيلين، الآن هنا لما ابدأ أقول شو + +226 +00:20:02,350 --> 00:20:10,330 +السبب؟ ال inductive effectطبعاً بشكل عام كلهم + +227 +00:20:10,330 --> 00:20:17,630 +يعتبروا ضعاف، ليش؟ لأن كلهم فيهم resonance، كلهم + +228 +00:20:17,630 --> 00:20:21,050 +يعتبروا ك basis ضعاف، لكن واحد أضعف من التاني أضعف + +229 +00:20:21,050 --> 00:20:26,610 +من التالت، الأن فرق الضعف اللي بين لضعاف أساساً + +230 +00:20:26,610 --> 00:20:31,670 +بسبب إيش؟ ال inductive effectلكن لو أنا باجي + +231 +00:20:31,670 --> 00:20:38,370 +بسألكم والله بشكل عام ال nitroaniline is a weak + +232 +00:20:38,370 --> 00:20:45,560 +base، ليش؟ هتقولولي ال resonance مصيبة؟و الحاجات + +233 +00:20:45,560 --> 00:20:50,980 +هم صيبة تانية ال nitro يعني صار سبب ضعفه شغل فيه + +234 +00:20:50,980 --> 00:20:55,280 +ال resonance و ال inductive effect لكن لو كنت بدأ + +235 +00:20:55,280 --> 00:20:58,500 +اقارنه مثلا مع ال methyl aniline لأ بقول ما هو ال + +236 +00:20:58,500 --> 00:21:01,720 +resonance و ال resonance هم عامل مشترك بطل هو اللي + +237 +00:21:01,720 --> 00:21:07,920 +مفرج صار إيش اللي مفرج؟ شكل أساسي ال inductive + +238 +00:21:07,920 --> 00:21:09,940 +effect واضحة الفكرة؟ + +239 +00:21:17,860 --> 00:21:23,620 +أخر شغلة في هذا الفصل، لو قلنا تفاعلات الـ Amines، + +240 +00:21:23,620 --> 00:21:28,240 +تفاعلات الـ Amines مروا علينا بدل المر ألف طالما + +241 +00:21:28,240 --> 00:21:33,140 +في زوج إلكترونات، إذا الـ Amines بيعملوا as الـ + +242 +00:21:33,140 --> 00:21:39,880 +Eucleophiles، واضح؟إذا بدكم تحكوا عن الكليهيليتز، + +243 +00:21:39,880 --> 00:21:44,120 +بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن الديهيد + +244 +00:21:44,120 --> 00:21:48,260 +وكيتون، بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن + +245 +00:21:48,260 --> 00:21:52,660 +كاربوكسيليك أسيتس ومشتقاتها، بتفعلوا كنيكليوفييل، + +246 +00:21:52,660 --> 00:21:56,280 +وكل الأمثلة مرت علينا، الآن مع الالكليهيليتز + +247 +00:21:56,280 --> 00:22:00,700 +بيعملوا النيكليوفيليك سبستيوشن، مع الديهيدس وكيتون + +248 +00:22:01,680 --> 00:22:06,140 +بيعملوه الـ Eucleophilic addition مع الـ E stars + +249 +00:22:06,140 --> 00:22:10,340 +ومشتقاتها بيعملوه مرة تانية الـ Eucleophilic + +250 +00:22:10,340 --> 00:22:14,900 +substitution يعني هاي نشوف عدة أمثلة هاي هذا أمين + +251 +00:22:14,900 --> 00:22:20,260 +RNH2 مع أسد الكلورايد هاي الـ Eucleophile هاجم طرد + +252 +00:22:20,260 --> 00:22:24,360 +الـ Cl هذا عبارة عن إيش الـ Eucleophilic + +253 +00:22:24,360 --> 00:22:29,520 +substitution على أسد الكلورايد هذا primary أمين طب + +254 +00:22:29,520 --> 00:22:33,230 +لو secondary أمينبرضه الـ Eucleophilic + +255 +00:22:33,230 --> 00:22:38,230 +Substitution على أسد إكلورايد مافيش فيها إشي لو + +256 +00:22:38,230 --> 00:22:41,710 +شوفناه مُركّب تاني برضه هذا سكندريامين مع أسد + +257 +00:22:41,710 --> 00:22:46,590 +إكلورايد الـ Eucleophilic Substitution لو شوفنا + +258 +00:22:46,590 --> 00:22:51,150 +أنيلين مع أسد أنهيدرايد بده يهاجمها نطوط رد هادي + +259 +00:22:51,150 --> 00:22:55,850 +الـ Eucleophilic Substitution واضح؟ كل هذه + +260 +00:22:55,850 --> 00:22:59,250 +التفاعلات حقيقة سبع + +261 +00:23:00,470 --> 00:23:07,030 +ومرت علينا في أي منطقة لما اتكلمنا على الأحماط + +262 +00:23:07,030 --> 00:23:13,130 +ومشتقاتها ربما البعض يقول طيب ذكرنا بأمثلة على ال + +263 +00:23:13,130 --> 00:23:16,630 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +264 +00:23:16,630 --> 00:23:17,190 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +265 +00:23:17,190 --> 00:23:17,570 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +266 +00:23:17,570 --> 00:23:24,530 +ال ال ال ال ال + +267 +00:23:24,530 --> 00:23:29,470 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +268 +00:23:29,470 --> 00:23:29,490 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +269 +00:23:31,660 --> 00:23:42,460 +CH3 CH2 NH2 هذا primary امين زائد هذا المركب و + +270 +00:23:42,460 --> 00:23:49,980 +حامل هنا ب R هذا يعتبر ايش الكلهيلايت هذا في + +271 +00:23:49,980 --> 00:23:53,520 +النهاية الكلهيلايت و لو حلقة خمسية كيف هتعملوا + +272 +00:23:56,960 --> 00:24:03,400 +واضح؟ وطالما الـ nucleophile neutral كمحص لإيش + +273 +00:24:03,400 --> 00:24:11,020 +هيكون؟ يفقد CH2 CH3 أكيد الـ H اللي فقدها مع ال PR + +274 +00:24:11,020 --> 00:24:17,940 +إيش هتعمل؟ HPR هذا من chapter 6 الـ nucleophilic + +275 +00:24:17,940 --> 00:24:22,820 +substitution ofAlkyl Halides الوثيقة الوثيقة + +276 +00:24:22,820 --> 00:24:27,820 +الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة + +277 +00:24:27,820 --> 00:24:30,180 +الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة + +278 +00:24:30,180 --> 00:24:31,120 +الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة + +279 +00:24:31,120 --> 00:24:31,460 +الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة + +280 +00:24:31,460 --> 00:24:36,880 +الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة + +281 +00:24:36,880 --> 00:24:41,160 +الوثيقة + +282 +00:24:41,160 --> 00:24:45,820 +الوثيقة + +283 +00:24:45,820 --> 00:24:47,480 +الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة + +284 +00:24:47,480 --> 00:24:49,140 +الوثيقة الوثيقة الوثيقة الوثيناخد كمان مرنو + +285 +00:24:49,140 --> 00:24:53,960 +سايكليك كيتون او الديهايد هى C double bond O C + +286 +00:24:53,960 --> 00:25:01,580 +double bond O زائد CH3 CH2 + +287 +00:25:01,580 --> 00:25:08,720 +NH2 تخيلوا اجتكوا اكمل هذه المعادلة كيف هتكملوها؟ + +288 +00:25:08,720 --> 00:25:12,260 +اه بدكم اتهاجموها على ال الديهايد او ال كيتون و + +289 +00:25:12,260 --> 00:25:16,540 +هذه تصير OH اذا للناتج اللى عندى + +290 +00:25:22,140 --> 00:25:30,100 +بدي يصير عندى OH OHANA NH + +291 +00:25:30,100 --> 00:25:39,120 +CH2 CH3 مش هذا اللي بدي يصير لكن الطالب الشاطر + +292 +00:25:39,120 --> 00:25:45,900 +اتعلمت كمان شغلة ان هذا هو تفاعل ل nucleophilic + +293 +00:25:45,900 --> 00:25:46,780 +addition + +294 +00:25:49,140 --> 00:25:54,660 +هذا هو تفاعل الـ Eucleophilic addition الآن مع ال + +295 +00:25:54,660 --> 00:25:58,600 +amines لما تكون ال H و ال OH جانب بعض، ايش + +296 +00:25:58,600 --> 00:26:05,460 +اتعلمنا؟ بيروح و بيفقد جزء ماء و بعمل double bond + +297 +00:26:08,450 --> 00:26:12,470 +قولنا احنا كل N H2 مع C double bond O ماصيرها + +298 +00:26:12,470 --> 00:26:17,130 +النهائي C double bond O الديهيد او كيتون تصير C + +299 +00:26:17,130 --> 00:26:23,790 +double bond N CH2 CH3 بصير ال shift basis وقولنا + +300 +00:26:23,790 --> 00:26:27,590 +ان التفاعل بهذه الحالة ايش بنقول عنه addition + +301 +00:26:27,590 --> 00:26:30,370 +elimination + +302 +00:26:31,670 --> 00:26:35,830 +نسيته تفاعل تكوين الأكزينز والهيدرازونز والسمي + +303 +00:26:35,830 --> 00:26:39,570 +كربازونز كل ال N-H2 مع ال C double bond O + +304 +00:26:39,570 --> 00:26:43,410 +الديهيدوكيتون كانت تعمل C double bond N على خطوتين + +305 +00:26:43,410 --> 00:26:51,100 +لكن في الأساس أن الأمين تفاعل كإيش؟كان uqlu5 وعمل + +306 +00:26:51,100 --> 00:26:54,760 +addition الان بعد هيك ان ال addition اتبع ال + +307 +00:26:54,760 --> 00:26:58,960 +elimination هذا امر ايش تاني هذا المحصلة النهائية + +308 +00:26:58,960 --> 00:27:03,480 +لكن ال addition ادشن و ال uqlu5 ال uqlu5 فال + +309 +00:27:03,480 --> 00:27:09,240 +amines تفاعلهم الأساسي بنقول هو ايش they react as + +310 +00:27:09,240 --> 00:27:14,480 +uqlu5 as uqlu5 واضح؟ + +311 +00:27:16,420 --> 00:27:20,000 +لكن لو جينا سألناكم ال reaction of amines with + +312 +00:27:20,000 --> 00:27:25,120 +aldehydes and ketones is a nucleophilic addition + +313 +00:27:25,120 --> 00:27:30,600 +in a brain cell واضح؟ انه بعدك followed by + +314 +00:27:30,600 --> 00:27:34,700 +elimination على أنه الرأس مرة تبسيط واضح؟ with + +315 +00:27:34,700 --> 00:27:39,920 +acids and their derivatives a nucleophilic + +316 +00:27:39,920 --> 00:27:44,620 +substitution with alkyl halides برضه nucleophilic + +317 +00:27:44,620 --> 00:27:45,840 +substitution + +318 +00:27:56,390 --> 00:28:01,410 +بهيك بنكون خلصنا الفكرة أو الكلام المختصر اللى + +319 +00:28:01,410 --> 00:28:07,510 +بنشرحه عن ال amines و + +320 +00:28:07,510 --> 00:28:11,670 +بنلتقل مباشرة + +321 +00:28:11,670 --> 00:28:15,970 +لفصل + +322 +00:28:15,970 --> 00:28:22,850 +الخامس عشر اللى هو يعتبر بداية ال general + +323 +00:28:22,850 --> 00:28:28,890 +biochemistry اللى بنحكي عنهاlimits and detergents + +324 +00:28:28,890 --> 00:28:37,110 +limits and detergents الان ال limits معناها + +325 +00:28:37,110 --> 00:28:41,190 +بالعربي الدهون اش + +326 +00:28:41,190 --> 00:28:50,630 +اللي تلغيه ال libidab اسمها ال libidab دهون اه في + +327 +00:28:50,630 --> 00:28:55,570 +مشكلة عندكوا في الورق؟أنا عند ال slides خلص و أنت + +328 +00:28:55,570 --> 00:29:07,090 +عندك إشي؟ من وين صورته؟ أي شباته؟ مالغيين + +329 +00:29:07,090 --> 00:29:13,300 +هدولة، مشيولين عن .. مش موجودين في الزمالةلأ لأ + +330 +00:29:13,300 --> 00:29:18,440 +هدولة ال slides اللي معكم زيادة فيهم بس كلمة واحدة + +331 +00:29:18,440 --> 00:29:22,940 +احنا شرحناها كتابة how to prepare phenol هي اللي + +332 +00:29:22,940 --> 00:29:27,740 +كنا مهتمين فيها متذاكرين المرة الماضية قولنالكم + +333 +00:29:27,740 --> 00:29:32,240 +كيف تحضروا ال phenol فقط لحد هنا وبنخلص مافيش اندي + +334 +00:29:32,240 --> 00:29:37,420 +انا عن ال computer الان ننتقل للفصل الخامس عشر + +335 +00:29:37,420 --> 00:29:42,280 +limits and detergentsالـ Libids الدهون الـ + +336 +00:29:42,280 --> 00:29:48,420 +detergents المنظفات الصناعية المنظفات الصناعية + +337 +00:29:48,420 --> 00:29:51,400 +الصوابين و الأشياء اللي بتكون في الشنب و غيرها و + +338 +00:29:51,400 --> 00:29:57,520 +غيراتها و هتلاحظوا انه في علاقة بين الدهون و بينال + +339 +00:29:57,520 --> 00:30:03,160 +detergents و ربما كلكم اتذكرين اساسا ان الصابون + +340 +00:30:03,160 --> 00:30:08,220 +عادة من وين كانوا بيجيبوها؟ من زيت الزتون .. زيت + +341 +00:30:08,220 --> 00:30:14,650 +الزتون، دهون والصابونمنظف طبعا soap الآن صاروا + +342 +00:30:14,650 --> 00:30:19,070 +يعملوا أشياء صناعية بنسميها synthetic detergents + +343 +00:30:19,070 --> 00:30:23,590 +يعني منظفات صناعية كل هذا الكلام هيكون جزء من + +344 +00:30:23,590 --> 00:30:30,270 +الكلام اللي هنناقشه في هذا الشركة الآن لو إجينا و + +345 +00:30:30,270 --> 00:30:38,380 +قولنا إيش هم ال livids إيش هم الدهونلاحظوا أنه + +346 +00:30:38,380 --> 00:30:42,140 +الأن بنبدأ شوية نختلف عن ال organic chemistry يعني + +347 +00:30:42,140 --> 00:30:45,760 +في ال organic chemistry كل chapter لما كنا نجيب + +348 +00:30:45,760 --> 00:30:50,080 +عائلة كنا نميز العائلة بالمجموعة الوظيفية اللي + +349 +00:30:50,080 --> 00:30:54,780 +موجودة فيها يعني نقول ال alcohols OH ال aldehydes + +350 +00:30:54,780 --> 00:31:00,490 +يضا بالبنض OC double bond O of R of R الاسد C + +351 +00:31:00,490 --> 00:31:04,830 +double bond O O H هناك كان التصنيف اعتمادا على ايش + +352 +00:31:04,830 --> 00:31:11,010 +المجموعة الوظيفية الان لما باجي بقول ال libids هل + +353 +00:31:11,010 --> 00:31:16,790 +يا ترى ال libids كعائلة تحكمها مجموعة وظيفية واحدة + +354 +00:31:16,790 --> 00:31:19,870 +يعني في الآخر الواحدة تيجي تقولي C double bond + +355 +00:31:19,870 --> 00:31:26,780 +ONH4 C double bond OSHهل تصنيف ال limits منطلق من + +356 +00:31:26,780 --> 00:31:29,980 +ال functional groups من المجموعات الوظيفية + +357 +00:31:29,980 --> 00:31:35,710 +الجوانب؟الـ Libids هي عائلة من المنتجات الطبيعية + +358 +00:31:35,710 --> 00:31:41,070 +بشكل عام Natural Products عائلة كبيرة جدا و ينضوي + +359 +00:31:41,070 --> 00:31:47,030 +تحتها تفرعات كتيرة هدولة بيمتازوا بشكل عام .. + +360 +00:31:47,030 --> 00:31:51,490 +بيمتازوا بشكل عام المراكبات المنتجة طبيعيا انه + +361 +00:31:51,490 --> 00:31:56,230 +بتدوب في ال organic solvents زي ال ether, + +362 +00:31:56,450 --> 00:32:00,330 +chloroform, أسيتون, بنزين وبشكل عام بدوبوش في + +363 +00:32:00,330 --> 00:32:05,710 +الميهإذا هنا اللي ميزهم كعائلة إن هما منتجات + +364 +00:32:05,710 --> 00:32:12,190 +طبيعية وشغل تانية soluble in organic solvents يعني + +365 +00:32:12,190 --> 00:32:19,870 +أنا بدي إن they are natural و soluble in non-polar + +366 +00:32:19,870 --> 00:32:24,370 +organic solvents insoluble in water + +367 +00:32:27,950 --> 00:32:31,530 +اللي أنا بدياهم عن ال limits they are natural + +368 +00:32:31,530 --> 00:32:37,510 +compounds soluble in non-polar organic solvents + +369 +00:32:37,510 --> 00:32:43,050 +insoluble in water طبعا طالما كانوا soluble in non + +370 +00:32:43,050 --> 00:32:46,090 +-polar organic solvents إذا انتوا هتستنتجوا ان هم + +371 +00:32:46,090 --> 00:32:51,790 +non-polar ليش؟ لأنه likelike واضح إذا هما non + +372 +00:32:51,790 --> 00:32:55,910 +polar و بدوبوا فيه ال non polar solvents الانب + +373 +00:32:55,910 --> 00:33:00,370 +يندرج تحتهم الحقيقة مجموعة كبيرة من المراكبات منهم + +374 +00:33:00,370 --> 00:33:05,090 +اللي بنسميه ال fatty acids الأحماض الدهنية بنشوف + +375 +00:33:05,090 --> 00:33:08,510 +شو هي ال fatty acids منهم ال soaps and detergents + +376 +00:33:08,510 --> 00:33:13,370 +الصوابين و المنظفات منهم ال fats and oils الدهون و + +377 +00:33:13,370 --> 00:33:18,770 +الزيون منهم ال waxes الشموةمنهم الـ Phospholipids + +378 +00:33:18,770 --> 00:33:23,330 +بنسميها Phospholipids منهم الـ Icosanoids مركبات + +379 +00:33:23,330 --> 00:33:28,590 +انكونا من عشرين ذرة كربون منهم Terbenes مجموعة + +380 +00:33:28,590 --> 00:33:34,590 +مركبات بتحده بصفة معينة بنشوفها وجود isoprene unit + +381 +00:33:34,590 --> 00:33:40,400 +منهم الستيرويد مركبات ممتازة وجود أربع حلقاتمنهم + +382 +00:33:40,400 --> 00:33:45,620 +بعض ال vitamins أشياء منوعة مافيش خاسم مشترك بينها + +383 +00:33:45,620 --> 00:33:50,980 +كل هدولة من ناحية المبدأ natural productsSoluble + +384 +00:33:50,980 --> 00:33:54,940 +in organic solvents and soluble in water are + +385 +00:33:54,940 --> 00:33:57,580 +classified as lipids + +386 +00:34:20,310 --> 00:34:24,990 +يعني التلات أشياء بنفهموا مع بعض، واضح؟ يعني اللي + +387 +00:34:24,990 --> 00:34:28,150 +بده يفهم ال fatty acids، بده يفهم ال fats، اللي + +388 +00:34:28,150 --> 00:34:30,890 +بده يفهم ال fats، بده يفهم ال oils، اللي بده يفهم + +389 +00:34:30,890 --> 00:34:33,110 +ال fats و ال oils، بده يفهم ال soaps و ال + +390 +00:34:33,110 --> 00:34:38,310 +detergents، التلاتة هتلاحظوا أن فيهم إيش؟ قاسم + +391 +00:34:38,310 --> 00:34:45,240 +مشترك، التلاتة هتلاحظوا أن فيهم قاسم مشتركوعشان + +392 +00:34:45,240 --> 00:34:51,440 +هيك خلّينا نبدأ بال fats and oils الآن بشكل عام + +393 +00:34:51,440 --> 00:34:57,640 +الدهون والزيوت أشهر شيء موجودين فيه على شكل اللي + +394 +00:34:57,640 --> 00:35:04,700 +بنسميه triglycerides إيش هما ال triglycerides؟ ال + +395 +00:35:04,700 --> 00:35:13,120 +triglycerides ببساطة عبارة عن إيسترز ل .. ال .. + +396 +00:35:14,640 --> 00:35:20,620 +للجليسارين طبعا كلكم اتذكرين انه احنا ايش اخدنا + +397 +00:35:20,620 --> 00:35:27,380 +الجليسارين سابقا قلنا تلات ذرات كربون تلات ذرات + +398 +00:35:27,380 --> 00:35:34,660 +كربون فيهم OH OH OH عشانك الجليسارول one two three + +399 +00:35:34,660 --> 00:35:41,880 +بروبان الترايول مظبوط ولا لأ one two three بروبان + +400 +00:35:41,880 --> 00:35:48,090 +الترايولهذا ال glycerin في الأساس اتفاعل مع أشياء + +401 +00:35:48,090 --> 00:35:53,850 +بنسميها fatty acids هتيجي تقولون احنا اتعلمنا ال + +402 +00:35:53,850 --> 00:35:58,370 +carboxylic acids اللي صيغتهم العامة C double bond + +403 +00:35:58,370 --> 00:36:04,570 +O OH متصلين في R بنقول ال fatty acids هم نفسهم + +404 +00:36:04,570 --> 00:36:14,080 +ولكن ال R تبعتهم كبيرةيعني بتكون عشر كربونات، + +405 +00:36:14,080 --> 00:36:17,220 +اتنائش، اربعة عاشر، ستة عاشر، تمانة عاشر، اشرين + +406 +00:36:17,220 --> 00:36:22,780 +الآن كلكم اتذكرين انه في ال alcohol و في ال acids + +407 +00:36:22,780 --> 00:36:32,300 +قولنا هذه المركبات التمتاز ان فيها طرف polar و طرف + +408 +00:36:32,300 --> 00:36:39,800 +non polarالـ R في الـ fatty acids الـ non-polar + +409 +00:36:39,800 --> 00:36:46,180 +الكبير، خلّينا نقول من عشرة و فوقوبناء على ذلك + +410 +00:36:46,180 --> 00:36:52,280 +الجزيء بمجمله يغلب عليه الـ non-polar part فبصير + +411 +00:36:52,280 --> 00:36:56,480 +water soluble ولا insoluble؟ بصير non-polar طالما + +412 +00:36:56,480 --> 00:37:01,680 +صار non-polar صار water insoluble بصير دوب في ال + +413 +00:37:01,680 --> 00:37:06,640 +organic solvent إذا هذه الجزيئات اللي فيها القاري + +414 +00:37:06,640 --> 00:37:10,190 +الكبيرة هي اللي بنسميها الـ fatty acidsفال fatty + +415 +00:37:10,190 --> 00:37:17,150 +acids ببساطة هي أحماض كربوكسيلية بسلسلة طويلة + +416 +00:37:17,150 --> 00:37:24,080 +وبناء على ذلك أصبحت هذه الأحماض non polarما بتدوبش + +417 +00:37:24,080 --> 00:37:27,220 +في الميه وعشان هيك بتدوبش في الميه بتدوب في + +418 +00:37:27,220 --> 00:37:33,500 +المراكبات العضوية عشان هيك سمنها مواد ايش؟ دهنية + +419 +00:37:33,500 --> 00:37:38,620 +او احماض دهنية فهما الأحماض الدهنية مجموعتهم + +420 +00:37:38,620 --> 00:37:42,600 +الأساسية زي ال carboxylic acids COOH هما + +421 +00:37:42,600 --> 00:37:49,330 +carboxylic acids اكبرواضح؟ هم ببساطة كربوكسيلك + +422 +00:37:49,330 --> 00:37:55,190 +أسنس كبار، الآن لو أجينا و قولنا كحول زائد حمض، شو + +423 +00:37:55,190 --> 00:38:04,910 +بيعطيني؟ إيستر، لو أخدنا أي كحول زائد حمض، إيستر، + +424 +00:38:04,910 --> 00:38:08,410 +هذا أخدنا التفاعل، الآن هاي كحول في الجليسرين و + +425 +00:38:08,410 --> 00:38:13,690 +هاي حمض، خليهم يتفاعلواهذه الكحولة اتفاعل، ماذا + +426 +00:38:13,690 --> 00:38:21,550 +سيعطينا؟ CH2O C double bond OR هذا Easter ولا لا؟ + +427 +00:38:21,550 --> 00:38:28,430 +و هذا؟ Easter تاني على الكحولة و هذا؟يستار تالت، + +428 +00:38:28,430 --> 00:38:33,570 +إذا كم إيستار عمل لجليسارين؟ لأنه فيه تلاتة أواتشز + +429 +00:38:33,570 --> 00:38:40,410 +عمل تلاتة إيستار الآن هذه المركبات بنسميها احنا + +430 +00:38:40,410 --> 00:38:46,410 +الـ triglycerides الـ tri لأنهم تلاتة، الجليساريدز + +431 +00:38:46,410 --> 00:38:49,150 +لأنهم إيستارز of جليسارين + +432 +00:38:51,280 --> 00:38:55,480 +اعرفنا إذا ليش الـ triglycerides؟ لأنه there are E + +433 +00:38:55,480 --> 00:39:02,700 +stars of glycerin وكم E star؟ هان و هان و هان، إذا + +434 +00:39:02,700 --> 00:39:08,690 +هذه الـ triglycerides هي عبارة عن الفات والـ oilهي + +435 +00:39:08,690 --> 00:39:12,230 +عبارة عن الزيت و الذهن و الزبدة و السمنة و زيت + +436 +00:39:12,230 --> 00:39:16,270 +الزتون و زيت عباد الشمس هو عبارة عن الـ + +437 +00:39:16,270 --> 00:39:19,310 +Triglycerides الميزة الأساسية اللي بتبقى بالكم + +438 +00:39:19,310 --> 00:39:26,230 +متذاكرينها فيه ان القعر هذه طويلة لأن القعر طويلة + +439 +00:39:26,230 --> 00:39:31,030 +كله water soluble ولا insoluble عشان هيك الزيت + +440 +00:39:31,030 --> 00:39:39,160 +الزيرج زيت الزتون بخلط مع الميه لأ واضح ف ..لاحظوا + +441 +00:39:39,160 --> 00:39:43,600 +اللي فهم هذا الكلام، بلاحظ العلاقة ما بين الـ + +442 +00:39:43,600 --> 00:39:46,800 +triglycerides و الـ fatty acids، انه انا لو عملت + +443 +00:39:46,800 --> 00:39:51,200 +هيدروليسيز، لو كسرت الـ triglycerides، سخنتهم + +444 +00:39:51,200 --> 00:39:55,280 +بالسوديوم هيدروكسيد و ضفت عليهم بعدين حامض، عاش + +445 +00:39:55,280 --> 00:40:02,420 +بحصل؟ بحصل على ال glycerin أو ال glycerol و ال + +446 +00:40:02,420 --> 00:40:10,380 +fatty acidsبحصل على ال glycerol و ال fatty acids + +447 +00:40:10,380 --> 00:40:17,060 +واضح الفكرة؟ اذا ال fatty acids هما في الأساس جزء + +448 +00:40:17,060 --> 00:40:22,280 +من ال tri glycerides بالتكسير بحصل على glycerin و + +449 +00:40:22,280 --> 00:40:27,600 +بحصل على fatty acid واضح الفكرة؟ + +450 +00:40:29,710 --> 00:40:34,910 +خلّينا شوية صغيرة نخرج عن السياق خلّينا شوية صغيرة + +451 +00:40:34,910 --> 00:40:41,870 +نخرج عن السياق الان جزء ال الكانز نرجع لل الكانز + +452 +00:40:41,870 --> 00:40:48,790 +مش هذا الجزء الأحمر هو عبارة عن الكانز طيب أول + +453 +00:40:48,790 --> 00:40:54,150 +chapter أخدناه في الكيميا العضوية شو كان؟الكينز، + +454 +00:40:54,150 --> 00:41:02,530 +وإيش أهم تفاعلات ال الكينز اللي احنا أخدناها؟ ان + +455 +00:41:02,530 --> 00:41:08,710 +ال الكينز بنحرقهم في وجود ال oxygen، بيعطونا ثاني + +456 +00:41:08,710 --> 00:41:15,970 +أكسيد الكربون وماء وحرارةطيب هذه المراكبات اللي + +457 +00:41:15,970 --> 00:41:20,090 +قال فيها Alkanes واحدة مين كنتيش تتخيل القاتل انه + +458 +00:41:20,090 --> 00:41:25,970 +حطينا السيرج على النار بدنا نولع السيرج حد بيمنعنا + +459 +00:41:25,970 --> 00:41:36,930 +يعني سيرج زائد Oxygen شو هيعطيني CO2 زائد H2O زائد + +460 +00:41:36,930 --> 00:41:43,730 +Heatمش هذه الـ aliphatic compounds الحمرة بتنحرج + +461 +00:41:43,730 --> 00:41:48,730 +وبتعطيني ثانو أكسيد كربون وميه وحرارة؟ إذا الـ + +462 +00:41:48,730 --> 00:41:53,790 +seerage ممكن ينحرج ويعطيني ثانو أكسيد كربون وميه + +463 +00:41:53,790 --> 00:41:59,530 +وحرارة؟ ولا مش ممكن؟ بتشوفوه بنحرج في الدار و + +464 +00:41:59,530 --> 00:42:04,530 +بتكونوا تنتبهوا لما بتشتغلوا؟ طب كويس الآن لو واحد + +465 +00:42:04,530 --> 00:42:11,060 +مخه مش مريحه أو الحصار مش مريحهوجطعوا البنزين .. + +466 +00:42:11,060 --> 00:42:15,720 +جطعوا السولار عن البلد وإيجى حط في سيارة ال مرسيدس + +467 +00:42:15,720 --> 00:42:18,920 +تبعته اللي بتمشي على السولار ولا في ال bus؟ سيرج + +468 +00:42:18,920 --> 00:42:25,740 +.. سيرج ومشى .. بيمشي ولا لأ؟ بيمشي .. بيمشي .. + +469 +00:42:25,740 --> 00:42:32,920 +بيمشي وعشان هيك في غزة في ظروف الحصار لما عدم + +470 +00:42:32,920 --> 00:42:38,270 +الوقودوكانوا بعض الباصات والسيارات المرسيدس مضطرة + +471 +00:42:38,270 --> 00:42:45,030 +تمشي حطوا searage في السيارة واشتغلت ومشيت صح لكن + +472 +00:42:45,030 --> 00:42:54,350 +كان عندكم مشكلة الشيء انه طلعت رائحة فظيعة جدا و + +473 +00:42:54,350 --> 00:42:58,850 +الناس كانت بتنخنيهمظبوط ولا لأ؟ طب هم الناس + +474 +00:42:58,850 --> 00:43:02,030 +مانخنجوش من ال solar العادى و من البنزين يعنى، + +475 +00:43:02,030 --> 00:43:05,990 +يقولوا تأثيرات سلبية، لكن مابتصلش لإنه الناس + +476 +00:43:05,990 --> 00:43:11,650 +ينخنجوا، إيش اللي صار إذا لما احنا ولّعنا السيرج؟ + +477 +00:43:11,650 --> 00:43:16,210 +اه، اللي صار لما ولّعنا السيرج، إنه السيرج جزءين، + +478 +00:43:16,210 --> 00:43:22,310 +هذا الجزء هو اللي عمل كوقودهذا الجزء التابع لـ + +479 +00:43:22,310 --> 00:43:28,990 +Glycerin راح يعمل مصيبة هذا بالحرق بيعطي مركب تاني + +480 +00:43:28,990 --> 00:43:36,990 +CH ضب البند OH CH ضب البند CH2 بنسميه أكرولين و لا + +481 +00:43:36,990 --> 00:43:42,450 +أكرالدهايد هذا المركب هو اللي ريحته كانت سيئة و + +482 +00:43:42,450 --> 00:43:49,350 +يطلع على الشوارع و غيره و غيراته و خنج الناسواضحة + +483 +00:43:49,350 --> 00:43:55,130 +الفكرة؟ فالغلطة اللى كانت ان الناس لما اجوا يحرقوا + +484 +00:43:55,130 --> 00:44:01,330 +ال series في متورات السيارات حرقوا ايش؟ الجزء اللى + +485 +00:44:01,330 --> 00:44:06,110 +عادة بيعطيه الطاقة والجزء الجيد زائد الجزء ايش؟ + +486 +00:44:06,110 --> 00:44:12,470 +السام والدار فطلعت عندهم حرارة ومشيت السيارة وكل + +487 +00:44:12,470 --> 00:44:16,810 +اشي لكن طلع عندهم كمان هذا المركب انتشر في الجو + +488 +00:44:16,810 --> 00:44:24,620 +خلق الناسواضحة الفكرة؟ طيب الآن لو في ناس بيفكروا + +489 +00:44:24,620 --> 00:44:31,940 +جيدا وقالوا يا تورا بدنا نحل المشكلة نطلع وقود من + +490 +00:44:31,940 --> 00:44:40,080 +الزيت ومن السيرج بيقدروا يعمله؟ لو إنهم في الأول + +491 +00:44:40,850 --> 00:44:46,750 +عملوا القاتل فصلوا هدول المركبين عن بعض يعني جابوا + +492 +00:44:46,750 --> 00:44:51,630 +ال searage قبل ما يحطوا كله في ماتور السيارة قبل + +493 +00:44:51,630 --> 00:44:57,410 +ما يحطوا كله في ماتور السيارة كسروا نصين الأن هذا + +494 +00:44:57,410 --> 00:45:04,480 +النصالمفيد هذا ال fuel هذا الوقود وهذا إيش؟ + +495 +00:45:04,480 --> 00:45:08,860 +الجليسيرين الآن أنا لما أكسره بداية قبل ما أحطه في + +496 +00:45:08,860 --> 00:45:13,340 +موتور السيارة الجليسيرين صار على جانب بفصله ولا + +497 +00:45:13,340 --> 00:45:17,600 +مابفصلوش بفصله باخده و باستفيد منه كمان بعمل منه + +498 +00:45:17,600 --> 00:45:21,220 +كريمات مش كل كريمات و شامبوات فيها جليسيرين عشان + +499 +00:45:21,220 --> 00:45:27,850 +نعمة الإيدين يعني أنا مش بس اتخلصت من ضرر حرقهأنا + +500 +00:45:27,850 --> 00:45:32,470 +أخدته واستفادت منه وهذا الجزء عادة بيفصله على شكل + +501 +00:45:32,470 --> 00:45:39,650 +E star أو إثل أو إثل أو إثل واضح؟ + +502 +00:45:39,650 --> 00:45:43,250 +يعني لما يعملوا التكسير بيفصلوا على شكل E star هذا + +503 +00:45:43,250 --> 00:45:50,610 +بناخده كوقود اليوم هذا الوقود اللي أخدنا إيش + +504 +00:45:50,610 --> 00:45:57,770 +بيسموه؟بيو ديزل بيو ديزل إيش يعني بيو ديزل يعني + +505 +00:45:57,770 --> 00:46:03,910 +الديزل الحيو اللي جاي من الزيوت هتقولولي في ديزل + +506 +00:46:03,910 --> 00:46:11,610 +بالطول من الزيت الجواب آه اليوم طائرات وسيارات + +507 +00:46:11,610 --> 00:46:17,370 +طائرات كاملة بتمشي على بيو ديزل بطوله من الزيوت + +508 +00:46:17,960 --> 00:46:23,540 +طبعا هالياطورة احنا ملاقين زيت ناكله سيرج و زيت + +509 +00:46:23,540 --> 00:46:29,620 +ناكله لما نحوله لوخود؟ الجواب اه كيف؟ الزيوت مش بس + +510 +00:46:29,620 --> 00:46:34,760 +كله مأكولة edible مأكول في زيوت inedibleزيوت لا + +511 +00:46:34,760 --> 00:46:40,480 +تؤكل تمام؟ بيزرعوها في أماكن كبيرة في الهند و في + +512 +00:46:40,480 --> 00:46:44,580 +غيرها و في غيراتها مثل مثلا زيت الجاتروفة و زيت + +513 +00:46:44,580 --> 00:46:49,520 +الكامليانة و زيت كذا في زيوت تؤكل و زيوت لا تؤكل + +514 +00:46:49,520 --> 00:46:54,800 +الزيوت اللتي لا تؤكل هي اللي بيحضروا منها المنظفات + +515 +00:46:54,800 --> 00:47:00,740 +و هي اللي بيحولوها لإيش؟ ل bio diesel و أشهرها زيت + +516 +00:47:00,740 --> 00:47:08,350 +اسمه الجاتروفةGatrofa Oil أشرب هذه الزيوت .. زيت + +517 +00:47:08,350 --> 00:47:13,010 +بنسميه إيش؟ زيت الجاتروفا فلاحظوا أنتوا كيف منطق + +518 +00:47:13,010 --> 00:47:17,350 +التفكير و منطق حل المشكلة في العلم أنه أنا فهمت + +519 +00:47:17,350 --> 00:47:22,450 +بداية .. أنه أنا فهمت بداية أن الحرارة بتجيني من + +520 +00:47:22,450 --> 00:47:29,170 +حرق هذا واضح؟الحرارة بتجيني من حرق هذا لكن هذا + +521 +00:47:29,170 --> 00:47:34,090 +موجود مع مركب تاني سام لما فصلته من الصين صار + +522 +00:47:34,090 --> 00:47:37,370 +بإمكاني أخد هذا و أسميه biodiesel و أحرب ولا لأ + +523 +00:47:37,370 --> 00:47:44,590 +الآن ضايقلي عشرين ثانية أحكيهم عارفين شو هم؟ + +524 +00:47:44,590 --> 00:47:52,180 +العشرين ثانية اللي بدنا نحكيهم و نخلصالعشرين ثانية + +525 +00:47:52,180 --> 00:47:56,160 +اللي بنحكيهم و بنخلص القاتل اتخيلوا لو أخدتوا هذا + +526 +00:47:56,160 --> 00:48:03,780 +ال Easter و حطيتوا هنا سلسلة طويلة و حطيتوا هنا + +527 +00:48:03,780 --> 00:48:11,850 +كمان سلسلة طويلة هذه السلاسل ايش بتعمل؟بتولع مع ال + +528 +00:48:11,850 --> 00:48:17,110 +Oxygen و بتعطي حرارة و إضاءة و إشي هذه المركبات ال + +529 +00:48:17,110 --> 00:48:22,090 +E Stars اللي فيها سلسلة طويلة يمين و سلسلة طويلة + +530 +00:48:22,090 --> 00:48:30,910 +الشمال عارفين هي إيش؟ هي الشمع ال wax الآن أنا لما + +531 +00:48:30,910 --> 00:48:37,390 +بولع الشمع حقيقة إيش بولع؟ السلاسل الألفاتية + +532 +00:48:40,000 --> 00:48:45,380 +وبهك بيكون يعرفنا إيش هو الشمع الشمع هو Easter لكن + +533 +00:48:45,380 --> 00:48:50,160 +هذا ال Easter بسلسلتين كبار هانا وإحنا عرفنا إنه + +534 +00:48:50,160 --> 00:48:55,180 +هذه السلاسل لما بتولع هي اللي بتعطينا شوية الحرارة + +535 +00:48:55,180 --> 00:48:57,880 +و ثاني أكسيد الكربون و الميه مش مهمين أهم شيء + +536 +00:48:57,880 --> 00:49:02,720 +الحرارة و الإضاءة واضح؟ فلو قلنا لكم إيش ال wax + +537 +00:49:02,720 --> 00:49:12,010 +بالظبط ال wax areأو الواكس هم أسطارين مع شبكات + +538 +00:49:12,010 --> 00:49:16,370 +طويلة أو شبكات ألفاتية طويلة يعني اللي بيميزهم + +539 +00:49:16,370 --> 00:49:21,530 +الشبكات الطويلة الشبكات الألفاتية وكلنا عارفين + +540 +00:49:21,530 --> 00:49:25,810 +الأن الشبكات الألفاتية إيش بنعمل فيها هي اللي + +541 +00:49:25,810 --> 00:49:30,250 +بنولعها و بتعطينا الطاقة هي اللي بنولعها و بتعطينا + +542 +00:49:30,250 --> 00:49:34,850 +الطاقةفبكون هذا هو إيش الشمال فلاحظوا كيف أنا + +543 +00:49:34,850 --> 00:49:41,570 +استفدت من ال sealage كوقود كيف أنا استفدت كمان من + +544 +00:49:41,570 --> 00:49:46,710 +ال wax أنه أولعه و يطلعلي حرارة من خلال أنه أنا + +545 +00:49:46,710 --> 00:49:50,110 +بستفيد من التفاعل الأصلي اللي أخدته في شبتر واحد + +546 +00:49:50,110 --> 00:49:55,350 +أنه الألكيز بتحض مع ال oxygen و ال combustion + +547 +00:49:55,350 --> 00:49:58,630 +طلعوا ثانو أكسيد كربون و ميه و حرارة + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/rNQZEu2DPCw_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/rNQZEu2DPCw_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..a7f39a6137d4b81fbeb03d9d074c01659c663790 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/rNQZEu2DPCw_postprocess.srt @@ -0,0 +1,2160 @@ +1 +00:00:20,750 --> 00:00:25,750 +بسم الله الرحمن الرحيم بنستغنف اليوم في موضوع ما + +2 +00:00:25,750 --> 00:00:30,570 +ساقنا في الكيميا العضوية و الحيوية اعطينا احنا او + +3 +00:00:30,570 --> 00:00:35,850 +بدأنا في فصل مقدمة ذكر بمبادئ أساسية بتخدمنا في + +4 +00:00:35,850 --> 00:00:41,360 +مجال الكيميا العضويةكان عنوان الفصل اللى احنا + +5 +00:00:41,360 --> 00:00:44,700 +بدأنا فيه bonding and isomerism يعني بدنا نتكلم عن + +6 +00:00:44,700 --> 00:00:47,600 +أنواع الروابط اتكلمنا عنها ionic compounds, + +7 +00:00:47,740 --> 00:00:52,040 +covalent compounds فكرة عن الروابط الأحدية + +8 +00:00:52,040 --> 00:00:57,100 +الثنائية الثلاثية قوة الرابطة طول الرابطة كل هذا + +9 +00:00:57,100 --> 00:01:01,740 +الكلام اتكلمنا عنه ال valency التكافؤ كل عنصر من + +10 +00:01:01,740 --> 00:01:05,800 +العناص الأساسية اللى عندنا كام رابطة بيعمل عادة + +11 +00:01:05,800 --> 00:01:10,740 +لما احنا بدنا نكون جزء عضوىالـ polarity of bonds و + +12 +00:01:10,740 --> 00:01:15,860 +polarity of compounds اتكلمنا ايضا عنها جزء ثاني + +13 +00:01:15,860 --> 00:01:21,480 +المتشكلات لان الكيميا العضوية فكرة اساسية جدا فيها + +14 +00:01:21,480 --> 00:01:26,460 +انه مجموعة قليلة من الذرات لكن بتعمل عدد كبير جدا + +15 +00:01:26,460 --> 00:01:30,820 +من المركبات يعني اليوم نتكلم عن حوالي عشرين مليون + +16 +00:01:30,820 --> 00:01:36,740 +مركب عضوي معروف ومشخصلما نفكر هدول عشرين مليون فقط + +17 +00:01:36,740 --> 00:01:41,680 +من الكاربون الهيدروجين النيتروجين الاكسوجين معنى + +18 +00:01:41,680 --> 00:01:47,100 +ذلك ان هدول نتجوا نتيجة التشكل هل الكاربون اجت في + +19 +00:01:47,100 --> 00:01:50,300 +الاول الاكسوجين في الاول الكلور اجت على الموقع + +20 +00:01:50,300 --> 00:01:53,140 +واحد على الموقع اتنين على الموقع تلاتة بتصير أشكال + +21 +00:01:53,140 --> 00:01:57,820 +مختلفة بيصير عندنا ظاهرة ال isomers طبعا ال + +22 +00:01:57,820 --> 00:02:02,080 +isomers قلنا في منها نوع سهلهو الـ Structural + +23 +00:02:02,080 --> 00:02:06,000 +Isomers اللي الذرات بتختلف في ارتباطها والجزيات + +24 +00:02:06,000 --> 00:02:10,700 +بتختلف في تسميتها وفي نوع تاني بنفرضله فاصل كامل + +25 +00:02:10,700 --> 00:02:16,780 +أثناء شرحنا الـ Stereoisomersكذلك كيف نكتب الصياغ + +26 +00:02:16,780 --> 00:02:21,020 +في الكيميا العضوية اتكلمنا عنه وقولنا انه احنا في + +27 +00:02:21,020 --> 00:02:25,520 +الكيميا العضوية صح بإمكاننا نكتب الصياغ مفصلة + +28 +00:02:25,520 --> 00:02:29,160 +بأعداد الروابط اللي اتفقنا عليها اللي هي لل carbon + +29 +00:02:29,160 --> 00:02:32,480 +أربع روابط ال nitrogen تلاتة ال oxygen اتنين ال + +30 +00:02:32,480 --> 00:02:37,540 +hydrogen وال halogens واحد لكن بإمكاننا نكتب صياغ + +31 +00:02:37,540 --> 00:02:42,720 +مختصرة جدامثل الصياغ اللى أمامكم وناقشناها في + +32 +00:02:42,720 --> 00:02:49,640 +المرة الماضية وكل رأس اذا لم يكتب عليه شيء ويجب ان + +33 +00:02:49,640 --> 00:02:55,350 +يكمل الى اربع روابط في المجملالان بنجي لنقطة + +34 +00:02:55,350 --> 00:02:59,990 +إضافية بتلزمنا أثناء شرحنا في الكيميا العضوية و + +35 +00:02:59,990 --> 00:03:02,850 +يفترض أن الناس بيتعلموها أيضا في ال general + +36 +00:03:02,850 --> 00:03:07,110 +chemistry اللي هي ال formal charges أو أحيانا + +37 +00:03:07,110 --> 00:03:12,700 +بترجموها الشحنات ربما الظاهريةالـ formal charges + +38 +00:03:12,700 --> 00:03:18,080 +لو احنا رسمنا جزيء حتى لو كان هذا الجزيء covalent + +39 +00:03:18,080 --> 00:03:21,900 +او molecular molecule يعني الروابط اللي فيها + +40 +00:03:21,900 --> 00:03:27,540 +covalent bonds وجزيء متعادل بيقول على الذرات اللي + +41 +00:03:27,540 --> 00:03:32,900 +موجودة في داخل هذا الجزيء يوجد شحنات بنسميها ايش + +42 +00:03:32,900 --> 00:03:39,480 +احنا ال formal charges الان يفترض انه الجزيء ككل + +43 +00:03:40,150 --> 00:03:44,310 +يكون عليه شحنة لو كان متعادل معنى ذلك مجموعة + +44 +00:03:44,310 --> 00:03:48,190 +الشحنات هذه كلها بساوي سفر يعني لو انا مثلا بدأ + +45 +00:03:48,190 --> 00:03:52,090 +احكي عن جزيء زي ال carbon tetrachloride يعني + +46 +00:03:52,090 --> 00:03:56,970 +carbon و 4 ذرات كلور المفروض انه كل ذرة من هذه + +47 +00:03:56,970 --> 00:04:02,070 +الذرات عليها شحنة انا بسميها formal charge الان + +48 +00:04:02,070 --> 00:04:08,130 +الجزء بالمجملبكون مجموعة الشحنات يعني لو أنا قلت + +49 +00:04:08,130 --> 00:04:14,270 +CCl4 ذرة كربون وأربع ذرات كلور انبين هنا أي شحنة؟ + +50 +00:04:14,270 --> 00:04:18,810 +لأ، إذا المفروض يكون عندي شحنات على الكربون شحنات + +51 +00:04:18,810 --> 00:04:24,230 +على الكلور ومجموعة هذه الشحنات يساوي إيش؟ سفر لكن + +52 +00:04:24,230 --> 00:04:30,570 +لو مثلا أنا حكيت عن ايون زي ما أحكي مثلا CO3 minus + +53 +00:04:30,570 --> 00:04:32,290 +minus ايون الكربونين + +54 +00:04:36,100 --> 00:04:40,680 +الشحنات المفروضة على الكربون والأكسجين شحنات + +55 +00:04:40,680 --> 00:04:44,260 +ومجموعة من هذه الشحنات يسوى ما يعني؟ مايعني مايعني + +56 +00:04:44,260 --> 00:04:44,980 +مايعني مايعني مايعني مايعني مايعني مايعني مايعني + +57 +00:04:44,980 --> 00:04:46,580 +مايعني مايعني مايعني مايعني مايعني مايعني مايعني + +58 +00:04:46,580 --> 00:04:47,380 +مايعني مايعني مايعني مايعني مايعني مايعني مايعني + +59 +00:04:47,380 --> 00:04:47,460 +مايعني مايعني مايعني مايعني مايعني مايعني مايعني + +60 +00:04:47,460 --> 00:04:47,720 +مايعني مايعني مايعني مايعني مايعني مايعني مايعني + +61 +00:04:47,720 --> 00:04:47,760 +مايعني مايعني مايعني مايعني مايعني مايعني مايعني + +62 +00:04:47,760 --> 00:04:53,390 +مايعني مايعنيبالنسبة لأ الشحنة اللي بتكون هنا هي + +63 +00:04:53,390 --> 00:04:57,650 +مجموع ال formal charges واضح يعني لما واحدة بتعمل + +64 +00:04:57,650 --> 00:05:01,270 +حسابة تقول احسب جداش فيه charge على الكاربون جداش + +65 +00:05:01,270 --> 00:05:04,730 +فيه على الأكسجين عملت جمعة ايه سوى شحنة لها جزء + +66 +00:05:04,730 --> 00:05:10,630 +متعادل هصير مجموعهمجزء مشحون مجموعهم الشحناء اللي + +67 +00:05:10,630 --> 00:05:15,270 +موجودة هنا الان كيف احنا بنحسب ال formality charge + +68 +00:05:15,270 --> 00:05:19,430 +ال formality charge بتساوي ال valence electrons + +69 +00:05:19,430 --> 00:05:23,160 +اللي هي الإلكترونات في المداري الأخيرممكن البعض + +70 +00:05:23,160 --> 00:05:27,460 +يقول طب و أنا بدأ أعمل توزيع إلكتروني عشان أعرف ال + +71 +00:05:27,460 --> 00:05:32,260 +Valence Electrons؟ بنقول لأ، بده يتذكر الإنسان إن + +72 +00:05:32,260 --> 00:05:36,960 +ال Valence Electrons بيساوي رقم المجموعة في الجدول + +73 +00:05:36,960 --> 00:05:42,120 +الدوري طبعا هيجي تساؤل تاني عندكم، هل يا ترى بدنا + +74 +00:05:42,120 --> 00:05:49,040 +نكون حافظين الجدول الدوري؟الجواب في منطقة معينة اه + +75 +00:05:49,040 --> 00:05:52,960 +بدنا نكون حافظين الجدول الدوري يعني يوم اتي احكي + +76 +00:05:52,960 --> 00:05:57,220 +مثلا على الهيدروجين بدنا نكون عارفين تماما ان + +77 +00:05:57,220 --> 00:06:02,380 +الهيدروجين في المجموعة الاولى يوم بحكي عن الذرات + +78 +00:06:02,380 --> 00:06:05,480 +الأساسية عندى في ال organ الchemistry اللى هى + +79 +00:06:05,480 --> 00:06:09,120 +تحديدا ال carbon بعد ال nitrogen ال oxygen ال + +80 +00:06:09,120 --> 00:06:14,110 +floorو تحت ال floor بيجوني ال halogens ال chlorine + +81 +00:06:14,110 --> 00:06:18,710 +البروم ال يولي تحت ال oxygen ال sulfur تقريبا هذه + +82 +00:06:18,710 --> 00:06:22,470 +هي ذرات الكيميا العضوية اللى بتمر عليها اكثر ما + +83 +00:06:22,470 --> 00:06:27,250 +يمكن الان بدي اكون عارف تماما ان ال carbon في + +84 +00:06:27,250 --> 00:06:29,930 +المجموعة الرابعة ال nitrogen في الخامسة ال oxygen + +85 +00:06:29,930 --> 00:06:33,790 +في السادسة ال floor في السابعةإذا الـ valence + +86 +00:06:33,790 --> 00:06:36,890 +electrons أو الإلكترونات الخارجية لأي ذرّة من + +87 +00:06:36,890 --> 00:06:42,370 +هدول، كم لمتهم؟ للأكسجون والسلفر، للنيتروجين، + +88 +00:06:42,370 --> 00:06:47,910 +خمسة، للكاربون، أربعة، واضح؟ هذا شيء يجب أن نعرفه + +89 +00:06:48,730 --> 00:06:51,570 +الأن الـ Formal Charge بتساوي الـ Valence + +90 +00:06:51,570 --> 00:06:56,690 +Electrons ناقص عدد الروابط اللي على الذرة المعينة + +91 +00:06:56,690 --> 00:07:01,990 +اللي أنا بحسبها ناقص أي عدد من الإلكترونات و غالبا + +92 +00:07:01,990 --> 00:07:05,790 +أزواج الإلكترونات موجودة على هذه الذرة مثلا لو + +93 +00:07:05,790 --> 00:07:10,290 +نظرت أنا لإيون الكربونات لو نظرت لإيون الكربونات + +94 +00:07:10,290 --> 00:07:13,850 +اعملتله Lewis Structure هذا الـ Lewis Structure + +95 +00:07:13,850 --> 00:07:19,490 +تبعه تماماالان لو جيت باسأل طب هذه ال carbon كام + +96 +00:07:19,490 --> 00:07:23,830 +شحنة عليها formal charge هقول ال valence electrons + +97 +00:07:23,830 --> 00:07:30,250 +بتاعونها أربعة ناقص الروابط اللي عاملهم أربعة ناقص + +98 +00:07:30,250 --> 00:07:35,230 +هل يظهر عليها أزواج إلكترونات لأ إذا ال formal + +99 +00:07:35,230 --> 00:07:41,850 +charge على هذه ال carbon سفر طب لو جيت لل oxygen + +100 +00:07:41,850 --> 00:07:49,310 +اللي جنبهاهأقول ال oxygen ستة ناقص كام رابطة ناقص + +101 +00:07:49,310 --> 00:07:55,370 +رابطتين ناقص كام إلكترون أربعة ستة ناقص اتنين ناقص + +102 +00:07:55,370 --> 00:08:01,440 +أربعةأيضا صفر طب لو جيت على ال oxygen هذي و هذي + +103 +00:08:01,440 --> 00:08:06,180 +زيها ست إلكترونات ال feelings electrons ناقص كام + +104 +00:08:06,180 --> 00:08:11,820 +رابطة واحد ناقص كام إلكترون نين أربعة ستة إذا هذي + +105 +00:08:11,820 --> 00:08:17,320 +minus one و هذي زيها minus one الآن هذي أربع ذرات + +106 +00:08:17,320 --> 00:08:21,270 +مكونين لهذا الايون كل واحدة لها شحنةالى formal + +107 +00:08:21,270 --> 00:08:26,470 +charge طب مجموع هذه الشحنات جديش minus اتنين احنا + +108 +00:08:26,470 --> 00:08:32,330 +طبعا عارفين ان ال CO3 two minus ايش فادتني ال + +109 +00:08:32,330 --> 00:08:36,430 +formal charge ايش فادتني ال formal charge فادتني + +110 +00:08:36,430 --> 00:08:42,390 +ان انا بقول هذا الايون المكون من اربع ذرات عليه + +111 +00:08:42,390 --> 00:08:46,950 +شحنتين سالبات طب لو سألنا السؤال where بالظبط + +112 +00:08:46,950 --> 00:08:52,560 +الشحنتين السالبات هدول اربع ذراتالـ CO3 أربع ذرات + +113 +00:08:53,330 --> 00:08:57,110 +شحنته العامة minus minus طب وين موجودين هدول + +114 +00:08:57,110 --> 00:09:01,850 +الشحنتين السالبات الان هذا الحساب اعطاني فكرة + +115 +00:09:01,850 --> 00:09:07,890 +موجودين على هذا ال oxygen و على هذا ال oxygen لو + +116 +00:09:07,890 --> 00:09:12,350 +الان انا بدي اجي اعمل تفاعل معين اجيب شيء موجب + +117 +00:09:12,350 --> 00:09:17,130 +يتفاعل وين بده يجي الموجب؟ تحديدا على هذه و هذه + +118 +00:09:17,130 --> 00:09:24,440 +يعني مثلا لو هذا ال ion بدي اجي افعله مع H plusوين + +119 +00:09:24,440 --> 00:09:28,120 +بدو ييجي ال H plus؟ الموجب بدو ييجي على السالب + +120 +00:09:28,120 --> 00:09:32,320 +عشان هيك الشكل اللي هيطلع عندك C ضب البند O، O + +121 +00:09:32,320 --> 00:09:37,940 +هتتفعل مع H، O هتتفعل مع H، هى الموجب اتفعل مع + +122 +00:09:37,940 --> 00:09:44,520 +السالب صار عند المركب H2CO3 اللى هو ال carbonic + +123 +00:09:44,520 --> 00:09:50,230 +acidواضح؟ اللي أنا عارفه، فهذه من فوائد ال formal + +124 +00:09:50,230 --> 00:09:56,090 +it charges إنها بتحدد لبالظبط لو في شحنات وين + +125 +00:09:56,090 --> 00:10:00,190 +موجودين، لو في شحنات بمجمل ال ion وين موجودين، + +126 +00:10:00,190 --> 00:10:07,570 +كذلكلو كان عندى الجزء متعادل يعنى بين شحنته سفر + +127 +00:10:07,570 --> 00:10:13,250 +ايضا كل ذرة فيه بتحمل شحنة يعنى مثلا لو أخدنا هذا + +128 +00:10:13,250 --> 00:10:20,430 +ال carbon tetrachloride CClClClCl + +129 +00:10:20,430 --> 00:10:27,410 +و توزيعه الإلكترونى بهذا الشكل و قلنا بدنا نجرب + +130 +00:10:27,410 --> 00:10:31,720 +نحسبله formal chargeالحالي يجي نقول ال carbon + +131 +00:10:31,720 --> 00:10:38,280 +أربعة ناقص أربع روابط مافيش أزواج إلكترونات إذا + +132 +00:10:38,280 --> 00:10:43,040 +هذه zero لو جيت ال chlorine كلهم يبينوا زي بعض ال + +133 +00:10:43,040 --> 00:10:51,520 +chlorine سبعة ناقص رابطة ناقص ستة + +134 +00:10:55,460 --> 00:11:04,560 +و المجموع تبعه صفر واضح؟ و المجموع تبعه صفر مرات + +135 +00:11:04,560 --> 00:11:09,540 +بيكون في عندكم على بعض الذرات موجب و سالب و + +136 +00:11:09,540 --> 00:11:12,760 +المجموع أيضا صفر يعني ممكن تلاقوا في حالة تانية + +137 +00:11:12,760 --> 00:11:20,610 +plus one و minus one و المجموع صفر الآنطالما عندي + +138 +00:11:20,610 --> 00:11:26,150 +أزواج إلكترونات و روابط بإمكاني أنا أحرك أزواج + +139 +00:11:26,150 --> 00:11:31,110 +الإلكترونات من مكانها و أعمل تغيير في الروابط يعني + +140 +00:11:31,110 --> 00:11:35,350 +مثلا لو إحنا إجينا و قولنا بدنا نحرك هذا زوج + +141 +00:11:35,350 --> 00:11:40,130 +الإلكترونات نجيبه على هذا الموقع بيصير؟ بنقدر + +142 +00:11:40,130 --> 00:11:43,050 +نجيبه لكن يا تورة هل معقول اللي كاربون تصير خمس + +143 +00:11:43,050 --> 00:11:47,370 +روابط؟ لأ وجدت هأ بدأت طار أحرك رابطة ما هي + +144 +00:11:47,370 --> 00:11:53,040 +الرابطة إلكترونيةوهذا إلكترونين وقت بدأ الطر أحرك + +145 +00:11:53,040 --> 00:11:58,240 +هذه الرابطة تيجي على ال oxygen هنا واضح؟ صار عندي + +146 +00:11:58,240 --> 00:12:02,500 +شكل جديد إيش الإختلاف بين الشكل الأول والشكل + +147 +00:12:02,500 --> 00:12:09,180 +التاني؟ تطلع عليهمفقط في مواقع الإلكترونات بمعنى + +148 +00:12:09,180 --> 00:12:13,380 +الذرات Carbon Oxygen Oxygen Oxygen Carbon Oxygen + +149 +00:12:13,380 --> 00:12:18,680 +Oxygen Oxygen لكن الإلكترونات تغير شكلها واضح + +150 +00:12:18,680 --> 00:12:22,940 +بإمكان أعمل كمان تغيير مثلا ممكن أجيب هذا زوج + +151 +00:12:22,940 --> 00:12:27,200 +الإلكترونات هان أخليها دي جهان صار عندي شكل جديد + +152 +00:12:27,200 --> 00:12:31,640 +الآن الشكل الأول التاني التالت شو بسميهم أنا + +153 +00:12:32,080 --> 00:12:36,300 +Resonance structures يعني أشكال رانيل بنقولها + +154 +00:12:36,300 --> 00:12:41,460 +بالعربي فال resonance كفكرة arises whenever we can + +155 +00:12:41,460 --> 00:12:44,320 +write two or more structures for a molecule with + +156 +00:12:44,320 --> 00:12:48,540 +different arrangement of electrons but identical + +157 +00:12:48,540 --> 00:12:52,020 +arrangement of atoms لاحظوا هذا بيجيبلنا مفهوم + +158 +00:12:52,020 --> 00:12:56,940 +كتير مهم عندنا أنه أنا ممكن أغير في الإلكترونات + +159 +00:12:56,940 --> 00:13:01,960 +بدون ما أغير الذراتهذه العملية اللى بغير فيها فقط + +160 +00:13:01,960 --> 00:13:09,300 +إلكترونات arrangement of إلكترون بدون ما أقترب من + +161 +00:13:09,300 --> 00:13:14,840 +الذرات شو بسميها أنا resonance structures الان ال + +162 +00:13:14,840 --> 00:13:18,840 +resonance structures بين شكل و التاني بنستعمل لهم + +163 +00:13:18,840 --> 00:13:23,500 +سهم زى ما انتوا شايفينهDouble Headed Arrow عشان + +164 +00:13:23,500 --> 00:13:29,800 +نقول ان هذا وهذا فقط يختلفوا في طريقة رسمنا + +165 +00:13:29,800 --> 00:13:35,200 +للإلكترونات بين الذرات ولكننا لم نغير في ايش في + +166 +00:13:35,200 --> 00:13:39,580 +مواقع الذرات يمكن مر عليكم هذا الكلام لما أخدت + +167 +00:13:39,580 --> 00:13:44,260 +أشكال البنزين متذكرين لما كنتوا تاخدوا البنزين + +168 +00:13:46,670 --> 00:13:51,890 +بهذا الشكل و كنتوا تقولوا ممكن يكون غيرنا الأشكال + +169 +00:13:51,890 --> 00:13:57,350 +بهذا الشكل الآن هذولا الشكلين تبعون البنزين عبارة + +170 +00:13:57,350 --> 00:14:01,530 +عن ايش resonance structures مرة أنا كان عندي رابطة + +171 +00:14:01,530 --> 00:14:05,130 +يعني إلكترونين مرة أنا رابطة زوجية يعني كأنها أربع + +172 +00:14:05,130 --> 00:14:09,090 +إلكترونات فأنا قاعد فقط بغير إلكترونات لكن هل + +173 +00:14:09,090 --> 00:14:14,070 +تغيرت الذراتولذلك هدول الشكلين بنستعملله ماذا + +174 +00:14:14,070 --> 00:14:21,210 +السهم اللي بعبر عن إيش ال resonance هذا الكلام + +175 +00:14:21,210 --> 00:14:24,710 +هيخلنا + +176 +00:14:24,710 --> 00:14:30,370 +ننتقل لشغلة الحقيقة مهمة في ال organ ال chemistry + +177 +00:14:30,370 --> 00:14:33,890 +انه في ال organ ال chemistry احنا بنستعمل أسهم + +178 +00:14:33,890 --> 00:14:40,860 +كتيركل سهم يستعمل له معنى واضح ويجب أن يعرف الطالب + +179 +00:14:40,860 --> 00:14:46,460 +يعني مش عشوائي ان الواحد يقعد يختار أسهم أو يرسمها + +180 +00:14:46,460 --> 00:14:50,460 +بطريقة معينة لأ الأسهم لها معنى في الكيمياء + +181 +00:14:50,460 --> 00:14:55,860 +العضوية من أهم الأسهم اللي احنا بنستعملها بعض + +182 +00:14:55,860 --> 00:15:01,170 +الأسهم اللي قارب نعطيكم إياها السهم الأولبنسميه + +183 +00:15:01,170 --> 00:15:05,630 +straight arrow يعني سهم بشكل مستقيم هذا السهم + +184 +00:15:05,630 --> 00:15:09,610 +بنستعمله في التعبير عن التفاعل والتفاعل زي ما + +185 +00:15:09,610 --> 00:15:14,930 +انتوا عارفين reactants بيعطوا products متفاعلات + +186 +00:15:14,930 --> 00:15:20,390 +بيعطوا نواتج الان بينهم اي سهم بستعمل ال straight + +187 +00:15:20,390 --> 00:15:24,950 +arrow يعني لو واحدة مثلا اتيت فكرت القمر مجرد ايش + +188 +00:15:24,950 --> 00:15:30,400 +مكان ترسم راحت في المعادلة كتبت زي هيكهل هذا هو + +189 +00:15:30,400 --> 00:15:33,920 +اللي موجود هناك؟ هذا سهم له معنى ثاني في ال + +190 +00:15:33,920 --> 00:15:37,540 +organic chemistry حتى لو ما شرحتش الآن فيجب أن + +191 +00:15:37,540 --> 00:15:42,700 +نلتزم بشكل السهم زي ما هو موجود هنا إذا أنا بأتكلم + +192 +00:15:42,700 --> 00:15:48,740 +عن تفاعل بدي أستعمل أي سهم ل straight arrow بشكل + +193 +00:15:48,740 --> 00:15:52,490 +اللي موجود عندنابعض التفاعلات أخدت هنا equilibrium + +194 +00:15:52,490 --> 00:15:56,990 +reaction يعني موجودين المتفاعلات والنواتج و أجيت + +195 +00:15:56,990 --> 00:16:02,610 +أبدأ أستعمل الأسهم الموجودة عندى اللى بسميها pair + +196 +00:16:02,610 --> 00:16:07,130 +of straight arrows with half heads زوج من الأسهم + +197 +00:16:07,130 --> 00:16:12,730 +المستقيمة بنصف رأس ربما كتير منكم لما كان يعبر عن + +198 +00:16:12,730 --> 00:16:20,280 +الاتزان كان يستعمل زى هى هذا الكلام غلطهذا الكلام + +199 +00:16:20,280 --> 00:16:29,900 +غلط الصح ان هذا بنصف رأس و هذا بنصف رأس هم لاحظين؟ + +200 +00:16:29,900 --> 00:16:34,120 +pair of straight arrows with half heads هذا يعبر + +201 +00:16:34,120 --> 00:16:39,100 +عن ايش؟ تفاعلات الاتزان equilibrium reactions يكون + +202 +00:16:39,100 --> 00:16:42,360 +عندكم ال reactants و ال products عند انتهاء + +203 +00:16:42,360 --> 00:16:48,700 +التفاعلالسهم هذا اسمه double headed straight arrow + +204 +00:16:48,700 --> 00:16:55,200 +سهم له رأسين هذا يستعمل لل resonance الان اتذكروا + +205 +00:16:55,200 --> 00:16:57,540 +معي ال resonance ايش قلنا عنه؟ + +206 +00:17:00,330 --> 00:17:04,270 +Structures with different arrangements of + +207 +00:17:04,270 --> 00:17:09,110 +electrons مرات بنيجي نسأل الطلاب بنقولهم this + +208 +00:17:09,110 --> 00:17:12,690 +arrow or double headed straight arrows are used + +209 +00:17:12,690 --> 00:17:15,670 +for structures with different arrangements of + +210 +00:17:15,670 --> 00:17:20,490 +atoms and electronsلأ different arrangement of + +211 +00:17:20,490 --> 00:17:24,490 +electrons فتكونوا متذكرين ان ال resonance فقط + +212 +00:17:24,490 --> 00:17:28,630 +اختلاف في ترتيب الالكترونات لكن ما بنقترب من + +213 +00:17:28,630 --> 00:17:32,030 +الذرات الذرات زي ما هم يعني اللي قاعد بيشتغل على + +214 +00:17:32,030 --> 00:17:37,050 +برنامج الرسم وحط الذرات في أول مرة زي المثال + +215 +00:17:37,050 --> 00:17:43,290 +السابق بيعمل نسخ و لصق و لصق مش هيغير ولا موقع ذرة + +216 +00:17:43,290 --> 00:17:49,200 +هوين بيصير يغير؟في الإلكترونات فقط واضح هذا الكلام + +217 +00:17:49,200 --> 00:17:53,720 +لازم يكون واضح بخصوص ال resonance من الأسهم كذلك + +218 +00:17:53,720 --> 00:17:59,360 +هذا السهم المنحني بسمي curved arrow يستعمل لتوضيح + +219 +00:17:59,360 --> 00:18:03,720 +حركة زوج من الإلكترونات وعشان هو يستعمل لتوضيح + +220 +00:18:03,720 --> 00:18:11,120 +حركة زوج من الإلكترونات بوضح في الرأسين هدولواضح؟ + +221 +00:18:11,120 --> 00:18:14,320 +تاوي لسه لما وضحنا ال resonance في المثال السابق + +222 +00:18:14,320 --> 00:18:19,100 +استعملناه متذكرين لما قلنا بدنا نحرك هذا الزوج من + +223 +00:18:19,100 --> 00:18:27,000 +الإلكترونات؟ إيش عملنا؟ high curved أقول لما قلنا + +224 +00:18:27,000 --> 00:18:30,300 +بدنا نحرك الرابط، طب ما هي الرابط أيضا إلكترونين، + +225 +00:18:30,300 --> 00:18:35,330 +نجيب إلكترونات هنا، كيف استعملنا؟Curved Arrow فالـ + +226 +00:18:35,330 --> 00:18:41,170 +Curved Arrow is used to indicate the movement of a + +227 +00:18:41,170 --> 00:18:45,290 +pair of electrons، two electrons، واضح؟ + +228 +00:18:50,240 --> 00:18:57,060 +أحيانا بنحرك بس إلكترون واحد مش إلكترونين وجدها + +229 +00:18:57,060 --> 00:19:03,620 +بنستعمل ال curved arrow هذا لكن برأس واحد يعني زي + +230 +00:19:03,620 --> 00:19:09,620 +هيك، هيك صار واضح لكم؟ الآن هذا بيشبه إيش؟ السنارة + +231 +00:19:09,620 --> 00:19:14,610 +تبعت الصيادصيدين السمك اللي بيصيدوا السمك زي هيك + +232 +00:19:14,610 --> 00:19:19,810 +شكل السنارة ولذلك هذا السهم بنسميه احنا ايش fish + +233 +00:19:19,810 --> 00:19:24,790 +hook يعني سهم السنارة fish hook arrow ف ال fish + +234 +00:19:24,790 --> 00:19:31,290 +hook arrow is used to indicate the movement of one + +235 +00:19:31,290 --> 00:19:36,520 +electronلاحظوا اللي كان two electrons كان له رأسين + +236 +00:19:36,520 --> 00:19:41,500 +اللي كان one electron له رأس واحد مثلا لو افترضنا + +237 +00:19:41,500 --> 00:19:46,780 +هذا جزء فيه رابطة، الرابطة كام electron؟ اتنين، + +238 +00:19:46,780 --> 00:19:51,120 +هاي في عندي electronين، الان انا بدي اكسر الرابطة + +239 +00:19:51,120 --> 00:19:56,240 +كسر متجانس اكسرها من النص، electron هان ييجي و + +240 +00:19:56,240 --> 00:20:00,640 +electron هان ييجي اي سهم بدي استعمل؟ ال fish hook + +241 +00:20:00,640 --> 00:20:06,660 +لو عملت زي هيكهيأجى هذا الإلكترون على CH3 صار CH3 + +242 +00:20:06,660 --> 00:20:14,860 +تحمل إلكترون واحد وهذا نفس الشيء واضح؟ اتخيلوا لو + +243 +00:20:14,860 --> 00:20:21,320 +مثلا في هذا الجزء نفسه كنت بدي أخلي الإلكترونين + +244 +00:20:21,320 --> 00:20:25,740 +يروحوا مع CH3 والتانية بدون إلكترونات أي سهم بدي + +245 +00:20:25,740 --> 00:20:32,470 +أستعمل السهم السابق وجدت لو بستعمل هذا السهمالـ + +246 +00:20:32,470 --> 00:20:39,970 +Curved Arrow هينتج عندي من هنا CH3 تحمل زوج + +247 +00:20:39,970 --> 00:20:46,930 +الإلكترونات كله والتانية CH3 + +248 +00:20:46,930 --> 00:20:51,970 +لا تحمل شيئا طبعا لو حسبته ال Formal Charge لهدول + +249 +00:20:51,970 --> 00:20:58,470 +القطعتين اللي طلعوا اتذكروا الكربون أربعة ناقص تلت + +250 +00:20:58,470 --> 00:21:05,890 +روابطناقص إلكترونيل شو هتكون minus ال carbon أربع + +251 +00:21:05,890 --> 00:21:14,590 +ناقص تلت روابط بس plus كأنه قسمت الجزء إلى قطعتين + +252 +00:21:14,590 --> 00:21:19,330 +إلى أيون سالب و أيون موجب لكن أنا قسمت إلى قطعتين + +253 +00:21:19,330 --> 00:21:24,610 +متعادلات فكل هذا الكلام إيش اللي بساعدني عليه أن + +254 +00:21:24,610 --> 00:21:30,460 +أكون فاهم معنى الأسهم اللي أنا بستعملهاو هذا + +255 +00:21:30,460 --> 00:21:34,680 +الكلام ما لم يتضرر بالطالب انه يحط السهم و يرسمه + +256 +00:21:34,680 --> 00:21:39,720 +بإيده و يكتب معناه بإيده بعد فترة هتلاقوه ايش نسيه + +257 +00:21:39,720 --> 00:21:43,480 +احنا دائما و ابدا مافيش امتحان الا بنسألكوا فيه عن + +258 +00:21:43,480 --> 00:21:49,180 +ايش الأسهم لابد الا يجيكم سؤال ايش معنى هذا السهم + +259 +00:21:49,180 --> 00:21:55,520 +لإيش يستعمل هذا السهم اخر + +260 +00:21:55,520 --> 00:22:02,160 +شغلة في هذا الفصلالكيميا العضوية قبل قليل خفتوا و + +261 +00:22:02,160 --> 00:22:08,460 +الأن نقطع الخوف و ننزل الخوف لماذا خفنا من الكيميا + +262 +00:22:08,460 --> 00:22:15,240 +العضوية لأن الكيميا العضوية عشرين مليون مركبأو + +263 +00:22:15,240 --> 00:22:19,560 +أكتر معروفين هدولة غير اللي مش معروفين طيب لما + +264 +00:22:19,560 --> 00:22:24,420 +الإنسان بتعامل مع عدد كبير من الأشياء و بده يقدر + +265 +00:22:24,420 --> 00:22:30,080 +يسيطر عليه كيف بيسيطر عليه؟ من خلال أنه يصنفوا إلى + +266 +00:22:30,080 --> 00:22:35,090 +مجموعات معينة يعمل classificationيعني حتى البشرية + +267 +00:22:35,090 --> 00:22:39,030 +الناس البشر اللي عايشين اليوم احنا بنعمللهم تصنفات + +268 +00:22:39,030 --> 00:22:43,210 +بتسهل علينا نتعامل معهم يعني بنقول والله ها السبعة + +269 +00:22:43,210 --> 00:22:46,810 +أو تمانية مليار بني آدم اللي موجودين ممكن نصنفهم + +270 +00:22:46,810 --> 00:22:54,270 +من زاوية انه ذكور واناث ممكن نصنفهم من زاوية انه + +271 +00:22:54,270 --> 00:23:01,170 +في منهم أغنياء ومتوسطي الحال وفقراءواضح؟ ممكن + +272 +00:23:01,170 --> 00:23:04,170 +نصورهم من زاوية ان في منهم اجسار و في منهم .. + +273 +00:23:04,760 --> 00:23:09,020 +إطوال، ممكن نصنفهم من زاوية الدين، نقول والله فيها + +274 +00:23:09,020 --> 00:23:12,680 +الجد نصارى، فيها الجد مسلمين، فيها الجد .. واضحة + +275 +00:23:12,680 --> 00:23:17,020 +الفكرة؟ كذلك الحالة لما أنا بتكلم عن عشرين مليون + +276 +00:23:17,020 --> 00:23:21,560 +مركب وبدأ أدرس organ ال chemistry و أفهم شيء عن كل + +277 +00:23:21,560 --> 00:23:26,060 +شيء فيهم، لابد أن أعمل تصنيف التصنيف اللي احنا + +278 +00:23:26,060 --> 00:23:31,680 +بنعمله .. فيه تصنيفات كتيرةيعني ممكن مراكبات + +279 +00:23:31,680 --> 00:23:36,420 +أصنفها حسب مصدرها، يعني منتجات طبيعية ولا منتجات + +280 +00:23:36,420 --> 00:23:41,680 +صناعية، ممكن حسب ريحتها، ممكن حسب طعمها، ممكن حسب + +281 +00:23:41,680 --> 00:23:47,040 +كيمياء حيوية، ممكن .. تصنيفات كتيرة، لكن جوا + +282 +00:23:47,040 --> 00:23:50,720 +الكيميا العضوية العادية عشان أسيطر على معظم + +283 +00:23:50,720 --> 00:23:54,980 +الأشياء الأساسية بنصنف حسب شيء بنسميه المجموعة + +284 +00:23:54,980 --> 00:24:01,830 +الوظيفيةشيء مميز في داخل مجموعة من المركبات بنسميه + +285 +00:24:01,830 --> 00:24:06,370 +functional group فال classification of organic + +286 +00:24:06,370 --> 00:24:09,450 +compounds بيكون according to functional groups + +287 +00:24:09,450 --> 00:24:15,250 +مثلا المركبات اللي كلها روابط أحادية بسميها + +288 +00:24:15,250 --> 00:24:19,690 +alkanesلو صار في عندى بين ال carbon و ال carbon + +289 +00:24:19,690 --> 00:24:25,190 +رابطة ثنائية بقول هذه عائلة ال alkenes لو صار + +290 +00:24:25,190 --> 00:24:31,070 +رابطة ثلاثية عائلة ال alkynes لو صار حلقة بروابط + +291 +00:24:31,070 --> 00:24:35,570 +زوجية بقول هدولة ال aromatic compounds لو صار + +292 +00:24:35,570 --> 00:24:41,400 +مركبات في مجموعة ال OHالكحولات وبيشتغ منها + +293 +00:24:41,400 --> 00:24:47,180 +الثيولات زي الكحولات بس بدل OH S H لو كان اكسوجين + +294 +00:24:47,180 --> 00:24:52,790 +بالكربونتينبقول الـ Ethers سلفر بين كربونتين ثيو + +295 +00:24:52,790 --> 00:24:57,570 +إيثرز الـ C double bond O في منها مجموعات كتيرة + +296 +00:24:57,570 --> 00:25:02,250 +الـ C double bond O اللي جنبها H و R بقول عنها + +297 +00:25:02,250 --> 00:25:06,290 +الديهيد لو كانت الـ C double bond O بين كربونتين + +298 +00:25:06,290 --> 00:25:12,080 +كيتون بين كربون و OHacid بين carbon و ore استر + +299 +00:25:12,080 --> 00:25:17,980 +وهكذا الان كل هذه المجموعات هنتعرف عليها في الجزء + +300 +00:25:17,980 --> 00:25:20,600 +الاول من هذا المساق اللي هو جزء ال organic + +301 +00:25:20,600 --> 00:25:25,280 +chemistry يعني كل ما تراونه امامكم على السبورة + +302 +00:25:25,280 --> 00:25:33,880 +هناخده بشكل مفصل و مختصر طبعا واضح ان اي انسان بده + +303 +00:25:33,880 --> 00:25:40,560 +يبتدئ هيبتدئ بأي جزءالالكينز اللي هي المركبات اللي + +304 +00:25:40,560 --> 00:25:46,460 +بتحتوي على روابط أحادية هذا بيكون بداية الفصل + +305 +00:25:46,460 --> 00:25:56,560 +التاني اللي احنا هنبدأ فيه مباشرة واضح؟ + +306 +00:25:58,420 --> 00:26:03,420 +الفصل الثاني اللى هنبدأ فيه بنسميه ال canes and + +307 +00:26:03,420 --> 00:26:09,740 +cycloalcanes يعني يمكن أن تكون هذه المركبات مركبات + +308 +00:26:09,740 --> 00:26:17,600 +متسلسلة و ممكن تكون سكرة على شكل حلقة لكن القاسم + +309 +00:26:17,600 --> 00:26:22,180 +المشترك في ال canes و ال cycloalcanes و الحقيقة + +310 +00:26:22,180 --> 00:26:28,070 +اللى بيعبر عنه هو هذا الحرف ال a اللى هناهو + +311 +00:26:28,070 --> 00:26:34,050 +الروابط الأحادية لو كانت ال الـ Keynes ال A صارت E + +312 +00:26:34,050 --> 00:26:38,130 +بدا أبدأ أحكي عن روابط ثنائية و لو بدا أحكي + +313 +00:26:38,130 --> 00:26:41,790 +Cycloalkynes هيصير فيها روابط ثنائية لو كانت فيها + +314 +00:26:41,790 --> 00:26:47,530 +Y الروابط الثلاثية فال ال Keynes وال Cycloalkynes + +315 +00:26:47,530 --> 00:26:52,310 +فيهم شئ مشترك أن كل الروابط اللي موجودة في الجزء + +316 +00:26:52,310 --> 00:26:54,830 +هي روابط أحادية + +317 +00:26:57,320 --> 00:27:04,960 +الان هذا الكلام بيجيبنا لتصنيف للاشياء الأساسية في + +318 +00:27:04,960 --> 00:27:07,260 +ال organ ال chemistry اللي أنا بسميها ال + +319 +00:27:07,260 --> 00:27:10,900 +hydrocarbons اللي بقصده بال hydrocarbons أبسط + +320 +00:27:10,900 --> 00:27:16,440 +المراكبات العضوية اللي فقط بتحتوي hydrogen و + +321 +00:27:16,440 --> 00:27:20,000 +carbon هاي معناه hydrocarbon hydrocarbons they + +322 +00:27:20,000 --> 00:27:23,980 +contain only carbon and hydrogen الان هدول + +323 +00:27:23,980 --> 00:27:30,000 +المراكباتبصنفهم لصنفين اما بيقول saturated او + +324 +00:27:30,000 --> 00:27:36,000 +unsaturated، saturated مشبع معناه مشبع جميع روابط + +325 +00:27:36,000 --> 00:27:41,360 +أحدية unsaturated في multiple bonds، يعني يا في + +326 +00:27:41,360 --> 00:27:46,710 +double bond يا فيالـ triple bonds الان المراكبات + +327 +00:27:46,710 --> 00:27:54,370 +اللى جميع روابطها أحدية هى ال الكينز والساكلو + +328 +00:27:54,370 --> 00:27:59,150 +الكينز هدول saturated اللى فيهم روابط ثنائية او + +329 +00:27:59,150 --> 00:28:02,830 +ثلاثية او اكتر ال الكينز اللى فيهم ال double bonds + +330 +00:28:02,830 --> 00:28:05,990 +ال الكينز اللى فيهم ال triple bonds و ال aromatic + +331 +00:28:05,990 --> 00:28:09,050 +compounds اللى هم المراكبات اللى بيشبهوا البنزين + +332 +00:28:09,050 --> 00:28:16,690 +فيهم حلقة زاد روابطزوجية فيهم حلقة زاد روابط زوجية + +333 +00:28:16,690 --> 00:28:22,630 +double bonds طبعا لما نيجي نتكلم عن ال alkanes + +334 +00:28:22,630 --> 00:28:28,650 +بنبدأ بمركب فيه carbon واحدة بعد هيك two carbons + +335 +00:28:28,650 --> 00:28:33,910 +three carbons four carbons و هكذا و بنكمل دائما و + +336 +00:28:33,910 --> 00:28:41,070 +أبدا لإيش لأقصى عدد بتحتمل ذرة ال carbon في هذه + +337 +00:28:41,070 --> 00:28:46,870 +الحالة هنكملبهيدروجينات هنكمل بهيدروجينات يعني + +338 +00:28:46,870 --> 00:28:52,310 +مثلا لو كنا بدنا ناخد الجزء الأبسط اللي هو جزء + +339 +00:28:52,310 --> 00:28:58,630 +الميثين هتلاحظوا انه فيه + +340 +00:28:58,630 --> 00:29:07,110 +اربع روابط وكل رابطة فيها هيدروجين اربع روابط وهي + +341 +00:29:07,110 --> 00:29:12,750 +مثلا الهيدروجين باللون نوعا ما ال orangeهذا اللي + +342 +00:29:12,750 --> 00:29:19,310 +هو جزيء الـ Methane الصيغة تبعته إيش بتكون CH4 + +343 +00:29:19,310 --> 00:29:24,170 +بنسميه Methane الآن من Carbon واحدة بقدر أعمل غير + +344 +00:29:24,170 --> 00:29:29,750 +هذا الجزيء؟ لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، + +345 +00:29:29,750 --> 00:29:30,490 +لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، + +346 +00:29:30,490 --> 00:29:31,510 +لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، + +347 +00:29:31,510 --> 00:29:33,410 +لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، ل + +348 +00:29:35,840 --> 00:29:40,560 +هيصير عنده جزء الـ E2 طب ذرتين الكربون هما اللي + +349 +00:29:40,560 --> 00:29:47,120 +هيشبكوا بعض في احتمالات كتيرة ممكن اعملها ايش هما + +350 +00:29:47,120 --> 00:29:54,040 +خليني استعمل روابط اقصر و اوضح اللون الأصفر هذا + +351 +00:29:54,040 --> 00:30:02,640 +هاي الجزء التاني و ربما تلاحظوا انه الكلام بياخدله + +352 +00:30:02,640 --> 00:30:05,520 +دقيقة واجت لكن لا بأس بذلك + +353 +00:30:09,830 --> 00:30:16,010 +هي هدول بلاش نحط ال hydrogens يفهموا ضمنها CH3 CH3 + +354 +00:30:16,010 --> 00:30:22,270 +دارتين كربون عندي إمكانية أعمل غير هذا الشكل لأاذا + +355 +00:30:22,270 --> 00:30:27,550 +كام isomer عندى من ال E2 ايضا isomer واحد مش قادر + +356 +00:30:27,550 --> 00:30:32,890 +اعمل غيره طيب الان ناس جابوا ذرة كربون جديدة ها + +357 +00:30:32,890 --> 00:30:36,630 +يوم مسكينها بدهم يضيفوها على هذا الجزء اكيد بدنا + +358 +00:30:36,630 --> 00:30:41,370 +نشيلها هيدروجين و نحط كربون يا بنحطها هنا او + +359 +00:30:41,370 --> 00:30:45,390 +بالجهات التانية نفس الاشي كام احتمال عندى عشان احط + +360 +00:30:45,390 --> 00:30:49,050 +ذرة الكربون الجديدة أبدا + +361 +00:30:50,460 --> 00:30:58,460 +فارجوني احتمال تاني و بنكمل هذه الذرة .. بنكمل هذه + +362 +00:30:58,460 --> 00:31:04,540 +الذرة هاي الجزء اللي من تلت كربونات ممكن تلت + +363 +00:31:04,540 --> 00:31:08,990 +كربونات احطه من غير هذا الاحتمال؟فكروا معي، لا + +364 +00:31:08,990 --> 00:31:13,930 +يمكن، إذا هذا الجزء اللي من تلات كربونات البروبين + +365 +00:31:13,930 --> 00:31:22,890 +اللي صيغته CH3 CH2 CH3 لا يوجد منه إلا شكل واحد، + +366 +00:31:22,890 --> 00:31:28,930 +متشكل واحد فقط لا غيرواضح؟ لحظة أنا بحط عدد ذرات + +367 +00:31:28,930 --> 00:31:34,110 +الكربون وال number of structural isomers فالميثان + +368 +00:31:34,110 --> 00:31:39,250 +والإيثان والبروبين لا يوجد منهم غير متشكل واحد + +369 +00:31:39,250 --> 00:31:43,490 +خلّيني أجيب في نص دقيقة الآن لو جينا واطلعنا على + +370 +00:31:43,490 --> 00:31:50,860 +الصيغ وقلنا إن الميثان CH4 والإيثان CH6لبروبين + +371 +00:31:50,860 --> 00:31:56,900 +C3H8 هذا الكلام هيرجعنا خطوة للوراء ان صيغة العامة + +372 +00:31:56,900 --> 00:32:05,180 +للالكينز CN H2N Plus 2 يعني لما تكون C1 تكون H 2X1 + +373 +00:32:05,180 --> 00:32:12,280 +اتنين زي اتنين اربعة لو كانت ال C3 اتنين في اتنين + +374 +00:32:14,820 --> 00:32:18,920 +إتنين في تلاتة ستة زاد اتنين تمانية شايفين + +375 +00:32:18,920 --> 00:32:23,760 +التمانية ولا لأ هايهم تلاتة و اتنين و تلاتة و هكذا + +376 +00:32:23,760 --> 00:32:28,820 +الآن لو بدنا نيجي على ال C4 المركب اللي من أربع + +377 +00:32:28,820 --> 00:32:35,480 +ذرات كربون طالما قلنا C4 إذا كم هيدروجينة هيكون + +378 +00:32:35,480 --> 00:32:40,380 +فيه حسب القاعدة أربعة في اتنين تمانية تمانية زاد + +379 +00:32:40,380 --> 00:32:52,020 +اتنين عشرة طيب خلينانحمل معنى ذرة كربون رباعية هاي + +380 +00:32:52,020 --> 00:32:58,160 +ذرة كربون و بدنا نضيف على هذا الجزءانتبهوا معي + +381 +00:32:58,160 --> 00:33:02,180 +الان بإمكاني اضيفها على الطرف يعني اعمل سلسلة + +382 +00:33:02,180 --> 00:33:07,140 +طويلة لو ضيفتها على هذه ال carbon صار مركب جديد + +383 +00:33:07,140 --> 00:33:11,980 +اربع ذرات متسلسلة لو ضيفتها هنا نفس الاشي اربع + +384 +00:33:11,980 --> 00:33:17,100 +ذرات متسلسلة لكن لو ضيفتها هناهيصير عندى مركب + +385 +00:33:17,100 --> 00:33:24,980 +متشعب branched molecule اذا لما بصل للاربعة بتبدأ + +386 +00:33:24,980 --> 00:33:32,080 +عند ظاهرة التشكل هنا بإمكانى ان احصل على مركبين + +387 +00:33:32,080 --> 00:33:39,240 +مركب بهذا الشكل مركب بهذا الشكل ونكمل هنا بالتأكيد + +388 +00:33:39,240 --> 00:33:42,840 +الهيدروجينات التلاتة + +389 +00:33:48,630 --> 00:33:54,350 +شايفينوا كيف؟ حيصير صيغته CH3 CH2 CH2 CH3 هذا + +390 +00:33:54,350 --> 00:33:57,790 +بتسميه بيوتين عادي، الآن هذا موجود عندنا بعد هيك + +391 +00:33:57,790 --> 00:34:03,090 +في الجدوللاحظوا بكربون واحدة قولت اندي ميثين + +392 +00:34:03,090 --> 00:34:10,070 +بتنتين ايه اتين بتلاتة بربين باربعة صار بإمكاني + +393 +00:34:10,070 --> 00:34:14,010 +اجيب الكربون الجديدة على الطرف هنا و اعمل مركب + +394 +00:34:14,010 --> 00:34:20,690 +متسلسل سميته ايش بيوتين طيب لو واحدة اجت و حطت + +395 +00:34:20,690 --> 00:34:26,730 +الكربون الجديدة في النص هنا عملت + +396 +00:34:26,730 --> 00:34:33,780 +branch compoundمركب متفرع هذا بسميه Isobutane شبيه + +397 +00:34:33,780 --> 00:34:39,160 +ل Butane Iso يعني شبيه واضح؟ Isobutane هاي ال + +398 +00:34:39,160 --> 00:34:43,680 +carbon الجديدة كان عندي تلاتة CH3 CH .. CH3 تلت + +399 +00:34:43,680 --> 00:34:48,880 +كربونات حطيت التفرع يا ترى من الطرف ولا حطيت + +400 +00:34:48,880 --> 00:34:54,200 +التفرع من النصهنا من النص وهنا من الطرف إذا من الـ + +401 +00:34:54,200 --> 00:35:01,600 +butane أو من الصيغة C4H10 كام isomers عندى؟ two + +402 +00:35:01,600 --> 00:35:06,960 +isomers إيش اسم هما دول ال two isomers؟ butane و + +403 +00:35:06,960 --> 00:35:11,140 +isobutane هذا الكلام بيجي بالتجريب الآن لو برجع + +404 +00:35:11,140 --> 00:35:17,680 +للخلف لاحظوا معاه لو بديت أحكي عن البنتين + +405 +00:35:19,430 --> 00:35:23,330 +هلاحر وهذا بدي اسيبه homework واجب عندكم انتوا + +406 +00:35:23,330 --> 00:35:27,590 +تتعبوا فيه شوية البنتين الهكسين الهبتين انه عدد + +407 +00:35:27,590 --> 00:35:35,050 +المركبات الممكنة لخمس ذرات كربون تلت مركبات تلت + +408 +00:35:35,050 --> 00:35:39,350 +مركبات طبعا واحدة بتقول طب انا كيف بدي اشتغل + +409 +00:35:39,350 --> 00:35:43,830 +الكلام صح؟كيف بدي أشغل الكلام صح؟ بنقولها بسيطة، + +410 +00:35:43,830 --> 00:35:48,310 +عشان تشتغليهم لوحدك، بدك تعمل القاتل، تقولي أربع + +411 +00:35:48,310 --> 00:35:51,950 +ذرات كربون، الهيكل اللي من أربع ذرات كربون، كام + +412 +00:35:51,950 --> 00:35:56,870 +احتمال له؟ إتنين، الآن بدي أزيد واحدة، خليني أنا + +413 +00:35:56,870 --> 00:36:01,450 +أمسي الجلم أحمر، هذه الواحدة اللي بدي أزيدها، يا + +414 +00:36:01,450 --> 00:36:06,470 +بدي أزيدها على هذا الشكل؟أو على هذا الشكل طب لو + +415 +00:36:06,470 --> 00:36:10,870 +بدأ أزيد carbon هنا وين ممكن أحطها؟ هذا الموقع و + +416 +00:36:10,870 --> 00:36:16,910 +هذا الموقع زي بعض هيطلعولي شكل و هذا الموقع و هذا + +417 +00:36:16,910 --> 00:36:23,250 +الموقع زي بعض هيطلعولي شكل واضح؟ يعني كإن هنا إجيت + +418 +00:36:23,250 --> 00:36:29,630 +و حطيت ال CH3H أو CH3H هاي صار عندى كام مركب + +419 +00:36:29,630 --> 00:36:37,380 +مركبين إجداد طب هناوين بتحط الكربونة الجديدة؟ يا + +420 +00:36:37,380 --> 00:36:41,480 +على الكربون الوسطانية هذه، يا على أي واحدة من + +421 +00:36:41,480 --> 00:36:44,160 +هدول، لحظوا دول زي بعض ولا لا؟ ملاحظين التماثل + +422 +00:36:44,160 --> 00:36:48,780 +اللي فيهم؟ فلو واحدة حطت على الكربون الوسطانية، هي + +423 +00:36:48,780 --> 00:36:54,620 +مركّب، و لو واحدة حطت على أي واحدة من هدولة، هي + +424 +00:36:54,620 --> 00:37:01,430 +مركّب، كم مركّب طلعوا؟لأ تلاتة، ليش؟ لما تتطلعوا + +425 +00:37:01,430 --> 00:37:07,630 +بعمق هذا المركب و هذا المركب نفس الاشياء تطلعوا + +426 +00:37:07,630 --> 00:37:12,630 +عليه carbon حاملة مجموعتين مثل، بعدين CH2 CH3 و + +427 +00:37:12,630 --> 00:37:18,390 +هذا carbon حاملة مجموعتين مثل، بعدين CH2 CH3 هذا و + +428 +00:37:18,390 --> 00:37:22,590 +هذا زي بعض، إذا لو قولت كام شكل طلع عندى من + +429 +00:37:22,590 --> 00:37:30,160 +البنتين، تلاتة، هذا واحد و هذا واحدو هذا واحد + +430 +00:37:30,160 --> 00:37:38,160 +واضح؟ الان هذا الشكل المتسلسل له اسم شو بسمي انا؟ + +431 +00:37:38,160 --> 00:37:45,820 +بنتين او انا بنتين انا بنتين بنتين + +432 +00:37:45,820 --> 00:37:53,020 +كام كربونة؟ واحد اتنين تلاتة اربعة خمسةبالشكل اللي + +433 +00:37:53,020 --> 00:37:57,200 +مرسوم هيك بنتين لما حطيت carbon على الفراغ، الآن + +434 +00:37:57,200 --> 00:38:04,800 +هذا الشكل إيش بسميه؟ ISO بنتين، شبيه البنتين، + +435 +00:38:04,800 --> 00:38:11,610 +لاحظوا معي كلمة ISO بدت إيش؟تتكرر توي اجاني ايزو + +436 +00:38:11,610 --> 00:38:17,610 +بيوتين من الايزو بيوتين عملت ايزو بنتين اذا وقت + +437 +00:38:17,610 --> 00:38:22,270 +ايش بشوف كلمة ايزو انا كلمة ايزو اللي بيميزها وجود + +438 +00:38:22,270 --> 00:38:28,600 +كاربون بتحملمجمعتين مثل يعني هذه الكربون اللى + +439 +00:38:28,600 --> 00:38:35,700 +بتحمل CH3 و كمان CH3 متفرع منها هذا الشكل بقوله + +440 +00:38:35,700 --> 00:38:41,120 +ايش انا ISO لما جيبت هنا كمان كربونا العدد الكلي + +441 +00:38:41,830 --> 00:38:47,830 +قداش صفة؟ اربعة واحد اتنين تلاتة اربعة فهذا المركب + +442 +00:38:47,830 --> 00:38:52,750 +شو سميته ايزو بيوتين لأنه عدده اربعة طب لو جبت + +443 +00:38:52,750 --> 00:38:58,370 +carbon تاني يعني خليته CH2 العدد الكل قداش صفة + +444 +00:38:58,370 --> 00:39:05,750 +عندى؟ خمسة هى هذا بيقولي ايزو و العدد الكل خمسة + +445 +00:39:05,750 --> 00:39:11,640 +بينتين طب لو الان قلت لو واحدة ايزو هكسينبدي أخلّي + +446 +00:39:11,640 --> 00:39:19,900 +هذه تنتين أزيد واحدة ايزو هبتين هذا الجزء بيقول لي + +447 +00:39:19,900 --> 00:39:25,260 +كلمة ايزو و العدد الكلي بيحدد اللي موجود عنده الان + +448 +00:39:25,260 --> 00:39:32,040 +هاي هذا الجزء موجود هنا هاي ايزو واحد اتنين تلاتة + +449 +00:39:32,040 --> 00:39:37,260 +اكملت اربعة خمسة اذا ايش صار عندك ايزو بنتين و هذا + +450 +00:39:37,260 --> 00:39:43,140 +نفسه ايزو بنتينمُركّبات البنتين هي البنتين والأيزو + +451 +00:39:43,140 --> 00:39:48,180 +بنتين وهذا المُركّب الأخير كاربون متفرع منها أربع + +452 +00:39:48,180 --> 00:39:51,660 +مجموعات مثل إسم الـ New بنتين + +453 +00:39:57,160 --> 00:40:00,800 +الـ isomers بتاعون البنتين، الخمسة isomers، لاحظوا + +454 +00:40:00,800 --> 00:40:06,980 +أنا قولت البنتين، خمس درات، عفوا التلاتة isomers، + +455 +00:40:06,980 --> 00:40:15,390 +كم isomers؟ إيش أسميهم؟ بنتين، iso-بنتين؟و نيو + +456 +00:40:15,390 --> 00:40:20,290 +بنتين بنتين ايزو بنتين نيو بنتين الان لو واحدة بدت + +457 +00:40:20,290 --> 00:40:25,170 +تعمل الستة بدت تجيب ورقة و جلم ارصاص وتجرب تاخد + +458 +00:40:25,170 --> 00:40:29,030 +لها ربع ساعة تلت ساعة من وين نقطة الانطلاق تبعتها + +459 +00:40:29,030 --> 00:40:34,870 +بدكون من هدولة التلاتة تعون البنتين وتصير تزيد + +460 +00:40:34,870 --> 00:40:41,070 +عليهم carbonواضح؟ لأن هدولة الخمس كربونات هي + +461 +00:40:41,070 --> 00:40:43,830 +أشكالهم، يا هذا، يا هذا، يا هذا، الآن بدي أزيد + +462 +00:40:43,830 --> 00:40:47,490 +عليهم كربون، بجرب كل احتمالاتهان، كل احتمالاتهان، + +463 +00:40:47,490 --> 00:40:51,590 +كل احتمالاتهان، و بشوف الأشكال المشتركة، و بطلع + +464 +00:40:51,590 --> 00:40:57,610 +الجواب، في النهاية، هلاحظ أن ال six كربونات، كم + +465 +00:40:57,610 --> 00:41:05,030 +مركب لهم؟ خمسة isomers، السبع كربوناتتسعة isomers + +466 +00:41:05,030 --> 00:41:10,670 +و هكذا طيب لو يا تورا سألنا سؤال و هذا أرجو أنكوا + +467 +00:41:10,670 --> 00:41:18,130 +تنتبهوا له هل هناك قاعدة عامة بتيجي بتقولي إذا + +468 +00:41:18,130 --> 00:41:21,950 +عندك هذا العدد من ال carbons معنى ذلك عندك هذا + +469 +00:41:21,950 --> 00:41:26,950 +العدد من ال isomers قاعدة رياضية حسابية بسيطة في + +470 +00:41:26,950 --> 00:41:33,420 +قاعدة بس لأول عشر مركباتالحقيقة مافيش قاعدة مافيش + +471 +00:41:33,420 --> 00:41:38,260 +قاعدة هذا كان أحيانا في أحد الكتب المدرسية محطوط + +472 +00:41:38,260 --> 00:41:42,580 +سؤال على الجانب هل توجد قاعدة وكثير من المدرسين + +473 +00:41:42,580 --> 00:41:48,140 +كانوا بيعملوا فيه اجتهادات كثيرة مافيش قاعدةإذا + +474 +00:41:48,140 --> 00:41:52,060 +أنا .. هذا الكلام كله بالتجريب بتم .. إذا أنا كان + +475 +00:41:52,060 --> 00:41:56,840 +في عندى .. إذا أنا كان في عندى عدد ال carbons إن + +476 +00:41:56,840 --> 00:42:00,320 +أقدر أعرف منها عدد ال isomers هذا الكلام بتم .. + +477 +00:42:00,320 --> 00:42:03,520 +بإيش؟ بالتجريب لكن لاحظوا كيف الكيميا العضوية + +478 +00:42:03,520 --> 00:42:09,710 +بتكبر كتير يعني مثلا لما نصل ل ..الـ 6 هكسين، 7 + +479 +00:42:09,710 --> 00:42:14,090 +هبتين، 8 أكتين، 9 نونين، 10 ديكين، 10 كربونات + +480 +00:42:14,090 --> 00:42:22,110 +بلاحظ أن العشر كربونات هدولة منهم 75 مركّب 75 + +481 +00:42:22,110 --> 00:42:29,610 +isomers يعني الصيغة C10H22 لأن عشرة في اتنين عشرين + +482 +00:42:29,610 --> 00:42:33,930 +زاد اتنين اتنين وعشرينفي بدها خمسة وسبعين مُركّب، + +483 +00:42:33,930 --> 00:42:37,690 +بهيك بنقدر نصير فاهمين ليش الكيميا العضوية كبيرة + +484 +00:42:37,690 --> 00:42:43,030 +في عدد مُركّباتها، انه من نفس العدد من الذرات عمال + +485 +00:42:43,030 --> 00:42:50,670 +بنعمل احنا عدد كبير جدا من المتشكلات، بنعمل عدد + +486 +00:42:50,670 --> 00:42:53,750 +كبير جدا من المتشكلات + +487 +00:42:55,530 --> 00:43:02,290 +هذا بالنسبة للألكنز الأساسية ومتشكلات هذه الألكنز + +488 +00:43:02,290 --> 00:43:07,590 +الأساسية المرة الماضية ونأكد عليك آخر شيء بدنا + +489 +00:43:07,590 --> 00:43:13,790 +نحكيه اتكلمنا عن جزء الميثين اللي هو الجزء الأول + +490 +00:43:13,790 --> 00:43:19,590 +وقلنا كيف شكله الميثين تتراهيدرال + +491 +00:43:19,590 --> 00:43:25,180 +CH4ومعنى tetrahedral أنه أبقله أربع وجوه يعني لو + +492 +00:43:25,180 --> 00:43:29,420 +أنا جيبت مثلث أو ممكن نستعمل الروابط الكبيرة عشان + +493 +00:43:29,420 --> 00:43:36,700 +نوضح الأمر خلال تلت دقائق تقريبا المتبقية هاي جزاء + +494 +00:43:36,700 --> 00:43:43,420 +الميثين هذا قولنا عنه إيش الشكل تبعه تتراهيدرال + +495 +00:43:43,420 --> 00:43:49,800 +رباعي الأوجه اللي بنقصده احنا برباعي الأوجه أنه + +496 +00:43:49,800 --> 00:43:56,940 +انا لو جيبتمثلث وجه زي هذا المثلث اللى موجود عندى + +497 +00:43:56,940 --> 00:44:04,100 +و سكرت هنا هى ايش عندى وجه طب لو عملت هان وجهين لو + +498 +00:44:04,100 --> 00:44:09,740 +عملت هان تلت أوجه لو عملت هان سكر الشكل شفتوا ليش + +499 +00:44:09,740 --> 00:44:14,600 +رباع الأوجه يعني لو أنا هذا بدي أسكره على شكل معين + +500 +00:44:14,600 --> 00:44:20,550 +بدي كام مثلث زي هذا أربعة أربعة أوجه هى وجهوهي + +501 +00:44:20,550 --> 00:44:28,910 +كمان وجه سكرت هان وهي كمان وجه معين سكرت هذه وهي + +502 +00:44:28,910 --> 00:44:33,870 +كمان الوجه الرابع سكرت هذه ولذلك ايش بنسمي الشكل + +503 +00:44:33,870 --> 00:44:40,390 +تبع الميثين تتراهيدرال واضح ان هذا الشكل في مستوى + +504 +00:44:40,390 --> 00:44:44,310 +واحد ولا بالفراغ يعني planner ولا three + +505 +00:44:44,310 --> 00:44:49,050 +dimensional بنسميه three dimensional بالفراغالان + +506 +00:44:49,050 --> 00:44:53,330 +لما بدى اعبر عن هذا الشكل كيف باعبر عنه افضل الطرق + +507 +00:44:53,330 --> 00:44:58,670 +للتعبير عنه ان انا امسكه بهذه الطريقة اتخيل ان + +508 +00:44:58,670 --> 00:45:04,050 +هدولة التنتين جايين في مستوى أفقي للامام لاحظوا + +509 +00:45:04,050 --> 00:45:08,050 +هاي المستوى هذا مستوى أفقي ولا لأ و بينهم زاوية + +510 +00:45:08,050 --> 00:45:11,930 +مية وتسعة و نصف و هدولة جايين في مستوى متعامد على + +511 +00:45:11,930 --> 00:45:16,610 +المستوى الأفقي للخلف اذا الجزء افضل طريقة لرسمه + +512 +00:45:16,610 --> 00:45:21,830 +اتخيله بهذا الشكلهي مستوى أفقي للأمام عمودي عليهم + +513 +00:45:21,830 --> 00:45:29,650 +تنتين في مستوى أفقي لوين؟ للخلف واضح؟ مستويين هي + +514 +00:45:29,650 --> 00:45:34,830 +مستوى أفقي ومستوى عمودي عليه الأفقي تنتين للأمام و + +515 +00:45:34,830 --> 00:45:40,010 +العمودي عليه تنتين للخلف طب هذا الكلام سهل أن + +516 +00:45:40,010 --> 00:45:44,750 +نشرحه لكن لو قلنا يا تورا بدنا نرسمه دائما الاشي + +517 +00:45:44,750 --> 00:45:50,670 +للخلف كيف برسمه أنا؟مُنَقَط أو شرطات dashes واللي + +518 +00:45:50,670 --> 00:45:56,030 +للأمام solid مسكّر واضح؟ أفضل الطرق اللي ممكن + +519 +00:45:56,030 --> 00:46:01,010 +نستعملها لرسم هذا الجزء هي هذه الطريقة ان اخلي + +520 +00:46:01,010 --> 00:46:06,870 +هدول ال hydrogens للأمام وبستعمل هذا المثلث أو + +521 +00:46:06,870 --> 00:46:13,850 +بنسمي احنا ايش wedge عارفين ايش يعني wedge؟ هذا + +522 +00:46:13,850 --> 00:46:22,930 +اللي زي هيكبنقول عنه wedge وتحديدا solid wedge ولو + +523 +00:46:22,930 --> 00:46:30,850 +كان للخلف التانية دولة للخلف بنعمله dashed wedge + +524 +00:46:30,850 --> 00:46:38,170 +wedge تترجم باللغة العربية بمعنى أسفيل الأسفيل + +525 +00:46:38,170 --> 00:46:42,930 +شغلة زي هذهشايفين هذه الخشبة؟ هذه إحنا إيش + +526 +00:46:42,930 --> 00:46:49,470 +بنسميها؟ أسفين ماروا عليكم هذا الإسم؟ حتى .. حتى + +527 +00:46:49,470 --> 00:46:53,890 +في اللغة .. حتى في اللغة الأدبية والإنسانية كلمة + +528 +00:46:53,890 --> 00:46:59,270 +أسفين بتمر معنى كتير اللي بيكون بيفرج اتنين أصدقاء + +529 +00:46:59,270 --> 00:47:04,440 +عن بعض إيش بنستعمله إحنا باللغة الأدبية؟بنقول و + +530 +00:47:04,440 --> 00:47:10,000 +جاء فلان و دق اسفينا بين الإخوة، فرجهم مع بعض، + +531 +00:47:10,000 --> 00:47:13,560 +يعني تخيلوا أنتوا، هاي هذه وهذه إخوة، الآن باجي + +532 +00:47:13,560 --> 00:47:16,840 +أنا بهذا الإسفين، بحطه، بصير بدوجي بهذا الشكل، + +533 +00:47:16,840 --> 00:47:22,390 +بهذا الشكل، شو بعمل؟ببعدهم عن بعض فكلمة دقة اسفينا + +534 +00:47:22,390 --> 00:47:27,190 +باللغة العربية والقصصية معناها بعادهم عن بعض هذا + +535 +00:47:27,190 --> 00:47:32,150 +اللي أنا بستعمله إيش بسميه أنا اسفين اللي للأمام + +536 +00:47:32,150 --> 00:47:37,610 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الرابطة تيجي على ال oxygen هنا واضح؟ صار عندي شكل جديد إيش الإختلاف بين الشكل الأول والشكل التاني؟ تطلع عليهم", "tokens": [2407, 3224, 15730, 11933, 23275, 2655, 2288, 11536, 9957, 4032, 38149, 47525, 10721, 41950, 2288, 5551, 5016, 31747, 29538, 34892, 16758, 9566, 3660, 6055, 1829, 7435, 1829, 15844, 2423, 9169, 34105, 4032, 46958, 5016, 22807, 20328, 9640, 18871, 16254, 13412, 28820, 10874, 16254, 3215, 11933, 1829, 8592, 33688, 46456, 15040, 5172, 49374, 25124, 28820, 16247, 12610, 16070, 8592, 28820, 16712, 7649, 1829, 22807, 6055, 9566, 1211, 3615, 25894, 16095], "avg_logprob": -0.2776785786662783, "compression_ratio": 1.5476190476190477, "no_speech_prob": 0.0, "words": [{"start": 709.1, "end": 709.68, "word": "وهذا", "probability": 0.6966959635416666}, {"start": 709.68, "end": 711.34, "word": " إلكترونين", "probability": 0.6998799641927084}, {"start": 711.34, "end": 711.9, "word": " وقت", "probability": 0.4989013671875}, {"start": 711.9, "end": 712.26, "word": " بدأ", 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751.64, "text": "فقط في مواقع الإلكترونات بمعنى الذرات Carbon Oxygen Oxygen Oxygen Carbon Oxygen Oxygen Oxygen لكن الإلكترونات تغير شكلها واضح بإمكان أعمل كمان تغيير مثلا ممكن أجيب هذا زوج الإلكترونات هان أخليها دي جهان صار عندي شكل جديد الآن الشكل الأول التاني التالت شو بسميهم أنا", "tokens": [5172, 47432, 8978, 3714, 14407, 4587, 3615, 33688, 23275, 2655, 2288, 11536, 9307, 4724, 2304, 3615, 1863, 7578, 32545, 2288, 9307, 31453, 16489, 8647, 16489, 8647, 16489, 8647, 31453, 16489, 8647, 16489, 8647, 16489, 8647, 44381, 33688, 23275, 2655, 2288, 11536, 9307, 6055, 17082, 13546, 13412, 28820, 11296, 4032, 46958, 5016, 4724, 28814, 2304, 41361, 5551, 25957, 1211, 9122, 2304, 7649, 6055, 17082, 1829, 13546, 50113, 15040, 3714, 43020, 5551, 7435, 1829, 3555, 23758, 30767, 29245, 33688, 23275, 2655, 2288, 11536, 9307, 8032, 7649, 5551, 9778, 20292, 11296, 11778, 1829, 10874, 3224, 7649, 20328, 9640, 18871, 16254, 13412, 28820, 10874, 16254, 3215, 6024, 48506, 25124, 28820, 16247, 12610, 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778.76, "text": "Resonance structures يعني أشكال رانيل بنقولها بالعربي فال resonance كفكرة arises whenever we can write two or more structures for a molecule with different arrangement of electrons but identical arrangement of atoms لاحظوا هذا بيجيبلنا مفهوم كتير مهم عندنا أنه أنا ممكن أغير في الإلكترونات بدون ما أغير الذرات", "tokens": [33274, 266, 719, 9227, 37495, 22653, 5551, 8592, 4117, 6027, 12602, 7649, 26895, 44945, 39648, 11296, 20666, 3615, 2288, 21292, 6156, 6027, 30944, 9122, 5172, 4117, 25720, 27388, 5699, 321, 393, 2464, 732, 420, 544, 9227, 337, 257, 15582, 365, 819, 17620, 295, 14265, 457, 14800, 17620, 295, 16871, 20193, 5016, 19913, 14407, 23758, 4724, 1829, 7435, 1829, 3555, 1211, 8315, 3714, 5172, 3224, 20498, 9122, 2655, 13546, 3714, 16095, 43242, 8315, 14739, 3224, 41850, 3714, 43020, 5551, 17082, 13546, 8978, 33688, 23275, 2655, 2288, 11536, 9307, 47525, 11536, 19446, 5551, 17082, 13546, 32545, 2288, 9307], "avg_logprob": -0.19909793814432988, 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اللي قاعد بيشتغل على برنامج الرسم وحط الذرات في أول مرة زي المثال السابق بيعمل نسخ و لصق و لصق مش هيغير ولا موقع ذرة هوين بيصير يغير؟", "tokens": [1211, 10721, 819, 17620, 295, 14265, 6156, 2655, 30544, 14407, 44650, 8848, 37983, 9957, 16472, 2423, 30944, 6156, 47432, 1975, 46456, 15040, 5172, 8978, 6055, 2288, 31371, 3555, 2423, 6027, 4117, 2655, 2288, 11536, 9307, 44381, 19446, 44945, 38149, 25513, 9154, 32545, 2288, 9307, 32545, 2288, 9307, 30767, 1829, 19446, 8032, 2304, 37495, 22653, 13672, 1829, 12174, 995, 22488, 4724, 1829, 8592, 2655, 17082, 1211, 15844, 4724, 2288, 8315, 2304, 7435, 34892, 38251, 4032, 5016, 9566, 32545, 2288, 9307, 8978, 5551, 12610, 3714, 25720, 30767, 1829, 9673, 12984, 6027, 21136, 16758, 4587, 4724, 1829, 25957, 1211, 8717, 3794, 9778, 4032, 5296, 9381, 4587, 4032, 5296, 9381, 4587, 37893, 39896, 17082, 13546, 49429, 3714, 30543, 3615, 29910, 25720, 31439, 9957, 4724, 1829, 9381, 13546, 7251, 17082, 13546, 22807], "avg_logprob": -0.13366699498146772, 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واضح لكم؟ الآن هذا بيشبه إيش؟ السنارة تبعت الصياد", "tokens": [10721, 5016, 1829, 7649, 995, 44945, 5016, 31747, 4724, 3794, 11933, 23275, 2655, 2288, 11536, 36764, 24401, 37893, 11933, 23275, 2655, 2288, 11536, 9957, 49610, 3215, 11296, 44945, 14851, 25957, 1211, 2423, 24991, 11610, 23758, 44381, 4724, 2288, 10721, 3794, 36764, 24401, 37495, 22653, 30767, 1829, 39896, 4117, 12399, 39896, 4117, 20328, 9640, 4032, 46958, 5016, 5296, 24793, 22807, 6024, 48506, 23758, 4724, 1829, 8592, 3555, 3224, 11933, 1829, 8592, 22807, 21136, 8315, 25720, 6055, 3555, 34268, 31767, 1829, 18513], "avg_logprob": -0.23225308936319233, "compression_ratio": 1.5909090909090908, "no_speech_prob": 0.0, "words": [{"start": 1130.24, "end": 1131.08, "word": "أحيانا", "probability": 0.8634765625}, {"start": 1131.08, "end": 1132.64, "word": " بنحرك", "probability": 0.5543619791666666}, {"start": 1132.64, "end": 1133.2, "word": " بس", "probability": 0.63525390625}, {"start": 1133.2, "end": 1134.02, "word": " 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"end": 1305.2, "word": " الأسهم", "probability": 0.8533528645833334}, {"start": 1305.2, "end": 1306.22, "word": " لابد", "probability": 0.95849609375}, {"start": 1306.22, "end": 1306.46, "word": " الا", "probability": 0.34033203125}, {"start": 1306.46, "end": 1307.02, "word": " يجيكم", "probability": 0.93505859375}, {"start": 1307.02, "end": 1307.78, "word": " سؤال", "probability": 0.9855143229166666}, {"start": 1307.78, "end": 1308.08, "word": " ايش", "probability": 0.92919921875}, {"start": 1308.08, "end": 1308.46, "word": " معنى", "probability": 0.94189453125}, {"start": 1308.46, "end": 1308.76, "word": " هذا", "probability": 0.96728515625}, {"start": 1308.76, "end": 1309.18, "word": " السهم", "probability": 0.98828125}, {"start": 1309.18, "end": 1309.56, "word": " لإيش", "probability": 0.7635498046875}, {"start": 1309.56, "end": 1310.84, "word": " يستعمل", "probability": 0.99462890625}, {"start": 1310.84, "end": 1311.96, "word": " هذا", "probability": 0.9619140625}, {"start": 1311.96, "end": 1312.4, "word": " السهم", "probability": 0.984375}, {"start": 1312.4, "end": 1315.52, "word": " اخر", "probability": 0.7705078125}, {"start": 1315.52, "end": 1316.1, "word": " شغلة", "probability": 0.9407552083333334}, {"start": 1316.1, "end": 1316.44, "word": " في", "probability": 0.95849609375}, {"start": 1316.44, "end": 1316.84, "word": " هذا", "probability": 0.982421875}, {"start": 1316.84, "end": 1317.76, "word": " الفصل", "probability": 0.971923828125}], "temperature": 1.0}, {"id": 57, "seek": 133388, "start": 1319.24, "end": 1333.88, "text": "الكيميا العضوية قبل قليل خفتوا و الأن نقطع الخوف و ننزل الخوف لماذا خفنا من الكيميا العضوية لأن الكيميا العضوية عشرين مليون مركب", "tokens": [6027, 4117, 32640, 25528, 18863, 11242, 2407, 10632, 12174, 36150, 12174, 20292, 1211, 16490, 5172, 2655, 14407, 4032, 16247, 1863, 8717, 47432, 3615, 33962, 38688, 4032, 8717, 1863, 11622, 1211, 33962, 38688, 32767, 45636, 995, 16490, 5172, 8315, 9154, 33251, 32640, 25528, 18863, 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butane أو من الصيغة C4H10 كام isomers عندى؟ two isomers إيش اسم هما دول ال two isomers؟ butane و isobutane هذا الكلام بيجي بالتجريب الآن لو برجع للخلف لاحظوا معاه لو بديت أحكي عن البنتين", "tokens": [3224, 8315, 9154, 28239, 9381, 37037, 8315, 9154, 41950, 28480, 11933, 15730, 9154, 2423, 39184, 457, 1929, 34051, 9154, 31767, 1829, 17082, 3660, 383, 19, 39, 3279, 9122, 10943, 307, 298, 433, 43242, 7578, 22807, 732, 307, 298, 433, 11933, 1829, 8592, 24525, 2304, 8032, 15042, 11778, 12610, 2423, 732, 307, 298, 433, 22807, 457, 1929, 4032, 307, 996, 325, 1929, 23758, 2423, 28820, 10943, 4724, 1829, 7435, 1829, 20666, 2655, 7435, 16572, 3555, 6024, 48506, 45164, 4724, 47341, 3615, 24976, 9778, 46538, 20193, 5016, 19913, 14407, 20449, 40294, 45164, 47525, 36081, 5551, 5016, 4117, 1829, 18871, 29739, 29399, 9957], "avg_logprob": -0.20281558874810096, "compression_ratio": 1.6203703703703705, "no_speech_prob": 0.0, "words": [{"start": 2091.3, "end": 2091.68, "word": "هنا", "probability": 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+1,1632 @@ +1 +00:00:19,470 --> 00:00:24,710 +بسم الله الرحمن الرحيم بنكمل اليوم في موضوع ال + +2 +00:00:24,710 --> 00:00:30,170 +aldehydes و ال ketones و ربما كلكم الذاكرين أنه + +3 +00:00:30,170 --> 00:00:34,130 +التفاعل الأساسي لل aldehydes و ال ketones كان + +4 +00:00:34,910 --> 00:00:40,890 +Heniocleophilic Addition أخدنا + +5 +00:00:40,890 --> 00:00:47,150 +عدة أمثلة ع الموضوع إضافة الماء الكحول ال cyanide + +6 +00:00:47,150 --> 00:00:53,200 +مثلا ال H- لعملية ال reductionواليوم هناخد بشكل + +7 +00:00:53,200 --> 00:00:58,440 +أساسي كمان مثلين على هذا الموضوع يعني للناس اللي + +8 +00:00:58,440 --> 00:01:03,180 +بيحبوا الصور الكلية وبيفهموا الموضوع بالصورة + +9 +00:01:03,180 --> 00:01:06,980 +الكلية مش بالصورة الجزائية أو الجزئية خلينا نقول + +10 +00:01:06,980 --> 00:01:13,120 +كأنه كل تفاعلات الكحولات لو بدكم تسجلوها إضافة ما + +11 +00:01:14,130 --> 00:01:21,730 +بحط OH كحول بحط Oethyl أو OR in general فعلا ال + +12 +00:01:21,730 --> 00:01:27,870 +cyanide بحط CN minus ال hydride بحطأتش ماينوس الان + +13 +00:01:27,870 --> 00:01:33,370 +في عندنا اضافتين واحدة من هذول الاضافتين التفاعل + +14 +00:01:33,370 --> 00:01:39,450 +مع green yard reagent واضح عادة هذا المتفاعل يمكن + +15 +00:01:39,450 --> 00:01:43,270 +ماعندكم مش خبرة عنه بنتعرف عليه شو هو green yard + +16 +00:01:43,270 --> 00:01:47,020 +reagentإذا بتلاحظوا reaction of aldehydes and + +17 +00:01:47,020 --> 00:01:51,340 +ketones with Grignard reagent ربما تقرأوا الكلمة + +18 +00:01:51,340 --> 00:01:57,260 +كأنها Grignard لكن عادة احنا بنقولها ايش Grignard + +19 +00:01:57,260 --> 00:02:06,290 +reagent هذا متفاعل اللي عمله لأنه مهم كتيراخد عليه + +20 +00:02:06,290 --> 00:02:13,430 +جائزة نوبل في الكيميا عشانك جربه ممكن تفهمه جيدا و + +21 +00:02:13,430 --> 00:02:19,730 +الكلام مش جديد يعني في ال 1911 تقريبا قبل أكثر من + +22 +00:02:20,620 --> 00:02:25,320 +ميت سنة بتعرف جائزة نوبل بدت من ال 1900 تقريبا + +23 +00:02:25,320 --> 00:02:31,620 +فبال 1911 أخد عليه جائزة نوبل ايش هو ال green yard + +24 +00:02:31,620 --> 00:02:38,120 +reagent بالظبط الان لو أخدنا احنا اي مركب متصل + +25 +00:02:38,120 --> 00:02:45,980 +بهالوجل RX او ARX بتحبوا تاخدوهم بالصيغة العامة + +26 +00:02:45,980 --> 00:02:54,100 +بمشي الحال يعني بقول RX اوARX بتحبوا تاخدوهم بمثال + +27 +00:02:54,100 --> 00:03:00,600 +بيمشي الحال برضه يعني مثلا نقول CH3CH2CL + +28 +00:03:00,600 --> 00:03:06,580 +هايه بمثال واضح CH3CH2PR + +29 +00:03:06,580 --> 00:03:13,120 +هذا RX ولا لأ؟ RX ولو بدي انا ARX مثلا اخد فنل + +30 +00:03:13,120 --> 00:03:24,730 +بنزينة فنل PR او فنل CLالان لو اخدنا RX او ARX + +31 +00:03:24,730 --> 00:03:29,590 +وفعلناهم مع بودرة المغنيسيوم في ظروف جافة في + +32 +00:03:29,590 --> 00:03:33,810 +solvent ال ether يعني هدولا بنافعلهم مع ايش؟ + +33 +00:03:33,810 --> 00:03:40,970 +مغنيسيوم MG و عادة بستعملوا solvent ether والاصل + +34 +00:03:40,970 --> 00:03:47,370 +يكون dry ether واضح؟ الان هذا بيتفعل بيعطينا الشكل + +35 +00:03:47,370 --> 00:03:59,110 +القاتل بيعطيناCH3 CH2 CH3 + +36 +00:03:59,110 --> 00:03:59,410 +CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH3 CH3 CH3 CH3 + +37 +00:03:59,410 --> 00:04:00,690 +CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 + +38 +00:04:00,690 --> 00:04:02,730 +CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 + +39 +00:04:02,730 --> 00:04:03,130 +CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 + +40 +00:04:03,130 --> 00:04:07,610 +CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 + +41 +00:04:07,610 --> 00:04:11,670 +CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 + +42 +00:04:11,670 --> 00:04:16,080 +CH3 CH3greenyard reagent الان لو كنت بدى اسميه + +43 +00:04:16,080 --> 00:04:20,860 +بمشي فيه من الشمال لليمين هذه المجموعة شو هي ايه + +44 +00:04:20,860 --> 00:04:29,040 +فين ماجنيسيوم برومايو هذا فنل ماجنيسيوم برومايو + +45 +00:04:29,040 --> 00:04:35,000 +ومثلها مثيل وبروبيل وايزوبروبيل وهكذا هذا هو ال + +46 +00:04:35,000 --> 00:04:39,320 +greenyard reagent عرفنا بالظبط شو هو الان هذا ال + +47 +00:04:39,320 --> 00:04:45,030 +greenyard reagentماذا هو الفائدة التي جعل الناس + +48 +00:04:45,030 --> 00:04:52,270 +يعطوه جائزة نوبل في الكيميا للعالم هذا؟ ال + +49 +00:04:52,270 --> 00:04:57,070 +greenery agent هو عبارة عن carbon nucleophile يعني + +50 +00:04:57,070 --> 00:05:02,450 +انا لما بدي اتعامل معه بدي اخده بهذا الشكل أنسى ال + +51 +00:05:02,450 --> 00:05:03,230 +MgBr + +52 +00:05:05,600 --> 00:05:09,900 +بدي أخده بهذا الشكل الان هو بهذا الشكل صار بيمثل + +53 +00:05:09,900 --> 00:05:17,120 +لي CH3 CH2 وزوج إلكترونات على الكاربون فهو carbon + +54 +00:05:17,120 --> 00:05:22,140 +nucleophile أو أخده بهذا الشكليعني هو صح موجود + +55 +00:05:22,140 --> 00:05:26,820 +كمركب لكن في لحظة التفاعل يعني تخيلوا بالظبط a + +56 +00:05:26,820 --> 00:05:31,400 +green yard reagent كأنه هذا القلم الآن هذا الجزء + +57 +00:05:31,400 --> 00:05:35,360 +اللي فيه ال nucleophile هو اللي بيجي يتفاعل و يعمل + +58 +00:05:35,360 --> 00:05:41,160 +addition و ال MgBr ما انه ملها واضح؟فكأنه يمثل هذا + +59 +00:05:41,160 --> 00:05:43,900 +القلم مع الغطاية، الان انا مهتم بالغطاية ولا + +60 +00:05:43,900 --> 00:05:48,020 +بالقلم؟ الان انا من ال green yardary agent بإيش + +61 +00:05:48,020 --> 00:05:53,820 +مهتم؟ بال R مع إلكتروناتها أو بال AR مع + +62 +00:05:53,820 --> 00:05:59,420 +إلكتروناتهاواضحة الفكرة؟ الان لما بدي اجي اقول ان + +63 +00:05:59,420 --> 00:06:05,240 +هذا ال R مع إلكتروناتها او ال AR مع إلكتروناتها + +64 +00:06:05,240 --> 00:06:08,960 +بدها تيجي تتفاعل مع الديهيد او الكيتون هي أصبحت + +65 +00:06:08,960 --> 00:06:14,800 +نيوكليوفاين الان كيف بتيجي و اين بتيجي تهاجم؟ هاي + +66 +00:06:14,800 --> 00:06:22,590 +ال R بدها تهاجم هنا وهذه ايش بدها تصير؟OH في + +67 +00:06:22,590 --> 00:06:26,770 +النهاية طبعا هو هنا كتبلكوا التفاعل بالتفصيل ان + +68 +00:06:26,770 --> 00:06:31,290 +اول ما بتهاجم هنا بتصير OMGPR بعدين بنضيف عليه + +69 +00:06:31,290 --> 00:06:35,990 +نقطة ميه و حامض فبتصفى OH الان هي نتيجة نهائية + +70 +00:06:35,990 --> 00:06:40,130 +يعني هذه الشغل تفصيل جوا التفاعل احنا مش مهتمين + +71 +00:06:40,130 --> 00:06:43,410 +فيها بدنا في النهاية نتيجة نهائية متذكرين المرة + +72 +00:06:43,410 --> 00:06:48,810 +الماضية لما كنا نقولكم كل CW bond O ايش بتصير وكنا + +73 +00:06:48,810 --> 00:06:56,310 +نحطها بمربع أخضرو النيوكليوفايل بيهاجم هاي + +74 +00:06:56,310 --> 00:07:01,330 +نيوكليوفايل و السيطة بالبنط O صارت OH الآن ال R و + +75 +00:07:01,330 --> 00:07:08,210 +ال R' ما تدخلوش احنا كل اللي عملناه الحقيقة في + +76 +00:07:08,210 --> 00:07:11,930 +التفاعلات كل اللي عملناه في التفاعلات تبع ال + +77 +00:07:11,930 --> 00:07:16,690 +aldehydes و ال ketones هو فقط تغيير اللي هان يعني + +78 +00:07:16,690 --> 00:07:20,310 +كل اللي درسنا قولنا لما تكون هذه مياه بده يكون هنا + +79 +00:07:22,430 --> 00:07:27,930 +OH لما يكون كحول OR لما يكون cyanide CN لما يكون + +80 +00:07:27,930 --> 00:07:32,970 +hydride H الان لما يكون green yard R + +81 +00:07:36,320 --> 00:07:40,660 +وبعد شوية هنجيب نيتروجين نيوكليوفايل يتحد هنا + +82 +00:07:40,660 --> 00:07:45,980 +بنكون خلصنا الشطر الألديهيد والكيتونز فكل شغلنا + +83 +00:07:45,980 --> 00:07:52,340 +الحقيقة هو عبارة عن أمثلة لنفس التفاعل أمثلة لنفس + +84 +00:07:52,340 --> 00:07:56,820 +التفاعل فقط تغيير النيوكليوفايل في كل الأحوال عندي + +85 +00:07:56,820 --> 00:08:00,500 +addition و ال C double bond O بتصير OH هذا عام + +86 +00:08:00,500 --> 00:08:05,030 +مشترك لكن النيوكليوفايل مارا يكون كذا كذا كذااليوم + +87 +00:08:05,030 --> 00:08:09,050 +ايش لنيو كليو فايل تبعنا ل green yard ray agent + +88 +00:08:09,050 --> 00:08:15,630 +اللي هو R مع إلكتروناتها او AR مع إلكتروناتها و + +89 +00:08:15,630 --> 00:08:19,850 +عرفنا كيف بتحضر يعني لو كنا بديني ب RX كتبنا مع ال + +90 +00:08:19,850 --> 00:08:25,790 +MG بنكتب RMGX بعدين لما بنفعله ايش بناخد منه بس ال + +91 +00:08:25,790 --> 00:08:34,190 +R ال RMGX مش موضوعنا الآن هذا التفاعل حقيقةمهم + +92 +00:08:34,190 --> 00:08:40,270 +كتير ليش؟ خلّينا نجرب نفس الـgreenyard reagent على + +93 +00:08:40,270 --> 00:08:44,770 +أنواع مختلفة من الالديهيدس والكيتونز نقول + +94 +00:08:44,770 --> 00:08:48,410 +الـgreenyard reagent تبعنا إثل الـRGBR يعني إثل + +95 +00:08:48,410 --> 00:08:52,430 +مجليسيامبروميدل الآن هذا إيش هيحُك اليوكليوفاين؟ + +96 +00:08:53,400 --> 00:08:59,020 +مجموعة ال aethyl لو فعلنا مع ال formaldehyde اللي + +97 +00:08:59,020 --> 00:09:05,580 +هو أبسط ال dehyde هذه بدها تصير OH و بده يحط عندها + +98 +00:09:05,580 --> 00:09:13,060 +مجموعة ال aethyl هاي مجموعة ال aethyl شايفينها و + +99 +00:09:13,060 --> 00:09:20,200 +هنا CH2 OH هذه ثابتةواضح؟ إذا هو حط مجموعة الـ + +100 +00:09:20,200 --> 00:09:22,660 +ethylene لاحظوا الآن ال green yard مع ال + +101 +00:09:22,660 --> 00:09:28,120 +formaldehyde كوالي كحول إيش نوع هذا الكحول؟ + +102 +00:09:28,120 --> 00:09:32,880 +primary alcohol طيب خليني أفعل ال green yard مع أي + +103 +00:09:32,880 --> 00:09:40,060 +aldehyde تاني غير ال formaldehyde يعني + +104 +00:09:40,060 --> 00:09:44,360 +acetaldehyde هذا, ibropenaldehyde, benzaldehyde + +105 +00:09:44,360 --> 00:09:51,840 +طبعا هيحط برضه مجموعةالإثل وهي جزء ال الديهايد + +106 +00:09:51,840 --> 00:09:56,320 +كانت كاربون متصل فيها H وCH3 وصارت OH الآن إيش + +107 +00:09:56,320 --> 00:10:02,760 +كوّل لها سكندري الكحول طب خلّيه يتفاعل مع ال كيتون + +108 +00:10:02,760 --> 00:10:10,200 +مع هذا الاسيتون شو هيحط مجموعة ال إثل تيرتشاري + +109 +00:10:10,200 --> 00:10:17,710 +الكحول واضح؟إذن الآن صرنا فاهمين ليش greenery + +110 +00:10:17,710 --> 00:10:21,810 +agent موضوع مهم لأن هو بالنسبة لنا بيمثل طريقة + +111 +00:10:21,810 --> 00:10:26,910 +لتحضير كل أنواع الكحولات يعني لو بدى primary + +112 +00:10:26,910 --> 00:10:32,610 +alcohol بدى أنطلق من ال formaldehyde تمام؟ لو بدى + +113 +00:10:32,610 --> 00:10:39,150 +secondary alcohol بدى أنطلق من أي aldehyde تاني + +114 +00:10:39,150 --> 00:10:44,410 +غيرغير ال formaldehyde لأن ال formaldehyde بيعطي + +115 +00:10:44,410 --> 00:10:47,710 +ال alcohol برايمر كل ال aldehydes التانية بيعطيه + +116 +00:10:48,170 --> 00:10:53,850 +secondary لو بدى tertiary alcohol بدى كيت بيعطينى + +117 +00:10:53,850 --> 00:10:58,830 +بدى اتفاعل مع او بدى تم التفاعل مع الكيتون وبناء + +118 +00:10:58,830 --> 00:11:03,810 +على ذلك لو قلنالكوا اكمل المعادلة او مثلا كيف تحضر + +119 +00:11:03,810 --> 00:11:10,910 +كحول معين كيف بدى يكون الجواب تبعنا باستعمال طريقة + +120 +00:11:10,910 --> 00:11:15,710 +ingredient باستعمال طريقة ingredient خلينا ناخد + +121 +00:11:17,360 --> 00:11:23,800 +مثال او اكتر على هذا الموضوع حتى انرسخ هذا الكلام + +122 +00:11:23,800 --> 00:11:32,360 +يعني لو اجينا سألناكم عندكم هذا الكحول فينيل CH2OH + +123 +00:11:32,360 --> 00:11:39,860 +how can you prepare this alcohol فكرولي ان انتوا + +124 +00:11:39,860 --> 00:11:44,080 +بتكونوا تحضروا هذا الكحول بطريقة السيد الجرين يعني + +125 +00:11:45,470 --> 00:11:51,690 +ماشي اللي هنقوله ايش + +126 +00:11:51,690 --> 00:12:00,310 +نوع هذا الكحول ال primary اذا انا لازمني ال CH2 و + +127 +00:12:00,310 --> 00:12:04,990 +ال double bond all formaldehyde و بدي افعله مع اي + +128 +00:12:04,990 --> 00:12:11,970 +green yardary agent مع فنل MgBr + +129 +00:12:14,230 --> 00:12:17,290 +فنل مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر + +130 +00:12:17,290 --> 00:12:19,310 +مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر + +131 +00:12:19,310 --> 00:12:20,190 +مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر + +132 +00:12:20,190 --> 00:12:25,610 +مجدر مجدر مجدر + +133 +00:12:25,610 --> 00:12:26,890 +مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر + +134 +00:12:26,890 --> 00:12:32,990 +مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر + +135 +00:12:32,990 --> 00:12:35,270 +مجدر + +136 +00:12:43,630 --> 00:12:49,690 +وكان السؤال بالشكل القاتى how can you prepare this + +137 +00:12:49,690 --> 00:12:57,390 +alcohol from two different compounds يعني بده يعمل + +138 +00:12:57,390 --> 00:13:01,010 +مركبين والمركبين معروفين جيدا بالنسبة إلينا كيف + +139 +00:13:01,010 --> 00:13:05,930 +بنحضر هذا الكحول من مركبين مختلفين two different + +140 +00:13:05,930 --> 00:13:12,390 +ketones الان + +141 +00:13:13,490 --> 00:13:17,790 +وحدة قالت ممكن نستعمل هذا ال C double bond O حاملة + +142 +00:13:17,790 --> 00:13:24,550 +تنتهي CH3 وحدة حاملة CH3 وحدة فنل C double bond O + +143 +00:13:24,550 --> 00:13:33,870 +CH3 و هذه فنل هذا المركب شو اسمه؟ خلينا في اللي + +144 +00:13:33,870 --> 00:13:34,630 +بنعرفه + +145 +00:13:37,180 --> 00:13:42,240 +اسيتون اسيتون ماحد بيقول عنه provenone واضح؟ + +146 +00:13:42,240 --> 00:13:47,860 +اسيتون و هذا يلا + +147 +00:13:47,860 --> 00:13:53,600 +بتحكوا بعد يومين فين ال C-double bond OCH3؟ + +148 +00:13:53,600 --> 00:13:58,740 +أسيتوفينونأبشر بطولى سلامة اليوم الرابعه + +149 +00:13:58,740 --> 00:14:05,060 +أسيتوفينون إذا هذا أسيتون هذا أسيتوفينون الآن + +150 +00:14:05,060 --> 00:14:09,500 +هدولة لما أنا بدي أفعلهم هذه إيش ناقصها مجموعة إيش + +151 +00:14:09,500 --> 00:14:19,380 +إذا هاخد فين ال .. MgBr MgBr و هذه إيش ناقصها هاخد + +152 +00:14:19,380 --> 00:14:24,600 +CH3 MgBr + +153 +00:14:27,780 --> 00:14:32,200 +واضح؟ مجمعتين بدهم يكونوا على الكيتون والتالتة بدي + +154 +00:14:32,200 --> 00:14:35,580 +اجيبها من ال green yard و اعملوا اي خلطة انتوا + +155 +00:14:35,580 --> 00:14:42,930 +بتكونوا معاها واضحة في هذه النقطة؟إذا مش صعب ان + +156 +00:14:42,930 --> 00:14:47,610 +نحضر primary او secondary او tertiary alcohol قطعة + +157 +00:14:47,610 --> 00:14:51,670 +من القطع هنجيبها من وين؟ من ال grill yard و الباقي + +158 +00:14:51,670 --> 00:14:57,730 +بيكون جزء ال aldehyde او ال ketone اللي هيكون + +159 +00:14:57,730 --> 00:14:59,830 +موجود عندنا و نبدأ فيه + +160 +00:15:09,860 --> 00:15:14,140 +الان بنجي لنقطة جديدة لكن مرت علينا مش هناخد فيها + +161 +00:15:14,140 --> 00:15:18,580 +كتير Oxidation of aldehydes and ketones مر علينا + +162 +00:15:18,580 --> 00:15:23,500 +احنا ان ال primary alcohol كانت تتأكسد لايش + +163 +00:15:23,500 --> 00:15:26,760 +لالدهيد + +164 +00:15:26,760 --> 00:15:30,620 +و اذا استعملنا عامل مؤكسد قوي الالدهيد شو بيصير؟ + +165 +00:15:30,620 --> 00:15:34,980 +acid خلاص اذا الجزء اللى بدنا يهو ال الديهيد كان + +166 +00:15:34,980 --> 00:15:40,260 +بي oxidizeto acids مرت علينا في جزء ال alcohol ولا + +167 +00:15:40,260 --> 00:15:44,230 +لأ؟أه كنا نقول الكحول بيصير ال الديهيد و ال + +168 +00:15:44,230 --> 00:15:48,050 +الديهيد أسد ال الديهيد أسد هو تفاعل لل الديهيد و + +169 +00:15:48,050 --> 00:15:51,610 +الكيتون صارنا عارفينه طيب ال secondary alcohol + +170 +00:15:51,610 --> 00:15:56,510 +كانوا يتأكسدوا لإيش لكيتون ال كيتون بتتأكسد أكسدة + +171 +00:15:56,510 --> 00:16:00,970 +إضافية لأ إذا هاي الموضوع أكسدت ال الديهيد و + +172 +00:16:00,970 --> 00:16:05,130 +الكيتون ان ال الديهيد بيصيروا أسد و الكيتون + +173 +00:16:05,130 --> 00:16:11,700 +بتأكسدوش خلصناواضح؟ وكل هذه الفكرة مرت علينا في أي + +174 +00:16:11,700 --> 00:16:18,260 +منطقة؟ في منطقة الكحولات كل هذه الفكرة مرت علينا + +175 +00:16:18,260 --> 00:16:21,080 +في منطقة الكحولات ليش؟ لأننا كنا نقول primary + +176 +00:16:21,080 --> 00:16:25,980 +alcohol، aldehyde acid secondary alcohol، ketone، + +177 +00:16:25,980 --> 00:16:31,140 +stop tertiary alcohol من الأساس مافيش أكسة ده، + +178 +00:16:31,140 --> 00:16:37,560 +واضح؟الان بنجي الى التفاعل الأخير لل ال الديهايتز + +179 +00:16:37,560 --> 00:16:43,200 +والكيتونز اللى هو التفاعل مع مركبات ال نيتروجين مع + +180 +00:16:43,200 --> 00:16:48,120 +ال نيتروجين ال يوكليوفايلز طبعا أشهر المركبات اللى + +181 +00:16:48,120 --> 00:16:54,760 +هتمر علينا غير الأمونيا الامونيا NH3 تمام؟ الان + +182 +00:16:54,760 --> 00:16:58,940 +انا لو أخدت من الأمونيا derivative لو أخدت من + +183 +00:16:58,940 --> 00:17:04,990 +الأمونيا derivative هخلى NH2و محل ال H التالتة احط + +184 +00:17:04,990 --> 00:17:09,350 +اشي معين خليني اسمي X يعني تطلعوا هذه احدى مشتقات + +185 +00:17:09,350 --> 00:17:16,030 +الأمونيا NH2 متصلة بإيش؟ ب X في الأمونيا ال X إيش + +186 +00:17:16,030 --> 00:17:23,510 +بتكون؟ Hydrogen الان ممكن ال X تكون مثل إثل ممكن + +187 +00:17:23,510 --> 00:17:29,270 +تكون NH2 تانية ممكن تكون R ممكن تكون OH ممكن تكون + +188 +00:17:29,270 --> 00:17:36,430 +ARاعتبروها X وكل اشي فيها ال X ممكن بيصير التفاعل + +189 +00:17:36,430 --> 00:17:40,830 +تبعنا للناس اللي بدهم يفهموه يقولوا ال X بتضلها + +190 +00:17:40,830 --> 00:17:46,970 +إيش؟ X مالنا و مالها كيف ال N H2 بتتفاعل مع ال C + +191 +00:17:46,970 --> 00:17:54,610 +double bond O واضح الكلام؟ كيف ال N H2 بتتفاعل مع + +192 +00:17:54,610 --> 00:18:00,470 +ال C double bond O الآن ال nitrogen هذاIn UQ5 + +193 +00:18:00,470 --> 00:18:05,670 +بيحمل زوج إلكترونات وبناء على ذلك لما بنفعله مع C + +194 +00:18:05,670 --> 00:18:09,770 +double bond O بده يهاجم عليها هنا و ال C double + +195 +00:18:09,770 --> 00:18:16,730 +bond O تصير OH فاللي هيتكون عنده حقيقة بنص الطريق + +196 +00:18:16,730 --> 00:18:23,860 +هو المركب القاتل اللي هيكون فيه عنده C Oأتش هنا + +197 +00:18:23,860 --> 00:18:33,840 +إيش موجود عندى OH وهنا خلّينا نقول N H متصلة بال X + +198 +00:18:33,840 --> 00:18:40,660 +وهنا المجموعتين اللى عندى واضح هذا ال N H المتصلة + +199 +00:18:40,660 --> 00:18:45,800 +بال X والمجموعتين اللى عندى واضح ولا لأ ولا أرسمه + +200 +00:18:45,800 --> 00:18:50,440 +بالطريقة اللى أنتم متعودين عليهاهذه الكربون متصل + +201 +00:18:50,440 --> 00:18:58,320 +فيها مجموعتين هذه شو صارت OH وهنا NHX + +202 +00:18:58,320 --> 00:19:06,500 +واضح؟ وهذه كنا نحطها بالأخضر وهذا لليوكليوفايل + +203 +00:19:06,500 --> 00:19:12,160 +اللي تم الهجوم عليه الآن هذا التفاعل شو نوعه؟ + +204 +00:19:13,370 --> 00:19:17,590 +addition reaction هذا تفاعل addition هذا + +205 +00:19:17,590 --> 00:19:24,050 +النيوكليوفايل واضح الفكرة ماجيبناش إش جديد الآن في + +206 +00:19:24,050 --> 00:19:29,330 +حالة ال nitrogen نيوكليوفايل والان H2 بعد ما بتم + +207 +00:19:29,330 --> 00:19:35,610 +هذا ال addition عادة وبشكل تلقائي بتم تفاعل تاني + +208 +00:19:35,970 --> 00:19:38,950 +ولذلك الناتج ما بيقفش عند ال addition يعني لو + +209 +00:19:38,950 --> 00:19:43,430 +الناتج بيقف عند ال addition الأمر بصير بتم تفاعل + +210 +00:19:43,430 --> 00:19:48,390 +تاني تلقائي هذا التفاعل التاني التلقائي في عندكم + +211 +00:19:48,390 --> 00:19:53,590 +هنا OH وفي عندنا هنا جنبها على الذرة المجاورة هدول + +212 +00:19:53,590 --> 00:19:57,890 +ذرتين متجاورتين carbon و nitrogen صح؟ على ال + +213 +00:19:57,890 --> 00:20:04,150 +carbon عندكم OH وعلى ال nitrogen H الآن بتم حذفال + +214 +00:20:04,150 --> 00:20:11,990 +OH مع ال H على شكل جزيء ماء هاي ال OH هذه مع ال H + +215 +00:20:11,990 --> 00:20:14,910 +اللي هنا ع شكل جزيء ماء لما بدوا ينحفوا شو بدوا + +216 +00:20:14,910 --> 00:20:21,430 +يصير مكانهم double bond هاني شلتم شلتم شلتم ايش + +217 +00:20:21,430 --> 00:20:28,990 +بده احط مكانهم double bondواضح؟ إذا بعد ال + +218 +00:20:28,990 --> 00:20:34,170 +addition صار عندي تفاعل elimination وعشان هيك + +219 +00:20:34,170 --> 00:20:38,690 +العنوان اللي عندكم كان إيش addition elimination + +220 +00:20:38,690 --> 00:20:42,510 +reactions of aldehydes and ketones هذه مع أي + +221 +00:20:42,510 --> 00:20:49,330 +مركبات بتصير؟مع الان H2 اللى متصل فيها أي X كانت + +222 +00:20:49,330 --> 00:20:54,930 +الان بيجي السؤال من ناحية السهولة هل يا ترى كل مرة + +223 +00:20:54,930 --> 00:21:00,380 +عشان نكتب الجواب الصحبدنا نقعد نتخيل الحالة + +224 +00:21:00,380 --> 00:21:04,520 +الوسيطة ونقول تمت الإضافة ونرسم الناتج وبعدين بتم + +225 +00:21:04,520 --> 00:21:08,980 +الحدف و تاخدوا خمس دقائق وانتوا تكتبوا الجواب لأ + +226 +00:21:08,980 --> 00:21:13,960 +بإمكاننا من ناحية تطبيقية نعمل الأمر بطريقة سهلة + +227 +00:21:13,960 --> 00:21:19,080 +جداالأمر بطريقة سهلة جدا اللي بيشمل العمليتين انه + +228 +00:21:19,080 --> 00:21:23,600 +دائما تخيلوا C double bond O والان H2 جايين بهذا + +229 +00:21:23,600 --> 00:21:27,980 +الشكل الان خلوها تصير C double bond N لاحظوا ايش + +230 +00:21:27,980 --> 00:21:37,060 +انا حدفت H2O فخلو بدل ما مكتوب عندكم C double bond + +231 +00:21:37,060 --> 00:21:43,480 +O خلوها C double bond N والان متصلة ب Xإذا هذا + +232 +00:21:43,480 --> 00:21:49,020 +التفاعل صار أسهل تفاعل فيهم نتيجته النهائية أنه في + +233 +00:21:49,020 --> 00:21:54,000 +التفاعل مع ال N H2 بدل ما كان عنده C double bond O + +234 +00:21:54,000 --> 00:22:02,360 +بتصير C double bond N واضحة الفكرة و ال N بأي X + +235 +00:22:02,360 --> 00:22:07,580 +متصلة يعتبر موضوع بسيط بس كنتيجة أنه C double bond + +236 +00:22:07,580 --> 00:22:15,640 +O بتصير C double bond Nأبتدت أن نكون كفكرة إلتهينا + +237 +00:22:15,640 --> 00:22:22,020 +من هذه التفاعلات ولكن الآن نريد أن نعرف أسماء + +238 +00:22:22,020 --> 00:22:27,970 +الأشياء التي تتفاعل عادةأو بمعنى آخر خلّينا نقول + +239 +00:22:27,970 --> 00:22:32,710 +نعطي أمثلة على ال X إيش ممكن تكون ال X واضحة + +240 +00:22:32,710 --> 00:22:37,950 +الفكرة؟ إيش ممكن تكون ال X؟ الآن هذه عندي دائما و + +241 +00:22:37,950 --> 00:22:42,270 +أبدا unatched two نتفق ال unatched two نحطها وين؟ + +242 +00:22:44,150 --> 00:22:48,970 +بمربع أخضر هذه اللي فاهمين هي ال N H 2 ال N متصلة + +243 +00:22:48,970 --> 00:22:55,090 +ب X ال X في هذا المثال شو هي N H 2 تانية ال N هذي + +244 +00:22:55,090 --> 00:22:58,950 +ال N H 2 اللي متصلة ب N H 2 تانية المركب بسميه + +245 +00:22:58,950 --> 00:23:06,810 +هيدرازين okay هيدرازين طيب لو ال N H 2 تانية كانت + +246 +00:23:06,810 --> 00:23:14,290 +متصلة ب N H phenyl يعني ال X عبارة عن إيش؟ان اتش + +247 +00:23:14,290 --> 00:23:20,770 +فينيل هذي ال X كلها واضح بيصير اسمه فينيل هيدرازيل + +248 +00:23:22,460 --> 00:23:26,180 +أكيد هدول فيش نقاش انه كل اشي اللي انا بدي احكيه + +249 +00:23:26,180 --> 00:23:32,400 +بده ينحفظ بالظبط فينل هيدرازين طيب هذه ال N-H2 + +250 +00:23:32,400 --> 00:23:37,320 +نفسها لو اتصلت ب N-H حاملة فينل وعالفينل على نمره + +251 +00:23:37,320 --> 00:23:42,120 +واحد اتنين تلاتة اربعة نيترو نايترو شو هنيجي + +252 +00:23:42,120 --> 00:23:51,480 +نسميه؟ two four dinitro فينل هيدرازين واضح؟ + +253 +00:23:53,580 --> 00:23:58,160 +Two for dinitrophin الهيدرازين الان لو جيبنا لأي + +254 +00:23:58,160 --> 00:24:02,760 +واحد من هدول هذا او هذا او هذا كيتون C double bond + +255 +00:24:02,760 --> 00:24:06,480 +O وقلنا بدنا نكمل المعادلة احنا و احنا مغمضين + +256 +00:24:06,480 --> 00:24:12,720 +متعودين ان هال C double bond O تصير C double bond + +257 +00:24:12,720 --> 00:24:18,210 +N خلص الجوابالـ C double bond O بتصير C double + +258 +00:24:18,210 --> 00:24:22,370 +bond N و بنحدث الـ H طوله طيب الآن لما اتكون هذا + +259 +00:24:22,370 --> 00:24:30,250 +المركب عندى هذا نتج من تفاعل الديهيد او كيتون + +260 +00:24:30,250 --> 00:24:39,130 +الديهيد او كيتون يعني انا حاطينهم بصيغة ايش R يعني + +261 +00:24:39,130 --> 00:24:43,470 +ممكن تكون H و H H و مثل مثل و مثل اثل و اثل + +262 +00:24:44,950 --> 00:24:50,250 +أتشوفينيل مثلوفينيل كل احتمالات واردة الان المركب + +263 +00:24:50,250 --> 00:24:53,070 +اللى بيلتج عندى اللى فيه ال c double bond او الان + +264 +00:24:53,070 --> 00:24:57,330 +ايش بدي اسميه بسمي اسم ال الديهايد او ال كيتون + +265 +00:24:57,330 --> 00:25:03,870 +اللى كوّنه و بحط النهاية اسم هذا لكن بدل ما اقول + +266 +00:25:03,870 --> 00:25:09,970 +in بقول on يعني لو كان متفاعل مع NH2 و NH2 بسميه + +267 +00:25:09,970 --> 00:25:13,510 +الديهايد او كيتون هيدرازون + +268 +00:25:14,360 --> 00:25:20,800 +لو مع هذا فينيل هيدرازون لو مع هذا two four + +269 +00:25:20,800 --> 00:25:26,220 +dinitrophenylheidrazone فالنتج مااخد نفس الاسم لكن + +270 +00:25:26,220 --> 00:25:36,360 +بنهاية on بدل نهاية in خلينا الان نشوفه بامثلة + +271 +00:25:36,360 --> 00:25:41,450 +اكتر يعني بدون ال R و ال Rبأمثلة اقصوا بريد جيجا + +272 +00:25:41,450 --> 00:25:45,090 +اقصوا بريد جيجا الأمثلة بتوضح حالها لحالها اقصوا + +273 +00:25:45,090 --> 00:25:49,110 +بريد جيجا ان الله يحبه الصابرين والصابرات كمان + +274 +00:25:49,110 --> 00:25:59,990 +ربنا بيحبهم يعني + +275 +00:25:59,990 --> 00:26:09,310 +لو اجينا هنا حقينا هذه CH3 CH3 هذا المركب شو اسمه + +276 +00:26:12,370 --> 00:26:19,830 +اسيتون وهذا هيدرازين + +277 +00:26:19,830 --> 00:26:27,190 +الان المركب اللي نشأ منهم شو بدي اسميه اسيتون + +278 +00:26:27,190 --> 00:26:35,630 +هيدرازون مش هيدرازين بيصيروا التانين مع بعض اسيتون + +279 +00:26:35,630 --> 00:26:39,510 +هيدرازون + +280 +00:26:40,980 --> 00:26:47,800 +و بناء على ذلك بنقدر نستنتج استنتاج بسيط جدا ان ال + +281 +00:26:47,800 --> 00:26:53,480 +hydrazines بيصيروا hydrazones طب ناخد مثال تاني + +282 +00:26:53,480 --> 00:26:58,960 +خلينا نحط هنا H ونحط هنا phenyl في الناتج ايش + +283 +00:26:58,960 --> 00:27:07,380 +هيكون عندي هنا H و phenylلو قولنا لواحدة سمينا ال + +284 +00:27:07,380 --> 00:27:14,520 +الديهيد او ال كيتون سمي هذا سمي الناتج واضحة + +285 +00:27:14,520 --> 00:27:18,560 +الفكرة؟ اتفضلي ايش هذا بنسميه؟ فينيل C double bond + +286 +00:27:18,560 --> 00:27:23,940 +OH فينيل + +287 +00:27:23,940 --> 00:27:29,200 +C double bond OH ايش اسمه؟ الاسيتوفينون اللي فيه + +288 +00:27:29,200 --> 00:27:30,080 +CH3 + +289 +00:27:42,220 --> 00:27:48,360 +بنزالدهيد بنزالدهيد بنزالدهيد + +290 +00:27:48,360 --> 00:27:56,880 +ممتازة الآن هذا إيش اسمه؟ + +291 +00:27:56,880 --> 00:28:02,180 +أخدناله اسم قبل شوية فنل هيدرازين + +292 +00:28:04,140 --> 00:28:13,040 +فنل هيدرازين فنل هيدرازين الآن الناتج اللي ناتج من + +293 +00:28:13,040 --> 00:28:18,680 +التنين ايش هيكون اسمه بنز الديهيد فنل هيدرازون بنز + +294 +00:28:18,680 --> 00:28:24,920 +الديهيد فنل هيدرازون هاي جزء بنز الديهيد وفنل + +295 +00:28:24,920 --> 00:28:31,840 +هيدرازون بنز الديهيد فنل + +296 +00:28:33,320 --> 00:28:38,180 +هيدرازون بدل ما كان الاسم عندى oen بدو يصير ايش + +297 +00:28:38,180 --> 00:28:42,300 +بنزالديهيدفينالهيدرازون + +298 +00:28:42,300 --> 00:28:45,860 +بنزالديهيدفينالهيدرازون + +299 +00:28:45,860 --> 00:28:47,920 +الان + +300 +00:29:00,620 --> 00:29:06,560 +لو مثلا اجينا وقلنالكوا لو سمحتوا نختبركوا شطرين + +301 +00:29:06,560 --> 00:29:12,280 +ولا لا ارسمولنا Cyclohexanone 2,4 + +302 +00:29:12,280 --> 00:29:22,440 +-dinitrophenylhydrazone هيك ايجاكم Cyclohexanone + +303 +00:29:22,440 --> 00:29:29,520 +2,4-dinitrophenyl + +304 +00:29:33,300 --> 00:29:39,480 +هيدرازون كل هذا اسم بني آدم مؤدب بدنا نور اسمه + +305 +00:29:39,480 --> 00:29:46,380 +السياسة العامة cut and conquer فرق تسد جزقوها ال + +306 +00:29:46,380 --> 00:29:52,100 +Cyclohexanone أصلا + +307 +00:29:52,100 --> 00:29:58,980 +كان زي هيك CWO بس احنا عرفنا بعد العقلة ال CWO إيش + +308 +00:29:58,980 --> 00:30:05,270 +بتصير؟C double bond N هاي حطينا ال N لما نكمل ال 2 + +309 +00:30:05,270 --> 00:30:12,250 +,4-dinitrophenylhydrazone بدنا نحط N H حاملة فنل + +310 +00:30:12,250 --> 00:30:23,190 +وعلى موقع 2 بالفنل N O 2 و N O 2 طبعا اللي بتدرب + +311 +00:30:23,190 --> 00:30:27,710 +عليهم بيتقنهم هاي Cyclohexanone 2,4 + +312 +00:30:27,710 --> 00:30:29,830 +-dinitrophenylhydrazone + +313 +00:30:34,850 --> 00:30:58,890 +واضحة الفكرة طيب + +314 +00:30:58,890 --> 00:31:05,400 +لو كان السؤالعشان تشوفوا العلم مبني على بعضه + +315 +00:31:05,400 --> 00:31:14,440 +ارسموا Cyclohexane Carb Aldehyde Hydrazol خلصنا + +316 +00:31:14,440 --> 00:31:23,540 +من هذا؟ Cyclohexane + +317 +00:31:23,540 --> 00:31:31,800 +Carb Aldehyde Cyclohexane Carb Aldehyde + +318 +00:31:36,170 --> 00:31:41,950 +Hydrazone كلمة واحدة + +319 +00:31:41,950 --> 00:31:47,490 +طبعا اللي بتعرفش ال Cyclohexane لحاله ولو بتعرفش + +320 +00:31:47,490 --> 00:31:51,370 +ال Hydrazone لحاله مش هترسم طبعا هذا Cyclohexane + +321 +00:31:51,370 --> 00:31:55,950 +إيش؟ Carb Aldehyde كلكوا لازم تكونوا متذكرين أنه + +322 +00:31:55,950 --> 00:32:00,410 +إحنا لما حكينا عن ال aldehydes مع الحلقة قلنا ال + +323 +00:32:00,410 --> 00:32:07,610 +aldehyde بيكون معلق تعليج على الحلقةيعني الـ + +324 +00:32:07,610 --> 00:32:11,010 +Cyclohexane كربلديهيد لو قلب لحاله زي هيك وهذه C + +325 +00:32:11,010 --> 00:32:16,750 +double bond O الأن لما تصير Hydrazone هتصير C + +326 +00:32:16,750 --> 00:32:21,530 +double bond N ولما يكون .. بس كلمة Hydrazone لحاله + +327 +00:32:21,530 --> 00:32:27,890 +بدون ولا إشي تاني N H 2 لو كانت فين ال Hydrazone؟ + +328 +00:32:27,890 --> 00:32:33,940 +بدي أحط فين ال .. طب لو قلتلكوا مثل Hydrazoneهتمثل + +329 +00:32:33,940 --> 00:32:39,440 +لو قولت اتل هيدرازون اتل لو قولت أسيتل هيدرازون + +330 +00:32:39,440 --> 00:32:46,480 +أسيتل حد مايعرفش الأسيتل C double bond O CH3 Form + +331 +00:32:46,480 --> 00:32:53,940 +الهيدرازون C double bond O H3 و هكذا واضحة الفكرة + +332 +00:32:53,940 --> 00:33:00,930 +يعني اتعمقنا كتير كتير زيادة في الموضوع الآنطيب + +333 +00:33:00,930 --> 00:33:06,650 +ناخد مشتقة تانية ناخد مشتقة تانية لو يا تورا + +334 +00:33:06,650 --> 00:33:12,430 +ماكانش عندى مع ال N H2 N H2 تانية لو كان عندى O H + +335 +00:33:12,430 --> 00:33:19,710 +لاحظوا هى عندى ال N H2 بس ايش ال X اللى هنا O H + +336 +00:33:19,710 --> 00:33:23,330 +هذا بنسمي Hydroxylamine + +337 +00:33:24,660 --> 00:33:30,340 +ماذا نسميه؟ هيدروكسل أمين هي الهيدروكسل وهي الأمين + +338 +00:33:30,340 --> 00:33:33,420 +لما بده يتفاعل ال C double bond اوه بتحصل في + +339 +00:33:33,420 --> 00:33:39,280 +النهاية C double bond L لما بدنا نسمي المركب بدنا + +340 +00:33:39,280 --> 00:33:45,300 +نقول ال الديهيد او ال كيتون والان + +341 +00:33:45,300 --> 00:33:49,460 +على هذا الجزء بنكتب كلمة واحدة أكزيم + +342 +00:33:51,630 --> 00:33:56,990 +يعني ال c double volt n o h ايش بنسميها اكزيم + +343 +00:33:56,990 --> 00:34:01,850 +اكزيم الان + +344 +00:34:01,850 --> 00:34:12,490 +واحدة + +345 +00:34:12,490 --> 00:34:19,470 +تقول اي جانا هذا في الامتحان رسمه أسيتوفينون اكزيم + +346 +00:34:20,940 --> 00:34:27,060 +اللي بدي يرسم بدي يقول هاي ال Acetophenon فينل و + +347 +00:34:27,060 --> 00:34:34,200 +CH3 و متصل بـ C double bond O أصلا عشان يكون + +348 +00:34:34,200 --> 00:34:41,680 +Acetophenon الأهم لما يصير أكزيم NOH و مثل و + +349 +00:34:41,680 --> 00:34:44,420 +Cyclohexanone أكزيم و Cyclopentanone أكزيم و كل + +350 +00:34:44,420 --> 00:34:51,160 +الأكزيمات إذا العملية سهلة ولا مش سهلةهنا أخدنا + +351 +00:34:51,160 --> 00:35:01,640 +مشتقة الهيدرازون ومشتقة الأكزيم طب + +352 +00:35:01,640 --> 00:35:07,560 +لو كانت هذه R يعني مثل ولا إثل؟ ايش بدي يكون + +353 +00:35:07,560 --> 00:35:13,000 +الجواب؟ R مثل أو إثل كعائلة بيسموها shift base + +354 +00:35:13,000 --> 00:35:20,500 +نتغلب أكتر بالاسماء تبعتها الآن بيضل عندىكل هدولة + +355 +00:35:20,500 --> 00:35:25,040 +موجودين يمكن ضلت عندي شغلة واحدة اخرى لو كانت هذه + +356 +00:35:25,040 --> 00:35:36,420 +unh2 unh c double bond o unh2 هذا مركب شوية ايش + +357 +00:35:36,420 --> 00:35:41,840 +ماله كبير لكن انا المهم عندي فيه ان هذه ال unh2 كل + +358 +00:35:41,840 --> 00:35:46,700 +هدولة يعتبروا x واحدة هتقول في تلتين unh2 في واحدة + +359 +00:35:46,700 --> 00:35:51,420 +هنا اقريبة على c double bond o واحدةبعيدة مين اللي + +360 +00:35:51,420 --> 00:35:55,140 +بتتفعل مع الالدهاد او الـ Ketone؟ هذه البعيدة + +361 +00:35:55,140 --> 00:35:58,060 +وبناء على ذلك لو هذا قلتلكوا فعلومة عن + +362 +00:35:58,060 --> 00:36:05,700 +الـcyclobentanone كيف هنكتب الجواب؟ زي ما اتعودنا + +363 +00:36:05,700 --> 00:36:09,960 +تماما، نحط الـcyclobentane + +364 +00:36:09,960 --> 00:36:17,540 +والسيضة بالبند او تصير سيضة بالبند and ونكمل + +365 +00:36:19,990 --> 00:36:26,670 +MHCW.O NH2 بيصير .. طب إيش اسم هذا و إيش اسم هذا + +366 +00:36:26,670 --> 00:36:37,450 +هذا اسمه سيمي كربازايد سيمي كربازايد طب و الناتج + +367 +00:36:37,450 --> 00:36:43,690 +اللي بتطلع من السيمي كربازايدSemi-carbazone زي + +368 +00:36:43,690 --> 00:36:49,210 +هيدرازين هيدرازون Carbazide Carbazone إذا هذا + +369 +00:36:49,210 --> 00:36:54,610 +المركب كاملا الأن لو بدنا نسميه شو هنسميه؟ + +370 +00:36:54,610 --> 00:37:00,450 +Cyclobentanone + +371 +00:37:00,450 --> 00:37:05,110 +Semi-carbazone + +372 +00:37:07,490 --> 00:37:17,290 +cyclobentanone-semicarbazone هذا + +373 +00:37:17,290 --> 00:37:29,310 +هو + +374 +00:37:29,310 --> 00:37:30,930 +ال slide الأخير + +375 +00:37:34,700 --> 00:37:41,500 +بتلخص لي كل الدارس انه ال amine اللي هو متصل في ال + +376 +00:37:41,500 --> 00:37:47,980 +NH2R بيعطي كعائلة عامة امين ال hydroxylamine بيعطي + +377 +00:37:47,980 --> 00:37:54,160 +oxime ال semi carbazide بيعطي semi carbazone ال + +378 +00:37:54,160 --> 00:38:00,880 +hydrazines بيعطي hydrazones واضح؟ مرة تانية نعيدهم + +379 +00:38:00,880 --> 00:38:08,150 +مع بعض ال hydrazineوالهيدروكس الأمين أكزيم والسمي + +380 +00:38:08,150 --> 00:38:13,650 +كربازايد سيمي كربازون والأمين اللي هي متصلة بR + +381 +00:38:13,650 --> 00:38:22,570 +امين امين بس واضح لو نعطي مثال ولا نقول الله + +382 +00:38:22,570 --> 00:38:27,630 +يعطيكوا العافية بنعطي مثلين بنعطي مثلين و بنخلص + +383 +00:38:27,630 --> 00:38:33,870 +اليوم إجاكم سؤال أرسموا إيثانال أكزيم + +384 +00:38:35,520 --> 00:38:48,140 +وإجانا السؤال ارسمه داي إثل كيتون فين الهيدرازون + +385 +00:38:48,140 --> 00:38:54,420 +يلا + +386 +00:38:54,420 --> 00:39:06,030 +نجلوني إيثانال عارفين الإيثانال؟اللي هو CHCH3 + +387 +00:39:06,030 --> 00:39:11,410 +اللي هو ال Acetaldehyde وهذه كانت C double bond O + +388 +00:39:11,410 --> 00:39:16,310 +ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش + +389 +00:39:16,310 --> 00:39:16,790 +ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش + +390 +00:39:16,790 --> 00:39:16,810 +ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش + +391 +00:39:16,810 --> 00:39:18,510 +ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش + +392 +00:39:18,510 --> 00:39:18,890 +ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش + +393 +00:39:18,890 --> 00:39:26,070 +ان او اتش ان او اتش ان او اتش ان + +394 +00:39:26,070 --> 00:39:30,520 +اهو الـ 3-bentanone هو داي إثل كيتون إيش بده أحط؟ + +395 +00:39:30,520 --> 00:39:35,700 +هاي الـ ketone C double bond O وهي مجموعة إثل وهي + +396 +00:39:35,700 --> 00:39:41,940 +مجموعة إثل مش CH2 CH3 إثل CH2 CH3 إثل داي إثل + +397 +00:39:41,940 --> 00:39:48,960 +كيتون الآن بده منه فين + +398 +00:39:48,960 --> 00:39:53,100 +الهيدرازون؟ أكيد هيكون + +399 +00:40:03,390 --> 00:40:07,770 +طبعا أنا بتوقعش ان كل إشي هتكون أتقنطوه لان لكن في + +400 +00:40:07,770 --> 00:40:11,290 +المحاضرة اللي جاية لما تتدربوا و ال organic تدريب + +401 +00:40:11,290 --> 00:40:16,110 +و كتابة أكيد ان شاء الله كل شيء بتتقنوه بهيك + +402 +00:40:16,110 --> 00:40:21,010 +بننتهي من درس ال aldehydes و ال ketones و ان شاء + +403 +00:40:21,010 --> 00:40:27,060 +الله يوم السبتفي عندنا مراجعة للامتحانات النصفية + +404 +00:40:27,060 --> 00:40:31,420 +كونوا مجاهزينها او ساحبينها ع ورق و حلينها احنا + +405 +00:40:31,420 --> 00:40:36,000 +بنحلها انا قدامكم و بنناقش اي مشكلة فيها و بعد هيك + +406 +00:40:36,000 --> 00:40:39,380 +ان شاء الله بنبدأ في موضوع الأحماض و مستقبلها و + +407 +00:40:39,380 --> 00:40:45,260 +الامتحان لنهاية الفصل السادس حكينا بوضوح الامتحان + +408 +00:40:45,260 --> 00:40:47,980 +لنهاية الفصل السادس اذا سمحت + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_postprocess.srt new file mode 100644 index 0000000000000000000000000000000000000000..101df04dcb1cf7e4d752fbab394f7301664d58d4 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_postprocess.srt @@ -0,0 +1,2076 @@ +1 +00:00:20,690 --> 00:00:23,670 +بسم الله الرحمن الرحيم، في موضوع الـ + +2 +00:00:23,670 --> 00:00:27,290 +Stereochemistry، آخر شغلة أتكلمنا عنها + +3 +00:00:30,440 --> 00:00:36,360 +كانت موضوع الخواص الفيزيائية ربما لل enantiomers + +4 +00:00:36,360 --> 00:00:41,000 +وقولنا ان ال enantiomers بيشتركوا في كل الخواص + +5 +00:00:41,000 --> 00:00:47,360 +الفيزيائية ما عدا خاصية ال rotation of polarized + +6 +00:00:47,360 --> 00:00:53,460 +light تدوير الضوء المستخدم في المستوى طبعا شرحنا + +7 +00:00:54,200 --> 00:00:59,300 +بشكل مبسط جهاز ال بولاريميتر وقلنا لو في عندنا two + +8 +00:00:59,300 --> 00:01:03,760 +انان شمارز حاطناهم في مسار الضوء تبع ال بولاريميتر + +9 +00:01:03,760 --> 00:01:09,780 +نفس الكمية واحد هيلف الضوء لليمين هيكون المركب + +10 +00:01:09,780 --> 00:01:14,630 +dextrorotatory أو positive التاني هيلف للشمالعشان + +11 +00:01:14,630 --> 00:01:18,610 +نتخلص من فكرة اننا نضل نقول حطينا نفس الكمية + +12 +00:01:18,610 --> 00:01:23,630 +اعرفنا شئ سمناه الدوران النوعى او ال specific + +13 +00:01:23,630 --> 00:01:27,770 +rotation ال specific rotation بمنطق الخواص بمنطق + +14 +00:01:27,770 --> 00:01:31,890 +الخواص هو عبارة عن intensive probability بمنطق + +15 +00:01:31,890 --> 00:01:34,750 +الخواص هو عبارة عن intensive probability يعني + +16 +00:01:34,750 --> 00:01:40,660 +المركب الواحد لهspecific rotation واحد ولذلك ربما + +17 +00:01:40,660 --> 00:01:46,980 +اعطناكوا homework وقلنا لكم شوفولنا مثلا ال R2 + +18 +00:01:46,980 --> 00:01:53,240 +butanol قداش الزاوية تبعته هذه الزاوية بتكون عبارة + +19 +00:01:53,240 --> 00:01:57,840 +عن شئ تجريبي ماعرفش في ناس جدروا يصلوا لهذه + +20 +00:01:57,840 --> 00:01:58,380 +الزاوية + +21 +00:02:00,890 --> 00:02:10,130 +الان تلتعش وتسعة سالب ولا موجب الان + +22 +00:02:10,130 --> 00:02:15,490 +وضحتلكوا انا لاحظوا يعني بكل وضوح قلتلكم اللي + +23 +00:02:15,490 --> 00:02:21,770 +بيعرف اللي بيعرف زاوية بيعرف التانية يعني اذا انا + +24 +00:02:21,770 --> 00:02:29,220 +كنت معطيكم في الواجبزاوية المُركّب الـR فتحته النت + +25 +00:02:29,220 --> 00:02:35,360 +وجدت الـS-13 وكذا إذا الـR هتكون الـPlus العكس + +26 +00:02:35,360 --> 00:02:42,380 +واضح؟ وانتهى على + +27 +00:02:42,380 --> 00:02:52,800 +أي حال فتش ربما بشكل أداء ليش؟ + +28 +00:02:54,350 --> 00:02:59,050 +معنى ذلك اتقانكوا لعملية البحث .. اتقانكوا لعملية + +29 +00:02:59,050 --> 00:03:03,930 +البحث ضعيف يعني انا بهمني ان انتوا تتعبوا انا + +30 +00:03:03,930 --> 00:03:08,750 +بهمني في النهاية ان انتوا .. ان انتوا تتعبوا يعني + +31 +00:03:08,750 --> 00:03:13,270 +ان اقولكوا specific rotation ل ال tube eutanol و + +32 +00:03:13,270 --> 00:03:19,170 +تقولوا اتغلبنا معنى ذلك ما تقلتوشممكن في عصر + +33 +00:03:19,170 --> 00:03:23,210 +المعلومات ناس مايقدروش يطولوا ل specific rotation + +34 +00:03:23,210 --> 00:03:28,090 +لتو بيوتانول او لتو كلورو بيوتانول هذه معلومة + +35 +00:03:28,090 --> 00:03:32,690 +ثابتة زي ما اجي اقولكم تماما ايش نقطة الغليان ايش + +36 +00:03:32,690 --> 00:03:36,410 +نقطة الانصحار ايش نقطة كده كل هذه المعلومات + +37 +00:03:36,410 --> 00:03:41,970 +معلومات متوفرة وموجودة على ال net مش ممكن الا انكم + +38 +00:03:41,970 --> 00:03:49,720 +تطولوها تمام بكل الأحوال لما اللاجئلأيزومر معين ل + +39 +00:03:49,720 --> 00:03:53,920 +specific rotation كأنه انا عندى لأيزومر التانى + +40 +00:03:53,920 --> 00:03:58,760 +مباشرة يعني لما يكون واحد موجب بمقدار معين التانى + +41 +00:03:58,760 --> 00:04:05,060 +بيكون سالب بنفس المقدار الان لاحظوا معايا لو حطينا + +42 +00:04:05,060 --> 00:04:10,150 +المركب الموجبأو أحد ال enantiomers في البولاريميتر + +43 +00:04:10,150 --> 00:04:15,350 +بلوف ايش؟ الضوء هذا الجزء اللي بلوف الضوء الآن + +44 +00:04:15,350 --> 00:04:21,830 +بنقول عنه مصطلح chiral molecule هنا كنت بنتبه ان + +45 +00:04:21,830 --> 00:04:26,970 +انا استعمل كلمة chiral مرتين مرة لما انا حكيت عن + +46 +00:04:26,970 --> 00:04:31,330 +chiral carbonالكايرال كاربون هي الكاربون اللي + +47 +00:04:31,330 --> 00:04:36,170 +عليها أربع مجموعات مختلفة لما بحكي عن كايرال + +48 +00:04:36,170 --> 00:04:41,230 +موليكيول الكايرال موليكيول هو الجزير اللي بيعمل + +49 +00:04:41,230 --> 00:04:45,750 +دوران للضوء إذا هو أحد ال enantiomersلما بيوجد + +50 +00:04:45,750 --> 00:04:50,890 +لحاله نحط احنا احد المركبات في مسار الضوء يعمل + +51 +00:04:50,890 --> 00:04:55,530 +دوران للضوء بنقول هذا المركب كايرال موليكيول + +52 +00:04:55,530 --> 00:04:58,750 +فالكايرال موليكيول هو اللي بيعمل دوران للضوء الآن + +53 +00:04:58,750 --> 00:05:02,370 +طالما انه دخل الضوء فيه وعمله دوران بنقول عنه + +54 +00:05:02,370 --> 00:05:06,610 +optically active يعني بدل ما نستعمل مصطلح بيعمل + +55 +00:05:06,610 --> 00:05:10,390 +دوران للضوء بنقول optically active فمعنى كلمة + +56 +00:05:10,390 --> 00:05:19,400 +optically active it rotateslight هو بيلف ايش؟ بيلف + +57 +00:05:19,400 --> 00:05:23,320 +في الضوء سواء لف الضوء شمال او لف الضوء يمين هو + +58 +00:05:23,320 --> 00:05:27,020 +بيكون ايش؟ optically active لاحظوا معي ايش + +59 +00:05:27,020 --> 00:05:31,700 +المركبات اللي بتكون optically inactive المركبات + +60 +00:05:31,700 --> 00:05:35,720 +اللي مافيش فيها كل هذه الظاهرة مابديش انا انسى ان + +61 +00:05:35,720 --> 00:05:38,980 +بداية ظاهرة ال enantiomers كانت بتتطلب كايرال + +62 +00:05:38,980 --> 00:05:44,880 +كاربونعشان يصير من المركب اتنين ROS و بعدين واحد + +63 +00:05:44,880 --> 00:05:49,040 +منهم موجب واحد سالب كان بتطلب كيرال كاربون طب لو + +64 +00:05:49,040 --> 00:05:52,980 +انا حاطيت مركب زي على سبيل المثال ال carbon + +65 +00:05:52,980 --> 00:05:54,040 +tetrachloride + +66 +00:05:56,090 --> 00:06:01,350 +هل هذا يا ترى باربع ذرات متشابهة في كايرال كاربون؟ + +67 +00:06:01,350 --> 00:06:05,850 +في منه اتنين؟ مافيش منه غير واحد، اذا هذا لو انا + +68 +00:06:05,850 --> 00:06:09,350 +حاطيته بمسار الضوء، بيكون optically active ولا + +69 +00:06:09,350 --> 00:06:14,170 +inactive؟ inactive، لو انا حاطيت ميه في مسار الضوء + +70 +00:06:15,320 --> 00:06:19,260 +بكون Optically Active ولا Inactive؟ Inactive لو + +71 +00:06:19,260 --> 00:06:25,280 +انا حطيت مثلا Dichloromethane CH2 Cl2 بكون + +72 +00:06:25,280 --> 00:06:29,960 +Optically Active ولا Inactive؟ Inactive لأنه عشان + +73 +00:06:29,960 --> 00:06:33,920 +يبدأ يصير أحد ال enantiomers في وجود chiral center + +74 +00:06:33,920 --> 00:06:37,960 +واحد المفروض يكون عندى أربع مجموعات مختلفة فخلينا + +75 +00:06:37,960 --> 00:06:43,840 +نقول انه نسبة كبيرة جدا من المراكبات العضوية أساسا + +76 +00:06:44,940 --> 00:06:50,300 +بتكون A chiral لاحظوا معاه هنا بنيجي لنقطة كتير + +77 +00:06:50,300 --> 00:06:55,220 +مهمة لما وصفنا مركب انه chiral بمعنى هو أحد + +78 +00:06:56,430 --> 00:07:01,010 +الإنانشومارز يعني كلمة chiral بتكون لما بيكون عندى + +79 +00:07:01,010 --> 00:07:05,730 +two enanchomars هذا المركب لو حاطيته لحاله بقول + +80 +00:07:05,730 --> 00:07:10,650 +عنه chiral بلف الضوء بزاوية معينة الآن ال + +81 +00:07:10,650 --> 00:07:14,530 +enanchomar التاني لو حاطيته في ال polarimeter برضه + +82 +00:07:14,530 --> 00:07:20,900 +chiral بنسميه بلف الضوء ولكن باتجاهمعاكس إذا صار + +83 +00:07:20,900 --> 00:07:24,840 +عندى مركب chiral و مركب chiral طيب لو حطيت مركب من + +84 +00:07:24,840 --> 00:07:28,660 +الأساس مافيه chiral center بلفش الضوء وجدت إيش بدى + +85 +00:07:28,660 --> 00:07:34,840 +أسمي هذا المركب A chiral هنا ال A بتصير أداة نفي + +86 +00:07:34,840 --> 00:07:38,840 +لاحظوا معناه .. لاحظوا معناه بتكونوا فاهمين شوية + +87 +00:07:38,840 --> 00:07:44,420 +باللغة الإنجليزية أدوات النكرة و أدوات المعرفة + +88 +00:07:44,420 --> 00:07:50,840 +يعني المركب هنا .. المركب هناكايرال ال a اللي + +89 +00:07:50,840 --> 00:07:56,260 +موجودة فيه هي أداة نكرة ولذلك إذا أنا مثلا بدي أجي + +90 +00:07:56,260 --> 00:08:00,340 +أحكي باللغة الإنقليزية أقول this is a chiral + +91 +00:08:00,340 --> 00:08:05,900 +compound معناه ذلك هذا مركب بلف الضوء ال a أداة + +92 +00:08:05,900 --> 00:08:09,880 +نكرة زي ما بنيجي نقول this is a table this is a + +93 +00:08:09,880 --> 00:08:14,220 +pen واضح الفكرة؟ الآن لو كنت بدي أحكي عن مركب زي + +94 +00:08:14,220 --> 00:08:20,470 +هذا شو بدي أقول عنه؟أكايرل، الآن هنا أكايرل كلمة + +95 +00:08:20,470 --> 00:08:24,470 +واحدة لما بدي استعمل إلها أذات نكرة بالإنقليزي بدي + +96 +00:08:24,470 --> 00:08:31,670 +أحفظ قدامها أن صارت هذه الكلمة كلمة واحدة أكايرل + +97 +00:08:32,460 --> 00:08:35,220 +فالكلمة اللى عندى للمركب اللى بيكون optically + +98 +00:08:35,220 --> 00:08:40,180 +active كايران ال optically inactive أكايرة الكلمة + +99 +00:08:40,180 --> 00:08:43,580 +واحدة الآن حسب قواعد اللغة الإنجليزية ان هنا بتدخل + +100 +00:08:43,580 --> 00:08:49,040 +أداة ناكرة ال a و هنا بتدخل أداة ناكرة ال m فإذا + +101 +00:08:49,040 --> 00:08:53,180 +كنتوا بتسمعوا أو بتقرؤوا بتكونوا منتبهين لهذا + +102 +00:08:53,180 --> 00:09:00,100 +الكلام ال m طيب يا تورا لو أنا حطيتمن ال two + +103 +00:09:00,100 --> 00:09:05,500 +enantiomers خليط متساوي يعني جبت كمية من ال + +104 +00:09:05,500 --> 00:09:08,700 +enantiomer الأول و كمية من ال enantiomer التاني و + +105 +00:09:08,700 --> 00:09:12,300 +حطيتهم مع بعض في ال polarimeter عملت منهم mixture + +106 +00:09:12,300 --> 00:09:18,120 +هذا الخليط المتساوي بيسموه racemic mixture فمعنى + +107 +00:09:18,120 --> 00:09:22,180 +racemic mixture او racemic modification هو خليط + +108 +00:09:22,180 --> 00:09:26,400 +متساوي من ال two enantiomers هل يا ترى هذا الخليط + +109 +00:09:26,400 --> 00:09:30,580 +المتساويبكون optically active ولا optically + +110 +00:09:30,580 --> 00:09:37,700 +inactive؟ optically inactive، ليش؟ لأن واحد بيلف + +111 +00:09:37,700 --> 00:09:41,880 +الضوء يمين، التاني بيلف الضوء شمال، المحص لزفر + +112 +00:09:43,230 --> 00:09:48,550 +واضح؟ زي تماما ما بنيجي بنقول واحد بيبني واحد + +113 +00:09:48,550 --> 00:09:54,410 +بيهدم ايش في نهاية المحصلة؟ صفر متى يبلغ البنيانو؟ + +114 +00:09:54,410 --> 00:10:00,630 +تماما هو أنت تبني وغيرك يهدم واضح الفكرة؟ ولذلك + +115 +00:10:00,630 --> 00:10:04,650 +إذا كان عندى خليط متساوي .. إذا كان عندى خليط + +116 +00:10:04,650 --> 00:10:11,560 +متساوي من ال two enansomers بتكون إيش؟الخليط + +117 +00:10:11,560 --> 00:10:16,780 +chiral ولا achiral كله optically active ولا + +118 +00:10:16,780 --> 00:10:20,480 +optically inactive؟ optically inactive طبعا هنا + +119 +00:10:20,480 --> 00:10:26,740 +ممكن يجيني السؤال طب يا تورا لو كان عندي خليط بنسب + +120 +00:10:26,740 --> 00:10:28,300 +غير متساوية + +121 +00:10:30,330 --> 00:10:36,830 +يعني مثلا خلطت من ال isomer الموجب نسبة 70% من ال + +122 +00:10:36,830 --> 00:10:42,110 +isomer السالب نسبة 30% هذا الخليط + +123 +00:10:44,420 --> 00:10:50,400 +هيكون optically active هذا الخليط هيكون optically + +124 +00:10:50,400 --> 00:10:57,780 +active ولكن بشكل ايش؟ جزئي بشكل جزئي تماما زي ما + +125 +00:10:57,780 --> 00:11:01,460 +بنيجي نقول مثلا بني ادم الله ربح سبعين كذا خسر + +126 +00:11:01,460 --> 00:11:07,660 +تلاتين كدهش في النهاية؟المربح 40 ولذلك هنا نسبة + +127 +00:11:07,660 --> 00:11:13,120 +الزيادة 40% موجب بنضربها في الزاوية الأصلية يعني + +128 +00:11:13,120 --> 00:11:18,780 +لو افترضت مثلا المركب النقي زاويته 20 هذه العشرين + +129 +00:11:18,780 --> 00:11:24,300 +للمركب الاش النقي لو وضعته زي ما هو وضعت أحد + +130 +00:11:24,300 --> 00:11:28,980 +الانانشومارز زاويته زائد عشرين الانانشومارز التاني + +131 +00:11:28,980 --> 00:11:34,690 +وضعته زاويتهنقص عشرين طب لو عملت خليط من التنين + +132 +00:11:34,690 --> 00:11:38,430 +سبعين في المية موجب تلاتين في المية سالب هذا + +133 +00:11:38,430 --> 00:11:44,120 +الخليط كده هتكون الزاوية تبعته؟لاحظوا انا في عندي + +134 +00:11:44,120 --> 00:11:49,360 +فرق اربعين في المية موجب هقول اربعين على مية ضرب + +135 +00:11:49,360 --> 00:11:53,360 +العشرين فالزاوية هتكون اقل من عشرين بالتأكيد + +136 +00:11:53,360 --> 00:11:59,540 +العشرين لأ النقي تماما لان انا عندي جزء من هذا جزء + +137 +00:11:59,540 --> 00:12:02,700 +اربعين في المية بس موجب فالاربعين في المية من + +138 +00:12:02,700 --> 00:12:09,990 +العشرين كده هتطلع نضربها تمانيةفهذا الخليط زاوية و + +139 +00:12:09,990 --> 00:12:14,570 +هتكون تمانية الان موجب ولا سالب؟ بالتأكيد هتتبع + +140 +00:12:14,570 --> 00:12:18,170 +الأعلى يعني لو حطيت كمية كبيرة من الموجب و قليلة + +141 +00:12:18,170 --> 00:12:21,730 +من السالب فالخليط موجب يعني الإشارة على طول بنحطها + +142 +00:12:21,730 --> 00:12:26,650 +مابدهاش حساب واحد ربح كتير و خسر أقل فهو رابح واحد + +143 +00:12:26,650 --> 00:12:31,410 +خسر كتير و ربح أقل فهو خاسر الآن بتطلع أنا أعلى + +144 +00:12:31,410 --> 00:12:35,310 +الموجب ولا السالب؟ إذا الخليط اللي عندي موجب لكن + +145 +00:12:35,310 --> 00:12:40,060 +مش هيصل للموجب النقل مش هيصل لعشرينواضح؟ أنا بقول + +146 +00:12:40,060 --> 00:12:44,920 +هنا في عندي تلاتين سالبات بتشطبك بقالها تلاتين + +147 +00:12:44,920 --> 00:12:49,460 +موجة بقىهدولة شطبوا بعض يعني كأنه في عندي تلاتين + +148 +00:12:49,460 --> 00:12:52,180 +في المية بيلفوا باتجاه و التلاتين باتجاه تاني + +149 +00:12:52,180 --> 00:12:55,220 +هدولة شطبوا بعض لما نشطب التلاتين السالبة مع + +150 +00:12:55,220 --> 00:12:59,180 +تلاتين اقبالها موجبة جداش ضال عندي اربعين من + +151 +00:12:59,180 --> 00:13:03,540 +الموجبة اربعين على مية ضارب عشرين بنقدر نحسب كمان + +152 +00:13:03,540 --> 00:13:09,780 +زاوية الخليط اذا دائما و ابدا زاوية الخليط اقل ولا + +153 +00:13:09,780 --> 00:13:14,380 +اكثر من الزاوية النقية اقل لاحظوا معي لو هالخليط + +154 +00:13:14,380 --> 00:13:22,640 +وصل خمسين و خمسينعندما تصبح زاويته صفر رسمك + +155 +00:13:22,640 --> 00:13:28,760 +ميكس شرف او رسمك موديفيكشنالخمسين وخمسين شطبوا بعض + +156 +00:13:28,760 --> 00:13:35,220 +تماما زي إنسان ربح خمسين دينار الصبح وخسر خمسين + +157 +00:13:35,220 --> 00:13:40,620 +دينار آخر النهار، إيش بيروح؟ صفر، لفنا خمسين موجب + +158 +00:13:40,620 --> 00:13:43,820 +و بعدين خمسين سلم، بنينا خمسين حجر و هدينا خمسين + +159 +00:13:43,820 --> 00:13:50,950 +حجر، شو المحصلة؟ صفر، واضح؟هذا بالنسبة لمعنى + +160 +00:13:50,950 --> 00:13:54,770 +كايرال موليكيول و أكايرال موليكيول و راسيمك ميكشر + +161 +00:13:54,770 --> 00:13:58,570 +ولذلك يجب أن تكونوا مميزين أن كلمة كايرال مرت معنى + +162 +00:13:58,570 --> 00:14:03,450 +في كام اتجاه كايرال كاربون معناها أربع مجموعات + +163 +00:14:03,450 --> 00:14:09,230 +مختلفة كايرال موليكيول معناه بلوف الضوء معناه بلوف + +164 +00:14:09,230 --> 00:14:15,950 +الضوء هذا الكلام كله متعلق بقصة ال rotationوهو + +165 +00:14:15,950 --> 00:14:19,970 +خاصية فيزيائية بالمناسبة معنى خاصية فيزيائية ان + +166 +00:14:19,970 --> 00:14:22,810 +انا لو بعد ما خدتها المركب وحطيته في ال + +167 +00:14:22,810 --> 00:14:26,690 +polarimeter وعملت كل القياسات باسترده زي ما هو ولا + +168 +00:14:26,690 --> 00:14:31,610 +لأ انا ماعملت عليه تفاعل هذا الكلام بيقودنا مباشرة + +169 +00:14:31,610 --> 00:14:36,770 +لشغلتانية ال enantiomersiatura من ناحية الخواص + +170 +00:14:36,770 --> 00:14:43,360 +الكيميائية هل بيختلفوا ولا لأيعني ال chemical + +171 +00:14:43,360 --> 00:14:48,580 +properties of enantiomers الخواص الكيميائية لل + +172 +00:14:48,580 --> 00:14:54,020 +enantiomers أسهل شيء ممكن نفهم من خلاله الموضوع + +173 +00:14:54,020 --> 00:14:59,560 +أسهل شيء ممكن نفهم من خلاله الموضوع عارفين شو هو؟ + +174 +00:14:59,560 --> 00:15:04,300 +هعطيكم مثال أو مثلين من الحياة مثال أو مثلين من + +175 +00:15:04,300 --> 00:15:10,730 +الحياةمرات بيكون عندنا عدسات للنضارات عدسات محدبة + +176 +00:15:10,730 --> 00:15:14,470 +ممكن نستعملها نجمع الأشعة أو ممكن بعض الأطفال + +177 +00:15:14,470 --> 00:15:19,230 +الصغار يجمعوا الأشعة أو يحرجوا ورقة بالعدسة بيصير + +178 +00:15:19,230 --> 00:15:20,210 +ولا لأ؟ + +179 +00:15:36,480 --> 00:15:39,820 +ولا صورتها غير المتطابقة في المرآة الإنانش + +180 +00:15:39,820 --> 00:15:44,700 +ومرتبعها؟ مابفرقش يعني لو فكنا العدستين من + +181 +00:15:44,700 --> 00:15:48,840 +النظارات وقولنا للطلاب يتعلموا ويركزوا أشعة الشمس + +182 +00:15:48,840 --> 00:15:52,780 +على البقرة استعملوها العدسة الاتنين هيحرجوا الورقة + +183 +00:15:52,780 --> 00:15:58,260 +إذا هنا اتنين اختلفوا ولا لأ؟ مااختلفوش طيب كويس + +184 +00:15:58,260 --> 00:16:03,860 +لو افترضنا على سبيل المثال إنه إنسان بيشتري أبواب + +185 +00:16:03,860 --> 00:16:08,950 +سياراتقديمة، بيشتريها بالكيلو، الباب وزنه عشرين + +186 +00:16:08,950 --> 00:16:14,090 +كيلو، يا ترى لو جيبناله الباب الأمامي اليمين أو + +187 +00:16:14,090 --> 00:16:19,950 +الباب الأمامي الشمال، بيفرق عنده؟ هو بيشتريهم حديد + +188 +00:16:19,950 --> 00:16:25,990 +خردو في النهاية؟بدوا يسارهم وانتهى افرج انه يشتري + +189 +00:16:25,990 --> 00:16:29,970 +باب يمين ولا باب شمال؟ مايفرقش، اذا ممكن مايفرقوش + +190 +00:16:29,970 --> 00:16:34,790 +طب وين بيفرق معه انه يشتري باب سيارة يمين او شمال؟ + +191 +00:16:34,790 --> 00:16:39,030 +لما يكون في عنده السيارة الكايرة اللي فيها ايضا + +192 +00:16:39,030 --> 00:16:45,150 +الفتحات مصممة يمين وشمال واجتها بيصيربيفرق عنده + +193 +00:16:45,150 --> 00:16:48,710 +لهذه الجهة بدي الباب اليمين لهذه الجهة بدي الباب + +194 +00:16:48,710 --> 00:16:53,710 +الشمال إذا كأنه الفتحات تبعون بواب السيارة كايرال + +195 +00:16:53,710 --> 00:17:00,110 +والبواب كايرال الان كل إشي بدي أحطه في مكانه وقتها + +196 +00:17:00,110 --> 00:17:04,650 +بيصير عند الفرق تماما زي ما أجي أنا أتكلم يعني + +197 +00:17:04,650 --> 00:17:13,120 +عفوا عن أقدام الأحذية الأحذية كايرالواضحة؟ و + +198 +00:17:13,120 --> 00:17:15,760 +الأقدام كايرل .. كايرل .. كايرل .. كايرل .. كايرل + +199 +00:17:15,760 --> 00:17:16,780 +.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. + +200 +00:17:16,780 --> 00:17:19,380 +كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. كايرل + +201 +00:17:19,380 --> 00:17:22,580 +.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. + +202 +00:17:22,580 --> 00:17:22,820 +كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. كايرل + +203 +00:17:22,820 --> 00:17:25,660 +.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. + +204 +00:17:25,710 --> 00:17:30,490 +طيب، هذا الكلام وين أكتر ما بيوجد؟ بيوجد في ال + +205 +00:17:30,490 --> 00:17:34,030 +biological systems، في النظم البيولوجية أنه في + +206 +00:17:34,030 --> 00:17:38,490 +النظم البيولوجية ال enzymes و ال receptors في + +207 +00:17:38,490 --> 00:17:42,330 +أحيان كثيرة كايرا يعني افترضوا مثلا عندي أنا + +208 +00:17:42,330 --> 00:17:47,590 +receptor موجب هذا ال receptor الموجب من خواصه أنه + +209 +00:17:47,590 --> 00:17:53,470 +بتفاعل مع دوة ال drugبتفعل مع دوة drug ال drug + +210 +00:17:53,470 --> 00:17:59,310 +ممكن يكون موجب ممكن يكون ثالث فيه منه اتنين الان + +211 +00:17:59,310 --> 00:18:04,740 +خلينا نفترض ان هذا ال receptor الموجببتفاعل مع + +212 +00:18:04,740 --> 00:18:08,900 +الدوى الموجب فلو جبتله الدوى الموجب بتفاعل معه + +213 +00:18:08,900 --> 00:18:12,320 +وبيؤدي لتأثيره بطيب البني آدم لو جبتله الدوى + +214 +00:18:12,320 --> 00:18:15,980 +السالم واحد + +215 +00:18:15,980 --> 00:18:20,180 +من اتنين ممكن يكون مافيش تفاعل بالمرة ومافيش أثر + +216 +00:18:20,180 --> 00:18:24,160 +بالمرة وممكن يتفاعل معه بطريقة معاتسة ويؤدي إلى + +217 +00:18:24,160 --> 00:18:30,950 +ضرر واضح؟حسب طبيعة الأدوية وحسب الـ Receptor + +218 +00:18:30,950 --> 00:18:34,370 +المعني ولذلك هذه النقطة أكثر ما بتواجهنا في + +219 +00:18:34,370 --> 00:18:39,810 +الكيميا وفي الأدوية أنه بيجوا بيدرسوا كل مركب من + +220 +00:18:39,810 --> 00:18:44,190 +التنين أنه فيهم اللي له الفاعلية ولذلك كثير من + +221 +00:18:44,190 --> 00:18:47,230 +الأدوية لما بتيجوا بتقرأوا الدوة الفعال بتلاقوا ال + +222 +00:18:47,230 --> 00:18:51,250 +R مثلا في مركب تاني الدوة الفعال ال S في مركب تالت + +223 +00:18:51,250 --> 00:18:55,700 +ال R في مركب رابع ال S حسب طبيعة إيش الدوةالان + +224 +00:18:55,700 --> 00:18:59,480 +بيصير السؤال طيب إذا هذا هو المركب الفعال اللى + +225 +00:18:59,480 --> 00:19:04,420 +يستخدم كعلاج المركب التانى شو بده يكون؟ممكن يكون + +226 +00:19:04,420 --> 00:19:09,780 +عديم الفائدة يعني حضوره زي غيابه لا يؤذي ولا يضر و + +227 +00:19:09,780 --> 00:19:15,480 +ممكن يكون مؤذى و مضر و يعمل مشاكل الآن تعون + +228 +00:19:15,480 --> 00:19:21,060 +الكيميا بيشتغلوا بالشكل القاتل إذا مركب منهم دوة و + +229 +00:19:21,060 --> 00:19:24,980 +التاني لا يضر بدل ما يفصلوهم انتوا لاحظوا لما حض + +230 +00:19:24,980 --> 00:19:28,870 +المركب طلعوا عندي خليط من التنينهنتعلم انه لما + +231 +00:19:28,870 --> 00:19:32,970 +نحضر الدواء بيطلع التانين خليط عملية الفصل عملية + +232 +00:19:32,970 --> 00:19:37,570 +صعبة و مكلفة ماديا كتير الان من هدولة مين المفيد + +233 +00:19:37,570 --> 00:19:42,550 +خلينا نفترض هذا الانانشومر التاني إذا كان مابضرش + +234 +00:19:42,550 --> 00:19:47,110 +سيبه معه بيأكلوا البني آدم و بيخرجوا من البني آدم + +235 +00:19:47,110 --> 00:19:52,640 +بدون ما يؤدي لأي ضرربيعطوا الدواء وبيعطوا التاني، + +236 +00:19:52,640 --> 00:19:56,700 +هم عارفين ان هذا التاني مش هيضر .. ان هذا التاني + +237 +00:19:56,700 --> 00:20:00,820 +مش هيضر هذا الكلام بالمناسبة مثلا بيعملوه في دواء + +238 +00:20:00,820 --> 00:20:06,020 +زي الابوبروفين ربما انتوا لما مار علينا جزء + +239 +00:20:06,020 --> 00:20:10,380 +الابوبروفين متذكرينه؟ و انا هفرجيكواياه في ال + +240 +00:20:10,380 --> 00:20:14,540 +aromatic compounds ارجعولهلو اتطلعتوا على + +241 +00:20:14,540 --> 00:20:18,000 +الابوبروفن او الاتروفن هتلاقوا فيه chiral center + +242 +00:20:18,000 --> 00:20:22,340 +فيه منه اتنين لان واحد منهم مفيد و بضيع الصداع + +243 +00:20:22,340 --> 00:20:28,000 +التاني مالوش تأثير واضح بيسيبوه مع بعض و بيعطوا + +244 +00:20:28,000 --> 00:20:31,400 +البني ادم اللي هو يستفيد من المفيد و يخرج الآخر + +245 +00:20:31,400 --> 00:20:36,630 +لمصيبة الكبيرة وين بتصير؟لو كان واحد منهم مفيد + +246 +00:20:36,630 --> 00:20:43,010 +والتاني ضار يجب حينها أن يفصل فصلا كاملا الضار + +247 +00:20:43,010 --> 00:20:48,730 +ويعطى الإنسان المفيد واضحة الفكرة؟ إذا أغلطنا بهذه + +248 +00:20:48,730 --> 00:20:53,210 +الشغلة، إيش حيصير فينا؟ حيصير فينا المقاس التالية + +249 +00:20:53,210 --> 00:20:57,750 +هذا مقال كتباه + +250 +00:21:03,190 --> 00:21:10,030 +دكتورة عن عقار هذا العقار ربما موجود هنا اسمه + +251 +00:21:10,030 --> 00:21:19,430 +الثاليدو أميد هذا قصته في الكيميا قصة مشهورة + +252 +00:21:19,430 --> 00:21:26,750 +كتير هذا هو العقار الثاليدو أميد الآن هذا الثاليدو + +253 +00:21:26,750 --> 00:21:32,540 +أميد في Cairo Center هنا واحدةيعني لما نطلع في + +254 +00:21:32,540 --> 00:21:37,140 +الشكل تبعه فيه chiral center واحدة إذا صار فيه منه + +255 +00:21:37,140 --> 00:21:46,100 +مركب R وصار منه مركب S الآن المركب R مفيد ولمين + +256 +00:21:46,100 --> 00:21:50,300 +المركب R مفيد تقريبا اخترع هذا الدواء في سنة 1953 + +257 +00:21:50,300 --> 00:21:56,940 +للنساء الحوامل بضيع عندهم الصداع المصاحب للحملنزل + +258 +00:21:56,940 --> 00:22:01,600 +السوق بدون ما تستكمل الدراسات الكاملة عليه في آخر + +259 +00:22:01,600 --> 00:22:07,920 +الخمسينات طلعت المصيبة أن المركب التاني الـ S هذا + +260 +00:22:07,920 --> 00:22:12,300 +بيخترق المشيمة و بيأثر على الأجنة اللي في بطون + +261 +00:22:12,300 --> 00:22:17,190 +الأمهات لأنهم بياخدوا الأمهات الحواملعشان الصداع + +262 +00:22:17,190 --> 00:22:21,750 +ما انتبهوش ما استكملوش الدراسات تبع الدواء فطلع + +263 +00:22:21,750 --> 00:22:26,350 +المركب الثاني بأثر على الأجنة، الآن عدد كبير من + +264 +00:22:26,350 --> 00:22:31,350 +النساء استعملوا بدأت أوروبا تتواجه بالأجنة + +265 +00:22:31,350 --> 00:22:36,920 +المشوهينتقريبا سنة و نص سنتين ستين و واحد و ستين + +266 +00:22:36,920 --> 00:22:41,000 +نهاية التسعة و خمسين مباشرة من أول ما انتبهولها مع + +267 +00:22:41,000 --> 00:22:45,360 +الواحد و ستين أوقفوا استعمال الدواء على طول لكن + +268 +00:22:45,360 --> 00:22:49,960 +بعد ما طلع عندهم جيل كامل من الأطفال المشواهين + +269 +00:22:49,960 --> 00:22:54,520 +ملمش أيديهم فقط لغلطة زي هيك انه كانوا يعطوا + +270 +00:22:54,520 --> 00:23:00,400 +الدواء و معاهالإينان شمار .. الإينان شمار إيش + +271 +00:23:00,400 --> 00:23:06,980 +اتضارت و ربما لو الصورة واضحة عندكم في أسماء + +272 +00:23:06,980 --> 00:23:12,780 +مشهورة في هذا المجال يعني هذا الإنسان يمكن مش واضح + +273 +00:23:12,780 --> 00:23:17,480 +كده بس اتطلعوا الإيدين بتاعونه بصار جدا الإيدين + +274 +00:23:17,480 --> 00:23:23,060 +بتاعونه اتطلعوا عليه بالصور بالنتبتنبسطوا، بتلاقوا + +275 +00:23:23,060 --> 00:23:28,240 +كتير، ليش؟ لأن هذا مذيع مشهور جدا، مذيع مشهور جدا + +276 +00:23:28,240 --> 00:23:34,420 +في ال BBC ومحرر أخبار في النهاية اسمه Adams Spank + +277 +00:23:34,420 --> 00:23:38,780 +Adams Spank اللي بدهم يقرأوا عن قصته Adams Spank + +278 +00:23:38,780 --> 00:23:44,790 +موليد ال 61يعني الحامل صار في الستين الام أخدت + +279 +00:23:44,790 --> 00:23:49,150 +الدواء هو موليد الواحد والستين بدون إيدين وبعين + +280 +00:23:49,150 --> 00:23:55,430 +يعني فيها إيش عوى كذلك الحال لو بدأ أطلع على أسماء + +281 +00:23:55,430 --> 00:24:00,790 +تانية هاي Adams Smug شايفين العين هنا شوية مافيش + +282 +00:24:00,790 --> 00:24:09,710 +إيدين هذا بني آدم مش بدخل سيجارة هذا برسم الريشة + +283 +00:24:09,710 --> 00:24:15,170 +في تمه لأنه مالوش إيدينرسام شهير ويله معارض شهيرة + +284 +00:24:15,170 --> 00:24:19,670 +برضه موليد ال واحد و ستين من غلطة زي هذه برضه + +285 +00:24:19,670 --> 00:24:23,650 +موليد ال واحد و ستين و هي المعرض الفني تبعه و هذا + +286 +00:24:23,650 --> 00:24:28,950 +بامالي الكوجادرين اللي تشوفوه هذا بيعزف ع الجثار + +287 +00:24:28,950 --> 00:24:36,790 +برجله ليش؟ برضه لأنه مالوش أطراف مالوش إيدين إيدين + +288 +00:24:36,790 --> 00:24:43,050 +و غير الإيدين كمان إيدين و عينينو جوزي أنتونيو + +289 +00:24:43,050 --> 00:24:47,130 +عازف شهير جدا من نيكاراجوا و ربما البعض سمع له + +290 +00:24:47,130 --> 00:24:52,480 +موسيقىعازف مشهور هدولة كلهم عايشين ولذلك من سنين + +291 +00:24:52,480 --> 00:24:56,640 +بسيطة الألمان عملوا فيلم عن هذا الموضوع واحتجوا + +292 +00:24:56,640 --> 00:25:01,980 +الشعب الألماني ليش؟ لأنه ذكروهم بالمقساة اللي مرت + +293 +00:25:01,980 --> 00:25:06,160 +في عام واحد وستين اتنين وستين مقسات الأجنة + +294 +00:25:06,160 --> 00:25:10,340 +المشوهين كل هذا الكلام لأن استعملنا الدوة الغلط + +295 +00:25:10,340 --> 00:25:16,090 +الفكرة ببساطةمرة تانية تشبه قصة المفتاح والذرفيل + +296 +00:25:16,090 --> 00:25:20,990 +الذرفيل كايرة الفراغي بيده مفتاح معين يتطابق معاه + +297 +00:25:20,990 --> 00:25:27,670 +نجيب المفتاح التاني مابفتحش مستفدناش اشي و لذلك في + +298 +00:25:27,670 --> 00:25:34,970 +الخواص الكيميائية ال enantiomers لهم نفس الخواص + +299 +00:25:34,970 --> 00:25:40,840 +الكيميائية ما عدااذا اتفعلوا مع مركبات فراغية زيهم + +300 +00:25:40,840 --> 00:25:45,680 +يعني لما بتفعل ال chiral مع ال chiral اشي ماخد + +301 +00:25:45,680 --> 00:25:49,000 +اتجاه فراغي شمال او يمين مع اشي ماخد اتجاه فراغي + +302 +00:25:49,000 --> 00:25:52,880 +شمال او يمين بيصير الاختلاف زي الزرفيل بتاع الباب + +303 +00:25:52,880 --> 00:25:57,820 +في شمال ويمين جوا والمفتاح في شمال ويمين بيصير + +304 +00:25:57,820 --> 00:26:04,160 +مفتاح معينلذرفي المعين واحد تاني مابظبطش او بادى + +305 +00:26:04,160 --> 00:26:08,340 +الى مشاكل ولذلك في الخواص الكيميائى المحاصلة اللى + +306 +00:26:08,340 --> 00:26:12,500 +بنقولها ان ال enantiomers they have the same + +307 +00:26:12,500 --> 00:26:16,780 +chemical the same chemical properties except when + +308 +00:26:16,780 --> 00:26:19,880 +they react with other chiral molecules لما يصير + +309 +00:26:19,880 --> 00:26:24,630 +التفاعل بين chiral و chiral وجعت المشكلةواضح + +310 +00:26:24,630 --> 00:26:31,030 +الفكرة؟ هذا كلام عام جدا لكن بحياتكوا .. يعني بأمل + +311 +00:26:31,030 --> 00:26:34,990 +أنه هتصيروا تشوفوا كتير هذه المسميات هتصيروا + +312 +00:26:34,990 --> 00:26:38,730 +تقرأوا كتير على الأدوية مكتوب عليها R و بين جثين + +313 +00:26:38,730 --> 00:26:42,330 +موجة بقى أو سالب و S و بين جثين موجة بقى أو سالب + +314 +00:26:42,330 --> 00:26:52,230 +فنكون عارفين كل هذه المصطلحات فليدو أمد فليدو + +315 +00:26:56,400 --> 00:27:03,260 +ثليده أمن لو قرأته قصة الثليده أمن قصة كبيرة جدا + +316 +00:27:03,260 --> 00:27:09,540 +بلاش ممكن نروح على شغلة تانية بسيطة جدا ربما مرت + +317 +00:27:09,540 --> 00:27:19,740 +عليكم كتير مر عليكم هذا اللي موجود هنا في الصورة + +318 +00:27:19,740 --> 00:27:27,120 +قادرين تشوفوه الفطرالفطر تبع البيتزا، الان متعودين + +319 +00:27:27,120 --> 00:27:31,500 +تقولوا ان الفطر في منه كويس و في منه سام، مظبوط؟ + +320 +00:27:31,500 --> 00:27:37,820 +الان الكويس والسام فيهم نفس المركب، نفس المركب، + +321 +00:27:37,820 --> 00:27:42,880 +تحديدا من ناحية كيميائية هذا هو المركب، واضح؟ من + +322 +00:27:42,880 --> 00:27:44,040 +ناحية كيميائية + +323 +00:27:47,540 --> 00:27:52,000 +هذا هو المركب، شايفينه؟ هاي المركب، الآن هذا + +324 +00:27:52,000 --> 00:27:59,860 +المركب في chiral center واحد، هذا واحد + +325 +00:27:59,860 --> 00:28:08,010 +منهم بيكون اكويس والتاني بيكون poisonous، سابفقط + +326 +00:28:08,010 --> 00:28:12,330 +بيختلفوا بال chiral center يعني نفس الجزء هذا اللي + +327 +00:28:12,330 --> 00:28:17,110 +بنسميه one octane three all ال R منه اللي كويس و + +328 +00:28:17,110 --> 00:28:22,590 +التاني ال 7 و انتوا دائما كانوا يحذروكوا في دراسة + +329 +00:28:22,590 --> 00:28:27,330 +النبات و انه احذروا الفطر اللي بيكون عادة شكله زي + +330 +00:28:27,330 --> 00:28:32,650 +المثلث يعني الفطر العادي هذا ال okay هذا العامل + +331 +00:28:32,650 --> 00:28:37,240 +مشكلة الآن هذولا فيهم نفس الهوركبنفس المُركّب اللي + +332 +00:28:37,240 --> 00:28:41,080 +خلّه مُركّب كويس ومُركّب سام انه هذا انانشومر وهذا + +333 +00:28:41,080 --> 00:28:45,660 +انانشومر تاني شوفوا هذا الفرق البسيط جدا اللي + +334 +00:28:45,660 --> 00:28:49,740 +بمرهانة قعد يؤثر على الأدوية ويؤثر على حياة الناس + +335 +00:28:49,740 --> 00:28:54,120 +هو فرق أساسي في فهم الكيمياء ولذلك يعني ال stereo + +336 +00:28:54,120 --> 00:28:59,980 +chemistry مش قصة يعني قصة شيء أحيانا صعب أو شيء + +337 +00:28:59,980 --> 00:29:05,490 +ممتع على جانب لإن فيه صميمفهم الكيمياء و في صميم + +338 +00:29:05,490 --> 00:29:11,470 +فهم الأدوية ان نكون فاهمين هذه الأمور المتعلقة بال + +339 +00:29:11,470 --> 00:29:18,890 +stereo chemistry طبعا الانسان كل ما بيتعب من شغلة + +340 +00:29:18,890 --> 00:29:24,270 +بيقول واجتاش بدنا نخلص من الشغلة اول ما بيحس انه + +341 +00:29:24,270 --> 00:29:30,310 +بده يخلص من الشغلة بيكتشف نقطة بسيطة جدا ان هو لسه + +342 +00:29:30,310 --> 00:29:36,330 +ماخدش من الموضوع نقطةأول ما بيحس أنه جربنا نخلص من + +343 +00:29:36,330 --> 00:29:40,950 +هالشغلة هو ما أخدش من الموضوع نقطة، ليش؟ لأنه أنا + +344 +00:29:40,950 --> 00:29:47,670 +تكلمت عن جزء في chiral centers واحد، قولت بيقدّي + +345 +00:29:47,670 --> 00:29:52,990 +لكم إينان شمار؟ إتنين، طيب يا تورة الآن لو أجيت و + +346 +00:29:52,990 --> 00:29:58,350 +أتكلمت عن ال chiral centers ال chiral centers + +347 +00:29:58,350 --> 00:30:02,190 +والإينان + +348 +00:30:02,190 --> 00:30:12,790 +شمارأو ال products ال stereo isomers لما + +349 +00:30:12,790 --> 00:30:17,690 +كان في عندى one chiral center كم واحد كانوا؟ طب يا + +350 +00:30:17,690 --> 00:30:19,910 +تورا لو صاروا اتنين، لو صاروا تلاتة، لو صاروا + +351 +00:30:19,910 --> 00:30:23,490 +أربعة، لو صاروا خمسة، لو صاروا ستة، كده بده يصير + +352 +00:30:23,490 --> 00:30:28,180 +عندى؟يعني جزء فيه تلاتة اربعة خمسة chiral centers + +353 +00:30:28,180 --> 00:30:33,060 +في عندى علاقة بتقوللي ال maximum possible number + +354 +00:30:33,060 --> 00:30:40,680 +of stereoisomers two to the N بحيث انه هذي ايش ال + +355 +00:30:40,680 --> 00:30:51,790 +N اتنين اقص واحد اتنين اقص اتنين اربعة2-3 8 2-4 16 + +356 +00:30:51,790 --> 00:30:59,050 +2-5 32 لما يبدأ يجينا مركب في خمسة chiral centers + +357 +00:30:59,050 --> 00:31:06,510 +هنكتشف أنه في منه 32 isomers هذول 32 isomers ممكن + +358 +00:31:06,510 --> 00:31:10,990 +واحد منهم يكون مفيد و بنستفيد منه والواحد و + +359 +00:31:10,990 --> 00:31:15,200 +التلاتين التانين بقابلهلاحظوا قداش الكلام بيصير + +360 +00:31:15,200 --> 00:31:20,440 +مرهق وهذا الكلام هيمر معكم على سبيل المثال الخامسة + +361 +00:31:20,440 --> 00:31:27,400 +لما ندرس ال biochemistry السكر اللي مكوّن من ست + +362 +00:31:27,400 --> 00:31:32,500 +درات كربون لما يكون في الشكل الحلقي في خمسة chiral + +363 +00:31:32,500 --> 00:31:39,340 +centers في منه اتنين و تلاتين isomersتخيلوا أنه + +364 +00:31:39,340 --> 00:31:44,700 +بدنا نتعلم لما نيجي ناخد السكر السداسي الماخد + +365 +00:31:44,700 --> 00:31:52,800 +الصيغة العامة C6H12O6 بدنا نرسم مش مركب واحد اتنين + +366 +00:31:52,800 --> 00:31:58,220 +و تلاتين مركب و نعرفهم و نميزهم بالاسم الان لما + +367 +00:31:58,220 --> 00:32:01,420 +المريض بيروح على المستشفى لما المريض بيروح على + +368 +00:32:01,420 --> 00:32:04,760 +المستشفى و بيقولوا بدنا نعطيه محلول سكر بتعرفوا + +369 +00:32:04,760 --> 00:32:10,490 +بيعطيه واحد من الاتنين و تلاتينواحد من ال 32 هدولة + +370 +00:32:10,490 --> 00:32:16,370 +واضح و الباقي مش هم اللي بيعطيها فالموضوع بيصير + +371 +00:32:16,370 --> 00:32:21,790 +بهذا الشكل كبير طبعا اللي بده يتدرج في الكلام يبدأ + +372 +00:32:21,790 --> 00:32:26,190 +يعطي مثال على اتنين chiral centers الان انا هنا + +373 +00:32:26,190 --> 00:32:31,390 +مابقولش ان هذا عدد ال isomers بقول هذا ال maximum + +374 +00:32:31,390 --> 00:32:38,340 +possible يعني هذاأعلى ما يمكن من ال isomers بس + +375 +00:32:38,340 --> 00:32:44,130 +ممكن يكون أقل منهيعني لما بيكون فيه اتنين chiral + +376 +00:32:44,130 --> 00:32:48,710 +centers ممكن يكون عنده العدد الأقصى أربعة و مرات + +377 +00:32:48,710 --> 00:32:53,490 +بيكونوا تلاتة و هكذا ممكن يقولوا واحد مابدناش + +378 +00:32:53,490 --> 00:32:58,790 +نتجاوز بس التلين يعني بدنا نشرح مثالين مثال لما + +379 +00:32:58,790 --> 00:33:02,790 +يكون عنده two chiral centers و عنده أربعة isomers + +380 +00:33:02,790 --> 00:33:07,230 +و مثال لما بيكون عنده two chiral centers بس ال + +381 +00:33:07,230 --> 00:33:11,430 +isomersتلاتة يعني بيطلع منهم في هذه الحالة اتنين + +382 +00:33:11,430 --> 00:33:16,710 +طلعوا شبه بعض نفس الاشياء واضح فبصير الدارس تبعنا + +383 +00:33:16,710 --> 00:33:23,630 +المركبات اللي فيهاأكتر من chiral centers والمثال + +384 +00:33:23,630 --> 00:33:26,770 +اللى بدنا نبدأ فيه لما يكون عندى two chiral + +385 +00:33:26,770 --> 00:33:32,650 +centers او centers لاحظوا ان هذا الكلام بيجيبنا + +386 +00:33:32,650 --> 00:33:41,000 +لنقطة ان انتوا لما بتتعلموا العلم بتتعلموا كيفبنوع + +387 +00:33:41,000 --> 00:33:46,340 +من البساطة بتتعلموا بنوع من البساطة في الأول يعني + +388 +00:33:46,340 --> 00:33:52,420 +بنعطيكوا جزء من العلم وبنخبي عنكم أجزاء بنعطيكوا + +389 +00:33:52,420 --> 00:33:57,340 +جزء وبنخبي عنكم أجزاء يعني لو جيبت سؤال احنا + +390 +00:33:57,340 --> 00:34:00,680 +اتعودنا ان نجاوبه وممكن اعطيتكوا ياهو ميركو سلمته + +391 +00:34:00,680 --> 00:34:05,960 +وقلتلكوا مركب البنتين لو عملتله monochlorination + +392 +00:34:07,760 --> 00:34:12,900 +هي واحد، اتنين، تلاتة، اربعة، خمسة كام ناتج عندي + +393 +00:34:12,900 --> 00:34:17,980 +من الـ monoclonation؟ اعملتوا؟ تلاتة واحدة ما زالت + +394 +00:34:17,980 --> 00:34:23,480 +بتقول تلاتة إذا حطيت هنا كلور، مُركّب وإذا حطيت + +395 +00:34:23,480 --> 00:34:27,600 +هنا مُركّب وإذا حطيت هنا مُركّب وسمناهم one + +396 +00:34:27,600 --> 00:34:33,360 +chloro, two chloro, three chloro الآن لاحظوا معي + +397 +00:34:33,360 --> 00:34:36,300 +لو هذا الكلام أنا إجيته طبقته + +398 +00:34:40,720 --> 00:34:44,160 +هذا مُركّب البنتين و افترض ان انا بعمل الكلور هاي + +399 +00:34:44,160 --> 00:34:47,080 +الكلور عن إمرأة واحد، هاي الكلور عن إمرأة اتنين، + +400 +00:34:47,080 --> 00:34:52,280 +هاي الكلور عن إمرأة تلاتة بتقصيروا الآن، بتقولوا، + +401 +00:34:52,280 --> 00:35:02,440 +في عندي chiral centers ولا لأ؟ هنا CH2 CH2 CH2 CH2 + +402 +00:35:02,440 --> 00:35:06,180 +CH3 إذا مافيش ولا chiral center، إذا هذا فعلا + +403 +00:35:06,180 --> 00:35:12,290 +مُركّب واحد، الواحد كلوره بينتينالان هنا حطوا + +404 +00:35:12,290 --> 00:35:18,170 +القدش لناقصة في Cairo Center إذا هذا مركبين في من + +405 +00:35:18,170 --> 00:35:22,430 +واحد R و واحد S يعني لو روحتوا تشتريوا مركب اسمه + +406 +00:35:22,430 --> 00:35:28,130 +two chlorobentain هتلاقوا مركبين البياح هيقولكم في + +407 +00:35:28,130 --> 00:35:31,070 +مركب اسمه R two chlorobentain و S two + +408 +00:35:31,070 --> 00:35:34,170 +chlorobentain بس فيش مركب اسم two chlorobentain + +409 +00:35:34,970 --> 00:35:38,470 +واضح؟ يا بدي يكون R يا بدي يكون S لأنه في كايرال + +410 +00:35:38,470 --> 00:35:44,770 +سنتر طيب هذا المركب لأ لأنه اثل او اثل CH2 CH3 + +411 +00:35:44,770 --> 00:35:47,210 +اللي هي مجموعة ايش الاثل + +412 +00:35:49,150 --> 00:35:53,910 +و هذه إثل فحامل HUC قالوا إثل و إثل إذا هذا فيش + +413 +00:35:53,910 --> 00:35:59,650 +منه غير مركّب الآن لو أنا إجيت سألتكم عادة أن الـ + +414 +00:35:59,650 --> 00:36:03,750 +monochlorination للوان بنتين بيعطيني + +415 +00:36:03,750 --> 00:36:09,450 +chemistructural isomers4 أربع لأ تلاتة لاحظوا + +416 +00:36:09,450 --> 00:36:14,010 +معايا ال structural isomers اللي بيختلفوا في ترتيب + +417 +00:36:14,010 --> 00:36:18,590 +مواقع الذرات من ناحية ال structure لكلور يا ع واحد + +418 +00:36:18,590 --> 00:36:23,170 +يا ع اتنين يا ع تلاتة هذا المركب هيكون اسمته two + +419 +00:36:23,170 --> 00:36:27,190 +chlorobentain والتاني two chlorobentain الآن ال R + +420 +00:36:27,190 --> 00:36:32,930 +و ال S stereo isomersولذلك، بدكم تنتبه لو أنا + +421 +00:36:32,930 --> 00:36:36,530 +بقولكوا بيعطيني كام structural isomers، ثلاثة، لكن + +422 +00:36:36,530 --> 00:36:41,250 +لو قلتلكم ال total number of isomers، أربعة، ال + +423 +00:36:41,250 --> 00:36:44,630 +total number of isomers، أربعة، لأن هذا واحد، هذا + +424 +00:36:44,630 --> 00:36:52,380 +في منه تنين، Rs، وهذا واحد، واضح الفكرة؟الان لو + +425 +00:36:52,380 --> 00:36:57,480 +اتينا احنا بدنا نزيد خطوة بدنا نقول it's two + +426 +00:36:57,480 --> 00:37:03,900 +chlorobentains بس نعمله dichlorination مش + +427 +00:37:03,900 --> 00:37:09,900 +monochlorination ربما ان انتوا حليتوا السؤال لكن + +428 +00:37:09,900 --> 00:37:17,070 +بدون ماشيبدون ما تاخدوا الاستيريو كيميستر بعين + +429 +00:37:17,070 --> 00:37:20,970 +الاعتبار يعني ممكن تفكروا تحطوا تنتين كلور هنا او + +430 +00:37:20,970 --> 00:37:24,650 +تنتين هنا او تنتين هنا او واحدة و واحدة واحدة + +431 +00:37:24,650 --> 00:37:27,450 +واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة + +432 +00:37:27,450 --> 00:37:27,730 +واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة + +433 +00:37:27,730 --> 00:37:27,990 +واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة + +434 +00:37:27,990 --> 00:37:29,050 +واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة + +435 +00:37:29,050 --> 00:37:31,090 +واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة + +436 +00:37:31,090 --> 00:37:37,070 +واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة + +437 +00:37:37,070 --> 00:37:41,490 +واحدة واحدة واحدة واحدة واحدةهذا مش هيكون في منه + +438 +00:37:41,490 --> 00:37:46,650 +إلى واحد او التنتين هان او التنتين هان طبعا هان زي + +439 +00:37:46,650 --> 00:37:49,910 +هان و هان زي هان بعدين ممكن تحطوا كلور ع واحد و ع + +440 +00:37:49,910 --> 00:37:54,510 +اتنين بيصير عندى one chiral center اللى هنا وجد + +441 +00:37:54,510 --> 00:37:57,850 +هذا المركب اللى فيه هنا كلور هنا كلور كم مركب منه + +442 +00:37:57,850 --> 00:38:03,810 +اتنين ممكن تحطه هان و هان بيصير برضه عندكم one + +443 +00:38:03,810 --> 00:38:08,690 +chiral center في منه جديش اتنين ممكن تحطه هان و + +444 +00:38:08,690 --> 00:38:14,080 +هانبرضه عندكم one chiral center فى منه اتنين ممكن + +445 +00:38:14,080 --> 00:38:17,660 +تحطوا هنا و هنا تخيلوا لما تحطوا هنا CL ما زال + +446 +00:38:17,660 --> 00:38:24,300 +عندكم CH2 مش chiral و CH2 و CH2 و CH2 و هنا CH2CL + +447 +00:38:24,300 --> 00:38:29,860 +مش chiral اذا لو انا جبتلكوا سؤال ال one five + +448 +00:38:29,860 --> 00:38:36,100 +dichlorobentane has two stereoisomers طلعوا معاه + +449 +00:38:36,100 --> 00:38:41,170 +هي كلور هي كلورشوفوا هنا كم كايرال سنتر فيه + +450 +00:38:41,170 --> 00:38:45,250 +CH2H2H2H2 + +451 +00:38:45,250 --> 00:38:49,210 +ولا كايرال سنتر إذا ال 1,5 ده يكلوره بين 2 فيه + +452 +00:38:49,210 --> 00:38:53,710 +مركب واحد لكن لو أنا كنت مثلا باجي بسألكم ال 1,2 + +453 +00:38:53,710 --> 00:39:03,210 +هيكلور أكيد هنا H هنا CL هتكون مكملة H2 HH صح ولا + +454 +00:39:03,210 --> 00:39:10,610 +لأ هذا كم مركب منه 2لأ و هذا مش chiral هذا بس one + +455 +00:39:10,610 --> 00:39:19,370 +chiral center فيه هذا مش chiral هذا CH2 و هذه H2 و + +456 +00:39:19,370 --> 00:39:23,590 +هذه H2 و هذه H3 one chiral center إذا ال one two + +457 +00:39:23,590 --> 00:39:29,710 +dichloro بينتين في منه كام مركب اتنين ارقص الآن لو + +458 +00:39:29,710 --> 00:39:34,070 +إجيت لواحد من هدول المجموعة و اتأملوا جيدا + +459 +00:39:36,880 --> 00:39:44,160 +وقلنا لكوا سمونا المركب التالي هذا + +460 +00:39:44,160 --> 00:39:48,040 +اتنين + +461 +00:39:48,040 --> 00:39:49,540 +ثلاثة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين + +462 +00:39:49,540 --> 00:39:49,620 +تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين + +463 +00:39:49,620 --> 00:39:50,060 +تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين + +464 +00:39:50,060 --> 00:39:50,980 +تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين + +465 +00:39:50,980 --> 00:39:56,440 +تلاتة اتنين تلاتة + +466 +00:39:56,440 --> 00:39:56,780 +اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة + +467 +00:39:56,780 --> 00:40:01,900 +اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين ت + +468 +00:40:05,330 --> 00:40:10,730 +هذه حملة مثل و H و CL و مجموعة كبيرة إذا هذه كايرا + +469 +00:40:10,730 --> 00:40:16,690 +و هذه حملة كلور و H و CH2 و CH3 و CHCL و CH3 أربع + +470 +00:40:16,690 --> 00:40:21,990 +مجموعات كايرا two chiral centers maximum بنتوقع + +471 +00:40:21,990 --> 00:40:26,650 +أربعة و حقيقة هنكتشف إن هدولة أربع مركبات + +472 +00:40:30,150 --> 00:40:34,470 +اللي كنا بنفكره و بنكتب ان هو مراكب واحد ال two + +473 +00:40:34,470 --> 00:40:38,330 +three dichlorobentain هتلاحظوا انه اربع مراكبات + +474 +00:40:38,330 --> 00:40:41,250 +يعني لو روحتوا على الدكانة تشتريوا two three + +475 +00:40:41,250 --> 00:40:43,570 +dichlorobentain لو سمحت بيعلى two three + +476 +00:40:43,570 --> 00:40:47,270 +dichlorobentain بيفتش مابلاقيش مراكب في الكون هيك + +477 +00:40:47,270 --> 00:40:51,250 +لو واحده اسمه two three dichlorobentain هيلاقيهم + +478 +00:40:51,250 --> 00:40:58,190 +اسمهم ROR SOS ROS SOR هتقولوا كيف هدولة ابن اتعلم + +479 +00:41:03,030 --> 00:41:07,570 +نرسمهم الان متشوقين انكوا تشوفوا شو مع الاربع + +480 +00:41:07,570 --> 00:41:13,150 +مركبات العملية بسيطة اتطلعوا مع هاي البنتين carbon + +481 +00:41:13,150 --> 00:41:20,730 +CH3 CH حملة CL CH حملة CL و إثل يعني CH2 CH3 ع + +482 +00:41:20,730 --> 00:41:24,960 +موقع اتنين وع موقع تلتة عندكم كلور ولا لأهي على + +483 +00:41:24,960 --> 00:41:29,560 +اتنين كلور و على تلاتة كلور الان حطوهم عكس بعض و + +484 +00:41:29,560 --> 00:41:34,100 +اعملوا صورتهم في المرايا صار هذا مركب و هذا مركب + +485 +00:41:34,100 --> 00:41:40,800 +غير متطابقين على بعض و حطوهم جنب بعض الكلور شايفين + +486 +00:41:40,800 --> 00:41:46,080 +الكلور عكس بعض و صورتهم في المرايا جنب بعض و + +487 +00:41:46,080 --> 00:41:52,520 +صورتهم في المراياكام مراكب صاروا؟ أربعة، الآن كل + +488 +00:41:52,520 --> 00:41:55,240 +اللي موجود عند الأربع مراكبات اسمهم two three + +489 +00:41:55,240 --> 00:41:59,000 +dichlorobentane باجي بسمي من هنا واحد اتنين تلاتة + +490 +00:41:59,000 --> 00:42:05,760 +اربعة لما بدي اقول هذا اتنين بدي احددها R ولا S و + +491 +00:42:05,760 --> 00:42:11,360 +تلاتة بدي احددها R ولا Sبسأل نفسي وين أقل مجموعة + +492 +00:42:11,360 --> 00:42:16,680 +على اتنين انا امركز الان على اتنين ال H شطبناها + +493 +00:42:16,680 --> 00:42:23,420 +قول انا على الجانب هنعكس الان عندكم Cl و Carbon و + +494 +00:42:23,420 --> 00:42:27,740 +CH3 طبعا هذه ال Carbon حملة Cl و هذه الحملة H اذا + +495 +00:42:27,740 --> 00:42:47,970 +كيف همشيأس أس أس أس أس أس أس أس أس أس أس + +496 +00:42:47,970 --> 00:42:54,580 +أس أس أس أس أس أس أس أس أس أس أس أسالـ H و الأعلى + +497 +00:42:54,580 --> 00:43:02,700 +مجموعة الـ Cl بعدها الكربون اللي حمله Cl بعدها هذه + +498 +00:43:02,700 --> 00:43:08,840 +الـ Ethyl CH2 CH3 أنا أعلى كربون بتحمل Cl ولا + +499 +00:43:08,840 --> 00:43:13,200 +كربون بتحمل H و H و C كربون بتحمل Cl مش فيها نقاش + +500 +00:43:13,200 --> 00:43:18,790 +الآن هاي واحد هذه كلها كمجموعة اتنينهذه تلات + +501 +00:43:18,790 --> 00:43:24,710 +مجموعات هذي واحد هذي اتنين هذي تلاتة ال R لما نمشي + +502 +00:43:24,710 --> 00:43:30,870 +بهذا الشكل واحد اتنين تلاتة شو مبينه بكتب 3R هذول + +503 +00:43:30,870 --> 00:43:36,090 +عكسهم هتلاقوهم 2S 3S بإمكانكوا في البيت الأن + +504 +00:43:36,090 --> 00:43:43,020 +تروحوا تحددوا كل هذه المواقعاعملوهم بهدوء هتلاحظوا + +505 +00:43:43,020 --> 00:43:47,080 +ان الأربع مركبات اللي موجودة هنا الاربع مركبات + +506 +00:43:47,080 --> 00:43:50,600 +اللي موجودة هنا two R ثري R وصورته في المرايا two + +507 +00:43:50,600 --> 00:43:55,060 +S ثري S دابن الصورة في المرايا أشمالها عكس يعني ال + +508 +00:43:55,060 --> 00:43:59,740 +R أقبالها S و ال R أقبالها S و بعدين ال two R ثري + +509 +00:43:59,740 --> 00:44:04,340 +S و أقبالها two S three R يعني ال two R two S و ال + +510 +00:44:04,340 --> 00:44:09,760 +three S three R مش أنا قولت كل نقطةعكس التانية في + +511 +00:44:09,760 --> 00:44:14,620 +المراية هل يترفيب هذه الرموز أي رمزين متشابهين؟ + +512 +00:44:14,620 --> 00:44:20,680 +إذا هدولة كام مركبة؟ أربع مركبات اتخيلوا عاد لو + +513 +00:44:20,680 --> 00:44:24,960 +واحد من هدولة الدوة و الباقين بضره أنه أنا اللي + +514 +00:44:24,960 --> 00:44:29,060 +بدي استعمله، هنفترض أن الدوة كان 2S 3S، بس هذا + +515 +00:44:29,060 --> 00:44:33,530 +اللي بدي استعمله، هذا لأ، هذا لأ، هذا لأواضحة + +516 +00:44:33,530 --> 00:44:36,830 +الفكرة شوما الأربع مركبات المرة الجاية ان شاء الله + +517 +00:44:36,830 --> 00:44:41,450 +انطلاقا من هذه النقطة بشرط تكونوا اتدربتوا على + +518 +00:44:41,450 --> 00:44:45,570 +تسمية المركبات وعلى تحديد ال chiral centers بشكل + +519 +00:44:45,570 --> 00:44:48,950 +أكبر بنستمر انطلاقا من هذه النقطة + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..926179726f782890f12de14f8d594f3e5bd9164c --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 2729, "start": 20.69, "end": 27.29, "text": "بسم الله الرحمن 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"word": " تتعبوا", "probability": 0.98408203125}, {"start": 182.81, "end": 183.93, "word": " انا", "probability": 0.73779296875}, {"start": 183.93, "end": 184.35, "word": " بهمني", "probability": 0.9303385416666666}, {"start": 184.35, "end": 184.49, "word": " في", "probability": 0.81591796875}, {"start": 184.49, "end": 185.05, "word": " النهاية", "probability": 0.9593098958333334}, {"start": 185.05, "end": 185.47, "word": " ان", "probability": 0.94580078125}, {"start": 185.47, "end": 186.11, "word": " انتوا", "probability": 0.9137369791666666}, {"start": 186.11, "end": 186.11, "word": " ..", "probability": 0.320068359375}, {"start": 186.11, "end": 186.91, "word": " ان", "probability": 0.80224609375}, {"start": 186.91, "end": 187.49, "word": " انتوا", "probability": 0.95703125}, {"start": 187.49, "end": 188.33, "word": " تتعبوا", "probability": 0.96845703125}, {"start": 188.33, "end": 188.75, "word": " يعني", "probability": 0.9267578125}, {"start": 188.75, "end": 188.87, "word": " ان", "probability": 0.63330078125}, {"start": 188.87, "end": 189.35, "word": " اقولكوا", "probability": 0.929931640625}, {"start": 189.35, "end": 189.83, "word": " specific", "probability": 0.96923828125}, {"start": 189.83, "end": 190.73, "word": " rotation", "probability": 0.9599609375}, {"start": 190.73, "end": 191.37, "word": " ل", "probability": 0.88134765625}, {"start": 191.37, "end": 191.99, "word": " ال", "probability": 0.57958984375}, {"start": 191.99, "end": 192.29, "word": " tube", "probability": 0.476318359375}, {"start": 192.29, "end": 193.09, "word": " eutanol", "probability": 0.60888671875}, {"start": 193.09, "end": 193.27, "word": " و", "probability": 0.712890625}, {"start": 193.27, "end": 193.61, "word": " تقولوا", "probability": 0.984375}, {"start": 193.61, "end": 194.39, "word": " اتغلبنا", "probability": 0.91689453125}, {"start": 194.39, "end": 195.09, "word": " معنى", "probability": 0.8738606770833334}, {"start": 195.09, "end": 195.43, "word": " ذلك", "probability": 0.9931640625}, {"start": 195.43, "end": 195.81, "word": " ما", "probability": 0.471923828125}, {"start": 195.81, "end": 196.41, "word": " تقلتوش", "probability": 0.8475748697916666}], "temperature": 1.0}, {"id": 9, "seek": 22633, "start": 197.57, "end": 226.33, "text": "ممكن في عصر المعلومات ناس مايقدروش يطولوا ل specific rotation لتو بيوتانول او لتو كلورو بيوتانول هذه معلومة ثابتة زي ما اجي اقولكم تماما ايش نقطة الغليان ايش نقطة الانصحار ايش نقطة كده كل هذه المعلومات معلومات متوفرة وموجودة على ال net مش ممكن الا انكم تطولوها تمام بكل الأحوال لما اللاجئ", "tokens": [2304, 43020, 8978, 6225, 9381, 2288, 9673, 30241, 20498, 9307, 8717, 32277, 19446, 1829, 28543, 2288, 2407, 8592, 7251, 9566, 12610, 14407, 5296, 2685, 12447, 5296, 2655, 2407, 4724, 1829, 35473, 7649, 12610, 1975, 2407, 5296, 2655, 2407, 9122, 1211, 13063, 2407, 4724, 1829, 35473, 7649, 12610, 29538, 20449, 1211, 20498, 3660, 38637, 16758, 2655, 3660, 30767, 1829, 19446, 1975, 7435, 1829, 1975, 39648, 24793, 46811, 10943, 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{"start": 219.77, "end": 219.99, "word": " net", "probability": 0.38134765625}, {"start": 219.99, "end": 220.25, "word": " مش", "probability": 0.919921875}, {"start": 220.25, "end": 220.69, "word": " ممكن", "probability": 0.986328125}, {"start": 220.69, "end": 221.13, "word": " الا", "probability": 0.88671875}, {"start": 221.13, "end": 221.97, "word": " انكم", "probability": 0.879150390625}, {"start": 221.97, "end": 222.55, "word": " تطولوها", "probability": 0.86015625}, {"start": 222.55, "end": 222.97, "word": " تمام", "probability": 0.840576171875}, {"start": 222.97, "end": 223.93, "word": " بكل", "probability": 0.6617431640625}, {"start": 223.93, "end": 224.61, "word": " الأحوال", "probability": 0.9237060546875}, {"start": 224.61, "end": 225.45, "word": " لما", "probability": 0.8994140625}, {"start": 225.45, "end": 226.33, "word": " اللاجئ", "probability": 0.5550944010416666}], "temperature": 1.0}, {"id": 10, "seek": 24696, "start": 227.74, "end": 246.96, "text": "لأيزومر معين ل specific rotation كأنه انا عندى لأيزومر التانى مباشرة يعني لما يكون واحد موجب بمقدار معين التانى بيكون سالب بنفس المقدار الان لاحظوا معايا لو حطينا المركب الموجب", "tokens": [1211, 10721, 1829, 11622, 20498, 2288, 20449, 9957, 5296, 2685, 12447, 9122, 33456, 3224, 1975, 8315, 43242, 7578, 5296, 10721, 1829, 11622, 20498, 2288, 16712, 7649, 7578, 3714, 3555, 33599, 25720, 37495, 22653, 5296, 15042, 7251, 30544, 36764, 24401, 3714, 29245, 3555, 4724, 2304, 28543, 9640, 20449, 9957, 16712, 7649, 7578, 4724, 1829, 30544, 8608, 6027, 3555, 44945, 36178, 9673, 28543, 9640, 2423, 7649, 20193, 5016, 19913, 14407, 20449, 995, 25528, 45164, 11331, 9566, 1829, 8315, 9673, 31747, 3555, 9673, 29245, 3555], "avg_logprob": -0.16763931297394166, "compression_ratio": 1.7055555555555555, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 227.74, "end": 229.0, "word": "لأيزومر", "probability": 0.65234375}, {"start": 229.0, "end": 229.56, "word": " معين", "probability": 0.959716796875}, 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الضوء", "probability": 0.906494140625}, {"start": 252.29, "end": 253.03, "word": " هذا", "probability": 0.71337890625}, {"start": 253.03, "end": 253.75, "word": " الجزء", "probability": 0.9078776041666666}, {"start": 253.75, "end": 253.99, "word": " اللي", "probability": 0.7362060546875}, {"start": 253.99, "end": 254.33, "word": " بلوف", "probability": 0.8347981770833334}, {"start": 254.33, "end": 254.75, "word": " الضوء", "probability": 0.968017578125}, {"start": 254.75, "end": 255.35, "word": " الآن", "probability": 0.759521484375}, {"start": 255.35, "end": 256.09, "word": " بنقول", "probability": 0.814208984375}, {"start": 256.09, "end": 256.65, "word": " عنه", "probability": 0.977783203125}, {"start": 256.65, "end": 258.03, "word": " مصطلح", "probability": 0.99033203125}, {"start": 258.03, "end": 258.97, "word": " chiral", "probability": 0.677490234375}, {"start": 258.97, "end": 259.71, "word": " molecule", "probability": 0.83056640625}, {"start": 259.71, "end": 260.57, "word": " 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optically active ولا inactive؟ inactive، لو انا حاطيت ميه في مسار الضوء", "tokens": [3224, 1211, 23758, 35186, 6055, 2288, 7578, 4724, 9640, 3555, 3615, 29910, 2288, 9307, 44650, 8592, 16758, 3224, 3660, 8978, 9122, 995, 13546, 6027, 9122, 9640, 3555, 11536, 22807, 8978, 9154, 3224, 1975, 2655, 1863, 9957, 22807, 19446, 41185, 8592, 9154, 3224, 32771, 13546, 36764, 24401, 12399, 1975, 15730, 23758, 45164, 1975, 8315, 11331, 41193, 36081, 3224, 4724, 2304, 3794, 9640, 6024, 114, 2407, 38207, 12399, 4724, 1829, 30544, 2427, 984, 4967, 49429, 294, 12596, 22807, 294, 12596, 12399, 45164, 1975, 8315, 11331, 41193, 36081, 3714, 1829, 3224, 8978, 47524, 9640, 6024, 114, 2407, 38207], "avg_logprob": -0.18945311894640326, "compression_ratio": 1.7486631016042782, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 356.09, "end": 356.43, "word": "هل", "probability": 0.97216796875}, {"start": 356.43, "end": 356.71, "word": " هذا", "probability": 0.94677734375}, {"start": 356.71, "end": 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"word": " منه", "probability": 0.993896484375}, {"start": 363.81, "end": 364.07, "word": " غير", "probability": 0.960205078125}, {"start": 364.07, "end": 364.83, "word": " واحد،", "probability": 0.80419921875}, {"start": 364.83, "end": 365.09, "word": " اذا", "probability": 0.77978515625}, {"start": 365.09, "end": 365.47, "word": " هذا", "probability": 0.7294921875}, {"start": 365.47, "end": 365.63, "word": " لو", "probability": 0.9892578125}, {"start": 365.63, "end": 365.85, "word": " انا", "probability": 0.85791015625}, {"start": 365.85, "end": 366.35, "word": " حاطيته", "probability": 0.86328125}, {"start": 366.35, "end": 366.91, "word": " بمسار", "probability": 0.7506103515625}, {"start": 366.91, "end": 367.69, "word": " الضوء،", "probability": 0.92509765625}, {"start": 367.69, "end": 368.01, "word": " بيكون", "probability": 0.9241536458333334}, {"start": 368.01, "end": 368.63, "word": " optically", "probability": 0.624267578125}, {"start": 368.63, "end": 369.09, "word": " active", 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حطيت مثلا Dichloromethane CH2 Cl2 بكون Optically Active ولا Inactive؟ Inactive لأنه عشان يبدأ يصير أحد ال enantiomers في وجود chiral center واحد المفروض يكون عندى أربع مجموعات مختلفة فخلينا نقول انه نسبة كبيرة جدا من المراكبات العضوية أساسا", "tokens": [3555, 30544, 21455, 984, 26635, 49429, 682, 12596, 22807, 682, 12596, 45164, 1975, 8315, 11331, 9566, 36081, 50113, 15040, 413, 480, 6746, 649, 71, 1929, 5995, 17, 2033, 17, 4724, 30544, 21455, 984, 26635, 49429, 682, 12596, 22807, 682, 12596, 5296, 33456, 3224, 6225, 8592, 7649, 7251, 44510, 10721, 7251, 9381, 13546, 5551, 24401, 2423, 465, 11520, 298, 433, 8978, 49610, 23328, 23782, 304, 3056, 36764, 24401, 9673, 5172, 32887, 11242, 7251, 30544, 43242, 7578, 5551, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660, 6156, 9778, 1211, 9957, 995, 8717, 39648, 16472, 3224, 8717, 35457, 3660, 9122, 3555, 48923, 10874, 28259, 9154, 9673, 23557, 4117, 3555, 9307, 18863, 11242, 2407, 10632, 5551, 3794, 32277, 995], 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Dichloromethane", "probability": 0.7509562174479166}, {"start": 381.68, "end": 383.12, "word": " CH2", "probability": 0.922119140625}, {"start": 383.12, "end": 384.74, "word": " Cl2", "probability": 0.617919921875}, {"start": 384.74, "end": 385.28, "word": " بكون", "probability": 0.808837890625}, {"start": 385.28, "end": 385.8, "word": " Optically", "probability": 0.93603515625}, {"start": 385.8, "end": 386.24, "word": " Active", "probability": 0.953125}, {"start": 386.24, "end": 386.48, "word": " ولا", "probability": 0.94140625}, {"start": 386.48, "end": 387.34, "word": " Inactive؟", "probability": 0.9314778645833334}, {"start": 387.34, "end": 388.42, "word": " Inactive", "probability": 0.9638671875}, {"start": 388.42, "end": 389.0, "word": " لأنه", "probability": 0.6953125}, {"start": 389.0, "end": 389.96, "word": " عشان", "probability": 0.9786783854166666}, {"start": 389.96, "end": 390.46, "word": " يبدأ", "probability": 0.9899088541666666}, {"start": 390.46, "end": 390.8, "word": " يصير", "probability": 0.98876953125}, {"start": 390.8, "end": 391.2, "word": " أحد", "probability": 0.78125}, {"start": 391.2, "end": 391.38, "word": " ال", "probability": 0.9501953125}, {"start": 391.38, "end": 392.4, "word": " enantiomers", "probability": 0.7257080078125}, {"start": 392.4, "end": 392.82, "word": " في", "probability": 0.92578125}, {"start": 392.82, "end": 393.18, "word": " وجود", "probability": 0.966064453125}, {"start": 393.18, "end": 393.62, "word": " chiral", "probability": 0.685546875}, {"start": 393.62, "end": 393.92, "word": " center", "probability": 0.80908203125}, {"start": 393.92, "end": 394.34, "word": " واحد", "probability": 0.85546875}, {"start": 394.34, "end": 395.18, "word": " المفروض", "probability": 0.989013671875}, {"start": 395.18, "end": 395.4, "word": " يكون", "probability": 0.977294921875}, {"start": 395.4, "end": 395.68, "word": " عندى", "probability": 0.67578125}, {"start": 395.68, "end": 395.94, "word": " أربع", "probability": 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0.9737548828125}], "temperature": 1.0}, {"id": 18, "seek": 41522, "start": 404.94, "end": 415.22, "text": "بتكون A chiral لاحظوا معاه هنا بنيجي لنقطة كتير مهمة لما وصفنا مركب انه chiral بمعنى هو أحد", "tokens": [3555, 2655, 30544, 316, 23782, 304, 20193, 5016, 19913, 14407, 20449, 40294, 34105, 44945, 1829, 7435, 1829, 5296, 1863, 47432, 3660, 9122, 2655, 13546, 3714, 16095, 3660, 5296, 15042, 4032, 9381, 5172, 8315, 3714, 31747, 3555, 16472, 3224, 23782, 304, 4724, 2304, 3615, 1863, 7578, 31439, 5551, 24401], "avg_logprob": -0.19786351554247797, "compression_ratio": 1.2459016393442623, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 404.94, "end": 405.94, "word": "بتكون", "probability": 0.7762858072916666}, {"start": 405.94, "end": 406.58, "word": " A", "probability": 0.2119140625}, {"start": 406.58, "end": 407.32, "word": " chiral", "probability": 0.59783935546875}, {"start": 407.32, "end": 408.2, "word": " لاحظوا", "probability": 0.8719482421875}, {"start": 408.2, 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421.43, "end": 422.47, "word": " enanchomars", "probability": 0.539520263671875}, {"start": 422.47, "end": 423.27, "word": " هذا", "probability": 0.8955078125}, {"start": 423.27, "end": 423.89, "word": " المركب", "probability": 0.8665364583333334}, {"start": 423.89, "end": 424.05, "word": " لو", "probability": 0.98681640625}, {"start": 424.05, "end": 424.55, "word": " حاطيته", "probability": 0.8609619140625}, {"start": 424.55, "end": 425.13, "word": " لحاله", "probability": 0.988525390625}, {"start": 425.13, "end": 425.73, "word": " بقول", "probability": 0.9658203125}, {"start": 425.73, "end": 426.03, "word": " عنه", "probability": 0.976318359375}, {"start": 426.03, "end": 426.61, "word": " chiral", "probability": 0.9248046875}, {"start": 426.61, "end": 427.05, "word": " بلف", "probability": 0.84033203125}, {"start": 427.05, "end": 427.39, "word": " الضوء", "probability": 0.96728515625}, {"start": 427.39, "end": 427.99, "word": " بزاوية", "probability": 0.94541015625}, {"start": 427.99, "end": 429.03, "word": " معينة", "probability": 0.9752604166666666}, {"start": 429.03, "end": 429.77, "word": " الآن", "probability": 0.6673583984375}, {"start": 429.77, "end": 430.65, "word": " ال", "probability": 0.88037109375}, {"start": 430.65, "end": 431.27, "word": " enanchomar", "probability": 0.6666259765625}, {"start": 431.27, "end": 431.67, "word": " التاني", "probability": 0.7858072916666666}, {"start": 431.67, "end": 431.83, "word": " لو", "probability": 0.97509765625}, {"start": 431.83, "end": 432.41, "word": " حاطيته", "probability": 0.986083984375}, {"start": 432.41, "end": 432.51, "word": " في", "probability": 0.87890625}, {"start": 432.51, "end": 432.61, "word": " ال", "probability": 0.7392578125}, {"start": 432.61, "end": 434.09, "word": " polarimeter", "probability": 0.5748291015625}, {"start": 434.09, "end": 434.53, "word": " برضه", "probability": 0.78369140625}, {"start": 434.53, "end": 435.21, "word": " chiral", "probability": 0.925048828125}, {"start": 435.21, "end": 436.23, "word": " بنسميه", "probability": 0.94140625}, {"start": 436.23, "end": 436.85, "word": " بلف", "probability": 0.870849609375}, {"start": 436.85, "end": 437.19, "word": " الضوء", "probability": 0.98583984375}, {"start": 437.19, "end": 437.63, "word": " ولكن", "probability": 0.879638671875}, {"start": 437.63, "end": 438.35, "word": " باتجاه", "probability": 0.9117431640625}], "temperature": 1.0}, {"id": 20, "seek": 46718, "start": 439.42, "end": 467.18, "text": "معاكس إذا صار عندى مركب chiral و مركب chiral طيب لو حطيت مركب من الأساس مافيه chiral center بلفش الضوء وجدت إيش بدى أسمي هذا المركب A chiral هنا ال A بتصير أداة نفي لاحظوا معناه .. لاحظوا معناه بتكونوا فاهمين شوية باللغة الإنجليزية أدوات النكرة و أدوات المعرفة يعني المركب هنا .. المركب هنا", "tokens": [2304, 3615, 995, 4117, 3794, 11933, 15730, 20328, 9640, 43242, 7578, 3714, 31747, 3555, 23782, 304, 4032, 3714, 31747, 3555, 23782, 304, 23032, 1829, 3555, 45164, 11331, 9566, 36081, 3714, 31747, 3555, 9154, 16247, 3794, 32277, 19446, 41185, 3224, 23782, 304, 3056, 4724, 1211, 5172, 8592, 6024, 114, 2407, 38207, 49610, 3215, 2655, 11933, 1829, 8592, 47525, 7578, 5551, 38251, 1829, 23758, 9673, 31747, 3555, 316, 23782, 304, 34105, 2423, 316, 39894, 9381, 13546, 5551, 28259, 3660, 8717, 41185, 20193, 5016, 19913, 14407, 20449, 8315, 3224, 4386, 20193, 5016, 19913, 14407, 20449, 8315, 3224, 39894, 30544, 14407, 6156, 995, 16095, 9957, 13412, 2407, 10632, 20666, 1211, 17082, 3660, 33688, 1863, 7435, 20292, 11622, 10632, 5551, 3215, 2407, 9307, 28239, 4117, 25720, 4032, 5551, 3215, 2407, 9307, 9673, 3615, 28480, 3660, 37495, 22653, 9673, 31747, 3555, 34105, 4386, 9673, 31747, 3555, 34105], "avg_logprob": -0.18364877222289502, "compression_ratio": 1.9291338582677164, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 439.42, "end": 440.22, "word": "معاكس", "probability": 0.953125}, {"start": 440.22, "end": 440.6, "word": " إذا", "probability": 0.687744140625}, {"start": 440.6, "end": 440.9, "word": " صار", "probability": 0.8505859375}, {"start": 440.9, "end": 441.14, "word": " عندى", "probability": 0.73095703125}, {"start": 441.14, "end": 441.56, "word": " مركب", "probability": 0.8084309895833334}, {"start": 441.56, "end": 442.12, "word": " chiral", "probability": 0.6153564453125}, {"start": 442.12, "end": 442.36, "word": " و", "probability": 0.962890625}, {"start": 442.36, "end": 442.82, "word": " مركب", "probability": 0.7962239583333334}, {"start": 442.82, "end": 443.22, "word": " chiral", "probability": 0.93798828125}, {"start": 443.22, "end": 443.74, "word": " طيب", "probability": 0.8650716145833334}, {"start": 443.74, "end": 443.88, "word": " لو", "probability": 0.9609375}, {"start": 443.88, "end": 444.26, "word": " حطيت", "probability": 0.8361002604166666}, {"start": 444.26, "end": 444.7, "word": " مركب", "probability": 0.9833984375}, {"start": 444.7, "end": 444.84, "word": " من", "probability": 0.91845703125}, {"start": 444.84, "end": 445.26, "word": " الأساس", "probability": 0.9599609375}, {"start": 445.26, "end": 445.66, "word": " مافيه", "probability": 0.6956380208333334}, {"start": 445.66, "end": 446.28, "word": " chiral", "probability": 0.895263671875}, {"start": 446.28, "end": 446.72, "word": " center", "probability": 0.8134765625}, {"start": 446.72, "end": 447.28, "word": " بلفش", "probability": 0.56884765625}, {"start": 447.28, "end": 447.64, "word": " الضوء", "probability": 0.9061279296875}, {"start": 447.64, "end": 448.3, "word": " وجدت", "probability": 0.6856689453125}, {"start": 448.3, "end": 448.44, "word": " إيش", "probability": 0.8369140625}, {"start": 448.44, "end": 448.66, "word": " بدى", "probability": 0.6854248046875}, {"start": 448.66, "end": 449.2, "word": " أسمي", "probability": 0.8621419270833334}, {"start": 449.2, "end": 449.4, "word": " هذا", "probability": 0.94482421875}, {"start": 449.4, "end": 450.16, "word": " المركب", "probability": 0.98388671875}, {"start": 450.16, "end": 451.44, "word": " A", "probability": 0.1558837890625}, {"start": 451.44, "end": 452.44, "word": " chiral", "probability": 0.93212890625}, {"start": 452.44, "end": 452.78, "word": " هنا", "probability": 0.69873046875}, {"start": 452.78, "end": 453.04, "word": " ال", "probability": 0.97607421875}, {"start": 453.04, "end": 453.3, "word": " A", "probability": 0.55908203125}, {"start": 453.3, "end": 453.92, "word": " بتصير", "probability": 0.8938802083333334}, {"start": 453.92, "end": 454.38, "word": " أداة", "probability": 0.8356119791666666}, {"start": 454.38, "end": 454.84, "word": " نفي", "probability": 0.8779296875}, {"start": 454.84, "end": 455.74, "word": " لاحظوا", "probability": 0.9276123046875}, {"start": 455.74, "end": 456.36, "word": " معناه", "probability": 0.8580729166666666}, {"start": 456.36, "end": 456.4, "word": " ..", "probability": 0.478759765625}, {"start": 456.4, "end": 456.78, "word": " لاحظوا", "probability": 0.9234619140625}, {"start": 456.78, "end": 457.18, "word": " معناه", "probability": 0.9889322916666666}, {"start": 457.18, "end": 457.84, "word": " بتكونوا", "probability": 0.8445638020833334}, {"start": 457.84, "end": 458.26, "word": " فاهمين", "probability": 0.908447265625}, {"start": 458.26, "end": 458.84, "word": " شوية", "probability": 0.8082682291666666}, {"start": 458.84, "end": 459.6, "word": " باللغة", "probability": 0.9874267578125}, {"start": 459.6, "end": 460.58, "word": " الإنجليزية", "probability": 0.9171549479166666}, {"start": 460.58, "end": 461.8, "word": " أدوات", "probability": 0.96630859375}, {"start": 461.8, "end": 462.74, "word": " النكرة", "probability": 0.80712890625}, {"start": 462.74, "end": 463.0, "word": " و", "probability": 0.84619140625}, {"start": 463.0, "end": 463.58, "word": " أدوات", "probability": 0.974365234375}, {"start": 463.58, "end": 464.42, "word": " المعرفة", "probability": 0.995361328125}, {"start": 464.42, "end": 464.88, "word": " يعني", "probability": 0.884033203125}, {"start": 464.88, "end": 465.58, "word": " المركب", "probability": 0.98193359375}, {"start": 465.58, "end": 466.0, "word": " هنا", "probability": 0.9853515625}, {"start": 466.0, "end": 466.22, "word": " ..", "probability": 0.70654296875}, {"start": 466.22, "end": 466.86, "word": " المركب", "probability": 0.9837239583333334}, {"start": 466.86, "end": 467.18, "word": " هنا", "probability": 0.9951171875}], "temperature": 1.0}, {"id": 21, "seek": 49610, "start": 468.9, "end": 496.1, "text": "كايرال ال a اللي موجودة فيه هي أداة نكرة ولذلك إذا أنا مثلا بدي أجي أحكي باللغة الإنقليزية أقول this is a chiral compound معناه ذلك هذا مركب بلف الضوء ال a أداة نكرة زي ما بنيجي نقول this is a table this is a pen واضح الفكرة؟ الآن لو كنت بدي أحكي عن مركب زي هذا شو بدي أقول عنه؟", "tokens": [4117, 995, 13546, 6027, 2423, 257, 13672, 1829, 3714, 29245, 23328, 3660, 8978, 3224, 39896, 5551, 28259, 3660, 8717, 4117, 25720, 35525, 8848, 23275, 11933, 15730, 41850, 50113, 15040, 4724, 16254, 5551, 7435, 1829, 5551, 5016, 4117, 1829, 20666, 1211, 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0.815185546875}, {"start": 470.84, "end": 471.62, "word": " موجودة", "probability": 0.96044921875}, {"start": 471.62, "end": 472.0, "word": " فيه", "probability": 0.947998046875}, {"start": 472.0, "end": 472.46, "word": " هي", "probability": 0.80322265625}, {"start": 472.46, "end": 473.1, "word": " أداة", "probability": 0.8512369791666666}, {"start": 473.1, "end": 473.8, "word": " نكرة", "probability": 0.869140625}, {"start": 473.8, "end": 475.16, "word": " ولذلك", "probability": 0.84619140625}, {"start": 475.16, "end": 475.46, "word": " إذا", "probability": 0.81298828125}, {"start": 475.46, "end": 475.66, "word": " أنا", "probability": 0.7763671875}, {"start": 475.66, "end": 475.86, "word": " مثلا", "probability": 0.893310546875}, {"start": 475.86, "end": 476.06, "word": " بدي", "probability": 0.6978759765625}, {"start": 476.06, "end": 476.26, "word": " أجي", "probability": 0.677490234375}, {"start": 476.26, "end": 476.5, "word": " أحكي", "probability": 0.9581298828125}, {"start": 476.5, "end": 476.78, "word": " باللغة", "probability": 0.98388671875}, {"start": 476.78, "end": 477.36, "word": " الإنقليزية", "probability": 0.8899739583333334}, {"start": 477.36, "end": 477.74, "word": " أقول", "probability": 0.84716796875}, {"start": 477.74, "end": 478.32, "word": " this", "probability": 0.82275390625}, {"start": 478.32, "end": 478.92, "word": " is", "probability": 0.9638671875}, {"start": 478.92, "end": 479.48, "word": " a", "probability": 0.98095703125}, {"start": 479.48, "end": 480.34, "word": " chiral", "probability": 0.7139892578125}, {"start": 480.34, "end": 480.98, "word": " compound", "probability": 0.9541015625}, {"start": 480.98, "end": 481.66, "word": " معناه", "probability": 0.7819010416666666}, {"start": 481.66, "end": 481.94, "word": " ذلك", "probability": 0.978759765625}, {"start": 481.94, "end": 482.3, "word": " هذا", "probability": 0.95263671875}, {"start": 482.3, "end": 483.1, "word": " مركب", "probability": 0.8580729166666666}, {"start": 483.1, "end": 483.88, "word": " بلف", "probability": 0.890380859375}, {"start": 483.88, "end": 484.82, "word": " الضوء", "probability": 0.9515380859375}, {"start": 484.82, "end": 485.24, "word": " ال", "probability": 0.9287109375}, {"start": 485.24, "end": 485.46, "word": " a", "probability": 0.93505859375}, {"start": 485.46, "end": 485.9, "word": " أداة", "probability": 0.93310546875}, {"start": 485.9, "end": 486.26, "word": " نكرة", "probability": 0.9677734375}, {"start": 486.26, "end": 486.74, "word": " زي", "probability": 0.927978515625}, {"start": 486.74, "end": 486.82, "word": " ما", "probability": 0.9345703125}, {"start": 486.82, "end": 487.08, "word": " بنيجي", "probability": 0.875}, {"start": 487.08, "end": 487.32, "word": " نقول", "probability": 0.877685546875}, {"start": 487.32, "end": 487.62, "word": " this", "probability": 0.95458984375}, {"start": 487.62, "end": 487.98, "word": " is", "probability": 0.95458984375}, {"start": 487.98, "end": 488.22, "word": " a", "probability": 0.978515625}, {"start": 488.22, "end": 488.74, "word": " table", "probability": 0.91650390625}, {"start": 488.74, "end": 489.32, "word": " this", "probability": 0.54443359375}, {"start": 489.32, "end": 489.6, "word": " is", "probability": 0.9638671875}, {"start": 489.6, "end": 489.88, "word": " a", "probability": 0.9931640625}, {"start": 489.88, "end": 490.26, "word": " pen", "probability": 0.47705078125}, {"start": 490.26, "end": 490.94, "word": " واضح", "probability": 0.9788411458333334}, {"start": 490.94, "end": 492.02, "word": " الفكرة؟", "probability": 0.78759765625}, {"start": 492.02, "end": 492.36, "word": " الآن", "probability": 0.6953125}, {"start": 492.36, "end": 492.72, "word": " لو", "probability": 0.9453125}, {"start": 492.72, "end": 492.94, "word": " كنت", "probability": 0.984130859375}, {"start": 492.94, "end": 493.14, "word": " بدي", "probability": 0.79052734375}, {"start": 493.14, "end": 493.36, "word": " أحكي", "probability": 0.9847412109375}, {"start": 493.36, "end": 493.5, "word": " عن", "probability": 0.98779296875}, {"start": 493.5, "end": 493.98, "word": " مركب", "probability": 0.9798177083333334}, {"start": 493.98, "end": 494.22, "word": " زي", "probability": 0.98291015625}, {"start": 494.22, "end": 494.56, "word": " هذا", "probability": 0.9775390625}, {"start": 494.56, "end": 495.0, "word": " شو", "probability": 0.91064453125}, {"start": 495.0, "end": 495.16, "word": " بدي", "probability": 0.955078125}, {"start": 495.16, "end": 495.52, "word": " أقول", "probability": 0.96142578125}, {"start": 495.52, "end": 496.1, "word": " عنه؟", "probability": 0.9767252604166666}], "temperature": 1.0}, {"id": 22, "seek": 51167, "start": 496.63, "end": 511.67, "text": "أكايرل، الآن هنا أكايرل كلمة واحدة لما بدي استعمل إلها أذات نكرة بالإنقليزي بدي أحفظ قدامها أن صارت هذه الكلمة كلمة واحدة أكايرل", "tokens": [10721, 4117, 995, 13546, 1211, 12399, 6024, 48506, 34105, 5551, 4117, 995, 13546, 1211, 9122, 19528, 3660, 36764, 24401, 3660, 5296, 15042, 4724, 16254, 44713, 25957, 1211, 11933, 1211, 11296, 5551, 8848, 9307, 8717, 4117, 25720, 20666, 28814, 1863, 4587, 20292, 11622, 1829, 4724, 16254, 5551, 5016, 5172, 19913, 12174, 3215, 10943, 11296, 14739, 20328, 9640, 2655, 29538, 33251, 19528, 3660, 9122, 19528, 3660, 36764, 24401, 3660, 5551, 4117, 995, 13546, 1211], "avg_logprob": -0.2564212394087282, "compression_ratio": 1.6956521739130435, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 496.63, "end": 497.93, "word": "أكايرل،", "probability": 0.6053263346354166}, {"start": 497.93, "end": 498.33, "word": " الآن", "probability": 0.62255859375}, {"start": 498.33, "end": 498.69, "word": " هنا", "probability": 0.845703125}, {"start": 498.69, "end": 499.57, "word": " أكايرل", "probability": 0.9416015625}, {"start": 499.57, "end": 500.47, "word": " كلمة", "probability": 0.87109375}, {"start": 500.47, "end": 501.11, "word": " واحدة", "probability": 0.9938151041666666}, {"start": 501.11, "end": 501.59, "word": " لما", "probability": 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"probability": 0.9208984375}, {"start": 596.89, "end": 597.81, "word": " يهدم", "probability": 0.9806315104166666}, {"start": 597.81, "end": 598.97, "word": " واضح", "probability": 0.88818359375}, {"start": 598.97, "end": 600.07, "word": " الفكرة؟", "probability": 0.9493408203125}, {"start": 600.07, "end": 600.63, "word": " ولذلك", "probability": 0.83740234375}, {"start": 600.63, "end": 601.09, "word": " إذا", "probability": 0.848388671875}, {"start": 601.09, "end": 601.37, "word": " كان", "probability": 0.99267578125}, {"start": 601.37, "end": 601.73, "word": " عندى", "probability": 0.6044921875}, {"start": 601.73, "end": 602.45, "word": " خليط", "probability": 0.9208984375}, {"start": 602.45, "end": 603.39, "word": " متساوي", "probability": 0.9688720703125}, {"start": 603.39, "end": 603.47, "word": " ..", "probability": 0.272216796875}, {"start": 603.47, "end": 603.69, "word": " إذا", "probability": 0.857666015625}, {"start": 603.69, "end": 603.93, "word": " كان", "probability": 0.99658203125}, {"start": 603.93, "end": 604.21, "word": " عندى", "probability": 0.9326171875}, {"start": 604.21, "end": 604.65, "word": " خليط", "probability": 0.9811197916666666}, {"start": 604.65, "end": 605.59, "word": " متساوي", "probability": 0.9901123046875}, {"start": 605.59, "end": 606.07, "word": " من", "probability": 0.97314453125}, {"start": 606.07, "end": 606.27, "word": " ال", "probability": 0.94140625}, {"start": 606.27, "end": 606.45, "word": " two", "probability": 0.7568359375}, {"start": 606.45, "end": 607.65, "word": " enansomers", "probability": 0.444122314453125}, {"start": 607.65, "end": 608.51, "word": " بتكون", "probability": 0.948974609375}, {"start": 608.51, "end": 609.43, "word": " إيش؟", "probability": 0.8948974609375}], "temperature": 1.0}, {"id": 27, "seek": 62829, "start": 610.32, "end": 628.3, "text": "الخليط chiral ولا achiral كله optically active ولا optically inactive؟ optically inactive طبعا هنا ممكن يجيني السؤال طب يا تورا لو كان عندي خليط بنسب غير متساوية", "tokens": [6027, 9778, 20292, 9566, 23782, 304, 49429, 2800, 35083, 28242, 3224, 2427, 984, 4967, 49429, 2427, 984, 294, 12596, 22807, 2427, 984, 294, 12596, 23032, 3555, 3615, 995, 34105, 3714, 43020, 7251, 7435, 9957, 1829, 21136, 33604, 6027, 23032, 3555, 35186, 6055, 13063, 995, 45164, 25961, 18871, 16254, 16490, 20292, 9566, 44945, 35457, 32771, 13546, 44650, 3794, 995, 2407, 10632], "avg_logprob": -0.13524590457072022, "compression_ratio": 1.5096774193548388, "no_speech_prob": 0.0, "words": [{"start": 610.32, "end": 611.56, "word": "الخليط", "probability": 0.9085693359375}, {"start": 611.56, "end": 612.72, "word": " chiral", "probability": 0.865478515625}, {"start": 612.72, "end": 613.04, "word": " ولا", "probability": 0.720703125}, {"start": 613.04, "end": 614.26, "word": " achiral", "probability": 0.789306640625}, {"start": 614.26, "end": 615.12, "word": " كله", "probability": 0.789794921875}, {"start": 615.12, "end": 615.82, "word": " optically", "probability": 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0.813720703125}, {"start": 622.96, "end": 623.26, "word": " يا", "probability": 0.90478515625}, {"start": 623.26, "end": 623.72, "word": " تورا", "probability": 0.7278645833333334}, {"start": 623.72, "end": 624.08, "word": " لو", "probability": 0.98095703125}, {"start": 624.08, "end": 624.36, "word": " كان", "probability": 0.978515625}, {"start": 624.36, "end": 624.66, "word": " عندي", "probability": 0.765869140625}, {"start": 624.66, "end": 626.02, "word": " خليط", "probability": 0.9505208333333334}, {"start": 626.02, "end": 626.74, "word": " بنسب", "probability": 0.949462890625}, {"start": 626.74, "end": 627.2, "word": " غير", "probability": 0.99560546875}, {"start": 627.2, "end": 628.3, "word": " متساوية", "probability": 0.9580078125}], "temperature": 1.0}, {"id": 28, "seek": 64211, "start": 630.33, "end": 642.11, "text": "يعني مثلا خلطت من ال isomer الموجب نسبة 70% من ال isomer السالب نسبة 30% هذا الخليط", "tokens": [40228, 22653, 50113, 15040, 16490, 1211, 9566, 2655, 9154, 2423, 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جزئي تماما زي ما بنيجي نقول مثلا بني ادم الله ربح سبعين كذا خسر تلاتين كدهش في النهاية؟", "tokens": [3224, 1829, 30544, 2427, 984, 4967, 23758, 33962, 20292, 9566, 39896, 30544, 2427, 984, 4967, 35525, 19452, 4724, 8592, 28820, 1975, 1829, 8592, 22807, 10874, 11622, 19986, 1829, 4724, 8592, 28820, 10874, 11622, 19986, 1829, 46811, 10943, 995, 30767, 1829, 19446, 44945, 1829, 7435, 1829, 8717, 39648, 50113, 15040, 4724, 22653, 1975, 40448, 21984, 12602, 49628, 8608, 3555, 3615, 9957, 9122, 15730, 16490, 3794, 2288, 6055, 1211, 9307, 9957, 9122, 3215, 3224, 8592, 8978, 28239, 11296, 10632, 22807], "avg_logprob": -0.18552215831189217, "compression_ratio": 1.606936416184971, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 644.42, "end": 645.54, "word": "هيكون", "probability": 0.8170572916666666}, {"start": 645.54, "end": 646.66, "word": " optically", "probability": 0.732666015625}, {"start": 646.66, "end": 648.34, "word": " active", "probability": 0.97021484375}, {"start": 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657.34, "end": 657.74, "word": " زي", "probability": 0.748779296875}, {"start": 657.74, "end": 657.78, "word": " ما", "probability": 0.955078125}, {"start": 657.78, "end": 658.14, "word": " بنيجي", "probability": 0.9044189453125}, {"start": 658.14, "end": 658.32, "word": " نقول", "probability": 0.974365234375}, {"start": 658.32, "end": 658.7, "word": " مثلا", "probability": 0.966796875}, {"start": 658.7, "end": 658.94, "word": " بني", "probability": 0.81591796875}, {"start": 658.94, "end": 659.24, "word": " ادم", "probability": 0.6976318359375}, {"start": 659.24, "end": 659.44, "word": " الله", "probability": 0.728515625}, {"start": 659.44, "end": 659.82, "word": " ربح", "probability": 0.97509765625}, {"start": 659.82, "end": 660.68, "word": " سبعين", "probability": 0.974609375}, {"start": 660.68, "end": 661.0, "word": " كذا", "probability": 0.819580078125}, {"start": 661.0, "end": 661.46, "word": " خسر", "probability": 0.9669596354166666}, {"start": 661.46, "end": 662.02, "word": " 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منه", "probability": 0.985595703125}, {"start": 2277.85, "end": 2278.47, "word": " اتنين", "probability": 0.918212890625}, {"start": 2278.47, "end": 2279.03, "word": " ممكن", "probability": 0.987060546875}, {"start": 2279.03, "end": 2279.51, "word": " تحطه", "probability": 0.87451171875}, {"start": 2279.51, "end": 2279.87, "word": " هان", "probability": 0.974609375}, {"start": 2279.87, "end": 2280.17, "word": " و", "probability": 0.97119140625}, {"start": 2280.17, "end": 2280.55, "word": " هان", "probability": 0.969970703125}, {"start": 2280.55, "end": 2282.15, "word": " بيصير", "probability": 0.9833984375}, {"start": 2282.15, "end": 2282.59, "word": " برضه", "probability": 0.8201497395833334}, {"start": 2282.59, "end": 2283.09, "word": " عندكم", "probability": 0.9697265625}, {"start": 2283.09, "end": 2283.81, "word": " one", "probability": 0.96533203125}, {"start": 2283.81, "end": 2284.33, "word": " chiral", "probability": 0.97021484375}, {"start": 2284.33, "end": 2284.89, "word": " center", "probability": 0.93408203125}, {"start": 2284.89, "end": 2285.57, "word": " في", "probability": 0.73388671875}, {"start": 2285.57, "end": 2285.87, "word": " منه", "probability": 0.907470703125}, {"start": 2285.87, "end": 2286.47, "word": " جديش", "probability": 0.6326497395833334}, {"start": 2286.47, "end": 2287.23, "word": " اتنين", "probability": 0.9814453125}, {"start": 2287.23, "end": 2287.71, "word": " ممكن", "probability": 0.988037109375}, {"start": 2287.71, "end": 2288.17, "word": " تحطه", "probability": 0.994140625}, {"start": 2288.17, "end": 2288.49, "word": " هان", "probability": 0.990234375}, {"start": 2288.49, "end": 2288.69, "word": " و", "probability": 0.99072265625}, {"start": 2288.69, "end": 2288.99, "word": " هان", "probability": 0.982177734375}], "temperature": 1.0}, {"id": 100, "seek": 231814, "start": 2290.14, "end": 2318.14, "text": "برضه عندكم one chiral center فى منه اتنين ممكن تحطوا هنا و هنا تخيلوا لما تحطوا هنا CL ما زال عندكم CH2 مش chiral و CH2 و CH2 و CH2 و هنا CH2CL مش chiral اذا لو انا جبتلكوا سؤال ال one five dichlorobentane has two stereoisomers طلعوا معاه هي كلور هي كلور", "tokens": [3555, 43042, 3224, 43242, 24793, 472, 23782, 304, 3056, 6156, 7578, 9154, 3224, 1975, 2655, 1863, 9957, 3714, 43020, 6055, 5016, 9566, 14407, 34105, 4032, 34105, 6055, 9778, 26895, 14407, 5296, 15042, 6055, 5016, 9566, 14407, 34105, 12855, 19446, 30767, 6027, 43242, 24793, 5995, 17, 37893, 23782, 304, 4032, 5995, 17, 4032, 5995, 17, 4032, 5995, 17, 4032, 34105, 5995, 17, 22458, 37893, 23782, 304, 1975, 15730, 45164, 1975, 8315, 10874, 3555, 2655, 23275, 14407, 8608, 33604, 6027, 2423, 472, 1732, 274, 480, 6746, 996, 317, 1929, 575, 732, 12730, 7376, 298, 433, 23032, 1211, 3615, 14407, 20449, 40294, 39896, 28242, 13063, 39896, 28242, 13063], "avg_logprob": -0.2069575459046184, "compression_ratio": 1.6772727272727272, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2290.14, "end": 2290.56, "word": "برضه", "probability": 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b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_postprocess.srt @@ -0,0 +1,1844 @@ +1 +00:00:20,990 --> 00:00:24,950 +بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في + +2 +00:00:24,950 --> 00:00:29,290 +تفاعلات ال alkenes وقلنا اللى بينظر للموضوع نظرة + +3 +00:00:29,290 --> 00:00:34,610 +كلية الموضوع بسيط الموضوع انه double bond هيوم + +4 +00:00:34,610 --> 00:00:40,230 +رابطتين بالاضافة بتصير single bond هذه العملية شو + +5 +00:00:40,230 --> 00:00:46,110 +بنسميها عملية addition عملية addition واتفقنا ان + +6 +00:00:46,110 --> 00:00:48,810 +في ال addition فى عندنا مكونات لل addition فى + +7 +00:00:48,810 --> 00:00:52,730 +عندنا ال alkeneو في عندنا ال reagent وهذا ممكن + +8 +00:00:52,730 --> 00:00:56,610 +يكون symmetric و لا unsymmetric وهذا نفس الشيء و + +9 +00:00:56,610 --> 00:00:59,610 +دائما قلنا بدنا ننتبه لو كان في عندنا + +10 +00:00:59,610 --> 00:01:03,550 +unsymmetrical alkene مع unsymmetrical reagent + +11 +00:01:03,550 --> 00:01:09,070 +بنتوقع انه بيكون عندنا two products الآن هنبدأ + +12 +00:01:09,070 --> 00:01:13,510 +ناخد أمثلة على هذا الموضوع تحديدا لو بدنا نتكلم + +13 +00:01:13,510 --> 00:01:18,580 +على إضافة الماءإضافة الماء، الماء بيضيف جزء إيه؟ + +14 +00:01:18,580 --> 00:01:25,940 +بيضيف H و O H هذه العملية بنسميها hydration لاحظوا + +15 +00:01:25,940 --> 00:01:30,780 +أنه عمليات الإضافة حسب ال reagent يعني المرة + +16 +00:01:30,780 --> 00:01:35,840 +الماضية إحنا لما إضفنا ال hydrogen عملية إضافة ال + +17 +00:01:35,840 --> 00:01:42,940 +hydrogen hydrogenation اسمها واضح؟عملية إضافة + +18 +00:01:42,940 --> 00:01:49,120 +الهيدروجين الان ممكن نضيف الهالوجين بشكل عام + +19 +00:01:49,120 --> 00:01:57,020 +بنسميها الهالوجيناشن طبعا بشكل خاص إكلوريناشن + +20 +00:01:57,020 --> 00:02:05,100 +بروميناشن و هكذا ممكن نضيف الميه بنسميها هيدريشن + +21 +00:02:05,100 --> 00:02:14,210 +إضافة الميهHydration واضح؟ ممكن نضيف HX خلّينا + +22 +00:02:14,210 --> 00:02:22,530 +نقول HBR و لا HCL على الطرفين الرابطة HX بنسميها + +23 +00:02:22,530 --> 00:02:27,530 +Hydro لأن فيها Hydrogen Hydro وHalogen + +24 +00:02:27,530 --> 00:02:34,730 +Halogenation Hydro Halogenation كل هذه العمليات هي + +25 +00:02:34,730 --> 00:02:40,670 +عمليات إيش؟إضافة إذا إليها أسماء hydrogenation, + +26 +00:02:40,750 --> 00:02:44,430 +halogenation, hydration, hydrohalogenation + +27 +00:02:44,430 --> 00:02:49,010 +ابتفاعلات تانية هنتعلمها بعدين و هتلاحظوا إنه في + +28 +00:02:49,010 --> 00:02:53,430 +الكيميا العضوية دائما عندكم الشغلات المتعاكسة + +29 +00:02:53,430 --> 00:02:57,770 +بمعنىان ال double bond لما اضيف عليها reagent + +30 +00:02:57,770 --> 00:03:01,370 +بتصير single bond يعني لو افترضنا ان هاي double + +31 +00:03:01,370 --> 00:03:06,030 +bond اضفت عليها reagent الناتج single bond الان لو + +32 +00:03:06,030 --> 00:03:11,470 +هذه ال single bond ابتفاعل تاني رفعت منها شغلتين + +33 +00:03:11,470 --> 00:03:16,510 +هتصير double bond اذا انا ممكن اعمل اضافة و ممكن + +34 +00:03:16,510 --> 00:03:22,760 +اعمل حذفواضح ال elimination بسميه فزي ما في عند ا + +35 +00:03:22,760 --> 00:03:28,840 +addition في عند كمان عكسه elimination هذه عمليات + +36 +00:03:28,840 --> 00:03:34,860 +ال elimination أيضا لها أسماء بمعنى لو كنا بنحذف + +37 +00:03:34,860 --> 00:03:39,240 +ذرتين هيدروجين و بنعمل double bond تاني هنسمي + +38 +00:03:39,240 --> 00:03:44,880 +العملية dehydrogenation هستخدم ل prefix دي هذا + +39 +00:03:44,880 --> 00:03:51,360 +للنفيD فحقول dehydrogenation لو كنت برفع زرتين + +40 +00:03:51,360 --> 00:03:58,300 +كلور او بروم Dehydrogenation لو كنت برفع HOH + +41 +00:03:58,300 --> 00:04:03,900 +Dehydration هذه الكلمة الشهيرة نزع الماء + +42 +00:04:03,900 --> 00:04:07,520 +Dehydration + +43 +00:04:08,520 --> 00:04:12,700 +لو كنا بنرفع ال .. ال hydrogen وال halogen + +44 +00:04:12,700 --> 00:04:17,120 +dehydrohalogenation واضح؟ dehydrohalogenation + +45 +00:04:17,120 --> 00:04:21,640 +ولذلك بتلاقوا هذه الكلمة انتبهولها جيدا واحفظوها + +46 +00:04:21,640 --> 00:04:26,460 +انتوا في المستقبل بتصيروا أمهات dehydration لما + +47 +00:04:26,460 --> 00:04:30,620 +الأطفال الصغار بيمرضوا بتروح فيهم على المستشفيات + +48 +00:04:30,620 --> 00:04:35,630 +بيكون ..عندهم جفاف فالطبيب ايش بيقول عنه عنده + +49 +00:04:35,630 --> 00:04:40,070 +dehydration يعني فقد الماء اللي عنده صار عنده جفاف + +50 +00:04:40,070 --> 00:04:44,350 +فبيسموها بالانجليزي ايش الجفاف dehydration يعني + +51 +00:04:44,350 --> 00:04:48,370 +ايه تسمعوا عن الطفل عنده dehydration لازم تعطوه + +52 +00:04:48,370 --> 00:04:53,830 +ايش محليل الان اول شئ بدنا نبدأ فيه ال hydration + +53 +00:04:53,830 --> 00:04:57,750 +اضافة الماء الان اضافة الماء على طرفين الرابط + +54 +00:04:57,750 --> 00:05:05,860 +الزوجية شو هيحط عندهH و OH واضح القصة طبعا في كل + +55 +00:05:05,860 --> 00:05:09,920 +شيء في تفاصيل كثيرة لكن احنا احيانا بنتجوزها في ال + +56 +00:05:09,920 --> 00:05:12,880 +course العام يعني كيف بنضافه مش مشكلة المهم ان ال + +57 +00:05:12,880 --> 00:05:17,600 +double bond راحت ال bi bond ألغيت صارت two new + +58 +00:05:17,600 --> 00:05:24,160 +sigma bonds واحدة H واحدة OH هذا التفاعل بشكل عام + +59 +00:05:24,160 --> 00:05:31,000 +الان لو اتيت للتفاعل بحالة خاصةأتطلعت على هذا الـ + +60 +00:05:31,000 --> 00:05:35,620 +Alkene اللي هو الـ Isobutyl الان لو اتطلعت على هذا + +61 +00:05:35,620 --> 00:05:40,380 +ال Isobutyl هتلاحظوا انه Unsymmetrical الكين بمعنى + +62 +00:05:40,380 --> 00:05:43,860 +لو اتيت في نص ال bubble bond اتخيلت اني بدأ اجسم + +63 +00:05:43,860 --> 00:05:50,680 +نصين هلعنى C ايش بتحمل؟H و H مختصرات وهنا C بتحمل + +64 +00:05:50,680 --> 00:05:57,620 +CH3 و CH3 طيب لما أنا بدي أضيف الميه نتخيل الميه + +65 +00:05:57,620 --> 00:06:02,560 +هدول الجزئين الأزرق و الأحمر بدي أضيف الميه هل يا + +66 +00:06:02,560 --> 00:06:07,620 +تورا ال H نعتبرها الزرقه نعتبر ال H الزرقه و ال OH + +67 +00:06:07,620 --> 00:06:12,980 +الحمره هل يا تورا بدي أحط هنا ال H و هنا ال OH ولا + +68 +00:06:12,980 --> 00:06:15,200 +هنا ال H و هنا ال OH + +69 +00:06:19,900 --> 00:06:24,640 +من الناحية النظرية البحتة، من ناحية النظرية + +70 +00:06:24,640 --> 00:06:29,560 +البحتة، لو احنا بنقول لطفل صغير تعال شيل هادي وحق + +71 +00:06:29,560 --> 00:06:36,060 +التنتين، ممكن يعمل هيك و ممكن يعمل هيك، من ناحية + +72 +00:06:36,060 --> 00:06:41,000 +النظرية البحتة، الأمرين ممكنين، مافيش فيهم ولا + +73 +00:06:41,000 --> 00:06:47,280 +مشكلةالان هدولة الأمرين احنا اعطيناهم اسماء قولنا + +74 +00:06:47,280 --> 00:06:53,500 +اذا بنضيف الهيدروجين على الكربون اللى بتحمل + +75 +00:06:53,500 --> 00:06:57,520 +هيدروجين اكثر هذه الان لو فصلناها بشكل كامل هي + +76 +00:06:57,520 --> 00:07:03,850 +عبارة عن C بتحمل H وHتمام؟ هذه C لا تحمل اش ولا + +77 +00:07:03,850 --> 00:07:08,950 +اتش لو ضفنا الهيدروجين على الكاربون اللي حامل + +78 +00:07:08,950 --> 00:07:13,630 +هيدروجين اكثر بنقول هذه الإضافة حسب قواعد + +79 +00:07:13,630 --> 00:07:17,650 +Markovnikov أو حسب قاعدة Markovnikov وقتها بروح + +80 +00:07:17,650 --> 00:07:22,190 +بحط ال H هنا نفترض باللون الأزرق و ال O أتش هنا و + +81 +00:07:22,190 --> 00:07:28,710 +بطلع عندى ناتج واضح؟ ان جرب نعمل الجواب لو جربنا + +82 +00:07:28,710 --> 00:07:36,900 +هنحط CCH3 CH3 وهذه ستصبح single bond CH2 هذا ما + +83 +00:07:36,900 --> 00:07:46,540 +كان موجود أصلا كله ما جاء عليه H و OH الأن بهذا + +84 +00:07:46,540 --> 00:07:50,560 +الشكل الهيدروجين جاء على أي كربون على اللي حملة + +85 +00:07:50,560 --> 00:07:56,940 +هيدروجين أكتر وهذه الإضافة بنسميها إضافة حسب قاعدة + +86 +00:07:56,940 --> 00:07:58,140 +Markov-Nikov + +87 +00:08:05,760 --> 00:08:11,760 +ماركوف نيكوفز اديشن اضافة ماركوف نيكوفز اضافة + +88 +00:08:11,760 --> 00:08:12,480 +ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف + +89 +00:08:12,480 --> 00:08:14,080 +نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز + +90 +00:08:14,080 --> 00:08:14,240 +اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة + +91 +00:08:14,240 --> 00:08:14,300 +ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف + +92 +00:08:14,300 --> 00:08:15,260 +نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز + +93 +00:08:15,260 --> 00:08:19,420 +اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة + +94 +00:08:19,420 --> 00:08:26,320 +ماركوف نيكوفز اضافCH3 CH3 وهخلّي هذه single bond + +95 +00:08:26,320 --> 00:08:31,380 +CH2 هاي الألكين الأصلي و أحطهم بالعكس يعني ال H + +96 +00:08:31,380 --> 00:08:41,120 +هنا و ال OH هنا إيش + +97 +00:08:41,120 --> 00:08:49,170 +المانع؟مش مانع هاي إضافة مية وهي إضافة مية هذه + +98 +00:08:49,170 --> 00:08:54,330 +الإضافة بنعطيها اسم بنقولها Anti-Markovnikov + +99 +00:08:54,330 --> 00:08:58,650 +addition إضافة عكس قاعدة Markovnikov + +100 +00:09:03,760 --> 00:09:07,420 +Nikov's addition إذا يمكن أن تكون الإضافة زيك + +101 +00:09:07,420 --> 00:09:10,380 +ويمكن أن تكون زيك هتقولوا طب وإحنا شو بده يعرفنا + +102 +00:09:10,380 --> 00:09:16,380 +كيف نعمل الإضافة بنقول أه حسب ال reagent المستعمل + +103 +00:09:16,380 --> 00:09:22,200 +الماء يمكن أن يضيف بهذا الشكل وينتج المركب اللي + +104 +00:09:22,200 --> 00:09:25,960 +أمامنا هنا على الجهة اليامين ويمكن أنه يضيف بالشكل + +105 +00:09:25,960 --> 00:09:31,500 +التاني وينتج مركب تانيممكن يعطي ناتج إضافة حسب + +106 +00:09:31,500 --> 00:09:35,480 +قاعدة Markovnikov وممكن يعطي عكسها هتقولولنا طب + +107 +00:09:35,480 --> 00:09:39,440 +وقت إيش بيعمل هيك ووقت إيش بيعمل هيك الجواب بسيط + +108 +00:09:39,440 --> 00:09:42,680 +لأ وإحنا بنحكي الصورة الكلية اللي تفهم من خلالها + +109 +00:09:42,680 --> 00:09:46,440 +إذا كانت إضافة الماء يعني هنا على السهم كتبنا + +110 +00:09:46,440 --> 00:09:51,980 +الماء في وجود الحامض H plus فإنه يضيف حسب قاعدة + +111 +00:09:51,980 --> 00:09:57,190 +Markovnikovإذا عرفنا ما الشرط الذي من خلاله تتم + +112 +00:09:57,190 --> 00:10:02,570 +الإضافة حسب قاعدة Markov Nikov أن نضيف الماء في + +113 +00:10:02,570 --> 00:10:08,950 +وجود كمية قليلة من الحامض وجدها بنضيف حسب قاعدة + +114 +00:10:08,950 --> 00:10:17,600 +Markov Nikovالان طب كيف بضيف عكس قاعدة Markovnikov + +115 +00:10:17,600 --> 00:10:21,200 +إذا + +116 +00:10:21,200 --> 00:10:28,020 +ضفنا الماء باستعمال reagent مختلف طبعا ظروف كاملة + +117 +00:10:28,020 --> 00:10:34,520 +مختلفة باستعمال مركب ال borane اللي بنقوله BH3طبعا + +118 +00:10:34,520 --> 00:10:39,660 +بعد هيكذا البرين بنحط عليه H2O2 هيدروجين بيروكسايد + +119 +00:10:39,660 --> 00:10:46,180 +لو ضفنا في وجود هذه المتفاعلات بضيف عكس قاعدة + +120 +00:10:46,180 --> 00:10:52,160 +ماركوف نيكوفطبعا ربما الآن بدت الصورة تتضح لكم + +121 +00:10:52,160 --> 00:10:56,980 +لأنه انا حاسس الصمت عندكم لأن انتوا اتعلمتوا نص + +122 +00:10:56,980 --> 00:11:01,180 +المعلومة بالثانوية انه الإضافة فقط حسب قاعدة + +123 +00:11:01,180 --> 00:11:05,560 +Markovnikov حسب قاعدة Markovnikov ضمن هذا الشرط + +124 +00:11:05,560 --> 00:11:11,480 +غير الشرط تحصل على إضافة عكس قاعدة Markovnikov إذا + +125 +00:11:11,480 --> 00:11:17,710 +الأمرين ممكنين واضح؟ اللي اتعلمتوا بالثانويةنص + +126 +00:11:17,710 --> 00:11:23,030 +القصة مش كل القصة، واضح؟ اللي اتعلمته بالثانوية + +127 +00:11:23,030 --> 00:11:29,390 +نصف هذه القصة مش كلها فقط، الآن احنا استكملنا + +128 +00:11:29,390 --> 00:11:32,850 +القصة لكم، اننا نقولكم لأ والله يا المية بتضيف + +129 +00:11:34,860 --> 00:11:39,160 +الميّه بتضيف بالطريقتين هذا الكلام بعد شوية + +130 +00:11:39,160 --> 00:11:43,520 +هتلاحظوه مش بسمع الميّه هذا الكلام بعد شوية + +131 +00:11:43,520 --> 00:11:49,200 +هتلاحظوه مش بسمع الميّه هتلاحظوه حتى مع ال HPR على + +132 +00:11:49,200 --> 00:11:52,920 +سبيل المثال يعني لو أخذنا نفس ال ال keen اللي كان + +133 +00:11:52,920 --> 00:11:56,820 +عندنا هان عارفينه ال C double bond C + +134 +00:11:59,940 --> 00:12:08,040 +CH3 و CH3 و قلنا بدنا نكمله باتجاهين مع الـHBr و + +135 +00:12:08,040 --> 00:12:13,520 +هنا كمان كتبنا HBr لو قلنا بدنا نكمل التفاعل مع + +136 +00:12:13,520 --> 00:12:20,460 +HBr في وجود H Plus سيضيف حسب قاعدة Markov Nikov و + +137 +00:12:20,460 --> 00:12:24,520 +لو قلنا بدنا نكمل التفاعل مع الـHBr في وجود + +138 +00:12:24,520 --> 00:12:30,160 +بيروكسايد سيضيف عكس قاعدة Markov Nikovالناتج + +139 +00:12:30,160 --> 00:12:33,340 +ببساطة نفس اللي موجود عندكم بدل كلمة OH اللي + +140 +00:12:33,340 --> 00:12:34,660 +بالأحمر شو بتحطه + +141 +00:12:41,060 --> 00:12:46,580 +إذا إضافة الماء أو إضافة الـ HPR يمكن أن تتم + +142 +00:12:46,580 --> 00:12:51,360 +بطريقة ولا بطريقتين وهنا بيصير مهم عندي جدا أن + +143 +00:12:51,360 --> 00:12:55,460 +أنتبه لل reactant للمتفاعل يعني لو احنا مرات بدنا + +144 +00:12:55,460 --> 00:12:59,840 +نسألكوا عن هذا الموضوع ممكن نجيبلكوا ال reactant + +145 +00:12:59,840 --> 00:13:03,100 +مع هذا نقولكوا اكتبوا النتيجة ممكن نجيب هذا ال + +146 +00:13:03,100 --> 00:13:06,300 +reactant و ال product و نقولكوا شو اللي استعملته + +147 +00:13:06,300 --> 00:13:11,620 +كمتفاعل كتبولي ال reactant اللي على السهلواضحك + +148 +00:13:11,620 --> 00:13:16,680 +الصورة؟ طبعا لو إجينا سألنا هذه النواتج ال + +149 +00:13:16,680 --> 00:13:20,100 +markovnikov product هذا بيسموه markovnikov product + +150 +00:13:20,100 --> 00:13:26,020 +و ال antimarkovnikov product ما العلاقة بينهما؟ + +151 +00:13:26,020 --> 00:13:30,000 +isomers + +152 +00:13:30,000 --> 00:13:32,540 +أي نوع من ال isomers هذا اللي بقصدي + +153 +00:13:36,070 --> 00:13:40,470 +الـ Markovnikov's product والـ Antimarkovnikov's + +154 +00:13:40,470 --> 00:13:45,250 +product They are isomers ليش؟ لأنه نفس الذرات + +155 +00:13:45,250 --> 00:13:50,610 +وحطيت H و OH حطيت ال H و OH بنفس المواقع ولا + +156 +00:13:50,610 --> 00:13:57,670 +بمواقع مختلفة طالما مواقع مختلفة Different bonding + +157 +00:13:57,670 --> 00:14:04,290 +عطول الجواب Structural isomers They are structural + +158 +00:14:04,290 --> 00:14:09,910 +isomersمش فيها نقاش مش ارتبطوا الذرات من مواقع + +159 +00:14:09,910 --> 00:14:13,210 +مختلفة هنا الهيدروجين على الأولى و ال OH على + +160 +00:14:13,210 --> 00:14:17,470 +التانية هنا ال OH على الأولى و ال H على التانية صح + +161 +00:14:17,470 --> 00:14:20,570 +ولا لأ different bonding different names + +162 +00:14:20,570 --> 00:14:27,490 +structural isomers واضح إذا فكرة إضافة ال + +163 +00:14:27,490 --> 00:14:33,850 +unsymmetrical agents ممكن تضيفطريقتين ماركوف نيكوف + +164 +00:14:33,850 --> 00:14:37,450 +وانتي ماركوف نيكوف حسب ظروف التفاعل شو الأمثلة + +165 +00:14:37,450 --> 00:14:43,840 +المطلوب من ان اعرفها الماءو ال HVR بدون تفاصيل + +166 +00:14:43,840 --> 00:14:47,600 +الميكانيزم اللي أحيانا ممكن تلاقوها موجودة عندكم + +167 +00:14:47,600 --> 00:14:50,920 +يعني أنا في النهاية ال course general organic + +168 +00:14:50,920 --> 00:14:56,340 +course بهمني تصلوا فيه للنتيجة بشكل عام ولذلك على + +169 +00:14:56,340 --> 00:14:59,960 +طول الآن ممكن ناخد أمثلة إضافية و تشوفوا كيف + +170 +00:14:59,960 --> 00:15:04,520 +الأمثلة الإضافية بنكملها بدون ما ندخل بتفاصيل كيف + +171 +00:15:04,520 --> 00:15:08,260 +تمت العملية المهم عنده النتج + +172 +00:15:19,100 --> 00:15:22,820 +الشرط اللي بتتم فيه الإضافة عكس قاعدة Markovnikov + +173 +00:15:22,820 --> 00:15:27,160 +موجود في هذا ال slide لاحظوا لأنه بضيف مركب اسمه + +174 +00:15:27,160 --> 00:15:32,960 +BH3 ال بي بورون مش بروم انتبه بورون ال بورون لما + +175 +00:15:32,960 --> 00:15:36,760 +تيجي على الجدول الدوري في أوله اللي هو العنصر + +176 +00:15:36,760 --> 00:15:43,920 +الخامس هيدروجين هيليوم ليثيوم بيريليوم بورونBoron + +177 +00:15:43,920 --> 00:15:50,200 +الأنصار الخامس تمام لما يكون BH3 بنسميه borane هذا + +178 +00:15:50,200 --> 00:15:52,500 +بنسميه بورين + +179 +00:15:55,140 --> 00:16:01,340 +الان هذا ال borane في وجود solvent THF اسمه تترا + +180 +00:16:01,340 --> 00:16:04,640 +هيدرو فيوران solvent مش مشكلة بالنسبالي ان كل + +181 +00:16:04,640 --> 00:16:11,000 +تفاعل بتم في وجود مضيب بنضيف ال borane مع ال THF + +182 +00:16:11,000 --> 00:16:15,240 +في خطوة أولى بنحركهم لفترة معينة و بعدين على نفس + +183 +00:16:15,240 --> 00:16:23,390 +التفاعل بنضيف H2O2 hydrogen peroxideماء الأكسجين + +184 +00:16:23,390 --> 00:16:26,050 +اللي بيستعملوها بتثبيت الشعر وغيرها في basic + +185 +00:16:26,050 --> 00:16:32,110 +medium في وجود OH- الان انا دائما بهمني تفهمين + +186 +00:16:32,110 --> 00:16:36,450 +الفكرة الرئيسية يعني ماتوهوش كتير في التفاصيل + +187 +00:16:36,450 --> 00:16:39,530 +ولذلك لما انا بكون بدي افهم الفكرة الرئيسية لو + +188 +00:16:39,530 --> 00:16:43,730 +واحدة فكرت كل هدول وقعدت بتحفظهم بتوه لأ انا بهمني + +189 +00:16:43,730 --> 00:16:47,850 +ببساطة في الأول الفكرة الأساسية ان الماء يضيف + +190 +00:16:47,850 --> 00:16:52,800 +بطريقتين واضحة ولا لأيضيف Markovnikov في وجود H+, + +191 +00:16:52,800 --> 00:16:57,700 +واضح ولا لأ؟ وبقول ببساطة يضيف Anti-Markovnikov + +192 +00:16:57,700 --> 00:17:01,480 +بطريقة البرون، الآن أنا اللي بسميها طريقة البرون، + +193 +00:17:01,480 --> 00:17:05,660 +لأن طريقة البرون مجموعة من الأشياء موجودة في الكتب + +194 +00:17:05,660 --> 00:17:08,560 +وما إلى ذلك، وبنكتوب الكتابة على السهم، مابديش + +195 +00:17:08,560 --> 00:17:13,450 +أتقوه إن أقعد أحفظ هدولة بدون ما أكون فهمت؟الشئ + +196 +00:17:13,450 --> 00:17:17,570 +الرئيسي كذلك الحالة لبروم ال HPR عفوا بيضيف + +197 +00:17:17,570 --> 00:17:22,810 +بطريقتين في وجود H plus ماركوفنيكوف في وجود مواد + +198 +00:17:22,810 --> 00:17:27,350 +بيسميها البروكسايد فوق الأكسد انتي ماركوفنيكوف + +199 +00:17:27,350 --> 00:17:31,570 +يعني هتلاحظوا ان عندكم HPR و مكتوب لك بيروكسايد + +200 +00:17:31,570 --> 00:17:39,330 +اذا وجدتها التنفيذ انتي ماركوفنيكوفسابقا كان عندى + +201 +00:17:39,330 --> 00:17:43,290 +ناس ممتازين اللى بيحاولوا يفهموا الأمور في الأول + +202 +00:17:43,290 --> 00:17:46,110 +بالصورة الكلية قبل ما يخوضوا بالتفاصيل بعض منكم + +203 +00:17:46,110 --> 00:17:49,370 +بيتعب لإنه بيصير يخوض بالتفاصيل و الأشياء قبل ما + +204 +00:17:49,370 --> 00:17:53,770 +يفهم الصورة الكلية هدولة الناس الممتازين طلبت منهم + +205 +00:17:53,770 --> 00:17:57,570 +كان شعراء انه يلخصوا ال organ ال chemistry شعرا + +206 +00:17:58,290 --> 00:18:03,030 +بلغة بسيطة وهذا اللي بنصحكم يوم الامتحان تدرسوه ما + +207 +00:18:03,030 --> 00:18:06,610 +تقعدوش بس تكتبوا الأشياء دي و تفهموا لا افهموا + +208 +00:18:06,610 --> 00:18:11,170 +الأفكار الرئيسية الأفكار الرئيسية ببساطة اللي قلنا + +209 +00:18:11,170 --> 00:18:16,490 +ساعتين فيها تفهم بدقيقتين ال double bond تفعلها + +210 +00:18:16,490 --> 00:18:22,100 +الأساس إضافةالهيدروجين يضيف بشكل متماثل من جهة + +211 +00:18:22,100 --> 00:18:27,760 +واحدة البرومين يضيف من جهتين الأشياء زي الـH2O و + +212 +00:18:27,760 --> 00:18:31,900 +الـHBr ممكن تضيف مع قاعدة ماركوف نيكوف عكس قاعدة + +213 +00:18:31,900 --> 00:18:35,180 +ماركوف نيكوف تضيف مع قاعدة ماركوف نيكوف في وجود + +214 +00:18:35,180 --> 00:18:40,120 +الحامض تضيف عكس قاعدة ماركوف نيكوف الماء في وجود + +215 +00:18:40,120 --> 00:18:43,480 +البرون و الـHBr في وجود البروكسايد + +216 +00:18:45,830 --> 00:18:49,310 +هذا كل الكلام اللي احنا حكيناه ماحكيناش ولا كلمة + +217 +00:18:49,310 --> 00:18:53,170 +غيره بهذا الشكل بتصير ال organic عندكم سهلة و + +218 +00:18:53,170 --> 00:18:58,870 +ممتعة هعندي HPR طبعا ال HPR في نهاية بده يحط H و + +219 +00:18:58,870 --> 00:19:03,970 +PR ع دابل بوند هذه كانت CH2 صارت CH3 و انا PR هذا + +220 +00:19:03,970 --> 00:19:12,370 +مثال عام لكن لو اجينا على مثال متخصص زي هذا المثال + +221 +00:19:12,370 --> 00:19:21,590 +هذا الكربون كام هيدروجين عليهامباشر هذه واحدة + +222 +00:19:21,590 --> 00:19:24,070 +طلع هذه متصلة ب carbon + +223 +00:19:27,380 --> 00:19:33,680 +بعد انا بحكي عن الاتصال المباشر مش موراء ما بعد + +224 +00:19:33,680 --> 00:19:38,460 +بعد حيفا شو مالي و ماله هذا اه هنا هيدروجين تان + +225 +00:19:38,460 --> 00:19:42,400 +مباشر هنا هيدروجين و كرمون مين عليها هيدروجين اكثر + +226 +00:19:42,400 --> 00:19:48,780 +هذه بناء على ذلك لما انا بقول بدي اضيف HPR في وجود + +227 +00:19:48,780 --> 00:19:53,320 +H Plus وين اجت الهيدروجين؟ بهذا الشكل وين اجت ال + +228 +00:19:53,320 --> 00:20:02,760 +PR؟ بهذا الشكل واضح؟هي اللي بديها دلوقت بتجي + +229 +00:20:02,760 --> 00:20:09,060 +بالجهتين، من فوق و من تحت، قليلا بس شويه هذه + +230 +00:20:09,060 --> 00:20:14,000 +الفكرة متطورة اكثر من ان ابيع فيها بقى بتيجي من + +231 +00:20:14,000 --> 00:20:17,260 +فوق و من تحت يعنى، بس مش موضوعنا لإنه علاقة + +232 +00:20:17,260 --> 00:20:22,410 +بالستيل و كيميسترا، الآن هاي مركب تانيهي عندكم + +233 +00:20:22,410 --> 00:20:27,170 +double bond وين الطرفين ال double bond؟ هدى و هدى، + +234 +00:20:27,170 --> 00:20:33,570 +الآن هنا في شيء مش مرسوم ولا لأ؟ أكيد ال H الأكيد + +235 +00:20:33,570 --> 00:20:35,150 +ال H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال + +236 +00:20:35,150 --> 00:20:35,390 +H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H + +237 +00:20:35,390 --> 00:20:35,870 +الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H + +238 +00:20:35,870 --> 00:20:35,890 +الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H + +239 +00:20:35,890 --> 00:20:36,110 +الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H + +240 +00:20:36,110 --> 00:20:36,610 +الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H + +241 +00:20:36,610 --> 00:20:39,010 +الأكيد ال H ال أكيد ال H ال أكيد ال H ال أكيد ال H + +242 +00:20:39,010 --> 00:20:44,980 +ال أكيد ال H ال أكيد ال H الإذا لو أنا كنت بدى + +243 +00:20:44,980 --> 00:20:51,000 +أكمل HPR في وجود H Plus كيف سأكتب الناتج؟ يعني لو + +244 +00:20:51,000 --> 00:20:57,060 +أنه أكمل المعادلة HPR H Plus بدى أحط الهيدروجين ع + +245 +00:20:57,060 --> 00:21:02,360 +اللي حاملة هيدروجين أكتر يعني بدى أحطها ناسيه H3 + +246 +00:21:02,360 --> 00:21:12,340 +وH هدولة اللي كانوا أصلا وجدت بدى أحط ال H تحتو ال + +247 +00:21:12,340 --> 00:21:18,800 +PR على هذا الكربون هذه إضافة ماركوفنيكوف الان لما + +248 +00:21:18,800 --> 00:21:24,560 +نيجي نعطيكم كملوا المعادلة HPR في وجود البروكسايد + +249 +00:21:24,560 --> 00:21:29,300 +بدي أحط بالعكس بدي أحط بالعكس ولذلك لو بتيجي + +250 +00:21:29,300 --> 00:21:33,080 +تتطلعوا هنا وين ال PR موجودة على أي كربون + +251 +00:21:35,850 --> 00:21:39,270 +هيها طبعا هو ورا السماء مرة لتحت و مرة لفوق هذا + +252 +00:21:39,270 --> 00:21:43,710 +السؤال الذكي اللي سألته زملتكوا بس بدناش نطول فيه + +253 +00:21:43,710 --> 00:21:46,830 +بيجعل + +254 +00:21:46,830 --> 00:21:51,550 +جهتين مش فيها مشكلة بس في كل الأحوال على أي carbon + +255 +00:21:51,550 --> 00:21:56,560 +إجت ال PRعلى حملة الهيدروجين على أي كاربون إجت + +256 +00:21:56,560 --> 00:22:00,840 +الهيدروجين على اللي أقل هذي Markov Nikov ولا أنت + +257 +00:22:00,840 --> 00:22:05,680 +Markov Nikov؟ أنا مابديش ياكلتوه في الشكل فوق و + +258 +00:22:05,680 --> 00:22:11,140 +تحت، حطوهم بس بالموقع الصح و غلط و مكفي، واضح؟ + +259 +00:22:11,140 --> 00:22:15,140 +يعني لما بنكمل هذه المعادلة، ببساطة إيش يكون + +260 +00:22:15,140 --> 00:22:24,560 +الجواب؟ هنا ال H وهنا ال PRهك النتج بدون يصفر اكتر + +261 +00:22:24,560 --> 00:22:29,580 +من هيك تفصيل مابلزمنيش هذه مع ولا عكس Markovnikov + +262 +00:22:29,580 --> 00:22:33,700 +لما يكون هيك جوابه لغير ال double bond عكس + +263 +00:22:33,700 --> 00:22:38,500 +Markovnikov هنا ال H هنا ال PR مع Markovnikov + +264 +00:22:38,500 --> 00:22:39,200 +فاهمنا؟ + +265 +00:22:50,600 --> 00:22:58,020 +بيجينا بعد هذه الإضافة إضافة جديدة هذه الإضافة + +266 +00:22:58,020 --> 00:22:59,980 +الجديدة + +267 +00:23:01,170 --> 00:23:07,110 +ان برضه احنا بنلغي فيها ال double bond و بنعمل two + +268 +00:23:07,110 --> 00:23:11,010 +new sigma bonds لكن هدول ال two new sigma bonds + +269 +00:23:11,010 --> 00:23:15,450 +بيكونوا على نفس ذرة ال oxygen ولذلك بيعطوني حلقة + +270 +00:23:15,450 --> 00:23:19,250 +ثلاثية لاحظوا هذا الكلام كيف هي عندكم carbon + +271 +00:23:19,250 --> 00:23:24,450 +carbon double bond صح ولا لأ الان لو فعلناها مع + +272 +00:23:24,450 --> 00:23:31,330 +bare acidBear بادئة معناها فوق يعني فيه ازيادة + +273 +00:23:31,330 --> 00:23:40,170 +الحامض العضوي كام أكسوجين فيه عادة ال acid؟ تنتيل + +274 +00:23:40,170 --> 00:23:44,570 +تلت روابط مع الأكسوجين يعني ال acid شكله العام + +275 +00:23:44,570 --> 00:23:55,300 +بهذا الشكل R C double bond O OH مشاكل الحامض؟RCOH + +276 +00:23:55,300 --> 00:23:59,640 +لو كانت هذه CH3 بيكون الاسيتك أسد لو كانت فنل + +277 +00:23:59,640 --> 00:24:05,260 +بيكون ال بنزويك أسد الان لو اجينا جنب ال COH + +278 +00:24:05,260 --> 00:24:12,400 +هتضيفنا كمان O يعني خلينا COOH زي هذا المركب اللي + +279 +00:24:12,400 --> 00:24:17,700 +هنا RCOOH + +280 +00:24:17,700 --> 00:24:24,640 +هذا زاد عندى بإيش؟بأكسوجينة صار فيه تلت أكسوجينات + +281 +00:24:24,640 --> 00:24:28,640 +هذا كام أكسوجينة في تنتين الآن هذا المركب اللي + +282 +00:24:28,640 --> 00:24:34,920 +صيرته العامة R C double bond O O O H بنسميه pear + +283 +00:24:34,920 --> 00:24:41,230 +acid فوق حامضيعني زاد فيه ال oxygen بمقدار ضرر + +284 +00:24:41,230 --> 00:24:46,310 +يعرفنا إيش معنى pear acid و لما نسميه بنسميه على + +285 +00:24:46,310 --> 00:24:49,570 +اسم الحامض الأصلي اللي كان موجود يعني لو افترضنا + +286 +00:24:49,570 --> 00:24:54,810 +الحامض الأصلي acidic acidبصير اللي فيه أكسجينة + +287 +00:24:54,810 --> 00:25:01,350 +زيادة بير أسيتك أسد، بنزويك أسد، بير بنزويك أسد، + +288 +00:25:01,350 --> 00:25:06,930 +يعني نفس الحامض تماما بس بنزيد عليه إيش؟ بير، يمكن + +289 +00:25:06,930 --> 00:25:12,590 +مرت عليكم لما أخدتوا أحماض الكلور مع الأكسجين لما + +290 +00:25:12,590 --> 00:25:18,510 +أخدتوا ال بيريكلوريك أسدمش كان عندكوا ClO3 لكلوريك + +291 +00:25:18,510 --> 00:25:25,530 +أسد لما صار ClO4 زاد أكسوجينة بيريكلوريك أسد واضح + +292 +00:25:25,530 --> 00:25:31,230 +فبير هنا بمعنى إيش الزيادة لو فعلنا الالكين مع + +293 +00:25:31,230 --> 00:25:36,480 +البر أسدمرة تانية بتنكسر ال double bond و بتعمل + +294 +00:25:36,480 --> 00:25:40,900 +رابطتين sigma لكن مع نفس ذرة ال oxygen اذا هذه + +295 +00:25:40,900 --> 00:25:48,220 +العملية ايضا عملية ايش اضافة تحويل ال by bond الى + +296 +00:25:48,220 --> 00:25:54,080 +two new sigma bonds اضافة ولا مش اضافة اضافة لكن + +297 +00:25:54,080 --> 00:25:56,880 +الان ال two new sigma bonds على نفس ال oxygen + +298 +00:25:56,880 --> 00:26:04,040 +فالناتج حلقة ثلاثيةالناتج حلقة ثلاثية هذه الحلقة + +299 +00:26:04,040 --> 00:26:10,460 +الثلاثية من ذرتين كربون و من أكسوجينة حلقة ثلاثية + +300 +00:26:10,460 --> 00:26:14,560 +ذرتين كربون و أكسوجينة هذه الثلاث ذرات تعونها الآن + +301 +00:26:14,560 --> 00:26:21,140 +هذه الحلقة الثلاثية كعائلة بيسموها ابوكسايد يعني + +302 +00:26:21,140 --> 00:26:25,380 +لو قلتلكم ما هي عائلة الابوكسايد لاحظوا family في + +303 +00:26:25,380 --> 00:26:29,660 +عندنا family و في عندنا في جوا ال family ايش أفراد + +304 +00:26:30,500 --> 00:26:33,720 +هك بتكون تفهموا الكيميا ان في العائلة العامة زي ال + +305 +00:26:33,720 --> 00:26:40,800 +ketones ال ketone family عائلة الآن جواتها acetone + +306 +00:26:40,800 --> 00:26:46,740 +وcyclohexanone وكذا وكذا ال alkenes عائلة جواتها + +307 +00:26:46,740 --> 00:26:53,910 +methane إيثين بروبين الآن ال epoxidesعائلة أيضا مش + +308 +00:26:53,910 --> 00:26:59,130 +اسم مركّب الابوكسايد عائلة الان طب ايش في جوات هذه + +309 +00:26:59,130 --> 00:27:05,730 +العائلة مركّبات؟ carbon تانو اكسوجينة وين بدو يصير + +310 +00:27:05,730 --> 00:27:10,630 +الخلاف؟ بدو يصير الخلاف في هدول المجموعات هل هدول + +311 +00:27:10,630 --> 00:27:14,130 +الأربعة هيدروجينز؟ هل واحدة فيهم مثل؟ هل تنتين + +312 +00:27:14,130 --> 00:27:16,910 +مثل؟ هل التلاتة مثل؟ هل الأربعة مثل؟ هل واحدة إثل؟ + +313 +00:27:16,910 --> 00:27:23,540 +هل واحدة بروبل؟وجدتها بيصير لكل مركب اسم طب كيف + +314 +00:27:23,540 --> 00:27:28,760 +بنسمي كل مركب؟ العملية سهلة بنيجي بنسأل نفسنا إيش + +315 +00:27:28,760 --> 00:27:36,160 +اسم الألكين الأصلي تبعه اللي كونه؟والناتج لما + +316 +00:27:36,160 --> 00:27:39,900 +نعمله بنسميه باسم الالكين بنضيف عليه oxide يعني + +317 +00:27:39,900 --> 00:27:46,200 +مثلا لو كان الالكين اللي عندكم CH2 double bond CH2 + +318 +00:27:46,200 --> 00:27:53,580 +هين حددنا مركب محدد هذا إيش اسمه اثيلين او اثيل + +319 +00:27:53,580 --> 00:27:59,300 +اثيلين الآن فعلنا مع ال bare acid هذا اللي موجود + +320 +00:27:59,300 --> 00:28:05,840 +عندناهتلتغي هذه الـ bi-bond وتعطيني أكسوجينة صار + +321 +00:28:05,840 --> 00:28:11,480 +عندى CH2 خلّيني نخلي الهيدروجين يخلع برا مرسومين + +322 +00:28:11,480 --> 00:28:14,620 +CH2 + +323 +00:28:14,620 --> 00:28:23,280 +CH2 و هنا أكسوجين الآن هذا من أي مركب نتاج من + +324 +00:28:23,280 --> 00:28:30,910 +الإثالين شو بدي أسميه إثالين أكسيد نسبة للأصلإذا + +325 +00:28:30,910 --> 00:28:35,970 +تسمية هذه المراكبات تسمية هذه المراكبات كل فرد + +326 +00:28:35,970 --> 00:28:42,350 +منها كيف بسميه باسم القلقين الأصلي مضاف إليه كلمة + +327 +00:28:42,350 --> 00:28:49,350 +أكسايد أثالين أكسايد واضحة الفكرة ولا لأ ماشي + +328 +00:28:49,350 --> 00:28:53,410 +أتأكد أنها واضحة ولا لأ الآن لو اني جيبت هذا + +329 +00:28:53,410 --> 00:28:58,310 +المراكب في الامتحان وقلتلك لو سمحته سمولي هذا + +330 +00:28:58,310 --> 00:29:04,760 +المراكبزي هيك هذا جايكوا في الامتحان و أنا قلتلكوا + +331 +00:29:04,760 --> 00:29:11,860 +صموه واحدة + +332 +00:29:11,860 --> 00:29:15,960 +بس Cyclohexane + +333 +00:29:15,960 --> 00:29:22,210 +Oxide بتكون تقولوا هذا إيش كان أصلاهي اللي شيلت + +334 +00:29:22,210 --> 00:29:26,990 +هذه .. هذا أصلا كان هيك لما ضيفت عليه شيلت ال + +335 +00:29:26,990 --> 00:29:30,910 +double bond و حطيت ال oxygen طب زي هيك إيش اسمه؟ + +336 +00:29:30,910 --> 00:29:41,120 +Cyclohexane شيلنا هذه صار Cyclohexane oxideواضح؟ + +337 +00:29:41,120 --> 00:29:48,940 +إذا هذه المركبات كأفراد تسمى باسم القلقين الأصلي + +338 +00:29:48,940 --> 00:29:55,160 +باسم القلقين الأصلي مضاف إلى كلمة Oxide واضحة ولا + +339 +00:29:55,160 --> 00:30:04,340 +ما واضحت؟ واضحة تماما، الآن إلها تسمية تانية كتير + +340 +00:30:04,340 --> 00:30:10,260 +في ناس بياخدوا أكتر من اسم، إلها تسمية تانيةأبسط + +341 +00:30:10,260 --> 00:30:15,340 +مُركّب في هذه العائلة كلها أي واحد الـ ethylene + +342 +00:30:15,340 --> 00:30:22,620 +oxide ليش؟ لأنه هنا O CH H H H H هذا المُركّب + +343 +00:30:22,620 --> 00:30:27,980 +الأبسط فيهم هذا المُركّب الأبسط ماخد اسم اسمه + +344 +00:30:27,980 --> 00:30:37,990 +Oxirane Oxirane تمام؟Oxirane بنحفظه ايه كويس الان + +345 +00:30:37,990 --> 00:30:43,270 +هذا ال Oxirane بنتخيله تلت مواقع بنبدأ ترقيمه من + +346 +00:30:43,270 --> 00:30:50,170 +ال Oxygen بنقول واحد اتنين تلاتةبنسميه ال parent + +347 +00:30:50,170 --> 00:30:55,410 +compound عمرنا قولنا كلمة parent المركب الأبسط + +348 +00:30:55,410 --> 00:30:59,310 +دائما بنقول عنه ال parent compound الآن هذا ال + +349 +00:30:59,310 --> 00:31:02,610 +parent compound لو يا ترى شيلنا من هدول ال + +350 +00:31:02,610 --> 00:31:10,870 +hydrogen ال hydrogen واحدة وحطينا بدلها CH3 واحدة + +351 +00:31:10,870 --> 00:31:12,610 +تقولي ايش بدها تسمي وجتها + +352 +00:31:15,250 --> 00:31:20,130 +أوكز إيرين المركب الأصلي على موقع اتنين إيش إجاله + +353 +00:31:20,130 --> 00:31:30,210 +مثل إذا هذا بيصير two مثل أوكز إيرين أنا اعتبرت ال + +354 +00:31:30,210 --> 00:31:34,990 +أوكز إيرين اللي فيه أربعة هيدروجين شلت منه واحدة + +355 +00:31:34,990 --> 00:31:39,630 +محل ما شلت بكتب اسم المجموعة لو كان كلور two chlor + +356 +00:31:39,630 --> 00:31:44,780 +أوكز إيرين لو كانت إثلتوقث ال Oxirane تعرفنا كيف + +357 +00:31:44,780 --> 00:31:49,800 +هذا سمنها؟ الآن هي تسمية هذا المركب اللي أمامكم + +358 +00:31:49,800 --> 00:31:54,360 +بطريقة ال Oxirane طب لو واحدة بدأت تسميه بطريقة ال + +359 +00:31:54,360 --> 00:32:02,200 +Alkyl Oxide، شو هتسميه؟ بروبين أكسيد، بروبين + +360 +00:32:02,200 --> 00:32:04,780 +أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، + +361 +00:32:04,780 --> 00:32:05,560 +بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين + +362 +00:32:05,560 --> 00:32:06,080 +أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، + +363 +00:32:06,080 --> 00:32:08,440 +بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين + +364 +00:32:08,440 --> 00:32:16,320 +أكسيد، بروبين أكسما هذا الالكين؟ واحد CH2 double + +365 +00:32:16,320 --> 00:32:22,300 +bond CH CH3 هذا الابروبيل و لذلك بيصير ابروبيل + +366 +00:32:22,300 --> 00:32:27,900 +أكسيد فلو جيبنالكم مثلا سؤال ابروبيل أكسيد is also + +367 +00:32:27,900 --> 00:32:32,780 +called وقتها بتقولوا 2-methyl oxirane 2-methyl + +368 +00:32:32,780 --> 00:32:38,900 +oxirane is also calledPropyl Oxide طبعا ال Oxirans + +369 +00:32:38,900 --> 00:32:42,760 +هذه في الكيميا الحلقية غير المتجانسة بنستعملها + +370 +00:32:42,760 --> 00:32:46,480 +أكتر في الكيميا العادية المشهورة أكتر يكون تسموها + +371 +00:32:46,480 --> 00:32:54,720 +نسبة للالكيم و تحطو إيش Oxide الإسمين بتلاقوهم إذا + +372 +00:32:54,720 --> 00:33:01,620 +شفنا هذه المراكبات كيف بنحضرها و كيفبنسميها كيف + +373 +00:33:01,620 --> 00:33:05,560 +بنحضرها و كيف بنسميها عساريا مينندسيا هل هذه + +374 +00:33:05,560 --> 00:33:08,800 +التسمية بتسميها ايوباك ولا ايوباك؟ لأ لأ هي + +375 +00:33:08,800 --> 00:33:14,240 +التسمية اللي هي ال auxirene نظام تسمي بسموه Hans + +376 +00:33:14,240 --> 00:33:18,550 +Wiedemann system of nomenclatureيستعمل عن طلاب + +377 +00:33:18,550 --> 00:33:23,570 +الكيميا للـ heterocyclic compounds واضح؟ hence + +378 +00:33:23,570 --> 00:33:26,570 +Vedman system of nomenclature الآن خلينا ناخد + +379 +00:33:26,570 --> 00:33:32,050 +أمثلة انسهل الموضوع هي كذا مثال جيبنا أكمل مع pear + +380 +00:33:32,050 --> 00:33:36,950 +acid شو عرفني pear acid؟ تلت أكسوجينات في كل + +381 +00:33:36,950 --> 00:33:42,370 +الأحوال شو اللي بدى أعمله؟ أشيل ال double bond؟أحط + +382 +00:33:42,370 --> 00:33:48,510 +مكانها أكسجين أشيل ال double bond أحط أكسجين أشيل + +383 +00:33:48,510 --> 00:33:52,630 +ال double bond أحط أكسجين إذا الأمر سهل و بسيط ولا + +384 +00:33:52,630 --> 00:33:57,110 +لأ الالكيل مع ال bear acid أشيل ال double bond أحط + +385 +00:33:57,110 --> 00:34:02,350 +أكسجين في حلقة ثلاثية كل هذه لو إجا شخص من برة و + +386 +00:34:02,350 --> 00:34:07,070 +يتطلع على السبورة ويقول له شو هذه المركبات؟ شو بدي + +387 +00:34:07,070 --> 00:34:14,200 +يجاوبنا؟Epoxides مش العائلة ابوكسايدز فلو يوم من + +388 +00:34:14,200 --> 00:34:19,140 +الأيام جريتوا مثلا عائلة الابوكسايدز افبالكم بلغة + +389 +00:34:19,140 --> 00:34:24,740 +بسيطة الحلقات الثلاثية التي تحتوي على ذرة أكسجين + +390 +00:34:24,740 --> 00:34:32,280 +واحدة هي عائلة الابوكسايدز واضحة؟ الآن بنلاحظ شغلة + +391 +00:34:32,280 --> 00:34:36,790 +في عائلة الابوكسايدزهذه الحلقة الثلاثية حتى لو + +392 +00:34:36,790 --> 00:34:41,950 +عملناها باستعمال ال model هنلاحظ فيها شغل يعني لو + +393 +00:34:41,950 --> 00:34:47,310 +جيبنا ذرة الأكسجين هذه اللي لونها أزرق شوية مش هي + +394 +00:34:47,310 --> 00:34:52,470 +زرق الأكسجين وجيبنا ذرتين carbon وجربنا نعمل + +395 +00:34:52,470 --> 00:34:58,350 +الحلقة الثلاثية باستعمال + +396 +00:34:59,200 --> 00:35:04,140 +الـ Models هتلاحظوا فيها ملاحظة اتطلعوا معاه قبل + +397 +00:35:04,140 --> 00:35:09,600 +ما اتسكر الحلقة شوفوا كيف مترايحة الروابط فيها و + +398 +00:35:09,600 --> 00:35:13,960 +انا بسكر ايش قاعد بعمل؟ بضغط .. بضغط .. بضغط .. + +399 +00:35:13,960 --> 00:35:18,720 +بضغط .. الآن غصب عن هذه ال carbon قاعد بعمل فيها + +400 +00:35:18,720 --> 00:35:24,240 +زاوية لو تتخيلوا جداش مقدارها؟ ستين .. ستين .. + +401 +00:35:24,240 --> 00:35:28,880 +ستين .. ستين .. مية و تمانينزوايا المثلث 180 طب + +402 +00:35:28,880 --> 00:35:32,420 +الزاوية المترايحة خليني أفلتها شوية أسيب ال carbon + +403 +00:35:32,420 --> 00:35:36,320 +تترايح جداش زاوية ال carbon هذه المترايحة لها مش + +404 +00:35:36,320 --> 00:35:43,020 +90 انسيتوا ال tetrahedral 109.5 هذه الزاوية 109.5 + +405 +00:35:43,020 --> 00:35:49,440 +مش هدول بكملهم اتش اتش بيكونوا .. 109.5 الزاوية + +406 +00:35:49,440 --> 00:35:55,990 +المترايحةهذه الـ CH2 وهذه بتكون زيها كمان CH2، + +407 +00:35:55,990 --> 00:36:01,750 +واضح؟ فالزاوية المتريحة 109.5، الآن أنا عشان أعمل + +408 +00:36:01,750 --> 00:36:05,330 +الحلقة الثلاثية، انزلت فيها لا جداش، انزلت فيها لا + +409 +00:36:05,330 --> 00:36:10,550 +ستين، إذا هذا ضغط شديد على الحلقة ولا لأ؟ بسميه + +410 +00:36:10,550 --> 00:36:14,650 +strain زي الزنبارك لما بتعصوه، strain بتصير + +411 +00:36:14,650 --> 00:36:20,890 +الحلقة، هذه الحلقة الـstrain لو بدت تعمل تفاعلوحد + +412 +00:36:20,890 --> 00:36:26,070 +مضغوط ايش التفاعل اللي بده يعمله؟ + +413 +00:36:26,070 --> 00:36:33,450 +Ring Opening لأنها Strained لما قادش أفعلها مع + +414 +00:36:33,450 --> 00:36:37,190 +أشياء التفاعل اللي بتعمله Ring Opening بتحب تفتح + +415 +00:36:37,190 --> 00:36:41,890 +بتحب مش يظلها مسكرة فبدنا نفهم احنا ان الحلقة + +416 +00:36:41,890 --> 00:36:46,290 +الثلاثية هذه Strained ايش يعني Strained؟ مضغوطة + +417 +00:36:46,290 --> 00:36:49,030 +بتحب تعمل Ring + +418 +00:36:51,710 --> 00:36:56,190 +Ring Opening بتفتح، بتريح الزوايا تبعتها زي أي بني + +419 +00:36:56,190 --> 00:37:01,090 +آدم مضغوط برتاح للزوايا الطبيعية، الزوايا الطبيعية + +420 +00:37:01,090 --> 00:37:08,120 +109.5، هي الآن هنا موجودة في جداشالان بيصير السؤال + +421 +00:37:08,120 --> 00:37:11,980 +يا تورا ايش الشيء اللى بده يعمل ال herring opening + +422 +00:37:11,980 --> 00:37:16,580 +و يتفاعل معها؟ لو اطلعتوا انتوا هنا، هاي الحلقة، + +423 +00:37:16,580 --> 00:37:22,800 +هذا أكسوجين سلبيته عالية، هذه كربون سلبيتها أقل، + +424 +00:37:22,800 --> 00:37:26,540 +اذا كأنه هذا الأكسوجين سالب و الكربون و الكربون + +425 +00:37:26,540 --> 00:37:31,880 +هذه ايش مالهم؟ موجباتهذه نقطة كتير مهمة اذا انا + +426 +00:37:31,880 --> 00:37:37,560 +بقدر اتخيل الان هذه ان هذه سالبة و انا عندي على ال + +427 +00:37:37,560 --> 00:37:42,660 +carbon موجب و على ال carbon موجب بناء على ذلك لو + +428 +00:37:42,660 --> 00:37:48,460 +جبت من برا اش سالب يتفاعل وين هيروح يهجم على ال + +429 +00:37:48,460 --> 00:37:52,160 +carbon هذا الاش السالب اللي انا بجيبه و بسميه ال + +430 +00:37:52,160 --> 00:37:56,020 +eucleophile اكيد شيء عليه أزواج الإلكترونات هي سبب + +431 +00:37:56,020 --> 00:38:02,090 +السالبإيش بسميه الـ Eucleophile يمكن هالكلمة هذه + +432 +00:38:02,090 --> 00:38:08,910 +ما مرتش معاكم قبل هيك ال Eucleophile لو فصلنا شوية + +433 +00:38:08,910 --> 00:38:13,370 +بكلمة ال Eucleophile file من اللاتيني معناه محب + +434 +00:38:13,370 --> 00:38:20,300 +محب يحبو نيوكليو من نيوكلياس النواة معناه + +435 +00:38:20,300 --> 00:38:24,700 +نيوكليوفايل يحب النواة طب النواة اللي في قلبها + +436 +00:38:24,700 --> 00:38:29,780 +موجب ولا سالب؟ موجب إذا بتصير معناة كلمة + +437 +00:38:29,780 --> 00:38:36,260 +نيوكليوفايل يحب الموجب ما الذي يحب الموجب؟ السالب + +438 +00:38:36,260 --> 00:38:40,020 +أو اللي بيحمل أزواج إلكترونات فهمتوا؟ إذا + +439 +00:38:40,020 --> 00:38:46,310 +النيوكليوفايل ببساطة شيء سالبأو شيء بيحمل أزواج + +440 +00:38:46,310 --> 00:38:49,970 +إلكترونات لأنه سالب أو بيحمل أزواج إلكترونات فهو + +441 +00:38:49,970 --> 00:38:54,970 +يحب ال إيش؟ الموجب الآن هذه ال carbon موجبة تحب + +442 +00:38:54,970 --> 00:38:58,990 +إيش؟ سالب سالب لو بدي أعطيها اسم بنفس منطق ال + +443 +00:38:58,990 --> 00:39:04,350 +nucleophile إيش هقول؟ أكس آن أكس آن file file هذه + +444 +00:39:04,350 --> 00:39:09,790 +يحب ال electrophile ال electrophile فال + +445 +00:39:09,790 --> 00:39:16,470 +electrophile شيء موجبيحب السالب لأن يوكليوفي شئ + +446 +00:39:16,470 --> 00:39:20,350 +سالب يحب الموجب هدول شغلتين بتفاعلوا مع بعض يعني + +447 +00:39:20,350 --> 00:39:24,090 +كأنه ببساطة ممكن واحدة اللي مش كتير حابه + +448 +00:39:24,090 --> 00:39:28,050 +هالمصطلحين لأول واحدة تقول يعني موجب وسالب أه + +449 +00:39:28,050 --> 00:39:32,110 +ببساطة يعني موجب وسالب لكن احنا من اليوم وطالع في + +450 +00:39:32,110 --> 00:39:34,750 +ال organ ال chemistry الموجب ايش هنسميه؟ + +451 +00:39:35,390 --> 00:39:40,390 +Electrophile والسالب ايش هنسميه النيوكليوفايل الان + +452 +00:39:40,390 --> 00:39:47,510 +هنقول انه النيوكليوفايل بيهاجم على ال Electrophile + +453 +00:39:47,510 --> 00:39:52,390 +بيعمل رابطة ممكن النيوكليوفايل يكون OH جاية من + +454 +00:39:52,390 --> 00:39:56,030 +الميه او تيجي من الميه فلما ييجي هذا ال OH + +455 +00:39:56,030 --> 00:40:00,470 +هنهيهاجم معقول يصيروا خمس روابط ولا هتكسر هذه + +456 +00:40:00,470 --> 00:40:10,140 +الرابطة تكسر وتفتح هتتحول ال O هذهالى OH الان بهذه + +457 +00:40:10,140 --> 00:40:13,220 +المنطقة راجعوا المرة اللى جايب ال road نبدأ من عند + +458 +00:40:13,220 --> 00:40:16,400 +هذه النقطة لكن بتكونوا اتدربتوا اكتر و بنشرح كل + +459 +00:40:16,400 --> 00:40:20,940 +الأمثلة ايش معنى Electrophile ايش معنى Nucleophile + +460 +00:40:20,940 --> 00:40:24,680 +هات بتتدربوا عليها بنشوف كيف ال ring opening بيصير + +461 +00:40:24,680 --> 00:40:26,600 +باكثر من مثل + diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/z4_9i2lZ2eY_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/z4_9i2lZ2eY_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..06221a431179ca47bac4a540fef3cdf8472859e0 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/z4_9i2lZ2eY_raw.srt @@ -0,0 +1,2084 @@ +1 +00:00:21,140 --> 00:00:26,480 +بسم الله الرحمن الرحيم المرة الماضية بدأنا في + +2 +00:00:26,480 --> 00:00:32,300 +الفصل الثالث في الكيميا العضوية اللي هو بعنوان ال + +3 +00:00:32,300 --> 00:00:37,500 +alkenes and alkynes طبعا بشكل أساسي اتعرفنا على + +4 +00:00:37,500 --> 00:00:42,020 +خواص الروابط الأوحدية الثنائية الثلاثية واخدنا + +5 +00:00:42,020 --> 00:00:46,840 +تسمية ال alkenes و ال alkynes وركزنا على فكرة + +6 +00:00:47,640 --> 00:00:53,300 +موجودة كثير في هذا المجال هي فكرة وجود ال stereo + +7 +00:00:53,300 --> 00:00:57,700 +isomers تحديدا ال cis و ال trans اللي قولنا عنهم + +8 +00:00:57,700 --> 00:01:00,780 +هدول عبارة عن diastereomers + +9 +00:01:03,880 --> 00:01:08,860 +كامتداد بسيط فقط لفكرة ال sis و ال trans احنا قلنا + +10 +00:01:08,860 --> 00:01:12,940 +بيكون عندنا موجود sis او trans سواء حول ال double + +11 +00:01:12,940 --> 00:01:17,340 +bond او حول ال single bond في حلقة اذا كان في عندى + +12 +00:01:17,340 --> 00:01:21,380 +على كل ذرة كربون من الذرات المعنية مجمعتين + +13 +00:01:21,380 --> 00:01:26,500 +مختلفتين بقدر اقول sis و trans يعني المركب بيكون + +14 +00:01:26,500 --> 00:01:33,310 +في منه اتنين الان لو يا ترى أخدنا مثال جديدهذا + +15 +00:01:33,310 --> 00:01:39,310 +المثال هي double bond وهي carbon وهي carbon هل هنا + +16 +00:01:39,310 --> 00:01:43,250 +في عندي مجموعتين مختلفتين ولا لأ؟ عندي مجموعتين + +17 +00:01:43,250 --> 00:01:47,910 +مختلفتين هل هنا في عندي مجموعتين مختلفتين ولا لأ؟ + +18 +00:01:47,910 --> 00:01:52,230 +في عندي مجموعتين مختلفتين إذا هذا المركب في منه + +19 +00:01:52,230 --> 00:01:57,130 +مركب واحد ولا اتنين؟في منه مراكبين لو بده المراكب + +20 +00:01:57,130 --> 00:02:02,650 +التاني بثبت اي تنتين وبعكس التنتين التانية يعني + +21 +00:02:02,650 --> 00:02:06,990 +لاحظوا هذا المراكب نفسه رسمناها تخلينا على سبيل + +22 +00:02:06,990 --> 00:02:12,190 +المثال اليود والكلور زي ما هما عكسنا مجموعة المثل + +23 +00:02:12,190 --> 00:02:16,170 +لتحت ال PR لفوق تخلينا ال PR لتحت المثل لفوق هاي + +24 +00:02:16,170 --> 00:02:22,320 +المراكب التانيواضح؟ ولو هذا المركب احنا بدنا نسميه + +25 +00:02:22,320 --> 00:02:28,540 +مش صعب علينا نسميه كمواقع ذرات كمواقع ذرات carbon + +26 +00:02:28,540 --> 00:02:34,400 +تنتين تلاتة أطول سلسلة اذا هذا المركب اي مركب + +27 +00:02:34,400 --> 00:02:44,250 +بروبيل بروبيل هذا المركب حامل يود وبروم وكلوربدنا + +28 +00:02:44,250 --> 00:02:47,990 +نذكرهم alphabetically، لاحظوا ما حد يقول إنه حامل + +29 +00:02:47,990 --> 00:02:53,430 +مثل، المثل جزء من السلسلات الطويلة، هو حامل تلاتة + +30 +00:02:53,430 --> 00:02:56,410 +substituents، يود و بروم و كلور، لما نذكرهم + +31 +00:02:56,410 --> 00:03:00,870 +alphabetically، two bromo, one cloro, one iodo, + +32 +00:03:01,090 --> 00:03:06,750 +one probine لكن، ضالت المشكلة، هل يترى هذا المركب + +33 +00:03:06,750 --> 00:03:12,470 +cis ولا trans؟اللي بتيجي تفكر بالعلم البسيط اللي + +34 +00:03:12,470 --> 00:03:18,050 +اتعلمته هتفكر بالقاتل انه احنا قولنا اذا في عندى + +35 +00:03:18,050 --> 00:03:21,430 +مثلا مجموعتين زي بعض كنا نقول كلور و كلور عجية + +36 +00:03:21,430 --> 00:03:26,130 +واحدة سس عجيتين متعاكسات Trans لكن الحمد لله هذا + +37 +00:03:26,130 --> 00:03:33,460 +المركب فيه اربع مجموعات مختلفة وبناء على ذلكرغم ان + +38 +00:03:33,460 --> 00:03:36,580 +انتوا قادرين تقولوا انه منه two compounds، two + +39 +00:03:36,580 --> 00:03:39,720 +stereoisomers، بس ولا واحدة قادرة تقول سيس ولا + +40 +00:03:39,720 --> 00:03:44,900 +ترانس تمام؟ الحقيقة الظاهرة هنا شوية اكبر من السيس + +41 +00:03:44,900 --> 00:03:49,660 +والترانس لما نيجي نحلها، بنحلها بالشكل القاتل، + +42 +00:03:49,660 --> 00:03:53,980 +بنسأل نفسنا، بنقول بدنا نقارن هذه الذرة وهذه + +43 +00:03:53,980 --> 00:04:00,320 +الذرة، يود وكلور، هدول مختلفتان، مين فيهم إلها + +44 +00:04:00,320 --> 00:04:05,880 +atomic number أعلى؟واضح؟ طبعا مابديش حد يقول مرة + +45 +00:04:05,880 --> 00:04:08,840 +تانية مش حافظ الجدول الدوري انا مابديش ال atomic + +46 +00:04:08,840 --> 00:04:15,380 +number انا بدي مقارنة والمقارنة الأصل معروفة معروف + +47 +00:04:15,380 --> 00:04:18,740 +جزء الجدول الدوري مائة مرة حكينا اللي فيه carbon, + +48 +00:04:18,960 --> 00:04:22,160 +nitrogen, oxygen, fluorine, chlorine, bromine, + +49 +00:04:22,160 --> 00:04:26,200 +iodine, sulfur هذي أعلى من هذه أعلى من هذه أعلى من + +50 +00:04:26,200 --> 00:04:30,350 +هذه أعلى من هذه أعلى من هذه أعلى من هذه واضح؟هذا + +51 +00:04:30,350 --> 00:04:34,670 +الكلام معروف اذا لما انا بدي اقارن يود مع كلور مين + +52 +00:04:34,670 --> 00:04:39,890 +الأعلى ال يود ممتازة في ال atomic number لما بدي + +53 +00:04:39,890 --> 00:04:45,150 +اقارن بروم مع كاربون اطلع ذرة ذرة مديش اقول مع ال + +54 +00:04:45,150 --> 00:04:48,550 +CH3 لأ مع الذرة المتصلة مباشرة مع اي ذرة المتصلة + +55 +00:04:48,550 --> 00:04:53,090 +مباشرة بال double bond كاربون الذرة هنا بروم مين + +56 +00:04:53,090 --> 00:04:58,510 +أعلى بروم ولا كاربونأكيد لبروم، الآن هذه الأعلى و + +57 +00:04:58,510 --> 00:05:03,350 +هذه الأعلى إجوا على جهة واحدة، في هذه الحالة كإني + +58 +00:05:03,350 --> 00:05:09,210 +بتخيل إنه المركب إيش؟ سس، لو إجيت هنا يود و كلور، + +59 +00:05:09,210 --> 00:05:17,270 +اليود أعلىبروم و Carbon البروم أعلى بناء على ذلك + +60 +00:05:17,270 --> 00:05:23,790 +المجموعات الأعلى أتوا على جهتين متعاكستين كأن هذا + +61 +00:05:23,790 --> 00:05:30,070 +المركب Trans لكن الحقيقة هنا جرت العادة أننا + +62 +00:05:30,070 --> 00:05:37,150 +مانستعملش مصطلح زد Trans و Cis لأ بنستعمل بديل له + +63 +00:05:37,150 --> 00:05:43,510 +ال Cis و ال Trans عادةتستعمل للمراكبات البسيطة + +64 +00:05:43,510 --> 00:05:50,170 +الواضحة اللي عمل هذه القواعد إنسان معتزب لغته لغته + +65 +00:05:50,170 --> 00:05:55,170 +ألمانية احنا في العربي كنا نستعمل بدل cis و trans + +66 +00:05:55,170 --> 00:06:04,930 +مع و ضد الإنجليز cis و trans الآن هو ألماني مش أقل + +67 +00:06:04,930 --> 00:06:09,680 +منه قال لأ أنا بدي أجيب من اللغة الألمانيةإيش معنى + +68 +00:06:09,680 --> 00:06:14,400 +مع وإيش معنى ضد، يعني البادئة تبقى .. البادئة + +69 +00:06:14,400 --> 00:06:17,960 +بديها من اللغة الألمانية، فباللغة الألمانية مع + +70 +00:06:17,960 --> 00:06:25,940 +اللي هي together، it's zusammen، zusammen بالزدسو + +71 +00:06:25,940 --> 00:06:31,600 +زامن الآن جال من سو زامن بدي أخد حرف ال Z فال Z + +72 +00:06:31,600 --> 00:06:38,080 +هذه صارت موازية لل سس اللي بالإنقليزي و لكلمة مع + +73 +00:06:38,080 --> 00:06:46,480 +اللي احنا بنستعملها بالعربي واضح ف Z بمعنى سس من + +74 +00:06:46,480 --> 00:06:51,940 +ناحية المعنى او مع الان اتيه ايش معنى ضد برضه راح + +75 +00:06:51,940 --> 00:06:59,280 +على اللغة تبعتهانت جاجل انت جاجل اخد منها حرف ايش؟ + +76 +00:07:00,080 --> 00:07:06,360 +انت جي جن اخد منها حرف ال E فال E هذه صارت بمعنى + +77 +00:07:06,360 --> 00:07:12,040 +Trans او بمعنى ضد للناس اللي بيكتبوا باللغة + +78 +00:07:12,040 --> 00:07:17,620 +العربية واضح طبعا البعض هيقول طب احنا وقتاش نكتب + +79 +00:07:17,620 --> 00:07:23,580 +Sis و Trans و وقتاش نكتب Z و E بنقول في المراكبات + +80 +00:07:23,580 --> 00:07:30,440 +البسيطة الواضحة بنكتب Sis و Transفي المُركّبات + +81 +00:07:30,440 --> 00:07:34,680 +اللي فيها أكتر من مجموعة و بنتغلب و نحسب ال atomic + +82 +00:07:34,680 --> 00:07:41,520 +number بنكتب Z to E بالمناسبة هل هذه القواعد اللي + +83 +00:07:41,520 --> 00:07:47,160 +هي ترتيب المجموعات حسب ال atomic number جديدة؟ لأ + +84 +00:07:47,160 --> 00:07:51,020 +يعني لو أنا أخدت نفس المُركّب البسيط اللي كنت + +85 +00:07:51,020 --> 00:07:59,810 +أحكيه CL CL H H هذا المُركّب عارفينه ولا لأ؟واضح؟ + +86 +00:07:59,810 --> 00:08:04,230 +الان لو اتيت سؤالك CL او H؟ مين اعلى في ال atomic + +87 +00:08:04,230 --> 00:08:10,650 +number؟ CLCl وH هاي مختلفتان و هاي مختلفتان مين + +88 +00:08:10,650 --> 00:08:13,550 +أعلى في ال atomic number اللي أعلى في ال atomic + +89 +00:08:13,550 --> 00:08:19,270 +number على جهة واحدة إذا هذا المركب Z بس لأنه بسيط + +90 +00:08:19,270 --> 00:08:24,530 +و مبين بالنظر استعمالنا له مصطلح إيش SIS واضح و + +91 +00:08:24,530 --> 00:08:30,310 +لذلك مش غلط كبير إنه مرات بتلاقوا بعض الناس بدل + +92 +00:08:30,310 --> 00:08:35,840 +كلمة SIS بيكتبوا Z أو بدل Z بيكتبوا SIS يعنيلكن + +93 +00:08:35,840 --> 00:08:39,540 +لما انتوا بدكم شبه قاعدة عامة بنقول إذا المركبات + +94 +00:08:39,540 --> 00:08:42,980 +بسيطة في الغالب هتلاقي الكتب كاتبة معها مصطلحات + +95 +00:08:42,980 --> 00:08:48,080 +SIS وTRANS إذا شوية أصعب هتلاقي الكتب كاتبة معها + +96 +00:08:48,080 --> 00:08:53,360 +مصطلحات Z وE واضح فقط لغاية + +97 +00:08:57,330 --> 00:09:03,570 +الان هذه القواعد عادة بيسموها Can Engel de Brelog + +98 +00:09:03,570 --> 00:09:08,050 +Rules اللي هي قواعد ترتيب المجموعات حسب الأعلى في + +99 +00:09:08,050 --> 00:09:11,610 +ال atomic number هتعود تلزمنا في ال stereo + +100 +00:09:11,610 --> 00:09:16,430 +chemistry و بنكتب اسم الآن مش مستعجلين عليه خلينا + +101 +00:09:16,430 --> 00:09:22,090 +ناخدها ببساطة قواعد ترتيب المجموعات حسب الاشالـ + +102 +00:09:22,090 --> 00:09:27,030 +atomic number أحيانا بيجي نحل مشكلتنا نشوف مين + +103 +00:09:27,030 --> 00:09:31,190 +أعلى في ال atomic number هنا سهل جدا يود ولا CL + +104 +00:09:31,190 --> 00:09:37,910 +يود ابتثانية أحيانا بيلاقي الذرتين زي بعض وجدتها + +105 +00:09:37,910 --> 00:09:44,390 +بيروح للذرة اللي بعدهمبالهم زي بعض بنروح للبعدها + +106 +00:09:44,390 --> 00:09:49,610 +لحد ما نصل لأول اختلاف بيخلي مجموعة أعلى من + +107 +00:09:49,610 --> 00:09:54,090 +التانية واضح يعني مثلا هذا المركب لو كنتوا بتطلع + +108 +00:09:54,090 --> 00:09:59,950 +عليه هاي carbon شو المجموعات اللي عليها CH3 CH2 + +109 +00:09:59,950 --> 00:10:06,530 +CH3 لو أجينا نسأل مين أعلى هدول مختلفات هنا carbon + +110 +00:10:07,430 --> 00:10:14,550 +وهنا carbon زي بعض وقت أروح للذرة التانية لو بدكوا + +111 +00:10:14,550 --> 00:10:20,430 +بالتفصيل الممل أكيد هتقولوا أن هنا في عندي H وH و + +112 +00:10:20,430 --> 00:10:31,390 +بعدها carbon هذه H وH و بعدها H فلو إجيتوا تقارنوا + +113 +00:10:31,390 --> 00:10:38,490 +C وحملة كل هذا زي بعضه C وحملةوين أول اختلاف؟ نمر + +114 +00:10:38,490 --> 00:10:43,810 +اتنين carbon، نمر اتنين H، اذا من المجموعة الأعلى + +115 +00:10:43,810 --> 00:10:50,010 +صفيات؟ فانا لما بمشي في المجموعاتبالترتيب يعني + +116 +00:10:50,010 --> 00:10:53,090 +الذرة الأولى ماحلتش المشكلة عند ما قالتليش مين + +117 +00:10:53,090 --> 00:10:57,330 +أعلى في ال atomic number بروح لا إيش للي بعدها أول + +118 +00:10:57,330 --> 00:11:01,370 +ذرة بتعمل الفرق هي اللي بتحدد هل هذه المجموعة أعلى + +119 +00:11:01,370 --> 00:11:05,050 +و هدى مع الخبرة بيصير سهل عليكم أنه لو بتشوفوا زي + +120 +00:11:05,050 --> 00:11:09,090 +إثل و مثل أنه بتاني تقولوا ال إثل بدون ما تقعدوا + +121 +00:11:09,090 --> 00:11:14,110 +تعملوا كل هالتحليل لكن القاعدة العامة ذرة ذرة + +122 +00:11:14,110 --> 00:11:14,950 +بنكون ماشيين + +123 +00:11:17,660 --> 00:11:24,700 +انجلي حالك صعب ان انا اعيد كتاب واضح و لذلك هذه + +124 +00:11:24,700 --> 00:11:30,040 +الاثل صارت اعلى من المثل الان هنحطين مركب او + +125 +00:11:30,040 --> 00:11:37,260 +مجمعتين شويه كبار لاحظوا carbon و carbonزي بعض هذه + +126 +00:11:37,260 --> 00:11:42,740 +carbon و هذه الذرة carbon الان هذه ال carbon متصلة + +127 +00:11:42,740 --> 00:11:47,700 +ب CH3 و هذه ال carbon متصلة ب CH3 كل ما هو مشترك + +128 +00:11:47,700 --> 00:11:51,480 +لن يحدد الفرق شو اللي بده يحدد الفرق؟ شي مختلف + +129 +00:11:51,480 --> 00:11:57,440 +الان بعد هيك هذه متصلة برابطة واحدة مع ال O هذه + +130 +00:11:57,440 --> 00:12:02,190 +متصلة بكم رابطة مع ال O؟ برابطة تانيةيعني كأنه هذه + +131 +00:12:02,190 --> 00:12:06,910 +متصلة بـ O وهذه متصلة بـ O اتفقنا طب الرابط الرابع + +132 +00:12:06,910 --> 00:12:14,480 +هنا H هنا Oابتبوا معي عاملوا هذه كإنها رابطتين مع + +133 +00:12:14,480 --> 00:12:18,080 +O و هذه كإنها رابطة يعني لو جيت سألت الأربع روابط + +134 +00:12:18,080 --> 00:12:24,980 +اللي على ال carbon واحدة مع CH3 مع CH3 مع O مع O + +135 +00:12:24,980 --> 00:12:29,640 +مع ال carbon هذه مع ال carbon هذه إيش ضال؟ الرابعة + +136 +00:12:29,640 --> 00:12:36,620 +مع H الرابعة مع O رابطة التانية، أنه أعلى و لذلك + +137 +00:12:36,620 --> 00:12:41,900 +كل المجموعة هذه صارت أعلىواضح؟ فأنا بالتدريج بقدر + +138 +00:12:41,900 --> 00:12:45,300 +أحل المشاكل الآن هذولا المجمعتين العليا على جهة + +139 +00:12:45,300 --> 00:12:52,100 +واحدة إذا هذا المركب إيش؟ Z واضح؟ هاي مركب تالت + +140 +00:12:52,100 --> 00:12:58,940 +هاي عندكم يود و كلور هذه الحالة السهلة من أعلى ال + +141 +00:12:58,940 --> 00:13:05,040 +يود أعلى من الكلور okay الآن هنا عندك carbon و + +142 +00:13:05,040 --> 00:13:07,100 +carbon + +143 +00:13:09,230 --> 00:13:13,670 +الذرتين زي بعض طالما زي بعض بتطلع على الذرات اللي + +144 +00:13:13,670 --> 00:13:18,610 +بعضهم هذه ال carbon متصلة ب carbon الرابطة الأولى + +145 +00:13:18,610 --> 00:13:24,090 +و الرابطة الثانية ب carbon و التالتة ب H يعني لو + +146 +00:13:24,090 --> 00:13:29,570 +جيتوا التلت روا بتاعونها carbon carbon H تعالوا + +147 +00:13:29,570 --> 00:13:36,410 +على هذه carbon carbon carbon اذا مين أعلى شوفت + +148 +00:13:36,410 --> 00:13:40,490 +واحدة افرجتهمفبصير كل هذه المجموعة على و لذلك هذا + +149 +00:13:40,490 --> 00:13:46,770 +المُركّب Z الآن بالتدريب بإمكانكم تتعودوا من خلال + +150 +00:13:46,770 --> 00:13:51,030 +حل أسئلة امتحانات سابقة او اشهر تلاحظوا و تميزوا + +151 +00:13:51,030 --> 00:13:54,570 +المُركّبات اللي فيها Z و E لكن في كل الأحوال إذا + +152 +00:13:54,570 --> 00:13:59,630 +إجاكوا تسمية ال keenإذا إجاكوا تسمية ال keen بتكون + +153 +00:13:59,630 --> 00:14:03,170 +تتطلعوا على أطراف ال double bond اللي موجودة فيه + +154 +00:14:03,170 --> 00:14:06,990 +إذا عليها مجموعات مختلفة ومجموعات مختلفة يجب أن + +155 +00:14:06,990 --> 00:14:12,950 +يوجد في التسمية z أو e وإذا كان الأمر بسيط جدا + +156 +00:14:12,950 --> 00:14:18,650 +ممكن تكتبوا cis وtrans واضح؟ ممكن تكتبوا cis + +157 +00:14:18,650 --> 00:14:23,630 +وtrans هذا بالنسبة لاستعمال البادئة z وe + +158 +00:14:26,930 --> 00:14:32,890 +الان بننتقل لموضوع جديد اللي هو تفاعلات ال الكنز + +159 +00:14:32,890 --> 00:14:39,090 +ال الكنز اللي هم تفاعل أساسي هتلاحظوا انه بتكرر + +160 +00:14:39,090 --> 00:14:44,470 +عندى كثير هذا التفاعل الأساسي اللي لل الكنز بسميه + +161 +00:14:44,470 --> 00:14:50,450 +انا addition reaction addition تفاعل إيش الإضافة + +162 +00:14:50,860 --> 00:14:55,580 +إيش هو باختصار تفاعل الإضافة؟ باختصار إنه بيكون + +163 +00:14:55,580 --> 00:15:00,650 +عندي carbonDouble bond carbon هاي ال double bond + +164 +00:15:00,650 --> 00:15:05,250 +يعني بركز تفاعل وين؟ ع ال double bond لما أجي أضيف + +165 +00:15:05,250 --> 00:15:10,250 +عليها أي reagent زي خلينا هيك ناخده بشكل عام HX + +166 +00:15:10,250 --> 00:15:14,810 +بيصير carbon single bond carbon لاحظوا ال double + +167 +00:15:14,810 --> 00:15:21,910 +bond صارت single bond ال bi bond هادي اتحولت لإيش؟ + +168 +00:15:21,910 --> 00:15:31,810 +انضاف رابطتين بدالها هنا Hو X اتش و X اتش و X اللي + +169 +00:15:31,810 --> 00:15:37,310 +انضافوا واضح طبعا هنا في عنده أشياء تانية كانت + +170 +00:15:37,310 --> 00:15:42,770 +موجودة بتظل زي ما هيأي ما كانت تكون يعني هذا + +171 +00:15:42,770 --> 00:15:46,170 +المركب شكله الكامل carbon عليها رابطات المتصلات + +172 +00:15:46,170 --> 00:15:49,830 +بإيش ما كان مش موضوعي وهذه نفس الاشياء أنا تركيزي + +173 +00:15:49,830 --> 00:15:55,770 +على carbon double bond carbon بخليها carbon single + +174 +00:15:55,770 --> 00:16:02,040 +bond carbon الآن هذه ال by bond اتحولت لإيشلـ two + +175 +00:16:02,040 --> 00:16:06,840 +new sigma bonds يعني تفاعل الـ addition لو بدي + +176 +00:16:06,840 --> 00:16:14,560 +تعريف له بدي أقول تحويل ال buy bond هذه الى two + +177 +00:16:14,560 --> 00:16:24,210 +new sigma bondsواضح تحويل ال buy bond ل two new + +178 +00:16:24,210 --> 00:16:28,990 +sigma bonds او ال double bond صارت single bond هذا + +179 +00:16:28,990 --> 00:16:33,510 +هو التفاعل الأساسي في ال ال keys تفاعل ال addition + +180 +00:16:33,510 --> 00:16:39,050 +ان احول انا ال double bond ل single bond واضح الان + +181 +00:16:39,050 --> 00:16:45,210 +لو بدنا نتطلع على مكونات هذا التفاعل هلاحظ ان هذا + +182 +00:16:45,210 --> 00:16:52,150 +التفاعل بتكون من شغلتينبتكون من الكين اللى بتم + +183 +00:16:52,150 --> 00:16:57,250 +عليه التفاعل والمادة المتفاعلة بسميها reagent واضح + +184 +00:16:57,250 --> 00:17:04,610 +فالكين هيكم شايفينه ال الكين بتفاعل مع ال reagent + +185 +00:17:04,610 --> 00:17:11,620 +اللى انا بدي اضيفه بيعمل additionمكونات عملية + +186 +00:17:11,620 --> 00:17:17,540 +الإضافة الكينورياجين الان لو بدى أطلع على أحوال + +187 +00:17:17,540 --> 00:17:21,260 +الألكين اللى موجود عندى هذا الألكين اللى موجود + +188 +00:17:21,260 --> 00:17:26,900 +عندى يمكن أن يكون ألكين متماثل ويمكن أن يكون ألكين + +189 +00:17:26,900 --> 00:17:34,660 +غير متماثل يعنى الألكين ممكن يكون symmetric متماثل + +190 +00:17:34,660 --> 00:17:38,000 +أو متشابه أو unsymmetric + +191 +00:17:40,420 --> 00:17:44,840 +خلّينا نعطيكم مثال على كل واحد، إيش يعني symmetry؟ + +192 +00:17:44,840 --> 00:17:49,200 +لو افترضت الألكين اللي عندى إيثيلين أبسط واحد، + +193 +00:17:49,200 --> 00:17:59,040 +يعني C double bond C وهنا H اتنين تلاتة أربعةهذا + +194 +00:17:59,040 --> 00:18:02,280 +متماثل ولا لأ؟ يعني لو اتخيلت ان هنا في مرايا + +195 +00:18:02,280 --> 00:18:06,460 +carbon CH2 و carbon CH2 هذا symmetric alkene ولا + +196 +00:18:06,460 --> 00:18:11,580 +لأ؟ أكيد الآن ممكن ناخد unsymmetric alkene لو + +197 +00:18:11,580 --> 00:18:16,980 +افترضت انه عند البروبين C double bond C حطيت هنا H + +198 +00:18:16,980 --> 00:18:25,720 +OH و هنا H و هنا CH3 البروبينهل يا ترى هذا الالكين + +199 +00:18:25,720 --> 00:18:32,180 +متماثل؟ هذا متماثل + +200 +00:18:32,180 --> 00:18:42,280 +CH2 CH2 هذا CH2 CH3 إذا الالكين ممكن يكون + +201 +00:18:42,280 --> 00:18:49,080 +symmetric وممكن يكون unsymmetric واضح الفكرة؟ الآن + +202 +00:18:49,080 --> 00:18:54,230 +لو جيت لل reagent اللي بدي أضيفهنفس الاشي كمان + +203 +00:18:54,230 --> 00:18:58,210 +ممكن يكون symmetric يعني الشغلتين زي بعض او + +204 +00:18:58,210 --> 00:19:03,270 +unsymmetric ناخد أنفلة بسيطة مثلا لو ناس بيضيفوا + +205 +00:19:03,270 --> 00:19:10,390 +الهيدروجين الهيدروجين عبارة عن ايش H وH هله + +206 +00:19:10,390 --> 00:19:14,730 +symmetric ولا لأ symmetric لو ناس بيضيفوا برومين + +207 +00:19:14,730 --> 00:19:17,470 +PR PR + +208 +00:19:19,970 --> 00:19:23,850 +Symmetric ولا لأ؟ Symmetric طب لو بدي أشوف الـ + +209 +00:19:23,850 --> 00:19:33,350 +Unsymmetric لو ناس بيضيفوا ميّه H و OH زي هي كي + +210 +00:19:33,350 --> 00:19:40,550 +بنعتبرها قطعة تانية H و OH لو بيضيفوا HBR او HCL + +211 +00:19:40,550 --> 00:19:48,840 +هاي HCL او HBR واضح ف ..اللي بنلاحظه لما بنعمل هذه + +212 +00:19:48,840 --> 00:19:52,280 +العملية ان ال الكين ممكن يكون symmetric او + +213 +00:19:52,280 --> 00:19:55,200 +unsymmetric و ال reagent ممكن يكون symmetric او + +214 +00:19:55,200 --> 00:20:01,800 +unsymmetric طيب عملية الإضافة كام ناتج بتطلع؟عملية + +215 +00:20:01,800 --> 00:20:08,040 +الإضافة في حالة واحدة بتطلع ناتجين بدنا نكون + +216 +00:20:08,040 --> 00:20:12,000 +منتبهين لها تماما، بعد ذلك بتطلع عندي ناتج واحد + +217 +00:20:12,000 --> 00:20:18,840 +إذا ضفت Unsymmetric reagent على Unsymmetric alkene + +218 +00:20:18,840 --> 00:20:27,500 +بتوقع ناتجين الآن بنرسمهم و بنوضحهممعد ذلك لو ضيفت + +219 +00:20:27,500 --> 00:20:29,940 +symmetric على symmetric أو symmetric على + +220 +00:20:29,940 --> 00:20:36,700 +unsymmetric ناتج واحد إذا متى يتوقع ناتجين؟ إذا + +221 +00:20:36,700 --> 00:20:41,980 +أنا بضيف unsymmetric alkene على unsymmetric + +222 +00:20:41,980 --> 00:20:46,720 +reagent هذه الحالة على طول يتوقع فيها كم ناتج؟ + +223 +00:20:46,720 --> 00:20:55,920 +ناتجين معد ذلك فيطلع عندى ناتج واحدخلّينا نبدأ + +224 +00:20:55,920 --> 00:21:02,300 +نشوف أمثلة على الحالات اللي بنضيف فيها أحد الأطراف + +225 +00:21:02,300 --> 00:21:06,820 +symmetric، قدش هيطلع عندنا؟ ناتج واحدة، بعدها + +226 +00:21:06,820 --> 00:21:12,020 +بننتقل لـ unsymmetric مع unsymmetric و بنشوف + +227 +00:21:12,020 --> 00:21:15,740 +ناتجين، نمشي الآن مع ال slides + +228 +00:21:26,510 --> 00:21:32,170 +هذه أول تفاعل لو احنا يا تورا بدنا نضيف الهيدروجين + +229 +00:21:32,170 --> 00:21:37,110 +الهيدروجين سيمتريك ولا انسيمتريك؟ سيمتريك إذا كام + +230 +00:21:37,110 --> 00:21:41,410 +ناتج بتوقع يطلع عنده؟ ناتج واحد أي أن كان الالكيد + +231 +00:21:41,410 --> 00:21:44,570 +سواء كان هذا الالكيد سيمتريك أو انسيمتريك طالما + +232 +00:21:44,570 --> 00:21:50,450 +الهيدروجين متماثل إذا اللي هيطلع عنده ناتج واحد + +233 +00:21:50,450 --> 00:21:54,930 +الآن لو بدنا نكتب هذا الناتج بدنا نضيف هيدروجين + +234 +00:21:54,930 --> 00:22:02,870 +وهيدروجينواضح؟ انتهى الجواب هذا الكن ضفنا عليه جزء + +235 +00:22:02,870 --> 00:22:07,010 +الهيدروجين حط هيدروجين هان وهيدروجين هان صار الكن + +236 +00:22:07,960 --> 00:22:13,200 +الالكيل باضافة الهيدروجين صار عبارة عن الكل + +237 +00:22:13,200 --> 00:22:16,460 +الهيدروجين + +238 +00:22:16,460 --> 00:22:22,080 +هنا بنضيف معلومة صغيرة انه لما بيضيف بيضيف من جهة + +239 +00:22:22,080 --> 00:22:25,980 +واحدة يعني مابتيجيش ذرة هيدروجين من فوق و ذرة + +240 +00:22:25,980 --> 00:22:30,190 +هيدروجين من التحت لأ الذرتين الهيدروجين بيجوامن + +241 +00:22:30,190 --> 00:22:34,610 +جهة واحدة يعني بهذا الشكل زي ما تتخيلوا انه انا + +242 +00:22:34,610 --> 00:22:38,710 +الان ماسك جزء الهيدروجين هذا قاعد بضيفه نفترض هان + +243 +00:22:38,710 --> 00:22:44,370 +دابل بوند الذرتين اجوا على الجهة هذه ما بيجيشبجهات + +244 +00:22:44,370 --> 00:22:48,990 +متعاكسة الان هذه الإضافة اللى من جهة واحدة انا + +245 +00:22:48,990 --> 00:22:53,630 +بسميها sin addition لو كان بضيف من جهتين عكس بعض + +246 +00:22:53,630 --> 00:22:57,890 +بسميها ايش Anti addition فالهيدروجين هنا ايش نوع + +247 +00:22:57,890 --> 00:23:03,230 +الإضافة اللى بعملها sin addition معنى sin addition + +248 +00:23:03,230 --> 00:23:09,360 +انه بضيف من جهة واحدةواضح؟ معنى sin addition انه + +249 +00:23:09,360 --> 00:23:15,160 +بيضيف من جهة واحدة ممكن نعطي تفسير سريع ليش + +250 +00:23:15,160 --> 00:23:19,360 +الهيدروجين بيضيف من جهة واحدة لو بتطلعوا بالاتباه + +251 +00:23:19,360 --> 00:23:25,260 +هذا التفاعل بتم من خلال إضافة غاز الهيدروجين في + +252 +00:23:25,260 --> 00:23:30,660 +وجود معدن هذا المعدن غالبا بنستعمل بلاتين قطع من + +253 +00:23:30,660 --> 00:23:37,380 +المعدن الصغيرةبلاتين ممكن نستعمل معدن تاني ممكن + +254 +00:23:37,380 --> 00:23:42,820 +نستعمل بلاديم ممكن نستعمل nickel وعشانك مرات + +255 +00:23:42,820 --> 00:23:48,340 +بتلاحظوا مكتوب عندكم ايش ام ايش يعني ام هنا metal + +256 +00:23:48,340 --> 00:23:55,460 +في وجود metal catalyst هذا عامل حفاز catalyst ام + +257 +00:23:55,460 --> 00:24:01,940 +يعني metalكتاليست ايش كتاليست؟ أعمل حفاظ أعمل حفاظ + +258 +00:24:01,940 --> 00:24:06,100 +الآن هذا ال كتاليست ممكن يكون platinum ممكن يكون + +259 +00:24:06,100 --> 00:24:11,140 +palladium ممكن يكون nickel واضح هذا بيخلي التفاعل + +260 +00:24:11,140 --> 00:24:16,860 +يمشي بشكل سريع طب إيش بيعمل هذا الكتاليست؟ هذا + +261 +00:24:16,860 --> 00:24:21,180 +الكتاليست يلتصق الهيدروجين على سطحه يعني تخيلوا + +262 +00:24:21,180 --> 00:24:27,310 +هذا هو الكتاليستهذا سطح معدن هو الـ catalyst الان + +263 +00:24:27,310 --> 00:24:32,030 +الهيدروجين كجزء بيجي يلتصق على سطح ال catalyst + +264 +00:24:32,030 --> 00:24:37,870 +طالما يلتصق على سطح ال catalyst بهذا الشكل لما + +265 +00:24:37,870 --> 00:24:42,370 +بيجي يضيف ع double bond هاي double bond شايفينهم؟ + +266 +00:24:42,370 --> 00:24:47,170 +هل ممكن هو ملتصق انه يضيف من جهتين؟ لأ بيجي زي هيك + +267 +00:24:47,170 --> 00:24:56,280 +زي هيكوترك الميتل كان ممسوك بالميتل جزء الهيدروجين + +268 +00:25:00,170 --> 00:25:05,170 +ضاف بهذا الشكل وبناء على ذلك ضاف من جهة واحدة + +269 +00:25:05,170 --> 00:25:11,170 +فبنقول احنا ان ال hydrogen gas adsorbs to the + +270 +00:25:11,170 --> 00:25:15,510 +metal surface لاحظوا تتذكروا معنا كلمة adsorption + +271 +00:25:15,510 --> 00:25:22,070 +adsorption شو معناها التصاق على السطح بديش اسمع + +272 +00:25:22,070 --> 00:25:29,510 +كلمة امتصاص كلمة امتصاصabsorption بالعربي شو + +273 +00:25:29,510 --> 00:25:33,830 +بنقولها absorption ادمصاص + +274 +00:25:33,830 --> 00:25:39,170 +بالدالة لاحظوا عندكم مصطلحين عندكم مصطلحين يعني + +275 +00:25:39,170 --> 00:25:44,070 +تخيلوا high metal surface و high metal surface بده + +276 +00:25:44,070 --> 00:25:49,290 +احط شيء عليه إذا الشيء هذا التسق هنا التساق على + +277 +00:25:49,290 --> 00:25:54,110 +السطح الخارجي هذا بسميه absorption + +278 +00:25:58,830 --> 00:26:06,610 +absorption وإذا هذا الشيء دخل جوا المتل تماما زي + +279 +00:26:06,610 --> 00:26:09,430 +ما الإنسان أحيانا بياخد برهام بيحطه على الإيد + +280 +00:26:09,430 --> 00:26:14,770 +بيدخل جوا الإيد هذه العملية إيش بنسميها absorption + +281 +00:26:14,770 --> 00:26:21,630 +absorption هدولة مصطلحين باللغة العربية بنسميه + +282 +00:26:21,630 --> 00:26:30,690 +absorptionادمصاص وال absorption امتصاص واضح فال + +283 +00:26:30,690 --> 00:26:35,030 +absorption عادة بيكون at the surface على السطح ال + +284 +00:26:35,030 --> 00:26:41,780 +absorption جواواضح الفكرة؟ بالمصطلحين الآن الغاز + +285 +00:26:41,780 --> 00:26:46,680 +يا ترى بقدر يدخل جوا المعدن إذا إيش بيصيرله؟ + +286 +00:26:46,680 --> 00:26:53,580 +absorption تماما زي مثلا الفحم ما بيمطص الغازاته + +287 +00:26:53,580 --> 00:26:57,300 +عشان هيك يستعمل في الأقنعة اللي بيستعملوها في + +288 +00:26:57,300 --> 00:27:01,780 +الحروب وما إلى ذلك بيخلوا الفحم باودر على أساس + +289 +00:27:01,780 --> 00:27:06,760 +يصيرله surface كبير الغاز وين بيجي بيلتصق؟على + +290 +00:27:06,760 --> 00:27:12,080 +السطح الخارجي لبودرة الفحم ولذلك القناع أو الكمامة + +291 +00:27:12,080 --> 00:27:17,700 +تبع الحرب بتكون ملانا ايش؟ فحم لأن الغازات بيصير + +292 +00:27:17,700 --> 00:27:22,420 +الالتصاق على سطح الفحم يمكن احنا الفكرة بنستعملها + +293 +00:27:22,420 --> 00:27:27,240 +شوية تطبيقيا لما الناس مرات بيسافروا و بدهم يسيبوا + +294 +00:27:27,240 --> 00:27:31,220 +التلاجة بتاعتهم لفترة مش شغالة بيجيبوا خمس ست + +295 +00:27:31,220 --> 00:27:36,790 +فحمات و بيحطوهم بالفريزر عشان مايصلوشواضح الفكرة؟ + +296 +00:27:36,790 --> 00:27:41,350 +الآن هذا الفحم بيلتصق عليه الغاز، كذلك الـmetal + +297 +00:27:41,350 --> 00:27:46,250 +هنا بيلتصق وين؟ الهيدروجين بيلتصق على الـmetal، + +298 +00:27:46,250 --> 00:27:49,730 +الآن هذا الهيدروجين اللي ملتصق على الـmetal لما + +299 +00:27:49,730 --> 00:27:54,310 +يلاقي الـdouble bond، هيضيف عليها من جهة واحدة، + +300 +00:27:54,310 --> 00:28:00,640 +يعمل عند إيش؟Sin addition يعني هاي مثال تاني هاي + +301 +00:28:00,640 --> 00:28:04,440 +double bond الهيدروجين ملتصق على سطح المعدن، هاي + +302 +00:28:04,440 --> 00:28:08,640 +المعدن هي ملتصق لما ضاف، ضاف من جهة واحدة ولا من + +303 +00:28:08,640 --> 00:28:13,260 +جهتين؟ من جهة واحدة فما نوع الإضافة هنا؟ Sin + +304 +00:28:13,260 --> 00:28:19,200 +addition الآن، هل يا ترى الـ Sin addition تؤدي + +305 +00:28:19,200 --> 00:28:24,750 +لتكون مركب cis أو trans أو لأ؟ هذا موضوع تانيبتكون + +306 +00:28:24,750 --> 00:28:30,090 +تميزه بين شغلتين، بين شيء اسمه كيف تمت الإضافة، + +307 +00:28:30,090 --> 00:28:33,910 +بنقول قولا واحدا تمت الإضافة من جهة واحدة، the + +308 +00:28:33,910 --> 00:28:38,730 +same addition، الآن الناتج، هل يا تورا الناتج اللي + +309 +00:28:38,730 --> 00:28:43,090 +موجود عندي، cis ولا trans؟كلمة Sis و Trans تعتمد + +310 +00:28:43,090 --> 00:28:46,730 +على المجموعات اللي موجودة، يعني هنا بعد ما تمت + +311 +00:28:46,730 --> 00:28:51,670 +الإضافة، و تمت من اتجاه واحد، باجي بسأل يا ترى، + +312 +00:28:51,670 --> 00:28:57,910 +هذا في Sis و Trans؟ بقول أتش و أتش متشابهتان، و + +313 +00:28:57,910 --> 00:29:01,090 +أتش مثل مختلفتان، مافيش ظاهرة الـ Sis و الـ Trans + +314 +00:29:02,120 --> 00:29:08,160 +لكن الإضافة تمت من جهة واحدة دائما الآن إن الإضافة + +315 +00:29:08,160 --> 00:29:11,480 +اللي من جهة واحدة اللي هي الـ Sin addition هل + +316 +00:29:11,480 --> 00:29:16,080 +إجباري إنها تطلع Sis و Trans؟ لأ Sis و Trans + +317 +00:29:16,080 --> 00:29:21,760 +بتعتمد على المجموعات الموجودة ولذلك نفس هذا المثال + +318 +00:29:21,760 --> 00:29:30,330 +لو طلعته هنا هاي Double bond عليها مجموعتين مثلو + +319 +00:29:30,330 --> 00:29:35,830 +بدنا نضيف عليها هيدروجين كيف هنضيف الهيدروجين؟ من + +320 +00:29:35,830 --> 00:29:40,110 +جهة واحدة هينضفنا الهيدروجين و الهيدروجين من جهة + +321 +00:29:40,110 --> 00:29:44,750 +واحدة لتحت يعني صار عندى الحلقة الخماسية فيها + +322 +00:29:44,750 --> 00:29:49,880 +مجموعتين الميثلعلى جهة واحدة والهيدروجينز على جهة + +323 +00:29:49,880 --> 00:29:54,760 +واحدة الان هذا المركب في سيس وترانز اطلعوا كاربون + +324 +00:29:54,760 --> 00:29:59,840 +حاملة مثل و اتش مختلفتان كاربون حاملة مثل و اتش + +325 +00:29:59,840 --> 00:30:04,280 +مختلفتان المثل والمثل على جهة واحدة اذا هذا المركب + +326 +00:30:04,280 --> 00:30:09,760 +سيس لاحظوا هنا صار عندي sin addition ادى لتكون + +327 +00:30:09,760 --> 00:30:15,460 +المركب الـSYS في المثال السابق صار عندي sin + +328 +00:30:15,460 --> 00:30:22,670 +additionما اداش لأشي ف ال sim addition دائما موجود + +329 +00:30:22,670 --> 00:30:26,590 +يؤدي ل sis او trans او مايكونش موجود هذا بيعتمد + +330 +00:30:26,590 --> 00:30:32,790 +على طبيعة المجموعات اللي موجودة وين على الalkene + +331 +00:30:32,790 --> 00:30:39,270 +هذا بالنسبة للجزء الأول اللي هو إضافة الهيدروجين + +332 +00:30:39,270 --> 00:30:45,400 +لاحظوا يمكن بيظل عندى كلمةموجودة في العنوان و لازم + +333 +00:30:45,400 --> 00:30:52,060 +نجف عندها سمى العملية reduction of alkenes هو ال + +334 +00:30:52,060 --> 00:31:05,760 +alkene هنا، شو صار؟ ال alkene صار ال ال ال ال ال + +335 +00:31:05,760 --> 00:31:05,840 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +336 +00:31:05,840 --> 00:31:05,840 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +337 +00:31:05,840 --> 00:31:05,920 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +338 +00:31:05,920 --> 00:31:06,060 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +339 +00:31:06,060 --> 00:31:06,060 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +340 +00:31:06,060 --> 00:31:06,060 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +341 +00:31:06,060 --> 00:31:06,060 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +342 +00:31:06,060 --> 00:31:06,060 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +343 +00:31:06,060 --> 00:31:06,060 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +344 +00:31:06,060 --> 00:31:06,060 +ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال + +345 +00:31:06,060 --> 00:31:10,590 +ال الالان احنا في ال organ ال chemistry في عندنا + +346 +00:31:10,590 --> 00:31:15,270 +قاعدة لما المركبات بتتحول من عائلة لعائلة لعائلة + +347 +00:31:15,270 --> 00:31:19,450 +لعائلة إذا تحولت باتجاه معين بقول هذه العملية + +348 +00:31:19,450 --> 00:31:24,430 +oxidation وإذا تحولت باتجاه آخر بقول هذه العملية + +349 +00:31:24,430 --> 00:31:31,090 +reduction فانا لو بدأ أعطيكم مختصر لهذا الأمر بقول + +350 +00:31:31,090 --> 00:31:40,850 +أبسط الأشياء ال alkanesتمام بعدها ال الكيلز بعد + +351 +00:31:40,850 --> 00:31:46,030 +هيك ربما عند ال alcohols ال RCH2OH + +352 +00:31:46,030 --> 00:31:52,350 +بعد هيك في عندك ال ketones و ال aldehydes اللي + +353 +00:31:52,350 --> 00:31:59,130 +فيهم C double bond O بعدهم الأحمار C double bond O + +354 +00:31:59,130 --> 00:32:06,780 +OH و أعلى مرتبة في الأكسدةتاني اكسيد الكربون اللى + +355 +00:32:06,780 --> 00:32:11,420 +متصل باربع روابط اكسجين الان اذا اتحولنا من الكن + +356 +00:32:11,420 --> 00:32:16,880 +لالكين فالعملية اكسدة من الكن لالكاي بعد شوية كمان + +357 +00:32:16,880 --> 00:32:22,320 +اكسدة لالكهول اكسدة لالديهايد اكسدة لاحظوا انا + +358 +00:32:22,320 --> 00:32:26,620 +عندى رابطة احدية مع الاكسجين هنا رابطتين في + +359 +00:32:26,620 --> 00:32:31,110 +الكيتون هناتلاتة للي بدهم يفهموا الأكسدا حتى من + +360 +00:32:31,110 --> 00:32:37,410 +ناحية ال Oxygen هنا أربعة الآن إذا مشينا بالعكس + +361 +00:32:37,410 --> 00:32:42,370 +بنقول العملية reduction عشان هيك لما ندرس الكيميا + +362 +00:32:42,370 --> 00:32:46,190 +بعد شوية نحول الكحول لالديهايد أو كيتون شو هنسمي + +363 +00:32:46,190 --> 00:32:50,870 +العملية؟ أكسدا يعني لما ندرس شapter ال alcohol و + +364 +00:32:50,870 --> 00:32:55,170 +بنقول alcohol اتحول لالديهايد أو كيتون هنسمي + +365 +00:32:55,170 --> 00:33:02,560 +العملية أكسدا كيتونرجع لالكهن Reduction الكن صار + +366 +00:33:02,560 --> 00:33:09,140 +الكن Oxidation الكن رجع ل الكن Reduction واضح؟ + +367 +00:33:09,140 --> 00:33:17,560 +فضمن هالسلسلة بنقدر نفهم .. ضمن هالسلسلة بنقدر + +368 +00:33:17,560 --> 00:33:22,860 +نفهم اللي احنا بنعنيه بالأكسدة والاختزال هذه كلها + +369 +00:33:22,860 --> 00:33:28,020 +أمثلة بتوضح كيف ضفنا ال hydrogenالان التفاعل + +370 +00:33:28,020 --> 00:33:33,440 +التاني إضافة لبروم مرة تانية لبروم Symmetric ولا + +371 +00:33:33,440 --> 00:33:39,180 +Unsymmetric؟ Symmetric Reagent لكن بالتجربة .. + +372 +00:33:39,180 --> 00:33:43,400 +بالدليل التجريبي مش كل شيء بالفصل فيه اللي لاحظوا + +373 +00:33:43,400 --> 00:33:48,660 +أن لبروم لما بيضيف .. بيضيف Anti addition من جهتين + +374 +00:33:48,660 --> 00:33:54,320 +متعاكستينيعني ما بيضيفش من نفس الجهة، لاحظوا هاي + +375 +00:33:54,320 --> 00:33:59,680 +الكين ضفنا عليه برومين أعطانا sin ولا anti + +376 +00:33:59,680 --> 00:34:04,700 +addition؟ Anti addition إذا الهيدروجين كأول + +377 +00:34:04,700 --> 00:34:09,360 +symmetric reagent ضاف من جهة واحدة لبرومين، يعني + +378 +00:34:09,360 --> 00:34:12,460 +لو تخيلت أن هذا جزء لبرومين و جاي يضيف على double + +379 +00:34:12,460 --> 00:34:19,650 +bond هنابيضيف من جهتين مختلفتين الآن مرة تانية + +380 +00:34:19,650 --> 00:34:25,570 +لبرومين دائما Anti-addition يعطي cis أو trans لأ + +381 +00:34:25,570 --> 00:34:32,610 +حسب الجزاء اللي موجود عنده حسب المجموعات اللي + +382 +00:34:32,610 --> 00:34:36,310 +موجودة على الجزاء عنده ممكن يعطي cis ممكن يعطي + +383 +00:34:36,310 --> 00:34:41,190 +trans ممكن مايعطيش إشي واضح؟ يعني في حالة زي هذه + +384 +00:34:41,190 --> 00:34:46,260 +لما بيضيف لو افترضنا ان هدولة كلهم Hydrogensلأ + +385 +00:34:46,260 --> 00:34:54,520 +طبعا لأ اكيد اكيد لأ لو افترضنا ان البروميل بيضيف + +386 +00:34:54,520 --> 00:35:00,060 +على الهيدروجين كل هدول الذرات الأربعة ما زالوا + +387 +00:35:00,060 --> 00:35:06,320 +هيدروجين الان لاحظوا زملتكم على طول غلطة، غلطة + +388 +00:35:06,320 --> 00:35:14,060 +كبيرة جد البحر ليش؟لأنه قلنا ظاهرة الـcis والترانس + +389 +00:35:14,060 --> 00:35:18,780 +أساسا كظاهرة يا بتنوجد حوالين ال double bond يا + +390 +00:35:18,780 --> 00:35:24,500 +حوالين ال single bond في الحلقة في منها؟ لأ وحكينا + +391 +00:35:24,500 --> 00:35:29,280 +أن هذا طالما single bond في حالة دوران دائم أبدت + +392 +00:35:29,280 --> 00:35:36,560 +هو في لحظة الإضافة بدى زي هيك لكن بعد ثانية بلوف + +393 +00:35:38,450 --> 00:35:40,690 +مافيش فيه كل ظاهرة الـcis و الـtrans الرابطة + +394 +00:35:40,690 --> 00:35:44,970 +الوحيدية فيها ظاهرة الـcis و الـtrans لا مافيش + +395 +00:35:44,970 --> 00:35:49,070 +فيها ظاهرة الـcis و الـtrans لكن الإضافة في لحظة + +396 +00:35:49,070 --> 00:35:54,270 +الإضافة كيف ضافوا إن فكوا الظارتين عن بعض إجت + +397 +00:35:54,270 --> 00:35:56,710 +واحدة من الأمام واحدة من الخلف هي معنى Anti + +398 +00:35:56,710 --> 00:36:02,190 +-addition إذا لو واحدة بتفكر في أي وقت بده يظهر + +399 +00:36:02,190 --> 00:36:07,720 +عند الـcis و الـtrans في الحلقاتفي الحلقات لأن + +400 +00:36:07,720 --> 00:36:14,000 +الحلقات هم الوحيدين اللي فيهم رابطة أحدية و فيهم + +401 +00:36:14,000 --> 00:36:18,360 +دائرة ال cis و ال trans انما في المناطق اللي زي + +402 +00:36:18,360 --> 00:36:23,460 +هذه مابطلعش عنده cis و trans بطلع غالبا في الحلقات + +403 +00:36:25,730 --> 00:36:30,370 +بدون ما نفصل ليش تم هذا الكلام تم بالتأكيد على + +404 +00:36:30,370 --> 00:36:33,970 +خطوطين يعني ضافة ذرة بروم وبعدين كملت البروم الجهة + +405 +00:36:33,970 --> 00:36:39,570 +التانية مش كثير مهتم بهذا ال ميكانيزم لكن خليني + +406 +00:36:39,570 --> 00:36:43,090 +أرجع مثلا على هذا المثال اللي ضيفنا فيه الهيدروجين + +407 +00:36:43,090 --> 00:36:49,050 +لو كنا جايبينه في الامتحان وقلنالكم أكمل وهينضيفنا + +408 +00:36:49,050 --> 00:36:53,390 +الهيدروجين بهذا الاتجاه وبالاتجاه التاني قلنا لكم + +409 +00:36:54,740 --> 00:37:00,080 +ضيفنا الـ PR 2 كيف + +410 +00:37:00,080 --> 00:37:06,760 +فجأة هكمل؟ هرسم + +411 +00:37:06,760 --> 00:37:13,500 +نفس الحلقة هذه بعدين + +412 +00:37:13,500 --> 00:37:24,380 +أخلي مجموعة مثل لفوق و مجموعة لتحت و ال PR لفوق + +413 +00:37:30,400 --> 00:37:38,660 +هذه لفوق وهذه PR وين بتصير؟ لتحت ال .. واضح؟ ربما + +414 +00:37:38,660 --> 00:37:45,240 +لو كانت الحلقة مرسومة بهذا الشكل يكون أسهل لكم نفس + +415 +00:37:45,240 --> 00:37:49,240 +الحلقة كأنه بتكون .. تتخيلوا بهذا الشكل كأنه عندكم + +416 +00:37:49,240 --> 00:37:59,400 +CH3 و CH3 بيصيروا عكس بعض و PR عكس بعض انتي ولا + +417 +00:37:59,400 --> 00:38:07,680 +لأ؟الان هدولة SES ولا TRANS هذا المُركّب TRANS هاي + +418 +00:38:07,680 --> 00:38:15,740 +ال PR و PR عكس بعض و مثل و مثل لأ هو انا .. بدل .. + +419 +00:38:15,740 --> 00:38:19,740 +لو النتج كان H2و بتكون تخلوا مجمعتين ال مثل ع جهة + +420 +00:38:19,740 --> 00:38:23,340 +واحدة مجمعتين ال H ع جهة واحدة بتكون تعملوا SEND + +421 +00:38:23,340 --> 00:38:26,500 +ADDITION واضح؟ + +422 +00:38:33,560 --> 00:38:40,620 +لأ لأ لأ ال CH3 ال CH3 لو كان عندنا model هذا + +423 +00:38:40,620 --> 00:38:45,620 +المركب بيكونوا في نفس مستوى الحلقة مش عكس بعض + +424 +00:38:45,620 --> 00:38:51,580 +تنسوش أحيانا في معلومات مبنية على بعض لما أخدنا + +425 +00:38:51,580 --> 00:38:58,300 +الشكل الهندسي حوالين ال double bondقلنا ان حوالين + +426 +00:38:58,300 --> 00:39:03,900 +ال double bond الشكل بلانر بزاوية 120 يعني هذه + +427 +00:39:03,900 --> 00:39:11,240 +الزاوية 120 وهذه 120 وهذه 120 هدولة في مستوى واحد + +428 +00:39:11,240 --> 00:39:15,820 +لو انا بدي افرجيكم بشكل عام كيف منظرهم باخد ملزمة + +429 +00:39:15,820 --> 00:39:21,850 +من هنازي هيك بتكون تتخيلوا الحلقة لما بيكون عند + +430 +00:39:21,850 --> 00:39:26,490 +هنا double bond لو تخيلتوا هاي مجمعتين ال CH3 هدول + +431 +00:39:26,490 --> 00:39:31,170 +ناخدهم + +432 +00:39:31,170 --> 00:39:36,010 +باللون الأسمر بيكونوا في نفس مستوى الحلقة ليش لأن + +433 +00:39:36,010 --> 00:39:40,190 +هنا في عند double bond لما هنا بيكون عند double + +434 +00:39:40,190 --> 00:39:46,590 +bond هدولة في نفس المستوى تبع الحلقةواضح؟ هدولة في + +435 +00:39:46,590 --> 00:39:51,510 +نفس المستوى تبع الحلقة لما بيجي البروم اضيف بيخلي + +436 +00:39:51,510 --> 00:39:55,570 +واحدة لتحت واحدة لفوق و البروم بنعكس لو اجي + +437 +00:39:55,570 --> 00:40:01,090 +الهيدروجين اضيف بيخلي تنتين لتحت و الهيدروجين بيجي + +438 +00:40:01,090 --> 00:40:07,770 +لفوق طبعا ما عدا ما عدا ال double bond بيكون انا + +439 +00:40:07,770 --> 00:40:13,050 +في عندى كام ذرة هيدروجين في الجزء؟ تنتينهنا في + +440 +00:40:13,050 --> 00:40:15,550 +واحدة لفوق واحدة لتحت هنا واحدة لفوق واحدة لتحت + +441 +00:40:15,550 --> 00:40:20,090 +هنا واحدة لفوق واحدة لتحت لكن هذه وهذه في مستوى + +442 +00:40:20,090 --> 00:40:25,070 +الجزء هذه وهذه في مستوى الجزء شوية بنحس ان الموضوع + +443 +00:40:25,070 --> 00:40:38,210 +صعب مافيش مشكلة بالمرة ناخد دقيقة و نعمل لكم model + +444 +00:40:38,210 --> 00:40:39,970 +هتفهموا + +445 +00:40:42,640 --> 00:40:47,920 +هتفهموا الموضوع بشكل جيد عشان هي احنا بنقول ال + +446 +00:40:47,920 --> 00:40:56,080 +models مرات كتير بتساعد لاحظوا + +447 +00:40:56,080 --> 00:41:00,580 +هاي عندى حلقة خماسية طبعا هي قولنا مش planner شوية + +448 +00:41:00,580 --> 00:41:06,040 +فيها زى ال envelope مش مشكلة كبيرة هذه الان لما + +449 +00:41:06,040 --> 00:41:13,610 +بدي اجي اعمل لما بدي اجي اعمل double bondعلى جهة + +450 +00:41:13,610 --> 00:41:17,850 +من الجهات هانا بدى اعمل double bond واحدة فيها + +451 +00:41:17,850 --> 00:41:28,510 +هينعمل ال double bond تمام شو تبقى عندى مجموعة CH3 + +452 +00:41:28,510 --> 00:41:35,470 +ومجموعة تانية CH3 هين بيانتهم باللون الأصمر الان + +453 +00:41:35,470 --> 00:41:40,310 +لاحظوا هدول المجمعتين في مستوى الحلقة ولا لأ في + +454 +00:41:40,310 --> 00:41:46,380 +مستوى الحلقةالان باقي الكربونات ايش عليهم؟ كل + +455 +00:41:46,380 --> 00:41:50,260 +واحدة تنتين CH2 العلم الجديد اللي اتعلمناه واحدة + +456 +00:41:50,260 --> 00:41:58,100 +لفوق واحدة لتحت هنا عند تنتين CH2 لفوق و لتحت هنا + +457 +00:41:58,100 --> 00:42:02,440 +في عند تنتين + +458 +00:42:02,440 --> 00:42:03,260 +هيدروجين + +459 +00:42:05,710 --> 00:42:09,730 +لا فوق ولا تحت هذا هو الجزء اللي موجود عندكم الان + +460 +00:42:09,730 --> 00:42:14,090 +لاحظوا ان هدولة في مستوى واحد carbon carbon carbon + +461 +00:42:14,090 --> 00:42:19,550 +carbon carbon carbon واضح فبناء على ذلك هدولة في + +462 +00:42:19,550 --> 00:42:23,970 +البداية كان السؤال هم أساسا مثل ال sex ولا ال + +463 +00:42:23,970 --> 00:42:29,470 +transلأ في الحلقة بيكونوا على نفس المستوى مافيش + +464 +00:42:29,470 --> 00:42:32,930 +فيه sis و trans ال sis و ال trans انه في فوق و تحت + +465 +00:42:32,930 --> 00:42:35,810 +حوالين ال single bond في الحلقة مش حوالين ال + +466 +00:42:35,810 --> 00:42:41,110 +double bond في الحلقة انما هدولة جايين على جهة + +467 +00:42:41,110 --> 00:42:46,030 +واحدة اللي محتمال يكونوا فوق او تحت الحلقة لأ لما + +468 +00:42:46,030 --> 00:42:51,890 +انا بعمل الاضافة خليني افترض ان انا بدي اضيف لبروم + +469 +00:42:51,890 --> 00:42:59,330 +و خليني اعطي لبروممجمعتين زرق او للهيدروجين + +470 +00:42:59,330 --> 00:43:05,670 +ونوضحهم بروابط كبيرة قلنا + +471 +00:43:05,670 --> 00:43:12,550 +عملية الإضافة هي عملية ايش؟ كسر رابطة زوجية الان + +472 +00:43:12,550 --> 00:43:20,410 +هي نكسرتها ونحط بدالها two new sigma bonds الان لو + +473 +00:43:20,410 --> 00:43:24,270 +كنت بضيف الهيدروجين هدول هيصيروا على جهة واحدة + +474 +00:43:25,230 --> 00:43:30,450 +والمثل على جهة واحدة هذه هي الـ Sin Addition اللي + +475 +00:43:30,450 --> 00:43:38,690 +قدّت لـ SIS مرة تانية لو رجعت و كنت بدأ أضيف لبروم + +476 +00:43:38,690 --> 00:43:42,550 +وقتها + +477 +00:43:42,550 --> 00:43:49,510 +لما بدأ أكسر الرابطة بدّو هدولة يتحركوا بهذا الشكل + +478 +00:43:56,030 --> 00:44:00,630 +واضح الفكرة؟ انا كسرت الروابط لأنهم مربطين، بس هم + +479 +00:44:00,630 --> 00:44:06,710 +في النهاية فراغات يعني، بالتالي سهل يتحركوا، واضح؟ + +480 +00:44:06,710 --> 00:44:10,850 +يعني انا عشان اعملكوا الشكل اضطريتوا ان تشوفوني + +481 +00:44:10,850 --> 00:44:14,870 +بكسر الرابطة، لكن في كل الأحوال، بدكم تكونوا + +482 +00:44:14,870 --> 00:44:19,390 +فاهمين من الأساس انتوا، لاحظوا الكيميا ما هي كل + +483 +00:44:19,390 --> 00:44:24,630 +كلمة مبنية على الثانيةلحظة ما كنا بنحكي عن تعريف + +484 +00:44:24,630 --> 00:44:31,110 +الرابطة إيش قولنا هي الرابطة؟ هي مسافة في الفراغ + +485 +00:44:31,110 --> 00:44:37,990 +يعني هذه وهذه بالظبط + +486 +00:44:37,990 --> 00:44:48,790 +برات + +487 +00:44:48,790 --> 00:44:55,120 +..يعني هذه المفاهيم تعبير عن خبرة في الكيميا الآن + +488 +00:44:55,120 --> 00:45:01,480 +هذه و هذه مسافات في الفراغ واضح ليست روابط جامدة + +489 +00:45:01,480 --> 00:45:07,380 +وبالتالي انا لما اجيب برم من جهتين وهذه مسافة + +490 +00:45:07,380 --> 00:45:11,280 +بالفراغ وهذه مسافة بالفراغ هتيجي برم من فوق هذه + +491 +00:45:11,280 --> 00:45:16,750 +تنزل لتحت هتيجي برم من تحت هذه تطلع لفوقواضح؟ لما + +492 +00:45:16,750 --> 00:45:20,750 +اجيب الهيدروجين حيجي الهيدروجين و الهيدروجين بهذا + +493 +00:45:20,750 --> 00:45:25,430 +الشكل ممسكين على سطح الميتال هذه و هذه هينزلوا + +494 +00:45:25,430 --> 00:45:31,050 +لتحت الان لما انا بشتغل بروابط صلبة في الهيدروجين + +495 +00:45:31,050 --> 00:45:37,790 +كان سهل ان اوضحلكوا هذا بالموديل صح؟في البروم لما + +496 +00:45:37,790 --> 00:45:41,810 +كسرت الرابطة اضطريت ان ابين كاني بكس الرابطة لكن + +497 +00:45:41,810 --> 00:45:47,050 +هي حقيقة لما تكونوا متخيلين مسافة بالفراغ ما كسرت + +498 +00:45:47,050 --> 00:45:52,710 +رابطة فقط هذه اتحركت لأعلى اجت البروم من جهة وهنا + +499 +00:45:52,710 --> 00:45:57,850 +اجت البروم من جهة تانية حوالين ال single bond ممكن + +500 +00:45:57,850 --> 00:46:01,590 +sis و trans طالما مختلفتان مختلفتان هذا المركب + +501 +00:46:01,590 --> 00:46:06,950 +اللي طلع عندي ايشtrans واضح؟ احنا في كل الأحوال + +502 +00:46:06,950 --> 00:46:13,170 +اللي بنركز عليه أنه إضافة الـhydrogen سن إضافة + +503 +00:46:13,170 --> 00:46:17,910 +البروم أنت الآن النتيجة سلسة الـtrans تعتمد على + +504 +00:46:17,910 --> 00:46:23,570 +طبيعة الجزء هل الجزء جزء حلقي جزء غير حلقي هل + +505 +00:46:23,570 --> 00:46:29,630 +المجموعات اللي فيه إيش نوعهاواضح؟ يعني خلّيني + +506 +00:46:29,630 --> 00:46:34,290 +بثانية أستأذنكم وأستاذن الأستاذ كمان لأننا خلّصنا + +507 +00:46:34,290 --> 00:46:41,010 +لو كنا بنضيف هيدروجين على هذا الجزء اللي في الأساس + +508 +00:46:41,010 --> 00:46:47,970 +كان عليه تنتين هيدروجين يعني هذا الجزء كان بهذا + +509 +00:46:47,970 --> 00:46:54,730 +الشكل وكنا جاعدين بنضيف عليههذه الـ double bundle + +510 +00:46:54,730 --> 00:47:01,030 +في الحلقة وكنا قاعدين بنضيف عليها هيدروجينز هيصير + +511 +00:47:01,030 --> 00:47:07,470 +H لتحت وهذه لتحت وH جديدة لفوق وH جديدة لفوق طلعت + +512 +00:47:07,470 --> 00:47:11,730 +كل ظاهرة الـ cis والترانس؟ لأ تعتمد على ال + +513 +00:47:11,730 --> 00:47:15,350 +substituents يعني لما كانوا المجموعتين مثل طلع + +514 +00:47:15,350 --> 00:47:20,140 +المركب cis لكن لو افترضنا المجموعتين Hمافيش كل + +515 +00:47:20,140 --> 00:47:23,380 +الظاهرة بس في كل الأحوال انا لما ضيفت ال hydrogen + +516 +00:47:23,380 --> 00:47:28,740 +من جهة واحدة لما ضيفت ال brom عرفنا ايش معنى سنه + +517 +00:47:28,740 --> 00:47:32,920 +addition و لذلك عملية الإضافة بسميها mood of + +518 +00:47:32,920 --> 00:47:37,300 +addition ال product depends on the nature of the + +519 +00:47:37,300 --> 00:47:41,240 +molecule على طبيعة الجزيء على المجموعات اللي + +520 +00:47:41,240 --> 00:47:45,760 +موجودة أساسا على أطراف الكربون هل الجزيء حلقة مش + +521 +00:47:45,760 --> 00:47:49,780 +حلقة ما إلى ذلكو منكتفي بهذا القدر + diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/4LCpYQUb-3Q_raw.srt b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/4LCpYQUb-3Q_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..8399182caf32b1ef747e14b726a215c37e115100 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/4LCpYQUb-3Q_raw.srt @@ -0,0 +1,560 @@ +1 +00:00:04,720 --> 00:00:08,120 +الحمد لله رب العالمين والصلاة والسلام على أشرف + +2 +00:00:08,120 --> 00:00:13,340 +الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحبه + +3 +00:00:13,340 --> 00:00:17,780 +أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت + +4 +00:00:17,780 --> 00:00:22,300 +العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما + +5 +00:00:22,300 --> 00:00:28,690 +علمتنا وازيدنا علمة آمين يا رب العالمين أما بعدقد + +6 +00:00:28,690 --> 00:00:34,430 +تحدثنا في المحاضرة الماضية عن واقع العالم الإسلامي + +7 +00:00:34,430 --> 00:00:42,410 +ومن هذا الواقع واقع العالم الإسلامي هناك مشكلة + +8 +00:00:42,410 --> 00:00:49,150 +يعاني منها المسلمون في العالم وهي ما يُعرف بمشكلة + +9 +00:00:49,150 --> 00:00:55,770 +الأقليات المسلمةفي العالم هناك أقليات مسلمة في دول + +10 +00:00:55,770 --> 00:01:01,030 +العالم غير الإسلامي يبلغ عددهم حوالي خمسمية مليون + +11 +00:01:01,030 --> 00:01:08,330 +مسلم يعني حوالي ثلث عدد المسلمين في العالمما هي + +12 +00:01:08,330 --> 00:01:14,950 +مطالب الأقليات التي تطالب بها في دولها التي تكون + +13 +00:01:14,950 --> 00:01:20,350 +فيها على رأس هذه المطالب المساواة مع الأغلبية في + +14 +00:01:20,350 --> 00:01:25,430 +الحقوق المدنية والسياسية أن يشعر هؤلاء الأقليات + +15 +00:01:25,430 --> 00:01:31,970 +المسلمونأقلية المسلمة بأنها لها نفس الحقوق المدنية + +16 +00:01:31,970 --> 00:01:39,410 +والسياسية لباقي أو لباقي رعاية الدولة أو مواطني + +17 +00:01:39,410 --> 00:01:46,230 +الدولة ما المراد بالأقلية في العُرف الدولي قبل + +18 +00:01:46,230 --> 00:01:50,450 +الأقلية المسلمة ما نعرفها نعرف المراد بالأقلية + +19 +00:01:50,450 --> 00:01:55,310 +كأقلية هي مجموعة أو فئات من رعاية دولة من الدول + +20 +00:01:56,050 --> 00:02:01,190 +تنتمي من حيث العرق أو اللغة أو الدين إلى غير ما + +21 +00:02:01,190 --> 00:02:08,230 +تنتمي اليه الأغلبية ولذلك هي أقلية، فئة، جماعة من + +22 +00:02:08,230 --> 00:02:13,930 +رعاية الدولة بيكون لغتها، دينها، عرقها غير ما + +23 +00:02:13,930 --> 00:02:18,280 +تنتمي اليه الأغلبيةأما التعريف الأقلية المسلمة + +24 +00:02:18,280 --> 00:02:23,880 +كمصطلح الأقليات المسلمة فهي جماعة إسلامية تشكل + +25 +00:02:23,880 --> 00:02:29,760 +العدد الأقل من مجموع السكان وتخضع لمعاملة مختلفة + +26 +00:02:29,760 --> 00:02:36,200 +نتيجة خصائصها المختلفةوفي تعريف آخر يقول هي مجموعة + +27 +00:02:36,200 --> 00:02:42,500 +من المسلمين تعيش تحت سلطان دولة غير مسلمة وفي وسط + +28 +00:02:42,500 --> 00:02:47,840 +أغلبية غير مسلمة يعني تعيش في مجتمع لا يكون فيه + +29 +00:02:47,840 --> 00:02:54,840 +الإسلام هو الدين السائد نتحدث + +30 +00:02:54,840 --> 00:03:02,200 +عن الواقع المعاصر لبعض الأقليات الإسلامية + +31 +00:03:04,700 --> 00:03:10,300 +هناك عامل مشترك واحد يجمع أو يشترك فيه تشترك فيه + +32 +00:03:10,300 --> 00:03:15,600 +الأقليات المسلمة على و هو تعرض العقيدة والقيم + +33 +00:03:15,600 --> 00:03:21,380 +الإسلامية لتحديات أو تهديدات وهذه التحديات + +34 +00:03:21,380 --> 00:03:27,220 +والتهديدات تختلف من دولة إلى دولة حسب درجة هذه + +35 +00:03:27,220 --> 00:03:33,010 +التهديدات وتأثيرهافنجد مثلا أن أغلب مناطق التوتر + +36 +00:03:33,010 --> 00:03:38,670 +تتركز في المناطق التي توجد فيها أقليات إسلامية كما + +37 +00:03:38,670 --> 00:03:43,210 +هو الحال في جامو وكشمير و تركستان الشرقية و + +38 +00:03:43,210 --> 00:03:48,090 +الفلبين و بورما و البلقان التي سنتحدث عن أحوالها + +39 +00:03:48,090 --> 00:03:51,330 +وأوضاعها بعد قليل + +40 +00:03:55,000 --> 00:03:58,340 +ما هي الأمور التي تزيد أوضاع الأقليات الإسلامية + +41 +00:03:58,340 --> 00:04:03,260 +سوءًا؟ في هناك ثلاث أمور تجعل أوضاع الأقليات + +42 +00:04:03,260 --> 00:04:07,660 +الإسلامية أكثر سوءًا، وفي ازدياد دائم الأمر الأول + +43 +00:04:07,660 --> 00:04:12,960 +إنخفاض متوسط الدخل السنوي لأفراد الأقليات + +44 +00:04:12,960 --> 00:04:19,880 +الإسلامية قياسًا أو بالنسبة للأغلبية في هذه الدول + +45 +00:04:19,880 --> 00:04:23,780 +التي فيها هذه الأقليات الأمر الثاني إزدياد نسبة + +46 +00:04:23,780 --> 00:04:30,510 +الأمميةحيث لا تُعطى الأقليات الإسلامية فرص للتعلم + +47 +00:04:30,510 --> 00:04:36,890 +مثل رعاية أو مواطني الدولة الأمر الثالث ارتفاع + +48 +00:04:36,890 --> 00:04:40,290 +معدلات الإصابة بالأمراض والأوبئة مما يؤدي إلى + +49 +00:04:40,290 --> 00:04:45,010 +ارتفاع معدلات الوفيات في هذه الأقليات هذه أمور + +50 +00:04:45,010 --> 00:04:52,010 +ثلاثة تزيد من أوضاع الأقليات الإسلامية سوءًاأما + +51 +00:04:52,010 --> 00:04:58,250 +الأقليات المسلمة التي سنتحدث عنها في هذا المساق + +52 +00:04:58,250 --> 00:05:05,090 +فسنركز الحديث عن أهم الأقليات المسلمة التي تعاني + +53 +00:05:05,090 --> 00:05:12,590 +مشكلات في العالم وهي موجودة ومكتوبة هنا سنتحدث عن + +54 +00:05:12,590 --> 00:05:18,850 +معاناة مسلمي Myanmar في بورما ويطلق عليه مسلمي + +55 +00:05:18,850 --> 00:05:23,870 +الروهينجاو أيضًا هنتكلم عن الأقلية المسلمة في + +56 +00:05:23,870 --> 00:05:28,170 +بولغاريا في رومانيا في روسيا في القوقاز في جامو و + +57 +00:05:28,170 --> 00:05:33,930 +كشمير و كذلك في الفلبين هذا المقرر فقط من هذه + +58 +00:05:33,930 --> 00:05:39,190 +الأقليات و نبدأ الحديث عن اضطهاد مسلمي الروهينجا + +59 +00:05:39,190 --> 00:05:49,080 +في ميانيمار وهي بورماميانامار إلها اسم رسمي يعني + +60 +00:05:49,080 --> 00:05:54,860 +يطلق عليها بجمهورية اتحاد ميانامار و بورما يعبر عن + +61 +00:05:54,860 --> 00:06:01,250 +جمهورية متحدة و تقع ضمن دول جنوب شرق آسياكيف قامت + +62 +00:06:01,250 --> 00:06:05,030 +هذه الجمهورية قامت نتيجة انفصالها عن حكومة الهند + +63 +00:06:05,030 --> 00:06:10,370 +البريطانية حينما كانت بريطانيا تحتل وتستعمل الهند + +64 +00:06:10,370 --> 00:06:15,150 +فنتيجة انفصال انفصالها + +65 +00:06:15,150 --> 00:06:18,370 +عن حكومة الهند البريطانية وكانت ضمن ولايات الهند + +66 +00:06:18,370 --> 00:06:22,170 +البريطانية قبل ذلك التي تتألف من عدة ولايات مثل + +67 +00:06:22,170 --> 00:06:26,150 +بورما و كارن و كايا و شانو و غيرها من هذه الأسماء + +68 +00:06:27,140 --> 00:06:34,180 +متى دخل الإسلام لـ Burma؟ في قولين في دخول الإسلام + +69 +00:06:34,180 --> 00:06:39,740 +لهذه المناطق القول الأول يقول من أو منذ القرن + +70 +00:06:39,740 --> 00:06:45,300 +الأول الهجري وعن طريق صحابي وهو وقاص ابن مالك، هذا + +71 +00:06:45,300 --> 00:06:49,600 +قول ورأي يعني دخلها الإسلام مبكرا في قول يقول لأ + +72 +00:06:49,600 --> 00:06:55,880 +في عهد هارون الرشيد في القرن الثامن الميلاديكم + +73 +00:06:55,880 --> 00:07:00,920 +يشكل المسلمون من السكان في بورما؟ أيضا هناك قولان + +74 +00:07:00,920 --> 00:07:07,260 +في ذلك في قول يقول 4% يعني نسبة أقلية بالمقارنة مع + +75 +00:07:07,260 --> 00:07:12,290 +الديانة البوذية التي يعتنقها معظم سكان بورماوفي + +76 +00:07:12,290 --> 00:07:17,570 +قول بيقول لأ نسبتهم أكبر حوالي 15% نسبهم يعيش في + +77 +00:07:17,570 --> 00:07:23,970 +قليم أركان ويتركز أكثر المسلمين في هذا القليم + +78 +00:07:23,970 --> 00:07:29,480 +وينتمون لقبائل الروهينجاوفي أركان واحدة تبلغ نسبة + +79 +00:07:29,480 --> 00:07:35,300 +المسلمين 70% كما قلنا يعني أكتر المسلمين موجودين + +80 +00:07:35,300 --> 00:07:40,180 +في هذا الإقليم لكنهم يعيشون تحت خط الفقر بيعتدي + +81 +00:07:40,180 --> 00:07:47,880 +عليهم البوذيون دائما، بقولنا كحركة متطرفةبوذية + +82 +00:07:47,880 --> 00:07:56,700 +أصبحت رمز لطيار بوذي معادي للمسلمين هي حركة 969 + +83 +00:07:56,700 --> 00:08:02,400 +هكذا سماها أهلها وأصحابها وهي حركة لطيار بوذي يريد + +84 +00:08:02,400 --> 00:08:06,600 +عزل وتهجير المسلمين ويشرف على هذه الحركة رهبان + +85 +00:08:06,600 --> 00:08:12,500 +بوذيون متطرفونمن الحركة أجازوا وأباحوا العنف ضد + +86 +00:08:12,500 --> 00:08:18,040 +المسلمين وجعلوا العنف جائز ومن يمارسه يثاب عليه + +87 +00:08:18,040 --> 00:08:24,180 +فهذه حركة سياسية بوذية قومية أسست في مينمار + +88 +00:08:24,180 --> 00:08:29,960 +وبتعتبر الإسلام كتهديد وشك الخطر على دولة مينمار + +89 +00:08:33,030 --> 00:08:37,650 +ما هي الاضطهادات التي تعرض لها مسلمون من النمار من + +90 +00:08:37,650 --> 00:08:42,830 +السلطات الحاكمة؟ ربما أهم شيء يهمنا في الحديث عن + +91 +00:08:42,830 --> 00:08:47,830 +الأقليات الإسلامية في جميع الدول التي أشارنا إليها + +92 +00:08:47,830 --> 00:08:53,390 +هي الاضطهادات التي يتعرض لها المسلمون في هذه الدول + +93 +00:08:53,390 --> 00:08:58,710 +من الاضطهادات التي تعرض لها مسلمون من النمار واحد + +94 +00:08:58,710 --> 00:09:04,600 +مصادر جميع أموالهم المنقولة والعقاروحتى هذه + +95 +00:09:04,600 --> 00:09:10,940 +السلطات أفقرت المسلمين وجعلتهم فقراء تحت خط الفقر + +96 +00:09:10,940 --> 00:09:15,560 +ايضا من هذه الاضطهادات منعهم من مغادرة البلاد حتى + +97 +00:09:15,560 --> 00:09:20,520 +لو كان ذلك للحج منع المسلمين من أداء فريضة الحج + +98 +00:09:20,520 --> 00:09:26,460 +كذلك سجن عشرات الألاف من مسلمين ينامروا وتعذيبهم + +99 +00:09:26,460 --> 00:09:32,920 +وطردهم بغير ذنبأيضًا من هذه الإضطهادات إجبارهم على + +100 +00:09:32,920 --> 00:09:37,940 +اعتناق البوذية، مما أدى لردة حوالي خمسين ألف مسلم + +101 +00:09:37,940 --> 00:09:44,130 +عن دينهوذلك بالحديد والنار والتعذيب والاضطهاد + +102 +00:09:44,130 --> 00:09:51,110 +أيضًا من هذه الاضطهادات تغييه ديمографي لجعل أركان + +103 +00:09:51,110 --> 00:09:55,650 +إقليما بوذية نقولنا أركان يتجمع فيه أكثر عدد من + +104 +00:09:55,650 --> 00:10:00,970 +المسلمين فيريد تريد السلطات الحاكمة أن تغيرنسبة + +105 +00:10:00,970 --> 00:10:05,830 +السكان الأعلى من المسلمين وهو ما يُعرف بالتغيير + +106 +00:10:05,830 --> 00:10:09,810 +الديمографي ليكون هذا الإقليم إقليم بوذي بدل ما + +107 +00:10:09,810 --> 00:10:15,270 +تكون الأغلبية فيه مسلمة أيضًا من الاضطهادات التي + +108 +00:10:15,270 --> 00:10:19,790 +اتعرض لها مسلمه من أمار تغيير طابع أركان بتمسي + +109 +00:10:19,790 --> 00:10:24,790 +المعالم الإسلامية التاريخية مثل المساجد و المدارس + +110 +00:10:24,790 --> 00:10:29,690 +الدينية فقاموا بهدم هذه المساجد و هذه المدارس + +111 +00:10:33,030 --> 00:10:39,710 +أيضا قام هناك عنف طائفي في مينامار، وأبرز مظاهر + +112 +00:10:39,710 --> 00:10:46,290 +هذا العنف قام البوذيون سنة 1942 بمذبحة كبيرة ضد + +113 +00:10:46,290 --> 00:10:50,490 +مسلمي الروهينجا، وهي اسم القبيلة التي ينتمي إليها + +114 +00:10:50,490 --> 00:10:55,550 +مسلمون ميناماروأيضًا ساعدهم في ذلك إنجلترا أو + +115 +00:10:55,550 --> 00:11:00,430 +بريطانيا وهذه المذبحة أدت إلى أودت بحياة أكتر من + +116 +00:11:00,430 --> 00:11:07,470 +مائة ألف مسلم معظمهم نساء وشيوخ وأطفال فهذا + +117 +00:11:07,470 --> 00:11:11,890 +من أكبر مظاهر العنف اللي حدث في مينامار وكان ضد أو + +118 +00:11:11,890 --> 00:11:17,270 +كان موجها ضد الأقلية المسلمة أيضًا من ذلك مصادرت + +119 +00:11:17,270 --> 00:11:20,390 +ما يزيد عن تسعين في المائة من أراضي المسلمين + +120 +00:11:20,390 --> 00:11:25,600 +وممتلكاتهو أيضًا من هذه المظاهر، المظاهر العنف، + +121 +00:11:25,600 --> 00:11:30,480 +سحب الجنسية من عشرات الألاف من المسلمين بولاية + +122 +00:11:30,480 --> 00:11:35,220 +أركان، حتى يقوموا بالتغيير الديمографي الذي تحدثنا + +123 +00:11:35,220 --> 00:11:41,310 +عنهمن أيضًا أبرز مظاهر العنف الطائفي إبعاد نحو 28 + +124 +00:11:41,310 --> 00:11:47,770 +ألف مسلم إلى الحدود مع بنجالدش تهجير وترحيل وإبعاد + +125 +00:11:47,770 --> 00:11:54,630 +لعدد كبير من المسلمين لتفريغ البلاد منهم أيضًا طرد + +126 +00:11:54,630 --> 00:11:58,330 +نصف مليون من المسلمين روهينجا من ديارهم وإبعادهم + +127 +00:11:58,330 --> 00:12:03,960 +إلى حدود بنجالدش مما أدى لوفات حوالي 40 ألف منهمو + +128 +00:12:03,960 --> 00:12:08,440 +كذلك طارد أكثر من نص مليون مسلم انتقاما منهم بسبب + +129 +00:12:08,440 --> 00:12:13,640 +تصويتهم لصالح المعارضة في الانتخابات النيابية + +130 +00:12:13,640 --> 00:12:17,760 +لأنهم يلا يريدون السلطات الحاكمة ويريدون استدالة + +131 +00:12:17,760 --> 00:12:24,440 +فلمّا لم يفوز أو لم تفوز المعارضة انتقم منهم أو + +132 +00:12:24,440 --> 00:12:31,320 +انتقمت منهم الحكومة الحالية بطارد أكثر من نص مليون + +133 +00:12:31,320 --> 00:12:37,170 +مسلمأيضا من أبرز مظاهر العنف في هذه الدولة قتل + +134 +00:12:37,170 --> 00:12:42,650 +الأطفال والنساء والشيوخ والاغتصاب الجماعي للنساء + +135 +00:12:42,650 --> 00:12:49,230 +هذا يعني هم مظاهر العنف الطائفي في مينمار + +136 +00:12:49,230 --> 00:12:55,610 +وماتعانيه الأقلية المسلمة في هذه الدولة التي تقضى + +137 +00:12:55,610 --> 00:13:01,150 +لجمهورية بورما الاتحاديةان شاء الله المحاضرة + +138 +00:13:01,150 --> 00:13:06,230 +القادمة سنكمل الحديث عن بقية الأقليات المسلمة + +139 +00:13:06,230 --> 00:13:12,130 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الخمسينيات يعني بعد الخمسينيات وذلك تحديدا بعد انتهاء الحرب الباردة بين الاتحاد السوفيتي والولايات المتحدة الأمريكية وكان ذلك عام 1961 طبعا الحرب الباردة يعني الكل كان بحشة قوة", "tokens": [6027, 12984, 7649, 1829, 24976, 4587, 2288, 1863, 18863, 46309, 9957, 25961, 18141, 6156, 15042, 6156, 30543, 34051, 6156, 30543, 33962, 2304, 3794, 9957, 1829, 9307, 37495, 22653, 39182, 33962, 2304, 3794, 9957, 1829, 9307, 4032, 8848, 23275, 6055, 5016, 16254, 28259, 39182, 16472, 47395, 16606, 21542, 25513, 29739, 9640, 41891, 49374, 2423, 9307, 5016, 18513, 21136, 38688, 1829, 31371, 16070, 12610, 47302, 9307, 9673, 2655, 24401, 3660, 16247, 2304, 16572, 4117, 10632, 4032, 41361, 29910, 23275, 6225, 10943, 41720, 23032, 3555, 3615, 995, 21542, 25513, 29739, 9640, 41891, 37495, 22653, 2423, 28820, 25961, 4724, 5016, 8592, 3660, 12174, 2407, 3660], "avg_logprob": -0.08226102795086655, "compression_ratio": 1.9702970297029703, "no_speech_prob": 0.0, "words": [{"start": 1118.07, "end": 1119.07, 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المسلمين لم يتركها بغير + +17 +00:01:29,720 --> 00:01:36,000 +نفوذ له بل جعل ورائه حكاما كانوا أشد منه على + +18 +00:01:36,000 --> 00:01:44,810 +الشعوب ظلما وقهرا وهذا أولئك الحكاموأنظمة الحكم في + +19 +00:01:44,810 --> 00:01:49,810 +ظل هؤلاء الحُكّام تعدت كثيرًا عن جوهر النظام + +20 +00:01:49,810 --> 00:01:56,670 +السياسي الإسلامي فهذه ثلاثة أمور حدثت في الواقع + +21 +00:01:56,670 --> 00:02:02,290 +السياسي للعالم الإسلاميوهي غيبة الخلافة الإسلامية + +22 +00:02:02,290 --> 00:02:08,270 +والبعد عن جوهر النظام السياسي الإسلامي والأمر + +23 +00:02:08,270 --> 00:02:13,250 +الثالث الاستعمار الجديد والحروب الصليبية الجديدة + +24 +00:02:13,250 --> 00:02:18,780 +وسنتحدث فقط عنأمرين من هذه الأمور الثلاثة الأمر + +25 +00:02:18,780 --> 00:02:22,920 +الأول والثاني غيبة الخلافة الإسلامية والبعد عن + +26 +00:02:22,920 --> 00:02:27,500 +جوهر النظام السياسي الإسلامي وأما الموضوع الثالث + +27 +00:02:27,500 --> 00:02:32,180 +فغير مقرر وهو الاستعمار الجديد والحروب الصليبية + +28 +00:02:33,410 --> 00:02:38,430 +نبدأ الحديث عن الأمر الأول من الأمور الثلاثة التي + +29 +00:02:38,430 --> 00:02:43,830 +حدثت في واقع العالم الإسلامي اللي هو غيبة الخلافة + +30 +00:02:43,830 --> 00:02:48,950 +الإسلامية وقبل الحديث عن غيبة الخلافة الإسلامية + +31 +00:02:48,950 --> 00:02:55,470 +وما تبعها من آثار على الواقع الإسلامي نتحدث عن + +32 +00:02:55,470 --> 00:03:00,570 +أهمية الخلافة أهمية الخلافة بالنسبة للمسلمينبعد + +33 +00:03:00,570 --> 00:03:05,190 +وفاة الرسول عليه الصلاة والسلام انشغل المسلمون + +34 +00:03:05,190 --> 00:03:12,010 +بتنصيب الخليفة والإمام قبل أن يدفنوا رسول الله صلى + +35 +00:03:12,010 --> 00:03:16,550 +الله عليه وسلم وهذا يدل على اهتمام المسلمين بهذا + +36 +00:03:16,550 --> 00:03:20,950 +الأمر حيث اجتمعوا في سقيفة بني ساعدة وأجمعوا على + +37 +00:03:20,950 --> 00:03:27,290 +اختيار أبي بكر خليفة للمسلمين ما هي الخلافة؟ما + +38 +00:03:27,290 --> 00:03:31,290 +المقصود بالخلافة الخلافة هناك تعريفات كثيرة لها من + +39 +00:03:31,290 --> 00:03:37,730 +هذه التعريفات أنها خلافة عن صاحب الشرع وهو النبي + +40 +00:03:37,730 --> 00:03:41,930 +صلى الله عليه وسلم خلافة عن صاحب الشرع في حراسة + +41 +00:03:41,930 --> 00:03:47,750 +الدين وسياسة الدنيا الخليفة دوره أن يحرص الدين + +42 +00:03:47,750 --> 00:03:53,560 +ويقود المسلمين في أمور الدنياوفي تعريف أخر للخلافة + +43 +00:03:53,560 --> 00:03:59,140 +بأنها الإمامة الموضوعة لخلافة النبوة في حراسة + +44 +00:03:59,140 --> 00:04:05,560 +الدين وسياسة الدنيا يعني معظم التعريفات تدور حول + +45 +00:04:05,560 --> 00:04:11,120 +هذين الأمرين حراسة الدين وسياسة الدنيا وقد بقيت + +46 +00:04:11,120 --> 00:04:15,820 +الخلافة الإسلامية تظل المسلمين أكثر من ألف عام وهي + +47 +00:04:15,820 --> 00:04:22,340 +تقيم حكم الله وشرع اللهوعندما آلت الخلافة إلى آل + +48 +00:04:22,340 --> 00:04:26,020 +عثمان وهم الأتراك حملوها أكثر من خمسمائة عام + +49 +00:04:26,020 --> 00:04:31,360 +وأرهبوا في تلك الحقبة التاريخية أرهبوا أعداء الله + +50 +00:04:31,360 --> 00:04:37,180 +في الشرق والغربوبالتالي تجمع على هذه الخلافة + +51 +00:04:37,180 --> 00:04:42,000 +وهؤلاء الخلفاء الأتراك تجمع عليها الأعداء وتأمروا + +52 +00:04:42,000 --> 00:04:52,380 +عليها وأصبح شغلهم الشاغل هو هذا هذه الخلافة وكيف + +53 +00:04:52,380 --> 00:04:56,560 +يقضون عليه أصبح يؤرقوا ماذا الأمر حتى سموا هذا + +54 +00:04:56,560 --> 00:05:02,600 +الأمر بالمسألة الشرقيةويقصدون بها الخلافة + +55 +00:05:02,600 --> 00:05:08,940 +العثمانية التركية وكيف يقضون عليها لأنه + +56 +00:05:08,940 --> 00:05:13,480 +عندما ضعفت قوة الدولة العثمانية طمع الأعداء فيها + +57 +00:05:13,480 --> 00:05:21,060 +فبقوا يبحثوا كيف يقضون عليها وينهونها فانتقلوا بعد + +58 +00:05:21,060 --> 00:05:25,700 +ذلك في بحث المسألة الشرقية إلى كيف يقضون على ما + +59 +00:05:25,700 --> 00:05:31,490 +أسموه الرجل المريضأطلقوا اسم الراجل المريض على آخر + +60 +00:05:31,490 --> 00:05:38,070 +عهد الخلافة العثمانية التركية عندما ضعفت ووهنت + +61 +00:05:38,070 --> 00:05:41,270 +وبعد + +62 +00:05:41,270 --> 00:05:46,510 +غياب الخلافة الإسلامية الأخيرة عن بلاد المسلمين + +63 +00:05:46,510 --> 00:05:50,390 +وعن العالم الإسلامي وعن الواقع السياسي + +64 +00:05:53,060 --> 00:06:01,980 +كان لها أثار كبيرة ومدمرة على حياة المسلمين وفي + +65 +00:06:01,980 --> 00:06:06,780 +واقعهم السياسي فبغياب الدولة الإسلامية غاب الحكم + +66 +00:06:06,780 --> 00:06:12,390 +بشرع الله تعالىوبغيابها غابت المظلة التي تضل + +67 +00:06:12,390 --> 00:06:17,890 +المسلمين وتجمعهم وتجمع شملهم في وحدة حقيقية قائمة + +68 +00:06:17,890 --> 00:06:23,210 +على وحدة العقيدة والدين والإيمان أيضا بغياب + +69 +00:06:23,210 --> 00:06:28,350 +الخلافة الإسلامية التركية غابت الدولة التي كانت + +70 +00:06:28,350 --> 00:06:33,530 +ترهب اليهود وأعداء الله في الشرق والغرب الذين + +71 +00:06:33,530 --> 00:06:39,530 +كانوا يحسبون لها الف حسابوأيضا بغيابها غابت الدولة + +72 +00:06:39,530 --> 00:06:44,790 +التي عرف اليهود أنه لا سبيل لهم إلى احتلال فلسطين + +73 +00:06:44,790 --> 00:06:51,090 +إلا بالقضاء عليها ولذلك ساهموا وساعدوا وشاركوا في + +74 +00:06:51,090 --> 00:06:58,790 +القضاء على هذه الخلافةماذا حدث بعد سقوط الخلافة؟ + +75 +00:06:58,790 --> 00:07:02,890 +بعد سقوطها أو إسقاطها أصح أن نقول إسقاطها لأنها لم + +76 +00:07:02,890 --> 00:07:06,810 +تسقط من ذاتها بل هم عملوا على إسقاطها الأعداء + +77 +00:07:06,810 --> 00:07:13,650 +تحالفوا على إسقاطها توزعت تركت الرجل المريض الذي + +78 +00:07:13,650 --> 00:07:19,800 +أطلقوا على الخلافة هذا الوصف الرجل المريضففي + +79 +00:07:19,800 --> 00:07:24,580 +العادة لما يموت الإنسان توزع تركته فشبهه بالرجل + +80 +00:07:24,580 --> 00:07:31,200 +المريض الذي مات وانتهى وبالتالي بدأ توزيع تركته + +81 +00:07:31,200 --> 00:07:34,900 +فوزعوا هذه التركة بين دول الاستعمار فرنسا + +82 +00:07:34,900 --> 00:07:39,380 +وبريطانيا وإيطاليا كما قلنا سابقا ليتم لهم بعد ذلك + +83 +00:07:39,380 --> 00:07:44,900 +التمهيد لقيام ما يسمى ويعرف بدولة إسرائيل + +84 +00:07:47,520 --> 00:07:53,580 +وحينما ارتأت الصهيونية والصليبية وهم حلف أصبحوا + +85 +00:07:53,580 --> 00:07:58,720 +حلفا واحدا صهيونية مع الصليبية لما ارتأوا ان ترحل + +86 +00:07:58,720 --> 00:08:03,500 +جنود الاحتلال الغربي الأجنبي أقاموا محلة .. محلة + +87 +00:08:04,040 --> 00:08:08,560 +هذه أو هذا الاحتلال أو هذا الاستعمار أقاموا من + +88 +00:08:08,560 --> 00:08:14,720 +يقوم بنفس الدور لكن بغير خسائر لهم من أرواح ودماء + +89 +00:08:14,720 --> 00:08:19,240 +وغرب عن الأوطان وبأداء أفضل من أداء الاحتلال + +90 +00:08:19,240 --> 00:08:20,080 +الأجنبي نفسه + +91 +00:08:24,380 --> 00:08:30,200 +ورغم غياب الخلافة الإسلامية عن العالم الإسلامي + +92 +00:08:30,200 --> 00:08:35,920 +فلازالت موجودة في العالم الإسلامي عناصر قوة وهي + +93 +00:08:35,920 --> 00:08:43,240 +عديدة فلبد من التركيز عليها والاهتمام بها رغم وجود + +94 +00:08:43,240 --> 00:08:49,180 +أيضًا عناصر ضعف يجب التغلب عليها فمن أهم عناصر + +95 +00:08:49,180 --> 00:08:57,060 +القوة التييمكن للمسلمين يستغلوها ويركزوا عليها + +96 +00:08:57,060 --> 00:09:05,020 +ويهتموا بها ويعيدوا من خلالها مجد الدولة والخلافة + +97 +00:09:05,020 --> 00:09:13,500 +مرة أخرى أهم هذه العناصر القوة هي قوة العقيدة قوة + +98 +00:09:13,500 --> 00:09:20,720 +الدين الإسلام بطبيعتهدين قوي ويدعو إلى القوة + +99 +00:09:20,720 --> 00:09:25,640 +والأخذ بالقوة والوحدة والتوحد فأهم عنصر من عناصر + +100 +00:09:25,640 --> 00:09:29,720 +القوة قوة العقيدة قوة الدين قوة الإسلام أيضا من + +101 +00:09:29,720 --> 00:09:33,300 +العناصر الكثرة العددية التي يتمتع بيها العالم + +102 +00:09:33,300 --> 00:09:38,300 +الإسلامي حوالي اتنين مليار مسلم اليوم عدد ليس + +103 +00:09:38,300 --> 00:09:41,870 +بقليلأيضًا من عناصر القوة الموقع الاستراتيجي + +104 +00:09:41,870 --> 00:09:47,470 +للعالم الإسلامي حيث يتمدد في ثلاث قارات ويطول على + +105 +00:09:47,470 --> 00:09:51,910 +أربع محيطات ويتحكم في سبع ممرات حيوية هذا الموقع + +106 +00:09:51,910 --> 00:09:56,070 +الاستراتيجي من عوامل قوة العالم الإسلامي أيضًا من + +107 +00:09:56,070 --> 00:10:00,390 +عوامل القوة الثروات الهائلة التي يتمتع بها العالم + +108 +00:10:00,390 --> 00:10:06,290 +الإسلامي من نفطه وغازه معادنه زراعه وغير ذلكومن + +109 +00:10:06,290 --> 00:10:10,830 +عوامل القوة أيضًا وعناصر القوة الحركات والجماعات + +110 +00:10:10,830 --> 00:10:16,370 +الإسلامية التي تغطي الساحات في العالم الإسلامي + +111 +00:10:16,370 --> 00:10:21,650 +أيضًا من عوامل القوة كذلك وعناصر القوة التراث + +112 +00:10:21,650 --> 00:10:26,950 +التاريخي الذي يشكل مادة فاعلة للتطلع للوحدة + +113 +00:10:26,950 --> 00:10:32,450 +الإسلامية في المستقبل لأن تراث تاريخي عظيمالقرآن + +114 +00:10:32,450 --> 00:10:39,950 +السنة التاريخي كل ذلك يجمع المسلمين ويوحدهم ومن + +115 +00:10:39,950 --> 00:10:45,370 +ذلك وحتة الثقافة ويشترك المسلمون في عناصر هذه + +116 +00:10:45,370 --> 00:10:50,570 +الثقافة كما قلنا من القرآن وسنة وأحكام ومعاملات + +117 +00:10:50,570 --> 00:10:54,950 +وأخلاق كل ذلك من التراث الإسلامي التاريخي الذي + +118 +00:10:54,950 --> 00:11:01,170 +يجمع بين المسلمين ويوحدهمأيضا من عناصر الوحدة + +119 +00:11:01,170 --> 00:11:05,950 +القوة بين المسلمين وعوامل القوة بينهم الروابط + +120 +00:11:05,950 --> 00:11:11,770 +المشتركة التي تجمع أفراد الأمة الإسلامية فنحن ننظر + +121 +00:11:11,770 --> 00:11:17,550 +إلى المسلمين على أنهم أمة واحدة مهما تعددت أجناسهم + +122 +00:11:17,550 --> 00:11:22,890 +وبيئاتهم ولغاتهم وألوانهم وأوطانهم إنما المؤمنون + +123 +00:11:22,890 --> 00:11:31,470 +أخو وإن هذه أمتكم أمة واحدةهذه عناصر القوة وفي + +124 +00:11:31,470 --> 00:11:37,790 +مقابلها هناك عناصر ضعف يعاني منها العالم الإسلامي + +125 +00:11:37,790 --> 00:11:44,590 +لابد من التخلص منها من أهم عناصر الضعف ضعف + +126 +00:11:44,590 --> 00:11:50,090 +الالتزام عموما للدين الإسلامي هناك متدينون وفي + +127 +00:11:50,090 --> 00:11:56,390 +المقابل هناك ناس غير ملتزمين بالدين كما يريد الله + +128 +00:11:56,390 --> 00:12:03,650 +ورسولهأيضًا من عوامل الضعف معاناة الأنظمة والنظم + +129 +00:12:03,650 --> 00:12:09,190 +الحاكمة من شتى صنوف الضعف الاقتصادي المالي السياسي + +130 +00:12:09,190 --> 00:12:16,830 +والتبعية للخارج فهم ليسوا أحرارًا في قراراتهم ومن + +131 +00:12:16,830 --> 00:12:20,290 +عوامل الضعف أيضًا وعناصر الضعف التخلف العلمي + +132 +00:12:20,290 --> 00:12:25,520 +والتكنولوجي إذا ما قارننا ذلك بالعالمالغربي و + +133 +00:12:25,520 --> 00:12:31,680 +الأوروبي و الأمريكا و أوروبا و اليابان و غيرها و + +134 +00:12:31,680 --> 00:12:34,700 +من هذه العوامل أيضا كثرت القلاقل و الفتن و + +135 +00:12:34,700 --> 00:12:42,960 +التحذبات و التجمعات و الطواقف هذا يضعف قوة + +136 +00:12:42,960 --> 00:12:48,520 +المسلمين ولا تنازعوا فتفشلوا و تذهب أريحكم أي + +137 +00:12:48,520 --> 00:12:54,130 +قوتكم التنازع والاختلافجماعات والتحذبات كل ذلك + +138 +00:12:54,130 --> 00:12:59,790 +يضعف المسلمين ومن ذلك أيضًا موجود بعض الأقليات + +139 +00:12:59,790 --> 00:13:03,690 +وهذه الأقليات في العادة كانت و لزالت تعمل كطابور + +140 +00:13:03,690 --> 00:13:11,190 +خامس يفتت صف المسلمين من الداخل ومن عوامل الضعف + +141 +00:13:11,190 --> 00:13:16,650 +أيضًا تقصير بعض التجمعات الإسلامية في أداء واجبها + +142 +00:13:16,650 --> 00:13:23,440 +الدعوي وحتى العلماءهناك تقصير واضح في أداء واجب + +143 +00:13:23,440 --> 00:13:31,080 +الدعوة وتوضيح الإسلام للناس من عواناصر وعوامل + +144 +00:13:31,080 --> 00:13:40,360 +الضعف أيضا فقدان الوحدة بين أقطار المسلمين فالعالم + +145 +00:13:40,360 --> 00:13:47,240 +الإسلامي اليوم موزعوبين أفكار شتى اشتراكية + +146 +00:13:47,240 --> 00:13:55,480 +ورقصمالية وديمقراطية ووطنية وقومية كل ذلك يفتت + +147 +00:13:55,480 --> 00:14:01,860 +ويضعف من قوة المسلمينأيضًا من العوامل الضعف الجهل + +148 +00:14:01,860 --> 00:14:07,320 +بالإسلام وعقائد الإسلام وأحكام الإسلام وفي مقابل + +149 +00:14:07,320 --> 00:14:11,660 +ذلك انتشار البدع والخرافات والمذاهب الهدامة كل ذلك + +150 +00:14:11,660 --> 00:14:17,510 +يضعف من قوة المسلمينومن العوامل أيضًا الهزيمة + +151 +00:14:17,510 --> 00:14:26,430 +النفسية لدى بعض المسلمين الذين شهدوا الاستعمار + +152 +00:14:26,430 --> 00:14:33,490 +والاحتلال وبعد إجلاء الاحتلال أو الاستعمار يصبح + +153 +00:14:33,490 --> 00:14:38,190 +هؤلاء يقارنوا بين ما كانوا عليه في ظل الاحتلال أو + +154 +00:14:38,190 --> 00:14:42,500 +الاستعمار وبين ما هم عليه اليوم في ظل الحكاموبعضهم + +155 +00:14:42,500 --> 00:14:47,080 +يتمنى لو بقى الاحتلال وبقى الاستعمار وهذه الهزيمة + +156 +00:14:47,080 --> 00:14:52,660 +النفسية المقصودة بها أيضًا من عوامل الضعف إبعاد + +157 +00:14:52,660 --> 00:14:57,240 +الإسلام عن المعركة كما قلنا في تمزق العالم + +158 +00:14:57,240 --> 00:15:02,840 +الإسلامي بين التكتلات والأحلافهناك رايات كثيرة + +159 +00:15:02,840 --> 00:15:10,000 +رفعت في معارك المسلمين غير الراية الإسلامية كما + +160 +00:15:10,000 --> 00:15:14,120 +قلنا الاشتراكية والرأسمالية والديمقراطية والقومية + +161 +00:15:14,120 --> 00:15:19,700 +والوطنية وأما الإسلام فكان بعيدا عن تلك المعارك + +162 +00:15:19,700 --> 00:15:24,160 +فهذا كان من عناصر الضعف للعالم الإسلامي + +163 +00:15:28,190 --> 00:15:34,460 +يبقى في عوامل قوة في عوامل ضعفيمكن من خلال عوامل + +164 +00:15:34,460 --> 00:15:41,180 +القوة نستنتج عوامل وحدة العالم الإسلامي كيف يعود + +165 +00:15:41,180 --> 00:15:46,340 +العالم الإسلامي موحدا ما هي عوامل وحدة العالم + +166 +00:15:46,340 --> 00:15:52,100 +الإسلامي هناك عوامل كثيرة يمكن أن يتوحد عليها + +167 +00:15:52,100 --> 00:15:57,900 +العالم الإسلامي ويصبح كتلة واحدة موحدة على رأس هذه + +168 +00:15:57,900 --> 00:16:04,430 +العوامل اللي هو العامل الأقوى دائماالعقدي الروابط + +169 +00:16:04,430 --> 00:16:10,370 +الإيمانية التي تجمع بين كل المسلمين من الشرق إلى + +170 +00:16:10,370 --> 00:16:16,130 +الغرب فالمسلم أخ المسلم بغض النظر عن الجنسية + +171 +00:16:16,130 --> 00:16:22,070 +والموطن واللغة المسلم أخ المسلم وليس العربي فقط أخ + +172 +00:16:22,070 --> 00:16:27,180 +العربي أو التركي أخ التركيفلسطين أخ الفلسطيني أو + +173 +00:16:27,180 --> 00:16:31,520 +المصري أخ المصري، كل من هو مسلم هو أخ للمسلم، إنما + +174 +00:16:31,520 --> 00:16:36,620 +المؤمنون أخوة، هذا أكبر عامل، وأكبر جامع، وأكبر + +175 +00:16:36,620 --> 00:16:42,460 +رابط يمكن أن يوحد المسلمين الرابط والعامل العقدي، + +176 +00:16:42,460 --> 00:16:47,200 +أيضًا من عوامل وحدة العالم الإسلامي، وحدة التشريع، + +177 +00:16:47,200 --> 00:16:55,600 +الله تعالى شرعلنا شرائع وتشريعات وأحكامكفيلة بأن + +178 +00:16:55,600 --> 00:17:01,560 +تجمعنا وتوحدنا وهي تشمل الفرائض والأوامر والنواهي + +179 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تاريخ مشترك وتوراث اشتركت فيه + +191 +00:18:03,530 --> 00:18:09,450 +كل القوميات الموجودة في العالم الإسلامي أيضًا منطق + +192 +00:18:09,450 --> 00:18:17,070 +العصريفرض على العالم الإسلامي أن يتوحد فالآن منطق + +193 +00:18:17,070 --> 00:18:22,290 +العصر هو الوحدة والتوحد كل دول العالم اليوم أو + +194 +00:18:22,290 --> 00:18:27,050 +معظم وأكثر دول العالم اليوم موحدة فيما بينها قديما + +195 +00:18:27,050 --> 00:18:32,610 +كان الاتحاد السوفيتي اليوم الولايات المتحدة + +196 +00:18:32,610 --> 00:18:40,080 +الأمريكية الاتحاد الأوروبيالأمم المتحدة كل هؤلاء + +197 +00:18:40,080 --> 00:18:44,820 +موحدون إلا العالم الإسلامي فمنطق العصر يفرض على + +198 +00:18:44,820 --> 00:18:51,340 +العالم الإسلامي اليوم أن يتوحد الله تعالى يدعونا + +199 +00:18:51,340 --> 00:18:58,280 +ويأمرنا ويحثنا على أن نتوحد وننظر إلى أعدائنا كيف + +200 +00:18:58,280 --> 00:19:05,430 +هم موحدون فلنكن مثلهمقال الله تعالى والذين كفروا + +201 +00:19:05,430 --> 00:19:10,710 +بعضهم أولياء بعض الكفار اليوم بيوالوا بعض قديما + 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+الثانيةاللي كانت معروضة عليهم .. فضل اللي بدنا + +68 +00:06:29,650 --> 00:06:32,470 +وجوه جديدة نوّه شوية .. فضل .. تنصير المغول + +69 +00:06:32,470 --> 00:06:35,950 +لتنييما استخدامه من جديد في قلوب مدامن التطالب + +70 +00:06:35,950 --> 00:06:39,130 +المسلمين وكان أيضا معروض عليه .. برك الله فيك .. + +71 +00:06:39,130 --> 00:06:44,110 +خطة أخرى أن يقوموا بتنصير المغول .. التطار يعني + +72 +00:06:44,110 --> 00:06:49,930 +جعلهم نصارى يدخلون في الدين النصراني المسيحي + +73 +00:06:49,930 --> 00:06:54,190 +المزعوم طبعا المحرف في ذلك الوقت فكانوا يطمعون في + +74 +00:06:54,190 --> 00:06:59,140 +..تنصير هؤلاء المغول حتى يكسبوهم إلى جانبهم لأنهم + +75 +00:06:59,140 --> 00:07:04,560 +كانوا قوة في ذلك الوقت عددا و عدة و عتاد و كانوا + +76 +00:07:04,560 --> 00:07:09,760 +متوحشين المغول و التطارف فقالوا لابد من أن نكسبهم + +77 +00:07:09,760 --> 00:07:15,140 +إلى جانبنا و نعتمد عليهم في حربنا القادمة ضد + +78 +00:07:15,140 --> 00:07:20,860 +المسلمين طيب أي الخطتين أو إلى أي الخطتين كان يميل + +79 +00:07:20,860 --> 00:07:22,140 +هذا البابا + +80 +00:07:25,950 --> 00:07:28,990 +ما هي الطريقة الثانية التي اعتمدها؟ اللي هي طريقة + +81 +00:07:28,990 --> 00:07:33,510 +اعتمد على الطريقة الثانية المعروضة عليه وهي تنصير + +82 +00:07:33,510 --> 00:07:39,530 +المغول جرب الطريقة الأولى وحاول ان يعني يسعى الى + +83 +00:07:39,530 --> 00:07:45,210 +تنصير المغول لكن الله سبحانه وتعالى أراد بالمغول + +84 +00:07:45,210 --> 00:07:51,830 +التتار خيرا فقد دخلوا او دخل كثير منهم في الإسلام + +85 +00:07:51,830 --> 00:07:57,120 +قيل انه أسلوب قائد كبير لهمفتابعوه في الإسلام + +86 +00:07:57,120 --> 00:08:03,540 +ودخلوا في الإسلام فأفشل الله سبحانه وتعالى كيدة + +87 +00:08:03,540 --> 00:08:08,680 +الصليبيين وخطتهم في ذلك بعد فشل هذه الخطة عاود + +88 +00:08:08,680 --> 00:08:14,180 +البابا سلسلتين الخامس الأخذ بخطة رامون لول التي + +89 +00:08:14,180 --> 00:08:21,100 +تقوم على فكرة تبشير المسلمينفكريا وغزوهم فكريا + +90 +00:08:21,100 --> 00:08:26,320 +وتبشيرهم بهذا الدين وإخراجهم عن دينهم وتشكيكهم في + +91 +00:08:26,320 --> 00:08:32,540 +دينهم وهذا يحتاج إلى برنامج عمل كامل ومتكامل يقوم + +92 +00:08:32,540 --> 00:08:38,840 +على دراسةوفهم مضامين الفكر الإسلامي ومعرفة مواضع + +93 +00:08:38,840 --> 00:08:43,480 +القوة والضعف أين مواضع القوة فنعمل على إضعافها أين + +94 +00:08:43,480 --> 00:08:49,840 +مواضع الضعف فيهم فندخل من خلالها كمرحلة أولى ثم + +95 +00:08:49,840 --> 00:08:54,260 +محاولة نقض هذا الفكر بالتشكيك فيه والافتراض عليه + +96 +00:08:55,340 --> 00:09:00,500 +وبالتالي ضرب إرادة المقاومة عند المسلمين التي + +97 +00:09:00,500 --> 00:09:06,220 +تتمثل في دينهم وعقيدتهم هذه الإرادة الصلبة + +98 +00:09:06,220 --> 00:09:10,020 +الموجودة عند المسلمين يستمدها المسلمون من دينهم من + +99 +00:09:10,020 --> 00:09:16,000 +عقيدتهم إذا لابد من التشكيك في هذه العقيدة وفي هذا + +100 +00:09:16,000 --> 00:09:22,100 +الدين ومن هنا بدأتمواجهة جديدة ومرحلة جديدة بين + +101 +00:09:22,100 --> 00:09:25,740 +الصليبيين الحاقدين على الإسلام والمسلمين وبين + +102 +00:09:25,740 --> 00:09:30,660 +المسلمين فبعد أن كانت الحروب الصليبية العسكرية + +103 +00:09:30,660 --> 00:09:35,600 +والمواجهة العسكرية الآن اعتمدوا الخطة الثانية اللي + +104 +00:09:35,600 --> 00:09:39,880 +هي الأولى حسب الذكر وهي خطة تبشير المسلمين أو + +105 +00:09:39,880 --> 00:09:41,340 +غزوهم فكريا + +106 +00:09:43,770 --> 00:09:48,110 +نرجع للسؤال الذي سألناه في بداية محاضرتنا هل + +107 +00:09:48,110 --> 00:09:53,590 +الحروب والصليبية انتهت بعد هزيمة الصليبيين على يد + +108 +00:09:53,590 --> 00:09:57,330 +القائد البطل صلاح الدين بعد أنهي تلك الهزيمة عبر + +109 +00:09:57,330 --> 00:10:03,810 +حروب كثيرة وجهاد طويل خضوا المسلمون ام لم تنتهي + +110 +00:10:03,810 --> 00:10:07,770 +بعد الجواب بكلمة يعني انتهت او لم تنتهي بكلمة بدا + +111 +00:10:07,770 --> 00:10:15,900 +لم تنتهي بعد بدليل الواقعفي القرن التاسع عشر عادت + +112 +00:10:15,900 --> 00:10:22,360 +أوروبا من جديد للحروب الصليبية في شكل آخر في شكل + +113 +00:10:22,360 --> 00:10:30,740 +احتلالات عسكرية واستعمار للبلاد الإسلامية فلم تسلم + +114 +00:10:30,740 --> 00:10:38,680 +تقريبا اي بلد او دولة اسلامية او عربية من احتلالهم + +115 +00:10:39,760 --> 00:10:44,880 +فقد احتلت فرنسا كما هو معروف عبر التاريخ احتلت مصر + +116 +00:10:44,880 --> 00:10:50,520 +ثم تلاها في الاحتلال لمصر بريطانيا و فرنسا ايضا + +117 +00:10:50,520 --> 00:10:54,520 +احتلت من بلاد المسلمين الجزائر و تونس و مراكش + +118 +00:10:54,520 --> 00:10:59,750 +واحتلت بلاد الشام و منها سورياثم عودت احتلالها + +119 +00:10:59,750 --> 00:11:05,690 +لمصر كما قلنا وبعدها جاء الانجليز و بريطانيا + +120 +00:11:05,690 --> 00:11:09,050 +واحتلت مصر واحتلت الهند كذلك و ليبيا احتلها + +121 +00:11:09,050 --> 00:11:15,230 +الايطاليونو في أثناء هذا الاحتلال و هذا الاستعمار + +122 +00:11:15,230 --> 00:11:20,130 +و وجود الصليبيين النصارى في بلاد المسلمين ايضا لم + +123 +00:11:20,130 --> 00:11:24,770 +يكتفوا بهذا الاحتلال العسكري و الغزو العسكري صاحبة + +124 +00:11:24,770 --> 00:11:31,210 +هذا الغزو العسكري اللي لهم ايضا غزو فكري بإثارة + +125 +00:11:31,210 --> 00:11:37,130 +القوميات و النعرات القومية بين المسلمين فهذا من + +126 +00:11:37,130 --> 00:11:43,990 +أصول طورانية و هم الأتراكحاولوا أن يغذوا هذا الفكر + +127 +00:11:43,990 --> 00:11:49,150 +القومي في الأطراق و الرجوع إلى ما قبل الإسلام و + +128 +00:11:49,150 --> 00:11:52,790 +كذلك في العرب حاولوا أن يثيروا المعرق القومية + +129 +00:11:52,790 --> 00:11:58,090 +العربية و أيضا دعوا إلى العلمانية التي تعني فصل + +130 +00:11:58,090 --> 00:12:03,870 +الدين عن الدولةوتبنى ذلك فيما بعد وكان من أوائل + +131 +00:12:03,870 --> 00:12:07,250 +الدول الإسلامية التي تبنت العلمانية وهذا الفصل + +132 +00:12:07,250 --> 00:12:11,810 +وكانت ايضا مبادرة في الدعوة الى القومية تركيا التي + +133 +00:12:11,810 --> 00:12:16,530 +كان يحكمها في ذلك الوقت حزب الاتحاد والتراقي والان + +134 +00:12:16,530 --> 00:12:21,510 +اختلفت تركيا فما عادت تركيا هي تركيا يعني السابق + +135 +00:12:23,800 --> 00:12:29,940 +وأخيرا وفي العصر الحديث ربما كلنا شاهدنا هذا الحدث + +136 +00:12:29,940 --> 00:12:34,420 +عادت الحروب الصليبية العسكرية مرة أخرى ولكن هذه + +137 +00:12:34,420 --> 00:12:39,960 +المرة بقيادة الوليات المتحدة الأمريكية التي تتزعم + +138 +00:12:39,960 --> 00:12:45,580 +اليوم الصليبية الحاقدة على الإسلام والمسلمين وتصف + +139 +00:12:45,580 --> 00:12:51,870 +نفسها بأنها سيدةالكون وسيدة العالم وده هنتحدث عنه + +140 +00:12:51,870 --> 00:12:57,310 +بالتفصيل في العالم حينما صناعتي عليه فاحتلت العراق + +141 +00:12:57,310 --> 00:13:03,750 +احتلت أفغانستان والكلام شاهدناه وعايشناه وسنأخذ + +142 +00:13:03,750 --> 00:13:09,770 +مثال فقط من هذه الاحتلالات وهو احتلال امريكا او + +143 +00:13:09,770 --> 00:13:13,230 +الولايات المتحدة الأمريكية للعراق والأهداف من ورا + +144 +00:13:13,230 --> 00:13:19,920 +هذا الاحتلالو سنكتفي تخفيفا عنكم بالعناوين فقط مش + +145 +00:13:19,920 --> 00:13:24,660 +هنكلفكم بالتفاصيل هناخد الأهداف الحقيقية من الحرب + +146 +00:13:24,660 --> 00:13:28,560 +على العراق هنكتفي بذكر الأهداف ذكرا لأن في تفاصيل + +147 +00:13:28,560 --> 00:13:33,320 +كثيرة ترجعون اليها للفائدة والاطلاع ففيها معلومات + +148 +00:13:33,320 --> 00:13:39,180 +قيمة وزخمة 100 من الأخوات تذكر لنا من هذه الأهداف + +149 +00:13:39,180 --> 00:13:46,060 +أهداف الحرب على العراقتأكيد التواجد العسكري + +150 +00:13:46,060 --> 00:13:50,060 +للولايات المتحدة في المنطقة العربية اول حاجة اول + +151 +00:13:50,060 --> 00:13:56,980 +شي تولد امريكا ان تؤكد دورها ونفوذها في المنطقة + +152 +00:13:56,980 --> 00:14:01,820 +العربية ولذلك جاءت واحتلت هذا الجزء الكبير العزيزي + +153 +00:14:01,820 --> 00:14:06,740 +الغالي من بلاد المسلمين وهو العراق حولت الصهاينة + +154 +00:14:06,740 --> 00:14:10,720 +المسيحيين التنصيب في اوساط الشعب العراق المسلمأيضا + +155 +00:14:10,720 --> 00:14:15,520 +هناك هدف وهو تنصير وتبشير في دائما وأبدا هؤلاء + +156 +00:14:15,520 --> 00:14:21,620 +يعني لا ينسون دينهم الذي ينتسبون إليه وهو محرف + +157 +00:14:21,620 --> 00:14:27,400 +فيسعون إلى نشره وإلى التبشير به فكان هناك محاولة + +158 +00:14:28,130 --> 00:14:33,110 +ربما كانت يائسة لكنها كانت محاولة من يعني ما يُعرف + +159 +00:14:33,110 --> 00:14:39,370 +بالصهاينة المسيحيين يعني المسيحيين والنصارى الذين + +160 +00:14:39,370 --> 00:14:45,510 +يؤمنون بفكرة الصهيونين يعني أن يكون لليهود دولة في + +161 +00:14:45,510 --> 00:14:51,620 +فلسطين على أرض فلسطين مع أنهم ليسوا يهودا لكنهممثل + +162 +00:14:51,620 --> 00:14:55,120 +اليهود في هذا الفكر و يؤيدون و يدعمون اليهود + +163 +00:14:55,120 --> 00:15:00,240 +فحاولت هذه الجهات عبر المقابرات الأمريكية + +164 +00:15:00,240 --> 00:15:07,000 +والصهيونية واليهودية ان يعني يقوموا بمحاولة + +165 +00:15:07,000 --> 00:15:10,520 +التنصير في أوساط هذا الشعب المستمر تلاتة .. فضل + +166 +00:15:10,520 --> 00:15:13,700 +الأخت اللي ورا علينا الصوت شوية + +167 +00:15:17,560 --> 00:15:23,000 +كل ما يمكن اسمعناه بمصطلح الفوضى الخلاقة التي يعني + +168 +00:15:23,000 --> 00:15:27,160 +أصبحت مصطلحة شعنة على ألثنات الساسة الأمريكيين + +169 +00:15:27,160 --> 00:15:31,580 +وصرحة بها أكثر من مرة في أكثر من مجال يريدوا أن + +170 +00:15:31,580 --> 00:15:35,500 +يثيروا الفوضى في العالم الإسلامي بإشغال العالم + +171 +00:15:35,500 --> 00:15:41,690 +الإسلامي بعضه وبعض بإشغال الفرق والمذاهبالاسلامية + +172 +00:15:41,690 --> 00:15:46,070 +حتى يقاتلوا بعض و بعضا و يغذوا هذه على حساب تلج و + +173 +00:15:46,070 --> 00:15:50,790 +يسعون في الأرض فسادا كلما أوقضوا نارا للحرب + +174 +00:15:50,790 --> 00:15:55,710 +أطفاءها الله و يسعون في الأرض فسادا هؤلاء يعني من + +175 +00:15:55,710 --> 00:15:59,350 +ورائهم اليهودية العالمية والصهيونية العالمية بل + +176 +00:15:59,350 --> 00:16:00,730 +والماسونية + +177 +00:16:02,600 --> 00:16:06,980 +تسيطر على العالم اليوم تبسط نفوذا ومن وراء الجميع + +178 +00:16:06,980 --> 00:16:12,880 +اليهود يد اليهود في كل حرب من هذه الحروب الكبيرة + +179 +00:16:12,880 --> 00:16:18,240 +وصدق الله تعالى كما قلنا في الآية السابقةكلما + +180 +00:16:18,240 --> 00:16:24,160 +أوقدوا نارا للحرب أطفعها الله ويسعون في الأرض + +181 +00:16:24,160 --> 00:16:28,760 +فسادة هذا من صفات اليهود اللي القرآن الكريم ذكرها + +182 +00:16:28,760 --> 00:16:34,100 +عنهم وتكلم بها عنهم أيضا من أهدافهم التأكيد + +183 +00:16:34,100 --> 00:16:37,680 +استمرار حملتها على ما تزعن بأنها محاربة للإنهاب + +184 +00:16:37,680 --> 00:16:41,070 +والتأكيد سيطرتها وصبتها على ما يعرفبرك الله فيك، + +185 +00:16:41,070 --> 00:16:46,570 +هي جاءت بهذا المبرر وبهذا السبب، وهو الإرهاب + +186 +00:16:46,570 --> 00:16:51,210 +والقضاء على الإرهاب والتنظيمات الإرهابية الموجودة + +187 +00:16:51,210 --> 00:16:54,850 +في العراق والتي أدعمها العراق حتى تحشد الجيوش التي + +188 +00:16:54,850 --> 00:17:00,290 +حشدتها في حربها خاصة الأولى ضد العراقفحشدت هذه + +189 +00:17:00,290 --> 00:17:06,990 +الجوش من جميع الدول تحت يعني ذريعة ومبرر وحجة + +190 +00:17:06,990 --> 00:17:12,910 +الإرهاب والأسلحة الكيموية وكذا وكذا ولم يكن شيء من + +191 +00:17:12,910 --> 00:17:17,390 +ذلك في تلك الدولة + +192 +00:17:17,390 --> 00:17:23,290 +فضل خمسة استنزف الموارد التانية العربية وهذا ما + +193 +00:17:23,290 --> 00:17:29,020 +حدث استنزفوا الموارد الاقتصادية والثروات والبترولو + +194 +00:17:29,020 --> 00:17:34,140 +قالوا للعرب و خاصة دول الخليج و غيرهم بان احنا + +195 +00:17:34,140 --> 00:17:41,240 +ندافع عنكم ضد هذا الذي يريد ان يتمدد في سلطته صدام + +196 +00:17:41,240 --> 00:17:45,720 +حسين في ذلك الوقت فلبوط ان تدعمونا يعني حرصا عليكم + +197 +00:17:45,720 --> 00:17:50,220 +و مصلحة لكم فامدونا بالمال فامدوهم بالمال و + +198 +00:17:50,220 --> 00:17:55,770 +البترول و ربما الى اليوموهم يعانون من تزييد الديون + +199 +00:17:55,770 --> 00:18:01,330 +لمستحقات الأمريكية اللي نابت عنهم في هذه الحرب + +200 +00:18:01,330 --> 00:18:07,710 +أيضا من هذه الأهداف اجراء تغييرات جوارية في البناء + +201 +00:18:07,710 --> 00:18:10,840 +الثقافي العلمي والسياسي والاجتماعي والتعليميا + +202 +00:18:10,840 --> 00:18:14,260 +أخوات هذا الكلام بارك الله فيك من أخطر الأهداف + +203 +00:18:14,260 --> 00:18:17,640 +التي لا ينتبه لها الكثير أو لا يعيرها اهتماما او + +204 +00:18:17,640 --> 00:18:21,400 +انتباه هو الغزو الفكر الذي نريد ان نتحدث عنه و + +205 +00:18:21,400 --> 00:18:27,430 +نركز عليه في حديثنا القاتل ربما ياخدمعظم الوقت + +206 +00:18:27,430 --> 00:18:32,410 +منهم بدهم يحدثوا تغييرات جوهرية في البناء الثقافي + +207 +00:18:32,410 --> 00:18:37,570 +يعملوا غزو ثقافي ثقافتهم الغربية كلها يطبعون فيه + +208 +00:18:37,570 --> 00:18:42,810 +ويجعلون .. ويجعلوننا أمثالهم على نفس النمط الذي + +209 +00:18:42,810 --> 00:18:47,890 +يسيرون علينا ترد ديننا وعقيدتنا وقيمنا وسلوكنا + +210 +00:18:47,890 --> 00:18:53,750 +وأخلاقنالنرتمي في أحضانهم و نأخذ عنهم و يكونون + +211 +00:18:53,750 --> 00:18:59,070 +النموذج و المثال لنا هذا ما يسعى اليه .. تسعى اليه + +212 +00:18:59,070 --> 00:19:04,590 +أمريكا اليوم و أوروبا معها و اليهود من ورا الجميع + +213 +00:19:04,590 --> 00:19:08,270 +و هذا ما بدأوا فيه بالفعل في كثير من البلدان + +214 +00:19:08,270 --> 00:19:12,010 +أصبحوا يتدخلون في المناهج و في التعليم و في + +215 +00:19:12,010 --> 00:19:20,340 +الثقافةويراقبون المناهج ويعدلون وينتقدون هذا سائق + +216 +00:19:20,340 --> 00:19:24,340 +وهذا ليس سائق هذا جائز وهذا غير جائز هذا مقبول هذا + +217 +00:19:24,340 --> 00:19:30,440 +غير مقبول شيلوا كذا وحطوا كذا في بعض الدول وبشهادة + +218 +00:19:30,440 --> 00:19:35,960 +يعني اناس صادقين وثقاء كانوا في تلك البلدان وقالوا + +219 +00:19:35,960 --> 00:19:41,140 +لنا انهم يعني بوفود يتحكمون بكل هذه الأمور التي + +220 +00:19:41,140 --> 00:19:48,300 +ذكرناهاقادم الأخطر الأهداف التي يريدونها بعد هذا + +221 +00:19:48,300 --> 00:19:56,360 +السرد لمكان عليه الحال سواء في أثناء الحروب + +222 +00:19:56,360 --> 00:20:00,020 +الصليبية أو الغزو التتاري والمغولي واليوم عادت + +223 +00:20:00,020 --> 00:20:04,900 +أمريكا من جديد وكذا نرجع مرة أخرى إلى الخطة التي + +224 +00:20:04,900 --> 00:20:11,100 +بدأنا الحديث عنهاوهي الخطة الجديدة للصليبيين لغزو + +225 +00:20:11,100 --> 00:20:15,040 +العالم الإسلام بعد فشل الخطة العسكرية والحروب + +226 +00:20:15,040 --> 00:20:21,580 +العسكرية المادية لجأوا كما قلنا إلى خطة الغزو + +227 +00:20:21,580 --> 00:20:26,740 +الفكري للعالم الإسلام فوجدوا أنه أفضل طريقة وأقرب + +228 +00:20:26,740 --> 00:20:33,200 +طريقةهي هذه الطريقة صلوك الغزو الفكر وصاروا على + +229 +00:20:33,200 --> 00:20:41,080 +قاعدة إذا أرهبك عدوك فافسد فكره ينتحر به ومن ثم + +230 +00:20:41,080 --> 00:20:46,600 +تستعبده فانت تستعبد هذا الذي تفسد عليه فكرة فبما + +231 +00:20:46,600 --> 00:20:54,260 +يقاومك وبما يواجهكسيكونوا ضعيفا وذليلا وستتحكم بيه + +232 +00:20:54,260 --> 00:20:59,580 +بكل سهولة فانتقلت المعركة من ساحة الحرب إلى ميدان + +233 +00:20:59,580 --> 00:21:05,120 +الفكر والثقافة ما المقصود بالغزو الفكري ذلك + +234 +00:21:05,120 --> 00:21:11,520 +المصطلح الذي رددناه أكثر من مرة وذكرناه وتكلمناه + +235 +00:21:11,520 --> 00:21:15,240 +فضل هذا التعريف تبع المعتمد الذي نريد أن نعتمد ما + +236 +00:21:15,240 --> 00:21:19,250 +المراد بالغزو الفكر اتفضلهو تغيير أحوال المسلمين + +237 +00:21:19,250 --> 00:21:23,170 +السياسية والثقافية والاجتماعية والاقتصادية عن طريق + +238 +00:21:23,170 --> 00:21:27,350 +استعمار القلوب والعقول وتبديل الأفكار والقيم + +239 +00:21:27,350 --> 00:21:31,390 +والعقائد فيصبح المجموعة الفكرية خاضة عن مشكلتها من + +240 +00:21:31,390 --> 00:21:35,380 +قادة القدورشايفين هذا الكلام؟ تغيير جذري يعني و + +241 +00:21:35,380 --> 00:21:40,920 +كله و شامل تغيير لأحوال المسلمين السياسية + +242 +00:21:40,920 --> 00:21:46,760 +والثقافية والاجتماعية والاقتصادية كيف يحدثون هذا + +243 +00:21:46,760 --> 00:21:52,720 +التغيير عبر هذا الغزو الذي يغزو العقول والقلوب + +244 +00:21:52,720 --> 00:22:00,430 +فيحتله فيعجب هذا المغزو بمن يغزوه يعجبعبر هذه + +245 +00:22:00,430 --> 00:22:04,630 +الثقافات والقيم الإجتماعية والاقتصاد القوي + +246 +00:22:04,630 --> 00:22:09,530 +والسياسة الحكيمة هكذا يصفون أنفسهم ويسويقون أنفسهم + +247 +00:22:09,530 --> 00:22:14,290 +في العالم الإسلامي وللأسف الشديد نجد كثير من + +248 +00:22:14,290 --> 00:22:17,330 +العالم الإسلامي وابناء العالم الإسلامي منصفق + +249 +00:22:17,330 --> 00:22:24,810 +لهؤلاء وتقبل هؤلاء وقبل هؤلاءو سوّغ لهم و سوق لهم + +250 +00:22:24,810 --> 00:22:34,270 +و حمل أفكارهم و دافع عنها ولا يزالون ولا يزالوا هم + +251 +00:22:34,270 --> 00:22:38,130 +ولا يزالون وهؤلاء ولا يزالون كما قال القرآن ولا + +252 +00:22:38,130 --> 00:22:43,770 +يزالون يقاتلونكم عن اليهود والنصارى والكفاء ولا + +253 +00:22:43,770 --> 00:22:49,170 +يزالون يقاتلونكم حتى يردوكم عن دينكم إن استطاع + +254 +00:22:49,740 --> 00:22:54,100 +لأنهم يعلمون أن قوة المسلمين في عقيدة كذلك هؤلاء + +255 +00:22:54,100 --> 00:22:59,040 +أتباعهم اليوم وفي ثوب جديد ويرتدون ثياب الوطني + +256 +00:22:59,040 --> 00:23:04,100 +وادفاع عن الوطن بهذه الحجة و القومية وكذا و + +257 +00:23:04,100 --> 00:23:09,240 +العلمانية قديما والليبرالية حديثا يزعمون ذلك وما + +258 +00:23:09,240 --> 00:23:15,050 +نراهم في شاشات التلفاز وعلى الفضايات المختلفةكلهم + +259 +00:23:15,050 --> 00:23:21,110 +هدفهم إقصاء وإبعاد المسلمين عن دينهم واستبدال هذه + +260 +00:23:21,110 --> 00:23:25,170 +العقيدة والدين بتلك الأفكار الغربية هذا هو الغزو + +261 +00:23:25,170 --> 00:23:31,210 +الفكري بعينه قضية تغيير ثقافي فكري جذري فإذا ما + +262 +00:23:31,210 --> 00:23:37,370 +تغير هذا الفكروهذه الثقافة التي تنبع من عقيدة + +263 +00:23:37,370 --> 00:23:44,210 +الإسلام سهولة السيطرة على المسلمين والتحكم فيهم + +264 +00:23:44,210 --> 00:23:48,700 +وأصبحنا جزءا منهم لا يتجزأكثير من الناس لا يستغنى + +265 +00:23:48,700 --> 00:23:53,120 +أصبح اليوم عن أمريكا وعن أوروبا و .. و .. و .. + +266 +00:23:53,120 --> 00:23:57,280 +ودعا إلى ذلك يعني صراحة كما سنرا عند الحديث عن + +267 +00:23:57,280 --> 00:24:02,580 +الاستشراك والتغريب بالتفصيل فهذه من مخاطر هذا + +268 +00:24:02,580 --> 00:24:07,940 +الغزو الفكريإنه يستهدف القلوب والعقول وتفكير + +269 +00:24:07,940 --> 00:24:12,100 +وتبديل الأفكار والقيم والعقائد فيصبح هذا المغزو + +270 +00:24:12,100 --> 00:24:17,280 +فكريا قاضعا لهم وكما قال أحد المفكرين المسلمين + +271 +00:24:17,280 --> 00:24:23,080 +الكبار مالك بن نبي يصبح عند أهل تلك البلاد المغزوة + +272 +00:24:23,080 --> 00:24:29,360 +القابلية للاستعمار بسبب أنهم قابلينمدام هو بيحمل + +273 +00:24:29,360 --> 00:24:33,520 +أفكاره و اتطبع بأفكار و قابل أفكاره بصير يتقبل + +274 +00:24:33,520 --> 00:24:39,940 +احتلاله و استعماره و بقائه في دياره بصير عنده + +275 +00:24:39,940 --> 00:24:42,060 +قابلية لهذا الاستعمار + +276 +00:24:45,200 --> 00:24:50,220 +طيب مدام الغرب فكر هذا التفكير الجديد وغير خطته + +277 +00:24:50,220 --> 00:24:55,500 +بهذا التغيير وبهذا الشكل يعني هل في فرق كبير بين + +278 +00:24:55,500 --> 00:24:59,420 +هذا الشكل الجديد وهذه الخطة الجديدة المسمى بالغزو + +279 +00:24:59,420 --> 00:25:03,820 +الفكري وبين الغزو العسكري الذي اعتمده في البداية + +280 +00:25:03,820 --> 00:25:08,130 +وخاطفي حروب كثيرة سميت بالحروب الصليبية ولا زال + +281 +00:25:08,130 --> 00:25:11,790 +ايضا لا يعني يا أخوات انه الآن اعتمد الغزو الفكر + +282 +00:25:11,790 --> 00:25:17,030 +انه انتهى عن الغزو العسكري لأ لازال في بلدان مغزوة + +283 +00:25:17,030 --> 00:25:21,730 +ومحتلة وكل يوم لسه فرنسا جديد يعني بتطمع في مالي + +284 +00:25:21,730 --> 00:25:26,030 +وهي قضية حديثة جديدة وامريكا لازال يعني لها بقايا + +285 +00:25:26,030 --> 00:25:31,170 +هنا و هناك وفي العراق ناهيكم عن القضيةالمركزية + +286 +00:25:31,170 --> 00:25:36,330 +للأمة العربية والإسلامية فلسطين التي لازالت محتلة + +287 +00:25:36,330 --> 00:25:41,750 +وتحت الاحتلال اذا حتى وهم يعتمدون خطة الغزو الفكري + +288 +00:25:41,750 --> 00:25:45,230 +لم ينتهوا من غزوهم العسكر عشان يقولنا العنوان ان + +289 +00:25:45,230 --> 00:25:48,870 +الحروب الصالبية لم تنتهي بعد نرجع الى السؤال مرة + +290 +00:25:48,870 --> 00:25:53,330 +اخرى ما الفرق او الفروق بين الغزو الفكري الجديد + +291 +00:25:53,330 --> 00:25:57,270 +وبين الغزو العسكري ونريد ان نسمع من الجميع اذا + +292 +00:25:57,270 --> 00:26:03,380 +يعني مفارحوار كبير بدنا نسمع من الجامعة اول هذه + +293 +00:26:03,380 --> 00:26:07,600 +الفروق الجوهرية .. اعلينا الصوت شوية عشان الكل + +294 +00:26:07,600 --> 00:26:11,520 +يسمع .. اولا الغزو العسكري ماهله؟ ايش هدفه؟ يستهدف + +295 +00:26:11,520 --> 00:26:15,820 +الأرض و مافيها من خيار موه و مهل .. نعم .. يستهدف + +296 +00:26:15,820 --> 00:26:19,780 +أشرف مافي الإنسان من عقيدة و فكر و قلب و عقلبارك + +297 +00:26:19,780 --> 00:26:22,460 +الله فيك .. لما نقول يا أخوات الغزو العسكر يستهدف + +298 +00:26:22,460 --> 00:26:26,280 +مش معناه هدفه .. لأ يعني هو بيأتي أين؟ يأتي على + +299 +00:26:26,280 --> 00:26:29,420 +الأرض و يبقى على الأرض و بينها بخيراته و بينها و + +300 +00:26:29,420 --> 00:26:32,900 +بينها .. لكن هذا الغزو الفكري اليوم هدفه و مش + +301 +00:26:32,900 --> 00:26:37,820 +الأرض في حد ذات .. بقدر ما هدفه العقيدة و الدين و + +302 +00:26:37,820 --> 00:26:41,520 +الفكر و الثقافة .. و ال .. و إذا مجاله هو العقل و + +303 +00:26:41,520 --> 00:26:44,900 +القلب .. لأ مجاله أن يأتي على الأرض و يقاتل على + +304 +00:26:44,900 --> 00:26:48,680 +الأرض و يحارب على الأرض .. هي المقصود .. و إلا هدف + +305 +00:26:48,680 --> 00:26:52,270 +الأثنين واحد ..هو القضاء على الإسلام والمسلمين و + +306 +00:26:52,270 --> 00:27:03,530 +.. نعم .. اتنين من النقاط .. اتفضل الأخت .. لماذا + +307 +00:27:03,530 --> 00:27:10,090 +الغزو العسكري يضرب الغزاة أنفسهم؟ + +308 +00:27:10,090 --> 00:27:18,820 +يعني هذا الغزو العسكريلا يقبله أهل البلاد التي + +309 +00:27:18,820 --> 00:27:23,740 +تحتال أرضهم وبالتالي سياثرون عليه ويقاومونه أما + +310 +00:27:23,740 --> 00:27:31,040 +الغزو الفكري؟ نعم + +311 +00:27:31,040 --> 00:27:36,280 +يفقد المسلمين القدرة والاستعداد للمواجهة والمجابة + +312 +00:27:37,290 --> 00:27:40,510 +حتى يكون عندهم القابلية كما قلنا للاستعمار لأنهم + +313 +00:27:40,510 --> 00:27:45,290 +بيغزوه فكريا فليه ما يقاتل من يتقبل فكره وافكاره + +314 +00:27:45,290 --> 00:27:52,470 +ويتطبع بقيمه وعاداته لن يجده غريبا عنه لأنه مثله + +315 +00:27:52,470 --> 00:27:58,410 +مثله سيكون تلاتة تفضل الأخت اللي هنا كنت بالعسكري + +316 +00:27:58,410 --> 00:28:02,250 +مش عاوم تحس العمل بيعمل أسلوب ده لأن الواضح اللي + +317 +00:28:02,250 --> 00:28:03,350 +حصل ليه + +318 +00:28:06,740 --> 00:28:10,880 +يعني قريب من النقطة الثانية من النقطة الثالثة هناك + +319 +00:28:10,880 --> 00:28:15,780 +يقول بكلمة يعني يضرب الغزاء أنفسهم أنفسهم هناك + +320 +00:28:15,780 --> 00:28:19,680 +يحرك فيهم القدرة على الاستعداد هنا يحرك العمل + +321 +00:28:19,680 --> 00:28:24,240 +للاستقلال ليبقى أهل البلاد مهما طال الزمن يعني + +322 +00:28:24,240 --> 00:28:28,560 +قابلين الاستعمار العسكري لكنهم يتقبلون الغزو + +323 +00:28:28,560 --> 00:28:35,280 +الفكري بفقدانهم للقدرة على المواجهة والمجابة أربعة + +324 +00:28:36,970 --> 00:28:40,870 +الغاز العسكري وسائله منافرة لأنها مصلبة بالدمار و + +325 +00:28:40,870 --> 00:28:45,890 +القتل و .. و .. و أدمان بينما الغاز العسكري وسائله + +326 +00:28:45,890 --> 00:28:50,170 +ناعمة و خادعة مصطوبة بالشهوات و الإقبال منها بيكون + +327 +00:28:50,170 --> 00:28:53,500 +أسرع من الغاز العسكري بارك الله فيك و أحسنإذا + +328 +00:28:53,500 --> 00:28:57,060 +الغزو العسكر يا أخوات لا أحد يقبله لأنه يأتي + +329 +00:28:57,060 --> 00:29:05,260 +بالقتل و بالدماء و بالاصابات .. إذا هو الوسائل + +330 +00:29:05,260 --> 00:29:09,580 +التي يعتمدها الغزو العسكري منفرة كل يكرهها و ينفر + +331 +00:29:09,580 --> 00:29:13,540 +منها و يتأذى منها وبالتالي لا أحد يقبل كما قلنا + +332 +00:29:13,540 --> 00:29:19,020 +قبل قليل بهذه الوسائل المنفرة الغزو الفكري لا ينفر + +333 +00:29:19,020 --> 00:29:27,380 +بل يغري و يرغب و يخدعبهذا البريق اللامع تحت سطار و + +334 +00:29:27,380 --> 00:29:34,020 +شعار المدنية و الحداثة و التقدم و التطور و + +335 +00:29:34,020 --> 00:29:38,060 +التكنولوجيا و التقدم و لا يقولك انا بدأ غربك و + +336 +00:29:38,060 --> 00:29:42,440 +اجعلك غربيا و بتدخلك زيه و بتدخلك تتقدم و تتطور و + +337 +00:29:42,440 --> 00:29:48,520 +كذا و كذا و كذا لأن بهذه المظاهر الخادعة و البراقة + +338 +00:29:48,520 --> 00:29:51,440 +خمسة .. تفضل يا أخت الورقة + +339 +00:30:02,390 --> 00:30:09,610 +و المعصولة ده بدوش عسل، بدوش .. اه كما تفضلت + +340 +00:30:09,610 --> 00:30:13,950 +الأخت، ان الغزو العسكري تكاليف ماله باردةباهظة .. + +341 +00:30:13,950 --> 00:30:18,350 +بتكلف .. هذا بده جيوش و عتاد و بده انفاق على هذه + +342 +00:30:18,350 --> 00:30:22,810 +الجيوش و بده أسلحة .. كل هذه تكاليف و باهظ .. و + +343 +00:30:22,810 --> 00:30:26,670 +التكاليف الأكثر القتل .. بتكلفهم أرواح يعني .. + +344 +00:30:26,670 --> 00:30:31,610 +أرواح جنود بده تقتل .. لكن الغزو العسكري كما قالت + +345 +00:30:31,610 --> 00:30:36,930 +يعني كل بضاعته و سلعته لسان معسول و لسان يتحدث و + +346 +00:30:36,930 --> 00:30:42,500 +يغري و يرغب بهذه الأفكارلا يحتاج .. مش معناه + +347 +00:30:42,500 --> 00:30:45,780 +بيحتاجش أبدا .. لأ هم بقلفوا و بيعملوا .. لكن ما + +348 +00:30:45,780 --> 00:30:49,920 +بيكلفهمش يعني بيخسروش .. بيخسروش مخاسر .. هي المال + +349 +00:30:49,920 --> 00:30:52,780 +أخر حاجة بيفكروا فيها .. بيخسروش ضحايا .. هي + +350 +00:30:52,780 --> 00:30:55,580 +المقصود بالتكاليف .. بيخسروش ضحايا كما يخسرونها + +351 +00:30:55,580 --> 00:30:58,500 +وين؟ في الغزو العسكري .. في الغزو .. بس بل يكون + +352 +00:30:58,500 --> 00:31:02,500 +المسلمون هم الضحايا في هذا الغزو الفكري .. لأن من + +353 +00:31:02,500 --> 00:31:07,600 +فقد دينه فقد كل شيء .. يعني فقدان الدين هو كل شيء + +354 +00:31:07,600 --> 00:31:13,770 +.. مش فقدان المال ولا فقدان أي شيء أخر ..قادة + +355 +00:31:13,770 --> 00:31:16,630 +الغزو العسكري وجنودهم يوجدون في مسرح للعمليات + +356 +00:31:16,630 --> 00:31:19,410 +والاهتلاف بينما في الغزو الشركي يكون القادة كمان + +357 +00:31:19,410 --> 00:31:22,470 +جايزين عن الأحداث نعم بارك الله فيك، برضه نقطة + +358 +00:31:22,470 --> 00:31:26,430 +جوهريه، لابد في الغزو العسكري و الاحتلال أن يكون + +359 +00:31:26,430 --> 00:31:30,890 +القادة متواجدين في الميدان ويأتوا بأنفسهم ويديروا + +360 +00:31:30,890 --> 00:31:35,650 +المعركةوظاهرين وبرزين ومعرفين لكن في الغزو الفكري + +361 +00:31:35,650 --> 00:31:42,930 +يستترون ورأس السطار وشعار و أقنعة وخادعة ولا + +362 +00:31:42,930 --> 00:31:47,050 +يظهرون .. لا يظهرون .. يظهر فكرهم وينتشر فكرهم وهم + +363 +00:31:47,050 --> 00:31:52,090 +غير ظاهرين على الساحة كما يظهرون في الغزو العسل + +364 +00:31:52,090 --> 00:31:55,710 +نقطة السابعة والأخيرة الأخوات ما سمعناهم .. فضل + +365 +00:31:55,710 --> 00:31:57,290 +أخت الورق .. اه حضرتك + +366 +00:32:02,920 --> 00:32:06,740 +هنا بقول كثيرا يعني مش .. معناها فيقله الغزو + +367 +00:32:06,740 --> 00:32:12,780 +العسكري لا يجد له كثيرا من الأتباع مقارنة .. هكذا + +368 +00:32:12,780 --> 00:32:17,200 +الكلام يفهم مقارنة بالغزو الفكري فنجد له أتباع + +369 +00:32:17,200 --> 00:32:20,960 +كثير و هنتكلم بعد قليل على أتباع و أنصار الغزو + +370 +00:32:20,960 --> 00:32:25,140 +الفكري و هنشوفهم من أصناف متعددة أما في الغزو + +371 +00:32:25,140 --> 00:32:31,140 +العسكريقليل من الناس يعني نسبيا عدد قليل الذي + +372 +00:32:31,140 --> 00:32:37,660 +يتقبل ذلك ويقبل ذلك ويعاون المحتل والمستعمر لأن + +373 +00:32:37,660 --> 00:32:45,640 +هذه اسمها يعني خيانة لله و للدين و للوطن فمن يقبل + +374 +00:32:45,640 --> 00:32:48,920 +هذه الخيانة مش بسهولة فاللي يقبلها بيكون لا دين له + +375 +00:32:48,920 --> 00:32:55,810 +أصلالا دين لهو ولا .. ولا ضمير أصلا إنساني حتى من + +376 +00:32:55,810 --> 00:33:00,030 +ناحية إنسانية لا يقبل الإنسان الإبن شعبي ووطني أن + +377 +00:33:00,030 --> 00:33:06,030 +يقتل بسببه حينما يكون هو متعامل أو عميلا خائنا مع + +378 +00:33:06,030 --> 00:33:09,710 +أدوي ضد أهل بلده ووطني لكن في الغزو الفكري بنلاقي + +379 +00:33:09,710 --> 00:33:16,220 +كتاب وأقلام وسياسيين وصحفيين وادباءيسويقون لهذا + +380 +00:33:16,220 --> 00:33:19,940 +الفكر و بتلاقي عددهم يعني كبير نسبيا بالنسبة + +381 +00:33:19,940 --> 00:33:26,840 +لأتباع الغزو العسكري طب ما هي الأهداف أو أهداف + +382 +00:33:26,840 --> 00:33:31,720 +الغزو الفكري؟ مدون ان اتحدثنا عنه و رأينا الفوارق + +383 +00:33:31,720 --> 00:33:36,920 +بين الغزو الفكري و العسكري أكيد له أهداف و أهداف + +384 +00:33:36,920 --> 00:33:38,860 +كثيرة منها واحد فضله + +385 +00:33:41,740 --> 00:33:45,520 +إذا هو الآن يريد أن يضرب الإسلام في العمق في القلب + +386 +00:33:45,520 --> 00:33:51,960 +من الداخل ويضعف فعليته التي تؤثر في المسلمين + +387 +00:33:51,960 --> 00:33:59,240 +فتجعلهم يرفضون الاحتلال والاستعمار وغزو من أي نوع + +388 +00:33:59,240 --> 00:34:06,280 +اثنين هنا أخوات فضل الأخت فضل + +389 +00:34:11,980 --> 00:34:15,460 +برك الله فيك، هذه كانت مشكلة كبيرة، ربما كانت من + +390 +00:34:15,460 --> 00:34:19,780 +أحد الأهداف خلال الحروب الصليبية المتتالية، لأن + +391 +00:34:19,780 --> 00:34:26,770 +الإسلام وصل إلى الغرب و إلى بلادهمفكيف يأتي هؤلاء + +392 +00:34:26,770 --> 00:34:33,810 +من أقصى البلاد إلى بلادنا وينشروا دينهم عقيدتهم؟ + +393 +00:34:33,810 --> 00:34:37,890 +طب احنا بدنا نمنعهم من ذلك ونحد من انتشاره ونحد من + +394 +00:34:37,890 --> 00:34:43,070 +انتشار هذا الدين وبالتالي خير وسيلة للدفاع ماذا؟ + +395 +00:34:43,400 --> 00:34:46,640 +الهجوم كالقعد خير وصيرة للدفاع على الهجوم بدل ما + +396 +00:34:46,640 --> 00:34:50,320 +ننتظرهم و نستنعهم يأتوا إلى ديارنا بدنا نهجم عليهم + +397 +00:34:50,320 --> 00:34:58,100 +لنوقف المد الإسلامي و نحصره داخل حدود لا تجاوزها + +398 +00:34:58,100 --> 00:35:02,180 +ثالثا فضلا تجزأت المسلمين أرضا و أمة و فكرا و + +399 +00:35:02,180 --> 00:35:07,200 +تشويه صورتهم التاريخية؟هذا الغزو الفكر اليوم يا + +400 +00:35:07,200 --> 00:35:12,840 +أخوات من أخطر ما فعل بالمسلمين أنه جزأهم وفرقهم + +401 +00:35:12,840 --> 00:35:17,160 +وشوى صورتهم التاريخية الآن المسلمين بعد أن كانوا + +402 +00:35:17,160 --> 00:35:22,480 +وحدة واحدة و أمة واحدة وخلافة واحدة ودولة واحدة + +403 +00:35:22,480 --> 00:35:27,920 +أصبح اليوم المسلمون أصبحوا فرقا و أحزابا وشيعة + +404 +00:35:27,920 --> 00:35:34,630 +وجماعات ويقاتلوا بعضها بعضاولا يتوحدون كما كانوا + +405 +00:35:34,630 --> 00:35:43,770 +متحدين من قبل وهناك أقوال كثيرة لمباشرين ومن أصحاب + +406 +00:35:43,770 --> 00:35:49,830 +الغزو الفكري يؤكدون هذه الأهداف التي هم عليها + +407 +00:35:49,830 --> 00:35:54,590 +نكتفي بقراءة مقالة أحد الصهاين اليهود الكبار وهو + +408 +00:35:55,320 --> 00:36:01,900 +أول رئيس وزراء لدولة الكيان المسخ الصوفيوني + +409 +00:36:01,900 --> 00:36:07,220 +بينجوريون قال نحن لا نخشى الاشتراكيات ولا الثوريات + +410 +00:36:07,220 --> 00:36:11,940 +ولا الديمقراطيات في المنطقة نحن فقط نخشى الإسلام + +411 +00:36:11,940 --> 00:36:17,700 +هذا المارد الذي نام طويلا وبدأ يتململ من جديد + +412 +00:36:17,700 --> 00:36:23,840 +فالكل يحسب حسابالهذا الدين العظيم لأنهم جربوه عبر + +413 +00:36:23,840 --> 00:36:30,560 +التاريخ كيف وحد المسلمين وكيف كان سبب قوتهم طيب + +414 +00:36:30,560 --> 00:36:35,540 +ننهي الحديث يا أخوات الحديث عن أتباع وأنصار الغزو + +415 +00:36:35,540 --> 00:36:41,940 +الفكري لناخد في تفاصيل هؤلاء أصناف من الناس موجودة + +416 +00:36:41,940 --> 00:36:47,700 +وهم أربعة أصناف الصنف الأول همالأجراء سنعرف + +417 +00:36:47,700 --> 00:36:51,880 +المقصود بيهم ثم الصنف الثاني هم الخارجون يعني عن + +418 +00:36:51,880 --> 00:36:57,220 +الدين والإسلام الصنف الثالث المتهاونون الرابع + +419 +00:36:58,980 --> 00:37:03,280 +الجهلة بحقيقة الإسلام كلهم يؤدي دوره في الغزو + +420 +00:37:03,280 --> 00:37:07,540 +والفكرة فهؤلاء الأجراء يعني العملاء ودورهم ماضح + +421 +00:37:07,540 --> 00:37:13,340 +ومعروف يبيعوا أنفسهم جراء مقابل دراهم معدود فنجد + +422 +00:37:13,340 --> 00:37:17,900 +هؤلاء ليسوا عملاء يعني فقط كما هو الحال عندنا لو + +423 +00:37:17,900 --> 00:37:23,060 +يقوم بيعني ..يتجسس على أولاد بلديه وشعبي ووطني + +424 +00:37:23,060 --> 00:37:26,680 +ويدل العدو عليهم بل قد نجدهم من السياسيين + +425 +00:37:26,680 --> 00:37:31,240 +والاقتصاديين والعسكرين والصحافيين والمثقفين + +426 +00:37:31,240 --> 00:37:36,740 +يسويقون لهذا الغزو والافكارالصنف الثاني الخارجون + +427 +00:37:36,740 --> 00:37:42,180 +عن الدين والإسلام الذين ارتدوا فهؤلاء أبواق سهلة + +428 +00:37:42,180 --> 00:37:48,480 +للغزو الفكري طالما أن الواحد منهم لا دين له ولا + +429 +00:37:48,480 --> 00:37:53,080 +عقيدة له فما الذي سيمنعه من أن يسوق لهذا الفكر؟أما + +430 +00:37:53,080 --> 00:37:58,040 +المتهاونون و هم طبقة موجودة في كل مجتمع مسلم لا + +431 +00:37:58,040 --> 00:38:02,800 +يبالي بأحداث ولا بسياسات ولا ما يحدث في المنطقة + +432 +00:38:02,800 --> 00:38:07,980 +ليس له هم إلا أن يأكل و يشرب و يتنزه ولا يهتم بأمر + +433 +00:38:07,980 --> 00:38:13,300 +المسلمين فهؤلاء يعني أيضا يسوقون لهذا الفكر لأنهم + +434 +00:38:13,300 --> 00:38:19,610 +يتقبلونه ولا يكترثون به ولا بخطورتهو بيكونوا يعني + +435 +00:38:19,610 --> 00:38:24,710 +دورهم دور سلبي على الأقل آخر هذه الأصناف الأتماء + +436 +00:38:24,710 --> 00:38:31,630 +الجهلة بحقيقة الإسلامهؤلاء جهلهم بهذا الدين أيضًا + +437 +00:38:31,630 --> 00:38:38,810 +يجعلهم يتقبلون هذا الفكر ويسوقونه أيضًا ويقولون + +438 +00:38:38,810 --> 00:38:42,750 +كلامًا لا يدون معنى كثير يوم نشوف في الإعلام و + +439 +00:38:42,750 --> 00:38:46,550 +الإذاعات بطلع فلان برفض الرئيس فلان و وزعيم لماذا؟ + +440 +00:38:46,550 --> 00:38:51,450 +وخلاص و برفضوا بس لا عنده فكر ولا فهم ولا عنده كذا + +441 +00:38:51,450 --> 00:38:56,800 +مجرد أنه يريد هذا الجهلالطامة الكبرى يعني موجود من + +442 +00:38:56,800 --> 00:39:00,700 +أصناف هؤلاء الناس ويدافع عن الفكر الآخر أو البديل + +443 +00:39:00,700 --> 00:39:06,960 +أو الغربي المعارض والمناقض للإسلام نقف يعني عند + +444 +00:39:06,960 --> 00:39:11,640 +وسائل الغزو الفكري في المحاضرة القادمة نتحدث ان + +445 +00:39:11,640 --> 00:39:15,420 +شاء الله عن وسائل الغزو الفكري وبارك الله فيكم + +446 +00:39:15,420 --> 00:39:17,820 +والسلام عليكم ورحمة الله وبركاته + diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/OdrH_hsO_o4_raw.srt b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/OdrH_hsO_o4_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..7d4269629c3300d9d59185f54ed07156254be5a6 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/OdrH_hsO_o4_raw.srt @@ -0,0 +1,1636 @@ +1 +00:00:20,910 --> 00:00:24,470 +الحمد لله والصلاة والسلام على رسول الله أما بعد + +2 +00:00:24,470 --> 00:00:31,650 +وصلنا إلى الحديث عن النموذج والشخصية الثانية من + +3 +00:00:31,650 --> 00:00:39,990 +النماذج التي أخذناها كنماذج من مصر كناس وأشخاص + +4 +00:00:39,990 --> 00:00:44,310 +تأثروا بالعلمانية هذا النموذج وهذه الشخصية الثانية + +5 +00:00:44,310 --> 00:00:50,150 +هو قاسمأمين وهو أحد تلاميذ الشيخ محمد عبدو درس في + +6 +00:00:50,150 --> 00:00:56,490 +الجامعات الفرنسية وأشهر هذه الجامعات جامعة Monoply + +7 +00:00:56,490 --> 00:01:01,030 +الفرنسية هناك تعرف على فتاة اسمها سلافة وصاحبته في + +8 +00:01:01,030 --> 00:01:08,010 +رحلته عاد إلى مصر بلده وهو يحمل أفكار غريبة وجديدة + +9 +00:01:08,880 --> 00:01:14,040 +أعجب بها زعماء وطنيون مشهورون في ذلك الوقت، أمثال + +10 +00:01:14,040 --> 00:01:18,540 +سعد زغلول ومصطفى كامل وأحمد لطف السيد وغيرهم، + +11 +00:01:18,540 --> 00:01:23,620 +وهؤلاء الزعماء كونهم يتبنون الفكر القومي والوطني + +12 +00:01:24,370 --> 00:01:28,510 +كان الاستعمار البريطاني في ذلك الوقت يعجب بهم و + +13 +00:01:28,510 --> 00:01:33,790 +بأفكارهم فكان يسمي مثل قاسم أمين و طه حسين و هذه + +14 +00:01:33,790 --> 00:01:38,690 +الزعمات و هذه الشخصيات بأتباع المرحوم الشيخ محمد + +15 +00:01:38,690 --> 00:01:43,390 +عبدو و كان هناك تناغم و انسجام في هذه الأفكار + +16 +00:01:43,390 --> 00:01:49,030 +جميعهاوتصب وتصب في مصاب واحد وقالب واحد مما جعل + +17 +00:01:49,030 --> 00:01:53,170 +الغربيين والأجانب وحتى الاستعمار يحجب بهذه الأفكار + +18 +00:01:53,170 --> 00:01:59,350 +لأن كلها تصب بعيدا عن الوحدة الإسلامية التي يخشاها + +19 +00:01:59,350 --> 00:02:03,630 +الغرب والاستعمار دائما الدعوة إلى القومية وإلى + +20 +00:02:03,630 --> 00:02:08,660 +الوطنية وإلى تجديد بعض مفاهيم الدين والإسلامالتي + +21 +00:02:08,660 --> 00:02:12,740 +تبتعد بالإنسان عن الجهاد و ضد الاستعمار و الاحتلال + +22 +00:02:12,740 --> 00:02:18,640 +و مقاومته هذه مما يغذيها ويدعمها الاستعمار دائما + +23 +00:02:18,640 --> 00:02:25,650 +قاسم أمين ألف كتابين مشهورينالكتاب الأول هو تحرير + +24 +00:02:25,650 --> 00:02:29,850 +المرأة والثاني المرأة الجديدة وفي هذين الكتابين + +25 +00:02:29,850 --> 00:02:36,470 +لخص أفكاره و آراءه المختلفة التي تبدو أمامكم جميعا + +26 +00:02:36,470 --> 00:02:41,090 +ونريد من الجميع المشاركة في الحديث عنها من أهم هذه + +27 +00:02:41,090 --> 00:02:47,320 +الأفكار وكلها كما ستراهم تنصبأو تحوم حول المرأة + +28 +00:02:47,320 --> 00:02:49,900 +لأن الكتابين يعني بيخصوا المرأة يعني العنوان + +29 +00:02:49,900 --> 00:02:54,680 +الكتابين خاص بالمرأة في سنجلة هذه القضايا يعني تخص + +30 +00:02:54,680 --> 00:03:01,360 +المرأة أكثر من شيء آخر تفضل مساواة المرأة برجل + +31 +00:03:01,360 --> 00:03:07,240 +متفوق رجل ذهب لسبب استعمال الأعضاءوليس هو ما خصه + +32 +00:03:07,240 --> 00:03:10,400 +الله سبحانه وتعالى بيه وكأنه الأمر طبيعي يعني لا + +33 +00:03:10,400 --> 00:03:15,840 +علاقة له بما أوكله الله سبحانه وتعالى للرجل من + +34 +00:03:15,840 --> 00:03:22,340 +القوامة وإنما يعني هذا أمر طبيعي لأن الرجل بعضلاته + +35 +00:03:22,340 --> 00:03:30,150 +وبستختامه لهذه الأعضاء هيما ما يجعله يتفوق على + +36 +00:03:30,150 --> 00:03:35,930 +المرأة ولا لشيء آخر يعني الميزة للرجل على المرأة + +37 +00:03:35,930 --> 00:03:39,770 +وكأنه المساواة يعني كاملة فقط بالشكل بس هو بيختلف + +38 +00:03:39,770 --> 00:03:44,110 +في معادة ذلك مرأة مثل الرجل يجب أن تفعل ما يفعله + +39 +00:03:44,110 --> 00:03:47,730 +الرجل في كل شيء معادة في هذا الجانبوهذا ليس صحيحا + +40 +00:03:47,730 --> 00:03:51,710 +ولا دقيقا ولا سليما هناك مساواة تامة وكاملة في + +41 +00:03:51,710 --> 00:03:55,190 +جوانب كثيرة في الإسلام بين الرجل والمرأة لكن هناك + +42 +00:03:55,190 --> 00:03:59,950 +فيه قصصيات للرجال على النساء لا يمكن فيها المساواة + +43 +00:03:59,950 --> 00:04:02,890 +لا يمكن للرجل أن يقوم ببعض الأعباء الموكلة إلى + +44 +00:04:02,890 --> 00:04:05,790 +المرأة ولا يمكن للمرأة أن تقوم ببعض الأعباء + +45 +00:04:05,790 --> 00:04:09,590 +الموكلة إلى الرجل وهذا الكلام سنتكلم عنه بالتفصيل + +46 +00:04:09,590 --> 00:04:14,030 +هنا الحديث عن المرأة وقضاياهاوالشبهات التي أثارها + +47 +00:04:14,030 --> 00:04:17,530 +أعداء الإسلام حول المرأة احنا لأ مش معنين بالرد + +48 +00:04:17,530 --> 00:04:21,930 +كثيرا يعني في كل نقطة لإن الرد يعني بيبعدنا كثيرا + +49 +00:04:21,930 --> 00:04:26,390 +احنا فقط بدنا نسلط الضوء على أفكار هذا الرجل اتنين + +50 +00:04:26,390 --> 00:04:29,790 +من ما ورد في هذين الكتابين الانتقاب والتباركة ليس + +51 +00:04:29,790 --> 00:04:34,330 +من مشروعية الإسلام الإسلامية ولا للتعاقد ولا للأذب + +52 +00:04:34,330 --> 00:04:37,170 +بهم من العادات القديمة السابقة على الإسلامبارك + +53 +00:04:37,170 --> 00:04:41,490 +الله فيك إذا ان اعتبر النقاب والحجاب هذا ليس أمرا + +54 +00:04:41,490 --> 00:04:45,590 +مشروعا مأمورا به مفروضا على المرأة وإنما هذا مما + +55 +00:04:45,590 --> 00:04:49,730 +توارثته النساء والأجيال جيلا بعد جيلا من العادات + +56 +00:04:49,730 --> 00:04:54,850 +والتقاليد فبقى وأين آيات القرآن الصريحة التي توجب + +57 +00:04:54,850 --> 00:04:59,670 +وتلزم المرأة المسلمة بالحجاب وحقوقه كما قلنا لنريد + +58 +00:04:59,670 --> 00:05:03,390 +أن نفصل في كل قضية من هذه القضايا في الأمر أوضح + +59 +00:05:03,390 --> 00:05:08,520 +وأسرح من أن نرد فيهالامر الثالث اتفضل يا أختي + +60 +00:05:08,520 --> 00:05:12,200 +العائق + +61 +00:05:12,200 --> 00:05:16,660 +بارك + +62 +00:05:16,660 --> 00:05:20,380 +الله فيك يعني هل هذا وصف صحيح جالس بالحجاب؟ هل + +63 +00:05:20,380 --> 00:05:26,080 +الحجاب و كله كنا محجبات؟ هل أعاققنا الحجاب عن ما + +64 +00:05:26,080 --> 00:05:29,560 +يذكره هذا؟ عن التقدم، عن التعلم، عن التعليم، عن + +65 +00:05:29,560 --> 00:05:36,460 +العمل؟وهل هو كما هو موصوف بأنه يتسطر أو تتسطر بيه + +66 +00:05:36,460 --> 00:05:40,680 +النساء اذا قلنا اذا في امرأة ثبت عليها او استخدمت + +67 +00:05:40,680 --> 00:05:46,660 +هذا النقاب لكي تقوم بجريمة او تتسطر بيه لكذا .. + +68 +00:05:46,660 --> 00:05:51,660 +لأن حالة واحدة او حالتين او ثلاثون هناك هل هذا يصح + +69 +00:05:51,660 --> 00:05:56,900 +ان يعمم على باقي النساء المحتشمات الورعات اللي + +70 +00:05:56,900 --> 00:06:02,360 +تحافظ على هذه الفريضةال .. وهذا الأمر الرباني يعني + +71 +00:06:02,360 --> 00:06:08,120 +الكلام برضه ليس صحيحا ولا سليما ولا يستحق أصلا + +72 +00:06:08,120 --> 00:06:12,960 +كمان الرد عليه لكن احنا مضطرين أحيانا انه نرد ولو + +73 +00:06:12,960 --> 00:06:19,680 +وعدنا بعدم الرد الأمر الرابع .. هنا الأخوات .. + +74 +00:06:19,680 --> 00:06:22,620 +فضلي الاختلاف بين الجنسين اللي هو دي بالمارس وليه + +75 +00:06:22,620 --> 00:06:27,960 +الاختلافات؟نعم، هل هذا صحيح؟ وده كمان؟ هذه دعوى + +76 +00:06:27,960 --> 00:06:31,620 +الغربيين والأجانب وعلماء النفس الغربيين والأجانب + +77 +00:06:31,620 --> 00:06:35,860 +الكفار البعيدين عن الحياة التي دعا إليه الإسلام + +78 +00:06:35,860 --> 00:06:41,400 +والذين يشجعون على الفاحشة والزنا والعلاقات الغير + +79 +00:06:41,400 --> 00:06:45,760 +مشروعة يقولون هذا الكلام ويدعونا إليه وحياتهم + +80 +00:06:45,760 --> 00:06:51,480 +ومجتمعاتهم قائمة على ذلك هل هذا يتناسب معمجتمعنا + +81 +00:06:51,480 --> 00:06:58,060 +الإسلامي القائم على الحياء والحشمة وقصصيات المرأة + +82 +00:06:58,060 --> 00:07:01,420 +بالنسبة للرجل تختلف المرأة عن الرجل في خصوصيتها + +83 +00:07:01,420 --> 00:07:06,660 +كيف تختلط بيه بدون ضرورة هذا الإختلاط يكون للضرورة + +84 +00:07:06,660 --> 00:07:10,860 +القصوى في حالات لابدة منها أو عنها كما نرى أحيانا + +85 +00:07:10,860 --> 00:07:14,390 +زي راكبة المرأة السيارة أو كان في مكان أو في ..لكن + +86 +00:07:14,390 --> 00:07:18,510 +مادام هناك او ليس هناك داعي للاختلاط فالاصل ان + +87 +00:07:18,510 --> 00:07:22,870 +يبقى الرجال في مكان والنساء في مكان الرجال لهم + +88 +00:07:22,870 --> 00:07:26,830 +اعمالهم الخاصة بيهم النساء لهم اعمالهم الخاصة بيهم + +89 +00:07:26,830 --> 00:07:33,910 +و هكذاأو هذه الدعوة عانى منها أو المجتمع الأوروبي + +90 +00:07:33,910 --> 00:07:37,710 +الغربي كثيرا وسنتحدث عن هذه المعاناة بالتفصيل + +91 +00:07:37,710 --> 00:07:41,550 +والمرأة بنوحد موجود national road نخرج عن إطارنا + +92 +00:07:41,550 --> 00:07:45,750 +بالتفصيل لما نتكلم عن قضية بعينها الإختلاط بين + +93 +00:07:45,750 --> 00:07:50,490 +الجنسين برضه في شبهات حول المرأة هناك التفصيل + +94 +00:07:50,490 --> 00:07:55,190 +والرديعني سيكون واقفيا ان شاء الله تعالى لان نريد + +95 +00:07:55,190 --> 00:07:58,670 +ان نطيل كثيرا في كل قضية اذا .. يعني رددنا بنرد + +96 +00:07:58,670 --> 00:08:03,810 +برضه باختصار شديد في كل قضية .. اتفضل رأيش الرئيس + +97 +00:08:03,810 --> 00:08:07,050 +الأمريكي جورج باش رصد مكافأة للمدارس الثانوية + +98 +00:08:07,050 --> 00:08:11,890 +اللتي تقوم بالفصل بين الجنسين .. صحيح صحيح + +99 +00:08:13,930 --> 00:08:17,030 +هذا صحيح و لو أردنا يعني أن يكون موضوعنا هو الرد ل + +100 +00:08:17,030 --> 00:08:20,850 +.. يعني فسحنا المجال في كل نقطة أن نرد عليه لكن + +101 +00:08:20,850 --> 00:08:25,230 +ليس هو .. ليس هنا مجال الرد على هذه القضايا سيأتي + +102 +00:08:25,230 --> 00:08:29,130 +يعني مفصلا في حينه و في وقته ان شاء الله و في + +103 +00:08:29,130 --> 00:08:38,210 +مكانه كذلك من أفكار هذا الرجل قاسم أمين في كتابيه + +104 +00:08:38,210 --> 00:08:44,760 +تحرير المرأة و المرأة الجديدة اتفضل اختيتابعوا لما + +105 +00:08:44,760 --> 00:08:50,740 +أقوله جيد فرق كبير بين أن تقبل المرأة على نفسها أو + +106 +00:08:50,740 --> 00:08:55,300 +لنفسها أن تكون ثاني أو تتزوج أو يتزوج زوجه عليها + +107 +00:08:55,300 --> 00:09:00,880 +هذا أمر طبيعي في العاطفة وفي الشعور قليل بل نادر + +108 +00:09:00,880 --> 00:09:07,280 +من تقبل هذا شبه إجماع عليا لكن المسألة الدقيقة و + +109 +00:09:07,280 --> 00:09:14,530 +الخطيرةحينما ترفض المرأة هذا الحكم كحكم، انتبهوا + +110 +00:09:14,530 --> 00:09:20,590 +جيدا، لا يحق ولا يصح ولا يجوز بحال لامرأة مسلمة أن + +111 +00:09:20,590 --> 00:09:26,980 +تعلق على هذا الحكم أو ترفضهأو تمطعد منه كحكم شرعي + +112 +00:09:26,980 --> 00:09:31,700 +أو يعني لا ترضى به هذا حكم الله وشرع الله ودين + +113 +00:09:31,700 --> 00:09:39,640 +الله ورفضه وعدم قبوله مسألة يعني تدخل في قضية + +114 +00:09:39,640 --> 00:09:45,890 +خطيرة تدخل في الكفر إذا كان عقيدة نعتقدهاوبعض + +115 +00:09:45,890 --> 00:09:51,290 +النساء وسمعتهن وقد صرحنا بذلك والله هذا ظلم والله + +116 +00:09:51,290 --> 00:09:55,770 +ظلم يعني الراجل اتزوج اكتر من واحد مش هذا ظلم طب + +117 +00:09:55,770 --> 00:09:57,790 +هذا ظلم لمين الكلام؟ ايه اللي انا بتواجهه ولا + +118 +00:09:57,790 --> 00:10:02,150 +لمين؟ مين صاحب هذا الحكم ومن صاحب هذا ال .. هذا + +119 +00:10:02,150 --> 00:10:05,310 +ربنا سبحانه وتعالى فرق بين ان تقبل او لا تقبل انت + +120 +00:10:05,310 --> 00:10:09,250 +حرة لا تقبله على نفسك ولا واحدة بتقبله على نفسكإلا + +121 +00:10:09,250 --> 00:10:12,590 +ما نظر كما قلنا إلا إذا كان حاسس زوجة بحاجة أو كذا + +122 +00:10:12,590 --> 00:10:16,530 +أو وضعها لا يسمح له في ظروف معينة في ظروف طبيعية + +123 +00:10:16,530 --> 00:10:23,050 +نادرة بل معلومة من تقبل هذا معروف في النساء وشعور + +124 +00:10:23,050 --> 00:10:27,290 +لكن كحكم شرعي بجوز لمسلمة اللي بتقول بجوز الآن + +125 +00:10:27,290 --> 00:10:31,230 +ترفع أصبعها نشوف بجوز ليه كمسلمة اعترض على الحكم + +126 +00:10:31,230 --> 00:10:37,240 +كحكمهو بيصير خلل كبير واضح؟ إذا فيه فرق بين هذا و + +127 +00:10:37,240 --> 00:10:41,440 +ذاك الحكم حكم و حكم الله فانكحوا ما طاب لكم من + +128 +00:10:41,440 --> 00:10:46,520 +النساء ماثنى و ثلاثة و رباع حكم شرعي له مبررات و + +129 +00:10:46,520 --> 00:10:50,860 +هو الحكم الجليل من وراه سنأخذ بالتفصيل ليس موضوعها + +130 +00:10:50,860 --> 00:10:55,900 +هنا لأنه ليس موضوعنا سنأخذ و سنعمل استفتاءعند + +131 +00:10:55,900 --> 00:11:01,440 +الحديث عن ذلك من مع وبعد أن ننتهي من مع ايضا او ضد + +132 +00:11:01,440 --> 00:11:07,940 +سنجد الفرق كبير بعد التفصيل الواضح في هذه الجزئية + +133 +00:11:07,940 --> 00:11:11,980 +و المقطة لأن هناك حكم كبيرة وجليلة من وراء هذا + +134 +00:11:11,980 --> 00:11:16,680 +التعدد لا يمكن لنا أن نتجاهلها أو ننكرها وهذه حكمة + +135 +00:11:16,680 --> 00:11:21,260 +الله تعالى في كل أحكامه التي شرعها لنا بس الآن + +136 +00:11:21,260 --> 00:11:26,450 +احنا اردنا التفريقفي هذا الأمر المهم فضل يا أستاذ + +137 +00:11:26,450 --> 00:11:36,010 +أسامي ادخلوا على الخطط ايوة + +138 +00:11:36,010 --> 00:11:42,950 +انت بتسجل عندك ولا ممكن تسجل نعم + +139 +00:11:50,050 --> 00:11:55,030 +فكيف يكون حالها نفسي والاجتماع وكل المستويات إلا + +140 +00:11:55,030 --> 00:12:01,420 +بترضيه لنفسك ولا ترضيه للآخرين؟هذه واحدة من حالات + +141 +00:12:01,420 --> 00:12:06,420 +وحكم جليلة كثيرة يعني انا وعدت وخلّينا على وعدنا + +142 +00:12:06,420 --> 00:12:10,820 +لأنها هتاخد مننا وقت يعني هي مشروحة ومفصلة في + +143 +00:12:10,820 --> 00:12:14,700 +حينها مابناش الآن نقولها ونعيدها لإن احنا معنيين + +144 +00:12:14,700 --> 00:12:20,060 +بكسب الوقت يعني نكتفي بهذه الجزئية وهي قريبة جدا + +145 +00:12:20,060 --> 00:12:23,860 +يعني في المحاضرة القادمة أو اللي بعدها سيمر معنا + +146 +00:12:23,860 --> 00:12:27,880 +موضوع المرأة والقضايا المتعلقة بها وستأتي مفصلةو + +147 +00:12:27,880 --> 00:12:31,180 +يوم سنسمح للأستاذ أسامة أبو حمزة و غيره و كل + +148 +00:12:31,180 --> 00:12:35,160 +الأخوات أن يدلوا بدلوهم في ذلك و نطرح القضية + +149 +00:12:35,160 --> 00:12:38,380 +للحوار و النقاش خاصة أنا مسجلة و الكل هيسمعنا فيها + +150 +00:12:38,380 --> 00:12:42,340 +و هذه القضية بتبتث حساسية عند كثير من النساء لنشوف + +151 +00:12:42,340 --> 00:12:45,380 +حكم الله فيها حينما شرع الله تعالى عشان الحكم + +152 +00:12:45,380 --> 00:12:50,020 +الجليل من وراها و بعدها اللي عندها كلام ممكن أن + +153 +00:12:50,020 --> 00:12:54,580 +تقوله و نسمعه في هذا الجانب ليس هو موضوعها الآن بس + +154 +00:12:54,580 --> 00:12:59,660 +نسمع الأخت كنت بتسألي ولا تفضل؟الجماعات يسمغى + +155 +00:12:59,660 --> 00:13:03,880 +المرأة عروضة نعم هذا برك الله فيك يعني الكلام فيه + +156 +00:13:03,880 --> 00:13:08,760 +دعوة ال .. ال .. ال .. الرذيلة يعني يعني الدعوة + +157 +00:13:08,760 --> 00:13:11,720 +إلى التختلط المرأة بالرجل والرجل بينبسط لما يكون + +158 +00:13:11,720 --> 00:13:15,020 +في امرأة او في .. يعني دعوة إلى الرذيلة وإلى الفاح + +159 +00:13:15,020 --> 00:13:21,390 +ويعني نزع ال .. ال .. الحياةالذي تمتاز به المرأة + +160 +00:13:21,390 --> 00:13:25,250 +المسلمة بل الرجل كمان الحياء شعبا من الإيمان لابد + +161 +00:13:25,250 --> 00:13:28,310 +ان يكون هناك حياء لابد ان يكون هناك حاجز و فاصل + +162 +00:13:28,310 --> 00:13:34,110 +بين الرجل و المرأة التي لا تحله بخلاف زوجته و أخته + +163 +00:13:34,110 --> 00:13:37,590 +و أمه و كده بياخد راحته معها و بيجلس معها من + +164 +00:13:37,590 --> 00:13:42,870 +محارمه او من من يجوز له زوجته تجوز له او لا من + +165 +00:13:42,870 --> 00:13:46,930 +محارمه التي لا مجال فيها لإثارة شهوة و لا كده لكن + +166 +00:13:46,930 --> 00:13:51,840 +هذه الدعوة إلى هذاالاختلاط بهذه الطريقة مدعا إلى + +167 +00:13:51,840 --> 00:13:55,720 +الرذيلة وهم يدعون إلى ذلك و هذا حال المجتمعات + +168 +00:13:55,720 --> 00:14:01,580 +الغربية لكن لا يليق بمجتمعاتنا الإسلامية أيضا دعا + +169 +00:14:01,580 --> 00:14:07,340 +إلى .. تفضل بارك + +170 +00:14:07,340 --> 00:14:10,320 +الله فيه، هذا القضية ليس منصوصا عليها عندنا، يعني + +171 +00:14:10,320 --> 00:14:15,630 +من أين جاء بها؟يقع عندنا الطلاق بمجرد أن يتلفظ بيه + +172 +00:14:15,630 --> 00:14:20,850 +الرجل باللفظ الصريح يقول لزوجته أنت طالق فيقف بدون + +173 +00:14:20,850 --> 00:14:25,090 +يعني وجود قاضي أو محكمة أو .. لكن قال بعض العلماء + +174 +00:14:25,090 --> 00:14:30,810 +أنه الآن في ظل الظروف الحالية يفضل تسجيل الطلاق في + +175 +00:14:30,810 --> 00:14:34,330 +المحكمة حفاظا على الحقوقمتى طلقتها في تاريخ كذا؟ + +176 +00:14:34,330 --> 00:14:38,130 +متى تنتهي عدتها؟ لو مات في أثناء العدة في أحكام لو + +177 +00:14:38,130 --> 00:14:41,730 +مات بعدها أو ماتت فيها؟ تارث و لا يارثة؟ لتارث و + +178 +00:14:41,730 --> 00:14:45,350 +لا يارثة؟ متى يجوز لو أن يعيدها؟ يعني إثباتا + +179 +00:14:45,350 --> 00:14:50,450 +للحقوق لكن كطلاق كحكم يقع بمجرد يعني التلفظ به + +180 +00:14:50,450 --> 00:14:54,590 +وليس شرطه أن يكون في وثيقة و رسمية و بحضور شاهدين + +181 +00:14:54,590 --> 00:14:59,410 +و هذا صراعق الزواج تفضلالدعوة اللي أخدت خطاها + +182 +00:14:59,410 --> 00:15:03,590 +البوروكية و أصلحت لحوالها على أساس العلم العصري و + +183 +00:15:03,590 --> 00:15:08,850 +طبقت ذلك عملية كاملة حيث أخد علي ابنتي و مربيتي و + +184 +00:15:08,850 --> 00:15:12,730 +فرنسية و إبليسية و ماتت سكت القلبية سكت القلبية + +185 +00:15:12,730 --> 00:15:20,810 +ولا القلبية؟ هي مكتوبة القلبية يعني لا القلبية ولا + +186 +00:15:20,810 --> 00:15:27,620 +القلبية مقبولة منك ولا مقبولة؟هتبقى عايزة تبقى + +187 +00:15:27,620 --> 00:15:29,740 +عايزة تبقى عايزة تبقى عايزة تبقى عايزة تبقى عايزة + +188 +00:15:29,740 --> 00:15:34,160 +تبقى عايزة تبقى عايزة تبقى عايزة تبقى عايزة تبقى + +189 +00:15:34,160 --> 00:15:34,320 +عايزة تبقى عايزة تبقى عايزة تبقى عايزة تبقى عايزة + +190 +00:15:34,320 --> 00:15:34,320 +تبقى عايزة تبقى عايزة تبقى عايزة تبقى عايزة تبقى + +191 +00:15:34,320 --> 00:15:37,440 +عايزة تبقى عايزة تبقى عايزة تبقى عايزة تبقى عايزة + +192 +00:15:37,440 --> 00:15:44,320 +تبقى عايزة تبقى عايزة تبقى + +193 +00:15:44,320 --> 00:15:48,720 +عايزة + +194 +00:15:48,720 --> 00:15:52,280 +تبقى عايز + +195 +00:15:53,770 --> 00:15:56,710 +احنا برضه الهدف كمان اننا نفرفشك عشان صح صح معاك + +196 +00:15:56,710 --> 00:16:01,910 +طيب + +197 +00:16:01,910 --> 00:16:04,410 +و انا كون ازعلت انت اهم حاجة الله يرضى عليك احنا + +198 +00:16:04,410 --> 00:16:09,270 +اه نعم + +199 +00:16:09,270 --> 00:16:13,740 +ازعلت عليه هو ولا ايه ايش بتقوليعامل عامل عامل + +200 +00:16:13,740 --> 00:16:17,040 +عامل عامل عامل عامل عامل عامل عامل عامل عامل عامل + +201 +00:16:17,040 --> 00:16:17,260 +عامل عامل عامل عامل عامل عامل عامل عامل عامل عامل + +202 +00:16:17,260 --> 00:16:22,380 +عامل عامل عامل عامل عامل عامل عامل عامل عامل عامل + +203 +00:16:22,380 --> 00:16:27,680 +عامل عامل عامل عامل عامل عامل عامل عامل عامل عامل + +204 +00:16:27,680 --> 00:16:27,680 +عامل عامل عامل عامل عامل عامل عامل عامل عامل عامل + +205 +00:16:27,680 --> 00:16:27,680 +عامل عامل عامل عامل عامل عامل عامل عامل عامل عامل + +206 +00:16:27,680 --> 00:16:30,240 +عامل عامل عامل عامل عامل عامل عامل عامل عامل عامل + +207 +00:16:30,240 --> 00:16:35,560 +عامل + +208 +00:16:35,560 --> 00:16:42,300 +عاممن هون وحتى في خاتمته واللي عياذه بالله مات وهو + +209 +00:16:42,300 --> 00:16:51,020 +يحضر حفل لبنات وطالبات رومانيات في نادى المدارس + +210 +00:16:51,020 --> 00:16:56,060 +العليا وهو يقدم هؤلاء الفتيات او الطالبات في هذا + +211 +00:16:56,060 --> 00:17:01,960 +الحفل اللى كان يحضره ومات فيههذا الحفل والحديث + +212 +00:17:01,960 --> 00:17:06,520 +يقول يعني يبعث المرء على ما مات عليه يعني هذه + +213 +00:17:06,520 --> 00:17:11,380 +نهاية .. من يقبل نهاية مثل هذه هي النهايةهذا + +214 +00:17:11,380 --> 00:17:16,440 +الكلام يا أخوات يعني بهذا الكلام ننتهي من أثار + +215 +00:17:16,440 --> 00:17:19,760 +العلمانية في الأفراد واخدنا منها ثلاث نماذج نموذج + +216 +00:17:19,760 --> 00:17:24,880 +من تركيا مصطفى كبال أتاتورك ونموذجين من مصر طه + +217 +00:17:24,880 --> 00:17:32,760 +حسين وقاسم أمين أما عن أثار العلمانية في المجتمع + +218 +00:17:32,760 --> 00:17:41,150 +وفي الأخلاق فهذه أيضا تستحقوا الوقوف عندهافدائما + +219 +00:17:41,150 --> 00:17:44,870 +الحديث برضه عن المرأة في العلمانية والعلمانيين + +220 +00:17:44,870 --> 00:17:52,770 +استخدموا المرأة كسلاح لنشر مبادئهم وافكارهم وفي + +221 +00:17:52,770 --> 00:17:56,190 +هذه المعركة التي يتخذونها ضد الإسلام فدائما + +222 +00:17:56,190 --> 00:18:02,250 +يتمسحون بحقوق المرأة ويظهرون أنهم مدافعون عن + +223 +00:18:02,250 --> 00:18:06,830 +المرأة وكأن الإسلام هكذا يريدون أن يصوروا ظلم + +224 +00:18:06,830 --> 00:18:13,340 +المرأةوهم يريدون أن يعدلوا معاها ويعطوها حقوقها + +225 +00:18:13,340 --> 00:18:20,240 +وينشلونها من هذا الظلم الذي أوقعه عليها الإسلام + +226 +00:18:20,240 --> 00:18:24,820 +هكذا يعني كانوا يصورون المرأة في الإسلام وهكذا + +227 +00:18:24,820 --> 00:18:29,800 +يصورون ويسوقون أنفسهم ففي المجتمع وفي الأخلاق + +228 +00:18:29,800 --> 00:18:35,640 +دائما كانت المرأة حاضرة كسلاحولكنهم استخدموها + +229 +00:18:35,640 --> 00:18:43,500 +وللأسف كسلعة رخيصة لإهانتها وإهانة شرفها وعفتها + +230 +00:18:43,500 --> 00:18:50,260 +فماذا حدث في العلمانية وأثارها في المجتمع وفي + +231 +00:18:50,260 --> 00:18:56,220 +الأخلاق؟ ماذا فعل العلمانيون في البلاد التي سيطروا + +232 +00:18:56,220 --> 00:19:00,900 +عليها وتحكموا فيها وهي معظم وأغلب بلدان العربية + +233 +00:19:00,900 --> 00:19:02,500 +والإسلاميين؟ + +234 +00:19:08,050 --> 00:19:12,730 +بارك الله فيك، هذا ما جنينه منه، تشرت الإباحية + +235 +00:19:12,730 --> 00:19:19,050 +والفوضى والرذيلة وعدم الأخلاق في مجتمعاتنا + +236 +00:19:19,050 --> 00:19:25,470 +الإسلامية، اتنين، تفضلي نعم + +237 +00:19:25,470 --> 00:19:31,020 +يعني معناه يعني غيرمحجبة غير ملتزمة بالفريضة + +238 +00:19:31,020 --> 00:19:37,140 +الشرعية الحجاب بل أظهرت مفاتنها وخرجت متبرجة + +239 +00:19:37,140 --> 00:19:41,740 +وسافرة ورأينا ذلك ونرى ذلك و لازلنا نرى ذلك وإن + +240 +00:19:41,740 --> 00:19:45,580 +كان الوضع اليوم في المجتمعات الإسلامية أفضل وفي + +241 +00:19:45,580 --> 00:19:50,140 +أحسن حال مما كان عليه سابقا حيث كان من النادر ما + +242 +00:19:50,140 --> 00:19:54,160 +نجت قديما امرأة محجبة الآن من النادر والحمد لله أو + +243 +00:19:54,160 --> 00:19:58,430 +القليلالقليل ما تكون المرأة المسلمة في المجتمعات + +244 +00:19:58,430 --> 00:20:02,930 +المسلمة غير محجبة يعني صار والحمد لله العكس هو + +245 +00:20:02,930 --> 00:20:09,250 +الصحيح وهذا يعني يبشر بالخير والأمل والتفاؤل بأن + +246 +00:20:09,250 --> 00:20:13,470 +المستقبل لهذا الدين والنصر للإسلام تفضل يا أختي + +247 +00:20:13,470 --> 00:20:15,010 +تلاتة؟ + +248 +00:20:19,910 --> 00:20:23,250 +برك الله فيك و هذا هو الواقع المشهود في مجتمعات + +249 +00:20:23,250 --> 00:20:28,850 +انه في كثير من بلداننا الإسلامية في اختلاط في + +250 +00:20:28,850 --> 00:20:31,950 +المدارس في الجامعات في الكليات في كذا .. كذا حتى + +251 +00:20:31,950 --> 00:20:37,050 +في غزة الحبيبة و احنا بين يعني نحافظ على عدم + +252 +00:20:37,050 --> 00:20:39,850 +الاختلاط و الفصل في الجامعة الإسلامية و معروف + +253 +00:20:39,850 --> 00:20:43,090 +الاتجاه الإسلامي و الصحوة الإسلامية هناك بعض + +254 +00:20:43,090 --> 00:20:46,410 +المدارس لازالت فيها بعض الاختلاطات و هناك بعض + +255 +00:20:46,410 --> 00:20:51,960 +الجامعات او الكليات و ان كانت قليلةيعني فيها يحدث + +256 +00:20:51,960 --> 00:20:56,120 +بعض الإختلاطات هنا و هناك إلا في هذه الجامعة + +257 +00:20:56,120 --> 00:21:00,660 +الحبيبة العزيزة الجامعة الإسلامية بقيت وحارسة على + +258 +00:21:00,660 --> 00:21:12,620 +عدم الإختلاط يعني دائما أيضا أربعة ناخد من الشجاعة + +259 +00:21:12,620 --> 00:21:14,300 +كلها يعني شاركونا لجميع تفضل يا أختي + +260 +00:21:17,930 --> 00:21:23,630 +بارك الله فيكي و هل يعني الخمر أمر عادي في مجتمع + +261 +00:21:23,630 --> 00:21:27,650 +مسلم ولا هو من الكبائر بل أم الكبائر و أم الخبائث + +262 +00:21:27,650 --> 00:21:33,190 +و الخمر معروفة يعني من كبائر الذنوب أصبح أمران + +263 +00:21:33,190 --> 00:21:39,670 +عاديا و أطلق عليها أسماء حتى ليست معتادة كانت زمان + +264 +00:21:39,670 --> 00:21:43,110 +الخمور و الخمر يعني هذه الكلمة لحالة بتظن الآن + +265 +00:21:43,110 --> 00:21:47,720 +مشروباتروحي تحت اسم مشروبات و روحية حتى يسويقون .. + +266 +00:21:47,720 --> 00:21:52,700 +حتى يسويقوا هذه المشروبات أو هذه الخمور كذلك .. + +267 +00:21:52,700 --> 00:21:58,900 +تفضل يا عزيزيوهذا الكلام ما كان في مجتمع مسلم ولا + +268 +00:21:58,900 --> 00:22:02,080 +في دولة إسلامية وإنما كله أفكار غربية وجاءت إلى + +269 +00:22:02,080 --> 00:22:07,080 +بلادنا الإسلامية وصار هناك الراقصين والراقصات + +270 +00:22:07,080 --> 00:22:13,460 +الأحيائي منهم والأموات لأن في منهم يعني من بقى حيا + +271 +00:22:13,460 --> 00:22:20,620 +وفي منهم من مات ستة فضل يا عزيزي عرفت أن المسلمين + +272 +00:22:20,620 --> 00:22:25,920 +أولاد الصينة ودول من قطة أجتماع الإسرائيلوهذه من + +273 +00:22:25,920 --> 00:22:30,060 +أخطر القضايا التي يعاني منها المجتمع الغربي اليوم + +274 +00:22:30,060 --> 00:22:35,560 +صدروا لنا هذه المعاناة بهذه الرذيلة وهذه الفاحشة + +275 +00:22:35,560 --> 00:22:41,360 +والدعوة إلى الإختلاط وقلة الحياة مما أدى إلى هذه + +276 +00:22:41,360 --> 00:22:43,000 +المفاسد كلها + +277 +00:22:47,240 --> 00:22:51,300 +الزناد والدور اللقطاء المعروف بالمبرات اليوم هذه + +278 +00:22:51,300 --> 00:22:54,600 +المرأة التي تفعل فعلتها أو مع الرجل ثم تلقي بولدها + +279 +00:22:54,600 --> 00:22:59,720 +في الشارع أو قرب من اعزكم الله مجمع للقمامة او + +280 +00:22:59,720 --> 00:23:05,200 +امام مستشفى اوفهذا من ما يندى له الجبين ونحن في + +281 +00:23:05,200 --> 00:23:09,200 +مجتمع صغير وفي المجتمعات الكبيرة الإسلامية موجود + +282 +00:23:09,200 --> 00:23:13,800 +هذا بكثرة وحالات الإجهاد وكذا .. هذا كله من أثار + +283 +00:23:13,800 --> 00:23:18,180 +هذه الفاحشة التي صدق الله تعالى فيها حين يقول + +284 +00:23:18,180 --> 00:23:23,140 +وَلَا تَقْرَبُ الذِّنَا إِنَّهُ كَانَ فَاحِشَةً + +285 +00:23:23,140 --> 00:23:30,560 +وَسَاءَ سَبِيلًا سبيل وطريق هذه الفاحشة سيء مدمر + +286 +00:23:31,740 --> 00:23:35,520 +وقد عانى منه الغرب ولا يزال يعانى وصدروا الى + +287 +00:23:35,520 --> 00:23:40,380 +مجتمعنا الإسلامية وللأسف وبدت هذه المعاناة واضحة + +288 +00:23:40,380 --> 00:23:47,060 +فيها أيضا العلمانية أثار في الحياة السياسية وفي + +289 +00:23:47,060 --> 00:23:52,050 +الحكم وفي الدولة كمايعني لها في المجتمع وفي + +290 +00:23:52,050 --> 00:23:56,950 +الأخلاق كما السلف أيضًا لها في السياسة والحكم + +291 +00:23:56,950 --> 00:24:01,870 +وهناك أيضًا نقاط عديدة يمكن رصدها في هذا الجانب + +292 +00:24:01,870 --> 00:24:06,590 +وبعض كلام يعني قد سبق الحديث عنه فقد تم إقصاء + +293 +00:24:06,590 --> 00:24:11,570 +القرآن والشريعة الإسلامية عن الحكم وما عادت + +294 +00:24:11,570 --> 00:24:15,130 +الشريعة الإسلامية حاكمة والقوانين الشرعية هي + +295 +00:24:15,130 --> 00:24:22,000 +الحاكمة وبقيتالعقيدة الإسلامية أو الأحكام خاصة + +296 +00:24:22,000 --> 00:24:27,620 +بالمزيد صلاة وعبادة وفي الأحكام الشخصية كالزواج + +297 +00:24:27,620 --> 00:24:31,440 +والطلاق والميراث وفقط هكذا هي الإسلام مجموعة من + +298 +00:24:31,440 --> 00:24:35,560 +العبادات وأحكام خاصة متعلقة بالزواج والطلاق فيما + +299 +00:24:35,560 --> 00:24:39,880 +عدا ذلك لا علاقة له بالسياسة ولا بالتشريع ولا + +300 +00:24:39,880 --> 00:24:44,400 +بالحكم ولا بالحياة ولا بالاقتصاد ولا بالدولة ولا + +301 +00:24:44,400 --> 00:24:51,860 +شيء من ذلكمقابل اقصاء هذه الشريعة الإسلامية الغراء + +302 +00:24:51,860 --> 00:24:55,680 +تم ايه؟ استيراد القوانين الوضعية عن الكفار تم + +303 +00:24:55,680 --> 00:25:00,340 +استبدال هذه الشريعة بقوانين وضعية بشرية مدنية + +304 +00:25:00,340 --> 00:25:09,180 +وضعها اناس بشر مثلنا مثلهم من الذي يعلم مصالح + +305 +00:25:09,180 --> 00:25:15,910 +الناس اكثرهم ولا خالقهم؟ خالقهم و لا يعلموا من خلق + +306 +00:25:15,910 --> 00:25:19,870 +و هو اللطيف الخبير قل أأنتم أعلم أم الله و الله + +307 +00:25:19,870 --> 00:25:24,470 +يعلموا و أنتم لا تعلمون أفحكم الجاهلية يبغون + +308 +00:25:24,470 --> 00:25:29,690 +يتحكموا إلى بعضهم البعض و إلى أحكام جاهلية ومن + +309 +00:25:29,690 --> 00:25:34,890 +أحسنوا من الله حكما لقوم يوقنون؟ لا أحد أحسن حكما + +310 +00:25:34,890 --> 00:25:40,970 +من حكم الله تعالىبعد ذلك أكتبر كل من يدعو إلى + +311 +00:25:40,970 --> 00:25:46,870 +العودة إلى الحكم بما أنزل الله درجه ومتخلف ويرجع + +312 +00:25:46,870 --> 00:25:50,670 +إلى العصور القديمة وإحنا في العصر الحديث وإحنا في + +313 +00:25:50,670 --> 00:25:55,110 +القرن العشرين وإحنا في التطور وإحنا في التقدم وهذا + +314 +00:25:55,110 --> 00:25:59,710 +يريد أن يدعونا إلى التراجع والتقهر وهكذا يوصف من + +315 +00:25:59,710 --> 00:26:03,530 +يريد أو من يدعو إلى تطبيق حكم الله وشرع الله + +316 +00:26:03,530 --> 00:26:09,280 +وشريعة الله في الأرضواستبدلوا بالحكم الإسلامي + +317 +00:26:09,280 --> 00:26:13,660 +والشرع الإسلامي ومبدأ الشورى بين المسلمين وهذه + +318 +00:26:13,660 --> 00:26:18,280 +المبادئ العظيمة بما يُعرف بالديمقراطية التي يتشدق + +319 +00:26:18,280 --> 00:26:25,160 +بها العالم اليوم وهي في حياتهم سائرة ومستساقة فإذا + +320 +00:26:25,160 --> 00:26:30,080 +ما طبقت ديمقراطيتهم في مجتمعاتنا الإسلامية + +321 +00:26:30,080 --> 00:26:36,280 +والعربية وأفرزتمسلمين منتخبين فازوا وانتصروا في + +322 +00:26:36,280 --> 00:26:41,360 +هذه الانتخابات وكفروا بمبدأهم وكفروا بفكرهم + +323 +00:26:41,360 --> 00:26:48,340 +الديمقراطي وبدأوا يكيدون لمن يفوز اذا كان مسلما او + +324 +00:26:48,340 --> 00:26:51,320 +كانوا من المسلمين مش هذه ديمقراطيتكم مش هذه + +325 +00:26:51,320 --> 00:26:57,240 +وسيلتكم مش هذه مبدأكم نريد ان نطبقهم لانكم ترفضون + +326 +00:26:57,240 --> 00:27:04,600 +الأحزاب الإسلامية والجماعة الإسلاميةفو إذا ما فاز + +327 +00:27:04,600 --> 00:27:09,200 +المسلمون كما قلنا و عدوهم و نصبوهم العداء و كانوا + +328 +00:27:09,200 --> 00:27:13,900 +لهم بالمرصد كذلك + +329 +00:27:13,900 --> 00:27:17,500 +من + +330 +00:27:17,500 --> 00:27:21,840 +أثار هذه العلمانية في الحكم و السياسة اتفضلوا + +331 +00:27:21,840 --> 00:27:25,080 +مصدقة الوحدة الإسلامية اللتي كانت تجمع الشعوب + +332 +00:27:25,080 --> 00:27:28,540 +المسلمة فقسمت البلاد إلى دولات و صارت الواوبة + +333 +00:27:28,540 --> 00:27:33,770 +بجعلها القوة الدوليةبرك الله فيك وحسن يعني هذه من + +334 +00:27:33,770 --> 00:27:38,870 +أثارها في الحياة السياسية أين وحدتنا كمسلمين كنا + +335 +00:27:38,870 --> 00:27:43,350 +موحدين كانت تجمعنا دولة واحدة كبرى اسمها دولة + +336 +00:27:43,350 --> 00:27:47,990 +الخلافة الإسلامية اللي كان آخرها الخلافة العثمانية + +337 +00:27:47,990 --> 00:27:54,430 +التركية الآن في ظل العلمانية عفوا في السياسة وفي + +338 +00:27:54,430 --> 00:28:01,990 +الحكمانقسمت هذه الدول وضعفت هذه الوحدة وانقسمت + +339 +00:28:01,990 --> 00:28:07,130 +البلاد الإسلامية إلى دولات وأقطار ان دول بسيطة + +340 +00:28:07,130 --> 00:28:11,270 +صغيرة مستقلة وعملة حالها دولة وإلا حاكم وإلا ملك + +341 +00:28:11,270 --> 00:28:16,670 +وإلا أمير وإلا .. أين دولة الإسلام العظيمة الكبرى + +342 +00:28:16,670 --> 00:28:21,900 +والعالم اليوم كله يتجه إلى التوحدالولايات المتحدة + +343 +00:28:21,900 --> 00:28:27,600 +الأمريكية الاتحاد الأوروبي الأمم المتحدة كلهم + +344 +00:28:27,600 --> 00:28:34,340 +متحدة إلا أننا نتفكك ونقسم وحتى في الدولة الواحدة + +345 +00:28:34,340 --> 00:28:38,100 +أحيانا بعض القوميات كالأكرادي وغيرهم يريدون ان + +346 +00:28:38,100 --> 00:28:42,260 +يستقلوا عن الدولة التركية وغيرهم في مشاكل معروفة + +347 +00:28:42,260 --> 00:28:46,800 +وظاهرة وكذا جنوب السودان استقل عن السودان وكأنه + +348 +00:28:46,800 --> 00:28:49,870 +سودان سودانية وليس سودان واحدةيعني بدل أن العالم + +349 +00:28:49,870 --> 00:28:54,430 +يتوحد و احنا قاعدين نقسم وهذا كله سياسة استعمارية + +350 +00:28:54,430 --> 00:28:59,970 +واضحة للعيال، سياسة فرق تسوء، يعني في الدول الكبرى + +351 +00:28:59,970 --> 00:29:03,030 +كانت و الآن حتى في الدول الصغرة يعني أرادوا أن + +352 +00:29:03,030 --> 00:29:09,680 +يقسموا هذه الدول، هذا ما جنينهم من هؤلاءومن أثاري + +353 +00:29:09,680 --> 00:29:14,460 +عشان ننتهي من هذه القضية والنقطة أثار العلمانية في + +354 +00:29:14,460 --> 00:29:19,300 +بلاد المسلمين يعني هي تابعة لنفس الموضوع لأنه لما + +355 +00:29:19,300 --> 00:29:24,260 +نغادر الحديث عن الأثار السياسية في السياسة والحكم + +356 +00:29:24,260 --> 00:29:30,220 +من أثارها يا أخوات .. أه .. مين نذكر لنا؟ فضل يا + +357 +00:29:30,220 --> 00:29:30,580 +أخوة + +358 +00:29:45,150 --> 00:29:50,690 +بارك الله فيك يعني شايفين هذا التعدد أو الأسماء + +359 +00:29:50,690 --> 00:29:56,210 +المتعددة والمصطلحات يعني كلها بديلا عن الإسلام + +360 +00:29:56,210 --> 00:30:02,060 +والحكم الإسلامي والشرع الإسلاميهو سماكم المسلمين + +361 +00:30:02,060 --> 00:30:06,040 +ومن أحسن قولًا من من دع إلى الله وعمل صالحًا وقال + +362 +00:30:06,040 --> 00:30:11,600 +إنني من المسلمين فصاروا يخجلون أن يقولوا نحن + +363 +00:30:11,600 --> 00:30:15,900 +مسلمين والإسلام فبدأنا نقول الإسلام والمسلمين ونحن + +364 +00:30:15,900 --> 00:30:23,340 +مسلمين ومؤمنين الثورة والثوريين التقدميين هؤلاء + +365 +00:30:23,340 --> 00:30:27,990 +المسلمين الرجعيين هم تقدميون ونحن رجعيونيعني + +366 +00:30:27,990 --> 00:30:31,930 +العلمانيون والليبراليون والتقدميون وكل ما ندعو إلى + +367 +00:30:31,930 --> 00:30:36,570 +الإسلام أصبح إيه؟ رجعين .. رجعين ومتخلفا الأصوليون + +368 +00:30:36,570 --> 00:30:39,510 +.. كان الأصول يعني إيش بخور؟ اللذي يدعو إلى الرجوع + +369 +00:30:39,510 --> 00:30:43,410 +إلى الأصل وإلى الأصول وإلى .. لذا يعني أمر عايز .. + +370 +00:30:43,410 --> 00:30:47,410 +الأصوليون فصارت الكلمة هذه في ذاتها أمر يعني مخيف + +371 +00:30:47,410 --> 00:30:50,610 +.. هذا أصولي .. يعني أصولي يعني إرهابي .. يعني + +372 +00:30:50,610 --> 00:30:54,430 +إرهابي يعني ..فيوصف الإسلام بالأصولية و الإرهاب و + +373 +00:30:54,430 --> 00:30:58,350 +هكذا و هدول المسلمين معتدلين و هدول المسلمين + +374 +00:30:58,350 --> 00:31:04,130 +متطرفين و متشددين و إرهابيين و حتى الإسلام في ذاته + +375 +00:31:04,130 --> 00:31:07,310 +أصبح مقسما هنا و هنا هذا التقسيم و هذا التمييز و + +376 +00:31:07,310 --> 00:31:12,280 +هذه المصطلحات مقصودة لتشويه صورة الإسلاممسلمين + +377 +00:31:12,280 --> 00:31:14,720 +ومين هم المسلمين المعتدلين اللي لا بيقاوموا ولا + +378 +00:31:14,720 --> 00:31:17,620 +بيجاهدوا بيرضوا بالاحتلال و بالاستعمار و بتنغموا + +379 +00:31:17,620 --> 00:31:20,920 +معاه و بيعملوا معاه مفاوضات و سلام و بتنزلوله عن + +380 +00:31:20,920 --> 00:31:24,420 +الأرض ما شاء الله دول مسلمين معتدلين هدول اللي + +381 +00:31:24,420 --> 00:31:26,960 +احنا بدنا إياهم عايزين أما هدول اللي بيقاوموا و + +382 +00:31:26,960 --> 00:31:30,200 +بيجاهدوا و بدفعوا عن حقهم و بدهم حقهم يعود إليهم + +383 +00:31:30,200 --> 00:31:36,290 +إرهابيين و متطرفين و قتلواهكذا أصبح الحال في + +384 +00:31:36,290 --> 00:31:41,510 +العالم. هل ننتهي من هذه المقطة و المقطة السابعة و + +385 +00:31:41,510 --> 00:31:44,930 +الثامنة لكي ننتهي ان شاء الله؟ فضل الأخطر. تمظبت + +386 +00:31:44,930 --> 00:31:48,430 +الدم الإسلامية إلى أحزاب الشيعة تعطائد و أفكار + +387 +00:31:48,430 --> 00:31:52,440 +متناقضة أكتر من العادية لإسلامويعطي الولاء الإخبار + +388 +00:31:52,440 --> 00:31:57,920 +قال تعالى يا أيها الذين آمنوا لا تتخدوا .. لا + +389 +00:31:57,920 --> 00:32:05,500 +تتخدوا اليهود والنصارى أولياء بعضهم أولياء بعض ومن + +390 +00:32:05,500 --> 00:32:11,100 +يتولهم منهم فإنه منهم .. الله أفتى عليك وبرك الله + +391 +00:32:11,100 --> 00:32:16,010 +فيك أحسنتيعني هذا قبل قليل ذكرنا الإنقسام اللي + +392 +00:32:16,010 --> 00:32:20,210 +حاصل يعني في الدول الكبرى، الآن في الدولة الواحدة + +393 +00:32:20,210 --> 00:32:23,750 +أصلا صار في أحزاب و في جامعات و في كذا و في أفكار + +394 +00:32:23,750 --> 00:32:30,670 +في دولة واحدةيعني بعد الحديث عن تفرق الدولة + +395 +00:32:30,670 --> 00:32:33,970 +الإسلامية و الخلافة الإسلامية إلى دول و إلى كده + +396 +00:32:33,970 --> 00:32:37,570 +أصبح في الدولة الواحدة مش فكر واحد مش اتجاه واحد + +397 +00:32:37,570 --> 00:32:42,630 +أفكار و أحزاب و إلى آخرى نقطة ثامنة الأخيرة من + +398 +00:32:42,630 --> 00:32:46,310 +أثار العلمانية في بلاد المسلمين .. مين من الأخوات + +399 +00:32:46,310 --> 00:32:47,470 +ما اتكلمتش؟ + +400 +00:32:53,500 --> 00:32:59,560 +أبعد الجيل المسلم عن منهج الله جراء هذه العلمانية + +401 +00:32:59,560 --> 00:33:04,710 +التي تفصل وتعزل وتقصي الدين عن السياسة والحكمومن + +402 +00:33:04,710 --> 00:33:12,090 +قبل عن المجتمع والأخلاق فهذه أثار العلمانية أنه + +403 +00:33:12,090 --> 00:33:16,650 +أصبحت الدعوة بدل إلى الإسلام إلى القوميات + +404 +00:33:16,650 --> 00:33:21,090 +والوطنيات وإلى الحضارات القديمة كالفرعونية + +405 +00:33:21,090 --> 00:33:26,530 +والفينيقية والارامية وغيرها بديلا عن الإسلام ودين + +406 +00:33:26,530 --> 00:33:30,630 +الإسلام ودعوةالإسلام في المحاضرة القادمة ان شاء + +407 +00:33:30,630 --> 00:33:34,210 +الله يعني سنتهي من الحديث عن العلمانية بالحديث عن + +408 +00:33:34,210 --> 00:33:38,350 +موقف الإسلام من العلمانية وحكم الإسلام في + +409 +00:33:38,350 --> 00:33:41,710 +العلمانية ان شاء الله تعالى الله يعطيكوا العفو + diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/ZwCfwTR5ySU_raw.json b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/ZwCfwTR5ySU_raw.json new file mode 100644 index 0000000000000000000000000000000000000000..6f865b4ac55651ea2187781dc65b8da3c4a22041 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/ZwCfwTR5ySU_raw.json @@ -0,0 +1 @@ +{"segments": [{"id": 1, "seek": 4625, "start": 20.97, "end": 46.25, "text": "الحمد لله يا رب العالمين والصلاة والسلام على أشرف الخلق وسيد المرسلين وسيدنا محمد وعلى آله وصحته أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت العلم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما علمتنا وزدنا علمة آمين يا رب العالمين أما بعد", "tokens": [6027, 35571, 3215, 24976, 3224, 35186, 12602, 3555, 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وفساد عقائده ونقصد به الدين النصراني نحن نتحدث عن النصرانية والعقيدة النصرانية وفساد العقيدة النصرانية حيث غير النصارى ورجاله الدين ورجاله الكنيسة وبدلوا وحرفوا في نصوص الكتاب المقدس عندهم عرف بالإنجيل", "tokens": [2655, 5016, 16572, 5172, 32748, 9957, 4032, 36178, 18513, 6225, 4587, 16373, 3215, 3224, 4032, 1863, 4587, 9381, 3215, 39627, 32748, 9957, 28239, 9381, 2288, 7649, 1829, 8717, 5016, 1863, 8717, 2655, 24401, 12984, 18871, 28239, 9381, 2288, 7649, 10632, 16070, 3615, 4587, 25708, 3660, 28239, 9381, 2288, 7649, 10632, 4032, 36178, 18513, 18863, 4587, 25708, 3660, 28239, 9381, 2288, 7649, 10632, 11331, 1829, 12984, 32771, 13546, 28239, 9381, 9640, 7578, 4032, 47341, 6027, 3224, 32748, 9957, 4032, 47341, 6027, 3224, 2423, 19452, 1829, 3794, 3660, 4032, 44510, 1211, 14407, 4032, 5016, 28480, 14407, 8978, 8717, 9381, 2407, 9381, 33251, 2655, 16758, 9673, 28543, 3794, 43242, 16095, 6225, 28480, 20666, 28814, 1863, 7435, 26895], "avg_logprob": -0.12697011180545972, 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وهي عقيدة التوحيد فبدل التوحيد ظهر التثليث القول بأن الله ثالث ثلاث لقد كفر الذين قالوا أن الله ثالث ثلاث", "tokens": [2407, 10874, 16606, 14407, 45030, 4587, 16373, 3215, 3714, 9778, 6027, 5172, 3660, 5296, 15042, 25961, 2655, 47356, 18863, 4587, 25708, 3660, 16247, 36520, 10632, 31767, 5016, 1829, 5016, 3660, 21136, 20292, 46007, 38392, 10874, 16606, 4724, 11296, 6225, 1829, 3794, 7578, 47356, 21136, 37440, 37037, 1829, 6225, 4587, 25708, 3660, 16712, 2407, 5016, 25708, 6156, 44510, 1211, 16712, 2407, 5016, 25708, 1357, 116, 3224, 2288, 16712, 12984, 20292, 12984, 25062, 12610, 4724, 33456, 21984, 38637, 6027, 12984, 38637, 1211, 5718, 104, 5296, 28543, 9122, 5172, 2288, 32545, 9957, 50239, 14407, 14739, 21984, 38637, 6027, 12984, 38637, 1211, 5718, 104], "avg_logprob": -0.09189356524165314, "compression_ratio": 2.0555555555555554, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 254.61, "end": 255.07, "word": "و", "probability": 0.505859375}, {"start": 255.07, "end": 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"duration_after_vad": 2515.944999999994} \ No newline at end of file diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/flwTkik4jL0_raw.srt b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/flwTkik4jL0_raw.srt new file mode 100644 index 0000000000000000000000000000000000000000..033239f4422836eaa3f4c90864cfc43f9eb796c6 --- /dev/null +++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/flwTkik4jL0_raw.srt @@ -0,0 +1,1844 @@ +1 +00:00:20,890 --> 00:00:24,290 +الحمد لله يا رب العالمين والصلاة والسلام على أشرف + +2 +00:00:24,290 --> 00:00:29,830 +الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحبه + +3 +00:00:29,830 --> 00:00:35,370 +أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت + +4 +00:00:35,370 --> 00:00:41,210 +العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما + +5 +00:00:41,210 --> 00:00:47,480 +علمتنا وزدنا علمة آمين يا رب العالمين أما بعدفقد + +6 +00:00:47,480 --> 00:00:50,200 +كان الحديث يا أخوات في المحاضرة الماضية حول + +7 +00:00:50,200 --> 00:00:54,940 +التغريب والأسباب التي أدت إلى تغريب كثير من + +8 +00:00:54,940 --> 00:01:00,620 +المسلمين ثم تطرقنا في نهاية المحاضرة إلى الحديث عن + +9 +00:01:00,620 --> 00:01:06,260 +مواقف المسلمين المختلفة تجاه ما يسمى بالحضارة + +10 +00:01:06,260 --> 00:01:13,710 +الغربيةوعرفنا أن هناك مواقف متعددة ومختلفة تجاه + +11 +00:01:13,710 --> 00:01:21,600 +التعامل مع هذه الحضارة المسمى بالحضارة الغربيةفمن + +12 +00:01:21,600 --> 00:01:26,560 +تذكرنا بهذه المواقف بإننا نتذكرها معاً بدأنا + +13 +00:01:26,560 --> 00:01:30,900 +الحديث يعني عن بعض هذه المواقف الموقف الأول + +14 +00:01:30,900 --> 00:01:34,980 +والثاني والثالث وتوقفنا عند الموقف الرابع حاول + +15 +00:01:34,980 --> 00:01:40,560 +نستذكر هذه المواقف الأربع فقط نذكرها ذكرا ثم نكمل + +16 +00:01:40,560 --> 00:01:46,950 +الحديث عن الموقف الرابع الذي توقفنا عندهمين ذاكر + +17 +00:01:46,950 --> 00:01:49,670 +ان الموقف الأول من الحضارة الموقف الأول هو الموقف + +18 +00:01:49,670 --> 00:01:55,870 +السلبي يقف أمام الحضارة الغربية يرافض كل ما يتعلق + +19 +00:01:55,870 --> 00:01:59,950 +بيها وعدم الأخذ بأي أسلوب مهم بارك الله فيك، لذا + +20 +00:01:59,950 --> 00:02:04,630 +الموقف الأول هو الموقف الرافض لهذه الحضارة الموقف + +21 +00:02:04,630 --> 00:02:08,650 +السلبي الرافض الموقف الثاني هتدعو إلى الانفتاح + +22 +00:02:08,650 --> 00:02:13,640 +الكام حول الحضارة الغربيةالموقف الداعي إلى الأخذ + +23 +00:02:13,640 --> 00:02:19,540 +بكل معنى الحضارة من خير وشر وحلو ومر الموقف الثالث + +24 +00:02:19,540 --> 00:02:22,700 +الموقف + +25 +00:02:22,700 --> 00:02:30,300 +الذي اتجه إلى تطوير الإسلام بما يتناسب ويتوافق مع + +26 +00:02:30,300 --> 00:02:35,830 +الحضارة الغربية أو الثقافة الغربيةالموقف الرابع + +27 +00:02:35,830 --> 00:02:40,170 +والذي نحن اليوم بصدده وتوقفنا عنده هو الذي تمثل + +28 +00:02:40,170 --> 00:02:42,950 +فيه الدعوة إلى احتفاظ المسلمين بهوياتهم الإسلامية + +29 +00:02:42,950 --> 00:02:45,910 +وشخصيتهم المستقلة ودالك حسب القرآن الكريم والسنة + +30 +00:02:45,910 --> 00:02:52,110 +النبوية بارك الله فيه وقد أبدأنا رأينا في الأراء + +31 +00:02:52,110 --> 00:02:59,410 +الثلاثة أو المواقف الثلاثة السابقة الرأيالسلبي أو + +32 +00:02:59,410 --> 00:03:03,970 +الموقف السلبي من الحضارة ورفضنا هذا الموقف لأنه + +33 +00:03:03,970 --> 00:03:10,890 +يعني لا يعبر عن فهم حقيقي وصحيح للإسلام ومبادئ + +34 +00:03:10,890 --> 00:03:18,320 +الإسلام والموقف الثاني أيضاالذي يرتمى في أحضان + +35 +00:03:18,320 --> 00:03:23,900 +الحضارة الغربية كمان تكلمنا عنه ورفضناه لأنه لا + +36 +00:03:23,900 --> 00:03:29,380 +يميز بين الخير والشر في هذه الحضارة والموقف الثالث + +37 +00:03:29,380 --> 00:03:33,700 +الذي يريد أن يطوع الإسلام أو يطور الإسلام أو يلوي + +38 +00:03:33,700 --> 00:03:38,380 +أعناق النصوص أو يحرف بعض النصوص لتتوافق وتتنسجم + +39 +00:03:38,380 --> 00:03:44,220 +كمان هذا رأي ليس سديد وليس سليم وهو رأي يعني مجانب + +40 +00:03:44,220 --> 00:03:49,790 +للصواب والحقبدنا نتعرف على الاتجاه الرابع الذي + +41 +00:03:49,790 --> 00:03:55,550 +ذكرته الأخر والذي يتمثل في احتفاظ المسلمين بهويتهم + +42 +00:03:55,550 --> 00:04:02,670 +الإسلامية بشخصيتهم المستقلة المتميزة كنتم خير أمة + +43 +00:04:02,670 --> 00:04:08,050 +أخرجت للناس وكذلك جعلناكم أمة وسطة وإن هذه أمتكم + +44 +00:04:08,050 --> 00:04:16,560 +أمة واحدة فهذه الأمة هذه الجماعة هي متميزةومميزة + +45 +00:04:16,560 --> 00:04:21,160 +ولها شخصيتها المستقلة لا ترتمي في أحضان هؤلاء ولا + +46 +00:04:21,160 --> 00:04:28,340 +في أحضان هؤلاء وتأخذ بالوسط والاعتدال فهي تستفيد + +47 +00:04:28,340 --> 00:04:32,700 +من هذه الحضارة تتعامل معها تأخذ منها النافع + +48 +00:04:32,700 --> 00:04:39,490 +والمفيد وتأخذ منها ما لا يتعارض معهوياتها + +49 +00:04:39,490 --> 00:04:45,010 +الإسلامية وثقافتها الإسلامية كذلك كل شيء لا يتعارض + +50 +00:04:45,010 --> 00:04:51,150 +مع الإسلام والمبادئ الإسلامية لا مانع عند المسلمين + +51 +00:04:51,150 --> 00:04:59,390 +من الأخذ به يعني من أين كانوبالتالي هذا الموقف هو + +52 +00:04:59,390 --> 00:05:05,330 +موقف المواجهة لهذه الحضارة والتحدي لها لأن هذا + +53 +00:05:05,330 --> 00:05:10,230 +الموقف يعبر عن الحضارة الإسلامية الحقيقية نحن + +54 +00:05:10,230 --> 00:05:15,630 +أصحاب حضارة كان لنا حضارة عظيمة ولا زالت مبادئها + +55 +00:05:15,630 --> 00:05:23,410 +موجودة فلماذا ننخرط ونذوب ونرتمي في أحضان هؤلاء + +56 +00:05:23,410 --> 00:05:28,700 +الغرب ونتأثر بهمفهم بالنسبة لنا يعني نتعامل معاهم + +57 +00:05:28,700 --> 00:05:34,620 +كمادة خام نستفيدوا منها أو يستفادوا من هذه المادة + +58 +00:05:34,620 --> 00:05:44,640 +و نتفحص ما عندهم و ننقض و نختار في النهاية ما هو + +59 +00:05:44,640 --> 00:05:47,080 +في الصالح العام + +60 +00:05:49,760 --> 00:05:55,780 +و يحدو أصحاب الموقف في موقفهم هذا يحدوهم قول + +61 +00:05:55,780 --> 00:06:00,140 +الرسول صلى الله عليه وسلم الحكمة ضالة المؤمن أن + +62 +00:06:00,140 --> 00:06:05,120 +وجدها فهو أحق ناس بيها وقوله صلى الله عليه وسلم لا + +63 +00:06:05,120 --> 00:06:10,250 +يكن أحدكم إما معاهيتبع هؤلاء ويتبع هؤلاء ويسير مع + +64 +00:06:10,250 --> 00:06:15,170 +كل ناعب، لا يكن أحدكم إما اعتبع، تابع، منقال، لا + +65 +00:06:15,170 --> 00:06:18,910 +يكن أحدكم إما يقولوا أنا مع الناس، أحسن الناس + +66 +00:06:18,910 --> 00:06:23,630 +وأحسنت، وإن أساء، أساء، لأ ليس هكذا المسلم ولا + +67 +00:06:23,630 --> 00:06:28,200 +المسلمبل يرشدنا النبي صلى الله عليه وسلم إلى + +68 +00:06:28,200 --> 00:06:35,440 +الشخصية المستقلة والموقف المستقل ولكن وطنوا أنفسكم + +69 +00:06:35,440 --> 00:06:40,540 +لازم نوطن أنفسنا وطن أنفسنا وتكون لنا الشخصية + +70 +00:06:40,540 --> 00:06:45,950 +المتميزة المستقلة إن أحسن الناسأن تحسنوا إذا + +71 +00:06:45,950 --> 00:06:49,370 +بيحسنوا فأسير معهم في إحسانهم أو أعملهم بهذا + +72 +00:06:49,370 --> 00:06:54,490 +الإحسان وإن أساء هل أستمر معهم ما الموقف المطلوب + +73 +00:06:54,490 --> 00:07:00,870 +أن تجتنب إساءته وإذا بيسيئوا باتبعهمش بل أجتنب + +74 +00:07:00,870 --> 00:07:07,030 +إساءته هكذا المسلم وهكذا موقفه الصعب طيب من يمثل + +75 +00:07:07,030 --> 00:07:11,710 +هذا الاتجاه الرابع وهذا الموقف الرابع في العالم + +76 +00:07:11,710 --> 00:07:17,160 +الإسلامي؟هناك جماعات وحركات وهيئات وعلماء ومفكرون + +77 +00:07:17,160 --> 00:07:21,460 +وفي بلدان المسلمين المختلفة وعندي في بعض الأمثلة + +78 +00:07:21,460 --> 00:07:27,400 +والنماذج لهذه البلدان ولهذه الجماعات ولهذه الحركات + +79 +00:07:27,400 --> 00:07:32,340 +والهيئات فعندي مثال في الهند وفي باكستان وفي مصر + +80 +00:07:32,340 --> 00:07:36,920 +وفي الجزائر وفي أندوليسيا وفي تركيا بدنا نتعرف على + +81 +00:07:36,920 --> 00:07:43,040 +هذه الأمثلة ناخد مثال أو مثالينعلى أكثر من كل بلد + +82 +00:07:43,040 --> 00:07:47,500 +من هذه البلدان ففي الهند من يمثل هذا الاتجاه في + +83 +00:07:47,500 --> 00:07:53,420 +الهند عالم كبير من علماء المسلمين ومفكر اسلامي + +84 +00:07:53,420 --> 00:08:00,500 +عظيم اسمه ابو الحسن الندويوكان هو مؤسس ورئيس ما + +85 +00:08:00,500 --> 00:08:05,400 +يُعرف بندوة العلماء زي مجلس يعني أو رابطة .. رابطة + +86 +00:08:05,400 --> 00:08:09,460 +علماء .. ندوة العلماء أسسها فهو رئيسها ورئيس + +87 +00:08:09,460 --> 00:08:16,860 +مجلسها الأعلى في باكستانرجل عالم كبير ايضا نتعرف + +88 +00:08:16,860 --> 00:08:19,980 +على هذه الأعلام و الأسماء البارزة من أعلام + +89 +00:08:19,980 --> 00:08:23,680 +المسلمين و علمائهم فضل في باكستان جماعة إسلامية + +90 +00:08:23,680 --> 00:08:26,920 +مؤسسة أبو الأعلى المودودي اللذي ألف في نقض الحضارة + +91 +00:08:26,920 --> 00:08:30,720 +الغربية برك الله فيك ألف كتاب اسمه إيش نحن + +92 +00:08:30,720 --> 00:08:35,360 +والحضارة الغربية هذا الرجل اسمه أبو الأعلى + +93 +00:08:35,360 --> 00:08:40,200 +المودودي في باكستان أسس الجماعة الإسلامية التي ما + +94 +00:08:40,200 --> 00:08:45,100 +زالتموجودة إلى الآن ومنتشرة في باكستان وربما هي من + +95 +00:08:45,100 --> 00:08:49,220 +أكبر الجامعات الإسلامية العاملة على الساحة + +96 +00:08:49,220 --> 00:08:56,380 +الباكستانية في مصر وغيرها من البلدان يمثل هذه أو + +97 +00:08:56,380 --> 00:08:59,480 +هذا الموقف وهذا الاتجاه تفضل في مصر وغيرها من + +98 +00:08:59,480 --> 00:09:02,400 +البلدان العربية يمثل هذا الاتجاه حركة الإخوان + +99 +00:09:02,400 --> 00:09:06,590 +المسلمين التي أسسها حسن البنيبارك الله فيك فهذه + +100 +00:09:06,590 --> 00:09:10,410 +الحركة هي حركة عالمية يا أخوات حركة الإخوان + +101 +00:09:10,410 --> 00:09:16,010 +المسلمين عالمية بعالمية الإسلام منتشرة وممتدة في + +102 +00:09:16,010 --> 00:09:21,550 +كل البلدان العربية والإسلامية لما تسير عليه من + +103 +00:09:21,550 --> 00:09:28,310 +المنهج الإسلامي الأصيل الوسطي المعتدل الذي أراده + +104 +00:09:28,310 --> 00:09:32,160 +الله سبحانه وتعالى لهذهالأمة في الأيات اللي + +105 +00:09:32,160 --> 00:09:37,720 +ذكرناها قبل قليل وكذلك جعلناكم أمة وسطة لتكونوا + +106 +00:09:37,720 --> 00:09:42,400 +شهداء على الناس ويكون الرسول عليكم شهيدًا وهي حركة + +107 +00:09:42,400 --> 00:09:47,920 +إسلامية معاصرة يعني نشأت وتأسست وبدأت في القرن أو + +108 +00:09:47,920 --> 00:09:52,120 +بداية القرن العشرين بعد سقوط الخلافة الإسلامية + +109 +00:09:52,120 --> 00:09:58,240 +والذي أسسها الإمام الشهيد حسن البنة رحمه الله عليه + +110 +00:09:59,690 --> 00:10:05,730 +وبعد أوجاء طبعا يعني قادة موجودون في مصر وفي غيرها + +111 +00:10:05,730 --> 00:10:10,230 +والذي تعتبر يعني حركة المقاومة الإسلامية حماس + +112 +00:10:10,230 --> 00:10:16,010 +عندنا هنا في فلسطين امتداد لها والتي أسسها الشيخ + +113 +00:10:16,010 --> 00:10:23,130 +أحمد ياسين رحمه الله تعالى وجميع الشهداء في + +114 +00:10:23,130 --> 00:10:30,310 +الجزائر مين بيمثل هذا الموقف؟ تفضل يا أختيعبد + +115 +00:10:30,310 --> 00:10:34,630 +الحميد بن باديس والبشير الإبراهيمي نعم هذا البرك + +116 +00:10:34,630 --> 00:10:38,670 +الله فيك اسمين دولة علماء كبار من علماء المسلمين + +117 +00:10:38,670 --> 00:10:41,850 +عبد الحميد بن باديس والبشير الإبراهيمي وأسسوا + +118 +00:10:41,850 --> 00:10:46,970 +جمعية العلماء الجزائرين في إندونسيا في حركة اسمها + +119 +00:10:46,970 --> 00:10:53,590 +حركة مشومي حركة مشومي موجودة في إندونسيا أما في + +120 +00:10:53,590 --> 00:10:58,190 +تركيا الحركة .. اه يا أخواتي اللي هنا ناخد واحدة + +121 +00:10:58,190 --> 00:10:59,610 +من كل جهة + +122 +00:11:02,020 --> 00:11:06,680 +الحركة النورية التي أسسها سعيد النورسي طبعا نورية + +123 +00:11:06,680 --> 00:11:16,880 +نسبة إلى مؤسسة سعيد النورسي و أيضا يمثل هذا الموقف + +124 +00:11:16,880 --> 00:11:24,810 +و هذا الاتجاه حركة أخرىالجماعة التي أسسها وكوّنها + +125 +00:11:24,810 --> 00:11:29,110 +الأستاذ .. أستاذ يعني professor نجم الدين أردكان + +126 +00:11:29,110 --> 00:11:35,090 +والتي يعني خرجت أو تخرجت منها رجب طيب أردوكان رئيس + +127 +00:11:35,090 --> 00:11:41,630 +وزراء تركيا الحاليهو رئيس أحزب العدالة والتنمية + +128 +00:11:41,630 --> 00:11:47,470 +الذي فاز في تركيا أخيرا ويحكم الآن تركيا هذا الرجل + +129 +00:11:47,470 --> 00:11:54,150 +الذي له مواقفه العظيمة الواضحة القوية تجاه العالم + +130 +00:11:54,150 --> 00:12:01,390 +الإسلامي وبخاصة الشعب الفلسطيني واهل غزة ومواقفه + +131 +00:12:01,390 --> 00:12:06,850 +أشهر من أن تذكر ونتحدث عنه + +132 +00:12:10,940 --> 00:12:13,980 +بعد الحديث عن هذه المواقف المختلفة يا أخوات أربع + +133 +00:12:13,980 --> 00:12:19,280 +مواقف تعرفنا عليها للمسلمين من الحضارة الغربية + +134 +00:12:19,280 --> 00:12:26,440 +موقفسلبي، رافض بالكلية، موقف بالعكس ومباطل يدعو + +135 +00:12:26,440 --> 00:12:31,280 +إلى الارتماء في أحضان الحضارة والأخذ منها بكل ما + +136 +00:12:31,280 --> 00:12:36,600 +فيها موقف يدعو إلى تطوير وتطويع وتمييع الإسلام + +137 +00:12:36,600 --> 00:12:40,600 +ليتوافق وينسجن مع هذه الحضارة كأنها الأصل وانا + +138 +00:12:40,600 --> 00:12:45,640 +الفرع وابدنا نلتحق بهذا الأصل نحن الأصل الإسلام هو + +139 +00:12:45,640 --> 00:12:53,450 +الأصل وليس هم الأصلالموقف الرابع الأخير الذي يبرز + +140 +00:12:53,450 --> 00:12:58,870 +الشخصية الإسلامية الحقيقية والمتميزة طيب ما رأيكم + +141 +00:12:58,870 --> 00:13:04,650 +في هذه المواقف المتعددة؟ لو بدنا نرجح موقف أو + +142 +00:13:04,650 --> 00:13:14,150 +اتجاه أو رأي فماذا نرجح؟ مين مع الموقف الأول؟ موقف + +143 +00:13:14,150 --> 00:13:21,010 +التاني؟ موقف التالت؟موقف الرابع والباقي اللي مش + +144 +00:13:21,010 --> 00:13:28,090 +رافع مش معاهإذا يعني رأي الأغلبية هم مع الموقف + +145 +00:13:28,090 --> 00:13:32,810 +الرابع والاتجاه وانا اعتقد جازما حتى اللي مارفعوش + +146 +00:13:32,810 --> 00:13:38,170 +خجلا ولا كسلا هم مع هذا الموقف طب مين يرفض علشان + +147 +00:13:38,170 --> 00:13:42,770 +نأكد هذه الحقيقة؟ مين يرفض الموقف الرابع؟ مين ضده + +148 +00:13:42,770 --> 00:13:46,230 +يعني؟ من اللي مارفعوش؟ اللي رفعه معروفين طب و اللي + +149 +00:13:46,230 --> 00:13:50,370 +مارفعوش مين بترفض؟ اه يعني مارفعتش خجلا او كسلا + +150 +00:13:50,370 --> 00:13:54,690 +معناههذا الموقف هو الذي يعبر عن موقف الإسلام + +151 +00:13:54,690 --> 00:14:01,370 +العظيم نحن لنا شخصيتنا المميزة المستقلة و لا مانع + +152 +00:14:01,370 --> 00:14:08,430 +عندنا أن نأخذ بكل نافع و يفيدنا في حياتنا الدنيوي + +153 +00:14:08,430 --> 00:14:18,740 +تقل الآن إلى الحديث عنكيفية مواجهة التغريب في خطته + +154 +00:14:18,740 --> 00:14:24,280 +التي وضعها التغريب + +155 +00:14:24,280 --> 00:14:29,840 +لسيطرة على العالم الإسلامي وتحقيق أهدافه احنا + +156 +00:14:29,840 --> 00:14:36,580 +مقابل هذه الخطة كيف نواجه تلك الخطة نضع أيضا خطة + +157 +00:14:36,580 --> 00:14:42,620 +مواجهة لهافي عندنا بعض النقاط ممكن أن نستعين بها + +158 +00:14:42,620 --> 00:14:47,860 +ممكن أيضا نضيف عليها نجتهد فيها تفضل أختي الأمر + +159 +00:14:47,860 --> 00:14:52,160 +الأول معرفة أهداف أعدائنا ومخططاتهم العمل على تصدي + +160 +00:14:52,160 --> 00:14:55,720 +لها لأن كل ما يحدث من حول أنه هو بتخطيط وزردين من + +161 +00:14:55,720 --> 00:15:02,160 +القوة الغربية السودانية التي تهدف إلى عدم جعل راية + +162 +00:15:02,160 --> 00:15:05,200 +الإسلام ترتفع وبذلك يجب علينا أن نعرف تفتر مخططات + +163 +00:15:05,200 --> 00:15:10,630 +من أجلأحسنت وبرك الله في دائما في أي عمل يريد + +164 +00:15:10,630 --> 00:15:14,330 +الإنسان أن يقوم به، يريد أن يواجه، لابد أن يتعرف + +165 +00:15:14,980 --> 00:15:20,640 +على الخصم يعني معرفة العدو أمر هام في التعامل معاه + +166 +00:15:20,640 --> 00:15:25,520 +وفي مواجهته فبنعرف أهدافهم ومخططاتهم علشان نعرف + +167 +00:15:25,520 --> 00:15:30,660 +كيف نواجه إذا ما بنعرفاش فلن نعرف كيف سنواجه + +168 +00:15:30,660 --> 00:15:35,600 +فالمعرفة في البداية هي البداية الطبيعية هو الأولى + +169 +00:15:35,600 --> 00:15:40,660 +في هذه الخطة اتنين فتاة يا عزيزي تورة الاسم ممكن + +170 +00:15:40,660 --> 00:15:44,690 +نشيل فيها تورة الأداءوالامهات دور في حماية المجتمع + +171 +00:15:44,690 --> 00:15:49,390 +والشباب من التغريب بارك الله فيك و هذا دور يعني + +172 +00:15:49,390 --> 00:15:54,710 +مفروض علينا وواجب علينا ليس فقط في التغريب بل في + +173 +00:15:54,710 --> 00:16:00,410 +كل وقت وفي كل حين يا أيها الذين آمنوا قووا أنفسكم + +174 +00:16:00,410 --> 00:16:06,520 +وأهليكم نارا ووقود والناس والحجار في كل شيءفي + +175 +00:16:06,520 --> 00:16:10,640 +التربية والتعليم وفي الأخلاق وفي المتابعة + +176 +00:16:10,640 --> 00:16:17,120 +والمراقبة ونريد من الأسرة من الراعي لهذه الأسرة من + +177 +00:16:17,120 --> 00:16:23,240 +الأب من الأمالمسئولية الكاملة والأمانة التي + +178 +00:16:23,240 --> 00:16:27,760 +تحملوها في رعاية الأسرة ونحن نتحدث عن وضع خطة + +179 +00:16:27,760 --> 00:16:32,140 +لمواجهة التغريب لابد من تفعيل هذا الدور دور الأسرة + +180 +00:16:32,140 --> 00:16:37,300 +كلكم راعين وكلكم مسئولون عن رعية هذه الآية وهذا + +181 +00:16:37,300 --> 00:16:42,560 +الحديث هم عنوان هذا الأمر لابد من القيام بالدور + +182 +00:16:42,560 --> 00:16:44,560 +وبالواجب + +183 +00:16:46,240 --> 00:16:50,660 +تلاتة، فضلوا تقيام العلماء والدعاء والمتخصصين + +184 +00:16:50,660 --> 00:16:54,100 +الذابين بدورهم في دورية المذنبين بجريمبرك الله + +185 +00:16:54,100 --> 00:17:01,100 +فيك، هذا عمر برضه هام وضروري ومدائم، الأصل أن يكون + +186 +00:17:01,100 --> 00:17:04,940 +دائم، يعني في هذه الحالة وفي غيرها، أن يقوم + +187 +00:17:04,940 --> 00:17:13,280 +العلماء والدعاء بدورهم التوعوي والتعليمي والمصح + +188 +00:17:13,280 --> 00:17:19,820 +والإرشاد والتوجيه للأمة يعني بأكملههو عموما من خطر + +189 +00:17:19,820 --> 00:17:25,180 +التغريب وخطر الارتماء في أحضان الغرب وما عند الغرب + +190 +00:17:25,180 --> 00:17:31,160 +من مبادئ وقيم ومثل مخالفة في كثير منها لقيمنا + +191 +00:17:31,160 --> 00:17:37,240 +وأخلاقنا اربعة اتفضل + +192 +00:17:37,240 --> 00:17:40,380 +اقامت المؤتمرات والأدوات الاجتماعية المضادة التي + +193 +00:17:40,380 --> 00:17:44,130 +تكشف المؤتمرات المحليةبارك الله فيه، اذا هم من ضمن + +194 +00:17:44,130 --> 00:17:47,850 +خططهم قامت المؤتمرات والندوات وبيعملوا وارشات + +195 +00:17:47,850 --> 00:17:52,950 +عاملة عشان يخططوا كيف يعني يسيطرون على العالم + +196 +00:17:52,950 --> 00:17:58,330 +الإسلامي بأفكارهم ومبادئهم، احنا في المقابل بدنا + +197 +00:17:58,330 --> 00:18:03,230 +أيضا في الخطة المواجهة أن نقيم هذه المؤتمرات وتلك + +198 +00:18:03,230 --> 00:18:11,160 +الندوات حتى نكشف مؤامراتي خمسة، فضلإقامة جمعيات + +199 +00:18:11,160 --> 00:18:14,440 +المتخصصة لحماية الشباب المسلم تبحث في مشاكل وما + +200 +00:18:14,440 --> 00:18:18,000 +تقدم لها حلول مناسبة قائمة على ديننا وأخلاقنابارك + +201 +00:18:18,000 --> 00:18:21,460 +الله فيهم هم سواء أهل التغريب يا أخوات أو من قبل + +202 +00:18:21,460 --> 00:18:27,800 +لما تحدثنا عن التنصير والتبشير وكذلك الاستشراق لهم + +203 +00:18:27,800 --> 00:18:33,400 +مؤسساتهم ولهم كما تحدثنا في وسائل التبشير وسائل + +204 +00:18:33,400 --> 00:18:37,360 +الاستشراق وسائل التغريب كلها من وسائلهم إقامة + +205 +00:18:37,360 --> 00:18:43,560 +الأندية والنوادي والجمعيات إذا نحن في خطة المواجهة + +206 +00:18:43,560 --> 00:18:51,640 +بدنا نخلق البديل لأبناءنايعني الذكورا و اناثا في + +207 +00:18:51,640 --> 00:19:00,580 +حمايتهم من الذهاب الى هذه الأندية و هذه الجمعيات + +208 +00:19:00,580 --> 00:19:05,740 +بدل ان يذهبوا الى جمعيات هؤلاء و أنديتهم يكون لهم + +209 +00:19:05,740 --> 00:19:13,640 +جمعيات و أندية خاصة بالمسلمين ستة و أخيرا فضل لخط + +210 +00:19:13,640 --> 00:19:18,260 +الوقتتحتاج من واجهة لأبناء الغرب لدراساتها وفكوثها + +211 +00:19:18,260 --> 00:19:21,460 +ومؤتمرات اتخاذي البثاليين المناسبة، استقصالها أو + +212 +00:19:21,460 --> 00:19:25,180 +لأ المناطقين ومحدد الأفكار المهنيةبارك الله فيك، + +213 +00:19:25,180 --> 00:19:31,180 +إذا عملت دراسات وبحوث وغير المؤتمرات، هذه الأمور + +214 +00:19:31,180 --> 00:19:38,660 +تصب في هذه المصلحة وفي هذه الفائدة وهي خطة مواجهة + +215 +00:19:38,660 --> 00:19:45,500 +للتغريب اللي في ملخصها ومجملها تبنى على التوعية + +216 +00:19:46,170 --> 00:19:50,610 +التوعية الكاملة والكافية بخطر التغريب فإذا ما كان + +217 +00:19:50,610 --> 00:19:57,590 +هناك وعي تم وكافي فنستطيع أن نواجه هذا التغريب ان + +218 +00:19:57,590 --> 00:20:04,190 +شاء الله تعالى ننتقل + +219 +00:20:04,190 --> 00:20:11,490 +بعد الحديث عنالخطط المواجهة للتغريب إلى الحديث عن + +220 +00:20:11,490 --> 00:20:16,090 +وسائل التغريب فكل مرة كنا نأخذ الوسائل في وسائل + +221 +00:20:16,090 --> 00:20:21,990 +الغزو الفكري التبشير الاستشراق أخذنا أهداف وسائل + +222 +00:20:21,990 --> 00:20:26,760 +الآن في التغريب كذلكلأهل التغريب وسائل مختلفة + +223 +00:20:26,760 --> 00:20:31,600 +ومتنوعة ومتعددة وفي الكتاب يعني موجود أشياء كثيرة + +224 +00:20:31,600 --> 00:20:36,220 +ومقدمات احنا سنقتصر على ذكر هذه الوسائل في هذه + +225 +00:20:36,220 --> 00:20:40,020 +المقدمة ندخل بعد ذلك إلى الحديث عن هذه الوسائل + +226 +00:20:40,020 --> 00:20:45,840 +مباشرة فلو جمعنا هذه الوسائل المطلوبة مننا في + +227 +00:20:45,840 --> 00:20:51,200 +المقرر وفي المساقيعني هانلخصها بهذه العناوين + +228 +00:20:51,200 --> 00:20:58,560 +الأربعة وبهذه الوسائل الأربعة وأولها العلمانية وإن + +229 +00:20:58,560 --> 00:21:03,280 +هنعرف ليش علمانية الأخر واحدة القومية وفي معها + +230 +00:21:03,280 --> 00:21:14,350 +الوطنية ثلاثة المرأة حضراتكم فضلا أربعة والأولىتحت + +231 +00:21:14,350 --> 00:21:18,650 +عناوين أولا ثانيا ثالثا ورابعا العناوين هذه + +232 +00:21:18,650 --> 00:21:23,970 +الموجودة يعني هي هذه عناوين وسائل التغريب لا أدرك + +233 +00:21:23,970 --> 00:21:29,490 +إن كانت يمكن في أخت تسأل وأنا بتكلم زي اللي اسمعت + +234 +00:21:29,490 --> 00:21:33,070 +أحد الأخوات كانت رافعة أصبعه أقول لو سمحت في حد يا + +235 +00:21:33,070 --> 00:21:37,970 +أخوات كان بتسأل سؤال ونبدأ + +236 +00:21:37,970 --> 00:21:45,010 +الحديث مباشرة عن أولهذه الوسائل الأربع من وسائل + +237 +00:21:45,010 --> 00:21:52,190 +التغريب الوهية .. إيش اسمها؟ العلمانية بفتح العين + +238 +00:21:52,190 --> 00:21:57,410 +فسنرى بعد قليل أنها الأصح والأدق والأفصح وإن كانت + +239 +00:21:57,410 --> 00:22:04,110 +هي والعلمانية أصلا لإتنين ترجمة غير دقيقة كما + +240 +00:22:04,110 --> 00:22:09,030 +سنتعرف بعد قليل على ذلك في المعنى اللغوي + +241 +00:22:09,030 --> 00:22:14,690 +والاصطلاحي للعلمانيلو أردنا الحديث عن العلمانية + +242 +00:22:14,690 --> 00:22:19,630 +الآن هنتكلم عنها تعريفة لغة أصل الكلمة من وين + +243 +00:22:19,630 --> 00:22:24,790 +علمانية أو علمانية تشوف من أصح في اللغة و كذلك في + +244 +00:22:24,790 --> 00:22:28,890 +الاصطلاح ماذا يعني مصطلح العلمانية كوسيلة من وسائل + +245 +00:22:28,890 --> 00:22:33,840 +التغريد ونبدأ بالمعنى اللغويإذا أردت أن أكشف عن + +246 +00:22:33,840 --> 00:22:40,400 +هذه الكلمة وهذا المصطلح في المعاجم العربية اللغوية + +247 +00:22:40,400 --> 00:22:44,580 +القديمة هل سأجد هذه الكلمة؟ هل كانت هذه الكلمة + +248 +00:22:44,580 --> 00:22:49,100 +معروفة من زمان و منذ القدم متداولة و مستعملة لم + +249 +00:22:49,100 --> 00:22:55,620 +تكن معروفة في معجم عربي قديم أو حتى حديث يعني في + +250 +00:22:55,620 --> 00:23:03,310 +العصر الحديث إلاحينما أو أول من جاء بهذه الكلمة + +251 +00:23:03,310 --> 00:23:08,590 +وذكرها هو مين؟ المعجم الوسيط وذلك في سنة الف + +252 +00:23:08,590 --> 00:23:12,410 +وتسعمائة واحد وستين يعني في القرن الحالي القرن + +253 +00:23:12,410 --> 00:23:18,650 +العشرين يعني لسه هذه الكلمة جديدة حادثة وليست من + +254 +00:23:18,650 --> 00:23:25,150 +الكلمات القديمة اللي مستخدمة ومستعملة منذ القدروهي + +255 +00:23:25,150 --> 00:23:34,850 +منصوبة إلى العلم ولا إلى العلم صاحب المعجم الوسيط + +256 +00:23:34,850 --> 00:23:41,450 +قال العلمانية نسبة إلى العلم والعلم بمعنى العالم + +257 +00:23:41,450 --> 00:23:47,410 +علم والعلم يعني بمعنى واحد وليس نسبة إلى العلم + +258 +00:23:52,370 --> 00:23:58,110 +العالم الديني أو الكهنوتي يعني العالم الديني أو + +259 +00:23:58,110 --> 00:24:02,990 +الكهنوتي المقصود بيه يعني خلاف أو يعني العلماني + +260 +00:24:03,690 --> 00:24:06,450 +يعني هو الأن بعرفنا العلمانية لكن لما يقول وهو + +261 +00:24:06,450 --> 00:24:11,410 +خلاف الديني أو الكهانوتي أي العلماني أو العالم + +262 +00:24:11,410 --> 00:24:17,130 +الذي قصده هو خلاف يعني عكس الديني أو الكهانوتي + +263 +00:24:17,130 --> 00:24:21,970 +علماني يعني علماني عكس ديني أو كهانوتي فهذا رجل + +264 +00:24:21,970 --> 00:24:27,950 +دين أو ديني رجل كهانوتي مقابله رجل علماني يعني هي + +265 +00:24:27,950 --> 00:24:33,480 +اللذي يقصد صاحب المعجبفلما أقول علماني يعني غير + +266 +00:24:33,480 --> 00:24:39,620 +ملتزم بالدين غير مقترف بالدين لا ديني ممكن أن + +267 +00:24:39,620 --> 00:24:46,200 +نسميه بهذا المصطلح وهذا الآن كل الكلام حسب هذا + +268 +00:24:46,200 --> 00:24:50,940 +المعجم الوسيط كهنوتي يعني الدين ومن المعاجم + +269 +00:24:50,940 --> 00:24:54,480 +الحديثة أيضا غير المعجم الوسيط الذي ذكر لنا هذه + +270 +00:24:54,480 --> 00:25:05,220 +الكلمة وهذا المصطلحمعجم مين؟ اسمه معجم المعلم + +271 +00:25:05,220 --> 00:25:11,600 +البستاني وليس البستاتي في بعض النسخ حرف ت فيها + +272 +00:25:11,600 --> 00:25:17,040 +فانا رجعت الاصل والتسمية لهذا المعجم فوجدته يعني + +273 +00:25:17,040 --> 00:25:23,860 +المعلم البستاني لرجل نصراني اسمه بطرس البستاني + +274 +00:25:23,860 --> 00:25:29,200 +وكان يلقب هذا الرجل بالمعلميعني من شدة علمه في + +275 +00:25:29,200 --> 00:25:33,600 +مجال اللغة كان عالم لغوي يعني كبير معروف فلقب + +276 +00:25:33,600 --> 00:25:38,820 +بالمعلم لمكانته و درجاته الألمية في اللغة فألف هذا + +277 +00:25:38,820 --> 00:25:45,020 +المعجم فسمي باللقب الذي لقب به هذا الرجل المعلم و + +278 +00:25:45,020 --> 00:25:50,500 +بقى اسم العائلة يعني في هذا المعجمفصار معجم المعلم + +279 +00:25:50,500 --> 00:25:55,360 +البستاني الذي يهمنا ما جاء في هذا المعجم ليس هو + +280 +00:25:55,360 --> 00:25:58,800 +الإسم بالدرجة الأولى جاء في هذا المعجم اللي هو + +281 +00:25:58,800 --> 00:26:05,720 +المعلم البستاني أن كلمة العلماني معناها العامي + +282 +00:26:05,720 --> 00:26:09,320 +وليس العامي الذي لا يعرف القراءة ولا الكتابة أي + +283 +00:26:09,320 --> 00:26:16,680 +الذي ليس بإكليريكيهيك التسمية أو اللفظة اللي جاءت + +284 +00:26:16,680 --> 00:26:21,640 +وبالبحث عن كلمة إكليريكي وإكليريكية فوجدناها كلمة + +285 +00:26:21,640 --> 00:26:27,360 +يونانية الأصل بالإنقليزي ecleric وecleric معناه + +286 +00:26:27,360 --> 00:26:34,860 +يعني عندهم نص في الإنجيل يعني الذي أخذ نصيبا من + +287 +00:26:34,860 --> 00:26:40,860 +الرب، هذا نصيب الربوبالتالي يعني هذا اللذي متدين + +288 +00:26:40,860 --> 00:26:49,000 +أخذ نصيب من الرب أخذ حظ أخذ كذا حظوة وبالتالي يعني + +289 +00:26:49,000 --> 00:26:56,060 +فيه مسحة من الدين يعني قريب من المتدين فالعلمان هو + +290 +00:26:56,060 --> 00:27:00,100 +الذي ليس ب eclerical يعني لا علاقة له ولا نصيبة له + +291 +00:27:00,100 --> 00:27:04,940 +من الدين كإنهي كبديهو لا نصيبة له من الإله من الرب + +292 +00:27:04,940 --> 00:27:10,200 +من الدينوهذا الذي يتحدث هذا الكلام راجل نصران + +293 +00:27:10,200 --> 00:27:14,980 +لأننا ناخد من نفس النصارى وتعريفهم فهم يفرقون هذه + +294 +00:27:14,980 --> 00:27:21,710 +التفرقة أيضا في معجمو أيضا صلحوا التسمية اسمه + +295 +00:27:21,710 --> 00:27:26,890 +المعجم مش معجم العربي والمعجم العربي الحديث اسمه + +296 +00:27:26,890 --> 00:27:32,410 +المعجم العربي الحديث لاروس وليس لارهوس بالها مافيش + +297 +00:27:32,410 --> 00:27:36,990 +لارهوس برضه لما بحثنا ورجعنا وجدنا اسمه الصحيح هو + +298 +00:27:36,990 --> 00:27:40,530 +لاروس يعني في بعض الأخطاء المطبعية أحيانا بتكون في + +299 +00:27:40,530 --> 00:27:46,090 +بعض النسخ للطبعفي المعجم العربي الحديث المعروف + +300 +00:27:46,090 --> 00:27:50,030 +بـLarus للدكتور خليل الجسر أيضًا جاء فيه نفس + +301 +00:27:50,030 --> 00:27:52,910 +المعنى أو قريب أن علماني ما + +302 +00:27:57,680 --> 00:28:03,840 +ما ليس كنسيا ولا دينيا إذا إيش موحظين في التلات + +303 +00:28:03,840 --> 00:28:08,920 +تعريفات في المعاجم المختلفة أن العلمان لا ديني ليس + +304 +00:28:08,920 --> 00:28:13,100 +دينيا لا علاقة له بالدين لا نصيبة له من الدين يعني + +305 +00:28:13,100 --> 00:28:18,580 +كل مقابل الديني كما قال الكهنوتي الكنسي المقابل له + +306 +00:28:18,580 --> 00:28:24,410 +العلمانو أيضا في معجة من آخر ألفه الياس بوكتور + +307 +00:28:24,410 --> 00:28:30,090 +برضه أسراني آخر جاءت ترجمة كلمة Lake Eau اللي هي + +308 +00:28:30,090 --> 00:28:38,810 +فرنسية الأصل يقول فيها والعلمانية ترجمة غير دقيقة + +309 +00:28:38,810 --> 00:28:47,570 +بل غير صحيحة لكلمة secularism يعني وكأنه أصل + +310 +00:28:47,570 --> 00:28:53,820 +الكلمة ومعناها secularismالكلمة باللغة الإنجليزية + +311 +00:28:53,820 --> 00:29:00,720 +أصل المصطلح كلمة علمانية كلمة المعربة لأنه لم يرد + +312 +00:29:00,720 --> 00:29:04,780 +لها أصل في اللغة العربية وهي معربة ومترجمة عن + +313 +00:29:04,780 --> 00:29:08,780 +مصطلح غربي أجنبي هذا المصطلح الغربي الأجنبي عند + +314 +00:29:08,780 --> 00:29:14,400 +أهله وأصحابه والذين قالوا به ماذا يسمى secularism + +315 +00:29:14,900 --> 00:29:18,180 +وهذه الكلمة وهذا المصطلح مطلوب مننا نحفظه في أربع + +316 +00:29:18,180 --> 00:29:25,040 +مصطلحات في أربع يعني قضايا سنتناولها بالحديث مطلوب + +317 +00:29:25,040 --> 00:29:28,740 +مننا نحفظ الأربع مصطلحات اللي هي العلمانية هنا + +318 +00:29:28,740 --> 00:29:34,730 +أولهاثم بعد ذلك القومية لأنه برضه أصلها غربي + +319 +00:29:34,730 --> 00:29:41,090 +والماسونية والعولمة الأربع في أصلهم ليست كلمات + +320 +00:29:41,090 --> 00:29:46,090 +يعني الفكر ليس فكر عربي وإنما عربي هذا الفكر هو + +321 +00:29:46,090 --> 00:29:51,350 +فكر غربي أجنبي ونحن نقلناه عندهم فالعلمانية عند + +322 +00:29:51,350 --> 00:29:56,590 +أهلها secularismو secularate بالفرنسية، احنا فقط + +323 +00:29:56,590 --> 00:30:02,130 +نقتصر على اللفظ والمصطلح الإنجليزي والsecularism + +324 +00:30:02,130 --> 00:30:09,930 +لا صيلة لها بلفظ العلمحتى يقال علمانية و نكسر + +325 +00:30:09,930 --> 00:30:15,250 +العين و ده سر يعني ان احنا بننصب العين ولا نكسر + +326 +00:30:15,250 --> 00:30:19,270 +يعني الكسر كان وصار تنسبة لمين؟ الى العلم و هي ليس + +327 +00:30:19,270 --> 00:30:22,650 +لها علاقة بالعلم secularism كلمة انجليزية مايلها + +328 +00:30:22,650 --> 00:30:26,550 +علاقة بالعلم ولا مشتقات العلم فلما نبحث عن العلم و + +329 +00:30:26,550 --> 00:30:30,790 +معناه في اللغة الإنجليزية معناه العلم scienceوهو + +330 +00:30:30,790 --> 00:30:33,830 +secularism و ال science يعني مالهاش علاقة و مش من + +331 +00:30:33,830 --> 00:30:37,650 +المشتقات و المذهب العلمي إذا بينا ننسب .. نقول + +332 +00:30:37,650 --> 00:30:42,950 +المذهب العلمي .. scientism و النسبة إلى العلم و + +333 +00:30:42,950 --> 00:30:49,030 +العلمي scientific إذا مايلها علاقة ب secularism و + +334 +00:30:49,030 --> 00:30:54,630 +secularismمصطلح خاص بالكلمة اللي قبل قليل عرفها + +335 +00:30:54,630 --> 00:30:59,930 +أكتر من واحد في المعاجم اللغوية اللي هي لا ديني + +336 +00:30:59,930 --> 00:31:04,510 +وسنتعرف عليه في المعنى الاصطلاحي بعد قليل ولمّا + +337 +00:31:04,510 --> 00:31:11,670 +يقال علماني اللي هو زيادة الألف والنون هذه أيضا + +338 +00:31:11,670 --> 00:31:19,050 +غير قياسية في اللغة العربية يعني استخدامها مش مترد + +339 +00:31:19,840 --> 00:31:24,900 +مثل كلمة رباني نسبة إلى رب وروحاني أو روحاني نسبة + +340 +00:31:24,900 --> 00:31:29,200 +إلى روح ونفساني ونوراني وجسماني فعلى وزنها وعلى + +341 +00:31:29,200 --> 00:31:35,780 +شكلتها جيش علماني أو علماني طيب ما هي الترجمة اذا + +342 +00:31:35,780 --> 00:31:42,180 +الدقيقة والصحيحة لكلمة العلمانية هل هي العلمية + +343 +00:31:42,180 --> 00:31:47,910 +والعلم والعلمي واللماذا يعني سميت بهذه التسمية + +344 +00:31:47,910 --> 00:31:52,190 +التي توهم النسبة إلى العلم فلو أردنا أن نعرف + +345 +00:31:52,190 --> 00:31:53,650 +ترجمتها الدقيقة + +346 +00:31:58,570 --> 00:32:02,510 +بارك الله فيه، لو أردنا أن معرفها بكلمة نقول + +347 +00:32:02,510 --> 00:32:09,270 +العلمانية معناها اللادينية أو الدنياوية التي لها + +348 +00:32:09,270 --> 00:32:12,690 +علاقة لها بالدين، دنياوية يعني مقابل دين ودنيا، + +349 +00:32:12,690 --> 00:32:17,590 +دين، دنيا، فهذه دنياوية وليس دينية، هذه الكلمة + +350 +00:32:17,590 --> 00:32:23,530 +الدقيقة الصحيحة في المعنى الذي يستعمله ويستخدمه + +351 +00:32:23,530 --> 00:32:28,420 +أهله عند أهله عند الغربالـ Secularism هو اللادينية + +352 +00:32:28,420 --> 00:32:34,660 +سنتعرف في التعريفات الاصطلاحية على هذا المعنى من + +353 +00:32:34,660 --> 00:32:37,840 +معاجم وقواميس الغرب نفسه + +354 +00:32:42,700 --> 00:32:46,660 +هناك كما قلنا قبل قليل يعني خلاف لغوى وبين + +355 +00:32:46,660 --> 00:32:51,640 +اللغويين أنفسهم حتى العرب منهم والمسلمين حول + +356 +00:32:51,640 --> 00:32:56,000 +النسبة علمانية أو علمانية فبعضهم ينطقوها بفتح + +357 +00:32:56,000 --> 00:33:00,320 +العين علمانية نسبة إلى العالم يعني بفتح العين نسبة + +358 +00:33:00,320 --> 00:33:04,920 +لمين؟ إلى العالم، للدنيا يعني مش عندك دنياوية، + +359 +00:33:04,920 --> 00:33:11,100 +عالم يعني الدنيا وبعضهم ينطقوها بكسر العين علمانية + +360 +00:33:11,870 --> 00:33:15,470 +بعض الأساتذة والدكاترة الكبار مثل الدكتور عدنان + +361 +00:33:15,470 --> 00:33:19,250 +الخطيب هو عضو مجمع اللغة العربية بالقاهرة قال إن + +362 +00:33:19,250 --> 00:33:26,290 +ضابط كلمة علماني بكسر العين يعني هو الأفسح والأصح + +363 +00:33:26,290 --> 00:33:31,470 +أما علماني فلا سند له من لغة أو تاريخ + +364 +00:33:33,980 --> 00:33:38,940 +و كذلك الدكتور عبدالصابور شاهين برضه راجل عالم في + +365 +00:33:38,940 --> 00:33:43,840 +اللغة و كبير و معروف و مفكر اسلامي مشهور و هو خبير + +366 +00:33:43,840 --> 00:33:47,980 +بمجمع اللغة العربية بالقاهرة كذلك قال كلمة + +367 +00:33:47,980 --> 00:33:52,960 +العلمانية بفتح العين هو الأصوب فانقول علمانية نسبة + +368 +00:33:52,960 --> 00:33:56,950 +إلى العالم إلى الدنيايعني العالم بمعنى الدنيا اظلع + +369 +00:33:56,950 --> 00:34:03,190 +علاقة بين العلمانية والعلم وشوفنا الكلام في المعنى + +370 +00:34:03,190 --> 00:34:05,230 +الإنجليزي قبل قليل + +371 +00:34:07,530 --> 00:34:11,830 +و هذا ينقلنا إلى الحديث عن معنى العلمانية اصطلاحا + +372 +00:34:11,830 --> 00:34:16,970 +لما نقول معناها اصطلاحا اذا بدنا ندقق و نركز على + +373 +00:34:16,970 --> 00:34:22,910 +معناها من مصادرها الأصلية عند أهلها عند أصحابها + +374 +00:34:22,910 --> 00:34:27,210 +عند الذين قالوا بها ونادوا بها و جاءوا به احنا لا + +375 +00:34:27,210 --> 00:34:32,530 +نعرف في ديننا هذا المصطلحوحتى الكلمة كما قلنا كلمة + +376 +00:34:32,530 --> 00:34:37,590 +يعني معربة وحديثة ومش موجودة في القديمة لا في + +377 +00:34:37,590 --> 00:34:41,650 +القرآن ولا في السنة ولا في أقوال العرب القدماء + +378 +00:34:42,370 --> 00:34:45,610 +وبالتالي نتعرف عليها من مصادر وفي عندي تعريفات + +379 +00:34:45,610 --> 00:34:52,130 +كثيرة حوالي ست تعريفات يعني لو اقتصرنا على الأربعة + +380 +00:34:52,130 --> 00:34:56,150 +الأولى منها وسنرى أن التعريفات الأربعة كلها قريبة + +381 +00:34:56,150 --> 00:35:03,070 +من بعضها بس للتأكيد نذكرها ولترسخ في الذهن معناها + +382 +00:35:03,070 --> 00:35:10,330 +فالتعريف الأولكما جاء في دائرة المعارف الأمريكية + +383 +00:35:10,330 --> 00:35:18,350 +دائرة معارف رسمية موثوقة أصلية بيرجع إليها فتتحدث + +384 +00:35:18,350 --> 00:35:23,430 +هذه الدائرة عن العلمانية فتعرفها بكلمة إيش + +385 +00:35:23,430 --> 00:35:26,530 +الدنياوي + +386 +00:35:26,530 --> 00:35:29,410 +وبالتالي تعريف الدنياوية + +387 +00:35:31,650 --> 00:35:34,450 +في نظام أخلاقي أُسس على مبادئ الأخلاق الطبيعية + +388 +00:35:34,450 --> 00:35:37,230 +ومستقل عن الديانات السماوية أو الخلق الخلق الخلق + +389 +00:35:37,230 --> 00:35:42,370 +وملاحظين أنا حاطط خط تحت كل ما يتعلق بمعنى المقصود + +390 +00:35:42,370 --> 00:35:47,550 +وهو اللادين عشان نراك ان هي الدنيا ويه الدنيا ويه + +391 +00:35:47,550 --> 00:35:51,490 +مقابل الدينين لأن هو بعرفها علي إنها الدنيا ويه + +392 +00:35:51,490 --> 00:35:54,250 +ومع ذلك ليش بيقول النظام أخلاقي أُسس على مبادئ + +393 +00:35:54,250 --> 00:35:58,350 +الأخلاق الطبيعي مستقل عن الديانات السماوية يعني لا + +394 +00:35:58,350 --> 00:36:03,200 +علاقة له بمين؟بالدين يعني بعيد عن الدين يعني مش + +395 +00:36:03,200 --> 00:36:08,140 +مرتبط بالدين يعني لا ديني وهذا هو المعنى الصحيح + +396 +00:36:08,140 --> 00:36:13,940 +والدقيق والمقصود في موسوعة أخرى دائرة المعارف + +397 +00:36:13,940 --> 00:36:19,140 +البريطانية وتحت مادة secularism اللي قبل قليل يعني + +398 +00:36:19,140 --> 00:36:23,620 +أكدنا عليها وركزنا عليها وهي أصل الكلمةباللغة + +399 +00:36:23,620 --> 00:36:28,700 +الإنجليزية بيعرف أو بتعرف هذه الدائرة هذه الكلمة + +400 +00:36:28,700 --> 00:36:34,180 +فتقول فضلاله في حركة اجتماعية تهدف إلى صرف الناس + +401 +00:36:34,180 --> 00:36:38,140 +وتوجيههم من الاهتمام بالآخر بالاهتمام بالتجارب + +402 +00:36:41,570 --> 00:36:47,370 +حركة اجتماعية وهدفها هو إبعاد صرف الناس عن إبعادهم + +403 +00:36:47,370 --> 00:36:51,490 +وتوجيههم بدل من الاهتمام بالآخرة إلى الاهتمام + +404 +00:36:51,490 --> 00:36:57,090 +بالدنيا وحدها الاهتمام فقط بالدنيا نحن خلقنا لهذه + +405 +00:36:57,090 --> 00:37:00,770 +الدنيا من أجل هذه الدنيا نعمل لهذه الدنيا ولا + +406 +00:37:00,770 --> 00:37:04,410 +علاقة لنا بغيب ولا بآخرة ولا بموراء الطبيعة كما + +407 +00:37:04,410 --> 00:37:12,260 +يقول هؤلاءطيب في كمان أيضا في قاموس العالم الجديد + +408 +00:37:12,260 --> 00:37:16,180 +Webster وهو يشرح مادة ال secularism نفسها والتركيز + +409 +00:37:16,180 --> 00:37:20,320 +كما تراهم على هذا المصطلح الإنجليزي secularism + +410 +00:37:20,320 --> 00:37:28,340 +بيتكرر وبينعاد فيه جاء بتعريفين لل secularism + +411 +00:37:28,340 --> 00:37:33,660 +التعريف الأول منهما يقول اه ايش بيقول التعريف + +412 +00:37:33,660 --> 00:37:34,880 +الأول منهما اتفضلوا + +413 +00:37:38,780 --> 00:37:43,160 +الـ secularism هي روح دنيا وية تتعلق بالدنيا ويلها + +414 +00:37:43,160 --> 00:37:47,420 +علاقة بالدنيا الروح الدنيا وية او اتجاهات دنيا وية + +415 +00:37:47,420 --> 00:37:52,660 +يعني بعيدة عن الدينية ولا علاقة بيها كذلك الاعتقاد + +416 +00:37:52,660 --> 00:37:56,740 +ب .. الاعتقاد بأن الدين والشؤون اللي كانت فيها لا + +417 +00:37:56,740 --> 00:38:00,970 +دخل لها بشؤونهابرضه نفس المعنى إن الدين ورجال + +418 +00:38:00,970 --> 00:38:05,110 +الكنيسة كل هذا لا علاقة له في شؤون الدولة فصل + +419 +00:38:05,110 --> 00:38:09,770 +الدين عن الدولة فصل الدين عن الحياة وهذه من + +420 +00:38:09,770 --> 00:38:15,090 +المعاني التي نضيفها إلى المعاني السابقة آخر يعني + +421 +00:38:15,090 --> 00:38:19,330 +هذه المعاجم والدوائر + +422 +00:38:19,330 --> 00:38:27,200 +في معجم export وهو يشرح كلمة sequelsecular وقريبة + +423 +00:38:27,200 --> 00:38:31,560 +من secularism يعني فيقول أيضا في تعريفين التعريف + +424 +00:38:31,560 --> 00:38:40,340 +الأول من هما .. يا أخوات مين من هنا؟ مين ماسمعناش + +425 +00:38:40,340 --> 00:38:44,800 +من الأخوات؟ مين فيكم ماسمعناش؟ فضل قال أنه دنياوي + +426 +00:38:44,800 --> 00:38:48,180 +أو مادي ليس دينيا ولا روحانيا مثل التربية + +427 +00:38:48,180 --> 00:38:50,980 +اللادينية أو الفن أو الموسيقى اللادينية والصوت + +428 +00:38:50,980 --> 00:38:56,020 +اللاديني والحكومة المناقضة للكنيسةبارك الله فيك + +429 +00:38:56,020 --> 00:39:01,060 +إذا هذه دنيوية مادية لا دينية ليس روحية كلها يعني + +430 +00:39:01,060 --> 00:39:07,760 +فصل وعزل وإقصاء الدين عن هذه القضايا عن التربية عن + +431 +00:39:07,760 --> 00:39:12,060 +الفن عن الموسيقى عن السلطة عن الحكومة كل هذا لا + +432 +00:39:12,060 --> 00:39:19,040 +علاقة للدين بهذه الأشياء المذكورة أيضا في رأي آخر + +433 +00:39:19,040 --> 00:39:24,220 +يقولالرأي الذي يقول لا ينبغي أن يكون الدين أساسا + +434 +00:39:24,220 --> 00:39:28,360 +الأخلاق والتربية يعني هذه الأخلاق احنا بنوضعها + +435 +00:39:28,360 --> 00:39:32,860 +لأنفسنا الدين لا علاقة له بالأخلاق مع أن منبع + +436 +00:39:32,860 --> 00:39:38,220 +الأخلاق هو من؟ الدين لكن عندهم لأنهم لا دينيين + +437 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"probability": 0.9241536458333334}, {"start": 177.75, "end": 177.95, "word": " أن", "probability": 0.7197265625}, {"start": 177.95, "end": 178.57, "word": " أصلها", "probability": 0.9801432291666666}, {"start": 178.57, "end": 179.49, "word": " ليس", "probability": 0.949951171875}, {"start": 179.49, "end": 180.67, "word": " عربية", "probability": 0.9072265625}, {"start": 180.67, "end": 180.79, "word": " ان", "probability": 0.304443359375}, {"start": 180.79, "end": 180.91, "word": " هذه", "probability": 0.873046875}, {"start": 180.91, "end": 181.27, "word": " الكلمة", "probability": 0.7604166666666666}, {"start": 181.27, "end": 181.41, "word": " لم", "probability": 0.93115234375}, {"start": 181.41, "end": 181.63, "word": " تنتج", "probability": 0.6536458333333334}, {"start": 181.63, "end": 181.77, "word": " في", "probability": 0.77783203125}, {"start": 181.77, "end": 182.25, "word": " القوامس", "probability": 0.86962890625}, {"start": 182.25, "end": 182.75, "word": " العربية", 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"word": " أو", "probability": 0.1636962890625}, {"start": 204.79, "end": 205.17, "word": " free", "probability": 0.873046875}, {"start": 205.17, "end": 206.13, "word": " masonary", "probability": 0.7898763020833334}, {"start": 206.13, "end": 206.59, "word": " free", "probability": 0.83984375}, {"start": 206.59, "end": 207.13, "word": " mason", "probability": 0.9228515625}, {"start": 207.13, "end": 208.25, "word": " يعني", "probability": 0.929931640625}, {"start": 208.25, "end": 209.11, "word": " البناء", "probability": 0.8722330729166666}, {"start": 209.11, "end": 210.21, "word": " الحر", "probability": 0.88330078125}, {"start": 210.21, "end": 210.45, "word": " free", "probability": 0.8974609375}, {"start": 210.45, "end": 211.15, "word": " masonary", "probability": 0.9619140625}, {"start": 211.15, "end": 211.49, "word": " يعني", "probability": 0.954833984375}, {"start": 211.49, "end": 212.33, "word": " البناء", "probability": 0.8538411458333334}, {"start": 212.33, "end": 213.31, "word": " الحر", "probability": 0.989013671875}, {"start": 213.31, "end": 213.97, "word": " ننسبه", "probability": 0.8291015625}, {"start": 213.97, "end": 215.53, "word": " للبناء", "probability": 0.884521484375}, {"start": 215.53, "end": 216.19, "word": " و", "probability": 0.92626953125}, {"start": 216.19, "end": 216.29, "word": " في", "probability": 0.6591796875}, {"start": 216.29, "end": 216.63, "word": " اللغة", "probability": 0.9962565104166666}, {"start": 216.63, "end": 217.73, "word": " الفرنسية", "probability": 0.9953125}, {"start": 217.73, "end": 218.19, "word": " قريب", "probability": 0.9752604166666666}, {"start": 218.19, "end": 218.61, "word": " برضه", "probability": 0.9654947916666666}, {"start": 218.61, "end": 219.15, "word": " من", "probability": 0.9892578125}, {"start": 219.15, "end": 219.49, "word": " هذا", "probability": 0.974609375}, {"start": 219.49, "end": 220.31, "word": " المصطلح", "probability": 0.9955078125}, {"start": 220.31, "end": 221.21, "word": " فيقول", "probability": 0.792724609375}, {"start": 221.21, "end": 221.49, "word": " في", "probability": 0.97705078125}, {"start": 221.49, "end": 221.93, "word": " اللغة", "probability": 0.9952799479166666}, {"start": 221.93, "end": 223.21, "word": " الفرنسية", "probability": 0.990234375}], "temperature": 1.0}, {"id": 10, "seek": 24902, "start": 224.68, "end": 249.02, "text": "franc-maçon هيك في اللهجة يعني بتاعتهم franc-maçon و free-maçonnerie franc-maçon يعني البناء الصادق هناك free-maçon أو free-maçonnerie يعني البناء أو البناء الحروة كلهما من البناء كما نلاحظ أو كما نرى لما عربت هذه الكلمة أو ترجمت فأصبح", "tokens": [69, 4257, 66, 12, 1696, 17134, 39896, 4117, 8978, 13672, 3224, 7435, 3660, 37495, 22653, 39894, 995, 34268, 16095, 30514, 12, 1696, 17134, 4032, 1737, 12, 1696, 17134, 1193, 414, 30514, 12, 1696, 17134, 37495, 22653, 29739, 1863, 16606, 31767, 18513, 4587, 34105, 4117, 1737, 12, 1696, 17134, 34051, 1737, 12, 1696, 17134, 1193, 414, 37495, 22653, 29739, 1863, 16606, 34051, 29739, 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