diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/-qkT9mZsHSE.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/-qkT9mZsHSE.srt
new file mode 100644
index 0000000000000000000000000000000000000000..cd91be4667b7fbd08e8eaeff6fa6a11f59098cff
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/-qkT9mZsHSE.srt
@@ -0,0 +1,2795 @@
+1
+00:00:05,150 --> 00:00:08,250
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله 
+
+2
+00:00:08,250 --> 00:00:11,990
+وبركاته اليوم هنستكمل في Chapter Stress and Load
+
+3
+00:00:11,990 --> 00:00:18,020
+analysis مادة تصميم الألوان واحد المحاضرة السابقة 
+
+4
+00:00:18,020 --> 00:00:22,100
+درستنا ال bending in straight beams درستنا ال
+
+5
+00:00:22,100 --> 00:00:25,640
+transfer shear stress in straight beams وحلينا 
+
+6
+00:00:25,640 --> 00:00:29,660
+مجموعة من الأمثلة اليوم هنكمل في دراسة ال torsion
+
+7
+00:00:29,660 --> 00:00:36,300
+هنبدأ أولا في ال round .. round rods بعدين 
+
+8
+00:00:36,300 --> 00:00:40,740
+هنخش على أشكال تانية اللي هي المستطيل .. المستطيل 
+
+9
+00:00:40,740 --> 00:00:47,890
+انفرغ .. ال .. أي شكل يكون غير مغلق مفتوح هنبدأ في
+
+10
+00:00:47,890 --> 00:00:52,770
+ال .. ال torsion في solid round bar أنا عندي هنا
+
+11
+00:00:52,770 --> 00:01:08,290
+solid round bar مثبت من الطرف فيه
+
+12
+00:01:08,290 --> 00:01:13,410
+torque فيه Torque بهذا الاتجاه
+
+13
+00:01:22,790 --> 00:01:26,090
+النتيجة ال Torque هصير ال twist عند الخط هذا
+
+14
+00:01:26,090 --> 00:01:35,410
+النقطة a هذا النقطة c هصير 
+
+15
+00:01:35,410 --> 00:01:41,270
+twist بزاوية 
+
+16
+00:01:41,270 --> 00:01:46,010
+gamma
+
+17
+00:01:49,330 --> 00:01:59,990
+عندي هاي مركز ال رد هاد الزرع هتكون theta
+
+18
+00:01:59,990 --> 00:02:05,470
+ال
+
+19
+00:02:05,470 --> 00:02:16,190
+radius لل bar ال maximum radius اللي هو R عندي 
+
+20
+00:02:16,190 --> 00:02:17,990
+هذا المحور الإحداثية X
+
+21
+00:02:22,290 --> 00:02:26,890
+هذا المحور إحداثيات Y
+
+22
+00:02:26,890 --> 00:02:36,670
+هذا
+
+23
+00:02:36,670 --> 00:02:44,190
+المحور إحداثيات Z ال
+
+24
+00:02:44,190 --> 00:02:50,330
+angle of twist θ يستوي ال Torque في طول ال bar 
+
+25
+00:02:56,490 --> 00:03:02,870
+على G في J جي اللى هي ال modulus of rigidity ال J 
+
+26
+00:03:02,870 --> 00:03:07,390
+ال polar moment of inertia ال T ال Torque و ال L
+
+27
+00:03:07,390 --> 00:03:12,570
+اللى هو طول ال bar و ال shear stress at any radius
+
+28
+00:03:12,570 --> 00:03:20,250
+ρ مواظبة
+
+29
+00:03:20,250 --> 00:03:25,470
+العلاقة تاو بسوا تي رو على Jالـ maximum shear
+
+30
+00:03:25,470 --> 00:03:27,490
+stress في حالة الـ torsion وين بيكون على الصفحة
+
+31
+00:03:27,490 --> 00:03:32,650
+الخارجية الـ tau max بالساوية T في R على J الـ R
+
+32
+00:03:32,650 --> 00:03:40,870
+هو نص قطر البر طبعا
+
+33
+00:03:40,870 --> 00:03:49,550
+المعادلات هذه مبنية على الفرضيات التالية أولا
+
+34
+00:03:49,550 --> 00:03:54,150
+شندي a pure Torque فيش any other type of loading بس
+
+35
+00:03:54,150 --> 00:03:59,190
+فقط عندي Torque لان 
+
+36
+00:03:59,190 --> 00:04:03,050
+بعيدا عن اي discontinuities or point of
+
+37
+00:04:03,050 --> 00:04:08,470
+application of Torque material obeys hook's law
+
+38
+00:04:08,470 --> 00:04:16,990
+يعني تصرفها ال stress مع ال strain خطي 
+
+39
+00:04:16,990 --> 00:04:20,350
+خطي 
+
+40
+00:04:28,570 --> 00:04:33,390
+adjacent cross sections originally plain and
+
+41
+00:04:33,390 --> 00:04:35,510
+parallel remain plain and parallel يعني دي هاي
+
+42
+00:04:35,510 --> 00:04:42,330
+عملت مقطع أحيان في البداية قبل ال loading كان 
+
+43
+00:04:42,330 --> 00:04:45,570
+مستوي وبعد ال loading بضله مستوي يعني بيطيارش 
+
+44
+00:04:45,570 --> 00:04:47,710
+الاستواء في المقاطع
+
+45
+00:04:51,400 --> 00:04:58,720
+radial lines remain straight before
+
+46
+00:04:58,720 --> 00:05:08,440
+loading هذا هو ال radial line after loading ماصارش
+
+47
+00:05:08,440 --> 00:05:19,660
+curved لسه دلو ايش عدل المعادلات
+
+48
+00:05:19,660 --> 00:05:32,890
+اللي شفناها تستخدم في حالة المقاطع اللي مدورة shear 
+
+49
+00:05:32,890 --> 00:05:40,530
+stress does not vary linearly with
+
+50
+00:05:40,530 --> 00:05:48,450
+radial distance بتغيرش بشكل linear لأن أنا في 
+
+51
+00:05:48,450 --> 00:05:49,850
+الآخر أنا عند ال shear stress
+
+52
+00:05:54,560 --> 00:06:00,180
+حكيت تاوم ماكس بالساوية
+
+53
+00:06:00,180 --> 00:06:08,840
+ت في ر على ج بالساوية ت في القطر على اتنين على باي
+
+54
+00:06:08,840 --> 00:06:14,740
+على اربع ستين باي ديوز اربعة
+
+55
+00:06:18,770 --> 00:06:27,050
+على اربع ستين يعني بصفة اتنين و تلاتين T على Pi D
+
+56
+00:06:27,050 --> 00:06:31,790
+تكبير هذه ال radial تغير مش linear معاها بال
+
+57
+00:06:31,790 --> 00:06:38,230
+maximum shear stress طبعا 
+
+58
+00:06:38,230 --> 00:06:41,610
+لاحظوا الجملة هذه هو بيحكي فقط على maximum shear 
+
+59
+00:06:41,610 --> 00:06:45,970
+stress لكن الـ shear stress at any other radius
+
+60
+00:06:45,970 --> 00:06:54,070
+بتغير linearly يعني بمعنى تاو بالثواب تي رو على جي 
+
+61
+00:06:54,070 --> 00:06:59,770
+هذا constant وهذا constant لل last section اما رو
+
+62
+00:06:59,770 --> 00:07:06,250
+بتغير طيب
+
+63
+00:07:06,250 --> 00:07:15,770
+الحالة الجديدة عليك هوان المقطع يكون مستطيل إذا 
+
+64
+00:07:15,770 --> 00:07:20,350
+كان عنده bar المقطع
+
+65
+00:07:20,350 --> 00:07:21,350
+كان مستطيل
+
+66
+00:07:40,700 --> 00:07:50,900
+هو عليه .. عليه Torque .. عليه Torque الضلع الطويل 
+
+67
+00:07:50,900 --> 00:07:58,400
+هذا بي و الضلع التاني سي 
+
+68
+00:08:07,010 --> 00:08:10,430
+طبعا نتيجة ال Torque هصير فيه rotation، هصير فيه
+
+69
+00:08:10,430 --> 00:08:17,010
+twist الماكسوم مش هي ال stress أو maximum يقع طول
+
+70
+00:08:17,010 --> 00:08:24,290
+علاقة T على Alpha في B C تربيع أو نفسها T على B 
+
+71
+00:08:24,290 --> 00:08:30,010
+تربيع في 3 زائد 1.8 على B على C لأن في جدول عندي
+
+72
+00:08:30,010 --> 00:08:33,650
+ماتين ال ratio بي على سي بعد من واحد يعني المقطع 
+
+73
+00:08:33,650 --> 00:08:40,090
+المربع بعدين صارت بي على سي الزيد يعني دايما ال بي
+
+74
+00:08:40,090 --> 00:08:44,010
+أكبر أو يساوي السي 
+
+75
+00:08:46,650 --> 00:08:50,550
+for different P على C معطينا قيمة Alpha و Beta
+
+76
+00:08:50,550 --> 00:08:55,050
+Alpha يعني إذا P على C بيسوا واحد و نص هذا قيمة
+
+77
+00:08:55,050 --> 00:08:58,430
+Alpha point اتنين تلاتة واحد و Beta بيسوا point 
+
+78
+00:08:58,430 --> 00:09:03,250
+واحد تسعة ستة و Theta بيسوا T في L على Beta B C
+
+79
+00:09:03,250 --> 00:09:08,270
+كيب في G ال T اللي هو ال Torque ال L الطول تاع ال
+
+80
+00:09:08,270 --> 00:09:14,290
+bar ال Beta empirical constant او يوجد من الجدول
+
+81
+00:09:14,290 --> 00:09:19,280
+التحت الـ B هذا الارتفاع الـ C هذا الارتفاع الجي
+
+82
+00:09:19,280 --> 00:09:28,280
+الموديلوس of rigidity طيب
+
+83
+00:09:28,280 --> 00:09:37,920
+لأن وين في عندي Torque وفي rotation معناته في عندي 
+
+84
+00:09:37,920 --> 00:09:42,940
+transfer of power في انتقال للقدرة او الطاقة في 
+
+85
+00:09:42,940 --> 00:09:47,940
+حالة ال metric unit ال power بالواط في علاقة بين 
+
+86
+00:09:47,940 --> 00:09:50,580
+ال power وال Torque والسرعة الزاوية ال power
+
+87
+00:09:50,580 --> 00:09:54,460
+بالساوية ال Torque في omega ال Torque واحدة تلت
+
+88
+00:09:54,460 --> 00:09:59,860
+نيوتن متر ال omega radians per second عند ال power 
+
+89
+00:09:59,860 --> 00:10:06,520
+h بالساوية T في omega omega إذا كانت السرعة
+
+90
+00:10:06,520 --> 00:10:10,960
+المعطلة في عند ال n بال radians revolutions per
+
+91
+00:10:10,960 --> 00:10:18,270
+minute ال omega هتكون ال n فى اتنين باى على ستين
+
+92
+00:10:18,270 --> 00:10:23,670
+يعني 
+
+93
+00:10:23,670 --> 00:10:30,490
+حسب ان ال power بالساوية H فى T فى N ال N بال RPM
+
+94
+00:10:30,490 --> 00:10:37,830
+فى اتنين باى على ستين يعني هتكون الساوية T فى N 
+
+95
+00:10:37,830 --> 00:10:41,830
+لما نقسم ستين على اتنين باى بتعطينا تسعة point
+
+96
+00:10:41,830 --> 00:10:49,460
+خمسة خمسة يعني ال Torque بالساعة وتسعة point خمسة 
+
+97
+00:10:49,460 --> 00:10:56,820
+خمسة في ال power على انا وحدة ال and بال R يعني 
+
+98
+00:10:56,820 --> 00:11:01,060
+هذا في حالة الوحدات المترية في حالة الوحدات
+
+99
+00:11:01,060 --> 00:11:06,000
+الإنجليزية ال
+
+100
+00:11:06,000 --> 00:11:10,980
+power هي المعطية بوحدة الحصان horse power ممكن 
+
+101
+00:11:10,980 --> 00:11:19,130
+استخدم المعادلة هذه أو المعادلة هذه ال F هي ال 
+
+102
+00:11:19,130 --> 00:11:24,650
+force Force في السرعة بيعطينا إيش؟ power ال V 
+
+103
+00:11:24,650 --> 00:11:30,370
+السرعة المحيطية وحدة ال feet per minute أو العلاقة
+
+104
+00:11:30,370 --> 00:11:37,970
+هذه ال T هو ال Torque على الشافت بواحدة ال pound 
+
+105
+00:11:37,970 --> 00:11:44,480
+per inch و ال N بواحدة ال RPM طب هو عامل تحويلات
+
+106
+00:11:44,480 --> 00:11:50,900
+مجهزة إذا ماكنت تحولوها لحق الكون نشوف
+
+107
+00:11:50,900 --> 00:12:02,660
+مثال عندي 
+
+108
+00:12:02,660 --> 00:12:10,950
+crank ماناولا عبارة عن الدراع هذا مقطع مستطيل هذه 
+
+109
+00:12:10,950 --> 00:12:16,910
+اليد ال handle و ال shaft هي مثبتة في الحيطة يعني و
+
+110
+00:12:16,910 --> 00:12:21,050
+في load قيمته F بيأثر في الطرفة يعني أنا بضغط
+
+111
+00:12:21,050 --> 00:12:29,670
+الشكل هذا لتحت معطين
+
+112
+00:12:29,670 --> 00:12:38,290
+ال F 300 pound force ال F بيستوى 300 pound 
+
+113
+00:12:45,720 --> 00:12:57,780
+force الشافت دي تحت الشافت 3/4 انش 3
+
+114
+00:12:57,780 --> 00:13:04,280
+ارباع انش draw
+
+115
+00:13:04,280 --> 00:13:11,050
+three body diagrams of the shaft a,b and arm a and 
+
+116
+00:13:11,050 --> 00:13:16,390
+arm b,c نعمل three body diagram للشافت a,b
+
+117
+00:13:16,390 --> 00:13:24,890
+والأذرع b,c compute
+
+118
+00:13:24,890 --> 00:13:30,790
+values of all forces moments and torques label
+
+119
+00:13:30,790 --> 00:13:33,790
+directions of current systems on these diagrams
+
+120
+00:13:33,790 --> 00:13:41,330
+تحط محاول إحداثية يعني أنا لو بدي أبدأ أخد الجزء 
+
+121
+00:13:41,330 --> 00:13:54,930
+هذا أخد ال free body diagram لحاله طيب
+
+122
+00:13:54,930 --> 00:14:00,530
+لو بدي أخد الجزء هذا free body diagram لحاله أعمل قطع
+
+123
+00:14:00,530 --> 00:14:04,430
+يعني خلينا نحكي هذه المحاور عندي X 
+
+124
+00:14:11,460 --> 00:14:16,680
+Y Z هاتبرك
+
+125
+00:14:16,680 --> 00:14:22,320
+على شكل خط عندي هنا عندي
+
+126
+00:14:22,320 --> 00:14:29,880
+خانية A B C خانية نسميها نقطة دي نقسمها D هاي C 
+
+127
+00:14:29,880 --> 00:14:35,240
+هاي D هاي عندي ال X Axis
+
+128
+00:14:41,510 --> 00:14:46,610
+وهاي عندي ال y axis و 
+
+129
+00:14:46,610 --> 00:14:50,650
+هاي عندي ال z axis
+
+130
+00:14:50,650 --> 00:14:57,990
+عندي بدي أعمل cut هن سيه عندي بتأث .. عندي بتأثر ال
+
+131
+00:14:57,990 --> 00:15:04,650
+force F طالما
+
+132
+00:15:04,650 --> 00:15:07,510
+أعمل cut هكون عندي force معكسه 
+
+133
+00:15:13,790 --> 00:15:21,190
+ف لحظة الف تعمل Moment بتحاول تعمل lay باتجاه ال 
+
+134
+00:15:21,190 --> 00:15:28,610
+negative z يعني بتحاول هي بتحاول تعمل bending بهذا
+
+135
+00:15:28,610 --> 00:15:33,350
+الاتجاه حوالي ال negative z من وقت ال reaction
+
+136
+00:15:33,350 --> 00:15:37,210
+Moment هتكون عكسه من وقت هتكون في عندي reaction 
+
+137
+00:15:37,210 --> 00:15:37,710
+Moment
+
+138
+00:15:42,210 --> 00:15:50,250
+بدي أستخدم سهمين بدي أسميها M1
+
+139
+00:15:50,250 --> 00:15:54,650
+طبعا 
+
+140
+00:15:54,650 --> 00:16:02,790
+هنا ال F هتكون اللي هي نفسها 300 فاوند ال 
+
+141
+00:16:02,790 --> 00:16:09,070
+moment المسافة من هنا لهنا المسافة
+
+142
+00:16:09,070 --> 00:16:10,710
+من هنا لهنا واحد و نصف انش
+
+143
+00:16:13,940 --> 00:16:18,700
+معناته M1 M1
+
+144
+00:16:18,700 --> 00:16:25,380
+هتكون تساوي واحد 
+
+145
+00:16:25,380 --> 00:16:33,460
+و نصف في ثلاث مئة صح؟ واحد و نصف في ثلاث مئة في اتجاه
+
+146
+00:16:33,460 --> 00:16:36,920
+الـ K يعني
+
+147
+00:16:36,920 --> 00:16:42,020
+أربعمائة و خمسين اتجاه الـ K أربعمائة و خمسين pound
+
+148
+00:16:44,600 --> 00:16:52,120
+باتجاه الـ G لأن هاخد الـ free body ده يجي رقم للـ
+
+149
+00:16:52,120 --> 00:17:00,020
+بي سي لأن هاخد الـ free body للـ بي سي هعتبره هاي الـ
+
+150
+00:17:00,020 --> 00:17:07,560
+بي سي هاي 
+
+151
+00:17:07,560 --> 00:17:12,940
+الـ C هاي الـ B هذا هو الـ Z axis
+
+152
+00:17:21,790 --> 00:17:33,870
+هذا الـ X axis وهذا الـ Y axis طيب
+
+153
+00:17:33,870 --> 00:17:50,270
+عن الـ C هتكون في عندي F عكس هذه هعندي هنا F و
+
+154
+00:17:50,270 --> 00:17:50,970
+في عندي moment
+
+155
+00:17:55,220 --> 00:18:00,120
+عكس سادة هتكون لسه 
+
+156
+00:18:00,120 --> 00:18:03,380
+مخلص باخد اللي هنا أنا لسه انتظرت انتظرت انتظرت
+
+157
+00:18:03,380 --> 00:18:06,620
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+158
+00:18:06,620 --> 00:18:06,640
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+159
+00:18:06,640 --> 00:18:06,700
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+160
+00:18:06,700 --> 00:18:07,200
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+161
+00:18:07,200 --> 00:18:07,440
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+162
+00:18:07,440 --> 00:18:23,860
+انتظرت انتظرت انتظرت انتظرت أن
+
+163
+00:18:24,260 --> 00:18:31,160
+بالنسبة لـ cd bending moment لأن هاي المقطع بتاعه
+
+164
+00:18:31,160 --> 00:18:34,820
+فبتحاول
+
+165
+00:18:34,820 --> 00:18:37,680
+تبقى ليه الـ torsion فالـ torsion عديه هتانه هي عكسه
+
+166
+00:18:37,680 --> 00:18:44,680
+هكون انديهين في
+
+167
+00:18:44,680 --> 00:18:46,220
+M1 عند B
+
+168
+00:18:51,640 --> 00:18:56,080
+الـ F بتحاول تعمل 
+
+169
+00:18:56,080 --> 00:19:02,520
+يعني هين بالـ نجم moment باتجاه الـ negative x axis
+
+170
+00:19:02,520 --> 00:19:09,380
+يعني هي بشكلها ده الـ reaction moment هكون عكسها
+
+171
+00:19:09,380 --> 00:19:18,080
+هكون ده هين ام اثنين
+
+172
+00:19:43,290 --> 00:19:49,950
+الآن في كمان الـ F حكينا هاي الـ bending moment
+
+173
+00:19:49,950 --> 00:19:58,200
+بتاعتها الـ ام اثنين ايش بالساوية؟
+
+174
+00:19:58,200 --> 00:20:07,600
+اللي هي الـ F ثلاث مئة في أربع انش بالساوية ثلاث مئة
+
+175
+00:20:07,600 --> 00:20:12,100
+في أربع في اتجاه الـ I
+
+176
+00:20:21,040 --> 00:20:25,360
+هذه reaction moment الآن الـ force اف بتحاول تعمل 
+
+177
+00:20:25,360 --> 00:20:30,340
+bending بهذا الاتجاه لأن اللي هو فيه الـ strength
+
+178
+00:20:30,340 --> 00:20:36,740
+هيقوى عشان قاوم الـ moment اللي جا من هنا بالـ
+
+179
+00:20:36,740 --> 00:20:41,340
+negative x axis لازم الـ moment بالـ positive axis
+
+180
+00:20:41,340 --> 00:20:46,220
+فهذه reaction moment فهتكون
+
+181
+00:20:46,220 --> 00:20:55,620
+لحظة شوية هتكون الألف و اثنين Pound في تجاه الـ I لسه 
+
+182
+00:20:55,620 --> 00:21:03,040
+ما خلصتش فاندي هين ثلاث مئة فاندي هين تلت
+
+183
+00:21:03,040 --> 00:21:10,400
+مية فاندي
+
+184
+00:21:10,400 --> 00:21:11,160
+هين ثلاث مئة فاندي هين ثلاث مئة فاندي هين ثلاث مئة
+
+185
+00:21:11,160 --> 00:21:11,640
+فاندي هين ثلاث مئة فاندي هين ثلاث مئة فاندي هين تلت
+
+186
+00:21:11,640 --> 00:21:11,780
+مية فاندي هين ثلاث مئة فاندي هين ثلاث مئة فاندي هين
+
+187
+00:21:11,780 --> 00:21:14,380
+مية فاندي هين ثلاث مئة فاندي هين ت
+
+188
+00:21:28,460 --> 00:21:36,180
+هذه AB أول
+
+189
+00:21:36,180 --> 00:21:38,640
+شي في الـ .. دايما في free body diagrams لازم أحط
+
+190
+00:21:38,640 --> 00:21:47,560
+المحاور ده هي صح عندي هاي الـ X axis هاي
+
+191
+00:21:47,560 --> 00:21:52,360
+الـ Y axis وهاي
+
+192
+00:21:52,360 --> 00:21:55,860
+الـ Z axis
+
+193
+00:22:03,620 --> 00:22:08,140
+طيب هاي بي أنا جاي من عند بي .. من عند بي هيكون في
+
+194
+00:22:08,140 --> 00:22:21,520
+عندي أول اش في عندي F لتحت و
+
+195
+00:22:21,520 --> 00:22:27,440
+في M2 لاتجاه المعاكس هاي M2
+
+196
+00:22:30,910 --> 00:22:37,930
+هذه ام واحد عشان
+
+197
+00:22:37,930 --> 00:22:46,810
+نميزها moment فاندي
+
+198
+00:22:46,810 --> 00:22:53,810
+ام اثنين باتجاه
+
+199
+00:22:53,810 --> 00:22:58,650
+هذا اتجاه مظبوط هذه ام اثنين
+
+200
+00:23:03,880 --> 00:23:24,640
+و عند M1 باتجاه الـ negative Z ناخد
+
+201
+00:23:24,640 --> 00:23:30,780
+الـ effect بتاع الـ moments عند A had it will be
+
+202
+00:23:30,780 --> 00:23:37,110
+resisted by M1 بهذا الاتجاه بالنجم
+
+203
+00:23:37,110 --> 00:23:40,530
+moment هتكون
+
+204
+00:23:40,530 --> 00:23:47,190
+هاي
+
+205
+00:23:47,190 --> 00:23:52,410
+M1 وعندي
+
+206
+00:23:52,410 --> 00:24:00,690
+هنا torsion M2
+
+207
+00:24:02,960 --> 00:24:11,260
+و في عندي force هدى للتحت هتكون هي اللي أعلى الآن
+
+208
+00:24:11,260 --> 00:24:22,860
+الـ force F بتحاول تعمل bending moment حوالين الـ
+
+209
+00:24:22,860 --> 00:24:29,280
+negative Z مانعة الـ resisting هتكون في الموجة في Z
+
+210
+00:24:36,270 --> 00:24:48,030
+م ثلاثة الام ثلاثة هتكون اف كم في خمسة يعني ألف
+
+211
+00:24:48,030 --> 00:25:00,690
+خمسمائة في اتجاه الـ K هيك
+
+212
+00:25:00,690 --> 00:25:01,490
+يعني اننا عملنا الـ
+
+213
+00:25:14,150 --> 00:25:21,410
+هذا المطبوع الأول المطبوع الثاني compute maximum of
+
+214
+00:25:21,410 --> 00:25:28,290
+torsional stress and bending stress in arm BC and
+
+215
+00:25:28,290 --> 00:25:42,510
+indicate where these act أول
+
+216
+00:25:42,510 --> 00:25:46,590
+شي على PC طبعا احنا هنهمل الـ Transverse shear
+
+217
+00:25:46,590 --> 00:25:47,030
+effect
+
+218
+00:25:49,680 --> 00:25:53,920
+اللي هو الشير نتيجة القوة المستعرضة هنهملها بس
+
+219
+00:25:53,920 --> 00:25:59,980
+هنتظر الـ shear stress due to torsion و الـ bending
+
+220
+00:25:59,980 --> 00:26:07,720
+stress الآن due to torsion المقطع أنا عندي هنا
+
+221
+00:26:07,720 --> 00:26:15,920
+المقطع جاي مستطيل جاي
+
+222
+00:26:15,920 --> 00:26:17,660
+سماكة ربع انش
+
+223
+00:26:25,740 --> 00:26:40,140
+والارتفاع واحد وربع نرجع
+
+224
+00:26:40,140 --> 00:26:47,740
+هنا للملاحظات بتاعتنا الـ
+
+225
+00:26:47,740 --> 00:26:53,000
+shear stress في الـ rectangularSections بيكون Zero
+
+226
+00:26:53,000 --> 00:26:56,340
+عند الـ corners يعني بيكون الـ duty ترجن بيكون هنا
+
+227
+00:26:56,340 --> 00:27:03,400
+الـ share stress Zero هنا Zero هنا Zero Zero و
+
+228
+00:27:03,400 --> 00:27:07,760
+بيكون الـ maximum على الضلع الطويل يعني بيكون الـ
+
+229
+00:27:07,760 --> 00:27:17,940
+maximum هنا هي بتكون الـ maximum marginal share
+
+230
+00:27:20,990 --> 00:27:24,490
+stress طبعا نشيل الـ stress يعني zero, zero, zero,
+
+231
+00:27:24,550 --> 00:27:33,270
+zero طيب
+
+232
+00:27:33,270 --> 00:27:40,890
+ما نبتدى نحسب وين هتكون .. يعني هتكون نقطة B and B
+
+233
+00:27:40,890 --> 00:27:46,190
+بتكون هي عيش الـ critical بتكون هي الـ critical
+
+234
+00:27:46,190 --> 00:27:47,490
+معناته الـ tau
+
+235
+00:27:51,960 --> 00:28:08,520
+ر بي سي تاو ماكس بالساوية المقطع المستطيل T
+
+236
+00:28:08,520 --> 00:28:12,520
+على
+
+237
+00:28:12,520 --> 00:28:16,500
+الف بي
+
+238
+00:28:16,500 --> 00:28:17,400
+سي تربيع
+
+239
+00:28:22,100 --> 00:28:26,280
+طبعا الـ torque في الحالة هذه بيساوي م واحد الـ
+
+240
+00:28:26,280 --> 00:28:33,220
+torque بيساوي م واحد أنا بالظبط طبعا بي على سي بي
+
+241
+00:28:33,220 --> 00:28:40,460
+هذه بي وهذه سي الـ بي على سي بيساوي واحد وربع على
+
+242
+00:28:40,460 --> 00:28:47,660
+ربع واحد وربع في خمسة
+
+243
+00:28:47,660 --> 00:28:49,740
+بما ان بي على سي خمسة
+
+244
+00:28:52,220 --> 00:28:55,640
+عند دانيل أنت جاي في النص بين أرواحك تفهم رايحانة
+
+245
+00:28:55,640 --> 00:29:03,400
+فالـ الفا هتكون point 282 زي point 299 على 2 لإنه
+
+246
+00:29:03,400 --> 00:29:13,400
+جاي في النص بالظبط الـ الفا الـ torque الساوى M1 اللي
+
+247
+00:29:13,400 --> 00:29:20,400
+هو 450 pound inch والـ الفا
+
+248
+00:29:22,460 --> 00:29:30,120
+حسبتوا ليها point 2905 point 2905
+
+249
+00:29:30,120 --> 00:29:31,580
+point 2905 point 2905 point 2905 point 2905 point
+
+250
+00:29:31,580 --> 00:29:35,920
+2905 point 2905 point 2905 point 2905 point 2905
+
+251
+00:29:35,920 --> 00:29:41,500
+point 2905 point 2905 point 2905 point 2905 point
+
+252
+00:29:41,500 --> 00:29:44,640
+2905
+
+253
+00:29:44,640 --> 00:29:44,660
+point 2905 point 2905 point 2905 point 2905 point
+
+254
+00:29:44,660 --> 00:29:44,840
+2905 point 2905 point 2905 point 2905 point 2905
+
+255
+00:29:44,840 --> 00:29:44,880
+point 2905 point 2905 point 2905 point 2905 point
+
+256
+00:29:44,880 --> 00:29:46,880
+point 2905 point 2905 point 2
+
+257
+00:29:59,650 --> 00:30:06,410
+تسعة عشر ألف وثمانية
+
+258
+00:30:06,410 --> 00:30:07,530
+وثمانية وثمانية وثمانية وثمانية وثمانية و
+
+259
+00:30:07,530 --> 00:30:12,170
+ثمانية وثمانية و
+
+260
+00:30:12,170 --> 00:30:12,510
+ثمانية وثمانية وثمانية وثمانية وثمانية و
+
+261
+00:30:12,510 --> 00:30:14,470
+ثمانية وثمانية وثمانية وثمانية وثمانية و
+
+262
+00:30:14,470 --> 00:30:18,010
+ثمانية وثمانية وثمانية وثمانية وثمانية و
+
+263
+00:30:18,010 --> 00:30:18,050
+ثمانية وثمانية وثمانية وثمانية وثمانية و
+
+264
+00:30:24,240 --> 00:30:29,000
+بدون ما أحسب كمان الـ maximum bending stress bending
+
+265
+00:30:29,000 --> 00:30:34,100
+stress الـ bending stress طبعا فيه bending ع حوالين
+
+266
+00:30:34,100 --> 00:30:40,720
+المستوى هذا يعني هكون بلزمني MX MX اللي هي M2 يعني
+
+267
+00:30:40,720 --> 00:30:43,920
+هكون الـ .. الـ .. الـ .. النوع من الـ stress due to
+
+268
+00:30:43,920 --> 00:30:47,320
+bending هكون maximum على الـ fiber هذي هكون عندي
+
+269
+00:30:47,320 --> 00:30:52,960
+هنا tension و تحت compression صح؟ هكون عندي الـ
+
+270
+00:30:52,960 --> 00:30:53,460
+sigma
+
+271
+00:30:59,900 --> 00:31:08,360
+Sigma Z ستكون في الحلقة هذه سيجما زد سيجما زد
+
+272
+00:31:08,360 --> 00:31:20,400
+بالساوية ام اثنين ام
+
+273
+00:31:20,400 --> 00:31:23,960
+اثنين في
+
+274
+00:31:23,960 --> 00:31:24,780
+بي على اثنين
+
+275
+00:31:29,910 --> 00:31:35,210
+على I حوالين الـ X هتكون
+
+276
+00:31:35,210 --> 00:31:41,370
+M2 اللي عندي أو M2 في
+
+277
+00:31:41,370 --> 00:31:53,450
+B على 2 الـ I هتكون واحد على اثنا عشر سي بيتا تكعيب يعني
+
+278
+00:31:53,450 --> 00:31:59,490
+هتساوي ستة M2
+
+279
+00:32:02,280 --> 00:32:06,640
+على C تربيع
+
+280
+00:32:06,640 --> 00:32:11,440
+يعني
+
+281
+00:32:11,440 --> 00:32:15,540
+هتساوي ستة
+
+282
+00:32:15,540 --> 00:32:25,240
+أهم اثنين اللي هي الف و 1200 على
+
+283
+00:32:25,240 --> 00:32:26,520
+C اللي هي ربع
+
+284
+00:32:31,560 --> 00:32:38,000
+في P وهي 1.25 تربيع
+
+285
+00:32:38,000 --> 00:32:47,220
+18
+
+286
+00:32:47,220 --> 00:32:53,200
+1432 PSI
+
+287
+00:33:01,930 --> 00:33:04,590
+ثوان أسوأ طالع بال max in order to reduce stress
+
+288
+00:33:04,590 --> 00:33:17,050
+and indicate where they act  اه ليش sigma z أنا
+
+289
+00:33:17,050 --> 00:33:23,530
+هنا بحاول أعمل bending بالشكل هذا مالك ال stress
+
+290
+00:33:23,530 --> 00:33:30,470
+هيكون في هذا الاتجاه مش بحاول أنا هيك أطعمجهيكون في
+
+291
+00:33:30,470 --> 00:33:40,030
+شد على هذا الاتجاه هذا الاتجاه ايش ال z هو normal
+
+292
+00:33:40,030 --> 00:33:47,810
+stress بس باتجاه ال z axis طيب لو أخذت ال section
+
+293
+00:33:47,810 --> 00:33:54,010
+احنا حكينا عند ال fiber هذا هيكون sigma z maximum
+
+294
+00:33:54,010 --> 00:33:57,450
+sigma z maximum
+
+295
+00:34:01,670 --> 00:34:07,450
+و يعني هنا ال fibers بيكون maximum tension هنا
+
+296
+00:34:07,450 --> 00:34:14,850
+maximum compression ال torsional shear
+
+297
+00:34:14,850 --> 00:34:27,330
+stress بيكون maximum هنا zero هنا zero يعني لو بدى
+
+298
+00:34:27,330 --> 00:34:33,910
+أعمله هعمله عند طرفها هذا هيكون شيء زي هيك و عند
+
+299
+00:34:33,910 --> 00:34:40,390
+طرفها هذا هيكون نفس الشكل بس ارتفاعه أقل هذا ال
+
+300
+00:34:40,390 --> 00:34:45,150
+shear stress ال total shear stress zero zero
+
+301
+00:34:45,150 --> 00:34:50,190
+maximum هذا
+
+302
+00:34:50,190 --> 00:34:53,070
+المطلوب الثاني المطلوب الثالث
+
+303
+00:35:00,450 --> 00:35:08,210
+determine maximum normal and shear stresses at a
+
+304
+00:35:08,210 --> 00:35:16,270
+هذه النقطة a عند
+
+305
+00:35:16,270 --> 00:35:21,410
+a في
+
+306
+00:35:21,410 --> 00:35:26,350
+عندي عند a at a في عندي torsion
+
+307
+00:35:29,520 --> 00:35:33,940
+قيمة الـ torque تبعته M2 في depending moment
+
+308
+00:35:33,940 --> 00:35:41,880
+قيمتها M3 M1 M3 M1 يعني إذا أخذت element هنا
+
+309
+00:35:41,880 --> 00:35:55,960
+element صغير هذا
+
+310
+00:35:55,960 --> 00:36:05,300
+critical element Delta X Delta Y Delta Z امسحها هذا
+
+311
+00:36:05,300 --> 00:36:10,300
+لو
+
+312
+00:36:10,300 --> 00:36:25,240
+أخذت ال element هنا و كبرته هذا
+
+313
+00:36:25,240 --> 00:36:25,780
+عند A
+
+314
+00:36:54,520 --> 00:36:59,400
+هذه ال X Axis وهذه
+
+315
+00:36:59,400 --> 00:37:04,060
+ال Z وهذه
+
+316
+00:37:04,060 --> 00:37:09,080
+ال Y
+
+317
+00:37:09,080 --> 00:37:15,580
+يعني
+
+318
+00:37:15,580 --> 00:37:20,440
+الفكرة من السؤال أن أنت في الأول تعمل فعلا في حالة
+
+319
+00:37:20,440 --> 00:37:22,540
+اللي كانت المثلة static تعمل force analysis وفي
+
+320
+00:37:22,540 --> 00:37:25,580
+حالة اللي كانت المثلة dynamics تعمل kinematic
+
+321
+00:37:25,580 --> 00:37:27,740
+analysis تحس ب displacement, velocities,
+
+322
+00:37:27,820 --> 00:37:30,840
+acceleration وبعدين تعمل force analysis تعمل free
+
+323
+00:37:30,840 --> 00:37:35,480
+body diagrams و بتطلع ال forces بعد ما تطلع ال
+
+324
+00:37:35,480 --> 00:37:38,680
+forces بتوجد بتحدد critical locations بالاتجاه
+
+325
+00:37:38,680 --> 00:37:42,460
+المحور و بالاتجاه المقطع بالاثنين بعمل اتحاد الـ
+
+326
+00:37:42,460 --> 00:37:46,100
+critical element اللي هي آخر خطوة هذه بعمل عليها
+
+327
+00:37:46,100 --> 00:37:50,940
+stress analysis بعمل عليها stress analysis الآن
+
+328
+00:37:50,940 --> 00:37:54,920
+اللحظة
+
+329
+00:37:54,920 --> 00:38:02,220
+ال load هنا بيحول من ال bending يعني هيكون في عندي
+
+330
+00:38:02,220 --> 00:38:08,360
+عزم normal stress باتجاه ال x axis هذا ال moment
+
+331
+00:38:08,360 --> 00:38:22,410
+اللي هنا بتعمل sigma x هنا sigma
+
+332
+00:38:22,410 --> 00:38:39,730
+x و
+
+333
+00:38:39,730 --> 00:38:47,740
+تحاول تعملTorsion Torsion خلينا ناخذ المقطع ندور
+
+334
+00:38:47,740 --> 00:38:58,020
+لحاله هي ال
+
+335
+00:38:58,020 --> 00:39:03,780
+Torsion اللي جاي بيحاول
+
+336
+00:39:03,780 --> 00:39:06,200
+يعمل Rotation
+
+337
+00:39:08,210 --> 00:39:15,990
+شكل هذا it will be resisted هكون عليه torsion يعني
+
+338
+00:39:15,990 --> 00:39:19,550
+هيكون هذا
+
+339
+00:39:19,550 --> 00:39:23,690
+هذا
+
+340
+00:39:23,690 --> 00:39:34,890
+ال tau العمود أو مستواه ما يش X Z لما
+
+341
+00:39:34,890 --> 00:39:39,520
+كنا نسمي أنا بشتغل على مستوى هذا المصادر العاملة
+
+342
+00:39:39,520 --> 00:39:47,180
+عليه x معناته هي x في اتجاه ال z tau xz الآن هاخده
+
+343
+00:39:47,180 --> 00:39:49,700
+من ال top view هكون أنا في ال xz plane هاخده في ال
+
+344
+00:39:49,700 --> 00:39:56,780
+xz plane هيسهل مسألة 2D
+
+345
+00:39:56,780 --> 00:39:59,840
+طبعا لو بدي أحط لترانزر شيريسترس هكون 3D هكون أندي
+
+346
+00:39:59,840 --> 00:40:05,220
+شيريسترس في هذا الاتجاه فأنا مهم لل Transverse
+
+347
+00:40:05,220 --> 00:40:10,040
+هكون أندي في ال xz plane الآن أنا هاطلع من ال y
+
+348
+00:40:10,040 --> 00:40:23,200
+axis ال y axis هذه ال x وهي ايش ال z هكون
+
+349
+00:40:23,200 --> 00:40:28,300
+عندي sigma sigma
+
+350
+00:40:28,300 --> 00:40:28,780
+x
+
+351
+00:40:37,760 --> 00:40:47,880
+وأندي ايش هذا
+
+352
+00:40:47,880 --> 00:40:57,900
+ال TAO X Z S
+
+353
+00:40:57,900 --> 00:41:07,530
+اللي دي بيستخدمها M4 هندي M4 M4 بتساوي M1 زائد M
+
+354
+00:41:07,530 --> 00:41:15,070
+ثلاثة ال M واحد عندي 450 وال M ثلاثة
+
+355
+00:41:15,070 --> 00:41:19,050
+1000
+
+356
+00:41:19,050 --> 00:41:22,650
+و 500 يعني 1950 هتكون 1000
+
+357
+00:41:22,650 --> 00:41:34,710
+وتسعمائة و خمسين pound انش ال
+
+358
+00:41:34,710 --> 00:41:35,630
+sigma X
+
+359
+00:41:39,050 --> 00:41:51,530
+هتكون M4 في
+
+360
+00:41:51,530 --> 00:42:03,060
+الـ D على 2 هذا عند A على Y على 64D أس أربعة هذه
+
+361
+00:42:03,060 --> 00:42:08,680
+اللي هي H I M في C على I M في C على I يعني هتكون
+
+362
+00:42:08,680 --> 00:42:12,980
+سواء 32 M
+
+363
+00:42:12,980 --> 00:42:21,120
+أربعة على باي D تكعيب يعني هتكون سواء 32 M
+
+364
+00:42:21,120 --> 00:42:25,320
+أربعة اللي هي 1950
+
+365
+00:42:25,320 --> 00:42:27,400
+اللي هي 1950
+
+366
+00:42:30,770 --> 00:42:41,570
+على باي و ال D اللي هي 0.75 تكعيب احسبوها
+
+367
+00:42:41,570 --> 00:42:44,630
+سبعة
+
+368
+00:42:44,630 --> 00:42:48,850
+و 47105 47105
+
+369
+00:42:48,850 --> 00:42:58,070
+و 105 47105 و 100
+
+370
+00:42:58,070 --> 00:42:59,210
+و 6 PSI
+
+371
+00:43:05,740 --> 00:43:20,180
+التاو اكس زد بتساوي M2 التاو اكس زد التاو
+
+372
+00:43:20,180 --> 00:43:33,360
+هشري على هذا خلاص هذا هو مش لازمة التاو
+
+373
+00:43:35,710 --> 00:43:48,330
+M2 XZ XZ
+
+374
+00:43:48,330 --> 00:43:49,350
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+375
+00:43:49,350 --> 00:43:49,430
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+376
+00:43:49,430 --> 00:43:53,010
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+377
+00:43:53,010 --> 00:43:53,030
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+378
+00:44:03,960 --> 00:44:08,680
+في ال R اللي هي D على 2 هي ال Polar Modulation باي
+
+379
+00:44:08,680 --> 00:44:16,840
+على اثنين باي على اثنين و 32D أس أربعة يعني
+
+380
+00:44:16,840 --> 00:44:25,640
+نحن نستوي 16 M اتنين على باي D تكعيب يعني نحن
+
+381
+00:44:25,640 --> 00:44:38,850
+نستوي 16 M اتنين عام اتنين كم؟ 1200 على
+
+382
+00:44:38,850 --> 00:44:51,230
+باي في 0.75 تكعيب احسب تاو اكس ز كم
+
+383
+00:44:51,230 --> 00:44:56,990
+تطلع 14433 14433
+
+384
+00:44:56,990 --> 00:44:59,190
+14433 14433
+
+385
+00:45:08,200 --> 00:45:18,400
+أنا حسبت أو I locate critical element defined
+
+386
+00:45:18,400 --> 00:45:24,960
+بالنسبة لما أحاول إحداثيات ال original بتاعة X Y Z
+
+387
+00:45:27,070 --> 00:45:31,130
+بس مش هذا هو ال critical orientation عشان أوي ال
+
+388
+00:45:31,130 --> 00:45:36,070
+critical orientation بدي
+
+389
+00:45:36,070 --> 00:45:42,030
+أحصل ال principle stresses يعني بدي أستخدم more
+
+390
+00:45:42,030 --> 00:45:48,310
+circle خلاص أنا صار عندي المسألة كلها همسحها
+
+391
+00:45:58,340 --> 00:46:03,300
+صار عندي هي الـ critical هي ال original element هي
+
+392
+00:46:03,300 --> 00:46:09,980
+صارت المسألة بالبساطة عندي sigma X
+
+393
+00:46:09,980 --> 00:46:15,900
+وعندي
+
+394
+00:46:15,900 --> 00:46:19,600
+الآن أنا هي تسميها تاو Z تسميها اللي بدك إياها
+
+395
+00:46:19,600 --> 00:46:22,040
+تسميها تاو XZ تاو XY اللي بدك إياها
+
+396
+00:46:27,650 --> 00:46:32,350
+عشان ما تتعرضوش تاو XZ خلاص صارت مسألة بسيطة
+
+397
+00:46:32,350 --> 00:46:41,830
+السيجما XN دي بيساوي 47000.106
+
+398
+00:46:41,830 --> 00:46:52,670
+Kpsi والتاو XZ بيساوي 14.494 Kilogram per square
+
+399
+00:46:52,670 --> 00:46:52,990
+inch
+
+400
+00:47:06,100 --> 00:47:10,100
+طيب حكيت في حالتين إذا كانت ال mechanical element
+
+401
+00:47:10,100 --> 00:47:15,960
+تحت الدراسة ساكن زي الحالة هذه ما فيش .. ما فيش
+
+402
+00:47:15,960 --> 00:47:19,840
+motion أساسا بعمل ايش summation force بيساوي 0 و
+
+403
+00:47:19,840 --> 00:47:20,740
+summation motion بيساوي 0
+
+404
+00:47:26,150 --> 00:47:28,990
+بدك ترسم .. بدك ترسم اللي هو ال shear و ال moment
+
+405
+00:47:28,990 --> 00:47:35,430
+diagrams واضح ال bending moment هنا maximum هنا ال
+
+406
+00:47:35,430 --> 00:47:41,270
+bending moment maximum لأ باينة .. باين عندك يعني
+
+407
+00:47:41,270 --> 00:47:45,090
+باينة بالنظر أن هو هذا اللي .. اللي بيكون ال
+
+408
+00:47:45,090 --> 00:47:47,870
+highest stressed element يعني أنا مثلا بضغط هنا
+
+409
+00:47:47,870 --> 00:47:52,450
+تتوقع هنا يكون critical أكثر من هنا اكيد لو هذا
+
+410
+00:47:52,450 --> 00:47:53,950
+يصير كسر هيسيه في المنطقة هذه
+
+411
+00:47:59,180 --> 00:48:06,300
+يعني هذا cantilevered و torsioned يعني كأنه أنا
+
+412
+00:48:06,300 --> 00:48:10,620
+معلق فيه من هنا و من هنا يعني مدة هذه عن جهة هنا
+
+413
+00:48:10,620 --> 00:48:15,120
+كمان فيه كأنه فيه وزن هنا cantilever و هذه عاملة
+
+414
+00:48:15,120 --> 00:48:18,000
+ايه ايش torsion فهتكون هذه ايه ايش فعلا هو هذا ال
+
+415
+00:48:18,000 --> 00:48:23,180
+critical limit لما
+
+416
+00:48:23,180 --> 00:48:29,390
+نرسم more circle ال center بتاع more circle بيكون
+
+417
+00:48:29,390 --> 00:48:31,970
+ات sigma X على sigma Y على اثنين فمش عندي غير sigma X
+
+418
+00:48:31,970 --> 00:48:37,650
+هكون عندي 47.106 على اثنين
+
+419
+00:48:37,650 --> 00:48:46,110
+يعني هيكون 23.5
+
+420
+00:48:46,110 --> 00:48:49,150
+خمسة
+
+421
+00:48:49,150 --> 00:48:53,270
+ثلاثة kilo pound
+
+422
+00:48:56,050 --> 00:49:01,370
+و ال radius تعالى more circle رح تكون R جذر
+
+423
+00:49:01,370 --> 00:49:05,990
+التربيع ل sigma X ناقص sigma Y على اتنين كل تربيع
+
+424
+00:49:05,990 --> 00:49:10,650
+زائد تاو XY تربيع اللي هتكون اللي هي ثلاثة و عشرين
+
+425
+00:49:10,650 --> 00:49:16,890
+point خمسة خمسة ثلاثة تربيع زائد أربعة عشر point
+
+426
+00:49:16,890 --> 00:49:24,630
+أربعة تسعة أربعة تربيع حسبنا ال radius بعدين بحسب
+
+427
+00:49:24,630 --> 00:49:31,880
+ال sigma السبعة و أربعين كم سبعة و أربعين أعطيني
+
+428
+00:49:31,880 --> 00:49:37,080
+ثلاثة ثلاثة دسمية السبعة و أربعين كيلو
+
+429
+00:49:37,080 --> 00:49:44,900
+pound per square inch طيب
+
+430
+00:49:44,900 --> 00:49:52,340
+ال sigma واحد هتكون C زائد R صح يعني هتكون ثلاثة و
+
+431
+00:49:52,340 --> 00:49:57,560
+عشرين point خمسة خمسة ثلاثة زي السبعين point
+
+432
+00:49:57,560 --> 00:50:06,920
+ستة خمسة خمسة أشبعوا واحد و خمسين point اتنين
+
+433
+00:50:06,920 --> 00:50:12,420
+sigma
+
+434
+00:50:12,420 --> 00:50:19,280
+اثنين C ناقص R اللي هو عندك ثلاثة و عشرين point خمسة
+
+435
+00:50:19,280 --> 00:50:25,160
+خمسة ثلاثة ناقص سبعة عشرين point ستة خمسة خمسة
+
+436
+00:50:25,160 --> 00:50:33,140
+سالب
+
+437
+00:50:33,140 --> 00:50:37,460
+أربعة point مائة و اثنين سالب أربعة point مائة و
+
+438
+00:50:37,460 --> 00:50:43,440
+اثنين kilopound per square inch معناته ال tau max
+
+439
+00:50:45,820 --> 00:50:49,360
+اللي هو oriented plus or minus خمسة و أربعين درجة
+
+440
+00:50:49,360 --> 00:50:51,280
+من ال planes اللي بتأثر على سيجما واحد و سيجما
+
+441
+00:50:51,280 --> 00:50:58,100
+اثنين بيساوي سيجما واحد ناقص سيجما اثنين على
+
+442
+00:50:58,100 --> 00:51:04,260
+اثنين اللي هتكون واحد و خمسين اللي هي هتكون أىش بتطلع
+
+443
+00:51:04,260 --> 00:51:10,320
+سبعة عشرين point ستة خمسة خمسة kilo pound per
+
+444
+00:51:10,320 --> 00:51:12,940
+square inch لما أجري some more circle
+
+445
+00:51:21,530 --> 00:51:30,250
+أول نقطة عندي سيجما X و هاد Clockwise يعني هاد كله
+
+446
+00:51:30,250 --> 00:51:35,090
+أعلى هذه نقطة نقطة بين صفر و ال counter
+
+447
+00:51:35,090 --> 00:51:39,390
+clockwise واصل
+
+448
+00:51:39,390 --> 00:51:46,490
+بينهم هاد ال center هاد
+
+449
+00:51:46,490 --> 00:51:58,220
+سيجما واحد و هاد سيجما اثنين الزاوية هادي اللي هو
+
+450
+00:51:58,220 --> 00:52:05,080
+اثنين فاي بي تان اثنين
+
+451
+00:52:05,080 --> 00:52:13,220
+فاي بي هتساوض له هادي اللي هو تاو اكس واي تاو اكس
+
+452
+00:52:13,220 --> 00:52:13,580
+واي
+
+453
+00:52:16,580 --> 00:52:25,280
+توزيد 14.494
+
+454
+00:52:25,280 --> 00:52:32,280
+على سيجما
+
+455
+00:52:32,280 --> 00:52:39,420
+X على 2 47 على 2 هو 23
+
+456
+00:52:41,700 --> 00:52:50,360
+point خمسة خمسة ثلاثة ومنها بحسب في بي يعني بحسب زو
+
+457
+00:52:50,360 --> 00:52:57,600
+حد وبعدين أقسمه على اثنين أكتر بتطلع؟
+
+458
+00:52:57,600 --> 00:53:02,680
+يعني الاثنين ضياءك أكتر تطلع من تقسيم الاثنين 15.8
+
+459
+00:53:02,680 --> 00:53:05,840
+معناته
+
+460
+00:53:05,840 --> 00:53:06,920
+من ال element هذا
+
+461
+00:53:11,230 --> 00:53:17,430
+هنمشي أنا من هذا طبعا هذا يمثل هذا ايش هذا ال X
+
+462
+00:53:17,430 --> 00:53:25,230
+Axis وهذا سميه ال Y Axis بدك ايه او زي ده هاي Y
+
+463
+00:53:25,230 --> 00:53:31,130
+Axis أنا هتحلف من ال X Axis باتجاه عقارب الساعة 15
+
+464
+00:53:31,130 --> 00:53:40,110
+.8 هاي ال X Axis هتحلف من الزاوية 15.8
+
+465
+00:53:41,980 --> 00:53:48,700
+هرسم element هي
+
+466
+00:53:48,700 --> 00:53:54,440
+sigma واحد وهي
+
+467
+00:53:54,440 --> 00:54:06,260
+sigma اثنين طيب
+
+468
+00:54:06,260 --> 00:54:10,220
+عشان أجيب ال maximum share stress هي tau maximum
+
+469
+00:54:21,270 --> 00:54:29,970
+Half plus or minus 45 من هذا الاتجاه يعني هروح 45
+
+470
+00:54:29,970 --> 00:54:32,190
+زي هيك يعني هسير هنا
+
+471
+00:54:39,940 --> 00:54:46,320
+إذا هاروح في عكس عقارب الساعة الخمسة و أربعين هيكون
+
+472
+00:54:46,320 --> 00:54:55,000
+هاداش clockwise هيكون عنده زي هيك
+
+473
+00:54:55,000 --> 00:54:58,460
+اللي هو ال tau maximum اللي هو هذا سبعة shape one
+
+474
+00:54:58,460 --> 00:55:05,200
+ستة خلال ال tau هذا الزاوية خمسة و أربعين هذا هو ال
+
+475
+00:55:05,200 --> 00:55:18,120
+max و برضه في حيكون عنده اللي هو سيجما
+
+476
+00:55:18,120 --> 00:55:21,940
+سيجما
+
+477
+00:55:21,940 --> 00:55:30,400
+اللي هو اللي هي هذه هتكون في الحالة دي sigma ع
+
+478
+00:55:30,400 --> 00:55:36,360
+اثنين sigma xz على اثنين لأن هذا يتساوى ال C يعني
+
+479
+00:56:24,630 --> 00:56:31,650
+طيب هيكون حلينا المسألة بشكل اكتر ما هو مطلوب
+
+480
+00:56:31,650 --> 00:56:39,970
+انحل
+
+481
+00:56:39,970 --> 00:56:44,390
+المثال ثاني a one point five inch diameter solid
+
+482
+00:56:44,390 --> 00:56:47,350
+steel shaft
+
+483
+00:56:48,780 --> 00:56:55,920
+عندي شافت هين عليها بكرتين هي بكرة و بكرة البكرة
+
+484
+00:56:55,920 --> 00:57:01,680
+دي قطرها أربع انش البكرة دي قطرها ثمانية انش لأن
+
+485
+00:57:01,680 --> 00:57:06,160
+هاي الحبل بتاع البكرة الشد الشد في الحبل بتاع
+
+486
+00:57:06,160 --> 00:57:11,040
+البكرة بيكون نفس الشد و لا بتلفش فعندي هين الشد
+
+487
+00:57:11,040 --> 00:57:15,600
+الـ 500 pound ع الطرف الثاني 2000 pound عند البكرة
+
+488
+00:57:15,600 --> 00:57:20,000
+التانية فيه على الطرف هذا 500 باوند والشد على
+
+489
+00:57:20,000 --> 00:57:25,720
+الطرف الثاني من الحبل 100 باوند الشافت طوله عشرة و
+
+490
+00:57:25,720 --> 00:57:32,460
+عشرة و عشرين و ثلاثين انش simply supported عند a و
+
+491
+00:57:32,460 --> 00:57:38,000
+d هاي ال x axis و y axis و z axis
+
+492
+00:57:47,040 --> 00:57:52,600
+considering bending and torsion stresses only
+
+493
+00:57:52,600 --> 00:57:57,900
+هنهمل transverse shear stress determine locations
+
+494
+00:57:57,900 --> 00:58:01,660
+and magnitudes of the greatest tensile compressive
+
+495
+00:58:01,660 --> 00:58:09,140
+and shear stresses in the shaft مثلا
+
+496
+00:58:09,140 --> 00:58:13,340
+زي هيك لازم آخذ free pedagram لازم أولا أعمل force
+
+497
+00:58:13,340 --> 00:58:14,080
+analysis
+
+498
+00:58:26,810 --> 00:58:33,050
+سأعمل في مستويات في الـ XY Plane يوجد طريقة ثانية
+
+499
+00:58:33,050 --> 00:58:36,470
+يمكنني أن أعمل نفسي طريقة الكتاب باشتغال مستويات
+
+500
+00:58:36,470 --> 00:58:39,930
+أو
+
+501
+00:58:39,930 --> 00:58:45,530
+أشتغل الـ 3D مباشرة يعني آخذ summation of forces
+
+502
+00:58:45,530 --> 00:58:49,490
+باتجاه ال X و Y و Z و آخذ summation of moment
+
+503
+00:58:49,490 --> 00:58:53,590
+حول اي نقطة مثلا نقطة A و منها أودي ال reaction
+
+504
+00:58:53,590 --> 00:58:53,930
+force
+
+505
+00:58:56,630 --> 00:59:04,550
+and a و reactions and d لأن هاخد حشة على اللي آخذ
+
+506
+00:59:04,550 --> 00:59:08,370
+أشد في المستوى في ال XY plane و ال XZ plane لما
+
+507
+00:59:08,370 --> 00:59:14,030
+نطلع ال XY plane هدول مش هيبينه هيبين انداش
+
+508
+00:59:14,030 --> 00:59:22,030
+الخمسمية و المية لما أنقلهم على النص في
+
+509
+00:59:22,030 --> 00:59:27,930
+ال XY plane هذا هتكون خمسمية و مية هتصير ستمية في
+
+510
+00:59:27,930 --> 00:59:33,450
+النص الخمسمية بتعمل moment خمسمية هذا القطر ثمانية
+
+511
+00:59:33,450 --> 00:59:38,770
+انش مص القطر أكام أربعة أربعة هذا هتعمل خك يعني
+
+512
+00:59:38,770 --> 00:59:45,790
+هتعمل خمسمية في أربعة ناقص مية في أربعة يعني ألف و
+
+513
+00:59:45,790 --> 00:59:50,150
+ستمية فهو
+
+514
+00:59:50,150 --> 00:59:55,770
+عمل في الأولش 3D ناقل ال forces يعني لما نقل عند
+
+515
+00:59:55,770 --> 01:00:01,930
+هذه هتكون 2000 زي ألف هتيجي في النص ألف و 2000 هذه
+
+516
+01:00:01,930 --> 01:00:05,330
+قطرها أربع انش يعني نص القطر اثنين انش يعني ألف في
+
+517
+01:00:05,330 --> 01:00:12,330
+اثنين ناقص 2000 في اثنين يعني ألف و ستمية هيكون يعني
+
+518
+01:00:12,330 --> 01:00:17,890
+عند هنا ألف و 2000 ألف و 2000 انتبهوا ال ألف أكتر
+
+519
+01:00:17,890 --> 01:00:25,300
+تعمل تورجن بالشكل هذا ف ..هيها فعلا بهذا الاتجاه
+
+520
+01:00:25,300 --> 01:00:30,800
+لدي ألف و 2000 high force و فيه dictatorial ألف
+
+521
+01:00:30,800 --> 01:00:36,740
+و ستمية التانية الخمسمية
+
+522
+01:00:36,740 --> 01:00:40,880
+بهذا الاتجاه positive x axis خمسمية في أربعة ناقص
+
+523
+01:00:40,880 --> 01:00:45,480
+مية في أربعة ألف و ستمية بس الاتجاه مش المعاكس اللي
+
+524
+01:00:45,480 --> 01:00:49,740
+هو باتجاه positive x axis و خمسمية زي المية هي
+
+525
+01:00:49,740 --> 01:00:58,110
+ستمية اللي عندما آخذ ال X Y Plane للشافت هاي ال X و
+
+526
+01:00:58,110 --> 01:01:04,670
+هاي ال Y هيبين عندي بس رد الفعل باتجاه ال Y عند A
+
+527
+01:01:04,670 --> 01:01:09,150
+و رد الفعل باتجاه ال Y عند D و هيبين عندي 600 لتحت
+
+528
+01:01:09,150 --> 01:01:13,070
+زاد في عندي ال torsion مش هتأثر على summation of
+
+529
+01:01:13,070 --> 01:01:20,730
+forces فهيكون بال X Y Plane عندي دي رجع كمرة هاي
+
+530
+01:01:20,730 --> 01:01:28,470
+بال X Y plane هتبين بس هذه ستمية هاي الستمية و هاد
+
+531
+01:01:28,470 --> 01:01:40,130
+أنا هسميها R A Y هاي A هاي عندك B هاي C هاي D يعني
+
+532
+01:01:40,130 --> 01:01:46,430
+هاندي هكون R A Y عندي هاد R
+
+533
+01:01:53,950 --> 01:02:00,170
+بر DY لو أخذت ال moment حوالين C عشان أحسب ال
+
+534
+01:02:00,170 --> 01:02:07,150
+forces صممش ال moment حوالين A حل
+
+535
+01:02:07,150 --> 01:02:12,710
+الشغل بال XY plane صممش
+
+536
+01:02:12,710 --> 01:02:23,150
+ال moment حوالين A بيساوي 0 هتكون ناقص ستمية في
+
+537
+01:02:23,150 --> 01:02:28,190
+عشرين زائد
+
+538
+01:02:28,190 --> 01:02:37,130
+R دي واي في ثلاثين تطلع
+
+539
+01:02:37,130 --> 01:02:44,110
+عند ر دي واي ستمية في عشرين اثنا عشر الف ع ثلاثين
+
+540
+01:02:44,110 --> 01:02:44,790
+أربعة مليون
+
+541
+01:02:48,780 --> 01:02:55,960
+بعدين summation لل forces باتجاه ال Y بيساوي صفر
+
+542
+01:02:55,960 --> 01:03:06,140
+بيساوي RAY ناقص مية زائد RDY اللي هي أربعمية
+
+543
+01:03:06,140 --> 01:03:16,420
+معناته RAY بيساوي 2000 pound صحيح مطلع وبعدين بعمل
+
+544
+01:03:16,420 --> 01:03:22,820
+ال shear diagram بعمل ال shear diagram
+
+545
+01:03:22,820 --> 01:03:30,660
+حيكون الشكل هذا shear
+
+546
+01:03:30,660 --> 01:03:40,920
+diagram عندي 200 هذه
+
+547
+01:03:40,920 --> 01:03:50,550
+200 وهذه سالب 400 صح؟ ال moment diagram هنكون عنده
+
+548
+01:03:50,550 --> 01:03:57,910
+2000 في عشرين أربعة
+
+549
+01:03:57,910 --> 01:04:06,290
+ألف يعني عندهين أربعة ألف pound inch ناقص أربعمائة
+
+550
+01:04:06,290 --> 01:04:10,170
+و عشرة بيساوي هذا هو ال moment diagram
+
+551
+01:04:13,960 --> 01:04:17,700
+هذا في ال X Y plane اللي هي ال moment diagram في
+
+552
+01:04:17,700 --> 01:04:23,320
+ال X Y plane طبعا هذا ال moment هتكون باتجاه ال Z
+
+553
+01:04:23,320 --> 01:04:32,400
+لأن هاي ال forces بتعمل في المحور هتكون moment حول
+
+554
+01:04:32,400 --> 01:04:36,060
+المحور العمودي على ال X Y plane فهذا هتكون MZ
+
+555
+01:04:36,060 --> 01:04:39,140
+moment
+
+556
+01:04:39,140 --> 01:04:47,930
+diagram لو أخذت ال XZ plane هاي ال XZ plane هاي ال
+
+557
+01:04:47,930 --> 01:04:52,930
+X في هذا الاتجاه و ال Z لتحت هيكون في عندي RAZ
+
+558
+01:04:52,930 --> 01:05:01,770
+وعندي RDZ وعندي باتجاه ال positive Z اللي هي 1200
+
+559
+01:05:01,770 --> 01:05:07,430
+عشان نذكر هاي
+
+560
+01:05:07,430 --> 01:05:08,990
+ال Z axis موجب لتحت 
+
+561
+01:05:14,760 --> 01:05:19,560
+هذا الـ z-axis موجب
+
+562
+01:05:19,560 --> 01:05:23,440
+لتحت الـ 
+
+563
+01:05:23,440 --> 01:05:26,080
+1000 باتجاه الـ positive z-axis  هياكسه
+
+564
+01:05:26,080 --> 01:05:33,360
+reactions معاكسية للفرصة هذه هكون هذه raz و rdz
+
+565
+01:05:33,360 --> 01:05:39,100
+بنفس الطريقة عندي
+
+566
+01:05:39,100 --> 01:05:45,540
+هذه الـ 1000 هاخد moment حوالين a هكون 1000
+
+567
+01:05:45,540 --> 01:05:50,400
+.. minus 1000 في عشرة زاد 400 في 30
+
+568
+01:05:50,400 --> 01:05:57,040
+زاد .. زاد 30 في RDZ و من هنا بحثوا RDZ ال
+
+569
+01:05:57,040 --> 01:06:03,620
+Z بيساوي 1000 في 3 على 1000 في 
+
+570
+01:06:03,620 --> 01:06:10,980
+3 .. في 10 على 30 تطلع 400 بعدين
+
+571
+01:06:10,980 --> 01:06:16,080
+summation لل force باتجاه ال Z بيساوي Zero هكون دي
+
+572
+01:06:16,080 --> 01:06:22,940
+1000 ناقص RAZ ناقص RDZ و أنا بحصل RAZ تطلعيش 
+
+573
+01:06:22,940 --> 01:06:26,340
+800 بعدين بعمل shear diagram
+
+574
+01:06:41,690 --> 01:06:47,250
+هذه ستكون 800 وهنا
+
+575
+01:06:47,250 --> 01:06:56,090
+سالب 400 صح 800 في 10 عايز 8000 نقص 
+
+576
+01:06:56,090 --> 01:07:01,390
+400 في 20 بتسفر لأن صار عند ال moment
+
+577
+01:07:01,390 --> 01:07:05,990
+diagram ال moment diagram صار في المستوين في ال
+
+578
+01:07:05,990 --> 01:07:10,350
+exit plane هاي
+
+579
+01:07:10,350 --> 01:07:10,870
+ال moment diagram
+
+580
+01:07:14,710 --> 01:07:23,630
+في ال X Y plane هاي ال moment diagram في ال X Z 
+
+581
+01:07:23,630 --> 01:07:33,130
+plane في ال X Y plane ال moment نقسمه 
+
+582
+01:07:33,130 --> 01:07:42,610
+لـ 3 أقسام في
+
+583
+01:07:42,610 --> 01:07:43,490
+ال X Y plane
+
+584
+01:07:50,470 --> 01:07:58,770
+هندي a,b,c,d هندهين 4000 هين هتكون طبعا نصها
+
+585
+01:07:58,770 --> 01:08:03,270
+هتكون هين 2000 هذا في ال X Y plane في ال X Z
+
+586
+01:08:03,270 --> 01:08:07,510
+plane اللي 
+
+587
+01:08:07,510 --> 01:08:16,550
+هو هيكون 8000 8000 جاي هين هين
+
+588
+01:08:16,550 --> 01:08:18,010
+هتكون 8000
+
+589
+01:08:20,690 --> 01:08:27,570
+و هين هتكون ايش 4000 مانعته
+
+590
+01:08:27,570 --> 01:08:32,810
+مش عارف مين most critical ال total moment عند بي م
+
+591
+01:08:32,810 --> 01:08:43,610
+بي هتكون جذر التربيعي لـ 2000 تربيع زي 8000 تربيع 
+
+592
+01:08:43,610 --> 01:08:54,020
+تربيعي أما عند سيهتكون جذر التربيعي ايه؟ 4000
+
+593
+01:08:54,020 --> 01:08:59,800
+تربيعي واضح
+
+594
+01:08:59,800 --> 01:09:07,280
+أن B more critical than C صح؟ لأن هندي يعني ..
+
+595
+01:09:07,280 --> 01:09:10,340
+يعني أكيد هذه أكبر أن هذه هتطلع أكثر من 8000 
+
+596
+01:09:10,340 --> 01:09:14,040
+هذه هتطلع 4000 5000 600 يمكن تطلع وش زي
+
+597
+01:09:14,040 --> 01:09:24,390
+هيك هتطلع أكثر من 8000 و متين هتكون عندي هذا 
+
+598
+01:09:24,390 --> 01:09:34,010
+بالنسبة لل بنجم بالنسبة لل تورجين بتبدأ تصبح 
+
+599
+01:09:34,010 --> 01:09:37,970
+resistance يعني لأن ال load يعني عندي مثلا ال
+
+600
+01:09:37,970 --> 01:09:42,610
+انبوت جاي هنا و ال load هنا مثلا جاي مصدر هين من
+
+601
+01:09:42,610 --> 01:09:47,210
+الموتور و هنا بتحميل ال load معناته على الشمال ال
+
+602
+01:09:47,210 --> 01:09:53,140
+B فيش تورجين مش مقاومة لكن على يمينها في مقاومة 
+
+603
+01:09:53,140 --> 01:09:59,520
+التورجن هنحسبه ال torque يعني ال most critical
+
+604
+01:09:59,520 --> 01:10:09,420
+location most critical location is
+
+605
+01:10:09,420 --> 01:10:20,570
+at B plus at B plus يعني عند at X بالساوية 10
+
+606
+01:10:20,570 --> 01:10:26,950
+plus هذا
+
+607
+01:10:26,950 --> 01:10:32,110
+هو ال most critical location لو بدي ارسم المقطع
+
+608
+01:10:32,110 --> 01:10:36,130
+عند B عند B هيكون عند هاي ال Y و Z axis
+
+609
+01:10:49,830 --> 01:11:08,850
+and b ها
+
+610
+01:11:08,850 --> 01:11:14,050
+هي ال y axis وها
+
+611
+01:11:14,050 --> 01:11:14,930
+هي ال z axis
+
+612
+01:11:24,590 --> 01:11:32,590
+في ال X Y plane في ال X Y plane هي يصير bending
+
+613
+01:11:32,590 --> 01:11:36,510
+بهذا الاتجاه لو طلعت فقط على هذا الاتجاه هي يكون
+
+614
+01:11:36,510 --> 01:11:43,930
+سطحي له هنا اندي هنا compression compression
+
+615
+01:11:43,930 --> 01:12:00,850
+وهنا tension هذا ال U to Mz du to m z صح وهذا du
+
+616
+01:12:00,850 --> 01:12:04,530
+to
+
+617
+01:12:04,530 --> 01:12:14,250
+mz باتجاه ال y في
+
+618
+01:12:14,250 --> 01:12:18,770
+ال xz plane هكون
+
+619
+01:12:18,770 --> 01:12:21,770
+دي هذا my هيكون
+
+620
+01:12:24,080 --> 01:12:29,360
+هذه هتكون compression وهذه
+
+621
+01:12:29,360 --> 01:12:36,120
+ايش هتكون tension هذه
+
+622
+01:12:36,120 --> 01:12:40,460
+due to
+
+623
+01:12:40,460 --> 01:12:49,960
+my وهذه due to
+
+624
+01:12:49,960 --> 01:13:11,590
+my لو بدي ارسم a distribution from U to MZ هكون
+
+625
+01:13:11,590 --> 01:13:20,250
+دي هين compression وهين
+
+626
+01:13:20,250 --> 01:13:20,690
+tension
+
+627
+01:13:23,510 --> 01:13:28,030
+and bending normal
+
+628
+01:13:28,030 --> 01:13:31,430
+bending
+
+629
+01:13:31,430 --> 01:13:35,990
+stress
+
+630
+01:13:35,990 --> 01:13:46,810
+due to mz لو اطلع هنا due to my
+
+631
+01:14:23,050 --> 01:14:32,110
+هنا هن compression هن عشر tension هن tension هن
+
+632
+01:14:32,110 --> 01:14:40,330
+compression هن bending normal bending
+
+633
+01:14:40,330 --> 01:14:47,230
+stress due
+
+634
+01:14:47,230 --> 01:14:49,610
+to my
+
+635
+01:15:03,700 --> 01:15:14,160
+الـ .. bending moment أنا
+
+636
+01:15:14,160 --> 01:15:23,780
+عندي هاي الـ my عندي الـ 8000 يعني
+
+637
+01:15:23,780 --> 01:15:30,480
+هكون عندي two locations هذه .. هذه في bending
+
+638
+01:15:30,480 --> 01:15:31,600
+moment بهذا الاتجاه
+
+639
+01:15:38,630 --> 01:15:45,730
+وهذا فيه bending moment بهذا الاتجاه فهذه قيمتها
+
+640
+01:15:45,730 --> 01:15:55,010
+8000 حوالي ال y axis وحوالي ال z axis أكثر 2000 
+
+641
+01:15:55,010 --> 01:16:00,910
+المحصلة بتاعتهم هتكون هذه المحصلة بتاعتهم
+
+642
+01:16:00,910 --> 01:16:09,060
+انتبهوا لما أنا طلع مثلا على حالة الـ MZ هي الـ MZ
+
+643
+01:16:09,060 --> 01:16:16,500
+بيكون عندهين compression و tension يعني على جنابه
+
+644
+01:16:16,500 --> 01:16:20,860
+up and down بيكون عنده compression و tension مش
+
+645
+01:16:20,860 --> 01:16:24,040
+مهم كتير بس أن ال maximum should be up and down
+
+646
+01:16:24,040 --> 01:16:32,000
+فهي المحصلة هذه هي المحصلة معناته أنا هروح up and
+
+647
+01:16:32,000 --> 01:16:33,240
+down هروح 90 درجة
+
+648
+01:16:36,950 --> 01:16:40,850
+هنا بيكون عندي ايش؟ compression maximum
+
+649
+01:16:40,850 --> 01:16:47,990
+compression وهنا بيكون maximum tension معناه تحسب
+
+650
+01:16:47,990 --> 01:16:53,330
+ال total moment أنا حسبت ال total moment اللي هي M
+
+651
+01:16:53,330 --> 01:17:00,770
+الكلية جذر التربيعي لـ 2000 تربيع زي 8000 تربيع 
+
+652
+01:17:09,580 --> 01:17:15,640
+8000 و 46 pound inch لأن
+
+653
+01:17:15,640 --> 01:17:28,840
+الزاوية هذه هسميها theta تان انفرس 8000 على 
+
+654
+01:17:28,840 --> 01:17:34,100
+2000 76 درجة
+
+655
+01:17:36,650 --> 01:17:41,330
+معناته هذا هتكون هذا 
+
+656
+01:17:41,330 --> 01:17:52,110
+برضه هتكون theta صح الـ
+
+657
+01:17:52,110 --> 01:18:03,950
+sigma normal stress هتكون M لأن هذا مدور مختلف لأن
+
+658
+01:18:03,950 --> 01:18:12,360
+هذا مدور بس يروح يقول أنه M في C على I يعني أنا 
+
+659
+01:18:12,360 --> 01:18:21,760
+هتكون تساوي 32 M على I دي تكيب يعني 
+
+660
+01:18:21,760 --> 01:18:26,140
+32 في 8046
+
+661
+01:18:26,140 --> 01:18:29,720
+على دي القطر تعالى شفت كم اعطينيها
+
+662
+01:18:39,740 --> 01:18:51,120
+1.5 انش على 1.5 انش بحسب
+
+663
+01:18:51,120 --> 01:18:55,960
+اللعب ال stress 4
+
+664
+01:18:55,960 --> 01:18:59,640
+20000 psi
+
+665
+01:18:59,640 --> 01:19:02,300
+بيرس كور انش التورجن
+
+666
+01:19:04,340 --> 01:19:08,560
+الساقو اللي هي الـ T في R على J هو شرس ال duty
+
+667
+01:19:08,560 --> 01:19:17,940
+torsion هتكون 16 T على Pi دي تكيب هتكون 16 
+
+668
+01:19:17,940 --> 01:19:28,720
+ال torque 600 على Pi في 1.5 تكيب
+
+669
+01:19:34,710 --> 01:19:40,350
+نعم 2416 2416
+
+670
+01:19:40,350 --> 01:19:45,410
+16 هذا 
+
+671
+01:19:45,410 --> 01:19:49,130
+الرقم غلط هذا 
+
+672
+01:19:49,130 --> 01:19:54,670
+2416 هذا 
+
+673
+01:19:54,670 --> 01:20:01,390
+صح الرقم هيك فرق نص يعني مش فارق لأ بحكيش عن نص 
+
+674
+01:20:01,390 --> 01:20:03,490
+أنا تمام نص الرقم هذا صح 
+
+675
+01:20:06,490 --> 01:20:12,110
+يعني هذا تقريبا .. هذا 5 أضعاف الرقم هذا 5 ..
+
+676
+01:20:12,110 --> 01:20:14,650
+يعني هتضرب هذا في 10 .. خلاص صح .. صح الرقم 10
+
+677
+01:20:14,650 --> 01:20:20,390
+4 .. صح .. صحيح الرقم صحيح خلاص .. هيك صح طيب 
+
+678
+01:20:20,390 --> 01:20:28,810
+طبعا ك stress element احنا اخذنا عند B plus يعني B
+
+679
+01:20:28,810 --> 01:20:30,330
+plus
+
+680
+01:20:35,700 --> 01:20:40,200
+يعني هكون stress element مش شكل هذا هنا لأ الـ 
+
+681
+01:20:40,200 --> 01:20:44,880
+torsion وين ما تدور نفس الاشي يعني لو أنا لفت 
+
+682
+01:20:44,880 --> 01:20:49,460
+الشرط ازاي و هيك و رجعته و حطيته هنا ماتتريجش معايا
+
+683
+01:20:49,460 --> 01:20:53,800
+واضح أنا عندي torsion فال element لو اخده عند B
+
+684
+01:20:53,800 --> 01:20:57,860
+plus هكون شكل ال element
+
+685
+01:21:18,530 --> 01:21:27,950
+هذه ال X Axis وهذه ال Z وهذه ال Y سيكون السيجما
+
+686
+01:21:27,950 --> 01:21:38,810
+اللي طلعتها سيجما
+
+687
+01:21:38,810 --> 01:21:40,730
+سيكون طبعا
+
+688
+01:21:45,630 --> 01:21:49,710
+في شيريس فعلا في ال two d's هكون two d's تت يعني
+
+689
+01:21:49,710 --> 01:22:00,630
+هكون عندي هي سيجما برضه 
+
+690
+01:22:00,630 --> 01:22:04,210
+من more circle بحسب سيجما 1 برصم more circle
+
+691
+01:22:04,210 --> 01:22:08,690
+بحسب سيجما 1 سيجما 2 أو تاو maximum يعني
+
+692
+01:22:08,690 --> 01:22:16,830
+هذا ال maximum أو ال most critical Element بالنسبة
+
+693
+01:22:16,830 --> 01:22:19,690
+لما هو الإحداثيات ال absolute coordinate system
+
+694
+01:22:19,690 --> 01:22:25,250
+اللي أنا حاطبها لكن this is not the most critical
+
+695
+01:22:25,250 --> 01:22:28,250
+orientation مش ال most critical orientation most 
+
+696
+01:22:28,250 --> 01:22:31,910
+critical orientation بوجده من خلال اللي هو ال more
+
+697
+01:22:31,910 --> 01:22:34,490
+circle بحث ال for instance ال sigma 1 و sigma 
+
+698
+01:22:34,490 --> 01:22:37,810
+2 و sigma 3 و tau max
+
+699
+01:22:46,340 --> 01:22:49,400
+هيك نكون خلصنا المحاضرة، طيب ولا عارف؟
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/-qkT9mZsHSE_raw.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/-qkT9mZsHSE_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..192914d9dbf97e064939d88dd5074241bfd2f23c
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/-qkT9mZsHSE_raw.srt
@@ -0,0 +1,2852 @@
+1
+00:00:05,150 --> 00:00:08,250
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,250 --> 00:00:11,990
+وبركاته اليوم هنستكمل في chapter stress and load
+
+3
+00:00:11,990 --> 00:00:18,020
+analysis مادة تصميم الألوان واحدالمحاضرة السابقة
+
+4
+00:00:18,020 --> 00:00:22,100
+درستنا ال bending in straight beams درستنا ال
+
+5
+00:00:22,100 --> 00:00:25,640
+transfer shear stress in straight beams وحلينا
+
+6
+00:00:25,640 --> 00:00:29,660
+مجموعة من الأمثلة اليوم هنكمل في دراسة ال light
+
+7
+00:00:29,660 --> 00:00:36,300
+torsion هنبدأ أولا في ال round .. round rods بعدين
+
+8
+00:00:36,300 --> 00:00:40,740
+هنخش على أشكال تانية اللي هي المستطيل .. المستطيل
+
+9
+00:00:40,740 --> 00:00:47,890
+انفرغ .. ال .. أي شكل يكون غير مغلق مفتوحهنبدأ في
+
+10
+00:00:47,890 --> 00:00:52,770
+ال .. ال torsion في solid round bar انا عندى هنا
+
+11
+00:00:52,770 --> 00:01:08,290
+solid round bar مثبت من الطرف فيه
+
+12
+00:01:08,290 --> 00:01:13,410
+torque فيه torque بهذا الاتجاه
+
+13
+00:01:22,790 --> 00:01:26,090
+النتيجة ال torque هصير ال twist عند الخط هذا
+
+14
+00:01:26,090 --> 00:01:35,410
+النقطة a هذا النقطة c هصير
+
+15
+00:01:35,410 --> 00:01:41,270
+twist بزاوية
+
+16
+00:01:41,270 --> 00:01:46,010
+gamma
+
+17
+00:01:49,330 --> 00:01:59,990
+عندي هاي مركز ال رد هاد الزرع هتكون theta
+
+18
+00:01:59,990 --> 00:02:05,470
+ال
+
+19
+00:02:05,470 --> 00:02:16,190
+radius لل bar ال maximum radius اللي هو R عندي
+
+20
+00:02:16,190 --> 00:02:17,990
+هذا المحور الإحداثية X
+
+21
+00:02:22,290 --> 00:02:26,890
+هذا يحمر احداثيات Y
+
+22
+00:02:26,890 --> 00:02:36,670
+هذا
+
+23
+00:02:36,670 --> 00:02:44,190
+يحمر احداثيات Z ال
+
+24
+00:02:44,190 --> 00:02:50,330
+angle of twist θ يستوي ال torque في طول ال bar
+
+25
+00:02:56,490 --> 00:03:02,870
+على G في J جي اللى هى ال modulus of rigidity ال J
+
+26
+00:03:02,870 --> 00:03:07,390
+ال polar moment of inertia ال T ال torque و ال L
+
+27
+00:03:07,390 --> 00:03:12,570
+اللى هو طول ال bar و ال shear stress at any radius
+
+28
+00:03:12,570 --> 00:03:20,250
+ρ مواظبة
+
+29
+00:03:20,250 --> 00:03:25,470
+العلاقة تاو بسوا تي رو على جىالـ maximum shear
+
+30
+00:03:25,470 --> 00:03:27,490
+stress في حالة الـ torsion وين بيكون على الصفحة
+
+31
+00:03:27,490 --> 00:03:32,650
+الخارجية الـ tau max بالساوية T في R على J الـ R
+
+32
+00:03:32,650 --> 00:03:40,870
+هو نص قطب البر طبعا
+
+33
+00:03:40,870 --> 00:03:49,550
+المعادلات هذه مبنية على الفرضيات التالية أولا
+
+34
+00:03:49,550 --> 00:03:54,150
+شندي a pure torqueفيش any other type of loading بس
+
+35
+00:03:54,150 --> 00:03:59,190
+فقط عندي torque لان
+
+36
+00:03:59,190 --> 00:04:03,050
+بعيدا عن اي discontinuities or point of
+
+37
+00:04:03,050 --> 00:04:08,470
+application of torque material obeys hooks law
+
+38
+00:04:08,470 --> 00:04:16,990
+يعني تصرفها ال stress مع ال strain خطة
+
+39
+00:04:16,990 --> 00:04:20,350
+كتاب
+
+40
+00:04:28,570 --> 00:04:33,390
+adjacent cross sections originally plain and
+
+41
+00:04:33,390 --> 00:04:35,510
+parallel remain plain and parallel يعني دي هاي
+
+42
+00:04:35,510 --> 00:04:42,330
+عملت مقطع احيان في البداية قبل ال loading كان
+
+43
+00:04:42,330 --> 00:04:45,570
+مستوي و بعد ال loading بضله مستوي يعني بيطيارش
+
+44
+00:04:45,570 --> 00:04:47,710
+الاستواق في المقاطع
+
+45
+00:04:51,400 --> 00:04:58,720
+radial lines remain straight before
+
+46
+00:04:58,720 --> 00:05:08,440
+loading هذا هو ال radial line after loading ماصارش
+
+47
+00:05:08,440 --> 00:05:19,660
+curved لسه دلو ايش عدل المعادلات
+
+48
+00:05:19,660 --> 00:05:32,890
+اللي شفناهاتستخدم في حالة المقاطع اللي مدورة shear
+
+49
+00:05:32,890 --> 00:05:40,530
+stress does not vary linearly with
+
+50
+00:05:40,530 --> 00:05:48,450
+radial distance بتغيرش بشكل linear لأنه أنا في
+
+51
+00:05:48,450 --> 00:05:49,850
+الآخر أنا عند ال shear stress
+
+52
+00:05:54,560 --> 00:06:00,180
+حكيت تاوم ماكس بالساوية
+
+53
+00:06:00,180 --> 00:06:08,840
+ت في ر على ج بالساوية ت في القطر على اتنين على باي
+
+54
+00:06:08,840 --> 00:06:14,740
+على اربع ستين بايديوز اربعة
+
+55
+00:06:18,770 --> 00:06:27,050
+على اربع ستين يعني بصفة اتنين و تلاتين T على Pi T
+
+56
+00:06:27,050 --> 00:06:31,790
+تكبير هذه ال radial تغير مش linear معاها بال
+
+57
+00:06:31,790 --> 00:06:38,230
+maximum shear stress طبعا
+
+58
+00:06:38,230 --> 00:06:41,610
+لاحظوا الجملة هذه هو بيحكي فقط على maximum shear
+
+59
+00:06:41,610 --> 00:06:45,970
+stressلكن الـ shear stress at any other radius
+
+60
+00:06:45,970 --> 00:06:54,070
+بتغير linearly يعني بمعنى تاو بالثواب تي رو على جي
+
+61
+00:06:54,070 --> 00:06:59,770
+هذا constant وهذا constant لل last section اما رو
+
+62
+00:06:59,770 --> 00:07:06,250
+بتغير طيب
+
+63
+00:07:06,250 --> 00:07:15,770
+الحالة الجديدة عليك هوان المقطع يكون مستطيل اذا
+
+64
+00:07:15,770 --> 00:07:20,350
+كان عنده bar المقطع
+
+65
+00:07:20,350 --> 00:07:21,350
+كان مستطيل
+
+66
+00:07:40,700 --> 00:07:50,900
+هو عليه .. عليه torque .. عليه torque الضلع الطويل
+
+67
+00:07:50,900 --> 00:07:58,400
+هذا بي و الضلع التاني سي
+
+68
+00:08:07,010 --> 00:08:10,430
+طبعا نتيجة ال torque هصير فيه rotation، هصير فيه
+
+69
+00:08:10,430 --> 00:08:17,010
+twist الماكسوم مش هي ال stress أو maximum يقع طول
+
+70
+00:08:17,010 --> 00:08:24,290
+علاقة T على Alpha في B C تربيع أو نفسها T على B
+
+71
+00:08:24,290 --> 00:08:30,010
+تربيع في 3 زائد 1.8 على B على Cلأن في جدول عندى
+
+72
+00:08:30,010 --> 00:08:33,650
+ماتين ال ratio بي على سي بعد من واحد يعني المقطع
+
+73
+00:08:33,650 --> 00:08:40,090
+المربع بعدين صارت بي على سي الزيد يعني دايما ال بي
+
+74
+00:08:40,090 --> 00:08:44,010
+أكبر أو يساوي السي
+
+75
+00:08:46,650 --> 00:08:50,550
+for different P على C معطينا قيمة Alpha و Beta
+
+76
+00:08:50,550 --> 00:08:55,050
+Alpha يعني اذا P على C بيسوا واحد و نص هذا قيمة
+
+77
+00:08:55,050 --> 00:08:58,430
+Alpha point اتنين تلاتة واحد و Beta بيسوا point
+
+78
+00:08:58,430 --> 00:09:03,250
+واحد تسعة ستة و Theta بيسوا T في L على Beta P ستة
+
+79
+00:09:03,250 --> 00:09:08,270
+كيب في G ال T اللي هو ال torque ال L الطول تاع ال
+
+80
+00:09:08,270 --> 00:09:14,290
+bar ال Beta empirical constant او يوجد من الجدول
+
+81
+00:09:14,290 --> 00:09:19,280
+التحتالـ B هذا الارتفاع الـ C هذا الارتفاع الجي
+
+82
+00:09:19,280 --> 00:09:28,280
+الموديلوس of rigidity طيب
+
+83
+00:09:28,280 --> 00:09:37,920
+لأن وين في عندي torque وفي rotation معناته في عندي
+
+84
+00:09:37,920 --> 00:09:42,940
+transfer of power في انتقال للقدرة او الطاقة في
+
+85
+00:09:42,940 --> 00:09:47,940
+حالة ال metric unitال power بال وطء في علاقة بين
+
+86
+00:09:47,940 --> 00:09:50,580
+ال power وال torque والسرعة الزاوية ال power
+
+87
+00:09:50,580 --> 00:09:54,460
+بالساوية ال torque في omega ال torque واحدة تلت
+
+88
+00:09:54,460 --> 00:09:59,860
+نيوتن متر ال omega radians per second عند ال power
+
+89
+00:09:59,860 --> 00:10:06,520
+h بالساوية T في omega omega إذا كانت السرعة
+
+90
+00:10:06,520 --> 00:10:10,960
+المعطلة في عند ال n بال radians revolutions per
+
+91
+00:10:10,960 --> 00:10:18,270
+minute ال omega هتكون ال nفى اتنين باى على ستين
+
+92
+00:10:18,270 --> 00:10:23,670
+يعني
+
+93
+00:10:23,670 --> 00:10:30,490
+حسب ان ال power بالساوية H فى T فى N ال N بال RPM
+
+94
+00:10:30,490 --> 00:10:37,830
+فى اتنين باى على ستين يعني هتكون الساوية T فى N
+
+95
+00:10:37,830 --> 00:10:41,830
+لما نقسم ستين على اتنين باى بتعطينا تسعة point
+
+96
+00:10:41,830 --> 00:10:49,460
+خمسة خمسةيعني ال torque بالساعة وتسعة point خمسة
+
+97
+00:10:49,460 --> 00:10:56,820
+خمسة في ال power على انا وحدة ال and بال R يعني
+
+98
+00:10:56,820 --> 00:11:01,060
+هذا في حالة الوحدات المترية في حالة الوحدات
+
+99
+00:11:01,060 --> 00:11:06,000
+الإنجليزية ال
+
+100
+00:11:06,000 --> 00:11:10,980
+power هي المعطية بوحدة الحصان horse power ممكن
+
+101
+00:11:10,980 --> 00:11:19,130
+استخدم المعادلة هذهأو المعادلة هذه ال F هي ال
+
+102
+00:11:19,130 --> 00:11:24,650
+force force في السرعة بيعطينا إيش؟ power ال V
+
+103
+00:11:24,650 --> 00:11:30,370
+السرعة المحيطية وحدة ال feet per minute أو العلاقة
+
+104
+00:11:30,370 --> 00:11:37,970
+هذه ال T هو ال torque على الشافت بواحدة ال pound
+
+105
+00:11:37,970 --> 00:11:44,480
+per inch و ال N بواحدة ال RPMطب هو عامل تحويلات
+
+106
+00:11:44,480 --> 00:11:50,900
+مجهزة اذا ماكنت تحولوها لحق الكون نشوف
+
+107
+00:11:50,900 --> 00:12:02,660
+مثال عندي
+
+108
+00:12:02,660 --> 00:12:10,950
+crank ماناولا عبارة عن الدراع هذا مقطع مستطيلهذه
+
+109
+00:12:10,950 --> 00:12:16,910
+اليد ال handle و ال shaft هي مثبت في الحيطة يعني و
+
+110
+00:12:16,910 --> 00:12:21,050
+في load قيمته F بيأثر في الطرفة يعني انا بضغط
+
+111
+00:12:21,050 --> 00:12:29,670
+الشكل هذا لتحت معطين
+
+112
+00:12:29,670 --> 00:12:38,290
+ال F تلتمية pound force ال F بيستوى تلتمية pound
+
+113
+00:12:45,720 --> 00:12:57,780
+force الشافت دي تحت الشافت تلت ارباع انش تلت
+
+114
+00:12:57,780 --> 00:13:04,280
+ارباع انش draw
+
+115
+00:13:04,280 --> 00:13:11,050
+three body diagramsof the shaft a,b and arm a and
+
+116
+00:13:11,050 --> 00:13:16,390
+arm b,c نعمل three body diagram للشافت a,b
+
+117
+00:13:16,390 --> 00:13:24,890
+والادراع b,c compute
+
+118
+00:13:24,890 --> 00:13:30,790
+values of all forces moments and torques label
+
+119
+00:13:30,790 --> 00:13:33,790
+directions of current systems on these diagrams
+
+120
+00:13:33,790 --> 00:13:41,330
+تحط محاول إحداثيةيعني انا لو بدي ابدأ اخد الجزء
+
+121
+00:13:41,330 --> 00:13:54,930
+هذا اخد ال free pedagram لحاله طيب
+
+122
+00:13:54,930 --> 00:14:00,530
+لو بدي اخد الجزء هذا free pedagram لحاله اعمل قطع
+
+123
+00:14:00,530 --> 00:14:04,430
+يعني خلينا نحكي هذه المحاور عندى X
+
+124
+00:14:11,460 --> 00:14:16,680
+Y Z هاتبرك
+
+125
+00:14:16,680 --> 00:14:22,320
+على شكل خط عندي هنا عندي
+
+126
+00:14:22,320 --> 00:14:29,880
+خانيا A B C خانيا نسميها نقطة دي نقسمها D هاي C
+
+127
+00:14:29,880 --> 00:14:35,240
+هاي D هاي عندي ال X Axis
+
+128
+00:14:41,510 --> 00:14:46,610
+و هاي عندي ال y axis و
+
+129
+00:14:46,610 --> 00:14:50,650
+هاي عندي ال z axis
+
+130
+00:14:50,650 --> 00:14:57,990
+عندي بدي اعمل cut هن سيه عندي بتأث .. عندي بتأث ال
+
+131
+00:14:57,990 --> 00:15:04,650
+force F طالما
+
+132
+00:15:04,650 --> 00:15:07,510
+اعمل cut هكون عندي force معكسه
+
+133
+00:15:13,790 --> 00:15:21,190
+ف لحظة الف تعمل moment بتحاول تعمل lay باتجاه ال
+
+134
+00:15:21,190 --> 00:15:28,610
+negative z يعني بتحاول هي بتحاول تعمل bending بهذا
+
+135
+00:15:28,610 --> 00:15:33,350
+الاتجاه حوالي ال negative z من وقت ال reaction
+
+136
+00:15:33,350 --> 00:15:37,210
+moment هتكون عكسه من وقت هتكون في عندي reaction
+
+137
+00:15:37,210 --> 00:15:37,710
+moment
+
+138
+00:15:42,210 --> 00:15:50,250
+بدي استخدم سهمين بدي اسميها M1
+
+139
+00:15:50,250 --> 00:15:54,650
+طبعا
+
+140
+00:15:54,650 --> 00:16:02,790
+هنا ال F هتكون اللي هي نفسها تلت ميت فاوند ال
+
+141
+00:16:02,790 --> 00:16:09,070
+moment المسافة من هنا لهنا المسافة
+
+142
+00:16:09,070 --> 00:16:10,710
+من هنا لهنا واحد و نص انش
+
+143
+00:16:13,940 --> 00:16:18,700
+معناته M1 M1
+
+144
+00:16:18,700 --> 00:16:25,380
+هتكون تساوي واحد
+
+145
+00:16:25,380 --> 00:16:33,460
+و نص في تلت مية صح؟ واحد و نص في تلت مية في اتجاه
+
+146
+00:16:33,460 --> 00:16:36,920
+ال K يعني
+
+147
+00:16:36,920 --> 00:16:42,020
+اربعمية و خمسين اتجاه ال K اربعمية و خمسين pound
+
+148
+00:16:44,600 --> 00:16:52,120
+باتجاه الـ G لان هاخد ال free body ده يجي رقم لل
+
+149
+00:16:52,120 --> 00:17:00,020
+بي سي لان هاخد ال free body لل بي سي هعتبره هاي ال
+
+150
+00:17:00,020 --> 00:17:07,560
+بي سي هاي
+
+151
+00:17:07,560 --> 00:17:12,940
+ال C هاي ال B هذا هو ال Z axis
+
+152
+00:17:21,790 --> 00:17:33,870
+هذا ال X axis وهذا ال Y axis طيب
+
+153
+00:17:33,870 --> 00:17:50,270
+عن C هتكون في عندي F عكس هذه هعندي هنا F و
+
+154
+00:17:50,270 --> 00:17:50,970
+في عندي moment
+
+155
+00:17:55,220 --> 00:18:00,120
+عكس سادة هتكون لسه
+
+156
+00:18:00,120 --> 00:18:03,380
+مخلص باخد اللي هنا انا لسه انتظرت انتظرت انتظرت
+
+157
+00:18:03,380 --> 00:18:06,620
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+158
+00:18:06,620 --> 00:18:06,640
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+159
+00:18:06,640 --> 00:18:06,700
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+160
+00:18:06,700 --> 00:18:07,200
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+161
+00:18:07,200 --> 00:18:07,440
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+162
+00:18:07,440 --> 00:18:07,440
+انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت انتظرت
+
+163
+00:18:07,440 --> 00:18:23,860
+انتظرت انتظرت انتظرت انتظرت ان
+
+164
+00:18:24,260 --> 00:18:31,160
+بالنسبة ل cd bending moment لان هاي المقطع بتاعه
+
+165
+00:18:31,160 --> 00:18:34,820
+فبتحاول
+
+166
+00:18:34,820 --> 00:18:37,680
+تبقى ليه ال torsion فالtorsion عديه هتانه هي عكسه
+
+167
+00:18:37,680 --> 00:18:44,680
+هكون انديهين في
+
+168
+00:18:44,680 --> 00:18:46,220
+M1 عند B
+
+169
+00:18:51,640 --> 00:18:56,080
+ال F بتحاول تعمل
+
+170
+00:18:56,080 --> 00:19:02,520
+يعني هين بال نجم moment باتجاه ال negative x axis
+
+171
+00:19:02,520 --> 00:19:09,380
+يعني هي بشكلها ده ال reaction moment هكون عكسها
+
+172
+00:19:09,380 --> 00:19:18,080
+هكون ده هين ام اتنين
+
+173
+00:19:43,290 --> 00:19:49,950
+الان في كمان ال F حكينا هاي ال bending moment
+
+174
+00:19:49,950 --> 00:19:58,200
+بتاعتهاال ام اتنين ايش بالساوية؟
+
+175
+00:19:58,200 --> 00:20:07,600
+اللي هي ال F تلت مية في اربع انش بالساوية تلت مية
+
+176
+00:20:07,600 --> 00:20:12,100
+في اربع في اتجاه ال I
+
+177
+00:20:21,040 --> 00:20:25,360
+هذه reaction moment الآن ال force اف بتحاول تعمل
+
+178
+00:20:25,360 --> 00:20:30,340
+bending بهذا الاتجاه لان اللي هو فيه ال strength
+
+179
+00:20:30,340 --> 00:20:36,740
+هيقوى عشان قاوم ال moment اللي جا من هنا بال
+
+180
+00:20:36,740 --> 00:20:41,340
+negative x axis لازم ال moment بال positive axis
+
+181
+00:20:41,340 --> 00:20:46,220
+فهذه reaction moment فهتكون
+
+182
+00:20:46,220 --> 00:20:55,620
+لحظة شوية هتكون الف و متينPound في تجاه الـ I لسه
+
+183
+00:20:55,620 --> 00:21:03,040
+ما خلصتش فاندي هين تلت مية فاندي هين تلت
+
+184
+00:21:03,040 --> 00:21:10,400
+مية فاندي
+
+185
+00:21:10,400 --> 00:21:11,160
+هين تلت مية فاندي هين تلت مية فاندي هين تلت مية
+
+186
+00:21:11,160 --> 00:21:11,640
+فاندي هين تلت مية فاندي هين تلت مية فاندي هين تلت
+
+187
+00:21:11,640 --> 00:21:11,780
+مية فاندي هين تلت مية فاندي هين تلت مية فاندي هين
+
+188
+00:21:11,780 --> 00:21:11,780
+تلت مية فاندي هين تلت مية فاندي هين تلت مية فاندي
+
+189
+00:21:11,780 --> 00:21:11,780
+هين تلت مية فاندي هين تلت مية فاندي هين تلت مية
+
+190
+00:21:11,780 --> 00:21:11,780
+فاندي هين تلت مية فاندي هين تلت مية فاندي هين تلت
+
+191
+00:21:11,780 --> 00:21:14,380
+مية فاندي هين تلت مية فاندي هين ت
+
+192
+00:21:28,460 --> 00:21:36,180
+هذه AB أول
+
+193
+00:21:36,180 --> 00:21:38,640
+شي في ال .. دايما في free body diagrams لازم أحط
+
+194
+00:21:38,640 --> 00:21:47,560
+المحاور ده هي صح عندي هاي ال X axis هاي
+
+195
+00:21:47,560 --> 00:21:52,360
+ال Y axis وهاي
+
+196
+00:21:52,360 --> 00:21:55,860
+ال Z axis
+
+197
+00:22:03,620 --> 00:22:08,140
+طيب هاي بي انا جاي من عند بي .. من عند بي هيكون في
+
+198
+00:22:08,140 --> 00:22:21,520
+عندي اول اش في عندي F لتحت و
+
+199
+00:22:21,520 --> 00:22:27,440
+في M2 لاتجاه المعاكس هاي M2
+
+200
+00:22:30,910 --> 00:22:37,930
+هذه ام واحد عشان
+
+201
+00:22:37,930 --> 00:22:46,810
+نميزها moment فاندي
+
+202
+00:22:46,810 --> 00:22:53,810
+ام اتنين باتجاه
+
+203
+00:22:53,810 --> 00:22:58,650
+هذا اتجاه مظبوط هذه ام اتنين
+
+204
+00:23:03,880 --> 00:23:24,640
+و عند M1 باتجاه الـ negative Z ناخد
+
+205
+00:23:24,640 --> 00:23:30,780
+ال effect بتاع ال moments عند A had it will be
+
+206
+00:23:30,780 --> 00:23:37,110
+resistedby M1 بهذا الاتجاه بالنجم
+
+207
+00:23:37,110 --> 00:23:40,530
+moment هتكون
+
+208
+00:23:40,530 --> 00:23:47,190
+هاي
+
+209
+00:23:47,190 --> 00:23:52,410
+M1 وعندي
+
+210
+00:23:52,410 --> 00:24:00,690
+هنا torsion M2
+
+211
+00:24:02,960 --> 00:24:11,260
+و في عندى force هدى للتحت هتكون هى اللى أعلى الان
+
+212
+00:24:11,260 --> 00:24:22,860
+ال force F بتحاول تعمل bending moment حوالين ال
+
+213
+00:24:22,860 --> 00:24:29,280
+negative Z مانعة ال resisting هتكون في الموجة في Z
+
+214
+00:24:36,270 --> 00:24:48,030
+م تلاتة الام تلاتة هتكون اف اكم في خمسة يعني الف
+
+215
+00:24:48,030 --> 00:25:00,690
+خمسمية في اتجاه ال K هيك
+
+216
+00:25:00,690 --> 00:25:01,490
+يعني اننا عملنا ال
+
+217
+00:25:14,150 --> 00:25:21,410
+هذا المطبو الأول المطبو التاني compute maximum of
+
+218
+00:25:21,410 --> 00:25:28,290
+torsional stress and bending stress in arm BCand
+
+219
+00:25:28,290 --> 00:25:42,510
+indicate where these act اول
+
+220
+00:25:42,510 --> 00:25:46,590
+اشي على PC طبعا احنا هنهمل ل Transverse shear
+
+221
+00:25:46,590 --> 00:25:47,030
+effect
+
+222
+00:25:49,680 --> 00:25:53,920
+اللي هو الشير نتيجة القوة المستعرضة هنهملها بس
+
+223
+00:25:53,920 --> 00:25:59,980
+هنتظر ال shear stress due to torsion و ال bending
+
+224
+00:25:59,980 --> 00:26:07,720
+stress الان due to torsion المقطع أنا عندي هنا
+
+225
+00:26:07,720 --> 00:26:15,920
+المقطع جاي مستطيل جاي
+
+226
+00:26:15,920 --> 00:26:17,660
+سماكة ربع انش
+
+227
+00:26:25,740 --> 00:26:40,140
+والارتفاع واحد ربع نرجع
+
+228
+00:26:40,140 --> 00:26:47,740
+هنا للملاحظات بتاعتنا ال
+
+229
+00:26:47,740 --> 00:26:53,000
+shear stress في ال rectangularSections بيكون Zero
+
+230
+00:26:53,000 --> 00:26:56,340
+عند ال corners يعني بيكون ال duty ترجن بيكون هنا
+
+231
+00:26:56,340 --> 00:27:03,400
+ال share stress Zero هنا Zero هنا Zero Zero و
+
+232
+00:27:03,400 --> 00:27:07,760
+بيكون ال maximum على الضلع الطويل يعني بيكون ال
+
+233
+00:27:07,760 --> 00:27:17,940
+maximum هنا هي بتكون ال maximum marginal share
+
+234
+00:27:20,990 --> 00:27:24,490
+stress طبعا نشيل ال stress يعني zero, zero, zero,
+
+235
+00:27:24,550 --> 00:27:33,270
+zero طيب
+
+236
+00:27:33,270 --> 00:27:40,890
+ما نبتدى نحسب وين هتكون .. يعني هتكون نقطة B and B
+
+237
+00:27:40,890 --> 00:27:46,190
+بتكون هي عيش ال critical بتكون هي ال critical
+
+238
+00:27:46,190 --> 00:27:47,490
+معناته ال tau
+
+239
+00:27:51,960 --> 00:28:08,520
+ر بي سي تاو ماكس بالساوية المقطع المستطيل T
+
+240
+00:28:08,520 --> 00:28:12,520
+على
+
+241
+00:28:12,520 --> 00:28:16,500
+الف بي
+
+242
+00:28:16,500 --> 00:28:17,400
+سي تربيع
+
+243
+00:28:22,100 --> 00:28:26,280
+طبعا ال torque في الحالة هذه بيساوي م واحد ال
+
+244
+00:28:26,280 --> 00:28:33,220
+torque بيساوي م واحد انا بالظبط طبعا بي على سي بي
+
+245
+00:28:33,220 --> 00:28:40,460
+هذه بي وهذه سي ال بي على سي بيساوي واحد وربع على
+
+246
+00:28:40,460 --> 00:28:47,660
+ربع واحد وربع في خمسة
+
+247
+00:28:47,660 --> 00:28:49,740
+بما ان بي على سي خمسة
+
+248
+00:28:52,220 --> 00:28:55,640
+عند دانيل انت جاي فى النص بين أرواحك تفهم رايحانة
+
+249
+00:28:55,640 --> 00:29:03,400
+فالالفه هتكون point 282 زي point 299 على 2 لإنه
+
+250
+00:29:03,400 --> 00:29:13,400
+جاى فى النص بالظبط الالفه ال torque الساوى M1 اللى
+
+251
+00:29:13,400 --> 00:29:20,400
+هو 450 pound inch والالفه
+
+252
+00:29:22,460 --> 00:29:30,120
+حسبتوا ليها point 2905 point 2905
+
+253
+00:29:30,120 --> 00:29:31,580
+point 2905 point 2905 point 2905 point 2905 point
+
+254
+00:29:31,580 --> 00:29:35,920
+2905 point 2905 point 2905 point 2905 point 2905
+
+255
+00:29:35,920 --> 00:29:41,500
+point 2905 point 2905 point 2905 point 2905 point
+
+256
+00:29:41,500 --> 00:29:44,640
+2905
+
+257
+00:29:44,640 --> 00:29:44,660
+point 2905 point 2905 point 2905 point 2905 point
+
+258
+00:29:44,660 --> 00:29:44,660
+2905 point 2905 point 2905 point 2905 point 2905
+
+259
+00:29:44,660 --> 00:29:44,660
+point 2905 point 2905 point 2905 point 2905 point
+
+260
+00:29:44,660 --> 00:29:44,840
+2905 point 2905 point 2905 point 2905 point 2905
+
+261
+00:29:44,840 --> 00:29:44,880
+point 2905 point 2905 point 2905 point 2905 point
+
+262
+00:29:44,880 --> 00:29:44,880
+2905 point 2905 point 2905 point 2905 point 2905
+
+263
+00:29:44,880 --> 00:29:44,880
+point 2905 point 2905 point 2905 point 2905 point
+
+264
+00:29:44,880 --> 00:29:44,880
+2905 point 2905 point 2905 point 2905 point 2905
+
+265
+00:29:44,880 --> 00:29:46,880
+point 2905 point 2905 point 2
+
+266
+00:29:59,650 --> 00:30:06,410
+تسع تاشر الف تمانية
+
+267
+00:30:06,410 --> 00:30:07,530
+و تمانية و اتمانية و اتمانية و اتمانية و اتمانية و
+
+268
+00:30:07,530 --> 00:30:12,170
+اتمانية و اتمانية و
+
+269
+00:30:12,170 --> 00:30:12,510
+اتمانية و اتمانية و اتمانية و اتمانية و اتمانية و
+
+270
+00:30:12,510 --> 00:30:14,470
+اتمانية و اتمانية و اتمانية و اتمانية و اتمانية و
+
+271
+00:30:14,470 --> 00:30:18,010
+اتمانية و اتمانية و اتمانية و اتمانية و اتمانية و
+
+272
+00:30:18,010 --> 00:30:18,010
+اتمانية و اتمانية و اتمانية و اتمانية و اتمانية و
+
+273
+00:30:18,010 --> 00:30:18,050
+اتمانية و اتمانية و اتمانية و اتمانية و اتمانية و
+
+274
+00:30:18,050 --> 00:30:18,050
+اتمانية و اتمانية و اتمانية و اتمانية
+
+275
+00:30:24,240 --> 00:30:29,000
+بدوني أحسب كمان ال maximum bending stress bending
+
+276
+00:30:29,000 --> 00:30:34,100
+stress ال bending stress طبعا فيه bending ع حوالين
+
+277
+00:30:34,100 --> 00:30:40,720
+المستوى هذا يعني هكون بلزمني MX MX اللي هي M2 يعني
+
+278
+00:30:40,720 --> 00:30:43,920
+هكون ال .. ال .. ال .. النوع من ال stress due to
+
+279
+00:30:43,920 --> 00:30:47,320
+bending هكون maximum على ال fiber هذي هكون عندي
+
+280
+00:30:47,320 --> 00:30:52,960
+هنا tension و تحت compression صح؟ هكون عندي ال
+
+281
+00:30:52,960 --> 00:30:53,460
+sigma
+
+282
+00:30:59,900 --> 00:31:08,360
+Sigma Z ستكون في الحلقة هذه سيجما زد سيجما زد
+
+283
+00:31:08,360 --> 00:31:20,400
+بالساوية اما اتنين اما
+
+284
+00:31:20,400 --> 00:31:23,960
+اتنين في
+
+285
+00:31:23,960 --> 00:31:24,780
+بي على اتنين
+
+286
+00:31:29,910 --> 00:31:35,210
+على I حوالين ال X هتكون
+
+287
+00:31:35,210 --> 00:31:41,370
+M2 اللي عندي او M2 في
+
+288
+00:31:41,370 --> 00:31:53,450
+B على 2 ال I هتكون واحد على اتناش C بيتا كيب يعني
+
+289
+00:31:53,450 --> 00:31:59,490
+هتساوي ستة M2
+
+290
+00:32:02,280 --> 00:32:06,640
+على C بتربيع
+
+291
+00:32:06,640 --> 00:32:11,440
+يعني
+
+292
+00:32:11,440 --> 00:32:15,540
+هتساوي ستة
+
+293
+00:32:15,540 --> 00:32:25,240
+أهم اتنين اللي هي الف و متين على
+
+294
+00:32:25,240 --> 00:32:26,520
+C اللي هي ربع
+
+295
+00:32:31,560 --> 00:32:38,000
+في P وهي واحد وربع تربيع
+
+296
+00:32:38,000 --> 00:32:47,220
+تمنتاشر
+
+297
+00:32:47,220 --> 00:32:53,200
+الف واربعمية واتنين وتلاتين PSI
+
+298
+00:33:01,930 --> 00:33:04,590
+ثوان أسوأ طالع بال max in order to reduce stress
+
+299
+00:33:04,590 --> 00:33:17,050
+and indicate where they act اه ليش sigma z انا
+
+300
+00:33:17,050 --> 00:33:23,530
+هنا بحاول اعمل bending بالشكل هذا مالك ال stress
+
+301
+00:33:23,530 --> 00:33:30,470
+هكون في هذا الاتجاه مش بحاول انا هيك اطعجفهيكون في
+
+302
+00:33:30,470 --> 00:33:40,030
+شد ع هدى باتجاه هدى باتجاه ايش ال z هو normal
+
+303
+00:33:40,030 --> 00:33:47,810
+stress بس باتجاه ال z axis طيب لو أخدت ال section
+
+304
+00:33:47,810 --> 00:33:54,010
+احنا حكينا عند ال fiber هدى هيكون sigma z maximum
+
+305
+00:33:54,010 --> 00:33:57,450
+sigma z maximum
+
+306
+00:34:01,670 --> 00:34:07,450
+و يعني هنا ال nurses بيكون maximum tension هنا
+
+307
+00:34:07,450 --> 00:34:14,850
+maximum compression ال torsional shear
+
+308
+00:34:14,850 --> 00:34:27,330
+stress بيكون maximum هنا zero هناzero يعني لو بدى
+
+309
+00:34:27,330 --> 00:34:33,910
+اعمله هعمله عند طرفها ده هيكون اشي زي هيك و عند
+
+310
+00:34:33,910 --> 00:34:40,390
+طرفها ده هيكون نفس الشكل بس ارتفاعه اقل هذا ال
+
+311
+00:34:40,390 --> 00:34:45,150
+share stress ال total share stress zero zero
+
+312
+00:34:45,150 --> 00:34:50,190
+maximum هذا
+
+313
+00:34:50,190 --> 00:34:53,070
+المطلوب التاني المطلوب التالت
+
+314
+00:35:00,450 --> 00:35:08,210
+determine maximum normal and shear stresses at a
+
+315
+00:35:08,210 --> 00:35:16,270
+هذه النقطة a عند
+
+316
+00:35:16,270 --> 00:35:21,410
+a في
+
+317
+00:35:21,410 --> 00:35:26,350
+عندي عند a at a في عندي torsion
+
+318
+00:35:29,520 --> 00:35:33,940
+قيمة الـ torque تبعته M2 في depending moment
+
+319
+00:35:33,940 --> 00:35:41,880
+قيمتها M3 M1 M3 M1 يعني اذا اخذت element هنا
+
+320
+00:35:41,880 --> 00:35:55,960
+element صغير هذا
+
+321
+00:35:55,960 --> 00:36:05,300
+critical elementDelta X Delta Y Delta Z امسحها ده
+
+322
+00:36:05,300 --> 00:36:10,300
+لو
+
+323
+00:36:10,300 --> 00:36:25,240
+أخدت ال element هنا و أكبرته هذا
+
+324
+00:36:25,240 --> 00:36:25,780
+عند A
+
+325
+00:36:54,520 --> 00:36:59,400
+هذه ال X Axis وهذه
+
+326
+00:36:59,400 --> 00:37:04,060
+ال Z وهذه
+
+327
+00:37:04,060 --> 00:37:09,080
+ال Y
+
+328
+00:37:09,080 --> 00:37:15,580
+يعني
+
+329
+00:37:15,580 --> 00:37:20,440
+الفكرة من السؤال ان انت في الأول تعمل فعلافي حالة
+
+330
+00:37:20,440 --> 00:37:22,540
+اللي كانت المثلة static تعمل force analysis وفي
+
+331
+00:37:22,540 --> 00:37:25,580
+حالة اللي كانت المثلة dynamics تعمل kinematic
+
+332
+00:37:25,580 --> 00:37:27,740
+analysis تحس ب displacement, velocities,
+
+333
+00:37:27,820 --> 00:37:30,840
+acceleration و بعدين تعمل force analysis تعمل free
+
+334
+00:37:30,840 --> 00:37:35,480
+body diagrams و بتطلع ال forces بعد ما تطلع ال
+
+335
+00:37:35,480 --> 00:37:38,680
+forces بتوجد بتحد critical locations بالاتجاه
+
+336
+00:37:38,680 --> 00:37:42,460
+المحور و بالاتجاه المقطع بالتنينبعمل اتحاد الـ
+
+337
+00:37:42,460 --> 00:37:46,100
+critical element اللي هي اخر خطوة هذه بعمل عليها
+
+338
+00:37:46,100 --> 00:37:50,940
+stress analysis بعمل عليها stress analysis الان
+
+339
+00:37:50,940 --> 00:37:54,920
+اللحظة
+
+340
+00:37:54,920 --> 00:38:02,220
+ال load هنا بيحول من ال bending يعني هكون في عندي
+
+341
+00:38:02,220 --> 00:38:08,360
+عشر normal stress بتجاه ال x axis هذا ال moment
+
+342
+00:38:08,360 --> 00:38:22,410
+اللي هنابتعمل sigma x هنا sigma
+
+343
+00:38:22,410 --> 00:38:39,730
+x و
+
+344
+00:38:39,730 --> 00:38:47,740
+تحاول تعملTorsion Torsion خلان ناخد المقطع ندور
+
+345
+00:38:47,740 --> 00:38:58,020
+لحاله هى ال
+
+346
+00:38:58,020 --> 00:39:03,780
+Torsion اللى جاى بيحاول
+
+347
+00:39:03,780 --> 00:39:06,200
+يعمل Rotation
+
+348
+00:39:08,210 --> 00:39:15,990
+شكل هذا it will be resisted هكون عليه torsion يعني
+
+349
+00:39:15,990 --> 00:39:19,550
+هكون ده
+
+350
+00:39:19,550 --> 00:39:23,690
+هاد
+
+351
+00:39:23,690 --> 00:39:34,890
+ال tau العمود او مستواليهاش X Z لما
+
+352
+00:39:34,890 --> 00:39:39,520
+كنا نسميأنا بشتغل على مستوى هذا المصادر العاملة
+
+353
+00:39:39,520 --> 00:39:47,180
+عليه x معناته هي x في اتجاه ال z tau xz الان هاخده
+
+354
+00:39:47,180 --> 00:39:49,700
+من ال top view هكون انا في ال xz plane هاخده في ال
+
+355
+00:39:49,700 --> 00:39:56,780
+xz plane هسارة مسألة 2D
+
+356
+00:39:56,780 --> 00:39:59,840
+طبعا لو بدى احط لترانزر شيريسترس هكون 3D هكون اندي
+
+357
+00:39:59,840 --> 00:40:05,220
+شيريسترس في هذا الاتجاه فانا مهم لل Transverse
+
+358
+00:40:05,220 --> 00:40:10,040
+هكون اندي في ال xz planeالان انا هاطلع من ال y
+
+359
+00:40:10,040 --> 00:40:23,200
+axis ال y axis هاي ال x وهي ايش ال z هكون
+
+360
+00:40:23,200 --> 00:40:28,300
+عندى sigma sigma
+
+361
+00:40:28,300 --> 00:40:28,780
+x
+
+362
+00:40:37,760 --> 00:40:47,880
+واندي ايش هاد
+
+363
+00:40:47,880 --> 00:40:57,900
+ال TAO X Z S
+
+364
+00:40:57,900 --> 00:41:07,530
+اللي دي بيستخدمها M4 هندي M4 M4 بتساوي M1زاد M
+
+365
+00:41:07,530 --> 00:41:15,070
+ثلاثة ال M واحد عندى اربعمائه و خمسين وال M ثلاثة
+
+366
+00:41:15,070 --> 00:41:19,050
+اكم الف
+
+367
+00:41:19,050 --> 00:41:22,650
+و خمسمية يعني الف وتسعمائه و خمسين هتكون الف
+
+368
+00:41:22,650 --> 00:41:34,710
+وتسعمائه و خمسين pound انش ال
+
+369
+00:41:34,710 --> 00:41:35,630
+sigma X
+
+370
+00:41:39,050 --> 00:41:51,530
+هتكون M4 في
+
+371
+00:41:51,530 --> 00:42:03,060
+الـ D على 2 هدا عند A على Y على 64D أُس أربعة هذي
+
+372
+00:42:03,060 --> 00:42:08,680
+اللي هي H I M في C على I M في C على I يعني هتكون
+
+373
+00:42:08,680 --> 00:42:12,980
+سوى اتنين و تلاتين M
+
+374
+00:42:12,980 --> 00:42:21,120
+أربعة على باي D تكييب يعني هتكون سوى اتنين و
+
+375
+00:42:21,120 --> 00:42:25,320
+تلاتين M
+
+376
+00:42:25,320 --> 00:42:27,400
+أربعة اللي هي الف وتسعمائة و خمسين
+
+377
+00:42:30,770 --> 00:42:41,570
+على باى و ال دى اللى هي بون سبعة خمسة تكيب تحسبوها
+
+378
+00:42:41,570 --> 00:42:44,630
+سبعة
+
+379
+00:42:44,630 --> 00:42:48,850
+واربعين الف ومية وخمسة سبعة واربعين الف ومية وخمسة
+
+380
+00:42:48,850 --> 00:42:58,070
+ومية وخمسة سبعة واربعين الف ومية
+
+381
+00:42:58,070 --> 00:42:59,210
+وستة PSI
+
+382
+00:43:05,740 --> 00:43:20,180
+التاو اكس زد بتسوأ ام اتنين التاو اكس زد التاو
+
+383
+00:43:20,180 --> 00:43:33,360
+هشري على هذا خلاص هذا هو مش لازمة التاو
+
+384
+00:43:35,710 --> 00:43:48,330
+م2 XZ XZ
+
+385
+00:43:48,330 --> 00:43:49,350
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+386
+00:43:49,350 --> 00:43:49,430
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+387
+00:43:49,430 --> 00:43:53,010
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+388
+00:43:53,010 --> 00:43:53,010
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+389
+00:43:53,010 --> 00:43:53,010
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+390
+00:43:53,010 --> 00:43:53,030
+XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ XZ
+
+391
+00:43:53,030 --> 00:43:53,030
+XZ XZ XZ XZ XZ XZ XZ
+
+392
+00:44:03,960 --> 00:44:08,680
+في ال R اللي هي D على 2 هي ال Polar Modulation باي
+
+393
+00:44:08,680 --> 00:44:16,840
+على اتنين باي على اتنين و تلاتين D أقصى أربعة يعني
+
+394
+00:44:16,840 --> 00:44:25,640
+نحن نستوى ستاش M اتنين على باي D تكعيب يعني نحن
+
+395
+00:44:25,640 --> 00:44:38,850
+نستوى ستاش M اتنينعام اتنين اكم؟ ألف و متين على
+
+396
+00:44:38,850 --> 00:44:51,230
+باى في بون سبعة خمسة تكيب تحسب تاو اكس ز اكم
+
+397
+00:44:51,230 --> 00:44:56,990
+تطلع اربع اتناشر الف و اربع مية تلت سنة اربع
+
+398
+00:44:56,990 --> 00:44:59,190
+اتناشر الف و اربع مية تلت سنة
+
+399
+00:45:08,200 --> 00:45:18,400
+أنا حسبت او I locate critical element defined
+
+400
+00:45:18,400 --> 00:45:24,960
+بالنسبة لما احاول إحداثيات ال original بتاعة X Y Z
+
+401
+00:45:27,070 --> 00:45:31,130
+بس مش هذا هو ال critical orientation عشان اوي ال
+
+402
+00:45:31,130 --> 00:45:36,070
+critical orientation بدي
+
+403
+00:45:36,070 --> 00:45:42,030
+احصل ال principle stresses يعني بدي استخدم more
+
+404
+00:45:42,030 --> 00:45:48,310
+circle خلاص أنا صار عندي المسألة كلها همسحها
+
+405
+00:45:58,340 --> 00:46:03,300
+صار عندى هى الـ critical هى ال original element هى
+
+406
+00:46:03,300 --> 00:46:09,980
+صارت المثلة بالبساطة عندى sigma X
+
+407
+00:46:09,980 --> 00:46:15,900
+وعندى
+
+408
+00:46:15,900 --> 00:46:19,600
+الان انا هى مستميعة تاوة Z استميها اللى بدك إياها
+
+409
+00:46:19,600 --> 00:46:22,040
+استميها تاوة XZ تاوة XY اللى بدك إياها
+
+410
+00:46:27,650 --> 00:46:32,350
+عشان ما تتعرضوش تاو XZ خلاص صارت مسألة بسيطة
+
+411
+00:46:32,350 --> 00:46:41,830
+السيجما XN دي بالساوية 47000.106
+
+412
+00:46:41,830 --> 00:46:52,670
+Kpsi والتاو XZ بالساوية 14.494 Kilogram per square
+
+413
+00:46:52,670 --> 00:46:52,990
+inch
+
+414
+00:47:06,100 --> 00:47:10,100
+طيب حكيت في حالتين إذا كانت ال mechanical element
+
+415
+00:47:10,100 --> 00:47:15,960
+تحت الدراسة ساكن زي الحالة هذه مافيش .. مافيش
+
+416
+00:47:15,960 --> 00:47:19,840
+motion أساسا بعمل إيش summation force بساوة 0 و
+
+417
+00:47:19,840 --> 00:47:20,740
+summation motion بساوة 0
+
+418
+00:47:26,150 --> 00:47:28,990
+بدك ترسم .. بدك ترسم اللي هو ال shear و ال moment
+
+419
+00:47:28,990 --> 00:47:35,430
+diagrams واضح ال bending moment هنا maximum هنا ال
+
+420
+00:47:35,430 --> 00:47:41,270
+bending moment maximum لأ باينه .. باين عندك يعني
+
+421
+00:47:41,270 --> 00:47:45,090
+باينه بالنظر ان هو هذا اللي .. اللي بيكون ال
+
+422
+00:47:45,090 --> 00:47:47,870
+highest stressed element يعني انا مثلا بضغط هنا
+
+423
+00:47:47,870 --> 00:47:52,450
+تتوقع هنا يكون critical اكتر من هنا اكيد لو ده
+
+424
+00:47:52,450 --> 00:47:53,950
+يصير كسر هسيه في المنطقة هذه
+
+425
+00:47:59,180 --> 00:48:06,300
+يعني هذا cantilevered و torsioned يعني كأنه انا
+
+426
+00:48:06,300 --> 00:48:10,620
+متعلق فيه من هنا و من هنا يعني مدة هذه عن جهة هنا
+
+427
+00:48:10,620 --> 00:48:15,120
+كمان فيه كأنه فيه وزن هنا cantilever و هذه عاملة
+
+428
+00:48:15,120 --> 00:48:18,000
+ايه اش torsion فهتكون هذه ايه اش فعلا هو ده ال
+
+429
+00:48:18,000 --> 00:48:23,180
+critical limit لما
+
+430
+00:48:23,180 --> 00:48:29,390
+نجرسم more circle ال center بتاع more circleبكون
+
+431
+00:48:29,390 --> 00:48:31,970
+ات سجما X على سجما Y على اتنين فمش عندى غير سجما X
+
+432
+00:48:31,970 --> 00:48:37,650
+هكون عندى سبعة واربعين point one oh ستة على اتنين
+
+433
+00:48:37,650 --> 00:48:46,110
+يعني هكون اتنين تلاتة point خمسة
+
+434
+00:48:46,110 --> 00:48:49,150
+خمسة
+
+435
+00:48:49,150 --> 00:48:53,270
+تلاتة kilo pound
+
+436
+00:48:56,050 --> 00:49:01,370
+و ال radius تعالى more circle رح تكون R جزر
+
+437
+00:49:01,370 --> 00:49:05,990
+التربية ل sigma X minus sigma Y على اتنين كل تربية
+
+438
+00:49:05,990 --> 00:49:10,650
+زائد تاو XY تربية اللى هتكون اللى هى تلاتة و عشرين
+
+439
+00:49:10,650 --> 00:49:16,890
+point خمسة خمسة تلاتة تربية زائد اربعتاش point
+
+440
+00:49:16,890 --> 00:49:24,630
+اربعة تسعة اربعة تربية حسبنا ال radius بعدين بحسب
+
+441
+00:49:24,630 --> 00:49:31,880
+ال sigmaالسبعة واربعين اكم سبعة واربعين اعطيني
+
+442
+00:49:31,880 --> 00:49:37,080
+تلاتة تلاتة دسمية السبعة واربعين كيلو
+
+443
+00:49:37,080 --> 00:49:44,900
+pound per square inch طيب
+
+444
+00:49:44,900 --> 00:49:52,340
+ال sigma واحد هتكون C زاد Rصح يعني هتكون تلاتة و
+
+445
+00:49:52,340 --> 00:49:57,560
+عشرين point خمسة خمسة تلاتة زي السبع عشرين point
+
+446
+00:49:57,560 --> 00:50:06,920
+ستة خمسة خمسة اشبعوا واحد و خمسين point اتنين
+
+447
+00:50:06,920 --> 00:50:12,420
+sigma
+
+448
+00:50:12,420 --> 00:50:19,280
+اتنين C minus Rاللي هو عندك تلاتة عشرين point خمسة
+
+449
+00:50:19,280 --> 00:50:25,160
+خمسة تلاتة minus سبعة عشرين point ستة خمسة خمسة
+
+450
+00:50:25,160 --> 00:50:33,140
+سلب
+
+451
+00:50:33,140 --> 00:50:37,460
+أربعة point مية و اتنين سلب أربعة point مية و
+
+452
+00:50:37,460 --> 00:50:43,440
+اتنين kilopound per square inch معناته ال tau max
+
+453
+00:50:45,820 --> 00:50:49,360
+اللي هو oriented plus or minus خمسة واربعين درجة
+
+454
+00:50:49,360 --> 00:50:51,280
+من ال planes اللي بتأثر على سيجما واحد وسيجما
+
+455
+00:50:51,280 --> 00:50:58,100
+اتنين بيساوي سيجما واحد minus سيجما اتنين على
+
+456
+00:50:58,100 --> 00:51:04,260
+اتنين اللي هتكون واحد وخمسين اللي هي هتكوناش بتطلع
+
+457
+00:51:04,260 --> 00:51:10,320
+سبع عشرين point ستة خمسة خمسة kilo pound per
+
+458
+00:51:10,320 --> 00:51:12,940
+square inch لما اجرى some more circle
+
+459
+00:51:21,530 --> 00:51:30,250
+أول نقطة عندى سجما X و هاد Clockwise يعني هاد كله
+
+460
+00:51:30,250 --> 00:51:35,090
+أعلى هذه نقطة نقطة بين السفر و ال counter
+
+461
+00:51:35,090 --> 00:51:39,390
+clockwise واصل
+
+462
+00:51:39,390 --> 00:51:46,490
+بينهم هاد ال center هاد
+
+463
+00:51:46,490 --> 00:51:58,220
+سجما واحدواداش سيجما اتنين الزاوية هادة اللي هو
+
+464
+00:51:58,220 --> 00:52:05,080
+اتنين فاي بي تان اتنين
+
+465
+00:52:05,080 --> 00:52:13,220
+فاي بي هتساوض له هادة اللي هو تاو اكس واي تاو اكس
+
+466
+00:52:13,220 --> 00:52:13,580
+واي
+
+467
+00:52:16,580 --> 00:52:25,280
+توزيد 14.494
+
+468
+00:52:25,280 --> 00:52:32,280
+على سجما
+
+469
+00:52:32,280 --> 00:52:39,420
+X على 2 47 على 2 هو 23
+
+470
+00:52:41,700 --> 00:52:50,360
+بنت خمسة خمسة ثلاثة ومنها بحسب في بي يعني بحسب زو
+
+471
+00:52:50,360 --> 00:52:57,600
+حد وبعدين أقسمه على اتنين أكتر بتطلع؟
+
+472
+00:52:57,600 --> 00:53:02,680
+يعني الأتنين ضياءك أكتر تطلع من تقسيم الاتنين 15.8
+
+473
+00:53:02,680 --> 00:53:05,840
+معناته
+
+474
+00:53:05,840 --> 00:53:06,920
+من ال element هذا
+
+475
+00:53:11,230 --> 00:53:17,430
+هنمشي انا من هذا طبعا هذا يمثل هذا ايش هذا ال X
+
+476
+00:53:17,430 --> 00:53:25,230
+Axis وهذا سميه ال Y Axis بدك ايه او زي ده هاي Y
+
+477
+00:53:25,230 --> 00:53:31,130
+Axis انا هتحلف من ال X Axis باتجاه عقارة الساعة 15
+
+478
+00:53:31,130 --> 00:53:40,110
+.8 هاي ال X Axis هتحلف من الزاوية 15.8
+
+479
+00:53:41,980 --> 00:53:48,700
+هرسم element هي
+
+480
+00:53:48,700 --> 00:53:54,440
+sigma واحد وهي
+
+481
+00:53:54,440 --> 00:54:06,260
+sigma اتنين طيب
+
+482
+00:54:06,260 --> 00:54:10,220
+عشان اجيب ال maximum share stress هي tau maximum
+
+483
+00:54:21,270 --> 00:54:29,970
+Half plus or minus 45 من هذا الاتجاه يعني هروح 45
+
+484
+00:54:29,970 --> 00:54:32,190
+زي هيك يعني هسير هنا
+
+485
+00:54:39,940 --> 00:54:46,320
+إذا هاروح في عكس عقارب الساعة الخمسة واربعين هيكون
+
+486
+00:54:46,320 --> 00:54:55,000
+هداياش clockwise هيكون عنده زي هيك
+
+487
+00:54:55,000 --> 00:54:58,460
+اللي هو ال tau maximum اللي هو هذا سبعة shape one
+
+488
+00:54:58,460 --> 00:55:05,200
+ستة خلال ال tau هذا الزاويةخمس واربعين هذا هو ال
+
+489
+00:55:05,200 --> 00:55:18,120
+max و برضه في حيكون عنده اللي هو سيجما
+
+490
+00:55:18,120 --> 00:55:21,940
+سيجما
+
+491
+00:55:21,940 --> 00:55:30,400
+اللي هو اللي هي هذههتكون في الحالة دي sigma ع
+
+492
+00:55:30,400 --> 00:55:36,360
+اتنين sigma xz على اتنين لان هذا يتساوى ال C يعني
+
+493
+00:56:24,630 --> 00:56:31,650
+طيب هيكون حلينا المسئلة بشكل اكتر ما هو مطلوب
+
+494
+00:56:31,650 --> 00:56:39,970
+انحلي
+
+495
+00:56:39,970 --> 00:56:44,390
+المثال تاني a one point five inch diameter solid
+
+496
+00:56:44,390 --> 00:56:47,350
+steel shaft
+
+497
+00:56:48,780 --> 00:56:55,920
+عندي شافت هين عليها بكرتين هي بكره و بكره البكره
+
+498
+00:56:55,920 --> 00:57:01,680
+دي قطرها اربع انش البكره دي قطرها تمانية انش لأن
+
+499
+00:57:01,680 --> 00:57:06,160
+هاي الحبل بتاع البكره الشد الشد في الحبل بتاع
+
+500
+00:57:06,160 --> 00:57:11,040
+البكره بيكونش نفس الشد و لا بتلفش فعندي هين الشد
+
+501
+00:57:11,040 --> 00:57:15,600
+ال الف pound ع الطرف تاني متين poundعند البكرة
+
+502
+00:57:15,600 --> 00:57:20,000
+التانية فيه على الطرف هذا خمس ميت باوند والشد على
+
+503
+00:57:20,000 --> 00:57:25,720
+الطرف التاني من الحبل ميت باوند الشاف طوله عشرة و
+
+504
+00:57:25,720 --> 00:57:32,460
+عشرة و عشرة و تلاتين انش simply supported عند a و
+
+505
+00:57:32,460 --> 00:57:38,000
+d هاي ال x axis و y axis و z axis
+
+506
+00:57:47,040 --> 00:57:52,600
+considering bending and torsion stresses only
+
+507
+00:57:52,600 --> 00:57:57,900
+هنهمل transverse shear stress determine locations
+
+508
+00:57:57,900 --> 00:58:01,660
+and magnitudes of the greatest tensile compressive
+
+509
+00:58:01,660 --> 00:58:09,140
+and shear stresses in the shaft مثلا
+
+510
+00:58:09,140 --> 00:58:13,340
+زي هيك لازم اخد free pedagram لازم أولا اعمل force
+
+511
+00:58:13,340 --> 00:58:14,080
+analysis
+
+512
+00:58:26,810 --> 00:58:33,050
+سأعمل في مستويات في الـ XY Plane يوجد طريقة تانية
+
+513
+00:58:33,050 --> 00:58:36,470
+يمكنني أن أعمل نفسي طريقة الكتاب باشتغال مستويات
+
+514
+00:58:36,470 --> 00:58:39,930
+او
+
+515
+00:58:39,930 --> 00:58:45,530
+اشتغل الـ 3D مباشرة يعني اخذ summation of forces
+
+516
+00:58:45,530 --> 00:58:49,490
+باتجاه ال X و Y و Z و اخذ summation of moment
+
+517
+00:58:49,490 --> 00:58:53,590
+حوالين اي نقطة مثلا نقطة A و منها اودي ال reaction
+
+518
+00:58:53,590 --> 00:58:53,930
+force
+
+519
+00:58:56,630 --> 00:59:04,550
+and a و reactions and d لان هاخد حشة على اللي اخد
+
+520
+00:59:04,550 --> 00:59:08,370
+أشد في المستوى في ال XY plane و ال XZ plane لما
+
+521
+00:59:08,370 --> 00:59:14,030
+نطلع ال XY plane هدول مش هيبينه هيبين اندياش
+
+522
+00:59:14,030 --> 00:59:22,030
+الخمسمية و المية لما انقلهم على النص في
+
+523
+00:59:22,030 --> 00:59:27,930
+ال XY planeهذا هتكون خمسمية و مية هصير ستمية في
+
+524
+00:59:27,930 --> 00:59:33,450
+النص الخمسمية بتعمل moment خمسمية هذا القطر تمانية
+
+525
+00:59:33,450 --> 00:59:38,770
+انش مص القطر أكام أربعة أربعة هذا هتعمل خك يعني
+
+526
+00:59:38,770 --> 00:59:45,790
+هتعمل خمسمية في أربعة ناقص مية في أربعة يعني الف و
+
+527
+00:59:45,790 --> 00:59:50,150
+ستمية فهو
+
+528
+00:59:50,150 --> 00:59:55,770
+عمل في الأولش 3D ناقل ال forcesيعني لما نقل عند
+
+529
+00:59:55,770 --> 01:00:01,930
+هذه هتكون متين زي ألف هتيجي في النص الف و متين هذه
+
+530
+01:00:01,930 --> 01:00:05,330
+قطرها أربع انش يعني نص القطر اتنين انش يعني الف في
+
+531
+01:00:05,330 --> 01:00:12,330
+اتنين ناقص متين في اتنين يعني الف ستمية هيكون يعني
+
+532
+01:00:12,330 --> 01:00:17,890
+عند هنا الف و متين الف متين انتبهوا ال الف أكتر
+
+533
+01:00:17,890 --> 01:00:25,300
+تعمل تورجن بالشكل هذا ف ..هيها فعلا بهذا الاتجاه
+
+534
+01:00:25,300 --> 01:00:30,800
+لدي الف و متين high force و فيه dictatorial الف
+
+535
+01:00:30,800 --> 01:00:36,740
+ستمية التانية الخمسمية
+
+536
+01:00:36,740 --> 01:00:40,880
+بهذا الاتجاه positive x axis خمسمية في أربعة ناقص
+
+537
+01:00:40,880 --> 01:00:45,480
+مية في أربعة ألف ستمية بس الاتجاه مش المعاكس اللي
+
+538
+01:00:45,480 --> 01:00:49,740
+هو باتجاه positive x axis و خمسمية زي المية هي
+
+539
+01:00:49,740 --> 01:00:58,110
+ستميةاللي عندما أخد ال X Y Plane للشافت هاي ال X و
+
+540
+01:00:58,110 --> 01:01:04,670
+هاي ال Y هيبين عندي بس رد الفعل باتجاه ال Y عند A
+
+541
+01:01:04,670 --> 01:01:09,150
+و رد الفعل باتجاه ال Y عند D و هيبين عندي 600 لتحت
+
+542
+01:01:09,150 --> 01:01:13,070
+زاد في عندي ال torsion مش هتأثر على summation of
+
+543
+01:01:13,070 --> 01:01:20,730
+forces فهيكون بال X Y Planeعندي دي رجع كمرة هاي
+
+544
+01:01:20,730 --> 01:01:28,470
+بال X Y plane هتبين بس هذه ستمية هاي الستمية و هاد
+
+545
+01:01:28,470 --> 01:01:40,130
+انا هسميها R A Y هاي A هاي عندك B هاي C هاي D يعني
+
+546
+01:01:40,130 --> 01:01:46,430
+هاندي هكون R A Y عندي هاد R
+
+547
+01:01:53,950 --> 01:02:00,170
+برDY لو أخدت ال moment حوالين C عشان أحسب ال
+
+548
+01:02:00,170 --> 01:02:07,150
+forces صممش ال moment حوالين A حل
+
+549
+01:02:07,150 --> 01:02:12,710
+الشغل بال XY plane صممش
+
+550
+01:02:12,710 --> 01:02:23,150
+ال moment حوالين A بالساوة 0هتكون ناقص ستمية في
+
+551
+01:02:23,150 --> 01:02:28,190
+عشرين زاد
+
+552
+01:02:28,190 --> 01:02:37,130
+ر دي واي في تلاتين تطلع
+
+553
+01:02:37,130 --> 01:02:44,110
+عند ر دي واي ستمية في عشرين اتماشر الف ع تلاتين
+
+554
+01:02:44,110 --> 01:02:44,790
+اربع مليون
+
+555
+01:02:48,780 --> 01:02:55,960
+بعدين summation لل forces باتجاه ال Y بستوى صفر
+
+556
+01:02:55,960 --> 01:03:06,140
+بتسوى RAY مانقصة مية زاد RDY اللي هي أربعمية
+
+557
+01:03:06,140 --> 01:03:16,420
+معناته RAY بستوى متين pound صحيح مطلع وبعدين بعمل
+
+558
+01:03:16,420 --> 01:03:22,820
+ال shear diagramبعمل ال share diagram
+
+559
+01:03:22,820 --> 01:03:30,660
+حيكون الشكل هذا share
+
+560
+01:03:30,660 --> 01:03:40,920
+diagram عندي 2 هذه
+
+561
+01:03:40,920 --> 01:03:50,550
+200 وهذه سالب 400 صح؟ال moment diagram هنكون عنده
+
+562
+01:03:50,550 --> 01:03:57,910
+متين في عشرين أربعة
+
+563
+01:03:57,910 --> 01:04:06,290
+ألف يعني عندهين أربعة ألف pound inch ناقص أربعمائة
+
+564
+01:04:06,290 --> 01:04:10,170
+و عشرة بتسفر هذا هو ال moment diagram
+
+565
+01:04:13,960 --> 01:04:17,700
+هذا في ال X Y plane اللي هي ال moment diagram في
+
+566
+01:04:17,700 --> 01:04:23,320
+ال X Y plane طبعا هذا ال moment هتكون باتجاه ال Z
+
+567
+01:04:23,320 --> 01:04:32,400
+لأن هاي ال forces بتعمل في المحور هتكون moment حول
+
+568
+01:04:32,400 --> 01:04:36,060
+المحور العمودي على ال X Y plane فهذا هتكون MZ
+
+569
+01:04:36,060 --> 01:04:39,140
+moment
+
+570
+01:04:39,140 --> 01:04:47,930
+diagramلو أخدت ال XZ plane هاي ال XZ plane هاي ال
+
+571
+01:04:47,930 --> 01:04:52,930
+X في هذا الاتجاه و ال Z لتحت هكون في عندي RAZ
+
+572
+01:04:52,930 --> 01:05:01,770
+وعندي RDZ وعندي باتجاه ال positive Z اللي هي H1200
+
+573
+01:05:01,770 --> 01:05:07,430
+عشان نذكر هاي
+
+574
+01:05:07,430 --> 01:05:08,990
+ال Z axis موجب لتحت
+
+575
+01:05:14,760 --> 01:05:19,560
+هذا الـ z-axis موجب
+
+576
+01:05:19,560 --> 01:05:23,440
+لتحت الـ
+
+577
+01:05:23,440 --> 01:05:26,080
+الف و متين باتجاه الـ positive z-axis هيأكسه
+
+578
+01:05:26,080 --> 01:05:33,360
+reactions معاكسية للفرصة هذه هكون هذه raz و rdz
+
+579
+01:05:33,360 --> 01:05:39,100
+بنفس الطريقة عندي
+
+580
+01:05:39,100 --> 01:05:45,540
+هذه الف و متين هاخد moment حوالين aهكون الف و مت
+
+581
+01:05:45,540 --> 01:05:50,400
+.. minus الف و متين في عشرة زاد أربعمية في تلاتين
+
+582
+01:05:50,400 --> 01:05:57,040
+زاد .. زاد تلاتين في R D Z و من هنا بحثوا R D Z ال
+
+583
+01:05:57,040 --> 01:06:03,620
+Z بيساوي الف و متين في تلاتة على الف و متين في
+
+584
+01:06:03,620 --> 01:06:10,980
+تلاتة .. في عشرة ع تلاتين تطلع أربعميةبعدين
+
+585
+01:06:10,980 --> 01:06:16,080
+summation لل force باتجاه ال Z بيساوي Zero هكون دي
+
+586
+01:06:16,080 --> 01:06:22,940
+ألف و متين ناقص RAZ ناقص RDZ و انا بحصل RAZ تطلعيش
+
+587
+01:06:22,940 --> 01:06:26,340
+تمانمية بعدين بعمل shear diagram
+
+588
+01:06:41,690 --> 01:06:47,250
+هذه ستكون تمنمية وهنا
+
+589
+01:06:47,250 --> 01:06:56,090
+سالب أربعمية صح تمنمية في عشر عايز تمان تلاف نقص
+
+590
+01:06:56,090 --> 01:07:01,390
+اربعمية في عشرين بتسفر لان صار عند ال moment
+
+591
+01:07:01,390 --> 01:07:05,990
+diagram ال moment diagram صار في المستوين في ال
+
+592
+01:07:05,990 --> 01:07:10,350
+exit plane هاي
+
+593
+01:07:10,350 --> 01:07:10,870
+ال moment diagram
+
+594
+01:07:14,710 --> 01:07:23,630
+في ال X Y plane هاي ال moment diagram في ال X Z
+
+595
+01:07:23,630 --> 01:07:33,130
+plane في ال X Y plane ال moment نقسمه
+
+596
+01:07:33,130 --> 01:07:42,610
+ل 3 أقسام في
+
+597
+01:07:42,610 --> 01:07:43,490
+ال X Y plane
+
+598
+01:07:50,470 --> 01:07:58,770
+هندي a,b,c,d هندهين أربعة تلاف هين هتكون طبعا نصها
+
+599
+01:07:58,770 --> 01:08:03,270
+هتكون هين ألفين هذا في ال X Y plane في ال X Z
+
+600
+01:08:03,270 --> 01:08:07,510
+plane اللي
+
+601
+01:08:07,510 --> 01:08:16,550
+هو هيكون تمان تلاف تمان تلاف جاي هين هين
+
+602
+01:08:16,550 --> 01:08:18,010
+هتكون تمان تلاف
+
+603
+01:08:20,690 --> 01:08:27,570
+و هين هتكون اش اربعة تلاف مانعته
+
+604
+01:08:27,570 --> 01:08:32,810
+مش عارف مين most critical ال total moment عند بي م
+
+605
+01:08:32,810 --> 01:08:43,610
+بي هتكون جزر التربية ل الفين تربية زي تمان تلاف
+
+606
+01:08:43,610 --> 01:08:54,020
+تربية اما عند سيهتكون جزر التربية ايه؟ اربع تلاف
+
+607
+01:08:54,020 --> 01:08:59,800
+تربية واضح
+
+608
+01:08:59,800 --> 01:09:07,280
+ان B more critical than C صح؟ لأن هندي يعني ..
+
+609
+01:09:07,280 --> 01:09:10,340
+يعني اكيد هذي اكبر ان هذي هتطلع اكتر من تمام تلاف
+
+610
+01:09:10,340 --> 01:09:14,040
+هذ هتطلع اربع تلاف خمس تلاف ستمية يمكن تطلع وش زي
+
+611
+01:09:14,040 --> 01:09:24,390
+هيك هتطلع اكتر من تمام تلاف و متينفهتكون عندى هذا
+
+612
+01:09:24,390 --> 01:09:34,010
+بالنسبة لل بنجم بالنسبة لل تورجين بتبدأ تصبح
+
+613
+01:09:34,010 --> 01:09:37,970
+resistance يعني لان ال load يعني عندى مثلا ال
+
+614
+01:09:37,970 --> 01:09:42,610
+انبوت جاى هنا و ال load هنا مثلا جاى مصدر هين من
+
+615
+01:09:42,610 --> 01:09:47,210
+الموتور و هنا بتحميل ال load معناته على الشمال ال
+
+616
+01:09:47,210 --> 01:09:53,140
+B فيش تورجينمش مقاومة لكن على يمينها في مقاومة
+
+617
+01:09:53,140 --> 01:09:59,520
+التورجن هنحسبه ال torque يعني ال most critical
+
+618
+01:09:59,520 --> 01:10:09,420
+location most critical location is
+
+619
+01:10:09,420 --> 01:10:20,570
+at B plus at B plus يعني عند atX بالساوية عشرة
+
+620
+01:10:20,570 --> 01:10:26,950
+plus هذا
+
+621
+01:10:26,950 --> 01:10:32,110
+هو ال most critical location لو بدى ارسم المقطع
+
+622
+01:10:32,110 --> 01:10:36,130
+عند B عند B هيكون عند هاي ال Y و Z axis
+
+623
+01:10:49,830 --> 01:11:08,850
+and b ها
+
+624
+01:11:08,850 --> 01:11:14,050
+هي ال y axis وها
+
+625
+01:11:14,050 --> 01:11:14,930
+هي ال z axis
+
+626
+01:11:24,590 --> 01:11:32,590
+في ال X Y plane في ال X Y plane هى يصير bending
+
+627
+01:11:32,590 --> 01:11:36,510
+بهذا الاتجاه لو طلعت فقط على هذا الاتجاه هى يكون
+
+628
+01:11:36,510 --> 01:11:43,930
+سطحي له هنا اندي هنا compression compression
+
+629
+01:11:43,930 --> 01:12:00,850
+وهنا tension هذا ال U to Mz du to m z صح وهذا du
+
+630
+01:12:00,850 --> 01:12:04,530
+to
+
+631
+01:12:04,530 --> 01:12:14,250
+m z باتجاه ال y في
+
+632
+01:12:14,250 --> 01:12:18,770
+ال xz plane هكون
+
+633
+01:12:18,770 --> 01:12:21,770
+دي هذا my هيكون
+
+634
+01:12:24,080 --> 01:12:29,360
+هذه هتكون compression وهذه
+
+635
+01:12:29,360 --> 01:12:36,120
+ايش هتكون tension هذه
+
+636
+01:12:36,120 --> 01:12:40,460
+due to
+
+637
+01:12:40,460 --> 01:12:49,960
+my وهذه due to
+
+638
+01:12:49,960 --> 01:13:11,590
+myلو بدى ارسم a distribution from U to MZ هكون
+
+639
+01:13:11,590 --> 01:13:20,250
+دي هين compression وهين
+
+640
+01:13:20,250 --> 01:13:20,690
+tension
+
+641
+01:13:23,510 --> 01:13:28,030
+and bending normal
+
+642
+01:13:28,030 --> 01:13:31,430
+bending
+
+643
+01:13:31,430 --> 01:13:35,990
+stress
+
+644
+01:13:35,990 --> 01:13:46,810
+due to mz لو اطلع هنا due to my
+
+645
+01:14:23,050 --> 01:14:32,110
+هنا هن compression هن عشر tension هن tension هن
+
+646
+01:14:32,110 --> 01:14:40,330
+compression هن bending normal bending
+
+647
+01:14:40,330 --> 01:14:47,230
+stress due
+
+648
+01:14:47,230 --> 01:14:49,610
+to my
+
+649
+01:15:03,700 --> 01:15:14,160
+ال .. bending moment انا
+
+650
+01:15:14,160 --> 01:15:23,780
+عندي هاي ال m y عندي ال 8000 يعني
+
+651
+01:15:23,780 --> 01:15:30,480
+هكون عندي two locations هذه .. هذه في bending
+
+652
+01:15:30,480 --> 01:15:31,600
+moment بهذا الاتجاه
+
+653
+01:15:38,630 --> 01:15:45,730
+وهذا فيه bending moment بهذا الاتجاه فهذه قيمتها
+
+654
+01:15:45,730 --> 01:15:55,010
+8000 حوالي ال y axis وحوالي ال z axis أكتر الفين
+
+655
+01:15:55,010 --> 01:16:00,910
+المحاصلة بتاعتهم هتكون هذه المحاصلة بتاعتهم
+
+656
+01:16:00,910 --> 01:16:09,060
+انتبهوا لما انا طلع مثلا على حالة ال MZهي ال MZ
+
+657
+01:16:09,060 --> 01:16:16,500
+بيكون عندهين compression و tension يعني على جنابة
+
+658
+01:16:16,500 --> 01:16:20,860
+up and down بيكون عنده compression و tension مش
+
+659
+01:16:20,860 --> 01:16:24,040
+مهم كتير بس ان ال maximum should be up and down
+
+660
+01:16:24,040 --> 01:16:32,000
+فهي المحصلة هذه هي المحصلة معناته انا هروح up and
+
+661
+01:16:32,000 --> 01:16:33,240
+down هروح تسعين درجة
+
+662
+01:16:36,950 --> 01:16:40,850
+هنا بيكون عندي ايش؟ compression maximum
+
+663
+01:16:40,850 --> 01:16:47,990
+compression وهنا بيكون maximum tension معناه تحسب
+
+664
+01:16:47,990 --> 01:16:53,330
+ال total moment انا حسبت ال total moment اللي هي M
+
+665
+01:16:53,330 --> 01:17:00,770
+الكلية الجزر التربيعي ل 2000 تربيع زي 8000 تربيع
+
+666
+01:17:09,580 --> 01:17:15,640
+تمان تلاف و متين و ست و اربعين pound inch لأن
+
+667
+01:17:15,640 --> 01:17:28,840
+الزاوية هذه هسميها theta تان انفرس تمان تلاف على
+
+668
+01:17:28,840 --> 01:17:34,100
+الفين ستة و سبعين درجة
+
+669
+01:17:36,650 --> 01:17:41,330
+معناته هذا هتكون هذا
+
+670
+01:17:41,330 --> 01:17:52,110
+برضه هتكون theta صح ال
+
+671
+01:17:52,110 --> 01:18:03,950
+sigma normal stress هتكون M لأن هذا مدور مختلف لأن
+
+672
+01:18:03,950 --> 01:18:12,360
+هذا مدوربس يروح يقول انه M في C على I يعني انا
+
+673
+01:18:12,360 --> 01:18:21,760
+هتكون تساوي اتنين و تلاتين M على I دي تكيب يعني
+
+674
+01:18:21,760 --> 01:18:26,140
+اتنين و تلاتين في تمان تلف و متين و ستة و اربعين
+
+675
+01:18:26,140 --> 01:18:29,720
+على دي القطر تعالى شفت كم اعطينيها
+
+676
+01:18:39,740 --> 01:18:51,120
+واحد و نص انش على واحد و نص انش بحسب
+
+677
+01:18:51,120 --> 01:18:55,960
+اللعب ال stress اربع
+
+678
+01:18:55,960 --> 01:18:59,640
+عشرين الف فان
+
+679
+01:18:59,640 --> 01:19:02,300
+بيرس كور انش التورجن
+
+680
+01:19:04,340 --> 01:19:08,560
+الساقو اللى هى ال T فى R على J هو شرس ال duty
+
+681
+01:19:08,560 --> 01:19:17,940
+torsion هتكون ستاشر T على Pi دى تكييب هتكون ستاشر
+
+682
+01:19:17,940 --> 01:19:28,720
+ال torque الف ستمية على Pi فى واحد و نص تكييب
+
+683
+01:19:34,710 --> 01:19:40,350
+نعم الفين و أربعمية و ستة عشر الفين و أربعمية و
+
+684
+01:19:40,350 --> 01:19:45,410
+ستة عشر هذا
+
+685
+01:19:45,410 --> 01:19:49,130
+الرقم غلط هذا
+
+686
+01:19:49,130 --> 01:19:54,670
+الفين و أربعمية و ستة عشر هذا
+
+687
+01:19:54,670 --> 01:20:01,390
+صح الرقم هيك فرق نص يعني مش فارق لأ بحكيش عن نص
+
+688
+01:20:01,390 --> 01:20:03,490
+أنا تمام نص الرقم هذا صح
+
+689
+01:20:06,490 --> 01:20:12,110
+يعني هذا تقريبا .. هذا خمس أضعاف الرقم هذا خمس ..
+
+690
+01:20:12,110 --> 01:20:14,650
+يعني هتضرب هذا في عشر .. خلاص صح .. صح الرقم عشر
+
+691
+01:20:14,650 --> 01:20:20,390
+أربع .. صح .. صحيح الرقم صحيح خلاص .. هيك صح طيب
+
+692
+01:20:20,390 --> 01:20:28,810
+طبعا ك stress element احنا أخدنا عند B plus يعني B
+
+693
+01:20:28,810 --> 01:20:30,330
+plus
+
+694
+01:20:35,700 --> 01:20:40,200
+يعني هكون stress element مش شكل هذا هنا لأ ال
+
+695
+01:20:40,200 --> 01:20:44,880
+torsion وين ما تدور نفس الاشي يعني لو أنا لفت
+
+696
+01:20:44,880 --> 01:20:49,460
+الشرط ازاي و هيك و رجعته و حطته هنا ماتتريجش معايا
+
+697
+01:20:49,460 --> 01:20:53,800
+واضح انا عندي torsion فال element لو اخده عند B
+
+698
+01:20:53,800 --> 01:20:57,860
+plus هكون شكل ال element
+
+699
+01:21:18,530 --> 01:21:27,950
+هذه ال X Axis وهذه ال Z وهذه ال Y سيكون السيجما
+
+700
+01:21:27,950 --> 01:21:38,810
+اللى طلعتها سيجما
+
+701
+01:21:38,810 --> 01:21:40,730
+سيكون طبعا
+
+702
+01:21:45,630 --> 01:21:49,710
+في شيريس فعلا في ال two d's هكون two d's تت يعني
+
+703
+01:21:49,710 --> 01:22:00,630
+هكون عندي هي سيجما برضه
+
+704
+01:22:00,630 --> 01:22:04,210
+من more circle بحسب سيجما واحد برصم more circle
+
+705
+01:22:04,210 --> 01:22:08,690
+بحسب سيجما واحد سيجما اتنين او تاو maximum يعني
+
+706
+01:22:08,690 --> 01:22:16,830
+هذا ال maximum او ال most criticalElement بالنسبة
+
+707
+01:22:16,830 --> 01:22:19,690
+لما هو الإحداثيات ال absolute coordinate system
+
+708
+01:22:19,690 --> 01:22:25,250
+اللي أنا حاطبها لكن this is not the most critical
+
+709
+01:22:25,250 --> 01:22:28,250
+orientation مش ال most critical orientation most
+
+710
+01:22:28,250 --> 01:22:31,910
+critical orientation بوجده من خلال اللي هو ال more
+
+711
+01:22:31,910 --> 01:22:34,490
+circle بحث ال for instance ال sigma one و sigma
+
+712
+01:22:34,490 --> 01:22:37,810
+two و sigma three و tau max
+
+713
+01:22:46,340 --> 01:22:49,400
+هيك نكون خلصنا المحاضرة، طيب ولا عارف؟
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/FFFtpNPdpGc_postprocess.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/FFFtpNPdpGc_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..a202c1cccbf069cc5aa99b408e0b355176b6dedd
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/FFFtpNPdpGc_postprocess.srt
@@ -0,0 +1,2148 @@
+1
+00:00:05,530 --> 00:00:08,070
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,070 --> 00:00:11,910
+وبركاته اليوم هنكمل في chapter تلاتة stress and
+
+3
+00:00:11,910 --> 00:00:17,510
+load analysis اليوم الموضوع هيكون curved beams in
+
+4
+00:00:17,510 --> 00:00:20,730
+bending سابقا درسنا ال bending في ال straight
+
+5
+00:00:20,730 --> 00:00:26,410
+beams حكينا ال sigma بساوة M في C basically sigma
+
+6
+00:00:26,410 --> 00:00:30,150
+بساوة
+
+7
+00:00:30,150 --> 00:00:39,760
+M في C على Iو ال stress بتغير linearly يعني لو
+
+8
+00:00:39,760 --> 00:00:47,400
+كانت مقطع مستطيل في عليه bending ال
+
+9
+00:00:47,400 --> 00:00:53,660
+stress
+
+10
+00:00:53,660 --> 00:00:59,510
+بتغير مع الوعيLinear اللي بيكون maximum عند ال
+
+11
+00:00:59,510 --> 00:01:04,530
+outer fiber و minimum عند ال inner أو بيكون عند ال
+
+12
+00:01:04,530 --> 00:01:07,390
+.. بيكون zero عند ال neutral axis و maximum عند ال
+
+13
+00:01:07,390 --> 00:01:09,810
+outer fiber و maximum سواء كان tension او
+
+14
+00:01:09,810 --> 00:01:14,670
+compression هذا في حالة ال straight beams في حالة
+
+15
+00:01:14,670 --> 00:01:18,490
+ال curved beamsلحظ برضه في حالة ال straight beams
+
+16
+00:01:18,490 --> 00:01:21,290
+ال neutral axis ينطبق على ال centroid ال axis
+
+17
+00:01:21,290 --> 00:01:25,450
+للمقطع لكن في حالة ال curved .. ال thick curved
+
+18
+00:01:25,450 --> 00:01:29,070
+beams ال neutral axis و ال centroid ال axis لا
+
+19
+00:01:29,070 --> 00:01:31,490
+ينطبقوا على بعض من بعض يعني في عندي ال neutral
+
+20
+00:01:31,490 --> 00:01:35,310
+axis و في عندي ال centroid ال axis غير منطبقين على
+
+21
+00:01:35,310 --> 00:01:35,630
+بعض
+
+22
+00:01:38,500 --> 00:01:41,440
+تاني اشي bending stress does not vary nearly with
+
+23
+00:01:41,440 --> 00:01:45,120
+distance from neutral axis ال bending stress
+
+24
+00:01:45,120 --> 00:01:49,540
+مابتتغير بشكل خطي مع المسافة او مع البعد عن ال
+
+25
+00:01:49,540 --> 00:01:55,580
+neutral axis هنشوف لان في عندي .. في curved beam
+
+26
+00:01:55,580 --> 00:02:04,740
+ممكن في عندي beam زي هيك عندي
+
+27
+00:02:04,740 --> 00:02:05,080
+support
+
+28
+00:02:10,070 --> 00:02:17,130
+و في عليه some loading يعني بندنج لأن انا بناخد
+
+29
+00:02:17,130 --> 00:02:22,110
+جزء من ال beam هذا ال radius هو ال radius الداخل
+
+30
+00:02:22,110 --> 00:02:28,250
+لل beam نص قطر التكور الداخلي ر اي هذا نص القطر
+
+31
+00:02:28,250 --> 00:02:32,390
+التكور الخارجي
+
+32
+00:02:32,390 --> 00:02:34,590
+ر او
+
+33
+00:02:45,370 --> 00:02:50,690
+هذا الـ neutral axis هذا
+
+34
+00:02:50,690 --> 00:02:55,310
+الـ
+
+35
+00:02:55,310 --> 00:03:01,430
+neutral axis و فيه bending moment M
+
+36
+00:03:23,730 --> 00:03:28,610
+طبعا لو أخدت مقطع هنا ممكن نحكي هذا ال general
+
+37
+00:03:28,610 --> 00:03:37,970
+shape مثلا للمقطع ارتفاع المقطع H
+
+38
+00:03:37,970 --> 00:03:43,030
+فانا
+
+39
+00:03:43,030 --> 00:03:45,570
+حاكي ان هذا هو ال neutral axis وهذا ال centroidal
+
+40
+00:03:45,570 --> 00:03:45,930
+axis
+
+41
+00:03:55,610 --> 00:04:01,810
+هذا ال central axis هذا
+
+42
+00:04:01,810 --> 00:04:09,750
+هو ال neutral axis ال
+
+43
+00:04:09,750 --> 00:04:15,290
+neutral axis في طبعا offset distance بين ال
+
+44
+00:04:15,290 --> 00:04:19,370
+central axis و ال neutral axis هسميها E هذا
+
+45
+00:04:19,370 --> 00:04:20,430
+المسافة E
+
+46
+00:04:27,370 --> 00:04:40,890
+و احنا حكينا هذه المسافة هسميها RN هذه RN مصقطر
+
+47
+00:04:40,890 --> 00:04:51,030
+تكوّر and neutral axis اللي هي هذه RN
+
+48
+00:04:51,030 --> 00:04:54,470
+وهذه RC
+
+49
+00:05:15,070 --> 00:05:25,250
+إذا خدنا أي element على بعد R من
+
+50
+00:05:25,250 --> 00:05:31,950
+مركز التكوّر هذه
+
+51
+00:05:31,950 --> 00:05:39,550
+المسافة R هسميها ايش هتكون هذه Y يعني
+
+52
+00:05:39,550 --> 00:05:44,270
+ال R زاد ال Y بيستوي ايش؟ RN ال R زاد ال Y
+
+53
+00:05:47,990 --> 00:05:55,210
+بستو R N ال
+
+54
+00:05:55,210 --> 00:06:01,630
+Y تكسب positive في هذا الاتجاه R Y هذا هو ال
+
+55
+00:06:01,630 --> 00:06:09,590
+element تحت
+
+56
+00:06:09,590 --> 00:06:10,190
+الدراسة
+
+57
+00:06:23,900 --> 00:06:28,660
+المسافة من الـ neutral axis لل inner fibre سميها
+
+58
+00:06:28,660 --> 00:06:34,800
+CI والمسافة
+
+59
+00:06:34,800 --> 00:06:38,260
+من ال neutral axis لل outer fibre ساميها CO
+
+60
+00:06:51,970 --> 00:06:59,210
+نتيجة ال bending يعني لو كان المقطع هذا بي سي هذا
+
+61
+00:06:59,210 --> 00:07:05,390
+بي سي before bending due to bending هصير some
+
+62
+00:07:05,390 --> 00:07:14,290
+rotation هتضل عند ال بي براين هذا الخط after
+
+63
+00:07:14,290 --> 00:07:15,650
+bending هضله straight
+
+64
+00:07:19,000 --> 00:07:31,560
+هذه بي براين وهذه سي براين هذه
+
+65
+00:07:31,560 --> 00:07:43,040
+الزاوية يعني
+
+66
+00:07:43,040 --> 00:07:47,940
+اتأني انا ايجي الفاية لو اخد section بي سيafter
+
+67
+00:07:47,940 --> 00:07:51,740
+bending بيصيرش فيه curvature بيبقى عدل يعني مستوى
+
+68
+00:07:51,740 --> 00:07:57,920
+هذا بي لف صحيح بس بيبقى عدل بيصيرش فيه curvature
+
+69
+00:07:57,920 --> 00:08:03,040
+بيبقى بي برايم سي برايم هذه
+
+70
+00:08:03,040 --> 00:08:08,380
+هي التسميات الرئيسية الآن المعادلات مش هطلب
+
+71
+00:08:08,380 --> 00:08:15,900
+اشتقاقها اني عندي RN بالساوية
+
+72
+00:08:18,460 --> 00:08:27,700
+A على تكامل DA على R و ال stress distribution
+
+73
+00:08:27,700 --> 00:08:31,880
+sigma بساوي
+
+74
+00:08:31,880 --> 00:08:36,080
+اللي هو MY على
+
+75
+00:08:36,080 --> 00:08:41,920
+A في E RN minus Y
+
+76
+00:08:51,270 --> 00:08:57,030
+يعني عندي حكينا ال Rn اللي هو هذا هذا ال Rn او هو
+
+77
+00:08:57,030 --> 00:09:02,590
+هذا مُعطل علاقة المساحة بتاعة ال cross section على
+
+78
+00:09:02,590 --> 00:09:07,650
+تكامل ال D A على R و ال stress distribution sigma
+
+79
+00:09:07,650 --> 00:09:14,150
+سواء M في Y على A E في R N نقص Y وهي اتجاه ال Y
+
+80
+00:09:20,870 --> 00:09:30,650
+الان لو بدأ اوى دى stress عند ال inner fiber عند
+
+81
+00:09:30,650 --> 00:09:38,690
+ال inner fiber ال Y اشو ساوى at ال inner fiber at
+
+82
+00:09:38,690 --> 00:09:54,440
+ال inner fiber بتكون عندى ال Y بالساويةسي اي صح؟
+
+83
+00:09:54,440 --> 00:10:07,420
+معناته سيجما يعني سيجما اي بيستو ام في سي اي على ا
+
+84
+00:10:07,420 --> 00:10:14,300
+في اي في ر ان ماينس سي اي
+
+85
+00:10:20,420 --> 00:10:28,540
+الان RN هاي RN مينس CI هيبقى عناش RI صح؟ يعني
+
+86
+00:10:28,540 --> 00:10:33,020
+هتساوي MCI
+
+87
+00:10:33,020 --> 00:10:37,460
+على AERI
+
+88
+00:10:37,460 --> 00:10:48,980
+اللي هي هذه المعادلةطول ال E صحيح لجسمها صحيح ال E
+
+89
+00:10:48,980 --> 00:10:52,320
+تختلف
+
+90
+00:10:52,320 --> 00:10:58,240
+باختلاف المقطع تختلف اختلاف المقطع و ال curvature
+
+91
+00:10:58,240 --> 00:11:02,720
+بتاع المقطع يعني لو كان straight beam ال E هتكون
+
+92
+00:11:02,720 --> 00:11:08,060
+سوى سفر اذا كان curved beam مش هتكون سفر طب يدي
+
+93
+00:11:08,060 --> 00:11:13,610
+ايش كل .. باختلاف ال curvature بتختلفالـ Sigma O
+
+94
+00:11:13,610 --> 00:11:22,510
+أدت اللي هو Outer Fiber أكون
+
+95
+00:11:22,510 --> 00:11:30,950
+عند ال Y بالسواء minus CO يعني أصلا ال Sigma Outer
+
+96
+00:11:30,950 --> 00:11:37,470
+بالساوية minus MCO
+
+97
+00:11:39,130 --> 00:11:50,070
+على ال A E في R N minus minus تصير زائد C O هتكون
+
+98
+00:11:50,070 --> 00:11:57,710
+سوى minus M C O هاي ال R N ال R N زائد C O عبارة
+
+99
+00:11:57,710 --> 00:12:07,530
+عن إيه R O على A E R O اللي هي المعادلة
+
+100
+00:12:10,450 --> 00:12:14,270
+الثاني طيب خلّيني أحاول مثال
+
+101
+00:12:31,730 --> 00:12:34,490
+Plot the distribution of stresses across section
+
+102
+00:12:34,490 --> 00:12:39,610
+AA of the crane hook shown فاندي crane hook هذه
+
+103
+00:12:39,610 --> 00:12:48,930
+عليها load F و بده عند المقطع AA هين ال stress
+
+104
+00:12:48,930 --> 00:12:59,150
+distribution المقطع
+
+105
+00:12:59,150 --> 00:13:07,510
+طبعا هين زي مستطيلو هذه المركز مركز التكوّر هذا ال
+
+106
+00:13:07,510 --> 00:13:10,930
+.. طبعا هذا عندى اتنين انش و هذا ستة انش معناته
+
+107
+00:13:10,930 --> 00:13:16,370
+هذا اكام؟ اربعة هذا اتنين هذا ستة معناته هذا ايش؟
+
+108
+00:13:16,370 --> 00:13:19,430
+اربعة معناه ال section اللى هو طلعت عليه من ال top
+
+109
+00:13:19,430 --> 00:13:25,910
+view هيبين عندى هى المركز و هذا هيكون ر اي
+
+110
+00:13:30,980 --> 00:13:40,240
+صح؟ وهذا رح يكون R
+
+111
+00:13:40,240 --> 00:13:46,840
+O وهذا H صح؟
+
+112
+00:13:46,840 --> 00:13:52,840
+وهذا
+
+113
+00:13:52,840 --> 00:13:53,460
+R C
+
+114
+00:14:02,480 --> 00:14:12,880
+طبعا هكون انا بدي احسب هكون هذه المسافة R and و
+
+115
+00:14:12,880 --> 00:14:19,020
+ال offset distance بين ال Rc و ال Rn اللي هي ايه
+
+116
+00:14:19,020 --> 00:14:25,480
+خنكتب اندي ر ايه شو ساوي اتنين
+
+117
+00:14:25,480 --> 00:14:32,930
+انش صح و ال ر او هاي هالتنين انش ر ايهو ال R O ستة
+
+118
+00:14:32,930 --> 00:14:38,750
+انش و
+
+119
+00:14:38,750 --> 00:14:41,870
+ال
+
+120
+00:14:41,870 --> 00:14:47,010
+H شو يساوي اللى
+
+121
+00:14:47,010 --> 00:14:54,150
+هى R O مينوس R I سوى أربعة انش و السماكة بيعطينيها
+
+122
+00:14:54,150 --> 00:14:57,930
+point سبعة خمسة انش مانا بتقول ايه اكم تساوي
+
+123
+00:15:01,210 --> 00:15:11,050
+اللي هي هتكون أربع في بون سبعة خمسة صح تلت انش
+
+124
+00:15:11,050 --> 00:15:19,430
+تربيع ال
+
+125
+00:15:19,430 --> 00:15:22,450
+RN
+
+126
+00:15:22,450 --> 00:15:26,050
+سواء
+
+127
+00:15:26,050 --> 00:15:38,190
+A على تكاملDA على R يعني لو أخدت element هاي
+
+128
+00:15:38,190 --> 00:15:46,610
+element على
+
+129
+00:15:46,610 --> 00:15:54,230
+بعد مسافة R احنا
+
+130
+00:15:54,230 --> 00:15:58,610
+حكينا ال Y is defined from the neutral axis
+
+131
+00:16:03,170 --> 00:16:10,210
+يعني ال Y تكون موجوبة في اتجاه مركز التكوّر ال دي
+
+132
+00:16:10,210 --> 00:16:17,110
+ايه بتاعتها دي؟ دي ايه ايش ساوي؟ حاجة ممكن اسميها
+
+133
+00:16:17,110 --> 00:16:23,990
+DR او
+
+134
+00:16:23,990 --> 00:16:25,690
+ممكن اسميها بيه
+
+135
+00:16:32,380 --> 00:16:39,940
+هتكون ال D A بسوة B D R يعني هدى ال A اللى هى
+
+136
+00:16:39,940 --> 00:16:50,920
+التلاتة على تكامل ال B D R على R من R I ل R O يعني
+
+137
+00:16:50,920 --> 00:16:59,080
+هتكون تلاتة على bond سبعة ال B هطلع ع برا ع bond
+
+138
+00:16:59,080 --> 00:17:04,240
+سبعة خمسةلن الار من ر اي لار او يعني اللي هتكون لن
+
+139
+00:17:04,240 --> 00:17:09,000
+الار او على ر اي لن
+
+140
+00:17:09,000 --> 00:17:18,240
+الار او على ر اي يعني هتساوي أربعة
+
+141
+00:17:18,240 --> 00:17:30,120
+على لن الار او اللي هي ستة على اتنين حسبوليها
+
+142
+00:17:31,070 --> 00:17:50,230
+اربع على لن التلاتة تحسبوا كل الرقم ماطين
+
+143
+00:17:50,230 --> 00:17:57,050
+ال force ال F عبارة عن خمس تلاف نيوتن ال F
+
+144
+00:17:59,810 --> 00:18:06,370
+3.64 كم هو الرقم؟ تلاتة و واحد ستة أربع واحد انش
+
+145
+00:18:06,370 --> 00:18:09,390
+معطني
+
+146
+00:18:09,390 --> 00:18:18,170
+ال force F خمس تلاف pound لو
+
+147
+00:18:18,170 --> 00:18:23,290
+عملت section هنا و
+
+148
+00:18:23,290 --> 00:18:25,370
+أخدت ال free bell diagram هذا الجزء بس
+
+149
+00:18:28,100 --> 00:18:33,160
+this is my free body diagram فى
+
+150
+00:18:33,160 --> 00:18:47,680
+عندى force F وستكون عندى F معاكسة لها هدو
+
+151
+00:18:47,680 --> 00:18:51,840
+تعمل counter clockwise moment
+
+152
+00:19:00,660 --> 00:19:07,700
+M ال M هتكون تساوي F
+
+153
+00:19:07,700 --> 00:19:14,260
+RC يعني
+
+154
+00:19:14,260 --> 00:19:25,740
+ال F عندي خمس تلاف ال RC اللي هي هتكون أربع
+
+155
+00:19:25,740 --> 00:19:26,100
+إنش
+
+156
+00:19:30,820 --> 00:19:40,040
+عشرين الف pound معناته ال service هذا معرض ل
+
+157
+00:19:40,040 --> 00:19:47,080
+bending و normal stress bending و normal stress
+
+158
+00:19:47,080 --> 00:19:53,520
+يعني لو حكيت عن ال sigmaهتكون sigma axial due to
+
+159
+00:19:53,520 --> 00:19:59,220
+sigma axial زائد sigma due bending ال sigma due to
+
+160
+00:19:59,220 --> 00:20:07,000
+axial واضح انها tensile موجبة هتكون F على A زائد
+
+161
+00:20:07,000 --> 00:20:13,180
+ال sigma due to bending ال
+
+162
+00:20:13,180 --> 00:20:18,080
+هي MY على
+
+163
+00:20:18,080 --> 00:20:19,960
+AE
+
+164
+00:20:22,320 --> 00:20:33,240
+في RN-Y احنا ال A ايش يساوي ال
+
+165
+00:20:33,240 --> 00:20:39,820
+A بيساوي RC-RN ال A بيساوي
+
+166
+00:20:39,820 --> 00:20:51,380
+RC-RN 4-3.641 يعني هتكون تساوي point
+
+167
+00:20:53,360 --> 00:21:09,960
+تلاتة خمسة تسعة انش هذا ال A يعني
+
+168
+00:21:09,960 --> 00:21:18,800
+انا هكون عنده ال F على A اللي عشرين ألف
+
+169
+00:21:23,070 --> 00:21:31,650
+الـ A عندي على التلاتة زاد ال M لأ
+
+170
+00:21:31,650 --> 00:21:40,070
+ال F خمس تلاف ال
+
+171
+00:21:40,070 --> 00:21:45,690
+M عشرين ألف في
+
+172
+00:21:45,690 --> 00:21:55,420
+ال Y على ال L هي تلاتةبالـ E يبقون تلاتة خمسة تسعة
+
+173
+00:21:55,420 --> 00:22:05,280
+بالـ RN الـ RN هي تلاتة بقون ستة أربعة واحد ناقص
+
+174
+00:22:05,280 --> 00:22:09,280
+Y أنا
+
+175
+00:22:09,280 --> 00:22:14,960
+حاسسه خمس تلاف على تلاتة أكمل
+
+176
+00:22:14,960 --> 00:22:18,560
+خمس تلاف على تلاتة
+
+177
+00:22:28,540 --> 00:22:33,060
+ألف و ستمية و ستة و ستين وين ستة سبعة طيب زائد
+
+178
+00:22:33,060 --> 00:22:40,520
+عشرين الف عشرين على تلاتة سبع تلاتة ست تلاتة اخصنا
+
+179
+00:22:40,520 --> 00:22:44,580
+عشرين الف على تلاتة على وان تلاتة خمسمية على هذا
+
+180
+00:22:44,580 --> 00:22:51,240
+برضه مرة تمانتاشر
+
+181
+00:22:51,240 --> 00:22:56,100
+الف و خمسمية و سبعين تمانتاشر الف و خمسمية و سبعين
+
+182
+00:22:58,500 --> 00:23:08,480
+y على ثلاثة point ستة أربع واحد ناقص y
+
+183
+00:23:08,480 --> 00:23:11,720
+لما
+
+184
+00:23:11,720 --> 00:23:26,940
+أخدت different ways حكيت هذه ال y هذه
+
+185
+00:23:26,940 --> 00:23:27,320
+ال y
+
+186
+00:23:42,790 --> 00:23:47,190
+ممكن تعملها مرحلتين يعني هو في النهاية إيش هكون
+
+187
+00:23:47,190 --> 00:23:50,730
+عندك ال
+
+188
+00:23:50,730 --> 00:23:54,250
+bending هعمل
+
+189
+00:23:54,250 --> 00:23:57,410
+compression على الجهة هذه لحاله و tension على
+
+190
+00:23:57,410 --> 00:24:03,020
+الجهة هذه يعني هنا هنشبعو هين هنطرح يعني ممكن تحكي
+
+191
+00:24:03,020 --> 00:24:09,780
+التالت هذا يعني
+
+192
+00:24:09,780 --> 00:24:19,300
+بالظبط بالظبط يعني sigma I هتكون واحد ستة ستة سبعة
+
+193
+00:24:19,300 --> 00:24:29,120
+زاد ال Y عندي في الحالة هذه اللي هي هذه المسافة
+
+194
+00:24:30,690 --> 00:24:42,130
+اللي هي بقى عن اتنين او نحكي ال CI ال CI بتساوي
+
+195
+00:24:42,130 --> 00:24:47,430
+ال
+
+196
+00:24:47,430 --> 00:24:55,870
+CI بتساوي اللي هو هذه المسافة صح هذه ال CI
+
+197
+00:25:05,960 --> 00:25:15,480
+المعنى التساوي بيستوى RN-RI هتكون تساوي RN تلاتة
+
+198
+00:25:15,480 --> 00:25:22,120
+point ستة اربع واحد ناقص اتنين يعني هتكون واحد
+
+199
+00:25:22,120 --> 00:25:28,100
+point ستة اربع واحد انش و CO تلاتة point ستة اربع
+
+200
+00:25:28,100 --> 00:25:33,320
+واحد زائد اتنين انش صح؟ يعني هتكون خمسة point ستة
+
+201
+00:25:33,320 --> 00:25:34,760
+اربع واحد انش
+
+202
+00:25:37,670 --> 00:25:41,010
+Sigma هتكون سوى الف تانمية و خمسين الف و تنتاشر
+
+203
+00:25:41,010 --> 00:25:44,710
+الف و خمسمية و سبعين في ال YI اللي هي بالسواء CI
+
+204
+00:25:44,710 --> 00:25:54,310
+في واحد point ستة اربعة واحد على تلاتة
+
+205
+00:25:54,310 --> 00:25:58,750
+point ستة اربعة واحد ناقص يعني هذا هتكون على اتنين
+
+206
+00:25:58,750 --> 00:26:00,470
+صح
+
+207
+00:26:02,780 --> 00:26:11,140
+وانا بحسب سيجما ايه سيجما او هتكون الف ستمية سبعة
+
+208
+00:26:11,140 --> 00:26:17,520
+ستين زائد هتكون الواي بالنجاتف في الحالة التانية
+
+209
+00:26:17,520 --> 00:26:28,580
+هتكون هذه سالب تمانتاشر الف وخمسمية وسبعين في اللي
+
+210
+00:26:28,580 --> 00:26:31,780
+هي C
+
+211
+00:26:33,710 --> 00:26:43,090
+ال سي او لأ في غلط هذه ال سي او هي ال سي او ال
+
+212
+00:26:43,090 --> 00:26:51,770
+سي او هتكون ال
+
+213
+00:26:51,770 --> 00:26:55,850
+سي او ال h minus
+
+214
+00:26:55,850 --> 00:27:06,820
+ci صح مش هذي ال سي اوهذا ال H صح
+
+215
+00:27:06,820 --> 00:27:13,320
+هتكون ال H minus ال CI ال H اللي هي أربعة minus
+
+216
+00:27:13,320 --> 00:27:20,940
+واحد point ستة أربعة واحد هتكون
+
+217
+00:27:20,940 --> 00:27:26,920
+اتنين point تلاتة
+
+218
+00:27:26,920 --> 00:27:29,780
+خمسة تسعة inch
+
+219
+00:27:32,500 --> 00:27:41,700
+يعني هتكون في اتنين point تلاتة خمسة تسعة على
+
+220
+00:27:41,700 --> 00:27:52,200
+تلاتة point ستة اربع واحدزائد اتنين point تلاتة
+
+221
+00:27:52,200 --> 00:27:56,940
+خمسة تسعة يعني هتكون هذه الجمعه هاياش ستة هذه هدول
+
+222
+00:27:56,940 --> 00:28:03,460
+ستة الجمعه هادى ماعرف يطلعيش ستة هيتلع سوء الحصول
+
+223
+00:28:03,460 --> 00:28:08,040
+التنتين هدول هدول اخمستاشر الف و متين و ستة و
+
+224
+00:28:08,040 --> 00:28:12,320
+تلاتين و ستة خمستاشر الف و متين و سبعة و تلاتين و
+
+225
+00:28:12,320 --> 00:28:12,820
+التانية
+
+226
+00:28:28,400 --> 00:28:33,600
+minus 16900 و التانية
+
+227
+00:28:59,390 --> 00:29:04,290
+السالب خمس تلاف ست
+
+228
+00:29:04,290 --> 00:29:16,610
+مية واربع ثلاثين اشارة
+
+229
+00:29:16,610 --> 00:29:19,710
+السالب على البرنامج ان عشان ال moment بعد ال force
+
+230
+00:29:19,710 --> 00:29:26,530
+لأ لأ هي اشارة السالب لان نطلع الموجب لل Y من
+
+231
+00:29:26,530 --> 00:29:31,540
+neutral X بين هاي الموجب ال Yلما روحت على ال CO
+
+232
+00:29:31,540 --> 00:29:36,880
+صارت بال negative ال Y فعوضت عن ال Y هنا ب minus 2
+
+233
+00:29:36,880 --> 00:29:46,080
+.359 و تحت minus minus بيصير موجة لأ لأ انت قمشي
+
+234
+00:29:46,080 --> 00:29:48,320
+على ال psycho convention تجي لحلقة صح يعني هنا
+
+235
+00:29:48,320 --> 00:29:52,400
+minus plus minus تحطيني minus و هنا minus minus
+
+236
+00:29:52,400 --> 00:29:53,600
+تحطيني plus
+
+237
+00:30:00,460 --> 00:30:08,600
+الان ال stress distribution هيكون non
+
+238
+00:30:08,600 --> 00:30:12,920
+linear وهي
+
+239
+00:30:12,920 --> 00:30:18,400
+neutral axis عند
+
+240
+00:30:18,400 --> 00:30:20,760
+ال inner fiber في عنده tension
+
+241
+00:30:30,080 --> 00:30:33,140
+عند ال author file عندي compression تقريبا التلت
+
+242
+00:30:33,140 --> 00:30:36,720
+يعني
+
+243
+00:30:36,720 --> 00:30:49,740
+هيكون high
+
+244
+00:30:49,740 --> 00:30:52,760
+stress distribution على الكران
+
+245
+00:30:55,570 --> 00:31:02,210
+عندي هين tension لو كنتوا ستة أشر ألف تسعمية
+
+246
+00:31:02,210 --> 00:31:06,690
+وتلاتة وعندي هين compression ماكس خمس تلاف ستمية
+
+247
+00:31:06,690 --> 00:31:16,750
+أربعة تلاتين في أسعار هاي
+
+248
+00:31:16,750 --> 00:31:20,230
+ال RN هاي ال RN زيرو ال neutral axis زيرو هاد ال
+
+249
+00:31:20,230 --> 00:31:21,610
+RN هاد
+
+250
+00:31:25,390 --> 00:31:40,730
+ال R N وهذه ال E وهذه ال R C وهذه طبعا ال R I وهذه
+
+251
+00:31:40,730 --> 00:31:48,970
+ال R O بقصد الدكتور ان ال R N كانت من ال bending
+
+252
+00:31:48,970 --> 00:31:53,510
+بس صحيح؟معانا في bending و normal بسبب ال stress
+
+253
+00:31:53,510 --> 00:31:58,750
+القارئان لل bending ايوة القارئان لل bending يعني
+
+254
+00:31:58,750 --> 00:32:03,030
+هم مش هتكون قارئان للموضوع الان هنا هنا هنا في
+
+255
+00:32:03,030 --> 00:32:09,970
+كلامك صحيح الان ايش اللي هسوي الان حط حط حط الان
+
+256
+00:32:09,970 --> 00:32:14,530
+بدك توجد يعني خلنا نحكي احنا وجدنا يعني هذا مش
+
+257
+00:32:14,530 --> 00:32:19,230
+zero صحيح مش zero هتكون واحد التاني هنا هتكون اشي
+
+258
+00:32:19,230 --> 00:32:26,010
+زي هيكهذه هتكون لو أنا ضفت هنا صفر due to bending
+
+259
+00:32:26,010 --> 00:32:32,330
+لما نضيف عليها هل
+
+260
+00:32:32,330 --> 00:32:37,610
+ال neutral ضفت عليها أكمل ألف صار له shift حيث صار
+
+261
+00:32:37,610 --> 00:32:42,870
+موجب اشي
+
+262
+00:32:42,870 --> 00:32:46,330
+زي هيك هل neutral axis بتاع ال bending
+
+263
+00:32:52,740 --> 00:32:57,740
+هن الف ستمية و سبعة ستين ال neutral axis وهن ستة
+
+264
+00:32:57,740 --> 00:33:05,040
+ألف وتسعمائة و تلاتة وهن ناقص خمس آلاف و ستمية و
+
+265
+00:33:05,040 --> 00:33:10,180
+أربعة و تلاتين هذا ال neutral axis بتاع ال bending
+
+266
+00:33:10,180 --> 00:33:13,860
+ال neutral axis صار shift لل total neutral axis
+
+267
+00:33:13,860 --> 00:33:19,260
+هذا سميه ال total neutral
+
+268
+00:33:21,270 --> 00:33:25,650
+طب التوتر اكس بحالة هذه بعتمد شكل كبير على قيمة ال
+
+269
+00:33:25,650 --> 00:33:41,030
+F في
+
+270
+00:33:41,030 --> 00:33:48,310
+سؤال تاني طيب
+
+271
+00:34:17,950 --> 00:34:22,730
+طيب ال table تلاتة أربعة في الكتاب معطيني for
+
+272
+00:34:22,730 --> 00:34:26,530
+different sections of curved beams يعني هذا curved
+
+273
+00:34:26,530 --> 00:34:31,710
+beam و هذا ال section تبعه هذا ال ri هذا ال rn هذا
+
+274
+00:34:31,710 --> 00:34:35,650
+ال rc هذا ال ro هذا ال h في حالة مقطعه مستطيل
+
+275
+00:34:35,650 --> 00:34:40,470
+معطيني ال rc بصورة i زادتش ع اتنين و معطيني ال rn
+
+276
+00:34:40,470 --> 00:34:47,390
+في حالة مقطع ع شكل شبه منحرفمعطينا هاي ال R I هذا
+
+277
+00:34:47,390 --> 00:34:53,750
+ال H وهذا ال R O معطينا معادل ال R C ومعادل ال R N
+
+278
+00:34:53,750 --> 00:35:03,750
+في حالة مقطع حرف I مقلوب عند هاي ال R I هاي ال R O
+
+279
+00:35:03,750 --> 00:35:08,770
+R C R N معطينا برضه معادل ال R C وR N في حالة مقطع
+
+280
+00:35:08,770 --> 00:35:16,730
+دائرة معطينا برضههذه الـRI هذه الـRO هذه الـRC و
+
+281
+00:35:16,730 --> 00:35:27,390
+الـ RN معطيين RC و RN R كبتر نصف قطر الدايرة طبعا
+
+282
+00:35:27,390 --> 00:35:35,110
+معطيين الأشكال المختلفة المعلومات هذه في
+
+283
+00:35:35,110 --> 00:35:36,390
+كل ما يزيد ال curvature
+
+284
+00:35:39,900 --> 00:35:45,680
+يقترب من معنى انها بيصير ايش؟ straight معناته كل
+
+285
+00:35:45,680 --> 00:35:50,480
+ما اقترب من ال straightness كل ما كانت ال E تقترب
+
+286
+00:35:50,480 --> 00:35:56,940
+من ال zero يعني كل ما بنطبق ال neutral axis على ال
+
+287
+00:35:56,940 --> 00:36:04,760
+central axisفكل ما تزرق
+
+288
+00:36:04,760 --> 00:36:09,600
+قيمة ال A في الحالة هذه ال A ممكن في حالة large
+
+289
+00:36:09,600 --> 00:36:13,640
+curvature تكون تقريبا بالثوابة I على RC
+
+290
+00:36:24,750 --> 00:36:28,230
+المسافة من مركز تكوّر لـcentroidal axis والـ A
+
+291
+00:36:28,230 --> 00:36:34,010
+مساحة المقطع الآن
+
+292
+00:36:34,010 --> 00:36:38,890
+إذا بعود هذه المعادلة بمعادلة ال stress اللي هي
+
+293
+00:36:38,890 --> 00:36:42,690
+هذه sigma
+
+294
+00:36:42,690 --> 00:36:46,470
+بسوء
+
+295
+00:36:46,470 --> 00:36:59,250
+M في Y على AA في RNناقص Y بعود
+
+296
+00:36:59,250 --> 00:37:09,490
+عن ال A ال
+
+297
+00:37:09,490 --> 00:37:18,490
+A اللي هي I على RC في A بسرع الشغل تطلع اندياش
+
+298
+00:37:19,580 --> 00:37:24,480
+المعادلة هي تقريبا سيجما وهنا بيعتبر رن ماينوس واي
+
+299
+00:37:24,480 --> 00:37:30,420
+اللي هي هذه ايش ر تطلع
+
+300
+00:37:30,420 --> 00:37:34,500
+عند المعادلة سيجما تقريبا م في واي على اي في ار سي
+
+301
+00:37:34,500 --> 00:37:40,400
+على ار هذا في الحال كان عندي large curvature
+
+302
+00:37:40,400 --> 00:37:41,860
+للبيمة
+
+303
+00:37:55,830 --> 00:38:01,430
+يعني لو انا جبت two beams نفس المقطع و نفس التحميل
+
+304
+00:38:01,430 --> 00:38:12,050
+يعني اذا جبت beam زي هيك عدل المقطع طبعا مستطيل و
+
+305
+00:38:12,050 --> 00:38:21,470
+عليها distributed load اي حالة حالة تانية نفس
+
+306
+00:38:21,470 --> 00:38:22,010
+ال span
+
+307
+00:38:40,580 --> 00:38:50,320
+و نفس الـ distributed load load موظّع متوقع
+
+308
+00:38:50,320 --> 00:38:54,500
+مين يعني أداء يكون أحسن هدا ال beam و لا هدا ال
+
+309
+00:38:54,500 --> 00:39:02,120
+beam يعني
+
+310
+00:39:02,120 --> 00:39:07,720
+لو كان هنا ال distribution ميت ميت النيوتن لكل متر
+
+311
+00:39:09,350 --> 00:39:12,790
+متوقع هذا يشيل نفس ال section متوقع هذا يشيل أكتر
+
+312
+00:39:12,790 --> 00:39:19,950
+ولا أقل من هذا؟ لأ هذا هشيل أقل هشيل أكتر وزم
+
+313
+00:39:19,950 --> 00:39:23,190
+معناه ال stress level هكون أقل من stress level هذا
+
+314
+00:39:23,190 --> 00:39:29,170
+هنا عشان في الجصور بيعملوا curvature بيعملوا
+
+315
+00:39:29,170 --> 00:39:33,090
+curvature طيب
+
+316
+00:39:33,090 --> 00:39:36,410
+نشوف
+
+317
+00:39:36,410 --> 00:39:36,890
+مثال
+
+318
+00:39:45,430 --> 00:39:49,410
+consider the circle section in table تلاتة أربعة
+
+319
+00:39:49,410 --> 00:39:54,970
+نرجع لتابل تلاتة أربعة عندي circle cross section
+
+320
+00:39:54,970 --> 00:39:58,610
+هاي
+
+321
+00:39:58,610 --> 00:40:03,010
+مركز التكوّر هاي
+
+322
+00:40:03,010 --> 00:40:10,250
+مركز الدائر المقطع هاي
+
+323
+00:40:10,250 --> 00:40:14,550
+عندى هذا هو ال RN
+
+324
+00:40:18,120 --> 00:40:29,200
+هذا ال E وهذا ال R C وهذا نص ال readers بتاعتها R
+
+325
+00:40:29,200 --> 00:40:38,940
+رئيسية و ال R C طبعا هذا ر I وهذا
+
+326
+00:40:38,940 --> 00:40:40,940
+ر O
+
+327
+00:40:45,220 --> 00:40:54,380
+الار سي بالساوية الار اي زاد الار كابيتال والار ان
+
+328
+00:40:54,380 --> 00:41:06,420
+بالساوية ار سكوار على اتنين في ار سي minus جزر
+
+329
+00:41:06,420 --> 00:41:12,120
+التربيع ايه الار سي تربيع minus ار تربيع
+
+330
+00:41:14,670 --> 00:41:23,650
+هذا هو ال table تلاتة اربعة where RC معطيني ال RC
+
+331
+00:41:23,650 --> 00:41:30,270
+بيستوى تلاتة انش ال RC بيستوى تلاتة انش وال R
+
+332
+00:41:30,270 --> 00:41:37,930
+capital بيستوى واحد انش determine E by using the
+
+333
+00:41:37,930 --> 00:41:42,690
+formula from the tableبنحسب ال a اللى هى ال a
+
+334
+00:41:42,690 --> 00:41:51,290
+بالحالة هذى مستويهش RC-RN and
+
+335
+00:41:51,290 --> 00:41:55,150
+the approximation by using equation 93 اللى هى
+
+336
+00:41:55,150 --> 00:42:04,370
+المعادلة هذى في الحالة الأولى احنا ال RC يعني من
+
+337
+00:42:04,370 --> 00:42:08,950
+ال RC ممكن نعرف ايه ال RC اللى هو معطينيها 3 انش
+
+338
+00:42:10,290 --> 00:42:17,570
+معناة ال R I ايش هتساوي اللي هو R C minus R ال R C
+
+339
+00:42:17,570 --> 00:42:26,570
+اللي هي تلاتة ناقص واحد اتنين انش ال
+
+340
+00:42:26,570 --> 00:42:39,390
+R N هتساوي واحد تربيع على اتنين ال R C تلاتة
+
+341
+00:42:41,130 --> 00:42:47,350
+minus جزر تربيعه لتلاتة تربيع ناقص واحد تربيع
+
+342
+00:42:47,350 --> 00:42:50,510
+سيبوها
+
+343
+00:42:50,510 --> 00:42:55,870
+ال RN اتنين يا دكتور بابا وين الاتنين؟ الاتنين هنا
+
+344
+00:42:55,870 --> 00:43:00,170
+باشي
+
+345
+00:43:00,170 --> 00:43:04,390
+احسبوا ليها هذه
+
+346
+00:43:04,390 --> 00:43:07,470
+ال RN اكام؟ اكام؟
+
+347
+00:43:23,970 --> 00:43:34,870
+تلاتة ماينس اتنين point تسعة
+
+348
+00:43:34,870 --> 00:43:40,440
+واحد اربعة انشهذا في حالة استخدام المعادلة هذه في
+
+349
+00:43:40,440 --> 00:43:47,520
+حالة المعادلة التانية ال E بالساوية
+
+350
+00:43:47,520 --> 00:43:57,300
+I على RC في A الآن ال I ايش بالساوية باي على اربع
+
+351
+00:43:57,300 --> 00:44:06,700
+ستين دي تربيع يعني هتكون باي على اربع ستينفى اتنين
+
+352
+00:44:06,700 --> 00:44:14,560
+دى اصلا اربعة فى اتنين اصلا اربعة اتنين اصلا اربعة
+
+353
+00:44:14,560 --> 00:44:19,420
+من ستاش يعني باى على اربعة بيطلع حسبوا ليها و ال
+
+354
+00:44:19,420 --> 00:44:32,740
+area باى ار تربيع يعني هتكون ساوى باى حسبوا
+
+355
+00:44:32,740 --> 00:44:47,120
+لي الأولىمعناته ال E تقريبا سبت ال I بوين
+
+356
+00:44:47,120 --> 00:44:54,740
+سبعة تمانية خمسة بوين سبعة تمانية خمسة
+
+357
+00:44:54,740 --> 00:45:01,280
+معناته ال E هتكون سبعة بوين سبعة تمانية خمسة على
+
+358
+00:45:01,280 --> 00:45:03,980
+تلاتة في باي
+
+359
+00:45:08,210 --> 00:45:14,830
+بسيبها تلعب وانت اه انش
+
+360
+00:45:14,830 --> 00:45:20,290
+يعني
+
+361
+00:45:20,290 --> 00:45:25,210
+لو ده حسب ال error اللي
+
+362
+00:45:25,210 --> 00:45:26,930
+حسبه ال error ولا ال percentage difference
+
+363
+00:45:26,930 --> 00:45:33,270
+difference مش error percentage difference
+
+364
+00:45:36,200 --> 00:45:41,920
+هيكون الساوية point o تمانية ستة minus point o
+
+365
+00:45:41,920 --> 00:45:48,620
+تمانية تلاتة على point o تمانية ستة في مية اكم
+
+366
+00:45:48,620 --> 00:45:54,720
+هيطلع
+
+367
+00:45:54,720 --> 00:45:59,320
+نعم
+
+368
+00:46:05,250 --> 00:46:11,450
+إذا عملت approximation معناته هذه .. هذه ال more
+
+369
+00:46:11,450 --> 00:46:15,870
+accurate result هتكون هي ال reference هي المرجع ..
+
+370
+00:46:15,870 --> 00:46:21,430
+المرجع دي يعني بيكون الأكتر دقتاً هذا
+
+371
+00:46:21,430 --> 00:46:27,190
+approximation هذا approximation but this is
+
+372
+00:46:27,190 --> 00:46:31,630
+approximated value I'm approximating this how far
+
+373
+00:46:31,630 --> 00:46:36,770
+انت ال approximation منالـ more accurate أو الـ
+
+374
+00:46:36,770 --> 00:46:39,430
+expected to be more accurate يعني هاد expected to
+
+375
+00:46:39,430 --> 00:46:43,690
+be more accurate معناته إذا أنا عملت approximation
+
+376
+00:46:43,690 --> 00:46:51,990
+to some expected هتكون هاد هي أكتر دقة أكم تطلع؟
+
+377
+00:47:06,190 --> 00:47:15,390
+طيب أكتر الفرق بيطلع؟
+
+378
+00:47:15,390 --> 00:47:23,770
+تلاتة point أربعة تمانية يعني
+
+379
+00:47:23,770 --> 00:47:25,750
+فرق يعني ممكن اعتبره مقبول
+
+380
+00:47:35,400 --> 00:47:42,500
+طبعا في حالة المقطع مش محرز اعمل approximation لان
+
+381
+00:47:42,500 --> 00:47:48,140
+المعادلات بتاعة المقطع اللي اندور سهلة لكن لو اندي
+
+382
+00:47:48,140 --> 00:47:55,440
+مقطع .. مقطع زي هذا المعادلات
+
+383
+00:47:55,440 --> 00:47:58,880
+كبيرة فمحرز ان اعمل approximation
+
+384
+00:48:04,800 --> 00:48:20,440
+طيب نكمل طيب
+
+385
+00:48:20,440 --> 00:48:23,700
+هنشوف
+
+386
+00:48:23,700 --> 00:48:28,660
+نوع تاني من ال stresses اللي هيالاجهدات نتيجتي
+
+387
+00:48:28,660 --> 00:48:31,620
+التلامس اللى هى contact stresses او بيسموها
+
+388
+00:48:31,620 --> 00:48:34,920
+Herzian stresses contact stresses او Herzian
+
+389
+00:48:34,920 --> 00:48:40,520
+stresses اذا عندي two bodies و ال system الخارجى
+
+390
+00:48:40,520 --> 00:48:45,400
+بتاعتها منحانية curved surfaces لما نضعتهم مع بعض
+
+391
+00:48:45,400 --> 00:48:49,140
+بيصير deformation at the surfaces بيصير عندي
+
+392
+00:48:49,140 --> 00:48:52,420
+اجهدات بسميها contact stresses او ال Herzian
+
+393
+00:48:52,420 --> 00:48:52,840
+stresses
+
+394
+00:48:56,160 --> 00:48:59,560
+في حالة مثلا السفير على سفير بدون compression
+
+395
+00:48:59,560 --> 00:49:04,220
+بيكون النقطة التامس اللي بدها إيهاش سفير على سفير
+
+396
+00:49:04,220 --> 00:49:10,400
+نقطة لما under compression النقطة بتتحول لإيهاش ل
+
+397
+00:49:10,400 --> 00:49:16,980
+area إذا كانت سلندر على سلندر line ال compression
+
+398
+00:49:16,980 --> 00:49:21,720
+بيحولها برضه ل area point or line of contact
+
+399
+00:49:21,720 --> 00:49:25,360
+changes to area contact upon loading
+
+400
+00:49:27,570 --> 00:49:30,670
+طبيعة ال stress .. ال stresses ال nature three
+
+401
+00:49:30,670 --> 00:49:36,390
+dimensional ال nature امثل على حالة ال contact
+
+402
+00:49:36,390 --> 00:49:44,390
+stresses اذا عندي عجلة على .. على ريل عجلة عريل
+
+403
+00:49:44,390 --> 00:49:51,310
+طبعا عندي cylindrical surface على stress surface
+
+404
+00:49:51,310 --> 00:49:54,690
+بيصير عندي هنا contact stresses نتيجة ال loading
+
+405
+00:49:54,690 --> 00:50:04,960
+على العجلأو في حالة الـ two gears الـ gear هذا
+
+406
+00:50:04,960 --> 00:50:09,020
+كرت سيريز نتيجة ال loading ال point contact او ال
+
+407
+00:50:09,020 --> 00:50:15,960
+line contact بتحول ل area contact او في حالة ال
+
+408
+00:50:15,960 --> 00:50:22,560
+bearings ال bearings بيكون عندي outer raceو في
+
+409
+00:50:22,560 --> 00:50:27,400
+عندهم مثلا كورة inner race و outer race و في
+
+410
+00:50:27,400 --> 00:50:31,280
+loading على الكورات بيصيرهم بدل ما هو point
+
+411
+00:50:31,280 --> 00:50:38,740
+contact بتحول لاش ل area contact في
+
+412
+00:50:38,740 --> 00:50:45,560
+المباني عندهان two solid spheres عندها سفير واحد و
+
+413
+00:50:45,560 --> 00:50:51,660
+سفير اتنين قطر سفير واحد هذه دي واحد
+
+414
+00:50:56,790 --> 00:51:05,870
+هذه قطرها دي اتنين وفي
+
+415
+00:51:05,870 --> 00:51:11,850
+two forces F عندي
+
+416
+00:51:11,850 --> 00:51:17,690
+F على الجهة التانية هذا ال Z axis طبعا
+
+417
+00:51:17,690 --> 00:51:25,510
+ال material بتاعة ال أسفير هذه ال material بقى
+
+418
+00:51:25,510 --> 00:51:29,470
+كمواحدهذه ماتي الرقم اتنين due to the compression
+
+419
+00:51:29,470 --> 00:51:37,150
+force حسينا اندي هي area القطر بتاعي حسينا اندي
+
+420
+00:51:37,150 --> 00:51:41,410
+دائرة في الحالة هذه قطر
+
+421
+00:51:41,410 --> 00:51:47,370
+الدائرة اتنين ايه وال stress distribution is
+
+422
+00:51:50,130 --> 00:51:54,730
+non-linear stress distribution وقدر المنطقة طبعا
+
+423
+00:51:54,730 --> 00:51:59,870
+لما تكون ال contact على حواقف الدائرة يكون سفر
+
+424
+00:51:59,870 --> 00:52:05,850
+أكيد مظلوط على الحواقف سفر بعدين يكون maximum في
+
+425
+00:52:05,850 --> 00:52:12,010
+النص يكون ال stress maximum في النص ال maximum
+
+426
+00:52:12,010 --> 00:52:17,320
+pressureفي مركز ال contact area بتكون سوى تلاتة F
+
+427
+00:52:17,320 --> 00:52:23,040
+على اتنين by A تربيع الان ال A التي على الكوانت
+
+428
+00:52:23,040 --> 00:52:28,320
+القطرها اتنين A و نص القطر A بعتمد على ال two
+
+429
+00:52:28,320 --> 00:52:34,580
+materials مثل ال واحد و اتنين و القطر واحد و القطر
+
+430
+00:52:34,580 --> 00:52:40,180
+اتنين و بعتمد على ال F بزود ال F بتزيد ال A
+
+431
+00:52:50,350 --> 00:52:56,870
+Pmax المفروض إليها معادلة أنا
+
+432
+00:52:56,870 --> 00:53:03,530
+مش حاططها .. هاي المعادلة بتاعتها هاي المعادلة
+
+433
+00:53:03,530 --> 00:53:09,150
+بتعتبر
+
+434
+00:53:09,150 --> 00:53:12,010
+حكيتنا عن ال force زوّت ال force بتزيد ال a أكيد
+
+435
+00:53:13,510 --> 00:53:17,870
+بتعتمد على ال materials هندي poison ratio واحد
+
+436
+00:53:17,870 --> 00:53:22,650
+modulus velocity واحد poison ratio اتنين modulus
+
+437
+00:53:22,650 --> 00:53:26,770
+velocity اتنين يعني كل ما كان ال modulus velocity
+
+438
+00:53:26,770 --> 00:53:32,950
+صغير يعني زبارك يبقى اقل بكون كان زبارك طريق ال
+
+439
+00:53:32,950 --> 00:53:38,770
+area هتزيد صح؟كل ما تقل الزمبراكية يعني كانها soft
+
+440
+00:53:38,770 --> 00:53:44,310
+spring فال area ليه بيزيد مع ال model الاساسية
+
+441
+00:53:44,310 --> 00:53:47,970
+الان
+
+442
+00:53:47,970 --> 00:53:57,590
+and واحد على دي واحد زاد واحد على دي اتنين طبعا كل
+
+443
+00:53:57,590 --> 00:54:03,650
+ما بيزيد الأقطار لما تضغط الفرد بيكون أكتر تفرض
+
+444
+00:54:03,650 --> 00:54:21,560
+معاه أكتر صح؟فبتزيد ال a طيب
+
+445
+00:54:21,560 --> 00:54:26,300
+اذا كان ال maximum pressure معطلل اقل تلاتة F على
+
+446
+00:54:26,300 --> 00:54:33,030
+اتنين A تربيع والايل هي المعادلة السابقةلأن نتيجة
+
+447
+00:54:33,030 --> 00:54:35,610
+الـ Poisson Ratio Effect ان عندي I Compression في
+
+448
+00:54:35,610 --> 00:54:39,730
+اتجاه الـ Z Axis بيطلع عندى Sigma Z نتيجة الـ
+
+449
+00:54:39,730 --> 00:54:42,130
+Poisson Ratio Effect هيطلع عندى Sigma X و Sigma Y
+
+450
+00:54:42,130 --> 00:54:47,850
+Sigma X و Sigma Y اللي هيسميها Sigma X بيساوي
+
+451
+00:54:47,850 --> 00:54:50,250
+Sigma Y بيساوي Sigma X بيساوي Sigma Y بيساوي Sigma
+
+452
+00:54:50,250 --> 00:54:51,010
+X بيساوي Sigma Y بيساوي Sigma X بيساوي Sigma Y
+
+453
+00:54:51,010 --> 00:54:52,050
+بيساوي Sigma X بيساوي Sigma Y بيساوي Sigma X
+
+454
+00:54:52,050 --> 00:54:54,850
+بيساوي Sigma X بيساوي Sigma Y بيساوي Sigma X
+
+455
+00:54:54,850 --> 00:54:57,270
+بيساوي Sigma X بيساوي Sigma X بيساوي Sigma X
+
+456
+00:54:57,270 --> 00:54:57,570
+بيساوي Sigma X بيساوي Sigma X بيساوي Sigma X
+
+457
+00:54:57,570 --> 00:55:00,630
+بيساوي Sigma X بيساوي Sigma X بيسازد على ايه الزد
+
+458
+00:55:00,630 --> 00:55:05,830
+هي المسافة below the surface of contact يعني الزد
+
+459
+00:55:05,830 --> 00:55:13,970
+هاي عندى السلندر وهاي السلندر الزد هاي الزد هاي ال
+
+460
+00:55:13,970 --> 00:55:22,170
+zero هي ال zero زد كل منزل طبعا بيصير عندى زي مجال
+
+461
+00:55:22,170 --> 00:55:28,660
+مجال إجهادي كأنه مجال معناطيسيالان بيكون maximum
+
+462
+00:55:28,660 --> 00:55:37,440
+في بداية ال contact و كل ما أنزل لجوه بيبعد ..
+
+463
+00:55:37,440 --> 00:55:42,920
+بيبعد كتير بتريح المادة فيعني من غير معادلات من
+
+464
+00:55:42,920 --> 00:55:46,220
+الممكن تتوقعها فعندك minus P maximum في واحد minus
+
+465
+00:55:46,220 --> 00:55:49,240
+K مطلق على زد على A tan inverse واحد على زد على A
+
+466
+00:55:49,240 --> 00:55:52,220
+في واحد زد on U طيب
+
+467
+00:55:53,900 --> 00:55:57,840
+الـ sigma z مباشرة جاي من ال pressure من ال
+
+468
+00:55:57,840 --> 00:56:00,300
+maximum pressure minus P maximum على واحد زي z
+
+469
+00:56:00,300 --> 00:56:06,860
+تربيع على a تربيع يعني ال z approach infinity
+
+470
+00:56:06,860 --> 00:56:15,010
+sigma z approach zero يعني far from the contactفش
+
+471
+00:56:15,010 --> 00:56:19,350
+stress بيكون عندك، far from the contact فش stress
+
+472
+00:56:19,350 --> 00:56:30,750
+حاول مثلا تضغط عيدك لفترة طويلة شعار
+
+473
+00:56:30,750 --> 00:56:33,750
+بتحس أنه فيه stress على ال surface أعلى ما يمكن
+
+474
+00:56:33,750 --> 00:56:37,070
+لجوه بيخف بعد فترة ما تسيبه يريح
+
+475
+00:56:40,360 --> 00:56:46,140
+بصير عملية اللى هى برجع تضافق الدم طبيعى فبصير
+
+476
+00:56:46,140 --> 00:56:56,780
+اعادة توزيع للاجهدات و ترجع المادة لطبيعتها طبعا
+
+477
+00:56:56,780 --> 00:57:00,260
+ال stress أخلاقات stress element عند ال contact
+
+478
+00:57:00,260 --> 00:57:03,880
+stress element مباشرة عند ال contact
+
+479
+00:57:07,770 --> 00:57:19,130
+أو حتى بلوذا surface هكون دي هذا sigma z هاي
+
+480
+00:57:19,130 --> 00:57:28,070
+هناك sigma x يعني ماتتركزوش على اتجاهات حالياً هاي
+
+481
+00:57:28,070 --> 00:57:36,840
+sigma y واضح انه الإجهادات هذههذه ال stress ال
+
+482
+00:57:36,840 --> 00:57:42,360
+principal stress ليش؟ لأن مافيش شير ال principal
+
+483
+00:57:42,360 --> 00:57:45,320
+stress المقنعة ممكن أسميها سجن واحد سجن اتنين او
+
+484
+00:57:45,320 --> 00:57:50,480
+سجن تلاتة ومنها
+
+485
+00:57:50,480 --> 00:57:54,800
+بحسب tau max لأن اذا انا برتقله سجن واحد اكبر من
+
+486
+00:57:54,800 --> 00:58:00,840
+سجن اتنين اكبر من سجن تلاتة بحسب tau max بستوى سجن
+
+487
+00:58:00,840 --> 00:58:04,260
+واحد minus سجن تلاتة على اتنين
+
+488
+00:58:08,520 --> 00:58:11,580
+لو أخدنا مثلا الحديد ال poison rage بتاعة الحديد
+
+489
+00:58:11,580 --> 00:58:17,320
+تلاتة من عشرة تطلع ال tau max بسبب point تلاتة P
+
+490
+00:58:17,320 --> 00:58:23,020
+max at a depth of point four eight A على عمق
+
+491
+00:58:23,020 --> 00:58:30,340
+تقريبا point خمسة L A اتطلع
+
+492
+00:58:30,340 --> 00:58:34,680
+انا اللي بيصير عندى هاي
+
+493
+00:58:34,680 --> 00:58:41,950
+عندى ال Zالـ Z يعني المسافة تحت السطح على السطح
+
+494
+00:58:41,950 --> 00:58:48,010
+مباشرة Zero كل منزل لجوه الـ Z مالقاش بتزيد وهين
+
+495
+00:58:48,010 --> 00:58:51,770
+ال stress هين طبعا ال Sigma Z هذا ال Sigma Z زي ما
+
+496
+00:58:51,770 --> 00:58:58,230
+احكي هنا Sigma Z بيكون maximum عند ال Z Zero ال Z
+
+497
+00:58:58,230 --> 00:59:05,160
+goes to infinity بروح بتجاه سفر Sigma Zو ال sigma
+
+498
+00:59:05,160 --> 00:59:09,500
+x و sigma y برضه هاد ال sigma x و sigma y بتكون
+
+499
+00:59:09,500 --> 00:59:14,400
+maximum عند zero as z goes to infinity بتروح متجاه
+
+500
+00:59:14,400 --> 00:59:20,860
+الصفر لكن احنا حكينا ال tau match سوى sigma 1
+
+501
+00:59:20,860 --> 00:59:26,920
+minus sigma 3 لحظ الفرق هنا الفرق بين sigma 1 و
+
+502
+00:59:26,920 --> 00:59:31,280
+sigma 3 هاي الفرق عند النقطة هادة
+
+503
+00:59:34,980 --> 00:59:38,620
+هي الفرق صح؟ مش احنا نستوى انا استوى ماكسوف سيجما
+
+504
+00:59:38,620 --> 00:59:42,840
+واحد معناه سيجما تلاتة على اتنين يعني مص المسافة
+
+505
+00:59:42,840 --> 00:59:49,720
+هذه اللي هي هذه اللي هي هذه صح فال stress السيجما
+
+506
+00:59:49,720 --> 00:59:52,660
+واحد سيجما X سيجما Y سيجما Z بتكون maximum at Z
+
+507
+00:59:52,660 --> 00:59:55,760
+بيستوى Zero لكن ال shear stress maximum shear
+
+508
+00:59:55,760 --> 01:00:00,140
+stress بيكون at some distance below the surface في
+
+509
+01:00:00,140 --> 01:00:00,620
+حالة
+
+510
+01:00:04,400 --> 01:00:10,000
+الشيارة تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+511
+01:00:10,000 --> 01:00:14,180
+تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+512
+01:00:14,180 --> 01:00:14,300
+تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+513
+01:00:14,300 --> 01:00:18,900
+تقريبا تقريبا
+
+514
+01:00:18,900 --> 01:00:25,860
+تقريب
+
+515
+01:00:26,300 --> 01:00:29,220
+two cylinders contact يعني عندي هذا بطل تسفير هذا
+
+516
+01:00:29,220 --> 01:00:32,900
+السيلندر وهذا السيلندر برضه ال line contact هتحول
+
+517
+01:00:32,900 --> 01:00:37,900
+ل area contact عرض ال .. عرض ال area اللي هو اتنين
+
+518
+01:00:37,900 --> 01:00:42,080
+بيه والعمق اللي هو طول السيلندر طول السيلندر
+
+519
+01:00:42,080 --> 01:00:44,140
+الأقصر إذا كانوا مش نفس الطول
+
+520
+01:00:48,200 --> 01:00:51,120
+الـ B هو الطوابع العلاقه هذه الـ B هي حاجة تتعمل
+
+521
+01:00:51,120 --> 01:00:55,560
+ألف بزيدي ال F بزيدي ال B ال B هي هذه ال two B
+
+522
+01:00:55,560 --> 01:01:03,120
+بزيدي ال E بزيدي ال B بزيدي ال D بزيدي ال H برضه
+
+523
+01:01:03,120 --> 01:01:06,980
+ال B ال maximum pressure بيكون سواء اتنين F على بي
+
+524
+01:01:06,980 --> 01:01:13,120
+بي ال ال L هو طول استوانه البعد التالت و
+
+525
+01:01:13,120 --> 01:01:18,380
+طبعا فى عندى تلاتة stresses فى عندى Sigma Zسيجما X
+
+526
+01:01:18,380 --> 01:01:25,580
+وسيجما Y طبعا بيكونوا maximum at z equal zero عند
+
+527
+01:01:25,580 --> 01:01:29,520
+ال contact سيجما
+
+528
+01:01:29,520 --> 01:01:38,620
+Z وسيجما Y وسيجما X بيكونوا maximum at zero ال
+
+529
+01:01:38,620 --> 01:01:44,760
+tau max هي ال tau max بتكون at some distance below
+
+530
+01:01:44,760 --> 01:01:46,140
+the surface
+
+531
+01:01:48,870 --> 01:01:53,870
+Tau maximum and for Poise ratio point تلاتة بتكون
+
+532
+01:01:53,870 --> 01:01:56,690
+at a distance بسبب point سبعة تمانية ستة بيه طبعا
+
+533
+01:01:56,690 --> 01:02:03,210
+هذا هو z as a function of d وهذا ال access لل
+
+534
+01:02:03,210 --> 01:02:09,410
+stress في
+
+535
+01:02:09,410 --> 01:02:17,220
+اي سؤال؟شوفوا كمان خلصنا chapter تلاتة يعني تقريبا
+
+536
+01:02:17,220 --> 01:02:20,380
+قطينا كل ال mechanics of material مع بعض الشغلات
+
+537
+01:02:20,380 --> 01:02:22,480
+أعلى من مستوى ال mechanics of material
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/FFFtpNPdpGc_raw.json b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/FFFtpNPdpGc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..3a55f5ab586872a5ecdbca9ab9e1648a1f903f81
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/FFFtpNPdpGc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3299, "start": 5.53, "end": 32.99, "text": "بسم الله الرحمن الرحيم السلام عليكم ورحمة الله وبركاته اليوم هنكمل في chapter تلاتة stress and load analysis اليوم الموضوع هيكون curved beams in bending سابقا درسنا ال bending في ال straight beams حكينا ال sigma بساوة M في C basically sigma بساوة M في C على I", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 21136, 37440, 25894, 24793, 4032, 2288, 35571, 3660, 21984, 4032, 26890, 4117, 9307, 3224, 45595, 20498, 8032, 1863, 24793, 1211, 8978, 7187, 6055, 1211, 9307, 3660, 4244, 293, 3677, 5215, 45595, 20498, 9673, 2407, 11242, 45367, 8032, 1829, 30544, 24991, 31040, 294, 22487, 8608, 16758, 4587, 995, 11778, 2288, 3794, 8315, 2423, 22487, 8978, 2423, 2997, 31040, 11331, 4117, 1829, 8315, 2423, 12771, 4724, 3794, 995, 2407, 3660, 376, 8978, 383, 1936, 12771, 4724, 3794, 995, 2407, 3660, 376, 8978, 383, 15844, 286], "avg_logprob": -0.1772513395996504, "compression_ratio": 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bending ال stress بتغير مع الوعي", "tokens": [2407, 2423, 4244, 39894, 17082, 13546, 43586, 37495, 22653, 45164, 25961, 2655, 3714, 47432, 3615, 3714, 14851, 9566, 26895, 8978, 47356, 22487, 2423, 4244, 39894, 17082, 13546, 20449, 2423, 45367, 1829], "avg_logprob": -0.13745117792859674, "compression_ratio": 1.2727272727272727, "no_speech_prob": 0.0, "words": [{"start": 34.88, "end": 35.14, "word": "و", "probability": 0.939453125}, {"start": 35.14, "end": 35.3, "word": " ال", "probability": 0.798828125}, {"start": 35.3, "end": 36.1, "word": " stress", "probability": 0.96630859375}, {"start": 36.1, "end": 37.34, "word": " بتغير", "probability": 0.9549153645833334}, {"start": 37.34, "end": 37.96, "word": " linearly", "probability": 0.955078125}, {"start": 37.96, "end": 39.58, "word": " يعني", "probability": 0.757568359375}, {"start": 39.58, "end": 39.76, "word": " لو", "probability": 0.9775390625}, {"start": 39.76, "end": 40.22, "word": " كانت", "probability": 0.931640625}, {"start": 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"word": " هذا", "probability": 0.5}, {"start": 170.69, "end": 175.31, "word": " الـ", "probability": 0.753173828125}, {"start": 175.31, "end": 175.51, "word": " neutral", "probability": 0.9619140625}, {"start": 175.51, "end": 176.87, "word": " axis", "probability": 0.908203125}, {"start": 176.87, "end": 178.79, "word": " و", "probability": 0.8369140625}, {"start": 178.79, "end": 179.41, "word": " فيه", "probability": 0.672607421875}, {"start": 179.41, "end": 179.89, "word": " bending", "probability": 0.64501953125}, {"start": 179.89, "end": 180.47, "word": " moment", "probability": 0.98193359375}, {"start": 180.47, "end": 181.43, "word": " M", "probability": 0.77490234375}], "temperature": 1.0}, {"id": 8, "seek": 22593, "start": 203.73, "end": 225.93, "text": "طبعا لو أخدت مقطع هنا ممكن نحكي هذا ال general shape مثلا للمقطع ارتفاع المقطع H فانا حاكي ان هذا هو ال neutral axis وهذا ال centroidal axis", "tokens": [9566, 3555, 3615, 995, 45164, 5551, 9778, 3215, 2655, 3714, 47432, 3615, 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"probability": 0.94873046875}, {"start": 243.33, "end": 249.75, "word": " ال", "probability": 0.196044921875}, {"start": 249.75, "end": 250.07, "word": " neutral", "probability": 0.85498046875}, {"start": 250.07, "end": 250.85, "word": " axis", "probability": 0.94970703125}, {"start": 250.85, "end": 252.79, "word": " في", "probability": 0.55517578125}, {"start": 252.79, "end": 253.21, "word": " طبعا", "probability": 0.9012451171875}, {"start": 253.21, "end": 253.69, "word": " offset", "probability": 0.32861328125}, {"start": 253.69, "end": 254.33, "word": " distance", "probability": 0.96435546875}, {"start": 254.33, "end": 254.81, "word": " بين", "probability": 0.9189453125}, {"start": 254.81, "end": 255.29, "word": " ال", "probability": 0.84619140625}, {"start": 255.29, "end": 255.61, "word": " central", "probability": 0.92236328125}, {"start": 255.61, "end": 256.17, "word": " axis", "probability": 0.9697265625}, {"start": 256.17, "end": 256.33, "word": " و", "probability": 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هسميها ايش هتكون هذه Y يعني ال R زاد ال Y بيستوي ايش؟ RN ال R زاد ال Y", "tokens": [28814, 15730, 16490, 3215, 8315, 36632, 4478, 15844, 39182, 497, 9154, 3714, 31747, 11622, 16712, 4117, 2407, 11703, 2288, 29538, 9673, 3794, 31845, 3660, 497, 8032, 38251, 1829, 11296, 1975, 1829, 8592, 8032, 2655, 30544, 29538, 398, 37495, 22653, 2423, 497, 30767, 18513, 2423, 398, 4724, 1829, 14851, 45865, 1975, 1829, 8592, 22807, 497, 45, 2423, 497, 30767, 18513, 2423, 398], "avg_logprob": -0.3220766028088908, "compression_ratio": 1.4589041095890412, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 315.07, "end": 315.39, "word": "إذا", "probability": 0.75244140625}, {"start": 315.39, "end": 315.75, "word": " خدنا", "probability": 0.7433268229166666}, {"start": 315.75, "end": 316.05, "word": " أي", "probability": 0.85693359375}, {"start": 316.05, "end": 316.67, "word": " element", "probability": 0.916015625}, {"start": 316.67, "end": 318.19, "word": " على", "probability": 0.859375}, 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"end": 335.43, "word": " Y", "probability": 0.84423828125}, {"start": 335.43, "end": 339.55, "word": " يعني", "probability": 0.912353515625}, {"start": 339.55, "end": 340.79, "word": " ال", "probability": 0.8349609375}, {"start": 340.79, "end": 341.03, "word": " R", "probability": 0.71923828125}, {"start": 341.03, "end": 341.33, "word": " زاد", "probability": 0.46142578125}, {"start": 341.33, "end": 341.47, "word": " ال", "probability": 0.86279296875}, {"start": 341.47, "end": 341.63, "word": " Y", "probability": 0.97705078125}, {"start": 341.63, "end": 342.07, "word": " بيستوي", "probability": 0.7781982421875}, {"start": 342.07, "end": 342.47, "word": " ايش؟", "probability": 0.71142578125}, {"start": 342.47, "end": 342.91, "word": " RN", "probability": 0.3563232421875}, {"start": 342.91, "end": 343.39, "word": " ال", "probability": 0.63037109375}, {"start": 343.39, "end": 343.63, "word": " R", "probability": 0.91943359375}, {"start": 343.63, "end": 343.89, "word": " زاد", 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"probability": 0.98779296875}, {"start": 369.59, "end": 370.19, "word": " الدراسة", "probability": 0.98876953125}], "temperature": 1.0}, {"id": 13, "seek": 39826, "start": 383.9, "end": 398.26, "text": "المسافة من الـ neutral axis لل inner fibre سميها CI والمسافة من ال neutral axis لل outer fibre ساميها CO", "tokens": [45340, 3794, 31845, 3660, 9154, 2423, 39184, 10598, 10298, 24976, 7284, 36738, 8608, 2304, 1829, 11296, 37777, 16070, 2304, 3794, 31845, 3660, 9154, 2423, 10598, 10298, 24976, 10847, 36738, 8608, 10943, 1829, 11296, 3002], "avg_logprob": -0.19921875, "compression_ratio": 1.5052631578947369, "no_speech_prob": 0.0, "words": [{"start": 383.9, "end": 384.66, "word": "المسافة", "probability": 0.9757080078125}, {"start": 384.66, "end": 384.78, "word": " من", "probability": 0.9814453125}, {"start": 384.78, "end": 384.86, "word": " الـ", "probability": 0.7005615234375}, {"start": 384.86, "end": 385.04, "word": " neutral", "probability": 0.87158203125}, {"start": 385.04, "end": 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"end": 2210.03, "word": " AA", "probability": 0.4404296875}, {"start": 2210.03, "end": 2212.53, "word": " في", "probability": 0.884765625}, {"start": 2212.53, "end": 2213.05, "word": " RN", "probability": 0.97119140625}], "temperature": 1.0}, {"id": 75, "seek": 223848, "start": 2214.13, "end": 2238.49, "text": "ناقص Y بعود عن ال A ال A اللي هي I على RC في A بسرع الشغل تطلع اندياش", "tokens": [1863, 995, 4587, 9381, 398, 45030, 23328, 18871, 2423, 316, 2423, 316, 13672, 1829, 39896, 286, 15844, 28987, 8978, 316, 4724, 3794, 2288, 3615, 25124, 17082, 1211, 6055, 9566, 1211, 3615, 16472, 16254, 33599], "avg_logprob": -0.3926339302744184, "compression_ratio": 1.2150537634408602, "no_speech_prob": 0.0, "words": [{"start": 2214.13, "end": 2214.83, "word": "ناقص", "probability": 0.68408203125}, {"start": 2214.83, "end": 2215.17, "word": " Y", "probability": 0.483642578125}, {"start": 2215.17, "end": 2219.25, "word": " بعود", "probability": 0.609619140625}, {"start": 2219.25, "end": 2219.53, "word": " عن", "probability": 0.740234375}, {"start": 2219.53, "end": 2219.85, "word": " ال", "probability": 0.9375}, {"start": 2219.85, "end": 2221.29, "word": " A", "probability": 0.69970703125}, {"start": 2221.29, "end": 2229.49, "word": " ال", "probability": 0.53564453125}, {"start": 2229.49, "end": 2229.83, "word": " A", "probability": 0.8076171875}, {"start": 2229.83, "end": 2231.27, "word": " اللي", "probability": 0.638427734375}, {"start": 2231.27, "end": 2231.51, "word": " هي", "probability": 0.912109375}, {"start": 2231.51, "end": 2231.93, "word": " I", "probability": 0.94677734375}, {"start": 2231.93, "end": 2233.35, "word": " على", "probability": 0.74169921875}, {"start": 2233.35, "end": 2233.89, "word": " RC", "probability": 0.83154296875}, {"start": 2233.89, "end": 2235.17, "word": " في", "probability": 0.83154296875}, {"start": 2235.17, "end": 2235.57, "word": " A", "probability": 0.92041015625}, {"start": 2235.57, "end": 2236.41, "word": " بسرع", "probability": 0.512298583984375}, {"start": 2236.41, "end": 2237.25, "word": " الشغل", "probability": 0.9597981770833334}, {"start": 2237.25, "end": 2237.99, "word": " تطلع", "probability": 0.8665771484375}, {"start": 2237.99, "end": 2238.49, "word": " اندياش", "probability": 0.4320475260416667}], "temperature": 1.0}, {"id": 76, "seek": 226186, "start": 2239.58, "end": 2261.86, "text": "المعادلة هي تقريبا سيجما وهنا بيعتبر رن ماينوس واي اللي هي هذه ايش ر تطلع عند المعادلة سيجما تقريبا م في واي على اي في ار سي على ار هذا في الحال كان عندي large curvature للبيمة", "tokens": [45340, 3615, 18513, 37977, 39896, 6055, 4587, 16572, 3555, 995, 8608, 1829, 7435, 15042, 37037, 8315, 4724, 1829, 34268, 26890, 12602, 1863, 19446, 9957, 41779, 4032, 47302, 13672, 1829, 39896, 29538, 1975, 1829, 8592, 12602, 6055, 9566, 1211, 3615, 43242, 9673, 3615, 18513, 37977, 8608, 1829, 7435, 15042, 6055, 4587, 16572, 3555, 995, 3714, 8978, 36764, 1829, 15844, 1975, 1829, 8978, 1975, 2288, 8608, 1829, 15844, 1975, 2288, 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" واي", "probability": 0.6624755859375}, {"start": 2253.04, "end": 2253.22, "word": " على", "probability": 0.65576171875}, {"start": 2253.22, "end": 2253.64, "word": " اي", "probability": 0.88134765625}, {"start": 2253.64, "end": 2253.82, "word": " في", "probability": 0.90185546875}, {"start": 2253.82, "end": 2254.1, "word": " ار", "probability": 0.5570068359375}, {"start": 2254.1, "end": 2254.5, "word": " سي", "probability": 0.783447265625}, {"start": 2254.5, "end": 2254.76, "word": " على", "probability": 0.80029296875}, {"start": 2254.76, "end": 2255.72, "word": " ار", "probability": 0.904052734375}, {"start": 2255.72, "end": 2256.86, "word": " هذا", "probability": 0.73779296875}, {"start": 2256.86, "end": 2257.0, "word": " في", "probability": 0.853515625}, {"start": 2257.0, "end": 2257.18, "word": " الحال", "probability": 0.7432861328125}, {"start": 2257.18, "end": 2257.38, "word": " كان", "probability": 0.55224609375}, {"start": 2257.38, "end": 2257.72, "word": " عندي", "probability": 0.6737060546875}, {"start": 2257.72, "end": 2259.8, "word": " large", "probability": 0.73486328125}, {"start": 2259.8, "end": 2260.4, "word": " curvature", "probability": 0.98193359375}, {"start": 2260.4, "end": 2261.86, "word": " للبيمة", "probability": 0.6876220703125}], "temperature": 1.0}, {"id": 77, "seek": 230201, "start": 2275.83, "end": 2302.01, "text": "يعني لو انا جبت two beams نفس المقطع و نفس التحميل يعني اذا جبت beam زي هيك عدل المقطع طبعا مستطيل و عليها distributed load اي حالة حالة تانية نفس ال span", "tokens": [40228, 22653, 45164, 1975, 8315, 10874, 3555, 2655, 732, 31040, 8717, 36178, 9673, 47432, 3615, 4032, 8717, 36178, 16712, 35571, 26895, 37495, 22653, 1975, 15730, 10874, 3555, 2655, 14269, 30767, 1829, 39896, 4117, 6225, 3215, 1211, 9673, 47432, 3615, 23032, 3555, 3615, 995, 3714, 14851, 9566, 26895, 4032, 25894, 11296, 12631, 3677, 1975, 1829, 11331, 6027, 3660, 11331, 6027, 3660, 6055, 7649, 10632, 8717, 36178, 2423, 16174], "avg_logprob": 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"probability": 0.9837239583333334}, {"start": 2281.43, "end": 2282.17, "word": " يعني", "probability": 0.7039794921875}, {"start": 2282.17, "end": 2282.29, "word": " اذا", "probability": 0.5640869140625}, {"start": 2282.29, "end": 2282.47, "word": " جبت", "probability": 0.9597981770833334}, {"start": 2282.47, "end": 2282.83, "word": " beam", "probability": 0.424560546875}, {"start": 2282.83, "end": 2283.03, "word": " زي", "probability": 0.5928955078125}, {"start": 2283.03, "end": 2283.31, "word": " هيك", "probability": 0.6810302734375}, {"start": 2283.31, "end": 2283.69, "word": " عدل", "probability": 0.7307942708333334}, {"start": 2283.69, "end": 2285.21, "word": " المقطع", "probability": 0.9012044270833334}, {"start": 2285.21, "end": 2285.47, "word": " طبعا", "probability": 0.973876953125}, {"start": 2285.47, "end": 2286.15, "word": " مستطيل", "probability": 0.91796875}, {"start": 2286.15, "end": 2292.05, "word": " و", "probability": 0.814453125}, {"start": 2292.05, "end": 2292.31, "word": " عليها", "probability": 0.504150390625}, {"start": 2292.31, "end": 2292.69, "word": " distributed", "probability": 0.7470703125}, {"start": 2292.69, "end": 2293.09, "word": " load", "probability": 0.9873046875}, {"start": 2293.09, "end": 2295.89, "word": " اي", "probability": 0.5615234375}, {"start": 2295.89, "end": 2296.41, "word": " حالة", "probability": 0.986328125}, {"start": 2296.41, "end": 2297.95, "word": " حالة", "probability": 0.94140625}, {"start": 2297.95, "end": 2298.45, "word": " تانية", "probability": 0.97998046875}, {"start": 2298.45, "end": 2301.47, "word": " نفس", "probability": 0.987548828125}, {"start": 2301.47, "end": 2301.61, "word": " ال", "probability": 0.81640625}, {"start": 2301.61, "end": 2302.01, "word": " span", "probability": 0.9853515625}], "temperature": 1.0}, {"id": 78, "seek": 234771, "start": 2320.58, "end": 2347.72, "text": "و نفس الـ distributed load load موظّع متوقع مين يعني أداء يكون أحسن هدا ال beam و لا هدا ال beam يعني لو كان هنا ال distribution ميت ميت النيوتن لكل متر", "tokens": [2407, 8717, 36178, 2423, 39184, 12631, 3677, 3677, 3714, 2407, 19913, 11703, 3615, 3714, 2655, 30543, 3615, 3714, 9957, 37495, 22653, 5551, 3215, 16606, 7251, 30544, 5551, 5016, 3794, 1863, 8032, 28259, 2423, 14269, 4032, 20193, 8032, 28259, 2423, 14269, 37495, 22653, 45164, 25961, 34105, 2423, 7316, 3714, 36081, 3714, 36081, 28239, 1829, 35473, 1863, 5296, 28820, 44650, 2288], "avg_logprob": -0.3682291805744171, "compression_ratio": 1.5294117647058822, "no_speech_prob": 0.0, "words": [{"start": 2320.58, "end": 2320.78, "word": "و", "probability": 0.8466796875}, {"start": 2320.78, "end": 2321.04, "word": " نفس", "probability": 0.935546875}, {"start": 2321.04, "end": 2321.14, "word": " الـ", "probability": 0.4339447021484375}, {"start": 2321.14, "end": 2321.46, "word": " distributed", "probability": 0.71826171875}, {"start": 2321.46, "end": 2321.8, "word": " load", "probability": 0.9619140625}, {"start": 2321.8, "end": 2322.72, "word": " load", "probability": 0.29833984375}, {"start": 2322.72, "end": 2323.26, "word": " موظّع", "probability": 0.6814453125}, {"start": 2323.26, "end": 2330.32, "word": " متوقع", "probability": 0.79632568359375}, {"start": 2330.32, "end": 2330.58, "word": " مين", "probability": 0.645263671875}, {"start": 2330.58, "end": 2331.04, "word": " يعني", "probability": 0.71533203125}, {"start": 2331.04, "end": 2332.82, "word": " أداء", "probability": 0.9091796875}, {"start": 2332.82, "end": 2333.04, "word": " يكون", "probability": 0.982177734375}, {"start": 2333.04, "end": 2333.36, "word": " أحسن", "probability": 0.983154296875}, {"start": 2333.36, "end": 2333.6, "word": " هدا", "probability": 0.398681640625}, {"start": 2333.6, "end": 2333.74, "word": " ال", "probability": 0.97119140625}, {"start": 2333.74, "end": 2333.94, "word": " beam", "probability": 0.8125}, {"start": 2333.94, "end": 2334.1, "word": " و", "probability": 0.32470703125}, {"start": 2334.1, "end": 2334.16, "word": " لا", "probability": 0.98486328125}, {"start": 2334.16, "end": 2334.36, "word": " هدا", "probability": 0.85546875}, {"start": 2334.36, "end": 2334.5, "word": " ال", "probability": 0.900390625}, {"start": 2334.5, "end": 2334.82, "word": " beam", "probability": 0.95458984375}, {"start": 2334.82, "end": 2342.12, "word": " يعني", "probability": 0.72216796875}, {"start": 2342.12, "end": 2342.28, "word": " لو", "probability": 0.96484375}, {"start": 2342.28, "end": 2342.48, "word": " كان", "probability": 0.98046875}, {"start": 2342.48, "end": 2342.66, "word": " هنا", "probability": 0.7021484375}, {"start": 2342.66, "end": 2342.74, "word": " ال", "probability": 0.87646484375}, {"start": 2342.74, "end": 2343.84, "word": " distribution", "probability": 0.129150390625}, {"start": 2343.84, "end": 2344.68, "word": " ميت", "probability": 0.5709228515625}, {"start": 2344.68, "end": 2345.1, "word": " ميت", "probability": 0.7271728515625}, {"start": 2345.1, "end": 2346.7, "word": " النيوتن", "probability": 0.700439453125}, {"start": 2346.7, "end": 2347.38, "word": " لكل", "probability": 0.979248046875}, {"start": 2347.38, "end": 2347.72, "word": " متر", "probability": 0.965087890625}], "temperature": 1.0}, {"id": 79, "seek": 237689, "start": 2349.35, "end": 2376.89, "text": "متوقع هذا يشيل نفس ال section متوقع هذا يشيل أكتر ولا أقل من هذا؟ لأ هذا هشيل أقل هشيل أكتر وزم معناه ال stress level هكون أقل من stress level هذا هنا عشان في الجصور بيعملوا curvature بيعملوا curvature طيب نشوف مثال", "tokens": [2304, 2655, 30543, 3615, 23758, 7251, 8592, 26895, 8717, 36178, 2423, 3541, 44650, 30543, 3615, 23758, 7251, 8592, 26895, 5551, 4117, 2655, 2288, 49429, 5551, 4587, 1211, 9154, 23758, 22807, 5296, 10721, 23758, 8032, 8592, 26895, 5551, 4587, 1211, 8032, 8592, 26895, 5551, 4117, 2655, 2288, 4032, 11622, 2304, 20449, 8315, 3224, 2423, 4244, 1496, 8032, 30544, 5551, 4587, 1211, 9154, 4244, 1496, 23758, 34105, 6225, 8592, 7649, 8978, 25724, 9381, 13063, 4724, 1829, 25957, 1211, 14407, 37638, 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"temperature": 1.0}, {"id": 81, "seek": 244094, "start": 2418.12, "end": 2440.94, "text": "هذا ال E وهذا ال R C وهذا نص ال readers بتاعتها R رئيسية و ال R C طبعا هذا ر I وهذا ر O", "tokens": [3224, 15730, 2423, 462, 37037, 15730, 2423, 497, 383, 37037, 15730, 8717, 9381, 2423, 1401, 433, 39894, 995, 34268, 11296, 497, 12602, 19986, 1829, 3794, 10632, 4032, 2423, 497, 383, 23032, 3555, 3615, 995, 23758, 12602, 286, 37037, 15730, 12602, 422], "avg_logprob": -0.5204613222962334, "compression_ratio": 1.3917525773195876, "no_speech_prob": 0.0, "words": [{"start": 2418.12, "end": 2418.48, "word": "هذا", "probability": 0.923828125}, {"start": 2418.48, "end": 2418.64, "word": " ال", "probability": 0.89794921875}, {"start": 2418.64, "end": 2418.92, "word": " E", "probability": 0.5400390625}, {"start": 2418.92, "end": 2421.32, "word": " وهذا", "probability": 0.7291259765625}, {"start": 2421.32, "end": 2421.76, "word": " ال", "probability": 0.11053466796875}, {"start": 2421.76, "end": 2424.16, "word": " R", "probability": 0.6611328125}, {"start": 2424.16, "end": 2425.3, "word": " C", "probability": 0.556640625}, {"start": 2425.3, "end": 2427.04, "word": " وهذا", "probability": 0.8173828125}, {"start": 2427.04, "end": 2427.3, "word": " نص", "probability": 0.964111328125}, {"start": 2427.3, "end": 2427.44, "word": " ال", "probability": 0.7919921875}, {"start": 2427.44, "end": 2428.16, "word": " readers", "probability": 0.25640869140625}, {"start": 2428.16, "end": 2428.58, "word": " بتاعتها", "probability": 0.726806640625}, {"start": 2428.58, "end": 2429.2, "word": " R", "probability": 0.39013671875}, {"start": 2429.2, "end": 2430.44, "word": " رئيسية", "probability": 0.480712890625}, {"start": 2430.44, "end": 2431.1, "word": " و", "probability": 0.1490478515625}, {"start": 2431.1, "end": 2432.94, "word": " ال", "probability": 0.66748046875}, {"start": 2432.94, "end": 2433.24, "word": " R", "probability": 0.7841796875}, {"start": 2433.24, "end": 2433.52, "word": " C", "probability": 0.9189453125}, {"start": 2433.52, "end": 2433.86, "word": " طبعا", "probability": 0.953857421875}, {"start": 2433.86, "end": 2434.02, "word": " هذا", "probability": 0.7275390625}, {"start": 2434.02, "end": 2434.26, "word": " ر", "probability": 0.50146484375}, {"start": 2434.26, "end": 2434.62, "word": " I", "probability": 0.7236328125}, {"start": 2434.62, "end": 2438.94, "word": " وهذا", "probability": 0.874755859375}, {"start": 2438.94, "end": 2439.62, "word": " ر", "probability": 0.64794921875}, {"start": 2439.62, "end": 2440.94, "word": " O", "probability": 0.90087890625}], "temperature": 1.0}, {"id": 82, "seek": 247212, "start": 2445.22, "end": 2472.12, "text": "الار سي بالساوية الار اي زاد الار كابيتال والار ان بالساوية ار سكوار على اتنين في ار سي minus جزر التربيع ايه الار سي تربيع minus ار تربيع", "tokens": [6027, 9640, 8608, 1829, 20666, 3794, 995, 2407, 10632, 2423, 9640, 1975, 1829, 30767, 18513, 2423, 9640, 9122, 16758, 36081, 6027, 16070, 9640, 16472, 20666, 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{"start": 2452.06, "end": 2452.76, "word": " كابيتال", "probability": 0.71759033203125}, {"start": 2452.76, "end": 2454.02, "word": " والار", "probability": 0.87744140625}, {"start": 2454.02, "end": 2454.38, "word": " ان", "probability": 0.80859375}, {"start": 2454.38, "end": 2456.6, "word": " بالساوية", "probability": 0.96337890625}, {"start": 2456.6, "end": 2456.88, "word": " ار", "probability": 0.706787109375}, {"start": 2456.88, "end": 2457.44, "word": " سكوار", "probability": 0.642578125}, {"start": 2457.44, "end": 2459.96, "word": " على", "probability": 0.5498046875}, {"start": 2459.96, "end": 2460.68, "word": " اتنين", "probability": 0.9686279296875}, {"start": 2460.68, "end": 2462.28, "word": " في", "probability": 0.91455078125}, {"start": 2462.28, "end": 2463.6, "word": " ار", "probability": 0.631103515625}, {"start": 2463.6, "end": 2464.22, "word": " سي", "probability": 0.961181640625}, {"start": 2464.22, "end": 2466.08, "word": " minus", "probability": 0.56298828125}, {"start": 2466.08, "end": 2466.42, "word": " جزر", "probability": 0.8426106770833334}, {"start": 2466.42, "end": 2466.94, "word": " التربيع", "probability": 0.8721923828125}, {"start": 2466.94, "end": 2467.28, "word": " ايه", "probability": 0.6873372395833334}, {"start": 2467.28, "end": 2468.52, "word": " الار", "probability": 0.7318115234375}, {"start": 2468.52, "end": 2468.92, "word": " سي", "probability": 0.97216796875}, {"start": 2468.92, "end": 2469.62, "word": " تربيع", "probability": 0.957275390625}, {"start": 2469.62, "end": 2471.04, "word": " minus", "probability": 0.96484375}, {"start": 2471.04, "end": 2471.54, "word": " ار", "probability": 0.91455078125}, {"start": 2471.54, "end": 2472.12, "word": " تربيع", "probability": 0.970703125}], "temperature": 1.0}, {"id": 83, "seek": 249911, "start": 2474.67, "end": 2499.11, "text": "هذا هو ال table تلاتة اربعة where RC معطيني ال RC بيستوى تلاتة انش ال RC بيستوى تلاتة انش وال R capital بيستوى واحد انش determine E by using the formula from the table", "tokens": [3224, 15730, 31439, 2423, 3199, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 689, 28987, 20449, 9566, 9957, 1829, 2423, 28987, 4724, 1829, 14851, 2407, 7578, 6055, 1211, 9307, 3660, 16472, 8592, 2423, 28987, 4724, 1829, 14851, 2407, 7578, 6055, 1211, 9307, 3660, 16472, 8592, 16070, 497, 4238, 4724, 1829, 14851, 2407, 7578, 36764, 24401, 16472, 8592, 6997, 462, 538, 1228, 264, 8513, 490, 264, 3199], "avg_logprob": -0.2368607891328407, "compression_ratio": 1.5555555555555556, "no_speech_prob": 0.0, "words": [{"start": 2474.67, "end": 2474.97, "word": "هذا", "probability": 0.59326171875}, {"start": 2474.97, "end": 2475.11, "word": " هو", "probability": 0.76904296875}, {"start": 2475.11, "end": 2475.21, "word": " ال", "probability": 0.74755859375}, {"start": 2475.21, "end": 2475.35, "word": " table", "probability": 0.39599609375}, {"start": 2475.35, "end": 2475.67, "word": " تلاتة", "probability": 0.8665771484375}, {"start": 2475.67, "end": 2476.09, 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expected to be more accurate يعني هاد expected to be more accurate معناته إذا أنا عملت approximation to some expected هتكون هاد هي أكتر دقة أكم تطلع؟", "tokens": [6027, 39184, 544, 8559, 34051, 2423, 39184, 5176, 281, 312, 544, 8559, 37495, 22653, 8032, 18513, 5176, 281, 312, 544, 8559, 20449, 8315, 47395, 11933, 15730, 41850, 6225, 42213, 2655, 28023, 281, 512, 5176, 8032, 2655, 30544, 8032, 18513, 39896, 5551, 4117, 2655, 2288, 11778, 28671, 5551, 24793, 6055, 9566, 1211, 3615, 22807], "avg_logprob": -0.2672164324257109, "compression_ratio": 1.5231788079470199, "no_speech_prob": 0.00010609626770019531, "words": [{"start": 2795.33, "end": 2795.65, "word": "الـ", "probability": 0.3900146484375}, {"start": 2795.65, "end": 2795.85, "word": " more", "probability": 0.72509765625}, {"start": 2795.85, "end": 2796.39, "word": " accurate", "probability": 0.88720703125}, {"start": 2796.39, "end": 2796.63, "word": " أو", "probability": 0.43017578125}, {"start": 2796.63, "end": 2796.77, "word": " 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"end": 2875.88, "word": " كبيرة", "probability": 0.9905598958333334}, {"start": 2875.88, "end": 2878.12, "word": " فمحرز", "probability": 0.9736328125}, {"start": 2878.12, "end": 2878.24, "word": " ان", "probability": 0.81884765625}, {"start": 2878.24, "end": 2878.46, "word": " اعمل", "probability": 0.9274088541666666}, {"start": 2878.46, "end": 2878.88, "word": " approximation", "probability": 0.94091796875}], "temperature": 1.0}, {"id": 97, "seek": 290636, "start": 2884.8, "end": 2906.36, "text": "طيب نكمل طيب هنشوف نوع تاني من ال stresses اللي هي", "tokens": [9566, 1829, 3555, 8717, 24793, 1211, 23032, 1829, 3555, 8032, 1863, 8592, 38688, 8717, 45367, 6055, 7649, 1829, 9154, 2423, 27732, 13672, 1829, 39896], "avg_logprob": -0.12039062976837159, "compression_ratio": 1.0933333333333333, "no_speech_prob": 0.0, "words": [{"start": 2884.8, "end": 2885.16, "word": "طيب", "probability": 0.9806315104166666}, {"start": 2885.16, "end": 2886.46, "word": " نكمل", "probability": 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ال system الخارجى بتاعتها منحانية curved surfaces لما نضعتهم مع بعض بيصير deformation at the surfaces بيصير عندي اجهدات بسميها contact stresses او ال Herzian stresses", "tokens": [6027, 26108, 3224, 3215, 9307, 8717, 31371, 7435, 31371, 16712, 37440, 3794, 13672, 7578, 8032, 7578, 3385, 27732, 1975, 2407, 4724, 1829, 38251, 2407, 11296, 24749, 952, 27732, 3385, 27732, 1975, 2407, 24749, 952, 27732, 1975, 15730, 18871, 16254, 732, 7510, 4032, 2423, 1185, 33962, 9640, 7435, 7578, 39894, 995, 34268, 11296, 9154, 5016, 7649, 10632, 24991, 16130, 5296, 15042, 8717, 11242, 34268, 16095, 20449, 45030, 11242, 4724, 1829, 9381, 13546, 34364, 412, 264, 16130, 4724, 1829, 9381, 13546, 18871, 16254, 1975, 7435, 3224, 3215, 9307, 4724, 38251, 1829, 11296, 3385, 27732, 1975, 2407, 2423, 24749, 952, 27732], "avg_logprob": -0.2285353478157159, "compression_ratio": 1.836283185840708, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 2907.46, "end": 2908.18, "word": "الاجهدات", "probability": 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"temperature": 1.0}, {"id": 117, "seek": 345385, "start": 3427.77, "end": 3453.85, "text": "أو حتى بلوذا surface هكون دي هذا sigma z هاي هناك sigma x يعني ماتتركزوش على اتجاهات حالياً هاي sigma y واضح انه الإجهادات هذه", "tokens": [10721, 2407, 11331, 49975, 4724, 1211, 2407, 15730, 3753, 8032, 30544, 11778, 1829, 23758, 12771, 710, 8032, 47302, 8032, 8315, 4117, 12771, 2031, 37495, 22653, 3714, 9307, 2655, 31747, 11622, 2407, 8592, 15844, 1975, 2655, 7435, 40294, 9307, 11331, 6027, 25528, 14111, 8032, 47302, 12771, 288, 4032, 46958, 5016, 16472, 3224, 33688, 7435, 3224, 18513, 9307, 29538], "avg_logprob": -0.35344827483440266, "compression_ratio": 1.4, "no_speech_prob": 0.0, "words": [{"start": 3427.77, "end": 3428.03, "word": "أو", "probability": 0.772216796875}, {"start": 3428.03, "end": 3428.29, "word": " حتى", "probability": 0.8896484375}, {"start": 3428.29, "end": 3428.71, "word": " بلوذا", "probability": 0.5166015625}, {"start": 3428.71, "end": 3429.27, "word": " surface", 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ومنها بحسب tau max لأن اذا انا برتقله سجن واحد اكبر من سجن اتنين اكبر من سجن تلاتة بحسب tau max بستوى سجن واحد minus سجن تلاتة على اتنين", "tokens": [3224, 24192, 2423, 4244, 2423, 9716, 4244, 32239, 8592, 22807, 5296, 33456, 19446, 41185, 8592, 13412, 13546, 2423, 9716, 4244, 9673, 4587, 1863, 27884, 3714, 43020, 5551, 38251, 1829, 11296, 8608, 7435, 1863, 36764, 24401, 8608, 7435, 1863, 1975, 2655, 1863, 9957, 1975, 2407, 8608, 7435, 1863, 6055, 1211, 9307, 3660, 4032, 27842, 11296, 4724, 5016, 35457, 17842, 11469, 5296, 33456, 1975, 15730, 1975, 8315, 4724, 43500, 4587, 1211, 3224, 8608, 7435, 1863, 36764, 24401, 1975, 4117, 26890, 9154, 8608, 7435, 1863, 1975, 2655, 1863, 9957, 1975, 4117, 26890, 9154, 8608, 7435, 1863, 6055, 1211, 9307, 3660, 4724, 5016, 35457, 17842, 11469, 4724, 14851, 2407, 7578, 8608, 7435, 1863, 36764, 24401, 3175, 8608, 7435, 1863, 6055, 1211, 9307, 3660, 15844, 1975, 2655, 1863, 9957], "avg_logprob": -0.28850000572204587, "compression_ratio": 2.111111111111111, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 3455.8, "end": 3456.16, "word": "هذه", "probability": 0.794921875}, {"start": 3456.16, "end": 3456.3, "word": " ال", "probability": 0.85302734375}, {"start": 3456.3, "end": 3456.5, "word": " stress", "probability": 0.2208251953125}, {"start": 3456.5, "end": 3456.84, "word": " ال", "probability": 0.27001953125}, {"start": 3456.84, "end": 3457.24, "word": " principal", "probability": 0.35009765625}, {"start": 3457.24, "end": 3457.68, "word": " stress", "probability": 0.76611328125}, {"start": 3457.68, "end": 3459.2, "word": " ليش؟", "probability": 0.661865234375}, {"start": 3459.2, "end": 3459.4, "word": " لأن", "probability": 0.833984375}, {"start": 3459.4, "end": 3459.62, "word": " مافيش", "probability": 0.8219401041666666}, {"start": 3459.62, "end": 3459.94, "word": " شير", "probability": 0.5809326171875}, {"start": 3459.94, "end": 3462.06, "word": " ال", "probability": 0.272216796875}, {"start": 3462.06, "end": 3462.36, "word": " principal", "probability": 0.62060546875}, {"start": 3462.36, "end": 3462.66, "word": " stress", "probability": 0.61669921875}, {"start": 3462.66, "end": 3462.9, "word": " المقنعة", "probability": 0.4996337890625}, {"start": 3462.9, "end": 3463.14, "word": " ممكن", "probability": 0.90673828125}, {"start": 3463.14, "end": 3463.72, "word": " أسميها", "probability": 0.82232666015625}, {"start": 3463.72, "end": 3463.94, "word": " سجن", "probability": 0.5113118489583334}, {"start": 3463.94, "end": 3464.24, "word": " واحد", "probability": 0.8232421875}, {"start": 3464.24, "end": 3464.56, "word": " سجن", "probability": 0.7473958333333334}, {"start": 3464.56, "end": 3465.02, "word": " اتنين", "probability": 0.9404296875}, {"start": 3465.02, "end": 3465.32, "word": " او", "probability": 0.764892578125}, {"start": 3465.32, "end": 3465.8, "word": " سجن", "probability": 0.95849609375}, {"start": 3465.8, "end": 3467.12, "word": " تلاتة", "probability": 0.87548828125}, {"start": 3467.12, "end": 3470.48, "word": " ومنها", "probability": 0.79248046875}, {"start": 3470.48, "end": 3470.94, "word": " بحسب", "probability": 0.9728190104166666}, {"start": 3470.94, "end": 3471.4, "word": " tau", "probability": 0.392578125}, {"start": 3471.4, "end": 3471.72, "word": " max", "probability": 0.91259765625}, {"start": 3471.72, "end": 3472.02, "word": " لأن", "probability": 0.58935546875}, {"start": 3472.02, "end": 3472.24, "word": " اذا", "probability": 0.715576171875}, {"start": 3472.24, "end": 3472.4, "word": " انا", "probability": 0.7056884765625}, {"start": 3472.4, "end": 3472.84, "word": " برتقله", "probability": 0.655078125}, {"start": 3472.84, "end": 3473.16, "word": " سجن", "probability": 0.8893229166666666}, {"start": 3473.16, "end": 3473.62, "word": " واحد", "probability": 0.972900390625}, {"start": 3473.62, "end": 3474.66, "word": " اكبر", "probability": 0.8776041666666666}, {"start": 3474.66, "end": 3474.8, "word": " من", "probability": 0.9873046875}, {"start": 3474.8, "end": 3475.08, "word": " سجن", "probability": 0.97802734375}, {"start": 3475.08, "end": 3475.64, "word": " اتنين", "probability": 0.98681640625}, {"start": 3475.64, "end": 3476.3, "word": " اكبر", "probability": 0.9591471354166666}, {"start": 3476.3, "end": 3476.38, "word": " من", "probability": 0.9873046875}, {"start": 3476.38, "end": 3476.64, "word": " سجن", "probability": 0.9884440104166666}, {"start": 3476.64, "end": 3477.38, "word": " تلاتة", "probability": 0.9300537109375}, {"start": 3477.38, "end": 3478.0, "word": " بحسب", "probability": 0.95556640625}, {"start": 3478.0, "end": 3478.3, "word": " tau", "probability": 0.6796875}, {"start": 3478.3, "end": 3478.72, "word": " max", "probability": 0.958984375}, {"start": 3478.72, "end": 3480.52, "word": " بستوى", "probability": 0.64337158203125}, {"start": 3480.52, "end": 3480.84, "word": " سجن", "probability": 0.7899576822916666}, {"start": 3480.84, "end": 3481.36, "word": " واحد", "probability": 0.973388671875}, {"start": 3481.36, "end": 3481.66, "word": " minus", "probability": 0.444580078125}, {"start": 3481.66, "end": 3482.04, "word": " سجن", "probability": 0.7767740885416666}, {"start": 3482.04, "end": 3482.52, "word": " تلاتة", "probability": 0.901611328125}, {"start": 3482.52, "end": 3482.7, "word": " على", "probability": 0.74365234375}, {"start": 3482.7, "end": 3484.26, "word": " اتنين", "probability": 0.97412109375}], "temperature": 1.0}, {"id": 119, "seek": 351580, "start": 3488.52, "end": 3515.8, "text": "لو أخدنا مثلا الحديد ال poison rage بتاعة الحديد تلاتة من عشرة تطلع ال tau max بسبب point تلاتة P max at a depth of point four eight A على عمق تقريبا point خمسة L A اتطلع انا اللي بيصير عندى هاي عندى ال Z", "tokens": [1211, 2407, 5551, 9778, 3215, 8315, 50113, 15040, 21542, 16254, 3215, 2423, 10836, 20133, 39894, 995, 27884, 21542, 16254, 3215, 6055, 1211, 9307, 3660, 9154, 6225, 8592, 25720, 6055, 9566, 1211, 3615, 2423, 17842, 11469, 4724, 35457, 3555, 935, 6055, 1211, 9307, 3660, 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3491.0, "end": 3491.16, "word": " بتاعة", "probability": 0.7498372395833334}, {"start": 3491.16, "end": 3491.58, "word": " الحديد", "probability": 0.9715169270833334}, {"start": 3491.58, "end": 3492.0, "word": " تلاتة", "probability": 0.7337646484375}, {"start": 3492.0, "end": 3492.1, "word": " من", "probability": 0.947265625}, {"start": 3492.1, "end": 3492.5, "word": " عشرة", "probability": 0.8211263020833334}, {"start": 3492.5, "end": 3494.5, "word": " تطلع", "probability": 0.8668212890625}, {"start": 3494.5, "end": 3494.68, "word": " ال", "probability": 0.7373046875}, {"start": 3494.68, "end": 3494.84, "word": " tau", "probability": 0.443603515625}, {"start": 3494.84, "end": 3495.24, "word": " max", "probability": 0.91943359375}, {"start": 3495.24, "end": 3495.7, "word": " بسبب", "probability": 0.8085123697916666}, {"start": 3495.7, "end": 3496.0, "word": " point", "probability": 0.81201171875}, {"start": 3496.0, "end": 3496.64, "word": " تلاتة", "probability": 0.93115234375}, 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"word": " تقريبا", "probability": 0.98876953125}, {"start": 3504.54, "end": 3505.32, "word": " point", "probability": 0.857421875}, {"start": 3505.32, "end": 3506.12, "word": " خمسة", "probability": 0.98046875}, {"start": 3506.12, "end": 3506.36, "word": " L", "probability": 0.3671875}, {"start": 3506.36, "end": 3507.28, "word": " A", "probability": 0.78955078125}, {"start": 3507.28, "end": 3510.34, "word": " اتطلع", "probability": 0.801318359375}, {"start": 3510.34, "end": 3510.48, "word": " انا", "probability": 0.6617431640625}, {"start": 3510.48, "end": 3510.76, "word": " اللي", "probability": 0.857177734375}, {"start": 3510.76, "end": 3511.06, "word": " بيصير", "probability": 0.75390625}, {"start": 3511.06, "end": 3511.44, "word": " عندى", "probability": 0.621826171875}, {"start": 3511.44, "end": 3514.68, "word": " هاي", "probability": 0.48583984375}, {"start": 3514.68, "end": 3515.1, "word": " عندى", "probability": 0.880859375}, {"start": 3515.1, "end": 3515.56, "word": " ال", "probability": 0.74560546875}, {"start": 3515.56, "end": 3515.8, "word": " Z", "probability": 0.56298828125}], "temperature": 1.0}, {"id": 120, "seek": 354169, "start": 3517.09, "end": 3541.69, "text": "الـ Z يعني المسافة تحت السطح على السطح مباشرة Zero كل منزل لجوه الـ Z مالقاش بتزيد وهين ال stress هين طبعا ال Sigma Z هذا ال Sigma Z زي ما احكي هنا Sigma Z بيكون maximum عند ال Z Zero ال Z goes to infinity بروح بتجاه سفر Sigma Z", "tokens": [6027, 39184, 1176, 37495, 22653, 9673, 3794, 31845, 3660, 6055, 33753, 21136, 9566, 5016, 15844, 21136, 9566, 5016, 3714, 3555, 33599, 25720, 17182, 28242, 9154, 11622, 1211, 5296, 7435, 2407, 3224, 2423, 39184, 1176, 3714, 6027, 4587, 33599, 39894, 11622, 25708, 37037, 9957, 2423, 4244, 8032, 9957, 23032, 3555, 3615, 995, 2423, 36595, 1176, 23758, 2423, 36595, 1176, 30767, 1829, 19446, 1975, 5016, 4117, 1829, 34105, 36595, 1176, 4724, 1829, 30544, 6674, 43242, 2423, 1176, 17182, 2423, 1176, 1709, 281, 13202, 4724, 32887, 5016, 39894, 7435, 40294, 8608, 5172, 2288, 36595, 1176], "avg_logprob": -0.27016127750437746, "compression_ratio": 1.602803738317757, "no_speech_prob": 9.447336196899414e-05, "words": [{"start": 3517.09, "end": 3517.47, "word": "الـ", "probability": 0.6220703125}, {"start": 3517.47, "end": 3517.65, "word": " Z", "probability": 0.41796875}, {"start": 3517.65, "end": 3518.87, "word": " يعني", "probability": 0.855224609375}, {"start": 3518.87, "end": 3519.75, "word": " المسافة", "probability": 0.9844970703125}, {"start": 3519.75, "end": 3520.55, "word": " تحت", "probability": 0.9873046875}, {"start": 3520.55, "end": 3521.05, "word": " السطح", "probability": 0.9303385416666666}, {"start": 3521.05, "end": 3521.69, "word": " على", "probability": 0.65771484375}, {"start": 3521.69, "end": 3521.95, "word": " السطح", "probability": 0.9871419270833334}, {"start": 3521.95, "end": 3522.49, "word": " مباشرة", "probability": 0.97998046875}, {"start": 3522.49, "end": 3523.83, "word": " Zero", "probability": 0.454833984375}, {"start": 3523.83, "end": 3524.13, "word": " كل", "probability": 0.83740234375}, {"start": 3524.13, "end": 3524.43, "word": " منزل", "probability": 0.80322265625}, {"start": 3524.43, "end": 3524.81, "word": " لجوه", "probability": 0.7061767578125}, {"start": 3524.81, "end": 3525.03, "word": " الـ", "probability": 0.737548828125}, {"start": 3525.03, "end": 3525.15, "word": " Z", "probability": 0.86328125}, {"start": 3525.15, "end": 3525.71, "word": " مالقاش", "probability": 0.7698974609375}, {"start": 3525.71, "end": 3527.05, "word": " بتزيد", "probability": 0.8380533854166666}, {"start": 3527.05, "end": 3528.01, "word": " وهين", "probability": 0.5428466796875}, {"start": 3528.01, "end": 3528.35, "word": " ال", "probability": 0.94482421875}, {"start": 3528.35, "end": 3528.73, "word": " stress", "probability": 0.89208984375}, {"start": 3528.73, "end": 3528.99, "word": " هين", "probability": 0.6123046875}, {"start": 3528.99, "end": 3529.23, "word": " طبعا", "probability": 0.947509765625}, {"start": 3529.23, "end": 3529.37, "word": " ال", "probability": 0.912109375}, {"start": 3529.37, "end": 3529.63, "word": " Sigma", "probability": 0.4599609375}, {"start": 3529.63, "end": 3529.95, "word": " Z", "probability": 0.82568359375}, {"start": 3529.95, "end": 3530.37, "word": " هذا", "probability": 0.65966796875}, {"start": 3530.37, "end": 3530.53, "word": " ال", "probability": 0.333251953125}, {"start": 3530.53, "end": 3530.73, "word": " Sigma", "probability": 0.93310546875}, {"start": 3530.73, "end": 3531.07, "word": " Z", "probability": 0.98486328125}, {"start": 3531.07, "end": 3531.67, "word": " زي", "probability": 0.547119140625}, {"start": 3531.67, "end": 3531.77, "word": " ما", "probability": 0.94384765625}, {"start": 3531.77, "end": 3531.95, "word": " احكي", "probability": 0.68963623046875}, {"start": 3531.95, "end": 3532.05, "word": " هنا", "probability": 0.85009765625}, {"start": 3532.05, "end": 3532.25, "word": " Sigma", "probability": 0.8330078125}, {"start": 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/FFFtpNPdpGc_raw.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/FFFtpNPdpGc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b83955324c34b87a6a94abbe5cd4bb333f077085
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/FFFtpNPdpGc_raw.srt
@@ -0,0 +1,2160 @@
+1
+00:00:05,530 --> 00:00:08,070
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,070 --> 00:00:11,910
+وبركاته اليوم هنكمل في chapter تلاتة stress and
+
+3
+00:00:11,910 --> 00:00:17,510
+load analysis اليوم الموضوع هيكون curved beams in
+
+4
+00:00:17,510 --> 00:00:20,730
+bending سابقا درسنا ال bending في ال straight
+
+5
+00:00:20,730 --> 00:00:26,410
+beams حكينا ال sigma بساوة M في C basically sigma
+
+6
+00:00:26,410 --> 00:00:30,150
+بساوة
+
+7
+00:00:30,150 --> 00:00:39,760
+M في C على Iو ال stress بتغير linearly يعني لو
+
+8
+00:00:39,760 --> 00:00:47,400
+كانت مقطع مستطيل في عليه bending ال
+
+9
+00:00:47,400 --> 00:00:53,660
+stress
+
+10
+00:00:53,660 --> 00:00:59,510
+بتغير مع الوعيLinear اللي بيكون maximum عند ال
+
+11
+00:00:59,510 --> 00:01:04,530
+outer fiber و minimum عند ال inner أو بيكون عند ال
+
+12
+00:01:04,530 --> 00:01:07,390
+.. بيكون zero عند ال neutral axis و maximum عند ال
+
+13
+00:01:07,390 --> 00:01:09,810
+outer fiber و maximum سواء كان tension او
+
+14
+00:01:09,810 --> 00:01:14,670
+compression هذا في حالة ال straight beams في حالة
+
+15
+00:01:14,670 --> 00:01:18,490
+ال curved beamsلحظ برضه في حالة ال straight beams
+
+16
+00:01:18,490 --> 00:01:21,290
+ال neutral axis ينطبق على ال centroid ال axis
+
+17
+00:01:21,290 --> 00:01:25,450
+للمقطع لكن في حالة ال curved .. ال thick curved
+
+18
+00:01:25,450 --> 00:01:29,070
+beams ال neutral axis و ال centroid ال axis لا
+
+19
+00:01:29,070 --> 00:01:31,490
+ينطبقوا على بعض من بعض يعني في عندي ال neutral
+
+20
+00:01:31,490 --> 00:01:35,310
+axis و في عندي ال centroid ال axis غير منطبقين على
+
+21
+00:01:35,310 --> 00:01:35,630
+بعض
+
+22
+00:01:38,500 --> 00:01:41,440
+تاني اشي bending stress does not vary nearly with
+
+23
+00:01:41,440 --> 00:01:45,120
+distance from neutral axis ال bending stress
+
+24
+00:01:45,120 --> 00:01:49,540
+مابتتغير بشكل خطي مع المسافة او مع البعد عن ال
+
+25
+00:01:49,540 --> 00:01:55,580
+neutral axis هنشوف لان في عندي .. في curved beam
+
+26
+00:01:55,580 --> 00:02:04,740
+ممكن في عندي beam زي هيك عندي
+
+27
+00:02:04,740 --> 00:02:05,080
+support
+
+28
+00:02:10,070 --> 00:02:17,130
+و في عليه some loading يعني بندنج لأن انا بناخد
+
+29
+00:02:17,130 --> 00:02:22,110
+جزء من ال beam هذا ال radius هو ال radius الداخل
+
+30
+00:02:22,110 --> 00:02:28,250
+لل beam نص قطر التكور الداخلي ر اي هذا نص القطر
+
+31
+00:02:28,250 --> 00:02:32,390
+التكور الخارجي
+
+32
+00:02:32,390 --> 00:02:34,590
+ر او
+
+33
+00:02:45,370 --> 00:02:50,690
+هذا الـ neutral axis هذا
+
+34
+00:02:50,690 --> 00:02:55,310
+الـ
+
+35
+00:02:55,310 --> 00:03:01,430
+neutral axis و فيه bending moment M
+
+36
+00:03:23,730 --> 00:03:28,610
+طبعا لو أخدت مقطع هنا ممكن نحكي هذا ال general
+
+37
+00:03:28,610 --> 00:03:37,970
+shape مثلا للمقطع ارتفاع المقطع H
+
+38
+00:03:37,970 --> 00:03:43,030
+فانا
+
+39
+00:03:43,030 --> 00:03:45,570
+حاكي ان هذا هو ال neutral axis وهذا ال centroidal
+
+40
+00:03:45,570 --> 00:03:45,930
+axis
+
+41
+00:03:55,610 --> 00:04:01,810
+هذا ال central axis هذا
+
+42
+00:04:01,810 --> 00:04:09,750
+هو ال neutral axis ال
+
+43
+00:04:09,750 --> 00:04:15,290
+neutral axis في طبعا offset distance بين ال
+
+44
+00:04:15,290 --> 00:04:19,370
+central axis و ال neutral axis هسميها E هذا
+
+45
+00:04:19,370 --> 00:04:20,430
+المسافة E
+
+46
+00:04:27,370 --> 00:04:40,890
+و احنا حكينا هذه المسافة هسميها RN هذه RN مصقطر
+
+47
+00:04:40,890 --> 00:04:51,030
+تكوّر and neutral axis اللي هي هذه RN
+
+48
+00:04:51,030 --> 00:04:54,470
+وهذه RC
+
+49
+00:05:15,070 --> 00:05:25,250
+إذا خدنا أي element على بعد R من
+
+50
+00:05:25,250 --> 00:05:31,950
+مركز التكوّر هذه
+
+51
+00:05:31,950 --> 00:05:39,550
+المسافة R هسميها ايش هتكون هذه Y يعني
+
+52
+00:05:39,550 --> 00:05:44,270
+ال R زاد ال Y بيستوي ايش؟ RN ال R زاد ال Y
+
+53
+00:05:47,990 --> 00:05:55,210
+بستو R N ال
+
+54
+00:05:55,210 --> 00:06:01,630
+Y تكسب positive في هذا الاتجاه R Y هذا هو ال
+
+55
+00:06:01,630 --> 00:06:09,590
+element تحت
+
+56
+00:06:09,590 --> 00:06:10,190
+الدراسة
+
+57
+00:06:23,900 --> 00:06:28,660
+المسافة من الـ neutral axis لل inner fibre سميها
+
+58
+00:06:28,660 --> 00:06:34,800
+CI والمسافة
+
+59
+00:06:34,800 --> 00:06:38,260
+من ال neutral axis لل outer fibre ساميها CO
+
+60
+00:06:51,970 --> 00:06:59,210
+نتيجة ال bending يعني لو كان المقطع هذا بي سي هذا
+
+61
+00:06:59,210 --> 00:07:05,390
+بي سي before bending due to bending هصير some
+
+62
+00:07:05,390 --> 00:07:14,290
+rotation هتضل عند ال بي براين هذا الخط after
+
+63
+00:07:14,290 --> 00:07:15,650
+bending هضله straight
+
+64
+00:07:19,000 --> 00:07:31,560
+هذه بي براين وهذه سي براين هذه
+
+65
+00:07:31,560 --> 00:07:43,040
+الزاوية يعني
+
+66
+00:07:43,040 --> 00:07:47,940
+اتأني انا ايجي الفاية لو اخد section بي سيafter
+
+67
+00:07:47,940 --> 00:07:51,740
+bending بيصيرش فيه curvature بيبقى عدل يعني مستوى
+
+68
+00:07:51,740 --> 00:07:57,920
+هذا بي لف صحيح بس بيبقى عدل بيصيرش فيه curvature
+
+69
+00:07:57,920 --> 00:08:03,040
+بيبقى بي برايم سي برايم هذه
+
+70
+00:08:03,040 --> 00:08:08,380
+هي التسميات الرئيسية الآن المعادلات مش هطلب
+
+71
+00:08:08,380 --> 00:08:15,900
+اشتقاقها اني عندي RN بالساوية
+
+72
+00:08:18,460 --> 00:08:27,700
+A على تكامل DA على R و ال stress distribution
+
+73
+00:08:27,700 --> 00:08:31,880
+sigma بساوي
+
+74
+00:08:31,880 --> 00:08:36,080
+اللي هو MY على
+
+75
+00:08:36,080 --> 00:08:41,920
+A في E RN minus Y
+
+76
+00:08:51,270 --> 00:08:57,030
+يعني عندي حكينا ال Rn اللي هو هذا هذا ال Rn او هو
+
+77
+00:08:57,030 --> 00:09:02,590
+هذا مُعطل علاقة المساحة بتاعة ال cross section على
+
+78
+00:09:02,590 --> 00:09:07,650
+تكامل ال D A على R و ال stress distribution sigma
+
+79
+00:09:07,650 --> 00:09:14,150
+سواء M في Y على A E في R N نقص Y وهي اتجاه ال Y
+
+80
+00:09:20,870 --> 00:09:30,650
+الان لو بدأ اوى دى stress عند ال inner fiber عند
+
+81
+00:09:30,650 --> 00:09:38,690
+ال inner fiber ال Y اشو ساوى at ال inner fiber at
+
+82
+00:09:38,690 --> 00:09:54,440
+ال inner fiber بتكون عندى ال Y بالساويةسي اي صح؟
+
+83
+00:09:54,440 --> 00:10:07,420
+معناته سيجما يعني سيجما اي بيستو ام في سي اي على ا
+
+84
+00:10:07,420 --> 00:10:14,300
+في اي في ر ان ماينس سي اي
+
+85
+00:10:20,420 --> 00:10:28,540
+الان RN هاي RN مينس CI هيبقى عناش RI صح؟ يعني
+
+86
+00:10:28,540 --> 00:10:33,020
+هتساوي MCI
+
+87
+00:10:33,020 --> 00:10:37,460
+على AERI
+
+88
+00:10:37,460 --> 00:10:48,980
+اللي هي هذه المعادلةطول ال E صحيح لجسمها صحيح ال E
+
+89
+00:10:48,980 --> 00:10:52,320
+تختلف
+
+90
+00:10:52,320 --> 00:10:58,240
+باختلاف المقطع تختلف اختلاف المقطع و ال curvature
+
+91
+00:10:58,240 --> 00:11:02,720
+بتاع المقطع يعني لو كان straight beam ال E هتكون
+
+92
+00:11:02,720 --> 00:11:08,060
+سوى سفر اذا كان curved beam مش هتكون سفر طب يدي
+
+93
+00:11:08,060 --> 00:11:13,610
+ايش كل .. باختلاف ال curvature بتختلفالـ Sigma O
+
+94
+00:11:13,610 --> 00:11:22,510
+أدت اللي هو Outer Fiber أكون
+
+95
+00:11:22,510 --> 00:11:30,950
+عند ال Y بالسواء minus CO يعني أصلا ال Sigma Outer
+
+96
+00:11:30,950 --> 00:11:37,470
+بالساوية minus MCO
+
+97
+00:11:39,130 --> 00:11:50,070
+على ال A E في R N minus minus تصير زائد C O هتكون
+
+98
+00:11:50,070 --> 00:11:57,710
+سوى minus M C O هاي ال R N ال R N زائد C O عبارة
+
+99
+00:11:57,710 --> 00:12:07,530
+عن إيه R O على A E R O اللي هي المعادلة
+
+100
+00:12:10,450 --> 00:12:14,270
+الثاني طيب خلّيني أحاول مثال
+
+101
+00:12:31,730 --> 00:12:34,490
+Plot the distribution of stresses across section
+
+102
+00:12:34,490 --> 00:12:39,610
+AA of the crane hook shown فاندي crane hook هذه
+
+103
+00:12:39,610 --> 00:12:48,930
+عليها load F و بده عند المقطع AA هين ال stress
+
+104
+00:12:48,930 --> 00:12:59,150
+distribution المقطع
+
+105
+00:12:59,150 --> 00:13:07,510
+طبعا هين زي مستطيلو هذه المركز مركز التكوّر هذا ال
+
+106
+00:13:07,510 --> 00:13:10,930
+.. طبعا هذا عندى اتنين انش و هذا ستة انش معناته
+
+107
+00:13:10,930 --> 00:13:16,370
+هذا اكام؟ اربعة هذا اتنين هذا ستة معناته هذا ايش؟
+
+108
+00:13:16,370 --> 00:13:19,430
+اربعة معناه ال section اللى هو طلعت عليه من ال top
+
+109
+00:13:19,430 --> 00:13:25,910
+view هيبين عندى هى المركز و هذا هيكون ر اي
+
+110
+00:13:30,980 --> 00:13:40,240
+صح؟ وهذا رح يكون R
+
+111
+00:13:40,240 --> 00:13:46,840
+O وهذا H صح؟
+
+112
+00:13:46,840 --> 00:13:52,840
+وهذا
+
+113
+00:13:52,840 --> 00:13:53,460
+R C
+
+114
+00:14:02,480 --> 00:14:12,880
+طبعا هكون انا بدي احسب هكون هذه المسافة R and و
+
+115
+00:14:12,880 --> 00:14:19,020
+ال offset distance بين ال Rc و ال Rn اللي هي ايه
+
+116
+00:14:19,020 --> 00:14:25,480
+خنكتب اندي ر ايه شو ساوي اتنين
+
+117
+00:14:25,480 --> 00:14:32,930
+انش صح و ال ر او هاي هالتنين انش ر ايهو ال R O ستة
+
+118
+00:14:32,930 --> 00:14:38,750
+انش و
+
+119
+00:14:38,750 --> 00:14:41,870
+ال
+
+120
+00:14:41,870 --> 00:14:47,010
+H شو يساوي اللى
+
+121
+00:14:47,010 --> 00:14:54,150
+هى R O مينوس R I سوى أربعة انش و السماكة بيعطينيها
+
+122
+00:14:54,150 --> 00:14:57,930
+point سبعة خمسة انش مانا بتقول ايه اكم تساوي
+
+123
+00:15:01,210 --> 00:15:11,050
+اللي هي هتكون أربع في بون سبعة خمسة صح تلت انش
+
+124
+00:15:11,050 --> 00:15:19,430
+تربيع ال
+
+125
+00:15:19,430 --> 00:15:22,450
+RN
+
+126
+00:15:22,450 --> 00:15:26,050
+سواء
+
+127
+00:15:26,050 --> 00:15:38,190
+A على تكاملDA على R يعني لو أخدت element هاي
+
+128
+00:15:38,190 --> 00:15:46,610
+element على
+
+129
+00:15:46,610 --> 00:15:54,230
+بعد مسافة R احنا
+
+130
+00:15:54,230 --> 00:15:58,610
+حكينا ال Y is defined from the neutral axis
+
+131
+00:16:03,170 --> 00:16:10,210
+يعني ال Y تكون موجوبة في اتجاه مركز التكوّر ال دي
+
+132
+00:16:10,210 --> 00:16:17,110
+ايه بتاعتها دي؟ دي ايه ايش ساوي؟ حاجة ممكن اسميها
+
+133
+00:16:17,110 --> 00:16:23,990
+DR او
+
+134
+00:16:23,990 --> 00:16:25,690
+ممكن اسميها بيه
+
+135
+00:16:32,380 --> 00:16:39,940
+هتكون ال D A بسوة B D R يعني هدى ال A اللى هى
+
+136
+00:16:39,940 --> 00:16:50,920
+التلاتة على تكامل ال B D R على R من R I ل R O يعني
+
+137
+00:16:50,920 --> 00:16:59,080
+هتكون تلاتة على bond سبعة ال B هطلع ع برا ع bond
+
+138
+00:16:59,080 --> 00:17:04,240
+سبعة خمسةلن الار من ر اي لار او يعني اللي هتكون لن
+
+139
+00:17:04,240 --> 00:17:09,000
+الار او على ر اي لن
+
+140
+00:17:09,000 --> 00:17:18,240
+الار او على ر اي يعني هتساوي أربعة
+
+141
+00:17:18,240 --> 00:17:30,120
+على لن الار او اللي هي ستة على اتنين حسبوليها
+
+142
+00:17:31,070 --> 00:17:50,230
+اربع على لن التلاتة تحسبوا كل الرقم ماطين
+
+143
+00:17:50,230 --> 00:17:57,050
+ال force ال F عبارة عن خمس تلاف نيوتن ال F
+
+144
+00:17:59,810 --> 00:18:06,370
+3.64 كم هو الرقم؟ تلاتة و واحد ستة أربع واحد انش
+
+145
+00:18:06,370 --> 00:18:09,390
+معطني
+
+146
+00:18:09,390 --> 00:18:18,170
+ال force F خمس تلاف pound لو
+
+147
+00:18:18,170 --> 00:18:23,290
+عملت section هنا و
+
+148
+00:18:23,290 --> 00:18:25,370
+أخدت ال free bell diagram هذا الجزء بس
+
+149
+00:18:28,100 --> 00:18:33,160
+this is my free body diagram فى
+
+150
+00:18:33,160 --> 00:18:47,680
+عندى force F وستكون عندى F معاكسة لها هدو
+
+151
+00:18:47,680 --> 00:18:51,840
+تعمل counter clockwise moment
+
+152
+00:19:00,660 --> 00:19:07,700
+M ال M هتكون تساوي F
+
+153
+00:19:07,700 --> 00:19:14,260
+RC يعني
+
+154
+00:19:14,260 --> 00:19:25,740
+ال F عندي خمس تلاف ال RC اللي هي هتكون أربع
+
+155
+00:19:25,740 --> 00:19:26,100
+إنش
+
+156
+00:19:30,820 --> 00:19:40,040
+عشرين الف pound معناته ال service هذا معرض ل
+
+157
+00:19:40,040 --> 00:19:47,080
+bending و normal stress bending و normal stress
+
+158
+00:19:47,080 --> 00:19:53,520
+يعني لو حكيت عن ال sigmaهتكون sigma axial due to
+
+159
+00:19:53,520 --> 00:19:59,220
+sigma axial زائد sigma due bending ال sigma due to
+
+160
+00:19:59,220 --> 00:20:07,000
+axial واضح انها tensile موجبة هتكون F على A زائد
+
+161
+00:20:07,000 --> 00:20:13,180
+ال sigma due to bending ال
+
+162
+00:20:13,180 --> 00:20:18,080
+هي MY على
+
+163
+00:20:18,080 --> 00:20:19,960
+AE
+
+164
+00:20:22,320 --> 00:20:33,240
+في RN-Y احنا ال A ايش يساوي ال
+
+165
+00:20:33,240 --> 00:20:39,820
+A بيساوي RC-RN ال A بيساوي
+
+166
+00:20:39,820 --> 00:20:51,380
+RC-RN 4-3.641 يعني هتكون تساوي point
+
+167
+00:20:53,360 --> 00:21:09,960
+تلاتة خمسة تسعة انش هذا ال A يعني
+
+168
+00:21:09,960 --> 00:21:18,800
+انا هكون عنده ال F على A اللي عشرين ألف
+
+169
+00:21:23,070 --> 00:21:31,650
+الـ A عندي على التلاتة زاد ال M لأ
+
+170
+00:21:31,650 --> 00:21:40,070
+ال F خمس تلاف ال
+
+171
+00:21:40,070 --> 00:21:45,690
+M عشرين ألف في
+
+172
+00:21:45,690 --> 00:21:55,420
+ال Y على ال L هي تلاتةبالـ E يبقون تلاتة خمسة تسعة
+
+173
+00:21:55,420 --> 00:22:05,280
+بالـ RN الـ RN هي تلاتة بقون ستة أربعة واحد ناقص
+
+174
+00:22:05,280 --> 00:22:09,280
+Y أنا
+
+175
+00:22:09,280 --> 00:22:14,960
+حاسسه خمس تلاف على تلاتة أكمل
+
+176
+00:22:14,960 --> 00:22:18,560
+خمس تلاف على تلاتة
+
+177
+00:22:28,540 --> 00:22:33,060
+ألف و ستمية و ستة و ستين وين ستة سبعة طيب زائد
+
+178
+00:22:33,060 --> 00:22:40,520
+عشرين الف عشرين على تلاتة سبع تلاتة ست تلاتة اخصنا
+
+179
+00:22:40,520 --> 00:22:44,580
+عشرين الف على تلاتة على وان تلاتة خمسمية على هذا
+
+180
+00:22:44,580 --> 00:22:51,240
+برضه مرة تمانتاشر
+
+181
+00:22:51,240 --> 00:22:56,100
+الف و خمسمية و سبعين تمانتاشر الف و خمسمية و سبعين
+
+182
+00:22:58,500 --> 00:23:08,480
+y على ثلاثة point ستة أربع واحد ناقص y
+
+183
+00:23:08,480 --> 00:23:11,720
+لما
+
+184
+00:23:11,720 --> 00:23:26,940
+أخدت different ways حكيت هذه ال y هذه
+
+185
+00:23:26,940 --> 00:23:27,320
+ال y
+
+186
+00:23:42,790 --> 00:23:47,190
+ممكن تعملها مرحلتين يعني هو في النهاية إيش هكون
+
+187
+00:23:47,190 --> 00:23:50,730
+عندك ال
+
+188
+00:23:50,730 --> 00:23:54,250
+bending هعمل
+
+189
+00:23:54,250 --> 00:23:57,410
+compression على الجهة هذه لحاله و tension على
+
+190
+00:23:57,410 --> 00:24:03,020
+الجهة هذه يعني هنا هنشبعو هين هنطرح يعني ممكن تحكي
+
+191
+00:24:03,020 --> 00:24:09,780
+التالت هذا يعني
+
+192
+00:24:09,780 --> 00:24:19,300
+بالظبط بالظبط يعني sigma I هتكون واحد ستة ستة سبعة
+
+193
+00:24:19,300 --> 00:24:29,120
+زاد ال Y عندي في الحالة هذه اللي هي هذه المسافة
+
+194
+00:24:30,690 --> 00:24:42,130
+اللي هي بقى عن اتنين او نحكي ال CI ال CI بتساوي
+
+195
+00:24:42,130 --> 00:24:47,430
+ال
+
+196
+00:24:47,430 --> 00:24:55,870
+CI بتساوي اللي هو هذه المسافة صح هذه ال CI
+
+197
+00:25:05,960 --> 00:25:15,480
+المعنى التساوي بيستوى RN-RI هتكون تساوي RN تلاتة
+
+198
+00:25:15,480 --> 00:25:22,120
+point ستة اربع واحد ناقص اتنين يعني هتكون واحد
+
+199
+00:25:22,120 --> 00:25:28,100
+point ستة اربع واحد انش و CO تلاتة point ستة اربع
+
+200
+00:25:28,100 --> 00:25:33,320
+واحد زائد اتنين انش صح؟ يعني هتكون خمسة point ستة
+
+201
+00:25:33,320 --> 00:25:34,760
+اربع واحد انش
+
+202
+00:25:37,670 --> 00:25:41,010
+Sigma هتكون سوى الف تانمية و خمسين الف و تنتاشر
+
+203
+00:25:41,010 --> 00:25:44,710
+الف و خمسمية و سبعين في ال YI اللي هي بالسواء CI
+
+204
+00:25:44,710 --> 00:25:54,310
+في واحد point ستة اربعة واحد على تلاتة
+
+205
+00:25:54,310 --> 00:25:58,750
+point ستة اربعة واحد ناقص يعني هذا هتكون على اتنين
+
+206
+00:25:58,750 --> 00:26:00,470
+صح
+
+207
+00:26:02,780 --> 00:26:11,140
+وانا بحسب سيجما ايه سيجما او هتكون الف ستمية سبعة
+
+208
+00:26:11,140 --> 00:26:17,520
+ستين زائد هتكون الواي بالنجاتف في الحالة التانية
+
+209
+00:26:17,520 --> 00:26:28,580
+هتكون هذه سالب تمانتاشر الف وخمسمية وسبعين في اللي
+
+210
+00:26:28,580 --> 00:26:31,780
+هي C
+
+211
+00:26:33,710 --> 00:26:43,090
+ال سي او لأ في غلط هذه ال سي او هي ال سي او ال
+
+212
+00:26:43,090 --> 00:26:51,770
+سي او هتكون ال
+
+213
+00:26:51,770 --> 00:26:55,850
+سي او ال h minus
+
+214
+00:26:55,850 --> 00:27:06,820
+ci صح مش هذي ال سي اوهذا ال H صح
+
+215
+00:27:06,820 --> 00:27:13,320
+هتكون ال H minus ال CI ال H اللي هي أربعة minus
+
+216
+00:27:13,320 --> 00:27:20,940
+واحد point ستة أربعة واحد هتكون
+
+217
+00:27:20,940 --> 00:27:26,920
+اتنين point تلاتة
+
+218
+00:27:26,920 --> 00:27:29,780
+خمسة تسعة inch
+
+219
+00:27:32,500 --> 00:27:41,700
+يعني هتكون في اتنين point تلاتة خمسة تسعة على
+
+220
+00:27:41,700 --> 00:27:52,200
+تلاتة point ستة اربع واحدزائد اتنين point تلاتة
+
+221
+00:27:52,200 --> 00:27:56,940
+خمسة تسعة يعني هتكون هذه الجمعه هاياش ستة هذه هدول
+
+222
+00:27:56,940 --> 00:28:03,460
+ستة الجمعه هادى ماعرف يطلعيش ستة هيتلع سوء الحصول
+
+223
+00:28:03,460 --> 00:28:08,040
+التنتين هدول هدول اخمستاشر الف و متين و ستة و
+
+224
+00:28:08,040 --> 00:28:12,320
+تلاتين و ستة خمستاشر الف و متين و سبعة و تلاتين و
+
+225
+00:28:12,320 --> 00:28:12,820
+التانية
+
+226
+00:28:28,400 --> 00:28:33,600
+minus 16900 و التانية
+
+227
+00:28:59,390 --> 00:29:04,290
+السالب خمس تلاف ست
+
+228
+00:29:04,290 --> 00:29:16,610
+مية واربع ثلاثين اشارة
+
+229
+00:29:16,610 --> 00:29:19,710
+السالب على البرنامج ان عشان ال moment بعد ال force
+
+230
+00:29:19,710 --> 00:29:26,530
+لأ لأ هي اشارة السالب لان نطلع الموجب لل Y من
+
+231
+00:29:26,530 --> 00:29:31,540
+neutral X بين هاي الموجب ال Yلما روحت على ال CO
+
+232
+00:29:31,540 --> 00:29:36,880
+صارت بال negative ال Y فعوضت عن ال Y هنا ب minus 2
+
+233
+00:29:36,880 --> 00:29:46,080
+.359 و تحت minus minus بيصير موجة لأ لأ انت قمشي
+
+234
+00:29:46,080 --> 00:29:48,320
+على ال psycho convention تجي لحلقة صح يعني هنا
+
+235
+00:29:48,320 --> 00:29:52,400
+minus plus minus تحطيني minus و هنا minus minus
+
+236
+00:29:52,400 --> 00:29:53,600
+تحطيني plus
+
+237
+00:30:00,460 --> 00:30:08,600
+الان ال stress distribution هيكون non
+
+238
+00:30:08,600 --> 00:30:12,920
+linear وهي
+
+239
+00:30:12,920 --> 00:30:18,400
+neutral axis عند
+
+240
+00:30:18,400 --> 00:30:20,760
+ال inner fiber في عنده tension
+
+241
+00:30:30,080 --> 00:30:33,140
+عند ال author file عندي compression تقريبا التلت
+
+242
+00:30:33,140 --> 00:30:36,720
+يعني
+
+243
+00:30:36,720 --> 00:30:49,740
+هيكون high
+
+244
+00:30:49,740 --> 00:30:52,760
+stress distribution على الكران
+
+245
+00:30:55,570 --> 00:31:02,210
+عندي هين tension لو كنتوا ستة أشر ألف تسعمية
+
+246
+00:31:02,210 --> 00:31:06,690
+وتلاتة وعندي هين compression ماكس خمس تلاف ستمية
+
+247
+00:31:06,690 --> 00:31:16,750
+أربعة تلاتين في أسعار هاي
+
+248
+00:31:16,750 --> 00:31:20,230
+ال RN هاي ال RN زيرو ال neutral axis زيرو هاد ال
+
+249
+00:31:20,230 --> 00:31:21,610
+RN هاد
+
+250
+00:31:25,390 --> 00:31:40,730
+ال R N وهذه ال E وهذه ال R C وهذه طبعا ال R I وهذه
+
+251
+00:31:40,730 --> 00:31:48,970
+ال R O بقصد الدكتور ان ال R N كانت من ال bending
+
+252
+00:31:48,970 --> 00:31:53,510
+بس صحيح؟معانا في bending و normal بسبب ال stress
+
+253
+00:31:53,510 --> 00:31:58,750
+القارئان لل bending ايوة القارئان لل bending يعني
+
+254
+00:31:58,750 --> 00:32:03,030
+هم مش هتكون قارئان للموضوع الان هنا هنا هنا في
+
+255
+00:32:03,030 --> 00:32:09,970
+كلامك صحيح الان ايش اللي هسوي الان حط حط حط الان
+
+256
+00:32:09,970 --> 00:32:14,530
+بدك توجد يعني خلنا نحكي احنا وجدنا يعني هذا مش
+
+257
+00:32:14,530 --> 00:32:19,230
+zero صحيح مش zero هتكون واحد التاني هنا هتكون اشي
+
+258
+00:32:19,230 --> 00:32:26,010
+زي هيكهذه هتكون لو أنا ضفت هنا صفر due to bending
+
+259
+00:32:26,010 --> 00:32:32,330
+لما نضيف عليها هل
+
+260
+00:32:32,330 --> 00:32:37,610
+ال neutral ضفت عليها أكمل ألف صار له shift حيث صار
+
+261
+00:32:37,610 --> 00:32:42,870
+موجب اشي
+
+262
+00:32:42,870 --> 00:32:46,330
+زي هيك هل neutral axis بتاع ال bending
+
+263
+00:32:52,740 --> 00:32:57,740
+هن الف ستمية و سبعة ستين ال neutral axis وهن ستة
+
+264
+00:32:57,740 --> 00:33:05,040
+ألف وتسعمائة و تلاتة وهن ناقص خمس آلاف و ستمية و
+
+265
+00:33:05,040 --> 00:33:10,180
+أربعة و تلاتين هذا ال neutral axis بتاع ال bending
+
+266
+00:33:10,180 --> 00:33:13,860
+ال neutral axis صار shift لل total neutral axis
+
+267
+00:33:13,860 --> 00:33:19,260
+هذا سميه ال total neutral
+
+268
+00:33:21,270 --> 00:33:25,650
+طب التوتر اكس بحالة هذه بعتمد شكل كبير على قيمة ال
+
+269
+00:33:25,650 --> 00:33:41,030
+F في
+
+270
+00:33:41,030 --> 00:33:48,310
+سؤال تاني طيب
+
+271
+00:34:17,950 --> 00:34:22,730
+طيب ال table تلاتة أربعة في الكتاب معطيني for
+
+272
+00:34:22,730 --> 00:34:26,530
+different sections of curved beams يعني هذا curved
+
+273
+00:34:26,530 --> 00:34:31,710
+beam و هذا ال section تبعه هذا ال ri هذا ال rn هذا
+
+274
+00:34:31,710 --> 00:34:35,650
+ال rc هذا ال ro هذا ال h في حالة مقطعه مستطيل
+
+275
+00:34:35,650 --> 00:34:40,470
+معطيني ال rc بصورة i زادتش ع اتنين و معطيني ال rn
+
+276
+00:34:40,470 --> 00:34:47,390
+في حالة مقطع ع شكل شبه منحرفمعطينا هاي ال R I هذا
+
+277
+00:34:47,390 --> 00:34:53,750
+ال H وهذا ال R O معطينا معادل ال R C ومعادل ال R N
+
+278
+00:34:53,750 --> 00:35:03,750
+في حالة مقطع حرف I مقلوب عند هاي ال R I هاي ال R O
+
+279
+00:35:03,750 --> 00:35:08,770
+R C R N معطينا برضه معادل ال R C وR N في حالة مقطع
+
+280
+00:35:08,770 --> 00:35:16,730
+دائرة معطينا برضههذه الـRI هذه الـRO هذه الـRC و
+
+281
+00:35:16,730 --> 00:35:27,390
+الـ RN معطيين RC و RN R كبتر نصف قطر الدايرة طبعا
+
+282
+00:35:27,390 --> 00:35:35,110
+معطيين الأشكال المختلفة المعلومات هذه في
+
+283
+00:35:35,110 --> 00:35:36,390
+كل ما يزيد ال curvature
+
+284
+00:35:39,900 --> 00:35:45,680
+يقترب من معنى انها بيصير ايش؟ straight معناته كل
+
+285
+00:35:45,680 --> 00:35:50,480
+ما اقترب من ال straightness كل ما كانت ال E تقترب
+
+286
+00:35:50,480 --> 00:35:56,940
+من ال zero يعني كل ما بنطبق ال neutral axis على ال
+
+287
+00:35:56,940 --> 00:36:04,760
+central axisفكل ما تزرق
+
+288
+00:36:04,760 --> 00:36:09,600
+قيمة ال A في الحالة هذه ال A ممكن في حالة large
+
+289
+00:36:09,600 --> 00:36:13,640
+curvature تكون تقريبا بالثوابة I على RC
+
+290
+00:36:24,750 --> 00:36:28,230
+المسافة من مركز تكوّر لـcentroidal axis والـ A
+
+291
+00:36:28,230 --> 00:36:34,010
+مساحة المقطع الآن
+
+292
+00:36:34,010 --> 00:36:38,890
+إذا بعود هذه المعادلة بمعادلة ال stress اللي هي
+
+293
+00:36:38,890 --> 00:36:42,690
+هذه sigma
+
+294
+00:36:42,690 --> 00:36:46,470
+بسوء
+
+295
+00:36:46,470 --> 00:36:59,250
+M في Y على AA في RNناقص Y بعود
+
+296
+00:36:59,250 --> 00:37:09,490
+عن ال A ال
+
+297
+00:37:09,490 --> 00:37:18,490
+A اللي هي I على RC في A بسرع الشغل تطلع اندياش
+
+298
+00:37:19,580 --> 00:37:24,480
+المعادلة هي تقريبا سيجما وهنا بيعتبر رن ماينوس واي
+
+299
+00:37:24,480 --> 00:37:30,420
+اللي هي هذه ايش ر تطلع
+
+300
+00:37:30,420 --> 00:37:34,500
+عند المعادلة سيجما تقريبا م في واي على اي في ار سي
+
+301
+00:37:34,500 --> 00:37:40,400
+على ار هذا في الحال كان عندي large curvature
+
+302
+00:37:40,400 --> 00:37:41,860
+للبيمة
+
+303
+00:37:55,830 --> 00:38:01,430
+يعني لو انا جبت two beams نفس المقطع و نفس التحميل
+
+304
+00:38:01,430 --> 00:38:12,050
+يعني اذا جبت beam زي هيك عدل المقطع طبعا مستطيل و
+
+305
+00:38:12,050 --> 00:38:21,470
+عليها distributed load اي حالة حالة تانية نفس
+
+306
+00:38:21,470 --> 00:38:22,010
+ال span
+
+307
+00:38:40,580 --> 00:38:50,320
+و نفس الـ distributed load load موظّع متوقع
+
+308
+00:38:50,320 --> 00:38:54,500
+مين يعني أداء يكون أحسن هدا ال beam و لا هدا ال
+
+309
+00:38:54,500 --> 00:39:02,120
+beam يعني
+
+310
+00:39:02,120 --> 00:39:07,720
+لو كان هنا ال distribution ميت ميت النيوتن لكل متر
+
+311
+00:39:09,350 --> 00:39:12,790
+متوقع هذا يشيل نفس ال section متوقع هذا يشيل أكتر
+
+312
+00:39:12,790 --> 00:39:19,950
+ولا أقل من هذا؟ لأ هذا هشيل أقل هشيل أكتر وزم
+
+313
+00:39:19,950 --> 00:39:23,190
+معناه ال stress level هكون أقل من stress level هذا
+
+314
+00:39:23,190 --> 00:39:29,170
+هنا عشان في الجصور بيعملوا curvature بيعملوا
+
+315
+00:39:29,170 --> 00:39:33,090
+curvature طيب
+
+316
+00:39:33,090 --> 00:39:36,410
+نشوف
+
+317
+00:39:36,410 --> 00:39:36,890
+مثال
+
+318
+00:39:45,430 --> 00:39:49,410
+consider the circle section in table تلاتة أربعة
+
+319
+00:39:49,410 --> 00:39:54,970
+نرجع لتابل تلاتة أربعة عندي circle cross section
+
+320
+00:39:54,970 --> 00:39:58,610
+هاي
+
+321
+00:39:58,610 --> 00:40:03,010
+مركز التكوّر هاي
+
+322
+00:40:03,010 --> 00:40:10,250
+مركز الدائر المقطع هاي
+
+323
+00:40:10,250 --> 00:40:14,550
+عندى هذا هو ال RN
+
+324
+00:40:18,120 --> 00:40:29,200
+هذا ال E وهذا ال R C وهذا نص ال readers بتاعتها R
+
+325
+00:40:29,200 --> 00:40:38,940
+رئيسية و ال R C طبعا هذا ر I وهذا
+
+326
+00:40:38,940 --> 00:40:40,940
+ر O
+
+327
+00:40:45,220 --> 00:40:54,380
+الار سي بالساوية الار اي زاد الار كابيتال والار ان
+
+328
+00:40:54,380 --> 00:41:06,420
+بالساوية ار سكوار على اتنين في ار سي minus جزر
+
+329
+00:41:06,420 --> 00:41:12,120
+التربيع ايه الار سي تربيع minus ار تربيع
+
+330
+00:41:14,670 --> 00:41:23,650
+هذا هو ال table تلاتة اربعة where RC معطيني ال RC
+
+331
+00:41:23,650 --> 00:41:30,270
+بيستوى تلاتة انش ال RC بيستوى تلاتة انش وال R
+
+332
+00:41:30,270 --> 00:41:37,930
+capital بيستوى واحد انش determine E by using the
+
+333
+00:41:37,930 --> 00:41:42,690
+formula from the tableبنحسب ال a اللى هى ال a
+
+334
+00:41:42,690 --> 00:41:51,290
+بالحالة هذى مستويهش RC-RN and
+
+335
+00:41:51,290 --> 00:41:55,150
+the approximation by using equation 93 اللى هى
+
+336
+00:41:55,150 --> 00:42:04,370
+المعادلة هذى في الحالة الأولى احنا ال RC يعني من
+
+337
+00:42:04,370 --> 00:42:08,950
+ال RC ممكن نعرف ايه ال RC اللى هو معطينيها 3 انش
+
+338
+00:42:10,290 --> 00:42:17,570
+معناة ال R I ايش هتساوي اللي هو R C minus R ال R C
+
+339
+00:42:17,570 --> 00:42:26,570
+اللي هي تلاتة ناقص واحد اتنين انش ال
+
+340
+00:42:26,570 --> 00:42:39,390
+R N هتساوي واحد تربيع على اتنين ال R C تلاتة
+
+341
+00:42:41,130 --> 00:42:47,350
+minus جزر تربيعه لتلاتة تربيع ناقص واحد تربيع
+
+342
+00:42:47,350 --> 00:42:50,510
+سيبوها
+
+343
+00:42:50,510 --> 00:42:55,870
+ال RN اتنين يا دكتور بابا وين الاتنين؟ الاتنين هنا
+
+344
+00:42:55,870 --> 00:43:00,170
+باشي
+
+345
+00:43:00,170 --> 00:43:04,390
+احسبوا ليها هذه
+
+346
+00:43:04,390 --> 00:43:07,470
+ال RN اكام؟ اكام؟
+
+347
+00:43:23,970 --> 00:43:34,870
+تلاتة ماينس اتنين point تسعة
+
+348
+00:43:34,870 --> 00:43:40,440
+واحد اربعة انشهذا في حالة استخدام المعادلة هذه في
+
+349
+00:43:40,440 --> 00:43:47,520
+حالة المعادلة التانية ال E بالساوية
+
+350
+00:43:47,520 --> 00:43:57,300
+I على RC في A الآن ال I ايش بالساوية باي على اربع
+
+351
+00:43:57,300 --> 00:44:06,700
+ستين دي تربيع يعني هتكون باي على اربع ستينفى اتنين
+
+352
+00:44:06,700 --> 00:44:14,560
+دى اصلا اربعة فى اتنين اصلا اربعة اتنين اصلا اربعة
+
+353
+00:44:14,560 --> 00:44:19,420
+من ستاش يعني باى على اربعة بيطلع حسبوا ليها و ال
+
+354
+00:44:19,420 --> 00:44:32,740
+area باى ار تربيع يعني هتكون ساوى باى حسبوا
+
+355
+00:44:32,740 --> 00:44:47,120
+لي الأولىمعناته ال E تقريبا سبت ال I بوين
+
+356
+00:44:47,120 --> 00:44:54,740
+سبعة تمانية خمسة بوين سبعة تمانية خمسة
+
+357
+00:44:54,740 --> 00:45:01,280
+معناته ال E هتكون سبعة بوين سبعة تمانية خمسة على
+
+358
+00:45:01,280 --> 00:45:03,980
+تلاتة في باي
+
+359
+00:45:08,210 --> 00:45:14,830
+بسيبها تلعب وانت اه انش
+
+360
+00:45:14,830 --> 00:45:20,290
+يعني
+
+361
+00:45:20,290 --> 00:45:25,210
+لو ده حسب ال error اللي
+
+362
+00:45:25,210 --> 00:45:26,930
+حسبه ال error ولا ال percentage difference
+
+363
+00:45:26,930 --> 00:45:33,270
+difference مش error percentage difference
+
+364
+00:45:36,200 --> 00:45:41,920
+هيكون الساوية point o تمانية ستة minus point o
+
+365
+00:45:41,920 --> 00:45:48,620
+تمانية تلاتة على point o تمانية ستة في مية اكم
+
+366
+00:45:48,620 --> 00:45:54,720
+هيطلع
+
+367
+00:45:54,720 --> 00:45:59,320
+نعم
+
+368
+00:46:05,250 --> 00:46:11,450
+إذا عملت approximation معناته هذه .. هذه ال more
+
+369
+00:46:11,450 --> 00:46:15,870
+accurate result هتكون هي ال reference هي المرجع ..
+
+370
+00:46:15,870 --> 00:46:21,430
+المرجع دي يعني بيكون الأكتر دقتاً هذا
+
+371
+00:46:21,430 --> 00:46:27,190
+approximation هذا approximation but this is
+
+372
+00:46:27,190 --> 00:46:31,630
+approximated value I'm approximating this how far
+
+373
+00:46:31,630 --> 00:46:36,770
+انت ال approximation منالـ more accurate أو الـ
+
+374
+00:46:36,770 --> 00:46:39,430
+expected to be more accurate يعني هاد expected to
+
+375
+00:46:39,430 --> 00:46:43,690
+be more accurate معناته إذا أنا عملت approximation
+
+376
+00:46:43,690 --> 00:46:51,990
+to some expected هتكون هاد هي أكتر دقة أكم تطلع؟
+
+377
+00:47:06,190 --> 00:47:15,390
+طيب أكتر الفرق بيطلع؟
+
+378
+00:47:15,390 --> 00:47:23,770
+تلاتة point أربعة تمانية يعني
+
+379
+00:47:23,770 --> 00:47:25,750
+فرق يعني ممكن اعتبره مقبول
+
+380
+00:47:35,400 --> 00:47:42,500
+طبعا في حالة المقطع مش محرز اعمل approximation لان
+
+381
+00:47:42,500 --> 00:47:48,140
+المعادلات بتاعة المقطع اللي اندور سهلة لكن لو اندي
+
+382
+00:47:48,140 --> 00:47:55,440
+مقطع .. مقطع زي هذا المعادلات
+
+383
+00:47:55,440 --> 00:47:58,880
+كبيرة فمحرز ان اعمل approximation
+
+384
+00:48:04,800 --> 00:48:20,440
+طيب نكمل طيب
+
+385
+00:48:20,440 --> 00:48:23,700
+هنشوف
+
+386
+00:48:23,700 --> 00:48:28,660
+نوع تاني من ال stresses اللي هيالاجهدات نتيجتي
+
+387
+00:48:28,660 --> 00:48:31,620
+التلامس اللى هى contact stresses او بيسموها
+
+388
+00:48:31,620 --> 00:48:34,920
+Herzian stresses contact stresses او Herzian
+
+389
+00:48:34,920 --> 00:48:40,520
+stresses اذا عندي two bodies و ال system الخارجى
+
+390
+00:48:40,520 --> 00:48:45,400
+بتاعتها منحانية curved surfaces لما نضعتهم مع بعض
+
+391
+00:48:45,400 --> 00:48:49,140
+بيصير deformation at the surfaces بيصير عندي
+
+392
+00:48:49,140 --> 00:48:52,420
+اجهدات بسميها contact stresses او ال Herzian
+
+393
+00:48:52,420 --> 00:48:52,840
+stresses
+
+394
+00:48:56,160 --> 00:48:59,560
+في حالة مثلا السفير على سفير بدون compression
+
+395
+00:48:59,560 --> 00:49:04,220
+بيكون النقطة التامس اللي بدها إيهاش سفير على سفير
+
+396
+00:49:04,220 --> 00:49:10,400
+نقطة لما under compression النقطة بتتحول لإيهاش ل
+
+397
+00:49:10,400 --> 00:49:16,980
+area إذا كانت سلندر على سلندر line ال compression
+
+398
+00:49:16,980 --> 00:49:21,720
+بيحولها برضه ل area point or line of contact
+
+399
+00:49:21,720 --> 00:49:25,360
+changes to area contact upon loading
+
+400
+00:49:27,570 --> 00:49:30,670
+طبيعة ال stress .. ال stresses ال nature three
+
+401
+00:49:30,670 --> 00:49:36,390
+dimensional ال nature امثل على حالة ال contact
+
+402
+00:49:36,390 --> 00:49:44,390
+stresses اذا عندي عجلة على .. على ريل عجلة عريل
+
+403
+00:49:44,390 --> 00:49:51,310
+طبعا عندي cylindrical surface على stress surface
+
+404
+00:49:51,310 --> 00:49:54,690
+بيصير عندي هنا contact stresses نتيجة ال loading
+
+405
+00:49:54,690 --> 00:50:04,960
+على العجلأو في حالة الـ two gears الـ gear هذا
+
+406
+00:50:04,960 --> 00:50:09,020
+كرت سيريز نتيجة ال loading ال point contact او ال
+
+407
+00:50:09,020 --> 00:50:15,960
+line contact بتحول ل area contact او في حالة ال
+
+408
+00:50:15,960 --> 00:50:22,560
+bearings ال bearings بيكون عندي outer raceو في
+
+409
+00:50:22,560 --> 00:50:27,400
+عندهم مثلا كورة inner race و outer race و في
+
+410
+00:50:27,400 --> 00:50:31,280
+loading على الكورات بيصيرهم بدل ما هو point
+
+411
+00:50:31,280 --> 00:50:38,740
+contact بتحول لاش ل area contact في
+
+412
+00:50:38,740 --> 00:50:45,560
+المباني عندهان two solid spheres عندها سفير واحد و
+
+413
+00:50:45,560 --> 00:50:51,660
+سفير اتنين قطر سفير واحد هذه دي واحد
+
+414
+00:50:56,790 --> 00:51:05,870
+هذه قطرها دي اتنين وفي
+
+415
+00:51:05,870 --> 00:51:11,850
+two forces F عندي
+
+416
+00:51:11,850 --> 00:51:17,690
+F على الجهة التانية هذا ال Z axis طبعا
+
+417
+00:51:17,690 --> 00:51:25,510
+ال material بتاعة ال أسفير هذه ال material بقى
+
+418
+00:51:25,510 --> 00:51:29,470
+كمواحدهذه ماتي الرقم اتنين due to the compression
+
+419
+00:51:29,470 --> 00:51:37,150
+force حسينا اندي هي area القطر بتاعي حسينا اندي
+
+420
+00:51:37,150 --> 00:51:41,410
+دائرة في الحالة هذه قطر
+
+421
+00:51:41,410 --> 00:51:47,370
+الدائرة اتنين ايه وال stress distribution is
+
+422
+00:51:50,130 --> 00:51:54,730
+non-linear stress distribution وقدر المنطقة طبعا
+
+423
+00:51:54,730 --> 00:51:59,870
+لما تكون ال contact على حواقف الدائرة يكون سفر
+
+424
+00:51:59,870 --> 00:52:05,850
+أكيد مظلوط على الحواقف سفر بعدين يكون maximum في
+
+425
+00:52:05,850 --> 00:52:12,010
+النص يكون ال stress maximum في النص ال maximum
+
+426
+00:52:12,010 --> 00:52:17,320
+pressureفي مركز ال contact area بتكون سوى تلاتة F
+
+427
+00:52:17,320 --> 00:52:23,040
+على اتنين by A تربيع الان ال A التي على الكوانت
+
+428
+00:52:23,040 --> 00:52:28,320
+القطرها اتنين A و نص القطر A بعتمد على ال two
+
+429
+00:52:28,320 --> 00:52:34,580
+materials مثل ال واحد و اتنين و القطر واحد و القطر
+
+430
+00:52:34,580 --> 00:52:40,180
+اتنين و بعتمد على ال F بزود ال F بتزيد ال A
+
+431
+00:52:50,350 --> 00:52:56,870
+Pmax المفروض إليها معادلة أنا
+
+432
+00:52:56,870 --> 00:53:03,530
+مش حاططها .. هاي المعادلة بتاعتها هاي المعادلة
+
+433
+00:53:03,530 --> 00:53:09,150
+بتعتبر
+
+434
+00:53:09,150 --> 00:53:12,010
+حكيتنا عن ال force زوّت ال force بتزيد ال a أكيد
+
+435
+00:53:13,510 --> 00:53:17,870
+بتعتمد على ال materials هندي poison ratio واحد
+
+436
+00:53:17,870 --> 00:53:22,650
+modulus velocity واحد poison ratio اتنين modulus
+
+437
+00:53:22,650 --> 00:53:26,770
+velocity اتنين يعني كل ما كان ال modulus velocity
+
+438
+00:53:26,770 --> 00:53:32,950
+صغير يعني زبارك يبقى اقل بكون كان زبارك طريق ال
+
+439
+00:53:32,950 --> 00:53:38,770
+area هتزيد صح؟كل ما تقل الزمبراكية يعني كانها soft
+
+440
+00:53:38,770 --> 00:53:44,310
+spring فال area ليه بيزيد مع ال model الاساسية
+
+441
+00:53:44,310 --> 00:53:47,970
+الان
+
+442
+00:53:47,970 --> 00:53:57,590
+and واحد على دي واحد زاد واحد على دي اتنين طبعا كل
+
+443
+00:53:57,590 --> 00:54:03,650
+ما بيزيد الأقطار لما تضغط الفرد بيكون أكتر تفرض
+
+444
+00:54:03,650 --> 00:54:21,560
+معاه أكتر صح؟فبتزيد ال a طيب
+
+445
+00:54:21,560 --> 00:54:26,300
+اذا كان ال maximum pressure معطلل اقل تلاتة F على
+
+446
+00:54:26,300 --> 00:54:33,030
+اتنين A تربيع والايل هي المعادلة السابقةلأن نتيجة
+
+447
+00:54:33,030 --> 00:54:35,610
+الـ Poisson Ratio Effect ان عندي I Compression في
+
+448
+00:54:35,610 --> 00:54:39,730
+اتجاه الـ Z Axis بيطلع عندى Sigma Z نتيجة الـ
+
+449
+00:54:39,730 --> 00:54:42,130
+Poisson Ratio Effect هيطلع عندى Sigma X و Sigma Y
+
+450
+00:54:42,130 --> 00:54:47,850
+Sigma X و Sigma Y اللي هيسميها Sigma X بيساوي
+
+451
+00:54:47,850 --> 00:54:50,250
+Sigma Y بيساوي Sigma X بيساوي Sigma Y بيساوي Sigma
+
+452
+00:54:50,250 --> 00:54:51,010
+X بيساوي Sigma Y بيساوي Sigma X بيساوي Sigma Y
+
+453
+00:54:51,010 --> 00:54:52,050
+بيساوي Sigma X بيساوي Sigma Y بيساوي Sigma X
+
+454
+00:54:52,050 --> 00:54:54,850
+بيساوي Sigma X بيساوي Sigma Y بيساوي Sigma X
+
+455
+00:54:54,850 --> 00:54:57,270
+بيساوي Sigma X بيساوي Sigma X بيساوي Sigma X
+
+456
+00:54:57,270 --> 00:54:57,570
+بيساوي Sigma X بيساوي Sigma X بيساوي Sigma X
+
+457
+00:54:57,570 --> 00:55:00,630
+بيساوي Sigma X بيساوي Sigma X بيسازد على ايه الزد
+
+458
+00:55:00,630 --> 00:55:05,830
+هي المسافة below the surface of contact يعني الزد
+
+459
+00:55:05,830 --> 00:55:13,970
+هاي عندى السلندر وهاي السلندر الزد هاي الزد هاي ال
+
+460
+00:55:13,970 --> 00:55:22,170
+zero هي ال zero زد كل منزل طبعا بيصير عندى زي مجال
+
+461
+00:55:22,170 --> 00:55:28,660
+مجال إجهادي كأنه مجال معناطيسيالان بيكون maximum
+
+462
+00:55:28,660 --> 00:55:37,440
+في بداية ال contact و كل ما أنزل لجوه بيبعد ..
+
+463
+00:55:37,440 --> 00:55:42,920
+بيبعد كتير بتريح المادة فيعني من غير معادلات من
+
+464
+00:55:42,920 --> 00:55:46,220
+الممكن تتوقعها فعندك minus P maximum في واحد minus
+
+465
+00:55:46,220 --> 00:55:49,240
+K مطلق على زد على A tan inverse واحد على زد على A
+
+466
+00:55:49,240 --> 00:55:52,220
+في واحد زد on U طيب
+
+467
+00:55:53,900 --> 00:55:57,840
+الـ sigma z مباشرة جاي من ال pressure من ال
+
+468
+00:55:57,840 --> 00:56:00,300
+maximum pressure minus P maximum على واحد زي z
+
+469
+00:56:00,300 --> 00:56:06,860
+تربيع على a تربيع يعني ال z approach infinity
+
+470
+00:56:06,860 --> 00:56:15,010
+sigma z approach zero يعني far from the contactفش
+
+471
+00:56:15,010 --> 00:56:19,350
+stress بيكون عندك، far from the contact فش stress
+
+472
+00:56:19,350 --> 00:56:30,750
+حاول مثلا تضغط عيدك لفترة طويلة شعار
+
+473
+00:56:30,750 --> 00:56:33,750
+بتحس أنه فيه stress على ال surface أعلى ما يمكن
+
+474
+00:56:33,750 --> 00:56:37,070
+لجوه بيخف بعد فترة ما تسيبه يريح
+
+475
+00:56:40,360 --> 00:56:46,140
+بصير عملية اللى هى برجع تضافق الدم طبيعى فبصير
+
+476
+00:56:46,140 --> 00:56:56,780
+اعادة توزيع للاجهدات و ترجع المادة لطبيعتها طبعا
+
+477
+00:56:56,780 --> 00:57:00,260
+ال stress أخلاقات stress element عند ال contact
+
+478
+00:57:00,260 --> 00:57:03,880
+stress element مباشرة عند ال contact
+
+479
+00:57:07,770 --> 00:57:19,130
+أو حتى بلوذا surface هكون دي هذا sigma z هاي
+
+480
+00:57:19,130 --> 00:57:28,070
+هناك sigma x يعني ماتتركزوش على اتجاهات حالياً هاي
+
+481
+00:57:28,070 --> 00:57:36,840
+sigma y واضح انه الإجهادات هذههذه ال stress ال
+
+482
+00:57:36,840 --> 00:57:42,360
+principal stress ليش؟ لأن مافيش شير ال principal
+
+483
+00:57:42,360 --> 00:57:45,320
+stress المقنعة ممكن أسميها سجن واحد سجن اتنين او
+
+484
+00:57:45,320 --> 00:57:50,480
+سجن تلاتة ومنها
+
+485
+00:57:50,480 --> 00:57:54,800
+بحسب tau max لأن اذا انا برتقله سجن واحد اكبر من
+
+486
+00:57:54,800 --> 00:58:00,840
+سجن اتنين اكبر من سجن تلاتة بحسب tau max بستوى سجن
+
+487
+00:58:00,840 --> 00:58:04,260
+واحد minus سجن تلاتة على اتنين
+
+488
+00:58:08,520 --> 00:58:11,580
+لو أخدنا مثلا الحديد ال poison rage بتاعة الحديد
+
+489
+00:58:11,580 --> 00:58:17,320
+تلاتة من عشرة تطلع ال tau max بسبب point تلاتة P
+
+490
+00:58:17,320 --> 00:58:23,020
+max at a depth of point four eight A على عمق
+
+491
+00:58:23,020 --> 00:58:30,340
+تقريبا point خمسة L A اتطلع
+
+492
+00:58:30,340 --> 00:58:34,680
+انا اللي بيصير عندى هاي
+
+493
+00:58:34,680 --> 00:58:41,950
+عندى ال Zالـ Z يعني المسافة تحت السطح على السطح
+
+494
+00:58:41,950 --> 00:58:48,010
+مباشرة Zero كل منزل لجوه الـ Z مالقاش بتزيد وهين
+
+495
+00:58:48,010 --> 00:58:51,770
+ال stress هين طبعا ال Sigma Z هذا ال Sigma Z زي ما
+
+496
+00:58:51,770 --> 00:58:58,230
+احكي هنا Sigma Z بيكون maximum عند ال Z Zero ال Z
+
+497
+00:58:58,230 --> 00:59:05,160
+goes to infinity بروح بتجاه سفر Sigma Zو ال sigma
+
+498
+00:59:05,160 --> 00:59:09,500
+x و sigma y برضه هاد ال sigma x و sigma y بتكون
+
+499
+00:59:09,500 --> 00:59:14,400
+maximum عند zero as z goes to infinity بتروح متجاه
+
+500
+00:59:14,400 --> 00:59:20,860
+الصفر لكن احنا حكينا ال tau match سوى sigma 1
+
+501
+00:59:20,860 --> 00:59:26,920
+minus sigma 3 لحظ الفرق هنا الفرق بين sigma 1 و
+
+502
+00:59:26,920 --> 00:59:31,280
+sigma 3 هاي الفرق عند النقطة هادة
+
+503
+00:59:34,980 --> 00:59:38,620
+هي الفرق صح؟ مش احنا نستوى انا استوى ماكسوف سيجما
+
+504
+00:59:38,620 --> 00:59:42,840
+واحد معناه سيجما تلاتة على اتنين يعني مص المسافة
+
+505
+00:59:42,840 --> 00:59:49,720
+هذه اللي هي هذه اللي هي هذه صح فال stress السيجما
+
+506
+00:59:49,720 --> 00:59:52,660
+واحد سيجما X سيجما Y سيجما Z بتكون maximum at Z
+
+507
+00:59:52,660 --> 00:59:55,760
+بيستوى Zero لكن ال shear stress maximum shear
+
+508
+00:59:55,760 --> 01:00:00,140
+stress بيكون at some distance below the surface في
+
+509
+01:00:00,140 --> 01:00:00,620
+حالة
+
+510
+01:00:04,400 --> 01:00:10,000
+الشيارة تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+511
+01:00:10,000 --> 01:00:14,180
+تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+512
+01:00:14,180 --> 01:00:14,180
+تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+513
+01:00:14,180 --> 01:00:14,300
+تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+514
+01:00:14,300 --> 01:00:14,300
+تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+515
+01:00:14,300 --> 01:00:14,300
+تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+516
+01:00:14,300 --> 01:00:18,900
+تقريبا تقريبا
+
+517
+01:00:18,900 --> 01:00:25,860
+تقريب
+
+518
+01:00:26,300 --> 01:00:29,220
+two cylinders contact يعني عندي هذا بطل تسفير هذا
+
+519
+01:00:29,220 --> 01:00:32,900
+السيلندر وهذا السيلندر برضه ال line contact هتحول
+
+520
+01:00:32,900 --> 01:00:37,900
+ل area contact عرض ال .. عرض ال area اللي هو اتنين
+
+521
+01:00:37,900 --> 01:00:42,080
+بيه والعمق اللي هو طول السيلندر طول السيلندر
+
+522
+01:00:42,080 --> 01:00:44,140
+الأقصر إذا كانوا مش نفس الطول
+
+523
+01:00:48,200 --> 01:00:51,120
+الـ B هو الطوابع العلاقه هذه الـ B هي حاجة تتعمل
+
+524
+01:00:51,120 --> 01:00:55,560
+ألف بزيدي ال F بزيدي ال B ال B هي هذه ال two B
+
+525
+01:00:55,560 --> 01:01:03,120
+بزيدي ال E بزيدي ال B بزيدي ال D بزيدي ال H برضه
+
+526
+01:01:03,120 --> 01:01:06,980
+ال B ال maximum pressure بيكون سواء اتنين F على بي
+
+527
+01:01:06,980 --> 01:01:13,120
+بي ال ال L هو طول استوانه البعد التالت و
+
+528
+01:01:13,120 --> 01:01:18,380
+طبعا فى عندى تلاتة stresses فى عندى Sigma Zسيجما X
+
+529
+01:01:18,380 --> 01:01:25,580
+وسيجما Y طبعا بيكونوا maximum at z equal zero عند
+
+530
+01:01:25,580 --> 01:01:29,520
+ال contact سيجما
+
+531
+01:01:29,520 --> 01:01:38,620
+Z وسيجما Y وسيجما X بيكونوا maximum at zero ال
+
+532
+01:01:38,620 --> 01:01:44,760
+tau max هي ال tau max بتكون at some distance below
+
+533
+01:01:44,760 --> 01:01:46,140
+the surface
+
+534
+01:01:48,870 --> 01:01:53,870
+Tau maximum and for Poise ratio point تلاتة بتكون
+
+535
+01:01:53,870 --> 01:01:56,690
+at a distance بسبب point سبعة تمانية ستة بيه طبعا
+
+536
+01:01:56,690 --> 01:02:03,210
+هذا هو z as a function of d وهذا ال access لل
+
+537
+01:02:03,210 --> 01:02:09,410
+stress في
+
+538
+01:02:09,410 --> 01:02:17,220
+اي سؤال؟شوفوا كمان خلصنا chapter تلاتة يعني تقريبا
+
+539
+01:02:17,220 --> 01:02:20,380
+قطينا كل ال mechanics of material مع بعض الشغلات
+
+540
+01:02:20,380 --> 01:02:22,480
+أعلى من مستوى ال mechanics of material
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/HcxL-em7sbY.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/HcxL-em7sbY.srt
new file mode 100644
index 0000000000000000000000000000000000000000..64d8a8be0795127c67be92ed7bea97531c17bbf6
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/HcxL-em7sbY.srt
@@ -0,0 +1,2521 @@
+1
+00:00:05,260 --> 00:00:08,120
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,120 --> 00:00:12,640
+وبركاته اليوم هنكمل الشرح الـ three load and
+
+3
+00:00:12,640 --> 00:00:17,440
+stress analysis اليوم هنبدأ نغطي الـ torsion في الـ
+
+4
+00:00:17,440 --> 00:00:22,280
+thin walled tubes طبعا 
+
+5
+00:00:22,280 --> 00:00:26,400
+الـ thin walled tubes قد تكون الـ tubes مغلقة أو
+
+6
+00:00:26,400 --> 00:00:31,740
+مفتوحة بيبين في الحالة دي عندي closed tube عند 
+
+7
+00:00:31,740 --> 00:00:32,300
+أنبوب
+
+8
+00:00:34,830 --> 00:00:43,050
+وفي عليها torque نتيجة الـ torque لو أخدت المقطع
+
+9
+00:00:43,050 --> 00:00:51,170
+هتصير 
+
+10
+00:00:51,170 --> 00:00:55,130
+عندي shear stress
+
+11
+00:01:20,510 --> 00:01:31,850
+تاُو  الـ tau box هتكون  ساويّة T في R على J لحظة وأنا 
+
+12
+00:01:31,850 --> 00:01:40,630
+أقعد في المنطقة فاضي طبعا هذا هيكون غير موجود لأنه
+
+13
+00:01:40,630 --> 00:01:41,650
+مش material صح؟
+
+14
+00:02:10,410 --> 00:02:18,010
+هذا thickness دي كل
+
+15
+00:02:18,010 --> 00:02:23,130
+ما قلّ thickness كل ما بتكون بتتجه في ارتفاع اللي
+
+16
+00:02:23,130 --> 00:02:29,930
+هو إيش الـ tau كل ما بيقلّ الـ thickness بتظهر هذه الـ
+
+17
+00:02:29,930 --> 00:02:38,870
+tau قيمتها بتزيد الـ tau على اللحم الحي هتزيد معناه 
+
+18
+00:02:38,870 --> 00:02:42,930
+أن هناك علاقة عكسية بين الـ tau والـ thickness  الـ T
+
+19
+00:02:42,930 --> 00:02:49,170
+لأن الحالة اللي كل مرة تقلّ الـ T بيزيد الـ tau
+
+20
+00:02:49,170 --> 00:02:57,650
+المفروض يعني الـ tau T بيساوي constant لأن
+
+21
+00:02:57,650 --> 00:03:01,670
+الـ tau تتناسب طردياً  وتتناسب عكسياً مع الـ T يعني الـ tau 
+
+22
+00:03:01,670 --> 00:03:04,810
+هتكون تساوي constant
+
+23
+00:03:06,530 --> 00:03:18,010
+على T فواضح أن T أو في T يساوي ثابت لو أخذنا
+
+24
+00:03:18,010 --> 00:03:22,530
+element إحنا
+
+25
+00:03:22,530 --> 00:03:28,410
+الزاوية هذه دي 
+
+26
+00:03:28,410 --> 00:03:40,160
+ثيتا وهذا radius R هذا الطول هيكون ds وفي shear stress
+
+27
+00:03:40,160 --> 00:03:45,520
+قيمته تقريبا
+
+28
+00:03:45,520 --> 00:03:56,960
+الـ
+
+29
+00:04:04,550 --> 00:04:07,150
+طبعا نتيجة shear stress هتصير عندي force tangential
+
+30
+00:04:07,150 --> 00:04:14,590
+force DF DF هتكون
+
+31
+00:04:14,590 --> 00:04:18,030
+الـ
+
+32
+00:04:18,030 --> 00:04:25,590
+shear stress هتكون tau في T في DS
+
+33
+00:04:33,170 --> 00:04:45,650
+الآن دي torque R دي F يعني هتكون تاو T في R DS
+
+34
+00:04:45,650 --> 00:04:55,730
+معناه الـ torque هيكون تكامل tau T
+
+35
+00:04:55,730 --> 00:05:00,150
+في R DS
+
+36
+00:05:06,650 --> 00:05:11,930
+الـ tau t قيمتها constant تطلع برة كلها مع بعض
+
+37
+00:05:11,930 --> 00:05:19,430
+فهذا الشيء اللي عندي tau t تكامل R DS
+
+38
+00:05:19,430 --> 00:05:28,830
+من في الحالة هذه من صفر لـ 2 π لحظة
+
+39
+00:05:28,830 --> 00:05:30,430
+لو أخدت المثلث ده 
+
+40
+00:05:38,710 --> 00:05:46,830
+مساحته مش هتكون مساحته نص
+
+41
+00:05:46,830 --> 00:05:51,130
+القاعدة في الارتفاع نص DS ولأن الـ D بتصغر كتير هتكون
+
+42
+00:05:51,130 --> 00:06:05,330
+في الـ R هتساوي نص الـ R نص الـ R DS نص الـ R DS
+
+43
+00:06:07,690 --> 00:06:12,850
+معناته 2 π دي 
+
+44
+00:06:12,850 --> 00:06:20,190
+هتصير ساويّة R DS معناته ده الـ term مش هتصير لما
+
+45
+00:06:20,190 --> 00:06:25,870
+أعمل integration معناته 2 π 
+
+46
+00:06:25,870 --> 00:06:29,110
+هتصير
+
+47
+00:06:29,110 --> 00:06:37,050
+ساويّة تكامل R DS أم لأن هذه مثلثات نجمع نجمعها
+
+48
+00:06:37,050 --> 00:06:43,290
+مثلثات هاخد مساحة الدائرة هذه صح فهتصفى
+
+49
+00:06:43,290 --> 00:06:53,750
+الـ torque ساويّة tau T في 2 π AM منها بنحسب 
+
+50
+00:06:56,330 --> 00:07:09,350
+shear stress tau T على 2 π AM ليه
+
+51
+00:07:09,350 --> 00:07:17,810
+المعادلة هذه طبعا
+
+52
+00:07:17,810 --> 00:07:24,040
+الـ AM هي الـ area enclosed by the section median
+
+53
+00:07:24,040 --> 00:07:27,820
+line section median line اللي هو هذا هذا الـ median 
+
+54
+00:07:27,820 --> 00:07:35,840
+line الـ
+
+55
+00:07:35,840 --> 00:07:44,100
+angle twist في الـ .. في الـ tube هيكون T في LM على
+
+56
+00:07:44,100 --> 00:07:51,450
+4 G AM تربيع هو طول الـ media line طول الـ media
+
+57
+00:07:51,450 --> 00:07:56,250
+line في حالة الدائرة طول الـ media line بيكون محيط 
+
+58
+00:07:56,250 --> 00:08:03,110
+الدائرة صح نشوف
+
+59
+00:08:03,110 --> 00:08:09,030
+مثال أول steel tube is forty inch long في عنده
+
+60
+00:08:09,030 --> 00:08:15,770
+steel tube طولها أربعين إنش الـ tube شكلها مستطيل 
+
+61
+00:08:16,600 --> 00:08:21,200
+بالطول تاعها أربعين إنش المقطع 2.5 إنش في 
+
+62
+00:08:21,200 --> 00:08:30,420
+3.6 و10 إنش بسماكة 0.1 إنش assume 
+
+63
+00:08:30,420 --> 00:08:37,680
+allowable shear stress الـ shear stress المسموح فيه
+
+64
+00:08:37,680 --> 00:08:44,600
+بـ 11.5 كيلو pound لكل
+
+65
+00:08:44,600 --> 00:08:54,600
+إنش مربع والـ shear modulus G بـ 11.5 ميجا
+
+66
+00:08:54,600 --> 00:09:01,540
+pound per square inch estimate
+
+67
+00:09:01,540 --> 00:09:08,160
+allowable torque احسب T allowable 
+
+68
+00:09:08,160 --> 00:09:13,500
+عند
+
+69
+00:09:13,500 --> 00:09:18,560
+المقطع طبعا هذه المعادلة بنفرضها يعني هتكون دي
+
+70
+00:09:18,560 --> 00:09:26,120
+المعادلة اللي هي tau ساويّة
+
+71
+00:09:26,120 --> 00:09:37,260
+T على 2 π AM في T والـ theta ساويّة
+
+72
+00:09:37,260 --> 00:09:55,610
+T LM على 4 G AM تربيع في T إحنا
+
+73
+00:09:55,610 --> 00:09:59,430
+بدنا نحسب إيه؟ الـ torque فلوقت الـ torque اللي هو 
+
+74
+00:09:59,430 --> 00:10:11,070
+bolt torque هيكون 2 tau AM في T الـ T عندنا 
+
+75
+00:10:11,070 --> 00:10:17,200
+معروف thickness اللي هو 0.18 إنش يعني 0.1
+
+76
+00:10:17,200 --> 00:10:21,140
+ثمانية
+
+77
+00:10:21,140 --> 00:10:25,800
+إنش والتعب عطيني 11.5 كيلو pound per
+
+78
+00:10:25,800 --> 00:10:31,640
+square inch بتضلي الـ AM الـ AM هي المستطيلة عندي 
+
+79
+00:10:42,080 --> 00:11:01,920
+الـ section media line هو هذا هذا 
+
+80
+00:11:01,920 --> 00:11:09,620
+أكمل طوله 3.6 هذا هيكون 3.6
+
+81
+00:11:09,620 --> 00:11:14,120
+معقص ثمانية هي واحدة 16 هنا وواحدة 16 هنا 
+
+82
+00:11:14,120 --> 00:11:25,380
+صح هتكون يعني 3.6 ناقص 0.1 
+
+83
+00:11:25,380 --> 00:11:33,240
+2.5 هيطلع
+
+84
+00:11:33,240 --> 00:11:38,960
+3.47 
+
+85
+00:11:40,580 --> 00:11:53,720
+خمسة مظبوط زي هيك والطول
+
+86
+00:11:53,720 --> 00:11:58,880
+هذا هذا
+
+87
+00:11:58,880 --> 00:12:04,880
+كله نص هذا
+
+88
+00:12:04,880 --> 00:12:05,300
+هيكون 
+
+89
+00:12:08,320 --> 00:12:12,140
+نص ناقص 0.125 هتكون 2.
+
+90
+00:12:12,140 --> 00:12:24,940
+375 صح؟
+
+91
+00:12:24,940 --> 00:12:28,560
+معناته 
+
+92
+00:12:28,560 --> 00:12:33,220
+الـ AM مش هتساوي هتكون 
+
+93
+00:12:33,220 --> 00:12:37,430
+تساوي طول الـ media line في الارتفاع المستطيل هتكون
+
+94
+00:12:37,430 --> 00:12:44,370
+ساويّة 3.475 في 2.
+
+95
+00:12:44,370 --> 00:12:52,930
+375 هذا الـ AM 
+
+96
+00:12:52,930 --> 00:12:59,290
+والـ
+
+97
+00:12:59,290 --> 00:12:59,650
+LM
+
+98
+00:13:03,020 --> 00:13:08,080
+هيكون هذا الطول زائد هذا زائد هذا زائد هذا بالظبط 
+
+99
+00:13:08,080 --> 00:13:13,800
+يعني عندك 2 3.475 زائد 
+
+100
+00:13:13,800 --> 00:13:20,140
+2.375 في 2 عشان تلعب
+
+101
+00:13:20,140 --> 00:13:24,040
+12 12
+
+102
+00:13:24,040 --> 00:13:30,200
+point أكتر من 11
+
+103
+00:13:30,200 --> 00:13:30,820
+point سبعة 
+
+104
+00:13:43,090 --> 00:13:50,390
+معناته الـ torque هيكون ساويّة 2 الـ tau 11000
+
+105
+00:13:50,390 --> 00:13:54,810
+و 500 في 
+
+106
+00:13:54,810 --> 00:13:58,350
+الـ AM 8.
+
+107
+00:13:58,350 --> 00:14:05,850
+253 في الـ thickness 0.1 على 
+
+108
+00:14:05,850 --> 00:14:06,370
+ثمانية
+
+109
+00:14:22,350 --> 00:14:31,130
+أه إحنا اشتقينا المعادلة إحنا
+
+110
+00:14:31,130 --> 00:14:41,230
+اشتقيناها لحالة مقطع مفرغ ودائري وعملنا
+
+111
+00:14:41,230 --> 00:14:48,360
+الحالة اللي عند المقطع مش مدور المقطع قيمته مستطيل
+
+112
+00:14:48,360 --> 00:14:52,820
+لما عملت اشتقاق المعادلات على مدور فـ الـ definitions
+
+113
+00:14:52,820 --> 00:14:58,000
+still apply يعني لما حكيت في المقطع المدور حكيت
+
+114
+00:14:58,000 --> 00:15:05,080
+اللي هو الـ EM مساحة الدائرة المتوسطة في الـ tube
+
+115
+00:15:05,080 --> 00:15:10,020
+بالظبط نفس الشيء في حالة مقطع مستطيل أي مقطع ثاني 
+
+116
+00:15:10,020 --> 00:15:11,240
+لو كانت ده مقطع زي هيك
+
+117
+00:15:17,480 --> 00:15:23,140
+الـ thickness زي هيك الـ media line تتعامل مع الـ
+
+118
+00:15:23,140 --> 00:15:31,420
+media line برضه تتعامل مع الـ media line بحث
+
+119
+00:15:31,420 --> 00:15:34,920
+الـ area اللي داخلة داخل الـ media line بغض النظر عن النقطة
+
+120
+00:15:34,920 --> 00:15:40,340
+المقطعة نقطة نقطة 23000 23
+
+121
+00:15:40,340 --> 00:15:40,720
+000
+
+122
+00:15:53,010 --> 00:15:56,670
+Pound هذا الـ allowable torque يعني هذا العزم 
+
+123
+00:15:56,670 --> 00:16:01,430
+المسموح فيه 23720 Pound لو دي حسب الـ angle twist theta theta 
+
+124
+00:16:08,870 --> 00:16:13,410
+بتساوي اللي هو الـ torque اللي هو 23720 
+
+125
+00:16:13,410 --> 00:16:28,300
+في الـ L M في 11.7 على 4 G 11
+
+126
+00:16:28,300 --> 00:16:38,260
+.5 في 10 أس 6 عشان نحولها للـ PSI في الـ AM تربيع في
+
+127
+00:16:38,260 --> 00:16:47,140
+8.253 تربيع في الـ thickness اللي هو 0.125 اللي
+
+128
+00:16:47,140 --> 00:17:08,890
+هو 0.18 هتطلع 3 أصفار بالـ radians 0
+
+129
+00:17:08,890 --> 00:17:14,310
+.0007
+
+130
+00:17:14,310 --> 00:17:18,050
+radians
+
+131
+00:17:20,640 --> 00:17:24,660
+يعني لو ده حوالي الـ degrees هضربه في 180
+
+132
+00:17:24,660 --> 00:17:42,780
+على π هضربه في 180 على π بيطلع 
+
+133
+00:17:42,780 --> 00:17:46,900
+0.400 أربعة
+
+134
+00:17:50,400 --> 00:17:58,720
+04 degrees
+
+135
+00:17:58,720 --> 00:18:05,240
+يعني 
+
+136
+00:18:05,240 --> 00:18:08,880
+نقسم 1 على 0.4 1 على 0.
+
+137
+00:18:08,880 --> 00:18:13,780
+4 يعني 1 على 25 دي الـ degree صح؟ 
+
+138
+00:18:16,080 --> 00:18:18,900
+هتطلع 1 على 25 يعني الـ degree الدرجة
+
+139
+00:18:18,900 --> 00:18:27,120
+نقسمها 25 تقسيمها في 
+
+
+
+141
+00:18:27,120 --> 00:18:35,180
+أي سؤال شوف مثال ثاني compare
+
+142
+00:18:45,710 --> 00:18:48,770
+Compare the shear stress on a circular cylindrical
+
+143
+00:18:48,770 --> 00:18:54,490
+tube في عندي أنبوب مقطعها أسطوانة with an outside
+
+144
+00:18:54,490 --> 00:18:58,030
+diameter of one inch القطر الخارجي بتاعها هذا 
+
+145
+00:18:58,030 --> 00:19:06,050
+tube اللي قطر خارجه اللي
+
+146
+00:19:06,050 --> 00:19:09,730
+قطر داخله القطر الخارجي بتاعها واحد إنش
+
+147
+00:19:19,900 --> 00:19:36,720
+واحد إنش والقطر الداخلي تسعة وعشرة إنش بنحسب
+
+148
+00:19:36,720 --> 00:19:43,600
+ال shear stress tau في
+
+149
+00:19:43,600 --> 00:19:48,440
+حالة استخدمت equation تلاتة
+
+150
+00:19:48,440 --> 00:19:56,410
+سبعة و ثلاثين مرة في حالة باستخدام equation تلاتة
+
+151
+00:19:56,410 --> 00:20:02,110
+خمسة وأربعين equation تلاتة خمسة وأربعين اللي هي
+
+152
+00:20:02,110 --> 00:20:07,890
+آخر واحدة أقولها اللي
+
+153
+00:20:07,890 --> 00:20:14,770
+هي هذه تلاتة
+
+154
+00:20:14,770 --> 00:20:21,680
+سبعة وثلاثين ال Tao تساوي T Tao max Tao R على J هذه
+
+155
+00:20:21,680 --> 00:20:36,420
+تلاتة سبعة وثلاثين و Tao تساوي T على اثنين AM T
+
+156
+00:20:36,420 --> 00:20:39,600
+اللي هي التلاتة خمسة وأربعين
+
+157
+00:20:52,800 --> 00:21:02,120
+طبعًا لنفس ال torque لنفس ال torque طيب أولًا
+
+158
+00:21:02,120 --> 00:21:05,800
+شوف نحسب ال end ال radius ال shear distance هيكون
+
+159
+00:21:05,800 --> 00:21:08,720
+maximum على ال outer fiber هيكون maximum هنا صح
+
+160
+00:21:08,720 --> 00:21:16,440
+التاو هتكون تاو maximum هتكون تساوي ال T في R
+
+161
+00:21:16,440 --> 00:21:18,720
+على J معناته ال R بتساوي
+
+162
+00:21:21,990 --> 00:21:31,330
+هيكون الشير السترس عند هنا ال maximum هي
+
+163
+00:21:31,330 --> 00:21:38,690
+كبير زي الشير السترس هذه ال tau max وهذه
+
+164
+00:21:38,690 --> 00:21:45,110
+ال tau minimum نحسب
+
+165
+00:21:45,110 --> 00:21:48,570
+ال J ال J ال polar moment of inertia يعني عندي
+
+166
+00:21:48,570 --> 00:21:58,960
+عبارة عن دائرتين صح؟ هتكون باي على اثنين وثلاثين في
+
+167
+00:21:58,960 --> 00:22:04,440
+القطر الخارجي اللي هو واحد قص أربعة ناقص تسعة و
+
+168
+00:22:04,440 --> 00:22:12,530
+عشرة قص أربعة حسبولي الجهةيعني point 8 1 في point
+
+169
+00:22:12,530 --> 00:22:19,930
+8 1 يعني هتكون point 1 9 في point 1 1 و point 1 9
+
+170
+00:22:19,930 --> 00:22:25,210
+في point 1 9 تطلع point O تلاتة ستة تلاتة تسعة
+
+171
+00:22:25,210 --> 00:22:28,310
+أربعة زي ايه Zero point zero تلاتة تلاتة Zero
+
+172
+00:22:28,310 --> 00:22:34,350
+point zero three three درست
+
+173
+00:22:34,350 --> 00:22:36,450
+في بقعة اثنين وثلاثين بقعة اثنين وثلاثين
+
+174
+00:22:43,460 --> 00:23:06,160
+0.03×32 هذا الجهاز احسبها كم المرة 0
+
+175
+00:23:06,160 --> 00:23:08,480
+.34×32
+
+176
+00:23:09,500 --> 00:23:12,820
+يحسب ليها كامل اضربها بعدين ثلاثين اضربها اضربها
+
+177
+00:23:12,820 --> 00:23:17,060
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+178
+00:23:17,060 --> 00:23:17,160
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+179
+00:23:17,160 --> 00:23:17,360
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+180
+00:23:17,360 --> 00:23:18,560
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+181
+00:23:18,560 --> 00:23:18,680
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+182
+00:23:18,680 --> 00:23:19,580
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+183
+00:23:19,580 --> 00:23:26,300
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+184
+00:23:26,300 --> 00:23:26,360
+ا
+
+185
+00:23:37,040 --> 00:23:45,520
+اللي هو واحد ناقص point تسعة على اثنين point zero
+
+186
+00:23:45,520 --> 00:24:00,420
+خمسة إنش ال medium circle اللي في النصي
+
+187
+00:24:00,420 --> 00:24:05,220
+دي medium هتكون
+
+188
+00:24:05,220 --> 00:24:15,490
+تساوي واحد ناقص point one ناقص point zero
+
+189
+00:24:15,490 --> 00:24:20,870
+five يعني هتكون point تسعة خمسة إنش
+
+190
+00:24:29,310 --> 00:24:37,070
+تساوي باي على أربعة DM تربيع يعني باي على أربعة
+
+191
+00:24:37,070 --> 00:24:50,450
+في ال DM اللي هي في point ساعة خمسة تربيع كام؟
+
+192
+00:24:50,450 --> 00:24:55,150
+Zero point Zero point كم يعني أعطيه ليه كمان
+
+193
+00:24:55,150 --> 00:25:09,390
+رقمين؟ 0.708 كم الرقم؟ ثمانيتين إنش تربيع
+
+194
+00:25:09,390 --> 00:25:20,630
+هذا الام هذا
+
+195
+00:25:20,630 --> 00:25:27,800
+كم؟ واحد إنش وهذا كم؟لما أطرح واحد ناقصها ناشرة
+
+196
+00:25:27,800 --> 00:25:34,620
+بيعطينا هادي زائد هادي على الجهتين صح؟ لما أطرح
+
+197
+00:25:34,620 --> 00:25:37,280
+هذا الطول هذا الطول من هذا الطول بيعطينا هادي زائد
+
+198
+00:25:37,280 --> 00:25:45,700
+هادي اللي هو اثنين ال T مش هي القسم ده اثنين طيب
+
+199
+00:25:45,700 --> 00:25:48,020
+الآن
+
+200
+00:25:50,760 --> 00:25:59,280
+باستخدام واحد equation تلاتة سبعة و ثلاثين ال tau
+
+201
+00:25:59,280 --> 00:26:04,400
+max هتكون اللي
+
+202
+00:26:04,400 --> 00:26:12,520
+هو ال T في ال R اللي هو نص إنش على
+
+203
+00:26:12,520 --> 00:26:18,900
+ال LJ اللي هو point O تلاتة تلاتة
+
+204
+00:26:24,110 --> 00:26:31,810
+حسبوها و ال tau minimum هتكون
+
+205
+00:26:31,810 --> 00:26:36,050
+تساوي tau max على
+
+206
+00:26:36,050 --> 00:26:40,390
+bond خمسة في bond أربعة خمسة
+
+207
+00:26:45,200 --> 00:26:51,840
+فاكروا كيف أنا عملت هذه براحتكوا يعني الآن تاومن
+
+208
+00:26:51,840 --> 00:26:54,740
+.. تاومن على bond .. يعني نفس المعادلة بس قسمت على
+
+209
+00:26:54,740 --> 00:27:00,080
+bond فاردت bond ابقى خمسة هاي اللي صار حسبوا
+
+210
+00:27:00,080 --> 00:27:03,360
+الأولى
+
+211
+00:27:03,360 --> 00:27:07,680
+خمسة عشر
+
+212
+00:27:07,680 --> 00:27:11,460
+.. خمسة عشر
+
+213
+00:27:11,460 --> 00:27:14,040
+ال T هذه
+
+214
+00:27:19,020 --> 00:27:25,680
+ثلاثين point تلاتة في point أربعة و خمسة أكمل
+
+215
+00:27:25,680 --> 00:27:32,740
+كلها كاملة تلاتة
+
+216
+00:27:32,740 --> 00:27:39,360
+عشرة point تلاتة و ستين T معناه في ال T mean ال T
+
+217
+00:27:39,360 --> 00:27:45,860
+average هتكون تاو average هتكون تساوي تاو max زائد
+
+218
+00:27:45,860 --> 00:27:51,500
+تاو مين و عتنين تاو average هتكون خمسة عشر point
+
+219
+00:27:51,500 --> 00:28:00,960
+خمسة عشر زائد تلاتة عشر point ستة تلاتة على اثنين في
+
+220
+00:28:00,960 --> 00:28:04,780
+ال
+
+221
+00:28:04,780 --> 00:28:13,500
+T لأن
+
+222
+00:28:13,500 --> 00:28:14,480
+باستخدام equation
+
+223
+00:28:18,050 --> 00:28:27,610
+تلاتة خمسة وأربعين هتكون التاو تساوي
+
+224
+00:28:27,610 --> 00:28:38,030
+T على اثنين AM في T تساوي
+
+225
+00:28:38,030 --> 00:28:46,790
+T على AM احنا حسبنا AM اللي هي point سبعة سفر
+
+226
+00:28:46,790 --> 00:28:54,890
+ثمانية ثمانية و ال thickness اللي هو point O خمسة
+
+227
+00:28:54,890 --> 00:29:11,170
+خلط
+
+228
+00:29:11,170 --> 00:29:26,570
+غلط يعني هدول غلطيًا دة غلط هي فيه اثنين على
+
+229
+00:29:26,570 --> 00:29:33,430
+اثنين بتطلع على صح أربعة عشر point كم الرقم T
+
+230
+00:29:44,680 --> 00:29:50,200
+يعني إذا اعتبرت هذا ال reference هيكون الاختلاف
+
+231
+00:29:50,200 --> 00:29:58,380
+percentage difference تساوي
+
+232
+00:29:58,380 --> 00:30:06,900
+14.39T-14.08T
+
+233
+00:30:08,880 --> 00:30:17,680
+على أربعة عشر point تسعة ثلاثين T في مية هتروح ال T
+
+234
+00:30:17,680 --> 00:30:22,860
+مع بعض سابل
+
+235
+00:30:22,860 --> 00:30:27,000
+ال أربعة عشر point تسعة ثلاثين ناقص أربعة عشر point
+
+236
+00:30:27,000 --> 00:30:32,380
+تسعة ثلاثين يعني هتكون point واحد ثلاثين على أربعة
+
+237
+00:30:32,380 --> 00:30:33,760
+عشر point تسعة ثلاثين في مية
+
+238
+00:30:42,710 --> 00:30:45,430
+بدي أحسبه سريع إذا رقم ذاك بتاخد فيه دقيقة وفوت
+
+239
+00:30:45,430 --> 00:30:50,030
+شفه وطلعه ال
+
+240
+00:30:50,030 --> 00:30:56,790
+personal
+
+241
+00:30:56,790 --> 00:31:02,610
+difference اثنين في المية يعني الفرق قليل كثير
+
+242
+00:31:02,610 --> 00:31:10,090
+نكمل
+
+243
+00:31:24,940 --> 00:31:28,340
+الآن في حالة open thin wall sections إذا عندي
+
+244
+00:31:28,340 --> 00:31:35,920
+الأنبوبة زي هذه مش مسكرة فيها فتحة تتوقع تكون أقوى
+
+245
+00:31:35,920 --> 00:31:42,100
+ولا أضعف؟ هتكون أضعف أكيد يعني مش هتشيل torque زي
+
+246
+00:31:42,100 --> 00:31:43,740
+لو كانت مغلقة
+
+247
+00:31:47,500 --> 00:31:52,120
+في الحالة دي لما هذا ال media line media line مش
+
+248
+00:31:52,120 --> 00:31:58,060
+مغلق بسميه open thin section عند مستطيل ممكن
+
+249
+00:31:58,060 --> 00:32:03,820
+أعتبرها مستطيل واستخدم معادلات السابقة أرتبه مقطع
+
+250
+00:32:03,820 --> 00:32:11,100
+مفتوح مش مغلق عند ال c shape هذا open مش مسكر ال
+
+251
+00:32:11,100 --> 00:32:16,700
+media line ال L shape برضه open ال z shape برضه ايه
+
+252
+00:32:16,700 --> 00:32:23,640
+عشان open ال torque نفس الشيء ال stress بتاعه سواء
+
+253
+00:32:23,640 --> 00:32:32,240
+ثلاثة T على L C تربيع ال T هو ال applied torque الـ
+
+254
+00:32:32,240 --> 00:32:37,360
+L طول ال media line يعني هذا هذا هو ال L هذا الطول
+
+255
+00:32:37,360 --> 00:32:42,060
+هذا كله هذا L هذا مع هذا مع هذا L هذا مع هذا L هذا
+
+256
+00:32:42,060 --> 00:32:48,280
+مع هذا مع هذا L ال C اللي هو ال thickness هذا ال C
+
+257
+00:32:48,280 --> 00:32:55,700
+هذا ال C هذا ال C هذا ال C هذا ال C ال .. و ال G
+
+258
+00:32:55,700 --> 00:32:58,900
+اللي هي ال modulus of rigidity او shear modulus
+
+259
+00:33:10,070 --> 00:33:13,810
+for small wall thickness stress and twist can
+
+260
+00:33:13,810 --> 00:33:18,150
+become quite large بالمقارنة معاياش لو كان المقطع
+
+261
+00:33:18,150 --> 00:33:22,810
+مغلق يعني لما يكون المقطع مش مغلق مفتوح ال share
+
+262
+00:33:22,810 --> 00:33:28,910
+stress و الزاوية اللي هيزداد بشكل كبير خلنا نعمل
+
+263
+00:33:28,910 --> 00:33:33,590
+مقارنة في عندي compare this round tube with and
+
+264
+00:33:33,590 --> 00:33:36,330
+without slit يعني في عندي هنا نبوب
+
+265
+00:33:41,130 --> 00:33:46,550
+بدنا نعمل دراسة الأول إنها مغلقة الحالة الثانية مش
+
+266
+00:33:46,550 --> 00:33:52,410
+مغلقة ratio of wall thickness to outside diameter
+
+267
+00:33:52,410 --> 00:34:03,290
+of point one يعني هذا هو ال wall thickness وهذا
+
+268
+00:34:03,290 --> 00:34:08,570
+ish ال outside diameter لأن دي T على ال outside
+
+269
+00:34:08,570 --> 00:34:18,720
+diameter بتساوي point one في حال لو كانت مغلقة نرجع
+
+270
+00:34:18,720 --> 00:34:24,940
+لعيش للمعادلة ال tao اش يساوي في حال نحكي هنا and
+
+271
+00:34:24,940 --> 00:34:29,980
+closed و
+
+272
+00:34:29,980 --> 00:34:40,060
+and اش open بيكون ال tao بيساوي T على اثنين اقم
+
+273
+00:35:08,410 --> 00:35:10,910
+طيب ال A أهم مش تساوي
+
+274
+00:35:14,690 --> 00:35:31,430
+by على أربعة أنا عندي هاي الدائرة ها
+
+275
+00:35:31,430 --> 00:35:38,910
+دي ال DM ال DM شو يساوي
+
+276
+00:35:43,870 --> 00:35:47,830
+بتساوي ال D ناقص
+
+277
+00:35:47,830 --> 00:35:57,510
+ال T بتساوي ال D ال T اللي هي عشان تساوي عشر ال D صح
+
+278
+00:35:57,510 --> 00:36:06,390
+يعني هتكون تساوي point nine ال D باي على أربعة DM
+
+279
+00:36:06,390 --> 00:36:15,850
+تربيع يعني باي على أربعة في point nine تسعة دي لكل
+
+280
+00:36:15,850 --> 00:36:26,870
+تربيع يعني هتكون باي على أربعة في point ثمانية واحد 
+
+281
+00:36:26,870 --> 00:36:31,590
+دي تربيع يعني
+
+282
+00:36:31,590 --> 00:36:40,050
+شير ستريس تاو هكون تاو تي على اتنين في باي على أربع
+
+283
+00:36:42,730 --> 00:36:51,030
+في point 0.81 ادي تربيع وال thickness اللي
+
+284
+00:36:51,030 --> 00:36:57,350
+هو عشر ادي يعني
+
+285
+00:36:57,350 --> 00:37:07,330
+هكون سوى اتنين تي على باي
+
+286
+00:37:07,330 --> 00:37:20,980
+في point 0.81 دي تكيب هاد
+
+287
+00:37:20,980 --> 00:37:27,280
+في حالة ال closed في حالة ال open القلش هتساوي
+
+288
+00:37:27,280 --> 00:37:32,180
+المحيط
+
+289
+00:37:32,180 --> 00:37:44,910
+بيساوي باي دي يعني هتكون باي في دي اللي هي في تسعة من
+
+290
+00:37:44,910 --> 00:37:51,730
+عشرة دي تقريبا أنا عملت خسارة
+
+291
+00:37:51,730 --> 00:37:57,350
+في طول مثل السلطة يعني التاو هتكون تساوي تلاتة تي
+
+292
+00:37:57,350 --> 00:38:05,650
+على ال L اللي هي تسعة من عشرة باي
+
+293
+00:38:09,930 --> 00:38:18,030
+دي ال سي عبارة عن ايش عن ال تي ال سي اللي هي تساوية تي
+
+294
+00:38:18,030 --> 00:38:30,990
+بالساوية عشر دي في عشر دي كل تربيع يعني هتكون
+
+295
+00:38:30,990 --> 00:38:37,590
+تساوي خلنا نسميها تاو واحد تاو اتنين يعني هتكون
+
+296
+00:38:40,240 --> 00:38:44,800
+تلاتة تي على
+
+297
+00:38:44,800 --> 00:38:50,760
+point 1 في point 1 اللي هي point 0.1 يعني
+
+298
+00:38:50,760 --> 00:39:00,040
+هتكون على point 0.09 باي ديتا كيب هاتة و اتنين
+
+299
+00:39:07,460 --> 00:39:13,840
+لو نقسم تاو اتنين على تاو واحد تاو اتنين على تاو
+
+300
+00:39:13,840 --> 00:39:20,620
+واحد هتكون تساوي تلاتة تي على بونت 0.09 باي
+
+301
+00:39:20,620 --> 00:39:29,860
+دي تكيب في هاد هتطلع صرف البسط هاد في باي في
+
+302
+00:39:29,860 --> 00:39:34,280
+بونت 0.8
+
+303
+00:39:34,280 --> 00:39:34,820
+1
+
+304
+00:39:37,550 --> 00:39:48,610
+دي تكيب على اتنين تي يعني أنا هتروح عند ال تي مع تي دي
+
+305
+00:39:48,610 --> 00:39:55,310
+تكيب مع دي تكيب و باي مع باي وهذه اللي ضربتها في
+
+306
+00:39:55,310 --> 00:39:59,970
+الف هتسير عند ايه تلاتة ع اتنين اللي هو 1.5
+
+307
+00:40:01,330 --> 00:40:09,750
+في 1.8 على 9 يعني هتكون 1.5 في
+
+308
+00:40:09,750 --> 00:40:17,690
+9 اللي هي 13.5 المعنى الشير ستريس في حالة
+
+309
+00:40:17,690 --> 00:40:25,310
+ال open section حوالي 14 أضعاف ارتفاع
+
+310
+00:40:25,310 --> 00:40:31,150
+ارتفاع الشير ستريس ميزة ولا سيئة سيء برفع ال stress
+
+311
+00:40:31,150 --> 00:40:43,670
+level فيه شكل المقطع برفع ال stress level فيه طبعا
+
+312
+00:40:43,670 --> 00:40:45,850
+هو طلع عنده 12 من 3 أنا عملت
+
+313
+00:40:45,850 --> 00:40:51,690
+approximation عشان اسهل الحسابات لما هنا عنده في
+
+314
+00:40:51,690 --> 00:40:59,590
+اندجابة عنده هنا ففرود أطراحها هذه طيب ال Twist
+
+315
+00:40:59,590 --> 00:41:12,390
+Angle الحالة الأولى هي θ واحد بالساوية θ
+
+316
+00:41:12,390 --> 00:41:17,210
+واحد بالساوية تي ال
+
+317
+00:41:17,210 --> 00:41:21,190
+أم على
+
+318
+00:41:21,190 --> 00:41:28,430
+4 جي أم تربيع
+
+319
+00:41:30,210 --> 00:41:42,370
+إف اتش في ال تي الحلق الثاني ثيتا تو في ال open اللي
+
+320
+00:41:42,370 --> 00:41:47,550
+هتساوي هتساوي
+
+321
+00:41:47,550 --> 00:41:56,010
+من هذه ال θ واحد بتساوي تلاتة تي تلاتة تي على
+
+322
+00:41:56,010 --> 00:41:58,190
+جي
+
+323
+00:42:00,850 --> 00:42:07,130
+ال سي تكيب يعني
+
+324
+00:42:07,130 --> 00:42:20,090
+هتكون تساوي تلاتة تي على جي ال تي تكيب صح؟ يعني ال
+
+325
+00:42:20,090 --> 00:42:24,490
+ثيتا تو على
+
+326
+00:42:24,490 --> 00:42:34,140
+ال ثيتا واحد هتكون تساوي تلاتة تي على ال جي ال تي
+
+327
+00:42:34,140 --> 00:42:52,220
+تكيب في 4 جي أم تربيع تي على تي ال ام خلينا نعمل
+
+328
+00:42:52,220 --> 00:43:00,020
+اختصارات هند ال جي بتروح هند ال تورك بيروحو
+
+329
+00:43:00,020 --> 00:43:09,120
+عندي تي بتروح هنا تصير هنا تربيع تصفي تلاتة
+
+330
+00:43:09,120 --> 00:43:15,140
+في 4 12 أم
+
+331
+00:43:15,140 --> 00:43:18,440
+تربيع
+
+332
+00:43:18,440 --> 00:43:26,820
+على ال تي تربيع ال أم
+
+333
+00:43:29,990 --> 00:43:47,610
+يعني هيساوي 12 قيم اللي هي باي على 4 في
+
+334
+00:43:47,610 --> 00:43:51,710
+بونت 8 يعني
+
+335
+00:43:51,710 --> 00:43:59,140
+هسيب باي على 4 تربيع في بونت 8.1 تربيع
+
+336
+00:43:59,140 --> 00:44:05,440
+في دي 4 هذه
+
+337
+00:44:05,440 --> 00:44:12,500
+أم تربيع على إل إل
+
+338
+00:44:12,500 --> 00:44:23,240
+اللي هو المحيط اللي هو باي دي ال إل اللي هي point
+
+339
+00:44:23,240 --> 00:44:26,100
+9 point 9
+
+340
+00:44:30,340 --> 00:44:38,440
+باي ايش دي و ال تي اللي يقارن point 1 في point 1
+
+341
+00:44:38,440 --> 00:44:47,260
+اللي هي point 0.1 دي تربيع في ال إل أم اللي هي
+
+342
+00:44:47,260 --> 00:44:50,180
+نفس الشيء في point 9 باي
+
+343
+00:45:00,700 --> 00:45:07,460
+دي يعني واضح أن ال دي هذه 1 3 4 بيروح مع
+
+344
+00:45:07,460 --> 00:45:11,260
+هدول وعندي
+
+345
+00:45:11,260 --> 00:45:18,600
+ال باي مع
+
+346
+00:45:18,600 --> 00:45:27,360
+ال باي بصفر ثيتا تو على ال ثيتا واحد بالساوية
+
+347
+00:45:27,360 --> 00:45:28,160
+12
+
+348
+00:45:31,450 --> 00:45:41,450
+في بونت 8.1 في بونت 8.1 على 16
+
+349
+00:45:41,450 --> 00:45:54,450
+في بونت 9 في بونت 0.1 في بونت 9 يعني هاي
+
+350
+00:45:54,450 --> 00:45:57,390
+1 2 ماهيقول صح؟
+
+351
+00:46:01,480 --> 00:46:10,160
+هو عندي ال 4 فيها ال 3 ال 4 فيها ال 4
+
+352
+00:46:10,160 --> 00:46:15,520
+يعني
+
+353
+00:46:15,520 --> 00:46:20,040
+هكون تساوي 3 على 4 اللي هي point 75
+
+354
+00:46:20,040 --> 00:46:27,980
+أدرس بسط بمية والمقام على مية هيكون 75 في
+
+355
+00:46:27,980 --> 00:46:29,040
+بونت 8.1
+
+356
+00:46:32,300 --> 00:46:38,560
+بس يقول ايه يعني يعني
+
+357
+00:46:38,560 --> 00:46:48,760
+3 على 4 × 8 يعني حوالي كم 60 يعني
+
+358
+00:46:48,760 --> 00:46:53,720
+ال twist في الحالة ال open حوالي أكثر من 60 درجة
+
+359
+00:46:53,720 --> 00:46:56,960
+لنفس ال torque لنفس مستوى ال torque
+
+360
+00:47:11,670 --> 00:47:36,990
+نشوف مثال ثاني 12 
+
+361
+00:47:36,990 --> 00:47:43,520
+inch long stickstrip of steel عندي شريحة من الحديد
+
+362
+00:47:43,520 --> 00:47:51,300
+طولها 12 انش is 1/8 inch سمكها
+
+363
+00:47:51,300 --> 00:47:59,040
+1/8 انش هذا السمك والارتفاع بتاعها 1 انش
+
+364
+00:47:59,040 --> 00:47:59,960
+يعني جاي زي هيك
+
+365
+00:48:18,160 --> 00:48:23,380
+هذه 12 انش وهذه
+
+366
+00:48:23,380 --> 00:48:29,720
+1/8 انش وهذه
+
+367
+00:48:29,720 --> 00:48:40,940
+1 انش if
+
+368
+00:48:40,940 --> 00:48:43,740
+the allowable shear stress is 11,5
+
+369
+00:48:43,740 --> 00:48:45,140
+00 psi
+
+370
+00:48:47,930 --> 00:48:57,090
+شير السترس المسموح 11500 psi and the shear modulus
+
+371
+00:48:57,090 --> 00:49:04,250
+is 11.5 Megapound per square inch و ال جي 11.5
+
+372
+00:49:04,250 --> 00:49:11,830
+Megapound لكل square inch fine طبعا هذه هيكون
+
+373
+00:49:11,830 --> 00:49:12,430
+عليها ال torque
+
+374
+00:49:17,340 --> 00:49:19,580
+find the torque corresponding to the lowest shear
+
+375
+00:49:19,580 --> 00:49:24,380
+stress يعني احسب له ال torque المسموح فيه بحيث ال
+
+376
+00:49:24,380 --> 00:49:29,480
+shear stress ما يزيدش عن القيمة هذه and the angle of
+
+377
+00:49:29,480 --> 00:49:33,460
+twist in degrees using
+
+378
+00:49:33,460 --> 00:49:37,840
+equation 3.44 equation 3.7 و
+
+379
+00:49:37,840 --> 00:49:42,100
+40 اللي هي الأخيرة و equation 3.40
+
+380
+00:49:42,100 --> 00:49:44,120
+و 3.1 40 3.40 و 3.1
+
+381
+00:49:44,120 --> 00:49:45,820
+40 بتاعت في المقطع المستطيل
+
+382
+00:49:56,560 --> 00:50:03,380
+اللي هي 3.40 equation equation
+
+383
+00:50:03,380 --> 00:50:13,380
+3.40 ال tau max بالساوية
+
+384
+00:50:13,380 --> 00:50:32,200
+تي على الفا بي سي تربيع وال ثيتا هو تي في إل على بيتا 
+
+385
+00:50:32,200 --> 00:50:43,980
+بي سي تكيب جي المعادلة
+
+386
+00:50:43,980 --> 00:50:45,760
+3.7 و 40 اللي هي آخر واحدة 3.7
+
+387
+00:50:45,760 --> 00:50:51,580
+و 40 هذا
+
+388
+00:50:51,580 --> 00:50:52,840
+هعتبره open section
+
+389
+00:51:00,040 --> 00:51:11,040
+التاو بالساوية تلاتة تي على ال سي تربيع والثيتا
+
+390
+00:51:11,040 --> 00:51:14,160
+بالساوية
+
+391
+00:51:14,160 --> 00:51:23,380
+تلاتة تي على جي ال سي تكيب من هذه
+
+392
+00:51:29,640 --> 00:51:34,180
+طيب معناته هنرجع نرجع واحدة واحدة نحل اللي
+
+393
+00:51:34,180 --> 00:51:41,260
+هو باستخدام المعادلة التالية ال
+
+394
+00:51:41,260 --> 00:51:48,180
+بي على ال سي ايش يساوي؟ اللي هي 1 على 8 1
+
+395
+00:51:48,180 --> 00:51:56,760
+على 1 على 8 يعني بتساوي ايش؟ 8 من
+
+396
+00:51:56,760 --> 00:52:02,900
+الجدول هذا 1 على سي بالصورة 8 بطلق الفا و
+
+397
+00:52:02,900 --> 00:52:10,580
+بيتا ال الفا بتطلع نفس القيمة في الحالة هذه ال
+
+398
+00:52:10,580 --> 00:52:14,320
+الفا سواء
+
+399
+00:52:14,320 --> 00:52:18,940
+ال بيتا بال سابونت 3
+
+400
+00:52:18,940 --> 00:52:19,540
+107
+
+401
+00:52:27,910 --> 00:52:39,650
+ال بي عندي 1 انش وال سي 1/8 انش معناته ال torque
+
+402
+00:52:39,650 --> 00:52:53,250
+هين هيكون تساوي ال تاو الفا بي سي تربيع ال
+
+403
+00:52:53,250 --> 00:52:56,090
+تاو ما تينيها 11500
+
+404
+00:53:00,560 --> 00:53:06,780
+في ال الفا اللي هي point 307 في ال بي
+
+405
+00:53:06,780 --> 00:53:22,140
+1 في ال سي تربيع 1/8 تربيع ايش
+
+406
+00:53:22,140 --> 00:53:25,340
+هذه؟
+
+407
+00:53:25,340 --> 00:53:27,960
+ايش الوحدات؟
+
+408
+00:53:30,380 --> 00:53:39,780
+550 بونت كم 1.6 pound inch
+
+409
+00:53:39,780 --> 00:53:45,280
+هذا ال torque طيب
+
+410
+00:53:45,280 --> 00:53:50,140
+نجي الحالة هذه ال torque هتكون في حالة المعادلة
+
+411
+00:53:50,140 --> 00:53:55,920
+اللي هي الثانية هتكون تساوي 3
+
+412
+00:53:58,790 --> 00:54:07,130
+تاو إل سي تربيع يعني هتكون تساوي 3 في 11500 و
+
+413
+00:54:07,130 --> 00:54:10,950
+500 ال
+
+414
+00:54:10,950 --> 00:54:18,010
+إل اللي هو طول ال mid line اللي هو 1 انش في
+
+415
+00:54:18,010 --> 00:54:26,130
+1 على 8 تربيع كم بيطلع 99 point
+
+416
+00:54:26,130 --> 00:54:33,160
+9 و 8 99 point 99 أو
+
+417
+00:54:33,160 --> 00:54:39,160
+98 pound inch طلعوا لإن هو 2
+
+418
+00:54:39,160 --> 00:54:44,500
+mathematical models يختلفوا عن بعض ال error عند
+
+419
+00:54:44,500 --> 00:54:47,820
+ضيافة دكتورة؟ لأ أنا بحكي عن ال percentage
+
+420
+00:54:47,820 --> 00:54:51,380
+difference percentage difference بيختلف عن ال 
+
+421
+00:54:51,380 --> 00:54:54,320
+percentage error ال error ده مش هو ال error تعريفه
+
+422
+00:54:56,950 --> 00:55:01,470
+إيش تعرف ال error؟ الخطأ الخطأ
+
+423
+00:55:01,470 --> 00:55:07,070
+هو الفرق بين القيمة اللي بتحسبها أو بتقيسها ناقص 
+
+424
+00:55:07,070 --> 00:55:12,290
+الـ true value هل هذه ال true value؟ هلها true
+
+425
+00:55:12,290 --> 00:55:14,570
+value؟ هذا ال mathematical model و هذا ال
+
+426
+00:55:14,570 --> 00:55:16,690
+mathematical model لا يعبر true هذا prediction
+
+427
+00:55:16,690 --> 00:55:21,410
+فبنفعش أحكي percentage error بحكي percentage
+
+428
+00:55:21,410 --> 00:55:26,480
+difference بين الاتنين أنا بقارن هذا مع هذا الفرق
+
+429
+00:55:26,480 --> 00:55:33,500
+بينهم كذا يمكن هذا الصح و هذا الصح أو الأقرب للصح
+
+430
+00:55:33,500 --> 00:55:40,100
+نحكي ال theta هنا ال theta في حالة المعادلات هذه
+
+431
+00:55:40,100 --> 00:55:47,200
+هتكون ساوية الـ T اللي حسبتها 55.16
+
+432
+00:55:52,320 --> 00:55:58,960
+الـ l اللي هو طوله اللي هو 12 انش الـ l هنا الـ l
+
+433
+00:55:58,960 --> 00:56:04,860
+سواء 12 انش انتبهوا الـ l اللي هنا ما تعكش على
+
+434
+00:56:04,860 --> 00:56:12,100
+الطول هذا الـ l اللي هي عياش هذا الطول هتكون خمسة 
+
+435
+00:56:12,100 --> 00:56:19,120
+خمسين ومس 12 في الـ l اللي هي 12 على
+
+436
+00:56:20,720 --> 00:56:33,480
+بتا التي هي point 3.07 في B1 في C
+
+437
+00:56:33,480 --> 00:56:37,780
+تكعيب في التي هي point 1.25 التي هي
+
+438
+00:56:37,780 --> 00:56:44,540
+8 تكعيب في G ال 10
+
+439
+00:56:44,540 --> 00:56:45,000
+و نص
+
+440
+00:56:48,260 --> 00:56:54,080
+في 10 أقل سالب 10 أقل 6 ال 6 عشان أحول ال
+
+441
+00:56:54,080 --> 00:56:56,400
+degrees هضربهم في 180 على باقي في 180 على
+
+442
+00:56:56,400 --> 00:57:00,820
+180 على 
+
+443
+00:57:00,820 --> 00:57:05,780
+باقي 5 
+
+444
+00:57:05,780 --> 00:57:13,560
+upon 6 degrees حين
+
+445
+00:57:13,560 --> 00:57:19,740
+الـ 6 حلقة تانية هتكون ساوية 3 التورك أنا حسبت
+
+446
+00:57:19,740 --> 00:57:26,340
+59.89 على G 11.5
+
+447
+00:57:26,340 --> 00:57:35,320
+10 راد 6 في
+
+448
+00:57:35,320 --> 00:57:38,140
+القل اللي هي 
+
+449
+00:57:55,780 --> 00:58:07,740
+لحظة قال اللي هي 1 اللي هي عندي هين في 1 في 
+
+450
+00:58:07,740 --> 00:58:14,560
+الـ C تكعيب اللي هي point 1.25 تكعيب في
+
+451
+00:58:14,560 --> 00:58:22,320
+180 على باي سيبوا كام دجريسة طلع 
+
+452
+00:58:35,850 --> 00:58:42,130
+مين بيحسب؟ ده الحسابات المهندس ما ركنش الحسابات
+
+453
+00:58:42,130 --> 00:58:46,830
+غيره لازم تعمل إيه؟ double check نعم point 400
+
+454
+00:58:46,830 --> 00:58:52,490
+و 8 و 8 دي degrees point كام؟ 400 و
+
+455
+00:58:52,490 --> 00:58:58,090
+8 و 8 معناه
+
+456
+00:58:58,090 --> 00:59:03,270
+هذا الرقم هذا غلط هذا فيه فرق كبير هذا أنا ما حسبتش
+
+457
+00:59:03,270 --> 00:59:04,730
+طب افحص هذا 
+
+458
+00:59:21,730 --> 00:59:28,370
+بواتستا دايمًا تعتمدش إن أي شيء في الكتب صح الكتب
+
+459
+00:59:28,370 --> 00:59:31,590
+.. الكتب ممكن يكون فيها أخطاء وارد أنا كتير كشفت
+
+460
+00:59:31,590 --> 00:59:37,270
+أخطاء في كتب الـ software .. الـ software بيكون فيها
+
+461
+00:59:37,270 --> 00:59:38,850
+أخطاء برمجية بعض الأحيان
+
+462
+00:59:41,630 --> 00:59:45,870
+Autocad قديماً كان بيقرأ أكيد صلحوها إيه ممكن أنا
+
+463
+00:59:45,870 --> 00:59:49,330
+طلعت فيه 13 خطأ فيه أخطاء هذا من حوالي 20 
+
+464
+00:59:49,330 --> 00:59:58,710
+سنة تقريباً أكيد صلحوها نعم مش فاهم خلاص احسبه
+
+465
+00:59:58,710 --> 01:00:01,750
+براحتك أنت عشان ..
+
+466
+01:00:09,700 --> 01:00:14,380
+اللي نحكي عن موضوع جديد حالياً stress concentration
+
+467
+01:00:14,380 --> 01:00:31,960
+أو ما يسمى تركيز الإجهادات تركيز الإجهادات إذا 
+
+468
+01:00:31,960 --> 01:00:38,090
+بيكون في عندي تغير في المقطع أو في ثقوب بتعمل تركيز
+
+469
+01:00:38,090 --> 01:00:42,670
+للإجهادات أنا عندي هنا من باقي عندي ثقب متعرض لـ  X
+
+470
+01:00:42,670 --> 01:00:48,150
+الـ stress sigma الآن بعيد عن الثقب بيكون الـ stress
+
+471
+01:00:48,150 --> 01:00:55,090
+level high مستوى لما أصير أقترب من الثقب الـ stress
+
+472
+01:00:55,090 --> 01:01:02,250
+بيرتفع نتيجة تركيز الإجهاد فهذه sigma max وهذه نمو
+
+473
+01:01:02,250 --> 01:01:06,530
+الـ stress اللي هو الـ stress بعيدا عن الـ
+
+474
+01:01:06,530 --> 01:01:11,770
+discontinuity و ال sigma max هو الـ stress close to
+
+475
+01:01:11,770 --> 01:01:15,330
+the discontinuity هيكون بعرف الـ geometric stress
+
+476
+01:01:15,330 --> 01:01:19,590
+concentration factor كتير بالسواء sigma max على
+
+477
+01:01:19,590 --> 01:01:25,670
+sigma nominal هذه sigma nominal وهذه sigma max
+
+478
+01:01:25,670 --> 01:01:31,190
+وهذه
+
+479
+01:01:36,060 --> 01:01:38,320
+stress بتغير بالشكل هذا
+
+480
+01:01:52,430 --> 01:01:55,650
+فبعرف الـ geometric stress concentration factor أو 
+
+481
+01:01:55,650 --> 01:01:57,230
+الـ theoretical stress concentration factor
+
+482
+01:01:57,230 --> 01:02:00,670
+بالمعادلة KT بيستوى sigma max على sigma nominal هذا في 
+
+483
+01:02:00,670 --> 01:02:03,270
+حالة كان عندي اللوع من الـ stress دي في حالة shear
+
+484
+01:02:03,270 --> 01:02:09,470
+stress بسميه بحط الـ KT as shear tau max maximum
+
+485
+01:02:09,470 --> 01:02:13,330
+shear stress على الـ nominal shear stress
+
+486
+01:02:17,730 --> 01:02:23,210
+في الكتاب الـ appendix A15 و A16 بيعطوني
+
+487
+01:02:23,210 --> 01:02:26,670
+theoretical stress concentration factors ل
+
+488
+01:02:26,670 --> 01:02:30,410
+different geometries و different loading
+
+489
+01:02:30,410 --> 01:02:35,790
+conditions اللي هو appendix A15 و A16 إذا بدك شيء
+
+490
+01:02:35,790 --> 01:02:40,290
+مفصل فيه واحد اسمه petersens stress concentration
+
+491
+01:02:40,290 --> 01:02:46,380
+factor دور عليه على ال .. على ال .. على الـ net هتشوفوا
+
+492
+01:02:46,380 --> 01:02:49,080
+كتاب handbook بيعطينا كل stress concentration
+
+493
+01:02:49,080 --> 01:02:55,760
+factors أنا هنا هعرض أمثلة هاندي مثلًا هذا A15 1
+
+494
+01:02:55,760 --> 01:03:01,120
+A15
+
+495
+01:03:01,120 --> 01:03:06,440
+1 هيعرض لي 
+
+496
+01:03:06,440 --> 01:03:11,360
+اللي هو المقطع أو الـ .. الـ .. الـ member شكله
+
+497
+01:03:27,080 --> 01:03:37,600
+و في عندي هنا في 
+
+498
+01:03:37,600 --> 01:03:44,280
+ثقوب في إيش؟ ثقوب في فارس هنا F
+
+499
+01:03:47,160 --> 01:03:50,120
+في force F هند هين هيكون طبعًا في stress
+
+500
+01:03:50,120 --> 01:03:53,420
+concentration و بيعطينا الـ geometric stress
+
+501
+01:03:53,420 --> 01:03:58,040
+concentration factor على المحور طبعًا دي هاد مسميها
+
+502
+01:03:58,040 --> 01:04:05,080
+الـ W و 
+
+503
+01:04:05,080 --> 01:04:08,160
+هاد H دي قطر الثقوب 
+
+504
+01:04:15,970 --> 01:04:21,590
+عارفين نحو بعضنا بعض الطين الـ D على W D على W وهنا
+
+505
+01:04:21,590 --> 01:04:27,850
+الـ KT طبعًا
+
+506
+01:04:27,850 --> 01:04:33,350
+كل ما يصغر الـ ratio D على W بتقل كل ما الـ stress 
+
+507
+01:04:33,350 --> 01:04:34,790
+concentration effect بيزيد
+
+508
+01:04:40,700 --> 01:04:44,100
+النت إيه؟ طبعًا الـ stress الـ sigma o الـ nominal
+
+509
+01:04:44,100 --> 01:04:47,300
+stress هو كاتب لك يعني في الأنواع بتاع الـ appendix 
+
+510
+01:04:47,300 --> 01:04:54,080
+sigma o بالساعة F على A و الـ A لما نأخذ مقطع هنا
+
+511
+01:04:54,080 --> 01:05:00,480
+هيكون
+
+512
+01:05:00,480 --> 01:05:01,880
+شكل المقطع جاي زي هيك
+
+513
+01:05:18,950 --> 01:05:26,710
+يعني هذا فاضي هذا W و
+
+514
+01:05:26,710 --> 01:05:32,510
+هذا H D معناه إن الـ net area اللي فيها لحم حي اللي 
+
+515
+01:05:32,510 --> 01:05:41,510
+هي H W minus إيه؟ بيستوي الـ W هذا T W
+
+516
+01:05:41,510 --> 01:05:46,090
+minus D في T
+
+517
+01:05:54,650 --> 01:06:00,670
+حالة تانية فيها 
+
+518
+01:06:00,670 --> 01:06:05,710
+عندي shaft مدور وفيه بتغير من القطر دي capital
+
+519
+01:06:05,710 --> 01:06:09,490
+لديها small من دي capital لديها small وفيه عنده هنا
+
+520
+01:06:09,490 --> 01:06:14,430
+small fillet fillet الـ radius بتاعها آه وفيه
+
+521
+01:06:14,430 --> 01:06:18,590
+bending moment عليه فيه bending moment مش torsion
+
+522
+01:06:24,030 --> 01:06:29,330
+الـ bending moment بتعمل stress concentration الآن
+
+523
+01:06:29,330 --> 01:06:31,410
+الـ stress concentration factor اللي هو على الـ y
+
+524
+01:06:31,410 --> 01:06:38,470
+axis هذا الكتية
+
+525
+01:06:38,470 --> 01:06:47,210
+بيعتمد على الـ ratio R على D هذا الـ ratio بين مص قطر 
+
+526
+01:06:47,210 --> 01:06:54,390
+الـ fillet على القطر الصغير ومعطين different curves دي 
+
+527
+01:06:54,390 --> 01:07:01,570
+هدول كيرفات دي capital على d small يعني مثلًا هذه d
+
+528
+01:07:01,570 --> 01:07:04,350
+capital على d small 3 هذه d capital على d
+
+529
+01:07:04,350 --> 01:07:11,130
+small 1.5 هذه 1.1 هذه 1.06 هذه 1.02 معطيني different
+
+530
+01:07:11,130 --> 01:07:13,910
+curves معناه واضح الـ KT is a function معنى الـ
+
+531
+01:07:13,910 --> 01:07:18,570
+ratio R small على D small with a function also مع 
+
+532
+01:07:18,570 --> 01:07:22,400
+دي capital على دي small الـ 
+
+533
+01:07:22,400 --> 01:07:29,520
+sigma o الـ nominal stress sigma o بيستوي MC على I
+
+534
+01:07:29,520 --> 01:07:38,960
+الـ C بيستوي دي small على 2 و الـ I 1 على 
+
+535
+01:07:38,960 --> 01:07:45,940
+4 باي دي قص 4
+
+536
+01:07:45,940 --> 01:07:50,300
+على 4 قصة 
+
+537
+01:07:54,380 --> 01:08:00,000
+هذا اللي هو الـ stress عند الـ fillet بيرتفع هضرب
+
+538
+01:08:00,000 --> 01:08:10,980
+اللي هو sigma max سوى KT في sigma o
+
+539
+01:08:30,180 --> 01:08:34,560
+الآن اعتبارنا للـ stress concentration factor
+
+540
+01:08:34,560 --> 01:08:37,860
+بيعتمد على طبيعة الـ loading هل الـ loading static 
+
+541
+01:08:37,860 --> 01:08:46,340
+ثابت ولا dynamic يعني متغير و برضه بيعتمد على طبيعة
+
+542
+01:08:46,340 --> 01:08:53,160
+المادة هل المادة ductile ولا brittle يعني الـ stress 
+
+543
+01:08:53,160 --> 01:08:56,940
+اعتبار أو يعني بيكون ذو أهمية الـ stress
+
+544
+01:08:56,940 --> 01:09:01,080
+concentration اعتمادًا على نوع الـ loading سواء كان 
+
+545
+01:09:01,080 --> 01:09:05,860
+static أو dynamic loading أو اعتمادًا على نوع 
+
+546
+01:09:05,860 --> 01:09:09,800
+المادة لو كانت ductile أو brittle لأن لو كان الـ
+
+547
+01:09:09,800 --> 01:09:13,540
+loading static و المادة ductile
+
+548
+01:09:15,330 --> 01:09:20,570
+الآن الـ material ductile يعني فيها مرونة لما مثلًا
+
+549
+01:09:20,570 --> 01:09:25,350
+بعمل bending الـ outer fiber هتصير فيها إيش؟ strains
+
+550
+01:09:25,350 --> 01:09:32,110
+الـ strains بتمثل كأنها مجال .. مجال تمدد .. مجال
+
+551
+01:09:32,110 --> 01:09:38,250
+تمدد لأن الـ material مش طبقات كرتون منفصل عن بعض
+
+552
+01:09:38,250 --> 01:09:43,510
+هكون فيها إيش؟ continuity استمرارية معناه الطبقة
+
+553
+01:09:43,510 --> 01:09:51,510
+العلوية لأن المادة مرنة هتنقل .. يعني هتسي لعندي
+
+554
+01:09:51,510 --> 01:09:56,270
+انتشار للـ strain field للطبقة اللي تحتها و اللي
+
+555
+01:09:56,270 --> 01:10:01,310
+تحتها تسلم تحتها وكذا وكذا وكذا فالمادة شو تسوي؟ 
+
+556
+01:10:01,310 --> 01:10:08,690
+بتريح بتريح معناه لو دخلت منطقة الـ plastic region
+
+557
+01:10:08,690 --> 01:10:16,160
+بيصير تريح للـ stress و بالتالي بيصيرش هند ممكن أحمل
+
+558
+01:10:16,160 --> 01:10:21,560
+الـ stress concentration بمعنى لو كان عندي هنا أنا
+
+559
+01:10:21,560 --> 01:10:24,480
+الـ nominal أنا واضح إن أنا في الـ elastic range
+
+560
+01:10:24,480 --> 01:10:28,760
+مثلًا وصلت 100 ميجا باسكال لكن نتيجة الـ stress
+
+561
+01:10:28,760 --> 01:10:32,440
+كان التركيز 2/100  
+
+562
+01:10:32,440 --> 01:10:37,880
+متى معناه دخلت أنا إيش في منطقة ال plastic
+
+563
+01:10:37,880 --> 01:10:42,360
+locally due to stress concentration لما تكون المادة 
+
+564
+01:10:42,360 --> 01:10:48,420
+ductile بتحاول تخفف عن حالها بيصير تنتقل لطبع لطبع
+
+565
+01:10:48,420 --> 01:10:50,020
+لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع
+
+566
+01:10:50,020 --> 01:10:50,440
+لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع
+
+567
+01:10:50,440 --> 01:10:52,080
+لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع
+
+568
+01:10:52,080 --> 01:10:58,260
+لطبع لطبع لطبع لطبع لطبع
+
+569
+01:10:58,260 --> 01:11:04,880
+لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع
+
+570
+01:11:04,880 --> 01:11:10,760
+لطبع لطبع
+
+571
+01:11:10,760 --> 01:11:13,940
+لطبع لطبع
+
+572
+01:11:17,410 --> 01:11:25,250
+في حالة ال brittle material  بنقدرش نهمل ال stress
+
+573
+01:11:25,250 --> 01:11:27,130
+concentration ال brittle material المادة ناشفة
+
+574
+01:11:27,130 --> 01:11:32,850
+فصعب أنه .. أنه يصير انتشار لل .. لل .. لل strain
+
+575
+01:11:32,850 --> 01:11:38,710
+field من طبقة لطبقة في حالة ال dynamic loading بغض
+
+576
+01:11:38,710 --> 01:11:45,010
+النظر المادة كانت ductile and brittle لازم آخذ في
+
+577
+01:11:45,010 --> 01:11:48,030
+عين الاعتبار ال stress concentration معناه إذا
+
+578
+01:11:48,030 --> 01:11:53,530
+كانت المادة ال loading static و المادة ductile
+
+579
+01:11:53,530 --> 01:11:56,890
+ممكن أحمل ال stress concentration إذا كانت ال
+
+580
+01:11:56,890 --> 01:12:01,830
+loading static و المادة brittle مش لازم أحمله إذا 
+
+581
+01:12:01,830 --> 01:12:07,230
+كان عندي ال loading dynamic بغض النظر ال ductile
+
+582
+01:12:07,230 --> 01:12:10,130
+أو ال brittle materials لازم آخده في عين الاعتبار
+
+583
+01:12:10,130 --> 01:12:11,130
+ال stress concentration
+
+584
+01:12:17,730 --> 01:12:24,150
+طيب في techniques أو طرق ممكن أستخدمها عشان أقلل
+
+585
+01:12:24,150 --> 01:12:29,330
+من ال .. من تركيز الإجهادات ممكن أنت بنطق 
+
+586
+01:12:29,330 --> 01:12:32,990
+التغير في المقطع أكبر ال fillet يعني أنا أكون
+
+587
+01:12:32,990 --> 01:12:39,350
+fillet حادة بترفع الجهد يعني أنا عشان مثلًا أنا لو
+
+588
+01:12:39,350 --> 01:12:42,610
+بدي أحاول أكسر خشب اخبط عليها خبطة هنا ممكن
+
+589
+01:12:42,610 --> 01:12:48,690
+ماتكسرش لكن لو ما تلحظ خفيف المنشار أو سكين خبط
+
+590
+01:12:48,690 --> 01:12:53,250
+عليها إيش تكسر هي كيف انكسرت انكسرت ال stress
+
+591
+01:12:53,250 --> 01:13:00,070
+level ارتفع فدخلت على ال plastic region انكسرت ف ..
+
+592
+01:13:00,070 --> 01:13:07,610
+ان .. increase ال radius reduce disruption يعني
+
+593
+01:13:07,610 --> 01:13:15,310
+أحاول قدر اللي كان أخلي التغير تدريجي قليل allowed
+
+594
+01:13:15,310 --> 01:13:18,890
+its zones to shape flow lines more gradual لأن ال
+
+595
+01:13:18,890 --> 01:13:25,910
+strain field كأنه مجال مغناطيسي أو مجال كهربائي هو
+
+596
+01:13:25,910 --> 01:13:30,500
+ال field بالأخير بضلله ف أنا بدي أعمل بعض الحركات أو 
+
+597
+01:13:30,500 --> 01:13:34,500
+بعض ال .. ال .. ال techniques بحيث إن أخلي ال flow
+
+598
+01:13:34,500 --> 01:13:38,020
+lines ما يصيرش فيه تدفق مفاجئ إنه تكون مش هيك و
+
+599
+01:13:38,020 --> 01:13:43,100
+فجأة تعلق لأ بدي أخلي أعمل shape ال geometry بحيث
+
+600
+01:13:43,100 --> 01:13:48,940
+إن ال streamlines بتاعة ال .. ال strain fields ت
+
+601
+01:13:48,940 --> 01:13:55,740
+flow smoothly يعني لما أحكي streamlines تتذكر
+
+602
+01:13:55,740 --> 01:14:01,880
+السيارات ال air dynamic كيف الشكل ده يعني ممكن أنا 
+
+603
+01:14:01,880 --> 01:14:16,480
+أعمل سيارة بالشكل هذا الهواء
+
+604
+01:14:16,480 --> 01:14:23,280
+هييجي هيخبط زي هيك و هيحاول يرجع هنا 
+
+605
+01:14:29,930 --> 01:14:55,450
+هذه حالة صح حالة تانية هو هنير شكل السيارة الآن
+
+606
+01:14:55,450 --> 01:14:56,390
+الهواء لم يمشي
+
+607
+01:14:59,190 --> 01:15:07,530
+بنزلق بشكل smooth بشكل smooth نفس الفكرة في ال
+
+608
+01:15:07,530 --> 01:15:15,210
+strain fields بدك ال strain fields بتكون smoothly
+
+609
+01:15:15,210 --> 01:15:19,510
+oriented أو تتدفق بشكل نعم و شكل متدرج في ال
+
+610
+01:15:19,510 --> 01:15:24,800
+materialال strain fields أو ال stress fields ممكن
+
+611
+01:15:24,800 --> 01:15:27,720
+أنا أعمل finite element analysis عشان أشوف كيف ال
+
+612
+01:15:27,720 --> 01:15:32,020
+strain fields موجودة باستخدام برامج finite element
+
+613
+01:15:32,020 --> 01:15:35,600
+ممكن أطلع دورك بيعمل finite element ansys,
+
+614
+01:15:35,920 --> 01:15:39,320
+abacus, nasa, ID's في برامج كتير بتعمليهاش finite
+
+615
+01:15:39,320 --> 01:15:44,240
+element من ال techniques اللي أنا بعمل مثلًا عندي
+
+616
+01:15:44,240 --> 01:15:44,820
+hand bearings
+
+617
+01:15:48,000 --> 01:15:52,660
+في فلتن دي يعني في حفر high shaft في حفر جاهزة هيك
+
+618
+01:15:52,660 --> 01:15:56,180
+ف ال strain .. strain fields ماشية بالشكل هذا لكن
+
+619
+01:15:56,180 --> 01:16:03,500
+لو ده كانت عففة هاد ده هيصير قفزة technique
+
+620
+01:16:03,500 --> 01:16:13,120
+تاني بعمل groove بقرأ
+
+621
+01:16:13,120 --> 01:16:14,380
+تدخل ال strain fields
+
+622
+01:16:26,780 --> 01:16:29,680
+برضه هذا بيعمل ليه relief بيخلي ال strength fields
+
+623
+01:16:29,680 --> 01:16:36,320
+to move smoothly إذا حد بدى يعرف كيف تنعمل هذا أو 
+
+624
+01:16:36,320 --> 01:16:41,940
+إيش الأساس تاعته بدك تخش تطلع روح على امازون تطلع
+
+625
+01:16:41,940 --> 01:16:48,060
+على ال theory of
+
+626
+01:16:48,060 --> 01:16:54,140
+elasticity و
+
+627
+01:16:54,140 --> 01:16:54,860
+ال theory of
+
+628
+01:16:59,550 --> 01:17:03,150
+plasticity اقرأ إذا حد المعنى يعرف التفاصيل أكثر
+
+629
+01:17:03,150 --> 01:17:09,670
+طيب
+
+630
+01:17:09,670 --> 01:17:13,550
+هيك بيكون إنّهينا المحاضرة المرة الجاية بنحل
+
+631
+01:17:13,550 --> 01:17:16,430
+examples أعطيكوا العفو 
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/HcxL-em7sbY_raw.json b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/HcxL-em7sbY_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..8e9bf32fb5f5a2cb8d3622d2cd5a25d4d9f0bcd3
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/HcxL-em7sbY_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3229, "start": 5.26, "end": 32.3, "text": "بسم الله الرحمن الرحيم السلام عليكم ورحمة الله وبركاته اليوم هنكمل الشرطة ال three load and stress analysis اليوم هنبدأ نغطي ال torsion في ال thin walled tubes طبعا ال thin walled tubes قد تكون ال tubes مغلقة او مفتوحة بيبين في الحالة دي عندى closed tube عند انبوب", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 21136, 37440, 25894, 24793, 4032, 2288, 35571, 3660, 21984, 4032, 26890, 4117, 9307, 3224, 45595, 20498, 8032, 1863, 24793, 1211, 25124, 2288, 9566, 3660, 2423, 1045, 3677, 293, 4244, 5215, 45595, 20498, 8032, 1863, 44510, 10721, 8717, 17082, 9566, 1829, 2423, 3930, 82, 313, 8978, 2423, 5862, 2929, 292, 21458, 23032, 3555, 3615, 995, 2423, 5862, 2929, 292, 21458, 12174, 3215, 6055, 30544, 2423, 21458, 3714, 17082, 1211, 28671, 1975, 2407, 3714, 5172, 2655, 2407, 5016, 3660, 4724, 1829, 3555, 9957, 8978, 21542, 6027, 3660, 11778, 1829, 43242, 7578, 5395, 9917, 43242, 16472, 3555, 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ثابت لو أخدنا element احنا الزاوية هذه دي ثيتا وهذا radius R", "tokens": [3615, 23942, 314, 6156, 2407, 46958, 5016, 16472, 314, 34051, 8978, 314, 7251, 3794, 995, 45865, 38637, 16758, 2655, 45164, 5551, 9778, 3215, 8315, 4478, 1975, 5016, 8315, 6024, 110, 995, 2407, 10632, 29538, 11778, 1829, 38637, 36081, 995, 37037, 15730, 15845, 497], "avg_logprob": -0.36718748577616434, "compression_ratio": 1.1885245901639345, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 186.53, "end": 187.11, "word": "على", "probability": 0.89208984375}, {"start": 187.11, "end": 188.63, "word": " T", "probability": 0.52978515625}, {"start": 188.63, "end": 191.43, "word": " فواضح", "probability": 0.91064453125}, {"start": 191.43, "end": 191.69, "word": " ان", "probability": 0.67626953125}, {"start": 191.69, "end": 192.15, "word": " T", "probability": 0.51025390625}, {"start": 192.15, "end": 192.33, "word": " أو", "probability": 0.2479248046875}, {"start": 192.33, "end": 192.47, "word": " في", 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باي على اربع في bond تمانية يعني هسيب باي على اربع تربية في bond تمانية واحد", "tokens": [40228, 22653, 8032, 1829, 3794, 995, 45865, 1975, 2655, 1863, 33599, 1975, 4587, 2304, 13672, 1829, 39896, 4724, 47302, 15844, 1975, 25513, 3615, 8978, 6086, 46811, 7649, 10632, 37495, 22653, 8032, 3794, 1829, 3555, 4724, 47302, 15844, 1975, 25513, 3615, 6055, 2288, 21292, 3660, 8978, 6086, 46811, 7649, 10632, 36764, 24401], "avg_logprob": -0.2575120066220944, "compression_ratio": 1.7428571428571429, "no_speech_prob": 0.0, "words": [{"start": 2609.99, "end": 2610.49, "word": "يعني", "probability": 0.91015625}, {"start": 2610.49, "end": 2611.43, "word": " هيساوي", "probability": 0.706982421875}, {"start": 2611.43, "end": 2614.23, "word": " اتناش", "probability": 0.8021240234375}, {"start": 2614.23, "end": 2617.19, "word": " اقم", "probability": 0.85400390625}, {"start": 2617.19, "end": 2619.27, "word": " اللي", "probability": 0.77197265625}, {"start": 2619.27, "end": 2619.47, "word": " هي", 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/HcxL-em7sbY_raw.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/HcxL-em7sbY_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f0227bbc918d967196619d435c14ee64429e109b
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/HcxL-em7sbY_raw.srt
@@ -0,0 +1,2528 @@
+1
+00:00:05,260 --> 00:00:08,120
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,120 --> 00:00:12,640
+وبركاته اليوم هنكمل الشرطة ال three load and
+
+3
+00:00:12,640 --> 00:00:17,440
+stress analysis اليوم هنبدأ نغطي ال torsion في ال
+
+4
+00:00:17,440 --> 00:00:22,280
+thin walled tubes طبعا
+
+5
+00:00:22,280 --> 00:00:26,400
+ال thin walled tubes قد تكون ال tubes مغلقة او
+
+6
+00:00:26,400 --> 00:00:31,740
+مفتوحة بيبين في الحالة دي عندى closed tube عند
+
+7
+00:00:31,740 --> 00:00:32,300
+انبوب
+
+8
+00:00:34,830 --> 00:00:43,050
+و في عليها torque نتيجة ال torque لو أخدت المقطع
+
+9
+00:00:43,050 --> 00:00:51,170
+هصير
+
+10
+00:00:51,170 --> 00:00:55,130
+عندى shear stress
+
+11
+00:01:20,510 --> 00:01:31,850
+تاو التاوباكس هتكون ساوية ت في ر على ج لحظة و انا
+
+12
+00:01:31,850 --> 00:01:40,630
+اقعد في المنطقة فادي طبعا هذا هيكون مش موجود لانه
+
+13
+00:01:40,630 --> 00:01:41,650
+مش material صح؟
+
+14
+00:02:10,410 --> 00:02:18,010
+هذا thickness دي كل
+
+15
+00:02:18,010 --> 00:02:23,130
+ما قل thickness كل ما بتكون بتتجه في ارتفاع اللي
+
+16
+00:02:23,130 --> 00:02:29,930
+هو إيش ال tau كل ما بيقل ال thickness بتظهر هذه ال
+
+17
+00:02:29,930 --> 00:02:38,870
+tau أشمالها بتزيد ال tau على اللحم الحي هتزيدمعناه
+
+18
+00:02:38,870 --> 00:02:42,930
+ان هناك علاقة عكسية بين ال tau و ال thickness ال T
+
+19
+00:02:42,930 --> 00:02:49,170
+لان الحالة اللى كل مرة تقل ال T بزيد ال tau
+
+20
+00:02:49,170 --> 00:02:57,650
+المفروض يعني ال tau T بيساوي constant لان
+
+21
+00:02:57,650 --> 00:03:01,670
+ال tau تتناسى و تتناسى و عكسي مع ال T يعني ال tau
+
+22
+00:03:01,670 --> 00:03:04,810
+هتكون تساوي constant
+
+23
+00:03:06,530 --> 00:03:18,010
+على T فواضح ان T أو في T يساوي ثابت لو أخدنا
+
+24
+00:03:18,010 --> 00:03:22,530
+element احنا
+
+25
+00:03:22,530 --> 00:03:28,410
+الزاوية هذه دي
+
+26
+00:03:28,410 --> 00:03:40,160
+ثيتا وهذا radius Rهذا الطول هيكون DS وفي شير استرس
+
+27
+00:03:40,160 --> 00:03:45,520
+قيمته تقريبا
+
+28
+00:03:45,520 --> 00:03:56,960
+ال
+
+29
+00:03:56,960 --> 00:03:56,960
+torque
+
+30
+00:04:04,550 --> 00:04:07,150
+طبعا نتيجة shear stress هسير عنده force tangential
+
+31
+00:04:07,150 --> 00:04:14,590
+force DF DF هتكون
+
+32
+00:04:14,590 --> 00:04:18,030
+ال
+
+33
+00:04:18,030 --> 00:04:25,590
+shear stress هتكون tau في T في DS
+
+34
+00:04:33,170 --> 00:04:45,650
+الان دي تورك ر دي اف يعني هكون تاو ت في ر دي اس
+
+35
+00:04:45,650 --> 00:04:55,730
+معناه التور هكون تكامل تاو ت
+
+36
+00:04:55,730 --> 00:05:00,150
+في ر دي اس
+
+37
+00:05:06,650 --> 00:05:11,930
+الـ tau t اشملها constant تطلع برا كلها مع بعض
+
+38
+00:05:11,930 --> 00:05:19,430
+فهذا الشيء اللي عندي tau t تكامل rds
+
+39
+00:05:19,430 --> 00:05:28,830
+من في الحالة هذه من صفر لاتنين by لحظة
+
+40
+00:05:28,830 --> 00:05:30,430
+لو أخدت المثلثة ده
+
+41
+00:05:38,710 --> 00:05:46,830
+مساحته مش هتكون مساحته نص
+
+42
+00:05:46,830 --> 00:05:51,130
+القاعد فى ارتفاع نص DS ولأن ال D تتصغير كتير هتكون
+
+43
+00:05:51,130 --> 00:06:05,330
+فى ال R هتساوي نص ال R نص ال R DS نص ال R DS
+
+44
+00:06:07,690 --> 00:06:12,850
+معناته اتنين دي
+
+45
+00:06:12,850 --> 00:06:20,190
+اقم بالساوية rds معناته ده ال term مش الساوية لما
+
+46
+00:06:20,190 --> 00:06:25,870
+اعمل integration معناته اتنين
+
+47
+00:06:25,870 --> 00:06:29,110
+اقم
+
+48
+00:06:29,110 --> 00:06:37,050
+بالساوية تكامل rdsام لان هذه مثلثات اجمع اجمعها
+
+49
+00:06:37,050 --> 00:06:43,290
+مثلثات هاخد مساحة الدقرة هذه صح فهتصفى
+
+50
+00:06:43,290 --> 00:06:53,750
+ال torque الساوية تاو T في اتنين ام منها بحسب
+
+51
+00:06:56,330 --> 00:07:09,350
+شيريسترستاو T على اتنين T AM ليه
+
+52
+00:07:09,350 --> 00:07:17,810
+المعادلة هذه طبعا
+
+53
+00:07:17,810 --> 00:07:24,040
+ال AMهي ال area enclosed by the section median
+
+54
+00:07:24,040 --> 00:07:27,820
+line section median line اللي هو هذا هذا ال median
+
+55
+00:07:27,820 --> 00:07:35,840
+line ال
+
+56
+00:07:35,840 --> 00:07:44,100
+angle twist في ال .. في ال tube هيكون T في LM على
+
+57
+00:07:44,100 --> 00:07:51,450
+أربع GAM تربيتيهو طول ال media line طول ال media
+
+58
+00:07:51,450 --> 00:07:56,250
+line في حالة الدائرة طول ال media line بيكون محيط
+
+59
+00:07:56,250 --> 00:08:03,110
+الدائرة صح نشوف
+
+60
+00:08:03,110 --> 00:08:09,030
+مثال اول steel tube is forty inch long في عنده
+
+61
+00:08:09,030 --> 00:08:15,770
+steel tube طولها اربعين انش ال tube شكلها مستطيل
+
+62
+00:08:16,600 --> 00:08:21,200
+بالطول تاعها اربعين انش المقطع اتنين و نص انش في
+
+63
+00:08:21,200 --> 00:08:30,420
+تلاتة ستة و عشرة انش بسماكة تم الانش assume
+
+64
+00:08:30,420 --> 00:08:37,680
+allowable share stress ال share stress المسموح فيه
+
+65
+00:08:37,680 --> 00:08:44,600
+بسوء احداشر و نص كيلو pound لكل
+
+66
+00:08:44,600 --> 00:08:54,600
+انش مربعوالشير موديلس جيه بس واحداشر و نص ميجا
+
+67
+00:08:54,600 --> 00:09:01,540
+باوند per square inch estimate
+
+68
+00:09:01,540 --> 00:09:08,160
+allowable torque احسب T allowable
+
+69
+00:09:08,160 --> 00:09:13,500
+عند
+
+70
+00:09:13,500 --> 00:09:18,560
+المقطع طبعا هذه انبعي بنفرجمعناته هتكون دي
+
+71
+00:09:18,560 --> 00:09:26,120
+المعادلة اللي هي tau بساوية
+
+72
+00:09:26,120 --> 00:09:37,260
+T على اتنين AM في T و ال theta بساوية
+
+73
+00:09:37,260 --> 00:09:55,610
+T ال M على اربعة G AMتربية فى T احنا
+
+74
+00:09:55,610 --> 00:09:59,430
+بدنا نحسب ايه؟ ال torque فلوقت ال torque اللي هو
+
+75
+00:09:59,430 --> 00:10:11,070
+bolt torque هكون اتنين tau am فى T ال T عندنا
+
+76
+00:10:11,070 --> 00:10:17,200
+معروف thickness اللي هو اكم8 انش يعني point واحد
+
+77
+00:10:17,200 --> 00:10:21,140
+تمانية
+
+78
+00:10:21,140 --> 00:10:25,800
+انش و التعب عطيني افتتاح و نص كيلو pound per
+
+79
+00:10:25,800 --> 00:10:31,640
+square inch بتضلي ال AM ال AM هي المستطيلة عندى
+
+80
+00:10:42,080 --> 00:11:01,920
+السيقشن media line هو هذا هذا
+
+81
+00:11:01,920 --> 00:11:09,620
+أكمل طوله تلاتة بونت ستة هذا هكون تلاتة بونت ستة
+
+82
+00:11:09,620 --> 00:11:14,120
+معقص تمانهي واحدة ستة عشر هنا و واحدة ستة عشر هنا
+
+83
+00:11:14,120 --> 00:11:25,380
+صح هتكون يعني تلاتة point ستة ناقص point واحد
+
+84
+00:11:25,380 --> 00:11:33,240
+اتنين خمسة هيطلع
+
+85
+00:11:33,240 --> 00:11:38,960
+تلاتة point اربعة سبعة
+
+86
+00:11:40,580 --> 00:11:53,720
+خمسة مظبوط زي هيك والطول
+
+87
+00:11:53,720 --> 00:11:58,880
+هذا هذا
+
+88
+00:11:58,880 --> 00:12:04,880
+كله نص هذا
+
+89
+00:12:04,880 --> 00:12:05,300
+هكون
+
+90
+00:12:08,320 --> 00:12:12,140
+نمص ناطس point واحد اتنين خمسة هتكون اتنين point
+
+91
+00:12:12,140 --> 00:12:24,940
+تلاتة سبعة خمسة صح؟
+
+92
+00:12:24,940 --> 00:12:28,560
+معناته
+
+93
+00:12:28,560 --> 00:12:33,220
+ال AM مش هتساوي هتكون
+
+94
+00:12:33,220 --> 00:12:37,430
+تساوي طول ال media line في الارتفاع المستطيلهتكون
+
+95
+00:12:37,430 --> 00:12:44,370
+الساوية تلاتة point أربع سبعة خمسة في اتنين point
+
+96
+00:12:44,370 --> 00:12:52,930
+تلاتة سبعة خمسة هذا ال AM تمانية
+
+97
+00:12:52,930 --> 00:12:59,290
+وال
+
+98
+00:12:59,290 --> 00:12:59,650
+LM
+
+99
+00:13:03,020 --> 00:13:08,080
+هيكون هذا الطول زاد هذا زاد هذا زاد هذا بالظبط
+
+100
+00:13:08,080 --> 00:13:13,800
+يعني عندك اتنين تلاتة point أربع سبعة خمسة زاد
+
+101
+00:13:13,800 --> 00:13:20,140
+اتنين point تلاتة سبعة خمسة في اتنين عاكم تلعب
+
+102
+00:13:20,140 --> 00:13:24,040
+اتناش point اتناش
+
+103
+00:13:24,040 --> 00:13:30,200
+point اكتر احداش
+
+104
+00:13:30,200 --> 00:13:30,820
+point سبعة
+
+105
+00:13:43,090 --> 00:13:50,390
+معناة ال tour هيكون ساوية اتنين ال tau احداشر الف
+
+106
+00:13:50,390 --> 00:13:54,810
+و خمسمية في
+
+107
+00:13:54,810 --> 00:13:58,350
+ال am تمانية
+
+108
+00:13:58,350 --> 00:14:05,850
+point اتنين خمسة تلاتة في ال thickness واحد على
+
+109
+00:14:05,850 --> 00:14:06,370
+تمانية
+
+110
+00:14:22,350 --> 00:14:31,130
+أه احنا اشتقنا المعادلة احنا
+
+111
+00:14:31,130 --> 00:14:41,230
+اشتقناها لحالة مقطع مفرغ ودائر وأعملنا
+
+112
+00:14:41,230 --> 00:14:48,360
+الحالة اللي عند المقطع مش مدور المقطع أشمالهمستطيل
+
+113
+00:14:48,360 --> 00:14:52,820
+لما عملت اشتقاق المعدلات على مدور ف ال definitions
+
+114
+00:14:52,820 --> 00:14:58,000
+still apply يعني لما حكيت في المقطع المدور حكيت
+
+115
+00:14:58,000 --> 00:15:05,080
+اللي هو ال EM مساحة الدائرة المتوسطة في النبوب
+
+116
+00:15:05,080 --> 00:15:10,020
+بالظبط نفس الاشي في حالة مقطع مستطيل اي مقطع تاني
+
+117
+00:15:10,020 --> 00:15:11,240
+لو كانت ده مقطع زي هيك
+
+118
+00:15:17,480 --> 00:15:23,140
+الـ thickness زي هيك ال media line تتعامل مع ال
+
+119
+00:15:23,140 --> 00:15:31,420
+media line برضه تتعامل معاش ال media line بحث
+
+120
+00:15:31,420 --> 00:15:34,920
+ال area اللي داخله داخل ال media line بغض النقطة
+
+121
+00:15:34,920 --> 00:15:40,340
+المقطعة نقطة نقطة تلاتة و عشرين الف تلاتة و عشرين
+
+122
+00:15:40,340 --> 00:15:40,720
+الف
+
+123
+00:15:53,010 --> 00:15:56,670
+Pound هذا ال allow ال torque يعني هذا العزم
+
+124
+00:15:56,670 --> 00:16:01,430
+المسموح فيه تلاتة و عشرين ألف سبعمائة و سبعة و
+
+125
+00:16:01,430 --> 00:16:08,870
+عشرين pound لو دي حسب ال angle twist theta theta
+
+126
+00:16:08,870 --> 00:16:13,410
+بتساوي اللي هو ال torque اللي هو تلاتة و عشرين ألف
+
+127
+00:16:13,410 --> 00:16:28,300
+سبعمائة و سبعة و عشرينفي ال L M في 11.7 على 4 G 11
+
+128
+00:16:28,300 --> 00:16:38,260
+.5 في 10 عقل 6 عشان نحو ال PSI في ال A M تربيع في
+
+129
+00:16:38,260 --> 00:16:47,140
+8.253 تربيع في ال thickness اللي هو point 125 اللي
+
+130
+00:16:47,140 --> 00:17:08,890
+هو تمانبتطلع تلت أسفار بال radians 0
+
+131
+00:17:08,890 --> 00:17:14,310
+.0007
+
+132
+00:17:14,310 --> 00:17:18,050
+radians
+
+133
+00:17:20,640 --> 00:17:24,660
+يعني لو ده حوالي ال degrees هضروه في مية و تمانين
+
+134
+00:17:24,660 --> 00:17:42,780
+علباء ضروه في مية و تمانين علباء بيطلع
+
+135
+00:17:42,780 --> 00:17:46,900
+point four zero zero أربعة
+
+136
+00:17:50,400 --> 00:17:58,720
+zero four degrees
+
+137
+00:17:58,720 --> 00:18:05,240
+يعني
+
+138
+00:18:05,240 --> 00:18:08,880
+اقسم واحد على point zero اربعة واحد على point zero
+
+139
+00:18:08,880 --> 00:18:13,780
+اربعة يعني واحد على خمس عشرين دي ال degree صح؟
+
+140
+00:18:16,080 --> 00:18:18,900
+تطلع واحد على خمس وعشرين يعني ال degree الدرجة
+
+141
+00:18:18,900 --> 00:18:27,120
+اقسمها خمس وعشرين تقسيمها في
+
+142
+00:18:27,120 --> 00:18:35,180
+اي سؤال شوف مثال تاني compare
+
+143
+00:18:45,710 --> 00:18:48,770
+Compare the shear stress on a circular cylindrical
+
+144
+00:18:48,770 --> 00:18:54,490
+tube في عندى انبوب مقطعها أسطوانة with an outside
+
+145
+00:18:54,490 --> 00:18:58,030
+diameter of one inch القطر الخارج بتاعها هذا ال
+
+146
+00:18:58,030 --> 00:19:06,050
+tube اللي قطر خارجه اللي
+
+147
+00:19:06,050 --> 00:19:09,730
+قطر داخله القطر الخارج بتاعها واحد انش
+
+148
+00:19:19,900 --> 00:19:36,720
+واحد انش والقطر الداخلي تسعة و عشرة انش بنحسب
+
+149
+00:19:36,720 --> 00:19:43,600
+ال shear stress tau في
+
+150
+00:19:43,600 --> 00:19:48,440
+حال استخدمت equation تلاتة
+
+151
+00:19:48,440 --> 00:19:56,410
+سبعة و تلاتينو مرة في حالة باستخدام equation تلاتة
+
+152
+00:19:56,410 --> 00:20:02,110
+خمسة واربعين equation تلاتة خمسة واربعين اللي هي
+
+153
+00:20:02,110 --> 00:20:07,890
+أخر واحدة اقولها اللي
+
+154
+00:20:07,890 --> 00:20:14,770
+هي هذه تلاتة
+
+155
+00:20:14,770 --> 00:20:21,680
+سوة تلاتين ال Tao سوة T Tao max Tao R على Jهذه
+
+156
+00:20:21,680 --> 00:20:36,420
+تلاتة سبعة و تلاتين و Tao بالساوية T على اتنين AMT
+
+157
+00:20:36,420 --> 00:20:39,600
+اللي هي التلاتة خمسة واربعين
+
+158
+00:20:52,800 --> 00:21:02,120
+طبعا لنفس ال torque لنفس ال torque طيب اولا
+
+159
+00:21:02,120 --> 00:21:05,800
+شوف نحسب ال end ال radius ال shear distance هيكون
+
+160
+00:21:05,800 --> 00:21:08,720
+maximum على ال outer fiber هيكون maximum هنا صح
+
+161
+00:21:08,720 --> 00:21:16,440
+التاو هتكون تاو maximum هتكون سوى تاو ال T في R
+
+162
+00:21:16,440 --> 00:21:18,720
+على J معناته ال R بتساوي
+
+163
+00:21:21,990 --> 00:21:31,330
+هيكون الشير السترس عند هنا ال maximum هي
+
+164
+00:21:31,330 --> 00:21:38,690
+كتار زيت الشير السترس هذه ال tau max وهذه
+
+165
+00:21:38,690 --> 00:21:45,110
+ال tau minimum نحسب
+
+166
+00:21:45,110 --> 00:21:48,570
+ال J ال J ال pole moment of inertia يعني عندي
+
+167
+00:21:48,570 --> 00:21:58,960
+عبارة عندائرتين صح؟ هتكون باي على اتنين وتلاتين في
+
+168
+00:21:58,960 --> 00:22:04,440
+القطر الخارجي اللي هو واحد قص أربعة ناقص تسعة و
+
+169
+00:22:04,440 --> 00:22:12,530
+نعشرة قص أربعة حسبولي الجهةيعني point 8 1 في point
+
+170
+00:22:12,530 --> 00:22:19,930
+8 1 يعني هتكون point 1 9 في point 1 1 و point 1 9
+
+171
+00:22:19,930 --> 00:22:25,210
+في point 1 9 تطلع point O تلاتة ستة تلاتة تسعة
+
+172
+00:22:25,210 --> 00:22:28,310
+أربعة زي ايه Zero point zero تلاتة تلاتة Zero
+
+173
+00:22:28,310 --> 00:22:34,350
+point zero three three درست
+
+174
+00:22:34,350 --> 00:22:36,450
+في بقعة تنين تلاتين بقعة تنين تلاتين
+
+175
+00:22:43,460 --> 00:23:06,160
+0.03×32 هذا الجهاز احسبها كم المرة 0
+
+176
+00:23:06,160 --> 00:23:08,480
+.34×32
+
+177
+00:23:09,500 --> 00:23:12,820
+يحسب ليها كامل اضروبها بعدين تلاتين اضربها اضربها
+
+178
+00:23:12,820 --> 00:23:17,060
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+179
+00:23:17,060 --> 00:23:17,160
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+180
+00:23:17,160 --> 00:23:17,360
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+181
+00:23:17,360 --> 00:23:18,560
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+182
+00:23:18,560 --> 00:23:18,680
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+183
+00:23:18,680 --> 00:23:19,580
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+184
+00:23:19,580 --> 00:23:26,300
+اضربها اضربها اضربها اضربها اضربها اضربها اضربها
+
+185
+00:23:26,300 --> 00:23:26,360
+ا
+
+186
+00:23:37,040 --> 00:23:45,520
+اللي هو واحد ناقص point تسعة على اتنين point zero
+
+187
+00:23:45,520 --> 00:24:00,420
+خمسة انش ال medium circle اللي في النصي
+
+188
+00:24:00,420 --> 00:24:05,220
+دي medium هتكون
+
+189
+00:24:05,220 --> 00:24:15,490
+سوى واحدناقص point one ناقص point zero
+
+190
+00:24:15,490 --> 00:24:20,870
+five يعني هتكون point تسعة خمسة انش
+
+191
+00:24:29,310 --> 00:24:37,070
+بالساوية باي على أربعة DM تربيع يعني باي على أربعة
+
+192
+00:24:37,070 --> 00:24:50,450
+في ال DM اللي هي في point ساعة خمسة تربيع كام؟
+
+193
+00:24:50,450 --> 00:24:55,150
+Zero point Zero point كم يعني اعطيه ليه كمان
+
+194
+00:24:55,150 --> 00:25:09,390
+رقمين؟0.708 كم الرقم؟ تمانيتين انش تربيع
+
+195
+00:25:09,390 --> 00:25:20,630
+هذا الام هذا
+
+196
+00:25:20,630 --> 00:25:27,800
+كم؟ واحد انش وهذا كم؟لما اطرح واحد ناقصها ناشرة
+
+197
+00:25:27,800 --> 00:25:34,620
+بيعطينا هادي زائد هادي على الجهتين صح؟ لما اطرح
+
+198
+00:25:34,620 --> 00:25:37,280
+هذا الطول هذا الطول من هذا الطول بيعطينا هادي زائد
+
+199
+00:25:37,280 --> 00:25:45,700
+هادي اللي هو اتنين ال T مش هي القسم ده اتنين طيب
+
+200
+00:25:45,700 --> 00:25:48,020
+الان
+
+201
+00:25:50,760 --> 00:25:59,280
+باستخدام واحد equation تلاتة سبعة و تلاتين ال tau
+
+202
+00:25:59,280 --> 00:26:04,400
+max هتكون اللي
+
+203
+00:26:04,400 --> 00:26:12,520
+هو ال T في ال R اللي هو نص انش على
+
+204
+00:26:12,520 --> 00:26:18,900
+ال LJ اللي هو point O تلاتة تلاتة
+
+205
+00:26:24,110 --> 00:26:31,810
+حسبوها و ال tau minimum هتكون
+
+206
+00:26:31,810 --> 00:26:36,050
+سوى tau max على
+
+207
+00:26:36,050 --> 00:26:40,390
+bond خمسة في bond أربعة خمسة
+
+208
+00:26:45,200 --> 00:26:51,840
+فاكروا كيف انا عملت هذه براحتكوا يعنى الان تاومن
+
+209
+00:26:51,840 --> 00:26:54,740
+.. تاومن على bond .. يعني نفس المعادلة بس قسمت على
+
+210
+00:26:54,740 --> 00:27:00,080
+bond فاردرت bond أبقى خمسة هاي اللي صار حسبوا
+
+211
+00:27:00,080 --> 00:27:03,360
+الأولى
+
+212
+00:27:03,360 --> 00:27:07,680
+خمستاش
+
+213
+00:27:07,680 --> 00:27:11,460
+.. خمستاش
+
+214
+00:27:11,460 --> 00:27:14,040
+ال T هذه
+
+215
+00:27:19,020 --> 00:27:25,680
+تلاتين point تلاتة في point أربعة و خمسة أكمل
+
+216
+00:27:25,680 --> 00:27:32,740
+كلها كاملة تلاتة
+
+217
+00:27:32,740 --> 00:27:39,360
+عشر point تلاتة و ستين تي معناه في ال T mean ال T
+
+218
+00:27:39,360 --> 00:27:45,860
+average هتكون تاو average هتكون تساوي تاو max زائد
+
+219
+00:27:45,860 --> 00:27:51,500
+تاو مين و عتنين تاو averageهتكون خمستاش point
+
+220
+00:27:51,500 --> 00:28:00,960
+خمستاش زائد تلاتاش point ستة تلاتة على اتنين في
+
+221
+00:28:00,960 --> 00:28:04,780
+ال
+
+222
+00:28:04,780 --> 00:28:13,500
+T لأن
+
+223
+00:28:13,500 --> 00:28:14,480
+باستخدام equation
+
+224
+00:28:18,050 --> 00:28:27,610
+تلاتة خمسة وأربعين هتكون التاو بالساوية
+
+225
+00:28:27,610 --> 00:28:38,030
+T على اتنين AM في T هساوية
+
+226
+00:28:38,030 --> 00:28:46,790
+T على AM احنا حسبنا AM اللي هي point سبعةسفر
+
+227
+00:28:46,790 --> 00:28:54,890
+تمانية تمانية و ال thickness اللي هو point O خمسة
+
+228
+00:28:54,890 --> 00:29:11,170
+خلط
+
+229
+00:29:11,170 --> 00:29:26,570
+غلط يعني هدول غلطيا دوة غلط هي فيه اتنين على
+
+230
+00:29:26,570 --> 00:29:33,430
+اتنين بتطلع على صح اربعتاش point كم الرقم T
+
+231
+00:29:44,680 --> 00:29:50,200
+يعني اذا اعتبرت هذا ال reference هكون الاختلاف
+
+232
+00:29:50,200 --> 00:29:58,380
+percentage difference ساوي
+
+233
+00:29:58,380 --> 00:30:06,900
+14.39T-14.08T
+
+234
+00:30:08,880 --> 00:30:17,680
+على اربع تاش point تسعة تلاتين T في مية هتروح ال T
+
+235
+00:30:17,680 --> 00:30:22,860
+مع بعض سابل
+
+236
+00:30:22,860 --> 00:30:27,000
+ال اربع تاش point تسعة تلاتين مانقص اربع تاش point
+
+237
+00:30:27,000 --> 00:30:32,380
+تسعة تلاتين يعني هتكون point واحد تلاتين على اربع
+
+238
+00:30:32,380 --> 00:30:33,760
+تاش point تسعة تلاتين في مية
+
+239
+00:30:42,710 --> 00:30:45,430
+بدي أحسبه سريع إذا رقم ذاك بتاخد فيه دقيقة وفوت
+
+240
+00:30:45,430 --> 00:30:50,030
+شفه و طلعه ال
+
+241
+00:30:50,030 --> 00:30:56,790
+personal
+
+242
+00:30:56,790 --> 00:31:02,610
+difference اتنين في المية يعني الفرق قليل كتير
+
+243
+00:31:02,610 --> 00:31:10,090
+نكمل
+
+244
+00:31:24,940 --> 00:31:28,340
+الان في حالة open thin wall sections إذا عندي
+
+245
+00:31:28,340 --> 00:31:35,920
+الإنبوبة زي هذه مش مسكرة فيها فتحة تتوقع تكون أقوى
+
+246
+00:31:35,920 --> 00:31:42,100
+ولا أضعف؟ هتكون أضعف أكيد يعني مش هتشيل torque زي
+
+247
+00:31:42,100 --> 00:31:43,740
+لو كانت مغلقة
+
+248
+00:31:47,500 --> 00:31:52,120
+في الحالة دي لما هذا ال media line media line مش
+
+249
+00:31:52,120 --> 00:31:58,060
+مغلق بسميه open thin section عند مستطيل ممكن
+
+250
+00:31:58,060 --> 00:32:03,820
+اعتبره مستطيل واستخدم معادلات السابقة ارتبه مقطع
+
+251
+00:32:03,820 --> 00:32:11,100
+مفتوح مش مغلق عند ال c shape هذا open مش مسكر ال
+
+252
+00:32:11,100 --> 00:32:16,700
+media line ال L shapeبرضه open ال z shape برضه ايه
+
+253
+00:32:16,700 --> 00:32:23,640
+عشان open ال torque نفس الشيء ال stress بتاعه سواء
+
+254
+00:32:23,640 --> 00:32:32,240
+تلاتة T على L C تربيع ال T هو ال applied torqueالـ
+
+255
+00:32:32,240 --> 00:32:37,360
+L طول ال media line يعني هذا هذا هو ال L هذا الطول
+
+256
+00:32:37,360 --> 00:32:42,060
+هذا كله هذا L هذا مع هذا مع هذا L هذا مع هذا L هذا
+
+257
+00:32:42,060 --> 00:32:48,280
+مع هذا مع هذا L ال C اللي هو ال thickness هذا ال C
+
+258
+00:32:48,280 --> 00:32:55,700
+هذا ال C هذا ال C هذا ال C هذا ال C ال .. و ال G
+
+259
+00:32:55,700 --> 00:32:58,900
+اللي هي ال modulus of rigidity او shear modulus
+
+260
+00:33:10,070 --> 00:33:13,810
+for small wall thickness stress and twist can
+
+261
+00:33:13,810 --> 00:33:18,150
+become quite large بالمقارنة معاياش لو كان المقطع
+
+262
+00:33:18,150 --> 00:33:22,810
+مغلق يعني لما يكون المقطع مش مغلق مفتوح ال share
+
+263
+00:33:22,810 --> 00:33:28,910
+stress و الزاوية اللي هيزداد بشكل كبير خلنا نعمل
+
+264
+00:33:28,910 --> 00:33:33,590
+مقارنة في عندي compare this round tube with and
+
+265
+00:33:33,590 --> 00:33:36,330
+without slit يعني في عندي هنا نبوب
+
+266
+00:33:41,130 --> 00:33:46,550
+بدنا نعمل دراسة الأول إنها مغلقة الحالة التانية مش
+
+267
+00:33:46,550 --> 00:33:52,410
+مغلقة ratio of wall thickness to outside diameter
+
+268
+00:33:52,410 --> 00:34:03,290
+of point one يعني هذا هو ال wall thickness وهذا
+
+269
+00:34:03,290 --> 00:34:08,570
+ish ال outside diameter لأن دي T على ال outside
+
+270
+00:34:08,570 --> 00:34:18,720
+diameterبساوي point one فى حال لو كانت مغلقة نرجع
+
+271
+00:34:18,720 --> 00:34:24,940
+لعيش للمعادة ال tao اش يساوي فى حال نحكي هنا and
+
+272
+00:34:24,940 --> 00:34:29,980
+closed و
+
+273
+00:34:29,980 --> 00:34:40,060
+and اش open بيكون ال tao بيساوي T على اتنين اقم
+
+274
+00:35:08,410 --> 00:35:10,910
+طيب ال A أهم مش الساوي
+
+275
+00:35:14,690 --> 00:35:31,430
+by على أربعة أنا عندي هاي الدائرة ها
+
+276
+00:35:31,430 --> 00:35:38,910
+دي ال DM ال DM شو يساوي
+
+277
+00:35:43,870 --> 00:35:47,830
+بساوي ال D ناقص
+
+278
+00:35:47,830 --> 00:35:57,510
+ال T بساوي ال D ال T اللي هي عشان ساوي عشر ال D صح
+
+279
+00:35:57,510 --> 00:36:06,390
+يعني هتكون ساوي point nine ال D باي على أربع DM
+
+280
+00:36:06,390 --> 00:36:15,850
+تربيع يعني باي على أربعفى point nine تسعة دى لكل
+
+281
+00:36:15,850 --> 00:36:26,870
+تربيع يعنى هتكون باي على أربع فى point تمانية واحد
+
+282
+00:36:26,870 --> 00:36:31,590
+دى تربيع يعنى
+
+283
+00:36:31,590 --> 00:36:40,050
+شيريسترس تاو هكون تاو تى على اتنين فى باي على أربع
+
+284
+00:36:42,730 --> 00:36:51,030
+في point تمانية واحد ادي تربيع وال thickness اللي
+
+285
+00:36:51,030 --> 00:36:57,350
+هو عشر ادي يعني
+
+286
+00:36:57,350 --> 00:37:07,330
+هكون سوى اتنين ت على by
+
+287
+00:37:07,330 --> 00:37:20,980
+في point zeroتمانية واحد دي تكيب هاد
+
+288
+00:37:20,980 --> 00:37:27,280
+في حالة ال closed في حالة ال open القلش هتساوي
+
+289
+00:37:27,280 --> 00:37:32,180
+المحيط
+
+290
+00:37:32,180 --> 00:37:44,910
+بيساوي by DM يعني هتكون byفى DM اللى هى فى تسعة من
+
+291
+00:37:44,910 --> 00:37:51,730
+عشرة D تقريبا انا اعملت خسارة
+
+292
+00:37:51,730 --> 00:37:57,350
+فى طول مثل السلطة يعنى التاو هتكون تساوي تلاتة T
+
+293
+00:37:57,350 --> 00:38:05,650
+على ال L اللى هى تسعة من عشرة باى
+
+294
+00:38:09,930 --> 00:38:18,030
+D ال C عبارة عن ايش عن ال T ال C اللي هي تساوية T
+
+295
+00:38:18,030 --> 00:38:30,990
+بالساوية عشر ال D في عشر ال D كل تربيع يعني هتكون
+
+296
+00:38:30,990 --> 00:38:37,590
+تساوية خلنا نسميها تو واحد تو اتنين يعني هتكون
+
+297
+00:38:40,240 --> 00:38:44,800
+تلاتة T على
+
+298
+00:38:44,800 --> 00:38:50,760
+point واحد في point واحد اللي هي point O واحد يعني
+
+299
+00:38:50,760 --> 00:39:00,040
+هتكون على point O O تسعة by ديتا كيب هاتة و اتنين
+
+300
+00:39:07,460 --> 00:39:13,840
+لو نقسم تاو اتنين على تاو واحد تاو اتنين على تاو
+
+301
+00:39:13,840 --> 00:39:20,620
+واحد هتكون الساعة تلاتة تي على بونت او او تسعة باي
+
+302
+00:39:20,620 --> 00:39:29,860
+دي تكييب في هاد هتطلع الصرف البسط هاد في باي في
+
+303
+00:39:29,860 --> 00:39:34,280
+بونت او تمانية
+
+304
+00:39:34,280 --> 00:39:34,820
+واحد
+
+305
+00:39:37,550 --> 00:39:48,610
+D تكيب على اتنين T يعني انا هتروح عند ال T مع T دي
+
+306
+00:39:48,610 --> 00:39:55,310
+تكيب مع دي تكيب و باي مع باي وهذه اللي ضربتها في
+
+307
+00:39:55,310 --> 00:39:59,970
+الف هتسير عند ايه تلاتة ع اتنين اللي هو واحد و نص
+
+308
+00:40:01,330 --> 00:40:09,750
+في واحد تمانين على تسعة يعني هتكون واحد و نص في
+
+309
+00:40:09,750 --> 00:40:17,690
+تسعة اللي هي تلتاش و نص المعنى الشيريسترس في حالة
+
+310
+00:40:17,690 --> 00:40:25,310
+ال open section حوالي اربعتاش أرضاف بارتفاع
+
+311
+00:40:25,310 --> 00:40:31,150
+ارتفاع الشيريسترس ميزة ولا سيئةسيئ برفع ال stress
+
+312
+00:40:31,150 --> 00:40:43,670
+level فيه شكل المقطع برفع ال stress level فيه طبعا
+
+313
+00:40:43,670 --> 00:40:45,850
+هو طلعت عنده اتناش مونت تلاتة انا عملت
+
+314
+00:40:45,850 --> 00:40:51,690
+approximation عشان اسهل الحسابات لما هنا عنده في
+
+315
+00:40:51,690 --> 00:40:59,590
+اندجابة عنده هنا ففرود أطراحها هذه طيبالـ Twist
+
+316
+00:40:59,590 --> 00:41:12,390
+Angle الحالة الأولى هي θ واحد بالساوية θ
+
+317
+00:41:12,390 --> 00:41:17,210
+واحد بالساوية T ال
+
+318
+00:41:17,210 --> 00:41:21,190
+M على
+
+319
+00:41:21,190 --> 00:41:28,430
+4G AM تربيع
+
+320
+00:41:30,210 --> 00:41:42,370
+fh في الـ T الحلق التاني theta two في ال open اللي
+
+321
+00:41:42,370 --> 00:41:47,550
+هتساوي هتساوي
+
+322
+00:41:47,550 --> 00:41:56,010
+من هذه ال theta one بتساوي تلتة T تلتة T على
+
+323
+00:41:56,010 --> 00:41:58,190
+G
+
+324
+00:42:00,850 --> 00:42:07,130
+ال C تكيب يعنى
+
+325
+00:42:07,130 --> 00:42:20,090
+هتكون ساوى تلاتة T على جي ال T تكيب صح؟ يعني ال
+
+326
+00:42:20,090 --> 00:42:24,490
+theta two على
+
+327
+00:42:24,490 --> 00:42:34,140
+ال theta واحد هتكون ساوى تلاتة Tعلى الـ G الـ T
+
+328
+00:42:34,140 --> 00:42:52,220
+تكييب في أربع G AM تربيع T على T LM خلينا نعمل
+
+329
+00:42:52,220 --> 00:43:00,020
+اختصارات Hand الـ G بتروح Hand ال torque بروحو
+
+330
+00:43:00,020 --> 00:43:09,120
+عندي T بتروح هنا تصير هنا تربيع تصفي تلاتة
+
+331
+00:43:09,120 --> 00:43:15,140
+في أربعة اتناش AM
+
+332
+00:43:15,140 --> 00:43:18,440
+تربيع
+
+333
+00:43:18,440 --> 00:43:26,820
+على ال T تربيع ال M
+
+334
+00:43:29,990 --> 00:43:47,610
+يعني هيساوي اتناش اقم اللي هي باي على اربع في
+
+335
+00:43:47,610 --> 00:43:51,710
+bond تمانية يعني
+
+336
+00:43:51,710 --> 00:43:59,140
+هسيب باي على اربع تربية في bond تمانية واحدتربية
+
+337
+00:43:59,140 --> 00:44:05,440
+في D أربعة هذه
+
+338
+00:44:05,440 --> 00:44:12,500
+AM تربية على L L
+
+339
+00:44:12,500 --> 00:44:23,240
+اللي هو المحيط اللي هو BY DM ال L اللي هي point
+
+340
+00:44:23,240 --> 00:44:26,100
+تسعة point تسعة
+
+341
+00:44:30,340 --> 00:44:38,440
+by ايش دي و ال T اللي يقارن point one في point one
+
+342
+00:44:38,440 --> 00:44:47,260
+اللي هي point O واحد دي تربيع في ال L M اللي هي
+
+343
+00:44:47,260 --> 00:44:50,180
+نفس الشي في point تسعة by
+
+344
+00:45:00,700 --> 00:45:07,460
+D يعني واضح ان ال ديز هذه واحد تلاتة اربع بروح مع
+
+345
+00:45:07,460 --> 00:45:11,260
+هدول وعندي
+
+346
+00:45:11,260 --> 00:45:18,600
+ال by مع
+
+347
+00:45:18,600 --> 00:45:27,360
+ال by بصفر theta two على ال theta واحد بالساوية
+
+348
+00:45:27,360 --> 00:45:28,160
+اتناش
+
+349
+00:45:31,450 --> 00:45:41,450
+في bond تمانية واحد في bond تمانية واحد على ستاش
+
+350
+00:45:41,450 --> 00:45:54,450
+في bond تسعة في bond او واحد في bond تسعة يعني هاي
+
+351
+00:45:54,450 --> 00:45:57,390
+واحد اتنين ماهيقول صح؟
+
+352
+00:46:01,480 --> 00:46:10,160
+هو عندى الاربعة فيها التلاتة الاربعة فيها الاربعة
+
+353
+00:46:10,160 --> 00:46:15,520
+يعنى
+
+354
+00:46:15,520 --> 00:46:20,040
+هكون ساوية تلاتة على اربعة اللى هى point سبعة خمسة
+
+355
+00:46:20,040 --> 00:46:27,980
+ادرس بسط بمية و المقام على مية هيكون خمسة سبعين في
+
+356
+00:46:27,980 --> 00:46:29,040
+point تمانية واحد
+
+357
+00:46:32,300 --> 00:46:38,560
+بس يقول ايه يعني يعني
+
+358
+00:46:38,560 --> 00:46:48,760
+تلت اربعة تمانين يعني حوالي اكم ستين يعني
+
+359
+00:46:48,760 --> 00:46:53,720
+ال twist في الحالة ال open حوالي اكتر من ستين بارف
+
+360
+00:46:53,720 --> 00:46:56,960
+لنفس ال torque لنفس مستوى ال torque
+
+361
+00:47:11,670 --> 00:47:36,990
+نشوف مثال تاني twelve
+
+362
+00:47:36,990 --> 00:47:43,520
+inch long stickstrip of steel عندي شريحة من الحديد
+
+363
+00:47:43,520 --> 00:47:51,300
+طولها اتناشر انش is one over eight inch ثمكتها
+
+364
+00:47:51,300 --> 00:47:59,040
+واحد تومن انش هذا الصمك والارتفاع بتاعها واحد انش
+
+365
+00:47:59,040 --> 00:47:59,960
+يعني جاي زي هيك
+
+366
+00:48:18,160 --> 00:48:23,380
+هذه اتناشر انش وهذه
+
+367
+00:48:23,380 --> 00:48:29,720
+اتمن انش وهذه
+
+368
+00:48:29,720 --> 00:48:40,940
+واحد انش if
+
+369
+00:48:40,940 --> 00:48:43,740
+the allowable share stress is eleven thousand five
+
+370
+00:48:43,740 --> 00:48:45,140
+hundred psi
+
+371
+00:48:47,930 --> 00:48:57,090
+شير السترس المسموح 11500 PSI and the shear modulus
+
+372
+00:48:57,090 --> 00:49:04,250
+is 11.5 Megapound per square inch و ال G 11.5
+
+373
+00:49:04,250 --> 00:49:11,830
+Megapound لكل square inch fine طبعا هذه هيكون
+
+374
+00:49:11,830 --> 00:49:12,430
+عليها ال torque
+
+375
+00:49:17,340 --> 00:49:19,580
+find the torque corresponding to the lowest shear
+
+376
+00:49:19,580 --> 00:49:24,380
+stress يعني احسبله ال torque المسموح فيه بحيث ال
+
+377
+00:49:24,380 --> 00:49:29,480
+shear stress مازيدش عن القيمة هذه and the angle of
+
+378
+00:49:29,480 --> 00:49:33,460
+twist in degrees using
+
+379
+00:49:33,460 --> 00:49:37,840
+equation تلاتة سبعة و أربعين equation تلاتة سبعة و
+
+380
+00:49:37,840 --> 00:49:42,100
+أربعين اللي هي الأخيرة و equation تلاتة اش اربعين
+
+381
+00:49:42,100 --> 00:49:44,120
+و تلاتة واحد اربعين تلاتة اربعين و تلاتة واحد
+
+382
+00:49:44,120 --> 00:49:45,820
+اربعين بتاعت في المقطع المستطيل
+
+383
+00:49:56,560 --> 00:50:03,380
+اللي هي تلاتة أربعين equation equation
+
+384
+00:50:03,380 --> 00:50:13,380
+تلاتة أربعين ال tau max بالساوية
+
+385
+00:50:13,380 --> 00:50:32,200
+T على Alpha ب C تربيعوالـ theta هو T في L على Beta
+
+386
+00:50:32,200 --> 00:50:43,980
+بي C تكيب G المعادلة
+
+387
+00:50:43,980 --> 00:50:45,760
+تلاتة سبع واربين اللي هي أخر واحدة تلاتة سبع
+
+388
+00:50:45,760 --> 00:50:51,580
+واربين هذا
+
+389
+00:50:51,580 --> 00:50:52,840
+هعتبره open section
+
+390
+00:51:00,040 --> 00:51:11,040
+التاو بالساوية تلاتة T على ال C تربيع والثتا
+
+391
+00:51:11,040 --> 00:51:14,160
+بالساوية
+
+392
+00:51:14,160 --> 00:51:23,380
+تلاتة T على G ال C تكيب من هذه
+
+393
+00:51:29,640 --> 00:51:34,180
+طيب معناته .. هنرجع .. نرجع واحدة واحدة نحل اللي
+
+394
+00:51:34,180 --> 00:51:41,260
+هو باستخدام المعادلة التالية ال
+
+395
+00:51:41,260 --> 00:51:48,180
+B على ال C إيش يساوي؟ اللي هي واحد على تمانية واحد
+
+396
+00:51:48,180 --> 00:51:56,760
+على واحد على تمانية يعني بتساوي إيش؟ تمانيةمن
+
+397
+00:51:56,760 --> 00:52:02,900
+الجدول هذا 1 على C بالصورة تمانية بطلق Alpha و
+
+398
+00:52:02,900 --> 00:52:10,580
+Beta ال Alpha بتطلع نفس القيمة في الحالة هذه ال
+
+399
+00:52:10,580 --> 00:52:14,320
+Alpha سواء
+
+400
+00:52:14,320 --> 00:52:18,940
+ال Beta بال سابونت تلت
+
+401
+00:52:18,940 --> 00:52:19,540
+مية و سبعة
+
+402
+00:52:27,910 --> 00:52:39,650
+ال B عندي واحد انش وال C طوان انش معناته ال torque
+
+403
+00:52:39,650 --> 00:52:53,250
+هين هكون الساوية ال TAU Alpha BC تربيع ال
+
+404
+00:52:53,250 --> 00:52:56,090
+TAU ماتينيها حداشر الف و خمس مية
+
+405
+00:53:00,560 --> 00:53:06,780
+في الـ alpha اللي هي point تلاتة سفر سبعة في ال B
+
+406
+00:53:06,780 --> 00:53:22,140
+واحد في ال C تربيع واحد على تمانية تربيع ايش
+
+407
+00:53:22,140 --> 00:53:25,340
+هذه؟
+
+408
+00:53:25,340 --> 00:53:27,960
+ايش الوحدات؟
+
+409
+00:53:30,380 --> 00:53:39,780
+خمسة خمسين بونت اكم واحد ستة pound انش
+
+410
+00:53:39,780 --> 00:53:45,280
+هذا ال torque طيب
+
+411
+00:53:45,280 --> 00:53:50,140
+نجر الحالة هذه ال torque هتكون في حالة المعادلة
+
+412
+00:53:50,140 --> 00:53:55,920
+اللي هي تانية هتكون ساوية تلت
+
+413
+00:53:58,790 --> 00:54:07,130
+تاو L C تربيع يعني هتكون سوى تلت في حداشر الف و
+
+414
+00:54:07,130 --> 00:54:10,950
+خمسمية ال
+
+415
+00:54:10,950 --> 00:54:18,010
+L اللي هو طول ال media line اللي هو واحد انش في
+
+416
+00:54:18,010 --> 00:54:26,130
+واحد على تمانية تربيع هكم بيطلع تسعة و خمسين point
+
+417
+00:54:26,130 --> 00:54:33,160
+تسعة و تمانيةتسعة و خمسين point تسعة و خمسين أو
+
+418
+00:54:33,160 --> 00:54:39,160
+تمانية و خمسين pound انش طلعوش لإن هو two
+
+419
+00:54:39,160 --> 00:54:44,500
+mathematical models يختلفوا عن بعض ال error عند
+
+420
+00:54:44,500 --> 00:54:47,820
+ضيابة دكتورة؟ لأ انا بحكي عن ال percentage
+
+421
+00:54:47,820 --> 00:54:51,380
+difference percentage difference بيختلف عن ال
+
+422
+00:54:51,380 --> 00:54:54,320
+percentage error ال error ده مش هو ال error تعريفه
+
+423
+00:54:56,950 --> 00:55:01,470
+إيش تعرف ال error؟ الخطأ الخطأ
+
+424
+00:55:01,470 --> 00:55:07,070
+هو الفرق بين القيمة اللي بتحسبها أو بتقيسها ناقص
+
+425
+00:55:07,070 --> 00:55:12,290
+لل true value هل هذه ال true value؟ هلها true
+
+426
+00:55:12,290 --> 00:55:14,570
+value؟ هذا ال mathematical model و هذا ال
+
+427
+00:55:14,570 --> 00:55:16,690
+mathematical model لا يعبر true هذا prediction
+
+428
+00:55:16,690 --> 00:55:21,410
+فبنفعش أحكي percentage error بحكي percentage
+
+429
+00:55:21,410 --> 00:55:26,480
+differenceبين الاتنين انا بقارن هذا مع هذا الفرق
+
+430
+00:55:26,480 --> 00:55:33,500
+بينهم كذا يمكن هذا الصح و هذا الصح او الأقرب للصح
+
+431
+00:55:33,500 --> 00:55:40,100
+نحكي ال theta هنا ال theta في حالة المعادلات هذه
+
+432
+00:55:40,100 --> 00:55:47,200
+هتكون ساوية T اللي احسبتها 55.16
+
+433
+00:55:52,320 --> 00:55:58,960
+الال اللي هو طوله اللي هو اتناشر انش الال هنا الال
+
+434
+00:55:58,960 --> 00:56:04,860
+سواء اتناشر انش انتبهوا الال اللي هنا ماتعكش على
+
+435
+00:56:04,860 --> 00:56:12,100
+الطول هذا الال اللي هي عياش هذا الطول هتكون خمسة
+
+436
+00:56:12,100 --> 00:56:19,120
+خمسين ومس اتناش في الال اللي هي اتناش على
+
+437
+00:56:20,720 --> 00:56:33,480
+بتا التي هي point تلاتة سفر سبعة في بي واحد في سي
+
+438
+00:56:33,480 --> 00:56:37,780
+تكييب في التي هي point واحد اتنين خمسة التي هي
+
+439
+00:56:37,780 --> 00:56:44,540
+تمان تكييب في جي الواحداشر
+
+440
+00:56:44,540 --> 00:56:45,000
+و نص
+
+441
+00:56:48,260 --> 00:56:54,080
+في عشرة أقل سالب عشرة أقل ست الستة عشان أحول ال
+
+442
+00:56:54,080 --> 00:56:56,400
+degrees هضبهم في مية و تمانين على باقية في مية و
+
+443
+00:56:56,400 --> 00:57:00,820
+تمانين على
+
+444
+00:57:00,820 --> 00:57:05,780
+باقية خمسة
+
+445
+00:57:05,780 --> 00:57:13,560
+upon ستة degrees حين
+
+446
+00:57:13,560 --> 00:57:19,740
+الستة حلقة تانية هتكون ساوية تلاتةالتورك انا حسب
+
+447
+00:57:19,740 --> 00:57:26,340
+تسعة و خمسين point تمانية تسعة على جيه احداشر و نص
+
+448
+00:57:26,340 --> 00:57:35,320
+عشرة رقص ستة في
+
+449
+00:57:35,320 --> 00:57:38,140
+القل اللي هي
+
+450
+00:57:55,780 --> 00:58:07,740
+لحظة قال اللي هي واحد اللي هي عندي هين في واحد في
+
+451
+00:58:07,740 --> 00:58:14,560
+ال C تكييب اللي هي point واحد اتنين خمسة تكييب في
+
+452
+00:58:14,560 --> 00:58:22,320
+مية و تمانين على باى تسبوا اكم دجريسه طلع
+
+453
+00:58:35,850 --> 00:58:42,130
+مين بيحسب؟ ده الحسابات المهندس ماريكنش الحسابات
+
+454
+00:58:42,130 --> 00:58:46,830
+غيره لازم تعمل ايه؟ double check نعم point اربعمية
+
+455
+00:58:46,830 --> 00:58:52,490
+و تمانية و تمانية دي degrees point اكم؟ اربعمية و
+
+456
+00:58:52,490 --> 00:58:58,090
+تمانية و تمانية معناه
+
+457
+00:58:58,090 --> 00:59:03,270
+هذا الرقم هذا غلط هذا في فرق كبير هذا أنا ماحسبتش
+
+458
+00:59:03,270 --> 00:59:04,730
+طب افحص هذا
+
+459
+00:59:21,730 --> 00:59:28,370
+بواتستا دايما تعتمدش ان اي اشي في الكتب صح الكتب
+
+460
+00:59:28,370 --> 00:59:31,590
+.. الكتب ممكن يكون فيها أخطاء وارد انا كتير كشفت
+
+461
+00:59:31,590 --> 00:59:37,270
+أخطاء بكتب ال software .. ال software بيكون فيها
+
+462
+00:59:37,270 --> 00:59:38,850
+أخطاء برمجية بعض أحيان
+
+463
+00:59:41,630 --> 00:59:45,870
+Autocad قديما كان بقرا أكيد صلحوها أيه ممكن أنا
+
+464
+00:59:45,870 --> 00:59:49,330
+طلعت فيه تلاتاشر خطأ فيه أخطاء هذا من حوالي عشرين
+
+465
+00:59:49,330 --> 00:59:58,710
+سنة تقريبا أكيد صلحوها نعم مش فاهم خلاص احسبه
+
+466
+00:59:58,710 --> 01:00:01,750
+براحتك انت عشان ..
+
+467
+01:00:09,700 --> 01:00:14,380
+اللي نحكي عن موضوع جديد حاليا stress concentration
+
+468
+01:00:14,380 --> 01:00:31,960
+أو ما يسمى تركيز الإجهادات تركيز الإجهادات إذا
+
+469
+01:00:31,960 --> 01:00:38,090
+بيكون في عندى تغير في المقطع أو في ثقوببتعمل تركيز
+
+470
+01:00:38,090 --> 01:00:42,670
+للإجهادات انا عندي هنا من باقي عندي ثقب متعرض لأكس
+
+471
+01:00:42,670 --> 01:00:48,150
+ال stress sigma الآن بعيد عن الثقب بيكون ال stress
+
+472
+01:00:48,150 --> 01:00:55,090
+level high مستوى لما أصير أقترب من الثقب ال stress
+
+473
+01:00:55,090 --> 01:01:02,250
+برتفع نتيجة تركيز الإجهاد فهذه sigma max وهذه نمو
+
+474
+01:01:02,250 --> 01:01:06,530
+ال stressاللي هو ال stress بعيدا عن ال
+
+475
+01:01:06,530 --> 01:01:11,770
+discontinuity و ال sigma max هو ال stress close to
+
+476
+01:01:11,770 --> 01:01:15,330
+the discontinuity هيكون بعرف ال geometric stress
+
+477
+01:01:15,330 --> 01:01:19,590
+concentration factor كتير بالسواء sigma max على
+
+478
+01:01:19,590 --> 01:01:25,670
+sigma nominal هذه sigma nominal وهذه sigma max
+
+479
+01:01:25,670 --> 01:01:31,190
+وهذه
+
+480
+01:01:36,060 --> 01:01:38,320
+stress بتغير بالشكل هذا
+
+481
+01:01:52,430 --> 01:01:55,650
+فبعرف الـ geometric stress concentration factor أو
+
+482
+01:01:55,650 --> 01:01:57,230
+الـ theoretical stress concentration factor
+
+483
+01:01:57,230 --> 01:02:00,670
+بالمعادلة KT بيستوى سجل max على سجل node هذا في
+
+484
+01:02:00,670 --> 01:02:03,270
+حالة كان عندي اللوع من ال stress دي في حالة shear
+
+485
+01:02:03,270 --> 01:02:09,470
+stress بسميه بحط ال KT as shear tau max maximum
+
+486
+01:02:09,470 --> 01:02:13,330
+shear stress على ال nominal shear stress
+
+487
+01:02:17,730 --> 01:02:23,210
+في الكتاب ال appendix A15 و A16 بيعطوني
+
+488
+01:02:23,210 --> 01:02:26,670
+theoretical stress concentration factors ل
+
+489
+01:02:26,670 --> 01:02:30,410
+different geometries و different loading
+
+490
+01:02:30,410 --> 01:02:35,790
+conditions اللي هو appendix A15 و A16 اذا بدك اشي
+
+491
+01:02:35,790 --> 01:02:40,290
+مفصل فيه واحد اسمه petersens stress concentration
+
+492
+01:02:40,290 --> 01:02:46,380
+factor دور عليه على ال .. على ال ..عال net هتشوفوا
+
+493
+01:02:46,380 --> 01:02:49,080
+كتاب handbook بيعطينا كل stress concentration
+
+494
+01:02:49,080 --> 01:02:55,760
+factors انا هنا هعرض امثلة هاندي مثلا هدا A15 1
+
+495
+01:02:55,760 --> 01:03:01,120
+A15
+
+496
+01:03:01,120 --> 01:03:06,440
+1 هعرضلي
+
+497
+01:03:06,440 --> 01:03:11,360
+اللي هو المقطع او ال .. ال .. ال member شكله
+
+498
+01:03:27,080 --> 01:03:37,600
+و فى عندى هنا فى
+
+499
+01:03:37,600 --> 01:03:44,280
+ثقوب فى ايش ثقوب فى فارس هنا F
+
+500
+01:03:47,160 --> 01:03:50,120
+في force F هند هين هيكون طبعا في stress
+
+501
+01:03:50,120 --> 01:03:53,420
+concentration وبيعطينا ال geometric stress
+
+502
+01:03:53,420 --> 01:03:58,040
+concentration factor على المحور طبعا دي هاد مسميها
+
+503
+01:03:58,040 --> 01:04:05,080
+ال W و
+
+504
+01:04:05,080 --> 01:04:08,160
+هاد H دي قطر الثقوب
+
+505
+01:04:15,970 --> 01:04:21,590
+عارفين نحو بعضنا بعض الطين ال D على W D على W وهنا
+
+506
+01:04:21,590 --> 01:04:27,850
+ال K T طبعا
+
+507
+01:04:27,850 --> 01:04:33,350
+كل ما يصغر ال ratio D على W بتقل كل ما ال stress
+
+508
+01:04:33,350 --> 01:04:34,790
+concentration effect بزيد
+
+509
+01:04:40,700 --> 01:04:44,100
+النت ايه طبعا ال stress ال sigma o ال nominal
+
+510
+01:04:44,100 --> 01:04:47,300
+stress هو كاتب لك يعني في الانواع بتاع ال appendix
+
+511
+01:04:47,300 --> 01:04:54,080
+sigma o بالساعة F على A و ال A لما ناخد مقطع هنا
+
+512
+01:04:54,080 --> 01:05:00,480
+هيكون
+
+513
+01:05:00,480 --> 01:05:01,880
+شكل المقطع جاي زي هيك
+
+514
+01:05:18,950 --> 01:05:26,710
+يعني هذا فاضي هذا W و
+
+515
+01:05:26,710 --> 01:05:32,510
+هذا H D معناه ان ال net area اللي فيها لحم حي اللي
+
+516
+01:05:32,510 --> 01:05:41,510
+هي H W minus ايه بيستوي ال W هذا T W
+
+517
+01:05:41,510 --> 01:05:46,090
+minus D في T
+
+518
+01:05:54,650 --> 01:06:00,670
+حالة تانية فيها
+
+519
+01:06:00,670 --> 01:06:05,710
+عندى shaft مدور وفيه بتغير من القطر دي capital
+
+520
+01:06:05,710 --> 01:06:09,490
+لديه small من دي capital لديه small وفيه عندهين
+
+521
+01:06:09,490 --> 01:06:14,430
+small fillet fillet ال radius بتاعها اه وفيه
+
+522
+01:06:14,430 --> 01:06:18,590
+bending moment عليه فيه bending moment مش torsion
+
+523
+01:06:24,030 --> 01:06:29,330
+الـ bending moment بتعمل stress concentration الان
+
+524
+01:06:29,330 --> 01:06:31,410
+ال stress concentration factor اللي هو على ال y
+
+525
+01:06:31,410 --> 01:06:38,470
+axis هذا الكتيه
+
+526
+01:06:38,470 --> 01:06:47,210
+بعتمد على ال ratio R على D هذا ال ratio بين مص قطر
+
+527
+01:06:47,210 --> 01:06:54,390
+الفلت على القطر الصغير ومعطين different curvesدى
+
+528
+01:06:54,390 --> 01:07:01,570
+هدول كيرفات دى capital على d small يعني مثلا هدى d
+
+529
+01:07:01,570 --> 01:07:04,350
+capital على d small تلاتة هدى d capital على d
+
+530
+01:07:04,350 --> 01:07:11,130
+small واحد و نص هدى واحد point one هدى واحد point
+
+531
+01:07:11,130 --> 01:07:13,910
+oh six هدى واحد point oh two معطيني different
+
+532
+01:07:13,910 --> 01:07:18,570
+curves معناه واضح ال KT is a function معنى ال
+
+533
+01:07:18,570 --> 01:07:22,400
+ratio R small على D smallwith a function also مع
+
+534
+01:07:22,400 --> 01:07:29,520
+دي capital على دي small ال
+
+535
+01:07:29,520 --> 01:07:38,960
+sigma o ال nominal stress sigma o بيستوى MC على I
+
+536
+01:07:38,960 --> 01:07:45,940
+ال C بيستوى دي small على اتنين وال I واحد على
+
+537
+01:07:45,940 --> 01:07:50,300
+اربعة ستين by دي قصة اربعة
+
+538
+01:07:54,380 --> 01:08:00,000
+هذا اللي هو ال stress عند ال fillet برتفع هضرب
+
+539
+01:08:00,000 --> 01:08:10,980
+اللي هو sigma max سوى KT في sigma R
+
+540
+01:08:30,180 --> 01:08:34,560
+الان اعتبارنا لل stress concentration factor
+
+541
+01:08:34,560 --> 01:08:37,860
+بيعتمد على طبيعة ال loading هل ال loading static
+
+542
+01:08:37,860 --> 01:08:46,340
+ثابت ولا dynamic يعني متغيروبرضه بيعتمد على طبيعة
+
+543
+01:08:46,340 --> 01:08:53,160
+المادة هالمادة ductile ولا brittle يعني ال stress
+
+544
+01:08:53,160 --> 01:08:56,940
+اعتبار او يعني بيكون ذو اهمية ال stress
+
+545
+01:08:56,940 --> 01:09:01,080
+concentration اعتمادا على نوع ال loading سواء كان
+
+546
+01:09:01,080 --> 01:09:05,860
+static او dynamic loading او اعتمادا على نوع
+
+547
+01:09:05,860 --> 01:09:09,800
+المادة لو كانت ductile او brittle لان لو كان ال
+
+548
+01:09:09,800 --> 01:09:13,540
+loading static و المادة ductile
+
+549
+01:09:15,330 --> 01:09:20,570
+الان ال material ductile يعني فيها مرونة لما مثلا
+
+550
+01:09:20,570 --> 01:09:25,350
+بعمل bending ال outer fiber هصير فيها إيش؟ strains
+
+551
+01:09:25,350 --> 01:09:32,110
+ال strains بتمثل كأنها مجال .. مجال تمدد .. مجال
+
+552
+01:09:32,110 --> 01:09:38,250
+تمدد لأن ال material مش طبقات كرتون منفصل عن بعض
+
+553
+01:09:38,250 --> 01:09:43,510
+هكون فيها إيش؟ continuity استمرادية معناه الطبقة
+
+554
+01:09:43,510 --> 01:09:51,510
+العلويةلأن المادة مرنة هتنقل ..يعني هسي لعندي
+
+555
+01:09:51,510 --> 01:09:56,270
+انتشار لل strain field للطبقة اللي تحتها و اللي
+
+556
+01:09:56,270 --> 01:10:01,310
+تحتها تسلم تحتها وكذا وكذا وكذا فالمادة شو تسوي؟
+
+557
+01:10:01,310 --> 01:10:08,690
+بتريح بتريح معناته لو دخلت منطقة ال plastic region
+
+558
+01:10:08,690 --> 01:10:16,160
+بصير تريح لل stress وبالتاليبصيرش هندي ممكن احمل
+
+559
+01:10:16,160 --> 01:10:21,560
+ال stress concentration بمعنى لو كان عندي هن انا
+
+560
+01:10:21,560 --> 01:10:24,480
+ال nominal انا واضح ان انا في ال elastic range
+
+561
+01:10:24,480 --> 01:10:28,760
+مثلا وصلت ميت ميجا بسكال لكن نتيجة ال stress
+
+562
+01:10:28,760 --> 01:10:32,440
+concentration كان الكتيه عند اتنين اتنين في مية
+
+563
+01:10:32,440 --> 01:10:37,880
+متين معناه دخلت انا ايش في منطقة ال plastic
+
+564
+01:10:37,880 --> 01:10:42,360
+locally due to stress concentration لما تكون مادة
+
+565
+01:10:42,360 --> 01:10:48,420
+ductileبتحاول تخفف عن حالها بصير تنتقل لطبع لطبع
+
+566
+01:10:48,420 --> 01:10:50,020
+لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع
+
+567
+01:10:50,020 --> 01:10:50,440
+لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع
+
+568
+01:10:50,440 --> 01:10:52,080
+لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع
+
+569
+01:10:52,080 --> 01:10:58,260
+لطبع لطبع لطبع لطبع لطبع
+
+570
+01:10:58,260 --> 01:11:04,880
+لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع لطبع
+
+571
+01:11:04,880 --> 01:11:10,760
+لطبع لطبع
+
+572
+01:11:10,760 --> 01:11:13,940
+لطبع لطبع
+
+573
+01:11:17,410 --> 01:11:25,250
+في حالة ال brittle material بنقدرش نهمل ال stress
+
+574
+01:11:25,250 --> 01:11:27,130
+concentration ال brittle material المادة ناشفة
+
+575
+01:11:27,130 --> 01:11:32,850
+فصعب انه .. انه يصير انتشار لل .. لل .. لل strain
+
+576
+01:11:32,850 --> 01:11:38,710
+field من طبقة لطبقة في حالة ال dynamic loading بغض
+
+577
+01:11:38,710 --> 01:11:45,010
+النظر المادة كانت ductile and brittleلازم اخد في
+
+578
+01:11:45,010 --> 01:11:48,030
+عين الاعتبار ال stress concentration معناته اذا
+
+579
+01:11:48,030 --> 01:11:53,530
+كانت المادة ال loading static و المادة ductile
+
+580
+01:11:53,530 --> 01:11:56,890
+ممكن احمل ال stress concentration اذا كانت ال
+
+581
+01:11:56,890 --> 01:12:01,830
+loading static و المادة brittle مش لازم احمله اذا
+
+582
+01:12:01,830 --> 01:12:07,230
+كان عندى ال loading dynamic بغض النظر ال ductile
+
+583
+01:12:07,230 --> 01:12:10,130
+او ال brittle materials لازم اخده في عين الاعتبار
+
+584
+01:12:10,130 --> 01:12:11,130
+ال stress concentration
+
+585
+01:12:17,730 --> 01:12:24,150
+طيب في techniques أو طرق ممكن استخدمها عشان أقلل
+
+586
+01:12:24,150 --> 01:12:29,330
+من ال .. من التركيز الإجهادات ممكن أنت بناطق
+
+587
+01:12:29,330 --> 01:12:32,990
+التغيّر في المقطع أكبر ال fillet يعني انا أكون
+
+588
+01:12:32,990 --> 01:12:39,350
+fillet حادةبترفع الجهد يعني انا عشان مثلا انا لو
+
+589
+01:12:39,350 --> 01:12:42,610
+بدي احاول اكسر خشب اخبط عليها خبطة هنا ممكن
+
+590
+01:12:42,610 --> 01:12:48,690
+ماتكسرش لكن لو ماتلحظ خفيف المنشار او سكين خبط
+
+591
+01:12:48,690 --> 01:12:53,250
+عليها ايش تكسر هي كيف انكسرت انكسرت ال stress
+
+592
+01:12:53,250 --> 01:13:00,070
+level ارتفع فدخلت على ال plastic region انكسر ف ..
+
+593
+01:13:00,070 --> 01:13:07,610
+ان .. increase ال radiusreduce disruption يعني
+
+594
+01:13:07,610 --> 01:13:15,310
+احاول قدر اللي كان اخلي التغير تدريجي قليل allowed
+
+595
+01:13:15,310 --> 01:13:18,890
+its zones to shape flow lines more gradual لان ال
+
+596
+01:13:18,890 --> 01:13:25,910
+strain field كأنه مجال مغناطيسي او مجال كهربائي هو
+
+597
+01:13:25,910 --> 01:13:30,500
+ال field بالاخر بضللهفانا بدي اعمل بعض الحركات او
+
+598
+01:13:30,500 --> 01:13:34,500
+بعض ال .. ال .. ال techniques بحيث ان اخلي ال flow
+
+599
+01:13:34,500 --> 01:13:38,020
+lines مايصيرش فيه تدفق مفاجئ انه تكون مش هيك و
+
+600
+01:13:38,020 --> 01:13:43,100
+فجأة تعلق لأ بدي اخلي اعمل shape ال geometry بحيث
+
+601
+01:13:43,100 --> 01:13:48,940
+انه ال streamlines بتاعة ال .. ال strain fields ت
+
+602
+01:13:48,940 --> 01:13:55,740
+flow smoothly يعني لما احكي streamlinesتتذكر
+
+603
+01:13:55,740 --> 01:14:01,880
+السيارات ال air dynamic كيف الشكل ده يعني ممكن انا
+
+604
+01:14:01,880 --> 01:14:16,480
+اعمل سيارة بالشكل هذا الهواء
+
+605
+01:14:16,480 --> 01:14:23,280
+هيجي هيخبط زي هيك و هيحاول يرجع هنا
+
+606
+01:14:29,930 --> 01:14:55,450
+هذه حالة صح حالة تانية هو هنير شكل السيارة الان
+
+607
+01:14:55,450 --> 01:14:56,390
+الهواء لم يمشي
+
+608
+01:14:59,190 --> 01:15:07,530
+بنزلق بشكل smooth بشكل smooth نفس الفكرة في ال
+
+609
+01:15:07,530 --> 01:15:15,210
+strain fields بدك ال strain fields بتكون smoothly
+
+610
+01:15:15,210 --> 01:15:19,510
+oriented أو تتدفق بشكل نعم و شكل متدرج في ال
+
+611
+01:15:19,510 --> 01:15:24,800
+materialال strain fields او ال stress fields ممكن
+
+612
+01:15:24,800 --> 01:15:27,720
+انا اعمل finite element analysis عشان اشوف كيف ال
+
+613
+01:15:27,720 --> 01:15:32,020
+strain fields موجودة باستخدام برامج finite element
+
+614
+01:15:32,020 --> 01:15:35,600
+ممكن اصطلع دورك بيعمل finite element ansys,
+
+615
+01:15:35,920 --> 01:15:39,320
+abacus, nasa, ID's في برامج كتير بتعمليهاش finite
+
+616
+01:15:39,320 --> 01:15:44,240
+element من ال techniques اللي انا بعمل مثلا عندي
+
+617
+01:15:44,240 --> 01:15:44,820
+hand bearings
+
+618
+01:15:48,000 --> 01:15:52,660
+في فلتن دي يعني في حفر high shaft في حفر جاهزة هيك
+
+619
+01:15:52,660 --> 01:15:56,180
+ف ال strain .. strain fields ماشية بالشكل هذا لكن
+
+620
+01:15:56,180 --> 01:16:03,500
+لو ده كانت عففة هاد ده هصير قفزة technique
+
+621
+01:16:03,500 --> 01:16:13,120
+تاني بعمل groove بقرأ
+
+622
+01:16:13,120 --> 01:16:14,380
+تدخل ال strain fields
+
+623
+01:16:26,780 --> 01:16:29,680
+برضه هذا بيعمل ليه relief بيخلي ال strength fields
+
+624
+01:16:29,680 --> 01:16:36,320
+to move smoothly اذا حد بدى يعرف كيف تنعمل هذا او
+
+625
+01:16:36,320 --> 01:16:41,940
+ايش الاساس تاعة بدك تخش تطلعه روح على امازون تطلع
+
+626
+01:16:41,940 --> 01:16:48,060
+على ال theory of
+
+627
+01:16:48,060 --> 01:16:54,140
+elasticity و
+
+628
+01:16:54,140 --> 01:16:54,860
+ال theory of
+
+629
+01:16:59,550 --> 01:17:03,150
+plasticity اقرأ اذا حد المعنى يعرف التفاصيل اكتر
+
+630
+01:17:03,150 --> 01:17:09,670
+طيب
+
+631
+01:17:09,670 --> 01:17:13,550
+هيك بيكون انهينا المحاضرة المرة الجاية بنحل
+
+632
+01:17:13,550 --> 01:17:16,430
+examples اعطيكوا العفو
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/OJ_cnqk3OA4_raw.json b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/OJ_cnqk3OA4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..482fadee75fccb3dc84e92dfa1aec8e596a57ec4
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/OJ_cnqk3OA4_raw.json
@@ -0,0 +1 @@
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19507, "start": 168.39, "end": 195.07, "text": "ix y z and sigma x sigma y و sigma", "tokens": [970, 288, 710, 293, 12771, 2031, 12771, 288, 4032, 12771], "avg_logprob": -0.6669034199281172, "compression_ratio": 1.0606060606060606, "no_speech_prob": 0.0, "words": [{"start": 168.39, "end": 169.79, "word": "ix", "probability": 0.059295654296875}, {"start": 169.79, "end": 171.19, "word": " y", "probability": 0.66357421875}, {"start": 171.19, "end": 173.37, "word": " z", "probability": 0.90576171875}, {"start": 173.37, "end": 183.79, "word": " and", "probability": 0.48583984375}, {"start": 183.79, "end": 184.17, "word": " sigma", "probability": 0.49462890625}, {"start": 184.17, "end": 184.67, "word": " x", "probability": 0.97412109375}, {"start": 184.67, "end": 190.01, "word": " sigma", "probability": 0.333740234375}, {"start": 190.01, "end": 190.47, "word": " y", "probability": 0.98876953125}, {"start": 190.47, "end": 194.77, "word": " و", "probability": 0.5908203125}, {"start": 194.77, 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منها بعدين بحسب ال principle stresses", "tokens": [3224, 1829, 30544, 8978, 3224, 3753, 25894, 11296, 2073, 295, 4244, 4032, 2710, 4244, 6156, 2304, 43020, 1975, 2407, 26108, 3224, 13672, 26895, 3660, 12174, 36150, 9957, 2423, 2710, 4244, 15844, 9673, 14851, 2407, 7578, 23758, 4032, 2073, 295, 4244, 20449, 12771, 2031, 12771, 288, 12771, 710, 8289, 17842, 2031, 88, 17842, 2031, 89, 17842, 288, 89, 44945, 36178, 21136, 25528, 4587, 13672, 1829, 11331, 995, 4117, 1829, 8315, 3224, 8978, 2423, 568, 67, 1389, 9154, 11296, 39182, 9957, 4724, 5016, 35457, 2423, 8665, 27732], "avg_logprob": -0.32303778064805405, "compression_ratio": 1.6136363636363635, "no_speech_prob": 0.0, "words": [{"start": 275.35, "end": 275.85, "word": "هيكون", "probability": 0.6190592447916666}, {"start": 275.85, "end": 276.15, "word": " فيه", "probability": 0.6246337890625}, {"start": 276.15, "end": 276.67, "word": " surface", "probability": 0.85546875}, {"start": 276.67, "end": 277.35, "word": " عليها", 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554.14, "end": 554.9, "word": " على", "probability": 0.9248046875}, {"start": 554.9, "end": 555.3, "word": " A", "probability": 0.982421875}, {"start": 555.3, "end": 563.1, "word": " لو", "probability": 0.90869140625}, {"start": 563.1, "end": 563.38, "word": " كان", "probability": 0.99072265625}, {"start": 563.38, "end": 563.76, "word": " عندي", "probability": 0.664306640625}, {"start": 563.76, "end": 564.44, "word": " element", "probability": 0.87744140625}], "temperature": 1.0}, {"id": 21, "seek": 59378, "start": 569.14, "end": 593.78, "text": "الـ 3D Element عليه عليه Sigma X و Sigma Y و Sigma Z", "tokens": [6027, 39184, 805, 35, 20900, 25894, 3224, 25894, 3224, 36595, 1783, 4032, 36595, 398, 4032, 36595, 1176], "avg_logprob": -0.3042534738779068, "compression_ratio": 1.2745098039215685, "no_speech_prob": 0.0, "words": [{"start": 569.14, "end": 569.52, "word": "الـ", "probability": 0.82861328125}, {"start": 569.52, "end": 569.88, "word": " 3D", "probability": 0.87451171875}, 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لحاله هيكون فيه strain عندى اللى هو sigma X على A لو كان sigma X لحاله لكن فيه عندى sigma Y بعكسه من ال minus nu في sigma Y", "tokens": [6027, 10721, 3555, 3794, 9566, 9154, 1783, 45164, 25961, 4724, 3794, 16150, 1783, 5296, 5016, 6027, 3224, 39896, 30544, 8978, 3224, 14249, 43242, 7578, 13672, 7578, 31439, 12771, 1783, 15844, 316, 45164, 25961, 12771, 1783, 5296, 5016, 6027, 3224, 44381, 8978, 3224, 43242, 7578, 12771, 398, 45030, 4117, 3794, 3224, 9154, 2423, 3175, 3822, 8978, 12771, 398], "avg_logprob": -0.2714170155854061, "compression_ratio": 1.5704225352112675, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 599.53, "end": 600.29, "word": "الأبسط", "probability": 0.704296875}, {"start": 600.29, "end": 600.43, "word": " من", "probability": 0.9775390625}, {"start": 600.43, "end": 600.89, "word": " X", "probability": 0.54443359375}, {"start": 600.89, "end": 603.51, "word": " لو", "probability": 0.947265625}, {"start": 603.51, "end": 603.73, "word": " كان", 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{"start": 987.11, "end": 988.19, "word": " beam", "probability": 0.6953125}, {"start": 988.19, "end": 988.47, "word": " is", "probability": 0.95703125}, {"start": 988.47, "end": 988.99, "word": " initially", "probability": 0.7099609375}, {"start": 988.99, "end": 989.75, "word": " straight", "probability": 0.8642578125}, {"start": 989.75, "end": 990.27, "word": " with", "probability": 0.9169921875}, {"start": 990.27, "end": 990.79, "word": " constant", "probability": 0.859375}, {"start": 990.79, "end": 991.11, "word": " cross", "probability": 0.84619140625}, {"start": 991.11, "end": 991.57, "word": " section", "probability": 0.72607421875}, {"start": 991.57, "end": 992.71, "word": " الجسر", "probability": 0.9703776041666666}, {"start": 992.71, "end": 992.91, "word": " في", "probability": 0.81787109375}, {"start": 992.91, "end": 993.35, "word": " البداية", "probability": 0.9508463541666666}, {"start": 993.35, "end": 994.05, "word": " كان", "probability": 0.97998046875}, {"start": 994.05, "end": 994.53, "word": " ردل", "probability": 0.6527506510416666}, {"start": 994.53, "end": 995.27, "word": " مستقيم", "probability": 0.9447021484375}, {"start": 995.27, "end": 995.85, "word": " و", "probability": 0.5712890625}, {"start": 995.85, "end": 996.27, "word": " المقطع", "probability": 0.9666341145833334}, {"start": 996.27, "end": 996.83, "word": " بتاعه", "probability": 0.765380859375}, {"start": 996.83, "end": 997.47, "word": " ثابت", "probability": 0.99365234375}], "temperature": 1.0}, {"id": 37, "seek": 102563, "start": 1000.57, "end": 1025.63, "text": "beam has axis of symmetry in plane of bending يعني المعادلات هذه مثلا هذه ال section مستطيل خلصت axis لاحظوا هذه ال y axis في symmetry حول ال y axis لكن لو كانت حالة", "tokens": [650, 335, 575, 10298, 295, 25440, 294, 5720, 295, 22487, 37495, 22653, 9673, 3615, 18513, 1211, 9307, 29538, 50113, 15040, 29538, 2423, 3541, 3714, 14851, 9566, 26895, 16490, 1211, 9381, 2655, 10298, 20193, 5016, 19913, 14407, 29538, 2423, 288, 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يعني", "probability": 0.82958984375}, {"start": 1007.19, "end": 1009.11, "word": " المعادلات", "probability": 0.787060546875}, {"start": 1009.11, "end": 1009.45, "word": " هذه", "probability": 0.6953125}, {"start": 1009.45, "end": 1010.93, "word": " مثلا", "probability": 0.5836181640625}, {"start": 1010.93, "end": 1011.09, "word": " هذه", "probability": 0.705078125}, {"start": 1011.09, "end": 1011.19, "word": " ال", "probability": 0.38232421875}, {"start": 1011.19, "end": 1011.39, "word": " section", "probability": 0.359375}, {"start": 1011.39, "end": 1012.89, "word": " مستطيل", "probability": 0.828857421875}, {"start": 1012.89, "end": 1017.27, "word": " خلصت", "probability": 0.6298828125}, {"start": 1017.27, "end": 1017.65, "word": " axis", "probability": 0.65283203125}, {"start": 1017.65, "end": 1019.21, "word": " لاحظوا", "probability": 0.864990234375}, {"start": 1019.21, "end": 1019.49, "word": " هذه", "probability": 0.56884765625}, {"start": 1019.49, "end": 1019.69, "word": " ال", 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0.982421875}], "temperature": 1.0}, {"id": 38, "seek": 106194, "start": 1034.1, "end": 1061.94, "text": "شي زي هيك فيه symmetry حوالين ال y axis لات عن طبق المعادلات failure is by bending اذا فأصار failure نتيجة ال bending يعني بيصير لايق بيصير طعج للمادة not by crushing, wrinkling او sideways backing", "tokens": [8592, 1829, 30767, 1829, 39896, 4117, 8978, 3224, 25440, 11331, 2407, 6027, 9957, 2423, 288, 10298, 5296, 9307, 18871, 23032, 3555, 4587, 9673, 3615, 18513, 1211, 9307, 7763, 307, 538, 22487, 1975, 15730, 6156, 10721, 9381, 9640, 7763, 8717, 31371, 7435, 3660, 2423, 22487, 37495, 22653, 4724, 1829, 9381, 13546, 20193, 1829, 4587, 4724, 1829, 9381, 13546, 23032, 3615, 7435, 5296, 19528, 18513, 3660, 406, 538, 31317, 11, 928, 45258, 1975, 2407, 26092, 19373], "avg_logprob": -0.3308333309491475, "compression_ratio": 1.4300518134715026, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1034.1, "end": 1034.46, "word": "شي", "probability": 0.5565185546875}, {"start": 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"end": 1053.52, "word": " لايق", "probability": 0.57470703125}, {"start": 1053.52, "end": 1053.92, "word": " بيصير", "probability": 0.87158203125}, {"start": 1053.92, "end": 1054.28, "word": " طعج", "probability": 0.8155924479166666}, {"start": 1054.28, "end": 1055.04, "word": " للمادة", "probability": 0.94873046875}, {"start": 1055.04, "end": 1057.14, "word": " not", "probability": 0.892578125}, {"start": 1057.14, "end": 1057.54, "word": " by", "probability": 0.97119140625}, {"start": 1057.54, "end": 1058.16, "word": " crushing,", "probability": 0.80517578125}, {"start": 1058.4, "end": 1058.8, "word": " wrinkling", "probability": 0.915283203125}, {"start": 1058.8, "end": 1059.4, "word": " او", "probability": 0.817138671875}, {"start": 1059.4, "end": 1060.26, "word": " sideways", "probability": 0.5751953125}, {"start": 1060.26, "end": 1061.94, "word": " backing", "probability": 0.07843017578125}], "temperature": 1.0}, {"id": 39, "seek": 108280, "start": 1064.24, "end": 1082.8, "text": "من جنب او crushing يعني بيصير فيه تكسير يعني بيصير كأنه بتكسر و بصرع لعب بيصير bending طبيعي plain cross sections remain plain نتيجة ال bending بيصير rotation في المستويات يعني المستوي في الأول بيكون مستوي", "tokens": [27842, 10874, 1863, 3555, 1975, 2407, 31317, 37495, 22653, 4724, 1829, 9381, 13546, 8978, 3224, 6055, 4117, 3794, 13546, 37495, 22653, 4724, 1829, 9381, 13546, 9122, 33456, 3224, 39894, 4117, 3794, 2288, 4032, 4724, 9381, 2288, 3615, 5296, 3615, 3555, 4724, 1829, 9381, 13546, 22487, 23032, 21292, 3615, 1829, 11121, 3278, 10863, 6222, 11121, 8717, 31371, 7435, 3660, 2423, 22487, 4724, 1829, 9381, 13546, 12447, 8978, 9673, 14851, 45865, 9307, 37495, 22653, 9673, 14851, 45865, 8978, 16247, 12610, 4724, 1829, 30544, 3714, 14851, 45865], "avg_logprob": -0.2077205910402186, "compression_ratio": 1.7458563535911602, "no_speech_prob": 3.635883331298828e-06, "words": [{"start": 1064.24, "end": 1064.46, "word": "من", "probability": 0.277099609375}, {"start": 1064.46, "end": 1064.94, "word": " جنب", "probability": 0.8592122395833334}, {"start": 1064.94, "end": 1065.76, "word": " او", "probability": 0.760986328125}, {"start": 1065.76, "end": 1066.26, "word": " crushing", "probability": 0.60888671875}, {"start": 1066.26, "end": 1066.76, "word": " يعني", "probability": 0.895263671875}, {"start": 1066.76, "end": 1067.24, "word": " بيصير", "probability": 0.8408203125}, {"start": 1067.24, "end": 1067.42, "word": " فيه", "probability": 0.89990234375}, {"start": 1067.42, "end": 1067.92, "word": " تكسير", "probability": 0.9677734375}, {"start": 1067.92, "end": 1068.12, "word": " يعني", "probability": 0.8671875}, {"start": 1068.12, "end": 1068.5, "word": " بيصير", "probability": 0.833984375}, {"start": 1068.5, "end": 1069.06, "word": " كأنه", "probability": 0.9498697916666666}, {"start": 1069.06, "end": 1070.4, "word": " بتكسر", "probability": 0.9400634765625}, {"start": 1070.4, "end": 1070.48, "word": " و", "probability": 0.6123046875}, {"start": 1070.48, "end": 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واحد الحالة ال general ان بيكونت two plane bending يعني في بنجي حوالين محور هذا و في بنجي حوالين محور هذا يعني مثلا لو عندى Cantilever", "tokens": [6027, 5016, 6027, 3660, 16247, 12610, 7578, 21136, 16758, 28671, 13672, 7578, 11778, 23557, 3794, 8315, 11296, 25961, 2655, 472, 5720, 22487, 37495, 22653, 2423, 22487, 11331, 2407, 6027, 9957, 3714, 14851, 2407, 7578, 36764, 24401, 21542, 6027, 3660, 2423, 2674, 16472, 4724, 1829, 30544, 2655, 732, 5720, 22487, 37495, 22653, 8978, 44945, 7435, 1829, 11331, 2407, 6027, 9957, 3714, 5016, 13063, 23758, 4032, 8978, 44945, 7435, 1829, 11331, 2407, 6027, 9957, 3714, 5016, 13063, 23758, 37495, 22653, 50113, 15040, 45164, 43242, 7578, 26697, 794, 331], "avg_logprob": -0.20061062841579833, "compression_ratio": 1.8770053475935828, "no_speech_prob": 0.0, "words": [{"start": 2678.06, "end": 2678.68, "word": "الحالة", "probability": 0.970947265625}, {"start": 2678.68, "end": 2678.92, "word": " الأولى", "probability": 0.9456380208333334}, {"start": 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"end": 2693.14, "word": " عندى", "probability": 0.631591796875}, {"start": 2693.14, "end": 2693.8, "word": " Cantilever", "probability": 0.6555989583333334}], "temperature": 1.0}, {"id": 94, "seek": 273927, "start": 2713.79, "end": 2739.27, "text": "و في عندى force هاي F و في عندى force بهذا الاتجاه P وهي ال X Axis وهي ال Y Axis وهي ال Z Axis في بننج نتيجة ال F حوالي ال Z Axis و في بننج حوالي ال Y Axis", "tokens": [2407, 8978, 43242, 7578, 3464, 8032, 47302, 479, 4032, 8978, 43242, 7578, 3464, 39627, 15730, 2423, 9307, 7435, 40294, 430, 37037, 1829, 2423, 1783, 20118, 271, 37037, 1829, 2423, 398, 20118, 271, 37037, 1829, 2423, 1176, 20118, 271, 8978, 44945, 1863, 7435, 8717, 31371, 7435, 3660, 2423, 479, 11331, 2407, 6027, 1829, 2423, 1176, 20118, 271, 4032, 8978, 44945, 1863, 7435, 11331, 2407, 6027, 1829, 2423, 398, 20118, 271], "avg_logprob": -0.2003348158938544, "compression_ratio": 1.8412698412698412, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2713.79, "end": 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{"start": 2738.31, "end": 2738.55, "word": " حوالي", "probability": 0.98095703125}, {"start": 2738.55, "end": 2738.65, "word": " ال", "probability": 0.935546875}, {"start": 2738.65, "end": 2738.81, "word": " Y", "probability": 0.98486328125}, {"start": 2738.81, "end": 2739.27, "word": " Axis", "probability": 0.9873046875}], "temperature": 1.0}, {"id": 95, "seek": 276877, "start": 2740.35, "end": 2768.77, "text": "فاحد بيسميها two plane bending يعني في عندى bending في المستويات في ال XY plane و في ال XZ plane ال .. ال .. ال moment ال sigma X بيساوي minus MZY على IZ", "tokens": [5172, 995, 24401, 4724, 1829, 38251, 1829, 11296, 732, 5720, 22487, 37495, 22653, 8978, 43242, 7578, 22487, 8978, 9673, 14851, 45865, 9307, 8978, 2423, 48826, 5720, 4032, 8978, 2423, 1783, 57, 5720, 2423, 4386, 2423, 4386, 2423, 1623, 2423, 12771, 1783, 4724, 1829, 3794, 995, 45865, 3175, 376, 26888, 15844, 286, 57], "avg_logprob": -0.3449292452830189, "compression_ratio": 1.435374149659864, "no_speech_prob": 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الأمور بتكون أسهل بحكي ال sigma maximum سواء M في C على I", "tokens": [11622, 16373, 3215, 16322, 1176, 15844, 286, 56, 34105, 6055, 5016, 4117, 1829, 22487, 11331, 2407, 6027, 1829, 1176, 10298, 37037, 24192, 22487, 11331, 2407, 6027, 9957, 2423, 398, 10298, 8978, 11331, 6027, 3660, 9673, 47432, 3615, 9122, 7649, 3714, 3215, 13063, 16247, 2304, 13063, 39894, 30544, 5551, 3794, 3224, 1211, 4724, 5016, 4117, 1829, 2423, 12771, 6674, 8608, 2407, 16606, 376, 8978, 383, 15844, 286], "avg_logprob": -0.3801306014630332, "compression_ratio": 1.4082840236686391, "no_speech_prob": 5.364418029785156e-07, "words": [{"start": 2770.4, "end": 2771.12, "word": "زائد", "probability": 0.53857421875}, {"start": 2771.12, "end": 2771.9, "word": " MY", "probability": 0.367919921875}, {"start": 2771.9, "end": 2773.84, "word": " Z", "probability": 0.479248046875}, {"start": 2773.84, "end": 2774.92, "word": " على", "probability": 0.390869140625}, {"start": 2774.92, "end": 2776.22, "word": " IY", 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"probability": 0.978515625}, {"start": 3443.6, "end": 3443.8, "word": " اللي", "probability": 0.95458984375}, {"start": 3443.8, "end": 3443.88, "word": " هي", "probability": 0.81689453125}, {"start": 3443.88, "end": 3444.02, "word": " 0", "probability": 0.94677734375}, {"start": 3444.02, "end": 3444.62, "word": ".375", "probability": 0.89501953125}], "temperature": 1.0}, {"id": 119, "seek": 347687, "start": 3449.77, "end": 3476.87, "text": "على ال IY اللي هي point O خمسة اتنين سبعة تلاتة PSI لاحظين نفس الرقم", "tokens": [3615, 23942, 2423, 286, 56, 13672, 1829, 39896, 935, 422, 16490, 2304, 3794, 3660, 1975, 2655, 1863, 9957, 8608, 3555, 27884, 6055, 1211, 9307, 3660, 8168, 40, 20193, 5016, 19913, 9957, 8717, 36178, 34892, 4587, 2304], "avg_logprob": -0.21209882401131294, "compression_ratio": 1.121212121212121, "no_speech_prob": 0.0, "words": [{"start": 3449.77, "end": 3450.13, "word": "على", "probability": 0.86572265625}, {"start": 3450.13, "end": 3450.33, "word": " ال", 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0.983642578125}, {"start": 3476.45, "end": 3476.87, "word": " الرقم", "probability": 0.9903971354166666}], "temperature": 1.0}, {"id": 120, "seek": 350954, "start": 3480.26, "end": 3509.54, "text": "هو اكيد نفس الرقم بس مع التقريبات ماشي مش مشكلة هي مش بالضروري تطلع نفس الرقم بس صدفة معناه طيب او هو ال example هيك مبرمج معناته عند النقطة هذه خلينا نسمي هذه النقطة a ال sigma عند a هتكون sigma عند t z زي ال sigma t y", "tokens": [3224, 2407, 1975, 4117, 25708, 8717, 36178, 34892, 4587, 2304, 4724, 3794, 20449, 16712, 4587, 16572, 3555, 9307, 3714, 33599, 1829, 37893, 37893, 28820, 3660, 39896, 37893, 20666, 11242, 2288, 13063, 1829, 6055, 9566, 1211, 3615, 8717, 36178, 34892, 4587, 2304, 4724, 3794, 20328, 3215, 5172, 3660, 20449, 8315, 3224, 23032, 1829, 3555, 1975, 2407, 31439, 2423, 1365, 39896, 4117, 3714, 26890, 2304, 7435, 20449, 8315, 47395, 43242, 28239, 47432, 3660, 29538, 16490, 20292, 8315, 8717, 38251, 1829, 29538, 28239, 47432, 3660, 257, 2423, 12771, 43242, 257, 8032, 2655, 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ال", "probability": 0.74951171875}, {"start": 3506.86, "end": 3507.26, "word": " sigma", "probability": 0.96875}, {"start": 3507.26, "end": 3507.86, "word": " t", "probability": 0.2998046875}, {"start": 3507.86, "end": 3509.54, "word": " y", "probability": 0.94677734375}], "temperature": 1.0}, {"id": 121, "seek": 354204, "start": 3512.58, "end": 3542.04, "text": "هتكون اللي هي خمس تلف ستمية وتسعين في اتنين اللي هي اكم احداشر الف تلتمية تسعة و ستمانية PSI وعند B هذه النقطة Sigma B هتكون minus Sigma A يعني هتكون احداشر الف تلتمية", "tokens": [3224, 2655, 30544, 13672, 1829, 39896, 16490, 2304, 3794, 6055, 1211, 5172, 8608, 39237, 10632, 34683, 3794, 3615, 9957, 8978, 1975, 2655, 1863, 9957, 13672, 1829, 39896, 1975, 24793, 1975, 24401, 33599, 2288, 27188, 6055, 1211, 2655, 2304, 10632, 6055, 3794, 27884, 4032, 8608, 2655, 2304, 7649, 10632, 8168, 40, 4032, 3615, 41260, 363, 29538, 28239, 47432, 3660, 36595, 363, 8032, 2655, 30544, 3175, 36595, 316, 37495, 22653, 8032, 2655, 30544, 1975, 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"end": 4319.25, "word": " تلاف", "probability": 0.7317708333333334}, {"start": 4319.25, "end": 4319.67, "word": " وتسعة", "probability": 0.7505696614583334}, {"start": 4319.67, "end": 4320.05, "word": " تلاف", "probability": 0.80908203125}, {"start": 4320.05, "end": 4321.07, "word": " وتسعة", "probability": 0.7462565104166666}, {"start": 4321.07, "end": 4321.55, "word": " تلاف", "probability": 0.89013671875}, {"start": 4321.55, "end": 4322.23, "word": " وتسعة", "probability": 0.8111165364583334}, {"start": 4322.23, "end": 4322.23, "word": " تلاف", "probability": 0.9181315104166666}, {"start": 4322.23, "end": 4323.35, "word": " وتسعة", "probability": 0.8427734375}, {"start": 4323.35, "end": 4323.35, "word": " تلاف", "probability": 0.9348958333333334}, {"start": 4323.35, "end": 4324.11, "word": " وتسعة", "probability": 0.841796875}, {"start": 4324.11, "end": 4325.07, "word": " تلاف", "probability": 0.9436848958333334}, {"start": 4325.07, "end": 4326.13, "word": " تسعة", "probability": 0.775390625}, {"start": 4326.13, "end": 4326.31, "word": " تلاف", "probability": 0.9417317708333334}, {"start": 4326.31, "end": 4326.31, "word": " تسعة", "probability": 0.802001953125}, {"start": 4326.31, "end": 4326.51, "word": " تلاف", "probability": 0.9462890625}, {"start": 4326.51, "end": 4326.51, "word": " تسعة", "probability": 0.8473307291666666}, {"start": 4326.51, "end": 4326.53, "word": " تلاف", "probability": 0.94580078125}, {"start": 4326.53, "end": 4326.53, "word": " تسعة", "probability": 0.8904622395833334}, {"start": 4326.53, "end": 4326.53, "word": " تلاف", "probability": 0.94970703125}, {"start": 4326.53, "end": 4326.53, "word": " تسعة", "probability": 0.9200846354166666}, {"start": 4326.53, "end": 4326.53, "word": " تلاف", "probability": 0.9524739583333334}, {"start": 4326.53, "end": 4326.53, "word": " تسعة", "probability": 0.9397786458333334}, {"start": 4326.53, "end": 4326.59, "word": " تلاف", "probability": 0.9571940104166666}, {"start": 4326.59, "end": 4327.07, "word": " تسعة", "probability": 0.9521484375}, {"start": 4327.07, "end": 4327.43, "word": " تلاف", "probability": 0.96044921875}, {"start": 4327.43, "end": 4327.43, "word": " تسعة", "probability": 0.9619140625}, {"start": 4327.43, "end": 4327.73, "word": " تلاف", "probability": 0.96337890625}, {"start": 4327.73, "end": 4329.19, "word": " تسعة", "probability": 0.9685872395833334}, {"start": 4329.19, "end": 4329.89, "word": " تلاف", "probability": 0.9656575520833334}, {"start": 4329.89, "end": 4329.97, "word": " تسعة", "probability": 0.9737955729166666}, {"start": 4329.97, "end": 4329.97, "word": " تلاف", "probability": 0.96875}, {"start": 4329.97, "end": 4330.35, "word": " تسعة", "probability": 0.9765625}, {"start": 4330.35, "end": 4330.35, "word": " تلاف", "probability": 0.9703776041666666}, {"start": 4330.35, "end": 4330.35, "word": " تسعة", "probability": 0.9794921875}, {"start": 4330.35, "end": 4330.35, "word": " تلاف", "probability": 0.97216796875}, {"start": 4330.35, "end": 4330.35, "word": " تسعة", "probability": 0.98095703125}, {"start": 4330.35, "end": 4330.35, "word": " تلاف", "probability": 0.97265625}, {"start": 4330.35, "end": 4330.35, "word": " تسعة", "probability": 0.9820963541666666}, {"start": 4330.35, "end": 4330.35, "word": " تلاف", "probability": 0.97412109375}, {"start": 4330.35, "end": 4330.35, "word": " تسعة", "probability": 0.982421875}, {"start": 4330.35, "end": 4330.35, "word": " تلاف", "probability": 0.9752604166666666}, {"start": 4330.35, "end": 4330.37, "word": " تسعة", "probability": 0.9832356770833334}, {"start": 4330.37, "end": 4330.45, "word": " تلاف", "probability": 0.9757486979166666}, {"start": 4330.45, "end": 4330.65, "word": " تسعة", "probability": 0.9833984375}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.9768880208333334}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.98291015625}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.9768880208333334}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.98193359375}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.97802734375}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.9816080729166666}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.97900390625}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.9812825520833334}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.97998046875}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.9806315104166666}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.9806315104166666}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.97900390625}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.9817708333333334}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.9791666666666666}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.9817708333333334}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.9777018229166666}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.9820963541666666}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.9767252604166666}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.9817708333333334}, {"start": 4330.65, "end": 4330.65, "word": " تسعة", "probability": 0.9757486979166666}, {"start": 4330.65, "end": 4330.65, "word": " تلاف", "probability": 0.98291015625}, {"start": 4330.65, "end": 4330.71, "word": " تسعة", "probability": 0.97509765625}, {"start": 4330.71, "end": 4330.97, "word": " تلاف", "probability": 0.9827473958333334}, {"start": 4330.97, "end": 4339.17, "word": " تسعة", "probability": 0.9742838541666666}, {"start": 4339.17, "end": 4339.83, "word": " تلاف", "probability": 0.9825846354166666}, {"start": 4339.83, "end": 4346.85, "word": " تسعة", "probability": 0.9724934895833334}, {"start": 4346.85, "end": 4347.63, "word": " تلاف", "probability": 0.9791666666666666}, {"start": 4347.63, "end": 4347.89, "word": " تس", "probability": 0.989990234375}], "temperature": 1.0}, {"id": 148, "seek": 438931, "start": 4371.33, "end": 4389.31, "text": "أتطلع تسعة تلاف؟ و أكام؟ هذا مدور، هذا بيم تان مختلف تيك ولا عافاك كمان خلصنا المحاضرة", "tokens": [10721, 2655, 9566, 1211, 3615, 6055, 3794, 27884, 6055, 15040, 5172, 22807, 4032, 5551, 4117, 10943, 22807, 23758, 3714, 3215, 13063, 12399, 23758, 4724, 32640, 6055, 7649, 3714, 46456, 46538, 6055, 1829, 4117, 49429, 6225, 31845, 995, 4117, 9122, 2304, 7649, 16490, 1211, 9381, 8315, 9673, 5016, 46958, 25720], "avg_logprob": -0.46062499940395357, "compression_ratio": 1.4181818181818182, "no_speech_prob": 0.0, "words": [{"start": 4371.33, "end": 4371.83, "word": "أتطلع", "probability": 0.5949462890625}, {"start": 4371.83, "end": 4372.07, "word": " تسعة", "probability": 0.9375}, {"start": 4372.07, "end": 4372.85, "word": " تلاف؟", "probability": 0.604736328125}, {"start": 4372.85, "end": 4373.81, "word": " و", "probability": 0.72705078125}, {"start": 4373.81, "end": 4375.01, "word": " أكام؟", "probability": 0.62799072265625}, {"start": 4375.01, "end": 4382.93, "word": " هذا", "probability": 0.33447265625}, {"start": 4382.93, "end": 4383.39, "word": " مدور،", "probability": 0.67633056640625}, {"start": 4383.39, "end": 4383.55, "word": " هذا", "probability": 0.755859375}, {"start": 4383.55, "end": 4384.39, "word": " بيم", "probability": 0.552978515625}, {"start": 4384.39, "end": 4384.65, "word": " تان", "probability": 0.745361328125}, {"start": 4384.65, "end": 4385.23, "word": " مختلف", "probability": 0.9248046875}, {"start": 4385.23, "end": 4387.67, "word": " تيك", "probability": 0.455810546875}, {"start": 4387.67, "end": 4387.75, "word": " ولا", "probability": 0.64111328125}, {"start": 4387.75, "end": 4388.07, "word": " عافاك", "probability": 0.59747314453125}, {"start": 4388.07, "end": 4388.31, "word": " كمان", 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/PdQg4WWo-pI_postprocess.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/PdQg4WWo-pI_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d0b7d365bd34ab8788e2c6656c0ffe6dd626f7b6
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/PdQg4WWo-pI_postprocess.srt
@@ -0,0 +1,2500 @@
+1
+00:00:05,770 --> 00:00:09,130
+طيب بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:09,130 --> 00:00:12,290
+وبركاته اليوم هنبدأ محاضرة زيدة في مادة تصميم
+
+3
+00:00:12,290 --> 00:00:16,590
+الألات هتكون chapter اللي هو load and stress
+
+4
+00:00:16,590 --> 00:00:20,370
+analysis ال chapter هذا فيه مراجعة على مادة
+
+5
+00:00:20,370 --> 00:00:24,990
+mechanics of material في إضافات أكتر على مستوى على
+
+6
+00:00:24,990 --> 00:00:28,890
+شوية من ال mechanics of material من حيث الموضوعات
+
+7
+00:00:28,890 --> 00:00:31,210
+أو من حيث العمق في التحليل
+
+8
+00:00:34,340 --> 00:00:39,800
+هنبدأ في ال shear و ال .. ال .. ال .. و ال bending
+
+9
+00:00:39,800 --> 00:00:47,060
+moment diagrams و كيفية حسابه
+
+10
+00:00:47,060 --> 00:00:54,260
+ان بيه عندى beam فى عندى beam فى support على أطراف
+
+11
+00:00:54,260 --> 00:00:58,440
+فى support على الطرف الأيصر و support على الطرف
+
+12
+00:00:58,440 --> 00:01:02,800
+الأيمن المحاور اللى هو عندى X
+
+13
+00:01:05,840 --> 00:01:15,760
+هذا المحور Y فين دي force F1 تأثر هنا فين F2 و F3
+
+14
+00:01:15,760 --> 00:01:22,260
+طبعا هكون فين دي رد فعل R1 وهين
+
+15
+00:01:22,260 --> 00:01:33,550
+رد فعل R2 لو أخدت section على بعد X1وعملت free
+
+16
+00:01:33,550 --> 00:01:37,650
+body diagram هيكون
+
+17
+00:01:37,650 --> 00:01:43,450
+عندهين هاي المسافة X واحد هاي R واحد طبعا هاد ال X
+
+18
+00:01:43,450 --> 00:01:51,310
+هاد ال Y وعند ال force F واحد هيكون عكس الرد الفعل
+
+19
+00:01:51,310 --> 00:01:54,870
+shear force V
+
+20
+00:01:57,260 --> 00:02:03,120
+و بندق moment M كي share force يلا اخدت ال moment
+
+21
+00:02:03,120 --> 00:02:04,720
+حوالين هذه هتكون عنده
+
+22
+00:02:08,670 --> 00:02:13,290
+الار واحد هتروح هتكون F واحد في المسافة بتاعتها
+
+23
+00:02:13,290 --> 00:02:16,350
+زائد
+
+24
+00:02:16,350 --> 00:02:22,830
+V في X واحد minus M بالساوياش Zero و لو أخرص ماشي
+
+25
+00:02:22,830 --> 00:02:28,150
+ال force باتجاه ال Y بتكون R واحد بالساوياش F واحد
+
+26
+00:02:28,150 --> 00:02:32,650
+زائد V الأن
+
+27
+00:02:32,650 --> 00:02:37,200
+أنا أخدت section هنا على البعد X واحدفكان عندي ..
+
+28
+00:02:37,200 --> 00:02:41,800
+عندي section عندي shear force V و M لو أخدت
+
+29
+00:02:41,800 --> 00:02:48,100
+another section على بعد delta
+
+30
+00:02:48,100 --> 00:02:53,940
+X و
+
+31
+00:02:53,940 --> 00:03:01,040
+أخدت ال section اللي انطلعته كان
+
+32
+00:03:01,040 --> 00:03:02,220
+عندي هنا V
+
+33
+00:03:13,420 --> 00:03:20,620
+وعندي counter clause M هيكون
+
+34
+00:03:20,620 --> 00:03:25,980
+هنا معاكس له M
+
+35
+00:03:25,980 --> 00:03:35,960
+زاد delta M و لو حكي هنا عايش V هذه المسافة
+
+36
+00:03:51,650 --> 00:03:59,350
+الان بعتبر moment موجبة اذا بتحاول تتنى ال beam
+
+37
+00:03:59,350 --> 00:04:04,470
+لتحت تخلى ال moment موجبة اذا بتحاول تخلى ال beam
+
+38
+00:04:04,470 --> 00:04:08,330
+بالشكل هذا يعني اذا في عندى moment بالشكل هذا
+
+39
+00:04:11,600 --> 00:04:15,540
+هي تعتبر positive bending moment positive bending
+
+40
+00:04:15,540 --> 00:04:22,240
+moment اذا
+
+41
+00:04:22,240 --> 00:04:25,860
+هو يبين دي هين فهي positive bending moment وبعرف
+
+42
+00:04:25,860 --> 00:04:28,680
+انا باخد small increment delta X يعني في الحالة
+
+43
+00:04:28,680 --> 00:04:35,200
+هذه moment هين موجب ولا سلبه سلبه اذا كانت العكس
+
+44
+00:04:35,200 --> 00:04:39,460
+ايش هتكون هين سلبه هين موجبه ال shear force
+
+45
+00:04:46,160 --> 00:04:49,340
+هذا positive وهذا negative حالتنا مش هتكون المبينة
+
+46
+00:04:49,340 --> 00:04:56,100
+عندى هنا negative share negative share بشكل عام
+
+47
+00:04:56,100 --> 00:04:59,420
+عشان مافكرش كتير فيها بناء على ال convention هذا
+
+48
+00:04:59,420 --> 00:05:08,040
+إذا باخد section اللى على الشمال أخد الجزء هذا اه
+
+49
+00:05:08,040 --> 00:05:12,400
+فانا الأصل أخدت ال section أنا عندى هنا أخدت
+
+50
+00:05:12,400 --> 00:05:21,870
+section هناهذا هتكون ال V عكس مظبوط و ال moment
+
+51
+00:05:21,870 --> 00:05:30,130
+عكسه ال moment عكس و ال V عكس واضح يعني انا باخد
+
+52
+00:05:30,130 --> 00:05:34,350
+يا جهة الشمال او الجهة اليامين لو خدت الجهة
+
+53
+00:05:34,350 --> 00:05:39,990
+اليامين هتكون ال V عكس ال V و ال M عكس ال M بشكل
+
+54
+00:05:39,990 --> 00:05:40,270
+عام
+
+55
+00:05:43,270 --> 00:05:47,230
+إذا خدت الفريقة دي جرام من الشمال و كان الشير لتح
+
+56
+00:05:47,230 --> 00:05:49,870
+هذا positive شير و إذا كانت ال bending moment
+
+57
+00:05:49,870 --> 00:05:52,850
+counter clockwise بعكس عقارب الساعة بتكون إيش
+
+58
+00:05:52,850 --> 00:05:58,330
+positive دي
+
+59
+00:05:58,330 --> 00:06:05,210
+اتأكد أنا positive ولا negative بناخد
+
+60
+00:06:05,210 --> 00:06:09,530
+زي ما حكينا هاي ال section تكملته هنا هكون V هكون
+
+61
+00:06:09,530 --> 00:06:17,500
+عكسها Vو ال moment هيكون هاي عكسها و باخد
+
+62
+00:06:17,500 --> 00:06:22,260
+increment على جواه دلتا X هيكون هاي دي moment و
+
+63
+00:06:22,260 --> 00:06:26,440
+هاي V هذي الحالة تمثل positive moment و positive
+
+64
+00:06:26,440 --> 00:06:31,740
+share معناته
+
+65
+00:06:31,740 --> 00:06:37,680
+بشكل تلقائي بتكون share is positiveإذا كان نازل
+
+66
+00:06:37,680 --> 00:06:42,040
+لتحت و ماخد ال section على الشمال و ال moment تكون
+
+67
+00:06:42,040 --> 00:06:50,280
+بعكس عقارب الساعة بعتبرها positive عندى
+
+68
+00:06:50,280 --> 00:06:54,540
+beam simply supported beam في عندى عليه
+
+69
+00:06:54,540 --> 00:07:00,820
+distributed load QX يعني load per unit length load
+
+70
+00:07:00,820 --> 00:07:07,050
+موزع يعني حمل لكل وحدة طولمن ال mechanics of
+
+71
+00:07:07,050 --> 00:07:14,550
+material كان في عندنا علاقات اللي هي V بيساوي DM
+
+72
+00:07:14,550 --> 00:07:23,890
+by DX ال shear force بيساوي DM by DX هذا في ال
+
+73
+00:07:23,890 --> 00:07:30,670
+mechanics of material معناه دي DM بيساوي
+
+74
+00:07:30,670 --> 00:07:47,050
+V DXلو أخد التكامل بين a و b ما ل mb وهنا من xa ل
+
+75
+00:07:47,050 --> 00:07:59,790
+xb هكون ان ال mb minus ma بالساوية تكامل vdx من xa
+
+76
+00:07:59,790 --> 00:08:15,150
+ل xb يعني ال mbبستوى MA زائد تكامل XA ل XB VDX
+
+77
+00:08:15,150 --> 00:08:22,850
+يعني ال B اللي انتوا شايفينه هنا لاخد
+
+78
+00:08:22,850 --> 00:08:30,810
+سكشن هذه A نقطة A وهذه نقطة B يعني هذا هكون XA
+
+79
+00:08:34,850 --> 00:08:44,530
+وها دي إيش XB المعادرة
+
+80
+00:08:44,530 --> 00:08:49,650
+بتحكي ال moment عند B بتساوي
+
+81
+00:08:49,650 --> 00:08:56,930
+بين moment عند A زاد المساحة تحت منحنى الشير بين
+
+82
+00:08:56,930 --> 00:09:04,290
+XA و XBالـ moment عند B سواء الـ moment عند A زاد
+
+83
+00:09:04,290 --> 00:09:15,270
+المساحة تحت منحنة الـ shear من XA ل XB نفس
+
+84
+00:09:15,270 --> 00:09:22,010
+الشيء فيه عندنا علاقة اللي هو DV by DX بالسواء الـ
+
+85
+00:09:22,010 --> 00:09:24,550
+Q الـ Q اللي هو الـ distributed load load لكل
+
+86
+00:09:24,550 --> 00:09:25,610
+واحدة طول
+
+87
+00:09:29,210 --> 00:09:40,330
+بسوة Q DX وانا بعمل تكامل بين XA ل XB بين VA ل VB
+
+88
+00:09:40,330 --> 00:09:50,010
+يعني انا هكون عندي VB minus VA بسوة تكامل Q DX من
+
+89
+00:09:50,010 --> 00:10:05,040
+XA ل XB يعني VBبالساوية VA زائد تكامل QDX من XA ل
+
+90
+00:10:05,040 --> 00:10:14,240
+XB يعني ال shear and B ال shear and B بالساوية
+
+91
+00:10:14,240 --> 00:10:19,900
+shear and A زائد المساحة تحت منحنة ل Q مع ال X بين
+
+92
+00:10:19,900 --> 00:10:21,940
+XA و XB اللي هي هذه المعادلة
+
+93
+00:10:31,850 --> 00:10:46,970
+نحل مثال derive the
+
+94
+00:10:46,970 --> 00:10:51,450
+loading shear force and bending moment diagrams
+
+95
+00:10:51,450 --> 00:11:01,200
+for the beam shown and beam and رد فعلR1 وR2 هاي
+
+96
+00:11:01,200 --> 00:11:06,560
+ال X axis هاي ال Y axis فاندي load 200 pound بيأثر
+
+97
+00:11:06,560 --> 00:11:11,340
+على بعد 4 انش واندي load 100 pound بيأثر على بعد
+
+98
+00:11:11,340 --> 00:11:16,760
+10 انش و ال beam طوله 20 انش بدنا نحسب ال reaction
+
+99
+00:11:16,760 --> 00:11:24,480
+forces و ال shear diagram و ال moment diagram اول
+
+100
+00:11:24,480 --> 00:11:29,420
+خطوة حاولي ادقاشreactions يعني انا اخدت ال moment
+
+101
+00:11:29,420 --> 00:11:38,500
+حوالين هاي عندى ال X هاي ال Y يعني انا اخدت ال
+
+102
+00:11:38,500 --> 00:11:43,600
+moment حوالين ال O summation للمoment حوالين ال O
+
+103
+00:11:43,600 --> 00:11:49,900
+بالساوة 0 و اعتبر عكس عقار السي عاش موجب بالساوة
+
+104
+00:11:49,900 --> 00:12:02,910
+هكون minus 200 في 4مينوس متين في أربعة مينوس مية
+
+105
+00:12:02,910 --> 00:12:07,970
+في عشرة زاد
+
+106
+00:12:07,970 --> 00:12:13,250
+عشرين R اتنين ومنها
+
+107
+00:12:13,250 --> 00:12:17,790
+R اتنين تطلع
+
+108
+00:12:17,790 --> 00:12:20,910
+التمنمية
+
+109
+00:12:22,600 --> 00:12:34,460
+أو الف تونمية على عشرين تسعين تسعين pound بعد
+
+110
+00:12:34,460 --> 00:12:39,820
+أن باخد summation لل forces باتجاه ال Y الصوت Zero
+
+111
+00:12:39,820 --> 00:12:44,520
+هكون
+
+112
+00:12:44,520 --> 00:12:48,840
+دي R واحد ناقص
+
+113
+00:12:48,840 --> 00:12:50,460
+متين
+
+114
+00:12:52,380 --> 00:13:03,600
+minus 100 زائد 90 يعني R1 بستوى تلت مية ناقص تسعين
+
+115
+00:13:03,600 --> 00:13:13,720
+متين و عشرة pound force هيك
+
+116
+00:13:13,720 --> 00:13:17,800
+أنا عرفت ال reactions هرسم ال shear diagram
+
+117
+00:13:24,750 --> 00:13:47,050
+و ال moment ده يجرأ حيبدأ
+
+118
+00:13:47,050 --> 00:13:51,370
+عند R1 يعني عند R1 210 حد من هنا 210
+
+119
+00:13:55,650 --> 00:14:07,590
+بعدين هترح ايش؟ متين متين بيضل ايش؟ عشرة هضل
+
+120
+00:14:07,590 --> 00:14:11,570
+ماشي هترح
+
+121
+00:14:11,570 --> 00:14:19,770
+مية هي سالب هضل
+
+122
+00:14:19,770 --> 00:14:26,430
+سالب تسعين وبعدين هطلع كمان تسعينمعناته هو هذا
+
+123
+00:14:26,430 --> 00:14:30,530
+الشير
+
+124
+00:14:30,530 --> 00:14:40,410
+ده جرام هذا
+
+125
+00:14:40,410 --> 00:14:46,030
+الشير ال
+
+126
+00:14:46,030 --> 00:14:46,670
+bedding moment
+
+127
+00:14:59,490 --> 00:15:08,250
+الـ moment عند O اشو الساوية عند O سفر هبدأ من سفر
+
+128
+00:15:08,250 --> 00:15:18,770
+هنحكي هنا اللي هو ال M B بسوء
+
+129
+00:15:18,770 --> 00:15:28,140
+M A زائد تكامل Vمن XA ل XB هذا الشكل العام لأن
+
+130
+00:15:28,140 --> 00:15:32,400
+معناته عند النقطة هذه عند النقطة هذه ال moment هي
+
+131
+00:15:32,400 --> 00:15:36,140
+نحسبها moment هي صفر زاد المساحة هذه يعني هتكون
+
+132
+00:15:36,140 --> 00:15:41,700
+عشرين متين و عشرة في أربعة تمامية و أربعين هذه
+
+133
+00:15:41,700 --> 00:15:47,580
+هتتمثل تمثل slope ل ال moment معناته هتكون هذه من
+
+134
+00:15:47,580 --> 00:15:50,400
+الدرجة الأولى slope constant يعني هتكون متين و
+
+135
+00:15:50,400 --> 00:15:50,780
+عشرة
+
+136
+00:15:57,420 --> 00:16:10,380
+تمنين و أربعين مظبوط تمنين و أربعين pound inch ال
+
+137
+00:16:10,380 --> 00:16:16,260
+moment عند النقطة هذه زاد المساحة هذه المساحة هذه
+
+138
+00:16:16,260 --> 00:16:21,840
+أكم ستة هذه ستة فعشرة ستة يعني تمنين و أربعين و
+
+139
+00:16:21,840 --> 00:16:28,450
+ستين تسع مية ال slope هنا شوف كم هو قيمتهأقل اقل
+
+140
+00:16:28,450 --> 00:16:37,270
+يعني مش هكون اعلى هيكون زي هيك هذا هتكون تسعمية
+
+141
+00:16:37,270 --> 00:16:44,290
+هنا المساحة ال moment هنا اللي هي تسعمية زي
+
+142
+00:16:44,290 --> 00:16:48,570
+المساحة هذه المساحة هذه هتكون بالسالف هتكون عندى
+
+143
+00:16:48,570 --> 00:16:53,070
+هذه عشرة تسعين
+
+144
+00:16:53,070 --> 00:16:55,930
+في عشرة تسعمية تسعمية نقص تسعمية صفر
+
+145
+00:17:00,850 --> 00:17:03,130
+فهي كتير مش sign convention انه في ال moment the
+
+146
+00:17:03,130 --> 00:17:08,430
+ground يكون الموجة لتحت و الساقية للأعلى؟ لأ لأ لأ
+
+147
+00:17:08,430 --> 00:17:11,490
+انت علي حالة بتعمل convention اللي بدك هي فرضي
+
+148
+00:17:11,490 --> 00:17:13,910
+يعني بس انت في الآخر نعمل .. احنا عاملين
+
+149
+00:17:13,910 --> 00:17:17,370
+convention متفق عليه، هيك عالميا أقول أكيد ما
+
+150
+00:17:17,370 --> 00:17:19,790
+أخدناها كانوا يقولون أنه ال .. sign convention
+
+151
+00:17:19,790 --> 00:17:22,670
+لتحت الموجة و الساقية لأعلى أنا ماعرفش في أي سياق
+
+152
+00:17:22,670 --> 00:17:27,510
+ذكرت عشان انا مش ه .. مش هجاوبك اهطب طب مثلا ال
+
+153
+00:17:27,510 --> 00:17:30,030
+study دي زي ايه؟ تكون ال sheer و ال moment دايما
+
+154
+00:17:30,030 --> 00:17:33,650
+ساوة و صفرة و داخرة و حنصل على الفرق؟ لأ مش
+
+155
+00:17:33,650 --> 00:17:37,370
+بالضرورة هتكون ساوة و صفرة، لو عندك cantilever و
+
+156
+00:17:37,370 --> 00:17:41,010
+عليه مثلا moment عليه في الطرف، فتكون سافرش، في
+
+157
+00:17:41,010 --> 00:17:46,370
+الحالة، في ال study supported، بيكوناش ساوة و صفرة
+
+158
+00:17:46,370 --> 00:17:48,430
+و ال sheer برضه زيه؟
+
+159
+00:17:54,310 --> 00:17:59,830
+فى الآخر فى الآخر برا حدود ال beam مثلا عندك ال
+
+160
+00:17:59,830 --> 00:18:06,790
+beam طوله L ال XL بيستوى L plus مافيش هى لا شير
+
+161
+00:18:06,790 --> 00:18:12,830
+ولا ممد وال X بيستوى Zero minus مافيش هى لا شير
+
+162
+00:18:12,830 --> 00:18:17,650
+ولا ممد وبالتالى لازم على الأطراف مايكونش عندك
+
+163
+00:18:17,650 --> 00:18:20,490
+مسفر واضحات؟
+
+164
+00:18:23,520 --> 00:18:35,180
+طيب نشوف فيه تكنيك جديد فيه
+
+165
+00:18:35,180 --> 00:18:44,560
+تكنيك جديد لحساب ال reactions و
+
+166
+00:18:44,560 --> 00:18:46,800
+حساب ال shear و ال bending moment ال diagrams
+
+167
+00:18:46,800 --> 00:18:50,820
+هنستخدم
+
+168
+00:18:50,820 --> 00:18:54,500
+ما يسمى singularity functionsالسيجارات ال
+
+169
+00:18:54,500 --> 00:18:57,480
+functions تعتمد على ال functions التالة اولش اللي
+
+170
+00:18:57,480 --> 00:19:00,080
+عندي اللي هو concentrated moment عندي هاي ال X
+
+171
+00:19:00,080 --> 00:19:12,480
+axis هاي ال X وهذه المسافة A وفي
+
+172
+00:19:12,480 --> 00:19:18,220
+عندي concentrated moment او
+
+173
+00:19:18,220 --> 00:19:27,260
+بيسموها unit doubledعندي هدا هتكون X minus A minus
+
+174
+00:19:27,260 --> 00:19:33,960
+2 هد مش تقص minus 2 X minus A تكتبش minus 2 هد ال
+
+175
+00:19:33,960 --> 00:19:44,940
+X في الحالة هد X minus A بتساوي by definition Zero
+
+176
+00:19:44,940 --> 00:19:48,280
+في
+
+177
+00:19:48,280 --> 00:19:54,120
+كل الأماكناللي بتكونش x بالساوية فيها ايه او
+
+178
+00:19:54,120 --> 00:19:59,220
+بتساوي plus or minus infinity at x بالساوية ايه
+
+179
+00:19:59,220 --> 00:20:04,780
+يعني لأن نقطة هذه فقط لها قيمة بتكون لأ بتكون فجأة
+
+180
+00:20:04,780 --> 00:20:11,600
+بيصير عندى jump في moment سموه unit doublet
+
+181
+00:20:11,600 --> 00:20:18,110
+infinity مفهوم مفتوحممكن الـ infinity تعتبرها واحد
+
+182
+00:20:18,110 --> 00:20:21,270
+ممكن تعتبرها مليار ممكن مليون ال infinity قيمة
+
+183
+00:20:21,270 --> 00:20:26,970
+كبيرة كثير minus infinity قيمة صغيرة كثير فهذه by
+
+184
+00:20:26,970 --> 00:20:31,390
+definition x minus a بتكون تساوي zero anywhere
+
+185
+00:20:31,390 --> 00:20:36,250
+except at x بالساوية a بتكون plus or minus
+
+186
+00:20:36,250 --> 00:20:43,450
+infinity التاني ال function التاني اللي هو x minus
+
+187
+00:20:43,450 --> 00:20:48,920
+aسالب واحد اللي هو concentrated force او unit
+
+188
+00:20:48,920 --> 00:20:59,580
+impulse هعندي X هدي A بيصير
+
+189
+00:20:59,580 --> 00:21:12,080
+فجأة قفزة ال X هين تكامل X minus A بيساوي
+
+190
+00:21:15,290 --> 00:21:27,670
+x minus a سالب واحد لان x minus a سالب واحد بتساوي
+
+191
+00:21:27,670 --> 00:21:36,770
+zero عند x not equal a و بتساوي plus infinity عند
+
+192
+00:21:36,770 --> 00:21:44,980
+x الساوي a و التكاملللـ X minus A سالو واحد DX
+
+193
+00:21:44,980 --> 00:21:53,760
+بسوا X minus A Zero يعني بتعطينا unit step
+
+194
+00:21:53,760 --> 00:22:05,980
+function ال unit step function هاندي ال X هي A هدا
+
+195
+00:22:05,980 --> 00:22:09,880
+X minus A Zero
+
+196
+00:22:11,740 --> 00:22:21,200
+الـ X minus A Zero اللي هي unit step بتساوي Zero
+
+197
+00:22:21,200 --> 00:22:31,040
+طالما X أقل من A بتساوي واحد إذا X أكبر أو يساوي A
+
+198
+00:22:31,040 --> 00:22:41,630
+و التكامل X minus A Zero DX بتساوي X minus Aواحد
+
+199
+00:22:41,630 --> 00:22:48,590
+بعد
+
+200
+00:22:48,590 --> 00:22:58,650
+ذلك يأتي الـ RAM طلع يعني RAM طلع عندي
+
+201
+00:22:58,650 --> 00:23:05,290
+هاي A هذه
+
+202
+00:23:05,290 --> 00:23:10,250
+X هذه X minus A واحد
+
+203
+00:23:11,880 --> 00:23:24,940
+ال X minus A واحد بيساوي Zero إذا X أقل من A أو
+
+204
+00:23:24,940 --> 00:23:32,420
+بتساوي X minus A إذا
+
+205
+00:23:32,420 --> 00:23:38,860
+X أكبر أوي يساوي A يعني إيش بوصل للدكتور من ال
+
+206
+00:23:38,860 --> 00:23:42,400
+minus اتنين و من ال minus واحدby definition هذي مش
+
+207
+00:23:42,400 --> 00:23:48,280
+أس by definition x minus a بتمثل اللي هو moment
+
+208
+00:23:48,280 --> 00:23:55,560
+مفاجئة مركزة moment مركزة ال x minus a by
+
+209
+00:23:55,560 --> 00:24:00,600
+definition بتمثل ليه impulse impulse هذي impulse
+
+210
+00:24:00,600 --> 00:24:09,240
+او اشي مركز هاي impulse مافيش اشي مفروض موزعاكس
+
+211
+00:24:09,240 --> 00:24:15,040
+ماينوس ايه؟ سويتش اكس ماينوس ايه؟ زيرو؟ سويتش بكون
+
+212
+00:24:15,040 --> 00:24:19,320
+طالما انا تحت ال a زيرو لما اصلا ال a السويتش
+
+213
+00:24:19,320 --> 00:24:24,800
+بيشتغل on بيصير الاكس
+
+214
+00:24:24,800 --> 00:24:31,300
+ماينوس ايه؟ واحد سويتش بس بقلى فيه بقلى فيه ال
+
+215
+00:24:31,300 --> 00:24:35,000
+load او ال voltage او ال امبير شوية شوية بطلع طلوع
+
+216
+00:24:40,390 --> 00:24:45,950
+طيب هنستخدم هذه ال mathematical definitions عشان
+
+217
+00:24:45,950 --> 00:24:51,090
+أحل المسائل
+
+218
+00:24:51,090 --> 00:24:54,950
+اللي هو ال load و ال shear و ال moment diagram لو
+
+219
+00:24:54,950 --> 00:24:57,330
+حلل مسألة السابقة رجعنا المسألة السابقة
+
+220
+00:25:14,820 --> 00:25:18,520
+أحنا في الأساس بشكل عام بيكون عندك Q بيكون عندك Q
+
+221
+00:25:18,520 --> 00:25:23,040
+بعدين
+
+222
+00:25:23,040 --> 00:25:30,940
+BGV شير Q يعني load موزع لكل واحدة الطول بعدين BGH
+
+223
+00:25:30,940 --> 00:25:37,560
+moment ال
+
+224
+00:25:37,560 --> 00:25:40,420
+ال
+
+225
+00:25:42,320 --> 00:25:49,120
+هنا حكينا اللي
+
+226
+00:25:49,120 --> 00:26:06,240
+هي ال V بيستوى DM بي DX و ال Q بيستوى DV بي DX طيب
+
+227
+00:26:06,240 --> 00:26:12,810
+خلينا نطلع نمثل ال loading بتاعهاالـ loading اللي
+
+228
+00:26:12,810 --> 00:26:18,250
+هو Q بتساوي
+
+229
+00:26:18,250 --> 00:26:22,010
+في
+
+230
+00:26:22,010 --> 00:26:28,570
+عند reaction عند ال O ال X عند O أشو يستوي؟ Zero
+
+231
+00:26:28,570 --> 00:26:37,090
+هذا يمثل إيه؟ impulse هتكون R واحد في
+
+232
+00:26:37,090 --> 00:26:44,570
+Xسالب واحد هي x minus a ال a ايش يساوي زي صفر
+
+233
+00:26:44,570 --> 00:26:53,950
+minus هذا m plus 3 هذا minus 200 minus
+
+234
+00:26:53,950 --> 00:27:04,350
+200 x minus 4 سالب واحد minus 100
+
+235
+00:27:06,930 --> 00:27:17,310
+R2X-10-1R2X
+
+236
+00:27:17,310 --> 00:27:25,610
+-20-1R2X
+
+237
+00:27:25,610 --> 00:27:34,550
+-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X
+
+238
+00:27:34,550 --> 00:27:34,570
+-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X
+
+239
+00:27:34,570 --> 00:27:36,460
+-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1R2X-20-1الـ V
+
+240
+00:27:36,460 --> 00:27:46,560
+بيستوع تكامل QDX هتكون R1 X
+
+241
+00:27:46,560 --> 00:27:50,880
+سفر
+
+242
+00:27:50,880 --> 00:27:54,220
+ناقص
+
+243
+00:27:54,220 --> 00:28:08,090
+200 X ناقص 4 سفر ناقص 100X ناقص عشرة سفر زاد R
+
+244
+00:28:08,090 --> 00:28:17,250
+اتنين X ناقص عشرين سفر عندي برضه ال moment ال DM
+
+245
+00:28:17,250 --> 00:28:26,870
+بيساوي VDX معناه ان ال moment بيساوي تكامل VDX
+
+246
+00:28:26,870 --> 00:28:30,750
+هكوندي R واحد
+
+247
+00:28:34,460 --> 00:28:55,280
+X1-200 X-4 1-100 X-10 1 R2 X-20 1
+
+248
+00:29:10,110 --> 00:29:17,250
+لما نفحص هذه الـ R1 X ناقص واحد هذه بتكون هي قيمة
+
+249
+00:29:17,250 --> 00:29:19,630
+فقط عند X الساوية Zero عند X الساوية Zero بتكون هي
+
+250
+00:29:19,630 --> 00:29:26,930
+قيمة، صح؟ Jump التانية بتكون فقط لها قيمة عند X،
+
+251
+00:29:26,930 --> 00:29:32,910
+عند X أربعة التالتة عند X الساوية عشرة الرابعة عند
+
+252
+00:29:32,910 --> 00:29:34,890
+X الساوية عشرين
+
+253
+00:29:39,770 --> 00:29:44,270
+يعني لو حطيت X Zero minus يعني أقل من Zero شوية
+
+254
+00:29:44,270 --> 00:29:51,550
+كلهم يكونوا سواء سفر صح؟
+
+255
+00:29:51,550 --> 00:29:58,450
+لو أخدت X عشرين plus كله
+
+256
+00:29:58,450 --> 00:30:03,850
+سفر ال shear
+
+257
+00:30:09,300 --> 00:30:17,080
+برضه عند x zero minus هذه
+
+258
+00:30:17,080 --> 00:30:30,000
+unit step function معناته هذه سامعها واحد وهذا
+
+259
+00:30:30,000 --> 00:30:34,760
+expression اتنين وهذا expression تلاتة وهذا اربعة
+
+260
+00:30:45,600 --> 00:30:58,900
+عندي سفر وهي عشرة وهي عشرين وهي أربعة هذا
+
+261
+00:30:58,900 --> 00:31:05,900
+هيكون بساوية .. هيكون R واحد R واحد بيداخل بس ال
+
+262
+00:31:05,900 --> 00:31:11,500
+function تبعه بدون ال R واحد هذا هتكون إذا X أقل
+
+263
+00:31:11,500 --> 00:31:16,440
+من سفرسفر اذا اكون سفر هتكون اياش واحد يعني ال
+
+264
+00:31:16,440 --> 00:31:20,380
+switch هذا بيشتغل على طول بعد ال X بيشتغل على طول
+
+265
+00:31:20,380 --> 00:31:26,300
+ال
+
+266
+00:31:26,300 --> 00:31:32,140
+switch بتاع الأولاني هذا اشتغل من بعد سفر ال
+
+267
+00:31:32,140 --> 00:31:37,360
+switch بتاع التانية اشتغل بعد الأربع هطلع شوية هك
+
+268
+00:31:37,360 --> 00:31:46,280
+عشان اميزك اشتغل بعدنعم انا بحكي بس على هذه بحكي
+
+269
+00:31:46,280 --> 00:31:51,120
+على ال switch انا عارف انا بحكي بس على ال X ناقص
+
+270
+00:31:51,120 --> 00:32:05,220
+أربعة ك switch ال X ناقص عشرة اشتغلت بعد العشرة ال
+
+271
+00:32:05,220 --> 00:32:09,380
+X ناقص عشرين بعد العشرين
+
+272
+00:32:19,160 --> 00:32:26,460
+بالنسبة لهدول همسح هذه انا
+
+273
+00:32:26,460 --> 00:32:32,080
+ماحكيش على الشير بحكي على ال function هذا اصبر
+
+274
+00:32:32,080 --> 00:32:36,760
+شوية بحكي على ال function هذا الان بدأ اخد ال
+
+275
+00:32:36,760 --> 00:32:44,620
+functions هدول هي عندي عشرة عشرين وهي عندي أربعة
+
+276
+00:32:45,990 --> 00:32:50,050
+هذا بيشتغل بعد الـ zero بسلوك واحد بيظل ماشي على
+
+277
+00:32:50,050 --> 00:32:57,030
+طول هذا
+
+278
+00:32:57,030 --> 00:33:06,230
+بيشتغل بعد الأربعة هذا
+
+279
+00:33:06,230 --> 00:33:14,130
+بيشتغل بعد العشرة هذا
+
+280
+00:33:14,130 --> 00:33:15,650
+بيشتغل بعد الأشترين
+
+281
+00:33:21,720 --> 00:33:34,060
+ماشي طيب الان
+
+282
+00:33:34,060 --> 00:33:54,440
+at V and M هكون R 0 at X equal 0 minus و atx عشرين
+
+283
+00:33:54,440 --> 00:34:02,020
+plus يعني
+
+284
+00:34:02,020 --> 00:34:15,040
+العواطف هذه and at x equal عشرين plus هكون
+
+285
+00:34:15,040 --> 00:34:18,160
+and v بالساوة zero بالساوة
+
+286
+00:34:21,970 --> 00:34:25,330
+هذه بيشتغل بعد السفر موجود بقناته هتكون R واحد في
+
+287
+00:34:25,330 --> 00:34:36,070
+واحد صح هتكون ايش؟ R واحد و هذا شغال بعد الأربع
+
+288
+00:34:36,070 --> 00:34:40,790
+ناقص متين في واحد و
+
+289
+00:34:40,790 --> 00:34:46,650
+هذا شغال بعد العشرة ناقص مية و هذا شغال بعد عشرين
+
+290
+00:34:46,650 --> 00:34:56,800
+انا حاكي عشرين plusزاد R2 يعني هكون ال R1 زاد R2
+
+291
+00:34:56,800 --> 00:35:06,840
+بسوة 300 هذه المعادلة نجيل ال moment برضه at X
+
+292
+00:35:06,840 --> 00:35:12,360
+بسوة 20 plus هكون
+
+293
+00:35:12,360 --> 00:35:16,420
+ال moment بسوة Zero بتساوي
+
+294
+00:35:27,180 --> 00:35:38,280
+الان هضرب في X R1 R1
+
+295
+00:35:38,280 --> 00:35:52,440
+في عشرين مظبوط ناقص متين خلينا نشوف كيف اجت هذه ال
+
+296
+00:35:52,440 --> 00:36:02,860
+X جاء زي هيكهيك جاي وهي ال X عشرين صح لأنها هتكون
+
+297
+00:36:02,860 --> 00:36:13,360
+عشرين فقر واحد لأن مسلوب يساوي واحد ناقص متين في
+
+298
+00:36:13,360 --> 00:36:25,980
+عشرين ناقص أربعة ناقص مية في عشرين ناقص عشرةزائد R
+
+299
+00:36:25,980 --> 00:36:33,140
+اتنين في عشرين ناقص عشرين يعني
+
+300
+00:36:33,140 --> 00:36:41,740
+انا هكون عندي اربعة عشرين R واحد ناقص عشرين ناقص
+
+301
+00:36:41,740 --> 00:36:53,560
+اربعة ستاشر في متين ناقص تلت تلاف و متين ناقص الف
+
+302
+00:36:56,460 --> 00:37:03,300
+زائد صفر يعني R واحد هيكون
+
+303
+00:37:03,300 --> 00:37:12,420
+ساوي تلت تلاف واربع تلاف ومتين على عشرين متين
+
+304
+00:37:12,420 --> 00:37:20,180
+وعشرة تطلع متين وعشرة pound عوض في هذه حسين انك
+
+305
+00:37:20,180 --> 00:37:26,900
+متين وعشرة زاد R اتنينبالساوية تلت مية معناته R
+
+306
+00:37:26,900 --> 00:37:36,100
+اتنين بالساوية تسعين pound force هيك اوجدنا ال
+
+307
+00:37:36,100 --> 00:37:42,760
+reactions صارت
+
+308
+00:37:42,760 --> 00:37:48,060
+معروف R واحد متين و عشرة لان عندما ندرسهم
+
+309
+00:38:04,100 --> 00:38:15,200
+هي ال shear diagram ال
+
+310
+00:38:15,200 --> 00:38:23,880
+V من صفر لاربعة بيكون
+
+311
+00:38:23,880 --> 00:38:33,650
+شغال بس ال R واحد كله طافلهذا كله بيكون طافى هتكون
+
+312
+00:38:33,650 --> 00:38:45,610
+R واحد ايه اكم 210 لما
+
+313
+00:38:45,610 --> 00:38:52,670
+بين اربعة و عشرة بيضلوا شغال ال R واحد مظبوط و
+
+314
+00:38:52,670 --> 00:38:59,490
+بيشتغل ال 200 بس بالسالمهكون متين و عشرة ناقص متين
+
+315
+00:38:59,490 --> 00:39:06,310
+هي عشرة بين
+
+316
+00:39:06,310 --> 00:39:14,910
+العشرة والعشرين يكون هذا شغال و هذا شغال و هذا
+
+317
+00:39:14,910 --> 00:39:19,510
+شغال هطلع حمية بيصير ناقص تسعين
+
+318
+00:39:28,510 --> 00:39:35,330
+لحد نصل ال 20 او نصل ال 20 بشتغل اللي هو ال R2
+
+319
+00:39:35,330 --> 00:39:42,130
+بسفر ليه بالنسبة
+
+320
+00:39:42,130 --> 00:39:42,610
+ل ال moment
+
+321
+00:40:07,790 --> 00:40:18,130
+ال moment هتكون تساوي هاخد
+
+322
+00:40:18,130 --> 00:40:25,830
+x من 0 ل 4 هتكون
+
+323
+00:40:25,830 --> 00:40:26,930
+R1 في x
+
+324
+00:40:38,050 --> 00:40:42,430
+اللي هى R واحد اكمل دى اتين
+
+325
+00:40:42,430 --> 00:40:47,670
+و عشرة يعنى هتكون اتين
+
+326
+00:40:47,670 --> 00:40:51,990
+و عشرة X من
+
+327
+00:40:51,990 --> 00:41:00,510
+X بين الأربعة و العشرة بيشتغل
+
+328
+00:41:00,510 --> 00:41:11,550
+هده و هده صح بيصير عندك R واحد في Xناقص متين في X
+
+329
+00:41:11,550 --> 00:41:19,590
+ناقص أربعة بين
+
+330
+00:41:19,590 --> 00:41:32,570
+ال X عشرة و عشرين بيكون هذا شغال R واحد X ناقص
+
+331
+00:41:32,570 --> 00:41:34,810
+متين
+
+332
+00:41:36,400 --> 00:41:48,520
+فى x ناقص أربعة ناقص مية فى x ناقص عشرة وهذا لسه
+
+333
+00:41:48,520 --> 00:41:59,060
+ماشتغلش زائد زيرو صح بيشتغل بعد العشرين لأ نجربه
+
+334
+00:41:59,060 --> 00:42:08,580
+نجربه احنا حكينا لو x بالساوياربع هتكون ال moment
+
+335
+00:42:08,580 --> 00:42:14,380
+اكم تمامية و اربعين و اللي لأ هو واضح انه خطيه
+
+336
+00:42:14,380 --> 00:42:23,800
+لدرجته العامة تمامية و اربعين جربوا
+
+337
+00:42:23,800 --> 00:42:32,440
+X عشرة هنا هاي تمامية و اربعين ناقص اتين في عشرة
+
+338
+00:42:34,860 --> 00:42:44,720
+نقص اربعة ستين يعني تمانية و اربعين اه
+
+339
+00:42:44,720 --> 00:42:52,040
+متين و عشرة يصلي متين و عشرة في عشرة الفين و مية
+
+340
+00:42:52,040 --> 00:43:00,020
+يعني الفين و مية ناقص متين في ستة ناقص الف و متين
+
+341
+00:43:00,020 --> 00:43:00,620
+تسعة مية
+
+342
+00:43:10,060 --> 00:43:20,680
+حطوا هنا x بالساوية عشرين هكون متين و عشرة في
+
+343
+00:43:20,680 --> 00:43:31,780
+تسعين متين و عشرة في عشرين ناقص متين في ستة عشر
+
+344
+00:43:31,780 --> 00:43:37,500
+ناقص مية في عشرة اكم تطلع؟
+
+345
+00:43:43,340 --> 00:43:48,660
+سيبوها اكيد هتطلع سفر بس تأكدوا سيبوها تطلع سفر
+
+346
+00:43:48,660 --> 00:43:56,240
+معاكم فانا جبت المعادلات مش رسمته بس باستخدام اللي
+
+347
+00:43:56,240 --> 00:44:03,860
+هو ال singularity functions طيب
+
+348
+00:44:03,860 --> 00:44:08,600
+الحل سؤال يعني في تفصيل اكتر
+
+349
+00:44:20,380 --> 00:44:23,740
+طيب شوف السؤال هذا
+
+350
+00:44:55,120 --> 00:45:02,600
+طيب عندي beam اللي
+
+351
+00:45:02,600 --> 00:45:13,140
+هو cantilever يعني fixed عن طرف هذا ال
+
+352
+00:45:13,140 --> 00:45:18,760
+beam طوله عشرة انش فاندي load موزع قيمته اشرين
+
+353
+00:45:18,760 --> 00:45:22,740
+pound four per inchبشتغل من بين التلاتة انش
+
+354
+00:45:22,740 --> 00:45:28,220
+والسبعة انش وفي عندي moment مركزة في نهاية ال beam
+
+355
+00:45:28,220 --> 00:45:33,320
+اللي هي قيمته اتين و اربعين pound force انش هذا ال
+
+356
+00:45:33,320 --> 00:45:42,940
+X axis طبعا هذا ال Y axis هذا ال EQ طبعا
+
+357
+00:45:42,940 --> 00:45:54,020
+هكون عندي هنا M1 عند رد فعل هنار واحد بدا نوجد ال
+
+358
+00:45:54,020 --> 00:45:58,500
+reactions ونرسم الشير ومدغرام باستخدام ال
+
+359
+00:45:58,500 --> 00:46:01,840
+singularity functions اول شئ I have to define ال Q
+
+360
+00:46:01,840 --> 00:46:06,720
+ال Q هكون
+
+361
+00:46:06,720 --> 00:46:13,560
+الساوية عند X بالساوية Zero عندي concentrated
+
+362
+00:46:13,560 --> 00:46:18,820
+moment نرجع على الشكل ال by convention هنا
+
+363
+00:46:21,000 --> 00:46:26,040
+Clockwise موجب Clockwise
+
+364
+00:46:26,040 --> 00:46:38,880
+هنا معرفه موجب نعم هيكون هذا سالب M واحد X X minus
+
+365
+00:46:38,880 --> 00:46:48,420
+Zero صح هتكون X سالب اتنين for a moment زائد R
+
+366
+00:46:48,420 --> 00:46:58,690
+واحدفى x هذه impulse سالب واحد الآن
+
+367
+00:46:58,690 --> 00:47:08,130
+عندي هنا fixed هكون step function zero لأن خليني
+
+368
+00:47:08,130 --> 00:47:14,710
+أحكي ل step function ناخد حالة عندي هاي a هذه
+
+369
+00:47:14,710 --> 00:47:27,690
+x minus aزيرو وهي حالة تانية هذه ايه بي هذه
+
+370
+00:47:27,690 --> 00:47:36,750
+اكس minus بي زيرو لو طرحت هذا من هذا ايش بيعطيناه
+
+371
+00:47:36,750 --> 00:47:44,390
+طبعا هذا كل واحد وهنا كل واحد هيسفر هيسير عندي من
+
+372
+00:47:44,390 --> 00:47:54,050
+هنا لهناهي من A ل B هدا هيكون ال function X minus
+
+373
+00:47:54,050 --> 00:48:06,490
+A Zero minus X minus B Zero واضحة هدا عندي unit
+
+374
+00:48:06,490 --> 00:48:10,050
+step function يعني before X سواء A بيكون سواء 0
+
+375
+00:48:10,050 --> 00:48:14,710
+سفر بعد الواحد بعد ال A بيكون سواء واحد عندي كمان
+
+376
+00:48:14,710 --> 00:48:19,060
+another step functionبشتغل عند x يستوى بي يعني بعد
+
+377
+00:48:19,060 --> 00:48:23,540
+ال x يستوى بي بيصير واحد before بي سفر لو طلعت هذا
+
+378
+00:48:23,540 --> 00:48:29,780
+من هذا هكون واحد في المنطقة هذه واحد ناقص سفر واحد
+
+379
+00:48:29,780 --> 00:48:35,060
+في المنطقة هذه واحد ناقص واحد سفر يعني هيسفر بعد
+
+380
+00:48:35,060 --> 00:48:39,020
+ال بي يعني هكون ال functional شغل on هكون بين ال a
+
+381
+00:48:48,020 --> 00:48:55,480
+بزايد او ناقص عشرين في
+
+382
+00:49:09,110 --> 00:49:22,730
+نقص عشرين في X minus تلاتة Zero minus X ناقص سبعة
+
+383
+00:49:22,730 --> 00:49:26,770
+Zero
+
+384
+00:49:26,770 --> 00:49:30,730
+عن
+
+385
+00:49:30,730 --> 00:49:35,030
+الطرف عند ال moment برضه counter clockwise minus
+
+386
+00:49:35,030 --> 00:49:35,870
+متين و أربعين
+
+387
+00:49:40,510 --> 00:49:53,550
+فى x minus عشرة سالب اتنين ال
+
+388
+00:49:53,550 --> 00:49:57,130
+V هي
+
+389
+00:49:57,130 --> 00:50:09,770
+تكامل ل Q DX مظبوط هكون minus M واحد X سالب واحد
+
+390
+00:50:10,720 --> 00:50:19,000
+زاد R واحد في X سفر
+
+391
+00:50:19,000 --> 00:50:26,120
+minus عشرين في
+
+392
+00:50:26,120 --> 00:50:36,060
+X minus تلاتة واحد زاد
+
+393
+00:50:36,060 --> 00:50:37,920
+عشرين
+
+394
+00:50:39,220 --> 00:50:54,260
+فى x minus 7 و 1 ناقص 240 فى x ناقص 10 سالب 1 هذه
+
+395
+00:50:54,260 --> 00:50:59,480
+ال V ال M سوى
+
+396
+00:50:59,480 --> 00:51:03,800
+تكامل VDX بتساوي
+
+397
+00:51:11,220 --> 00:51:18,320
+-M1 X0 R1
+
+398
+00:51:18,320 --> 00:51:22,260
+X1
+
+399
+00:51:22,260 --> 00:51:31,800
+-20 X-3 2
+
+400
+00:51:37,760 --> 00:51:43,720
+زائد عشرين اكس
+
+401
+00:51:43,720 --> 00:51:48,460
+ناقص سبعة اتنين
+
+402
+00:51:48,460 --> 00:51:51,800
+ماينوس
+
+403
+00:51:51,800 --> 00:52:00,680
+متين و اربعين اظن ان نرجع نص التكامل نص هذا على
+
+404
+00:52:00,680 --> 00:52:05,420
+اتنين هذا على
+
+405
+00:52:05,420 --> 00:52:05,920
+اتنين
+
+406
+00:52:08,980 --> 00:52:25,720
+هذه على اتنين ناقص متين واربعين X ناقص عشرة سفر لأ
+
+407
+00:52:25,720 --> 00:52:34,440
+لأ انت by definition هات by definition انا هنا صار
+
+408
+00:52:34,440 --> 00:52:38,100
+عندى ارتفعت الدرجة هناك مارتفعتش الدرجة
+
+409
+00:52:40,770 --> 00:52:57,390
+بالظبط بالظبط مش power صحيح طيب الان عند
+
+410
+00:52:57,390 --> 00:53:03,690
+x at x بالساوية at x بالساوية zero minus
+
+411
+00:53:10,660 --> 00:53:16,720
+ولا واحد فيهم بيشتغل طلعوا هذا مش شغال هذا مش شغال
+
+412
+00:53:16,720 --> 00:53:22,560
+مش شغال ولا واحد فيهم بيشتغل
+
+413
+00:53:22,560 --> 00:53:37,900
+و add x ساوية عشرة plus كون
+
+414
+00:53:37,900 --> 00:53:50,290
+هذا شغالهذا شغال، هذا شغال، كله شغالين، صح؟
+
+415
+00:53:50,290 --> 00:54:02,830
+طيب معناته نحكي at x بالثاوية عشرة plus ال V
+
+416
+00:54:02,830 --> 00:54:07,050
+بالثاوية، سفر ششير بالثاوية
+
+417
+00:54:14,240 --> 00:54:27,360
+هذا هتكون minus ال
+
+418
+00:54:27,360 --> 00:54:35,140
+moment هذه بتكون لها قيمة عند x بستوى سفر any x
+
+419
+00:54:35,140 --> 00:54:41,180
+any other x هتكون سفر صح؟ هذا المقال هتكون سفر
+
+420
+00:54:45,970 --> 00:54:50,450
+وهذا step function او unit step function هتكون
+
+421
+00:54:50,450 --> 00:54:54,110
+زائد R واحد يعني يعني يعني يعني بعد السفر بيصير له
+
+422
+00:54:54,110 --> 00:55:03,710
+قيمة صح؟ زائد R واحد و هذا بعد التلاتة هذا بعد
+
+423
+00:55:03,710 --> 00:55:08,110
+التلاتة بيكون ايش زي هيك هاي X بالثاوض تلاتة هذا X
+
+424
+00:55:08,110 --> 00:55:16,000
+بالثاوض تلاتة يعني هتكون minus عشرين في عشرةناقص
+
+425
+00:55:16,000 --> 00:55:29,460
+تلاتة زائد عشرين في عشرة ناقص سبعة هذا
+
+426
+00:55:29,460 --> 00:55:35,320
+ال X عشرة plus مافيه قيمة فقط عند X يساوي عشرة
+
+427
+00:55:35,320 --> 00:55:44,380
+بالظبط يعني ناقص Zero يعني هتكون عند R واحد هتساوي
+
+428
+00:55:48,890 --> 00:55:53,450
+عشريف سبعة مية
+
+429
+00:55:53,450 --> 00:56:00,950
+و أربعين ناقص عشريف
+
+430
+00:56:00,950 --> 00:56:10,870
+تلاتة ستين مظبوط
+
+431
+00:56:10,870 --> 00:56:18,370
+صحيح
+
+432
+00:56:22,040 --> 00:56:26,960
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+433
+00:56:26,960 --> 00:56:28,700
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+434
+00:56:28,700 --> 00:56:28,740
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+435
+00:56:28,740 --> 00:56:28,780
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+436
+00:56:28,780 --> 00:56:28,880
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+437
+00:56:28,880 --> 00:56:30,340
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+438
+00:56:30,340 --> 00:56:47,300
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+439
+00:56:51,080 --> 00:56:54,420
+واضح؟ هذا step function بتكون قيمته قبل ال X في
+
+440
+00:56:54,420 --> 00:56:58,960
+السواء Zero و بعد X بيبقى أكبر ال X في السواء Zero
+
+441
+00:56:58,960 --> 00:57:04,060
+بيكون قيمته واحد واحد في R واحد R واحد صحيح طب
+
+442
+00:57:04,060 --> 00:57:09,020
+دكتور احنا قلنا انها لعشرة plus هل انه مش هي اخر
+
+443
+00:57:09,020 --> 00:57:14,140
+ايش هنكون محددين من الزفر للعشرة؟ صحيح يعني هي
+
+444
+00:57:14,140 --> 00:57:18,420
+منطقة غير قيمة ال step ماشي انت اتلقيت مرة ال بين
+
+445
+00:57:19,240 --> 00:57:24,540
+عشان هيك .. ما هي .. ما هي الفكرة ان انت ايك عشرة
+
+446
+00:57:24,540 --> 00:57:29,000
+plus عشرة plus تعتبر point او او او او او او او او
+
+447
+00:57:29,000 --> 00:57:29,920
+او او او او او او او او او او او او او او او او او
+
+448
+00:57:29,920 --> 00:57:30,080
+او او او او او او او او او او او او او او او او او
+
+449
+00:57:30,080 --> 00:57:30,420
+او او او او او او او او او او او او او او او او او
+
+450
+00:57:30,420 --> 00:57:30,500
+او او او او او او او او او او او او او او او او او
+
+451
+00:57:30,500 --> 00:57:38,380
+او او
+
+452
+00:57:38,380 --> 00:57:48,200
+او
+
+453
+00:57:48,500 --> 00:57:52,340
+في step function step function هذا بيشتغل بيصير on
+
+454
+00:57:52,340 --> 00:57:57,940
+بعد ال X بالساوية Zero مفتوح على طول شغال على مال
+
+455
+00:57:57,940 --> 00:58:06,120
+النهاية هذا شغال من عند X الساوية هذا RAM شغال من
+
+456
+00:58:06,120 --> 00:58:11,620
+عند X الساوية تلاتة وطلع يعني هاي X الساوية تلاتة
+
+457
+00:58:11,620 --> 00:58:17,860
+شغال على طول هذا شغال بعد X
+
+458
+00:58:22,190 --> 00:58:26,890
+سبعة هذا concentrated بيشتغل فقط عند x الساعة و
+
+459
+00:58:26,890 --> 00:58:43,090
+عشرة عند عشرة plus أو عشرة minus بيشتغلش الآن
+
+460
+00:58:43,090 --> 00:58:45,910
+هنشوفها واحدة واحدة اول خطوة هنجيه ال reactions
+
+461
+00:58:45,910 --> 00:58:47,770
+هنعوض x الساعة و عشرة
+
+462
+00:58:50,750 --> 00:58:56,490
+حسبنا ال R واحد ناخد معاملة ال moment برضه at X
+
+463
+00:58:56,490 --> 00:59:03,110
+بالساوية عشرة plus مافيش P أساسا ال moment شوفوا
+
+464
+00:59:03,110 --> 00:59:09,970
+الساوية بتساوية
+
+465
+00:59:09,970 --> 00:59:17,930
+هيا هذا step function بيشتغل بعد السفر معناته M
+
+466
+00:59:17,930 --> 00:59:18,710
+واحد موجودة
+
+467
+00:59:22,600 --> 00:59:30,720
+-M1 وهذا طلع شغالة بعد الـ X الساعة و سفر والـ X
+
+468
+00:59:30,720 --> 00:59:39,680
+قيمتها هكون زائد R1 في عشرة ناقص
+
+469
+00:59:39,680 --> 00:59:46,260
+هشيعتني ان ناقص عشرة في X
+
+470
+00:59:53,340 --> 01:00:00,280
+عشرة ناقص تلاتة لكل تربيع
+
+471
+01:00:00,280 --> 01:00:09,920
+زائد
+
+472
+01:00:09,920 --> 01:00:13,260
+عشرة
+
+473
+01:00:16,290 --> 01:00:23,030
+عشرة ناقص سبعة في عشرة ناقص سبعة تربية ناقص سبعة
+
+474
+01:00:23,030 --> 01:00:26,450
+ما الاتنين عليها نقص نعم ليش سبعة ما الاتنين عليها
+
+475
+01:00:26,450 --> 01:00:36,550
+نقص اه لو أخدنا الحلقة البسيطة الرقم
+
+476
+01:00:36,550 --> 01:00:43,890
+عنده هي الرقم اكس السبعة هي رايحة بالشكل هذا لبعض
+
+477
+01:00:43,890 --> 01:00:44,370
+النهاية
+
+478
+01:00:46,910 --> 01:00:53,610
+اجمعها ايش هتعطيلي؟ هتعطيلي هذه معادلة Y Y
+
+479
+01:00:53,610 --> 01:01:01,070
+بالساوية X كإنها التكمل تعالى ايش بالساوية؟ X
+
+480
+01:01:01,070 --> 01:01:10,150
+تربيع ع اتنين يعني هتكون ايه؟ برابولة رايح لما
+
+481
+01:01:10,150 --> 01:01:16,450
+لنهاية برابولة رايح لما لنهايةإذا كانت X بيستوي A
+
+482
+01:01:16,450 --> 01:01:24,850
+أساسا هي ال RAM بتاعتها اللي
+
+483
+01:01:24,850 --> 01:01:30,470
+صار أنه عندك بدأ الجزء الموجب من ال parabola بعد
+
+484
+01:01:30,470 --> 01:01:38,130
+ال X بيستوي A يعني هي هذي X بيستوي A واضحة
+
+485
+01:01:38,130 --> 01:01:45,610
+ليش النصأنا عملت shift سواء كان في ال calculus كان
+
+486
+01:01:45,610 --> 01:01:48,830
+ممكن اعمل shift باتجاه ال x axis او باتجاه ال y
+
+487
+01:01:48,830 --> 01:01:53,410
+axis انا عملتله هنا shift زحت ال parabola باتجاه
+
+488
+01:01:53,410 --> 01:01:58,510
+ال x axis لما حكيت x لما حكيت x ناقص تلاتة الكل
+
+489
+01:01:58,510 --> 01:02:03,650
+تربيع كأنه parabola مزاح سبع وحدها تجاه ال x axis
+
+490
+01:02:03,650 --> 01:02:08,310
+نفس ال parabola اللي عند x يستوى zero بس انا بزيحه
+
+491
+01:02:17,410 --> 01:02:24,470
+طيب وين وصلنا زاد عشرة ناقص متين واربعين ناقص متين
+
+492
+01:02:24,470 --> 01:02:33,010
+واربعين في صفر ناقص متين واربعين في اياش في صفر
+
+493
+01:02:33,010 --> 01:02:40,970
+يعني هيكون عنده متين
+
+494
+01:02:40,970 --> 01:02:45,830
+واربعين هتحط X الساوي لأ صحيح كلام ناقص متين
+
+495
+01:02:45,830 --> 01:02:50,780
+واربعينفى واحد ليش
+
+496
+01:02:50,780 --> 01:02:54,520
+لأن هذا unit step function بيشتغل مباشرة بعد ال X
+
+497
+01:02:54,520 --> 01:02:58,960
+الساوية ايش عشرة فهذا هتكون قيمته واحد ناقص تانية
+
+498
+01:02:58,960 --> 01:03:06,760
+واربعين فى واحد يعني هيكون عندى ناقص M واحد ال R
+
+499
+01:03:06,760 --> 01:03:14,020
+واحد أكتر حسبناها تمانين زائد تمانية ناقص
+
+500
+01:03:15,420 --> 01:03:20,380
+هنا سبعة تربية تسعة وأربعين في عشرة أربعين وتسعين
+
+501
+01:03:20,380 --> 01:03:30,660
+لاحظ
+
+502
+01:03:30,660 --> 01:03:39,640
+شوية ناقص أربعين وتسعين زاد عشرة عشرة عشرة
+
+503
+01:03:39,640 --> 01:03:52,580
+في تسعةتسعين لأ من الصفر عشرة في تسعة تسعين ناقص
+
+504
+01:03:52,580 --> 01:03:58,100
+متين واربعين بالساوي
+
+505
+01:03:58,100 --> 01:04:04,920
+ايش سفر ومنها بحسب ال M واحدهجيبها جهة تانية هتكون
+
+506
+01:04:04,920 --> 01:04:09,120
+تمامية نقص واحد وتسعين زي التسعين نقص اتنين
+
+507
+01:04:09,120 --> 01:04:17,620
+واربعين اكم تطلع مية وستين pound inch pound force
+
+508
+01:04:17,620 --> 01:04:23,180
+inch هيك حسبت ال reactions و ال moments اللي
+
+509
+01:04:23,180 --> 01:04:27,060
+هنخليه نعمل ال share و ال moment diagram
+
+510
+01:04:35,730 --> 01:04:43,670
+بحكي ال share ال V هيكون يساوي ال
+
+511
+01:04:43,670 --> 01:04:50,670
+share ال M1 حسبناها كم طلعت؟ مية و ستين مية و ستين
+
+512
+01:04:50,670 --> 01:04:58,070
+هحكيها عشان M1 بيساوي مية و ستين pound انش وال R1
+
+513
+01:04:58,070 --> 01:05:02,990
+ده كم؟ ربما تبقى تمانين تمانين pound
+
+514
+01:05:14,580 --> 01:05:22,100
+الـ V هتكون
+
+515
+01:05:22,100 --> 01:05:33,000
+تساوي هد مش هتشتغل غير عند Zero صح هد هتشتغل زاد R
+
+516
+01:05:33,000 --> 01:05:42,520
+واحد مابعد يعني هناخد فترات بين سفر و تلاتةو تلاتة
+
+517
+01:05:42,520 --> 01:05:48,640
+و سبعة و سبعة و عشرة هاخد بين سفر و تلاتة X بين
+
+518
+01:05:48,640 --> 01:05:57,500
+سفر و تلاتة هتكون
+
+519
+01:05:57,500 --> 01:06:03,040
+هذا
+
+520
+01:06:03,040 --> 01:06:10,080
+هتكون ايه اش R واحد لان
+
+521
+01:06:10,080 --> 01:06:18,700
+هذا step functionناقص عشرين في
+
+522
+01:06:18,700 --> 01:06:34,580
+X ناقص تلاتة زائد عشرين في X ناقص سبعة وهذا
+
+523
+01:06:34,580 --> 01:06:40,360
+يكون الشغال صح؟ يعني
+
+524
+01:06:41,960 --> 01:06:45,920
+الان راح عندي تمانين لو حطينا X بالثانوية تلاتة
+
+525
+01:06:45,920 --> 01:06:46,900
+خلّين نرسم
+
+526
+01:07:28,550 --> 01:07:33,290
+انت أكد كده مرة عندي ال V من سفر من X من X من سفر
+
+527
+01:07:33,290 --> 01:07:39,870
+لتلاتة من سفر لتلاتة هذا بيكون الشغال هذا بيشتغل
+
+528
+01:07:39,870 --> 01:07:51,610
+هذا هذا مش شغال صح هذا لسه ماشتغلتش اه لو حطينا ال
+
+529
+01:07:51,610 --> 01:07:56,430
+X بالساوية تلاتة او لو حطيت ال X بالساوية
+
+530
+01:07:59,690 --> 01:08:04,410
+لحظة لحظة، الآن هذه برضه بتكون الشغالة، هذه بتكون
+
+531
+01:08:04,410 --> 01:08:14,410
+الشغالة، صح؟ هتكون R واحد، ال R واحد عندي أكم؟
+
+532
+01:08:14,410 --> 01:08:15,810
+تمانين
+
+533
+01:08:31,150 --> 01:08:40,230
+طيب X بين التلاتة والسبعة بيكون
+
+534
+01:08:40,230 --> 01:08:46,930
+شغال ال R واحد واشتغل
+
+535
+01:08:46,930 --> 01:08:54,250
+X ناقص تلاتة minus عشرين في X ناقص تلاتة هذا لسه
+
+536
+01:08:54,250 --> 01:08:56,990
+ماشتغلش ولا هذا اشتغل صح؟
+
+537
+01:08:59,490 --> 01:09:11,210
+لو حطينا x بالساوية سبعة سبعة
+
+538
+01:09:11,210 --> 01:09:11,370
+سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة
+
+539
+01:09:11,370 --> 01:09:13,550
+سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة
+
+540
+01:09:13,550 --> 01:09:14,030
+سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة سبعة
+
+541
+01:09:14,030 --> 01:09:23,110
+سبعة سبعة سبعة سبعة سبعة سبعة سبعة
+
+542
+01:09:23,110 --> 01:09:26,170
+سبعة سب
+
+543
+01:09:27,160 --> 01:09:33,240
+لأ بتبدأ تشغّل يعني هذه ال function هذا مع بعض هذا
+
+544
+01:09:33,240 --> 01:09:40,280
+شغال هاي أول واحد هذا شغال وهذا شغال لكن هدول لسه
+
+545
+01:09:40,280 --> 01:09:45,700
+ماشتغلوش مش ماشتغل انه ببدأ عند السبعة بالظبط صفر
+
+546
+01:09:45,700 --> 01:09:48,720
+يعني قيمته عند السبعة بالظبط معناه مش مفيد احطه
+
+547
+01:09:48,720 --> 01:09:53,500
+فالشغال فعليا هو بيعطي قيمة ر واحد وعشرين في X
+
+548
+01:09:53,500 --> 01:09:57,130
+ناقص تلاتةيعني هتكون عند ار واحد لو حكيت ار واحد
+
+549
+01:09:57,130 --> 01:10:05,070
+عنده تمانين ناقص عشرين في سبعة ناقص تلاتة هتكون
+
+550
+01:10:05,070 --> 01:10:13,130
+تمانين ناقص تمانين صفر و هي اتطلعوا عشرين في أربعة
+
+551
+01:10:13,130 --> 01:10:18,710
+ناقص تمانين يعني هتكون ساوى صفر
+
+552
+01:10:29,050 --> 01:10:33,270
+ما حكيتلك عندي السبعة هذا ببدأ يشتغل بس كيبته سفر
+
+553
+01:10:33,270 --> 01:10:36,530
+بين
+
+554
+01:10:36,530 --> 01:10:46,110
+السبعة X بين السبعة والعشرة بيكون عندك R واحد ناقص
+
+555
+01:10:46,110 --> 01:10:52,670
+عشرين في X ناقص تلاتة زائد عشرين في X ناقص سبعة
+
+556
+01:11:05,770 --> 01:11:13,110
+أقل مش أقل لو يساوي طيب
+
+557
+01:11:13,110 --> 01:11:25,200
+لو حطيت X عشرة هكون عندى تمانين ناقص عشرينفي سبعة
+
+558
+01:11:25,200 --> 01:11:31,440
+زائد عشرين في
+
+559
+01:11:31,440 --> 01:11:39,860
+إيش؟ في صفر غلطان صح زيك؟ لأ عشرة بدي أحط عشرة
+
+560
+01:11:39,860 --> 01:11:49,630
+الآن التمانين ناقص عشرين في سبعة زائد عشرينفي
+
+561
+01:11:49,630 --> 01:11:57,890
+تلاتة يعني هكون تمانين ناقص مية و أربعين زائد ستين
+
+562
+01:11:57,890 --> 01:12:04,670
+ايش هسير فيه؟ صفر مستيرياش؟
+
+563
+01:12:04,670 --> 01:12:17,070
+صفر معناته هكون ماشي زي هيك صح؟
+
+564
+01:12:17,070 --> 01:12:19,050
+اه
+
+565
+01:12:20,480 --> 01:12:28,680
+عند السفر بالظبط عشان اكون دقيق ياد لازم تخلي
+
+566
+01:12:28,680 --> 01:12:38,920
+السفر لحاله خاطره اكبر اكبر عند السفر plus طيب
+
+567
+01:12:38,920 --> 01:12:45,960
+هذا بالنسبة لإياش لل share عند السفر لإياش
+
+568
+01:12:49,980 --> 01:12:56,440
+المشكلة بتقفز فجأة يعني انك عندك zero plus zero
+
+569
+01:12:56,440 --> 01:13:05,120
+plus فتقفز فجأة فبعتبرها كأنها سفر واضحة؟
+
+570
+01:13:05,120 --> 01:13:12,940
+طيب الآن ال moment هناخد
+
+571
+01:13:12,940 --> 01:13:16,800
+بين X صفر و تلاتة
+
+572
+01:13:19,630 --> 01:13:24,390
+هي ال moment هذي
+
+573
+01:13:24,390 --> 01:13:29,870
+هتكون شغلة صح بعد أكبر من السفن سنة تلت هتكون شغلة
+
+574
+01:13:29,870 --> 01:13:36,310
+minus M واحد زائد
+
+575
+01:13:36,310 --> 01:13:46,810
+R واحد في X هذي لسه ماشتغلتش و هذي ماشتغلتش و هذي
+
+576
+01:13:46,810 --> 01:13:54,230
+ماشتغلتشيعني هتكون ال M واحد احنا حسبناها كم مية و
+
+577
+01:13:54,230 --> 01:14:02,030
+ستين يعني هتكون نقص مية و ستين زاد
+
+578
+01:14:02,030 --> 01:14:10,530
+تمانين في X تمانين
+
+579
+01:14:10,530 --> 01:14:11,250
+في تلاتين
+
+580
+01:14:18,240 --> 01:14:25,920
+حط x بالساوية صفر هتكون ناقص مية و ستين لأن في
+
+581
+01:14:25,920 --> 01:14:32,520
+عندي concentrated moment ناقص مية
+
+582
+01:14:32,520 --> 01:14:38,980
+و ستين حط x بالساوية تلاتة تمانين في تلاتة متين و
+
+583
+01:14:38,980 --> 01:14:43,880
+أربعين ناقص مية و ستين تمانين هذي constant فعلا
+
+584
+01:14:43,880 --> 01:14:47,860
+هذي هتكون عشر linear يعني هتكون عندهين
+
+585
+01:14:56,730 --> 01:15:06,710
+بين اكس بين تلاتة و سبعة هيكون ناقص مائة و ستين
+
+586
+01:15:06,710 --> 01:15:14,190
+زائد تمانين اكس هضيف ايه هاد
+
+587
+01:15:14,190 --> 01:15:17,930
+شغال هاد شغال وهاد اشتغلت ناقص عشرة
+
+588
+01:15:23,160 --> 01:15:30,500
+في x ناقص ثلاثة تربيع هذه لسه ما اشتغلت و لا هاد
+
+589
+01:15:30,500 --> 01:15:34,020
+اشتغلت
+
+590
+01:15:34,020 --> 01:15:45,140
+حط x بالساوية سبعة هكون دي ناقص مية و ستين زائد
+
+591
+01:15:45,140 --> 01:15:49,960
+خمس مية و ستين هين
+
+592
+01:15:49,960 --> 01:15:57,680
+اربع في اربع ستاشفعشرة ناقص مية و ستين أكمل طلع
+
+593
+01:15:57,680 --> 01:16:01,320
+خمسمية و ستين ناقص مية و ستين أربعمية ناقص مية
+
+594
+01:16:01,320 --> 01:16:05,940
+تلاتمية متين و أربعين صح؟
+
+595
+01:16:05,940 --> 01:16:11,080
+متين و أربعين طبعا هذا إيش لاحظوا الدرجة بتاعتها
+
+596
+01:16:11,080 --> 01:16:13,120
+فرابولا
+
+597
+01:16:33,840 --> 01:16:44,060
+بين X سبعة وأقل من عشرة هكون ناقص مية ستين زائد
+
+598
+01:16:44,060 --> 01:16:49,000
+تمانين X ناقص عشرة في X ناقص تلاتة
+
+599
+01:16:54,160 --> 01:17:04,040
+في x ناقص ثلاثة هذا شغال شغال شغال زائد عشرة ناقص
+
+600
+01:17:04,040 --> 01:17:08,200
+ستين زائد
+
+601
+01:17:08,200 --> 01:17:12,140
+عشرة في
+
+602
+01:17:12,140 --> 01:17:15,780
+x ناقص
+
+603
+01:17:15,780 --> 01:17:18,980
+سبعة لكل تربيع
+
+604
+01:17:30,310 --> 01:17:38,350
+هذه مش هتكون شغالة عند X و الساعة عشرة minus الآن
+
+605
+01:17:38,350 --> 01:17:45,710
+لو عوّض X عندك X و الساعة عشر هكون ناقص مية و ستين
+
+606
+01:17:45,710 --> 01:17:52,810
+زائد تمانية ناقص
+
+607
+01:17:52,810 --> 01:17:57,870
+عشرة في سبعة ناقص سبعين
+
+608
+01:17:59,690 --> 01:18:06,650
+الان عندي هنا تلاتة تربية ناقص
+
+609
+01:18:06,650 --> 01:18:11,730
+اربعمية وتسعين زائد
+
+610
+01:18:11,730 --> 01:18:20,730
+تسعين احسبوها هتكون
+
+611
+01:18:20,730 --> 01:18:25,250
+تطلعاش
+
+612
+01:18:25,250 --> 01:18:28,010
+ميتين واربعين
+
+613
+01:18:30,060 --> 01:18:34,060
+واضح المسافة هذه بالساوية zero انا اتضلتها ماشي
+
+614
+01:18:34,060 --> 01:18:40,860
+عادل زي هيك وفجأة
+
+615
+01:18:40,860 --> 01:18:46,160
+نزلت .. نزلتها ال 240 لتحت نزلتها
+
+616
+01:18:46,160 --> 01:18:55,480
+ال 240 لتحت لو
+
+617
+01:18:55,480 --> 01:18:56,740
+حطيت مرحلة رابعة
+
+618
+01:19:01,440 --> 01:19:09,820
+أحط اليساوي بقضيف اللي عليها هذه واضح هى
+
+619
+01:19:09,820 --> 01:19:12,300
+كمان ال shear moment diagram جبنا الكويتش طبعا
+
+620
+01:19:12,300 --> 01:19:14,560
+الكويتش هتمكن تعمل ايه اللي هي ال simplification
+
+621
+01:19:14,560 --> 01:19:17,320
+عندها يعني ارواحها نقص شرين هي تبسطها اكتر
+
+622
+01:19:20,870 --> 01:19:23,830
+طبعا هذه مزيتها في البرمجة، برمجتها سهلة، انت
+
+623
+01:19:23,830 --> 01:19:27,610
+تبرمج على ال MATLAB او اي برنامج تاني، سهلة في
+
+624
+01:19:27,610 --> 01:19:30,610
+البرمجة و إذا اتعود عليها بتعطيلك سرعة، هي بس
+
+625
+01:19:30,610 --> 01:19:32,550
+تعود، في اي سؤال؟
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/d41O2ORAk3g_postprocess.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/d41O2ORAk3g_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..35fb3ee52d374112b76efea1dd413932d194748c
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/d41O2ORAk3g_postprocess.srt
@@ -0,0 +1,3328 @@
+1
+00:00:05,400 --> 00:00:07,780
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:07,780 --> 00:00:12,660
+وبركاته اليوم محاضرة في مادة تصميم الآلات المحاضرة
+
+3
+00:00:12,660 --> 00:00:18,410
+اللي هتكون مقدمة لتصميم ال .. ال mechanicalطبعا
+
+4
+00:00:18,410 --> 00:00:23,030
+هنبدأ في بعض التعريفات او المفاهيم يعني هنعرف ايش
+
+5
+00:00:23,030 --> 00:00:27,910
+معناه design design ان انا اعمل خطة معينة عشان
+
+6
+00:00:27,910 --> 00:00:31,970
+احقق هدف او غاية معينة هدفه مثلا اعمل impact
+
+7
+00:00:31,970 --> 00:00:36,570
+testing machine هذا هدف ايش الاحتياج محتاجينه في
+
+8
+00:00:36,570 --> 00:00:41,610
+المختبر فهذا عندي احتياج محتاج اصلا اعمل ماكينة
+
+9
+00:00:41,610 --> 00:00:45,990
+لفرم ل plasticفي احتياج عندى انا بدى افرم ال
+
+10
+00:00:45,990 --> 00:00:50,650
+plastic محتاج اعمل ماكينة عشان اتعدل السياخ بطون
+
+11
+00:00:50,650 --> 00:00:56,630
+في احتياج عند السياخ بطون بدها تعديل وبالتالي عشان
+
+12
+00:00:56,630 --> 00:01:01,090
+to design لازم يكون عندى خطة لازم يكون عندى خطة
+
+13
+00:01:01,090 --> 00:01:05,490
+عشان اصل لهذا الهدف او هذا الغير طبعا الخطة او ال
+
+14
+00:01:05,490 --> 00:01:10,910
+designبتطلب اللي هو innovation الإبداع بتطلب انك
+
+15
+00:01:10,910 --> 00:01:14,570
+تعمل iteration تقيد الحسابات او تكررها و بتطلب
+
+16
+00:01:14,570 --> 00:01:18,490
+تتخذ قرار في بعض الأحيان ما بيكون عندك معلومات
+
+17
+00:01:18,490 --> 00:01:25,280
+كافية فبدك تتخذ قرار معينأي تصميم ل product عشان
+
+18
+00:01:25,280 --> 00:01:27,720
+أصلا product لازم ال product يكون functional
+
+19
+00:01:27,720 --> 00:01:32,420
+function يعني يقدر الوظيفة المطلوبة منه يعني بتعمل
+
+20
+00:01:32,420 --> 00:01:36,680
+ماكينة لفرم لبلاستيك لازم تفرم بلاستيك ولا ماحققتش
+
+21
+00:01:36,680 --> 00:01:41,060
+الغاية بتاعتها لازم تكون safe ال machine هيتعامل
+
+22
+00:01:41,060 --> 00:01:45,560
+معاها عامل أو فني فلازم تكون التعامل معاها بشكل
+
+23
+00:01:45,560 --> 00:01:49,980
+آمن reliable يعتاد بيها يعني مش كل يوم أطلعل فيها
+
+24
+00:01:49,980 --> 00:01:55,910
+كتير و متكررةcompetitive انت مش لحالك في السوق في
+
+25
+00:01:55,910 --> 00:02:01,150
+ناس كتير بصنع ماكنات شبيهة فلازم تعمل منتج منافس
+
+26
+00:02:01,150 --> 00:02:05,870
+من حيث الجودة او الخيارات الإضافية في ال machine
+
+27
+00:02:05,870 --> 00:02:12,830
+او من حيث السعر usable usable يعني قابلة للاستخدام
+
+28
+00:02:12,830 --> 00:02:18,230
+انت في النهاية لازم تحقق حاجة اذا فيش حاجة مافي
+
+29
+00:02:18,230 --> 00:02:21,510
+داعي تعمل machine manufacturable
+
+30
+00:02:22,610 --> 00:02:26,350
+قابلة للتصنيع قابلة للتصنيع في المكان اللي انت
+
+31
+00:02:26,350 --> 00:02:30,230
+بتصنيعه في البيئة مثلا بدك تصنيع جهاز في غزة و بده
+
+32
+00:02:30,230 --> 00:02:34,050
+تقنيات عالة جدا مش موجودة ل .. في .. عندنا في غزة
+
+33
+00:02:34,050 --> 00:02:39,110
+مش حد يقدر تصنيعه لازم يكون marketable يكون قابل
+
+34
+00:02:39,110 --> 00:02:43,010
+للتسويق عشان يكون marketable لازم يكون ينافس في
+
+35
+00:02:43,010 --> 00:02:47,810
+الجودة و ينافس السعر انا مش .. مش منطق اعمل مثلا
+
+36
+00:02:47,810 --> 00:02:52,950
+عصارة للفواكهيتكلف فصلا أبيعها ب 2000 دولار، مافيش
+
+37
+00:02:52,950 --> 00:02:56,710
+حاجة هنشتريها، فلازم يكون السعر منافس وجودها
+
+38
+00:02:56,710 --> 00:02:57,390
+منافسة
+
+39
+00:03:02,060 --> 00:03:08,120
+طبعا التصميم الميكانيكي يتضمن جميع تخصصات في
+
+40
+00:03:08,120 --> 00:03:10,740
+الهندسة الميكانيكية في بعض الأحيان يتجاوز تخصصات
+
+41
+00:03:10,740 --> 00:03:13,540
+في الهندسة الميكانيكية ممكن أحتاج في الهندسة
+
+42
+00:03:13,540 --> 00:03:18,240
+الكهربائية ممكن أحتاج في الحسوب ممكن أحتاج في
+
+43
+00:03:18,240 --> 00:03:20,760
+الكيميا ممكن أحتاج في ال microbiology يعني ممكن
+
+44
+00:03:20,760 --> 00:03:24,180
+أحتاج العديد من التخصصات على سبيل المثال المحاور
+
+45
+00:03:24,180 --> 00:03:28,950
+جورنال بيرينجبدخل فيها علم المواقع، بدخل فيها علم
+
+46
+00:03:28,950 --> 00:03:32,950
+انتقال الحرارة، بدخل فيها علم الاحتكاك، بدخل فيها
+
+47
+00:03:32,950 --> 00:03:36,370
+اللي هو energy transport انتقال الطاقة، بختار فيها
+
+48
+00:03:36,370 --> 00:03:39,770
+material لل component بتاعة ال journal bearing
+
+49
+00:03:39,770 --> 00:03:43,690
+وفيه يعني طبعا thermomechanical treatments فيه
+
+50
+00:03:43,690 --> 00:03:48,670
+بيصير ومعالجات حرارية او ميكانيكية او تانية مع بعض
+
+51
+00:03:48,670 --> 00:03:51,670
+عشان مثلا احصل على خلاص ميكانيكية لل parts بتاعة
+
+52
+00:03:51,670 --> 00:03:52,990
+ال journal bearing
+
+53
+00:03:56,500 --> 00:04:02,920
+ال design process بشكل مبسط اللي بديه من .. من ..
+
+54
+00:04:02,920 --> 00:04:07,360
+بديه من هنا يعني
+
+55
+00:04:07,360 --> 00:04:12,820
+انا ببدأ في عندي احتياج I define the problem بعمل
+
+56
+00:04:12,820 --> 00:04:19,140
+analysis للمشكلة تحت الدراسة بعدين identify key
+
+57
+00:04:19,140 --> 00:04:22,220
+requirements بحدد المتطلبات الأساسية من المنتج
+
+58
+00:04:22,220 --> 00:04:27,230
+اللي انا بدي أعمله designيعني لو بدى اعمل ماكينة
+
+59
+00:04:27,230 --> 00:04:31,250
+لفرم البلاستيك والله بحكي للماكينة هذه بدى اتفرم
+
+60
+00:04:31,250 --> 00:04:35,310
+البلاستيك من نوع نيلون هذا requirement او من نوع
+
+61
+00:04:35,310 --> 00:04:41,230
+PET او من نوع ABS بدى الطاقة الإنتاجية بتاعتها
+
+62
+00:04:41,230 --> 00:04:47,270
+مثلا عشرة طن في الساعة بدى حجم ال particle مايزيدش
+
+63
+00:04:47,270 --> 00:04:50,970
+مثلا عن اتنين صمتة انا هذه كلها requirement في ال
+
+64
+00:04:50,970 --> 00:04:55,980
+product تبعتيطبعا مافيش حاجة نبدأ في الصفر مثلا
+
+65
+00:04:55,980 --> 00:04:58,500
+بعمل literature review أو بعمل research بشوف الناس
+
+66
+00:04:58,500 --> 00:05:02,220
+تانين إيه مش مشتغلين research سواء روحت على ..
+
+67
+00:05:02,220 --> 00:05:07,140
+شوفت machines تانية أو استشارت مهندسين تانين أو
+
+68
+00:05:07,140 --> 00:05:11,640
+خبراء تانين أو حتى خشيت .. خشيت على internet وشوفت
+
+69
+00:05:12,050 --> 00:05:14,770
+أبحاث منشورة عن نفس الموضوع اللي أنا حشت عليه
+
+70
+00:05:14,770 --> 00:05:18,490
+فلازم أعمل research لازم أجمع بيانات قدر الإمكان
+
+71
+00:05:18,490 --> 00:05:22,010
+بعدين بعمل ID generation بعدين بعمل sketching
+
+72
+00:05:22,010 --> 00:05:25,970
+لمكونات ال machine ماحكي ال machine لازم يكون فيها
+
+73
+00:05:25,970 --> 00:05:29,950
+مثلا one shaft نتيجة ال research مثلا الشريدينج
+
+74
+00:05:29,950 --> 00:05:33,930
+machines فيه بتكون one shaft machine فيه two shaft
+
+75
+00:05:33,930 --> 00:05:36,850
+machines فيه three shaft machines فيه four shaft
+
+76
+00:05:36,850 --> 00:05:41,980
+machines فيه أنواع شفر مختلفةانواع ال reduction في
+
+77
+00:05:41,980 --> 00:05:45,440
+ال speed مختلفة فانا ببدأ اعمل formulate او
+
+78
+00:05:45,440 --> 00:05:50,400
+generate اللي هي فكرة التصميم بتاعي لان once I
+
+79
+00:05:50,400 --> 00:05:55,040
+generated الفكرة ببدأ اخش تفاصيل اكتر بعمل idea
+
+80
+00:05:55,040 --> 00:06:00,000
+development ببدأ افصل اكتر طبعا ال process هذه مش
+
+81
+00:06:00,000 --> 00:06:04,520
+sequential مية في المية يعني while I'm doing مثلا
+
+82
+00:06:04,520 --> 00:06:10,560
+idea generationممكن احتاج ارجع اعمل research اكتر
+
+83
+00:06:10,560 --> 00:06:14,260
+حاول اكتشف ان الله عندي بدي معلومات اكتر او حتى من
+
+84
+00:06:14,260 --> 00:06:18,660
+انا لو كنت في مرحلة ال research لان انا كان عندي
+
+85
+00:06:18,660 --> 00:06:22,000
+الفكرة المبسطة للمشيين انه تكون one shaft لان
+
+86
+00:06:22,000 --> 00:06:24,100
+اكتشفت والله ممكن تكون two shaft او three shaft
+
+87
+00:06:24,100 --> 00:06:28,060
+معناه انت برجع بعدل ايش identify اللي هو key
+
+88
+00:06:28,060 --> 00:06:33,780
+requirementsonce I developed ال idea completely
+
+89
+00:06:33,780 --> 00:06:40,800
+بعمل ال designs تصميم طبعا بعد بعمل ال design
+
+90
+00:06:40,800 --> 00:06:44,660
+بستخدم مثلا CAD ال software ممكن استخدم solid work
+
+91
+00:06:44,660 --> 00:06:50,820
+inventor IDs او اي برنامج تانيبعمل simulation لل
+
+92
+00:06:50,820 --> 00:06:54,080
+machine بتاعتي انا مش كل الخطوات مذكورة بعمل
+
+93
+00:06:54,080 --> 00:06:58,580
+محاكاة لل machine محاكاة ممكن اعمل محاكاة للحركة
+
+94
+00:06:58,580 --> 00:07:03,060
+انها بتتحرك بشكل صحيح ممكن اعمل محاكاة لل forces
+
+95
+00:07:03,060 --> 00:07:07,740
+ممكن اعمل محاكاة لل stresses ممكن اعمل محاكاة لل
+
+96
+00:07:07,740 --> 00:07:12,560
+.. لل deflections اذا في درجات الحرارة ممكن اعمل
+
+97
+00:07:12,560 --> 00:07:15,440
+محاكاة لتوزيع درجات الحرارة في ال mechanical parts
+
+98
+00:07:15,440 --> 00:07:16,580
+اللي هي ال critical parts
+
+99
+00:07:20,060 --> 00:07:24,380
+وانصي ان انا انجحت في ال .. في ال .. في ال .. في
+
+100
+00:07:24,380 --> 00:07:31,740
+المحاكاة ان الامور كلها سليمة مية في المية و
+
+101
+00:07:31,740 --> 00:07:35,720
+احضر لوحات تفصيلية عشان تروح على ال production
+
+102
+00:07:35,720 --> 00:07:42,760
+الانتاج اللوحات التفصيلية هتروح لورش هندسية بدها
+
+103
+00:07:42,760 --> 00:07:47,140
+تصنع عشان تصنع لازم تشوف لوحات فيها تفاصيل
+
+104
+00:07:47,140 --> 00:07:52,950
+ومواصفات فنيةطبعا I produce في الأول ب .. بأنتجش
+
+105
+00:07:52,950 --> 00:07:55,710
+.. انا مثلا المفروض بدي أنتج مليون قطعة في السنة
+
+106
+00:07:55,710 --> 00:08:00,610
+بروحش أنتج مليون قطعة أول مرة بعمل إيهاش؟ نموذج ال
+
+107
+00:08:00,610 --> 00:08:04,070
+prototype طبعا هذه فيها تفصيل بعمل ال prototype في
+
+108
+00:08:04,070 --> 00:08:10,710
+ال prototype ببدأ أجرب فيه بكتشف بعض الأخطاء بعمل
+
+109
+00:08:10,710 --> 00:08:13,670
+.. انا ممكن أرجع جوا لخطوات دالورا ممكن أرجع على
+
+110
+00:08:13,670 --> 00:08:16,310
+ال .. ال idea مش واضحة عندي أعمل more idea
+
+111
+00:08:16,310 --> 00:08:21,000
+developmentأو حتى ال key requirements مش واضح عندي
+
+112
+00:08:21,000 --> 00:08:25,320
+فهي مش sequential مية في المية فانا I build ال
+
+113
+00:08:25,320 --> 00:08:28,780
+prototype بعمل testing على ال prototype بعمل
+
+114
+00:08:28,780 --> 00:08:32,020
+تعديلات على ال prototype ففيه iteration احنا فيها
+
+115
+00:08:32,020 --> 00:08:37,460
+نحكي ان انا فيها H Iteration once I reach
+
+116
+00:08:37,460 --> 00:08:42,060
+finalization او optimized the prototype ببدأ عملية
+
+117
+00:08:42,060 --> 00:08:44,880
+الإنتاج اللي هي ال mass production
+
+118
+00:08:49,070 --> 00:08:56,290
+أنا ذكرت كذا شغلة طبعا خلصت من عملية الإنتاج طبعا
+
+119
+00:08:56,290 --> 00:09:00,530
+في مراحل ممكن أبدأ أحضر للتسويق بشكل مسبق يعني مش
+
+120
+00:09:00,530 --> 00:09:05,290
+هستنى أنا أخلص كل خطوات و أبدأ أعمل حملة تسويقية
+
+121
+00:09:05,290 --> 00:09:11,130
+أو حملة إدعائية ممكن أحضر بشكل مسبق بدخل الأسواق
+
+122
+00:09:11,130 --> 00:09:16,570
+دخلت الأسواقممكن نفس المستخدمين يكتشفوا بعض ال ..
+
+123
+00:09:16,570 --> 00:09:20,750
+او بعض العيوب في المنتج او يحتاجوا تفاصيل او
+
+124
+00:09:20,750 --> 00:09:24,950
+خيارات اضافية في المنتج فلازم ان انا اتخذ راجعة من
+
+125
+00:09:24,950 --> 00:09:30,030
+الزبائن عشان اعمل مثلا اللي هو second version من
+
+126
+00:09:30,030 --> 00:09:34,590
+ال product احط عليها الإضافات او متطلبات الزبائن
+
+127
+00:09:34,590 --> 00:09:37,690
+في سؤال حتى اللحظة؟
+
+128
+00:09:43,350 --> 00:09:46,230
+when we design لما نعمل design لازم ناخد في
+
+129
+00:09:46,230 --> 00:09:50,990
+الاعتبار التالي احنا حكينا ال functionality ان
+
+130
+00:09:50,990 --> 00:09:54,830
+المنتج او ال machine لازم تقدر المهمة المطلوبة
+
+131
+00:09:54,830 --> 00:10:00,990
+منها ال strength و ال stresses ال stresses في ال
+
+132
+00:10:00,990 --> 00:10:05,250
+mechanical parts المكونة للمachine مش لازم تتجاوز
+
+133
+00:10:05,250 --> 00:10:11,430
+ال stresses المسموح فيهابتبحث against distortion
+
+134
+00:10:11,430 --> 00:10:14,710
+إذا فيه هنيلاي أو deflections، مابتديش .. مابتدي
+
+135
+00:10:14,710 --> 00:10:18,490
+تكون عندي distortions و deflections below القيم
+
+136
+00:10:18,490 --> 00:10:22,370
+المسموح فيها ال weird مابتديش يصير تآكل في ال ..
+
+137
+00:10:22,370 --> 00:10:26,690
+في ال .. في ال parts ال corrosion مابتديش يصير
+
+138
+00:10:26,690 --> 00:10:31,230
+فيها تآكل، ال corrosion ممكن يكون صدا أو أي اشي
+
+139
+00:10:31,230 --> 00:10:34,660
+تانيإذا كانت في بيئة بحرية، بيعني أنت بدأ تختار
+
+140
+00:10:34,660 --> 00:10:37,760
+material تقاوم البيئة البحرية، إذا كانت بيئة
+
+141
+00:10:37,760 --> 00:10:42,940
+حرارية، بدي أختار مواد تقاوم الحرارة، إذا كانت
+
+142
+00:10:42,940 --> 00:10:45,600
+البيئة الكيميائية، بدي أتقاوم المواد الكيميائية
+
+143
+00:10:45,600 --> 00:10:49,180
+لحتى تتعامل معاها، تتعامل ال machine معاها safety
+
+144
+00:10:49,180 --> 00:10:52,940
+ال machine لازم يكون safe ال machine لازم يكون
+
+145
+00:10:52,940 --> 00:10:57,880
+reliable، يعتاد بها، مافيش عطالة كتير قابل للتصنيع
+
+146
+00:10:59,150 --> 00:11:05,510
+utility قابل للاستخدام ال cost يكون مناسب ال
+
+147
+00:11:05,510 --> 00:11:08,310
+friction بعض الأحيان ال friction ممكن يكون لازم
+
+148
+00:11:08,310 --> 00:11:12,150
+بتعطيني ال friction اذا بعمل طير لازم اهتم في ال
+
+149
+00:11:12,150 --> 00:11:15,730
+friction characteristics بتاعة العجل بتاع السيارة
+
+150
+00:11:15,730 --> 00:11:18,750
+بعض الأحيان في application بديش انا الاحتكاك بيكون
+
+151
+00:11:18,750 --> 00:11:24,950
+مش مفيد مؤذىفي شغلات تانية، في الأسيار مثلا، أسيار
+
+152
+00:11:24,950 --> 00:11:28,030
+تنقل أغراض من مكان لمكان، أنا محتاج فريكشن،
+
+153
+00:11:28,030 --> 00:11:30,290
+الفريكشن أساسا هو اللي بيحركها، لو مافيش فريكشن
+
+154
+00:11:30,290 --> 00:11:36,830
+كافي، بيصير انزلاق، بيبقى ال part محله ال weight
+
+155
+00:11:39,670 --> 00:11:43,590
+بصنع body لطيارة مش .. مش منطقي يعني ال body يكون
+
+156
+00:11:43,590 --> 00:11:48,870
+مصنوع من مادة ثقيلة جدا من الارصاص مثلا كثافته
+
+157
+00:11:48,870 --> 00:11:54,250
+عالية جدا، بدي أختار مواد قوية جدا وخفيفة جدا، بدي
+
+158
+00:11:54,250 --> 00:11:58,610
+أصنع نضارة، نضارات مثلا حاليا بتكون الإطار بتاعها
+
+159
+00:11:58,610 --> 00:12:02,890
+plastic، ممكن يكون الإطار titanium، titanium سعره
+
+160
+00:12:02,890 --> 00:12:07,130
+.. وزنه خفيف كتير و ال strength بتاعته عال جدا،
+
+161
+00:12:07,130 --> 00:12:11,740
+العدساتالعدسات بتاعة النضارة بتكون plastic زجاج
+
+162
+00:12:11,740 --> 00:12:15,820
+polycarbonate كل واحدة لها مزايا وكلها عيوب مثلا
+
+163
+00:12:15,820 --> 00:12:22,980
+الزجاج صعب الخدش بس وزنه ثقيل ال plastic خفيف بس
+
+164
+00:12:22,980 --> 00:12:26,820
+سهل الخدش ال polycarbonate فيها المزتين خفت وزن
+
+165
+00:12:26,820 --> 00:12:30,980
+وفيها strength بتقاوم الخدوج فبيدرعي على كل
+
+166
+00:12:30,980 --> 00:12:37,000
+الشغلات هذه ال noiseبديش عمل يعني machine تكون
+
+167
+00:12:37,000 --> 00:12:42,100
+noisy تكون بتطلع مستوى الصوت او ضجيج مرتفع ممكن
+
+168
+00:12:42,100 --> 00:12:46,860
+يأثر على صحة أذن الإنسان المستخدم لهذه ال machine
+
+169
+00:12:46,860 --> 00:12:52,600
+ال styling شكل ال product الشكل مهم جدا انت لما
+
+170
+00:12:52,600 --> 00:12:56,260
+تشتري اي machine ممكن تشتري غسل غسلت نفس الأداء
+
+171
+00:12:56,260 --> 00:12:59,660
+تماما 100% بس تحكي والله هذه أحلى الغسالة من هذه
+
+172
+00:12:59,660 --> 00:13:06,060
+الغسالة ال ..ال shape ال size ال shape و ال size
+
+173
+00:13:06,060 --> 00:13:11,600
+دايما بيجوا مع بعض في بعض التطبيقات ال shape مهم
+
+174
+00:13:11,600 --> 00:13:15,920
+كتير بيأثر على الأداء زي مثلا الطائرات الطيارات
+
+175
+00:13:15,920 --> 00:13:18,660
+الشكلها مهم كتير بيأثر على الأداء بيأثر على سلاك
+
+176
+00:13:18,660 --> 00:13:24,580
+الوقود ال control يكون ال control system ال
+
+177
+00:13:24,580 --> 00:13:27,180
+control مفتوح كتير يعني انها easy to control او ال
+
+178
+00:13:27,180 --> 00:13:31,490
+control system بتاعها يكون بسيطفي بعض التطبيقات
+
+179
+00:13:31,490 --> 00:13:35,690
+محتاج thermal properties إذا أنا بعمل تبريد تكييف
+
+180
+00:13:35,690 --> 00:13:39,470
+بدي أعمل جدران بدي أستخد المعواز الحرارية مش .. مش
+
+181
+00:13:39,470 --> 00:13:42,750
+منطق أحط معواز الحرارية تكون حديد هستخدم مواد
+
+182
+00:13:42,750 --> 00:13:49,130
+خصائصها الحرارية مناسبة ال surface surface finish
+
+183
+00:13:49,130 --> 00:13:53,230
+بدخل تحت كتير ال surface finish نفسه النقومة بعض
+
+184
+00:13:53,230 --> 00:13:57,090
+الحين بيلزمني أكون عندي سطح نعم بعض الحين في أحيان
+
+185
+00:13:57,090 --> 00:14:01,170
+أخر بيلزمني سطح خشم مثلا انا بدي عندياندي نبط ل
+
+186
+00:14:01,170 --> 00:14:05,930
+device مش صح يكون ال surface بتاعها نعم لازم يكون
+
+187
+00:14:05,930 --> 00:14:11,390
+فيه خشونة عشان اعمل friction كده فيه تلف معاه ال
+
+188
+00:14:11,390 --> 00:14:16,170
+application هل بيبذلني نظام تزيد ل .. ل .. ل .. ل
+
+189
+00:14:16,170 --> 00:14:20,900
+.. بحيث ان اقل ال .. ال .. ال frictionال
+
+190
+00:14:20,900 --> 00:14:23,920
+marketability قابلة لتسويق ولا مش قابلة لتسويق كل
+
+191
+00:14:23,920 --> 00:14:27,220
+هذه design considerations ال maintenance ال
+
+192
+00:14:27,220 --> 00:14:30,620
+machine او ال mechanical system should be easy to
+
+193
+00:14:30,620 --> 00:14:35,160
+maintain لازم يكون سهل الصيانة ال volume يعني اذا
+
+194
+00:14:35,160 --> 00:14:39,860
+انا ممكن اعمل machine حجمها مثلا تلاتة في اتنين في
+
+195
+00:14:39,860 --> 00:14:43,720
+واحد متر واحد تاني ممكن اعملها بحجم اصغر كل ما قلي
+
+196
+00:14:43,720 --> 00:14:49,610
+الحجم كل ما كان احسنLiability، liability اللي هي
+
+197
+00:14:49,610 --> 00:14:54,770
+الأمور أو المسئولية القانونية، إذا عندي منتج قد
+
+198
+00:14:54,770 --> 00:14:59,890
+يؤدي إلى الوفاء مثلا نتيجة استخدام سيء أو نتيجة
+
+199
+00:14:59,890 --> 00:15:04,790
+تصميم سيء، أنا هتحمل مسئولية قانونية، أنا أعمل
+
+200
+00:15:04,790 --> 00:15:11,710
+مثلا جهاز في المجال الطبيمثلا عمل جهاز يساعد الناس
+
+201
+00:15:11,710 --> 00:15:15,610
+دو الاحتجازات الخاصة انهم يمشوا اكتشف ان الجهاز
+
+202
+00:15:15,610 --> 00:15:19,530
+بشكل خطور على ال .. على ال .. على الأشخاص وبيقدر
+
+203
+00:15:19,530 --> 00:15:22,970
+انهم يصير وقوع متكارئ لهم ويصير كثور معناته انا
+
+204
+00:15:22,970 --> 00:15:26,190
+هتحسب على الكلام هذا من ناحية قانونية
+
+205
+00:15:26,190 --> 00:15:30,730
+remanufactability
+
+206
+00:15:30,730 --> 00:15:37,020
+and our resource recoveryهل ممكن اعادة تدويره و
+
+207
+00:15:37,020 --> 00:15:41,860
+اعادة تصنيع المنتج؟ هذه صارت حاليا اشي مهم كتير ان
+
+208
+00:15:41,860 --> 00:15:44,920
+اعمل product بحيث يمكن اعادة تصنيعها او اعادة
+
+209
+00:15:44,920 --> 00:15:48,640
+تدويرها ترجع للحياة مرة جديدة هذه كلها design
+
+210
+00:15:48,640 --> 00:15:51,460
+considerations اللي لازم ناخدها في الاعتبار لما
+
+211
+00:15:51,460 --> 00:15:52,760
+نصمم اي منتج
+
+212
+00:15:55,240 --> 00:15:58,920
+طبعا بالزمن ال computational tools بالزمن الأدوات
+
+213
+00:15:58,920 --> 00:16:02,520
+بتساعدني في عملية التصميم بتسميه في الحالة
+
+214
+00:16:02,520 --> 00:16:06,180
+computer-aided engineering اللي هي أي استخدام
+
+215
+00:16:06,180 --> 00:16:08,940
+للكمبيوتر و ال software اللي بتساعدني في عملية
+
+216
+00:16:08,940 --> 00:16:12,000
+التصميم هذه اللي هي computer-aided engineering
+
+217
+00:16:12,000 --> 00:16:15,380
+طبعا فاندي computer-aided design packages اللي هي
+
+218
+00:16:15,380 --> 00:16:18,640
+ال CAD زي ال solid work ال auto CAD ال inventors
+
+219
+00:16:18,640 --> 00:16:23,640
+هذه كلها تابعة عائلة ال CAD computer-aided
+
+220
+00:16:23,640 --> 00:16:29,880
+manufacturingبتساعد في عملية التصنيع بدخل تحتها ال
+
+221
+00:16:29,880 --> 00:16:33,500
+.. ال .. ال .. ال CNC ال rapid prototyping ال 3D
+
+222
+00:16:33,500 --> 00:16:38,380
+printers كلها تدخل تحت ال manufacturing فى برامج
+
+223
+00:16:38,380 --> 00:16:43,800
+كتير فى مثلا فى ال CNC ان ال master cam فى هنا
+
+224
+00:16:43,800 --> 00:16:47,540
+clear cut فى edge cut فى كتير برامج فى ال computer
+
+225
+00:16:47,540 --> 00:16:51,560
+aided manufacturing فى فى ال engineering tools
+
+226
+00:16:51,560 --> 00:16:55,640
+analysis and simulationفي برامج الـ finite element
+
+227
+00:16:55,640 --> 00:17:01,360
+analysis زي ansys اباكاس نيسا IDs في برامج كتير
+
+228
+00:17:01,360 --> 00:17:03,960
+تستخدم في ال finite element analysis فيه اللي هو
+
+229
+00:17:03,960 --> 00:17:08,740
+CFD computation fluid dynamics and dynamic
+
+230
+00:17:08,740 --> 00:17:10,900
+analysis زي Adams simulation X
+
+231
+00:17:13,490 --> 00:17:18,430
+في ال math solvers زي برامج ال Excel، Excel هي ال
+
+232
+00:17:18,430 --> 00:17:23,510
+spreadsheets فين هي لغات البرمجة زي ال C++ زي ال
+
+233
+00:17:23,510 --> 00:17:27,030
+Java وفي لغات برمجة جديدة بدأت تظهر فين ال
+
+234
+00:17:27,030 --> 00:17:30,910
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+
+235
+00:17:30,910 --> 00:17:35,450
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+236
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+كل هذه الشغلات تلزم في عملية التصميم وكلها
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+المكتبات اللي هي من خلال ال engineering hand box
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+241
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+او ال text box او ال journals او الاختراعات براية
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+00:18:04,620 --> 00:18:10,250
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+00:18:14,430 --> 00:18:19,810
+في غزة بتروح على وزارة الزراعة عندك اللي هو ال US
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+patent and trademark في كل بلد في مكتب لتسجيل
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+247
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+00:18:33,550 --> 00:18:37,070
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+249
+00:18:37,070 --> 00:18:40,170
+مثل اختراع اذا ان ال document بيكلف اتنين و نص
+
+250
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+251
+00:18:45,730 --> 00:18:52,850
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+252
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+254
+00:19:00,190 --> 00:19:04,210
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+00:19:04,210 --> 00:19:06,530
+Society of Mechanical Engineers Society of
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+00:19:06,530 --> 00:19:10,010
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+00:19:10,010 --> 00:19:14,850
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+260
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+catalogات اللي .. اللي بتصدرها الشركات حين صارت
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+263
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+
+264
+00:19:39,650 --> 00:19:44,010
+على SKF او NSK هم عندهم ال calculators الخاصة بحط
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+265
+00:19:44,010 --> 00:19:47,910
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+266
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+267
+00:19:51,530 --> 00:19:56,590
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+268
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+أكبر المصادر المتاحة حاليا
+
+269
+00:20:02,510 --> 00:20:07,050
+في useful internet sites هذه من ال .. طبعا .. طبعا
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+00:20:07,050 --> 00:20:10,810
+هذه بتتغير من يوم ليوم ويمكن تحديثها ويمكن تكتشفوا
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+271
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+272
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+spec هذا مشهور كتير فعندي ang net global فعندي e
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+273
+00:20:19,310 --> 00:20:24,010
+fundamentals فعندي thomas net فعندي US patent
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+274
+00:20:24,010 --> 00:20:28,810
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+
+275
+00:20:35,810 --> 00:20:41,330
+الان ايش مسئولية مهندس التصميم؟
+
+276
+00:20:41,330 --> 00:20:46,590
+اول مهمة او من مسئوليات المهندس التصميم انه يحقق
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+278
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+279
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+الان في بعض النصائح اللى ممكن واجهها لمهندس
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+280
+00:21:04,400 --> 00:21:08,640
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+
+281
+00:21:08,640 --> 00:21:12,620
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+282
+00:21:12,620 --> 00:21:17,800
+مستواك ضيف keep current in the field of practice
+
+283
+00:21:17,800 --> 00:21:23,120
+دايما حدث و جدد معلوماتك و خبراتك keep good
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+00:21:23,120 --> 00:21:26,780
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+285
+00:21:26,780 --> 00:21:33,280
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+286
+00:21:33,280 --> 00:21:35,960
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+287
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+288
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+289
+00:21:42,020 --> 00:21:46,020
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+
+290
+00:21:46,020 --> 00:21:52,220
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+
+291
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+292
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+293
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+294
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+معلومات فنية بحتها مش معلومات أي كلام و تخضع
+
+295
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+296
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+297
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+298
+00:22:34,720 --> 00:22:38,120
+practice في national society of professional
+
+299
+00:22:38,120 --> 00:22:42,800
+engineers ال NSPA طبعة code of ethics for
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+300
+00:22:42,800 --> 00:22:46,560
+engineers and engineers agreed خشوا على الصفحة هذه
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+301
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+302
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+303
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+304
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+305
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+306
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+
+307
+00:23:22,120 --> 00:23:26,420
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+308
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+
+309
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+310
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+325
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+
+386
+00:29:39,760 --> 00:29:40,020
+codes
+
+387
+00:29:44,450 --> 00:29:52,090
+الجانب الاقتصادي في عملية التصميم مهم جدا لان في
+
+388
+00:29:52,090 --> 00:29:57,950
+الآخر انا بدي اعمل منتجات بمستوى جودة معين بتكلفة
+
+389
+00:29:57,950 --> 00:30:02,150
+مناسبةطبعا اول principle طبعا فيه principles كتير
+
+390
+00:30:02,150 --> 00:30:05,930
+من اهم ال principles في الاقتصاديات ال .. ال .. ال
+
+391
+00:30:05,930 --> 00:30:13,310
+design ان استخدم standard size standard size يعني
+
+392
+00:30:13,310 --> 00:30:18,630
+لازمنا استخدم في machine معينة برغة البراغ فيها
+
+393
+00:30:18,630 --> 00:30:22,230
+standards موجودة في الأسواق ليش اصمم برغ خاص و
+
+394
+00:30:22,230 --> 00:30:27,100
+اصنع خصيصا اذا فيه standard قريبالزمنى terrace و
+
+395
+00:30:27,100 --> 00:30:33,220
+في terrace ال terrace في كتير صار ينتج بمواصفات
+
+396
+00:30:33,220 --> 00:30:37,060
+قياسية و بكميات و باسعار منافسة ليش اعمل terrace
+
+397
+00:30:37,060 --> 00:30:40,660
+خاص بعمل شوية تعديلات على ال design عشان اخد اللي
+
+398
+00:30:40,660 --> 00:30:47,920
+هو ال standard sizeطب استخدم standard sizes كمان
+
+399
+00:30:47,920 --> 00:30:51,480
+في ال dimensions في ال table 17 بيعطينا standard
+
+400
+00:30:51,480 --> 00:30:55,680
+sizes فيه اندهين مثلا ناخد ال metric system
+
+401
+00:30:55,680 --> 00:31:00,260
+millimeter system عندك
+
+402
+00:31:00,620 --> 00:31:10,080
+.O5.O6.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7
+
+403
+00:31:10,080 --> 00:31:13,920
+.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7
+
+404
+00:31:13,920 --> 00:31:20,420
+.O7.O7
+
+405
+00:31:20,420 --> 00:31:24,820
+.O7.O7
+
+406
+00:31:24,820 --> 00:31:27,220
+.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7
+
+407
+00:31:27,220 --> 00:31:28,140
+.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7.O7
+
+408
+00:31:28,140 --> 00:31:28,920
+.O7.O7.O7.O7.O7.O7.O
+
+409
+00:31:34,600 --> 00:31:40,100
+متسامح الان ال tolerance معناته التسامح في ال
+
+410
+00:31:40,100 --> 00:31:44,720
+dimensions لل mechanical parts عادة كل ما كانت
+
+411
+00:31:44,720 --> 00:31:47,900
+الدقة عالية في ال mechanical part كل ما التكلفة
+
+412
+00:31:47,900 --> 00:31:53,620
+ترتفع ترتفع ليش لأنه محتاج لعملية تصنيع إضافية
+
+413
+00:31:53,620 --> 00:31:57,780
+محتاج inspection فحص للقراءات
+
+414
+00:32:01,670 --> 00:32:06,530
+machines with lower production rates كل ما زاد ال
+
+415
+00:32:06,530 --> 00:32:08,970
+production rate بتاع ال machine كل ما بدى التساوم
+
+416
+00:32:08,970 --> 00:32:12,590
+أكتر في ال dimensions إذا بدى دقة أعلى أعلى أعلى
+
+417
+00:32:12,590 --> 00:32:18,390
+ال production capacity أشملها بتقل بشكل عام طبعا
+
+418
+00:32:18,390 --> 00:32:22,490
+ال curve هذا موارديني
+
+419
+00:32:22,490 --> 00:32:28,390
+ال cost مع ال tolerance طبعا في هذا الاتجاهال
+
+420
+00:32:28,390 --> 00:32:31,410
+tolerance بقل يعني سياندي هنا ال tolerance point o
+
+421
+00:32:31,410 --> 00:32:35,890
+o o o two five هنا في البداية point o تلاتة يعني
+
+422
+00:32:35,890 --> 00:32:40,070
+هنا التساومح كتير هنا التساومح شماله قليل واضح ال
+
+423
+00:32:40,070 --> 00:32:47,350
+course المقاله بقلع مع ارتفاع ات ا ا ا ا ا ا ا ا ا
+
+424
+00:32:47,350 --> 00:32:48,330
+ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا
+
+425
+00:32:48,330 --> 00:32:48,530
+ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا
+
+426
+00:32:48,530 --> 00:32:48,810
+ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا
+
+427
+00:32:48,810 --> 00:32:48,950
+ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا
+
+428
+00:32:48,950 --> 00:32:48,990
+ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا ا
+
+429
+00:32:48,990 --> 00:32:49,490
+ا ا ا ا ا ا ا ا ا ا ا ا ا ا
+
+430
+00:32:55,690 --> 00:33:02,130
+بعض احيان بدي عندى خيارات بدي خيارات الخيارات
+
+431
+00:33:02,130 --> 00:33:06,970
+محتاج اعمل break even analysis مثلا عندى هنا
+
+432
+00:33:06,970 --> 00:33:13,430
+example عندى
+
+433
+00:33:13,430 --> 00:33:19,190
+في عندى بدي اعمل two mechanical او two production
+
+434
+00:33:19,190 --> 00:33:21,870
+systems احد ال production system بستخدم automatic
+
+435
+00:33:21,870 --> 00:33:26,750
+screw machineالخيار التاني hand hand او manual
+
+436
+00:33:26,750 --> 00:33:31,310
+screw machine يعني في ماكينة قالية و في ماكينة
+
+437
+00:33:31,310 --> 00:33:35,630
+يدوية لأن الماكينة القالية بتعطيني خمس و عشرين
+
+438
+00:33:35,630 --> 00:33:38,690
+parts per hour الإنتاج يتعدى خمس و عشرين قطعة
+
+439
+00:33:38,690 --> 00:33:42,630
+بالساعة الماكينة اليدوية عشرة قطعة بالساعة
+
+440
+00:33:42,630 --> 00:33:47,830
+الماكينة القالية محتاجة كل مرة في بداية اليوم او
+
+441
+00:33:47,830 --> 00:33:52,430
+في بداية وضع القوالب و خلافه setup time تلت ساعات
+
+442
+00:33:53,810 --> 00:33:59,450
+تكلفة العمالة عشرين دولار في الساعة هنا مش محتاجة
+
+443
+00:33:59,450 --> 00:34:03,730
+setup يعني zero time for setup تكلفة العمالة هي
+
+444
+00:34:03,730 --> 00:34:09,310
+بغض النظر عن ال machine عشرين دولار في الساعة الآن
+
+445
+00:34:09,310 --> 00:34:17,290
+ال cost نحكي اللي هو واحد ال automatic screw
+
+446
+00:34:17,290 --> 00:34:25,070
+machine ال costهيكون ال variable جزئين في fixed
+
+447
+00:34:25,070 --> 00:34:29,510
+زاد
+
+448
+00:34:29,510 --> 00:34:34,510
+اللي هو ال variable ال
+
+449
+00:34:34,510 --> 00:34:42,230
+fixed عنده تلت باخد عنده هنا تلت ساعات setup time
+
+450
+00:34:42,230 --> 00:34:47,970
+تلت hour في عشرين
+
+451
+00:34:51,760 --> 00:35:03,840
+الدولار في الساعة زاد ال variable عنده
+
+452
+00:35:03,840 --> 00:35:10,080
+عشرين عشرين
+
+453
+00:35:10,080 --> 00:35:17,480
+اللي هي الدولار على كل ساعة
+
+454
+00:35:20,210 --> 00:35:29,150
+على خمسة و عشرين part لكل ساعة في number of parts
+
+455
+00:35:29,150 --> 00:35:37,790
+صح ال number of parts وحدتها ايش هكون part يعني
+
+456
+00:35:37,790 --> 00:35:41,890
+هكون part مع part بتروح اول ممارس دولار ايش
+
+457
+00:35:41,890 --> 00:35:48,520
+دولارات الممارس هتكون تلاتة فعشان هتكون ستينزاد
+
+458
+00:35:48,520 --> 00:35:52,800
+عشان على خمسين زاد من تمانية ال number of produced
+
+459
+00:35:52,800 --> 00:35:57,580
+parts هذا في حالة اللي هي automatic screw machine
+
+460
+00:35:57,580 --> 00:36:04,980
+في حالة ال hand screw machine screw
+
+461
+00:36:04,980 --> 00:36:11,460
+machine عند ال cost بالصورة
+
+462
+00:36:11,460 --> 00:36:17,620
+ال fixed اندي اش فيش setup سفر زاد
+
+463
+00:36:20,550 --> 00:36:29,650
+عندي اللي هو عشرين على عشرة صح في N يعني هكون
+
+464
+00:36:29,650 --> 00:36:36,690
+اتنين N متى
+
+465
+00:36:36,690 --> 00:36:40,390
+ال two options بيكون متساويين خلاص لما دي cost one
+
+466
+00:36:40,390 --> 00:36:49,770
+cost two لما cost one بيساوي cost two يعني هكون
+
+467
+00:36:49,770 --> 00:36:57,300
+عندىاللي هو ستين زي تمانية من عشرة N بالساوية
+
+468
+00:36:57,300 --> 00:37:06,200
+اتنين N يعني واحد point اتنين N بالساوية ستين يعني
+
+469
+00:37:06,200 --> 00:37:17,360
+N شو يساوي خمسين part كل ساعةهنا انا اعمل plot لل
+
+470
+00:37:17,360 --> 00:37:20,000
+production capacity ال number of parts as a
+
+471
+00:37:20,000 --> 00:37:26,060
+function of cost احنا وجدنا عند الخمسين ال two
+
+472
+00:37:26,060 --> 00:37:31,360
+systems بيعطوني نفس النتيجة عند الخمسين هذه خمسين
+
+473
+00:37:31,360 --> 00:37:38,080
+بيعطوني نفس النتيجة ال cost عند الخمسين هيكون ال
+
+474
+00:37:38,080 --> 00:37:38,500
+cost
+
+475
+00:37:41,420 --> 00:37:48,260
+one هيكون عندى ستين زي تمام من عشرة في خمسين
+
+476
+00:37:48,260 --> 00:37:54,880
+بالساويهاش مية مية دولار فعلا
+
+477
+00:37:54,880 --> 00:38:02,660
+ال cost بيكون مية دولار طيب
+
+478
+00:38:04,450 --> 00:38:08,270
+تحت الخمسين في عنواناته عند الخمسين بتساوى معناه
+
+479
+00:38:08,270 --> 00:38:12,750
+تحت الخمسين و أعلى من الخمسين بيختلفوا is for n
+
+480
+00:38:12,750 --> 00:38:22,350
+أقل من خمسين طبعا لحظه لحظه ال cost اتنين ال cost
+
+481
+00:38:22,350 --> 00:38:28,190
+اتنين اتنين n يعني هي ال care بتاعها بدي من الصفر
+
+482
+00:38:36,080 --> 00:38:39,000
+لما انت ساعة صفر بتكون في اندي initial cost setup
+
+483
+00:38:39,000 --> 00:38:46,700
+time ستين هاي ال cost اتنين بدينا
+
+484
+00:38:46,700 --> 00:38:54,420
+من الستين طبعا مافيش داعي كتير افكر اذا هاد بدى من
+
+485
+00:38:54,420 --> 00:38:57,360
+ستين مستحيل تكون زي هيك مش هال تقوى في الخمسين
+
+486
+00:38:57,360 --> 00:38:59,940
+معناه ال slope بتاعها هاد هتكون اقل و مبين ال
+
+487
+00:38:59,940 --> 00:39:02,840
+slope عندي هنا عندي ال slope هنا اتنين هي ال slope
+
+488
+00:39:02,840 --> 00:39:08,840
+اكم تمانية من عشرةطيب واضح حد بسمي break even
+
+489
+00:39:08,840 --> 00:39:14,520
+analysis واضح انه ال .. ال manual machine اذا ال
+
+490
+00:39:14,520 --> 00:39:19,400
+production capacity منخفضة بتكون مش دي اكتر لكن
+
+491
+00:39:19,400 --> 00:39:22,000
+اذا ال production capacity بتكون اكتر من خمسية
+
+492
+00:39:22,000 --> 00:39:24,820
+يعني ال production capacity عالية هيكون اللي هو ال
+
+493
+00:39:24,820 --> 00:39:27,460
+automatic machine اوفر يعني انا اخدت هنا
+
+494
+00:39:27,460 --> 00:39:33,370
+production capacity عند عشرينواضح هاي ال cost لل
+
+495
+00:39:33,370 --> 00:39:35,630
+automatic machine و هاي ال cost لل manual machine
+
+496
+00:39:35,630 --> 00:39:42,990
+فى فرق عند اخد مثلا 80 هنا فى
+
+497
+00:39:42,990 --> 00:39:48,190
+فرق ال fixed machine بتكلف اكتر من او ال manual
+
+498
+00:39:48,190 --> 00:39:53,550
+machine بتكلف اكتر من ال automatic machine فاختيار
+
+499
+00:39:53,550 --> 00:39:56,910
+لل option تبعى بعتمد على ال production capacity
+
+500
+00:39:56,910 --> 00:39:58,330
+المطلوبة منه
+
+501
+00:40:01,090 --> 00:40:07,810
+يعني مش دايما الاتمة هي الحل حسب التكلفة المالية
+
+502
+00:40:07,810 --> 00:40:27,610
+الان
+
+503
+00:40:27,610 --> 00:40:31,830
+ال safety الأمانال product liability اللي هي
+
+504
+00:40:31,830 --> 00:40:37,070
+المسئولية القانونية اول شي manufacturer is liable
+
+505
+00:40:37,070 --> 00:40:40,630
+for damage or harm that results because of a
+
+506
+00:40:40,630 --> 00:40:46,150
+defect المصنع مسئول تحمل مسئولية القانونية
+
+507
+00:40:46,150 --> 00:40:52,030
+والجزائية لأي damage أو ضرر ناتج عن خلل في التصميم
+
+508
+00:40:52,030 --> 00:40:55,970
+أو التصنيع negligence
+
+509
+00:40:55,970 --> 00:41:03,880
+not need not be provenالاهمال مش محتاج اثبت ان هذا
+
+510
+00:41:03,880 --> 00:41:09,580
+مهمل بكون واضح calls for good engineering analysis
+
+511
+00:41:09,580 --> 00:41:12,100
+and design quality control and comprehensive
+
+512
+00:41:12,100 --> 00:41:19,540
+testing لان المطلوب مننا كمهندسين دايما نعمل تحليل
+
+513
+00:41:19,540 --> 00:41:26,970
+هندسة سليمنعمل equality control اللي هو ضبط الجودة
+
+514
+00:41:26,970 --> 00:41:31,630
+و نعمل فحوصات شاملة على المنتجات قبل ما تنزع على
+
+515
+00:41:31,630 --> 00:41:32,870
+السوق نتأكد انها 100%
+
+516
+00:41:39,000 --> 00:41:43,360
+الان ال strength ال stress and ال strength لو بدي
+
+517
+00:41:43,360 --> 00:41:46,420
+اقارن بين ال strength ال strength عبارة عن خاصية
+
+518
+00:41:46,420 --> 00:41:55,840
+للمادة بغض النظر عن حجمها او شكلها يعني الحديد او
+
+519
+00:41:55,840 --> 00:41:58,460
+نوع معين نوع الحديد ال tin style strength مثلا له
+
+520
+00:41:58,460 --> 00:42:03,620
+اربعمية ميجا بسكال بغض نظر شكله كان مدور مربع قطره
+
+521
+00:42:03,620 --> 00:42:09,750
+متر قطره واحد مليام هذه strength خاصية للمادةال
+
+522
+00:42:09,750 --> 00:42:15,630
+stress هي state of property بتمثل عن إجهاد في نقطة
+
+523
+00:42:15,630 --> 00:42:20,350
+معينة في ال mechanical part طبعا الإجهاد بيعتمدش
+
+524
+00:42:20,350 --> 00:42:25,870
+على ال material بيعتمد على ال shape و ال size يعني
+
+525
+00:42:25,870 --> 00:42:28,990
+ال geometry بيعتمد على ال geometry و ال loading
+
+526
+00:42:28,990 --> 00:42:32,530
+condition برضهنوع ال loading هل هو loading tensile
+
+527
+00:42:32,530 --> 00:42:35,350
+loading، هل هو bending loading، هل هو torsion
+
+528
+00:42:35,350 --> 00:42:37,530
+loading، هل هو combination loading، يعني بيتمت على
+
+529
+00:42:37,530 --> 00:42:41,190
+ال loading وعلى ال geometry وبعض الأحيان بيتمت
+
+530
+00:42:41,190 --> 00:42:47,670
+كمان على ال temperature ال
+
+531
+00:42:47,670 --> 00:42:51,290
+uncertainty
+
+532
+00:42:51,290 --> 00:43:00,480
+ايش يعني certain؟ certain ايش معناها؟متأكد
+
+533
+00:43:00,480 --> 00:43:05,920
+uncertain مش متأكد معناته ال uncertain بتمثل اللي
+
+534
+00:43:05,920 --> 00:43:12,980
+هو يعني اختلاف القياسات عما هو إيش مقصود أو هو
+
+535
+00:43:12,980 --> 00:43:17,560
+مطلوب هذا ال uncertainty common sources of
+
+536
+00:43:17,560 --> 00:43:20,940
+uncertainty in stress or strength يعني أحد المصائل
+
+537
+00:43:20,940 --> 00:43:27,850
+العوامل اللي بتقدر للاختلاف كتيرةممكن تكون منفردة
+
+538
+00:43:27,850 --> 00:43:34,170
+الأسباب أو مجتمعة ممكن ال composition of material
+
+539
+00:43:34,170 --> 00:43:38,950
+ما تكونش في المادة متجانس في ناحية تركبية مافيش
+
+540
+00:43:38,950 --> 00:43:44,330
+تجانس في التركيب، منطقة فيها شوايب أكتر من التانية
+
+541
+00:43:48,640 --> 00:43:53,260
+effect of processing locally or nearby properties
+
+542
+00:43:53,260 --> 00:44:00,760
+عملية التصنيع بتأثر برضه على الخواص أي عملية تصنيع
+
+543
+00:44:00,760 --> 00:44:06,560
+بيكون فيها نسبة خطأ غير نسبة خطأ عملية تصنيع بتأثر
+
+544
+00:44:06,560 --> 00:44:09,440
+على الخواص مثلا انا اعمل جيبت قطع عندي rolling
+
+545
+00:44:09,440 --> 00:44:10,300
+process
+
+546
+00:44:16,930 --> 00:44:21,990
+بنعملية dolphinة ال grains اللي هتطلع هنا هتطلعيش
+
+547
+00:44:21,990 --> 00:44:28,150
+مطاولة استطالة فيها فالخواص في الاتجاه الطولي
+
+548
+00:44:28,150 --> 00:44:32,130
+مختلف عن الخواص في الاتجاه المستعرض فال processing
+
+549
+00:44:32,130 --> 00:44:32,590
+أثر
+
+550
+00:44:35,900 --> 00:44:39,340
+effect of thermomechanical treatment on properties
+
+551
+00:44:39,340 --> 00:44:45,780
+تأثير المعاملات الحرارية أو و الميكانيكية على
+
+552
+00:44:45,780 --> 00:44:52,180
+الخواص ممكن اعمل معارجة سطحية معارج سطحية ما تكونش
+
+553
+00:44:52,180 --> 00:44:57,200
+منتظمة عند كل لقطة طبعا درجة الانتظام و uniformity
+
+554
+00:44:57,200 --> 00:45:01,420
+ممكن ارفعها كل ما بده uniformity اكتر كل ما بده
+
+555
+00:45:01,420 --> 00:45:07,350
+عملية تحكم اكتر فتكلفة بالزيادةintensity and
+
+556
+00:45:07,350 --> 00:45:10,950
+distribution of loading هل التحميل على ال
+
+557
+00:45:10,950 --> 00:45:18,150
+mechanical part مركز ولا موزع؟
+
+558
+00:45:18,150 --> 00:45:23,030
+validity of mathematical models used to represent
+
+559
+00:45:23,030 --> 00:45:27,050
+reality الآن في عندي واقع الحال وفيه انا استخدمت
+
+560
+00:45:27,050 --> 00:45:32,970
+نماذج رياضية عشان اعمل analysisالان مدى مطابقة
+
+561
+00:45:32,970 --> 00:45:37,110
+النماذج الرياضية لو اقل حال بيأثر عليه ممكن يعمل
+
+562
+00:45:37,110 --> 00:45:40,930
+أخطاء intense
+
+563
+00:45:40,930 --> 00:45:49,210
+of stress concentration عندي shaft هذه حالة حالة
+
+564
+00:45:49,210 --> 00:45:49,630
+تانية
+
+565
+00:45:57,100 --> 00:46:09,020
+عملت fillet حالة تالتة عملت اشي .. اشي زي هيك
+
+566
+00:46:09,020 --> 00:46:14,340
+ال stress concentration هي ان بيختلف هذه عن هذه عن
+
+567
+00:46:14,340 --> 00:46:21,320
+هذه كلهم بيقدروا نفس الوظيفة fillet
+
+568
+00:46:21,320 --> 00:46:21,920
+افضل
+
+569
+00:46:25,080 --> 00:46:27,800
+أه طبعا لازم تعمل fillet بس انا بحكيلك انا هان
+
+570
+00:46:27,800 --> 00:46:30,820
+واحد عمل sharp edge عملتله high stress
+
+571
+00:46:30,820 --> 00:46:34,060
+concentration هواحد عمل fillet عمل stress
+
+572
+00:46:34,060 --> 00:46:37,500
+concentration مختلف حد عمل fillet مع groove عمل
+
+573
+00:46:37,500 --> 00:46:43,420
+stress concentration مختلف لأ
+
+574
+00:46:43,420 --> 00:46:50,020
+أقل .. أقل من هذه أقل من هذه اه الان طبعا هذه
+
+575
+00:46:50,020 --> 00:46:52,000
+مفيدة لو بدي أركب mechanical part هنا
+
+576
+00:47:04,550 --> 00:47:12,490
+عشان تركب .. تركز صح على الكتف اللي هنا influence
+
+577
+00:47:12,490 --> 00:47:15,610
+of time on strength and geometry تأثير العمل
+
+578
+00:47:15,610 --> 00:47:20,910
+الزمني يعني إذا عندك mechanical part تحت تأثير
+
+579
+00:47:20,910 --> 00:47:29,960
+loadبشكل مستديم ودرجة الحرارة مرتفعة هتسحف هتتغير
+
+580
+00:47:29,960 --> 00:47:34,480
+الخواص مع الزمن وممكن تصير برضه تصير لها عند ال
+
+581
+00:47:34,480 --> 00:47:37,700
+grain boundaries تصير نشفان embrittlement نتيجة
+
+582
+00:47:37,700 --> 00:47:41,760
+استخدام درجة الحرارة مرتفعة لفترة زمنية طويلة يعني
+
+583
+00:47:41,760 --> 00:47:46,780
+تجيب قطعة مطاط وارميها في الشمس بعد شهر او بعد
+
+584
+00:47:46,780 --> 00:47:51,920
+فترة تنشففالعمل ازاي برضه مهم في التأثير على
+
+585
+00:47:51,920 --> 00:47:55,640
+الخلاص effect of corrosion and wear تأثير الصدا
+
+586
+00:47:55,640 --> 00:47:57,520
+والتأكل
+
+587
+00:48:03,700 --> 00:48:07,520
+طبعا عشان اعمل uncertainty analysis مضطر استخدم
+
+588
+00:48:07,520 --> 00:48:10,960
+اللي هو الأدوات الإحصائية بالدعرة في ال
+
+589
+00:48:10,960 --> 00:48:13,080
+distribution اللي هي normal distribution, chi
+
+590
+00:48:13,080 --> 00:48:15,680
+distribution, student distribution و ال webel
+
+591
+00:48:15,680 --> 00:48:19,140
+distribution فيه طرق إحصائية لدراسة ال uncertainty
+
+592
+00:48:19,140 --> 00:48:26,200
+في الخواص أو ال dimensions مصطلح
+
+593
+00:48:26,200 --> 00:48:27,960
+تانه احنا عارف كتير اللي هو reliability
+
+594
+00:48:27,960 --> 00:48:36,400
+reliability هي قياس لاحتماليةنجاح mechanical part
+
+595
+00:48:36,400 --> 00:48:40,720
+يؤدي وظيفته يعني هي قياس لنجاح mechanical part
+
+596
+00:48:40,720 --> 00:48:47,160
+يؤدي وظيفته خلال فترة تلت اللي هو الخدمة بتاعته أو
+
+597
+00:48:47,160 --> 00:48:53,400
+قياس ل not failing during use قياس not failing not
+
+598
+00:48:53,400 --> 00:48:55,820
+failing يعني إيش؟ not failing success
+
+599
+00:49:01,010 --> 00:49:11,070
+Probability of failure هي عدد المرات من عدد كل
+
+600
+00:49:11,070 --> 00:49:12,270
+المحاولات
+
+601
+00:49:16,990 --> 00:49:19,930
+الـ failure هذه الـ product of failure النجاح
+
+602
+00:49:19,930 --> 00:49:24,090
+بالساوي يعني failure ما نجاح مجمومة شو يساوي؟ مية
+
+603
+00:49:24,090 --> 00:49:28,050
+بالمية واحد معناته ال reliability هتكون واحد minus
+
+604
+00:49:28,050 --> 00:49:35,090
+PF example اذا عندي الف قطعة ستة متصنع الف قطعة و
+
+605
+00:49:35,090 --> 00:49:41,510
+من كل الف ست قطع كانت defective failed معناته ال
+
+606
+00:49:41,510 --> 00:49:44,940
+product of failure هتكون ستة من الفيعني ال
+
+607
+00:49:44,940 --> 00:49:48,260
+reliability هتكون واحد ما قصتها لألف يعني point
+
+608
+00:49:48,260 --> 00:49:57,600
+nine nine four إذا
+
+609
+00:49:57,600 --> 00:50:02,240
+عندي ال serious system مكون من مجموعة من القطع ال
+
+610
+00:50:02,240 --> 00:50:05,380
+overall reliability هي عبارة عن حاصل ال
+
+611
+00:50:05,380 --> 00:50:10,670
+multiplication حاصل ضرب ال individualreliabilities
+
+612
+00:50:10,670 --> 00:50:13,430
+لل mechanical system يعني لو ماعندي mechanical
+
+613
+00:50:13,430 --> 00:50:19,370
+system عندي shaft عندي
+
+614
+00:50:19,370 --> 00:50:23,170
+هين bearing
+
+615
+00:50:23,170 --> 00:50:29,750
+وهين عندي bearing ال
+
+616
+00:50:29,750 --> 00:50:35,070
+bearing دي هين ال reliability بتاعتها 95% و ال
+
+617
+00:50:35,070 --> 00:50:39,770
+bearing على اليمين ال reliability بتاعتها 98%الـ
+
+618
+00:50:39,770 --> 00:50:43,350
+total level هتكون R1 في R2 يعني هتكون bond 95 في
+
+619
+00:50:43,350 --> 00:50:48,410
+bond 98 تطلع bond 93 لل system كله لل chef system
+
+620
+00:50:48,410 --> 00:50:54,790
+في
+
+621
+00:50:54,790 --> 00:50:58,250
+عدة dimensions and tolerances في ال nominal size
+
+622
+00:51:01,020 --> 00:51:03,960
+اللي هو ال size we use in speaking of an element
+
+623
+00:51:03,960 --> 00:51:08,540
+اذا عندى part ميكانيكى بيحكي هذا ال .. ال .. ال ..
+
+624
+00:51:08,540 --> 00:51:14,800
+ال part مثلا قطره عشرة ملي هذا ال nominal size لكن
+
+625
+00:51:14,800 --> 00:51:18,750
+ال size اللي حكيه لو قسته انا بال caliberبيكون فيه
+
+626
+00:51:18,750 --> 00:51:22,370
+شويه تسامح ممكن يكون عندى plus or minus point one
+
+627
+00:51:22,370 --> 00:51:26,550
+millimeter يعني ممكن يكون القطر يتلوح بين تسعة
+
+628
+00:51:26,550 --> 00:51:31,970
+point تسعة لعشرة point one millimeter ف ال nominal
+
+629
+00:51:31,970 --> 00:51:35,950
+size انا هو انا معرفه ال nominal هو عشرة مليار بس
+
+630
+00:51:35,950 --> 00:51:40,110
+الحقيقة بيكون اكتر او اقل within ال tolerance
+
+631
+00:51:40,110 --> 00:51:41,110
+المسموح فيه
+
+632
+00:51:46,850 --> 00:51:50,350
+إذا كانت نسبة عالية بحاول بزود ال factor of safety
+
+633
+00:51:50,350 --> 00:51:53,370
+للماكينات تانية و لا بقى لازم أجلّشها؟ بدك تشوف
+
+634
+00:51:53,370 --> 00:51:57,910
+أولشه ليش عندك failure عالي، ما هو برضه رفع ال
+
+635
+00:51:57,910 --> 00:52:00,350
+factor of safety، بضيف تكلفة، بضيف .. بضيف عليه
+
+636
+00:52:00,350 --> 00:52:03,730
+ماتير الكتير، بضيف عملية تصنيع إضافية، بدي أشوف
+
+637
+00:52:03,730 --> 00:52:07,860
+أولشه ليش بيصير عندي failureأيوة بدك تعمل analysis
+
+638
+00:52:07,860 --> 00:52:14,460
+يعني مثلا انا بعض ال kick سنة
+
+639
+00:52:14,460 --> 00:52:22,600
+.. سنة تسعين كان في .. انا مش شغلت شغلات كان في
+
+640
+00:52:22,600 --> 00:52:27,500
+أنا shaft في ال gearbox .. gearbox لشركة Chrysler
+
+641
+00:52:31,590 --> 00:52:38,010
+في أمريكا في تلات شركات رئيسية اللي هي إيش ال GM و
+
+642
+00:52:38,010 --> 00:52:43,610
+Ford هدول أكبر تلات شركات طبعا أكبرهم واحد اتنين
+
+643
+00:52:43,610 --> 00:52:48,150
+تلاتة فكان في قطعة في سيارات أحد سيارات الشركة
+
+644
+00:52:48,150 --> 00:52:53,450
+الكرسي اللي هو شافت عمود كان سيرله فيه تفاصيل كتير
+
+645
+00:52:53,450 --> 00:52:57,270
+طبعا في شات و فيه fillets مثلا فيه fillet عندهين
+
+646
+00:52:57,270 --> 00:52:58,150
+شي زي هيك مثلا
+
+647
+00:53:01,830 --> 00:53:08,230
+كان ده من السير كسر في المنطقة دي failure بنفعش
+
+648
+00:53:08,230 --> 00:53:11,510
+أروح زي ما حكى عبدالكريم أنه قبل أروح أكبر الشافة
+
+649
+00:53:11,510 --> 00:53:14,770
+و تكبر الشافة في .. في .. في truth و في bearing و
+
+650
+00:53:14,770 --> 00:53:17,550
+في .. في gearbox في .. في شغلات كتير هغير مش عيد
+
+651
+00:53:17,550 --> 00:53:22,970
+تكبرت الشافته بس بده أعرف ليش بنكسر فعملنا ..
+
+652
+00:53:22,970 --> 00:53:27,970
+فعملنا طبعا force analysis و stress analysis عملنا
+
+653
+00:53:27,970 --> 00:53:31,080
+finite element analysisشوفنا ال stress
+
+654
+00:53:31,080 --> 00:53:34,380
+distribution في المنطقة هذه وبعدين نلعب في .. نلعب
+
+655
+00:53:34,380 --> 00:53:38,300
+في ال fillet نغير في ال fillet لحد minimize اللي
+
+656
+00:53:38,300 --> 00:53:43,220
+هو ال stress concentration ويعني صارت تغيرات ..
+
+657
+00:53:43,220 --> 00:53:46,200
+عملنا تغيرات في ال geometry هنا فانت في الأول تدرس
+
+658
+00:53:46,200 --> 00:53:50,420
+تعت .. يعني انت لما تشخص حالة مريض او بتعطيش علاج
+
+659
+00:53:50,420 --> 00:53:56,320
+غير لما تشخص فانت لازم تشخص ليش صار الفالير بناء
+
+660
+00:53:56,320 --> 00:54:01,110
+على الفالير اذا لازم اكبر safety factor بكبرهبس
+
+661
+00:54:01,110 --> 00:54:07,210
+احتمال ملزمش احتمال material او whatever اي action
+
+662
+00:54:07,210 --> 00:54:10,790
+محتاجين تعمله لازم تعمله لازم تسويه بس اذا مش
+
+663
+00:54:10,790 --> 00:54:13,730
+محتاج اغير ال material المشكلة في ال geometry شوية
+
+664
+00:54:13,730 --> 00:54:19,490
+تعديل في ال geometry تنعمل ايوة بالظبط فبدك تعمل
+
+665
+00:54:19,490 --> 00:54:25,150
+انا لازم تدرس المشكلة
+
+666
+00:54:25,150 --> 00:54:28,410
+يعني دراسة اي مشكلة بيتمد على التلات
+
+667
+00:54:31,470 --> 00:54:37,190
+تلت عناصر، عنصر الخبرة اللي .. اللي هو experience،
+
+668
+00:54:37,190 --> 00:54:43,410
+عندك rational و عندك اللي هو measurements أو
+
+669
+00:54:43,410 --> 00:54:48,200
+analysisعنصر الخبرة بتكون مرت عليك حالة مشابهة
+
+670
+00:54:48,200 --> 00:54:51,940
+سابقا مرت عليك تجارب تانية فممكن تتوقع أيش السبب
+
+671
+00:54:51,940 --> 00:54:55,980
+عنصر rational بدك تستخدم ال .. ال physics law و ال
+
+672
+00:54:55,980 --> 00:54:59,740
+chemistry القوانين اللي هي الطبيعية عشان تفهم إيش
+
+673
+00:54:59,740 --> 00:55:04,040
+اللي بيصير عنصر اللي هو ال .. ال experimentation
+
+674
+00:55:04,040 --> 00:55:07,160
+بدك محتاج تعمل قياسات تشوف .. تقيس إجهادات تقيس
+
+675
+00:55:07,160 --> 00:55:11,360
+deflections تعمل شوية analysis عشان تفهم المشكلة
+
+676
+00:55:11,360 --> 00:55:21,060
+طيبمش مصطلح reliability و مش time dependent نعم قد
+
+677
+00:55:21,060 --> 00:55:24,920
+تكون time dependent طبعا يعني موضوع ال barrier و
+
+678
+00:55:24,920 --> 00:55:28,920
+ال reliability اللي بتبقى تحت فيه هذا المتعملية
+
+679
+00:55:28,920 --> 00:55:32,700
+بتصير قبل ال production ولا بعد ال production من
+
+680
+00:55:32,700 --> 00:55:38,040
+ال feedback لأ انا في اسمه design for reliability
+
+681
+00:55:38,970 --> 00:55:42,490
+يعني انا بكون محدد انا هذا بده يكون الترس reliable
+
+682
+00:55:42,490 --> 00:55:47,370
+98% انا بكون حار في حالي ال defect او نسبة ال
+
+683
+00:55:47,370 --> 00:55:51,190
+defect في ال parts بتاعتي بشكل مسبق اللي انا لما
+
+684
+00:55:51,190 --> 00:55:55,470
+تيجي تصنع قد يختلف عن الاشي المقصود فيه بدك تضطر
+
+685
+00:55:55,470 --> 00:55:58,610
+تعمل تعديلات في الجامعة يا دكتور ان في فترة زمنية
+
+686
+00:55:58,610 --> 00:56:03,480
+انه يجير مثلا بيشتغل لمدة 800 ألف ساعة؟ماشي بقى
+
+687
+00:56:03,480 --> 00:56:06,080
+انت في عملية ال design process ال design process
+
+688
+00:56:06,080 --> 00:56:08,680
+اللي عندك ده صمم gear reliable تمنت سنين و أثنية
+
+689
+00:56:08,680 --> 00:56:13,080
+يعيش مائة ألف ساعة هاي الحالة و انا دي حالة ان انا
+
+690
+00:56:13,080 --> 00:56:16,460
+هصمم ترس reliability تقريبا تمنت سنين و أثنية برضه
+
+691
+00:56:16,460 --> 00:56:21,580
+بس بتعيش مائة ساعة and I'll take care of life
+
+692
+00:56:21,580 --> 00:56:24,660
+while keeping يعني انا ممكن احافظ على ال building
+
+693
+00:56:24,660 --> 00:56:27,040
+لفترة طويلة او حافظ على الفترة قصيرة حسب ال
+
+694
+00:56:27,040 --> 00:56:30,840
+application طيب السؤال التاني
+
+695
+00:56:34,510 --> 00:56:37,110
+ال limits اللي هي ال stated maximum and minimum
+
+696
+00:56:37,110 --> 00:56:40,330
+dimensions اي dimension انا عندي ال shaft مسموح
+
+697
+00:56:40,330 --> 00:56:43,410
+تكون مثلا بين تسعة و تسعة و عشرة قطر للقطر بين
+
+698
+00:56:43,410 --> 00:56:45,590
+تسعة و تسعة و عشرة مثلا لعشرة point one هذه ال
+
+699
+00:56:45,590 --> 00:56:48,310
+maximum و ال minimum و ال minimum limits ال
+
+700
+00:56:48,310 --> 00:56:53,050
+tolerance هو الفرق بين ال maximum و ال minimum في
+
+701
+00:56:53,050 --> 00:56:55,330
+عندى ال tolerance ممكن يكون bilateral مثلا نحكي هي
+
+702
+00:56:55,330 --> 00:57:02,150
+عشرة عشرةplus or minus point واحد millimeter هذا
+
+703
+00:57:02,150 --> 00:57:06,050
+bilateral يعني ال nominal size عشرة ممكن تكون أعلى
+
+704
+00:57:06,050 --> 00:57:12,230
+point one أو تحته point one فان دي unilateral ممكن
+
+705
+00:57:12,230 --> 00:57:19,610
+نحكي عشرة plus point one minus zero هذا يعني
+
+706
+00:57:19,610 --> 00:57:20,450
+unilateral
+
+707
+00:57:23,440 --> 00:57:26,940
+ال clearance هو في اي .. في بعض الطبقات اذا عندي
+
+708
+00:57:26,940 --> 00:57:32,820
+some part move بالنسبة لل other part عشان يتحرك
+
+709
+00:57:32,820 --> 00:57:35,940
+بالنسبة لازم يكون في بينهم clearance في فراغ ال
+
+710
+00:57:35,940 --> 00:57:40,700
+clearance هو ايش الخلوص او الفراغ هو الفرق في ال
+
+711
+00:57:40,700 --> 00:57:45,020
+size between two mating cylindrical parts where
+
+712
+00:57:45,020 --> 00:57:47,520
+they have relative motion في بينهم حركة نسبية واحد
+
+713
+00:57:47,520 --> 00:57:49,360
+بتحرك بالنسبة للتاني
+
+714
+00:57:52,430 --> 00:58:00,430
+ال interference بيكون ال shaft أكبر من ال hole هذا
+
+715
+00:58:00,430 --> 00:58:06,510
+interference يعني أنا عندى لأثبت قطع مثلا ممكن
+
+716
+00:58:06,510 --> 00:58:09,790
+أثبت ترس هاي عمود
+
+717
+00:58:28,600 --> 00:58:32,580
+ودا احط thirds
+
+718
+00:58:32,580 --> 00:58:35,780
+اثبته
+
+719
+00:58:35,780 --> 00:58:41,520
+هنا ممكن
+
+720
+00:58:41,520 --> 00:58:50,780
+اثبته باستخدام ال interference fit يعني كون الفتحة
+
+721
+00:58:50,780 --> 00:58:59,230
+بتاعة الجير اصغر من قطر الشفتةلأن بدخله حشر مثلا
+
+722
+00:58:59,230 --> 00:59:04,450
+او بعمل تسخين مظبوط فبصير عندي interference يعني
+
+723
+00:59:04,450 --> 00:59:08,110
+ممكن ا press fit او shrink fit او التاني مواعد
+
+724
+00:59:08,110 --> 00:59:11,650
+press and shrink fit طبعا shrink fit حاليا معظم ال
+
+725
+00:59:11,650 --> 00:59:14,430
+gear boxes اللي مابتشوفوها كلها shrink fit لتروس
+
+726
+00:59:14,430 --> 00:59:18,710
+ال shrink fit طبعا بيعطيني high torque capacityانت
+
+727
+00:59:18,710 --> 00:59:22,150
+بس بدك interference تحكي مثلا point 01 او يعني
+
+728
+00:59:22,150 --> 00:59:25,950
+خفيف جدا عشان تعطي لان بيصير عندك هنا عندى normal
+
+729
+00:59:25,950 --> 00:59:29,870
+force موزعة و بيصير عندى friction اللى هو نحكي
+
+730
+00:59:29,870 --> 00:59:35,330
+ببساطة ميو في ان طبعا friction موزعة على كل المحيط
+
+731
+00:59:35,330 --> 00:59:42,530
+ال allowanceال minimum stated clearance او ال
+
+732
+00:59:42,530 --> 00:59:45,350
+maximum stated interference of mating parts ال
+
+733
+00:59:45,350 --> 00:59:54,190
+allowance اللي هو ال allow هو
+
+734
+00:59:54,190 --> 00:59:59,170
+ال minimum stated يعني مثلا عندي الان اذا عندي
+
+735
+00:59:59,170 --> 01:00:09,590
+hole وعندي shaft ال hole له minimum و maximumوالـ
+
+736
+01:00:09,590 --> 01:00:15,850
+shaft اللي هو minimum اللي هو maximum في
+
+737
+01:00:15,850 --> 01:00:21,150
+حالتين إذا عندي كان في عندي clearance و الحالة
+
+738
+01:00:21,150 --> 01:00:28,430
+التانية عندي إيش interference في
+
+739
+01:00:28,430 --> 01:00:35,810
+حالة ال clearance ال allowance بيكون هو ال minimum
+
+740
+01:00:35,810 --> 01:00:36,250
+hole
+
+741
+01:00:39,190 --> 01:00:43,930
+minus ال maximum shaft في
+
+742
+01:00:43,930 --> 01:00:50,990
+حالة interference ال allowance بيكون ال maximum
+
+743
+01:00:50,990 --> 01:01:01,690
+maximum hole ال maximum shaft minus
+
+744
+01:01:11,150 --> 01:01:15,990
+الـ minimum hole
+
+745
+01:01:15,990 --> 01:01:20,690
+نفس
+
+746
+01:01:20,690 --> 01:01:24,690
+الشي تقريبا يعني هنا في حالة ال minimum stated
+
+747
+01:01:24,690 --> 01:01:30,710
+clearance هيكون عندى minimum hole لان ال hole أكبر
+
+748
+01:01:30,710 --> 01:01:36,090
+نقص ال maximum shaft في حالة ال interference بيكون
+
+749
+01:01:36,090 --> 01:01:37,790
+ال maximum stated interference
+
+750
+01:01:41,490 --> 01:01:45,230
+minus ال minimum hole اذا حطيت ال maximum hole
+
+751
+01:01:45,230 --> 01:01:52,430
+بيكون ال interference ايش اقل الان
+
+752
+01:01:52,430 --> 01:01:56,090
+موضوع اخر ال calculation and significant figures
+
+753
+01:01:56,090 --> 01:02:00,110
+ال accuracy of any number depends on number of
+
+754
+01:02:00,110 --> 01:02:04,810
+significant figures describing the number اللي هي
+
+755
+01:02:04,810 --> 01:02:07,070
+عدد الأرقام اللي بستخدمها في الحسابات بتاعتى هي
+
+756
+01:02:07,070 --> 01:02:12,170
+significant figuresunless otherwise stated إذا لم
+
+757
+01:02:12,170 --> 01:02:15,750
+يُذكر no less than three significant figures
+
+758
+01:02:15,750 --> 01:02:18,370
+should be used in your calculation ما تستخدمش أقل
+
+759
+01:02:18,370 --> 01:02:26,310
+من تلات أرقام في كل حسابك إلا إذا ذكر غير ذلك مثلا
+
+760
+01:02:26,310 --> 01:02:32,410
+عندي 706 هذا three significant figures 3.14 three
+
+761
+01:02:32,410 --> 01:02:33,790
+significant figures
+
+762
+01:02:36,020 --> 01:02:39,400
+تنين واحد تسعة فى فرق بين ال significant figures و
+
+763
+01:02:39,400 --> 01:02:41,440
+ال distant places هى ال distant places اللى عندى
+
+764
+01:02:41,440 --> 01:02:45,420
+هنا account خمسة لكن ال significant figures
+
+765
+01:02:45,420 --> 01:02:51,520
+فارتنادش two one point nine عشان
+
+766
+01:02:51,520 --> 01:02:55,440
+هيك إذا عندى رقم كبير مثلا واحد سنتين الف ستمية
+
+767
+01:02:55,440 --> 01:02:59,920
+هذا ماتتبرش خمسة significant figures هذا هى واحد
+
+768
+01:02:59,920 --> 01:03:02,360
+سنتين point ستة فعشرة لاس تلاتة او تسعة واحد ستة
+
+769
+01:03:02,360 --> 01:03:03,540
+عشر فعشرة لاس اتنين
+
+770
+01:03:06,800 --> 01:03:10,000
+إذا بدى four four significant figures بكتب واحد
+
+771
+01:03:10,000 --> 01:03:15,700
+سنتة point ستة zero فعشرة أقصى تلاتة الان
+
+772
+01:03:15,700 --> 01:03:18,800
+ملاحظ never report a number of significant figures
+
+773
+01:03:18,800 --> 01:03:21,920
+of a calculation any greater than smallest number
+
+774
+01:03:21,920 --> 01:03:27,080
+of significant figures يعني عشان ضارب تلاتة point
+
+775
+01:03:27,080 --> 01:03:34,120
+اتنين في تلاتة point خمسة سبعة تمانية اضربوليها
+
+776
+01:03:34,120 --> 01:03:34,680
+بالله يعني
+
+777
+01:03:37,730 --> 01:03:44,570
+أي حد على الجوال بصراحة
+
+778
+01:03:44,570 --> 01:03:47,710
+اعطينا
+
+779
+01:03:47,710 --> 01:03:52,090
+بالضبط احداش point اربع اربع اربع اربع اربع تسعة
+
+780
+01:03:52,090 --> 01:04:03,710
+ستة تسعة ستة الصح تكتبها احداش بنفعش
+
+781
+01:04:04,870 --> 01:04:08,510
+انت بتحكي ان الدقة هنا لحد two دسم ال places كيف
+
+782
+01:04:08,510 --> 01:04:12,370
+هتعملها اتنين اربعة لستر سكت دسم ال places مش رايك
+
+783
+01:04:12,370 --> 01:04:18,570
+بصح هنحكي هنا تلاتة point اتنين زيرو زي هيك يعني
+
+784
+01:04:18,570 --> 01:04:23,710
+هذه قراءة ال caliber مثلا احداش point اربعة لو
+
+785
+01:04:23,710 --> 01:04:31,670
+حكيت احداش zero هصير احداش point اربعة خمسة واضح؟
+
+786
+01:04:37,550 --> 01:04:45,690
+اه طبعا مش هي يأثر على نتائج الحالي يعني هو بتأثر
+
+787
+01:04:45,690 --> 01:04:51,410
+طبعا انت .. انت .. انت بتحكيلي مثلا انا
+
+788
+01:04:51,410 --> 01:04:55,990
+ماخد قصة في
+
+789
+01:04:55,990 --> 01:05:02,630
+dimension معين dimension معين ان انا احكي هي هي
+
+790
+01:05:10,590 --> 01:05:16,210
+أو خليني أخد شكل أسهل بس لحظة أعطيك مثال بسيط هاي
+
+791
+01:05:16,210 --> 01:05:25,610
+قطعة و روحت قصة هاد ب caliber طلعت
+
+792
+01:05:25,610 --> 01:05:36,370
+تلاتة point نين سفر خمسة و قصة هاد طول caliber
+
+793
+01:05:36,370 --> 01:05:44,230
+مجاوش معاهالكاليبر الصغير قصته بمصطلح طلعت مثلا
+
+794
+01:05:44,230 --> 01:05:56,570
+تلاتين او نحكي متين بالبنيوتر متين
+
+795
+01:05:56,570 --> 01:06:02,370
+متين او عشرين عشرين
+
+796
+01:06:02,370 --> 01:06:08,310
+point one ايش ال dimension هذا X ال X ايش حتساوي
+
+797
+01:06:09,660 --> 01:06:15,460
+عشرين point one minus تلاتة point اتنين سفر خمسة
+
+798
+01:06:15,460 --> 01:06:20,660
+ايش بتطلع عندكوا ستاش
+
+799
+01:06:20,660 --> 01:06:28,700
+point سبعة تسعة خمسة
+
+800
+01:06:28,700 --> 01:06:35,000
+المفروض اكتبوا ستاش point تمانية ليش مين ال
+
+801
+01:06:35,000 --> 01:06:39,200
+controlling اكتر في الحالة هذه المصطر ال caliber
+
+802
+01:06:40,500 --> 01:06:45,700
+المسطرة controlling لأنها الدقة فيها اقل فبكتب رقم
+
+803
+01:06:45,700 --> 01:06:54,000
+ستاش point تمانية بنفعش اكتب ستاش point سبعة تسعة
+
+804
+01:06:54,000 --> 01:06:57,760
+خمسة يعني انا بتدعي ان دقة المسطرة هي نفس دقة ال
+
+805
+01:06:57,760 --> 01:07:04,220
+caliber طبعا
+
+806
+01:07:04,220 --> 01:07:11,220
+في في الكتاب مسائل مرتبطة مع بعضمثلا مثلًا تلاتة
+
+807
+01:07:11,220 --> 01:07:15,160
+واحد واربعة خمسين واربعة سبعتين واربعة أربع سنتين
+
+808
+01:07:15,160 --> 01:07:22,160
+هذه مثال ممتدة عندي مثلًا هدول .. هذا شفتر تلاتة
+
+809
+01:07:22,160 --> 01:07:24,620
+شفتر أربعة شفتر أربعة شفتر أربعة شفتر أربعة شفتر
+
+810
+01:07:24,620 --> 01:07:28,260
+أربعة شفتر أربعة شفتر أربعة شفتر أربعة شفتر أربعة
+
+811
+01:07:28,260 --> 01:07:32,520
+شفتر أربعة شفتر أربعة شفتر أربعة شفتر أربعة شفتر
+
+812
+01:07:32,520 --> 01:07:33,300
+أربعة شفتر أربعة شفتر أربعة شفتر أربعة شفتر أربعة
+
+813
+01:07:33,300 --> 01:07:36,240
+شفتر أربعة شفتر أربعة شفتر أربعة شفتر أربعة شفتر أ
+
+814
+01:07:40,260 --> 01:07:44,920
+الان ال .. ك case study أنا .. أنا هعرضها بس أنا
+
+815
+01:07:44,920 --> 01:07:47,660
+فاضل case study نحكي عليها ال case بتاعتنا المرة
+
+816
+01:07:47,660 --> 01:07:55,680
+الجاية هنحكي على اللي هو ال design requirements و
+
+817
+01:07:55,680 --> 01:07:59,480
+ال design specifications هيك نكون خلصنا chapter
+
+818
+01:07:59,480 --> 01:08:02,020
+one اعطيكوا العفو، في اي سؤال؟
+
+819
+01:08:06,720 --> 01:08:08,940
+يعني بالنسبة لما احكي مثلا تلاتة point اتنين ثلاثة
+
+820
+01:08:08,940 --> 01:08:13,300
+خمسة هتجه ل three significant event او ل four هذه
+
+821
+01:08:13,300 --> 01:08:18,020
+four هذي
+
+822
+01:08:18,020 --> 01:08:21,380
+ال decimal place بتاعتها تلاتة لإن ممكن اكتب هنا
+
+823
+01:08:21,380 --> 01:08:31,780
+هذه تلت تلاف و متين و خمسة في عشرة أسالب تلاتة هذا
+
+824
+01:08:31,780 --> 01:08:36,640
+البرتقال دي physics one لل significant figuresأخد
+
+825
+01:08:36,640 --> 01:08:40,260
+الاسم جديد؟ اه ف numerical analysis اللي هو
+
+826
+01:08:40,260 --> 01:08:43,800
+numerical methods and analysis اللي هو أهم الموضوع
+
+827
+01:08:43,800 --> 01:08:46,320
+الجزء التاني اللي هو numerical methods and error
+
+828
+01:08:46,320 --> 01:08:51,800
+analysis أهم العملية اللي أحسب ال .. ال route ل
+
+829
+01:08:51,800 --> 01:08:55,360
+equations أو أعمل integration numerically أو أعمل
+
+830
+01:08:55,360 --> 01:08:58,060
+differentiation numerically هذا معروف ال .. ال ..
+
+831
+01:08:58,060 --> 01:09:01,340
+ال .. بس كيف أعمل error analysis هذا المهم الموضوع
+
+832
+01:09:04,570 --> 01:09:06,130
+أحضر الجامعه نكمل .. أعطيكوا العفو
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/i3VwDY5UAc0.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/i3VwDY5UAc0.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e2370a6b848e76faaadf225cc4247e14ca06ec42
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/i3VwDY5UAc0.srt
@@ -0,0 +1,2762 @@
+1
+00:00:05,420 --> 00:00:08,360
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,360 --> 00:00:12,680
+وبركاته اليوم هنبدأ المحاضرة الثانية التي هتكون
+
+3
+00:00:12,680 --> 00:00:16,660
+مراجعة لعلم ال material science  ليس كل شيء طبعًا
+
+4
+00:00:16,660 --> 00:00:21,120
+الأشياء الأساسية التي هتنزلنا في مادة تصميم الآلات
+
+5
+00:00:21,120 --> 00:00:26,580
+في البداية احنا في ال material science عملنا ما
+
+6
+00:00:26,580 --> 00:00:31,640
+هو ما يسمى ال standard tensile test فحص الشد كان
+
+7
+00:00:31,640 --> 00:00:36,540
+الهدف أننا نتعرف على الخواص الميكانيكية للمواد
+
+8
+00:00:36,540 --> 00:00:43,250
+وكان تركيزنا على المعدن، كنا نحضر عينة معيارية لها
+
+9
+00:00:43,250 --> 00:00:49,750
+مقطعتها مدور لها gauge length و gauge diameter و
+
+10
+00:00:49,750 --> 00:00:54,570
+عند الأطراف بيصير أطرافها دي لمسك العينة يتم
+
+11
+00:00:54,570 --> 00:00:58,910
+العينة تحت تأثير load محوري و كنا نحسس بال
+
+12
+00:00:58,910 --> 00:01:01,990
+engineering stress sigma بيساوي P على A node و
+
+13
+00:01:01,990 --> 00:01:05,990
+engineering strain delta L على L node أو L minus L
+
+14
+00:01:05,990 --> 00:01:12,350
+node على L node بعدين عملنا plot لل stress-strain
+
+15
+00:01:12,350 --> 00:01:17,170
+curve في عندي على المحور الأفقي ال strain على المحور
+
+16
+00:01:17,170 --> 00:01:22,870
+الرأسي ال stress حصلنا على ما يسمى اللي هو stress
+
+17
+00:01:22,870 --> 00:01:27,350
+-strain curve في نقاط مهمة أنَّها كانت ال
+
+18
+00:01:27,350 --> 00:01:31,450
+proportional limit هي نهاية ال proportional limit 
+
+19
+00:01:31,450 --> 00:01:34,590
+الفترة التي بتكون علاقة بال stress و ال strain
+
+20
+00:01:34,590 --> 00:01:41,210
+خطية و ال elastic limit هي ال stress level below
+
+21
+00:01:41,210 --> 00:01:44,310
+which لن يكون لديها permanent deformation يعني إذا
+
+22
+00:01:44,310 --> 00:01:51,130
+نزلت ال load هترجع العينة للصفر عرفنا ال point two
+
+23
+00:01:51,130 --> 00:01:59,150
+percent yield strength اللي هو SY عند ال ultimate
+
+24
+00:01:59,150 --> 00:02:04,770
+tensile strength و عند ال fracture stress طبعًا
+
+25
+00:02:04,770 --> 00:02:09,170
+واضح أن هاد ال ductile material و هاد ال brittle
+
+26
+00:02:09,170 --> 00:02:12,010
+material ال ductile material بيصير فيها plastic
+
+27
+00:02:12,010 --> 00:02:16,170
+deformation كتير لحد الكثرة ال brittle material
+
+28
+00:02:16,170 --> 00:02:19,550
+كمية ال plastic deformation بيصير فيها قليلة جدا
+
+29
+00:02:19,550 --> 00:02:20,750
+تكثر بسرعة معه
+
+30
+00:02:26,810 --> 00:02:31,070
+طبعًا في المنطقة هذا بيسميه linear elastic material
+
+31
+00:02:31,070 --> 00:02:35,050
+في المنطقة الخطية التي علاقة كانت بال stress و ال
+
+32
+00:02:35,050 --> 00:02:37,590
+engineering stress و ال engineering strain سيجما
+
+33
+00:02:37,590 --> 00:02:43,710
+بيساوى E capital في أبسلون ال E capital هي ال
+
+34
+00:02:43,710 --> 00:02:47,690
+modulus of elasticity في كتب اسمها young's modulus
+
+35
+00:02:47,690 --> 00:02:53,650
+هي بتعبر عن زنبركية المادة how stiff is
+
+36
+00:02:53,650 --> 00:02:54,370
+the material
+
+37
+00:02:57,460 --> 00:03:02,640
+عادة ال E capital بتعتمدش على المعالجات الحرارية
+
+38
+00:03:02,640 --> 00:03:08,160
+أو المحتوى الكربوني أو المحتوى التسبيكي للحديد ال
+
+39
+00:03:08,160 --> 00:03:16,240
+E تقريبًا بتكون ثابتة لكل أو لمعظم سبائك الحديد
+
+40
+00:03:16,240 --> 00:03:21,020
+طبعًا
+
+41
+00:03:21,020 --> 00:03:25,290
+هذا ال engineering stress strain curve في تحت ال
+
+42
+00:03:25,290 --> 00:03:28,090
+true stress strain curve كنا نحسب ال true stress
+
+43
+00:03:28,090 --> 00:03:35,410
+sigma sigma true بيساوى القوة اللحظية على المقطع
+
+44
+00:03:35,410 --> 00:03:43,290
+اللحظي F على A I اللحظي و ال epsilon اللي هو تكامل
+
+45
+00:03:43,290 --> 00:03:51,110
+DL على L من L mod ل L اللي هو بيساوي L L على L mod
+
+46
+00:03:54,310 --> 00:03:57,450
+التحت هو لل true stress strain curve لل true stress
+
+47
+00:03:57,450 --> 00:04:00,650
+strain curve كان لزمنا في ال ..  ليس في ال design بل
+
+48
+00:04:00,650 --> 00:04:04,050
+لزمنا في ال manufacturing كان في علاقة بين لل true
+
+49
+00:04:04,050 --> 00:04:10,850
+stress و لل true strain من خلال علاقة K أبسلون
+
+50
+00:04:10,850 --> 00:04:20,590
+true to the power N for
+
+51
+00:04:20,590 --> 00:04:25,990
+ductile materials بيكون ال ultimate strength in
+
+52
+00:04:25,990 --> 00:04:30,830
+compression بيساوي ال ultimate strength in tension
+
+53
+00:04:30,830 --> 00:04:35,050
+لكن في حالة ال brittle materials مثل البطان ال
+
+54
+00:04:35,050 --> 00:04:38,070
+ultimate strength in compression بيكون أكبر بكثير
+
+55
+00:04:38,070 --> 00:04:44,590
+من ال ultimate strength in tension في
+
+56
+00:04:44,590 --> 00:04:48,490
+ال torsional strength القوة المعاكسة القوة التي التي
+
+57
+00:04:48,490 --> 00:04:54,570
+قوة معاكسة لها هذا الـ torsional strength يتم
+
+58
+00:04:54,570 --> 00:04:59,250
+حسابها أو إيجادها باستخدام عينات مقطعها مدورة
+
+59
+00:04:59,250 --> 00:05:02,790
+بعملها لحد ما يصير الـ plastic deformation لحد ما يصير
+
+60
+00:05:02,790 --> 00:05:06,730
+الـ plastic deformation ب .. هذه هي ال ultimate ال
+
+61
+00:05:06,730 --> 00:05:14,470
+.. torsional strength TAU maximum TAU
+
+62
+00:05:14,470 --> 00:05:17,910
+في ال mechanics ال material بشكل عام في حالة ال
+
+63
+00:05:17,910 --> 00:05:26,250
+torsion سواء TR على J طبعًا في علاقة بين ال tau و ال
+
+64
+00:05:26,250 --> 00:05:29,110
+angle و ال twist يعني أنا أسكها من طرف و أعمل
+
+65
+00:05:29,110 --> 00:05:34,510
+twisting بيصير في عنده rotation التي هي ال angle و
+
+66
+00:05:34,510 --> 00:05:34,830
+ال twist
+
+67
+00:05:37,670 --> 00:05:43,410
+الـ linear tau maximum بيساوى GR على L node في theta ال
+
+68
+00:05:43,410 --> 00:05:46,370
+G التي هي ال shear modulus أو ال modulus of
+
+69
+00:05:46,370 --> 00:05:50,230
+rigidity ال theta ال angle twist بوحدة ال radians
+
+70
+00:05:50,230 --> 00:05:57,650
+و ال L node اللي هو ال gauge length ال
+
+71
+00:05:57,650 --> 00:06:00,870
+gauge
+
+72
+00:06:00,870 --> 00:06:05,670
+length أنا 
+
+73
+00:06:05,670 --> 00:06:06,630
+لما أمسك العينة
+
+74
+00:06:12,700 --> 00:06:20,940
+بتكون من الطرف المسوكة و
+
+75
+00:06:20,940 --> 00:06:28,660
+أنا ببقى بقى عليها إيش؟ torque ليس كل الطول من
+
+76
+00:06:28,660 --> 00:06:31,100
+من منطقة ال application لو اتفرض ال application بتاع
+
+77
+00:06:31,100 --> 00:06:37,780
+التورك بدأ من هنا يعني هذه هي ال gauge length لو
+
+78
+00:06:37,780 --> 00:06:41,970
+كنت مسكت من هنا بتكون هذه هي ال gauge length هسمون
+
+79
+00:06:41,970 --> 00:06:45,750
+أنا ماسك ال
+
+80
+00:06:45,750 --> 00:06:52,450
+maximum
+
+81
+00:06:52,450 --> 00:06:58,330
+shear في حالة ال torsion بيكون على ال shear
+
+82
+00:06:58,330 --> 00:07:06,630
+distribution هذا
+
+83
+00:07:06,630 --> 00:07:10,710
+ال tau max هذا ال radius
+
+84
+00:07:13,330 --> 00:07:20,030
+تاو ماكس بيساوى ال torque في ال radius على ال
+
+85
+00:07:20,030 --> 00:07:23,750
+polar moment of inertia ال polar moment of inertia
+
+86
+00:07:23,750 --> 00:07:34,730
+بيساوى باي على اتنين و تلاتين باي دي تكيب أو
+
+87
+00:07:34,730 --> 00:07:40,770
+بيساوى نص ماهي دي بيساوياش ا على اتنين يعني هصير
+
+88
+00:07:40,770 --> 00:07:48,750
+ستاش وصير نص by R تربيع يعني لو عوضنا بيصير تو
+
+89
+00:07:48,750 --> 00:08:05,590
+ماكس ت ر على نص by R square ارس أربعة هتكون
+
+90
+00:08:05,590 --> 00:08:20,140
+بيساوى اتنين ت على باى أو تكيب فين
+
+91
+00:08:20,140 --> 00:08:23,340
+ال yield؟ ال yield is the torsion strength هي ال
+
+92
+00:08:23,340 --> 00:08:29,460
+maximum shear stress التي عندها بدخل .. بيصير عند
+
+93
+00:08:29,460 --> 00:08:34,720
+ال .. ال .. ال .. ال .. العلاقة ليست linear يعني لما
+
+94
+00:08:34,720 --> 00:08:39,860
+أنا ألف بيكون تقريبًا خط مستقيم بيصير curved هذه
+
+95
+00:08:39,860 --> 00:08:41,860
+باسمها ال yield strength أو لما أدخل ال plastic
+
+96
+00:08:41,860 --> 00:08:45,300
+deformation ال modulus of rupture هو ال maximum
+
+97
+00:08:45,300 --> 00:08:49,980
+point on torque twist diagram أنا برضه برسم torque
+
+98
+00:08:49,980 --> 00:08:59,740
+twist diagram برسم torque مع ال theta هذه
+
+99
+00:08:59,740 --> 00:09:01,740
+التي هي SSU
+
+100
+00:09:13,920 --> 00:09:18,580
+ال Resilience هي
+
+101
+00:09:18,580 --> 00:09:24,860
+قدرة المادة على امتصاص ال energy within the
+
+102
+00:09:24,860 --> 00:09:30,540
+elastic range يعني هاي ال stress-strain curve، هاي
+
+103
+00:09:30,540 --> 00:09:35,420
+strain، هاي stress وهذا ال curve منطقة ال elastic
+
+104
+00:09:35,420 --> 00:09:41,180
+region لو عملت unloading عند ال elastic limit برجع
+
+105
+00:09:41,180 --> 00:09:45,520
+للصفر مافيش عندها plastic deformation ال resilience
+
+106
+00:09:45,520 --> 00:09:50,900
+هو الطاقة الممتصة من العينة طاقة ممتصة من العينة
+
+107
+00:09:50,900 --> 00:09:54,980
+في فترة ال elastic region في ال elastic region هذا
+
+108
+00:09:54,980 --> 00:10:00,060
+يمثل ال resilience كل ما زاد ال resilience كل ما
+
+109
+00:10:00,060 --> 00:10:05,360
+كان عند المادة قدرة أنَّها تمشي في elastic region
+
+110
+00:10:05,360 --> 00:10:06,640
+أكبر مدى ممكن
+
+111
+00:10:09,830 --> 00:10:20,770
+يعني احنا فاكرين أن هي هتكون المساحة هذه و
+
+112
+00:10:20,770 --> 00:10:27,930
+قربنا المساحة المثلث ال modulus of resilience صار
+
+113
+00:10:27,930 --> 00:10:32,750
+نص مساحة القاعدة التي هي epsilon yield
+
+114
+00:10:37,130 --> 00:10:43,090
+في الـ sigma yield وحكينا تقريبًا ال sigma بيساوي E في
+
+115
+00:10:43,090 --> 00:10:51,830
+أبسلون yield ووصلنا للعلاقة هذه ال
+
+116
+00:10:51,830 --> 00:10:57,370
+modulus of resilience تقريبًا بيساوي أسوأ تربيع على 2E
+
+117
+00:10:57,370 --> 00:11:01,770
+الأسوأ هي ال yield strength و ال E ال modulus of
+
+118
+00:11:01,770 --> 00:11:02,270
+elasticity
+
+119
+00:11:08,010 --> 00:11:10,810
+for two materials with the same yield strength لما
+
+120
+00:11:10,810 --> 00:11:13,910
+دي two يعني لهم نفس ال yield strength the less
+
+121
+00:11:13,910 --> 00:11:17,430
+stiff material has a greater greater resilience
+
+122
+00:11:17,430 --> 00:11:26,810
+less stiff يعني هاي material وهاي
+
+123
+00:11:26,810 --> 00:11:31,770
+هاي
+
+124
+00:11:31,770 --> 00:11:38,220
+ال material one هاي ال material two من ال E أعلى؟
+
+125
+00:11:38,220 --> 00:11:45,780
+واحد ولا اثنين؟ واحد E واحد أعلى من E اثنين لأن ال
+
+126
+00:11:45,780 --> 00:11:51,660
+E بتمثل ال slope صح؟ واضح ال slope هنا أعلى من هنا
+
+127
+00:11:51,660 --> 00:11:59,600
+إذا كان لهم تقريبًا نفس ال yield strength بتكون
+
+128
+00:11:59,600 --> 00:12:05,720
+ال modulus of resilience اثنين أكبر من واحد صحيح
+
+129
+00:12:09,230 --> 00:12:13,370
+ال toughness هي كمية الطاقة التي تمتصها العينة
+
+130
+00:12:13,370 --> 00:12:19,530
+خلال الفحص لحد الكثرة ال toughness هي كمية الطاقة
+
+131
+00:12:19,530 --> 00:12:28,670
+التي تمتصها العينة خلال الفحص لحد الكثرة تقريبًا
+
+132
+00:12:28,670 --> 00:12:31,370
+نحكي هنا ال modulus of result أو ال modulus الذي
+
+133
+00:12:31,370 --> 00:12:36,940
+هو ال toughness بتساوي SY زي SUT على اثنين في
+
+134
+00:12:36,940 --> 00:12:40,600
+الابسلون F الابسلون F هو ال strain at fracture
+
+135
+00:12:40,600 --> 00:12:56,380
+الابسلون F هو ال strain at fracture الآن
+
+136
+00:12:56,380 --> 00:13:00,980
+سنتطلع على statistical significance of material
+
+137
+00:13:00,980 --> 00:13:06,420
+properties طبعًا strength values are obtained from
+
+138
+00:13:06,420 --> 00:13:10,000
+testing many nominally identical specimens  لكي
+
+139
+00:13:10,000 --> 00:13:13,700
+أحصى ال strength values لا يعمل لا يقومون بفحص شد واحد
+
+140
+00:13:13,700 --> 00:13:19,240
+مثلًا  يقومون ب 100 فحص يأخذون بيانات للعديد من الفحوصات 
+
+141
+00:13:19,240 --> 00:13:24,060
+بعدين بيعمل statistical analysis عشان يجيب اللي هو
+
+142
+00:13:24,060 --> 00:13:25,960
+الـ main strength
+
+143
+00:13:27,820 --> 00:13:33,540
+عشان تجيب الـ standard deviation و distribution للـ
+
+144
+00:13:33,540 --> 00:13:38,840
+strength وبالتالي
+
+145
+00:13:38,840 --> 00:13:45,160
+الـ strength لها distribution وبالتالي it has its
+
+146
+00:13:45,160 --> 00:13:50,680
+statistical nature تشوف 
+147
+00:13:50,680 --> 00:13:51,180
+مثال
+
+148
+00:14:00,170 --> 00:14:08,030
+في عندي حديد رقم عشرة عشرين steel رقم عشرة عشرين عشرة
+
+149
+00:14:08,030 --> 00:14:13,530
+هي نسبة الكربون هذا العشرة يعني plain carbon steel
+
+150
+00:14:13,530 --> 00:14:17,430
+plain يعني حديد سادة يعني ما فيش فيه عناصر أخرى
+
+151
+00:14:17,430 --> 00:14:20,550
+ما فيش فيه مثلاً مانجانيز ما فيش فيه فanadium ما فيش فيه
+
+152
+00:14:20,550 --> 00:14:24,970
+مغنيسيوم ما فيش فيه فسفور بس حديد و كربون كربون سادة
+
+153
+00:14:24,970 --> 00:14:30,230
+plain carbon steel نسبة الكربون فيه 0.2
+
+154
+00:14:30,230 --> 00:14:36,910
+في المئة يعني هذه مقسومة على مئة يعني هتكون 0.2
+
+155
+00:14:36,910 --> 00:14:43,190
+percent الـ carbon فيها إن عملت ألف عينة
+
+156
+00:14:43,190 --> 00:14:49,650
+تم فحص ألف عينة و لكل عينة إنعمل الـ stress strain
+
+157
+00:14:49,650 --> 00:14:57,300
+curve و من الـ stress strain curve طلعنا اللي هو الـ
+
+158
+00:14:57,300 --> 00:15:02,660
+tensile strength طلع
+
+159
+00:15:02,660 --> 00:15:07,440
+عندي عينتين أنا عند المجموع العينات عندي عينتين
+
+160
+00:15:07,440 --> 00:15:11,540
+كانت الـ strength اللي هي ستة و خمسين و نص كيلو
+
+161
+00:15:11,540 --> 00:15:15,840
+pound per square inch تلات عشرة عينة سبعة و خمسين و
+
+162
+00:15:15,840 --> 00:15:19,960
+نص تلاتة و عينة ثمانية و خمسين و نص واحدة و تلاتين
+
+163
+00:15:19,960 --> 00:15:25,850
+عينة تسعة و خمسين و نصمية واحد و خمسين عينة تلات
+
+164
+00:15:25,850 --> 00:15:29,590
+ستين و نص تسعة و أربع عينة سبعة و ستين و نص أربع
+
+165
+00:15:29,590 --> 00:15:33,330
+عينات سبعين و نص عينتين و واحد سبعين point five
+
+166
+00:15:33,330 --> 00:15:38,810
+هذه البيانات اللي طلعت معايا في التجربة how to
+
+167
+00:15:38,810 --> 00:15:43,010
+characterize this material خليني أشوف الـ example
+
+168
+00:15:43,010 --> 00:15:51,010
+أنا عامله على الـ Excel العمود الأول بيبين لي قيمة
+
+169
+00:15:51,010 --> 00:15:55,880
+strength احنا كان عندنا الفحصو العمود الثاني مثل
+
+170
+00:15:55,880 --> 00:16:01,980
+تكرار للنتيجة الـ frequency يعني عندي عينتين جبولي
+
+171
+00:16:01,980 --> 00:16:05,300
+الـ strength ستة و خمسين و نص عندي تلات عشرة عينة
+
+172
+00:16:05,300 --> 00:16:09,930
+جبولي الـ strength سبعة و خمسين و نصمثلاً مية و تسعة
+
+173
+00:16:09,930 --> 00:16:14,290
+عينة جبولي strength واحد ستين ونص مية و تلاتين
+
+174
+00:16:14,290 --> 00:16:18,130
+عينة جبولي خمس ستين ونص تسعة و أربعين عينة جبولي
+
+175
+00:16:18,130 --> 00:16:22,390
+سبعة ستين ونص أربع عينة جبولي سبعين ونص عينتين
+
+176
+00:16:22,390 --> 00:16:26,130
+جبولي واحد سبعين ونص المجموع ألف قياس كلها ألف
+
+177
+00:16:26,130 --> 00:16:31,730
+لما نجمع الأرقام هذه تعطينا ألف عينة عشان ن
+
+178
+00:16:31,730 --> 00:16:38,050
+characterize لازم أحسب أول شيء ايش الـ mean valueالـ
+
+179
+00:16:38,050 --> 00:16:45,550
+mean value ايش هتساوي الآن بنعرفش نحكي الـ mean
+
+180
+00:16:45,550 --> 00:16:50,890
+value الـ average أجمعه و أقسم عليه على العدد لا كل
+
+181
+00:16:50,890 --> 00:16:54,080
+واحدة بدي أضربها في الـ weight تاعتها يعني عندي هنااللي
+
+182
+00:16:54,080 --> 00:16:57,640
+هو الـ frequency في الـ strength يعني أندي هنا اتنين
+
+183
+00:16:57,640 --> 00:17:01,680
+في ستة و خمسين ونص مية و تلات عشرة طبعاً عشرة سبعة و
+
+184
+00:17:01,680 --> 00:17:04,860
+خمسين و نص مية ألف و خمس وتلاتين بعدين بجمع الـ
+
+185
+00:17:04,860 --> 00:17:09,680
+weights كلها بجمع الـ weights كلها الـ X average زي
+
+186
+00:17:09,680 --> 00:17:16,600
+ما انتش فيه بتساوي واحد على N الـ summation للـ FI
+
+187
+00:17:16,600 --> 00:17:24,300
+XI الـ FI اللي هو تكرارللقراءة اللي قيمتها ايش xi
+
+188
+00:17:24,300 --> 00:17:34,840
+يعني هيكون عندي هتكون f1 في x1 زائد f2 في x2 زائد
+
+189
+00:17:34,840 --> 00:17:41,660
+f3 x3 و هكذا اللي أنا عندي أكلهم هتكون ألف يعني يعني
+
+190
+00:17:41,660 --> 00:17:47,600
+الرقم هذا الرقم هذا بأقسم على ايش هذا الرقم بيساوي
+
+191
+00:17:47,600 --> 00:17:50,280
+الـ summation للـ fi xi يعني هتكون عندي
+
+192
+00:17:56,660 --> 00:18:00,900
+الـ summation للـ FI
+
+193
+00:18:00,900 --> 00:18:06,320
+XI من الـ excel sheet طالع لي تلات ستين ألف و ستمية
+
+194
+00:18:06,320 --> 00:18:11,200
+و خمسة و عشرين تلات ستين ألف و ستمية و خمسة و
+
+195
+00:18:11,200 --> 00:18:19,470
+عشرين معناته الـ X mean هتكون واحد على N الـ summation للـ
+
+196
+00:18:19,470 --> 00:18:30,910
+FI XI I من واحد ل ألف
+
+197
+00:18:30,910 --> 00:18:38,770
+مش واحد ل ألف ده خليها N
+
+198
+00:18:38,770 --> 00:18:43,210
+small الـ summation كان لدي تلات ستين ألف و ستمية و خمسة
+
+199
+00:18:43,210 --> 00:18:48,010
+و عشرين الآن capital الـ N يعني بيطلع الـ average عندي
+
+200
+00:18:48,010 --> 00:18:53,370
+تلات ستين point ستة اتنين خمسة kilo pound per square
+
+201
+00:18:53,370 --> 00:18:59,450
+inch طيب
+
+202
+00:18:59,450 --> 00:19:10,870
+البيانات هذه تمثل sample ولا population؟ ايش عن الـ
+
+203
+00:19:10,870 --> 00:19:15,880
+population؟ و ايش عن الـ sample؟السبب اللي عينة
+
+204
+00:19:15,880 --> 00:19:22,640
+واحدة إنه يعني مثلاً لو أنا درست مرضى السكر كل
+
+205
+00:19:22,640 --> 00:19:27,540
+المصابين بالسكر في قطاع غزة أخذت فحص السكر لكل
+
+206
+00:19:27,540 --> 00:19:32,420
+مرضى السكر في قطاع غزة population طب أنا هالمنطقة
+
+207
+00:19:32,420 --> 00:19:38,590
+أو عملي إنه أفحص كل قطاع غزة بأخد sample يعني سنة
+
+208
+00:19:38,590 --> 00:19:42,590
+كده أنا فيها عندي سلة بيكون فيها كل شيء بأكبش منها
+
+209
+00:19:42,590 --> 00:19:47,050
+الـ capture هذه هي ايش الـ sample العينات نقطة واحدة
+
+210
+00:19:47,050 --> 00:19:52,910
+بس الـ sample بتكون مجموعة عينات فالـ standard
+
+211
+00:19:52,910 --> 00:19:58,430
+deviation في حالة إذا الأرقام بتاعتها based on
+
+212
+00:19:58,430 --> 00:20:04,800
+sample تُعطى بالعلاقة هذه اللي هي الـ standard
+
+213
+00:20:04,800 --> 00:20:08,240
+deviation أو جذر التربيع ل summation الـ FI XI تربيع
+
+214
+00:20:08,240 --> 00:20:12,500
+ناقص N capital في X mean تربيع على N ناقص واحد
+
+215
+00:20:12,500 --> 00:20:16,340
+وعندما أنا أتو في الجدول هتبقلبني أحسب الـ XI
+
+216
+00:20:16,340 --> 00:20:21,460
+تربيع FI يعني حضرتك بحكي ستة و خمسين و نص تربيع في
+
+217
+00:20:21,460 --> 00:20:27,960
+اتنين و سبعة و خمسين و نص تربيع في تمان عشرة و
+
+218
+00:20:27,960 --> 00:20:32,000
+ثمانية و خمسين و نص تربيع في تلاتة و عشرين و تسعة
+
+219
+00:20:32,000 --> 00:20:34,720
+خمسين و نص تربيع في واحد و تلاتين بحصل على العمود
+
+220
+00:20:34,720 --> 00:20:38,860
+هذا بعدين بيكون عندي ايش الـ summation معناه إن
+
+221
+00:20:38,860 --> 00:20:45,780
+عندي الـ standard deviation SX بيساوي
+
+222
+00:20:45,780 --> 00:20:55,940
+اللي هي جذر التربيع ل summation للـ FI XI تربيع الـ
+
+223
+00:20:55,940 --> 00:21:03,580
+I من واحد ل Kأو N small ناقص N capital X mean
+
+224
+00:21:03,580 --> 00:21:12,860
+تربيع على N ناقص واحد الـ summation للـ FI XI
+
+225
+00:21:12,860 --> 00:21:15,680
+تربيع اللي هي هذه الـ summation اللي هي أربعماية و
+
+226
+00:21:15,680 --> 00:21:23,340
+خمس ألف أربعماية و خمس ألف هذة و جذر تربيع أربعماية
+
+227
+00:21:23,340 --> 00:21:33,660
+أو خمس ألف أو أربع مليون أربع خمسين ثمانية
+
+228
+00:21:33,660 --> 00:21:37,460
+ستة أربعة ناقص
+
+229
+00:21:37,460 --> 00:21:44,520
+N اللي هي ألف في الـ X اللي هي مين اللي هي تلات
+
+230
+00:21:44,520 --> 00:21:48,540
+ستين تلات
+
+231
+00:21:48,540 --> 00:21:52,730
+ستين ستمية و خمسة و عشرين ممكن أعتبر القانون أغيره
+
+232
+00:21:52,730 --> 00:22:01,310
+أعتبره بيساوي جذر التربيع للـ summation fi xi تربيع
+
+233
+00:22:01,310 --> 00:22:11,630
+I equal واحد ل K ناقص الـ summation للـ fi xi على N
+
+234
+00:22:11,630 --> 00:22:13,270
+ناقص واحد
+
+235
+00:22:16,400 --> 00:22:21,100
+لنفرض بأن الـ X average اللي هي تلات ستين و
+
+236
+00:22:21,100 --> 00:22:29,420
+خمسة في ألف بتعطيني ايش؟ الرقم هذه صح؟ يعني هيكون
+
+237
+00:22:29,420 --> 00:22:34,080
+جذر التربيع للأربع
+
+238
+00:22:34,080 --> 00:22:39,220
+مليون خمسة أربع ثمانية ستة أربعة معينة تلات ستين
+
+239
+00:22:39,220 --> 00:22:42,460
+ستماية خمسة و عشرين على ألف ناقصها على تسعماية
+
+240
+00:22:42,460 --> 00:22:46,260
+و تسعة و تسعين بيطلع الـ standard deviation دي اتنين
+
+241
+00:22:46,260 --> 00:22:54,920
+point خمسة تسعة أربعة kilo pound per square inch
+
+242
+00:22:54,920 --> 00:23:05,480
+نعم
+
+243
+00:23:05,480 --> 00:23:10,720
+الـ mean value main side string square
+
+244
+00:23:16,320 --> 00:23:22,360
+هذا كل قيمة اللي هو الـ frequency واحد تكرار رقم
+
+245
+00:23:22,360 --> 00:23:26,580
+واحد في القيمة واحد تربيع زائد الـ frequency اتنين
+
+246
+00:23:26,580 --> 00:23:30,660
+في القيمة اتنين تربيع
+
+247
+00:23:30,660 --> 00:23:36,800
+آه صحيح معناه تهيئة صحيح كلامك هذا صحيح ناقص ألف
+
+248
+00:23:38,700 --> 00:23:43,980
+أنا آسف في تلات ستين point اتنين خمسة ستة اتنين
+
+249
+00:23:43,980 --> 00:23:52,880
+خمسة تربيع صحيح في خطأ كان لأن
+
+250
+00:23:52,880 --> 00:23:56,260
+الصورة اللي هي دي X تربيع لكن لو N في X كان كلام
+
+251
+00:23:56,260 --> 00:24:00,300
+اللي حكيته صح فهي كان صح فبيطلع الـ standard
+
+252
+00:24:00,300 --> 00:24:04,440
+deviation قيمته اتنين point خمسة تسعة أربعة الآن
+
+253
+00:24:04,440 --> 00:24:05,560
+لما نعيش نعمل الـ plot
+
+254
+00:24:08,280 --> 00:24:12,760
+لما نيجي نعمل plot ممكن
+
+255
+00:24:12,760 --> 00:24:19,940
+نعمل plot على مستويين ممكن
+
+256
+00:24:19,940 --> 00:24:26,200
+نعمل histogram histogram
+
+257
+00:24:26,200 --> 00:24:36,700
+أنا حكيت عندي أنا التوزيع كانت حطينا الـ frequency حطينا
+
+258
+00:24:36,700 --> 00:24:44,120
+الـ frequency وحطينا القيم عند
+
+259
+00:24:44,120 --> 00:24:49,740
+هنا احنا
+
+260
+00:24:49,740 --> 00:24:57,860
+بدنا ستة خمسين و نص ستة خمسين و نص سبعة
+
+261
+00:24:57,860 --> 00:25:02,280
+خمسين و نص ثمانية خمسين و نص كنا نزود واحد تسعة
+
+262
+00:25:02,280 --> 00:25:05,680
+خمسين و نص ستة و نص واحد ستة و نص اتنين و ستة و نص
+
+263
+00:25:05,680 --> 00:25:08,920
+تلات ستة و نص أربع ستة و نص خمسين و نص اللي كل
+
+264
+00:25:08,920 --> 00:25:11,400
+واحدة عارف أنا اتكررت ماذا ستة و خمسين و نص كانت
+
+265
+00:25:11,400 --> 00:25:18,380
+تكرار عندي اتنين اتنين من كم من ألف معناته ماخدة
+
+266
+00:25:18,380 --> 00:25:24,400
+0.02 اللي هي ماخدة 0.02 من ايش
+
+267
+00:25:24,400 --> 00:25:29,300
+0.002 من الألف القراءة الثانية كانت إذا
+
+268
+00:25:29,300 --> 00:25:33,050
+تفكرين ماخدة أظن تمان عشرة تلات عشرة تلات عشرة على ألف
+
+269
+00:25:33,050 --> 00:25:44,110
+القراءة الثالثة نرجع للـ Excel القراءة
+
+270
+00:25:44,110 --> 00:25:47,590
+العلماء ده اللي هي اتنين يعني الـ observed
+
+271
+00:25:47,590 --> 00:25:51,550
+probability density function اللي هي اتنين على ألف
+
+272
+00:25:51,550 --> 00:25:57,530
+هاي عندك اتنين على ألف هذه تلات عشرة على ألف هذه
+
+273
+00:25:57,530 --> 00:26:02,370
+تلاتة و عشرين على ألف واحد و تلاتين على ألف تلاتة على
+
+274
+00:26:02,370 --> 00:26:07,110
+ألف و هكذا اللي
+
+275
+00:26:07,110 --> 00:26:17,970
+بسوي بحكي
+
+276
+00:26:17,970 --> 00:26:23,350
+الله هاي الستة خمسين و نص هاي السبعة خمسين و نص
+
+277
+00:26:26,160 --> 00:26:34,980
+هي ثمانية و خمسين و نص و هكذا عدد
+
+278
+00:26:34,980 --> 00:26:39,340
+القراءات اللي ماخذين ستة و خمسين و نص اتنين يعني
+
+279
+00:26:39,340 --> 00:26:42,200
+0.02 لما أجمع هدول ايه كم بيطلع مجموعهم
+
+280
+00:26:42,200 --> 00:26:52,500
+واحد فعندي هتكون هاي هذه ماخدة اتنين الثانية ماخدة 
+
+281
+00:26:52,500 --> 00:26:54,720
+طبنتاش
+
+282
+00:27:02,380 --> 00:27:11,640
+فبيطلع عندي ما يسمى histogram بيطلع
+
+283
+00:27:11,640 --> 00:27:17,560
+ما يسمى عندي ايش الـ histogram 
+
+284
+00:27:17,560 --> 00:27:22,140
+الـ histogram بيبين لي التوزيع القراءات كيف هي موزعة
+
+285
+00:27:22,140 --> 00:27:30,600
+القراءات أو كثافة التوزيع واضح لو نطلع هنا عندي
+
+286
+00:27:30,600 --> 00:27:40,360
+بيزيد point 02 أكثر ايش عندي 151 هنا اللي هي عند
+
+287
+00:27:40,360 --> 00:27:48,560
+63.5 كانت ايش الـ maximum أكبر قيمة هذا بيسمى الـ
+
+288
+00:27:48,560 --> 00:27:51,900
+histogram الـ histogram لو عملت plot على القيم
+
+289
+00:27:51,900 --> 00:27:56,500
+بيطلع
+
+290
+00:27:56,500 --> 00:27:57,800
+معظم عندي اللي هي normal
+
+291
+00:28:01,520 --> 00:28:07,720
+النورمال ديستربيوشن والجاوس ديستربيوشن النورمال
+
+292
+00:28:07,720 --> 00:28:17,720
+ديستربيوشن هو عبارة عن علاقة اللي هي دي F of X اللي 
+
+293
+00:28:17,720 --> 00:28:22,940
+هو الـ probability density function واحد على سيجما X
+
+294
+00:28:22,940 --> 00:28:32,390
+جذر التربيع يعني اثنين باي الـ exponential لـ minus
+
+295
+00:28:32,390 --> 00:28:47,550
+نصف في X ناقص ميو على سيجما X نعم
+
+296
+00:28:47,550 --> 00:28:53,450
+هنحط ميو X يعني كثير ميو X يعني و Y وين ميو X لأ
+
+297
+00:28:53,450 --> 00:28:58,480
+هو X يعني القراءة ميو X ميو X هذه ايش هي الـ main
+
+298
+00:28:58,480 --> 00:29:07,540
+value ميو X هي الـ X mean الـ ميو value السيجما X 
+
+299
+00:29:07,540 --> 00:29:11,760
+هي الـ standard deviation لأن بعوض عن سيجما X أنا
+
+300
+00:29:11,760 --> 00:29:15,920
+حسبت الـ standard deviation already 2.594 والميو
+
+301
+00:29:15,920 --> 00:29:22,840
+حسبتها اللي هي 63.625 63.625 بعوضها هنا هنا
+
+302
+00:29:26,780 --> 00:29:33,240
+صارت الـ density function is a function only of X 
+
+303
+00:29:33,240 --> 00:29:41,280
+لو أحط X مثلا ستين هيعطيني قراءة أحط مثلا سبعين
+
+304
+00:29:41,280 --> 00:29:44,940
+هيعطيني قراءة فبحصل على الـ curve هذا اللي هو
+
+305
+00:29:44,940 --> 00:29:51,360
+probability density function الآن
+
+306
+00:30:05,390 --> 00:30:10,530
+طبعًا أنتم أنا بفترض أنكم هذا الشيء بتعرفوه أنا 
+
+307
+00:30:10,530 --> 00:30:13,030
+ماعطيش أكثر كلام للموضوع هذا في الـ .. في الـ
+
+308
+00:30:13,030 --> 00:30:20,090
+measurement فهذا f of x اللي طلع معايا هذه X main
+
+309
+00:30:20,090 --> 00:30:25,630
+هذا X mean طبعًا
+
+310
+00:30:31,970 --> 00:30:36,270
+ممكن أبعّد عشان غطى تقريبًا معظم الـ data هذه تكون
+
+311
+00:30:36,270 --> 00:30:51,290
+تقريبًا ثلاثة سيجما وهنا تكون ثلاثة سيجما فالـ 
+
+312
+00:30:51,290 --> 00:30:54,990
+probability density function للـ data بتاعتنا طلعت
+
+313
+00:30:54,990 --> 00:30:58,130
+بالشكل هذا f of x هو واحد على point اتنين خمس أربع
+
+314
+00:30:58,130 --> 00:31:02,930
+هذا الـ standard deviation وهذا ايش الـ X mean الـ 
+
+315
+00:31:02,930 --> 00:31:08,130
+main value بأعبر
+
+316
+00:31:08,130 --> 00:31:15,070
+عنها الـ SUT الـ
+
+317
+00:31:15,070 --> 00:31:22,070
+SUT N معناها is normally distributed function الـ 
+
+318
+00:31:22,070 --> 00:31:26,840
+mean بتاعتها تلات ستين point ست اتنين والـ standard
+
+319
+00:31:26,840 --> 00:31:30,220
+deviation اتنين point خمسة أربعة لحظة استخدمت كم
+
+320
+00:31:30,220 --> 00:31:33,460
+significant figures أربعة لحظة يعني أربعة بين
+
+321
+00:31:33,460 --> 00:31:41,600
+أربعة ما نفعش أحط الرقم الخامس فلما نكتب sut n بين
+
+322
+00:31:41,600 --> 00:31:44,500
+قوسين تلات ستين point ست اتنين واتنين point خمسة
+
+323
+00:31:44,500 --> 00:31:49,020
+أربعة معناته الـ dissolution normal هذا الـ mean
+
+324
+00:31:49,020 --> 00:31:51,120
+value هذا الـ standard deviation
+
+325
+00:31:56,810 --> 00:32:00,890
+الجداول فيها الخصائص تعطيني مش كل التفاصيل هذه 
+
+326
+00:32:00,890 --> 00:32:06,750
+تعطيني single value تعطيني single value للـ
+
+327
+00:32:06,750 --> 00:32:12,670
+strength الجداول common to use ninety nine percent
+
+328
+00:32:12,670 --> 00:32:17,210
+minimum strength يعني بحكيلك هذا ninety nine
+
+329
+00:32:17,210 --> 00:32:21,710
+percent minimum strength indicating أن تسعة وتسعين في
+
+330
+00:32:21,710 --> 00:32:26,620
+المائة من العينة exceed this value يعني بنحكيلك الـ
+
+331
+00:32:26,620 --> 00:32:29,920
+strength it ninety nine .. ninety nine percent من
+
+332
+00:32:29,920 --> 00:32:32,580
+الـ strength اللي سواء مية kilo pound per square
+
+333
+00:32:32,580 --> 00:32:37,420
+inch معناته تسعة وتسعين في المائة من العينات تتخطى القيمة
+
+334
+00:32:37,420 --> 00:32:41,000
+هذه يعني هذه هي القيمة الدنيا
+
+335
+00:33:02,220 --> 00:33:06,700
+الـ cold working هي عبارة عن process بعمل plastic 
+
+336
+00:33:06,700 --> 00:33:13,300
+deformation على الـ material بهدف رفع الـ strength
+
+337
+00:33:13,300 --> 00:33:17,580
+بتاعتها by strain hardening effect إذا فاهمين الـ
+
+338
+00:33:17,580 --> 00:33:23,180
+strain hardening effect بيزيد عدد الـ dislocations
+
+339
+00:33:23,180 --> 00:33:30,320
+في المادة وبتكون مخربشة مع بعض فبيصير المقاومة
+
+340
+00:33:31,840 --> 00:33:35,500
+لحركة انزلاق المستويات الذرية أو لحركة الـ
+
+341
+00:33:35,500 --> 00:33:40,960
+dislocations بيصير أصعب فالـ strength بتزيد فـ
+
+342
+00:33:40,960 --> 00:33:43,560
+it is a process of a strain hardening وجاء من
+
+343
+00:33:43,560 --> 00:33:44,820
+علاقة هذا الـ sigma true
+
+344
+00:34:00,670 --> 00:34:11,690
+لو أخذت log الـ sigma true هتكون سواء log الكمية زاد
+
+345
+00:34:11,690 --> 00:34:18,930
+عن log absolute true يعني لو رسمت على log log 
+
+346
+00:34:18,930 --> 00:34:19,490
+scale
+
+347
+00:34:23,660 --> 00:34:31,220
+log of epsilon true مع log of sigma true هتطلع
+
+348
+00:34:31,220 --> 00:34:41,380
+العلاقة شيء زي هيك هذا الأسلوب لو
+
+349
+00:34:41,380 --> 00:34:46,380
+عندي مادة بالشكل هذا ومادة بالشكل هذا هاي N واحد
+
+350
+00:34:46,380 --> 00:34:48,840
+و N اثنين
+
+351
+00:34:54,660 --> 00:34:57,740
+مين أكثر يتمدد؟ واحد ولا اثنين عندها قابلية to be
+
+352
+00:34:57,740 --> 00:35:00,720
+strain hardened أو to be cold worked؟ مين أكثر؟ واحد
+
+353
+00:35:00,720 --> 00:35:05,680
+ولا اثنين؟
+
+354
+00:35:05,680 --> 00:35:12,600
+ليش بدّنا؟ على
+
+355
+00:35:12,600 --> 00:35:17,460
+فقط نفس الـ K الـ
+
+356
+00:35:17,460 --> 00:35:23,180
+slope الـ N الآن هو the measure of the capacity of
+
+357
+00:35:23,180 --> 00:35:25,660
+the ability of a material to strain harden كل ما
+
+358
+00:35:25,660 --> 00:35:29,840
+يزيد بيصير الكمية أنها تتـ strain harden أسهل
+
+359
+00:35:29,840 --> 00:35:35,400
+يعني مادة قاسية كثير بتكون قيمتها منخفضة وبالتالي 
+
+360
+00:35:35,400 --> 00:35:39,480
+إمكانية أن أقسيها أكثر بيصير أصعب مادة قاسية كثير
+
+361
+00:35:39,480 --> 00:35:42,840
+في الأول بتكون الـ capacity to be strain hardened
+
+362
+00:35:42,840 --> 00:35:47,650
+أعلى بعد شوية لو كملت بيصير .. بيضلها .. بيضلها
+
+363
+00:35:47,650 --> 00:35:51,390
+تقل عندها الـ .. الـ .. بتضلها الكويتسترات بتقل بعد
+
+364
+00:35:51,390 --> 00:35:57,990
+عمل أول cold working أو أول strain hardening عند
+
+365
+00:35:57,990 --> 00:36:05,450
+الـ stress strain curve for some material عملت 
+
+366
+00:36:05,450 --> 00:36:10,130
+loading هاي الـ strain هاي الـ stress عملت loading 
+
+367
+00:36:10,130 --> 00:36:15,090
+دخلت الـ plastic region بعدين بديت أعمل unloading
+
+368
+00:36:15,090 --> 00:36:19,890
+هرجع لأن طالما دخلت لـ plastic region هكون دي الـ
+
+369
+00:36:19,890 --> 00:36:27,610
+strain جزئين جزء linear أو elastic وجزء plastic أو 
+
+370
+00:36:27,610 --> 00:36:32,250
+non elastic الجزء الـ elastic يتم استرجاعه لأن لما
+
+371
+00:36:32,250 --> 00:36:35,210
+رجعت ما رجعت لسه رجعت لهنا المعنى هذا هو ايش يمثل
+
+372
+00:36:35,210 --> 00:36:40,170
+الـ plastic strain اللي تم استرجاعه اللي هو هذا الـ
+
+373
+00:36:40,170 --> 00:36:42,450
+plastic strain
+
+374
+00:36:44,840 --> 00:36:54,420
+و هذا أبسلون plastic والـ total strain total 
+
+375
+00:36:54,420 --> 00:37:04,880
+strain so أبسلون elastic زائد أبسلون plastic و
+
+376
+00:37:04,880 --> 00:37:13,580
+الأبسلون elastic بستوى اللي هو سيجما على E أبسلون
+
+377
+00:37:13,580 --> 00:37:14,160
+plastic
+
+378
+00:37:20,530 --> 00:37:25,830
+لأ لأ لأ لأ هذا قليل من الـ strength لأن الـ elastic
+
+379
+00:37:25,830 --> 00:37:29,530
+strain ثابت لنفس الـ material صحيح لأن هذا كله
+
+380
+00:37:29,530 --> 00:37:36,270
+مسترد لو وصلت هنا أنا لو كنت هنا ورجعت هرجع موازي
+
+381
+00:37:36,270 --> 00:37:44,870
+هي هي الـ plastic strain وهي
+
+382
+00:37:44,870 --> 00:37:47,960
+الـ elastic strain ما طيرت في قيمة الـ Elastic 
+
+383
+00:37:47,960 --> 00:37:57,640
+Strain، طيرت في قيمة الـ Plastic Strain فأنا
+
+384
+00:37:57,640 --> 00:38:02,460
+أول شيء عملت loading لحد ما وصلت لنقطة I ورجعت صار
+
+385
+00:38:02,460 --> 00:38:06,460
+عندي ما رجعتش للصفر لأنه دخلت الـ plastic range هذا
+
+386
+00:38:06,460 --> 00:38:13,300
+أبسلون plastic إذا بعمل loading كمان مرة حصل I و
+
+387
+00:38:13,300 --> 00:38:22,310
+أنا لسه في الـ elastic range هتصير المادة هتصير مش
+
+388
+00:38:22,310 --> 00:38:29,250
+زي هيك صارت المادة أقوى لو عملت unloading من هنا و
+
+389
+00:38:29,250 --> 00:38:36,810
+رجعت هرجع زي هيك المادة كل ما لها بتصير brittle
+
+390
+00:38:36,810 --> 00:38:37,970
+أكثر تنشف
+
+391
+00:38:41,580 --> 00:38:44,640
+ففيه limit للاستيرنهارنج ما نفعش أعمل استيرنهارنج
+
+392
+00:38:44,640 --> 00:38:48,720
+too much هتصير المادة too brittle ممكن تصير في نهاية
+
+393
+00:38:48,720 --> 00:38:53,320
+الـ
+
+394
+00:38:53,320 --> 00:39:04,860
+hardness
+
+395
+00:39:04,860 --> 00:39:18,780
+هي مقاومة المادة للخدش من أداة مصنوعة من مادة أكثر 
+
+396
+00:39:18,780 --> 00:39:23,920
+قساوة من المادة تحت الفحص يعني
+
+397
+00:39:23,920 --> 00:39:31,280
+ما نفعش أخدش الحديد القاسي بخشب حتى لو كان عنده حد
+
+398
+00:39:31,280 --> 00:39:39,800
+مش هيخدشه فهي مقاومة المادة للخدش من pointed tool
+
+399
+00:39:39,800 --> 00:39:43,680
+يعني tool رأس مدبب بس الـ hardness بتاعته أعلى من
+
+400
+00:39:43,680 --> 00:39:49,240
+المادة تاعت الفحص عندنا كثير فاحصات طرق لفحص الـ
+
+401
+00:39:49,240 --> 00:39:52,720
+hardness منها Rockwell hardness test وعندنا Brinell
+
+402
+00:39:52,720 --> 00:39:56,200
+hardness test و Vickers hardness test وفي فحصات
+
+403
+00:39:56,200 --> 00:40:00,780
+ثانية هذه الأكثر شهرة طبعًا 
+
+404
+00:40:00,780 --> 00:40:04,840
+في علاقة بين الـ ultimate tensile strength والـ
+
+405
+00:40:04,840 --> 00:40:11,340
+hardness في حالة الستيل SUT بيساوي ثلاثة point
+
+406
+00:40:11,340 --> 00:40:15,920
+أربعة hardness of brittle لو كانت الوحدات بالميجا
+
+407
+00:40:15,920 --> 00:40:22,640
+باسكال وحدات SI unit ففي حالة الـ cast iron الـ SU
+
+408
+00:40:22,640 --> 00:40:25,280
+بيساوي واحد point خمسة ثمانية H بيه hardness of
+
+409
+00:40:25,280 --> 00:40:28,700
+brittle ناقص ستة وثمانين ميجا باسكال طبعًا ومعطيني
+
+410
+00:40:28,700 --> 00:40:33,200
+علاقة مرة في حالة الـ English unit ومرة في حالة الـ
+
+411
+00:40:33,200 --> 00:40:34,120
+SI units
+
+412
+00:40:39,820 --> 00:40:43,900
+في الـ impact properties خصائص المادة تحت تأثير
+
+413
+00:40:43,900 --> 00:40:48,160
+الصدمات الميكانيكية استخدمنا شاربي نوتش impact
+
+414
+00:40:48,160 --> 00:40:55,420
+test في الـ Charpy notch impact test بنثبت
+
+415
+00:40:55,420 --> 00:41:01,520
+عينة وبنضربها بشكوش بـ .. بندول بنضربها لحد ايش؟
+
+416
+00:41:01,520 --> 00:41:06,680
+الكسر وكنا نقيس كمية الطاقة اللي متصرفة خلال
+
+417
+00:41:06,680 --> 00:41:10,080
+عملية الكسر كل ما كانت كمية الطاقة اللي متصرفة
+
+418
+00:41:10,080 --> 00:41:14,300
+خلال عملية الكسر أكثر معناته هذا بيؤكد أن المادة
+
+419
+00:41:14,300 --> 00:41:17,960
+قدرتها على امتصاص الصدمات أكثر كل ما قلت الطاقة
+
+420
+00:41:17,960 --> 00:41:21,280
+اللي متصرفة في كسر العينة كل ما كانت المادة قدرتها 
+
+421
+00:41:21,280 --> 00:41:25,020
+على امتصاص الصدمات أقل و عملنا رسمنا الـ curve هذا
+
+422
+00:41:26,190 --> 00:41:30,270
+يعني هين درجة الحرارة تنبرتشها و هين الشاربة الـ
+
+423
+00:41:30,270 --> 00:41:35,410
+impact energy ده مين جال على قساوة المادة أو 
+
+424
+00:41:35,410 --> 00:41:40,450
+مورانتها؟ اللي هو قدرتها على مص الصدمات؟ الآن
+
+425
+00:41:40,450 --> 00:41:43,550
+قدرتها على مص الصدمات بيتمد على الـ character
+
+426
+00:41:43,550 --> 00:41:47,150
+بتاعها هي كيف هتتصرف هتتصرف ductile ولا brittle؟
+
+427
+00:41:47,150 --> 00:41:49,750
+تصرف الـ ductile و الـ brittle بيتم من درجة الحرارة
+
+428
+00:41:49,750 --> 00:41:54,750
+يعني الحديد عن درجات حرارة الغرفة العادية ductile
+
+429
+00:41:55,790 --> 00:42:00,130
+بمتص ضمات لكن برضه عند ماقص مية و خمسين بيصير
+
+430
+00:42:00,130 --> 00:42:05,810
+very brittle ناشف باطل متص فعندي ما يسمى هذا هو الـ
+
+431
+00:42:05,810 --> 00:42:11,070
+curve يعني الـ material هذا واضح تقريبا أعلى .. بعد
+
+432
+00:42:11,070 --> 00:42:17,200
+السفر بتتصرف تقريبا ductile تحت السفر تتصرف as
+
+433
+00:42:17,200 --> 00:42:21,600
+brittle والدليل في المنطقة هذه الـ absorbed energy
+
+434
+00:42:21,600 --> 00:42:26,220
+بتكون قليلة في المنطقة هذه الـ absorbed energy
+
+435
+00:42:26,220 --> 00:42:34,560
+بتكون عالية بشكل
+
+436
+00:42:34,560 --> 00:42:38,910
+عام الـ FCC الـ BCC materials بيكون فيها الـ
+
+437
+00:42:38,910 --> 00:42:43,570
+Transition Temperature واضحة في حالة الـ FCC بيكون
+
+438
+00:42:43,570 --> 00:42:47,990
+مافيش تقرية يعني تقرية بيكون الـ impact energy بشكل
+
+439
+00:42:47,990 --> 00:42:53,410
+هذا هاي عندي اللي هو الـ temperature و الـ energy
+
+440
+00:42:53,410 --> 00:42:56,890
+لكن
+
+441
+00:42:56,890 --> 00:43:05,730
+في حالة BCC metals مش زي هيك هذا FCC هذا BCC
+
+442
+00:43:15,050 --> 00:43:18,930
+الآن السؤال هل الـ .. الـ .. الـ .. الـ strength تتغير
+
+443
+00:43:18,930 --> 00:43:24,810
+مع درجة الحرارة؟ اه تتغير مع درجة الحرارة هندرس في
+
+444
+00:43:24,810 --> 00:43:29,270
+curve بين الـ strength as a function of temperature
+
+445
+00:43:29,270 --> 00:43:32,730
+الـ curve اللي علوه مثل الـ ultimate strength والـ
+
+446
+00:43:32,730 --> 00:43:37,850
+curve التانية مثل الـ yield strength في حالة الـ
+
+447
+00:43:37,850 --> 00:43:40,250
+ultimate strength كل ما ازود درجة الحرارة في
+
+448
+00:43:40,250 --> 00:43:43,810
+البداية بتكون الـ ultimate strength بيزيد بشكل غير
+
+449
+00:43:43,810 --> 00:43:49,460
+ملحوظ لحد ما تصل maximum وبعدين تتناقص بشكل سريع 
+
+450
+00:43:49,460 --> 00:43:54,280
+مع درجة الحرارة الـ ultimate tensile strength لكن
+
+451
+00:43:54,280 --> 00:44:01,020
+الـ yield strength دائماً بتقل مع درجة الحرارة
+
+452
+00:44:01,020 --> 00:44:05,400
+الـ
+
+453
+00:44:05,400 --> 00:44:11,340
+creep هي ظاهرة الزحف أو ظاهرة التمدد تحت تأثير
+
+454
+00:44:11,340 --> 00:44:18,640
+أحمال عن درجات حرارة مرتفعة بيصير عندي تمدد بشكل
+
+455
+00:44:18,640 --> 00:44:23,100
+مستمر رسمناه يسمى creep curve كان مكون من تلات
+
+456
+00:44:23,100 --> 00:44:26,300
+مراحل المرحلة اللي بيسمونها الـ primary stage
+
+457
+00:44:26,300 --> 00:44:29,480
+المرحلة التانية الـ secondary stage المرحلة التالتة
+
+458
+00:44:29,480 --> 00:44:33,480
+الـ tertiary stage في الـ primary stage بيكون الـ
+
+459
+00:44:33,480 --> 00:44:41,720
+strain بيزيد بمعدل متناقص بيزيد بمعدل متناقص بيصير 
+
+460
+00:44:41,720 --> 00:44:46,100
+linear at constant rate وبعدين بيزيد الـ strain
+
+461
+00:44:46,100 --> 00:44:56,680
+بمعدل متزايد لحد الكسر أو حد الفيلير طيب
+
+462
+00:44:56,680 --> 00:45:00,120
+نظم
+
+463
+00:45:00,120 --> 00:45:04,020
+الترقيم material numbering systems فأني common
+
+464
+00:45:04,020 --> 00:45:07,220
+numbering systems مجموعة من طرق الترقيم للمواد
+
+465
+00:45:07,220 --> 00:45:09,400
+عندي
+
+466
+00:45:10,930 --> 00:45:13,690
+society of automotive engineers S.A.E. لها 
+
+467
+00:45:13,690 --> 00:45:17,350
+numbering system and American iron and steel
+
+468
+00:45:17,350 --> 00:45:20,870
+institute لها numbering system and unified
+
+469
+00:45:20,870 --> 00:45:24,410
+numbering system الـ U.N.S. and American society
+
+470
+00:45:24,410 --> 00:45:27,830
+for testing and materials A.S.T.M for cast iron
+
+471
+00:45:27,830 --> 00:45:32,510
+لها numbering system
+
+472
+00:45:32,510 --> 00:45:38,070
+الـ اه ماشي الـ system المشهور عندنا اللي بيشتغل 
+
+473
+00:45:39,090 --> 00:45:42,770
+كلهم، يعني هدول كلهم مستخدمين، يعني .. يعني كلهم
+
+474
+00:45:42,770 --> 00:45:46,050
+هدول مستخدمين، الآن هنا .. أنت بتحكي في غزو ولا ..
+
+475
+00:45:46,050 --> 00:45:52,770
+ولا وين؟ عالمياً .. عالمياً هذه مشهورة كثير، يعني
+
+476
+00:45:52,770 --> 00:45:57,150
+هذه مشهورة كثير في .. في الولايات المتحدة، في عندك
+
+477
+00:45:57,150 --> 00:46:00,590
+الـ standard طبعاً الياباني وفي عندك الـ .. الـ
+
+478
+00:46:00,590 --> 00:46:03,330
+standard الـ .. الـ .. البريطاني وفي عندك الـ 
+
+479
+00:46:03,330 --> 00:46:08,830
+standard الألماني نعم society زي دي بتسمي المواد و
+
+480
+00:46:08,830 --> 00:46:12,910
+بتعريفها هذا الـ .. أحدث مش كلها هذا النظام في
+
+481
+00:46:12,910 --> 00:46:16,690
+أمريكا معظمه وكثير من الدول ماشية عليه كثير من
+
+482
+00:46:16,690 --> 00:46:18,730
+الدول ماشية عليه بس في standard ثانية هتشوف اللي 
+
+483
+00:46:18,730 --> 00:46:23,110
+هو النظام الياباني نظام الألماني ونظام بريطانيا
+
+484
+00:46:23,110 --> 00:46:26,750
+هم هدول أنظمة كثير شهر كثير طبعاً من .. في .. في 
+
+485
+00:46:26,750 --> 00:46:30,010
+يعني بتحكي والله المدى رقمها كذا تعادل رقم كذا في
+
+486
+00:46:30,010 --> 00:46:35,460
+النظام الألماني أو الـ .. المدى رقمت ..في الـ .. في 
+
+487
+00:46:35,460 --> 00:46:39,460
+الـ S.C.E رقم معين وعادل في النظام الألماني اللي لها
+
+488
+00:46:39,460 --> 00:46:43,420
+رقم معادل يعني في تحويل بين الأنظمة يعني عشر و
+
+489
+00:46:43,420 --> 00:46:46,900
+عشرين ستين مختلف من نظام لنظام مثلاً؟ لأ خليني 
+
+490
+00:46:46,900 --> 00:46:51,600
+أبتعد .. يعني أنت .. أنت .. هذا طريقة ترقيم مختصة
+
+491
+00:46:51,600 --> 00:46:54,340
+بالـ organization نفسها مينفعش تحكي والله مختلفة و
+
+492
+00:46:54,340 --> 00:46:57,920
+مش مختلفة هذا نظام ترقيمهم لما أنت تختار مادة
+
+493
+00:46:57,920 --> 00:47:01,020
+تختار حسن النظام اللي أنت شغال عليه أنت في الآخر
+
+494
+00:47:01,020 --> 00:47:03,760
+تختار مش أرقام .. تختار ش أرقام أنت ايش تختار؟
+
+495
+00:47:04,650 --> 00:47:09,110
+بتختار خواص مظبوط الخواص اللي بتناسب مع الرقم بغض 
+
+496
+00:47:09,110 --> 00:47:13,450
+النظر عن الـ system تخدها وبتحط philosophical أنا 
+
+497
+00:47:13,450 --> 00:47:21,750
+اخترت والله اللي هو مثلاً S.A.E 1020 مثلاً اللي خواصه
+
+498
+00:47:21,750 --> 00:47:30,350
+واحد اثنين تلاتة لأن 
+
+499
+00:47:30,350 --> 00:47:36,630
+ماتقارنوطش لأن في نظام ترقيم نظام ترقيم أنه ترقيم 
+
+500
+00:47:36,630 --> 00:47:41,170
+مختلف عن بعض أنا في الآخر باختار خواص باختار خواص
+
+501
+00:47:41,170 --> 00:47:46,250
+لأن بفتح كتالوجنا الكتالوج بحكي والله الـ ST حسب
+
+502
+00:47:46,250 --> 00:47:50,110
+ترقيم النظام الألماني الـ ST رقم واحد هي خواصه أنا
+
+503
+00:47:50,110 --> 00:47:56,770
+باختار الخواص وفي الآخر هدخل ايش؟ كتالوج وبحط بحكي
+
+504
+00:47:56,770 --> 00:47:59,590
+طبق النظام الترقيم الألماني كذا كذا أو طبق النظام
+
+505
+00:47:59,590 --> 00:48:06,870
+الـ S.E.E أو طبق النظام الـ A.I.S.I أو الـ U.N.S الآن
+
+506
+00:48:06,870 --> 00:48:10,570
+الـ U.N.S numbering system تم اعتماد بواسطة الـ
+
+507
+00:48:10,570 --> 00:48:13,250
+society of automotive engineers سنة ألف تسعمائة وخمس
+
+508
+00:48:13,250 --> 00:48:21,330
+سبعين مكون من letter letter مطبوع بخمس أرقام كم
+
+509
+00:48:21,330 --> 00:48:27,310
+الرقم مطبوع بخمس digits الآن 
+
+510
+00:48:27,310 --> 00:48:37,190
+الـ letter قد يكون G أو A أو C أو S G carbon and
+
+511
+00:48:37,190 --> 00:48:42,640
+alloys steel اللي هو الحديد والسباكة الـ G الـ A 
+
+512
+00:48:42,640 --> 00:48:48,320
+الالمنيوم سباكة الالمنيوم الـ C سباكة النحاس الـ S
+
+513
+00:48:48,320 --> 00:48:55,280
+سباكة الـ stainless steel الآن حكينا .. الآن الرقم
+
+514
+00:48:55,280 --> 00:49:02,700
+ممكن يكون G ورا خمس أرقام أو A ورا خمس أرقام أو C
+
+515
+00:49:02,700 --> 00:49:08,420
+ورا خمس أرقام أو S ورا خمس أرقام مثلاً لو أخذنا الـ 
+
+516
+00:49:08,420 --> 00:49:16,620
+G الـ G ايش؟ steel سباكة الحديد والسباكة اللي احنا
+
+517
+00:49:16,620 --> 00:49:30,780
+حكينا G هاي X X X X X أو الرقمين بيمثل
+
+518
+00:49:30,780 --> 00:49:33,980
+الـ الـ الـ first two digits indicate composition
+
+519
+00:49:33,980 --> 00:49:40,140
+بيحكوا علياش الـ composition
+
+520
+00:49:47,570 --> 00:49:53,810
+الرقمين التانين بيحكوا عن نسبة الكربون هتكون XX
+
+521
+00:49:53,810 --> 00:50:01,330
+على 100% نسبة الكربون الرقم 
+
+522
+00:50:01,330 --> 00:50:06,630
+الأخير رقم خاص بس أنا بأهم إن الرقمين الأولين 
+
+523
+00:50:06,630 --> 00:50:12,740
+والتالت والرابع يعني لما نحكي G طبعاً الأول رقم اللي 
+
+524
+00:50:12,740 --> 00:50:16,920
+عندي G 10 G 11 G 13 G 3
+
+525
+00:50:16,920 --> 00:50:24,920
+و40 G 49 لو حكيت G 10 2
+
+526
+00:50:24,920 --> 00:50:31,840
+زيرو ايش معناه بيطلع G أول رقم اللي عندي هاي هون
+
+527
+00:50:31,840 --> 00:50:35,760
+plain carbon حديد سادة ما فيش فيه عناصر تانية بس 
+
+528
+00:50:35,760 --> 00:50:36,040
+carbon
+
+529
+00:50:38,980 --> 00:50:42,000
+20 هقسم هذا عالمياً الشيء عالمياً اللي هي point
+
+530
+00:50:42,000 --> 00:50:52,980
+2 في المية carbon لو حكيت G 40 30
+
+531
+00:50:52,980 --> 00:51:02,840
+نصف
+
+532
+00:51:02,840 --> 00:51:06,460
+كربون في point 3 في المية point 3 في المية
+
+533
+00:51:08,650 --> 00:51:12,650
+هذه مثال G 25 2 25 9
+
+534
+00:51:12,650 --> 00:51:17,450
+8 6 25 هي 25 Chrome
+
+535
+00:51:17,450 --> 00:51:23,050
+Steel نفس الكربون فيه كم بقون 9 8 في
+
+536
+00:51:23,050 --> 00:51:28,010
+المية بقون 9 8 في المية هذا الكلام كل 
+
+537
+00:51:28,010 --> 00:51:35,910
+الواحد يقيمه أو خلاص؟ نعم حد لاقيش هذا U.N.S هذا نظام 
+
+538
+00:51:35,910 --> 00:51:39,270
+الترقيم للـ U.N.S بدك أنت ترقيم تاني تطلع عليها
+
+539
+00:51:39,270 --> 00:51:46,350
+اللي هي شوف كيف نظام ترقيمهم الـ 
+
+540
+00:51:46,350 --> 00:51:49,330
+alloy steels سابقاً في chrome alloy steels نيكل
+
+541
+00:51:49,330 --> 00:51:53,770
+alloy steels في عندي مانجانيز يكون فيها مانجانيز
+
+542
+00:51:53,770 --> 00:51:55,830
+الشكل الأساسي في عندي silicone alloy steels
+
+543
+00:51:55,830 --> 00:52:00,090
+موليبدينوم alloy steels و vanadium alloy steels و
+
+544
+00:52:00,090 --> 00:52:01,610
+tungsten alloy steels
+
+545
+00:52:05,380 --> 00:52:11,180
+الـ stainless steels هي عبارة عن سباكة أساس الحديد
+
+546
+00:52:11,180 --> 00:52:16,620
+بالنسبة للـ chrome بتكون فيها مرتفع أقلش 12% هذا
+
+547
+00:52:16,620 --> 00:52:19,560
+اللي هو الـ stainless steel الـ chrome فيها بيكون
+
+548
+00:52:19,560 --> 00:52:26,800
+أقلش 12% طبعاً مذيتها يعني بتقاوم resist اللي هو
+
+549
+00:52:26,800 --> 00:52:30,220
+corrosive conditions most مش كل .. مش كل شي بتقاوم
+
+550
+00:52:30,220 --> 00:52:35,920
+most corrosive conditions في عندي أربع نوع من الـ
+
+551
+00:52:35,920 --> 00:52:38,140
+stainless steel فعندي ferratic chromium stainless
+
+552
+00:52:38,140 --> 00:52:41,960
+steel فعندي austenitic chromium nickel stainless
+
+553
+00:52:41,960 --> 00:52:46,460
+steel فعندي martenistic stainless steel فعندي
+
+554
+00:52:46,460 --> 00:52:54,620
+precipitation hardenable stainless steel في
+
+555
+00:52:54,620 --> 00:52:58,320
+الـ casting materials اللي هو الحديد السابق السكب 
+
+556
+00:52:58,320 --> 00:53:03,910
+في ست أنواع الـ Gray Cast Iron والـ Ductile and
+
+557
+00:53:03,910 --> 00:53:07,350
+Nodular Cast Iron والـ White Cast Iron والـ
+
+558
+00:53:07,350 --> 00:53:11,190
+Malleable Cast Iron والـ Alloy Cast Iron والـ Cast
+
+559
+00:53:11,190 --> 00:53:17,810
+Steel الـ
+
+560
+00:53:17,810 --> 00:53:23,850
+Nonferrous metals هي المعادن اللي ما فيها حديد اللي 
+
+561
+00:53:23,850 --> 00:53:28,130
+هي الألمنيوم المنجانيستي ثلاثة مش كله طبعا الذاكرة
+
+562
+00:53:28,130 --> 00:53:34,140
+ثلاثة بس هم أكتران الألمنيوم ماغنيسيوم تيتانيوم ..
+
+563
+00:53:34,140 --> 00:53:39,060
+هنا الـ copper based alloys .. copper based alloys
+
+564
+00:53:39,060 --> 00:53:44,680
+فيه كثير منها عندي .. في سبائك نحاس بيكون .. برأس
+
+565
+00:53:44,680 --> 00:53:51,020
+نسبة الزنك فيه خمسة إلى خمسة عشر في المئة يعني طبعا تحتها
+
+566
+00:53:51,020 --> 00:53:54,560
+ما زال في عندي range في كذا نوع gilding brass,
+
+567
+00:53:54,800 --> 00:53:57,400
+commercial bronze, red brass في أنواع كثير من ال
+
+568
+00:53:57,400 --> 00:54:00,920
+brass في عندي brass نسبة الزنك فيه من عشرين لستة و
+
+569
+00:54:00,920 --> 00:54:04,180
+ثلاثين في المئة عندي low brass, cartridge brass,
+
+570
+00:54:04,300 --> 00:54:08,000
+naval brass, low lead brass في أنواع كثير من ال
+
+571
+00:54:08,000 --> 00:54:11,740
+.. ال .. اللي هو الـ brass يعني الـ brass نسبة الزنك
+
+572
+00:54:11,740 --> 00:54:15,300
+من ستة وثلاثين لثمانين في المئة فيه months مثل naval
+
+573
+00:54:15,300 --> 00:54:19,440
+brass في عند الـ bronze بيكون فيه إيش؟ silicon ال
+
+574
+00:54:19,440 --> 00:54:23,600
+bronze بيكون فيه الـ silicon الـ silicon الـ bronze
+
+575
+00:54:23,600 --> 00:54:25,320
+في عند الـ phosphorus الـ bronze في عند الـ aluminium
+
+576
+00:54:25,320 --> 00:54:30,120
+الـ bronze في عند الـ beryllium الـ bronze يعني ال
+
+577
+00:54:30,120 --> 00:54:33,700
+brass بيكون عنصر أساسي في الزنك الـ bronze ممكن
+
+578
+00:54:33,700 --> 00:54:37,100
+يكون فيه silicon ممكن يكون فيه فوسفور ممكن فيه
+
+579
+00:54:37,100 --> 00:54:39,140
+aluminium ممكن يكون فيه beryllium
+
+580
+00:54:42,170 --> 00:54:49,770
+نأتي للـ plastics ال
+
+581
+00:54:49,770 --> 00:54:53,210
+plastics فيه نوعان أساسيا في عندي thermoplastic و
+
+582
+00:54:53,210 --> 00:54:57,090
+في عندي thermoset plastic الـ thermoplastic هي أي
+
+583
+00:54:57,090 --> 00:55:04,770
+plastic اللي ممكن أشكله بالتسخين بأسهله وبضخه في
+
+584
+00:55:04,770 --> 00:55:10,930
+قالب بأخذ شكل القالب بالتسخين يسيح وبأخذ شكله هي ال
+
+585
+00:55:10,930 --> 00:55:15,730
+thermoplastic الـ thermoset الـ thermoset هي ال
+
+586
+00:55:15,730 --> 00:55:23,970
+material بتسيح تحت الضغط وبتتجمد أو بيصير a curing
+
+587
+00:55:23,970 --> 00:55:29,520
+بالحرارة يعني بيستخدموا ضغط و حرارة ضغط عشان يخليها
+
+588
+00:55:29,520 --> 00:55:32,880
+fluidized تمشي و الحرارة عشان يعملوا لها curing
+
+589
+00:55:32,880 --> 00:55:39,340
+تنشف بالحرارة هذا اللي هي الـ thermoset طبعا ال
+
+590
+00:55:39,340 --> 00:55:42,380
+thermoplastic الـ material اللي فيه كثير عندي فيه
+
+591
+00:55:42,380 --> 00:55:48,020
+عندي ABS group عندي acetal acrylic عندي phenylene
+
+592
+00:55:48,020 --> 00:55:54,000
+عندي polycarbonate عندي polyester عندي polyamide
+
+593
+00:55:54,000 --> 00:55:59,610
+عندي أنواع كثير وهنا حاطط الخواص بتاعة ال
+
+594
+00:55:59,610 --> 00:56:05,350
+thermoplastic .. thermoplastic materials فعندي ال
+
+595
+00:56:05,350 --> 00:56:13,510
+thermoset materials زي الـ alkyd عند الـ aminos عند
+
+596
+00:56:13,510 --> 00:56:17,730
+الـ epoxies عند الفينولكس عند السيليكونز هذه كلها
+
+597
+00:56:17,730 --> 00:56:23,380
+تصنف كـ thermoset materials هذا بده كورس كامل
+
+598
+00:56:23,380 --> 00:56:26,880
+لحالها اللي هي الـ course .. اه اتفضل .. كنتم بدكم
+
+599
+00:56:26,880 --> 00:56:30,460
+course ليش خططنا عن زي مثلًا الـ material وما ينفعش
+
+600
+00:56:30,460 --> 00:56:34,900
+.. الـ plastic طالعينه .. مش مطالبينهم بدها انت هذا
+
+601
+00:56:34,900 --> 00:56:38,640
+الـ course مركز ال .. ال .. لإن إحنا بنركز على
+
+602
+00:56:38,640 --> 00:56:43,960
+المواد البلورية crystal materials الـ plastic is
+
+603
+00:56:43,960 --> 00:56:48,780
+not a crystal material اه فهو فعلًا إحنا بندرس
+
+604
+00:56:48,780 --> 00:56:52,190
+mechanical engineering ما بندرس اللي هو material
+
+605
+00:56:52,190 --> 00:56:55,630
+engineering، في فرع بيكون عندك material
+
+606
+00:56:55,630 --> 00:56:58,810
+engineering شكل كاملة، تأخذ يعني كثير كورسات في ال
+
+607
+00:56:58,810 --> 00:57:04,050
+material .. ceramics .. composite .. polymers ..
+
+608
+00:57:04,050 --> 00:57:11,290
+في تفاصيل كثير حتى
+
+609
+00:57:11,290 --> 00:57:17,660
+في الـ baccadoris طيب composite materials اسمه نفسه
+
+610
+00:57:17,660 --> 00:57:20,440
+composite مكونا من two or more dissimilar
+
+611
+00:57:20,440 --> 00:57:23,000
+materials مكونا من مادتين أو أكثر من المواد
+
+612
+00:57:23,000 --> 00:57:27,640
+الخواص مختلفة عن بعض each of which contributed
+
+613
+00:57:27,640 --> 00:57:30,560
+to the final properties المواد المكونة للـ composite
+
+614
+00:57:30,560 --> 00:57:33,960
+بيطور الخواص النهائية للمادة لكن لو عملت section
+
+615
+00:57:33,960 --> 00:57:38,800
+في المادة كل مادة محتفظة بخواصها بشكل منفصل يعني
+
+616
+00:57:38,800 --> 00:57:46,500
+الخرسانة المسلحة يعتبر إيش؟ composite في حصى في أسمنت
+
+617
+00:57:46,500 --> 00:57:48,580
+وفي عندي حديد
+
+618
+00:57:56,700 --> 00:58:00,040
+الآن طبعًا لو ال .. ال .. الـ fiberglass is
+
+619
+00:58:00,040 --> 00:58:03,540
+composite material بنستخدم filler الآن طبعًا في عند
+
+620
+00:58:03,540 --> 00:58:06,420
+المادة الأساسية اللي بتكون عادة الـ strength
+
+621
+00:58:06,420 --> 00:58:09,440
+بتاعتها عالية و brittle وفي مادة الـ filler
+
+622
+00:58:09,440 --> 00:58:13,000
+material اللي هي بتخلق .. بتعبي المادة بشكل عام
+
+623
+00:58:13,000 --> 00:58:18,840
+مثلًا في حالة ال .. ال .. الـ fiberglass الـ filler
+
+624
+00:58:18,840 --> 00:58:23,760
+material ممكن تكون على شكل شبكة شبكة ممكن تكون على
+
+625
+00:58:23,760 --> 00:58:28,100
+شكل خطوط أو على شكل الـ nodular أو على شكل حبيبات
+
+626
+00:58:28,100 --> 00:58:34,060
+وتنخلط معاها اللي هو الـ epoxy تتجمد بالـ C and H
+
+627
+00:58:34,060 --> 00:58:36,160
+مادة competent material
+
+628
+00:58:39,480 --> 00:58:42,960
+الموجود عندنا .. الموجود .. النوع اللي عندنا موجود
+
+629
+00:58:42,960 --> 00:58:46,080
+فتاح في غزل هو النوع هذا الـ filler ماديته عبارة عن
+
+630
+00:58:46,080 --> 00:58:55,960
+بتكون شبكة fibers الـ filler
+
+631
+00:58:55,960 --> 00:58:59,240
+هي اللي هي بتكون مثلًا في حالة الـ fiberglass اللي
+
+632
+00:58:59,240 --> 00:59:04,900
+هو اللي هو الألياف الزجاجية الألياف الزجاجية لحالها
+
+633
+00:59:04,900 --> 00:59:11,090
+هشة بتتفتفت you apply اللي هو الـ epoxy طبقة بعدين
+
+634
+00:59:11,090 --> 00:59:14,210
+بتحط عندك اللي هو الـ filler material أو الشبكة
+
+635
+00:59:14,210 --> 00:59:20,070
+بعدين بتدهن عليها وكذا تطلع خش على اليوتيوب شوف
+
+636
+00:59:20,070 --> 00:59:22,910
+الـ composite الـ fiberglass application هتشوف
+
+637
+00:59:22,910 --> 00:59:25,990
+فيديوهات كثير fiberglass application شوف كيف
+
+638
+00:59:25,990 --> 00:59:28,370
+بيعملوه يمكن أي حد نفسه يعملوه لحاله
+
+639
+00:59:32,640 --> 00:59:35,720
+الآن الـ material families and classes حكينا فيه أن
+
+640
+00:59:35,720 --> 00:59:40,600
+المعادن .. المعادن فيه السبائك الألمونيوم والنحاس،
+
+641
+00:59:40,600 --> 00:59:44,320
+الرصاص، المنجنيز، الصلب ستين، التيتانيوم،
+
+642
+00:59:44,320 --> 00:59:52,690
+التنجستن، الرصاص، الزنك، عندي الـ ceramics ال
+
+643
+00:59:52,690 --> 00:59:57,070
+ceramics عندي اللي هي عندي الـ alumina AL2O3، عندي
+
+644
+00:59:57,070 --> 00:59:59,430
+الـ aluminium nitride، عندي الـ boron carbide،
+
+645
+00:59:59,430 --> 01:00:02,390
+عندي الـ silicon carbide، silicon nitride، tungsten
+
+646
+01:00:02,390 --> 01:00:06,250
+carbide، الـ brick يعتبر برضه إيش ceramic، ال
+
+647
+01:00:06,250 --> 01:00:10,670
+concrete ceramic، الأحجار ceramic، الـ soda lime
+
+648
+01:00:10,670 --> 01:00:15,050
+glass، ال .. الـ silica glass و الـ glass ceramics،
+
+649
+01:00:15,050 --> 01:00:19,760
+هذه كلها مواد ceramic العائلة الثانية هي ال
+
+650
+01:00:19,760 --> 01:00:24,280
+polymers الـ polymers عند الـ ABS عند الـ PET عند ال
+
+651
+01:00:24,280 --> 01:00:28,920
+PE عند الـ PP الـ polypropylene يعني في أنواع كثير
+
+652
+01:00:28,920 --> 01:00:33,140
+من الـ polymers عند
+
+653
+01:00:33,140 --> 01:00:39,410
+الـ elastomers هي الـ rubbers سواء كانت طبيعية المطاط
+
+654
+01:00:39,410 --> 01:00:43,810
+سواء كانت طبيعية أو صناعية وفيها كثير من ال
+
+655
+01:00:43,810 --> 01:00:48,610
+rubbers عند الـ hybrids يعني الـ composites composite
+
+656
+01:00:48,610 --> 01:00:52,850
+materials عند الـ foams وعند الـ natural materials
+
+657
+01:00:52,850 --> 01:00:55,350
+فهذه كل الـ materials الموجودة طبعًا في materials
+
+658
+01:00:55,350 --> 01:01:01,530
+ثانية اللي هي الـ الـ nano materials الـ nano carbon
+
+659
+01:01:01,530 --> 01:01:03,470
+tubes وفيها تفاصيل
+
+660
+01:01:06,560 --> 01:01:09,140
+عندي هي المار جين الـ Young modulus أو الـ modulus
+
+661
+01:01:09,140 --> 01:01:12,200
+بالنسبة له for various materials هذا on average
+
+662
+01:01:12,200 --> 01:01:16,780
+عندي مثلًا هي الـ tungsten carbide is very hard
+
+663
+01:01:16,780 --> 01:01:19,980
+material فما أتوقع يكون الـ stress strain curve
+
+664
+01:01:19,980 --> 01:01:21,140
+بتاعها شيء زي هيك
+
+665
+01:01:25,560 --> 01:01:30,000
+يعني بتكون very hard بيصيرش الـ plastic deformation
+
+666
+01:01:30,000 --> 01:01:34,020
+almost zero لحد الكسر والـ slope تقريبًا بيكون يعني
+
+667
+01:01:34,020 --> 01:01:36,200
+almost ستين درجة فبتكون الـ modulus of elasticity
+
+668
+01:01:36,200 --> 01:01:41,160
+بتاعتها مرتفعة لو أخذت مادة هنا تحت flexible
+
+669
+01:01:41,160 --> 01:01:45,740
+polymer material هتكون منحنى جديد وبيكون ال
+
+670
+01:01:45,740 --> 01:01:49,020
+slope بتاع الـ stress strength بتاعها قليل وبتاع
+
+671
+01:01:49,020 --> 01:01:50,960
+الـ modulus of elasticity بتكون إلا منخفضة لو
+
+672
+01:01:50,960 --> 01:01:51,780
+أخذنا مادة هنا
+
+673
+01:01:56,040 --> 01:02:00,200
+Titanium Alloy Titanium
+
+674
+01:02:00,200 --> 01:02:04,840
+Alloy برضه still الـ model الـ still بتاعتها عالية
+
+675
+01:02:04,840 --> 01:02:11,740
+عن الـ nickel alloy طبعًا الـ titanium وال
+
+676
+01:02:11,740 --> 01:02:17,620
+nickel الـ strength للـ weight ratio مرتفعة يعني for
+
+677
+01:02:17,620 --> 01:02:24,020
+the same unit of weight بحصل strength أعلى في
+
+678
+01:02:24,020 --> 01:02:28,490
+التيتانيوم وأكثر أعلى من الحديد واضح؟ الـ strength
+
+679
+01:02:28,490 --> 01:02:32,350
+weight ratio عالية عشان تستخدم في الـ applications
+
+680
+01:02:32,350 --> 01:02:37,130
+اللي أنا محتاج أخفف في الوزن فيها كثير زي مثلًا
+
+681
+01:02:37,130 --> 01:02:42,050
+نظارات مش محتاج .. أنا يعني لازم أكون خفيفة قدر
+
+682
+01:02:42,050 --> 01:02:46,030
+الممكن في الطائرات بتحتاج أستخدم مواد خفيفة الوزن
+
+683
+01:02:46,030 --> 01:02:51,350
+والقوة فيها مرتفعة يعني يهمني نسبة الـ strength
+
+684
+01:02:51,350 --> 01:02:56,870
+للوزن بتطلعش على الـ strength لحالة أو الوزن يهمني
+
+685
+01:02:56,870 --> 01:02:57,450
+الـ ratio
+
+686
+01:03:00,400 --> 01:03:07,040
+في أي سؤال؟ هيكم خلصنا الـ chapter اثنين تقريبًا معظم
+
+687
+01:03:07,040 --> 01:03:14,660
+المرة عليكم المحاضرة
+
+688
+01:03:14,660 --> 01:03:20,150
+الجاي هنبدأ في chapter ثلاثة اللي هو هنبدأ اللي هو
+
+689
+01:03:20,150 --> 01:03:24,270
+يعني مراجعة مع بعض تفصيل للـ mechanics وال
+
+690
+01:03:24,270 --> 01:03:28,490
+material، يعني الـ chapter ثلاثة وأربعة هيكون تحضير لخمسة
+
+691
+01:03:28,490 --> 01:03:31,010
+و ستة وسبعة، أعطيكم العافية
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/i3VwDY5UAc0_raw.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/i3VwDY5UAc0_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..bcc95102e3001632b0d3157bc344b4ae1c2df5d4
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/i3VwDY5UAc0_raw.srt
@@ -0,0 +1,2764 @@
+1
+00:00:05,420 --> 00:00:08,360
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,360 --> 00:00:12,680
+وبركاته اليوم هنبدأ المحاضرة التانية اللى هتكون
+
+3
+00:00:12,680 --> 00:00:16,660
+مراجعة لعلم ال material science مش كل شيء طبعا
+
+4
+00:00:16,660 --> 00:00:21,120
+الشغلات الأساسية اللى هتنزلنا في مادة تصميم الألات
+
+5
+00:00:21,120 --> 00:00:26,580
+في البداية احنا في ال material science عملنا اللى
+
+6
+00:00:26,580 --> 00:00:31,640
+هو ما يسمى ال standard tensile testفحص الشد كان
+
+7
+00:00:31,640 --> 00:00:36,540
+الهدف أننا نتعرف على الخواص الميكانيكية للمواد
+
+8
+00:00:36,540 --> 00:00:43,250
+وكان تركيزنا على المعدن، كنا نحضر عينة معياريةلها
+
+9
+00:00:43,250 --> 00:00:49,750
+مقطعتها مدور لها gauge length و gauge diameter و
+
+10
+00:00:49,750 --> 00:00:54,570
+عند الأطراف بيصير أطرافها دي لمسك العينة يتم
+
+11
+00:00:54,570 --> 00:00:58,910
+العينة تحت تأثير load محوري و كنا نحسس بال
+
+12
+00:00:58,910 --> 00:01:01,990
+engineering stress sigma بسوة P على A node و
+
+13
+00:01:01,990 --> 00:01:05,990
+engineering strain delta L على L node او L minus L
+
+14
+00:01:05,990 --> 00:01:12,350
+node على L nodeبعدين عملنا plot لل stress-strain
+
+15
+00:01:12,350 --> 00:01:17,170
+curve في عندي على المحور الأفقي ال strain ع المحور
+
+16
+00:01:17,170 --> 00:01:22,870
+الرأسي ال stress حصلنا على ما يسمى اللي هو stress
+
+17
+00:01:22,870 --> 00:01:27,350
+-strain curve في نقاط مهمة انها كانت ال
+
+18
+00:01:27,350 --> 00:01:31,450
+proportional limit هي ال proportional limit نهاية
+
+19
+00:01:31,450 --> 00:01:34,590
+الفترة اللي بتكون علاقة بال stress و ال strain
+
+20
+00:01:34,590 --> 00:01:41,210
+خطيةو ال elastic limit هي ال stress level below
+
+21
+00:01:41,210 --> 00:01:44,310
+which مش هكون دي permanent deformation يعني إذا
+
+22
+00:01:44,310 --> 00:01:51,130
+نزلت ال load هترجع العينة للصفر عرفنا ال point two
+
+23
+00:01:51,130 --> 00:01:59,150
+percent yield strength اللي هوSY عند ال ultimate
+
+24
+00:01:59,150 --> 00:02:04,770
+tensile strength و عند ال fracture stress طبعا
+
+25
+00:02:04,770 --> 00:02:09,170
+واضح ان هاد ال ductile material و هاد ال brittle
+
+26
+00:02:09,170 --> 00:02:12,010
+material ال ductile material بيصير فيها plastic
+
+27
+00:02:12,010 --> 00:02:16,170
+deformation كتير لحد الكثر ال brittle material
+
+28
+00:02:16,170 --> 00:02:19,550
+كمية ال plastic deformation بيصير فيها قليلة جدا
+
+29
+00:02:19,550 --> 00:02:20,750
+تكتر بسرعة معاه
+
+30
+00:02:26,810 --> 00:02:31,070
+طبعا في المنطقة هذا بيسميه linear elastic material
+
+31
+00:02:31,070 --> 00:02:35,050
+في المنطقة الخطية اللي علاقة كانت بال stress و ال
+
+32
+00:02:35,050 --> 00:02:37,590
+engineering stress و ال engineering strain سيجما
+
+33
+00:02:37,590 --> 00:02:43,710
+بساوي E capital في أبسلون ال E capital هي ال
+
+34
+00:02:43,710 --> 00:02:47,690
+modulus of elasticity في كتب اسمها young's modulus
+
+35
+00:02:47,690 --> 00:02:53,650
+هي بتعبر عن زنبراكية زنبراكية الماد how stiff is
+
+36
+00:02:53,650 --> 00:02:54,370
+the material
+
+37
+00:02:57,460 --> 00:03:02,640
+عادة ال E capital بتعتمدش على المعالجات الحرارية
+
+38
+00:03:02,640 --> 00:03:08,160
+او المحتوى الكربوني او المحتوى التسبيكي للحديد ال
+
+39
+00:03:08,160 --> 00:03:16,240
+E تقريبا بتكون ثابتة لكل او لمعظم سبائك الحديد
+
+40
+00:03:16,240 --> 00:03:21,020
+طبعا
+
+41
+00:03:21,020 --> 00:03:25,290
+هذا ال engineering stress strain curveفى تحت ال
+
+42
+00:03:25,290 --> 00:03:28,090
+true stress strain curve كنا نحسب ال true stress
+
+43
+00:03:28,090 --> 00:03:35,410
+sigma sigma true بستوى القوة اللحظية على المقطع
+
+44
+00:03:35,410 --> 00:03:43,290
+اللحظى F على A I اللحظى و ال epsilon اللى هو تكامل
+
+45
+00:03:43,290 --> 00:03:51,110
+DL على L من L mod لL اللى هو بستوى L L على L mod
+
+46
+00:03:54,310 --> 00:03:57,450
+التحت هو لل true stress strain care لل true stress
+
+47
+00:03:57,450 --> 00:04:00,650
+strain care كان لزمنا في ال .. مش في ال design بل
+
+48
+00:04:00,650 --> 00:04:04,050
+لزمنا في ال manufacturing كان في علاقة بين لل true
+
+49
+00:04:04,050 --> 00:04:10,850
+stress و لل true strain من خلال علاقة K أبسلون
+
+50
+00:04:10,850 --> 00:04:20,590
+true to the power N for
+
+51
+00:04:20,590 --> 00:04:25,990
+ductile materialsبيكون ال ultimate strength in
+
+52
+00:04:25,990 --> 00:04:30,830
+compression بيستوى ال ultimate strength in tension
+
+53
+00:04:30,830 --> 00:04:35,050
+لكن في حالة ال brittle materials زي البطون ال
+
+54
+00:04:35,050 --> 00:04:38,070
+ultimate strength in compression بيكون أكبر بكتير
+
+55
+00:04:38,070 --> 00:04:44,590
+من ال ultimate strength in tension في
+
+56
+00:04:44,590 --> 00:04:48,490
+ال torrent strength القوة المعاكسة القوة اللي اللي
+
+57
+00:04:48,490 --> 00:04:54,570
+قوة معاكسة الليهذا الـ torsional strength يتم
+
+58
+00:04:54,570 --> 00:04:59,250
+حسابها أو إيجادها باستخدام عينات مقطعها مدورة
+
+59
+00:04:59,250 --> 00:05:02,790
+بعملها لحد مصير الـ plastic deformation لحد مصير
+
+60
+00:05:02,790 --> 00:05:06,730
+الـ plastic deformation ب .. هذه هي ال ultimate ال
+
+61
+00:05:06,730 --> 00:05:14,470
+.. torsional strength TAU maximum TAU
+
+62
+00:05:14,470 --> 00:05:17,910
+في ال mechanics ال material بشكل عام في حالة ال
+
+63
+00:05:17,910 --> 00:05:26,250
+torsion سواء TR على Jطبعا في علاقة بين ال tau و ال
+
+64
+00:05:26,250 --> 00:05:29,110
+angle و ال twist يعني انا اناسكه من طرف و اعمل
+
+65
+00:05:29,110 --> 00:05:34,510
+twisting بيصير في عنده rotation اللي هي ال angle و
+
+66
+00:05:34,510 --> 00:05:34,830
+ال twist
+
+67
+00:05:37,670 --> 00:05:43,410
+لينيار تاو ماكسوم بيستوى GR على L node في theta ال
+
+68
+00:05:43,410 --> 00:05:46,370
+G اللي هي ال shear modulus او ال modulus of
+
+69
+00:05:46,370 --> 00:05:50,230
+rigidity ال theta ال angle twist بوحدة ال radians
+
+70
+00:05:50,230 --> 00:05:57,650
+و ال L node اللي هو ال gauge length ال
+
+71
+00:05:57,650 --> 00:06:00,870
+gauge
+
+72
+00:06:00,870 --> 00:06:05,670
+length انا
+
+73
+00:06:05,670 --> 00:06:06,630
+لما امسك العينة
+
+74
+00:06:12,700 --> 00:06:20,940
+بتكون من الطرف المسوقة و
+
+75
+00:06:20,940 --> 00:06:28,660
+انا ببقى بقى عليها ايش؟ torque مش كل الطول من
+
+76
+00:06:28,660 --> 00:06:31,100
+منطقة ال application لو اتفرض ال application بتاع
+
+77
+00:06:31,100 --> 00:06:37,780
+ترك بدأ من هنا يعني هذه هي ال gauge length لو
+
+78
+00:06:37,780 --> 00:06:41,970
+كنت مسكت من هنا بتكون هذه هي ال gauge lengthهسمون
+
+79
+00:06:41,970 --> 00:06:45,750
+انا ماسك ال
+
+80
+00:06:45,750 --> 00:06:52,450
+maximum
+
+81
+00:06:52,450 --> 00:06:58,330
+shear في حالة ال torsion بيكون على ال shear
+
+82
+00:06:58,330 --> 00:07:06,630
+distribution هذا
+
+83
+00:07:06,630 --> 00:07:10,710
+ال tau max هذا ال radius
+
+84
+00:07:13,330 --> 00:07:20,030
+تاو ماكس بيساوي ال torque في ال radius على ال
+
+85
+00:07:20,030 --> 00:07:23,750
+polar moment of inertia ال polar moment of inertia
+
+86
+00:07:23,750 --> 00:07:34,730
+بيساوي باي على اتنين و تلاتين باي دي تكيب او
+
+87
+00:07:34,730 --> 00:07:40,770
+بيساوي نص ماهي دي بيساوياش ا على اتنينيعني هصير
+
+88
+00:07:40,770 --> 00:07:48,750
+ستاش وصير نص by R تربيع يعني لو عوضنا بيصير تو
+
+89
+00:07:48,750 --> 00:08:05,590
+ماكس ت ر على نص by R square ارس اربعة هتكون
+
+90
+00:08:05,590 --> 00:08:20,140
+سوى اتنين ت على باىأو تكيب فين
+
+91
+00:08:20,140 --> 00:08:23,340
+ال yield؟ ال yield is the torsion strength هي ال
+
+92
+00:08:23,340 --> 00:08:29,460
+maximum shear stress اللي عندها بدخل .. بيصير عند
+
+93
+00:08:29,460 --> 00:08:34,720
+ال .. ال .. ال .. ال .. العلاقة مش linear يعني لما
+
+94
+00:08:34,720 --> 00:08:39,860
+أنا ألف بيكون تقريبا خط مستقيم بيصير curvedفهذه
+
+95
+00:08:39,860 --> 00:08:41,860
+باسمها ال yield strength او لما ادخل ال plastic
+
+96
+00:08:41,860 --> 00:08:45,300
+deformation ال modulus of rupture هو ال maximum
+
+97
+00:08:45,300 --> 00:08:49,980
+point on torque twist diagram انا برضه برسم torque
+
+98
+00:08:49,980 --> 00:08:59,740
+twist diagram برسم torque مع ال theta هذه
+
+99
+00:08:59,740 --> 00:09:01,740
+اللي هي SSU
+
+100
+00:09:13,920 --> 00:09:18,580
+ال Resilience هي
+
+101
+00:09:18,580 --> 00:09:24,860
+قدرة المادة على انتصاص ال energy within the
+
+102
+00:09:24,860 --> 00:09:30,540
+elastic range يعني هاي ال stress-strain curve، هاي
+
+103
+00:09:30,540 --> 00:09:35,420
+strain، هاي stress وهذا ال curve منطق ال elastic
+
+104
+00:09:35,420 --> 00:09:41,180
+regionلو عملت unloading عند ال elastic limit برجع
+
+105
+00:09:41,180 --> 00:09:45,520
+للصفر مافيش عنده plastic deformation ال resilience
+
+106
+00:09:45,520 --> 00:09:50,900
+هو الطاقة الممتصة من العينة طاقة ممتصة من العينة
+
+107
+00:09:50,900 --> 00:09:54,980
+في فترة ال elastic region في ال elastic region هذا
+
+108
+00:09:54,980 --> 00:10:00,060
+يتمثل ال resilience كل ما زيد ال resilience كل ما
+
+109
+00:10:00,060 --> 00:10:05,360
+كان عند المادة قدرة أنها تمشي في elastic region
+
+110
+00:10:05,360 --> 00:10:06,640
+أكبر مدى ممكن
+
+111
+00:10:09,830 --> 00:10:20,770
+يعني احنا فاكرين ان هي هتكون المساحة هادئة و
+
+112
+00:10:20,770 --> 00:10:27,930
+قربنا المساحة المثلث ال modulus of resilience صار
+
+113
+00:10:27,930 --> 00:10:32,750
+نص مساحة القاعدة اللي هي epsilon yield
+
+114
+00:10:37,130 --> 00:10:43,090
+في الـ sigma yield وحكينا تقريبا ال sigma سوى E في
+
+115
+00:10:43,090 --> 00:10:51,830
+أبسر ال yield ووصلنا للعلاقة هذه ال
+
+116
+00:10:51,830 --> 00:10:57,370
+modulus of resilience تقريبا سوى أسوأ تربيع على 2E
+
+117
+00:10:57,370 --> 00:11:01,770
+الأسوأ هي ال yield strength وال E ال modulus of
+
+118
+00:11:01,770 --> 00:11:02,270
+elasticity
+
+119
+00:11:08,010 --> 00:11:10,810
+for two materials with the same yield strength لما
+
+120
+00:11:10,810 --> 00:11:13,910
+دي two يعني لهم نفس ال yield strength the less
+
+121
+00:11:13,910 --> 00:11:17,430
+stiff material has a greater greater resilience
+
+122
+00:11:17,430 --> 00:11:26,810
+less stiff يعني هاي material وهاي
+
+123
+00:11:26,810 --> 00:11:31,770
+هاي
+
+124
+00:11:31,770 --> 00:11:38,220
+ال material one هاي ال material twoمن ال E أعلى؟
+
+125
+00:11:38,220 --> 00:11:45,780
+واحد ولا اتنين؟ واحد E واحد أعلى من E اتنين لأن ال
+
+126
+00:11:45,780 --> 00:11:51,660
+E بتمثل ال slope صح؟ واضح ال slope هنا أعلى من هنا
+
+127
+00:11:51,660 --> 00:11:59,600
+إذا كان لهم تقريبا نفس ال yield strength بتكون
+
+128
+00:11:59,600 --> 00:12:05,720
+ال modulus of resilience اتنين أكبر من واحد صحيح
+
+129
+00:12:09,230 --> 00:12:13,370
+ال toughness هي كمية الطاقة اللى تمتصها العينة
+
+130
+00:12:13,370 --> 00:12:19,530
+خلال الفحص لحد الكثرة ال toughness هي كمية الطاقة
+
+131
+00:12:19,530 --> 00:12:28,670
+اللى تمتصها العينة خلال الفحص لحد الكثرة تقريبا
+
+132
+00:12:28,670 --> 00:12:31,370
+نحكي هنا ال modulus of result او ال modulus اللى
+
+133
+00:12:31,370 --> 00:12:36,940
+هو ال toughnessبتساوي SY زي SUT على اتنين في
+
+134
+00:12:36,940 --> 00:12:40,600
+الابسلون F الابسلون F هو ال strain at fracture
+
+135
+00:12:40,600 --> 00:12:56,380
+الابسلون F هو ال strain at fracture الان
+
+136
+00:12:56,380 --> 00:13:00,980
+هنتطلع على statistical significance of material
+
+137
+00:13:00,980 --> 00:13:06,420
+propertiesطبعا strength values are obtained from
+
+138
+00:13:06,420 --> 00:13:10,000
+testing many nominally identical specimens عشان
+
+139
+00:13:10,000 --> 00:13:13,700
+أحصى ال strength values بيعملش بيعملوش فحص شد واحد
+
+140
+00:13:13,700 --> 00:13:19,240
+مثلا بيعمله مية فحص باخد بيانات للعديد من الفحصات
+
+141
+00:13:19,240 --> 00:13:24,060
+بعدين بيعمل statistical analysis عشان يجيب اللي هو
+
+142
+00:13:24,060 --> 00:13:25,960
+ال main strength
+
+143
+00:13:27,820 --> 00:13:33,540
+عشان تجيب ال standard deviation و distribution لل
+
+144
+00:13:33,540 --> 00:13:38,840
+strength وبالتالي
+
+145
+00:13:38,840 --> 00:13:45,160
+ال strength لها distribution وبالتالي it has its
+
+146
+00:13:45,160 --> 00:13:50,680
+statistical nature تشوف
+
+147
+00:13:50,680 --> 00:13:51,180
+مثال
+
+148
+00:14:00,170 --> 00:14:08,030
+في عند حديد عشرة عشرين steel رقم عشرة عشرين عشرة
+
+149
+00:14:08,030 --> 00:14:13,530
+هي نسبة الكربون هذا العشرة يعني plan carbon steel
+
+150
+00:14:13,530 --> 00:14:17,430
+plan يعني حديد سادة يعني مافيش فيه أنصار أخرى
+
+151
+00:14:17,430 --> 00:14:20,550
+مافيش فيه مثلا مانجانيز مافيش فيه فنادم مافيش فيه
+
+152
+00:14:20,550 --> 00:14:24,970
+مغنيسوم مافيش فيه فسفور بس حديد و كربون كربون سادة
+
+153
+00:14:24,970 --> 00:14:30,230
+plan carbon steel نسبة الكربون فيهzero point two
+
+154
+00:14:30,230 --> 00:14:36,910
+في المية يعني هذه مقصومة على مية يعني هتكون zero
+
+155
+00:14:36,910 --> 00:14:43,190
+point two percent ال carbon فيها ان عملت الف عينة
+
+156
+00:14:43,190 --> 00:14:49,650
+تم فحص الف عينة و لكل عينة انعمل ال stress strain
+
+157
+00:14:49,650 --> 00:14:57,300
+curve و من ال stress strain curveطلعنا اللى هو ال
+
+158
+00:14:57,300 --> 00:15:02,660
+tensile stress طلع
+
+159
+00:15:02,660 --> 00:15:07,440
+عندى عينتين انا عند المجموع العينات عند عينتين
+
+160
+00:15:07,440 --> 00:15:11,540
+كانت ال strength اللى هى ستة و خمسين و نص كيلو
+
+161
+00:15:11,540 --> 00:15:15,840
+pound per square inch طمنتاشر عينة سبعة و خمسين و
+
+162
+00:15:15,840 --> 00:15:19,960
+نص تلاتة و عينة تمانية و خمسين و نص واحدة و تلاتين
+
+163
+00:15:19,960 --> 00:15:25,850
+عينة تسعة و خمسين و نصمية واحد و خمسين عينا تلاش
+
+164
+00:15:25,850 --> 00:15:29,590
+ستين و نص تسعة و اربع عينا سبعة و ستين و نص اربع
+
+165
+00:15:29,590 --> 00:15:33,330
+عينات سبعين و نص عينتين و واحد سبعين point five
+
+166
+00:15:33,330 --> 00:15:38,810
+هذه البيانات اللي طلت معايا في التجربة how to
+
+167
+00:15:38,810 --> 00:15:43,010
+characterize this material خليني اشوف ال example
+
+168
+00:15:43,010 --> 00:15:51,010
+انا عامله على ال Excel العمود الأول بورجيني قيمة
+
+169
+00:15:51,010 --> 00:15:55,880
+strength احنا كان عندنا الفحصو العمود التاني مثل
+
+170
+00:15:55,880 --> 00:16:01,980
+اتكرار للنتيجة ال frequency يعني عندي عينتين جابول
+
+171
+00:16:01,980 --> 00:16:05,300
+ال strength ستة و خمسين و نص عندي تلانتاشر عينة
+
+172
+00:16:05,300 --> 00:16:09,930
+جابول ال strength سبعة و خمسين و نصمثلا مية وتسعة
+
+173
+00:16:09,930 --> 00:16:14,290
+عينا جابولي strength واحد ستين ونص مية وتلاتين
+
+174
+00:16:14,290 --> 00:16:18,130
+عينا جابولي خمس ستين ونص تسعة واربعين عينا جابولي
+
+175
+00:16:18,130 --> 00:16:22,390
+سبعة ستين ونص اربع عينا جابولي سبعين ونص عينتين
+
+176
+00:16:22,390 --> 00:16:26,130
+جابولي واحد سبعين ونص المجموع الف حصات كلها الف
+
+177
+00:16:26,130 --> 00:16:31,730
+لما ندرجع الأرقام هذه تعطينا الف عينا عشان ت
+
+178
+00:16:31,730 --> 00:16:38,050
+characterize لازم احسب اول شي ايش ال mean valueالـ
+
+179
+00:16:38,050 --> 00:16:45,550
+mean value ايش هتساوي الان بنفعش احكي ال mean
+
+180
+00:16:45,550 --> 00:16:50,890
+value ال average اجمعه و اقسم عليه على العدد لأ كل
+
+181
+00:16:50,890 --> 00:16:54,080
+واحدة بده اضرب في ال way تاعتها يعني عندي هنااللي
+
+182
+00:16:54,080 --> 00:16:57,640
+هو ال frequency في ال strength يعني انديهين اتنين
+
+183
+00:16:57,640 --> 00:17:01,680
+في ستة و خمسية و نص مية و تلتاش طبعا تاشر سبعة و
+
+184
+00:17:01,680 --> 00:17:04,860
+خمسية و نص مية الف و خمس اتفانين بعدين بجمع ال
+
+185
+00:17:04,860 --> 00:17:09,680
+weights كلها بجمع ال weights كلها ال X average زي
+
+186
+00:17:09,680 --> 00:17:16,600
+ما انتش فيه بتساوي واحد على N ال summation لل FI
+
+187
+00:17:16,600 --> 00:17:24,300
+XI ال FI اللي هو تكرارللقراءة اللي قيمتها إيش xi
+
+188
+00:17:24,300 --> 00:17:34,840
+يعني هيكون عندى هتكون f1 في x1 زياد f2 في x2 زياد
+
+189
+00:17:34,840 --> 00:17:41,660
+f3 x3 و هكذا اللي أنا عندى أكم هتكون ألف يعني يعني
+
+190
+00:17:41,660 --> 00:17:47,600
+الرقم هذا الرقم هذا بأقسم على إيش هذا الرقم بساوي
+
+191
+00:17:47,600 --> 00:17:50,280
+ال summation لل fi xi يعني هتكون عندى
+
+192
+00:17:56,660 --> 00:18:00,900
+الصماش لل FI
+
+193
+00:18:00,900 --> 00:18:06,320
+XI من ال excel sheet طالع لي تلات ستين ألف و ستمية
+
+194
+00:18:06,320 --> 00:18:11,200
+و خمسة و عشرين تلات ستين ألف و ستمية و خمسة و
+
+195
+00:18:11,200 --> 00:18:19,470
+عشرين معناته ال X mean هتكون واحد على Nالصممش لل
+
+196
+00:18:19,470 --> 00:18:30,910
+FI XI I من واحد لان او
+
+197
+00:18:30,910 --> 00:18:38,770
+مش واحد لان اي اي مختلفة مش واحد لالف ده خليها N
+
+198
+00:18:38,770 --> 00:18:43,210
+small الصممش كان لدي تلات ستين الف وستمية وخمسة
+
+199
+00:18:43,210 --> 00:18:48,010
+وعشرين الان capital الفيعني بيطلع ال average عندي
+
+200
+00:18:48,010 --> 00:18:53,370
+تلات ستين بون ستة اتنين خمسة kilo pound per square
+
+201
+00:18:53,370 --> 00:18:59,450
+inch طيب
+
+202
+00:18:59,450 --> 00:19:10,870
+البيانات هذه تمثل sample ولا population؟ ايش عن ال
+
+203
+00:19:10,870 --> 00:19:15,880
+population؟ و ايش عن ال sample؟السبب اللي عين
+
+204
+00:19:15,880 --> 00:19:22,640
+واحدة انه يعني مثلا لو أنا درست مرضى السكر كل
+
+205
+00:19:22,640 --> 00:19:27,540
+المصابين بالسكر في قطاع غزة أخدت فحص السكر لكل
+
+206
+00:19:27,540 --> 00:19:32,420
+مرضى السكر في قطاع غزة population طب أنا هالمنطقة
+
+207
+00:19:32,420 --> 00:19:38,590
+أو عملي أنه أفحص كل قطاع غزةباخد sample يعني سنة
+
+208
+00:19:38,590 --> 00:19:42,590
+كده انا فيها عندى سلة بيكون فيها كل إشي بكبش منها
+
+209
+00:19:42,590 --> 00:19:47,050
+ال capture هذه هي إيش ال sample العينات نقطة واحدة
+
+210
+00:19:47,050 --> 00:19:52,910
+بس ال sample بتكون مجموعة عينات ف ال standard
+
+211
+00:19:52,910 --> 00:19:58,430
+deviation في حالة إذا الأرقام بتاعتها based on
+
+212
+00:19:58,430 --> 00:20:04,800
+sample تُعطى بالعلاقة هذهاللي هي ال standard
+
+213
+00:20:04,800 --> 00:20:08,240
+ratios أو جزر التربيع اللي اصمش ال FI XI تربيع
+
+214
+00:20:08,240 --> 00:20:12,500
+minus N capital في X mean تربيع على N minus واحد
+
+215
+00:20:12,500 --> 00:20:16,340
+وعندما انا اتو في الجدول هتبالذبني احسب ال XI
+
+216
+00:20:16,340 --> 00:20:21,460
+تربيع FI يعني حضره بحكي ستة و خمسين و نص تربيع في
+
+217
+00:20:21,460 --> 00:20:27,960
+اتنين و سبعة و خمسين و نص تربيع في تمانتاش و
+
+218
+00:20:27,960 --> 00:20:32,000
+تمانية و خمسية و نص تربيع في تلاتة و عشرينو تسعة
+
+219
+00:20:32,000 --> 00:20:34,720
+خمسين و نص تربيع في واحد تلاتين بحصل على العمود
+
+220
+00:20:34,720 --> 00:20:38,860
+هذا بعدين بيكون عندي ايش ال summation معناه ان
+
+221
+00:20:38,860 --> 00:20:45,780
+عندي ال standard deviation SX بالساوية
+
+222
+00:20:45,780 --> 00:20:55,940
+اللي هي جزر التربيع ل summation لل FI XI تربيع ال
+
+223
+00:20:55,940 --> 00:21:03,580
+I من واحد ل Kأو N small minus N capital X mean
+
+224
+00:21:03,580 --> 00:21:12,860
+تربيع على N minus واحدة ال summation لل FI XI
+
+225
+00:21:12,860 --> 00:21:15,680
+تربيع اللي هي هذه ال summation اللي هي أربعمية و
+
+226
+00:21:15,680 --> 00:21:23,340
+خمس ألف أربعمية و خمس ألف هزة و جزر تربيعاربعمية
+
+227
+00:21:23,340 --> 00:21:33,660
+او خمس الف او اربع مليون اربع خمسين تمانية
+
+228
+00:21:33,660 --> 00:21:37,460
+ستة اربعة minus
+
+229
+00:21:37,460 --> 00:21:44,520
+N اللي هي الف في ال X اللي هي مين اللي هي تلات
+
+230
+00:21:44,520 --> 00:21:48,540
+ستين تلات
+
+231
+00:21:48,540 --> 00:21:52,730
+ستين ستمية وخمس عشرينممكن اعتبر القانون اغيره
+
+232
+00:21:52,730 --> 00:22:01,310
+اعتبره يساوي جزر التربيع لل summation fi xi تربية
+
+233
+00:22:01,310 --> 00:22:11,630
+I equal واحد ل K minus ال summation لل fi xi على N
+
+234
+00:22:11,630 --> 00:22:13,270
+minus واحد
+
+235
+00:22:16,400 --> 00:22:21,100
+لنقضه بانت ال X average اللي هي تلستي و ستين و
+
+236
+00:22:21,100 --> 00:22:29,420
+خمسة في الان بتعطيني ايش؟ الرقم هذه صح؟ يعني هكون
+
+237
+00:22:29,420 --> 00:22:34,080
+جزر التربيه للاربع
+
+238
+00:22:34,080 --> 00:22:39,220
+سفر خمسة اربع تمانية ستة اربع معينة ستلات ستين
+
+239
+00:22:39,220 --> 00:22:42,460
+ستمائية خمسة و عشرين على الف نقصه على تسعمائة
+
+240
+00:22:42,460 --> 00:22:46,260
+وتسعة تسعينبطلع ال standard deviation دي اتنين
+
+241
+00:22:46,260 --> 00:22:54,920
+point خمسة تسعة اربعة kilo pound per square inch
+
+242
+00:22:54,920 --> 00:23:05,480
+نعم
+
+243
+00:23:05,480 --> 00:23:10,720
+ال main value main side string square
+
+244
+00:23:16,320 --> 00:23:22,360
+هذا كل قيمة اللي هو ال frequency واحد تكرار رقم
+
+245
+00:23:22,360 --> 00:23:26,580
+واحد في القيمة واحد تربيع زاد ال frequency اتنين
+
+246
+00:23:26,580 --> 00:23:30,660
+في القيمة اتنين تربيع
+
+247
+00:23:30,660 --> 00:23:36,800
+اه صحيح معناه تهيأك صحيح كلامك هذا صحيح minus الف
+
+248
+00:23:38,700 --> 00:23:43,980
+انا اسف فى تلت ستين point اتنين خمسة ستة اتنين
+
+249
+00:23:43,980 --> 00:23:52,880
+خمسة تربيع صحيح فى خطأ كان لأن
+
+250
+00:23:52,880 --> 00:23:56,260
+الصورة اللى هى دى X تربيع لكن لو N فى X كان كلام
+
+251
+00:23:56,260 --> 00:24:00,300
+اللى حكيته صح فهى كان صح فبطلع ال standard
+
+252
+00:24:00,300 --> 00:24:04,440
+deviation قيمته اتنين point خمسة تسعة اربعة الان
+
+253
+00:24:04,440 --> 00:24:05,560
+لما نعيش نعمل ال plot
+
+254
+00:24:08,280 --> 00:24:12,760
+لما نهاجر نعمل plot ممكن
+
+255
+00:24:12,760 --> 00:24:19,940
+نعمل plot على مستويين ممكن
+
+256
+00:24:19,940 --> 00:24:26,200
+نعمل histogram histogram
+
+257
+00:24:26,200 --> 00:24:36,700
+انا حكيت عندي انا التوزيع كانتحطت ال frequency حطت
+
+258
+00:24:36,700 --> 00:24:44,120
+ال frequency وحطت القيم عند
+
+259
+00:24:44,120 --> 00:24:49,740
+هنا احنا
+
+260
+00:24:49,740 --> 00:24:57,860
+بدنا ستة خمسين و نص ستة خمسين و نص سبعة
+
+261
+00:24:57,860 --> 00:25:02,280
+خمسين و نص تمانية خمسين و نص كنا نزود واحدتسعة
+
+262
+00:25:02,280 --> 00:25:05,680
+خمسية و نص ستة و نص واحد ستة و نص اتنين و ستة و نص
+
+263
+00:25:05,680 --> 00:25:08,920
+تلات ستة و نص اربع ستة و نص خمسية و نص اللي كل
+
+264
+00:25:08,920 --> 00:25:11,400
+واحدة عارف انا اتكررها ماذا ستة و خمسية و نص كانت
+
+265
+00:25:11,400 --> 00:25:18,380
+تكرار عندي اتنين اتنين من اكم من الف معناته ماخدة
+
+266
+00:25:18,380 --> 00:25:24,400
+point oh two اللي هي ماخدة point oh two من ايش
+
+267
+00:25:24,400 --> 00:25:29,300
+point oh oh two من الالف القراءة التانية كانت اذا
+
+268
+00:25:29,300 --> 00:25:33,050
+تفكرين ماخدة اظن تمانتاشطمنتاش طمنتاش على الف
+
+269
+00:25:33,050 --> 00:25:44,110
+القراءة التالتة نرجع لل Excel القراءة
+
+270
+00:25:44,110 --> 00:25:47,590
+العلماء ده اللي هي اتنين يعني ال observed
+
+271
+00:25:47,590 --> 00:25:51,550
+probability density function اللي هي اتنين على الف
+
+272
+00:25:51,550 --> 00:25:57,530
+هاي عندك اتنين على الف هذه طمنتاش على الف هذه
+
+273
+00:25:57,530 --> 00:26:02,370
+تلاتة عشرين على الفواحد تلاتية على ألف تلاتة على
+
+274
+00:26:02,370 --> 00:26:07,110
+ألف و هكذا اللي
+
+275
+00:26:07,110 --> 00:26:17,970
+بسوي بحكي
+
+276
+00:26:17,970 --> 00:26:23,350
+الله هاي الستة خمسين و نص هاي السبعة خمسين و نص
+
+277
+00:26:26,160 --> 00:26:34,980
+هي تمانية و خمسين و نص و هكذا عدد
+
+278
+00:26:34,980 --> 00:26:39,340
+القراءات اللي ماخدين ستة و خمسين و نص اتنين يعني
+
+279
+00:26:39,340 --> 00:26:42,200
+point او اتنين لما اجمع هدول ايه كم بيطلع مجموعهم
+
+280
+00:26:42,200 --> 00:26:52,500
+واحد فعندي هتكون هاي هذه ماخدة اتنين التانية ماخدة
+
+281
+00:26:52,500 --> 00:26:54,720
+طبنتاش
+
+282
+00:27:02,380 --> 00:27:11,640
+فبطلع عندى ما يسمى histogram بطلع
+
+283
+00:27:11,640 --> 00:27:17,560
+ما يسمى عندى ايش histogram ال
+
+284
+00:27:17,560 --> 00:27:22,140
+histogram بيبينى التوزيع القراءات كيفش هي موزعة
+
+285
+00:27:22,140 --> 00:27:30,600
+القراءات او كثافة التوزيع واضح لو نطلع هناعندي
+
+286
+00:27:30,600 --> 00:27:40,360
+بيزيد point 02 اكتر ايش عندى 151 هنا اللي هي عند
+
+287
+00:27:40,360 --> 00:27:48,560
+63.5 كانت ايش ال maximum اكبر مصيب هذا بيسمي ال
+
+288
+00:27:48,560 --> 00:27:51,900
+histogram ال histogram لو عملت plot على القنة
+
+289
+00:27:51,900 --> 00:27:56,500
+بيطلع
+
+290
+00:27:56,500 --> 00:27:57,800
+معسم عندى اللي هي normal
+
+291
+00:28:01,520 --> 00:28:07,720
+النورمال ديستربيوشن والجاوس ديستربيوشن النورمال
+
+292
+00:28:07,720 --> 00:28:17,720
+ديستربيوشن هو اطابر علاقة اللي هي دي F of X اللي
+
+293
+00:28:17,720 --> 00:28:22,940
+هو ال property density function واحد على سيجما X
+
+294
+00:28:22,940 --> 00:28:32,390
+جزر التربية يعنيلتنين باي ال exponential ل minus
+
+295
+00:28:32,390 --> 00:28:47,550
+نص في X minus ميو على سيجما X نعم
+
+296
+00:28:47,550 --> 00:28:53,450
+هنحط ميو X يعني كتير ميو X يعني و Y وين ميو X لأ
+
+297
+00:28:53,450 --> 00:28:58,480
+هو X يعني القراعميو اكس ميو اكس هده ايش هي ال main
+
+298
+00:28:58,480 --> 00:29:07,540
+value ميو اكس هي ال X mean الميو value السيجما X
+
+299
+00:29:07,540 --> 00:29:11,760
+هي ال standard deviation لان بعوضا على سيجما X انا
+
+300
+00:29:11,760 --> 00:29:15,920
+حسبت ال standard deviation already 2.594 والميو
+
+301
+00:29:15,920 --> 00:29:22,840
+حسبتها اللي هي 63.625 63.625 بعوضا هنا هنا
+
+302
+00:29:26,780 --> 00:29:33,240
+صارت ال density function is a function only of X
+
+303
+00:29:33,240 --> 00:29:41,280
+لو اقعد X مثلا ستين هيعطيني قراءة هقعد مثلا سبعين
+
+304
+00:29:41,280 --> 00:29:44,940
+هيعطيني قراءة فبحصل على ال curve هذا اللي هو
+
+305
+00:29:44,940 --> 00:29:51,360
+probability density function الآن
+
+306
+00:30:05,390 --> 00:30:10,530
+طبعا انتوا انا بفترض انكوا هذا الاشي بتعرفوه انا
+
+307
+00:30:10,530 --> 00:30:13,030
+ماعطيش أكتر كامة للموضوع هذا في ال .. في ال
+
+308
+00:30:13,030 --> 00:30:20,090
+measurement فهذا f of x اللي طلع معايا هذي x main
+
+309
+00:30:20,090 --> 00:30:25,630
+هذا x main طبعا
+
+310
+00:30:31,970 --> 00:30:36,270
+ممكن ابعد عشان غطى تقريب معظم ال data هذه تكون
+
+311
+00:30:36,270 --> 00:30:51,290
+تقريبا تلاتة sigma وهنا تكون تلاتة sigma فال
+
+312
+00:30:51,290 --> 00:30:54,990
+product density function لل data بتاعتناطلعت
+
+313
+00:30:54,990 --> 00:30:58,130
+بالشكل هذا f of x هو واحد ع point اتنين خمس أربع
+
+314
+00:30:58,130 --> 00:31:02,930
+هذا ال standard deviation وهذا ايش ال X mean ال
+
+315
+00:31:02,930 --> 00:31:08,130
+main value بعبر
+
+316
+00:31:08,130 --> 00:31:15,070
+عنها ال SUT ال
+
+317
+00:31:15,070 --> 00:31:22,070
+SUT N معناه is normally distributed function ال
+
+318
+00:31:22,070 --> 00:31:26,840
+mean تعوتلات ستين point ست اتنين و ال standard
+
+319
+00:31:26,840 --> 00:31:30,220
+deviation اتنين point خمسة اربعة لحظة استخدمت اكم
+
+320
+00:31:30,220 --> 00:31:33,460
+significant figures اربعة لحظة يعني اربعة بين
+
+321
+00:31:33,460 --> 00:31:41,600
+اربعة مانفعش احط الرقم الخامس فلما نكتب sut n بين
+
+322
+00:31:41,600 --> 00:31:44,500
+قوسين تلات ستين point ست اتنين و اتنين point خمسة
+
+323
+00:31:44,500 --> 00:31:49,020
+اربعة معناته ال dissolution normal هذا ال mean
+
+324
+00:31:49,020 --> 00:31:51,120
+value هذا ال standard deviation
+
+325
+00:31:56,810 --> 00:32:00,890
+الجداول فيها الخواص تعطيني مش كل التفاصيل هذه
+
+326
+00:32:00,890 --> 00:32:06,750
+تعطيني single value تعطيني single value لل
+
+327
+00:32:06,750 --> 00:32:12,670
+strength الجداول common to use ninety nine percent
+
+328
+00:32:12,670 --> 00:32:17,210
+minimum strength يعني بحكيلك هذا ninety nine
+
+329
+00:32:17,210 --> 00:32:21,710
+percent minimum strength indicating ان تسعة سنة في
+
+330
+00:32:21,710 --> 00:32:26,620
+الانهية من العينة exceed this valueيعني بنحكيك ال
+
+331
+00:32:26,620 --> 00:32:29,920
+strength it ninety nine .. ninety nine percent من
+
+332
+00:32:29,920 --> 00:32:32,580
+ال strength اللي سواء مية kilo pound per square
+
+333
+00:32:32,580 --> 00:32:37,420
+inch معناته تسعة وتسعين فيه من العينات تخطط القيمة
+
+334
+00:32:37,420 --> 00:32:41,000
+هذه يعني هذه هي القيمة الدنيا
+
+335
+00:33:02,220 --> 00:33:06,700
+ال cold working هي عبارة عن process بعمل plastic
+
+336
+00:33:06,700 --> 00:33:13,300
+deformation على ال material بهدف رفع ال strength
+
+337
+00:33:13,300 --> 00:33:17,580
+بتاعتها by strain hardening effect اذا فاكدين ال
+
+338
+00:33:17,580 --> 00:33:23,180
+strain hardening effect بيزود عدد ال dislocations
+
+339
+00:33:23,180 --> 00:33:30,320
+في المادة و بتكون مخربشة مع بعض فبصير المقاومة
+
+340
+00:33:31,840 --> 00:33:35,500
+لحركة انزلاق المستوات الذرية او لحركة ال
+
+341
+00:33:35,500 --> 00:33:40,960
+dislocations بيصير اصعب فال string تشملها بالزيد ف
+
+342
+00:33:40,960 --> 00:33:43,560
+it is a process of a string hardening و جاء من
+
+343
+00:33:43,560 --> 00:33:44,820
+علاقة هذا ال sigma true
+
+344
+00:34:00,670 --> 00:34:11,690
+لو أخدت log ال sigma true هتكون سوى log الكة زاد
+
+345
+00:34:11,690 --> 00:34:18,930
+عن log absolute true يعني لو رسمت على log log
+
+346
+00:34:18,930 --> 00:34:19,490
+scale
+
+347
+00:34:23,660 --> 00:34:31,220
+log of epsilon true مع log of sigma true هتطلع
+
+348
+00:34:31,220 --> 00:34:41,380
+العلاقة اشي زي هيك هذا الاسلوب لو
+
+349
+00:34:41,380 --> 00:34:46,380
+عندي مادة بالشكل هذا و مادة بالشكل هذا هاي N واحد
+
+350
+00:34:46,380 --> 00:34:48,840
+و N اتنين
+
+351
+00:34:54,660 --> 00:34:57,740
+مين أن يتمدى؟ واحد ولا اتنين عندها قابلية to be
+
+352
+00:34:57,740 --> 00:35:00,720
+strain hardened او to be cold war؟ مين اكتر؟ واحد
+
+353
+00:35:00,720 --> 00:35:05,680
+ولا اتنين؟
+
+354
+00:35:05,680 --> 00:35:12,600
+ليش داني؟ على
+
+355
+00:35:12,600 --> 00:35:17,460
+فقط نفس ال K ال
+
+356
+00:35:17,460 --> 00:35:23,180
+slope ال Nالان هو the measure of the capacity of
+
+357
+00:35:23,180 --> 00:35:25,660
+the ability of a material to strain harden كل ما
+
+358
+00:35:25,660 --> 00:35:29,840
+بيزيد بيصير الكبسطة انها تت strain harden أسهل
+
+359
+00:35:29,840 --> 00:35:35,400
+يعني مادة قاسية كتير بتكون تاع الان منخفض وبالتالي
+
+360
+00:35:35,400 --> 00:35:39,480
+إمكانية ان اقسيها أكتر بيصير أصعب مادة طريقة كتير
+
+361
+00:35:39,480 --> 00:35:42,840
+في الأول بتكون ال capacity to be strain hardened
+
+362
+00:35:42,840 --> 00:35:47,650
+أعلىبعد شوية لو كملت بيصير .. بيضالها .. بيضالها
+
+363
+00:35:47,650 --> 00:35:51,390
+تقل عندها ال .. ال .. بتضال الكويتسترات بتقل بعد
+
+364
+00:35:51,390 --> 00:35:57,990
+عمل اول cold working او اول strain hardening عند
+
+365
+00:35:57,990 --> 00:36:05,450
+ال stress strain curve for some material عملت
+
+366
+00:36:05,450 --> 00:36:10,130
+loading هاي ال strain هاي ال stress عملت loading
+
+367
+00:36:10,130 --> 00:36:15,090
+دخلت ال plastic regionبعدين بديت اعمل unloading
+
+368
+00:36:15,090 --> 00:36:19,890
+هرجع لان طالما دخلت ل plastic region هكون دي ال
+
+369
+00:36:19,890 --> 00:36:27,610
+strain جزءين جزء linear او elastic وجزء plastic او
+
+370
+00:36:27,610 --> 00:36:32,250
+non elastic الجزء ال elastic يتم استرجاعه لان لما
+
+371
+00:36:32,250 --> 00:36:35,210
+رجعت ما رجعت لسه رجعت لهنا المعنى هذا هو ايش يمثل
+
+372
+00:36:35,210 --> 00:36:40,170
+ال plastic strain اللي تم استرجاعه اللي هو هذا ال
+
+373
+00:36:40,170 --> 00:36:42,450
+plastic strain
+
+374
+00:36:44,840 --> 00:36:54,420
+و هذا أبسلون plastic و ال total strain total
+
+375
+00:36:54,420 --> 00:37:04,880
+strain so أبسلون elastic زاد أبسلون plastic و
+
+376
+00:37:04,880 --> 00:37:13,580
+الأبسلون elastic بستوى اللي هو sigma على E أبسلون
+
+377
+00:37:13,580 --> 00:37:14,160
+plastic
+
+378
+00:37:20,530 --> 00:37:25,830
+لأ لأ لأ لأ هذا قليل من ال strength لأن ال elastic
+
+379
+00:37:25,830 --> 00:37:29,530
+strain ثابت لنفس ال material صحيح لأن هذا كله
+
+380
+00:37:29,530 --> 00:37:36,270
+مسترد لو وصلت هنا انا لو كنت هنا و رجعت هرجع موازي
+
+381
+00:37:36,270 --> 00:37:44,870
+هي هي ال plastic strain وهي
+
+382
+00:37:44,870 --> 00:37:47,960
+ال elastic strainما طيرت في قيمة الـ Elastic
+
+383
+00:37:47,960 --> 00:37:57,640
+String، طيرت في قيمة الـ Plastic String فأنا
+
+384
+00:37:57,640 --> 00:38:02,460
+أولش عملت loading لحد ما وصلت لنقطة I و رجعت صار
+
+385
+00:38:02,460 --> 00:38:06,460
+عندي مارجعتش للصفر لأنه دخلت ال plastic range هذا
+
+386
+00:38:06,460 --> 00:38:13,300
+أبسلون plastic إذا بعمل loading كمان مرة حصل I و
+
+387
+00:38:13,300 --> 00:38:22,310
+أنا لسه في ال elastic rangeهتصير المادة هتصير مش
+
+388
+00:38:22,310 --> 00:38:29,250
+زي هيك صارت المادة اقوى لو عملت unloading من هنا و
+
+389
+00:38:29,250 --> 00:38:36,810
+رجعت هرجع زي هيك المادة كل ما لها بتصير brittle
+
+390
+00:38:36,810 --> 00:38:37,970
+اكتر انشف
+
+391
+00:38:41,580 --> 00:38:44,640
+ففيه limit للاستيرنهارنج مالفعش هعمل استيرنهارنج
+
+392
+00:38:44,640 --> 00:38:48,720
+too much هصير المادة too brittle ممكن تصير فاليار
+
+393
+00:38:48,720 --> 00:38:53,320
+ال
+
+394
+00:38:53,320 --> 00:39:04,860
+hardness
+
+395
+00:39:04,860 --> 00:39:18,780
+هي مقاومةالمادة للخدش من اداء مصنوعة من مادة اكثر
+
+396
+00:39:18,780 --> 00:39:23,920
+قساوة من المادة تحت الفحص يعني
+
+397
+00:39:23,920 --> 00:39:31,280
+مانفعش اخدش الحديد القاسي بخشب حتى لو كان عفته حد
+
+398
+00:39:31,280 --> 00:39:39,800
+مش هيقدشه فهي مقاومة المادة للخدش منpointed tool
+
+399
+00:39:39,800 --> 00:39:43,680
+يعني tool رأس مدبّب بس ال hardness بتاعته أعلى من
+
+400
+00:39:43,680 --> 00:39:49,240
+المادة تاعت الفحص عنا كتير مفحصات طرق لفحص ال
+
+401
+00:39:49,240 --> 00:39:52,720
+hardness منها rockwell hardness test وعنا brain
+
+402
+00:39:52,720 --> 00:39:56,200
+hardness test وvickers hardness test وفي فحصات
+
+403
+00:39:56,200 --> 00:40:00,780
+تانية هذه الأكتر شهرة طبعا
+
+404
+00:40:00,780 --> 00:40:04,840
+في علاقة بين ال ultimate tensile strength و ال
+
+405
+00:40:04,840 --> 00:40:11,340
+hardnessفي حالة الستيل SUT بيساوي تلاتة point
+
+406
+00:40:11,340 --> 00:40:15,920
+أربعة hardness of brittle لو كانت الوحدات بالميجا
+
+407
+00:40:15,920 --> 00:40:22,640
+باسكال وحدات SI unit ففي حالة ال cast iron ال SU
+
+408
+00:40:22,640 --> 00:40:25,280
+بيساوي واحد point خمسة تمانية H بيه hardness of
+
+409
+00:40:25,280 --> 00:40:28,700
+brittle minus ستة وتمانين ميجا باسكال طبعا ومعطيني
+
+410
+00:40:28,700 --> 00:40:33,200
+علاقة مرة في حالة ال English unit ومرة في حالة ال
+
+411
+00:40:33,200 --> 00:40:34,120
+SI units
+
+412
+00:40:39,820 --> 00:40:43,900
+في ال impact properties خصائص المادة تحت أثير
+
+413
+00:40:43,900 --> 00:40:48,160
+الصدمات الميكانيكية استخدمنا شاربي نوتش impact
+
+414
+00:40:48,160 --> 00:40:55,420
+test في ال sharp notch impact test بنثبت
+
+415
+00:40:55,420 --> 00:41:01,520
+عينةو بنضربها بشكوش ب .. بندول بنضربها لحد ايش؟
+
+416
+00:41:01,520 --> 00:41:06,680
+الكسر و كنا نقيس كمية الطاقة اللى متصطفة خلال
+
+417
+00:41:06,680 --> 00:41:10,080
+عملية الكسر كل ما كانت كمية الطاقة اللى متصطفة
+
+418
+00:41:10,080 --> 00:41:14,300
+خلال عملية الكسر اكتر ماناته هذا بيأكد ان المادة
+
+419
+00:41:14,300 --> 00:41:17,960
+قدرتها على امتصال الصدمات اكتر كل ما قلت الطاقة
+
+420
+00:41:17,960 --> 00:41:21,280
+اللى متصطفة في كسر العينة كل ما كانت المادة قدرتها
+
+421
+00:41:21,280 --> 00:41:25,020
+على امتصال الصدمات اقل و عملنا رسمنا ال curve هذا
+
+422
+00:41:26,190 --> 00:41:30,270
+يعني هين درجة الحرارة تنبرتشها و هين الشاربه ال
+
+423
+00:41:30,270 --> 00:41:35,410
+impact energy ده مين جال على قصار المادة او
+
+424
+00:41:35,410 --> 00:41:40,450
+مورانتها؟ اللي هو قدرتها على مص الصدمات؟ الان
+
+425
+00:41:40,450 --> 00:41:43,550
+قدرتها على مص الصدمات بيتمد على ال character
+
+426
+00:41:43,550 --> 00:41:47,150
+بتاعها هي كيف هتتصرف هتتصرف tactile ولا brittle؟
+
+427
+00:41:47,150 --> 00:41:49,750
+تصرف ال tactile و ال brittle بيتم من درجة الحرارة
+
+428
+00:41:49,750 --> 00:41:54,750
+يعني الحديد عن درجات حرارة الغرفة العادية tactile
+
+429
+00:41:55,790 --> 00:42:00,130
+بمتص ضمات لكن برضه عند ماقص مية مية و خمسين بيصير
+
+430
+00:42:00,130 --> 00:42:05,810
+very brittle ناشف باطل متص فعندي ما يسمى هذا هو ال
+
+431
+00:42:05,810 --> 00:42:11,070
+curve يعني ال material هذا واضح تقريبا اعلى .. بعد
+
+432
+00:42:11,070 --> 00:42:17,200
+السفر بتتصرف تقريبا ductileتحت السفر تتصرف ash
+
+433
+00:42:17,200 --> 00:42:21,600
+British والدليل في المنطقة هذه ال absorbed energy
+
+434
+00:42:21,600 --> 00:42:26,220
+بتكون قليلة في المنطقة هذه ال absorbed energy
+
+435
+00:42:26,220 --> 00:42:34,560
+بتكون عالية بشكل
+
+436
+00:42:34,560 --> 00:42:38,910
+عام ال FCC ال BCC materials بيكون فيهاالـ
+
+437
+00:42:38,910 --> 00:42:43,570
+Transition Temperature واضحة في حالة ال FCC بيكون
+
+438
+00:42:43,570 --> 00:42:47,990
+مافيش تقرية يعني تقرية بيكون ال impact energy بشكل
+
+439
+00:42:47,990 --> 00:42:53,410
+هذا هاي عندى اللي هو ال temperature و ال energy
+
+440
+00:42:53,410 --> 00:42:56,890
+لكن
+
+441
+00:42:56,890 --> 00:43:05,730
+في حالة BCC metals مش زي هيك هذا FCC هذا BCC
+
+442
+00:43:15,050 --> 00:43:18,930
+الان السؤال هل ال .. ال .. ال .. ال strength تتغير
+
+443
+00:43:18,930 --> 00:43:24,810
+مع درجة الحرارة؟ اه تتغير مع درجة الحرارة هندهن في
+
+444
+00:43:24,810 --> 00:43:29,270
+curve بين ال strength as a function of temperature
+
+445
+00:43:29,270 --> 00:43:32,730
+ال curve اللي علوه مثل ال ultimate strength وال
+
+446
+00:43:32,730 --> 00:43:37,850
+curve التان مثل ال yield strength في حالة ال
+
+447
+00:43:37,850 --> 00:43:40,250
+ultimate strength كل ما ازود درجة الحرارة في
+
+448
+00:43:40,250 --> 00:43:43,810
+البداية بتكون ال ultimate strength بزيد بشكل غير
+
+449
+00:43:43,810 --> 00:43:49,460
+ملحوظلحد ما تصل maximum و بعدين تتناقص بشكل سريع
+
+450
+00:43:49,460 --> 00:43:54,280
+مع درجة الحرارة ال ultimate tensile strength لكن
+
+451
+00:43:54,280 --> 00:44:01,020
+ال yield strength دايما بتقل مع درجة الحرارة
+
+452
+00:44:01,020 --> 00:44:05,400
+ال
+
+453
+00:44:05,400 --> 00:44:11,340
+creep هي ظاهرة الزحف او ظاهرة التمدد تحت تأثير
+
+454
+00:44:11,340 --> 00:44:18,640
+أحمالعن درجات حرارة مرتفعة بيصير عندي تمدد بشكل
+
+455
+00:44:18,640 --> 00:44:23,100
+مستمر رسمناه يسمى creep curve كان مكوّن من تلات
+
+456
+00:44:23,100 --> 00:44:26,300
+برحل المرحلة اللي بيسمونها ال primary stage
+
+457
+00:44:26,300 --> 00:44:29,480
+المرحلة التانية ال secondary stage المرحلة التالتة
+
+458
+00:44:29,480 --> 00:44:33,480
+ال tertiary stage في ال primary stage بيكون ال
+
+459
+00:44:33,480 --> 00:44:41,720
+strain بيزيد بمعدل متناقص بيزيد معدل متناقصبصير
+
+460
+00:44:41,720 --> 00:44:46,100
+linear at constant rate وبعدين بزيد ال strain
+
+461
+00:44:46,100 --> 00:44:56,680
+بمعدل متزايد لحد الكسر او حد الفيلير طيب
+
+462
+00:44:56,680 --> 00:45:00,120
+نظم
+
+463
+00:45:00,120 --> 00:45:04,020
+الترقيم material numbering systems فاني common
+
+464
+00:45:04,020 --> 00:45:07,220
+numbering systems مجموعة من طرق الترقيم للمواد
+
+465
+00:45:07,220 --> 00:45:09,400
+عندي
+
+466
+00:45:10,930 --> 00:45:13,690
+society of automotive engineers S.A.E. الها
+
+467
+00:45:13,690 --> 00:45:17,350
+numbering system and American iron and steel
+
+468
+00:45:17,350 --> 00:45:20,870
+institute الها numbering system and unified
+
+469
+00:45:20,870 --> 00:45:24,410
+numbering system ال U.N.S. and American society
+
+470
+00:45:24,410 --> 00:45:27,830
+for testing and materials A.S.T.M for cast iron
+
+471
+00:45:27,830 --> 00:45:32,510
+الها numbering system
+
+472
+00:45:32,510 --> 00:45:38,070
+ال اه ماشي ال system المشهور عندنا اللي بيشتغل
+
+473
+00:45:39,090 --> 00:45:42,770
+كلهم، يعني هدول كلهم مستخدمين، يعني .. يعني كلهم
+
+474
+00:45:42,770 --> 00:45:46,050
+هدول مستخدمين، الآن هنا .. أنت بتحكي في غزو ولا ..
+
+475
+00:45:46,050 --> 00:45:52,770
+ولا وين؟ عالميا .. عالميا هذه مشهورة كتير، يعني
+
+476
+00:45:52,770 --> 00:45:57,150
+هذه مشهورة كتير في .. في الولايات المتحدة، في عندك
+
+477
+00:45:57,150 --> 00:46:00,590
+ال standard طبعا الياباني و في عندك ال .. ال
+
+478
+00:46:00,590 --> 00:46:03,330
+standard ال .. ال .. البريطاني و في عندك ال
+
+479
+00:46:03,330 --> 00:46:08,830
+standard الألمانينعم society زي دي بتسمي المواد و
+
+480
+00:46:08,830 --> 00:46:12,910
+بتعقيمها هذا ال .. أحدث مش كلها هذا النظام في
+
+481
+00:46:12,910 --> 00:46:16,690
+أمريكا معظمه و كتير من الدول ماشية عليه كتير من
+
+482
+00:46:16,690 --> 00:46:18,730
+الدول ماشية عليه بس في standard تانية هتشوف اللي
+
+483
+00:46:18,730 --> 00:46:23,110
+هو النظام الياباني نظام الألماني و نظام بريطانيا
+
+484
+00:46:23,110 --> 00:46:26,750
+هم هدول أنظمه الكتير شهر كتير طبعا من .. في .. في
+
+485
+00:46:26,750 --> 00:46:30,010
+يعني بتحكي والله المدى رقمها كذا تعادل رقم كذا في
+
+486
+00:46:30,010 --> 00:46:35,460
+النظام الألماني أو ال .. المدى رقمت ..في ال .. في
+
+487
+00:46:35,460 --> 00:46:39,460
+ال SCE رقم معين و عادل في النظام الألماني اللي لها
+
+488
+00:46:39,460 --> 00:46:43,420
+رقم معادل يعني في تحويل بين الأنظمة يعني عشر و
+
+489
+00:46:43,420 --> 00:46:46,900
+عشرين ستين مختلف من نظام لنظام مثلا؟ لأ خليني
+
+490
+00:46:46,900 --> 00:46:51,600
+أبتعد .. يعني انت .. انت .. هذا طريقة ترقيم مختصة
+
+491
+00:46:51,600 --> 00:46:54,340
+بال organization نفسها مينفعش تحكي والله مختلفة و
+
+492
+00:46:54,340 --> 00:46:57,920
+مش مختلفة هذا نظام ترقيمهم لما انت تختار مادة
+
+493
+00:46:57,920 --> 00:47:01,020
+تختار حسن النظام اللي انت شغال عليه انت في الآخر
+
+494
+00:47:01,020 --> 00:47:03,760
+تختار مش أرقام .. تختارش أرقام انت ايش تختار؟
+
+495
+00:47:04,650 --> 00:47:09,110
+بتختار خواص مظبوط الخواص اللى بتناسى بالرقم بغض
+
+496
+00:47:09,110 --> 00:47:13,450
+النظر عن ال system تخدها و بتحط philosophical انا
+
+497
+00:47:13,450 --> 00:47:21,750
+اختارت والله اللى هو مثلا SAA 1020 مثلا اللى خواصه
+
+498
+00:47:21,750 --> 00:47:30,350
+واحد اتنين تلاتة لان
+
+499
+00:47:30,350 --> 00:47:36,630
+ماتقاربطوش لان في نظام ترقيمنظام ترقيم انه ترقيم
+
+500
+00:47:36,630 --> 00:47:41,170
+مختلف عن بعض انا في الآخر باختار خواص باختار خواص
+
+501
+00:47:41,170 --> 00:47:46,250
+لان بفتح كتالوجنا الكتالوج بحكي والله ال ST حسب
+
+502
+00:47:46,250 --> 00:47:50,110
+ترقيم النظام الألماني ال ST رقم واحد هيخواصه انا
+
+503
+00:47:50,110 --> 00:47:56,770
+باختار الخواصوفي الآخر هدخل ايش؟ كتالوج وبحط بحكي
+
+504
+00:47:56,770 --> 00:47:59,590
+طبق النظام الترقيم الألماني كذا كذا أو طبق النظام
+
+505
+00:47:59,590 --> 00:48:06,870
+ال S E E او طبق النظام ال A I S I او ال U N S الان
+
+506
+00:48:06,870 --> 00:48:10,570
+ال U N S numbering system تم اضغط بواسطة ال
+
+507
+00:48:10,570 --> 00:48:13,250
+society of automotive engineers سنة الف تسعين وخمس
+
+508
+00:48:13,250 --> 00:48:21,330
+سبعين مكوّن من letter letterمطبوع بخمس أرقام كم
+
+509
+00:48:21,330 --> 00:48:27,310
+الرقم مطبوع بخمس digits الان
+
+510
+00:48:27,310 --> 00:48:37,190
+ال letter قد يكون G او A او C او S G carbon and
+
+511
+00:48:37,190 --> 00:48:42,640
+alloys steel اللي هو الحديد والسباكه ال Gالـ A
+
+512
+00:48:42,640 --> 00:48:48,320
+الالمنيوم سباق الالمنيوم ال C سباق الانحاس ال S
+
+513
+00:48:48,320 --> 00:48:55,280
+سباق ال stainless steel الآن حكينا .. الآن الرقم
+
+514
+00:48:55,280 --> 00:49:02,700
+ممكن يكون G ورا خمس أرقام أو A ورا خمس أرقام أو C
+
+515
+00:49:02,700 --> 00:49:08,420
+ورا خمس أرقام أو S ورا خمس أرقام مثلا لو أخدنا ال
+
+516
+00:49:08,420 --> 00:49:16,620
+G ال G إيش؟steel سبق الحديد والسباقه اللي احنا
+
+517
+00:49:16,620 --> 00:49:30,780
+حكينا جي هاي اكس اكس اكس اكس اكس او الرقامين بيمثل
+
+518
+00:49:30,780 --> 00:49:33,980
+ال ال ال first two digits indicate composition
+
+519
+00:49:33,980 --> 00:49:40,140
+بيحكوا علياش ال composition
+
+520
+00:49:47,570 --> 00:49:53,810
+الرقمين التانين بيحكوا عن نسبة الكربون هتكون XX
+
+521
+00:49:53,810 --> 00:50:01,330
+على 100% نسبة الكربون الرقم
+
+522
+00:50:01,330 --> 00:50:06,630
+الأخير رقم خاص بس انا باهم ان الرقمين الأولين
+
+523
+00:50:06,630 --> 00:50:12,740
+والتالت والرابع يعني لما نحكي Gطبعا الأول رقم اللي
+
+524
+00:50:12,740 --> 00:50:16,920
+عندي جي وان زيرو جي وان وان جي وان تلتاش جي تلاتة
+
+525
+00:50:16,920 --> 00:50:24,920
+واربعين جي أربع تسعين لو حكيت جي وان زيرو اتنين
+
+526
+00:50:24,920 --> 00:50:31,840
+زيرو ايش معناته بطلع جي أول رقم اللي عندي هاي هون
+
+527
+00:50:31,840 --> 00:50:35,760
+plain carbon حديد سادة مافيش فيه عناصر تانية بس
+
+528
+00:50:35,760 --> 00:50:36,040
+carbon
+
+529
+00:50:38,980 --> 00:50:42,000
+تو زيرو هقسم هذا عالميا الشي عالمية اللي هي point
+
+530
+00:50:42,000 --> 00:50:52,980
+اتنين في المية carbon لو حكيت جي جي اربعين تلاتين
+
+531
+00:50:52,980 --> 00:51:02,840
+نصف
+
+532
+00:51:02,840 --> 00:51:06,460
+كربون في point تلاتة في المية point تلاتة في المية
+
+533
+00:51:08,650 --> 00:51:12,650
+هذه مثال جي اتنين و خمسين اتنين اتنين و خمسين تسعة
+
+534
+00:51:12,650 --> 00:51:17,450
+تمانية ستة اتنين و خمسين هي اتنين و خمسين Chrome
+
+535
+00:51:17,450 --> 00:51:23,050
+Steel نفس الكربون فيه اكم بقون تسعة تمانية في
+
+536
+00:51:23,050 --> 00:51:28,010
+المية بقون تسعة تمانية في المية هذا الكلام كل
+
+537
+00:51:28,010 --> 00:51:35,910
+الواحد تقيمه او خلاص؟ نعم حد لاقيش هذاUNS هذا نظام
+
+538
+00:51:35,910 --> 00:51:39,270
+الترقيم للـ UNS بدك أنت ترقيم تاني اتطلع عليها
+
+539
+00:51:39,270 --> 00:51:46,350
+اللي هي شوف كيف نظام ترقيمهم ال
+
+540
+00:51:46,350 --> 00:51:49,330
+alloy steels سابقا في chrome alloy steels نيكل
+
+541
+00:51:49,330 --> 00:51:53,770
+alloy steels في عندي مانجانيز يكون فيها مانجانيز
+
+542
+00:51:53,770 --> 00:51:55,830
+الشكل الأساسي في عندي silicone alloy steels
+
+543
+00:51:55,830 --> 00:52:00,090
+موليدنوم alloy steels و vanadium alloy steels و
+
+544
+00:52:00,090 --> 00:52:01,610
+tungsten alloy steels
+
+545
+00:52:05,380 --> 00:52:11,180
+الـ stainless steels هي عبارة عن سباق أساس الحديد
+
+546
+00:52:11,180 --> 00:52:16,620
+بالنسبة لـ chrome بتكون فيها مرتفع أقلش 12% هذا
+
+547
+00:52:16,620 --> 00:52:19,560
+اللي هو ال stainless steel ال chrome فيها بيكون
+
+548
+00:52:19,560 --> 00:52:26,800
+أقلش 12% طبعا مذيتها يعني بتقاوم resist اللي هو
+
+549
+00:52:26,800 --> 00:52:30,220
+corrosive conditions most مش كل .. مش كل شي بتقاوم
+
+550
+00:52:30,220 --> 00:52:35,920
+most corrosive conditionsفي عندى أربع نوع من ال
+
+551
+00:52:35,920 --> 00:52:38,140
+stainless steel فعندى ferratic chromium stainless
+
+552
+00:52:38,140 --> 00:52:41,960
+steel فعندى austenitic chromium nickel stainless
+
+553
+00:52:41,960 --> 00:52:46,460
+steel فعندى martinistic stainless steel فعندى
+
+554
+00:52:46,460 --> 00:52:54,620
+precipitation hardenable stainless steel في
+
+555
+00:52:54,620 --> 00:52:58,320
+ال casting materials اللى هو الحديد السابق السكب
+
+556
+00:52:58,320 --> 00:53:03,910
+في ست نوعالـ Gray Cast Iron والـ Ductile and
+
+557
+00:53:03,910 --> 00:53:07,350
+Nodular Cast Iron والـ White Cast Iron والـ
+
+558
+00:53:07,350 --> 00:53:11,190
+Millable Cast Iron والـ Alloy Cast Iron والـ Cast
+
+559
+00:53:11,190 --> 00:53:17,810
+Steel الـ
+
+560
+00:53:17,810 --> 00:53:23,850
+Nonferrous metals هي البعادل اللي مافيه حديده اللي
+
+561
+00:53:23,850 --> 00:53:28,130
+هي الألمنيوم المنجانيستي تلاتة مش كله طبعا الذاكرة
+
+562
+00:53:28,130 --> 00:53:34,140
+تلاتة بس هم أكتران الأمنيوم مغنيسيوم تيتانيوم ..
+
+563
+00:53:34,140 --> 00:53:39,060
+هنا ال cover based alloys .. cover based alloys
+
+564
+00:53:39,060 --> 00:53:44,680
+فيه كتير منها عندى .. في سباق انحاس بيكون .. براس
+
+565
+00:53:44,680 --> 00:53:51,020
+نسبة الذنب فيه خمس الى خمس عشر فلم يعنيطبعا تحتها
+
+566
+00:53:51,020 --> 00:53:54,560
+ما زال في عندى range في كذا نوع guiling brass,
+
+567
+00:53:54,800 --> 00:53:57,400
+commercial bronze, red brass في انواع كتير من ال
+
+568
+00:53:57,400 --> 00:54:00,920
+brass في عندى brass نسبة الذنب فيه من عشرين لست و
+
+569
+00:54:00,920 --> 00:54:04,180
+تلاتين في المية عندى low brass, cartridge brass,
+
+570
+00:54:04,300 --> 00:54:08,000
+gallop brass, low lead brass في انواع كتير من ال
+
+571
+00:54:08,000 --> 00:54:11,740
+.. ال .. اللي هو ال brassيعني ال brass نسبة الذنب
+
+572
+00:54:11,740 --> 00:54:15,300
+من ستة وتلاتين لعربين فمية فيه months مثل novel
+
+573
+00:54:15,300 --> 00:54:19,440
+brass في عند ال bronze بيكون فيه ايش؟ silicon ال
+
+574
+00:54:19,440 --> 00:54:23,600
+bronze بيكون فيه ال silicon ال silicon ال bronze
+
+575
+00:54:23,600 --> 00:54:25,320
+في عند ال phosphorus ال bronze في عند ال aluminium
+
+576
+00:54:25,320 --> 00:54:30,120
+ال bronze في عند ال beryllium ال bronze يعني ال
+
+577
+00:54:30,120 --> 00:54:33,700
+brass بيكون عنصر أساسي في الذنب ال bronze ممكن
+
+578
+00:54:33,700 --> 00:54:37,100
+يكون فيه silicone ممكن يكون فيه فسفور ممكن فيه
+
+579
+00:54:37,100 --> 00:54:39,140
+aluminium ممكن يكون فيه beryllium
+
+580
+00:54:42,170 --> 00:54:49,770
+نيجي لل plastics ال
+
+581
+00:54:49,770 --> 00:54:53,210
+plastics فيه نوعين أساسيا في عندى thermoplastic و
+
+582
+00:54:53,210 --> 00:54:57,090
+في عندى thermoset plastic ال thermoplastic هي أي
+
+583
+00:54:57,090 --> 00:55:04,770
+plastic اللى ممكن أشكلهبالتسخين بأسهره وبضخه في
+
+584
+00:55:04,770 --> 00:55:10,930
+قالب باخد شكل القالب بالتسخين بسيح وباخد شكل هي ال
+
+585
+00:55:10,930 --> 00:55:15,730
+thermoplastic ال thermostat ال thermostat هي ال
+
+586
+00:55:15,730 --> 00:55:23,970
+material بتسيح تحت الضغط وبتتجمد أو بيصير a curing
+
+587
+00:55:23,970 --> 00:55:29,520
+بالحرارةيعني بيستخدموا ضغط و حرارة ضغط عشان يخليها
+
+588
+00:55:29,520 --> 00:55:32,880
+fluidized تمشي و الحرارة عشان يعملوا لها curing
+
+589
+00:55:32,880 --> 00:55:39,340
+تنشف بالحرارة هذا اللي هي ال thermostat طبعا ال
+
+590
+00:55:39,340 --> 00:55:42,380
+thermoplastic ال material اللي فيه كتير عندى فيه
+
+591
+00:55:42,380 --> 00:55:48,020
+عندى ABS group عندى acetal acrylic عندى phenylene
+
+592
+00:55:48,020 --> 00:55:54,000
+عندى polycarbonate عندى polyester عندى polyamide
+
+593
+00:55:54,000 --> 00:55:59,610
+عندىانواع كتير و هنا حاطط الخواص بتاعة ال
+
+594
+00:55:59,610 --> 00:56:05,350
+thermoplastic .. thermoplastic materials فعندى ال
+
+595
+00:56:05,350 --> 00:56:13,510
+thermoset materials زى ال alkyd عند ال aminos عند
+
+596
+00:56:13,510 --> 00:56:17,730
+ال e-boxes عند الفينالكس عند السيليكونز هذه كلها
+
+597
+00:56:17,730 --> 00:56:23,380
+تصنف ك thermoset materialsهذا بدها course كامل
+
+598
+00:56:23,380 --> 00:56:26,880
+لحالها اللي هي ال course .. اه اتفضل .. كنتوا بدها
+
+599
+00:56:26,880 --> 00:56:30,460
+course ليش خططنا عن زي مثلا ال material و ماينفعش
+
+600
+00:56:30,460 --> 00:56:34,900
+.. ال plastic طالعينه .. مش مطالينهم بدوا انت هذا
+
+601
+00:56:34,900 --> 00:56:38,640
+ال course مركز ال .. ال .. لإن احنا بنركز على
+
+602
+00:56:38,640 --> 00:56:43,960
+المواد البلورية crystal materials ال plastic is
+
+603
+00:56:43,960 --> 00:56:48,780
+not a crystal material اه فهو فعلا احنا بندرس
+
+604
+00:56:48,780 --> 00:56:52,190
+mechanical engineeringما بندرس اللي هو material
+
+605
+00:56:52,190 --> 00:56:55,630
+engineering، في بارة بتكون عندك material
+
+606
+00:56:55,630 --> 00:56:58,810
+engineering شكل كاملة، تاخد يعني كتير كورسات في ال
+
+607
+00:56:58,810 --> 00:57:04,050
+material .. ceramics .. composite .. polymers ..
+
+608
+00:57:04,050 --> 00:57:11,290
+في تفاصيل كتير حتى
+
+609
+00:57:11,290 --> 00:57:17,660
+في ال baccadorisطيب composite materials اسمه نفسه
+
+610
+00:57:17,660 --> 00:57:20,440
+composite مكونا من two or more dissimilar
+
+611
+00:57:20,440 --> 00:57:23,000
+materials مكونا من مادتين او اكتر من المواد
+
+612
+00:57:23,000 --> 00:57:27,640
+الخواصة مختلفة عن بعض each of which contributed
+
+613
+00:57:27,640 --> 00:57:30,560
+the final properties المواد المكوناة لل composite
+
+614
+00:57:30,560 --> 00:57:33,960
+بيطول الخواصة النهائية للمادة لكن لو عملت section
+
+615
+00:57:33,960 --> 00:57:38,800
+في المادة كل مادة محتفظة بخواصة بشكل منفصل يعني
+
+616
+00:57:38,800 --> 00:57:46,500
+البطون المسلح يعتبر ايش؟composite في حصمة في أسمنت
+
+617
+00:57:46,500 --> 00:57:48,580
+و في عندى حديد
+
+618
+00:57:56,700 --> 00:58:00,040
+الان طبعا لو ال .. ال .. ال fiberglass is
+
+619
+00:58:00,040 --> 00:58:03,540
+composite material بستخدم filler الان طبعا في عند
+
+620
+00:58:03,540 --> 00:58:06,420
+المادة الأساسية اللى بتكون عادة ال strength
+
+621
+00:58:06,420 --> 00:58:09,440
+بتاعتها عالية و brittle و في مادة ال filler
+
+622
+00:58:09,440 --> 00:58:13,000
+material اللى هي بتخلق .. بتعبي المادة بشكل عام
+
+623
+00:58:13,000 --> 00:58:18,840
+مثلا في حالة ال .. ال .. ال fiberglassال filler
+
+624
+00:58:18,840 --> 00:58:23,760
+material ممكن تكون على شكل شبكة شبك ممكن تكون على
+
+625
+00:58:23,760 --> 00:58:28,100
+شكل اخطوط او على شكل ال nodular او على شكل حبيبات
+
+626
+00:58:28,100 --> 00:58:34,060
+و تنخلط معاها اللي هو ال E-boxy تتجمد بال C and H
+
+627
+00:58:34,060 --> 00:58:36,160
+مادة competent material
+
+628
+00:58:39,480 --> 00:58:42,960
+الموجود عندنا .. الموجود .. النوع اللى عندنا موجود
+
+629
+00:58:42,960 --> 00:58:46,080
+فتاح فى غزل هو النوع هذا ال filler ماتيها عبارة عن
+
+630
+00:58:46,080 --> 00:58:55,960
+بتكون شبكة fibers ال filler
+
+631
+00:58:55,960 --> 00:58:59,240
+هي اللى هى بتكون مثلا فى حالة ال fiberglass اللى
+
+632
+00:58:59,240 --> 00:59:04,900
+هو اللى هو الياف الزجاجية الياف الزجاجية لحالها
+
+633
+00:59:04,900 --> 00:59:11,090
+هشة بتتفتفتف you apply اللي هو ال epoxy طبقة بعدين
+
+634
+00:59:11,090 --> 00:59:14,210
+بتحط عندك اللي هو ال filler material او الشبكة
+
+635
+00:59:14,210 --> 00:59:20,070
+بعدين بتدهن عليها و كذا اتطلع خش على اليوتيوب شوف
+
+636
+00:59:20,070 --> 00:59:22,910
+ال compass ال fiberglass application هتشوف
+
+637
+00:59:22,910 --> 00:59:25,990
+فيديوهات كتير fiberglass application شوف كيف
+
+638
+00:59:25,990 --> 00:59:28,370
+بيعملوه يمكن اي حد نفسه يعملوه لحاله
+
+639
+00:59:32,640 --> 00:59:35,720
+الان ال material families and classes حكينا فيه ان
+
+640
+00:59:35,720 --> 00:59:40,600
+المعادن .. المعادن فيه السباق الألماني والانحاس،
+
+641
+00:59:40,600 --> 00:59:44,320
+الرصاص، البنجانيز، الستيلستين، التيتانيوم،
+
+642
+00:59:44,320 --> 00:59:52,690
+التنجسترون، الليد، الزنك، عندي ال ceramicsال
+
+643
+00:59:52,690 --> 00:59:57,070
+ceramics عندي اللي هي عندي ال alumina AL2O3، عندي
+
+644
+00:59:57,070 --> 00:59:59,430
+ال aluminium ال nitride، عندي ال boron carbide،
+
+645
+00:59:59,430 --> 01:00:02,390
+عندي ال silicon carbide، silicon nitride، tungsten
+
+646
+01:00:02,390 --> 01:00:06,250
+carbide، ال brick يعتبر برضه إيش ceramic، ال
+
+647
+01:00:06,250 --> 01:00:10,670
+concrete ceramic، الأحجار ceramic، ال soda lime
+
+648
+01:00:10,670 --> 01:00:15,050
+glass، ال .. ال silica glass و ال glass ceramics،
+
+649
+01:00:15,050 --> 01:00:19,760
+هذه كلها مواد ceramicالعائلة التانية هي ال
+
+650
+01:00:19,760 --> 01:00:24,280
+polymers ال polymers عند ال ABS عند ال PET عند ال
+
+651
+01:00:24,280 --> 01:00:28,920
+PE عند ال PP ال polypropylene يعني في أنواع كتير
+
+652
+01:00:28,920 --> 01:00:33,140
+من ال polymers عند
+
+653
+01:00:33,140 --> 01:00:39,410
+ال elastomersهي ال rubbers سواء كانت طبيعية المطاط
+
+654
+01:00:39,410 --> 01:00:43,810
+سواء كانت طبيعية او صناعية و فيها كتير من ال
+
+655
+01:00:43,810 --> 01:00:48,610
+rubbers عند ال hybrids يعني ال composites compost
+
+656
+01:00:48,610 --> 01:00:52,850
+materials عند ال foams و عند ال natural materials
+
+657
+01:00:52,850 --> 01:00:55,350
+فهذه كل ال materials الموجودة طبعا في materials
+
+658
+01:00:55,350 --> 01:01:01,530
+تانية اللي هي ال ال nano materials ال nano carbon
+
+659
+01:01:01,530 --> 01:01:03,470
+tubes و فيها تفاصيل
+
+660
+01:01:06,560 --> 01:01:09,140
+عندى هى الماريجين ال young modulus او ال modulus
+
+661
+01:01:09,140 --> 01:01:12,200
+بالنسبة ليه for various materials هذا on average
+
+662
+01:01:12,200 --> 01:01:16,780
+عندى مثلا هى ال tungsten carbide is very hard
+
+663
+01:01:16,780 --> 01:01:19,980
+material فما اتوقع يكون ال stress strain curve
+
+664
+01:01:19,980 --> 01:01:21,140
+بتاعها اشي زي هيك
+
+665
+01:01:25,560 --> 01:01:30,000
+يعني بتكون very hard بيصيرش ال plastic deformation
+
+666
+01:01:30,000 --> 01:01:34,020
+almost zero لحد الكسر و ال slope تقريب بيكون يعني
+
+667
+01:01:34,020 --> 01:01:36,200
+almost سنتين درجة فبتكون ال modulus of elasticity
+
+668
+01:01:36,200 --> 01:01:41,160
+بتاعتها مرتفعة لو أخدت مادة هنا تحت flexible
+
+669
+01:01:41,160 --> 01:01:45,740
+polymer material هتكون طارية جديدة و بيكون ال
+
+670
+01:01:45,740 --> 01:01:49,020
+slope بتاع ال stress strength بتاعها قليل و بتاع
+
+671
+01:01:49,020 --> 01:01:50,960
+ال modulus of elasticity بتكون إلا من الخفضة لو
+
+672
+01:01:50,960 --> 01:01:51,780
+أخدنا مادة هنا
+
+673
+01:01:56,040 --> 01:02:00,200
+Titanium Alloy Titanium
+
+674
+01:02:00,200 --> 01:02:04,840
+Alloy برضه still ال model ال still بتاعتها ash
+
+675
+01:02:04,840 --> 01:02:11,740
+عالية عن ال nickel alloy طبعا ال titanium و ال
+
+676
+01:02:11,740 --> 01:02:17,620
+nickel ال strength لل weight ratio مرتفعة يعني for
+
+677
+01:02:17,620 --> 01:02:24,020
+the same unit of weightبحصل strength أعلى في
+
+678
+01:02:24,020 --> 01:02:28,490
+التيتاني وأكت أعلى من الهديد واضح؟ال strength
+
+679
+01:02:28,490 --> 01:02:32,350
+weight ratio عالية عشان تستخدم في ال applications
+
+680
+01:02:32,350 --> 01:02:37,130
+اللي أنا محتاج أخفف في الوزن فيها كتير زي مثلا
+
+681
+01:02:37,130 --> 01:02:42,050
+نضارات مش محتاج .. انا يعني لازم أكون خفيفة قدر
+
+682
+01:02:42,050 --> 01:02:46,030
+الممكن في الطائرات بتحتاج أستخدم مواد خفيفة الوزن
+
+683
+01:02:46,030 --> 01:02:51,350
+و القوة فيها مرتفعة يعني بهمني نسبة ال strength
+
+684
+01:02:51,350 --> 01:02:56,870
+للوزن بتطلعش على ال strength لحالة أو الوزن بهمني
+
+685
+01:02:56,870 --> 01:02:57,450
+ال ratio
+
+686
+01:03:00,400 --> 01:03:07,040
+في اي سؤال؟ هيكم خلصنا ال chapter اتنين تقريب معظم
+
+687
+01:03:07,040 --> 01:03:14,660
+المرة عليكم المحاضرة
+
+688
+01:03:14,660 --> 01:03:20,150
+الجاي هنبدأ في chapter تلاتةاللي هو هنبدأ اللي هو
+
+689
+01:03:20,150 --> 01:03:24,270
+يعني مراجعة مع بعض تفصيل لل mechanics و ال
+
+690
+01:03:24,270 --> 01:03:28,490
+material، يعني الشبطر تلت و أربع هكون تحضير لخمسة
+
+691
+01:03:28,490 --> 01:03:31,010
+و ستة و سبعة، أعطيكم العافية
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/iF9_1ET6MVU.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/iF9_1ET6MVU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..917bef02ca1542697c99e1b71e3fb729709ba166
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/iF9_1ET6MVU.srt
@@ -0,0 +1,2781 @@
+1
+00:00:05,110 --> 00:00:08,190
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,190 --> 00:00:12,290
+وبركاته اليوم هنستكمل chapter ثلاثة stress and
+
+3
+00:00:12,290 --> 00:00:16,370
+load analysis المرة الفاتتة حكينا عن ال stress
+
+4
+00:00:16,370 --> 00:00:21,210
+concentration كيف ال stress بترتفع عن مناطق ال
+
+5
+00:00:21,210 --> 00:00:25,750
+discontinuities بترتفع عن ال nominal value بيصير أن
+
+6
+00:00:25,750 --> 00:00:29,830
+التركيز الإجهادي اليوم هنحل مجموعة من الأمثلة عشان
+
+7
+00:00:29,830 --> 00:00:31,010
+نوضح الفكرة
+
+8
+00:00:33,500 --> 00:00:39,840
+المثال أمامكم في عندي thin plate عرض
+
+9
+00:00:39,840 --> 00:00:45,920
+من هنا أربعين ملي من هنا ثلاثين ملي في ثقب
+
+10
+00:00:45,920 --> 00:00:53,580
+هنا ال plate سمكها أربعة ملي وفي load مئة كيلو
+
+11
+00:00:53,580 --> 00:00:58,460
+نيوتن في fillet عندي هنا radiusها واحد ملي متر
+
+12
+00:01:06,590 --> 00:01:09,790
+it is desired to drill a hole through the center
+
+13
+00:01:09,790 --> 00:01:13,550
+of the forty millimeter face of the plate to allow
+
+14
+00:01:13,550 --> 00:01:21,210
+a cable to pass through it المطلوب نفتح ثقوب في
+
+15
+00:01:21,210 --> 00:01:29,570
+المنطقة هذه عشان أدخل منه a cable
+
+16
+00:01:29,570 --> 00:01:32,150
+a four millimeter hole is sufficient for the cable
+
+17
+00:01:32,150 --> 00:01:43,400
+to fit ثقوب كثيرة أربعة ملي كافي لدخول الكابل بق
+
+18
+00:01:43,400 --> 00:01:46,800
+an eight millimeter drill is readily available لكن
+
+19
+00:01:46,800 --> 00:01:51,980
+القطعة هذه فيها already ثقوب موجودة ثمانية ملي فيها
+
+20
+00:01:51,980 --> 00:01:54,480
+already ثقوب موجودة ثمانية ملي لكن مطلوب أوي بكفي
+
+21
+00:01:54,480 --> 00:01:59,160
+أربعة ملي لكن هي في ثقوب موجودة قطرها ثمانية ملي
+
+22
+00:02:03,640 --> 00:02:07,340
+will a crack be more likely to initiate at the
+
+23
+00:02:07,340 --> 00:02:11,820
+larger hole the smaller hole or at the fillet إذا
+
+24
+00:02:11,820 --> 00:02:18,080
+حيصير failure أو يصير بداية تشقق هل حيصير عند ال
+
+25
+00:02:18,080 --> 00:02:24,020
+hole قطر أربعة ملي أو ال hole قطر ثمانية ملي أو عند
+
+26
+00:02:24,020 --> 00:02:29,040
+ال fillet خليني أفحص عليه check
+
+27
+00:02:35,240 --> 00:02:40,920
+at the hole هذه
+
+28
+00:02:40,920 --> 00:02:46,760
+منطقة ال hole لو
+
+29
+00:02:46,760 --> 00:02:47,620
+أخذت section هنا
+
+30
+00:03:10,400 --> 00:03:16,040
+هذه thickness اللي
+
+31
+00:03:16,040 --> 00:03:20,760
+هي أربعة ملي متر هذه
+
+32
+00:03:20,760 --> 00:03:29,180
+كلها عرضها أربعين وهذه
+
+33
+00:03:29,180 --> 00:03:32,860
+تعتمد يا أربعة يا ثمانية صح يعني المرة لو كنت
+
+34
+00:03:32,860 --> 00:03:37,760
+كاتب أربعة يعني المرة اللي هنشتغل على أربعة و
+
+35
+00:03:37,760 --> 00:03:40,600
+المرة اللي هنشتغل على ثمانية مرة على أربعة و مرة
+
+36
+00:03:40,600 --> 00:03:44,940
+على ثمانية يعني عندي أربعة و ثمانية عندي ثمانية
+
+37
+00:03:44,940 --> 00:03:50,000
+خليني
+
+38
+00:03:50,000 --> 00:04:03,540
+أحكي ال هو واحد four millimeter hole هتكون
+
+39
+00:04:03,540 --> 00:04:06,300
+مساحة المقطع الصافي الـ A
+
+40
+00:04:11,330 --> 00:04:19,510
+اللي هو هتكون أربعة في أربعين ناقص
+
+41
+00:04:19,510 --> 00:04:27,870
+أربعة في أربعة صح؟ يعني
+
+42
+00:04:27,870 --> 00:04:31,650
+هيكون مئة وستون ناقص ستة عشر مئة وأربعة وأربعين
+
+43
+00:04:31,650 --> 00:04:32,970
+millimeter square
+
+44
+00:04:39,770 --> 00:04:43,050
+وأنا بحسب إن نمو ال stress في المنطقة هذه الـ Sigma
+
+45
+00:04:43,050 --> 00:04:48,710
+o هتكون
+
+46
+00:04:48,710 --> 00:04:56,230
+عشرة آلاف نيوتن على المساحة اللي هي
+
+47
+00:04:56,230 --> 00:05:01,390
+مئة وأربعة وأربعين طلعيها بالميجا باسكال هذا نحسب
+
+48
+00:05:01,390 --> 00:05:01,750
+ورايا
+
+49
+00:05:07,070 --> 00:05:10,550
+طيب الآن نتيجة الثقوب في عندي تركيز إجهاد في عندي
+
+50
+00:05:10,550 --> 00:05:19,570
+stress concentration هروح على Appendix A 15 1 6
+
+51
+00:05:19,570 --> 00:05:24,710
+69
+
+52
+00:05:24,710 --> 00:05:27,730
+.4
+
+53
+00:05:27,730 --> 00:05:31,210
+ميجا
+
+54
+00:05:31,210 --> 00:05:31,730
+باسكال
+
+55
+00:05:37,090 --> 00:05:40,830
+طيب أنا في عندي stress concentration هروح على
+
+56
+00:05:40,830 --> 00:05:45,090
+appendix A خمسة عشر واحد في آخر الكتاب أنا ماخذ
+
+57
+00:05:45,090 --> 00:05:54,850
+الصورة جيبها من الكتاب appendix A الـ thickness
+
+58
+00:05:54,850 --> 00:05:58,250
+اثنين
+
+59
+00:05:58,250 --> 00:06:05,190
+millimeter صحيح يعني هي دي thickness يعني لو فرض
+
+60
+00:06:05,190 --> 00:06:11,630
+كانت أربعة ملي خلي نكملها بتأثرش
+
+61
+00:06:11,630 --> 00:06:21,590
+على طبيعة المثال بدنا نخليها اثنين مين نخليها هنا
+
+62
+00:06:21,590 --> 00:06:28,130
+هتكون هنقسم على اثنين صح هنا
+
+63
+00:06:28,130 --> 00:06:36,560
+هتكون أربعة أربعة هنا عندي اثنين تسعة اثنين اثنين
+
+64
+00:06:36,560 --> 00:06:44,180
+وسبعين وعندي
+
+65
+00:06:44,180 --> 00:06:48,360
+هنا على
+
+66
+00:06:48,360 --> 00:06:53,660
+اثنين وسبعين ميجا
+
+67
+00:06:53,660 --> 00:06:54,740
+باسكال
+
+68
+00:07:00,570 --> 00:07:04,070
+هذا الـ Sigma هو فكان فينا stress concentration
+
+69
+00:07:04,070 --> 00:07:12,010
+بروح على Appendix A خمسة عشر واحد
+
+70
+00:07:12,010 --> 00:07:19,470
+واحد دي
+
+71
+00:07:19,470 --> 00:07:26,950
+هي دي دي على W اللي
+
+72
+00:07:26,950 --> 00:07:27,730
+هي أربعة
+
+73
+00:07:30,240 --> 00:07:51,020
+الـ W التي هي أربعين صح point one high point one منها
+
+74
+00:07:51,020 --> 00:07:55,800
+بطل الـ Kt يعني
+
+75
+00:07:55,800 --> 00:08:04,030
+تقريباً يعني اثنين point سبعة أقل شوية الـ Kt
+
+76
+00:08:04,030 --> 00:08:13,450
+معناه في الـ Sigma max هتكون Kt في الـ Sigma o
+
+77
+00:08:13,450 --> 00:08:19,470
+يعني اثنين point سبعة في مئة وثمانية وثلاثين point
+
+78
+00:08:19,470 --> 00:08:19,990
+تسعة
+
+79
+00:08:33,990 --> 00:08:38,790
+طيب هاد الـ case الأولى الـ case الثانية اللي وعندي
+
+80
+00:08:38,790 --> 00:08:46,190
+eight millimeter hole منها تطلع البحث بالـ area
+
+81
+00:08:46,190 --> 00:08:53,130
+اللي هتكون الـ area نفس الأشياء مش نفسه مش هتكون
+
+82
+00:08:53,130 --> 00:09:01,810
+اثنين في أربعين ناقص اثنين في ثمانية يعني
+
+83
+00:09:01,810 --> 00:09:02,910
+أربعة وستين
+
+84
+00:09:09,130 --> 00:09:14,010
+الـ Sigma O هتكون
+
+85
+00:09:14,010 --> 00:09:18,470
+عشرة آلاف على
+
+86
+00:09:18,470 --> 00:09:32,570
+أربعة وستين اللي
+
+87
+00:09:32,570 --> 00:09:38,700
+أنا بدي أحسب الـ Sigma O هي أكبر من هذه لكن مش هتصرف
+
+88
+00:09:38,700 --> 00:09:42,400
+بدي أشوف الـ stress concentration اللي أنا عندي A
+
+89
+00:09:42,400 --> 00:09:52,100
+خمسة عشر واحد الـ D على W ثمانية على أربعين اللي هي
+
+90
+00:09:52,100 --> 00:10:04,000
+point اثنين وأنا بطلع الـ Kt اثنين
+
+91
+00:10:04,000 --> 00:10:04,780
+point خمسة
+
+92
+00:10:07,800 --> 00:10:12,120
+معناته الـ Signal max هيكون
+
+93
+00:10:12,120 --> 00:10:19,460
+اثنين ونص في مئة وستة وخمسين point اثنين خمسة
+
+94
+00:10:19,460 --> 00:10:24,700
+ثلاث
+
+95
+00:10:24,700 --> 00:10:25,560
+مئة وتسعين
+
+96
+00:10:36,880 --> 00:10:40,240
+يعني الـ software mean critical أكثر الثمانية ملي
+
+97
+00:10:40,240 --> 00:10:47,960
+ولا الأربعة ملي ثمانية
+
+98
+00:10:47,960 --> 00:10:55,540
+مو الـ critical معناته من ناحية stress الأربعة ملي
+
+99
+00:10:55,540 --> 00:11:02,260
+أفضل من الثمانية ملي الآن بدنا نفحص الحالة اللي هي
+
+100
+00:11:02,260 --> 00:11:02,940
+عند الفيلت
+
+101
+00:11:06,710 --> 00:11:15,370
+الـ fillet اللي هي case 3 and check at
+
+102
+00:11:15,370 --> 00:11:22,230
+the fillet هنروح
+
+103
+00:11:22,230 --> 00:11:29,250
+للـ fillet طبعاً أن الـ fillet هنا الـ cross section
+
+104
+00:11:29,250 --> 00:11:33,250
+أربعة وثلاثين في اثنين معناته الـ sigma الـ nominal
+
+105
+00:11:37,380 --> 00:11:42,520
+بتساوي اللي هي عشرة آلاف على
+
+106
+00:11:42,520 --> 00:11:57,260
+أربعة وثلاثين في اثنين مئة
+
+107
+00:11:57,260 --> 00:12:08,040
+سبعة وأربعين غلط لأنه هذه صح مئة سبعة وأربعين مئة
+
+108
+00:12:08,040 --> 00:12:14,640
+وسبعه وأربعين ميجا
+
+109
+00:12:14,640 --> 00:12:29,360
+باسكال طيب في عندي stress concentration طيب
+
+110
+00:12:29,360 --> 00:12:33,120
+هنروح
+
+111
+00:12:33,120 --> 00:12:34,300
+على appendix
+
+112
+00:12:37,840 --> 00:12:46,400
+ا خمسة عشر خمسة ا خمسة عشر خمسة
+
+113
+00:12:46,400 --> 00:12:57,440
+بالزمن r على r على دي r على دي بتساوي ال r 
+
+114
+00:12:57,440 --> 00:13:01,540
+دي ال fillet واحد من اللي حلينا على أربعة وثلاثين
+
+115
+00:13:06,630 --> 00:13:11,230
+والزمن دي Capital على
+
+116
+00:13:11,230 --> 00:13:24,490
+دي اللي أربعين على أربعة وثلاثين point
+
+117
+00:13:24,490 --> 00:13:33,850
+o ثلاثة والـ دي Capital على دي واحد point
+
+118
+00:13:36,970 --> 00:13:46,110
+1 8 يعني
+
+119
+00:13:46,110 --> 00:13:50,410
+أول شيء نأخذ الـ R على دي اللي هي point o ثلاثة يعني
+
+120
+00:13:50,410 --> 00:13:52,290
+دي هين point o تقريباً تقريباً هنا
+
+121
+00:14:06,090 --> 00:14:14,750
+والـ D كابيتال على دي واحد ثمانية عشر يعني
+
+122
+00:14:14,750 --> 00:14:20,590
+عند
+
+123
+00:14:20,590 --> 00:14:24,190
+الواحد ثمانية عشر جاب بين واحد point واحد والواحد
+
+124
+00:14:24,190 --> 00:14:30,110
+point خمسة يعني اتطلعت بالشكل هذا لأخذت بالشكل عند
+
+125
+00:14:30,110 --> 00:14:38,440
+أي نقطة عمودي عملت interpolation هتكون واحد point
+
+126
+00:14:38,440 --> 00:14:41,400
+ثمانية عشر المسافة هنا دي فاصلة كم واحد ونص ناقص
+
+127
+00:14:41,400 --> 00:14:47,000
+واحد point واحد كم point أربع point أربع يعني
+
+128
+00:14:47,000 --> 00:14:51,440
+هتكون عندي هنا واحد ونص ناقص واحد point ثمانية عشر
+
+129
+00:14:51,440 --> 00:14:54,960
+على point أربع تاكر إن أنا أحسبه كم واحد ونص
+
+130
+00:14:54,960 --> 00:15:03,240
+ناقص واحد point ثمانية عشر point
+
+131
+00:15:03,240 --> 00:15:10,360
+ثمانية عشر اللي هي واحد point خمسة ناقص واحد point
+
+132
+00:15:10,360 --> 00:15:14,060
+ثمانية عشر بعدين اطلع النتيجة اقسمها على أربع من عشرة
+
+133
+00:15:14,060 --> 00:15:20,260
+point ثمانية يعني point ثمانية تقريباً لو قسمت هذه
+
+134
+00:15:20,260 --> 00:15:24,400
+عشرة اقسم هي قسمين بعدين عندي
+
+135
+00:15:28,550 --> 00:15:36,510
+واحد اثنين ثلاثة أربعة خمسة ستة سبعة ثمانية تسعة
+
+136
+00:15:36,510 --> 00:15:41,110
+عشرة يعني الحاجة هنا الـ curve curve حاجة في منطقة
+
+137
+00:15:41,110 --> 00:15:45,850
+الثمانية من عشرة مظبوط معناته هيكون الـ curve جاي
+
+138
+00:15:45,850 --> 00:15:55,070
+شيء زي هيك أنا بقدر أعمل interpolation يعني هنكون
+
+139
+00:15:55,070 --> 00:15:56,150
+احنا في المنطقة هذه
+
+140
+00:15:59,880 --> 00:16:10,120
+يعني هدي هدي اثنين point ثلاثة الـ Kt سو 
+
+141
+00:16:10,120 --> 00:16:18,980
+اتنين point تلاتة معناته ال sigma max هتكون
+
+142
+00:16:18,980 --> 00:16:24,760
+اتنين point تلاتة في مية و سبعة و اربعين point 
+143
+00:16:24,760 --> 00:16:25,220
+واحد
+
+144
+00:16:41,850 --> 00:16:47,010
+ميجا باسكال أنا 
+
+145
+00:16:47,010 --> 00:16:53,330
+عندي هاي كيس واحد هاي
+
+146
+00:16:53,330 --> 00:16:59,930
+كيس اتنين وهاي
+147
+00:16:59,930 --> 00:17:00,870
+كيس تلاتة
+
+148
+00:17:06,640 --> 00:17:12,800
+لو بدت ارتبهم ترتيب من حيث التأثير أو ارتفاع ال
+
+149
+00:17:12,800 --> 00:17:20,540
+stress هتكون هذه رقم واحد صح وهذه
+
+150
+00:17:20,540 --> 00:17:25,800
+رقم اتنين وهذه
+
+151
+00:17:25,800 --> 00:17:30,260
+رقم تلاتة معناته المصدر كريتيكا لما نكون الثقوب
+
+152
+00:17:30,260 --> 00:17:30,980
+ثمانية ملي
+
+153
+00:17:34,060 --> 00:17:40,480
+يليه يليه الثقب أربع ملي بعده بيجي الفلت اللي هي
+
+154
+00:17:40,480 --> 00:17:45,820
+واحد ملي
+
+155
+00:17:45,820 --> 00:17:56,940
+هاي السؤال متوقع
+
+156
+00:17:56,940 --> 00:18:00,920
+يكسر على الفلت ولا على الثقبع الثقوب يعني stress
+
+157
+00:18:00,920 --> 00:18:06,060
+level أعلى، عالثقوب ثمانية ملي احنا حكينا في
+
+158
+00:18:06,060 --> 00:18:11,000
+الحسابات ال stress فيانا ال stress و strength ال
+
+159
+00:18:11,000 --> 00:18:14,560
+stress ما هي خاص في ال material ال stress اللي
+
+160
+00:18:14,560 --> 00:18:20,260
+خاص في ال loading و ال geometry و نضيف شغلة كمان ال
+
+161
+00:18:20,260 --> 00:18:23,340
+stress concentration loading جيومتري و stress
+
+162
+00:18:23,340 --> 00:18:27,120
+concentration ال strength بتاعة الحديد it is
+
+163
+00:18:27,120 --> 00:18:32,240
+strength قوة الحديد بغض النظر عن ال loading عشان كده
+
+164
+00:18:32,240 --> 00:18:35,120
+أنا بحس ب stress level و بقارنها بال strength
+
+165
+00:18:35,120 --> 00:18:38,020
+بتاعة ال material تحت الدراسة عشان أعرف إن في اندي
+
+166
+00:18:38,020 --> 00:18:44,380
+failure ولا مش failure ال strength
+
+167
+00:18:44,380 --> 00:18:46,840
+اللي علاقة بالجيومتري كيف؟
+
+168
+00:18:52,560 --> 00:18:55,860
+أيوة ال stress level بيختلف باختلاف الجيومترية
+
+169
+00:18:55,860 --> 00:18:59,460
+كويس لأ ما هدك .. هدك مش strength تحكي عليها
+
+170
+00:18:59,460 --> 00:19:06,020
+stress فال stress level يرتفع أو ينخفض بتغير ال
+
+171
+00:19:06,020 --> 00:19:12,780
+loading أو تغير المقطع الجيومتري أو بوجود تركيز
+
+172
+00:19:12,780 --> 00:19:15,040
+إجهادي stress concentration
+
+173
+00:19:37,590 --> 00:19:41,430
+طيب إن خش على ال stress in pressurized cylinders
+
+174
+00:19:41,430 --> 00:19:47,570
+في الاستوانات المضغوطة أنا حينها هأرضى عليكم
+
+175
+00:19:47,570 --> 00:19:51,990
+المعادلات مش مطلوب إنكم اشتقاقها فاندي السيلندر
+
+176
+00:19:51,990 --> 00:19:55,350
+القطر
+
+177
+00:19:55,350 --> 00:20:00,730
+الداخل ر اي اللي هو inner radiusو القطر الخارج
+
+178
+00:20:00,730 --> 00:20:04,750
+لها RO اللي هو ال outside radius يعني في استوانة
+
+179
+00:20:04,750 --> 00:20:09,490
+مفوقة لها قطر داخل ر اي و قطر خارج ر او ال
+
+180
+00:20:09,490 --> 00:20:11,810
+general case إن يكون في pressure جوا و pressure
+
+181
+00:20:11,810 --> 00:20:19,610
+برا pressure جوا و pressure برا من جوا ل pressure
+
+182
+00:20:19,610 --> 00:20:24,870
+جوا الاستوانة قيمته PI اللي هو inside pressure ال
+
+183
+00:20:24,870 --> 00:20:31,350
+pressure برا الاستوانة PO نتيجة ال pressureلو كان
+
+184
+00:20:31,350 --> 00:20:36,450
+برشة من جوه هتحاول استوانة ايش تفتح مظبوط معناته
+
+185
+00:20:36,450 --> 00:20:39,910
+إن في عندي hoop او tangential stress لو أخدت
+
+186
+00:20:39,910 --> 00:20:49,150
+stress element يعني هأكون
+
+187
+00:20:49,150 --> 00:20:56,790
+في عندي tangential stress وعندي
+
+188
+00:21:00,600 --> 00:21:07,820
+radial stress سيجما راديال ال tangential stress
+
+189
+00:21:07,820 --> 00:21:12,700
+موطني علاقة هادئ سيجما ال tangential في سواء P I R
+
+190
+00:21:12,700 --> 00:21:16,240
+I Square minus P O R O Square minus R I Square R O
+
+191
+00:21:16,240 --> 00:21:20,280
+Square في P O minus P I على R Square R هي ال R at
+
+192
+00:21:20,280 --> 00:21:22,480
+any location ال stress at any location at any
+
+193
+00:21:22,480 --> 00:21:27,400
+radial location R على R O تربيع minus R I تربيع
+
+194
+00:21:27,400 --> 00:21:30,600
+ال radial stress is given by this equation P I R I
+
+195
+00:21:30,600 --> 00:21:36,280
+square minus P O R O square زائد اتنين R I square
+
+196
+00:21:36,280 --> 00:21:39,940
+R O square في P O minus P I على ارضي نفس المعادلة
+
+197
+00:21:39,940 --> 00:21:45,680
+بس لحظة اللي بيختلف بس ليش هذا minus هذا plus و
+
+198
+00:21:45,680 --> 00:21:55,000
+المقام نفس المقام R O تربيع minus R I تربيع طيب
+
+199
+00:21:55,000 --> 00:21:56,400
+هناخد special case
+
+200
+00:22:00,600 --> 00:22:03,460
+إنه ما يوجد ضغط خارجي ضغط بس من جوا الأسطوانة
+
+201
+00:22:03,460 --> 00:22:11,560
+ما يوجد ضغط خارجي يعني ال P O ال P O بيساوي Zero
+
+202
+00:22:11,560 --> 00:22:15,560
+ما يوجد ضغط خارجي لما نعود في المعادلة عن P O
+
+203
+00:22:15,560 --> 00:22:25,040
+بيساوى Zero هدا هتروح هدا هروح ترم Zero هدا Zero
+
+204
+00:22:25,040 --> 00:22:30,220
+هدا ايش Zero هتصير ال Sigma تاني جان شال
+
+205
+00:22:33,040 --> 00:22:45,020
+بتساوي P I R I تربيع minus هتدخلين عندي minus
+
+206
+00:22:45,020 --> 00:22:53,980
+minus تصير plus plus R I تربيع
+
+207
+00:22:53,980 --> 00:23:09,470
+R O تربيع في P I على ر تربيع على
+
+208
+00:23:09,470 --> 00:23:19,630
+ر او تربيع minus ر اي تربيع يعني أخدت مشترك بين
+
+209
+00:23:19,630 --> 00:23:31,170
+التلين بي اي ر اي تربيع حيصفي واحدهتبقى عندى P I
+
+210
+00:23:31,170 --> 00:23:36,170
+زائد R O تربيع على
+
+211
+00:23:36,170 --> 00:23:50,170
+R تربيع على R O تربيع minus R I تربيع ليه
+
+212
+00:23:50,170 --> 00:23:55,930
+هذه المعادلة R I تربيع P I على R O تربيع minus R I
+
+213
+00:23:55,930 --> 00:24:00,340
+تربيع في واحد زائد R O تربيع على R تربيع بنفس ال
+
+214
+00:24:00,340 --> 00:24:03,780
+logic بتطلع
+
+215
+00:24:03,780 --> 00:24:08,840
+عندي ال radial stress sigma r يعني هدول ال test
+
+216
+00:24:08,840 --> 00:24:16,240
+نفس الشيء بس يختلف هذا plus هذا ايش minus لإن
+
+217
+00:24:16,240 --> 00:24:25,240
+لو بدى أجيب ال stress distribution على المقطع لإن
+
+218
+00:24:25,240 --> 00:24:30,920
+في عنديعندي ال two extreme conditions اللي هي ر
+
+219
+00:24:30,920 --> 00:24:40,760
+بيستوى ر I و ر بيستوى ر O لما ر بتستوى ر I تكون ال
+
+220
+00:24:40,760 --> 00:24:47,740
+ر O على ر I أكبر من واحد صح؟ لما ر أت
+
+221
+00:24:51,560 --> 00:25:01,020
+ر ر اي تربيع
+
+222
+00:25:01,020 --> 00:25:11,200
+في اي على ر او تربيع minus ر اي تربيع في واحد زائد
+
+223
+00:25:11,200 --> 00:25:16,900
+ر او تربيع على ر اي تربيع
+
+224
+00:25:23,680 --> 00:25:33,080
+طيب at r equal ro بيصير ال sigma tangential بيساوي
+
+225
+00:25:33,080 --> 00:25:41,460
+ر I تربيع في I على ر O تربيع minus ر I تربيع في
+
+226
+00:25:41,460 --> 00:25:47,600
+واحد زائد ايش؟ زائد واحد ال
+
+227
+00:25:47,600 --> 00:25:50,860
+term هذا ال ر O على ر I تربيع أكبر من واحد صح؟
+
+228
+00:25:55,250 --> 00:25:58,910
+معناته ال stress level عند ال inner fiber بيكون
+
+229
+00:25:58,910 --> 00:26:03,230
+أعلى من ال stress level عند ال outer fiber معناته
+
+230
+00:26:03,230 --> 00:26:05,930
+هأكون ال stress distribution high maximum عند ال
+
+231
+00:26:05,930 --> 00:26:17,410
+inner fiber و minimum عند ال outer fiber بالظبط
+
+232
+00:26:17,410 --> 00:26:20,790
+و
+
+233
+00:26:20,790 --> 00:26:31,260
+ال distribution is non linearفي حالة ال sigma r at
+
+234
+00:26:31,260 --> 00:26:38,740
+r equal ri بيصير
+
+235
+00:26:38,740 --> 00:26:48,580
+ال sigma ر عنده بتساوي اللي هي ri تربيع vi على ro
+
+236
+00:26:48,580 --> 00:26:52,740
+تربيع minus ri تربيع في واحد
+
+237
+00:26:58,150 --> 00:27:08,230
+-ro تربيع على ri تربيع هيكون الساوى ر ا ع بيصير
+
+238
+00:27:08,230 --> 00:27:11,810
+negative ال pressure الساوى negative ال pressure
+
+239
+00:27:11,810 --> 00:27:16,070
+لأن أنا هأخذ ر ا ع تربيع مشترك بالسيران دي ر اي
+
+240
+00:27:16,070 --> 00:27:18,930
+تربيع معناس ر تربيع خدها السير بتطلع برا بتطلع ر
+
+241
+00:27:18,930 --> 00:27:22,470
+اي تربيع معناه تربيع و ال bus مع المقام بيستخدم
+
+242
+00:27:22,470 --> 00:27:28,370
+minus P I هذا منطقي لأن أول fiber متعرض للضغط
+
+243
+00:27:28,370 --> 00:27:36,110
+مباشر radially متعرض للضغط مباشر radially at R
+
+244
+00:27:36,110 --> 00:27:40,890
+بيستخدم ر او بتكون
+
+245
+00:27:40,890 --> 00:27:41,830
+دي ال sigma R
+
+246
+00:27:45,430 --> 00:27:52,890
+هتكون ر اي تربيع P I على ر او تربيع minus ر اي
+
+247
+00:27:52,890 --> 00:27:59,750
+تربيع في واحد minus ر او تربيع على ر او تربيع اللي
+
+248
+00:27:59,750 --> 00:28:09,450
+هي ايش؟ Zero.معناته ال pressure عند ال outer fiber
+
+249
+00:28:09,450 --> 00:28:12,870
+Zero و عند ال inner fiber تساوى minus ال P I
+
+250
+00:28:12,870 --> 00:28:13,570
+بالنجاتف
+
+251
+00:28:17,890 --> 00:28:20,030
+و ال distribution بين ال inner fiber و ال outer
+
+252
+00:28:20,030 --> 00:28:26,950
+fiber non-linear non
+
+253
+00:28:26,950 --> 00:28:33,390
+-linear طبعا
+
+254
+00:28:33,390 --> 00:28:41,570
+أنت في حالة الضغط الخارج كان صفر اذا
+
+255
+00:28:41,570 --> 00:28:44,730
+كانت الاستوانة طبعا بفترض كل حسابات الاستوانة تشمل
+
+256
+00:28:44,730 --> 00:28:50,520
+على مفتوحة يعني كأنه خط غاز وماشي لما للنهاية لكن
+
+257
+00:28:50,520 --> 00:28:54,500
+لو كانت الاستوانة مغلقة من الطرفين اذا كانت مغلقة
+
+258
+00:28:54,500 --> 00:28:58,560
+من الطرفين هتصير
+
+259
+00:28:58,560 --> 00:29:04,860
+stress component تالتة
+
+260
+00:29:04,860 --> 00:29:09,060
+عند هذه الاستوانة من جوا
+
+261
+00:29:18,260 --> 00:29:29,480
+هيكون فيه فرشة من كل الجهات هسي
+
+262
+00:29:29,480 --> 00:29:31,900
+لو أخدت مقطع بالاتجاه الطولي فهيعندي stress
+
+263
+00:29:31,900 --> 00:29:35,020
+بالاتجاه الطولي بهذا الاتجاه هيك يعني هذا الاتجاه
+
+264
+00:29:35,020 --> 00:29:41,540
+هأكون sigma L المقطع
+
+265
+00:29:41,540 --> 00:29:57,650
+هذا sigma Lالنقطة هذه هي ر اي ر اي ر او
+
+266
+00:29:57,650 --> 00:30:00,570
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+267
+00:30:00,570 --> 00:30:01,090
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+268
+00:30:01,090 --> 00:30:01,170
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+269
+00:30:01,170 --> 00:30:02,390
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+270
+00:30:02,390 --> 00:30:04,750
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+271
+00:30:04,750 --> 00:30:05,290
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+272
+00:30:05,290 --> 00:30:16,100
+ر او ر او ر او ر او ر او ر او ر او ر او ر اوبي ر
+
+273
+00:30:16,100 --> 00:30:21,160
+اي تربيع عند المقطع هأقعد هأسيء عندي stress level
+
+274
+00:30:21,160 --> 00:30:31,600
+sigma L بيساوي في على ال area في بي ر اي تربيع على
+
+275
+00:30:31,600 --> 00:30:39,800
+ال area هيكون عندي بي ر او تربيع minus بي ر اي
+
+276
+00:30:39,800 --> 00:30:51,070
+تربيع يعني هتصفى بي اي تربيعفي ر اي تربيع على ر او
+
+277
+00:30:51,070 --> 00:30:58,930
+تربيع minus ر اي تربيع ليه
+
+278
+00:30:58,930 --> 00:31:09,470
+هذه المعادلة في حال
+
+279
+00:31:09,470 --> 00:31:11,710
+كانت النبوبة مغلقة
+
+280
+00:31:18,730 --> 00:31:24,670
+طبعا هذا السابق اللي هو thick cylinder theory يعني 
+
+281
+00:31:24,670 --> 00:31:28,530
+بفترض أنه الـ .. الـ .. الـ .. الـ cylinder خملتها
+
+282
+00:31:28,530 --> 00:31:34,550
+كبيرة في حالة كانت الـ cylinder ثمكتها قليلة الـ thin
+
+283
+00:31:34,550 --> 00:31:41,430
+cylinder ممكن نعمل بعض التقريبات الآن في حالة الـ
+
+284
+00:31:41,430 --> 00:31:45,330
+pressure vessels with wall thickness
+
+285
+00:31:48,970 --> 00:31:57,610
+أقل أو يساوي واحد على عشرة الـ mean radius بعتبرها
+
+286
+00:31:57,610 --> 00:32:05,050
+ياش thin wall بعتبرها thin wall في حالة thin wall
+
+287
+00:32:05,050 --> 00:32:13,310
+بيكون عند الـ .. خلّيني أرجع للمعادلة الأصلية هنا
+
+288
+00:32:22,070 --> 00:32:27,310
+لو أخدت الـ Sigma Radial طبعًا الـ thickness هيكون
+
+289
+00:32:27,310 --> 00:32:40,050
+ايه ro ماينص ri صح؟ إذا عند الصورة هنا هذا ro
+
+290
+00:32:40,050 --> 00:32:48,110
+و هذا ri هذا هيكون ايه الـ thickness الـ
+
+291
+00:32:48,110 --> 00:32:53,090
+thickness هيكون سواء ro ماينص riالـ Sigma
+
+292
+00:32:53,090 --> 00:33:03,470
+Radial ستكون تساوي ri تربيع pi على الـ ro تربيع
+
+293
+00:33:03,470 --> 00:33:08,430
+مناسب الـ ri تربيع ستكون
+
+294
+00:33:08,430 --> 00:33:16,730
+ro مانص ri في ro زائد ri ro مانص ri في ro
+
+295
+00:33:16,730 --> 00:33:21,150
+زائد ri
+
+296
+00:33:25,200 --> 00:33:40,820
+في واحد minus ro تربيع على ro تربيع يعني
+
+297
+00:33:40,820 --> 00:33:48,540
+و الـ .. يعني هتكون لسه ri تربيع في pi على الـ
+
+298
+00:33:48,540 --> 00:33:52,680
+thickness الـ ro زائد الـ ri
+
+299
+00:33:56,610 --> 00:34:01,830
+الـ ro زائد الـ ri لو حكيت الـ r مين الـ r مين هتكون
+
+300
+00:34:01,830 --> 00:34:11,270
+تستوياش ro زائد ri على اتنين فهنا الـ ro زائد r
+
+301
+00:34:11,270 --> 00:34:19,110
+i هتستوياش في اتنين اه الـ mean radius rm
+
+302
+00:34:25,110 --> 00:34:31,430
+في 1-ro تربيه على ro تربيه أنا دي أحاول أريكوا أن
+
+303
+00:34:31,430 --> 00:34:38,270
+الـ stigma r هتكون أقل بكثير من اللي
+
+304
+00:34:38,270 --> 00:34:47,470
+هو بالضبط أو ممكن تأخذ الـ limit limit
+
+305
+00:34:47,470 --> 00:34:52,330
+as r
+
+306
+00:34:56,650 --> 00:35:08,910
+طلع أنت هنا يعني هدول ثابت هذا ثابت وهذا ثابت لحظة
+
+307
+00:35:08,910 --> 00:35:14,190
+الـ ro تربيع لما تكون قريبة كثير من الـ ri تربيع
+
+308
+00:35:14,190 --> 00:35:22,250
+الـ term هذا ايش معلومة بيكبر بيكبر بيكبر كثير بيكبر
+
+309
+00:35:22,250 --> 00:35:27,520
+معناه لو واحد ناقص الرقم بيصغر كثير بيقرب من الصفر
+
+310
+00:35:27,520 --> 00:35:33,580
+هي أن عندي plus يعني anyway هذا is insignificant
+
+311
+00:35:33,580 --> 00:35:36,780
+أو هيكون insignificant بالنسبالي للواحد فبتصيرها
+
+312
+00:35:36,780 --> 00:35:40,480
+تقريبًا واحد زائد هي تقريبًا بيصير اتنين يعني هاد
+
+313
+00:35:40,480 --> 00:35:44,420
+بيصير قريب من الواحد واحد زائد واحد اتنين هاد قريب
+
+314
+00:35:44,420 --> 00:35:48,280
+من الواحد وأنا طوأ يعني قريبة الصفر هتكون الـ sigma
+
+315
+00:35:48,280 --> 00:35:55,020
+r كل ما قلت السمكة بيصير small compared بال
+
+316
+00:35:55,020 --> 00:36:02,960
+tangential stress طبعًا هيكون دي still still الـ
+
+317
+00:36:02,960 --> 00:36:09,560
+distribution is nonlinear بس
+
+318
+00:36:09,560 --> 00:36:12,100
+الـ thickness بقى دي المكان ايش زيك هيصير ايش صغير
+
+319
+00:36:14,290 --> 00:36:20,090
+هتكون ايش ايه؟ صغير فهحسب اللي هو sigma average الـ
+
+320
+00:36:20,090 --> 00:36:24,330
+average tangential stress الـ sigma tangential
+
+321
+00:36:24,330 --> 00:36:28,410
+average طب هتعوض .. هتعوض ايه؟ هتعوض مرة r
+
+322
+00:36:28,410 --> 00:36:33,730
+بالستويه ri و مرة r بالستويه ro بقى أنت تحكي
+
+323
+00:36:33,730 --> 00:36:36,650
+sigma average الـ .. الـ .. الـ .. الـ sigma
+
+324
+00:36:36,650 --> 00:36:44,290
+tangential i زي الـ sigma tangential o على اتنين و
+
+325
+00:36:44,290 --> 00:36:49,230
+بعدين بتحول الـ radius لـ الـ diameters يعني الـ di
+
+326
+00:36:49,230 --> 00:36:52,710
+بيستوى اتنين الـ ri بيطلع عندي الـ sigma tangential
+
+327
+00:36:52,710 --> 00:36:56,570
+average pdi على اتنين t p اللي هو الـ pressure جوا
+
+328
+00:36:56,570 --> 00:36:59,350
+الاستوانة الـ di اللي هو الـ inner diameter
+
+329
+00:36:59,350 --> 00:37:06,930
+للاستوانة و الـ t thickness بتاع الاستوانة و الـ
+
+330
+00:37:06,930 --> 00:37:10,670
+sigma t maximum الـ maximum tangential stress هيكون
+
+331
+00:37:11,550 --> 00:37:19,510
+p di زائد t على اتنين t الاسترس الطولي هيكون سيجم
+
+332
+00:37:19,510 --> 00:37:31,610
+ألو سواء pdi على أربع t pdi على أربع t تشوف
+
+333
+00:37:31,610 --> 00:37:32,050
+مثال
+
+334
+00:37:39,300 --> 00:37:44,000
+الألمنيوم اللاوي pressure vessel is made of tubing
+
+335
+00:37:44,000 --> 00:37:46,720
+having an outside diameter of eight inch and a
+
+336
+00:37:46,720 --> 00:37:52,940
+wall thickness of quarter inch عندي pressure
+
+337
+00:37:52,940 --> 00:38:00,460
+vessel خزان ضغط مصنوع من سبيكة ألمنيوم أو انبوب
+
+338
+00:38:00,460 --> 00:38:02,780
+ألمنيوم قطرها الخارجي ثمانية انش
+
+339
+00:38:11,200 --> 00:38:17,380
+القطر الخارجي ثمانية
+
+340
+00:38:17,380 --> 00:38:31,380
+انش والسماكة الانبوب ربع انش water
+
+341
+00:38:31,380 --> 00:38:35,480
+pressure can the cylinder carry؟ ايش في مطبخته
+
+342
+00:38:35,480 --> 00:38:40,240
+ممكن الـ cylinder اتشيله؟F permissible tangential
+
+343
+00:38:40,240 --> 00:38:47,040
+stress sigma tangential permissible المسموح فيه
+
+344
+00:38:47,040 --> 00:38:57,120
+بتساوي إثنا عشر كيلو pound لكل square inch and
+
+345
+00:38:57,120 --> 00:39:00,380
+theory for thin walled vessels is assumed to apply
+
+346
+00:39:00,380 --> 00:39:03,660
+نظرية الـ thin walled vessels thin walled cylinders
+
+347
+00:39:03,660 --> 00:39:08,970
+apply متأكد applies or not applyعند الـ radius أكم
+
+348
+00:39:08,970 --> 00:39:16,910
+بيستوي الـ ro بيستوي
+
+349
+00:39:16,910 --> 00:39:27,310
+أربعة انش الـ ri أكم بيستوي ثلاثة
+
+350
+00:39:27,310 --> 00:39:36,820
+و خمسة وسبعين والـ rm هكون ثلاثة بنت يعني دي
+
+351
+00:39:36,820 --> 00:39:40,160
+خمسة عشر على اتنين سبعة ونصف ثلاثة point ثمانية
+
+352
+00:39:40,160 --> 00:39:45,020
+اتنين وخمسة مظبوط انش
+
+353
+00:39:45,020 --> 00:39:49,020
+يعني
+
+354
+00:39:49,020 --> 00:39:54,680
+الـ rm على الـ thickness سواء ثلاثة point ثمانية
+
+355
+00:39:54,680 --> 00:40:04,660
+اتنين وخمسة على ربع يعني هتكون أكبر من عشرة أكبر من
+
+356
+00:40:04,660 --> 00:40:08,320
+عشرة يعني
+
+357
+00:40:08,320 --> 00:40:11,820
+تقريبًا أربعة في أربعة ستة عشر حوالي الخمسة عشر point
+
+358
+00:40:11,820 --> 00:40:15,920
+something فواضح أنه الـ thickness أقل من العشرة
+
+359
+00:40:15,920 --> 00:40:22,200
+بيعناته ممكن نستخدم الـ thin wall cylinder theory
+
+360
+00:40:23,920 --> 00:40:28,480
+في حالة الـ thin walled cylinders theory الـ sigma
+
+361
+00:40:28,480 --> 00:40:34,720
+tangential maximum اللي
+
+362
+00:40:34,720 --> 00:40:47,700
+هي بالساوية الـ p في di زائد t على 2t عند الـ طبعًا
+
+363
+00:40:47,700 --> 00:40:53,300
+هتساوي الـ sigma tangential permissible
+
+364
+00:40:55,400 --> 00:41:04,020
+الـ di الـ di هتكون اتنين في ثلاثة point سبعة
+
+365
+00:41:04,020 --> 00:41:12,900
+خمسة يعني سبعة ونصف يعني
+
+366
+00:41:12,900 --> 00:41:21,820
+الـ pressure هيكون sigma tangential permissible في
+
+367
+00:41:21,820 --> 00:41:31,670
+اتنين t على di زائد t يعني أنا حاجز ساوي اتنين في
+
+368
+00:41:31,670 --> 00:41:35,970
+اتماش في
+
+369
+00:41:35,970 --> 00:41:41,090
+الـ thickness ربع انش على
+
+370
+00:41:41,090 --> 00:41:49,050
+الـ di اللي هي سبعة ونصف زائد ربع
+
+371
+00:41:50,510 --> 00:41:57,210
+يعني عندي ربع في اتنين ونصف، في اثنا عشر، ستة، أكم؟
+
+372
+00:41:57,210 --> 00:42:05,410
+point سبعة سبعة أربعة point سبعة سبعة أربعة kilo
+
+373
+00:42:05,410 --> 00:42:10,880
+pound per square inch هذا الضغط اللي ممكن تشيله
+
+374
+00:42:10,880 --> 00:42:16,900
+الاستوانة إذا الـ max الـ permissible tangential
+
+375
+00:42:16,900 --> 00:42:19,560
+stress طبعًا في بعض الكتب ما بيسموه tangential
+
+376
+00:42:19,560 --> 00:42:36,040
+بيسموه hoop stress hoop طيب
+
+377
+00:42:39,330 --> 00:42:44,010
+هذا المطبوق الأول on the basis of pressure found
+
+378
+00:42:44,010 --> 00:42:47,610
+in part a بناء على قيمة الضغط اللي حسبناها في
+
+379
+00:42:47,610 --> 00:42:54,770
+الجزء a compute stress components using stress for
+
+380
+00:42:54,770 --> 00:43:01,170
+thick walled cylinders احسب الـ stresses بناء على
+
+381
+00:43:01,170 --> 00:43:05,450
+الـ pressure اللي احنا عارفينه اعتمادًا على نظريتي الـ
+
+382
+00:43:05,450 --> 00:43:11,020
+thick walls يعني هنستخدم المعادلة هذه الـ sigma
+
+383
+00:43:11,020 --> 00:43:15,820
+tangential هتكون طبقا للـ thick wall sigma
+
+384
+00:43:15,820 --> 00:43:22,340
+tangential maximum وين
+
+385
+00:43:22,340 --> 00:43:30,700
+هتكون عند الـ r بيستوي ri صح هتكون سواء ri تربيع
+
+386
+00:43:30,700 --> 00:43:40,270
+pi على ro تربيع minus ri تربيع في واحد زائد ro
+
+387
+00:43:40,270 --> 00:43:48,450
+تربيع على ri تربيع هتكون تساوي الـ ri اللي هي ثلاثة
+
+388
+00:43:48,450 --> 00:43:53,490
+bond سبعة خمسة تربيع
+
+389
+00:43:53,490 --> 00:44:03,490
+في bond سبعة أربعة على أربعة تربيع minus ثلاثة
+
+390
+00:44:03,490 --> 00:44:13,530
+bond سبعة خمسة تربيع في واحد زائد أربعة تربيع على
+
+391
+00:44:13,530 --> 00:44:24,290
+ثلاثة point سبعة خمسة تربيع أكم تطلع اتماش
+
+392
+00:44:24,290 --> 00:44:34,000
+point بس أكم صفر الصفر صفر يعني واضح قريب كثير من
+
+393
+00:44:34,000 --> 00:44:38,020
+الـ permissible معناته النظرية يعني is accurate
+
+394
+00:44:38,020 --> 00:44:44,660
+enough الـ sigma radial طبعًا الـ sigma radial
+
+395
+00:44:44,660 --> 00:44:47,040
+maximum هتكون جوا هتكون minus pi في جدا احسب
+
+396
+00:44:47,040 --> 00:44:51,260
+sigma radial maximum
+
+397
+00:44:51,260 --> 00:44:58,400
+so minus pi اللي هي minus إثنا عشر كيلو pound بال
+
+398
+00:44:58,400 --> 00:45:05,580
+square inch فواضح أنه أفرض هذه الصح لأن هي الـ more
+
+399
+00:45:05,580 --> 00:45:09,540
+accurate theory يعني
+
+400
+00:45:09,540 --> 00:45:15,660
+الـ percentage difference هذا هو أو percentage
+
+401
+00:45:15,660 --> 00:45:24,700
+difference ولا percentage error difference
+
+402
+00:45:24,700 --> 00:45:25,260
+ولا error
+
+403
+00:45:28,010 --> 00:45:30,530
+difference it's not error الـ error ده يعني بيكون
+
+404
+00:45:30,530 --> 00:45:38,550
+الـ true value minus الـ observed value أو الـ .. ف
+
+405
+00:45:38,550 --> 00:45:43,810
+.. فاحنا ما بنعرفش هد .. هد theory و هد theory it's
+
+406
+00:45:43,810 --> 00:45:48,910
+a mathematical model فانا قلتوا هد ممكن تكون أقرب
+
+407
+00:45:48,910 --> 00:45:52,550
+للاش للـ true فانا قلت أنا هحس الـ difference
+
+408
+00:45:52,550 --> 00:45:57,120
+between this theory and this theory الـ difference
+
+409
+00:45:57,120 --> 00:46:02,040
+هتكون 12.009
+
+410
+00:46:02,040 --> 00:46:12,840
+-12 على 12.009 في المية سبوها
+
+411
+00:46:12,840 --> 00:46:18,520
+point 0
+
+412
+00:46:18,520 --> 00:46:27,970
+.75 في المية يعني اختلاف بين الـ thin أجيد الـ بيغان
+
+413
+00:46:27,970 --> 00:46:35,450
+مش اثنا عشر سبعة مية وأربعة وسبعين ايش الوحدات بس كده
+
+414
+00:46:35,450 --> 00:46:40,910
+فيه أسئلة فيه أسئلة أنا ايش كاتب هنا كيلو كيلو بقى
+
+415
+00:46:40,910 --> 00:46:43,430
+ده لازم تقوله لازم تقوله لازم تقوله لازم تقوله
+
+416
+00:46:43,430 --> 00:46:45,410
+لازم تقوله لازم تقوله لازم تقوله لازم تقوله
+
+417
+00:46:45,410 --> 00:46:46,370
+لازم تقوله لازم تقوله لازم تقوله لازم تقوله
+
+418
+00:46:46,370 --> 00:46:52,330
+لازم تقوله لازم تقوله لازم تقوله لاز
+
+419
+00:46:55,290 --> 00:47:03,350
+طبعًا بالضبط صحيح سالب point سبعة سبعة أربعة kilo
+
+420
+00:47:03,350 --> 00:47:08,550
+pound per square inch صحيح طيب الـ difference 
+
+421
+00:47:08,550 --> 00:47:13,470
+between the two theories is not significant ليس ذا 
+
+422
+00:47:13,470 --> 00:47:20,450
+أهمية الفرق point O سبعة خمسة ثلاثة في المئة أنا
+
+423
+00:47:20,450 --> 00:47:23,710
+قلت لو زاد stress عام اتماشي
+
+424
+00:47:29,120 --> 00:47:33,920
+لأ أنت مش مسموح لك تتخطى هذه يعني أنت حاطط أنت
+
+425
+00:47:33,920 --> 00:47:38,380
+كمصمم أنت تحكي ال permissible بمعناه هذه حاطط
+
+426
+00:47:38,380 --> 00:47:41,080
+some factor of safety حاطط عامل الأمان مثلا أنت
+
+427
+00:47:41,080 --> 00:47:43,460
+حاطط عامل الأمان على سبيل المثال إحنا مش عارفين ال
+
+428
+00:47:43,460 --> 00:47:48,420
+material عامل الأمان مثلا أنت حاطط مثلا اثنين إذا
+
+429
+00:47:48,420 --> 00:47:52,540
+زادت ال sigma عن اثنا عشر بمعناه هينزل عن عامل الأمان
+
+430
+00:47:52,540 --> 00:47:56,370
+اللي أنت حاططه هينزل factor of safety هذا لا يعني أن
+
+431
+00:47:56,370 --> 00:48:01,110
+نصير failure لا يعني إيه نصير failure إلا إذا كان
+
+432
+00:48:01,110 --> 00:48:04,950
+ال factor of safety مش مساويه واحد فمش مهم إذا
+
+433
+00:48:04,950 --> 00:48:10,870
+جيت إحنا بيبقى بال stress على حسب ما اتكرر بالعرض
+
+434
+00:48:10,870 --> 00:48:15,730
+بيختلف على طول صح ولا لا؟ كيف يعني؟ لأنه مرة جيت
+
+435
+00:48:15,730 --> 00:48:22,990
+بالوكالة إيه أما كنا بتجسس من ال diploma عملنا 
+
+436
+00:48:22,990 --> 00:48:28,570
+تحليل على اللي هو ال man hole .. إيش هو .. لل
+
+437
+00:48:28,570 --> 00:48:33,410
+exhaust تبع ال .. تبع ال .. ال gas  درعين تمام؟ اه
+
+438
+00:48:33,410 --> 00:48:37,930
+ال man hole عملنا مرة بالعرض ومرة بالطول ماشي
+
+439
+00:48:37,930 --> 00:48:41,430
+أنا هيبقى أحكيلك أنت عندك الطول ال man hole أو
+
+440
+00:48:41,430 --> 00:48:44,210
+هو اللي هو الطول اللي طالع منه ال exhaust gases
+
+441
+00:48:44,210 --> 00:48:49,370
+ما
+
+442
+00:48:49,370 --> 00:49:02,280
+هو بيختلف أكيد عندك هاي الأسطوانة ب 3D اسطوانة
+
+443
+00:49:02,280 --> 00:49:07,100
+مفتوحة تعبتها كنت ولا مسكرة مفتوحة يعني ما فيه ضغط
+
+444
+00:49:07,100 --> 00:49:18,880
+جوا لأن فيها thickness كمان وفي
+
+445
+00:49:18,880 --> 00:49:19,460
+جوا ضغط
+
+446
+00:49:22,390 --> 00:49:25,430
+لو أخذت stress element بس من جوا أخذت stress element
+
+447
+00:49:25,430 --> 00:49:30,330
+يعني احتسبت هذا المقطع أخذت stress element هنا
+
+448
+00:49:30,330 --> 00:49:35,610
+stress
+
+449
+00:49:35,610 --> 00:49:46,810
+element هطلع برة هحكي هذا ال X هذا ال Y وهذا ال Z
+
+450
+00:49:46,810 --> 00:49:55,160
+ال stress element هرسمه هذه الموازنة ال X axis وهذه
+
+451
+00:49:55,160 --> 00:50:10,640
+ال Y axis وهذه ال Z axis هذا
+
+452
+00:50:10,640 --> 00:50:18,140
+اللي لما اتكبرته هيكون
+
+453
+00:50:18,140 --> 00:50:19,740
+باتجاه ال Z
+
+454
+00:50:23,190 --> 00:50:29,150
+في هندي في sigma tangential اللي هي sigma z في
+
+455
+00:50:29,150 --> 00:50:34,510
+الحلقة هذه فهو هندي هين اللي هو ده هو اللي هو ب
+
+456
+00:50:34,510 --> 00:50:39,970
+stress بيحاول يمزق الأنبوب بشكل هذا وفي هندي لو
+
+457
+00:50:39,970 --> 00:50:46,250
+كأخدت هندي هندي هنحكي أنه هندي في ال Y sigma
+
+458
+00:50:46,250 --> 00:50:52,030
+R و sigma R الأنبوب مفتوح
+
+459
+00:50:55,840 --> 00:51:00,220
+مفتوح مانعته الغازات المضغوطة بتطلع ماشي تطلع على
+
+460
+00:51:00,220 --> 00:51:04,140
+ال .. على وين؟ على الهواء الخارجي مانعته ال
+
+461
+00:51:04,140 --> 00:51:09,560
+gauge pressure إيش ساعة؟ صفر فبتعملش stress بهذا
+
+462
+00:51:09,560 --> 00:51:16,520
+الاتجاه نظريا بس هو في الواقعية ألا يكون في الحقب
+
+463
+00:51:16,520 --> 00:51:21,080
+أو عرض الواقع ألا يكون في تصميم للمتّلل stress لأنه
+
+464
+00:51:21,080 --> 00:51:26,520
+في حرارة كمان لا تنسى في عنده حرارة ال
+
+465
+00:51:26,520 --> 00:51:30,480
+temperature distribution مش منتظم بيصير تمددات
+
+466
+00:51:30,480 --> 00:51:38,700
+طولية وقطرية التمددات ممكن تعمل إجهادات جوابتك على
+
+467
+00:51:38,700 --> 00:51:45,340
+سؤالك؟ هو نفس الدكتور في في design ال manhole نفسه
+
+468
+00:51:45,340 --> 00:51:49,560
+في أي .. في أي application، في أحيانًا بعمل manhole
+
+469
+00:51:49,560 --> 00:51:56,750
+على شكل بيضاوي بنجي بشكل بيضاوي؟ أنت بتحكي المنهول
+
+470
+00:51:56,750 --> 00:52:01,310
+إيش تاني اللي هو المنهول اللي هو المنهول اللي هو
+
+471
+00:52:01,310 --> 00:52:01,970
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+472
+00:52:01,970 --> 00:52:02,990
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+473
+00:52:02,990 --> 00:52:03,010
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+474
+00:52:03,010 --> 00:52:03,290
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+475
+00:52:03,290 --> 00:52:06,610
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+476
+00:52:06,610 --> 00:52:09,990
+المنهول
+
+477
+00:52:09,990 --> 00:52:13,790
+اللي هو المنه
+
+478
+00:52:26,070 --> 00:52:35,870
+بشكل بيضاوي وأخذت إيش stress element هيكون
+
+479
+00:52:35,870 --> 00:52:41,490
+فيه two surfaces أو عندنا هاي stress component
+
+480
+00:52:41,490 --> 00:52:49,290
+tension و stress component tension وفي واحدة منهم
+
+481
+00:52:49,290 --> 00:52:54,790
+هتكون عاشيعني ممكن نعتبر هذه hoop stress وهذه
+
+482
+00:52:54,790 --> 00:52:57,790
+hoop stress بس في two directions two hoop stress
+
+483
+00:52:57,790 --> 00:53:01,090
+component هذه في حالة spherical coordinates
+
+484
+00:53:01,090 --> 00:53:06,410
+هتستخدم إحداثيات spherical
+
+485
+00:53:06,410 --> 00:53:16,270
+اه ال sigma r
+
+486
+00:53:16,270 --> 00:53:17,810
+اللي لأن في اتجاه ال y
+
+487
+00:53:21,100 --> 00:53:25,080
+الـ Sigma Z هي بتحاول تفتحها بالشكل هذا فبصي تعمل
+
+488
+00:53:25,080 --> 00:53:28,840
+إيش؟ هو في stress أو تنجلش ال stress Sigma تنجلشها
+
+489
+00:53:28,840 --> 00:53:34,780
+في الاتجاه الطولي مش مغلق أنبوب بطلع ما فيش ضغط
+
+490
+00:53:34,780 --> 00:53:37,180
+ما فيش ضغط بهذا الاتجاه اللي يعمل stress بهذا
+
+491
+00:53:37,180 --> 00:53:43,860
+الاتجاه لكن في ضغط داخل هنا Sigma I باتجاه ال Y
+
+492
+00:53:43,860 --> 00:53:46,840
+axis طبعًا المفروض أنا آخذ ال element آخذه هنا
+
+493
+00:53:55,030 --> 00:54:03,230
+الشيء المهم في الـ inner fibre هي
+
+494
+00:54:03,230 --> 00:54:06,550
+الـ
+
+495
+00:54:06,550 --> 00:54:07,770
+sigma tangential maximum
+
+496
+00:54:10,830 --> 00:54:15,870
+اللي هو إيش؟ sigma radial المفروض أنا أعمل طبعًا
+
+497
+00:54:15,870 --> 00:54:19,310
+لازم أخش تفاصيل بعد هيك المفروض أعمل اللي هو
+
+498
+00:54:19,310 --> 00:54:24,410
+ال Mohr's circle أنا عارف sigma واحد اللي أنا برتب
+
+499
+00:54:24,410 --> 00:54:27,390
+sigma واحد و sigma اثنين و sigma ثلاثة بيحس إن
+
+500
+00:54:27,390 --> 00:54:29,970
+sigma واحد أكبر من sigma اثنين أكبر من sigma ثلاثة
+
+501
+00:54:29,970 --> 00:54:32,130
+sigma اثنين في الحالة .. sigma واحد في الحالة
+
+502
+00:54:32,130 --> 00:54:35,770
+بتكون إيش؟ sigma اثنين general sigma اثنين بتكون
+
+503
+00:54:35,770 --> 00:54:38,770
+سواء صفر و sigma ثلاثة اللي هي minus ال pressure
+
+504
+00:54:40,270 --> 00:54:43,370
+بعدين يا بستخدم الحصر theory بستخدمها لو بدي
+
+505
+00:54:43,370 --> 00:54:47,030
+أستخدم ال maximum shear stress theory بحسب ال
+
+506
+00:54:47,030 --> 00:54:49,050
+maximum shear stress اللي هو sigma واحد معناه
+
+507
+00:54:49,050 --> 00:54:53,770
+sigma ثلاثة على اثنين اللي هتكون اللي هي sigma
+
+508
+00:54:53,770 --> 00:54:58,630
+tangential minus minus هتصير يعني هتكون sigma
+
+509
+00:54:58,630 --> 00:55:02,310
+tangential زائد ال PI على اثنين تحصر maximum shear
+
+510
+00:55:02,310 --> 00:55:06,330
+ومن هنا بتكمل خيوط ما نستبقش الأمور هذا الكلام في
+
+511
+00:55:06,330 --> 00:55:07,870
+chapter 5 اللي بنحكي عنه
+
+512
+00:55:23,470 --> 00:55:27,610
+طيب ممكن نستخدم ال .. ال .. ال .. ال theory of
+
+513
+00:55:27,610 --> 00:55:31,930
+thick cylinder نطبقها بطريقة ثانية في حالة عندي
+
+514
+00:55:31,930 --> 00:55:38,030
+rotating rings عندي ring rotating rings زي .. زي
+
+515
+00:55:38,030 --> 00:55:46,040
+ال fly wheels بتطور بسرعة ال blowers شفاطة الهواء
+
+516
+00:55:46,040 --> 00:55:50,680
+زي ال discs بتكون دور نتيجة طرد .. نتيجة طرد إذا
+
+517
+00:55:50,680 --> 00:55:56,680
+عندي أي جسم بدور disc بشكل هذا بدور
+
+518
+00:55:56,680 --> 00:56:06,040
+بسرعة زي omega يحسيه القوة طرد مركزه برة فحسيه
+
+519
+00:56:06,040 --> 00:56:10,320
+اللي عندي إيش stresses ال .. إذا بتلاحظوا
+
+520
+00:56:10,320 --> 00:56:20,350
+المولينكس القديم المولينكس القديم شاف المولينكس هذه
+
+521
+00:56:20,350 --> 00:56:30,510
+الشفرات هنا هذا
+
+522
+00:56:30,510 --> 00:56:38,510
+الشاف وعندي FPG عندي
+
+523
+00:56:38,510 --> 00:56:40,010
+العمود
+
+524
+00:56:43,450 --> 00:56:49,190
+هو العمود جاي من مطر بيلف كانت تكون هذه إيش ال
+
+525
+00:56:49,190 --> 00:56:53,670
+material بتاعتها القديمة
+
+526
+00:56:53,670 --> 00:57:00,190
+مطر لما بيدور هذه أنت بدخله فيه فراغ لما بتدور
+
+527
+00:57:00,190 --> 00:57:09,130
+إيش تفتح بتسكر عن هذه تدور معها طبعًا فتحت نتيجة
+
+528
+00:57:09,130 --> 00:57:13,780
+قوة الطرد المركزي في عندي normal ازاي الـ
+
+529
+00:57:13,780 --> 00:57:17,340
+centrifugal clutch بالضبط ازاي ال clutch ال
+
+530
+00:57:17,340 --> 00:57:23,820
+centrifugal فهذه بتفتح وبتمسك عليها فنفس الإشي
+
+531
+00:57:23,820 --> 00:57:28,980
+discs يعني هذه بتلاحظوا يعني مجرد إذا بتشغل ال
+
+532
+00:57:28,980 --> 00:57:37,780
+motor بتبين عادة معك يعني بتفتح نفس الفكرة في ال
+
+533
+00:57:37,780 --> 00:57:42,860
+discs إنها تجد قوة الطرد المركزي بس عند a normal هي
+
+534
+00:57:42,860 --> 00:57:52,140
+omega square في R هذه المسافة R حاسس إن عندي كمان
+
+535
+00:57:52,140 --> 00:57:57,140
+force قوة طرد مركزي برة اللي هي بيكون سواء M
+
+536
+00:57:57,140 --> 00:58:02,240
+omega square في R اللي هي A normal في H في R
+
+537
+00:58:06,930 --> 00:58:10,730
+فنتيجة قوة الطرد المركزي هتصير عندي tangential
+
+538
+00:58:10,730 --> 00:58:14,610
+stresses و radial stresses في ال disk أو ال
+
+539
+00:58:14,610 --> 00:58:21,150
+flywheel أو ال blower فهتصير عندي tangential و
+
+540
+00:58:21,150 --> 00:58:27,010
+radial stresses فبيصير
+
+541
+00:58:27,010 --> 00:58:33,930
+كأنه أنا I apply pressures زي نفس فكرة ال thick
+
+542
+00:58:33,930 --> 00:58:40,610
+walled pressure cylinders اللي بيختلف الاختلاف إن
+
+543
+00:58:40,610 --> 00:58:44,890
+ال pressure ناتج عن inertia forces في حالة ال
+
+544
+00:58:44,890 --> 00:58:48,110
+thick cylinders ال pressure ناتج عن غازات أو سوائل
+
+545
+00:58:51,130 --> 00:58:55,030
+ال .. ال .. ال conditions outside radius is larger
+
+546
+00:58:55,030 --> 00:58:59,210
+.. large compared with thickness يعني هنا أساس أنه
+
+547
+00:58:59,210 --> 00:59:02,390
+ال thickness is constant المعادلات الجاية هشوفها
+
+548
+00:59:02,390 --> 00:59:06,050
+stresses are constant over the thickness الإجهادات
+
+549
+00:59:06,050 --> 00:59:08,450
+هتكون ثابتة على ال thickness هذه الفرضيات
+
+550
+00:59:08,450 --> 00:59:15,190
+للمعادلات الجاية إذا عندي disk
+
+551
+00:59:15,190 --> 00:59:18,910
+.. disk هي disk مفتوحة
+
+552
+00:59:20,450 --> 00:59:27,890
+يعني لديه radius داخلي راي لديه radius خارجي ر أو
+
+553
+00:59:27,890 --> 00:59:38,330
+بدور بسرعة زاوية أميجا سيكون هناك stress
+
+554
+00:59:38,330 --> 00:59:44,830
+طولية سيجما تنجينشيل وسيجما
+
+555
+00:59:47,560 --> 00:59:51,560
+معطاب للعلاقة هذه sigma tangential rho omega
+
+556
+00:59:51,560 --> 00:59:54,500
+square اللي هي رو ال density للمaterial بتاعة ال
+
+557
+00:59:54,500 --> 00:59:58,680
+disk ال omega السرعة الذهاب دورها ال disk في تلاتة
+
+558
+00:59:58,680 --> 01:00:03,540
+زي نيو على ثمانية نيو اللي هي ال Poisson ratio في
+
+559
+01:00:03,540 --> 01:00:07,120
+ر I square زي ر أسكوير زي ر I square ر اسكوير على
+
+560
+01:00:07,120 --> 01:00:10,080
+ر اسكوير ناقص واحد زي تلاتة نيو على تلاتة زي نيو 
+
+561
+01:00:10,080 --> 01:00:14,140
+في رأسكويرنفس مش المعادلة هذه لل radial stresses
+
+562
+01:00:14,140 --> 01:00:21,080
+نفس المعادلة تختلف هذه plus minus بس ال term هذا و
+
+563
+01:00:21,080 --> 01:00:24,660
+ال term هذا مختلف عن هذا ال term يعني ال term
+
+564
+01:00:24,660 --> 01:00:27,460
+الأول و الثاني نفس الأشياء ال term الثالث نفس
+
+565
+01:00:27,460 --> 01:00:31,040
+الأشياء بس بختلف الإشارة مختلف ال term الثالث قيمة
+
+566
+01:00:31,040 --> 01:00:36,730
+مختلفة. نتيجة الـ rotation عند سرعة عالية بـ
+
+567
+01:00:36,730 --> 01:00:39,450
+cylindrical tangential أو radial stresses due to
+
+568
+01:00:39,450 --> 01:00:47,950
+inertial forces قوة القصور الذاتي الآن
+
+569
+01:00:47,950 --> 01:00:54,170
+إذا عندي أنا الموضوع الثاني على ال press و ال
+
+570
+01:00:54,170 --> 01:01:00,450
+shrink fit ال
+
+571
+01:01:00,450 --> 01:01:07,760
+press fit أنا بكون عندي shaft و hole ال shaft بكون
+
+572
+01:01:07,760 --> 01:01:11,360
+قطره أكبر من ال hole بحشره حشر في أيّاش ال hole فده
+
+573
+01:01:11,360 --> 01:01:19,580
+press fit by force ال shrink fit ببرد الشافت أو و
+
+574
+01:01:19,580 --> 01:01:26,640
+بسخن أيّاش ال hole بتمدد لما نبرد بيصير ضغط عليه
+
+575
+01:01:27,510 --> 01:01:29,730
+طبعًا بتعمل ال friction يعني ال normal force بتعمل
+
+576
+01:01:29,730 --> 01:01:31,950
+ال friction ال force يعني بتقاوم ال torque بشكل
+
+577
+01:01:31,950 --> 01:01:37,230
+كبير جدًّا. معظم ال gear boxes حاليًا معمولة اللي هو ال
+
+578
+01:01:37,230 --> 01:01:42,330
+gears مثبتة باستخدام shrink fit طبعًا shrink fit
+
+579
+01:01:42,330 --> 01:01:48,410
+ميزته بيعطيني high torque capacity رقم واحد رقم
+
+580
+01:01:48,410 --> 01:01:53,670
+اثنين مش محتاج أعمل key ways مجارة المجارة تعمل
+
+581
+01:01:53,670 --> 01:01:57,640
+stress concentration بستغنى عنها و التركيبة في ال
+
+582
+01:01:57,640 --> 01:02:04,140
+mass production أسرع و أسهل منها في حالة بدها مش
+
+583
+01:02:04,140 --> 01:02:08,920
+machining كثير على ال mechanical parts في عندي ..
+
+584
+01:02:08,920 --> 01:02:15,480
+عندي .. عندي .. عندي هاي shaft و عندي هاي hole ال
+
+585
+01:02:15,480 --> 01:02:22,280
+hole أو الشافت .. هاي الشافت الشافت مثقوب فيه ثقوب
+
+586
+01:02:24,160 --> 01:02:32,040
+في له r صغير و في 
+
+587
+01:02:32,040 --> 01:02:44,120
+له common radius R كابيتال و في ال whole له r أو
+
+588
+01:02:49,650 --> 01:02:54,870
+الآن نتيجة أنه في تداخل بين ال shaft و ال hole في
+
+589
+01:02:54,870 --> 01:03:03,210
+تداخل بمقدار delta radial distance دلتا
+
+590
+01:03:05,970 --> 01:03:09,310
+و هذا أكمل هذا حيصير pressure على ال shaft pressure
+
+591
+01:03:09,310 --> 01:03:14,910
+من برة و على ال pressure من جوة ال pressure سواء
+
+592
+01:03:14,910 --> 01:03:17,890
+كان حصل ايش تدرس أنت اعتبره من برة أو من جوة ال
+
+593
+01:03:17,890 --> 01:03:25,130
+pressure بين اثنين باعتمد على قيمة ايش delta وعلى
+
+594
+01:03:25,130 --> 01:03:29,520
+ال materials لل both parts لل shaft و ال hole يعني
+
+595
+01:03:29,520 --> 01:03:33,820
+مبين اندي هي ال modulus of elasticity و باين ال
+
+596
+01:03:33,820 --> 01:03:37,280
+poison ratio فاهم فاهم اندي هاد ال E O ال modulus
+
+597
+01:03:37,280 --> 01:03:41,980
+of elasticity لل outer part و هاد ال modulus of
+
+598
+01:03:41,980 --> 01:03:45,740
+elasticity لل inner part هاد ال poison ratio لل
+
+599
+01:03:45,740 --> 01:03:50,460
+outside part هاد ال poison ratio لل inside part
+
+600
+01:03:53,110 --> 01:03:56,710
+فقيمة ال pressure بتزيد كل ما زاد ال interference
+
+601
+01:03:56,710 --> 01:04:01,930
+و بتعتمد برضه على ال material properties الموديلس
+
+602
+01:04:01,930 --> 01:04:05,290
+و الاستيك المدرس الموديلس والاسيستي بتمثل زنبركية
+
+603
+01:04:05,290 --> 01:04:12,410
+المادة المادة كأنها زنبرك وضادة كل
+
+604
+01:04:12,410 --> 01:04:17,490
+ما كان الموديلس الاستعالج كثير كل ما كان ال
+
+605
+01:04:17,490 --> 01:04:22,600
+interference أصعب كل ما كان interference أصعب يعني
+
+606
+01:04:22,600 --> 01:04:27,260
+لو أنا بدي أحشر shaft في قطعة مطاط سهل أمغطها صح
+
+607
+01:04:27,260 --> 01:04:32,100
+لكن لو بدي أضغط قطعة حديد في حديد صعب كثير لأن
+
+608
+01:04:32,100 --> 01:04:34,880
+ال modulus velocity بتاعة الحديد أعلى كثير من
+
+609
+01:04:34,880 --> 01:04:36,980
+modulus velocity للمطاط
+
+610
+01:04:43,190 --> 01:04:46,410
+طبعًا في حالة خاصة إذا كان if both cylinders are of
+
+611
+01:04:46,410 --> 01:04:52,630
+the same material بتكون ال EI بيساوي ال EO و ال UO
+
+612
+01:04:52,630 --> 01:04:56,490
+بيساوي ال UI بيصير معادلة أبسط بيكون ال pressure
+
+613
+01:04:56,490 --> 01:05:00,690
+is given by this equation في حالة إن ال inner part
+
+614
+01:05:00,690 --> 01:05:03,450
+و ال outer part لهم نفس ال material
+
+615
+01:05:15,100 --> 01:05:19,520
+طبعًا I will apply المعادلات
+
+616
+01:05:19,520 --> 01:05:26,900
+بتاعة ال thick cylinders في حالة عندي cylinder
+
+617
+01:05:26,900 --> 01:05:30,540
+عليها pressure from the outside pressure from the
+
+618
+01:05:30,540 --> 01:05:34,580
+inside في عندي tangential stress component و عندي
+
+619
+01:05:34,580 --> 01:05:36,980
+radial stress component موطنة اللي لقيتها دي رودي
+
+620
+01:05:36,980 --> 01:05:43,490
+حكينا عنها الآن لو بدي آخذ ال inner part ال inner
+
+621
+01:05:43,490 --> 01:05:47,650
+part اللي هو الشفت الشفت متعرض لضغط من برة ولا من
+
+622
+01:05:47,650 --> 01:05:52,850
+جوا؟ outside يعني ال P I عليه شو يساوي؟ صفر و ال
+
+623
+01:05:52,850 --> 01:05:59,790
+P O بيساوي ايش؟ ال P I بيساوي صفر و P O بيساوي P و
+
+624
+01:05:59,790 --> 01:06:05,690
+ال most critical جاية في ال interface بين الشفت و
+
+625
+01:06:05,690 --> 01:06:10,300
+ال hole يعني عند عندنا من ال radius بيستوي R
+
+626
+01:06:10,300 --> 01:06:14,120
+كابيتال و بيكون في عندي قيمة ال pressure بيستوي P
+
+627
+01:06:14,120 --> 01:06:20,180
+يعني at R ال sigma تنجلش على ال inner member at R
+
+628
+01:06:20,180 --> 01:06:26,060
+بيستوي R كابيتال نعمل ال simplification بنعمل في
+
+629
+01:06:26,060 --> 01:06:33,180
+المعادلة السابقة اللي هي هذه بنحط ال P I بيستوي
+
+630
+01:06:33,180 --> 01:06:38,840
+صفر يعني هذا ال term روح و هذا ال term يروح بنعوض
+
+631
+01:06:38,840 --> 01:06:43,380
+عن R ب R capital و بحسب ال sigma tangential
+
+632
+01:06:43,380 --> 01:06:50,860
+بالنسبة لل outer member عليه ضغط من جوة صح ال P O
+
+633
+01:06:50,860 --> 01:06:56,780
+بالساوي صفر و P و I الوقين بالساوي P برضه نفس
+
+634
+01:06:56,780 --> 01:07:00,320
+الشيء بنعوض عن R بالساوي R capital في معادة ال
+
+635
+01:07:00,320 --> 01:07:04,740
+sigma radial و بحسب اللي هي sigma radial عند ال
+
+636
+01:07:04,740 --> 01:07:07,740
+interference اللي هي P في RO square زي R square
+
+637
+01:07:07,740 --> 01:07:12,120
+على RO square minus R square بالطريقة هذه حسبت
+
+638
+01:07:12,120 --> 01:07:16,280
+tangential stress و radial stress at the
+
+639
+01:07:16,280 --> 01:07:19,180
+interference between the two mating parts اللي هو
+
+640
+01:07:19,180 --> 01:07:20,360
+الشافت و ال whole
+
+641
+01:07:35,040 --> 01:07:41,360
+طبعًا طالما عرفت ال .. ال .. ال tangential stress
+
+642
+01:07:41,360 --> 01:07:47,640
+at the interference يعني ممكن أحسب ال torque
+
+643
+01:07:47,640 --> 01:07:52,080
+capacity ال torque capacity لل .. لل assembly
+
+644
+01:07:52,080 --> 01:07:59,960
+torque capacity لل assembly ال torque capacity لل
+
+645
+01:07:59,960 --> 01:08:05,570
+assembly حتكون stress في ايش؟ tangential stress
+
+646
+01:08:05,570 --> 01:08:12,290
+حأعمل moment في surface area تعطيني ايش؟
+
+647
+01:08:12,290 --> 01:08:20,590
+force tangential force في radius ايش تعطيني؟
+
+648
+01:08:20,590 --> 01:08:26,590
+تعطيني torque تعطيني torque جرّبوا فحصوه لحالكم
+
+649
+01:08:27,580 --> 01:08:31,560
+اطلعوا على press and shrink fit torque capacity
+
+650
+01:08:31,560 --> 01:08:44,280
+calculation اطلعوا على torque capacity of
+
+651
+01:08:44,280 --> 01:08:49,960
+press and shrink fits
+
+652
+01:09:04,550 --> 01:09:16,890
+طيب هنحكي آخر شيء و نخلص المحاضرة الآن
+
+653
+01:09:16,890 --> 01:09:21,610
+إذا فاني temperature effect some mechanical part و
+
+654
+01:09:21,610 --> 01:09:24,830
+سخنته حيصير له تمدد
+
+655
+01:09:27,530 --> 01:09:30,990
+التمدد أو الـ strain لكل واحدة الطول لكل واحدة
+
+656
+01:09:30,990 --> 01:09:34,030
+الطول أبسل X بالسواء أبسل Y بالسواء أبسل Z بالسواء
+
+657
+01:09:34,030 --> 01:09:37,830
+Alpha في Delta T Delta T الفرق داشرة الحرارة Alpha
+
+658
+01:09:37,830 --> 01:09:43,510
+معامل التمدد الطولي معامل
+
+659
+01:09:43,510 --> 01:09:51,050
+التمدد الحراري في جدول تلاتة تلاتة معطيني معامل
+
+660
+01:09:51,050 --> 01:09:52,910
+التمدد الحراري
+
+661
+01:09:54,810 --> 01:09:58,270
+لـ different materials عندك aluminium, brass,
+
+662
+01:09:58,430 --> 01:10:01,050
+carbon steel, cast iron, magnesium, nickel,
+
+663
+01:10:01,690 --> 01:10:06,230
+stainless steel, tungsten و عطينا بوحدات مختلفة
+
+664
+01:10:06,230 --> 01:10:14,030
+باستخدام السلسيوس scale أو الفهرنهايت scale و عطينا
+
+665
+01:10:14,030 --> 01:10:20,010
+هذه القيم الألفا لأن طالما ال mechanical member
+
+666
+01:10:20,010 --> 01:10:25,910
+بسخنه is free بتمدد بس ما فيش فيه stresses لكن لو
+
+667
+01:10:25,910 --> 01:10:29,750
+جيت bar هاي
+
+668
+01:10:29,750 --> 01:10:42,070
+ال bar مسكته ثبته و بعدين سخنت بدي
+
+669
+01:10:42,070 --> 01:10:45,950
+أحاول أنا ايش؟ حيُحاول يتمدد بس أنا معناه يتمدد ايش
+
+670
+01:10:45,950 --> 01:10:51,050
+بيصير عندي؟ بيصير stresses على فرض أنه thick
+
+671
+01:10:51,050 --> 01:10:51,430
+enough
+
+672
+01:10:54,070 --> 01:10:59,110
+بيصير في عنده stresses نتيجة بيحاول هو يتمدد بقيمة
+
+673
+01:10:59,110 --> 01:11:04,230
+epsilon x لكن أنا مانعه لو كانت تمدد في ال elastic
+
+674
+01:11:04,230 --> 01:11:12,330
+region يعني بقى ممكن أحسب أبسرن X اللي بيساوي Alpha
+
+675
+01:11:12,330 --> 01:11:21,450
+Delta T بعدين Sigma X بيساوي أبسرن X في E إذا كنا
+
+676
+01:11:21,450 --> 01:11:27,190
+في ال elastic region وكان معدن اللي هي هذه
+
+677
+01:11:27,190 --> 01:11:30,810
+المعادلة حيُكون ايش؟ إذا من المنطقي كل ال stress
+
+678
+01:11:30,810 --> 01:11:35,170
+هي compression ولا tension؟ compression
+
+679
+01:11:35,170 --> 01:11:40,150
+حيُكون لو أنا مانع فبيحاول يتمدد هو مضغوط من الجهة
+
+680
+01:11:40,150 --> 01:11:43,390
+مضغوط هو بيصير اندي compression stress ال sigma
+
+681
+01:11:43,390 --> 01:11:47,690
+سواء minus E في epsilon minus alpha delta T في E
+
+682
+01:11:47,690 --> 01:12:01,330
+إذا كان عندي plate plate و ممسوك من الأطراف و عطيتة
+
+683
+01:12:01,330 --> 01:12:08,260
+سخنته حيُحاول يتمدد بهذا الاتجاه و هذا الاتجاه طبعًا
+
+684
+01:12:08,260 --> 01:12:13,900
+نتيجة الـ Poisson Ratio Effect حيُكون فيه إذا فاكرين
+
+685
+01:12:13,900 --> 01:12:20,280
+أبسرن
+
+686
+01:12:20,280 --> 01:12:24,060
+X يساوي واحد
+
+687
+01:12:24,060 --> 01:12:32,280
+على E في سيجما X minus U في سيجما Y زائد سيجما Z
+
+688
+01:12:32,280 --> 01:12:43,910
+صح؟ و أبسرن Y يساوي واحد على E في Sigma Y minus U في
+
+689
+01:12:43,910 --> 01:12:55,890
+Sigma Z Sigma X زي Sigma Z بس
+
+690
+01:12:55,890 --> 01:13:00,640
+اختار علاقات هذه بنوجد علاقة الاسترس طبعًا حيصير
+
+691
+01:13:00,640 --> 01:13:04,260
+متساوي بالاتجاه ال X و ال Y في الحالة هذه ممسوك من
+
+692
+01:13:04,260 --> 01:13:09,660
+جهتين حيُكون ال sigma يساوي minus Alpha Delta T في
+
+693
+01:13:09,660 --> 01:13:15,260
+E على 1 minus Nu فدخلت ال poison ratio effect على
+
+694
+01:13:15,260 --> 01:13:15,740
+الخط
+
+695
+01:13:23,010 --> 01:13:27,950
+لحد هنا بنكون خلصنا المحاضرة المراجعة بنكمل تأكلوا
+
+696
+01:13:27,950 --> 01:13:28,310
+العافية 
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/iF9_1ET6MVU_raw.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/iF9_1ET6MVU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..5e142b307c77adf27e5528ea88c9aafc4b27ceb8
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/iF9_1ET6MVU_raw.srt
@@ -0,0 +1,2800 @@
+1
+00:00:05,110 --> 00:00:08,190
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,190 --> 00:00:12,290
+وبركاته اليوم هنستكمل chapter تلاتة stress and
+
+3
+00:00:12,290 --> 00:00:16,370
+load analysis المرة الفاتحة حكينا عن ال stress
+
+4
+00:00:16,370 --> 00:00:21,210
+concentration كيف ال stress برتفع عن مناطق ال
+
+5
+00:00:21,210 --> 00:00:25,750
+discontinuities برتفع عن ال nominal value بيصير ان
+
+6
+00:00:25,750 --> 00:00:29,830
+التركيز إجهادي اليوم هنحل مجموعة من الأمثلة عشان
+
+7
+00:00:29,830 --> 00:00:31,010
+نوضح الفكرة
+
+8
+00:00:33,500 --> 00:00:39,840
+المثال أمامكم في عندى thin plate عرض
+
+9
+00:00:39,840 --> 00:00:45,920
+من هنا اربعين ملي من هنا اربع تلاتين ملي في ثقب
+
+10
+00:00:45,920 --> 00:00:53,580
+هنا ال plate ثمكته اربع ملي وفي load ميت كيلو
+
+11
+00:00:53,580 --> 00:00:58,460
+نيوتن في فلت عندى هنا radiusها واحد ملي متر
+
+12
+00:01:06,590 --> 00:01:09,790
+it is desired to drill a hole through the center
+
+13
+00:01:09,790 --> 00:01:13,550
+of the forty millimeter face of the plate to allow
+
+14
+00:01:13,550 --> 00:01:21,210
+a cable to pass through it المطلوب نفتح ثقوب في
+
+15
+00:01:21,210 --> 00:01:29,570
+المنطقة هذه عشان أدخل منه cable a
+
+16
+00:01:29,570 --> 00:01:32,150
+four millimeter hole is sufficient for the cable
+
+17
+00:01:32,150 --> 00:01:43,400
+to fit ثقوب كترةأربعة ملي كافي لدخول الكابل بق
+
+18
+00:01:43,400 --> 00:01:46,800
+an eight millimeter drill is readily available لكن
+
+19
+00:01:46,800 --> 00:01:51,980
+القطعة هذه فيها already ثقوب موجود تمانية ملي فيها
+
+20
+00:01:51,980 --> 00:01:54,480
+already ثقوب موجود تمانية ملي لكن مطلوب أوي بكفي
+
+21
+00:01:54,480 --> 00:01:59,160
+أربعة ملي لكن هي في ثقوب موجود قطره تمانية ملي
+
+22
+00:02:03,640 --> 00:02:07,340
+will a crack be more likely to initiate at the
+
+23
+00:02:07,340 --> 00:02:11,820
+larger hole the smaller hole or at the fillet اذا
+
+24
+00:02:11,820 --> 00:02:18,080
+حيصير failure او يصير بداية تشقق هل حيصير عند ال
+
+25
+00:02:18,080 --> 00:02:24,020
+hole قطر أربع ملي او ال hole قطر تمانية ملي او عند
+
+26
+00:02:24,020 --> 00:02:29,040
+ال fillet خلّيني فحص عليه check
+
+27
+00:02:35,240 --> 00:02:40,920
+at the hall هذه
+
+28
+00:02:40,920 --> 00:02:46,760
+منطقة ال hall لو
+
+29
+00:02:46,760 --> 00:02:47,620
+أخدت section هنا
+
+30
+00:03:10,400 --> 00:03:16,040
+هذه thickness اللي
+
+31
+00:03:16,040 --> 00:03:20,760
+هي أربعة ملي متر هذه
+
+32
+00:03:20,760 --> 00:03:29,180
+كلها عرضها أربعين وهذه
+
+33
+00:03:29,180 --> 00:03:32,860
+تعتمد يا أربعة يا تمانية صح يعني المرة لو كنت
+
+34
+00:03:32,860 --> 00:03:37,760
+كتبون أربعة يعني المرة اللي هنشتغل على أربعة و
+
+35
+00:03:37,760 --> 00:03:40,600
+المرة اللي هنشتغل على تمانيةمرة على أربعة و مرة
+
+36
+00:03:40,600 --> 00:03:44,940
+على تمانية يعني عندي أربعة و تمانية عندي تمانية
+
+37
+00:03:44,940 --> 00:03:50,000
+خلّيني
+
+38
+00:03:50,000 --> 00:04:03,540
+أحكي ال هو واحد four millimeter hole هتكون
+
+39
+00:04:03,540 --> 00:04:06,300
+مساحة المقطع الصافي ال a
+
+40
+00:04:11,330 --> 00:04:19,510
+اللي هو هتكون أربعة في أربعين ناقص
+
+41
+00:04:19,510 --> 00:04:27,870
+أربعة في أربعة صح؟ يعني
+
+42
+00:04:27,870 --> 00:04:31,650
+هيكون مية و ستين ناقص ستاش مية و أربعة و أربعين
+
+43
+00:04:31,650 --> 00:04:32,970
+millimeter square
+
+44
+00:04:39,770 --> 00:04:43,050
+وانا بحسب ان نمو ال stress في المنطقة هذه ال sigma
+
+45
+00:04:43,050 --> 00:04:48,710
+o هتكون
+
+46
+00:04:48,710 --> 00:04:56,230
+الساعة اللي هي عشر تلاف نيوتن ع المساحة اللي هي
+
+47
+00:04:56,230 --> 00:05:01,390
+مية و أربع و أربعين تطنيها بالميجا باسكال هذا نحسب
+
+48
+00:05:01,390 --> 00:05:01,750
+ورايا
+
+49
+00:05:07,070 --> 00:05:10,550
+طيب الان نتيجة الثقوب في عندي تركيز إجهاد في عندي
+
+50
+00:05:10,550 --> 00:05:19,570
+stress concentration هروح ع بندكس A 15 1 6
+
+51
+00:05:19,570 --> 00:05:24,710
+69
+
+52
+00:05:24,710 --> 00:05:27,730
+.4
+
+53
+00:05:27,730 --> 00:05:31,210
+ميجا
+
+54
+00:05:31,210 --> 00:05:31,730
+بسكال
+
+55
+00:05:37,090 --> 00:05:40,830
+طيب انا في عندى stress concentration هروح على
+
+56
+00:05:40,830 --> 00:05:45,090
+appendix A خمساش واحد في اخر الكتاب انا ماخد
+
+57
+00:05:45,090 --> 00:05:54,850
+الصورة جيبها من الكتاب appendix A ال thickness
+
+58
+00:05:54,850 --> 00:05:58,250
+اتنين
+
+59
+00:05:58,250 --> 00:06:05,190
+millimeter صحيح يعني هي دى thickness يعني عفرض
+
+60
+00:06:05,190 --> 00:06:11,630
+كانتاربع مليه خلي نكملها بتأثرش
+
+61
+00:06:11,630 --> 00:06:21,590
+على طبيعة المثلة بدها نخليها اتنين مين نخليها هنا
+
+62
+00:06:21,590 --> 00:06:28,130
+هتكون هنقسم على اتنين صح هنا
+
+63
+00:06:28,130 --> 00:06:36,560
+هتكون اربع اربع هنا عندي اتنيناين اتنين اتنين
+
+64
+00:06:36,560 --> 00:06:44,180
+وسبعين وعندي
+
+65
+00:06:44,180 --> 00:06:48,360
+هنا على
+
+66
+00:06:48,360 --> 00:06:53,660
+اتنين وسبعين ماجي
+
+67
+00:06:53,660 --> 00:06:54,740
+باسكار
+
+68
+00:07:00,570 --> 00:07:04,070
+هذا ال sigma هو فكان فينا stress concentration
+
+69
+00:07:04,070 --> 00:07:12,010
+بروح على pendex A خمستاش واحد
+
+70
+00:07:12,010 --> 00:07:19,470
+واحد دي
+
+71
+00:07:19,470 --> 00:07:26,950
+هي دي دي على W اللي
+
+72
+00:07:26,950 --> 00:07:27,730
+هي أربعة
+
+73
+00:07:30,240 --> 00:07:51,020
+w التي هي أربعين صح point one high point one منها
+
+74
+00:07:51,020 --> 00:07:55,800
+بطل الكاتي يعني
+
+75
+00:07:55,800 --> 00:08:04,030
+تقريبايعني اتنين point سبعة اقل شوية الكاتي
+
+76
+00:08:04,030 --> 00:08:13,450
+معناه في ال sigma max هتكون كاتي في ال sigma o
+
+77
+00:08:13,450 --> 00:08:19,470
+يعني اتنين point سبعة في مية و تمانية تلاتين point
+
+78
+00:08:19,470 --> 00:08:19,990
+تسعة
+
+79
+00:08:33,990 --> 00:08:38,790
+طيب هاد ال case الأولى ال case التانية اللي وعندي
+
+80
+00:08:38,790 --> 00:08:46,190
+eight millimeter hole منها تطلع البحث بال area
+
+81
+00:08:46,190 --> 00:08:53,130
+اللي هتكون ال area نفس الأشياء مش نفسه مش هتكون
+
+82
+00:08:53,130 --> 00:09:01,810
+اتنين في اربعين ناقص اتنين في تمانية يعني
+
+83
+00:09:01,810 --> 00:09:02,910
+اربع و ستين
+
+84
+00:09:09,130 --> 00:09:14,010
+الـ Sigma O هتكون
+
+85
+00:09:14,010 --> 00:09:18,470
+عشر تلاف على
+
+86
+00:09:18,470 --> 00:09:32,570
+أربعة ستين اللي
+
+87
+00:09:32,570 --> 00:09:38,700
+أنا بدي أحسب ال Sigma O هي أكبر من هذهلكن مش هتصرف
+
+88
+00:09:38,700 --> 00:09:42,400
+بدي اشوف ال stress concentration اللي انا عندي A
+
+89
+00:09:42,400 --> 00:09:52,100
+خمستاش واحد ال D على W تمانية على أربعين اللي هي
+
+90
+00:09:52,100 --> 00:10:04,000
+point اتنين و انا بطلع ال KT اتنين
+
+91
+00:10:04,000 --> 00:10:04,780
+point خمسة
+
+92
+00:10:07,800 --> 00:10:12,120
+معناته ال signal max هيكون
+
+93
+00:10:12,120 --> 00:10:19,460
+اتنين و نص في مية و ستة و خمسين point اتنين خمسة
+
+94
+00:10:19,460 --> 00:10:24,700
+تلت
+
+95
+00:10:24,700 --> 00:10:25,560
+مية وتسعين
+
+96
+00:10:36,880 --> 00:10:40,240
+يعني ال software mean critical اكتر التمانية ملي
+
+97
+00:10:40,240 --> 00:10:47,960
+ولا الأربعة ملي تمانية
+
+98
+00:10:47,960 --> 00:10:55,540
+مو ال critical معناته من ناحية stress الأربعة ملي
+
+99
+00:10:55,540 --> 00:11:02,260
+افضل من التمانية ملي الأن بدنا نفحص الحالة اللي هي
+
+100
+00:11:02,260 --> 00:11:02,940
+عند الفيلت
+
+101
+00:11:06,710 --> 00:11:15,370
+الـ fillet اللي هي case 3 and check at
+
+102
+00:11:15,370 --> 00:11:22,230
+the fillet هنروح
+
+103
+00:11:22,230 --> 00:11:29,250
+لل fillet طبعا ان ال fillet هنا ال cross section
+
+104
+00:11:29,250 --> 00:11:33,250
+اربعة تلاتين في اتنين معناته ال sigma ال nominal
+
+105
+00:11:37,380 --> 00:11:42,520
+بتساوي اللي هي عشر تلاف على
+
+106
+00:11:42,520 --> 00:11:57,260
+اربعة و تلاتين في اتنين مية
+
+107
+00:11:57,260 --> 00:12:08,040
+سبعة و اربعين غلط لأنه هذه صح مية سبعة و اربعينمية
+
+108
+00:12:08,040 --> 00:12:14,640
+و سبعة و اربعين ميجا
+
+109
+00:12:14,640 --> 00:12:29,360
+باسكال طيب في عندي stress concentration طيب
+
+110
+00:12:29,360 --> 00:12:33,120
+هنروح
+
+111
+00:12:33,120 --> 00:12:34,300
+على appendix
+
+112
+00:12:37,840 --> 00:12:46,400
+ا خمستاش خمسة ا خمستاش خمسة
+
+113
+00:12:46,400 --> 00:12:57,440
+بالزمن ا ر على ا ر على دي ا ر على دي بتساوي الارن
+
+114
+00:12:57,440 --> 00:13:01,540
+دي الفيلت واحد من اللي حلتنا على اربعة تلاتين
+
+115
+00:13:06,630 --> 00:13:11,230
+والزمن دي capital على
+
+116
+00:13:11,230 --> 00:13:24,490
+دي اللي اربعين على اربعة و تلاتين point
+
+117
+00:13:24,490 --> 00:13:33,850
+o تلاتة و ال دي capital على دي واحد point
+
+118
+00:13:36,970 --> 00:13:46,110
+1 8 يعني
+
+119
+00:13:46,110 --> 00:13:50,410
+أولش ناخد ال R على دي اللي هي point O تلاتة يعني
+
+120
+00:13:50,410 --> 00:13:52,290
+دي هين point O تقريبا تقريبا هنا
+
+121
+00:14:06,090 --> 00:14:14,750
+و ال D كبت على دي واحد تمانتاش يعني
+
+122
+00:14:14,750 --> 00:14:20,590
+عند
+
+123
+00:14:20,590 --> 00:14:24,190
+ال واحد تمانتاش جاب بين واحد point واحد والواحد
+
+124
+00:14:24,190 --> 00:14:30,110
+point خمسة يعني اتطلعت بالشكل هذا لاخدت بالشكل عند
+
+125
+00:14:30,110 --> 00:14:38,440
+اي نقطة عمودي عملت interpolationهتكون واحد point
+
+126
+00:14:38,440 --> 00:14:41,400
+تمانتاش المسافر هنا دي فادي اكم واحد و نص ناقص
+
+127
+00:14:41,400 --> 00:14:47,000
+واحد point واحد اكم point اربع point اربع يعني
+
+128
+00:14:47,000 --> 00:14:51,440
+هتكون عندى هنا واحد و نص ناقص واحد point تمانتاش
+
+129
+00:14:51,440 --> 00:14:54,960
+على point اربع تاكر ان انا احسبه اكم واحد و نص
+
+130
+00:14:54,960 --> 00:15:03,240
+ناقص واحد point تمانتاش point
+
+131
+00:15:03,240 --> 00:15:10,360
+تمانتاشاللي هي واحد point خمسة ناقص واحد point
+
+132
+00:15:10,360 --> 00:15:14,060
+تمانتاش بعدين اطلع النتيجة اقسمها على اربع من عشرة
+
+133
+00:15:14,060 --> 00:15:20,260
+point تمانية يعني point تمانية تقريبا لو قسمت هذه
+
+134
+00:15:20,260 --> 00:15:24,400
+عشر اقسم هي قسمين بعدين عندي
+
+135
+00:15:28,550 --> 00:15:36,510
+واحد اتنين تلاتة اربعة خمسة ستة سبعة تمانية تسعة
+
+136
+00:15:36,510 --> 00:15:41,110
+عشرة يعني الحاجة هنا ال curve curve حاجة في منطقة
+
+137
+00:15:41,110 --> 00:15:45,850
+التمانية من عشرة مظبوط معناته هيكون ال curve جاي
+
+138
+00:15:45,850 --> 00:15:55,070
+اشي زي هيك انا بقدر اعمل interpolation يعني هنكون
+
+139
+00:15:55,070 --> 00:15:56,150
+احنا في المنطقة هذه
+
+140
+00:15:59,880 --> 00:16:10,120
+يعني هدي هدي اتنين point تلاتة ال kitty سو
+
+141
+00:16:10,120 --> 00:16:18,980
+اتنين point تلاتة معناته ال sigma max هتكون
+
+142
+00:16:18,980 --> 00:16:24,760
+اتنين point تلاتة في مية و سبعة و اربعين point
+
+143
+00:16:24,760 --> 00:16:25,220
+واحد
+
+144
+00:16:41,850 --> 00:16:47,010
+ميجا باسكال انا
+
+145
+00:16:47,010 --> 00:16:53,330
+عندي هاي كيس واحد هاي
+
+146
+00:16:53,330 --> 00:16:59,930
+كيس اتنين وهاي
+
+147
+00:16:59,930 --> 00:17:00,870
+كيس تلاتة
+
+148
+00:17:06,640 --> 00:17:12,800
+لو بدت ارتبهم ترتيب من حيث التأثير او ارتفاع ال
+
+149
+00:17:12,800 --> 00:17:20,540
+stress هتكون هذه رقم واحد صح وهذه
+
+150
+00:17:20,540 --> 00:17:25,800
+رقم اتنين وهذه
+
+151
+00:17:25,800 --> 00:17:30,260
+رقم تلاتة معناته المصدر كريتيكا لما نكون الثقوب
+
+152
+00:17:30,260 --> 00:17:30,980
+تمانية ملة
+
+153
+00:17:34,060 --> 00:17:40,480
+يليه يليه الثقب أربع مليه بعده بيجي الفلت اللي هي
+
+154
+00:17:40,480 --> 00:17:45,820
+واحد مليه
+
+155
+00:17:45,820 --> 00:17:56,940
+هاي السؤال متوقع
+
+156
+00:17:56,940 --> 00:18:00,920
+يكسر على الفلت ولا على الثقبعالثقوب يعني stress
+
+157
+00:18:00,920 --> 00:18:06,060
+level أعلى، عالثقوب تمانية ملي احنا حكينا في
+
+158
+00:18:06,060 --> 00:18:11,000
+الحسابات ال stress فيانا ال stress و strength ال
+
+159
+00:18:11,000 --> 00:18:14,560
+stress مانهاش خاص في ال material ال stress اللي
+
+160
+00:18:14,560 --> 00:18:20,260
+خاص في ال loading و ال geometryو نضيف شغلة كمان ال
+
+161
+00:18:20,260 --> 00:18:23,340
+stress concentration loading جيومتري و stress
+
+162
+00:18:23,340 --> 00:18:27,120
+concentration ال strength بتاعة الحديد it is
+
+163
+00:18:27,120 --> 00:18:32,240
+strength قوة الحديد بغض نظر عن ال loading عشان كده
+
+164
+00:18:32,240 --> 00:18:35,120
+أنا بحس ب stress level و بقارنها بال strength
+
+165
+00:18:35,120 --> 00:18:38,020
+بتاعة ال material تحت الدراسة عشان أعرف ان في اندي
+
+166
+00:18:38,020 --> 00:18:44,380
+failure ولا مش failure ال strength
+
+167
+00:18:44,380 --> 00:18:46,840
+اللي علاقة بالجيومتري كيف؟
+
+168
+00:18:52,560 --> 00:18:55,860
+أيوة ال stress level بيختلف باختلاف الجيومترية
+
+169
+00:18:55,860 --> 00:18:59,460
+كويس لأ ما هدك .. هدك مش strength تحكي عليها
+
+170
+00:18:59,460 --> 00:19:06,020
+stress فال stress level يرتفع أو ينخفض بتغير ال
+
+171
+00:19:06,020 --> 00:19:12,780
+loading أو تغير المقطع الجيومتري أو بوجود تركيز
+
+172
+00:19:12,780 --> 00:19:15,040
+إجهادي stress concentration
+
+173
+00:19:37,590 --> 00:19:41,430
+طيب ان خش على ال stress in pressurized cylinders
+
+174
+00:19:41,430 --> 00:19:47,570
+في الاستوانات المضغوطة انا حينها هارض عليكم
+
+175
+00:19:47,570 --> 00:19:51,990
+المعادلات مش مطلوب انكوا اشتقاقها فاندي السيلندر
+
+176
+00:19:51,990 --> 00:19:55,350
+القطر
+
+177
+00:19:55,350 --> 00:20:00,730
+الداخل ر ايه اللي هو inner radiusو القطر الخارج
+
+178
+00:20:00,730 --> 00:20:04,750
+لها RO اللي هو ال outside radius يعني في استوانة
+
+179
+00:20:04,750 --> 00:20:09,490
+مفقوقة لها قطر داخل ر اي و قطر خارج ر او ال
+
+180
+00:20:09,490 --> 00:20:11,810
+general case ان يكون في pressure جوا و pressure
+
+181
+00:20:11,810 --> 00:20:19,610
+برا pressure جوا و pressure برا من جوا ل pressure
+
+182
+00:20:19,610 --> 00:20:24,870
+جوا الاستوانة قيمته PI اللي هو inside pressure ال
+
+183
+00:20:24,870 --> 00:20:31,350
+pressure برا الاستوانة PO نتيجة ال pressureلو كان
+
+184
+00:20:31,350 --> 00:20:36,450
+برشه من جوه هتحاول استوانه ايش تفتح مظبوط مانعني
+
+185
+00:20:36,450 --> 00:20:39,910
+ان في عندي hoop او tangential stress لو أخدت
+
+186
+00:20:39,910 --> 00:20:49,150
+stress element يعني هكون
+
+187
+00:20:49,150 --> 00:20:56,790
+في عندي tangential stress وعندي
+
+188
+00:21:00,600 --> 00:21:07,820
+radial stress سيجما راديال ال tangential stress
+
+189
+00:21:07,820 --> 00:21:12,700
+موطني علاقة هادئ سيجما ال tangential في سواء P I R
+
+190
+00:21:12,700 --> 00:21:16,240
+I Square minus P O R O Square minus R I Square R O
+
+191
+00:21:16,240 --> 00:21:20,280
+Square في P O minus P I على R Square R هي ال R at
+
+192
+00:21:20,280 --> 00:21:22,480
+any location ال stress at any location at any
+
+193
+00:21:22,480 --> 00:21:27,400
+radial location R على R O تربيه minus R I تربيهو
+
+194
+00:21:27,400 --> 00:21:30,600
+ال radial stress is given by this equation P I R I
+
+195
+00:21:30,600 --> 00:21:36,280
+square minus P O R O square زائد اتنين R I square
+
+196
+00:21:36,280 --> 00:21:39,940
+R O square في P O minus P I على ارضي نفس المعادلة
+
+197
+00:21:39,940 --> 00:21:45,680
+بس لحظة اللي بيختلف بس ليش هذا minus هذا plus و
+
+198
+00:21:45,680 --> 00:21:55,000
+المقام نفس المقام R O تربية minus R I تربية طيب
+
+199
+00:21:55,000 --> 00:21:56,400
+هناخد special case
+
+200
+00:22:00,600 --> 00:22:03,460
+إنه مايوجد ضغط خارجي ضغط بس من جوا الأسطوانة
+
+201
+00:22:03,460 --> 00:22:11,560
+مايوجد ضغط خارجي يعني ال P O ال P O بالساوية Zero
+
+202
+00:22:11,560 --> 00:22:15,560
+مايوجد ضغط خارجي لما نعود في المعادلة عن P O
+
+203
+00:22:15,560 --> 00:22:25,040
+بالساوية Zero هدا هتروح هدا هروح ترم Zero هدا Zero
+
+204
+00:22:25,040 --> 00:22:30,220
+هدا أيش Zero هتصير ال Sigma تاني جان شال
+
+205
+00:22:33,040 --> 00:22:45,020
+بتساوي P I R I تربيع minus هتدخلين عندي minus
+
+206
+00:22:45,020 --> 00:22:53,980
+minus تصير plus plus R I تربيع
+
+207
+00:22:53,980 --> 00:23:09,470
+R O تربيع في P Iعلى ر تربيع على
+
+208
+00:23:09,470 --> 00:23:19,630
+ر او تربيع minus ر اي تربيع يعني اخدت مشترك بين
+
+209
+00:23:19,630 --> 00:23:31,170
+التلين بي اي ر اي تربيع حيصفي واحدهتبقى عندى P I
+
+210
+00:23:31,170 --> 00:23:36,170
+زائد R O تربيع على
+
+211
+00:23:36,170 --> 00:23:50,170
+R تربيع على R O تربيع minus R I تربيع ليه
+
+212
+00:23:50,170 --> 00:23:55,930
+هذه المعادلة R I تربيع P I على R O تربيع minus R I
+
+213
+00:23:55,930 --> 00:24:00,340
+تربيع في واحد زائد R O تربيع على R تربيعبنفس ال
+
+214
+00:24:00,340 --> 00:24:03,780
+logic بتطلع
+
+215
+00:24:03,780 --> 00:24:08,840
+عندي ال radial stress sigma r يعني هدول ال test
+
+216
+00:24:08,840 --> 00:24:16,240
+نفس الشي بس يختلف هذا plus هذا إيش minus لإن
+
+217
+00:24:16,240 --> 00:24:25,240
+لو بدى أجيب ال stress distribution على المقطع لإن
+
+218
+00:24:25,240 --> 00:24:30,920
+في عنديعندي ال two extreme conditions اللي هي ر
+
+219
+00:24:30,920 --> 00:24:40,760
+بيستوى ر I و ر بيستوى ر O لما ر بتستوى ر I تكون ال
+
+220
+00:24:40,760 --> 00:24:47,740
+ر O على ر I أكبر من واحد صح؟ لما ر أت
+
+221
+00:24:51,560 --> 00:25:01,020
+ر ر اي تربيع
+
+222
+00:25:01,020 --> 00:25:11,200
+في اي على ر او تربيع minus ر اي تربيع في واحد زائد
+
+223
+00:25:11,200 --> 00:25:16,900
+ر او تربيع على ر اي تربيع
+
+224
+00:25:23,680 --> 00:25:33,080
+طيب at r equal ro بيصير ال sigma tangential بيساوي
+
+225
+00:25:33,080 --> 00:25:41,460
+ر I تربيع في I على ر O تربيع minus ر I تربيع في
+
+226
+00:25:41,460 --> 00:25:47,600
+واحد زياد ايش؟ زياد واحد ال
+
+227
+00:25:47,600 --> 00:25:50,860
+term هذا ال ر O على ر I تربيع اكبر من واحد صح؟
+
+228
+00:25:55,250 --> 00:25:58,910
+معناته ال stress level عند ال inner fiber بيكون
+
+229
+00:25:58,910 --> 00:26:03,230
+أعلى من ال stress level عند ال outer fiber معناته
+
+230
+00:26:03,230 --> 00:26:05,930
+هكون ال stress distribution high maximum عند ال
+
+231
+00:26:05,930 --> 00:26:17,410
+inner fiber و minimum عند ال outer fiber بالظبط
+
+232
+00:26:17,410 --> 00:26:20,790
+و
+
+233
+00:26:20,790 --> 00:26:31,260
+ال distribution is non linearفي حالة ال sigma r at
+
+234
+00:26:31,260 --> 00:26:38,740
+r equal ri بيصير
+
+235
+00:26:38,740 --> 00:26:48,580
+ال sigma ر عنده بتساوي اللي هي ri تربيع vi على ro
+
+236
+00:26:48,580 --> 00:26:52,740
+تربيع minus ri تربيع في واحد
+
+237
+00:26:58,150 --> 00:27:08,230
+-ro تربيع على ri تربيع هيكون الساوى ر ا ع بيصير
+
+238
+00:27:08,230 --> 00:27:11,810
+negative ال pressure الساوى negative ال pressure
+
+239
+00:27:11,810 --> 00:27:16,070
+لان انا هاخد ر ا ع تربيع مشتركبالسيران دي ر اي
+
+240
+00:27:16,070 --> 00:27:18,930
+تربيع معناس ر تربيع خدها السير بتطلع برا بتطلع ر
+
+241
+00:27:18,930 --> 00:27:22,470
+اي تربيع معناه تربيع و ال bus مع المقام بيستخدم
+
+242
+00:27:22,470 --> 00:27:28,370
+minus P I هذا منطقي لأن أول fiber متعرض للضغط
+
+243
+00:27:28,370 --> 00:27:36,110
+مباشر radially متعرض للضغط مباشر radially at R
+
+244
+00:27:36,110 --> 00:27:40,890
+بيستخدم ر او بتكون
+
+245
+00:27:40,890 --> 00:27:41,830
+دي ال sigma R
+
+246
+00:27:45,430 --> 00:27:52,890
+هتكون ر اي تربيع P I على ر او تربيع minus ر اي
+
+247
+00:27:52,890 --> 00:27:59,750
+تربيع في واحد minus ر او تربيع على ر او تربيع اللي
+
+248
+00:27:59,750 --> 00:28:09,450
+هي إيش؟ Zero.معناته ال pressure عند ال outer fiber
+
+249
+00:28:09,450 --> 00:28:12,870
+Zero و عند ال inner fiber تسوى minus ال P I
+
+250
+00:28:12,870 --> 00:28:13,570
+بالنجاتف
+
+251
+00:28:17,890 --> 00:28:20,030
+و ال distribution بين ال inner fiber و ال outer
+
+252
+00:28:20,030 --> 00:28:26,950
+fiber non-linear non
+
+253
+00:28:26,950 --> 00:28:33,390
+-linear طبعا
+
+254
+00:28:33,390 --> 00:28:41,570
+انت في حالة الضغط الخارج كان صفر اذا
+
+255
+00:28:41,570 --> 00:28:44,730
+كانت الاستوانة طبعا بفترض كل حسابات الاستوانة يشمل
+
+256
+00:28:44,730 --> 00:28:50,520
+على مفتوحةيعني كأنه خط غاز وماشي لما للنهاية لكن
+
+257
+00:28:50,520 --> 00:28:54,500
+لو كانت الاستوانة مغلقة من الطرفين اذا كانت مغلقة
+
+258
+00:28:54,500 --> 00:28:58,560
+من الطرفين هصير
+
+259
+00:28:58,560 --> 00:29:04,860
+stress component تالتة
+
+260
+00:29:04,860 --> 00:29:09,060
+عند هذه الاستوانة من جوا
+
+261
+00:29:18,260 --> 00:29:29,480
+هيكون فيه فرشة من كل الجهات هسي
+
+262
+00:29:29,480 --> 00:29:31,900
+لو أخدت مقطع بالاتجاه الطولي فهيعندي stress
+
+263
+00:29:31,900 --> 00:29:35,020
+بالاتجاه الطولي بهذا الاتجاه هيك يعني هذا الاتجاه
+
+264
+00:29:35,020 --> 00:29:41,540
+هكون sigma L المقطع
+
+265
+00:29:41,540 --> 00:29:57,650
+هذا sigma Lالنقطة هذه هي ر اي ر اي ر او
+
+266
+00:29:57,650 --> 00:30:00,570
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+267
+00:30:00,570 --> 00:30:01,090
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+268
+00:30:01,090 --> 00:30:01,170
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+269
+00:30:01,170 --> 00:30:02,390
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+270
+00:30:02,390 --> 00:30:04,750
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+271
+00:30:04,750 --> 00:30:05,290
+ر او ر او ر او ر او ر او ر او ر او ر او ر او ر او
+
+272
+00:30:05,290 --> 00:30:16,100
+ر او ر او ر او ر او ر او ر او ر او ر او ر اوبي ر
+
+273
+00:30:16,100 --> 00:30:21,160
+اي تربيع عند المقطع هقعد هسير عندى stress level
+
+274
+00:30:21,160 --> 00:30:31,600
+sigma L بسواء في على ال area في بي ر اي تربيع على
+
+275
+00:30:31,600 --> 00:30:39,800
+ال area هيكون عندى بي ر او تربيع minus بي ر اي
+
+276
+00:30:39,800 --> 00:30:51,070
+تربيع يعني هتصفى بي اي تربيعفي ر اي تربيع على ر او
+
+277
+00:30:51,070 --> 00:30:58,930
+تربيع minus ر اي تربيع ليه
+
+278
+00:30:58,930 --> 00:31:09,470
+هذه المعادلة في حال
+
+279
+00:31:09,470 --> 00:31:11,710
+كانت النبوبة مغلقة
+
+280
+00:31:18,730 --> 00:31:24,670
+طبعا هذا السابق اللي هو thick cylinder theory يعني
+
+281
+00:31:24,670 --> 00:31:28,530
+بفترض انه ال .. ال .. ال .. ال cylinder خملتها
+
+282
+00:31:28,530 --> 00:31:34,550
+كبيرة في حالة كانت ال cylinder ثمكتها قليل ال thin
+
+283
+00:31:34,550 --> 00:31:41,430
+cylinder ممكن نعمل بعض التقريبات الان في حالة ال
+
+284
+00:31:41,430 --> 00:31:45,330
+pressure vessels with wall thickness
+
+285
+00:31:48,970 --> 00:31:57,610
+أقل أو يساوي واحد على عشرة ال mean radius بعتبرها
+
+286
+00:31:57,610 --> 00:32:05,050
+ياش thin wall بعتبرها thin wall في حالة thin wall
+
+287
+00:32:05,050 --> 00:32:13,310
+بيكون عند ال .. خلّيني أرجع للمعادلة الأصلية هنا
+
+288
+00:32:22,070 --> 00:32:27,310
+لو أخدت الـ Sigma Radial طبعا ال thickness هيكون
+
+289
+00:32:27,310 --> 00:32:40,050
+ايه ر او ماينس ر اي صح؟ اذا عند الصورة هنا هذا ر
+
+290
+00:32:40,050 --> 00:32:48,110
+اي و هذا ر او هذا هيكون ايه ال thickness ال
+
+291
+00:32:48,110 --> 00:32:53,090
+thickness هيكون سواء ر او ماينس ر ايالـ Sigma
+
+292
+00:32:53,090 --> 00:33:03,470
+Radial ستكون تساوي ر I تربيع P I على الـ ر O تربيع
+
+293
+00:33:03,470 --> 00:33:08,430
+مناسب الـ ر I تربيع ستكون
+
+294
+00:33:08,430 --> 00:33:16,730
+ر O مانس ر I في ر O زاد ر I ر O مانس ر I في ر O
+
+295
+00:33:16,730 --> 00:33:21,150
+زاد ر I
+
+296
+00:33:25,200 --> 00:33:40,820
+في واحد minus RO تربيع على R تربيع يعني
+
+297
+00:33:40,820 --> 00:33:48,540
+و ال .. يعني هتكون لسه ر I تربيع في I على ال
+
+298
+00:33:48,540 --> 00:33:52,680
+thickness ال RO زاد ال RI
+
+299
+00:33:56,610 --> 00:34:01,830
+الـ RO زاد ال RI لو حكيت ال R مين ال R مين هتكون
+
+300
+00:34:01,830 --> 00:34:11,270
+تستوياش ر او زاد ر اي على اتنين فهنا ال ر او زاد ر
+
+301
+00:34:11,270 --> 00:34:19,110
+اي هتستوياش في اتنين اه ال mean radius RM
+
+302
+00:34:25,110 --> 00:34:31,430
+في 1-r أو تربيه على r تربيه انا دي احاول اريكوا ان
+
+303
+00:34:31,430 --> 00:34:38,270
+ال stigma r هتكون اقل بكتير من اللي
+
+304
+00:34:38,270 --> 00:34:47,470
+هو بالظبط او ممكن تاخد ال limit limit
+
+305
+00:34:47,470 --> 00:34:52,330
+as r
+
+306
+00:34:56,650 --> 00:35:08,910
+طلع انت هنا يعني هدول ثابت هذا ثابت وهذا ثابت لحظة
+
+307
+00:35:08,910 --> 00:35:14,190
+ال ر او تربية لما تكون قريبة كتير من ال ر اي تربية
+
+308
+00:35:14,190 --> 00:35:22,250
+ال term هذا ايش معلومة بكبر بكبر بكبر كتير بكبر
+
+309
+00:35:22,250 --> 00:35:27,520
+معناه لو واحد ناقص الرقمبصغر كتير بيقرب من السفر
+
+310
+00:35:27,520 --> 00:35:33,580
+هي ان عندي plus يعني anyway هذا is insignificant
+
+311
+00:35:33,580 --> 00:35:36,780
+او هيكون insignificant بالنسبالي للواحد فبتصيرها
+
+312
+00:35:36,780 --> 00:35:40,480
+تقريبا واحد زائد هي تقريبا بيصير اتنين يعني هاد
+
+313
+00:35:40,480 --> 00:35:44,420
+بيصير قريب من الواحد واحد زائد واحد اتنين هاد قريب
+
+314
+00:35:44,420 --> 00:35:48,280
+من الواحد وانا طوأ يعني قريبة السفر هتكون ال sigma
+
+315
+00:35:48,280 --> 00:35:55,020
+R كل ما قلت السمكةبصير small compared بال
+
+316
+00:35:55,020 --> 00:36:02,960
+tangential stress طبعا هيكون دي still still ال
+
+317
+00:36:02,960 --> 00:36:09,560
+distribution is nonlinear بس
+
+318
+00:36:09,560 --> 00:36:12,100
+ال thickness بقى دي المكان اشي زيك هيصير اشي صغير
+
+319
+00:36:14,290 --> 00:36:20,090
+هتكون ايش ايه؟ صغير فهحسب اللي هو sigma average ال
+
+320
+00:36:20,090 --> 00:36:24,330
+average tangential stress ال sigma tangential
+
+321
+00:36:24,330 --> 00:36:28,410
+average طب هتعوض .. هتعوض ايه؟ هتعوض مرة R
+
+322
+00:36:28,410 --> 00:36:33,730
+بالستويه ر I و مرة R بالستويه ر O بقى انت تحكي
+
+323
+00:36:33,730 --> 00:36:36,650
+sigma average ال .. ال .. ال .. ال sigma
+
+324
+00:36:36,650 --> 00:36:44,290
+tangential I زي ال sigma tangential O على اتنينو
+
+325
+00:36:44,290 --> 00:36:49,230
+بعدين بتحول ال radius ل ال diameters يعني ال DI
+
+326
+00:36:49,230 --> 00:36:52,710
+بيستوى اتنين ال RI بيطلع عندى ال sigma tangential
+
+327
+00:36:52,710 --> 00:36:56,570
+average PDI على اتنين T P اللي هو ال pressure جوا
+
+328
+00:36:56,570 --> 00:36:59,350
+الاستوانة ال DI اللي هو ال inner diameter
+
+329
+00:36:59,350 --> 00:37:06,930
+للاستوانة و ال T thickness بتاع الاستوانة و ال
+
+330
+00:37:06,930 --> 00:37:10,670
+sigma T maximum ال maximum tangential stress هيكون
+
+331
+00:37:11,550 --> 00:37:19,510
+P DI زائد T على اتنين T الاسترس الطولي هيكون سيجم
+
+332
+00:37:19,510 --> 00:37:31,610
+ألو سواء PDI على أربع T PDI على أربع T تشوف
+
+333
+00:37:31,610 --> 00:37:32,050
+مثال
+
+334
+00:37:39,300 --> 00:37:44,000
+الألمنيوم اللاوي pressure vessel is made of tubing
+
+335
+00:37:44,000 --> 00:37:46,720
+having an outside diameter of eight inch and a
+
+336
+00:37:46,720 --> 00:37:52,940
+wall thickness of quarter inch عندي pressure
+
+337
+00:37:52,940 --> 00:38:00,460
+vessel خزان ضغط مصنوع من سبيكة ألمانيوم أو انبوب
+
+338
+00:38:00,460 --> 00:38:02,780
+ألمانيوم قطرها الخارجي تمانية انش
+
+339
+00:38:11,200 --> 00:38:17,380
+القطر الخارجي تمانية
+
+340
+00:38:17,380 --> 00:38:31,380
+انش والسماكة الانبوب ربع انش water
+
+341
+00:38:31,380 --> 00:38:35,480
+pressure can the cylinder carry؟ ايش في مطبخته
+
+342
+00:38:35,480 --> 00:38:40,240
+ممكن ال cylinder اتشيله؟F permissible tangential
+
+343
+00:38:40,240 --> 00:38:47,040
+stress sigma tangential permissible المسموح فيه
+
+344
+00:38:47,040 --> 00:38:57,120
+بتساوي اتناشر كيلو pound لكل square inch and
+
+345
+00:38:57,120 --> 00:39:00,380
+theory for thin walled vessels is assumed to apply
+
+346
+00:39:00,380 --> 00:39:03,660
+نظرية ال thin walled vessels thin walled cylinders
+
+347
+00:39:03,660 --> 00:39:08,970
+apply متأكد applies or not applyعند ال radius أكم
+
+348
+00:39:08,970 --> 00:39:16,910
+بيستوي ال ر او بيستوي
+
+349
+00:39:16,910 --> 00:39:27,310
+أربعة انش ال ر اي أكم بيستوي تلاتة
+
+350
+00:39:27,310 --> 00:39:36,820
+و خمسة سبعين و ال ر مين هكون تلاتةبنت يعني دي
+
+351
+00:39:36,820 --> 00:39:40,160
+خمستاش على اتنين سبعة و نص تلاتة point تمانية
+
+352
+00:39:40,160 --> 00:39:45,020
+اتنين خمسة مظبوط انش
+
+353
+00:39:45,020 --> 00:39:49,020
+يعني
+
+354
+00:39:49,020 --> 00:39:54,680
+ال RM على ال thickness سوى تلاتة point تمانية
+
+355
+00:39:54,680 --> 00:40:04,660
+اتنين خمسة على رباعيعني هتكون أكبر من عشرة أكبر من
+
+356
+00:40:04,660 --> 00:40:08,320
+عشرة يعني
+
+357
+00:40:08,320 --> 00:40:11,820
+تقريبا أربع في أربع ستاش حوالي الخمستاش point
+
+358
+00:40:11,820 --> 00:40:15,920
+something فواضح أنه ال thickness أقل من العشرة
+
+359
+00:40:15,920 --> 00:40:22,200
+بيعناته ممكن نستخدم ال thin wall cylinder theory
+
+360
+00:40:23,920 --> 00:40:28,480
+في حالة الـ thin walled cylinders theory ال sigma
+
+361
+00:40:28,480 --> 00:40:34,720
+tangential maximum اللي
+
+362
+00:40:34,720 --> 00:40:47,700
+هي بالساوية ال P في DI زائد T على 2T عند ال طبعا
+
+363
+00:40:47,700 --> 00:40:53,300
+هتساوي ال sigma tangential permissible
+
+364
+00:40:55,400 --> 00:41:04,020
+ال دي آي ال دي آي هتكون اتنين في تلاتة point سبعة
+
+365
+00:41:04,020 --> 00:41:12,900
+خمسة يعني سبعة و نص يعني
+
+366
+00:41:12,900 --> 00:41:21,820
+ال pressure هيكون sigma tangential permissible في
+
+367
+00:41:21,820 --> 00:41:31,670
+اتنين Tعلى DI زائد T يعني انا حاجز ساوي اتنين في
+
+368
+00:41:31,670 --> 00:41:35,970
+اتماش في
+
+369
+00:41:35,970 --> 00:41:41,090
+ال thickness ربع انش على
+
+370
+00:41:41,090 --> 00:41:49,050
+ال DI اللي هي سبعة و نص زائد ربع
+
+371
+00:41:50,510 --> 00:41:57,210
+يعني عندي ربع في اتنين و نص، في اتناش، ستة، أكم؟
+
+372
+00:41:57,210 --> 00:42:05,410
+point سبعة سبعة أربعة point سبعة سبعة أربعة kilo
+
+373
+00:42:05,410 --> 00:42:10,880
+pound per square inchهذا الضغط اللي ممكن تشيله
+
+374
+00:42:10,880 --> 00:42:16,900
+استوانة إذا ال max ال permissible tangential
+
+375
+00:42:16,900 --> 00:42:19,560
+stress طبعا في بعض الكتب ما بيسموه tangential
+
+376
+00:42:19,560 --> 00:42:36,040
+بيسموه hoop stress hoop طيب
+
+377
+00:42:39,330 --> 00:42:44,010
+هذا المطبوق الأول on the basis of pressure found
+
+378
+00:42:44,010 --> 00:42:47,610
+in part a بناء على قيمة الضغط اللي حسبناها في
+
+379
+00:42:47,610 --> 00:42:54,770
+الجزء a compute stress components using stress for
+
+380
+00:42:54,770 --> 00:43:01,170
+thick walled cylinders احسب ال stresses بناء على
+
+381
+00:43:01,170 --> 00:43:05,450
+ال pressure اللي احنا عارفينه اعتماد على نظريتي ال
+
+382
+00:43:05,450 --> 00:43:11,020
+thick walls يعني هنستخدم المعادلة هذهالـ sigma
+
+383
+00:43:11,020 --> 00:43:15,820
+tangential هتكون طبقا للـ thick wall sigma
+
+384
+00:43:15,820 --> 00:43:22,340
+tangential maximum وين
+
+385
+00:43:22,340 --> 00:43:30,700
+هتكون عند ال R بيستوى ر I صح هتكون سواء ر I تربية
+
+386
+00:43:30,700 --> 00:43:40,270
+P I على ر O تربية minus ر I تربيةفي واحد زاد ro
+
+387
+00:43:40,270 --> 00:43:48,450
+تربيع على ri تربيع هتكون تساوي ال ri اللي هي تلاتة
+
+388
+00:43:48,450 --> 00:43:53,490
+bond سبعة خمسة تربيع
+
+389
+00:43:53,490 --> 00:44:03,490
+في bond سبعة أربعة على أربعة تربيع minus تلاتة
+
+390
+00:44:03,490 --> 00:44:13,530
+bond سبعة خمسةتربية في واحد زائد اربعة تربية ع
+
+391
+00:44:13,530 --> 00:44:24,290
+تلاتة point سبعة خمسة تربية اكم تطلع اتماش
+
+392
+00:44:24,290 --> 00:44:34,000
+point بس اكم سفر السفر سفر يعني واضح قريب كتيرمن
+
+393
+00:44:34,000 --> 00:44:38,020
+ال permissible معناته النظرية يعني is accurate
+
+394
+00:44:38,020 --> 00:44:44,660
+enough ال sigma radial طبعا ال sigma radial
+
+395
+00:44:44,660 --> 00:44:47,040
+maximum هتكون جوا هتكون minus P I في جدا احسب
+
+396
+00:44:47,040 --> 00:44:51,260
+sigma radial maximum
+
+397
+00:44:51,260 --> 00:44:58,400
+so minus P I اللي هي minus اتناشر كيلو pound بال
+
+398
+00:44:58,400 --> 00:45:05,580
+square inch فواضح انهفأفرض هذه الصح لإن هي ال more
+
+399
+00:45:05,580 --> 00:45:09,540
+accurate theory يعني
+
+400
+00:45:09,540 --> 00:45:15,660
+ال percentage difference هذا هو او percentage
+
+401
+00:45:15,660 --> 00:45:24,700
+difference ولا percentage error difference
+
+402
+00:45:24,700 --> 00:45:25,260
+ولا error
+
+403
+00:45:28,010 --> 00:45:30,530
+difference it's not error ال error ده يعني بيكون
+
+404
+00:45:30,530 --> 00:45:38,550
+ال true value minus ال observed value او ال .. ف
+
+405
+00:45:38,550 --> 00:45:43,810
+.. فاحنا مابنعرفش هد .. هد theory و هد theory it's
+
+406
+00:45:43,810 --> 00:45:48,910
+a mathematical model فانا قلتوا هد ممكن تكون اقرب
+
+407
+00:45:48,910 --> 00:45:52,550
+للاش لل true فانا قلت انا هحس ال difference
+
+408
+00:45:52,550 --> 00:45:57,120
+between this theory and this theoryالـ difference
+
+409
+00:45:57,120 --> 00:46:02,040
+هتكون 12.009
+
+410
+00:46:02,040 --> 00:46:12,840
+-12 على 12.009 في المية سبوها
+
+411
+00:46:12,840 --> 00:46:18,520
+point 0
+
+412
+00:46:18,520 --> 00:46:27,970
+.75 في المية يعني اختلاف بين ال thinأجيد ال بيغان
+
+413
+00:46:27,970 --> 00:46:35,450
+مش اتناش سبعمية و اربعة و سبعين ايش الوحدات بس كده
+
+414
+00:46:35,450 --> 00:46:40,910
+فيه أسئلة فيه أسئلة انا إيش كاتب هنا كيلو كيلو بقى
+
+415
+00:46:40,910 --> 00:46:43,430
+ده لازم تقويله لازم تقويله لازم تقويله لازم تقويله
+
+416
+00:46:43,430 --> 00:46:45,410
+لازم تقويله لازم تقويله لازم تقويله لازم تقويله
+
+417
+00:46:45,410 --> 00:46:46,370
+لازم تقويله لازم تقويله لازم تقويله لازم تقويله
+
+418
+00:46:46,370 --> 00:46:46,370
+لازم تقويله لازم تقويله لازم تقويله لازم تقويله
+
+419
+00:46:46,370 --> 00:46:52,330
+لازم تقويله لازم تقويله لازم تقويله لاز
+
+420
+00:46:55,290 --> 00:47:03,350
+طبعا بالظبط صحيح سالب point seven سبعة أربعة kilo
+
+421
+00:47:03,350 --> 00:47:08,550
+pound per square inch صحيح طيب ال difference
+
+422
+00:47:08,550 --> 00:47:13,470
+between the two theories is not significant ليس ذو
+
+423
+00:47:13,470 --> 00:47:20,450
+أهمية الفرق point O سبعة خمسة ثلاثة في المية انا
+
+424
+00:47:20,450 --> 00:47:23,710
+قلت لو زد stress عام اتماشي
+
+425
+00:47:29,120 --> 00:47:33,920
+لأ انت مش مسموح لك تتخطى هذه يعني انت حاطط انت
+
+426
+00:47:33,920 --> 00:47:38,380
+كمصمم انت تحكي ال permissible بمعناته هذه حاطط
+
+427
+00:47:38,380 --> 00:47:41,080
+some factor of safety حاطط عنب الأمان مثلا انت
+
+428
+00:47:41,080 --> 00:47:43,460
+حاطط عنب الأمان على سبيل المثال احنا مش عارفين ال
+
+429
+00:47:43,460 --> 00:47:48,420
+material عنب الأمان مثلا انت حاطط مثلا اتنين اذا
+
+430
+00:47:48,420 --> 00:47:52,540
+زادت ال sigma عن اتناش بمعناته هينزل عن عنب الأمان
+
+431
+00:47:52,540 --> 00:47:56,370
+اللي انت حاططهينزل factor of safety هذا لا يعني ان
+
+432
+00:47:56,370 --> 00:48:01,110
+نصير failure لا يعني ايه نصير failure الا اذا كان
+
+433
+00:48:01,110 --> 00:48:04,950
+ال factor of safety مشو ساويه واحد فمش مهم اذا
+
+434
+00:48:04,950 --> 00:48:10,870
+جيتها احنا بيبقى بال stress على حسب ما اتكر بالعرض
+
+435
+00:48:10,870 --> 00:48:15,730
+بيختلف على طول صح ولا لا؟ كيف يعني؟ لأنه مرة جيت
+
+436
+00:48:15,730 --> 00:48:22,990
+بالوكالة ايه اما كنا بتجسس من ال diplomaعملنا
+
+437
+00:48:22,990 --> 00:48:28,570
+تحليل على اللي هو ال man hole .. اش هو .. لل
+
+438
+00:48:28,570 --> 00:48:33,410
+exhaust تبع ال .. تبع ال .. ال gas دروعين تمام؟ اه
+
+439
+00:48:33,410 --> 00:48:37,930
+ال man hole عملنا مرة بالعرض و مرة بالطوول ماشي
+
+440
+00:48:37,930 --> 00:48:41,430
+انا هيبقى احكيلك انت عندك الطوولة ال man hole او
+
+441
+00:48:41,430 --> 00:48:44,210
+هو اللي هو الطوولة اللي طالة منها ال exhaust gases
+
+442
+00:48:44,210 --> 00:48:49,370
+ما
+
+443
+00:48:49,370 --> 00:49:02,280
+هو بختلف اكيدعندك هاي الاستوانة ب 3D استوانة
+
+444
+00:49:02,280 --> 00:49:07,100
+مفتوحة تعبتها كنت ولا مسكرة مفتوحة يعني مافيه ضغط
+
+445
+00:49:07,100 --> 00:49:18,880
+جوا لأن فيها thickness كمان وفي
+
+446
+00:49:18,880 --> 00:49:19,460
+جوا ضغط
+
+447
+00:49:22,390 --> 00:49:25,430
+لو خدت stress element بس من جوا خدت stress element
+
+448
+00:49:25,430 --> 00:49:30,330
+يعني احتبت هذا المقطع خدت stress element هنا
+
+449
+00:49:30,330 --> 00:49:35,610
+stress
+
+450
+00:49:35,610 --> 00:49:46,810
+element هطلع برا هحكي هذا ال X هذا ال Y وهذا ال Z
+
+451
+00:49:46,810 --> 00:49:55,160
+ال stress element هرسمههذه الموازنة ال X axis وهذه
+
+452
+00:49:55,160 --> 00:50:10,640
+ال Y axis وهذه ال Z axis هذا
+
+453
+00:50:10,640 --> 00:50:18,140
+اللي لم اتكبرته هيكون
+
+454
+00:50:18,140 --> 00:50:19,740
+باتجاه ال Z
+
+455
+00:50:23,190 --> 00:50:29,150
+فى هندي فى sigma tangential اللى هى sigma z فى
+
+456
+00:50:29,150 --> 00:50:34,510
+الحلقة هذه فهو هندي هين اللى هو ده هو اللى هو ب
+
+457
+00:50:34,510 --> 00:50:39,970
+stress بيحاول يمزق الانبوب بشكل هذا وفى هندي لو
+
+458
+00:50:39,970 --> 00:50:46,250
+كأخدت هندي هندي هنحكوا انه هندي في ال Y sigma
+
+459
+00:50:46,250 --> 00:50:52,030
+R و sigma R الانبوب مفتوح
+
+460
+00:50:55,840 --> 00:51:00,220
+مفتوح مانعته الغازات المضغوطة بتطلع ماشي تطلع على
+
+461
+00:51:00,220 --> 00:51:04,140
+ال .. على الوين؟ على الهواء الخارجي مانعته ال
+
+462
+00:51:04,140 --> 00:51:09,560
+gauge pressure ايش ساعة؟ صفر فبتعملش stress بهذا
+
+463
+00:51:09,560 --> 00:51:16,520
+الاتجاه نظريابس هو في الواقعية ألا يكون في الحقب
+
+464
+00:51:16,520 --> 00:51:21,080
+أو عرض الواقع ألا يكون في صمم للمتل ال stress لأنه
+
+465
+00:51:21,080 --> 00:51:26,520
+في حرارة كمان لا تنساش في عنده حرارة ال
+
+466
+00:51:26,520 --> 00:51:30,480
+temperature distribution مش منتظم بيصير تمددات
+
+467
+00:51:30,480 --> 00:51:38,700
+طولية وقطرية التمددات ممكن تعمل إجهدات جوابتك على
+
+468
+00:51:38,700 --> 00:51:45,340
+سؤالك؟هو النفس الدكتورفي في design ال manhole نفسه
+
+469
+00:51:45,340 --> 00:51:49,560
+في أي .. في أي application، في أحيانا بعمل manhole
+
+470
+00:51:49,560 --> 00:51:56,750
+على شكل بيضاويبينجأ بشكل بيضاوي؟ انت بتحكي المنهول
+
+471
+00:51:56,750 --> 00:52:01,310
+اشي تاني اللي هو المنهول اللي هو المنهول اللي هو
+
+472
+00:52:01,310 --> 00:52:01,970
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+473
+00:52:01,970 --> 00:52:02,990
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+474
+00:52:02,990 --> 00:52:02,990
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+475
+00:52:02,990 --> 00:52:02,990
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+476
+00:52:02,990 --> 00:52:03,010
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+477
+00:52:03,010 --> 00:52:03,010
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+478
+00:52:03,010 --> 00:52:03,290
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+479
+00:52:03,290 --> 00:52:06,610
+المنهول اللي هو المنهول اللي هو المنهول اللي هو
+
+480
+00:52:06,610 --> 00:52:09,990
+المنهول
+
+481
+00:52:09,990 --> 00:52:13,790
+اللي هو المنه
+
+482
+00:52:26,070 --> 00:52:35,870
+بشكل بيضاوي واخدت ايه stress element هيكون
+
+483
+00:52:35,870 --> 00:52:41,490
+فيه two surfaces او عندنا هاي stress component
+
+484
+00:52:41,490 --> 00:52:49,290
+tension و stress component tension و في واحدة منهم
+
+485
+00:52:49,290 --> 00:52:54,790
+هتكون عاشيعني ممكن نعتبر هذه hoop stress و هذه
+
+486
+00:52:54,790 --> 00:52:57,790
+hoop stress بس في two directions two hoop stress
+
+487
+00:52:57,790 --> 00:53:01,090
+component هذه في حالة spherical coordinates
+
+488
+00:53:01,090 --> 00:53:06,410
+هتستخدم إحداثيات spherical
+
+489
+00:53:06,410 --> 00:53:16,270
+اه ال sigma r
+
+490
+00:53:16,270 --> 00:53:17,810
+اللي لان في اتجاه ال y
+
+491
+00:53:21,100 --> 00:53:25,080
+الـ Sigma Z هي بتحاول تفتحها بالشكل هذا فبصي تعمل
+
+492
+00:53:25,080 --> 00:53:28,840
+ايه؟ هو في stress او تنجلش ال stress Sigma تنجلشها
+
+493
+00:53:28,840 --> 00:53:34,780
+في الاتجاه الطولي مش مغلق انبوب بطلع مافيش ضغط
+
+494
+00:53:34,780 --> 00:53:37,180
+مافيش ضغط بهذا الاتجاه اللي يعمل stress بهذا
+
+495
+00:53:37,180 --> 00:53:43,860
+الاتجاه لكن في ضغط داخل هنا Sigma I باتجاه ال Y
+
+496
+00:53:43,860 --> 00:53:46,840
+axis طبعا المفروض انا اخد ال element اخده هنا
+
+497
+00:53:55,030 --> 00:54:03,230
+الشيء المهم في الـ inner fibre هي
+
+498
+00:54:03,230 --> 00:54:06,550
+الـ
+
+499
+00:54:06,550 --> 00:54:07,770
+sigma تنجنشال maximum
+
+500
+00:54:10,830 --> 00:54:15,870
+اللي هو ايش؟ sigma radial المفروض انا اعمل طبعا
+
+501
+00:54:15,870 --> 00:54:19,310
+لازم اخش تفاصيل بعد هيك المفروض اعمل اللي هو
+
+502
+00:54:19,310 --> 00:54:24,410
+الارثومار circle انا عارف sigma واحد اللي انا برتب
+
+503
+00:54:24,410 --> 00:54:27,390
+sigma واحد و sigma اتنين و sigma تلاتة بيحس ان
+
+504
+00:54:27,390 --> 00:54:29,970
+sigma واحد اكبر من sigma اتنين اكبر من sigma تلاتة
+
+505
+00:54:29,970 --> 00:54:32,130
+sigma اتنين في الحالة .. sigma واحد في الحالة
+
+506
+00:54:32,130 --> 00:54:35,770
+بتكون ايش؟ sigma اتنين general sigma اتنين بتكون
+
+507
+00:54:35,770 --> 00:54:38,770
+سواء صفر و sigma تلاتة اللي هي minus ال pressure
+
+508
+00:54:40,270 --> 00:54:43,370
+بعدين يا بستخدم الحصر الثيرو بستخدمها لو بدى
+
+509
+00:54:43,370 --> 00:54:47,030
+استخدم ال maximum share stress theory بحسب ال
+
+510
+00:54:47,030 --> 00:54:49,050
+maximum share stress اللى هو sigma واحد معناه
+
+511
+00:54:49,050 --> 00:54:53,770
+sigma تلت على اتنين اللى هتكون اللى هي sigma
+
+512
+00:54:53,770 --> 00:54:58,630
+tangential minus minus هتسير يعني هتكون sigma
+
+513
+00:54:58,630 --> 00:55:02,310
+tangential زاد ال PI على اتنين تحسر maximum share
+
+514
+00:55:02,310 --> 00:55:06,330
+ومن هنا بتكمل خيوا ما نستبقش الأمور هذا الكلام في
+
+515
+00:55:06,330 --> 00:55:07,870
+chapter 5 اللى بنحكي عنه
+
+516
+00:55:23,470 --> 00:55:27,610
+طيب ممكن نستخدم ال .. ال .. ال .. ال theory of
+
+517
+00:55:27,610 --> 00:55:31,930
+thick cylinder نطبقها بطريقة تانية في حالة عندي
+
+518
+00:55:31,930 --> 00:55:38,030
+rotating rings عندي ring rotating rings زي .. زي
+
+519
+00:55:38,030 --> 00:55:46,040
+ال fly wheels بتطور بسرعةال blowers شفتعة الهواء
+
+520
+00:55:46,040 --> 00:55:50,680
+زي ال discs بتكون دور نتيجة طرد .. نتيجة طرد اذا
+
+521
+00:55:50,680 --> 00:55:56,680
+عندى اي جسم بدور ديسك بشكل هذا بدور
+
+522
+00:55:56,680 --> 00:56:06,040
+بسرعة زي omega حسيه القوة طرد مركزه لبرا فحسيه
+
+523
+00:56:06,040 --> 00:56:10,320
+اللي عندى اياش stresses ال .. اذا بتلاحظوا
+
+524
+00:56:10,320 --> 00:56:20,350
+المولينكس القديمالمولنكس القديم شاف المولنكس هذه
+
+525
+00:56:20,350 --> 00:56:30,510
+الشفرات هنا هذا
+
+526
+00:56:30,510 --> 00:56:38,510
+الشاف وعندي FPG عندي
+
+527
+00:56:38,510 --> 00:56:40,010
+العمود
+
+528
+00:56:43,450 --> 00:56:49,190
+هو العمود جاي من مطار بيلف كانت تكون هذه ايش ال
+
+529
+00:56:49,190 --> 00:56:53,670
+material بتاعتها القديم
+
+530
+00:56:53,670 --> 00:57:00,190
+مطار لما بيدور هذه انت بدخله فيه فراغ لما بتدور
+
+531
+00:57:00,190 --> 00:57:09,130
+ايش تفتح بتسكر عن هذه تدور معها طبعا فتحت نتيجة
+
+532
+00:57:09,130 --> 00:57:13,780
+قوة الطرد المركزي في عندي normalأزاي الـ
+
+533
+00:57:13,780 --> 00:57:17,340
+centrifugal clutch بالظبط ازاي ال clutch ال
+
+534
+00:57:17,340 --> 00:57:23,820
+centrifugal فهذه بتفتح و بتمسك عليها فنفس الاشي
+
+535
+00:57:23,820 --> 00:57:28,980
+ديسكات يعني هذه بتلاحظوا يعني مجرد اذا بتشغل ال
+
+536
+00:57:28,980 --> 00:57:37,780
+motor بتبين عادة معاك يعني بتفتح نفس الفكرة في ال
+
+537
+00:57:37,780 --> 00:57:42,860
+discs انها تجد قوة الطرد المركزي بس عند a normalهي
+
+538
+00:57:42,860 --> 00:57:52,140
+omega square في R هذه المسافة R حاسس ان عندي كمان
+
+539
+00:57:52,140 --> 00:57:57,140
+force قوة طارد مركزي لبرا اللي هي بيكون سواء M
+
+540
+00:57:57,140 --> 00:58:02,240
+omega square في R اللي هي A normal في H في R
+
+541
+00:58:06,930 --> 00:58:10,730
+فنتيزة قوة الطرد المركزى هتصير عندى tangential
+
+542
+00:58:10,730 --> 00:58:14,610
+stresses و radial stresses فى ال disk او ال
+
+543
+00:58:14,610 --> 00:58:21,150
+flywheel او ال blower فهتصير عندى tangential و
+
+544
+00:58:21,150 --> 00:58:27,010
+radial stresses فبصير
+
+545
+00:58:27,010 --> 00:58:33,930
+كأنه اناI apply pressures زي نفس فكرة ال thick
+
+546
+00:58:33,930 --> 00:58:40,610
+walled pressure cylinders اللي بيختلف الاختلاف ان
+
+547
+00:58:40,610 --> 00:58:44,890
+ال pressure ناتج عن inertia forces في حالة ال
+
+548
+00:58:44,890 --> 00:58:48,110
+thick cylinders ال pressure ناتج عن غازات او سوائل
+
+549
+00:58:51,130 --> 00:58:55,030
+ال .. ال .. ال conditions outside radius is larger
+
+550
+00:58:55,030 --> 00:58:59,210
+.. large compared with thickness يعني هنا أساس أنه
+
+551
+00:58:59,210 --> 00:59:02,390
+ال thickness is constant المعادلات الجاية هشوفها
+
+552
+00:59:02,390 --> 00:59:06,050
+stresses are constant over the thickness الجهدات
+
+553
+00:59:06,050 --> 00:59:08,450
+هتكون ثابتة على ال thickness هذه الفرضيات
+
+554
+00:59:08,450 --> 00:59:15,190
+للمعادلات الجاية إذا عندي disk
+
+555
+00:59:15,190 --> 00:59:18,910
+.. disk هي disk مفتوح
+
+556
+00:59:20,450 --> 00:59:27,890
+يعني لديه radius داخلي راي لديه radius خارجي ر او
+
+557
+00:59:27,890 --> 00:59:38,330
+بدور بسرعة زاوية أميجا سيكون هناك stress
+
+558
+00:59:38,330 --> 00:59:44,830
+طولية سيجما تنجينشيل وسيجما
+
+559
+00:59:47,560 --> 00:59:51,560
+معطاب للعلاقة هذه sigma tangential rho omega
+
+560
+00:59:51,560 --> 00:59:54,500
+square اللي هي رو ال density للمaterial بتاعة ال
+
+561
+00:59:54,500 --> 00:59:58,680
+disk ال omega السرعة الذهب دورها ال disk في تلاتة
+
+562
+00:59:58,680 --> 01:00:03,540
+زي نيو على تمانية نيو اللي هي ال Poisson ratio في
+
+563
+01:00:03,540 --> 01:00:07,120
+ر I square زي ر أسكوير زي ر I square ر أسكوير على
+
+564
+01:00:07,120 --> 01:00:10,080
+ر أسكوير minus واحد زي تلاتة نيو على تلاتة زي نيو
+
+565
+01:00:10,080 --> 01:00:14,140
+في ر أسكويرنفس مش المعادلة هذه لل radial stresses
+
+566
+01:00:14,140 --> 01:00:21,080
+نفس المعادلة تختلف هذه plus minus بس ال term هذا و
+
+567
+01:00:21,080 --> 01:00:24,660
+ال term هذا مختلف عن هذا ال term يعني ال term
+
+568
+01:00:24,660 --> 01:00:27,460
+الأول و التاني نفس الأشياء ال term التالت نفس
+
+569
+01:00:27,460 --> 01:00:31,040
+الأشياء بس بختلف الإشارة مختلف ال term التالت قيمة
+
+570
+01:00:31,040 --> 01:00:36,730
+مختلفةفنتيجة الـ rotation عند سرعة عالية بـ
+
+571
+01:00:36,730 --> 01:00:39,450
+cylindrical tangential او radial stresses due to
+
+572
+01:00:39,450 --> 01:00:47,950
+inertial forces قوة القصور الذاتية الان
+
+573
+01:00:47,950 --> 01:00:54,170
+اذا عندي انا الموضوع التاني على ال press و ال
+
+574
+01:00:54,170 --> 01:01:00,450
+shrink fit ال
+
+575
+01:01:00,450 --> 01:01:07,760
+press fitانا بكون عندى shaft و hole ال shaft بكون
+
+576
+01:01:07,760 --> 01:01:11,360
+قطره اكبر من ال hole بحشره حشر في اياش ال hole فده
+
+577
+01:01:11,360 --> 01:01:19,580
+press fit by force ال shrink fit ببرد الشافت او و
+
+578
+01:01:19,580 --> 01:01:26,640
+بسخن اياش ال hole بتمدد لما نيبرد بيصير ضغط عليه
+
+579
+01:01:27,510 --> 01:01:29,730
+طبعا بتعمل ال friction يعني ال normal force بتعمل
+
+580
+01:01:29,730 --> 01:01:31,950
+ال friction ال force يعني بتقاوم ال torque بشكل
+
+581
+01:01:31,950 --> 01:01:37,230
+كبرجد معظم ال gear boxes حاليا معمولة اللي هو ال
+
+582
+01:01:37,230 --> 01:01:42,330
+gears مثبتة باستخدام shrink fit طبعا shrink fit
+
+583
+01:01:42,330 --> 01:01:48,410
+ميزته بيعطيني high torque capacity رقم واحد رقم
+
+584
+01:01:48,410 --> 01:01:53,670
+اتنين مش محتاج اعمل key ways مجارة المجارة تعمل
+
+585
+01:01:53,670 --> 01:01:57,640
+stress concentration بستغنى عنهاو التركيبة في ال
+
+586
+01:01:57,640 --> 01:02:04,140
+mass production أسرع و أسهل منها في حالة بدها مش
+
+587
+01:02:04,140 --> 01:02:08,920
+machining كتير على ال mechanical parts في عندي ..
+
+588
+01:02:08,920 --> 01:02:15,480
+عندي .. عندي .. عندي هاي shaft و عندي هاي hole ال
+
+589
+01:02:15,480 --> 01:02:22,280
+hole او الشافت .. هاي الشافت الشافت مثقوب فيه ثقوب
+
+590
+01:02:24,160 --> 01:02:32,040
+في له ر اي و في
+
+591
+01:02:32,040 --> 01:02:44,120
+له common radius ر كابيتال و في ال whole له ر او
+
+592
+01:02:49,650 --> 01:02:54,870
+الان نتيجة انه في تداخل بين ال shaft و ال hole في
+
+593
+01:02:54,870 --> 01:03:03,210
+تداخل بمقدار delta radial distance دلتا
+
+594
+01:03:05,970 --> 01:03:09,310
+وهذا اكمل هذا هصير pressure على ال shaft pressure
+
+595
+01:03:09,310 --> 01:03:14,910
+من برا وعلى ال pressure من جوا ال pressure سواء
+
+596
+01:03:14,910 --> 01:03:17,890
+كان حصل ايش تدرس انت اعتبره من برا او من جوا ال
+
+597
+01:03:17,890 --> 01:03:25,130
+pressure بين اتنين باعتمد على قيمة ايش delta وعلى
+
+598
+01:03:25,130 --> 01:03:29,520
+ال materialsلل both parts لل shaft و ال hole يعني
+
+599
+01:03:29,520 --> 01:03:33,820
+مبين اندي هي ال modulus of elasticity و باين ال
+
+600
+01:03:33,820 --> 01:03:37,280
+poison ratio فاهم فاهم اندي هاد ال E O ال modulus
+
+601
+01:03:37,280 --> 01:03:41,980
+of elasticity لل outer part و هاد ال modulus of
+
+602
+01:03:41,980 --> 01:03:45,740
+elasticity لل inner part هاد ال poison ratio لل
+
+603
+01:03:45,740 --> 01:03:50,460
+outside part هاد ال poison ratio لل inside part
+
+604
+01:03:53,110 --> 01:03:56,710
+فقيمة ال pressure بتزيد كل ما زاد ال interference
+
+605
+01:03:56,710 --> 01:04:01,930
+و بتعتمد برضه على ال material properties الموديلس
+
+606
+01:04:01,930 --> 01:04:05,290
+والاسيستي المدرس الموديلس والاسيستي بتمثل زمبراكية
+
+607
+01:04:05,290 --> 01:04:12,410
+المادة المادة كأنها زمبراك وضادة كل
+
+608
+01:04:12,410 --> 01:04:17,490
+ما كان الموديلس الاستعالج كتير كل ما كان ال
+
+609
+01:04:17,490 --> 01:04:22,600
+interference أصعبكل ما كان interference أصعب يعني
+
+610
+01:04:22,600 --> 01:04:27,260
+لو أنا بده أحشر shaft في قطعة مطات سهل أمغطها صح
+
+611
+01:04:27,260 --> 01:04:32,100
+لكن لو بده أضغط قطعة الحديد في حديد صعب كتير لأن
+
+612
+01:04:32,100 --> 01:04:34,880
+ال modulus velocity بتاعة الحديد أعلى كتير من
+
+613
+01:04:34,880 --> 01:04:36,980
+modulus velocity للمطات
+
+614
+01:04:43,190 --> 01:04:46,410
+طبعا في حالة خاصة اذا كان if both cylinders are of
+
+615
+01:04:46,410 --> 01:04:52,630
+the same material بتكون ال EI بيساوي ال EO و ال UO
+
+616
+01:04:52,630 --> 01:04:56,490
+بيساوي ال UI بيصير معادلة أبسط بيكون ال pressure
+
+617
+01:04:56,490 --> 01:05:00,690
+is given by this equation في حالة ان ال inner part
+
+618
+01:05:00,690 --> 01:05:03,450
+و ال outer part لهم نفس ال material
+
+619
+01:05:15,100 --> 01:05:19,520
+طبعا I will apply المعادلات
+
+620
+01:05:19,520 --> 01:05:26,900
+بتاعة ال thick cylinders في حالة عندي cylinder
+
+621
+01:05:26,900 --> 01:05:30,540
+عليها pressure from the outside pressure from the
+
+622
+01:05:30,540 --> 01:05:34,580
+inside في عندي tangential stress component و عندي
+
+623
+01:05:34,580 --> 01:05:36,980
+radial stress component موطنة اللي لقيتها دي رودي
+
+624
+01:05:36,980 --> 01:05:43,490
+حكينا عنها الان لو بدى اخدال inner part ال inner
+
+625
+01:05:43,490 --> 01:05:47,650
+part اللي هو الشفت الشفت متعرض لضغط من برا ولا من
+
+626
+01:05:47,650 --> 01:05:52,850
+جوا؟ outside يعني ال P I عليه شو يساوي؟ zero و ال
+
+627
+01:05:52,850 --> 01:05:59,790
+P O بيساوياش ال P P I بيساوي zero و P O بيساوي P و
+
+628
+01:05:59,790 --> 01:06:05,690
+ال most critical جاية في ال interface بين الشفت و
+
+629
+01:06:05,690 --> 01:06:10,300
+ال hole يعني عندعندنا من ال radius بيستوي R
+
+630
+01:06:10,300 --> 01:06:14,120
+كابيتال وبيكون في عندي قيمة ال pressure بيستوي P
+
+631
+01:06:14,120 --> 01:06:20,180
+يعني at R ال sigma تنجلش على ال inner member at R
+
+632
+01:06:20,180 --> 01:06:26,060
+بيستوي R كابيتال نعمل ال simplification بنعمل في
+
+633
+01:06:26,060 --> 01:06:33,180
+المعادلة السابقة اللي هي هذه بنحط ال P I بيستوي
+
+634
+01:06:33,180 --> 01:06:38,840
+Zeroيعني هذا ال term روح و هذا ال term بروح بنعوض
+
+635
+01:06:38,840 --> 01:06:43,380
+عن R ب R capital و بحسب ال sigma tangential
+
+636
+01:06:43,380 --> 01:06:50,860
+بالنسبة لل outer member عليه ضغط من جوا صح ال P O
+
+637
+01:06:50,860 --> 01:06:56,780
+بالساوية سفر و P و I الوقين بالساويات P برضه نفس
+
+638
+01:06:56,780 --> 01:07:00,320
+الاشي بيعوض عن R بالساوية R capital في معادة ال
+
+639
+01:07:00,320 --> 01:07:04,740
+sigma radialو بحسب اللي هي sigma radial عند ال
+
+640
+01:07:04,740 --> 01:07:07,740
+interference اللي هي P في RO square زي R square
+
+641
+01:07:07,740 --> 01:07:12,120
+على RO square minus R square بالطريقة هذه حسبت
+
+642
+01:07:12,120 --> 01:07:16,280
+tangential stress و radial stress at the
+
+643
+01:07:16,280 --> 01:07:19,180
+interference between the two mating parts اللي هو
+
+644
+01:07:19,180 --> 01:07:20,360
+الشافت و ال whole
+
+645
+01:07:35,040 --> 01:07:41,360
+طبعا طالما عرفت ال .. ال .. ال tangential stress
+
+646
+01:07:41,360 --> 01:07:47,640
+at the interference يعني ممكن احسب ال torque
+
+647
+01:07:47,640 --> 01:07:52,080
+capacity ال torque capacity لل .. لل assembly
+
+648
+01:07:52,080 --> 01:07:59,960
+torque capacity لل assembly ال torque capacity لل
+
+649
+01:07:59,960 --> 01:08:05,570
+assembly هتكونstress في إيش؟ tangential stress
+
+650
+01:08:05,570 --> 01:08:12,290
+هحاول يعمل moment في surface area تعطيني إيش؟
+
+651
+01:08:12,290 --> 01:08:20,590
+force tangential force في radius إيش تعطيني؟
+
+652
+01:08:20,590 --> 01:08:26,590
+تعطيني torque تعطيني torque جربوا فحصوه لحالكوا
+
+653
+01:08:27,580 --> 01:08:31,560
+تطلع على press and shrink fit torque capacity
+
+654
+01:08:31,560 --> 01:08:44,280
+calculation تطلع على torque capacity of
+
+655
+01:08:44,280 --> 01:08:49,960
+press and shrink fits
+
+656
+01:09:04,550 --> 01:09:16,890
+طيب هنحكي أخر إشي و نخلص المحاضرة الان
+
+657
+01:09:16,890 --> 01:09:21,610
+إذا فاني temperature effect some mechanical part و
+
+658
+01:09:21,610 --> 01:09:24,830
+سخنته هصيرله تمدد
+
+659
+01:09:27,530 --> 01:09:30,990
+التمدد أو الـ strain لكل واحدة الطول لكل واحدة
+
+660
+01:09:30,990 --> 01:09:34,030
+الطول أبسل X بالسواء أبسل Y بالسواء أبسل Z بالسواء
+
+661
+01:09:34,030 --> 01:09:37,830
+Alpha في Delta T Delta T الفرق داشرة الحرارة Alpha
+
+662
+01:09:37,830 --> 01:09:43,510
+معامل التمدد الطولي معامل
+
+663
+01:09:43,510 --> 01:09:51,050
+التمدد الحراري في جدول تلاتة تلاتة معطيني معامل
+
+664
+01:09:51,050 --> 01:09:52,910
+التمدد الحراري
+
+665
+01:09:54,810 --> 01:09:58,270
+لـ different materials عندك aluminium, brass,
+
+666
+01:09:58,430 --> 01:10:01,050
+carbon steel, cast iron, magnesium, nickel,
+
+667
+01:10:01,690 --> 01:10:06,230
+stainless steel, tungsten وعطينا بوحدات مختلفة
+
+668
+01:10:06,230 --> 01:10:14,030
+باستخدام السلسة scale او فيهرانهايت scale وعطينا
+
+669
+01:10:14,030 --> 01:10:20,010
+هذه القيم الألفة لأن طالما ال mechanical member
+
+670
+01:10:20,010 --> 01:10:25,910
+بسخنه is freeبتمدد بس مافيش فيه stresses لكن لو
+
+671
+01:10:25,910 --> 01:10:29,750
+جيت bar هاي
+
+672
+01:10:29,750 --> 01:10:42,070
+ال bar مسكته ثبته و بعدين سخنت بدي
+
+673
+01:10:42,070 --> 01:10:45,950
+أحاول أنا أيش؟ هيحاول اتمدد بس أنا معناه اتمدد ايش
+
+674
+01:10:45,950 --> 01:10:51,050
+بيصير عندي؟ بيصير stresses على فرض انه thick
+
+675
+01:10:51,050 --> 01:10:51,430
+enough
+
+676
+01:10:54,070 --> 01:10:59,110
+بصير في عنده stresses نتيجة بيحاول هو يتمدد بقيمة
+
+677
+01:10:59,110 --> 01:11:04,230
+epsilon x لكن انا مانعه لو كانت تمدد في ال elastic
+
+678
+01:11:04,230 --> 01:11:12,330
+regionيعني بقى ممكن أحسب أبسرن X اللي بيساوي Alpha
+
+679
+01:11:12,330 --> 01:11:21,450
+Delta T بعدين Sigma X بيساوي أبسرن X في E إذا كنا
+
+680
+01:11:21,450 --> 01:11:27,190
+في ال elastic region وكان معدن اللي هي هذه
+
+681
+01:11:27,190 --> 01:11:30,810
+المعادلة هايكون إيهاش إذا من المنطقى كل ال stress
+
+682
+01:11:30,810 --> 01:11:35,170
+هي compression ولا tension compression
+
+683
+01:11:35,170 --> 01:11:40,150
+هايكونلو انا mano فبحاول اتمدد هو مضغوط من الجهة
+
+684
+01:11:40,150 --> 01:11:43,390
+مضغوط هو بيصير اندي compression stress ال sigma
+
+685
+01:11:43,390 --> 01:11:47,690
+سواء minus E في epsilon minus alpha delta T في E
+
+686
+01:11:47,690 --> 01:12:01,330
+اذا كان عندي plate plate و ممسوك من الأطراف وعطيته
+
+687
+01:12:01,330 --> 01:12:08,260
+سخنته هحاول اتمدد بهذا الاتجاه وهذا الاتجاهطبعا
+
+688
+01:12:08,260 --> 01:12:13,900
+نتيجة الـ Poisson Ratio Effect هكون فيه اذا فاكرين
+
+689
+01:12:13,900 --> 01:12:20,280
+أبسرن
+
+690
+01:12:20,280 --> 01:12:24,060
+X سواحد
+
+691
+01:12:24,060 --> 01:12:32,280
+على E في سيجما X minus U في سيجما Y زائد سيجما Z
+
+692
+01:12:32,280 --> 01:12:43,910
+صح؟ و أبسرنو Y سواحدة ل E في Sigma Y minus U في
+
+693
+01:12:43,910 --> 01:12:55,890
+Sigma Z Sigma X زي Sigma Z بس
+
+694
+01:12:55,890 --> 01:13:00,640
+اختار علاقات هذهبنوجد علاقة الاسترس طبعا هيصير
+
+695
+01:13:00,640 --> 01:13:04,260
+متساوى بالاتجاه ال X وال Y في الحالة هذه ممسوك من
+
+696
+01:13:04,260 --> 01:13:09,660
+اجهتين هيكون ال sigma أساوي minus Alpha Delta T في
+
+697
+01:13:09,660 --> 01:13:15,260
+E على 1 minus Nu فدخلت ال poison ratio effect على
+
+698
+01:13:15,260 --> 01:13:15,740
+الخط
+
+699
+01:13:23,010 --> 01:13:27,950
+لحد هنا بنكون خلصنا المحاضرة المراجعة بنكمل تاكلوا
+
+700
+01:13:27,950 --> 01:13:28,310
+العافية
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/icLNiNsLHbs_postprocess.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/icLNiNsLHbs_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..540bf606c4d125bce7da7b01ff3e1b46cf4f0bb9
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/icLNiNsLHbs_postprocess.srt
@@ -0,0 +1,2840 @@
+1
+00:00:05,040 --> 00:00:07,880
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:07,880 --> 00:00:13,480
+وبركاته اليوم هنستكمل ال stress and load analysis
+
+3
+00:00:13,480 --> 00:00:17,520
+chapter three machine design واحدالمحاضرة اللى
+
+4
+00:00:17,520 --> 00:00:22,520
+فاتت حكينا عن ال bending stretches في straight
+
+5
+00:00:22,520 --> 00:00:28,940
+beams جيبنا المعادلة حكينا sigma X بصفة و minus MZ
+
+6
+00:00:28,940 --> 00:00:36,240
+في Y على IZ و خلينا مثال بعدين حكينا درستنا اللى
+
+7
+00:00:36,240 --> 00:00:43,130
+هو bending في two planes يعني كان في عندىمز ومي
+
+8
+00:00:43,130 --> 00:00:48,750
+شوفنا كيف كنا نجمع ال stress و حلينا example اليوم
+
+9
+00:00:48,750 --> 00:00:52,510
+هنكمل هندرس ال shear stresses for beams in bending
+
+10
+00:00:52,510 --> 00:00:56,850
+دايما وين في bending بيكون في عندي transverse
+
+11
+00:00:56,850 --> 00:01:07,490
+shear فين بيبين عندي هين beam هذا ال x axis هذا ال
+
+12
+00:01:07,490 --> 00:01:18,450
+y axisفى عليه some load w خت element dx على مسافة
+
+13
+00:01:18,450 --> 00:01:30,250
+x هكوين
+
+14
+00:01:30,250 --> 00:01:39,450
+دى هي انشيرV و Bending Moment M After Delta X
+
+15
+00:01:39,450 --> 00:01:50,870
+الشير هيتغير هصير Differential V زائد DV و
+
+16
+00:01:50,870 --> 00:01:56,450
+ال moment هصير M زائد DM
+
+17
+00:02:04,520 --> 00:02:10,280
+هذه المثلوفة DX اللى أخدته اللى هطلعته برا نتيجة
+
+18
+00:02:10,280 --> 00:02:18,200
+ال bending هكون عنده normal stress على الجهة دي
+
+19
+00:02:18,200 --> 00:02:22,760
+هندهين compression و compression minus M في Y على
+
+20
+00:02:22,760 --> 00:02:29,880
+I وهين ال moment قيمتهااللي هي في عيني جزئية م و
+
+21
+00:02:29,880 --> 00:02:37,240
+في جزئية dm يعني هكون m في y على i زائد dmy على i
+
+22
+00:02:37,240 --> 00:02:52,860
+لو أخدت element برتفاع
+
+23
+00:02:52,860 --> 00:02:53,700
+dy
+
+24
+00:03:05,220 --> 00:03:11,540
+هتكون دي اكس دي واي دي اكس دي واي دي اكس
+
+25
+00:03:11,540 --> 00:03:19,100
+دي واي دي اكس دي واي دي اكس
+
+26
+00:03:19,100 --> 00:03:20,660
+دي واي دي اكس دي اكس دي واي دي اكس دي اكس دي واي
+
+27
+00:03:20,660 --> 00:03:20,760
+دي اكس دي اكس دي اكس دي اكس دي اكس دي اكس دي اكس
+
+28
+00:03:20,760 --> 00:03:20,940
+دي اكس دي اكس دي اكس دي اكس دي اكس دي اكس دي اكس
+
+29
+00:03:44,550 --> 00:03:51,110
+البعد هذا اللي هو البعد التالت بي
+
+30
+00:03:51,110 --> 00:03:58,010
+الان على الجهة هذا ال element هذا على الجهة هذه
+
+31
+00:03:58,010 --> 00:04:01,370
+حيكون عنده
+
+32
+00:04:01,370 --> 00:04:09,990
+اف اف هتكون سيجما اكس ب area صح؟ على الجهة التانية
+
+33
+00:04:09,990 --> 00:04:13,950
+برضه هنا حيكون اف
+
+34
+00:04:15,940 --> 00:04:23,140
+زاد DF اللي هتكون ال stress هذا في ال area لاحظوا
+
+35
+00:04:23,140 --> 00:04:28,960
+في عندى هذه الجزئية من هذا الطرف ات cancel out مع
+
+36
+00:04:28,960 --> 00:04:35,460
+هذه صح؟ هذه الجاية زي هيك و هذه عكسها يعني هذه هت
+
+37
+00:04:35,460 --> 00:04:39,480
+cancel .. هتظل هذه معناته هتظل على جهة هذه اللي هي
+
+38
+00:04:42,500 --> 00:04:50,360
+force بالسواء التكامل طبعا هذه المسافة هي y واحد
+
+39
+00:04:50,360 --> 00:04:56,920
+هذا ال x axis التكامل
+
+40
+00:04:56,920 --> 00:05:00,060
+من y واحد لل c
+
+41
+00:05:12,680 --> 00:05:19,380
+هتكون عندى اللى هو دي اف بالاساس
+
+42
+00:05:19,380 --> 00:05:28,300
+بالسواء sigma X في D area sigma
+
+43
+00:05:28,300 --> 00:05:35,020
+X هتكون اذا فاكر ان ال sigma بالسواء M في Y على I
+
+44
+00:05:35,020 --> 00:05:39,840
+هذه المعادلة المعروفة عندكوا هتكون عند اللى هى DM
+
+45
+00:05:41,990 --> 00:05:53,110
+في Y على I في الـ D Area عبارة عن Delta Y في البعد
+
+46
+00:05:53,110 --> 00:06:07,350
+التالت B Delta Y في B Delta Y في
+
+47
+00:06:07,350 --> 00:06:09,550
+B Delta Y أو دعنا نسميها D A
+
+48
+00:06:28,870 --> 00:06:37,090
+أنا once I define إشي و بتطلع على رسم كلمة سالب و
+
+49
+00:06:37,090 --> 00:06:38,170
+موجب مالهاش معناه
+
+50
+00:06:43,080 --> 00:06:46,600
+أيوة هو هي .. لأن هنا عنده compression هو يعني فهو
+
+51
+00:06:46,600 --> 00:06:49,960
+حاط اتجاه هذه ال force بيعدى الاتجاه يعني عندهين
+
+52
+00:06:49,960 --> 00:06:55,860
+compression ال moment موجة بقى و ال why إيش موجة و
+
+53
+00:06:55,860 --> 00:06:57,860
+هيطلع السلب compression ال stress compression
+
+54
+00:06:57,860 --> 00:07:06,020
+هينتج عنه force بيعدى الاتجاه خلنا
+
+55
+00:07:06,020 --> 00:07:08,700
+نسمي هذه دي ايه؟
+
+56
+00:07:11,850 --> 00:07:20,490
+هيكون دي برضه shear هين تاو وهين تاو و العرض هذا
+
+57
+00:07:20,490 --> 00:07:24,370
+dx
+
+58
+00:07:24,370 --> 00:07:28,650
+المفروض
+
+59
+00:07:28,650 --> 00:07:35,010
+نعمل force balance لل element هذا to balance this
+
+60
+00:07:35,010 --> 00:07:41,400
+force Fلازم يكون في نت شير تاو تجاه ال X axis
+
+61
+00:07:41,400 --> 00:07:46,860
+summation force تجاه ال X axis بالساوية Zero يعني
+
+62
+00:07:46,860 --> 00:07:52,920
+اذا تحكي عن التاو في ال area اللي هي عبارة عن DX
+
+63
+00:07:52,920 --> 00:08:03,000
+في B B DX حساوية تكامل اللي هي ال force اللي هي
+
+64
+00:08:03,000 --> 00:08:04,860
+عندي DM
+
+65
+00:08:07,130 --> 00:08:18,090
+Y على I في DA X الطرفين على B DX حسين دي التاو
+
+66
+00:08:18,090 --> 00:08:31,490
+تكامل DM على DX في Y على BI DA
+
+67
+00:08:39,390 --> 00:08:44,150
+DM by DX ايش هي ال
+
+68
+00:08:44,150 --> 00:08:56,110
+share يعني هتكون تساوي تكامل VY على BIDA يعني
+
+69
+00:08:56,110 --> 00:09:06,160
+هتكون ال share هتطلع برا V و I برا VI بتكامل YDAمن
+
+70
+00:09:06,160 --> 00:09:17,160
+Y1 ل C هذا ال term سموه Q يعني
+
+71
+00:09:17,160 --> 00:09:28,720
+ال Tao هتساوي V على I بي في Q هذا مره طالع في ال
+
+72
+00:09:28,720 --> 00:09:29,560
+mechanics و ال material
+
+73
+00:09:33,850 --> 00:09:41,390
+الـ Q هي ال moment of remaining area اللي عندها
+
+74
+00:09:41,390 --> 00:09:44,870
+بدنا نحسب ال share stress ال moment of remaining
+
+75
+00:09:44,870 --> 00:09:47,810
+area عند النقطة اللي بدنا نحسب عندها ال share
+
+76
+00:09:47,810 --> 00:09:53,650
+stress طيب خليني أشوف نقطة حالة خاصة لو بدنا نحسب
+
+77
+00:09:53,650 --> 00:09:54,050
+ال Q
+
+78
+00:09:59,300 --> 00:10:08,020
+عندي beam مقطع مستطيل beam
+
+79
+00:10:08,020 --> 00:10:15,220
+مقطع مستطيل وفي عن نقطة معينة يعني هاي ال X هاي ال
+
+80
+00:10:15,220 --> 00:10:18,720
+Y هاي
+
+81
+00:10:18,720 --> 00:10:25,400
+ال X Axis فعندي هنشير V و Moment M
+
+82
+00:10:32,070 --> 00:10:41,070
+بدي احسب ال key المقطع مستطيل فانا اخد
+
+83
+00:10:41,070 --> 00:10:50,350
+element على
+
+84
+00:10:50,350 --> 00:10:57,310
+بعد y و
+
+85
+00:10:57,310 --> 00:11:12,310
+ارتفع ال elementdy هذا عرض المستطيل بيحس
+
+86
+00:11:12,310 --> 00:11:25,890
+كيو من y واحد يعني for a given y واحد ل c ارتفاع
+
+87
+00:11:25,890 --> 00:11:28,570
+المقطع h
+
+88
+00:11:39,800 --> 00:11:52,280
+الـ Q هتكون تساوي تكامل من Y1 ل C ل YDA الـ
+
+89
+00:11:52,280 --> 00:11:55,560
+DA عبارة عن
+
+90
+00:11:58,550 --> 00:12:10,750
+فى ايش فى dy هتكون تساوي تكامل y b dy من y واحد ل
+
+91
+00:12:10,750 --> 00:12:20,310
+c ال b ثابت بي تكامل من y واحد ل c ل y dy تكامل
+
+92
+00:12:20,310 --> 00:12:27,830
+هذا شو تساويY تربيع اتنين صح هتكون B على اتنين في
+
+93
+00:12:27,830 --> 00:12:38,450
+Y تربيع من Y واحد لل C يعني هكون B على اتنين في
+
+94
+00:12:38,450 --> 00:12:44,150
+C تربيع ناقص Y واحد تربيع
+
+95
+00:12:46,510 --> 00:12:56,770
+معناته ال Tao هيكون سواء V في Q على I في B يعني V
+
+96
+00:12:56,770 --> 00:13:03,190
+ال I للمقطة
+
+97
+00:13:03,190 --> 00:13:12,710
+هذا حوالين ال Z axis بتكون تساوي ال I واحد على
+
+98
+00:13:12,710 --> 00:13:14,870
+اتناش B
+
+99
+00:13:16,530 --> 00:13:22,190
+H تكيب يعني هتكون واحد على اتناش ب ال H في الحالة
+
+100
+00:13:22,190 --> 00:13:28,850
+هتكون اتنين C صح في اتنين C كل تكيب يعني هيكون
+
+101
+00:13:28,850 --> 00:13:36,990
+تمانية ع اتناش يعني اتنين ع تلاتة صح اتنين ع تلاتة
+
+102
+00:13:36,990 --> 00:13:40,830
+ب C تكيب صح
+
+103
+00:13:43,450 --> 00:13:56,950
+يعني الطاقة تكون سوى V Q بي على اتنين في C تربيع
+
+104
+00:13:56,950 --> 00:14:09,190
+ناقص Y واحد تربيع ال I اللي هي اتنين ع تلاتة بي C
+
+105
+00:14:09,190 --> 00:14:12,570
+تكيب فاش
+
+106
+00:14:13,860 --> 00:14:19,920
+ت بي يعني
+
+107
+00:14:19,920 --> 00:14:31,940
+هتروح بي مع بي الان ال area للمقطع ايش تستوي ال
+
+108
+00:14:31,940 --> 00:14:43,660
+بي في اتنين سي صح؟ يعني الترا و هتكون تستويهاخد c
+
+109
+00:14:43,660 --> 00:14:53,240
+ع مشترك انا هاخد c هحكي v c تربيع على اتنين في
+
+110
+00:14:53,240 --> 00:15:03,280
+اتنين على تلاتة ب c تكيب في واحد ناقص y واحد على c
+
+111
+00:15:03,280 --> 00:15:09,800
+لكل تربيع خد c ع مشترك طلعتها برا هيروح عند ال c
+
+112
+00:15:09,800 --> 00:15:18,080
+تربيعمع C تكيب هصير عندي هطلق
+
+113
+00:15:18,080 --> 00:15:31,260
+هصير تلاتة على اتنين V على اتنين BC في واحد minus
+
+114
+00:15:31,260 --> 00:15:40,780
+Y واحد على C الكل تربيع هذا ايش حكينا ال Aيعني
+
+115
+00:15:40,780 --> 00:15:51,460
+هتساوى الـ tau ثلاثة V على اتنين A في واحد minus Y
+
+116
+00:15:51,460 --> 00:15:58,220
+واحد على C الكل الترابع هذا
+
+117
+00:15:58,220 --> 00:16:01,440
+في حالة مقطع مستطيل اللي هي هذه المعادلة
+
+118
+00:16:23,390 --> 00:16:31,510
+طيب V متى بتكون maximum؟
+
+119
+00:16:31,510 --> 00:16:36,410
+لما ال term هذا .. يعني هذه constant لما ال term
+
+120
+00:16:36,410 --> 00:16:42,570
+هذا يكون ايش؟ maximum متى هذا بيكون maximum؟ اللي
+
+121
+00:16:42,570 --> 00:16:47,090
+هي سفر يعني عند neutral axis لما ال Y واحد سوى سفر
+
+122
+00:16:47,090 --> 00:16:51,910
+بيكون الشيري stress بيكون maximumبالنص ملعقته V
+
+123
+00:16:51,910 --> 00:16:58,370
+tau maximum بالساوية
+
+124
+00:16:58,370 --> 00:17:09,850
+تلاتة V ع اتنين A at Y واحد على C بالساوية سفر عند
+
+125
+00:17:09,850 --> 00:17:13,710
+ال neutral axis بيكون ال bending moment ال ال ال
+
+126
+00:17:13,710 --> 00:17:18,190
+stress due to bending moment Zero بتكون maximum
+
+127
+00:17:18,190 --> 00:17:19,310
+عند ال outer fiber
+
+128
+00:17:35,440 --> 00:17:39,840
+بنفس ال logic لو عملنا دائرة نحسب ال Q لها
+
+129
+00:17:52,660 --> 00:18:11,580
+لو عنا دائرة ده
+
+130
+00:18:11,580 --> 00:18:13,420
+نفس الـ Q هناخد element
+
+131
+00:18:26,170 --> 00:18:31,650
+هذا Y هذا Z هذا
+
+132
+00:18:31,650 --> 00:18:37,370
+Y و
+
+133
+00:18:37,370 --> 00:18:48,430
+هذا ايش؟ Dy بدى احسب ال Q من Y واحد نحكي له C هذي
+
+134
+00:18:48,430 --> 00:18:52,650
+عشان نسميها نسميها
+
+135
+00:18:52,650 --> 00:18:52,910
+R
+
+136
+00:19:00,550 --> 00:19:13,710
+الـ Q هتكون ساوية تكامل YDA من Y1 ل R هتكون تكامل
+
+137
+00:19:13,710 --> 00:19:31,070
+من Y1 ل R ل D A هذا بالنسبالي فقه كم؟ Z صح؟وهذه
+
+138
+00:19:31,070 --> 00:19:43,830
+قيمتها أيه؟ z صح؟ يعني هتكون z مع z اتنين z في dy
+
+139
+00:19:43,830 --> 00:19:51,790
+y في اتنين z dy
+
+140
+00:19:51,790 --> 00:19:55,090
+ال
+
+141
+00:19:55,090 --> 00:19:59,790
+z متغيرة دكتور عملها dz ولا كده؟ لأ ال z متغيرة
+
+142
+00:20:01,090 --> 00:20:08,450
+يعني معناته انا هاخد علاقة هتكون عندي Y تربيع زائد
+
+143
+00:20:08,450 --> 00:20:17,150
+Z تربيع دائما بالسواء ايش R تربيع معناته Z تربيع
+
+144
+00:20:17,150 --> 00:20:29,390
+او Z بالسواء R تربيع minus Y تربيع تحت الجدريعني
+
+145
+00:20:29,390 --> 00:20:36,550
+انا هتكون من Y واحد ل R ل اتنين Y في الجذر
+
+146
+00:20:36,550 --> 00:20:50,670
+التربيعي ل R تربيع ناقص Y تربيع DY ممكن
+
+147
+00:20:50,670 --> 00:21:00,820
+احكي USo R تربيع ناقص Y تربيع، صح؟ بظبط؟معناته DU
+
+148
+00:21:00,820 --> 00:21:04,760
+بسوا
+
+149
+00:21:04,760 --> 00:21:13,940
+ناقص اتنين Y، DY يعني
+
+150
+00:21:13,940 --> 00:21:16,840
+هذه هتصير Q تكامل
+
+151
+00:21:18,670 --> 00:21:26,830
+تنين y dy هي minus ايش minus u هذي تنين y dy هي
+
+152
+00:21:26,830 --> 00:21:32,910
+minus u اللي هي هدف هذي و هذي ايش جزر
+
+153
+00:21:32,910 --> 00:21:36,610
+ايش جزر
+
+154
+00:21:36,610 --> 00:21:41,350
+ال u اللي
+
+155
+00:21:41,350 --> 00:21:47,430
+هي هذي u اص نص صح
+
+156
+00:21:57,160 --> 00:22:09,620
+الان ال 2y dy عبارة عن minus du صح هذا فيه اص نص
+
+157
+00:22:09,620 --> 00:22:17,500
+ايه خلصنا صح يعني هاسير ناقص
+
+158
+00:22:17,500 --> 00:22:25,300
+2 عال 3U از تلاتة على اتنين نرجحها زي ما كانت
+
+159
+00:22:25,300 --> 00:22:32,600
+هتكون ناقص اتنين على تلاتة ال U R
+
+160
+00:22:32,600 --> 00:22:42,980
+تربية ناقص Y تربية از تلاتة على اتنين من Y واحد ل
+
+161
+00:22:42,980 --> 00:22:47,900
+R واحد صح؟ يعني هتكون ناقص اتنين على تلاتة
+
+162
+00:22:53,650 --> 00:23:01,390
+فى عوض من R هذا طبعا عوض من R هذا مش هتكون ساوى
+
+163
+00:23:01,390 --> 00:23:06,290
+صفر ناقص
+
+164
+00:23:06,290 --> 00:23:19,940
+R تربيه ناقص Y1 تربيع أس تلاتة على اتنين يعني
+
+165
+00:23:19,940 --> 00:23:28,140
+هتكون تساوي اتنين ع تلاتة اتنين
+
+166
+00:23:28,140 --> 00:23:39,040
+ع تلاتة في R تربيع ناقص Y واحد تربيع أس تلاتة على
+
+167
+00:23:39,040 --> 00:23:39,420
+اتنين
+
+168
+00:23:50,120 --> 00:23:56,560
+معناته الـ TAU على المقطع اللي مضور هتكون سواء VQ
+
+169
+00:23:56,560 --> 00:24:05,080
+على I بشكل عام في H في
+
+170
+00:24:05,080 --> 00:24:13,760
+B الـ B اللي هي H متغيرة
+
+171
+00:24:18,890 --> 00:24:29,270
+ب اللي هي ايش اتنين اتنين زد اتنين زد هتساوي خلنا
+
+172
+00:24:29,270 --> 00:24:34,010
+نحكي ال I في الساوية عند الدائرة باي
+
+173
+00:24:34,010 --> 00:24:45,130
+على اربع ستين دي اص اربعة او باي على اربعة ار اص
+
+174
+00:24:45,130 --> 00:24:46,290
+اربعة صح؟
+
+175
+00:24:49,840 --> 00:25:05,020
+يعني هتكون V على باي على أربعة R قصة أربعة في Q
+
+176
+00:25:05,020 --> 00:25:08,220
+اتنين
+
+177
+00:25:08,220 --> 00:25:18,000
+على تلاتة في R تربيع ناقص Y واحد تربيع قصة تلاتة
+
+178
+00:25:18,000 --> 00:25:19,420
+على اتنين
+
+179
+00:25:33,410 --> 00:25:45,750
+طيب على بي اللي هي عبارة عن اش اللي هي اتنين زد
+
+180
+00:25:45,750 --> 00:25:52,010
+طيب
+
+181
+00:25:53,310 --> 00:25:57,610
+متى بتكون ال .. ال .. ال .. شو اسمه؟ متى بتكون ال
+
+182
+00:25:57,610 --> 00:26:03,530
+tau maximum لما
+
+183
+00:26:03,530 --> 00:26:06,510
+ال .. هذا maximum يعني لما ال y واحد ساوي هش سفر
+
+184
+00:26:06,510 --> 00:26:12,510
+يعني ال tau max بالساوية
+
+185
+00:26:12,510 --> 00:26:22,470
+V على او اربع V على Pi R أقصى أربعة
+
+186
+00:26:27,530 --> 00:26:35,690
+لما هذه صفر صح هصير R تربيع .. هصير هذا R تكييب صح
+
+187
+00:26:35,690 --> 00:26:44,710
+ف R تكييب في اتنين ع تلاتة في اتنين ع تلاتة R
+
+188
+00:26:44,710 --> 00:26:53,170
+تكييب في ايش في اتنين R لان ال Z يعني ان انت
+
+189
+00:26:53,170 --> 00:27:01,310
+مالعكس ايش الساويةتنين R في اتنين اربع R صح؟
+
+190
+00:27:01,310 --> 00:27:11,950
+اربع R يعني اختصره اربع مع اربع R تكييب مع R يعني
+
+191
+00:27:11,950 --> 00:27:23,590
+هتكون صفة اتنين V ع تلاتة by R تربيع
+
+192
+00:27:30,580 --> 00:27:40,900
+بس فيهم رقم غلط شكله فيهم
+
+193
+00:27:40,900 --> 00:27:52,140
+some error راجعوه هتطلع ال tau max بتساوي
+
+194
+00:27:52,140 --> 00:27:55,580
+اربعة V على تلاتة
+
+195
+00:27:58,690 --> 00:28:01,250
+أرجوها طيب
+
+196
+00:28:09,410 --> 00:28:13,250
+طبعا الشكل تيابة تلات تنين معطيني اللي هو ال .. ال
+
+197
+00:28:13,250 --> 00:28:16,710
+.. ال tau max ل different cross sections معطيني
+
+198
+00:28:16,710 --> 00:28:21,710
+المستطيل تلات على اتنين V على A للدائرة اربع V على
+
+199
+00:28:21,710 --> 00:28:30,250
+تلاتة A للانبوب مقطع انبوب اتنين V على A ل I B ال
+
+200
+00:28:30,250 --> 00:28:32,750
+tau max of V على ال A ال web
+
+201
+00:28:37,990 --> 00:28:46,290
+اللي هبقى بنشوف ال significance
+
+202
+00:28:46,290 --> 00:28:50,950
+انا
+
+203
+00:28:50,950 --> 00:28:53,430
+هاكي انا وين فيه bending ممكن انا ناقش share
+
+204
+00:28:53,430 --> 00:29:01,430
+process share بنشوف ال significance ل share stress
+
+205
+00:29:01,430 --> 00:29:07,920
+بالمقارنة مع ال bending stressالاختار كان تليفر
+
+206
+00:29:07,920 --> 00:29:09,260
+بيه مقطع مستطيل
+
+207
+00:29:32,360 --> 00:29:40,040
+هذا كان تليفر بيه و في عليه بأثر هشيا محمود في
+
+208
+00:29:40,040 --> 00:29:53,380
+عليه force ال بيه مدى طوله L و
+
+209
+00:29:53,380 --> 00:29:57,360
+مقطعه هذا بيه في H
+
+210
+00:30:02,180 --> 00:30:06,600
+طبعا ال moment هتكون maximum في النقطة هذه صح ال M
+
+211
+00:30:06,600 --> 00:30:09,620
+هتسوى
+
+212
+00:30:09,620 --> 00:30:21,660
+F في L ال moment سوى F في L و ال V بساوية
+
+213
+00:30:21,660 --> 00:30:27,220
+بساوية F ال V بساوية F
+
+214
+00:30:31,320 --> 00:30:43,280
+لو خدت اي element هاي
+
+215
+00:30:43,280 --> 00:30:59,100
+ال X axis هاي ال Y axis Y و هاي ال Z خدت
+
+216
+00:30:59,100 --> 00:31:00,180
+المقطع و طلعته برا
+
+217
+00:31:09,060 --> 00:31:22,540
+هذه ز اكسس وهذه Y اكسس اخد
+
+218
+00:31:22,540 --> 00:31:31,720
+اي فترة Y سيكون
+
+219
+00:31:31,720 --> 00:31:35,900
+لدي Sigma
+
+220
+00:31:35,900 --> 00:31:48,290
+X due to bendingم قيمتها في Y على I صح؟ هيكون
+
+221
+00:31:48,290 --> 00:32:01,690
+ال normal stress علاقة
+
+222
+00:32:01,690 --> 00:32:10,850
+خطية صح؟ M في Y على I ال M بالساوية F في Lفي Y ال
+
+223
+00:32:10,850 --> 00:32:17,130
+I اللي هي بي على اتناش طبعا بي على اتناش H تكيب
+
+224
+00:32:17,130 --> 00:32:23,990
+يعني هتساوي اتناشر
+
+225
+00:32:23,990 --> 00:32:37,890
+FL على بي H تكيب في Yالـ share stress هنا share
+
+226
+00:32:37,890 --> 00:32:44,330
+stress distribution تاو هيكون non
+
+227
+00:32:44,330 --> 00:32:50,110
+linear التاو التاو
+
+228
+00:32:50,110 --> 00:33:04,230
+هيكون V تلاتة V ع اتنين A في واحد ناقص Y تربيع
+
+229
+00:33:08,350 --> 00:33:17,070
+في القرأن Y على Y تربيع في C تربيع حيساوى
+
+230
+00:33:17,070 --> 00:33:33,390
+تلاتة F ال A يبقى على ال B في H في واحد ناقص Y
+
+231
+00:33:33,390 --> 00:33:35,930
+تربيع على C تربيع
+
+232
+00:33:38,740 --> 00:33:44,880
+هذا stress element stress element لو بدأ ارسم more
+
+233
+00:33:44,880 --> 00:33:47,860
+circle يعني هكون عندى stress element بالشكل هذا
+
+234
+00:33:47,860 --> 00:33:52,160
+هكون
+
+235
+00:33:52,160 --> 00:33:58,040
+عندى sigma X وعندي
+
+236
+00:34:07,260 --> 00:34:12,940
+تاو سمي x,y,x,z تاو
+
+237
+00:34:12,940 --> 00:34:19,760
+لو أرسم ال more circle لهذه هيكون
+
+238
+00:34:19,760 --> 00:34:27,960
+more circle جايب الشكل هذا ال center
+
+239
+00:34:27,960 --> 00:34:32,320
+تاع more circle هتكون عند sigma x زي sigma 1 على 2
+
+240
+00:34:32,320 --> 00:34:39,480
+صح؟ يعني هتكون عند sigma xعلى اتنين وال radius
+
+241
+00:34:39,480 --> 00:34:43,780
+هكون جزر التربية ل sigma x minus sigma y على اتنين
+
+242
+00:34:43,780 --> 00:34:51,400
+لكل تربية زائد tau xy تربية يعني هكون جزر التربية
+
+243
+00:34:51,400 --> 00:35:03,000
+ل sigma x تربية على اربعة زائد tau تربية
+
+244
+00:35:18,770 --> 00:35:26,910
+طيب ال tau max ال tau max at
+
+245
+00:35:26,910 --> 00:35:32,290
+any element هكون ال radius طوا more circle صح؟ و
+
+246
+00:35:32,290 --> 00:35:39,830
+هكون الجزر التربيعي ل sigma تربيع على أربعة زائد
+
+247
+00:35:39,830 --> 00:35:44,250
+tau تربيع يعني
+
+248
+00:35:48,190 --> 00:36:00,930
+هذا ساوى هذا السجن الجزر التربيهي هذا
+
+249
+00:36:00,930 --> 00:36:14,210
+ربع نربع هذا اتناش تربيه F تربيه L تربيه Y تربيه
+
+250
+00:36:15,470 --> 00:36:22,590
+على P تربية H6 هتمثل
+
+251
+00:36:22,590 --> 00:36:33,170
+الـ Sigma الجزء هذا زائد T تربية زائد تسعة F تربية
+
+252
+00:36:33,170 --> 00:36:45,480
+على أربعة P تربية H تربية في واحد minus Yتربيه على
+
+253
+00:36:45,480 --> 00:36:54,760
+C تربيه الكل تربيه هنطلع
+
+254
+00:36:54,760 --> 00:37:07,720
+برا ال F هتطلع برا هذا و نطلع ال L و نطلع ال B و
+
+255
+00:37:07,720 --> 00:37:08,120
+ال H
+
+256
+00:37:18,470 --> 00:37:25,650
+وعندي ربع نطلع اتنين برا وعندي تسعة نطلع التلاتة
+
+257
+00:37:25,650 --> 00:37:32,430
+برا في الجزر التربية حصف في المعادلة اللي هادر هي
+
+258
+00:37:32,430 --> 00:37:51,790
+اربعة اربعة L على H لكل تربيةفي y على c الكل
+
+259
+00:37:51,790 --> 00:37:58,490
+تربيع زائد اللي
+
+260
+00:37:58,490 --> 00:38:06,770
+هو واحد ناقص y على c الكل تربيع الكل تربيع اللي هي
+
+261
+00:38:06,770 --> 00:38:13,410
+هذه المعادلة هذا الجزء ايش مثل ناتج عن الشير صح؟
+
+262
+00:38:15,940 --> 00:38:23,320
+فهذا ناتج عن ايه؟ ال bending moment هذا ناتج عن ال
+
+263
+00:38:23,320 --> 00:38:27,820
+bending moment
+
+264
+00:38:27,820 --> 00:38:31,520
+ال
+
+265
+00:38:31,520 --> 00:38:34,340
+maximum shear stress ناتج عن شغلتي أنا ال bending
+
+266
+00:38:34,340 --> 00:38:38,780
+moment لو احنا انا و يعوضنا اللي هي sigma X وهذا
+
+267
+00:38:38,780 --> 00:38:40,740
+ناتج عن ال shear
+
+268
+00:38:45,310 --> 00:38:51,230
+الان هناخد في عين الاعتبار ال
+
+269
+00:38:51,230 --> 00:39:00,590
+slender ratio يعني هاخد L على H هذه one variable و
+
+270
+00:39:00,590 --> 00:39:06,450
+هاخد Y على C another variable بده اخد L على H as a
+
+271
+00:39:06,450 --> 00:39:11,550
+variable و Y على C as another variable
+
+272
+00:39:18,840 --> 00:39:26,900
+طيب for any given L على H لو ثبتنا L على H و بعدين
+
+273
+00:39:26,900 --> 00:39:32,060
+نلعب في ال Y على C ال Y على C عند neutral X مش
+
+274
+00:39:32,060 --> 00:39:40,840
+ويساوي Zero يعني انا هتصفح عند Zero مفيش شير مفيش
+
+275
+00:39:40,840 --> 00:39:44,700
+يعني يعني يعني يعني بيكون الشير Max وY على Zero
+
+276
+00:39:44,700 --> 00:39:49,810
+هتبساوي سفربيظل هذه واحد وهذه اش هتسفر يعني مافيش
+
+277
+00:39:49,810 --> 00:39:57,850
+binding مافيش بنج هتسفر هي تلاتة F على اتنين BH
+
+278
+00:39:57,850 --> 00:40:03,470
+اتنين BH الان
+
+279
+00:40:03,470 --> 00:40:12,910
+for any L على H at Y على C بالستوال Zero ال
+
+280
+00:40:12,910 --> 00:40:18,980
+L على H وين المبينةبينها هنا طب معناته سفرت معناته
+
+281
+00:40:18,980 --> 00:40:26,880
+بتأثرش معناته for one على سي بالصفر ال maximum
+
+282
+00:40:26,880 --> 00:40:34,410
+share stress is maximumلأن مافي bending effect
+
+283
+00:40:34,410 --> 00:40:38,210
+بمعنى يعني ال section هنا عند y على c بساوة سفر
+
+284
+00:40:38,210 --> 00:40:41,650
+بيعطيني ال maximum shear stress و ال section هنا
+
+285
+00:40:41,650 --> 00:40:46,450
+برضه عند ال neutral axis بيعطيني برضه نفس ال
+
+286
+00:40:46,450 --> 00:40:48,250
+maximum shear stress و ال section هنا نفسي ليش
+
+287
+00:40:48,250 --> 00:40:53,430
+واقع كذا معناه مابتحتملش على المسافة هذا for y على
+
+288
+00:40:53,430 --> 00:40:59,510
+c بالساوة سفرطيب ناخد ال other extreme for y على c
+
+289
+00:40:59,510 --> 00:41:05,590
+بالساوية واحد يعني احنا احنا هي وين عند ال outer
+
+290
+00:41:05,590 --> 00:41:10,230
+fiber بيكونش y على c بالساوية واحد معناته هاد
+
+291
+00:41:10,230 --> 00:41:13,870
+هتسفر معناته مافيش shear عنده بيضالي لو ماسيطرياش
+
+292
+00:41:13,870 --> 00:41:22,090
+ال bending طبعا هاد هيتلع برا هتصير العلاقة خطية
+
+293
+00:41:22,090 --> 00:41:29,840
+بين ال maximum shear stressو ال Y على C فانا ممكن
+
+294
+00:41:29,840 --> 00:41:34,740
+ايش أسوي يعني هي linear لو ثبتت ال Y على C ثبتت ال
+
+295
+00:41:34,740 --> 00:41:38,600
+Y على C بتكون
+
+296
+00:41:38,600 --> 00:41:44,480
+linear مع ال L على H و لو ثبتت ال L على H بتكون
+
+297
+00:41:44,480 --> 00:41:50,060
+linear مع ال Y على C هو ايش هنا نسوي هنا ماخدلي
+
+298
+00:41:50,060 --> 00:41:54,920
+حالة ال Y على C بالساعة واحدبتكون ال bending
+
+299
+00:41:54,920 --> 00:42:00,520
+moment او ال maximum shear stress ال maximum
+
+300
+00:42:00,520 --> 00:42:07,240
+stress بيكون linear مع ال L على H ف
+
+301
+00:42:07,240 --> 00:42:13,000
+for Y على C بالساوية واحد يعني عند ال outer fiber
+
+302
+00:42:13,000 --> 00:42:18,420
+مافيش عند ال shear بيكون المسيطر بشكل كامل ال
+
+303
+00:42:18,420 --> 00:42:23,000
+bending ف ال maximum shear stress is due only to
+
+304
+00:42:23,000 --> 00:42:31,310
+bendingمومنت بتغير linearly مع ال L على H for Y
+
+305
+00:42:31,310 --> 00:42:39,930
+على C بالساوية واحد طيب for any value other than Y
+
+306
+00:42:39,930 --> 00:42:44,110
+على C بالساوية سفر Y على C بالساوية واحد بيكون
+
+307
+00:42:44,110 --> 00:42:50,850
+موجود شير موجود إيش بين المتنين الموجودين فهو
+
+308
+00:42:50,850 --> 00:42:56,810
+يماخد اندحالةy على c بيساوي اتنين ع تلاتة y على c
+
+309
+00:42:56,810 --> 00:42:58,450
+بيساوي اتنين ع تلاتة وy على c بيساوي اتنين ع تلاتة
+
+310
+00:42:58,450 --> 00:42:58,990
+اتنين ع تلاتة وy على c بيساوي اتنين ع تلاتة وy على
+
+311
+00:42:58,990 --> 00:42:59,010
+c بيساوي اتنين ع تلاتة وy على c بيساوي اتنين ع
+
+312
+00:42:59,010 --> 00:42:59,130
+تلاتة وy على c بيساوي اتنين ع تلاتة وy على c
+
+313
+00:42:59,130 --> 00:43:08,110
+وy
+
+314
+00:43:08,110 --> 00:43:20,250
+على c بيساوي اتنين ع تلاتة وy على
+
+315
+00:43:20,250 --> 00:43:28,340
+c بيساوي ابعتمدش على ال على H هذا الشيء مابعتمد
+
+316
+00:43:28,340 --> 00:43:35,340
+على ال على H فكل ما ال ال على H بتقل ال effect على
+
+317
+00:43:35,340 --> 00:43:39,260
+ال bending معله بقل او كل ما ال ال على H بتزيد ال
+
+318
+00:43:39,260 --> 00:43:42,720
+effect على ال bending moment بزيد معناته اذا كان
+
+319
+00:43:42,720 --> 00:43:46,640
+عند بيم طويل كتير ببدأ قيمة
+
+320
+00:43:48,790 --> 00:43:52,770
+أو تأثير ال direct shear على maximum shear stress
+
+321
+00:43:52,770 --> 00:43:56,750
+بيبدأ يقل كتير كل ما ازود ال L على H المعنى ان كل
+
+322
+00:43:56,750 --> 00:44:02,850
+ما كان ال beam طويل ممكن يكون ال shear stress is
+
+323
+00:44:02,850 --> 00:44:12,510
+not significant اهمله فإذا كان ال beam طويل هذا
+
+324
+00:44:12,510 --> 00:44:19,250
+هيكبر كتير هذا ثابتوبالتالي بالمحصلة بال total اذا
+
+325
+00:44:19,250 --> 00:44:22,790
+هذا ثابت وهذا بيكبر مانعته هذا قيمة هذا بالنسبة
+
+326
+00:44:22,790 --> 00:44:29,910
+لكل اشهر مالها بتقل نسبيا لكن قيمته مطلقاش ثابتة
+
+327
+00:44:29,910 --> 00:44:37,470
+فمانعته كل ما صار ال beam أقصر يعني بدل خمس متر
+
+328
+00:44:37,470 --> 00:44:42,150
+صارت طوله عشرة صنطة حسيت تقرير almost مش فيه
+
+329
+00:44:42,150 --> 00:44:47,010
+bendingهل تصير أنا قريب من حالة القص المباشر؟ قريب
+
+330
+00:44:47,010 --> 00:44:53,690
+جدا من حالة القص المباشر فمعناته for bees كل ما
+
+331
+00:44:53,690 --> 00:45:00,790
+يزيد ال L على H كل ما تصير ال effect بتاع ال
+
+332
+00:45:00,790 --> 00:45:02,590
+direct shear insignificant
+
+333
+00:45:06,510 --> 00:45:09,130
+و كل ما بيقلل الـ L على ال H كل ما بيصير ال effect
+
+334
+00:45:09,130 --> 00:45:13,970
+بتاع ال .. ال .. ال direct shear more significant
+
+335
+00:45:13,970 --> 00:45:21,110
+عشان إذا عندي pin و في يعني هاي عمود قصير و في
+
+336
+00:45:21,110 --> 00:45:26,210
+عليه loading ال .. ال most critic في الحلقة هدياش؟
+
+337
+00:45:26,210 --> 00:45:35,370
+shear .. shear مافيش عندياش moment نشوف
+
+338
+00:45:35,370 --> 00:45:35,850
+مثال
+
+339
+00:45:40,950 --> 00:45:45,970
+المثال عندى beam طوله
+
+340
+00:45:45,970 --> 00:45:52,350
+اتماشر انش بيأثر على جودة الانش من طرف الشمال قوة
+
+341
+00:45:52,350 --> 00:45:57,350
+قيمتها اربعمائة و تمانية باون فورس this supported
+
+342
+00:45:57,350 --> 00:46:02,070
+ادنى يعني اندي support هنا و support هنا المقطع
+
+343
+00:46:02,070 --> 00:46:07,520
+تار على شكل I beamو تم تقريبه بشكل هذا ال IBM
+
+344
+00:46:07,520 --> 00:46:11,940
+لتسيي الحسابات يعني ال fillets اشمالها انشالت عشان
+
+345
+00:46:11,940 --> 00:46:23,220
+تسهل الحسابات الموجودة في البنية الشاشة points
+
+346
+00:46:23,220 --> 00:46:27,200
+of interest are labeled a,b,c and d في نقاط بتهمنا
+
+347
+00:46:27,200 --> 00:46:37,490
+اللي هي نقطةA وB وC وD at
+
+348
+00:46:37,490 --> 00:46:41,630
+the
+
+349
+00:46:41,630 --> 00:46:46,710
+critical axial location find the following
+
+350
+00:46:46,710 --> 00:46:51,930
+informationprofile of distribution of transverse
+
+351
+00:46:51,930 --> 00:46:56,590
+shear stress obtaining values at each of the
+
+352
+00:46:56,590 --> 00:46:59,870
+points of interest نشوف كيف transverse shear
+
+353
+00:46:59,870 --> 00:47:05,570
+stress بتغير عند كل النقاط A وB وC وD و ال benig
+
+354
+00:47:05,570 --> 00:47:12,930
+stress at A وB وC و
+
+355
+00:47:12,930 --> 00:47:18,300
+ال maximum shear stress يعني بعد محسبلترانزشير
+
+356
+00:47:18,300 --> 00:47:22,800
+استرس والبندق استرس بحسب maximum shear stress
+
+357
+00:47:22,800 --> 00:47:27,820
+خليني
+
+358
+00:47:27,820 --> 00:47:32,980
+اعمل اللي هو المعادلة عند ال sigma x اول شي بتجاه
+
+359
+00:47:32,980 --> 00:47:35,800
+ال axis of direction ايش ال most critical location
+
+360
+00:47:35,800 --> 00:47:40,980
+او كيف هعرف ال most critical location يعني
+
+361
+00:47:40,980 --> 00:47:46,120
+اول شي بيدوش ال reaction forces صح هذا النقطة اه
+
+362
+00:47:48,870 --> 00:47:57,730
+هذه Y هذه X هخص
+
+363
+00:47:57,730 --> 00:48:09,670
+moment حوالين O هتكون
+
+364
+00:48:09,670 --> 00:48:19,840
+عندي ناقص تلاتة في 488زاد ار اتنين في اتناش زاد
+
+365
+00:48:19,840 --> 00:48:28,800
+اتناش ار اتنين معناته ار اتنين بالساوية اربعين و
+
+366
+00:48:28,800 --> 00:48:33,180
+تمانين على اربع يعني اربع تمانين عارف على اربع
+
+367
+00:48:33,180 --> 00:48:38,740
+اتناش اتنين مظبوط pound force
+
+368
+00:48:42,460 --> 00:48:47,840
+بعدها summation of forces باتجاه الوار سواء zero
+
+369
+00:48:47,840 --> 00:49:00,180
+بتساوي R واحد ناقص اربعمية و تمانية و تمانين زائد
+
+370
+00:49:00,180 --> 00:49:05,200
+R اتنين اللي هي مية و اتنين و عشرين منها R واحد
+
+371
+00:49:05,200 --> 00:49:10,760
+بالساوية ستة ستة تلاتة
+
+372
+00:49:16,730 --> 00:49:23,230
+طيب كيف حاجة ال critical location عكس
+
+373
+00:49:23,230 --> 00:49:35,130
+ال location برسم ال shear و من و ال diagram ال
+
+374
+00:49:35,130 --> 00:49:42,690
+shear diagram هذه
+
+375
+00:49:42,690 --> 00:49:47,860
+تلاتمية و ستة ستين وهذه minusمية و اتنين و عشرين
+
+376
+00:49:47,860 --> 00:49:53,460
+هذا الشهير يعني
+
+377
+00:49:53,460 --> 00:50:02,700
+ال building moment هتكون
+
+378
+00:50:02,700 --> 00:50:09,600
+تلات مين و ستة و ستين في تلاتة ستة بتلاتة تمانتاش
+
+379
+00:50:09,600 --> 00:50:13,920
+ستة بتلاتة بتسعتاش تلاتة بتلاتة بعشرة
+
+380
+00:50:17,080 --> 00:50:25,300
+انش صح؟ صح معناته
+
+381
+00:50:25,300 --> 00:50:31,660
+where is the most critical location
+
+382
+00:50:31,660 --> 00:50:41,380
+عند النقطة هذه
+
+383
+00:50:41,380 --> 00:50:43,900
+بالظبط عندها ولا كيف؟
+
+384
+00:50:47,220 --> 00:50:49,920
+أنا بحكي على أكس ال direction في اتجاه ال x axis
+
+385
+00:50:49,920 --> 00:50:57,380
+على يسارها just and x بيستوى تلاتة minus لأنه
+
+386
+00:50:57,380 --> 00:51:00,800
+الشير بيكون تلات مية و ستة و ستين هي الماكس مائة
+
+387
+00:51:00,800 --> 00:51:05,940
+اتنين و عشرين يعني ال most critical location most
+
+388
+00:51:05,940 --> 00:51:10,820
+critical location
+
+389
+00:51:13,360 --> 00:51:25,120
+is at x equal تلاتة minus يعني
+
+390
+00:51:25,120 --> 00:51:30,080
+just to the left of the load
+
+391
+00:51:45,130 --> 00:51:49,850
+يعني بيكون ال V تكون تساوي تلت مية و ستة و ستين
+
+392
+00:51:49,850 --> 00:51:59,370
+pound و ال moment بتكون الف و تمانية وتسعين pound
+
+393
+00:51:59,370 --> 00:52:08,650
+انش واضح
+
+394
+00:52:08,650 --> 00:52:12,370
+ان ده هيكون السطح العلوي compression و السطح
+
+395
+00:52:12,370 --> 00:52:14,530
+السفلياش tension
+
+396
+00:52:18,340 --> 00:52:24,080
+الـ Sigma X
+
+397
+00:52:24,080 --> 00:52:33,640
+قيمتها بسوء M في Y على I معناته
+
+398
+00:52:33,640 --> 00:52:41,880
+أطلوب نحسب ال I لل section هذا ال I حوالين ال Z
+
+399
+00:52:41,880 --> 00:52:43,400
+Axis هذا ال Z Axis
+
+400
+00:52:56,310 --> 00:53:04,770
+هاخد معناته هعمل جدول معناه
+
+401
+00:53:04,770 --> 00:53:10,050
+محسوب هاي ال neutral axis مفيش
+
+402
+00:53:10,050 --> 00:53:18,630
+ده احسبه هنحكي هعمل انا ده two areas هعمل ال area
+
+403
+00:53:18,630 --> 00:53:21,750
+هذه وهذه وهذه
+
+404
+00:53:25,080 --> 00:53:29,920
+أه ليش؟ بلزمنيش أستخدم برنامج ال access theory لكن
+
+405
+00:53:29,920 --> 00:53:33,440
+لو استخدت هذه .. هذه و هذه بلزمني أستخدم برنامج ال
+
+406
+00:53:33,440 --> 00:53:39,540
+access theory فهذا يكون عندي ال .. ال area ال
+
+407
+00:53:39,540 --> 00:53:44,520
+number واحد
+
+408
+00:53:44,520 --> 00:53:55,400
+اتنين بدي أحكي ال B و ال H ال Bال B ال area
+
+409
+00:53:55,400 --> 00:53:59,580
+الكبيرة اللي
+
+410
+00:53:59,580 --> 00:54:03,300
+هي اتنين
+
+411
+00:54:03,300 --> 00:54:08,620
+point تلاتة تلاتة اتنين point
+
+412
+00:54:08,620 --> 00:54:16,480
+تلاتة تلاتة وال H تلاتة
+
+413
+00:54:16,480 --> 00:54:27,410
+ال area التانيةالواحدة منهم هتكون one point oh
+
+414
+00:54:27,410 --> 00:54:33,990
+تمانية في
+
+415
+00:54:33,990 --> 00:54:41,590
+تلاتة minus point اتنين ستة minus point اتنين ستة
+
+416
+00:54:41,590 --> 00:54:47,030
+يعني تلاتة ناقص point اتنين خمسة اكم اتنين point
+
+417
+00:54:47,030 --> 00:54:52,310
+اربعة تمانية معناته ال area
+
+418
+00:54:56,440 --> 00:54:59,780
+هتكون تلاتة في اتنين من تلاتة لاتة يعني ايه تسعة
+
+419
+00:54:59,780 --> 00:55:03,460
+ستة
+
+420
+00:55:03,460 --> 00:55:14,360
+هنا هادف هادف في اتنين بالسالب اضرب
+
+421
+00:55:14,360 --> 00:55:16,340
+اتنين من اربع اتنين من اتنين من اربع اتنين من
+
+422
+00:55:16,340 --> 00:55:16,940
+اتنين من اتنين من اتنين من اتنين من اتنين من اتنين
+
+423
+00:55:16,940 --> 00:55:18,280
+من اتنين من اتنين من اتنين من اتنين من اتنين من
+
+424
+00:55:18,280 --> 00:55:18,420
+من اتنين من اتن
+
+425
+00:55:32,270 --> 00:55:37,630
+ال I هتكون
+
+426
+00:55:37,630 --> 00:55:43,970
+واحد على اتناش بي اتش تكيب اللي واحد على اتناش في
+
+427
+00:55:43,970 --> 00:55:45,930
+اتنين point تلاتة تلاتة ال I
+
+428
+00:56:20,670 --> 00:56:23,830
+معناه ان ال net area اترح من ال 6.99
+
+429
+00:56:31,380 --> 00:56:38,640
+وحد point وحد point وحد point وحد point وحد point
+
+430
+00:56:38,640 --> 00:56:44,680
+وحد point وحد point وحد point وحد point وحد point
+
+431
+00:56:44,680 --> 00:56:44,700
+وحد point وحد point وحد point وحد point وحد point
+
+432
+00:56:44,700 --> 00:56:45,960
+وحد point وحد point وحد point وحد point وحد point
+
+433
+00:56:45,960 --> 00:56:46,000
+وحد point وحد point وحد point وحد point وحد point
+
+434
+00:56:46,000 --> 00:56:46,300
+وحد point وحد point وحد point وحد point وحد point
+
+435
+00:56:46,300 --> 00:56:46,600
+وحد point وحد point وحد point وحد point وحد point
+
+436
+00:56:46,600 --> 00:56:49,180
+وحد point وحد point وحد point وحد point وحد point
+
+437
+00:56:49,180 --> 00:56:55,540
+وحد point وحد point وحد point وحد point وحد
+
+438
+00:56:56,950 --> 00:57:01,230
+العيلة التانية واحد على اتناش في بي اتش تكيب في
+
+439
+00:57:01,230 --> 00:57:05,290
+اتنين بعد ما تحسب واحد على اتناش بي اتش تكيب و
+
+440
+00:57:05,290 --> 00:57:12,370
+دوبها في اتنين اتنين
+
+441
+00:57:12,370 --> 00:57:18,510
+بالسالب اتنين في
+
+442
+00:57:18,510 --> 00:57:25,650
+كم رقم؟ خمس اتنين يعني ال net ايش هيكون؟
+
+443
+00:57:29,510 --> 00:57:37,210
+اطرحه هكون صفر ستة
+
+444
+00:57:37,210 --> 00:57:50,030
+تسعة اربعة اتنين مظهر انش
+
+445
+00:57:50,030 --> 00:57:51,450
+قصة اربعة
+
+446
+00:57:58,440 --> 00:58:01,500
+معناة ال I حسبنا هتطلع تنين بونت أربع تسعة ستة انش
+
+447
+00:58:01,500 --> 00:58:09,900
+قصة أربعة ال
+
+448
+00:58:09,900 --> 00:58:22,100
+sigma X م في Y على I هي الساوية ال M عندي ألف
+
+449
+00:58:22,100 --> 00:58:26,720
+وتمانية وتسعين على
+
+450
+00:58:28,830 --> 00:58:37,370
+خلّيني احنا هتلزمنا لأ هادى ال
+
+451
+00:58:37,370 --> 00:58:47,830
+Sigma X هسه M في Y على I هتساوي ألف وتمانية وتسعين
+
+452
+00:58:47,830 --> 00:59:00,590
+Y على اتنين point اربعة تسع ستة سفراسيبوها اربعمية
+
+453
+00:59:00,590 --> 00:59:07,710
+وتسعة وتلاتين اربعمية وتسعة وتلاتين point ايش تسعة
+
+454
+00:59:07,710 --> 00:59:17,290
+واحد تسعة واحد صح why why why تسعة why طيب التاو
+
+455
+00:59:17,290 --> 00:59:26,490
+ايش متساوي تلاتة
+
+456
+00:59:28,070 --> 00:59:35,930
+مش تلاتة بالساوية
+
+457
+00:59:35,930 --> 00:59:41,090
+VQ على
+
+458
+00:59:41,090 --> 00:59:53,410
+I في B VQ على I في B يعني عندي QP variables بس
+
+459
+00:59:53,410 --> 00:59:57,010
+هاود عن VI V اللي هي تلاتمية و ستة و ستين
+
+460
+00:59:59,700 --> 01:00:07,660
+Q ال I اندي اكم؟ اتنين point اربع تسعة ستة سفر B
+
+461
+01:00:07,660 --> 01:00:14,080
+يعني هتساوي مية ستة واربعين point ستة تلاتة اربع
+
+462
+01:00:14,080 --> 01:00:18,720
+ستة مية ستة واربعين point ستة تلاتة اربع ستة ستة
+
+463
+01:00:18,720 --> 01:00:24,720
+تلاتة اربع ستة Q على B
+
+464
+01:00:33,020 --> 01:00:40,000
+معناة at point of interest عندي
+
+465
+01:00:40,000 --> 01:00:43,320
+.. عندي ال point of interest عندي النقاط a و b و c
+
+466
+01:00:43,320 --> 01:00:51,420
+و d عندي هى عندي ال point ال
+
+467
+01:00:51,420 --> 01:00:55,420
+point and
+
+468
+01:00:55,420 --> 01:00:59,440
+a ايش ال b بتساوي؟
+
+469
+01:01:02,570 --> 01:01:12,250
+عند نقطة a ال
+
+470
+01:01:12,250 --> 01:01:17,990
+bh ساوى point واحد سبعة اللي هو هذا العرض point
+
+471
+01:01:17,990 --> 01:01:23,670
+واحد سبعة point
+
+472
+01:01:23,670 --> 01:01:27,470
+واحد سبعة
+
+473
+01:01:34,970 --> 01:01:44,770
+والـ Q ايش بتساوي ال moment of remaining area يعني
+
+474
+01:01:44,770 --> 01:01:48,370
+above ال neutral axis ال area above neutral axis
+
+475
+01:01:48,370 --> 01:01:57,790
+يعني نقطة A هي هذه المساحة كل هذه المساحة moment
+
+476
+01:01:57,790 --> 01:02:02,900
+of this area above this axisلما تحاول ال
+
+477
+01:02:02,900 --> 01:02:07,360
+integration تجري ل YDA moment of area moment of
+
+478
+01:02:07,360 --> 01:02:12,400
+area moment of this remaining area يعني دي عبارة
+
+479
+01:02:12,400 --> 01:02:18,360
+عن two areas هذه هذه
+
+480
+01:02:18,360 --> 01:02:21,940
+اللي عرضها point واحد سبعة في واحد point اتنين
+
+481
+01:02:21,940 --> 01:02:22,460
+اربعة
+
+482
+01:02:31,830 --> 01:02:38,150
+هتكون point واحد سبعة في
+
+483
+01:02:38,150 --> 01:02:46,550
+واحد point اتنين اربعة في هذه
+
+484
+01:02:46,550 --> 01:02:50,230
+بُعد ال area هذه النص اللي واحد point اتنين اربعة
+
+485
+01:02:50,230 --> 01:03:06,360
+على اتنين هيكون هذه تربيةعلى اتنين زاد ال
+
+486
+01:03:06,360 --> 01:03:14,040
+area هذه عبارة عن اتنين point تلاتة تلاتة في اتنين
+
+487
+01:03:14,040 --> 01:03:22,160
+point ستة اتنين point تلاتة تلاتة في point اتنين
+
+488
+01:03:22,160 --> 01:03:31,640
+ستة في المسافةفي المسافة هذه اللي هي عبارة عن واحد
+
+489
+01:03:31,640 --> 01:03:36,860
+point اتنين اربع زاد point واحد تلاتة نص هذه يعني
+
+490
+01:03:36,860 --> 01:03:45,360
+واحد point تلاتة سبعة في واحد point
+
+491
+01:03:45,360 --> 01:03:53,580
+تلاتة سبعة حيث ساوى حسبوها
+
+492
+01:04:22,190 --> 01:04:30,690
+بنقطة تسعة ستة تسعة ستة تسعة ستة تسعة ستة تسعة ستة
+
+493
+01:04:30,690 --> 01:04:34,190
+تسعة ستة تسعة ستة تسعة ستة تسعة ستة تسعة ستة تسعة
+
+494
+01:04:34,190 --> 01:04:34,310
+ستة تسعة ستة تسعة ستة تسعة ستة تسعة ستة تسعة ستة
+
+495
+01:04:34,310 --> 01:04:35,350
+تسعة ستة تسعة ستة تسعة ستة تسعة ستة تسعة ستة تسعة
+
+496
+01:04:35,350 --> 01:04:40,960
+ستة تسعة ستة تسعة ستة تسعة ستعة تسعة سمعناته التاو
+
+497
+01:04:40,960 --> 01:04:48,780
+التاو
+
+498
+01:04:48,780 --> 01:04:55,200
+ايش الساعة صارت Q معروفة وB معروفة يعني حضروا مين
+
+499
+01:04:55,200 --> 01:04:57,500
+ستعرفي تلاتة في Q على B أكتر بتطلع
+
+500
+01:05:14,670 --> 01:05:20,970
+828.5800 PSI
+
+501
+01:05:20,970 --> 01:05:25,610
+طبعا ال
+
+502
+01:05:25,610 --> 01:05:30,550
+sigma X شو الساوية ال
+
+503
+01:05:30,550 --> 01:05:34,150
+Y شو الساوية صفر عند A
+
+504
+01:05:43,260 --> 01:05:47,480
+معنى التاو ماكسيمم ايش يساوي؟ تاو تاو ماكسيمم
+
+505
+01:05:47,480 --> 01:05:54,760
+التاو ماكسيمم هتكون
+
+506
+01:05:54,760 --> 01:06:03,960
+جزر التربيع لسيجما اكس تربيع على اربعة زائد تاو
+
+507
+01:06:03,960 --> 01:06:08,900
+تربيع هذه صفر معناته هذه هتكون الساويه تاو
+
+508
+01:06:12,510 --> 01:06:18,250
+tau maximum ستكون سواء تمانية اتنين تمانية point
+
+509
+01:06:18,250 --> 01:06:27,890
+خمسة تمانية يعني نقطة A نقطة B بي
+
+510
+01:06:27,890 --> 01:06:36,650
+جاية just below ال discontinuity يعني بي جاية just
+
+511
+01:06:36,650 --> 01:06:38,650
+below ال discontinuity يعني بي جاية just below ال
+
+512
+01:06:42,870 --> 01:06:49,330
+سبعة ال remaining area ال
+
+513
+01:06:49,330 --> 01:06:54,030
+remaining area هذه
+
+514
+01:06:54,030 --> 01:06:57,990
+ال remaining area هذه ال above هذه ال remaining
+
+515
+01:06:57,990 --> 01:07:09,390
+area مع ال view بتاعة هتكون اتنين point
+
+516
+01:07:09,390 --> 01:07:20,080
+تلاتة تلاتةفي point اتنين ستة في واحد point تلاتة
+
+517
+01:07:20,080 --> 01:07:27,640
+سبعة واحد point تلاتة سبعة أحس
+
+518
+01:07:27,640 --> 01:07:32,260
+بقولك يو point
+
+519
+01:07:32,260 --> 01:07:36,360
+تمانية اتنين تسعة تسعة تسعة point تمانية اتنين
+
+520
+01:07:36,360 --> 01:07:39,580
+تسعة
+
+521
+01:07:39,580 --> 01:07:41,380
+تسعة تسعة
+
+522
+01:07:43,600 --> 01:07:47,940
+معناته تاو هتكون
+
+523
+01:07:47,940 --> 01:08:00,940
+في Q على B سبعة
+
+524
+01:08:00,940 --> 01:08:03,880
+و بقية و خمس أسطاش و خمسة و تمانية سبعة و بقية و
+
+525
+01:08:03,880 --> 01:08:11,120
+خمس أسطاش point تمانية خمسية ال
+
+526
+01:08:11,120 --> 01:08:19,960
+sigma Xالـ Y عنده يلها قيمة صح؟ 1.24 من عوضها الـ
+
+527
+01:08:19,960 --> 01:08:32,760
+1.24 تعطيني إيش الـ Sigma X 545
+
+528
+01:08:32,760 --> 01:08:39,740
+.47
+
+529
+01:08:39,740 --> 01:08:45,720
+طيب ال tau max بنحسب هناخمسمية و سبعة و ربعين
+
+530
+01:08:45,720 --> 01:08:51,620
+تربيع على أربع زائد تاو تربيع تحت الجدر تاو max
+
+531
+01:08:51,620 --> 01:09:05,200
+سبعمية
+
+532
+01:09:05,200 --> 01:09:09,000
+سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية
+
+533
+01:09:09,000 --> 01:09:09,480
+سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية
+
+534
+01:09:09,480 --> 01:09:09,500
+سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية
+
+535
+01:09:09,500 --> 01:09:09,560
+سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية
+
+536
+01:09:09,560 --> 01:09:09,780
+سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية
+
+537
+01:09:09,780 --> 01:09:12,200
+سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية سبعمية
+
+538
+01:09:12,200 --> 01:09:19,060
+سبعمية سبعمية سبعميةالـ B هتكبر
+
+539
+01:09:19,060 --> 01:09:26,080
+الـ B هصير اتنين point تلاتة
+
+540
+01:09:26,080 --> 01:09:31,020
+تلاتة لكن نفس الـ Q هتكون اللي هي point تمانية
+
+541
+01:09:31,020 --> 01:09:37,900
+اتنين تسعة تسعة الصدن
+
+542
+01:09:37,900 --> 01:09:42,800
+ليه شيريستروس هينزل اضربه
+
+543
+01:09:42,800 --> 01:09:43,840
+جيب ال TAO
+
+544
+01:09:51,110 --> 01:10:02,190
+52.22 52.22 52
+
+545
+01:10:02,190 --> 01:10:07,970
+.22
+
+546
+01:10:07,970 --> 01:10:11,650
+و
+
+547
+01:10:11,650 --> 01:10:18,190
+ال sigma x هتكون نفسها خمسمية و لأ الموبايل
+
+548
+01:10:18,190 --> 01:10:24,030
+ماتغيرتشوخمسة واربعين point اربعة سبعة و ال tau
+
+549
+01:10:24,030 --> 01:10:29,990
+max احسبه من هذه المعادلة هذه تربيع على اربعة زاد
+
+550
+01:10:29,990 --> 01:10:47,710
+هذه تربيع تحت الجذر طيب
+
+551
+01:10:50,700 --> 01:11:00,900
+بالنسبة لل D ال Q تاعتها سفر خلاص خلاصنا ال Q سفر
+
+552
+01:11:00,900 --> 01:11:05,980
+وال B اتنين point تلاتة تلاتة معناته التاوه ايش
+
+553
+01:11:05,980 --> 01:11:13,980
+يكون ساوي؟ Zero ال Y بتكون اللي هي واحد و نص يعني
+
+554
+01:11:13,980 --> 01:11:18,700
+هعوض .. عشان احسب سيج ماكس بحسب Y واحد و نص اكم؟
+
+555
+01:11:25,780 --> 01:11:29,040
+تطلع ستمية تسعة و خمسين point خمسة و تمانية ستمية
+
+556
+01:11:29,040 --> 01:11:36,740
+تسعة و خمسين point خمسة و تمانية و
+
+557
+01:11:36,740 --> 01:11:42,300
+ال tau max هتكون هادي على اتنين تلت
+
+558
+01:11:42,300 --> 01:11:45,880
+مية تسعة و عشرين point اتنين و تسعين تلت مية تسعة
+
+559
+01:11:45,880 --> 01:11:50,100
+و عشرين point اتنين و تسعين و الأولى التالتة
+
+560
+01:12:15,640 --> 01:12:18,140
+متين و سبعة و سبعين؟
+
+561
+01:12:37,970 --> 01:12:46,450
+معناته لو بدي أخد بدي
+
+562
+01:12:46,450 --> 01:12:52,410
+أخد البني stress لحاله هيكون
+
+563
+01:12:52,410 --> 01:12:56,190
+عندي
+
+564
+01:12:56,190 --> 01:13:05,150
+عندي
+
+565
+01:13:05,150 --> 01:13:05,670
+hand compression
+
+566
+01:13:10,670 --> 01:13:17,450
+تحت tension هذا
+
+567
+01:13:17,450 --> 01:13:34,870
+sigma x التاو هيكون
+
+568
+01:13:34,870 --> 01:13:35,570
+maximum
+
+569
+01:13:44,070 --> 01:13:49,170
+هكون maximum هنا و بنزل ال non linear بعدين بنزل
+
+570
+01:13:49,170 --> 01:14:01,550
+فجأة زي هيك بعدين بكمل non linear هذا
+
+571
+01:14:01,550 --> 01:14:08,910
+ال tau maximum و عند كل واحدة إيها قيمتها عند ال
+
+572
+01:14:08,910 --> 01:14:10,730
+zero اللي هو ال tau
+
+573
+01:14:19,910 --> 01:14:27,950
+بعدين سبعمية و خمسة عشر point تمانية و خمسة بعدين
+
+574
+01:14:27,950 --> 01:14:33,510
+هان اتنين و خمسين point اتنين اتنين و هان اش zero
+
+575
+01:14:33,510 --> 01:14:35,490
+ال tau max
+
+576
+01:14:46,280 --> 01:14:49,940
+هيكون عندهين تمانمية و تمانية و عشرين maximum
+
+577
+01:14:49,940 --> 01:14:52,960
+بعدين
+
+578
+01:14:52,960 --> 01:14:59,640
+بنزل لسبعمية و ستة و ستين بعدين بنزل لامتين و سبعة
+
+579
+01:14:59,640 --> 01:15:10,900
+و سبعين يعني
+
+580
+01:15:10,900 --> 01:15:16,530
+عندهين تمانمية و تمانية و عشرينبونت خمس تمانية
+
+581
+01:15:16,530 --> 01:15:30,370
+سبعمية وستة وستين بونت زير واربع واندي
+
+582
+01:15:30,370 --> 01:15:37,210
+بعدين اتنين وسبعة وسبعين بونت سبعة
+
+583
+01:15:46,340 --> 01:15:53,400
+فيش غلطين؟ عندي
+
+584
+01:15:53,400 --> 01:16:00,100
+هاي تمانمية و خمسة خمسية هاي تمانمية و تمانية و
+
+585
+01:16:00,100 --> 01:16:02,100
+عشرين point خمسة تمانية
+
+586
+01:16:06,140 --> 01:16:11,540
+بعدين سبعمية و ستة و ستين point zero اربع بعدين
+
+587
+01:16:11,540 --> 01:16:19,780
+بنزل ل متين و سبعة و سبعين point سبعة بعدين بنزل
+
+588
+01:16:19,780 --> 01:16:23,260
+هنا ل
+
+589
+01:16:23,260 --> 01:16:31,580
+متين .. تلت مية او بزيد تلت
+
+590
+01:16:31,580 --> 01:16:35,920
+مية و تسعة و عشرين
+
+591
+01:16:39,880 --> 01:16:51,180
+.92 طبعا هو ash symmetric لأن
+
+592
+01:16:51,180 --> 01:16:55,240
+عند ال outer fiber بيكون ال status stress لو أخد
+
+593
+01:16:55,240 --> 01:17:05,180
+element هيكون عنده sigma Xهو sigma x ومافي شير
+
+594
+01:17:05,180 --> 01:17:12,340
+عندى مافي شير لأن ال tau maximum الو قيمة بيكون I
+
+595
+01:17:12,340 --> 01:17:15,260
+rotate this element some angle خمسة واربعين درجة
+
+596
+01:17:15,260 --> 01:17:23,060
+هتكون لو sigma x على اتنين حلو فاش زاوية خمسة
+
+597
+01:17:23,060 --> 01:17:32,920
+واربعين اه
+
+598
+01:17:35,540 --> 01:17:40,120
+عند نفس النقطة ايه الفرق بين التاو والتاو ماكس عند
+
+599
+01:17:40,120 --> 01:17:44,400
+نفس النقطة نفس النقطة نفس النقطة اه عند اي نقطة
+
+600
+01:17:44,400 --> 01:17:49,280
+لان انت احنا اللي جيبنا احنا جيبنا ال state of
+
+601
+01:17:49,280 --> 01:17:55,860
+stress في الحسابات بتاعتنا parallel لمحاول احتثيات
+
+602
+01:17:55,860 --> 01:18:05,790
+اللي احنا عاملينها يعني مثلا نقطة B نقطة Bهذا يعني
+
+603
+01:18:05,790 --> 01:18:16,430
+جيبنا stress element فيه sigma X وفي
+
+604
+01:18:16,430 --> 01:18:23,970
+عندي H تاو
+
+605
+01:18:23,970 --> 01:18:30,490
+هذا ال stress element اللي هو oriented موازي
+
+606
+01:18:30,490 --> 01:18:36,210
+المحاول احداثياتواضح لان انا لما اقرب و برسم more
+
+607
+01:18:36,210 --> 01:18:41,330
+circle هذا ما تصل ليش ال most critical critical او
+
+608
+01:18:41,330 --> 01:18:46,050
+most critical shear stress فانا ممكن من ال more
+
+609
+01:18:46,050 --> 01:18:54,070
+circle ارسم ايه ارسم احسب ال principal stresses و
+
+610
+01:18:54,070 --> 01:18:58,850
+ال maximum shear stress فال more circle هذا هتكون
+
+611
+01:18:58,850 --> 01:19:03,350
+عندى نقطة تانية عندى نقطة sigma Xو tau counter
+
+612
+01:19:03,350 --> 01:19:11,470
+clockwise هذه النقطة و zero و tau clockwise صح
+
+613
+01:19:11,470 --> 01:19:18,330
+يعني لما ارسل more circle عند
+
+614
+01:19:18,330 --> 01:19:23,110
+هاي sigma x هذه
+
+615
+01:19:23,110 --> 01:19:28,350
+sigma x وهذه
+
+616
+01:19:28,350 --> 01:19:28,650
+tau
+
+617
+01:19:31,790 --> 01:19:40,490
+النقطة التانية سفر سفر
+
+618
+01:19:40,490 --> 01:19:47,170
+و
+
+619
+01:19:47,170 --> 01:19:54,090
+Tao Clockwise Hi
+
+620
+01:19:54,090 --> 01:19:54,830
+Mars يا رجال
+
+621
+01:20:00,620 --> 01:20:06,520
+السينتر جاء عند سيجما X على اتنين سينتر اللي هو
+
+622
+01:20:06,520 --> 01:20:13,800
+هذا والراديوس
+
+623
+01:20:13,800 --> 01:20:20,320
+تعمار circle جزر التربيع لسيجما X على اتنين هو
+
+624
+01:20:20,320 --> 01:20:26,360
+سيجما X زي سيجما X وانا سيجما Y هذا سفر لكل تربيع
+
+625
+01:20:26,360 --> 01:20:27,360
+زي التاو
+
+626
+01:20:29,930 --> 01:20:35,450
+معناته سيجما واحد بساوي
+
+627
+01:20:35,450 --> 01:20:44,950
+C زائد ال radius هذا سيجما واحد صح؟ والسيجما اتنين
+
+628
+01:20:44,950 --> 01:20:56,450
+بساوي C minus R لاحظ ال radius هي طلع المعادلة
+
+629
+01:20:56,450 --> 01:20:57,670
+اكبر من ايه؟
+
+630
+01:21:00,450 --> 01:21:05,750
+أكبر من C هتطلع هذا بال negative بالحالة هذه هتطلع
+
+631
+01:21:05,750 --> 01:21:13,750
+بال negative تاو ماكس هتكون سيجما واحد minus سيجما
+
+632
+01:21:13,750 --> 01:21:20,110
+اتنين على اتنين اللي هي بالستويات ال R فهو عند نفس
+
+633
+01:21:20,110 --> 01:21:24,730
+النقطة انا جبت ال stress distribution بالاتجاهات
+
+634
+01:21:24,730 --> 01:21:32,490
+هيه بس هل ال fiber ال materialبالقول انتش متعرض لـ
+
+635
+01:21:32,490 --> 01:21:37,930
+maximum conditions لأ فانت عشان هيك بتعمل rotation
+
+636
+01:21:37,930 --> 01:21:45,330
+يعني لما تحسب سجما X هتروح تدور هاي .. هاد ياش هاد
+
+637
+01:21:45,330 --> 01:21:49,750
+اتنين في تعالى principal صح؟ هتدور counter
+
+638
+01:21:49,750 --> 01:21:57,610
+clockwise هاي ال X axis هتدور ياش؟ هتدور في بي هاي
+
+639
+01:21:57,610 --> 01:22:03,550
+ال element هاي سجما واحدهذه سيجما واحد وهذه سيجما
+
+640
+01:22:03,550 --> 01:22:10,330
+اتنين وهذه سيجما اتنين صح؟ عشان تجيب ال maximum
+
+641
+01:22:10,330 --> 01:22:18,150
+shear stress يعني هذه سيجما واحد يا بتروح من سيجما
+
+642
+01:22:18,150 --> 01:22:22,430
+واحد direction بتلف counter clockwise خمسة واربعين
+
+643
+01:22:22,430 --> 01:22:30,820
+درجة يعني هتلف كمان هذه خمسة واربعين درجةو هاي
+
+644
+01:22:30,820 --> 01:22:35,780
+طبعا عند ال max الشيء ال stress still في عنده
+
+645
+01:22:35,780 --> 01:22:38,980
+still
+
+646
+01:22:38,980 --> 01:22:43,920
+بيكون في عنده normal
+
+647
+01:22:43,920 --> 01:22:50,640
+stresses normal stresses فهيكون عنده في tau, tau
+
+648
+01:22:50,640 --> 01:22:59,340
+max, tau max, هذه ال tau maxبس في عندى stress
+
+649
+01:22:59,340 --> 01:23:03,560
+level كمان فيه .. فيه normal stress احنا ليش بنحسب
+
+650
+01:23:03,560 --> 01:23:06,320
+max و share stress لأنه .. يعني احنا بنجهز لشطر
+
+651
+01:23:06,320 --> 01:23:12,140
+خمسة و ستة لأنه اذا بدى استخدم ال maximum share
+
+652
+01:23:12,140 --> 01:23:15,580
+stress theory لما نيجي لاحقا حازان يحسب tau max
+
+653
+01:23:15,580 --> 01:23:19,160
+اذا بالزمن استخدم ال .. ال maximum distortion
+
+654
+01:23:19,160 --> 01:23:21,280
+energy theory بالزمن استخدم ال sigma واحد و sigma
+
+655
+01:23:21,280 --> 01:23:24,140
+اتنين و sigma اتنين حسب ال design theory حسب ال
+
+656
+01:23:24,140 --> 01:23:31,020
+design theoryفبالزمن أحسب ال maximum shear stress،
+
+657
+01:23:31,020 --> 01:23:36,620
+condition ايش؟ يعني مثلا انت ما جيبت هنا ال shear
+
+658
+01:23:36,620 --> 01:23:39,700
+zero و بعدين shear maximum لنفس ال .. لأ ما هو
+
+659
+01:23:39,700 --> 01:23:43,500
+هادي هادي بتجيب ال maximum عند location معين يعني
+
+660
+01:23:43,500 --> 01:23:47,940
+هادي بتختلف عن هادي، ايش ال most critical فيهم في
+
+661
+01:23:47,940 --> 01:23:49,340
+الحالة هادي؟ هي هذه النقطة
+
+662
+01:23:54,050 --> 01:23:57,250
+الـ orientation يعني احنا في الأول احنا جيبنا ال
+
+663
+01:23:57,250 --> 01:24:01,570
+.. ال critical conditions X يعني مظبوط بعدين فحصنا
+
+664
+01:24:01,570 --> 01:24:04,730
+عند section Y عند ال section هذا فحصنا شوفنا وين
+
+665
+01:24:04,730 --> 01:24:08,950
+بيكون الشير ال .. ال .. ال tau maximum و وين بيكون
+
+666
+01:24:08,950 --> 01:24:12,070
+maximum لما كلهم هدول tau maximum but at different
+
+667
+01:24:12,070 --> 01:24:16,690
+points صح؟ أكبر واحدة فيهم هذه إذا بدنا نستخدم ال
+
+668
+01:24:16,690 --> 01:24:18,990
+maximum الشير الشريف تشير معناته هذه هي ال
+
+669
+01:24:18,990 --> 01:24:19,250
+critical
+
+670
+01:24:25,770 --> 01:24:29,210
+دكتور، التصميم اللي بتبقى هى انه فيه اكتر من طريقة
+
+671
+01:24:29,210 --> 01:24:32,450
+عشان نجيب يعنى الحل أو نحدد يعنى ال dimension بتاع
+
+672
+01:24:32,450 --> 01:24:35,270
+ال shaft او شي زي هيك؟ او هى اي طريقة واحدة مش
+
+673
+01:24:35,270 --> 01:24:39,630
+عارفة؟ هنجيلها، انا .. ليش انا مش .. مش سريع،
+
+674
+01:24:39,630 --> 01:24:45,790
+بتصير عندكوا إحساس بالهدى، بال stresses لإنه
+
+675
+01:24:45,790 --> 01:24:49,130
+واضح ليش .. لسه مفيش عندكوا إحساس مش موجود وليش ..
+
+676
+01:24:49,130 --> 01:24:52,290
+ليش .. ليش بحسبتها و maximum وليش بحسبتها وإيش ال
+
+677
+01:24:52,290 --> 01:24:56,770
+.. ال critical element كيف بنحصل؟هذا بده ممارسة،
+
+678
+01:24:56,770 --> 01:24:59,610
+مع الممارسة بيصير عندكوا إحساس كيف ال stresses
+
+679
+01:24:59,610 --> 01:25:04,210
+بتتغير جوه ال material طب يعني مش ممكن يا دكتور مش
+
+680
+01:25:04,210 --> 01:25:07,390
+بنعتمد على اللي هو ال critical shear stress،
+
+681
+01:25:07,390 --> 01:25:10,290
+maximum shear stress، اللي أنا عندي مثلا من ال 277
+
+682
+01:25:10,290 --> 01:25:15,310
+هو already صار فيه failure في المادة ال
+
+683
+01:25:15,310 --> 01:25:18,290
+maximum shear stress يعني عشانكم مستعجلين، maximum
+
+684
+01:25:18,290 --> 01:25:21,250
+shear stress اللي بتحكي بيصير failure .. failure
+
+685
+01:25:21,250 --> 01:25:26,740
+في ال materialلما ال maximum shear stress في ال
+
+686
+01:25:26,740 --> 01:25:32,960
+material عند نقطة معينة بيصير يساو أو يتخطى ال
+
+687
+01:25:32,960 --> 01:25:38,080
+shear .. ال strength in shear .. ال strength in
+
+688
+01:25:38,080 --> 01:25:43,470
+shear، في فرق من ال strength؟و ال stress ال
+
+689
+01:25:43,470 --> 01:25:47,570
+strength ايه عشان خاصية ال material ال stress هي
+
+690
+01:25:47,570 --> 01:25:51,750
+actual state موجودة في ال material بغض نظر عن ال
+
+691
+01:25:51,750 --> 01:25:57,950
+material و بغض نظر عن ال .. يعني .. يعني ال stress
+
+692
+01:25:57,950 --> 01:26:03,130
+بيتمد على ال loading نوعية ال loading مظبوط و على
+
+693
+01:26:03,130 --> 01:26:07,560
+ال dimensions ال cross sectionباعتمد على الـ
+
+694
+01:26:07,560 --> 01:26:11,040
+Geometry و باعتمد على ال loading هذه ال stresses
+
+695
+01:26:11,040 --> 01:26:17,320
+لكن ال strength مايلها خص لا بال loading ولا ..
+
+696
+01:26:17,320 --> 01:26:20,000
+ولا بالشي اسمه ولا بال dimensions بتاعة ال part
+
+697
+01:26:20,000 --> 01:26:23,660
+ولا شكل ال part وبالتالي ال maximum shear stress
+
+698
+01:26:23,660 --> 01:26:28,140
+.. shear stress تيوري بتحكي انه بيصير failure لما
+
+699
+01:26:28,140 --> 01:26:31,820
+ال maximum shear stress at the critical location
+
+700
+01:26:31,820 --> 01:26:36,630
+اللي انت هتختاره كمصمم بيساوي او بتخطىالـ yield
+
+701
+01:26:36,630 --> 01:26:41,410
+strength in shear عشان نكون نحسب المجزم shear ال
+
+702
+01:26:41,410 --> 01:26:44,690
+stress في رسمة ال moment يا دكتور .. نعم .. في
+
+703
+01:26:44,690 --> 01:26:47,350
+رسمة ال moment .. اه .. ليش هدفرنا الجزء الفجي ان
+
+704
+01:26:47,350 --> 01:26:49,850
+هو ال tension في الرسمة .. نعم .. في رسمة ال
+
+705
+01:26:49,850 --> 01:26:53,750
+moment .. ال moment دا يا جرام .. فعلا اللي بلدك
+
+706
+01:26:53,750 --> 01:26:56,210
+.. هذا اه .. ليش هدفرنا ال tension هو الجزء الفجي
+
+707
+01:26:56,210 --> 01:26:59,710
+يعني .. انا ماعتبرهش الجزء الفجي يعني .. الجزء
+
+708
+01:26:59,710 --> 01:27:03,510
+التحتاني .. tensionهاي ال compression هاي بال
+
+709
+01:27:03,510 --> 01:27:13,210
+negative X وهي ال tension بال positive X طيب
+
+710
+01:27:13,210 --> 01:27:13,650
+كل عافية
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/icLNiNsLHbs_raw.json b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/icLNiNsLHbs_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..9479e14c0d8b3c5806a2225b50bea9eb114ba731
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/icLNiNsLHbs_raw.json
@@ -0,0 +1 @@
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المعادلة اللي هادر هي اربعة اربعة L على H لكل تربية", "tokens": [2407, 3615, 1863, 16254, 12602, 3555, 3615, 8717, 9566, 1211, 3615, 1975, 2655, 1863, 9957, 4724, 23557, 4032, 3615, 1863, 16254, 6055, 3794, 27884, 8717, 9566, 1211, 3615, 16712, 1211, 9307, 3660, 4724, 23557, 8978, 25724, 11622, 2288, 16712, 25513, 10632, 11331, 9381, 5172, 8978, 9673, 3615, 18513, 37977, 13672, 1829, 8032, 18513, 2288, 39896, 1975, 25513, 27884, 1975, 25513, 27884, 441, 15844, 389, 5296, 28820, 6055, 25513, 10632], "avg_logprob": -0.238169641154153, "compression_ratio": 1.748091603053435, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 2238.4700000000003, "end": 2239.65, "word": "وعندي", "probability": 0.767578125}, {"start": 2239.65, "end": 2240.03, "word": " ربع", "probability": 0.9513346354166666}, {"start": 2240.03, "end": 2240.71, "word": " نطلع", "probability": 0.75628662109375}, {"start": 2240.71, "end": 2241.49, "word": " اتنين", "probability": 0.9005126953125}, {"start": 2241.49, 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"text": "بعتمدش على ال على H هذا الشيء مابعتمد على ال على H فكل ما ال ال على H بتقل ال effect على ال bending معله بقل او كل ما ال ال على H بتزيد ال effect على ال bending moment بزيد معناته اذا كان عند بيم طويل كتير ببدأ قيمة", "tokens": [3555, 34268, 2304, 3215, 8592, 15844, 2423, 15844, 389, 23758, 25124, 1829, 38207, 19446, 3555, 34268, 2304, 3215, 15844, 2423, 15844, 389, 6156, 28820, 19446, 2423, 2423, 15844, 389, 39894, 4587, 1211, 2423, 1802, 15844, 2423, 22487, 20449, 43761, 4724, 4587, 1211, 1975, 2407, 28242, 19446, 2423, 2423, 15844, 389, 39894, 11622, 25708, 2423, 1802, 15844, 2423, 22487, 1623, 4724, 11622, 25708, 20449, 8315, 47395, 1975, 15730, 25961, 43242, 4724, 32640, 23032, 2407, 26895, 9122, 2655, 13546, 4724, 44510, 10721, 12174, 32640, 3660], "avg_logprob": -0.23995535625588327, "compression_ratio": 2.0294117647058822, "no_speech_prob": 1.2516975402832031e-06, "words": [{"start": 2602.9, "end": 2603.48, "word": "بعتمدش", "probability": 0.68212890625}, {"start": 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"temperature": 1.0}, {"id": 91, "seek": 265423, "start": 2628.79, "end": 2654.23, "text": "أو تأثير ال direct shear على maximum shear stress بيبدأ يقل كتير كل ما ازود ال L على H المعنى ان كل ما كان ال beam طويل ممكن يكون ال shear stress is not significant اهمله فإذا كان ال beam طويل هذا هيكبر كتير هذا ثابت", "tokens": [10721, 2407, 6055, 10721, 12984, 13546, 2423, 2047, 24082, 15844, 11469, 332, 449, 24082, 4244, 4724, 1829, 44510, 10721, 7251, 4587, 1211, 9122, 2655, 13546, 28242, 19446, 1975, 11622, 23328, 2423, 441, 15844, 389, 9673, 3615, 1863, 7578, 16472, 28242, 19446, 25961, 2423, 14269, 23032, 2407, 26895, 3714, 43020, 7251, 30544, 2423, 24082, 4244, 307, 406, 4776, 1975, 16095, 43761, 6156, 28814, 15730, 25961, 2423, 14269, 23032, 2407, 26895, 23758, 39896, 4117, 26890, 9122, 2655, 13546, 23758, 38637, 16758, 2655], "avg_logprob": -0.1858603365627336, "compression_ratio": 1.671875, "no_speech_prob": 2.205371856689453e-06, "words": [{"start": 2628.79, "end": 2629.09, "word": 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فإذا", "probability": 0.88916015625}, {"start": 2648.01, "end": 2648.31, "word": " كان", "probability": 0.99658203125}, {"start": 2648.31, "end": 2648.47, "word": " ال", "probability": 0.96630859375}, {"start": 2648.47, "end": 2648.67, "word": " beam", "probability": 0.96484375}, {"start": 2648.67, "end": 2649.93, "word": " طويل", "probability": 0.9580078125}, {"start": 2649.93, "end": 2652.51, "word": " هذا", "probability": 0.46630859375}, {"start": 2652.51, "end": 2653.01, "word": " هيكبر", "probability": 0.95263671875}, {"start": 2653.01, "end": 2653.49, "word": " كتير", "probability": 0.9637044270833334}, {"start": 2653.49, "end": 2653.73, "word": " هذا", "probability": 0.7568359375}, {"start": 2653.73, "end": 2654.23, "word": " ثابت", "probability": 0.99462890625}], "temperature": 1.0}, {"id": 92, "seek": 268243, "start": 2656.21, "end": 2682.43, "text": "وبالتالي بالمحصلة بال total اذا هذا ثابت وهذا بيكبر مانعته هذا قيمة هذا بالنسبة لكل اشهر مالها بتقل نسبيا لكن قيمته مطلقاش ثابتة فمانعته كل ما صار ال beam أقصر يعني بدل خمس متر صارت طوله عشرة صنطة حسيت تقرير almost مش فيه bending", "tokens": [37746, 6027, 2655, 6027, 1829, 20666, 2304, 5016, 9381, 37977, 20666, 3217, 1975, 15730, 23758, 38637, 16758, 2655, 37037, 15730, 4724, 1829, 4117, 3555, 2288, 3714, 7649, 34268, 3224, 23758, 12174, 32640, 3660, 23758, 20666, 1863, 35457, 3660, 5296, 28820, 1975, 8592, 3224, 2288, 3714, 6027, 11296, 39894, 4587, 1211, 8717, 35457, 25528, 44381, 12174, 32640, 47395, 3714, 9566, 1211, 4587, 33599, 38637, 16758, 2655, 3660, 6156, 2304, 7649, 34268, 3224, 28242, 19446, 20328, 9640, 2423, 14269, 5551, 4587, 9381, 2288, 37495, 22653, 47525, 1211, 16490, 2304, 3794, 44650, 2288, 20328, 9640, 2655, 23032, 12610, 3224, 6225, 8592, 25720, 20328, 1863, 9566, 3660, 11331, 3794, 36081, 6055, 4587, 16572, 2288, 1920, 37893, 8978, 3224, 22487], "avg_logprob": -0.3081896644214104, "compression_ratio": 1.7623318385650224, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 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"probability": 0.9462890625}, {"start": 2671.87, "end": 2672.09, "word": " كل", "probability": 0.97119140625}, {"start": 2672.09, "end": 2672.29, "word": " ما", "probability": 0.74853515625}, {"start": 2672.29, "end": 2672.51, "word": " صار", "probability": 0.90966796875}, {"start": 2672.51, "end": 2672.65, "word": " ال", "probability": 0.96044921875}, {"start": 2672.65, "end": 2672.95, "word": " beam", "probability": 0.73828125}, {"start": 2672.95, "end": 2674.25, "word": " أقصر", "probability": 0.769287109375}, {"start": 2674.25, "end": 2675.67, "word": " يعني", "probability": 0.918701171875}, {"start": 2675.67, "end": 2676.69, "word": " بدل", "probability": 0.5657958984375}, {"start": 2676.69, "end": 2677.13, "word": " خمس", "probability": 0.8761393229166666}, {"start": 2677.13, "end": 2677.47, "word": " متر", "probability": 0.872802734375}, {"start": 2677.47, "end": 2677.81, "word": " صارت", "probability": 0.7884928385416666}, {"start": 2677.81, "end": 2678.23, "word": " طوله", 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انش بيأثر على جودة الانش من طرف الشمال قوة قيمتها اربعمائة و تمانية باون فورس this supported ادنى يعني اندي support هنا و support هنا المقطع تار على شكل I beam", "tokens": [45340, 12984, 6027, 43242, 7578, 14269, 23032, 12610, 3224, 1975, 2655, 2304, 33599, 2288, 16472, 8592, 4724, 1829, 10721, 49115, 15844, 10874, 23328, 3660, 2423, 7649, 8592, 9154, 23032, 28480, 25124, 2304, 6027, 12174, 2407, 3660, 12174, 32640, 2655, 11296, 1975, 25513, 25957, 16373, 3660, 4032, 46811, 7649, 10632, 4724, 995, 11536, 6156, 13063, 3794, 341, 8104, 1975, 3215, 1863, 7578, 37495, 22653, 16472, 16254, 1406, 34105, 4032, 1406, 34105, 9673, 47432, 3615, 6055, 9640, 15844, 13412, 28820, 286, 14269], "avg_logprob": -0.36439042032500846, "compression_ratio": 1.5721649484536082, "no_speech_prob": 0.0, "words": [{"start": 2740.95, "end": 2741.59, "word": "المثال", "probability": 0.9256184895833334}, {"start": 2741.59, "end": 2741.99, "word": " عندى", "probability": 0.587158203125}, {"start": 2741.99, "end": 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عشان تسهل الحسابات الموجودة في البنية الشاشة points of interest are labeled a,b,c and d في نقاط بتهمنا اللي هي نقطة", "tokens": [2407, 46811, 6055, 4587, 16572, 3555, 3224, 4724, 8592, 28820, 23758, 2423, 23487, 5296, 2655, 3794, 1829, 1829, 21542, 3794, 16758, 9307, 37495, 22653, 2423, 2836, 1385, 1975, 8592, 2304, 6027, 11296, 16472, 8592, 6027, 2655, 6225, 8592, 7649, 6055, 3794, 3224, 1211, 21542, 3794, 16758, 9307, 9673, 29245, 23328, 3660, 8978, 29739, 1863, 10632, 2423, 8592, 33599, 3660, 2793, 295, 1179, 366, 21335, 257, 11, 65, 11, 66, 293, 274, 8978, 8717, 4587, 41193, 39894, 16095, 8315, 13672, 1829, 39896, 8717, 47432, 3660], "avg_logprob": -0.3152573431239409, "compression_ratio": 1.5101010101010102, "no_speech_prob": 0.0, "words": [{"start": 2765.46, "end": 2765.74, "word": "و", "probability": 0.650390625}, {"start": 2765.74, "end": 2765.98, "word": " تم", "probability": 0.88134765625}, {"start": 2765.98, "end": 2766.54, "word": " تقريبه", "probability": 0.953515625}, 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new file mode 100644
index 0000000000000000000000000000000000000000..2d487bcc5c41556515759753c42808a9cdbffca8
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"probability": 0.72216796875}, {"start": 320.7, "end": 321.2, "word": " ال", "probability": 0.904296875}, {"start": 321.2, "end": 321.44, "word": " z", "probability": 0.884765625}, {"start": 321.44, "end": 321.78, "word": " تاو", "probability": 0.7980143229166666}, {"start": 321.78, "end": 322.52, "word": " زد", "probability": 0.968505859375}, {"start": 322.52, "end": 323.06, "word": " موازي", "probability": 0.9625244140625}, {"start": 323.06, "end": 323.18, "word": " ال", "probability": 0.8046875}, {"start": 323.18, "end": 323.44, "word": " x", "probability": 0.884765625}, {"start": 323.44, "end": 323.82, "word": " axis", "probability": 0.91015625}], "temperature": 1.0}, {"id": 13, "seek": 35275, "start": 325.89, "end": 352.75, "text": "بالاضافة للمورمو ال stress components اللي هو sigma x و sigma y و sigma z هدرس الحالة اللي هي تمثل ل plane stress case", "tokens": [3555, 6027, 46958, 31845, 3660, 5296, 19528, 13063, 2304, 2407, 2423, 4244, 6677, 13672, 1829, 31439, 12771, 2031, 4032, 12771, 288, 4032, 12771, 710, 8032, 3215, 2288, 3794, 21542, 6027, 3660, 13672, 1829, 39896, 46811, 12984, 1211, 5296, 5720, 4244, 1389], "avg_logprob": -0.28776042589119505, "compression_ratio": 1.3898305084745763, "no_speech_prob": 0.0, "words": [{"start": 325.89, "end": 326.43, "word": "بالاضافة", "probability": 0.9005859375}, {"start": 326.43, "end": 326.91, "word": " للمورمو", "probability": 0.58642578125}, {"start": 326.91, "end": 326.99, "word": " ال", "probability": 0.41748046875}, {"start": 326.99, "end": 327.23, "word": " stress", "probability": 0.93701171875}, {"start": 327.23, "end": 327.89, "word": " components", "probability": 0.69091796875}, {"start": 327.89, "end": 328.29, "word": " اللي", "probability": 0.740966796875}, {"start": 328.29, "end": 328.55, "word": " هو", "probability": 0.96337890625}, {"start": 328.55, "end": 328.99, "word": " sigma", "probability": 0.5673828125}, {"start": 328.99, "end": 329.59, "word": " x", "probability": 0.51318359375}, {"start": 329.59, "end": 331.39, "word": " و", "probability": 0.8359375}, {"start": 331.39, "end": 331.83, "word": " sigma", "probability": 0.92529296875}, {"start": 331.83, "end": 332.89, "word": " y", "probability": 0.97021484375}, {"start": 332.89, "end": 334.31, "word": " و", "probability": 0.986328125}, {"start": 334.31, "end": 334.67, "word": " sigma", "probability": 0.95947265625}, {"start": 334.67, "end": 337.27, "word": " z", "probability": 0.98193359375}, {"start": 337.27, "end": 349.57, "word": " هدرس", "probability": 0.7757568359375}, {"start": 349.57, "end": 349.95, "word": " الحالة", "probability": 0.9749348958333334}, {"start": 349.95, "end": 350.05, "word": " اللي", "probability": 0.907470703125}, {"start": 350.05, "end": 350.33, "word": " هي", "probability": 0.72216796875}, {"start": 350.33, "end": 351.05, "word": " تمثل", "probability": 0.8048502604166666}, {"start": 351.05, "end": 351.23, "word": " ل", "probability": 0.400146484375}, {"start": 351.23, "end": 351.55, "word": " plane", "probability": 0.41796875}, {"start": 351.55, "end": 352.11, "word": " stress", "probability": 0.9765625}, {"start": 352.11, "end": 352.75, "word": " case", "probability": 0.95703125}], "temperature": 1.0}, {"id": 14, "seek": 38124, "start": 355.96, "end": 381.24, "text": "بكون عندى plan stress يعني stress فى بوادين او فى مستوى اذا كانت ال stresses on one surface are zero يعني هى ال X Y Z لو كانت ال stresses على المستوى هذا المتعود على Z axis ال sigma Z والتوزيد X والتوزيد Y بتستوى Zero بعتبرها", "tokens": [3555, 30544, 43242, 7578, 1393, 4244, 37495, 22653, 4244, 6156, 7578, 4724, 14407, 3215, 9957, 1975, 2407, 6156, 7578, 3714, 14851, 2407, 7578, 1975, 15730, 25961, 2655, 2423, 27732, 322, 472, 3753, 366, 4018, 37495, 22653, 8032, 7578, 2423, 1783, 398, 1176, 45164, 25961, 2655, 2423, 27732, 15844, 9673, 14851, 2407, 7578, 23758, 9673, 2655, 3615, 23328, 15844, 1176, 10298, 2423, 12771, 1176, 16070, 2655, 2407, 11622, 25708, 1783, 16070, 2655, 2407, 11622, 25708, 398, 39894, 14851, 2407, 7578, 17182, 4724, 34268, 26890, 11296], "avg_logprob": -0.2556985406314625, "compression_ratio": 1.743455497382199, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 355.96, "end": 356.48, "word": "بكون", "probability": 0.742919921875}, {"start": 356.48, "end": 356.8, "word": " عندى", "probability": 0.84375}, {"start": 356.8, "end": 357.06, "word": " plan", "probability": 0.5732421875}, {"start": 357.06, "end": 357.56, "word": " stress", "probability": 0.9638671875}, {"start": 357.56, "end": 357.84, "word": " يعني", "probability": 0.747314453125}, {"start": 357.84, "end": 358.78, "word": " stress", "probability": 0.95654296875}, {"start": 358.78, "end": 360.24, "word": " فى", "probability": 0.6875}, {"start": 360.24, "end": 360.8, "word": " بوادين", "probability": 0.676177978515625}, {"start": 360.8, "end": 361.5, "word": " او", "probability": 0.869384765625}, {"start": 361.5, "end": 361.66, "word": " فى", "probability": 0.947021484375}, {"start": 361.66, "end": 362.24, "word": " مستوى", "probability": 0.98681640625}, {"start": 362.24, "end": 363.82, "word": " اذا", "probability": 0.868408203125}, {"start": 363.82, "end": 364.18, "word": " كانت", "probability": 0.986083984375}, {"start": 364.18, "end": 364.28, "word": " ال", "probability": 0.95458984375}, {"start": 364.28, "end": 364.54, "word": " stresses", "probability": 0.5244140625}, {"start": 364.54, "end": 364.84, "word": " on", "probability": 0.8720703125}, {"start": 364.84, "end": 365.16, "word": " one", "probability": 0.93994140625}, {"start": 365.16, "end": 365.62, "word": " surface", "probability": 0.8935546875}, {"start": 365.62, "end": 365.88, "word": " are", "probability": 0.52490234375}, {"start": 365.88, "end": 366.22, "word": " zero", "probability": 0.56982421875}, {"start": 366.22, "end": 367.28, "word": " يعني", "probability": 0.76513671875}, {"start": 367.28, "end": 368.7, "word": " هى", "probability": 0.62060546875}, {"start": 368.7, "end": 368.84, "word": " ال", "probability": 0.8701171875}, {"start": 368.84, "end": 369.12, "word": " X", "probability": 0.63525390625}, {"start": 369.12, "end": 369.54, "word": " Y", "probability": 0.439453125}, {"start": 369.54, "end": 369.94, "word": " Z", "probability": 0.7861328125}, {"start": 369.94, "end": 370.82, "word": " لو", "probability": 0.939453125}, {"start": 370.82, "end": 371.16, "word": " كانت", "probability": 0.98388671875}, {"start": 371.16, "end": 371.22, "word": " ال", "probability": 0.982421875}, {"start": 371.22, "end": 371.56, "word": " stresses", "probability": 0.87890625}, {"start": 371.56, "end": 371.84, "word": " على", "probability": 0.86279296875}, {"start": 371.84, "end": 372.4, "word": " المستوى", "probability": 0.971923828125}, {"start": 372.4, "end": 373.6, "word": " هذا", "probability": 0.52490234375}, {"start": 373.6, "end": 374.1, "word": " المتعود", "probability": 0.918212890625}, {"start": 374.1, "end": 374.28, "word": " على", "probability": 0.5927734375}, {"start": 374.28, "end": 374.46, "word": " Z", "probability": 0.6591796875}, {"start": 374.46, "end": 374.94, "word": " axis", "probability": 0.59130859375}, {"start": 374.94, "end": 376.04, "word": " ال", "probability": 0.335693359375}, {"start": 376.04, "end": 376.26, "word": " sigma", "probability": 0.6728515625}, {"start": 376.26, "end": 376.62, "word": " Z", "probability": 0.77978515625}, {"start": 376.62, "end": 378.08, "word": " والتوزيد", "probability": 0.60947265625}, {"start": 378.08, "end": 378.38, "word": " X", "probability": 0.978515625}, {"start": 378.38, "end": 378.92, "word": " والتوزيد", "probability": 0.9326171875}, {"start": 378.92, "end": 379.1, "word": " Y", "probability": 0.990234375}, {"start": 379.1, "end": 379.56, "word": " بتستوى", "probability": 0.81982421875}, {"start": 379.56, "end": 379.9, "word": " Zero", "probability": 0.56494140625}, {"start": 379.9, "end": 381.24, "word": " بعتبرها", "probability": 0.881591796875}], "temperature": 1.0}, {"id": 15, "seek": 39915, "start": 382.17, "end": 399.15, "text": "a case of plan stress ال case of plan stress عندى هاي ال x axis هاي ال y axis عندى sigma x sigma y tau xy tau xy tau xy tau xy", "tokens": [64, 1389, 295, 1393, 4244, 2423, 1389, 295, 1393, 4244, 43242, 7578, 8032, 47302, 2423, 2031, 10298, 8032, 47302, 2423, 288, 10298, 43242, 7578, 12771, 2031, 12771, 288, 17842, 2031, 88, 17842, 2031, 88, 17842, 2031, 88, 17842, 2031, 88], "avg_logprob": -0.26238566491662, "compression_ratio": 1.7804878048780488, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 382.17, "end": 382.39, "word": "a", "probability": 0.1573486328125}, {"start": 382.39, "end": 382.83, "word": " case", "probability": 0.93359375}, {"start": 382.83, "end": 383.23, "word": " of", "probability": 0.98291015625}, {"start": 383.23, "end": 383.63, "word": " plan", "probability": 0.4921875}, {"start": 383.63, "end": 384.07, "word": " stress", "probability": 0.80078125}, {"start": 384.07, "end": 384.77, "word": " ال", "probability": 0.3203125}, {"start": 384.77, "end": 384.99, "word": " case", "probability": 0.79931640625}, {"start": 384.99, "end": 385.09, "word": " of", "probability": 0.955078125}, {"start": 385.09, "end": 385.29, "word": " plan", "probability": 0.96484375}, {"start": 385.29, "end": 385.71, "word": " stress", "probability": 0.9697265625}, {"start": 385.71, "end": 386.25, "word": " عندى", "probability": 0.571533203125}, {"start": 386.25, "end": 386.87, "word": " هاي", "probability": 0.722412109375}, {"start": 386.87, "end": 387.01, "word": " ال", "probability": 0.95556640625}, {"start": 387.01, "end": 387.21, "word": " x", "probability": 0.673828125}, {"start": 387.21, "end": 387.71, "word": " axis", "probability": 0.86328125}, {"start": 387.71, "end": 388.57, "word": " هاي", "probability": 0.6622314453125}, {"start": 388.57, "end": 388.67, "word": " ال", "probability": 0.990234375}, {"start": 388.67, "end": 388.83, "word": " y", "probability": 0.94091796875}, {"start": 388.83, "end": 389.37, "word": " axis", "probability": 0.93603515625}, {"start": 389.37, "end": 390.61, "word": " عندى", "probability": 0.82080078125}, {"start": 390.61, "end": 390.95, "word": " sigma", "probability": 0.61328125}, {"start": 390.95, "end": 391.47, "word": " x", "probability": 0.93994140625}, {"start": 391.47, "end": 392.61, "word": " sigma", "probability": 0.71240234375}, {"start": 392.61, "end": 393.09, "word": " y", "probability": 0.98974609375}, {"start": 393.09, "end": 394.21, "word": " tau", "probability": 0.49072265625}, {"start": 394.21, "end": 394.83, "word": " xy", "probability": 0.914794921875}, {"start": 394.83, "end": 395.51, "word": " tau", "probability": 0.8759765625}, {"start": 395.51, "end": 396.21, "word": " xy", "probability": 0.9912109375}, {"start": 396.21, "end": 397.09, "word": " tau", "probability": 0.919921875}, {"start": 397.09, "end": 398.03, "word": " xy", "probability": 0.99365234375}, {"start": 398.03, "end": 398.65, "word": " tau", "probability": 0.91455078125}, {"start": 398.65, "end": 399.15, "word": " xy", "probability": 0.994384765625}], "temperature": 1.0}, {"id": 16, "seek": 42992, "start": 400.56, "end": 429.92, "text": "هذا case هو plan stress اللي هو z أكس عمودي على الصفحة sigma z بالساوية zero و sigma zx بالساوية zero أو tau zx و tau zy بالساوية zero هناخد الحالة ل plan stress case بدي أشوف", "tokens": [3224, 15730, 1389, 31439, 1393, 4244, 13672, 1829, 31439, 710, 5551, 4117, 3794, 6225, 2304, 2407, 16254, 15844, 31767, 5172, 5016, 3660, 12771, 710, 20666, 3794, 995, 2407, 10632, 4018, 4032, 12771, 710, 87, 20666, 3794, 995, 2407, 10632, 4018, 34051, 17842, 710, 87, 4032, 17842, 710, 88, 20666, 3794, 995, 2407, 10632, 4018, 8032, 1863, 47283, 3215, 21542, 6027, 3660, 5296, 1393, 4244, 1389, 4724, 16254, 5551, 8592, 38688], "avg_logprob": -0.3232834456672131, "compression_ratio": 1.6233766233766234, "no_speech_prob": 0.0, "words": [{"start": 400.56, "end": 400.92, "word": "هذا", "probability": 0.4971923828125}, {"start": 400.92, "end": 401.18, "word": " case", "probability": 0.1456298828125}, {"start": 401.18, "end": 401.32, "word": " هو", "probability": 0.2060546875}, {"start": 401.32, "end": 401.52, "word": " plan", "probability": 0.71435546875}, {"start": 401.52, "end": 401.94, "word": " stress", "probability": 0.8984375}, {"start": 401.94, "end": 402.64, "word": " اللي", "probability": 0.5164794921875}, {"start": 402.64, "end": 402.94, "word": " هو", "probability": 0.94677734375}, {"start": 402.94, "end": 403.2, "word": " z", "probability": 0.443603515625}, {"start": 403.2, "end": 403.48, "word": " أكس", "probability": 0.7508951822916666}, {"start": 403.48, "end": 403.88, "word": " عمودي", "probability": 0.784912109375}, {"start": 403.88, "end": 404.0, "word": " على", "probability": 0.7431640625}, {"start": 404.0, "end": 404.42, "word": " الصفحة", "probability": 0.8587646484375}, {"start": 404.42, "end": 404.9, "word": " sigma", "probability": 0.388671875}, {"start": 404.9, "end": 405.16, "word": " z", "probability": 0.91162109375}, {"start": 405.16, "end": 405.58, "word": " بالساوية", "probability": 0.590234375}, {"start": 405.58, "end": 405.9, "word": " zero", "probability": 0.56884765625}, {"start": 405.9, "end": 406.52, "word": " و", "probability": 0.7353515625}, {"start": 406.52, "end": 406.78, "word": " sigma", "probability": 0.75439453125}, {"start": 406.78, "end": 407.58, "word": " zx", "probability": 0.75439453125}, {"start": 407.58, "end": 408.28, "word": " بالساوية", "probability": 0.95966796875}, {"start": 408.28, "end": 408.56, "word": " zero", "probability": 0.80712890625}, {"start": 408.56, "end": 408.82, "word": " أو", "probability": 0.6201171875}, {"start": 408.82, "end": 409.1, "word": " tau", "probability": 0.31103515625}, {"start": 409.1, "end": 409.86, "word": " zx", "probability": 0.94091796875}, {"start": 409.86, "end": 410.42, "word": " و", "probability": 0.89306640625}, {"start": 410.42, "end": 410.66, "word": " tau", "probability": 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stresses at any other plane مش موازي لل X-axis يعني مش موازي أو متعب لل X-axis يعني انا ماخد الحلقة هاي مستوى عمود على ال X-axis وهي مستوى عمود على ال Y-axis what if اذا كان عندي مستوى ميل فانا هنا اندي ان هاي ال X-axis ماخد مستوى ميل بزاوية Phi مع ال Y-axis", "tokens": [6027, 39184, 27732, 412, 604, 661, 5720, 37893, 3714, 2407, 31377, 1829, 24976, 1783, 12, 24633, 37495, 22653, 37893, 3714, 2407, 31377, 1829, 34051, 44650, 3615, 3555, 24976, 1783, 12, 24633, 37495, 22653, 1975, 8315, 3714, 47283, 3215, 21542, 1211, 28671, 8032, 47302, 3714, 14851, 2407, 7578, 6225, 2304, 23328, 15844, 2423, 1783, 12, 24633, 37037, 1829, 3714, 14851, 2407, 7578, 6225, 2304, 23328, 15844, 2423, 398, 12, 24633, 437, 498, 1975, 15730, 25961, 18871, 16254, 3714, 14851, 2407, 7578, 3714, 26895, 6156, 7649, 995, 34105, 16472, 16254, 16472, 8032, 47302, 2423, 1783, 12, 24633, 3714, 47283, 3215, 3714, 14851, 2407, 7578, 3714, 26895, 4724, 11622, 995, 2407, 10632, 41435, 20449, 2423, 398, 12, 24633], 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"text": "لأن هذه المسافة هاتبعها Delta X هذه المسافة Delta Y البعد التالت", "tokens": [1211, 33456, 29538, 9673, 3794, 31845, 3660, 8032, 9307, 3555, 3615, 11296, 18183, 1783, 29538, 9673, 3794, 31845, 3660, 18183, 398, 29739, 22488, 16712, 6027, 2655], "avg_logprob": -0.28616896823600485, "compression_ratio": 1.4583333333333333, "no_speech_prob": 0.0, "words": [{"start": 523.61, "end": 523.97, "word": "لأن", "probability": 0.68798828125}, {"start": 523.97, "end": 524.29, "word": " هذه", "probability": 0.7490234375}, {"start": 524.29, "end": 524.83, "word": " المسافة", "probability": 0.9752197265625}, {"start": 524.83, "end": 525.33, "word": " هاتبعها", "probability": 0.72998046875}, {"start": 525.33, "end": 525.83, "word": " Delta", "probability": 0.10003662109375}, {"start": 525.83, "end": 526.41, "word": " X", "probability": 0.90234375}, {"start": 526.41, "end": 535.27, "word": " هذه", "probability": 0.267578125}, {"start": 535.27, "end": 536.03, "word": " المسافة", "probability": 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مافيش لأ minus tau xy في delta x delta z", "tokens": [3224, 24192, 19446, 41185, 8592, 5296, 10721, 3175, 17842, 2031, 88, 8978, 8289, 2031, 8289, 710], "avg_logprob": -0.4806985294117647, "compression_ratio": 0.9655172413793104, "no_speech_prob": 0.0, "words": [{"start": 635.48, "end": 635.94, "word": "هذه", "probability": 0.4215087890625}, {"start": 635.94, "end": 636.5, "word": " مافيش", "probability": 0.6565755208333334}, {"start": 636.5, "end": 637.18, "word": " لأ", "probability": 0.6981201171875}, {"start": 637.18, "end": 638.16, "word": " minus", "probability": 0.224609375}, {"start": 638.16, "end": 639.02, "word": " tau", "probability": 0.50830078125}, {"start": 639.02, "end": 639.98, "word": " xy", "probability": 0.69140625}, {"start": 639.98, "end": 646.32, "word": " في", "probability": 0.55029296875}, {"start": 646.32, "end": 646.6, "word": " delta", "probability": 0.83837890625}, {"start": 646.6, "end": 647.06, "word": " x", "probability": 0.982421875}, {"start": 647.06, 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{"id": 26, "seek": 72297, "start": 700.41, "end": 722.97, "text": "مظلوط يعني في النهاية ستكون هي سيجما سيجما في الدرع هذا بتعطينا force في delta S تعطينا force بتاخد المركبة بتاعتها في cosine", "tokens": [2304, 19913, 1211, 2407, 9566, 37495, 22653, 8978, 28239, 11296, 10632, 8608, 2655, 30544, 39896, 8608, 1829, 7435, 15042, 8608, 1829, 7435, 15042, 8978, 32748, 2288, 3615, 23758, 39894, 3615, 9566, 1829, 8315, 3464, 8978, 8289, 318, 6055, 3615, 9566, 1829, 8315, 3464, 39894, 47283, 3215, 9673, 31747, 49401, 39894, 995, 34268, 11296, 8978, 23565], "avg_logprob": -0.36830357142857145, "compression_ratio": 1.4927536231884058, "no_speech_prob": 1.3113021850585938e-06, "words": [{"start": 700.4100000000001, "end": 701.8100000000001, "word": "مظلوط", "probability": 0.583642578125}, {"start": 701.8100000000001, "end": 703.21, "word": " يعني", "probability": 0.5853271484375}, {"start": 703.21, "end": 703.73, "word": " في", "probability": 0.8330078125}, {"start": 703.73, "end": 704.53, 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ال", "probability": 0.76171875}, {"start": 3458.88, "end": 3459.14, "word": " tau", "probability": 0.250732421875}, {"start": 3459.14, "end": 3459.7, "word": " لو", "probability": 0.442626953125}, {"start": 3459.7, "end": 3459.84, "word": " كنا", "probability": 0.96435546875}, {"start": 3459.84, "end": 3460.02, "word": " نرسم", "probability": 0.6322428385416666}, {"start": 3460.02, "end": 3460.3, "word": " more", "probability": 0.81982421875}, {"start": 3460.3, "end": 3460.6, "word": " circle", "probability": 0.92041015625}, {"start": 3460.6, "end": 3460.82, "word": " كنا", "probability": 0.8623046875}, {"start": 3460.82, "end": 3461.24, "word": " نعرف", "probability": 0.95654296875}, {"start": 3461.24, "end": 3462.56, "word": " ال", "probability": 0.81787109375}, {"start": 3462.56, "end": 3462.94, "word": " tau", "probability": 0.6396484375}, {"start": 3462.94, "end": 3463.2, "word": " هاد", "probability": 0.3060302734375}, {"start": 3463.2, "end": 3463.42, "word": " مثلا", "probability": 0.8125}, {"start": 3463.42, "end": 3463.72, "word": " هاد", "probability": 0.8056640625}, {"start": 3463.72, "end": 3464.2, "word": " ال", "probability": 0.7822265625}, {"start": 3464.2, "end": 3464.5, "word": " tau", "probability": 0.6083984375}, {"start": 3464.5, "end": 3464.68, "word": " مع", "probability": 0.98828125}, {"start": 3464.68, "end": 3464.78, "word": " ال", "probability": 0.955078125}, {"start": 3464.78, "end": 3464.94, "word": " x", "probability": 0.63134765625}, {"start": 3464.94, "end": 3465.28, "word": " axis", "probability": 0.65673828125}, {"start": 3465.28, "end": 3465.7, "word": " counter", "probability": 0.939453125}, {"start": 3465.7, "end": 3466.18, "word": " clockwise", "probability": 0.76904296875}, {"start": 3466.18, "end": 3466.4, "word": " كنا", "probability": 0.932861328125}, {"start": 3466.4, "end": 3466.6, "word": " نعرف", "probability": 0.9899088541666666}, {"start": 3466.6, "end": 3466.74, "word": " ال", "probability": 0.75537109375}, {"start": 3466.74, "end": 3466.94, "word": " counter", "probability": 0.9658203125}, {"start": 3466.94, "end": 3467.46, "word": " clockwise", "probability": 0.9052734375}, {"start": 3467.46, "end": 3468.48, "word": " موجة", "probability": 0.629638671875}, {"start": 3468.48, "end": 3469.74, "word": " يعني", "probability": 0.915283203125}, {"start": 3469.74, "end": 3469.96, "word": " هد", "probability": 0.74560546875}, {"start": 3469.96, "end": 3470.12, "word": " يقول", "probability": 0.73974609375}, {"start": 3470.12, "end": 3470.54, "word": " بيعملوا", "probability": 0.9421875}, {"start": 3470.54, "end": 3470.98, "word": " ايش؟", "probability": 0.77783203125}], "temperature": 1.0}, {"id": 121, "seek": 349792, "start": 3471.74, "end": 3497.92, "text": "بيعملوا ازدواج موجب عندي هنا تاو counter clockwise و هنا تاو clockwise طيب نيجي ل more circle هخلي المعادة لأنا عشان تعرفوا كيف أجت", "tokens": [21292, 25957, 1211, 14407, 1975, 11622, 3215, 2407, 26108, 3714, 29245, 3555, 18871, 16254, 34105, 6055, 995, 2407, 5682, 35790, 4032, 34105, 6055, 995, 2407, 35790, 23032, 1829, 3555, 8717, 1829, 7435, 1829, 5296, 544, 6329, 8032, 9778, 20292, 9673, 3615, 18513, 3660, 5296, 10721, 8315, 6225, 8592, 7649, 37279, 28480, 14407, 9122, 33911, 5551, 7435, 2655], "avg_logprob": -0.26360451609923924, "compression_ratio": 1.36, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3471.74, "end": 3472.32, "word": "بيعملوا", "probability": 0.7835693359375}, {"start": 3472.32, "end": 3472.92, "word": " ازدواج", "probability": 0.86201171875}, {"start": 3472.92, "end": 3473.68, "word": " موجب", "probability": 0.8792317708333334}, {"start": 3473.68, "end": 3475.46, "word": " عندي", "probability": 0.6832275390625}, {"start": 3475.46, "end": 3475.66, "word": " هنا", "probability": 0.43505859375}, {"start": 3475.66, "end": 3476.18, "word": " تاو", "probability": 0.6735026041666666}, {"start": 3476.18, "end": 3477.78, "word": " counter", "probability": 0.8779296875}, {"start": 3477.78, "end": 3478.4, "word": " clockwise", "probability": 0.7392578125}, {"start": 3478.4, "end": 3479.36, "word": " و", "probability": 0.51025390625}, {"start": 3479.36, "end": 3479.54, "word": " هنا", "probability": 0.77001953125}, {"start": 3479.54, "end": 3480.08, "word": " تاو", "probability": 0.8396809895833334}, {"start": 3480.08, "end": 3481.06, "word": " clockwise", "probability": 0.66650390625}, {"start": 3481.06, "end": 3486.22, "word": " طيب", "probability": 0.9200846354166666}, {"start": 3486.22, "end": 3486.5, "word": " نيجي", "probability": 0.9241943359375}, {"start": 3486.5, "end": 3486.58, "word": " ل", "probability": 0.7890625}, {"start": 3486.58, "end": 3486.76, "word": " more", "probability": 0.7431640625}, {"start": 3486.76, "end": 3487.32, "word": " circle", "probability": 0.93994140625}, {"start": 3487.32, "end": 3493.46, "word": " هخلي", "probability": 0.6436360677083334}, {"start": 3493.46, "end": 3493.92, "word": " المعادة", "probability": 0.73809814453125}, {"start": 3493.92, "end": 3494.32, "word": " لأنا", "probability": 0.7073567708333334}, {"start": 3494.32, "end": 3496.82, "word": " عشان", "probability": 0.9811197916666666}, {"start": 3496.82, "end": 3497.28, "word": " تعرفوا", "probability": 0.9684244791666666}, {"start": 3497.28, "end": 3497.5, "word": " كيف", "probability": 0.97265625}, {"start": 3497.5, "end": 3497.92, "word": " أجت", "probability": 0.8468424479166666}], "temperature": 1.0}, {"id": 122, "seek": 352593, "start": 3504.17, "end": 3525.93, "text": "الاشة عند ال C سوى Sigma X زي Sigma Y على اتنين عند ال R بسوى جزر التربيع ل Sigma X minus Sigma Y على اتنين لكل تربيع زي تاو XY تربيع", "tokens": [6027, 33599, 3660, 43242, 2423, 383, 8608, 2407, 7578, 36595, 1783, 30767, 1829, 36595, 398, 15844, 1975, 2655, 1863, 9957, 43242, 2423, 497, 4724, 3794, 2407, 7578, 10874, 11622, 2288, 16712, 2288, 21292, 3615, 5296, 36595, 1783, 3175, 36595, 398, 15844, 1975, 2655, 1863, 9957, 5296, 28820, 6055, 2288, 21292, 3615, 30767, 1829, 6055, 995, 2407, 48826, 6055, 2288, 21292, 3615], "avg_logprob": -0.25907257968379604, "compression_ratio": 1.6290322580645162, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 3504.17, "end": 3505.21, "word": "الاشة", "probability": 0.4342041015625}, {"start": 3505.21, "end": 3506.25, "word": " عند", "probability": 0.80517578125}, {"start": 3506.25, "end": 3506.47, "word": " ال", "probability": 0.76513671875}, {"start": 3506.47, "end": 3506.79, "word": " C", "probability": 0.576171875}, {"start": 3506.79, "end": 3508.87, "word": " سوى", "probability": 0.5240478515625}, {"start": 3508.87, "end": 3509.15, "word": " Sigma", "probability": 0.50341796875}, {"start": 3509.15, "end": 3509.59, "word": " X", "probability": 0.923828125}, {"start": 3509.59, "end": 3509.99, "word": " زي", "probability": 0.6097412109375}, {"start": 3509.99, "end": 3510.35, "word": " Sigma", "probability": 0.9072265625}, {"start": 3510.35, "end": 3510.77, "word": " Y", "probability": 0.9794921875}, {"start": 3510.77, "end": 3511.77, "word": " على", "probability": 0.65771484375}, {"start": 3511.77, "end": 3512.31, "word": " اتنين", "probability": 0.8038330078125}, {"start": 3512.31, "end": 3513.09, "word": " عند", "probability": 0.84130859375}, {"start": 3513.09, "end": 3513.37, "word": " ال", "probability": 0.96484375}, {"start": 3513.37, "end": 3513.79, "word": " R", "probability": 0.9736328125}, {"start": 3513.79, "end": 3515.17, "word": " بسوى", "probability": 0.8521728515625}, {"start": 3515.17, "end": 3515.49, "word": " جزر", "probability": 0.92529296875}, {"start": 3515.49, "end": 3516.07, "word": " التربيع", "probability": 0.781005859375}, {"start": 3516.07, "end": 3517.11, "word": " ل", "probability": 0.7490234375}, {"start": 3517.11, "end": 3517.45, "word": " Sigma", "probability": 0.89306640625}, {"start": 3517.45, "end": 3517.97, "word": " X", "probability": 0.9912109375}, {"start": 3517.97, "end": 3518.69, "word": " minus", "probability": 0.728515625}, {"start": 3518.69, "end": 3519.03, "word": " Sigma", "probability": 0.90771484375}, {"start": 3519.03, "end": 3519.39, "word": " Y", "probability": 0.98974609375}, {"start": 3519.39, "end": 3519.75, "word": " على", "probability": 0.84033203125}, {"start": 3519.75, "end": 3520.27, "word": " اتنين", "probability": 0.9791259765625}, {"start": 3520.27, "end": 3521.01, "word": " لكل", "probability": 0.948974609375}, {"start": 3521.01, "end": 3521.67, "word": " تربيع", "probability": 0.927490234375}, {"start": 3521.67, "end": 3522.77, "word": " زي", "probability": 0.93505859375}, {"start": 3522.77, "end": 3523.89, "word": " تاو", "probability": 0.6531575520833334}, {"start": 3523.89, "end": 3524.35, "word": " XY", "probability": 0.70166015625}, {"start": 3524.35, "end": 3525.93, "word": " تربيع", "probability": 0.9124755859375}], "temperature": 1.0}, {"id": 123, "seek": 355482, "start": 3533.1, "end": 3554.82, "text": "هي مورسيكا لان عندي محورين محور السيجما محور التاو عندي هنا تاو clockwise وهنا تاو counter clockwise عندي stress element sigma x", "tokens": [3224, 1829, 3714, 13063, 3794, 1829, 4117, 995, 5296, 7649, 18871, 16254, 3714, 5016, 13063, 9957, 3714, 5016, 13063, 21136, 1829, 7435, 15042, 3714, 5016, 13063, 16712, 995, 2407, 18871, 16254, 34105, 6055, 995, 2407, 35790, 37037, 8315, 6055, 995, 2407, 5682, 35790, 18871, 16254, 4244, 4478, 12771, 2031], "avg_logprob": -0.37812500953674316, "compression_ratio": 1.5403225806451613, "no_speech_prob": 0.0, "words": [{"start": 3533.1, "end": 3533.4, "word": "هي", "probability": 0.45709228515625}, {"start": 3533.4, "end": 3534.02, "word": " مورسيكا", "probability": 0.78076171875}, {"start": 3534.02, "end": 3534.24, "word": " لان", "probability": 0.55517578125}, {"start": 3534.24, "end": 3534.64, "word": " عندي", "probability": 0.6097412109375}, {"start": 3534.64, "end": 3536.02, "word": " محورين", "probability": 0.912841796875}, {"start": 3536.02, "end": 3536.88, "word": " محور", "probability": 0.8974609375}, {"start": 3536.88, "end": 3537.38, "word": " السيجما", "probability": 0.6312255859375}, {"start": 3537.38, "end": 3539.22, "word": " محور", "probability": 0.8733723958333334}, {"start": 3539.22, "end": 3539.56, "word": " التاو", "probability": 0.79248046875}, {"start": 3539.56, "end": 3539.78, "word": " عندي", "probability": 0.5914306640625}, {"start": 3539.78, "end": 3539.96, "word": " هنا", "probability": 0.48291015625}, {"start": 3539.96, "end": 3540.82, "word": " تاو", "probability": 0.7479654947916666}, {"start": 3540.82, "end": 3541.54, "word": " clockwise", "probability": 0.5712890625}, {"start": 3541.54, "end": 3543.16, "word": " وهنا", "probability": 0.743896484375}, {"start": 3543.16, "end": 3543.9, "word": " تاو", "probability": 0.84521484375}, {"start": 3543.9, "end": 3545.62, "word": " counter", "probability": 0.8994140625}, {"start": 3545.62, "end": 3547.8, "word": " clockwise", "probability": 0.59130859375}, {"start": 3547.8, "end": 3550.04, "word": " عندي", "probability": 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نشوف مثال", "tokens": [1211, 5172, 2655, 8032, 4117, 3552, 33, 5682, 35790, 8717, 8592, 38688, 50113, 6027], "avg_logprob": -0.642187484105428, "compression_ratio": 0.8225806451612904, "no_speech_prob": 0.0, "words": [{"start": 4215.02, "end": 4215.54, "word": "لفت", "probability": 0.59814453125}, {"start": 4215.54, "end": 4215.86, "word": " هك", "probability": 0.5660400390625}, {"start": 4215.86, "end": 4217.58, "word": " 25B", "probability": 0.220245361328125}, {"start": 4217.58, "end": 4219.2, "word": " counter", "probability": 0.492431640625}, {"start": 4219.2, "end": 4219.72, "word": " clockwise", "probability": 0.77490234375}, {"start": 4219.72, "end": 4228.44, "word": " نشوف", "probability": 0.688232421875}, {"start": 4228.44, "end": 4228.94, "word": " مثال", "probability": 0.819580078125}], "temperature": 1.0}, {"id": 147, "seek": 427314, "start": 4250.03, "end": 4273.15, "text": "Find Stress Element علي Normal Stress Sigma X Sigma X بالساوة تمانين ميجا بسكال و هنا Clockwise", "tokens": [37, 471, 38258, 20900, 25894, 21277, 38258, 36595, 1783, 36595, 1783, 20666, 3794, 995, 2407, 3660, 6055, 2304, 7649, 9957, 3714, 1829, 7435, 995, 4724, 3794, 4117, 6027, 4032, 34105, 46986, 3711], "avg_logprob": -0.5004734848484849, "compression_ratio": 1.087719298245614, "no_speech_prob": 0.0, "words": [{"start": 4250.03, "end": 4250.33, "word": "Find", "probability": 0.6624755859375}, {"start": 4250.33, "end": 4250.75, "word": " Stress", "probability": 0.44921875}, {"start": 4250.75, "end": 4251.23, "word": " Element", "probability": 0.6357421875}, {"start": 4251.23, "end": 4258.45, "word": " علي", "probability": 0.2364501953125}, {"start": 4258.45, "end": 4258.75, "word": " Normal", "probability": 0.65673828125}, {"start": 4258.75, "end": 4259.39, "word": " Stress", "probability": 0.94189453125}, {"start": 4259.39, "end": 4262.23, "word": " Sigma", "probability": 0.384033203125}, {"start": 4262.23, "end": 4262.73, "word": " X", "probability": 0.912109375}, {"start": 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/m24YdEGrcDc_raw.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/m24YdEGrcDc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e38900b39246146311af327338bc165ee07034c2
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/m24YdEGrcDc_raw.srt
@@ -0,0 +1,2764 @@
+1
+00:00:05,400 --> 00:00:08,420
+السلام عليكم ورحمة الله وبركاته بسم الله الرحمن
+
+2
+00:00:08,420 --> 00:00:12,620
+الرحيم اليوم هنستكمل chapter three اللي هو load
+
+3
+00:00:12,620 --> 00:00:17,300
+and stress analysis اللي في المحاضرة الفاتتة قطينا
+
+4
+00:00:17,300 --> 00:00:21,520
+ال bending and ال .. ال shear و ال bending moment
+
+5
+00:00:21,520 --> 00:00:27,180
+diagrams حلينا بالطريقة التقليدية حددنا ال sign
+
+6
+00:00:27,180 --> 00:00:29,620
+convention لل positive moment و ال sign convention
+
+7
+00:00:29,620 --> 00:00:35,330
+لل positive and negative shearحكينا في علاقة بين
+
+8
+00:00:35,330 --> 00:00:40,330
+ال shear stress و ال moment V بيستوى DM by DX و ال
+
+9
+00:00:40,330 --> 00:00:47,590
+Q بيستوى DV by DX حلينا example بالطريقة التقليدية
+
+10
+00:00:47,590 --> 00:00:52,090
+انه ناخد summation of forces و نجيد ال reactions
+
+11
+00:00:52,090 --> 00:00:56,570
+بعدين ناخد section نعمل free body diagram و نحسب
+
+12
+00:00:56,570 --> 00:00:59,070
+ال shear و ال bending moment diagram منه رسمنا ال
+
+13
+00:00:59,070 --> 00:01:00,730
+shear و ال moment diagram
+
+14
+00:01:02,760 --> 00:01:07,120
+بعدين استخدمنا ال singularity functions عشان نوجد
+
+15
+00:01:07,120 --> 00:01:10,400
+ال reactions و نوجد ال shear و ال bending moment
+
+16
+00:01:10,400 --> 00:01:17,360
+diagrams حلنا example تلات تلاتة اليوم هنكمل برضه
+
+17
+00:01:17,360 --> 00:01:23,140
+مراجعة على مادة ال mechanics of material انبين
+
+18
+00:01:23,140 --> 00:01:29,730
+عندى stress elementstress element هذا قد يكون نقطة
+
+19
+00:01:29,730 --> 00:01:34,050
+في mechanical member في machine يعني ال stress في
+
+20
+00:01:34,050 --> 00:01:39,550
+ال .. في النهاية ناتج عن أحمال سواء كانت أحمال
+
+21
+00:01:39,550 --> 00:01:45,910
+يعني مفردة يعني زي حمل شد أو compression أو حمل
+
+22
+00:01:45,910 --> 00:01:54,010
+ثاني أو حمل lay أو حمل shearأو أحمل مركبة، مركبة
+
+23
+00:01:54,010 --> 00:02:00,350
+شير على axial على bending على .. على torsion في
+
+24
+00:02:00,350 --> 00:02:03,630
+النهاية هيتولد end stresses ال most general case ل
+
+25
+00:02:03,630 --> 00:02:08,100
+stress elementان يكون عليه كل stress موجودة في كل
+
+26
+00:02:08,100 --> 00:02:11,560
+اتجاهات عندها small stress element هذا هو ال X
+
+27
+00:02:11,560 --> 00:02:21,560
+axis Y Z عند سيجما X سيجما Y سيجما Z وعندها كل سطح
+
+28
+00:02:21,560 --> 00:02:28,140
+سطح فيه two components لل share اذا عندي السطح هذا
+
+29
+00:02:28,140 --> 00:02:33,020
+عندي X Y Z
+
+30
+00:02:35,160 --> 00:02:39,760
+الان كيف بنسمي تسمية الشير stress سطح هذا عليه two
+
+31
+00:02:39,760 --> 00:02:46,380
+components component موازية لل z axis و component
+
+32
+00:02:46,380 --> 00:02:54,800
+موازية لل x axis لل y axis الان بعرف الشير tau
+
+33
+00:02:54,800 --> 00:03:00,480
+مثلا عندي tau x z
+
+34
+00:03:02,640 --> 00:03:16,460
+ال X مثل المحور المتعمد على المستوى تحت الدراسة
+
+35
+00:03:16,460 --> 00:03:22,680
+أنا بحكي المستوى هذا صح؟ المتعمد عليه إيه إيش؟ ال
+
+36
+00:03:22,680 --> 00:03:30,620
+X axis فهي عندي ال X ال Z اللي هي .. اللي هو
+
+37
+00:03:30,620 --> 00:03:31,180
+direction
+
+38
+00:03:36,080 --> 00:03:44,900
+parallel to shear stress component
+
+39
+00:03:44,900 --> 00:03:54,280
+يعني لما نحكي tau xz هي مركبة ال shear اللي وقع في
+
+40
+00:03:54,280 --> 00:04:00,520
+المستوى المتعمد على ال x axis موازية لل z يعني
+
+41
+00:04:00,520 --> 00:04:02,880
+احنا احنا هنكون عنده هذه
+
+42
+00:04:07,440 --> 00:04:18,580
+Tau X Z هي موازية لل Z وعندي Tau X
+
+43
+00:04:18,580 --> 00:04:25,080
+Y مثلا المستوى هذه أول أول شي عندها هكون ال Y عندي
+
+44
+00:04:25,080 --> 00:04:31,340
+هذه Tau هاي ال direction عمود على المستوى
+
+45
+00:04:31,340 --> 00:04:36,770
+بالمناسبة المستوى دائما يعرف باشبالمتعمد عليه
+
+46
+00:04:36,770 --> 00:04:45,490
+بالعمودي عليه تاو Y X وعندي
+
+47
+00:04:45,490 --> 00:04:51,570
+تاو Y Z لأن هو هي عمودي على المستوى معرف بال
+
+48
+00:04:51,570 --> 00:04:56,530
+Normal عليه اللي هو ال Y موازن ال Z Axis تاو Y X
+
+49
+00:04:56,530 --> 00:04:59,610
+المستوى
+
+50
+00:04:59,610 --> 00:05:03,670
+هذا معرف بالعمود عليه اللي هو ال Y Axis و هو في
+
+51
+00:05:03,670 --> 00:05:09,560
+اتجاه ال X Axisعندي هين المستوهة ده متعمدة على ال
+
+52
+00:05:09,560 --> 00:05:18,100
+z axis فهيبدأ تاو زد موازي ال y عندي هين تاو
+
+53
+00:05:18,100 --> 00:05:23,820
+المستوهة ده عمودي على ال z تاو زد موازي ال x axis
+
+54
+00:05:25,890 --> 00:05:28,550
+بالاضافة للمورمو ال stress components اللي هو
+
+55
+00:05:28,550 --> 00:05:49,570
+sigma x و sigma y و sigma z هدرس
+
+56
+00:05:49,570 --> 00:05:52,750
+الحالة اللي هي تمثل ل plane stress case
+
+57
+00:05:55,960 --> 00:06:01,660
+بكون عندى plan stress يعني stress فى بوادين او فى
+
+58
+00:06:01,660 --> 00:06:06,220
+مستوى اذا كانت ال stresses on one surface are zero
+
+59
+00:06:06,220 --> 00:06:12,400
+يعني هى ال X Y Z لو كانت ال stresses على المستوى
+
+60
+00:06:12,400 --> 00:06:18,380
+هذا المتعود على Z axis ال sigma Z والتوزيد X
+
+61
+00:06:18,380 --> 00:06:23,630
+والتوزيد Y بتستوى Zero بعتبرهاa case of plan
+
+62
+00:06:23,630 --> 00:06:27,710
+stress ال case of plan stress عندى هاي ال x axis
+
+63
+00:06:27,710 --> 00:06:36,210
+هاي ال y axis عندى sigma x sigma y tau xy tau xy
+
+64
+00:06:36,210 --> 00:06:43,480
+tau xy tau xyهذا case هو plan stress اللي هو z أكس
+
+65
+00:06:43,480 --> 00:06:47,580
+عمودي على الصفحة sigma z بالساوية zero و sigma zx
+
+66
+00:06:47,580 --> 00:06:52,780
+بالساوية zero أو tau zx و tau zy بالساوية zero
+
+67
+00:06:52,780 --> 00:07:02,400
+هناخد
+
+68
+00:07:02,400 --> 00:07:13,230
+الحالة ل plan stress case بدي أشوفالـ stresses at
+
+69
+00:07:13,230 --> 00:07:18,410
+any other plane مش موازي لل X-axis يعني مش موازي
+
+70
+00:07:18,410 --> 00:07:20,930
+أو متعب لل X-axis يعني انا ماخد الحلقة هاي مستوى
+
+71
+00:07:20,930 --> 00:07:24,270
+عمود على ال X-axis وهي مستوى عمود على ال Y-axis
+
+72
+00:07:24,270 --> 00:07:28,310
+what if اذا كان عندي مستوى ميل فانا هنا اندي ان
+
+73
+00:07:28,310 --> 00:07:37,390
+هاي ال X-axis ماخد مستوى ميل بزاوية Phi مع ال Y
+
+74
+00:07:37,390 --> 00:07:47,650
+-axisطبعا على المستوى هذا يوجد stress sigma x و
+
+75
+00:07:47,650 --> 00:08:00,090
+stress tau xy على المستوى هذا يوجد sigma y و tau
+
+76
+00:08:00,090 --> 00:08:06,230
+xy على المستوى اللي ما يلحق هو اندي stress normal
+
+77
+00:08:06,230 --> 00:08:07,130
+stress component
+
+78
+00:08:10,480 --> 00:08:17,920
+سيجما وشير السترس كومبونات تاو طبعا الزاوية هد
+
+79
+00:08:17,920 --> 00:08:26,260
+هتكون إيه؟ فاي لإن هد فاي هد هتكون تسعين ناقص فاي
+
+80
+00:08:26,260 --> 00:08:32,920
+صح؟ هد فاي معناته هد تسعين ناقص فاي معناته هد إيه؟
+
+81
+00:08:32,920 --> 00:08:33,320
+فاي
+
+82
+00:08:43,610 --> 00:08:55,270
+لأن هذه المسافة هاتبعها Delta X هذه
+
+83
+00:08:55,270 --> 00:09:06,270
+المسافة Delta Y البعد
+
+84
+00:09:06,270 --> 00:09:06,870
+التالت
+
+85
+00:09:19,020 --> 00:09:26,460
+هذا البعد التالت هسميه
+
+86
+00:09:26,460 --> 00:09:35,060
+delta z انا
+
+87
+00:09:35,060 --> 00:09:36,180
+بعمل free body diagram
+
+88
+00:09:39,420 --> 00:09:48,820
+هعندي ال X axis هاي ال Y axis هاخد
+
+89
+00:09:48,820 --> 00:09:54,620
+summation of forces باتجاه ال X axis summation of
+
+90
+00:09:54,620 --> 00:09:59,680
+forces بتجاه ال Y axis summation of forces بتجاه
+
+91
+00:09:59,680 --> 00:10:04,940
+ال X بالساوية Zero و اعتبر هذا الاتجاه الموجب
+
+92
+00:10:08,260 --> 00:10:13,220
+الـ sigma x هذه بتأثر بهذا الاتجاه stress في area
+
+93
+00:10:13,220 --> 00:10:19,280
+بيعطيني force فهيكون minus sigma x ال area هتكون
+
+94
+00:10:19,280 --> 00:10:20,280
+delta y في delta z
+
+95
+00:10:35,480 --> 00:10:46,320
+هذه مافيش لأ minus tau xy في
+
+96
+00:10:46,320 --> 00:10:48,840
+delta x delta z
+
+97
+00:11:05,240 --> 00:11:10,740
+بتساوى عند هاي sigma اللي هو مركبتين واحد اتجاه ال
+
+98
+00:11:10,740 --> 00:11:23,700
+X axis بساوى زائد sigma في cos فاي فيه
+
+99
+00:11:23,700 --> 00:11:34,120
+بتساوى عند دلتا S في دلتا
+
+100
+00:11:34,120 --> 00:11:34,460
+S
+
+101
+00:11:40,410 --> 00:11:51,810
+مظلوط يعني في النهاية ستكون هي سيجما سيجما في
+
+102
+00:11:51,810 --> 00:11:58,990
+الدرع هذا بتعطينا force في delta S تعطينا force
+
+103
+00:11:58,990 --> 00:12:06,120
+بتاخد المركبة بتاعتها في cosineالـ Phi Delta S
+
+104
+00:12:06,120 --> 00:12:12,240
+طبعا في Delta Z ستكون
+
+105
+00:12:12,240 --> 00:12:17,760
+Sigma Delta
+
+106
+00:12:17,760 --> 00:12:26,280
+S Delta Z في المركبة بتاعتها اللي هي إيش Cos Phi
+
+107
+00:12:26,280 --> 00:12:30,240
+minus
+
+108
+00:12:30,240 --> 00:12:30,640
+Tau
+
+109
+00:12:36,770 --> 00:12:53,610
+في Delta S Delta Z Sin Phi طيب
+
+110
+00:12:53,610 --> 00:12:59,890
+لاحظوا
+
+111
+00:12:59,890 --> 00:13:06,810
+في علاقة بين Delta Sو ال delta x و ال delta y يعني
+
+112
+00:13:06,810 --> 00:13:14,270
+ممكن احكي انا cosine الفي ايش
+
+113
+00:13:14,270 --> 00:13:18,210
+هو الساوية delta
+
+114
+00:13:18,210 --> 00:13:28,110
+y على delta s صح delta y على delta s cosine الفي
+
+115
+00:13:28,110 --> 00:13:31,730
+delta
+
+116
+00:13:31,730 --> 00:13:43,500
+x على delta sيعني ممكن احكي انا دلتا S بتساوي دلتا
+
+117
+00:13:43,500 --> 00:13:54,180
+Y على كسين الفي و برضه بتساوي دلتا X على سين الفي
+
+118
+00:13:54,180 --> 00:13:58,660
+نرجع
+
+119
+00:13:58,660 --> 00:14:02,940
+لمعادة، صارت عندي المعادة عندي سفربالسواء minus
+
+120
+00:14:02,940 --> 00:14:17,900
+sigma x delta y delta z minus tau xy delta x delta
+
+121
+00:14:17,900 --> 00:14:27,740
+z زائد sigma sigma
+
+122
+00:14:27,740 --> 00:14:34,030
+delta اذا عندي هنا cosine فيمعناه دلتا S هتكون في
+
+123
+00:14:34,030 --> 00:14:44,910
+دلتا Y على cosine الفاي في دلتا Z cosine الفاي
+
+124
+00:14:44,910 --> 00:14:47,950
+minus
+
+125
+00:14:47,950 --> 00:14:51,830
+tau
+
+126
+00:14:51,830 --> 00:14:58,550
+في دلتا X على sine الفاي
+
+127
+00:14:59,840 --> 00:15:17,400
+دلتا زد صين دلتا زد صين الفاية يعني
+
+128
+00:15:17,400 --> 00:15:21,600
+ادي ال cos فاية هنا تختصر
+
+129
+00:15:25,580 --> 00:15:33,060
+وSin فاي تختصر و Delta Z تختصر
+
+130
+00:15:33,060 --> 00:15:37,080
+و Delta
+
+131
+00:15:37,080 --> 00:15:41,660
+Z تختصر طيب
+
+132
+00:15:41,660 --> 00:15:48,100
+لو قسمت الطرفين على Delta X خينا ناخد لحالة لان
+
+133
+00:15:48,100 --> 00:15:58,550
+End صار Zeroبسوا minus sigma x delta y minus tau
+
+134
+00:15:58,550 --> 00:16:06,110
+xy delta x delta
+
+135
+00:16:06,110 --> 00:16:13,210
+x زاد sigma delta y
+
+136
+00:16:17,930 --> 00:16:28,570
+مينس تا دلتا اكس فيش ضال؟ لأ انا هضطر اعود اجحك من
+
+137
+00:16:28,570 --> 00:16:39,290
+هنا دلتا Y بالساوية دلتا S في cos فاي ماشي و دلتا
+
+138
+00:16:39,290 --> 00:16:46,740
+X بالساوية دلتا S في sin فاي ليش هعمل زي هيك؟عشان
+
+139
+00:16:46,740 --> 00:16:54,380
+ألغى ألغى هدول صح يعني حسابي عند ال zero minus
+
+140
+00:16:54,380 --> 00:17:05,740
+sigma x في delta s cosine فى minus tau xy delta s
+
+141
+00:17:05,740 --> 00:17:15,200
+sine فى زاد sigma في delta s cosine فى
+
+142
+00:17:21,590 --> 00:17:34,470
+من أول ماشي الان هيروح عندى Delta S Delta S Delta
+
+143
+00:17:34,470 --> 00:17:44,630
+S Delta S حاسين عندى Zero minus Sigma X Cos Phi
+
+144
+00:17:46,110 --> 00:17:59,810
+minus tau xy sine of phi زائد sigma cosine of phi
+
+145
+00:17:59,810 --> 00:18:05,670
+minus tau sine of phi احنا نحسب sigma و tau
+
+146
+00:18:35,110 --> 00:18:36,910
+الحق الصممش ال forces
+
+147
+00:18:40,090 --> 00:18:49,370
+باتجاه ال Y بتساوي Zero هكون
+
+148
+00:18:49,370 --> 00:18:56,850
+دي Minus Tau XY Delta
+
+149
+00:18:56,850 --> 00:19:05,550
+Y Delta Z Minus
+
+150
+00:19:05,550 --> 00:19:06,450
+Sigma Y
+
+151
+00:19:10,920 --> 00:19:18,480
+Delta X Delta Z Delta
+
+152
+00:19:18,480 --> 00:19:29,380
+X Delta Z Minus Sigma Y Delta X Delta Z زاد
+
+153
+00:19:29,380 --> 00:19:44,990
+Sigma Delta SDelta Z Sin Phi زاد
+
+154
+00:19:44,990 --> 00:19:57,870
+Tau Delta S Delta Z Cos Phi خلّيني
+
+155
+00:19:57,870 --> 00:20:01,050
+اختصر أول أول يعني واضح Delta Z بتروح معانا
+
+156
+00:20:06,320 --> 00:20:12,920
+لأ اعوض عن Delta Y Delta S Cos Phi حسين عن دي صفر
+
+157
+00:20:12,920 --> 00:20:23,460
+بيساو minus Tau XY Delta Y اللي هي Delta S Cos Phi
+
+158
+00:20:23,460 --> 00:20:39,190
+minus Sigma Y في Delta S Sin Phiزاد سيجما دلتا S
+
+159
+00:20:39,190 --> 00:20:54,150
+صين الفاى زاد تا دلتا S كسين الفاى يعني
+
+160
+00:20:54,150 --> 00:20:55,230
+هتروح عندي دلتا S
+
+161
+00:21:03,510 --> 00:21:12,990
+هيصف عندي سيجما ساين الفاى سيجما ساين الفاى زائد
+
+162
+00:21:12,990 --> 00:21:27,850
+تاو كساين الفاى بتساوي تاو X Y هتساوي سيجما Y ساين
+
+163
+00:21:27,850 --> 00:21:32,130
+الفاى زائد
+
+164
+00:21:33,720 --> 00:21:44,260
+تاو اكس واي كوسين الفاية مظبوط
+
+165
+00:21:44,260 --> 00:21:52,000
+سيجما واي كوسين الفاية زي تاو اكس واي كوسين الفاية
+
+166
+00:21:52,000 --> 00:22:00,780
+هذه معادلة اتنين هربع
+
+167
+00:22:00,780 --> 00:22:05,960
+واحدواربع اتنين واجمعهم مع بعض يعني احكي واحد
+
+168
+00:22:05,960 --> 00:22:13,060
+square زائد
+
+169
+00:22:13,060 --> 00:22:20,960
+اتنين معدل اتنين square هاي
+
+170
+00:22:20,960 --> 00:22:26,680
+واحد هكون اتنقل بين الاتنين بين هاد و هاد هكون دي
+
+171
+00:22:26,680 --> 00:22:27,600
+sigma تربيع
+
+172
+00:22:37,950 --> 00:22:49,150
+سيجما تربية ساين تربية فاي هرجع هنا زي تاو تربية
+
+173
+00:22:49,150 --> 00:23:00,640
+ساين تربية فاي هاجه هنا زي تاو تربيةcos تربية فاي
+
+174
+00:23:00,640 --> 00:23:11,880
+ماشي رابطها هتكون minus اتنين minus اتنين سيجما
+
+175
+00:23:11,880 --> 00:23:18,580
+سيجما تاو كساين ساي زي اتنين سيجما تاو ساين كساين
+
+176
+00:23:18,580 --> 00:23:23,520
+بالغبال على بعض معناه انت خلصنا جهة الشمال هتساوي
+
+177
+00:23:31,610 --> 00:23:37,250
+سيجما اكس تربيع
+
+178
+00:23:37,250 --> 00:23:48,030
+سيجما اكس تربيع كوسين تربيع في زاد
+
+179
+00:23:48,030 --> 00:23:56,090
+سيجما اكس تربيع سيجما
+
+180
+00:23:56,090 --> 00:24:11,220
+واي هذه زاد سيجما وايتربية sin تربية في زائد
+
+181
+00:24:11,220 --> 00:24:24,040
+TAO XY تربية sin تربية في زائد
+
+182
+00:24:24,040 --> 00:24:31,100
+TAO XY تربية cos تربية في
+
+183
+00:24:34,800 --> 00:24:42,980
+زائد عندي اتنين هادي في هادي، صح؟ زائد اتنين هادي
+
+184
+00:24:42,980 --> 00:24:49,720
+في هادي، زائد اتنين تو
+
+185
+00:24:49,720 --> 00:24:54,720
+اكس واي سيجما
+
+186
+00:24:54,720 --> 00:25:02,580
+اكس صين في كوسين في
+
+187
+00:25:04,690 --> 00:25:10,010
+زاد اتنين تاو
+
+188
+00:25:10,010 --> 00:25:14,490
+اكس واي سيجما
+
+189
+00:25:14,490 --> 00:25:21,750
+واي صين في كوصين في
+
+190
+00:25:39,980 --> 00:25:43,940
+طيب هذا sigma تربيع cos تربيع زي sigma تربيع sin
+
+191
+00:25:43,940 --> 00:25:51,440
+تربيع ماهو الساوية سيجما تربيع سيجما تربيع زي
+
+192
+00:25:51,440 --> 00:26:00,620
+التاو تربيع زي
+
+193
+00:26:00,620 --> 00:26:05,400
+التاو تربيع بتساوية
+
+194
+00:26:09,780 --> 00:26:20,940
+سيجما اكس تربيع لأ
+
+195
+00:26:20,940 --> 00:26:26,220
+مافيش اختصارات عشان انا اسوي هنضب المعادل الاولى
+
+196
+00:26:26,220 --> 00:26:32,660
+cosine والمعادل التانية بصين بعد ايه بنجمعهم ليش
+
+197
+00:26:32,660 --> 00:26:37,960
+حضروا اللي قالوا لأن بلغي التاو مع ناتو حل غيادة
+
+198
+00:26:39,120 --> 00:26:46,200
+هذه معادلة واحد هك
+
+199
+00:26:46,200 --> 00:26:49,020
+انا اعططنى معادلة اللى هى انا روحت على more circle
+
+200
+00:26:49,020 --> 00:26:54,420
+اقعدل هك انا هك حصل ل more circle معادلة دائرة بس
+
+201
+00:26:54,420 --> 00:26:58,020
+انا هجيب sigma لحال و tau لحال بعدين هروح على more
+
+202
+00:26:58,020 --> 00:27:01,460
+circle هتعرف بعد شوية انه عملت more circle انا
+
+203
+00:27:01,460 --> 00:27:08,510
+اللى عملته حاليا هك multiply واحد واحدفى cosine
+
+204
+00:27:08,510 --> 00:27:17,270
+فاى زائد اتنين فى sin فاى ايش حاسسيه اللى عندىه
+
+205
+00:27:17,270 --> 00:27:20,510
+سيجما
+
+206
+00:27:20,510 --> 00:27:25,230
+كوصين تربيع يعني هذا هتروح مع هذا سيجما كوصين
+
+207
+00:27:25,230 --> 00:27:33,670
+تربيع زائد سيجما sin تربيع سيجما سيجما بتساوي
+
+208
+00:27:33,670 --> 00:27:36,270
+سيجما X
+
+209
+00:27:41,110 --> 00:27:50,230
+الأولى في Cos Sigma X Cos تربيع Phi زائد Sigma Y
+
+210
+00:27:50,230 --> 00:28:00,590
+في Sin تربيع Phi Cos
+
+211
+00:28:00,590 --> 00:28:21,660
+Sin زائد اتنينtau xy sin phi cos phi اللي
+
+212
+00:28:21,660 --> 00:28:27,480
+.. اللي .. اللي شسواه هو .. هنختصر عندكوا cosine
+
+213
+00:28:27,480 --> 00:28:33,840
+two theta ايش يستوي؟ cosine تربيعتي
+
+214
+00:28:38,390 --> 00:28:46,430
+cos²θ-sin²θ صح هذه هتكون تساوي cos²θ
+
+215
+00:28:46,430 --> 00:28:57,010
+-1-cos²θ صح يعني هتكون تساوي 2cos²θ
+
+216
+00:28:57,010 --> 00:29:04,250
+-1 يعني cos²θ بالساوية نص
+
+217
+00:29:06,680 --> 00:29:15,020
+فى واحد زاد cosine two theta هى الصيغة مظبوط الان
+
+218
+00:29:15,020 --> 00:29:20,900
+انا ممكن احكيه برضه cosine two theta بستوى واحد
+
+219
+00:29:20,900 --> 00:29:27,440
+minus sin تربيع theta minus sin تربيع theta صح
+
+220
+00:29:27,440 --> 00:29:34,320
+يعنى هتكون واحد ماقص اتنين sin تربيع theta يعني
+
+221
+00:29:34,320 --> 00:29:35,660
+cosine two theta
+
+222
+00:29:59,640 --> 00:30:07,400
+معناته هيجي اعوض عن هذا سجماسيجما بساوية سيجما X
+
+223
+00:30:07,400 --> 00:30:19,280
+في cos تربيع ثيتا عبر عن نص في واحد زائد cosine
+
+224
+00:30:19,280 --> 00:30:25,600
+two في زائد
+
+225
+00:30:25,600 --> 00:30:38,020
+سيجما Y على اتنين في واحد minus cosineتو فاى زاد
+
+226
+00:30:38,020 --> 00:30:52,920
+تاو اكس واي صين تو فاى يعني
+
+227
+00:30:52,920 --> 00:30:57,120
+انا هاكون لحظة هي سيجما اكس على اتنين زائد سيجما
+
+228
+00:30:57,120 --> 00:31:02,320
+واي على اتنين سيجما اكس على اتنين سيجما اكس زائد
+
+229
+00:31:02,320 --> 00:31:07,500
+سيجما وايعلى اتنين خلصنا اول term زائد sigma x
+
+230
+00:31:07,500 --> 00:31:10,780
+minus
+
+231
+00:31:10,780 --> 00:31:22,600
+sigma y على اتنين cosine two phi مظلوط زائد tau xy
+
+232
+00:31:22,600 --> 00:31:28,460
+sine two phi اللي هي معادلة sigma اللي هي ادى
+
+233
+00:31:28,460 --> 00:31:28,880
+المعادلة
+
+234
+00:31:34,200 --> 00:31:41,440
+احنا عرفنا sigma بنفس
+
+235
+00:31:41,440 --> 00:31:47,560
+المنطقة لو ضربنا المعادلة الأولى ب sin phi
+
+236
+00:31:47,560 --> 00:31:53,380
+والمعادلة
+
+237
+00:31:53,380 --> 00:31:57,580
+التانية ب minus cosine phi يعني حكينا
+
+238
+00:32:04,680 --> 00:32:12,400
+Sin Phi أعضر
+
+239
+00:32:12,400 --> 00:32:20,640
+الأولى بالـ minus ماشي Sin Phi في معادلة واحد
+
+240
+00:32:20,640 --> 00:32:30,300
+minus Cos Phi في المعادلة التانية هيعطينا
+
+241
+00:32:34,760 --> 00:32:41,700
+يعني هاد هتروح مع هاد صح؟ هاد هتصير minus tau sine
+
+242
+00:32:41,700 --> 00:32:47,560
+تربية minus tau cosine تربية يعني هتكون minus tau
+
+243
+00:32:47,560 --> 00:32:57,300
+minus tau هتساوي sigma x هتكون
+
+244
+00:32:57,300 --> 00:32:58,220
+دي sigma x
+
+245
+00:33:03,670 --> 00:33:12,150
+Sin Phi Cos Phi Minus
+
+246
+00:33:12,150 --> 00:33:19,730
+Sigma Y Sin
+
+247
+00:33:19,730 --> 00:33:27,970
+Phi Cos Phi عندي
+
+248
+00:33:27,970 --> 00:33:28,170
+هنا
+
+249
+00:33:31,160 --> 00:33:39,580
+تاو اكس واي تاو اكس واي صين .. صين تربيع وعندي هنا
+
+250
+00:33:39,580 --> 00:33:42,600
+زاد
+
+251
+00:33:42,600 --> 00:33:51,460
+تاو اكس واي صين تربيع
+
+252
+00:33:51,460 --> 00:33:57,320
+في minus
+
+253
+00:33:57,320 --> 00:34:09,900
+تاو اكس وايقصاين تربيه فاي يعني
+
+254
+00:34:09,900 --> 00:34:13,580
+حسينا
+
+255
+00:34:13,580 --> 00:34:18,300
+اندي minus tao او قليني اقسم على minus يعني انا
+
+256
+00:34:18,300 --> 00:34:24,160
+حاسس ان ال tao بتساوي
+
+257
+00:34:24,160 --> 00:34:29,640
+minus sigma ارمص
+
+258
+00:34:32,010 --> 00:34:46,430
+Sigma X Sine 2 Phi زائد نص Sigma Y Sine 2 Phi
+
+259
+00:34:46,430 --> 00:34:51,150
+minus
+
+260
+00:34:51,150 --> 00:34:58,510
+Tau XY في
+
+261
+00:34:58,510 --> 00:35:10,910
+Cos تربيعفاي ماينس ساين تربيه فاي صح يعني
+
+262
+00:35:10,910 --> 00:35:15,150
+حسينا اندي التاو بدي
+
+263
+00:35:15,150 --> 00:35:23,730
+اخد ماينس عام مشترك هتكون سيجما اكس ماينس سيجما
+
+264
+00:35:23,730 --> 00:35:32,940
+واي على اتنين ساين two في خد بين هد و هدminus tau
+
+265
+00:35:32,940 --> 00:35:39,480
+xy في
+
+266
+00:35:39,480 --> 00:35:48,680
+ال cosine تربية في نص في
+
+267
+00:35:48,680 --> 00:35:57,700
+واحد زائد cosine two في ناقص نص
+
+268
+00:35:59,850 --> 00:36:11,150
+في واحد minus cosine two five هذا
+
+269
+00:36:11,150 --> 00:36:18,530
+ال term هيروح الواحد مع الواحد صح ما هو نعرف ان
+
+270
+00:36:18,530 --> 00:36:22,830
+انت عندك نص cosine مع نص cosine ايش هو الساوية
+
+271
+00:36:31,010 --> 00:36:42,270
+Tau XY Cos Sigma X minus Sigma Y على 2 Sine 2 Phi
+
+272
+00:36:42,270 --> 00:36:49,430
+زائد Tau XY فيه إشارة غلط راجعها زائد Tau XY فيه
+
+273
+00:36:49,430 --> 00:36:58,210
+Cos 2 Phiهذه المعادلة رجعها براحتك خلاص انت لحالك
+
+274
+00:36:58,210 --> 00:37:03,470
+تدور عليها و صليحها طيب معناته ان المعادلة sigma
+
+275
+00:37:03,470 --> 00:37:06,310
+ازاى sigma y على اتنين زى sigma x minus sigma y
+
+276
+00:37:06,310 --> 00:37:09,470
+على اتنين cosine two phi زى تاو اكس في سين تو في و
+
+277
+00:37:09,470 --> 00:37:16,930
+التاو وشيري stress at any angle في مطلق minus
+
+278
+00:37:16,930 --> 00:37:19,370
+sigma x minus sigma y على اتنين sin two phi زى تاو
+
+279
+00:37:19,370 --> 00:37:22,390
+اكس في cosine two phi اه
+
+280
+00:37:32,160 --> 00:37:46,460
+أه ماشي لما
+
+281
+00:37:46,460 --> 00:37:50,560
+تعرفنا علاقة بين sigma و tau at any planewith
+
+282
+00:37:50,560 --> 00:37:55,580
+respect to sigma x و sigma y و tau x و tau xy و
+
+283
+00:37:55,580 --> 00:37:59,220
+phi الان
+
+284
+00:37:59,220 --> 00:38:02,760
+بدى احسب ال principle stresses يعني متى ال normal
+
+285
+00:38:02,760 --> 00:38:06,920
+stresses بيكونوا maximum for sigma to be maximum
+
+286
+00:38:06,920 --> 00:38:09,900
+لازم يكون ال first derivative with respect of y
+
+287
+00:38:09,900 --> 00:38:16,880
+ايه شو ساوي؟ zero يعني لو حسبت حكيت d sigma على d
+
+288
+00:38:16,880 --> 00:38:24,690
+phi و سويتها للصفرهيكون هذا سفر صح لأنه ماعملش
+
+289
+00:38:24,690 --> 00:38:36,390
+تفاق بالنسبة لفاي minus سفر minus اتنين في sigma x
+
+290
+00:38:36,390 --> 00:38:45,770
+minus sigma y على اتنين sine two five زائد اتنين
+
+291
+00:38:45,770 --> 00:38:48,310
+tau xy
+
+292
+00:38:53,560 --> 00:39:02,620
+معناته هكون عندى sigma x minus sigma y sin 2 phi
+
+293
+00:39:02,620 --> 00:39:16,990
+هتساوي اتنين tau x cosine 2 phiأكسل طرفين على
+
+294
+00:39:16,990 --> 00:39:22,390
+كوسين فايف بيساندي تان توفاى
+
+295
+00:39:22,390 --> 00:39:36,210
+تان توفاى بتساوي اتنين تاو اكس واي على سيجما اكس
+
+296
+00:39:36,210 --> 00:39:39,650
+minus سيجما واي at this angle
+
+297
+00:39:42,510 --> 00:39:47,570
+بيكون ال normal stress maximum normal stress بيكون
+
+298
+00:39:47,570 --> 00:39:52,970
+maximum اللي
+
+299
+00:39:52,970 --> 00:39:56,790
+هي هذه المعدلة اللي انا عشان احسب ال principal
+
+300
+00:39:56,790 --> 00:40:05,150
+stresses هاوض هاوض بالزاوية هذه انا هاي تان فاية
+
+301
+00:40:05,150 --> 00:40:12,240
+عند هاي الزاوية فاية نعتبر هذه فاية كأنها فايةهي
+
+302
+00:40:12,240 --> 00:40:18,980
+عندى اتنين تاو XY او ممكن اعتبرها بالصيغة هذى تاو
+
+303
+00:40:18,980 --> 00:40:24,360
+XY على
+
+304
+00:40:24,360 --> 00:40:31,080
+اتنين زى هك بيصير نفس الاشي التان مقابل على مجول
+
+305
+00:40:31,080 --> 00:40:36,800
+هي عندهين Sigma X minus Sigma Y على اتنين معناته
+
+306
+00:40:36,800 --> 00:40:40,620
+هذا الضلعش هكون ساوى جزر التربيع
+
+307
+00:40:45,690 --> 00:40:52,310
+لأحنا لغناه صح؟ هتكون جزر التربيه ل sigma x minus
+
+308
+00:40:52,310 --> 00:41:00,170
+sigma y على 2 لكل تربيه زي ال tau xy تربيه يعني
+
+309
+00:41:00,170 --> 00:41:03,890
+لأن ال sigma بدنا نحصل على ال sigma principle هعوض
+
+310
+00:41:03,890 --> 00:41:10,790
+عن فعل انا هتسيب عن دي ال sigma بتساوي sigma x زي
+
+311
+00:41:10,790 --> 00:41:13,290
+sigma y على 2
+
+312
+00:41:18,430 --> 00:41:29,350
+زاد sigma x هذا طبعا اتنين فيا زائد sigma x minus
+
+313
+00:41:29,350 --> 00:41:38,430
+sigma y على اتنين في ال cosine اللي هي عبارة عن
+
+314
+00:41:38,430 --> 00:41:47,120
+sigma x minus sigma y على اتنينوالجدر اللي هو ال
+
+315
+00:41:47,120 --> 00:41:55,860
+water بحتي الجدر معروف انه جواها هذا الكلام انا
+
+316
+00:41:55,860 --> 00:42:01,140
+بعوض هناك زاد tau
+
+317
+00:42:01,140 --> 00:42:05,500
+xy sin
+
+318
+00:42:05,500 --> 00:42:11,000
+2 phi اللي عبارة عن tau xy
+
+319
+00:42:15,310 --> 00:42:27,250
+على الجدر طيب
+
+320
+00:42:27,250 --> 00:42:32,470
+بعمله لأن صار معروف كل ال mathematical test موجود
+
+321
+00:42:32,470 --> 00:42:34,910
+عندكوا المعناه اللي حكيت فيها اعملها
+
+322
+00:42:34,910 --> 00:42:37,630
+simplification تيجي ده تعملها simplification لأن
+
+323
+00:42:37,630 --> 00:42:38,150
+simplify
+
+324
+00:42:44,990 --> 00:42:52,990
+بيعطينا المعادلة هذه ال principle stresses اللي هي
+
+325
+00:42:52,990 --> 00:42:55,970
+عند ال two principle stresses sigma one and sigma
+
+326
+00:42:55,970 --> 00:42:58,850
+two sigma one يعني sigma x زي sigma one على اتنين
+
+327
+00:42:58,850 --> 00:43:01,070
+زي او ناقص sigma x وانا sigma one على اتنين الكل
+
+328
+00:43:01,070 --> 00:43:06,360
+تربيع زي ال tau xy تربيعواضح انه هيطلع عندنا جدر
+
+329
+00:43:06,360 --> 00:43:10,980
+الجدر اللي هو هذا في المعادلة هذول هو ال principle
+
+330
+00:43:10,980 --> 00:43:18,600
+stresses الآن خلينا نشوف قيمة الشير stress لما
+
+331
+00:43:18,600 --> 00:43:22,600
+نكون ال stress principle ايش عن ال principle يعني
+
+332
+00:43:22,600 --> 00:43:29,380
+ال normal stress بيكون ايش maximum عند ال tau اللي
+
+333
+00:43:29,380 --> 00:43:34,220
+هو at maximum normal
+
+334
+00:43:36,380 --> 00:43:43,100
+stress بتكون عندي tan
+
+335
+00:43:43,100 --> 00:43:53,900
+phi بتساوي tau xy على sigma x minus sigma y على
+
+336
+00:43:53,900 --> 00:43:57,000
+اتنين صح؟ tan اتنين phi
+
+337
+00:44:05,340 --> 00:44:14,860
+عوض عن تاو هتكون minus sigma x minus sigma y على
+
+338
+00:44:14,860 --> 00:44:23,760
+اتنين في sine two phi اللي هي عبارة عن تاو xy على
+
+339
+00:44:23,760 --> 00:44:27,200
+الجدار صح؟
+
+340
+00:44:27,200 --> 00:44:30,680
+هي ال sign مقابل الوطن هي المقابل
+
+341
+00:44:33,980 --> 00:44:42,060
+زائد tau xy cosine
+
+342
+00:44:42,060 --> 00:44:49,900
+two phi عبارة عن sigma x minus sigma y على اتنين
+
+343
+00:44:49,900 --> 00:44:57,400
+على جدر صح؟ لاحظوا هذا بيساوي هذا واحد موجة واحد
+
+344
+00:44:57,400 --> 00:45:00,280
+ثالث بلغوا بعض صح؟
+
+345
+00:45:03,630 --> 00:45:08,830
+معناته at the plains where the normal stresses are
+
+346
+00:45:08,830 --> 00:45:12,650
+maximum، بيكونش عندنا شيري، بيكون الشيري شو ساوية؟
+
+347
+00:45:12,650 --> 00:45:19,170
+zero معناته and zero shear stresses at the
+
+348
+00:45:19,170 --> 00:45:24,770
+principal surface معناته
+
+349
+00:45:24,770 --> 00:45:28,910
+فقط بيكون عند .. and the principal plains، بيكون
+
+350
+00:45:28,910 --> 00:45:31,810
+فقط principal normal stresses، no shear stress
+
+351
+00:45:41,860 --> 00:45:49,560
+الكو ساين هى انا بحكي كو ساين تو فاى الكو ساين
+
+352
+00:45:49,560 --> 00:45:56,720
+مجاور على وطر هى
+
+353
+00:45:56,720 --> 00:46:04,520
+انا بعطيك هى عندك تو فاى ال تو فاى بتساوي هى تاو
+
+354
+00:46:04,520 --> 00:46:09,450
+اكس واى هذا for any angleهذه المقابل على المجاور
+
+355
+00:46:09,450 --> 00:46:13,410
+على sigma x الوطر
+
+356
+00:46:13,410 --> 00:46:20,450
+ايه حاكم قيمة في الحلقة هذه جدر التربية يعني ف ال
+
+357
+00:46:20,450 --> 00:46:25,030
+sign هذا جدر التربية على الوطر و ال cosine المجاور
+
+358
+00:46:25,030 --> 00:46:28,910
+على الوطر انا بلو مرسوم من بين عندي هذا المقابل
+
+359
+00:46:28,910 --> 00:46:34,630
+هذا المجاور يعني مقابل ال sign مقابل على جدر و
+
+360
+00:46:34,630 --> 00:46:43,500
+cosineمجاور على جدر واضح؟ لأ انا فاهم انا فاهم انا
+
+361
+00:46:43,500 --> 00:46:46,440
+اللي كيف اللي قلت اللي اتعجبني فالقانون مش تان
+
+362
+00:46:46,440 --> 00:46:52,340
+توفاي توفاي اه يسوي الشيء اللي هو .. انا اشتقتلك
+
+363
+00:46:52,340 --> 00:46:56,280
+اياها انا .. انا حكيتلك بيكون هذا ال stress بشكل
+
+364
+00:46:56,280 --> 00:47:02,120
+عام on ال plane لكن عندي one specific plane ال
+
+365
+00:47:02,120 --> 00:47:05,710
+maximum بيكون عندي ال stress maximumfor discipline
+
+366
+00:47:05,710 --> 00:47:11,550
+انا بحكي تغير sigma ماعياش مع الفاية a discipline
+
+367
+00:47:11,550 --> 00:47:14,550
+where the normal stress is maximum بيكون ال
+
+368
+00:47:14,550 --> 00:47:16,330
+derivative لل sigma بالنسبة لو فاية بيستوى زيرو
+
+369
+00:47:16,330 --> 00:47:19,410
+يعني انا اشتقتها بالنسبة دي sigma بقى دي فاية
+
+370
+00:47:19,410 --> 00:47:23,270
+سويتها لزيرو و طلعت تطلع عند ال 10 to 5 اللي هي
+
+371
+00:47:23,270 --> 00:47:26,010
+سوى تو اكس واي على سجن اكس واحد ناسم واي على اتنين
+
+372
+00:47:26,010 --> 00:47:27,490
+من هنا اجت
+
+373
+00:47:38,560 --> 00:47:41,760
+طيب ال shear stress بيكون maximum هذا برضه ممكن
+
+374
+00:47:41,760 --> 00:47:48,240
+تثبتوها نرجع
+
+375
+00:47:48,240 --> 00:47:54,040
+للمعادلة يعني
+
+376
+00:47:54,040 --> 00:48:03,520
+ال D Tau 100% D Tau by D Phi بتساوي
+
+377
+00:48:06,060 --> 00:48:12,960
+minus sigma x minus sigma y في
+
+378
+00:48:12,960 --> 00:48:19,300
+cosine two phi minus
+
+379
+00:48:19,300 --> 00:48:31,420
+اتنين tau xy sin two phi سواء او زير عشان اجد ال
+
+380
+00:48:31,420 --> 00:48:33,820
+maximum ال plane اللي بيكون علشان ال stress
+
+381
+00:48:33,820 --> 00:48:41,850
+maximumيعني انا هكون عندى اتنين تاو اكس واي صين
+
+382
+00:48:41,850 --> 00:48:51,110
+توفاى بسوى ماينوس سيجما اكس ماينوس سيجما واي كوسين
+
+383
+00:48:51,110 --> 00:49:00,950
+توفاى يعني انا هكون عندى تان توفاى هتكون تسوى
+
+384
+00:49:00,950 --> 00:49:06,790
+ماينوستاو minus
+
+385
+00:49:06,790 --> 00:49:17,750
+cosine minus sigma x minus sigma y على اتنين تاو
+
+386
+00:49:17,750 --> 00:49:24,270
+اكس واي هذا
+
+387
+00:49:24,270 --> 00:49:25,470
+بتاعة ال share stress
+
+388
+00:49:28,140 --> 00:49:35,240
+يعني ال turn ده متمثل إيه؟ slope صح؟ ال turn to
+
+389
+00:49:35,240 --> 00:49:40,820
+phi بتاعة ال principle stress بتاعة ال stress كانت
+
+390
+00:49:40,820 --> 00:49:47,540
+سواء اتنين tau xy على sigma x minus sigma y صح؟
+
+391
+00:49:47,540 --> 00:49:55,790
+اضره هدي في هدي هكون ده turnالـ two phi بتاعة ال
+
+392
+00:49:55,790 --> 00:50:03,650
+shear بتختلف في تان ال two phi بتاعة ال stress سوى
+
+393
+00:50:03,650 --> 00:50:11,170
+minus واحد معناته ال two phi angle بتاعة ال shear
+
+394
+00:50:11,170 --> 00:50:18,270
+stress متعمدة مع ال two phi angle بتاعة ال normal
+
+395
+00:50:18,270 --> 00:50:22,970
+stressلأنه اذا يكون حاصل multiplication لتو slopes
+
+396
+00:50:22,970 --> 00:50:27,450
+الساوي السالب معناته متعاملين معناته ازاق بين ..
+
+397
+00:50:27,450 --> 00:50:30,170
+بين .. بين two phi و two phi تسعين درجة معناته مع
+
+398
+00:50:30,170 --> 00:50:33,310
+phi و phi أكم؟ خمسة و أربعين خمسة و أربعين لإن
+
+399
+00:50:33,310 --> 00:50:40,050
+هتقسم مع اتنين معناته ال angle between
+
+400
+00:50:40,050 --> 00:50:44,910
+principle
+
+401
+00:50:48,910 --> 00:51:01,190
+principle plane planes and planes of maximum shear
+
+402
+00:51:01,190 --> 00:51:14,570
+is plus or minus خمس و أربعين دولار اللي
+
+403
+00:51:14,570 --> 00:51:15,210
+هي هات الجملة
+
+404
+00:51:23,040 --> 00:51:26,660
+اذا عوّضت عن الزاوية هذه اللي هي tan two phi بتاعة
+
+405
+00:51:26,660 --> 00:51:29,260
+ال share stress بالسبب أنا sigma x minus sigma y
+
+406
+00:51:29,260 --> 00:51:32,980
+على اتنين تاو x عوضت في معدلة ات تاو بيطلع ال
+
+407
+00:51:32,980 --> 00:51:36,600
+maximum share stress تاو احد تاو اتنين plus or
+
+408
+00:51:36,600 --> 00:51:39,560
+minus sigma x minus sigma y على اتنين لكل تربيع
+
+409
+00:51:39,560 --> 00:51:45,100
+زاو تاو xy تربيع واضح؟
+
+410
+00:51:45,100 --> 00:51:49,000
+هنروح على more circle
+
+411
+00:51:58,250 --> 00:52:02,830
+تطلع المعادلة هذه و تطلع فيها كويس تكتشف انها
+
+412
+00:52:02,830 --> 00:52:09,330
+تنتهي مع بعض بمثل معادلة دائرة هدول مع بعض معادلة
+
+413
+00:52:09,330 --> 00:52:13,310
+دائرة كيف؟ لو أخدت ال sigma أو المعادلة حكيت sigma
+
+414
+00:52:13,310 --> 00:52:19,650
+minus خليني
+
+415
+00:52:19,650 --> 00:52:24,350
+أسمي let
+
+416
+00:52:26,430 --> 00:52:35,550
+C سواء Sigma X زي Sigma Y على اتنين يعني هاد
+
+417
+00:52:35,550 --> 00:52:44,030
+أسميها C حسين دي Sigma minus C بسوء
+
+418
+00:52:44,030 --> 00:52:56,010
+Sigma X minus Sigma Y على اتنين Cos 2 Phiزاد تاو
+
+419
+00:52:56,010 --> 00:53:04,290
+اكس واي صين تو في والمعادلة التانية تاو بستوي
+
+420
+00:53:04,290 --> 00:53:13,790
+سيجما اكس minus سيجما واي على اتنين صين two في زاد
+
+421
+00:53:13,790 --> 00:53:19,790
+تاو اكس واي cosine two في خلينا نسمي هذه معادلة
+
+422
+00:53:19,790 --> 00:53:23,490
+تلاتة هذه معادلة ايش اربع
+
+423
+00:53:27,800 --> 00:53:32,980
+طاوب الساوي السالبي طاوب
+
+424
+00:53:32,980 --> 00:53:39,360
+الساوي السالبي صحيح هنا هيك صحيح انا بحكي هحكي
+
+425
+00:53:39,360 --> 00:53:45,700
+تلاتة square ربع المعتلة زائد اربعة square اجمعهم
+
+426
+00:53:45,700 --> 00:53:49,080
+اجمع الشمال مع الشمال و اللي يبقى على اليمين هتكون
+
+427
+00:53:49,080 --> 00:53:55,760
+هذه ال sigma minus c لكل تربيع زائد تاو تربيع
+
+428
+00:53:59,560 --> 00:54:04,760
+زاية تاو تربيع هتكون تساوي هذه تربيع زاية هذه
+
+429
+00:54:04,760 --> 00:54:09,140
+تربيع شوية طينة نفس هيكون cosine تربيع زاية sin
+
+430
+00:54:09,140 --> 00:54:15,860
+تربيع واحد هيكون سيجما X minus sigma Y على اتنين
+
+431
+00:54:15,860 --> 00:54:23,000
+لكل تربيع وهذه sin تربيع مع cosine تربيع زاية تاو
+
+432
+00:54:23,000 --> 00:54:24,040
+XY تربيع
+
+433
+00:54:27,960 --> 00:54:32,340
+زائد اتنين هذا في هذا زائد اتنين هذا في هذا يعني
+
+434
+00:54:32,340 --> 00:54:37,280
+لو نقضي احكي احد اي حاجة it will cancel out لان
+
+435
+00:54:37,280 --> 00:54:43,760
+هنا سالب وهنا موجب هيك خلصنا وانته معادلة دائرة
+
+436
+00:54:43,760 --> 00:54:55,500
+بشكل عام هي اي دائرة هي X Y هي دائرة هي مركزها لو
+
+437
+00:54:55,500 --> 00:55:05,490
+حكيت هذه Hوها دي إيش K الدقرة
+
+438
+00:55:05,490 --> 00:55:10,630
+اللي جاي في المركز بالظبط إيش معدلتها X تربية زاد
+
+439
+00:55:10,630 --> 00:55:18,530
+Y تربية سواء R تربية الآن المركز المعادلة الدقرة
+
+440
+00:55:18,530 --> 00:55:28,350
+هتكون X minus H لكل تربيةزائد y minus k كل تربيع
+
+441
+00:55:28,350 --> 00:55:33,670
+سواء r تربيع معناته
+
+442
+00:55:33,670 --> 00:55:42,250
+هذه معادلة هذول ال terms هسميها يعني هكون sigma
+
+443
+00:55:42,250 --> 00:55:51,170
+minus c لكل تربيع بتساوي r capital تربيع زائد tau
+
+444
+00:55:51,170 --> 00:55:59,690
+تربيعSigma minus C كل تربيه زائد تاو تربيه So R
+
+445
+00:55:59,690 --> 00:56:09,850
+capital تربيه هذا معامل الدائرة مركزها جاي لو عملت
+
+446
+00:56:09,850 --> 00:56:13,650
+plot Sigma مع تاو Sigma مع تاو مركز جاي على ال X
+
+447
+00:56:13,650 --> 00:56:21,010
+axis يعني عندي هي عندي Sigma مع تاو هي ال C
+
+448
+00:56:24,700 --> 00:56:34,520
+وهاي الدائرة وها دي ايش ال R بتاعتها ال R بتاعتها
+
+449
+00:56:34,520 --> 00:56:39,780
+من
+
+450
+00:56:39,780 --> 00:56:50,780
+هنا جت ايش more circle هد هي more circle
+
+451
+00:56:54,590 --> 00:57:02,090
+North circle is a plot of shear stress versus
+
+452
+00:57:02,090 --> 00:57:07,330
+normal stress ال plot هذا يعني plot هذا ال
+
+453
+00:57:07,330 --> 00:57:14,570
+equation مع هذا ال equation بيعطينا دائرة مركزها
+
+454
+00:57:14,570 --> 00:57:21,610
+مواقع على محور ال sigma و يبعد C ال C كما احنا
+
+455
+00:57:21,610 --> 00:57:30,440
+حكيناسيجما اكس زي سيجما واي على اتنين انا
+
+456
+00:57:30,440 --> 00:57:34,460
+اتوم more circle هاي
+
+457
+00:57:34,460 --> 00:57:40,020
+more circle هاي ال sigma هاي ال tau لو كنا نرسم
+
+458
+00:57:40,020 --> 00:57:44,680
+more circle كنا نعرف ال tau هاد مثلا هاد ال tau مع
+
+459
+00:57:44,680 --> 00:57:46,940
+ال x axis counter clockwise كنا نعرف ال counter
+
+460
+00:57:46,940 --> 00:57:52,320
+clockwise موجة يعني هد يقول بيعملوا ايش؟بيعملوا
+
+461
+00:57:52,320 --> 00:57:59,540
+ازدواج موجب عندي هنا تاو counter clockwise و هنا
+
+462
+00:57:59,540 --> 00:58:06,220
+تاو clockwise طيب
+
+463
+00:58:06,220 --> 00:58:13,460
+نيجي ل more circle هخلي
+
+464
+00:58:13,460 --> 00:58:17,920
+المعادة لأنا عشان تعرفوا كيف أجت
+
+465
+00:58:24,170 --> 00:58:32,310
+الاشة عند ال C سوى Sigma X زي Sigma Y على اتنين
+
+466
+00:58:32,310 --> 00:58:39,390
+عند ال R بسوى جزر التربيع ل Sigma X minus Sigma Y
+
+467
+00:58:39,390 --> 00:58:45,930
+على اتنين لكل تربيع زي تاو XY تربيع
+
+468
+00:58:53,100 --> 00:58:59,560
+هي مورسيكا لان عندي محورين محور السيجما محور التاو
+
+469
+00:58:59,560 --> 00:59:07,800
+عندي هنا تاو clockwise وهنا تاو counter clockwise
+
+470
+00:59:07,800 --> 00:59:14,360
+عندي stress element sigma
+
+471
+00:59:14,360 --> 00:59:14,820
+x
+
+472
+00:59:22,190 --> 00:59:27,510
+و tau xy وعندي
+
+473
+00:59:27,510 --> 00:59:33,170
+sigma y على
+
+474
+00:59:33,170 --> 00:59:37,590
+المستوى هذا فاندي sigma x و tau xy counter
+
+475
+00:59:37,590 --> 00:59:41,630
+clockwise tau xy جاي counter clockwise مع sigma x
+
+476
+00:59:41,630 --> 00:59:50,370
+فحروح اعمل اخد اول نقطة هذه هذه
+
+477
+00:59:50,370 --> 00:59:51,010
+عبارة عن ايه
+
+478
+00:59:54,760 --> 01:00:06,060
+سيجما اكس سيجما
+
+479
+01:00:06,060 --> 01:00:15,780
+اكس وهذه المسافة تاو اكس
+
+480
+01:00:15,780 --> 01:00:16,160
+واي
+
+481
+01:00:20,430 --> 01:00:28,930
+ع المستوى هذا عندي sigma y و tau xy clockwise هكون
+
+482
+01:00:28,930 --> 01:00:41,710
+عندي هي sigma y و
+
+483
+01:00:41,710 --> 01:00:44,230
+هي tau xy
+
+484
+01:00:57,760 --> 01:01:03,700
+هذه sigma y وهذه
+
+485
+01:01:03,700 --> 01:01:08,780
+sigma x فهذه المسافة كم الفرق بينهم sigma x minus
+
+486
+01:01:08,780 --> 01:01:15,920
+sigma y مص
+
+487
+01:01:15,920 --> 01:01:16,820
+المسافة هذه
+
+488
+01:01:23,880 --> 01:01:29,300
+اللي هي sigma x minus sigma y على اتنين صح مش
+
+489
+01:01:29,300 --> 01:01:32,640
+عايزة sigma x تنقص sigma y مصها هكون sigma x minus
+
+490
+01:01:32,640 --> 01:01:37,180
+sigma y على اتنين لأن المص هذا لو اجبع مع sigma y
+
+491
+01:01:37,180 --> 01:01:44,160
+يعني sigma x minus sigma y على اتنين زي sigma y
+
+492
+01:01:44,160 --> 01:01:49,260
+sigma y عبارة عن اتنين sigma y عاتنين صح يعني
+
+493
+01:01:49,260 --> 01:01:55,920
+اتنين يعني هكون عندى اتنينسيجما اكس ماينس سيجما
+
+494
+01:01:55,920 --> 01:02:01,940
+واي زائد اتنين سيجما واي يعني هصف ايش سيجما اكس
+
+495
+01:02:01,940 --> 01:02:09,940
+زائد سيجما واي على اتنين معناته هذه النقطة هتكون
+
+496
+01:02:09,940 --> 01:02:18,860
+سيجما اكس زائد سيجما واي على اتنين اللي هو ايش ده
+
+497
+01:02:18,860 --> 01:02:22,580
+ال center تعمر circle هذا ال center
+
+498
+01:02:27,070 --> 01:02:31,810
+طيب احنا حاولين نحكي ان هذه الـ tau xy و هذه
+
+499
+01:02:31,810 --> 01:02:36,890
+المسافة sigma x و sigma x minus sigma y هذه
+
+500
+01:02:36,890 --> 01:02:40,790
+المسافة معناه تقول اخدت المثلث القائم الزوايا هذا
+
+501
+01:02:40,790 --> 01:02:47,510
+الطول ايش حيكون هذا جد التربيع لهذه التربيع زي هذه
+
+502
+01:02:47,510 --> 01:02:52,110
+التربيع اللي هي هذا هتكون اللي هي R
+
+503
+01:03:18,620 --> 01:03:25,560
+النقطة التانية هي نقطة A وهي نقطة B A بتمثل
+
+504
+01:03:25,560 --> 01:03:26,360
+المستوى هذا
+
+505
+01:03:29,190 --> 01:03:33,850
+و B المستوى هذا الذهب بين المستوى هذا و المستوى
+
+506
+01:03:33,850 --> 01:03:40,410
+هذا فى أرض الواقع تسعين لك انا بتعامل مع two five
+
+507
+01:03:40,410 --> 01:03:46,610
+تسعين الذهب بينهم ايش مية و تين درجة يعنى هذه تمثل
+
+508
+01:03:46,610 --> 01:03:56,130
+ال X axis وهذه ال Y axis وهذه الذهب بينهم مية و
+
+509
+01:03:56,130 --> 01:03:58,330
+تين درجة اللى هى two five واضح
+
+510
+01:04:11,920 --> 01:04:15,560
+احنا حكينا ال principal stresses او ال stress
+
+511
+01:04:15,560 --> 01:04:23,260
+بيكون principal لما ال share stress بيكون ساوي صفر
+
+512
+01:04:23,260 --> 01:04:28,160
+معناته هذه مثل
+
+513
+01:04:28,160 --> 01:04:32,780
+sigma one one principal stress و هذه sigma two
+
+514
+01:04:32,780 --> 01:04:35,980
+another principal stress ليش عند النقطة هذه share
+
+515
+01:04:35,980 --> 01:04:43,180
+stress بيساوي share stress zero مظلوطالشير ال
+
+516
+01:04:43,180 --> 01:04:55,100
+stress بيكون زاوية zero طيب
+
+517
+01:04:55,100 --> 01:05:00,760
+واضح
+
+518
+01:05:00,760 --> 01:05:07,360
+ان sigma one بيساوي ال center زاد ال radius صح؟
+
+519
+01:05:07,360 --> 01:05:16,460
+sigma oneبستوى ال center زائد ال radius و ال sigma
+
+520
+01:05:16,460 --> 01:05:25,220
+two بستوى ال center ناقص ال radius sigma two بستوى
+
+521
+01:05:25,220 --> 01:05:28,820
+ال center minus ال radius و ال center احنا we
+
+522
+01:05:28,820 --> 01:05:34,440
+defined اللي هو sigma x زائد sigma y على اتنينو ال
+
+523
+01:05:34,440 --> 01:05:38,960
+radius اللي هو square root ل sigma x minus sigma y
+
+524
+01:05:38,960 --> 01:05:49,200
+على 2 الكل تربيع زي ال tau xy تربيع طيب
+
+525
+01:05:49,200 --> 01:05:54,280
+ال phi b او الزاوية اللي بتعرفلي ال principle
+
+526
+01:05:54,280 --> 01:05:59,840
+plane هاي ال x axis مش هذا principle معناته
+
+527
+01:05:59,840 --> 01:06:06,440
+principle stress اههذا stress لل stress اه هذا لل
+
+528
+01:06:06,440 --> 01:06:12,940
+normal stress هذه الزرعه هتكون اللي هي اتنين فاي
+
+529
+01:06:12,940 --> 01:06:23,780
+principle لاحظوا ten ten طلعهين اتنين ten
+
+530
+01:06:23,780 --> 01:06:29,960
+اتنين في بي هيها هذه في بي هذه
+
+531
+01:06:32,690 --> 01:06:41,250
+بالساوة هادى المسافة اللى هى ash tau xy على
+
+532
+01:06:41,250 --> 01:06:48,110
+هادى اللى هى sigma x minus sigma y على
+
+533
+01:06:48,110 --> 01:06:53,570
+اتنين مظموط كلام صح طيب
+
+534
+01:06:53,570 --> 01:06:58,310
+معناته
+
+535
+01:06:58,310 --> 01:07:02,980
+فى الحالة هادى عشان object of principle stressبدي
+
+536
+01:07:02,980 --> 01:07:07,860
+من ال positive x axis أدور بزاوية في بي يعني إذا
+
+537
+01:07:07,860 --> 01:07:13,900
+هذا هو ال positive x axis إذا هذا هو ال positive x
+
+538
+01:07:13,900 --> 01:07:18,680
+axis بدي
+
+539
+01:07:18,680 --> 01:07:24,460
+أدور بزاوية في
+
+540
+01:07:24,460 --> 01:07:37,790
+بي و أرسم elementهذا سيكون عليه سجم واحد وهذا
+
+541
+01:07:37,790 --> 01:07:46,370
+سجم واحد وهذا
+
+542
+01:07:46,370 --> 01:07:51,690
+سجم اتنين لأن الزرع بين سجم واحد وهذا سجم واحد
+
+543
+01:07:51,690 --> 01:07:55,690
+وهذا سجم اتنين يعني الزرع بينهم 180 درجة معناته
+
+544
+01:07:55,690 --> 01:08:05,610
+سيكون سجم اتنين متعمد عليهفى ششير طبعا فى ششير فاي
+
+545
+01:08:05,610 --> 01:08:09,230
+بى و لا اتنين فاي بى يا دكتور؟ انا هى اتنين فاي بى
+
+546
+01:08:09,230 --> 01:08:12,230
+لكن لما ارسم ال stress element اللى عنده ال normal
+
+547
+01:08:12,230 --> 01:08:17,790
+stresses اللى بتكون maximum برسم فاي بى بحسب ال
+
+548
+01:08:17,790 --> 01:08:19,970
+two فاي بى بعدين منها بحسب الفاي بى
+
+549
+01:08:25,380 --> 01:08:29,880
+عشان اعرف هذه النقطة هتكون sigma x و tau xy
+
+550
+01:08:29,880 --> 01:08:37,820
+counter clockwise وهذه sigma y و tau xy clockwise
+
+551
+01:08:37,820 --> 01:08:44,980
+واضحت
+
+552
+01:08:44,980 --> 01:08:49,540
+ايش هي more circle؟هذا مهم كتير انا عشان ايك فصلت
+
+553
+01:08:49,540 --> 01:08:55,700
+فيه لإنه بدى تكون فاهم ماتتعاملش مع ال circle بس
+
+554
+01:08:55,700 --> 01:09:00,080
+اعمل كذا ورسوم كذا وكذا تاوة تنساها تعرف الأساس
+
+555
+01:09:00,080 --> 01:09:03,440
+تاعها فانت كيف تنظر ال counter هناك clockwise؟
+
+556
+01:09:03,440 --> 01:09:08,420
+ليش؟ ال definition .. ال definition تاع ال shear
+
+557
+01:09:08,420 --> 01:09:14,100
+stress ال definition تعنى shear stress بعتبر لتحت
+
+558
+01:09:14,100 --> 01:09:21,220
+counter clockwiseو لعنة clockwise واضح يعني بعتبر
+
+559
+01:09:21,220 --> 01:09:25,200
+counter clockwise شير استرس لتحت counter clockwise
+
+560
+01:09:25,200 --> 01:09:30,040
+negative clockwise إيش positive هذا شير استرس لكن
+
+561
+01:09:30,040 --> 01:09:37,060
+angles أنا I'm rotating rotating
+
+562
+01:09:37,060 --> 01:09:41,480
+أكم تسعين درجة يعني أنا مثلا هاندي هاي ال X axis
+
+563
+01:09:41,480 --> 01:09:51,590
+هاي المستوى هذاإذا لفيت ال X Axis تسعين درجة بعكس
+
+564
+01:09:51,590 --> 01:09:56,430
+عقار بالسياقة بيعطينا المستويه ده اللي مبين عندي
+
+565
+01:09:56,430 --> 01:10:04,250
+هي نقاش مية و تمانين درجة أضحك؟ فانا بلف صح عشان
+
+566
+01:10:04,250 --> 01:10:08,490
+أوصل ال X Axis لفيت تسعين درجة عشان أوصل ال
+
+567
+01:10:08,490 --> 01:10:11,670
+principle معناته أنا لفيت زي هيك هذه مثلات
+
+568
+01:10:11,670 --> 01:10:28,440
+positive تسعينلفت هك 25B counter clockwise نشوف
+
+569
+01:10:28,440 --> 01:10:28,940
+مثال
+
+570
+01:10:50,030 --> 01:10:58,450
+Find Stress Element علي
+
+571
+01:10:58,450 --> 01:11:07,750
+Normal Stress Sigma X Sigma
+
+572
+01:11:07,750 --> 01:11:13,150
+X بالساوة تمانين ميجا بسكال و هنا Clockwise
+
+573
+01:11:20,270 --> 01:11:27,210
+تاو XY بستوى خمسين ميجا بسكال using Mohr circle
+
+574
+01:11:27,210 --> 01:11:30,410
+find principal stresses and directions and show a
+
+575
+01:11:30,410 --> 01:11:32,870
+stress element correctly aligned with respect to
+
+576
+01:11:32,870 --> 01:11:43,950
+XY coordinates حرصوا ال Mohr circle عندي
+
+577
+01:11:43,950 --> 01:11:51,990
+هي sigma هي تاوعندي عصير فصيلة sigma x 80 هذي
+
+578
+01:11:51,990 --> 01:11:55,990
+clockwise ولا counter clockwise معناته التوحد كل
+
+579
+01:11:55,990 --> 01:12:04,540
+اعلى عشان خلنا نعمل تقسيمةهي عشرة عشرين تلاتين
+
+580
+01:12:04,540 --> 01:12:12,520
+اربعين خمسين ستين سبعين تمانين وعندي عشرة عشرين
+
+581
+01:12:12,520 --> 01:12:21,920
+تلاتين اربعين خمسين عشرة عشرين تلاتين اربعين خمسين
+
+582
+01:12:21,920 --> 01:12:22,620
+ستين
+
+583
+01:12:30,570 --> 01:12:36,670
+عندى المستوى هذا سيجم اكس تمانين واحد اتنين تلاتة
+
+584
+01:12:36,670 --> 01:12:43,670
+اربع خمس ستة سبعة وانية و ال tao clockwise هتكون
+
+585
+01:12:43,670 --> 01:12:50,930
+الاعلى خمسين خليني
+
+586
+01:12:50,930 --> 01:12:51,950
+امسح ال stress element
+
+587
+01:12:59,360 --> 01:13:06,040
+هذه النقطة النقطة التانية على المستوى هذا الـ
+
+588
+01:13:06,040 --> 01:13:14,240
+Sigma Y Zero هذه Zero مع خمسين لتحت هذه واحد،
+
+589
+01:13:14,240 --> 01:13:18,280
+اتنين، تلاتة، أربعة، خمسة هذه النقطة التانية لأن
+
+590
+01:13:18,280 --> 01:13:26,100
+مصل بينهم هذا
+
+591
+01:13:26,100 --> 01:13:32,960
+ال Centerطبعا واضح ال center هيكون سيجمه اكس زي
+
+592
+01:13:32,960 --> 01:13:41,100
+سيجمه ايه على اتنين اللي هو هيكون اربعين ميجا
+
+593
+01:13:41,100 --> 01:13:48,720
+بسكال هاي ال center هرسميه ال
+
+594
+01:13:48,720 --> 01:13:50,160
+more circle
+
+595
+01:13:57,530 --> 01:14:06,650
+هذا واضح ال x axis صح وهذا ال y axis هذا
+
+596
+01:14:06,650 --> 01:14:14,550
+ال x axis وهذا ال y axis هذا
+
+597
+01:14:14,550 --> 01:14:17,870
+tau
+
+598
+01:14:17,870 --> 01:14:29,020
+xy وهذا ايه sigma x minus sigma y على اتنينوهذه
+
+599
+01:14:29,020 --> 01:14:39,640
+two five P تان two five P بتساوية تاو X Y اللي هو
+
+600
+01:14:39,640 --> 01:14:45,100
+خمسين على
+
+601
+01:14:45,100 --> 01:14:51,000
+سيجما X minus سيجما Y على اتنين على اربعين صح وانا
+
+602
+01:14:51,000 --> 01:14:55,780
+بحسب two five P اسبوليها ايش تطلع حد اسبولي two
+
+603
+01:14:55,780 --> 01:14:56,480
+five P على السريع
+
+604
+01:15:13,410 --> 01:15:19,070
+الراديوس هيكون الجزر التربيعي ل سيجما X minus
+
+605
+01:15:19,070 --> 01:15:26,030
+سيجما Y على 2 لكل تربيع زي تو XY تربيع يعني هيكون
+
+606
+01:15:26,030 --> 01:15:34,470
+الجزر التربيعي ل 40 تربيع زي 50 تربيع
+
+607
+01:15:38,040 --> 01:15:41,240
+خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و
+
+608
+01:15:41,240 --> 01:15:43,740
+خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و
+
+609
+01:15:43,740 --> 01:15:46,520
+خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و
+
+610
+01:15:46,520 --> 01:15:51,360
+خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و
+
+611
+01:15:51,360 --> 01:15:51,360
+خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و
+
+612
+01:15:51,360 --> 01:15:57,160
+خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و خمسة و
+
+613
+01:15:57,160 --> 01:16:05,940
+خمسة و خمسة و خمسة
+
+614
+01:16:10,900 --> 01:16:16,760
+اربع ستين point ميجا
+
+615
+01:16:16,760 --> 01:16:24,140
+بسكال الان انا محتمش طالما ورجيتك الفاي بي
+
+616
+01:16:24,140 --> 01:16:28,680
+graphically الإشارات لاتعني شيء انا اسمه حتى انا
+
+617
+01:16:28,680 --> 01:16:33,760
+حاكي نيجاتيف ماشي انا بحكيلك هاي الفاي بي بتحكيلي
+
+618
+01:16:33,760 --> 01:16:38,160
+نيجاتيف الشوف
+
+619
+01:16:38,160 --> 01:16:45,140
+مش زي السماع صح؟بختلف فعندي ال 5P الان هاي ال X
+
+620
+01:16:45,140 --> 01:16:50,380
+الان هرسم ال stress element هاي
+
+621
+01:16:50,380 --> 01:16:54,520
+ال stress element تبعي انا همشي clockwise بالزاوية
+
+622
+01:16:54,520 --> 01:17:00,620
+25 درجة هاي ال X axis همشي
+
+623
+01:17:00,620 --> 01:17:06,800
+زاوية 25.65
+
+624
+01:17:06,800 --> 01:17:09,720
+degrees هرسم stress element
+
+625
+01:17:13,180 --> 01:17:22,100
+هنا سيجما واحد وهنا سيجما اتنين
+
+626
+01:17:22,100 --> 01:17:30,380
+الآن سيجما واحد في الساعة ال C زاد ال radius صح ال
+
+627
+01:17:30,380 --> 01:17:34,800
+C اللي هو اربعين زاد اربعة وستين point O تلاتة
+
+628
+01:17:34,800 --> 01:17:39,980
+يعني مية واربعة point O تلاتة هندي مية واربعة
+
+629
+01:17:39,980 --> 01:17:50,640
+point O تلاتةو ال sigma two هتكون ال
+
+630
+01:17:50,640 --> 01:17:57,860
+sigma two بالساوية C minus R ال C اللي هي اربعين
+
+631
+01:17:57,860 --> 01:18:04,180
+مينوس اربع ستين point O تلاتة هتكون مينوس اربع و
+
+632
+01:18:04,180 --> 01:18:11,640
+عشرين point O تلاتة صحيح ميجا بسكال يعني هتكون
+
+633
+01:18:11,640 --> 01:18:20,890
+compressionهتكون عندى compression سيجما
+
+634
+01:18:20,890 --> 01:18:26,610
+التول هي minus اربع عشرين point او تلاتة
+
+635
+01:18:26,610 --> 01:18:32,890
+ميجاباسكال هذا هو ال stress element اللى
+
+636
+01:18:32,890 --> 01:18:38,930
+بيكون عندى ال stress is principal وكنت احكي ال
+
+637
+01:18:38,930 --> 01:18:47,350
+maximum الشيء ال stressالتاو maximum بيساوي
+
+638
+01:18:47,350 --> 01:18:50,950
+ال
+
+639
+01:18:50,950 --> 01:18:55,090
+radius او
+
+640
+01:18:55,090 --> 01:19:03,270
+بيساوي السيجما واحد minus السيجما اتنين على اتنين
+
+641
+01:19:08,560 --> 01:19:16,540
+مية و اربعة point o تلاتة minus minus اربعة و
+
+642
+01:19:16,540 --> 01:19:26,800
+عشرين point o تلاتة على اتنين اكم اطلع اربعة و
+
+643
+01:19:26,800 --> 01:19:37,540
+ستين point o تلاتة ميجا بسكال هذا ال tau maxال tau
+
+644
+01:19:37,540 --> 01:19:45,700
+max بيعمل plus or minus plus
+
+645
+01:19:45,700 --> 01:19:51,380
+or minus زاوية خمس و أربعين يعني انا عندي هاي ..
+
+646
+01:19:51,380 --> 01:19:54,920
+هاي ال direction بتاع ال principle stress فاندي
+
+647
+01:19:54,920 --> 01:19:59,060
+واحدة counter clockwise هلف زاوية تسعين درجة اتنين
+
+648
+01:19:59,060 --> 01:20:04,500
+في و انا هلف زاوية خمس و أربعين هجوا انها ده
+
+649
+01:20:07,080 --> 01:20:17,300
+هذه الزاوية خمسة واربعين وهذه ال stress element
+
+650
+01:20:17,300 --> 01:20:25,700
+هنا ال fit clockwise هتعطي تو counter clockwise
+
+651
+01:20:25,700 --> 01:20:28,780
+هتكون
+
+652
+01:20:28,780 --> 01:20:33,580
+بالظبط
+
+653
+01:20:33,580 --> 01:20:40,390
+هكذاالتي تاو maximum
+
+654
+01:20:40,390 --> 01:20:46,750
+طبعا
+
+655
+01:20:46,750 --> 01:20:53,410
+عند تاو maximum بيكون فيه number stress ايش قيمته
+
+656
+01:20:53,410 --> 01:20:56,570
+لا
+
+657
+01:20:56,570 --> 01:21:07,300
+ايه sigma x زي sigma y اتنين بتكون عنده stressاللي
+
+658
+01:21:07,300 --> 01:21:13,480
+هي عند اربعين وعند
+
+659
+01:21:13,480 --> 01:21:17,740
+stress عند
+
+660
+01:21:17,740 --> 01:21:20,760
+ال maximum share stress planes بيكونش نوع ما
+
+661
+01:21:20,760 --> 01:21:24,260
+stress بالزاوية zero بيكون فيه نوع stress وهي عند
+
+662
+01:21:24,260 --> 01:21:32,330
+هاي tau max ها دي tau, tau maxهذه هي قيمة stress
+
+663
+01:21:32,330 --> 01:21:36,490
+هذه اللي هي sigma x زي sigma y على اتنين اللي هي
+
+664
+01:21:36,490 --> 01:21:53,490
+ال center طبعا
+
+665
+01:21:53,490 --> 01:21:57,710
+ال norm stress هذا كام لو في الحالة هذه كام لو
+
+666
+01:22:00,870 --> 01:22:05,430
+بيكون كما لو ان ال element محتوظ في ميه الميه اللي
+
+667
+01:22:05,430 --> 01:22:09,950
+بتحط فيها اشي تضغط عليها من كل الجهات بس هان هنا
+
+668
+01:22:09,950 --> 01:22:12,190
+انا ضاغط في اتجاه الموج بقى انا بسحب هنا و بسحب
+
+669
+01:22:12,190 --> 01:22:16,490
+هنا فال poison ratio effect بلتغف الحالة هذه لو
+
+670
+01:22:16,490 --> 01:22:21,070
+انا بسحب زي هيك بحاول ارفع هذا بسحب معاكس و نفس
+
+671
+01:22:21,070 --> 01:22:25,270
+القيمة بلغي الأثر تبعه فلو كنت اشي محوط من كل
+
+672
+01:22:25,270 --> 01:22:30,120
+الجهات بالميهبيكون ضغط من كل الجهات ففيش
+
+673
+01:22:30,120 --> 01:22:36,940
+deformation في ال ..في التجاه اللي عمودي على السطح
+
+674
+01:22:36,940 --> 01:22:41,200
+عشان يسموه hydrostatic element هذا حاجرنا مستقبلا
+
+675
+01:22:41,200 --> 01:22:46,980
+للي هي ال maximum shear او ال maximum distortion
+
+676
+01:22:46,980 --> 01:22:53,200
+energy theory معظم ال energy اللي بتروح في ال
+
+677
+01:22:53,200 --> 01:22:58,000
+deformation بتروح على شكل distortion يعني بتغير
+
+678
+01:22:58,000 --> 01:23:03,470
+الشكل لكن متغيرش ال dimensionsهيك نكون خلصنا
+
+679
+01:23:03,470 --> 01:23:08,630
+المحاضرة يعني، اتفضل ال ايش؟
+
+680
+01:23:08,630 --> 01:23:13,230
+لا أنا حاكتش counter clockwise، أنا حاكت clockwise
+
+681
+01:23:13,230 --> 01:23:16,790
+ال maximum أنا هادي، إذا بدأ أبدأ، هاي ال
+
+682
+01:23:16,790 --> 01:23:21,170
+principle، هاي ال principle إذا بدأ أروح زي هيك،
+
+683
+01:23:21,170 --> 01:23:24,890
+هاروح counter clockwise خمس و أربعين، اللي هو هادي
+
+684
+01:23:24,890 --> 01:23:31,860
+اللي هي هادي، هتكون إيش؟ clockwiseلكن أنا شوفت
+
+685
+01:23:31,860 --> 01:23:37,180
+أسلّي أمشي من هذه clockwise
+
+686
+01:23:37,180 --> 01:23:41,560
+خمسة فمشيت من هنا لأن أنا قرصت ماشي في اتجاه معين
+
+687
+01:23:41,560 --> 01:23:44,700
+دي مش هقربش حالي فمشيت هيك خمسة واربعين clockwise
+
+688
+01:23:44,700 --> 01:23:50,120
+عرفتي المصطلح هذا هذا حيكون علياش counter
+
+689
+01:23:50,120 --> 01:23:52,140
+clockwise بقى انا قلت لهم حيكون عليه clockwise
+
+690
+01:23:52,140 --> 01:23:56,540
+أعطيكوا
+
+691
+01:23:56,540 --> 01:23:56,740
+العفو
+
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/zPhrosq6KF8.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/zPhrosq6KF8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b72bee9b3aa7a45f3ca0cd9f07f313a3a8be3feb
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/zPhrosq6KF8.srt
@@ -0,0 +1,2763 @@
+1
+00:00:05,380 --> 00:00:08,440
+السلام عليكم ورحمة الله وبركاته بسم الله الرحمن
+
+2
+00:00:08,440 --> 00:00:12,640
+الرحيم اليوم هنستكمل chapter three اللي هو load
+
+3
+00:00:12,640 --> 00:00:17,320
+and stress analysis اللي في المحاضرة الماضية غطينا
+
+4
+00:00:17,320 --> 00:00:21,500
+ال bending و الـ .. ال shear و ال bending moment
+
+5
+00:00:21,500 --> 00:00:27,200
+diagrams حلينا بالطريقة التقليدية حددنا ال sign
+
+6
+00:00:27,200 --> 00:00:29,640
+convention لل positive moment و ال sign convention
+
+7
+00:00:29,640 --> 00:00:35,340
+لل positive and negative shear حكينا في علاقة بين
+
+8
+00:00:35,340 --> 00:00:40,200
+ال shear stress و ال moment ال V بيستوى DM by DX و
+
+9
+00:00:40,200 --> 00:00:46,560
+ال Q بيستوى DV by DX حلينا example بالطريقة
+
+10
+00:00:46,560 --> 00:00:51,580
+التقليدية أنه نأخذ summation of forces و الموجودة
+
+11
+00:00:51,580 --> 00:00:55,620
+ال reactions بعدين نأخذ section نعمل free body
+
+12
+00:00:55,620 --> 00:00:57,820
+diagram و نحسب ال shear و ال bending moment
+
+13
+00:00:57,820 --> 00:01:00,740
+diagram منه رسمنا ال shear و ال moment diagram
+
+14
+00:01:02,770 --> 00:01:07,130
+بعدين استخدمنا ال singularity functions عشان نوجد
+
+15
+00:01:07,130 --> 00:01:10,390
+ال reactions و نوجد ال shear و ال bending moment
+
+16
+00:01:10,390 --> 00:01:17,370
+diagrams  حلينا example تلت ثلاثة اليوم هنكمل برضه 
+
+17
+00:01:17,370 --> 00:01:23,450
+مراجعة لمادة ال mechanics of material ان بين اندي
+
+18
+00:01:23,450 --> 00:01:30,260
+stress element stress element هذا قد يكون نقطة في
+
+19
+00:01:30,260 --> 00:01:34,180
+mechanical member في machine يعني ال stress في ال
+
+20
+00:01:34,180 --> 00:01:40,320
+.. في النهاية ناتج عن أحمال سواء كانت أحمال يعني
+
+21
+00:01:40,320 --> 00:01:48,180
+مفردة يعني زي حمل شد أو compression أو حمل ثاني أو
+
+22
+00:01:48,180 --> 00:01:54,850
+حمل lay أو حمل shear أو أحمال مركبة، مع مركبة شير
+
+23
+00:01:54,850 --> 00:02:00,350
+على axial على bending على .. على torsion في
+
+24
+00:02:00,350 --> 00:02:02,830
+النهاية هيتولى ال end stresses ال most general
+
+25
+00:02:02,830 --> 00:02:07,200
+case لل stress element أن يكون عليه كل stress
+
+26
+00:02:07,200 --> 00:02:10,020
+موجودة في كل الاتجاهات أنا عندي هنا small stress
+
+27
+00:02:10,020 --> 00:02:16,840
+element هذا هو ال X axis Y Z أنا عندي Sigma X
+
+28
+00:02:16,840 --> 00:02:22,940
+Sigma Y Sigma Z وعندي على كل سطح سطح فيه two
+
+29
+00:02:22,940 --> 00:02:28,500
+components لل shear إذا أنا عندي السطح هذا عندي ال
+
+30
+00:02:28,500 --> 00:02:39,120
+X ال Y ال Z الآن كيف بنسمي تسمية ال shear stress سطح
+
+31
+00:02:39,120 --> 00:02:44,920
+عليه two components component موازية لل z axis
+
+32
+00:02:44,920 --> 00:02:52,560
+component موازية لل x axis لل y axis الآن بعرف
+
+33
+00:02:52,560 --> 00:03:04,100
+ال shear tau مثلا عندي tau xz ال X مثل
+
+34
+00:03:06,860 --> 00:03:19,120
+المحور المتعامد على المستوى تحت الدراسة أنا بأحكي
+
+35
+00:03:19,120 --> 00:03:23,440
+المستوى هذا صح؟ المتعامد عليه إيه إيش؟ ال X axis
+
+36
+00:03:23,440 --> 00:03:31,200
+فهي عندي ال X ال Z اللي هي .. اللي هو direction
+
+37
+00:03:36,260 --> 00:03:44,940
+parallel to shear stress component
+
+38
+00:03:44,940 --> 00:03:54,180
+يعني لما نحكي tau xz هي مركبة ال shear اللي وقع
+
+39
+00:03:54,180 --> 00:04:00,540
+في المستوى المتعامد على ال x axis موازية لل z يعني
+
+40
+00:04:00,540 --> 00:04:02,880
+احنا هنا هتكون عندي هذه
+
+41
+00:04:07,450 --> 00:04:18,570
+Tau X Z هي موازية لل Z وعندي Tau X
+
+42
+00:04:18,570 --> 00:04:25,090
+Y مثلا المستوى هذه أول أول شيء عند حكومة ال Y عندي
+
+43
+00:04:25,090 --> 00:04:32,690
+هذه Tau هي ال direction عمود على المستوى بالمناسبة
+
+44
+00:04:32,690 --> 00:04:37,940
+المستوى دائما يعرف بإيش؟ بالمتعامد عليه بالعمودي عليه
+
+45
+00:04:37,940 --> 00:04:45,500
+تاو Y X وعندي
+
+46
+00:04:45,500 --> 00:04:51,580
+تاو Y Z لأن هو هي عمودي على المستوى معرف بال
+
+47
+00:04:51,580 --> 00:04:56,520
+Normal عليه اللي هو ال Y موازن ل Z Axis تاو Y X
+
+48
+00:04:56,520 --> 00:04:59,620
+المستوى
+
+49
+00:04:59,620 --> 00:05:03,660
+هذا معرف بالعمود عليه اللي هو ال Y Axis و هو في
+
+50
+00:05:03,660 --> 00:05:09,580
+اتجاه ال X Axis عندي هين المستوى ده متعمدة على ال
+
+51
+00:05:09,580 --> 00:05:18,040
+z axis فهيبدأ tau z موازية ال y عندي هين tau
+
+52
+00:05:18,040 --> 00:05:23,880
+المستوى ده عمودي على ال z موازية ال x axis
+
+53
+00:05:25,890 --> 00:05:29,010
+بالإضافة لـ Normal Stress Components اللي هو Sigma
+
+54
+00:05:29,010 --> 00:05:49,570
+X و Sigma Y و Sigma Z هندرس
+
+55
+00:05:49,570 --> 00:05:52,750
+الحالة اللي هي تمثل لـ Plain Stress Case
+
+56
+00:05:55,980 --> 00:06:01,680
+بكون عندي plan stress يعني stress في بعضين أو في
+
+57
+00:06:01,680 --> 00:06:06,220
+مستوى إذا كانت ال stresses on one surface are zero
+
+58
+00:06:06,220 --> 00:06:12,420
+يعني هاي ال X Y Z لو كانت ال stresses على المستوى
+
+59
+00:06:12,420 --> 00:06:18,400
+هذا المتعامد على Z axis ال sigma Z والتاو X
+
+60
+00:06:18,400 --> 00:06:23,650
+والتاو Y بتستوى Zero بعتبرها a case of planned
+
+61
+00:06:23,650 --> 00:06:27,210
+stress ال case of planned stress عندي هاي ال x
+
+62
+00:06:27,210 --> 00:06:35,530
+axis هاي ال y axis عندي sigma x sigma y tau xy tau
+
+63
+00:06:35,530 --> 00:06:43,480
+xy tau xy tau xy هذا case و plan stress اللي هو zx
+
+64
+00:06:43,480 --> 00:06:47,580
+زعمودي على الصفحة sigma z بالساوية zero و sigma zx
+
+65
+00:06:47,580 --> 00:06:52,800
+بالساوية zero أو tau zx و tau zy بالساوية zero
+
+66
+00:06:52,800 --> 00:07:02,420
+هنأخذ
+
+67
+00:07:02,420 --> 00:07:13,250
+الحالة ل plan stress case بدي أشوف الـ stresses at
+
+68
+00:07:13,250 --> 00:07:18,410
+any other plane مش موازي لل X-axis يعني مش موازي
+
+69
+00:07:18,410 --> 00:07:20,950
+أو متعدد لل X-axis يعني أنا ماخد حلقة هاي مستوى
+
+70
+00:07:20,950 --> 00:07:24,290
+عمود على ال X-axis وهي مستوى عمود على ال Y-axis
+
+71
+00:07:24,290 --> 00:07:28,310
+what if إذا كان عندي مستوى ميل رأينا هنا اندي أن
+
+72
+00:07:28,310 --> 00:07:37,390
+هاي ال X-axis ماخد مستوى ميل بزاوية Phi مع ال Y
+
+73
+00:07:37,390 --> 00:07:47,650
+-axis طبعا على المستوى هذا يوجد stress sigma x و
+
+74
+00:07:47,650 --> 00:08:00,090
+stress tau xy على المستوى هذا يوجد sigma y و tau
+
+75
+00:08:00,090 --> 00:08:06,170
+xy على المستوى المائل اللي حيكون عندي stress more
+
+76
+00:08:06,170 --> 00:08:07,110
+than stress component
+
+77
+00:08:10,500 --> 00:08:17,960
+سيجما و شير السترس كومبوننت تاو طبعا الزاوية هذا
+
+78
+00:08:17,960 --> 00:08:22,860
+هتكون إيه؟ في
+
+79
+00:08:22,860 --> 00:08:29,940
+لإن هذا في هذا هتكون تسعين ناقص في صح؟ هذا في
+
+80
+00:08:29,940 --> 00:08:33,300
+معناته تسعين ناقص في معناته هذا إيه؟ في
+
+81
+00:08:43,630 --> 00:08:55,310
+لأن هذه المسافة هاتبعها Delta X وهذه
+
+82
+00:08:55,310 --> 00:09:06,290
+المسافة Delta Y البعد
+
+83
+00:09:06,290 --> 00:09:06,890
+الثالث
+
+84
+00:09:19,570 --> 00:09:26,410
+هذا البعد الثالث هسميه
+
+85
+00:09:26,410 --> 00:09:35,070
+delta z أنا
+
+86
+00:09:35,070 --> 00:09:39,930
+بعمل free body diagram هاندي
+
+87
+00:09:39,930 --> 00:09:45,130
+ال x axis هاي ال y axis
+
+88
+00:09:48,380 --> 00:09:54,440
+هاخد summation of forces باتجاه ال X axis باتجاه
+
+89
+00:09:54,440 --> 00:09:59,700
+ال Y axis باتجاه
+
+90
+00:09:59,700 --> 00:10:08,540
+ال X بالساوية 0 و أعتبر هذا الاتجاه الموجب ال
+
+91
+00:10:08,540 --> 00:10:13,240
+sigma X هذه بتأثر بهذا الاتجاه stress في area
+
+92
+00:10:13,240 --> 00:10:19,330
+يعطيني إيش forceفهيكون minus sigma x ال area هيكون
+
+93
+00:10:19,330 --> 00:10:25,890
+delta y في delta z minus sigma x delta
+
+94
+00:10:25,890 --> 00:10:35,830
+y delta z هذه ال area هذا
+
+95
+00:10:35,830 --> 00:10:39,930
+مافيش لأ minus tau xy
+
+96
+00:10:46,110 --> 00:11:06,090
+في Delta X Delta Z Delta X Delta Z بتساوي
+
+97
+00:11:06,090 --> 00:11:11,450
+عند هاي Sigma اللي هو مركبتين واحد اتجاه ال X Axis
+
+98
+00:11:16,360 --> 00:11:24,020
+سيجما في كوسين الفا فيه
+
+99
+00:11:24,020 --> 00:11:33,740
+لأن هذا دلتا S هذا أو في
+
+100
+00:11:33,740 --> 00:11:38,880
+دلتا S مظبوط
+
+101
+00:11:38,880 --> 00:11:43,760
+طبعا ما فقت دكتور ديالي في دلتا X و دلتا Y يعني في
+
+102
+00:11:43,760 --> 00:11:52,420
+النهاية ستكون هي سيجما سيجما في الضلع هذه اللي
+
+103
+00:11:52,420 --> 00:12:00,180
+بتعطيني ال force في delta S بتعطيني ال force بدي
+
+104
+00:12:00,180 --> 00:12:07,160
+أخد المركبة بتاعتها في cosine الفي دلتا S طبعا في
+
+105
+00:12:07,160 --> 00:12:07,720
+delta Z
+
+106
+00:12:11,750 --> 00:12:17,910
+سيكون سيجما دلتا
+
+107
+00:12:17,910 --> 00:12:21,590
+S دلتا
+
+108
+00:12:21,590 --> 00:12:26,670
+Z في المركبة بتاعتها اللي هي إيش؟ كوسين الفا
+
+109
+00:12:26,670 --> 00:12:30,250
+minus
+
+110
+00:12:30,250 --> 00:12:34,210
+تاو
+
+111
+00:12:34,210 --> 00:12:52,840
+في دلتا S دلتا Z cos φ طيب
+
+112
+00:12:52,840 --> 00:12:59,900
+لحظة
+
+113
+00:12:59,900 --> 00:13:06,840
+في علاقة بين ال delta S و delta X و delta Y يعني
+
+114
+00:13:06,840 --> 00:13:08,120
+ممكن أحكي أنا
+
+115
+00:13:13,970 --> 00:13:18,370
+ماذا يساوي دلتا
+
+116
+00:13:18,370 --> 00:13:31,910
+Y على دلتا S دلتا Y على دلتا S كوسين الفي دلتا
+
+117
+00:13:31,910 --> 00:13:39,950
+X على دلتا S يعني ممكن أحكي أنا دلتا S بتساوي
+
+118
+00:13:42,870 --> 00:13:53,170
+delta y على cos فاي و برضه بالساوية delta x على
+
+119
+00:13:53,170 --> 00:13:58,670
+sin فاي نرجع
+
+120
+00:13:58,670 --> 00:14:03,950
+للمعادلة صارت عند المعادلة صفر بالساوية minus sigma x
+
+121
+00:14:03,950 --> 00:14:21,100
+delta y delta z minus tau xy delta x delta z زاد
+
+122
+00:14:21,100 --> 00:14:27,800
+sigma sigma
+
+123
+00:14:27,800 --> 00:14:34,320
+delta s هي cosine فيه معناه دلتا س هتكون في delta
+
+124
+00:14:34,320 --> 00:14:51,850
+y على cosine فيه في delta z cos فيه minus tau
+
+125
+00:14:51,850 --> 00:15:06,390
+فيه delta x على sin فيه delta z sin delta z sin فيه
+
+126
+00:15:17,100 --> 00:15:25,840
+يعني أدى ال cos فاي هنا تختصر و
+
+127
+00:15:25,840 --> 00:15:33,000
+sin فاي تختصر و Delta Z تختصر
+
+128
+00:15:33,000 --> 00:15:37,040
+Delta
+
+129
+00:15:37,040 --> 00:15:41,680
+Z تختصر طيب
+
+130
+00:15:41,680 --> 00:15:48,110
+لو قسمت الطرفين على Delta X خلّيني أخد لحالة لأن
+
+131
+00:15:48,110 --> 00:15:58,050
+عندي صار Zero بيستوى minus Sigma X Delta Y minus
+
+132
+00:15:58,050 --> 00:16:06,150
+Tau XY Delta X Delta
+
+133
+00:16:06,150 --> 00:16:13,230
+X زاد Sigma Delta Y
+
+134
+00:16:18,730 --> 00:16:28,490
+مينوس تاو دلتا اكس فيش ضال؟ لأ أنا هضطر أعود أجحك
+
+135
+00:16:28,490 --> 00:16:38,930
+من هنا دلتا Y بالساوية دلتا S في cos فاي ماشي و
+
+136
+00:16:38,930 --> 00:16:45,770
+دلتا X بالساوية دلتا S في sin فاي ليش هعمل زي هيك؟
+
+137
+00:16:46,360 --> 00:16:52,740
+عشان ألغى ألغى هدول صح؟ يعني أنا حسين عند ال zero
+
+138
+00:16:52,740 --> 00:17:03,040
+so minus sigma x في delta s cosine الفي minus tau
+
+139
+00:17:03,040 --> 00:17:13,740
+xy delta s sine الفي زاد sigma في delta s cosine
+
+140
+00:17:13,740 --> 00:17:24,390
+الفي من أول 
+
+141
+00:17:24,390 --> 00:17:34,630
+ماشي الآن أنا هيروح عندي delta s و delta s و delta 
+
+142
+00:17:34,630 --> 00:17:40,450
+s حاسس
+
+143
+00:17:40,450 --> 00:17:48,170
+أن عندي zero minus sigma x cosine phi minus tau xy
+
+144
+00:17:48,170 --> 00:18:01,790
+sine of phi زائد sigma cosine of phi minus tau 
+
+145
+00:18:01,790 --> 00:18:06,950
+sine of phi إحنا نحسب sigma و tau إحنا نحسب sigma
+
+146
+00:18:06,950 --> 00:18:10,910
+و tau يعني خلينا أحكي sigma
+
+147
+00:18:35,090 --> 00:18:36,930
+إنحق الصميم الـ forces
+
+148
+00:18:40,090 --> 00:18:49,410
+باتجاه ال Y بتساوي Zero هكون
+
+149
+00:18:49,410 --> 00:18:56,870
+دي Minus Tau XY Delta 
+
+150
+00:18:56,870 --> 00:19:05,570
+Y Delta Z Minus
+
+151
+00:19:05,570 --> 00:19:06,470
+Sigma Y
+
+152
+00:19:10,940 --> 00:19:18,500
+Delta X Delta Z Delta 
+
+153
+00:19:18,500 --> 00:19:29,380
+X Delta Z Minus Sigma Y Delta X Delta Z زاد
+
+154
+00:19:29,380 --> 00:19:45,000
+Sigma Delta S Delta Z Sin Phi زاد
+
+155
+00:19:45,000 --> 00:19:57,880
+Tau Delta S Delta Z Cos Phi خلّيني
+
+156
+00:19:57,880 --> 00:20:00,640
+أختصر أول أول أول أول يعني واضح Delta Z بتروح
+
+157
+00:20:00,640 --> 00:20:02,700
+معنا Delta Z بتروح
+
+158
+00:20:06,340 --> 00:20:12,920
+لأ أعوض عن Delta Y Delta S Cos Phi حسينا دي صفر
+
+159
+00:20:12,920 --> 00:20:22,720
+بالساوة minus Tau XY Delta Y اللي هي Delta S Cos
+
+160
+00:20:22,720 --> 00:20:38,680
+Phi minus Sigma Y في Delta S Sin Phi زاد سيجما دلتا
+
+161
+00:20:38,680 --> 00:20:54,160
+اس صين الفاى زاد تا دلتا اس كسين الفاى يعني
+
+162
+00:20:54,160 --> 00:20:55,220
+هتروح عندي دلتا اس
+
+163
+00:21:03,510 --> 00:21:12,950
+هيصف عندي سيجما ساين الفاى سيجما ساين الفاى زاد
+
+164
+00:21:12,950 --> 00:21:27,870
+تاو كساين الفاى بتساوي تاو XY هتساوي سيجما Y ساين
+
+165
+00:21:27,870 --> 00:21:32,090
+الفاى زاد
+
+166
+00:21:33,740 --> 00:21:44,280
+تاو اكس واي كوسين الفاية مظبوط
+
+167
+00:21:44,280 --> 00:21:52,020
+سيجما واي كوسين الفاية زي تاو اكس واي كوسين الفاية
+
+168
+00:21:52,020 --> 00:22:00,780
+هذه معادلة اتنين هربع
+
+169
+00:22:00,780 --> 00:22:05,980
+واحد واربع اتنين واجمعهم مع بعض أنا أحكي واحد
+
+170
+00:22:05,980 --> 00:22:13,080
+square زائد
+
+171
+00:22:13,080 --> 00:22:20,980
+اتنين معدل اتنين square هاي
+
+172
+00:22:20,980 --> 00:22:26,700
+واحد هكون أنقل بين الاتنين بين هاد و هاد هكون دي
+
+173
+00:22:26,700 --> 00:22:27,620
+sigma تربيع
+
+174
+00:22:38,030 --> 00:22:45,530
+سيجمه تربية سيجمه تربية سيجمه تربية سيجمه تربية
+
+175
+00:22:45,530 --> 00:22:52,030
+سيجمه تربية
+
+176
+00:22:57,960 --> 00:23:10,760
+cos تربيع فاي ماشي رابطها هتكون minus اتنين minus
+
+177
+00:23:10,760 --> 00:23:17,220
+اتنين سيجما سيجما تاو كسايم ساي زي اتنين سيجما تاو
+
+178
+00:23:17,220 --> 00:23:20,580
+ساين كسايم بالغبال على بعض معناه أنت خلصنا جهة
+
+179
+00:23:20,580 --> 00:23:23,540
+الشمال هتساوي
+
+180
+00:23:31,630 --> 00:23:37,270
+سيجما اكس تربيه
+
+181
+00:23:37,270 --> 00:23:48,030
+سيجما اكس تربيه كوسين تربيه في زاد
+
+182
+00:23:48,030 --> 00:23:56,090
+سيجما اكس تربيه سيجما
+
+183
+00:23:56,090 --> 00:24:11,240
+واي هذه زاد سيجما وايتربية sin تربيه في زائد
+
+184
+00:24:11,240 --> 00:24:24,060
+TAO XY تربيه sin تربيه في زائد
+
+185
+00:24:24,060 --> 00:24:31,120
+TAO XY تربيه cos تربيه في
+
+186
+00:24:34,800 --> 00:24:43,000
+زائد عندي اتنين هادي في هادي، صح؟ زائد اتنين هادي
+
+187
+00:24:43,000 --> 00:24:49,740
+في هادي، زائد اتنين تو
+
+188
+00:24:49,740 --> 00:24:54,740
+اكس واي سيجما
+
+189
+00:24:54,740 --> 00:25:02,560
+اكس صين في كوسين في
+
+190
+00:25:04,710 --> 00:25:10,010
+زاد اتنين تاو
+
+191
+00:25:10,010 --> 00:25:14,490
+اكس واي سيجما
+
+192
+00:25:14,490 --> 00:25:21,750
+واي صين في كوسين في
+
+193
+00:25:40,340 --> 00:25:43,940
+طيب هذا sigma تربيع cos تربيع زي sigma تربيع sin
+
+194
+00:25:43,940 --> 00:25:46,900
+تربيع ايش بتساوي؟ sigma تربيع يعني هالصحفة عندي
+
+195
+00:25:46,900 --> 00:26:00,740
+sigma تربيع زائد تاو تربيع زائد
+
+196
+00:26:00,740 --> 00:26:05,360
+تاو تربيع بتساوي
+
+197
+00:26:09,800 --> 00:26:20,960
+الـ Sigma X تربيع لأ
+
+198
+00:26:20,960 --> 00:26:26,580
+مافيش اختصارات عشان أسوي هنضب المعادلة الأولى Cos
+
+199
+00:26:26,580 --> 00:26:32,940
+والمعادلة التانية Sin بعد ايه بنجمعهم؟ ليش هضلوا
+
+200
+00:26:32,940 --> 00:26:46,220
+لأن بلغي التاو معناته حل غيادة هذه معادلة واحد هك
+
+201
+00:26:46,220 --> 00:26:49,040
+أنا اعططنى معادلة اللي هي أنا روحت على more circle
+
+202
+00:26:49,040 --> 00:26:54,420
+اقعدل هك أنا هك حصل ل more circle معادلة دائرة بس
+
+203
+00:26:54,420 --> 00:26:58,060
+أنا هجيب sigma لحال و tau لحال بعدين هروح على more
+
+204
+00:26:58,060 --> 00:27:01,500
+circle هتعرف بعد شوية انه عملت more circle أنا
+
+205
+00:27:01,500 --> 00:27:08,530
+اللي عملته حاليا هك multiply واحد واحد في cosine
+
+206
+00:27:08,530 --> 00:27:17,550
+فاى زائد اتنين في sine فاى ايش حاسسيه اللي عنديه
+
+207
+00:27:17,550 --> 00:27:25,250
+سيجما كوسين تربيه يعني هذا هتروح معاه سيجما كوسين
+
+208
+00:27:25,250 --> 00:27:31,890
+تربيه زائد سيجما sine تربيه سيجما هيكون عندي سيجما
+
+209
+00:27:31,890 --> 00:27:36,310
+بتساوي sigma X
+
+210
+00:27:41,070 --> 00:27:50,250
+الأولى في Cos Sigma X Cos تربيع Phi زائد Sigma Y
+
+211
+00:27:50,250 --> 00:28:00,610
+في Sin تربيع Phi Cos
+
+212
+00:28:00,610 --> 00:28:21,680
+Sin زائد اتنين Tau XYSin Phi Cos Phi اللي
+
+213
+00:28:21,680 --> 00:28:27,340
+.. اللي .. اللي سواه هو .. هانا اختصر عندكوا Cos
+
+214
+00:28:27,340 --> 00:28:33,860
+Two Theta F ساوية Cos تربيعتي
+
+215
+00:28:38,410 --> 00:28:46,450
+cos²θ-sin²θ هذه ستكون تساوي cos²θ
+
+216
+00:28:46,450 --> 00:28:57,030
+-1-cos²θ ستكون تساوي 2cos²θ
+
+217
+00:28:57,030 --> 00:29:04,250
+-1 يعني cos²θ بالساوية نص
+
+218
+00:29:06,700 --> 00:29:13,960
+في واحد زائد cosine two theta هاي الصيغة مظبوط؟
+
+219
+00:29:13,960 --> 00:29:20,300
+الآن أنا ممكن أحكيه برضه cosine two theta بستوى
+
+220
+00:29:20,300 --> 00:29:25,160
+واحد minus sin تربيع theta minus sin تربيع theta
+
+221
+00:29:25,160 --> 00:29:33,460
+صح؟ يعني هتكون واحد ماقص اتنين sin تربيع theta
+
+222
+00:29:33,460 --> 00:29:35,660
+يعني cosine two theta
+
+223
+00:29:59,660 --> 00:30:07,420
+معناته هيجي أعوض عن هذا سجماسيجما بالساوية سيجما X
+
+224
+00:30:07,420 --> 00:30:15,360
+في cos تربيع في عبر
+
+225
+00:30:15,360 --> 00:30:25,620
+عن نص في واحد زائد cosine two في زائد
+
+226
+00:30:25,620 --> 00:30:38,040
+سيجما Y على اتنين في واحد minus cosine تو في زاد
+
+227
+00:30:38,040 --> 00:30:52,940
+تاو اكس واي صين تو في يعني
+
+228
+00:30:52,940 --> 00:30:57,120
+أنا هكون لحظة هي سيجما اكس على اتنين زائد سيجما
+
+229
+00:30:57,120 --> 00:31:02,320
+واي على اتنين سيجما اكس على اتنين سيجما اكس زائد
+
+230
+00:31:02,320 --> 00:31:07,700
+سيجما واي على اتنين خلصنا اول term زائد sigma x
+
+231
+00:31:07,700 --> 00:31:10,760
+minus
+
+232
+00:31:10,760 --> 00:31:22,620
+sigma y على اتنين cosine two phi مظلوط زائد tau xy
+
+233
+00:31:22,620 --> 00:31:28,480
+sine two phi اللي هي معادلة sigma اللي هي عادية
+
+234
+00:31:28,480 --> 00:31:28,900
+المعادلة
+
+235
+00:31:34,220 --> 00:31:41,460
+إحنا عرفنا sigma بنفس
+
+236
+00:31:41,460 --> 00:31:47,580
+المنطقة لو ضربنا المعادلة الأولى ب sin phi
+
+237
+00:31:47,580 --> 00:31:53,400
+والمعادلة
+
+238
+00:31:53,400 --> 00:31:57,600
+التانية ب minus cosine phi يعني حكينا
+
+239
+00:32:04,690 --> 00:32:12,290
+sin phi أو
+
+240
+00:32:12,290 --> 00:32:22,890
+ضرب الأولى minus ماشي sin phi في معادلة واحد minus
+
+241
+00:32:22,890 --> 00:32:30,310
+cosine phi في المعادلة التانية هيعطينا
+
+242
+00:32:34,780 --> 00:32:41,720
+يعني هاد هتروح مع هاد صح؟ هاد هتصير minus tau sine
+
+243
+00:32:41,720 --> 00:32:47,580
+تربيه minus tau cosine تربيه يعني هتكون minus tau
+
+244
+00:32:47,580 --> 00:32:57,320
+minus tau هتساوي sigma x هتكون
+
+245
+00:32:57,320 --> 00:32:58,240
+دي sigma x
+
+246
+00:33:03,690 --> 00:33:12,170
+Sin Phi Cos Phi Minus
+
+247
+00:33:12,170 --> 00:33:19,750
+Sigma Y Sin
+
+248
+00:33:19,750 --> 00:33:27,970
+Phi Cos Phi عندي
+
+249
+00:33:27,970 --> 00:33:28,170
+هنا
+
+250
+00:33:31,180 --> 00:33:40,420
+تاو اكس واي تاو اكس واي صين .. صين تربيع وعندي هين
+
+251
+00:33:40,420 --> 00:33:51,360
+زاد تاو اكس واي صين تربيع
+
+252
+00:33:51,360 --> 00:33:57,360
+في minus
+
+253
+00:33:57,360 --> 00:34:09,920
+تاو اكس وايcos تربيه فاي يعني
+
+254
+00:34:09,920 --> 00:34:13,540
+حاسيب
+
+255
+00:34:13,540 --> 00:34:18,320
+عندي minus tao أو خليني أقسم على minus يعني أنا
+
+256
+00:34:18,320 --> 00:34:24,180
+حاسب عندي تاو بتساوي
+
+257
+00:34:24,180 --> 00:34:29,620
+minus مص
+
+258
+00:34:32,030 --> 00:34:51,150
+Sigma X Sine 2 Phi زاد نص Sigma Y Sine 2 Phi minus
+
+259
+00:34:51,150 --> 00:34:58,510
+Tau XY في
+
+260
+00:34:58,510 --> 00:35:11,250
+Cos تربيعفاي ماينس صين تربيه فاي صح؟ يعني حاسيسي
+
+261
+00:35:11,250 --> 00:35:15,150
+اندي التاو بدي
+
+262
+00:35:15,150 --> 00:35:23,750
+أخد ماينس عام مشترك هتكون سيجما اكس ماينس سيجما
+
+263
+00:35:23,750 --> 00:35:32,950
+واي على اتنين صين two في خد بين هد و هد minus tau
+
+264
+00:35:32,950 --> 00:35:39,490
+xy في
+
+265
+00:35:39,490 --> 00:35:48,690
+ال cosine تربيع في نص في
+
+266
+00:35:48,690 --> 00:35:57,690
+واحد زائد cosine two في ناقص نص
+
+267
+00:35:59,860 --> 00:36:11,140
+في واحد minus cosine two five هذا
+
+268
+00:36:11,140 --> 00:36:18,520
+ال term هيروح الواحد مع الواحد صح ما هو نعرف ان
+
+269
+00:36:18,520 --> 00:36:22,960
+أنت عندك نص cosine مع نص cosine ايش مستويه
+
+270
+00:36:31,030 --> 00:36:41,330
+Tau XY Cos Sigma X minus Sigma Y على اتنين Sine
+
+271
+00:36:41,330 --> 00:36:46,350
+Two Fi زائد Tau XY فيه إشارة غلطة راجعها زائد Tau
+
+272
+00:36:46,350 --> 00:36:57,550
+XY فيه Cos Two Fi هذه المعادلة رجعها براحتك خلاص
+
+273
+00:36:57,550 --> 00:37:02,830
+أنت لحالك تدور عليها و تصليحها طيب معناته ان
+
+274
+00:37:02,830 --> 00:37:04,710
+المعادلة sigma is equal to sigma x زي sigma y على
+
+275
+00:37:04,710 --> 00:37:06,930
+اتنين زي sigma x minus sigma y على اتنين cosine
+
+276
+00:37:06,930 --> 00:37:12,270
+two phi زي التو xy sin two phi والتاو واشير stress
+
+277
+00:37:12,270 --> 00:37:17,890
+at any angle phi مطلق minus sigma x minus sigma y
+
+278
+00:37:17,890 --> 00:37:22,390
+على اتنين sin two phi زي التو xy cosine two phi اه
+
+279
+00:37:31,080 --> 00:37:46,480
+اه ماشي لما
+
+280
+00:37:46,480 --> 00:37:50,580
+تعرفنا العقابين sigma و tau at any planewith
+
+281
+00:37:50,580 --> 00:37:55,580
+with respect to sigma x و sigma y و tau x و tau xy و
+
+282
+00:37:55,580 --> 00:37:59,260
+phi الآن
+
+283
+00:37:59,260 --> 00:38:02,780
+بدي احسب ال principle stresses يعني متى ال normal
+
+284
+00:38:02,780 --> 00:38:06,940
+stresses بيكونوا maximum for sigma to be maximum
+
+285
+00:38:06,940 --> 00:38:09,900
+لازم يكون ال first derivative with respect to phi
+
+286
+00:38:09,900 --> 00:38:16,880
+ايش يساوي؟ zero يعني لو حسبت حكيت d sigma على d
+
+287
+00:38:16,880 --> 00:38:24,910
+phi و سويتها للصفر هيكون هذا صفر صح أنا ما عملت اشتقاق
+
+288
+00:38:24,910 --> 00:38:36,410
+بالنسبة لفاي minus صفر minus اثنين في sigma x
+
+289
+00:38:36,410 --> 00:38:47,630
+minus sigma y على اثنين sin two phi زائد اثنين tau
+
+290
+00:38:47,630 --> 00:38:54,970
+xy كوساين ال two phi معناته
+
+291
+00:38:54,970 --> 00:39:02,210
+هكون عندي سيجما اكس ماينس سيجما واي ساين ال two
+
+292
+00:39:02,210 --> 00:39:16,250
+phi هتساوي اثنين تاو xy كوساين two phi 
+
+293
+00:39:16,250 --> 00:39:24,030
+طرفين على كوساين فايف تان two phi
+
+294
+00:39:24,030 --> 00:39:29,470
+تان two phi بتساوي
+
+295
+00:39:29,470 --> 00:39:38,490
+اثنين تاو xy على سيجما اكس ماينس سيجما واي at
+
+296
+00:39:38,490 --> 00:39:39,670
+this angle
+
+297
+00:39:42,510 --> 00:39:47,570
+بيكون ال normal stress maximum normal stress بيكون
+
+298
+00:39:47,570 --> 00:39:52,970
+maximum اللي
+
+299
+00:39:52,970 --> 00:39:56,790
+هي هذه المعادلة اللي أنا عشان أحسب ال principal
+
+300
+00:39:56,790 --> 00:40:04,870
+stresses هعوض .. هعوض بالزاوية هذه أنا هاي تان
+
+301
+00:40:04,870 --> 00:40:10,130
+فاية عند هاي الزاوية فاية نعتبر هذه فاية كأنها
+
+302
+00:40:10,130 --> 00:40:18,470
+فاية هي عندي اثنين تاو XY او ممكن اعتبرها بالصيغة
+
+303
+00:40:18,470 --> 00:40:24,370
+هذه tau XY على
+
+304
+00:40:24,370 --> 00:40:31,090
+اثنين زي هيك بيصير نفس الشيء التان مقابل على مجاور
+
+305
+00:40:31,090 --> 00:40:36,810
+هي عندها اثنين سيجما X minus سيجما Y على اثنين معناته
+
+306
+00:40:36,810 --> 00:40:40,630
+هذا الضلع ايش هكون ساوى جذر التربيع
+
+307
+00:40:45,710 --> 00:40:52,330
+لإحنا لغيّرنا صح؟ هتكون جذر التربيع ل sigma x minus
+
+308
+00:40:52,330 --> 00:41:01,610
+sigma y على اثنين لكل تربيع زي ال tau xy تربيع لأن
+
+309
+00:41:01,610 --> 00:41:04,430
+ال sigma بدنا نحصل ال sigma principle هعوض عن فعل
+
+310
+00:41:04,430 --> 00:41:10,810
+أنا حاططها ياما اندي ال sigma بتساوي sigma x زي
+
+311
+00:41:10,810 --> 00:41:13,510
+sigma y على اثنين
+
+312
+00:41:18,350 --> 00:41:29,370
+زائد sigma x هذا طبعا اثنين فيا زائد sigma x minus
+
+313
+00:41:29,370 --> 00:41:38,450
+sigma y على اثنين في ال cosine اللي هي عبارة عن
+
+314
+00:41:38,450 --> 00:41:47,040
+sigma x minus sigma y على اثنين والجذر اللي هو
+
+315
+00:41:47,040 --> 00:41:55,880
+الوتر حتى الجذر معروف إنه جوا هذا الكلام أنا
+
+316
+00:41:55,880 --> 00:42:10,220
+بعوض هناك زائد tau xy sin 2 phi اللي عبارة عن tau
+
+317
+00:42:10,220 --> 00:42:11,020
+xy
+
+318
+00:42:15,430 --> 00:42:27,290
+على الجذر طيب
+
+319
+00:42:27,290 --> 00:42:32,470
+بعمله لأن صار معروف كل ال mathematical terms موجود
+
+320
+00:42:32,470 --> 00:42:34,910
+عندكوا المعادلة اللي حكيت فيها اعملها
+
+321
+00:42:34,910 --> 00:42:37,650
+simplification دي ده تماما simplification لأن
+
+322
+00:42:37,650 --> 00:42:38,170
+simplify
+
+323
+00:42:44,980 --> 00:42:53,000
+بيعطينا المعادلة هذه ال principle stresses اللي هي
+
+324
+00:42:53,000 --> 00:42:55,760
+أنا عندي two principle stresses sigma one and
+
+325
+00:42:55,760 --> 00:42:58,560
+sigma two sigma one يعني sigma x زي sigma y على
+
+326
+00:42:58,560 --> 00:43:00,840
+اثنين زي أو ناقص sigma x وانا sigma one على اثنين
+
+327
+00:43:00,840 --> 00:43:05,820
+الكل تربيع زي ال tau xy تربيع واضح إنه هيطلع إن
+
+328
+00:43:05,820 --> 00:43:09,620
+أنا عندنا جذر الجذر اللي هو هذا في المعادلة هذول
+
+329
+00:43:09,620 --> 00:43:14,340
+هو ال principle stresses الآن خلينا نشوف قيمة الشير
+
+330
+00:43:14,340 --> 00:43:18,620
+ال stress لما
+
+331
+00:43:18,620 --> 00:43:22,600
+يكون ال stress principal ايش عن ال principal يعني
+
+332
+00:43:22,600 --> 00:43:29,380
+ال normal stress بيكون ايش maximum عند ال tau اللي
+
+333
+00:43:29,380 --> 00:43:43,560
+هو at maximum normal stress بتكون عندي tan phi
+
+334
+00:43:43,560 --> 00:43:54,300
+بتساوي tau xy على sigma x minus sigma y على اثنين
+
+335
+00:43:54,300 --> 00:44:05,820
+صح؟ tan اثنين phi اعوض
+
+336
+00:44:05,820 --> 00:44:16,640
+عنها هتكون minus sigma x minus sigma y على اثنين في
+
+337
+00:44:16,640 --> 00:44:27,140
+sine two phi اللي هي عبارة عن tau xy على الجذر صح؟
+
+338
+00:44:27,140 --> 00:44:34,600
+فهي ال sine مقابل والوتر هاي المقابل زائد
+
+339
+00:44:34,600 --> 00:44:36,540
+tau
+
+340
+00:44:40,230 --> 00:44:48,670
+xy cosine two phi عبارة عن sigma x minus sigma y
+
+341
+00:44:48,670 --> 00:44:56,970
+على اثنين على جذر صح؟ لاحظوا هذا بيساوي هذا واحد
+
+342
+00:44:56,970 --> 00:45:03,310
+موجب وواحد سالب بيلغوا بعض صح؟
+
+343
+00:45:03,310 --> 00:45:08,840
+معناته at the planes where the normal stresses are
+
+344
+00:45:08,840 --> 00:45:12,600
+maximum بيكونش عندنا شير بيكون الشير شو يساوي؟
+
+345
+00:45:12,600 --> 00:45:19,180
+zero معناته and zero shear stresses at the
+
+346
+00:45:19,180 --> 00:45:24,780
+principal surface معناته
+
+347
+00:45:24,780 --> 00:45:29,060
+فقط بيكون عنده and the principal planes بيكون عنده
+
+348
+00:45:29,060 --> 00:45:31,860
+فقط principal normal stresses no shear stress
+
+349
+00:45:41,890 --> 00:45:49,570
+الكو ساين هي أنا بحكي كو ساين two phi كو ساين
+
+350
+00:45:49,570 --> 00:45:56,730
+مجاور على وتر هي
+
+351
+00:45:56,730 --> 00:46:04,050
+أنا بعطيه لك هي عندك two phi ال two phi بتساوي
+
+352
+00:46:04,050 --> 00:46:09,450
+هي tau xy هذا for any angle هي المقابل على مجاور
+
+353
+00:46:09,450 --> 00:46:13,390
+على sigma x الوتر
+
+354
+00:46:13,390 --> 00:46:20,470
+ايش هيكون قيمة بالحالة هذه جذر التربيع يعني فال
+
+355
+00:46:20,470 --> 00:46:25,050
+sign هذا جذر التربيع على الوتر و ال cosine المجاور
+
+356
+00:46:25,050 --> 00:46:28,930
+على الوتر أنا بلغ مرصم من بعيد عندي هذا المقابل
+
+357
+00:46:28,930 --> 00:46:34,630
+هذا المجاور يعني مقابل ال sign مقابل على جذر و
+
+358
+00:46:34,630 --> 00:46:43,510
+cosine مجاور على جذر واضح؟ لإنا فاهم .. فاهم أنا
+
+359
+00:46:43,510 --> 00:46:46,790
+اللي كيف أقول أنا .. أنا قصد في القانون مش تان ..
+
+360
+00:46:46,790 --> 00:46:50,870
+two say .. two phi .. two phi اه يساوي الشيء اللي
+
+361
+00:46:50,870 --> 00:46:54,690
+هو .. أنا اشتقيت لك اياها أنا .. أنا حكيت لك بيكون
+
+362
+00:46:54,690 --> 00:47:00,570
+هذا ال stress بشكل عام on ال plane لكن اندي one
+
+363
+00:47:00,570 --> 00:47:03,610
+specific plane ال maximum بيكون دي ال stress
+
+364
+00:47:03,610 --> 00:47:08,910
+maximum for principle أنا بحكي تغير sigma ما عياش
+
+365
+00:47:08,910 --> 00:47:13,450
+مع ال phi a principle where the normal stress is
+
+366
+00:47:13,450 --> 00:47:15,590
+maximum بيكون ال derivative لل sigma بالنسبة ل
+
+367
+00:47:15,590 --> 00:47:18,990
+phi بيستوي zero يعني أنا اشتقيتها بالنسبة دي sigma
+
+368
+00:47:18,990 --> 00:47:21,790
+بقى دي phi سويتها ل zero و طلعت تطلع عند ال ten
+
+369
+00:47:21,790 --> 00:47:24,850
+to phi اللي هي تساوي two x y على sigma x one x y
+
+370
+00:47:24,850 --> 00:47:27,510
+على اثنين من هنا نجت
+
+371
+00:47:38,570 --> 00:47:41,770
+طيب ال shear stress بيكون maximum هذا برضه ممكن
+
+372
+00:47:41,770 --> 00:47:48,250
+تثبتوها نرجع
+
+373
+00:47:48,250 --> 00:47:54,050
+للمعادلة يعني
+
+374
+00:47:54,050 --> 00:48:03,550
+ال D Tau 100% D Tau by D Phi بتساوي
+
+375
+00:48:06,080 --> 00:48:12,980
+minus sigma x minus sigma y في
+
+376
+00:48:12,980 --> 00:48:19,300
+cosine two phi minus
+
+377
+00:48:19,300 --> 00:48:31,440
+اثنين tau xy sine two phi تساوي ل zero عشان أجد ال
+
+378
+00:48:31,440 --> 00:48:33,840
+maximum ال plane اللي بيكون الشيء ال stress
+
+379
+00:48:33,840 --> 00:48:42,050
+maximum يعني أنا هكون عندي اثنين تاو xy sin two
+
+380
+00:48:42,050 --> 00:48:51,090
+phi تساوي minus sigma x minus sigma y cosine
+
+381
+00:48:51,090 --> 00:49:00,530
+two phi يعني أنا هكون عندي ten two phi هتكون
+
+382
+00:49:00,530 --> 00:49:06,800
+تساوي minus tau minus
+
+383
+00:49:06,800 --> 00:49:17,760
+cosine minus sigma x minus sigma y على اثنين tau
+
+384
+00:49:17,760 --> 00:49:24,280
+xy هذه
+
+385
+00:49:24,280 --> 00:49:25,480
+بتاعة ال shear stress
+
+386
+00:49:28,140 --> 00:49:35,700
+يعني ال tan ده متمثل ايه؟ slope صح؟ ال turn to phi
+
+387
+00:49:35,700 --> 00:49:40,820
+بتاعة ال principle stress بتاعة ال stress كانت
+
+388
+00:49:40,820 --> 00:49:47,560
+تساوي اثنين tau xy على sigma x minus sigma y صح؟
+
+389
+00:49:47,560 --> 00:49:55,790
+ادروا هدفها دي حكوا عن ده turn ال two phi بتاعة ال
+
+390
+00:49:55,790 --> 00:50:03,670
+shear بتختلف في تان ال two phi بتاعة ال stress تساوي
+
+391
+00:50:03,670 --> 00:50:11,190
+minus واحد معناته ال two phi angle بتاعة ال shear
+
+392
+00:50:11,190 --> 00:50:18,290
+stress متعامدة مع ال two phi angle بتاعة ال normal
+
+393
+00:50:18,290 --> 00:50:22,630
+stress لأن إذا يكون حاصل multiplication ل two
+
+394
+00:50:22,630 --> 00:50:27,210
+slopes الساقين سالب معناته متعامدين معناته الزاوية
+
+395
+00:50:27,210 --> 00:50:31,370
+بين two phi و two phi تسعين درجة مع phi و phi كم؟
+
+396
+00:50:31,370 --> 00:50:34,750
+خمسة و اربعين خمسة و اربعين لإنه بتتصف مع اثنين
+
+397
+00:50:34,750 --> 00:50:40,070
+معناته ال angle between
+
+398
+00:50:40,070 --> 00:50:44,930
+principle
+
+399
+00:50:48,910 --> 00:50:54,350
+principle planes and
+
+400
+00:50:54,350 --> 00:51:06,810
+planes of maximum shear is plus or minus خمسة و
+
+401
+00:51:06,810 --> 00:51:14,570
+اربعين درجة اللي
+
+402
+00:51:14,570 --> 00:51:15,230
+هي كجملة
+
+403
+00:51:23,060 --> 00:51:26,680
+إذا عوضت عن الزاوية هذه التي هي tan two phi بتاعة
+
+404
+00:51:26,680 --> 00:51:29,280
+ال shear stress بالصيغة sigma x minus sigma y
+
+405
+00:51:29,280 --> 00:51:32,980
+على اثنين tau x عوضتها في معادلة tau بيطلع ال
+
+406
+00:51:32,980 --> 00:51:36,600
+maximum shear stress tau واحد tau اثنين plus or
+
+407
+00:51:36,600 --> 00:51:39,580
+minus sigma x minus sigma y على اثنين لكل تربيع
+
+408
+00:51:39,580 --> 00:51:44,760
+زائد tau xy تربيع واضح؟
+
+409
+00:51:44,760 --> 00:51:47,780
+هنروح
+
+410
+00:51:47,780 --> 00:51:49,020
+على more circle
+
+411
+00:51:58,260 --> 00:52:02,840
+تطلع المعادلة هذه و تطلع فيها كويس تكتشف انها
+
+412
+00:52:02,840 --> 00:52:09,220
+اثنتين مع بعض بتمثل معادلة دائرة هدول مع بعض مع
+
+413
+00:52:09,220 --> 00:52:12,840
+معادلة دائرة كيف؟ لو أخدت ال Sigma اول معادلة حكيت
+
+414
+00:52:12,840 --> 00:52:19,660
+Sigma minus خليني
+
+415
+00:52:19,660 --> 00:52:24,460
+اسمى .. اسمى let
+
+416
+00:52:26,440 --> 00:52:36,160
+C تساوي Sigma X زائد Sigma Y على 2 يعني هذا اسميها C
+
+417
+00:52:36,160 --> 00:52:44,020
+حسن دي Sigma minus C بسوء
+
+418
+00:52:44,020 --> 00:52:56,420
+Sigma X minus Sigma Y على 2 Cos 2 Phi زائد tau xy
+
+419
+00:52:56,420 --> 00:53:04,660
+Sin two Phi والمعادلة الثانية tau بتساوي سيجما
+
+420
+00:53:04,660 --> 00:53:14,900
+X minus سيجما واي على اثنين Sin two Phi زائد tau 
+
+421
+00:53:14,900 --> 00:53:20,380
+اكس واي cosine two في خلينا نسمي هذه معادلة ثلاثة
+
+422
+00:53:20,380 --> 00:53:23,480
+هذه معادلة ايش أربع
+
+423
+00:53:32,140 --> 00:53:40,120
+تاو بالثالث صحيح هنا هكذا صحيح أنا هأحكي ثلاثة square
+
+424
+00:53:40,120 --> 00:53:45,940
+ربع المعادلة تاو زائد أربعة square اجمعهم اجمع
+
+425
+00:53:45,940 --> 00:53:49,260
+الشمال مع الشمال واللي يبقى مع اليمين هتكون هذه
+
+426
+00:53:49,260 --> 00:53:55,780
+ال sigma minus c لكل تربيع زائد تاو تربيع
+
+427
+00:53:59,580 --> 00:54:04,760
+زي الـ tau تربيع هتكون تساوي هذه التربيع زي هذه
+
+428
+00:54:04,760 --> 00:54:09,540
+التربيع الشياطينة نفس هيكون cos تربيع زي sin تربيع
+
+429
+00:54:09,540 --> 00:54:16,960
+واحد هيكون سيجما X minus سيجما Y على اثنين لكل
+
+430
+00:54:16,960 --> 00:54:23,300
+تربيع وهذه sin تربيع مع cos تربيع زي الـ tau XY
+
+431
+00:54:23,300 --> 00:54:24,080
+تربيع
+
+432
+00:54:27,980 --> 00:54:32,360
+زائد اثنين هذا في هذا زائد اثنين هذا في هذا يعني
+
+433
+00:54:32,360 --> 00:54:35,980
+عندما نقضي الحكاية على أي حاجة it will cancel out
+
+434
+00:54:35,980 --> 00:54:43,340
+لأن هنا سالب وهنا موجب هيك خلصنا معناته معادلة
+
+435
+00:54:43,340 --> 00:54:53,340
+الدائرة بشكل عام هي أي دائرة هي X Y هي دائرة هي
+
+436
+00:54:53,340 --> 00:55:05,510
+مركزها لو حكيتها دي Hوها دي ايش K الدائرة
+
+437
+00:55:05,510 --> 00:55:10,650
+اللي جاي في المركز بالظبط ايش معادلتها X تربيع زائد
+
+438
+00:55:10,650 --> 00:55:18,550
+Y تربيع سواء R تربيع الآن المركز معادلة الدائرة
+
+439
+00:55:18,550 --> 00:55:28,370
+هتكون X minus H لكل تربيع زائد y minus k كل تربيع
+
+440
+00:55:28,370 --> 00:55:33,690
+سواء R تربيع معناته
+
+441
+00:55:33,690 --> 00:55:42,250
+هذه معادلة هذول ال terms هأسميها يعني هأكون sigma
+
+442
+00:55:42,250 --> 00:55:51,210
+minus c لكل تربيع بتساوي R capital تربيع زائد تاو
+
+443
+00:55:51,210 --> 00:55:59,690
+تربيعSigma minus C كل تربيع زائد تاو تربيع So R
+
+444
+00:55:59,690 --> 00:56:09,850
+capital تربيع هذا معامل الدائرة مركزها جاي لو عملت
+
+445
+00:56:09,850 --> 00:56:13,670
+plot Sigma مع تاو Sigma مع تاو مركز جاي على ال X
+
+446
+00:56:13,670 --> 00:56:21,030
+axis يعني عندي هي عندي Sigma مع تاو هي ال C
+
+447
+00:56:24,700 --> 00:56:34,500
+و هذه الدائرة وهذا ايش ال R بتاعتها ال R بتاعتها
+
+448
+00:56:34,500 --> 00:56:39,800
+من
+
+449
+00:56:39,800 --> 00:56:50,820
+هنا جت ايش more circle هذه more circle
+
+450
+00:56:54,590 --> 00:57:02,110
+Mohr circle is a plot of shear stress versus
+
+451
+00:57:02,110 --> 00:57:07,350
+normal stress ال plot هذا يعني plot هذه ال
+
+452
+00:57:07,350 --> 00:57:14,590
+equation مع هذه ال equation بيعطينا دائرة مركزها
+
+453
+00:57:14,590 --> 00:57:21,630
+مواقع على محور ال sigma و يبعد C ال C كما احنا
+
+454
+00:57:21,630 --> 00:57:30,460
+حكيناسيجما اكس زي السيجما واي على اثنين أنا
+
+455
+00:57:30,460 --> 00:57:34,480
+اتوم more circle هاي
+
+456
+00:57:34,480 --> 00:57:40,300
+more circle هاي السيجما هاي التاو لو كنا نرسم more
+
+457
+00:57:40,300 --> 00:57:44,960
+circle كنا نعرف التاو هاد مثلا هاد التاو مع ال X
+
+458
+00:57:44,960 --> 00:57:46,940
+axis counter clockwise كنا نعرف ال counter
+
+459
+00:57:46,940 --> 00:57:52,340
+clockwise موجة يعني هاد يقول بيعملوا ايش بيعملوا
+
+460
+00:57:52,340 --> 00:57:59,560
+ازدواج موجب عندي هنا تاو counter clockwise و هنا
+
+461
+00:57:59,560 --> 00:58:06,240
+تاو clockwise طيب
+
+462
+00:58:06,240 --> 00:58:13,460
+نيجي ل more circle هأخلي
+
+463
+00:58:13,460 --> 00:58:26,270
+المعادلة عشان تعرفوا كيف أجتال .. ال issue عند
+
+464
+00:58:26,270 --> 00:58:33,810
+ال C سوى Sigma X زي Sigma Y على اثنين عند ال R
+
+465
+00:58:33,810 --> 00:58:40,290
+بسوى جزر التربيع ل Sigma X minus Sigma Y على اثنين
+
+466
+00:58:40,290 --> 00:58:45,930
+لكل تربيع زي تاو XY تربيع
+
+467
+00:58:53,120 --> 00:58:59,580
+هي مرسومة لأن عندي محورين محور السيجما محور التاو
+
+468
+00:58:59,580 --> 00:59:07,800
+عندي هنا تاو clockwise وهنا تاو counter clockwise
+
+469
+00:59:07,800 --> 00:59:14,380
+عندي stress element سيجما
+
+470
+00:59:14,380 --> 00:59:14,820
+x
+
+471
+00:59:22,190 --> 00:59:27,490
+و tau xy وعندي
+
+472
+00:59:27,490 --> 00:59:33,710
+سيجما y على المستوى
+
+473
+00:59:33,710 --> 00:59:39,450
+هذا فبالتالي سيجما x و tau xy counter clockwise tau
+
+474
+00:59:39,450 --> 00:59:44,150
+xy جاي counter clockwise مع سيجما x فبروح أعمل آخذ
+
+475
+00:59:44,150 --> 00:59:50,370
+أول نقطة هذه هذه
+
+476
+00:59:50,370 --> 00:59:51,050
+عبارة عن ايه
+
+477
+00:59:54,780 --> 01:00:06,080
+سيجما x سيجما
+
+478
+01:00:06,080 --> 01:00:15,800
+x وهذه المسافة تاو x
+
+479
+01:00:15,800 --> 01:00:17,280
+واي نقطة
+
+480
+01:00:20,430 --> 01:00:28,950
+على المستوى هذا عندي سيجما y و tau xy clockwise هأكون
+
+481
+01:00:28,950 --> 01:00:41,710
+عندي هي سيجما y و
+
+482
+01:00:41,710 --> 01:00:44,230
+هي tau xy
+
+483
+01:00:57,770 --> 01:01:03,710
+هذه سيجما y وهذه
+
+484
+01:01:03,710 --> 01:01:08,770
+سيجما x فهذه المسافة كم الفرق بينهم سيجما x minus
+
+485
+01:01:08,770 --> 01:01:15,930
+سيجما y  مص
+
+486
+01:01:15,930 --> 01:01:16,830
+المسافة هذه
+
+487
+01:01:23,860 --> 01:01:29,460
+اللي هي سيجما x minus سيجما y على اثنين صح مش هذا
+
+488
+01:01:29,460 --> 01:01:32,880
+سيجما x تنقص سيجما y نصها هأكون سيجما x minus سيجما
+
+489
+01:01:32,880 --> 01:01:37,320
+y على اثنين لأن نص هذا لو أجبع مع سيجما y يعني
+
+490
+01:01:37,320 --> 01:01:46,320
+سيجما x minus سيجما y على اثنين زي سيجما y سيجما y
+
+491
+01:01:46,320 --> 01:01:51,660
+عبارة عن اثنين سيجما y على اثنين صح يعني اثنين يعني
+
+492
+01:01:51,660 --> 01:01:57,250
+هأكون عندي اثنين سيجما x ماينس سيجما واي زائد
+
+493
+01:01:57,250 --> 01:02:03,070
+اثنين سيجما واي يعني هيصف ايش سيجما x زائد سيجما
+
+494
+01:02:03,070 --> 01:02:09,930
+واي على اثنين معناته هذه النقطة هتكون
+
+495
+01:02:09,930 --> 01:02:18,890
+سيجما x زائد سيجما واي على اثنين اللي هو ايش ده
+
+496
+01:02:18,890 --> 01:02:22,590
+ال center تعمر circle هذا ال center
+
+497
+01:02:27,210 --> 01:02:34,010
+طيب احنا حكينا هذه ال tau xy وهذه المسافة سيجما x
+
+498
+01:02:34,010 --> 01:02:38,990
+و سيجما x minus سيجما y هذه المسافة معناته تقول
+
+499
+01:02:38,990 --> 01:02:44,450
+أخذت المثلث القائم الزوايا هذه الطول ايش هيكون هذه
+
+500
+01:02:44,450 --> 01:02:49,650
+الجديد تربيع هذه تربيع زي جديد تربيع اللى هذه
+
+501
+01:02:49,650 --> 01:02:50,670
+هذه هتكون R
+
+502
+01:03:18,620 --> 01:03:25,580
+النقطة الثانية هي نقطة A وهي نقطة B A بتمثل
+
+503
+01:03:25,580 --> 01:03:26,380
+المستوى هذا
+
+504
+01:03:29,210 --> 01:03:33,870
+و B المستوى هذا الزاوية بين المستوى هذا و المستوى
+
+505
+01:03:33,870 --> 01:03:40,410
+هذا في أرض الواقع تسعين لكن أنا بتعامل مع two five
+
+506
+01:03:40,410 --> 01:03:47,550
+تسعين زاوية بينهم ايش مئة وعشرين درجة يعني هذه تمثل
+
+507
+01:03:47,550 --> 01:03:56,150
+ال X axis وهذه ال Y axis وهذه الزاوية بينهم مئة و
+
+508
+01:03:56,150 --> 01:03:58,350
+عين درجة اللي هي two five واضح
+
+509
+01:04:11,940 --> 01:04:15,640
+احنا حاولنا ال principal stresses أو ال stress
+
+510
+01:04:15,640 --> 01:04:23,280
+بيكون principal لما ال shear stress بيكون يساوي صفر
+
+511
+01:04:23,280 --> 01:04:28,160
+معناته هذه مثل
+
+512
+01:04:28,160 --> 01:04:32,800
+سيجما one one principal stress وهذه سيجما two
+
+513
+01:04:32,800 --> 01:04:36,000
+another principal stress ليش عند النقطة هذه share
+
+514
+01:04:36,000 --> 01:04:43,190
+stress بيساوي shear stress zero مظبوط؟ الشير ال
+
+515
+01:04:43,190 --> 01:04:55,050
+stress بيكون زاوية zero طيب
+
+516
+01:04:55,050 --> 01:05:00,770
+واضح
+
+517
+01:05:00,770 --> 01:05:07,370
+ان سيجما one بيساوي ال center زائد ال radius صح؟
+
+518
+01:05:07,370 --> 01:05:16,270
+سيجما one بيساوي ال center زائد ال radius وال
+
+519
+01:05:16,270 --> 01:05:22,790
+سيجما two بيساوي ال center ناقص ال radius سيجما
+
+520
+01:05:22,790 --> 01:05:28,410
+two بيساوي ال center minus ال radius وال center
+
+521
+01:05:28,410 --> 01:05:32,990
+احنا we defined اللي هو سيجما x زائد سيجما y على
+
+522
+01:05:32,990 --> 01:05:37,850
+اثنينو ال radius اللي هو square root ل سيجما x
+
+523
+01:05:37,850 --> 01:05:43,490
+minus سيجما y على اثنين لكل تربيع زي ال tau xy
+
+524
+01:05:43,490 --> 01:05:49,210
+تربيع طيب
+
+525
+01:05:49,210 --> 01:05:54,290
+ال phi b أو الزاوية اللي بتعرفلي ال principle
+
+526
+01:05:54,290 --> 01:05:59,850
+plane هاي ال x axis مش هذا principle معناته
+
+527
+01:05:59,850 --> 01:06:05,910
+principal stress اه هذه لل stress لل strength اه
+
+528
+01:06:05,910 --> 01:06:11,650
+هذه لل normal stress هذه الزاوية هتكون اللي هي
+
+529
+01:06:11,650 --> 01:06:23,790
+اثنين فاي principal لاحظوا ten ten طالعين اثنين ten
+
+530
+01:06:23,790 --> 01:06:28,970
+اثنين في بي هيها هذه في بي
+
+531
+01:06:32,710 --> 01:06:41,250
+بساوية هذه المسافة اللي هي ايه؟ tau xy على
+
+532
+01:06:41,250 --> 01:06:48,130
+هذه اللي هي سيجما x minus سيجما y على
+
+533
+01:06:48,130 --> 01:06:58,330
+اثنين مظبوط كلام صح؟ طيب معناته
+
+534
+01:06:58,330 --> 01:07:03,000
+في الحالة هذه عشان object of principle stress بدي
+
+535
+01:07:03,000 --> 01:07:07,880
+من ال positive x axis أدور بزاوية في بي يعني إذا
+
+536
+01:07:07,880 --> 01:07:13,920
+هذا هو ال positive x axis إذا هذا هو ال positive x
+
+537
+01:07:13,920 --> 01:07:18,700
+axis بدي
+
+538
+01:07:18,700 --> 01:07:24,480
+أدور بزاوية في
+
+539
+01:07:24,480 --> 01:07:28,360
+بي وارسم
+
+540
+01:07:28,360 --> 01:07:37,790
+element هذه سيكون علي سيجما واحد وهذه
+
+541
+01:07:37,790 --> 01:07:46,370
+سيجما واحد وهذه
+
+542
+01:07:46,370 --> 01:07:52,210
+سيجما اثنين لأن الزرع بين سيجما واحد هنا وسيجما
+
+543
+01:07:52,210 --> 01:07:57,130
+اثنين هنا الزرع بينهم 180 درجة معناته سيكون سيجما
+
+544
+01:07:57,130 --> 01:08:06,650
+اثنين متعامد عليه في شير طبعا في شير 5B ولا 2 5B
+
+545
+01:08:06,650 --> 01:08:10,590
+يا دكتور؟ أنا هي 2 5B لكن لما ارسم ال stress
+
+546
+01:08:10,590 --> 01:08:14,410
+element اللي عندي ال normal stresses اللي بتكون
+
+547
+01:08:14,410 --> 01:08:19,930
+maximum برسم 5B بحسب ال 2 5B بعدين منها بحسب ال 5B
+
+548
+01:08:25,400 --> 01:08:29,900
+عشان أعرف هذه النقطة هتكون سيجما x و tau xy
+
+549
+01:08:29,900 --> 01:08:37,800
+counter clockwise وهذه سيجما y و tau xy clockwise
+
+550
+01:08:37,800 --> 01:08:45,000
+واضحت
+
+551
+01:08:45,000 --> 01:08:49,560
+ايش هي more circle؟ هذا مهم كثير أنا عشان ايك فصلت
+
+552
+01:08:49,560 --> 01:08:55,820
+فيه لإني بدي تكون فاهم ما تتعاملش مع ال circle بس
+
+553
+01:08:55,820 --> 01:08:59,600
+اعمل كذا وارسم كذا وكذا تا و تنساها، لكي تعرف
+
+554
+01:08:59,600 --> 01:09:06,200
+الأساس تاعها ال definition
+
+555
+01:09:06,200 --> 01:09:11,600
+.. ال definition تاع ال shear stress ال definition
+
+556
+01:09:11,600 --> 01:09:16,740
+تاع الشير stress بعتبر لتحت counter clockwise و
+
+557
+01:09:16,740 --> 01:09:22,100
+لفوق clockwise واضح يعني بعتبر counter clockwise
+
+558
+01:09:22,100 --> 01:09:25,740
+shear stress لتحت counter clockwise negative
+
+559
+01:09:25,740 --> 01:09:30,740
+clockwise ايش positive هذا shear stress لكن angles
+
+560
+01:09:30,740 --> 01:09:37,080
+أنا I'm rotating rotating
+
+561
+01:09:37,080 --> 01:09:41,480
+أكم تسعين درجة يعني أنا مثلاً هندي هاي الـ X axis
+
+562
+01:09:41,480 --> 01:09:51,610
+هاي المستوى هذا إذا لفيت الـ X axis تسعين درجة بعكس
+
+563
+01:09:51,610 --> 01:09:56,450
+عقار بالسيعة بيعطينا المستقبل هذا اللي مبين عندي
+
+564
+01:09:56,450 --> 01:10:05,250
+هنا 180 درجة وضحت ف أنا بلف صح عشان أوصل الـ X axis
+
+565
+01:10:05,250 --> 01:10:09,450
+لفيت تسعين درجة عشان أوصل الـ principle معناته أنا
+
+566
+01:10:09,450 --> 01:10:17,620
+لفيت زي هيك هذه مثلات positive تسعين لفت هك 25D
+
+567
+01:10:17,620 --> 01:10:28,460
+counter clockwise نشوف
+
+568
+01:10:28,460 --> 01:10:28,960
+مثال
+
+569
+01:10:50,030 --> 01:10:58,470
+Find Stress Element علي
+
+570
+01:10:58,470 --> 01:11:07,750
+Normal Stress Sigma X Sigma
+
+571
+01:11:07,750 --> 01:11:13,170
+X بالستة و ثمانين ميجا باسكال And Clockwise
+
+572
+01:11:20,290 --> 01:11:27,210
+تاو XY بستوى خمسين ميجاباسكال using Mohr's circle
+
+573
+01:11:27,210 --> 01:11:30,430
+find principal stresses and directions and show a
+
+574
+01:11:30,430 --> 01:11:32,870
+stress element correctly aligned with respect to
+
+575
+01:11:32,870 --> 01:11:43,850
+XY coordinates حرصوا الـ Mohr's circle عند
+
+576
+01:11:43,850 --> 01:11:51,180
+هي سيجما هي تاو على الـ surface هذا الـ sigma x 80
+
+577
+01:11:51,180 --> 01:11:55,400
+هل هذا clockwise أو counter clockwise؟ معناته
+
+578
+01:11:55,400 --> 01:12:03,550
+التوحد كل أعلى عشان نعمل تقسيمة هي عشرة عشرين
+
+579
+01:12:03,550 --> 01:12:11,470
+ثلاثين أربعين خمسين ستين سبعين ثمانين وعندي عشرة
+
+580
+01:12:11,470 --> 01:12:19,810
+عشرين ثلاثين أربعين خمسين عشرة عشرين ثلاثين أربعين
+
+581
+01:12:19,810 --> 01:12:22,610
+خمسين ستين
+
+582
+01:12:30,350 --> 01:12:36,690
+عندي المستوى هذا سيجما اكس ثمانين واحد اثنين ثلاثة
+
+583
+01:12:36,690 --> 01:12:43,670
+أربع خمس ستة سبعة وثمانية والتاو Clockwise هتكون
+
+584
+01:12:43,670 --> 01:12:50,970
+الأعلى خمسين خليني 
+
+585
+01:12:50,970 --> 01:12:51,990
+امسح الـ stress element
+
+586
+01:12:59,380 --> 01:13:06,060
+هذه النقطة النقطة الثانية على المستوى هذا الـ
+
+587
+01:13:06,060 --> 01:13:14,160
+Sigma Y Zero هذه Zero مع خمسين لتحت هذه واحد،
+
+588
+01:13:14,160 --> 01:13:18,300
+اثنين، ثلاثة، أربعة، خمسة هذه النقطة الثانية لأن
+
+589
+01:13:18,300 --> 01:13:26,120
+مصل بينهم هذا
+
+590
+01:13:26,120 --> 01:13:32,980
+الـ Center طبعاً واضح الـ center هيكون سيجما X زي
+
+591
+01:13:32,980 --> 01:13:44,100
+سيجما Y على 2 اللي هو هيكون أربعين ميجا باسكال هاي
+
+592
+01:13:44,100 --> 01:13:49,180
+الـ center هرسماش المار
+
+593
+01:13:49,180 --> 01:13:50,200
+سيركل
+
+594
+01:13:57,550 --> 01:14:06,670
+هذا واضح الـ X Axis صح وهذا الـ Y Axis هذا
+
+595
+01:14:06,670 --> 01:14:14,550
+الـ X Axis وهذا الـ Y Axis هذا
+
+596
+01:14:14,550 --> 01:14:17,950
+Tau
+
+597
+01:14:17,950 --> 01:14:29,680
+XY وهذا F Sigma X ناقص Sigma Y على اثنين وهذه two
+
+598
+01:14:29,680 --> 01:14:40,660
+five P تان two five P بتساوي تاو X Y اللي هو خمسين
+
+599
+01:14:40,660 --> 01:14:45,120
+على
+
+600
+01:14:45,120 --> 01:14:51,020
+سيجما X ناقص سيجما Y على اثنين على أربعين صح و أنا
+
+601
+01:14:51,020 --> 01:14:55,800
+بحسب two five P اسبوليها ايش تطلع حد اسبولي two
+
+602
+01:14:55,800 --> 01:14:56,540
+five P على السريع
+
+603
+01:15:13,400 --> 01:15:19,080
+الراديوس هيكون الجذر التربيعي لـ سيجما X ناقص
+
+604
+01:15:19,080 --> 01:15:25,780
+سيجما Y على اثنين لكل تربيع زائد تاو XY تربيع يعني
+
+605
+01:15:25,780 --> 01:15:33,440
+هيكون الجذر التربيعي لأربعين تربيع زائد خمسين
+
+606
+01:15:33,440 --> 01:15:40,540
+تربيع هيساوي الـ
+
+607
+01:15:40,540 --> 01:15:44,750
+two phi بيئة كم؟ خمسة و خمسين واحد و خمسين واحد 
+
+608
+01:15:44,750 --> 01:15:45,710
+و خمسين واحد و خمسين واحد و خمسين واحد و خمسين
+
+609
+01:15:45,710 --> 01:15:46,270
+واحد و خمسين واحد و خمسين واحد و خمسين
+
+610
+01:15:46,270 --> 01:15:54,510
+و خمسين واحد و خمسين واحد و خمسين واحد و
+
+611
+01:15:54,510 --> 01:15:59,350
+خمسين واحد و خمسين واحد و خمسين واحد و خمسين
+
+612
+01:15:59,350 --> 01:15:59,770
+و خمسين واحد و خمسين واحد و خمسين واحد و خمسين
+
+613
+01:15:59,770 --> 01:16:00,130
+و خمسين واحد و خمسين واحد و خمسين واحد و خمسين
+
+614
+01:16:00,130 --> 01:16:06,290
+واحد و
+
+615
+01:16:06,290 --> 01:16:06,310
+خ
+
+616
+01:16:10,830 --> 01:16:17,290
+أربعة و ستين بوينت أربعة و ستين بوينت ميجا باسكال
+
+617
+01:16:17,290 --> 01:16:24,150
+ميجا باسكال الآن أنا محتمش طالما ورجيتك الـ phi بي
+
+618
+01:16:24,150 --> 01:16:28,710
+graphically الإشارات لا تعني شيء أنا اسمه حتى إن
+
+619
+01:16:28,710 --> 01:16:32,590
+أنا حاكي نيجاتيف ماشي أنا بحكيلك هاي الـ phi بي
+
+620
+01:16:32,590 --> 01:16:38,170
+بتحكيلي نيجاتيف الشوف
+
+621
+01:16:38,170 --> 01:16:45,820
+مش زي السماع صح؟ يختلف فعندي الـ 5P الآن هارسم الـ
+
+622
+01:16:45,820 --> 01:16:50,400
+stress element هاي
+
+623
+01:16:50,400 --> 01:16:53,440
+الـ stress element التبعي أنا همشي Clockwise
+
+624
+01:16:53,440 --> 01:17:00,640
+بالزاوية 25 درجة هاي الـ X axis همشي
+
+625
+01:17:00,640 --> 01:17:09,680
+زاوية 25.65 degrees هرسم stress element
+
+626
+01:17:13,200 --> 01:17:24,200
+هنا سيجما واحد وهنا سيجما اثنين الآن
+
+627
+01:17:24,200 --> 01:17:30,620
+سيجما واحد في الساعة الـ C زاد الـ radius صح الـ C
+
+628
+01:17:30,620 --> 01:17:35,420
+اللي هو أربعين زاد أربعة و ستين بوينت O ثلاثة يعني
+
+629
+01:17:35,420 --> 01:17:42,160
+مئة وأربعة بوينت O ثلاثة هندي مئة وأربعة بوينت O
+
+630
+01:17:42,160 --> 01:17:50,650
+ثلاثة و ال sigma two هتكون الـ
+
+631
+01:17:50,650 --> 01:17:57,870
+sigma two بالساوية C ناقص R الـ C اللي هي أربعين
+
+632
+01:17:57,870 --> 01:18:04,190
+ناقص أربع ستين بوينت O ثلاثة هتكون ناقص أربع و
+
+633
+01:18:04,190 --> 01:18:11,650
+عشرين بوينت O ثلاثة صحيح ميجا باسكال يعني هتكون
+
+634
+01:18:11,650 --> 01:18:20,900
+compression هتكون عندها compression سيجما
+
+635
+01:18:20,900 --> 01:18:28,240
+التول هي minus 24 بوينت O ثلاثة ميجاباسكال هذا هو
+
+636
+01:18:28,240 --> 01:18:32,880
+الـ stress element اللي
+
+637
+01:18:32,880 --> 01:18:38,940
+بيكون عند الـ stress is principal و كنت احكي الـ
+
+638
+01:18:38,940 --> 01:18:47,370
+maximum شير الـ stress التاو maximum بيساوي
+
+639
+01:18:47,370 --> 01:18:50,970
+الـ
+
+640
+01:18:50,970 --> 01:18:55,110
+radius أو
+
+641
+01:18:55,110 --> 01:19:03,490
+بيساوي السيجما واحد ناقص السيجما اثنين على اثنين
+
+642
+01:19:08,560 --> 01:19:16,560
+مئة وأربعة بوينت o ثلاثة ناقص ناقص أربعة و
+
+643
+01:19:16,560 --> 01:19:26,780
+عشرين بوينت o ثلاثة على اثنين ايه كم يطلع أربعة و
+
+644
+01:19:26,780 --> 01:19:37,390
+ستين بوينت o ثلاثة ميجا باسكال هذا الـ tau max الـ
+
+645
+01:19:37,390 --> 01:19:45,710
+tau max بيعمل plus or minus plus
+
+646
+01:19:45,710 --> 01:19:51,430
+or minus زاوية خمسة وأربعين يعني أنا عندي هاي ..
+
+647
+01:19:51,430 --> 01:19:54,930
+هاي الـ direction بتاع الـ principle stress فاندي
+
+648
+01:19:54,930 --> 01:19:59,050
+واحدة counter clockwise هلف زاوية تسعين درجة اثنين
+
+649
+01:19:59,050 --> 01:20:03,890
+في و أنا هلف زاوية خمسة وأربعين هج من هذا
+
+650
+01:20:07,080 --> 01:20:17,380
+هذه الزاوية خمسة وأربعين وهذه الـ stress element
+
+651
+01:20:17,380 --> 01:20:25,700
+هنا الـ fit clockwise هتعطي تو counter clockwise
+
+652
+01:20:25,700 --> 01:20:28,760
+هكون
+
+653
+01:20:28,760 --> 01:20:33,580
+بالضبط
+
+654
+01:20:33,580 --> 01:20:40,510
+هكذا اللي هي tau maximum
+
+655
+01:20:40,510 --> 01:20:46,770
+طبعاً
+
+656
+01:20:46,770 --> 01:20:52,970
+عند الـ tau maximum بيكون فيه normal stress ايش
+
+657
+01:20:52,970 --> 01:20:56,670
+قيمته لأ
+
+658
+01:20:56,670 --> 01:21:07,310
+ايه sigma x زي sigma y اثنين بتكون عندها stress اللي
+
+659
+01:21:07,310 --> 01:21:13,370
+هي عند أربعين وهي
+
+660
+01:21:13,370 --> 01:21:17,750
+عند stress عند
+
+661
+01:21:17,750 --> 01:21:20,990
+ال maximum share stress planes بيكونش non stress
+
+662
+01:21:20,990 --> 01:21:24,690
+بالزاوية zero بيكون فيه non stress وهي عند هاي tau
+
+663
+01:21:24,690 --> 01:21:33,170
+max ها دي tau, tau max هذه قيمة الـ stress هذه اللي
+
+664
+01:21:33,170 --> 01:21:36,930
+هي sigma x زي sigma y على اثنين اللي هي الـ center
+
+665
+01:21:36,930 --> 01:21:53,510
+طبعاً
+
+666
+01:21:53,510 --> 01:21:57,770
+الـ norm stress هذا كما لو في الحالة هذه كما لو
+
+667
+01:22:00,870 --> 01:22:05,430
+بيكون كما لو أن الـ element محتوظ في مية المية اللي
+
+668
+01:22:05,430 --> 01:22:09,990
+بتحط فيها أشهر تضغط عليها من كل الجهات بس هين هين
+
+669
+01:22:09,990 --> 01:22:12,550
+أنا ضاغط في اتجاه الموج يعني بسحب هين و بسحب هين
+
+670
+01:22:12,550 --> 01:22:16,610
+فالـ prize ratio effect بالتغفل حالة هذه لو أنا
+
+671
+01:22:16,610 --> 01:22:21,070
+بسحب زي هيك بيحاول يرفع هذا بسحب معاكس و نفس
+
+672
+01:22:21,070 --> 01:22:25,290
+القيمة بلغي الأثر تبعه فلو كون أشهر محوط من كل
+
+673
+01:22:25,290 --> 01:22:30,140
+الجهات بالمية بيكون ضغط من كل الجهات ففيش
+
+674
+01:22:30,140 --> 01:22:36,960
+deformation في الـ ..في الاتجاه العمودي على السطح
+
+675
+01:22:36,960 --> 01:22:41,200
+عشان يسموه hydrostatic element هذا هيجورنا مستقبلاً
+
+676
+01:22:41,200 --> 01:22:47,000
+للي هي الـ maximum shear أو الـ maximum distortion
+
+677
+01:22:47,000 --> 01:22:53,220
+energy theory معظم الـ energy اللي بتروح في الـ
+
+678
+01:22:53,220 --> 01:22:58,020
+deformation بتروح على شكل distortion يعني بتغير
+
+679
+01:22:58,020 --> 01:23:03,500
+الشكل لكن متغيرش الـ dimensions هيك إنكم خلصنا
+
+680
+01:23:03,500 --> 01:23:04,420
+المحاضرة
+
+681
+01:23:10,730 --> 01:23:13,230
+لأ أنا حاكتش counter clockwise أنا حاكت Clockwise
+
+682
+01:23:13,230 --> 01:23:17,230
+طبعاً maximum أنا هادي إذا بدأ بدأ هاي الـ principle
+
+683
+01:23:17,230 --> 01:23:21,830
+هاي الـ principle إذا بدأ اروح زي هيك هاروح counter
+
+684
+01:23:21,830 --> 01:23:28,190
+clockwise خمسة وأربعين اللي هو هادي اللي هي هادي
+
+685
+01:23:28,190 --> 01:23:33,790
+هتكون ايه؟ Clockwise لكن أنا شوفت أسهل أمشي من
+
+686
+01:23:33,790 --> 01:23:37,190
+هادي Clockwise
+
+687
+01:23:38,690 --> 01:23:41,550
+خمسة فمشيت من هنا لأن أنا قرصت ماشي في تجاه معين
+
+688
+01:23:41,550 --> 01:23:44,390
+ماقدرش أقربش حالي فمشيت هيك خمسة وأربعين Clockwise
+
+689
+01:23:44,390 --> 01:23:50,630
+رفت المصطلح هذا هد حاكم عليهاش counter clockwise
+
+690
+01:23:50,630 --> 01:23:56,550
+بيعني أنت بتاعي حاكم عليه Clockwise أعطيكوا 
+
+691
+01:23:56,550 --> 01:23:56,750
+العفو 
diff --git a/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/zPhrosq6KF8_raw.srt b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/zPhrosq6KF8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..781ff5ca2cc896c1d9338f9b590ae7153f91c92e
--- /dev/null
+++ b/PL9fwy3NUQKwa2X-pioSkZED6Y37BsLOeR/zPhrosq6KF8_raw.srt
@@ -0,0 +1,2772 @@
+1
+00:00:05,380 --> 00:00:08,440
+السلام عليكم ورحمة الله وبركاته بسم الله الرحمن
+
+2
+00:00:08,440 --> 00:00:12,640
+الرحيم اليوم هنستكمل chapter three اللي هو load
+
+3
+00:00:12,640 --> 00:00:17,320
+and stress analysis اللي في المحاضرة الفاتتة غطينا
+
+4
+00:00:17,320 --> 00:00:21,500
+ال bending and ال .. ال shear و ال bending moment
+
+5
+00:00:21,500 --> 00:00:27,200
+diagrams حلينا بالطريقة التقليدية حددنا ال sign
+
+6
+00:00:27,200 --> 00:00:29,640
+convention لل positive moment و ال sign convention
+
+7
+00:00:29,640 --> 00:00:35,340
+لل positive and negative shearحكينا في علاقة بين
+
+8
+00:00:35,340 --> 00:00:40,200
+ال shear stress و ال moment ال V بيستوى DM by DX و
+
+9
+00:00:40,200 --> 00:00:46,560
+ال Q بيستوى DV by DX حلينا example بالطريقة
+
+10
+00:00:46,560 --> 00:00:51,580
+التقليدية انه ناخد summation of forces و الموجودة
+
+11
+00:00:51,580 --> 00:00:55,620
+ال reactions بعدين ناخد section نعمل free body
+
+12
+00:00:55,620 --> 00:00:57,820
+diagram و نحسب ال shear و ال bending moment
+
+13
+00:00:57,820 --> 00:01:00,740
+diagram منه رسمنا ال shear و ال moment diagram
+
+14
+00:01:02,770 --> 00:01:07,130
+بعدين استخدمنا ال singularity functions عشان نوجد
+
+15
+00:01:07,130 --> 00:01:10,390
+ال reactions و نوجد ال shear و ال bending moment
+
+16
+00:01:10,390 --> 00:01:17,370
+diagrams حلنا example تلت تلتة اليوم هنكمل برضه
+
+17
+00:01:17,370 --> 00:01:23,450
+مراجعة لمادة ال mechanics of material انبين اندي
+
+18
+00:01:23,450 --> 00:01:30,260
+stress elementstress element هذا قد يكون نقطة في
+
+19
+00:01:30,260 --> 00:01:34,180
+mechanical member في machine يعني ال stress في ال
+
+20
+00:01:34,180 --> 00:01:40,320
+.. في النهاية ناتج عن أحمال سواء كانت أحمال يعني
+
+21
+00:01:40,320 --> 00:01:48,180
+مفردة يعني زي حمل شد أو compression أو حمل ثاني أو
+
+22
+00:01:48,180 --> 00:01:54,850
+حمل lay أو حمل shearأو أحمل مراكبة، مع مراكبة شير
+
+23
+00:01:54,850 --> 00:02:00,350
+على axial على bending على .. على torsion في
+
+24
+00:02:00,350 --> 00:02:02,830
+النهاية هيتولى ال end stresses ال most general
+
+25
+00:02:02,830 --> 00:02:07,200
+case لل stress elementان يكون عليه كل stress
+
+26
+00:02:07,200 --> 00:02:10,020
+موجودة في كل اتجاهات انا عندي هنا small stress
+
+27
+00:02:10,020 --> 00:02:16,840
+element هذا هو ال X axis Y Z انا عندي Sigma X
+
+28
+00:02:16,840 --> 00:02:22,940
+Sigma Y Sigma Z وعندي على كل سطح سطح فيه two
+
+29
+00:02:22,940 --> 00:02:28,500
+components لل share اذا انا عندي السطح هذا عندي ال
+
+30
+00:02:28,500 --> 00:02:39,120
+X ال Y ال Zالان كيف بنسمي تسمية الشير stress سطح
+
+31
+00:02:39,120 --> 00:02:44,920
+عليه two components component موازية لل z axis
+
+32
+00:02:44,920 --> 00:02:52,560
+component موازية لل x axis لل y axis الان بعرف
+
+33
+00:02:52,560 --> 00:03:04,100
+الشير تاو مثلا عندي تاو اكس زد ال X مثل
+
+34
+00:03:06,860 --> 00:03:19,120
+المحور المتعمد على المستوى تحت الدراسة أنا بحكي
+
+35
+00:03:19,120 --> 00:03:23,440
+المستوى هذا صح؟ المتعمد عليه إيه إيش؟ ال X axis
+
+36
+00:03:23,440 --> 00:03:31,200
+فهي عندي ال X ال Z اللي هي .. اللي هو direction
+
+37
+00:03:36,260 --> 00:03:44,940
+parallel to shear stress component
+
+38
+00:03:44,940 --> 00:03:54,180
+يعني لما نحكي tau xz هي مراكبة ال shear اللي وقع
+
+39
+00:03:54,180 --> 00:04:00,540
+في المستوى المتعمد على ال x axis موازية لل z يعني
+
+40
+00:04:00,540 --> 00:04:02,880
+احنا هنا هتكون عندي هذه
+
+41
+00:04:07,450 --> 00:04:18,570
+Tau X Z هي موازية لل Z وعندي Tau X
+
+42
+00:04:18,570 --> 00:04:25,090
+Y مثلا المستوى هذه أول أول شي عند حكومة ال Y عندي
+
+43
+00:04:25,090 --> 00:04:32,690
+هذه Tau هي ال direction عمود على المستوى بالمناسبة
+
+44
+00:04:32,690 --> 00:04:37,940
+المستوى دائما يعرف بإيشبالمتعمد عليه بالعمودي عليه
+
+45
+00:04:37,940 --> 00:04:45,500
+تاو Y X وعندي
+
+46
+00:04:45,500 --> 00:04:51,580
+تاو Y Z لأن هو هي عمودي على المستوى معرف بال
+
+47
+00:04:51,580 --> 00:04:56,520
+Normal عليه اللي هو ال Y موازن ل Z Axis تاو Y X
+
+48
+00:04:56,520 --> 00:04:59,620
+المستوى
+
+49
+00:04:59,620 --> 00:05:03,660
+هذا معرف بالعمود عليه اللي هو ال Y Axis و هو في
+
+50
+00:05:03,660 --> 00:05:09,580
+اتجاه ال X Axisعندي هين المستوهة ده متعمدة على ال
+
+51
+00:05:09,580 --> 00:05:18,040
+z axis فهيبدأ tau z موازية ال y عندي هين tau
+
+52
+00:05:18,040 --> 00:05:23,880
+المستوهة ده عمودي على ال z موازية ال x axis
+
+53
+00:05:25,890 --> 00:05:29,010
+بالاضافة لـ Normal Stress Components اللي هو Sigma
+
+54
+00:05:29,010 --> 00:05:49,570
+X و Sigma Y و Sigma Z هندرس
+
+55
+00:05:49,570 --> 00:05:52,750
+الحالة اللي هي تمثل لـ Plain Stress Case
+
+56
+00:05:55,980 --> 00:06:01,680
+بكون عندى plan stress يعني stress في بعضين او في
+
+57
+00:06:01,680 --> 00:06:06,220
+مستوى اذا كانت ال stresses on one surface are zero
+
+58
+00:06:06,220 --> 00:06:12,420
+يعني هاي ال X Y Z لو كانت ال stresses على المستوى
+
+59
+00:06:12,420 --> 00:06:18,400
+هذا المتعود على Z axis ال sigma Z والتوزيد X
+
+60
+00:06:18,400 --> 00:06:23,650
+والتوزيد Y بتستوى Zero بعتبرهاa case of planned
+
+61
+00:06:23,650 --> 00:06:27,210
+stress ال case of planned stress عندى هاي ال x
+
+62
+00:06:27,210 --> 00:06:35,530
+axis هاي ال y axis عندى sigma x sigma y tau xy tau
+
+63
+00:06:35,530 --> 00:06:43,480
+xy tau xy tau xyهاد case و plan stress اللي هو zx
+
+64
+00:06:43,480 --> 00:06:47,580
+زعمودي على الصفحه sigma z بالساوية zero و sigma zx
+
+65
+00:06:47,580 --> 00:06:52,800
+بالساوية zero او tau zx و tau zy بالساوية zero
+
+66
+00:06:52,800 --> 00:07:02,420
+هناخد
+
+67
+00:07:02,420 --> 00:07:13,250
+الحالة ل plan stress case بدي اشوفالـ stresses at
+
+68
+00:07:13,250 --> 00:07:18,410
+any other plane مش موازي لل X-axis يعني مش موازي
+
+69
+00:07:18,410 --> 00:07:20,950
+أو متعدد لل X-axis يعني انا ماخد حلقة هاي مستوى
+
+70
+00:07:20,950 --> 00:07:24,290
+عمود على ال X-axis وهي مستوى عمود على ال Y-axis
+
+71
+00:07:24,290 --> 00:07:28,310
+what if اذا كان عندي مستوى ميل رأينا هنا اندي ان
+
+72
+00:07:28,310 --> 00:07:37,390
+هاي ال X-axis ماخد مستوى ميل بزاوية Phi مع ال Y
+
+73
+00:07:37,390 --> 00:07:47,650
+-axisطبعا على المستوى هذا يوجد stress sigma x و
+
+74
+00:07:47,650 --> 00:08:00,090
+stress tau xy على المستوى هذا يوجد sigma y و tau
+
+75
+00:08:00,090 --> 00:08:06,170
+xy على المستوى المائي اللي حيكون عندي stress more
+
+76
+00:08:06,170 --> 00:08:07,110
+than stress component
+
+77
+00:08:10,500 --> 00:08:17,960
+سيجما وشير السترس كومبوننت تاو طبعا الزاوية هدا
+
+78
+00:08:17,960 --> 00:08:22,860
+هتكون إيه؟ في
+
+79
+00:08:22,860 --> 00:08:29,940
+لإن هدا في هدا هتكون تسعين ناقص في صح؟ هدا في
+
+80
+00:08:29,940 --> 00:08:33,300
+معناته تسعين ناقص في معناته هدا إيه؟ في
+
+81
+00:08:43,630 --> 00:08:55,310
+لأن هذه المسافة هاتبعها Delta X وهذه
+
+82
+00:08:55,310 --> 00:09:06,290
+المسافة Delta Y البعد
+
+83
+00:09:06,290 --> 00:09:06,890
+التالت
+
+84
+00:09:19,570 --> 00:09:26,410
+هذا البعد التالت هسميه
+
+85
+00:09:26,410 --> 00:09:35,070
+delta z انا
+
+86
+00:09:35,070 --> 00:09:39,930
+بعمل free body diagram هاندي
+
+87
+00:09:39,930 --> 00:09:45,130
+ال x axis هاي ال y axis
+
+88
+00:09:48,380 --> 00:09:54,440
+هاخد summation of forces باتجاه ال X axis باتجاه
+
+89
+00:09:54,440 --> 00:09:59,700
+ال Y axis باتجاه
+
+90
+00:09:59,700 --> 00:10:08,540
+ال X بالساوية 0 و اعتبر هذا الاتجاه الموجب ال
+
+91
+00:10:08,540 --> 00:10:13,240
+sigma X هذه بتأثر بهذا الاتجاه stress في area
+
+92
+00:10:13,240 --> 00:10:19,330
+يعطيني ايش forceفهيكون minus sigma x ال area هيكون
+
+93
+00:10:19,330 --> 00:10:25,890
+delta y في delta z minus sigma x delta
+
+94
+00:10:25,890 --> 00:10:35,830
+y delta z هذه ال area هذا
+
+95
+00:10:35,830 --> 00:10:39,930
+مافيش لأ minus tau xy
+
+96
+00:10:46,110 --> 00:11:06,090
+في Delta X Delta Z Delta X Delta Z بتساوي
+
+97
+00:11:06,090 --> 00:11:11,450
+عند هاي Sigma اللي هو مركبتين واحد اتجاه ال X Axis
+
+98
+00:11:16,360 --> 00:11:24,020
+سيجما في كوسين الفاية فيه
+
+99
+00:11:24,020 --> 00:11:33,740
+لأن هذا دلتا S هذا او في
+
+100
+00:11:33,740 --> 00:11:38,880
+دلتا S مظبوط
+
+101
+00:11:38,880 --> 00:11:43,760
+طبعا مافق دكتور ديالي في دلتا X و دلتا Yيعني في
+
+102
+00:11:43,760 --> 00:11:52,420
+النهاية ستكون هي سيجما سيجما في الضرع هذه اللي
+
+103
+00:11:52,420 --> 00:12:00,180
+بتعطيني ال force في delta S بتعطيني ال force بدي
+
+104
+00:12:00,180 --> 00:12:07,160
+أخد المركبة بتاعتها في cosine الفي دلتا S طبعا في
+
+105
+00:12:07,160 --> 00:12:07,720
+delta Z
+
+106
+00:12:11,750 --> 00:12:17,910
+سيكون سيجما دلتا
+
+107
+00:12:17,910 --> 00:12:21,590
+S دلتا
+
+108
+00:12:21,590 --> 00:12:26,670
+Z في المراكبة بتاعتها اللي هي ايش؟ كوسين الفاية
+
+109
+00:12:26,670 --> 00:12:30,250
+minus
+
+110
+00:12:30,250 --> 00:12:34,210
+تاو
+
+111
+00:12:34,210 --> 00:12:52,840
+في دلتا S دلتا Zcos φ طيب
+
+112
+00:12:52,840 --> 00:12:59,900
+لحظة
+
+113
+00:12:59,900 --> 00:13:06,840
+في علاقة بين ال delta S و delta X و delta Y يعني
+
+114
+00:13:06,840 --> 00:13:08,120
+ممكن احكي انا
+
+115
+00:13:13,970 --> 00:13:18,370
+ماذا يساوي دلتا
+
+116
+00:13:18,370 --> 00:13:31,910
+Y على دلتا S دلتا Y على دلتا S أوصين الفي دلتا
+
+117
+00:13:31,910 --> 00:13:39,950
+X على دلتا S يعني ممكن احكي انا دلتا S بتساوي
+
+118
+00:13:42,870 --> 00:13:53,170
+delta y على cos فاي و برضه بالساوية delta x على
+
+119
+00:13:53,170 --> 00:13:58,670
+sin فاي نرجع
+
+120
+00:13:58,670 --> 00:14:03,950
+لمعادة صارت عند المعادة سفر بالساوية minus sigma x
+
+121
+00:14:03,950 --> 00:14:21,100
+delta y delta zminus tau xy delta x delta z زاد
+
+122
+00:14:21,100 --> 00:14:27,800
+sigma sigma
+
+123
+00:14:27,800 --> 00:14:34,320
+delta s هي cosine فيه معناه دلتا س هتكون في delta
+
+124
+00:14:34,320 --> 00:14:51,850
+y على cosine فيهفى delta z cos فى minus tau
+
+125
+00:14:51,850 --> 00:15:06,390
+فى delta x على sin فى delta z sin delta z sin فى
+
+126
+00:15:17,100 --> 00:15:25,840
+يعني ادى ال cos فاى هنا تختصر و
+
+127
+00:15:25,840 --> 00:15:33,000
+sin فاى تختصر و Delta Z تختصر
+
+128
+00:15:33,000 --> 00:15:37,040
+Delta
+
+129
+00:15:37,040 --> 00:15:41,680
+Z تختصر طيب
+
+130
+00:15:41,680 --> 00:15:48,110
+لو قسمت الطرفين على Delta Xخلّيني أخد لحالة لإن
+
+131
+00:15:48,110 --> 00:15:58,050
+عندي صار Zero بيستوى minus Sigma X Delta Y minus
+
+132
+00:15:58,050 --> 00:16:06,150
+Tau XY Delta X Delta
+
+133
+00:16:06,150 --> 00:16:13,230
+X زاد Sigma Delta Y
+
+134
+00:16:18,730 --> 00:16:28,490
+مينوس تاو دلتا اكس فيش ضال؟ لأ انا هضطر اعود اجحك
+
+135
+00:16:28,490 --> 00:16:38,930
+من هنا دلتا Y بالساوية دلتا S في cos فاي ماشي و
+
+136
+00:16:38,930 --> 00:16:45,770
+دلتا X بالساوية دلتا S في sin فاي ليش هعمل زي هيك؟
+
+137
+00:16:46,360 --> 00:16:52,740
+عشان ألغى ألغى هدول صح؟ يعني أنا حسين عند ال zero
+
+138
+00:16:52,740 --> 00:17:03,040
+so minus sigma x في delta s cosine الفي minus tau
+
+139
+00:17:03,040 --> 00:17:13,740
+xy delta s sine الفي زاد sigma في delta s cosine
+
+140
+00:17:13,740 --> 00:17:24,390
+الفيمن أول
+
+141
+00:17:24,390 --> 00:17:34,630
+ماشي الان انا هيروح عندى delta s و delta s و delta
+
+142
+00:17:34,630 --> 00:17:40,450
+s حاسس
+
+143
+00:17:40,450 --> 00:17:48,170
+ان عندي zero minus sigma x cosine phiminus tau xy
+
+144
+00:17:48,170 --> 00:18:01,790
+sine of phi زائد sigma cosine of phi minus tau
+
+145
+00:18:01,790 --> 00:18:06,950
+sine of phi احنا نحسب sigma و tau احنا نحسب sigma
+
+146
+00:18:06,950 --> 00:18:10,910
+و tau يعني خلينا احكي sigma
+
+147
+00:18:35,090 --> 00:18:36,930
+انحق الصميم الـ forces
+
+148
+00:18:40,090 --> 00:18:49,410
+باتجاه ال Y بتساوي Zero هكون
+
+149
+00:18:49,410 --> 00:18:56,870
+دي Minus Tau XY Delta
+
+150
+00:18:56,870 --> 00:19:05,570
+Y Delta Z Minus
+
+151
+00:19:05,570 --> 00:19:06,470
+Sigma Y
+
+152
+00:19:10,940 --> 00:19:18,500
+Delta X Delta Z Delta
+
+153
+00:19:18,500 --> 00:19:29,380
+X Delta Z Minus Sigma Y Delta X Delta Z زاد
+
+154
+00:19:29,380 --> 00:19:45,000
+Sigma Delta SDelta Z Sin Phi زاد
+
+155
+00:19:45,000 --> 00:19:57,880
+Tau Delta S Delta Z Cos Phi خلّيني
+
+156
+00:19:57,880 --> 00:20:00,640
+اختصر اول اول اول اول يعني واضح Delta Z بتروح
+
+157
+00:20:00,640 --> 00:20:02,700
+معانا Delta Z بتروح
+
+158
+00:20:06,340 --> 00:20:12,920
+لأ اعوض عن Delta Y Delta S Cos Phi حسينا دي صفر
+
+159
+00:20:12,920 --> 00:20:22,720
+بالساوة minus Tau XY Delta Y اللي هي Delta S Cos
+
+160
+00:20:22,720 --> 00:20:38,680
+Phi minus Sigma Y في Delta S Sin Phiزاد سيجما دلتا
+
+161
+00:20:38,680 --> 00:20:54,160
+اس صين الفاى زاد تا دلتا اس كسين الفاى يعني
+
+162
+00:20:54,160 --> 00:20:55,220
+هتروح عندي دلتا اس
+
+163
+00:21:03,510 --> 00:21:12,950
+هيصف عندى سيجما ساين الفاى سيجما ساين الفاى زاد
+
+164
+00:21:12,950 --> 00:21:27,870
+تاو كساين الفاى بتساوي تاو XY هتساوي سيجما Y ساين
+
+165
+00:21:27,870 --> 00:21:32,090
+الفاى زاد
+
+166
+00:21:33,740 --> 00:21:44,280
+تاو اكس واي كوسين الفاية مظبوط
+
+167
+00:21:44,280 --> 00:21:52,020
+سيجما واي كوسين الفاية زي تاو اكس واي كوسين الفاية
+
+168
+00:21:52,020 --> 00:22:00,780
+هذه معادلة اتنين هربع
+
+169
+00:22:00,780 --> 00:22:05,980
+واحدواربع اتنين واجمعهم مع بعض انا احكي واحد
+
+170
+00:22:05,980 --> 00:22:13,080
+square زائد
+
+171
+00:22:13,080 --> 00:22:20,980
+اتنين معدل اتنين square هاي
+
+172
+00:22:20,980 --> 00:22:26,700
+واحد هكون اتنقل بين الاتنين بين هاد و هاد هكون دي
+
+173
+00:22:26,700 --> 00:22:27,620
+sigma تربيع
+
+174
+00:22:38,030 --> 00:22:45,530
+سيجمه تربية سيجمه تربية سيجمه تربية سيجمه تربية
+
+175
+00:22:45,530 --> 00:22:52,030
+سيجمه تربية
+
+176
+00:22:57,960 --> 00:23:10,760
+cos تربيع فاي ماشي رابطها هتكون minus اتنين minus
+
+177
+00:23:10,760 --> 00:23:17,220
+اتنين سيجما سيجما تاو كسايم ساي زي اتنين سيجما تاو
+
+178
+00:23:17,220 --> 00:23:20,580
+ساين كسايم بالغبال على بعض معناه انت خلصنا جهة
+
+179
+00:23:20,580 --> 00:23:23,540
+الشمال هتساوي
+
+180
+00:23:31,630 --> 00:23:37,270
+سيجما اكس تربيه
+
+181
+00:23:37,270 --> 00:23:48,030
+سيجما اكس تربيه كوسين تربيه في زاد
+
+182
+00:23:48,030 --> 00:23:56,090
+سيجما اكس تربيه سيجما
+
+183
+00:23:56,090 --> 00:24:11,240
+واي هذه زاد سيجما وايتربية sin تربية في زائد
+
+184
+00:24:11,240 --> 00:24:24,060
+TAO XY تربية sin تربية في زائد
+
+185
+00:24:24,060 --> 00:24:31,120
+TAO XY تربية cos تربية في
+
+186
+00:24:34,800 --> 00:24:43,000
+زائد عندي اتنين هادي في هادي، صح؟ زائد اتنين هادي
+
+187
+00:24:43,000 --> 00:24:49,740
+في هادي، زائد اتنين تو
+
+188
+00:24:49,740 --> 00:24:54,740
+اكس واي سيجما
+
+189
+00:24:54,740 --> 00:25:02,560
+اكس صين في كوسين في
+
+190
+00:25:04,710 --> 00:25:10,010
+زاد اتنين تاو
+
+191
+00:25:10,010 --> 00:25:14,490
+اكس واي سيجما
+
+192
+00:25:14,490 --> 00:25:21,750
+واي صين في كوسين في
+
+193
+00:25:40,340 --> 00:25:43,940
+طيب هذا sigma تربيع cos تربيع زي sigma تربيع sin
+
+194
+00:25:43,940 --> 00:25:46,900
+تربيع ايش بتساوي؟ sigma تربيع يعني هالصحفة عندى
+
+195
+00:25:46,900 --> 00:26:00,740
+sigma تربيع زائد تاو تربيع زائد
+
+196
+00:26:00,740 --> 00:26:05,360
+تاو تربيع بتساوي
+
+197
+00:26:09,800 --> 00:26:20,960
+الـ Sigma X تربيع لأ
+
+198
+00:26:20,960 --> 00:26:26,580
+مافيش اختصارات عشان أسوي هنضب المعادلة الأولى Cos
+
+199
+00:26:26,580 --> 00:26:32,940
+والمعادلة التانية Sin بعد ايه بنجمعهم؟ ليش هضلوا
+
+200
+00:26:32,940 --> 00:26:46,220
+لأن بلغي التاو معناته حل غيادةهذه معادلة واحد هك
+
+201
+00:26:46,220 --> 00:26:49,040
+انا اعططنى معادلة اللى هى انا روحت على more circle
+
+202
+00:26:49,040 --> 00:26:54,420
+اقعدل هك انا هك حصل ل more circle معادلة دائرة بس
+
+203
+00:26:54,420 --> 00:26:58,060
+انا هجيب sigma لحال و tau لحال بعدين هروح على more
+
+204
+00:26:58,060 --> 00:27:01,500
+circle هتعرف بعد شوية انه عملت more circle انا
+
+205
+00:27:01,500 --> 00:27:08,530
+اللى عملته حاليا هك multiply واحد واحدفى cosine
+
+206
+00:27:08,530 --> 00:27:17,550
+فاى زائد اتنين فى sine فاى ايش حاسسيه اللي عندىه
+
+207
+00:27:17,550 --> 00:27:25,250
+سيجما كوسين تربيه يعني هذا هتروح معاه سيجما كوسين
+
+208
+00:27:25,250 --> 00:27:31,890
+تربيه زائد سيجما sine تربيه سيجما هيكون عندى سيجما
+
+209
+00:27:31,890 --> 00:27:36,310
+بتساوي sigma X
+
+210
+00:27:41,070 --> 00:27:50,250
+الأولى في Cos Sigma X Cos تربيع Phi زائد Sigma Y
+
+211
+00:27:50,250 --> 00:28:00,610
+في Sin تربيع Phi Cos
+
+212
+00:28:00,610 --> 00:28:21,680
+Sin زائد اتنين Tau XYSin Phi Cos Phi اللي
+
+213
+00:28:21,680 --> 00:28:27,340
+.. اللي .. اللي سواه هو .. هانا اختصر عندكوا Cos
+
+214
+00:28:27,340 --> 00:28:33,860
+Two Theta F ساوية Cos تربيعتي
+
+215
+00:28:38,410 --> 00:28:46,450
+cos²θ-sin²θ هذه ستكون تساوي cos²θ
+
+216
+00:28:46,450 --> 00:28:57,030
+-1-cos²θ ستكون تساوي 2cos²θ
+
+217
+00:28:57,030 --> 00:29:04,250
+-1 يعني cos²θ بالساوية نص
+
+218
+00:29:06,700 --> 00:29:13,960
+في واحد زاد cosine two theta هاي الصيغة مظبوط؟
+
+219
+00:29:13,960 --> 00:29:20,300
+الآن انا ممكن احكيه برضه cosine two theta بستوى
+
+220
+00:29:20,300 --> 00:29:25,160
+واحد minus sin تربيع theta minus sin تربيع theta
+
+221
+00:29:25,160 --> 00:29:33,460
+صح؟ يعني هتكون واحد ماقص اتنين sin تربيع theta
+
+222
+00:29:33,460 --> 00:29:35,660
+يعني cosine two theta
+
+223
+00:29:59,660 --> 00:30:07,420
+معناته هيجي اعوض عن هذا سجماسيجما بالساوية سيجما X
+
+224
+00:30:07,420 --> 00:30:15,360
+في cos تربيع في عبر
+
+225
+00:30:15,360 --> 00:30:25,620
+عن نص في واحد زائد cosine two في زائد
+
+226
+00:30:25,620 --> 00:30:38,040
+سيجما Y على اتنين في واحد minus cosineتو في زاد
+
+227
+00:30:38,040 --> 00:30:52,940
+تاو اكس واي صين تو في يعني
+
+228
+00:30:52,940 --> 00:30:57,120
+انا هكون لحظة هي سيجما اكس على اتنين زائد سيجما
+
+229
+00:30:57,120 --> 00:31:02,320
+واي على اتنين سيجما اكس على اتنين سيجما اكس زائد
+
+230
+00:31:02,320 --> 00:31:07,700
+سيجما وايعلى اتنين خلصنا اول term زائد sigma x
+
+231
+00:31:07,700 --> 00:31:10,760
+minus
+
+232
+00:31:10,760 --> 00:31:22,620
+sigma y على اتنين cosine two phi مظلوط زائد tau xy
+
+233
+00:31:22,620 --> 00:31:28,480
+sine two phi اللي هي معادلة sigma اللي هي عادية
+
+234
+00:31:28,480 --> 00:31:28,900
+المعادلة
+
+235
+00:31:34,220 --> 00:31:41,460
+احنا عرفنا sigma بنفس
+
+236
+00:31:41,460 --> 00:31:47,580
+المنطقة لو ضربنا المعادلة الأولى ب sin phi
+
+237
+00:31:47,580 --> 00:31:53,400
+والمعادلة
+
+238
+00:31:53,400 --> 00:31:57,600
+التانية ب minus cosine phi يعني حكينا
+
+239
+00:32:04,690 --> 00:32:12,290
+sin phi او
+
+240
+00:32:12,290 --> 00:32:22,890
+ضرب الأولى minus ماشي sin phi في معادلة واحد minus
+
+241
+00:32:22,890 --> 00:32:30,310
+cosine phi في المعادلة التانية هيعطينا
+
+242
+00:32:34,780 --> 00:32:41,720
+يعني هاد هتروح مع هاد صح؟ هاد هتصير minus tau sine
+
+243
+00:32:41,720 --> 00:32:47,580
+تربيه minus tau cosine تربيه يعني هتكون minus tau
+
+244
+00:32:47,580 --> 00:32:57,320
+minus tau هتساوي sigma x هتكون
+
+245
+00:32:57,320 --> 00:32:58,240
+دي sigma x
+
+246
+00:33:03,690 --> 00:33:12,170
+Sin Phi Cos Phi Minus
+
+247
+00:33:12,170 --> 00:33:19,750
+Sigma Y Sin
+
+248
+00:33:19,750 --> 00:33:27,970
+Phi Cos Phi عندي
+
+249
+00:33:27,970 --> 00:33:28,170
+هنا
+
+250
+00:33:31,180 --> 00:33:40,420
+تاو اكس واي تاو اكس واي صين .. صين تربيع وعندي هين
+
+251
+00:33:40,420 --> 00:33:51,360
+زاد تاو اكس واي صين تربيع
+
+252
+00:33:51,360 --> 00:33:57,360
+في minus
+
+253
+00:33:57,360 --> 00:34:09,920
+تاو اكس وايcos تربيه فاي يعني
+
+254
+00:34:09,920 --> 00:34:13,540
+حاسيب
+
+255
+00:34:13,540 --> 00:34:18,320
+عندي minus tao او خليني اقسم على minus يعني انا
+
+256
+00:34:18,320 --> 00:34:24,180
+حاسب عندي تاو بتساوي
+
+257
+00:34:24,180 --> 00:34:29,620
+minus مص
+
+258
+00:34:32,030 --> 00:34:51,150
+Sigma X Sine 2 Phi زاد نص Sigma Y Sine 2 Phi minus
+
+259
+00:34:51,150 --> 00:34:58,510
+Tau XY في
+
+260
+00:34:58,510 --> 00:35:11,250
+Cos تربيعفاي ماينس صين تربيه فاي صح؟ يعني حاسيسي
+
+261
+00:35:11,250 --> 00:35:15,150
+اندي التاو بدي
+
+262
+00:35:15,150 --> 00:35:23,750
+اخد ماينس عام مشترك هتكون سيجما اكس ماينس سيجما
+
+263
+00:35:23,750 --> 00:35:32,950
+واي على اتنين صين two في خد بين هد و هدminus tau
+
+264
+00:35:32,950 --> 00:35:39,490
+xy في
+
+265
+00:35:39,490 --> 00:35:48,690
+ال cosine تربيع في نص في
+
+266
+00:35:48,690 --> 00:35:57,690
+واحد زائد cosine two في ناقص نص
+
+267
+00:35:59,860 --> 00:36:11,140
+في واحد minus cosine two five هذا
+
+268
+00:36:11,140 --> 00:36:18,520
+ال term هيروح الواحد مع الواحد صح ما هو نعرف ان
+
+269
+00:36:18,520 --> 00:36:22,960
+انت عندك نص cosine مع نص cosine ايش مستويه
+
+270
+00:36:31,030 --> 00:36:41,330
+Tau XY Cos Sigma X minus Sigma Y على اتنين Sine
+
+271
+00:36:41,330 --> 00:36:46,350
+Two Fi زائد Tau XY فيه إشارة غلطة راجعها زائد Tau
+
+272
+00:36:46,350 --> 00:36:57,550
+XY فيه Cos Two Fiهذه المعادلة رجعها براحتك خلاص
+
+273
+00:36:57,550 --> 00:37:02,830
+انت لحالك تدور عليها و تصليحها طيب معناته ان
+
+274
+00:37:02,830 --> 00:37:04,710
+المعادلة sigma is equal to sigma x زي sigma y على
+
+275
+00:37:04,710 --> 00:37:06,930
+اتنين زي sigma x minus sigma y على اتنين cosine
+
+276
+00:37:06,930 --> 00:37:12,270
+two phi زي التو xy sin two phi والتاو واشير stress
+
+277
+00:37:12,270 --> 00:37:17,890
+at any angle phi مطلق minus sigma x minus sigma y
+
+278
+00:37:17,890 --> 00:37:22,390
+على اتنين sin two phi زي التو xy cosine two phi اه
+
+279
+00:37:31,080 --> 00:37:46,480
+أه ماشي لما
+
+280
+00:37:46,480 --> 00:37:50,580
+تعرفنا العقابين sigma و tau at any planewith
+
+281
+00:37:50,580 --> 00:37:55,580
+respect to sigma x و sigma y و tau x و tau xy و
+
+282
+00:37:55,580 --> 00:37:59,260
+phi الان
+
+283
+00:37:59,260 --> 00:38:02,780
+بدى احسب ال principle stresses يعني متى ال normal
+
+284
+00:38:02,780 --> 00:38:06,940
+stresses بيكونوا maximum for sigma to be maximum
+
+285
+00:38:06,940 --> 00:38:09,900
+لازم يكون ال first derivative with respect to y
+
+286
+00:38:09,900 --> 00:38:16,880
+ايش يساوي؟ zero يعني لو حسبت حكيت d sigma على d
+
+287
+00:38:16,880 --> 00:38:24,910
+phiوصويتها للصفر هيكون هذا صفر صح انا ماعمل اشتغال
+
+288
+00:38:24,910 --> 00:38:36,410
+بالنسبة لفاي minus صفر minus اتنين في sigma x
+
+289
+00:38:36,410 --> 00:38:47,630
+minus sigma y على اتنين sin two five زائد اتنينتاو
+
+290
+00:38:47,630 --> 00:38:54,970
+اكس واي كوساين ال two five معناته
+
+291
+00:38:54,970 --> 00:39:02,210
+هكون عندى سيجما اكس ماينس سيجما واي ساين ال two
+
+292
+00:39:02,210 --> 00:39:16,250
+five هتساوي اتنين تاو اكس كوساين two fiveاكسل
+
+293
+00:39:16,250 --> 00:39:24,030
+طرفين على كوسين فايف تان توفاى
+
+294
+00:39:24,030 --> 00:39:29,470
+تان توفاى بتساوي
+
+295
+00:39:29,470 --> 00:39:38,490
+اتنين تاو اكس واي على سيجما اكس مانس سيجما واي at
+
+296
+00:39:38,490 --> 00:39:39,670
+this angle
+
+297
+00:39:42,510 --> 00:39:47,570
+بيكون ال normal stress maximum normal stress بيكون
+
+298
+00:39:47,570 --> 00:39:52,970
+maximum اللي
+
+299
+00:39:52,970 --> 00:39:56,790
+هي هذه المعادلة اللي أنا عشان أحسب ال principal
+
+300
+00:39:56,790 --> 00:40:04,870
+stresses هعوض .. هعوض بالزاوية هذه أنا هاي تان
+
+301
+00:40:04,870 --> 00:40:10,130
+فاية عند هاي الزاوية فاية نعتبر هذه فاية كأنها
+
+302
+00:40:10,130 --> 00:40:18,470
+فايةهي عندى اتنين تاو XY او ممكن اعتبرها بالصيغة
+
+303
+00:40:18,470 --> 00:40:24,370
+هذى تاو XY على
+
+304
+00:40:24,370 --> 00:40:31,090
+اتنين زى هك بيصير نفس الاشي التان مقابل على مجور
+
+305
+00:40:31,090 --> 00:40:36,810
+هي عندهين سيجما X minus سيجما Y على اتنين معناته
+
+306
+00:40:36,810 --> 00:40:40,630
+هذا الضلعاش هكون ساوى جزر التربيع
+
+307
+00:40:45,710 --> 00:40:52,330
+لأحنا لغيرنا صح؟ هتكون جزر التربيع ل sigma x minus
+
+308
+00:40:52,330 --> 00:41:01,610
+sigma y على اتنين لكل تربيع زي ال tau xy تربيع لأن
+
+309
+00:41:01,610 --> 00:41:04,430
+ال sigma بدا نحصل ال sigma principle هعوض عن فعل
+
+310
+00:41:04,430 --> 00:41:10,810
+انا حاطس ياما اندي ال sigma بتساوي sigma x زي
+
+311
+00:41:10,810 --> 00:41:13,510
+sigma y على اتنين
+
+312
+00:41:18,350 --> 00:41:29,370
+زاد sigma x هذا طبعا اتنين فيا زائد sigma x minus
+
+313
+00:41:29,370 --> 00:41:38,450
+sigma y على اتنين في ال cosine اللي هي عبارة عن
+
+314
+00:41:38,450 --> 00:41:47,040
+sigma x minus sigma y على اتنينوالجدر اللي هو
+
+315
+00:41:47,040 --> 00:41:55,880
+الوطر حتى الجدر معروف انه جوا هذا الكلام انا
+
+316
+00:41:55,880 --> 00:42:10,220
+بعوض هناك زاد tau xy sin 2 phi اللي عبارة عن tau
+
+317
+00:42:10,220 --> 00:42:11,020
+xy
+
+318
+00:42:15,430 --> 00:42:27,290
+على الجدر طيب
+
+319
+00:42:27,290 --> 00:42:32,470
+بعمله لأن صار معروف كل ال mathematical terms موجود
+
+320
+00:42:32,470 --> 00:42:34,910
+عندكوا المعناه اللي حكيت فيها اعملها
+
+321
+00:42:34,910 --> 00:42:37,650
+simplification دي ده تماما simplification لأن
+
+322
+00:42:37,650 --> 00:42:38,170
+simplify
+
+323
+00:42:44,980 --> 00:42:53,000
+بيعطينا المعادلة هذه ال principle stresses اللي هي
+
+324
+00:42:53,000 --> 00:42:55,760
+انا عندي two principle stresses sigma one and
+
+325
+00:42:55,760 --> 00:42:58,560
+sigma two sigma one يعني sigma x زي sigma one على
+
+326
+00:42:58,560 --> 00:43:00,840
+اتنين زي او ناقص sigma x وانا sigma one على اتنين
+
+327
+00:43:00,840 --> 00:43:05,820
+الكل تربيع زي ال tau xy تربيع واضح انه هيطلع ان
+
+328
+00:43:05,820 --> 00:43:09,620
+انا عندنا جدر الجدر اللي هو هذا في المعادلة هذول
+
+329
+00:43:09,620 --> 00:43:14,340
+هو ال principle stressesالان خلينا نشوف قيمة الشير
+
+330
+00:43:14,340 --> 00:43:18,620
+ال stress لما
+
+331
+00:43:18,620 --> 00:43:22,600
+يكون ال stress principal ايش عن ال principal يعني
+
+332
+00:43:22,600 --> 00:43:29,380
+ال normal stress بيكون ايش maximum عند ال tau اللي
+
+333
+00:43:29,380 --> 00:43:43,560
+هو at maximum normal stress بتكون عندىtan phi
+
+334
+00:43:43,560 --> 00:43:54,300
+بتساوي tau xy على sigma x minus sigma y على اتنين
+
+335
+00:43:54,300 --> 00:44:05,820
+صح؟ tan اتنين phi اعوض
+
+336
+00:44:05,820 --> 00:44:16,640
+عنهتكون minus sigma x minus sigma y على اتنين في
+
+337
+00:44:16,640 --> 00:44:27,140
+sine two phi اللي هي عبارة عن tau xy على الجدد صح؟
+
+338
+00:44:27,140 --> 00:44:34,600
+فهي ال sine مقابل الوطن هاي المقابل زائد
+
+339
+00:44:34,600 --> 00:44:36,540
+tau
+
+340
+00:44:40,230 --> 00:44:48,670
+xy cosine two phi عبارة عن sigma x minus sigma y
+
+341
+00:44:48,670 --> 00:44:56,970
+على اتنين على جدر صح؟ لاحظوا هذا بيساوي هذا واحد
+
+342
+00:44:56,970 --> 00:45:03,310
+موج وواحد ثالث بيلغوا بعض صح؟
+
+343
+00:45:03,310 --> 00:45:08,840
+معناته at the plains wherethe normal stresses are
+
+344
+00:45:08,840 --> 00:45:12,600
+maximum بيكونش عندنا شيري بيكون الشيري شو ساوي؟
+
+345
+00:45:12,600 --> 00:45:19,180
+zero معناته and zero shear stresses at the
+
+346
+00:45:19,180 --> 00:45:24,780
+principal surface معناته
+
+347
+00:45:24,780 --> 00:45:29,060
+فقط بيكون عنده and the principal planes بيكون عنده
+
+348
+00:45:29,060 --> 00:45:31,860
+فقط principal normal stresses no shear stress
+
+349
+00:45:41,890 --> 00:45:49,570
+الكو ساين هى انا بحكي كو ساين two five كو ساين
+
+350
+00:45:49,570 --> 00:45:56,730
+مجاور على وطر هى
+
+351
+00:45:56,730 --> 00:46:04,050
+انا بعطيه لك هى عندك two five ال two five بتساوي
+
+352
+00:46:04,050 --> 00:46:09,450
+هى tau x yهذا for any angle هاي المقابل على مجاور
+
+353
+00:46:09,450 --> 00:46:13,390
+على sigma x الوطر
+
+354
+00:46:13,390 --> 00:46:20,470
+ايش هيكون قيمة بالحالة هذه جدر التربية يعني فال
+
+355
+00:46:20,470 --> 00:46:25,050
+sign هذا جدر التربية على الوطر و ال cosine المجاور
+
+356
+00:46:25,050 --> 00:46:28,930
+على الوطر انا بلغ مرصم من بعيد عندي هذا المقابل
+
+357
+00:46:28,930 --> 00:46:34,630
+هذا المجاور يعني مقابل ال sign مقابل على جدر و
+
+358
+00:46:34,630 --> 00:46:43,510
+cosineمجاور على جدر واضح؟ لأ انا فاهم .. فاهم انا
+
+359
+00:46:43,510 --> 00:46:46,790
+اللي كيف اقول انا .. انا قصد فالقانون مش تان ..
+
+360
+00:46:46,790 --> 00:46:50,870
+two say .. two five .. two five اه يسوي الشي اللي
+
+361
+00:46:50,870 --> 00:46:54,690
+هو .. انا اشتقتلك اياها انا .. انا حكيتلك بيكون
+
+362
+00:46:54,690 --> 00:47:00,570
+هذا ال stress بشكل عام on ال plane لكن اندي one
+
+363
+00:47:00,570 --> 00:47:03,610
+specific plane ال maximum بيكون دي ال stress
+
+364
+00:47:03,610 --> 00:47:08,910
+maximumfor discipline انا بحكي تغير sigma ماعياش
+
+365
+00:47:08,910 --> 00:47:13,450
+مع ال five a discipline where the normal stress is
+
+366
+00:47:13,450 --> 00:47:15,590
+maximum بيكون ال derivative لل sigma بالنسبة لو
+
+367
+00:47:15,590 --> 00:47:18,990
+five بيستوى zero يعني انا اشتقتها بالنسبة دي sigma
+
+368
+00:47:18,990 --> 00:47:21,790
+بقى دي five سويتها ل zero و طلعت تطلع عند ال ten
+
+369
+00:47:21,790 --> 00:47:24,850
+to five اللي هي سوى two x y على sigma x one x y
+
+370
+00:47:24,850 --> 00:47:27,510
+على اتنين من هنا نجت
+
+371
+00:47:38,570 --> 00:47:41,770
+طيب ال shear stress بيكون maximum هذا برضه ممكن
+
+372
+00:47:41,770 --> 00:47:48,250
+تثبتوها نرجع
+
+373
+00:47:48,250 --> 00:47:54,050
+للمعادلة يعني
+
+374
+00:47:54,050 --> 00:48:03,550
+ال D Tau 100% D Tau by D Phi بتساوي
+
+375
+00:48:06,080 --> 00:48:12,980
+minus sigma x minus sigma y في
+
+376
+00:48:12,980 --> 00:48:19,300
+cosine two phi minus
+
+377
+00:48:19,300 --> 00:48:31,440
+اتنين tau xy sine two phi سواء ل zero عشان اجد ال
+
+378
+00:48:31,440 --> 00:48:33,840
+maximum ال plane اللي بيكون الشيء ال stress
+
+379
+00:48:33,840 --> 00:48:42,050
+maximumيعني انا هكون عندى اتنين تاو اكس واي صين تو
+
+380
+00:48:42,050 --> 00:48:51,090
+فاي بالساوية minus sigma x minus sigma y cosine
+
+381
+00:48:51,090 --> 00:49:00,530
+two five يعني انا هكون عندى ten two five هتكون
+
+382
+00:49:00,530 --> 00:49:06,800
+تساوية minusتاو minus
+
+383
+00:49:06,800 --> 00:49:17,760
+cosine minus sigma x minus sigma y على اتنين تاو
+
+384
+00:49:17,760 --> 00:49:24,280
+xy هذه
+
+385
+00:49:24,280 --> 00:49:25,480
+بتاعة ال share stress
+
+386
+00:49:28,140 --> 00:49:35,700
+يعني ال tan ده متمثل إيه؟ slope صح؟ ال turn to phi
+
+387
+00:49:35,700 --> 00:49:40,820
+بتاعة ال principle stress بتاعة ال stress كانت
+
+388
+00:49:40,820 --> 00:49:47,560
+سواء اتنين tau xy على sigma x minus sigma y صح؟
+
+389
+00:49:47,560 --> 00:49:55,790
+ادروا هدفها دي حكوا عن ده turnالـ two phi بتاعة ال
+
+390
+00:49:55,790 --> 00:50:03,670
+shear بتختلف في تان ال two phi بتاعة ال stress سو
+
+391
+00:50:03,670 --> 00:50:11,190
+minus واحد معناته ال two phi angle بتاعة ال shear
+
+392
+00:50:11,190 --> 00:50:18,290
+stress متعمدة مع ال two phi angle بتاعة ال normal
+
+393
+00:50:18,290 --> 00:50:22,630
+stressلأنه إذا يكون حاصل multiplication ل two
+
+394
+00:50:22,630 --> 00:50:27,210
+slopes الساق والسالب معناته متعاملين معناته الزق
+
+395
+00:50:27,210 --> 00:50:31,370
+بين two phi و two phi تسعين درجة مع phi و phi أكم؟
+
+396
+00:50:31,370 --> 00:50:34,750
+خمسة و أربعين خمسة و أربعين لإنها تتصف مع اتنين
+
+397
+00:50:34,750 --> 00:50:40,070
+معناته ال angle between
+
+398
+00:50:40,070 --> 00:50:44,930
+principle
+
+399
+00:50:48,910 --> 00:50:54,350
+principle planes and
+
+400
+00:50:54,350 --> 00:51:06,810
+planes of maximum shear is plus or minus خمس و
+
+401
+00:51:06,810 --> 00:51:14,570
+أربعين درجة اللي
+
+402
+00:51:14,570 --> 00:51:15,230
+هي كجملة
+
+403
+00:51:23,060 --> 00:51:26,680
+إذا عوّضت عن الزاوية هذه التي هي tan two phi بتاعة
+
+404
+00:51:26,680 --> 00:51:29,280
+الـ shear stress بالصبانة sigma x minus sigma y
+
+405
+00:51:29,280 --> 00:51:32,980
+على اتنين تاو x عوضتها في معادلة ات تاو بيطلع ال
+
+406
+00:51:32,980 --> 00:51:36,600
+maximum shear stress تاو احد تاو اتنين plus or
+
+407
+00:51:36,600 --> 00:51:39,580
+minus sigma x minus sigma y على اتنين لكل تربيع
+
+408
+00:51:39,580 --> 00:51:44,760
+زاو تاو xy تربيع واضح؟
+
+409
+00:51:44,760 --> 00:51:47,780
+هنروح
+
+410
+00:51:47,780 --> 00:51:49,020
+على more circle
+
+411
+00:51:58,260 --> 00:52:02,840
+تطلع المعادلة هذه و تطلع فيها كويس تكتشف انها
+
+412
+00:52:02,840 --> 00:52:09,220
+تنتين مع بعض بمثل معادلة دائرة هدول مع بعض مع
+
+413
+00:52:09,220 --> 00:52:12,840
+مادلة دائرة كيف؟ لو أخدت الـ Sigma أول معادة حكيت
+
+414
+00:52:12,840 --> 00:52:19,660
+Sigma minus خليني
+
+415
+00:52:19,660 --> 00:52:24,460
+أسمي .. أسمي let
+
+416
+00:52:26,440 --> 00:52:36,160
+C سواء Sigma X زي Sigma Y على 2 يعني هاد أسميها C
+
+417
+00:52:36,160 --> 00:52:44,020
+حسن دي Sigma minus C بسوء
+
+418
+00:52:44,020 --> 00:52:56,420
+Sigma X minus Sigma Y على 2 Cos 2 Phiزاد تاو اكس
+
+419
+00:52:56,420 --> 00:53:04,660
+واي صين تو في والمعادلة التانية تاو بستوي سيجما
+
+420
+00:53:04,660 --> 00:53:14,900
+اكس minus سيجما واي على اتنين صين two في زاد تاو
+
+421
+00:53:14,900 --> 00:53:20,380
+اكس واي cosine two في خلينا نسمي هذه معادلة تلاتة
+
+422
+00:53:20,380 --> 00:53:23,480
+هذه معادلة ايش اربع
+
+423
+00:53:32,140 --> 00:53:40,120
+تاو بالثالث صحيح هنا هك صحيح انا هحكي تلاتة square
+
+424
+00:53:40,120 --> 00:53:45,940
+ربع المعتلة تا زائد اربعة square اجمعهم اجمع
+
+425
+00:53:45,940 --> 00:53:49,260
+الشمال مع الشمال و اللي يبقى مع اليمين هتكون هذه
+
+426
+00:53:49,260 --> 00:53:55,780
+ال sigma minus c لكل تربيع زائد تاو تربيع
+
+427
+00:53:59,580 --> 00:54:04,760
+زي الـ tau تربيع هتكون تساوي هذه التربيع زي هذه
+
+428
+00:54:04,760 --> 00:54:09,540
+التربيع الشياطينة نفس هيكون cos تربيع زي sin تربيع
+
+429
+00:54:09,540 --> 00:54:16,960
+واحد هيكون سيجما X minus sigma Y على اتنين لكل
+
+430
+00:54:16,960 --> 00:54:23,300
+تربيع وهذه sin تربيع مع cos تربيع زي الـ tau XY
+
+431
+00:54:23,300 --> 00:54:24,080
+تربيع
+
+432
+00:54:27,980 --> 00:54:32,360
+زائد اتنين هذا في هذا زائد اتنين هذا في هذا يعني
+
+433
+00:54:32,360 --> 00:54:35,980
+عندما نقضي الحكاية على أي حاجة it will cancel out
+
+434
+00:54:35,980 --> 00:54:43,340
+لان هنا سالب وهنا موجب هيك خلصنا معناته معادلة
+
+435
+00:54:43,340 --> 00:54:53,340
+الدائرة بشكل عام هي اي دائرة هي X Y هي دائرة هي
+
+436
+00:54:53,340 --> 00:55:05,510
+مركزها لو حكيتها دي Hوها دي إيش K الدقرة
+
+437
+00:55:05,510 --> 00:55:10,650
+اللي جاي في المركز بالظبط إيش معدلتها X تربية زاد
+
+438
+00:55:10,650 --> 00:55:18,550
+Y تربية سواء R تربية الآن المركز المعادلة الدقرة
+
+439
+00:55:18,550 --> 00:55:28,370
+هتكون X minus H لكل تربيةزائد y minus k كل تربيع
+
+440
+00:55:28,370 --> 00:55:33,690
+سواء ر تربيع معناته
+
+441
+00:55:33,690 --> 00:55:42,250
+هذه معادلة هذول ال terms هسميها يعني هكون sigma
+
+442
+00:55:42,250 --> 00:55:51,210
+minus c لكل تربيع بتساوي ر capital تربيع زائد تاو
+
+443
+00:55:51,210 --> 00:55:59,690
+تربيعSigma minus C كل تربيه زائد تاو تربيه So R
+
+444
+00:55:59,690 --> 00:56:09,850
+capital تربيه هذا معامل الدائرة مركزها جاي لو عملت
+
+445
+00:56:09,850 --> 00:56:13,670
+plot Sigma مع تاو Sigma مع تاو مركز جاي على ال X
+
+446
+00:56:13,670 --> 00:56:21,030
+axis يعني عندي هي عندي Sigma مع تاو هي ال C
+
+447
+00:56:24,700 --> 00:56:34,500
+و هذه الدائرة و هذا ايش ال R بتاعتها ال R بتاعتها
+
+448
+00:56:34,500 --> 00:56:39,800
+من
+
+449
+00:56:39,800 --> 00:56:50,820
+هنا جت ايش more circle هذه more circle
+
+450
+00:56:54,590 --> 00:57:02,110
+North circle is a plot of shear stress versus
+
+451
+00:57:02,110 --> 00:57:07,350
+normal stress ال plot هذا يعني plot هذه ال
+
+452
+00:57:07,350 --> 00:57:14,590
+equation مع هذه ال equation بيعطينا دائرة مركزها
+
+453
+00:57:14,590 --> 00:57:21,630
+مواقع على محور ال sigma و يبعد C ال C كما احنا
+
+454
+00:57:21,630 --> 00:57:30,460
+حكيناسيجما اكس زي السيجما واي على اتنين انا
+
+455
+00:57:30,460 --> 00:57:34,480
+اتوم more circle هاي
+
+456
+00:57:34,480 --> 00:57:40,300
+more circle هاي السيجما هاي التاو لو كنا نرسم more
+
+457
+00:57:40,300 --> 00:57:44,960
+circle كنا نعرف التاو هاد مثلا هاد التاو مع ال X
+
+458
+00:57:44,960 --> 00:57:46,940
+axis counter clockwise كنا نعرف ال counter
+
+459
+00:57:46,940 --> 00:57:52,340
+clockwise موجة يعني هاد يقول بيعملوا ايشبيعملوا
+
+460
+00:57:52,340 --> 00:57:59,560
+ازدواج موجب عندي هنا تاو counter clockwise و هنا
+
+461
+00:57:59,560 --> 00:58:06,240
+تاو clockwise طيب
+
+462
+00:58:06,240 --> 00:58:13,460
+نيجي ل more circle هخلي
+
+463
+00:58:13,460 --> 00:58:26,270
+المعادلة عشان تعرفوا كيف أجتال .. ال issue عند
+
+464
+00:58:26,270 --> 00:58:33,810
+ال C سوى Sigma X زي Sigma Y على اتنين عند ال R
+
+465
+00:58:33,810 --> 00:58:40,290
+بسوى جزر التربيع ل Sigma X minus Sigma Y على اتنين
+
+466
+00:58:40,290 --> 00:58:45,930
+لكل تربيع زي تاو XY تربيع
+
+467
+00:58:53,120 --> 00:58:59,580
+هي مرسيكا لان عندي محورين محور السيجما محور التاو
+
+468
+00:58:59,580 --> 00:59:07,800
+عندي هنا تاو clockwise وهنا تاو counter clockwise
+
+469
+00:59:07,800 --> 00:59:14,380
+عندي stress element sigma
+
+470
+00:59:14,380 --> 00:59:14,820
+x
+
+471
+00:59:22,190 --> 00:59:27,490
+و tau xy وعندي
+
+472
+00:59:27,490 --> 00:59:33,710
+sigma y عالمستوى
+
+473
+00:59:33,710 --> 00:59:39,450
+هذا فاندي sigma x و tau xy counter clockwise tau
+
+474
+00:59:39,450 --> 00:59:44,150
+xy جاي counter clockwise مع sigma x فهروح اعمل اخد
+
+475
+00:59:44,150 --> 00:59:50,370
+اول نقطة هذه هذه
+
+476
+00:59:50,370 --> 00:59:51,050
+عبارة عن ايه
+
+477
+00:59:54,780 --> 01:00:06,080
+سيجما اكس سيجما
+
+478
+01:00:06,080 --> 01:00:15,800
+اكس وهذه المسافة تاو اكس
+
+479
+01:00:15,800 --> 01:00:17,280
+واي نقطة
+
+480
+01:00:20,430 --> 01:00:28,950
+ع المستوى هذا عندي sigma y و tau xy clockwise هكون
+
+481
+01:00:28,950 --> 01:00:41,710
+عندي هي sigma y و
+
+482
+01:00:41,710 --> 01:00:44,230
+هي tau xy
+
+483
+01:00:57,770 --> 01:01:03,710
+هذه sigma y وهذه
+
+484
+01:01:03,710 --> 01:01:08,770
+sigma x فهذه المسافة كم الفرق بينهم sigma x minus
+
+485
+01:01:08,770 --> 01:01:15,930
+sigma y مص
+
+486
+01:01:15,930 --> 01:01:16,830
+المسافة هذه
+
+487
+01:01:23,860 --> 01:01:29,460
+اللي هي sigma x minus sigma y على اتنين صح مش هذا
+
+488
+01:01:29,460 --> 01:01:32,880
+sigma x تنقص sigma y نصها هكون sigma x minus sigma
+
+489
+01:01:32,880 --> 01:01:37,320
+y على اتنين لأن نص هذا لو أجبع مع sigma y يعني
+
+490
+01:01:37,320 --> 01:01:46,320
+sigma x minus sigma y على اتنين زي sigma y sigma y
+
+491
+01:01:46,320 --> 01:01:51,660
+عبارة عن اتنين sigma y عاتنين صح يعني اتنين يعني
+
+492
+01:01:51,660 --> 01:01:57,250
+هكون عندى اتنينسيجما اكس ماينس سيجما واي زائد
+
+493
+01:01:57,250 --> 01:02:03,070
+اتنين سيجما واي يعني هيصف ايش سيجما اكس زائد سيجما
+
+494
+01:02:03,070 --> 01:02:09,930
+واي على اتنين معناته هذه النقطة هتكون
+
+495
+01:02:09,930 --> 01:02:18,890
+سيجما اكس زائد سيجما واي على اتنين اللي هو ايش ده
+
+496
+01:02:18,890 --> 01:02:22,590
+ال center تعمر circle هذا ال center
+
+497
+01:02:27,210 --> 01:02:34,010
+طيب احنا حكينا هدى ال tau xy و هدى المسافة sigma x
+
+498
+01:02:34,010 --> 01:02:38,990
+و sigma x minus sigma y هدى المسافة معناه تقول
+
+499
+01:02:38,990 --> 01:02:44,450
+اخدت المثلث القائم الزوايا هدى الطول اش هيكون هدى
+
+500
+01:02:44,450 --> 01:02:49,650
+الجدد التربيع لهدى التربيع زى جدد التربيع اللى هدى
+
+501
+01:02:49,650 --> 01:02:50,670
+هدى هتكون R
+
+502
+01:03:18,620 --> 01:03:25,580
+النقطة التانية هي نقطة A وهي نقطة B A بتمثل
+
+503
+01:03:25,580 --> 01:03:26,380
+المستوى هذا
+
+504
+01:03:29,210 --> 01:03:33,870
+و B المستوى هذا الزاوية بين المستوى هذا و المستوى
+
+505
+01:03:33,870 --> 01:03:40,410
+هذا في أرض الواقع تسعين لك انا بتعامل مع two five
+
+506
+01:03:40,410 --> 01:03:47,550
+تسعين زاوية بينهم ايش مية و تين درجة يعني هذه تمثل
+
+507
+01:03:47,550 --> 01:03:56,150
+ال X axis وهذه ال Y axis وهذه الزاوية بينهم مية و
+
+508
+01:03:56,150 --> 01:03:58,350
+تين درجة اللي هي two five واضح
+
+509
+01:04:11,940 --> 01:04:15,640
+احنا حاولنا ال principal stresses او ال stress
+
+510
+01:04:15,640 --> 01:04:23,280
+بيكون principal لما ال share stress بيكون ساوي صفر
+
+511
+01:04:23,280 --> 01:04:28,160
+معناته هذه مثل
+
+512
+01:04:28,160 --> 01:04:32,800
+sigma one one principal stress و هذه sigma two
+
+513
+01:04:32,800 --> 01:04:36,000
+another principal stress ليش عند النقطة هذه share
+
+514
+01:04:36,000 --> 01:04:43,190
+stress بيساوي share stress zero مظلوط؟الشير ال
+
+515
+01:04:43,190 --> 01:04:55,050
+stress بيكون زاوية zero طيب
+
+516
+01:04:55,050 --> 01:05:00,770
+واضح
+
+517
+01:05:00,770 --> 01:05:07,370
+ان sigma one بيساوي ال center زاد ال radius صح؟
+
+518
+01:05:07,370 --> 01:05:16,270
+sigma one بيساوي ال centerزائد ال radius و ال
+
+519
+01:05:16,270 --> 01:05:22,790
+sigma two بيساوي ال center ناقص ال radius sigma
+
+520
+01:05:22,790 --> 01:05:28,410
+two بيساوي ال center minus ال radius و ال center
+
+521
+01:05:28,410 --> 01:05:32,990
+احنا we defined اللي هو sigma x زائد sigma y على
+
+522
+01:05:32,990 --> 01:05:37,850
+اتنينو ال radius اللي هو square root ل sigma x
+
+523
+01:05:37,850 --> 01:05:43,490
+minus sigma y على اتنين لكل تربيع زي ال tau xy
+
+524
+01:05:43,490 --> 01:05:49,210
+تربيع طيب
+
+525
+01:05:49,210 --> 01:05:54,290
+ال phi b او الزاوية اللي بتعرفلي ال principle
+
+526
+01:05:54,290 --> 01:05:59,850
+plane هاي ال x axis مش هذا principle معناته
+
+527
+01:05:59,850 --> 01:06:05,910
+principle stress اههذه لل stress لل strength اه
+
+528
+01:06:05,910 --> 01:06:11,650
+هذه لل normal stress هذه الزاوية هتكون اللي هي
+
+529
+01:06:11,650 --> 01:06:23,790
+اتنين فاي principal لاحظوا ten ten طلعين اتنين ten
+
+530
+01:06:23,790 --> 01:06:28,970
+اتنين في بي هيها هذه في بي
+
+531
+01:06:32,710 --> 01:06:41,250
+بساوة هذه المسافة اللي هي ايه؟ tau xy على
+
+532
+01:06:41,250 --> 01:06:48,130
+هذه اللي هي sigma x minus sigma y على
+
+533
+01:06:48,130 --> 01:06:58,330
+اتنين مظموط كلام صح؟ طيب معناته
+
+534
+01:06:58,330 --> 01:07:03,000
+في الحالة هذه عشان object of principle stressبدي
+
+535
+01:07:03,000 --> 01:07:07,880
+من ال positive x axis ادور بزاوية في بي يعني اذا
+
+536
+01:07:07,880 --> 01:07:13,920
+هذا هو ال positive x axis اذا هذا هو ال positive x
+
+537
+01:07:13,920 --> 01:07:18,700
+axis بدي
+
+538
+01:07:18,700 --> 01:07:24,480
+ادور بزاوية في
+
+539
+01:07:24,480 --> 01:07:28,360
+بي وارسم
+
+540
+01:07:28,360 --> 01:07:37,790
+elementهذه سيكون علي سيجما واحد وهذه
+
+541
+01:07:37,790 --> 01:07:46,370
+سيجما واحد وهذه
+
+542
+01:07:46,370 --> 01:07:52,210
+سيجما اتنين لأن الزرع بين سيجما واحد هنا وسيجما
+
+543
+01:07:52,210 --> 01:07:57,130
+اتنين هنا الزرع بينهم 180 درجة معناته سيكون سيجما
+
+544
+01:07:57,130 --> 01:08:06,650
+اتنين متعمد عليهفى ششير طبعا فى ششير 5B و لا 2 5B
+
+545
+01:08:06,650 --> 01:08:10,590
+يا دكتور؟ انا هى 2 5B لكن لما ارسم ال stress
+
+546
+01:08:10,590 --> 01:08:14,410
+element اللى عندى ال normal stresses اللى بتكون
+
+547
+01:08:14,410 --> 01:08:19,930
+maximum برسم 5B بحسب ال 2 5B بعدين منها بحسب ال 5B
+
+548
+01:08:25,400 --> 01:08:29,900
+عشان اعرف هذه النقطة هتكون sigma x و tau xy
+
+549
+01:08:29,900 --> 01:08:37,800
+counter clockwise وهذه sigma y و tau xy clockwise
+
+550
+01:08:37,800 --> 01:08:45,000
+واضحت
+
+551
+01:08:45,000 --> 01:08:49,560
+ايش هي more circle؟هذا مهم كتير انا عشان ايك فصلت
+
+552
+01:08:49,560 --> 01:08:55,820
+فيه لإنه بدى تكون فاهم ماتتعاملش مع ال circle بس
+
+553
+01:08:55,820 --> 01:08:59,600
+اعمل كذا و ارسم كذا و كذا تا و تنساها، لكي تعرف
+
+554
+01:08:59,600 --> 01:09:06,200
+الأساس تاعها ال definition
+
+555
+01:09:06,200 --> 01:09:11,600
+.. ال definition تاع ال shear stress ال definition
+
+556
+01:09:11,600 --> 01:09:16,740
+تاع الشير stress بعتبر لتحت counter clockwiseو
+
+557
+01:09:16,740 --> 01:09:22,100
+لعنة clockwise واضح يعني بعتبر counter clockwise
+
+558
+01:09:22,100 --> 01:09:25,740
+شير استرس لتحت counter clockwise negative
+
+559
+01:09:25,740 --> 01:09:30,740
+clockwise إيش positive هذا شير استرس لكن angles
+
+560
+01:09:30,740 --> 01:09:37,080
+أنا I'm rotating rotating
+
+561
+01:09:37,080 --> 01:09:41,480
+أكم تسعين درجة يعني أنا مثلا هندي هاي ال X axis
+
+562
+01:09:41,480 --> 01:09:51,610
+هاي المستوى هذاإذا لفيت ال X axis تسعين درجة بعكس
+
+563
+01:09:51,610 --> 01:09:56,450
+عقار بالسيعة بيعطينا المستقبل هذا اللي مبين عندي
+
+564
+01:09:56,450 --> 01:10:05,250
+هنا 180 درجة وضحك فانا بلف صح عشان أوصل ال X axis
+
+565
+01:10:05,250 --> 01:10:09,450
+لفيت تسعين درجة عشان أوصل ال principle معناته أنا
+
+566
+01:10:09,450 --> 01:10:17,620
+لفيت زي هيك هذه مثلات positive تسعينلفت هك 25D
+
+567
+01:10:17,620 --> 01:10:28,460
+counter clockwise نشوف
+
+568
+01:10:28,460 --> 01:10:28,960
+مثال
+
+569
+01:10:50,030 --> 01:10:58,470
+Find Stress Element علي
+
+570
+01:10:58,470 --> 01:11:07,750
+Normal Stress Sigma X Sigma
+
+571
+01:11:07,750 --> 01:11:13,170
+X بالستة و تمانين ميجا بسكال And Clockwise
+
+572
+01:11:20,290 --> 01:11:27,210
+تاو XY بستوى خمسين ميجاباسكال using Mohr's circle
+
+573
+01:11:27,210 --> 01:11:30,430
+find principal stresses and directions and show a
+
+574
+01:11:30,430 --> 01:11:32,870
+stress element correctly aligned with respect to
+
+575
+01:11:32,870 --> 01:11:43,850
+XY coordinates حرصوا ال Mohr's circle عند
+
+576
+01:11:43,850 --> 01:11:51,180
+هي سيجما هي تاوعلى الـ surface هذا الـ sigma x 80
+
+577
+01:11:51,180 --> 01:11:55,400
+هل هذا clockwise او counter clockwise؟ معناته
+
+578
+01:11:55,400 --> 01:12:03,550
+التوحد كل اعلى عشان نعمل تقسيمةهي عشرة عشرين
+
+579
+01:12:03,550 --> 01:12:11,470
+تلاتين اربعين خمسين ستين سبعين تمانين وعندي عشرة
+
+580
+01:12:11,470 --> 01:12:19,810
+عشرين تلاتين اربعين خمسين عشرة عشرين تلاتين اربعين
+
+581
+01:12:19,810 --> 01:12:22,610
+خمسين ستين
+
+582
+01:12:30,350 --> 01:12:36,690
+عندى المستوى هذا سيجب اكس تمانين واحد اتنين تلاتة
+
+583
+01:12:36,690 --> 01:12:43,670
+اربع خمس ستة سبعة وانية والتاو Clockwise هتكون
+
+584
+01:12:43,670 --> 01:12:50,970
+الاعلى خمسين خليني
+
+585
+01:12:50,970 --> 01:12:51,990
+امسح ال stress element
+
+586
+01:12:59,380 --> 01:13:06,060
+هذه النقطة النقطة التانية على المستوى هذا الـ
+
+587
+01:13:06,060 --> 01:13:14,160
+Sigma Y Zero هذه Zero مع خمسين لتحت هذه واحد،
+
+588
+01:13:14,160 --> 01:13:18,300
+اتنين، تلاتة، اربع، خمسة هذه النقطة التانية لأن
+
+589
+01:13:18,300 --> 01:13:26,120
+مصل بينهم هذا
+
+590
+01:13:26,120 --> 01:13:32,980
+الـ Centerطبعا واضح ال center هيكون سيجما X زي
+
+591
+01:13:32,980 --> 01:13:44,100
+سيجما Y على 2 اللي هو هيكون اربعين ميجا بسكال هاي
+
+592
+01:13:44,100 --> 01:13:49,180
+ال center هرسماش المار
+
+593
+01:13:49,180 --> 01:13:50,200
+سيركل
+
+594
+01:13:57,550 --> 01:14:06,670
+هذا واضح ال X Axis صح وهذا ال Y Axis هذا
+
+595
+01:14:06,670 --> 01:14:14,550
+ال X Axis وهذا ال Y Axis هذا
+
+596
+01:14:14,550 --> 01:14:17,950
+Tau
+
+597
+01:14:17,950 --> 01:14:29,680
+XY وهذا F Sigma X minus Sigma Y على اتنينوهذه two
+
+598
+01:14:29,680 --> 01:14:40,660
+five P تان two five P بتساوي تاو X Y اللي هو خمسين
+
+599
+01:14:40,660 --> 01:14:45,120
+على
+
+600
+01:14:45,120 --> 01:14:51,020
+سيجما X minus سيجما Y على اتنين على اربعين صح وانا
+
+601
+01:14:51,020 --> 01:14:55,800
+بحسب two five P اسبوليها ايش تطلع حد اسبولي two
+
+602
+01:14:55,800 --> 01:14:56,540
+five P على السريع
+
+603
+01:15:13,400 --> 01:15:19,080
+الراديوس هيكون الجزر التربيعي ل سيجما X minus
+
+604
+01:15:19,080 --> 01:15:25,780
+سيجما Y على اتنين لكل تربيع زائد تاو XY تربيع يعني
+
+605
+01:15:25,780 --> 01:15:33,440
+هيكون الجزر التربيعي لاربعين تربيع زائد خمسين
+
+606
+01:15:33,440 --> 01:15:40,540
+تربيع هيساوي ال
+
+607
+01:15:40,540 --> 01:15:44,750
+two phi بيئة كم؟خمس واحد و خمسين واحد و خمسين واحد
+
+608
+01:15:44,750 --> 01:15:45,710
+و خمسين واحد و خمسين واحد و خمسين واحد و خمسين
+
+609
+01:15:45,710 --> 01:15:46,270
+واحد و خمسين واحد و خمسين واحد و خمسين واحد و
+
+610
+01:15:46,270 --> 01:15:54,510
+خمسين واحد و خمسين واحد و خمسين واحد و
+
+611
+01:15:54,510 --> 01:15:59,350
+خمسين واحد و خمسين واحد و خمسين واحد و خمسين واحد
+
+612
+01:15:59,350 --> 01:15:59,770
+و خمسين واحد و خمسين واحد و خمسين واحد و خمسين
+
+613
+01:15:59,770 --> 01:15:59,770
+واحد و خمسين واحد و خمسين واحد و خمسين واحد و
+
+614
+01:15:59,770 --> 01:15:59,770
+خمسين واحد و خمسين واحد و خمسين واحد و خمسين واحد
+
+615
+01:15:59,770 --> 01:16:00,130
+و خمسين واحد و خمسين واحد و خمسين واحد و خمسين
+
+616
+01:16:00,130 --> 01:16:06,290
+واحد و
+
+617
+01:16:06,290 --> 01:16:06,310
+خ
+
+618
+01:16:10,830 --> 01:16:17,290
+اربع و ستين point أربع و ستين point ميجا بسكال
+
+619
+01:16:17,290 --> 01:16:24,150
+ميجا بسكال الان انا محتمش طالما ورجيتك الفاي بي
+
+620
+01:16:24,150 --> 01:16:28,710
+graphically الإشارات لاتعني شيء انا اسمه حتى ان
+
+621
+01:16:28,710 --> 01:16:32,590
+انا حاكي نيجاتيف ماشي انا بحكيلك هاي الفاي بي
+
+622
+01:16:32,590 --> 01:16:38,170
+بتحكيلي نيجاتيف الشوف
+
+623
+01:16:38,170 --> 01:16:45,820
+مش زي السماع صح؟بختلف فعندي ال 5P الان هارسم ال
+
+624
+01:16:45,820 --> 01:16:50,400
+stress element هاي
+
+625
+01:16:50,400 --> 01:16:53,440
+ال stress element التبعي انا همشي clockwise
+
+626
+01:16:53,440 --> 01:17:00,640
+بالزاوية 25 درجة هاي ال X axis همشي
+
+627
+01:17:00,640 --> 01:17:09,680
+زاوية 25.65 degrees هرسم stress element
+
+628
+01:17:13,200 --> 01:17:24,200
+هنا سيجما واحد وهنا سيجما اتنين الآن
+
+629
+01:17:24,200 --> 01:17:30,620
+سيجما واحد في الساعة ال C زاد ال radius صح ال C
+
+630
+01:17:30,620 --> 01:17:35,420
+اللي هو اربعين زاد اربعة وستين point O تلاتة يعني
+
+631
+01:17:35,420 --> 01:17:42,160
+مية واربعة point O تلاتة هندي مية واربعة point O
+
+632
+01:17:42,160 --> 01:17:50,650
+تلاتةو ال sigma two هتكون ال
+
+633
+01:17:50,650 --> 01:17:57,870
+sigma two بالساوية C minus R ال C اللي هي اربعين
+
+634
+01:17:57,870 --> 01:18:04,190
+مينوس اربع ستين point O تلاتة هتكون مينوس اربع و
+
+635
+01:18:04,190 --> 01:18:11,650
+عشرين point O تلاتة صحيح ميجا بسكال يعني هتكون
+
+636
+01:18:11,650 --> 01:18:20,900
+compressionهتكون عنده compression سجم
+
+637
+01:18:20,900 --> 01:18:28,240
+التول هي minus 24 point O ثلاثة ميجاباسكال هذا هو
+
+638
+01:18:28,240 --> 01:18:32,880
+ال stress element اللي
+
+639
+01:18:32,880 --> 01:18:38,940
+بيكون عند ال stress is principal و كنت احكي ال
+
+640
+01:18:38,940 --> 01:18:47,370
+maximum شير ال stressالتاو maximum بيساوي
+
+641
+01:18:47,370 --> 01:18:50,970
+ال
+
+642
+01:18:50,970 --> 01:18:55,110
+radius او
+
+643
+01:18:55,110 --> 01:19:03,490
+بيساوي السيجما واحد minus السيجما اتنين على اتنين
+
+644
+01:19:08,560 --> 01:19:16,560
+مية و اربعة point o تلاتة minus minus اربعة و
+
+645
+01:19:16,560 --> 01:19:26,780
+عشرين point o تلاتة على اتنين ايه كم اطلع اربعة و
+
+646
+01:19:26,780 --> 01:19:37,390
+ستين point o تلاتة ميجا بسكال هذا ال tau maxالـ
+
+647
+01:19:37,390 --> 01:19:45,710
+tau max بيعمل plus or minus plus
+
+648
+01:19:45,710 --> 01:19:51,430
+or minus زاوية خمس و أربعين يعني انا عندي هاي ..
+
+649
+01:19:51,430 --> 01:19:54,930
+هاي ال direction بتاع ال principle stress فاندي
+
+650
+01:19:54,930 --> 01:19:59,050
+واحدة counter clockwise هلف زاوية تسعين درجة اتنين
+
+651
+01:19:59,050 --> 01:20:03,890
+في و انا هلف زاوية خمس و أربعين هج من هذا
+
+652
+01:20:07,080 --> 01:20:17,380
+هذه الزاوية خمسة واربعين وهذه ال stress element
+
+653
+01:20:17,380 --> 01:20:25,700
+هنا ال fit clockwise هتعطي تو counter clockwise
+
+654
+01:20:25,700 --> 01:20:28,760
+هكون
+
+655
+01:20:28,760 --> 01:20:33,580
+بالظبط
+
+656
+01:20:33,580 --> 01:20:40,510
+هكذااللي هي tau maximum
+
+657
+01:20:40,510 --> 01:20:46,770
+طبعا
+
+658
+01:20:46,770 --> 01:20:52,970
+عند ال tau maximum بيكون فيه number stress ايش
+
+659
+01:20:52,970 --> 01:20:56,670
+قيمته لأ
+
+660
+01:20:56,670 --> 01:21:07,310
+ايه sigma x زي sigma y اتنين بتكون عنده stressاللي
+
+661
+01:21:07,310 --> 01:21:13,370
+هي عند اربعين وهي
+
+662
+01:21:13,370 --> 01:21:17,750
+عند stress عند
+
+663
+01:21:17,750 --> 01:21:20,990
+ال maximum share stress planes بيكونش non stress
+
+664
+01:21:20,990 --> 01:21:24,690
+بالزاوية zero بيكون فيه non stress وهي عند هاي tau
+
+665
+01:21:24,690 --> 01:21:33,170
+max ها دي tau, tau maxهذه قيمة ال stress هذه اللي
+
+666
+01:21:33,170 --> 01:21:36,930
+هي sigma x زي sigma y على اتنين اللي هي ال center
+
+667
+01:21:36,930 --> 01:21:53,510
+طبعا
+
+668
+01:21:53,510 --> 01:21:57,770
+ال norm stress هذا كما لو في الحالة هذه كما لو
+
+669
+01:22:00,870 --> 01:22:05,430
+بيكون كما لو ان ال element محتوظ في ميه الميه اللى
+
+670
+01:22:05,430 --> 01:22:09,990
+بتحط فيها اشهر تضغط عليها من كل الجهات بس هين هين
+
+671
+01:22:09,990 --> 01:22:12,550
+انا ضاغط في اتجاه الموج يعني بسحب هين و بسحب هين
+
+672
+01:22:12,550 --> 01:22:16,610
+فال prize ratio effect بالتغفل حالة هذه لو انا
+
+673
+01:22:16,610 --> 01:22:21,070
+بسحب زي هيك بيحاول يرفع هذا بسحب معاكس و نفس
+
+674
+01:22:21,070 --> 01:22:25,290
+القيمة بلغي الأثر تبعه فلو كون اشهر محوط من كل
+
+675
+01:22:25,290 --> 01:22:30,140
+الجهات بالميهبيكون ضغط من كل الجهات ففيش
+
+676
+01:22:30,140 --> 01:22:36,960
+deformation في ال ..في الاتجاه العمودي على السطح
+
+677
+01:22:36,960 --> 01:22:41,200
+عشان يسموه hydrostatic element هذا هيجورنا مستقبلا
+
+678
+01:22:41,200 --> 01:22:47,000
+للي هي ال maximum shear او ال maximum distortion
+
+679
+01:22:47,000 --> 01:22:53,220
+energy theory معظم ال energy اللي بتروح في ال
+
+680
+01:22:53,220 --> 01:22:58,020
+deformation بتروح على شكل distortion يعني بتغير
+
+681
+01:22:58,020 --> 01:23:03,500
+الشكل لكن متغيرش ال dimensions هيك انكم خلصنا
+
+682
+01:23:03,500 --> 01:23:04,420
+المحاضرة
+
+683
+01:23:10,730 --> 01:23:13,230
+لأ انا حاكتش counter clockwise انا حاكت clockwise
+
+684
+01:23:13,230 --> 01:23:17,230
+طبعا maximum انا هادي اذا بدأ بدأ هاي ال principle
+
+685
+01:23:17,230 --> 01:23:21,830
+هاي ال principle اذا بدأ اروح زي هيك هاروح counter
+
+686
+01:23:21,830 --> 01:23:28,190
+clockwise خمسة و اربعين اللي هو هادي اللي هي هادي
+
+687
+01:23:28,190 --> 01:23:33,790
+هتكون ايه؟ clockwise لكن انا شوفت أسهل أمشي من
+
+688
+01:23:33,790 --> 01:23:37,190
+هادي clockwise
+
+689
+01:23:38,690 --> 01:23:41,550
+خمسة فمشيت من هنا لإن أنا قرصت ماشي في تجاه معين
+
+690
+01:23:41,550 --> 01:23:44,390
+ماقدرش أقربش حالي فمشيت هيك خمسة واربعين clockwise
+
+691
+01:23:44,390 --> 01:23:50,630
+رفت المصطلح هذا هد حاكم عليهاش counter clockwise
+
+692
+01:23:50,630 --> 01:23:56,550
+بيعني انت بتاعي حاكم عليه clockwise أعطيكوا
+
+693
+01:23:56,550 --> 01:23:56,750
+العفو
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..58e9a075588b4eb498bbc1c4c8d7b76353a7393d
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_postprocess.srt
@@ -0,0 +1,2216 @@
+1
+00:00:21,350 --> 00:00:25,870
+بسم الله الرحمن الرحيم نستأنف اليوم في موضوع ال
+
+2
+00:00:25,870 --> 00:00:30,470
+alkanes و ال cycloalkanes زي ما بتعرفوا المرة
+
+3
+00:00:30,470 --> 00:00:37,030
+الماضية أعطينا فكرة عن ال alkanes من ناحية التسمية
+
+4
+00:00:37,030 --> 00:00:41,330
+و من ناحية بعض الخواص الفيزيائية و من ناحية
+
+5
+00:00:41,330 --> 00:00:51,110
+تركيبها بمعنى عدد ذرات ال carbon و ال hydrogenو
+
+6
+00:00:51,110 --> 00:00:57,310
+الصيغة العامة ربما بتذكروا حكينا للالكينز CNN H2N
+
+7
+00:00:57,310 --> 00:01:02,560
+Plus Twoالان من انواع ال hydrocarbons اللى بنقول
+
+8
+00:01:02,560 --> 00:01:07,080
+عنها مشبعة saturated ال cycle alkenes عشان ناخد
+
+9
+00:01:07,080 --> 00:01:12,600
+cycle alkenes او حتى بعد هيك alkenes بننطلق احنا
+
+10
+00:01:12,600 --> 00:01:17,220
+من ال alkenes يعني اتخيلوا هذا المركب اللى امامكم
+
+11
+00:01:17,220 --> 00:01:26,060
+هذا عبارة عن بروبين C3H8 واضح؟لو بدى انا اجعل هذا
+
+12
+00:01:26,060 --> 00:01:32,700
+المركب اشيل ذرتين هيدروجين و احط بدالهم رابطة يعني
+
+13
+00:01:32,700 --> 00:01:37,400
+هى ذرة هيدروجين و من جنبها تماما يعني عندك ذرتين
+
+14
+00:01:37,400 --> 00:01:41,240
+كربون متجاورات شيلت ذرة هيدروجين و حطيت رابطة
+
+15
+00:01:41,240 --> 00:01:48,270
+مكانهم بيصير عندى ال keenبصير عندى الكين اللى فيه
+
+16
+00:01:48,270 --> 00:01:52,210
+double bond لبروبيل الان لو سألت ال الكين ايش
+
+17
+00:01:52,210 --> 00:01:59,970
+الصيغة العامة له لاحظوا معاه C3H6
+
+18
+00:02:01,060 --> 00:02:09,040
+C3H6 معنا ذلك الصيغة العامة للالكينز CNNH2N واضح
+
+19
+00:02:09,040 --> 00:02:15,540
+نقص كم هيدروجينة تنتين الان لو جربنا نشيل كمان
+
+20
+00:02:15,540 --> 00:02:19,180
+هيدروجين تان من جنب بعض و نحط رابطة مكانهم يعني
+
+21
+00:02:19,180 --> 00:02:24,060
+هاي كمان هيدروجين شيلتها و كمان هيدروجين و حطيت
+
+22
+00:02:24,060 --> 00:02:32,960
+رابطة صار عندى رابطةثلاثية ال kind صار عندي ال
+
+23
+00:02:32,960 --> 00:02:39,660
+kind هذا ال ال kind الصيغة العامة إيه له CNH2N-2
+
+24
+00:02:39,660 --> 00:02:44,940
+يعني لما أقول C3H326
+
+25
+00:02:44,940 --> 00:02:50,830
+-2 أربعة شايفين الأربعةفهذه الصيغة العامة لل
+
+26
+00:02:50,830 --> 00:02:56,690
+الkins لل الkinds لل الkins الآن خلّينا نرجع مرة
+
+27
+00:02:56,690 --> 00:03:01,890
+تانية لل الkins ونشوف طيب إيش الصيغة العامة لل
+
+28
+00:03:01,890 --> 00:03:06,370
+cycloalkins اللي الآن بدهم يمروا علينا ال
+
+29
+00:03:06,370 --> 00:03:11,050
+cycloalkins يعني لو بدي أعمل حلقة و كل الروابط
+
+30
+00:03:11,050 --> 00:03:17,770
+تبعت هذه الحلقة روابط إيش أحديةعشان اعمل حلقة
+
+31
+00:03:17,770 --> 00:03:24,250
+المفروض ان اشيل ذرتين هيدروجين لكن بشيلهم مش من
+
+32
+00:03:24,250 --> 00:03:28,810
+جنب بعض في هذه الحالة مثلا بشيلهم من الأطراف هشيلت
+
+33
+00:03:28,810 --> 00:03:33,990
+ذرة هيدروجين من هنا و ذرة هيدروجين تانية من
+
+34
+00:03:33,990 --> 00:03:41,210
+الأطراف و حطيت مكانها رابطة صار
+
+35
+00:03:41,210 --> 00:03:47,060
+عند مركب حلقهcycloalkane لأنه إجا من تلت كربونات
+
+36
+00:03:47,060 --> 00:03:53,100
+بروبيل، شو صرت أسميه؟ Cyclopropane طيب، الآن طالما
+
+37
+00:03:53,100 --> 00:03:58,100
+أنا شيلت هيدروجين تان، والواقع أيضا بأيد هالكلام
+
+38
+00:03:58,100 --> 00:04:00,400
+C3H
+
+39
+00:04:01,190 --> 00:04:08,670
+Six إذا ما الصيغة العامة للـ Cycloalkynes CNH2N
+
+40
+00:04:08,670 --> 00:04:15,810
+CNH2N لاحظوا معناه إن ال الكينز و ال Cycloalkynes
+
+41
+00:04:15,810 --> 00:04:19,990
+بينشأوا عنفق الذرتين هيدروجين ولذلك الطرفين اللي
+
+42
+00:04:19,990 --> 00:04:26,110
+همنفس الصيغة العامة لكن لو فقدوا ذرات الهيدروجين
+
+43
+00:04:26,110 --> 00:04:31,050
+من جانب بعض اعملنا رابطة مكانهم صار عند ال الكين
+
+44
+00:04:31,050 --> 00:04:35,450
+لو فقدوا من اماكن بعيدة و اعملنا رابطة صار عند
+
+45
+00:04:35,450 --> 00:04:40,370
+Cycloalkyn و لذلك ال Cycloalkyn و ال الكين هما
+
+46
+00:04:40,370 --> 00:04:46,750
+يمتلون نفس الفورمولة CNH2N
+
+47
+00:04:46,750 --> 00:04:52,900
+هذه النقطة الأولى اللى بدى احكيها في الموضوعالان
+
+48
+00:04:52,900 --> 00:04:57,960
+لو اتطلعنا اكثر على الـ Cyclopropane بدنا معلومات
+
+49
+00:04:57,960 --> 00:05:03,040
+اكثر عنه، لاحظوا ان تلت ذرات الكربون تبعون الـ
+
+50
+00:05:03,040 --> 00:05:09,830
+Cyclopropane في مستوى واحد، واضح؟و أي تلت ذرات في
+
+51
+00:05:09,830 --> 00:05:13,470
+الدنيا بالمناسبة بيكونوا في مستوى واحد يعني مش
+
+52
+00:05:13,470 --> 00:05:17,130
+ممكن تلاتة إلا يكونوا في مستوى واحد واحد اتنين
+
+53
+00:05:17,130 --> 00:05:22,070
+حطوا التالتة هذا في مستوى واحد ولذلك لو سألنا عن
+
+54
+00:05:22,070 --> 00:05:27,370
+الـcyclopropane إيش الشكل تبعه بدنا نقول planner
+
+55
+00:05:27,370 --> 00:05:34,230
+planner يعني في مستوى واحد مش بتلت أبعاد يعني لو
+
+56
+00:05:34,230 --> 00:05:39,070
+كنا بنحكي عن XY هذا في ال XYواضحة الفكرة؟ هذه
+
+57
+00:05:39,070 --> 00:05:41,870
+النقطة الثانية اللى بدنا ننبهها بالنسبة للـ
+
+58
+00:05:41,870 --> 00:05:48,610
+Cyclopropane الان نقطة تالتة كتير مهمة جدا عندنا
+
+59
+00:05:48,610 --> 00:05:55,510
+دائما في أي مركب نعرف أنواع ذرات الهيدروجيلعشان
+
+60
+00:05:55,510 --> 00:05:59,570
+لما بنعمل التفاعلات النواتج تتمد كم نوع ذرات
+
+61
+00:05:59,570 --> 00:06:04,410
+هيدروجين عندك يعني ربما المركب الأصلي اللى قبل ما
+
+62
+00:06:04,410 --> 00:06:08,230
+يكون Cyclopropane اللى هو البروبين لما حكينا المرة
+
+63
+00:06:08,230 --> 00:06:18,590
+الماضية CH3 CH2 CH3 كم نوع من ذرات الهيدروجين فيه
+
+64
+00:06:18,590 --> 00:06:24,250
+نوعين هدولة الستة زي بعض و هدولة التنتين زي بعض و
+
+65
+00:06:24,250 --> 00:06:27,630
+عشان ايه بعد شوية لو بدي اعمل عليه تفاعلات اقول طب
+
+66
+00:06:27,630 --> 00:06:32,530
+نشيل هيدروجينة نحط مركانها كلور لو شيلت من هان
+
+67
+00:06:32,530 --> 00:06:37,610
+بطلع عنده مركب بسميه one chlorobrobil لو شيلت من
+
+68
+00:06:37,610 --> 00:06:43,220
+هانبطلع مركّب تاني بسميه 2-chloropropane فبناء على
+
+69
+00:06:43,220 --> 00:06:47,240
+عدد أنواع الهيدروجين انا بقدر اعرف ايش اللي بيصير
+
+70
+00:06:47,240 --> 00:06:51,340
+عندى بالتفاعل طيب يا تورا لو مسكت ال cyclopropane
+
+71
+00:06:51,340 --> 00:06:59,720
+و سألت هدولة 6 ذرات هيدروجين كام نوع؟نوع واحد
+
+72
+00:06:59,720 --> 00:07:04,400
+بمعنى لو انا امسكت ذرة كلور خلّينا نفترض هذه لمخ
+
+73
+00:07:04,400 --> 00:07:08,520
+اللون الأخضر بدي اشيل اي هيدروجين و احط مكانها
+
+74
+00:07:08,520 --> 00:07:14,180
+كلور مش هذا تفاعل ابدال بدلنا هيدروجين بكلور الان
+
+75
+00:07:14,180 --> 00:07:20,460
+لو شيلت هذه و حطيت كلور هيطلع عندى مركببس بيصير
+
+76
+00:07:20,460 --> 00:07:25,920
+اسمه اكلورو سايكلو بروبين طب لو كنت بده احك مكان
+
+77
+00:07:25,920 --> 00:07:33,120
+هادي نفس الاشي واضح مكان هادي مكان هادي ف ست ذرات
+
+78
+00:07:33,120 --> 00:07:38,520
+الهيدروجين في هذا المركب they are equivalent يعني
+
+79
+00:07:38,520 --> 00:07:43,560
+لو كنا بنسألكم the six hydrogens of cyclopropane
+
+80
+00:07:43,560 --> 00:07:50,880
+areequivalent متكافئات واضحة الفكرة وعشان هيك
+
+81
+00:07:50,880 --> 00:07:56,440
+بنقدر نتبع هالكلام جملة تانية monochlorination of
+
+82
+00:07:56,440 --> 00:07:59,600
+cyclopropane معناه monochlorination إن أنا أبدل
+
+83
+00:07:59,600 --> 00:08:05,680
+هيدروجين واحدة بكلور واحدة شو بسمي العملية؟ mono
+
+84
+00:08:05,680 --> 00:08:11,120
+يعني أحادي monochlorination
+
+85
+00:08:11,120 --> 00:08:18,080
+إيش يعني chlorination؟تفاعل مع الكلور تفاعل الـ
+
+86
+00:08:18,080 --> 00:08:21,340
+Cyclopropane مع الكلور إبدال بذرة واحدة
+
+87
+00:08:21,340 --> 00:08:27,820
+Monochlorination of Cyclopropane produces only one
+
+88
+00:08:27,820 --> 00:08:34,880
+product بيطلع فقط ناتج واحد، شو سميته أنا؟
+
+89
+00:08:34,880 --> 00:08:40,900
+Chlorocyclopropane واضح؟
+
+90
+00:08:41,270 --> 00:08:48,910
+الان اذا بنستمر بنفس هذه الفكرة وبنقول ان انسان
+
+91
+00:08:48,910 --> 00:08:54,850
+عمل هذا التفاعل وصار عنده chlorocyclopropane وفكر
+
+92
+00:08:54,850 --> 00:09:00,570
+انه بده يعمل تفاعل تاني على ال cyclopropane ابدل
+
+93
+00:09:00,570 --> 00:09:06,850
+كمان هيدروجين لازم يكون عارف كم نوع من الهيدروجين
+
+94
+00:09:06,850 --> 00:09:15,380
+عنده في هذا المركب الانلا أكيد لا الان احنا بحاجة
+
+95
+00:09:15,380 --> 00:09:24,980
+إلى عمق في التفكير و في النظر الأمر مش سهل اكثر
+
+96
+00:09:24,980 --> 00:09:31,580
+من نوع يعني هذا لما بضحط chlorine تانية كان مركب
+
+97
+00:09:31,580 --> 00:09:38,640
+بينتج عندى فيه واضح؟في الحقيقة هنكتشف انهم اللي
+
+98
+00:09:38,640 --> 00:09:45,540
+بينتجوا تلت مركبات معناه ذلك عندنا تلت أنواع من
+
+99
+00:09:45,540 --> 00:09:49,220
+الهيدروجيل بنعملهم بال model و بعدين بنكتبهم
+
+100
+00:09:49,220 --> 00:09:53,680
+معادلة حتى نأكد المعلومة الآن لو إجت طالبة منكم
+
+101
+00:09:53,680 --> 00:09:59,240
+قالت بدي أشيل هذه الهيدروجيل اللي على نفس الكاربون
+
+102
+00:09:59,240 --> 00:10:05,020
+اللي حامله كلور و أحط محالها كلورطلعت مركّب حامل
+
+103
+00:10:05,020 --> 00:10:08,840
+ذرتين كلور على نفس الكربون هذا
+
+104
+00:10:08,840 --> 00:10:13,180
+Dichlorocyclopropane لكن التسمية بتشترط اني لازم
+
+105
+00:10:13,180 --> 00:10:17,680
+احدد الان مواقعهم وين موجودة هذه عن امر واحد و هذه
+
+106
+00:10:17,680 --> 00:10:23,680
+ع واحد اذا هذا لو كنت بدى اسميه هسميه one one
+
+107
+00:10:23,680 --> 00:10:28,540
+مرتين لازم اقول one يعني ذرة على one والتانية على
+
+108
+00:10:28,540 --> 00:10:32,600
+one one one dichlorocyclopropane
+
+109
+00:10:33,600 --> 00:10:39,640
+هذا مُركّب إجى مكان ذرّة الهيدروجين اللي هنا الان
+
+110
+00:10:39,640 --> 00:10:47,020
+لو إجيت طلعت على هدول الذرات نسبتهم لهذه واحد تنين
+
+111
+00:10:47,020 --> 00:10:56,580
+او واحد تنين واضح؟ الان لو شيلت هذه حطيت مكانها
+
+112
+00:10:56,580 --> 00:11:04,460
+اكلور هيطلع عند مُركّب جديدDichlorocyclopropane
+
+113
+00:11:04,460 --> 00:11:09,300
+قدرتين لكلور على موقعين متجاورين عشانك بقول one
+
+114
+00:11:09,300 --> 00:11:13,520
+two dichlorocyclopropane
+
+115
+00:11:13,520 --> 00:11:19,240
+one two dichlorocyclopropane هاي مركب تاني الان
+
+116
+00:11:19,240 --> 00:11:25,060
+ممكن واحدة منكم تفكر تقول طب خلينا نشيل هذه الذرعة
+
+117
+00:11:25,060 --> 00:11:30,880
+مش من نفس الجهة اللي هنا من الجهة المعاكسة ونحط
+
+118
+00:11:34,790 --> 00:11:40,130
+one two dichlorocyclopropane الان السؤال هل يا ترى
+
+119
+00:11:40,130 --> 00:11:44,950
+المركب اللى فى ذرتين لكلور على جهة واحدة زى اللى
+
+120
+00:11:44,950 --> 00:11:49,070
+فى ذرتين لكلور متعاكسة ممكن البعض يقول طب احنا
+
+121
+00:11:49,070 --> 00:11:54,190
+بنلف حوالين الرابط لو جربنا اللفتذكروا أن الدوران
+
+122
+00:11:54,190 --> 00:12:00,050
+ممنوع حول الحلقة مافيش إمكانية إذا هدول مركبين طيب
+
+123
+00:12:00,050 --> 00:12:04,210
+هذا اسمه one two و اللي كان ع جهة واحدة برضه اسمه
+
+124
+00:12:04,210 --> 00:12:07,510
+one two dichlorocyclopropane لو بدي أميزهم أكثر
+
+125
+00:12:07,510 --> 00:12:11,890
+بقول اه في عندي one two اللي على جهة واحدة و one
+
+126
+00:12:11,890 --> 00:12:19,170
+two اللي على جهتين متعاكستين هنا بدأنا نتكلم في ال
+
+127
+00:12:19,170 --> 00:12:24,460
+stereo chemistryانه صحيح الذرات موجودين على موقع
+
+128
+00:12:24,460 --> 00:12:28,440
+واحد و اتنين يعني same bonding لكن هنا على واحد و
+
+129
+00:12:28,440 --> 00:12:32,480
+اتنين على جهة واحدة و على واحد و اتنين على جهتين
+
+130
+00:12:32,480 --> 00:12:37,660
+متعاكستين الاسم في الحالتين one two
+
+131
+00:12:37,660 --> 00:12:42,770
+dichlorocyclopropane لكن بدي اضيف عليه مرة معو مرة
+
+132
+00:12:42,770 --> 00:12:49,450
+ضد لو كنا بنكتب بالعربي فعلا بيستعملوا مع كلمتين
+
+133
+00:12:49,450 --> 00:12:55,110
+مع على جهة واحدة و ضد على جهتين متعاكستين الآن
+
+134
+00:12:55,110 --> 00:12:58,550
+بالإنقليزي بيروحوا بيحطوا prefix ال prefix يعني
+
+135
+00:12:58,550 --> 00:13:03,690
+اشي في أول الكلام بادئة توضح هذا الكلام بيروحوا
+
+136
+00:13:03,690 --> 00:13:08,910
+بيضيفوا cis بمعنى على جهة واحدة و trans بمعنى على
+
+137
+00:13:08,910 --> 00:13:16,000
+جهتينSex و Trans يعني على جهة واحدة وعلى جهتين
+
+138
+00:13:16,000 --> 00:13:24,840
+خلينا هذا الكلام إذا بتسمحوا نتخيله بمعادلة ليش
+
+139
+00:13:24,840 --> 00:13:29,660
+لأنه دائما إنتوا لو بدكوا تكتبوا هتكتبوا معادلات
+
+140
+00:13:29,660 --> 00:13:31,780
+بمعنى هاي في عند أنا
+
+141
+00:13:36,020 --> 00:13:41,100
+Cyclopropane هذا Cyclopropane كام هيدروجين فيه؟
+
+142
+00:13:41,100 --> 00:13:46,860
+ستة لو قلت بدي أعمل إيه له؟ إكلورينايشن CL2 في
+
+143
+00:13:46,860 --> 00:13:51,460
+البداية بدي أعمل مونوكلورينايشن أبدل ذرة واحدة شو
+
+144
+00:13:51,460 --> 00:13:57,400
+هينشاء عندى؟ إكلورو سايكلوبروبين على أي موقع ابنه
+
+145
+00:13:57,400 --> 00:14:03,840
+كتوبة ماعنداش مشكلة إكلورو سايكلوبروبين
+
+146
+00:14:03,840 --> 00:14:07,900
+هيك حاجة أسميهالان لو افترضت هذا ال
+
+147
+00:14:07,900 --> 00:14:14,440
+chlorocyclopropane بدي اعمله كمان chlorination
+
+148
+00:14:14,440 --> 00:14:20,000
+حيصير بالمجمل كم ذرة ال chlor أبدلت تنتين اه كمان
+
+149
+00:14:20,000 --> 00:14:25,720
+مرة chlorination حيصير عندي عدة احتمالات هذا
+
+150
+00:14:25,720 --> 00:14:29,140
+الاحتمال ان ذرة ال chlor تيجي على نفس الذرة اللي
+
+151
+00:14:29,140 --> 00:14:35,700
+حملة ال chlor الأولى ايش سمناهالأ اللي عملناه في
+
+152
+00:14:35,700 --> 00:14:42,520
+الأولى ال chlorine ال chlorine على نفس الذرة one
+
+153
+00:14:42,520 --> 00:14:45,880
+one one one one one one one one one one one one
+
+154
+00:14:45,880 --> 00:14:46,040
+one one one one one one one one one one one one
+
+155
+00:14:46,040 --> 00:14:46,060
+one one one one one one one one one one one one
+
+156
+00:14:46,060 --> 00:14:53,560
+one one one one one one one one one one one one
+
+157
+00:14:53,560 --> 00:14:53,820
+one one one one one one one one one one one one
+
+158
+00:14:53,820 --> 00:14:54,180
+one one one one one one one one one one one one
+
+159
+00:14:54,180 --> 00:14:54,200
+one one one one one one one one one one one one
+
+160
+00:14:54,200 --> 00:14:54,300
+one one one one one one one one one one one one
+
+161
+00:15:10,380 --> 00:15:18,060
+الان يا تورا لو كنا بدنا نحط ذرة الكلور على الموقع
+
+162
+00:15:18,060 --> 00:15:24,020
+اتنين خلينا نحط واحد و اتنين هنا بهذا الشكل ممكن
+
+163
+00:15:24,020 --> 00:15:30,380
+يكون عنده ذرتين كلور على جهة واحدة او ذرتين كلور
+
+164
+00:15:30,380 --> 00:15:33,920
+على جهتين متعاكسات
+
+165
+00:15:35,440 --> 00:15:40,600
+واضح؟ الان هاي واحد اتنين تلاتة واحد اتنين تلاتة
+
+166
+00:15:40,600 --> 00:15:45,240
+اذا كل مركب من هدوله ايش اسمه one two
+
+167
+00:15:45,240 --> 00:15:56,340
+dichlorocyclopropane one two dichlorocyclopropane
+
+168
+00:15:56,340 --> 00:15:58,800
+لكن
+
+169
+00:16:05,080 --> 00:16:10,380
+لكن لما بدي اميز هدول المركبات هنا الديكلورو جايين
+
+170
+00:16:10,380 --> 00:16:16,680
+على جهة واحدة فهذا الاسم الكامل له شو حيصير SES
+
+171
+00:16:16,680 --> 00:16:22,200
+شرطة one two dichlorocyclopropane يعني لما بدي
+
+172
+00:16:22,200 --> 00:16:27,540
+اجيب هذا في الامتحان سموه هتكتبوا SES شرطة one two
+
+173
+00:16:27,540 --> 00:16:33,430
+dichlorocyclopropane لو كنت بدي اسمي هذاالترانس
+
+174
+00:16:33,430 --> 00:16:37,190
+شرطة one two dichlorocyclopropane طبعا اكيد الذره
+
+175
+00:16:37,190 --> 00:16:44,010
+التاني اللي هي ذره ايش ال hydrogenواضح؟ لاحظوا ان
+
+176
+00:16:44,010 --> 00:16:49,010
+هدول المركبين .. هدول المركبين من ناحية ال bonding
+
+177
+00:16:49,010 --> 00:16:53,170
+.. من ناحية ال bonding they have the same bonding
+
+178
+00:16:53,170 --> 00:16:57,230
+من أي ناحية؟ ان ذرة كلورة على موقع واحد و التاني
+
+179
+00:16:57,230 --> 00:17:00,690
+على موقع التاني على واحد على اتنين .. على واحد على
+
+180
+00:17:00,690 --> 00:17:06,310
+اتنين the same bonding لكن اين الاختلاف؟ بالشكل ..
+
+181
+00:17:06,310 --> 00:17:10,930
+بالشكل الفراغي they have the same bondingbut
+
+182
+00:17:10,930 --> 00:17:15,470
+different arrangement in space شكلهم بالفراغ مختلف
+
+183
+00:17:15,470 --> 00:17:19,010
+ان هدول الذرتين ع جهة واحدة و هدول الذرتين ع جهات
+
+184
+00:17:19,010 --> 00:17:22,850
+متعاكسة بس اتنين ع واحد اتنين هذا النوع اللي احنا
+
+185
+00:17:22,850 --> 00:17:29,250
+ايش سمنا stereo isomersهذا النوع اللي سمناه stereo
+
+186
+00:17:29,250 --> 00:17:32,910
+isomers لما حكينا على ال isomerism قلنا ال stereo
+
+187
+00:17:32,910 --> 00:17:37,630
+isomers they have the same bonding يعني لما أجي
+
+188
+00:17:37,630 --> 00:17:41,670
+أقول الكلور وين؟ ع واحد و التانية ع اتنين في
+
+189
+00:17:41,670 --> 00:17:45,870
+التاني الكلور وين؟ ع واحد و التانية ع اتنين اذا
+
+190
+00:17:45,870 --> 00:17:50,310
+they have the same bonding طب وين اختلفوا؟بشكل
+
+191
+00:17:50,310 --> 00:17:54,390
+برفرات اه هدول ع واحد و اتنين ع جهة واحدة على واحد
+
+192
+00:17:54,390 --> 00:17:57,630
+و اتنين ع جهتين مختلفتين هذه بنسميها different
+
+193
+00:17:57,630 --> 00:18:03,710
+arrangement in space اذا العلاقة بين هذا ال cis و
+
+194
+00:18:03,710 --> 00:18:12,070
+ال trans they are stereo isomers لاحظوا
+
+195
+00:18:12,070 --> 00:18:16,930
+لو قلتلكوا ما العلاقة بين هذا المركب و هذا المركب
+
+196
+00:18:16,930 --> 00:18:22,870
+في ال isomersهنا they have different bonding و
+
+197
+00:18:22,870 --> 00:18:29,140
+different namesذرتين الكلور على واحد و واحد وعشان
+
+198
+00:18:29,140 --> 00:18:33,980
+هيك سميته one one dichlorocyclopropane هنا ذرتين
+
+199
+00:18:33,980 --> 00:18:36,600
+الكلور على واحد و اتنين هذا ال same bonding ولا
+
+200
+00:18:36,600 --> 00:18:40,020
+different bonding different bonding ال different
+
+201
+00:18:40,020 --> 00:18:45,220
+bonding أدى إلى different names أنا لما حددت مواقع
+
+202
+00:18:45,220 --> 00:18:49,620
+الكلور قلت one one هنا قلت one two إذا هذا المركب
+
+203
+00:18:49,620 --> 00:18:50,860
+و هذا المركب
+
+204
+00:18:53,140 --> 00:18:58,280
+صحيح مكونين من نفس الذرات لكن فيهم different
+
+205
+00:18:58,280 --> 00:19:01,860
+bonding و different names فالعلاقة بين ال 11
+
+206
+00:19:01,860 --> 00:19:06,420
+-dichlorocyclopropane و ال 12-dichlorocyclopropane
+
+207
+00:19:06,420 --> 00:19:11,480
+they are structural isomers و كذلك العلاقة بين هذا
+
+208
+00:19:11,480 --> 00:19:15,140
+و هذا لكن لو قلت العلاقة بين ال cis و ال trans
+
+209
+00:19:15,140 --> 00:19:19,120
+they are stereo isomers
+
+210
+00:19:21,810 --> 00:19:26,210
+Same bonding but different arrangement in space هي
+
+211
+00:19:26,210 --> 00:19:30,550
+تعريف الـ Stereoisomers نفس الإرتباط ولكن يختلف
+
+212
+00:19:30,550 --> 00:19:33,610
+فيه الشكل بالفراغ
+
+213
+00:19:37,910 --> 00:19:43,110
+لما قلنا لـ Stereoisomers قلنا نوعين نوع منهم
+
+214
+00:19:43,110 --> 00:19:48,150
+بنسميه Diastereomers هنتعلمه و نوع منهم بنسميه
+
+215
+00:19:48,150 --> 00:19:54,330
+Enantiomers الآن هدولة المركبين مثال لأحد أنواع
+
+216
+00:19:54,330 --> 00:19:59,290
+الـ Stereoisomers الاتنين مثال للـ Diastereomers
+
+217
+00:19:59,290 --> 00:20:02,050
+Diastereomers
+
+218
+00:20:03,170 --> 00:20:06,650
+يعني لما ناخد الاستيريو ايزو مارز ونقول يقسموا إلى
+
+219
+00:20:06,650 --> 00:20:12,590
+نوعين داياستيريو مارز وانانشو مارز الانانشو مارز
+
+220
+00:20:12,590 --> 00:20:17,370
+هندرسهم بأي فصل بالفصل الخامس الداياستيريو مارز
+
+221
+00:20:17,370 --> 00:20:22,520
+الآن بيمروا عليناطيب لو واحدة بده تيجي تقول طب إيش
+
+222
+00:20:22,520 --> 00:20:26,660
+يعني بالظبط diastereomers؟ إيش يعني بالظبط
+
+223
+00:20:26,660 --> 00:20:31,540
+diastereomers؟ بنقول ببساطة التعريف العام التعريف
+
+224
+00:20:31,540 --> 00:20:35,780
+العام ل diastereomers ال diastereomers they are
+
+225
+00:20:35,780 --> 00:20:41,360
+non mirror image stereoisomers يعني stereoisomers
+
+226
+00:20:41,360 --> 00:20:47,140
+ولكن مش صورة بعض في المرآة يعني لو تخيلت أنا أنه
+
+227
+00:20:47,140 --> 00:20:52,280
+بين واحد والتانيفي بينهم مرايا، هل الواحد منهم
+
+228
+00:20:52,280 --> 00:20:57,060
+صورة التالف في المرآة ولا لأ؟ يعني تخيلوا أن أنا
+
+229
+00:20:57,060 --> 00:21:03,800
+هنا حطيت مرآة، دائما و أبدا، أمام المرآة كل جسم له
+
+230
+00:21:03,800 --> 00:21:11,800
+صورة، والصورة في المرآة دائما معاكسة تماما لصورة
+
+231
+00:21:11,800 --> 00:21:16,740
+الجسميعني لو أنا وقفت زي المرأة .. أمام المرأة
+
+232
+00:21:16,740 --> 00:21:22,720
+بهذا الشكل كل النظر تبعي باتجاهكم الآن الصورة اللي
+
+233
+00:21:22,720 --> 00:21:28,960
+في المرأة بكل أبعادها يجب أن تكون معاكسة لصورة
+
+234
+00:21:28,960 --> 00:21:35,380
+الجسم دائما صورة المرأة معاكسة لصورة الجسم بكل
+
+235
+00:21:35,380 --> 00:21:41,560
+مكوناتهاالان لو اتيت يا تورا اتسألت هل هدولة من
+
+236
+00:21:41,560 --> 00:21:47,360
+الاساس صورة مرآه ولا مش صورة مرآه؟ لاحظوا يمكن هنا
+
+237
+00:21:47,360 --> 00:21:50,600
+تلاقي كلور متجه باتجاه هذه عكسها وهذه الهيدروجين
+
+238
+00:21:50,600 --> 00:21:55,600
+باتجاه هذه عكسها يعني لحد هذه النقطةمعاكسات لكن
+
+239
+00:21:55,600 --> 00:22:01,280
+هنا في chlorine إقبالها hydrogen تحت هنا في
+
+240
+00:22:01,280 --> 00:22:05,140
+chlorine إقبالها hydrogen هل هدولة بيصيروا صورة
+
+241
+00:22:05,140 --> 00:22:11,730
+مرآة إذا بطلوا صورة مرآةشرط صورة المرآة أن كل جزء
+
+242
+00:22:11,730 --> 00:22:16,930
+من الجزيئات هيكون بعكس الجثة الآخر هدولة فيهم
+
+243
+00:22:16,930 --> 00:22:19,910
+أشياء أساسا مش اقبال .. مش .. يعني هذه لا فوق،
+
+244
+00:22:19,910 --> 00:22:25,650
+كلور اقبالها هيدروجين، إذا هدولة الشكلين الcess
+
+245
+00:22:25,650 --> 00:22:30,730
+والترانس لما أنا بدي أحكي عنهم بقول they are non
+
+246
+00:22:30,730 --> 00:22:38,720
+mirrorimages، إيش يعني non-mirror images؟ مش صورة
+
+247
+00:22:38,720 --> 00:22:42,120
+بعض في المرأة، الأشياء اللي بتكون مش صورة بعض في
+
+248
+00:22:42,120 --> 00:22:47,960
+المرأة هي اللي تعرف ان اسمها diastereomers، وهذا
+
+249
+00:22:47,960 --> 00:22:53,760
+مثال عليها، ف ال cicatrans، isomers، they are
+
+250
+00:22:53,760 --> 00:22:55,720
+diastereomers
+
+251
+00:22:57,420 --> 00:23:00,580
+They are non-mirror image stereoisomers, so they
+
+252
+00:23:00,580 --> 00:23:06,520
+are diastereomers فكتصنيف من أنواع الاستيريو ايزو
+
+253
+00:23:06,520 --> 00:23:10,460
+مارز، they are diastereomers واضح؟ ولذلك لو
+
+254
+00:23:10,460 --> 00:23:14,080
+جيبنالكم سؤال صح و غلط Sistransisomers are
+
+255
+00:23:14,080 --> 00:23:21,360
+stereoisomers صحالان لو بدى اسأل اكثر عمقًا
+
+256
+00:23:21,360 --> 00:23:26,640
+Sistransisomers are diastereomers برضه صح ما هي
+
+257
+00:23:26,640 --> 00:23:31,080
+diastereomers نوع لكن لو قلنا Sistransisomers are
+
+258
+00:23:31,080 --> 00:23:36,000
+enantiomers لأ و هنتعلم ال enantiomers مستقبلا لو
+
+259
+00:23:36,000 --> 00:23:42,280
+قلنا Sistransisomers are structural isomersبرضه
+
+260
+00:23:42,280 --> 00:23:47,080
+غلط لأ مش structural .. ال structural بيختلفوا في
+
+261
+00:23:47,080 --> 00:23:49,580
+ال bonding هدولة they have the same bonding ع واحد
+
+262
+00:23:49,580 --> 00:23:56,120
+و اتنين ع واحد و اتنين واضح؟ لكن هذا المركب و هذا
+
+263
+00:23:56,120 --> 00:24:00,180
+they are structural isomers بس ال cis trans
+
+264
+00:24:00,180 --> 00:24:04,400
+isomers are stereoisomers أي نوع من ال
+
+265
+00:24:04,400 --> 00:24:10,050
+stereoisomers تحديدا ده يا stereomersتطلعوا معي
+
+266
+00:24:10,050 --> 00:24:14,650
+مرة تانية نرسم أحد هدولة أو نعمل model لأحد هدولة
+
+267
+00:24:14,650 --> 00:24:18,950
+المركبات اللي هم ال sis, trans, isomers واضح؟ هذا
+
+268
+00:24:18,950 --> 00:24:25,810
+أي مركب فيهم؟ ال sis والتاني لترانس متى توجد عندنا
+
+269
+00:24:25,810 --> 00:24:29,840
+ظاهرة ال sis و الترانس؟يعني في ناس بيقولوا وقتش
+
+270
+00:24:29,840 --> 00:24:33,660
+بدأ اقول ان في عندى cis و trans او لأ بنقول القاتل
+
+271
+00:24:33,660 --> 00:24:38,740
+ظاهرة ال cis و ال trans توجد في مكانين اما في
+
+272
+00:24:38,740 --> 00:24:45,400
+الحلقات او المكان التاني حول الروابط الزوجية صار
+
+273
+00:24:45,400 --> 00:24:50,320
+عندى نقطة كتير مهمة ناس بدهم يفهموا كل موضوع
+
+274
+00:24:53,400 --> 00:24:58,400
+كل موضوع ال sis و ال trans وين عمره يمر علي كلمة
+
+275
+00:24:58,400 --> 00:25:07,120
+sis و ال trans بنقول ال sis و ال trans هتشوفهم
+
+276
+00:25:07,120 --> 00:25:18,180
+بمكانين sis و ال trans اما في ال cycles او في ال
+
+277
+00:25:18,180 --> 00:25:23,160
+alkenesالالكينز اللي فيها روابط الزوجين هذا المكان
+
+278
+00:25:23,160 --> 00:25:29,940
+اللي بتشوفه فيه كلمة sis و trans في ال cycles مثل
+
+279
+00:25:29,940 --> 00:25:35,680
+المثال اللي احنا رسمنا زي ما قولنا هذا مثلا بهذا
+
+280
+00:25:35,680 --> 00:25:43,400
+الشكل sis و بهذا الشكل ال trans هاي بال cycle اللي
+
+281
+00:25:43,400 --> 00:25:48,970
+اتعرفنا عليه طيب حوالين ال double bondنفس الاشي لو
+
+282
+00:25:48,970 --> 00:25:52,810
+تخيل انه عندنا carbon double bond carbon حطينا
+
+283
+00:25:52,810 --> 00:25:59,310
+زرتين كلور بهذا الشكل وهنا carbon double bond
+
+284
+00:25:59,310 --> 00:26:07,670
+carbon حطينا زرتين كلور بهذا الشكل هذا
+
+285
+00:26:07,670 --> 00:26:12,890
+إثالين وهذا إثالين هذولة زرتين كلور على واحد
+
+286
+00:26:12,890 --> 00:26:20,030
+واتنين على جهة واحدةانا على واحد و اتنين و اتنين
+
+287
+00:26:20,030 --> 00:26:24,370
+على جهتين مختلفتين اذا الاتنين اسمه one two
+
+288
+00:26:24,370 --> 00:26:33,450
+dichloroethane طب كيف بدي اميزهم هدوله sis و هدوله
+
+289
+00:26:33,450 --> 00:26:38,010
+ال trans هدوله ال sis و هدوله ال trans فدائرة ال
+
+290
+00:26:38,010 --> 00:26:42,570
+sis و ال trans مكان وجودها في الدنيا مكانين ال
+
+291
+00:26:42,570 --> 00:26:44,790
+cycloalkenes و
+
+292
+00:26:46,730 --> 00:26:51,230
+الالكايز الالكينز عفوا ليش هذا الكلام بيتم لأنه
+
+293
+00:26:51,230 --> 00:26:56,390
+انا لو جربت في cycle الكل بدي ألوف هذا هيك أخلي
+
+294
+00:26:56,390 --> 00:27:00,470
+هدول يصيروا عكس بعض يعني ال 6 يصير ال trans لاحظوا
+
+295
+00:27:00,470 --> 00:27:05,210
+لأنه مربوط بالحلقة الدوران حول الحلقة ممنوع
+
+296
+00:27:05,210 --> 00:27:11,210
+الدوران حول الحلقة ممنوع الان طيب لو اتخيلتوا ان
+
+297
+00:27:11,210 --> 00:27:19,360
+انا في عندهالكين وهي مُركّب الـ CIS مش هذا
+
+298
+00:27:19,360 --> 00:27:25,900
+المُركّب اللي مرسوم CIS 1,2-dichloroethane الأن
+
+299
+00:27:25,900 --> 00:27:31,860
+لاحظوا لو بدى ألف و أخلي هدولة يصيروا عكس بعضبرضه
+
+300
+00:27:31,860 --> 00:27:35,500
+لأن الرابطة الزوجية رابطة قوية الدوران حولها
+
+301
+00:27:35,500 --> 00:27:43,500
+ممنوعة إذا العامل المشترك في هذا الموضوع ما بين
+
+302
+00:27:43,500 --> 00:27:51,800
+الحلقة و ما بين الألكين أنه في الحالتين الدوران
+
+303
+00:27:51,800 --> 00:27:57,040
+ممنوعة لذلك مقدرش أنا أعمل دوران أحول واحد للتاني
+
+304
+00:27:59,010 --> 00:28:05,410
+فكل واحد منهم بيصير مركّب منفصل بخواص منفصلة بمعنى
+
+305
+00:28:05,410 --> 00:28:10,150
+لو واحدة راحت تشتري مركّب كيميائي جالت بدّي one
+
+306
+00:28:10,150 --> 00:28:15,030
+two dichlorocyclopropane البياحة يقولها مافيش
+
+307
+00:28:15,030 --> 00:28:20,230
+عندى، في عندى؟two bottles مرتبانين واحد بكتب عليه
+
+308
+00:28:20,230 --> 00:28:26,170
+sis والتاني trans واضح الفكرة زي لما الواحدة
+
+309
+00:28:26,170 --> 00:28:31,510
+بيجيها مولود مافيش يكون عشوائي يا ولد يا بنت لو
+
+310
+00:28:31,510 --> 00:28:37,030
+قلنا مثلا one two dichloroethaneروحنا نشتريه،
+
+311
+00:28:37,030 --> 00:28:42,930
+مافيش، هتلاقوا عند البائع two bottles مرتبان CES 1
+
+312
+00:28:42,930 --> 00:28:49,270
+,2-dichloroethane بقواص معينة و بظائف معينة في
+
+313
+00:28:49,270 --> 00:28:54,590
+الحياة و هتلاقوا مركب تاني مختلف ال Trans و زي ما
+
+314
+00:28:54,590 --> 00:28:59,520
+قلنا العلاقة بين هدولة VRDiastereomers they are
+
+315
+00:28:59,520 --> 00:29:04,740
+non mirror images كلام سليم ولا لأ؟ مش صورة بعض في
+
+316
+00:29:04,740 --> 00:29:10,720
+المرأة في الخصائص
+
+317
+00:29:10,720 --> 00:29:16,420
+الفيزيائية أكيد و الكيميائية بيختلفوا في كل شيء
+
+318
+00:29:16,420 --> 00:29:21,910
+صاروا مركبينواضح مركبين they have different
+
+319
+00:29:21,910 --> 00:29:24,810
+physical properties، واحد من نقطة غليانه مثلا
+
+320
+00:29:24,810 --> 00:29:29,970
+سبعين، التانه نقطة غليانه تسعين، يختلفوا، واضح
+
+321
+00:29:29,970 --> 00:29:37,080
+الفكرة؟الان البعض احيانا بيقول طيب وكتش انا ممكن
+
+322
+00:29:37,080 --> 00:29:42,040
+يكون عندى ظاهرة ال sesual trance وانتبه لها اكثر و
+
+323
+00:29:42,040 --> 00:29:47,880
+وكتش لأ يعني لما أخدنا هذا المركب اللى حطينا فيه
+
+324
+00:29:47,880 --> 00:29:53,180
+chlorine و chlorine هنا طبعا اكيد هنا في hydrogen
+
+325
+00:29:53,180 --> 00:29:59,760
+ماجيبناش سيرة sesual tranceجيبناه إيش صيرت Sis &
+
+326
+00:29:59,760 --> 00:30:05,580
+Trans؟ وسمناها one-one-dichlorocyclo
+
+327
+00:30:05,580 --> 00:30:11,080
+-propane كذلك الحالة لو أنا انطلقت من الاثيليل
+
+328
+00:30:11,080 --> 00:30:16,540
+وحطيت ذرتين كلور على ال carbon الأولى يعني كان
+
+329
+00:30:16,540 --> 00:30:19,600
+عندى هذا المركب carbon double bond carbon ..
+
+330
+00:30:22,850 --> 00:30:26,870
+لو كان عندى هذا المركب carbon double bond carbon
+
+331
+00:30:26,870 --> 00:30:32,450
+وحطيت ذرتين كلور على الموقع الأول وقلنا إيش هذا
+
+332
+00:30:32,450 --> 00:30:39,880
+بدنا نسميهone one dichloroethane one one
+
+333
+00:30:39,880 --> 00:30:44,680
+dichloroethane مظبوط ولا لأ الان جيبنا هانة صيرت
+
+334
+00:30:44,680 --> 00:30:50,740
+cis و trans هان اه هان اه طيب بيصير سؤال وكتش
+
+335
+00:30:50,740 --> 00:30:54,360
+بيكون عندى ظاهرة ال cis و ال trans كلها موجودة
+
+336
+00:30:54,360 --> 00:31:00,220
+وكتش لأ الجواب بسيطبطلّع على الطرفين اللي بيحملوا
+
+337
+00:31:00,220 --> 00:31:03,920
+الذرات اللي هم الطرفين ال double bond أو الطرفين
+
+338
+00:31:03,920 --> 00:31:08,760
+اللي هنا إذا كانت كل ذرة تحمل مجموعتين مختلفتين
+
+339
+00:31:08,760 --> 00:31:11,760
+بيكون عند السيس و ترانس يعني هاي ال double bond
+
+340
+00:31:11,760 --> 00:31:19,200
+هادي غير هادي إذا هدوله مختلفتان ولا لأ هادي غير
+
+341
+00:31:19,200 --> 00:31:24,910
+هادي هدول مختلفتان و هدول مختلفتانإذا في عندي أكيد
+
+342
+00:31:24,910 --> 00:31:28,970
+من هذا المركب sis و trans هذا ال sis كيف بدي أجيب
+
+343
+00:31:28,970 --> 00:31:36,230
+لل trans؟ بال rotation؟ خليني أقول لو جيبنا لكوا
+
+344
+00:31:36,230 --> 00:31:42,070
+سؤال كيف نحول مركب ال sis إلى ال trans؟ أو نقول
+
+345
+00:31:42,070 --> 00:31:46,070
+sis compounds can be converted to trans by
+
+346
+00:31:46,070 --> 00:31:50,810
+rotation هاي الدوران جادر يلوف؟ لأ طب لو بدي أخلي
+
+347
+00:31:50,810 --> 00:31:58,660
+هذا ال sis transbond breaking bond formation اذا
+
+348
+00:31:58,660 --> 00:32:03,740
+انا كيف بحول السسلة ل Trans بال bond breaking و
+
+349
+00:32:03,740 --> 00:32:07,220
+bond formation بكسر الروابط و بحطها من اول و جديد
+
+350
+00:32:07,220 --> 00:32:11,150
+بس الدوران لا يؤدي الى هذا الكلامهنا صرت ما أعطيكم
+
+351
+00:32:11,150 --> 00:32:15,190
+كمان معلومتين إضافيتين عن ظاهرة الـ sexual trance
+
+352
+00:32:15,190 --> 00:32:20,110
+عشان توجد كظاهرة لابد كل carbon من أطراف الـ
+
+353
+00:32:20,110 --> 00:32:26,170
+double bond تحمل مجموعتين مختلفتينواضح؟ و لو بدى
+
+354
+00:32:26,170 --> 00:32:32,790
+احول ال 6 والترانس لازم اعمل
+
+355
+00:32:32,790 --> 00:32:36,870
+bond breaking و bond formation هذا الكلام بينطبق
+
+356
+00:32:36,870 --> 00:32:40,550
+على ال alkenes اللي فيهم ظاهرة ال 6 والترانس و
+
+357
+00:32:40,550 --> 00:32:46,810
+بينطبق أيضا على ال cycloalkenes كل هذه مفاهيم
+
+358
+00:32:46,810 --> 00:32:54,970
+أساسية و مهمة جدا في فعلنا لهذه الظاهرةالـ
+
+359
+00:32:54,970 --> 00:32:58,130
+Stereoisomers أو الـ Diastereomers اللي هي ظاهرة
+
+360
+00:32:58,130 --> 00:33:02,910
+الـ cis والترانس مكان وجودها الـ Cycloalkynes و
+
+361
+00:33:02,910 --> 00:33:09,230
+الـ Alkenes شرط وجودها ان كل طرف من الأطراف تبعت
+
+362
+00:33:09,230 --> 00:33:14,670
+ال carbons المكونة للـ double bond بتحمل مجموعتين
+
+363
+00:33:14,670 --> 00:33:17,890
+مختلفتين عشان ايك لو حد انا بدي احكي عن ال cis
+
+364
+00:33:17,890 --> 00:33:22,420
+والترانس هذه ال carbon شو بتحمل؟نفس المجموعات، هذا
+
+365
+00:33:22,420 --> 00:33:26,000
+ال carbo شو بتحمل؟ هذا شو بتحمل؟ أنا مافيش عنده ال
+
+366
+00:33:26,000 --> 00:33:31,060
+cis و ال trans، خلاص هو مركّب واحد، واضح؟ شرط فكرة
+
+367
+00:33:31,060 --> 00:33:37,870
+ال cis و ال trans أنه يكون عندهع كل طرف من أطراف
+
+368
+00:33:37,870 --> 00:33:41,250
+ال carbon سواء في الحلقة أو في ال double bond
+
+369
+00:33:41,250 --> 00:33:45,510
+مجموعات مختلفة ولذلك لو سألنا مثلا يا ترى هذا
+
+370
+00:33:45,510 --> 00:33:49,210
+المركب ال carbon double bond carbon وحطين هنا CL و
+
+371
+00:33:49,210 --> 00:33:54,690
+هنا CL و هنا H و هنا CL هل هذا في منه cis و trans؟
+
+372
+00:33:54,690 --> 00:34:02,790
+لأ هذا فقط مركب واحد لأن هنا HCL مختلفة لكن نفس
+
+373
+00:34:02,790 --> 00:34:12,160
+الشيءو شرط ال sis و ال trans مختلفة مختلفة غير هيك
+
+374
+00:34:12,160 --> 00:34:18,320
+ما بنتكلمش عن sis و trans سواء كنا بنحكي في ال ال
+
+375
+00:34:18,320 --> 00:34:25,600
+keys أو كنا بنحكي في الحلقات ال cyclo ال keys
+
+376
+00:34:30,680 --> 00:34:36,320
+أتعمقنا كثير في الـ Cyclopropane لكن أخدنا معلومات
+
+377
+00:34:36,320 --> 00:34:42,820
+كثير مهمة بخصوص ظاهرة بتتكرر معنا سواء الآن أو في
+
+378
+00:34:42,820 --> 00:34:48,060
+المستقبل لما ندرس ال الكينز الآن لو إجيت لمركب
+
+379
+00:34:48,060 --> 00:34:50,380
+الـcyclobutane
+
+380
+00:34:53,020 --> 00:34:57,300
+كم هيدروجين فيه؟ أربع كربونات كل كربون تو
+
+381
+00:34:57,300 --> 00:35:03,960
+هيدروجين؟ تمانية التمانية they are equivalent يعني
+
+382
+00:35:03,960 --> 00:35:09,020
+لو كنت أعمل عليه monochlorination بطلع بس مركب
+
+383
+00:35:09,020 --> 00:35:14,340
+واحد لكن لو قلنا نبدأ بالcyclobutane ونعمل
+
+384
+00:35:14,340 --> 00:35:20,260
+dichlorination هيطلع عندنا أكيد عدد أكبر من
+
+385
+00:35:20,260 --> 00:35:24,940
+المركباتواضح؟ يعني انتوا تخيلوا مش كل شي بدنا
+
+386
+00:35:24,940 --> 00:35:28,500
+نفصله بدنا نسيب شي انتوا تجربوه في البيت يعني هي
+
+387
+00:35:28,500 --> 00:35:33,360
+عندى ذرة الكلور الأولى و هنا فيه H لو بدى أحط كلور
+
+388
+00:35:33,360 --> 00:35:41,880
+تانية ممكن أحطها على الموقع الأول اعمل one one
+
+389
+00:35:41,880 --> 00:35:46,200
+dichlorocyclopropane صحيه ولا لأ؟ ممكن أحطها على
+
+390
+00:35:46,200 --> 00:35:53,330
+الموقع التانيأو Trans ممكن احطه على الموقع التالت
+
+391
+00:35:53,330 --> 00:35:59,030
+ايضا SIS او Trans بمعنى في الحلقة مش ضروري مش
+
+392
+00:35:59,030 --> 00:36:02,830
+ضروري ان ال SIS و ال Trans يكونوا جانب بعض يعني
+
+393
+00:36:02,830 --> 00:36:09,910
+هاي تخيلوا هذا Cyclobutane تجاوزا هاي ذرتين لكلور
+
+394
+00:36:09,910 --> 00:36:15,960
+خلينا نتخيلهم باللون الأحمر هذا المركب اي مركبone
+
+395
+00:36:15,960 --> 00:36:22,040
+one-dichlorocyclobutane، الآن هذا المركّب one two
+
+396
+00:36:22,040 --> 00:36:30,660
+-cis، هذا one two-trans، هذا one three-cis، هذا
+
+397
+00:36:30,660 --> 00:36:36,200
+one three-transواضح؟ يعني مش ضروري ان ال sis و ال
+
+398
+00:36:36,200 --> 00:36:39,360
+trans في الحلقة انهم يكونوا جانب بعض ممكن يكونوا
+
+399
+00:36:39,360 --> 00:36:42,480
+على واحد اتنين او على واحد تلات في الحلقات الأكبر
+
+400
+00:36:42,480 --> 00:36:47,980
+ممكن يكونوا أبعد كمان واضح؟ بتظهر نقطة الحقيقة في
+
+401
+00:36:47,980 --> 00:36:54,020
+موضوع ال cyclobutane ان هل يا ترى ال cyclobutane
+
+402
+00:36:54,020 --> 00:37:00,440
+بلانربهذا الشكل؟ الجواب لو كنا بنطلع على الزوايا
+
+403
+00:37:00,440 --> 00:37:04,940
+تبعته بشكل دقيق هو مش planner هو شوية بيقول عنه
+
+404
+00:37:04,940 --> 00:37:09,500
+puckered يعني مثني شوية لجوا الان بيشبه ايش بهذا
+
+405
+00:37:09,500 --> 00:37:16,000
+الشكل الفراشة ال butterflyواضح؟ فالـ cyclobutane
+
+406
+00:37:16,000 --> 00:37:21,580
+is not a planar molecule مش موجود بهذا الشكل في
+
+407
+00:37:21,580 --> 00:37:27,640
+مستوى واحد لأ من ثاني شوية للداخل عامل زي الفراشة
+
+408
+00:37:27,640 --> 00:37:34,760
+بتعرفوا أنتوا كيف عادة بترسموا الفراشة؟ فأنا لو
+
+409
+00:37:34,760 --> 00:37:39,140
+بدأ أرسم ال cyclobutane بهذا الشكل بارسمه واحد
+
+410
+00:37:39,140 --> 00:37:41,840
+اتنين تلاتة أربع هذه الأربع كربونات
+
+411
+00:37:44,220 --> 00:37:51,580
+cyclobutane is not a planar molecule الان تقريبا
+
+412
+00:37:51,580 --> 00:37:58,240
+المعلومات بتصير تتكرر هنا قولنا زي الاش زي ال
+
+413
+00:37:58,240 --> 00:38:03,900
+butter fly اللي هي الفراشة طب لو بدى احكي عن
+
+414
+00:38:03,900 --> 00:38:08,000
+الcyclobutane معلومات ال cis و ال trans و ال
+
+415
+00:38:08,000 --> 00:38:13,160
+substitution نفس الشيءممكن تعملوا على اكثر من موقع
+
+416
+00:38:13,160 --> 00:38:19,400
+لكن لو كنت بده احط اول كلور العشرة هيدروجين هم
+
+417
+00:38:19,400 --> 00:38:24,800
+اكويفلانت عشان ايه لما بده اعمل monochlorination
+
+418
+00:38:24,800 --> 00:38:28,960
+يعني بس one كلور بده يطلع عندى مركب بعدين لما بده
+
+419
+00:38:28,960 --> 00:38:32,740
+اعمل dichlorination بطلع عندى اكثر من مركب
+
+420
+00:38:32,740 --> 00:38:36,900
+بإمكانكوا تحسبوهم و تجمعوهم طب يا تورا لو حكيت عن
+
+421
+00:38:36,900 --> 00:38:42,220
+الشكل تبعه هل هو planner؟الجواب لأ مش planner طب
+
+422
+00:38:42,220 --> 00:38:45,920
+هى زى إيش بيعمل الآن تخيلوا هى الحلقة الخماسية
+
+423
+00:38:45,920 --> 00:38:50,420
+شايفينها هى دى اللى أمامكوا حلقة خماسية ولا لأ؟
+
+424
+00:38:50,420 --> 00:38:57,600
+واحد تانين تلاتة أربعة خمسة هيك بتكون planner لكن
+
+425
+00:38:57,600 --> 00:39:03,100
+هى عاملة بهذا الشكل الآن هذا الشكل لو كنا نعطيه
+
+426
+00:39:03,100 --> 00:39:09,040
+اسمبنقول عنه non planner أكيد لكن إله اسم أمركوا
+
+427
+00:39:09,040 --> 00:39:17,720
+شفتوا ضرف مغلف رسالة مفتوح it is like an open
+
+428
+00:39:17,720 --> 00:39:23,380
+envelope فهذا الشكل لو قلنا لكوا عنه planner لأ
+
+429
+00:39:23,380 --> 00:39:29,640
+هتقولوا it is like an open envelope اللي هو ضرف
+
+430
+00:39:29,640 --> 00:39:37,370
+رسالة مفتوح لو كنتوا بتكونوا ترسموهبشكل فراغي open
+
+431
+00:39:37,370 --> 00:39:41,350
+envelope مش envelope ال .. الظرف تبع الرسالة و
+
+432
+00:39:41,350 --> 00:39:45,050
+الموضوع it is like an open envelope لو بدي ارسمه
+
+433
+00:39:45,050 --> 00:39:49,990
+بهذا الشكل بارسمه فال Cyclopropane is a planar
+
+434
+00:39:49,990 --> 00:39:56,970
+Cyclobutane لأ Cyclopentane لأ الان لو انتقلنا بعد
+
+435
+00:39:56,970 --> 00:40:00,980
+هيك لل Cyclohexaneلاحظوا ال Cyclohexane الكلام
+
+436
+00:40:00,980 --> 00:40:04,100
+اللي موجود عليه في الدنيا كتير جدا احنا بنعطيه
+
+437
+00:40:04,100 --> 00:40:09,880
+مختصر للمختصر عليه ليش؟ لأن عليه كلام كتير لو كان
+
+438
+00:40:09,880 --> 00:40:15,340
+بهذا الشكل بيكون planner هي حلقة سدسية شايفينها
+
+439
+00:40:15,340 --> 00:40:19,780
+الواقع ان ال Cyclohexane مش زي هيك لما نتعلم في
+
+440
+00:40:19,780 --> 00:40:25,100
+chapter 4 عن البنزين البنزين زي هيك plannerالبنزين
+
+441
+00:40:25,100 --> 00:40:33,820
+C6H6 بلانر لكن الـCyclohexane ليس مليكيوم بلانر مش
+
+442
+00:40:33,820 --> 00:40:38,520
+بلانر طب ها كيف بينوجد؟ ممكن ينوجد على أكثر من
+
+443
+00:40:38,520 --> 00:40:42,860
+هيئة هيئة بيقول عنها confirmation confirmation
+
+444
+00:40:42,860 --> 00:40:47,820
+هيئة بمعنى ممكن نمسكه بهذا الشكل لاحظوا نفس الحلقة
+
+445
+00:40:47,820 --> 00:40:52,200
+شايفين كيف أنا مسكها؟الان هذا الشكل اللي انا ماسكه
+
+446
+00:40:52,200 --> 00:40:59,000
+يشبه ماذا؟ القارب او الزورق بسمي انا هيئة القارب
+
+447
+00:40:59,000 --> 00:41:04,740
+boat confirmation boat confirmation موجود عندكم
+
+448
+00:41:04,740 --> 00:41:13,520
+ربما بهذا المكان شايفينه؟
+
+449
+00:41:14,650 --> 00:41:19,050
+بهذا الشكل بيرسم بسهولة boat conformation يمكن أن
+
+450
+00:41:19,050 --> 00:41:26,830
+يكون على هيئة القارب بهذا الشكل و يمكن أن يكون على
+
+451
+00:41:26,830 --> 00:41:34,270
+هيئة الكرسي لو تخيلته زي هيك هي كأنه هذا كرسي هي
+
+452
+00:41:34,270 --> 00:41:37,910
+الرجلين وهي القاعدة اللي الناس بيجلس عليها وهي
+
+453
+00:41:37,910 --> 00:41:42,100
+الظهرطبعا هذا ال chair confirmation و ال boat
+
+454
+00:41:42,100 --> 00:41:46,020
+confirmation بيجلبه يعني هذا الشكل زي ما بتكون
+
+455
+00:41:46,020 --> 00:41:51,040
+تماما معاكم الشمسية ال umbrella في يوم عاصف كيف
+
+456
+00:41:51,040 --> 00:41:56,960
+بتكون؟ بتجلب للأمام و للخلف؟ هاد العملية بسميها
+
+457
+00:41:56,960 --> 00:42:03,200
+عشان flipping الشكل لما بيصير يجلب بهذا الشكل لفوق
+
+458
+00:42:03,200 --> 00:42:06,940
+لتحت زي الشمسية ما بتعمل بسمي العملية عشان
+
+459
+00:42:06,940 --> 00:42:07,540
+flipping
+
+460
+00:42:10,670 --> 00:42:17,390
+flipping الآن ممكن الـcyclohexane يكون بلحظة boat
+
+461
+00:42:17,390 --> 00:42:22,970
+هذه تجلب لتحت صار chair لحظة هذا ال chair هيظهر
+
+462
+00:42:22,970 --> 00:42:26,790
+للخلف و الأرجل للأمام ممكن تجلب هذه الأرجل تصير
+
+463
+00:42:26,790 --> 00:42:31,830
+بهذا الشكل و بهذا الشكل هو في حالة تقلب دائم يعني
+
+464
+00:42:31,830 --> 00:42:37,390
+الذرات في حالة تقلب دائما تماما مثل مثل إيش شمسية
+
+465
+00:42:37,390 --> 00:42:41,930
+في مهب الريحمثل مثل ال umbrella أو الشمسية في ماب
+
+466
+00:42:41,930 --> 00:42:47,450
+بالريح إذا هو يمكن أن يوجد على هيئة القارب ويمكن
+
+467
+00:42:47,450 --> 00:42:54,680
+أن يوجد على هيئةالكرسي لـ Chair Conformation أو
+
+468
+00:42:54,680 --> 00:43:00,120
+Boat Conformation واضح؟ زي ما حكيت، كثير فيه
+
+469
+00:43:00,120 --> 00:43:04,080
+تفاصيل للهيدروجينات و التركيبة لكن احنا بنتجاوز
+
+470
+00:43:04,080 --> 00:43:08,780
+هذا الكلام، بنقف ان الـCyclohexane ممكن يكون على
+
+471
+00:43:08,780 --> 00:43:12,500
+شكل الـChair Conformation وبيعمل flipping، بيقلب
+
+472
+00:43:13,380 --> 00:43:19,880
+مرة تانية انا اكد عادى الظاهر هيه بهذا الشكل بيكون
+
+473
+00:43:19,880 --> 00:43:23,500
+share و بيصير boat و بيرجع ت share و ت share بهذا
+
+474
+00:43:23,500 --> 00:43:27,040
+الشكل و ت share بهذا الشكل هو في حالة تقلب ايش
+
+475
+00:43:27,040 --> 00:43:32,860
+دائم الان اي الأشكال اثبت معنى اثبت هنا انه بيقضي
+
+476
+00:43:32,860 --> 00:43:37,380
+في وقت كتير ال share ولا ال boat ال share بنقول
+
+477
+00:43:37,380 --> 00:43:43,580
+عنه is more stable than the boatmore stable معناه
+
+478
+00:43:43,580 --> 00:43:48,360
+more stable أنه أنا لو بتطلع عليه و هو بيجلب هو
+
+479
+00:43:48,360 --> 00:43:53,440
+يتقلب بين هذه الأشكال لكن يبقى لفترة أطول على هيئة
+
+480
+00:43:53,440 --> 00:43:58,580
+إيش الكرسي يبقى لفترة أطول على هيئة الكرسي الآن
+
+481
+00:43:58,580 --> 00:44:04,040
+عملية أنهليش لفترة أطول على هيئة الكرسي؟ ليش هذا
+
+482
+00:44:04,040 --> 00:44:08,140
+أثبت؟ ما إلى ذلك؟ هذا الكلام لطلبة مختصين في
+
+483
+00:44:08,140 --> 00:44:12,600
+الكيميا فيه تفصيل كتير، يعني اللي الآن بنحكيه بخمس
+
+484
+00:44:12,600 --> 00:44:17,480
+دقائق، بنعمله فصل كامل لطالب الكيميا يتعمق فيه
+
+485
+00:44:17,480 --> 00:44:20,140
+بالcyclohexane، لكن احنا الآن اللي بنايعه
+
+486
+00:44:20,140 --> 00:44:25,480
+الcyclohexaneكلام بسيط ان هو non planar molecule
+
+487
+00:44:25,480 --> 00:44:30,700
+يوجد فيه اكتر من conformation هيئة منها ال boat
+
+488
+00:44:30,700 --> 00:44:35,420
+conformation و ال chair conformation واضح ال boat
+
+489
+00:44:35,420 --> 00:44:39,120
+conformation و ال chair conformation اكتر من هيك
+
+490
+00:44:39,120 --> 00:44:45,770
+مابدناش نتكلم عن هذا الموضوعطبعا الكلام اللي هو
+
+491
+00:44:45,770 --> 00:44:50,290
+حكيناه عن الـcis و الـtrans في الحلقات الخماسية
+
+492
+00:44:50,290 --> 00:44:54,790
+والسوداسية والسبعية والربعية والثلاثية كله موجود
+
+493
+00:44:54,790 --> 00:45:00,910
+واضح؟ كله موجود أخر شغلة بدنا نتكلمها اليوم إن شاء
+
+494
+00:45:00,910 --> 00:45:09,660
+الله تفاعلات الالكانز تفاعلات الالكانزقليلة جدا،
+
+495
+00:45:09,660 --> 00:45:12,880
+عشانيك احنا بنقول الالكينز they are generally
+
+496
+00:45:12,880 --> 00:45:17,220
+inert، ايش يعني inert؟ يعني قليلة التفاعلات،
+
+497
+00:45:17,220 --> 00:45:21,540
+عشانيك كل اشي inert يستعمل ك solvent، يعني يستعمل
+
+498
+00:45:21,540 --> 00:45:25,680
+كمثيب عضوي، لأن الأشياء بتكون في قلبه و بتفعلش
+
+499
+00:45:25,680 --> 00:45:32,220
+معها، في تفاعل مشهور جدا للالكينز، ان الالكينز لو
+
+500
+00:45:32,220 --> 00:45:36,840
+حرقناهم في وجود الأكسجين، بيعطونا ثانو أكسيد كربون
+
+501
+00:45:36,840 --> 00:45:42,940
+وماءوهذا التفاعل هو تفاعل حرق الغاز المنزلي لما
+
+502
+00:45:42,940 --> 00:45:47,660
+احنا بنشعل الغاز هو تفاعل حرق على سبيل المثال
+
+503
+00:45:47,660 --> 00:45:53,220
+الوقود البنزين والديزل في السيارات كله الكان
+
+504
+00:45:53,220 --> 00:45:58,180
+بنحرقه في وجود ال oxygen بنسمي العملية combustion
+
+505
+00:45:58,180 --> 00:46:03,200
+إيش يعني combustion burning in the presence of
+
+506
+00:46:03,200 --> 00:46:09,540
+oxygen burning يعني burningin the presence of
+
+507
+00:46:09,540 --> 00:46:17,980
+oxygen ايش بيعطيني؟ ثاني أكسيد كربون وماء بدون ما
+
+508
+00:46:17,980 --> 00:46:21,480
+ندخل بتفاصيل الأرقام كيف توزن المعادلة مش الموضوع
+
+509
+00:46:21,480 --> 00:46:26,400
+احنا بهمنا الآن النتيجة ان الالكينز بصير التفاعل
+
+510
+00:46:26,400 --> 00:46:32,700
+مع الأكسجين تعطيتانو أكسيد كربون و ماء زائد و ربما
+
+511
+00:46:32,700 --> 00:46:37,880
+أهم من الشغلتين بالنسبة لنا ال heat الحرارة عشان
+
+512
+00:46:37,880 --> 00:46:41,380
+هيك حرق الغاز و حرق البنزين اللي بيعطيني حرارة
+
+513
+00:46:41,380 --> 00:46:45,700
+بشغل عليها موقد الغاز بمشي عليها السيارة كل هذه
+
+514
+00:46:45,700 --> 00:46:50,130
+الأشياءالشغل التاني أو التفاعل التاني ال
+
+515
+00:46:50,130 --> 00:46:54,270
+halogenation هو التفاعل مع ال halogens الكلور و
+
+516
+00:46:54,270 --> 00:46:58,690
+البرومي بشكل أساسي عادة يتم هذا التفاعل في وجود
+
+517
+00:46:58,690 --> 00:47:01,210
+الحرارة أو الضوء
+
+518
+00:47:17,340 --> 00:47:22,460
+كم عدد النواتج اللي بتطلع؟ يعتمد على أنواع
+
+519
+00:47:22,460 --> 00:47:27,240
+الهيدروجين يعني لو كان المركب اللي عندكم هو
+
+520
+00:47:27,240 --> 00:47:32,340
+البروبين زي ما احنا حكينا وين
+
+521
+00:47:32,340 --> 00:47:38,040
+هيحط ال chlorine؟ يا ع موقع واحد و ال chlorine و
+
+522
+00:47:38,040 --> 00:47:40,400
+البروبين يا ع موقع اتنين اتنين اتنين اتنين اتنين
+
+523
+00:47:40,400 --> 00:47:40,820
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+524
+00:47:40,820 --> 00:47:41,480
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+525
+00:47:41,480 --> 00:47:41,500
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+526
+00:47:41,500 --> 00:47:46,500
+اتنين اتنين اتنين اتنين اتنين اتنين ااو ايزوبروبل
+
+527
+00:47:46,500 --> 00:47:49,900
+اكلورايد لو نفس المراكب بيقولنا بيعمله
+
+528
+00:47:49,900 --> 00:47:56,090
+دايكلوريلاشينوين ممكن احض دارتين لكلور؟ يا على
+
+529
+00:47:56,090 --> 00:47:59,750
+نمرة واحد واحد بيصير one one dichlorobropane يا
+
+530
+00:47:59,750 --> 00:48:07,150
+على واحد واثنين يا ع اتنين واثنين او ع واحد واثنين
+
+531
+00:48:07,150 --> 00:48:11,170
+او ع واحد تلاتة اذا لو انا قلتلكم dichlorination
+
+532
+00:48:11,170 --> 00:48:16,210
+of a propane produces come isomers كي بتكون تعمله
+
+533
+00:48:16,210 --> 00:48:22,960
+و تجربه بالورقة و الجلمتستفيدوا من كل المعلومات
+
+534
+00:48:22,960 --> 00:48:28,720
+اللي حكيناها بمعنى لو كان السؤال عندكم عن cycle
+
+535
+00:48:28,720 --> 00:48:33,000
+بتعرفوا تجاوبوه احنا اليوم جاوبناها لـcyclopropane
+
+536
+00:48:33,000 --> 00:48:37,220
+قولنا الـ monochlorination بيعطينا كام مركب؟ واحد
+
+537
+00:48:37,220 --> 00:48:43,300
+ال-dichlorination بيعطينا كام مركب؟ تلاتةسمناهم
+
+538
+00:48:43,300 --> 00:48:48,640
+one one و one two six و one two .. Trans مظبوط ولا
+
+539
+00:48:48,640 --> 00:48:53,860
+لأ؟ و هكذا دائما ممكن يجيكم أسئلة و ممكن الأن
+
+540
+00:48:53,860 --> 00:48:58,540
+ماعطيكم سؤالين أنتوا تحلوهم لوحدكم تتدربوا عليهم و
+
+541
+00:48:58,540 --> 00:49:03,980
+بننهي فيهم المحاضرة لو مثلا قلنالكوا اعملونا لمركب
+
+542
+00:49:03,980 --> 00:49:11,980
+لبيوتينمونو إكلورينايشن ودايكلورينايشن تعملوه و
+
+543
+00:49:11,980 --> 00:49:16,400
+تسلمونا إياه و لهذا المُركّب لو تخيلتوا إنه في
+
+544
+00:49:16,400 --> 00:49:23,000
+عندكم مثل سايكلوبروبين شايفينه
+
+545
+00:49:23,000 --> 00:49:29,160
+المُركّب؟ إيش اسمه؟ مثل سايكلوبروبين اعملوله مونو
+
+546
+00:49:29,160 --> 00:49:34,510
+إكلورينايشنوDichlorination وشوفوا كم ناتج بيطلع
+
+547
+00:49:34,510 --> 00:49:38,230
+عندكم طبعا بتكونوا تنتبهوا ان الchlorination ممكن
+
+548
+00:49:38,230 --> 00:49:43,330
+يجي على المثل او على الحلقة بدي كل النواتج الممكنة
+
+549
+00:49:43,330 --> 00:49:47,830
+وهنا كل النواتج الممكنة هذا بحاجة انكوا تتدربوا
+
+550
+00:49:47,830 --> 00:49:52,700
+بشكل جيدو تعرفوا أنواع الهيدروجينز اللي موجودة و
+
+551
+00:49:52,700 --> 00:49:56,040
+تحددوا كام ناتج بيطلع عندهم من ال monochlorination
+
+552
+00:49:56,040 --> 00:50:00,340
+و ال dichlorination ترسموهم بعد ما ترسموهم انتبهوا
+
+553
+00:50:00,340 --> 00:50:05,180
+إذا في أشكال متشابهة انه ما تكرروهاش وبهيك بننهي
+
+554
+00:50:05,180 --> 00:50:06,040
+اليوم ان شاء الله
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..27db1b25fd229653382ea829fa02b2ffef46e294
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-9ge495lcEc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4909, "start": 21.35, "end": 49.09, "text": "بسم الله الرحمن الرحيم نستأنف اليوم في موضوع ال alkanes و ال cycloalkanes زي ما بتعرفوا المرة الماضية أعطينا فكرة عن ال alkanes من ناحية التسمية و من ناحية بعض الخواص الفيزيائية و من ناحية تركيبها بمعنى عدد ذرات ال carbon و ال hydrogen", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 8717, 14851, 33456, 5172, 45595, 20498, 8978, 3714, 2407, 11242, 45367, 2423, 419, 5225, 279, 4032, 2423, 38154, 752, 667, 12779, 30767, 1829, 19446, 39894, 3615, 28480, 14407, 9673, 25720, 9673, 46958, 10632, 5551, 3615, 9566, 1829, 8315, 6156, 4117, 25720, 18871, 2423, 419, 5225, 279, 9154, 8717, 39319, 10632, 16712, 38251, 10632, 4032, 9154, 8717, 39319, 10632, 45030, 11242, 33962, 2407, 33546, 27188, 1829, 11622, 1829, 16373, 10632, 4032, 9154, 8717, 39319, 10632, 6055, 31747, 1829, 3555, 11296, 4724, 2304, 3615, 1863, 7578, 6225, 3215, 3215, 29910, 2288, 9307, 2423, 5954, 4032, 2423, 12697], "avg_logprob": -0.11331845294861566, "compression_ratio": 1.8254716981132075, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 21.35, "end": 21.69, "word": "بسم", "probability": 0.923828125}, {"start": 21.69, "end": 21.89, "word": " الله", "probability": 0.9697265625}, {"start": 21.89, "end": 22.23, "word": " الرحمن", "probability": 0.9718424479166666}, {"start": 22.23, "end": 22.65, "word": " الرحيم", "probability": 0.99267578125}, {"start": 22.65, "end": 24.33, "word": " نستأنف", "probability": 0.8016357421875}, {"start": 24.33, "end": 24.65, "word": " اليوم", "probability": 0.940185546875}, {"start": 24.65, "end": 24.83, "word": " في", "probability": 0.91259765625}, {"start": 24.83, "end": 25.47, "word": " موضوع", "probability": 0.99365234375}, {"start": 25.47, "end": 25.87, "word": " ال", "probability": 0.9580078125}, {"start": 25.87, "end": 26.57, "word": " alkanes", "probability": 0.5718180338541666}, {"start": 26.57, "end": 26.73, "word": " و", "probability": 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"text": "ثلاثية ال kind صار عندي ال kind هذا ال ال kind الصيغة العامة إيه له CNH2N-2 يعني لما أقول C3H326-2 أربعة شايفين الأربعة", "tokens": [12984, 1211, 5718, 104, 10632, 2423, 733, 20328, 9640, 43242, 1829, 2423, 733, 23758, 2423, 2423, 733, 31767, 1829, 17082, 3660, 18863, 10943, 3660, 11933, 1829, 3224, 46740, 383, 45, 39, 17, 45, 12, 17, 37495, 22653, 5296, 15042, 5551, 39648, 383, 18, 39, 18, 17, 21, 12, 17, 5551, 25513, 27884, 13412, 995, 33911, 9957, 16247, 25513, 27884], "avg_logprob": -0.36640625397364296, "compression_ratio": 1.3695652173913044, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 149.22, "end": 150.24, "word": "ثلاثية", "probability": 0.88115234375}, {"start": 150.24, "end": 150.98, "word": " ال", "probability": 0.638671875}, {"start": 150.98, "end": 151.64, "word": " kind", "probability": 0.166748046875}, {"start": 151.64, "end": 152.38, "word": " صار", "probability": 0.71142578125}, {"start": 152.38, "end": 152.78, "word": " عندي", 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أنا شيلت هيدروجين تان، والواقع أيضا بأيد هالكلام C3H", "tokens": [1344, 66, 752, 667, 1929, 5296, 33456, 3224, 11933, 7435, 995, 9154, 6055, 1211, 2655, 9122, 25513, 2407, 8315, 2655, 4724, 32887, 21292, 1211, 12399, 13412, 2407, 20328, 43500, 5551, 38251, 1829, 3224, 22807, 10295, 3474, 404, 1513, 1929, 23032, 1829, 3555, 12399, 6024, 48506, 23032, 6027, 15042, 41850, 13412, 26895, 2655, 8032, 25708, 2288, 29245, 9957, 6055, 7649, 12399, 16070, 14407, 4587, 3615, 36632, 11242, 995, 4724, 10721, 25708, 8032, 6027, 28820, 10943, 383, 18, 39], "avg_logprob": -0.2944711672189908, "compression_ratio": 1.3609467455621302, "no_speech_prob": 1.4901161193847656e-06, "words": [{"start": 223.54, "end": 224.94, "word": "cycloalkane", "probability": 0.749365234375}, {"start": 224.94, "end": 225.62, "word": " لأنه", "probability": 0.798828125}, {"start": 225.62, "end": 225.92, "word": " إجا", "probability": 0.4177652994791667}, {"start": 225.92, "end": 226.04, "word": " من", "probability": 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" نفس", "probability": 0.751220703125}, {"start": 281.23, "end": 283.63, "word": " الفورمولة", "probability": 0.6754150390625}, {"start": 283.63, "end": 286.75, "word": " CNH2N", "probability": 0.6708984375}, {"start": 286.75, "end": 287.79, "word": " هذه", "probability": 0.716796875}, {"start": 287.79, "end": 288.89, "word": " النقطة", "probability": 0.96337890625}, {"start": 288.89, "end": 289.17, "word": " الأولى", "probability": 0.9454752604166666}, {"start": 289.17, "end": 289.27, "word": " اللى", "probability": 0.801513671875}, {"start": 289.27, "end": 289.39, "word": " بدى", "probability": 0.55810546875}, {"start": 289.39, "end": 289.75, "word": " احكيها", "probability": 0.90830078125}, {"start": 289.75, "end": 289.87, "word": " في", "probability": 0.86865234375}, {"start": 289.87, "end": 290.35, "word": " الموضوع", "probability": 0.99755859375}], "temperature": 1.0}, {"id": 13, "seek": 30724, "start": 292.36, "end": 307.24, "text": "الان لو اتطلعنا اكثر على الـ Cyclopropane بدنا معلومات اكثر عنه، لاحظوا ان تلت ذرات الكربون تبعون الـ Cyclopropane في مستوى واحد، واضح؟", "tokens": [6027, 7649, 45164, 1975, 2655, 9566, 1211, 3615, 8315, 1975, 4117, 49115, 15844, 2423, 39184, 49173, 404, 1513, 1929, 47525, 8315, 20449, 1211, 20498, 9307, 1975, 4117, 49115, 18871, 3224, 12399, 20193, 5016, 19913, 14407, 16472, 6055, 1211, 2655, 29910, 2288, 9307, 33251, 25513, 11536, 6055, 3555, 3615, 11536, 2423, 39184, 49173, 404, 1513, 1929, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 12399, 4032, 46958, 5016, 22807], "avg_logprob": -0.18612131870844784, "compression_ratio": 1.5135135135135136, "no_speech_prob": 0.0, "words": [{"start": 292.36, "end": 292.9, "word": "الان", "probability": 0.798095703125}, {"start": 292.9, "end": 293.88, "word": " لو", "probability": 0.79638671875}, {"start": 293.88, "end": 294.7, "word": " اتطلعنا", "probability": 0.7773030598958334}, {"start": 294.7, "end": 295.16, "word": " اكثر", "probability": 0.8655598958333334}, {"start": 295.16, 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"probability": 0.875}], "temperature": 1.0}, {"id": 19, "seek": 43892, "start": 416.2, "end": 438.92, "text": "نوع واحد بمعنى لو انا امسكت ذرة كلور خلّينا نفترض هذه لمخ اللون الأخضر بدي اشيل اي هيدروجين و احط مكانها كلور مش هذا تفاعل ابدال بدلنا هيدروجين بكلور الان لو شيلت هذه و حطيت كلور هيطلع عندى مركب", "tokens": [1863, 45367, 36764, 24401, 4724, 2304, 3615, 1863, 7578, 45164, 1975, 8315, 1975, 2304, 3794, 4117, 2655, 29910, 25720, 28242, 13063, 16490, 1211, 11703, 9957, 995, 8717, 5172, 2655, 43042, 29538, 32767, 9778, 13672, 11536, 16247, 9778, 11242, 2288, 4724, 16254, 1975, 8592, 26895, 1975, 1829, 8032, 25708, 2288, 29245, 9957, 4032, 1975, 5016, 9566, 3714, 41361, 11296, 28242, 13063, 37893, 23758, 6055, 5172, 995, 30241, 1975, 44510, 6027, 47525, 1211, 8315, 8032, 25708, 2288, 29245, 9957, 4724, 28820, 13063, 2423, 7649, 45164, 13412, 26895, 2655, 29538, 4032, 11331, 9566, 36081, 28242, 13063, 39896, 9566, 1211, 3615, 43242, 7578, 3714, 31747, 3555], "avg_logprob": 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"probability": 0.9899088541666666}, {"start": 468.42, "end": 469.38, "word": " وعشان", "probability": 0.75347900390625}, {"start": 469.38, "end": 470.88, "word": " هيك", "probability": 0.957275390625}, {"start": 470.88, "end": 471.7, "word": " بنقدر", "probability": 0.86279296875}, {"start": 471.7, "end": 472.2, "word": " نتبع", "probability": 0.9676513671875}, {"start": 472.2, "end": 472.98, "word": " هالكلام", "probability": 0.8323974609375}, {"start": 472.98, "end": 473.84, "word": " جملة", "probability": 0.9554036458333334}, {"start": 473.84, "end": 474.4, "word": " تانية", "probability": 0.97412109375}, {"start": 474.4, "end": 476.18, "word": " monochlorination", "probability": 0.7393798828125}, {"start": 476.18, "end": 476.44, "word": " of", "probability": 0.9462890625}, {"start": 476.44, "end": 477.34, "word": " cyclopropane", "probability": 0.81298828125}, {"start": 477.34, "end": 477.8, "word": " معناه", "probability": 0.841796875}, {"start": 477.8, "end": 478.8, "word": " monochlorination", "probability": 0.8150634765625}, {"start": 478.8, "end": 478.98, "word": " إن", "probability": 0.21044921875}, {"start": 478.98, "end": 479.1, "word": " أنا", "probability": 0.77001953125}, {"start": 479.1, "end": 479.6, "word": " أبدل", "probability": 0.9073893229166666}, {"start": 479.6, "end": 480.34, "word": " هيدروجين", "probability": 0.839697265625}, {"start": 480.34, "end": 481.2, "word": " واحدة", "probability": 0.966796875}, {"start": 481.2, "end": 481.92, "word": " بكلور", "probability": 0.869140625}, {"start": 481.92, "end": 482.3, "word": " واحدة", "probability": 0.98046875}, {"start": 482.3, "end": 482.46, "word": " شو", "probability": 0.747802734375}, {"start": 482.46, "end": 482.9, "word": " بسمي", "probability": 0.9591471354166666}, {"start": 482.9, "end": 484.38, "word": " العملية؟", "probability": 0.8255615234375}, {"start": 484.38, "end": 485.68, "word": " mono", "probability": 0.51123046875}, {"start": 485.68, "end": 486.92, "word": " يعني", "probability": 0.8720703125}, {"start": 486.92, "end": 487.6, "word": " أحادي", "probability": 0.7562255859375}, {"start": 487.6, "end": 491.12, "word": " monochlorination", "probability": 0.675750732421875}, {"start": 491.12, "end": 491.82, "word": " إيش", "probability": 0.83837890625}, {"start": 491.82, "end": 492.02, "word": " يعني", "probability": 0.9736328125}, {"start": 492.02, "end": 493.3, "word": " chlorination؟", "probability": 0.8995768229166666}], "temperature": 1.0}, {"id": 22, "seek": 52090, "start": 494.82, "end": 520.9, "text": "تفاعل مع الكلور تفاعل الـ Cyclopropane مع الكلور إبدال بذرة واحدة Monochlorination of Cyclopropane produces only one product بيطلع فقط ناتج واحد، شو سميته أنا؟ Chlorocyclopropane واضح؟", "tokens": [2655, 5172, 995, 30241, 20449, 33251, 1211, 13063, 6055, 5172, 995, 30241, 2423, 39184, 49173, 404, 1513, 1929, 20449, 33251, 1211, 13063, 11933, 44510, 6027, 4724, 8848, 25720, 36764, 24401, 3660, 4713, 8997, 6746, 2486, 295, 49173, 404, 1513, 1929, 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"word": " same", "probability": 0.92333984375}, {"start": 1029.29, "end": 1029.87, "word": " bonding", "probability": 0.912109375}], "temperature": 1.0}, {"id": 42, "seek": 104633, "start": 1030.57, "end": 1046.33, "text": "but different arrangement in space شكلهم بالفراغ مختلف ان هدول الذرتين ع جهة واحدة و هدول الذرتين ع جهات متعاكسة بس اتنين ع واحد اتنين هذا النوع اللي احنا ايش سمنا stereo isomers", "tokens": [5955, 819, 17620, 294, 1901, 13412, 28820, 16095, 20666, 5172, 2288, 5718, 118, 3714, 46456, 46538, 16472, 8032, 3215, 12610, 32545, 2288, 2655, 9957, 6225, 10874, 3224, 3660, 36764, 24401, 3660, 4032, 8032, 3215, 12610, 32545, 43500, 9957, 6225, 10874, 3224, 9307, 44650, 3615, 995, 4117, 3794, 3660, 4724, 3794, 1975, 2655, 1863, 9957, 6225, 36764, 24401, 1975, 2655, 1863, 9957, 23758, 28239, 45367, 13672, 1829, 1975, 5016, 8315, 1975, 1829, 8592, 8608, 2304, 8315, 29029, 307, 298, 433], "avg_logprob": -0.22851562071591616, "compression_ratio": 1.6337209302325582, "no_speech_prob": 0.0, "words": [{"start": 1030.57, "end": 1030.93, "word": "but", "probability": 0.09857177734375}, {"start": 1030.93, "end": 1031.55, "word": " different", "probability": 0.83251953125}, {"start": 1031.55, "end": 1032.27, "word": " arrangement", "probability": 0.5283203125}, {"start": 1032.27, "end": 1032.67, "word": " in", "probability": 0.95556640625}, {"start": 1032.67, "end": 1033.49, "word": " space", "probability": 0.88818359375}, {"start": 1033.49, "end": 1034.47, "word": " شكلهم", "probability": 0.86572265625}, {"start": 1034.47, "end": 1035.01, "word": " بالفراغ", "probability": 0.80595703125}, {"start": 1035.01, "end": 1035.47, "word": " مختلف", "probability": 0.9557291666666666}, {"start": 1035.47, "end": 1035.61, "word": " ان", "probability": 0.369873046875}, {"start": 1035.61, "end": 1035.95, "word": " هدول", "probability": 0.7974446614583334}, {"start": 1035.95, "end": 1036.53, "word": " الذرتين", "probability": 0.68170166015625}, {"start": 1036.53, "end": 1036.65, "word": " ع", "probability": 0.77001953125}, {"start": 1036.65, "end": 1036.91, "word": " جهة", "probability": 0.8271484375}, {"start": 1036.91, "end": 1037.61, "word": " واحدة", "probability": 0.95068359375}, {"start": 1037.61, "end": 1037.89, "word": " و", "probability": 0.60888671875}, {"start": 1037.89, "end": 1038.11, "word": " هدول", "probability": 0.9449869791666666}, {"start": 1038.11, "end": 1038.59, "word": " الذرتين", "probability": 0.8297526041666666}, {"start": 1038.59, "end": 1038.71, "word": " ع", "probability": 0.962890625}, {"start": 1038.71, "end": 1039.01, "word": " جهات", "probability": 0.9156901041666666}, {"start": 1039.01, "end": 1039.91, "word": " متعاكسة", "probability": 0.9178059895833334}, {"start": 1039.91, "end": 1040.33, "word": " بس", "probability": 0.837158203125}, {"start": 1040.33, "end": 1040.69, "word": " اتنين", "probability": 0.75091552734375}, {"start": 1040.69, "end": 1040.83, "word": " ع", "probability": 0.7421875}, {"start": 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قلنا ال stereo isomers they have the same bonding يعني لما أجي أقول الكلور وين؟ ع واحد و التانية ع اتنين في التاني الكلور وين؟ ع واحد و التانية ع اتنين اذا they have the same bonding طب وين اختلفوا؟", "tokens": [3224, 15730, 28239, 45367, 13672, 1829, 8608, 2304, 8315, 3224, 29029, 307, 298, 433, 5296, 15042, 11331, 4117, 1829, 8315, 15844, 2423, 307, 14301, 1434, 12174, 1211, 8315, 2423, 29029, 307, 298, 433, 436, 362, 264, 912, 28824, 37495, 22653, 5296, 15042, 5551, 7435, 1829, 5551, 39648, 33251, 1211, 13063, 4032, 9957, 22807, 6225, 36764, 24401, 4032, 16712, 7649, 10632, 6225, 1975, 2655, 1863, 9957, 8978, 16712, 7649, 1829, 33251, 1211, 13063, 4032, 9957, 22807, 6225, 36764, 24401, 4032, 16712, 7649, 10632, 6225, 1975, 2655, 1863, 9957, 1975, 15730, 436, 362, 264, 912, 28824, 23032, 3555, 4032, 9957, 1975, 46456, 46538, 14407, 22807], "avg_logprob": -0.15256911157988584, "compression_ratio": 1.9748743718592965, "no_speech_prob": 0.0, "words": [{"start": 1047.01, "end": 1047.49, 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{"start": 1057.95, "end": 1058.69, "word": " الكلور", "probability": 0.7347005208333334}, {"start": 1058.69, "end": 1059.01, "word": " وين؟", "probability": 0.8857421875}, {"start": 1059.01, "end": 1059.09, "word": " ع", "probability": 0.75732421875}, {"start": 1059.09, "end": 1059.55, "word": " واحد", "probability": 0.9248046875}, {"start": 1059.55, "end": 1059.69, "word": " و", "probability": 0.5}, {"start": 1059.69, "end": 1060.27, "word": " التانية", "probability": 0.869140625}, {"start": 1060.27, "end": 1060.69, "word": " ع", "probability": 0.8359375}, {"start": 1060.69, "end": 1061.09, "word": " اتنين", "probability": 0.8831787109375}, {"start": 1061.09, "end": 1061.67, "word": " في", "probability": 0.52978515625}, {"start": 1061.67, "end": 1062.07, "word": " التاني", "probability": 0.919921875}, {"start": 1062.07, "end": 1062.49, "word": " الكلور", "probability": 0.94189453125}, {"start": 1062.49, "end": 1062.97, "word": " وين؟", "probability": 0.98388671875}, {"start": 1062.97, "end": 1063.13, "word": " ع", "probability": 0.96728515625}, {"start": 1063.13, "end": 1063.95, "word": " واحد", "probability": 0.978271484375}, {"start": 1063.95, "end": 1064.11, "word": " و", "probability": 0.9580078125}, {"start": 1064.11, "end": 1064.63, "word": " التانية", "probability": 0.9803059895833334}, {"start": 1064.63, "end": 1065.31, "word": " ع", "probability": 0.9091796875}, {"start": 1065.31, "end": 1065.63, "word": " اتنين", "probability": 0.9495849609375}, {"start": 1065.63, "end": 1065.87, "word": " اذا", "probability": 0.6214599609375}, {"start": 1065.87, "end": 1066.05, "word": " they", "probability": 0.93115234375}, {"start": 1066.05, "end": 1066.31, "word": " have", "probability": 0.97216796875}, {"start": 1066.31, "end": 1066.47, "word": " the", "probability": 0.93994140625}, {"start": 1066.47, "end": 1066.75, "word": " same", "probability": 0.919921875}, {"start": 1066.75, "end": 1067.29, "word": " bonding", "probability": 0.90771484375}, {"start": 1067.29, "end": 1067.79, "word": " طب", "probability": 0.902099609375}, {"start": 1067.79, "end": 1067.97, "word": " وين", "probability": 0.988525390625}, {"start": 1067.97, "end": 1068.81, "word": " اختلفوا؟", "probability": 0.97451171875}], "temperature": 1.0}, {"id": 44, "seek": 109821, "start": 1069.67, "end": 1098.21, "text": "بشكل برفرات اه هدول ع واحد و اتنين ع جهة واحدة على واحد و اتنين ع جهتين مختلفتين هذه بنسميها different arrangement in space اذا العلاقة بين هذا ال cis و ال trans they are stereo isomers لاحظوا لو قلتلكوا ما العلاقة بين هذا المركب و هذا المركب في ال isomers", "tokens": [3555, 8592, 28820, 4724, 2288, 5172, 2288, 9307, 1975, 3224, 8032, 3215, 12610, 6225, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 6225, 10874, 3224, 3660, 36764, 24401, 3660, 15844, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 6225, 10874, 3224, 2655, 9957, 3714, 46456, 46538, 2655, 9957, 29538, 44945, 38251, 1829, 11296, 819, 17620, 294, 1901, 1975, 15730, 18863, 15040, 28671, 49374, 23758, 2423, 37847, 4032, 2423, 1145, 436, 366, 29029, 307, 298, 433, 20193, 5016, 19913, 14407, 45164, 12174, 1211, 2655, 23275, 14407, 19446, 18863, 15040, 28671, 49374, 23758, 9673, 31747, 3555, 4032, 23758, 9673, 31747, 3555, 8978, 2423, 307, 298, 433], "avg_logprob": -0.1903822835787986, "compression_ratio": 1.8957345971563981, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1069.67, "end": 1070.31, "word": "بشكل", "probability": 0.7825520833333334}, {"start": 1070.31, "end": 1070.87, "word": " برفرات", "probability": 0.77451171875}, {"start": 1070.87, "end": 1071.21, "word": " اه", "probability": 0.5272216796875}, {"start": 1071.21, "end": 1071.51, "word": " هدول", "probability": 0.8868815104166666}, {"start": 1071.51, "end": 1071.63, "word": " ع", "probability": 0.6865234375}, {"start": 1071.63, "end": 1071.93, "word": " واحد", "probability": 0.7841796875}, {"start": 1071.93, "end": 1072.09, "word": " و", "probability": 0.95263671875}, {"start": 1072.09, "end": 1072.35, "word": " اتنين", "probability": 0.930419921875}, {"start": 1072.35, "end": 1072.55, "word": " ع", "probability": 0.82373046875}, {"start": 1072.55, "end": 1072.73, "word": " جهة", "probability": 0.88134765625}, {"start": 1072.73, "end": 1073.47, "word": " واحدة", "probability": 0.9435221354166666}, {"start": 1073.47, "end": 1074.09, "word": " على", "probability": 0.308837890625}, {"start": 1074.09, "end": 1074.39, "word": " واحد", "probability": 0.97900390625}, {"start": 1074.39, "end": 1074.53, "word": " و", "probability": 0.95361328125}, {"start": 1074.53, "end": 1074.73, "word": " اتنين", "probability": 0.9683837890625}, {"start": 1074.73, "end": 1074.89, "word": " ع", "probability": 0.8427734375}, {"start": 1074.89, "end": 1075.29, "word": " جهتين", "probability": 0.95166015625}, {"start": 1075.29, "end": 1076.23, "word": " مختلفتين", "probability": 0.97578125}, {"start": 1076.23, "end": 1076.61, "word": " هذه", "probability": 0.322021484375}, {"start": 1076.61, "end": 1077.25, "word": " بنسميها", "probability": 0.9002685546875}, {"start": 1077.25, "end": 1077.63, "word": " different", "probability": 0.7822265625}, {"start": 1077.63, "end": 1078.65, "word": " arrangement", "probability": 0.7919921875}, {"start": 1078.65, "end": 1079.09, "word": " in", "probability": 0.95068359375}, {"start": 1079.09, "end": 1080.29, "word": " space", "probability": 0.90625}, {"start": 1080.29, "end": 1080.99, "word": " اذا", "probability": 0.64306640625}, {"start": 1080.99, "end": 1081.91, "word": " العلاقة", "probability": 0.9619140625}, {"start": 1081.91, "end": 1082.17, "word": " بين", "probability": 0.9677734375}, {"start": 1082.17, "end": 1082.65, "word": " هذا", "probability": 0.87060546875}, {"start": 1082.65, "end": 1082.99, "word": " ال", "probability": 0.88037109375}, {"start": 1082.99, "end": 1083.33, "word": " cis", "probability": 0.383056640625}, {"start": 1083.33, "end": 1083.71, "word": " و", "probability": 0.62353515625}, {"start": 1083.71, "end": 1083.79, "word": " ال", "probability": 0.47314453125}, {"start": 1083.79, "end": 1084.49, "word": " trans", "probability": 0.67724609375}, {"start": 1084.49, "end": 1085.05, "word": " they", "probability": 0.78662109375}, {"start": 1085.05, "end": 1085.69, "word": " are", "probability": 0.966796875}, {"start": 1085.69, "end": 1087.85, "word": " stereo", "probability": 0.468017578125}, {"start": 1087.85, "end": 1088.89, "word": " isomers", "probability": 0.9158528645833334}, {"start": 1088.89, "end": 1092.07, "word": " لاحظوا", "probability": 0.81121826171875}, {"start": 1092.07, "end": 1092.45, "word": " لو", "probability": 0.9384765625}, {"start": 1092.45, "end": 1092.95, "word": " قلتلكوا", "probability": 0.93720703125}, {"start": 1092.95, "end": 1093.03, "word": " ما", "probability": 0.79345703125}, {"start": 1093.03, "end": 1093.65, "word": " العلاقة", "probability": 0.9588216145833334}, {"start": 1093.65, "end": 1093.95, "word": " بين", "probability": 0.84521484375}, {"start": 1093.95, "end": 1094.39, "word": " هذا", "probability": 0.95751953125}, {"start": 1094.39, "end": 1095.09, "word": " المركب", "probability": 0.9069010416666666}, {"start": 1095.09, "end": 1095.19, "word": " و", "probability": 0.88720703125}, {"start": 1095.19, "end": 1095.47, "word": " هذا", "probability": 0.95166015625}, {"start": 1095.47, "end": 1096.93, "word": " المركب", "probability": 0.9860026041666666}, {"start": 1096.93, "end": 1097.35, "word": " في", "probability": 0.89013671875}, {"start": 1097.35, "end": 1097.47, "word": " ال", "probability": 0.884765625}, {"start": 1097.47, "end": 1098.21, "word": " isomers", "probability": 0.9640299479166666}], "temperature": 1.0}, {"id": 45, "seek": 110397, "start": 1099.61, "end": 1103.97, "text": "هنا they have different bonding و different names", "tokens": [3224, 8315, 436, 362, 819, 28824, 4032, 819, 5288], "avg_logprob": -0.35117186307907106, "compression_ratio": 1.0192307692307692, "no_speech_prob": 0.0, "words": [{"start": 1099.61, "end": 1100.09, "word": "هنا", "probability": 0.737548828125}, {"start": 1100.09, "end": 1100.35, "word": " they", "probability": 0.306884765625}, {"start": 1100.35, "end": 1100.65, "word": " have", "probability": 0.96044921875}, {"start": 1100.65, "end": 1101.19, "word": " different", "probability": 0.95068359375}, {"start": 1101.19, "end": 1101.73, "word": " bonding", "probability": 0.7197265625}, {"start": 1101.73, "end": 1102.87, "word": " و", "probability": 0.8505859375}, {"start": 1102.87, "end": 1103.27, "word": " different", "probability": 0.84814453125}, {"start": 1103.27, "end": 1103.97, "word": " names", "probability": 0.89599609375}], "temperature": 1.0}, {"id": 46, "seek": 113085, "start": 1105.94, "end": 1130.86, "text": "ذرتين الكلور على واحد و واحد وعشان هيك سميته one one dichlorocyclopropane هنا ذرتين الكلور على واحد و اتنين هذا ال same bonding ولا different bonding different bonding ال different bonding أدى إلى different names أنا لما حددت مواقع الكلور قلت one one هنا قلت one two إذا هذا المركب و هذا المركب", "tokens": [8848, 43500, 9957, 33251, 1211, 13063, 15844, 36764, 24401, 4032, 36764, 24401, 4032, 3615, 8592, 7649, 39896, 4117, 8608, 2304, 36081, 3224, 472, 472, 10390, 6746, 31078, 3474, 404, 1513, 1929, 34105, 29910, 43500, 9957, 33251, 1211, 13063, 15844, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 23758, 2423, 912, 28824, 49429, 819, 28824, 819, 28824, 2423, 819, 28824, 5551, 3215, 7578, 30731, 819, 5288, 41850, 5296, 15042, 11331, 3215, 3215, 2655, 3714, 14407, 4587, 3615, 33251, 1211, 13063, 12174, 1211, 2655, 472, 472, 34105, 12174, 1211, 2655, 472, 732, 11933, 15730, 23758, 9673, 31747, 3555, 4032, 23758, 9673, 31747, 3555], "avg_logprob": -0.23746906530739056, "compression_ratio": 2.0531400966183573, "no_speech_prob": 0.0, "words": [{"start": 1105.94, "end": 1106.58, "word": "ذرتين", "probability": 0.6253255208333334}, {"start": 1106.58, "end": 1107.02, "word": " الكلور", "probability": 0.7620442708333334}, {"start": 1107.02, "end": 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1129.8, "word": " و", "probability": 0.73291015625}, {"start": 1129.8, "end": 1130.1, "word": " هذا", "probability": 0.93798828125}, {"start": 1130.1, "end": 1130.86, "word": " المركب", "probability": 0.9856770833333334}], "temperature": 1.0}, {"id": 47, "seek": 115911, "start": 1133.14, "end": 1159.12, "text": "صحيح مكونين من نفس الذرات لكن فيهم different bonding و different names فالعلاقة بين ال 11-dichlorocyclopropane و ال 12-dichlorocyclopropane they are structural isomers و كذلك العلاقة بين هذا و هذا لكن لو قلت العلاقة بين ال cis و ال trans they are stereo isomers", "tokens": [9381, 5016, 1829, 5016, 3714, 30544, 9957, 9154, 8717, 36178, 32545, 2288, 9307, 44381, 8978, 16095, 819, 28824, 4032, 819, 5288, 6156, 6027, 3615, 15040, 28671, 49374, 2423, 2975, 12, 67, 480, 6746, 31078, 3474, 404, 1513, 1929, 4032, 2423, 2272, 12, 67, 480, 6746, 31078, 3474, 404, 1513, 1929, 436, 366, 15067, 307, 298, 433, 4032, 9122, 8848, 23275, 18863, 15040, 28671, 49374, 23758, 4032, 23758, 44381, 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"-dichlorocyclopropane", "probability": 0.9656575520833334}, {"start": 1146.42, "end": 1146.64, "word": " they", "probability": 0.28173828125}, {"start": 1146.64, "end": 1147.16, "word": " are", "probability": 0.96337890625}, {"start": 1147.16, "end": 1148.5, "word": " structural", "probability": 0.78466796875}, {"start": 1148.5, "end": 1149.52, "word": " isomers", "probability": 0.9651692708333334}, {"start": 1149.52, "end": 1149.92, "word": " و", "probability": 0.92626953125}, {"start": 1149.92, "end": 1150.38, "word": " كذلك", "probability": 0.9562174479166666}, {"start": 1150.38, "end": 1150.92, "word": " العلاقة", "probability": 0.9830729166666666}, {"start": 1150.92, "end": 1151.18, "word": " بين", "probability": 0.97021484375}, {"start": 1151.18, "end": 1151.48, "word": " هذا", "probability": 0.794921875}, {"start": 1151.48, "end": 1151.64, "word": " و", "probability": 0.7451171875}, {"start": 1151.64, "end": 1151.9, "word": " هذا", "probability": 0.94384765625}, {"start": 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"word": " stereo", "probability": 0.71875}, {"start": 1158.0, "end": 1159.12, "word": " isomers", "probability": 0.95947265625}], "temperature": 1.0}, {"id": 48, "seek": 117360, "start": 1161.81, "end": 1173.61, "text": "Same bonding but different arrangement in space هي تعريف الـ Stereoisomers نفس الإرتباط ولكن يختلف فيه الشكل بالفراغ", "tokens": [50, 529, 28824, 457, 819, 17620, 294, 1901, 39896, 37279, 16572, 5172, 2423, 39184, 745, 323, 7376, 298, 433, 8717, 36178, 33688, 43500, 3555, 41193, 35525, 19452, 7251, 46456, 46538, 8978, 3224, 25124, 28820, 20666, 5172, 2288, 5718, 118], "avg_logprob": -0.3025390639901161, "compression_ratio": 1.1666666666666667, "no_speech_prob": 0.0, "words": [{"start": 1161.81, "end": 1162.49, "word": "Same", "probability": 0.57391357421875}, {"start": 1162.49, "end": 1163.37, "word": " bonding", "probability": 0.845703125}, {"start": 1163.37, "end": 1164.01, "word": " but", "probability": 0.481201171875}, {"start": 1164.01, "end": 1164.71, "word": " different", "probability": 0.80908203125}, {"start": 1164.71, "end": 1165.43, "word": " arrangement", "probability": 0.6201171875}, {"start": 1165.43, "end": 1165.69, "word": " in", "probability": 0.91845703125}, {"start": 1165.69, "end": 1166.07, "word": " space", "probability": 0.86962890625}, {"start": 1166.07, "end": 1166.21, "word": " هي", "probability": 0.1185302734375}, {"start": 1166.21, "end": 1166.63, "word": " تعريف", "probability": 0.9830729166666666}, {"start": 1166.63, "end": 1166.83, "word": " الـ", "probability": 0.5621337890625}, {"start": 1166.83, "end": 1167.79, "word": " Stereoisomers", "probability": 0.792431640625}, {"start": 1167.79, "end": 1168.81, "word": " نفس", "probability": 0.94873046875}, {"start": 1168.81, "end": 1169.59, "word": " الإرتباط", "probability": 0.89111328125}, {"start": 1169.59, "end": 1170.01, "word": " ولكن", "probability": 0.88134765625}, {"start": 1170.01, "end": 1170.55, "word": " يختلف", "probability": 0.9855143229166666}, {"start": 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1184.59, "end": 1185.71, "word": " Diastereomers", "probability": 0.72158203125}, {"start": 1185.71, "end": 1186.67, "word": " هنتعلمه", "probability": 0.8330078125}, {"start": 1186.67, "end": 1187.05, "word": " و", "probability": 0.85107421875}, {"start": 1187.05, "end": 1187.27, "word": " نوع", "probability": 0.9150390625}, {"start": 1187.27, "end": 1187.53, "word": " منهم", "probability": 0.990234375}, {"start": 1187.53, "end": 1188.15, "word": " بنسميه", "probability": 0.938720703125}, {"start": 1188.15, "end": 1188.83, "word": " Enantiomers", "probability": 0.79083251953125}, {"start": 1188.83, "end": 1189.67, "word": " الآن", "probability": 0.593994140625}, {"start": 1189.67, "end": 1190.59, "word": " هدولة", "probability": 0.7301025390625}, {"start": 1190.59, "end": 1191.71, "word": " المركبين", "probability": 0.916015625}, {"start": 1191.71, "end": 1192.93, "word": " مثال", "probability": 0.9912109375}, {"start": 1192.93, "end": 1193.77, "word": " لأحد", "probability": 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9307, 7435, 40294, 29538, 6225, 4117, 3794, 11296, 37037, 24192, 2423, 3224, 25708, 2288, 29245, 9957, 4724, 9307, 7435, 40294, 29538, 6225, 4117, 3794, 11296, 37495, 22653, 5296, 24401, 29538, 28239, 47432, 3660], "avg_logprob": -0.22639973709980646, "compression_ratio": 1.910179640718563, "no_speech_prob": 0.0, "words": [{"start": 1297.28, "end": 1297.86, "word": "الان", "probability": 0.866455078125}, {"start": 1297.86, "end": 1298.32, "word": " لو", "probability": 0.85888671875}, {"start": 1298.32, "end": 1298.72, "word": " اتيت", "probability": 0.69873046875}, {"start": 1298.72, "end": 1298.86, "word": " يا", "probability": 0.6943359375}, {"start": 1298.86, "end": 1299.22, "word": " تورا", "probability": 0.8128255208333334}, {"start": 1299.22, "end": 1300.48, "word": " اتسألت", "probability": 0.79034423828125}, {"start": 1300.48, "end": 1300.86, "word": " هل", "probability": 0.894287109375}, {"start": 1300.86, "end": 1301.4, "word": " هدولة", "probability": 0.6912841796875}, {"start": 1301.4, "end": 1301.56, "word": " من", "probability": 0.97705078125}, {"start": 1301.56, "end": 1302.44, "word": " الاساس", "probability": 0.8211263020833334}, {"start": 1302.44, "end": 1303.26, "word": " صورة", "probability": 0.9900716145833334}, {"start": 1303.26, "end": 1303.8, "word": " مرآه", "probability": 0.77919921875}, {"start": 1303.8, "end": 1303.94, "word": " ولا", "probability": 0.82421875}, {"start": 1303.94, "end": 1304.18, "word": " مش", "probability": 0.9248046875}, {"start": 1304.18, "end": 1304.58, "word": " صورة", "probability": 0.9806315104166666}, {"start": 1304.58, "end": 1305.24, "word": " مرآه؟", "probability": 0.8777262369791666}, {"start": 1305.24, "end": 1306.6, "word": " لاحظوا", "probability": 0.8853759765625}, {"start": 1306.6, "end": 1307.14, "word": " يمكن", "probability": 0.88623046875}, {"start": 1307.14, "end": 1307.36, "word": " هنا", "probability": 0.81494140625}, {"start": 1307.36, "end": 1307.78, "word": " تلاقي", "probability": 0.84521484375}, {"start": 1307.78, "end": 1308.26, "word": " كلور", "probability": 0.7285970052083334}, {"start": 1308.26, "end": 1308.78, "word": " متجه", "probability": 0.92626953125}, {"start": 1308.78, "end": 1309.24, "word": " باتجاه", "probability": 0.8282470703125}, {"start": 1309.24, "end": 1309.48, "word": " هذه", "probability": 0.51904296875}, {"start": 1309.48, "end": 1309.9, "word": " عكسها", "probability": 0.9508056640625}, {"start": 1309.9, "end": 1310.12, "word": " وهذه", "probability": 0.328857421875}, {"start": 1310.12, "end": 1310.6, "word": " الهيدروجين", "probability": 0.8495279947916666}, {"start": 1310.6, "end": 1310.96, "word": " باتجاه", "probability": 0.822509765625}, {"start": 1310.96, "end": 1311.08, "word": " هذه", "probability": 0.8876953125}, {"start": 1311.08, "end": 1311.4, "word": " عكسها", "probability": 0.989501953125}, {"start": 1311.4, "end": 1311.8, "word": " يعني", "probability": 0.825927734375}, {"start": 1311.8, "end": 1312.18, "word": " لحد", "probability": 0.906982421875}, {"start": 1312.18, "end": 1312.4, "word": " هذه", "probability": 0.67626953125}, {"start": 1312.4, "end": 1313.06, "word": " النقطة", "probability": 0.982421875}], "temperature": 1.0}, {"id": 55, "seek": 132822, "start": 1314.14, "end": 1328.22, "text": "معاكسات لكن هنا في chlorine إقبالها hydrogen تحت هنا في chlorine إقبالها hydrogen هل هدولة بيصيروا صورة مرآة إذا بطلوا صورة مرآة", "tokens": [2304, 3615, 995, 4117, 3794, 9307, 44381, 34105, 8978, 39888, 11933, 4587, 3555, 6027, 11296, 12697, 6055, 33753, 34105, 8978, 39888, 11933, 4587, 3555, 6027, 11296, 12697, 8032, 1211, 8032, 3215, 12610, 3660, 4724, 1829, 9381, 13546, 14407, 20328, 13063, 3660, 3714, 2288, 148, 95, 3660, 11933, 15730, 4724, 9566, 1211, 14407, 20328, 13063, 3660, 3714, 2288, 148, 95, 3660], "avg_logprob": -0.15112704429470125, "compression_ratio": 1.5984251968503937, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1314.14, "end": 1315.14, "word": "معاكسات", "probability": 0.9659016927083334}, {"start": 1315.14, "end": 1315.6, "word": " لكن", "probability": 0.4873046875}, {"start": 1315.6, "end": 1316.12, "word": " هنا", "probability": 0.98486328125}, {"start": 1316.12, "end": 1316.46, "word": " في", "probability": 0.9423828125}, {"start": 1316.46, "end": 1317.0, "word": " chlorine", "probability": 0.279052734375}, {"start": 1317.0, "end": 1318.46, "word": " إقبالها", "probability": 0.855712890625}, {"start": 1318.46, "end": 1319.76, "word": " hydrogen", "probability": 0.421142578125}, {"start": 1319.76, "end": 1320.76, "word": " تحت", "probability": 0.839111328125}, {"start": 1320.76, "end": 1320.98, "word": " هنا", "probability": 0.94970703125}, {"start": 1320.98, "end": 1321.28, "word": " في", "probability": 0.91552734375}, {"start": 1321.28, "end": 1322.16, "word": " chlorine", "probability": 0.67138671875}, {"start": 1322.16, "end": 1322.68, "word": " إقبالها", "probability": 0.963671875}, {"start": 1322.68, "end": 1322.98, "word": " hydrogen", "probability": 0.60546875}, {"start": 1322.98, "end": 1323.42, "word": " هل", "probability": 0.926025390625}, {"start": 1323.42, "end": 1323.8, "word": " هدولة", "probability": 0.8343505859375}, {"start": 1323.8, "end": 1324.56, "word": " بيصيروا", "probability": 0.9607421875}, {"start": 1324.56, "end": 1325.14, "word": " صورة", "probability": 0.9763997395833334}, {"start": 1325.14, "end": 1326.36, "word": " مرآة", "probability": 0.82841796875}, {"start": 1326.36, "end": 1326.64, "word": " إذا", "probability": 0.730224609375}, {"start": 1326.64, "end": 1327.18, "word": " بطلوا", "probability": 0.9476318359375}, {"start": 1327.18, "end": 1327.58, "word": " صورة", "probability": 0.9938151041666666}, {"start": 1327.58, "end": 1328.22, "word": " مرآة", "probability": 0.9859375}], "temperature": 1.0}, {"id": 56, "seek": 135187, "start": 1329.11, "end": 1351.87, "text": "شرط صورة المرآة أن كل جزء من الجزيئات هيكون بعكس الجثة الآخر هدولة فيهم أشياء أساسا مش اقبال .. مش .. يعني هذه لا فوق، كلور اقبالها هيدروجين، إذا هدولة الشكلين الcess والترانس لما أنا بدي أحكي عنهم بقول they are non mirror", "tokens": [46309, 9566, 20328, 13063, 3660, 9673, 2288, 148, 95, 3660, 14739, 28242, 10874, 11622, 38207, 9154, 25724, 11622, 1829, 19986, 9307, 39896, 30544, 45030, 4117, 3794, 25724, 12984, 3660, 6024, 95, 34740, 8032, 3215, 12610, 3660, 8978, 16095, 5551, 8592, 1829, 16606, 5551, 3794, 32277, 995, 37893, 1975, 4587, 3555, 6027, 4386, 37893, 4386, 37495, 22653, 29538, 20193, 6156, 30543, 12399, 9122, 1211, 13063, 1975, 4587, 3555, 6027, 11296, 8032, 25708, 2288, 29245, 9957, 12399, 11933, 15730, 8032, 3215, 12610, 3660, 25124, 28820, 9957, 2423, 780, 16070, 2655, 2288, 7649, 3794, 5296, 15042, 41850, 4724, 16254, 5551, 5016, 4117, 1829, 18871, 16095, 4724, 39648, 436, 366, 2107, 8013], "avg_logprob": -0.3047591633752945, "compression_ratio": 1.6363636363636365, "no_speech_prob": 0.0, "words": [{"start": 1329.11, "end": 1329.61, "word": "شرط", "probability": 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"probability": 0.5481363932291666}, {"start": 1339.91, "end": 1340.45, "word": " كلور", "probability": 0.677734375}, {"start": 1340.45, "end": 1341.45, "word": " اقبالها", "probability": 0.863330078125}, {"start": 1341.45, "end": 1342.99, "word": " هيدروجين،", "probability": 0.7574869791666666}, {"start": 1342.99, "end": 1343.29, "word": " إذا", "probability": 0.70263671875}, {"start": 1343.29, "end": 1344.13, "word": " هدولة", "probability": 0.8848876953125}, {"start": 1344.13, "end": 1344.97, "word": " الشكلين", "probability": 0.86181640625}, {"start": 1344.97, "end": 1345.65, "word": " الcess", "probability": 0.436767578125}, {"start": 1345.65, "end": 1346.61, "word": " والترانس", "probability": 0.803125}, {"start": 1346.61, "end": 1347.05, "word": " لما", "probability": 0.890625}, {"start": 1347.05, "end": 1347.33, "word": " أنا", "probability": 0.69091796875}, {"start": 1347.33, "end": 1347.77, "word": " بدي", "probability": 0.758544921875}, {"start": 1347.77, "end": 1348.19, "word": " أحكي", "probability": 0.963623046875}, {"start": 1348.19, "end": 1348.49, "word": " عنهم", "probability": 0.990478515625}, {"start": 1348.49, "end": 1348.95, "word": " بقول", "probability": 0.957275390625}, {"start": 1348.95, "end": 1349.41, "word": " they", "probability": 0.76416015625}, {"start": 1349.41, "end": 1350.03, "word": " are", "probability": 0.9609375}, {"start": 1350.03, "end": 1350.73, "word": " non", "probability": 0.80419921875}, {"start": 1350.73, "end": 1351.87, "word": " mirror", "probability": 0.481201171875}], "temperature": 1.0}, {"id": 57, "seek": 137572, "start": 1353.72, "end": 1375.72, "text": "images، إيش يعني non-mirror images؟ مش صورة بعض في المرأة، الأشياء اللي بتكون مش صورة بعض في المرأة هي اللي تعرف ان اسمها diastereomers، وهذا مثال عليها، ف ال cicatrans، isomers، they are diastereomers", "tokens": [332, 1660, 12399, 11933, 1829, 8592, 37495, 22653, 2107, 12, 19834, 2874, 5267, 22807, 37893, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 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{"start": 1362.12, "end": 1362.58, "word": " المرأة", "probability": 0.95361328125}, {"start": 1362.58, "end": 1362.96, "word": " هي", "probability": 0.6376953125}, {"start": 1362.96, "end": 1363.18, "word": " اللي", "probability": 0.977783203125}, {"start": 1363.18, "end": 1363.88, "word": " تعرف", "probability": 0.968017578125}, {"start": 1363.88, "end": 1365.36, "word": " ان", "probability": 0.33935546875}, {"start": 1365.36, "end": 1366.36, "word": " اسمها", "probability": 0.9641927083333334}, {"start": 1366.36, "end": 1367.6, "word": " diastereomers،", "probability": 0.61358642578125}, {"start": 1367.6, "end": 1367.96, "word": " وهذا", "probability": 0.885009765625}, {"start": 1367.96, "end": 1368.46, "word": " مثال", "probability": 0.973876953125}, {"start": 1368.46, "end": 1369.54, "word": " عليها،", "probability": 0.7962239583333334}, {"start": 1369.54, "end": 1369.7, "word": " ف", "probability": 0.953125}, {"start": 1369.7, "end": 1369.86, "word": " ال", "probability": 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1447.16, "word": " ده", "probability": 0.5748291015625}, {"start": 1447.16, "end": 1447.3, "word": " يا", "probability": 0.42724609375}, {"start": 1447.3, "end": 1447.94, "word": " stereomers", "probability": 0.8937174479166666}], "temperature": 1.0}, {"id": 61, "seek": 146803, "start": 1449.09, "end": 1468.03, "text": "تطلعوا معي مرة تانية نرسم أحد هدولة أو نعمل model لأحد هدولة المركبات اللي هم ال sis, trans, isomers واضح؟ هذا أي مركب فيهم؟ ال sis والتاني لترانس متى توجد عندنا ظاهرة ال sis و الترانس؟", "tokens": [2655, 9566, 1211, 3615, 14407, 20449, 1829, 3714, 25720, 6055, 7649, 10632, 8717, 2288, 38251, 5551, 24401, 8032, 3215, 12610, 3660, 34051, 8717, 25957, 1211, 2316, 5296, 10721, 24401, 8032, 3215, 12610, 3660, 9673, 31747, 3555, 9307, 13672, 1829, 8032, 2304, 2423, 26288, 11, 1145, 11, 307, 298, 433, 4032, 46958, 5016, 22807, 23758, 36632, 3714, 31747, 3555, 8978, 16095, 22807, 2423, 26288, 16070, 2655, 7649, 1829, 5296, 2655, 2288, 7649, 3794, 44650, 7578, 33427, 7435, 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trans هاي بال cycle اللي اتعرفنا عليه طيب حوالين ال double bond", "tokens": [6027, 6027, 4117, 9957, 11622, 13672, 1829, 8978, 11296, 12602, 14407, 3555, 9566, 6024, 110, 29245, 9957, 23758, 9673, 41361, 13672, 1829, 39894, 8592, 38688, 3224, 8978, 3224, 9122, 19528, 3660, 26288, 4032, 1145, 8978, 2423, 17796, 50113, 1211, 9673, 12984, 6027, 13672, 1829, 1975, 5016, 8315, 12602, 38251, 8315, 30767, 1829, 19446, 12174, 12610, 8315, 23758, 50113, 15040, 39627, 15730, 25124, 28820, 26288, 4032, 39627, 15730, 25124, 28820, 2423, 1145, 8032, 47302, 20666, 6586, 13672, 1829, 1975, 2655, 3615, 28480, 8315, 47356, 23032, 1829, 3555, 11331, 2407, 6027, 9957, 2423, 3834, 6086], "avg_logprob": -0.18650265862333013, "compression_ratio": 1.854368932038835, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1520.1, "end": 1520.86, "word": "الالكينز", "probability": 0.70673828125}, {"start": 1520.86, "end": 1520.96, "word": " اللي", "probability": 0.791259765625}, {"start": 1520.96, "end": 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بيتم لأنه انا لو جربت في cycle الكل بدي ألوف هذا هيك أخلي هدول يصيروا عكس بعض يعني ال 6 يصير ال trans لاحظوا لأنه مربوط بالحلقة الدوران حول الحلقة ممنوع الدوران حول الحلقة ممنوع الان طيب لو اتخيلتوا ان انا في عنده", "tokens": [6027, 6027, 4117, 47302, 11622, 2423, 6027, 4117, 9957, 11622, 6225, 5172, 14407, 32239, 8592, 23758, 2423, 28820, 10943, 4724, 36081, 2304, 5296, 33456, 3224, 1975, 8315, 45164, 10874, 25513, 2655, 8978, 6586, 2423, 28820, 4724, 16254, 5551, 1211, 38688, 23758, 39896, 4117, 5551, 9778, 20292, 8032, 3215, 12610, 7251, 9381, 13546, 14407, 6225, 4117, 3794, 45030, 11242, 37495, 22653, 2423, 1386, 7251, 9381, 13546, 2423, 1145, 20193, 5016, 19913, 14407, 5296, 33456, 3224, 3714, 25513, 2407, 9566, 20666, 5016, 1211, 28671, 32748, 13063, 7649, 11331, 12610, 21542, 1211, 28671, 3714, 27842, 45367, 32748, 13063, 7649, 11331, 12610, 21542, 1211, 28671, 3714, 27842, 45367, 2423, 7649, 23032, 1829, 3555, 45164, 1975, 2655, 9778, 26895, 2655, 14407, 16472, 1975, 8315, 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{"start": 1703.63, "end": 1704.15, "word": " الفكرة", "probability": 0.9207356770833334}, {"start": 1704.15, "end": 1704.95, "word": " زي", "probability": 0.64501953125}, {"start": 1704.95, "end": 1705.47, "word": " لما", "probability": 0.9091796875}, {"start": 1705.47, "end": 1706.17, "word": " الواحدة", "probability": 0.9349365234375}, {"start": 1706.17, "end": 1706.55, "word": " بيجيها", "probability": 0.98681640625}, {"start": 1706.55, "end": 1707.19, "word": " مولود", "probability": 0.9908854166666666}, {"start": 1707.19, "end": 1708.05, "word": " مافيش", "probability": 0.7647298177083334}, {"start": 1708.05, "end": 1708.35, "word": " يكون", "probability": 0.912353515625}, {"start": 1708.35, "end": 1709.05, "word": " عشوائي", "probability": 0.9857421875}, {"start": 1709.05, "end": 1709.37, "word": " يا", "probability": 0.75244140625}, {"start": 1709.37, "end": 1709.85, "word": " ولد", "probability": 0.7305908203125}, {"start": 1709.85, "end": 1710.77, "word": " يا", "probability": 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بظائف", "probability": 0.8232421875}, {"start": 1728.57, "end": 1729.15, "word": " معينة", "probability": 0.9944661458333334}, {"start": 1729.15, "end": 1729.27, "word": " في", "probability": 0.8876953125}, {"start": 1729.27, "end": 1729.79, "word": " الحياة", "probability": 0.9934895833333334}, {"start": 1729.79, "end": 1730.07, "word": " و", "probability": 0.5634765625}, {"start": 1730.07, "end": 1730.55, "word": " هتلاقوا", "probability": 0.96689453125}, {"start": 1730.55, "end": 1731.15, "word": " مركب", "probability": 0.8126627604166666}, {"start": 1731.15, "end": 1731.79, "word": " تاني", "probability": 0.9762369791666666}, {"start": 1731.79, "end": 1732.79, "word": " مختلف", "probability": 0.978515625}, {"start": 1732.79, "end": 1733.21, "word": " ال", "probability": 0.548828125}, {"start": 1733.21, "end": 1733.89, "word": " Trans", "probability": 0.46435546875}, {"start": 1733.89, "end": 1734.31, "word": " و", "probability": 0.85595703125}, {"start": 1734.31, "end": 1734.51, "word": " زي", "probability": 0.8916015625}, {"start": 1734.51, "end": 1734.59, "word": " ما", "probability": 0.98779296875}, {"start": 1734.59, "end": 1734.83, "word": " قلنا", "probability": 0.8816731770833334}, {"start": 1734.83, "end": 1735.31, "word": " العلاقة", "probability": 0.9484049479166666}, {"start": 1735.31, "end": 1735.55, "word": " بين", "probability": 0.98388671875}, {"start": 1735.55, "end": 1736.21, "word": " هدولة", "probability": 0.78118896484375}, {"start": 1736.21, "end": 1736.61, "word": " VR", "probability": 0.64453125}], "temperature": 1.0}, {"id": 73, "seek": 175780, "start": 1737.72, "end": 1757.8, "text": "Diastereomers they are non mirror images كلام سليم ولا لأ؟ مش صورة بعض في المرأة في الخصائص الفيزيائية أكيد و الكيميائية بيختلفوا في كل شيء صاروا مركبين", "tokens": [35, 72, 525, 323, 298, 433, 436, 366, 2107, 8013, 5267, 28242, 10943, 8608, 20292, 2304, 49429, 5296, 10721, 22807, 37893, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 10721, 3660, 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"end": 2203.42, "word": " يكونوا", "probability": 0.9903971354166666}, {"start": 2203.42, "end": 2203.84, "word": " أبعد", "probability": 0.8860677083333334}, {"start": 2203.84, "end": 2204.3, "word": " كمان", "probability": 0.9765625}, {"start": 2204.3, "end": 2205.56, "word": " واضح؟", "probability": 0.7987060546875}, {"start": 2205.56, "end": 2205.98, "word": " بتظهر", "probability": 0.74658203125}, {"start": 2205.98, "end": 2206.38, "word": " نقطة", "probability": 0.96435546875}, {"start": 2206.38, "end": 2207.0, "word": " الحقيقة", "probability": 0.9669596354166666}, {"start": 2207.0, "end": 2207.98, "word": " في", "probability": 0.9658203125}, {"start": 2207.98, "end": 2208.42, "word": " موضوع", "probability": 0.9940185546875}, {"start": 2208.42, "end": 2208.62, "word": " ال", "probability": 0.89306640625}, {"start": 2208.62, "end": 2210.86, "word": " cyclobutane", "probability": 0.6790313720703125}, {"start": 2210.86, "end": 2211.36, "word": " ان", "probability": 0.576171875}, {"start": 2211.36, "end": 2211.64, "word": " هل", "probability": 0.7186279296875}, {"start": 2211.64, "end": 2211.82, "word": " يا", "probability": 0.62451171875}, {"start": 2211.82, "end": 2212.4, "word": " ترى", "probability": 0.8821614583333334}, {"start": 2212.4, "end": 2212.66, "word": " ال", "probability": 0.78955078125}, {"start": 2212.66, "end": 2214.02, "word": " cyclobutane", "probability": 0.8883056640625}, {"start": 2214.02, "end": 2214.98, "word": " بلانر", "probability": 0.61956787109375}], "temperature": 1.0}, {"id": 94, "seek": 223258, "start": 2215.96, "end": 2232.58, "text": "بهذا الشكل؟ الجواب لو كنا بنطلع على الزوايا تبعته بشكل دقيق هو مش planner هو شوية بيقول عنه puckered يعني مثني شوية لجوا الان بيشبه ايش بهذا الشكل الفراشة ال butterfly", "tokens": [3555, 3224, 15730, 25124, 28820, 22807, 25724, 14407, 3555, 45164, 9122, 8315, 44945, 9566, 1211, 3615, 15844, 6024, 110, 14407, 25528, 6055, 3555, 34268, 3224, 4724, 8592, 28820, 11778, 38436, 4587, 31439, 37893, 31268, 31439, 13412, 2407, 10632, 4724, 1829, 39648, 18871, 3224, 47181, 323, 67, 37495, 22653, 50113, 22653, 13412, 2407, 10632, 5296, 7435, 14407, 2423, 7649, 4724, 1829, 8592, 3555, 3224, 1975, 1829, 8592, 39627, 15730, 25124, 28820, 27188, 2288, 33599, 3660, 2423, 22140], "avg_logprob": -0.2102272796940494, "compression_ratio": 1.5730337078651686, "no_speech_prob": 1.8477439880371094e-06, "words": [{"start": 2215.96, "end": 2216.44, "word": "بهذا", "probability": 0.8404947916666666}, {"start": 2216.44, "end": 2217.14, "word": " الشكل؟", "probability": 0.8600260416666666}, {"start": 2217.14, "end": 2218.64, "word": " الجواب", "probability": 0.8831380208333334}, {"start": 2218.64, "end": 2218.96, "word": " لو", "probability": 0.87646484375}, {"start": 2218.96, "end": 2219.24, "word": " كنا", "probability": 0.9912109375}, {"start": 2219.24, "end": 2219.78, "word": " بنطلع", "probability": 0.8458251953125}, {"start": 2219.78, "end": 2219.96, "word": " على", "probability": 0.857421875}, {"start": 2219.96, "end": 2220.44, "word": " الزوايا", "probability": 0.916259765625}, {"start": 2220.44, "end": 2220.92, "word": " تبعته", "probability": 0.83734130859375}, {"start": 2220.92, "end": 2221.34, "word": " بشكل", "probability": 0.9866536458333334}, {"start": 2221.34, "end": 2221.88, "word": " دقيق", "probability": 0.9944661458333334}, {"start": 2221.88, "end": 2222.34, "word": " هو", "probability": 0.9150390625}, {"start": 2222.34, "end": 2222.74, "word": " مش", "probability": 0.98681640625}, {"start": 2222.74, "end": 2223.22, "word": " planner", "probability": 0.78173828125}, {"start": 2223.22, "end": 2223.78, "word": " هو", "probability": 0.89697265625}, {"start": 2223.78, "end": 2224.24, "word": " شوية", "probability": 0.8943684895833334}, {"start": 2224.24, "end": 2224.58, "word": " بيقول", "probability": 0.652587890625}, {"start": 2224.58, "end": 2224.94, "word": " عنه", "probability": 0.96240234375}, {"start": 2224.94, "end": 2225.46, "word": " puckered", 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"word": " butterfly", "probability": 0.9296875}], "temperature": 1.0}, {"id": 95, "seek": 226184, "start": 2233.64, "end": 2261.84, "text": "واضح؟ فالـ cyclobutane is not a planar molecule مش موجود بهذا الشكل في مستوى واحد لأ من ثاني شوية للداخل عامل زي الفراشة بتعرفوا أنتوا كيف عادة بترسموا الفراشة؟ فأنا لو بدأ أرسم ال cyclobutane بهذا الشكل بارسمه واحد اتنين تلاتة أربع هذه الأربع كربونات", "tokens": [2407, 46958, 5016, 22807, 6156, 6027, 39184, 19474, 996, 325, 1929, 307, 406, 257, 1393, 289, 15582, 37893, 3714, 29245, 23328, 39627, 15730, 25124, 28820, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 5296, 10721, 9154, 38637, 7649, 1829, 13412, 2407, 10632, 24976, 3215, 47283, 1211, 6225, 10943, 1211, 30767, 1829, 27188, 2288, 33599, 3660, 39894, 3615, 28480, 14407, 14739, 2655, 14407, 9122, 33911, 6225, 18513, 3660, 39894, 2288, 38251, 14407, 27188, 2288, 33599, 3660, 22807, 6156, 10721, 8315, 45164, 47525, 10721, 5551, 2288, 38251, 2423, 19474, 996, 325, 1929, 39627, 15730, 25124, 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"word": " عامل", "probability": 0.9957682291666666}, {"start": 2246.78, "end": 2247.1, "word": " زي", "probability": 0.910888671875}, {"start": 2247.1, "end": 2247.64, "word": " الفراشة", "probability": 0.9100341796875}, {"start": 2247.64, "end": 2248.06, "word": " بتعرفوا", "probability": 0.93359375}, {"start": 2248.06, "end": 2248.28, "word": " أنتوا", "probability": 0.614013671875}, {"start": 2248.28, "end": 2248.48, "word": " كيف", "probability": 0.97021484375}, {"start": 2248.48, "end": 2248.84, "word": " عادة", "probability": 0.9864908854166666}, {"start": 2248.84, "end": 2249.48, "word": " بترسموا", "probability": 0.95458984375}, {"start": 2249.48, "end": 2252.14, "word": " الفراشة؟", "probability": 0.864990234375}, {"start": 2252.14, "end": 2254.6, "word": " فأنا", "probability": 0.7967936197916666}, {"start": 2254.6, "end": 2254.76, "word": " لو", "probability": 0.98681640625}, {"start": 2254.76, "end": 2255.0, "word": " بدأ", "probability": 0.596923828125}, {"start": 2255.0, "end": 2255.32, "word": " أرسم", "probability": 0.8800455729166666}, {"start": 2255.32, "end": 2255.5, "word": " ال", "probability": 0.92578125}, {"start": 2255.5, "end": 2256.54, "word": " cyclobutane", "probability": 0.83892822265625}, {"start": 2256.54, "end": 2257.26, "word": " بهذا", "probability": 0.94873046875}, {"start": 2257.26, "end": 2257.6, "word": " الشكل", "probability": 0.9892578125}, {"start": 2257.6, "end": 2258.36, "word": " بارسمه", "probability": 0.815185546875}, {"start": 2258.36, "end": 2259.14, "word": " واحد", "probability": 0.759033203125}, {"start": 2259.14, "end": 2259.58, "word": " اتنين", "probability": 0.895263671875}, {"start": 2259.58, "end": 2260.18, "word": " تلاتة", "probability": 0.923583984375}, {"start": 2260.18, "end": 2260.52, "word": " أربع", "probability": 0.70068359375}, {"start": 2260.52, "end": 2260.7, "word": " هذه", "probability": 0.2183837890625}, {"start": 2260.7, "end": 2261.12, "word": " الأربع", "probability": 0.93212890625}, {"start": 2261.12, "end": 2261.84, "word": " كربونات", "probability": 0.85546875}], "temperature": 1.0}, {"id": 96, "seek": 229010, "start": 2264.22, "end": 2290.1, "text": "cyclobutane is not a planar molecule الان تقريبا المعلومات بتصير تتكرر هنا قولنا زي الاش زي ال butter fly اللي هي الفراشة طب لو بدى احكي عن الcyclobutane معلومات ال cis و ال trans و ال substitution نفس الشيء", "tokens": [1344, 66, 752, 5955, 1929, 307, 406, 257, 1393, 289, 15582, 2423, 7649, 6055, 4587, 16572, 3555, 995, 9673, 30241, 20498, 9307, 39894, 9381, 13546, 6055, 2655, 37983, 2288, 34105, 12174, 12610, 8315, 30767, 1829, 2423, 33599, 30767, 1829, 2423, 5517, 3603, 13672, 1829, 39896, 27188, 2288, 33599, 3660, 23032, 3555, 45164, 47525, 7578, 1975, 5016, 4117, 1829, 18871, 2423, 1344, 66, 752, 5955, 1929, 20449, 1211, 20498, 9307, 2423, 37847, 4032, 2423, 1145, 4032, 2423, 35827, 8717, 36178, 25124, 1829, 38207], "avg_logprob": -0.26694276677556783, "compression_ratio": 1.5561224489795917, "no_speech_prob": 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"probability": 0.16796875}, {"start": 2275.94, "end": 2276.28, "word": " قولنا", "probability": 0.8201497395833334}, {"start": 2276.28, "end": 2276.54, "word": " زي", "probability": 0.88232421875}, {"start": 2276.54, "end": 2277.0, "word": " الاش", "probability": 0.461669921875}, {"start": 2277.0, "end": 2278.1, "word": " زي", "probability": 0.770751953125}, {"start": 2278.1, "end": 2278.24, "word": " ال", "probability": 0.798828125}, {"start": 2278.24, "end": 2278.6, "word": " butter", "probability": 0.80712890625}, {"start": 2278.6, "end": 2280.44, "word": " fly", "probability": 0.275146484375}, {"start": 2280.44, "end": 2280.62, "word": " اللي", "probability": 0.634033203125}, {"start": 2280.62, "end": 2281.04, "word": " هي", "probability": 0.830078125}, {"start": 2281.04, "end": 2282.76, "word": " الفراشة", "probability": 0.958251953125}, {"start": 2282.76, "end": 2283.16, "word": " طب", "probability": 0.892333984375}, {"start": 2283.16, "end": 2283.26, "word": " لو", "probability": 0.98486328125}, {"start": 2283.26, "end": 2283.46, "word": " بدى", "probability": 0.572265625}, {"start": 2283.46, "end": 2283.74, "word": " احكي", "probability": 0.9019775390625}, {"start": 2283.74, "end": 2283.9, "word": " عن", "probability": 0.98876953125}, {"start": 2283.9, "end": 2285.1, "word": " الcyclobutane", "probability": 0.7373046875}, {"start": 2285.1, "end": 2286.48, "word": " معلومات", "probability": 0.9114990234375}, {"start": 2286.48, "end": 2286.7, "word": " ال", "probability": 0.93798828125}, {"start": 2286.7, "end": 2286.92, "word": " cis", "probability": 0.358642578125}, {"start": 2286.92, "end": 2287.12, "word": " و", "probability": 0.439208984375}, {"start": 2287.12, "end": 2287.24, "word": " ال", "probability": 0.76806640625}, {"start": 2287.24, "end": 2287.72, "word": " trans", "probability": 0.591796875}, {"start": 2287.72, "end": 2287.88, "word": " و", "probability": 0.8798828125}, {"start": 2287.88, "end": 2288.0, "word": " ال", "probability": 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اكثر", "probability": 0.8338216145833334}, {"start": 2292.34, "end": 2292.56, "word": " من", "probability": 0.97607421875}, {"start": 2292.56, "end": 2293.16, "word": " موقع", "probability": 0.9900716145833334}, {"start": 2293.16, "end": 2294.34, "word": " لكن", "probability": 0.79345703125}, {"start": 2294.34, "end": 2295.2, "word": " لو", "probability": 0.85693359375}, {"start": 2295.2, "end": 2295.44, "word": " كنت", "probability": 0.9755859375}, {"start": 2295.44, "end": 2295.66, "word": " بده", "probability": 0.509033203125}, {"start": 2295.66, "end": 2295.88, "word": " احط", "probability": 0.8447265625}, {"start": 2295.88, "end": 2296.26, "word": " اول", "probability": 0.862060546875}, {"start": 2296.26, "end": 2296.86, "word": " كلور", "probability": 0.681884765625}, {"start": 2296.86, "end": 2297.9, "word": " العشرة", "probability": 0.6857096354166666}, {"start": 2297.9, "end": 2298.68, "word": " هيدروجين", "probability": 0.77548828125}, {"start": 2298.68, "end": 2299.4, 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0.9332682291666666}, {"start": 2312.06, "end": 2312.26, "word": " من", "probability": 0.970703125}, {"start": 2312.26, "end": 2312.74, "word": " مركب", "probability": 0.9767252604166666}, {"start": 2312.74, "end": 2313.56, "word": " بإمكانكوا", "probability": 0.8960774739583334}, {"start": 2313.56, "end": 2314.24, "word": " تحسبوهم", "probability": 0.87529296875}, {"start": 2314.24, "end": 2314.36, "word": " و", "probability": 0.61962890625}, {"start": 2314.36, "end": 2314.9, "word": " تجمعوهم", "probability": 0.9376627604166666}, {"start": 2314.9, "end": 2315.36, "word": " طب", "probability": 0.807861328125}, {"start": 2315.36, "end": 2315.5, "word": " يا", "probability": 0.94482421875}, {"start": 2315.5, "end": 2315.86, "word": " تورا", "probability": 0.7686360677083334}, {"start": 2315.86, "end": 2316.28, "word": " لو", "probability": 0.97705078125}, {"start": 2316.28, "end": 2316.7, "word": " حكيت", "probability": 0.9884440104166666}, {"start": 2316.7, "end": 2316.9, "word": " عن", "probability": 0.9833984375}, {"start": 2316.9, "end": 2317.3, "word": " الشكل", "probability": 0.950439453125}, {"start": 2317.3, "end": 2317.68, "word": " تبعه", "probability": 0.8907470703125}, {"start": 2317.68, "end": 2317.86, "word": " هل", "probability": 0.946533203125}, {"start": 2317.86, "end": 2318.02, "word": " هو", "probability": 0.9912109375}, {"start": 2318.02, "end": 2318.6, "word": " planner؟", "probability": 0.759521484375}], "temperature": 1.0}, {"id": 98, "seek": 234354, "start": 2319.3, "end": 2343.54, "text": "الجواب لأ مش planner طب هى زى إيش بيعمل الآن تخيلوا هى الحلقة الخماسية شايفينها هى دى اللى أمامكوا حلقة خماسية ولا لأ؟ واحد تانين تلاتة أربعة خمسة هيك بتكون planner لكن هى عاملة بهذا الشكل الآن هذا الشكل لو كنا نعطيه اسم", "tokens": [6027, 7435, 14407, 3555, 5296, 10721, 37893, 31268, 23032, 3555, 8032, 7578, 30767, 7578, 11933, 1829, 8592, 4724, 1829, 25957, 1211, 6024, 48506, 6055, 9778, 26895, 14407, 8032, 7578, 21542, 1211, 28671, 33962, 15042, 3794, 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"probability": 0.88330078125}, {"start": 2322.22, "end": 2322.6, "word": " هى", "probability": 0.6392822265625}, {"start": 2322.6, "end": 2322.9, "word": " زى", "probability": 0.929443359375}, {"start": 2322.9, "end": 2323.14, "word": " إيش", "probability": 0.7635904947916666}, {"start": 2323.14, "end": 2323.6, "word": " بيعمل", "probability": 0.9151611328125}, {"start": 2323.6, "end": 2324.12, "word": " الآن", "probability": 0.560546875}, {"start": 2324.12, "end": 2324.6, "word": " تخيلوا", "probability": 0.976806640625}, {"start": 2324.6, "end": 2324.74, "word": " هى", "probability": 0.755859375}, {"start": 2324.74, "end": 2325.18, "word": " الحلقة", "probability": 0.98388671875}, {"start": 2325.18, "end": 2325.92, "word": " الخماسية", "probability": 0.878662109375}, {"start": 2325.92, "end": 2326.64, "word": " شايفينها", "probability": 0.9552734375}, {"start": 2326.64, "end": 2327.6, "word": " هى", "probability": 0.377197265625}, {"start": 2327.6, "end": 2327.72, "word": " دى", "probability": 0.883056640625}, {"start": 2327.72, "end": 2327.82, "word": " اللى", "probability": 0.990478515625}, {"start": 2327.82, "end": 2328.3, "word": " أمامكوا", "probability": 0.89248046875}, {"start": 2328.3, "end": 2328.64, "word": " حلقة", "probability": 0.9568684895833334}, {"start": 2328.64, "end": 2329.34, "word": " خماسية", "probability": 0.93017578125}, {"start": 2329.34, "end": 2329.54, "word": " ولا", "probability": 0.74267578125}, {"start": 2329.54, "end": 2330.42, "word": " لأ؟", "probability": 0.7853190104166666}, {"start": 2330.42, "end": 2331.02, "word": " واحد", "probability": 0.835205078125}, {"start": 2331.02, "end": 2331.92, "word": " تانين", "probability": 0.6533203125}, {"start": 2331.92, "end": 2332.9, "word": " تلاتة", "probability": 0.92822265625}, {"start": 2332.9, "end": 2333.8, "word": " أربعة", "probability": 0.8670247395833334}, {"start": 2333.8, "end": 2334.72, "word": " خمسة", "probability": 0.9722900390625}, {"start": 2334.72, "end": 2335.38, "word": " هيك", "probability": 0.9140625}, {"start": 2335.38, "end": 2335.98, "word": " بتكون", "probability": 0.983642578125}, {"start": 2335.98, "end": 2336.96, "word": " planner", "probability": 0.8623046875}, {"start": 2336.96, "end": 2337.6, "word": " لكن", "probability": 0.8125}, {"start": 2337.6, "end": 2337.88, "word": " هى", "probability": 0.802001953125}, {"start": 2337.88, "end": 2338.4, "word": " عاملة", "probability": 0.9920247395833334}, {"start": 2338.4, "end": 2339.04, "word": " بهذا", "probability": 0.94921875}, {"start": 2339.04, "end": 2339.58, "word": " الشكل", "probability": 0.990234375}, {"start": 2339.58, "end": 2341.64, "word": " الآن", "probability": 0.6500244140625}, {"start": 2341.64, "end": 2341.9, "word": " هذا", "probability": 0.8720703125}, {"start": 2341.9, "end": 2342.26, "word": " الشكل", "probability": 0.986328125}, {"start": 2342.26, "end": 2342.42, "word": " لو", "probability": 0.97900390625}, {"start": 2342.42, "end": 2342.62, "word": " كنا", "probability": 0.625}, {"start": 2342.62, "end": 2343.1, "word": " نعطيه", "probability": 0.953125}, {"start": 2343.1, "end": 2343.54, "word": " اسم", "probability": 0.879638671875}], "temperature": 1.0}, {"id": 99, "seek": 237214, "start": 2344.36, "end": 2372.14, "text": "بنقول عنه non planner أكيد لكن إله اسم أمركوا شفتوا ضرف مغلف رسالة مفتوح it is like an open envelope فهذا الشكل لو قلنا لكوا عنه planner لأ هتقولوا it is like an open envelope اللي هو ضرف رسالة مفتوح لو كنتوا بتكونوا ترسموه", "tokens": [3555, 1863, 39648, 18871, 3224, 2107, 31268, 5551, 4117, 25708, 44381, 11933, 43761, 24525, 2304, 5551, 29973, 4117, 14407, 13412, 5172, 2655, 14407, 48812, 28480, 3714, 17082, 46538, 12602, 3794, 6027, 3660, 3714, 5172, 2655, 2407, 5016, 309, 307, 411, 364, 1269, 19989, 6156, 3224, 15730, 25124, 28820, 45164, 12174, 1211, 8315, 5296, 4117, 14407, 18871, 3224, 31268, 5296, 10721, 8032, 2655, 39648, 14407, 309, 307, 411, 364, 1269, 19989, 13672, 1829, 31439, 48812, 28480, 12602, 3794, 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2349.04, "end": 2349.52, "word": " شفتوا", "probability": 0.7474365234375}, {"start": 2349.52, "end": 2350.12, "word": " ضرف", "probability": 0.6279296875}, {"start": 2350.12, "end": 2351.6, "word": " مغلف", "probability": 0.93603515625}, {"start": 2351.6, "end": 2352.2, "word": " رسالة", "probability": 0.9674072265625}, {"start": 2352.2, "end": 2352.86, "word": " مفتوح", "probability": 0.9966796875}, {"start": 2352.86, "end": 2354.34, "word": " it", "probability": 0.63525390625}, {"start": 2354.34, "end": 2355.6, "word": " is", "probability": 0.92578125}, {"start": 2355.6, "end": 2356.12, "word": " like", "probability": 0.9580078125}, {"start": 2356.12, "end": 2356.86, "word": " an", "probability": 0.826171875}, {"start": 2356.86, "end": 2357.72, "word": " open", "probability": 0.9326171875}, {"start": 2357.72, "end": 2358.48, "word": " envelope", "probability": 0.84521484375}, {"start": 2358.48, "end": 2360.68, "word": " فهذا", "probability": 0.9654947916666666}, {"start": 2360.68, 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2366.24, "word": " open", "probability": 0.87939453125}, {"start": 2366.24, "end": 2367.98, "word": " envelope", "probability": 0.884765625}, {"start": 2367.98, "end": 2369.02, "word": " اللي", "probability": 0.8994140625}, {"start": 2369.02, "end": 2369.26, "word": " هو", "probability": 0.98291015625}, {"start": 2369.26, "end": 2369.64, "word": " ضرف", "probability": 0.929931640625}, {"start": 2369.64, "end": 2370.1, "word": " رسالة", "probability": 0.9954833984375}, {"start": 2370.1, "end": 2370.38, "word": " مفتوح", "probability": 0.9970703125}, {"start": 2370.38, "end": 2370.76, "word": " لو", "probability": 0.8544921875}, {"start": 2370.76, "end": 2371.08, "word": " كنتوا", "probability": 0.9943033854166666}, {"start": 2371.08, "end": 2371.32, "word": " بتكونوا", "probability": 0.7888997395833334}, {"start": 2371.32, "end": 2372.14, "word": " ترسموه", "probability": 0.9744140625}], "temperature": 1.0}, {"id": 100, "seek": 239839, "start": 2372.91, "end": 2398.39, "text": "بشكل فراغي open envelope مش envelope ال .. الظرف تبع الرسالة و الموضوع it is like an open envelope لو بدي ارسمه بهذا الشكل بارسمه فال Cyclopropane is a planar Cyclobutane لأ Cyclopentane لأ الان لو انتقلنا بعد هيك لل Cyclohexane", "tokens": [3555, 8592, 28820, 6156, 2288, 5718, 118, 1829, 1269, 19989, 37893, 19989, 2423, 4386, 6024, 116, 28480, 6055, 3555, 3615, 34892, 3794, 6027, 3660, 4032, 9673, 2407, 11242, 45367, 309, 307, 411, 364, 1269, 19989, 45164, 4724, 16254, 1975, 2288, 38251, 3224, 39627, 15730, 25124, 28820, 4724, 9640, 38251, 3224, 6156, 6027, 10295, 3474, 404, 1513, 1929, 307, 257, 1393, 289, 10295, 66, 752, 5955, 1929, 5296, 10721, 10295, 3474, 404, 317, 1929, 5296, 10721, 2423, 7649, 45164, 16472, 2655, 4587, 1211, 8315, 39182, 39896, 4117, 24976, 10295, 66, 752, 675, 87, 1929], "avg_logprob": -0.2774268477521044, "compression_ratio": 1.601010101010101, "no_speech_prob": 0.0, "words": [{"start": 2372.91, "end": 2373.45, "word": "بشكل", "probability": 0.90283203125}, 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{"start": 2381.63, "end": 2382.07, "word": " it", "probability": 0.70361328125}, {"start": 2382.07, "end": 2382.27, "word": " is", "probability": 0.90966796875}, {"start": 2382.27, "end": 2382.55, "word": " like", "probability": 0.95361328125}, {"start": 2382.55, "end": 2382.81, "word": " an", "probability": 0.8271484375}, {"start": 2382.81, "end": 2383.33, "word": " open", "probability": 0.94140625}, {"start": 2383.33, "end": 2384.01, "word": " envelope", "probability": 0.89208984375}, {"start": 2384.01, "end": 2384.39, "word": " لو", "probability": 0.94921875}, {"start": 2384.39, "end": 2384.55, "word": " بدي", "probability": 0.740234375}, {"start": 2384.55, "end": 2385.05, "word": " ارسمه", "probability": 0.84149169921875}, {"start": 2385.05, "end": 2385.51, "word": " بهذا", "probability": 0.924560546875}, {"start": 2385.51, "end": 2385.93, "word": " الشكل", "probability": 0.991943359375}, {"start": 2385.93, "end": 2386.77, "word": " بارسمه", "probability": 0.9044189453125}, 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لاحظوا نفس الحلقة شايفين كيف أنا مسكها؟", "tokens": [6027, 3555, 1863, 11622, 9957, 383, 21, 39, 21, 4724, 1211, 7649, 2288, 44381, 2423, 39184, 34, 88, 66, 752, 675, 87, 1929, 32239, 3794, 3714, 20292, 4117, 1829, 20498, 4724, 1211, 7649, 2288, 37893, 4724, 1211, 7649, 2288, 23032, 3555, 8032, 995, 9122, 33911, 4724, 1829, 1863, 29245, 3215, 22807, 3714, 43020, 7251, 1863, 29245, 3215, 15844, 5551, 4117, 49115, 9154, 39896, 19986, 3660, 39896, 19986, 3660, 4724, 1829, 39648, 18871, 11296, 21871, 21871, 39896, 19986, 3660, 4724, 2304, 3615, 1863, 7578, 3714, 43020, 8717, 2304, 3794, 4117, 3224, 39627, 15730, 25124, 28820, 20193, 5016, 19913, 14407, 8717, 36178, 21542, 1211, 28671, 13412, 995, 33911, 9957, 9122, 33911, 41850, 47524, 4117, 11296, 22807], "avg_logprob": -0.22160325750060703, "compression_ratio": 1.7235023041474655, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2424.28, "end": 2425.1, "word": "البنزين", "probability": 0.91455078125}, {"start": 2425.1, "end": 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أنا", "probability": 0.767578125}, {"start": 2448.62, "end": 2449.48, "word": " مسكها؟", "probability": 0.8665771484375}], "temperature": 1.0}, {"id": 103, "seek": 247352, "start": 2450.0, "end": 2473.52, "text": "الان هذا الشكل اللي انا ماسكه يشبه ماذا؟ القارب او الزورق بسمي انا هيئة القارب boat confirmation boat confirmation موجود عندكم ربما بهذا المكان شايفينه؟", "tokens": [6027, 7649, 23758, 25124, 28820, 13672, 1829, 1975, 8315, 19446, 3794, 4117, 3224, 7251, 8592, 3555, 3224, 3714, 45636, 995, 22807, 25062, 9640, 3555, 1975, 2407, 6024, 110, 13063, 4587, 4724, 38251, 1829, 1975, 8315, 39896, 19986, 3660, 25062, 9640, 3555, 6582, 21871, 6582, 21871, 3714, 29245, 23328, 43242, 24793, 12602, 3555, 15042, 39627, 15730, 9673, 41361, 13412, 995, 33911, 9957, 3224, 22807], "avg_logprob": -0.13012695545330644, "compression_ratio": 1.6, "no_speech_prob": 0.0, "words": [{"start": 2450.0, "end": 2450.44, "word": "الان", "probability": 0.8037109375}, {"start": 2450.44, "end": 2450.96, 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شايفينه", "probability": 0.923828125}, {"start": 2963.0, "end": 2964.28, "word": " المُركّب؟", "probability": 0.8729248046875}, {"start": 2964.28, "end": 2964.4, "word": " إيش", "probability": 0.8050130208333334}, {"start": 2964.4, "end": 2965.6, "word": " اسمه؟", "probability": 0.9100341796875}, {"start": 2965.6, "end": 2966.04, "word": " مثل", "probability": 0.9931640625}, {"start": 2966.04, "end": 2967.08, "word": " سايكلوبروبين", "probability": 0.8897705078125}, {"start": 2967.08, "end": 2968.3, "word": " اعملوله", "probability": 0.8814453125}, {"start": 2968.3, "end": 2969.16, "word": " مونو", "probability": 0.8562825520833334}, {"start": 2969.16, "end": 2970.18, "word": " إكلورينايشن", "probability": 0.9128146701388888}], "temperature": 1.0}, {"id": 125, "seek": 298893, "start": 2971.47, "end": 2988.93, "text": "وDichlorination وشوفوا كم ناتج بيطلع عندكم طبعا بتكونوا تنتبهوا ان الchlorination ممكن يجي على المثل او على الحلقة بدي كل النواتج الممكنة وهنا كل النواتج الممكنة هذا بحاجة انكوا تتدربوا بشكل جيد", "tokens": [2407, 35, 480, 6746, 2486, 4032, 8592, 38688, 14407, 9122, 2304, 8717, 9307, 7435, 4724, 1829, 9566, 1211, 3615, 43242, 24793, 23032, 3555, 3615, 995, 39894, 30544, 14407, 6055, 29399, 3555, 3224, 14407, 16472, 2423, 11439, 284, 2486, 3714, 43020, 7251, 7435, 1829, 15844, 9673, 12984, 1211, 1975, 2407, 15844, 21542, 1211, 28671, 4724, 16254, 28242, 28239, 2407, 9307, 7435, 9673, 43020, 3660, 37037, 8315, 28242, 28239, 2407, 9307, 7435, 9673, 43020, 3660, 23758, 4724, 5016, 26108, 3660, 16472, 4117, 14407, 6055, 2655, 3215, 25513, 14407, 4724, 8592, 28820, 10874, 25708], "avg_logprob": -0.2455842410740645, "compression_ratio": 1.8186813186813187, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2971.47, "end": 2972.47, "word": "وDichlorination", "probability": 0.552685546875}, {"start": 2972.47, "end": 2972.97, "word": " وشوفوا", "probability": 0.810302734375}, {"start": 2972.97, "end": 2973.21, "word": " كم", "probability": 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المثل", "probability": 0.7413736979166666}, {"start": 2979.15, "end": 2979.71, "word": " او", "probability": 0.8212890625}, {"start": 2979.71, "end": 2980.09, "word": " على", "probability": 0.8896484375}, {"start": 2980.09, "end": 2981.51, "word": " الحلقة", "probability": 0.97900390625}, {"start": 2981.51, "end": 2981.75, "word": " بدي", "probability": 0.61767578125}, {"start": 2981.75, "end": 2982.01, "word": " كل", "probability": 0.432861328125}, {"start": 2982.01, "end": 2982.65, "word": " النواتج", "probability": 0.875732421875}, {"start": 2982.65, "end": 2983.33, "word": " الممكنة", "probability": 0.9420572916666666}, {"start": 2983.33, "end": 2984.37, "word": " وهنا", "probability": 0.47613525390625}, {"start": 2984.37, "end": 2984.57, "word": " كل", "probability": 0.970703125}, {"start": 2984.57, "end": 2985.03, "word": " النواتج", "probability": 0.9432373046875}, {"start": 2985.03, "end": 2985.53, "word": " الممكنة", "probability": 0.9803059895833334}, {"start": 2985.53, "end": 2986.03, "word": " هذا", "probability": 0.78076171875}, {"start": 2986.03, "end": 2986.75, "word": " بحاجة", "probability": 0.9920654296875}, {"start": 2986.75, "end": 2987.23, "word": " انكوا", "probability": 0.8098958333333334}, {"start": 2987.23, "end": 2987.83, "word": " تتدربوا", "probability": 0.91494140625}, {"start": 2987.83, "end": 2988.31, "word": " بشكل", "probability": 0.9934895833333334}, {"start": 2988.31, "end": 2988.93, "word": " جيد", "probability": 0.987060546875}], "temperature": 1.0}, {"id": 126, "seek": 300604, "start": 2989.62, "end": 3006.04, "text": "و تعرفوا أنواع الهيدروجينز اللي موجودة و تحددوا كام ناتج بيطلع عندهم من ال monochlorination و ال dichlorination ترسموهم بعد ما ترسموهم انتبهوا إذا في أشكال متشابهة انه ما تكرروهاش وبهيك بننهي اليوم ان شاء الله", "tokens": [2407, 37279, 28480, 14407, 14739, 14407, 3615, 2423, 3224, 25708, 2288, 29245, 9957, 11622, 13672, 1829, 3714, 29245, 23328, 3660, 4032, 6055, 24401, 3215, 14407, 9122, 10943, 8717, 9307, 7435, 4724, 1829, 9566, 1211, 3615, 43242, 16095, 9154, 2423, 1108, 8997, 6746, 2486, 4032, 2423, 10390, 6746, 2486, 6055, 2288, 38251, 2407, 16095, 39182, 19446, 6055, 2288, 38251, 2407, 16095, 16472, 2655, 3555, 3224, 14407, 11933, 15730, 8978, 5551, 8592, 4117, 6027, 44650, 8592, 16758, 3224, 3660, 16472, 3224, 19446, 6055, 37983, 2288, 2407, 11296, 8592, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984], "avg_logprob": -0.20173267267718173, "compression_ratio": 1.6971153846153846, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2989.62, "end": 2989.82, "word": "و", "probability": 0.35693359375}, {"start": 2989.82, "end": 2990.32, "word": " تعرفوا", "probability": 0.87939453125}, {"start": 2990.32, "end": 2990.68, "word": " أنواع", "probability": 0.9345703125}, {"start": 2990.68, "end": 2991.44, "word": " الهيدروجينز", "probability": 0.7777622767857143}, {"start": 2991.44, "end": 2991.58, "word": " اللي", "probability": 0.643798828125}, {"start": 2991.58, "end": 2992.32, "word": " موجودة", "probability": 0.9873046875}, {"start": 2992.32, "end": 2992.7, "word": " و", "probability": 0.64599609375}, {"start": 2992.7, "end": 2993.44, "word": " تحددوا", "probability": 0.8753662109375}, {"start": 2993.44, "end": 2994.0, "word": " كام", "probability": 0.7275390625}, {"start": 2994.0, "end": 2994.36, "word": " ناتج", "probability": 0.9871419270833334}, {"start": 2994.36, "end": 2994.72, "word": " بيطلع", "probability": 0.90146484375}, {"start": 2994.72, "end": 2994.98, "word": " عندهم", "probability": 0.6868896484375}, {"start": 2994.98, "end": 2995.12, "word": " من", "probability": 0.939453125}, {"start": 2995.12, "end": 2995.22, "word": " ال", "probability": 0.9609375}, {"start": 2995.22, "end": 2996.04, "word": " monochlorination", "probability": 0.65142822265625}, {"start": 2996.04, "end": 2996.2, "word": " و", "probability": 0.93701171875}, {"start": 2996.2, "end": 2996.26, "word": " ال", "probability": 0.80517578125}, {"start": 2996.26, "end": 2997.0, "word": " dichlorination", "probability": 0.7526041666666666}, {"start": 2997.0, "end": 2997.8, "word": " ترسموهم", "probability": 0.9169921875}, {"start": 2997.8, "end": 2998.36, "word": " بعد", "probability": 0.70947265625}, {"start": 2998.36, "end": 2998.52, "word": " ما", "probability": 0.916015625}, {"start": 2998.52, "end": 2999.44, "word": " ترسموهم", "probability": 0.9890625}, {"start": 2999.44, "end": 3000.34, "word": " انتبهوا", "probability": 0.9478515625}, {"start": 3000.34, "end": 3000.56, "word": " إذا", "probability": 0.768310546875}, {"start": 3000.56, "end": 3000.72, "word": " في", "probability": 0.83251953125}, {"start": 3000.72, "end": 3001.16, "word": " أشكال", "probability": 0.9620361328125}, {"start": 3001.16, "end": 3002.18, "word": " متشابهة", "probability": 0.963671875}, {"start": 3002.18, "end": 3002.64, "word": " انه", "probability": 0.534423828125}, {"start": 3002.64, "end": 3002.7, "word": " ما", "probability": 0.6611328125}, {"start": 3002.7, "end": 3003.66, "word": " تكرروهاش", "probability": 0.8272298177083334}, {"start": 3003.66, "end": 3004.7, "word": " وبهيك", "probability": 0.7799072265625}, {"start": 3004.7, "end": 3005.18, "word": " بننهي", "probability": 0.906982421875}, {"start": 3005.18, "end": 3005.5, "word": " اليوم", "probability": 0.967041015625}, {"start": 3005.5, "end": 3005.72, "word": " ان", "probability": 0.473876953125}, {"start": 3005.72, "end": 3005.98, "word": " شاء", "probability": 0.970703125}, {"start": 3005.98, "end": 3006.04, "word": " الله", "probability": 0.94873046875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3006.89125, "duration_after_vad": 2895.673749999989}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..82a5200cf7ab9e0e4c85df14d592edc3c2b33801
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/-FzTT8Q4Xi8_postprocess.srt
@@ -0,0 +1,1960 @@
+1
+00:00:18,780 --> 00:00:24,830
+بسم الله الرحمن الرحيمبعد ما اتكلمنا المرة الماضية
+
+2
+00:00:24,830 --> 00:00:29,410
+عن السكريات المنفردة اتعرفنا عليها ال mono
+
+3
+00:00:29,410 --> 00:00:34,750
+-saccharides الان بدنا نتكلم عن ال di-saccharides
+
+4
+00:00:34,750 --> 00:00:39,930
+طبعا اللي بنقصده احنا ب di-saccharides انه جزيئين
+
+5
+00:00:39,930 --> 00:00:43,910
+من ال mono-saccharides يتحدوا مع بعض و بيعملوا
+
+6
+00:00:43,910 --> 00:00:51,360
+ايش؟ di-saccharide الان مش دائما مش دائمامش دائما
+
+7
+00:00:51,360 --> 00:00:54,820
+هدول الجزيئين اللي بدهم يتحدوا مع بعض بيكونوا زي
+
+8
+00:00:54,820 --> 00:01:00,140
+بعض يعني يوم بدأ احكي انا عن دايسا كرايد ممكن اجيب
+
+9
+00:01:00,140 --> 00:01:06,260
+نفس الجزيئين تماما بكل محتوياتهم طبعا بالتأكيد ال
+
+10
+00:01:06,260 --> 00:01:09,680
+stereo chemistry تكون نفس الشيء تماما و يعملوا
+
+11
+00:01:09,680 --> 00:01:14,040
+دايسا كرايد و ممكن اجيب جزيئين مختلفين و يعملوا
+
+12
+00:01:14,040 --> 00:01:19,820
+دايسا كرايد فمش ضروريمش ضروري ان الـ disaccharide
+
+13
+00:01:19,820 --> 00:01:26,240
+يكون مكوّن من الجزيئين نفسهم تماما، واضح؟ يعني
+
+14
+00:01:26,240 --> 00:01:30,560
+ممكن يكون فعلا من نفس الجزيئين مكوّن disaccharide
+
+15
+00:01:30,560 --> 00:01:36,920
+وممكن يكون من جزيئين مختلفين وهذا اللي هنشوفه لما
+
+16
+00:01:36,920 --> 00:01:45,550
+نستعرض بعض الـ disaccharides بشكل عام ويعني جداأول
+
+17
+00:01:45,550 --> 00:01:51,710
+دايسا كارايد بدنا نستعرضه المالتوز، واضح؟
+
+18
+00:01:51,710 --> 00:01:57,970
+المالتوز، الآن هذا الديسا كارايد مكون من سكرين
+
+19
+00:01:57,970 --> 00:02:03,070
+جولوكوز، لكن فيهم اختلاف في ال stereo chemistry
+
+20
+00:02:03,470 --> 00:02:08,830
+فيهم اختلاف في ال stereo chemistry واحد منهم واحد
+
+21
+00:02:08,830 --> 00:02:14,730
+منهم alpha glucose والتاني منهم beta glucose الآن
+
+22
+00:02:14,730 --> 00:02:19,390
+اللي بتذكروا معنا قولنا احنا ان ال alpha و ال beta
+
+23
+00:02:19,390 --> 00:02:24,930
+sugars بصيروا لما نسكر اخر carbon اللي سمناها ال
+
+24
+00:02:24,930 --> 00:02:29,300
+anomeric carbon و نعملفي حالة السكريات هذه الميزات
+
+25
+00:02:29,300 --> 00:02:35,240
+الكربونات ال fifth chiral center فإذا ال OH كانت
+
+26
+00:02:35,240 --> 00:02:40,020
+للأسفل على هذا الكربون تحديدا بنقول هذا السكر
+
+27
+00:02:40,020 --> 00:02:46,120
+Alpha وإذا كانت للأعلى Beta الآن هذا ال maltose لو
+
+28
+00:02:46,120 --> 00:02:50,760
+بتطلع عليه أنا هيمكون من سكر متصل في ال anomeric
+
+29
+00:02:50,760 --> 00:02:54,560
+carbon لاحظوا أنا تركيزي على أي كربون ال anomeric
+
+30
+00:02:54,560 --> 00:02:59,820
+carbon نكون معلمينها إلى أساساهذه السكرين المتحدين
+
+31
+00:02:59,820 --> 00:03:07,180
+الآن اتطلعوا على واحد منهم ال oxygen فيه alpha
+
+32
+00:03:07,180 --> 00:03:18,840
+واضح التاني منهم ال oxygen فيه betaواضح فالملتوز
+
+33
+00:03:18,840 --> 00:03:24,740
+بيكون في هذه الحالة امكون من Alpha-Glucose مع Beta
+
+34
+00:03:24,740 --> 00:03:29,660
+-Glucose هى دول اتنين قبل ما يتصلوا مع بعض هذا
+
+35
+00:03:29,660 --> 00:03:35,440
+بهذا الشكل كان OH كان Alpha-Glucose هذا كان Beta
+
+36
+00:03:35,440 --> 00:03:41,320
+-Glucose فاتنين اتصلوا مع بعض من خلال موقع اربعة
+
+37
+00:03:41,320 --> 00:03:45,060
+لما ناخد الترقيم واحد اتنين تلاتة اربعة هذا الموقع
+
+38
+00:03:46,020 --> 00:03:49,540
+أربعة اتحدوا من خلال هذه ال Oxygenة اللي في موقع
+
+39
+00:03:49,540 --> 00:03:55,920
+أربعة عملوا رابطة واضح فصار عند المركب مكوّن من
+
+40
+00:03:55,920 --> 00:04:03,040
+Alpha و من Dبيتا جولوكوز وعشان هيك لما بدنا نسميه
+
+41
+00:04:03,040 --> 00:04:09,900
+ممكن انه نقرأ الاسم تبعه هتحسوا انه مش صعب هو ممكن
+
+42
+00:04:09,900 --> 00:04:15,120
+تتخيلوا مركب بيتا جولوكوز لو حطيت ع موقع اربعة مثل
+
+43
+00:04:15,120 --> 00:04:19,960
+شو كنتوا هتسموه four مثل بيتا جولوكوز
+
+44
+00:04:23,450 --> 00:04:29,690
+الاسم الـ Beta في آخر الكلام Beta-D-Glucobiranose
+
+45
+00:04:29,690 --> 00:04:35,170
+مش سمناه لأن جولوكوزم سكرة حلقة سداسية
+
+46
+00:04:35,170 --> 00:04:40,030
+Glucobiranose وD و Beta لأن هذه موجودة في الوضع
+
+47
+00:04:40,030 --> 00:04:45,410
+Beta الآن هذا على موقع أربعة هي على موقع أربعة من
+
+48
+00:04:45,410 --> 00:04:50,950
+خلال ال Oxygen متحد بإيش ب Alpha-D-Glucobiranose
+
+49
+00:04:51,620 --> 00:04:57,800
+واضح الفكرة؟ فيذكر الاسم العام على موقع أربعة من
+
+50
+00:04:57,800 --> 00:05:05,690
+هذا السكر، إيش موجود عنده على موقع أربعة؟الفا دي
+
+51
+00:05:05,690 --> 00:05:08,890
+جلوكو بايرانوس طبعا اتصاله من خلال ال O عشان هيك
+
+52
+00:05:08,890 --> 00:05:13,490
+كتبنا O فاللي بده يفهم الاسم الاسم مش صعب انه هاي
+
+53
+00:05:13,490 --> 00:05:18,290
+المركب اللي عندى بيتا جلوكو بايرانوس على موقع
+
+54
+00:05:18,290 --> 00:05:22,650
+اربعة منه ايش ايجا نعتبرها بين قوسينAlpha
+
+55
+00:05:22,650 --> 00:05:28,230
+Glucobiranose فهذا سكر الملتوز ببساطة هذه الأشياء
+
+56
+00:05:28,230 --> 00:05:34,030
+بيبقى تفهموا فيها الأفكار العامة فالملتوز من سكرين
+
+57
+00:05:34,030 --> 00:05:38,350
+جولوكوز لكن اتنين مش Alpha Alpha ولا Beta Beta
+
+58
+00:05:38,350 --> 00:05:46,590
+Alpha مع Betaالان بيجيني سكر تاني السيلو بيوز
+
+59
+00:05:46,590 --> 00:05:55,730
+السيلو بيوز متحد من سكرين متفقين تماما بيتا جلوكو
+
+60
+00:05:55,730 --> 00:06:00,550
+بيرانوز مع بيتا جلوكو بيرانوز واضح؟ ولذلك لو انا
+
+61
+00:06:00,550 --> 00:06:07,550
+بدأ اطلع على هذا السكر هذا بيتا ولا لا؟ بيتا وعلى
+
+62
+00:06:07,550 --> 00:06:14,780
+هذا السكرهذه أيضًا Beta فلما بنسميه نسبة لهذا Beta
+
+63
+00:06:14,780 --> 00:06:20,740
+D Glucopyranose متحد من موقع أربعةواحد اتنين تلاتة
+
+64
+00:06:20,740 --> 00:06:25,880
+اربعة متحد من موقع اربعة من خلال ال oxygen ال beta
+
+65
+00:06:25,880 --> 00:06:31,160
+D-glucobiranose واضح يعني هذا كأننا بنقول beta D
+
+66
+00:06:31,160 --> 00:06:36,660
+-glucobiranose يحمل على موقع اربعة beta D
+
+67
+00:06:36,660 --> 00:06:42,100
+-glucobiranose واضح الفكرة فال cellobiose بيكون من
+
+68
+00:06:42,100 --> 00:06:50,330
+سكرين متماثلينتماما، لاحظوا قداش نسبة الخلاف اللي
+
+69
+00:06:50,330 --> 00:06:56,450
+بتعمل يعني مركبات مختلفة، يعني انا بحكي عن
+
+70
+00:06:56,450 --> 00:07:02,330
+Glucopyranose و Glucopyranose و بحكي عن هذا Beta
+
+71
+00:07:02,330 --> 00:07:06,870
+في الحالتين، بس التاني مرة Beta و مرة ايش Alpha
+
+72
+00:07:07,710 --> 00:07:14,870
+خلاف بسيط جدا بس كايرال سنتر واحد، الآن بعد شوية
+
+73
+00:07:14,870 --> 00:07:19,770
+هتكتشفوا ان هذا الخلاف البسيط جدا في كايرال سنتر
+
+74
+00:07:19,770 --> 00:07:26,510
+الوحيد بيتبع خلاف كبير جدا جدا جدا في الخواص بعد
+
+75
+00:07:26,510 --> 00:07:31,760
+ذلك للمراكباتيعني لما ييجيوا الجزيئات الـ
+
+76
+00:07:31,760 --> 00:07:35,200
+disaccharides بدهم يعملوا polysaccharides هاي
+
+77
+00:07:35,200 --> 00:07:38,540
+disaccharide و خلّينا نعتبر هاي كمان disaccharide
+
+78
+00:07:38,540 --> 00:07:43,120
+هذا كان من Beta و Beta و هذا كان من Beta و Alpha
+
+79
+00:07:43,120 --> 00:07:47,660
+الان اللي كان من Alpha و Beta الملتوز بيعمل جزئ
+
+80
+00:07:47,660 --> 00:07:56,080
+كبير اسمه نشا او glycogenاللي هي تخزين أو أماكن
+
+81
+00:07:56,080 --> 00:07:59,380
+تخزين ال carbohydrates سواء في النبات أو في
+
+82
+00:07:59,380 --> 00:08:03,400
+الحيوان وهذه بتدوب في الميه وبيقدر البني آدم
+
+83
+00:08:03,400 --> 00:08:07,000
+يهضمها يعني البني آدم لما بياكل النشويات بيقدر
+
+84
+00:08:07,000 --> 00:08:12,180
+بسهولة يحللها للسكريات الأولية بتاعتها أكيد الآن
+
+85
+00:08:12,180 --> 00:08:16,060
+اللي مكوّن من ال beta و ال beta هيجي يعمل ال
+
+86
+00:08:16,060 --> 00:08:20,600
+cellulose هيعمل الخشب البني آدم بيقدرش يهضم الخشب
+
+87
+00:08:20,600 --> 00:08:27,570
+الآن هتيجي تقوله شو الفرق؟بين أساس الخشب و أساس
+
+88
+00:08:27,570 --> 00:08:33,270
+النشا أساس الخشب cellobiose و اتحد و أعطاني
+
+89
+00:08:33,270 --> 00:08:39,110
+cellulose و أساس النشا الملتوز و أعطاني starch
+
+90
+00:08:39,110 --> 00:08:46,230
+واضح فقط مختلفين هدول الاتنين بواحد من السكريات
+
+91
+00:08:46,230 --> 00:08:49,770
+جولوكوز جولوكوز صح جولوكوز جولوكوز بس هذا beta و
+
+92
+00:08:49,770 --> 00:08:55,240
+beta هذا beta و alphaمخيلوا كيف اختلاف بسيط في ال
+
+93
+00:08:55,240 --> 00:09:00,740
+stereochemistry بيقدر الاختلاف كبير بعد هيك في
+
+94
+00:09:00,740 --> 00:09:05,480
+الخواص و في الاستفادة من المركبات بيجينا سكر
+
+95
+00:09:05,480 --> 00:09:15,960
+الحليب ال lactoseاللاكتوز أيضا في جولوكوز لكن في
+
+96
+00:09:15,960 --> 00:09:20,900
+جالاكتوز يعني هدولا ال stereo chemical centers
+
+97
+00:09:20,900 --> 00:09:26,320
+اتغير فيهم اكتر كل الفروقات بينهم هي فروقات ايش
+
+98
+00:09:26,320 --> 00:09:30,500
+لحتى لها ال stereo chemistry يعني هذه الوحدة مش
+
+99
+00:09:30,500 --> 00:09:36,340
+بيتا جولوكوز في هذه الحالة الفا جولوكوز متحد مع
+
+100
+00:09:36,340 --> 00:09:42,300
+بيتا جالاكتوزعشانك لو ذكرنا الاسم العام هتلاحظوا
+
+101
+00:09:42,300 --> 00:09:47,260
+في الآخر Alpha D Glucopyranose هي ال Alpha D
+
+102
+00:09:47,260 --> 00:09:54,480
+Glucopyranose وشايفين أنها Alpha الآن متحد من موقع
+
+103
+00:09:54,480 --> 00:10:01,340
+أربعة ال Beta D Galactopyranose طبعا بنكتب Beta D
+
+104
+00:10:01,340 --> 00:10:07,450
+Galactopyranoseال YL اللي هي بصفته أصبح مجموعة زي
+
+105
+00:10:07,450 --> 00:10:14,330
+ما بقول مثل اثل بروبل ال YL لأنه أصبح مجموعة واضحة
+
+106
+00:10:14,330 --> 00:10:20,630
+الفكرة؟ هذا ال lactose طبعا بيجي صاحبنا، مين
+
+107
+00:10:20,630 --> 00:10:27,330
+صاحبنا؟السكاروز ماحدش اقول عن السكاروز العدو
+
+108
+00:10:27,330 --> 00:10:33,030
+تبعنا، يعني في ناس دائما متطرفين في الحكم على اللي
+
+109
+00:10:33,030 --> 00:10:37,090
+هي هذه الأشياء، كل هذه السكريات و كل حتى الدهون
+
+110
+00:10:37,090 --> 00:10:40,730
+بتلزم للإنسان، بس المشكلة مش أن الإنسان ياخد
+
+111
+00:10:40,730 --> 00:10:45,340
+سكريات و ياخد دهونالمشكلة أنه ياخدها بإفراط يعني
+
+112
+00:10:45,340 --> 00:10:49,160
+الإنسان بحاجة للسكريات، بحاجة للدهون بالتأكيد،
+
+113
+00:10:49,160 --> 00:10:53,940
+بحاجة للكلسترول، بحاجة لكل إشي لكن الإفراط في أي
+
+114
+00:10:53,940 --> 00:10:58,840
+شغل هو اللي بيعمل عندنا إيش المشكلة الآن لو إجينا
+
+115
+00:10:58,840 --> 00:11:02,640
+اتطلعنا على السكروز اللي هو السكر اللي إحنا
+
+116
+00:11:02,640 --> 00:11:07,540
+بنستعمله هتلاحظوا مرة تانية في عندى Alpha
+
+117
+00:11:07,540 --> 00:11:11,680
+-Glucopyranose هاي Alpha هذه شايفينها؟
+
+118
+00:11:14,950 --> 00:11:19,930
+طالما لا أسفل إذا هذه إيش؟ Alpha لكن المرة هذه
+
+119
+00:11:19,930 --> 00:11:27,030
+الاتحاد تبعه مش من موقع أربعة هو متحد ب fractose
+
+120
+00:11:27,030 --> 00:11:33,390
+واضح؟ هو متحد ب fractose و ال fractose keto sugar
+
+121
+00:11:33,390 --> 00:11:38,370
+لما أخدنا السكريات قلنا إن في عندنا ال doses من ال
+
+122
+00:11:38,370 --> 00:11:43,920
+aldehydesو Ketosis لفراكتوز كيتو شوجار و لما بيسكر
+
+123
+00:11:43,920 --> 00:11:50,240
+بيسكر على السكر خماسي السكر الخماسي فيورانوز و من
+
+124
+00:11:50,240 --> 00:11:56,020
+الفيورانوز متحد من موقع ايش؟ واحد واضح؟ الان هذا
+
+125
+00:11:56,020 --> 00:12:04,630
+الفيورانوز لما بتطلع فيهبيتا واضح؟ اذا هذا بيتا
+
+126
+00:12:04,630 --> 00:12:09,270
+عشانك هتلاقوا الاسم تبعه اعتبروا ان هذا هو الأصل
+
+127
+00:12:09,270 --> 00:12:14,010
+وهذه هي الاش المجموعة اللي جاية على الأصل واضح؟
+
+128
+00:12:14,010 --> 00:12:19,950
+فهتلاحظوا بيتا دي فراكتو فيورانوزيل طبعا
+
+129
+00:12:19,950 --> 00:12:26,210
+فيورانوزيل لأنه جاي ايش؟ مجموعة متحدة مع الف دي
+
+130
+00:12:26,210 --> 00:12:33,150
+غلوكوما كتبش هنا by rhinos، كتب by rhinocide، ليش؟
+
+131
+00:12:33,150 --> 00:12:37,790
+لأن الاتحاد تم هنا من موقع واحد، لاحظوا في
+
+132
+00:12:37,790 --> 00:12:41,270
+السكريات اللي قبل شوية، لما كنا نيجع هذا السكر،
+
+133
+00:12:41,270 --> 00:12:45,150
+الاتحاد تم من أي موقع؟ أربعة، هنا الاتحاد تم من
+
+134
+00:12:45,150 --> 00:12:53,080
+موقع واحد، فإذا هذه الرابطة بطلت OH صارت O-Carbon
+
+135
+00:12:53,080 --> 00:12:58,340
+معنا ذلك هذه الرابطة ايش بدها تكون؟ Glycosidic
+
+136
+00:12:58,340 --> 00:13:02,280
+bond واضح؟ عشان Glycosidic bond عشان تكون
+
+137
+00:13:02,280 --> 00:13:08,400
+Glycoside هنحط ايش؟ Glucoburanoside لاحظته هنا
+
+138
+00:13:08,400 --> 00:13:12,640
+كلمة؟ Buranoside لو رجعتوا على الأسماء اللي قبل
+
+139
+00:13:12,640 --> 00:13:19,240
+كان حط Glucoburanose لأن هذه كانت تكون OHفي كل
+
+140
+00:13:19,240 --> 00:13:23,280
+اللي قبل هذه كانت OH غلوكو باي رانوس سواء كان
+
+141
+00:13:23,280 --> 00:13:28,860
+Alpha أو Beta لكن هنا بطلت OH صار الاتحاد من عندها
+
+142
+00:13:28,860 --> 00:13:33,420
+و عشان هيك صارت هذه الرابطة Glycosidic bond فقال
+
+143
+00:13:33,420 --> 00:13:38,300
+غلوكو باي رانوسايد غلوكو باي رانوسايد فالحقيقة
+
+144
+00:13:40,010 --> 00:13:46,150
+السكر اللى فيه two glycosidic bonds هو سكر ايش
+
+145
+00:13:46,150 --> 00:13:50,210
+السكروز انتبهوا لو كانوا بيسألكوا multiple choice
+
+146
+00:13:50,210 --> 00:13:58,670
+الان هذه الرابطة carbon و carbon هذى glycosidic
+
+147
+00:13:58,670 --> 00:14:04,230
+bond ولا لأ و هذا الرابطة glycosidic bond فلما
+
+148
+00:14:04,230 --> 00:14:10,320
+نيجي نطلع احنا حقيقة على السكروزكم جليكوسايدك بوند
+
+149
+00:14:10,320 --> 00:14:18,940
+فيه؟ تنتين لو رجعنا اتطلعنا على السكريات
+
+150
+00:14:18,940 --> 00:14:25,100
+اللي قبل هنا كم جليكوسايدك بوند؟ واحدة ماحدش يقول
+
+151
+00:14:25,100 --> 00:14:29,520
+هذه جليكوسايدك بوند ليش؟ لأن الجليكوسايدك بوند
+
+152
+00:14:29,520 --> 00:14:34,700
+اللي بتتكون على الكايرال سنتر الأخير على هذه مش
+
+153
+00:14:34,700 --> 00:14:40,650
+على هذا الموقع أربعةواضح؟ يعني مش اي او كربون
+
+154
+00:14:40,650 --> 00:14:47,850
+glycosidic bond ال glycosidic bond مرتبطة بأي بأي
+
+155
+00:14:47,850 --> 00:14:52,630
+كربون بال anomeric carbon اللي كانت أساسا الديهايد
+
+156
+00:14:52,630 --> 00:14:56,350
+واضح؟ ولذلك هذه glycosidic bond بس هذه مش
+
+157
+00:14:56,350 --> 00:15:01,390
+glycosidic bond واضح؟ فلو أنا اجيت على ال lactose
+
+158
+00:15:01,390 --> 00:15:08,540
+في one glycosidic bond لو رجعتعلى السيلو بيوز على
+
+159
+00:15:08,540 --> 00:15:13,640
+سبيل المثال برضه أي واحدة anomeric carbon كل سكر
+
+160
+00:15:13,640 --> 00:15:17,780
+فيه two anomeric carbon مظبوط ولا لأ هذه فيها
+
+161
+00:15:17,780 --> 00:15:24,200
+glycosidic bond هذه فيها لذلك في السيلو بيوز في
+
+162
+00:15:24,200 --> 00:15:30,950
+عنده one glycosidic bond هذه لأواضحة الفكرة؟ يعني
+
+163
+00:15:30,950 --> 00:15:34,970
+انا عندي two anomeric carbons مين فيهم glycosidic
+
+164
+00:15:34,970 --> 00:15:40,630
+bond؟ هذي ال O H glycosidic، هذي، اه واضحة الفكرة؟
+
+165
+00:15:40,630 --> 00:15:44,950
+فدائما لما بدنا نعرف كام glycosidic bond، نرجع على
+
+166
+00:15:44,950 --> 00:15:53,670
+الملتوز مثلا، هذي ال anomeric carbons الآن لو
+
+167
+00:15:53,670 --> 00:15:57,690
+إجينا سألنا هذي glycosidic bond؟ O H، هذي
+
+168
+00:15:59,540 --> 00:16:07,100
+Glycosidic bond فالملتوز والسيلوبيوز واللاكتوز
+
+169
+00:16:07,100 --> 00:16:11,380
+هدولة فيهم و one glycosidic bond و التانية عادية
+
+170
+00:16:11,380 --> 00:16:16,740
+عشان ايه كنتوا تلاقوا؟ Glucopyranose عادي لكن لما
+
+171
+00:16:16,740 --> 00:16:23,340
+وصلنا للسكروز لو اجينا سألنا وين ال anomeric
+
+172
+00:16:23,340 --> 00:16:24,180
+carbons؟
+
+173
+00:16:26,580 --> 00:16:31,440
+هي الانوميرك كاربونز الان هنا في جليكوسايدك بوند
+
+174
+00:16:31,440 --> 00:16:36,640
+فيه هنا في جليكوسايدك بوند فيه تنتين جليكوسايدك
+
+175
+00:16:36,640 --> 00:16:42,920
+بوند واضح؟ وعشان هيك هذا لما أنهينا اسمه أنهينا ب
+
+176
+00:16:42,920 --> 00:16:49,480
+side اللي هو alpha D-glucopyranoside زي ما اتعلمنا
+
+177
+00:16:49,480 --> 00:16:53,160
+لما أخدنا الجليكوسايدك بوند وقلنا بننهي بإيش؟
+
+178
+00:16:53,160 --> 00:16:54,360
+جليكوسايد
+
+179
+00:16:57,360 --> 00:17:03,560
+هذا بالنسبة لبعض السكريات اللي هي بنستفيد منها ل
+
+180
+00:17:03,560 --> 00:17:08,700
+ال die saccharides الكلام يمكن يجيب بعضه أن القاسم
+
+181
+00:17:08,700 --> 00:17:16,810
+المشترك ربما في الأشياء المحلية طعم الحلوواضح؟
+
+182
+00:17:16,810 --> 00:17:20,550
+يعني الإنسان بيفتش في النهاية عن إيش؟ الطعم كذلك
+
+183
+00:17:20,550 --> 00:17:24,450
+الحال يمكن تلاحظوه في العطور يعني مار علينا و إحنا
+
+184
+00:17:24,450 --> 00:17:31,410
+بنشرح بعض العطور العطور لا يوجد خليني أقول مجموعة
+
+185
+00:17:31,410 --> 00:17:35,810
+كيميائية تكون قاسم مشترك ما بين العطور ما القاسم
+
+186
+00:17:35,810 --> 00:17:41,920
+المشترك؟الرائحة الذكية، الرائحة الجيدة الآن العطر
+
+187
+00:17:41,920 --> 00:17:46,360
+ممكن مرة يكون Easter ممكن مرة يكون الديهيد ممكن
+
+188
+00:17:46,360 --> 00:17:50,440
+مرة يكون كيتون شوفنا الياسمون مثلا شوفنا ..
+
+189
+00:17:50,440 --> 00:17:53,940
+متذكرين الياسمين كان كيتون شوفنا ال Easter's قولنا
+
+190
+00:17:53,940 --> 00:17:58,040
+عنها مواد عطرية مافيش قاسم كيميائي مشترك القاسم
+
+191
+00:17:58,040 --> 00:18:03,310
+الكيميائي ما بين العطورهو الرائحة الجيدة الآن
+
+192
+00:18:03,310 --> 00:18:07,290
+القاسم الكيميائي ما بين ال sweeteners المحليات و
+
+193
+00:18:07,290 --> 00:18:12,970
+منها السكر هو الطعم الاش؟ الحلو ولذلك الآن في
+
+194
+00:18:12,970 --> 00:18:17,490
+سكريات اللي هي السكريات هذه الصناعية اللي بياخدوها
+
+195
+00:18:17,490 --> 00:18:21,430
+الناس اللي عندهم سكر و ما إلى ذلك لو اطلعت على
+
+196
+00:18:21,430 --> 00:18:25,590
+أنواعها المختلفة مش هتلاقيوا شيء مشترك في الشكل
+
+197
+00:18:25,590 --> 00:18:32,500
+بينها لكن هالمراكبات لما حضروهالاحظوا انه طعمها
+
+198
+00:18:32,500 --> 00:18:37,440
+حلو وبشكل عام آمن يعني كتير في مركبات طعمها حلو
+
+199
+00:18:37,440 --> 00:18:40,980
+لكن خطيرة جدا بيقدرش الإنسان يتعامل معايا
+
+200
+00:18:40,980 --> 00:18:45,440
+الكلوروفورم طعمه حلو لكن سامه carcinogenic لكن هذا
+
+201
+00:18:45,440 --> 00:18:50,040
+المركب مثلا بدون ما ناخد طرق تحضيره هو السكارين
+
+202
+00:18:50,040 --> 00:18:54,720
+سواء وجد ع شكل السكارين أو عشان يدوب بيسحبوا القدش
+
+203
+00:18:54,720 --> 00:18:58,580
+بيعملوا ال salt تبعه طبعا دائما لما نقول salt ال
+
+204
+00:18:58,580 --> 00:19:03,300
+salt ليش بنعمله احناعشان الذائبية تكون أعلى في
+
+205
+00:19:03,300 --> 00:19:08,740
+الميه فلو اطلعنا احنا هذا ال sodium سكارين اللي هو
+
+206
+00:19:08,740 --> 00:19:12,740
+اللي بنستعمله و بنحطه على الشاي مافيش علاقة بين
+
+207
+00:19:12,740 --> 00:19:20,080
+شكله وبين شكل السكاروز لكن يوضع بديل للسكاروز،
+
+208
+00:19:20,080 --> 00:19:25,780
+مظبوط ولا لأ؟ ليش يوضع بديل للسكاروز؟ بسبب الطعم
+
+209
+00:19:25,780 --> 00:19:30,730
+الحلو، الآن في سكريات تانية غير السكاروزالسكارين
+
+210
+00:19:30,730 --> 00:19:36,150
+تستعمل منها مثلا ال Aspartame و ال Cyclamates لو
+
+211
+00:19:36,150 --> 00:19:42,110
+فتشته Cyclamates لو فتشته على شكل ال Aspartame و
+
+212
+00:19:42,110 --> 00:19:46,030
+ال Cyclamate و السكارين هتلاقي كل واحد يمثل شكل
+
+213
+00:19:46,030 --> 00:19:52,410
+معين مافيش قاسم مشترك بينهم القاسم المشترك هو إيش؟
+
+214
+00:19:52,410 --> 00:19:57,510
+الطعم الحلو القاسم المشترك هو الطعم الحلو يعني هاي
+
+215
+00:19:57,510 --> 00:20:02,700
+ال Aspartameطلعوا هذا شكل و هذا شكل بتلاحظوا فيه
+
+216
+00:20:02,700 --> 00:20:07,740
+شيء مشترك مع السكرين طب العسل بس زي محلق و بطعم
+
+217
+00:20:07,740 --> 00:20:12,060
+حلو؟ ايه هو؟ العسل؟ ما هو العسل فيه سكريات كتيرة
+
+218
+00:20:12,060 --> 00:20:17,120
+لأ لأ مش من هدولة من السكريات العادية اللي أخدناها
+
+219
+00:20:17,120 --> 00:20:23,000
+بس تركيبته عاد كبيرة في سكريات و فيتامينات و إشي
+
+220
+00:20:23,000 --> 00:20:31,540
+أكثر من شغلها الآنهذه الـ Disaccharides سواء كانت
+
+221
+00:20:31,540 --> 00:20:37,740
+سكريات مختلفة زي الملتوز اللي احنا قلنا عنه Alpha
+
+222
+00:20:37,740 --> 00:20:43,810
+و Beta الجلوكوز متحدين مع بعض أوالسيلو بيوز اللي
+
+223
+00:20:43,810 --> 00:20:47,710
+قلنا عنه بيتا و بيتا يعني خلينا نركز احنا على
+
+224
+00:20:47,710 --> 00:20:52,810
+الملتوز الملتوز كان من ألفة و بيتا جولوكوز مكون
+
+225
+00:20:52,810 --> 00:20:57,790
+واضح؟ و السيلو بيوز من بيتا و بيتا جولوكوز الآن
+
+226
+00:20:57,790 --> 00:21:02,470
+هدولة لما بيجوا بيعملوا بوليمار كبير لما بيعملوا
+
+227
+00:21:02,470 --> 00:21:06,750
+بوليمار كبير بيكون هم الوحدة الأساسية المتكررة في
+
+228
+00:21:06,750 --> 00:21:12,930
+البوليمار بيعطوناالـ starch أو النشا في حالة ما
+
+229
+00:21:12,930 --> 00:21:18,570
+نتكلم عن إيش؟ عن الملتوز، في حالة ما نتكلم عن
+
+230
+00:21:18,570 --> 00:21:22,990
+السيلوبايوز، بيعطينا السيليلوز، واضح؟ فالملتوز
+
+231
+00:21:22,990 --> 00:21:29,130
+بيعطيني إيش؟ النشا، starch، السيلوبايوز بيعطيني
+
+232
+00:21:29,130 --> 00:21:36,470
+السيليلوز، الخشب، واضح؟ بولمار كبير طبعاًلاحظوا
+
+233
+00:21:36,470 --> 00:21:40,990
+عاد حسب ال polymer اللي بتكون يعني يوم ما نحكي عن
+
+234
+00:21:40,990 --> 00:21:45,550
+polymer يعني عدد كبير من الشغلات هتلاحظوا في علم
+
+235
+00:21:45,550 --> 00:21:50,250
+ال polymerization هذا العدد ممكن يكون 300 وحدة
+
+236
+00:21:50,250 --> 00:21:56,200
+ممكن يكون الف ممكن يكون تلت تلافتمام؟ حسب طريقة
+
+237
+00:21:56,200 --> 00:21:59,420
+الارتباط اللى موجودة في هذا العدد وحسب عدد
+
+238
+00:21:59,420 --> 00:22:03,760
+الجزيئات او الوحدات المكونة له الآن وحدة ال stars
+
+239
+00:22:03,760 --> 00:22:08,300
+هي ايش؟ ال maltose هذه الوحدة اللى مكونة من سكرين
+
+240
+00:22:08,300 --> 00:22:13,160
+حسب كمية الأشياء المتصلة بيصير عند نوع ال polymer
+
+241
+00:22:13,160 --> 00:22:16,340
+عشانك انتوا بال plastic بتلاحظوا في عندكوا أنواع
+
+242
+00:22:16,340 --> 00:22:21,460
+كتيرةفي النيلون في عندكم أنواع كتيرة هذا بيصير
+
+243
+00:22:21,460 --> 00:22:25,860
+يدخل فيه جانب الصناعة انه قداش العدد اللي خلناه
+
+244
+00:22:25,860 --> 00:22:31,640
+يتحد تقريبا يعمل polymer هالخليه 300 جزء و وحدة ال
+
+245
+00:22:31,640 --> 00:22:37,640
+polymer 3000 2000 واضح الفكرة؟ الآن نفس الفكرة من
+
+246
+00:22:37,640 --> 00:22:43,350
+الملتوز هلاحظ ان في انهاالـ starch لو حللته
+
+247
+00:22:43,350 --> 00:22:47,990
+بيعطيني ملتوز، الملتوز لو حللته بيعطيني جولوكوز،
+
+248
+00:22:47,990 --> 00:22:52,830
+لكن جولوكوز Alpha
+
+249
+00:22:53,990 --> 00:22:58,410
+وبيتاجولوكوز لكن هذه الوحدة المتكررة وحدة الملتوز
+
+250
+00:22:58,410 --> 00:23:03,350
+اعملوا منها عدد كبير الان لاحظوا ان النشا مكون من
+
+251
+00:23:03,350 --> 00:23:08,230
+شغلتين من اميلوز بنسبة 20% والباقي تقريبا
+
+252
+00:23:08,230 --> 00:23:15,200
+اميلوبكتل ايش بيفرقوا هدولة الشغلتين؟بعدد الجزيئات
+
+253
+00:23:15,200 --> 00:23:19,980
+المكونة له بطريقة الاتحاد يعني ال amylose في
+
+254
+00:23:19,980 --> 00:23:25,840
+جولوكوز units عادة بيكون عددها ما يقارب بين خمسين
+
+255
+00:23:25,840 --> 00:23:30,260
+لتلتمية جولوكوز unit لكن أهم شيء بيميزها أن هي
+
+256
+00:23:30,260 --> 00:23:37,970
+موجودة في إيش؟بسلاسل بدون تفرعات، واضح؟ سلاسل بهذا
+
+257
+00:23:37,970 --> 00:23:42,830
+الشكل بدون ما يصير فيها تفرعات، العدد تبع ال
+
+258
+00:23:42,830 --> 00:23:47,410
+geolocose units بيكون ما بين خمسين إلى تلتمية
+
+259
+00:23:47,410 --> 00:23:52,770
+geolocose unit والاتحاد زي ما انتوا عارفين نمر
+
+260
+00:23:52,770 --> 00:23:58,270
+أربعة من هان وبتحد من واحد مع الجزء التانييعني
+
+261
+00:23:58,270 --> 00:24:02,190
+احنا لما كنا نتكلم عن ال مالتوز، كنا هنا في عنا
+
+262
+00:24:02,190 --> 00:24:07,550
+الاتحاد مع أربعة أو سابين واحد، أوقتش، الآن لما
+
+263
+00:24:07,550 --> 00:24:11,150
+بتعمل polymer، بيجيب التحد منها، يعني لو انتوا
+
+264
+00:24:11,150 --> 00:24:16,630
+تذكرتوا المالتوز، مش كانت هذه تكون فيهقواتش لما
+
+265
+00:24:16,630 --> 00:24:20,930
+نحكي عن الملتوز لوحده الآن بيصير يتحد من هذه
+
+266
+00:24:20,930 --> 00:24:23,690
+القواتش عشان يعمل ال polymer يعني القواتش اللي
+
+267
+00:24:23,690 --> 00:24:28,610
+كانت ماتروكة فاضية بيصير يتحد من خلالها مع موقع
+
+268
+00:24:28,610 --> 00:24:33,130
+أربعة من وحدة ملتوز تانية بطلع عنده جزء كبير
+
+269
+00:24:33,130 --> 00:24:34,210
+بنسميه إيش
+
+270
+00:24:37,020 --> 00:24:43,020
+الاميلوز الاميلوز هذا احد مكونات النشا الان النشا
+
+271
+00:24:43,020 --> 00:24:49,260
+في مكون تاني الاميلوبكتين الاميلوبكتين في ما بين
+
+272
+00:24:49,260 --> 00:24:53,460
+تلتمية الى خمستلاف جولوكوز units يعني الجولوكوز
+
+273
+00:24:53,460 --> 00:24:59,860
+units اللى في عددها اكبر لكن اهم شغل فيه is
+
+274
+00:24:59,860 --> 00:25:06,920
+هايلبراجد واضح يعني الاميلوز سلسلةالـ amylobectin
+
+275
+00:25:06,920 --> 00:25:13,440
+في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300
+
+276
+00:25:13,440 --> 00:25:17,220
+إلى 5000 جولوكوز units is a highly branched
+
+277
+00:25:17,220 --> 00:25:21,660
+molecule او highly branched molecule chains with
+
+278
+00:25:21,660 --> 00:25:24,360
+consecutive one four links شوفنا كيف one four
+
+279
+00:25:24,360 --> 00:25:28,520
+links الارتباط ال average يعني كل مجموعة حوالي
+
+280
+00:25:28,520 --> 00:25:35,070
+خمسة وعشرين لتلاتين وحدةو بعدين بيجي تفرع 25 ل 30
+
+281
+00:25:35,070 --> 00:25:41,110
+و تفرع بيصير الجزء أشماله highly branched واضح
+
+282
+00:25:41,110 --> 00:25:48,470
+فواضح أن جزء ال amylobectin أكبر من ال amylose و
+
+283
+00:25:48,470 --> 00:25:55,150
+بنفس الوقت اللي بيميزه التفرعات واضح فال amylose
+
+284
+00:25:55,150 --> 00:26:02,220
+is a chain moleculeالـ amylobectin هو جزئ عالي جزئ
+
+285
+00:26:02,220 --> 00:26:11,520
+فيه تفرعات كتيرة طبعا هذه كل أشكال تقريبية بتوضح
+
+286
+00:26:11,520 --> 00:26:20,720
+لنا كيف بيتكونوا هذول الجزيئات الأن لو جينا من ال
+
+287
+00:26:20,720 --> 00:26:30,470
+amylose أيضاغير النشق بمكوينه يعني من الملتوز كان
+
+288
+00:26:30,470 --> 00:26:35,130
+في عنده ال starch اللي هو مكوّن من amylose و
+
+289
+00:26:35,130 --> 00:26:40,470
+mylobectin أيضًا من الملتوز في عنده الجليكوجين ال
+
+290
+00:26:40,470 --> 00:26:45,470
+starch ما كان تخزين ال carbohydratesفي النبات
+
+291
+00:26:45,470 --> 00:26:49,410
+الجليكوجين مكان تخزين ال carbohydrates في
+
+292
+00:26:49,410 --> 00:26:55,750
+الحيوانات برضه هو فيه جولوكوز units لكن حوالي مائة
+
+293
+00:26:55,750 --> 00:27:00,590
+ألف جولوكوز unit لاحظوا العدد في الجليكوجين
+
+294
+00:27:00,590 --> 00:27:06,810
+جليكوجين بيزيد بشكل كبير وبرنشد يعني كل ما بين كل
+
+295
+00:27:06,810 --> 00:27:11,010
+تمانية ل 12 جولوكوز unit خلينا هيك نتخيل هتلاحظوا
+
+296
+00:27:11,010 --> 00:27:17,930
+ان في عندكم إيشالجزء هذا الجليكوجين بيكون أيضا
+
+297
+00:27:17,930 --> 00:27:24,090
+highly branched الآن الجليكوجين بيجي من الجلوكوز
+
+298
+00:27:24,090 --> 00:27:30,130
+اللي بيمتص من أمعاء produced from glucose that is
+
+299
+00:27:30,130 --> 00:27:35,930
+absorbed from intestines into the blood الآن إيش
+
+300
+00:27:35,930 --> 00:27:41,060
+وظيفته هذا الجليكوجين؟ يمكن مار عليكمبيولوجيا اللي
+
+301
+00:27:41,060 --> 00:27:45,260
+هو توازن السكر helps maintain the glucose balance
+
+302
+00:27:45,260 --> 00:27:49,660
+واضح يعني إذا في عندي جولوكوز ازيادة بيجي و بتخزن
+
+303
+00:27:49,660 --> 00:27:54,340
+وين في الجليكوجين بدخل ضمن البوليمار الآن إذا
+
+304
+00:27:54,340 --> 00:28:00,770
+الجسم نقص عليه الجولوكوزبصير هذا نفسه يفرز أو يعطي
+
+305
+00:28:00,770 --> 00:28:07,930
+الجسم وحدات جولوكوز واضح الفكرة؟ يعني هو كأنه هاي
+
+306
+00:28:07,930 --> 00:28:12,450
+جزيئات الجولوكوز بتقدروا تتخيلوها بتمطس من المعدة
+
+307
+00:28:12,450 --> 00:28:16,030
+المفروض لازم لحرق الأكل الناس اللي بياكلوا كتير
+
+308
+00:28:16,030 --> 00:28:21,510
+okay بنجمع هذه الجزيئات هيعملنا إيش؟جلايكوجين
+
+309
+00:28:21,510 --> 00:28:25,790
+وخزانة الان بعد هيك صار البني ادم عنده ناقص في
+
+310
+00:28:25,790 --> 00:28:31,010
+السكر جد ما فيه ناقص بيصير يطلع له جولوكوز واضح؟
+
+311
+00:28:31,010 --> 00:28:36,090
+واضحة الفكرة العامة خليني اقول العامة جدا
+
+312
+00:28:36,090 --> 00:28:42,890
+لجلايكوجين الان لو طلعنا على ال cellulose ال
+
+313
+00:28:42,890 --> 00:28:48,830
+cellulose هو ال polymerاللي جاي من الـ cellobiose
+
+314
+00:28:48,830 --> 00:28:55,010
+اللي بيعمل الخشب يعني النشا والجليكوجين جايين من
+
+315
+00:28:55,010 --> 00:29:01,430
+وين؟ من الملتوز من الملتوز لكن ال cellulose جاي من
+
+316
+00:29:01,430 --> 00:29:03,410
+ال cellobiose
+
+317
+00:29:05,410 --> 00:29:11,210
+بيتا وبيتا sugar فالcellulose is an unbranched
+
+318
+00:29:11,210 --> 00:29:16,210
+polymer مستقيم مافيش فيه branches of glucose
+
+319
+00:29:16,210 --> 00:29:20,110
+joined by one four beta glycosidic bonds كل
+
+320
+00:29:20,110 --> 00:29:29,390
+هالكلام شفناه لاحظوا معي كيف فرق في الأساس بسيط
+
+321
+00:29:29,390 --> 00:29:37,500
+جدا انه هذا منسيلو بيوز هذا من مالتوز السيلو بيوز
+
+322
+00:29:37,500 --> 00:29:42,260
+و المالتوز متحدين في beta غلوكوز لكن السكر التاني
+
+323
+00:29:42,260 --> 00:29:46,820
+في كل واحدة واحد منهم واحد alpha واحد beta يعني
+
+324
+00:29:46,820 --> 00:29:51,120
+خلينا نقول هنا في عند بيتا و بيتا نفس الاشي في
+
+325
+00:29:51,120 --> 00:29:57,340
+السكرين الآن في المالتوز هذا alpha في السيلو بيوز
+
+326
+00:29:58,430 --> 00:30:03,590
+هذا beta فهذا alpha beta هذا beta beta الآن هذا
+
+327
+00:30:03,590 --> 00:30:07,690
+بيصير ملتوز و بيعملني نشا و glycogen هذا بيصير
+
+328
+00:30:07,690 --> 00:30:12,970
+cellulose و cellobiose و بيعمله ال cellulose الان
+
+329
+00:30:12,970 --> 00:30:16,990
+البني آدم بيقدر يهضم النشا بيقدر يهضم ال glycogen
+
+330
+00:30:16,990 --> 00:30:22,670
+بيقدرش يهضم ال cellulose ال cellulose واضح فال
+
+331
+00:30:22,670 --> 00:30:26,830
+humans and other animals they digest starch and
+
+332
+00:30:26,830 --> 00:30:32,880
+glycogenبيقدروا يهضموا النشق والجليكوجين، الآن
+
+333
+00:30:32,880 --> 00:30:37,360
+الحيوانات
+
+334
+00:30:37,360 --> 00:30:42,610
+والنمليمكن تقولوا النمل صار أقوى من البني آدم يعني
+
+335
+00:30:42,610 --> 00:30:46,550
+هو النمل بيقدر يخضم الخشب و البني آدم مابيقدرش
+
+336
+00:30:46,550 --> 00:30:52,030
+معنا ذلك النمل أقوى من البني آدم هي المشكلة انه
+
+337
+00:30:52,030 --> 00:30:57,150
+كمان مش النمل اللي بيخضم او مش الحيوانات المجترة
+
+338
+00:30:57,150 --> 00:31:01,570
+اللي بتخضم لأ بكتيريا موجودة جوا أمعاها هذه
+
+339
+00:31:01,570 --> 00:31:05,050
+البكتيريا اللي جوا أمعاها بتفرز اللي هو
+
+340
+00:31:08,560 --> 00:31:14,060
+الانزيمات اللى هى ال beta glycosidase اللى بتساعد
+
+341
+00:31:14,060 --> 00:31:19,960
+على عملية ايش ان تقدر تهضم الخشب وتستفيد منه واضح
+
+342
+00:31:19,960 --> 00:31:27,760
+فماني بكتيريا contain beta glycosidase دايما اذا
+
+343
+00:31:27,760 --> 00:31:33,510
+شفتوا هذه النهاية ايش هذاالنزيم Oxidase و
+
+344
+00:31:33,510 --> 00:31:37,870
+Redactase و glycosidase and they can hydrolyze
+
+345
+00:31:37,870 --> 00:31:42,810
+يعني يفككوا ال cellulose فلو احنا قلنالكم ان ال
+
+346
+00:31:42,810 --> 00:31:46,090
+humans can hydrolyze cellulose
+
+347
+00:31:48,210 --> 00:31:52,250
+واضح؟ لكن في بكتيريا كتير بتقدر تعمل هذا الكلام
+
+348
+00:31:52,250 --> 00:31:55,990
+هذه موجودة في ال termites اللي هو النمل الأبيض و
+
+349
+00:31:55,990 --> 00:31:59,510
+ال ruminants اللي هي الحيوانات المجترة اللي
+
+350
+00:31:59,510 --> 00:32:03,050
+بتلاقوها مستعدة تاكل ال .. إيش؟ زي الجمل و زي ..
+
+351
+00:32:03,050 --> 00:32:08,250
+أه اللي بتاكل الخشب فبكتيريا في معدتها بتقدر تدخل
+
+352
+00:32:08,250 --> 00:32:13,450
+على هذا الخشب و تحلله لوحدات السكر بحيث أنه النمل
+
+353
+00:32:13,450 --> 00:32:18,430
+الأبيض أو الحيوانات هذه المجترة تقدر تستفيد منهأو
+
+354
+00:32:18,430 --> 00:32:22,310
+من السكر اللي موجود فيه لكن البني آدم مابيقدرش
+
+355
+00:32:22,310 --> 00:32:26,730
+يخدمه أخر
+
+356
+00:32:26,730 --> 00:32:33,090
+شغلة أخر شغلة بنحكيها بالنسبة لهذا الجزء أنه في
+
+357
+00:32:33,090 --> 00:32:37,870
+عندى بعض ال sugars يمكن أن ينزع منها أكسجين هذه
+
+358
+00:32:37,870 --> 00:32:42,850
+بتفيدنا لما بدنا ندرس ال nuclear acid اللي هي
+
+359
+00:32:42,850 --> 00:32:49,090
+الأحماض النووية ومنهابصير اسمها deoxy sugars يعني
+
+360
+00:32:49,090 --> 00:32:53,470
+لاحظوا هذا ال sugar لما يكون فيه ال oxygen و سكر
+
+361
+00:32:53,470 --> 00:32:58,610
+من خمس كربونات tripose تمام لما نشيل منه oxygen
+
+362
+00:32:58,610 --> 00:33:02,870
+منها يعني في الأصل كان في عنده OH لو شيلنا منه
+
+363
+00:33:02,870 --> 00:33:09,490
+oxygen ايش بيصير اسمه؟ deoxy، deoxy يعني منزوعأه
+
+364
+00:33:09,490 --> 00:33:14,570
+لحظة ميزه .. ميزه رجاء في الكلمات، عشانك احنا
+
+365
+00:33:14,570 --> 00:33:22,080
+بنقول اتعبوا شوية، يعني لو اتينا قولنالكم ضايقزيدا
+
+366
+00:33:22,080 --> 00:33:27,800
+يعني اتنين اه لكن دي منزوعة زي ما كنا نقول
+
+367
+00:33:27,800 --> 00:33:31,760
+hydrogenation, dehydrogenation, hydration,
+
+368
+00:33:32,600 --> 00:33:38,260
+dehydrogenation, halogenation, dehydrogenation فال
+
+369
+00:33:38,260 --> 00:33:43,820
+دي بتاعنا اللي هو العكس فهذا ال beta دي دي
+
+370
+00:33:43,820 --> 00:33:48,860
+oxyribofuranose طب علشه فيورانوز لأنهمن حلقاء
+
+371
+00:33:48,860 --> 00:33:53,520
+خماسية هو ال sugar تبع ال DNA هو عبارة عن Ribose
+
+372
+00:33:53,520 --> 00:33:58,720
+نزعت منه ال Oxygen و لو كان ال Ribose اللي في ال
+
+373
+00:33:58,720 --> 00:34:05,400
+Oxygen بيعملنا ال RNA Ribonucleic Acid لما يكون ال
+
+374
+00:34:05,400 --> 00:34:09,800
+DNA Deoxyribonucleic Acid واضح؟
+
+375
+00:34:12,560 --> 00:34:19,700
+الكلام عام عن اللي هي ال dice carats و عن ال
+
+376
+00:34:19,700 --> 00:34:26,210
+polymers اللي بتكونوا منهم خلينا يعني نبدأنعطي
+
+377
+00:34:26,210 --> 00:34:31,310
+فكرة عامة ليش أنا محتاجها الآن مقارنة مع
+
+378
+00:34:31,310 --> 00:34:37,050
+البروتينات اللي بدنا ناخدها في الفصل الأخير ان شاء
+
+379
+00:34:37,050 --> 00:34:41,910
+الله اللي هو ال amino acids و ال peptides و ال
+
+380
+00:34:41,910 --> 00:34:48,210
+proteins زي ما لاحظته يمكن أهم شغلة في ال
+
+381
+00:34:48,210 --> 00:34:52,290
+polysaccharides أهم شغلة في ال polysaccharides أن
+
+382
+00:34:52,290 --> 00:34:57,650
+هم polymersماذا يعني polymers؟ يعني لما أقول
+
+383
+00:34:57,650 --> 00:35:04,150
+النشا، إيش الوحدة تبعته؟ هتقولولي مالتوز
+
+384
+00:35:04,150 --> 00:35:10,390
+البيسكريدي المالتوز، تمام؟ لو قولت مثلا السيللوز،
+
+385
+00:35:10,390 --> 00:35:15,870
+بوليمر كبير، إيش الوحدة تبعته؟ السيلوبيوز، ولذلك
+
+386
+00:35:15,870 --> 00:35:23,490
+ال polysaccharidesيمكن التعامل معها يكون أسهل كتير
+
+387
+00:35:23,490 --> 00:35:28,790
+من التعامل مع البروتينات ليش؟ لأن ال
+
+388
+00:35:28,790 --> 00:35:32,930
+polysaccharides عندي وحدة و بتتكرر يعني كأن
+
+389
+00:35:32,930 --> 00:35:37,110
+الإنسان بيقدر يقول عنهم ان they are real polymers
+
+390
+00:35:37,110 --> 00:35:43,710
+واضح؟ ال polymers مكون من إيش؟مونومارز تتحد تصير
+
+391
+00:35:43,710 --> 00:35:47,910
+دايمارز، ترايمارز، تترامارز، في الآخر إيش؟
+
+392
+00:35:47,910 --> 00:35:55,190
+بوليمارز، فالبوليمار من ناحية المبدأ وحدة متكررة،
+
+393
+00:35:55,190 --> 00:36:00,390
+البوليمار وحدة إيش مالها؟ متكررة، فلمّا أجي أقول
+
+394
+00:36:00,390 --> 00:36:05,990
+starch polymer ما وحدته المتكررة؟ الملتوز، انتهى
+
+395
+00:36:06,580 --> 00:36:13,060
+واضح؟ الآن لما بدي اجي .. لما بدي اجي اتكلم عن ال
+
+396
+00:36:13,060 --> 00:36:18,900
+proteins هلاحظ ان في عندي اختلاف أساسي ال proteins
+
+397
+00:36:18,900 --> 00:36:26,580
+عبارة عن amino acids وال amino acids مختلفين
+
+398
+00:36:27,350 --> 00:36:33,110
+واضح ال amino acids مختلفين ولذلك انا لما بدي اجي
+
+399
+00:36:33,110 --> 00:36:38,050
+اعمل مثلا نشا بقدر اقول بقدر اقول في حالة النشا او
+
+400
+00:36:38,050 --> 00:36:44,630
+ال amylose مالتوز تلاتين
+
+401
+00:36:44,630 --> 00:36:50,320
+وحدة مثلا او تلاتميت وحدةملتوز 300 وحدة واضح؟
+
+402
+00:36:50,320 --> 00:36:56,520
+الملتوز مكرر كده؟ 300 مرة هاي صرت عامل مثلا اميلوز
+
+403
+00:36:56,520 --> 00:37:01,240
+لكن لو جيت بدي اعمل البروتين او الأصغر من البروتين
+
+404
+00:37:01,240 --> 00:37:04,720
+ال بيبتايد اللي هيمر علينا بعد شوية مابقدرش اعمل
+
+405
+00:37:04,720 --> 00:37:09,460
+مثل هذه المعادلة واضح؟ يعني هذه المعادلة ان اقول
+
+406
+00:37:09,460 --> 00:37:15,860
+انه is a real polymerاللي هي ال polysaccharides
+
+407
+00:37:15,860 --> 00:37:21,480
+مالتوز منه تلاتمية وحدة او منه مائة الف وحدة في ال
+
+408
+00:37:21,480 --> 00:37:26,640
+glycogen على سبيل المثال او ما إلى ذلك هي وحدة و
+
+409
+00:37:26,640 --> 00:37:32,680
+متكررة لما بدي اجي احكي عن ال protein
+
+410
+00:37:36,730 --> 00:37:43,590
+هلاحظ ان البروتين عبارة عن amino acids عدد كبير من
+
+411
+00:37:43,590 --> 00:37:49,190
+ال amino acids الان كل amino acid من ناحية المبدأ
+
+412
+00:37:49,190 --> 00:37:56,730
+بختلف عن التاني يعني خليني اتخيل ان هذا حقيقة بمثل
+
+413
+00:37:56,730 --> 00:38:03,490
+البروتين الان هذا بقدر احط عليه كذا to the N لأ طب
+
+414
+00:38:03,490 --> 00:38:10,740
+ايش المطلوب اعمله؟أعمله إيش التسلسل تبعه، يعني لو
+
+415
+00:38:10,740 --> 00:38:14,600
+اتخيلت أنا أن هذا بروتين صغير، يعني بيبتايد، بقول
+
+416
+00:38:14,600 --> 00:38:19,700
+لحظة معايا إيش التسلسل تبعه من amino acids، أسود،
+
+417
+00:38:19,700 --> 00:38:27,230
+أخضر، أحمر، أسود، أزرقتمام؟ الآن كل واحد شكل من
+
+418
+00:38:27,230 --> 00:38:29,870
+هدول، يعني هذا في الـ amino acids ممكن يكون
+
+419
+00:38:29,870 --> 00:38:36,990
+إجليسين، ألانين، سيستين، تريبتوفان، كذا، فما بقدرش
+
+420
+00:38:36,990 --> 00:38:38,830
+أصيغه بصيغة
+
+421
+00:38:41,480 --> 00:38:45,080
+amino acid و بعدين اقول عنه to the end فالان
+
+422
+00:38:45,080 --> 00:38:51,640
+تخيلوا لو كان في عندي مثلا protein من 300 amino
+
+423
+00:38:51,640 --> 00:38:58,780
+acid عشان اعرفه جيدا ايش المطلوب مني اعمل احدد ال
+
+424
+00:38:58,780 --> 00:39:04,200
+300 amino acid مرتبين هذا بيسموه ايش؟ sequence
+
+425
+00:39:04,200 --> 00:39:11,930
+يعني كيف هدول مرتبينأعمل التسلسل تبعه، الآن فكرة
+
+426
+00:39:11,930 --> 00:39:16,490
+ال sequence أو التسلسل غير موجودة في ال
+
+427
+00:39:16,490 --> 00:39:21,170
+polysaccharides، ال polysaccharides نفس الشغلة to
+
+428
+00:39:21,170 --> 00:39:28,380
+the Nمالتوز to the M خلصت واضح بينما في ال
+
+429
+00:39:28,380 --> 00:39:33,100
+proteins هتواجهنا صعوبة ان ال proteins وحدتهم
+
+430
+00:39:33,100 --> 00:39:37,660
+الأساسية amino acids ال amino acids عادة اللي
+
+431
+00:39:37,660 --> 00:39:41,720
+موجودين في ال protein عشرين amino acid الان لما
+
+432
+00:39:41,720 --> 00:39:50,400
+يكون عندى protein من تلتمية amino acid كويس
+
+433
+00:39:50,400 --> 00:39:56,960
+في أشياء مكررة لكنلابد من ال sequence هم اكيد هم
+
+434
+00:39:56,960 --> 00:40:00,580
+اكيد عشرين amino acid تقريبا اللي موجودين في ال
+
+435
+00:40:00,580 --> 00:40:07,180
+proteins لكن هدول العشرين لما بدي اخد منهم protein
+
+436
+00:40:07,180 --> 00:40:15,700
+من تلاتمية amino acid كيف هيكونوا؟ هيكونوا
+
+437
+00:40:15,700 --> 00:40:22,050
+مختلفين مافيش ان احك مثلا glycine to the Nعشان
+
+438
+00:40:22,050 --> 00:40:28,290
+اميز اي protein عن التاني لازم اعد ال 300 ولذلك ال
+
+439
+00:40:28,290 --> 00:40:32,950
+protein لو انا بدى اتكلم عنه انه هل هو real
+
+440
+00:40:32,950 --> 00:40:40,870
+polymer يعني حقيقي بمعنى الكلمة الجواب لأ ال real
+
+441
+00:40:40,870 --> 00:40:48,390
+polymer حقيقة ايش هو؟ monomerto the end زي ما
+
+442
+00:40:48,390 --> 00:40:52,770
+شوفنا ال polyethylene و ال PVC و حتى كمان ال
+
+443
+00:40:52,770 --> 00:40:57,750
+polysaccharides مونومر مكرر لكن هنا لما بدي أجي
+
+444
+00:40:57,750 --> 00:41:01,570
+أحكي عن ال protein هصير أجيب ال amino acids أقول
+
+445
+00:41:01,570 --> 00:41:07,910
+glycine, alanine, tryptophan, cysteine كذا كذا
+
+446
+00:41:07,910 --> 00:41:14,270
+هتلاحظوا أنه مطلوب منناانحدد الترتيب تبع ال amino
+
+447
+00:41:14,270 --> 00:41:17,690
+acids ولذلك ال proteins لو الإنسان بده يستعمل
+
+448
+00:41:17,690 --> 00:41:23,010
+الكلام بدقة أكثر they are macro molecules جزيئات
+
+449
+00:41:23,010 --> 00:41:30,490
+كبيرة macro molecules جزيئات كبيرة أكثر منهم إيش
+
+450
+00:41:30,490 --> 00:41:39,610
+polymers they are macro molecules أكثر منهمبولمار
+
+451
+00:41:39,610 --> 00:41:46,310
+طبعا فيهم نوعا ما شيء مشترك بيخلي بعض الناس يقولوا
+
+452
+00:41:46,310 --> 00:41:54,670
+ممكن تجاوزا نعتبر ال protein بولمار ليش؟ لأنه لو
+
+453
+00:41:54,670 --> 00:42:00,010
+أنا اتطلعت على الهيكل تبعه اللي بتكرر هلاحظ ان هو
+
+454
+00:42:00,010 --> 00:42:05,960
+عبارة عن NCEالان هذه الوحدة بتتكرر في البروتين
+
+455
+00:42:05,960 --> 00:42:12,760
+بعدها N C C double bond O بعدها N C C double bond
+
+456
+00:42:12,760 --> 00:42:19,220
+O هتقولولي مش ناقص غير ايش تكتب هذولة to the N طب
+
+457
+00:42:19,220 --> 00:42:25,870
+ليش مش قادر اكتبهم؟لأن كل amino acid فيها R group
+
+458
+00:42:25,870 --> 00:42:33,210
+مختلفة يعني هذه مرة H هذه مرة CH3 هذه مرة CH2SH
+
+459
+00:42:33,210 --> 00:42:40,430
+فلو بتطلع على الهيكل الأساسي للذرات لبروتين NCC
+
+460
+00:42:40,430 --> 00:42:45,870
+double bond O هو مكرر لكن لو طلعت على هذه المجموعة
+
+461
+00:42:46,670 --> 00:42:51,530
+مش مكررة بناء على ذلك لو هذا مثلا كان بيبتايد هذا
+
+462
+00:42:51,530 --> 00:42:55,810
+بيبتايد مكون من كام amino acid من تلاتة هتعلم أن
+
+463
+00:42:55,810 --> 00:43:00,570
+هذا اسمه إجليسين هذا اسمه ألانين هذا اسمه سيستين
+
+464
+00:43:00,570 --> 00:43:05,450
+حصير أقول هذاEglicin, Alanine, Cysteine هيكون بفرق
+
+465
+00:43:05,450 --> 00:43:08,390
+عن Alanine, Eglicin, Cysteine من نفس التلاتة
+
+466
+00:43:08,390 --> 00:43:14,810
+فانفعلكوا لما نصيح نحكي عن تلاتمية فالبروتين بوجهة
+
+467
+00:43:14,810 --> 00:43:19,870
+النظر اللي بده يتطلع الهيكل الأساسي هو كأنه بوليمر
+
+468
+00:43:19,870 --> 00:43:25,170
+امكرر في N, C, C double bond O N, C, C double bond
+
+469
+00:43:25,170 --> 00:43:28,950
+O لكن لما نيجي نلاحظ أن هذه المجموعة اللي هنا
+
+470
+00:43:28,950 --> 00:43:36,740
+اختلفتبطل polymer ولذلك ال polymer مابنعدش ال 300
+
+471
+00:43:36,740 --> 00:43:40,680
+وحدة ولا ال 5000 وحدة تبعته بس ال protein بدي
+
+472
+00:43:40,680 --> 00:43:45,860
+أجهزة و بدي علم يوم أقول هذا protein كذا يذكر لل
+
+473
+00:43:45,860 --> 00:43:54,170
+5000 وحدة مرتبين و نفس الاشي هيتكرر معاكم مهمفي ال
+
+474
+00:43:54,170 --> 00:43:58,670
+nucleic acids عشان هيك في الشفرة الوراثية وغيرها
+
+475
+00:43:58,670 --> 00:44:02,570
+وغيراتها هتلاحظوا ان البني ادم بيختلف عن التاني و
+
+476
+00:44:02,570 --> 00:44:07,270
+الشغل بتختلف عن التاني انه بدي اذكر الأشياء مرتبة
+
+477
+00:44:08,550 --> 00:44:18,550
+كذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+478
+00:44:18,550 --> 00:44:19,230
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+479
+00:44:19,230 --> 00:44:19,250
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+480
+00:44:19,250 --> 00:44:19,450
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+481
+00:44:19,450 --> 00:44:22,470
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+482
+00:44:22,470 --> 00:44:25,070
+وكذا
+
+483
+00:44:25,690 --> 00:44:30,730
+جزيئات كبيرة اكثر من ان نسميها Polymers و نقدر
+
+484
+00:44:30,730 --> 00:44:35,170
+نكتب شغلته دي انا الان حيصير درسنا القادم سهل اللي
+
+485
+00:44:35,170 --> 00:44:39,730
+بده يدرس ال proteins ايش أساسهم اذا اول شئ بدنا
+
+486
+00:44:39,730 --> 00:44:45,310
+نتعلم على ال amino acids بعدين ال amino acids بتحد
+
+487
+00:44:45,310 --> 00:44:48,890
+و بيعملوا ال protein نتعلم كيف نوجد ال sequence و
+
+488
+00:44:48,890 --> 00:44:53,390
+كيف نحضر ال protein لو بدنايالكن حيكون ان شاء الله
+
+489
+00:44:53,390 --> 00:44:58,410
+درسنا القادم على الوحدة المكونة للبروتين اللي هي
+
+490
+00:44:58,410 --> 00:45:00,370
+عبارة عن ايش؟ الامام
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..2e75bdedf1cf3578baf973b94c8ca17054408e61
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3986, "start": 19.57, "end": 39.87, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله بنشرح معلومات ايضا مختصرة على موضوع ال carbohydrates جزء من ال biochemistry طبعا ال carbohydrates هم اكثر", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 44945, 46309, 5016, 20449, 1211, 20498, 9307, 1975, 1829, 11242, 995, 3714, 46456, 9381, 25720, 15844, 3714, 2407, 11242, 45367, 2423, 36817, 10874, 11622, 38207, 9154, 2423, 12198, 48353, 23032, 3555, 3615, 995, 2423, 36817, 8032, 2304, 1975, 4117, 49115], "avg_logprob": -0.0793805778292673, "compression_ratio": 1.513157894736842, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 19.57, "end": 19.95, "word": "بسم", "probability": 0.921142578125}, {"start": 19.95, "end": 20.11, "word": " الله", "probability": 0.970703125}, {"start": 20.11, "end": 20.49, "word": " الرحمن", "probability": 0.9500325520833334}, {"start": 20.49, "end": 20.95, "word": " الرحيم", "probability": 0.9928385416666666}, {"start": 20.95, "end": 22.39, "word": " اليوم", "probability": 0.8359375}, {"start": 22.39, "end": 22.55, "word": " ان", "probability": 0.68359375}, {"start": 22.55, "end": 22.75, "word": " شاء", "probability": 0.96826171875}, {"start": 22.75, "end": 22.89, "word": " الله", "probability": 0.9541015625}, {"start": 22.89, "end": 24.47, "word": " بنشرح", "probability": 0.9567057291666666}, {"start": 24.47, "end": 25.77, "word": " معلومات", "probability": 0.9752197265625}, {"start": 25.77, "end": 26.11, "word": " ايضا", "probability": 0.8516845703125}, {"start": 26.11, "end": 26.93, "word": " مختصرة", "probability": 0.9754638671875}, {"start": 26.93, "end": 27.91, "word": " على", "probability": 0.79248046875}, {"start": 27.91, "end": 28.55, "word": " موضوع", "probability": 0.9765625}, {"start": 28.55, "end": 29.17, "word": " ال", "probability": 0.8857421875}, {"start": 29.17, "end": 30.19, "word": " carbohydrates", "probability": 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carbohydrates هذا الكلام يمكن يعطيكم إيش فكرة", "tokens": [7435, 11622, 1829, 19986, 9307, 7251, 43020, 3714, 29245, 23328, 3660, 8978, 41950, 21292, 27884, 9154, 25724, 11622, 1829, 19986, 9307, 21542, 1829, 2407, 10632, 7251, 43020, 29739, 3615, 11242, 7251, 14851, 17082, 25513, 44381, 5296, 15042, 6055, 5172, 37983, 14407, 4724, 3794, 12174, 3215, 33599, 8978, 20666, 3215, 22653, 995, 8717, 3555, 9307, 9307, 4032, 28239, 3555, 9307, 9307, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 2815, 425, 541, 4032, 2423, 2815, 425, 541, 31439, 6225, 3555, 9640, 3660, 18871, 36817, 23758, 2423, 28820, 10943, 7251, 43020, 37495, 9566, 1829, 24793, 11933, 1829, 8592, 6156, 4117, 25720], "avg_logprob": -0.09067235134466729, "compression_ratio": 1.6775700934579438, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 40.85, "end": 42.35, "word": "جزيئات", "probability": 0.92041015625}, {"start": 42.35, "end": 43.13, "word": " يمكن", "probability": 0.830322265625}, {"start": 43.13, "end": 44.09, "word": " موجودة", "probability": 0.9931640625}, {"start": 44.09, "end": 44.81, "word": " في", "probability": 0.91064453125}, {"start": 44.81, "end": 45.39, "word": " الطبيعة", "probability": 0.97998046875}, {"start": 45.39, "end": 45.59, "word": " من", "probability": 0.9453125}, {"start": 45.59, "end": 46.21, "word": " الجزيئات", "probability": 0.97685546875}, {"start": 46.21, "end": 46.93, "word": " الحيوية", "probability": 0.9783935546875}, {"start": 46.93, "end": 47.85, "word": " يمكن", "probability": 0.866943359375}, {"start": 47.85, "end": 48.31, "word": " البعض", "probability": 0.9886067708333334}, {"start": 48.31, "end": 49.03, "word": " يستغرب", "probability": 0.9876708984375}, {"start": 49.03, "end": 49.71, "word": " لكن", "probability": 0.7978515625}, {"start": 49.71, "end": 50.37, "word": " لما", "probability": 0.96484375}, {"start": 50.37, "end": 50.97, "word": " تفكروا", "probability": 0.98046875}, {"start": 50.97, "end": 51.21, "word": " بس", "probability": 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58.57, "end": 58.81, "word": " هو", "probability": 0.96923828125}, {"start": 58.81, "end": 59.31, "word": " عبارة", "probability": 0.9471435546875}, {"start": 59.31, "end": 59.73, "word": " عن", "probability": 0.98681640625}, {"start": 59.73, "end": 61.53, "word": " carbohydrates", "probability": 0.9404296875}, {"start": 61.53, "end": 63.03, "word": " هذا", "probability": 0.88671875}, {"start": 63.03, "end": 63.43, "word": " الكلام", "probability": 0.9601236979166666}, {"start": 63.43, "end": 63.71, "word": " يمكن", "probability": 0.95361328125}, {"start": 63.71, "end": 64.39, "word": " يعطيكم", "probability": 0.9462890625}, {"start": 64.39, "end": 64.79, "word": " إيش", "probability": 0.7789713541666666}, {"start": 64.79, "end": 66.21, "word": " فكرة", "probability": 0.9207356770833334}], "temperature": 1.0}, {"id": 3, "seek": 8573, "start": 67.35, "end": 85.73, "text": "بشكل عام ال carbohydrates الصيغة تبعتهم هي عبارة عن carbon مع مية مكررين يعني CH2O to the N فمن هنا إجت فكرة carbohydrates يعني ال carbons وبعدين المية", "tokens": [3555, 8592, 28820, 6225, 10943, 2423, 36817, 31767, 1829, 17082, 3660, 6055, 3555, 34268, 16095, 39896, 6225, 3555, 9640, 3660, 18871, 5954, 20449, 3714, 10632, 3714, 37983, 2288, 9957, 37495, 22653, 5995, 17, 46, 281, 264, 426, 6156, 27842, 34105, 11933, 7435, 2655, 6156, 4117, 25720, 36817, 37495, 22653, 2423, 12143, 892, 46599, 22488, 9957, 9673, 10632], "avg_logprob": -0.16500538818795105, "compression_ratio": 1.4394904458598725, "no_speech_prob": 0.0, "words": [{"start": 67.35, "end": 68.35, "word": "بشكل", "probability": 0.9619140625}, {"start": 68.35, "end": 68.73, "word": " عام", "probability": 0.997802734375}, {"start": 68.73, "end": 69.23, "word": " ال", "probability": 0.90771484375}, {"start": 69.23, "end": 69.89, "word": " carbohydrates", "probability": 0.88232421875}, {"start": 69.89, "end": 70.61, "word": " الصيغة", "probability": 0.9678955078125}, {"start": 70.61, "end": 71.51, "word": " تبعتهم", "probability": 0.95166015625}, {"start": 71.51, "end": 72.35, "word": " هي", "probability": 0.8427734375}, {"start": 72.35, "end": 72.83, "word": " عبارة", "probability": 0.9940185546875}, {"start": 72.83, "end": 73.07, "word": " عن", "probability": 0.994140625}, {"start": 73.07, "end": 73.73, "word": " carbon", "probability": 0.62353515625}, {"start": 73.73, "end": 74.31, "word": " مع", "probability": 0.984375}, {"start": 74.31, "end": 74.83, "word": " مية", "probability": 0.6256103515625}, {"start": 74.83, "end": 76.01, "word": " مكررين", "probability": 0.9459228515625}, {"start": 76.01, "end": 76.35, "word": " يعني", "probability": 0.825439453125}, {"start": 76.35, "end": 77.89, "word": " CH2O", "probability": 0.8562825520833334}, {"start": 77.89, "end": 78.07, "word": " to", "probability": 0.26220703125}, {"start": 78.07, "end": 78.27, "word": " the", "probability": 0.880859375}, {"start": 78.27, "end": 78.51, "word": " N", "probability": 0.8251953125}, {"start": 78.51, "end": 79.47, "word": " فمن", "probability": 0.868896484375}, {"start": 79.47, "end": 79.73, "word": " هنا", "probability": 0.9599609375}, {"start": 79.73, "end": 80.09, "word": " إجت", "probability": 0.6722819010416666}, {"start": 80.09, "end": 80.57, "word": " فكرة", "probability": 0.9915364583333334}, {"start": 80.57, "end": 81.89, "word": " carbohydrates", "probability": 0.92431640625}, {"start": 81.89, "end": 82.61, "word": " يعني", "probability": 0.92041015625}, {"start": 82.61, "end": 82.93, "word": " ال", "probability": 0.7421875}, {"start": 82.93, "end": 83.75, "word": " carbons", "probability": 0.835693359375}, {"start": 83.75, "end": 85.11, "word": " وبعدين", "probability": 0.8111165364583334}, {"start": 85.11, "end": 85.73, "word": " المية", "probability": 0.781982421875}], "temperature": 1.0}, {"id": 4, "seek": 11427, "start": 86.63, "end": 114.27, "text": "Carbons وميّه واضح فعلى سبيل المثال يعني لو بدكوا تاخدوا أنتوا أبسط سكر .. أبسط سكر اللي هو C6H12O6 الآن بنقدر نقول هذا عبارة عن 6 في C وH2O فهو مضاعف لل Carbon و الميّه", "tokens": [24437, 33568, 4032, 2304, 1829, 11703, 3224, 4032, 46958, 5016, 6156, 3615, 23942, 8608, 21292, 1211, 9673, 12984, 6027, 37495, 22653, 45164, 47525, 4117, 14407, 6055, 47283, 3215, 14407, 14739, 2655, 14407, 5551, 3555, 3794, 9566, 8608, 37983, 4386, 5551, 3555, 3794, 9566, 8608, 37983, 13672, 1829, 31439, 383, 21, 39, 4762, 46, 21, 6024, 48506, 44945, 28543, 2288, 8717, 39648, 23758, 6225, 3555, 9640, 3660, 18871, 1386, 8978, 383, 4032, 39, 17, 46, 6156, 3224, 2407, 3714, 11242, 45761, 5172, 24976, 31453, 4032, 9673, 1829, 11703, 3224], "avg_logprob": -0.196804769923178, "compression_ratio": 1.4578947368421054, "no_speech_prob": 0.0, "words": [{"start": 86.63, "end": 87.39, "word": "Carbons", "probability": 0.65673828125}, {"start": 87.39, "end": 88.25, "word": " وميّه", "probability": 0.75556640625}, {"start": 88.25, "end": 89.25, "word": " واضح", "probability": 0.8986002604166666}, {"start": 89.25, "end": 90.93, "word": " فعلى", "probability": 0.6484375}, {"start": 90.93, "end": 91.37, "word": " سبيل", "probability": 0.9855143229166666}, {"start": 91.37, "end": 91.87, "word": " المثال", "probability": 0.9884440104166666}, {"start": 91.87, "end": 92.09, "word": " يعني", "probability": 0.798095703125}, {"start": 92.09, "end": 92.23, "word": " لو", "probability": 0.9248046875}, {"start": 92.23, "end": 92.47, "word": " بدكوا", "probability": 0.5999348958333334}, {"start": 92.47, "end": 92.85, "word": " تاخدوا", "probability": 0.9873046875}, {"start": 92.85, "end": 93.21, "word": " أنتوا", "probability": 0.76904296875}, {"start": 93.21, "end": 94.13, "word": " أبسط", "probability": 0.9720458984375}, {"start": 94.13, "end": 95.31, "word": " سكر", "probability": 0.84130859375}, {"start": 95.31, "end": 95.45, "word": " ..", "probability": 0.195556640625}, {"start": 95.45, "end": 95.81, "word": " أبسط", "probability": 0.9178466796875}, {"start": 95.81, "end": 96.33, "word": " سكر", "probability": 0.89453125}, {"start": 96.33, "end": 97.01, "word": " اللي", "probability": 0.907958984375}, {"start": 97.01, "end": 97.39, "word": " هو", "probability": 0.9814453125}, {"start": 97.39, "end": 102.51, "word": " C6H12O6", "probability": 0.8524576822916666}, {"start": 102.51, "end": 103.45, "word": " الآن", "probability": 0.598388671875}, {"start": 103.45, "end": 104.27, "word": " بنقدر", "probability": 0.9347330729166666}, {"start": 104.27, "end": 104.55, "word": " نقول", "probability": 0.973876953125}, {"start": 104.55, "end": 104.83, "word": " هذا", "probability": 0.95263671875}, {"start": 104.83, "end": 105.23, "word": " عبارة", "probability": 0.9886474609375}, {"start": 105.23, "end": 105.47, "word": " عن", "probability": 0.9921875}, {"start": 105.47, "end": 105.99, "word": " 6", "probability": 0.701171875}, {"start": 105.99, "end": 107.33, "word": " في", "probability": 0.74169921875}, {"start": 107.33, "end": 107.97, "word": " C", "probability": 0.94921875}, {"start": 107.97, "end": 111.01, "word": " وH2O", "probability": 0.8759765625}, {"start": 111.01, "end": 112.19, "word": " فهو", "probability": 0.9905598958333334}, {"start": 112.19, "end": 112.91, "word": " مضاعف", "probability": 0.9822998046875}, {"start": 112.91, "end": 113.13, "word": " لل", "probability": 0.64111328125}, {"start": 113.13, "end": 113.55, "word": " Carbon", "probability": 0.1903076171875}, {"start": 113.55, "end": 113.77, "word": " و", "probability": 0.82421875}, {"start": 113.77, "end": 114.27, "word": " الميّه", "probability": 0.8828125}], "temperature": 1.0}, {"id": 5, "seek": 14291, "start": 114.82, "end": 142.92, "text": "واضح؟ C6H12O6 واضح الفكرة؟ ومن هنا إجا الاسم carbohydrate لأنه بشكل أساسي الصيغة البسيطة تبعته هي عبارة عن carbon وميه واضح هذه الفكرة؟ يعني لما نيجي نسألكم أن ال carbohydrates الصيغة الأساسية بتاعتهم carbon و oxygen carbon و hydrogen", "tokens": [2407, 46958, 5016, 22807, 383, 21, 39, 4762, 46, 21, 4032, 46958, 5016, 27188, 4117, 25720, 22807, 4032, 27842, 34105, 11933, 7435, 995, 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"word": " ومن", "probability": 0.883056640625}, {"start": 120.74, "end": 120.88, "word": " هنا", "probability": 0.8583984375}, {"start": 120.88, "end": 121.2, "word": " إجا", "probability": 0.512451171875}, {"start": 121.2, "end": 121.72, "word": " الاسم", "probability": 0.8125}, {"start": 121.72, "end": 123.18, "word": " carbohydrate", "probability": 0.7861328125}, {"start": 123.18, "end": 124.9, "word": " لأنه", "probability": 0.8946940104166666}, {"start": 124.9, "end": 125.76, "word": " بشكل", "probability": 0.8231608072916666}, {"start": 125.76, "end": 126.54, "word": " أساسي", "probability": 0.9766845703125}, {"start": 126.54, "end": 127.18, "word": " الصيغة", "probability": 0.9779052734375}, {"start": 127.18, "end": 127.74, "word": " البسيطة", "probability": 0.969921875}, {"start": 127.74, "end": 128.44, "word": " تبعته", "probability": 0.924072265625}, {"start": 128.44, "end": 129.06, "word": " هي", "probability": 0.912109375}, {"start": 129.06, "end": 129.52, "word": " عبارة", "probability": 0.99609375}, {"start": 129.52, "end": 129.88, "word": " عن", "probability": 0.9951171875}, {"start": 129.88, "end": 131.74, "word": " carbon", "probability": 0.424072265625}, {"start": 131.74, "end": 132.76, "word": " وميه", "probability": 0.77197265625}, {"start": 132.76, "end": 133.12, "word": " واضح", "probability": 0.9505208333333334}, {"start": 133.12, "end": 133.3, "word": " هذه", "probability": 0.6962890625}, {"start": 133.3, "end": 134.8, "word": " الفكرة؟", "probability": 0.916015625}, {"start": 134.8, "end": 136.14, "word": " يعني", "probability": 0.922607421875}, {"start": 136.14, "end": 136.34, "word": " لما", "probability": 0.75390625}, {"start": 136.34, "end": 136.82, "word": " نيجي", "probability": 0.9417724609375}, {"start": 136.82, "end": 137.42, "word": " نسألكم", "probability": 0.96435546875}, {"start": 137.42, "end": 137.56, "word": " أن", "probability": 0.412841796875}, {"start": 137.56, "end": 137.7, "word": " ال", "probability": 0.884765625}, {"start": 137.7, "end": 138.34, "word": " carbohydrates", "probability": 0.94482421875}, {"start": 138.34, "end": 138.88, "word": " الصيغة", "probability": 0.98828125}, {"start": 138.88, "end": 139.46, "word": " الأساسية", "probability": 0.9886474609375}, {"start": 139.46, "end": 139.98, "word": " بتاعتهم", "probability": 0.89404296875}, {"start": 139.98, "end": 140.46, "word": " carbon", "probability": 0.70458984375}, {"start": 140.46, "end": 140.66, "word": " و", "probability": 0.94775390625}, {"start": 140.66, "end": 141.28, "word": " oxygen", "probability": 0.83203125}, {"start": 141.28, "end": 142.04, "word": " carbon", "probability": 0.42333984375}, {"start": 142.04, "end": 142.28, "word": " و", "probability": 0.93994140625}, {"start": 142.28, "end": 142.92, "word": " hydrogen", "probability": 0.8984375}], "temperature": 1.0}, {"id": 6, "seek": 16754, "start": 143.86, "end": 167.54, "text": "لأ لو كربون و هيدروجين كال سمناها hydrocarbon لكن carbohydrate يعني كربون و مياه الآن ال carbohydrates ببساطة احنا بنقدر نتخيلها اذا بنفهمها بالشكل القاتل هي عبارة عن جزيئات في الغالب كبيرة يعني ممكن نتخيل ان هذا جزيئ", "tokens": [1211, 10721, 45164, 9122, 25513, 11536, 4032, 8032, 25708, 2288, 29245, 9957, 9122, 6027, 8608, 2304, 8315, 11296, 15435, 39294, 44381, 47048, 37495, 22653, 9122, 25513, 11536, 4032, 3714, 25528, 3224, 6024, 48506, 2423, 36817, 4724, 3555, 3794, 41193, 3660, 1975, 5016, 8315, 44945, 28543, 2288, 8717, 2655, 9778, 26895, 11296, 1975, 15730, 44945, 5172, 16095, 11296, 20666, 8592, 28820, 25062, 9307, 1211, 39896, 6225, 3555, 9640, 3660, 18871, 10874, 11622, 1829, 19986, 9307, 8978, 6024, 118, 6027, 3555, 9122, 3555, 48923, 37495, 22653, 3714, 43020, 8717, 2655, 9778, 26895, 16472, 23758, 10874, 11622, 1829, 19986], "avg_logprob": -0.20989046883337276, "compression_ratio": 1.7439613526570048, "no_speech_prob": 0.0, "words": [{"start": 143.86, "end": 144.24, "word": "لأ", "probability": 0.923828125}, {"start": 144.24, "end": 144.44, "word": " لو", 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"probability": 0.7134602864583334}, {"start": 151.42, "end": 152.18, "word": " الآن", "probability": 0.6148681640625}, {"start": 152.18, "end": 152.9, "word": " ال", "probability": 0.908203125}, {"start": 152.9, "end": 153.68, "word": " carbohydrates", "probability": 0.90771484375}, {"start": 153.68, "end": 155.16, "word": " ببساطة", "probability": 0.906640625}, {"start": 155.16, "end": 155.4, "word": " احنا", "probability": 0.8167317708333334}, {"start": 155.4, "end": 155.84, "word": " بنقدر", "probability": 0.8898111979166666}, {"start": 155.84, "end": 156.7, "word": " نتخيلها", "probability": 0.98876953125}, {"start": 156.7, "end": 157.1, "word": " اذا", "probability": 0.7666015625}, {"start": 157.1, "end": 157.76, "word": " بنفهمها", "probability": 0.830810546875}, {"start": 157.76, "end": 158.24, "word": " بالشكل", "probability": 0.9230143229166666}, {"start": 158.24, "end": 158.94, "word": " القاتل", "probability": 0.5629069010416666}, {"start": 158.94, "end": 159.9, "word": " 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كام", "probability": 0.810302734375}, {"start": 1922.3, "end": 1922.76, "word": " كايرال", "probability": 0.98046875}, {"start": 1922.76, "end": 1923.3, "word": " سنتر", "probability": 0.9723307291666666}, {"start": 1923.3, "end": 1924.06, "word": " عندى", "probability": 0.927490234375}, {"start": 1924.06, "end": 1924.86, "word": " هى", "probability": 0.5877685546875}, {"start": 1924.86, "end": 1925.4, "word": " واحد", "probability": 0.8857421875}, {"start": 1925.4, "end": 1926.56, "word": " اتنين", "probability": 0.95458984375}, {"start": 1926.56, "end": 1928.06, "word": " تلاتة", "probability": 0.9244384765625}, {"start": 1928.06, "end": 1929.08, "word": " اربعة", "probability": 0.8289388020833334}, {"start": 1929.08, "end": 1930.36, "word": " ولمّا", "probability": 0.7821044921875}, {"start": 1930.36, "end": 1930.72, "word": " اجى", "probability": 0.8792317708333334}, {"start": 1930.72, "end": 1931.08, "word": " اعمل", "probability": 0.9195963541666666}, {"start": 1931.08, "end": 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"end": 1950.33, "word": " هذا", "probability": 0.42431640625}, {"start": 1950.33, "end": 1951.01, "word": " الكربون", "probability": 0.7586263020833334}, {"start": 1951.01, "end": 1951.81, "word": " تحديدا", "probability": 0.8631591796875}, {"start": 1951.81, "end": 1952.63, "word": " بناء", "probability": 0.753173828125}, {"start": 1952.63, "end": 1952.91, "word": " على", "probability": 0.8583984375}, {"start": 1952.91, "end": 1953.23, "word": " ذلك", "probability": 0.99072265625}, {"start": 1953.23, "end": 1953.43, "word": " لما", "probability": 0.879150390625}, {"start": 1953.43, "end": 1953.83, "word": " بعمل", "probability": 0.93798828125}, {"start": 1953.83, "end": 1954.41, "word": " generation", "probability": 0.9716796875}, {"start": 1954.41, "end": 1954.71, "word": " لل", "probability": 0.7841796875}, {"start": 1954.71, "end": 1955.19, "word": " chiral", "probability": 0.944580078125}, {"start": 1955.19, "end": 1955.57, "word": " center", "probability": 0.91064453125}, {"start": 1955.57, "end": 1955.81, "word": " على", "probability": 0.876953125}, {"start": 1955.81, "end": 1956.15, "word": " هذا", "probability": 0.93505859375}, {"start": 1956.15, "end": 1956.91, "word": " الكربون", "probability": 0.98388671875}, {"start": 1956.91, "end": 1957.49, "word": " ايش", "probability": 0.80322265625}, {"start": 1957.49, "end": 1957.89, "word": " بيصير", "probability": 0.7896728515625}, {"start": 1957.89, "end": 1958.67, "word": " عندى؟", "probability": 0.705078125}, {"start": 1958.67, "end": 1959.63, "word": " two", "probability": 0.61669921875}, {"start": 1959.63, "end": 1960.67, "word": " enantiomers", "probability": 0.7694091796875}], "temperature": 1.0}, {"id": 84, "seek": 197295, "start": 1961.63, "end": 1972.95, "text": "مظبوط ولا لأ؟ الان هدولة لما بدهم يتموه طبعا مش two enantiomers أقفل two diastereomers ليش؟ لأن أنا مش generation of the first chiral center", "tokens": [2304, 19913, 3555, 2407, 9566, 49429, 5296, 10721, 22807, 2423, 7649, 8032, 3215, 12610, 3660, 5296, 15042, 47525, 16095, 7251, 39237, 2407, 3224, 23032, 3555, 3615, 995, 37893, 732, 465, 11520, 298, 433, 5551, 4587, 5172, 1211, 732, 1026, 525, 323, 298, 433, 32239, 8592, 22807, 5296, 33456, 41850, 37893, 5125, 295, 264, 700, 23782, 304, 3056], "avg_logprob": -0.3712284379991992, "compression_ratio": 1.2763157894736843, "no_speech_prob": 0.0, "words": [{"start": 1961.63, "end": 1962.11, "word": "مظبوط", "probability": 0.6874267578125}, {"start": 1962.11, "end": 1962.27, "word": " ولا", "probability": 0.8642578125}, {"start": 1962.27, "end": 1962.95, "word": " لأ؟", "probability": 0.6504720052083334}, {"start": 1962.95, "end": 1963.33, "word": " الان", "probability": 0.58197021484375}, {"start": 1963.33, "end": 1964.09, "word": " هدولة", "probability": 0.76153564453125}, {"start": 1964.09, "end": 1964.27, "word": " لما", "probability": 0.6861572265625}, {"start": 1964.27, "end": 1964.63, "word": " بدهم", "probability": 0.837646484375}, {"start": 1964.63, "end": 1965.45, "word": " يتموه", "probability": 0.7757568359375}, {"start": 1965.45, "end": 1966.11, "word": " طبعا", "probability": 0.799896240234375}, {"start": 1966.11, "end": 1966.41, "word": " مش", "probability": 0.7841796875}, {"start": 1966.41, "end": 1966.59, "word": " two", "probability": 0.763671875}, {"start": 1966.59, "end": 1967.49, "word": " enantiomers", "probability": 0.697021484375}, {"start": 1967.49, "end": 1968.47, "word": " أقفل", "probability": 0.626220703125}, {"start": 1968.47, "end": 1968.87, "word": " two", "probability": 0.86767578125}, {"start": 1968.87, "end": 1969.89, "word": " diastereomers", "probability": 0.86142578125}, {"start": 1969.89, "end": 1970.23, "word": " ليش؟", "probability": 0.7051595052083334}, {"start": 1970.23, "end": 1970.35, "word": " لأن", "probability": 0.841552734375}, {"start": 1970.35, "end": 1970.51, "word": " أنا", "probability": 0.234375}, {"start": 1970.51, "end": 1970.69, "word": " مش", "probability": 0.98046875}, {"start": 1970.69, 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{"start": 1981.34, "end": 1981.58, "word": " هو", "probability": 0.76123046875}, {"start": 1981.58, "end": 1981.9, "word": " اول", "probability": 0.945556640625}, {"start": 1981.9, "end": 1982.4, "word": " chiral", "probability": 0.966552734375}, {"start": 1982.4, "end": 1982.7, "word": " center", "probability": 0.9423828125}, {"start": 1982.7, "end": 1982.94, "word": " ولا", "probability": 0.76953125}, {"start": 1982.94, "end": 1984.04, "word": " نمرخمسة؟", "probability": 0.7462681361607143}, {"start": 1984.04, "end": 1984.7, "word": " نمرخمسة", "probability": 0.9779459635416666}, {"start": 1984.7, "end": 1985.54, "word": " نمرخمسة", "probability": 0.872314453125}, {"start": 1985.54, "end": 1986.0, "word": " لما", "probability": 0.86328125}, {"start": 1986.0, "end": 1986.74, "word": " بنعمل", "probability": 0.9150390625}, {"start": 1986.74, "end": 1987.48, "word": " chiral", "probability": 0.947265625}, {"start": 1987.48, "end": 1988.08, "word": " center", "probability": 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الـOH مرة هتكون للأعلى و مرة هتكون للأسفل هم لاحظين؟", "tokens": [2304, 2655, 8848, 37983, 9957, 3224, 22807, 5125, 295, 257, 1150, 23782, 304, 3056, 295, 257, 2636, 295, 257, 6409, 23782, 304, 3056, 14725, 364, 2681, 9925, 295, 1026, 525, 323, 298, 433, 16247, 19528, 34105, 47525, 8315, 8717, 8592, 38688, 9122, 33911, 23758, 47525, 3224, 7251, 9381, 13546, 23782, 304, 3056, 2423, 39184, 34, 48812, 3555, 9566, 31439, 47525, 3224, 6055, 9381, 13546, 13931, 29538, 2423, 39184, 31187, 3714, 25720, 8032, 2655, 30544, 24976, 10721, 3615, 23942, 4032, 3714, 25720, 8032, 2655, 30544, 24976, 10721, 3794, 5172, 1211, 8032, 2304, 20193, 5016, 19913, 9957, 22807], "avg_logprob": -0.2855992268041237, "compression_ratio": 1.5502183406113537, "no_speech_prob": 0.0, "words": [{"start": 2002.8400000000001, "end": 2003.68, "word": "متذكرينه؟", "probability": 0.7743094308035714}, {"start": 2003.68, "end": 2004.3, "word": " generation", "probability": 0.35302734375}, {"start": 2004.3, "end": 2004.56, 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46958, 5016, 22807, 29538, 2423, 13931, 20193, 37279, 7649, 1829, 1975, 11622, 3215, 5016, 10943, 12399, 20193, 5016, 19913, 14407, 29538, 2423, 13931], "avg_logprob": -0.20010964768497566, "compression_ratio": 1.6384615384615384, "no_speech_prob": 0.0, "words": [{"start": 2748.11, "end": 2748.73, "word": "Beta", "probability": 0.51837158203125}, {"start": 2748.73, "end": 2749.63, "word": " و", "probability": 0.578125}, {"start": 2749.63, "end": 2750.17, "word": " 36", "probability": 0.751953125}, {"start": 2750.17, "end": 2750.55, "word": "%", "probability": 0.6796875}, {"start": 2750.55, "end": 2750.97, "word": " Alpha", "probability": 0.71630859375}, {"start": 2750.97, "end": 2751.49, "word": " ايش", "probability": 0.7122395833333334}, {"start": 2751.49, "end": 2752.33, "word": " معناه؟", "probability": 0.807861328125}, {"start": 2752.33, "end": 2752.71, "word": " معناه", "probability": 0.90185546875}, {"start": 2752.71, "end": 2752.87, "word": " ان", "probability": 0.5029296875}, {"start": 2752.87, "end": 2753.11, "word": " ال", "probability": 0.38671875}, {"start": 2753.11, "end": 2753.15, "word": " ..", "probability": 0.224609375}, {"start": 2753.15, "end": 2753.55, "word": " which", "probability": 0.81396484375}, {"start": 2753.55, "end": 2753.81, "word": " is", "probability": 0.9599609375}, {"start": 2753.81, "end": 2754.11, "word": " more", "probability": 0.962890625}, {"start": 2754.11, "end": 2754.85, "word": " stable", "probability": 0.84765625}, {"start": 2754.85, "end": 2755.91, "word": " ال", "probability": 0.71826171875}, {"start": 2755.91, "end": 2756.13, "word": " Beta", "probability": 0.5654296875}, {"start": 2756.13, "end": 2756.33, "word": " ولا", "probability": 0.86083984375}, {"start": 2756.33, "end": 2756.49, "word": " ال", "probability": 0.95654296875}, {"start": 2756.49, "end": 2757.35, "word": " Alpha؟", "probability": 0.806640625}, {"start": 2757.35, "end": 2757.81, "word": " ال", "probability": 0.91552734375}, {"start": 2757.81, "end": 2758.23, "word": " Beta", "probability": 0.90625}, {"start": 2758.23, "end": 2759.11, "word": " طبعا", "probability": 0.9725341796875}, {"start": 2759.11, "end": 2759.23, "word": " هم", "probability": 0.7958984375}, {"start": 2759.23, "end": 2760.07, "word": " بيفسروا", "probability": 0.815625}, {"start": 2760.07, "end": 2760.65, "word": " على", "probability": 0.71533203125}, {"start": 2760.65, "end": 2761.25, "word": " انه", "probability": 0.8662109375}, {"start": 2761.25, "end": 2761.57, "word": " لو", "probability": 0.97900390625}, {"start": 2761.57, "end": 2762.27, "word": " رسمنا", "probability": 0.9783528645833334}, {"start": 2762.27, "end": 2762.93, "word": " السكر", "probability": 0.919921875}, {"start": 2762.93, "end": 2763.19, "word": " على", "probability": 0.9033203125}, {"start": 2763.19, "end": 2763.71, "word": " شكل", "probability": 0.98828125}, {"start": 2763.71, "end": 2764.99, "word": " الكرسي", "probability": 0.9700927734375}, {"start": 2764.99, "end": 2765.33, "word": " مش", "probability": 0.8056640625}, {"start": 2765.33, "end": 2765.71, "word": " السكر", "probability": 0.9609375}, {"start": 2765.71, "end": 2766.71, "word": " Cyclohexane", "probability": 0.9016927083333334}, {"start": 2766.71, "end": 2766.89, "word": " في", "probability": 0.80078125}, {"start": 2766.89, "end": 2767.41, "word": " النهاية", "probability": 0.9641927083333334}, {"start": 2767.41, "end": 2768.31, "word": " بتكون", "probability": 0.939697265625}, {"start": 2768.31, "end": 2768.61, "word": " ال", "probability": 0.97998046875}, {"start": 2768.61, "end": 2769.05, "word": " OH", "probability": 0.66845703125}, {"start": 2769.05, "end": 2769.33, "word": " في", "probability": 0.93896484375}, {"start": 2769.33, "end": 2769.45, "word": " ال", "probability": 0.90478515625}, {"start": 2769.45, "end": 2769.83, "word": " Beta", "probability": 0.83447265625}, {"start": 2769.83, "end": 2771.15, "word": " equatorial", "probability": 0.9072265625}, {"start": 2771.15, "end": 2771.41, "word": " يعني", "probability": 0.937744140625}, {"start": 2771.41, "end": 2771.75, "word": " غير", "probability": 0.99609375}, {"start": 2771.75, "end": 2772.73, "word": " مزدحمة", "probability": 0.8720703125}, {"start": 2772.73, "end": 2774.25, "word": " واضح؟", "probability": 0.9332275390625}, {"start": 2774.25, "end": 2774.55, "word": " هذه", "probability": 0.74853515625}, {"start": 2774.55, "end": 2774.73, "word": " ال", "probability": 0.9794921875}, {"start": 2774.73, "end": 2775.13, "word": " OH", "probability": 0.89990234375}, {"start": 2775.13, "end": 2775.37, "word": " لا", "probability": 0.76318359375}, {"start": 2775.37, "end": 2775.83, "word": " تعاني", "probability": 0.7921549479166666}, {"start": 2775.83, "end": 2776.27, "word": " ازدحام،", "probability": 0.6945393880208334}, {"start": 2776.27, "end": 2776.55, "word": " لاحظوا", "probability": 0.8958740234375}, {"start": 2776.55, "end": 2776.77, "word": " هذه", "probability": 0.923828125}, {"start": 2776.77, 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"avg_logprob": -0.24672965670740882, "compression_ratio": 1.7333333333333334, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2778.37, "end": 2778.69, "word": "not", "probability": 0.4013671875}, {"start": 2778.69, "end": 2779.45, "word": " crowded", "probability": 0.67529296875}, {"start": 2779.45, "end": 2780.95, "word": " غير", "probability": 0.92529296875}, {"start": 2780.95, "end": 2781.81, "word": " مزحمة", "probability": 0.856201171875}, {"start": 2781.81, "end": 2782.75, "word": " الان", "probability": 0.60009765625}, {"start": 2782.75, "end": 2783.15, "word": " هذه", "probability": 0.875}, {"start": 2783.15, "end": 2783.33, "word": " ال", "probability": 0.64501953125}, {"start": 2783.33, "end": 2783.81, "word": " اواتش", "probability": 0.5581512451171875}, {"start": 2783.81, "end": 2783.99, "word": " اللي", "probability": 0.648681640625}, {"start": 2783.99, "end": 2784.17, "word": " طلع", "probability": 0.63623046875}, {"start": 2784.17, "end": 2784.83, "word": " عليها", "probability": 0.996337890625}, {"start": 2784.83, "end": 2787.45, "word": " crowded", "probability": 0.3271484375}, {"start": 2787.45, "end": 2789.67, "word": " مزحمة", "probability": 0.9073486328125}, {"start": 2789.67, "end": 2791.13, "word": " عشان", "probability": 0.8883463541666666}, {"start": 2791.13, "end": 2791.29, "word": " هيك", "probability": 0.6634521484375}, {"start": 2791.29, "end": 2791.39, "word": " هو", "probability": 0.9296875}, {"start": 2791.39, "end": 2791.93, "word": " بفضل", "probability": 0.8485107421875}, {"start": 2791.93, "end": 2792.29, "word": " يكون", "probability": 0.968994140625}, {"start": 2792.29, "end": 2792.71, "word": " في", "probability": 0.9189453125}, {"start": 2792.71, "end": 2792.87, "word": " ال", "probability": 0.9423828125}, {"start": 2792.87, "end": 2793.21, "word": " beta", "probability": 0.84326171875}, {"start": 2793.21, "end": 2793.45, "word": " ولا", "probability": 0.66162109375}, {"start": 2793.45, "end": 2793.67, "word": " في", "probability": 0.6318359375}, {"start": 2793.67, "end": 2793.79, "word": " ال", "probability": 0.94091796875}, {"start": 2793.79, "end": 2794.19, "word": " alpha", "probability": 0.8740234375}, {"start": 2794.19, "end": 2795.37, "word": " بالنسبة", "probability": 0.8399658203125}, {"start": 2795.37, "end": 2795.77, "word": " أعلى", "probability": 0.751220703125}, {"start": 2795.77, "end": 2796.77, "word": " في", "probability": 0.91796875}, {"start": 2796.77, "end": 2796.91, "word": " ال", "probability": 0.9775390625}, {"start": 2796.91, "end": 2797.29, "word": " beta", "probability": 0.9521484375}, {"start": 2797.29, "end": 2798.29, "word": " بهيك", "probability": 0.8190104166666666}, {"start": 2798.29, "end": 2799.17, "word": " بننهي", "probability": 0.9287109375}, {"start": 2799.17, "end": 2799.83, "word": " اليوم", "probability": 0.929931640625}, {"start": 2799.83, "end": 2800.95, "word": " هذا", "probability": 0.97119140625}, {"start": 2800.95, "end": 2801.53, "word": " الجزء", "probability": 0.9925130208333334}, {"start": 2801.53, "end": 2802.39, "word": " و", "probability": 0.6650390625}, {"start": 2802.39, "end": 2802.67, "word": " المرة", "probability": 0.789306640625}, {"start": 2802.67, "end": 2802.81, "word": " اللي", "probability": 0.6689453125}, {"start": 2802.81, "end": 2802.97, "word": " جاي", "probability": 0.757568359375}, {"start": 2802.97, "end": 2803.09, "word": " ان", "probability": 0.79345703125}, {"start": 2803.09, "end": 2803.31, "word": " شاء", "probability": 0.97119140625}, {"start": 2803.31, "end": 2803.43, "word": " الله", "probability": 0.95947265625}, {"start": 2803.43, "end": 2804.51, "word": " بنستكمل", "probability": 0.972900390625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2804.7615625, "duration_after_vad": 2717.13187499999}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e0811fe4c9950f5bca860343df18b7123065ddb4
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1IQ9qNweIrU_raw.srt
@@ -0,0 +1,2092 @@
+1
+00:00:19,570 --> 00:00:24,470
+بسم الله الرحمن الرحيم اليوم ان شاء الله بنشرح
+
+2
+00:00:24,470 --> 00:00:31,450
+معلومات ايضا مختصرة على موضوع ال carbohydrates جزء
+
+3
+00:00:31,450 --> 00:00:39,870
+من ال biochemistry طبعا ال carbohydrates هم اكثر
+
+4
+00:00:40,850 --> 00:00:46,930
+جزيئات يمكن موجودة في الطبيعة من الجزيئات الحيوية
+
+5
+00:00:46,930 --> 00:00:51,770
+يمكن البعض يستغرب لكن لما تفكروا بس قداش في
+
+6
+00:00:51,770 --> 00:00:57,810
+بالدنيا نباتات و النباتات بشكل أساسي cellulose و
+
+7
+00:00:57,810 --> 00:01:03,430
+ال cellulose هو عبارة عن carbohydrates هذا الكلام
+
+8
+00:01:03,430 --> 00:01:09,890
+يمكن يعطيكم إيش فكرةبشكل عام ال carbohydrates
+
+9
+00:01:09,890 --> 00:01:16,010
+الصيغة تبعتهم هي عبارة عن carbon مع مية مكررين
+
+10
+00:01:16,010 --> 00:01:21,890
+يعني CH2O to the N فمن هنا إجت فكرة carbohydrates
+
+11
+00:01:21,890 --> 00:01:29,250
+يعني ال carbons وبعدين الميةCarbons وميّه واضح
+
+12
+00:01:29,250 --> 00:01:34,130
+فعلى سبيل المثال يعني لو بدكوا تاخدوا أنتوا أبسط
+
+13
+00:01:34,130 --> 00:01:42,510
+سكر .. أبسط سكر اللي هو C6H12O6
+
+14
+00:01:42,510 --> 00:01:51,010
+الآن بنقدر نقول هذا عبارة عن 6 في C وH2O
+
+15
+00:01:51,010 --> 00:01:58,700
+فهو مضاعف لل Carbon و الميّهواضح؟ C6H12O6
+
+16
+00:01:58,700 --> 00:02:04,900
+واضح الفكرة؟ ومن هنا إجا الاسم carbohydrate لأنه
+
+17
+00:02:04,900 --> 00:02:11,740
+بشكل أساسي الصيغة البسيطة تبعته هي عبارة عن carbon
+
+18
+00:02:11,740 --> 00:02:17,700
+وميه واضح هذه الفكرة؟ يعني لما نيجي نسألكم أن ال
+
+19
+00:02:17,700 --> 00:02:20,660
+carbohydrates الصيغة الأساسية بتاعتهم carbon و
+
+20
+00:02:20,660 --> 00:02:25,540
+oxygen carbon و hydrogenلأ لو كربون و هيدروجين كال
+
+21
+00:02:25,540 --> 00:02:30,800
+سمناها hydrocarbon لكن carbohydrate يعني كربون و
+
+22
+00:02:30,800 --> 00:02:35,840
+مياه الآن ال carbohydrates ببساطة احنا بنقدر
+
+23
+00:02:35,840 --> 00:02:41,260
+نتخيلها اذا بنفهمها بالشكل القاتل هي عبارة عن
+
+24
+00:02:41,260 --> 00:02:47,540
+جزيئات في الغالب كبيرة يعني ممكن نتخيل ان هذا جزيئ
+
+25
+00:02:48,170 --> 00:02:55,070
+كبير أشبه ما تكون بوليمار تمام الآن هذه الجزيئات
+
+26
+00:02:55,070 --> 00:02:59,650
+الكبيرة بنسميها احنا polysaccharides يعني سكريات
+
+27
+00:02:59,650 --> 00:03:05,720
+اشمالها عديدة لو عملنا لها hydrolysisفي وجود حمض
+
+28
+00:03:05,720 --> 00:03:12,200
+ميه بتتكسر الى جزيئات اصغر من وحدتين او تلاتة هذه
+
+29
+00:03:12,200 --> 00:03:16,980
+الجزيئات الاصغر بنسميها oligosaccharides يعني هي
+
+30
+00:03:16,980 --> 00:03:21,780
+كانت الكبيرة polysaccharide اتكسرت الى
+
+31
+00:03:21,780 --> 00:03:26,720
+oligosaccharides سكريات بسيطة زى السكريات الثنائية
+
+32
+00:03:26,720 --> 00:03:31,770
+هتمر علينا الان لو كسرناها اكتربصير عندى
+
+33
+00:03:31,770 --> 00:03:37,150
+monosaccharides اللى هو السكر المنفرد فإحنا لما
+
+34
+00:03:37,150 --> 00:03:41,750
+بدنا ندرس الآن بهذا الفصل و نتعرف على السكريات
+
+35
+00:03:41,750 --> 00:03:47,110
+هيكون المحور تبعنا بسيط جدا هنبدأ نقول إيش والله
+
+36
+00:03:47,110 --> 00:03:53,090
+ال monosaccharidesالمنفرد بعد هيك من اكثر من
+
+37
+00:03:53,090 --> 00:03:57,690
+monosaccharide هنعمل disaccharide اللي هو نوع من
+
+38
+00:03:57,690 --> 00:04:01,970
+ال oligosaccharide هيطلع عند السكاروز والملتوز
+
+39
+00:04:01,970 --> 00:04:06,430
+والاشياء هذه اللي هيواضح؟ الآن من ال
+
+40
+00:04:06,430 --> 00:04:11,950
+oligosaccharides هنعمل الجزيئات الكبيرة بشكل أساسي
+
+41
+00:04:11,950 --> 00:04:17,870
+النشا ال starch و ال cellulose واضح؟ فاحنا هنمشي
+
+42
+00:04:17,870 --> 00:04:22,110
+بهذا التدريج أن نتعرف في البداية شو هي ال
+
+43
+00:04:22,110 --> 00:04:27,120
+monosaccharides شو معناه sugarمنفرد لوحده الآن بعد
+
+44
+00:04:27,120 --> 00:04:32,160
+هيك اتنين من الشجر المنفرد هيعملولي Dysaccharide
+
+45
+00:04:32,160 --> 00:04:36,280
+اللي هو يعتبر نوع من ال Oligosaccharides و بعدين
+
+46
+00:04:36,280 --> 00:04:41,180
+لو اتحدوا ال Dysaccharides بشكل كبير عدد كبير منهم
+
+47
+00:04:41,180 --> 00:04:46,140
+بيعطينا ال إيش ال polysaccharides على سبيل المثال
+
+48
+00:04:46,140 --> 00:04:52,890
+النشا polysaccharideالنشط بولي ساكرايد لو عملنا له
+
+49
+00:04:52,890 --> 00:04:58,510
+هيدروليسيز بيعطينا داي ساكرايد اللي هو الملتوز
+
+50
+00:04:58,510 --> 00:05:03,950
+فالملتوز أوليغو ساكرايد أو داي ساكرايد ما هو الداي
+
+51
+00:05:03,950 --> 00:05:08,910
+أحد أنواع الأوليغو ساكرايد الآن لو الملتوز كسرناه
+
+52
+00:05:08,910 --> 00:05:16,240
+للوحدات الأساسية هو مكون من وحدتين جولوكوزالملتوز
+
+53
+00:05:16,240 --> 00:05:21,220
+من وحدتين جولوكوز واضح الفكرة فالجولوكوز مونو
+
+54
+00:05:21,220 --> 00:05:27,760
+ساكرايد الملتوز داي ساكرايد الاسترش بوني ساكرايد
+
+55
+00:05:27,760 --> 00:05:34,260
+واضح طبعا اللي بده يبتدى الان يتعرف ايش هم المونو
+
+56
+00:05:34,260 --> 00:05:37,300
+ساكرايد ايش هم المونو ساكرايد
+
+57
+00:05:40,150 --> 00:05:45,650
+ال sugar بنعرفهم انهم polyhydroxyaldehydes او
+
+58
+00:05:45,650 --> 00:05:49,670
+polyhydroxyketones ال polyhydroxyaldehydes بنسميهم
+
+59
+00:05:49,670 --> 00:05:54,130
+ال doses و ال polyhydroxyketones كيتوزز بمعنى
+
+60
+00:05:54,130 --> 00:06:01,070
+الشجر لازم يكون فيه يا aldehyde يا كيتون مع
+
+61
+00:06:01,070 --> 00:06:09,170
+مجموعات OH كتيرة اكثر من مجموعة OHولذلك لو احنا
+
+62
+00:06:09,170 --> 00:06:13,850
+اتطلعنا مثلا على المركب اللى موجود عندنا هنا اللى
+
+63
+00:06:13,850 --> 00:06:19,570
+هو الجليسرال ديهايد هل يترى هذا يمكن انه يتصنف
+
+64
+00:06:19,570 --> 00:06:27,510
+بمنطق الكيميا ك sugar فى عندي هنا الديهايد وفى
+
+65
+00:06:27,510 --> 00:06:35,050
+عندي هنا مجموعاتOH إذا هذا بولي هيدروكسي الديهايد
+
+66
+00:06:35,050 --> 00:06:39,330
+يعني عديد هيدروكسي ال الديهايد ولذلك هذا بنقول عنه
+
+67
+00:06:39,330 --> 00:06:45,550
+إيش ال dose ال dose يعني sugar من ال الديهايد طيب
+
+68
+00:06:45,550 --> 00:06:50,570
+ال dye هيدروكسي أسيتون بتعرفوا ال أسيتون CH3C
+
+69
+00:06:50,570 --> 00:06:55,130
+double bond O CH3 شيلت H حطيت مكان هنا OH وكمان
+
+70
+00:06:55,130 --> 00:07:01,270
+هنا OH صارDihydroxy-13-Dihydroxyacetone الآن هذا
+
+71
+00:07:01,270 --> 00:07:08,050
+الـDihydroxyacetone فيه كيتون وفيه
+
+72
+00:07:08,050 --> 00:07:14,870
+مجموعات OH إذا هذا عبارة عن بوليهيدروكس كيتون
+
+73
+00:07:14,870 --> 00:07:20,010
+بوليهيدروكس كيتون إذا هذا sugar كيتوز
+
+74
+00:07:21,950 --> 00:07:27,190
+ليش؟ لأنه جاي من كيتون، الدوز من ال الديهايد، واضح
+
+75
+00:07:27,190 --> 00:07:34,110
+الفكرة؟ الآن لو اتطلعت على ال glycerol، ال
+
+76
+00:07:34,110 --> 00:07:37,950
+glycerol او ال glycerin، فيه بس ال O H's، مافيه
+
+77
+00:07:37,950 --> 00:07:43,190
+الديهايد او كيتون، فهل ال glycerin بنصنفه انه
+
+78
+00:07:43,190 --> 00:07:46,930
+sugar كيميائيا؟ لأواضحة الفكرة؟ يعني لما نيجي
+
+79
+00:07:46,930 --> 00:07:51,410
+نقولكم glycerol can be classified as a sugar او is
+
+80
+00:07:51,410 --> 00:07:54,630
+classified as a sugar، لأ، لو قلنالكوا
+
+81
+00:07:54,630 --> 00:08:01,810
+dihydroxyacetone is an aldose، فهمته؟ او لو
+
+82
+00:08:01,810 --> 00:08:07,390
+قلنالكوا glyceraldehyde is equitoseglial aldehyde
+
+83
+00:08:07,390 --> 00:08:11,630
+is an aldose, dihydroxyacetone is a ketose تفهمنا
+
+84
+00:08:11,630 --> 00:08:15,710
+بالظبط إذا إيش معنى sugar، إيش معنى aldose، إيش
+
+85
+00:08:15,710 --> 00:08:20,550
+معنى ketose، واضحة الفكرة؟ والشجر لازم ينوجد فيه
+
+86
+00:08:20,550 --> 00:08:26,790
+كام شغلة؟ شغلتين، يا الديهيد، يا كيتون، ومجموعات
+
+87
+00:08:26,790 --> 00:08:35,230
+الـOH، هذا اللي بدنا نصنفه sugarلو بدنا ننطلق من
+
+88
+00:08:35,230 --> 00:08:40,850
+ال glyceraldehyde، ال glyceraldehyde كم carbon كان
+
+89
+00:08:40,850 --> 00:08:47,710
+فيه؟ تلاتة، تلاتة، احنا بدنا نعلمكوا العد، تلاتة،
+
+90
+00:08:47,710 --> 00:08:49,670
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+91
+00:08:49,670 --> 00:08:51,370
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+92
+00:08:51,370 --> 00:08:51,370
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+93
+00:08:51,370 --> 00:08:51,370
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+94
+00:08:51,370 --> 00:08:58,720
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تهي الديهيد و
+
+95
+00:08:58,720 --> 00:09:02,360
+أكتر من جمعة أواتش هذا بنقول عنه تيتروز تيتروز
+
+96
+00:09:02,360 --> 00:09:09,430
+يعني سكر إيش من أربع كربونات طب لو كانوا خمسةبنتوز
+
+97
+00:09:09,430 --> 00:09:14,530
+لو كانوا ستة هكسوز طبعا هذه كلها اللي موجودة عندنا
+
+98
+00:09:14,530 --> 00:09:20,150
+لأن الجزء الأول فيها الديهيد they are all doses طب
+
+99
+00:09:20,150 --> 00:09:25,830
+لو كان فيها كيتون برضه هذا تتروز وبنتوز وهكسوز لكن
+
+100
+00:09:25,830 --> 00:09:31,590
+هذه ايش كيتوز واضح؟ الان كل واحد هياخد اسم تفصيلي
+
+101
+00:09:31,590 --> 00:09:36,490
+بس بشكل عام ممكن السكر يكون من تلات ذرات من أربعة
+
+102
+00:09:36,490 --> 00:09:41,610
+من خمسة من ستةيعني هدولة خلينا نقول الاش المشهورين
+
+103
+00:09:41,610 --> 00:09:48,410
+الآن لو بدنا نتطلع في ال sugars و اتطلعنا على أبسط
+
+104
+00:09:48,410 --> 00:09:54,770
+واحد فيهم ال glyceraldehyde ع طول هنلاحظ أن هذا ال
+
+105
+00:09:54,770 --> 00:10:00,310
+glyceraldehyde فيه chiral center يعني لو اتطلعنا
+
+106
+00:10:00,310 --> 00:10:03,210
+ال C double bond OH اللي هو جزء ال aldehyde هذا
+
+107
+00:10:03,210 --> 00:10:06,090
+مافيش فيه chiral center ال chiral center أربع
+
+108
+00:10:06,090 --> 00:10:12,980
+مجموعاتمختلفة، الآن ال CH2OH الأخيرة مافيها chiral
+
+109
+00:10:12,980 --> 00:10:19,460
+center، الكاربون الوسطني هاديفيها chiral center
+
+110
+00:10:19,460 --> 00:10:22,940
+الكربون الوسطاني اللي موجود عندنا فيها chiral
+
+111
+00:10:22,940 --> 00:10:28,920
+center الآن لاحظوا معي انه في ال sugars في ال
+
+112
+00:10:28,920 --> 00:10:34,760
+sugars هذه جزيئات شوية كبيرة وكل واحد ممكن يرسمها
+
+113
+00:10:34,760 --> 00:10:38,880
+بطريقة معينة يعني واحد ممكن يرسم واقف نايم مائل
+
+114
+00:10:38,880 --> 00:10:45,000
+عشان يسهلوا تبعون ال biochemistry على بعض المتابعة
+
+115
+00:10:45,000 --> 00:10:52,080
+اتفقواإنه يوحدوا طريقة الرسم، يعني ليش أضلني أتعب
+
+116
+00:10:52,080 --> 00:10:55,680
+الطالب مرة أحط مجموعة الالديهايد يمين، مرة شمال،
+
+117
+00:10:55,680 --> 00:10:59,820
+مرة فوق، مرة تحت، بره أرسم الجزء مائل، في كل لحظة
+
+118
+00:10:59,820 --> 00:11:04,670
+هو بيصير بحاجة إلىمزيد من التفكير و من الوقت عشان
+
+119
+00:11:04,670 --> 00:11:10,530
+يفهم إيش شكل الجزء فقالوا إيش المانع؟ إيش المانع؟
+
+120
+00:11:10,530 --> 00:11:15,910
+إن نوحد طريقة الرسم لما نرسم ال sugars بدل ما كل
+
+121
+00:11:15,910 --> 00:11:18,650
+واحد يرسمه بطريقة معينة و نقعد نقول وين ال
+
+122
+00:11:18,650 --> 00:11:22,350
+aldehyde وين ال OHS وين ال chiral center ليش ما
+
+123
+00:11:22,350 --> 00:11:29,310
+نرسم بطريقة موحدة؟بنسهل على الناس تمام؟ طيب إيش
+
+124
+00:11:29,310 --> 00:11:33,910
+فكرة الرسم بالطريقة الموحدة؟ جال خلّي المجموعة
+
+125
+00:11:33,910 --> 00:11:37,210
+اللي هي الكبيرة ال carbon اللي حاملة أعلى إشي اللي
+
+126
+00:11:37,210 --> 00:11:42,630
+هي ال aldehyde تكون لفوق و ارسم بهذا الشكل العمودي
+
+127
+00:11:42,630 --> 00:11:46,950
+واضح؟ يعني نخلي مجموعة ال aldehyde أو ال keto اللي
+
+128
+00:11:46,950 --> 00:11:54,970
+وجدت لأعلى و بنرسم بشكل عموديطبعا اخر شئ هنا هيكون
+
+129
+00:11:54,970 --> 00:12:03,090
+عندى CH2OH الان ايش ضال عندى على الوسط OH OH ضال
+
+130
+00:12:03,090 --> 00:12:09,030
+عندى في الوسط OH OH هذه ال OH OH بالتأكيد طالما
+
+131
+00:12:09,030 --> 00:12:14,830
+هذا chiral center هيكون فيه الجزئ و صورتهفى
+
+132
+00:12:14,830 --> 00:12:18,490
+المراية حيكون عند الجزء و صورته فى المراية لو
+
+133
+00:12:18,490 --> 00:12:22,630
+جربنا ان نشوف ال configuration إيه لو جربنا نشوف
+
+134
+00:12:22,630 --> 00:12:29,390
+ال configuration إيه هتتذكروا ان هذه أقل مجموعة و
+
+135
+00:12:29,390 --> 00:12:33,570
+ال oxygen أعلى مجموعة بعدين الكاربون اللى متصل
+
+136
+00:12:33,570 --> 00:12:37,490
+مرتين بال oxygen بعدها بعدين الكاربون اللى متصل
+
+137
+00:12:37,490 --> 00:12:41,830
+مرة بال oxygen وبناء على ذلك لو أنا بدي أمشي هى
+
+138
+00:12:41,830 --> 00:12:50,270
+نمره واحدنمرة اتنين، نمرة تلاتة، مبينة كإنها S،
+
+139
+00:12:50,270 --> 00:12:54,830
+لكن لأن هذه المجموعة الصغيرة للأمام، بنعكس ال
+
+140
+00:12:54,830 --> 00:13:01,270
+configuration، إذن هذا Rوبالتجربة ال R طلع بلس
+
+141
+00:13:01,270 --> 00:13:04,390
+بتذكرين لما قولنا ال plus و ال minus هذا من قصة
+
+142
+00:13:04,390 --> 00:13:09,330
+بالتجربة بال بولاريمتر الآن هذا بالتأكيد ال
+
+143
+00:13:09,330 --> 00:13:13,490
+enantiomer التاني هو ال S فبناء على ذلك ال
+
+144
+00:13:13,490 --> 00:13:19,650
+glyceraldehyde طالما في one chiral center إذا في
+
+145
+00:13:19,650 --> 00:13:27,060
+منه كام مركب اتنين R و Sالان تابعون ال
+
+146
+00:13:27,060 --> 00:13:32,020
+biochemistry قالوا احنا بنحب الخصوصية مش حابين
+
+147
+00:13:32,020 --> 00:13:36,580
+نظلنا مربوطين في جماعة الكيميا طب ليش يا عم
+
+148
+00:13:36,580 --> 00:13:41,800
+بتزيدوا غلبتنا قال بهمش الطلاب بتحملونا ايش اللي
+
+149
+00:13:41,800 --> 00:13:48,740
+بدكمياه قال بدل ما نستعمل ال R و ال S نستعمل D و L
+
+150
+00:13:50,330 --> 00:13:54,210
+هما لو ضالوا على ال R و ال S العلم بيمشي لكن قرروا
+
+151
+00:13:54,210 --> 00:13:59,650
+انهم بيستعملوا D و L الآن ضمن هذا الشكل اللي رسمنا
+
+152
+00:13:59,650 --> 00:14:02,450
+فيه يعني المجموعة هذه ال الدياد أو ال keto اللي
+
+153
+00:14:02,450 --> 00:14:07,630
+فوق قالوا إذا كانت ال OH على ال carbon اللي هي قبل
+
+154
+00:14:07,630 --> 00:14:10,770
+الأخيرة منها يعني هي أخر carbon من تحتها دي اللي
+
+155
+00:14:10,770 --> 00:14:16,010
+قبلها إذا كانت ال OH على اليمين بنعطي للمركب الرمز
+
+156
+00:14:16,500 --> 00:14:22,460
+وإذا كانت الـ OH على الشمال بنعطي المركب الرمز L
+
+157
+00:14:22,460 --> 00:14:27,540
+فصيرنا نقول هذا دي إجليسرال ديهيد وهال و هذا
+
+158
+00:14:27,540 --> 00:14:33,000
+الإجليسرال ديهيد الآن هم ركزوا على أي كاربون
+
+159
+00:14:33,000 --> 00:14:38,980
+تحديدا حاملة الـ OHالـ OH اللي جابلي الأخيرة، ليش؟
+
+160
+00:14:38,980 --> 00:14:42,820
+لأنه بعد شوية .. بعد شوية حيصير عندى أكثر من
+
+161
+00:14:42,820 --> 00:14:47,580
+Carbon بتحمل OH OH OH OH و أكثر من chiral center
+
+162
+00:14:47,580 --> 00:14:52,680
+مين فيهم اللي بدي أوصفه أنه D أو L؟ وين بدي أطلع؟
+
+163
+00:14:52,680 --> 00:14:56,940
+بدي أطلع مش على آخر Carbon، آخر Carbon مش chiral
+
+164
+00:14:56,940 --> 00:15:02,660
+أول Carbon chiral من تحت، اللي هي نمرة 2، لأن هو
+
+165
+00:15:02,660 --> 00:15:08,570
+اللي مش chiralواضح فلما انا بدي بعد شوية اصير اطلع
+
+166
+00:15:08,570 --> 00:15:15,310
+هيك على شكله و اقول هذا D ولا L بدي اطلع وين من
+
+167
+00:15:15,310 --> 00:15:23,190
+التحت طبعا هنا في عندي scheme كيف ببدأ انا ازيد في
+
+168
+00:15:23,190 --> 00:15:28,070
+مجموعات ال OH يعني اول ما بدأت تلاتة بعد هيك ببدأ
+
+169
+00:15:28,070 --> 00:15:34,930
+ازيد واضح انه هذا ال scheme يمكناضعيف جدا و لذلك
+
+170
+00:15:34,930 --> 00:15:41,230
+انا حاولت ان اجزء هذا ال scheme لأشياء لعلها تكون
+
+171
+00:15:41,230 --> 00:15:47,490
+أوضح لاحظوا معي بالنسبة لل glyceral dehyd هي ال OH
+
+172
+00:15:47,490 --> 00:15:52,200
+هنا على اليمين اذا انا جيبت بس منه ايش؟الـ D
+
+173
+00:15:52,200 --> 00:15:57,540
+-Glyceraldehyde الان يا ترى لو بدى ازيد كربون تانى
+
+174
+00:15:57,540 --> 00:16:03,280
+على ال D-Glyceraldehyde وين بدى اجي احطها؟ بهذا
+
+175
+00:16:03,280 --> 00:16:14,060
+الموقع واضح؟ هذه الكربون حاملةوح وح وح
+
+176
+00:16:14,060 --> 00:16:16,620
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+177
+00:16:16,620 --> 00:16:16,620
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+178
+00:16:16,620 --> 00:16:16,900
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+179
+00:16:16,900 --> 00:16:21,200
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+180
+00:16:21,200 --> 00:16:25,800
+وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+181
+00:16:25,800 --> 00:16:25,800
+وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح وح
+
+182
+00:16:25,800 --> 00:16:25,920
+وح وح وح وح وح وح وح وح وح وح وح
+
+183
+00:16:36,210 --> 00:16:40,270
+D لكن انا ال carbon اللي زيدتها في الوسط اللي الآن
+
+184
+00:16:40,270 --> 00:16:43,350
+بعلم عليها بالأحمر اللي هو ال chiral center التاني
+
+185
+00:16:43,350 --> 00:16:49,430
+مرة حطيت فيه ال OH علي اليمين و مرة حطيت فيه ال OH
+
+186
+00:16:49,430 --> 00:16:54,990
+علي الشمال بناء على ذلك لما انا زيدت من تلت ذرات
+
+187
+00:16:54,990 --> 00:17:01,630
+لاربع ذرات من ال D اعملت كام مركب اتنين طب لو
+
+188
+00:17:01,630 --> 00:17:07,900
+أخدنا الجزء التاني اللي هو ال Lهتكون ال OH هذه على
+
+189
+00:17:07,900 --> 00:17:11,820
+اليسار و هزيد واحدة مرة يمين و مرة شمال برضه هعمل
+
+190
+00:17:11,820 --> 00:17:19,400
+ايش؟ اتنين واضح؟ اذا كام مركب صار عندي من الاربع
+
+191
+00:17:19,400 --> 00:17:23,280
+ذرات كربون اللي هو two chiral centers؟ اربع احنا
+
+192
+00:17:23,280 --> 00:17:30,700
+أخدنا انهعدد الـ Stereoisomers 2 to the N فلما كان
+
+193
+00:17:30,700 --> 00:17:35,300
+عندي one chiral center كان عندي مركبين اللي هو الـ
+
+194
+00:17:35,300 --> 00:17:39,740
+D-glyceraldehyde و الـ L-glyceraldehyde طب الآن
+
+195
+00:17:39,740 --> 00:17:42,680
+لما زيدت كمان chiral center، one chiral center و
+
+196
+00:17:42,680 --> 00:17:47,170
+one chiral centerصار عندى كام مُركّب؟ أربعة شومة
+
+197
+00:17:47,170 --> 00:17:51,770
+الأربعة في عندى هذا المُركّب لأن هذه الـ OH أول
+
+198
+00:17:51,770 --> 00:17:57,210
+واحدة كيرال من تحت على اليمين دي بسميه D-erythrose
+
+199
+00:17:58,950 --> 00:18:03,570
+تمام؟ و لأن الـ OH هذه على الشمال بيصير مركّب تاني
+
+200
+00:18:03,570 --> 00:18:09,070
+طبعا هذه طالما علي اليمين هتعطيني كلمة إيش؟ D دي
+
+201
+00:18:09,070 --> 00:18:14,070
+هذا بسميه Ethreose فصار في عندي مركّب اسمه D
+
+202
+00:18:14,070 --> 00:18:20,410
+-Erythrose و مركّب اسمه D-Ethreose ال Erythrose زي
+
+203
+00:18:20,410 --> 00:18:24,570
+ما بتلاحظوا اللي موجودة فيه الـ OH التاني على
+
+204
+00:18:25,670 --> 00:18:31,110
+اليمين والثريوز اللي موجودة فيه هذه على اليسار طب
+
+205
+00:18:31,110 --> 00:18:36,720
+الأن وين المركبين التانيين؟الـ L اللي هم الـ L لما
+
+206
+00:18:36,720 --> 00:18:40,320
+بدي الـ L شو بدي أعمل بهدي؟ بدي أعكسها يعني أنا
+
+207
+00:18:40,320 --> 00:18:45,060
+هنا جايب نص الصورة جايب ال D زي ما فيه D بتاخدوا
+
+208
+00:18:45,060 --> 00:18:49,880
+نفس الجزيه تماما و بس بنعكس منه إيش الـ OH الـ OH
+
+209
+00:18:49,880 --> 00:18:55,720
+الخضرة أول واحدة كايرال من تحت طبعا هي بتكون تاني
+
+210
+00:18:55,720 --> 00:18:59,780
+واحدة لإن هذه مش كايرال هي أول واحدة كايرال من تحت
+
+211
+00:19:01,360 --> 00:19:06,880
+واضح الفكرة؟ الآن اتخيلوا من هدول الاتنين لو بدى
+
+212
+00:19:06,880 --> 00:19:12,040
+ازيد كمان ذرة carbon يعني اخليهم بدل اربعة خمسة
+
+213
+00:19:12,040 --> 00:19:20,280
+وين هازيد ذرة ال carbon هادي؟ هنا الان من هذه لما
+
+214
+00:19:20,280 --> 00:19:26,720
+بدى ازيد واحدة هنا وين هتيجي؟يا يمين، يا شمال، يا
+
+215
+00:19:26,720 --> 00:19:29,980
+شمال،
+
+216
+00:19:29,980 --> 00:19:37,580
+يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا
+
+217
+00:19:37,580 --> 00:19:42,640
+شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا شمال،
+
+218
+00:19:42,640 --> 00:19:45,500
+يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا
+
+219
+00:19:45,500 --> 00:19:46,080
+شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا شمال،
+
+220
+00:19:46,080 --> 00:19:46,080
+يا شمال، يا شمال، يا شمال، يا شمال، يا شمال، يا
+
+221
+00:19:46,080 --> 00:19:52,290
+شمال، يا شمالتمانية اتنين اقصد تلاتة تمانية الان
+
+222
+00:19:52,290 --> 00:19:56,950
+لو بدنا نتعرف عليهم نتعرف على نصهم اللي هم جايين
+
+223
+00:19:56,950 --> 00:20:02,710
+من وين من ال D هاي المركب ال D اللي توي رسمناه
+
+224
+00:20:02,710 --> 00:20:09,850
+طالما هذي على اليمين اذا هذا D صحيح الان بدي ازيد
+
+225
+00:20:09,850 --> 00:20:17,330
+كمان هذا الرباعي لأ هذا صار الخماسي حط هذه وين مرة
+
+226
+00:20:18,610 --> 00:20:25,130
+يمين مرة شمال، الآن هذول أعطاهم أسماء، شو أعطاهم؟
+
+227
+00:20:25,130 --> 00:20:31,490
+دي رايبوز وهذا دي أرابينوز، ليش دي؟ لأنه هذي
+
+228
+00:20:31,490 --> 00:20:36,690
+عاليمين، الآن بنصير نقول شو هو الرايبوز؟ الرايبوز
+
+229
+00:20:36,690 --> 00:20:40,790
+السكر الخماسي اللي تلت مجموعات ال OH في جين ع جهة
+
+230
+00:20:40,790 --> 00:20:46,690
+واحدةالان الارابينوز الشو هو السكر الخماسي اللى
+
+231
+00:20:46,690 --> 00:20:50,930
+هدولة بتنتنع جهة وادي على جهة تانية لحظوا قاعدة
+
+232
+00:20:50,930 --> 00:20:57,170
+بتكتر المراكبات عندى هذا خمس درات كربون واحد اتنين
+
+233
+00:20:57,170 --> 00:21:02,690
+تلاتة اربعة خمسة بكم chiral center تلاتة طالما
+
+234
+00:21:02,690 --> 00:21:07,410
+عندى تلاتة chiral center اذا كم مركب تمانية وين
+
+235
+00:21:07,410 --> 00:21:16,070
+التمانية4D و 4R بالظبط واضحة؟
+
+236
+00:21:16,070 --> 00:21:22,770
+انا هنا بس أخدت الاريثروز و جسمته يتبعوا معاك هذا
+
+237
+00:21:22,770 --> 00:21:28,590
+بس اللي نتج من الاريثروز لما أجسم للثريوز بيعطيني
+
+238
+00:21:28,590 --> 00:21:35,410
+كمان اتنين اتنين و اتنين اربع اربع و هكذا واضح؟
+
+239
+00:21:35,410 --> 00:21:36,430
+هاي للثريوز
+
+240
+00:21:40,860 --> 00:21:44,360
+خلّينا هذا اللي اتعودنا نقول عنه دي نخليه باللون
+
+241
+00:21:44,360 --> 00:21:48,780
+الأخضر هذا السكر التالي الاثريوز مش احنا قولنا
+
+242
+00:21:48,780 --> 00:21:57,060
+الاريثروز و الاثريوز الاريثروز بيقسم لاتنين هايهم
+
+243
+00:21:57,060 --> 00:22:01,760
+و الاثريوز بيقسم لاتنين تانين الان الاتنين اللي
+
+244
+00:22:01,760 --> 00:22:05,820
+بيقسملهم الاثريوز بياخدوا اسم اكزايلوز و لاكزوز
+
+245
+00:22:07,610 --> 00:22:13,030
+فصار المجموع من الخماسي اربعة D و اربعة L كده؟
+
+246
+00:22:13,030 --> 00:22:19,030
+تمانية لو جينا اي واحد من هدولة بدنا نزيد له
+
+247
+00:22:19,030 --> 00:22:25,250
+chiral center هيقسم لإيش؟ لاتنين طالما وما تمانية
+
+248
+00:22:25,250 --> 00:22:29,290
+كل واحد يقسم لاتنين هيصير المجموع ستة عشر كلام
+
+249
+00:22:29,290 --> 00:22:32,650
+منطقي ليش؟ لأنه لما يصير عند اربعة chiral centers
+
+250
+00:22:32,650 --> 00:22:39,090
+اتنين اقص اربعة16 16 اتنين اقصى اربعة ستة عشر فلما
+
+251
+00:22:39,090 --> 00:22:43,230
+نيجي نتعرف عليهم لما نيجي نتعرف عليهم لو أخدنا
+
+252
+00:22:43,230 --> 00:22:49,250
+مثلا الريبوز هاي ال O H هذه العملة دي و زيدنا
+
+253
+00:22:49,250 --> 00:22:53,690
+كايرة ال center وين هنا
+
+254
+00:22:53,690 --> 00:23:01,730
+هذا هيعمل O H مرة يمين و مرة شمال
+
+255
+00:23:03,120 --> 00:23:07,240
+لو أخدنا الأرابينوز برضه وين بدنا نزيد الـ OH؟
+
+256
+00:23:07,240 --> 00:23:14,580
+هنا، هتيجي مرة يمين و مرة شمال، الآن هدولة بنبدأ
+
+257
+00:23:14,580 --> 00:23:19,980
+نعطيهم أسماء اللي كلهم جايين زي بعض سموه ألوز، هذا
+
+258
+00:23:19,980 --> 00:23:25,360
+تلاتة و بعدين واحدة زي بعض ألتروز، هذا الجولوكوز
+
+259
+00:23:25,360 --> 00:23:31,300
+صاحبنا، اللي بدأ تحفظ الجولوكوزيعني منهم كلهم بدنا
+
+260
+00:23:31,300 --> 00:23:34,860
+نقولكوا بس احفظوا الجولوكوز كيف ترتيب مجموعاته
+
+261
+00:23:34,860 --> 00:23:39,960
+طبعا اللي بدها تحفظ الجولوكوز بدها تقولوا one and
+
+262
+00:23:39,960 --> 00:23:44,440
+six carbonate صحيح؟ الآن الـC double bond OH
+
+263
+00:23:44,440 --> 00:23:51,400
+الالديهيد هذه لفوق أكيد مافيها نقاش والـCH2OH هذه
+
+264
+00:23:51,400 --> 00:23:59,040
+لتحت أكيد ولا فيها نقاش؟ الآن لو قلنا Dجولوكوز،
+
+265
+00:23:59,040 --> 00:24:03,900
+إيش معناه دي؟ إنه هذه لازم تكون على اليمين، الآن
+
+266
+00:24:03,900 --> 00:24:08,080
+في دي جولوكوز، بعد ما نحط هذه على اليمين، ضال عنده
+
+267
+00:24:08,080 --> 00:24:16,960
+يمين شمال يمين، ولو كنا جايلين الجولوكوز، هتخلوا
+
+268
+00:24:16,960 --> 00:24:22,200
+هذه تيجي هنا والباقي زي ما هوواضح؟ يعني اللي بيغير
+
+269
+00:24:22,200 --> 00:24:25,660
+دي و قل هذه المجموعة، هذه يمين دي، لو قلتلكوا بدي
+
+270
+00:24:25,660 --> 00:24:31,560
+القل جولوكوز، خدوا هذا الـD و غيروا بس هذه، إذا
+
+271
+00:24:31,560 --> 00:24:36,520
+كانت هذه يمين، دي جولوكوزة، الآن الخلاصة بهذا
+
+272
+00:24:36,520 --> 00:24:44,240
+الشكل، كم sugar طلع عنده؟16 16 sugar و الكلام
+
+273
+00:24:44,240 --> 00:24:49,740
+منطقي ليش من ال 6 كربونات لأن ال 6 كربونات فيهم 4
+
+274
+00:24:49,740 --> 00:24:55,760
+chiral centers و المركب مش symmetric 2 أس 4 16
+
+275
+00:24:55,760 --> 00:25:02,220
+الان لو بدنا هدولا ال 16 ناخد أسماءهم هاي أربعة
+
+276
+00:25:02,220 --> 00:25:06,020
+منهم الألوز و الألتروز و الجولوكوز و المانوز و لو
+
+277
+00:25:06,020 --> 00:25:12,140
+أخدنا الأربعة التانين اللي في الأساس جوا منالثريوز
+
+278
+00:25:12,140 --> 00:25:16,660
+الجولوز والأيدوز والجالاكتوز والتالوز الآن هذول
+
+279
+00:25:16,660 --> 00:25:21,460
+تمانية ايش التمانية التانية كل هذول التمانية دي
+
+280
+00:25:21,460 --> 00:25:30,640
+التمانية التانية ال ال واضح فبصف عندى ست عشر مركب
+
+281
+00:25:30,640 --> 00:25:37,340
+لل C6 لاحظوا معايا هذول الست عشر مركباخذين بعين
+
+282
+00:25:37,340 --> 00:25:42,040
+الاعتبار ان الجولوكوز بهذا الشكل موجود على شكل
+
+283
+00:25:42,040 --> 00:25:48,300
+فاتح مش مسكّر بعد شوية هانيجي نعمل ال cyclic sugar
+
+284
+00:25:48,300 --> 00:25:51,940
+يعني نخليه يسكّر على بعضه كيف بده يسكّر على بعضه
+
+285
+00:25:51,940 --> 00:25:55,340
+احنا لما شرحنا ال aldehyde قولنا لكم في عندي OH
+
+286
+00:25:55,340 --> 00:25:59,980
+وفي عندي aldehyde الكحول بتفعل مع ال aldehyde
+
+287
+00:25:59,980 --> 00:26:04,790
+يعطيني hemiacetalأخدناها كمثال فبنخلّي هذه تسكّر
+
+288
+00:26:04,790 --> 00:26:10,310
+هنا لو هذه سكّرت هنا هنعمل ال Cairo Center الخامس
+
+289
+00:26:10,310 --> 00:26:14,930
+وقت كام ايزومار حيصير عندى اذا صاروا خمس Cairo
+
+290
+00:26:14,930 --> 00:26:22,010
+Centers اتنين اص خمسة ايش اتنين اص خمسة اتنين
+
+291
+00:26:22,010 --> 00:26:28,310
+وتلاتين ايزومار واضح اتنين وتلاتين ايزومار هيكون
+
+292
+00:26:28,310 --> 00:26:39,230
+عندكم من ال C6من 6 ذرات كربون لاحظوا كم هو استيريو
+
+293
+00:26:39,230 --> 00:26:42,870
+كيميستر مهم يعني حد ما درسش استيريو كيميستر عمره
+
+294
+00:26:42,870 --> 00:26:48,360
+ممكن يستوعب موضوعالـ sugars مستحيل وهذا الكلام
+
+295
+00:26:48,360 --> 00:26:51,940
+اللي تقريبا احنا كنا حاطينه في ال scheme العام كنا
+
+296
+00:26:51,940 --> 00:26:57,380
+حاطين لكم كيف الزيادة one chiral center تمام
+
+297
+00:26:57,380 --> 00:27:01,660
+بيكونوا تنين أخدت واحد منهم اعملتله زيادة chiral
+
+298
+00:27:01,660 --> 00:27:06,150
+صاروايعني هن واحد و في واحد تاني موجود يعني لو حد
+
+299
+00:27:06,150 --> 00:27:09,690
+بده يحط ال scheme كاملا بده يجد هذا ال scheme و
+
+300
+00:27:09,690 --> 00:27:12,310
+يحط واحد تاني ليش؟ لأنه انا هن بدت بال D
+
+301
+00:27:12,310 --> 00:27:17,870
+-Glyceraldehyde فيه زيه ال glyceraldehyde و بيقسم
+
+302
+00:27:17,870 --> 00:27:24,430
+بنفس الشكل و بياخد نفس الأسماء طبعا لاحظوا معي أن
+
+303
+00:27:24,430 --> 00:27:29,740
+الأسماء الأساسية الأسماء الأساسية كام اسمتمانية
+
+304
+00:27:29,740 --> 00:27:36,860
+الأسماء الأساسية تمانية اللي هي موجودين
+
+305
+00:27:36,860 --> 00:27:40,560
+عندكم الالوز والألتروز والجولوكوز والمانوز وكذا
+
+306
+00:27:40,560 --> 00:27:47,020
+كذا الآن كيف التمانية بيصيروا الست عاشر طبعا
+
+307
+00:27:47,020 --> 00:27:51,120
+هذا الكلام بإمكانكم أنتم تجلسوا تتدربوا عليه
+
+308
+00:27:51,120 --> 00:27:58,200
+تقرؤوا زي ما قلنا مش ضروري أننا بدنا نحفظهالان لسه
+
+309
+00:27:58,200 --> 00:28:03,880
+الكيميائيين ما شبعوش يعني وصلوكوا ل 16 مركب و بدهم
+
+310
+00:28:03,880 --> 00:28:11,550
+ايش؟وبدهم اكتر قالوا طالما ان السكر فيه OH وفيه
+
+311
+00:28:11,550 --> 00:28:16,050
+الديهايد يعني الكحول و الديهايد نرجع لكيمية ال
+
+312
+00:28:16,050 --> 00:28:20,790
+الديهايد ماش كنا نقول ان ال الديهايد بيعمل تفاعل
+
+313
+00:28:20,790 --> 00:28:26,050
+addition مع الكحولات وبيعطيني hemiacetal ال OH
+
+314
+00:28:26,050 --> 00:28:32,420
+بتهاجم علىالـ C double bond O تبعت ال الديهايد
+
+315
+00:28:32,420 --> 00:28:39,080
+بتخليها OH متذكرينه التفاعل ولا نذكر فيه الناس
+
+316
+00:28:39,080 --> 00:28:43,340
+اللي مش متذكرينه التفاعل نكتبها لما كنا نقول مثلا
+
+317
+00:28:43,340 --> 00:28:51,840
+Methanol مثل OH هي نرسمه بالأسود زائد CH3C double
+
+318
+00:28:51,840 --> 00:29:00,510
+bond OH هي الكحول وهي إيش؟الالديهيد هذه الكحول
+
+319
+00:29:00,510 --> 00:29:05,190
+وهذه الالديهيد لو قلنا لكوا في الامتحان اكمل هذه
+
+320
+00:29:05,190 --> 00:29:08,910
+المعادلة كيف بتفعل الكحول و الالديهيد مش هذا
+
+321
+00:29:08,910 --> 00:29:14,550
+نيوكليوفاين بيعمل addition بيجي بها جمهان وهذا
+
+322
+00:29:14,550 --> 00:29:22,690
+بتصير OH وبناء على ذلك هيكون الناتج CH3C
+
+323
+00:29:22,690 --> 00:29:29,250
+هذا صفية OH وهذا ال H الأصلية وإيجي عندنا من هناو
+
+324
+00:29:29,250 --> 00:29:34,870
+مثل هذا شو سمنا Himacetal Himacetal Himacetal
+
+325
+00:29:34,870 --> 00:29:39,790
+Himacetal
+
+326
+00:29:39,790 --> 00:29:44,810
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+327
+00:29:44,810 --> 00:29:45,610
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+328
+00:29:45,610 --> 00:29:45,770
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+329
+00:29:45,770 --> 00:29:45,810
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+330
+00:29:45,810 --> 00:29:45,810
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+331
+00:29:45,810 --> 00:29:45,890
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+332
+00:29:45,890 --> 00:29:45,890
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+333
+00:29:45,890 --> 00:29:45,890
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+334
+00:29:45,890 --> 00:29:47,790
+Himacetal Himacetal Himacetal Himacetal Himacetal
+
+335
+00:29:47,790 --> 00:29:55,530
+Himacetal Himacetal Himacetal
+
+336
+00:29:55,530 --> 00:30:07,430
+Himacetal HimacetHemiacetal OR و OR أسيتال، الآن
+
+337
+00:30:07,430 --> 00:30:12,770
+السكر فيه OH و فيه الديهايد، إيش المانع إنهم
+
+338
+00:30:12,770 --> 00:30:19,560
+يسكروا على بعض؟فيش مانع، وعشان هيك بيصير بيعمل
+
+339
+00:30:19,560 --> 00:30:23,580
+الشكل الحلقي، بنفس منطقة هذا التفاعل، يعني هذا
+
+340
+00:30:23,580 --> 00:30:28,440
+تفاعل تذكير كيف كان الكحول يتفاعل مع إيش؟ مع ال
+
+341
+00:30:28,440 --> 00:30:35,450
+الديهيد، الآن بدنا نرجع لهمفي السكر بدا نرجع للسكر
+
+342
+00:30:35,450 --> 00:30:41,710
+و نشوف كيف بتم هذا التفاعل هاي السكر بنرسمه بشكل
+
+343
+00:30:41,710 --> 00:30:46,070
+ملتوى خليكوا تطلعوا معنا هاي ال الديهايد C double
+
+344
+00:30:46,070 --> 00:30:50,430
+bond O و بعدين carbon حاملة OH و carbon حاملة OH و
+
+345
+00:30:50,430 --> 00:30:56,150
+carbon حاملة OH و هذه اللي هي ال carbon اللي كانت
+
+346
+00:30:56,150 --> 00:31:00,710
+معطية ال D اللي هي القبل الأخيرة
+
+347
+00:31:06,670 --> 00:31:14,590
+الان من ناحية المبدأ كل OH من هدوله ممكن تسكر على
+
+348
+00:31:14,590 --> 00:31:19,780
+ال الديهايديعني نظرياً هذه الـ OH ممكن تسكر على ال
+
+349
+00:31:19,780 --> 00:31:23,320
+الديهاد تعطينا حلقة ثلاثية، هذه ممكن تسكر على ال
+
+350
+00:31:23,320 --> 00:31:26,600
+الديهاد تعطينا حلقة رباعية، هذه ممكن تسكر على
+
+351
+00:31:26,600 --> 00:31:30,260
+الديهاد تعطينا حلقات خماسية، هذه ممكن تسكر تعطينا
+
+352
+00:31:30,260 --> 00:31:35,020
+حلقة سداسية، هذه ممكن تسكرتعطي حلقة سباعية لكن
+
+353
+00:31:35,020 --> 00:31:41,200
+أشهر إغلاق اللي بيعطي الحلقة السداسية فال OH اللي
+
+354
+00:31:41,200 --> 00:31:45,600
+بتسكر في حالة الجولوكوز هي ال OH اللي كانت تتحدد
+
+355
+00:31:45,600 --> 00:31:50,620
+ال D والL ال OH هذه اللي جاب للاخيرة الآن هذه بدأ
+
+356
+00:31:50,620 --> 00:31:56,400
+تيجي تسكر هناهيصير عندى كايرال سنتر جديد يعنى هذه
+
+357
+00:31:56,400 --> 00:32:01,420
+ال carbon هتعمل ايش كايرال سنتر جديد طب انا فى
+
+358
+00:32:01,420 --> 00:32:08,060
+الأساس كام كايرال سنتر عندى هى واحد اتنين تلاتة
+
+359
+00:32:08,060 --> 00:32:14,440
+اربعة ولمّا اجى اعمل هنا الإغلاق هيصيروا ايش خمسة
+
+360
+00:32:15,390 --> 00:32:20,530
+هيصيروا خمسة chiral centers وبناء على ذلك لاحظوا
+
+361
+00:32:20,530 --> 00:32:25,890
+معاه ان هدولة اللي هم ابعد عن التفاعل بيظلوا زي ما
+
+362
+00:32:25,890 --> 00:32:29,730
+هم لكن انا بدي اعمل generation لل chiral center
+
+363
+00:32:29,730 --> 00:32:33,830
+على هذا الكربون تحديدا بناء على ذلك لما بعمل
+
+364
+00:32:33,830 --> 00:32:37,490
+generation لل chiral center على هذا الكربون ايش
+
+365
+00:32:37,490 --> 00:32:43,330
+بيصير عندى؟ two enantiomersمظبوط ولا لأ؟ الان
+
+366
+00:32:43,330 --> 00:32:48,470
+هدولة لما بدهم يتموه طبعا مش two enantiomers أقفل
+
+367
+00:32:48,470 --> 00:32:51,450
+two diastereomers ليش؟ لأن أنا مش generation of
+
+368
+00:32:51,450 --> 00:32:55,860
+the first chiral centerاحنا قولنا two enantiomars
+
+369
+00:32:55,860 --> 00:33:00,960
+in equal ratios لو كان ايش؟ اول chiral center بس
+
+370
+00:33:00,960 --> 00:33:04,700
+هل هذا هو اول chiral center ولا نمرخمسة؟ نمرخمسة
+
+371
+00:33:04,700 --> 00:33:09,580
+نمرخمسة لما بنعمل chiral center اشديد second,
+
+372
+00:33:09,940 --> 00:33:13,600
+third, fourth, fifth chiral center شو كان يطلع
+
+373
+00:33:13,600 --> 00:33:18,860
+عندنا؟ اللي جيبناها سؤال في الامتحان unequal
+
+374
+00:33:18,860 --> 00:33:24,720
+mixture of diastereomersمتذكرينه؟ generation of a
+
+375
+00:33:24,720 --> 00:33:28,400
+second chiral center of a third of a fourth chiral
+
+376
+00:33:28,400 --> 00:33:31,640
+center produces an equal mixture of diastereomers
+
+377
+00:33:31,640 --> 00:33:35,320
+الألم هنا بدنا نشوف كيف هذا بده يصير chiral center
+
+378
+00:33:35,320 --> 00:33:41,720
+الـC ضبط هو بده تصير OH هذه الـOH مرة هتكون للأعلى
+
+379
+00:33:41,720 --> 00:33:50,080
+و مرة هتكون للأسفل هم
+
+380
+00:33:50,080 --> 00:33:54,910
+لاحظين؟هي ال chiral center مرة لفوق و مرة لتحت
+
+381
+00:33:54,910 --> 00:34:03,250
+واضح الفكرة؟ الآن في هذا الجزء صار عنده اللي هو ال
+
+382
+00:34:03,250 --> 00:34:07,930
+chiral center الخامس لحظة أنا بدأت بأي سكر؟ ال
+
+383
+00:34:07,930 --> 00:34:11,590
+جولوكوز ال D جولوكوز الآن ال D جولوكوز أعطاني كم
+
+384
+00:34:11,590 --> 00:34:18,270
+مركب؟ اتنين طب أنا كل السكريات اللي اتعرفت عليهم
+
+385
+00:34:18,270 --> 00:34:25,650
+قداش كانواكانوا ستة عشر تمانية D و تمانية L إذا ال
+
+386
+00:34:25,650 --> 00:34:30,410
+D جولوكوز أعطى اتنين الستة عشر كل واحد فيهم هيعطي
+
+387
+00:34:30,410 --> 00:34:34,950
+اتنين اتنين اتنين اتنين اتنين اتنين بستة عشر اتنين
+
+388
+00:34:34,950 --> 00:34:39,280
+و تلاتين هي الاتنين و التلاتين I زمرواضح؟ الان
+
+389
+00:34:39,280 --> 00:34:42,660
+هدولة اللي جدوا عندنا اجداد جايين من الجولوكوز و
+
+390
+00:34:42,660 --> 00:34:46,860
+جايين تحديدا من اي جولوكوز؟ من ال D جولوكوز لما
+
+391
+00:34:46,860 --> 00:34:50,280
+بدنا نميزهم عن بعض انتوا بتقدروا تميزهم تقولوا
+
+392
+00:34:50,280 --> 00:34:57,260
+واحد في ال OH لفوق واحد في ال OH لتحت الان بلغة
+
+393
+00:34:57,260 --> 00:35:01,880
+الكيميا بنقول اللي بيطلع بهذا الشكل و ال OH لفوق
+
+394
+00:35:01,880 --> 00:35:08,090
+بنسميه beta و بنحط الاسم القديممن وين هذا جاي؟ من
+
+395
+00:35:08,090 --> 00:35:12,070
+D جولوكوز، فصار ده Beta D جولوكوز، يعني ال Beta
+
+396
+00:35:12,070 --> 00:35:21,490
+اللي هي لفوق، اه، وإذا كانت لتحت؟ Alpha D جولوكوز،
+
+397
+00:35:21,490 --> 00:35:27,460
+واضح؟الان مرة تانية عشان تبعون ال biochemistry
+
+398
+00:35:27,460 --> 00:35:33,080
+اسهلوا على نفسهم هذه الحلقة السوداسية يمكن ان ترسم
+
+399
+00:35:33,080 --> 00:35:37,660
+بإيش بطرق كتير مختلفة يعني ممكن تخلوا ال oxygen
+
+400
+00:35:37,660 --> 00:35:42,380
+هان هان هان اعتادوا انهم يرسموها بهذا الشكل اللي
+
+401
+00:35:42,380 --> 00:35:47,920
+موجود أمامكم يعني بدكوا ترسموها حلقة سوداسية بهذا
+
+402
+00:35:47,920 --> 00:35:52,680
+الشكل وتجددوا انكوا تحطوا ال oxygen وين؟ع هذا
+
+403
+00:35:52,680 --> 00:35:58,660
+الموقع وبناء على ذلك واجتها بنقول ان الكاربون اللي
+
+404
+00:35:58,660 --> 00:36:03,320
+ماكنتش كايرال سنتر وصارت كايرال سنتر هي اي كاربون؟
+
+405
+00:36:03,320 --> 00:36:09,600
+هذه عشان الناس مايتخربطوش بطريقة الرسم ترسم الحلقة
+
+406
+00:36:09,600 --> 00:36:14,140
+السوداسية عادة في ال biochemistry بهذا الشكل ال
+
+407
+00:36:14,140 --> 00:36:19,640
+oxygen اللي سكرت هي هان هذه الكاربون اللي كانت
+
+408
+00:36:20,700 --> 00:36:28,460
+الديهايد ماكنتش كايرال سنتر صارت كايرال سنتر واضح؟
+
+409
+00:36:28,460 --> 00:36:33,560
+هيهانة قبل ما يسكركانت كايران ولا لأ؟ لأ كان
+
+410
+00:36:33,560 --> 00:36:37,960
+المركب .. كم كايرال سنتر فيه؟ كانوا أربعة و هذه
+
+411
+00:36:37,960 --> 00:36:41,940
+زادت .. هايهم الكايرال سنتر الأربعة و هذه زادت
+
+412
+00:36:41,940 --> 00:36:47,260
+صاروا كدهش؟ خمسة واضح؟ الآن هذه الكاربون اللي
+
+413
+00:36:47,260 --> 00:36:52,440
+ماكنتش كايرال سنتر كانت الديهايد و صارت كايرال
+
+414
+00:36:52,440 --> 00:36:57,560
+سنتر إلها اسم بنسميها Anomeric Carbon
+
+415
+00:36:59,780 --> 00:37:05,500
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+416
+00:37:05,500 --> 00:37:07,800
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+417
+00:37:07,800 --> 00:37:08,020
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+418
+00:37:08,020 --> 00:37:10,440
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+419
+00:37:10,440 --> 00:37:12,440
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+420
+00:37:12,440 --> 00:37:12,540
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+421
+00:37:12,540 --> 00:37:12,540
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+422
+00:37:12,540 --> 00:37:12,540
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+423
+00:37:12,540 --> 00:37:12,540
+انوميرك كاربون انوميرك كاربون انوميرك كاربون
+
+424
+00:37:12,540 --> 00:37:16,080
+انوميرك كاربونالكاربون اللي عملت الكايرال سنتر
+
+425
+00:37:16,080 --> 00:37:20,660
+الجديد كانوا أربعة صاروا إيش؟ خمسة، مين اللي عملت
+
+426
+00:37:20,660 --> 00:37:24,960
+الكايرال سنتر الجديد؟ هذه تبعت ال الديهايد بسميها
+
+427
+00:37:24,960 --> 00:37:30,100
+Anomeric Carbon، الآن إذا الكايرال سنتر هذا الجديد
+
+428
+00:37:30,730 --> 00:37:36,350
+أجت فيه مجموعة الـ OH لأعلى بقول هذا Beta Sugar
+
+429
+00:37:36,350 --> 00:37:41,070
+وإذا أجت لأسفل Alpha Alpha بيضلوا ماخد نفس الاسم
+
+430
+00:37:41,070 --> 00:37:45,630
+اللي هو الـ D والجولوكوز اللي هو يعبر عن كل
+
+431
+00:37:45,630 --> 00:37:52,230
+الترتيبات هذه واضح؟ الآن طالما كانوا 16 وكل واحد
+
+432
+00:37:52,230 --> 00:37:59,750
+بدأ أعمل منهAlpha و Beta قداش حيصيروا 32 طبعا
+
+433
+00:37:59,750 --> 00:38:04,570
+بتكونوا منتبهين أن الأسماء الأساسية في ال sugars
+
+434
+00:38:04,570 --> 00:38:11,990
+قداش تمانية واضحة الفكرة الأسماء الأساسية اللي هي
+
+435
+00:38:11,990 --> 00:38:16,330
+جولوكوز و جولاكتوز و ألوز و ما إلى ذلك كام اسم
+
+436
+00:38:16,330 --> 00:38:20,750
+تمان أسماء يعني خليني أوضحلكوا الصورة مرة أخيرة
+
+437
+00:38:24,310 --> 00:38:29,390
+تمان أسماء أساسية الان هدولة تمان أسماء أساسية كل
+
+438
+00:38:29,390 --> 00:38:35,690
+اسم فيه منه D و L و بعد هيك كل اسم بيصير ايش فيه
+
+439
+00:38:35,690 --> 00:38:44,130
+منه Alpha هذا بيكون Alpha D و Beta D و هذا بيصير
+
+440
+00:38:44,130 --> 00:38:51,510
+منه Alpha L و Beta L واضح؟ هي هذا كده صفة منه؟
+
+441
+00:38:51,510 --> 00:38:58,660
+أربعةيعني لو قولنا من الجولوكوز الجولوكوز
+
+442
+00:38:58,660 --> 00:39:02,800
+واحد منهم في Alpha D جولوكوز و Beta D جولوكوز
+
+443
+00:39:02,800 --> 00:39:09,440
+Alpha L جولوكوز و Beta L جولوكوز و من كل واحد
+
+444
+00:39:09,440 --> 00:39:14,200
+موجودة نفسها للتقسيمة طالما تمان أسماء أساسية في
+
+445
+00:39:14,200 --> 00:39:23,300
+أربعرموز صفر العدد لكل جداش 32 سكر في حالة ما كان
+
+446
+00:39:23,300 --> 00:39:30,020
+السكر إيه اشماله؟ Cyclic لكن لو كان acyclic بس
+
+447
+00:39:30,020 --> 00:39:34,620
+بنصفة ال 16 لأنه ماعملناش ال chiral center الخامس
+
+448
+00:39:34,620 --> 00:39:39,100
+اللي هو ماهيكون جولوكوز D و L جلاكتوز D و L مانوز
+
+449
+00:39:39,100 --> 00:39:47,570
+D و L و هكذا إذا كان acyclicالسكر السداسي بيكون
+
+450
+00:39:47,570 --> 00:39:53,750
+العدد الكلي 16 وإذا كان Cyclic بيكون العدد الكلي
+
+451
+00:39:53,750 --> 00:40:00,490
+32 الآن في ال A Cyclic تمان أسماء كل واحد بيقسم D
+
+452
+00:40:00,490 --> 00:40:08,530
+و L في ال Cyclic كل D و كل L بتقسم إلى ألفة و بيتا
+
+453
+00:40:08,530 --> 00:40:12,550
+الان
+
+454
+00:40:12,550 --> 00:40:18,700
+انتبهوا معيقلنا احنا انه لما يتكون هذا الدياستيريو
+
+455
+00:40:18,700 --> 00:40:23,460
+مارس بيكونوا ب equal ratios ولا unequal ratios؟
+
+456
+00:40:23,460 --> 00:40:30,200
+unequal ratios الان اللي طلع عندنا حقيقة ان ال
+
+457
+00:40:30,200 --> 00:40:37,520
+beta بيطلع بنسبة 64% و ال alpha من الجولوكوس بيطلع
+
+458
+00:40:37,520 --> 00:40:45,380
+بنسبة 36% واضح؟طبعا ال beta لحاله له زاوية دوران
+
+459
+00:40:45,380 --> 00:40:51,420
+plus 19 و ال alpha لحاله لو فصلوا له زاوية دوران
+
+460
+00:40:51,420 --> 00:40:59,120
+112 الان لو حطيت الخليط تبعهم بطلع زاوية بين
+
+461
+00:40:59,120 --> 00:41:02,700
+التنتين ماخدة نسبة بعين الاعتبار الخليط بطلع
+
+462
+00:41:02,700 --> 00:41:10,450
+زاويته حقيقة 52لاحظوا معي، الآن هذا كله اتزان، هذا
+
+463
+00:41:10,450 --> 00:41:15,750
+كله ايش؟ اتزان، بمعنى، لو أنا بدأت في هذا الـA
+
+464
+00:41:15,750 --> 00:41:21,390
+Cyclic و سبته في المحلول، بعد يوم، ايش هلاجيك؟ في
+
+465
+00:41:21,390 --> 00:41:27,090
+نسبة جليلة من الـCyclic ضايلة، سكر لهذا و لهذا، و
+
+466
+00:41:27,090 --> 00:41:34,670
+بنسبة 64% إلى 36%، و بخليط الزاوية تبعتهنتأكد منها
+
+467
+00:41:34,670 --> 00:41:47,210
+بالظبط قداش 52 52 اللي هو الاش ال mixture الخليط
+
+468
+00:41:47,210 --> 00:41:51,460
+اللي من هذا و من هذاالـ A Cyclic له زاوية تانية
+
+469
+00:41:51,460 --> 00:41:55,920
+مالنا و ماله بحكي عن الـ mixture اللي من هذا و من
+
+470
+00:41:55,920 --> 00:42:03,260
+هذا بيكون زاوية و قداش 52 طيب يا تورا لو حطينا الـ
+
+471
+00:42:03,260 --> 00:42:10,040
+A Cyclic هيسكر لإيش؟ لهدولة بنسبة 64 ل 36 طب لو
+
+472
+00:42:10,040 --> 00:42:16,880
+جيبنا هذا نقي و حطيناه لحاله و غيبنا عنه يوم إيش
+
+473
+00:42:16,880 --> 00:42:24,640
+بيعمل؟لا بيعمل اشي هذا في حالة اتزان مع الفاتح
+
+474
+00:42:24,640 --> 00:42:32,760
+الان نتيجة الاتزان بيفتح لما بيفتح بيسكر من اول و
+
+475
+00:42:32,760 --> 00:42:38,520
+جديد بالجهتين وبناء على ذلك لو اجينا حاطينا هذا
+
+476
+00:42:38,520 --> 00:42:43,480
+المسكر و سبناه يوم هو في اتزان مع الفاتح فتح سكر
+
+477
+00:42:43,480 --> 00:42:46,920
+اشمال يمين اشمال يمين بعد يوم بنلاقي ايش الناس
+
+478
+00:42:46,920 --> 00:42:53,530
+بصفيتوجود الاتنين ال alpha و ال beta بنفس النسبة
+
+479
+00:42:53,530 --> 00:43:01,190
+اللي هي ال 64 ل 36 طب لو جيبنا هذا المسكر و
+
+480
+00:43:01,190 --> 00:43:08,250
+دوّبناه في المحلول و سيبناه يوم يومين هذا هيفتح ل
+
+481
+00:43:08,250 --> 00:43:13,940
+ال a cyclic ال a cyclic هيسكر من أول و جديدشمال
+
+482
+00:43:13,940 --> 00:43:19,640
+ويمين شمال ويمين الى ان يصل الى الاتزان 64% الى 36
+
+483
+00:43:19,640 --> 00:43:25,120
+% فسواء بدأت بال A cyclic و سبته في المحلول او
+
+484
+00:43:25,120 --> 00:43:27,880
+بدأت بهذا و سبته في المحلول او بدأت بهذا و سبته في
+
+485
+00:43:27,880 --> 00:43:33,760
+المحلول اصل لنفس الخليط نفس النتيجة هذه العملية
+
+486
+00:43:33,760 --> 00:43:39,670
+الحقيقة بيسموها mutarotationلحظة الميوتا روتيشن هي
+
+487
+00:43:39,670 --> 00:43:44,070
+التغيير في الروتيشن الأبطالي بسبب تغيير الانو مارس
+
+488
+00:43:44,070 --> 00:43:53,290
+هدولة .. هدولة التنين الجداد بنسميهم احنا ايش؟ انو
+
+489
+00:43:53,290 --> 00:43:58,300
+مارساللي جايين من ال anomeric carbon اللي اختلفوا
+
+490
+00:43:58,300 --> 00:44:03,420
+في one chiral center واضح؟ يعني ال anomer beta
+
+491
+00:44:03,420 --> 00:44:07,860
+بيصير ال anomer alpha و ال anomer alpha بيصير ال
+
+492
+00:44:07,860 --> 00:44:12,560
+anomer beta لو حطيت ال alpha بصف على اتزان من
+
+493
+00:44:12,560 --> 00:44:17,120
+alpha و betaو لو حطيت ال beta بصف على اتزان من
+
+494
+00:44:17,120 --> 00:44:21,080
+alpha و beta و بنفس النسبة هذه العملية اللي احنا
+
+495
+00:44:21,080 --> 00:44:24,420
+بنسميها ايش ال mutation rotation لما احط ال alpha
+
+496
+00:44:24,420 --> 00:44:27,300
+و اكون جسد في ال polarimeter راح لاحظ ان الزاوية
+
+497
+00:44:27,300 --> 00:44:32,680
+في أولها 146 بعد شوية بتجل بتجل بتجل اخر مابتصف
+
+498
+00:44:32,680 --> 00:44:40,550
+يداش 52 لو حطيت ال betaالزاوية 19 بضلني اديس معي
+
+499
+00:44:40,550 --> 00:44:46,990
+الزمن بتضل ازيد ازيد ازيد اخر ما بتصفح 52 هذا
+
+500
+00:44:46,990 --> 00:44:52,390
+التغير في ال rotation إلى أن يصل 52 يعني إذا بدأت
+
+501
+00:44:52,390 --> 00:44:57,960
+من هنا ستصل ل 52 وإذا بدأت من هنا ستصل ل 52هذا ايش
+
+502
+00:44:57,960 --> 00:45:03,260
+بنسميه احنا ميوتا روتيشن اللي هو نشوف ايش تعريفه
+
+503
+00:45:03,260 --> 00:45:06,920
+is the change in optical rotation التغيير في ال
+
+504
+00:45:06,920 --> 00:45:09,780
+optical rotation due to inter conversion of
+
+505
+00:45:09,780 --> 00:45:13,360
+animals ان ال alpha بتصير a cyclic و بترجع تصير
+
+506
+00:45:13,360 --> 00:45:17,540
+alpha و beta in solution it is explained by the
+
+507
+00:45:17,540 --> 00:45:22,980
+equilibriumبالفسيرة بإيش أنه في اتزان أنه ال beta
+
+508
+00:45:22,980 --> 00:45:26,080
+بيفتح و بسكر alpha و beta ال alpha بيفتح و بسكر
+
+509
+00:45:26,080 --> 00:45:31,560
+alpha و beta و بنفس إيش الإتزان طبعا بإمكانهم
+
+510
+00:45:31,560 --> 00:45:34,680
+يعملوا حسابات احنا مش موضوعنا الحسابات احنا
+
+511
+00:45:34,680 --> 00:45:38,840
+موضوعنا ببساطة الآن أنه في عندنا سواء بدأت ب alpha
+
+512
+00:45:38,840 --> 00:45:44,980
+أو beta بالمحلول هاصل إلى إيش إلى الاتزان هذا
+
+513
+00:45:44,980 --> 00:45:53,110
+الاتزان 64%Beta و 36% Alpha ايش معناه؟ معناه ان ال
+
+514
+00:45:53,110 --> 00:45:57,810
+.. which is more stable ال Beta ولا ال Alpha؟ ال
+
+515
+00:45:57,810 --> 00:46:03,190
+Beta طبعا هم بيفسروا على انه لو رسمنا السكر على
+
+516
+00:46:03,190 --> 00:46:08,310
+شكل الكرسي مش السكر Cyclohexane في النهاية بتكون
+
+517
+00:46:08,310 --> 00:46:14,250
+ال OH في ال Beta equatorial يعني غير مزدحمة واضح؟
+
+518
+00:46:14,250 --> 00:46:18,690
+هذه ال OH لا تعاني ازدحام، لاحظوا هذه ال OHnot
+
+519
+00:46:18,690 --> 00:46:24,830
+crowded غير مزحمة الان هذه ال اواتش اللي طلع عليها
+
+520
+00:46:24,830 --> 00:46:33,450
+crowded مزحمة عشان هيك هو بفضل يكون في ال beta ولا
+
+521
+00:46:33,450 --> 00:46:39,170
+في ال alpha بالنسبة أعلى في ال beta بهيك بننهي
+
+522
+00:46:39,170 --> 00:46:43,430
+اليوم هذا الجزء و المرة اللي جاي ان شاء الله
+
+523
+00:46:43,430 --> 00:46:44,510
+بنستكمل
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4753652e2218d0884eeb33c0ae73abc7219b9989
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_postprocess.srt
@@ -0,0 +1,2120 @@
+1
+00:00:20,690 --> 00:00:24,750
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry
+
+2
+00:00:24,750 --> 00:00:29,730
+ربما المرة الماضية نوّهنا من خلال أنفلة تطبيقية من
+
+3
+00:00:29,730 --> 00:00:36,970
+خلال أهمية فهم ال stereo isomers في الحياة العملية
+
+4
+00:00:36,970 --> 00:00:42,990
+أن هذا موضوع مهم ولذلك شوية بنظل نتوسع فيه بعد ما
+
+5
+00:00:42,990 --> 00:00:46,830
+أخدنا المركبات اللي فيها one chiral center قولنا
+
+6
+00:00:46,830 --> 00:00:51,610
+ال one chiral center بيعتق فقطtwo isomers بعد ذلك
+
+7
+00:00:51,610 --> 00:00:56,690
+إذا زاد العدد بيبدأوا يزيدوا ال isomers طبعا بيحكم
+
+8
+00:00:56,690 --> 00:01:00,890
+الأمر المعادلة two to the n لكن ال two to the n
+
+9
+00:01:00,890 --> 00:01:05,230
+هذا أقصى عدد ممكن من ال isomers في كل الأحوال ممكن
+
+10
+00:01:05,230 --> 00:01:10,290
+يكون العدد أقل من هيك وقلنا هنعطي مثال على العدد
+
+11
+00:01:10,290 --> 00:01:15,330
+الأقصى ومثال على وانتش العدد بيصير أقل في حالة ما
+
+12
+00:01:15,330 --> 00:01:20,620
+عندنا two chiral centersبدأنا في مثال كنا عادة
+
+13
+00:01:20,620 --> 00:01:25,140
+ناخده على أنه مثال بسيط يعني الفكره مركب واحد لما
+
+14
+00:01:25,140 --> 00:01:29,620
+نيجي نقول two three dichloro بنتين بالفكره مركب
+
+15
+00:01:29,620 --> 00:01:33,640
+واحد لكن لما بنيجي نتطلع على موقع اتنين وعلى موقع
+
+16
+00:01:33,640 --> 00:01:39,410
+تلاتةبنلاحظ ان الاتنين they are chiral centers
+
+17
+00:01:39,410 --> 00:01:42,750
+وبناء على ذلك بنبدأ نتوقع انه كام مركبة بيصير
+
+18
+00:01:42,750 --> 00:01:48,890
+عندنا اربع مركبات جربنا نرسمهم من خلال انه نتخيل
+
+19
+00:01:48,890 --> 00:01:52,010
+مثلا بدنا ناخد السلسلة الكربونية بهذا الشكل يعني
+
+20
+00:01:52,010 --> 00:01:56,970
+الخمس كربونات واحد اتنين تلاتة و الاثلاربعة خمسة
+
+21
+00:01:56,970 --> 00:02:01,390
+CH2 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+22
+00:02:01,390 --> 00:02:06,770
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+23
+00:02:06,770 --> 00:02:08,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+24
+00:02:08,170 --> 00:02:08,950
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+25
+00:02:08,950 --> 00:02:09,750
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+26
+00:02:09,750 --> 00:02:10,270
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+27
+00:02:10,270 --> 00:02:11,790
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+28
+00:02:11,790 --> 00:02:13,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+29
+00:02:13,190 --> 00:02:23,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+30
+00:02:23,190 --> 00:02:27,670
+CH3 CHيعني ال R عكسة S ال R عكسة S كلام منطقي الان
+
+31
+00:02:27,670 --> 00:02:32,110
+لو جينا نطلع على المركب الثاني two R three S هذا
+
+32
+00:02:32,110 --> 00:02:37,870
+عكسه ال R اقبلها S ال S اقبلها R لأنه دائما صورة
+
+33
+00:02:37,870 --> 00:02:43,590
+بعض في المرأة بتعني التعاكس التام فلو احنا سألنا
+
+34
+00:02:43,590 --> 00:02:48,170
+ايش العلاقة بين واحد و اتنين they are enantiomersو
+
+35
+00:02:48,170 --> 00:02:52,290
+بيصير مفهوم عندنا ان اي مركبة لما نقول عنهم in
+
+36
+00:02:52,290 --> 00:02:58,650
+anchors بدتكون اشاراتهم عكس بعض الان طبعا انتوا
+
+37
+00:02:58,650 --> 00:03:02,390
+بالنظر بتقولوا صورة بعض في المرأة غير متطابقة لكن
+
+38
+00:03:02,390 --> 00:03:08,390
+ماتنسوش شغلة ان انا بإمكاني ارسم
+
+39
+00:03:09,150 --> 00:03:13,850
+المُركّب بطرق مختلفة بحيث أنه انتوا بمجرد النظر
+
+40
+00:03:13,850 --> 00:03:18,430
+البسيط ما تقدروش تتاخدوا قرار من النظر وجهة القرار
+
+41
+00:03:18,430 --> 00:03:21,750
+الأكيد بتقدروا تتاخدوا من إيش في علاقة بين
+
+42
+00:03:21,750 --> 00:03:29,110
+المُركّبين من قيم A و S خليني أؤكد الفكرة هذه لو
+
+43
+00:03:29,110 --> 00:03:34,310
+فقط أنا بدي أشغل معكم على مُركّب في one chiral
+
+44
+00:03:34,310 --> 00:03:40,470
+centerلو رسمت منه شكلين شو الاحتمالات المتوقعين
+
+45
+00:03:40,470 --> 00:03:43,610
+لما يكون عندي one chiral center؟ يا بده يكون
+
+46
+00:03:43,610 --> 00:03:48,910
+المركب نفسه رسمه بطريقتين مختلفة يا بده يكون in
+
+47
+00:03:48,910 --> 00:03:51,410
+anchormers ماعندي احتمال تاني
+
+48
+00:03:53,870 --> 00:04:01,450
+أخذ بسرعة عشوائيا هاي مركّب CH3CLPR وهي مركّب كتبت
+
+49
+00:04:01,450 --> 00:04:08,010
+هنا ال PR وهنا ال H وهنا ال CL وهنا ال CH3 لاحظوا
+
+50
+00:04:08,010 --> 00:04:12,610
+هدول المركّبين لو سألتكم ما العلاقة بينهما اللي
+
+51
+00:04:12,610 --> 00:04:16,030
+بده تيجي تتطلع تشوف أي شيء بالنظر و المرايا و
+
+52
+00:04:16,030 --> 00:04:22,100
+بنطبقه و مابنطبقوش حتىمش هتقدر، لأنه أنا أرسمهم
+
+53
+00:04:22,100 --> 00:04:25,640
+بطرق مختلفة، ماحدش بيمنعني أرسمهم بطرق مختلفة،
+
+54
+00:04:25,640 --> 00:04:31,700
+الآن أسهل شيء أن أحدد لكل مركب R أو S، الآن إذا
+
+55
+00:04:31,700 --> 00:04:35,500
+هذا طلع R و هذا R، معنى ذلك نفس المركب مرسوم بطرق
+
+56
+00:04:35,500 --> 00:04:40,800
+مختلفة، S و S نفس المركبإذا هذا R و هذا S, they
+
+57
+00:04:40,800 --> 00:04:44,140
+are enantiomers إذا هذا S و هذا R, they are
+
+58
+00:04:44,140 --> 00:04:48,260
+enantiomers هيكا بيكون أسهل طريقة أن أعملهم ولذلك
+
+59
+00:04:48,260 --> 00:04:54,380
+لو بدي أجي أطلع لهذا أقل مجموع ال H ب RCLCH3 من
+
+60
+00:04:54,380 --> 00:05:00,660
+بين R S لأن هذا ال H للأمام الآن لو بدي أطلع
+
+61
+00:05:00,660 --> 00:05:12,780
+المركب الثاني ب R CL SCH3 بين R مرة تانية وبنخليها
+
+62
+00:05:12,780 --> 00:05:18,100
+R لأن ال H للخلف هدول الانشو مارس طالما واحد قسي
+
+63
+00:05:18,100 --> 00:05:21,380
+التاني R إذا we are in ancho mars فالانشو مارس
+
+64
+00:05:21,380 --> 00:05:25,040
+دايما عكس بعض الان لو عندكوا خمسة كايرة ال centers
+
+65
+00:05:25,040 --> 00:05:29,520
+مش واحدإيش بتكون في الخمسة يكونوا عشان يكونوا
+
+66
+00:05:29,520 --> 00:05:35,300
+مركبين انانشومارز؟ كل واحد عكس التاني زي أنا باجف
+
+67
+00:05:35,300 --> 00:05:38,420
+قدام المرايا، الإيدين عكس بعض، الوش عكس بعض، البطن
+
+68
+00:05:38,420 --> 00:05:42,060
+عكس بعض، الرجلين عكس بعض، كل شيء بيكون عكس التاني،
+
+69
+00:05:42,060 --> 00:05:45,120
+يعني لو عندي ان شاء الله عشرين Cairo Center في
+
+70
+00:05:45,120 --> 00:05:49,600
+مركب، الانانشومارز تبعه، العشرين المقابلات بيكونوا
+
+71
+00:05:49,600 --> 00:05:56,300
+عكسهم، لو واحدة منهم اختلتببطلوا in anchormers على
+
+72
+00:05:56,300 --> 00:05:59,840
+طول ببطلوا صورة بعض في المرآة إذا بطلوا صورة بعض
+
+73
+00:05:59,840 --> 00:06:04,700
+في المرآة، شو بدوا يصيروا؟ ديستيريومارز، تنسوش إن
+
+74
+00:06:04,700 --> 00:06:08,740
+احنا عرفنا الديستيريومارز، they are non-mirror
+
+75
+00:06:08,740 --> 00:06:12,580
+image in anchormers ولذلك لو أنا سألت العلاقة بين
+
+76
+00:06:12,580 --> 00:06:20,780
+هدول، خلّينا نوضحها باسم RS عكس بعضعكس بعض اذا
+
+77
+00:06:20,780 --> 00:06:24,580
+they are enansimals واضح؟ الان لو سئلت هدول
+
+78
+00:06:24,580 --> 00:06:33,560
+الاتنين RS SR عكس طلع عليهم R اقبلها S S اقبلها R
+
+79
+00:06:33,560 --> 00:06:39,320
+عكس بعض they are enansimals الان لو اجيت اخدت مثلا
+
+80
+00:06:39,320 --> 00:06:49,160
+المركب واحد مع تلاتة اتطلعوا R وRهدولا متل بعض و
+
+81
+00:06:49,160 --> 00:06:56,860
+are و us عكس بعض هل هدولا عكس بعض بالكامل؟ لأ
+
+82
+00:06:56,860 --> 00:07:01,500
+هدولا متل بعض بالكامل؟ لأ مالو كانوا عكس بعض
+
+83
+00:07:01,500 --> 00:07:04,560
+بالكامل يعني كل نقطة عكس التانية they are
+
+84
+00:07:04,560 --> 00:07:10,000
+enantiomers الان لو كل نقطة زي التانية they are
+
+85
+00:07:10,000 --> 00:07:14,600
+the same compoundلو كل نقطة زي التانية هو نفس
+
+86
+00:07:14,600 --> 00:07:20,760
+المُركّب الـ R إيش زي بعض و إيش عكس بعض بطلوا صورة
+
+87
+00:07:20,760 --> 00:07:24,400
+بعض في المرأة أو بطلوا نفس المُركّب إيش هيصفه؟ ده
+
+88
+00:07:24,400 --> 00:07:28,180
+الـ Stereomers إذا لما بنيجي نتطلع إنه بدنا نفهم
+
+89
+00:07:28,180 --> 00:07:32,260
+العلاقة بين مُركّبين من خلال الرموز هنقول إنه
+
+90
+00:07:32,260 --> 00:07:36,260
+عندنا تلت احتمالات في حالة ما عندي أكتر من chiral
+
+91
+00:07:36,260 --> 00:07:40,600
+center لحظة لما كان عندي one chiral centerبدون ما
+
+92
+00:07:40,600 --> 00:07:44,080
+أعمل R و S بقولكوا عندي احتمالين يا بدهم يكونوا
+
+93
+00:07:44,080 --> 00:07:50,120
+نفس المركب R R S S يا بدهم يكونوا Enansi و Mars S
+
+94
+00:07:50,120 --> 00:07:54,840
+R أو R S الان لو كان عندي more than one chiral
+
+95
+00:07:54,840 --> 00:07:57,960
+center عندي تلت احتمالات الاحتمال الاول بدهم
+
+96
+00:07:57,960 --> 00:08:03,440
+يكونوا Enansi و Mars كل شيء عكس بعض الاحتمال
+
+97
+00:08:03,440 --> 00:08:09,150
+التاني انهم يكونوا نفس المركب كل شيء نفسهزي بعض طب
+
+98
+00:08:09,150 --> 00:08:12,950
+لو طلع شيء عكس و شيء زي بعض وجدت دي R ده يستيريو
+
+99
+00:08:12,950 --> 00:08:18,370
+مارس لحظوا الآن لو اجيت على واحد و تلاتة R و S عكس
+
+100
+00:08:18,370 --> 00:08:23,670
+بعض R و R زي بعض اذا هدولة صورت بعض في المرقاة لأ
+
+101
+00:08:23,670 --> 00:08:28,530
+نفس المركب لأ ر ده يستيريو مارس اذا واحد و تلاتة
+
+102
+00:08:28,530 --> 00:08:31,970
+ده يستيريو مارس لو طبقته مرة تانية على واحد و
+
+103
+00:08:31,970 --> 00:08:39,700
+أربعة مثلا ما العلاقة بينهم Rو S عكس بعض، هم
+
+104
+00:08:39,700 --> 00:08:47,540
+لاحظين؟ R و R نفس بعض، they are diastereomers لو
+
+105
+00:08:47,540 --> 00:08:52,720
+إجينا اتطلعنا على اتنين و تلاتة،
+
+106
+00:08:52,720 --> 00:09:02,010
+لاحظوا؟ S و Rعكس بعض السؤاس زي بعض كذلك الحال لو
+
+107
+00:09:02,010 --> 00:09:08,070
+اتطلعت اتنين اربع السؤاس نفس الاشي السؤاد عكس بعض
+
+108
+00:09:08,070 --> 00:09:13,230
+they are diastereomers واضح؟صار عندى نوع تانى من
+
+109
+00:09:13,230 --> 00:09:17,590
+الدياستيريو مارز جاي من وين جاي من المركبات فيها
+
+110
+00:09:17,590 --> 00:09:20,910
+chiral centers يعني احنا اول ما أخدنا تعريف
+
+111
+00:09:20,910 --> 00:09:25,270
+الدياستيريو مارز قولنا كل شيء مش صورة بعض في
+
+112
+00:09:25,270 --> 00:09:29,500
+المرقاة they are diastereomarsالأمثلة الكيميائية
+
+113
+00:09:29,500 --> 00:09:33,820
+الأولى اللى أخدناها شو هي الـ Cis والـ Trans أو
+
+114
+00:09:33,820 --> 00:09:37,300
+الـ Z والـ E they are diastereomers الآن بيجينا
+
+115
+00:09:37,300 --> 00:09:40,900
+أمثلة تانية لما يكون عندى more than one chiral
+
+116
+00:09:40,900 --> 00:09:45,160
+center هذه الأمثلة بتقول القاتل انه لو كان في عندى
+
+117
+00:09:45,160 --> 00:09:51,530
+مركبين في الإشارات تبعتهممش زي بعض تماما، مش نفس
+
+118
+00:09:51,530 --> 00:09:54,650
+المُركّب، ولا Inansiomers و they are
+
+119
+00:09:54,650 --> 00:10:00,010
+stereoisomers، إيش هيصفهم؟ ديستيريو مارس، واضح؟
+
+120
+00:10:00,010 --> 00:10:05,270
+وبهيك أخدنا إن الديستيريو مارس بكم ما كان، بنشوفهم
+
+121
+00:10:05,270 --> 00:10:11,460
+بالكيميامكالين بال CC trans او ZE و بال chiral
+
+122
+00:10:11,460 --> 00:10:15,680
+compounds او بال stereo chemistry لما يكون عندى
+
+123
+00:10:15,680 --> 00:10:21,440
+اكتر من chiral center بشرط انه ننتبه ل ROS
+
+124
+00:10:21,440 --> 00:10:27,760
+بالطريقة اللى اتكلمنا فيها الان طالما ان هدولةالهم
+
+125
+00:10:27,760 --> 00:10:31,760
+إشارات مختلفة فى كام مركب عندى لتو ثري دايكلورو
+
+126
+00:10:31,760 --> 00:10:36,180
+بنتين أربعة هى رموزهم اللى بدى تروح تشتريهم من
+
+127
+00:10:36,180 --> 00:10:39,800
+السوق هتلاقيهم أربعة مركبات الآن احنا قولنا ممكن
+
+128
+00:10:39,800 --> 00:10:46,760
+يكون العدد أقل ناخد مثالهذا المثال 2,3
+
+129
+00:10:46,760 --> 00:10:51,800
+-dichlorobutane قال ذرة كربون واحدة يعني لو انا
+
+130
+00:10:51,800 --> 00:10:56,080
+رسمت هاي كربون تنتين تلاتة اربعة اذا المركب اللي
+
+131
+00:10:56,080 --> 00:11:02,100
+عندى ايش بيوتين واضح لاحظوا ايش بيفرق يعني كتير
+
+132
+00:11:02,100 --> 00:11:09,120
+لبيوتين عنالبنتين لو انا مجرد ان كتبت كتابة مثل
+
+133
+00:11:09,120 --> 00:11:17,800
+CH3 CHCl CHCl CH3 عارفين شو بيفرق؟ لو انا اتيت بين
+
+134
+00:11:17,800 --> 00:11:20,840
+هدولة الـ chiral centers التنين الكاربونز اللي
+
+135
+00:11:20,840 --> 00:11:26,760
+حاملة كلور و جسمت المركب من النصتطلعوا هنا إيش
+
+136
+00:11:26,760 --> 00:11:33,460
+اللي موجود Carbon حاملة HCl و بعدها CH3 و هنا
+
+137
+00:11:33,460 --> 00:11:39,240
+Carbon حاملة HCl و بعدها CH3 إذا هذا المركب صار
+
+138
+00:11:39,240 --> 00:11:44,460
+مركب متماثل قبل شوية لما كنت .. أو من هنا على هذا
+
+139
+00:11:44,460 --> 00:11:49,800
+الشكل أجسم زي هيك تطلعوا كأعداد ذراتماذا عندكم
+
+140
+00:11:49,800 --> 00:11:54,980
+هنا؟ كاربون حاملة HCl وCH3 وهنا كاربون حاملة HCl
+
+141
+00:11:54,980 --> 00:12:01,860
+وCH3 فعدد الذرات اللي بهذا الاتجاه هو نفسه عدد
+
+142
+00:12:01,860 --> 00:12:05,760
+الذرات اللي بهذا الاتجاه فهذا الكاربون بيحمل نوع
+
+143
+00:12:05,760 --> 00:12:10,380
+من التماثل هذا الكلام في المثال السابق ماكانش لما
+
+144
+00:12:10,380 --> 00:12:16,160
+كنتوا تحطوا خط هنابين ال two chiral centers عدولي
+
+145
+00:12:16,160 --> 00:12:22,780
+كل الذرات اللي هتشومها C وH وCL و CH3 و هنا CH وCL
+
+146
+00:12:22,780 --> 00:12:29,460
+و بعدها CH2 CH3 إذا هل هذا النص زي هذا النص لأ في
+
+147
+00:12:29,460 --> 00:12:34,910
+حالة البيوتينأ لبيوتين في تماثل داخلي بين ال two
+
+148
+00:12:34,910 --> 00:12:39,790
+chiral centers يعني المركب سيماتريك الآن لو إجينا
+
+149
+00:12:39,790 --> 00:12:44,310
+جربنا نرسم ال isomers بنفس الطريقة اللي اتعلمناها
+
+150
+00:12:44,310 --> 00:12:51,270
+سابقا يعني أجي أحط تنتين كلور عكس بعض و صورتهم في
+
+151
+00:12:51,270 --> 00:12:54,810
+المرأة و تنتين كلور على جهة واحدة و صورتهم في
+
+152
+00:12:54,810 --> 00:13:02,210
+المرأة و بعدين أحدد R و Sلاحظوا هذه الرسمة تماما
+
+153
+00:13:02,210 --> 00:13:06,510
+هي نسخ و لصق من الرسمة السابقة بس بدل ما كنا
+
+154
+00:13:06,510 --> 00:13:12,890
+كاتبين هنا اثل كتبنا مثل واضح؟ و لذلك انتوا الان
+
+155
+00:13:12,890 --> 00:13:20,310
+كام مركب بتشوفه؟مازالتوا بتشوفوا أربع مركبات
+
+156
+00:13:20,310 --> 00:13:26,150
+للوهلة الأولى لكن لو نظرنا بعمق لهدولة الأربع
+
+157
+00:13:26,150 --> 00:13:32,130
+مركبات هلاحظ ان هذا 2R3R و هذا 2S3S
+
+158
+00:13:34,300 --> 00:13:40,660
+عكس بعض هتيجوا تستنتجوا انهم انانشومارز فش اننا
+
+159
+00:13:40,660 --> 00:13:45,160
+خلاف الآن لما بتيجوا تطلع على المركبين التانيين
+
+160
+00:13:45,160 --> 00:13:49,140
+وخلونا نقول .. نقولنا الترقيم واحد اتنين تلاتة
+
+161
+00:13:49,140 --> 00:13:55,720
+اربعة واحد اتنين تلاتة اربعة و هيناخد واحدة بس
+
+162
+00:13:55,720 --> 00:14:01,560
+نأكد هي ال CL نمرة واحدوهذه ال carbon الحاملة Cl2
+
+163
+00:14:01,560 --> 00:14:09,860
+و CH3 بين S كتبناها R وهذه لو بدنا نتطلع عليها 1 2
+
+164
+00:14:09,860 --> 00:14:16,300
+Cl بعدين carbon حاملة Cl بعدين CH3 Cl بعدين carbon
+
+165
+00:14:16,300 --> 00:14:21,100
+حاملة Cl بعدين CH3 بين R كتبنا S إذا هيك مظبوطين
+
+166
+00:14:21,100 --> 00:14:25,900
+هدولة two R three Sلو اعملنا المركب التاني لجبانو
+
+167
+00:14:25,900 --> 00:14:30,260
+بين two as three are اي حد هيتطلع بهذا الشكل
+
+168
+00:14:30,260 --> 00:14:33,800
+البصير شو هيقول هدول العلاقة بينهم they are
+
+169
+00:14:33,800 --> 00:14:36,760
+enantiomers الان بنقول لأ they are the same
+
+170
+00:14:36,760 --> 00:14:42,420
+compound هتبدو يصير عندكم مشكلة ليش لأنه هتقولوا
+
+171
+00:14:42,420 --> 00:14:47,540
+انت لسه توت و التصوير شاهد علينا كمان بتقول انه
+
+172
+00:14:47,540 --> 00:14:55,020
+اذا كل شيء عكس بعضهthey are enantiomers هاي مثال و
+
+173
+00:14:55,020 --> 00:14:59,320
+فيها دول عكس بعض لكن أنا قاعد بقول عنهم they are
+
+174
+00:14:59,320 --> 00:15:05,060
+the same compound كيف هذا الكلام بيصير؟ هل يا ترى
+
+175
+00:15:05,060 --> 00:15:09,520
+الإنسان بناقض في الحكي ولا لأ؟ الحقيقة في سبب و
+
+176
+00:15:09,520 --> 00:15:15,240
+الأمر هنابحاجة إلى نظرة شوية متعمقة .. بحاجة إلى
+
+177
+00:15:15,240 --> 00:15:19,380
+نظرة شوية متعمقة بين هدول الصورتين تحديدا لو
+
+178
+00:15:19,380 --> 00:15:23,140
+اتخيلتوا انتوا .. لو اتخيلتوا ان انتوا حاطيتوا
+
+179
+00:15:23,140 --> 00:15:26,660
+دبوس هنا مسيكتوا هذا المركب بعدين لفتوه بهذا الشكل
+
+180
+00:15:26,660 --> 00:15:30,980
+طلعوا معايا مرة تانية كأنه هنا فيه محور و الف
+
+181
+00:15:30,980 --> 00:15:35,640
+المركب بهذا الشكل وين هتيجي هذه ال CH3 وين هتطلع
+
+182
+00:15:35,640 --> 00:15:41,720
+هذه ال CL تنتين وين هييجوا ال Hهيصيروا نفس هذا
+
+183
+00:15:41,720 --> 00:15:48,580
+المُركّب ولا لأ؟ نفس المُركّب واضح؟ بهذا الشكل
+
+184
+00:15:48,580 --> 00:15:54,420
+لفوه هاي الـ CLE جوهان و الـ H3 و الـ CH3 انعكسوا
+
+185
+00:15:54,420 --> 00:16:00,660
+ممكن واحدة تيجي تقولي ما كان لفت اللي قبله خليني
+
+186
+00:16:00,660 --> 00:16:05,680
+أرجع للي قبله اللي قبله ماكانش متمثل يعني لما ألف
+
+187
+00:16:05,680 --> 00:16:12,140
+شو بده ينزل هنا CH3 شو بده يطلع هنا؟صح لما انا هاد
+
+188
+00:16:12,140 --> 00:16:15,140
+و بدى ألف و هيك ال CL's و ال H's بيجوا مكان بعض
+
+189
+00:16:15,140 --> 00:16:19,940
+لكن محل ال Ethel شو بتيجي؟ محل ال Ethel مثل هذه
+
+190
+00:16:20,690 --> 00:16:26,010
+املاحظين يعني هذا لو لفته بينطبق على هذا لأ بينما
+
+191
+00:16:26,010 --> 00:16:30,910
+اللي بعده بينطبق ماسبب الانطباق في الحالة التالية
+
+192
+00:16:30,910 --> 00:16:34,390
+و عدم الانطباق في الحالة الأولى انه هذا في الحالة
+
+193
+00:16:34,390 --> 00:16:39,970
+هذه غير متماثل داخليا يعني هذه CH3 هذه اتل مش هذا
+
+194
+00:16:39,970 --> 00:16:47,410
+النص زي هذا بينما في المركب اللي بعده هذا متماثل
+
+195
+00:16:48,570 --> 00:16:51,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+196
+00:16:51,090 --> 00:16:58,750
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+197
+00:16:58,750 --> 00:16:59,530
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+198
+00:16:59,530 --> 00:17:00,070
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+199
+00:17:00,070 --> 00:17:00,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+200
+00:17:00,090 --> 00:17:00,210
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+201
+00:17:00,210 --> 00:17:00,910
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+202
+00:17:00,910 --> 00:17:00,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+203
+00:17:00,950 --> 00:17:01,730
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+204
+00:17:01,730 --> 00:17:13,310
+مثل مثل
+
+205
+00:17:13,310 --> 00:17:17,470
+مثل مثالـR و الـS اللي مبينين عكس بعض كيف بدنا نحل
+
+206
+00:17:17,470 --> 00:17:23,450
+مشكلتهم لأن احنا قلنا إذا كل شي عكس بعض لازم نصنف
+
+207
+00:17:23,450 --> 00:17:28,970
+المراكبات in anchors طب هي مبينين عكس بعض آه مديش
+
+208
+00:17:28,970 --> 00:17:33,990
+تنسوا شغلة هذا المراكب لو أنا جبته لكم في الامتحان
+
+209
+00:17:33,990 --> 00:17:39,610
+و قلتلكم سموهو إجت واحدة منكم اتطلعت فيه و حطت
+
+210
+00:17:39,610 --> 00:17:46,850
+ترقيم 1234 صار هذا موقع 2 و عملته لجته 2R هذا موقع
+
+211
+00:17:46,850 --> 00:17:53,050
+3 و عملته لجته 3S طيب لو واحدة تانية إجت و قالت
+
+212
+00:17:53,050 --> 00:18:00,930
+خليني أرقم من تحت ما هو متمثل هاي 1234 ع 23 أيضا
+
+213
+00:18:01,530 --> 00:18:06,510
+Echlor, إذا هذا بترقم من كام جهة؟ من الجهتين نفس
+
+214
+00:18:06,510 --> 00:18:11,230
+الشيء هذا بترقم من الجهتين نفس الشيء المركب اللي
+
+215
+00:18:11,230 --> 00:18:16,230
+جابي اللي بقدرش أعمل فيه هذا الكلام بدي أكو أتضالك
+
+216
+00:18:16,230 --> 00:18:22,490
+و أتقرره لو كنت بده أرقم من هنا هذه CH2 CH3 لحظة
+
+217
+00:18:22,490 --> 00:18:28,720
+واحد اتنين هيصيروا ال Echlorتلاتة اربعة واحد اتنين
+
+218
+00:18:28,720 --> 00:18:34,200
+تلاتة اذا هذا كام ترقيم يحتمل واحد فقط واحد اتنين
+
+219
+00:18:34,200 --> 00:18:37,920
+تلاتة عشان ال glory يكونوا اقل ترقيم من هنا واحد
+
+220
+00:18:37,920 --> 00:18:41,140
+اتنين تلاتة اربعة خمسة بيكون اتنين تلاتة من هنا
+
+221
+00:18:41,140 --> 00:18:45,640
+واحد اتنين تلاتة اربعة خمسة بيصير تلاتة اربعة اذا
+
+222
+00:18:45,640 --> 00:18:52,420
+هذا كام ترقيم يحتمليحتمل ترقيم واحد فقط لكن المركب
+
+223
+00:18:52,420 --> 00:18:56,880
+اللي بعده المتماثل لو انا رقمته زي ما انتوا شايفين
+
+224
+00:18:56,880 --> 00:19:06,100
+بالازرق صح و لو انا رقمته بالاحمر صح طيب اللي رقمت
+
+225
+00:19:06,100 --> 00:19:12,660
+بالازرق كتبت المركب 2R3S23Diclorobutane
+
+226
+00:19:12,660 --> 00:19:17,390
+طب و اللي بده ترقم بالاحمر شو هتكتب؟الـ 2 ما احنا
+
+227
+00:19:17,390 --> 00:19:21,950
+عارفين ان هذه R و هذه S بغض النظر عن الترقيم هتكتب
+
+228
+00:19:21,950 --> 00:19:25,270
+2S3R
+
+229
+00:19:25,270 --> 00:19:30,930
+الآن اي جواب اللي بدنا نعتبره صح الجوابين صح هذا
+
+230
+00:19:30,930 --> 00:19:36,610
+إله اسمين هذا إله اسمين لأنه متماثل وعشانك المدرس
+
+231
+00:19:36,610 --> 00:19:40,250
+اللي بده يصلح بيجيبلكوا هذا المركب ويقولكوا اعطوه
+
+232
+00:19:40,250 --> 00:19:45,680
+اسمهذا الجواب يبدو يعتبره صح وهذا الجواب يبدو
+
+233
+00:19:45,680 --> 00:19:49,600
+يعتبره صح لسبب بسيط انه مافيه فارق نهائي بين انكوا
+
+234
+00:19:49,600 --> 00:19:54,280
+ترقموه من هنا او من هنا الان نفس الشيء في المركب
+
+235
+00:19:54,280 --> 00:19:58,900
+التاني لما رقمناه بالازرق واحد اتنين تلاتة اربعة
+
+236
+00:19:58,900 --> 00:20:05,140
+طب لو واحدة عملتله ترقيم تاني بالاحمر ايش هتكتبوه؟
+
+237
+00:20:05,140 --> 00:20:11,040
+two R three S الان اتطلعوا هذا أحد أسماء two S
+
+238
+00:20:11,040 --> 00:20:19,770
+three Rهذا أحد أسمائه 2R3S
+
+239
+00:20:19,770 --> 00:20:28,590
+و هذا 2R3S لأن الجزء ببساطة متماثل لأن هذا الجزء
+
+240
+00:20:28,590 --> 00:20:33,490
+ببساطة متماثل بياخد اسمين و هدول الشكلين بيكونوا
+
+241
+00:20:33,490 --> 00:20:38,710
+مركب واحد مش مركبينواضح؟ مركّب واحد وبتسمى
+
+242
+00:20:38,710 --> 00:20:42,110
+بطريقتين، الآن إذا اتفقنا إن هدولة they are the
+
+243
+00:20:42,110 --> 00:20:46,250
+same compound، بأكتر من طريقة فرجيتكم، اللي بدأ من
+
+244
+00:20:46,250 --> 00:20:49,710
+خلال الإشارات، إنه يلهم نفس الإشارات، أيه؟ يلهم
+
+245
+00:20:49,710 --> 00:20:56,750
+نفس الإشارات ولا لأ؟2R 3S .. 2S 3R .. 2S 3R .. 2S
+
+246
+00:20:56,750 --> 00:21:04,650
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+247
+00:21:04,650 --> 00:21:05,570
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+248
+00:21:05,570 --> 00:21:05,730
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+249
+00:21:05,730 --> 00:21:05,930
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+250
+00:21:05,930 --> 00:21:06,830
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+251
+00:21:06,830 --> 00:21:14,070
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+252
+00:21:14,070 --> 00:21:21,840
+2S 3R .. 2S 3Rوغيرهم سواء سمته 2R3S او 2S3R هو نفس
+
+253
+00:21:21,840 --> 00:21:26,100
+المركب له اسميننفس المركب له اسمين شو اللي عمله
+
+254
+00:21:26,100 --> 00:21:31,660
+الاسمين التماثل اذا لو انا بجاجي اسأل ببساطة لو
+
+255
+00:21:31,660 --> 00:21:35,480
+واحدة ع طول بده تعرف انه عندها اربع مركبات ولا
+
+256
+00:21:35,480 --> 00:21:40,320
+تلاتة ايش اول ما بده تطلع عليه في الجزء انه هل يا
+
+257
+00:21:40,320 --> 00:21:44,460
+ترى هذا الجزء اللي عنده فيه تماثل ولا لا اذا فيه
+
+258
+00:21:44,460 --> 00:21:49,620
+تماثل ع طول بده تحكي عن كام مركبعن تلاتة مافيش
+
+259
+00:21:49,620 --> 00:21:53,820
+تماثل بده تحكي عن أربع يعني لو مثلا سألكوا هذا
+
+260
+00:21:53,820 --> 00:22:05,280
+السؤال CH3 CHBR CHCL CH3 كام Cairo Center فيه؟هن و
+
+261
+00:22:05,280 --> 00:22:09,200
+هن قبل ما ارسم ايزو مارزو اتعب كام ايزو مارزو
+
+262
+00:22:09,200 --> 00:22:14,480
+تتوقعوا له اربعة عطول اربعة ليش لانه انا لو جسمت
+
+263
+00:22:14,480 --> 00:22:18,260
+بين هدولة two chiral centers هذي الظرات مش هى هذي
+
+264
+00:22:18,260 --> 00:22:25,060
+الظرات هنا عندكم H و CL هنا H .. خلاص انتهى واضح؟
+
+265
+00:22:25,060 --> 00:22:31,600
+و هكذاواضح، الان هذا المركب اللي فيه تماثل داخلي،
+
+266
+00:22:31,600 --> 00:22:37,860
+لو انتوا بتتأملوا فيه بعمق شوية، بتحسوا انه اللي
+
+267
+00:22:37,860 --> 00:22:44,250
+خلّاه يصيرنفس المركب و اقدر الفه انه انا لو اني
+
+268
+00:22:44,250 --> 00:22:48,650
+اتخيلت مرايا في نص المركب هذا النص اللى فوق صورة
+
+269
+00:22:48,650 --> 00:22:52,770
+النص اللى تحت فى المرأة ولا لأ طلعوا معاك هى ال CL
+
+270
+00:22:52,770 --> 00:23:00,790
+اقبالها CL ال H H ال مثل مثل اذا one half of the
+
+271
+00:23:00,790 --> 00:23:04,170
+molecule is the mirror image of the other half ولا
+
+272
+00:23:04,170 --> 00:23:10,660
+لأ هذا النص هو صورة هذا النص فى المرأةواضح الكلام؟
+
+273
+00:23:10,660 --> 00:23:14,420
+زي الناس اللي بتطلعوا على كروت الشدة إذا عمركوا
+
+274
+00:23:14,420 --> 00:23:18,780
+شفتوها بتشوفوا الرسومات اللي فيها البني آدم هيك او
+
+275
+00:23:18,780 --> 00:23:24,620
+بصر هيك بعدين هذا
+
+276
+00:23:24,620 --> 00:23:29,540
+زيه بالظبط .. هذا زيه بالظبط أنه النص هذا .. صورة
+
+277
+00:23:29,540 --> 00:23:37,180
+النص هذا في المرأةواضح؟ الان هذا المركب كأنه حقيقة
+
+278
+00:23:37,180 --> 00:23:42,380
+يحتوي على مركبين كأنه هذا مركب بإمكانكوا تتخيلوه و
+
+279
+00:23:42,380 --> 00:23:47,540
+هذا مركب تاني و هاي هم بس متصلين في بعض و من البعض
+
+280
+00:23:47,540 --> 00:23:52,760
+لو إجيت بديت أفكر بعمق شوية هذا لو إنه حطناه لوحده
+
+281
+00:23:52,760 --> 00:23:59,810
+في المرآة بيطلع كايران و إلهrotation وهذا لو حطيته
+
+282
+00:23:59,810 --> 00:24:04,450
+لوحده في المرأة كايرة له rotation طيب لو أخدت
+
+283
+00:24:04,450 --> 00:24:09,530
+مليون جزء من المركب الكلي كده يكون من هذا النص
+
+284
+00:24:09,530 --> 00:24:15,370
+مليون و من هذا النص مليون و المليونين عكس بعض صار
+
+285
+00:24:15,370 --> 00:24:21,750
+هذا بنفسه يشبه إيش؟Racemic mixture اللى أخدناه
+
+286
+00:24:21,750 --> 00:24:25,510
+المرة الماضية لما كنا نقولكوا لو كان عندى خليط
+
+287
+00:24:25,510 --> 00:24:31,050
+متساوي من two isomers شو سمناه؟ Racemic mixture
+
+288
+00:24:31,050 --> 00:24:35,850
+واحد منهم بيلف يمين التانى اشمال قداش بيكون
+
+289
+00:24:35,850 --> 00:24:41,240
+بالمجمل ال rotation له؟ سفرالـ Racemic mixture
+
+290
+00:24:41,240 --> 00:24:45,460
+بيكون optically active ولا inactive؟ optically
+
+291
+00:24:45,460 --> 00:24:48,880
+inactive ليش optically inactive؟ لأنه فيه عدد
+
+292
+00:24:48,880 --> 00:24:54,240
+متساوي من ال enantiomers بيلغوا بعض الان هذا تماما
+
+293
+00:24:54,240 --> 00:24:58,700
+يشبه الracemic mixture كأنه هاي نص و هاي نص هدول
+
+294
+00:24:58,700 --> 00:25:04,040
+عكس بعض ولا لا؟ واحد R و واحد S الجزء الكبير لو
+
+295
+00:25:04,040 --> 00:25:09,210
+منه مليون كدهش فيه من هذا؟ و من هذا؟أذا هذا
+
+296
+00:25:09,210 --> 00:25:13,330
+racemic mixture كأنه بامتياز بس موجود في مركب واحد
+
+297
+00:25:13,330 --> 00:25:17,550
+فهذا المركب بالمجمل بيكون optically active ولا
+
+298
+00:25:17,550 --> 00:25:24,070
+inactive هالمركب العجيب هذا المتماثل اللي موجود ال
+
+299
+00:25:24,070 --> 00:25:28,390
+configuration فيه لنصه عكس التاني اللي نصه صورة
+
+300
+00:25:28,390 --> 00:25:32,270
+بعض أو صورة نص التاني في المرآة أخد اسم في ال
+
+301
+00:25:32,270 --> 00:25:36,910
+stereo chemistry بيسميه meso compound أو
+
+302
+00:25:36,910 --> 00:25:42,570
+mesostructureلحظة الان لو بدنا نقرأ ايش تعريف ال
+
+303
+00:25:42,570 --> 00:25:47,170
+meso compound كل الكلام هذا معرف هنا كل اللي حكينا
+
+304
+00:25:47,170 --> 00:25:53,050
+ال meso compound is an achiral diastereomer of the
+
+305
+00:25:53,050 --> 00:25:56,450
+compound achiral يعني optically inactive شوفنا ليش
+
+306
+00:25:56,450 --> 00:26:02,470
+انه achiral و ليش انه optically inactiveرغم أنه في
+
+307
+00:26:02,470 --> 00:26:06,750
+مركز استيريوجينيك كم مركز استيريوجينيك فيه؟ اتنين
+
+308
+00:26:06,750 --> 00:26:11,630
+لكن هو بالمحصلة كايرال ولا اكايرال؟ اكايرال
+
+309
+00:26:11,630 --> 00:26:14,190
+optical and active although it contains
+
+310
+00:26:14,190 --> 00:26:18,030
+stereogenic centers الان its stereogenic centers
+
+311
+00:26:18,030 --> 00:26:23,190
+have opposite configurations يعني لازم واحد R
+
+312
+00:26:23,190 --> 00:26:26,970
+والتاني S هذا اللي بيكون ال mesocompound او نفس
+
+313
+00:26:26,970 --> 00:26:32,470
+المركب one half of the molecule isThe mirror image
+
+314
+00:26:32,470 --> 00:26:37,330
+of the other half اللي في هذه المواصفات بنقول انه
+
+315
+00:26:37,330 --> 00:26:43,520
+ميزو كومباوند بيكون مركب واحد مشمش مركبين
+
+316
+00:26:43,520 --> 00:26:46,160
+optically inactive يعني لو جينا سئلناكوا في
+
+317
+00:26:46,160 --> 00:26:49,360
+الامتحان ميزو كومباوند is optically active or
+
+318
+00:26:49,360 --> 00:26:55,260
+inactive؟ inactive الميزو كومباوند if مركب متماثل
+
+319
+00:26:55,260 --> 00:26:58,680
+لما اجي ارسم عندى two R three R two S three S و
+
+320
+00:26:58,680 --> 00:27:02,880
+two R three S او التانية من اللي فيهم بتكون ميزو؟
+
+321
+00:27:02,880 --> 00:27:09,000
+اللي فيها هدول عكس بعض يعني اللي بتكون RR او SS كل
+
+322
+00:27:09,000 --> 00:27:13,630
+واحدة منهم فردة in andيعني هذه لو أخدتها لحالها
+
+323
+00:27:13,630 --> 00:27:19,130
+optically active لو
+
+324
+00:27:19,130 --> 00:27:23,650
+عملت خليط متساوي من هدول الاتنين بيصير عند راسمك
+
+325
+00:27:24,520 --> 00:27:28,120
+mixture بيصير optical inactive لو أخدت من واحدة
+
+326
+00:27:28,120 --> 00:27:33,360
+اكتر من التانية زي ما اتعلمنا بيصير النتج نتاج
+
+327
+00:27:33,360 --> 00:27:38,600
+التنتين لكن هذا المركب هذا المركب اللي بيميزه انه
+
+328
+00:27:38,600 --> 00:27:43,100
+واحدة منه R والتانية S اذا انا لما بتعرف ال mezzo
+
+329
+00:27:43,100 --> 00:27:47,380
+compound في المركب المتماثل اللي بيكون منه واحدة R
+
+330
+00:27:47,380 --> 00:27:53,360
+والتانية S هذا ال mezzo compound والمجموع بيطلع
+
+331
+00:27:54,340 --> 00:27:59,240
+تلات مركبات في النهاية الان لو اتيت سألة طيب يا
+
+332
+00:27:59,240 --> 00:28:02,700
+تورا قولنا احنا اكيد بين هذا و هذا العلاقة they
+
+333
+00:28:02,700 --> 00:28:06,720
+are enantiomers طب لو اي واحد من هذول ال
+
+334
+00:28:06,720 --> 00:28:11,520
+enantiomers قرنته بال meso compound اه طلعوا two
+
+335
+00:28:11,520 --> 00:28:18,320
+are نفس الاشي هدوله واضح نفس الشي و three are
+
+336
+00:28:18,320 --> 00:28:24,870
+three asعكس بعض، اشي نفسه، اشي عكسه، فين VR؟ ده
+
+337
+00:28:24,870 --> 00:28:30,950
+يستيريو مارسي، فين VR؟ ده يستيريو مارسي بتايع ليه؟
+
+338
+00:28:30,950 --> 00:28:35,490
+بيكفي على موضوع ال two chiral centers الآن في
+
+339
+00:28:35,490 --> 00:28:41,850
+عندكم مجموعة من الأسئلة كيف توجدوا العلاقة بين
+
+340
+00:28:41,850 --> 00:28:47,080
+المركبين حتى لو رسمناهم بطرق مختلفةلاحظوا هذه
+
+341
+00:28:47,080 --> 00:28:50,980
+المُركّبات مرسومة بطرق مختلفة تماما مرة الـH لفوق
+
+342
+00:28:50,980 --> 00:28:54,820
+و مرة الـH على الجانب لكنهم نفس المُركّب بالمناسبة
+
+343
+00:28:54,820 --> 00:29:00,060
+يعني من ناحية structure أو روابط يعني كاربون
+
+344
+00:29:00,060 --> 00:29:04,280
+الأولى حملة PR و CL و بعدين CH3 و هاي الكاربون
+
+345
+00:29:04,280 --> 00:29:07,680
+اللي هو حملة PR و CL و بعدين CH3 يعني لو هذا و هذا
+
+346
+00:29:07,680 --> 00:29:13,090
+كنت بدأ أسميهم one-bromo one-chloro-ethaneمرة
+
+347
+00:29:13,090 --> 00:29:18,290
+تانية هاي carbon واحد هاي اتنين شو هتسموه وان
+
+348
+00:29:18,290 --> 00:29:25,500
+برومو وان كلوروإيه ثاني الار هدول الاتنين اللي
+
+349
+00:29:25,500 --> 00:29:29,680
+مرسومين بيدي العلاقة بينهم مش مرسومين بطريقة اللي
+
+350
+00:29:29,680 --> 00:29:33,180
+بالعين المجردة أشوف أنهم بينيهم مرسومين زي بعض أو
+
+351
+00:29:33,180 --> 00:29:37,000
+كل واحدة عكس التانية مرسومين بطرق مختلفة إذا على
+
+352
+00:29:37,000 --> 00:29:42,200
+طول ماليش حل إلا أحدد ال configuration أحددهم بضوء
+
+353
+00:29:42,200 --> 00:29:46,880
+هذا طلع R و هذا R then they are the same compound
+
+354
+00:29:46,880 --> 00:29:53,920
+واضح؟ الآن جيبنالكم مركبين تانينكم carbon هذا لو
+
+355
+00:29:53,920 --> 00:29:59,540
+بدكوا تسموه المركب هذا أطول سلسلة فيه قداش أربعة
+
+356
+00:29:59,540 --> 00:30:09,160
+واحد اتنين اعلم على أطول سلسلة CH3CCCH3
+
+357
+00:30:09,160 --> 00:30:17,440
+إذا هذا المركب اللي عندى بيوتين شو بيحمل بيوتين؟ع
+
+358
+00:30:17,440 --> 00:30:21,920
+نمره 2 برومه ع نمره 3 كلور ترقيب واحد عندي عشان
+
+359
+00:30:21,920 --> 00:30:26,340
+اخلي البروم اقل ما يمكن اتنين برومه ثلاثة ثلاثة
+
+360
+00:30:26,340 --> 00:30:27,620
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+361
+00:30:27,620 --> 00:30:29,600
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+362
+00:30:29,600 --> 00:30:36,300
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+363
+00:30:36,300 --> 00:30:44,220
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+364
+00:30:44,220 --> 00:30:50,050
+ثلاثة ثأحدد R و S لما أعملهم بهدوء بتعملهم في
+
+365
+00:30:50,050 --> 00:30:56,550
+البيت هنا two S and two R انبينين عكس بعض three S
+
+366
+00:30:56,550 --> 00:31:01,850
+and three R the same then they are diastereomers
+
+367
+00:31:01,850 --> 00:31:05,730
+كذلك
+
+368
+00:31:05,730 --> 00:31:11,930
+الحال هذا المركب هي أطول سلسلة فيهنطلع عليها واحد
+
+369
+00:31:11,930 --> 00:31:15,810
+اتنين تلاتة اربعة ع تنين برم وع تلاتة كلور وهذه
+
+370
+00:31:15,810 --> 00:31:20,350
+أطول السلسلة واحد اتنين تلاتة اربعة ع تنين برم وع
+
+371
+00:31:20,350 --> 00:31:28,710
+تلاتة كلور نحدد له R وS two S two R three S three
+
+372
+00:31:28,710 --> 00:31:37,170
+R الترقيم من هناك كل شيء عكس بعضين VR انانشومارز
+
+373
+00:31:37,170 --> 00:31:41,670
+اللي بعده نفس الشيء لو عملته بهدوءthe same
+
+374
+00:31:41,670 --> 00:31:46,270
+compound واضح؟ the same compound طبعا انتوا بدكوا
+
+375
+00:31:46,270 --> 00:31:51,970
+تحذروا بس بحالة واحدة لما يكون المركب متماثل و
+
+376
+00:31:51,970 --> 00:31:57,010
+يطلع عندكم 2R 3S و التالية 2S 3R بدكوا ترجعوا
+
+377
+00:31:57,010 --> 00:32:00,770
+تفكروا بالإيش بال meso compound اللي هو the same
+
+378
+00:32:00,770 --> 00:32:04,910
+compoundلو كان المراكب متماثل الأمثل هذا اللي
+
+379
+00:32:04,910 --> 00:32:09,350
+قدامكم مش متماثل لأنه على جهة بروم و على جهة كلور
+
+380
+00:32:09,350 --> 00:32:15,150
+دائما التفكير وين بده يكون قف و أفكر لما يكون فيه
+
+381
+00:32:15,150 --> 00:32:19,490
+تماثل داخلي إذا في تماثل داخلي و طلع عندكم ال
+
+382
+00:32:19,490 --> 00:32:26,150
+configurations في المتماثل إذا طلع عندكم R و S و
+
+383
+00:32:26,150 --> 00:32:31,390
+جبالها S و Rthey are the same compound هذا الحكي
+
+384
+00:32:31,390 --> 00:32:37,610
+وين بيكون في المركبات المتماثلة بيكون المركب فعلا
+
+385
+00:32:37,610 --> 00:32:44,630
+ميزو لما أحكي عن مركبين ر أس و أس و ر طلعوا معاكم
+
+386
+00:32:44,630 --> 00:32:51,270
+if مركب فيه تماثل داخلي بنقول عنهم they are the
+
+387
+00:32:51,270 --> 00:32:56,130
+same compound أو بنقول this is a mezzo compound
+
+388
+00:32:56,130 --> 00:33:01,530
+وبيكون طبعا opticallyinactive بيكون optically
+
+389
+00:33:01,530 --> 00:33:05,810
+inactive الان
+
+390
+00:33:05,810 --> 00:33:13,230
+لو اجينا لتفاعلات او التفاعلات المرتبطة بال stereo
+
+391
+00:33:13,230 --> 00:33:17,590
+chemistry في ال stereo chemistry في عندى اكتر من
+
+392
+00:33:17,590 --> 00:33:21,520
+نوع من التفاعلاتأحد هذه التفاعلات بنسميه
+
+393
+00:33:21,520 --> 00:33:25,720
+generation of a chiral center يعني انتوا بدأتوا
+
+394
+00:33:25,720 --> 00:33:30,320
+بمركب مش فيه ولا chiral center اعملتوا chiral
+
+395
+00:33:30,320 --> 00:33:35,740
+center خلينا ناخد مثال بسيط لو قلنا لكوا بدنا نعمل
+
+396
+00:33:35,740 --> 00:33:44,340
+chlorination للبيوتين بتذكرين البيوتين CH3 CH2 CH2
+
+397
+00:33:45,570 --> 00:33:50,510
+CH3 هل يترى هذا في أي كايرال سنتر؟ لا في كربون
+
+398
+00:33:50,510 --> 00:33:55,770
+بتحمل أربع مجموعات الآن بدنا نشيل هيدروجين يا من
+
+399
+00:33:55,770 --> 00:34:00,590
+موقع واحد يا من موقع اتنين يعني انا لما بعمل ال
+
+400
+00:34:00,590 --> 00:34:04,370
+chlorineation على البيوتين كام ناتج كنا متوقعين
+
+401
+00:34:04,370 --> 00:34:08,630
+اللي بيطلع عندنا اتنين المركب الأول اللي بيجيب ال
+
+402
+00:34:08,630 --> 00:34:13,150
+chlorine على موقع واحد هل صار في كايرال سنتر؟ لا
+
+403
+00:34:14,270 --> 00:34:18,910
+تخيلوا لو بدأ أضع الكلور على موقع واحد CH2CL
+
+404
+00:34:43,960 --> 00:34:47,500
+فى كل الأحوال بيصير عندى carol center يعني تخيل لو
+
+405
+00:34:47,500 --> 00:34:50,320
+أنا حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+406
+00:34:50,320 --> 00:34:55,040
+و لو حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+407
+00:34:55,040 --> 00:34:59,820
+اتطلعوا بينهم سواء كعلاقة أو لو حسبتولهم R و S
+
+408
+00:34:59,820 --> 00:35:07,910
+هتلاحظوا ان هدول الاتنين عكس بعض Rانانشو مارزي
+
+409
+00:35:07,910 --> 00:35:13,250
+يعني هاي ال H نفترض CL و بعدين اثلو مثل مبينة R
+
+410
+00:35:13,250 --> 00:35:18,650
+this is S وهي هذي ال H بنشطبها CL مبينة S هاي ال
+
+411
+00:35:18,650 --> 00:35:23,970
+configuration لهدول اذا انا وين اعملت chiral
+
+412
+00:35:23,970 --> 00:35:27,830
+center ع موقع واحد ولا ع موقع اتنين ع موقع اتنين
+
+413
+00:35:27,830 --> 00:35:31,870
+وين بعمل chiral center بطلع عندى خليط من two
+
+414
+00:35:31,870 --> 00:35:36,810
+انانشو مارزيبطلع عندى خليط من two enansimers اذا
+
+415
+00:35:36,810 --> 00:35:40,270
+لو اجيت انا سألتكوا الان سؤال بالمجمل
+
+416
+00:35:40,270 --> 00:35:46,110
+لchlorination of butane كم مركب بيعطينى تلاتة
+
+417
+00:35:46,110 --> 00:35:50,130
+تلاتة تنسوش انه انا في شغل مش كاتبة لأنه خارج
+
+418
+00:35:50,130 --> 00:35:57,190
+الإطار تبعنا انه لو فعلنا على هذا بيعطينا CH2CL
+
+419
+00:35:57,190 --> 00:36:00,450
+اللى هو ال one chlorobutane هذا مافيه chiral
+
+420
+00:36:00,450 --> 00:36:08,390
+centersهذا يبدو يجي الكلورة ع موقع واحد او ع موقع
+
+421
+00:36:08,390 --> 00:36:12,530
+اتنين ع موقع واحد عمل كايرال سنتر اذا هو مركب واحد
+
+422
+00:36:12,530 --> 00:36:16,490
+ع موقع اتنين عمل كايرال سنتر و ايه اللي بيصير
+
+423
+00:36:16,490 --> 00:36:20,790
+كايرال سنتر بيطلع عندى كام مركب اتنين اذا مجموع
+
+424
+00:36:20,790 --> 00:36:25,310
+المركبات قداشر تلاتة طب لو قولتلى واحدة سميلي
+
+425
+00:36:25,310 --> 00:36:27,890
+التلات نواتج اللى بيطلعوا من ال chlorineation و ال
+
+426
+00:36:27,890 --> 00:36:32,010
+butane شو هتقرأواحد كلورو بيوتين واحد كلورو بيوتين
+
+427
+00:36:32,010 --> 00:36:35,930
+ممتازة ارتو
+
+428
+00:36:35,930 --> 00:36:40,970
+كلورو بيوتين و استو كلورو بيوتين فبال total كام
+
+429
+00:36:40,970 --> 00:36:45,810
+مركب طلعوا تلاتة لكن لو كان السؤال كام structural
+
+430
+00:36:45,810 --> 00:36:50,610
+isomer بيطلع عنده من ال chlorineation اتنين لأن
+
+431
+00:36:50,610 --> 00:36:54,710
+معنى structural isomer مواقع الارتباط لكلور يا
+
+432
+00:36:54,710 --> 00:37:00,470
+بترتبط ع واحد يا بترتبط ع اتنينهدولة اتنين stereo
+
+433
+00:37:00,470 --> 00:37:05,390
+isomers ال R2 كلورو بيوتين و ال S2 كلورو بيوتين
+
+434
+00:37:05,390 --> 00:37:09,670
+they have the same bonding الارتباط فيه مع موقع
+
+435
+00:37:09,670 --> 00:37:13,870
+ايش اتنين but different arrangement in space هدولة
+
+436
+00:37:13,870 --> 00:37:18,010
+stereo isomers فبدكوا تنتبهوا لما بنسألكوا في
+
+437
+00:37:18,010 --> 00:37:21,550
+المنطقة لما نيجي نقولكم ال chlorineation في بيوتين
+
+438
+00:37:21,550 --> 00:37:26,670
+producesتو Structural Isomers، الـ Structural
+
+439
+00:37:26,670 --> 00:37:30,770
+مواقع، يا بتيجي الكلور على واحد، يا على اتنين،
+
+440
+00:37:30,770 --> 00:37:35,590
+الآن اللي على اتنين، في منها اتنين Stereoisomers،
+
+441
+00:37:35,590 --> 00:37:43,130
+اللي هم الـR والـS، واضح؟العلى اتنين في منها two
+
+442
+00:37:43,130 --> 00:37:47,750
+stereoisomers الار والاسم طبعا عادة بفسروا هذا
+
+443
+00:37:47,750 --> 00:37:50,870
+الكلام احنا مش اتنين ركزنا على ال mechanism of
+
+444
+00:37:50,870 --> 00:37:55,590
+reaction بفسروا انه هذا التفاعل اول ما بيبدأ
+
+445
+00:37:55,590 --> 00:38:00,410
+بترتفع في ذرة هيدروجين بيصيروا هدولة التلاتة
+
+446
+00:38:00,410 --> 00:38:06,520
+planner في مستوى واحد يعني لو انا بدي اجي اتخيلليش
+
+447
+00:38:06,520 --> 00:38:10,780
+تم التفاعل على الجهتين؟ لما تم التفاعل على
+
+448
+00:38:10,780 --> 00:38:18,200
+الجهتين؟ ممكن ايه بسرعة اريكم باستعمال ال models و
+
+449
+00:38:18,200 --> 00:38:27,360
+بأمل انها ال models بتخدمنا اتخيلوا
+
+450
+00:38:27,360 --> 00:38:33,500
+معنا لو اتخيلنا ان في عندنا CH3 ال CH3 نتخيلهاذرة
+
+451
+00:38:33,500 --> 00:38:39,550
+كربون صمرة CH3تمام؟ لما أشيل H بيبقى عندى كام
+
+452
+00:38:39,550 --> 00:38:44,650
+هيدروجين؟ واحدة و إيش بيبقى عندى؟ مجموعة ال إفل
+
+453
+00:38:44,650 --> 00:38:48,770
+لسه ماجيبتش ال chlorine أنا بدي بهذا كيف بعمل
+
+454
+00:38:48,770 --> 00:38:52,830
+الإبدال؟ بشيل الهيدروجينة في الأول و بعدين بحط
+
+455
+00:38:52,830 --> 00:38:57,250
+بدالها chlorine فدولة كام رابطة حوالين الكربون؟
+
+456
+00:38:57,250 --> 00:38:58,910
+أربعة أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+457
+00:38:58,910 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+458
+00:38:59,790 --> 00:39:06,750
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة
+
+459
+00:39:07,360 --> 00:39:13,760
+بمشي الحال هاي هذا صار بهذا الشكل بالظبط طلعوا في
+
+460
+00:39:13,760 --> 00:39:20,740
+مجموعة مثل و H و إثل و ال H الأخيرة شيلناها
+
+461
+00:39:20,740 --> 00:39:24,240
+رفعناها الآن بدنا نجيب ال chlorine تتفاعل
+
+462
+00:39:26,450 --> 00:39:29,650
+هذه الـ Intermediate للحظة برفعت الـ H الأولى
+
+463
+00:39:29,650 --> 00:39:33,330
+بلانر في مستوى واحد الكلور بإمكانها تيجي تهاجم
+
+464
+00:39:33,330 --> 00:39:37,470
+عليها من هنا و هدولا بتعجوا حلو ميك او من هنا
+
+465
+00:39:37,470 --> 00:39:43,910
+طالما انها بلانر في فرق ان الكلور هي جاية من بعيد
+
+466
+00:39:43,910 --> 00:39:49,130
+بفرق عندها انها تمشي من هنا او من هنا اطلع معي
+
+467
+00:39:49,130 --> 00:39:52,670
+شايفين هدول الممرين اللي في القاعة لو انا بدي اروح
+
+468
+00:39:52,670 --> 00:39:59,700
+لاخر نقطةبإمكاني أمشي من هنا و من هنا بشكل متساوي
+
+469
+00:39:59,700 --> 00:40:04,520
+ولا لأ؟ ماعندي مشكلة، بدي أروح لآخر نقطة وهي عندي
+
+470
+00:40:04,520 --> 00:40:08,240
+مصارين متكافئت كذلك الحال، هذا planner بدي تيجي
+
+471
+00:40:08,240 --> 00:40:12,200
+اكلور من برا تتفاعل عليه، ترد تعمل المجموعة
+
+472
+00:40:12,200 --> 00:40:16,180
+الرابعةإذا أتيت من هنا عملة انانشومر و إذا أتيت من
+
+473
+00:40:16,180 --> 00:40:20,660
+هنا عملة التاني الان من ناحية الاحتمالات متساوية
+
+474
+00:40:20,660 --> 00:40:25,440
+تماما و لذلك يظهر عندي راسيمك ميكسشر يعني يظهر
+
+475
+00:40:25,440 --> 00:40:30,220
+الاتنين و يظهرون بنسب متساوية يظهر الاتنين و
+
+476
+00:40:30,220 --> 00:40:34,100
+يظهرون بنسب متساوية فبصير المحصلة ان ال generation
+
+477
+00:40:34,100 --> 00:40:42,710
+of a chiral center produces راسيمك ميكسشرواضح؟ ال
+
+478
+00:40:42,710 --> 00:40:46,690
+generation of a chiral center produces a racemic
+
+479
+00:40:46,690 --> 00:40:53,110
+mixture الان لو قلنا بدل racemic mixture equal
+
+480
+00:40:53,110 --> 00:40:59,740
+number of enantiomers أكيد صح .. أكيد صحgeneration
+
+481
+00:40:59,740 --> 00:41:02,520
+of a chiral center produces racemic mixtures
+
+482
+00:41:02,520 --> 00:41:10,660
+لاحظوا هذه الجملة بالنسبة للكيميا ما بين الكيميا
+
+483
+00:41:10,660 --> 00:41:15,480
+اللي بيصنعوها البشر و ما بين خلق الله سبحانه
+
+484
+00:41:15,480 --> 00:41:21,070
+وتعالى بتعمل فرق كبير جدااليوم لما انا باجي في
+
+485
+00:41:21,070 --> 00:41:26,450
+المختبر بده احضر مركب و اعمل chiral center انا
+
+486
+00:41:26,450 --> 00:41:31,290
+مابتحكمش في الاحتمالات بطلع عندى خليط متساوي و
+
+487
+00:41:31,290 --> 00:41:36,090
+بعدين اتعب و افصله و هذا السبب ربما في انه في دوة
+
+488
+00:41:36,090 --> 00:41:41,360
+مثل الثاليدواميد كان بيطلع الخليطالمتساوي ال R و
+
+489
+00:41:41,360 --> 00:41:45,860
+ال S لمنهم واحد مفيد و واحد ضار و عمل مشاكل كتير
+
+490
+00:41:45,860 --> 00:41:50,160
+كل ما بشغل في المختبر المختبر بطلعلي خليط من
+
+491
+00:41:50,160 --> 00:41:52,940
+المركبين اذا مش عندى chiral center انا بدي اعمله
+
+492
+00:41:52,940 --> 00:41:57,460
+بطلعلي .. بطلعلي ايش؟ racemic mixture الان في
+
+493
+00:41:57,460 --> 00:42:02,570
+الطبيعة فيه انزيماتالانزيمات كأنها بتاخد بإيدي
+
+494
+00:42:02,570 --> 00:42:05,850
+المجموعة اللي جاية بالظبط بداخلها من جهة واحدة
+
+495
+00:42:05,850 --> 00:42:10,030
+ولذلك المنتجات الطبيعية بيطلع منها بس one in a
+
+496
+00:42:10,030 --> 00:42:16,750
+number هذا خلقههذا خلق الله يعني انا لما شغلة كون
+
+497
+00:42:16,750 --> 00:42:21,210
+بتحضرها الانزيمات و بتتحضر جوا الجسم بتلاقوا بيطلع
+
+498
+00:42:21,210 --> 00:42:26,330
+منها بس واحد لما اجي انا اعيد التفاعل بالمختبر و
+
+499
+00:42:26,330 --> 00:42:30,110
+بدون انزيمات و بكذا بيطلع عندى خليط متساوي من
+
+500
+00:42:30,110 --> 00:42:34,830
+التنين ولذلك اللى بده مركبات نقية يعني بده one in
+
+501
+00:42:34,830 --> 00:42:39,750
+one شمر ايش اسهل طريقة يعملها؟ ياخدها من مصادرها
+
+502
+00:42:39,750 --> 00:42:44,590
+الطبيعية اذا كانت تحضر في الطبيعةطبعا إذا كانت لا
+
+503
+00:42:44,590 --> 00:42:51,850
+تحضر في الطبيعة بده يجعب هذه المشكلة و يطلع عنده
+
+504
+00:42:51,850 --> 00:42:56,450
+خليط من التنين عشان ايه كده في الكيميا بيسموه ايش
+
+505
+00:42:56,450 --> 00:43:02,990
+Symmetric Synthesis Symmetric Synthesis ايش معنى
+
+506
+00:43:02,990 --> 00:43:08,350
+Symmetric انه بيطلع خليط متمافل من التنين جد بعض و
+
+507
+00:43:08,350 --> 00:43:15,290
+بعدين يقعد ايش يعمليفصل فيهم الآن بدأوا من جديد
+
+508
+00:43:15,290 --> 00:43:21,030
+يستعملوا طرق حديثة في ال synthesis و يضيفوا عوامل
+
+509
+00:43:21,030 --> 00:43:25,330
+حفازة اللي تخلى واحد من هدول يطلع بنسبة اكتر من
+
+510
+00:43:25,330 --> 00:43:30,490
+التانية او يكاد يكون يطلع نقي وجدتها اذا طلعوا مش
+
+511
+00:43:30,490 --> 00:43:35,790
+متساويات شو بدى اسم ال synthesis Asymmetric
+
+512
+00:43:35,790 --> 00:43:40,010
+synthesisواضح؟ يعني الـ symmetric synthesis بتطلع
+
+513
+00:43:40,010 --> 00:43:44,810
+الخليط متساوي الآن إذا صرت أضيف عوامل حفازة بطرق
+
+514
+00:43:44,810 --> 00:43:49,290
+معينة بتحذيرات بصير أشتغل ايش؟ asymmetric
+
+515
+00:43:49,290 --> 00:43:52,910
+synthesis اليوم اللي منكم بده تدرس كيميا وبعدين
+
+516
+00:43:52,910 --> 00:43:57,120
+تقول أنا بدي أخد جائزة نوبل في الكيمياBye Bye
+
+517
+00:43:57,120 --> 00:44:01,260
+Asymmetric Synthesis بدا تشتغل على ايش؟ Asymmetric
+
+518
+00:44:01,260 --> 00:44:05,420
+Synthesis تصير تتعلم كتير تضيف عوامل حفازة
+
+519
+00:44:05,420 --> 00:44:12,040
+بمواصفات معينة تخلي التفاعل تطلع واحدمايطلعش
+
+520
+00:44:12,040 --> 00:44:16,200
+التاني او طلع واحد مثلا بنسبة 90% و التاني بنسبة
+
+521
+00:44:16,200 --> 00:44:20,800
+10% على سبيل المثال و كل ما جدت تطلع واحد تماما و
+
+522
+00:44:20,800 --> 00:44:26,500
+تلغي التاني كل ما كانت تمثل ايش نجاح كبير في الشغل
+
+523
+00:44:26,500 --> 00:44:31,720
+افهمنا اذا المشكلة ما بين الطبيعة و ما بين المختبر
+
+524
+00:44:31,720 --> 00:44:36,380
+المختبر هو وضع الطبيعيبطلّع لي خليط الطبيعة بوضعها
+
+525
+00:44:36,380 --> 00:44:42,120
+الطبيعي بطلّع واحد الان العالم بيسعوا نحو ايش؟ ان
+
+526
+00:44:42,120 --> 00:44:45,960
+يقتربوا من الطبيعة انهم يقدروا يطلعوا واحد و لو
+
+527
+00:44:45,960 --> 00:44:51,120
+بنسبة كبيرة في ما يسمى بالعلم ايش؟ asymmetric
+
+528
+00:44:51,120 --> 00:44:55,620
+synthesis بس بالتأكيد هذا الموضوع كتير متطور
+
+529
+00:44:55,620 --> 00:44:59,860
+بالنسبة لطالب organic يعني ما لم تتخصصوا كيميا مش
+
+530
+00:44:59,860 --> 00:45:02,460
+هتشتغلوا فيه بنكمل ان شاء الله في مرات
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..864b835533104ec7e59ec3855116960bf3f85565
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/1TcAfdTqDds_raw.srt
@@ -0,0 +1,2128 @@
+1
+00:00:20,690 --> 00:00:24,750
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry
+
+2
+00:00:24,750 --> 00:00:29,730
+ربما المرة الماضية نوّهنا من خلال أنفلة تطبيقية من
+
+3
+00:00:29,730 --> 00:00:36,970
+خلال أهمية فهم ال stereo isomers في الحياة العملية
+
+4
+00:00:36,970 --> 00:00:42,990
+أن هذا موضوع مهم ولذلك شوية بنظل نتوسع فيه بعد ما
+
+5
+00:00:42,990 --> 00:00:46,830
+أخدنا المركبات اللي فيها one chiral center قولنا
+
+6
+00:00:46,830 --> 00:00:51,610
+ال one chiral center بيعتق فقطtwo isomers بعد ذلك
+
+7
+00:00:51,610 --> 00:00:56,690
+إذا زاد العدد بيبدأوا يزيدوا ال isomers طبعا بيحكم
+
+8
+00:00:56,690 --> 00:01:00,890
+الأمر المعادلة two to the n لكن ال two to the n
+
+9
+00:01:00,890 --> 00:01:05,230
+هذا أقصى عدد ممكن من ال isomers في كل الأحوال ممكن
+
+10
+00:01:05,230 --> 00:01:10,290
+يكون العدد أقل من هيك وقلنا هنعطي مثال على العدد
+
+11
+00:01:10,290 --> 00:01:15,330
+الأقصى ومثال على وانتش العدد بيصير أقل في حالة ما
+
+12
+00:01:15,330 --> 00:01:20,620
+عندنا two chiral centersبدأنا في مثال كنا عادة
+
+13
+00:01:20,620 --> 00:01:25,140
+ناخده على أنه مثال بسيط يعني الفكره مركب واحد لما
+
+14
+00:01:25,140 --> 00:01:29,620
+نيجي نقول two three dichloro بنتين بالفكره مركب
+
+15
+00:01:29,620 --> 00:01:33,640
+واحد لكن لما بنيجي نتطلع على موقع اتنين وعلى موقع
+
+16
+00:01:33,640 --> 00:01:39,410
+تلاتةبنلاحظ ان الاتنين they are chiral centers
+
+17
+00:01:39,410 --> 00:01:42,750
+وبناء على ذلك بنبدأ نتوقع انه كام مركبة بيصير
+
+18
+00:01:42,750 --> 00:01:48,890
+عندنا اربع مركبات جربنا نرسمهم من خلال انه نتخيل
+
+19
+00:01:48,890 --> 00:01:52,010
+مثلا بدنا ناخد السلسلة الكربونية بهذا الشكل يعني
+
+20
+00:01:52,010 --> 00:01:56,970
+الخمس كربونات واحد اتنين تلاتة و الاثلاربعة خمسة
+
+21
+00:01:56,970 --> 00:02:01,390
+CH2 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+22
+00:02:01,390 --> 00:02:06,770
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+23
+00:02:06,770 --> 00:02:08,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+24
+00:02:08,170 --> 00:02:08,950
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+25
+00:02:08,950 --> 00:02:09,750
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+26
+00:02:09,750 --> 00:02:10,270
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+27
+00:02:10,270 --> 00:02:11,790
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+28
+00:02:11,790 --> 00:02:13,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+29
+00:02:13,190 --> 00:02:23,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+30
+00:02:23,190 --> 00:02:27,670
+CH3 CHيعني ال R عكسة S ال R عكسة S كلام منطقي الان
+
+31
+00:02:27,670 --> 00:02:32,110
+لو جينا نطلع على المركب الثاني two R three S هذا
+
+32
+00:02:32,110 --> 00:02:37,870
+عكسه ال R اقبلها S ال S اقبلها R لأنه دائما صورة
+
+33
+00:02:37,870 --> 00:02:43,590
+بعض في المرأة بتعني التعاكس التام فلو احنا سألنا
+
+34
+00:02:43,590 --> 00:02:48,170
+ايش العلاقة بين واحد و اتنين they are enantiomersو
+
+35
+00:02:48,170 --> 00:02:52,290
+بيصير مفهوم عندنا ان اي مركبة لما نقول عنهم in
+
+36
+00:02:52,290 --> 00:02:58,650
+anchors بدتكون اشاراتهم عكس بعض الان طبعا انتوا
+
+37
+00:02:58,650 --> 00:03:02,390
+بالنظر بتقولوا صورة بعض في المرأة غير متطابقة لكن
+
+38
+00:03:02,390 --> 00:03:08,390
+ماتنسوش شغلة ان انا بإمكاني ارسم
+
+39
+00:03:09,150 --> 00:03:13,850
+المُركّب بطرق مختلفة بحيث أنه انتوا بمجرد النظر
+
+40
+00:03:13,850 --> 00:03:18,430
+البسيط ما تقدروش تتاخدوا قرار من النظر وجهة القرار
+
+41
+00:03:18,430 --> 00:03:21,750
+الأكيد بتقدروا تتاخدوا من إيش في علاقة بين
+
+42
+00:03:21,750 --> 00:03:29,110
+المُركّبين من قيم A و S خليني أؤكد الفكرة هذه لو
+
+43
+00:03:29,110 --> 00:03:34,310
+فقط أنا بدي أشغل معكم على مُركّب في one chiral
+
+44
+00:03:34,310 --> 00:03:40,470
+centerلو رسمت منه شكلين شو الاحتمالات المتوقعين
+
+45
+00:03:40,470 --> 00:03:43,610
+لما يكون عندي one chiral center؟ يا بده يكون
+
+46
+00:03:43,610 --> 00:03:48,910
+المركب نفسه رسمه بطريقتين مختلفة يا بده يكون in
+
+47
+00:03:48,910 --> 00:03:51,410
+anchormers ماعندي احتمال تاني
+
+48
+00:03:53,870 --> 00:04:01,450
+أخذ بسرعة عشوائيا هاي مركّب CH3CLPR وهي مركّب كتبت
+
+49
+00:04:01,450 --> 00:04:08,010
+هنا ال PR وهنا ال H وهنا ال CL وهنا ال CH3 لاحظوا
+
+50
+00:04:08,010 --> 00:04:12,610
+هدول المركّبين لو سألتكم ما العلاقة بينهما اللي
+
+51
+00:04:12,610 --> 00:04:16,030
+بده تيجي تتطلع تشوف أي شيء بالنظر و المرايا و
+
+52
+00:04:16,030 --> 00:04:22,100
+بنطبقه و مابنطبقوش حتىمش هتقدر، لأنه أنا أرسمهم
+
+53
+00:04:22,100 --> 00:04:25,640
+بطرق مختلفة، ماحدش بيمنعني أرسمهم بطرق مختلفة،
+
+54
+00:04:25,640 --> 00:04:31,700
+الآن أسهل شيء أن أحدد لكل مركب R أو S، الآن إذا
+
+55
+00:04:31,700 --> 00:04:35,500
+هذا طلع R و هذا R، معنى ذلك نفس المركب مرسوم بطرق
+
+56
+00:04:35,500 --> 00:04:40,800
+مختلفة، S و S نفس المركبإذا هذا R و هذا S, they
+
+57
+00:04:40,800 --> 00:04:44,140
+are enantiomers إذا هذا S و هذا R, they are
+
+58
+00:04:44,140 --> 00:04:48,260
+enantiomers هيكا بيكون أسهل طريقة أن أعملهم ولذلك
+
+59
+00:04:48,260 --> 00:04:54,380
+لو بدي أجي أطلع لهذا أقل مجموع ال H ب RCLCH3 من
+
+60
+00:04:54,380 --> 00:05:00,660
+بين R S لأن هذا ال H للأمام الآن لو بدي أطلع
+
+61
+00:05:00,660 --> 00:05:12,780
+المركب الثاني ب R CL SCH3 بين R مرة تانية وبنخليها
+
+62
+00:05:12,780 --> 00:05:18,100
+R لأن ال H للخلف هدول الانشو مارس طالما واحد قسي
+
+63
+00:05:18,100 --> 00:05:21,380
+التاني R إذا we are in ancho mars فالانشو مارس
+
+64
+00:05:21,380 --> 00:05:25,040
+دايما عكس بعض الان لو عندكوا خمسة كايرة ال centers
+
+65
+00:05:25,040 --> 00:05:29,520
+مش واحدإيش بتكون في الخمسة يكونوا عشان يكونوا
+
+66
+00:05:29,520 --> 00:05:35,300
+مركبين انانشومارز؟ كل واحد عكس التاني زي أنا باجف
+
+67
+00:05:35,300 --> 00:05:38,420
+قدام المرايا، الإيدين عكس بعض، الوش عكس بعض، البطن
+
+68
+00:05:38,420 --> 00:05:42,060
+عكس بعض، الرجلين عكس بعض، كل شيء بيكون عكس التاني،
+
+69
+00:05:42,060 --> 00:05:45,120
+يعني لو عندي ان شاء الله عشرين Cairo Center في
+
+70
+00:05:45,120 --> 00:05:49,600
+مركب، الانانشومارز تبعه، العشرين المقابلات بيكونوا
+
+71
+00:05:49,600 --> 00:05:56,300
+عكسهم، لو واحدة منهم اختلتببطلوا in anchormers على
+
+72
+00:05:56,300 --> 00:05:59,840
+طول ببطلوا صورة بعض في المرآة إذا بطلوا صورة بعض
+
+73
+00:05:59,840 --> 00:06:04,700
+في المرآة، شو بدوا يصيروا؟ ديستيريومارز، تنسوش إن
+
+74
+00:06:04,700 --> 00:06:08,740
+احنا عرفنا الديستيريومارز، they are non-mirror
+
+75
+00:06:08,740 --> 00:06:12,580
+image in anchormers ولذلك لو أنا سألت العلاقة بين
+
+76
+00:06:12,580 --> 00:06:20,780
+هدول، خلّينا نوضحها باسم RS عكس بعضعكس بعض اذا
+
+77
+00:06:20,780 --> 00:06:24,580
+they are enansimals واضح؟ الان لو سئلت هدول
+
+78
+00:06:24,580 --> 00:06:33,560
+الاتنين RS SR عكس طلع عليهم R اقبلها S S اقبلها R
+
+79
+00:06:33,560 --> 00:06:39,320
+عكس بعض they are enansimals الان لو اجيت اخدت مثلا
+
+80
+00:06:39,320 --> 00:06:49,160
+المركب واحد مع تلاتة اتطلعوا R وRهدولا متل بعض و
+
+81
+00:06:49,160 --> 00:06:56,860
+are و us عكس بعض هل هدولا عكس بعض بالكامل؟ لأ
+
+82
+00:06:56,860 --> 00:07:01,500
+هدولا متل بعض بالكامل؟ لأ مالو كانوا عكس بعض
+
+83
+00:07:01,500 --> 00:07:04,560
+بالكامل يعني كل نقطة عكس التانية they are
+
+84
+00:07:04,560 --> 00:07:10,000
+enantiomers الان لو كل نقطة زي التانية they are
+
+85
+00:07:10,000 --> 00:07:14,600
+the same compoundلو كل نقطة زي التانية هو نفس
+
+86
+00:07:14,600 --> 00:07:20,760
+المُركّب الـ R إيش زي بعض و إيش عكس بعض بطلوا صورة
+
+87
+00:07:20,760 --> 00:07:24,400
+بعض في المرأة أو بطلوا نفس المُركّب إيش هيصفه؟ ده
+
+88
+00:07:24,400 --> 00:07:28,180
+الـ Stereomers إذا لما بنيجي نتطلع إنه بدنا نفهم
+
+89
+00:07:28,180 --> 00:07:32,260
+العلاقة بين مُركّبين من خلال الرموز هنقول إنه
+
+90
+00:07:32,260 --> 00:07:36,260
+عندنا تلت احتمالات في حالة ما عندي أكتر من chiral
+
+91
+00:07:36,260 --> 00:07:40,600
+center لحظة لما كان عندي one chiral centerبدون ما
+
+92
+00:07:40,600 --> 00:07:44,080
+أعمل R و S بقولكوا عندي احتمالين يا بدهم يكونوا
+
+93
+00:07:44,080 --> 00:07:50,120
+نفس المركب R R S S يا بدهم يكونوا Enansi و Mars S
+
+94
+00:07:50,120 --> 00:07:54,840
+R أو R S الان لو كان عندي more than one chiral
+
+95
+00:07:54,840 --> 00:07:57,960
+center عندي تلت احتمالات الاحتمال الاول بدهم
+
+96
+00:07:57,960 --> 00:08:03,440
+يكونوا Enansi و Mars كل شيء عكس بعض الاحتمال
+
+97
+00:08:03,440 --> 00:08:09,150
+التاني انهم يكونوا نفس المركب كل شيء نفسهزي بعض طب
+
+98
+00:08:09,150 --> 00:08:12,950
+لو طلع شيء عكس و شيء زي بعض وجدت دي R ده يستيريو
+
+99
+00:08:12,950 --> 00:08:18,370
+مارس لحظوا الآن لو اجيت على واحد و تلاتة R و S عكس
+
+100
+00:08:18,370 --> 00:08:23,670
+بعض R و R زي بعض اذا هدولة صورت بعض في المرقاة لأ
+
+101
+00:08:23,670 --> 00:08:28,530
+نفس المركب لأ ر ده يستيريو مارس اذا واحد و تلاتة
+
+102
+00:08:28,530 --> 00:08:31,970
+ده يستيريو مارس لو طبقته مرة تانية على واحد و
+
+103
+00:08:31,970 --> 00:08:39,700
+أربعة مثلا ما العلاقة بينهم Rو S عكس بعض، هم
+
+104
+00:08:39,700 --> 00:08:47,540
+لاحظين؟ R و R نفس بعض، they are diastereomers لو
+
+105
+00:08:47,540 --> 00:08:52,720
+إجينا اتطلعنا على اتنين و تلاتة،
+
+106
+00:08:52,720 --> 00:09:02,010
+لاحظوا؟ S و Rعكس بعض السؤاس زي بعض كذلك الحال لو
+
+107
+00:09:02,010 --> 00:09:08,070
+اتطلعت اتنين اربع السؤاس نفس الاشي السؤاد عكس بعض
+
+108
+00:09:08,070 --> 00:09:13,230
+they are diastereomers واضح؟صار عندى نوع تانى من
+
+109
+00:09:13,230 --> 00:09:17,590
+الدياستيريو مارز جاي من وين جاي من المركبات فيها
+
+110
+00:09:17,590 --> 00:09:20,910
+chiral centers يعني احنا اول ما أخدنا تعريف
+
+111
+00:09:20,910 --> 00:09:25,270
+الدياستيريو مارز قولنا كل شيء مش صورة بعض في
+
+112
+00:09:25,270 --> 00:09:29,500
+المرقاة they are diastereomarsالأمثلة الكيميائية
+
+113
+00:09:29,500 --> 00:09:33,820
+الأولى اللى أخدناها شو هي الـ Cis والـ Trans أو
+
+114
+00:09:33,820 --> 00:09:37,300
+الـ Z والـ E they are diastereomers الآن بيجينا
+
+115
+00:09:37,300 --> 00:09:40,900
+أمثلة تانية لما يكون عندى more than one chiral
+
+116
+00:09:40,900 --> 00:09:45,160
+center هذه الأمثلة بتقول القاتل انه لو كان في عندى
+
+117
+00:09:45,160 --> 00:09:51,530
+مركبين في الإشارات تبعتهممش زي بعض تماما، مش نفس
+
+118
+00:09:51,530 --> 00:09:54,650
+المُركّب، ولا Inansiomers و they are
+
+119
+00:09:54,650 --> 00:10:00,010
+stereoisomers، إيش هيصفهم؟ ديستيريو مارس، واضح؟
+
+120
+00:10:00,010 --> 00:10:05,270
+وبهيك أخدنا إن الديستيريو مارس بكم ما كان، بنشوفهم
+
+121
+00:10:05,270 --> 00:10:11,460
+بالكيميامكالين بال CC trans او ZE و بال chiral
+
+122
+00:10:11,460 --> 00:10:15,680
+compounds او بال stereo chemistry لما يكون عندى
+
+123
+00:10:15,680 --> 00:10:21,440
+اكتر من chiral center بشرط انه ننتبه ل ROS
+
+124
+00:10:21,440 --> 00:10:27,760
+بالطريقة اللى اتكلمنا فيها الان طالما ان هدولةالهم
+
+125
+00:10:27,760 --> 00:10:31,760
+إشارات مختلفة فى كام مركب عندى لتو ثري دايكلورو
+
+126
+00:10:31,760 --> 00:10:36,180
+بنتين أربعة هى رموزهم اللى بدى تروح تشتريهم من
+
+127
+00:10:36,180 --> 00:10:39,800
+السوق هتلاقيهم أربعة مركبات الآن احنا قولنا ممكن
+
+128
+00:10:39,800 --> 00:10:46,760
+يكون العدد أقل ناخد مثالهذا المثال 2,3
+
+129
+00:10:46,760 --> 00:10:51,800
+-dichlorobutane قال ذرة كربون واحدة يعني لو انا
+
+130
+00:10:51,800 --> 00:10:56,080
+رسمت هاي كربون تنتين تلاتة اربعة اذا المركب اللي
+
+131
+00:10:56,080 --> 00:11:02,100
+عندى ايش بيوتين واضح لاحظوا ايش بيفرق يعني كتير
+
+132
+00:11:02,100 --> 00:11:09,120
+لبيوتين عنالبنتين لو انا مجرد ان كتبت كتابة مثل
+
+133
+00:11:09,120 --> 00:11:17,800
+CH3 CHCl CHCl CH3 عارفين شو بيفرق؟ لو انا اتيت بين
+
+134
+00:11:17,800 --> 00:11:20,840
+هدولة الـ chiral centers التنين الكاربونز اللي
+
+135
+00:11:20,840 --> 00:11:26,760
+حاملة كلور و جسمت المركب من النصتطلعوا هنا إيش
+
+136
+00:11:26,760 --> 00:11:33,460
+اللي موجود Carbon حاملة HCl و بعدها CH3 و هنا
+
+137
+00:11:33,460 --> 00:11:39,240
+Carbon حاملة HCl و بعدها CH3 إذا هذا المركب صار
+
+138
+00:11:39,240 --> 00:11:44,460
+مركب متماثل قبل شوية لما كنت .. أو من هنا على هذا
+
+139
+00:11:44,460 --> 00:11:49,800
+الشكل أجسم زي هيك تطلعوا كأعداد ذراتماذا عندكم
+
+140
+00:11:49,800 --> 00:11:54,980
+هنا؟ كاربون حاملة HCl وCH3 وهنا كاربون حاملة HCl
+
+141
+00:11:54,980 --> 00:12:01,860
+وCH3 فعدد الذرات اللي بهذا الاتجاه هو نفسه عدد
+
+142
+00:12:01,860 --> 00:12:05,760
+الذرات اللي بهذا الاتجاه فهذا الكاربون بيحمل نوع
+
+143
+00:12:05,760 --> 00:12:10,380
+من التماثل هذا الكلام في المثال السابق ماكانش لما
+
+144
+00:12:10,380 --> 00:12:16,160
+كنتوا تحطوا خط هنابين ال two chiral centers عدولي
+
+145
+00:12:16,160 --> 00:12:22,780
+كل الذرات اللي هتشومها C وH وCL و CH3 و هنا CH وCL
+
+146
+00:12:22,780 --> 00:12:29,460
+و بعدها CH2 CH3 إذا هل هذا النص زي هذا النص لأ في
+
+147
+00:12:29,460 --> 00:12:34,910
+حالة البيوتينأ لبيوتين في تماثل داخلي بين ال two
+
+148
+00:12:34,910 --> 00:12:39,790
+chiral centers يعني المركب سيماتريك الآن لو إجينا
+
+149
+00:12:39,790 --> 00:12:44,310
+جربنا نرسم ال isomers بنفس الطريقة اللي اتعلمناها
+
+150
+00:12:44,310 --> 00:12:51,270
+سابقا يعني أجي أحط تنتين كلور عكس بعض و صورتهم في
+
+151
+00:12:51,270 --> 00:12:54,810
+المرأة و تنتين كلور على جهة واحدة و صورتهم في
+
+152
+00:12:54,810 --> 00:13:02,210
+المرأة و بعدين أحدد R و Sلاحظوا هذه الرسمة تماما
+
+153
+00:13:02,210 --> 00:13:06,510
+هي نسخ و لصق من الرسمة السابقة بس بدل ما كنا
+
+154
+00:13:06,510 --> 00:13:12,890
+كاتبين هنا اثل كتبنا مثل واضح؟ و لذلك انتوا الان
+
+155
+00:13:12,890 --> 00:13:20,310
+كام مركب بتشوفه؟مازالتوا بتشوفوا أربع مركبات
+
+156
+00:13:20,310 --> 00:13:26,150
+للوهلة الأولى لكن لو نظرنا بعمق لهدولة الأربع
+
+157
+00:13:26,150 --> 00:13:32,130
+مركبات هلاحظ ان هذا 2R3R و هذا 2S3S
+
+158
+00:13:34,300 --> 00:13:40,660
+عكس بعض هتيجوا تستنتجوا انهم انانشومارز فش اننا
+
+159
+00:13:40,660 --> 00:13:45,160
+خلاف الآن لما بتيجوا تطلع على المركبين التانيين
+
+160
+00:13:45,160 --> 00:13:49,140
+وخلونا نقول .. نقولنا الترقيم واحد اتنين تلاتة
+
+161
+00:13:49,140 --> 00:13:55,720
+اربعة واحد اتنين تلاتة اربعة و هيناخد واحدة بس
+
+162
+00:13:55,720 --> 00:14:01,560
+نأكد هي ال CL نمرة واحدوهذه ال carbon الحاملة Cl2
+
+163
+00:14:01,560 --> 00:14:09,860
+و CH3 بين S كتبناها R وهذه لو بدنا نتطلع عليها 1 2
+
+164
+00:14:09,860 --> 00:14:16,300
+Cl بعدين carbon حاملة Cl بعدين CH3 Cl بعدين carbon
+
+165
+00:14:16,300 --> 00:14:21,100
+حاملة Cl بعدين CH3 بين R كتبنا S إذا هيك مظبوطين
+
+166
+00:14:21,100 --> 00:14:25,900
+هدولة two R three Sلو اعملنا المركب التاني لجبانو
+
+167
+00:14:25,900 --> 00:14:30,260
+بين two as three are اي حد هيتطلع بهذا الشكل
+
+168
+00:14:30,260 --> 00:14:33,800
+البصير شو هيقول هدول العلاقة بينهم they are
+
+169
+00:14:33,800 --> 00:14:36,760
+enantiomers الان بنقول لأ they are the same
+
+170
+00:14:36,760 --> 00:14:42,420
+compound هتبدو يصير عندكم مشكلة ليش لأنه هتقولوا
+
+171
+00:14:42,420 --> 00:14:47,540
+انت لسه توت و التصوير شاهد علينا كمان بتقول انه
+
+172
+00:14:47,540 --> 00:14:55,020
+اذا كل شيء عكس بعضهthey are enantiomers هاي مثال و
+
+173
+00:14:55,020 --> 00:14:59,320
+فيها دول عكس بعض لكن أنا قاعد بقول عنهم they are
+
+174
+00:14:59,320 --> 00:15:05,060
+the same compound كيف هذا الكلام بيصير؟ هل يا ترى
+
+175
+00:15:05,060 --> 00:15:09,520
+الإنسان بناقض في الحكي ولا لأ؟ الحقيقة في سبب و
+
+176
+00:15:09,520 --> 00:15:15,240
+الأمر هنابحاجة إلى نظرة شوية متعمقة .. بحاجة إلى
+
+177
+00:15:15,240 --> 00:15:19,380
+نظرة شوية متعمقة بين هدول الصورتين تحديدا لو
+
+178
+00:15:19,380 --> 00:15:23,140
+اتخيلتوا انتوا .. لو اتخيلتوا ان انتوا حاطيتوا
+
+179
+00:15:23,140 --> 00:15:26,660
+دبوس هنا مسيكتوا هذا المركب بعدين لفتوه بهذا الشكل
+
+180
+00:15:26,660 --> 00:15:30,980
+طلعوا معايا مرة تانية كأنه هنا فيه محور و الف
+
+181
+00:15:30,980 --> 00:15:35,640
+المركب بهذا الشكل وين هتيجي هذه ال CH3 وين هتطلع
+
+182
+00:15:35,640 --> 00:15:41,720
+هذه ال CL تنتين وين هييجوا ال Hهيصيروا نفس هذا
+
+183
+00:15:41,720 --> 00:15:48,580
+المُركّب ولا لأ؟ نفس المُركّب واضح؟ بهذا الشكل
+
+184
+00:15:48,580 --> 00:15:54,420
+لفوه هاي الـ CLE جوهان و الـ H3 و الـ CH3 انعكسوا
+
+185
+00:15:54,420 --> 00:16:00,660
+ممكن واحدة تيجي تقولي ما كان لفت اللي قبله خليني
+
+186
+00:16:00,660 --> 00:16:05,680
+أرجع للي قبله اللي قبله ماكانش متمثل يعني لما ألف
+
+187
+00:16:05,680 --> 00:16:12,140
+شو بده ينزل هنا CH3 شو بده يطلع هنا؟صح لما انا هاد
+
+188
+00:16:12,140 --> 00:16:15,140
+و بدى ألف و هيك ال CL's و ال H's بيجوا مكان بعض
+
+189
+00:16:15,140 --> 00:16:19,940
+لكن محل ال Ethel شو بتيجي؟ محل ال Ethel مثل هذه
+
+190
+00:16:20,690 --> 00:16:26,010
+املاحظين يعني هذا لو لفته بينطبق على هذا لأ بينما
+
+191
+00:16:26,010 --> 00:16:30,910
+اللي بعده بينطبق ماسبب الانطباق في الحالة التالية
+
+192
+00:16:30,910 --> 00:16:34,390
+و عدم الانطباق في الحالة الأولى انه هذا في الحالة
+
+193
+00:16:34,390 --> 00:16:39,970
+هذه غير متماثل داخليا يعني هذه CH3 هذه اتل مش هذا
+
+194
+00:16:39,970 --> 00:16:47,410
+النص زي هذا بينما في المركب اللي بعده هذا متماثل
+
+195
+00:16:48,570 --> 00:16:51,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+196
+00:16:51,090 --> 00:16:58,750
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+197
+00:16:58,750 --> 00:16:59,530
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+198
+00:16:59,530 --> 00:17:00,070
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+199
+00:17:00,070 --> 00:17:00,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+200
+00:17:00,090 --> 00:17:00,210
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+201
+00:17:00,210 --> 00:17:00,910
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+202
+00:17:00,910 --> 00:17:00,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+203
+00:17:00,950 --> 00:17:01,730
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+204
+00:17:01,730 --> 00:17:13,310
+مثل مثل
+
+205
+00:17:13,310 --> 00:17:17,470
+مثل مثالـR و الـS اللي مبينين عكس بعض كيف بدنا نحل
+
+206
+00:17:17,470 --> 00:17:23,450
+مشكلتهم لأن احنا قلنا إذا كل شي عكس بعض لازم نصنف
+
+207
+00:17:23,450 --> 00:17:28,970
+المراكبات in anchors طب هي مبينين عكس بعض آه مديش
+
+208
+00:17:28,970 --> 00:17:33,990
+تنسوا شغلة هذا المراكب لو أنا جبته لكم في الامتحان
+
+209
+00:17:33,990 --> 00:17:39,610
+و قلتلكم سموهو إجت واحدة منكم اتطلعت فيه و حطت
+
+210
+00:17:39,610 --> 00:17:46,850
+ترقيم 1234 صار هذا موقع 2 و عملته لجته 2R هذا موقع
+
+211
+00:17:46,850 --> 00:17:53,050
+3 و عملته لجته 3S طيب لو واحدة تانية إجت و قالت
+
+212
+00:17:53,050 --> 00:18:00,930
+خليني أرقم من تحت ما هو متمثل هاي 1234 ع 23 أيضا
+
+213
+00:18:01,530 --> 00:18:06,510
+Echlor, إذا هذا بترقم من كام جهة؟ من الجهتين نفس
+
+214
+00:18:06,510 --> 00:18:11,230
+الشيء هذا بترقم من الجهتين نفس الشيء المركب اللي
+
+215
+00:18:11,230 --> 00:18:16,230
+جابي اللي بقدرش أعمل فيه هذا الكلام بدي أكو أتضالك
+
+216
+00:18:16,230 --> 00:18:22,490
+و أتقرره لو كنت بده أرقم من هنا هذه CH2 CH3 لحظة
+
+217
+00:18:22,490 --> 00:18:28,720
+واحد اتنين هيصيروا ال Echlorتلاتة اربعة واحد اتنين
+
+218
+00:18:28,720 --> 00:18:34,200
+تلاتة اذا هذا كام ترقيم يحتمل واحد فقط واحد اتنين
+
+219
+00:18:34,200 --> 00:18:37,920
+تلاتة عشان ال glory يكونوا اقل ترقيم من هنا واحد
+
+220
+00:18:37,920 --> 00:18:41,140
+اتنين تلاتة اربعة خمسة بيكون اتنين تلاتة من هنا
+
+221
+00:18:41,140 --> 00:18:45,640
+واحد اتنين تلاتة اربعة خمسة بيصير تلاتة اربعة اذا
+
+222
+00:18:45,640 --> 00:18:52,420
+هذا كام ترقيم يحتمليحتمل ترقيم واحد فقط لكن المركب
+
+223
+00:18:52,420 --> 00:18:56,880
+اللي بعده المتماثل لو انا رقمته زي ما انتوا شايفين
+
+224
+00:18:56,880 --> 00:19:06,100
+بالازرق صح و لو انا رقمته بالاحمر صح طيب اللي رقمت
+
+225
+00:19:06,100 --> 00:19:12,660
+بالازرق كتبت المركب 2R3S23Diclorobutane
+
+226
+00:19:12,660 --> 00:19:17,390
+طب و اللي بده ترقم بالاحمر شو هتكتب؟الـ 2 ما احنا
+
+227
+00:19:17,390 --> 00:19:21,950
+عارفين ان هذه R و هذه S بغض النظر عن الترقيم هتكتب
+
+228
+00:19:21,950 --> 00:19:25,270
+2S3R
+
+229
+00:19:25,270 --> 00:19:30,930
+الآن اي جواب اللي بدنا نعتبره صح الجوابين صح هذا
+
+230
+00:19:30,930 --> 00:19:36,610
+إله اسمين هذا إله اسمين لأنه متماثل وعشانك المدرس
+
+231
+00:19:36,610 --> 00:19:40,250
+اللي بده يصلح بيجيبلكوا هذا المركب ويقولكوا اعطوه
+
+232
+00:19:40,250 --> 00:19:45,680
+اسمهذا الجواب يبدو يعتبره صح وهذا الجواب يبدو
+
+233
+00:19:45,680 --> 00:19:49,600
+يعتبره صح لسبب بسيط انه مافيه فارق نهائي بين انكوا
+
+234
+00:19:49,600 --> 00:19:54,280
+ترقموه من هنا او من هنا الان نفس الشيء في المركب
+
+235
+00:19:54,280 --> 00:19:58,900
+التاني لما رقمناه بالازرق واحد اتنين تلاتة اربعة
+
+236
+00:19:58,900 --> 00:20:05,140
+طب لو واحدة عملتله ترقيم تاني بالاحمر ايش هتكتبوه؟
+
+237
+00:20:05,140 --> 00:20:11,040
+two R three S الان اتطلعوا هذا أحد أسماء two S
+
+238
+00:20:11,040 --> 00:20:19,770
+three Rهذا أحد أسمائه 2R3S
+
+239
+00:20:19,770 --> 00:20:28,590
+و هذا 2R3S لأن الجزء ببساطة متماثل لأن هذا الجزء
+
+240
+00:20:28,590 --> 00:20:33,490
+ببساطة متماثل بياخد اسمين و هدول الشكلين بيكونوا
+
+241
+00:20:33,490 --> 00:20:38,710
+مركب واحد مش مركبينواضح؟ مركّب واحد وبتسمى
+
+242
+00:20:38,710 --> 00:20:42,110
+بطريقتين، الآن إذا اتفقنا إن هدولة they are the
+
+243
+00:20:42,110 --> 00:20:46,250
+same compound، بأكتر من طريقة فرجيتكم، اللي بدأ من
+
+244
+00:20:46,250 --> 00:20:49,710
+خلال الإشارات، إنه يلهم نفس الإشارات، أيه؟ يلهم
+
+245
+00:20:49,710 --> 00:20:56,750
+نفس الإشارات ولا لأ؟2R 3S .. 2S 3R .. 2S 3R .. 2S
+
+246
+00:20:56,750 --> 00:21:04,650
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+247
+00:21:04,650 --> 00:21:05,570
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+248
+00:21:05,570 --> 00:21:05,730
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+249
+00:21:05,730 --> 00:21:05,930
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+250
+00:21:05,930 --> 00:21:06,830
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+251
+00:21:06,830 --> 00:21:06,830
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+252
+00:21:06,830 --> 00:21:14,070
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+253
+00:21:14,070 --> 00:21:21,840
+2S 3R .. 2S 3Rوغيرهم سواء سمته 2R3S او 2S3R هو نفس
+
+254
+00:21:21,840 --> 00:21:26,100
+المركب له اسميننفس المركب له اسمين شو اللي عمله
+
+255
+00:21:26,100 --> 00:21:31,660
+الاسمين التماثل اذا لو انا بجاجي اسأل ببساطة لو
+
+256
+00:21:31,660 --> 00:21:35,480
+واحدة ع طول بده تعرف انه عندها اربع مركبات ولا
+
+257
+00:21:35,480 --> 00:21:40,320
+تلاتة ايش اول ما بده تطلع عليه في الجزء انه هل يا
+
+258
+00:21:40,320 --> 00:21:44,460
+ترى هذا الجزء اللي عنده فيه تماثل ولا لا اذا فيه
+
+259
+00:21:44,460 --> 00:21:49,620
+تماثل ع طول بده تحكي عن كام مركبعن تلاتة مافيش
+
+260
+00:21:49,620 --> 00:21:53,820
+تماثل بده تحكي عن أربع يعني لو مثلا سألكوا هذا
+
+261
+00:21:53,820 --> 00:22:05,280
+السؤال CH3 CHBR CHCL CH3 كام Cairo Center فيه؟هن و
+
+262
+00:22:05,280 --> 00:22:09,200
+هن قبل ما ارسم ايزو مارزو اتعب كام ايزو مارزو
+
+263
+00:22:09,200 --> 00:22:14,480
+تتوقعوا له اربعة عطول اربعة ليش لانه انا لو جسمت
+
+264
+00:22:14,480 --> 00:22:18,260
+بين هدولة two chiral centers هذي الظرات مش هى هذي
+
+265
+00:22:18,260 --> 00:22:25,060
+الظرات هنا عندكم H و CL هنا H .. خلاص انتهى واضح؟
+
+266
+00:22:25,060 --> 00:22:31,600
+و هكذاواضح، الان هذا المركب اللي فيه تماثل داخلي،
+
+267
+00:22:31,600 --> 00:22:37,860
+لو انتوا بتتأملوا فيه بعمق شوية، بتحسوا انه اللي
+
+268
+00:22:37,860 --> 00:22:44,250
+خلّاه يصيرنفس المركب و اقدر الفه انه انا لو اني
+
+269
+00:22:44,250 --> 00:22:48,650
+اتخيلت مرايا في نص المركب هذا النص اللى فوق صورة
+
+270
+00:22:48,650 --> 00:22:52,770
+النص اللى تحت فى المرأة ولا لأ طلعوا معاك هى ال CL
+
+271
+00:22:52,770 --> 00:23:00,790
+اقبالها CL ال H H ال مثل مثل اذا one half of the
+
+272
+00:23:00,790 --> 00:23:04,170
+molecule is the mirror image of the other half ولا
+
+273
+00:23:04,170 --> 00:23:10,660
+لأ هذا النص هو صورة هذا النص فى المرأةواضح الكلام؟
+
+274
+00:23:10,660 --> 00:23:14,420
+زي الناس اللي بتطلعوا على كروت الشدة إذا عمركوا
+
+275
+00:23:14,420 --> 00:23:18,780
+شفتوها بتشوفوا الرسومات اللي فيها البني آدم هيك او
+
+276
+00:23:18,780 --> 00:23:24,620
+بصر هيك بعدين هذا
+
+277
+00:23:24,620 --> 00:23:29,540
+زيه بالظبط .. هذا زيه بالظبط أنه النص هذا .. صورة
+
+278
+00:23:29,540 --> 00:23:37,180
+النص هذا في المرأةواضح؟ الان هذا المركب كأنه حقيقة
+
+279
+00:23:37,180 --> 00:23:42,380
+يحتوي على مركبين كأنه هذا مركب بإمكانكوا تتخيلوه و
+
+280
+00:23:42,380 --> 00:23:47,540
+هذا مركب تاني و هاي هم بس متصلين في بعض و من البعض
+
+281
+00:23:47,540 --> 00:23:52,760
+لو إجيت بديت أفكر بعمق شوية هذا لو إنه حطناه لوحده
+
+282
+00:23:52,760 --> 00:23:59,810
+في المرآة بيطلع كايران و إلهrotation وهذا لو حطيته
+
+283
+00:23:59,810 --> 00:24:04,450
+لوحده في المرأة كايرة له rotation طيب لو أخدت
+
+284
+00:24:04,450 --> 00:24:09,530
+مليون جزء من المركب الكلي كده يكون من هذا النص
+
+285
+00:24:09,530 --> 00:24:15,370
+مليون و من هذا النص مليون و المليونين عكس بعض صار
+
+286
+00:24:15,370 --> 00:24:21,750
+هذا بنفسه يشبه إيش؟Racemic mixture اللى أخدناه
+
+287
+00:24:21,750 --> 00:24:25,510
+المرة الماضية لما كنا نقولكوا لو كان عندى خليط
+
+288
+00:24:25,510 --> 00:24:31,050
+متساوي من two isomers شو سمناه؟ Racemic mixture
+
+289
+00:24:31,050 --> 00:24:35,850
+واحد منهم بيلف يمين التانى اشمال قداش بيكون
+
+290
+00:24:35,850 --> 00:24:41,240
+بالمجمل ال rotation له؟ سفرالـ Racemic mixture
+
+291
+00:24:41,240 --> 00:24:45,460
+بيكون optically active ولا inactive؟ optically
+
+292
+00:24:45,460 --> 00:24:48,880
+inactive ليش optically inactive؟ لأنه فيه عدد
+
+293
+00:24:48,880 --> 00:24:54,240
+متساوي من ال enantiomers بيلغوا بعض الان هذا تماما
+
+294
+00:24:54,240 --> 00:24:58,700
+يشبه الracemic mixture كأنه هاي نص و هاي نص هدول
+
+295
+00:24:58,700 --> 00:25:04,040
+عكس بعض ولا لا؟ واحد R و واحد S الجزء الكبير لو
+
+296
+00:25:04,040 --> 00:25:09,210
+منه مليون كدهش فيه من هذا؟ و من هذا؟أذا هذا
+
+297
+00:25:09,210 --> 00:25:13,330
+racemic mixture كأنه بامتياز بس موجود في مركب واحد
+
+298
+00:25:13,330 --> 00:25:17,550
+فهذا المركب بالمجمل بيكون optically active ولا
+
+299
+00:25:17,550 --> 00:25:24,070
+inactive هالمركب العجيب هذا المتماثل اللي موجود ال
+
+300
+00:25:24,070 --> 00:25:28,390
+configuration فيه لنصه عكس التاني اللي نصه صورة
+
+301
+00:25:28,390 --> 00:25:32,270
+بعض أو صورة نص التاني في المرآة أخد اسم في ال
+
+302
+00:25:32,270 --> 00:25:36,910
+stereo chemistry بيسميه meso compound أو
+
+303
+00:25:36,910 --> 00:25:42,570
+mesostructureلحظة الان لو بدنا نقرأ ايش تعريف ال
+
+304
+00:25:42,570 --> 00:25:47,170
+meso compound كل الكلام هذا معرف هنا كل اللي حكينا
+
+305
+00:25:47,170 --> 00:25:53,050
+ال meso compound is an achiral diastereomer of the
+
+306
+00:25:53,050 --> 00:25:56,450
+compound achiral يعني optically inactive شوفنا ليش
+
+307
+00:25:56,450 --> 00:26:02,470
+انه achiral و ليش انه optically inactiveرغم أنه في
+
+308
+00:26:02,470 --> 00:26:06,750
+مركز استيريوجينيك كم مركز استيريوجينيك فيه؟ اتنين
+
+309
+00:26:06,750 --> 00:26:11,630
+لكن هو بالمحصلة كايرال ولا اكايرال؟ اكايرال
+
+310
+00:26:11,630 --> 00:26:14,190
+optical and active although it contains
+
+311
+00:26:14,190 --> 00:26:18,030
+stereogenic centers الان its stereogenic centers
+
+312
+00:26:18,030 --> 00:26:23,190
+have opposite configurations يعني لازم واحد R
+
+313
+00:26:23,190 --> 00:26:26,970
+والتاني S هذا اللي بيكون ال mesocompound او نفس
+
+314
+00:26:26,970 --> 00:26:32,470
+المركب one half of the molecule isThe mirror image
+
+315
+00:26:32,470 --> 00:26:37,330
+of the other half اللي في هذه المواصفات بنقول انه
+
+316
+00:26:37,330 --> 00:26:43,520
+ميزو كومباوند بيكون مركب واحد مشمش مركبين
+
+317
+00:26:43,520 --> 00:26:46,160
+optically inactive يعني لو جينا سئلناكوا في
+
+318
+00:26:46,160 --> 00:26:49,360
+الامتحان ميزو كومباوند is optically active or
+
+319
+00:26:49,360 --> 00:26:55,260
+inactive؟ inactive الميزو كومباوند if مركب متماثل
+
+320
+00:26:55,260 --> 00:26:58,680
+لما اجي ارسم عندى two R three R two S three S و
+
+321
+00:26:58,680 --> 00:27:02,880
+two R three S او التانية من اللي فيهم بتكون ميزو؟
+
+322
+00:27:02,880 --> 00:27:09,000
+اللي فيها هدول عكس بعض يعني اللي بتكون RR او SS كل
+
+323
+00:27:09,000 --> 00:27:13,630
+واحدة منهم فردة in andيعني هذه لو أخدتها لحالها
+
+324
+00:27:13,630 --> 00:27:19,130
+optically active لو
+
+325
+00:27:19,130 --> 00:27:23,650
+عملت خليط متساوي من هدول الاتنين بيصير عند راسمك
+
+326
+00:27:24,520 --> 00:27:28,120
+mixture بيصير optical inactive لو أخدت من واحدة
+
+327
+00:27:28,120 --> 00:27:33,360
+اكتر من التانية زي ما اتعلمنا بيصير النتج نتاج
+
+328
+00:27:33,360 --> 00:27:38,600
+التنتين لكن هذا المركب هذا المركب اللي بيميزه انه
+
+329
+00:27:38,600 --> 00:27:43,100
+واحدة منه R والتانية S اذا انا لما بتعرف ال mezzo
+
+330
+00:27:43,100 --> 00:27:47,380
+compound في المركب المتماثل اللي بيكون منه واحدة R
+
+331
+00:27:47,380 --> 00:27:53,360
+والتانية S هذا ال mezzo compound والمجموع بيطلع
+
+332
+00:27:54,340 --> 00:27:59,240
+تلات مركبات في النهاية الان لو اتيت سألة طيب يا
+
+333
+00:27:59,240 --> 00:28:02,700
+تورا قولنا احنا اكيد بين هذا و هذا العلاقة they
+
+334
+00:28:02,700 --> 00:28:06,720
+are enantiomers طب لو اي واحد من هذول ال
+
+335
+00:28:06,720 --> 00:28:11,520
+enantiomers قرنته بال meso compound اه طلعوا two
+
+336
+00:28:11,520 --> 00:28:18,320
+are نفس الاشي هدوله واضح نفس الشي و three are
+
+337
+00:28:18,320 --> 00:28:24,870
+three asعكس بعض، اشي نفسه، اشي عكسه، فين VR؟ ده
+
+338
+00:28:24,870 --> 00:28:30,950
+يستيريو مارسي، فين VR؟ ده يستيريو مارسي بتايع ليه؟
+
+339
+00:28:30,950 --> 00:28:35,490
+بيكفي على موضوع ال two chiral centers الآن في
+
+340
+00:28:35,490 --> 00:28:41,850
+عندكم مجموعة من الأسئلة كيف توجدوا العلاقة بين
+
+341
+00:28:41,850 --> 00:28:47,080
+المركبين حتى لو رسمناهم بطرق مختلفةلاحظوا هذه
+
+342
+00:28:47,080 --> 00:28:50,980
+المُركّبات مرسومة بطرق مختلفة تماما مرة الـH لفوق
+
+343
+00:28:50,980 --> 00:28:54,820
+و مرة الـH على الجانب لكنهم نفس المُركّب بالمناسبة
+
+344
+00:28:54,820 --> 00:29:00,060
+يعني من ناحية structure أو روابط يعني كاربون
+
+345
+00:29:00,060 --> 00:29:04,280
+الأولى حملة PR و CL و بعدين CH3 و هاي الكاربون
+
+346
+00:29:04,280 --> 00:29:07,680
+اللي هو حملة PR و CL و بعدين CH3 يعني لو هذا و هذا
+
+347
+00:29:07,680 --> 00:29:13,090
+كنت بدأ أسميهم one-bromo one-chloro-ethaneمرة
+
+348
+00:29:13,090 --> 00:29:18,290
+تانية هاي carbon واحد هاي اتنين شو هتسموه وان
+
+349
+00:29:18,290 --> 00:29:25,500
+برومو وان كلوروإيه ثاني الار هدول الاتنين اللي
+
+350
+00:29:25,500 --> 00:29:29,680
+مرسومين بيدي العلاقة بينهم مش مرسومين بطريقة اللي
+
+351
+00:29:29,680 --> 00:29:33,180
+بالعين المجردة أشوف أنهم بينيهم مرسومين زي بعض أو
+
+352
+00:29:33,180 --> 00:29:37,000
+كل واحدة عكس التانية مرسومين بطرق مختلفة إذا على
+
+353
+00:29:37,000 --> 00:29:42,200
+طول ماليش حل إلا أحدد ال configuration أحددهم بضوء
+
+354
+00:29:42,200 --> 00:29:46,880
+هذا طلع R و هذا R then they are the same compound
+
+355
+00:29:46,880 --> 00:29:53,920
+واضح؟ الآن جيبنالكم مركبين تانينكم carbon هذا لو
+
+356
+00:29:53,920 --> 00:29:59,540
+بدكوا تسموه المركب هذا أطول سلسلة فيه قداش أربعة
+
+357
+00:29:59,540 --> 00:30:09,160
+واحد اتنين اعلم على أطول سلسلة CH3CCCH3
+
+358
+00:30:09,160 --> 00:30:17,440
+إذا هذا المركب اللي عندى بيوتين شو بيحمل بيوتين؟ع
+
+359
+00:30:17,440 --> 00:30:21,920
+نمره 2 برومه ع نمره 3 كلور ترقيب واحد عندي عشان
+
+360
+00:30:21,920 --> 00:30:26,340
+اخلي البروم اقل ما يمكن اتنين برومه ثلاثة ثلاثة
+
+361
+00:30:26,340 --> 00:30:27,620
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+362
+00:30:27,620 --> 00:30:29,600
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+363
+00:30:29,600 --> 00:30:36,300
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+364
+00:30:36,300 --> 00:30:44,220
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+365
+00:30:44,220 --> 00:30:50,050
+ثلاثة ثأحدد R و S لما أعملهم بهدوء بتعملهم في
+
+366
+00:30:50,050 --> 00:30:56,550
+البيت هنا two S and two R انبينين عكس بعض three S
+
+367
+00:30:56,550 --> 00:31:01,850
+and three R the same then they are diastereomers
+
+368
+00:31:01,850 --> 00:31:05,730
+كذلك
+
+369
+00:31:05,730 --> 00:31:11,930
+الحال هذا المركب هي أطول سلسلة فيهنطلع عليها واحد
+
+370
+00:31:11,930 --> 00:31:15,810
+اتنين تلاتة اربعة ع تنين برم وع تلاتة كلور وهذه
+
+371
+00:31:15,810 --> 00:31:20,350
+أطول السلسلة واحد اتنين تلاتة اربعة ع تنين برم وع
+
+372
+00:31:20,350 --> 00:31:28,710
+تلاتة كلور نحدد له R وS two S two R three S three
+
+373
+00:31:28,710 --> 00:31:37,170
+R الترقيم من هناك كل شيء عكس بعضين VR انانشومارز
+
+374
+00:31:37,170 --> 00:31:41,670
+اللي بعده نفس الشيء لو عملته بهدوءthe same
+
+375
+00:31:41,670 --> 00:31:46,270
+compound واضح؟ the same compound طبعا انتوا بدكوا
+
+376
+00:31:46,270 --> 00:31:51,970
+تحذروا بس بحالة واحدة لما يكون المركب متماثل و
+
+377
+00:31:51,970 --> 00:31:57,010
+يطلع عندكم 2R 3S و التالية 2S 3R بدكوا ترجعوا
+
+378
+00:31:57,010 --> 00:32:00,770
+تفكروا بالإيش بال meso compound اللي هو the same
+
+379
+00:32:00,770 --> 00:32:04,910
+compoundلو كان المراكب متماثل الأمثل هذا اللي
+
+380
+00:32:04,910 --> 00:32:09,350
+قدامكم مش متماثل لأنه على جهة بروم و على جهة كلور
+
+381
+00:32:09,350 --> 00:32:15,150
+دائما التفكير وين بده يكون قف و أفكر لما يكون فيه
+
+382
+00:32:15,150 --> 00:32:19,490
+تماثل داخلي إذا في تماثل داخلي و طلع عندكم ال
+
+383
+00:32:19,490 --> 00:32:26,150
+configurations في المتماثل إذا طلع عندكم R و S و
+
+384
+00:32:26,150 --> 00:32:31,390
+جبالها S و Rthey are the same compound هذا الحكي
+
+385
+00:32:31,390 --> 00:32:37,610
+وين بيكون في المركبات المتماثلة بيكون المركب فعلا
+
+386
+00:32:37,610 --> 00:32:44,630
+ميزو لما أحكي عن مركبين ر أس و أس و ر طلعوا معاكم
+
+387
+00:32:44,630 --> 00:32:51,270
+if مركب فيه تماثل داخلي بنقول عنهم they are the
+
+388
+00:32:51,270 --> 00:32:56,130
+same compound أو بنقول this is a mezzo compound
+
+389
+00:32:56,130 --> 00:33:01,530
+وبيكون طبعا opticallyinactive بيكون optically
+
+390
+00:33:01,530 --> 00:33:05,810
+inactive الان
+
+391
+00:33:05,810 --> 00:33:13,230
+لو اجينا لتفاعلات او التفاعلات المرتبطة بال stereo
+
+392
+00:33:13,230 --> 00:33:17,590
+chemistry في ال stereo chemistry في عندى اكتر من
+
+393
+00:33:17,590 --> 00:33:21,520
+نوع من التفاعلاتأحد هذه التفاعلات بنسميه
+
+394
+00:33:21,520 --> 00:33:25,720
+generation of a chiral center يعني انتوا بدأتوا
+
+395
+00:33:25,720 --> 00:33:30,320
+بمركب مش فيه ولا chiral center اعملتوا chiral
+
+396
+00:33:30,320 --> 00:33:35,740
+center خلينا ناخد مثال بسيط لو قلنا لكوا بدنا نعمل
+
+397
+00:33:35,740 --> 00:33:44,340
+chlorination للبيوتين بتذكرين البيوتين CH3 CH2 CH2
+
+398
+00:33:45,570 --> 00:33:50,510
+CH3 هل يترى هذا في أي كايرال سنتر؟ لا في كربون
+
+399
+00:33:50,510 --> 00:33:55,770
+بتحمل أربع مجموعات الآن بدنا نشيل هيدروجين يا من
+
+400
+00:33:55,770 --> 00:34:00,590
+موقع واحد يا من موقع اتنين يعني انا لما بعمل ال
+
+401
+00:34:00,590 --> 00:34:04,370
+chlorineation على البيوتين كام ناتج كنا متوقعين
+
+402
+00:34:04,370 --> 00:34:08,630
+اللي بيطلع عندنا اتنين المركب الأول اللي بيجيب ال
+
+403
+00:34:08,630 --> 00:34:13,150
+chlorine على موقع واحد هل صار في كايرال سنتر؟ لا
+
+404
+00:34:14,270 --> 00:34:18,910
+تخيلوا لو بدأ أضع الكلور على موقع واحد CH2CL
+
+405
+00:34:43,960 --> 00:34:47,500
+فى كل الأحوال بيصير عندى carol center يعني تخيل لو
+
+406
+00:34:47,500 --> 00:34:50,320
+أنا حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+407
+00:34:50,320 --> 00:34:55,040
+و لو حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+408
+00:34:55,040 --> 00:34:59,820
+اتطلعوا بينهم سواء كعلاقة أو لو حسبتولهم R و S
+
+409
+00:34:59,820 --> 00:35:07,910
+هتلاحظوا ان هدول الاتنين عكس بعض Rانانشو مارزي
+
+410
+00:35:07,910 --> 00:35:13,250
+يعني هاي ال H نفترض CL و بعدين اثلو مثل مبينة R
+
+411
+00:35:13,250 --> 00:35:18,650
+this is S وهي هذي ال H بنشطبها CL مبينة S هاي ال
+
+412
+00:35:18,650 --> 00:35:23,970
+configuration لهدول اذا انا وين اعملت chiral
+
+413
+00:35:23,970 --> 00:35:27,830
+center ع موقع واحد ولا ع موقع اتنين ع موقع اتنين
+
+414
+00:35:27,830 --> 00:35:31,870
+وين بعمل chiral center بطلع عندى خليط من two
+
+415
+00:35:31,870 --> 00:35:36,810
+انانشو مارزيبطلع عندى خليط من two enansimers اذا
+
+416
+00:35:36,810 --> 00:35:40,270
+لو اجيت انا سألتكوا الان سؤال بالمجمل
+
+417
+00:35:40,270 --> 00:35:46,110
+لchlorination of butane كم مركب بيعطينى تلاتة
+
+418
+00:35:46,110 --> 00:35:50,130
+تلاتة تنسوش انه انا في شغل مش كاتبة لأنه خارج
+
+419
+00:35:50,130 --> 00:35:57,190
+الإطار تبعنا انه لو فعلنا على هذا بيعطينا CH2CL
+
+420
+00:35:57,190 --> 00:36:00,450
+اللى هو ال one chlorobutane هذا مافيه chiral
+
+421
+00:36:00,450 --> 00:36:08,390
+centersهذا يبدو يجي الكلورة ع موقع واحد او ع موقع
+
+422
+00:36:08,390 --> 00:36:12,530
+اتنين ع موقع واحد عمل كايرال سنتر اذا هو مركب واحد
+
+423
+00:36:12,530 --> 00:36:16,490
+ع موقع اتنين عمل كايرال سنتر و ايه اللي بيصير
+
+424
+00:36:16,490 --> 00:36:20,790
+كايرال سنتر بيطلع عندى كام مركب اتنين اذا مجموع
+
+425
+00:36:20,790 --> 00:36:25,310
+المركبات قداشر تلاتة طب لو قولتلى واحدة سميلي
+
+426
+00:36:25,310 --> 00:36:27,890
+التلات نواتج اللى بيطلعوا من ال chlorineation و ال
+
+427
+00:36:27,890 --> 00:36:32,010
+butane شو هتقرأواحد كلورو بيوتين واحد كلورو بيوتين
+
+428
+00:36:32,010 --> 00:36:35,930
+ممتازة ارتو
+
+429
+00:36:35,930 --> 00:36:40,970
+كلورو بيوتين و استو كلورو بيوتين فبال total كام
+
+430
+00:36:40,970 --> 00:36:45,810
+مركب طلعوا تلاتة لكن لو كان السؤال كام structural
+
+431
+00:36:45,810 --> 00:36:50,610
+isomer بيطلع عنده من ال chlorineation اتنين لأن
+
+432
+00:36:50,610 --> 00:36:54,710
+معنى structural isomer مواقع الارتباط لكلور يا
+
+433
+00:36:54,710 --> 00:37:00,470
+بترتبط ع واحد يا بترتبط ع اتنينهدولة اتنين stereo
+
+434
+00:37:00,470 --> 00:37:05,390
+isomers ال R2 كلورو بيوتين و ال S2 كلورو بيوتين
+
+435
+00:37:05,390 --> 00:37:09,670
+they have the same bonding الارتباط فيه مع موقع
+
+436
+00:37:09,670 --> 00:37:13,870
+ايش اتنين but different arrangement in space هدولة
+
+437
+00:37:13,870 --> 00:37:18,010
+stereo isomers فبدكوا تنتبهوا لما بنسألكوا في
+
+438
+00:37:18,010 --> 00:37:21,550
+المنطقة لما نيجي نقولكم ال chlorineation في بيوتين
+
+439
+00:37:21,550 --> 00:37:26,670
+producesتو Structural Isomers، الـ Structural
+
+440
+00:37:26,670 --> 00:37:30,770
+مواقع، يا بتيجي الكلور على واحد، يا على اتنين،
+
+441
+00:37:30,770 --> 00:37:35,590
+الآن اللي على اتنين، في منها اتنين Stereoisomers،
+
+442
+00:37:35,590 --> 00:37:43,130
+اللي هم الـR والـS، واضح؟العلى اتنين في منها two
+
+443
+00:37:43,130 --> 00:37:47,750
+stereoisomers الار والاسم طبعا عادة بفسروا هذا
+
+444
+00:37:47,750 --> 00:37:50,870
+الكلام احنا مش اتنين ركزنا على ال mechanism of
+
+445
+00:37:50,870 --> 00:37:55,590
+reaction بفسروا انه هذا التفاعل اول ما بيبدأ
+
+446
+00:37:55,590 --> 00:38:00,410
+بترتفع في ذرة هيدروجين بيصيروا هدولة التلاتة
+
+447
+00:38:00,410 --> 00:38:06,520
+planner في مستوى واحد يعني لو انا بدي اجي اتخيلليش
+
+448
+00:38:06,520 --> 00:38:10,780
+تم التفاعل على الجهتين؟ لما تم التفاعل على
+
+449
+00:38:10,780 --> 00:38:18,200
+الجهتين؟ ممكن ايه بسرعة اريكم باستعمال ال models و
+
+450
+00:38:18,200 --> 00:38:27,360
+بأمل انها ال models بتخدمنا اتخيلوا
+
+451
+00:38:27,360 --> 00:38:33,500
+معنا لو اتخيلنا ان في عندنا CH3 ال CH3 نتخيلهاذرة
+
+452
+00:38:33,500 --> 00:38:39,550
+كربون صمرة CH3تمام؟ لما أشيل H بيبقى عندى كام
+
+453
+00:38:39,550 --> 00:38:44,650
+هيدروجين؟ واحدة و إيش بيبقى عندى؟ مجموعة ال إفل
+
+454
+00:38:44,650 --> 00:38:48,770
+لسه ماجيبتش ال chlorine أنا بدي بهذا كيف بعمل
+
+455
+00:38:48,770 --> 00:38:52,830
+الإبدال؟ بشيل الهيدروجينة في الأول و بعدين بحط
+
+456
+00:38:52,830 --> 00:38:57,250
+بدالها chlorine فدولة كام رابطة حوالين الكربون؟
+
+457
+00:38:57,250 --> 00:38:58,910
+أربعة أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+458
+00:38:58,910 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+459
+00:38:59,790 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+460
+00:38:59,790 --> 00:39:06,750
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة
+
+461
+00:39:07,360 --> 00:39:13,760
+بمشي الحال هاي هذا صار بهذا الشكل بالظبط طلعوا في
+
+462
+00:39:13,760 --> 00:39:20,740
+مجموعة مثل و H و إثل و ال H الأخيرة شيلناها
+
+463
+00:39:20,740 --> 00:39:24,240
+رفعناها الآن بدنا نجيب ال chlorine تتفاعل
+
+464
+00:39:26,450 --> 00:39:29,650
+هذه الـ Intermediate للحظة برفعت الـ H الأولى
+
+465
+00:39:29,650 --> 00:39:33,330
+بلانر في مستوى واحد الكلور بإمكانها تيجي تهاجم
+
+466
+00:39:33,330 --> 00:39:37,470
+عليها من هنا و هدولا بتعجوا حلو ميك او من هنا
+
+467
+00:39:37,470 --> 00:39:43,910
+طالما انها بلانر في فرق ان الكلور هي جاية من بعيد
+
+468
+00:39:43,910 --> 00:39:49,130
+بفرق عندها انها تمشي من هنا او من هنا اطلع معي
+
+469
+00:39:49,130 --> 00:39:52,670
+شايفين هدول الممرين اللي في القاعة لو انا بدي اروح
+
+470
+00:39:52,670 --> 00:39:59,700
+لاخر نقطةبإمكاني أمشي من هنا و من هنا بشكل متساوي
+
+471
+00:39:59,700 --> 00:40:04,520
+ولا لأ؟ ماعندي مشكلة، بدي أروح لآخر نقطة وهي عندي
+
+472
+00:40:04,520 --> 00:40:08,240
+مصارين متكافئت كذلك الحال، هذا planner بدي تيجي
+
+473
+00:40:08,240 --> 00:40:12,200
+اكلور من برا تتفاعل عليه، ترد تعمل المجموعة
+
+474
+00:40:12,200 --> 00:40:16,180
+الرابعةإذا أتيت من هنا عملة انانشومر و إذا أتيت من
+
+475
+00:40:16,180 --> 00:40:20,660
+هنا عملة التاني الان من ناحية الاحتمالات متساوية
+
+476
+00:40:20,660 --> 00:40:25,440
+تماما و لذلك يظهر عندي راسيمك ميكسشر يعني يظهر
+
+477
+00:40:25,440 --> 00:40:30,220
+الاتنين و يظهرون بنسب متساوية يظهر الاتنين و
+
+478
+00:40:30,220 --> 00:40:34,100
+يظهرون بنسب متساوية فبصير المحصلة ان ال generation
+
+479
+00:40:34,100 --> 00:40:42,710
+of a chiral center produces راسيمك ميكسشرواضح؟ ال
+
+480
+00:40:42,710 --> 00:40:46,690
+generation of a chiral center produces a racemic
+
+481
+00:40:46,690 --> 00:40:53,110
+mixture الان لو قلنا بدل racemic mixture equal
+
+482
+00:40:53,110 --> 00:40:59,740
+number of enantiomers أكيد صح .. أكيد صحgeneration
+
+483
+00:40:59,740 --> 00:41:02,520
+of a chiral center produces racemic mixtures
+
+484
+00:41:02,520 --> 00:41:10,660
+لاحظوا هذه الجملة بالنسبة للكيميا ما بين الكيميا
+
+485
+00:41:10,660 --> 00:41:15,480
+اللي بيصنعوها البشر و ما بين خلق الله سبحانه
+
+486
+00:41:15,480 --> 00:41:21,070
+وتعالى بتعمل فرق كبير جدااليوم لما انا باجي في
+
+487
+00:41:21,070 --> 00:41:26,450
+المختبر بده احضر مركب و اعمل chiral center انا
+
+488
+00:41:26,450 --> 00:41:31,290
+مابتحكمش في الاحتمالات بطلع عندى خليط متساوي و
+
+489
+00:41:31,290 --> 00:41:36,090
+بعدين اتعب و افصله و هذا السبب ربما في انه في دوة
+
+490
+00:41:36,090 --> 00:41:41,360
+مثل الثاليدواميد كان بيطلع الخليطالمتساوي ال R و
+
+491
+00:41:41,360 --> 00:41:45,860
+ال S لمنهم واحد مفيد و واحد ضار و عمل مشاكل كتير
+
+492
+00:41:45,860 --> 00:41:50,160
+كل ما بشغل في المختبر المختبر بطلعلي خليط من
+
+493
+00:41:50,160 --> 00:41:52,940
+المركبين اذا مش عندى chiral center انا بدي اعمله
+
+494
+00:41:52,940 --> 00:41:57,460
+بطلعلي .. بطلعلي ايش؟ racemic mixture الان في
+
+495
+00:41:57,460 --> 00:42:02,570
+الطبيعة فيه انزيماتالانزيمات كأنها بتاخد بإيدي
+
+496
+00:42:02,570 --> 00:42:05,850
+المجموعة اللي جاية بالظبط بداخلها من جهة واحدة
+
+497
+00:42:05,850 --> 00:42:10,030
+ولذلك المنتجات الطبيعية بيطلع منها بس one in a
+
+498
+00:42:10,030 --> 00:42:16,750
+number هذا خلقههذا خلق الله يعني انا لما شغلة كون
+
+499
+00:42:16,750 --> 00:42:21,210
+بتحضرها الانزيمات و بتتحضر جوا الجسم بتلاقوا بيطلع
+
+500
+00:42:21,210 --> 00:42:26,330
+منها بس واحد لما اجي انا اعيد التفاعل بالمختبر و
+
+501
+00:42:26,330 --> 00:42:30,110
+بدون انزيمات و بكذا بيطلع عندى خليط متساوي من
+
+502
+00:42:30,110 --> 00:42:34,830
+التنين ولذلك اللى بده مركبات نقية يعني بده one in
+
+503
+00:42:34,830 --> 00:42:39,750
+one شمر ايش اسهل طريقة يعملها؟ ياخدها من مصادرها
+
+504
+00:42:39,750 --> 00:42:44,590
+الطبيعية اذا كانت تحضر في الطبيعةطبعا إذا كانت لا
+
+505
+00:42:44,590 --> 00:42:51,850
+تحضر في الطبيعة بده يجعب هذه المشكلة و يطلع عنده
+
+506
+00:42:51,850 --> 00:42:56,450
+خليط من التنين عشان ايه كده في الكيميا بيسموه ايش
+
+507
+00:42:56,450 --> 00:43:02,990
+Symmetric Synthesis Symmetric Synthesis ايش معنى
+
+508
+00:43:02,990 --> 00:43:08,350
+Symmetric انه بيطلع خليط متمافل من التنين جد بعض و
+
+509
+00:43:08,350 --> 00:43:15,290
+بعدين يقعد ايش يعمليفصل فيهم الآن بدأوا من جديد
+
+510
+00:43:15,290 --> 00:43:21,030
+يستعملوا طرق حديثة في ال synthesis و يضيفوا عوامل
+
+511
+00:43:21,030 --> 00:43:25,330
+حفازة اللي تخلى واحد من هدول يطلع بنسبة اكتر من
+
+512
+00:43:25,330 --> 00:43:30,490
+التانية او يكاد يكون يطلع نقي وجدتها اذا طلعوا مش
+
+513
+00:43:30,490 --> 00:43:35,790
+متساويات شو بدى اسم ال synthesis Asymmetric
+
+514
+00:43:35,790 --> 00:43:40,010
+synthesisواضح؟ يعني الـ symmetric synthesis بتطلع
+
+515
+00:43:40,010 --> 00:43:44,810
+الخليط متساوي الآن إذا صرت أضيف عوامل حفازة بطرق
+
+516
+00:43:44,810 --> 00:43:49,290
+معينة بتحذيرات بصير أشتغل ايش؟ asymmetric
+
+517
+00:43:49,290 --> 00:43:52,910
+synthesis اليوم اللي منكم بده تدرس كيميا وبعدين
+
+518
+00:43:52,910 --> 00:43:57,120
+تقول أنا بدي أخد جائزة نوبل في الكيمياBye Bye
+
+519
+00:43:57,120 --> 00:44:01,260
+Asymmetric Synthesis بدا تشتغل على ايش؟ Asymmetric
+
+520
+00:44:01,260 --> 00:44:05,420
+Synthesis تصير تتعلم كتير تضيف عوامل حفازة
+
+521
+00:44:05,420 --> 00:44:12,040
+بمواصفات معينة تخلي التفاعل تطلع واحدمايطلعش
+
+522
+00:44:12,040 --> 00:44:16,200
+التاني او طلع واحد مثلا بنسبة 90% و التاني بنسبة
+
+523
+00:44:16,200 --> 00:44:20,800
+10% على سبيل المثال و كل ما جدت تطلع واحد تماما و
+
+524
+00:44:20,800 --> 00:44:26,500
+تلغي التاني كل ما كانت تمثل ايش نجاح كبير في الشغل
+
+525
+00:44:26,500 --> 00:44:31,720
+افهمنا اذا المشكلة ما بين الطبيعة و ما بين المختبر
+
+526
+00:44:31,720 --> 00:44:36,380
+المختبر هو وضع الطبيعيبطلّع لي خليط الطبيعة بوضعها
+
+527
+00:44:36,380 --> 00:44:42,120
+الطبيعي بطلّع واحد الان العالم بيسعوا نحو ايش؟ ان
+
+528
+00:44:42,120 --> 00:44:45,960
+يقتربوا من الطبيعة انهم يقدروا يطلعوا واحد و لو
+
+529
+00:44:45,960 --> 00:44:51,120
+بنسبة كبيرة في ما يسمى بالعلم ايش؟ asymmetric
+
+530
+00:44:51,120 --> 00:44:55,620
+synthesis بس بالتأكيد هذا الموضوع كتير متطور
+
+531
+00:44:55,620 --> 00:44:59,860
+بالنسبة لطالب organic يعني ما لم تتخصصوا كيميا مش
+
+532
+00:44:59,860 --> 00:45:02,460
+هتشتغلوا فيه بنكمل ان شاء الله في مرات
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..a5ae737f15baa5f3e34d6727b9022160a3112579
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/2vgDME64dpU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2775, "start": 19.59, "end": 27.75, "text": "بسم الله الرحمن الرحيم في موضوع الفصل التاسع ال aldehydes و ال ketones اعطينا المرة الماضية", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 8978, 3714, 2407, 11242, 45367, 27188, 36520, 16712, 32277, 3615, 2423, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 1975, 3615, 9566, 1829, 8315, 9673, 25720, 9673, 46958, 10632], "avg_logprob": -0.12890624465086523, "compression_ratio": 1.3482142857142858, "no_speech_prob": 0.0, "words": [{"start": 19.59, "end": 20.09, "word": "بسم", "probability": 0.90380859375}, {"start": 20.09, "end": 20.25, "word": " الله", "probability": 0.9599609375}, {"start": 20.25, "end": 20.65, "word": " الرحمن", "probability": 0.9833984375}, {"start": 20.65, "end": 21.15, "word": " الرحيم", "probability": 0.9949544270833334}, {"start": 21.15, "end": 22.41, "word": " في", "probability": 0.477294921875}, {"start": 22.41, "end": 23.07, "word": " موضوع", 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"probability": 0.99267578125}, {"start": 113.03, "end": 113.79, "word": " يعني", "probability": 0.87451171875}, {"start": 113.79, "end": 114.05, "word": " على", "probability": 0.90966796875}, {"start": 114.05, "end": 115.19, "word": " سبيل", "probability": 0.9830729166666666}, {"start": 115.19, "end": 115.93, "word": " المثال", "probability": 0.9889322916666666}, {"start": 115.93, "end": 116.63, "word": " لو", "probability": 0.919921875}, {"start": 116.63, "end": 116.89, "word": " كنت", "probability": 0.976806640625}, {"start": 116.89, "end": 117.11, "word": " بدى", "probability": 0.6865234375}, {"start": 117.11, "end": 117.43, "word": " اشوف", "probability": 0.8870442708333334}, {"start": 117.43, "end": 117.99, "word": " مركب", "probability": 0.9000651041666666}, {"start": 117.99, "end": 118.21, "word": " زي", "probability": 0.920166015625}, {"start": 118.21, "end": 118.45, "word": " هذا", "probability": 0.71044921875}, {"start": 118.45, "end": 118.87, "word": " سيضة", "probability": 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أسمي", "probability": 0.95947265625}, {"start": 133.43, "end": 134.01, "word": " واحد،", "probability": 0.7215983072916666}, {"start": 134.01, "end": 134.59, "word": " اتنين،", "probability": 0.94658203125}, {"start": 134.59, "end": 135.63, "word": " تلاتة،", "probability": 0.93955078125}, {"start": 135.63, "end": 135.77, "word": " شو", "probability": 0.884521484375}, {"start": 135.77, "end": 136.01, "word": " بدأ", "probability": 0.6846923828125}, {"start": 136.01, "end": 136.47, "word": " أسمي", "probability": 0.9208984375}, {"start": 136.47, "end": 136.71, "word": " هذا", "probability": 0.984375}, {"start": 136.71, "end": 136.91, "word": " الـ", "probability": 0.5689697265625}, {"start": 136.91, "end": 138.75, "word": " Ketone؟", "probability": 0.67926025390625}, {"start": 138.75, "end": 139.65, "word": " Iprobanone", "probability": 0.59674072265625}, {"start": 139.65, "end": 140.29, "word": " على", "probability": 0.6748046875}, {"start": 140.29, "end": 140.61, "word": " نمرة", "probability": 0.77001953125}, {"start": 140.61, "end": 140.99, "word": " واحد", "probability": 0.989990234375}, {"start": 140.99, "end": 141.19, "word": " ولا", "probability": 0.716796875}, {"start": 141.19, "end": 141.57, "word": " اتنين", "probability": 0.9822998046875}, {"start": 141.57, "end": 141.79, "word": " الـ", "probability": 0.6346435546875}, {"start": 141.79, "end": 141.91, "word": " C", "probability": 0.833984375}, {"start": 141.91, "end": 142.05, "word": " double", "probability": 0.92578125}, {"start": 142.05, "end": 142.43, "word": " bond", "probability": 0.97802734375}, {"start": 142.43, "end": 142.83, "word": " O؟", "probability": 0.866455078125}, {"start": 142.83, "end": 143.57, "word": " على", "probability": 0.7900390625}, {"start": 143.57, "end": 144.05, "word": " واحد،", "probability": 0.8995768229166666}, {"start": 144.05, "end": 144.23, "word": " اذا", "probability": 0.7291259765625}, {"start": 144.23, "end": 144.61, "word": " هذا", "probability": 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"probability": 0.96435546875}, {"start": 164.33, "end": 164.97, "word": " شبه", "probability": 0.78466796875}, {"start": 164.97, "end": 165.45, "word": " بهذه", "probability": 0.828857421875}, {"start": 165.45, "end": 165.85, "word": " الحالة", "probability": 0.95458984375}, {"start": 165.85, "end": 166.25, "word": " ممكن", "probability": 0.853759765625}, {"start": 166.25, "end": 166.69, "word": " يكون", "probability": 0.9228515625}, {"start": 166.69, "end": 167.33, "word": " الكيتون", "probability": 0.7371419270833334}, {"start": 167.33, "end": 167.55, "word": " على", "probability": 0.8759765625}, {"start": 167.55, "end": 167.93, "word": " موقع", "probability": 0.9811197916666666}, {"start": 167.93, "end": 168.29, "word": " واحد", "probability": 0.986572265625}, {"start": 168.29, "end": 169.01, "word": " بعد", "probability": 0.61474609375}, {"start": 169.01, "end": 169.65, "word": " ذلك", "probability": 0.99365234375}, {"start": 169.65, "end": 170.21, "word": " مثلا", "probability": 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205.86, "text": "لكن اختصرنا الاتنين لإيش؟ لأن لو جت على واحد هيصير بروبانال و هذا المركب لبروبانون هو الاسيتون الان هنا عندي اربع كربونات اذا بحكي انا عن بيوتانون ال C double bond O جاية فيه على موقع اتنين من ناحية المبدأ ايضا ممكن نختصرها", "tokens": [1211, 19452, 1975, 46456, 9381, 2288, 8315, 2423, 9307, 1863, 9957, 5296, 28814, 1829, 8592, 22807, 5296, 33456, 45164, 10874, 2655, 15844, 36764, 24401, 8032, 1829, 9381, 13546, 4724, 32887, 3555, 7649, 6027, 4032, 23758, 9673, 31747, 3555, 5296, 26890, 37746, 7649, 11536, 31439, 2423, 32277, 36081, 11536, 2423, 7649, 34105, 18871, 16254, 1975, 25513, 3615, 9122, 25513, 2407, 8315, 2655, 1975, 15730, 4724, 5016, 4117, 1829, 1975, 8315, 18871, 4724, 1829, 35473, 7649, 11536, 2423, 383, 3834, 6086, 422, 10874, 995, 10632, 8978, 3224, 15844, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 1975, 1829, 11242, 995, 3714, 43020, 8717, 46456, 9381, 2288, 11296], "avg_logprob": -0.2677176312676498, 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و", "probability": 0.47705078125}, {"start": 187.7, "end": 189.68, "word": " هذا", "probability": 0.642578125}, {"start": 189.68, "end": 190.26, "word": " المركب", "probability": 0.8585611979166666}, {"start": 190.26, "end": 191.06, "word": " لبروبانون", "probability": 0.798974609375}, {"start": 191.06, "end": 191.52, "word": " هو", "probability": 0.955078125}, {"start": 191.52, "end": 193.5, "word": " الاسيتون", "probability": 0.835693359375}, {"start": 193.5, "end": 194.56, "word": " الان", "probability": 0.61041259765625}, {"start": 194.56, "end": 195.32, "word": " هنا", "probability": 0.495849609375}, {"start": 195.32, "end": 195.88, "word": " عندي", "probability": 0.70263671875}, {"start": 195.88, "end": 196.58, "word": " اربع", "probability": 0.8253580729166666}, {"start": 196.58, "end": 197.3, "word": " كربونات", "probability": 0.88955078125}, {"start": 197.3, "end": 197.52, "word": " اذا", "probability": 0.6883544921875}, {"start": 197.52, "end": 197.92, "word": " بحكي", "probability": 0.951904296875}, {"start": 197.92, "end": 198.14, "word": " انا", "probability": 0.681640625}, {"start": 198.14, "end": 198.42, "word": " عن", "probability": 0.9853515625}, {"start": 198.42, "end": 199.44, "word": " بيوتانون", "probability": 0.85517578125}, {"start": 199.44, "end": 200.0, "word": " ال", "probability": 0.76171875}, {"start": 200.0, "end": 200.12, "word": " C", "probability": 0.2076416015625}, {"start": 200.12, "end": 200.34, "word": " double", "probability": 0.58984375}, {"start": 200.34, "end": 200.66, "word": " bond", "probability": 0.89111328125}, {"start": 200.66, "end": 200.84, "word": " O", "probability": 0.849609375}, {"start": 200.84, "end": 201.16, "word": " جاية", "probability": 0.81982421875}, {"start": 201.16, "end": 201.36, "word": " فيه", "probability": 0.90966796875}, {"start": 201.36, "end": 201.48, "word": " على", "probability": 0.83349609375}, {"start": 201.48, "end": 202.04, "word": " موقع", "probability": 0.9812825520833334}, {"start": 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0.822509765625}, {"start": 783.78, "end": 783.96, "word": " هو", "probability": 0.986328125}, {"start": 783.96, "end": 784.12, "word": " ال", "probability": 0.75830078125}, {"start": 784.12, "end": 784.34, "word": " common", "probability": 0.8095703125}, {"start": 784.34, "end": 785.22, "word": " nomenclature", "probability": 0.8829345703125}], "temperature": 1.0}, {"id": 34, "seek": 80144, "start": 786.14, "end": 801.44, "text": "ماشي لبيوتنال هو نفسه بيوترالديهيد أخدناه في أول slides لما قلنا بروبيونالديهيد وبيوتيرالديهيد الناس الشطرين اللي بيحفظوا هاي بيوتنال بيوتيرالديهيد", "tokens": [2304, 33599, 1829, 5296, 21292, 35473, 1863, 6027, 31439, 8717, 36178, 3224, 4724, 1829, 35473, 2288, 6027, 16254, 3224, 25708, 5551, 9778, 3215, 8315, 3224, 8978, 5551, 12610, 9788, 5296, 15042, 12174, 1211, 8315, 4724, 32887, 21292, 11536, 6027, 16254, 3224, 25708, 4032, 21292, 35473, 13546, 6027, 16254, 3224, 25708, 2423, 8315, 3794, 25124, 9566, 2288, 9957, 13672, 1829, 4724, 1829, 5016, 5172, 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"text": "الان لو كنا بنسمي فيه ال common nomenclature وبنعبر عن البروم هنا بنعبرش بنظام الترقيم هذا لأ بنيجي بنقول والله الموقع الأول بعد ال c double bond o بنعطيه alpha الموقع اللي بعده beta الموقع اللي بعده gamma و هكذا فلاحظوا ان الموقع alpha بالنسبة ل c double bond o هو موقع ايش", "tokens": [6027, 7649, 45164, 9122, 8315, 44945, 38251, 1829, 8978, 3224, 2423, 2689, 297, 4726, 3474, 1503, 46599, 1863, 3615, 3555, 2288, 18871, 2423, 26890, 20498, 34105, 44945, 3615, 3555, 2288, 8592, 44945, 19913, 10943, 16712, 2288, 4587, 32640, 23758, 5296, 10721, 44945, 1829, 7435, 1829, 44945, 39648, 16070, 43761, 9673, 30543, 3615, 16247, 12610, 39182, 2423, 269, 3834, 6086, 277, 44945, 3615, 9566, 1829, 3224, 8961, 9673, 30543, 3615, 13672, 1829, 39182, 3224, 9861, 9673, 30543, 3615, 13672, 1829, 39182, 3224, 15546, 4032, 8032, 4117, 15730, 6156, 15040, 5016, 19913, 14407, 16472, 9673, 30543, 3615, 8961, 20666, 1863, 35457, 3660, 5296, 269, 3834, 6086, 277, 31439, 3714, 30543, 3615, 1975, 1829, 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بال bond O بنظام ال أيوبك على موقع اتنين بنظام ال common موقع اتنين بيكون موقع Alpha مش Beta يعني مابنجيش نحط Alpha هان و Beta هان لأ ال Alpha هي موقع اتنين", "tokens": [5172, 28814, 15730, 44713, 25957, 1211, 8315, 5296, 2407, 9381, 5172, 9673, 14407, 4587, 3615, 25724, 7649, 3555, 21136, 1829, 11242, 3660, 20666, 39184, 6086, 422, 20588, 4032, 33286, 4032, 24723, 1696, 34051, 25961, 18871, 16254, 36632, 13412, 17082, 1211, 8032, 7649, 4724, 39648, 39896, 20666, 1863, 35457, 3660, 24976, 3794, 1829, 11242, 3660, 20666, 6086, 422, 44945, 19913, 10943, 2423, 36632, 37746, 4117, 15844, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 44945, 19913, 10943, 2423, 2689, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 4724, 1829, 30544, 3714, 30543, 3615, 20588, 37893, 33286, 37495, 22653, 3714, 16758, 1863, 7435, 1829, 8592, 8717, 5016, 9566, 20588, 8032, 7649, 4032, 33286, 8032, 7649, 5296, 10721, 2423, 20588, 39896, 3714, 30543, 3615, 1975, 2655, 1863, 9957], "avg_logprob": -0.18447580789366075, 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0.93212890625}, {"start": 869.36, "end": 869.9, "word": " موقع", "probability": 0.9580078125}, {"start": 869.9, "end": 870.32, "word": " اتنين", "probability": 0.98828125}, {"start": 870.32, "end": 870.64, "word": " بيكون", "probability": 0.8834635416666666}, {"start": 870.64, "end": 871.1, "word": " موقع", "probability": 0.9619140625}, {"start": 871.1, "end": 872.26, "word": " Alpha", "probability": 0.485595703125}, {"start": 872.26, "end": 872.76, "word": " مش", "probability": 0.9189453125}, {"start": 872.76, "end": 873.9, "word": " Beta", "probability": 0.7451171875}, {"start": 873.9, "end": 874.56, "word": " يعني", "probability": 0.9326171875}, {"start": 874.56, "end": 875.1, "word": " مابنجيش", "probability": 0.9232584635416666}, {"start": 875.1, "end": 875.44, "word": " نحط", "probability": 0.8704427083333334}, {"start": 875.44, "end": 875.88, "word": " Alpha", "probability": 0.9443359375}, {"start": 875.88, "end": 876.42, "word": " هان", "probability": 0.80712890625}, {"start": 876.42, "end": 876.72, "word": " و", "probability": 0.96923828125}, {"start": 876.72, "end": 877.04, "word": " Beta", "probability": 0.79736328125}, {"start": 877.04, "end": 877.58, "word": " هان", "probability": 0.88916015625}, {"start": 877.58, "end": 877.98, "word": " لأ", "probability": 0.91796875}, {"start": 877.98, "end": 878.18, "word": " ال", "probability": 0.953125}, {"start": 878.18, "end": 878.66, "word": " Alpha", "probability": 0.84375}, {"start": 878.66, "end": 879.06, "word": " هي", "probability": 0.9013671875}, {"start": 879.06, "end": 879.46, "word": " موقع", "probability": 0.9949544270833334}, {"start": 879.46, "end": 879.84, "word": " اتنين", "probability": 0.98828125}], "temperature": 1.0}, {"id": 38, "seek": 89504, "start": 880.38, "end": 895.04, "text": "وبنمشي ولذلك هذا المركب مثلا واحد اتنين تلاتة حامل OH بال .. بال IUPAC Nomenclature three hydroxybutanol في اي مشكلة؟ three hydroxybutanol", "tokens": [37746, 1863, 2304, 8592, 1829, 4032, 1211, 8848, 23275, 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0.970458984375}, {"start": 884.4, "end": 884.9, "word": " تلاتة", "probability": 0.940185546875}, {"start": 884.9, "end": 885.3, "word": " حامل", "probability": 0.9777018229166666}, {"start": 885.3, "end": 885.88, "word": " OH", "probability": 0.50927734375}, {"start": 885.88, "end": 886.86, "word": " بال", "probability": 0.71875}, {"start": 886.86, "end": 887.02, "word": " ..", "probability": 0.160888671875}, {"start": 887.02, "end": 887.46, "word": " بال", "probability": 0.892578125}, {"start": 887.46, "end": 888.04, "word": " IUPAC", "probability": 0.499755859375}, {"start": 888.04, "end": 889.0, "word": " Nomenclature", "probability": 0.81951904296875}, {"start": 889.0, "end": 889.42, "word": " three", "probability": 0.290771484375}, {"start": 889.42, "end": 891.04, "word": " hydroxybutanol", "probability": 0.700439453125}, {"start": 891.04, "end": 891.26, "word": " في", "probability": 0.77978515625}, {"start": 891.26, "end": 891.46, "word": " اي", "probability": 0.830078125}, 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"word": " ايش", "probability": 0.6066080729166666}, {"start": 899.13, "end": 899.97, "word": " هنسميه", "probability": 0.90751953125}, {"start": 899.97, "end": 900.77, "word": " هى", "probability": 0.5478515625}, {"start": 900.77, "end": 901.15, "word": " Alpha", "probability": 0.453125}, {"start": 901.15, "end": 901.47, "word": " هى", "probability": 0.86328125}, {"start": 901.47, "end": 901.83, "word": " Beta", "probability": 0.87744140625}, {"start": 901.83, "end": 902.21, "word": " Beta", "probability": 0.430908203125}, {"start": 902.21, "end": 904.23, "word": "-hydroxybutyraldehyde", "probability": 0.878125}, {"start": 904.23, "end": 904.57, "word": " لاحظوا", "probability": 0.76513671875}, {"start": 904.57, "end": 904.77, "word": " هذه", "probability": 0.3544921875}, {"start": 904.77, "end": 904.91, "word": " اللى", "probability": 0.748779296875}, {"start": 904.91, "end": 905.51, "word": " كتبناها", "probability": 0.9755859375}, {"start": 905.51, "end": 906.17, "word": " EY", 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"probability": 0.9873046875}, {"start": 915.73, "end": 916.17, "word": " قرأ", "probability": 0.97900390625}, {"start": 916.17, "end": 917.39, "word": " هالشغلة", "probability": 0.88076171875}, {"start": 917.39, "end": 918.01, "word": " في", "probability": 0.876953125}, {"start": 918.01, "end": 918.21, "word": " يوم", "probability": 0.965087890625}, {"start": 918.21, "end": 918.33, "word": " من", "probability": 0.70068359375}, {"start": 918.33, "end": 918.73, "word": " الأيام", "probability": 0.8855794270833334}, {"start": 918.73, "end": 919.61, "word": " مايستغربش", "probability": 0.9153645833333334}, {"start": 919.61, "end": 919.77, "word": " يعني", "probability": 0.859130859375}, {"start": 919.77, "end": 920.47, "word": " مايفكرش", "probability": 0.943603515625}, {"start": 920.47, "end": 920.67, "word": " ان", "probability": 0.8740234375}, {"start": 920.67, "end": 921.13, "word": " واحد", "probability": 0.986572265625}, {"start": 921.13, "end": 921.57, "word": " هيكون", "probability": 0.7763671875}, {"start": 921.57, "end": 921.89, "word": " Alpha", "probability": 0.9482421875}, {"start": 921.89, "end": 922.47, "word": " اتنين", "probability": 0.9603271484375}, {"start": 922.47, "end": 922.81, "word": " Beta", "probability": 0.68603515625}, {"start": 922.81, "end": 923.03, "word": " زى", "probability": 0.849609375}, {"start": 923.03, "end": 923.11, "word": " ما", "probability": 0.9775390625}, {"start": 923.11, "end": 923.35, "word": " انتوا", "probability": 0.8154296875}, {"start": 923.35, "end": 923.63, "word": " فاهمين", "probability": 0.98046875}, {"start": 923.63, "end": 924.21, "word": " لأ", "probability": 0.884521484375}, {"start": 924.21, "end": 924.43, "word": " هو", "probability": 0.95947265625}, {"start": 924.43, "end": 925.01, "word": " موقع", "probability": 0.99462890625}, {"start": 925.01, "end": 925.67, "word": " اتنين", "probability": 0.9898681640625}], "temperature": 1.0}, {"id": 40, "seek": 94744, "start": 926.5, "end": 947.44, "text": "في ال IUPAC بيكون Alpha في ال common nomenclature طبعا بتيجي شغلات تانية، الان لو افترضتوا ان كان عندكم ال ketone on طب لو صار عندكم اتنين C double bond O ketone ايش هتستعمله؟ Dione", "tokens": [41185, 2423, 286, 22917, 4378, 4724, 1829, 30544, 20588, 8978, 2423, 2689, 297, 4726, 3474, 1503, 23032, 3555, 3615, 995, 39894, 1829, 7435, 1829, 13412, 17082, 1211, 9307, 6055, 7649, 10632, 12399, 2423, 7649, 45164, 1975, 5172, 2655, 43042, 2655, 14407, 16472, 25961, 43242, 24793, 2423, 14979, 546, 322, 23032, 3555, 45164, 20328, 9640, 43242, 24793, 1975, 2655, 1863, 9957, 383, 3834, 6086, 422, 14979, 546, 1975, 1829, 8592, 8032, 2655, 14851, 25957, 43761, 22807, 413, 5328], "avg_logprob": -0.31089742940205795, "compression_ratio": 1.3724489795918366, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 926.5, "end": 926.76, "word": "في", "probability": 0.364501953125}, {"start": 926.76, "end": 926.92, "word": " ال", "probability": 0.63525390625}, {"start": 926.92, "end": 927.56, "word": " IUPAC", "probability": 0.5506184895833334}, {"start": 927.56, "end": 928.56, "word": " بيكون", "probability": 0.7037353515625}, {"start": 928.56, "end": 929.1, "word": " Alpha", "probability": 0.45654296875}, {"start": 929.1, "end": 930.02, "word": " في", "probability": 0.90087890625}, {"start": 930.02, "end": 930.9, "word": " ال", "probability": 0.701171875}, {"start": 930.9, "end": 931.16, "word": " common", "probability": 0.828125}, {"start": 931.16, "end": 932.08, "word": " nomenclature", "probability": 0.8507080078125}, {"start": 932.08, "end": 933.1, "word": " طبعا", "probability": 0.9735107421875}, {"start": 933.1, "end": 933.48, "word": " بتيجي", "probability": 0.8297119140625}, {"start": 933.48, "end": 933.98, "word": " شغلات", "probability": 0.7701416015625}, {"start": 933.98, "end": 934.8, "word": " تانية،", "probability": 0.80474853515625}, {"start": 934.8, "end": 935.2, "word": " الان", "probability": 0.56146240234375}, {"start": 935.2, "end": 935.58, 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0.910400390625}, {"start": 941.58, "end": 941.8, "word": " C", "probability": 0.60009765625}, {"start": 941.8, "end": 942.1, "word": " double", "probability": 0.70361328125}, {"start": 942.1, "end": 942.46, "word": " bond", "probability": 0.9501953125}, {"start": 942.46, "end": 942.72, "word": " O", "probability": 0.92431640625}, {"start": 942.72, "end": 944.22, "word": " ketone", "probability": 0.72265625}, {"start": 944.22, "end": 944.64, "word": " ايش", "probability": 0.7696940104166666}, {"start": 944.64, "end": 946.72, "word": " هتستعمله؟", "probability": 0.853759765625}, {"start": 946.72, "end": 947.44, "word": " Dione", "probability": 0.46539306640625}], "temperature": 1.0}, {"id": 41, "seek": 97515, "start": 948.47, "end": 975.15, "text": "زي ما كان يكون ال alcohol all كنا نستعمل die all و try all و تترا all كذلك الحال لو كان عندنا تنتين كيتون الكيتون الواحد on اتنين كيتون die on تلاتة كيتون try on فهذا المركب مثلا سايكلو بنتان on ولا بنتان die on هي on و on", "tokens": [11622, 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{"start": 1148.92, "end": 1149.34, "word": " في", "probability": 0.8076171875}, {"start": 1149.34, "end": 1150.0, "word": " القديم", "probability": 0.9814453125}, {"start": 1150.0, "end": 1150.16, "word": " اللي", "probability": 0.88525390625}, {"start": 1150.16, "end": 1150.54, "word": " الناس", "probability": 0.9695638020833334}, {"start": 1150.54, "end": 1150.76, "word": " مش", "probability": 0.99169921875}, {"start": 1150.76, "end": 1151.52, "word": " متذاكرة", "probability": 0.8502197265625}, {"start": 1151.52, "end": 1152.12, "word": " قولنا", "probability": 0.7789713541666666}, {"start": 1152.12, "end": 1152.32, "word": " اذا", "probability": 0.756103515625}, {"start": 1152.32, "end": 1152.64, "word": " كانوا", "probability": 0.974853515625}, {"start": 1152.64, "end": 1153.06, "word": " اربعة", "probability": 0.86279296875}, {"start": 1153.06, "end": 1153.3, "word": " هي", "probability": 0.4541015625}, {"start": 1153.3, "end": 1153.8, "word": " واحد", "probability": 0.940673828125}, {"start": 1153.8, "end": 1154.34, "word": " اتنين", "probability": 0.9599609375}, {"start": 1154.34, "end": 1154.98, "word": " تلاتة", "probability": 0.9185791015625}, {"start": 1154.98, "end": 1155.3, "word": " اربعة", "probability": 0.9453125}, {"start": 1155.3, "end": 1155.92, "word": " والاتصال", "probability": 0.84197998046875}, {"start": 1155.92, "end": 1156.08, "word": " من", "probability": 0.94921875}, {"start": 1156.08, "end": 1156.52, "word": " موقع", "probability": 0.9609375}, {"start": 1156.52, "end": 1157.06, "word": " اتنين", "probability": 0.9652099609375}, {"start": 1157.06, "end": 1157.96, "word": " اسمها", "probability": 0.9256184895833334}, {"start": 1157.96, "end": 1158.96, "word": " secondary", "probability": 0.85693359375}, {"start": 1158.96, "end": 1159.8, "word": " butyl", "probability": 0.5931396484375}, {"start": 1159.8, "end": 1160.82, "word": " ترجعوا", "probability": 0.9609375}, {"start": 1160.82, "end": 1161.28, "word": " عندكم", "probability": 0.7056884765625}, {"start": 1161.28, "end": 1162.28, "word": " بتلاحظوا", "probability": 0.9412109375}, {"start": 1162.28, "end": 1164.66, "word": " secondary", "probability": 0.387451171875}, {"start": 1164.66, "end": 1166.84, "word": " butyl", "probability": 0.950439453125}, {"start": 1166.84, "end": 1168.4, "word": " شايفين", "probability": 0.9093017578125}, {"start": 1168.4, "end": 1168.76, "word": " الناس", "probability": 0.9903971354166666}, {"start": 1168.76, "end": 1168.9, "word": " اللي", "probability": 0.984130859375}, {"start": 1168.9, "end": 1169.5, "word": " بدرسوش", "probability": 0.98505859375}, {"start": 1169.5, "end": 1170.02, "word": " كتير", "probability": 0.9820963541666666}, {"start": 1170.02, "end": 1171.62, "word": " secondary", "probability": 0.62060546875}, {"start": 1171.62, "end": 1172.58, "word": " butyl", "probability": 0.96630859375}], "temperature": 1.0}, {"id": 50, "seek": 120402, "start": 1174.4, "end": 1204.02, "text": "اخدتوها بوضوح جدا سكندر بيوت الـ Cyclopropane طيب الآن هنا اعتبرنا الأساس إيش؟ الـ Cyclopropane هل يا تورا ممكن أننا نعتبر الأساس السلسلة؟ أكيد لما نعتبر الأساس السلسلة، شو هنقول؟ البيوتين على نمرأ اتنين من البيوتين، إيش عندكم؟ Cyclopropane", "tokens": [47283, 3215, 2655, 2407, 11296, 4724, 2407, 11242, 2407, 5016, 10874, 28259, 8608, 19452, 3215, 2288, 4724, 1829, 35473, 2423, 39184, 49173, 404, 1513, 1929, 23032, 1829, 3555, 6024, 48506, 34105, 1975, 34268, 26890, 8315, 16247, 3794, 32277, 11933, 1829, 8592, 22807, 2423, 39184, 49173, 404, 1513, 1929, 8032, 1211, 35186, 6055, 13063, 995, 3714, 43020, 14739, 8315, 8717, 34268, 26890, 16247, 3794, 32277, 21136, 1211, 3794, 37977, 22807, 5551, 4117, 25708, 5296, 15042, 8717, 34268, 26890, 16247, 3794, 32277, 21136, 1211, 3794, 37977, 12399, 13412, 2407, 8032, 1863, 39648, 22807, 2423, 21292, 35473, 9957, 15844, 8717, 29973, 10721, 1975, 2655, 1863, 9957, 9154, 2423, 21292, 35473, 9957, 12399, 11933, 1829, 8592, 43242, 24793, 22807, 49173, 404, 1513, 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"probability": 0.8958740234375}, {"start": 1200.66, "end": 1200.9, "word": " من", "probability": 0.9951171875}, {"start": 1200.9, "end": 1201.8, "word": " البيوتين،", "probability": 0.9421875}, {"start": 1201.8, "end": 1202.0, "word": " إيش", "probability": 0.9363606770833334}, {"start": 1202.0, "end": 1202.76, "word": " عندكم؟", "probability": 0.982421875}, {"start": 1202.76, "end": 1204.02, "word": " Cyclopropane", "probability": 0.871826171875}], "temperature": 1.0}, {"id": 51, "seek": 122129, "start": 1204.89, "end": 1221.29, "text": "لحتى الآن مش عمال تقدروا تذكرواها بإنصيغة مجموعة بزام Cyclopropane لما يصير مجموعة شو هيصير؟ Cyclopropane اذا اتنين Cyclopropane", "tokens": [1211, 33753, 7578, 6024, 48506, 37893, 6225, 2304, 6027, 6055, 28543, 2288, 14407, 6055, 8848, 37983, 14407, 11296, 4724, 28814, 1863, 9381, 1829, 17082, 3660, 3714, 7435, 2304, 2407, 27884, 4724, 11622, 10943, 49173, 404, 1513, 1929, 5296, 15042, 7251, 9381, 13546, 3714, 7435, 2304, 2407, 27884, 13412, 2407, 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ال cyclopropane هو نفسه اتنين cyclopropyl butane يعني انا لما اجيت اسميه .. انا لما اجيت اسميه .. قولت يا تورا بدي اخلي مرجعيتي الحلقة ولا اخلي مرجعيتي ايش؟", "tokens": [2407, 46958, 5016, 22807, 6156, 6027, 3794, 19452, 3215, 2288, 1829, 4724, 1829, 35473, 2423, 19474, 404, 1513, 1929, 31439, 8717, 36178, 3224, 1975, 2655, 1863, 9957, 19474, 404, 1513, 5088, 457, 1929, 37495, 22653, 1975, 8315, 5296, 15042, 1975, 7435, 36081, 24525, 2304, 1829, 3224, 4386, 1975, 8315, 5296, 15042, 1975, 7435, 36081, 24525, 2304, 1829, 3224, 4386, 12174, 12610, 2655, 35186, 6055, 13063, 995, 4724, 16254, 1975, 9778, 20292, 3714, 47341, 3615, 1829, 31371, 21542, 1211, 28671, 49429, 1975, 9778, 20292, 3714, 47341, 3615, 1829, 31371, 1975, 1829, 8592, 22807], "avg_logprob": -0.19506048066641696, "compression_ratio": 1.7159763313609468, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1223.62, "end": 1224.54, "word": "واضح؟", "probability": 0.8824462890625}, {"start": 1224.54, "end": 1225.62, "word": " فالسكندري", "probability": 0.794677734375}, {"start": 1225.62, "end": 1226.02, "word": " بيوت", "probability": 0.8990885416666666}, {"start": 1226.02, "end": 1226.28, "word": " ال", "probability": 0.76318359375}, {"start": 1226.28, "end": 1228.22, "word": " cyclopropane", "probability": 0.72235107421875}, {"start": 1228.22, "end": 1228.74, "word": " هو", "probability": 0.98388671875}, {"start": 1228.74, "end": 1229.7, "word": " نفسه", "probability": 0.99609375}, {"start": 1229.7, "end": 1230.42, "word": " اتنين", "probability": 0.9351806640625}, {"start": 1230.42, "end": 1231.86, "word": " cyclopropyl", "probability": 0.758056640625}, {"start": 1231.86, "end": 1232.64, "word": " butane", "probability": 0.6990966796875}, {"start": 1232.64, "end": 1233.2, "word": " يعني", "probability": 0.869384765625}, {"start": 1233.2, "end": 1233.52, "word": " انا", "probability": 0.782470703125}, {"start": 1233.52, "end": 1233.76, "word": " لما", "probability": 0.934326171875}, {"start": 1233.76, "end": 1234.22, "word": " اجيت", "probability": 0.8492838541666666}, {"start": 1234.22, "end": 1235.22, "word": " اسميه", "probability": 0.8470458984375}, {"start": 1235.22, "end": 1235.22, "word": " ..", "probability": 0.6240234375}, {"start": 1235.22, "end": 1235.46, "word": " انا", "probability": 0.878662109375}, {"start": 1235.46, "end": 1235.64, "word": " لما", "probability": 0.989990234375}, {"start": 1235.64, "end": 1236.0, "word": " اجيت", "probability": 0.9856770833333334}, {"start": 1236.0, "end": 1236.88, "word": " اسميه", "probability": 0.9793701171875}, {"start": 1236.88, "end": 1236.98, "word": " ..", "probability": 0.432373046875}, {"start": 1236.98, "end": 1237.3, "word": " قولت", "probability": 0.8235677083333334}, {"start": 1237.3, "end": 1237.42, "word": " يا", "probability": 0.9130859375}, {"start": 1237.42, "end": 1237.76, "word": " تورا", "probability": 0.7556966145833334}, {"start": 1237.76, "end": 1238.2, "word": " بدي", "probability": 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1443.92, "text": "واضحت الفكرة تماما ولا فيها مشكلة الان طيب اذا هذا المثال دخل في ال behind او كيتون يعني افترض انه خلته زي هي", "tokens": [2407, 46958, 5016, 2655, 27188, 4117, 25720, 46811, 10943, 995, 49429, 8978, 11296, 37893, 28820, 3660, 2423, 7649, 23032, 1829, 3555, 1975, 15730, 23758, 9673, 12984, 6027, 11778, 9778, 1211, 8978, 2423, 2261, 1975, 2407, 9122, 36081, 11536, 37495, 22653, 1975, 5172, 2655, 43042, 16472, 3224, 16490, 1211, 47395, 30767, 1829, 39896], "avg_logprob": -0.22199292340368595, "compression_ratio": 1.4393939393939394, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1423.88, "end": 1424.38, "word": "واضحت", "probability": 0.7449951171875}, {"start": 1424.38, "end": 1424.82, "word": " الفكرة", "probability": 0.9915364583333334}, {"start": 1424.82, "end": 1429.06, "word": " تماما", "probability": 0.9905598958333334}, {"start": 1429.06, "end": 1430.12, "word": " ولا", "probability": 0.5673828125}, {"start": 1430.12, "end": 1430.38, "word": " 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{"start": 2804.9, "end": 2805.2, "word": " فيكم", "probability": 0.86328125}, {"start": 2805.2, "end": 2805.7, "word": " اتذكر", "probability": 0.77886962890625}, {"start": 2805.7, "end": 2805.96, "word": " انه", "probability": 0.840087890625}, {"start": 2805.96, "end": 2806.44, "word": " سمناه", "probability": 0.808837890625}, {"start": 2806.44, "end": 2807.14, "word": " كيومين؟", "probability": 0.9478515625}], "temperature": 1.0}, {"id": 118, "seek": 283446, "start": 2808.08, "end": 2834.46, "text": "هذا الكيومين مع الـ Oxygen و Sulphuric Acid بيكسل تفاعل كتير هذا مهم لسبب بسيط انه بيعطي ناتجين مهمات مش ناتج واحد من هنا بيكسل هذه بتصير CWO وهذه بتصير CWO الآن هذا الجزء CH3 CH3 هو ايش ال Acetone هذا الجزء بيحول الى Enol بيصير Phenol", "tokens": [3224, 15730, 33251, 1829, 20498, 9957, 20449, 2423, 39184, 16489, 8647, 4032, 35897, 950, 374, 299, 5097, 327, 4724, 1829, 4117, 3794, 1211, 6055, 5172, 995, 30241, 9122, 2655, 13546, 23758, 3714, 16095, 5296, 35457, 3555, 4724, 3794, 1829, 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"probability": 0.772705078125}, {"start": 2811.0, "end": 2811.14, "word": " و", "probability": 0.85546875}, {"start": 2811.14, "end": 2811.78, "word": " Sulphuric", "probability": 0.7913818359375}, {"start": 2811.78, "end": 2812.28, "word": " Acid", "probability": 0.754638671875}, {"start": 2812.28, "end": 2813.38, "word": " بيكسل", "probability": 0.747998046875}, {"start": 2813.38, "end": 2814.14, "word": " تفاعل", "probability": 0.85986328125}, {"start": 2814.14, "end": 2814.48, "word": " كتير", "probability": 0.9246419270833334}, {"start": 2814.48, "end": 2814.68, "word": " هذا", "probability": 0.5712890625}, {"start": 2814.68, "end": 2815.08, "word": " مهم", "probability": 0.9755859375}, {"start": 2815.08, "end": 2815.54, "word": " لسبب", "probability": 0.95947265625}, {"start": 2815.54, "end": 2815.9, "word": " بسيط", "probability": 0.9969482421875}, {"start": 2815.9, "end": 2816.1, "word": " انه", "probability": 0.73828125}, {"start": 2816.1, "end": 2816.5, "word": " بيعطي", "probability": 0.9453125}, {"start": 2816.5, "end": 2817.04, "word": " ناتجين", "probability": 0.969970703125}, {"start": 2817.04, "end": 2817.72, "word": " مهمات", "probability": 0.810791015625}, {"start": 2817.72, "end": 2818.12, "word": " مش", "probability": 0.69091796875}, {"start": 2818.12, "end": 2818.5, "word": " ناتج", "probability": 0.99072265625}, {"start": 2818.5, "end": 2818.96, "word": " واحد", "probability": 0.99462890625}, {"start": 2818.96, "end": 2819.56, "word": " من", "probability": 0.76171875}, {"start": 2819.56, "end": 2819.82, "word": " هنا", "probability": 0.9462890625}, {"start": 2819.82, "end": 2820.42, "word": " بيكسل", "probability": 0.93818359375}, {"start": 2820.42, "end": 2820.88, "word": " هذه", "probability": 0.4404296875}, {"start": 2820.88, "end": 2821.32, "word": " بتصير", "probability": 0.84912109375}, {"start": 2821.32, "end": 2822.22, "word": " CWO", "probability": 0.3365885416666667}, {"start": 2822.22, "end": 2822.52, "word": " وهذه", "probability": 0.6563720703125}, {"start": 2822.52, "end": 2822.88, "word": " بتصير", "probability": 0.8719075520833334}, {"start": 2822.88, "end": 2823.68, "word": " CWO", "probability": 0.9293619791666666}, {"start": 2823.68, "end": 2824.42, "word": " الآن", "probability": 0.640380859375}, {"start": 2824.42, "end": 2824.78, "word": " هذا", "probability": 0.9267578125}, {"start": 2824.78, "end": 2825.24, "word": " الجزء", "probability": 0.98291015625}, {"start": 2825.24, "end": 2825.86, "word": " CH3", "probability": 0.95068359375}, {"start": 2825.86, "end": 2827.24, "word": " CH3", "probability": 0.72509765625}, {"start": 2827.24, "end": 2827.54, "word": " هو", "probability": 0.68115234375}, {"start": 2827.54, "end": 2828.04, "word": " ايش", "probability": 0.6817220052083334}, {"start": 2828.04, "end": 2828.84, "word": " ال", "probability": 0.78955078125}, {"start": 2828.84, "end": 2829.42, "word": " Acetone", "probability": 0.710205078125}, {"start": 2829.42, "end": 2829.88, "word": " هذا", "probability": 0.912109375}, {"start": 2829.88, "end": 2830.5, "word": " الجزء", "probability": 0.9931640625}, {"start": 2830.5, "end": 2831.9, "word": " بيحول", "probability": 0.9346923828125}, {"start": 2831.9, "end": 2832.5, "word": " الى", "probability": 0.614990234375}, {"start": 2832.5, "end": 2833.1, "word": " Enol", "probability": 0.6776123046875}, {"start": 2833.1, "end": 2833.66, "word": " بيصير", "probability": 0.8712158203125}, {"start": 2833.66, "end": 2834.46, "word": " Phenol", "probability": 0.9444986979166666}], "temperature": 1.0}, {"id": 119, "seek": 286387, "start": 2836.31, "end": 2863.87, "text": "فتفاعل الكيومين مع الأكسجين وحمض الكابريتيك إيش بيعطينا؟ Phenol and Acetone يعني لو بدنا نسألكوا reaction of الكيومين with أكسجين و presence of sulphuric acid بطريقة معينة produces Phenol and Acetone و هدولة المركبين إيش مالهم؟ مركبات مهمة جدا في ال organ الchemistry", "tokens": [5172, 2655, 5172, 995, 30241, 33251, 1829, 20498, 9957, 20449, 16247, 4117, 3794, 7435, 9957, 4032, 35571, 11242, 33251, 16758, 16572, 31371, 4117, 11933, 1829, 8592, 4724, 40228, 9566, 1829, 8315, 22807, 2623, 268, 401, 293, 5097, 302, 546, 37495, 22653, 45164, 47525, 8315, 8717, 3794, 10721, 23275, 14407, 5480, 295, 33251, 1829, 20498, 9957, 365, 5551, 4117, 3794, 7435, 9957, 4032, 6814, 295, 47286, 374, 299, 8258, 4724, 9566, 16572, 28671, 20449, 9957, 3660, 14725, 2623, 268, 401, 293, 5097, 302, 546, 4032, 8032, 3215, 12610, 3660, 9673, 31747, 3555, 9957, 11933, 1829, 8592, 3714, 6027, 16095, 22807, 3714, 31747, 3555, 9307, 3714, 16095, 3660, 10874, 28259, 8978, 2423, 1798, 2423, 48353], "avg_logprob": -0.2420504417335778, "compression_ratio": 1.597609561752988, "no_speech_prob": 0.0, "words": [{"start": 2836.3100000000004, "end": 2837.51, "word": "فتفاعل", "probability": 0.828515625}, {"start": 2837.51, "end": 2838.25, "word": " الكيومين", "probability": 0.8558349609375}, {"start": 2838.25, "end": 2838.45, "word": " مع", "probability": 0.95654296875}, {"start": 2838.45, "end": 2839.23, "word": " الأكسجين", "probability": 0.803759765625}, {"start": 2839.23, "end": 2839.79, "word": " وحمض", "probability": 0.912109375}, {"start": 2839.79, "end": 2840.73, "word": " الكابريتيك", "probability": 0.82587890625}, {"start": 2840.73, "end": 2841.15, "word": " إيش", "probability": 0.6745402018229166}, {"start": 2841.15, "end": 2842.63, "word": " بيعطينا؟", "probability": 0.8920084635416666}, {"start": 2842.63, "end": 2843.37, "word": " Phenol", "probability": 0.691650390625}, {"start": 2843.37, "end": 2844.11, "word": " and", "probability": 0.79931640625}, {"start": 2844.11, "end": 2844.73, "word": " Acetone", "probability": 0.7842610677083334}, {"start": 2844.73, "end": 2844.93, "word": " يعني", "probability": 0.7197265625}, {"start": 2844.93, "end": 2845.11, "word": " لو", "probability": 0.96630859375}, {"start": 2845.11, "end": 2845.37, "word": " بدنا", "probability": 0.8359375}, {"start": 2845.37, "end": 2846.25, "word": " نسألكوا", "probability": 0.86640625}, {"start": 2846.25, "end": 2846.97, "word": " reaction", "probability": 0.59375}, {"start": 2846.97, "end": 2847.41, "word": " of", "probability": 0.93212890625}, {"start": 2847.41, "end": 2848.01, "word": " الكيومين", "probability": 0.9510498046875}, {"start": 2848.01, "end": 2848.21, "word": " with", "probability": 0.77197265625}, {"start": 2848.21, "end": 2848.79, "word": " أكسجين", "probability": 0.89111328125}, {"start": 2848.79, "end": 2848.91, "word": " و", "probability": 0.196533203125}, {"start": 2848.91, "end": 2849.17, "word": " presence", "probability": 0.1864013671875}, {"start": 2849.17, "end": 2849.83, "word": " of", "probability": 0.95263671875}, {"start": 2849.83, "end": 2850.67, "word": " sulphuric", "probability": 0.7679850260416666}, {"start": 2850.67, "end": 2851.01, "word": " acid", "probability": 0.9619140625}, {"start": 2851.01, "end": 2851.53, "word": " بطريقة", "probability": 0.943603515625}, {"start": 2851.53, "end": 2852.33, "word": " معينة", "probability": 0.98876953125}, {"start": 2852.33, "end": 2854.13, "word": " produces", "probability": 0.73828125}, {"start": 2854.13, "end": 2856.37, "word": " Phenol", "probability": 0.8518880208333334}, {"start": 2856.37, "end": 2856.85, "word": " and", "probability": 0.9638671875}, {"start": 2856.85, "end": 2857.65, "word": " Acetone", "probability": 0.9430338541666666}, {"start": 2857.65, "end": 2857.73, "word": " و", "probability": 0.454833984375}, {"start": 2857.73, "end": 2858.13, "word": " هدولة", "probability": 0.7235107421875}, {"start": 2858.13, "end": 2858.85, "word": " المركبين", "probability": 0.85467529296875}, {"start": 2858.85, "end": 2859.11, "word": " إيش", "probability": 0.9733072916666666}, {"start": 2859.11, "end": 2860.05, "word": " مالهم؟", "probability": 0.8739013671875}, {"start": 2860.05, "end": 2860.89, "word": " مركبات", "probability": 0.9725341796875}, {"start": 2860.89, "end": 2861.97, "word": " مهمة", "probability": 0.9899088541666666}, {"start": 2861.97, "end": 2862.71, "word": " جدا", "probability": 0.975830078125}, {"start": 2862.71, "end": 2862.89, "word": " في", "probability": 0.89697265625}, {"start": 2862.89, "end": 2863.03, "word": " ال", "probability": 0.71728515625}, {"start": 2863.03, "end": 2863.31, "word": " organ", "probability": 0.47021484375}, {"start": 2863.31, "end": 2863.87, "word": " الchemistry", "probability": 0.36767578125}], "temperature": 1.0}, {"id": 120, "seek": 287049, "start": 2866.55, "end": 2870.49, "text": "لحد هنا بننهي اليوم ان شاء الله إلى اللقاء", "tokens": [1211, 24401, 34105, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984, 30731, 13672, 4587, 16606], "avg_logprob": -0.2304687516556846, "compression_ratio": 1.1343283582089552, "no_speech_prob": 0.0, "words": [{"start": 2866.55, "end": 2867.07, "word": "لحد", "probability": 0.986328125}, {"start": 2867.07, "end": 2867.49, "word": " هنا", "probability": 0.9580078125}, {"start": 2867.49, "end": 2868.71, "word": " بننهي", "probability": 0.77838134765625}, {"start": 2868.71, "end": 2869.19, "word": " اليوم", "probability": 0.942626953125}, {"start": 2869.19, "end": 2869.37, "word": " ان", "probability": 0.6064453125}, {"start": 2869.37, "end": 2869.65, "word": " شاء", "probability": 0.982421875}, {"start": 2869.65, "end": 2869.79, "word": " الله", "probability": 0.9541015625}, {"start": 2869.79, "end": 2870.01, "word": " إلى", "probability": 0.332275390625}, {"start": 2870.01, "end": 2870.49, "word": " اللقاء", "probability": 0.827880859375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2871.1475, "duration_after_vad": 2750.8587499999935}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..568d9416148a87b1e6d5323b09df9fe822cdbac8
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/3snjlIzta1E_postprocess.srt
@@ -0,0 +1,1864 @@
+1
+00:00:19,510 --> 00:00:24,470
+بسم الله الرحمن الرحيم المرة الماضية بدأنا في
+
+2
+00:00:24,470 --> 00:00:28,170
+موضوع ال libids و ال detergents بشكل أساسي بدأنا
+
+3
+00:00:28,170 --> 00:00:33,130
+نتعرف على ال triglycerides و قلنا أن ال
+
+4
+00:00:33,130 --> 00:00:39,410
+triglycerides من شغلتين من إجليسرول اللي هو بيمثل
+
+5
+00:00:39,410 --> 00:00:44,310
+جزء ال alcohol و fatty acidواضح هدول لما بتحدوا مع
+
+6
+00:00:44,310 --> 00:00:49,490
+بعض بيعملوا عندنا إيش لـ triglycerides لو عملنا
+
+7
+00:00:49,490 --> 00:00:53,110
+hydrolysis تكسير لـ triglycerides ب Sodium
+
+8
+00:00:53,110 --> 00:00:58,650
+hydroxide بنحصل على إجليسرين و fatty acids الآن ال
+
+9
+00:00:58,650 --> 00:01:03,790
+fatty acids عرفناهم إنهم carboxylic acids عادية
+
+10
+00:01:03,790 --> 00:01:08,610
+يعني فيهم مجموعة COOH لكن السلسلة اللي موجودة فيهم
+
+11
+00:01:08,610 --> 00:01:15,130
+بشكل عامسلسلة طويلة و بذلك بيغلب عليهم جانب ال non
+
+12
+00:01:15,130 --> 00:01:21,410
+-polarity و بالتالي بيصيروا بيدوبوا في المذيبات
+
+13
+00:01:21,410 --> 00:01:27,910
+العضوية بشكل عامالان لو بدنا نتعرف اكتر على ال
+
+14
+00:01:27,910 --> 00:01:32,130
+fatty acids، بنقول ال fatty acids في منهم fatty
+
+15
+00:01:32,130 --> 00:01:37,850
+acids saturated، واضح؟ معنى saturated انه موجود
+
+16
+00:01:37,850 --> 00:01:41,330
+فيهم ولا double bond، مافيش فيهم double bonds، وفي
+
+17
+00:01:41,330 --> 00:01:45,670
+unsaturated فيهم double bond او اكتر، واضح؟ فيهم
+
+18
+00:01:45,670 --> 00:01:51,130
+double bond او اكترالان بشكل عام ال fatty acids
+
+19
+00:01:51,130 --> 00:01:55,630
+اللي موجودين في الزيوت و في الدهون بيكونوا عدد ال
+
+20
+00:01:55,630 --> 00:02:01,190
+carbons اللي فيهم عدد زوجييعني هتلاحظوا لما نتعرف
+
+21
+00:02:01,190 --> 00:02:08,450
+عليهم هنبدأ من 12، 14، 16، 18، 20، مش هنحكي عن 13،
+
+22
+00:02:08,450 --> 00:02:14,010
+مش هنحكي عن 15، واضح؟ هذا بيرجع حقيقة إلى فكرة
+
+23
+00:02:14,010 --> 00:02:17,630
+تحضيرهم في الجسم أنه هي فكرة مضاعفات اتنين، يعني
+
+24
+00:02:17,630 --> 00:02:21,870
+بيكون في عندى اتنينبيجيهم كمان اتنين بيصيروا اربعة
+
+25
+00:02:21,870 --> 00:02:24,730
+كمان اتنين بيصيروا ستة كمان اتنين بيصيروا تمانية
+
+26
+00:02:24,730 --> 00:02:29,050
+فزيادة اتنين اتنين اتنين ولذلك لو بدنا نقول انه
+
+27
+00:02:29,050 --> 00:02:33,530
+عدد ال carbons في ال fatty acids odd ولا even
+
+28
+00:02:33,530 --> 00:02:40,970
+الجواب even واضح؟الان المشهورين منهم .. المشهورين
+
+29
+00:02:40,970 --> 00:02:47,970
+منهم اللوريك أسد بنسميه اللي فيه اتناشر كاربون بعد
+
+30
+00:02:47,970 --> 00:02:54,670
+هيك ميريستك أسد اربعة عشر كاربون بالميتك أسد هذا
+
+31
+00:02:54,670 --> 00:03:00,210
+من البلم يعني زيت الاش النخيل بالميتك أسد ستة عشر
+
+32
+00:03:00,210 --> 00:03:07,250
+استيرك أسداللي هو حامض ضهني تمنتعش و arachidic
+
+33
+00:03:07,250 --> 00:03:12,830
+acid .. arachidic acid اللي هو إيش؟ عشرين يمكن لما
+
+34
+00:03:12,830 --> 00:03:19,110
+تسمعوا كلمة stearic تظل في مخكم تخربطلها مع كلمة
+
+35
+00:03:19,110 --> 00:03:27,970
+تانية مع حمض تاني citric acid مرات
+
+36
+00:03:27,970 --> 00:03:32,320
+اللي ..اللي بيكون مش متعود ع الكلام بيخلطوا
+
+37
+00:03:32,320 --> 00:03:36,720
+الكلمتين citric استيرك بيصير خربطهم citric acid
+
+38
+00:03:36,720 --> 00:03:45,100
+حمض اللمون حمض اللمون و citronel لمون واضح؟ الآن
+
+39
+00:03:45,100 --> 00:03:49,940
+استيرك حمض دهني ال citric acid حامض تاني بشكل معين
+
+40
+00:03:49,940 --> 00:03:54,500
+فيه تلت مجموعات carboxylic acids مش موضوعنا فلما
+
+41
+00:03:54,500 --> 00:04:00,350
+نقول citric غير عنstearic ولذلك انتوا لما تكونوا
+
+42
+00:04:00,350 --> 00:04:05,110
+تقرأوا المكونات ضالكوا ميزوا عن الشغلتين عن بعض
+
+43
+00:04:05,110 --> 00:04:12,250
+يعني لو بتقرأوا مثلا في مادة أخذية على سبيل المثال
+
+44
+00:04:12,250 --> 00:04:18,710
+مع شوية drops للزور لإشي زي هيك يمكن تلاقوا citric
+
+45
+00:04:18,710 --> 00:04:24,570
+acid حمض لمون لكن لو بتقرأوا في شامبوهات وغيرها
+
+46
+00:04:24,570 --> 00:04:30,350
+وغيراتها يمكن تلاقوا stearicفستيرك شيء وستريك شيء
+
+47
+00:04:30,350 --> 00:04:35,190
+الاستيرك أسد is a fatty is a saturated fatty acid
+
+48
+00:04:35,190 --> 00:04:40,550
+in fact containing 18 carbon atoms واضح الفكرة
+
+49
+00:04:40,550 --> 00:04:45,890
+الان لاحظوا لو اطلعتوا على ال melting point لهذه
+
+50
+00:04:45,890 --> 00:04:50,190
+المركبات اربعة واربعين تمانية وخمسين تلاتة وستين
+
+51
+00:04:50,190 --> 00:04:55,170
+يعني كلهم ايش solids in principle الان لو انتقلنا
+
+52
+00:04:55,170 --> 00:05:01,440
+علىالـ unsaturated acids اللي فيهم double bonds
+
+53
+00:05:01,440 --> 00:05:06,360
+لاحظوا لو اجينا في عندي double bond واحدة بتبدأ
+
+54
+00:05:06,360 --> 00:05:11,060
+على الموقع تسعة على carbon تسعة بيصير الحامض اسمه
+
+55
+00:05:11,060 --> 00:05:18,380
+oleic acid الأن لو في عندي تنتين double bonds بعد
+
+56
+00:05:18,380 --> 00:05:23,750
+هيك لينوليك أسدلو في عندى تلاتة double bonds
+
+57
+00:05:23,750 --> 00:05:29,910
+لينولينيك لينولينيك لينولينيك لينولينيك لينولينيك
+
+58
+00:05:29,910 --> 00:05:34,630
+واضح هنا double bond واحدة تلتين تلاتة
+
+59
+00:05:36,580 --> 00:05:40,760
+بالنظر إلى ال melting point لهدول المركبات لاحظوا
+
+60
+00:05:40,760 --> 00:05:44,700
+معايا اللي فيه .. اللي فيش فيه double bond يعني
+
+61
+00:05:44,700 --> 00:05:50,460
+هدول كلهم 18 carbon atom 18 .. 18 .. 18 .. و ال
+
+62
+00:05:50,460 --> 00:05:53,640
+stearic 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+63
+00:05:53,640 --> 00:05:55,780
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+64
+00:05:55,780 --> 00:05:58,060
+.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+65
+00:05:58,060 --> 00:06:01,660
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+66
+00:06:01,660 --> 00:06:04,200
+.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+67
+00:06:04,200 --> 00:06:06,040
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+68
+00:06:06,040 --> 00:06:06,200
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+69
+00:06:06,710 --> 00:06:12,510
+إذا خلصنا من السؤال كل ما زاد كلهم تمنتعش الآن
+
+70
+00:06:12,510 --> 00:06:18,390
+لاحظوا معاه هنا مافيش عندي double points بعد هيك
+
+71
+00:06:18,390 --> 00:06:23,590
+كانت ال melting point سبعين بعدك صار عندي one
+
+72
+00:06:23,590 --> 00:06:28,720
+double point نزلتلتلت عشر صار عندى تنتين double
+
+73
+00:06:28,720 --> 00:06:33,340
+points نزلت لناقص خمسة صار عندى تلاتة double
+
+74
+00:06:33,340 --> 00:06:39,320
+points نزلت لأكم لناقص احد عشر اذا بنقدر احنا
+
+75
+00:06:39,320 --> 00:06:45,180
+نستنتج انه كل ما بيزيدوا ال double points او as
+
+76
+00:06:45,180 --> 00:06:49,180
+the unsaturation increases يعني كل ما بيزيد عدم
+
+77
+00:06:49,180 --> 00:06:55,720
+التشبع ال melting point بتصير اقلكل ما بيزيد عدم
+
+78
+00:06:55,720 --> 00:06:59,920
+التشبع كل ما ال melting point لل fatty acid بتصير
+
+79
+00:06:59,920 --> 00:07:05,940
+ايش اقل طبعا هذا الكلام بحاجة الى تفسير ليش ال
+
+80
+00:07:05,940 --> 00:07:09,900
+saturated fatty acids in general اللي هو ال
+
+81
+00:07:09,900 --> 00:07:14,060
+melting point عالية ال unsaturated منخفضة لاحظوا
+
+82
+00:07:14,060 --> 00:07:17,960
+هنا السبعين معناه على حرارة الغرفة تبعتنا احنا
+
+83
+00:07:17,960 --> 00:07:22,740
+معدل حرارة الغرفة خمسة وعشرين تلاتين solidالان
+
+84
+00:07:22,740 --> 00:07:28,960
+التلتعش في الجو تبعنا اليوم هيكون سائل لأن الحرارة
+
+85
+00:07:28,960 --> 00:07:32,580
+خمسة و عشرين عندنا فهو لما بنصار عن التلتعش إن أنا
+
+86
+00:07:32,580 --> 00:07:36,180
+سائل، إن ناقص خمسة أكيد سائل، إن ناقص إحد أش سائل،
+
+87
+00:07:36,180 --> 00:07:40,640
+يعني كأنه بنقدر ناخد معلومة جديدة إن ال
+
+88
+00:07:40,640 --> 00:07:48,350
+unsaturated they are liquidsيعني انسهار أو انخفاض
+
+89
+00:07:48,350 --> 00:07:51,630
+نقطة الانسهار تبعهم تخلهم liquids ال saturated
+
+90
+00:07:51,630 --> 00:07:59,770
+they are solids الاناذي
+
+91
+00:07:59,770 --> 00:08:05,690
+القصة جديرة ان نكون احنا متوقفين عندها خلينا ناخد
+
+92
+00:08:05,690 --> 00:08:10,920
+اذا شوية معلومات تساعدنا نفسر هذا الكلامأول اشي
+
+93
+00:08:10,920 --> 00:08:14,600
+most fatty acids are unbranched يعني ال fatty
+
+94
+00:08:14,600 --> 00:08:19,080
+acids سلاسل غير متفرعة سلسلة طويلة واضحة مافيها
+
+95
+00:08:19,080 --> 00:08:24,690
+branchingand contain an even number of carbon
+
+96
+00:08:24,690 --> 00:08:29,890
+atoms فيهم عدد ال carbon atoms عدد إيش زوجة الان
+
+97
+00:08:29,890 --> 00:08:34,010
+ال unsaturated acids أول ما أبدأ أقول double bond
+
+98
+00:08:34,010 --> 00:08:39,410
+كلمة ال double bond ارتبطت الذهن بcis و trans او z
+
+99
+00:08:39,410 --> 00:08:46,090
+و e اه unsaturated acids usually have the cis or z
+
+100
+00:08:46,090 --> 00:08:50,720
+configurationالـ Unsaturated بيكون ال
+
+101
+00:08:50,720 --> 00:08:56,020
+configuration فيهم إيش زد يعني ال .. ال أتشز بيجوا
+
+102
+00:08:56,020 --> 00:09:01,420
+على جهة و ال carbons على جهة التانية الآن they
+
+103
+00:09:01,420 --> 00:09:03,720
+have lower boiling points than the corresponding
+
+104
+00:09:03,720 --> 00:09:08,260
+saturated ones شوفنا من خلال القيم أن ال
+
+105
+00:09:08,260 --> 00:09:13,860
+unsaturated نقاط الانسهار بتاعتهم أقل من إيش أقل
+
+106
+00:09:13,860 --> 00:09:17,060
+من ال saturated ممتاز
+
+107
+00:09:20,030 --> 00:09:24,490
+الان بنجي للسؤال الأول ليش هدولة solids والتانين
+
+108
+00:09:24,490 --> 00:09:31,420
+liquids اتطلعوا معايا لو اتخيلت انا هذا شكللـ
+
+109
+00:09:31,420 --> 00:09:35,200
+triglycerides يعني هذا الجزء الجليسرين و هذا الاشي
+
+110
+00:09:35,200 --> 00:09:39,720
+الزهري هو ال oxygen و بعد هيك في عندي تلت سلاسل
+
+111
+00:09:39,720 --> 00:09:45,560
+طويلة سلسلة تنتين تلاتة الان هذه السلاسل لما تكون
+
+112
+00:09:45,560 --> 00:09:50,340
+مشبعة لما تكون مشبعة بشكل عام بنتخيلها بهذا الشكل
+
+113
+00:09:50,340 --> 00:09:55,820
+المستقيم الان لاحظوا كيف شكل المركب هو شكل منتظم
+
+114
+00:09:56,070 --> 00:10:01,290
+قالم المركب الشكل تبعه منتظم معناه ذلك ان الجزيئات
+
+115
+00:10:01,290 --> 00:10:05,930
+بتيجي فوق بعضها بشكل جيد تترتب فوق بعضها في الحالة
+
+116
+00:10:05,930 --> 00:10:10,450
+الصلبة وهذا اللي بيخليها تكون ايه اش solids الان
+
+117
+00:10:10,450 --> 00:10:16,410
+لو فقط واحدة من هدولة صار فيها double bond يعني لو
+
+118
+00:10:16,410 --> 00:10:20,790
+كان عندى ال triglycerides مديش اقول التلاتة فيهم
+
+119
+00:10:20,790 --> 00:10:23,670
+double bonds خليني اقول هذه saturated و هذه
+
+120
+00:10:23,670 --> 00:10:28,530
+saturated واحدة بسقولت يكون فيها double bond و ال
+
+121
+00:10:28,530 --> 00:10:31,550
+double bond اللي بده تكون فيها إيش بده تكون sis
+
+122
+00:10:31,550 --> 00:10:35,990
+هتصير بهذا الشكل اتطلع من عندها هاي ال sis اللي
+
+123
+00:10:35,990 --> 00:10:40,750
+موجود فيها هاي ال double bond و هذا الجزء هاي أنا
+
+124
+00:10:40,750 --> 00:10:45,690
+carbon و أنا carbon على نفس الجهة هذا الشكل عمل
+
+125
+00:10:45,690 --> 00:10:53,030
+إيش فيها انتناقةواضح؟ الآن هذا الانفناق حافظ على
+
+126
+00:10:53,030 --> 00:10:58,750
+الشكل المنتظم للجزيء ولا بطل الجزيء منتظم؟ بطل
+
+127
+00:10:58,750 --> 00:11:02,830
+الجزيء منتظم ولذلك لما تيجي الجزيقات بتنحط فوق بعض
+
+128
+00:11:02,830 --> 00:11:07,130
+في solid lattice في الشبكة عشان تكون المركب الصلب
+
+129
+00:11:07,130 --> 00:11:11,450
+مابتبعدش فوق بعض جيدا، مابتكونش متراسة فوق بعض
+
+130
+00:11:11,450 --> 00:11:16,630
+البعض فالمادة بتحول إلى إيش؟ إلى liquid أو بتنخفض
+
+131
+00:11:16,630 --> 00:11:23,240
+نقاط انصحارهاولذلك هنا احنا انا شفنا ال space
+
+132
+00:11:23,240 --> 00:11:26,860
+filling and schematic model of glycerol التسمية
+
+133
+00:11:26,860 --> 00:11:30,380
+بناخدها tri-palmitate هذا من ال palmitic acid يعني
+
+134
+00:11:30,380 --> 00:11:35,380
+كام كربون؟ 16 اللي متذكرين هذا المشبع ايش ماله؟
+
+135
+00:11:35,380 --> 00:11:41,520
+كان regular كان منتظم بينما لاحظوا معي هنا هذا
+
+136
+00:11:41,520 --> 00:11:46,680
+اللي فيه بس واحدغير مشبع، في double bond، راح
+
+137
+00:11:46,680 --> 00:11:50,220
+الانتظام، الآن اتخيلوا انه لو اكثر من واحد في
+
+138
+00:11:50,220 --> 00:11:53,480
+double bonds، اتخيل لو هذا فيه اكثر من double
+
+139
+00:11:53,480 --> 00:11:58,200
+bond، وكل double bond فيهم صار أشبه بإيش؟
+
+140
+00:12:00,430 --> 00:12:05,610
+لأ صار أشبه حقيقة .. صار أشبه حقيقة بالفكرة اللي
+
+141
+00:12:05,610 --> 00:12:11,730
+أخدناها لما درسنا ال ال can's ال chain ال can's و
+
+142
+00:12:11,730 --> 00:12:15,610
+ال branch ال can's و قولنا أن ال chain they have
+
+143
+00:12:15,610 --> 00:12:20,810
+higherboiling point و melting point than ال branch
+
+144
+00:12:20,810 --> 00:12:25,610
+ليش؟ لأن ال branch أصبح شكلهم زي إيش؟ زي الكرة
+
+145
+00:12:25,610 --> 00:12:30,510
+بطلوا منتظمين فوق بعضهم البعض، واضح؟ لما أخدنا
+
+146
+00:12:30,510 --> 00:12:33,510
+قولنا مين، إله ال boiling point أعلى، ال chain ولا
+
+147
+00:12:33,510 --> 00:12:39,770
+ال branch؟لأن ال branch بطل شكله منتظم الفكرة
+
+148
+00:12:39,770 --> 00:12:43,890
+بالانتظام، الآن هذا اللي في double bonds نفس
+
+149
+00:12:43,890 --> 00:12:48,250
+الفكرة زي ال branch، يعني لاحظوا أنه لو كان هنا في
+
+150
+00:12:48,250 --> 00:12:52,990
+branch مش هتعمل هيك وتقضي على الانتظام اللي كان
+
+151
+00:12:52,990 --> 00:12:59,180
+موجود، الآن هذا الكلام اللي عملته double bondفال
+
+152
+00:12:59,180 --> 00:13:03,560
+branching بيقضي على الانتظام ووجود ال cyst double
+
+153
+00:13:03,560 --> 00:13:07,240
+bond بهذا الشكل ايضا قضى على الانتظام فالفكرة
+
+154
+00:13:07,240 --> 00:13:12,780
+العامة في الحالتين لما نقول ان ال kids بشكل عام
+
+155
+00:13:12,780 --> 00:13:16,060
+انه ال branch they have lower boiling points and
+
+156
+00:13:16,060 --> 00:13:20,150
+melting points because they are irregularالان هنا
+
+157
+00:13:20,150 --> 00:13:24,550
+الـ triglycerides that contain unsaturated fatty
+
+158
+00:13:24,550 --> 00:13:27,470
+acids they have lower boiling point and melting
+
+159
+00:13:27,470 --> 00:13:31,990
+point because they are irregular من وين اجت ال
+
+160
+00:13:31,990 --> 00:13:36,330
+irregularity اللي فيهم، عدم الانتظام من وجود ال
+
+161
+00:13:36,330 --> 00:13:39,370
+double bond و ال cis configuration اللي موجود
+
+162
+00:13:39,370 --> 00:13:44,450
+فيها، واضح؟ الان هذا الكلام بيفرق عندي وين؟ بيفرق
+
+163
+00:13:44,450 --> 00:13:49,870
+عندي وين؟ال oil however are liquid بيصير في عندى
+
+164
+00:13:49,870 --> 00:13:56,350
+اشي اسمه بالمطبخ خلينا نقول شغلتين بيصير في عندكم
+
+165
+00:13:56,350 --> 00:14:01,010
+زيت، زيت الجلي، زيت عباد الشمس، زيت الصوية اللي
+
+166
+00:14:01,010 --> 00:14:06,290
+بتسموه searage، هذا liquid و بيصير في عندكم صلب،
+
+167
+00:14:06,290 --> 00:14:11,260
+السمنة والزبدةملاحظين انتوا هدولة ماشي بيفرجوا
+
+168
+00:14:11,260 --> 00:14:17,240
+ببعض، السمنة والزبدة saturated،
+
+169
+00:14:17,240 --> 00:14:21,650
+الزيت اللي فيه ال double bondsالزيت اللي فيه ال
+
+170
+00:14:21,650 --> 00:14:25,130
+double bonds عشان هيك صار liquid, oils however are
+
+171
+00:14:25,130 --> 00:14:32,190
+liquids because they contain lower percentage of
+
+172
+00:14:32,190 --> 00:14:35,230
+unsaturated .. higher percentage عفوا .. higher
+
+173
+00:14:35,230 --> 00:14:38,490
+percentage of unsaturated fatty acids إذا لو
+
+174
+00:14:38,490 --> 00:14:43,310
+بيناقول مين اللي فيه ال double bonds؟ ال oil ولا
+
+175
+00:14:43,310 --> 00:14:48,010
+ال fat؟ السمنة والزبدة بيناقول عنهم fatsالزيت
+
+176
+00:14:48,010 --> 00:14:51,170
+والسيرش .. زيت الزتون والسيرش .. بنقول عنهم إيش؟
+
+177
+00:14:51,170 --> 00:14:54,830
+Oil .. ال oil هو اللي فيه ال double bonds .. و ال
+
+178
+00:14:54,830 --> 00:14:59,150
+double bonds هي اللي خفضت إيش نقطة انسهاره .. الآن
+
+179
+00:14:59,150 --> 00:15:03,050
+لاحظوا معاك ان انتوا اتعلمتوا كيميا .. ان انتوا
+
+180
+00:15:03,050 --> 00:15:08,300
+اتعلمتوا كيميااتعلمتوا ان ال double bond ممكن
+
+181
+00:15:08,300 --> 00:15:14,140
+نعملها ايش؟ hydrogenation نعملها single bond الان
+
+182
+00:15:14,140 --> 00:15:21,060
+لو اعملت لهذا المركب hydrogenation هذا زيت اعملت
+
+183
+00:15:21,060 --> 00:15:25,300
+هدرجة اللي هو شو بيصير؟ بيصير solid بيصير سمنة
+
+184
+00:15:25,300 --> 00:15:30,830
+فالسمنة تنتج من هدرجة الزيوتبس حطوا هنا هيدروجين و
+
+185
+00:15:30,830 --> 00:15:37,190
+هيدروجين، هذا صار saturated فحولت ال oil إلى fat،
+
+186
+00:15:37,190 --> 00:15:42,750
+سر السمنة والزبدة واضح اذا وين؟ بتيجي بالظبط فكرة
+
+187
+00:15:42,750 --> 00:15:49,070
+الهدرجة، الهدرجة بتحول السائل إلى صلب، في ناس
+
+188
+00:15:49,070 --> 00:15:52,030
+بيحبوا الشغلات الصلبة، يتعاملوا معها،
+
+189
+00:15:52,030 --> 00:15:57,540
+hydrogenationواضح؟ اتعلمنا ان ال hydrogenation على
+
+190
+00:15:57,540 --> 00:16:01,060
+ال double bond بيحول ال double bond إلى single
+
+191
+00:16:01,060 --> 00:16:05,620
+bond هاي ال unsaturated صار saturated معناه ذلك ال
+
+192
+00:16:05,620 --> 00:16:11,520
+liquid صار solid لأنه غير المنتظم بسبب ال double
+
+193
+00:16:11,520 --> 00:16:15,840
+bond سيصبح منتظم بعد أن تذهب ال double bond واضحة
+
+194
+00:16:15,840 --> 00:16:16,480
+الفكرة؟
+
+195
+00:16:18,930 --> 00:16:23,230
+ما بنعملش عملية عكسية العملية اللى موجودة ال هدرجة
+
+196
+00:16:23,230 --> 00:16:29,310
+مش العكسي السمنة لما بتكويها تصير سائل فاطوها على
+
+197
+00:16:29,310 --> 00:16:34,810
+النار سايحوها على النار هذا تسخين اسمه بس أنا بحكي
+
+198
+00:16:34,810 --> 00:16:41,230
+على هدرجة واضح؟ الآن هنا بتجيني مشكلة جديدة هنا
+
+199
+00:16:41,230 --> 00:16:46,630
+بتجيني مشكلة جديدة وانتبهوا لها جيدا انتبهوا لها
+
+200
+00:16:46,630 --> 00:16:52,820
+جيدا لأنها مشكلة خطيرةالان زي ما اتفقنا احنا ان
+
+201
+00:16:52,820 --> 00:16:57,480
+الزيوت بشكل عام فيها double bonds وال double bonds
+
+202
+00:16:57,480 --> 00:17:04,580
+ايش ال configuration فيها سيس الان لو يا ترىنتيجة
+
+203
+00:17:04,580 --> 00:17:09,440
+عمل كيميائي أو عمل إنساني أو تسخين زائد السس اتحول
+
+204
+00:17:09,440 --> 00:17:13,460
+ل Trans بالحرارة احنا قلنا بالوضع الطبيعي بتتحولش
+
+205
+00:17:13,460 --> 00:17:17,820
+يعني حرارة الغرفة بدون تفاعلات كيميائية بدون تسخين
+
+206
+00:17:17,820 --> 00:17:24,460
+السس Trans are not interconvertable easyب .. ب ..
+
+207
+00:17:24,460 --> 00:17:28,340
+ب .. ليش؟ لأن الدوران حوالين ال double bond صعب مش
+
+208
+00:17:28,340 --> 00:17:34,080
+سهل لكن بالتسخين أو بعوامل كيميائية ممكن تتم
+
+209
+00:17:34,080 --> 00:17:38,560
+العملية؟ ممكن، بالذات بالتسخين طب وين احنا بنسخن
+
+210
+00:17:38,560 --> 00:17:43,820
+اكتر اشيء؟ لما نجلي بال series الآن جاليا مرة
+
+211
+00:17:43,820 --> 00:17:49,210
+واحدةزي ما بتجلو بيضة مش مشكلة تحطوا زيت زاتون و
+
+212
+00:17:49,210 --> 00:17:53,670
+البيضة دقيقة وقال ماشي لكن الناس اللي بيجلو
+
+213
+00:17:53,670 --> 00:18:00,510
+بالسيرج عشر مرات البطاطا و الفلافل معناه ذلك ان
+
+214
+00:18:00,510 --> 00:18:05,090
+معها التسخين نسبة كبيرة جدا من ال ces ممكن تصير
+
+215
+00:18:05,090 --> 00:18:09,750
+ايش؟ Trans الان ال Trans compounds are
+
+216
+00:18:09,750 --> 00:18:15,660
+carcinogenic ال Trans مصارطنينهم لاحظين و لذلك
+
+217
+00:18:15,660 --> 00:18:22,820
+يحذر من القلي المتكرر في الزيوت يعني مش شطارة انه
+
+218
+00:18:22,820 --> 00:18:27,840
+رابط البيت والله بتجلي مرة مارتين تلاتة عشرة او
+
+219
+00:18:27,840 --> 00:18:32,700
+الناس اللي بيشتغلوا في الشوارع او المطاعم بيجلوا
+
+220
+00:18:32,700 --> 00:18:36,240
+عشر مرات ما هو كل ما احنا جاعدين بنسخن على السيرج
+
+221
+00:18:36,240 --> 00:18:40,520
+و كل ما بنجلي فيه بزيادة كل ما بنحول double bones
+
+222
+00:18:40,520 --> 00:18:46,130
+اكترنتيجة الحرارة من cis إلى trans كل ما بيصير
+
+223
+00:18:46,130 --> 00:18:50,350
+الإنسان طبعا هياخد مع الأشياء المجلية زيوت كمان و
+
+224
+00:18:50,350 --> 00:18:56,550
+هذه الأشياء fatty acids، انتبهوا معي، fatty acids
+
+225
+00:18:56,550 --> 00:19:03,430
+with trans bonds are carcinogenic، مسارتمينو لذلك
+
+226
+00:19:03,430 --> 00:19:08,350
+يعني اكثر من مرة و تانية ما اتجربوش تجلو انما انه
+
+227
+00:19:08,350 --> 00:19:13,910
+الزيت بينجل فيه ايام و ليالي كل هذا الكلام يعتبر
+
+228
+00:19:13,910 --> 00:19:18,430
+كلام إيش خاطر الآن لاحظوا معاك انه برضه عملية
+
+229
+00:19:18,430 --> 00:19:26,120
+الهدرجة برضه عملية الهدرجة عملية كيميائيةبنحول
+
+230
+00:19:26,120 --> 00:19:32,420
+فيها احنا نسبة كبيرة من ال double bonds إلى single
+
+231
+00:19:32,420 --> 00:19:36,140
+bonds يعني جاعدين احنا نحول double bond إلى single
+
+232
+00:19:36,140 --> 00:19:39,800
+bond هذه ال double bond اللي احنا بنحولها sis ولا
+
+233
+00:19:39,800 --> 00:19:44,680
+trans؟ sisالان هذه ال هدرجة لما بنحكي عن زيت مش زي
+
+234
+00:19:44,680 --> 00:19:49,440
+مركب كيميائي يعني مش عملية سهلة عادة ما بتتمش على
+
+235
+00:19:49,440 --> 00:19:53,840
+كل ال double bonds لكن بتعمل نسبة كبيرة منهم واضحة
+
+236
+00:19:53,840 --> 00:19:59,820
+الفكرة؟ الان في هذه الأثناء بعض ال six double
+
+237
+00:19:59,820 --> 00:20:03,000
+bonds بيظلهم six يعني ما بيصلهمش الدور انهم ايش
+
+238
+00:20:03,000 --> 00:20:08,240
+انه يصيرلهم هدرجة وبعض ال six منهم بتتحولوا إلى
+
+239
+00:20:08,240 --> 00:20:16,060
+transوبالتالي بتصير الهدرجة أيضا عاملة مشكلة مش من
+
+240
+00:20:16,060 --> 00:20:20,040
+منطقة ان هي حولت ال double bond إلى single bond
+
+241
+00:20:20,040 --> 00:20:25,580
+يعني لو ان هي بشكل نظيف ودقيق ومتقن حولت ال double
+
+242
+00:20:25,580 --> 00:20:29,320
+bonds إلى single bonds يعني حولت الزيت إلى سمنة
+
+243
+00:20:29,320 --> 00:20:35,410
+مافيش مشكلةلكن المشكلة ان هذه الهدرجة غالبا بتكون
+
+244
+00:20:35,410 --> 00:20:40,410
+غير كاملة لحد معين بيضل شوية SIS BONS ونتيجة
+
+245
+00:20:40,410 --> 00:20:45,750
+التفاعل الكيميائي بعض ال SISBONS بيصيروا Trans
+
+246
+00:20:45,750 --> 00:20:54,780
+واضح؟ ولذلك اليومصار يعني في دول معينة يجبروا
+
+247
+00:20:54,780 --> 00:20:59,920
+الشركات المصنعة انه تعمل فحوصات و انه على نفس
+
+248
+00:20:59,920 --> 00:21:05,920
+الزبدة و على نفس السمنة تكتب جداش نسبة لترانس فيها
+
+249
+00:21:06,870 --> 00:21:10,710
+والمواطن لازم يعرف اقل تقدير انتوا الان كمتعلمين
+
+250
+00:21:10,710 --> 00:21:16,130
+انه كل ما نسبة لل Trans بتزيد كل ما المركب بيكون
+
+251
+00:21:16,130 --> 00:21:22,750
+ايش اخطر كل ما المركب بيكون carcinogenic واضح؟
+
+252
+00:21:22,750 --> 00:21:30,570
+الان بنيجي لكيف يا ترى بنسمي ال triglycerides
+
+253
+00:21:30,570 --> 00:21:37,170
+خلينا ننتبه لشغلةإنهم لـ triglycerides عبارة عن
+
+254
+00:21:37,170 --> 00:21:44,870
+glycerol صح؟ حامل كام fatty acid؟ تلاتة، الآن لـ
+
+255
+00:21:44,870 --> 00:21:49,570
+triglycerides نوعين،
+
+256
+00:21:49,570 --> 00:21:53,790
+ع طول، أي واحدة بتقدر تقولي شو النوعين، انتظر،
+
+257
+00:21:53,790 --> 00:21:59,250
+ممكن يكونوا متماثلين، يعني فيهم نفس ال fatty acid
+
+258
+00:22:00,450 --> 00:22:04,870
+واضح؟ يعني اربعتاش اربعتاش اربعتاش مشبه او ستاش
+
+259
+00:22:04,870 --> 00:22:10,890
+ستاش ستاش مشبه وممكن يكونوا غير متماثلين صارت
+
+260
+00:22:10,890 --> 00:22:13,830
+الأفكار شبيهة بأشياء أخدتها زي لما أخدنا ال ether
+
+261
+00:22:13,830 --> 00:22:18,250
+متماثل وغير متماثل زي ما أخدنا ال anhydride متماثل
+
+262
+00:22:18,250 --> 00:22:22,650
+وغير متماثل كمان ال triglycerides ممكن يكونوا
+
+263
+00:22:23,260 --> 00:22:28,120
+Simple يعني متماثلين أو Mixed Mixed يعني مخلطين
+
+264
+00:22:28,120 --> 00:22:32,680
+يعني يكون هذا 16 هذا 18 هذا 18 فيه double bond
+
+265
+00:22:32,680 --> 00:22:40,160
+واضح؟ الآن أكيد لما بدنا نسمي لو كانوا متماثلين
+
+266
+00:22:40,160 --> 00:22:46,220
+هنذكر اسم الفاتئاسد لمرة واحدة و لو كانوا غير
+
+267
+00:22:46,220 --> 00:22:51,530
+متماثلين بدنا نذكر إيش؟الثلاث أسماء اللي موجودة مش
+
+268
+00:22:51,530 --> 00:22:55,890
+هذه لازم تكون الفكرة العامة الآن بشكل عام ك common
+
+269
+00:22:55,890 --> 00:23:01,070
+name وخلينا نبدأ بال common name للمتماثلين لو كان
+
+270
+00:23:01,070 --> 00:23:07,970
+ال fatty acid ال 12 اللي هو اللوريك أسد تمام بنسمي
+
+271
+00:23:07,970 --> 00:23:10,630
+المركب Trilaurin
+
+272
+00:23:13,300 --> 00:23:19,580
+واضح؟ إذا من ال acid lauryl بحط إيش؟ lauryl tri
+
+273
+00:23:19,580 --> 00:23:27,660
+-lauryl طيب لو كان stearic tri-stearic يعني لاحظوا
+
+274
+00:23:27,660 --> 00:23:35,300
+معي كان ال acid الأصلي lauryl لما عملت منه ال tri
+
+275
+00:23:35,300 --> 00:23:41,860
+-glyceride ضفت كلمة trialهذه إجت جديدة اللورك
+
+276
+00:23:41,860 --> 00:23:50,100
+خلّيت منها لور و حطيت لها إيش؟ حطيت لها in بدل اك
+
+277
+00:23:50,100 --> 00:23:58,260
+in ال try لورن طيب من ال steerك المتماثل try
+
+278
+00:23:58,260 --> 00:24:06,150
+steering من الأوليك المتماثل try أولينواضح؟
+
+279
+00:24:06,150 --> 00:24:10,870
+ترايقليا ولاحظوا على طول طبعا هيبين معاكم كيف
+
+280
+00:24:10,870 --> 00:24:14,890
+لتراي لاورين مثلا ال melting point له لأن كل ال
+
+281
+00:24:14,890 --> 00:24:20,510
+fatty acids تبعته مشبعة خمسة واربعين هذا
+
+282
+00:24:20,510 --> 00:24:27,490
+لترايستيرين واحد وسبعين الان لو سألت واحدة منكم لو
+
+283
+00:24:27,490 --> 00:24:31,650
+سألت واحدة منكم ليش لتراي لاورين خمسة واربعين و
+
+284
+00:24:31,650 --> 00:24:37,120
+لترايستيرين واحد وسبعينالسلسلة أطول، الموليكولا
+
+285
+00:24:37,120 --> 00:24:41,400
+رويت، الكلمتين صح، التنين مشبع، مشبع، بطل، التشبع
+
+286
+00:24:41,400 --> 00:24:47,300
+هو الفارق، فقط طول السلسلة، أه، لكن لما هنا أجيت
+
+287
+00:24:47,300 --> 00:24:53,430
+18 و 18و حطيت تلاتة double bonds يعني خصام ست
+
+288
+00:24:53,430 --> 00:24:56,410
+هيدروجينات مش المشكلة بفرق ال molecular weight
+
+289
+00:24:56,410 --> 00:25:00,290
+يعني ست وحدات في جزاء كبير زي هذا في ال molecular
+
+290
+00:25:00,290 --> 00:25:04,550
+weight ماسهمهم مش فرق لكن المشكلة حقيقة لما أنا
+
+291
+00:25:04,550 --> 00:25:11,450
+بنزل هذا 18 و هذا 18 قليل ال 18 في one double bond
+
+292
+00:25:11,450 --> 00:25:16,970
+لما بنزل من 71 ل 4 هذا مش فاتقش التغير في ال
+
+293
+00:25:16,970 --> 00:25:21,280
+molecular weightهذا نتيجة وجود ال double bonds،
+
+294
+00:25:21,280 --> 00:25:24,300
+ليش؟ لأن وجدت لو بدي أجي هنا، بدي أعمل هذه ال
+
+295
+00:25:24,300 --> 00:25:26,840
+double bonds زي هيك و زي هيك، بعدين هذه زي هيك و
+
+296
+00:25:26,840 --> 00:25:34,010
+زي هيك، بعدين هذه، صار إيش؟ زي الكرةالجزيق وجده
+
+297
+00:25:34,010 --> 00:25:39,090
+بده يصير زي كرة كيف بده يكون منتظم في solid state
+
+298
+00:25:39,090 --> 00:25:44,550
+واضح الفكرة فلما بده أقول ليش ال triolين لو بده
+
+299
+00:25:44,550 --> 00:25:49,710
+أجي أسألكم ال triolين have lower melting point
+
+300
+00:25:49,710 --> 00:25:54,770
+than tristerine because of the presence of the
+
+301
+00:25:54,770 --> 00:26:00,230
+double bonds or because it is unsaturated واضح
+
+302
+00:26:00,230 --> 00:26:05,250
+الفكرةو هذا وجود ال double bond أو ال unsaturation
+
+303
+00:26:05,250 --> 00:26:09,790
+خلّاه regular ولا irregular؟ irregular بطل منتظم
+
+304
+00:26:09,790 --> 00:26:14,070
+بطل زي .. زي حجار الطوب المنتظمة كيف بتصفق بعض
+
+305
+00:26:14,070 --> 00:26:18,870
+بشكل قوى بينما حجار مش منتظمة بتضل إيش؟ توجع أو
+
+306
+00:26:18,870 --> 00:26:26,600
+ألعاب الأطفال اللي بيسموها ال Legoالان موضوع
+
+307
+00:26:26,600 --> 00:26:30,780
+الهيدروجينيشن of vegetable oils حكينا قولنا ان
+
+308
+00:26:30,780 --> 00:26:36,420
+احنا ممكن ناخد ال oil ويصير زبدة او سمنة
+
+309
+00:26:36,420 --> 00:26:40,120
+بالهيدروجينيشن تحويل ال double bond الى single
+
+310
+00:26:40,120 --> 00:26:42,780
+bond هذا الكلام برفع ال melting point بيحول ال
+
+311
+00:26:42,780 --> 00:26:47,380
+liquid الى solid الهيدروجينيشن عادة بتنفي وجود
+
+312
+00:26:47,380 --> 00:26:52,360
+الهيدروجين و نكلكتاليست و heat لكن هناك خطورة
+
+313
+00:26:52,360 --> 00:26:54,420
+مصاحبة للهيدروجينيشن
+
+314
+00:26:56,690 --> 00:27:02,110
+تحويل بعض ال sis bonds إلى trans يعني التحويل من
+
+315
+00:27:02,110 --> 00:27:05,630
+sis إلى saturated أو من double bond إلى saturated
+
+316
+00:27:05,630 --> 00:27:10,750
+هذا مافيش فيه مشكلة لكن كتفاعل جانبي بعض ال sis
+
+317
+00:27:10,750 --> 00:27:15,450
+بصير trans هنا توجد المشكلة
+
+318
+00:27:16,590 --> 00:27:21,350
+الان مرة تانية نرجع لل simple and mixed
+
+319
+00:27:21,350 --> 00:27:25,210
+triglycerides اللي هي المتماثلة و غير المتماثلة
+
+320
+00:27:25,210 --> 00:27:32,490
+اتفقنا احنا ان المتماثل بنعطي اسم common name
+
+321
+00:27:32,490 --> 00:27:38,470
+trystyrian يعني هذا 18 اذا ايش الحامض تبعه؟ Styric
+
+322
+00:27:38,470 --> 00:27:44,190
+Styric Styric فالمركب trystyrian طيب لو كنا بنسمي
+
+323
+00:27:44,190 --> 00:27:51,210
+ايوبكيعني Triglycerides is a common name و أنا
+
+324
+00:27:51,210 --> 00:27:55,470
+مرات بجيبلكوا سؤال في الامتحان .. بجيبلكوا سؤال في
+
+325
+00:27:55,470 --> 00:28:00,810
+الامتحان ال Triglycerides is also called .. or the
+
+326
+00:28:00,810 --> 00:28:06,830
+Ayurvedic name of Triglycerides is .. الآن عشان
+
+327
+00:28:06,830 --> 00:28:11,650
+نجاوبه صح احنا قولنا ال Triglycerides they are
+
+328
+00:28:11,650 --> 00:28:18,550
+Easter'sEaster صح ولا لأ؟ كيف أنا كنت أسمي ال
+
+329
+00:28:18,550 --> 00:28:22,970
+Easter؟ خليني أتذكر كيف أنا كنت أسمي ال Easter،
+
+330
+00:28:22,970 --> 00:28:29,370
+هيني بدي أكتب Easter عشان واحدة تذكرني كيف،
+
+331
+00:28:29,370 --> 00:28:32,690
+هاي Easter، شايفينه اللي على اللوح؟ واحدة تسميه
+
+332
+00:28:32,690 --> 00:28:37,370
+جزء الكحول في الأول
+
+333
+00:28:40,150 --> 00:28:49,150
+مثل هاي جزء الكحول وبعدين جزء الحامض انتوا بتكونوا
+
+334
+00:28:49,150 --> 00:28:52,910
+شايفوني ومن جلة دراستكوا بنزويك أسد ال Easter
+
+335
+00:28:52,910 --> 00:28:58,130
+بنتهي بنزويت مثل بنزويت أسيتات بيوتانويت اه هذا
+
+336
+00:28:58,130 --> 00:29:04,970
+مثل ايش؟ بنزويت اذا تسمية ال Easterلعبوا لو أنكوا
+
+337
+00:29:04,970 --> 00:29:09,030
+بتحاولوا تحفظوا الكيميا كرموز بتتغلبوا لو أنكوا
+
+338
+00:29:09,030 --> 00:29:13,310
+حفظتوا الكيميا أنه تسمية ال Easter مجموعة الكحول
+
+339
+00:29:13,310 --> 00:29:18,690
+في الأول بعدين ال acid منتهي ب إيه؟ إثل أستيت مثل
+
+340
+00:29:18,690 --> 00:29:24,730
+بنزويت فين ال بيوتانويت صح ولا لأ؟ طيب الآن كويس
+
+341
+00:29:24,730 --> 00:29:31,770
+لو إجيت على هذا شو هو جزء الكحول فيه؟ ال glycerin
+
+342
+00:29:32,770 --> 00:29:38,250
+وشو الأحمض؟ الاستيرك أسد مش هذا الحامض و هذا
+
+343
+00:29:38,250 --> 00:29:44,590
+الكحول ولا لأ ايش اول اشي بنذكره؟ جزء الكحول
+
+344
+00:29:44,590 --> 00:29:53,350
+إجليسارين إجليساريل و الاستيرك أسدStraight لكن لأن
+
+345
+00:29:53,350 --> 00:29:58,330
+في عندي منه تلاتة بقول glycerol ال try straight
+
+346
+00:29:58,330 --> 00:30:03,290
+إذا أنا نفس المنطقة ده اسمها ال Easter الكحول في
+
+347
+00:30:03,290 --> 00:30:09,070
+الأول و بعدين النهاية eight و حطيت try لأن عندي كم
+
+348
+00:30:09,070 --> 00:30:16,160
+حامض تلاتةإذا هذا هي جزء الكحول اللي فيه في واحدة
+
+349
+00:30:16,160 --> 00:30:19,140
+منكم مالخومة كتير عشان الكحول مرسوم على اليمين مش
+
+350
+00:30:19,140 --> 00:30:22,660
+على الشمال المهم نذكر الكحول في الأول كيف نرسمه مش
+
+351
+00:30:22,660 --> 00:30:28,360
+مشكلة واضحة الفكرة ولا لأ؟ واضحات؟ يعني هذا لو كنت
+
+352
+00:30:28,360 --> 00:30:35,540
+راسمه بالعكس إيش برضه هسميه؟ واضح؟ شايف هي كناس
+
+353
+00:30:35,540 --> 00:30:40,360
+مرات بهمش بيغرجوا بشبهر ميه؟
+
+354
+00:30:43,590 --> 00:30:46,990
+يعني اتعودتوا انتوا انه هذا نعمله زي هيك او يبدو
+
+355
+00:30:46,990 --> 00:30:53,130
+معكوس لان لما يرسم زي هيك وين جزء الكحول مثل وين
+
+356
+00:30:53,130 --> 00:30:57,250
+جزء الاسد مثل بنزويت مثل بنزويت خلاص يعني الفكرة
+
+357
+00:30:57,250 --> 00:31:01,950
+مش انه بدهم يبينوا هدولة معكوسين دائما لأ لأ مش
+
+358
+00:31:01,950 --> 00:31:06,890
+هذه الفكرة حسب طريقة الرسم يذكر جزء الكحول اولا ثم
+
+359
+00:31:06,890 --> 00:31:10,770
+جزء الحامض منتهي بالنهاية ايه ولذلك هذا هيك ايش
+
+360
+00:31:10,770 --> 00:31:14,780
+بدنا نسميهمثل؟ بنزوية
+
+361
+00:31:18,100 --> 00:31:22,640
+أكيد اكيد طبعا اه ليش مايجيكيش ارسمي نفسي كل هذان
+
+362
+00:31:22,640 --> 00:31:27,800
+الكربونات بترسم ترسم شو وراكم انتوا دافعين رسوم
+
+363
+00:31:27,800 --> 00:31:32,760
+بتكونوا بتتعلموا واضح تسمية ال easter تسمية ال
+
+364
+00:31:32,760 --> 00:31:37,840
+easter ببساطة انه تذكروا جزء الكحول بعدين جزء
+
+365
+00:31:37,840 --> 00:31:42,400
+الحامض المساهي بالنهاية ايش ات فهذا صار glycerol
+
+366
+00:31:42,400 --> 00:31:50,100
+tryStirate هذه فهمناها طيب لو كانوا الأحماض الآن
+
+367
+00:31:50,100 --> 00:31:56,200
+مختلفين يعني صار عنده اللي أنا بسميه إيش mixed
+
+368
+00:31:56,200 --> 00:32:02,760
+triglyceride مرة تانية هحط في الأول جزء الكحول إذا
+
+369
+00:32:02,760 --> 00:32:09,450
+هنا هذا الجزء الكحول هي الجزء اللي جاي من الكحولمش
+
+370
+00:32:09,450 --> 00:32:16,310
+بختلف عليه، الآن الأحماض بدي أذكرهم مرتبين، واحد،
+
+371
+00:32:16,310 --> 00:32:20,950
+اتنين، تلاتة، طبعا هتقولولي إذا عرفنا واحد، بعده
+
+372
+00:32:20,950 --> 00:32:24,270
+بنقول اتنين، تلاتة، يمكن تصير المشكلة عندكم أن هذا
+
+373
+00:32:24,270 --> 00:32:28,730
+واحد، بعدين اتنين، تلاتة، ولا هذا واحد، بعدين
+
+374
+00:32:28,730 --> 00:32:33,800
+اتنين، تلاتةواضح؟ يعني المشكلة أن أذكر واحد، بعد
+
+375
+00:32:33,800 --> 00:32:38,020
+ما أذكر واحد لازم أمشي فيهم إيش، امرتبين، الآن
+
+376
+00:32:38,020 --> 00:32:44,760
+ببساطة بنقول الأصغر والأكثر تشبعا هو اللي بنحطه
+
+377
+00:32:44,760 --> 00:32:49,940
+نمرة واحد يعني لما أنا بدأ أختار وين نمرة واحد،
+
+378
+00:32:49,940 --> 00:32:54,960
+بدأ أختار الأصغر منهم والأكثر تشبعايعني لو لجيت
+
+379
+00:32:54,960 --> 00:32:58,980
+هنا ستة عشر وهنا تمانت عشر مشبعين التنين مين بدي
+
+380
+00:32:58,980 --> 00:33:05,540
+أحطهم؟ ستة عشر الان لو لجيت هنا ستة عشر وهنا تمانت
+
+381
+00:33:05,540 --> 00:33:11,280
+عشر وكمان هذا مشبع الستة عشر الآن بعد ما أحط الستة
+
+382
+00:33:11,280 --> 00:33:16,280
+عشر مامشي فيهم بالترتيب واضح؟ ولذلك هدولة لو انا
+
+383
+00:33:16,280 --> 00:33:22,470
+اجيت اطلعت الستة عشر بال methic acidالـ 18 المشبع
+
+384
+00:33:22,470 --> 00:33:27,790
+استيرك الـ 18 اللي فيه double bond أوليك لما أنا
+
+385
+00:33:27,790 --> 00:33:32,150
+بدي أسميهم بقول glycerin بعدين بجعل بالميتو
+
+386
+00:33:32,150 --> 00:33:38,510
+بالميتو بعدين الاستيرك استيره بعدين على الأوليك
+
+387
+00:33:38,510 --> 00:33:45,490
+أولييت بحط ات في النهاية لاحظوا معي أن الأوليك أن
+
+388
+00:33:45,490 --> 00:33:46,390
+الأوليك
+
+389
+00:33:50,390 --> 00:33:58,870
+الـ O تبعته عليها إيش؟ نجوطين طبعا على الكمبيوتر
+
+390
+00:33:58,870 --> 00:34:03,230
+ممكن تلاقوا الـ O اللي عليها نجوطين و ممكن أنه
+
+391
+00:34:03,230 --> 00:34:06,430
+ماتلاقوهاش، الآن لو مالاجيتوهاش الـ O اللي عليها
+
+392
+00:34:06,430 --> 00:34:08,870
+نجوطين اكتبوها إيش؟
+
+393
+00:34:10,720 --> 00:34:17,820
+والفظوها OE فهي O ممالة إلى الكسر يعني بمنطق
+
+394
+00:34:17,820 --> 00:34:24,480
+التجويد هي O ممالة للكسر و ال A اللي عليها نقطين A
+
+395
+00:34:24,480 --> 00:34:30,400
+ممالة للكسر و ال U اللي عليها نقطين ممالة للكسر
+
+396
+00:34:30,400 --> 00:34:38,300
+كمان ولذلك لما الألمان بيقرؤوا هذه الكلمة أول أول
+
+397
+00:34:39,500 --> 00:34:44,840
+لحظوا الفك كيف بنزل لتحت إمالة للكسر مار عليكم
+
+398
+00:34:44,840 --> 00:34:49,320
+الإمالات ولا لأ؟
+
+399
+00:34:49,320 --> 00:34:55,740
+ولا في عندنا ولا إمالة في القرآن الكريم برواية حفظ
+
+400
+00:34:55,740 --> 00:35:02,450
+عن عاصرهي إمالة واحدة لكن روحوا على روايات تانية
+
+401
+00:35:02,450 --> 00:35:08,870
+زي مثلا الكساء وغير وغيرات كله إمالات واضح؟ أه في
+
+402
+00:35:08,870 --> 00:35:14,550
+القرآن الكريم وقال اركبوا فيها بسم الله مجريها ما
+
+403
+00:35:14,550 --> 00:35:19,490
+تقولوش مجريها هادفرة كسر كامل هي ألف ممالة للكسر
+
+404
+00:35:19,490 --> 00:35:26,690
+بسم الله مجريها ومرساها طبعاعند غير حفظة عن عاصم
+
+405
+00:35:26,690 --> 00:35:32,110
+معظم بيقرأوا باسم الله مجراها بيرجعوها مجراها و
+
+406
+00:35:32,110 --> 00:35:36,530
+مرساها بيحطوهم زي ما .. فهذه قول هذه قوليك قوليك
+
+407
+00:35:36,530 --> 00:35:44,270
+الفك يكون ميل للكسر او تقرأوها ايش اوأو نقرأها OE
+
+408
+00:35:44,270 --> 00:35:50,130
+إذا سهلة تسمية بدي أحط glycerin وإذا كانوا زي بعض
+
+409
+00:35:50,130 --> 00:35:55,330
+بحط ال tri و الحمض eight وإذا كانوا مش زي بعض بدي
+
+410
+00:35:55,330 --> 00:35:58,770
+أذكر التلاتة هقول مين بدي أبدأ واحد و بعدين اتنين
+
+411
+00:35:58,770 --> 00:36:04,210
+تلاتة الواحد هو الأصغر و الأكتر تشبعانيعني لو
+
+412
+00:36:04,210 --> 00:36:07,990
+إجينا اتطلعنا على هذا المثال نتطلع فيه عندنا
+
+413
+00:36:07,990 --> 00:36:13,210
+هاناستيرك أسد وهانا بالميتك أسد وهانا أوليك أسد
+
+414
+00:36:13,210 --> 00:36:17,630
+الآن أنا بأتطلع على الأطراف أنا مقارنتني من أين
+
+415
+00:36:17,630 --> 00:36:21,350
+بدي أبدأ من هذا الطرف و لا من هذا الطرف واضحة
+
+416
+00:36:21,350 --> 00:36:28,690
+الفكرة؟ الآن اتطلعوا من هذا الطرف أوليك 18 غير
+
+417
+00:36:28,690 --> 00:36:34,880
+مشبعاستيرك تمانتعش مشبع تمانتعش و تمانتعش مشبع و
+
+418
+00:36:34,880 --> 00:36:41,320
+غير مشبع من وين بدي أبدأ تمانتعش مشبع تمانتعش مشبع
+
+419
+00:36:41,320 --> 00:36:49,500
+و لذلك هذا المركب لما أنا بدي أسميه إجليساريل
+
+420
+00:36:49,500 --> 00:36:53,720
+بعدين بسيب فراغ مشبولنا في ال Easter بنسيب فراغ زي
+
+421
+00:36:53,720 --> 00:36:59,640
+إتل فراغ أستيتل إجليساريل فراغ استيرو بالميتو
+
+422
+00:37:02,340 --> 00:37:10,300
+واضح؟ الار اتخيلوا لو اجاكم سؤال اجليساريل بالميتو
+
+423
+00:37:10,300 --> 00:37:15,340
+استيروا قليل واجليساريل استيروا بالميتو قليل يعني
+
+424
+00:37:15,340 --> 00:37:20,300
+عكس التانين فيهم حطيت فيهم التلاتة هذا بيبدأ
+
+425
+00:37:20,300 --> 00:37:24,440
+بالميتو بعدين استيره بعدين قليل هذا بيبدأ استيره
+
+426
+00:37:24,440 --> 00:37:30,300
+بعدين بالميتو قليل هدول اش بيكون العلاقة بينهم؟We
+
+427
+00:37:30,300 --> 00:37:37,280
+are surely isomers فش نقاش إنهم isomers الآن أي
+
+428
+00:37:37,280 --> 00:37:41,840
+نوع من ال isomers؟
+
+429
+00:37:41,840 --> 00:37:47,960
+الآن اطلعوا معي هايهم، تلاتة، واحدة تشوفهم ك ..
+
+430
+00:37:47,960 --> 00:37:50,820
+برا الكيميا، برا الكيميا مش هاي ال glycerol وهيو
+
+431
+00:37:50,820 --> 00:37:55,860
+حاملهم التلاتة، حاملهم التلاتة أزرق، أحمر، يعني
+
+432
+00:37:55,860 --> 00:38:01,600
+يجربوا بيصيروا زي أعلام فلسطينأزرق، أحمر، أصمر،
+
+433
+00:38:01,600 --> 00:38:11,200
+أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق،
+
+434
+00:38:11,200 --> 00:38:11,220
+أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر،
+
+435
+00:38:11,220 --> 00:38:11,240
+أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر،
+
+436
+00:38:11,240 --> 00:38:11,720
+أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق،
+
+437
+00:38:11,720 --> 00:38:13,520
+أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر،
+
+438
+00:38:13,520 --> 00:38:16,920
+أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر،
+
+439
+00:38:16,920 --> 00:38:22,200
+أحمرمواقع الارتباط اتغيرت، هذا كان شابق في أول
+
+440
+00:38:22,200 --> 00:38:25,980
+كاربون الأزرق والأحمر في التانية، الأحمر صار في
+
+441
+00:38:25,980 --> 00:38:30,540
+الأولى والأزرق في التانية، different bonding، بزن
+
+442
+00:38:30,540 --> 00:38:35,820
+different bonding، اذا structural isomers،
+
+443
+00:38:35,820 --> 00:38:40,040
+different bonding تبعها كمان شغلة، different names
+
+444
+00:38:41,090 --> 00:38:44,950
+واضح؟ عشان ايك، لاحظوا واحد كان اسمه glycerol
+
+445
+00:38:44,950 --> 00:38:48,350
+بالميتو ستيرو أوليات، التاني glycerol ستيرو
+
+446
+00:38:48,350 --> 00:38:51,150
+بالميتو أوليات، الآن هذول أخدوا different names
+
+447
+00:38:51,150 --> 00:38:54,230
+ولا لأ؟ طالما different names، إذا they are
+
+448
+00:38:54,230 --> 00:38:59,470
+structural isomers، ال stereo isomers كانوا ياخدوا
+
+449
+00:38:59,470 --> 00:39:05,780
+نفس الاسميفرقوا بس في البادقة في الانانشو مارز R
+
+450
+00:39:05,780 --> 00:39:11,680
+ولا S ولا كذا وفي الدياستيريو مارز S أو Trans أو Z
+
+451
+00:39:11,680 --> 00:39:16,340
+أو E same name وكانوا ياخدوا different descriptive
+
+452
+00:39:16,340 --> 00:39:20,680
+البادقة اللي بتوصف الشكل الفراغي مش سميناها
+
+453
+00:39:20,680 --> 00:39:25,520
+descriptive البادقة ال R أو ال S أو ال Z أو ال E
+
+454
+00:39:25,520 --> 00:39:30,460
+أو ال S أو ال Trans لكن إلهم نفس الاش نفس الإسم
+
+455
+00:39:31,530 --> 00:39:35,470
+الان لاحظوا معاه لو قلنا لكم draw this structure
+
+456
+00:39:35,470 --> 00:39:41,210
+for glyceryl trimeristate اللي هو meristic acid ال
+
+457
+00:39:41,210 --> 00:39:48,210
+14 موجود عندكم بدكوا تحطوهربما من الأخطاء اللي
+
+458
+00:39:48,210 --> 00:39:50,450
+كتير الطلاب بيخطئوها
+
+459
+00:40:19,820 --> 00:40:23,880
+تطلعوا كيف الشكل الصحيح ال O هان هذا جزء الكحول
+
+460
+00:40:23,880 --> 00:40:29,400
+هذا جزء الحامض ال glycerin هو المتصل بال O العادية
+
+461
+00:40:29,400 --> 00:40:33,400
+single bond بعدين ال C double bond O مش العكس هذا
+
+462
+00:40:33,400 --> 00:40:36,340
+من الأخطاء الشائعة لما نقول للطلبة ارسمولنا
+
+463
+00:40:36,340 --> 00:40:41,640
+triglyceride بيروحوا بيرسموليا معكوس واضح؟
+
+464
+00:40:44,360 --> 00:40:49,780
+على أي حال، بهيك تقريبا بننهي اليوم بكرا إجازة عيد
+
+465
+00:40:49,780 --> 00:40:54,740
+العمال، ماعرفش وقتاش بيكون عيد الطلاب، عيدنا يوم
+
+466
+00:40:54,740 --> 00:40:57,280
+نجاحنا
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..fb6d6837eba461ceaaca22b71b32343165a6d781
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/6-G8b-zOS0Y_raw.srt
@@ -0,0 +1,1884 @@
+1
+00:00:19,520 --> 00:00:23,540
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:23,540 --> 00:00:28,820
+موضوع ال acidity و عرفنا بالظبط ايش معنى الأحمار و
+
+3
+00:00:28,820 --> 00:00:35,360
+وضحنا انه مهم جدا نعرف ايش معنى ال BKAال acidity
+
+4
+00:00:35,360 --> 00:00:39,820
+constant و قولنا كل ما ال PKA قلة كل ما الحامض
+
+5
+00:00:39,820 --> 00:00:45,000
+بيكون ايش اقوى بعد هي طرحنا سؤال و أعطينا عليه
+
+6
+00:00:45,000 --> 00:00:49,940
+إجابة عامة بدون ما ندخل بأنفلة تفصيلية كان السؤال
+
+7
+00:00:49,940 --> 00:00:54,540
+لما بدأ قارن حامض مع حامض تاني من الأقوى و من
+
+8
+00:00:54,540 --> 00:00:59,250
+الأقل بدأ اعتمد على ايشلما بقارن الأحماض في قوتها
+
+9
+00:00:59,250 --> 00:01:05,270
+بدي أنظر لل أيون السالب اللي بتكون نتيجة اللي هو
+
+10
+00:01:05,270 --> 00:01:10,430
+تحلل الحمض بالماء هذا ال أيون السالب بدي الشحنة
+
+11
+00:01:10,430 --> 00:01:14,110
+تبعته تكون أقل ما يمكن هذا اللي بنسميه إيش احنا ال
+
+12
+00:01:14,110 --> 00:01:18,470
+stability ل ال negative أيون معنى ال stability أن
+
+13
+00:01:18,470 --> 00:01:21,710
+الشحنة تكون أقل ما يمكن الآن إيش اللي بيقلل
+
+14
+00:01:21,710 --> 00:01:27,060
+الشحنة؟تلات تأثيرات ممكن الحجم اللي بيحمل الشحنة
+
+15
+00:01:27,060 --> 00:01:30,920
+وممكن شيء نسميه ال inductive effect اللي هو تأثير
+
+16
+00:01:30,920 --> 00:01:36,180
+المساعدة وممكن شيء نسميه ال resonance effect
+
+17
+00:01:36,180 --> 00:01:42,660
+أعطينا بعض الأمثلة لكن خلينا نأكد الآن مثلا لو
+
+18
+00:01:42,660 --> 00:01:48,420
+أجينا نقارن ال phenolsمع الالكوهولز العادية
+
+19
+00:01:48,420 --> 00:01:54,480
+الاليفاتك الالكوهولز بمعنى انا بدي اقارن ROH مع
+
+20
+00:01:54,480 --> 00:01:59,320
+فنل OH لاحظوا المقطة الأولى انه لما ايجي يعمل
+
+21
+00:01:59,320 --> 00:02:04,680
+المقارنة ويفهم المقارنة سابه هو من الحامض ايش كتب؟
+
+22
+00:02:04,680 --> 00:02:10,760
+الايون السالد يعني كتب أنا R O minus وفنل O minus
+
+23
+00:02:10,760 --> 00:02:17,990
+فالحكم هوالـ Ion السالب الان هذا الـ RO- الشحن
+
+24
+00:02:17,990 --> 00:02:22,450
+اللي موجود عليه ثابت على ال oxygen مافيش فيها حركة
+
+25
+00:02:22,450 --> 00:02:25,970
+مافيش فيها resonance ال oxygen ذرة صغيرة يعني
+
+26
+00:02:25,970 --> 00:02:29,710
+بيقول it cannot carry the negative charge صعب
+
+27
+00:02:29,710 --> 00:02:33,250
+عليها تحمل ال negative charge ولذلك ال Ion كله
+
+28
+00:02:33,250 --> 00:02:37,050
+بيكون unstable فلاحظوا الكلام ان ال charge is
+
+29
+00:02:37,050 --> 00:02:43,570
+localized يعني محمولة على موقع واحد مش عملهاتتنجل
+
+30
+00:02:43,570 --> 00:02:48,730
+localized متموضعة محمولة في موضع واحد عكسها ايش؟
+
+31
+00:02:48,730 --> 00:02:53,410
+delocalized فبصير عندي كلمتين localized اشي على
+
+32
+00:02:53,410 --> 00:02:57,550
+موضع واحد delocalized زي ما انا اجي احمل هذا هيك
+
+33
+00:02:57,550 --> 00:03:01,550
+بس عن ايد هذه و فقط لا غير هيك بيكون هذا الحمل
+
+34
+00:03:01,550 --> 00:03:07,590
+localized الآن لو كنت بنجلهبيكون De-localized واضح
+
+35
+00:03:07,590 --> 00:03:13,210
+فإذا بنلاحظ أنه بالفينول الشحنة السالبة في أحد ال
+
+36
+00:03:13,210 --> 00:03:16,350
+resonance structures على ال oxygen لكن لو عملنا
+
+37
+00:03:16,350 --> 00:03:20,450
+حركة إلكترونات زوج من الإلكترونات بهذا الشكل و
+
+38
+00:03:20,450 --> 00:03:23,710
+حركنا ال bond هنلاحظ أنها ممكن تصير على ال carbon
+
+39
+00:03:23,710 --> 00:03:26,510
+اللي موجودة هنا بحركة تانية على ال carbon اللي
+
+40
+00:03:26,510 --> 00:03:29,750
+موجودة هنا بحركة تالتة على ال carbon لاحظوا أنه
+
+41
+00:03:29,750 --> 00:03:34,460
+بطلت الشحنةمحمولة على مكان واحد بطلت localized
+
+42
+00:03:34,460 --> 00:03:39,000
+صارت delocalized هذا resonance واضح او
+
+43
+00:03:39,000 --> 00:03:42,400
+delocalization يعني بيستعملوا كلمة resonance او
+
+44
+00:03:42,400 --> 00:03:46,900
+delocalization بنفس المعنى واضح ف because of the
+
+45
+00:03:46,900 --> 00:03:52,360
+delocalization of the charge in phenoxide and ion
+
+46
+00:03:52,360 --> 00:03:56,540
+or anion لحظوا ال phenyl O minus شو بنسميه
+
+47
+00:03:58,860 --> 00:04:02,960
+فينوكسايد انا يعني يمكن سابقا حكينالكم هي اللي لو
+
+48
+00:04:02,960 --> 00:04:09,300
+كانت هذه مثل O minus مثوكسايد مثل O minus إثوكسايد
+
+49
+00:04:09,300 --> 00:04:16,880
+HO minusHydroxide هيدروكسايد هيدروكسايد
+
+50
+00:04:16,880 --> 00:04:17,360
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+51
+00:04:17,360 --> 00:04:20,000
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+52
+00:04:20,000 --> 00:04:20,660
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+53
+00:04:20,660 --> 00:04:22,780
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+54
+00:04:22,780 --> 00:04:27,020
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+55
+00:04:27,020 --> 00:04:30,260
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+56
+00:04:30,260 --> 00:04:37,420
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+57
+00:04:37,420 --> 00:04:43,720
+هيدروكسايد هيدروحوالي ست عشر، خمس عشر و نص و خمس
+
+58
+00:04:43,720 --> 00:04:47,340
+عشر و تسعة فلما نيجي نسأل ليش ال phenols are more
+
+59
+00:04:47,340 --> 00:04:51,140
+acidic than alcohols الجواب because of resonance
+
+60
+00:04:51,140 --> 00:04:56,460
+or because of delocalization of its chargeطبعا لو
+
+61
+00:04:56,460 --> 00:05:02,800
+صار عندى Nitrophenol ال delocalization بزيد يعني
+
+62
+00:05:02,800 --> 00:05:07,600
+الشحنة السالبة بالاضافة لإنها ممكن تنوجد على مواضع
+
+63
+00:05:07,600 --> 00:05:12,500
+كثيرة كمان بصير بإمكانها تنوجد على ذرات ال oxygen
+
+64
+00:05:12,500 --> 00:05:15,260
+بتاعون ال Nitro فبصير
+
+65
+00:05:17,450 --> 00:05:22,290
+الـ Delocalization للـ negative charge ايش ماله
+
+66
+00:05:22,290 --> 00:05:27,270
+اكتر بيصير عندي more delocalization يعني الشحنة
+
+67
+00:05:27,270 --> 00:05:31,350
+موزعة زي حمل بيحملوا اتنين اتريحوا شوية طب لو
+
+68
+00:05:31,350 --> 00:05:36,630
+حملوا تلاتة افضل لو حملوا اربعة أسهل واضح الفكرة
+
+69
+00:05:36,630 --> 00:05:42,650
+فبالنيتروفينول عندي more delocalization ولذلك نزل
+
+70
+00:05:42,650 --> 00:05:48,190
+النيتروفينول لقداشلسبعة و اتنين من عشرة ال BKA اذا
+
+71
+00:05:48,190 --> 00:05:52,510
+which is more acidic ال Nitrophenol is more acidic
+
+72
+00:05:52,510 --> 00:05:57,290
+لانه فيه more resonance طب لو صارت Trinitrophenol
+
+73
+00:05:57,290 --> 00:06:02,970
+more and more فهيصل ل point two five وبناء على ذلك
+
+74
+00:06:02,970 --> 00:06:08,670
+سمنا ايش احنا بكريك اسد ل Trinitrophenolهذه كلها
+
+75
+00:06:08,670 --> 00:06:12,850
+أمثلة على الـ Resonance Effect الآن لو كنت بدي
+
+76
+00:06:12,850 --> 00:06:17,290
+أمثلة على ال Inductive Effect لو بدأت بالإيثانول
+
+77
+00:06:17,290 --> 00:06:24,150
+فيه تلت مجموعات هيدروجين CH2OH CH3 طيب لو حطيت
+
+78
+00:06:24,150 --> 00:06:28,830
+واحدة من الهيدروجين زي كلور بتبدأ هذه الكلور تسحب
+
+79
+00:06:28,830 --> 00:06:30,210
+جزء من الشحنة
+
+80
+00:06:32,900 --> 00:06:36,200
+افترضوا ان كلهم فيهم شحنة سالبة قللت الشحنة
+
+81
+00:06:36,200 --> 00:06:41,580
+السالبة هذا ال effect سحب الشحنة with drawing of
+
+82
+00:06:41,580 --> 00:06:47,930
+the chargeأو إعطاء شحنة إيش بنسميه إحنا Inductive
+
+83
+00:06:47,930 --> 00:06:51,050
+Effect فال Inductive Effect هو سحب الشحنة أو
+
+84
+00:06:51,050 --> 00:06:55,470
+إعطائها مش نقلها لأ الشحنة موجودة هنا لكن افترض
+
+85
+00:06:55,470 --> 00:07:00,090
+الشحنة هنا عشر وحدات سحبنا منها واحدتين ال CL اللي
+
+86
+00:07:00,090 --> 00:07:05,050
+أنا بتحب السالب سحبت واحدتين جديش صفية بدل عشرة
+
+87
+00:07:05,050 --> 00:07:11,820
+تمانية واضح؟ الآن لو حطيت انتين CLصار عندى more
+
+88
+00:07:11,820 --> 00:07:17,220
+and more with the drawing لو حطيت تلاتة CL كلهم
+
+89
+00:07:17,220 --> 00:07:22,160
+بيسحبوا الشحنة السالبة بناء على ذلك ال effect هنا
+
+90
+00:07:22,160 --> 00:07:25,480
+لما انا بقول ان ال trichloroethanol is more acidic
+
+91
+00:07:25,480 --> 00:07:28,240
+than dichloroethanol than chloroethanol than
+
+92
+00:07:28,240 --> 00:07:32,340
+ethanol هذا ايش اللي بنسميه احنا inductive effect
+
+93
+00:07:32,340 --> 00:07:39,750
+واضح؟لمّا قررنا الـ RSH و الـ ROH مين اللي قلنا
+
+94
+00:07:39,750 --> 00:07:45,010
+فيهم أقوى كأسس؟ RSH طب الآن بنقول الـ RSH أقوى من
+
+95
+00:07:45,010 --> 00:07:51,310
+الـ ROH، why؟ because of the size، إذن هاي نعرفه
+
+96
+00:07:51,310 --> 00:08:00,410
+طيب، لو بدأجي أقول الـ ARSH مع الـ ROH، مين أقوى؟
+
+97
+00:08:02,130 --> 00:08:06,990
+because of the size لحظوا ال AR هنا و ال AR هنا
+
+98
+00:08:06,990 --> 00:08:11,890
+فيهم resonance فبطل ال resonance هو السبب يعني ال
+
+99
+00:08:11,890 --> 00:08:16,150
+aromatic او البنزينة هنا و البنزينة هنا فينول و
+
+100
+00:08:16,150 --> 00:08:22,040
+ثيوفينول ال AR عامل مشتركاللي بيعمل resonance بناء
+
+101
+00:08:22,040 --> 00:08:25,900
+على ذلك لو حد .. لو بدنا نجيب سؤال arsh is more
+
+102
+00:08:25,900 --> 00:08:30,240
+acidic than aroh due to resonance غلط لأنه هنا فيه
+
+103
+00:08:30,240 --> 00:08:33,680
+resonance و هنا فيه resonance طب هاش المختلف
+
+104
+00:08:33,680 --> 00:08:41,950
+sulfur و oxygen اذا because of the sizeلكن لو اجيت
+
+105
+00:08:41,950 --> 00:08:49,470
+قلتلكم بدأ اقارن ARSH و RSH، لاحظوا ال sulphur،
+
+106
+00:08:49,470 --> 00:08:53,990
+sulphur the same size، اذا وين صار الفرق؟ AR ولا
+
+107
+00:08:53,990 --> 00:09:00,310
+R؟ اذا why؟ because of resonance
+
+108
+00:09:04,470 --> 00:09:11,150
+لو كنت بدأ اقارن A R O H مع R O H ال O و ال O نفس
+
+109
+00:09:11,150 --> 00:09:16,870
+ال size اللي اتغير R و A R إذا مين أعلى؟ A R
+
+110
+00:09:16,870 --> 00:09:23,650
+because of resonance بضحك الفكرة لما بنعمل مقارنة
+
+111
+00:09:23,650 --> 00:09:29,630
+الآن لو إجيت على هدولة كلهم و قولت بدأ أسطب كل
+
+112
+00:09:29,630 --> 00:09:37,500
+الكلاموبلغة عربية بسيطة جدا بدي أقول من الأقوى ومن
+
+113
+00:09:37,500 --> 00:09:44,240
+الأضعف في الأربعة ال A R S H هو أقوى حاجة ال A R S
+
+114
+00:09:44,240 --> 00:09:51,560
+H هو الأقوى the strongest وال R O H هو الأضعف
+
+115
+00:09:54,370 --> 00:10:00,150
+يعني لو بقارن ال alcohols و ال thyols و ال phenols
+
+116
+00:10:00,150 --> 00:10:04,330
+و ال thyophenols أقوى واحد فيهم ال thyophenol و
+
+117
+00:10:04,330 --> 00:10:08,710
+أضعف واحد فيهم بالحمضية اللي هو إيش ال alcohol هذا
+
+118
+00:10:08,710 --> 00:10:14,970
+الكلام بينعكس على التفاعلات الكيميائيةهذا الكلام
+
+119
+00:10:14,970 --> 00:10:19,170
+الآن ان هذا الأضعف بنعكس على التفاعلات الكيميائية
+
+120
+00:10:19,170 --> 00:10:22,990
+وين بنعكس على التفاعلات الكيميائية مش احنا قاعدين
+
+121
+00:10:22,990 --> 00:10:28,010
+نقول هدولة أحماط مظبوط ولا لأ طول عمرنا بنعرف
+
+122
+00:10:28,010 --> 00:10:35,170
+الجملة الشهيرة حمض زاد قاعدة ملح زاد ماء بناء على
+
+123
+00:10:35,170 --> 00:10:40,570
+ذلك لو اجيت أفاعل هدولة مثلا مع قاعدة قوية زي ال N
+
+124
+00:10:40,570 --> 00:10:53,890
+A O Hزائد NaOH كلهم مش هم زائد قاعدة اه هلاحظ ان
+
+125
+00:10:53,890 --> 00:10:57,670
+تلاتة منهم بتفاعل وبيعطوا ملح زائد ماء واحد
+
+126
+00:10:57,670 --> 00:11:05,990
+مابتفعلش الا مابتفعلش هذا هذا بتفعل هذا بتفعل هذا
+
+127
+00:11:05,990 --> 00:11:11,040
+بتفعلواضح؟ طبعا لو قولنا لكم اكتبوا المعادلة،
+
+128
+00:11:11,040 --> 00:11:17,080
+عندنا مثال، لو أخدنا هذا ال R O H زي N A O H، إيش
+
+129
+00:11:17,080 --> 00:11:24,600
+كتبنا؟ No reaction لكن لو قولنا R S H زي N A O H،
+
+130
+00:11:24,600 --> 00:11:29,770
+ال H مع ال O H، إيش بيعملوا؟ ميّهطول عمره و ال RS
+
+131
+00:11:29,770 --> 00:11:36,350
+minus مع ال NA NA plus RS minus و بنفس الطريقة
+
+132
+00:11:36,350 --> 00:11:45,830
+بإمكانكم تكتبوا إيش كل الأشياء RSH
+
+133
+00:11:45,830 --> 00:11:46,050
+مع
+
+134
+00:11:57,410 --> 00:12:03,230
+فاهم الان دائما اذا وجد عندك مش سؤال مش سؤالك هذا
+
+135
+00:12:03,230 --> 00:12:08,170
+ال specific مش سؤالك هذا ال specific لأ اذا اي
+
+136
+00:12:08,170 --> 00:12:15,110
+شغلة حطيت فيها متغيرين معناه ذلك مش هيكون عندك ثقة
+
+137
+00:12:15,110 --> 00:12:20,110
+كاملة انك بتقدر تاخد الجواب مباشرة الا من التجربة
+
+138
+00:12:20,110 --> 00:12:27,210
+و من قيمة اش بتطلع التجربة ال BKAإذا صار عندك
+
+139
+00:12:27,210 --> 00:12:31,910
+متغيرين سؤالك انا بعتبره جيد انه انت غيرتي هنا ال
+
+140
+00:12:31,910 --> 00:12:37,970
+ar و r و هنا ال o و ال s و سألت مين الأقوى فيهم
+
+141
+00:12:37,970 --> 00:12:44,250
+كام متغير عندك اتنين الحل انك تبحثي تعمل التجربة و
+
+142
+00:12:44,250 --> 00:12:48,550
+تشوف ال bk ايه لهذا و ال bk لهذا و تعمل المقارنة
+
+143
+00:12:48,550 --> 00:12:54,180
+ولذلك في العلم دائما لما بتعملوا المقارنةبتثبتوا
+
+144
+00:12:54,180 --> 00:12:59,600
+جميع المتغيرات ما عدا متغير واحد بيصير بإمكانكوا
+
+145
+00:12:59,600 --> 00:13:03,420
+تعملوله مقارنة و تعملوله قوانين يمكن هذا الكلام
+
+146
+00:13:03,420 --> 00:13:08,780
+أكثر شيء مر عليكم في منطقة الغازات ليش؟ لأن
+
+147
+00:13:08,780 --> 00:13:13,500
+الغازات لها أكتر من متغير الضغط والحجم وعدد
+
+148
+00:13:13,500 --> 00:13:19,790
+المولات ودرجة الحرارةأربع متغيرات في الغازات واضح؟
+
+149
+00:13:19,790 --> 00:13:23,810
+الآن الغازات في النهاية كانت بتنجمع بمعادلة B في V
+
+150
+00:13:23,810 --> 00:13:28,570
+بساوي N في R في T pressure في volume بساوي number
+
+151
+00:13:28,570 --> 00:13:32,610
+of moles في R تابع الغازات في ال temperature الآن
+
+152
+00:13:32,610 --> 00:13:36,770
+لما كنت قادش أقول بدي أقارن ال volume مع ال
+
+153
+00:13:36,770 --> 00:13:43,210
+temperature كنت أحط لنفس الكمية من الغاز عندنفس
+
+154
+00:13:43,210 --> 00:13:49,550
+الضغط واضح بعد ذلك تصبح المقارنة أصعب تعمل تجربة
+
+155
+00:13:49,550 --> 00:13:55,930
+الان هنا ال O و O مشتركات ال R و AR مختلفات سهل
+
+156
+00:13:55,930 --> 00:14:01,650
+علي أعطي جواب واضح الفكرة؟ لكن هنا ال S أفضل من ال
+
+157
+00:14:01,650 --> 00:14:07,940
+O و ال AR أفضل من ال Rإيش النتيجة؟ التجربة
+
+158
+00:14:07,940 --> 00:14:14,040
+المجموعة التجربة واضح؟ يعني مافيش عندك جواب هذي
+
+159
+00:14:14,040 --> 00:14:16,880
+أفضل من هذي و هذي أفضل من هذي طب هذي أفضل من هذي
+
+160
+00:14:16,880 --> 00:14:20,440
+بقدش و هذي أفضل من هذي بقدش عشان يطلع عندي جواب؟
+
+161
+00:14:20,440 --> 00:14:29,160
+لأ بدك تعمل التجربة واضح؟ سؤال جيد الآن لاحظوا معي
+
+162
+00:14:29,160 --> 00:14:32,340
+هل يا ترى الكيميائي
+
+163
+00:14:33,600 --> 00:14:38,120
+بيستسلم؟ لأ، يعني سبحان الله زي ما بتقول آية كريمة
+
+164
+00:14:38,120 --> 00:14:44,820
+وفوق كل ذي علم عليم واضح؟ يعني احنا قولنا الكحول
+
+165
+00:14:44,820 --> 00:14:52,580
+هذا زائد N A O H لا يتفاعل طب ال N A O H كان تصنيف
+
+166
+00:14:52,580 --> 00:15:00,380
+strong baseقاعدة قوية الان ال N A O H is a strong
+
+167
+00:15:00,380 --> 00:15:05,360
+base مركب ايوني و قاعدة قوية طب حبيل غصب عنه
+
+168
+00:15:05,360 --> 00:15:11,000
+الكحول الفاعله ايش بنعمله بنجيبله very strong base
+
+169
+00:15:11,000 --> 00:15:16,460
+يعني بنجيبله قاعدة تكون اقوى من ال N A O H موجود
+
+170
+00:15:16,460 --> 00:15:20,860
+يعني بدل ما اجي افعله مع ال N A O H اللي strong
+
+171
+00:15:20,860 --> 00:15:26,490
+base ممكن افعله مع N A Hهذا المركب اسمه Sodium
+
+172
+00:15:26,490 --> 00:15:33,110
+Hydride الجزء القاعد فيه ايون H- الهيدرايد H-
+
+173
+00:15:33,110 --> 00:15:40,510
+واضح؟ ايش بنسمي هذا Sodium Hydride لاحظوا ال I
+
+174
+00:15:40,510 --> 00:15:47,390
+نهاية ايون سالف يعني هذا NA plus H- ويمكن كلكم
+
+175
+00:15:47,390 --> 00:15:54,470
+بتعرفوا او سبق مر عليكم ان ال H لهاتلت حلق ال H
+
+176
+00:15:54,470 --> 00:15:58,910
+ممكن تتخيلوها بتلت حلق ال H لحالها اللي فيها
+
+177
+00:15:58,910 --> 00:16:04,010
+إلكترون و ال H اللي فقدت الإلكترون و ال H لو
+
+178
+00:16:04,010 --> 00:16:09,010
+اكتسبت كمان إلكترون يعني ذرة الهيدروجين هي الذرة
+
+179
+00:16:09,010 --> 00:16:12,430
+اللي فيها إلكترون و بروتون فهذا ال H اللي فيها
+
+180
+00:16:12,430 --> 00:16:17,810
+إلكترون و بروتون هيدروجين أتم الآن لو فقدت
+
+181
+00:16:18,700 --> 00:16:25,900
+الإلكترون شو بنسميها بروتون بروتون ما انتوا تخيلوا
+
+182
+00:16:25,900 --> 00:16:31,020
+الذرة اتخيلوها بالذرة مش عندى نواة موجبة في كل
+
+183
+00:16:31,020 --> 00:16:38,060
+الأحوال و هالنواة الموجبة حواليهاالألكترون صارت
+
+184
+00:16:38,060 --> 00:16:41,660
+هيدروجين أتم الهيدروجين أتم نوال موجبة حوالها
+
+185
+00:16:41,660 --> 00:16:47,140
+إلكترون طيب لو صارت هيك وشيلنا الإلكترون شو الصفة
+
+186
+00:16:47,140 --> 00:16:55,280
+عندي النوال موجبة بس لبروتون واضح؟ الآن لو اكتسبت
+
+187
+00:16:55,280 --> 00:17:00,620
+كمان إلكترون تاني بتصير هيدرايد أنيون فهذه
+
+188
+00:17:00,620 --> 00:17:09,330
+هيدروجين أتمهذا البروتون وهذا الهيدرايد أنيون ال H
+
+189
+00:17:09,330 --> 00:17:14,810
+minus هيدرايد أنيون كتبنا هناك هيدرايد هذا دايما
+
+190
+00:17:14,810 --> 00:17:20,320
+البروتون اش بنسمي احنا او ال H plusبروتون ال H بلس
+
+191
+00:17:20,320 --> 00:17:25,400
+بروتون ولذلك الأحماض لما بنوصفها مثلا بنقول ال
+
+192
+00:17:25,400 --> 00:17:31,020
+HNO3 بنقول عنه في بروتون واحد monobrotic acid ال
+
+193
+00:17:31,020 --> 00:17:38,640
+H2SO4 بنقول dibrotic acid ال H3BO4 بنقول عنه
+
+194
+00:17:38,640 --> 00:17:43,100
+tribrotic acid واضح؟ اللي جابنا عن هالكلام كلمة
+
+195
+00:17:43,100 --> 00:17:51,800
+إيش؟السوديوم هايدرايد هو مصدر
+
+196
+00:17:51,800 --> 00:17:57,080
+قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى
+
+197
+00:17:57,080 --> 00:17:57,100
+قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى
+
+198
+00:17:57,100 --> 00:18:01,200
+قوى قوى قوى قوى قوى قوى قوى
+
+199
+00:18:02,990 --> 00:18:06,750
+اللي هو لو كنا بناخده مع الاثانول مثلا Sodium
+
+200
+00:18:06,750 --> 00:18:11,870
+Ethoxide كذلك الحال لو فعلنا مع ال metal نفسه NA
+
+201
+00:18:11,870 --> 00:18:19,010
+Sodium Metal Sodium Metal كmetal لوحده أقوى كقاعدة
+
+202
+00:18:19,010 --> 00:18:24,350
+من ال NAOH يعني بإمكانه يتفاعل ال ROH مع ال NA
+
+203
+00:18:24,350 --> 00:18:29,290
+ويعطينا RO minus في الحالتين ال بيكتمل التفاعل انه
+
+204
+00:18:29,290 --> 00:18:35,630
+بيطلع غاز هيدروجينفصحيح ان ال R O H بتفعلش مع ال N
+
+205
+00:18:35,630 --> 00:18:40,290
+A O H ولكنه يتفاعل مع ال sodium hydrate او ال
+
+206
+00:18:40,290 --> 00:18:46,090
+sodium metal وبيعطينا ال R O minus N A plus واضح
+
+207
+00:18:46,090 --> 00:18:54,450
+هذه الفكرة لان هذه تعتبر كقواعد اقوى من ال N A O H
+
+208
+00:18:56,180 --> 00:19:01,080
+بهيك بيكفي في موضوع ال acidity لو اجينا على ال
+
+209
+00:19:01,080 --> 00:19:07,040
+preparation of alcohol الحقيقة هتلاحظ انه بشكل عام
+
+210
+00:19:07,040 --> 00:19:14,260
+ال preparation of alcohol مر معنا طب وين مر معنا؟
+
+211
+00:19:14,260 --> 00:19:21,040
+في مكانين المكان الأول لما كنا ناخد double bond و
+
+212
+00:19:21,040 --> 00:19:24,440
+نعمل عليها addition of water in presence of acid
+
+213
+00:19:25,200 --> 00:19:31,800
+إيش كانت الضيف؟ H و OH إذا إنها تيش كحول، واضح؟
+
+214
+00:19:31,800 --> 00:19:37,680
+فإضافة الماء للالكينز هذه الطريقة ولذلك الإثانول
+
+215
+00:19:37,680 --> 00:19:42,800
+مثلا بنحضره بإضافة الماء للإثيلين
+
+216
+00:19:44,070 --> 00:19:48,550
+طبعا إله شغل عملي و ال yield جليل لكن بيعيدوا
+
+217
+00:19:48,550 --> 00:19:51,810
+التفاعل أكتر من مرة لحد ما يمشوا التفاعل يعني
+
+218
+00:19:51,810 --> 00:19:57,110
+الفكرة العلمية أنه بتفاعل و بيضيف واضح صناعيا أكيد
+
+219
+00:19:57,110 --> 00:20:01,690
+إله أجهزة أو إله متابعة صناعية كذلك الحال اللي
+
+220
+00:20:01,690 --> 00:20:06,230
+بتذكر ال alkenes و إضافة الميه لازم يظلوا متذكر
+
+221
+00:20:06,230 --> 00:20:06,710
+إيش
+
+222
+00:20:09,640 --> 00:20:12,940
+Markovnikov وAntimarkovnikov addition يعني انا لما
+
+223
+00:20:12,940 --> 00:20:18,520
+كنت على البروبين اضيف الماء في وجود H بلس وين كنت
+
+224
+00:20:18,520 --> 00:20:23,700
+احط الهيدروجين هان ال O-H هان اطلع البروبان to all
+
+225
+00:20:23,700 --> 00:20:27,780
+او to probanol او ايزو برو بالالكول ماكانش يطلع
+
+226
+00:20:27,780 --> 00:20:34,200
+هذا طب لو بدنا هذا شو كنا نعمل Antimarkovnikov
+
+227
+00:20:36,400 --> 00:20:40,420
+كنا نستعمل طريقة ال boron ال bh3 و توابعها
+
+228
+00:20:40,420 --> 00:20:46,540
+بترجعوها واضح؟ إذا الكحولات يمكن أن تحضر و أخدنا
+
+229
+00:20:46,540 --> 00:20:51,000
+هذا الكلام بالتفصيل من خلال إضافة الماء على ال
+
+230
+00:20:51,000 --> 00:20:56,860
+alkyls برضه طريقة تانية أخدناها لتحضير الكحولات
+
+231
+00:20:56,860 --> 00:20:59,440
+مين اتذكرنا فيها؟
+
+232
+00:21:04,290 --> 00:21:10,270
+الـ RX زائد الماء أو الـ OH ماينوس مش كنا ناخد هذه
+
+233
+00:21:10,270 --> 00:21:18,110
+المعادلة RX زائد H2O in general R OH لنيوكليوفيليك
+
+234
+00:21:18,110 --> 00:21:23,710
+سبستيوشن على ال الكلهيلايت شبتر ستة سواء كنا نفعله
+
+235
+00:21:23,710 --> 00:21:27,940
+مع نيوترال نيوكليوفايل او معit charged the
+
+236
+00:21:27,940 --> 00:21:32,680
+nucleophile واضح ال substitution إذا الطرق العامة
+
+237
+00:21:32,680 --> 00:21:38,340
+لتحضير الكحولات يا إما من ال RX بالإبدال يا إما من
+
+238
+00:21:38,340 --> 00:21:45,840
+ال alkenes بتفاعل إيش بنسميه الإضافة ما هو مع
+
+239
+00:21:45,840 --> 00:21:53,100
+الميه تفاعل إضافة addition reaction واضح الآن لو
+
+240
+00:21:53,100 --> 00:22:00,470
+إجينا بعد هيك على تفاعلاتالكحولات تفاعلات الكحولات
+
+241
+00:22:00,470 --> 00:22:05,210
+طبعا في زميلة لكم بس عشان يعني ما نغمطهاش حقها ان
+
+242
+00:22:05,210 --> 00:22:10,530
+هي منتبهة جالت من ال evoxides كلامها سليم يعني لما
+
+243
+00:22:10,530 --> 00:22:14,950
+كان يكون عندكم الالكين و اضيف عليه ال oxygen أعمل
+
+244
+00:22:14,950 --> 00:22:22,050
+منه evoxide و بعد هيك لو عملنا ring opening
+
+245
+00:22:22,050 --> 00:22:28,320
+باستعمال ال nucleophile كنا نقول CCOH و يجي
+
+246
+00:22:28,320 --> 00:22:32,640
+لنكليوفايل this is an alcohol كلامها سليم ماكنش
+
+247
+00:22:32,640 --> 00:22:39,500
+فيه غلط واضح لكن منطلقوا ايش الالكين برضه منطلقنا
+
+248
+00:22:39,500 --> 00:22:43,860
+الالكين اعملنا ابوكسايد و عملنا ring opening هذا
+
+249
+00:22:43,860 --> 00:22:48,780
+الكلام ماكن ان شاء الله الان لو اجينا على موضوع ال
+
+250
+00:22:48,780 --> 00:22:56,650
+reactions of alcoholsمن تفاعلات ال alcohols تفاعل
+
+251
+00:22:56,650 --> 00:23:01,390
+ال dehydration معنى ال dehydration او acidic
+
+252
+00:23:01,390 --> 00:23:08,500
+dehydration نزع الماء في وجود الحامضنزع الماء في
+
+253
+00:23:08,500 --> 00:23:12,660
+وجود الحامض هذا ايش اسمه dehydration حدف الماء في
+
+254
+00:23:12,660 --> 00:23:17,280
+وجود الحامض الآن بدنا ننتبه هنا لنقطة انه احنا
+
+255
+00:23:17,280 --> 00:23:22,940
+ممكن نعمل هذا التفاعل بطريقتين تؤدي الى ناتجين
+
+256
+00:23:22,940 --> 00:23:28,280
+مختلفين ممكن من نفس الكحول يعني لو أخدنا الاثانول
+
+257
+00:23:28,280 --> 00:23:31,240
+كمثال ننزع من هنا OH
+
+258
+00:23:34,460 --> 00:23:40,300
+OH من carbon مجاورة هنا رفعنا ايش؟ مية لما بنشيل
+
+259
+00:23:40,300 --> 00:23:48,100
+OH مع اتش شو ممكن نعمل؟ الالكين الحد في عكس ايش؟
+
+260
+00:23:48,100 --> 00:23:53,400
+الاضافة اضافة الماء على الالكين بتاعة الالكول حد
+
+261
+00:23:53,400 --> 00:23:58,520
+في ال ..إضافة الماء على الالكين تعطي الالكول وحذف
+
+262
+00:23:58,520 --> 00:24:03,620
+الماء من الالكول ممكن يعطي الالكين هذا أحد النواتج
+
+263
+00:24:03,620 --> 00:24:09,120
+الناتج التاني انه يتفاعلوا جزيئين من الالكول مع
+
+264
+00:24:09,120 --> 00:24:15,040
+بعضواضح؟ يعملول ال ether يعني هذا ال ethanol مع
+
+265
+00:24:15,040 --> 00:24:19,740
+ethanol تاني CH3CH2OH
+
+266
+00:24:19,740 --> 00:24:24,020
+يعني طبعا من و ال ethanol التاني ما انا حاطط ال
+
+267
+00:24:24,020 --> 00:24:29,380
+ethanol ملايين الجزيئات فجزيئ بتفاعل ايش؟ مع جزيئ
+
+268
+00:24:29,380 --> 00:24:35,200
+لاحظوا لما يعمل ال ether CH3CH2OCH2CH3
+
+269
+00:24:35,200 --> 00:24:41,990
+ايش حُدف من هدول الجزيئين؟مية O H من واحد O H من
+
+270
+00:24:41,990 --> 00:24:46,490
+واحد يعني كأنه بالظبط اللي بده يصير هنا أن هذه ال
+
+271
+00:24:46,490 --> 00:24:51,630
+O بدها تهاجم هنا على الكربون وتترد ال O H الآن و
+
+272
+00:24:51,630 --> 00:24:53,230
+هذه ال O شو هتخسر؟
+
+273
+00:24:57,940 --> 00:25:01,920
+هي لما هذه هاجمت من خلال الـ Oxygen كان يوكليوفايل
+
+274
+00:25:01,920 --> 00:25:06,880
+طردت الـ OH والنيوترال يوكليوفايل دايما بيخسر ايش؟
+
+275
+00:25:06,880 --> 00:25:11,740
+H اتفقنا على هذا الكلام هذه خسرت الـ H والـ OH ايش
+
+276
+00:25:11,740 --> 00:25:19,280
+عملوه؟ H2O يعني هنا زائد H2O وهنا زائد H2O لكن هنا
+
+277
+00:25:19,280 --> 00:25:23,780
+ما حُدفت من جزء واحد اعطت الالكين لو حُدفت من
+
+278
+00:25:23,780 --> 00:25:31,820
+التفاعل بين جزيين بتعطي ايش؟الـ Ether الـ ROR هو
+
+279
+00:25:31,820 --> 00:25:36,780
+الـ Ether طبعاً بيصير السؤال يا ترى أي التفاعلات
+
+280
+00:25:36,780 --> 00:25:42,640
+بيمشي بيعتمد على عدة عوامل من أهمها درجة الحرارة
+
+281
+00:25:42,640 --> 00:25:47,580
+زائد العوامل الحفازة اللي بيستعملوها للتفاعل خلينا
+
+282
+00:25:47,580 --> 00:25:51,260
+نكون مركزين على درجة الحرارة لو هذا التفاعل عملناه
+
+283
+00:25:51,260 --> 00:25:56,280
+عند 140 درجة مئوية هيعطينا بشكل أساس الـ Etherو لو
+
+284
+00:25:56,280 --> 00:26:00,740
+عملناها عند 180 درجة مئوية هيعطينا بشكل أساسي
+
+285
+00:26:00,740 --> 00:26:06,220
+الالكيد لكن بقولكوا أن التفاعل صناعيا له شغلات
+
+286
+00:26:06,220 --> 00:26:11,300
+تانية و بيستعمله catalyst معينة اللي مع الحرارة
+
+287
+00:26:11,300 --> 00:26:16,960
+تفضل هذا أو هذا يعني بعض العوامل الحفازة مع حرارة
+
+288
+00:26:16,960 --> 00:26:21,760
+أعلى من 180 ع 250 ممكن تخلي التفاعل يعطي بس ال
+
+289
+00:26:21,760 --> 00:26:27,030
+الكيد و بعض العوامل الحفازةعلى مية و اربعين، مية و
+
+290
+00:26:27,030 --> 00:26:34,050
+خمسين، ممكن تخليه يعطي بس إيش؟الإيثر الآن بدناش
+
+291
+00:26:34,050 --> 00:26:37,510
+ندخل في التفصيل الممل احنا بنقول انه تسخين
+
+292
+00:26:37,510 --> 00:26:42,030
+الاثانول في وجود الحامض 140 هيعطيني ال ether و 180
+
+293
+00:26:42,030 --> 00:26:47,950
+هيعطيني ال alkene و القمر لما يصير في الصناعة اكيد
+
+294
+00:26:47,950 --> 00:26:52,310
+اللي بيشتغلوا فيه يعني عندهم انتباه لأشياء إضافية
+
+295
+00:26:52,310 --> 00:26:56,290
+و لعوامل حفازة اللي يتحكموا ايش الناتج اللي بيطلع
+
+296
+00:26:56,290 --> 00:26:56,670
+عندهم
+
+297
+00:26:59,310 --> 00:27:04,610
+الان لو أخدنا مثال تاني لو أخدنا ال tertiary butyl
+
+298
+00:27:04,610 --> 00:27:08,770
+alcohol عارفينه ال tertiary butyl alcohol اللي هو
+
+299
+00:27:08,770 --> 00:27:12,470
+ال carbon اللي حامله تلت مجموعات مثل يعني لو رسمته
+
+300
+00:27:12,470 --> 00:27:22,330
+انا OH CH3 CH3 CH3 و سخناه في وجود حامض بالتأكيد
+
+301
+00:27:22,330 --> 00:27:31,490
+هيفقدالـ OH و هيفقد معها H من كاربون مجاورة الآن
+
+302
+00:27:31,490 --> 00:27:35,770
+التلت ذرات اللي هنا متكافئات ولا لأ؟ والتسع
+
+303
+00:27:35,770 --> 00:27:39,150
+هيدروجينات متكافئات عشان ايه؟ لو بدأ أقولكوا هذا
+
+304
+00:27:39,150 --> 00:27:42,990
+الحذف أو هذا ال dehydrationيعني جيكوا اك سؤال
+
+305
+00:27:42,990 --> 00:27:46,930
+dehydration of tertiary-butanol او tertiary-butyl
+
+306
+00:27:46,930 --> 00:27:51,770
+alcohol produces how many products؟ one يعني لو
+
+307
+00:27:51,770 --> 00:27:55,970
+شال H من هان زي هان زي هان بدون ما ندخل في
+
+308
+00:27:55,970 --> 00:27:59,250
+الميكانيزم لو رسمتوا double bond هان او رسمتوها
+
+309
+00:27:59,250 --> 00:28:03,230
+هان او رسمتوها هان هو ايش؟ نفس المركب هنا مثلا
+
+310
+00:28:03,230 --> 00:28:09,230
+رسمنا الـOH هذه مع H من هدولة هي الناتج ايش اسمه؟
+
+311
+00:28:09,230 --> 00:28:15,840
+ISOبيوتين مار عليكم ايزو بيوتين او لو بتكوينها بال
+
+312
+00:28:15,840 --> 00:28:22,300
+ايوبك one two three وعنمرة اتنين حامل ايش مثل اذا
+
+313
+00:28:22,300 --> 00:28:27,660
+two مثل بروبين two مثل بروبين هو نفس ال ايزو
+
+314
+00:28:27,660 --> 00:28:32,300
+بيوتين الان لاحظوا معايا ان انتوا صارت عندكم
+
+315
+00:28:32,300 --> 00:28:39,490
+الفكرة انه بتحذف OHو Hydrogen مجاورة لحسن الحظ في
+
+316
+00:28:39,490 --> 00:28:43,830
+ال tertiary butanol التلاتة زي بعض طلع بيطلع عندى
+
+317
+00:28:43,830 --> 00:28:49,330
+كام ناتج طب لو التلاتة مختلفات هيعطينى كام ناتج
+
+318
+00:28:49,330 --> 00:28:55,080
+اعملتوا مثال شبيه جدا بس لما كنتوا تحلفوا ايشمش ال
+
+319
+00:28:55,080 --> 00:29:01,400
+H O H ال H C L و سلمتوه homeware الحد في الميه زي
+
+320
+00:29:01,400 --> 00:29:06,420
+حد في ال H C L طب حد في ال H C L متذاكرين قاعدة
+
+321
+00:29:06,420 --> 00:29:14,280
+أخدتوها عشان اتقولكوا أي نواتج أفضل ال more
+
+322
+00:29:14,280 --> 00:29:18,740
+substituted زي سفرول ولذلك لو مثلا أخدتوا ال two
+
+323
+00:29:18,740 --> 00:29:25,870
+butanol أكيد بدنا نحدفالـ OH لكن يا تراب نحذف H من
+
+324
+00:29:25,870 --> 00:29:32,670
+هنا و لا H من هنا إذا حذفنا هذه ال H بنطلع هذا و
+
+325
+00:29:32,670 --> 00:29:36,350
+إذا حذفنا هذه ال H بنطلع هذا which is more
+
+326
+00:29:36,350 --> 00:29:41,780
+substitutedفي حد في ال alkalites زيها تماما ال
+
+327
+00:29:41,780 --> 00:29:45,020
+alcohols هذا more substituted بيكون ال major
+
+328
+00:29:45,020 --> 00:29:50,780
+product ال less substituted ال minor product واضح؟
+
+329
+00:29:50,780 --> 00:29:56,640
+كذلك الحالة بهذا المثال هيبدأ احذف ال OH تأكيد مش
+
+330
+00:29:56,640 --> 00:30:03,450
+فيها نقاش بس بدي Hمجاورة هنا في اتش وهذا المثل
+
+331
+00:30:03,450 --> 00:30:08,030
+كمان فيها اتش لو حذفت هذا الاتش اللي هنا بيطلع
+
+332
+00:30:08,030 --> 00:30:12,110
+الناتج التاني و لو حذفت الاتش من هنا او اتش او اتش
+
+333
+00:30:12,110 --> 00:30:17,050
+بيطلع هذا نتطلع عليهم which is more substituted
+
+334
+00:30:17,050 --> 00:30:21,470
+اكيد هذا more substituted ال major ال minor نفس
+
+335
+00:30:21,470 --> 00:30:24,610
+الكلام كنا نجيب السؤال بس بدل ما نكون كاتبين OH
+
+336
+00:30:24,610 --> 00:30:31,410
+نكون كاتبين CL او PRاللي عملناه لما كان دا يكون CL
+
+337
+00:30:31,410 --> 00:30:35,170
+او PR في chapter ال elimination في ال alkalites هو
+
+338
+00:30:35,170 --> 00:30:40,270
+نفسه بنطبقه على ال alcohol ف ال dehydration of
+
+339
+00:30:40,270 --> 00:30:46,530
+alcohol بيعطي نتائج موازية تماما ل ال
+
+340
+00:30:46,530 --> 00:30:51,100
+dehydrohalogenation of alcoholAlkyl Halides لاحظوا
+
+341
+00:30:51,100 --> 00:30:55,720
+في ال alcohols شو سمينا العملية؟ dehydration نزع
+
+342
+00:30:55,720 --> 00:31:00,780
+الماء OH وH طب لو كانت هذه بيه R او halogen X وH
+
+343
+00:31:00,780 --> 00:31:05,380
+ايش قولنا عنها؟ dehydrohalogenation
+
+344
+00:31:05,380 --> 00:31:11,600
+واضح؟ يعني لو هذه كانت X, hydro و halogen فصارت
+
+345
+00:31:11,600 --> 00:31:15,280
+dehydrohalogenation
+
+346
+00:31:15,280 --> 00:31:22,830
+لما H و OHdehydration و سبق أن وضحت لكم إيش معناه
+
+347
+00:31:22,830 --> 00:31:26,710
+الإضافات و النزع hydrogenation, dehydrogenation,
+
+348
+00:31:26,850 --> 00:31:30,290
+hydration, dehydration, hydrogenation,
+
+349
+00:31:30,410 --> 00:31:36,990
+dehydrogenation هذه المصطلحات لازم تكون واضحة لازم
+
+350
+00:31:36,990 --> 00:31:44,750
+تكون واضحة عندكم من تفاعلات ال alcohols التفاعل مع
+
+351
+00:31:44,750 --> 00:31:49,670
+ال hydrogen halidesالان هذا التفاعل سبق اننا
+
+352
+00:31:49,670 --> 00:31:54,870
+شرحناه لكن بنعيد نأكد عليه مرة ثانية ال alcohol مع
+
+353
+00:31:54,870 --> 00:32:00,370
+ال hydrogen halide بيبدل ال OH ب X بيعطيني RX زائد
+
+354
+00:32:00,370 --> 00:32:06,290
+H2O الان لو اتيت انا اتطلعت على ال alcohol ايش
+
+355
+00:32:06,290 --> 00:32:10,900
+ممكن يكون ال alcohol ممكن يكون tertiaryو secondary
+
+356
+00:32:10,900 --> 00:32:14,800
+و primary افضل اش هيتفاعل مع ال tertiary ال
+
+357
+00:32:14,800 --> 00:32:24,040
+hydrogen halides ممكن تكون يود و بروم و كلور واضح؟
+
+358
+00:32:25,040 --> 00:32:28,740
+الـ hydrogen halides يا يود يا بروم يا كلور، مين
+
+359
+00:32:28,740 --> 00:32:32,420
+أحسن واحدة بتتفعل؟ أفضل من البروم، أفضل من الكلور
+
+360
+00:32:32,420 --> 00:32:36,580
+والالكهول تيرتشري أفضل من سكندريا، أفضل من إيش؟ ال
+
+361
+00:32:36,580 --> 00:32:41,280
+primary بناء على ذلك، لو أنا أجي اتفعلت أي ألكهول
+
+362
+00:32:41,280 --> 00:32:47,660
+من هدولة مع يود أو بروم، يعني مع HI أو HPR، هيتفعل
+
+363
+00:32:47,660 --> 00:32:53,360
+بدون مشاكل ويعمل إبدالهتصير المشكلة وين؟ لو بدأ
+
+364
+00:32:53,360 --> 00:32:59,060
+ضقة فاعل، الأضعف هان مع الأضعف هان، بتمشي التفاعل
+
+365
+00:33:00,250 --> 00:33:05,650
+بشكل عام يعني لو أخدت ال primary alkyl halide مع
+
+366
+00:33:05,650 --> 00:33:10,450
+HCl مش هيعمل إبدال يعني لو أخدت ال ethanol مع ال
+
+367
+00:33:10,450 --> 00:33:16,090
+HCl إيثانول مع HCl بيعمل إبدال إيثانول primary HCl
+
+368
+00:33:16,090 --> 00:33:20,250
+للأضعف بيعملش إبدال بعد ذلك خدوا على سبيل المثال
+
+369
+00:33:20,250 --> 00:33:25,890
+high tertiary alkyl halide ملاحظين انتوا؟ مع HCl
+
+370
+00:33:25,890 --> 00:33:29,070
+عمل
+
+371
+00:33:29,070 --> 00:33:34,250
+إبدالTertiary Alkylide مع HCl عمل إبدالة اللي ما
+
+372
+00:33:34,250 --> 00:33:42,010
+بيعملش أي واحد ال primary مع ال HCl يمكن هنا مرات
+
+373
+00:33:42,010 --> 00:33:45,270
+التفاعل بيكون إيش قوي زي التانين يعني حطوله
+
+374
+00:33:45,270 --> 00:33:50,670
+catalyst zinc chloride ما بضرش مش مشكلة بس بيمشي
+
+375
+00:33:50,670 --> 00:33:57,220
+في الآخر واضح؟ بيمشيحتى لو أخدت secondary alcohol
+
+376
+00:33:57,220 --> 00:34:01,200
+ماقعدش CL في وجود ذنك كلورادي و شوية تسخين بمشي
+
+377
+00:34:01,200 --> 00:34:06,560
+لكن مين اللي فيه المشكلة ال primary؟ اه مع ال FCL
+
+378
+00:34:06,560 --> 00:34:12,580
+لاحظوا هنا عشان هيك بنلاقي حلول بديلة لما يصير عند
+
+379
+00:34:12,580 --> 00:34:17,340
+primary لو قلتلكوا ماقعدش CL إيش الجواب؟ نوريا
+
+380
+00:34:20,520 --> 00:34:24,140
+بدّو البني آدم هيك هيك لازم يحوّل الـ OH لـCl
+
+381
+00:34:24,140 --> 00:34:28,180
+بيغير ال reagent يعني لو استعمل ال primary مع ال
+
+382
+00:34:28,180 --> 00:34:35,080
+BCL3 فوسفوراس الـ Trichloride بيعمل تفاعل واضح؟
+
+383
+00:34:35,080 --> 00:34:38,780
+يعني ال primary الكهول مع فوسفوراس ال Trichloride
+
+384
+00:34:38,780 --> 00:34:43,080
+بتفاعل بيبدّي ال OH بCL لكن مع ال HCL لأ بتفاعل
+
+385
+00:34:43,080 --> 00:34:47,320
+وغير الفوسفوراس ال Trichloride أخدنا كمان reagent
+
+386
+00:34:47,320 --> 00:34:56,800
+SOCL2 هذا مشهور بيسميه ثيونيليكلورايد واضح؟ برضه
+
+387
+00:34:56,800 --> 00:35:02,920
+هذا ايش بيعمل؟ بتفاعل و بيبدل ال OH ل ال primary
+
+388
+00:35:02,920 --> 00:35:08,880
+بCL فسواء استعملت الفوسفوراس ال trichloride او
+
+389
+00:35:08,880 --> 00:35:12,380
+الثيونيليكلورايد بقدر اعمل التفاعل لكن لو استعملت
+
+390
+00:35:12,380 --> 00:35:19,650
+ال HCl بمشيش التفاعلطبعا ما عدا ذلك مع اليود و مع
+
+391
+00:35:19,650 --> 00:35:23,730
+البروم بيمشي مع كله تيرتشاري .. سكندر .. برايماري
+
+392
+00:35:23,730 --> 00:35:29,370
+.. يعني المشكلة حقيقة بين ال primary و ال hcl في
+
+393
+00:35:29,370 --> 00:35:32,150
+حلول بديلة ولا لأ؟ كم حل؟
+
+394
+00:35:40,460 --> 00:35:46,160
+هي هنا على سبيل المثال ال primary مع ال SOCl2
+
+395
+00:35:46,160 --> 00:35:51,480
+بتفاعل مية في المية الان لاحظوا ان هذا التفاعل
+
+396
+00:35:51,480 --> 00:35:57,100
+تفاعل إبدال ال OH ب X خاص بال alcohol يعني ال
+
+397
+00:35:57,100 --> 00:36:03,950
+phenols لا يتم عليها إبداليعني لو قلنا لكوا ال A R
+
+398
+00:36:03,950 --> 00:36:16,610
+O H مع HBR مع HCL مع BCL3 مع SOCL2 بكل لغات الأرض
+
+399
+00:36:16,610 --> 00:36:25,460
+لا تتفاعل مافيش إبدال علىالاروماتيك كومباونز لإيش؟
+
+400
+00:36:25,460 --> 00:36:29,400
+لأنه أنا هنا بدي أجيب سالب الـ nucleophile سالب و
+
+401
+00:36:29,400 --> 00:36:32,740
+أخليه يهاجم على البنزينة و احنا من البداية اتفقنا
+
+402
+00:36:32,740 --> 00:36:36,080
+انه الإبدال اللي على البنزين Electrophilic
+
+403
+00:36:36,080 --> 00:36:39,460
+Substitution in general واضح؟ يعني انا لو اجيت
+
+404
+00:36:39,460 --> 00:36:43,740
+افعل مع هدولة في النهاية هاجيب PR minus او I minus
+
+405
+00:36:43,740 --> 00:36:47,960
+minus على minus بيصير و لذلك الإبدالات اللي هنا
+
+406
+00:36:47,960 --> 00:36:53,940
+كلها اللي أخدناها هي متعلقةبالكحولات بال R O H لكن
+
+407
+00:36:53,940 --> 00:36:58,440
+لو صارت A R O H بنزينة أو حملة O H و قلتلكوا
+
+408
+00:36:58,440 --> 00:37:03,740
+بدلوها ب C L و ب R لأواضح؟ هنا مافيش substitution
+
+409
+00:37:03,740 --> 00:37:07,840
+في ال aromatic compounds ال substitution في إيش؟
+
+410
+00:37:07,840 --> 00:37:12,200
+في ال aliphatic compounds تبوا هذا الكلام ممكن
+
+411
+00:37:12,200 --> 00:37:16,440
+نسألكوا يا صح و غلط aromatic alcohols undergo
+
+412
+00:37:16,440 --> 00:37:22,540
+substitution in uneasy manner مثلا ولا .. no they
+
+413
+00:37:22,540 --> 00:37:26,320
+don't undergo substitution
+
+414
+00:37:30,300 --> 00:37:34,040
+ما هو الـ Electrophilic Substitution بيبطل في هذه
+
+415
+00:37:34,040 --> 00:37:38,420
+الحالة للـ OH بيصير في مكان تاني على البنزينة
+
+416
+00:37:38,420 --> 00:37:44,520
+بيختلف التفاعل يعني زي ما تجيب فينول و بدك تعمل
+
+417
+00:37:44,520 --> 00:37:50,200
+مثلا مع الchlor FeCl3 على سبيل المثال أو تاخد O
+
+418
+00:37:50,200 --> 00:37:57,880
+Methyl بتصير تبدل هنا بتبدل Hydrogens مش بتبدلطبعا
+
+419
+00:37:57,880 --> 00:38:01,320
+المشكلة ان الفينول نفسه بعارض مع ال FEC الاتنين
+
+420
+00:38:01,320 --> 00:38:05,420
+افترض او مثل مثلا بتبدليش ال او مثل بتبدلي ايش
+
+421
+00:38:05,420 --> 00:38:11,540
+بتبدلي على الحلقة هيدروجينات بتبدلي هيدروجينات على
+
+422
+00:38:11,540 --> 00:38:20,140
+الحلقة الان ال alcohol من تفاعلاتها الشهيرة تفاعل
+
+423
+00:38:20,140 --> 00:38:25,720
+ال oxidation خليني اقول ايش معنى ال oxidationال
+
+424
+00:38:25,720 --> 00:38:29,920
+Oxidation بلغة الكيميا ما انا عارف ترجمتها انه
+
+425
+00:38:29,920 --> 00:38:34,900
+افقد ال H تبعت ال OH يعني لو انا اطلعت على المركب
+
+426
+00:38:34,900 --> 00:38:41,420
+CHOH زي هيك و ايش ما كان يكون عندى هنا ان افقد
+
+427
+00:38:41,420 --> 00:38:47,910
+جزئها هيدروجينأفقد الـ H اللي على الأكسجين و H على
+
+428
+00:38:47,910 --> 00:38:52,310
+الكربون المتسقة بها الأكسجين مباشرة الآن هدولة لو
+
+429
+00:38:52,310 --> 00:38:56,550
+فقدوا زي هيك على شكل جزء هيدروجين هذه إيش بنتيجة
+
+430
+00:38:56,550 --> 00:39:02,950
+تعمل هنا double bond طالما عملت double bond شو
+
+431
+00:39:02,950 --> 00:39:09,330
+هيصير النتج الديهايد أو كيتونباعتمد على هدول
+
+432
+00:39:09,330 --> 00:39:13,130
+المجموعتين خلّينا نكون في البداية فاهمين قصة
+
+433
+00:39:13,130 --> 00:39:18,950
+الأكسدة الأكسدة معناها ان ال COH بيصير C double
+
+434
+00:39:18,950 --> 00:39:24,090
+bond O طالما C double bond O صارت اذا صارت الجهاي
+
+435
+00:39:24,090 --> 00:39:29,870
+او كيتون هتفقد ال H تعطي ال OH OH عن الكربون اللي
+
+436
+00:39:29,870 --> 00:39:35,790
+هنا اول سؤال هيجيكم طب يا ترى لو فيش هنا H
+
+437
+00:39:38,560 --> 00:39:43,880
+يعني لو هذه كانت R و R و R فى عندي OH مستعدة تفقد
+
+438
+00:39:43,880 --> 00:39:48,860
+ال H بس فىش هنا H يعني صار إيش نوع ال alcohol?
+
+439
+00:39:50,620 --> 00:39:55,800
+tertiary واضحة؟ يعني افترضوا هذه كانت C وهذه C
+
+440
+00:39:55,800 --> 00:40:02,370
+وهذه C CH3 CH3 CH3 هنا فى H هنا مافيش Hبدوا يتم
+
+441
+00:40:02,370 --> 00:40:07,270
+الأكسدة؟ إذا على طول هنطلع قاعدة أن الـ tertiary
+
+442
+00:40:07,270 --> 00:40:11,070
+alcohols اللي مافيش عليهم هيدروجينة هنا بتأكسدوش
+
+443
+00:40:11,070 --> 00:40:17,150
+إذا التأكسد خاص بماذا؟ ال primary و ال secondary
+
+444
+00:40:17,150 --> 00:40:22,090
+التيرتشاري مابصله أكسدة ليش؟ لأن الأكسد بدأ أفقد
+
+445
+00:40:22,090 --> 00:40:25,130
+من ال OH هيدروجينة و من الكربون اللي حامله
+
+446
+00:40:25,130 --> 00:40:27,850
+هيدروجينة طب الكربون اللي حامله مش حامله هيدروجينة
+
+447
+00:40:28,820 --> 00:40:33,540
+إذا الأكسدة لا تتم مع إيش؟ مع ال tertiary
+
+448
+00:40:33,540 --> 00:40:37,860
+alcohols، الآن مع ال primary وال secondary؟ بالتم،
+
+449
+00:40:37,860 --> 00:40:44,160
+شو بدها تعطيني؟الديهايد او كيتون وقت ايش بتعطي
+
+450
+00:40:44,160 --> 00:40:49,760
+الديهايد و وقت ايش بتعطي كيتون ال primary ببساطة
+
+451
+00:40:49,760 --> 00:40:55,480
+بيعطي الديهايد و ال secondary بيعطي كيتون واضح؟
+
+452
+00:40:55,480 --> 00:40:59,380
+اذا كأنه لو الانسان بده يلخص الكلام ان ال alcohol
+
+453
+00:40:59,380 --> 00:41:03,920
+في كام نوع؟ primary secondary و tertiary ال
+
+454
+00:41:03,920 --> 00:41:11,080
+tertiaryكفى الله المؤمنين القتال ..مش فيها كلمة شر
+
+455
+00:41:11,080 --> 00:41:17,300
+..وكفى الله المؤمنين القتال ال tertiary بتأكسدش ال
+
+456
+00:41:17,300 --> 00:41:22,400
+primary لما يتأكسد شو هيعطيني ال dihyde ال
+
+457
+00:41:22,400 --> 00:41:28,130
+secondary لما يتأكسد شو هيعطيني كيتونلحظته هيك
+
+458
+00:41:28,130 --> 00:41:34,290
+بيصير العلم ايش ماله؟ سهل انه ال alcohols تلاتة ال
+
+459
+00:41:34,290 --> 00:41:38,630
+primary او ال secondary او ال tertiary ال primary
+
+460
+00:41:38,630 --> 00:41:44,560
+هيعطيني aldehyde ال secondary كيتون ال tertiaryمش
+
+461
+00:41:44,560 --> 00:41:50,320
+حيت أكسد الان المرة الجاية بتجيجتين هنوضح ايش
+
+462
+00:41:50,320 --> 00:41:54,440
+العامل المؤكسد اللي بتتم فيه العملية يعني نبدأ من
+
+463
+00:41:54,440 --> 00:41:58,820
+هذه بنشرحها بتجيجتين وننتبه ان ال الديهايد ممكن
+
+464
+00:41:58,820 --> 00:42:06,400
+بعدين يعمل تفاعل تاني يصير أسد هذه زيادة واضح؟ لكن
+
+465
+00:42:06,400 --> 00:42:12,560
+الأكسد الأساسية الأولى ال primary شو بيصير؟الـ
+
+466
+00:42:12,560 --> 00:42:17,640
+secondary الـ tertiary لا يتأكسد الان ال primary
+
+467
+00:42:17,640 --> 00:42:22,200
+بعد ما يصير الديهاي ممكن لو العامل المؤكسد قوي
+
+468
+00:42:22,200 --> 00:42:28,660
+يمشي كمان مرحلة يصير أسد لو ضعيف بيظل زي ما هو إذا
+
+469
+00:42:28,660 --> 00:42:32,340
+بتصير قصتنا إيش العامل المؤكسد اللي استعملنا هان و
+
+470
+00:42:32,340 --> 00:42:37,340
+هان هان من الأساس مافيش أكسدة من هذه المقطة ان شاء
+
+471
+00:42:37,340 --> 00:42:40,120
+الله بنبدأ المرة الجاية
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..7be7452f0f81323e1dd5a708258e82498d9b65cb
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_postprocess.srt
@@ -0,0 +1,1992 @@
+1
+00:00:20,330 --> 00:00:25,410
+بسم الله الرحمن الرحيم اليوم ان شاء الله درسنا مش
+
+2
+00:00:25,410 --> 00:00:30,670
+في موضوع معين لأ هو مراجعة شاملة من خلال حل
+
+3
+00:00:30,670 --> 00:00:36,320
+الامتحانات السابقة استعدادا للامتحانالنصفي ربما
+
+4
+00:00:36,320 --> 00:00:40,320
+أحيانا اتلاحظوا بعض الأسئلة لامتحان النصفي كان
+
+5
+00:00:40,320 --> 00:00:44,380
+للفصل السابع المرة هذه طلبنا منكوا للفصل السادس
+
+6
+00:00:44,380 --> 00:00:49,160
+فمش مشكلة يعني الإنسان بيقدر يعرف الأسئلة هتلاحظوا
+
+7
+00:00:49,160 --> 00:00:54,980
+ان في عندنا أسئلة متنوعة بشكل عام دائما ننصح
+
+8
+00:00:54,980 --> 00:01:01,250
+الطلاب انه يهتموابالأفكار الأساسية العامة يكونوا
+
+9
+00:01:01,250 --> 00:01:06,030
+فاهمينها بنسبة أكبر هذا بمنعش أنه في أشياء متخصصة
+
+10
+00:01:06,030 --> 00:01:09,730
+لكن دائما الطالب أول شيء يجب أن يكون عنده يعني
+
+11
+00:01:09,730 --> 00:01:14,190
+قناع أن هو فاهم الاشي الأفكار العامة ولذلك ربما
+
+12
+00:01:14,190 --> 00:01:19,110
+تلاحظوا أنه يعني لو أنا بدأ أصنف الأسئلة مش في هذا
+
+13
+00:01:19,110 --> 00:01:24,450
+الامتحان في معظم الامتحانات هنكتشف أنه هي عنوين
+
+14
+00:01:25,470 --> 00:01:30,250
+يعني هي عنوين لأشياء احنا درسناها خلينا نشوف هذا
+
+15
+00:01:30,250 --> 00:01:35,710
+الكلام من خلال التطبيق الآن في هذا الامتحان اللي
+
+16
+00:01:35,710 --> 00:01:41,350
+أمامنا في عندنا مجموعة من الجمال هذه المجموعة من
+
+17
+00:01:41,350 --> 00:01:46,450
+الجمال بدنا نكمل الفراغ فيها complete the
+
+18
+00:01:46,450 --> 00:01:50,450
+following السؤال أول مثلا بيسألنا الدياستيريو
+
+19
+00:01:50,450 --> 00:01:55,210
+مارزهاف و بيحكي عن ال physical propertiesالان كان
+
+20
+00:01:55,210 --> 00:01:58,970
+واضح تماما ان ال بيستيريو مارز هيف different
+
+21
+00:01:58,970 --> 00:02:02,390
+physical
+
+22
+00:02:02,390 --> 00:02:10,670
+properties واضح الان السؤال التاني addition of HBr
+
+23
+00:02:10,670 --> 00:02:17,410
+H plus to isobutene produces لاحظوا هنا السؤال هذا
+
+24
+00:02:17,410 --> 00:02:22,070
+في فكرتين ان الطالب لازم في الأول يعرف ايش هو ال
+
+25
+00:02:22,070 --> 00:02:28,970
+isobuteneهذا ال isobutene واضح بعد هيك إضافة ال
+
+26
+00:02:28,970 --> 00:02:35,930
+HBR H plus معناه ذلك هذه إضافة حسب Markov-Nikov
+
+27
+00:02:35,930 --> 00:02:40,670
+addition يعني هذه بدها تروح يجي عند هنا H و يجي
+
+28
+00:02:40,670 --> 00:02:44,070
+عند هنا CL او PR و بنحكي عن PR
+
+29
+00:02:47,350 --> 00:02:53,650
+الان هذا المركب اللى طلع عندى carbon حاملة CH3 CH3
+
+30
+00:02:53,650 --> 00:03:01,230
+CH3Br هذه مجموعة لها اسم ولا لأ تيرتشاري بيوتل
+
+31
+00:03:01,230 --> 00:03:09,310
+إبرومايد produces tertiary butyl bromide من تسمية
+
+32
+00:03:09,310 --> 00:03:16,810
+المجموعات produces tertiary butyl bromideالان فكرة
+
+33
+00:03:16,810 --> 00:03:20,890
+عامة قلنا ال branched alkanes اللي هم ال boiling
+
+34
+00:03:20,890 --> 00:03:23,930
+point و ال melting point lower than ال chain
+
+35
+00:03:23,930 --> 00:03:28,390
+alkanes الان ال branched alkanes هم اكيد هنا هتكون
+
+36
+00:03:28,390 --> 00:03:32,110
+higher او lower boiling point than the
+
+37
+00:03:32,110 --> 00:03:37,890
+corresponding chain lower ال
+
+38
+00:03:37,890 --> 00:03:44,850
+curved arrows قلنا عنهمالهم رأسين are used to
+
+39
+00:03:44,850 --> 00:03:53,830
+indicate the movement of two electrons ممتاز ال
+
+40
+00:03:53,830 --> 00:04:00,350
+reaction المهم من البنزين هو أي تحديد تحديد
+
+41
+00:04:00,350 --> 00:04:07,070
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+42
+00:04:07,070 --> 00:04:10,130
+الهواتف الهواتف
+
+43
+00:04:10,130 --> 00:04:10,910
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+44
+00:04:10,910 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+45
+00:04:11,810 --> 00:04:24,490
+الكلهيليتز اليوكليوفيليك اليوكليوفيليك
+
+46
+00:04:28,790 --> 00:04:33,570
+Dipromination of a Neopentane gives a total of ..
+
+47
+00:04:33,570 --> 00:04:38,110
+لاحظوا معي تكونوا عارفين لـ Neopentane يعني أنا
+
+48
+00:04:38,110 --> 00:04:41,950
+هنا باختبركم أن تكونوا عارفين هذا المُركّب لـ
+
+49
+00:04:41,950 --> 00:04:45,470
+Neopentane اللي هي الكربون اللي حاملة كام مثل؟
+
+50
+00:04:45,470 --> 00:04:49,910
+أربعة الأربعة الأربعة دي دي Dipromination
+
+51
+00:04:51,580 --> 00:04:57,320
+يعني احض ذرتين abroad كم ناتج بتوقع التنتين ممكن
+
+52
+00:04:57,320 --> 00:05:00,880
+ييجوا على نفس الذرع اذا اجوا تنتين هان زي هان زي
+
+53
+00:05:00,880 --> 00:05:08,060
+هان و ممكن ييجوا علىدرتين مختلفتين يعني ايه ييجي
+
+54
+00:05:08,060 --> 00:05:12,460
+هان و هان لحظوا هان و هان زي هذه و هذه زي هذه و
+
+55
+00:05:12,460 --> 00:05:15,860
+هذه زي هذه و هذه لأن المجموعات كلها ماخدة
+
+56
+00:05:15,860 --> 00:05:19,140
+tetrahedral arrangement متذكرين لما كنا نقول مافيش
+
+57
+00:05:19,140 --> 00:05:23,100
+اشي اسمه مجموعتين جان بعض و اشي اسمه مجموعتين قبال
+
+58
+00:05:23,100 --> 00:05:27,280
+بعض يعني تيجي طالبة تقول حط ال .. البروم هان و هان
+
+59
+00:05:27,280 --> 00:05:30,860
+بتختلف عن البروم هان و هان لأ هذه الزاوية PR, CPR
+
+60
+00:05:30,860 --> 00:05:37,280
+قداش مقدارهامية و تسعة و نص كربون حملة PR كربون كم
+
+61
+00:05:37,280 --> 00:05:40,640
+.. كربون حملة PR كدهش مقدارها؟ مية و تسعة و نص إذا
+
+62
+00:05:40,640 --> 00:05:45,260
+كم ناتج هنا؟ أربعة ليش أربعة؟ مش هو two bromine
+
+63
+00:05:45,260 --> 00:05:50,800
+atoms طيب انا .. انا حطيت two bromine atoms أو
+
+64
+00:05:50,800 --> 00:05:53,720
+حطيت وحدها وحدها هاي معناه die bromination طيب و
+
+65
+00:05:53,720 --> 00:05:57,100
+لو حطنا على ال carbon نفل نص ال carbon نفل نص
+
+66
+00:05:57,100 --> 00:05:58,540
+بيصير على خمس روابط؟
+
+67
+00:06:01,850 --> 00:06:05,670
+يا التنتين على هذه الذرة، يا التنتين كل واحدة على
+
+68
+00:06:05,670 --> 00:06:11,690
+ذرة، سواء كانت هان أو هان أو هان، إذا كان مركب two
+
+69
+00:06:11,690 --> 00:06:15,910
+isomers، structural isomers of course
+
+70
+00:06:18,990 --> 00:06:24,790
+The IUPAC name of allyl chloride لاحظوا كام سؤال
+
+71
+00:06:24,790 --> 00:06:28,970
+صار جايكم اؤكد انكوا تكونوا عارفين المجموعات
+
+72
+00:06:28,970 --> 00:06:32,150
+والمركبات الأساسية اللي أخدناها جيبنا ال tertiary
+
+73
+00:06:32,150 --> 00:06:38,430
+butyl هاي جيبنا ال allyl اللي هي CH2 CH double
+
+74
+00:06:38,430 --> 00:06:44,770
+bond CH2 Hanachlor وقولنا سابقا ان هذا بدو يتسمى
+
+75
+00:06:44,770 --> 00:06:53,810
+واحد اتنينتلاتة اذا three chloro one
+
+76
+00:06:53,810 --> 00:07:04,450
+propene three chloro one propene واضح؟
+
+77
+00:07:04,450 --> 00:07:09,150
+فحفظ المجموعات بين القليل ايزو بروبيل ايزو بيوتل
+
+78
+00:07:09,150 --> 00:07:13,250
+اساسي جداgeneration of the second chiral center
+
+79
+00:07:13,250 --> 00:07:19,290
+produces unequal mixture of diastereomers هذا أكمل
+
+80
+00:07:19,290 --> 00:07:26,470
+الجواب، هيك العنوان صح ولا لأ؟ unequal mixture of
+
+81
+00:07:26,470 --> 00:07:32,470
+diastereomers والfirst
+
+82
+00:07:32,470 --> 00:07:36,350
+chiral center شو كان بيعمل؟ racemic mixture of
+
+83
+00:07:36,350 --> 00:07:42,090
+enantiomers the meso compound is opticallyinactive
+
+84
+00:07:42,090 --> 00:07:47,630
+كان عنوان meso compounds are optically inactive
+
+85
+00:07:47,630 --> 00:07:54,790
+واضح هي دي مراجعة شاملة خلينا نقوله بعتقد جميلة
+
+86
+00:07:54,790 --> 00:07:59,930
+لمفاهيم أساسية أخدناها واضحة
+
+87
+00:08:12,680 --> 00:08:18,980
+الان بعد هيك ارسمولنا أشكال بعض المركبات
+
+88
+00:08:18,980 --> 00:08:22,000
+Cyclobentane
+
+89
+00:08:22,000 --> 00:08:26,500
+مين ما بيعرفوا ال Cyclobentane؟ هاي ال
+
+90
+00:08:26,500 --> 00:08:30,500
+Cyclobentane أسس على نمرة واحد و تلت يعني لو قولنا
+
+91
+00:08:30,500 --> 00:08:38,230
+هنا مثلا خلينا نحط إبروم للأمام وهنابروم هاي واحد
+
+92
+00:08:38,230 --> 00:08:43,990
+اتنين تلاتة وستعملنا
+
+93
+00:08:43,990 --> 00:08:51,070
+الشكل الفراغي عشان نبين انه مجموعتين للامام الان
+
+94
+00:08:51,070 --> 00:08:58,450
+Cyclohexane نعرف ال Cyclohexane هاي Cyclohexane
+
+95
+00:08:58,450 --> 00:09:03,980
+والترقيم بيكون واحدتنين و نستمر نمر عبر ال double
+
+96
+00:09:03,980 --> 00:09:09,280
+bond صح ولا لأ يعني واحد اتنين تلاتة اربعة خمسة
+
+97
+00:09:09,280 --> 00:09:12,280
+ستة الان على نمرة اتنين ايش في اندي في ال
+
+98
+00:09:12,280 --> 00:09:24,860
+Cyclohexane بروم وعلى نمرة تلاتة isopropyl for
+
+99
+00:09:24,860 --> 00:09:32,020
+nitroicumin اخدنا الاكيومين انه ال isopropylبنزين
+
+100
+00:09:32,020 --> 00:09:38,360
+قلنا ايزوبروب البنزين is كيومين لما بتحط على
+
+101
+00:09:38,360 --> 00:09:49,060
+الأربعة ن او اتو for نيترو كيومين الان المركب هذا
+
+102
+00:09:49,060 --> 00:09:54,420
+بدنا نسميه اين و اين ضايقين
+
+103
+00:09:55,420 --> 00:10:01,040
+لما بدنا ننتبه من وين بدنا نعمل الترقيم يعني واحد
+
+104
+00:10:01,040 --> 00:10:06,460
+اتنين تلاتة اربعة خمسة و هنا في كمان carbon ستة
+
+105
+00:10:06,460 --> 00:10:10,840
+طبعا لاحظوا انه انا لو برقم من هنا بيكون double
+
+106
+00:10:10,840 --> 00:10:16,120
+points عند اتنينوخمسة لو برقم هنا عند واحد اتنين
+
+107
+00:10:16,120 --> 00:10:19,860
+واحد واربعة لازم اسعى ان ال double poles يكونوا
+
+108
+00:10:19,860 --> 00:10:25,160
+اقل ترقيم اذا هذا هقول واحد اتنين تلاتة اربعة خمسة
+
+109
+00:10:25,160 --> 00:10:33,960
+ستة فهذا المركب هيكون one four hexadien
+
+110
+00:10:33,960 --> 00:10:41,370
+ايش بيحمل على نمرة تلاتة وعلى نمرة اربعةأه إذا هذا
+
+111
+00:10:41,370 --> 00:10:49,490
+كمان بدو ييجي عليه three four diapromo one four
+
+112
+00:10:49,490 --> 00:10:55,660
+الآن هذا double bondمافيش عليها مجموعات مختلفان و
+
+113
+00:10:55,660 --> 00:10:58,500
+.. يعني مافيش فيها ظاهرة ال sexual trance بس هذا
+
+114
+00:10:58,500 --> 00:11:02,700
+ال double bond فيها .. يعني هنا في عندى مثل و أتش،
+
+115
+00:11:02,700 --> 00:11:07,040
+لاحظوا كل رأس زي هذا يعتبر مثل، انتبهوله في العد و
+
+116
+00:11:07,040 --> 00:11:12,110
+انتبهوله لما تشتغلوا، المثل أعلى من الأتشالمثل
+
+117
+00:11:12,110 --> 00:11:17,350
+أعلى من الـ H هنا PR و Carbon أنا باطلع فقط على
+
+118
+00:11:17,350 --> 00:11:20,470
+الذرة الأولى و الأولى هذه PR وهذه Carbon الآن
+
+119
+00:11:20,470 --> 00:11:25,410
+هذولا المجمعتين على جهة واحدة إذا هذا المركب Z
+
+120
+00:11:25,410 --> 00:11:31,610
+فلما بدي تسمية كاملة Z three four dibromo one four
+
+121
+00:11:31,610 --> 00:11:33,050
+hexadien
+
+122
+00:11:35,670 --> 00:11:38,790
+واضح؟ ال double bond التانية مافيش فيها أي شيء
+
+123
+00:11:38,790 --> 00:11:42,490
+طبعا واضح أنه هنا في chiral center لكن طالما أنا
+
+124
+00:11:42,490 --> 00:11:47,010
+ماحطتوش على شكل صليب معناه ذلك أنا مش مركز أني
+
+125
+00:11:47,010 --> 00:11:54,470
+اتحددولي IR أو استركتو مفتوح هذا المركب مثلا في
+
+126
+00:11:54,470 --> 00:11:58,330
+chiral center وموضح أنه أنا طالب ال chiral center
+
+127
+00:11:58,330 --> 00:12:06,270
+هنا واضح؟ لو أتيت طلعت أطول سلسلةانعلمها بالاحمر
+
+128
+00:12:06,270 --> 00:12:14,430
+واحد اتنين تلاتة اربعة اذا هذا بيوتين ايش بيحمل
+
+129
+00:12:14,430 --> 00:12:19,450
+هذا البيوتين على البيوتين واحد اتنين تلاتة اربعة
+
+130
+00:12:19,450 --> 00:12:26,870
+على نمرة واحد اكلور وعلى نمرة تلاتة فنل والترقيم
+
+131
+00:12:26,870 --> 00:12:29,770
+منها لان لو رقمتي منها هيصيروا على اتنين واربعة
+
+132
+00:12:29,770 --> 00:12:38,510
+بدي ال lower numbering اذا هذاone chloro three
+
+133
+00:12:38,510 --> 00:12:47,330
+phenyl بيوتين الان في chiral center ال chiral
+
+134
+00:12:47,330 --> 00:12:53,370
+center هنا ال H أقل مجموعة أكيد البنزينة نمرة واحد
+
+135
+00:12:53,370 --> 00:13:00,310
+الكاربون هذه نمرة اتنين وال CH3 نمرة تلاتةواحد
+
+136
+00:13:00,310 --> 00:13:06,870
+اتنين تلاتة وهذه موجودة اذا هذا اس one chlorine
+
+137
+00:13:06,870 --> 00:13:08,750
+three phenyl butane
+
+138
+00:13:15,300 --> 00:13:19,960
+المُركّب اللي بعده aromatic فيه مجموعتين، معنا ذلك
+
+139
+00:13:19,960 --> 00:13:24,020
+السؤال إنه مين أعلى في الأولوية عشان أسمه إيه؟ ال
+
+140
+00:13:24,020 --> 00:13:27,600
+ketone ولا ال alcohol؟ ال ketone، الآن هذا
+
+141
+00:13:27,600 --> 00:13:32,320
+المُركّب إيش اسمه؟ أسيتوفينون، نكتب small letter
+
+142
+00:13:34,690 --> 00:13:40,030
+acetophenon ال O H بترجع على أصلها ال three one
+
+143
+00:13:40,030 --> 00:13:45,710
+two three ال three أو ميتا هيدروكسي الشغلتين صح ال
+
+144
+00:13:45,710 --> 00:13:50,470
+three هيدروكسي أسيتوفينون كلمة واحدة واضح ال three
+
+145
+00:13:50,470 --> 00:13:57,030
+هيدروكسي أسيتوفينون بتيعني كل هذه من ضمن الأفكار
+
+146
+00:13:57,030 --> 00:14:01,610
+العامة الأساسية اللي احنا درسناكم
+
+147
+00:14:18,380 --> 00:14:25,580
+الان بعد ذلك عندى اكمال معادلات هذا المركب مثل
+
+148
+00:14:25,580 --> 00:14:32,160
+Cyclopropane مثل Cyclopropane وحطينا لكوا بدنا
+
+149
+00:14:32,160 --> 00:14:37,020
+نشوف all structural isomers يعني مش مركز انا على
+
+150
+00:14:37,020 --> 00:14:40,720
+ال stereo isomers او اعمله monochlorination يعني
+
+151
+00:14:40,720 --> 00:14:46,860
+احط one chlorine atomواضح؟ وين بده احط هذه ال
+
+152
+00:14:46,860 --> 00:14:55,400
+chlorine طبعا هنبدأ نرسم اكثر من شكل مش عارف تلاتة
+
+153
+00:14:55,400 --> 00:14:59,900
+اربعة بنجرب احنا الان اكيد ال chlorine بإمكانها
+
+154
+00:14:59,900 --> 00:15:06,810
+تيجي هنا على المثلوأكيد ال chlorine بإمكانها تيجي
+
+155
+00:15:06,810 --> 00:15:11,250
+على هذا الموقع وأكيد ال chlorine بإمكانها تيجي على
+
+156
+00:15:11,250 --> 00:15:15,510
+هذا الموقع لأن هذا و هذا زي بعض، ضال عندكم إشي
+
+157
+00:15:15,510 --> 00:15:21,170
+تاني؟ خلاص وكل
+
+158
+00:15:21,170 --> 00:15:23,210
+واحد فيهم أكيد إله اسم مختلف
+
+159
+00:15:29,980 --> 00:15:35,600
+الان لاحظوا معي هذا المركب فيه double bond بنقول
+
+160
+00:15:35,600 --> 00:15:40,880
+في نمر واحد بدنا نضيف عليه pear acid ايش معناه
+
+161
+00:15:40,880 --> 00:15:48,260
+pear acid انه بده يلغي هذه و يعملي حلقة لكن انا
+
+162
+00:15:48,260 --> 00:15:53,160
+كمان بعد ما عملت هذه الحلقة بده اعمل ring opening
+
+163
+00:15:53,160 --> 00:15:59,920
+ضيفت ميهواضحة الفكرة؟ كيف هذي بتعمل ring opening؟
+
+164
+00:15:59,920 --> 00:16:07,240
+بيكونوا سن ولا أنتي؟ مجموعات ال OHS ال
+
+165
+00:16:07,240 --> 00:16:10,360
+ring opening من البرأس الانتي
+
+166
+00:16:12,610 --> 00:16:17,550
+هي الميه من وين بتيجي عكس هذه اللي كان يعمل sin
+
+167
+00:16:17,550 --> 00:16:22,350
+addition لمجموعتين OH الكيامان O4 والأزوميوم O4
+
+168
+00:16:22,350 --> 00:16:27,590
+أخدناهم بيعملوا sin addition لمجموعتين OH لكن بهذه
+
+169
+00:16:27,590 --> 00:16:31,890
+الطريقة بنطلع ال Anti product اللي كان واضح تماما
+
+170
+00:16:31,890 --> 00:16:37,350
+يعني بدكوا تحطوا OH على جهة و OH على الجهة التانية
+
+171
+00:16:37,350 --> 00:16:42,720
+بالتأكيد هنا هتكون هذه المجموعة هيكهيأجوا اشمالهم
+
+172
+00:16:42,720 --> 00:16:47,880
+انتي طبعا
+
+173
+00:16:47,880 --> 00:16:51,600
+اي واحدة متذاكرة جيدا مش ضروري تفكر تعمل زي هيك
+
+174
+00:16:51,600 --> 00:16:54,900
+خلاص هو ال bare acid و بعدين نعمل ring opening في
+
+175
+00:16:54,900 --> 00:17:00,660
+الميه هذا محصلته في الدماغ بيحط مجمعتين OH انتي
+
+176
+00:17:00,660 --> 00:17:09,120
+انتي طبعا الان لما نضيف H2 في وجود platinum
+
+177
+00:17:20,030 --> 00:17:25,790
+هذا المُركّب اللي فيه ال PR لحظة انا هنا حاططلكم
+
+178
+00:17:25,790 --> 00:17:29,290
+KOH و جايلكم ان انا بدي ال major elimination
+
+179
+00:17:29,290 --> 00:17:33,950
+product كأني بقول انو حطوا double bond هان او هان
+
+180
+00:17:33,950 --> 00:17:39,750
+واضح انه كتير ركزنا معاكم انه the more substituted
+
+181
+00:17:39,750 --> 00:17:44,710
+ال keenوالـ Form حسب قاعدة Zaitsev إذا هنا بدو
+
+182
+00:17:44,710 --> 00:17:52,170
+ييجي ال الـ K واضح؟ مش هتيجي ال PR مع هذه ال H لأن
+
+183
+00:17:52,170 --> 00:17:56,530
+هذا less substituted ال K هذا ال more substituted
+
+184
+00:17:56,530 --> 00:18:00,890
+الآن بعد هيك هذا المركب بدنا نضيف عليه ميا في وجود
+
+185
+00:18:00,890 --> 00:18:06,590
+H plus هذا إضافة Markovnikov لحظة هنا في carbon
+
+186
+00:18:06,590 --> 00:18:12,190
+تحمل H و هذه ال carbon لأ تحملش H إذالو حطينا
+
+187
+00:18:12,190 --> 00:18:19,390
+الشكل العام بس بتكون المشكلة وين أحط ال H وين أحط
+
+188
+00:18:19,390 --> 00:18:30,150
+ال OH حسب
+
+189
+00:18:30,150 --> 00:18:36,430
+قاعدة Markovnikov لأنه في الأساس هنا في عندكم H
+
+190
+00:18:36,430 --> 00:18:38,650
+اللي كانت متروكة فاضية
+
+191
+00:18:56,340 --> 00:19:03,760
+الان هنا بدنا نضيف HPR في وجود البروكسايد اذا هنا
+
+192
+00:19:03,760 --> 00:19:09,600
+الإضافة مع ولا عكس قاعدة Markovnikov عكس قاعدة
+
+193
+00:19:09,600 --> 00:19:15,520
+Markovnikov لاحظوا لما انا هنا بد اضيف H على هذه
+
+194
+00:19:15,520 --> 00:19:21,870
+الجهة و ال PR على اللي بتحمل Hانتبهوا معي ال H هنا
+
+195
+00:19:21,870 --> 00:19:26,350
+طالما عندكم مثل و مثل ماعملتش chiral center هنا
+
+196
+00:19:26,350 --> 00:19:30,390
+لأن هدول المجموعتين زي بعض يعني مافيش اد اربع
+
+197
+00:19:30,390 --> 00:19:35,850
+مجموعات مختلفة لكن هنا بدي يكون عندكم مثل و H و
+
+198
+00:19:35,850 --> 00:19:44,410
+هتيجيها ب Rهي مثل وهي H و إيش هيجي عندك PR في هذه
+
+199
+00:19:44,410 --> 00:19:50,450
+الحالة حيصير في كايرال سنتر على هذا الكربون الان
+
+200
+00:19:50,450 --> 00:19:56,410
+ال generation و في كايرال سنتر شو بيطلعلك رسمك
+
+201
+00:19:56,410 --> 00:20:01,550
+mixture كان هذا عنوان إذا انا لما بدي أجي أشتغل
+
+202
+00:20:01,550 --> 00:20:07,250
+الأصل بدي أشتغل بهذا الشكلهدولة بأي طريقة تكتبوها
+
+203
+00:20:07,250 --> 00:20:10,370
+مافيش فيها مشكلة إطلاقا لأنه مش chiral center في
+
+204
+00:20:10,370 --> 00:20:14,410
+النهاية يعني
+
+205
+00:20:14,410 --> 00:20:19,050
+لو كتبيه بأي طريقة مش مشكلة لكن هنا بدي أجي مثلا
+
+206
+00:20:19,050 --> 00:20:25,470
+أقول ال PR هان ال PR عكسها ممكن نكتب ال H و ال H و
+
+207
+00:20:25,470 --> 00:20:30,710
+نكتبالـ CH3 والـ CH3 أهم شيء نعمله .. أهم شيء
+
+208
+00:20:30,710 --> 00:20:38,610
+نعمله أن هذه المنطقة يكونوا هذولة أشملهم عكس بعض و
+
+209
+00:20:38,610 --> 00:20:42,330
+هذولة بيطلعوا ال 50 50 ratio
+
+210
+00:20:44,190 --> 00:20:47,510
+الان بأي طريقة تكتبوها مافيش مشكلة مش هيكون خلاف
+
+211
+00:20:47,510 --> 00:20:51,270
+يعني واحدة كتبت هنا PR و هنا CH3 و هنا H و عملت
+
+212
+00:20:51,270 --> 00:20:54,770
+صورتها مش مشكلة واحدة كتبت هنا CH3 و هنا H و هنا
+
+213
+00:20:54,770 --> 00:21:01,330
+PR مافيش مشكلة اهم يعني ارسموا التلاتة بأي شكل
+
+214
+00:21:01,330 --> 00:21:06,150
+بدكم إياه بس حطوا صورتهم في المرايا لو احنا نفس
+
+215
+00:21:06,150 --> 00:21:08,930
+الشكل بس شيلنا لابتا ثنائية و حاطينا ال PR هيك و
+
+216
+00:21:08,930 --> 00:21:10,770
+هيك وين تحط ال PR؟
+
+217
+00:21:25,670 --> 00:21:29,510
+الان السؤال اللي بعده draw all the possible
+
+218
+00:21:29,510 --> 00:21:34,870
+isomers having the formula C3H4
+
+219
+00:21:35,800 --> 00:21:41,180
+الان عندما تفكر في هذا الكلام تفكر في صيغة العامة
+
+220
+00:21:41,180 --> 00:21:52,320
+للمركبات الوضع الطبيعي ال C3 بتاخد HS في
+
+221
+00:21:52,320 --> 00:21:59,470
+الألكال اللي كله single bonds يعني ال C3H8 في
+
+222
+00:21:59,470 --> 00:22:07,170
+الالكينز صح؟ الان اذا شيلت منها هيدروجينتين صارت
+
+223
+00:22:07,170 --> 00:22:12,870
+C3H6 مقابل ان شيلتم يا عملت bubble bond يا حلقة
+
+224
+00:22:12,870 --> 00:22:17,910
+الان لسه انا مش بس هيدروجنتين بده اشيل كمان تنتين
+
+225
+00:22:17,910 --> 00:22:22,690
+يعني شيلت هيدروجنتين وكمان هيدروجنتين معنى ذلك
+
+226
+00:22:22,690 --> 00:22:27,870
+التفكير اللي بده يكون عندكم اما تنتين bubble bonds
+
+227
+00:22:28,750 --> 00:22:35,290
+أو تنتين حلقات او حلقة و double bond واضح؟ لأن كل
+
+228
+00:22:35,290 --> 00:22:39,130
+هيدروجينتين معناهم ان انت شيلتوا ايش؟ يا عملتوا
+
+229
+00:22:39,130 --> 00:22:42,810
+double bond يا عملتوا حلقة واضح؟ فانا شيلت
+
+230
+00:22:42,810 --> 00:22:46,310
+هيدروجين مرتين بين التمانية والاربعة اربع
+
+231
+00:22:46,310 --> 00:22:50,750
+هيدروجينات تنتين و تنتين الآن بدكوا تقولوا يا
+
+232
+00:22:50,750 --> 00:22:54,790
+تنتين double bonds يا تنتين حلقات يا double bond
+
+233
+00:22:54,790 --> 00:23:01,040
+وحلقة طبعا ال C3H4 ما بتحتملتلتين حلقات يعني كلها
+
+234
+00:23:01,040 --> 00:23:05,860
+كم ذرة هي تلاتة بناء على ذلك لو أنا فكرت أني بدأ
+
+235
+00:23:05,860 --> 00:23:10,220
+أعمل منهم حلقة حلقة واحدة لازم ألاحقها بكمان ايش
+
+236
+00:23:10,220 --> 00:23:14,760
+double bond لاحظوا لو هنا اتيتوا تكملوا ال
+
+237
+00:23:14,760 --> 00:23:20,420
+hydrogens هتطلع الفورموله صح اتش اتش اتش اتش اتش
+
+238
+00:23:20,420 --> 00:23:23,500
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+239
+00:23:26,930 --> 00:23:32,270
+هذا الاحتمال اللى فيه حلقات الان بعد هيك ممكن اعمل
+
+240
+00:23:32,270 --> 00:23:37,870
+التنتين bubble bonds اعتبرهم ال kind triple bond
+
+241
+00:23:37,870 --> 00:23:48,130
+يعني احط C triple bond C و هنا CH3 CH3
+
+242
+00:23:48,130 --> 00:23:55,510
+و هذه H هدولة بمثابة تنتين bubble bonds هاي CH3
+
+243
+00:23:57,130 --> 00:24:02,770
+ممكن احط تنتين double bonds جانب بعض carbon double
+
+244
+00:24:02,770 --> 00:24:07,490
+bond carbon double bond carbon وهنا بدو يكون عندكم
+
+245
+00:24:07,490 --> 00:24:14,490
+CH2 CH2
+
+246
+00:24:14,490 --> 00:24:15,910
+في غير هيك؟
+
+247
+00:24:19,310 --> 00:24:23,910
+أهم شيء اللى بنى عليها هذا السؤال انه نفهم احنا ان
+
+248
+00:24:23,910 --> 00:24:31,610
+الصيغة المشبعة تماما لل C3 هي H8 الان مقابل كل
+
+249
+00:24:31,610 --> 00:24:35,990
+هيدروجينتين بخصومهم بدي اعمل double bond او حلقة
+
+250
+00:24:35,990 --> 00:24:41,170
+واضح فخصمت هيدروجنتين على كام مرة امرتين اربعة
+
+251
+00:24:41,170 --> 00:24:44,730
+تقسيم اتنين اتنين فهنا عملت حلقة و double bond هنا
+
+252
+00:24:44,730 --> 00:24:47,370
+عملت تنتين by bonds هنا عملت تنتين double bonds
+
+253
+00:24:49,120 --> 00:24:53,720
+ولما تكملوا الشكل كيميائيا شكل سليم 100% ولا لأ؟
+
+254
+00:25:08,560 --> 00:25:13,280
+الان هذا السؤال نمشي أسرع على تفاعل ال الكاينز
+
+255
+00:25:13,280 --> 00:25:17,380
+قلنا ال terminal الكاينز are acidic يعني هذا شو
+
+256
+00:25:17,380 --> 00:25:23,400
+بده يعطينا فنل C triple bond C minus الان إذا
+
+257
+00:25:23,400 --> 00:25:31,440
+فعلتوا مع إيثالبروميد CH3 CH2Br بده يعمل عليها ال
+
+258
+00:25:31,440 --> 00:25:36,890
+eucleophilic substitution هذه الكربون اتهاجمهاتطرد
+
+259
+00:25:36,890 --> 00:25:43,610
+ال PR ما هو ذا نيوكليو 5 إذا النتيجة فينيل C
+
+260
+00:25:43,610 --> 00:25:55,130
+triple bond C وهنا هياتحدت مع CH2 CH3 طردت ال PR
+
+261
+00:25:55,130 --> 00:26:02,330
+إبدالي نيوكليو فينيل الان هذا المركب مع ال lithium
+
+262
+00:26:02,330 --> 00:26:07,730
+و ال ammonia شو بيعمل؟Double bond هو اكيد بيضيف
+
+263
+00:26:07,730 --> 00:26:16,630
+الهيدروجين عكس بعض لكن مافيش فارق بالنتيجة هايو
+
+264
+00:26:16,630 --> 00:26:20,910
+الهيدروجين اللي ضفته كيف اجوا عكس بعض لكن المراكب
+
+265
+00:26:20,910 --> 00:26:26,810
+لا فيه cis ولا trans لأن هدوله زي بعض الان بعد هيك
+
+266
+00:26:26,810 --> 00:26:30,450
+هذا المراكب بتعمله اوزونوليسيز شو ال اوزونوليسيز
+
+267
+00:26:30,450 --> 00:26:35,130
+نكسر ال double bond لتنتين
+
+268
+00:26:36,290 --> 00:26:42,030
+C double bond O إذا
+
+269
+00:26:42,030 --> 00:26:47,130
+انكوّننا الألكين وبعدين كسرنا لتنتين C double bond
+
+270
+00:26:47,130 --> 00:26:48,830
+O هذا ال ozoneolysis
+
+271
+00:27:03,880 --> 00:27:10,080
+بعد هيك السؤال كيف ممكن نحضر المراكبات الآتية سيس
+
+272
+00:27:10,080 --> 00:27:15,900
+وانتو سايكلو بنتين دايول يعني
+
+273
+00:27:15,900 --> 00:27:26,420
+هنا سايكلو بنتين و OH و OH على جهة واحدة الآن أي
+
+274
+00:27:26,420 --> 00:27:32,140
+واحدة فيكوا شاطرة هتقول السيس كيف كنت أجيبه ترجع
+
+275
+00:27:32,140 --> 00:27:41,640
+برجوعالألكين مع الكيامان او فور في ال basic medium
+
+276
+00:27:41,640 --> 00:27:48,440
+او اوزميام او فور الان انا كنت حاكي هنا مابديش
+
+277
+00:27:48,440 --> 00:27:51,820
+ابدأ من ال cyclopentane مابدي ابدأ من ال promo
+
+278
+00:27:51,820 --> 00:27:58,240
+cyclopentane يعني هنا في عند بي ار الان يا تورا
+
+279
+00:27:58,240 --> 00:28:06,550
+هذه ال بي ار فيش جنب هاتشها اكيدبقدر استعمل KOH
+
+280
+00:28:06,550 --> 00:28:20,150
+بتصير ألكيل والألكيل بضيف عليه الميه starting
+
+281
+00:28:20,150 --> 00:28:29,490
+from بنزين برا نيترو كيومين هيلي
+
+282
+00:28:29,490 --> 00:28:35,410
+كيومين وحملة نيترواللي متذكرة هذي بتودي على الميتا
+
+283
+00:28:35,410 --> 00:28:39,790
+هذي Orthobara ال الكلي جروبز كلهم ال R Orthobara
+
+284
+00:28:39,790 --> 00:28:44,610
+الآن الوضع اللي موجود عندك اذا اول اشي انا بدي
+
+285
+00:28:44,610 --> 00:28:54,250
+اعمله اني بدي احضر هذا المركب وبعدين اه الان بيضل
+
+286
+00:28:54,250 --> 00:28:56,350
+ايش ال reagents ايزوبروبليكلورايد
+
+287
+00:28:56,350 --> 00:29:02,740
+ايزوبروبليكلورايد معالألمنيوميكلورايد او whatever
+
+288
+00:29:02,740 --> 00:29:11,080
+وبعدين هنا بدي اعمل نيتريشن بيطلع
+
+289
+00:29:11,080 --> 00:29:19,680
+ال ortho زائد البارا product واضح؟
+
+290
+00:29:21,290 --> 00:29:26,590
+هي الامتحان كامل مع الشريح والتفصيل الممل اعملناه
+
+291
+00:29:26,590 --> 00:29:29,350
+معاكم بطول الساعة اكيد لما يجيكوا انتوا كطلاب
+
+292
+00:29:29,350 --> 00:29:34,430
+هتاخدوا عليه ساعة لكن السؤال في حرف منه خارج عن
+
+293
+00:29:34,430 --> 00:29:37,590
+اللي درسته؟ الحمد لله ربنا
+
+294
+00:29:48,970 --> 00:29:54,650
+خلّينا نكسب الوقت و نحل امتحان من باب المراجعة
+
+295
+00:29:54,650 --> 00:29:58,030
+الشاملة
+
+296
+00:29:58,030 --> 00:30:16,490
+هذا
+
+297
+00:30:16,490 --> 00:30:27,530
+الامتحانالنمط تبعه في سؤال صح و غلط خلينا
+
+298
+00:30:27,530 --> 00:30:31,930
+نشوفه there are four types of hydrogen and
+
+299
+00:30:31,930 --> 00:30:37,170
+isobentane هذا بيستلزم ان انا اعرف ايش ال
+
+300
+00:30:37,170 --> 00:30:43,070
+isobentaneالان هاي ال eyes وبينتين كام نوع عندى من
+
+301
+00:30:43,070 --> 00:30:49,890
+ال hydrogens خلينا نقول هدول ال hydrogens زى بعض و
+
+302
+00:30:49,890 --> 00:30:59,490
+هدى و هدى و هدى نفس ايش؟ كيف؟
+
+303
+00:31:01,530 --> 00:31:06,390
+رجاءً لما بجيبلكوا سؤال ما تفكروش أنه أنواع ال
+
+304
+00:31:06,390 --> 00:31:10,970
+hydrogens أنه primary و secondary و tertiary مش
+
+305
+00:31:10,970 --> 00:31:14,590
+هذا اللي علمتكوا إياه إطلاقا، يعني من ال primary
+
+306
+00:31:14,590 --> 00:31:20,200
+ممكن يكون عندهكذا مجموعة برايمر لكن كل واحدة تمثل
+
+307
+00:31:20,200 --> 00:31:25,060
+نوع في الهيدروجينز واضح؟ عمره ماكان السؤال حددولي
+
+308
+00:31:25,060 --> 00:31:28,540
+كام نوع هيدروجينز انكوا تفكروا بكلمة برايمر و
+
+309
+00:31:28,540 --> 00:31:31,700
+سكندر و تيرتشل ولا هذا اللي علمناكم إياه يعني على
+
+310
+00:31:31,700 --> 00:31:36,520
+سبيل المثال على سبيل المثال حتى نأكد المعلومة الآن
+
+311
+00:31:36,520 --> 00:31:45,540
+لو حطيت هذا المركب هي هذه CH3 وهي هذه CH3 هذه زي
+
+312
+00:31:45,540 --> 00:31:51,700
+هذه؟لو حطيت هنا كلور بدل H من هنا زي ما حطي بدل H
+
+313
+00:31:51,700 --> 00:31:57,120
+من هنا مش كل CH3 بدي أقول عنها زي بعض ولا كل CH2
+
+314
+00:31:57,120 --> 00:32:04,380
+زي بعض لأ واضح؟ ولذلك هذا المركب الآن كام هيدروجين
+
+315
+00:32:04,380 --> 00:32:08,580
+فيه هدول المجمعتين زي بعض هي كمان نوع هي كمان نوع
+
+316
+00:32:08,580 --> 00:32:15,260
+هي كمان نوع أربع أنواع من الهيدروجين واضح؟طيب
+
+317
+00:32:15,260 --> 00:32:20,480
+احبطت شوية اتجاوزجالبة تقولي في هذا كام نوع من
+
+318
+00:32:20,480 --> 00:32:26,860
+الهيدروجين عندك؟ يعني لو قولنا لكوا برائث التلوين
+
+319
+00:32:26,860 --> 00:32:34,280
+كام نوع من الهيدروجين؟ واحد هدولة تنتين زي بعض،
+
+320
+00:32:34,280 --> 00:32:41,860
+هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول زي
+
+321
+00:32:41,860 --> 00:32:43,760
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول
+
+322
+00:32:43,760 --> 00:32:45,480
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعهتنسيش ان
+
+323
+00:32:45,480 --> 00:32:52,860
+هذه double bond ان هذه الدويرة اصلا و هدولة مافيش
+
+324
+00:32:52,860 --> 00:32:58,000
+عليهم غير مجموعة واحدة يعني انا واحد اتنين تلاتة
+
+325
+00:32:58,000 --> 00:33:02,100
+اربعة مافيش انا hydrogen فلما نكون راسمين دائرة
+
+326
+00:33:02,100 --> 00:33:05,840
+ماحدش يفكر ان هوان و هوان فيها hydrogen واضحة
+
+327
+00:33:05,840 --> 00:33:09,240
+الفكرة؟ هي اللي بيوجع الانسان في الغلط ان انا مش
+
+328
+00:33:09,240 --> 00:33:13,220
+راسم ال double bonds ان انا عامل هيك بس هذه لها
+
+329
+00:33:13,220 --> 00:33:17,180
+معنى في الكيميافما تفكروش ان هنا وهنا يوجد
+
+330
+00:33:17,180 --> 00:33:23,500
+هيدروجينز في الشكل يا
+
+331
+00:33:23,500 --> 00:33:28,780
+ريتما ماحطتش الامتحان كان جيبتي الكويزمة اه there
+
+332
+00:33:28,780 --> 00:33:33,460
+are three possible stereoisomers of 1,2
+
+333
+00:33:33,460 --> 00:33:39,460
+-dichlorobrobane الان لاحظوا بالكتورث مش شكل
+
+334
+00:33:39,460 --> 00:33:46,160
+البروبين كام كاربونتلاتة على نمرة واحد و اتنين في
+
+335
+00:33:46,160 --> 00:33:50,120
+عندى chlorine يعني هذه حملة chlorine و هذه حملة
+
+336
+00:33:50,120 --> 00:33:54,780
+chlorine لو كملنا ال hydrogens الان هنا CH2 هنا
+
+337
+00:33:54,780 --> 00:34:04,140
+CH3 الان من هذا المركب كم isomer عندى اه
+
+338
+00:34:04,140 --> 00:34:09,580
+بديش انسى ان في عندى chiral center هنا مافيش هنا
+
+339
+00:34:09,580 --> 00:34:13,940
+في chiral centerطالما عندي chiral center إذا
+
+340
+00:34:13,940 --> 00:34:23,740
+المركب و صورته إذا كام stereo isomer عند هنا الصح؟
+
+341
+00:34:23,740 --> 00:34:30,220
+نان .. نان هذا واحد اللي موجود عندكم حقيقة هو ال S
+
+342
+00:34:30,220 --> 00:34:35,900
+بتقدر ترسم صورته في المرايا ال R اللي موجود هو ال
+
+343
+00:34:35,900 --> 00:34:40,200
+S بتقدر ترسم ال R إذا هذه الجملة غلط
+
+344
+00:34:46,280 --> 00:34:53,080
+Addition of HBr Peroxide to styrene produces two
+
+345
+00:34:53,080 --> 00:34:59,040
+stereoisomers طبعا اللي مش عارف ال styrene زنبها ع
+
+346
+00:34:59,040 --> 00:35:08,500
+جنبها CH double bond CH2 لاحظوا هذا سؤال جميل لو
+
+347
+00:35:08,500 --> 00:35:13,060
+انا كنت باضيف HBr في وجود H plus هضيفه حسب قاعدة
+
+348
+00:35:13,060 --> 00:35:18,780
+Markovnikov هحط هنا ال Hوهنا ال PR وجدت في هذه
+
+349
+00:35:18,780 --> 00:35:24,080
+الحالة هعمل chiral center هنا هيطلع عندى ناتجين لو
+
+350
+00:35:24,080 --> 00:35:28,460
+أنا بضيف ال HPR في وجود H Plus هنا ال H هنا ال PR
+
+351
+00:35:28,460 --> 00:35:32,920
+إذا انا عملت chiral center لأن لما بضيف في وجود ال
+
+352
+00:35:32,920 --> 00:35:37,780
+peroxide Anti Markovnikov's addition يعني بدي ألغى
+
+353
+00:35:37,780 --> 00:35:45,050
+هذا ال double bond و أحط هنا H و هنا PRبر فيها انا
+
+354
+00:35:45,050 --> 00:35:50,050
+كايرال سنتر فيها انا كايرال سنتر اذا الكم ايزو مار
+
+355
+00:35:50,050 --> 00:35:57,430
+طلع عني واحد مش اتنين لو كنا بنضيف hbr في وجود h
+
+356
+00:35:57,430 --> 00:35:58,550
+plus بطلع اتنين
+
+357
+00:36:08,270 --> 00:36:11,910
+هذا السؤال MAI reacts with ethyl chloride
+
+358
+00:36:11,910 --> 00:36:16,410
+producing ethyl iodide لاحظوا هنا إبدال أن اليود
+
+359
+00:36:16,410 --> 00:36:23,670
+بيحل محل كلور هذه المعلومة أخدناها ولا لأ اليود
+
+360
+00:36:23,670 --> 00:36:32,630
+بيحل محل كلور و العكس مش صحيح Cyclohexanol بتكون
+
+361
+00:36:32,630 --> 00:36:37,730
+تتذكروا بمخكوا ع طول ال Cyclohexanolركزنا عليه في
+
+362
+00:36:37,730 --> 00:36:43,130
+الرسم ولا لأ؟ اللي متصل ب OH لو عملتله أكسدة شو
+
+363
+00:36:43,130 --> 00:36:52,690
+هيعمل؟ هيحذف ال H و ال H هاي الأكسدة تبعته، هاي
+
+364
+00:36:52,690 --> 00:36:57,360
+أكسدته، إيش أعطاني؟عطاني كيتون أساسا
+
+365
+00:36:57,360 --> 00:37:00,680
+الـcyclohexanol is secondary alcohol secondary
+
+366
+00:37:00,680 --> 00:37:05,420
+alcohols are oxidized to ketones وهي بالرسمة بيعطي
+
+367
+00:37:05,420 --> 00:37:13,660
+كيتون أنا كاتبلكم غلط مش الديهيد كيتون dehydration
+
+368
+00:37:13,660 --> 00:37:18,180
+of secondary butyl alcohol مرة تانية رجعنا تكونوا
+
+369
+00:37:18,180 --> 00:37:23,060
+حافظين أسماء إيش المجموعات ال secondary butyl اللي
+
+370
+00:37:23,060 --> 00:37:30,120
+حاملة هناعلى هذا الموقع وهذا لما يحمل OH سكندر
+
+371
+00:37:30,120 --> 00:37:35,020
+بيوت الالكهول طبعا ال dehydration يا ال OH من هنا
+
+372
+00:37:35,020 --> 00:37:42,620
+او من هنا اخدنا انه حسب قاعدة زي سف الحذف و more
+
+373
+00:37:42,620 --> 00:37:47,320
+substituted product will form اذا ال one butane
+
+374
+00:37:47,320 --> 00:37:51,260
+ولا ال two butane انا كاتبينلكم بشكل أساسي one
+
+375
+00:37:51,260 --> 00:37:52,820
+butane اذا خطأ
+
+376
+00:38:10,810 --> 00:38:15,070
+dichlorination of cyclobutane gives a total of
+
+377
+00:38:15,070 --> 00:38:19,310
+لحظوا ال cyclobutane بهذا الشكل بدي أضع عليه
+
+378
+00:38:19,310 --> 00:38:25,830
+مجموعتين كلور كيف ممكن أضعهم على واحد و واحد أو
+
+379
+00:38:25,830 --> 00:38:29,150
+على واحد و اتنين على واحد و اتنين بيجي ال ces و ال
+
+380
+00:38:29,150 --> 00:38:29,810
+trans
+
+381
+00:38:39,260 --> 00:38:45,180
+cyclobutane ..cyclobutane ..انا متأسف okay ..الان
+
+382
+00:38:45,180 --> 00:38:48,500
+ال ..cyclobutane ..حطوا مجموعتين كلور على واحد
+
+383
+00:38:48,500 --> 00:38:53,980
+واحد ..هذا مركب ..بعدين ع واحد و اتنين .. six و
+
+384
+00:38:53,980 --> 00:38:57,860
+trance .. بعدين ع واحد و تلاتة .. six و trance ..
+
+385
+00:38:57,860 --> 00:39:02,300
+اذا قداش المجموعة؟ خمسة ..هي نفس فكرة ال
+
+386
+00:39:02,300 --> 00:39:07,200
+..cyclobrote .. بس على أوصةThe common name of two
+
+387
+00:39:07,200 --> 00:39:19,360
+propene one all يعني هاي CH2OH CH double bond CH2
+
+388
+00:39:19,360 --> 00:39:26,160
+لحظوا هذا two propene واحد اتنين تلاتة one all هنا
+
+389
+00:39:26,160 --> 00:39:30,340
+فسرناه الآن الناس اللي متذكرة شكل المجموعة شو هي
+
+390
+00:39:30,340 --> 00:39:32,400
+الالكول
+
+391
+00:39:34,300 --> 00:39:40,940
+قلل ألكول قلل ألكول إذا كان شوكارو مستعمل لإيصال
+
+392
+00:39:40,940 --> 00:39:45,440
+حركة محركة واحدة إلكترون واحدة إلكترون فالمثال لـ
+
+393
+00:39:45,440 --> 00:39:51,880
+Cyclic Alkenes هو CNH2N-2 لاحظوا الـ Cyclic بدأ
+
+394
+00:39:51,880 --> 00:39:55,660
+أقسم جبالها اتنين من الفورمولة الأصلية والـ E بدأ
+
+395
+00:39:55,660 --> 00:40:00,400
+أقسم اتنين إذا صارت زي formula of الكائنات يعني
+
+396
+00:40:00,400 --> 00:40:08,300
+CNHتو ان ماينوس تو وبتاعة اللي عملناها مركبة زيها
+
+397
+00:40:08,300 --> 00:40:14,260
+اوزونوليسيس او سيس اوري ترانس تو بيوتين خليني
+
+398
+00:40:14,260 --> 00:40:19,860
+اخد ال سيس تو بيوتين ارسمه هان هاي ال سيس تو
+
+399
+00:40:19,860 --> 00:40:23,880
+بيوتين بدي اكسره من هان C double bond O وهذه H
+
+400
+00:40:23,880 --> 00:40:30,660
+بالتأكيدهذا C double bond OH CH3 Acetaldehyde هذا
+
+401
+00:40:30,660 --> 00:40:38,400
+C double bond OH CH3 Acetaldehyde و لل Trans هاي
+
+402
+00:40:38,400 --> 00:40:47,640
+CH3H و هنا CH3H الان اكسروا هذا من هنا و اكسروا
+
+403
+00:40:47,640 --> 00:40:53,400
+هذا من هنا و حطوا ايش Oxygen Oxygen Oxygen Oxygen
+
+404
+00:40:53,980 --> 00:40:59,480
+كل النواتج ايش؟ أسيتلديهيد بيعطي نفس الناتج
+
+405
+00:40:59,480 --> 00:41:07,000
+produces only أسيتلديهيد أو إيثانال أسيتلديهيد
+
+406
+00:41:07,000 --> 00:41:14,960
+CH3SH is more acidic than CH3OH due to size
+
+407
+00:41:17,520 --> 00:41:22,560
+سلفر مع اكسجين ايش العامل المحدد في ال acidity ال
+
+408
+00:41:22,560 --> 00:41:27,820
+size ال due to size
+
+409
+00:41:27,820 --> 00:41:34,740
+الان
+
+410
+00:41:34,740 --> 00:41:40,660
+ارسموا المراكبات التالية بدي بيوتينيعني carbon
+
+411
+00:41:40,660 --> 00:41:46,820
+تنتين تلاتة أربعة على لمرة اتنين ايش موجود عندكم؟
+
+412
+00:41:46,820 --> 00:41:56,900
+فينوكسي يعني O phenyl OH OHANA CH3 CH2 CH3 الآن
+
+413
+00:41:56,900 --> 00:42:01,120
+انا برسم المركب بعدين بشوفه اذا طلع R كان بيها
+
+414
+00:42:01,120 --> 00:42:06,970
+ماطلعش Rبعكس اي مجموع تاني الا لو جيت تطلعت عليه
+
+415
+00:42:06,970 --> 00:42:11,890
+كيف مبين هذي واحد هذي اتنين هذي تلاتة مبين اس و
+
+416
+00:42:11,890 --> 00:42:18,590
+هذي على الجانب اذا هذا فعلا الار ايزو مار عندي
+
+417
+00:42:18,590 --> 00:42:24,770
+سايكلو بنتين هاي السايكلو بنتين خليني ارسمه بهذا
+
+418
+00:42:24,770 --> 00:42:30,530
+الشكلcyclopentane واحد اتنين تلاتة اربعة خمسة على
+
+419
+00:42:30,530 --> 00:42:38,950
+نمرة تلاتة واربعة شو بدي احط كلور وكلور بالزويك
+
+420
+00:42:38,950 --> 00:42:47,010
+أسد C double bond O OH وهنا ال formal C double
+
+421
+00:42:47,010 --> 00:42:57,620
+bond OH هذا ميتاميتا أو بارا هذا موضوع بسيط هذا
+
+422
+00:42:57,620 --> 00:43:01,020
+المركب
+
+423
+00:43:01,020 --> 00:43:10,120
+Cyclopentane شو هذه المجموعة؟ Isobutyl Isobutyl
+
+424
+00:43:10,120 --> 00:43:15,680
+Cyclopentane هذا
+
+425
+00:43:15,680 --> 00:43:22,160
+كحول ألكين من وين الترقيم؟ من عند الكحول يعني هذا
+
+426
+00:43:25,670 --> 00:43:36,290
+بيوتين بيوت two in one all و إيش بيحمل بعد هى two
+
+427
+00:43:36,290 --> 00:43:43,710
+bromo فيه زده E لحظوا هنا ال brom و هنا الميثل ال
+
+428
+00:43:43,710 --> 00:43:47,270
+brom أعلى من الكربون و الميثل أعلى من ال H إذا هذا
+
+429
+00:43:47,270 --> 00:43:51,750
+E هذا أسيتوفينون
+
+430
+00:44:14,250 --> 00:44:18,730
+مش كتير معنا وقت ان شاء الله بخمس دقائق نمشي أسرع
+
+431
+00:44:18,730 --> 00:44:21,270
+بدنا خمس دقائق نمشي أسرع شوية
+
+432
+00:44:24,120 --> 00:44:30,000
+هحاول امشي بشكل سريع الان هنا في ال HBr Peroxide
+
+433
+00:44:30,000 --> 00:44:35,140
+الفكرة الأساسية اللى بتكون تعمله شو هي انت
+
+434
+00:44:35,140 --> 00:44:43,000
+Markovnikov واضح فلو انتوا جيتوا واشتغلتوا H CH3
+
+435
+00:44:43,000 --> 00:44:51,740
+CH2 هنا H هنا H وين هتحطوا ال Br وهنا
+
+436
+00:44:51,740 --> 00:44:56,880
+ال Hهي الـ Antimark of Nikon واضح؟ الان هذا لو
+
+437
+00:44:56,880 --> 00:45:00,320
+فعلته مع ال Oethel minus Can you clear your file؟
+
+438
+00:45:00,320 --> 00:45:08,700
+شو بتعمل؟ بتحيل محل لبروم يعني بتحط كل الجزيء و
+
+439
+00:45:08,700 --> 00:45:18,540
+تكتبوا هنا Oethel و لو فعلته مع ال SH minus بدنا
+
+440
+00:45:18,540 --> 00:45:26,810
+نحط كل الجزيء مرة تانيةوبنحط هنا sh ابدال يعني هذا
+
+441
+00:45:26,810 --> 00:45:30,870
+البروم بتبدل هذا عنوان chapter 6 انه البروم بتبدل
+
+442
+00:45:30,870 --> 00:45:36,310
+بال او اثل او بال sh هنا بالكئمن او فور مع ال o h
+
+443
+00:45:36,310 --> 00:45:44,090
+minus شو بدها تحط مجمعتين o h على جهة واحدة بال
+
+444
+00:45:44,090 --> 00:45:50,730
+ozonolysis بدوا يعمل تلتين c double point o بتكمل
+
+445
+00:45:50,730 --> 00:45:58,340
+الجزيةبالميه هذه بتضيف حسب قاعدة Markovnikov
+
+446
+00:45:58,340 --> 00:46:03,220
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+447
+00:46:03,220 --> 00:46:07,800
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+448
+00:46:07,800 --> 00:46:07,980
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+449
+00:46:07,980 --> 00:46:09,020
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+450
+00:46:09,020 --> 00:46:09,960
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+451
+00:46:09,960 --> 00:46:20,320
+اتش اتش اتش اتش اتش اتش اتش اتش
+
+452
+00:46:20,320 --> 00:46:22,320
+ات
+
+453
+00:46:33,790 --> 00:46:41,490
+أخر شغلة الأفكار الأساسية هنا إضافة ميه وبعدين
+
+454
+00:46:41,490 --> 00:46:47,110
+توتوميرزم متذاكرينها ال
+
+455
+00:46:47,110 --> 00:46:54,030
+ISOبنتين هي ال ISOبنتين اعملولها إكلوريناشن توي
+
+456
+00:46:54,030 --> 00:47:01,240
+حكينا كام موقع فيها؟واحد اتنين تلاتة اربعة لما
+
+457
+00:47:01,240 --> 00:47:05,440
+احطولكوا all possible monochlorination products
+
+458
+00:47:05,440 --> 00:47:10,700
+انتبهوا معي لما احط كلور هان و هان هذا ناتج و اذا
+
+459
+00:47:10,700 --> 00:47:13,740
+حطيت هان هذا ناتج هذا فيش فيه chiral center هذا
+
+460
+00:47:13,740 --> 00:47:17,500
+فيش فيه chiral center لو حطيت هان CH2Cl فيش فيه
+
+461
+00:47:17,500 --> 00:47:23,210
+chiral center لو حطيت هانأتش و CL في كايرالسنتر
+
+462
+00:47:23,210 --> 00:47:27,430
+هدا بده يطلع منه كام واحد اتنين اذا المجموع كده؟
+
+463
+00:47:27,430 --> 00:47:32,890
+خمسة product لما ادخل ال stereo isomers هذه النقطة
+
+464
+00:47:32,890 --> 00:47:38,510
+تحديدا بحط فيها ال H و ال CL يعني الناتجين اللي
+
+465
+00:47:38,510 --> 00:47:44,450
+بدهم يكونوا هنا لو رسمت الناتج و صورته في المرايا
+
+466
+00:47:44,450 --> 00:47:52,680
+بدكوا تكونوا حاطين هنا مثلاH و CH3 و CL وهنا تحطوا
+
+467
+00:47:52,680 --> 00:48:02,100
+CL و H و CH3 الناتج و صورته في المرأة واضح
+
+468
+00:48:02,100 --> 00:48:06,300
+الناتج و صورته في المرأة هذوله اتنين و بعدين
+
+469
+00:48:06,300 --> 00:48:09,920
+بتحطوا هن واحد و هن واحد و هن واحد المجموع كده؟
+
+470
+00:48:09,920 --> 00:48:17,300
+خمسة خمسة بقى لعنا اتنين صغار كتير
+
+471
+00:48:25,790 --> 00:48:29,490
+isopropylacetophenon الفكرة فقط انكوا تعرفوا مين
+
+472
+00:48:29,490 --> 00:48:34,550
+بده احطها في الأول انهي المجموعة اللي بتلحط نمرا
+
+473
+00:48:34,550 --> 00:48:42,090
+واحد ال isopropyl ال isopropyl orthopara ال
+
+474
+00:48:42,090 --> 00:48:46,290
+isopropyl orthopara directing و بعدين ال
+
+475
+00:48:46,290 --> 00:48:47,270
+acetophenon
+
+476
+00:48:49,330 --> 00:48:54,330
+Cl ألمنيوم كلورايد و هنا ايزو بروبل كلورايد
+
+477
+00:48:54,330 --> 00:49:02,530
+ألمنيوم كلورايد أخر سؤال سيث ثريهكسيني من ون
+
+478
+00:49:02,530 --> 00:49:07,430
+بيوتايل لاحظوا هذا ال ون بيوتايل بهذا الشكل CH3
+
+479
+00:49:07,430 --> 00:49:15,670
+CH2 C triple bond CH من أربعة بده أحضر ستة
+
+480
+00:49:15,670 --> 00:49:17,890
+ملاحظين؟
+
+481
+00:49:18,690 --> 00:49:24,670
+من الأربعة شو بده احضر؟ ستة كيف بده اعمل هذا
+
+482
+00:49:24,670 --> 00:49:31,470
+الكلام؟ اول اشي بده ازيد ذاتين carbon فانا لو فعلت
+
+483
+00:49:31,470 --> 00:49:38,380
+مع ال NANH2 نمرة واحد خلت هذه minusو بعدين نمرة
+
+484
+00:49:38,380 --> 00:49:44,540
+اتنين فعلتها مع إثيل بروميد CH3 CH2Br ال minus
+
+485
+00:49:44,540 --> 00:49:48,760
+اللي بيحجم على ال PR و أجتها بيصير عندي هذا ال
+
+486
+00:49:48,760 --> 00:49:56,140
+كائن CH3 CH2 C triple bond C وهي ال إثيل اللي أنا
+
+487
+00:49:56,140 --> 00:50:04,950
+حطيتها CH2 CH3 الان من هذه بدي أخليهاالكين
+
+488
+00:50:04,950 --> 00:50:09,090
+والالكين يكون إيش؟ SES كيف بحول ال triple bond
+
+489
+00:50:09,090 --> 00:50:18,610
+لالكين SES؟ H2 Lendlers Catalyst Lendlers Catalyst
+
+490
+00:50:18,610 --> 00:50:24,350
+إذا هذا السؤال فيه فكرتين أساسيات الفكرة الأولى أن
+
+491
+00:50:24,350 --> 00:50:28,010
+ال terminal alkyl بيصير نيوكليوفايل ممكن يعمل
+
+492
+00:50:28,010 --> 00:50:34,070
+إبدال علىالكالهلايد كبرت السلسلة و بعدين ل triple
+
+493
+00:50:34,070 --> 00:50:38,010
+bond ان اخليها cis او trans اخدته قولت انا ل
+
+494
+00:50:38,010 --> 00:50:43,470
+triple bond يا بخليها الكن يا cis الكن يا trans
+
+495
+00:50:43,470 --> 00:50:48,590
+الكن كل واحدة في إلها شروط معينة ابقى اك تقريبا
+
+496
+00:50:48,590 --> 00:50:53,810
+بنكون غطينا يعني باسئلة مختلفة معظم الأشياء اللي
+
+497
+00:50:53,810 --> 00:50:57,490
+درسناها و بنتمنالكوا ان شاء الله النجاح و التوفيق
+
+498
+00:50:57,490 --> 00:50:59,050
+في الامتحان اللي بدكنوا تقدموه
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b1ff61fb564655edd9f3fec95105a569bd4a5b59
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/635vH7PE99A_raw.srt
@@ -0,0 +1,2012 @@
+1
+00:00:20,330 --> 00:00:25,410
+بسم الله الرحمن الرحيم اليوم ان شاء الله درسنا مش
+
+2
+00:00:25,410 --> 00:00:30,670
+في موضوع معين لأ هو مراجعة شاملة من خلال حل
+
+3
+00:00:30,670 --> 00:00:36,320
+الامتحانات السابقة استعدادا للامتحانالنصفي ربما
+
+4
+00:00:36,320 --> 00:00:40,320
+أحيانا اتلاحظوا بعض الأسئلة لامتحان النصفي كان
+
+5
+00:00:40,320 --> 00:00:44,380
+للفصل السابع المرة هذه طلبنا منكوا للفصل السادس
+
+6
+00:00:44,380 --> 00:00:49,160
+فمش مشكلة يعني الإنسان بيقدر يعرف الأسئلة هتلاحظوا
+
+7
+00:00:49,160 --> 00:00:54,980
+ان في عندنا أسئلة متنوعة بشكل عام دائما ننصح
+
+8
+00:00:54,980 --> 00:01:01,250
+الطلاب انه يهتموابالأفكار الأساسية العامة يكونوا
+
+9
+00:01:01,250 --> 00:01:06,030
+فاهمينها بنسبة أكبر هذا بمنعش أنه في أشياء متخصصة
+
+10
+00:01:06,030 --> 00:01:09,730
+لكن دائما الطالب أول شيء يجب أن يكون عنده يعني
+
+11
+00:01:09,730 --> 00:01:14,190
+قناع أن هو فاهم الاشي الأفكار العامة ولذلك ربما
+
+12
+00:01:14,190 --> 00:01:19,110
+تلاحظوا أنه يعني لو أنا بدأ أصنف الأسئلة مش في هذا
+
+13
+00:01:19,110 --> 00:01:24,450
+الامتحان في معظم الامتحانات هنكتشف أنه هي عنوين
+
+14
+00:01:25,470 --> 00:01:30,250
+يعني هي عنوين لأشياء احنا درسناها خلينا نشوف هذا
+
+15
+00:01:30,250 --> 00:01:35,710
+الكلام من خلال التطبيق الآن في هذا الامتحان اللي
+
+16
+00:01:35,710 --> 00:01:41,350
+أمامنا في عندنا مجموعة من الجمال هذه المجموعة من
+
+17
+00:01:41,350 --> 00:01:46,450
+الجمال بدنا نكمل الفراغ فيها complete the
+
+18
+00:01:46,450 --> 00:01:50,450
+following السؤال أول مثلا بيسألنا الدياستيريو
+
+19
+00:01:50,450 --> 00:01:55,210
+مارزهاف و بيحكي عن ال physical propertiesالان كان
+
+20
+00:01:55,210 --> 00:01:58,970
+واضح تماما ان ال بيستيريو مارز هيف different
+
+21
+00:01:58,970 --> 00:02:02,390
+physical
+
+22
+00:02:02,390 --> 00:02:10,670
+properties واضح الان السؤال التاني addition of HBr
+
+23
+00:02:10,670 --> 00:02:17,410
+H plus to isobutene produces لاحظوا هنا السؤال هذا
+
+24
+00:02:17,410 --> 00:02:22,070
+في فكرتين ان الطالب لازم في الأول يعرف ايش هو ال
+
+25
+00:02:22,070 --> 00:02:28,970
+isobuteneهذا ال isobutene واضح بعد هيك إضافة ال
+
+26
+00:02:28,970 --> 00:02:35,930
+HBR H plus معناه ذلك هذه إضافة حسب Markov-Nikov
+
+27
+00:02:35,930 --> 00:02:40,670
+addition يعني هذه بدها تروح يجي عند هنا H و يجي
+
+28
+00:02:40,670 --> 00:02:44,070
+عند هنا CL او PR و بنحكي عن PR
+
+29
+00:02:47,350 --> 00:02:53,650
+الان هذا المركب اللى طلع عندى carbon حاملة CH3 CH3
+
+30
+00:02:53,650 --> 00:03:01,230
+CH3Br هذه مجموعة لها اسم ولا لأ تيرتشاري بيوتل
+
+31
+00:03:01,230 --> 00:03:09,310
+إبرومايد produces tertiary butyl bromide من تسمية
+
+32
+00:03:09,310 --> 00:03:16,810
+المجموعات produces tertiary butyl bromideالان فكرة
+
+33
+00:03:16,810 --> 00:03:20,890
+عامة قلنا ال branched alkanes اللي هم ال boiling
+
+34
+00:03:20,890 --> 00:03:23,930
+point و ال melting point lower than ال chain
+
+35
+00:03:23,930 --> 00:03:28,390
+alkanes الان ال branched alkanes هم اكيد هنا هتكون
+
+36
+00:03:28,390 --> 00:03:32,110
+higher او lower boiling point than the
+
+37
+00:03:32,110 --> 00:03:37,890
+corresponding chain lower ال
+
+38
+00:03:37,890 --> 00:03:44,850
+curved arrows قلنا عنهمالهم رأسين are used to
+
+39
+00:03:44,850 --> 00:03:53,830
+indicate the movement of two electrons ممتاز ال
+
+40
+00:03:53,830 --> 00:04:00,350
+reaction المهم من البنزين هو أي تحديد تحديد
+
+41
+00:04:00,350 --> 00:04:07,070
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+42
+00:04:07,070 --> 00:04:10,130
+الهواتف الهواتف
+
+43
+00:04:10,130 --> 00:04:10,910
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+44
+00:04:10,910 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+45
+00:04:11,090 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+46
+00:04:11,090 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+47
+00:04:11,090 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف ال
+
+48
+00:04:11,810 --> 00:04:24,490
+الكلهيليتز اليوكليوفيليك اليوكليوفيليك
+
+49
+00:04:28,790 --> 00:04:33,570
+Dipromination of a Neopentane gives a total of ..
+
+50
+00:04:33,570 --> 00:04:38,110
+لاحظوا معي تكونوا عارفين لـ Neopentane يعني أنا
+
+51
+00:04:38,110 --> 00:04:41,950
+هنا باختبركم أن تكونوا عارفين هذا المُركّب لـ
+
+52
+00:04:41,950 --> 00:04:45,470
+Neopentane اللي هي الكربون اللي حاملة كام مثل؟
+
+53
+00:04:45,470 --> 00:04:49,910
+أربعة الأربعة الأربعة دي دي Dipromination
+
+54
+00:04:51,580 --> 00:04:57,320
+يعني احض ذرتين abroad كم ناتج بتوقع التنتين ممكن
+
+55
+00:04:57,320 --> 00:05:00,880
+ييجوا على نفس الذرع اذا اجوا تنتين هان زي هان زي
+
+56
+00:05:00,880 --> 00:05:08,060
+هان و ممكن ييجوا علىدرتين مختلفتين يعني ايه ييجي
+
+57
+00:05:08,060 --> 00:05:12,460
+هان و هان لحظوا هان و هان زي هذه و هذه زي هذه و
+
+58
+00:05:12,460 --> 00:05:15,860
+هذه زي هذه و هذه لأن المجموعات كلها ماخدة
+
+59
+00:05:15,860 --> 00:05:19,140
+tetrahedral arrangement متذكرين لما كنا نقول مافيش
+
+60
+00:05:19,140 --> 00:05:23,100
+اشي اسمه مجموعتين جان بعض و اشي اسمه مجموعتين قبال
+
+61
+00:05:23,100 --> 00:05:27,280
+بعض يعني تيجي طالبة تقول حط ال .. البروم هان و هان
+
+62
+00:05:27,280 --> 00:05:30,860
+بتختلف عن البروم هان و هان لأ هذه الزاوية PR, CPR
+
+63
+00:05:30,860 --> 00:05:37,280
+قداش مقدارهامية و تسعة و نص كربون حملة PR كربون كم
+
+64
+00:05:37,280 --> 00:05:40,640
+.. كربون حملة PR كدهش مقدارها؟ مية و تسعة و نص إذا
+
+65
+00:05:40,640 --> 00:05:45,260
+كم ناتج هنا؟ أربعة ليش أربعة؟ مش هو two bromine
+
+66
+00:05:45,260 --> 00:05:50,800
+atoms طيب انا .. انا حطيت two bromine atoms أو
+
+67
+00:05:50,800 --> 00:05:53,720
+حطيت وحدها وحدها هاي معناه die bromination طيب و
+
+68
+00:05:53,720 --> 00:05:57,100
+لو حطنا على ال carbon نفل نص ال carbon نفل نص
+
+69
+00:05:57,100 --> 00:05:58,540
+بيصير على خمس روابط؟
+
+70
+00:06:01,850 --> 00:06:05,670
+يا التنتين على هذه الذرة، يا التنتين كل واحدة على
+
+71
+00:06:05,670 --> 00:06:11,690
+ذرة، سواء كانت هان أو هان أو هان، إذا كان مركب two
+
+72
+00:06:11,690 --> 00:06:15,910
+isomers، structural isomers of course
+
+73
+00:06:18,990 --> 00:06:24,790
+The IUPAC name of allyl chloride لاحظوا كام سؤال
+
+74
+00:06:24,790 --> 00:06:28,970
+صار جايكم اؤكد انكوا تكونوا عارفين المجموعات
+
+75
+00:06:28,970 --> 00:06:32,150
+والمركبات الأساسية اللي أخدناها جيبنا ال tertiary
+
+76
+00:06:32,150 --> 00:06:38,430
+butyl هاي جيبنا ال allyl اللي هي CH2 CH double
+
+77
+00:06:38,430 --> 00:06:44,770
+bond CH2 Hanachlor وقولنا سابقا ان هذا بدو يتسمى
+
+78
+00:06:44,770 --> 00:06:53,810
+واحد اتنينتلاتة اذا three chloro one
+
+79
+00:06:53,810 --> 00:07:04,450
+propene three chloro one propene واضح؟
+
+80
+00:07:04,450 --> 00:07:09,150
+فحفظ المجموعات بين القليل ايزو بروبيل ايزو بيوتل
+
+81
+00:07:09,150 --> 00:07:13,250
+اساسي جداgeneration of the second chiral center
+
+82
+00:07:13,250 --> 00:07:19,290
+produces unequal mixture of diastereomers هذا أكمل
+
+83
+00:07:19,290 --> 00:07:26,470
+الجواب، هيك العنوان صح ولا لأ؟ unequal mixture of
+
+84
+00:07:26,470 --> 00:07:32,470
+diastereomers والfirst
+
+85
+00:07:32,470 --> 00:07:36,350
+chiral center شو كان بيعمل؟ racemic mixture of
+
+86
+00:07:36,350 --> 00:07:42,090
+enantiomers the meso compound is opticallyinactive
+
+87
+00:07:42,090 --> 00:07:47,630
+كان عنوان meso compounds are optically inactive
+
+88
+00:07:47,630 --> 00:07:54,790
+واضح هي دي مراجعة شاملة خلينا نقوله بعتقد جميلة
+
+89
+00:07:54,790 --> 00:07:59,930
+لمفاهيم أساسية أخدناها واضحة
+
+90
+00:08:12,680 --> 00:08:18,980
+الان بعد هيك ارسمولنا أشكال بعض المركبات
+
+91
+00:08:18,980 --> 00:08:22,000
+Cyclobentane
+
+92
+00:08:22,000 --> 00:08:26,500
+مين ما بيعرفوا ال Cyclobentane؟ هاي ال
+
+93
+00:08:26,500 --> 00:08:30,500
+Cyclobentane أسس على نمرة واحد و تلت يعني لو قولنا
+
+94
+00:08:30,500 --> 00:08:38,230
+هنا مثلا خلينا نحط إبروم للأمام وهنابروم هاي واحد
+
+95
+00:08:38,230 --> 00:08:43,990
+اتنين تلاتة وستعملنا
+
+96
+00:08:43,990 --> 00:08:51,070
+الشكل الفراغي عشان نبين انه مجموعتين للامام الان
+
+97
+00:08:51,070 --> 00:08:58,450
+Cyclohexane نعرف ال Cyclohexane هاي Cyclohexane
+
+98
+00:08:58,450 --> 00:09:03,980
+والترقيم بيكون واحدتنين و نستمر نمر عبر ال double
+
+99
+00:09:03,980 --> 00:09:09,280
+bond صح ولا لأ يعني واحد اتنين تلاتة اربعة خمسة
+
+100
+00:09:09,280 --> 00:09:12,280
+ستة الان على نمرة اتنين ايش في اندي في ال
+
+101
+00:09:12,280 --> 00:09:24,860
+Cyclohexane بروم وعلى نمرة تلاتة isopropyl for
+
+102
+00:09:24,860 --> 00:09:32,020
+nitroicumin اخدنا الاكيومين انه ال isopropylبنزين
+
+103
+00:09:32,020 --> 00:09:38,360
+قلنا ايزوبروب البنزين is كيومين لما بتحط على
+
+104
+00:09:38,360 --> 00:09:49,060
+الأربعة ن او اتو for نيترو كيومين الان المركب هذا
+
+105
+00:09:49,060 --> 00:09:54,420
+بدنا نسميه اين و اين ضايقين
+
+106
+00:09:55,420 --> 00:10:01,040
+لما بدنا ننتبه من وين بدنا نعمل الترقيم يعني واحد
+
+107
+00:10:01,040 --> 00:10:06,460
+اتنين تلاتة اربعة خمسة و هنا في كمان carbon ستة
+
+108
+00:10:06,460 --> 00:10:10,840
+طبعا لاحظوا انه انا لو برقم من هنا بيكون double
+
+109
+00:10:10,840 --> 00:10:16,120
+points عند اتنينوخمسة لو برقم هنا عند واحد اتنين
+
+110
+00:10:16,120 --> 00:10:19,860
+واحد واربعة لازم اسعى ان ال double poles يكونوا
+
+111
+00:10:19,860 --> 00:10:25,160
+اقل ترقيم اذا هذا هقول واحد اتنين تلاتة اربعة خمسة
+
+112
+00:10:25,160 --> 00:10:33,960
+ستة فهذا المركب هيكون one four hexadien
+
+113
+00:10:33,960 --> 00:10:41,370
+ايش بيحمل على نمرة تلاتة وعلى نمرة اربعةأه إذا هذا
+
+114
+00:10:41,370 --> 00:10:49,490
+كمان بدو ييجي عليه three four diapromo one four
+
+115
+00:10:49,490 --> 00:10:55,660
+الآن هذا double bondمافيش عليها مجموعات مختلفان و
+
+116
+00:10:55,660 --> 00:10:58,500
+.. يعني مافيش فيها ظاهرة ال sexual trance بس هذا
+
+117
+00:10:58,500 --> 00:11:02,700
+ال double bond فيها .. يعني هنا في عندى مثل و أتش،
+
+118
+00:11:02,700 --> 00:11:07,040
+لاحظوا كل رأس زي هذا يعتبر مثل، انتبهوله في العد و
+
+119
+00:11:07,040 --> 00:11:12,110
+انتبهوله لما تشتغلوا، المثل أعلى من الأتشالمثل
+
+120
+00:11:12,110 --> 00:11:17,350
+أعلى من الـ H هنا PR و Carbon أنا باطلع فقط على
+
+121
+00:11:17,350 --> 00:11:20,470
+الذرة الأولى و الأولى هذه PR وهذه Carbon الآن
+
+122
+00:11:20,470 --> 00:11:25,410
+هذولا المجمعتين على جهة واحدة إذا هذا المركب Z
+
+123
+00:11:25,410 --> 00:11:31,610
+فلما بدي تسمية كاملة Z three four dibromo one four
+
+124
+00:11:31,610 --> 00:11:33,050
+hexadien
+
+125
+00:11:35,670 --> 00:11:38,790
+واضح؟ ال double bond التانية مافيش فيها أي شيء
+
+126
+00:11:38,790 --> 00:11:42,490
+طبعا واضح أنه هنا في chiral center لكن طالما أنا
+
+127
+00:11:42,490 --> 00:11:47,010
+ماحطتوش على شكل صليب معناه ذلك أنا مش مركز أني
+
+128
+00:11:47,010 --> 00:11:54,470
+اتحددولي IR أو استركتو مفتوح هذا المركب مثلا في
+
+129
+00:11:54,470 --> 00:11:58,330
+chiral center وموضح أنه أنا طالب ال chiral center
+
+130
+00:11:58,330 --> 00:12:06,270
+هنا واضح؟ لو أتيت طلعت أطول سلسلةانعلمها بالاحمر
+
+131
+00:12:06,270 --> 00:12:14,430
+واحد اتنين تلاتة اربعة اذا هذا بيوتين ايش بيحمل
+
+132
+00:12:14,430 --> 00:12:19,450
+هذا البيوتين على البيوتين واحد اتنين تلاتة اربعة
+
+133
+00:12:19,450 --> 00:12:26,870
+على نمرة واحد اكلور وعلى نمرة تلاتة فنل والترقيم
+
+134
+00:12:26,870 --> 00:12:29,770
+منها لان لو رقمتي منها هيصيروا على اتنين واربعة
+
+135
+00:12:29,770 --> 00:12:38,510
+بدي ال lower numbering اذا هذاone chloro three
+
+136
+00:12:38,510 --> 00:12:47,330
+phenyl بيوتين الان في chiral center ال chiral
+
+137
+00:12:47,330 --> 00:12:53,370
+center هنا ال H أقل مجموعة أكيد البنزينة نمرة واحد
+
+138
+00:12:53,370 --> 00:13:00,310
+الكاربون هذه نمرة اتنين وال CH3 نمرة تلاتةواحد
+
+139
+00:13:00,310 --> 00:13:06,870
+اتنين تلاتة وهذه موجودة اذا هذا اس one chlorine
+
+140
+00:13:06,870 --> 00:13:08,750
+three phenyl butane
+
+141
+00:13:15,300 --> 00:13:19,960
+المُركّب اللي بعده aromatic فيه مجموعتين، معنا ذلك
+
+142
+00:13:19,960 --> 00:13:24,020
+السؤال إنه مين أعلى في الأولوية عشان أسمه إيه؟ ال
+
+143
+00:13:24,020 --> 00:13:27,600
+ketone ولا ال alcohol؟ ال ketone، الآن هذا
+
+144
+00:13:27,600 --> 00:13:32,320
+المُركّب إيش اسمه؟ أسيتوفينون، نكتب small letter
+
+145
+00:13:34,690 --> 00:13:40,030
+acetophenon ال O H بترجع على أصلها ال three one
+
+146
+00:13:40,030 --> 00:13:45,710
+two three ال three أو ميتا هيدروكسي الشغلتين صح ال
+
+147
+00:13:45,710 --> 00:13:50,470
+three هيدروكسي أسيتوفينون كلمة واحدة واضح ال three
+
+148
+00:13:50,470 --> 00:13:57,030
+هيدروكسي أسيتوفينون بتيعني كل هذه من ضمن الأفكار
+
+149
+00:13:57,030 --> 00:14:01,610
+العامة الأساسية اللي احنا درسناكم
+
+150
+00:14:18,380 --> 00:14:25,580
+الان بعد ذلك عندى اكمال معادلات هذا المركب مثل
+
+151
+00:14:25,580 --> 00:14:32,160
+Cyclopropane مثل Cyclopropane وحطينا لكوا بدنا
+
+152
+00:14:32,160 --> 00:14:37,020
+نشوف all structural isomers يعني مش مركز انا على
+
+153
+00:14:37,020 --> 00:14:40,720
+ال stereo isomers او اعمله monochlorination يعني
+
+154
+00:14:40,720 --> 00:14:46,860
+احط one chlorine atomواضح؟ وين بده احط هذه ال
+
+155
+00:14:46,860 --> 00:14:55,400
+chlorine طبعا هنبدأ نرسم اكثر من شكل مش عارف تلاتة
+
+156
+00:14:55,400 --> 00:14:59,900
+اربعة بنجرب احنا الان اكيد ال chlorine بإمكانها
+
+157
+00:14:59,900 --> 00:15:06,810
+تيجي هنا على المثلوأكيد ال chlorine بإمكانها تيجي
+
+158
+00:15:06,810 --> 00:15:11,250
+على هذا الموقع وأكيد ال chlorine بإمكانها تيجي على
+
+159
+00:15:11,250 --> 00:15:15,510
+هذا الموقع لأن هذا و هذا زي بعض، ضال عندكم إشي
+
+160
+00:15:15,510 --> 00:15:21,170
+تاني؟ خلاص وكل
+
+161
+00:15:21,170 --> 00:15:23,210
+واحد فيهم أكيد إله اسم مختلف
+
+162
+00:15:29,980 --> 00:15:35,600
+الان لاحظوا معي هذا المركب فيه double bond بنقول
+
+163
+00:15:35,600 --> 00:15:40,880
+في نمر واحد بدنا نضيف عليه pear acid ايش معناه
+
+164
+00:15:40,880 --> 00:15:48,260
+pear acid انه بده يلغي هذه و يعملي حلقة لكن انا
+
+165
+00:15:48,260 --> 00:15:53,160
+كمان بعد ما عملت هذه الحلقة بده اعمل ring opening
+
+166
+00:15:53,160 --> 00:15:59,920
+ضيفت ميهواضحة الفكرة؟ كيف هذي بتعمل ring opening؟
+
+167
+00:15:59,920 --> 00:16:07,240
+بيكونوا سن ولا أنتي؟ مجموعات ال OHS ال
+
+168
+00:16:07,240 --> 00:16:10,360
+ring opening من البرأس الانتي
+
+169
+00:16:12,610 --> 00:16:17,550
+هي الميه من وين بتيجي عكس هذه اللي كان يعمل sin
+
+170
+00:16:17,550 --> 00:16:22,350
+addition لمجموعتين OH الكيامان O4 والأزوميوم O4
+
+171
+00:16:22,350 --> 00:16:27,590
+أخدناهم بيعملوا sin addition لمجموعتين OH لكن بهذه
+
+172
+00:16:27,590 --> 00:16:31,890
+الطريقة بنطلع ال Anti product اللي كان واضح تماما
+
+173
+00:16:31,890 --> 00:16:37,350
+يعني بدكوا تحطوا OH على جهة و OH على الجهة التانية
+
+174
+00:16:37,350 --> 00:16:42,720
+بالتأكيد هنا هتكون هذه المجموعة هيكهيأجوا اشمالهم
+
+175
+00:16:42,720 --> 00:16:47,880
+انتي طبعا
+
+176
+00:16:47,880 --> 00:16:51,600
+اي واحدة متذاكرة جيدا مش ضروري تفكر تعمل زي هيك
+
+177
+00:16:51,600 --> 00:16:54,900
+خلاص هو ال bare acid و بعدين نعمل ring opening في
+
+178
+00:16:54,900 --> 00:17:00,660
+الميه هذا محصلته في الدماغ بيحط مجمعتين OH انتي
+
+179
+00:17:00,660 --> 00:17:09,120
+انتي طبعا الان لما نضيف H2 في وجود platinum
+
+180
+00:17:20,030 --> 00:17:25,790
+هذا المُركّب اللي فيه ال PR لحظة انا هنا حاططلكم
+
+181
+00:17:25,790 --> 00:17:29,290
+KOH و جايلكم ان انا بدي ال major elimination
+
+182
+00:17:29,290 --> 00:17:33,950
+product كأني بقول انو حطوا double bond هان او هان
+
+183
+00:17:33,950 --> 00:17:39,750
+واضح انه كتير ركزنا معاكم انه the more substituted
+
+184
+00:17:39,750 --> 00:17:44,710
+ال keenوالـ Form حسب قاعدة Zaitsev إذا هنا بدو
+
+185
+00:17:44,710 --> 00:17:52,170
+ييجي ال الـ K واضح؟ مش هتيجي ال PR مع هذه ال H لأن
+
+186
+00:17:52,170 --> 00:17:56,530
+هذا less substituted ال K هذا ال more substituted
+
+187
+00:17:56,530 --> 00:18:00,890
+الآن بعد هيك هذا المركب بدنا نضيف عليه ميا في وجود
+
+188
+00:18:00,890 --> 00:18:06,590
+H plus هذا إضافة Markovnikov لحظة هنا في carbon
+
+189
+00:18:06,590 --> 00:18:12,190
+تحمل H و هذه ال carbon لأ تحملش H إذالو حطينا
+
+190
+00:18:12,190 --> 00:18:19,390
+الشكل العام بس بتكون المشكلة وين أحط ال H وين أحط
+
+191
+00:18:19,390 --> 00:18:30,150
+ال OH حسب
+
+192
+00:18:30,150 --> 00:18:36,430
+قاعدة Markovnikov لأنه في الأساس هنا في عندكم H
+
+193
+00:18:36,430 --> 00:18:38,650
+اللي كانت متروكة فاضية
+
+194
+00:18:56,340 --> 00:19:03,760
+الان هنا بدنا نضيف HPR في وجود البروكسايد اذا هنا
+
+195
+00:19:03,760 --> 00:19:09,600
+الإضافة مع ولا عكس قاعدة Markovnikov عكس قاعدة
+
+196
+00:19:09,600 --> 00:19:15,520
+Markovnikov لاحظوا لما انا هنا بد اضيف H على هذه
+
+197
+00:19:15,520 --> 00:19:21,870
+الجهة و ال PR على اللي بتحمل Hانتبهوا معي ال H هنا
+
+198
+00:19:21,870 --> 00:19:26,350
+طالما عندكم مثل و مثل ماعملتش chiral center هنا
+
+199
+00:19:26,350 --> 00:19:30,390
+لأن هدول المجموعتين زي بعض يعني مافيش اد اربع
+
+200
+00:19:30,390 --> 00:19:35,850
+مجموعات مختلفة لكن هنا بدي يكون عندكم مثل و H و
+
+201
+00:19:35,850 --> 00:19:44,410
+هتيجيها ب Rهي مثل وهي H و إيش هيجي عندك PR في هذه
+
+202
+00:19:44,410 --> 00:19:50,450
+الحالة حيصير في كايرال سنتر على هذا الكربون الان
+
+203
+00:19:50,450 --> 00:19:56,410
+ال generation و في كايرال سنتر شو بيطلعلك رسمك
+
+204
+00:19:56,410 --> 00:20:01,550
+mixture كان هذا عنوان إذا انا لما بدي أجي أشتغل
+
+205
+00:20:01,550 --> 00:20:07,250
+الأصل بدي أشتغل بهذا الشكلهدولة بأي طريقة تكتبوها
+
+206
+00:20:07,250 --> 00:20:10,370
+مافيش فيها مشكلة إطلاقا لأنه مش chiral center في
+
+207
+00:20:10,370 --> 00:20:14,410
+النهاية يعني
+
+208
+00:20:14,410 --> 00:20:19,050
+لو كتبيه بأي طريقة مش مشكلة لكن هنا بدي أجي مثلا
+
+209
+00:20:19,050 --> 00:20:25,470
+أقول ال PR هان ال PR عكسها ممكن نكتب ال H و ال H و
+
+210
+00:20:25,470 --> 00:20:30,710
+نكتبالـ CH3 والـ CH3 أهم شيء نعمله .. أهم شيء
+
+211
+00:20:30,710 --> 00:20:38,610
+نعمله أن هذه المنطقة يكونوا هذولة أشملهم عكس بعض و
+
+212
+00:20:38,610 --> 00:20:42,330
+هذولة بيطلعوا ال 50 50 ratio
+
+213
+00:20:44,190 --> 00:20:47,510
+الان بأي طريقة تكتبوها مافيش مشكلة مش هيكون خلاف
+
+214
+00:20:47,510 --> 00:20:51,270
+يعني واحدة كتبت هنا PR و هنا CH3 و هنا H و عملت
+
+215
+00:20:51,270 --> 00:20:54,770
+صورتها مش مشكلة واحدة كتبت هنا CH3 و هنا H و هنا
+
+216
+00:20:54,770 --> 00:21:01,330
+PR مافيش مشكلة اهم يعني ارسموا التلاتة بأي شكل
+
+217
+00:21:01,330 --> 00:21:06,150
+بدكم إياه بس حطوا صورتهم في المرايا لو احنا نفس
+
+218
+00:21:06,150 --> 00:21:08,930
+الشكل بس شيلنا لابتا ثنائية و حاطينا ال PR هيك و
+
+219
+00:21:08,930 --> 00:21:10,770
+هيك وين تحط ال PR؟
+
+220
+00:21:25,670 --> 00:21:29,510
+الان السؤال اللي بعده draw all the possible
+
+221
+00:21:29,510 --> 00:21:34,870
+isomers having the formula C3H4
+
+222
+00:21:35,800 --> 00:21:41,180
+الان عندما تفكر في هذا الكلام تفكر في صيغة العامة
+
+223
+00:21:41,180 --> 00:21:52,320
+للمركبات الوضع الطبيعي ال C3 بتاخد HS في
+
+224
+00:21:52,320 --> 00:21:59,470
+الألكال اللي كله single bonds يعني ال C3H8 في
+
+225
+00:21:59,470 --> 00:22:07,170
+الالكينز صح؟ الان اذا شيلت منها هيدروجينتين صارت
+
+226
+00:22:07,170 --> 00:22:12,870
+C3H6 مقابل ان شيلتم يا عملت bubble bond يا حلقة
+
+227
+00:22:12,870 --> 00:22:17,910
+الان لسه انا مش بس هيدروجنتين بده اشيل كمان تنتين
+
+228
+00:22:17,910 --> 00:22:22,690
+يعني شيلت هيدروجنتين وكمان هيدروجنتين معنى ذلك
+
+229
+00:22:22,690 --> 00:22:27,870
+التفكير اللي بده يكون عندكم اما تنتين bubble bonds
+
+230
+00:22:28,750 --> 00:22:35,290
+أو تنتين حلقات او حلقة و double bond واضح؟ لأن كل
+
+231
+00:22:35,290 --> 00:22:39,130
+هيدروجينتين معناهم ان انت شيلتوا ايش؟ يا عملتوا
+
+232
+00:22:39,130 --> 00:22:42,810
+double bond يا عملتوا حلقة واضح؟ فانا شيلت
+
+233
+00:22:42,810 --> 00:22:46,310
+هيدروجين مرتين بين التمانية والاربعة اربع
+
+234
+00:22:46,310 --> 00:22:50,750
+هيدروجينات تنتين و تنتين الآن بدكوا تقولوا يا
+
+235
+00:22:50,750 --> 00:22:54,790
+تنتين double bonds يا تنتين حلقات يا double bond
+
+236
+00:22:54,790 --> 00:23:01,040
+وحلقة طبعا ال C3H4 ما بتحتملتلتين حلقات يعني كلها
+
+237
+00:23:01,040 --> 00:23:05,860
+كم ذرة هي تلاتة بناء على ذلك لو أنا فكرت أني بدأ
+
+238
+00:23:05,860 --> 00:23:10,220
+أعمل منهم حلقة حلقة واحدة لازم ألاحقها بكمان ايش
+
+239
+00:23:10,220 --> 00:23:14,760
+double bond لاحظوا لو هنا اتيتوا تكملوا ال
+
+240
+00:23:14,760 --> 00:23:20,420
+hydrogens هتطلع الفورموله صح اتش اتش اتش اتش اتش
+
+241
+00:23:20,420 --> 00:23:23,500
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+242
+00:23:26,930 --> 00:23:32,270
+هذا الاحتمال اللى فيه حلقات الان بعد هيك ممكن اعمل
+
+243
+00:23:32,270 --> 00:23:37,870
+التنتين bubble bonds اعتبرهم ال kind triple bond
+
+244
+00:23:37,870 --> 00:23:48,130
+يعني احط C triple bond C و هنا CH3 CH3
+
+245
+00:23:48,130 --> 00:23:55,510
+و هذه H هدولة بمثابة تنتين bubble bonds هاي CH3
+
+246
+00:23:57,130 --> 00:24:02,770
+ممكن احط تنتين double bonds جانب بعض carbon double
+
+247
+00:24:02,770 --> 00:24:07,490
+bond carbon double bond carbon وهنا بدو يكون عندكم
+
+248
+00:24:07,490 --> 00:24:14,490
+CH2 CH2
+
+249
+00:24:14,490 --> 00:24:15,910
+في غير هيك؟
+
+250
+00:24:19,310 --> 00:24:23,910
+أهم شيء اللى بنى عليها هذا السؤال انه نفهم احنا ان
+
+251
+00:24:23,910 --> 00:24:31,610
+الصيغة المشبعة تماما لل C3 هي H8 الان مقابل كل
+
+252
+00:24:31,610 --> 00:24:35,990
+هيدروجينتين بخصومهم بدي اعمل double bond او حلقة
+
+253
+00:24:35,990 --> 00:24:41,170
+واضح فخصمت هيدروجنتين على كام مرة امرتين اربعة
+
+254
+00:24:41,170 --> 00:24:44,730
+تقسيم اتنين اتنين فهنا عملت حلقة و double bond هنا
+
+255
+00:24:44,730 --> 00:24:47,370
+عملت تنتين by bonds هنا عملت تنتين double bonds
+
+256
+00:24:49,120 --> 00:24:53,720
+ولما تكملوا الشكل كيميائيا شكل سليم 100% ولا لأ؟
+
+257
+00:25:08,560 --> 00:25:13,280
+الان هذا السؤال نمشي أسرع على تفاعل ال الكاينز
+
+258
+00:25:13,280 --> 00:25:17,380
+قلنا ال terminal الكاينز are acidic يعني هذا شو
+
+259
+00:25:17,380 --> 00:25:23,400
+بده يعطينا فنل C triple bond C minus الان إذا
+
+260
+00:25:23,400 --> 00:25:31,440
+فعلتوا مع إيثالبروميد CH3 CH2Br بده يعمل عليها ال
+
+261
+00:25:31,440 --> 00:25:36,890
+eucleophilic substitution هذه الكربون اتهاجمهاتطرد
+
+262
+00:25:36,890 --> 00:25:43,610
+ال PR ما هو ذا نيوكليو 5 إذا النتيجة فينيل C
+
+263
+00:25:43,610 --> 00:25:55,130
+triple bond C وهنا هياتحدت مع CH2 CH3 طردت ال PR
+
+264
+00:25:55,130 --> 00:26:02,330
+إبدالي نيوكليو فينيل الان هذا المركب مع ال lithium
+
+265
+00:26:02,330 --> 00:26:07,730
+و ال ammonia شو بيعمل؟Double bond هو اكيد بيضيف
+
+266
+00:26:07,730 --> 00:26:16,630
+الهيدروجين عكس بعض لكن مافيش فارق بالنتيجة هايو
+
+267
+00:26:16,630 --> 00:26:20,910
+الهيدروجين اللي ضفته كيف اجوا عكس بعض لكن المراكب
+
+268
+00:26:20,910 --> 00:26:26,810
+لا فيه cis ولا trans لأن هدوله زي بعض الان بعد هيك
+
+269
+00:26:26,810 --> 00:26:30,450
+هذا المراكب بتعمله اوزونوليسيز شو ال اوزونوليسيز
+
+270
+00:26:30,450 --> 00:26:35,130
+نكسر ال double bond لتنتين
+
+271
+00:26:36,290 --> 00:26:42,030
+C double bond O إذا
+
+272
+00:26:42,030 --> 00:26:47,130
+انكوّننا الألكين وبعدين كسرنا لتنتين C double bond
+
+273
+00:26:47,130 --> 00:26:48,830
+O هذا ال ozoneolysis
+
+274
+00:27:03,880 --> 00:27:10,080
+بعد هيك السؤال كيف ممكن نحضر المراكبات الآتية سيس
+
+275
+00:27:10,080 --> 00:27:15,900
+وانتو سايكلو بنتين دايول يعني
+
+276
+00:27:15,900 --> 00:27:26,420
+هنا سايكلو بنتين و OH و OH على جهة واحدة الآن أي
+
+277
+00:27:26,420 --> 00:27:32,140
+واحدة فيكوا شاطرة هتقول السيس كيف كنت أجيبه ترجع
+
+278
+00:27:32,140 --> 00:27:41,640
+برجوعالألكين مع الكيامان او فور في ال basic medium
+
+279
+00:27:41,640 --> 00:27:48,440
+او اوزميام او فور الان انا كنت حاكي هنا مابديش
+
+280
+00:27:48,440 --> 00:27:51,820
+ابدأ من ال cyclopentane مابدي ابدأ من ال promo
+
+281
+00:27:51,820 --> 00:27:58,240
+cyclopentane يعني هنا في عند بي ار الان يا تورا
+
+282
+00:27:58,240 --> 00:28:06,550
+هذه ال بي ار فيش جنب هاتشها اكيدبقدر استعمل KOH
+
+283
+00:28:06,550 --> 00:28:20,150
+بتصير ألكيل والألكيل بضيف عليه الميه starting
+
+284
+00:28:20,150 --> 00:28:29,490
+from بنزين برا نيترو كيومين هيلي
+
+285
+00:28:29,490 --> 00:28:35,410
+كيومين وحملة نيترواللي متذكرة هذي بتودي على الميتا
+
+286
+00:28:35,410 --> 00:28:39,790
+هذي Orthobara ال الكلي جروبز كلهم ال R Orthobara
+
+287
+00:28:39,790 --> 00:28:44,610
+الآن الوضع اللي موجود عندك اذا اول اشي انا بدي
+
+288
+00:28:44,610 --> 00:28:54,250
+اعمله اني بدي احضر هذا المركب وبعدين اه الان بيضل
+
+289
+00:28:54,250 --> 00:28:56,350
+ايش ال reagents ايزوبروبليكلورايد
+
+290
+00:28:56,350 --> 00:29:02,740
+ايزوبروبليكلورايد معالألمنيوميكلورايد او whatever
+
+291
+00:29:02,740 --> 00:29:11,080
+وبعدين هنا بدي اعمل نيتريشن بيطلع
+
+292
+00:29:11,080 --> 00:29:19,680
+ال ortho زائد البارا product واضح؟
+
+293
+00:29:21,290 --> 00:29:26,590
+هي الامتحان كامل مع الشريح والتفصيل الممل اعملناه
+
+294
+00:29:26,590 --> 00:29:29,350
+معاكم بطول الساعة اكيد لما يجيكوا انتوا كطلاب
+
+295
+00:29:29,350 --> 00:29:34,430
+هتاخدوا عليه ساعة لكن السؤال في حرف منه خارج عن
+
+296
+00:29:34,430 --> 00:29:37,590
+اللي درسته؟ الحمد لله ربنا
+
+297
+00:29:48,970 --> 00:29:54,650
+خلّينا نكسب الوقت و نحل امتحان من باب المراجعة
+
+298
+00:29:54,650 --> 00:29:58,030
+الشاملة
+
+299
+00:29:58,030 --> 00:30:16,490
+هذا
+
+300
+00:30:16,490 --> 00:30:27,530
+الامتحانالنمط تبعه في سؤال صح و غلط خلينا
+
+301
+00:30:27,530 --> 00:30:31,930
+نشوفه there are four types of hydrogen and
+
+302
+00:30:31,930 --> 00:30:37,170
+isobentane هذا بيستلزم ان انا اعرف ايش ال
+
+303
+00:30:37,170 --> 00:30:43,070
+isobentaneالان هاي ال eyes وبينتين كام نوع عندى من
+
+304
+00:30:43,070 --> 00:30:49,890
+ال hydrogens خلينا نقول هدول ال hydrogens زى بعض و
+
+305
+00:30:49,890 --> 00:30:59,490
+هدى و هدى و هدى نفس ايش؟ كيف؟
+
+306
+00:31:01,530 --> 00:31:06,390
+رجاءً لما بجيبلكوا سؤال ما تفكروش أنه أنواع ال
+
+307
+00:31:06,390 --> 00:31:10,970
+hydrogens أنه primary و secondary و tertiary مش
+
+308
+00:31:10,970 --> 00:31:14,590
+هذا اللي علمتكوا إياه إطلاقا، يعني من ال primary
+
+309
+00:31:14,590 --> 00:31:20,200
+ممكن يكون عندهكذا مجموعة برايمر لكن كل واحدة تمثل
+
+310
+00:31:20,200 --> 00:31:25,060
+نوع في الهيدروجينز واضح؟ عمره ماكان السؤال حددولي
+
+311
+00:31:25,060 --> 00:31:28,540
+كام نوع هيدروجينز انكوا تفكروا بكلمة برايمر و
+
+312
+00:31:28,540 --> 00:31:31,700
+سكندر و تيرتشل ولا هذا اللي علمناكم إياه يعني على
+
+313
+00:31:31,700 --> 00:31:36,520
+سبيل المثال على سبيل المثال حتى نأكد المعلومة الآن
+
+314
+00:31:36,520 --> 00:31:45,540
+لو حطيت هذا المركب هي هذه CH3 وهي هذه CH3 هذه زي
+
+315
+00:31:45,540 --> 00:31:51,700
+هذه؟لو حطيت هنا كلور بدل H من هنا زي ما حطي بدل H
+
+316
+00:31:51,700 --> 00:31:57,120
+من هنا مش كل CH3 بدي أقول عنها زي بعض ولا كل CH2
+
+317
+00:31:57,120 --> 00:32:04,380
+زي بعض لأ واضح؟ ولذلك هذا المركب الآن كام هيدروجين
+
+318
+00:32:04,380 --> 00:32:08,580
+فيه هدول المجمعتين زي بعض هي كمان نوع هي كمان نوع
+
+319
+00:32:08,580 --> 00:32:15,260
+هي كمان نوع أربع أنواع من الهيدروجين واضح؟طيب
+
+320
+00:32:15,260 --> 00:32:20,480
+احبطت شوية اتجاوزجالبة تقولي في هذا كام نوع من
+
+321
+00:32:20,480 --> 00:32:26,860
+الهيدروجين عندك؟ يعني لو قولنا لكوا برائث التلوين
+
+322
+00:32:26,860 --> 00:32:34,280
+كام نوع من الهيدروجين؟ واحد هدولة تنتين زي بعض،
+
+323
+00:32:34,280 --> 00:32:41,860
+هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول زي
+
+324
+00:32:41,860 --> 00:32:43,760
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول
+
+325
+00:32:43,760 --> 00:32:43,760
+زي بعض، هدول زي بعض، هدول زي بعض، هدول زي بعض،
+
+326
+00:32:43,760 --> 00:32:43,760
+هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول زي
+
+327
+00:32:43,760 --> 00:32:45,480
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعهتنسيش ان
+
+328
+00:32:45,480 --> 00:32:52,860
+هذه double bond ان هذه الدويرة اصلا و هدولة مافيش
+
+329
+00:32:52,860 --> 00:32:58,000
+عليهم غير مجموعة واحدة يعني انا واحد اتنين تلاتة
+
+330
+00:32:58,000 --> 00:33:02,100
+اربعة مافيش انا hydrogen فلما نكون راسمين دائرة
+
+331
+00:33:02,100 --> 00:33:05,840
+ماحدش يفكر ان هوان و هوان فيها hydrogen واضحة
+
+332
+00:33:05,840 --> 00:33:09,240
+الفكرة؟ هي اللي بيوجع الانسان في الغلط ان انا مش
+
+333
+00:33:09,240 --> 00:33:13,220
+راسم ال double bonds ان انا عامل هيك بس هذه لها
+
+334
+00:33:13,220 --> 00:33:17,180
+معنى في الكيميافما تفكروش ان هنا وهنا يوجد
+
+335
+00:33:17,180 --> 00:33:23,500
+هيدروجينز في الشكل يا
+
+336
+00:33:23,500 --> 00:33:28,780
+ريتما ماحطتش الامتحان كان جيبتي الكويزمة اه there
+
+337
+00:33:28,780 --> 00:33:33,460
+are three possible stereoisomers of 1,2
+
+338
+00:33:33,460 --> 00:33:39,460
+-dichlorobrobane الان لاحظوا بالكتورث مش شكل
+
+339
+00:33:39,460 --> 00:33:46,160
+البروبين كام كاربونتلاتة على نمرة واحد و اتنين في
+
+340
+00:33:46,160 --> 00:33:50,120
+عندى chlorine يعني هذه حملة chlorine و هذه حملة
+
+341
+00:33:50,120 --> 00:33:54,780
+chlorine لو كملنا ال hydrogens الان هنا CH2 هنا
+
+342
+00:33:54,780 --> 00:34:04,140
+CH3 الان من هذا المركب كم isomer عندى اه
+
+343
+00:34:04,140 --> 00:34:09,580
+بديش انسى ان في عندى chiral center هنا مافيش هنا
+
+344
+00:34:09,580 --> 00:34:13,940
+في chiral centerطالما عندي chiral center إذا
+
+345
+00:34:13,940 --> 00:34:23,740
+المركب و صورته إذا كام stereo isomer عند هنا الصح؟
+
+346
+00:34:23,740 --> 00:34:30,220
+نان .. نان هذا واحد اللي موجود عندكم حقيقة هو ال S
+
+347
+00:34:30,220 --> 00:34:35,900
+بتقدر ترسم صورته في المرايا ال R اللي موجود هو ال
+
+348
+00:34:35,900 --> 00:34:40,200
+S بتقدر ترسم ال R إذا هذه الجملة غلط
+
+349
+00:34:46,280 --> 00:34:53,080
+Addition of HBr Peroxide to styrene produces two
+
+350
+00:34:53,080 --> 00:34:59,040
+stereoisomers طبعا اللي مش عارف ال styrene زنبها ع
+
+351
+00:34:59,040 --> 00:35:08,500
+جنبها CH double bond CH2 لاحظوا هذا سؤال جميل لو
+
+352
+00:35:08,500 --> 00:35:13,060
+انا كنت باضيف HBr في وجود H plus هضيفه حسب قاعدة
+
+353
+00:35:13,060 --> 00:35:18,780
+Markovnikov هحط هنا ال Hوهنا ال PR وجدت في هذه
+
+354
+00:35:18,780 --> 00:35:24,080
+الحالة هعمل chiral center هنا هيطلع عندى ناتجين لو
+
+355
+00:35:24,080 --> 00:35:28,460
+أنا بضيف ال HPR في وجود H Plus هنا ال H هنا ال PR
+
+356
+00:35:28,460 --> 00:35:32,920
+إذا انا عملت chiral center لأن لما بضيف في وجود ال
+
+357
+00:35:32,920 --> 00:35:37,780
+peroxide Anti Markovnikov's addition يعني بدي ألغى
+
+358
+00:35:37,780 --> 00:35:45,050
+هذا ال double bond و أحط هنا H و هنا PRبر فيها انا
+
+359
+00:35:45,050 --> 00:35:50,050
+كايرال سنتر فيها انا كايرال سنتر اذا الكم ايزو مار
+
+360
+00:35:50,050 --> 00:35:57,430
+طلع عني واحد مش اتنين لو كنا بنضيف hbr في وجود h
+
+361
+00:35:57,430 --> 00:35:58,550
+plus بطلع اتنين
+
+362
+00:36:08,270 --> 00:36:11,910
+هذا السؤال MAI reacts with ethyl chloride
+
+363
+00:36:11,910 --> 00:36:16,410
+producing ethyl iodide لاحظوا هنا إبدال أن اليود
+
+364
+00:36:16,410 --> 00:36:23,670
+بيحل محل كلور هذه المعلومة أخدناها ولا لأ اليود
+
+365
+00:36:23,670 --> 00:36:32,630
+بيحل محل كلور و العكس مش صحيح Cyclohexanol بتكون
+
+366
+00:36:32,630 --> 00:36:37,730
+تتذكروا بمخكوا ع طول ال Cyclohexanolركزنا عليه في
+
+367
+00:36:37,730 --> 00:36:43,130
+الرسم ولا لأ؟ اللي متصل ب OH لو عملتله أكسدة شو
+
+368
+00:36:43,130 --> 00:36:52,690
+هيعمل؟ هيحذف ال H و ال H هاي الأكسدة تبعته، هاي
+
+369
+00:36:52,690 --> 00:36:57,360
+أكسدته، إيش أعطاني؟عطاني كيتون أساسا
+
+370
+00:36:57,360 --> 00:37:00,680
+الـcyclohexanol is secondary alcohol secondary
+
+371
+00:37:00,680 --> 00:37:05,420
+alcohols are oxidized to ketones وهي بالرسمة بيعطي
+
+372
+00:37:05,420 --> 00:37:13,660
+كيتون أنا كاتبلكم غلط مش الديهيد كيتون dehydration
+
+373
+00:37:13,660 --> 00:37:18,180
+of secondary butyl alcohol مرة تانية رجعنا تكونوا
+
+374
+00:37:18,180 --> 00:37:23,060
+حافظين أسماء إيش المجموعات ال secondary butyl اللي
+
+375
+00:37:23,060 --> 00:37:30,120
+حاملة هناعلى هذا الموقع وهذا لما يحمل OH سكندر
+
+376
+00:37:30,120 --> 00:37:35,020
+بيوت الالكهول طبعا ال dehydration يا ال OH من هنا
+
+377
+00:37:35,020 --> 00:37:42,620
+او من هنا اخدنا انه حسب قاعدة زي سف الحذف و more
+
+378
+00:37:42,620 --> 00:37:47,320
+substituted product will form اذا ال one butane
+
+379
+00:37:47,320 --> 00:37:51,260
+ولا ال two butane انا كاتبينلكم بشكل أساسي one
+
+380
+00:37:51,260 --> 00:37:52,820
+butane اذا خطأ
+
+381
+00:38:10,810 --> 00:38:15,070
+dichlorination of cyclobutane gives a total of
+
+382
+00:38:15,070 --> 00:38:19,310
+لحظوا ال cyclobutane بهذا الشكل بدي أضع عليه
+
+383
+00:38:19,310 --> 00:38:25,830
+مجموعتين كلور كيف ممكن أضعهم على واحد و واحد أو
+
+384
+00:38:25,830 --> 00:38:29,150
+على واحد و اتنين على واحد و اتنين بيجي ال ces و ال
+
+385
+00:38:29,150 --> 00:38:29,810
+trans
+
+386
+00:38:39,260 --> 00:38:45,180
+cyclobutane ..cyclobutane ..انا متأسف okay ..الان
+
+387
+00:38:45,180 --> 00:38:48,500
+ال ..cyclobutane ..حطوا مجموعتين كلور على واحد
+
+388
+00:38:48,500 --> 00:38:53,980
+واحد ..هذا مركب ..بعدين ع واحد و اتنين .. six و
+
+389
+00:38:53,980 --> 00:38:57,860
+trance .. بعدين ع واحد و تلاتة .. six و trance ..
+
+390
+00:38:57,860 --> 00:39:02,300
+اذا قداش المجموعة؟ خمسة ..هي نفس فكرة ال
+
+391
+00:39:02,300 --> 00:39:07,200
+..cyclobrote .. بس على أوصةThe common name of two
+
+392
+00:39:07,200 --> 00:39:19,360
+propene one all يعني هاي CH2OH CH double bond CH2
+
+393
+00:39:19,360 --> 00:39:26,160
+لحظوا هذا two propene واحد اتنين تلاتة one all هنا
+
+394
+00:39:26,160 --> 00:39:30,340
+فسرناه الآن الناس اللي متذكرة شكل المجموعة شو هي
+
+395
+00:39:30,340 --> 00:39:32,400
+الالكول
+
+396
+00:39:34,300 --> 00:39:40,940
+قلل ألكول قلل ألكول إذا كان شوكارو مستعمل لإيصال
+
+397
+00:39:40,940 --> 00:39:45,440
+حركة محركة واحدة إلكترون واحدة إلكترون فالمثال لـ
+
+398
+00:39:45,440 --> 00:39:51,880
+Cyclic Alkenes هو CNH2N-2 لاحظوا الـ Cyclic بدأ
+
+399
+00:39:51,880 --> 00:39:55,660
+أقسم جبالها اتنين من الفورمولة الأصلية والـ E بدأ
+
+400
+00:39:55,660 --> 00:40:00,400
+أقسم اتنين إذا صارت زي formula of الكائنات يعني
+
+401
+00:40:00,400 --> 00:40:08,300
+CNHتو ان ماينوس تو وبتاعة اللي عملناها مركبة زيها
+
+402
+00:40:08,300 --> 00:40:14,260
+اوزونوليسيس او سيس اوري ترانس تو بيوتين خليني
+
+403
+00:40:14,260 --> 00:40:19,860
+اخد ال سيس تو بيوتين ارسمه هان هاي ال سيس تو
+
+404
+00:40:19,860 --> 00:40:23,880
+بيوتين بدي اكسره من هان C double bond O وهذه H
+
+405
+00:40:23,880 --> 00:40:30,660
+بالتأكيدهذا C double bond OH CH3 Acetaldehyde هذا
+
+406
+00:40:30,660 --> 00:40:38,400
+C double bond OH CH3 Acetaldehyde و لل Trans هاي
+
+407
+00:40:38,400 --> 00:40:47,640
+CH3H و هنا CH3H الان اكسروا هذا من هنا و اكسروا
+
+408
+00:40:47,640 --> 00:40:53,400
+هذا من هنا و حطوا ايش Oxygen Oxygen Oxygen Oxygen
+
+409
+00:40:53,980 --> 00:40:59,480
+كل النواتج ايش؟ أسيتلديهيد بيعطي نفس الناتج
+
+410
+00:40:59,480 --> 00:41:07,000
+produces only أسيتلديهيد أو إيثانال أسيتلديهيد
+
+411
+00:41:07,000 --> 00:41:14,960
+CH3SH is more acidic than CH3OH due to size
+
+412
+00:41:17,520 --> 00:41:22,560
+سلفر مع اكسجين ايش العامل المحدد في ال acidity ال
+
+413
+00:41:22,560 --> 00:41:27,820
+size ال due to size
+
+414
+00:41:27,820 --> 00:41:34,740
+الان
+
+415
+00:41:34,740 --> 00:41:40,660
+ارسموا المراكبات التالية بدي بيوتينيعني carbon
+
+416
+00:41:40,660 --> 00:41:46,820
+تنتين تلاتة أربعة على لمرة اتنين ايش موجود عندكم؟
+
+417
+00:41:46,820 --> 00:41:56,900
+فينوكسي يعني O phenyl OH OHANA CH3 CH2 CH3 الآن
+
+418
+00:41:56,900 --> 00:42:01,120
+انا برسم المركب بعدين بشوفه اذا طلع R كان بيها
+
+419
+00:42:01,120 --> 00:42:06,970
+ماطلعش Rبعكس اي مجموع تاني الا لو جيت تطلعت عليه
+
+420
+00:42:06,970 --> 00:42:11,890
+كيف مبين هذي واحد هذي اتنين هذي تلاتة مبين اس و
+
+421
+00:42:11,890 --> 00:42:18,590
+هذي على الجانب اذا هذا فعلا الار ايزو مار عندي
+
+422
+00:42:18,590 --> 00:42:24,770
+سايكلو بنتين هاي السايكلو بنتين خليني ارسمه بهذا
+
+423
+00:42:24,770 --> 00:42:30,530
+الشكلcyclopentane واحد اتنين تلاتة اربعة خمسة على
+
+424
+00:42:30,530 --> 00:42:38,950
+نمرة تلاتة واربعة شو بدي احط كلور وكلور بالزويك
+
+425
+00:42:38,950 --> 00:42:47,010
+أسد C double bond O OH وهنا ال formal C double
+
+426
+00:42:47,010 --> 00:42:57,620
+bond OH هذا ميتاميتا أو بارا هذا موضوع بسيط هذا
+
+427
+00:42:57,620 --> 00:43:01,020
+المركب
+
+428
+00:43:01,020 --> 00:43:10,120
+Cyclopentane شو هذه المجموعة؟ Isobutyl Isobutyl
+
+429
+00:43:10,120 --> 00:43:15,680
+Cyclopentane هذا
+
+430
+00:43:15,680 --> 00:43:22,160
+كحول ألكين من وين الترقيم؟ من عند الكحول يعني هذا
+
+431
+00:43:25,670 --> 00:43:36,290
+بيوتين بيوت two in one all و إيش بيحمل بعد هى two
+
+432
+00:43:36,290 --> 00:43:43,710
+bromo فيه زده E لحظوا هنا ال brom و هنا الميثل ال
+
+433
+00:43:43,710 --> 00:43:47,270
+brom أعلى من الكربون و الميثل أعلى من ال H إذا هذا
+
+434
+00:43:47,270 --> 00:43:51,750
+E هذا أسيتوفينون
+
+435
+00:44:14,250 --> 00:44:18,730
+مش كتير معنا وقت ان شاء الله بخمس دقائق نمشي أسرع
+
+436
+00:44:18,730 --> 00:44:21,270
+بدنا خمس دقائق نمشي أسرع شوية
+
+437
+00:44:24,120 --> 00:44:30,000
+هحاول امشي بشكل سريع الان هنا في ال HBr Peroxide
+
+438
+00:44:30,000 --> 00:44:35,140
+الفكرة الأساسية اللى بتكون تعمله شو هي انت
+
+439
+00:44:35,140 --> 00:44:43,000
+Markovnikov واضح فلو انتوا جيتوا واشتغلتوا H CH3
+
+440
+00:44:43,000 --> 00:44:51,740
+CH2 هنا H هنا H وين هتحطوا ال Br وهنا
+
+441
+00:44:51,740 --> 00:44:56,880
+ال Hهي الـ Antimark of Nikon واضح؟ الان هذا لو
+
+442
+00:44:56,880 --> 00:45:00,320
+فعلته مع ال Oethel minus Can you clear your file؟
+
+443
+00:45:00,320 --> 00:45:08,700
+شو بتعمل؟ بتحيل محل لبروم يعني بتحط كل الجزيء و
+
+444
+00:45:08,700 --> 00:45:18,540
+تكتبوا هنا Oethel و لو فعلته مع ال SH minus بدنا
+
+445
+00:45:18,540 --> 00:45:26,810
+نحط كل الجزيء مرة تانيةوبنحط هنا sh ابدال يعني هذا
+
+446
+00:45:26,810 --> 00:45:30,870
+البروم بتبدل هذا عنوان chapter 6 انه البروم بتبدل
+
+447
+00:45:30,870 --> 00:45:36,310
+بال او اثل او بال sh هنا بالكئمن او فور مع ال o h
+
+448
+00:45:36,310 --> 00:45:44,090
+minus شو بدها تحط مجمعتين o h على جهة واحدة بال
+
+449
+00:45:44,090 --> 00:45:50,730
+ozonolysis بدوا يعمل تلتين c double point o بتكمل
+
+450
+00:45:50,730 --> 00:45:58,340
+الجزيةبالميه هذه بتضيف حسب قاعدة Markovnikov
+
+451
+00:45:58,340 --> 00:46:03,220
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+452
+00:46:03,220 --> 00:46:07,800
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+453
+00:46:07,800 --> 00:46:07,980
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+454
+00:46:07,980 --> 00:46:09,020
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+455
+00:46:09,020 --> 00:46:09,960
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+456
+00:46:09,960 --> 00:46:20,320
+اتش اتش اتش اتش اتش اتش اتش اتش
+
+457
+00:46:20,320 --> 00:46:22,320
+ات
+
+458
+00:46:33,790 --> 00:46:41,490
+أخر شغلة الأفكار الأساسية هنا إضافة ميه وبعدين
+
+459
+00:46:41,490 --> 00:46:47,110
+توتوميرزم متذاكرينها ال
+
+460
+00:46:47,110 --> 00:46:54,030
+ISOبنتين هي ال ISOبنتين اعملولها إكلوريناشن توي
+
+461
+00:46:54,030 --> 00:47:01,240
+حكينا كام موقع فيها؟واحد اتنين تلاتة اربعة لما
+
+462
+00:47:01,240 --> 00:47:05,440
+احطولكوا all possible monochlorination products
+
+463
+00:47:05,440 --> 00:47:10,700
+انتبهوا معي لما احط كلور هان و هان هذا ناتج و اذا
+
+464
+00:47:10,700 --> 00:47:13,740
+حطيت هان هذا ناتج هذا فيش فيه chiral center هذا
+
+465
+00:47:13,740 --> 00:47:17,500
+فيش فيه chiral center لو حطيت هان CH2Cl فيش فيه
+
+466
+00:47:17,500 --> 00:47:23,210
+chiral center لو حطيت هانأتش و CL في كايرالسنتر
+
+467
+00:47:23,210 --> 00:47:27,430
+هدا بده يطلع منه كام واحد اتنين اذا المجموع كده؟
+
+468
+00:47:27,430 --> 00:47:32,890
+خمسة product لما ادخل ال stereo isomers هذه النقطة
+
+469
+00:47:32,890 --> 00:47:38,510
+تحديدا بحط فيها ال H و ال CL يعني الناتجين اللي
+
+470
+00:47:38,510 --> 00:47:44,450
+بدهم يكونوا هنا لو رسمت الناتج و صورته في المرايا
+
+471
+00:47:44,450 --> 00:47:52,680
+بدكوا تكونوا حاطين هنا مثلاH و CH3 و CL وهنا تحطوا
+
+472
+00:47:52,680 --> 00:48:02,100
+CL و H و CH3 الناتج و صورته في المرأة واضح
+
+473
+00:48:02,100 --> 00:48:06,300
+الناتج و صورته في المرأة هذوله اتنين و بعدين
+
+474
+00:48:06,300 --> 00:48:09,920
+بتحطوا هن واحد و هن واحد و هن واحد المجموع كده؟
+
+475
+00:48:09,920 --> 00:48:17,300
+خمسة خمسة بقى لعنا اتنين صغار كتير
+
+476
+00:48:25,790 --> 00:48:29,490
+isopropylacetophenon الفكرة فقط انكوا تعرفوا مين
+
+477
+00:48:29,490 --> 00:48:34,550
+بده احطها في الأول انهي المجموعة اللي بتلحط نمرا
+
+478
+00:48:34,550 --> 00:48:42,090
+واحد ال isopropyl ال isopropyl orthopara ال
+
+479
+00:48:42,090 --> 00:48:46,290
+isopropyl orthopara directing و بعدين ال
+
+480
+00:48:46,290 --> 00:48:47,270
+acetophenon
+
+481
+00:48:49,330 --> 00:48:54,330
+Cl ألمنيوم كلورايد و هنا ايزو بروبل كلورايد
+
+482
+00:48:54,330 --> 00:49:02,530
+ألمنيوم كلورايد أخر سؤال سيث ثريهكسيني من ون
+
+483
+00:49:02,530 --> 00:49:07,430
+بيوتايل لاحظوا هذا ال ون بيوتايل بهذا الشكل CH3
+
+484
+00:49:07,430 --> 00:49:15,670
+CH2 C triple bond CH من أربعة بده أحضر ستة
+
+485
+00:49:15,670 --> 00:49:17,890
+ملاحظين؟
+
+486
+00:49:18,690 --> 00:49:24,670
+من الأربعة شو بده احضر؟ ستة كيف بده اعمل هذا
+
+487
+00:49:24,670 --> 00:49:31,470
+الكلام؟ اول اشي بده ازيد ذاتين carbon فانا لو فعلت
+
+488
+00:49:31,470 --> 00:49:38,380
+مع ال NANH2 نمرة واحد خلت هذه minusو بعدين نمرة
+
+489
+00:49:38,380 --> 00:49:44,540
+اتنين فعلتها مع إثيل بروميد CH3 CH2Br ال minus
+
+490
+00:49:44,540 --> 00:49:48,760
+اللي بيحجم على ال PR و أجتها بيصير عندي هذا ال
+
+491
+00:49:48,760 --> 00:49:56,140
+كائن CH3 CH2 C triple bond C وهي ال إثيل اللي أنا
+
+492
+00:49:56,140 --> 00:50:04,950
+حطيتها CH2 CH3 الان من هذه بدي أخليهاالكين
+
+493
+00:50:04,950 --> 00:50:09,090
+والالكين يكون إيش؟ SES كيف بحول ال triple bond
+
+494
+00:50:09,090 --> 00:50:18,610
+لالكين SES؟ H2 Lendlers Catalyst Lendlers Catalyst
+
+495
+00:50:18,610 --> 00:50:24,350
+إذا هذا السؤال فيه فكرتين أساسيات الفكرة الأولى أن
+
+496
+00:50:24,350 --> 00:50:28,010
+ال terminal alkyl بيصير نيوكليوفايل ممكن يعمل
+
+497
+00:50:28,010 --> 00:50:34,070
+إبدال علىالكالهلايد كبرت السلسلة و بعدين ل triple
+
+498
+00:50:34,070 --> 00:50:38,010
+bond ان اخليها cis او trans اخدته قولت انا ل
+
+499
+00:50:38,010 --> 00:50:43,470
+triple bond يا بخليها الكن يا cis الكن يا trans
+
+500
+00:50:43,470 --> 00:50:48,590
+الكن كل واحدة في إلها شروط معينة ابقى اك تقريبا
+
+501
+00:50:48,590 --> 00:50:53,810
+بنكون غطينا يعني باسئلة مختلفة معظم الأشياء اللي
+
+502
+00:50:53,810 --> 00:50:57,490
+درسناها و بنتمنالكوا ان شاء الله النجاح و التوفيق
+
+503
+00:50:57,490 --> 00:50:59,050
+في الامتحان اللي بدكنوا تقدموه
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4b8131f65ab6d70a139d0eb9aeb6fd4046050680
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_postprocess.srt
@@ -0,0 +1,1840 @@
+1
+00:00:24,690 --> 00:00:29,550
+الحدي عشر في جزء الكيميا الرجوية العادى قبل ما
+
+2
+00:00:29,550 --> 00:00:35,290
+ننتقل لمقدمة البيت الاسطي اللى هو بعنوان amines
+
+3
+00:00:35,290 --> 00:00:43,010
+amines يعني مركبات ال nitrogen المركبات اللى فيها
+
+4
+00:00:43,010 --> 00:00:49,250
+ال nitrogen طبعا كلنا عارفين ان ال amine او ال
+
+5
+00:00:49,250 --> 00:00:49,810
+nitrogen
+
+6
+00:01:07,020 --> 00:01:13,380
+الان هذول ال ثلاث روابط في أبسط المركبات على
+
+7
+00:01:13,380 --> 00:01:18,940
+الإطلاق تبع ال نيتروجيز لما بيكونوا إيش هيدروجيز
+
+8
+00:01:18,940 --> 00:01:26,200
+بيكون عنده جزء الأمونيا يعني أبسط مركب للنيتروجيز
+
+9
+00:01:26,200 --> 00:01:30,640
+هو جزء الأمونيا الآن الأمونيا ممكن ما نعتبرهاش
+
+10
+00:01:30,640 --> 00:01:31,220
+مركبة
+
+11
+00:01:45,690 --> 00:01:47,650
+إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا
+
+12
+00:01:47,650 --> 00:01:48,170
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+13
+00:01:48,170 --> 00:01:48,250
+إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا
+
+14
+00:01:48,250 --> 00:01:49,730
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+15
+00:01:49,730 --> 00:01:51,150
+إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا
+
+16
+00:01:51,150 --> 00:01:51,170
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+17
+00:01:51,170 --> 00:01:51,390
+نعمل إبدال إذا بدنا نعمل إبدال إذا بدنا نعمل إبدال
+
+18
+00:01:51,390 --> 00:02:01,170
+إبدال إذا بدنا نعمل إبدال إبدال إذا
+
+19
+00:02:01,170 --> 00:02:03,150
+بدنا نعمل إ
+
+20
+00:02:16,910 --> 00:02:20,930
+هذا بنسميه primary amine يعني نيتوجن متصل فيه بكام
+
+21
+00:02:20,930 --> 00:02:26,630
+carbon واحدة الآن لو بدّرنا التانية صار انتزلتين R
+
+22
+00:02:26,630 --> 00:02:33,370
+صار secondary amine لو بدّرنا التالتة صار tertiary
+
+23
+00:02:33,370 --> 00:02:37,310
+amine فال amines المشهورة ال primary و ال
+
+24
+00:02:37,310 --> 00:02:42,370
+secondary و ال tertiary الآن هل يا ترى ممكن نعمل
+
+25
+00:02:42,370 --> 00:02:49,030
+كمان R رابعة؟في مرات معينة لو جيبنا R موجبة فعنا
+
+26
+00:02:49,030 --> 00:02:53,970
+مع هذا زوج الإلكترونات بيعمل رابط بهذا الشكل
+
+27
+00:02:53,970 --> 00:02:58,650
+وبيعمل الـR الرابعة لكن في هذه الحالة لو حسبنا
+
+28
+00:02:58,650 --> 00:03:04,910
+الـformal charge عن الـNitrogen بتصير موجبة واضح؟
+
+29
+00:03:04,910 --> 00:03:11,290
+فبصير عنده صوت يعني طالما فيه موجب إذا في مرافق له
+
+30
+00:03:13,270 --> 00:03:18,630
+واضح طالما فيه موجب إذا فيه إله مرافق سارق تماما
+
+31
+00:03:18,630 --> 00:03:22,270
+زي لما كنتوا تاخدوا المركب المشهور مثلا ال
+
+32
+00:03:22,270 --> 00:03:26,430
+ammonium chloride كنتوا توصلوا على ال nitrogen
+
+33
+00:03:26,430 --> 00:03:34,990
+أربع روابط تحطوا على ال nitrogen اتش تدين تلاتة
+
+34
+00:03:34,990 --> 00:03:39,690
+أربعة رحزوج الإلكترونات و واحد منها دولة الارش هذا
+
+35
+00:03:39,690 --> 00:03:40,330
+الشكل ال
+
+36
+00:03:44,910 --> 00:03:52,370
+الأيون الموجة دائما بنتهيأ باسم ايش ات الايون
+
+37
+00:03:52,370 --> 00:03:57,030
+السالب كربونيت نيتريت سولفيت هذه الايونات السالبة
+
+38
+00:03:57,030 --> 00:04:02,470
+الايونات الموجة بنهيتها اونيوم امونيوم هيدرونيوم
+
+39
+00:04:02,470 --> 00:04:07,730
+اكزونيوم فوسفونيوم وضع ولذلك هذا ايش كان يتسمى
+
+40
+00:04:07,730 --> 00:04:08,470
+المركب
+
+41
+00:04:18,250 --> 00:04:23,590
+هذه النهاية onium نستعملها لأيون الموجة عشان ايه
+
+42
+00:04:23,590 --> 00:04:26,970
+لو بنيجي نسألكم the ending onium is used for
+
+43
+00:04:26,970 --> 00:04:31,210
+negative ions it's for the positive ions واضح
+
+44
+00:04:31,210 --> 00:04:36,670
+onium امونيوم اوزونيوم وهكذا الان هذا لما يكون
+
+45
+00:04:36,670 --> 00:04:40,350
+عليه مجموعات R بيقول فهذه الحالة
+
+46
+00:04:46,500 --> 00:04:50,560
+يعني عليها كام رابطة؟ أربع فبصير عندك ال
+
+47
+00:04:50,560 --> 00:04:54,200
+quaternary ammonium salts اللي هي R for N positive
+
+48
+00:04:54,200 --> 00:04:57,780
+أكيد طالما عندكوا N positive لازم يكون فيه معها
+
+49
+00:04:57,780 --> 00:05:04,580
+إيش؟ X سالبة واضح أكيد هيكون معها X سالبة وهذه
+
+50
+00:05:04,580 --> 00:05:08,560
+موجودة كثير الآن التشكيل العالمي ال nitrogen
+
+51
+00:05:08,560 --> 00:05:14,080
+compounds they are very importantin chemistry and
+
+52
+00:05:14,080 --> 00:05:19,060
+in biology يعني ال amino acids أساسي فيهم ال
+
+53
+00:05:19,060 --> 00:05:24,680
+nitrogen ال DNA ال RNA فيهم ال basis واضح ال
+
+54
+00:05:24,680 --> 00:05:29,920
+nitrogen basis اسمها ال alkaloids اللي هي المركبات
+
+55
+00:05:29,920 --> 00:05:32,300
+ال natural product اللي بتكون عادة
+
+56
+00:05:38,200 --> 00:05:44,760
+النيتروجين هو السبب ال basicity و لذلك بنسميها ال
+
+57
+00:05:44,760 --> 00:05:49,460
+caloids، ال caloids جاي من القالي، القالي يعني
+
+58
+00:05:49,460 --> 00:05:49,980
+قلوي
+
+59
+00:05:53,060 --> 00:05:59,080
+الان طبعا بالنسبة لخلاص ال amines كنا بنتذكر ان ال
+
+60
+00:05:59,080 --> 00:06:02,200
+nitrogen من أعلى السليبيات يعني ال hydrogen
+
+61
+00:06:02,200 --> 00:06:07,540
+bonding أساسا لما بنعرفه احنا بنربطه بتلت ذرات
+
+62
+00:06:07,540 --> 00:06:13,580
+أساسية إذا اتصلت ال hydrogen مع ال fluorine أو ال
+
+63
+00:06:13,580 --> 00:06:19,280
+oxygen أو ال nitrogen فهو أحد التلاتة اللي بيعملوا
+
+64
+00:06:19,280 --> 00:06:22,750
+hydrogen bondingواضح؟ ليش؟ لأن الـ
+
+65
+00:06:22,750 --> 00:06:26,650
+electronegativity للنيتروجين عالية حوالي تلاتة
+
+66
+00:06:26,650 --> 00:06:30,570
+فالـ unatched bond is very polar تعمل hydrogen
+
+67
+00:06:30,570 --> 00:06:33,710
+bonding is possible طالما في عندي hydrogen
+
+68
+00:06:33,710 --> 00:06:37,130
+bonding، إذا ال boiling points للأمين يفترض أن
+
+69
+00:06:37,130 --> 00:06:41,710
+تكون إيش؟ مرتفعة وزي ما قلنا طالما في عندي أزواج
+
+70
+00:06:41,710 --> 00:06:46,710
+إلكترونية على النيتروجين، إذا الـ nitrogen's are
+
+71
+00:06:46,710 --> 00:06:55,660
+basesالـ A كيف بنسمي ال Amines؟ ال Amines تسميتها
+
+72
+00:06:55,660 --> 00:07:01,720
+في ال IUPAC system سهلة مابنعطيهاش اسم عائلة
+
+73
+00:07:01,720 --> 00:07:07,680
+بنعتبرها substitute فبصير
+
+74
+00:07:07,680 --> 00:07:13,220
+أصل الاسم للألكين يعني زي ما الألكين على سبيل
+
+75
+00:07:13,220 --> 00:07:19,370
+المثال بنرسمه سلسلة من ستة، شو بنسميها؟هكسين لو
+
+76
+00:07:19,370 --> 00:07:23,370
+عليها على موقع اتنين كلور شو بيصير المقارنة two
+
+77
+00:07:23,370 --> 00:07:27,310
+chloro hexane الان لو عليها على موقع اتنين NH2
+
+78
+00:07:27,310 --> 00:07:34,830
+بنسميها two amino hexane فاحنا بنسمي المركبات ال
+
+79
+00:07:34,830 --> 00:07:40,250
+amines كأنها ال cans و بنستعمل ايش NH2
+
+80
+00:07:41,530 --> 00:07:47,430
+بنسميها إيش؟ قمائم الان يمكن هنا .. يمكن هنا البعض
+
+81
+00:07:47,430 --> 00:07:52,870
+يقول طب لو كانت مش هنقدش توقف، يعني هاي عندى ..
+
+82
+00:07:52,870 --> 00:07:58,310
+نفترض سلسلة بهذا الشكل، جدري نشوفها كام carbon؟
+
+83
+00:07:58,310 --> 00:08:01,970
+واحد، اتنين، تلاتة، اربعة، خمسة، ستة، ستة، ستة
+
+84
+00:08:01,970 --> 00:08:07,630
+الان لو افترضنا أن عندكم على هذا الموقع برومماذا
+
+85
+00:08:07,630 --> 00:08:12,850
+سنذكره إبراهيم إبراهيم طيب لو افترضنا الآن إنه على
+
+86
+00:08:12,850 --> 00:08:22,190
+هذا الموقع إجا عنده ال H2 امينو إيش هسميه امينو
+
+87
+00:08:22,190 --> 00:08:26,490
+امينو و بعدين هسمي الاسم طيب لو افترضت إنه اللي
+
+88
+00:08:26,490 --> 00:08:32,350
+إجت عنده مش NH2 NHCH3
+
+89
+00:08:39,710 --> 00:08:43,470
+هذا الشبكة بهذا الشكل من خلال الـ Nitrogen هذي إيش
+
+90
+00:08:43,470 --> 00:08:50,890
+اسمها؟ Amino طب لو كان الشبكة مجموعة NHCH3 ميثل
+
+91
+00:08:50,890 --> 00:08:59,150
+امايو طب لو الشبكة ن تنتل CH3 داي ميثل امايو،
+
+92
+00:08:59,150 --> 00:09:06,710
+واضح؟ إذن هذه المجموعة الـNH2 اسمها امايو الـNH
+
+93
+00:09:06,710 --> 00:09:07,570
+لحملة ميثل امايو
+
+94
+00:09:13,190 --> 00:09:20,990
+والألهج اللي حملة الدين مثل دايمثل
+
+95
+00:09:20,990 --> 00:09:32,110
+امايو و لذلك لو احنا بنانيجي نتطلع تكون عندنا مركب
+
+96
+00:09:43,560 --> 00:09:50,920
+تلاتة برومود اتنين تلاتة اربعة خمسة ستة تلاتة
+
+97
+00:09:50,920 --> 00:09:56,160
+برومود اتنين تلاتة اربعة خمسة ستة تلاتة برومود
+
+98
+00:09:56,160 --> 00:10:01,680
+اتنين تلاتة اربعة خمسة ستة اتنين تلاتة برومود
+
+99
+00:10:01,680 --> 00:10:02,240
+اتنين تلاتة برومود اتنين تلاتة برومود اتنين تلاتة
+
+100
+00:10:02,240 --> 00:10:02,460
+برومود اتنين تلاتة برومود اتنين تلاتة برومود اتنين
+
+101
+00:10:02,460 --> 00:10:02,680
+اتنين تلاتة برومود اتنين تلاتة برومود اتنين تلاتة
+
+102
+00:10:02,680 --> 00:10:03,440
+برومود ات
+
+103
+00:10:09,470 --> 00:10:13,950
+واضحين to dimethylaminohexane
+
+104
+00:10:58,850 --> 00:11:05,550
+الان بدنا نبحث عن أطول سلسلة ألفاتية أطول سلسلة
+
+105
+00:11:05,550 --> 00:11:08,750
+ألفاتية من 1،2،3،4
+
+106
+00:11:13,720 --> 00:11:19,620
+طبعا واحد اتنين تلاتة اربعة خمسة ستة بناء على ذلك
+
+107
+00:11:19,620 --> 00:11:25,680
+المركب اللي عندنا شو اسمه اكسين اكسين اكسين اكسين
+
+108
+00:11:25,680 --> 00:11:31,980
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+109
+00:11:31,980 --> 00:11:36,300
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+110
+00:11:36,300 --> 00:11:41,440
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+111
+00:11:41,440 --> 00:11:43,640
+اكسين اكسين اكسين اكسين اكسين اكسين اكسين اكسين
+
+112
+00:11:47,630 --> 00:11:54,130
+الكلام في موازاة ولا لأ اثل مع ال oxygen اثل مع ال
+
+113
+00:11:54,130 --> 00:11:59,830
+nitrogen اثل امينو الآن لما بنشوفه من بين اليوتيوب
+
+114
+00:11:59,830 --> 00:12:11,510
+أولا تلاتة اثل امينو هذه مجموعة اتنين اثوكسي
+
+115
+00:12:11,510 --> 00:12:18,910
+علمناها اكسير واضح؟يعني مش بس الأمور بتقف عند مثل
+
+116
+00:12:18,910 --> 00:12:23,370
+أمينو ضاي مثل أمينو ممكن يكون عندكم إثل أمينو ضاي
+
+117
+00:12:23,370 --> 00:12:28,670
+إثل أمينو بروبل أمينو مثلا ضاي بروبل أمينو وممكن
+
+118
+00:12:28,670 --> 00:12:31,870
+كمان اللي يكونوا على الأمينو يكونوا مجمعتين
+
+119
+00:12:31,870 --> 00:12:36,310
+مختلفتين بأذكر التنتين بأسمعهم يعني لو أقول إثل و
+
+120
+00:12:36,310 --> 00:12:41,210
+مثل شو هسمي المجموعة إثل مثل أمينو
+
+121
+00:12:43,590 --> 00:12:47,870
+يعني اللي اتعلم organic كويس خلاص بصير تحل المشاكل
+
+122
+00:12:47,870 --> 00:12:52,050
+اللي بتواجهه لوحده طب لو ذكرنا ال ethoxy قبل ال
+
+123
+00:12:52,050 --> 00:12:58,710
+ethyl اشتغل alphabetical لما حرف الأول مايمشيش
+
+124
+00:12:58,710 --> 00:13:02,710
+معاك امشي على اللي بعده واضح؟ إذا لاجيت أن ال
+
+125
+00:13:02,710 --> 00:13:08,230
+ethoxy سابق في ال alphabetical سبجيها واضح؟ يعني
+
+126
+00:13:08,230 --> 00:13:11,790
+ارجعوا للي كتبنا مين سابق ethyl ولا ethoxy
+
+127
+00:13:18,030 --> 00:13:24,370
+اللي بيشتغل براحته يرتب الأمور Alpha Beta, إيش ما
+
+128
+00:13:24,370 --> 00:13:27,630
+بتكون المجموعات، بمشي حرف حرفة، واضحة فيك
+
+129
+00:13:34,790 --> 00:13:39,210
+طبعا لاحظوا هنا مثلا إيجا مع كثول، ضال الأساس
+
+130
+00:13:39,210 --> 00:13:42,650
+الكثول، يعني واحد، اتنين، تلاتة، أربعة، هذا
+
+131
+00:13:42,650 --> 00:13:45,650
+بيوتالول، وانت بيوتالول، على نبرة اتنين، ابروم،
+
+132
+00:13:45,650 --> 00:13:51,190
+مثلا على نبرة أربعة، أمين، واضح الفكرة؟ لو كان مع
+
+133
+00:13:51,190 --> 00:13:54,270
+الديهيد أو كيتون، نفس الأشياء، لو مع carboxylic
+
+134
+00:13:54,270 --> 00:14:00,110
+acid، نفس الأشياء، ومن هنا هتبدأ تلاقوا مثلا ال
+
+135
+00:14:00,110 --> 00:14:02,190
+amino acids
+
+136
+00:14:03,900 --> 00:14:08,120
+لما ندرس البروتينات، البروتينات من إيش بشكل أساسي
+
+137
+00:14:08,120 --> 00:14:14,100
+متكونة؟ من ال amino acids فلما نيجي نسمي، لما نيجي
+
+138
+00:14:14,100 --> 00:14:19,920
+نسمي، حق نعتبر أنه إحنا في عندنا ال acid زي هيك
+
+139
+00:14:19,920 --> 00:14:28,140
+مثلا، سي ده بيكون OH لو بيجينا هنا CH وحطينا هنا
+
+140
+00:14:28,140 --> 00:14:31,960
+NH2 CH2
+
+141
+00:14:53,340 --> 00:14:57,800
+الان في البيو كيميستر اذا بدنا نعطي اسم glycine
+
+142
+00:14:57,800 --> 00:15:00,340
+بيصير اسم شهرة تاني
+
+143
+00:15:06,760 --> 00:15:12,160
+هذه بدأت تسمى a mind أو أسمي للكيتون أو للالدهاي
+
+144
+00:15:12,160 --> 00:15:13,880
+أو للالكوبول
+
+145
+00:15:29,090 --> 00:15:33,330
+واضح؟ هاي أمثلة إضافية، هاي أطول سلسلة تلاتة
+
+146
+00:15:33,330 --> 00:15:38,630
+بروبين، على نجرة واحد أماين، one a minor بروبين،
+
+147
+00:15:38,630 --> 00:15:45,200
+هذا بروبينto aminopropane واضح؟ الان لاحظوا معاك
+
+148
+00:15:45,200 --> 00:15:49,420
+طب لو كنا بيجينا ال common nomenclature ال common
+
+149
+00:15:49,420 --> 00:15:53,880
+nomenclature وعطيناها قاعدة عامة كلنا بنذكر اسم
+
+150
+00:15:53,880 --> 00:15:58,760
+المجموعة و بعدها عائلة يعني لو كان أنا كله كنا
+
+151
+00:15:58,760 --> 00:16:02,500
+نسميه propane، نسميه chloride لو بروم، نسميه
+
+152
+00:16:02,500 --> 00:16:06,080
+propane، نسميه bromide لو و أش، نسميه propane،
+
+153
+00:16:06,080 --> 00:16:06,560
+نسميه alcohol
+
+154
+00:16:09,400 --> 00:16:18,860
+هذا البروبل هو اسم المجموعة و بعدين امين هذا
+
+155
+00:16:18,860 --> 00:16:24,500
+البروبل هو ايزو بروبل
+
+156
+00:16:33,510 --> 00:16:37,930
+و هكذا واضح طبعا هذه ال common nouns هتكون في
+
+157
+00:16:37,930 --> 00:16:43,490
+المركبات اللي هي المجموعات اللي اتعلمناها مثل اثر
+
+158
+00:16:43,490 --> 00:16:47,310
+بربل ايزو بربل ايزو بيوتل تيرتشير بيوتل المجموعات
+
+159
+00:16:47,310 --> 00:16:50,510
+اللي اتعلمناها في أشياء مااخدنا لاش اس المجموعات
+
+160
+00:16:50,510 --> 00:16:54,310
+مش هتاخد ال common nomenclature هذا مثلا ستة على
+
+161
+00:16:54,310 --> 00:16:59,190
+بوضع اتنين امين اتنين امين او اكسين مش هتلاقي انه
+
+162
+00:16:59,190 --> 00:17:05,670
+اخدنا اس المجموعةواضح؟ طبعا فى ناس ممكن يقولوا عنه
+
+163
+00:17:05,670 --> 00:17:09,930
+two hex الأمين لإنه سهل شوية لكن بعد هيك لو هانصر
+
+164
+00:17:09,930 --> 00:17:15,010
+شغلة و شغلة خلاص بتسموه إيش؟ أيوبة بتسموه أيوبة
+
+165
+00:17:15,010 --> 00:17:19,450
+تمام واضحة فكرة ال أيوبة ال nomenclature و ال
+
+166
+00:17:19,450 --> 00:17:21,890
+common nomenclature ال common nomenclature أيضا
+
+167
+00:17:21,890 --> 00:17:28,090
+إلها trait العائلة المجموعة تسمى إيش؟ العائلة
+
+168
+00:17:28,090 --> 00:17:29,530
+واضح؟
+
+169
+00:17:31,820 --> 00:17:36,060
+هذا المُركّب لو بجنب عليه وأطول سلسلة فيه
+
+170
+00:17:39,800 --> 00:17:44,360
+إذا هذا problem على مين راح واحد حامل كل هذه
+
+171
+00:17:44,360 --> 00:17:48,640
+المجموعة؟ مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+172
+00:17:48,640 --> 00:17:49,660
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+173
+00:17:49,660 --> 00:17:51,140
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+174
+00:17:51,140 --> 00:17:54,640
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+175
+00:17:54,640 --> 00:17:57,260
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+176
+00:17:57,260 --> 00:17:57,600
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+177
+00:17:57,600 --> 00:18:04,580
+مثل مثل مثل مثل مثل مثل مثل
+
+178
+00:18:05,720 --> 00:18:11,160
+هك بيصير أسهل لكم one methyl aminopropane لكن لو
+
+179
+00:18:11,160 --> 00:18:15,180
+شفتواها مكتوبة بطريقة تانية مثل هذه الطريقة ال مثل
+
+180
+00:18:15,180 --> 00:18:20,580
+معناها أن المثل متصلة بإيش بالنيتروجين و كأنه هذا
+
+181
+00:18:20,580 --> 00:18:23,340
+one aminopropane
+
+182
+00:18:33,770 --> 00:18:36,790
+Dimethyl Amino Cyclohexane
+
+183
+00:19:11,700 --> 00:19:20,220
+الان CH2 CH3 الان عند سلسلة اتل و سلسلة اتل بتاخد
+
+184
+00:19:20,220 --> 00:19:24,120
+واحدة منهم خليني افترض ان هذا الاساس اللي بنيت
+
+185
+00:19:24,120 --> 00:19:30,260
+الاسم عليه واحد اتنين هذا عبارة عن ايش عبارة عن
+
+186
+00:19:30,260 --> 00:19:37,000
+اتل لو بتاخدوا هذه السلسلة CH2 CH3 اذا تمركب ايش
+
+187
+00:19:37,520 --> 00:19:44,480
+Ethane هذا الـ Ethane على ممر واحد شو بيحمل؟
+
+188
+00:19:44,480 --> 00:19:49,300
+بس one substitute كل هذه عبارة عن one substitute
+
+189
+00:19:49,300 --> 00:19:56,700
+انا اصلا المركب Ethane CH3 CH3 شيلت H وحطيت كل هذا
+
+190
+00:19:56,700 --> 00:20:01,320
+الكلام الآن بيصير هذه المجموعة بدي اسميها هذا
+
+191
+00:20:01,320 --> 00:20:09,940
+Ethane مثل Amineإثل مثل أمينو عشان تسمها إثل مثل
+
+192
+00:20:09,940 --> 00:20:14,880
+أمينو أو ضعف من عنده أن إثل يعني أنه اتبعوا إن
+
+193
+00:20:14,880 --> 00:20:20,980
+الإثل برسمة وين عن أن أن مثل و أين موجود هذا كله
+
+194
+00:20:20,980 --> 00:20:25,500
+على دمر واحد ولا اتنين هو واحد طبعا لو ماحطش
+
+195
+00:20:25,500 --> 00:20:29,320
+الواحد لما تكون إثل مافيش مشكلة لأن مافيش فيها إلا
+
+196
+00:20:29,320 --> 00:20:35,440
+تكون واحد لكن لو كبرت لازم واضح واضحفزي هيك بتسمو
+
+197
+00:20:35,440 --> 00:20:40,840
+ايش بتكتبوه يكون صحيح لو كتبتوا one أساس طريقة
+
+198
+00:20:40,840 --> 00:20:48,700
+أيكم ايش بتكتبوه one مثل مثل أمينو أمينو هذي
+
+199
+00:20:48,700 --> 00:20:54,240
+المجموعة اللي بالأحمر one و أمينو سن المجموعة مثل
+
+200
+00:20:54,240 --> 00:20:56,140
+أمينو و كله عبارة عن
+
+201
+00:21:00,110 --> 00:21:05,370
+واضح حتى لو لغينا ال one هنا ابتفها بس بالخاص انه
+
+202
+00:21:05,370 --> 00:21:08,490
+حد يروح يحطلنا ال ethyl و ال methyl باماكن تانية
+
+203
+00:21:08,490 --> 00:21:13,110
+عشان نحاول ايش نوضحهم او مرات خوف لو واحد ييجي
+
+204
+00:21:13,110 --> 00:21:17,370
+يصير و يحط ethyl و methyl هنا بيضيفوا كلمة ايش أن
+
+205
+00:21:17,370 --> 00:21:22,390
+انه يعني تأكيدا في انه ماتغلطوش يعني ان ال ethyl
+
+206
+00:21:22,390 --> 00:21:24,430
+على ال nitrogen ال methyl على
+
+207
+00:21:31,700 --> 00:21:35,460
+لو اتينا هنا بروبين على نمرة واحد امينو على نمرة
+
+208
+00:21:35,460 --> 00:21:42,140
+اتنين امينو، شو هيكون؟ هذا المركب واحد اتنين تلاتة
+
+209
+00:21:42,140 --> 00:21:47,100
+اربعة two-butanol على نمرة تلاتة امينو على نمرة
+
+210
+00:21:47,100 --> 00:21:51,920
+تلاتة مثل اي واحد اتنين تلاتة اربعة، ليش الترقيم
+
+211
+00:21:51,920 --> 00:21:58,930
+حببنا هنا؟ عشان القول تكون أفضل ما يمكن العائلةالـ
+
+212
+00:21:58,930 --> 00:22:02,370
+All بتكون أقل ما يمكن، هذا الـ Core، أساسه الـ
+
+213
+00:22:02,370 --> 00:22:06,250
+Core، واضح؟ فبدي أنا الـ OH تكون أقل ما يمكن، لو
+
+214
+00:22:06,250 --> 00:22:10,730
+ملقمت منها أنا الـ OH هتطلع على لبرة تلاتة، واضح؟
+
+215
+00:22:10,730 --> 00:22:14,770
+فهو عبارة عن الـ Good على لبرة تلاتة حامل أمينو
+
+216
+00:22:14,770 --> 00:22:16,410
+وعلى لبرة تلاتة حامل
+
+217
+00:22:25,780 --> 00:22:29,800
+طبعا زي ما حكينا بالنسبة ل ال common nomenclature
+
+218
+00:22:29,800 --> 00:22:35,480
+عادة بنذكر اسم المجموعة و بعدها بنحط ايش امين و
+
+219
+00:22:35,480 --> 00:22:44,420
+لذلك هذه CH3 and H2 مثل امين، هذي دايمثل امين،
+
+220
+00:22:44,420 --> 00:22:49,680
+الامين حملة كام مثل؟ تنتهي المجموعة دايمثل امين في
+
+221
+00:22:49,680 --> 00:22:52,400
+ممكن يكون ال try مثل امين
+
+222
+00:23:00,290 --> 00:23:02,170
+كله اسمه amine باسم مُركّب
+
+223
+00:23:02,170 --> 00:23:28,830
+نيتروجينكتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناتراميناترام
+
+224
+00:23:29,650 --> 00:23:35,910
+إنه هذه ethyl و ethyl و ethyl و ethyl و ethyl و
+
+225
+00:23:35,910 --> 00:23:41,010
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+226
+00:23:41,010 --> 00:23:43,710
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+227
+00:23:43,710 --> 00:23:44,510
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+228
+00:23:44,510 --> 00:23:45,090
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+229
+00:23:45,090 --> 00:23:45,670
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+230
+00:23:45,670 --> 00:23:51,290
+ethyl و ethyl و ethyl و ethyl و ethyl و ethyl و
+
+231
+00:23:51,290 --> 00:23:54,950
+ethyl و ethyl و
+
+232
+00:23:59,000 --> 00:24:03,700
+بتذكرهم alphabetical اثل مثل امين الافضل
+
+233
+00:24:03,700 --> 00:24:11,320
+alphabetical يعني اثل مثل اثل مثل امين الخلاصة انه
+
+234
+00:24:11,320 --> 00:24:15,740
+التسمية بال common nomenclature التسمية بال common
+
+235
+00:24:15,740 --> 00:24:19,860
+nomenclature بنذكر فيها اسم المجموعة و بعدين بننهي
+
+236
+00:24:19,860 --> 00:24:26,770
+بالنهاية امين اللي هي العائلة واضح؟فزي ما بتلاحظوا
+
+237
+00:24:26,770 --> 00:24:30,890
+الأمينز أكتر من تسمية لهم أشهر نظام الـ Iopaque
+
+238
+00:24:30,890 --> 00:24:34,350
+أنه نعتبرهم ألكين وهي أمثلة إضافية حتى أنه
+
+239
+00:24:34,350 --> 00:24:39,310
+اترجعوها ال Iopaque بنذكرهم ألكينزي ال common
+
+240
+00:24:39,310 --> 00:24:46,450
+بنذكر المجموعة ثم العائلة الأهم في نظام تسمية تالت
+
+241
+00:24:46,450 --> 00:24:47,850
+حسب ال chemical abstract
+
+242
+00:25:06,820 --> 00:25:13,020
+بس لما بيسميه بيسميش طبعا مركب رباع بيوت الأمين لأ
+
+243
+00:25:13,020 --> 00:25:21,000
+بيسميه بيوتان أمينبعرفش إذا دي واضحة ولا بنزم أني
+
+244
+00:25:21,000 --> 00:25:27,160
+أوضحها أكتر لكم يعني خليني
+
+245
+00:25:27,160 --> 00:25:35,080
+أخد هذا المركب و أحط هنا OH عشان أنتوا تنتبهوا لما
+
+246
+00:25:35,080 --> 00:25:41,600
+أنا كنت أسمي هذا بيوتان
+
+247
+00:25:48,620 --> 00:25:56,180
+و أحطله one هذا ال IOPAC منه الان لما كنت أسميه
+
+248
+00:25:56,180 --> 00:26:04,600
+بال common nominative شو كنت أسميه؟ butyl و أحط
+
+249
+00:26:04,600 --> 00:26:12,820
+العائلة alcohol butyl alcohol okay butyl alcohol
+
+250
+00:26:12,820 --> 00:26:17,360
+الان الناس اللي بيعملوا على نظام تسمية تالف
+
+251
+00:26:21,690 --> 00:26:28,830
+عندي nh2، بدي أعطي العائلة أمين، يعني نغير هذه
+
+252
+00:26:28,830 --> 00:26:36,910
+نخليها nh2، فبصير بيوتان أمين، طب وهذا بيوت
+
+253
+00:26:36,910 --> 00:26:43,790
+الأمين، واضح تلاحظين أنه الفرق ما بينبيوتان و
+
+254
+00:26:43,790 --> 00:26:47,870
+بيوتين في كل الأحوال هذا النظام مابتيش يقتصر معالي
+
+255
+00:26:47,870 --> 00:26:51,730
+لكن مرات بنذكر أشياء اللي لو قرأتوها ماتحسوش
+
+256
+00:26:51,730 --> 00:26:54,790
+باستغراب احنا اللي بدنا نسمي عليه the iopac
+
+257
+00:26:54,790 --> 00:27:00,230
+nomenclature ان مراكبات ال amines بتتبع الalkenes
+
+258
+00:27:00,230 --> 00:27:04,490
+هي مشتقات للalkenes و لو كنا بتناقلكم ال common
+
+259
+00:27:04,490 --> 00:27:07,730
+nomenclatures تبعها فبنكتم المجموعة و بعدين ال
+
+260
+00:27:07,730 --> 00:27:14,400
+amine لكن لو قرأتوا اشي تانيما تستمر مش واضح؟
+
+261
+00:27:14,400 --> 00:27:19,940
+باختصار المركبات تبعت ال amines تتبع عائلة ال
+
+262
+00:27:19,940 --> 00:27:23,720
+alkanes يعني نهيتها إيفين بروبين بيوتين هكسل
+
+263
+00:27:23,720 --> 00:27:29,140
+whatever طبعا مركبات ال amines في الدنيا كتيرة
+
+264
+00:27:29,140 --> 00:27:33,700
+كلها مركبات في الكيميا الحلقية مش بطلب نحفظها بس
+
+265
+00:27:33,700 --> 00:27:38,100
+حتى تحسوا كدهش موضوع ال nitrogen موضوع واسع يعني
+
+266
+00:27:38,100 --> 00:27:43,010
+يمكن تقوله ربع الكيميا العضوية المركبات معاهواضح؟
+
+267
+00:27:43,010 --> 00:27:47,110
+البُركّب هذا الوحيد يمكن يعرفي أنه البنزينة اللي
+
+268
+00:27:47,110 --> 00:27:54,630
+عليها الأن H2O هي عبارة عن أنيليا الأن بالنسبة للـ
+
+269
+00:27:54,630 --> 00:27:59,010
+physical properties of amines بشكل عام احنا بيقول
+
+270
+00:27:59,010 --> 00:28:03,680
+أن ال physical properties ofhydrogen bonding
+
+271
+00:28:03,680 --> 00:28:10,440
+وبالتالي من ناحية من ناحية من ناحية مقارنة ال
+
+272
+00:28:10,440 --> 00:28:14,340
+boiling point تبعتهم يفترض انها ليش تكون عالية
+
+273
+00:28:14,340 --> 00:28:18,820
+مرتفعة طبعا اللي بده يعمل المقارنة ويفهمها جيدا
+
+274
+00:28:18,820 --> 00:28:24,120
+بده يقارن مع إشي مافيش فيه hydrogen bonding يعني
+
+275
+00:28:24,120 --> 00:28:26,640
+إشي فيه hydrogen bonding وإشي مافيه hydrogen
+
+276
+00:28:26,640 --> 00:28:29,200
+bonding وبده يوحد العوامل التانية
+
+277
+00:28:38,870 --> 00:28:42,670
+طب هذا ليش مرتفع كتير اكتر من هذا؟ بطل ال
+
+278
+00:28:42,670 --> 00:28:46,450
+molecular weight هو السبب و قداش بديكون السبب ال
+
+279
+00:28:46,450 --> 00:28:52,910
+hydrogen بدي ولذلك هلأ اعمللكم مثال كتير جميل أخد
+
+280
+00:28:52,910 --> 00:28:58,830
+من ال alkanes ال ethane و لاحظوا عندى ال ethane ال
+
+281
+00:28:58,830 --> 00:29:03,540
+molecular weight تبعه قداش تلاتينكامهم كامهم 12,
+
+282
+00:29:03,640 --> 00:29:09,400
+12, 24, 26 هيدروجين تلاتين و أخد الميث الأمين
+
+283
+00:29:09,400 --> 00:29:15,520
+الميث الأمين لو حسبنا ال molecular weight 31 هذا
+
+284
+00:29:15,520 --> 00:29:21,160
+أمين هذا الكلب و أخد الميثانول ال alcohol ال
+
+285
+00:29:21,160 --> 00:29:28,740
+molecular weight تبعه 32تجاوزا او تقريبا التلاتين
+
+286
+00:29:28,740 --> 00:29:31,640
+في ال molecular weight زي الواحد و التلاتين زي
+
+287
+00:29:31,640 --> 00:29:36,260
+الاتنين و التلاتين إذا هدولة التلات مراكبات equal
+
+288
+00:29:36,260 --> 00:29:39,040
+بالنسبالي .. اللي هم equal molecular weight فلو
+
+289
+00:29:39,040 --> 00:29:43,380
+اختلفوا بال boiling point هيكون اختلاف بسبب ال
+
+290
+00:29:43,380 --> 00:29:47,920
+molecular weight لأ لأ بنفتش على إشي تاني الآن لو
+
+291
+00:29:47,920 --> 00:29:53,480
+إجهنا اتطلعنا على قداش ال boiling point اللي هو
+
+292
+00:29:55,080 --> 00:30:04,760
+هنلاحظ ان الاثان ناقص 88 المثل أمين ناقص 6 جديش
+
+293
+00:30:04,760 --> 00:30:12,340
+زاد المثل أمين عن الاثان من ناقص 88 لناقص 6 82
+
+294
+00:30:12,340 --> 00:30:20,660
+درجة82 درجة هذا زيادة من وين نجوله الـ 82 درجة من
+
+295
+00:30:20,660 --> 00:30:26,940
+الهيدروجين البونديني الان الميثانول 65 جداش زاد
+
+296
+00:30:26,940 --> 00:30:34,560
+الميثانول عن الميثين احسبوا 88 و 65 حوالي 140 درجة
+
+297
+00:30:34,560 --> 00:30:39,320
+من وين نجول 140 درجة من الهيدروجين البونديني طبعا
+
+298
+00:30:39,320 --> 00:30:43,160
+ممكن واحدة تيجي تتساءل ما هو مش كل هيدروجين
+
+299
+00:30:43,160 --> 00:30:49,270
+بوندينيزي بعضه، يعني مع ال مثل أمين زادت ال
+
+300
+00:30:49,270 --> 00:30:53,230
+boiling point، لكن كده زادت؟ تمانين درجة، مع
+
+301
+00:30:53,230 --> 00:30:56,970
+الميثانول زادت ال boiling point، كده زادت؟ مية و
+
+302
+00:30:56,970 --> 00:31:00,690
+أربعين درجة، اه ما احنا بنعرف أن ال oxygen
+
+303
+00:31:00,690 --> 00:31:07,780
+السليلية تبعته أعلى من ال nitrogenواضح؟ ولذلك الـ
+
+304
+00:31:07,780 --> 00:31:11,140
+hydrogen bonding اللي موجود في حالات ال oxygen
+
+305
+00:31:11,140 --> 00:31:14,980
+أكتر من اللي في ال nitrogen فارتفاع رخطة الغليان
+
+306
+00:31:14,980 --> 00:31:18,900
+لمركب في oxygen بيكون أكتر من اللي مركب في
+
+307
+00:31:18,900 --> 00:31:23,320
+nitrogen في كل الأحوال .. في كل الأحوال المركبين
+
+308
+00:31:23,320 --> 00:31:25,780
+أشمالهم مرتفعين
+
+309
+00:31:27,590 --> 00:31:33,390
+عشان اقولك انه في عندك ناقص 88 للإيثين وقاعدة
+
+310
+00:31:33,390 --> 00:31:38,970
+بتزيد الحرارة لما صارت مثل الامين ناقص 6 ولا ..
+
+311
+00:31:38,970 --> 00:31:47,650
+ناقص 6 ارتفاع 80 درجة لما قولت ميثانون زائد 65 هذا
+
+312
+00:31:47,650 --> 00:31:51,510
+ارتفاع و هذا ارتفاع لكن الارتفاع الناشئ عن
+
+313
+00:31:51,510 --> 00:31:52,470
+الأكسجين
+
+314
+00:31:55,140 --> 00:31:59,080
+النيتروجين انا مابتش انسى ان الـ electronegativity
+
+315
+00:31:59,080 --> 00:32:01,840
+للأكسجين تلاتة و نص ال electronegativity
+
+316
+00:32:01,840 --> 00:32:07,480
+للنيتروجين تلاتة فلأنه السليبية لأن الأكسجين أعلى
+
+317
+00:32:07,480 --> 00:32:09,520
+فال hydrogen bonding اللي فيه
+
+318
+00:32:13,840 --> 00:32:17,520
+الارتفاع ارتفاع وهيدروجين bonding هيدروجين bonding
+
+319
+00:32:17,520 --> 00:32:22,320
+واضح لكن لو جيت بتهاجأت أسألكوا تحديدًا ليش
+
+320
+00:32:22,320 --> 00:32:26,460
+الميثانول أعلى من الميث الأمين؟ هنال أكسجين؟ اه
+
+321
+00:32:26,460 --> 00:32:30,000
+مالكشنش يقولولي هيدروجين bonding أنا فيه هيدروجين
+
+322
+00:32:30,000 --> 00:32:33,920
+bonding وانا فيه هيدروجين bonding لأن السالبية
+
+323
+00:32:33,920 --> 00:32:38,000
+للأكسجين أعلى فالهيدروجين bonding تبعه أقل
+
+324
+00:32:47,850 --> 00:32:55,250
+المقارنة نفسها تماما بس تختلف القيامة، واضح؟ فال
+
+325
+00:32:55,250 --> 00:33:00,110
+alcohol بتكون أعلى من ال amines أعلى كتير كتير من
+
+326
+00:33:00,110 --> 00:33:09,370
+ال alkyls، والسبب الhydrogen bonyالان كيف بنحضر ال
+
+327
+00:33:09,370 --> 00:33:14,330
+amines؟ نسبة من هذه الطرق اللي هي طرق تحضير ال
+
+328
+00:33:14,330 --> 00:33:19,830
+amines مرت معنا على سبيل المثال المرة الماضية لما
+
+329
+00:33:19,830 --> 00:33:25,130
+درسنا ال amides أخدنا أن ال production of amides
+
+330
+00:33:25,130 --> 00:33:29,490
+produces amine، produces amine، ان هذا ال c double
+
+331
+00:33:29,490 --> 00:33:36,270
+point هو تشفت CHOإذا إحدى طرق تحضير الأمين
+
+332
+00:33:36,270 --> 00:33:41,230
+reduction of amides واضح؟ reduction of amides
+
+333
+00:33:41,230 --> 00:33:47,290
+produces amines طبعا الناس الشطرين ما بدهم يشيفوا
+
+334
+00:33:47,290 --> 00:33:52,010
+عند هذه النقطة بيقدروا يرجعوا لورا كام خطوة جد ما
+
+335
+00:33:52,010 --> 00:33:59,390
+بدهم بمعنى الأمد من وين جاي؟ من الاسد والاسد إيه
+
+336
+00:33:59,390 --> 00:34:00,650
+طرق تحضيره؟
+
+337
+00:34:02,750 --> 00:34:07,250
+كان في عنده طرق تساوي و طرق زيادة و .. كل هذا
+
+338
+00:34:07,250 --> 00:34:12,890
+الكلام بدي أنتبهله يعني لو أنا طلبت بيكم amines من
+
+339
+00:34:12,890 --> 00:34:20,710
+ال amide فهذا هو السؤال السهل، الآن ممكن أرجعه بال
+
+340
+00:34:20,710 --> 00:34:28,330
+amine من ال acid؟ طب ال acid من إيش؟ مثلا من
+
+341
+00:34:28,330 --> 00:34:35,080
+الكحول، طريقة التساويأو الـ Dehydrate بطريقة
+
+342
+00:34:35,080 --> 00:34:40,600
+التساوي أو RX و بزيد عليها CO2 ولا بزيد عليها
+
+343
+00:34:40,600 --> 00:34:48,320
+Greenium CN أو من الكيل والكيل بحط عليه بعد هيك
+
+344
+00:34:48,320 --> 00:34:52,660
+Alcohol أو بحط عليه بيئة بمعنى كل الكيميا اللي قبل
+
+345
+00:34:52,660 --> 00:34:57,450
+اللي أعطينا عليها أمثلة كيف تحضروا ال acidبتصير
+
+346
+00:34:57,450 --> 00:35:02,530
+بعد هيك تلقاء الأسد بيصير أمد و الأمد بيصير أمين
+
+347
+00:35:02,530 --> 00:35:07,670
+فمش ضروري أنه هنا بتصير اللي هو الناس الشطريين
+
+348
+00:35:07,670 --> 00:35:11,270
+اللي بدوا يقعدوا بينهم بين نفسهم يفكروا لمدة نص
+
+349
+00:35:11,270 --> 00:35:15,350
+ساعة ساعة يتخيلوا كيف ممكن ينسقلوا في هذه المنطقة
+
+350
+00:35:15,350 --> 00:35:21,270
+مش بس يقولوا أنه والله الأمين من الأمد، كويس، و
+
+351
+00:35:21,270 --> 00:35:27,880
+الأمد من الأسد، و الأسدراجعوا الخمس طرق تبعونه
+
+352
+00:35:27,880 --> 00:35:32,840
+الان كل نقطة بداية بيحطل الإنسان يقولكم كيف منها
+
+353
+00:35:32,840 --> 00:35:39,440
+بتحضروا amines إذا الطالب ماعملش هالكلام لوحده
+
+354
+00:35:39,440 --> 00:35:45,660
+باستمتاع واجع ما نبدأ به لل acid و بعدين ال acid و
+
+355
+00:35:45,660 --> 00:35:49,940
+بعدين ال amide و بعدين ال amine مش هيتعلم واضحة
+
+356
+00:35:49,940 --> 00:35:55,760
+الفكرة؟ الان بيجينا ال aromatic amineاللي هو
+
+357
+00:35:55,760 --> 00:36:00,440
+الأليلين الآن لاحظوا من الأخطاء الشائعة دايما لما
+
+358
+00:36:00,440 --> 00:36:05,240
+نقول حضرونا الأليلين أنه أي حد فيكم بالذات إذا كنا
+
+359
+00:36:05,240 --> 00:36:10,640
+الأليلين من البنزين how can you prepare أليلين
+
+360
+00:36:10,640 --> 00:36:18,080
+starting from بنزين أكبر غلطة ممكن تعملوا عندكوا
+
+361
+00:36:18,080 --> 00:36:21,020
+تقولوا زي هيك و تيشوا تكتبوا لأنهاتين three
+
+362
+00:36:24,650 --> 00:36:30,170
+طبعا ليش هذه أكبر غلطة في الدنيا لأنه احنا اتفقنا
+
+363
+00:36:30,170 --> 00:36:36,770
+ان البنزين عبارة عن سحابة إلكترونية سالب السالب لا
+
+364
+00:36:36,770 --> 00:36:43,130
+يستطيع ان يهاجم عليه سالب ولذلك لا يمكن ان نيجي
+
+365
+00:36:43,130 --> 00:36:47,430
+نقول بدنا نجيب الأمونيا السالبة على البنزين السالب
+
+366
+00:36:47,430 --> 00:36:48,610
+ونحضر هذا الكلام
+
+367
+00:36:52,670 --> 00:36:56,730
+بنقول حضرولنا الانيلين من البنزين ماحدش يقول بنزين
+
+368
+00:36:56,730 --> 00:37:01,630
+زايد أمونيا أنيلين إيش من يجلبوا الأمونيا هنا إما
+
+369
+00:37:01,630 --> 00:37:05,450
+إذا كنتوا أقطام المغناطيس اللي زي بعض الشمالي
+
+370
+00:37:05,450 --> 00:37:09,650
+والشمالي بتاعون ألعاب الأطفال جربوهم مع بعض كيف
+
+371
+00:37:09,650 --> 00:37:15,530
+بيكونوا جاعدين نفس الشي هذا سهل وسهلعمرهم هيقدروا
+
+372
+00:37:15,530 --> 00:37:19,850
+يجربوا على بعض؟ لأ، إذا هذه الطريقة غير سليمة
+
+373
+00:37:19,850 --> 00:37:24,950
+إطلاقا لإنه محضر من خلالها الأدلين طب ها إيش
+
+374
+00:37:24,950 --> 00:37:29,310
+الطريقة السليمة؟ الطريقة السليمة إنه إحنا محضر
+
+375
+00:37:29,310 --> 00:37:34,230
+الـNitro Benzene هذا من الـHNO3 و الـH2SO4
+
+376
+00:37:34,230 --> 00:37:40,210
+اتعلمناه بعدين الـNitro Benzene الـNitro Benzene
+
+377
+00:37:40,210 --> 00:37:46,490
+بال reductionبنضيف عليها هيدروجين reduction
+
+378
+00:37:46,490 --> 00:37:52,470
+بالهيدروجين هيدروجينونيكل مثلا بتحول إلى إيش؟
+
+379
+00:37:52,470 --> 00:37:59,090
+الانيلين إذا الانيلين من البنزين يمر تأكيدا عبر
+
+380
+00:37:59,090 --> 00:38:04,390
+النيترو بنزين لما نقول بدنا انيلين من البنزين
+
+381
+00:38:04,390 --> 00:38:12,070
+بتكون قولولي المسار بنزين نيترو بنزين انيلين
+
+382
+00:38:14,070 --> 00:38:20,930
+وقع الفكرة هذا هو المسار بنزين نايترو بنزين قليل
+
+383
+00:38:20,930 --> 00:38:29,950
+الآن لبس ان انا اضيفلكم هنا كمان معلومة كتير مهمة
+
+384
+00:38:29,950 --> 00:38:32,990
+مر
+
+385
+00:38:32,990 --> 00:38:40,250
+علينا طبعا هنا قلنا HRO3H2O4 مر علينا الفيلول
+
+386
+00:38:41,480 --> 00:38:46,700
+بتعرفوا ال phenol؟ اه لو اتينا و قولنالكم how can
+
+387
+00:38:46,700 --> 00:38:52,560
+you prepare phenol يعني
+
+388
+00:38:52,560 --> 00:39:00,160
+هنا OH starting from بنزين كيف
+
+389
+00:39:00,160 --> 00:39:05,780
+تحضر ال phenol من البنزين؟ الآن أكبر غلط ممكن
+
+390
+00:39:05,780 --> 00:39:08,820
+الواحد يعمله إيش؟ يقول بنزين
+
+391
+00:39:17,390 --> 00:39:24,350
+- أزواج إلكترونال ليش؟ لأن هذا السالب لا يهاجم على
+
+392
+00:39:24,350 --> 00:39:30,770
+هذا السالب إذن مش ممكن أقول البنزين .. مش ممكن
+
+393
+00:39:30,770 --> 00:39:34,290
+أقول البنزين فعله مع الـ OH بيعطينا فينول أول ما
+
+394
+00:39:34,290 --> 00:39:40,830
+جالبهم OH على بنزين بتنافر واضح؟ إذن لابد من طريقة
+
+395
+00:39:40,830 --> 00:39:46,880
+تانيةلتحضير الفينول هذه الطريقة التالية لتحضير
+
+396
+00:39:46,880 --> 00:39:51,680
+الفينول بتمشي عبر هذا المسار تمام عبر هذا المسار
+
+397
+00:39:51,680 --> 00:39:58,820
+بيقول بنزين نيترو بنزين أنيلين و بعدين بدي كمان
+
+398
+00:39:58,820 --> 00:40:05,440
+reactions هنا بحط نمرة واحد NKF2 صوديوم نيترايت
+
+399
+00:40:05,440 --> 00:40:09,980
+تمام و نمرة اتنين بحط H2O
+
+400
+00:40:13,640 --> 00:40:22,220
+أش فبصير الفيلول من البنزين سلسله أطول كمان بنزين
+
+401
+00:40:22,220 --> 00:40:30,200
+نيترو بنزين أنيلين فيلول واضح؟ فأي تحضير الأنيلين
+
+402
+00:40:30,200 --> 00:40:34,640
+من البنزين عبر نيترو بنزين؟ وتحضير الفيلول من
+
+403
+00:40:34,640 --> 00:40:39,700
+البنزين عبر نيترو بنزين أنيلين فيلول هانا ال
+
+404
+00:40:39,700 --> 00:40:41,640
+reduction دايما باستعمال أش
+
+405
+00:40:44,660 --> 00:40:51,720
+مع metal زي ال nickel او ما شبه و هذا كثير مرات
+
+406
+00:40:51,720 --> 00:40:56,020
+بتجيبوا .. بتجيبوا يا سؤال صح و غلط اكمل معادلة
+
+407
+00:40:56,020 --> 00:40:59,440
+فيلون can be prepared from the reaction مثلا of
+
+408
+00:40:59,440 --> 00:41:04,260
+بنزين والسوديوم هيدروكسايد هو السوديوم هيدروكسايد
+
+409
+00:41:04,260 --> 00:41:13,990
+COH- خطأ خطأ خطأ إلو إيش سلسلة متتاليةزي سلاسل
+
+410
+00:41:13,990 --> 00:41:19,530
+الرواد في علم الحديث، عارفينها؟ سلسلة ذهبية وسلسلة
+
+411
+00:41:19,530 --> 00:41:26,410
+كذا، وراوة النعمان وعنمان السماء، كيف يروي مالك عن
+
+412
+00:41:26,410 --> 00:41:32,590
+أنسى طيب،
+
+413
+00:41:32,590 --> 00:41:37,820
+كام طريقة هيك منكون أخدنا لتحضير الأمينس؟Tintin من
+
+414
+00:41:37,820 --> 00:41:41,980
+الـ Amides وتحضير الـ aromatic amines من الـ
+
+415
+00:41:41,980 --> 00:41:47,620
+Nitrobenzene الآن في عندى طريقة تالتة reduction of
+
+416
+00:41:47,620 --> 00:41:53,120
+cyanide يعني الـCN هذه هي عبارة عن إيش لو إحنا
+
+417
+00:41:53,120 --> 00:42:02,680
+طلعنا عليها C driven on Nلو طفنا عليها هيدروجين
+
+418
+00:42:02,680 --> 00:42:08,860
+هيكتبلكوا 4H طبعا 4H هذي بتيجينا غالبا من Lithium
+
+419
+00:42:08,860 --> 00:42:12,600
+Aluminum Hydride الهيدروجين مش هذا مصدق ده
+
+420
+00:42:12,600 --> 00:42:19,040
+هيدروجين، هتنقضوا بالبند وتحطوا H وH و تنقضوا كمان
+
+421
+00:42:19,040 --> 00:42:21,800
+بند وتحطوا H وH
+
+422
+00:42:23,770 --> 00:42:29,050
+صارت عبارة عن أميل، إذا ال reduction of nitro
+
+423
+00:42:29,050 --> 00:42:32,410
+compounds في الغضب لل triple bonds البايبل دي
+
+424
+00:42:32,410 --> 00:42:38,310
+الأولى والبايبل دي التانية بنتهي CH2NH2 هل كانت CE
+
+425
+00:42:38,310 --> 00:42:42,830
+N؟ ضيفنا H وH وH وH وH وH وH وH وH وH وH وH وH وH
+
+426
+00:42:42,830 --> 00:42:45,870
+وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH
+
+427
+00:42:45,870 --> 00:42:46,050
+وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH
+
+428
+00:42:46,050 --> 00:42:46,310
+وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH وH
+
+429
+00:42:46,310 --> 00:42:50,930
+وH وH وH وH وH وH وH وH وH وH وH وH وH وH وبترجع
+
+430
+00:42:50,930 --> 00:43:00,150
+خطوة لبرا هذه مثلا كانت CH3CL مع CL minus بالإبدال
+
+431
+00:43:00,150 --> 00:43:10,390
+بتحل ال CL محل ال CL بتحل ال CL محل ال CL إذا من
+
+432
+00:43:10,390 --> 00:43:16,250
+ال highlights كنا نبدل ال CL و ال PR بCL بعد هيك
+
+433
+00:43:16,250 --> 00:43:19,430
+ال CL بنضيف عليها هيدروجين نعملها reduction
+
+434
+00:43:28,380 --> 00:43:34,500
+أخر طريقة أخدناها عشان يكب نذكرها بدقيقة لما أخدنا
+
+435
+00:43:34,500 --> 00:43:38,820
+chapter ال Rx لو قلنا لكم أكمل المعادلة لغاية كل
+
+436
+00:43:38,820 --> 00:43:42,660
+هدول اللي قدامكم بس عشان تتأكدوا أن احنا أخدناها
+
+437
+00:43:42,660 --> 00:43:52,500
+قلنا لكم CH3 CH2PR هذا عبارة عن إيش الكلهلان زائد
+
+438
+00:43:52,500 --> 00:43:59,100
+NH3 ال Euclidean 5كيف كنتوا تكملوا هذه المعادلة؟
+
+439
+00:43:59,100 --> 00:44:04,820
+امير او اموريا مع هالك اللي lied الـ eucleophilic
+
+440
+00:44:04,820 --> 00:44:13,260
+substitution اللي بدأ بوضوع شبطة ستة CH3 CH2 و هذا
+
+441
+00:44:13,260 --> 00:44:16,560
+ال neutral ال eucleophil دائما بيفقد H
+
+442
+00:44:21,410 --> 00:44:26,030
+أي مشتقة أمونيا المهم يكون فيها على أقل تقدير أتش
+
+443
+00:44:26,030 --> 00:44:29,450
+يعني المهم
+
+444
+00:44:29,450 --> 00:44:34,330
+يكون عندكم إيش أتش عشان الأتش تفقد أمين زي الأكل
+
+445
+00:44:34,330 --> 00:44:40,790
+هلاي بعمل إبداع وهذا حلنا عليه مسائل كتير في الفصل
+
+446
+00:44:40,790 --> 00:44:47,330
+السادسهذه أيضًا طريقة و عليها مثالين توضحيين
+
+447
+00:44:47,330 --> 00:44:52,970
+عندكم، اللي هي طريقة إبدال على ال الكلهيلات، طريقة
+
+448
+00:44:52,970 --> 00:44:57,510
+الإبدال على ال الكلهيلات، يعني لاحظوا هذا ال
+
+449
+00:44:57,510 --> 00:45:03,850
+الكلهيلات وينه؟ المثل أيضاري، بجيب بداله الأمين،
+
+450
+00:45:03,850 --> 00:45:05,850
+هذه الأمين، اتجه الآن
+
+451
+00:45:09,910 --> 00:45:15,350
+لأ هو بهذا المثال هاي ال kilohydride هاي ال PR إيش
+
+452
+00:45:15,350 --> 00:45:18,790
+في عنده هنا ال unatomobiles ال unatomobiles خلّى
+
+453
+00:45:18,790 --> 00:45:25,250
+الآن نتاجر تجربة ال PR و إذا بتعمل إيش حلقات صار
+
+454
+00:45:25,250 --> 00:45:30,470
+عندى مركب النكوتين هذا المركب النكوتين كيف نحطه
+
+455
+00:45:30,470 --> 00:45:35,190
+نكوتين السجاني في كل الأحوال ال unat
+
+456
+00:45:39,910 --> 00:45:43,910
+الـ PR أو الـ CL ابتفعوا الإدالة، فطرق تحضير
+
+457
+00:45:43,910 --> 00:45:49,370
+الأمين استلخيصا من الـ Amides، من الـ CL، من
+
+458
+00:45:49,370 --> 00:45:52,690
+الإدالة محل الـ Halogens، والـ Aromatic أمين
+
+459
+00:45:52,690 --> 00:45:58,190
+باختزال الـ Nitrobenzene، واضحة الفكرة؟ إن شاء
+
+460
+00:45:58,190 --> 00:45:58,290
+الله
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..97446cc63ea6fa0d0d19aa97472ba5e031d7b545
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/E7VyTXNPHOg_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4981, "start": 24.69, "end": 49.81, "text": "الحدي عشر في جزء الكيميا الرجوية العادى قبل ما ننتقل لمقدمة البيت الاسطي اللى هو بعنوان amines amines يعني مركبات ال nitrogen المركبات اللى فيها ال nitrogen طبعا كلنا عارفين ان ال amine او ال nitrogen", "tokens": [6027, 5016, 16254, 6225, 46309, 8978, 10874, 11622, 38207, 33251, 32640, 25528, 34892, 7435, 2407, 10632, 18863, 18513, 7578, 12174, 36150, 19446, 8717, 29399, 4587, 1211, 32767, 28543, 46007, 2423, 21292, 2655, 2423, 32277, 9566, 1829, 13672, 7578, 31439, 4724, 3615, 1863, 2407, 7649, 669, 1652, 669, 1652, 37495, 22653, 3714, 31747, 3555, 9307, 2423, 17903, 9673, 31747, 3555, 9307, 13672, 7578, 8978, 11296, 2423, 17903, 23032, 3555, 3615, 995, 28242, 8315, 6225, 9640, 5172, 9957, 16472, 2423, 669, 533, 1975, 2407, 2423, 17903], "avg_logprob": -0.29025735013625203, "compression_ratio": 1.7608695652173914, "no_speech_prob": 5.125999450683594e-06, "words": [{"start": 24.69, "end": 24.99, "word": 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"end": 1628.33, "word": " amine", "probability": 0.764404296875}, {"start": 1628.33, "end": 1628.93, "word": " لكن", "probability": 0.88525390625}, {"start": 1628.93, "end": 1629.25, "word": " لو", "probability": 0.986328125}, {"start": 1629.25, "end": 1629.77, "word": " قرأتوا", "probability": 0.9228515625}, {"start": 1629.77, "end": 1630.09, "word": " اشي", "probability": 0.7198893229166666}, {"start": 1630.09, "end": 1630.59, "word": " تاني", "probability": 0.9772135416666666}], "temperature": 1.0}, {"id": 58, "seek": 166128, "start": 1631.74, "end": 1661.28, "text": "ما تستمر مش واضح؟ باختصار المركبات تبعت ال amines تتبع عائلة ال alkanes يعني نهيتها إيفين بروبين بيوتين هكسل whatever طبعا مركبات ال amines في الدنيا كتيرة كلها مركبات في الكيميا الحلقية مش بطلب نحفظها بس حتى تحسوا كدهش موضوع ال nitrogen موضوع واسع يعني يمكن تقوله ربع الكيميا العضوية المركبات معاه", "tokens": [15042, 6055, 14851, 29973, 37893, 4032, 46958, 5016, 22807, 4724, 47283, 2655, 9381, 9640, 9673, 31747, 3555, 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"text": "hydrogen bonding وبالتالي من ناحية من ناحية من ناحية مقارنة ال boiling point تبعتهم يفترض انها ليش تكون عالية مرتفعة طبعا اللي بده يعمل المقارنة ويفهمها جيدا بده يقارن مع إشي مافيش فيه hydrogen bonding يعني إشي فيه hydrogen bonding وإشي مافيه hydrogen bonding وبده يوحد العوامل التانية", "tokens": [21591, 7747, 28824, 46599, 6027, 2655, 6027, 1829, 9154, 8717, 39319, 10632, 9154, 8717, 39319, 10632, 9154, 8717, 39319, 10632, 3714, 4587, 9640, 1863, 3660, 2423, 16208, 935, 6055, 3555, 34268, 16095, 7251, 5172, 2655, 43042, 16472, 11296, 32239, 8592, 6055, 30544, 6225, 6027, 10632, 3714, 43500, 5172, 27884, 23032, 3555, 3615, 995, 13672, 1829, 47525, 3224, 7251, 25957, 1211, 9673, 4587, 9640, 1863, 3660, 4032, 33911, 16095, 11296, 10874, 25708, 995, 47525, 3224, 7251, 4587, 9640, 1863, 20449, 11933, 8592, 1829, 19446, 41185, 8592, 8978, 3224, 12697, 28824, 37495, 22653, 11933, 8592, 1829, 8978, 3224, 12697, 28824, 4032, 28814, 8592, 1829, 19446, 41185, 3224, 12697, 28824, 4032, 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0.876953125}, {"start": 2228.23, "end": 2228.53, "word": " بعض", "probability": 0.99658203125}, {"start": 2228.53, "end": 2229.65, "word": " كيف", "probability": 0.818603515625}, {"start": 2229.65, "end": 2229.99, "word": " بيكونوا", "probability": 0.9324951171875}, {"start": 2229.99, "end": 2230.55, "word": " جاعدين", "probability": 0.8905029296875}, {"start": 2230.55, "end": 2231.71, "word": " نفس", "probability": 0.861328125}, {"start": 2231.71, "end": 2232.09, "word": " الشي", "probability": 0.7998046875}, {"start": 2232.09, "end": 2232.35, "word": " هذا", "probability": 0.282470703125}, {"start": 2232.35, "end": 2232.79, "word": " سهل", "probability": 0.8048502604166666}, {"start": 2232.79, "end": 2233.43, "word": " وسهل", "probability": 0.8048095703125}], "temperature": 1.0}, {"id": 81, "seek": 226213, "start": 2234.59, "end": 2262.13, "text": "عمرهم هيقدروا يجربوا على بعض؟ لأ، إذا هذه الطريقة غير سليمة إطلاقا لإنه محضر من خلالها الأدلين طب ها إيش الطريقة السليمة؟ الطريقة السليمة إنه إحنا محضر الـNitro Benzene هذا من الـHNO3 و الـH2SO4 اتعلمناه بعدين الـNitro Benzene الـNitro Benzene بال reduction", "tokens": [25957, 2288, 16095, 8032, 1829, 28543, 2288, 14407, 7251, 7435, 25513, 14407, 15844, 45030, 11242, 22807, 5296, 10721, 12399, 11933, 15730, 29538, 41950, 16572, 28671, 32771, 13546, 8608, 20292, 46007, 11933, 9566, 15040, 4587, 995, 5296, 28814, 1863, 3224, 3714, 5016, 11242, 2288, 9154, 16490, 1211, 6027, 11296, 16247, 3215, 1211, 9957, 23032, 3555, 8032, 995, 11933, 1829, 8592, 41950, 16572, 28671, 21136, 20292, 46007, 22807, 41950, 16572, 28671, 21136, 20292, 46007, 36145, 3224, 11933, 5016, 8315, 3714, 5016, 11242, 2288, 2423, 39184, 45, 270, 340, 3964, 89, 1450, 23758, 9154, 2423, 39184, 39, 12861, 18, 4032, 2423, 39184, 39, 17, 17188, 19, 1975, 2655, 3615, 19528, 8315, 3224, 39182, 9957, 2423, 39184, 45, 270, 340, 3964, 89, 1450, 2423, 39184, 45, 270, 340, 3964, 89, 1450, 20666, 11004], "avg_logprob": -0.20132211526999108, "compression_ratio": 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0.9705403645833334}, {"start": 2239.85, "end": 2240.75, "word": " إطلاقا", "probability": 0.88134765625}, {"start": 2240.75, "end": 2241.65, "word": " لإنه", "probability": 0.7896728515625}, {"start": 2241.65, "end": 2242.11, "word": " محضر", "probability": 0.78289794921875}, {"start": 2242.11, "end": 2242.29, "word": " من", "probability": 0.9970703125}, {"start": 2242.29, "end": 2243.11, "word": " خلالها", "probability": 0.995849609375}, {"start": 2243.11, "end": 2244.17, "word": " الأدلين", "probability": 0.748779296875}, {"start": 2244.17, "end": 2244.61, "word": " طب", "probability": 0.894287109375}, {"start": 2244.61, "end": 2244.75, "word": " ها", "probability": 0.3890380859375}, {"start": 2244.75, "end": 2244.95, "word": " إيش", "probability": 0.8631184895833334}, {"start": 2244.95, "end": 2245.41, "word": " الطريقة", "probability": 0.9773763020833334}, {"start": 2245.41, "end": 2246.37, "word": " السليمة؟", "probability": 0.9486083984375}, {"start": 2246.37, "end": 2246.85, "word": " الطريقة", "probability": 0.98486328125}, {"start": 2246.85, "end": 2247.61, "word": " السليمة", "probability": 0.9847005208333334}, {"start": 2247.61, "end": 2248.49, "word": " إنه", "probability": 0.71240234375}, {"start": 2248.49, "end": 2248.79, "word": " إحنا", "probability": 0.9386393229166666}, {"start": 2248.79, "end": 2249.31, "word": " محضر", "probability": 0.98046875}, {"start": 2249.31, "end": 2250.05, "word": " الـNitro", "probability": 0.740576171875}, {"start": 2250.05, "end": 2250.79, "word": " Benzene", "probability": 0.755859375}, {"start": 2250.79, "end": 2251.49, "word": " هذا", "probability": 0.826171875}, {"start": 2251.49, "end": 2251.71, "word": " من", "probability": 0.96484375}, {"start": 2251.71, "end": 2252.89, "word": " الـHNO3", "probability": 0.8388671875}, {"start": 2252.89, "end": 2253.03, "word": " و", "probability": 0.76513671875}, {"start": 2253.03, "end": 2254.23, "word": " الـH2SO4", "probability": 0.8631184895833334}, {"start": 2254.23, "end": 2255.21, "word": " اتعلمناه", "probability": 0.8772786458333334}, {"start": 2255.21, "end": 2255.95, "word": " بعدين", "probability": 0.7666015625}, {"start": 2255.95, "end": 2256.77, "word": " الـNitro", "probability": 0.93056640625}, {"start": 2256.77, "end": 2257.85, "word": " Benzene", "probability": 0.9358723958333334}, {"start": 2257.85, "end": 2259.19, "word": " الـNitro", "probability": 0.89755859375}, {"start": 2259.19, "end": 2260.21, "word": " Benzene", "probability": 0.97216796875}, {"start": 2260.21, "end": 2261.61, "word": " بال", "probability": 0.9453125}, {"start": 2261.61, "end": 2262.13, "word": " reduction", "probability": 0.64208984375}], "temperature": 1.0}, {"id": 82, "seek": 229207, "start": 2263.31, "end": 2292.07, "text": "بنضيف عليها هيدروجين reduction بالهيدروجين هيدروجينونيكل مثلا بتحول إلى إيش؟ الانيلين إذا الانيلين من البنزين يمر تأكيدا عبر النيترو بنزين لما نقول بدنا انيلين من البنزين بتكون قولولي المسار بنزين نيترو بنزين انيلين", "tokens": [3555, 1863, 11242, 33911, 25894, 11296, 8032, 25708, 2288, 29245, 9957, 11004, 20666, 3224, 25708, 2288, 29245, 9957, 8032, 25708, 2288, 29245, 9957, 11536, 1829, 28820, 50113, 15040, 39894, 5016, 12610, 30731, 11933, 1829, 8592, 22807, 2423, 7649, 26895, 9957, 11933, 15730, 2423, 7649, 26895, 9957, 9154, 29739, 1863, 11622, 9957, 7251, 29973, 6055, 10721, 4117, 25708, 995, 6225, 26890, 2423, 22653, 2655, 32887, 44945, 11622, 9957, 5296, 15042, 8717, 39648, 47525, 8315, 16472, 26895, 9957, 9154, 29739, 1863, 11622, 9957, 39894, 30544, 12174, 12610, 12610, 1829, 9673, 3794, 9640, 44945, 11622, 9957, 8717, 36081, 32887, 44945, 11622, 9957, 16472, 26895, 9957], "avg_logprob": -0.23922936343452306, "compression_ratio": 2.0802139037433154, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2263.31, "end": 2263.89, "word": "بنضيف", "probability": 0.7890625}, {"start": 2263.89, "end": 2264.31, "word": " عليها", "probability": 0.979736328125}, {"start": 2264.31, "end": 2265.11, "word": " هيدروجين", "probability": 0.816650390625}, {"start": 2265.11, "end": 2266.49, "word": " reduction", "probability": 0.462890625}, {"start": 2266.49, "end": 2267.29, "word": " بالهيدروجين", "probability": 0.9554036458333334}, {"start": 2267.29, "end": 2268.45, "word": " هيدروجينونيكل", "probability": 0.6464614868164062}, {"start": 2268.45, "end": 2268.99, "word": " مثلا", "probability": 0.954345703125}, {"start": 2268.99, "end": 2271.51, "word": " بتحول", "probability": 0.8974609375}, {"start": 2271.51, "end": 2271.83, "word": " إلى", "probability": 0.341064453125}, {"start": 2271.83, "end": 2272.47, "word": " إيش؟", "probability": 0.8138427734375}, {"start": 2272.47, "end": 2273.33, "word": " الانيلين", "probability": 0.67706298828125}, {"start": 2273.33, "end": 2274.05, "word": " إذا", "probability": 0.79736328125}, {"start": 2274.05, "end": 2275.23, "word": " الانيلين", "probability": 0.9129638671875}, {"start": 2275.23, "end": 2275.47, "word": " من", "probability": 0.994140625}, {"start": 2275.47, "end": 2276.29, "word": " البنزين", "probability": 0.97509765625}, {"start": 2276.29, "end": 2277.17, "word": " يمر", "probability": 0.927001953125}, {"start": 2277.17, "end": 2278.31, "word": " تأكيدا", "probability": 0.92294921875}, {"start": 2278.31, "end": 2279.09, "word": " عبر", "probability": 0.9853515625}, {"start": 2279.09, "end": 2281.79, "word": " النيترو", "probability": 0.7040252685546875}, {"start": 2281.79, "end": 2282.47, "word": " بنزين", "probability": 0.9674479166666666}, {"start": 2282.47, "end": 2282.83, "word": " لما", "probability": 0.907958984375}, {"start": 2282.83, "end": 2283.05, "word": " نقول", "probability": 0.789306640625}, {"start": 2283.05, "end": 2283.33, "word": " بدنا", "probability": 0.6004638671875}, {"start": 2283.33, "end": 2283.79, "word": " انيلين", "probability": 0.7926432291666666}, {"start": 2283.79, "end": 2283.93, "word": " من", "probability": 0.99609375}, {"start": 2283.93, "end": 2284.39, "word": " البنزين", "probability": 0.9930419921875}, {"start": 2284.39, "end": 2284.71, "word": " بتكون", "probability": 0.781982421875}, {"start": 2284.71, "end": 2285.29, "word": " قولولي", "probability": 0.73785400390625}, {"start": 2285.29, "end": 2286.37, "word": " المسار", "probability": 0.7412923177083334}, {"start": 2286.37, "end": 2287.51, "word": " بنزين", "probability": 0.9638671875}, {"start": 2287.51, "end": 2289.59, "word": " نيترو", "probability": 0.873046875}, {"start": 2289.59, "end": 2290.53, "word": " بنزين", "probability": 0.9915364583333334}, {"start": 2290.53, "end": 2292.07, "word": " انيلين", "probability": 0.79296875}], "temperature": 1.0}, {"id": 83, "seek": 232025, "start": 2294.07, "end": 2320.25, "text": "وقع الفكرة هذا هو المسار بنزين نايترو بنزين قليل الآن لبس ان انا اضيفلكم هنا كمان معلومة كتير مهمة مر علينا طبعا هنا قلنا HRO3H2O4 مر علينا الفيلول", "tokens": [2407, 4587, 3615, 27188, 4117, 25720, 23758, 31439, 9673, 3794, 9640, 44945, 11622, 9957, 8717, 995, 36081, 32887, 44945, 11622, 9957, 12174, 20292, 1211, 6024, 48506, 5296, 3555, 3794, 16472, 1975, 8315, 1975, 11242, 33911, 23275, 2304, 34105, 9122, 2304, 7649, 20449, 1211, 20498, 3660, 9122, 2655, 13546, 3714, 16095, 3660, 3714, 2288, 25894, 8315, 23032, 3555, 3615, 995, 34105, 12174, 1211, 8315, 19460, 46, 18, 39, 17, 46, 19, 3714, 2288, 25894, 8315, 27188, 26895, 12610], "avg_logprob": -0.2802483928509248, "compression_ratio": 1.6709677419354838, "no_speech_prob": 0.0, "words": [{"start": 2294.07, "end": 2294.45, "word": "وقع", "probability": 0.5751139322916666}, {"start": 2294.45, "end": 2294.97, "word": " الفكرة", "probability": 0.9920247395833334}, {"start": 2294.97, "end": 2296.03, "word": " هذا", "probability": 0.525390625}, {"start": 2296.03, "end": 2296.29, "word": " هو", "probability": 0.97314453125}, {"start": 2296.29, "end": 2297.17, "word": " المسار", "probability": 0.8349609375}, {"start": 2297.17, "end": 2298.67, "word": " بنزين", "probability": 0.931640625}, {"start": 2298.67, "end": 2299.45, "word": " نايترو", "probability": 0.69244384765625}, {"start": 2299.45, "end": 2300.13, "word": " بنزين", "probability": 0.990234375}, {"start": 2300.13, "end": 2300.93, "word": " قليل", "probability": 0.6192220052083334}, {"start": 2300.93, "end": 2302.19, "word": " الآن", "probability": 0.642578125}, {"start": 2302.19, "end": 2303.47, "word": " لبس", "probability": 0.7610677083333334}, {"start": 2303.47, "end": 2303.93, "word": " ان", "probability": 0.45458984375}, {"start": 2303.93, "end": 2304.61, "word": " انا", "probability": 0.6160888671875}, {"start": 2304.61, "end": 2306.11, "word": " اضيفلكم", "probability": 0.77197265625}, {"start": 2306.11, "end": 2306.61, "word": " هنا", "probability": 0.86474609375}, {"start": 2306.61, "end": 2307.23, "word": " كمان", "probability": 0.8072102864583334}, {"start": 2307.23, "end": 2308.03, "word": " معلومة", "probability": 0.94384765625}, {"start": 2308.03, "end": 2308.57, "word": " كتير", "probability": 0.8673502604166666}, {"start": 2308.57, "end": 2309.95, "word": " مهمة", "probability": 0.9820963541666666}, {"start": 2309.95, "end": 2312.99, "word": " مر", "probability": 0.79638671875}, {"start": 2312.99, "end": 2313.65, "word": " علينا", "probability": 0.968994140625}, {"start": 2313.65, "end": 2314.49, "word": " طبعا", "probability": 0.8721923828125}, {"start": 2314.49, "end": 2314.65, "word": " هنا", "probability": 0.30810546875}, {"start": 2314.65, "end": 2314.95, "word": " قلنا", "probability": 0.67041015625}, {"start": 2314.95, "end": 2317.35, "word": " HRO3H2O4", "probability": 0.6719796316964286}, {"start": 2317.35, "end": 2318.29, "word": " مر", "probability": 0.86572265625}, {"start": 2318.29, "end": 2318.97, "word": " علينا", "probability": 0.978759765625}, {"start": 2318.97, "end": 2320.25, "word": " الفيلول", "probability": 0.8077799479166666}], "temperature": 1.0}, {"id": 84, "seek": 234882, "start": 2321.48, "end": 2348.82, "text": "بتعرفوا ال phenol؟ اه لو اتينا و قولنالكم how can you prepare phenol يعني هنا OH starting from بنزين كيف تحضر ال phenol من البنزين؟ الآن أكبر غلط ممكن الواحد يعمله إيش؟ يقول بنزين", "tokens": [3555, 2655, 3615, 28480, 14407, 2423, 7279, 401, 22807, 1975, 3224, 45164, 1975, 31371, 8315, 4032, 12174, 12610, 8315, 23275, 2304, 577, 393, 291, 5940, 7279, 401, 37495, 22653, 34105, 13931, 2891, 490, 44945, 11622, 9957, 9122, 33911, 6055, 5016, 11242, 2288, 2423, 7279, 401, 9154, 29739, 1863, 11622, 9957, 22807, 6024, 48506, 5551, 4117, 26890, 32771, 1211, 9566, 3714, 43020, 2423, 14407, 24401, 7251, 25957, 43761, 11933, 1829, 8592, 22807, 7251, 39648, 44945, 11622, 9957], "avg_logprob": -0.20961850107490243, "compression_ratio": 1.4734042553191489, "no_speech_prob": 0.0, "words": [{"start": 2321.48, "end": 2322.02, "word": "بتعرفوا", "probability": 0.88955078125}, {"start": 2322.02, "end": 2322.16, "word": " ال", "probability": 0.583984375}, {"start": 2322.16, "end": 2323.36, "word": " phenol؟", "probability": 0.725830078125}, {"start": 2323.36, "end": 2323.88, "word": " اه", "probability": 0.756103515625}, {"start": 2323.88, "end": 2324.48, "word": " لو", "probability": 0.70361328125}, {"start": 2324.48, "end": 2325.04, "word": " اتينا", "probability": 0.79296875}, {"start": 2325.04, "end": 2325.2, "word": " و", "probability": 0.9609375}, {"start": 2325.2, "end": 2325.94, "word": " قولنالكم", "probability": 0.732275390625}, {"start": 2325.94, "end": 2326.32, "word": " how", "probability": 0.73095703125}, {"start": 2326.32, "end": 2326.7, "word": " can", "probability": 0.93701171875}, {"start": 2326.7, "end": 2326.94, "word": " you", "probability": 0.9697265625}, {"start": 2326.94, "end": 2327.58, "word": " prepare", "probability": 0.94140625}, {"start": 2327.58, "end": 2328.76, "word": " phenol", "probability": 0.9384765625}, {"start": 2328.76, "end": 2332.56, "word": " يعني", "probability": 0.7353515625}, {"start": 2332.56, "end": 2333.1, "word": " هنا", "probability": 0.7333984375}, {"start": 2333.1, "end": 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"probability": 0.7516276041666666}, {"start": 2725.99, "end": 2726.75, "word": " النكوتين", "probability": 0.74493408203125}, {"start": 2726.75, "end": 2727.81, "word": " هذا", "probability": 0.70458984375}, {"start": 2727.81, "end": 2728.45, "word": " المركب", "probability": 0.9562174479166666}, {"start": 2728.45, "end": 2729.43, "word": " النكوتين", "probability": 0.878662109375}, {"start": 2729.43, "end": 2729.87, "word": " كيف", "probability": 0.9580078125}, {"start": 2729.87, "end": 2730.47, "word": " نحطه", "probability": 0.8720703125}, {"start": 2730.47, "end": 2731.87, "word": " نكوتين", "probability": 0.8756103515625}, {"start": 2731.87, "end": 2732.97, "word": " السجاني", "probability": 0.6014404296875}, {"start": 2732.97, "end": 2733.15, "word": " في", "probability": 0.6396484375}, {"start": 2733.15, "end": 2733.35, "word": " كل", "probability": 0.9912109375}, {"start": 2733.35, "end": 2734.05, "word": " الأحوال", "probability": 0.9620361328125}, {"start": 2734.05, "end": 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21984], "avg_logprob": -0.2529189580089443, "compression_ratio": 1.5625, "no_speech_prob": 5.030632019042969e-05, "words": [{"start": 2739.91, "end": 2740.19, "word": "الـ", "probability": 0.655029296875}, {"start": 2740.19, "end": 2740.45, "word": " PR", "probability": 0.458251953125}, {"start": 2740.45, "end": 2740.83, "word": " أو", "probability": 0.7587890625}, {"start": 2740.83, "end": 2741.07, "word": " الـ", "probability": 0.825439453125}, {"start": 2741.07, "end": 2741.49, "word": " CL", "probability": 0.56884765625}, {"start": 2741.49, "end": 2742.39, "word": " ابتفعوا", "probability": 0.80205078125}, {"start": 2742.39, "end": 2743.09, "word": " الإدالة،", "probability": 0.665185546875}, {"start": 2743.09, "end": 2743.47, "word": " فطرق", "probability": 0.910888671875}, {"start": 2743.47, "end": 2743.91, "word": " تحضير", "probability": 0.9249267578125}, {"start": 2743.91, "end": 2744.91, "word": " الأمين", "probability": 0.8860677083333334}, {"start": 2744.91, "end": 2745.81, "word": " استلخيصا", "probability": 0.7929280598958334}, {"start": 2745.81, "end": 2746.25, "word": " من", "probability": 0.8798828125}, {"start": 2746.25, "end": 2746.45, "word": " الـ", "probability": 0.751220703125}, {"start": 2746.45, "end": 2747.73, "word": " Amides،", "probability": 0.5367838541666666}, {"start": 2747.73, "end": 2747.97, "word": " من", "probability": 0.9580078125}, {"start": 2747.97, "end": 2748.17, "word": " الـ", "probability": 0.9755859375}, {"start": 2748.17, "end": 2749.21, "word": " CL،", "probability": 0.5115966796875}, {"start": 2749.21, "end": 2749.37, "word": " من", "probability": 0.98681640625}, {"start": 2749.37, "end": 2750.01, "word": " الإدالة", "probability": 0.957275390625}, {"start": 2750.01, "end": 2750.37, "word": " محل", "probability": 0.8388671875}, {"start": 2750.37, "end": 2750.55, "word": " الـ", "probability": 0.904541015625}, {"start": 2750.55, "end": 2751.59, "word": " Halogens،", "probability": 0.580810546875}, {"start": 2751.59, "end": 2751.77, "word": " والـ", "probability": 0.544677734375}, {"start": 2751.77, "end": 2752.25, "word": " Aromatic", "probability": 0.78369140625}, {"start": 2752.25, "end": 2752.69, "word": " أمين", "probability": 0.8986002604166666}, {"start": 2752.69, "end": 2753.55, "word": " باختزال", "probability": 0.937109375}, {"start": 2753.55, "end": 2753.95, "word": " الـ", "probability": 0.875244140625}, {"start": 2753.95, "end": 2756.47, "word": " Nitrobenzene،", "probability": 0.7223307291666666}, {"start": 2756.47, "end": 2756.81, "word": " واضحة", "probability": 0.94873046875}, {"start": 2756.81, "end": 2757.83, "word": " الفكرة؟", "probability": 0.9788818359375}, {"start": 2757.83, "end": 2757.99, "word": " إن", "probability": 0.56787109375}, {"start": 2757.99, "end": 2758.19, "word": " شاء", "probability": 0.95361328125}, {"start": 2758.19, "end": 2758.29, "word": " الله", "probability": 0.9609375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 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\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d82554c6651f42c5944c21b82685881bb1b382ce
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/JNa-wqL1MMY_raw.srt
@@ -0,0 +1,1924 @@
+1
+00:00:19,740 --> 00:00:25,800
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في ال
+
+2
+00:00:25,800 --> 00:00:30,360
+dry glycerides و ال fats and oils يمكن لاحقته
+
+3
+00:00:30,360 --> 00:00:36,240
+انتوا شغلة ان فيهم شيء مشترك الشيء المشترك اللي
+
+4
+00:00:36,240 --> 00:00:43,090
+فيهم هو ال glycerol واضح؟الان فيهم بعد هيك أشياء
+
+5
+00:00:43,090 --> 00:00:49,130
+مختلفة، الأشياء المختلفة هي ال fatty acids، يعني
+
+6
+00:00:49,130 --> 00:00:53,450
+احنا اتفقنا ان الـ triglycerides، ال glycerol متصل
+
+7
+00:00:53,450 --> 00:00:58,920
+فيه تلاتة fatty acids عاملين E starsهدولة التلات
+
+8
+00:00:58,920 --> 00:01:03,240
+شغلات بيختلفوا يعني ال glycerol واحد مش فيه خلافة
+
+9
+00:01:03,240 --> 00:01:08,440
+لكن هل يتر هدولة تلات فات أسيتس من نفس النوع بداية
+
+10
+00:01:08,440 --> 00:01:13,460
+بيكون simply triglycerides او مختلفين بيكون mixed
+
+11
+00:01:13,460 --> 00:01:14,540
+triglycerides
+
+12
+00:01:17,790 --> 00:01:22,530
+ايش الاحتمالات انهم يكونوا موجودين saturated كلهم
+
+13
+00:01:22,530 --> 00:01:27,870
+ولا unsaturated ولا بنسب مختلفة الان هذا الاختلاف
+
+14
+00:01:27,870 --> 00:01:33,390
+في التلاتة fatty acids اللي موجودين هو اللي بسبب
+
+15
+00:01:33,390 --> 00:01:38,210
+اختلاف بين انه المركب نفسه او المادة نفسها تكون
+
+16
+00:01:38,210 --> 00:01:44,110
+fat يعني بحالة صلبة او تكون oil وحتى لما تكون oil
+
+17
+00:01:44,110 --> 00:01:50,030
+ما بين زيت وزيتأو ما بين fat و fat أيضا في ايش
+
+18
+00:01:50,030 --> 00:01:54,930
+عندنا؟ في اختلاف هذا الاختلاف مرده لإيش؟ مرده
+
+19
+00:01:54,930 --> 00:01:59,790
+لاختلاف أنواع و نسب ال fatty acids اللي موجودين
+
+20
+00:01:59,790 --> 00:02:05,790
+يعني مثلا بشكل عام بنقدر نقول ان الزيوت تحتوي على
+
+21
+00:02:05,790 --> 00:02:10,270
+نسبة أكثر من ال saturated ولا ال unsaturated fatty
+
+22
+00:02:10,270 --> 00:02:14,130
+acidsالـ Unsaturated و هم اللي بيخلوها Liquid و
+
+23
+00:02:14,130 --> 00:02:18,310
+عشان هيك لو بدنا نتطلع مثلا على ال olive oil على
+
+24
+00:02:18,310 --> 00:02:23,930
+زيت الزتون هلاحظ انه في من ال unsaturated acids 83
+
+25
+00:02:23,930 --> 00:02:29,710
+من ال oleic acid اللي في double bond واحدة 83% و 7
+
+26
+00:02:29,710 --> 00:02:33,950
+% من ال linoleic acid اللي فيه تنتين double bonds
+
+27
+00:02:33,950 --> 00:02:40,390
+بمعنى مجموع ال unsaturated في زيت الزتون كدهش 90%
+
+28
+00:02:41,360 --> 00:02:46,620
+إذا معظم الزيت المجموع اللي فيه جديش 90% لو طلعنا
+
+29
+00:02:46,620 --> 00:02:53,220
+على زيت النخل بنلاحظ النسبة 51% على زيت الدرة 80%
+
+30
+00:02:53,220 --> 00:03:02,280
+هنا زيت ال peanut اللي هي الصوية 85% يعني الزيوتي
+
+31
+00:03:02,280 --> 00:03:05,960
+بشكل عام بنقدر نقوله هذه الجملة اللي بنضال
+
+32
+00:03:05,960 --> 00:03:10,150
+متذاكرينها بيكون فيها higherpercentage of
+
+33
+00:03:10,150 --> 00:03:14,430
+saturated ولا unsaturated .. unsaturated fatty
+
+34
+00:03:14,430 --> 00:03:20,090
+acids الآن بالنسبة للأشياء التانية اللي بتصير fat
+
+35
+00:03:20,090 --> 00:03:24,110
+يعني نوعا ما صلب يعني على سبيل المثال الزبدة لو
+
+36
+00:03:24,110 --> 00:03:27,010
+بنتطلع على الزبدة قداش فيها unsaturated fatty
+
+37
+00:03:27,010 --> 00:03:31,110
+acids من اللي وليك و اللي نوليك ستة و عشرين و
+
+38
+00:03:31,110 --> 00:03:39,300
+اتنين28 بينما معظمها مخلوط فيها عدة أنواع من ال
+
+39
+00:03:39,300 --> 00:03:45,300
+saturated fatty acids سواء كانت اللي هي ال C10 اقل
+
+40
+00:03:45,300 --> 00:03:50,480
+من C10 .. C12 اللورك، الميرستك، البلمتك، الاستيرك،
+
+41
+00:03:50,480 --> 00:03:57,220
+كلهم موجودين إيش؟كنسب من الـ saturated fatty acids
+
+42
+00:03:57,220 --> 00:04:02,120
+فبشكل عام احنا بيقول ان ال fats بيكون فيهم ال
+
+43
+00:04:02,120 --> 00:04:08,060
+higher percentage من ال ايش؟ ال higher من ال
+
+44
+00:04:08,060 --> 00:04:13,810
+saturated fatty acidsمن ال unsaturated لكن ما بين
+
+45
+00:04:13,810 --> 00:04:17,130
+زيت و زيت ليش بيختلفوا الزيوت في الطعم يعني مش كل
+
+46
+00:04:17,130 --> 00:04:21,150
+الزيت واحد و مش كل الفات واحد لما نيجي نقول والله
+
+47
+00:04:21,150 --> 00:04:27,990
+زيت الزتون ولا زيت الصوية على سبيل المثالبختلفه كل
+
+48
+00:04:27,990 --> 00:04:32,490
+واحد فيه نسبة معينة بتعطي طعم معين ولذلك بشكل عام
+
+49
+00:04:32,490 --> 00:04:36,630
+احنا متعودين اكتر ان زيت الزيتون نستعمله باستعمال
+
+50
+00:04:36,630 --> 00:04:41,710
+معين زيت الصيام يمكن للجالي باستعمال تاني هذا فقط
+
+51
+00:04:41,710 --> 00:04:47,930
+على اختلاف نسبة ايش ال fatty acids وانواعهم واضح
+
+52
+00:04:47,930 --> 00:04:51,670
+الفكرة هذا اللي بيميز الزيوت و الدون عن بعض نسب ال
+
+53
+00:04:51,670 --> 00:04:59,210
+fatty acids وانواعها الآنمن سواء قلنا الدهون او
+
+54
+00:04:59,210 --> 00:05:04,550
+الزيوت بنعمل احنا ايش تفاعل بنسميه soapification
+
+55
+00:05:04,550 --> 00:05:09,130
+تفاعل تحلل لها وهو التفاعل اللي من خلاله بنحضر
+
+56
+00:05:09,130 --> 00:05:12,850
+احنا الصابون اللي احنا عارفين يعني عادة الصابون
+
+57
+00:05:12,850 --> 00:05:18,270
+تحضيرها الصابون العادي البلدي من زيت الزتون انه
+
+58
+00:05:18,270 --> 00:05:23,130
+انا باخد ال triglycerides مثلاTriglyceride معين اي
+
+59
+00:05:23,130 --> 00:05:26,650
+زيت زتون انا ماخد زيت عادي من زيت النخل على سبيل
+
+60
+00:05:26,650 --> 00:05:31,150
+المثال وبعد هيك بالفعل مع ال sodium hydroxide
+
+61
+00:05:31,150 --> 00:05:37,730
+بيصيرله تحلل بناخد جزء لجليسرين وجزء لجليسرين خلاص
+
+62
+00:05:37,730 --> 00:05:41,590
+مابناشي يا ابن فصله الان الجزء التاني بيصير على
+
+63
+00:05:41,590 --> 00:05:47,380
+شكل حامضتلات أحماض و الحامض في وجود ال sodium
+
+64
+00:05:47,380 --> 00:05:52,340
+hydroxide هيكون على شكل إيش؟ الملح تبعه، الأن لما
+
+65
+00:05:52,340 --> 00:05:56,940
+صار الحامض على شكل الملح، هذا ملح الحامض هو
+
+66
+00:05:56,940 --> 00:06:03,200
+الصابون يعني اللبنانيش يقولكم إيش ببساطة الصابون؟
+
+67
+00:06:03,200 --> 00:06:11,290
+الجواب بيكون salt إيش هو ال salt؟ Saltملح يعني
+
+68
+00:06:11,290 --> 00:06:15,430
+طرفه C double bond O O minus نفترض مع ال A plus
+
+69
+00:06:15,430 --> 00:06:22,650
+Salt of fatty acid هو ملح الفاتي أسد Salt of fatty
+
+70
+00:06:22,650 --> 00:06:26,570
+acid بنحضره من خلال إن انفاع الزيوت أو الدهون ل
+
+71
+00:06:26,570 --> 00:06:30,790
+Triglycerides مع Sodium hydroxide طبعا هتلاحظوا
+
+72
+00:06:30,790 --> 00:06:36,790
+انتوا ان هذا الصابون بيمتاز بإيش بيمتاز بوجود طرف
+
+73
+00:06:37,690 --> 00:06:43,630
+ننقل إلى السلسلة يعني هذا مثلا من ال بالميتك أسد
+
+74
+00:06:43,630 --> 00:06:48,630
+يعني ستة عشر كاربون وعشانك بيسموه سوديوم بالميتيت
+
+75
+00:06:48,630 --> 00:06:53,050
+زي اللي من الاسيتك أسد كنا نسميه سوديوم أسيتيت
+
+76
+00:06:53,050 --> 00:06:57,310
+الآن هاي عندي ستة عشر كاربون هذه السلسلة اللي هي
+
+77
+00:06:57,310 --> 00:07:04,970
+الالفتك وعلى طرفها C double bond O O minusالان صار
+
+78
+00:07:04,970 --> 00:07:08,390
+الصابوني مكون من شغلتين polar part
+
+79
+00:07:13,350 --> 00:07:17,870
+واضح؟ طبعا ال non-polar part في الصابون هو جزء
+
+80
+00:07:17,870 --> 00:07:23,890
+كبير ولذلك الصابون يستخدم لغسل ايش؟ الدهون لأن
+
+81
+00:07:23,890 --> 00:07:28,190
+الدهون non-polar و هذا الجزء non-polar فالدهون لما
+
+82
+00:07:28,190 --> 00:07:32,650
+احنا بنغسل الأيدان بالصابون بتدوب في أي جزء في ال
+
+83
+00:07:32,650 --> 00:07:38,310
+non-polar يعني هذا الجزء بيصير ادوب الدهونواضح؟
+
+84
+00:07:38,310 --> 00:07:42,070
+هذا الجزء الـ non-polar هو اللي بدوّب الدهون عن
+
+85
+00:07:42,070 --> 00:07:45,790
+إيد الإنسان لما بيعمل الغسل باستعمال .. إيش؟
+
+86
+00:07:45,790 --> 00:07:53,090
+الصابون، الآن لاحظوا معنى، الزيوت غالية وإلى
+
+87
+00:07:53,090 --> 00:07:57,940
+استعمالات لازمة للناس في الأكل وغيره وغيراتهمظبوط
+
+88
+00:07:57,940 --> 00:08:02,840
+ولا لأ؟ يعني مثلا زيت الزتون اليوم صار غالي جدا
+
+89
+00:08:02,840 --> 00:08:06,600
+زمان يمكن كان متوفر والناس جلال وبالتالي كانوا
+
+90
+00:08:06,600 --> 00:08:10,760
+ياخدوا زيت زتون ويعملوا صابونة اليوم لو بدنا نلاحق
+
+91
+00:08:10,760 --> 00:08:14,860
+عن ناس صابون كل زيت الزتون ماحدش هيكله كله هنحاوله
+
+92
+00:08:14,860 --> 00:08:19,860
+لإيش؟ لصابون ولذلك بدأت الفكرة انه لأ ليش ما نعمل
+
+93
+00:08:19,860 --> 00:08:26,020
+احنا صابونصناعي من غير زيت الزتون الآن اللي بيعمل
+
+94
+00:08:26,020 --> 00:08:29,840
+صابون صناعي بيقول ما هي الفكرة العامة للصابون
+
+95
+00:08:29,840 --> 00:08:36,960
+الفكرة العامة للصابون polar مع non polar تمام؟
+
+96
+00:08:36,960 --> 00:08:42,140
+جيبهم من أي جهة كانت في الدنيا بتطلع شبيه الصابون
+
+97
+00:08:42,140 --> 00:08:47,100
+ليش؟ لأن ال non polar هيدوب الدهون اللي هي non
+
+98
+00:08:47,100 --> 00:08:52,630
+polar وبناء على ذلك صار عندناالاشياء اللي بنسميها
+
+99
+00:08:52,630 --> 00:08:55,970
+احنا ال synthetic detergents يعني المنظفات
+
+100
+00:08:55,970 --> 00:09:02,850
+الصناعية او Sidnets لاحظوا كيف انطلقوا بالفكرة هم
+
+101
+00:09:02,850 --> 00:09:06,790
+جالوا هاي الصابون مثلا من الاستيرك اسد عندي لزوم
+
+102
+00:09:06,790 --> 00:09:11,690
+Sodium Sterate لو قلالكم اي سؤال في الامتحان
+
+103
+00:09:11,690 --> 00:09:18,290
+Sodium Sterate او Sodium Palmitateهو سلطة استيريت
+
+104
+00:09:18,290 --> 00:09:25,010
+بلمتات ميرستات كل هذه صوابين الآن فيها جزء بولا
+
+105
+00:09:25,010 --> 00:09:34,010
+وجزء نان بولالكن هذا مأخوذ من الزيت الزتون، الآن
+
+106
+00:09:34,010 --> 00:09:38,890
+كيميائيا قالوا خلينا نجيب جزء non-polar من الكيميا
+
+107
+00:09:38,890 --> 00:09:42,410
+من عندنا، جابوا سلسلة طويلة وكمان فيها حلقة بنزين،
+
+108
+00:09:42,410 --> 00:09:46,350
+في كل الأحوال هذه السلسلة إيش مالها؟ non-polar،
+
+109
+00:09:46,350 --> 00:09:51,800
+وشبكوا معها شيء ما polarمرة تانية مرة تالتة لاحظوا
+
+110
+00:09:51,800 --> 00:09:57,020
+معي كلمة بولر أهم شيء يكون لها قطب الان ان القطب
+
+111
+00:09:57,020 --> 00:10:01,580
+يكون موجب او سالب او حتى شيء قطبي مافيش فيه موجب
+
+112
+00:10:01,580 --> 00:10:06,300
+او سالب بس زي OH بيمشي ولذلك في الصوابين الصناعية
+
+113
+00:10:06,300 --> 00:10:10,080
+هتلاحظوا ان هذا الجزء مثلا ممكن يكون S double bond
+
+114
+00:10:10,080 --> 00:10:14,830
+O double bond O O minusسالب عشان هيك بنقول عن هذا
+
+115
+00:10:14,830 --> 00:10:20,650
+الصابون anionic detergent لأن ال ion هنا سالب ممكن
+
+116
+00:10:20,650 --> 00:10:26,590
+نحطه موجب السالب قطب والموجب قطب يعني مش إلزام أن
+
+117
+00:10:26,590 --> 00:10:31,590
+القطب يكون سالب ولذلك لو حطينا ammonium salt هنا
+
+118
+00:10:31,590 --> 00:10:37,690
+هذا موجب الموجب برضه قطب أو شي قطبة ممكن نحطه شي
+
+119
+00:10:37,690 --> 00:10:43,370
+متعادل لكن فيه مجموعة قطبية زي ال OHفبصير عندى
+
+120
+00:10:43,370 --> 00:10:49,110
+ايش؟ non-ionic فالجزء البولر مش الزام انه يكون
+
+121
+00:10:49,110 --> 00:10:54,950
+سالب لأ ممكن يكون سالب بنقول عنه المنظفات anionic
+
+122
+00:10:54,950 --> 00:10:58,730
+detergents ممكن يكون موجب بنقول عنها cationic
+
+123
+00:10:58,730 --> 00:11:03,370
+detergents وممكن يكون لا موجب ولا سالب يعني متعادل
+
+124
+00:11:03,370 --> 00:11:08,090
+نيوترال او non-ionic detergents و هذه السلاسل
+
+125
+00:11:08,090 --> 00:11:13,260
+بنحطها من عندنا في الكيمياالكيميا فيها مركبات و
+
+126
+00:11:13,260 --> 00:11:17,900
+تحضيرات سلسلة كل هذا بتصير عبارة عن ايش؟ Synthetic
+
+127
+00:11:17,900 --> 00:11:22,060
+detergents أخذت من الصبون فكرته الأساسية اللي هي
+
+128
+00:11:22,060 --> 00:11:27,280
+بولر و نانبولر وغيرت شو هو البولر وغيرت شو هو ال
+
+129
+00:11:27,280 --> 00:11:31,620
+نانبولر كمان يعني لاحظوا هنا البولر متغير و ال
+
+130
+00:11:31,620 --> 00:11:38,500
+نانبولر متغير لكن الفكرة العامة بولر مع نانبولر ما
+
+131
+00:11:38,500 --> 00:11:39,760
+زالت موجودة
+
+132
+00:11:42,300 --> 00:11:47,360
+الان ابهيك بنكون خلصنا الـ triglycerides الـ
+
+133
+00:11:47,360 --> 00:11:53,000
+triglycerides الحقيقة مشتق منهم ال phospholipids
+
+134
+00:11:53,000 --> 00:11:58,420
+واضح؟ ال triglycerides مشتق منهم ال phospholipids
+
+135
+00:11:58,420 --> 00:12:02,260
+لو انا بنفس المنطق اللي تو اتكلمت فيه عن ال
+
+136
+00:12:02,260 --> 00:12:05,660
+triglycerides بدي اقول شومة ال triglycerides عشان
+
+137
+00:12:05,660 --> 00:12:10,700
+انتقل منهم لل phospholipids كان عندى إجليسرولو
+
+138
+00:12:10,700 --> 00:12:17,140
+fatty acid أول و fatty acid تاني و fatty acid تالت
+
+139
+00:12:17,140 --> 00:12:22,810
+مظبوط ولا لأ؟ الآن ال phospholipids بنحافظ فيهمعلى
+
+140
+00:12:22,810 --> 00:12:27,350
+ال aglycerol وعلى اتنين من ال fatty acids هدول
+
+141
+00:12:27,350 --> 00:12:31,790
+بيخليهم زي ما هم معناه تالت fatty acid بنشيله بنحط
+
+142
+00:12:31,790 --> 00:12:36,590
+عليه مجموعة فوسفات مع مجموعة ماء صغيرة معروفة
+
+143
+00:12:36,590 --> 00:12:40,510
+بالكيميا بيصير اسمه ايش؟ phospholipid لأنه هنا اجى
+
+144
+00:12:40,510 --> 00:12:46,320
+عندىمجموعة ال .. ال .. ال .. ال .. PO4 فالشئ
+
+145
+00:12:46,320 --> 00:12:50,540
+المشترك ما بين ال triglycerides و ال phospholipids
+
+146
+00:12:50,540 --> 00:12:56,690
+هو ال glycerolو اتنين من ال fatty acids واحد من ال
+
+147
+00:12:56,690 --> 00:13:03,110
+fatty acids بيحولوا الى مجموعة فوسفات مع جزيق صغير
+
+148
+00:13:03,110 --> 00:13:09,650
+طبعا بشكل عام غير ال glycerol يعني هل كل ال lipids
+
+149
+00:13:09,650 --> 00:13:15,090
+مبنية على glycerol اللي هو التلاتة carbon يعني هذا
+
+150
+00:13:15,090 --> 00:13:23,060
+ال glycerol كام carbon؟تلاتة CH2 CH CH2 و بستكمل
+
+151
+00:13:23,060 --> 00:13:27,360
+من هنا ال limits هدولة اللي مبنيين على ال glycerol
+
+152
+00:13:27,360 --> 00:13:34,420
+بنسميهم احنا ايش ال tri glycerides الان في عنبنوع
+
+153
+00:13:34,420 --> 00:13:38,880
+تاني من ال limits يمكن ما جيبناش سيرته مبني على
+
+154
+00:13:38,880 --> 00:13:44,220
+اربع ذرات كربون بنسميه ايش sphingothenes
+
+155
+00:13:45,050 --> 00:13:49,150
+السفينجوسينز بدل الجليسيرين بحب انا شبه في
+
+156
+00:13:49,150 --> 00:13:55,930
+الجليسيرين بالمناسبة CH2OH بعدين CHNH2 بعدين CHOH
+
+157
+00:13:55,930 --> 00:13:59,530
+بعدين CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+158
+00:13:59,530 --> 00:14:00,270
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+159
+00:14:00,270 --> 00:14:01,230
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+160
+00:14:01,230 --> 00:14:02,590
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+161
+00:14:02,590 --> 00:14:05,810
+CH CH CH CH CH CH CH
+
+162
+00:14:05,810 --> 00:14:05,810
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+163
+00:14:05,810 --> 00:14:05,810
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+164
+00:14:05,810 --> 00:14:07,610
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+165
+00:14:07,610 --> 00:14:09,590
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+166
+00:14:09,590 --> 00:14:09,590
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+167
+00:14:09,590 --> 00:14:12,710
+CH CH CH CH CH CH CH CH CH CH CH CH CH CH
+
+168
+00:14:12,710 --> 00:14:20,690
+CH CH CHتلاتة O H's هنا صار عندى تنتين O H's و
+
+169
+00:14:20,690 --> 00:14:26,850
+واحدة N H2 بناء على ذلك ال O H's بيعملوا إيش؟ E
+
+170
+00:14:26,850 --> 00:14:33,290
+star و ال N H2 بيعملوا أمد فالسفينجوسين موجود في E
+
+171
+00:14:33,290 --> 00:14:38,190
+stars و أمد يعني اتنين E stars و واحد أمد بينما
+
+172
+00:14:38,190 --> 00:14:43,930
+للـ triglycerides في تلاتة E starsهذا نوع من الـ
+
+173
+00:14:43,930 --> 00:14:49,730
+lipids و هذا نوع من الـ triglycerides في كل
+
+174
+00:14:49,730 --> 00:14:54,230
+الأحوال سواء كان البناء الأساسي اللي أنا مبني عندي
+
+175
+00:14:54,230 --> 00:15:00,930
+على غليسرول بثلاث أواتش أو على الاسفينجوسين بتنتين
+
+176
+00:15:00,930 --> 00:15:08,310
+أواتش واحدة مجموعة الفاتككل هدولة لو اجينا شبكنا
+
+177
+00:15:08,310 --> 00:15:12,050
+مع واحدة منهم مجموعة ال phosphoric acid او
+
+178
+00:15:12,050 --> 00:15:16,270
+الفوسفات و جزء صغير زي ال ethanol امين او زي
+
+179
+00:15:16,270 --> 00:15:20,530
+الكولين هيدروكسايد بيصير عند ال ايش ال
+
+180
+00:15:20,530 --> 00:15:25,850
+phospholipids و بناء على ذلك لو احنا بنشوف منظر ال
+
+181
+00:15:25,850 --> 00:15:30,480
+phospholipidsهتلاحظوا بالشكل القاتل هي
+
+182
+00:15:30,480 --> 00:15:35,160
+phospholipids من ال glycerol CH2O C double bond O
+
+183
+00:15:35,160 --> 00:15:38,780
+هذا الجزء زي ما هو زي ما هو في ال tri glycerides E
+
+184
+00:15:38,780 --> 00:15:45,660
+star وكمان CO O C double bond O whatever هذا نفسه
+
+185
+00:15:45,660 --> 00:15:49,020
+fatty acid على الموقع التالت ايش حطينا
+
+186
+00:16:02,680 --> 00:16:04,080
+وبووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو
+
+187
+00:16:19,850 --> 00:16:23,830
+اللي هو ال phospholipids وبناء على ذلك مرات لما
+
+188
+00:16:23,830 --> 00:16:27,070
+بييجوا بيختصروا ال phospholipids طبعا هنا مجموعة
+
+189
+00:16:27,070 --> 00:16:32,090
+الفوسفات مع هذا الجزء بيعملوا طرف منفصل طرف بولر
+
+190
+00:16:32,090 --> 00:16:36,130
+عشانك مرات لما بيختصروا ال phospholipids بيروحوا
+
+191
+00:16:36,130 --> 00:16:40,530
+بيعملوا هيك سلسلتين هدول السلسلتين بيقصروا فيهم
+
+192
+00:16:40,530 --> 00:16:46,070
+الاتنين fatty acids اللي ضالهم إيش موجودينمش احنا
+
+193
+00:16:46,070 --> 00:16:51,090
+قولنا في تلاتة fatty acids اتنين ضالوا موجودين و
+
+194
+00:16:51,090 --> 00:16:55,750
+التالت صار phosphate بعلمه بإيش؟ أو ionic بكرة
+
+195
+00:16:55,750 --> 00:17:02,070
+زرقاء أو برأس أزرق فهي التلاتة fatty acid و الأزرق
+
+196
+00:17:02,070 --> 00:17:07,100
+هذا إيش؟ phosphate فبصير هذا المنظر العاميعني يمثل
+
+197
+00:17:07,100 --> 00:17:11,600
+اختصار للإيش؟ لل phospholipid الآن لاحظوا هذا
+
+198
+00:17:11,600 --> 00:17:16,760
+الجزء مرة تانية polar هذا الجزء non polar فصار
+
+199
+00:17:16,760 --> 00:17:22,860
+كأنه ال phospholipid polar و non polarواضح؟ هذه
+
+200
+00:17:22,860 --> 00:17:27,500
+الصفات انه يكون polar و non-polar ع طول بتدخل في
+
+201
+00:17:27,500 --> 00:17:32,000
+إيش؟ في الوظيفة تبعته يعني ال phospholipid بشكل
+
+202
+00:17:32,000 --> 00:17:36,820
+أساسي زي ما انتوا شايفين في ال slide السابقة بشكل
+
+203
+00:17:36,820 --> 00:17:42,900
+جداش؟ 40% من ال cell membrane يعني الجدار ..
+
+204
+00:17:42,900 --> 00:17:47,620
+الجدار تبع الخلية بنسبة كبيرة منه بيكون عبارة عن
+
+205
+00:17:47,620 --> 00:17:52,270
+إيش؟phospholipids وعرفنا الـ phospholipids الآن
+
+206
+00:17:52,270 --> 00:17:58,310
+حسب ترتيب الـ phospholipids بهذا الشكل لو وضعناهم
+
+207
+00:17:58,310 --> 00:18:04,850
+او لو لفناهم على شكل زي كرة بيسموها ليبوزوم لاحظوا
+
+208
+00:18:04,850 --> 00:18:09,290
+بيكون في عندى جزء بولر الجزء البولر بتلتصق فيه ايش
+
+209
+00:18:09,290 --> 00:18:14,570
+الميه اكيواس بيكون و هذا الجزء الخارجي بولر برضه
+
+210
+00:18:14,570 --> 00:18:19,110
+اكيواس فصار عندى هنا اكيواس interiorو aqueous
+
+211
+00:18:19,110 --> 00:18:23,390
+exterior aqueous interior و aqueous exterior ليش؟
+
+212
+00:18:23,390 --> 00:18:27,230
+لأن هذا الجزء هو الجزء ال إيش ال polar الجزء ال
+
+213
+00:18:27,230 --> 00:18:30,910
+non polar وين موجود؟ في النص، هذي بيسموها
+
+214
+00:18:30,910 --> 00:18:35,130
+liposomes بتعني يمكن هي ك aggregates aggregate
+
+215
+00:18:35,130 --> 00:18:41,100
+يعني تجمع مرت معاكوا في ال biology أوىفي الأحياء
+
+216
+00:18:41,100 --> 00:18:45,680
+بيمور معاكم أكتر هذا الكلام يعني فقط في منطقة
+
+217
+00:18:45,680 --> 00:18:50,880
+الكيميا بهمنا أننا نعرفكوا الشكل الكيميائي لكن بعد
+
+218
+00:18:50,880 --> 00:18:54,940
+هيك إيش وظيفته وكيف بيدخل في الخلية وكيف بيساعد
+
+219
+00:18:54,940 --> 00:18:58,760
+فيها كل هذا منطقة Biology يعني لما بنجرب على ال
+
+220
+00:18:58,760 --> 00:19:04,150
+biochemistry بشكل عام بنعطيكوا إيش؟الشكل الكيميائي
+
+221
+00:19:04,150 --> 00:19:07,270
+ان نكون فاهمين بالظبط ايش ال phospholipids الان
+
+222
+00:19:07,270 --> 00:19:09,990
+افهمنا انه في اتنين fatty acids دلوا زي ما هم
+
+223
+00:19:09,990 --> 00:19:14,030
+مجموعة phosphate مع كذا صار في جزء polar جزء non
+
+224
+00:19:14,030 --> 00:19:17,530
+polar ما إلى ذلك الان بعد ذلك لما تروحوا على ال
+
+225
+00:19:17,530 --> 00:19:20,930
+biology ينحكوا قدامكوا phospholipids ويبدوا
+
+226
+00:19:20,930 --> 00:19:29,370
+يعطوكوا تفاصيل اكثر you have an idea واضح غير
+
+227
+00:19:29,370 --> 00:19:34,760
+ال phospholipidsالـ waxes احنا بتيالي حكينا عنها
+
+228
+00:19:34,760 --> 00:19:40,500
+قولنا E stars فيها aliphatic chain طويل يمين و
+
+229
+00:19:40,500 --> 00:19:44,260
+شمال وهذه ال aliphatic chain هي اللي بتتفاعل مع ال
+
+230
+00:19:44,260 --> 00:19:50,360
+oxygen بتعطيني CO2 زائد H2O زائد ال heat أو ال
+
+231
+00:19:50,360 --> 00:19:54,060
+light الحرارة اللي احنا بنشوفها وعشانك بنحرق الشمع
+
+232
+00:19:54,060 --> 00:20:01,450
+فاحنا لما نحرق الشمع بنحرق حقيقةالسلاسل الألفاتية
+
+233
+00:20:01,450 --> 00:20:07,590
+اللي موجودة على طرفي هذا ال Easter اتكلمنا عن ال
+
+234
+00:20:07,590 --> 00:20:14,830
+waxes مافيش فيه فكرة اكتر بنجي لنوع تاني من ال
+
+235
+00:20:14,830 --> 00:20:18,810
+lipids اللي هم ال terbenes و من ال terbenes هنكتشف
+
+236
+00:20:18,810 --> 00:20:26,150
+انه مشتقة بعدين ل ال steroidsال تيربينز يمكن أكبر
+
+237
+00:20:26,150 --> 00:20:30,590
+عائلة في ال natural products الطبيعية بتطلعها
+
+238
+00:20:30,590 --> 00:20:35,570
+النباتات وغيرها وغيراتها، هذه العائلة بتمتاز إنها
+
+239
+00:20:35,570 --> 00:20:40,250
+مكونة من وحدة أساسية، هذه الوحدة الأساسية هي ال
+
+240
+00:20:40,250 --> 00:20:44,930
+isopentaneالأيزو بنتين الان هنا بيسموها ايزو brain
+
+241
+00:20:44,930 --> 00:20:48,850
+unit فالأيزو brain unit هي الأيزو بنتين، لاحظوا،
+
+242
+00:20:48,850 --> 00:20:52,950
+واحد، اتنين، تلاتة، بهذا الشكل، قولنا هذه ايزو،
+
+243
+00:20:52,950 --> 00:20:57,710
+العدد الكل، أربعة، خمسة، ايزو، بنتين، لو كانت بس
+
+244
+00:20:57,710 --> 00:21:00,670
+تلاتة، شابكا، من هنا، كنا نقول ايزو بروبين، مع
+
+245
+00:21:00,670 --> 00:21:05,650
+أربع ايزو بنتين، بيوتين، ايزو بنتين، ايزو هكسين،
+
+246
+00:21:05,650 --> 00:21:11,590
+هذه الوحدة الـبنتين او ال isoprene unit من اليوم
+
+247
+00:21:11,590 --> 00:21:17,050
+الطالع بنسميها بتتجمع مع بعضها بتعمل جزيئات
+
+248
+00:21:17,050 --> 00:21:20,770
+بنسميها ايش ال turbines فهتلاحظوا القاعدة مباشرة
+
+249
+00:21:20,770 --> 00:21:25,050
+ان ال turbines هتكون مضاعفات عددها لكل مضاعفات ال
+
+250
+00:21:25,050 --> 00:21:30,970
+ايش الخامسة يعني ممكن يجتمعوا جزيئين من ال
+
+251
+00:21:30,970 --> 00:21:34,590
+isoprene unit يعني خمسة و خمسة لما بيجتمع two
+
+252
+00:21:34,590 --> 00:21:40,520
+isoprene units هيصير عندى كام carbonعشرة تمام هذا
+
+253
+00:21:40,520 --> 00:21:47,200
+اللي فيه اجتماع جزيئين من ال isoprene units بنسميه
+
+254
+00:21:47,200 --> 00:21:51,440
+mono turbine ممكن يجتمعوا تلت جزيئات بيصير المجموع
+
+255
+00:21:51,440 --> 00:21:55,960
+الكل خمستاشر بنسميه cis-q turbines ممكن يجتمعوا
+
+256
+00:21:55,960 --> 00:22:01,740
+اربع جزيئات بنسميه di turbines اربعة في خمسةعشرين
+
+257
+00:22:01,740 --> 00:22:05,680
+خمس جزيات خمسة بخمسة خمسة وعشرين sister turbines
+
+258
+00:22:05,680 --> 00:22:10,160
+ممكن يجتمعوا ست جزيات بنسميها tri turbines ممكن
+
+259
+00:22:10,160 --> 00:22:16,680
+تمان جزيات tetra turbines فلاحظوا دائما لما تشوفوا
+
+260
+00:22:16,680 --> 00:22:20,520
+هنا تمانية onygenous alcohol isobarine units هذا
+
+261
+00:22:20,520 --> 00:22:23,920
+أي نوع من ال turbines ايه اسمه على اتنين التمانية
+
+262
+00:22:23,920 --> 00:22:27,940
+tetra turbines الستة tri turbines الأربعة
+
+263
+00:22:30,300 --> 00:22:37,060
+مونو تربين و بيكونوا هدولة جزيئات مختلفة لاحظوا
+
+264
+00:22:37,060 --> 00:22:41,880
+مثلا هاي جزيئ انتوا بتطلع عليه كأنه جزيئ عادي لكن
+
+265
+00:22:41,880 --> 00:22:52,320
+لو احنا اتينا اتطلعنا و قسمنا بهذا الشكل هذا
+
+266
+00:22:52,320 --> 00:22:56,780
+الجزيئ من عشر كربونات عدوا الآن من هنا هاي وحدة ال
+
+267
+00:22:56,780 --> 00:23:02,700
+ISOطلعوا هاي carbon اتنين تلاتة هاذي ال ISO ولا لأ
+
+268
+00:23:02,700 --> 00:23:11,000
+اربعة خمسة هاي الخمس درات هاي isoprene unit ونش
+
+269
+00:23:11,000 --> 00:23:16,240
+نطلع كمان مرة هاي واحد اتنين تلاتة هاي ال ISO
+
+270
+00:23:16,240 --> 00:23:19,640
+اربعة خمسة
+
+271
+00:23:21,670 --> 00:23:25,150
+هي isoprene unit و isoprene unit طبعاً لما بتحدوا
+
+272
+00:23:25,150 --> 00:23:29,190
+بيزيد عليهم مجموعات بيعملوا روابط ثنائية غيره لكن
+
+273
+00:23:29,190 --> 00:23:34,570
+العدد الكلي لل carbons عشرة، خمسة في اتنين، اذا
+
+274
+00:23:34,570 --> 00:23:39,830
+هذا اي نوع من التربين، mono-terbine، إله اسم طبعاً
+
+275
+00:23:40,860 --> 00:23:45,120
+هذا نفس الفكرة لو إجينا نقسمه من هنا أحيانا
+
+276
+00:23:45,120 --> 00:23:49,820
+المركبات زي هذه بتبين يعني مابخترش على بالك أن هي
+
+277
+00:23:49,820 --> 00:23:56,060
+فعلا مكونة من الخمستين لكن لو إحنا إجينا أخدناها
+
+278
+00:23:56,060 --> 00:24:05,940
+بهذا الشكل واضح؟ خلينا نتطلع هاي واحد اتنين تلاتة
+
+279
+00:24:05,940 --> 00:24:12,720
+هي ال ISO أربعةخمسة هذي isoprene unit ولا لأ اه لو
+
+280
+00:24:12,720 --> 00:24:20,420
+اتينا واطلعنا منها واحد اتنين تلاتة اربعة خمسة
+
+281
+00:24:20,420 --> 00:24:26,060
+isoprene unit ولا لأ واضح و بيصير مركبات ماخدة
+
+282
+00:24:26,060 --> 00:24:29,860
+اسماء كتيرة في الدنيا الآن افهمنا ايش معنى
+
+283
+00:24:29,860 --> 00:24:34,600
+turbines مش مطلوب مننا نحفظ ولا مركب لكن لما نسمع
+
+284
+00:24:34,600 --> 00:24:40,130
+turbines they are compounds formed fromIsobrane
+
+285
+00:24:40,130 --> 00:24:44,210
+units الان لو قلنا لكم الـ Monoturbine كم Isobrane
+
+286
+00:24:44,210 --> 00:24:51,390
+unit؟ الـ Diterbine، الـ Triterbine، التتراتربين،
+
+287
+00:24:51,390 --> 00:24:55,510
+وقيتا لو جينا قلنا لكم كم carbon atom التتراتربين
+
+288
+00:24:58,300 --> 00:25:02,120
+تمانية في خمسة مش تمانية ايزوبرين يونيتز تمانية في
+
+289
+00:25:02,120 --> 00:25:07,040
+خمسة اربعين هذه السؤال مرات بتجيكوا اكمل الفراغ و
+
+290
+00:25:07,040 --> 00:25:11,220
+صح و غلط يعني نيجي نقولكوا تتراتيربينز contain 30
+
+291
+00:25:11,220 --> 00:25:17,160
+carbon atoms او 3 ايزوبرين يونيتز او 7 ايزوبرين
+
+292
+00:25:17,160 --> 00:25:24,800
+يونيتز واضح الفكرة اقل التقدير احفظولي ايش يسمى ال
+
+293
+00:25:24,800 --> 00:25:30,670
+monoوالداي و الاتراي و التترا بلاش تحفظوا الإسمين
+
+294
+00:25:30,670 --> 00:25:35,170
+اللي تقعدوا فيهم سيسكيو تيربينز و سيستر تيربينز
+
+295
+00:25:35,830 --> 00:25:42,250
+مونو، داي، تراي، تترا، واضح؟ فلو نسألنا عن عدد ال
+
+296
+00:25:42,250 --> 00:25:45,670
+isoprene units أو عن عدد ال carbon atoms اللي
+
+297
+00:25:45,670 --> 00:25:50,690
+موجودة فيهم، نكون إيش؟ عارفين طبعا اكتر في منهم
+
+298
+00:25:50,690 --> 00:25:55,330
+أحيانا البعض حتى من مصدر حيوان بيسموه squalene هذا
+
+299
+00:25:55,330 --> 00:26:01,060
+في أزل تلاتين6 isoprene units 30 carbon atoms
+
+300
+00:26:01,060 --> 00:26:06,420
+لاحظوا معنى ال beta carotene ال beta carotene اللي
+
+301
+00:26:06,420 --> 00:26:10,240
+موجود في الجزر و اللي بيعطي الجزر اللون الأصفر
+
+302
+00:26:10,240 --> 00:26:17,380
+تبعه برضه هذا لو اجينا جسمناه هلاحظ انه عبارة عن
+
+303
+00:26:17,380 --> 00:26:22,930
+ايشتربين من عدة isobrain units هذا ال beta
+
+304
+00:26:22,930 --> 00:26:28,310
+-carotene لما الإنسان بياخده في ال enzymes بيكسر
+
+305
+00:26:28,310 --> 00:26:32,150
+من النص يعني اتخيلوا هذا الشكل العام بدون تفاصيل
+
+306
+00:26:32,150 --> 00:26:38,690
+كسرناه من النص من هنا نصه اتطلع عليه هذا النص
+
+307
+00:26:38,690 --> 00:26:45,480
+المشترك منههو عبارة عن ايش؟ vitamin A بناء على ذلك
+
+308
+00:26:45,480 --> 00:26:51,560
+البني آدم اللي بياكل جزر كتير اللي بياكل جزر كتير
+
+309
+00:26:51,560 --> 00:26:59,440
+بإمكانكوا تتخيلوا ان الجزر بهذا الشكل تمام؟ ان
+
+310
+00:26:59,440 --> 00:27:04,880
+الجزر بهذا الشكل الان vitamin A هو هذا الجزء
+
+311
+00:27:05,720 --> 00:27:08,920
+Vitamin A هو هذا الجزر الآن اللي أخد ال beta
+
+312
+00:27:08,920 --> 00:27:14,460
+-carotene من الجزر بعملية كسر من نص ال beta
+
+313
+00:27:14,460 --> 00:27:17,920
+-carotene بيطلع عنده ال vitamin A تخيلوا أن حد ما
+
+314
+00:27:17,920 --> 00:27:23,960
+أخدش ال beta-carotene وقعد يكوّن هذا من مكوناته
+
+315
+00:27:23,960 --> 00:27:29,910
+الأولية فأسهل أشياء البني آدم يأكل الجزرالجزر فيه
+
+316
+00:27:29,910 --> 00:27:34,710
+ال beta-carotene الكامل بعملية تكسور بسيطة صار في
+
+317
+00:27:34,710 --> 00:27:39,950
+عنده vitamin A و vitamin A طبعا اللي لما تدرسوا
+
+318
+00:27:39,950 --> 00:27:42,710
+عملية الإبصار بالذات الناس اللي هيدرسوا بصريات
+
+319
+00:27:42,710 --> 00:27:48,510
+طبية في رابطة cis بتصير trans اسمه retinol
+
+320
+00:27:48,510 --> 00:27:52,310
+بالأكسجين بيصير له أكسدة مع isomerization cis
+
+321
+00:27:52,310 --> 00:27:57,260
+trans بيصير cis-retinalهذا الانتقال بعد ذلك بين
+
+322
+00:27:57,260 --> 00:28:00,640
+الـ cis والـ trans مع انتصاص الضوء هو اللي بيبقى
+
+323
+00:28:00,640 --> 00:28:05,570
+مسئول عن كل عملية الإبصاريعني هذا ال 11-cis
+
+324
+00:28:05,570 --> 00:28:09,890
+-retinal اللي فيها دي موجودة الرابطة cis ومع
+
+325
+00:28:09,890 --> 00:28:13,070
+امتصاص الضوء بتصير ال Trans بعدين بتعود تفقد الضوء
+
+326
+00:28:13,070 --> 00:28:17,350
+بترجع cis هذه الإشارات الضوئية كلها هي اللي بتنقل
+
+327
+00:28:17,350 --> 00:28:22,190
+للمخ و بتعمل إيش الصورة فكل عملية الإبصار معتمد
+
+328
+00:28:22,190 --> 00:28:26,730
+على إيش؟ على ال 11-cis-retinal 11 طبعا على موقع
+
+329
+00:28:26,730 --> 00:28:31,170
+الرابطة الزوجية هنا 11 11-cis-retinal طب 11-cis
+
+330
+00:28:31,170 --> 00:28:35,380
+-retinal من وين جبناها؟من vitamin A، طب vitamin A
+
+331
+00:28:35,380 --> 00:28:39,800
+من وين جيبناه؟ من الجزر، إذا المادة الأساسية
+
+332
+00:28:39,800 --> 00:28:43,860
+للإبصار ال 11th-seretinal إجت من vitamin A، إجت من
+
+333
+00:28:43,860 --> 00:28:50,780
+الجزر، فالناس اعترافا بالأصل، إيش بيقولوا؟ الجزر
+
+334
+00:28:50,780 --> 00:28:54,510
+بيقوى النظر، بيقولوش vitamin A بيقوى النظرقولوا
+
+335
+00:28:54,510 --> 00:29:00,710
+الجزر بجوّل نظر لأن الجزر هو مصدر ايش؟ vitamin A و
+
+336
+00:29:00,710 --> 00:29:04,970
+vitamin A هو اللي عمل لهذا واضح؟ ولذلك لو سألنا أي
+
+337
+00:29:04,970 --> 00:29:10,470
+بني آدم من الأصل تبعك ممكن يقول الأب بس بنفس الوقت
+
+338
+00:29:10,470 --> 00:29:15,990
+ممكن يقول ايش؟ الجد فالعرب لما كانوا بيتباهوا
+
+339
+00:29:15,990 --> 00:29:21,910
+كانوا بيتباهوا بإيش مرات كتيرة؟ بالأجدادمظبوط ولا
+
+340
+00:29:21,910 --> 00:29:28,350
+لأ؟ لما الفرزق كان بيتباهى بأجداده وببيته وبعيلته
+
+341
+00:29:28,350 --> 00:29:34,070
+ويقول بيت بناه لنا المليك وما بنى حكم السماء فإنه
+
+342
+00:29:34,070 --> 00:29:40,270
+لا ينقض بيت زرارة محتبن بفنائه ومجاشع وابو الفوارس
+
+343
+00:29:40,270 --> 00:29:45,870
+نحشله، هدول أجداده، الآن مين جد السسر تنال؟ الجزر
+
+344
+00:29:47,990 --> 00:29:52,570
+احنا مابنقولش عاد انتبهوا معناه احنا لما نرجع خطوة
+
+345
+00:29:52,570 --> 00:29:57,830
+خطوة للخلف بالكيميا بنقول ال beta-carotene الان
+
+346
+00:29:57,830 --> 00:30:00,230
+واحدة منكم بدها تروح تقول عند إمها ال beta
+
+347
+00:30:00,230 --> 00:30:03,110
+-carotene ولا بتقول اهو ال beta-carotene نفسه من
+
+348
+00:30:03,110 --> 00:30:09,510
+وين من الجزر اه فبنقول في الآخر الجزر بجوّر نظر
+
+349
+00:30:09,510 --> 00:30:13,250
+الان السلسلة جزر beta-carotene، vitamin A، S،
+
+350
+00:30:13,250 --> 00:30:17,470
+ريتينال افهمنا كيف بتيجي السلسلة؟
+
+351
+00:30:21,760 --> 00:30:29,200
+الآن من هذه الـ Isobrane units أيضا بتكون مركبات
+
+352
+00:30:29,200 --> 00:30:35,760
+من أربع حلقات تلت حلقات سداسيات و حلقة خماسية بهذا
+
+353
+00:30:35,760 --> 00:30:39,880
+الشكل هذول أفلا كمان جايين من ال Isobrane units
+
+354
+00:30:39,880 --> 00:30:46,620
+بنسميهم إيش؟ Steroids فال Steroids ببساطة هم عبارة
+
+355
+00:30:46,620 --> 00:30:52,330
+عن Lipidsمن أربع حلقات تلت حلقات سداسية و حلقة
+
+356
+00:30:52,330 --> 00:30:56,570
+خمسية بالشكل هذا يعني ما نحطهم مش بشكل مستقيم لأ
+
+357
+00:30:56,570 --> 00:31:02,050
+لهم شكل خلاص بينطبع إيش صورة في ذهن الإنسان طبعا
+
+358
+00:31:02,050 --> 00:31:07,430
+هدول الأربع حلقات فيهم مجموعات في أماكن مختلفة حسب
+
+359
+00:31:07,430 --> 00:31:12,770
+اختلاف المجموعات تبعتهم بيصيروا يطلعولنا إيشأنواع
+
+360
+00:31:12,770 --> 00:31:17,470
+من الجزيئات و من الهرمونات و ما إلى ذلك ال
+
+361
+00:31:17,470 --> 00:31:22,510
+backbone تبعهم اللي هو الهيكل الأساسي تبعهم الأربع
+
+362
+00:31:22,510 --> 00:31:27,990
+حلقات لكن الاختلاف في المجموعات اللي موجودة عليهم
+
+363
+00:31:27,990 --> 00:31:35,160
+فمن أشهرهم على سبيل المثال الكوليسترونواضح؟
+
+364
+00:31:35,160 --> 00:31:41,360
+الكوليسترول في النهاية بيصف من 27 carbon atom محضر
+
+365
+00:31:41,360 --> 00:31:48,100
+من الانوستيرول موجود في ال animal cells بشكل أساسي
+
+366
+00:31:48,100 --> 00:31:54,490
+بتركز في ال brain و في الحبل الشوكةSpinal cord هو
+
+367
+00:31:54,490 --> 00:31:59,450
+المكون الأساسي للجاليستون الجاليستون يعني حصوة
+
+368
+00:31:59,450 --> 00:32:04,290
+المرارة طبعا الناس اللي منكوا حدرسوا الحصوات سبق
+
+369
+00:32:04,290 --> 00:32:08,070
+أنه مرات اتكلمنا عن الحصوات اللي من الأملاح في
+
+370
+00:32:08,070 --> 00:32:14,970
+الكيلية وقلنا انها الشرر الاش؟ مين متذكرة؟الـ
+
+371
+00:32:14,970 --> 00:32:19,070
+Oxalic Acid Salts لما حكينا عن ال Oxalic Acid و
+
+372
+00:32:19,070 --> 00:32:23,090
+قلتلكوا احفظوا شكل ال Oxalic Acid ال Oxalic Acid
+
+373
+00:32:23,090 --> 00:32:27,070
+Salts متذكرينه؟ اقول لكوا فيه فوسفات و فيه من ال
+
+374
+00:32:27,070 --> 00:32:31,610
+Oxalic Acid، ال Oxalic Acid هذا الحامض اللي مكون
+
+375
+00:32:31,610 --> 00:32:39,440
+من كم؟ Carbon, Diacid, Oxalic AcidOxalic acid لما
+
+376
+00:32:39,440 --> 00:32:43,040
+يعمل salts من هنا هذه ال salts بتعمل حصوات إيش
+
+377
+00:32:43,040 --> 00:32:47,680
+الكيلية؟ حصوات الكيلية حجار stones يعني لما ناس
+
+378
+00:32:47,680 --> 00:32:52,280
+أحيانا حد منهم بيعمل عملية الحصوة و بيطلق ..
+
+379
+00:32:52,280 --> 00:32:56,900
+بيحطوها بالشكوش بيكسروها حصوة إيش؟ حجار بينما
+
+380
+00:32:56,900 --> 00:33:03,850
+حصوات المرارة حصوات مطاطيةيعني دهنية بتنجص بإش
+
+381
+00:33:03,850 --> 00:33:08,790
+بالسكينة بتنجص بالسكينة هذه حصوات المرارة من الإش
+
+382
+00:33:08,790 --> 00:33:17,120
+مكونها الأساسي هوالكلسترول واضح مكونها الأساسي هو
+
+383
+00:33:17,120 --> 00:33:24,020
+الكلسترول طبعا الكلسترول بيضلوا يرتبط في الذهن هو
+
+384
+00:33:24,020 --> 00:33:29,500
+الكلسترول واحد الكلسترول واحد كليسترول كيميائيا
+
+385
+00:33:29,500 --> 00:33:35,580
+كلسترول لكن مرات ربما تصيروا تسمعوا والان بحكي
+
+386
+00:33:35,580 --> 00:33:40,390
+بشكل عام كثقافة عامة جداو بتعود تتوسع فيه اكيد في
+
+387
+00:33:40,390 --> 00:33:47,430
+ال biology بتسمع كوليسترول سيء و كوليسترولحميد او
+
+388
+00:33:47,430 --> 00:33:55,970
+مفيد اه اللي هي ال HDL و LDL high density
+
+389
+00:33:55,970 --> 00:34:00,210
+lipoprotein و low density lipoprotein الان بيصير
+
+390
+00:34:00,210 --> 00:34:04,610
+الكوليسترول نفسه هذا يعني الكوليسترول واحد لكن هذا
+
+391
+00:34:04,610 --> 00:34:13,300
+الكوليسترول لما نقول انه في عنده HDLو LDL و هذا ال
+
+392
+00:34:13,300 --> 00:34:16,900
+LDL هو اللي بيقولوا عنه الكوليسترول ايش السيء اللي
+
+393
+00:34:16,900 --> 00:34:21,200
+بيعمل ترسبات وجلطات هذا الكوليسترول نفسه بيصير
+
+394
+00:34:21,200 --> 00:34:27,630
+محمول هيكا في قلب بروتين معينالان البروتين انواع
+
+395
+00:34:27,630 --> 00:34:31,510
+يعني خلينا نتخيل انه ممكن البروتين الأحمر و ممكن
+
+396
+00:34:31,510 --> 00:34:36,350
+بروتين تاني أخضر يحمله فحسب نوع البروتين الان
+
+397
+00:34:36,350 --> 00:34:40,090
+الكلسترول نفترض اللي محمول في البروتين الأحمر
+
+398
+00:34:40,090 --> 00:34:46,590
+بيكون كثافته أقل شوية صغيرة من الكلسترول إذا كان
+
+399
+00:34:46,590 --> 00:34:52,510
+محمول في بروتين تاني في بروتين تاني هيك نفترضههذا
+
+400
+00:34:52,510 --> 00:34:57,190
+البروتين الأخضر فبصير بالمجموع في عنده low density
+
+401
+00:34:57,190 --> 00:35:02,730
+lipoprotein و high density lipoprotein طبعا واحد
+
+402
+00:35:02,730 --> 00:35:09,420
+منهمدار والثاني مفيد اللي داره بيحب ان نسبته تكون
+
+403
+00:35:09,420 --> 00:35:12,680
+دائما قليلة ومحددة بتاخدوها في التحاليل الطبية
+
+404
+00:35:12,680 --> 00:35:16,600
+اللي هو ال low density ال high density حتى لما
+
+405
+00:35:16,600 --> 00:35:21,140
+بيزيد بيكون ايش بيكون كويس في كل الأحوال مش ال
+
+406
+00:35:21,140 --> 00:35:26,650
+cholesterol نوعينلأ الكوليسترول ككلسترول نوع واحد
+
+407
+00:35:26,650 --> 00:35:31,670
+هو هذا الجزء كوليسترول جزء محدد لكن الكوليسترول
+
+408
+00:35:31,670 --> 00:35:38,140
+محمول في أي بروتينصار نوعين يعني الكوليسترول مع
+
+409
+00:35:38,140 --> 00:35:42,720
+بروتين ألف صار نوع بكثافة منخفضة الكوليسترول مع
+
+410
+00:35:42,720 --> 00:35:47,900
+بروتين با صار نوع تاني بكثافة مرتفعة لكن
+
+411
+00:35:47,900 --> 00:35:54,440
+الكوليسترول نوع واحد الكوليسترول كجزء كيميائي كجزء
+
+412
+00:35:54,440 --> 00:35:59,140
+كيميائي نوع واحد لكن هذا الكوليسترول محمول في أي
+
+413
+00:35:59,140 --> 00:36:06,910
+بروتين هنا بيصير إيش الخلاف واضح؟فعشان هيك حيصير
+
+414
+00:36:06,910 --> 00:36:13,070
+عندكم HDL و LDL و لما تصيروا تحللوا بعدها
+
+415
+00:36:13,070 --> 00:36:19,330
+كوليسترول بتصيروا و الله تبحثوا عن total كوليسترول
+
+416
+00:36:19,330 --> 00:36:23,690
+و لا تقعدوا تفصلوا فيه بدي أشوف جديش ال HDL و جديش
+
+417
+00:36:23,690 --> 00:36:28,390
+ال LDL بصير هذا جزء من العلم اللي هتاخدوه بالتفصيل
+
+418
+00:36:29,230 --> 00:36:34,110
+بس احنا الآن بناخد الشكل العام للكلسترول وقلنا عنه
+
+419
+00:36:34,110 --> 00:36:38,110
+مكون أساسي لحصوة المرارة وقلنا عنه انه مكون من أكم
+
+420
+00:36:38,110 --> 00:36:45,910
+حلقة؟ أربع حلقات وهي هنا شكل حصوة المرارة الان
+
+421
+00:36:45,910 --> 00:36:50,910
+لاحظوا ان الكوليسترول أساسي في الهرمونات الجنسية
+
+422
+00:36:51,910 --> 00:36:57,310
+سواء كانت الهرمونات الجنسية الذكورية أو الأنثوية
+
+423
+00:36:57,310 --> 00:37:01,930
+الهرمونات الأنثوية بيسموها Astrogens ال Astrogens
+
+424
+00:37:01,930 --> 00:37:06,730
+اللي هي ال Female Hormones والهرمونات بتاع ال Male
+
+425
+00:37:06,730 --> 00:37:11,270
+Hormones إيش بيسموهم؟ Androgens من أشهرهم بتاع ال
+
+426
+00:37:11,270 --> 00:37:16,810
+females ال Estradiol و ال Progesteroneلمّا نطلع
+
+427
+00:37:16,810 --> 00:37:21,110
+عليهم، إيش الوظائف تبعتهم؟ وظائفهم تنظيم الصفات
+
+428
+00:37:21,110 --> 00:37:25,930
+الجنسية، خشونة .. نعومة الصوت عند الإناف مثلا،
+
+429
+00:37:25,930 --> 00:37:30,010
+خشونة الصوت عند الرجال، الشعر، بعدين بتدخلوا في
+
+430
+00:37:30,010 --> 00:37:33,590
+الدورة الشهرية عند النساء، كل هذا الكلام بيمنعوا
+
+431
+00:37:33,590 --> 00:37:37,310
+التبويض في مرحلة معينة لما بيصير الحمل، بييجي في
+
+432
+00:37:37,310 --> 00:37:40,850
+التبويض، كل هذا الكلام، مين اللي بيقوم فيه؟ اللي
+
+433
+00:37:40,850 --> 00:37:44,710
+هي ال Astrogens استرديولوبروجسترون
+
+434
+00:37:45,920 --> 00:37:51,480
+عند الرجال الهرمون او عند الذكور ايش تستوستيرون و
+
+435
+00:37:51,480 --> 00:37:56,740
+أندروستيرون الان لو اجينا تطلعنا عليهم كلهم ايش
+
+436
+00:37:56,740 --> 00:38:01,120
+استيرويد انا عملتلهم صورة مكبرة شوية تطلعوا
+
+437
+00:38:01,120 --> 00:38:07,100
+استيرويد استيرويد استيرويداستيرويد طب وين الاختلاف
+
+438
+00:38:07,100 --> 00:38:12,180
+بينهم؟ في المجموعات الوظيفية يعني لو اجيت انا
+
+439
+00:38:12,180 --> 00:38:18,660
+لليبروجيستيرون مثلا والتيستيستيرون اشهر هرمون عند
+
+440
+00:38:18,660 --> 00:38:22,140
+الاناث دائما بيكونوا ايش يقولوا؟ ليبروجيستيرون عند
+
+441
+00:38:22,140 --> 00:38:26,280
+الذكور؟ التيستيستيرون ابدوا واتأملوا في الشكلين
+
+442
+00:38:26,280 --> 00:38:31,980
+تبعونهم ابدوا من عندها الـ C double bond O و
+
+443
+00:38:31,980 --> 00:38:38,570
+الحلقةو CH3 و لاحظوا كيف ال stereochemistry مهمة
+
+444
+00:38:38,570 --> 00:38:43,310
+جدا .. ال stereochemistry .. الأن منها .. منها ..
+
+445
+00:38:43,310 --> 00:38:48,790
+منها .. في الآخر ماصفش غير هذا الفرق .. Acetyl
+
+446
+00:38:48,790 --> 00:38:53,630
+group و لا OH group .. بتخلي واحد هرمون أنثوي و
+
+447
+00:38:53,630 --> 00:38:59,440
+بتخلي الثاني هرمون ذكوريلاحظوا كم التغير البسيط ..
+
+448
+00:38:59,440 --> 00:39:04,180
+التغير البسيط في مجموعة كيميائية جاعت بعكس الوظائف
+
+449
+00:39:04,180 --> 00:39:07,680
+احنا شوفنا اكتر من هيك احنا شوفنا كمان في ال
+
+450
+00:39:07,680 --> 00:39:11,580
+stereo chemistry انه تغير شكل المجموعات بيحول
+
+451
+00:39:11,580 --> 00:39:15,980
+المركب من سام إلى مفيده عشان هيك انا لاحظوا كم
+
+452
+00:39:15,980 --> 00:39:19,460
+عندي stereo chemistry هانو هانو هانو كل هذا الكلام
+
+453
+00:39:19,460 --> 00:39:25,280
+مدروس بشكل كامل عند العلماء فهذه ال six hormones
+
+454
+00:39:25,280 --> 00:39:31,280
+they arein general استيرويدز بينقسموا زي ما اتفقنا
+
+455
+00:39:31,280 --> 00:39:35,620
+إلى كام نوع استروجينز اللي هي ال female hormones و
+
+456
+00:39:35,620 --> 00:39:39,420
+أندروجينز و في منها أنواع و أشكال مش مطلوب نحفظ
+
+457
+00:39:39,420 --> 00:39:44,620
+بالتأكيد ولا شكل بس يكون فاهمين الفكرة أن كلهم
+
+458
+00:39:44,620 --> 00:39:49,800
+استيرويدز و أن الشبه بينهم كبير جدا لكن اختلاف
+
+459
+00:39:49,800 --> 00:39:55,400
+مجموعة يؤدي إلى اختلاف كبير في الوظيفةطبعا من
+
+460
+00:39:55,400 --> 00:40:00,960
+هدولة بيصير عندي أشياء اللي هي بنطلع منهم أدوية
+
+461
+00:40:00,960 --> 00:40:10,870
+على سبيل المثال الدواء اللي هيالأقراس منع الحمل هي
+
+462
+00:40:10,870 --> 00:40:17,290
+أقراس شبيهة بهذه الهرمونات مثلا هنا دوة هي بيشبه
+
+463
+00:40:17,290 --> 00:40:22,530
+ال استيرويد برضه هذا بيساعد على الإجهاد بدون
+
+464
+00:40:22,530 --> 00:40:26,590
+عمليات جراحية في مراحل معينة مقارنة في أوروبا
+
+465
+00:40:26,590 --> 00:40:31,150
+وغيرها لو بدنا نشوف ال cortisone اللي بيستعملوه
+
+466
+00:40:31,150 --> 00:40:35,770
+لالتهاب المفاصل و للناس اللي عندهم تكسر في ال
+
+467
+00:40:35,770 --> 00:40:41,090
+plateletsفي التجلط هذا ال Cortisone الناس اللي
+
+468
+00:40:41,090 --> 00:40:46,150
+بياخدوه بتشوفوهم كيف بينتفخوا اه هاي ال Cortisone
+
+469
+00:40:46,150 --> 00:40:52,230
+استيرويدز بالنسبة شبه .. بالنسبة شبه كبيرة في ال
+
+470
+00:40:52,230 --> 00:40:56,630
+sex hormone يستعمل بشكل أساسي in the treatment of
+
+471
+00:40:56,630 --> 00:41:05,210
+arthritis التي هي إيش؟ التهاب المفاصلالمفاصل والـ
+
+472
+00:41:05,210 --> 00:41:09,890
+platelets فالخلاصة انه هيرمونات كتير مأخوذ منها
+
+473
+00:41:09,890 --> 00:41:14,950
+كمان أدوية كتير كلها في طبيعتها ايش بنسميها؟
+
+474
+00:41:14,950 --> 00:41:19,270
+استيرويدال وعشان هيك هتصيروا تلاقوا في الأدوية وفي
+
+475
+00:41:19,270 --> 00:41:23,850
+المضادات الحيوية انه تلاقوا استيرويدال drugs يعني
+
+476
+00:41:23,850 --> 00:41:26,830
+أدوية من الاستيرويدس ايش يعني أدوية من
+
+477
+00:41:26,830 --> 00:41:27,810
+الاستيرويدس؟
+
+478
+00:41:32,390 --> 00:41:36,590
+اربع حلقات حتى لو زعلوا جماعة رابعة مش موضوع احنا
+
+479
+00:41:36,590 --> 00:41:44,430
+بنقول ايش اربع حلقات الاستيرويد اربع حلقات ابهيك
+
+480
+00:41:44,430 --> 00:41:50,350
+بننتهي من اعطاء فكرة عامة عن موضوع ال labels و الى
+
+481
+00:41:50,350 --> 00:41:51,710
+لقاء قادم ان شاء الله
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..945958f6bb3e43700e703f3c6e821501612c9e3c
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/L036VR_7BVU_postprocess.srt
@@ -0,0 +1,1832 @@
+1
+00:00:21,210 --> 00:00:26,340
+بسم الله الرحمن الرحيمباقي عندنا في موضوع
+
+2
+00:00:26,340 --> 00:00:30,340
+التفاعلات او التفاعلات المرتبطة بال
+
+3
+00:00:30,340 --> 00:00:34,940
+stereochemistry شغلتين بسيطات احنا اتكلمنا في
+
+4
+00:00:34,940 --> 00:00:38,600
+الاول على نقطة كتير مهمة او على تفاعل كتير مهم
+
+5
+00:00:38,600 --> 00:00:43,740
+قولنا دائما في المختبر بالوضع الطبيعي لما نعمل
+
+6
+00:00:43,740 --> 00:00:47,560
+generation of a chiral center بيطلع عندى racemic
+
+7
+00:00:47,560 --> 00:00:50,400
+mixture equal mixture of enantiomers و هذا بده
+
+8
+00:00:50,400 --> 00:00:54,830
+غلبة و بده فصل و ما إلى ذلكوالان بيحاولوا انهم
+
+9
+00:00:54,830 --> 00:00:59,250
+يتغلبوا على هذا الكلام من خلال تقنيات حديثة في
+
+10
+00:00:59,250 --> 00:01:04,390
+التحضير بيسموها asymmetric synthesis هذا التفاعل
+
+11
+00:01:04,390 --> 00:01:10,030
+الأولالتفاعل التاني، لو أنا يا تورا بعمل تفاعل
+
+12
+00:01:10,030 --> 00:01:15,450
+بعيدا عن ال chiral center، الآن إيش معنى بعيدا عن
+
+13
+00:01:15,450 --> 00:01:21,310
+ال chiral center؟ بمعنى لأكسر رابطة متصلة بال
+
+14
+00:01:21,310 --> 00:01:25,330
+chiral center، يعني الأربع روابط المتصلين بال
+
+15
+00:01:25,330 --> 00:01:30,950
+chiral center بكسرهم مشكل ما بعد ذلك يعتبر ايش؟
+
+16
+00:01:30,950 --> 00:01:35,230
+تفاعل بعيد عن الـ Chiral Center واضح الفكرة؟ يعني
+
+17
+00:01:35,230 --> 00:01:39,110
+مثلا في هذا المركب، عندي هنا أنا Chiral Center
+
+18
+00:01:39,110 --> 00:01:45,010
+متصل بـ Methyl و بـ Ethyl و COH و بH، الآن هذا الـ
+
+19
+00:01:45,010 --> 00:01:50,240
+Chiral Center عليه كام رابطةأربع روابط لو أنا بدي
+
+20
+00:01:50,240 --> 00:01:55,460
+أبدل مجموعة ال O H هنا اللي هي ال acidic O H
+
+21
+00:01:55,460 --> 00:02:01,200
+مجموعة ال O H الحامضية هذه كلها بمجموعة O Ethyl
+
+22
+00:02:01,200 --> 00:02:06,420
+بمعنى في الكيميا هذا التفاعل هنتعلمه بنبدل فيه ال
+
+23
+00:02:06,420 --> 00:02:12,340
+acid ل E starباستعمال التفاعل مع الكحول شيلت الـ
+
+24
+00:02:12,340 --> 00:02:19,240
+OH و خلتها ايش؟ O Ethan الان هذه الأربع رواضة كسرت
+
+25
+00:02:19,240 --> 00:02:25,380
+جزء منها؟ لأ وبناء على ذلكالجيومتري حوالين
+
+26
+00:02:25,380 --> 00:02:28,640
+الكايرال كاربون الشكل اللذس حوالين الكايرال كاربون
+
+27
+00:02:28,640 --> 00:02:33,620
+بيضل زي ما هو فأنا كأن بعمل عملية ايش نسخ و لصق
+
+28
+00:02:33,620 --> 00:02:38,960
+بلغة الكمبيوتر يعني باجي بعمل نسخ لهذا بكل موابط و
+
+29
+00:02:38,960 --> 00:02:43,740
+لاحظوا ال H باتجاه ال CO باتجاه ال CH3 ال إثل بحطه
+
+30
+00:02:43,740 --> 00:02:48,120
+هنا و بعمل التغيير اللي عندهو بناء على ذلك بنقول
+
+31
+00:02:48,120 --> 00:02:52,740
+انه تم عنده retention of configuration يعني الشكل
+
+32
+00:02:52,740 --> 00:02:58,360
+ضل زي ما هو اتجاه الاربع روابط اللي محيطين بال
+
+33
+00:02:58,360 --> 00:03:03,440
+chiral center ضالهم ايش زي ما هو لو انا بدي اعطيكم
+
+34
+00:03:03,440 --> 00:03:07,700
+مثال يعني تخيلوا مثلا انا بهذا الشكل هينعمل chiral
+
+35
+00:03:07,700 --> 00:03:12,260
+center من اربع شغلاتوأتيت أعمل التفاعل هنا كان
+
+36
+00:03:12,260 --> 00:03:15,900
+مافيش في إيدي جلم امسكت جلم هل غيرت في اتجاه
+
+37
+00:03:15,900 --> 00:03:19,480
+الأربع روابط ولا في عند retention of configuration
+
+38
+00:03:19,480 --> 00:03:23,760
+في عند retention of configuration إذا التفاعل
+
+39
+00:03:23,760 --> 00:03:28,720
+بعيدا عن ال chiral center بتم في retention of
+
+40
+00:03:28,720 --> 00:03:31,660
+configuration معنى retention of configuration أن
+
+41
+00:03:31,660 --> 00:03:36,600
+اتجاهات الروابط الأربع تبقى كما هي لم نكسر شيء
+
+42
+00:03:36,600 --> 00:03:42,300
+حولهاكذلك الحال هنا احنا حاطين مثال تاني لو فعلنا
+
+43
+00:03:42,300 --> 00:03:47,740
+هذا المركب يعلن الكايرال سنتر بدلنا هذه ال O H
+
+44
+00:03:47,740 --> 00:03:51,740
+خلناها C double bond O باستعمال اكسدة ابعام
+
+45
+00:03:51,740 --> 00:03:53,620
+المؤكسل عادة بنسميه
+
+46
+00:03:56,470 --> 00:04:01,290
+الان هذول الاربع روابط صار عندهم تغيير و لا تغيير
+
+47
+00:04:01,290 --> 00:04:06,390
+بعد الكايرالسينفاق بعد اذا كل الاتجاهات تبقى كما
+
+48
+00:04:06,390 --> 00:04:13,840
+هي CLH CH2 CH3 الـC هادىالتغير بعدها ما كسرت روابط
+
+49
+00:04:13,840 --> 00:04:16,660
+بالتصيلة بال chiral center مرة تانية في عندي
+
+50
+00:04:16,660 --> 00:04:20,280
+retention of configuration إذا ال reaction away
+
+51
+00:04:20,280 --> 00:04:23,160
+from a chiral center results in retention of
+
+52
+00:04:23,160 --> 00:04:30,000
+configuration الآن بهمني أعطي بس ملاحظة خفيفةالـ
+
+53
+00:04:30,000 --> 00:04:34,600
+retention of configuration معناه أن الأربع روابط
+
+54
+00:04:34,600 --> 00:04:39,720
+تبقى في اتجاهاتها ليس له علاقة .. ليس له علاقة
+
+55
+00:04:39,720 --> 00:04:46,100
+بكلمة R و S أنا هنا و أنا بشتغل كتبت R ولا S ولا
+
+56
+00:04:46,100 --> 00:04:50,380
+شفت أن ال R دلت R ولا ال S دلت S؟ ماجبتش سيرة
+
+57
+00:04:50,380 --> 00:04:55,100
+هالكلام، ليش؟ لأنه أنا لما بغير مجموعة هنا أو هنا
+
+58
+00:04:55,100 --> 00:05:02,890
+ممكن الأولويات تتغير؟ أكيدأكيد حتى لو غيرت مجموعة
+
+59
+00:05:02,890 --> 00:05:06,790
+بعيد ممكن يصير فيه تغيير بالأولويات و لذلك ممكن R
+
+60
+00:05:06,790 --> 00:05:11,430
+عند الضل R ممكن R تصير S ممكن S تصير R ممكن S تظل
+
+61
+00:05:11,430 --> 00:05:16,370
+S أو تتقلب إلى R هذا موضوع ما درسته انا اطلاقا انا
+
+62
+00:05:16,370 --> 00:05:21,650
+بدرس الأربع روابط في اتجاهاتهم فيهم تغيير ولا لأ
+
+63
+00:05:21,650 --> 00:05:26,020
+هى معناه retention of configuration الان R و Sمن
+
+64
+00:05:26,020 --> 00:05:31,160
+أول و جديد في عندكم اشي اسمه قواعد ترتيب المجموعات
+
+65
+00:05:31,160 --> 00:05:36,320
+حسب الأولويات واحد اتنين تلاتة اربعة بنرتبهم ضلت
+
+66
+00:05:36,320 --> 00:05:41,460
+الارار صارت اسم مش مشيء بالنسبة الي واضح الفكرة
+
+67
+00:05:41,460 --> 00:05:47,200
+فكلمة retention of configurationلا تعني اطلاقا ..
+
+68
+00:05:47,200 --> 00:05:52,700
+لا تعني اطلاقا ان ال R دلت R او ال S دلت S لأ تعني
+
+69
+00:05:52,700 --> 00:05:58,520
+ان الأربع روابط ضالهم باتجاههم ال R و ال S اولويات
+
+70
+00:05:58,520 --> 00:06:01,420
+اللي بيحسب اولويات يشوف حسب المثال اللي عنده
+
+71
+00:06:01,420 --> 00:06:05,480
+هتلاقوا مثال بتم فيه تغيير مثال بتم مش فيه تغيير
+
+72
+00:06:05,480 --> 00:06:09,460
+حسب هالمجموعة اللي طلعت و المجموعة اللي اجت هذا
+
+73
+00:06:09,460 --> 00:06:15,200
+موضوع تاني واضح الفكرة؟وهذا كثير بنسألكم بمعناه
+
+74
+00:06:15,200 --> 00:06:19,280
+انه هالمعنى كلمة retention of configuration means
+
+75
+00:06:19,280 --> 00:06:24,420
+are must be are in the product لأ مش ضروري ممكن
+
+76
+00:06:24,420 --> 00:06:29,400
+تظل ممكن تتغير هذا موضوع و هذا موضوع تاني
+
+77
+00:06:33,710 --> 00:06:39,030
+هذه تفاعلات بناخدها بعدين بس بنعطيها كأمثلة يعني
+
+78
+00:06:39,030 --> 00:06:43,710
+هذا تأكسد كحول إلى aldehyde لما ندرس chapter
+
+79
+00:06:43,710 --> 00:06:49,410
+الكحولات ب chapter 7 بنشرحه الآن بديش أنا أسمي لا
+
+80
+00:06:49,410 --> 00:06:52,750
+كحول ولا aldehyde أنا قلت ال Canada دي CO single
+
+81
+00:06:52,750 --> 00:06:57,840
+bond صارت CO double bond غيرت هان ولا لأ؟تستعجلوش
+
+82
+00:06:57,840 --> 00:07:02,880
+العلم هذا تحول حامض إلى Easter بدلت ال OH ب Oethel
+
+83
+00:07:02,880 --> 00:07:08,140
+بدرسه ب Chapter 10 مش هو موضوعي غيرت بدي ألغي كل
+
+84
+00:07:08,140 --> 00:07:13,060
+اللي كاتبه و أكتب XY عشان اترايحيني أعصابي خلت XY
+
+85
+00:07:13,060 --> 00:07:14,980
+واضح؟
+
+86
+00:07:16,500 --> 00:07:21,120
+دائما تتعبوش أنفسكم في الفكرة غير الأساسية بدلت X
+
+87
+00:07:21,120 --> 00:07:26,760
+بY إيش التفاعل مش مشكلة مش X صارت Y تفاعل general
+
+88
+00:07:26,760 --> 00:07:31,520
+بدلته بعيدا عن ال chiral center إيش بيظل عنده
+
+89
+00:07:31,520 --> 00:07:37,960
+retention إنما هدولا التفاعلين كتفصيل بناخدهم في
+
+90
+00:07:37,960 --> 00:07:43,160
+chapter 7 أو chapter 10 لكن استعانا فيهم كأمثلة
+
+91
+00:07:45,090 --> 00:07:50,130
+التفاعل التالت generation of a second chiral
+
+92
+00:07:50,130 --> 00:07:54,370
+center يعني لاحظوا احنا اول مرة قولنا ماكنش لنا
+
+93
+00:07:54,370 --> 00:07:57,390
+chiral center نهائي و عملنا له generation، شو طلع
+
+94
+00:07:57,390 --> 00:08:04,840
+عندى؟ رسمic mixtureتاني تفاعل لما اعملت تفاعل بعيد
+
+95
+00:08:04,840 --> 00:08:08,320
+عن الكايرال سنتر شو صار عندى retention of
+
+96
+00:08:08,320 --> 00:08:13,880
+configuration طيب الآن لو كان في عندى كايرال سنتر
+
+97
+00:08:13,880 --> 00:08:19,160
+اول و بدى اعمل كايرال سنتر تاني شو بده يصير عندى؟
+
+98
+00:08:19,160 --> 00:08:25,120
+خلّينا نشوف مثال هذه مثال لو طلعنا على هذا المركب
+
+99
+00:08:25,120 --> 00:08:29,880
+الآن هذه الكاربون اللى موجودة هنا بتحمل مثل
+
+100
+00:08:29,880 --> 00:08:33,970
+وchloro Hو المجموعة اللي فيها double bond كايرال
+
+101
+00:08:33,970 --> 00:08:39,290
+سنتر ولا لأ كايرال سنتر انا مش موضوعي اطلاقا هذه
+
+102
+00:08:39,290 --> 00:08:42,770
+ال carbon بدي اعمل التفاعل على ال double bond يعني
+
+103
+00:08:42,770 --> 00:08:48,160
+على ال double bond بدي اجي اضيف hbr في وجودH plus
+
+104
+00:08:48,160 --> 00:08:53,940
+هذه أخدناها إضافة Markovnikov يعني بدأ أحط ال H
+
+105
+00:08:53,940 --> 00:09:00,080
+هنا في الأول أبدأ تفاعل بإضافة ال H هنا وبعدين
+
+106
+00:09:00,080 --> 00:09:06,260
+أكمل ال PR على هذا الموقع لاحظوا إيش اللي بدو يصير
+
+107
+00:09:06,260 --> 00:09:12,060
+عندي لما أضيف ال H على هذا الموقع كام رابط هيظل
+
+108
+00:09:12,060 --> 00:09:20,250
+على هذه النقطة تلت روابط تلت روابطحاولوا تستحضروا
+
+109
+00:09:20,250 --> 00:09:24,510
+الشكل مع الهيدروجين المحذوف مع الهيدروجين المحذوف
+
+110
+00:09:24,510 --> 00:09:30,210
+أعطيكم H هاي
+
+111
+00:09:30,210 --> 00:09:35,830
+الشكل الكامل واضح؟ لما أضيف هنا H هذا الكربون بدل
+
+112
+00:09:35,830 --> 00:09:41,630
+ما يكون CH2 ماذا سيحصل؟ CH3 سيحصل CH3 و ال double
+
+113
+00:09:41,630 --> 00:09:48,850
+bond هذه ستذهب علىأساس أنه هيجي يخجم عندي هنا PR
+
+114
+00:09:48,850 --> 00:09:53,270
+في الخطوة التالية الآن لاحظوا معي لو اتطلعنا على
+
+115
+00:09:53,270 --> 00:09:58,450
+هذا الجزء هذا الجزء يا ترى هل احنا بنشتغل قريب عنه
+
+116
+00:09:58,450 --> 00:10:04,430
+ولا بالنسبة له بنشتغل reaction away from a chiral
+
+117
+00:10:04,430 --> 00:10:08,290
+center away from a chiral center وعشانك بنحطه زي
+
+118
+00:10:08,290 --> 00:10:10,630
+ما هو لاحظوا إيش معناه retention of configuration
+
+119
+00:10:10,630 --> 00:10:14,750
+المثل اللي فوق ال CL على اليمين ال H على الشمالهذا
+
+120
+00:10:14,750 --> 00:10:19,010
+retention of configuration ولا لأ؟ الآن هذه النقطة
+
+121
+00:10:19,010 --> 00:10:27,690
+هي النقطة اللي هنا ال CH2 شو صارت؟ CH3 و هذه ما
+
+122
+00:10:27,690 --> 00:10:35,090
+زالت H و الآن أنا بانتظار ال PR لما نيجي نطلع
+
+123
+00:10:35,090 --> 00:10:38,130
+حوالين هذه ال carbon ايش الشكل؟
+
+124
+00:10:40,850 --> 00:10:46,950
+بناء على ذلك بنتوقع ان ال PR بإمكانها تهجم من
+
+125
+00:10:46,950 --> 00:10:51,010
+الجهتين زي ما أخذنا في أول مرة لما درسنا ال
+
+126
+00:10:51,010 --> 00:10:53,950
+generation of a chiral center بمعنى ال PR ممكن
+
+127
+00:10:53,950 --> 00:10:58,830
+تيجي من هنا و ال PR ممكن تيجي تهاجي من هنا إذا كام
+
+128
+00:10:58,830 --> 00:11:03,070
+ناتج بدو يطلع عندى هى ال PR إذا إجت من هذا الاتجاه
+
+129
+00:11:03,070 --> 00:11:09,380
+و هى ال PR إذا إجت من الاتجاه التالفزي لما درسنا
+
+130
+00:11:09,380 --> 00:11:12,600
+اول مرة الـ Chiral Center تقولنا عندنا بلانر
+
+131
+00:11:12,600 --> 00:11:18,100
+انترميديت تم التفاعل من ايه؟ من الجهتين الان هنا
+
+132
+00:11:18,100 --> 00:11:22,180
+في عند بلانر انترميديت اتكونت نتيجة انه ضفت اتش
+
+133
+00:11:22,180 --> 00:11:29,780
+لغية ال bubble bond التفاعل بإمكانه تم من الجهتينو
+
+134
+00:11:29,780 --> 00:11:35,340
+بناء على ذلك كام ناتج يطلع عنده؟ اتنين بيفرق عن
+
+135
+00:11:35,340 --> 00:11:40,880
+المثال الأول بشغل واحدة انه هل يترى الاحتمالات
+
+136
+00:11:40,880 --> 00:11:44,860
+متساوية ان هذا ييجي عن اليمين او عن الشمال في
+
+137
+00:11:44,860 --> 00:11:48,960
+generation of a first chiral center كنا نقول
+
+138
+00:11:48,960 --> 00:11:54,000
+الاحتمالات بتكون متساوية و بناء على ذلك يطلع عنده
+
+139
+00:11:55,740 --> 00:12:01,120
+الان بسبب وجود الكايرال سنتر الاول اللى بيخل
+
+140
+00:12:01,120 --> 00:12:06,400
+الفراغات حوالين هذا الكاربون غير متساوية مابيكونوش
+
+141
+00:12:06,400 --> 00:12:13,720
+الاحتمالين بنفس المقدار فبتم صحيح هجوم من الجهتين
+
+142
+00:12:13,720 --> 00:12:20,570
+ولكن ليسبنسب متساوية يعني مابيجيش 50% من التفاعل
+
+143
+00:12:20,570 --> 00:12:24,430
+من هنا و 50% من التفاعل من هنا ليش هذا الكلام
+
+144
+00:12:24,430 --> 00:12:30,240
+امتنع؟بسبب وجود ال chiral center اللي بيخلي جهة
+
+145
+00:12:30,240 --> 00:12:35,240
+أحيانا مغلقة أكتر من الجهة التانية بيصير فيه فرق
+
+146
+00:12:35,240 --> 00:12:40,180
+بالوسع زي إنسان كان عنده مسارين متساويين تماما
+
+147
+00:12:40,180 --> 00:12:44,520
+بيمكنه يمشي من هنا و من هنا الآن إجا شيء سكر جزء
+
+148
+00:12:44,520 --> 00:12:50,520
+من مسار معين بيضلوا يمشي بنفس النسبة ولا غالبا
+
+149
+00:12:50,520 --> 00:12:55,530
+بيروح على المسار الأكتر يعني ساعة و فراغواضح
+
+150
+00:12:55,530 --> 00:13:00,610
+الفكرة؟ الآن شو اللي خلّى عدم التساوي؟ الكايرال
+
+151
+00:13:00,610 --> 00:13:04,450
+سنتر الأول الكايرال سنتر الأول بيخلّى عدم تساوي
+
+152
+00:13:04,450 --> 00:13:08,890
+إذا لو أنا اتطلعت الآن على هدول الناتجين اللي
+
+153
+00:13:08,890 --> 00:13:13,610
+طلعوا بنسب متساوي ولا غير متساوية؟ غير متساوية غير
+
+154
+00:13:13,610 --> 00:13:17,690
+متساوية in unequal amounts وسألت يا تورا ما
+
+155
+00:13:17,690 --> 00:13:24,530
+العلاقة بين هدول المركبين اللي طلعوا عندهم؟لاحظوا
+
+156
+00:13:24,530 --> 00:13:30,570
+هذا الجزء و هذا الجزء ايش مالهم صورة بعض في المرأة
+
+157
+00:13:30,570 --> 00:13:36,450
+و متعاكسة طب و هذا و هذا نفس الشيء إذا المركب كله
+
+158
+00:13:36,450 --> 00:13:42,110
+صورة بعض و لا لأ إذا بدكم تعملوا باستعمال الرموز
+
+159
+00:13:42,110 --> 00:13:49,370
+بإمكانكم تعملوا R و S بمعنى نلغي هذه ال edge هعندي
+
+160
+00:13:49,370 --> 00:13:55,180
+واحد اتنين تلاتة هذه البيانة Rهذه S الانهان ما
+
+161
+00:13:55,180 --> 00:14:00,540
+اتغيرت ضلت زي ما هي هالكلور و بعدين كربون حملة
+
+162
+00:14:00,540 --> 00:14:06,460
+برون بعدين اذا هذه ايش S طيب لو اتيت و طلعت هنا
+
+163
+00:14:06,460 --> 00:14:09,900
+واحد
+
+164
+00:14:09,900 --> 00:14:14,640
+اتنين R
+
+165
+00:14:14,640 --> 00:14:21,860
+S هذه واحد اتنين R S
+
+166
+00:14:24,660 --> 00:14:31,600
+مكتوبها R رجعوهم بهدوء ال R شيء متعاكس وشيء متساوي
+
+167
+00:14:31,600 --> 00:14:37,740
+اذا هدوله ايش ديستريو مارس ف ال generation of a
+
+168
+00:14:37,740 --> 00:14:42,920
+second chiral center المحاصلة تبعته it results in
+
+169
+00:14:42,920 --> 00:14:46,560
+diastereomeric products at different rates بسرعة
+
+170
+00:14:46,560 --> 00:14:53,300
+مختلفة الأهم منها and inunequal amounts يعني لو
+
+171
+00:14:53,300 --> 00:14:56,520
+أنا باسألكوا سؤال صح و غلط generation of a second
+
+172
+00:14:56,520 --> 00:15:00,580
+chiral center results in the stereomeric mixture
+
+173
+00:15:00,580 --> 00:15:06,440
+or products in equal amounts and unequal amounts
+
+174
+00:15:06,590 --> 00:15:10,050
+طبعا ليش صار الـ unequal amount؟ because of the
+
+175
+00:15:10,050 --> 00:15:14,750
+presence of the first chiral center وجود ال chiral
+
+176
+00:15:14,750 --> 00:15:19,390
+center الأول خلّى احتمالات الهجوم من الجهتين غير
+
+177
+00:15:19,390 --> 00:15:22,770
+متساوي يعني الوسع اللي موجود من الجهة بختلف عن
+
+178
+00:15:22,770 --> 00:15:25,370
+الوسع اللي موجود من الجهة التانية الآن ذرة بدأت
+
+179
+00:15:25,370 --> 00:15:29,370
+تتفاعل التفاعل هو هجوم، ذرة ماشية و بدأت تيجي الآن
+
+180
+00:15:29,370 --> 00:15:31,850
+دايما اللي بدو يروح، يروح من المنطقة الواسعة ولا
+
+181
+00:15:31,850 --> 00:15:39,690
+الديقة؟ من المنطقة الواسعة، واضح؟هذا المحصلة
+
+182
+00:15:39,690 --> 00:15:44,370
+بالنسبة لعملية generation of a chiral center وزي
+
+183
+00:15:44,370 --> 00:15:48,650
+ما لاحظته ان هذا التفاعل بيدمج التفاعلين السابقين
+
+184
+00:15:48,650 --> 00:15:53,490
+يعني بالنسبة لهذا هو تفاعل بعيد عنه ولذلك هذا
+
+185
+00:15:53,490 --> 00:15:58,870
+الجزء ايش ماله؟ ضال في retention of configuration
+
+186
+00:15:58,870 --> 00:16:04,250
+وال generation of a chiral center تمهن ولكن بنسبة
+
+187
+00:16:04,250 --> 00:16:05,990
+غير متساوية
+
+188
+00:16:07,980 --> 00:16:11,920
+بهيك احنا بننتهي من chapter ال stereochemistry في
+
+189
+00:16:11,920 --> 00:16:15,120
+عندكم slide عن resolution of enantiomers اتكلمنا
+
+190
+00:16:15,120 --> 00:16:19,500
+عنها اللي هي فصل ال enantiomers لو حضرناهم كخليط
+
+191
+00:16:19,500 --> 00:16:24,060
+متساوي وقولنا ان هذه العملية بكل الأحوال مش عملية
+
+192
+00:16:24,060 --> 00:16:30,580
+سهلة يمكن ان تعمل بعدة طرق فنية في المختبرات لكن
+
+193
+00:16:30,580 --> 00:16:36,120
+بتاخد وقت ومش عملية سهلة والافضل من resolution of
+
+194
+00:16:36,120 --> 00:16:42,550
+enantiomersأما أن أخد المركب نقي من الطبيعة أو
+
+195
+00:16:42,550 --> 00:16:46,930
+الاحتمال التاني لو و لابد في المختبر ان اعمل
+
+196
+00:16:46,930 --> 00:16:51,710
+asymmetric synthesis انتبهوا معي لو بدأ اقول ايش
+
+197
+00:16:51,710 --> 00:16:58,110
+افضل اشي للوصول للمركبات النقية نمرة واحد من ال
+
+198
+00:16:58,110 --> 00:17:04,230
+nature الطبيعة بتعطينا مركبات نقية نمرة اتنين ان
+
+199
+00:17:04,230 --> 00:17:10,070
+اعملasymmetric synthesis يعني أعمل synthesis
+
+200
+00:17:10,070 --> 00:17:18,670
+يعطيني واحد أكتر من التاني نمرة تلاتة أن أعمل ال
+
+201
+00:17:18,670 --> 00:17:21,950
+synthesis اللي حكينا اللي بيطلعوا التنين متساويات
+
+202
+00:17:21,950 --> 00:17:26,890
+في اللي إيش اسمه symmetric synthesis لكن ال
+
+203
+00:17:26,890 --> 00:17:31,650
+symmetric synthesis إيش بدوا يتبعوه؟Symmetric
+
+204
+00:17:31,650 --> 00:17:36,050
+Synthesis هذا يجب ان يتبع Resolution لان افصلهم
+
+205
+00:17:36,050 --> 00:17:41,430
+بتجارب صعبة الانزيمات
+
+206
+00:17:41,430 --> 00:17:48,760
+في ال nature ال catalystsبمواصفات معينة عادة كيرال
+
+207
+00:17:48,760 --> 00:17:53,500
+كتاليست في الطريقة التانية يعني اللي بيساعد على ان
+
+208
+00:17:53,500 --> 00:17:57,920
+انا احصل على المركب النقي في ال nature اللي هو ال
+
+209
+00:17:57,920 --> 00:18:02,820
+enzymes الان اللي بيساعد على ان احصل على ال
+
+210
+00:18:02,820 --> 00:18:05,880
+asymmetric synthesis يعني يطلعوا مش بنسبة متساوية
+
+211
+00:18:05,880 --> 00:18:09,280
+واحد اكثر من التاني الى درجة اقترب من النقاوة
+
+212
+00:18:09,280 --> 00:18:14,360
+احيانا ان انا باستعملكتاليست والكتاليست بيكون
+
+213
+00:18:14,360 --> 00:18:21,260
+كايرة الكتاليست عادة واضح؟ الان هذه طرق وقاية ليش
+
+214
+00:18:21,260 --> 00:18:25,000
+بعملها؟ عشان ما اجعش انه طلع عندى خليطه اتغلب
+
+215
+00:18:25,000 --> 00:18:28,640
+بفاصله لو مامشيش بهذه الطريقة او بهذه الطريقة
+
+216
+00:18:28,640 --> 00:18:33,220
+اعملت symmetric synthesis خليط متساوي من الاتنين و
+
+217
+00:18:33,220 --> 00:18:37,980
+اجت بدأ اجع في مشكلة ايش؟فصل الخليط يعني الخليط
+
+218
+00:18:37,980 --> 00:18:42,560
+اللى عندى نفترض R و S بدأ ادخل على عملية الفصل شو
+
+219
+00:18:42,560 --> 00:18:47,640
+بنسميها الفصل resolution هذه يمكن أن تتم باكثر من
+
+220
+00:18:47,640 --> 00:18:52,720
+طريقة كيميائية لكن بكل الأوقات ما تفكروش أنها
+
+221
+00:18:52,720 --> 00:18:57,080
+طريقة سهلة طريقة صعبة يعني أحيانا انتوا بيكونوا
+
+222
+00:18:57,080 --> 00:19:02,860
+التخيل عندكمانه شغلة صعبة يعني بدي اخد مختبر بدل
+
+223
+00:19:02,860 --> 00:19:07,300
+ما يكون ساعتين يكون تلت ساعات وانتهي ان انا فصلت
+
+224
+00:19:07,300 --> 00:19:11,020
+المادة لأ لما انا بقول ال resolution of
+
+225
+00:19:11,020 --> 00:19:15,520
+enhancements عملية صعبة يعني واحد باحث بيشتغل وطلع
+
+226
+00:19:15,520 --> 00:19:20,340
+عنده mix chart و بده يبدأ يفصل فيه ممكن الأمور معه
+
+227
+00:19:20,340 --> 00:19:23,640
+اذا بدأ من نقطة الصفر وماعندهش اي فكرة على الموضوع
+
+228
+00:19:23,640 --> 00:19:28,770
+يبدأ تجارب تاخد سنةمش بحكي عن ساعتين و تلاتة و
+
+229
+00:19:28,770 --> 00:19:34,410
+أربعة لأ بحكي عن سنة و أكتر كمان من سنة ليست عملية
+
+230
+00:19:34,410 --> 00:19:50,430
+سهلة في الوضع الطبيعي ابهيك
+
+231
+00:19:50,430 --> 00:19:54,930
+بنكون طبعا خلصنا هذا ال chapter اللي اسمه
+
+232
+00:19:58,800 --> 00:20:04,620
+استيريو كيميستري وبننتقل
+
+233
+00:20:04,620 --> 00:20:11,960
+مباشرة الى فصل اخر هذا الفصل الاخر بدنا ناخده نوعا
+
+234
+00:20:11,960 --> 00:20:19,910
+ما باختصار .. نوعا ما باختصار عنوانه الكلهيلايزو
+
+235
+00:20:19,910 --> 00:20:24,950
+طبعا ال الكلهليتز المجموعة هذه من المركبات لها
+
+236
+00:20:24,950 --> 00:20:30,870
+تفاعلين substitution and elimination تفاعل الإبدال
+
+237
+00:20:30,870 --> 00:20:37,980
+وتفاعل الحدث بالنسبة ل الكلاعرفنا إيش يعني الكل؟
+
+238
+00:20:37,980 --> 00:20:44,860
+مجموعة الكل مثل و إثل و بربل و كل شيء مأخوذ من ال
+
+239
+00:20:44,860 --> 00:20:50,260
+الكلس سواء له اسم و لا مالوش اسم و الهيليدز متصل
+
+240
+00:20:50,260 --> 00:20:57,300
+بهالوجين كلور بروم يود فلور أحيانا فال الكلهيليدز
+
+241
+00:20:57,300 --> 00:21:03,750
+ببساطة هم ال الكلس المتصلين بهالوجينيعني لو اجينا
+
+242
+00:21:03,750 --> 00:21:08,130
+و قولنا هذا المركب يا تورا و كتبنا هنا PR عبارة عن
+
+243
+00:21:08,130 --> 00:21:14,170
+إيش الكل هيلايد لأن هذا الجزء الكن و هذا الجزء
+
+244
+00:21:14,170 --> 00:21:18,250
+الهالوجين و عشان ذلك مرات بيسموها أي معنى الكل
+
+245
+00:21:18,250 --> 00:21:22,030
+هيلايد في جزء الكن و جزء الهالوجين عشان ذلك مرات
+
+246
+00:21:22,030 --> 00:21:28,870
+بيسموهم الهالوجينو الكنز الكل هيلايد او الهالوجينو
+
+247
+00:21:28,870 --> 00:21:32,490
+الكنز نفس الفكرة تماما
+
+248
+00:21:38,950 --> 00:21:43,570
+الان زي ما حكيت ال الكلهيلايتز بيسموهم مرات
+
+249
+00:21:43,570 --> 00:21:48,410
+الهالوجينوالكينز او هالوالكينز فسواء قرأنا العنوان
+
+250
+00:21:48,410 --> 00:21:53,170
+الكلهيلايتز او هالوجينوالكينز او هالوالكينز هو ال
+
+251
+00:21:53,170 --> 00:21:58,300
+cane حاملالهالوجين البساطة مش مشكلة كبيرة فال
+
+252
+00:21:58,300 --> 00:22:02,040
+الهالوجين محتوى الهالوجين اتوم و الهالوجين اتوم
+
+253
+00:22:02,040 --> 00:22:06,020
+معروفين بالنسبة لنا فلورين و كلورين و برومين و
+
+254
+00:22:06,020 --> 00:22:08,620
+ايودين متصلين ب الهالوجروم
+
+255
+00:22:11,830 --> 00:22:16,410
+الالكالهيلايتز ممكن ان نصنفهم احنا الى primary و
+
+256
+00:22:16,410 --> 00:22:19,890
+secondary و tertiary الكلهيلايتز هذا المصطلح
+
+257
+00:22:19,890 --> 00:22:23,770
+بيفيدنا اثناء ما بنشرح عن الموضوع ايش بنقصد احنا
+
+258
+00:22:23,770 --> 00:22:27,490
+بال primary و ال secondary و ال tertiary او باللغة
+
+259
+00:22:27,490 --> 00:22:32,170
+العربية اولي و ثانوي و ثالثي ال primary و ال
+
+260
+00:22:32,170 --> 00:22:35,790
+secondary و ال tertiary الكلهيلايتز باجي انا على
+
+261
+00:22:35,790 --> 00:22:39,430
+ذرة الكربون اللى حاملة ال halogen يعني هذا الكربون
+
+262
+00:22:39,430 --> 00:22:45,830
+اللى حاملة ال halogenمتصلة بكم كاربون؟ اذا متصلة
+
+263
+00:22:45,830 --> 00:22:50,610
+بكاربون واحدة بقول عنها primary لحظة ايه الكاربون
+
+264
+00:22:50,610 --> 00:22:54,950
+اللي حاملة الهالوجين متصلة بكم كاربون واحدة اذا
+
+265
+00:22:54,950 --> 00:22:58,170
+بقول عنها primary طبعا الناس الشاطرين بيصيروا
+
+266
+00:22:58,170 --> 00:23:02,530
+يفهموها يعني بشكل سهل بيقولوا لو الكاربون اللي
+
+267
+00:23:02,530 --> 00:23:08,540
+حاملة الهالوجين كانت CH2لاحظوا CH2 و ال PR هي تلات
+
+268
+00:23:08,540 --> 00:23:13,000
+روابط إذا كده يظل متصلة مع واحدة هذا ال primary
+
+269
+00:23:13,000 --> 00:23:19,140
+فاللي بيميز ال primary وجود ال CH2 هالوجينالان ال
+
+270
+00:23:19,140 --> 00:23:24,540
+secondary الكربون اللى حامله ال halogen هى هى هذه
+
+271
+00:23:24,540 --> 00:23:27,380
+الكربون اللى حامله ال halogen متصلة بكم كربون؟
+
+272
+00:23:27,380 --> 00:23:31,000
+تنتين تنتين بقول عنها ال secondary الان ايش بيكون
+
+273
+00:23:31,000 --> 00:23:36,600
+موجود فيها؟ CH يعني كأنه ال primary CH2 halogen ال
+
+274
+00:23:36,600 --> 00:23:43,960
+secondary CH halogen لو اجيت على ال tertiaryC
+
+275
+00:23:43,960 --> 00:23:49,220
+متصلة بالهالوجين طب و التلاتة روابط التانية متصلين
+
+276
+00:23:49,220 --> 00:23:54,600
+بالكاربون هاي C متصلة بالهالوجين و بعد هيك رابطة
+
+277
+00:23:54,600 --> 00:23:58,120
+تنتين تلاتة متصلة بالكاربون هذا النوع من ال
+
+278
+00:23:58,120 --> 00:24:02,340
+الكلهيلايتش شو بسمي انا tertiary alkyl halides
+
+279
+00:24:02,340 --> 00:24:06,040
+فإذا قلنا او رسمنا اي الكلهيلايت و قلنا عنه
+
+280
+00:24:06,040 --> 00:24:09,400
+primary او secondary او tertiary بفترض ان هذه
+
+281
+00:24:09,400 --> 00:24:17,540
+الشغلة تكون واضحةعشان نفهم الـ Alkyl Halides محور
+
+282
+00:24:17,540 --> 00:24:22,220
+الـ Alkyl Halides هو رابطة الـ Carbon-Halogen يعني
+
+283
+00:24:22,220 --> 00:24:27,180
+بين الـ Carbon والـ X الـ Halogen في عنده رابطة
+
+284
+00:24:28,310 --> 00:24:32,150
+الان بدي افهم هذه الرابطة جيدا لان التفاعلات
+
+285
+00:24:32,150 --> 00:24:37,330
+هيعتمد على هذه الرابطة ال carbon halogen bond جزء
+
+286
+00:24:37,330 --> 00:24:41,990
+من فهم هذا الموضوع ان اشوف فرق السالبية هنا هل
+
+287
+00:24:41,990 --> 00:24:47,310
+يترى هذه الرابطة polar ولا non polar عشان اشوف
+
+288
+00:24:47,310 --> 00:24:53,550
+الرابطة جيدا بدي اشوف ايش السالبية للكربون الكربون
+
+289
+00:24:53,550 --> 00:24:58,350
+سالبيته اتنين ونصال carbon ايش السالبية تبعته
+
+290
+00:24:58,350 --> 00:25:05,330
+اتنين و نص الان ال halogens كم واحد اه لاحظوا
+
+291
+00:25:05,330 --> 00:25:16,670
+floor سالبيته قداش اربعة و بروم تلاتة floor
+
+292
+00:25:16,670 --> 00:25:19,750
+تلاتة
+
+293
+00:25:19,750 --> 00:25:21,590
+بروم
+
+294
+00:25:23,000 --> 00:25:29,680
+2.8 و اليود 2.5 لاحظوا اليود و الكربون فيهم فرق
+
+295
+00:25:29,680 --> 00:25:34,620
+سالبية إذا الرابطة بشكل عام non polar مافيش فرق
+
+296
+00:25:34,620 --> 00:25:40,320
+سالبية الكربون 2.5 و اليود 2.5 لكن بعد ذلك مع
+
+297
+00:25:40,320 --> 00:25:45,140
+البروم و الكلور و الفلور في فرق سالبية لمصلحة
+
+298
+00:25:45,140 --> 00:25:50,080
+الهالوجين إذا بشكل عام مع هذول الذرات كيف بنتوقع
+
+299
+00:25:50,080 --> 00:25:57,150
+ال polarity للرابطة تكونإن الكربون تكون موجبة
+
+300
+00:25:57,150 --> 00:26:05,090
+والهالوجين سالبة واضح؟ أكبر فرق وين موجود؟ مع ال
+
+301
+00:26:05,090 --> 00:26:11,910
+floor أقل فرق العدم مع اليود الأن لاحظوا معي كل ما
+
+302
+00:26:11,910 --> 00:26:16,390
+كان الفرق كبير كل ما جربت الرابط تشبه الرابط
+
+303
+00:26:16,390 --> 00:26:20,890
+الأيونية بمعنى أخر بتصير أقوىو بناء على ذلك لو انا
+
+304
+00:26:20,890 --> 00:26:25,270
+بدى اشوف قوة هذه الروابط اللى هى مع ال flour و ال
+
+305
+00:26:25,270 --> 00:26:29,330
+brom و ال chlor و ال iod هلاحظ انه و اقارنها بقوة
+
+306
+00:26:29,330 --> 00:26:32,750
+رابطة ال carbon-H اللى هى تعتبر بلغة الكيميا رابطة
+
+307
+00:26:32,750 --> 00:26:38,930
+قوية و مش سائل تنقصت ال carbon-H 413 كيلوجول لكل
+
+308
+00:26:38,930 --> 00:26:42,910
+مول بدى عشان اكسر هذه الرابطة الان ال carbon-flour
+
+309
+00:26:42,910 --> 00:26:48,150
+اقوى منهاليش؟ لأن فرق ال polarity عالي صارت تشبه
+
+310
+00:26:48,150 --> 00:26:52,990
+رابطة ايونية قوية ال carboniclor 346 ال
+
+311
+00:26:52,990 --> 00:26:59,910
+carboniclor 290 ال carboniclor 228 أقوى واحدة فيهم
+
+312
+00:26:59,910 --> 00:27:06,670
+مين؟ مع ال fluor الآن جزء أساسي في بناء الكيميا
+
+313
+00:27:06,670 --> 00:27:09,850
+تبع ال alkyl halides ان انا بدي أكسر الرابطة هذه
+
+314
+00:27:09,850 --> 00:27:15,000
+اللي بين ال carbon و ال halogenيعني سواء في تفاعل
+
+315
+00:27:15,000 --> 00:27:20,020
+الإبدال أو الحذف، هذه الرابطة بدها تنكسر طيب ال
+
+316
+00:27:20,020 --> 00:27:23,480
+floor رابطته قوية؟ صعب، صعب، صعب، صعب، صعب، صعب،
+
+317
+00:27:23,480 --> 00:27:24,200
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+318
+00:27:24,200 --> 00:27:24,620
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+319
+00:27:24,620 --> 00:27:24,820
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+320
+00:27:24,820 --> 00:27:33,340
+صعب، صعب، صعب، صعب، صعب، صعب،
+
+321
+00:27:33,340 --> 00:27:41,060
+صعب، صعب، صعب،
+
+322
+00:27:41,060 --> 00:27:45,880
+صوبناء على ذلك عندما أعمل إبدال و أخد أمثلة على
+
+323
+00:27:45,880 --> 00:27:50,360
+الإبدال و أعمل حذف و في التفاعلين الإبدال و الحذف
+
+324
+00:27:50,360 --> 00:27:56,800
+تكسر فيه رابطة الأمثلة اللي هشوفها كلور بروم يود
+
+325
+00:27:56,800 --> 00:28:01,880
+مش هشوف أمثلة على ال floor لأن ال floor رابطة قوية
+
+326
+00:28:01,880 --> 00:28:06,380
+صعب كسرها وبناء على ذلك تفاعلات الإبدال و الحذف
+
+327
+00:28:06,380 --> 00:28:11,010
+مرتبطة بدول التلاتة ال floor برا الموضوعواضح
+
+328
+00:28:11,010 --> 00:28:17,150
+الفكرة؟ الآن
+
+329
+00:28:17,150 --> 00:28:22,890
+طالما احنا بنقول بدنا نكسر الرابط مع ال halogen
+
+330
+00:28:22,890 --> 00:28:28,230
+أني أضعف رابط فيهم اليود بناء على ذلك لو انا بعمل
+
+331
+00:28:28,230 --> 00:28:33,530
+تفاعل مع اليود بيكون سهل ولا صعب؟ سهل جداالبروم
+
+332
+00:28:33,530 --> 00:28:37,350
+بقعده في السهولة الكلور بقعده وعشان هيك لو انا بدى
+
+333
+00:28:37,350 --> 00:28:40,990
+اشوف ال rate of reaction لو كنت بفعل يود وبروم
+
+334
+00:28:40,990 --> 00:28:46,270
+وكلور مقارنة بعض و بالبعض أسرع تفاعل مع اليود أسرع
+
+335
+00:28:46,270 --> 00:28:51,580
+من البروم أسرع من الكلورلكلور والسبب قوة الرابطة
+
+336
+00:28:51,580 --> 00:28:56,100
+لأن هنا في رابطة ضعيفة بتنكسر بسهولة واضح الرابطة
+
+337
+00:28:56,100 --> 00:29:00,340
+مع اليود رابطة ضعيفة بتنكسر بسهولة يمكن هذا الكلام
+
+338
+00:29:00,340 --> 00:29:04,100
+حتى في الحياة العملية بتلاحظوا حتى في الحياة
+
+339
+00:29:04,100 --> 00:29:09,320
+العملية بتلاحظوا كثير من الأدوية مثلا موجود مكون
+
+340
+00:29:09,320 --> 00:29:15,660
+أساسي منها اليود هذه الأدوية لو اتعرضت لشوية حرارة
+
+341
+00:29:15,660 --> 00:29:20,980
+بسيطة أو لضوء الشمسبتنكسر الرابطة اللي معاليه طبعا
+
+342
+00:29:20,980 --> 00:29:24,240
+كنا انكسرت الرابطة إذا الدواء كله إيش صار فيه؟ خير
+
+343
+00:29:24,240 --> 00:29:28,680
+وعشان هيك هنلاحظ أن هذا النوع من الأدوية بيحطوه في
+
+344
+00:29:28,680 --> 00:29:33,800
+جزايز غامقة لونها بني وغالبا بيحفظوه بعيدا عن
+
+345
+00:29:33,800 --> 00:29:38,930
+الضوء و الحرارة و أحيانا في حرارة باردةيعني شوف
+
+346
+00:29:38,930 --> 00:29:43,690
+كيف لما مراتب تقرأ على شيء معين يحفظ بعيدا عن
+
+347
+00:29:43,690 --> 00:29:46,730
+الضوء و الحرارة ليش؟ بيكون هذا الشيء المعين فيه
+
+348
+00:29:46,730 --> 00:29:52,790
+روابط ضعيفة حتى حرارة الجو حتى على ضو الشمس ممكن
+
+349
+00:29:52,790 --> 00:29:58,410
+تتكسر فبنصير نحط مثلا جزاز بن يمنع أنه يدخل الضوء
+
+350
+00:29:58,410 --> 00:30:02,030
+بشكل كبير بنقبل حطه بعيد عن الضوء و عن الحرارة
+
+351
+00:30:02,030 --> 00:30:06,870
+ممكن يحتفظ فيهبالتلاجة على سبيل المثال كل هذا
+
+352
+00:30:06,870 --> 00:30:12,670
+نتيجة فهم قوة الروابط الكيميائية و دائما انتوا
+
+353
+00:30:12,670 --> 00:30:16,630
+يعني جزء منكوا في علوم الصحة و جزء في غيرها لحتى
+
+354
+00:30:16,630 --> 00:30:20,190
+تتعاملوا مع أدوى او اشياء اول ما بدكوا تمسكوا اي
+
+355
+00:30:20,190 --> 00:30:28,090
+عبو الدواء شغلتين الشيء الاول صحتكماقرأوا الكلام
+
+356
+00:30:28,090 --> 00:30:33,550
+اللي عليها، ضار، سام، يجوز أن نشمه، لا يجوز، كل
+
+357
+00:30:33,550 --> 00:30:38,050
+هذا الكلام مكتوب على العبوة ويله إشارات معينة،
+
+358
+00:30:38,050 --> 00:30:42,230
+بيحرق كوروسف مثلا زي أحماض إذا انكبت على الإيد
+
+359
+00:30:42,230 --> 00:30:46,200
+بتحرقها، إذا انكبت على الملابس بتحرقهامنفعش
+
+360
+00:30:46,200 --> 00:30:49,400
+الإنسان يتعامل مع أشياء و هو مش عارفها يكون
+
+361
+00:30:49,400 --> 00:30:55,240
+بيتعامل مع سم و بيسيبه ينكب على إيده و مابيغسلش و
+
+362
+00:30:55,240 --> 00:31:00,040
+مابياخدش احتياطات ولا بيلبس gloves ولا أي شيء و
+
+363
+00:31:00,040 --> 00:31:06,940
+شغلت تانية بيكون مكتوب عندكم كلمة storeاحفظه وانت
+
+364
+00:31:06,940 --> 00:31:12,160
+احفظه طبعا شغل اضافية بيكون عندكوا expire date انه
+
+365
+00:31:12,160 --> 00:31:16,120
+هذا بعد فترة معينة ما تفتحوه بيخرب بالذات كتير
+
+366
+00:31:16,120 --> 00:31:20,800
+مركبات بيكون مسكر عليها بشكل محكم لكن لما تفتحوها
+
+367
+00:31:20,800 --> 00:31:26,970
+تتفعل مع oxygen الهواءممكن تتفاعل مع الهوى نفسه أو
+
+368
+00:31:26,970 --> 00:31:31,370
+تمتص رطوبة من الهوى وبناء على ذلك تخرب فهتلاحظوا
+
+369
+00:31:31,370 --> 00:31:35,990
+بعض المراكبات مكتوب عليها لا يستعمل بعد أسبوع أو
+
+370
+00:31:35,990 --> 00:31:41,050
+أسبوعين من فتح العبوة كل إنسان بدي يتعامل بأدوية
+
+371
+00:31:41,050 --> 00:31:45,050
+أو pre agents بدي يكون منتبه لهذه الأمور وإلا
+
+372
+00:31:45,050 --> 00:31:47,470
+بيجعل بإيش؟ بالغلط
+
+373
+00:31:51,720 --> 00:31:57,640
+الان لو اجينا على التفاعلات تبعت ال alkyl halides
+
+374
+00:31:57,640 --> 00:32:04,320
+ممكن البعض يقول طب احنا ما أعطيناش التسمية مشعلة
+
+375
+00:32:04,320 --> 00:32:09,760
+جديدة مرت عليكم لما أخدنا ال alkenes يعني لو انا
+
+376
+00:32:09,760 --> 00:32:15,600
+جبتلكوا هذا المركب هذا
+
+377
+00:32:15,600 --> 00:32:22,830
+ال alkyl halide مين تسميه؟احد اتنين تلاتة اربعة
+
+378
+00:32:22,830 --> 00:32:30,340
+خمسة بنتين اثنان كلورو اثنان مثل بنتينأخدنا
+
+379
+00:32:30,340 --> 00:32:36,180
+التسمية ولا لأ؟ أخدنا التسمية طيب واحدة بتقول ماشي
+
+380
+00:32:36,180 --> 00:32:40,800
+التسمية أخدناها طيب و ال preparation التحضير هو
+
+381
+00:32:40,800 --> 00:32:45,220
+احنا عادة لما بندرس عائلة كيميائية اول اشي بنتعرف
+
+382
+00:32:45,220 --> 00:32:49,420
+على العائلة بعدين بناخد ال nomenclature التسمية
+
+383
+00:32:49,420 --> 00:32:54,500
+بعدين التحضير بعدين التفاعلات احنا عمال جاعدين
+
+384
+00:32:54,500 --> 00:33:00,060
+بنفض جزءالتسمية وشوفنا أننا أخدناها طب و جزء
+
+385
+00:33:00,060 --> 00:33:04,800
+التحضير أخدناها
+
+386
+00:33:04,800 --> 00:33:09,420
+من أكثر من طريقة أخدناها بأكثر من طريقة لما كنا
+
+387
+00:33:09,420 --> 00:33:13,220
+نيجي نقولكم مثلا ابرو بيل و اعملوله chlorination
+
+388
+00:33:13,220 --> 00:33:20,960
+شو كنتوا تطلعوا؟One Chloro, Two Chloro مش هذي
+
+389
+00:33:20,960 --> 00:33:25,680
+Alkyl Halides إذا ال Direct Halogenation طريقة من
+
+390
+00:33:25,680 --> 00:33:30,500
+طرق التحضير ولا لأ و حلينا عليها أمثلة تأكيد ..
+
+391
+00:33:30,500 --> 00:33:36,120
+تأكيد لما كنا .. هاي أول طريقة ال Halogenation طب
+
+392
+00:33:36,120 --> 00:33:42,440
+لو أعطيناكوا هذا المركب و قولنا لكم ضيفوا عليه HBR
+
+393
+00:33:46,050 --> 00:33:50,770
+هتقولولي مع Markovnikov ولا أنت Markovnikov؟ إذا
+
+394
+00:33:50,770 --> 00:33:55,510
+Markovnikov بيجي H و PR to Bromo وإذا أنت
+
+395
+00:33:55,510 --> 00:34:01,390
+Markovnikov H و PR و لا Bromo هذه المركبات مش ال
+
+396
+00:34:01,390 --> 00:34:06,230
+الهيليتز اللي نتجت الطريقة إذا أخدناها فإيش طروب
+
+397
+00:34:06,230 --> 00:34:12,210
+تحضير ال الهيليتز؟ نمرة واحد ال halogenation of
+
+398
+00:34:12,210 --> 00:34:20,960
+alkenesالـ Halogenation طب نمره اتنين ال addition
+
+399
+00:34:20,960 --> 00:34:29,660
+of HX to الكيين أو الكايين كمان لما كنا نضيف على
+
+400
+00:34:29,660 --> 00:34:37,360
+الكاين مرتين واضح؟ في طرق تالتة أخدناها في طريق
+
+401
+00:34:37,360 --> 00:34:42,920
+تالت لو هنا إجينا ضفنا على نفس هذا المركب PR2
+
+402
+00:34:46,320 --> 00:34:50,940
+أيش كان يعطيني؟ كان يعمل لي إضافة two PR atoms
+
+403
+00:34:50,940 --> 00:34:56,800
+بسين ولا ب Anti-addition؟ Anti-addition هيعمل لي
+
+404
+00:34:56,800 --> 00:35:03,020
+dihalo compound هذه طريقة الإبوكسايد رينج لو
+
+405
+00:35:03,020 --> 00:35:07,020
+فتحناها برضه بتصير طريقة إذا إحنا أخدنا الحقيقة
+
+406
+00:35:07,020 --> 00:35:14,730
+أكثر من طريقة لتحضيرالـ Halo Compounds في طريقة
+
+407
+00:35:14,730 --> 00:35:17,890
+إضافية
+
+408
+00:35:17,890 --> 00:35:23,610
+غير التلات طرق هدول اللي هم ال ال ال ال ال ال ال
+
+409
+00:35:23,610 --> 00:35:24,970
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+410
+00:35:24,970 --> 00:35:25,010
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+411
+00:35:25,010 --> 00:35:28,170
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+412
+00:35:28,170 --> 00:35:28,990
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+413
+00:35:28,990 --> 00:35:29,570
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+414
+00:35:29,570 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+415
+00:35:29,610 --> 00:35:33,550
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+416
+00:35:39,410 --> 00:35:46,970
+بتفاعلها ما عدش X أخليها RX يعني تحويل الكحول إلى
+
+417
+00:35:46,970 --> 00:35:51,810
+الكلهلايت هذه الطريقة لها تفاصيل كتير لما ندرس
+
+418
+00:35:51,810 --> 00:35:55,630
+chapter الكحولات بندرس كتفاعل على الكحول يعني
+
+419
+00:35:55,630 --> 00:36:00,290
+بإمكاننا ندرسها الأن كطريقة للتحضير و بإمكاننا
+
+420
+00:36:00,290 --> 00:36:05,900
+ندرسها في chapter الكحولات كتفاعل على الكحولواضح؟
+
+421
+00:36:05,900 --> 00:36:10,640
+هذا كحول، هذا الكلهلايت، بالنسبة للكحول هي تفاعل،
+
+422
+00:36:10,640 --> 00:36:14,980
+بالنسبة لالكلهلايت هي طريقة تحضير، لما ندرس
+
+423
+00:36:14,980 --> 00:36:19,720
+الكحولات و تفاعلاتها، هيكون عندنا تفاعل أساسي
+
+424
+00:36:19,720 --> 00:36:27,560
+تحويلالكحول إلى ال alkyl halides بمجموعة من
+
+425
+00:36:27,560 --> 00:36:31,440
+التفاصيل بندرسها بوقته، هاي بتصير كمان طريقة
+
+426
+00:36:31,440 --> 00:36:39,390
+إضافية لتحضير ال alkyl halidesكام طريقة؟ اربعة مين
+
+427
+00:36:39,390 --> 00:36:44,790
+تقول اليوم باختصار اتفضلي ال direct halogenation
+
+428
+00:36:44,790 --> 00:36:48,330
+في وجود الضوء او الحرارة لل ال alkenes اضافة ال X2
+
+429
+00:36:48,330 --> 00:36:56,190
+لل ال alkenes او اضافة ال HX
+
+430
+00:36:56,190 --> 00:37:01,620
+لل ال alkenes او لل ال alkynesو بعدين من الكحولات
+
+431
+00:37:01,620 --> 00:37:05,900
+في وجود HX او reagents تانية بندرسها في chapter
+
+432
+00:37:05,900 --> 00:37:10,860
+الكحولات هيصيرنا ذاكرينكوا كم طريقة اربع طرق
+
+433
+00:37:10,860 --> 00:37:15,380
+لتحضير ال alkyl halides تلاتة أخدتهم و طريقة
+
+434
+00:37:15,380 --> 00:37:24,180
+بندرسها في chapter الكحولات الآن التفاعل الأساسي
+
+435
+00:37:24,180 --> 00:37:30,380
+لل alkyl halides هو تفاعلالإبدال التفاعل الأساسي
+
+436
+00:37:30,380 --> 00:37:34,860
+لـ alkalites هو تفاعل الإبدال لو أنا أتي أتطلع طيب
+
+437
+00:37:34,860 --> 00:37:38,920
+إيش اللي بده أبدله؟ وكيف بده يتم الإبدال اللي
+
+438
+00:37:38,920 --> 00:37:44,480
+عندي؟ اتطلعوا هاي عندي carbon حاملة نفترض PR وهنا
+
+439
+00:37:44,480 --> 00:37:49,400
+في تلت روابط، بلاش نركز عليهم شو هما الآن إيش
+
+440
+00:37:49,400 --> 00:37:55,520
+اتفقنا على الرابط اللي موجود هنا؟قول لعنها بولا
+
+441
+00:37:55,520 --> 00:38:02,180
+يعني هذه موجبة وهذه سالبة بناء على ذلك هلاحظ أن
+
+442
+00:38:02,180 --> 00:38:06,720
+التفاعل الأساسي عندنا لما بناجي المرة الجاية اللي
+
+443
+00:38:06,720 --> 00:38:10,500
+اتكلم أنه بيجي نيوكليوفايل لإن نيوكليوفايل حامل
+
+444
+00:38:10,500 --> 00:38:15,840
+إلكترونات وين بيهاجم؟ على الكاربون الموجب يعني هذا
+
+445
+00:38:15,840 --> 00:38:22,560
+سالب للنيوكليوفايل سالب بيجي إيش بيطلعك باله؟ سالب
+
+446
+00:38:23,370 --> 00:38:27,830
+السالب هاجم على الكربون الموجب، طرد سالب إجا سالب،
+
+447
+00:38:27,830 --> 00:38:33,550
+طرد سالب، إجا موجب، طرد موجب أخدنا في البنزين
+
+448
+00:38:33,550 --> 00:38:38,190
+الإبدال إيش كان؟ موجب مكان موجب، سميناها
+
+449
+00:38:38,190 --> 00:38:41,950
+Electrophilic Substitution الآن هنا بدو ييجي سالب
+
+450
+00:38:41,950 --> 00:38:47,030
+مكان سالب، يعني إيش اللي بدو يطرد؟ ال X مع
+
+451
+00:38:47,030 --> 00:38:52,340
+إلكتروناته، شو اللي بدو يهاجم؟لنيوكليوفايل و بناء
+
+452
+00:38:52,340 --> 00:38:56,880
+على ذلك بيصير المفروض فينا نتذكر ايش معنى
+
+453
+00:38:56,880 --> 00:39:01,040
+النيوكليوفايل اللي بدو يهاجم هنا و يحل محل ال X
+
+454
+00:39:01,040 --> 00:39:06,220
+ولذلك المرة القادمة هنبدأ من كلمة ايش الـ
+
+455
+00:39:06,220 --> 00:39:11,190
+Eucleophilic Substitution يعني نبدأ نتعرف علىللـ
+
+456
+00:39:11,190 --> 00:39:14,950
+nucleophile اللي بده يهاجم ويبدأ التفاعل لأن الـ
+
+457
+00:39:14,950 --> 00:39:18,790
+nucleophile هو السالب اللي بده يهاجم ويحل محل
+
+458
+00:39:18,790 --> 00:39:23,630
+الهالوجين السالبة يعمل عملية الإبدال شكرا
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..cb98d7dd3a4f4664700923d83aa364c8f947a29e
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_postprocess.srt
@@ -0,0 +1,1876 @@
+1
+00:00:19,780 --> 00:00:23,920
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا على
+
+2
+00:00:23,920 --> 00:00:28,440
+أكسدة الكحولات عرفنا ايش اللي بنقصده في الأكسدة
+
+3
+00:00:28,440 --> 00:00:34,660
+تحويل ال OH إلى C double bond O من خلال فقط ذاتين
+
+4
+00:00:34,660 --> 00:00:40,740
+هيدروجين ولذلك احنا قلنا ان ال primary alcohol
+
+5
+00:00:40,740 --> 00:00:46,000
+بتأكسد و بصير ال aldehydes و ال secondary alcohol
+
+6
+00:00:46,000 --> 00:00:51,060
+بتأكسد و بصير ال ketonesالـ tertiary alcohols مش
+
+7
+00:00:51,060 --> 00:00:55,540
+عندهم إمكانية انهم يتأكسدوا ربما ضالت شغلة صغيرة
+
+8
+00:00:55,540 --> 00:00:59,580
+ان نحكي شو هو العامل المؤكسد اللي احنا بنستعمله
+
+9
+00:00:59,580 --> 00:01:06,160
+عادة لأكسدة ال primary alcohols بحيث تقف الأكسدة
+
+10
+00:01:06,160 --> 00:01:12,340
+عند ال aldehyde بنستعمل reagent بنعطيه رمز BCC
+
+11
+00:01:12,340 --> 00:01:17,380
+بريدينيام كلورو كروميت البريدينيام كلورو كروميت
+
+12
+00:01:18,050 --> 00:01:22,050
+بيحذف هيدروجينتين بيحوّل ال primary alcohol إلى
+
+13
+00:01:22,050 --> 00:01:27,230
+الديهيد يعني لاحظوا هاي إيثانون primary alcohol
+
+14
+00:01:27,230 --> 00:01:30,950
+هيفقد الهيدروجينتين هنا بدها دي تصير double bond
+
+15
+00:01:30,950 --> 00:01:34,670
+صار الديهيد إذا لو قلنا شو العامل المؤكسد اللي
+
+16
+00:01:34,670 --> 00:01:40,180
+استعملناه هناBCC باكسد ال primary alcohol ال
+
+17
+00:01:40,180 --> 00:01:46,340
+الديهايد الان ربما احنا نوحنا المرة الماضية ان ال
+
+18
+00:01:46,340 --> 00:01:51,420
+الديهايد ممكن يصير عليه اكسدة إضافية بإضافة
+
+19
+00:01:51,690 --> 00:01:55,830
+أكسوجينة بدل الهيدروجين يعني عملية إبدال يعني هذا
+
+20
+00:01:55,830 --> 00:02:00,330
+ال الديهايد بعد ما يتكون لو استعملتله عامل مؤكسد
+
+21
+00:02:00,330 --> 00:02:07,170
+أقوى ممكن أن أحوله أخليه بدل ما هو CH3COOH يعني
+
+22
+00:02:07,170 --> 00:02:11,070
+متصل مرتين بالأكسوجين أبدل ال H و أخليه H يعني
+
+23
+00:02:11,070 --> 00:02:17,090
+أخليه إيش يصير Carboxylic Acid يصفةسي أتش ثري سي
+
+24
+00:02:17,090 --> 00:02:21,750
+دبل بوند او الان عملية الأكسدة الإضافية تحويل هذه
+
+25
+00:02:21,750 --> 00:02:31,690
+ال H إلى OH واضح فال primary alcohol بالأكسدة
+
+26
+00:02:31,690 --> 00:02:35,030
+خلّينا نقول الضعيفة بيصير الديهايد و بيجف عند ال
+
+27
+00:02:35,030 --> 00:02:35,890
+الديهايد
+
+28
+00:02:39,060 --> 00:02:44,500
+اذا احنا كملنا بعد هيك في موضوع ال .. الاكسدة اذا
+
+29
+00:02:44,500 --> 00:02:49,040
+احنا كملنا بعد هيك في موضوع الاكسدة بحيث استعملنا
+
+30
+00:02:49,040 --> 00:02:52,500
+عامل مؤكسد اقوى و عادة العامل المؤكسد الاقوى هو
+
+31
+00:02:52,500 --> 00:02:57,260
+احد العوامل المؤكسدة اللي موجودة عندكم هنا كمان او
+
+32
+00:02:57,260 --> 00:03:01,440
+فور بيرمانجانات البوتاسيوم
+
+33
+00:03:02,970 --> 00:03:10,210
+بوتاسيوم بيرمانجانيت كتو كروميام 2 O7 بوتاسيوم
+
+34
+00:03:10,210 --> 00:03:11,050
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+35
+00:03:11,050 --> 00:03:11,270
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+36
+00:03:11,270 --> 00:03:12,210
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+37
+00:03:12,210 --> 00:03:12,890
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+38
+00:03:12,890 --> 00:03:13,030
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+39
+00:03:13,030 --> 00:03:14,450
+بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم بوتاسيوم
+
+40
+00:03:14,450 --> 00:03:17,470
+بوتاسيوم
+
+41
+00:03:17,470 --> 00:03:24,750
+بوتاسيوم بوتاسيوم بوتاسيوم بفال أكسدة هنا على
+
+42
+00:03:24,750 --> 00:03:29,470
+مرحلة ولا على مرحلتين؟ على مرحلتين بيجي السؤال طب
+
+43
+00:03:29,470 --> 00:03:35,070
+يا تورا لو استعملنا العامل المؤكسد القوي هذا مع ال
+
+44
+00:03:35,070 --> 00:03:42,210
+alcohol مع ال primary alcohol إيش هيعمل؟هيعمل
+
+45
+00:03:42,210 --> 00:03:47,030
+عمليتين الأكسدة هيمر بال الديهايد وبسرعة يظل مستمر
+
+46
+00:03:47,030 --> 00:03:50,730
+لإيش؟ للكربوكسيلك أسد يعني لو استعملت هذا العامل
+
+47
+00:03:50,730 --> 00:03:55,030
+المؤكسد من خلاله اعملت الأكسدة هاحصل على
+
+48
+00:03:55,030 --> 00:03:59,990
+الكربوكسيلك أسد واضح؟ فهيصير عندكم أن ال primary
+
+49
+00:03:59,990 --> 00:04:05,390
+alcohol بعامل مؤكسد قوي واحد من هدول التلاتة
+
+50
+00:04:05,390 --> 00:04:12,000
+نتيجته نهائيةCarboxylic Acid فهمان بمخنا بنقول مر
+
+51
+00:04:12,000 --> 00:04:16,860
+بمرحلة ال الديهايد واتحول بسرعة لاش ل Acid فإذا
+
+52
+00:04:16,860 --> 00:04:20,680
+استعمل عامل قوي النتيجة نهائية ال Acid إذا استعمل
+
+53
+00:04:20,680 --> 00:04:25,620
+عامل ضعيف النتيجة نهائية ال الديهايد لو حد بعد هيك
+
+54
+00:04:25,620 --> 00:04:30,380
+بده يحول ال الديهايد ل Acid يرود يستعمل مرة تانية
+
+55
+00:04:30,380 --> 00:04:35,770
+العامل المؤكسد القويلاحظوا هذه الأكسدة .. هذه
+
+56
+00:04:35,770 --> 00:04:41,150
+الأكسدة أكسدة كثير مهمة و كثير شهيرة يعني ماضلش
+
+57
+00:04:41,150 --> 00:04:45,970
+بعدها انتبهوا معي ال carbon في ال primary alcohol
+
+58
+00:04:45,970 --> 00:04:49,990
+بكم رابطة متصلة مع ال oxygen؟ واحدة .. واحدة ..
+
+59
+00:04:49,990 --> 00:04:51,690
+واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. واحدة
+
+60
+00:04:51,690 --> 00:04:51,850
+واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. واحدة
+
+61
+00:04:51,850 --> 00:04:51,910
+واحدة .. واحدة .. واحدة .. واحدة .. واحدة .. واحدة
+
+62
+00:04:51,910 --> 00:04:52,170
+.. واحدة .. واحدة .. واحدة .. واحدة .. واحدة ..
+
+63
+00:04:52,170 --> 00:05:00,650
+واحدة .. واحدة .. واحدة .. واحدة .. واحد
+
+64
+00:05:02,850 --> 00:05:07,930
+الاربعة بيبطل في إمكانية للاربعة من ناحية المبدأ
+
+65
+00:05:07,930 --> 00:05:13,610
+فيه أعلى مراتب الأكسدة أنه يصير CO2 تاني أكسيد
+
+66
+00:05:13,610 --> 00:05:17,650
+الكربون تطلعوا
+
+67
+00:05:17,650 --> 00:05:20,770
+هنا من ضمن الاتحاد مع الأكسجين بنصير فاهمين
+
+68
+00:05:20,770 --> 00:05:25,370
+الأكسدة بالمفهوم البسيط القديم اتحاد مرة مع
+
+69
+00:05:25,370 --> 00:05:31,970
+الأكسجين مرتينتلاتة الأربع روابط صاروا متحدين مع
+
+70
+00:05:31,970 --> 00:05:37,150
+الأكسجين فأعلى مرحلة في الأكسجين ده أنه يصل لثاني
+
+71
+00:05:37,150 --> 00:05:38,290
+أكسيد الكربون
+
+72
+00:05:43,190 --> 00:05:48,650
+هذه الأكسادات حقيقة بتتم في التطبيق العملي و بتتم
+
+73
+00:05:48,650 --> 00:05:53,530
+كمان في جسم الإنسان يعني في التطبيق العملي لما
+
+74
+00:05:53,530 --> 00:05:58,970
+بيصنعوا الخمر هم بيجيبوا السكريات بيخمروها بتصير
+
+75
+00:05:58,970 --> 00:06:04,830
+إيثانول يعني لما بنفكر إنه عندنا sugar السكر
+
+76
+00:06:04,830 --> 00:06:11,730
+بالتخمير شو بيصير إيثانوللذلك بيخمروا العناب
+
+77
+00:06:11,730 --> 00:06:18,630
+الليزبي بالطمر يصير إيثانول يصير الخمرة طيب و كذلك
+
+78
+00:06:18,630 --> 00:06:23,290
+الفواكه الانجاس والتفاح وما إلى ذلك طب لو خمروه
+
+79
+00:06:23,290 --> 00:06:27,650
+لفترة أطول بظروف معينة يعرفها الناس اللي بيشتغلوا
+
+80
+00:06:27,650 --> 00:06:34,950
+بهذه الأمور هيتحول لإيش؟ لخل و لذلك الخل هو مرحلة
+
+81
+00:06:34,950 --> 00:06:37,690
+بعد الخمر
+
+82
+00:06:39,360 --> 00:06:42,740
+يعني لما بتم عملية التخمر أول اشي بيصير عند ال
+
+83
+00:06:42,740 --> 00:06:46,780
+ethanol الخمر وبعد هيك ال ethanol نفسه بتحول لخل
+
+84
+00:06:46,780 --> 00:06:55,480
+لاحظوا معنى ان الخمر محرم وناجس و الخل محرمحلال
+
+85
+00:06:55,480 --> 00:07:01,340
+وطاهر وفي الحديث افضل ادامكم الخل .. من افضل الأكل
+
+86
+00:07:01,340 --> 00:07:05,140
+اللي ممكن الانسان ياكله يستفيد منه حتى من ناحية
+
+87
+00:07:05,140 --> 00:07:08,800
+بيو كيميسترا يستعمل في تصنيع الجزيئات الأكبر منه
+
+88
+00:07:08,800 --> 00:07:15,790
+الخلالان طب الخمر هذا النجس لما بتحول لخل ايش
+
+89
+00:07:15,790 --> 00:07:21,210
+بيصير فيه؟ يطهر الفقاء ايش بيقولوا عنه؟ يطهر
+
+90
+00:07:21,210 --> 00:07:26,830
+بالتحول يعني إذا تحول النجس من حالته الكيميائية
+
+91
+00:07:26,830 --> 00:07:31,550
+إلى حالة أخرى فإنهم يصبحوا طاهرا ولذلك هذا الخمر
+
+92
+00:07:31,550 --> 00:07:41,490
+حرام هذا الخل حلالواضح؟ إذا تحول النجس إلى طاهر
+
+93
+00:07:41,490 --> 00:07:45,670
+فإنه يطهر، إذا تحول إلى مادة تانية، بيسموها إيش
+
+94
+00:07:45,670 --> 00:07:51,610
+هذه الشغلة؟ التطهير بالتحول، لأنه تحول من المادة
+
+95
+00:07:51,610 --> 00:07:55,870
+النجسة إلى مادة جديدة، فالمادة الجديدة هذه طالما
+
+96
+00:07:55,870 --> 00:07:59,270
+اختلفت في خواصة عن المادة الأولى فهي مادة إشمالها
+
+97
+00:07:59,270 --> 00:08:03,940
+طاهرةالان طيب الناس اللي بيشربوا الخمر إيش بيصير
+
+98
+00:08:03,940 --> 00:08:08,500
+بجسمهم؟ ما هو الخمر بيأثر على العقل بيشرب البني
+
+99
+00:08:08,500 --> 00:08:12,060
+آدم الخمر و بيروح عقله و كل الأشياء الأعراض السكر
+
+100
+00:08:12,060 --> 00:08:15,600
+اللي أنتوا بتعرفوها بعد سبع تمان ساعات تسعة ساعات
+
+101
+00:08:15,600 --> 00:08:19,980
+بيرجع إنسان طبيعي ولا لأ طب كيف الجسم اتخلص من
+
+102
+00:08:19,980 --> 00:08:23,360
+الخمر إذا؟ ما هو الجسم أخد إيثانول هو اللي عمل
+
+103
+00:08:23,360 --> 00:08:27,360
+عنده كل المشاكل كل هذه العمليات بتصير جوا الجسم
+
+104
+00:08:28,560 --> 00:08:33,780
+بالانزيمات المرة هذه إيثانول بيصير الديهايد بيصير
+
+105
+00:08:33,780 --> 00:08:40,070
+acid بيصير ثانو أكسيد الكربون بيطلع مع الزفيريعني
+
+106
+00:08:40,070 --> 00:08:44,390
+في النهاية الخمر كيف البني آدم بده يطلعه على شكل
+
+107
+00:08:44,390 --> 00:08:48,370
+carbon dioxide كل هذه العمليات عمليات الأكسدة
+
+108
+00:08:48,370 --> 00:08:52,890
+حقيقة بالتم في الجسم و زي ما انتوا شايفين بالتم
+
+109
+00:08:52,890 --> 00:08:57,990
+أيضا في الحياة العملية و في الصناعة صناعة الخل هي
+
+110
+00:08:57,990 --> 00:09:02,170
+عبارة عن أكسدة في النهاية هي عبارة عن أكسدة
+
+111
+00:09:06,160 --> 00:09:11,080
+هذا الكلام اللى موجود عندنا هنا الان لو كنا بنعمل
+
+112
+00:09:11,080 --> 00:09:14,900
+ال اكسدة ل secondary alcohol شو اتفقنا عليه بيصير
+
+113
+00:09:14,900 --> 00:09:19,320
+كيتون الان العامل المؤكسد احد العوامل المؤكسدة
+
+114
+00:09:19,320 --> 00:09:24,320
+القوية يعني كيعمل او 4 كي 2 كروميوم 2 او 7 كروميوم
+
+115
+00:09:24,320 --> 00:09:28,920
+او 3 عادة ب sulfuric acid يعني عشان احول ال
+
+116
+00:09:28,920 --> 00:09:34,520
+secondary alcohol الى كيتون بدي استعمل احد العوامل
+
+117
+00:09:34,520 --> 00:09:40,170
+المؤكسدةالقوية التيرتشاري الالكول زي ما اتفقنا مش
+
+118
+00:09:40,170 --> 00:09:45,890
+فيه هيدروجين تفقد ولذلك لا يتأكد بهذا تقريبا بنكون
+
+119
+00:09:45,890 --> 00:09:51,840
+أنهينا موضوعأكسدت الكحولات و دائما بنصحكم ما
+
+120
+00:09:51,840 --> 00:09:55,820
+تحفظوش كأشكال كيميائية لإحفظوه كأفكار ان ال
+
+121
+00:09:55,820 --> 00:09:58,460
+primary alcohol بيصير الديهايد و ممكن ال middle
+
+122
+00:09:58,460 --> 00:10:02,120
+acid حسب قوة العامل مؤكسد ال secondary alcohol
+
+123
+00:10:02,120 --> 00:10:06,140
+بيصير ال ketone و ال tertiary alcohol لايتأكسدش
+
+124
+00:10:06,140 --> 00:10:13,460
+الديهايد بتكون من أول .. احنا من أين يعني جيناها؟
+
+125
+00:10:13,460 --> 00:10:17,120
+هي من نفس التفاعل؟اي O ما هي ال alcohol اللي أنا
+
+126
+00:10:17,120 --> 00:10:21,780
+بادي فيه لأ ال O هذه معناها oxidizing agent
+
+127
+00:10:21,780 --> 00:10:26,920
+احفظوها هذا الرمز ال O اللي مكتوبة بجثين مربعين
+
+128
+00:10:26,920 --> 00:10:31,340
+معناها oxidizing agent بس هو ماحددوش يعني لما
+
+129
+00:10:31,340 --> 00:10:38,420
+تقرؤوا على سهم محطوطة ال O زي هيك معناها بالاكسدة
+
+130
+00:10:39,160 --> 00:10:43,060
+هو مش بواجهة انه يذكر العامل المؤكسد بس وين
+
+131
+00:10:43,060 --> 00:10:47,880
+بتقراوها هذا رمز يعني تفاعل أكسدة باستعمال عامل
+
+132
+00:10:47,880 --> 00:10:50,960
+مؤكسد الآن العوامل المؤكسدة شرحنالكوا إياها اللي
+
+133
+00:10:50,960 --> 00:10:56,480
+في المختبر وقولنالكوا في الجسم في انزيمات عادة
+
+134
+00:10:56,480 --> 00:11:03,200
+Oxidase بتسمى و بتقوم بهذه العملية واضح فهذه ال O
+
+135
+00:11:03,200 --> 00:11:09,350
+اللي مكتوبة بالجسم ربع منها عامل مؤكسدالان ال
+
+136
+00:11:09,350 --> 00:11:15,030
+polyhydroxy compounds هي مركبات تحتوي على اكثر من
+
+137
+00:11:15,030 --> 00:11:19,530
+مجموعة OH و طبعا طالما انه بتحتوي على اكثر من
+
+138
+00:11:19,530 --> 00:11:23,270
+مجموعة OH شو بنتوقع احنا في ال boiling point لهذه
+
+139
+00:11:23,270 --> 00:11:28,150
+المركبات؟ بده تزيد يعني لو عملنا مقارنة مع المركب
+
+140
+00:11:28,150 --> 00:11:31,670
+اللي فيه كربنتين و مجمعتين OH اللي هو ال ethanol
+
+141
+00:11:31,670 --> 00:11:39,330
+CH3 CH2 OH جديش كانت ال boiling point تبعته؟78 لو
+
+142
+00:11:39,330 --> 00:11:45,410
+صاروا مجمعتين OH بتصير يداش 198 لو صاروا تلاتة OH
+
+143
+00:11:45,410 --> 00:11:52,530
+متين وتسعين لو صاروا ستة OH بتحول لصلب بيصير مادة
+
+144
+00:11:52,530 --> 00:11:57,450
+صلبة الها melting point 110 ل 112 واضح؟ وكل هذه
+
+145
+00:11:57,450 --> 00:12:02,210
+المركبات اللي بالذات اللي فيها OH اللي أمامكم عادة
+
+146
+00:12:02,210 --> 00:12:08,120
+بتكون water soluble بتدوب في الميه إيش السبب؟لأنها
+
+147
+00:12:08,120 --> 00:12:12,400
+polar و like dissolves like الآن المركب اللي فيه
+
+148
+00:12:12,400 --> 00:12:16,540
+مجموعتين OH بنسميه احنا إيثالين جليكول لو بدنا
+
+149
+00:12:16,540 --> 00:12:21,480
+يابل ايو باك بزامتين تين OH بدل all دايول حيصير
+
+150
+00:12:21,480 --> 00:12:25,080
+one two اثان دايول اللي فيه تلاتة OH هو ال
+
+151
+00:12:25,080 --> 00:12:30,060
+glycerinاللي بنعمل فيه الإيدين أو ال glycerol one
+
+152
+00:12:30,060 --> 00:12:36,000
+two three بروبان ال triol اللي فيه ستة O H's ال
+
+153
+00:12:36,000 --> 00:12:40,580
+sorbitol المطهر اللي عادة بيستعمله لتطهير الإيدين
+
+154
+00:12:40,580 --> 00:12:43,860
+و الأرضيات اللي هو one two three four five six
+
+155
+00:12:43,860 --> 00:12:53,560
+hexane hexaol ربما بيفيد هنا نقطةتظلوا دائما
+
+156
+00:12:53,560 --> 00:12:59,400
+متذكرينها لأنه ممكن تسألوا عنها ان المركبات عديدة
+
+157
+00:12:59,400 --> 00:13:04,960
+ال O H ليست السكريات طيب السكريات ايش بتكون
+
+158
+00:13:04,960 --> 00:13:09,060
+السكريات او sugars و هنعود ناخد هذا الكلام في ال
+
+159
+00:13:09,060 --> 00:13:14,540
+biochemistry هي مركبات عديدة ال O H لكن بينوجد
+
+160
+00:13:14,540 --> 00:13:18,940
+فيها مجموعة واحدة بالاضافة لل O H الديهيد او كيتون
+
+161
+00:13:19,910 --> 00:13:25,290
+فعشان المُركّب يكون سُكر ضمن تصنيف الكيميائي من
+
+162
+00:13:25,290 --> 00:13:29,250
+السُكريات بدوا يكون فيه مجموعات أوقاتش كتير بس
+
+163
+00:13:29,250 --> 00:13:34,790
+بدوا يكون فيه واحدة الديهايد او كيتون يعني مثلا لو
+
+164
+00:13:34,790 --> 00:13:40,680
+هذه كانت كيتونهذا بلغة الكيميا بيصير إيش؟ sugar لو
+
+165
+00:13:40,680 --> 00:13:44,940
+هذه نفترض كانت الديهيد هذا بلغة الكيميا بيصير
+
+166
+00:13:44,940 --> 00:13:51,980
+sugar فال sugars تعريفها بوليهيدروكسي صح بس مش
+
+167
+00:13:51,980 --> 00:13:57,520
+بوليهيدروكسي compounds لأ بوليهيدروكسي الديهيد أو
+
+168
+00:13:57,520 --> 00:14:04,270
+كيتون واضح؟شوفنا إيش بيفرغوا السكريات عن ال
+
+169
+00:14:04,270 --> 00:14:07,810
+polyhydroxy compounds ال polyhydroxy compounds بس
+
+170
+00:14:07,810 --> 00:14:13,690
+مجموعات OH لو مع مجموعات ال OH إيجي عندى aldehyde
+
+171
+00:14:13,690 --> 00:14:18,050
+أو كيتون وقتها بيصيروا المراكبات إيش sugars ال
+
+172
+00:14:18,050 --> 00:14:22,410
+polyhydroxy aldehydes هنتعلم إنه اسمهم ال doses و
+
+173
+00:14:22,410 --> 00:14:26,690
+ال polyhydroxy ketones هنتعلم إنه اسمهم ketoses
+
+174
+00:14:26,690 --> 00:14:32,120
+واضح؟فنضل متذكرين هذه المعلومة ان السكر الديهيد او
+
+175
+00:14:32,120 --> 00:14:39,220
+كيتون مع مجموعات O H اكتار واضح الديهيد او كيتون
+
+176
+00:14:39,220 --> 00:14:44,480
+لحاله مش Sugar مجموعات O H لحالهابرضه مش sugar
+
+177
+00:14:44,480 --> 00:14:50,940
+واضح ال sugar ال dehydrate او كيتون ومعه مجموعات
+
+178
+00:14:50,940 --> 00:14:57,400
+OH اكتر طبعا في مركبات تانية ربما اخليكوا تعرفوا
+
+179
+00:14:57,400 --> 00:15:01,460
+واحد منها بس aromatic compounds عليهم اكتر من ال
+
+180
+00:15:01,460 --> 00:15:04,480
+OH و بيمروا مرات معاكم في ال biology او ال
+
+181
+00:15:04,480 --> 00:15:08,560
+biochemistry مثلا المركب اللي فيه تنتين OH على ال
+
+182
+00:15:08,560 --> 00:15:13,560
+ortho position اسمه catecholاكتير هتظل تقرأ
+
+183
+00:15:13,560 --> 00:15:17,580
+كاتيكول و ما إلى ذلك و هذا المركب resource ..
+
+184
+00:15:17,580 --> 00:15:23,800
+resource in all هذا hydroquinone هذا بيرو .. بيرو
+
+185
+00:15:23,800 --> 00:15:29,510
+غالول الآن خلّينا اليوميعني إذا بدنا بالتأكيد
+
+186
+00:15:29,510 --> 00:15:32,210
+تكونوا حافظين مركّب تعرفوا الـ hydroquinone
+
+187
+00:15:32,210 --> 00:15:37,850
+الهيدروكوينون المركّب اللي فيه بارا دايهيدروكسي
+
+188
+00:15:37,850 --> 00:15:41,390
+بنزين واضح؟ هذا إيش اسمه؟
+
+189
+00:15:43,500 --> 00:15:49,240
+الان الـ Hydroquinone عادة بيعمل أكسدة و زي ما
+
+190
+00:15:49,240 --> 00:15:54,300
+قلنا احنا محصلة الأكسدة فقد ذرتين الهيدروجين و
+
+191
+00:15:54,300 --> 00:15:57,820
+تكوين رابطة لو انا اطلعت على هذا الجزء الـ
+
+192
+00:15:57,820 --> 00:16:03,300
+Hydroquinone هاي رابطة تنتين تلاتة طب لو فقدت هذه
+
+193
+00:16:03,300 --> 00:16:08,540
+الـ H و هذه الـ Hهعمل كمان رابط اي كداش حيصير
+
+194
+00:16:08,540 --> 00:16:12,840
+مجموع الروابط الزوجية اربعة حيصير بهذا الشكل شكل
+
+195
+00:16:12,840 --> 00:16:17,240
+المركب الان هذا بنسمي احنا Benzoquinone او 1,4
+
+196
+00:16:17,240 --> 00:16:21,600
+-benzoquinone لاحظوا ان هذه العملية تمت في وجود
+
+197
+00:16:21,600 --> 00:16:28,870
+عاملمؤكسد فالفينول تتأكسد
+
+198
+00:16:28,870 --> 00:16:34,710
+و تصبح تحديدا منها الهيدروكوينون بيصبح بالزوكوينون
+
+199
+00:16:34,710 --> 00:16:39,270
+و كل الفينول بشكل عام عادة ما بتتم عليها تأكسد
+
+200
+00:16:39,270 --> 00:16:43,810
+بطريقة او باخره هذا الكلام بيحولنا لتطبيق كتير مهم
+
+201
+00:16:43,810 --> 00:16:48,430
+ان فيه مركبات احنا في الدنيا بنسميها antioxidants
+
+202
+00:16:48,430 --> 00:16:51,790
+يعني مركبات
+
+203
+00:16:53,530 --> 00:17:00,090
+بديش اقول عنها انا مضادة ربما الترجمة مرات تحتاج
+
+204
+00:17:00,090 --> 00:17:06,950
+إلى نوع من الدقة تماما زي ما بنترجم احنا كلمة
+
+205
+00:17:06,950 --> 00:17:11,900
+مانعة الصواعقتمام؟ اكتر ربما مر عليكم انه باللغة
+
+206
+00:17:11,900 --> 00:17:17,280
+العربية بيستعمله مانعة الصواعق الحقيقة الصاعقة من
+
+207
+00:17:17,280 --> 00:17:21,020
+ربنا سبحانه وتعالى هذا العمود الحديد اللي احنا
+
+208
+00:17:21,020 --> 00:17:27,650
+بنحقه هيك هل يا ترى يمنع الصاعقة أن تحدث؟أه إذا هو
+
+209
+00:17:27,650 --> 00:17:32,290
+إيش بيعمل هو يمطس الصائقة و لا يمنع الصائقة و لذلك
+
+210
+00:17:32,290 --> 00:17:36,870
+الصائقة كهربا كبيرة جدا لو نزلت على المبنى بتحرج
+
+211
+00:17:36,870 --> 00:17:40,030
+أو بتحرك شبكات الكهربا اللي فيه لما يحطوا هذه
+
+212
+00:17:40,030 --> 00:17:44,130
+الحديدة كل الكهربا اللي نازلة من الصائقة بتدخل في
+
+213
+00:17:44,130 --> 00:17:48,390
+الحديدة موصولة بسلك في الأرض بتتفرج في الأرض بتتوه
+
+214
+00:17:48,390 --> 00:17:54,170
+بدل ما تنزل على الأجهزة و على المبنى فبهذا المفهوم
+
+215
+00:17:54,170 --> 00:17:59,390
+الصائقة صائقة لم تمنعلكن ايش اللي صار عنده؟ تم
+
+216
+00:17:59,390 --> 00:18:05,690
+انتصاص للصواقة ولذلك ربما يكون أدق انها تتسمى مش
+
+217
+00:18:05,690 --> 00:18:12,310
+مانعة الصواقر، ماصة الصواقر، واضح؟ كذلك الحال في
+
+218
+00:18:12,310 --> 00:18:16,110
+المركبات اللي اسمها antioxidants و اللي احنا عادة
+
+219
+00:18:16,110 --> 00:18:24,150
+بنضيفها على الأطعمةتسميتها بمضادات الأكسدة وكأنها
+
+220
+00:18:24,150 --> 00:18:30,510
+تمنع الأكسدة ليست تسمية أو ليست ترجمة دقيقة لهذا
+
+221
+00:18:30,510 --> 00:18:36,830
+المصطلح الأصل أن نقول عنها مركبات ماصة للأكسدة
+
+222
+00:18:36,830 --> 00:18:43,530
+بمعنى إذا احنا عملنا مثلا علبة معلباتأو مرتاديلة
+
+223
+00:18:43,530 --> 00:18:47,990
+أو ما إلى ذلك وضفنا عليها هذه المادة ودخل عليها ..
+
+224
+00:18:47,990 --> 00:18:52,510
+دخل عليها شوية أكسوجين وهي مغلقة هذا الأكسوجين أو
+
+225
+00:18:52,510 --> 00:18:56,510
+أي مادة مؤكسدة هيك هيك وظيفته هيجوم فيها هيعمل
+
+226
+00:18:56,510 --> 00:19:01,190
+أكسدة لكن اللي بيصير .. اللي بيصير بالظبط .. اللي
+
+227
+00:19:01,190 --> 00:19:06,190
+بيصير بالظبط في فكرة الـ Antioxidants اتخيلوها
+
+228
+00:19:06,190 --> 00:19:11,680
+انتوا بهذا الشكل ان انا هيعندي علبة معلباتواضح؟
+
+229
+00:19:11,680 --> 00:19:19,280
+هذه معلبة لحمة الان هذه المعلبة اللحمة فيها اللحوم
+
+230
+00:19:19,280 --> 00:19:25,440
+خلينا نقول الحمراء وفيها بنسبة قليلة جدا جدا
+
+231
+00:19:25,440 --> 00:19:34,360
+antioxidant المادة هذه اللي بنقول عنهاالان اتيت
+
+232
+00:19:34,360 --> 00:19:41,620
+اكساد او اكسوجين او اكساد اكساد اكساد اكساد اكساد
+
+233
+00:19:41,620 --> 00:19:50,450
+اكساد اكسادإذا أكسدت اللحوم هتطلع مواد سامة برائحة
+
+234
+00:19:50,450 --> 00:19:55,870
+سيئة اللي هو فساد اللحمة، الآن في احتمال تاني إنها
+
+235
+00:19:55,870 --> 00:20:00,290
+ت أكسد ال antioxidant اللي أنا حطيته، بشكل عام
+
+236
+00:20:00,290 --> 00:20:04,490
+ميزة ال antioxidant إنه أسهل في الأكسدة، وبناء على
+
+237
+00:20:04,490 --> 00:20:10,290
+ذلك لما هذه بتتيجي إيش المادة الأسهل أن تتأكسد ال
+
+238
+00:20:10,290 --> 00:20:16,220
+antioxidant؟واضح؟ فالعمل المؤكسد هي كيك بيأكسد
+
+239
+00:20:16,220 --> 00:20:24,440
+فبيأكسد ال antioxid يعني مرة تانية نرجع نقول أن
+
+240
+00:20:24,440 --> 00:20:31,560
+اللحوم دلت زي ما هي ماصارش عليها إشي الآن ال
+
+241
+00:20:31,560 --> 00:20:35,100
+antioxid اتغيرت صارت أشياء جديدة
+
+242
+00:20:38,120 --> 00:20:43,060
+فعملية ال Oxidation حولت ال antioxidant لمادة
+
+243
+00:20:43,060 --> 00:20:46,620
+تانية الآن انتبهوا للناس اللي بيشتغلوا في الأغذية
+
+244
+00:20:46,620 --> 00:20:51,280
+شرط عندهم أن هذه المادة اللي أنا بستعملها
+
+245
+00:20:51,280 --> 00:20:56,320
+antioxidant تكون آمنة وغير سامة، مظبوط ولا لأ؟ ما
+
+246
+00:20:56,320 --> 00:21:01,730
+أنا ضيفة على الأكل، إذا هذه لازم تكون إيش؟ Safeو
+
+247
+00:21:01,730 --> 00:21:07,190
+ناتج أكسادتها أيضا هيضلوا في الأكل برضه لازم ايش
+
+248
+00:21:07,190 --> 00:21:15,490
+يكون safeفهل يا ترى عملية ال Axa ده مُنِعت ولا
+
+249
+00:21:15,490 --> 00:21:21,110
+تمت؟ تمت لكن تمت على إيش؟ على ال antioxidant مش
+
+250
+00:21:21,110 --> 00:21:24,730
+على اللحوم وال antioxidant تحول إلى مادة غير ضارة
+
+251
+00:21:24,730 --> 00:21:28,190
+وبالتالي ماصارش تأثير هذه فكرة بالظبط ال
+
+252
+00:21:28,190 --> 00:21:32,010
+antioxidants الآن من المواد اللي بتستعمل
+
+253
+00:21:32,010 --> 00:21:36,050
+antioxidants اللي هي ال phenolsيعني لو بتكون
+
+254
+00:21:36,050 --> 00:21:39,370
+تبحثوا في google search مثلا اكتبوا antioxidant
+
+255
+00:21:39,370 --> 00:21:43,350
+بتلاقوه بيكمل الكوفينول و آلاف الأبحاث و المواد
+
+256
+00:21:43,350 --> 00:21:50,710
+بعضها طبيعي و بعضها صناعي يعني مثلا هذا vitamin E
+
+257
+00:21:50,710 --> 00:21:55,070
+لاحظوا فيه هنا مجموعة الفينول ولا لأ
+
+258
+00:21:57,730 --> 00:22:02,250
+شكل كبير ماله و ماله لكن الجزء الفعال فيه جزء
+
+259
+00:22:02,250 --> 00:22:08,450
+الفينول ولذلك vitamin E بنقول عنه natural phenolic
+
+260
+00:22:08,450 --> 00:22:13,090
+antioxidant يعني مضاد للأكسدة أو مواصل الأكسدة
+
+261
+00:22:13,090 --> 00:22:19,100
+خلينا هيك اتفقنا عليه من مصادرطبيعية الآن في مواد
+
+262
+00:22:19,100 --> 00:22:22,740
+من مصادر صناعية يعني صنعوها في المختبر و بيضفوها و
+
+263
+00:22:22,740 --> 00:22:26,460
+هذه مشهورة كل علب المرتدلة و البندورة و البصاريش
+
+264
+00:22:26,460 --> 00:22:30,880
+بيضفو عليها منها هذه المراكبات أهم شي انتبهوا فيها
+
+265
+00:22:30,880 --> 00:22:38,020
+مجموعة ال ايش ال O H's الان هذه المراكبات مشتقات
+
+266
+00:22:38,020 --> 00:22:43,900
+أنيزول متذكرين الانيزول البنزينة اللي عليها O مثل
+
+267
+00:22:43,900 --> 00:22:49,510
+هذه اسمها أنيزوللما أخدنا ال aromatic compounds
+
+268
+00:22:49,510 --> 00:22:54,070
+أنيزول بنزين عليها O مثل عشان هيك هذا بنقول عنه
+
+269
+00:22:54,070 --> 00:22:58,350
+butylated لإنه هذا المجموعه butyl اربع كربونات
+
+270
+00:22:58,350 --> 00:23:05,130
+هيدروكسي لإنه فيه OH والاصل أنيزول شوفتوا الاسم من
+
+271
+00:23:05,130 --> 00:23:08,990
+كام قطعة مكوّن بيوتل و هيدروكسي و أنيزول هاي ال
+
+272
+00:23:08,990 --> 00:23:11,270
+butyl انعلمه بالأحمر
+
+273
+00:23:13,790 --> 00:23:21,090
+بيوتليتد هيدروكسي أنيزول الان ايش بيختصروه BHA
+
+274
+00:23:21,090 --> 00:23:26,630
+وهذا زيه بيوتليتد هيدروكسي أنيزول طيب لو الحلقة
+
+275
+00:23:26,630 --> 00:23:35,090
+الأصلية كانت طلوين هي بيوتلأيضا اكثر من مجموعة في
+
+276
+00:23:35,090 --> 00:23:41,510
+هذا المُركّب بيوتل وهيدروكسي وطولوين بيوتلاتد
+
+277
+00:23:41,510 --> 00:23:46,990
+هيدروكسي طولوين بيوتلاتد
+
+278
+00:23:46,990 --> 00:23:51,140
+هيدروكسي طولوينو عادة بتاخد رموز يعني بتلاقوها
+
+279
+00:23:51,140 --> 00:23:58,080
+بكتبوا BHA و BHT فالـ BHA و BHT اللي هي butylated
+
+280
+00:23:58,080 --> 00:24:01,240
+hydroxy anisole و butylated hydroxy toluene are
+
+281
+00:24:01,240 --> 00:24:06,840
+synthetic antioxidants عارفين إيش يعني synthetic
+
+282
+00:24:07,620 --> 00:24:13,500
+يعني مصنعة في المعمل، synthetic، هذه natural من
+
+283
+00:24:13,500 --> 00:24:17,420
+الطبيعة، في أشياء في الطبيعة و في أشياء بنصنعها
+
+284
+00:24:17,420 --> 00:24:26,180
+احنا و بنضيفها على الأطعمة هذا بالنسبة لموضوع الـ
+
+285
+00:24:26,180 --> 00:24:27,560
+Antioxidants
+
+286
+00:24:31,430 --> 00:24:36,590
+المُركّب أنيزول، المُركّب أنيزول، المُركّب أنيزول،
+
+287
+00:24:36,590 --> 00:24:43,090
+أما هي methoxy، methoxy، مش فيها خلافبنجي للعائلة
+
+288
+00:24:43,090 --> 00:24:48,550
+المشتقة من ال alcohols اللي قُبضلت فيها مجموعة ال
+
+289
+00:24:48,550 --> 00:24:55,330
+OH ب SH هذه العائلة شو بنسميها؟ Thyol فبدل ما يصير
+
+290
+00:24:55,330 --> 00:24:59,750
+نهاية المُركّب All بيصير نهاية المُركّب Thyol
+
+291
+00:24:59,750 --> 00:25:04,510
+ولذلك هذا مثلا كنا نسميه بال OH مثال All بيصير
+
+292
+00:25:04,510 --> 00:25:12,160
+مثالثيول هذا ابروبانول بيصير ابروبانثيول او عفوا
+
+293
+00:25:12,160 --> 00:25:16,520
+بيوتان اربعة بيوتانثيول طبعا لازم نحدد الموقع ولا
+
+294
+00:25:16,520 --> 00:25:23,080
+لأ ابيوتانثيول هذا بدل فينول شو بنسميه؟ ثيوفينول
+
+295
+00:25:23,080 --> 00:25:27,640
+ال OH فينول بال سالفر ثيوفينول الآن متذكرين لما
+
+296
+00:25:27,640 --> 00:25:32,960
+كان انا يكون OH شو كنت اسمي المركب؟ مثل ال alcohol
+
+297
+00:25:34,340 --> 00:25:40,120
+أو بيوت ال alcohol بال common name ال common name
+
+298
+00:25:40,120 --> 00:25:45,660
+بذكر المجموعة ثم العائلة مثل مثل alcohol هذا
+
+299
+00:25:45,660 --> 00:25:48,920
+common name المجموعة في العائلة بيوت ال alcohol و
+
+300
+00:25:48,920 --> 00:25:53,460
+هكذا الآن العائلة الموازية لكلمة alcohol في
+
+301
+00:25:53,460 --> 00:26:00,020
+الكبريت مركبتان فهذا بيصير مثلمركبتان هذا بيصير
+
+302
+00:26:00,020 --> 00:26:06,180
+بيوتل مركبتان هذا بيصير فنل مركبتان فمركبتان هي
+
+303
+00:26:06,180 --> 00:26:12,360
+العائلة الموازية لكلمة إيش؟ Alcohol زي ما كنت أقول
+
+304
+00:26:12,360 --> 00:26:15,400
+مثل ألكول، إثل ألكول، برو بالألكول، لو قلتلكوا
+
+305
+00:26:15,400 --> 00:26:19,720
+أرسموا مثل مركبتان، إثل مركبتان، بيوتل مركبتان،
+
+306
+00:26:19,720 --> 00:26:23,420
+ايزو بيوتل مركبتان، بتكون تشيلوا بدل أو أتش و
+
+307
+00:26:23,420 --> 00:26:29,570
+تحطوا الالكول، واضح؟طبعا وين انتوا بتشوفوا كلمة
+
+308
+00:26:29,570 --> 00:26:33,430
+mercapto او ثيو اعرفوا ان انتوا أمام مركب فيه
+
+309
+00:26:33,430 --> 00:26:37,290
+cabret يعني مركبات الكابريت دائما يا هتلاقوا فيها
+
+310
+00:26:37,290 --> 00:26:42,350
+ثيو زي ما شوفته هنا يا mercapto مثلا هذا حمض الخل
+
+311
+00:26:42,350 --> 00:26:49,930
+بس حولنا فيه بدل ما كانت OH أسيتك أسن CH3C double
+
+312
+00:26:49,930 --> 00:26:55,450
+bond O OH أسيتك أسن طب لو شيلت ال O خلتها S صار
+
+313
+00:26:55,450 --> 00:27:04,380
+ثيونacetic acid واضح هذا مثلا sulphide السلفر
+
+314
+00:27:04,380 --> 00:27:12,420
+المتصل فيها مجموعتين R إثل و إثل داي إثل sulphide
+
+315
+00:27:12,420 --> 00:27:16,100
+و الداي مرات تختصر يعني بنقدر نسميه الداي إثل و
+
+316
+00:27:16,100 --> 00:27:20,280
+بنقدر نسميه إثل يعني لما نقول إثل sulphide أو داي
+
+317
+00:27:20,280 --> 00:27:24,560
+إثل sulphide الإسمين صحيحين
+
+318
+00:27:25,800 --> 00:27:29,720
+الان لو اجينا عليها هذه العائلة قولنا يا تورا هذه
+
+319
+00:27:29,720 --> 00:27:33,800
+عائلة التيورس كيف بنحضرها ال R X أخدناها في
+
+320
+00:27:33,800 --> 00:27:37,700
+chapter 6 بال nucleophilic substitution فعلوها مع
+
+321
+00:27:37,700 --> 00:27:42,440
+S H minus charged nucleophile بيهاجم على ال R و
+
+322
+00:27:42,440 --> 00:27:48,580
+بيطرد ال X هذا الإبدال اللي أخدناه في chapter 6
+
+323
+00:27:48,580 --> 00:27:57,270
+مشحون مكان مشحون فال R X بتصيرRSH اذا هى هذا اللى
+
+324
+00:27:57,270 --> 00:28:03,070
+هو how to prepare thyols by reaction of RX يصيروا
+
+325
+00:28:03,070 --> 00:28:08,710
+RSH الان بدى يكون عندكم شوية كيميا كبيرة فى مخكم
+
+326
+00:28:08,710 --> 00:28:13,490
+بمعنى لو انا يا تورا قلتلكم كيف بدكم تحضروا thyol
+
+327
+00:28:13,490 --> 00:28:16,970
+من الالكول الthyol انتوا عامال عندكم من وين بنحضره
+
+328
+00:28:16,970 --> 00:28:25,170
+من ال RX طب لو انا بديلكم ب ROHأخدت طريقة تحوّل ال
+
+329
+00:28:25,170 --> 00:28:32,310
+R OH ل R X تكون متذكرينها طيب ممكن كمان أبدأ من ال
+
+330
+00:28:32,310 --> 00:28:37,290
+كيم أخدت طريقة تحوّل ال ال كيم ل R X ولا لأ إضافة
+
+331
+00:28:37,290 --> 00:28:47,070
+HX فبصير مطلوب منكوا أن تدمجوا أكثر من معلومة في
+
+332
+00:28:47,070 --> 00:28:53,260
+الكيمياأخدنا احنا ان الثيولز are stronger acids
+
+333
+00:28:53,260 --> 00:28:58,520
+than alcohols، والسبب ايش حكينا؟ ال size، ال size،
+
+334
+00:28:58,520 --> 00:29:01,660
+ولذلك الثيولز بتفاعلوا مع ال sodium hydroxide
+
+335
+00:29:01,660 --> 00:29:07,170
+وبيعطوا ملح وماء، هذه المعادلة أخدناهامن أهم
+
+336
+00:29:07,170 --> 00:29:12,450
+التفاعلات تبعت الـthiols أنه بيتم عليهم أكسدة
+
+337
+00:29:12,450 --> 00:29:16,650
+جزيئين thiol بيفقدوا هيدروجين ماشيلنا ساعة بيقول
+
+338
+00:29:16,650 --> 00:29:20,790
+الأكسدة بيدا تفقد ذاتين هيدروجين الأن بنجيب جزيئين
+
+339
+00:29:20,790 --> 00:29:25,830
+thiol RSH بنسبة اتنين مثلا بالأكسدة بيفقدوا
+
+340
+00:29:25,830 --> 00:29:32,760
+هيدروجينيعني ماينوس اكشت و الاكس ده بيصير RSSR هذا
+
+341
+00:29:32,760 --> 00:29:37,940
+صار اسمه داي سالفايد لما عندي سالفار واحدة سالفايد
+
+342
+00:29:37,940 --> 00:29:41,940
+لما عندي تنتين داي سالفايد لو افترضنا هنا اثل و
+
+343
+00:29:41,940 --> 00:29:48,040
+اثل شو بدا اسم المركب داي اثل داي سالفايد طب لو
+
+344
+00:29:48,040 --> 00:29:52,600
+مثل و مثل داي مثل داي سالفايد لو هذه المجموعة اللي
+
+345
+00:29:52,600 --> 00:29:59,580
+مرة أخدناهاالألل اللى موجودة فيه التومة داي ألل
+
+346
+00:29:59,580 --> 00:30:06,300
+داي سالفايد واضح فالثيول هم اكسيدز لثيول داي
+
+347
+00:30:06,300 --> 00:30:11,040
+سالفايد الان لو ضفنا عليهم هيدروجين يعملنا التفاعل
+
+348
+00:30:11,040 --> 00:30:17,820
+العكسى ال داي سالفايد ايش بيرجعوا ثيول اذا هذه
+
+349
+00:30:17,820 --> 00:30:23,900
+عمليةبتمشي باتجاهين بحق في الهيدروجين الثيول بيصير
+
+350
+00:30:23,900 --> 00:30:27,600
+داي سالفايد هذه أكسه ده بإضافة الهيدروجين ال داي
+
+351
+00:30:27,600 --> 00:30:33,160
+سالفايد بترجع لإيش؟لثيول الان هذه العملية .. هذه
+
+352
+00:30:33,160 --> 00:30:37,900
+العملية الحقيقة عملية في ال biology و في الأحياء
+
+353
+00:30:37,900 --> 00:30:42,340
+كتير مهمة ليش؟ لأنه في النهاية البروتينات لما
+
+354
+00:30:42,340 --> 00:30:47,540
+بتتماسك مع بعض لبعض فيها مجموعات الثيول و تحديدا
+
+355
+00:30:47,540 --> 00:30:51,920
+جاية من ال amino acid السيستين فتخيلوا ان عندكم
+
+356
+00:30:51,920 --> 00:30:57,060
+مثلا سلسلتين و في النهاية فيهم SH من البروتين هذا
+
+357
+00:30:57,060 --> 00:31:05,700
+بالأكسدةيفقد الهيدروجنتين و يعمل رابطة، بهيك صار
+
+358
+00:31:05,700 --> 00:31:11,320
+البروتين امسك بشكل قوي ولا لأ؟ بيصير البروتين امسك
+
+359
+00:31:11,320 --> 00:31:18,040
+بشكل قوي، الآن من أمثلة البروتينات اللي فيها الـ
+
+360
+00:31:18,040 --> 00:31:24,390
+disulfides الشعرو عشان هيك الشعر لاحظه أنه أحيانا
+
+361
+00:31:24,390 --> 00:31:28,350
+لما الإنسان إيده بتقترب من النار أو بينحرق شعره
+
+362
+00:31:28,350 --> 00:31:34,090
+بيشم رائحة سيئة رائحة حرق الشعر سيئة شو السبب؟ أن
+
+363
+00:31:34,090 --> 00:31:42,430
+الشعر فيه كبريت الآن هذا الشعر الناس للأسف الشديد
+
+364
+00:31:42,430 --> 00:31:48,730
+مش عاجبها حالها كل من هو بده يغير إيش شكله امتثالا
+
+365
+00:31:51,390 --> 00:31:58,310
+لما قولت الشيطان ثم لأمرنهم فلا يغيرن خلق الله
+
+366
+00:31:58,310 --> 00:32:03,850
+يعني اللي في أفريقيا الشعر عندهم لو لو بيعمل بده
+
+367
+00:32:03,850 --> 00:32:07,510
+يفرده و اللي في أوروبا ربنا ماعطيهم الشعر العدل
+
+368
+00:32:07,510 --> 00:32:13,930
+بتشوفهم كيف بدهم يعملوا الوف الان هذا بالانجليزي
+
+369
+00:32:13,930 --> 00:32:20,920
+احنا بنقوله curly الشعرالمجاعد المجاعد أو straight
+
+370
+00:32:20,920 --> 00:32:24,780
+الشعر المستقيم الشعر المستقيم الان ابتاع ال
+
+371
+00:32:24,780 --> 00:32:28,920
+straight بدو يصير مجاعد وابتاع المجاعد بدو يصير
+
+372
+00:32:28,920 --> 00:32:33,240
+straight ماحدش عاجبه حاله هذه العملية سواء تمت
+
+373
+00:32:33,240 --> 00:32:38,210
+بهذا الاتجاه او بهذا الاتجاه هي عملية كيميائيةهي
+
+374
+00:32:38,210 --> 00:32:41,170
+عملية كيميائية، يعني هذه العملية اللي بتنعمل في
+
+375
+00:32:41,170 --> 00:32:47,250
+صالونات لحلاجة وعند الكوفيرات الحقيقة هي عملية
+
+376
+00:32:47,250 --> 00:32:51,330
+كيميائية الفكرة فيها وين؟ انه احنا بنقدر نتخيل
+
+377
+00:32:51,330 --> 00:32:57,170
+الشعر بروتين وهذا البروتين ممسك بـ disulfide bonds
+
+378
+00:32:57,170 --> 00:33:05,450
+ملاحظين هنا؟هذه بتقدروا تتخيلوها شعرة، الان كونوا
+
+379
+00:33:05,450 --> 00:33:10,470
+الشعر في الـ disulfide bond هذه، بيصير الشعر قوي
+
+380
+00:33:10,470 --> 00:33:15,830
+ولا لأ؟ بالنسبة لخيط، بالنسبة لخيط يعتبر الشعر
+
+381
+00:33:15,830 --> 00:33:23,200
+قوي، سبب القوة تبعته وجود إيش؟ وجود؟الـ disulfide
+
+382
+00:33:23,200 --> 00:33:29,060
+bond الان كيف يتحول
+
+383
+00:33:29,060 --> 00:33:34,800
+الشعر من شكل إلى آخر خلينا نعملها ربما بالجلم
+
+384
+00:33:34,800 --> 00:33:44,260
+بتحبوا نبدأ بإيش؟ بشعر straight ونخليه curly الان
+
+385
+00:33:44,260 --> 00:33:52,020
+هذه الشعره straight هذه الشعره إيش فيها روابط؟SS
+
+386
+00:33:52,020 --> 00:33:58,460
+نعمل رابطتين او تلاتة الان هذه الروابط بيخليها
+
+387
+00:33:58,460 --> 00:34:03,660
+عدلة طب لو انا بدي اتنيها شعره جوية ايش لازم اعمل
+
+388
+00:34:03,660 --> 00:34:08,800
+في الاول اكسر هدوله عشان هيك بييجوا بيعملوا عملية
+
+389
+00:34:08,800 --> 00:34:14,830
+ايش reductionيعني بيحطوا مادة ع الشعر و بيفركوه
+
+390
+00:34:14,830 --> 00:34:19,670
+بتدخل هذه المادة جوا الشعر فبتضعف الشعره بتصير
+
+391
+00:34:19,670 --> 00:34:23,690
+عملية reduction الان ال reduction لاحظوا معي شو
+
+392
+00:34:23,690 --> 00:34:33,170
+عمل؟ كسر ال di-sulfate خلاها SH SH SH SH و هكذا
+
+393
+00:34:33,170 --> 00:34:43,400
+الان هذه كانت شعره قويةصارت شعرة ضعيفة الآن الشعرة
+
+394
+00:34:43,400 --> 00:34:49,800
+الضعيفة بالمشط مع شوية استشوار ممكن نتنيها واضح؟
+
+395
+00:34:49,800 --> 00:34:57,820
+لأنها ضعيفة وعشان هيك ممكن نخليها بهذا الشكل طبعا
+
+396
+00:34:57,820 --> 00:35:05,960
+أسأتش أسأتش تمت المهمة ولا لأ؟ تمت، هذه الشعرة
+
+397
+00:35:05,960 --> 00:35:12,520
+اللي كانتعدلة إيش صارت؟ إضعيفة بس هذه في الأجارة
+
+398
+00:35:12,520 --> 00:35:19,320
+بتستهلش ميت شكل تستهل بس قداشر؟
+
+399
+00:35:19,320 --> 00:35:26,740
+اشرين تلاتين شكل ليش؟ لأنه إضعيفة بتعاود تعدل ما
+
+400
+00:35:26,740 --> 00:35:31,060
+هو اللي بيعمل منكر بده يكمله إذا إيش الحل عشان
+
+401
+00:35:31,060 --> 00:35:38,820
+نكمل هالقصة؟ إننا نرد بشكل جديد نجويهاعشان بتكون
+
+402
+00:35:38,820 --> 00:35:44,440
+تدفعوا مصارى، بتقولش الواحد الشعر يكون طويل، يصاب،
+
+403
+00:35:44,440 --> 00:35:50,640
+املولو، بعدين روح قدر لجارجع زي ما هو، املاحظين
+
+404
+00:35:50,640 --> 00:35:54,360
+انتوا؟ عشان هيك هذى بيعملولها كمان عملية كيميائية،
+
+405
+00:35:54,360 --> 00:35:58,380
+شو العملية الكيميائية؟ أكسدة مرة تانية ع الشكل
+
+406
+00:35:58,380 --> 00:36:08,260
+الجديد عشان ترجع جوية، لإن هذى ضعيفةهذه ضعيفة،
+
+407
+00:36:08,260 --> 00:36:13,300
+بدنا نحافظ على الشكل الجديد اللي عملناه وعشان هيك
+
+408
+00:36:13,300 --> 00:36:17,440
+اللي انتوا مرات بتسموه مثبت أو غيره ميتي الأكسجين
+
+409
+00:36:17,440 --> 00:36:26,800
+اللي بتبحط اه H2O2 أكسدا فلاحظوا
+
+410
+00:36:26,800 --> 00:36:34,040
+عملية تحويل الشعر من شعر straight إلى curly بتمر
+
+411
+00:36:34,040 --> 00:36:40,610
+بكم عملية؟عمليتين العملية
+
+412
+00:36:40,610 --> 00:36:44,150
+الأولى reduction صارت الشعر القوى ضعيفة
+
+413
+00:36:46,370 --> 00:36:51,770
+ملفوفة بشكل معين وبعدين رديت أكسادتها إذا رجعتها
+
+414
+00:36:51,770 --> 00:36:56,570
+لشكل إيش القوي عشان هيك بتثبت بالشكل الجديد
+
+415
+00:36:56,570 --> 00:37:01,710
+فعمليتين بتتموا على الشعرة عشان تتحول هذا التحول
+
+416
+00:37:01,710 --> 00:37:06,850
+عملية reduction وعملية oxidation الآن لو سألنا أي
+
+417
+00:37:06,850 --> 00:37:14,850
+واحدة فيكم طيب ناس من أفريقيا مثلاشعرهم مجعد، بدهم
+
+418
+00:37:14,850 --> 00:37:19,870
+يخلوه عدل، بدهم يعكسوا كل هذه الدائرة، بدهم يبدأوا
+
+419
+00:37:19,870 --> 00:37:25,430
+بال reduction عكس ال oxidation، reduction، تصير
+
+420
+00:37:25,430 --> 00:37:30,410
+زيك ضعيفة، بعدين بيعدلوها بالاستشوار والنار، بتصير
+
+421
+00:37:30,410 --> 00:37:38,250
+عدلة، فرحوا، بعدين بيأكسدوها، بتصير قوية بالشكل
+
+422
+00:37:38,250 --> 00:37:44,070
+الجديدشوفتوا كيف هذه العملية كلها اذا عمليات قصة
+
+423
+00:37:44,070 --> 00:37:49,010
+الشعر هذه عمليات ايش مالها كيميائية الان هذا تطبيق
+
+424
+00:37:49,010 --> 00:37:54,590
+Biology بس انا بهمش لو سمحتوا خلال دقيقتين هحكيلكم
+
+425
+00:37:54,590 --> 00:38:00,070
+على تطبيق اهم كتير منه كمان يعني هذا تطبيق ترفي
+
+426
+00:38:00,070 --> 00:38:04,770
+لكن في تطبيق في الحياة و بالذات بعض الناس منكم
+
+427
+00:38:04,770 --> 00:38:09,790
+يمكن يتخصصوا في البصريات الطبيةتطبيق كتير مهم
+
+428
+00:38:09,790 --> 00:38:19,290
+بتعرفوا الخشب اللي موجود اليوم ال MDF وغيره لو كان
+
+429
+00:38:19,290 --> 00:38:22,650
+محطوط على الأرض و بيصير أحيانا رطوبة في الأرض و
+
+430
+00:38:22,650 --> 00:38:28,070
+بتشطفه اشي زي هيك شو بيصيله؟ بينفش عارفين هذه
+
+431
+00:38:28,070 --> 00:38:32,350
+الشغلة؟ يعني انه بيكون عندكم الخشبة كأنها طبقات زي
+
+432
+00:38:32,350 --> 00:38:35,810
+هيك مع الرطوبة كيف بتصير؟
+
+433
+00:38:38,140 --> 00:38:43,600
+بتنفش، هذه الفكرة عارفينها؟ كويس، الآن في فكرة
+
+434
+00:38:43,600 --> 00:38:47,960
+موازية لها، في فكرة موازية لها تماما، انه احنا
+
+435
+00:38:47,960 --> 00:38:54,350
+عندنا في القرنية تبعت العلم، هذه تحدوبهايعني كما
+
+436
+00:38:54,350 --> 00:38:59,790
+قال الله تعالى وكل شي عنده بمقدار مش المفروض يختل
+
+437
+00:38:59,790 --> 00:39:04,090
+يعني اتخيلوها انتوا و الامر schematic و تفصيله عند
+
+438
+00:39:04,090 --> 00:39:08,510
+الإخوة التعون البصرية تتخيلوها مثلا بهذا الشكل
+
+439
+00:39:08,510 --> 00:39:13,870
+الآن هذا التحدب خلاص لازم نظلنا ايش احنا ملتزمين
+
+440
+00:39:13,870 --> 00:39:19,800
+فيه هذا في عند انا disulfide bondsيعني أس .. أس ..
+
+441
+00:39:19,800 --> 00:39:26,420
+أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس
+
+442
+00:39:26,420 --> 00:39:26,820
+أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس
+
+443
+00:39:26,820 --> 00:39:29,340
+.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس ..
+
+444
+00:39:29,340 --> 00:39:29,920
+أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس
+
+445
+00:39:29,920 --> 00:39:32,400
+.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس ..
+
+446
+00:39:32,400 --> 00:39:33,340
+أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس
+
+447
+00:39:33,340 --> 00:39:33,680
+.. أس .. أس .. أس .. أس .. أس .. أس .. أس .. أس ..
+
+448
+00:39:33,680 --> 00:39:44,760
+أس .. أس .. أس .. أس
+
+449
+00:39:44,760 --> 00:39:52,110
+..زي الخشب اللي نفش املاحظين؟ تماما، بهذه الحالة
+
+450
+00:39:52,110 --> 00:39:56,150
+صارت مشكلة في الإبصار ولا لأ؟ صار مشكلة في الإبصار
+
+451
+00:39:56,150 --> 00:40:00,430
+طيب يا تورا لو بدنا نعالج هذه المشكلة في الإبصار،
+
+452
+00:40:00,430 --> 00:40:07,310
+شو بدنا نعمل؟ بمنطق الكيميا بدأ
+
+453
+00:40:07,310 --> 00:40:12,490
+أعمل أكسدةبدي أرجح هذه لهذه بدي أكوّن الـ
+
+454
+00:40:12,490 --> 00:40:17,450
+disulfide bonds ولذلك أنا لما بدي أعالج هاي حالة
+
+455
+00:40:17,450 --> 00:40:21,850
+المرض و هاي حالة السليم لما بدي أعالج المريض أرجعه
+
+456
+00:40:21,850 --> 00:40:26,990
+لسليم إيش بدي أعمل؟ Oxidation هذه من العمليات
+
+457
+00:40:26,990 --> 00:40:30,410
+الحديثة اللي تجرى و كمان تجرى في غزة غالبا بتاعة
+
+458
+00:40:30,410 --> 00:40:33,890
+اللي بيستعملوا ال ozone كعمل مؤكسد مع أشياء تقنية
+
+459
+00:40:33,890 --> 00:40:39,230
+كاملة بس الإنسان يكون فاهم إيشال general idea
+
+460
+00:40:39,230 --> 00:40:43,670
+الفكرة العامة الفكرة العامة انه داي سالفايد بتصير
+
+461
+00:40:43,670 --> 00:40:49,230
+ايش ثيول بطل الشكل المنتظم القرنية و ما إلى ذلك
+
+462
+00:40:49,230 --> 00:40:54,390
+لما ارد أعمل الأكسة ده بيرجع الثيول إلى داي
+
+463
+00:40:54,390 --> 00:40:59,830
+سالفايد رجعتهازي ما كانت، فالأفكار البسيطة اللي
+
+464
+00:40:59,830 --> 00:41:05,430
+أحيانا بتمر عليكم يعني ربما أول ما الإنسان بيشرح
+
+465
+00:41:05,430 --> 00:41:08,230
+لما تشوفوا كلمة آسيول
+
+466
+00:41:11,410 --> 00:41:16,530
+ثيول يصير داي سالفايد okay فكرة كيميا لكن الجميل
+
+467
+00:41:16,530 --> 00:41:21,210
+دائما بفكرة الكيميا انها بتتحول لفكرة ايش لفكرة
+
+468
+00:41:21,210 --> 00:41:27,970
+تطبيق ولا فكرة حياة بهيك بننهي chapter ال alcohols
+
+469
+00:41:27,970 --> 00:41:32,430
+ان شاء الله المرة القادمة بنبدأ في موضوع ال ethers
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..24512ba5f9584e23a80a691d856fcec6280af8bc
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/QEReWkHS3Uk_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4846, "start": 19.78, "end": 48.46, "text": "بسم الله الرحمن الرحيم المرة الماضية اتكلمنا على أكسدة الكحولات عرفنا ايش اللي بنقصده في الأكسدة تحويل ال OH إلى C double bond O من خلال فقط ذاتين هيدروجين ولذلك احنا قلنا ان ال primary alcohol بتأكسد و بصير ال aldehydes و ال secondary alcohol بتأكسد و بصير ال ketones", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 1975, 2655, 4117, 19528, 8315, 15844, 5551, 4117, 3794, 41891, 33251, 5016, 12610, 9307, 6225, 28480, 8315, 1975, 1829, 8592, 13672, 1829, 44945, 4587, 9381, 3215, 3224, 8978, 16247, 4117, 3794, 41891, 6055, 5016, 2407, 26895, 2423, 13931, 30731, 383, 3834, 6086, 422, 9154, 16490, 1211, 6027, 6156, 47432, 29910, 9307, 9957, 8032, 25708, 2288, 29245, 9957, 35525, 8848, 23275, 1975, 5016, 8315, 12174, 1211, 8315, 16472, 2423, 6194, 7658, 39894, 10721, 4117, 3794, 3215, 4032, 4724, 9381, 13546, 2423, 16798, 68, 3495, 14792, 4032, 2423, 11396, 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{"start": 25.62, "end": 26.72, "word": " عرفنا", "probability": 0.8839518229166666}, {"start": 26.72, "end": 26.9, "word": " ايش", "probability": 0.6261393229166666}, {"start": 26.9, "end": 27.06, "word": " اللي", "probability": 0.8974609375}, {"start": 27.06, "end": 27.64, "word": " بنقصده", "probability": 0.97841796875}, {"start": 27.64, "end": 27.76, "word": " في", "probability": 0.90771484375}, {"start": 27.76, "end": 28.44, "word": " الأكسدة", "probability": 0.983642578125}, {"start": 28.44, "end": 29.92, "word": " تحويل", "probability": 0.9437255859375}, {"start": 29.92, "end": 30.12, "word": " ال", "probability": 0.95751953125}, {"start": 30.12, "end": 30.6, "word": " OH", "probability": 0.55029296875}, {"start": 30.6, "end": 31.06, "word": " إلى", "probability": 0.755859375}, {"start": 31.06, "end": 31.8, "word": " C", "probability": 0.55810546875}, {"start": 31.8, "end": 31.98, "word": " double", "probability": 0.64501953125}, {"start": 31.98, "end": 32.5, "word": " bond", 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انهم", "probability": 0.4560546875}, {"start": 52.38, "end": 53.22, "word": " يتأكسدوا", "probability": 0.8646763392857143}, {"start": 53.22, "end": 54.38, "word": " ربما", "probability": 0.9775390625}, {"start": 54.38, "end": 54.82, "word": " ضالت", "probability": 0.7736002604166666}, {"start": 54.82, "end": 55.16, "word": " شغلة", "probability": 0.90478515625}, {"start": 55.16, "end": 55.54, "word": " صغيرة", "probability": 0.9931640625}, {"start": 55.54, "end": 55.76, "word": " ان", "probability": 0.630859375}, {"start": 55.76, "end": 56.46, "word": " نحكي", "probability": 0.84405517578125}, {"start": 56.46, "end": 56.64, "word": " شو", "probability": 0.80810546875}, {"start": 56.64, "end": 56.76, "word": " هو", "probability": 0.62939453125}, {"start": 56.76, "end": 57.36, "word": " العامل", "probability": 0.9910481770833334}, {"start": 57.36, "end": 58.34, "word": " المؤكسد", "probability": 0.919140625}, {"start": 58.34, "end": 58.48, "word": " اللي", "probability": 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search مثلا اكتبوا antioxidant بتلاقوه بيكمل الكوفينول و آلاف الأبحاث و المواد بعضها طبيعي و بعضها صناعي يعني مثلا هذا vitamin E لاحظوا فيه هنا مجموعة الفينول ولا لأ", "tokens": [40228, 22653, 45164, 39894, 30544, 6055, 49628, 12984, 14407, 8978, 20742, 3164, 50113, 15040, 1975, 4117, 2655, 3555, 14407, 33369, 394, 39894, 15040, 4587, 2407, 3224, 4724, 1829, 24793, 1211, 33251, 38688, 9957, 12610, 4032, 19753, 15040, 5172, 16247, 49628, 5718, 104, 4032, 9673, 14407, 3215, 45030, 11242, 11296, 23032, 21292, 3615, 1829, 4032, 45030, 11242, 11296, 20328, 8315, 3615, 1829, 37495, 22653, 50113, 15040, 23758, 17163, 462, 20193, 5016, 19913, 14407, 8978, 3224, 34105, 3714, 7435, 2304, 2407, 27884, 27188, 9957, 12610, 49429, 5296, 10721], "avg_logprob": -0.17708333675888763, "compression_ratio": 1.6515151515151516, "no_speech_prob": 0.0, "words": [{"start": 1295.07, "end": 1295.35, "word": "يعني", "probability": 0.681884765625}, {"start": 1295.35, "end": 1295.59, "word": " لو", "probability": 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new file mode 100644
index 0000000000000000000000000000000000000000..35d1952504d76508b27c9af3437cc98bdbdbcfd4
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/RrfAVHquALA_raw.json
@@ -0,0 +1 @@
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ال common name تبعه ايش salicylic acid الان هذا فيه OH اللي هي تعتبر الكهور من ناحية المبدأ هذا ال OH لما اتهاجل على ال acid anhydride عادة بيفعله مع ال acetic anhydride فهتكسر من هنا الحامض", "tokens": [3224, 15730, 2423, 1315, 1975, 1829, 37746, 4117, 2423, 7649, 45164, 47525, 24793, 2423, 2689, 1315, 6055, 3555, 3615, 3224, 1975, 1829, 8592, 1845, 2632, 1050, 8258, 2423, 7649, 23758, 8978, 3224, 13931, 13672, 1829, 39896, 6055, 34268, 26890, 33251, 3224, 13063, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 23758, 2423, 13931, 5296, 15042, 1975, 47395, 26108, 1211, 15844, 2423, 8258, 18931, 6655, 25502, 6225, 18513, 3660, 4724, 33911, 30241, 3224, 20449, 2423, 696, 3532, 18931, 6655, 25502, 6156, 3224, 2655, 4117, 3794, 2288, 9154, 34105, 21542, 10943, 11242], "avg_logprob": -0.2878472199042638, "compression_ratio": 1.642512077294686, "no_speech_prob": 0.0, "words": [{"start": 176.36, "end": 176.82, "word": "هذا", "probability": 0.940673828125}, {"start": 176.82, "end": 177.08, 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بس بيحاولوا يخففوا من مشاكل تأثيره على المعدة من خلال أنه بيكون مخلوط بنظام ال buffer هو مشكلة الأسبيرين حقيقة أنه الجزء الفعال فيه اللي هو ال salicylic acid نفسه لكن ال salicylic acid نفسه يعني شديد على المعدة", "tokens": [1211, 10721, 31439, 4724, 3794, 4724, 1829, 5016, 995, 12610, 14407, 7251, 9778, 5172, 5172, 14407, 9154, 37893, 995, 28820, 6055, 10721, 12984, 13546, 3224, 15844, 9673, 22488, 3660, 9154, 16490, 1211, 6027, 14739, 3224, 4724, 1829, 30544, 3714, 9778, 1211, 2407, 9566, 44945, 19913, 10943, 2423, 21762, 31439, 37893, 28820, 3660, 16247, 35457, 13546, 9957, 11331, 38436, 28671, 14739, 3224, 25724, 11622, 38207, 27188, 3615, 6027, 8978, 3224, 13672, 1829, 31439, 2423, 1845, 2632, 1050, 8258, 8717, 36178, 3224, 44381, 2423, 1845, 2632, 1050, 8258, 8717, 36178, 3224, 37495, 22653, 13412, 16254, 3215, 15844, 9673, 22488, 3660], "avg_logprob": -0.10314078343034995, "compression_ratio": 1.7647058823529411, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 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بـ Carbon و بـ Carbon و هنا الطبيعة الحالي بـ Carbon هتكون ايش؟ Tertiary بناء على ذلك الأمد بيصير تلت أنواع", "tokens": [2407, 6027, 39184, 37942, 7747, 45164, 25961, 2655, 44650, 36520, 3660, 4724, 39184, 497, 4032, 4724, 39184, 497, 4386, 4724, 39184, 31453, 4032, 4724, 39184, 31453, 4032, 34105, 41950, 21292, 27884, 21542, 6027, 1829, 4724, 39184, 31453, 8032, 2655, 30544, 1975, 1829, 8592, 22807, 6564, 7317, 822, 44945, 16606, 15844, 29910, 23275, 16247, 2304, 3215, 4724, 1829, 9381, 13546, 6055, 1211, 2655, 14739, 14407, 3615], "avg_logprob": -0.26065340547850635, "compression_ratio": 1.391566265060241, "no_speech_prob": 0.0, "words": [{"start": 495.85, "end": 496.41, "word": "والـ", "probability": 0.6417643229166666}, {"start": 496.41, "end": 496.99, "word": " Nitrogen", "probability": 0.646240234375}, {"start": 496.99, "end": 497.45, "word": " لو", "probability": 0.9775390625}, {"start": 497.45, "end": 497.87, "word": " كانت", "probability": 0.971923828125}, {"start": 497.87, "end": 498.53, "word": " متصلة", "probability": 0.9033203125}, {"start": 498.53, "end": 498.87, "word": " بـ", "probability": 0.72314453125}, {"start": 498.87, "end": 499.29, "word": " R", "probability": 0.5341796875}, {"start": 499.29, "end": 499.89, "word": " و", "probability": 0.61767578125}, {"start": 499.89, "end": 500.21, "word": " بـ", "probability": 0.760498046875}, {"start": 500.21, "end": 500.63, "word": " R", "probability": 0.84716796875}, {"start": 500.63, "end": 500.93, "word": " ..", "probability": 0.258056640625}, {"start": 500.93, "end": 501.21, "word": " بـ", "probability": 0.7138671875}, {"start": 501.21, "end": 502.57, "word": " Carbon", "probability": 0.7529296875}, {"start": 502.57, "end": 502.87, "word": " و", "probability": 0.79931640625}, {"start": 502.87, "end": 503.09, "word": " بـ", "probability": 0.79833984375}, {"start": 503.09, "end": 503.55, "word": " Carbon", "probability": 0.94384765625}, {"start": 503.55, "end": 503.83, "word": " و", "probability": 0.51318359375}, {"start": 503.83, "end": 504.03, "word": " هنا", "probability": 0.53076171875}, {"start": 504.03, "end": 504.55, "word": " الطبيعة", "probability": 0.93603515625}, {"start": 504.55, "end": 504.95, "word": " الحالي", "probability": 0.81298828125}, {"start": 504.95, "end": 505.13, "word": " بـ", "probability": 0.85498046875}, {"start": 505.13, "end": 505.47, "word": " Carbon", "probability": 0.9228515625}, {"start": 505.47, "end": 506.17, "word": " هتكون", "probability": 0.8790690104166666}, {"start": 506.17, "end": 506.83, "word": " ايش؟", "probability": 0.7850341796875}, {"start": 506.83, "end": 507.51, "word": " Tertiary", "probability": 0.6359049479166666}, {"start": 507.51, "end": 508.21, "word": " بناء", "probability": 0.778564453125}, {"start": 508.21, "end": 508.49, "word": " على", "probability": 0.7138671875}, {"start": 508.49, "end": 509.07, "word": " ذلك", "probability": 0.992919921875}, {"start": 509.07, "end": 509.89, "word": " الأمد", "probability": 0.7555338541666666}, {"start": 509.89, "end": 510.47, "word": " بيصير", "probability": 0.942138671875}, {"start": 510.47, "end": 511.05, "word": " تلت", "probability": 0.794921875}, {"start": 511.05, "end": 511.67, "word": " أنواع", "probability": 0.93798828125}], "temperature": 1.0}, {"id": 23, "seek": 53989, "start": 512.49, "end": 539.89, "text": "والأمد بيصير تعريفه العام C double bond O متصلة بإيش؟ بنيتروجين هالنيتروجين هذه تكون NH2 primary أمد NHR secondary أمد NR2 tertiary أمد واضح هذه الفكرة؟ الآن هذه الفكرة طالما احنا وقفنا عندها هتجيبنا لنقطة كتير مهمة", "tokens": [2407, 6027, 10721, 2304, 3215, 4724, 1829, 9381, 13546, 37279, 16572, 5172, 3224, 18863, 10943, 383, 3834, 6086, 422, 44650, 36520, 3660, 4724, 28814, 1829, 8592, 22807, 44945, 36081, 2288, 29245, 9957, 8032, 6027, 22653, 2655, 2288, 29245, 9957, 29538, 6055, 30544, 31118, 17, 6194, 5551, 2304, 3215, 31118, 49, 11396, 5551, 2304, 3215, 38399, 17, 38726, 29104, 5551, 2304, 3215, 4032, 46958, 5016, 29538, 27188, 4117, 25720, 22807, 6024, 48506, 29538, 27188, 4117, 25720, 23032, 6027, 15042, 1975, 5016, 8315, 4032, 4587, 5172, 8315, 43242, 11296, 8032, 2655, 7435, 1829, 3555, 8315, 5296, 1863, 47432, 3660, 9122, 2655, 13546, 3714, 16095, 3660], "avg_logprob": -0.24338941992475435, "compression_ratio": 1.5936073059360731, "no_speech_prob": 0.0, "words": [{"start": 512.49, "end": 513.19, "word": "والأمد", "probability": 0.719677734375}, {"start": 513.19, "end": 513.91, "word": " بيصير", "probability": 0.8560791015625}, {"start": 513.91, "end": 514.53, "word": " تعريفه", "probability": 0.9832763671875}, {"start": 514.53, "end": 515.03, "word": " العام", "probability": 0.88427734375}, {"start": 515.03, "end": 515.75, "word": " C", "probability": 0.5615234375}, {"start": 515.75, "end": 516.15, "word": " double", "probability": 0.2489013671875}, {"start": 516.15, "end": 516.63, "word": " bond", "probability": 0.9267578125}, {"start": 516.63, "end": 517.17, "word": " O", "probability": 0.81787109375}, {"start": 517.17, "end": 518.09, "word": " متصلة", "probability": 0.5978190104166666}, {"start": 518.09, "end": 518.69, "word": " بإيش؟", "probability": 0.75068359375}, {"start": 518.69, "end": 520.17, "word": " بنيتروجين", "probability": 0.7569580078125}, {"start": 520.17, "end": 521.19, "word": " هالنيتروجين", "probability": 0.7462855747767857}, {"start": 521.19, "end": 521.47, "word": " هذه", "probability": 0.368408203125}, {"start": 521.47, "end": 522.19, "word": " تكون", "probability": 0.871826171875}, {"start": 522.19, "end": 523.11, "word": " NH2", "probability": 0.77001953125}, {"start": 523.11, "end": 524.53, "word": " primary", "probability": 0.6767578125}, {"start": 524.53, "end": 524.93, "word": " أمد", "probability": 0.8046061197916666}, {"start": 524.93, "end": 526.13, "word": " NHR", "probability": 0.716064453125}, {"start": 526.13, "end": 527.35, "word": " secondary", "probability": 0.179931640625}, {"start": 527.35, "end": 527.69, "word": " أمد", "probability": 0.9137369791666666}, {"start": 527.69, "end": 528.87, "word": " NR2", "probability": 0.6392822265625}, {"start": 528.87, "end": 530.03, "word": " tertiary", "probability": 0.948974609375}, {"start": 530.03, "end": 530.65, "word": " أمد", "probability": 0.9404296875}, {"start": 530.65, "end": 530.93, "word": " واضح", "probability": 0.96728515625}, {"start": 530.93, "end": 531.15, "word": " هذه", "probability": 0.296875}, {"start": 531.15, "end": 532.97, "word": " الفكرة؟", "probability": 0.9107666015625}, {"start": 532.97, "end": 533.43, "word": " الآن", "probability": 0.7626953125}, {"start": 533.43, "end": 534.11, "word": " هذه", "probability": 0.87890625}, {"start": 534.11, "end": 534.63, "word": " الفكرة", "probability": 0.9954427083333334}, {"start": 534.63, "end": 535.13, "word": " طالما", "probability": 0.9840494791666666}, {"start": 535.13, "end": 535.63, "word": " احنا", "probability": 0.83642578125}, {"start": 535.63, "end": 536.07, "word": " وقفنا", "probability": 0.95703125}, {"start": 536.07, "end": 536.71, "word": " عندها", "probability": 0.9970703125}, {"start": 536.71, "end": 538.41, "word": " هتجيبنا", "probability": 0.9032389322916666}, {"start": 538.41, "end": 538.97, "word": " لنقطة", "probability": 0.961181640625}, {"start": 538.97, "end": 539.29, "word": " كتير", "probability": 0.9381510416666666}, {"start": 539.29, "end": 539.89, "word": " مهمة", "probability": 0.9951171875}], "temperature": 1.0}, {"id": 24, "seek": 56779, "start": 541.11, "end": 567.79, "text": "العمل ممكن يعمل hydrogen bonding وممكن مايعملش وممكن يعمل بشكل كبير وممكن يعمل بشكل اقل عارفين انتوا ال hydrogen bonding بيصير لما يكون عندى hydrogen متطابط يا بنيتروجين يا باكسوجين يا بفلورين الان لو اجيت على المركب اللى هو ال primary amine فيه MH", "tokens": [6027, 25957, 1211, 3714, 43020, 7251, 25957, 1211, 12697, 28824, 4032, 2304, 43020, 19446, 1829, 25957, 1211, 8592, 4032, 2304, 43020, 7251, 25957, 1211, 4724, 8592, 28820, 9122, 3555, 13546, 4032, 2304, 43020, 7251, 25957, 1211, 4724, 8592, 28820, 1975, 4587, 1211, 6225, 9640, 5172, 9957, 16472, 2655, 14407, 2423, 12697, 28824, 4724, 1829, 9381, 13546, 5296, 15042, 7251, 30544, 43242, 7578, 12697, 44650, 9566, 16758, 9566, 35186, 44945, 36081, 2288, 29245, 9957, 35186, 4724, 995, 4117, 3794, 29245, 9957, 35186, 4724, 5172, 1211, 13063, 9957, 2423, 7649, 45164, 1975, 7435, 36081, 15844, 9673, 31747, 3555, 13672, 7578, 31439, 2423, 6194, 669, 533, 8978, 3224, 34796], "avg_logprob": -0.2521904350441193, "compression_ratio": 1.9371980676328502, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 541.11, "end": 542.11, "word": "العمل", "probability": 0.6084798177083334}, {"start": 542.11, "end": 543.11, "word": " ممكن", "probability": 0.7283935546875}, {"start": 543.11, "end": 543.81, "word": " يعمل", "probability": 0.9749348958333334}, {"start": 543.81, "end": 544.89, "word": " hydrogen", "probability": 0.12384033203125}, {"start": 544.89, "end": 545.55, "word": " bonding", "probability": 0.92431640625}, {"start": 545.55, "end": 546.69, "word": " وممكن", "probability": 0.7965494791666666}, {"start": 546.69, "end": 548.87, "word": " مايعملش", "probability": 0.723828125}, {"start": 548.87, "end": 549.25, "word": " وممكن", "probability": 0.7495930989583334}, {"start": 549.25, "end": 549.59, "word": " يعمل", "probability": 0.9523111979166666}, {"start": 549.59, "end": 550.01, "word": " بشكل", "probability": 0.98046875}, {"start": 550.01, "end": 550.51, "word": " كبير", "probability": 0.9921875}, {"start": 550.51, "end": 551.21, "word": " وممكن", "probability": 0.93798828125}, {"start": 551.21, "end": 551.53, "word": " يعمل", "probability": 0.9724934895833334}, {"start": 551.53, "end": 551.93, "word": " بشكل", "probability": 0.9856770833333334}, {"start": 551.93, "end": 552.27, "word": " اقل", "probability": 0.7964680989583334}, {"start": 552.27, "end": 552.73, "word": " عارفين", "probability": 0.913330078125}, {"start": 552.73, "end": 552.97, "word": " انتوا", "probability": 0.7685546875}, {"start": 552.97, "end": 553.05, "word": " ال", "probability": 0.873046875}, {"start": 553.05, "end": 553.41, "word": " hydrogen", "probability": 0.74951171875}, {"start": 553.41, "end": 553.83, "word": " bonding", "probability": 0.95263671875}, {"start": 553.83, "end": 554.43, "word": " بيصير", "probability": 0.9171142578125}, {"start": 554.43, "end": 554.95, "word": " لما", "probability": 0.935302734375}, {"start": 554.95, "end": 555.19, "word": " يكون", "probability": 0.98046875}, {"start": 555.19, "end": 555.47, "word": " عندى", "probability": 0.823486328125}, {"start": 555.47, "end": 555.99, "word": " hydrogen", "probability": 0.6396484375}, {"start": 555.99, "end": 556.85, "word": " متطابط", "probability": 0.65985107421875}, {"start": 556.85, "end": 557.59, "word": " يا", "probability": 0.50341796875}, {"start": 557.59, "end": 558.37, "word": " بنيتروجين", "probability": 0.74775390625}, {"start": 558.37, "end": 558.55, "word": " يا", "probability": 0.80126953125}, {"start": 558.55, "end": 559.17, "word": " باكسوجين", "probability": 0.7635091145833334}, {"start": 559.17, "end": 559.45, "word": " يا", "probability": 0.9091796875}, {"start": 559.45, "end": 560.13, "word": " بفلورين", "probability": 0.96943359375}, {"start": 560.13, "end": 561.05, "word": " الان", "probability": 0.69775390625}, {"start": 561.05, "end": 561.49, "word": " لو", "probability": 0.9814453125}, {"start": 561.49, "end": 561.99, "word": " اجيت", "probability": 0.8299153645833334}, {"start": 561.99, "end": 562.37, "word": " على", "probability": 0.81494140625}, {"start": 562.37, "end": 563.73, "word": " المركب", "probability": 0.9254557291666666}, {"start": 563.73, "end": 563.87, "word": " اللى", "probability": 0.862548828125}, {"start": 563.87, "end": 564.05, "word": " هو", "probability": 0.89404296875}, {"start": 564.05, "end": 564.23, "word": " ال", "probability": 0.9453125}, {"start": 564.23, "end": 564.97, "word": " primary", "probability": 0.90234375}, {"start": 564.97, "end": 565.57, "word": " amine", "probability": 0.4388427734375}, {"start": 565.57, "end": 567.41, "word": " فيه", "probability": 0.649658203125}, {"start": 567.41, "end": 567.79, "word": " MH", "probability": 0.417236328125}], "temperature": 1.0}, {"id": 25, "seek": 59349, "start": 569.61, "end": 593.49, "text": "و تنتين مش واحدة تمام اذا ال primary amide ممكن يعمل hydrogen bonding ولا لأ و ممكن يعمل كام hydrogen bonding طالما فيه تنتين hydrogen ممكن يعمل two hydrogen bonding الان لو اجيت على ال secondary amide في كام هيدروجينة", "tokens": [2407, 6055, 29399, 9957, 37893, 36764, 24401, 3660, 46811, 10943, 1975, 15730, 2423, 6194, 669, 482, 3714, 43020, 7251, 25957, 1211, 12697, 28824, 49429, 5296, 10721, 4032, 3714, 43020, 7251, 25957, 1211, 9122, 10943, 12697, 28824, 23032, 6027, 15042, 8978, 3224, 6055, 29399, 9957, 12697, 3714, 43020, 7251, 25957, 1211, 732, 12697, 28824, 2423, 7649, 45164, 1975, 7435, 36081, 15844, 2423, 11396, 669, 482, 8978, 9122, 10943, 8032, 25708, 2288, 29245, 9957, 3660], "avg_logprob": -0.21072635598279335, "compression_ratio": 1.7796610169491525, "no_speech_prob": 0.0, "words": [{"start": 569.61, "end": 569.97, "word": "و", "probability": 0.53369140625}, {"start": 569.97, "end": 570.73, "word": " تنتين", "probability": 0.706787109375}, {"start": 570.73, "end": 570.95, "word": " مش", "probability": 0.55615234375}, {"start": 570.95, "end": 571.51, "word": " واحدة", "probability": 0.9397786458333334}, {"start": 571.51, "end": 572.41, "word": " تمام", "probability": 0.6875}, {"start": 572.41, "end": 573.15, "word": " اذا", "probability": 0.59442138671875}, {"start": 573.15, "end": 573.63, "word": " ال", "probability": 0.9345703125}, {"start": 573.63, "end": 574.27, "word": " primary", "probability": 0.82470703125}, {"start": 574.27, "end": 574.69, "word": " amide", "probability": 0.681640625}, {"start": 574.69, "end": 575.15, "word": " ممكن", "probability": 0.97216796875}, {"start": 575.15, "end": 575.77, "word": " يعمل", "probability": 0.9724934895833334}, {"start": 575.77, "end": 576.35, "word": " hydrogen", "probability": 0.84423828125}, {"start": 576.35, "end": 576.89, "word": " bonding", "probability": 0.95849609375}, {"start": 576.89, "end": 577.15, "word": " ولا", "probability": 0.7177734375}, {"start": 577.15, "end": 577.59, "word": " لأ", "probability": 0.84033203125}, {"start": 577.59, "end": 578.35, "word": " و", "probability": 0.43798828125}, {"start": 578.35, "end": 578.69, "word": " ممكن", "probability": 0.827392578125}, {"start": 578.69, "end": 579.07, "word": " يعمل", "probability": 0.9903971354166666}, {"start": 579.07, "end": 579.35, "word": " كام", "probability": 0.825927734375}, {"start": 579.35, "end": 579.87, "word": " hydrogen", "probability": 0.896484375}, {"start": 579.87, "end": 580.43, "word": " bonding", "probability": 0.96630859375}, {"start": 580.43, "end": 581.43, "word": " طالما", "probability": 0.96533203125}, {"start": 581.43, "end": 581.71, "word": " فيه", "probability": 0.6116943359375}, {"start": 581.71, "end": 582.11, "word": " تنتين", "probability": 0.98779296875}, {"start": 582.11, "end": 582.63, "word": " hydrogen", "probability": 0.6708984375}, {"start": 582.63, "end": 583.47, "word": " ممكن", "probability": 0.940185546875}, {"start": 583.47, "end": 583.85, "word": " يعمل", "probability": 0.9930013020833334}, {"start": 583.85, "end": 584.09, "word": " two", "probability": 0.8525390625}, {"start": 584.09, "end": 584.73, "word": " hydrogen", "probability": 0.94970703125}, {"start": 584.73, "end": 585.37, "word": " bonding", "probability": 0.96435546875}, {"start": 585.37, "end": 587.73, "word": " الان", "probability": 0.6328125}, {"start": 587.73, "end": 588.17, "word": " لو", "probability": 0.97705078125}, {"start": 588.17, "end": 588.59, "word": " اجيت", "probability": 0.8439127604166666}, {"start": 588.59, "end": 588.93, "word": " على", "probability": 0.8408203125}, {"start": 588.93, "end": 589.31, "word": " ال", "probability": 0.7880859375}, {"start": 589.31, "end": 589.95, "word": " secondary", "probability": 0.90185546875}, {"start": 589.95, "end": 590.65, "word": " amide", "probability": 0.935546875}, {"start": 590.65, "end": 592.23, "word": " في", "probability": 0.78466796875}, {"start": 592.23, "end": 592.55, "word": " كام", "probability": 0.938720703125}, {"start": 592.55, "end": 593.49, "word": " هيدروجينة", "probability": 0.8828125}], "temperature": 1.0}, {"id": 26, "seek": 61791, "start": 594.27, "end": 617.91, "text": "وحدة إذا ممكن يعمل one hydrogen bonding لو إجيت على ال tertiary amide مش فيه hydrogen إذا بيعملش hydrogen bonding واضحة الفكرة إذا لو أنا بدي أجي أشوف ال amides من ناحية ال hydrogen bonding مين أكثر واحد بيعمل hydrogen bonding بعده", "tokens": [2407, 24401, 3660, 11933, 15730, 3714, 43020, 7251, 25957, 1211, 472, 12697, 28824, 45164, 11933, 7435, 36081, 15844, 2423, 38726, 29104, 669, 482, 37893, 8978, 3224, 12697, 11933, 15730, 4724, 1829, 25957, 1211, 8592, 12697, 28824, 4032, 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"word": " لو", "probability": 0.72802734375}, {"start": 599.31, "end": 599.83, "word": " إجيت", "probability": 0.7610677083333334}, {"start": 599.83, "end": 600.27, "word": " على", "probability": 0.91015625}, {"start": 600.27, "end": 601.03, "word": " ال", "probability": 0.70703125}, {"start": 601.03, "end": 601.79, "word": " tertiary", "probability": 0.91552734375}, {"start": 601.79, "end": 602.35, "word": " amide", "probability": 0.806396484375}, {"start": 602.35, "end": 603.19, "word": " مش", "probability": 0.50439453125}, {"start": 603.19, "end": 603.43, "word": " فيه", "probability": 0.916015625}, {"start": 603.43, "end": 603.97, "word": " hydrogen", "probability": 0.8271484375}, {"start": 603.97, "end": 604.59, "word": " إذا", "probability": 0.88623046875}, {"start": 604.59, "end": 605.27, "word": " بيعملش", "probability": 0.9162109375}, {"start": 605.27, "end": 605.75, "word": " hydrogen", "probability": 0.83740234375}, {"start": 605.75, "end": 606.51, "word": " bonding", "probability": 0.96337890625}, {"start": 606.51, "end": 607.29, "word": " واضحة", "probability": 0.8355712890625}, {"start": 607.29, "end": 607.69, "word": " الفكرة", "probability": 0.99267578125}, {"start": 607.69, "end": 608.45, "word": " إذا", "probability": 0.7054443359375}, {"start": 608.45, "end": 608.85, "word": " لو", "probability": 0.9697265625}, {"start": 608.85, "end": 609.03, "word": " أنا", "probability": 0.7900390625}, {"start": 609.03, "end": 609.25, "word": " بدي", "probability": 0.68603515625}, {"start": 609.25, "end": 609.49, "word": " أجي", "probability": 0.8492838541666666}, {"start": 609.49, "end": 609.85, "word": " أشوف", "probability": 0.9744466145833334}, {"start": 609.85, "end": 610.05, "word": " ال", "probability": 0.978515625}, {"start": 610.05, "end": 610.49, "word": " amides", "probability": 0.861572265625}, {"start": 610.49, "end": 610.65, "word": " من", "probability": 0.9892578125}, {"start": 610.65, "end": 610.95, "word": " ناحية", "probability": 0.9851888020833334}, {"start": 610.95, "end": 611.07, "word": " ال", "probability": 0.96435546875}, {"start": 611.07, "end": 611.45, "word": " hydrogen", "probability": 0.93408203125}, {"start": 611.45, "end": 612.05, "word": " bonding", "probability": 0.9501953125}, {"start": 612.05, "end": 612.71, "word": " مين", "probability": 0.880615234375}, {"start": 612.71, "end": 613.23, "word": " أكثر", "probability": 0.8336588541666666}, {"start": 613.23, "end": 613.67, "word": " واحد", "probability": 0.98388671875}, {"start": 613.67, "end": 614.45, "word": " بيعمل", "probability": 0.980224609375}, {"start": 614.45, "end": 615.37, "word": " hydrogen", "probability": 0.9619140625}, {"start": 615.37, "end": 616.13, "word": " bonding", "probability": 0.95703125}, {"start": 616.13, "end": 617.91, "word": " بعده", "probability": 0.55267333984375}], "temperature": 1.0}, {"id": 27, "seek": 64419, "start": 618.45, "end": 644.19, "text": "بعده tertiary ع طول مباشرة ال hydrogen bonding بنعكس على أي خاصية على ال boiling point بناء على ذلك لما انا بدي اجي احكي عن ال boiling point مين هيكون اعلى boiling point ال primary اعلى من ال secondary اعلى من ال tertiary", "tokens": [3555, 22488, 3224, 38726, 29104, 6225, 23032, 12610, 3714, 3555, 33599, 25720, 2423, 12697, 28824, 44945, 3615, 4117, 3794, 15844, 36632, 16490, 33546, 10632, 15844, 2423, 16208, 935, 44945, 16606, 15844, 29910, 23275, 5296, 15042, 1975, 8315, 4724, 16254, 1975, 7435, 1829, 1975, 5016, 4117, 1829, 18871, 2423, 16208, 935, 3714, 9957, 39896, 30544, 1975, 3615, 23942, 16208, 935, 2423, 6194, 1975, 3615, 23942, 9154, 2423, 11396, 1975, 3615, 23942, 9154, 2423, 38726, 29104], "avg_logprob": -0.170625003973643, "compression_ratio": 1.7135135135135136, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 618.45, "end": 619.65, "word": "بعده", "probability": 0.7799479166666666}, {"start": 619.65, "end": 621.03, "word": " tertiary", "probability": 0.6678466796875}, {"start": 621.03, "end": 621.51, "word": " ع", 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{"start": 628.05, "end": 628.81, "word": " point", "probability": 0.982421875}, {"start": 628.81, "end": 629.65, "word": " بناء", "probability": 0.891845703125}, {"start": 629.65, "end": 629.97, "word": " على", "probability": 0.8154296875}, {"start": 629.97, "end": 630.55, "word": " ذلك", "probability": 0.99365234375}, {"start": 630.55, "end": 631.05, "word": " لما", "probability": 0.868408203125}, {"start": 631.05, "end": 631.25, "word": " انا", "probability": 0.730712890625}, {"start": 631.25, "end": 631.47, "word": " بدي", "probability": 0.6337890625}, {"start": 631.47, "end": 631.71, "word": " اجي", "probability": 0.7745768229166666}, {"start": 631.71, "end": 632.09, "word": " احكي", "probability": 0.9580078125}, {"start": 632.09, "end": 632.25, "word": " عن", "probability": 0.97119140625}, {"start": 632.25, "end": 632.39, "word": " ال", "probability": 0.951171875}, {"start": 632.39, "end": 632.81, "word": " boiling", "probability": 0.9560546875}, {"start": 632.81, "end": 633.59, "word": " point", "probability": 0.98583984375}, {"start": 633.59, "end": 634.33, "word": " مين", "probability": 0.937255859375}, {"start": 634.33, "end": 634.93, "word": " هيكون", "probability": 0.96923828125}, {"start": 634.93, "end": 635.35, "word": " اعلى", "probability": 0.93798828125}, {"start": 635.35, "end": 635.83, "word": " boiling", "probability": 0.90869140625}, {"start": 635.83, "end": 636.51, "word": " point", "probability": 0.98681640625}, {"start": 636.51, "end": 636.89, "word": " ال", "probability": 0.74755859375}, {"start": 636.89, "end": 638.11, "word": " primary", "probability": 0.89794921875}, {"start": 638.11, "end": 639.85, "word": " اعلى", "probability": 0.9441731770833334}, {"start": 639.85, "end": 640.65, "word": " من", "probability": 0.9873046875}, {"start": 640.65, "end": 640.87, "word": " ال", "probability": 0.908203125}, {"start": 640.87, "end": 641.53, "word": " secondary", "probability": 0.9169921875}, {"start": 641.53, "end": 642.21, "word": " اعلى", "probability": 0.9788411458333334}, {"start": 642.21, "end": 643.37, "word": " من", "probability": 0.99609375}, {"start": 643.37, "end": 643.57, "word": " ال", "probability": 0.697265625}, {"start": 643.57, "end": 644.19, "word": " tertiary", "probability": 0.968017578125}], "temperature": 1.0}, {"id": 28, "seek": 66913, "start": 645.01, "end": 669.13, "text": "الان لو قلنا لكوا ليش ال primary أعلى من ال secondary لأن ال primary فيه تنين هيدروجين bonding السكندرية واحدة ليش السكندرية أعلى من ال tertiary السكندرية فيه إمكانية لوان هيدروجين bonding الترتشيري مافيش فيه إمكانية للهيدروجين bonding فالأمر في ال boiling point ما بين ال primary والسكندرية والترتشيري", "tokens": [6027, 7649, 45164, 12174, 1211, 8315, 5296, 4117, 14407, 32239, 8592, 2423, 6194, 5551, 3615, 23942, 9154, 2423, 11396, 5296, 33456, 2423, 6194, 8978, 3224, 6055, 1863, 9957, 8032, 25708, 2288, 29245, 9957, 28824, 21136, 19452, 3215, 2288, 10632, 36764, 24401, 3660, 32239, 8592, 21136, 19452, 3215, 2288, 10632, 5551, 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bonding", "probability": 0.3603515625}, {"start": 652.11, "end": 652.97, "word": " السكندرية", "probability": 0.62626953125}, {"start": 652.97, "end": 653.45, "word": " واحدة", "probability": 0.8670247395833334}, {"start": 653.45, "end": 654.25, "word": " ليش", "probability": 0.836669921875}, {"start": 654.25, "end": 654.89, "word": " السكندرية", "probability": 0.89736328125}, {"start": 654.89, "end": 655.09, "word": " أعلى", "probability": 0.951171875}, {"start": 655.09, "end": 655.27, "word": " من", "probability": 0.994140625}, {"start": 655.27, "end": 655.43, "word": " ال", "probability": 0.5302734375}, {"start": 655.43, "end": 655.93, "word": " tertiary", "probability": 0.97705078125}, {"start": 655.93, "end": 657.23, "word": " السكندرية", "probability": 0.90966796875}, {"start": 657.23, "end": 657.71, "word": " فيه", "probability": 0.5595703125}, {"start": 657.71, "end": 658.17, "word": " إمكانية", "probability": 0.9354248046875}, {"start": 658.17, "end": 658.51, "word": " لوان", "probability": 0.3614908854166667}, {"start": 658.51, "end": 659.03, "word": " هيدروجين", "probability": 0.89765625}, {"start": 659.03, "end": 659.39, "word": " bonding", "probability": 0.96435546875}, {"start": 659.39, "end": 660.39, "word": " الترتشيري", "probability": 0.6940511067708334}, {"start": 660.39, "end": 661.19, "word": " مافيش", "probability": 0.9129231770833334}, {"start": 661.19, "end": 661.43, "word": " فيه", "probability": 0.890380859375}, {"start": 661.43, "end": 662.09, "word": " إمكانية", "probability": 0.981201171875}, {"start": 662.09, "end": 662.87, "word": " للهيدروجين", "probability": 0.9269205729166666}, {"start": 662.87, "end": 663.13, "word": " bonding", "probability": 0.98291015625}, {"start": 663.13, "end": 664.31, "word": " فالأمر", "probability": 0.902587890625}, {"start": 664.31, "end": 664.95, "word": " في", "probability": 0.94384765625}, {"start": 664.95, "end": 665.09, "word": " ال", "probability": 0.92529296875}, {"start": 665.09, "end": 665.45, "word": " boiling", "probability": 0.9365234375}, {"start": 665.45, "end": 665.89, "word": " point", "probability": 0.98388671875}, {"start": 665.89, "end": 666.11, "word": " ما", "probability": 0.89208984375}, {"start": 666.11, "end": 666.33, "word": " بين", "probability": 0.962890625}, {"start": 666.33, "end": 666.65, "word": " ال", "probability": 0.98095703125}, {"start": 666.65, "end": 667.29, "word": " primary", "probability": 0.9443359375}, {"start": 667.29, "end": 668.31, "word": " والسكندرية", "probability": 0.895263671875}, {"start": 668.31, "end": 669.13, "word": " والترتشيري", "probability": 0.7274983723958334}], "temperature": 1.0}, {"id": 29, "seek": 68421, "start": 670.47, "end": 684.21, "text": "هو إلى إمكانية تكوين الـ hydrogen bonding واضحة هذه الفكرة كتصنيف amides و كنقاط غليان لاحظوا هذه الفكرة نفسها موجودة هنا مثلا", "tokens": [3224, 2407, 30731, 11933, 2304, 41361, 10632, 6055, 4117, 2407, 9957, 2423, 39184, 12697, 28824, 4032, 46958, 5016, 3660, 29538, 27188, 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Formament", "tokens": [6027, 148, 48506, 12399, 45164, 39182, 4117, 11331, 42213, 2655, 14407, 50113, 1211, 3714, 7435, 2304, 45367, 9307, 12399, 6156, 3224, 1829, 6055, 9381, 49628, 11778, 16373, 46007, 8978, 2423, 39184, 10126, 2466], "avg_logprob": -0.5983455671983606, "compression_ratio": 1.1, "no_speech_prob": 0.0, "words": [{"start": 791.77, "end": 792.57, "word": "الآن،", "probability": 0.478363037109375}, {"start": 792.57, "end": 793.01, "word": " لو", "probability": 0.80615234375}, {"start": 793.01, "end": 793.61, "word": " بعدك", "probability": 0.74560546875}, {"start": 793.61, "end": 794.39, "word": " حملتوا", "probability": 0.715972900390625}, {"start": 794.39, "end": 794.79, "word": " مثل", "probability": 0.8525390625}, {"start": 794.79, "end": 795.93, "word": " مجموعات،", "probability": 0.6421101888020834}, {"start": 795.93, "end": 796.59, "word": " فهي", "probability": 0.4047037760416667}, {"start": 796.59, "end": 796.89, "word": " تصبح", "probability": 0.641357421875}, 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احنا قلنا تقريبا تلت اسابيع اربعة بس بندرس ال Carbonyl groups ال C double bond O في ال aldehydes في ال ketones في ال acids في ال E stars very reactive واضح؟", "tokens": [2407, 2741, 65, 2526, 75, 383, 3834, 6086, 422, 2423, 7649, 20193, 5016, 19913, 14407, 20449, 995, 25528, 28242, 36764, 24401, 3660, 9154, 16095, 9154, 5172, 2288, 41891, 588, 28897, 37495, 22653, 2423, 2741, 65, 2526, 75, 1594, 45164, 24401, 11296, 588, 28897, 4032, 1975, 5016, 8315, 12174, 1211, 8315, 6055, 4587, 16572, 3555, 995, 6055, 1211, 2655, 24525, 16758, 40228, 1975, 25513, 27884, 4724, 3794, 44945, 3215, 2288, 3794, 2423, 2741, 65, 2526, 75, 3935, 2423, 383, 3834, 6086, 422, 8978, 2423, 16798, 68, 3495, 14792, 8978, 2423, 14979, 2213, 8978, 2423, 21667, 8978, 2423, 462, 6105, 588, 28897, 4032, 46958, 5016, 22807], "avg_logprob": -0.2385416689373198, "compression_ratio": 1.7880184331797235, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1154.1, "end": 1154.32, "word": "و", "probability": 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double", "probability": 0.85009765625}, {"start": 1174.16, "end": 1174.5, "word": " bond", "probability": 0.96044921875}, {"start": 1174.5, "end": 1174.74, "word": " O", "probability": 0.9765625}, {"start": 1174.74, "end": 1174.9, "word": " في", "probability": 0.7705078125}, {"start": 1174.9, "end": 1174.98, "word": " ال", "probability": 0.919921875}, {"start": 1174.98, "end": 1175.72, "word": " aldehydes", "probability": 0.65228271484375}, {"start": 1175.72, "end": 1175.9, "word": " في", "probability": 0.7841796875}, {"start": 1175.9, "end": 1175.96, "word": " ال", "probability": 0.779296875}, {"start": 1175.96, "end": 1176.46, "word": " ketones", "probability": 0.77099609375}, {"start": 1176.46, "end": 1176.62, "word": " في", "probability": 0.9521484375}, {"start": 1176.62, "end": 1176.74, "word": " ال", "probability": 0.94921875}, {"start": 1176.74, "end": 1177.12, "word": " acids", "probability": 0.783203125}, {"start": 1177.12, "end": 1177.3, "word": " في", "probability": 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ال reactivity تفاعل مع الخارج تمام", "tokens": [409, 265, 12596, 44381, 13672, 1829, 4724, 33911, 16095, 32748, 22653, 995, 4724, 1829, 28543, 2288, 7251, 5172, 16095, 23758, 16247, 29973, 10874, 25708, 995, 13672, 1829, 4724, 33911, 16095, 32748, 22653, 995, 4724, 1829, 28543, 2288, 7251, 5172, 16095, 23758, 16247, 29973, 10874, 25708, 995, 2423, 4515, 4253, 2423, 4515, 4253, 20449, 8315, 11296, 6055, 5172, 995, 30241, 20449, 33962, 9640, 7435, 2423, 4515, 4253, 6055, 5172, 995, 30241, 20449, 33962, 9640, 7435, 46811, 10943], "avg_logprob": -0.10998376584672309, "compression_ratio": 2.3282442748091605, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1251.5900000000001, "end": 1252.91, "word": "unreactive", "probability": 0.7569986979166666}, {"start": 1252.91, "end": 1254.23, "word": " لكن", "probability": 0.58154296875}, {"start": 1254.23, "end": 1254.69, "word": " اللي", "probability": 0.916015625}, {"start": 1254.69, "end": 1255.31, "word": " بيفهم", "probability": 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"end": 1275.38, "word": " الأمة", "probability": 0.8818359375}, {"start": 1275.38, "end": 1276.42, "word": " العربية", "probability": 0.9793294270833334}, {"start": 1276.42, "end": 1276.56, "word": " ..", "probability": 0.443603515625}, {"start": 1276.56, "end": 1277.22, "word": " الأمة", "probability": 0.894287109375}, {"start": 1277.22, "end": 1278.12, "word": " العربية", "probability": 0.9903971354166666}, {"start": 1278.12, "end": 1278.82, "word": " كان", "probability": 0.9677734375}, {"start": 1278.82, "end": 1279.56, "word": " ممكن", "probability": 0.95751953125}, {"start": 1279.56, "end": 1280.1, "word": " تكون", "probability": 0.995849609375}, {"start": 1280.1, "end": 1280.9, "word": " reactive", "probability": 0.87060546875}, {"start": 1280.9, "end": 1281.76, "word": " بس", "probability": 0.823974609375}, {"start": 1281.76, "end": 1282.26, "word": " بشرط", "probability": 0.9119466145833334}, {"start": 1282.26, "end": 1282.94, "word": " reactive", "probability": 0.73193359375}, {"start": 1282.94, "end": 1283.34, "word": " ضد", "probability": 0.99169921875}, {"start": 1283.34, "end": 1283.78, "word": " مين", "probability": 0.989013671875}], "temperature": 1.0}, {"id": 56, "seek": 131209, "start": 1284.49, "end": 1312.09, "text": "ضد أعداءها الأمة العربية ممكن تكون reactive و very reactive ضد أعداءها اليوم لما صارت الأمة العربية في كل دولة فيها و ما بين الدول بعد هيك في كل دولة في شق reactive و شق reactive هدول الشقين طبق تالف بعض كيف صفيه مع الخارج? unreactive يعني في اليمن", "tokens": [11242, 3215, 5551, 22488, 16606, 11296, 16247, 46007, 18863, 25513, 10632, 3714, 43020, 6055, 30544, 28897, 4032, 588, 28897, 48812, 3215, 5551, 22488, 16606, 11296, 45595, 20498, 5296, 15042, 20328, 9640, 2655, 16247, 46007, 18863, 25513, 10632, 8978, 28242, 11778, 12610, 3660, 8978, 11296, 4032, 19446, 49374, 32748, 12610, 39182, 39896, 4117, 8978, 28242, 11778, 12610, 3660, 8978, 13412, 4587, 28897, 4032, 13412, 4587, 28897, 8032, 3215, 12610, 25124, 4587, 9957, 23032, 3555, 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" نيجي", "probability": 0.96435546875}, {"start": 2208.49, "end": 2208.85, "word": " نقول", "probability": 0.992431640625}, {"start": 2208.85, "end": 2209.91, "word": " تحضير", "probability": 0.9290771484375}, {"start": 2209.91, "end": 2210.77, "word": " الأمين", "probability": 0.9576822916666666}], "temperature": 1.0}, {"id": 98, "seek": 223779, "start": 2212.89, "end": 2237.79, "text": "بالـ reduction of amides شبيه بهذا التفاعل عشان تعملوا المقارنة انه كان ال Easter ال R سيضا بالبند OOR بالليثيام ألومنوم هيدرايد بال reduction شو كان يعطيني ال primary alcohol كان يعطيني RCH2OH لاحظوا المعادلتين هدولة", "tokens": [3555, 6027, 39184, 11004, 295, 669, 1875, 13412, 21292, 3224, 39627, 15730, 16712, 5172, 995, 30241, 6225, 8592, 7649, 6055, 25957, 1211, 14407, 9673, 4587, 9640, 1863, 3660, 16472, 3224, 25961, 2423, 9403, 2423, 497, 8608, 1829, 11242, 995, 20666, 3555, 41260, 422, 2483, 20666, 20292, 12984, 1829, 10943, 5551, 1211, 20498, 1863, 20498, 8032, 25708, 23557, 25708, 20666, 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new file mode 100644
index 0000000000000000000000000000000000000000..0c00532793b4d58cbd314874e035a70b891b579b
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VEV_j0BJLYk_raw.json
@@ -0,0 +1 @@
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3224, 2365, 1929], "avg_logprob": -0.1450471685461278, "compression_ratio": 1.8926829268292682, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 97.53, "end": 97.79, "word": "لما", "probability": 0.7164306640625}, {"start": 97.79, "end": 98.33, "word": " اتكلمنا", "probability": 0.94248046875}, {"start": 98.33, "end": 98.67, "word": " المرة", "probability": 0.964599609375}, {"start": 98.67, "end": 99.11, "word": " الماضية", "probability": 0.9830729166666666}, {"start": 99.11, "end": 99.29, "word": " عن", "probability": 0.994140625}, {"start": 99.29, "end": 100.11, "word": " الكحولات", "probability": 0.9945068359375}, {"start": 100.11, "end": 100.55, "word": " و", "probability": 0.98583984375}, {"start": 100.55, "end": 100.73, "word": " عن", "probability": 0.86474609375}, {"start": 100.73, "end": 100.87, "word": " ال", "probability": 0.986328125}, {"start": 100.87, "end": 101.51, "word": " aldehydes", "probability": 0.7369384765625}, {"start": 101.51, "end": 102.03, "word": " هذه", "probability": 0.2244873046875}, {"start": 102.03, "end": 102.77, "word": " الطريقة", "probability": 0.9026692708333334}, {"start": 102.77, "end": 103.57, "word": " طريقة", "probability": 0.93212890625}, {"start": 103.57, "end": 104.11, "word": " ايش", "probability": 0.7820638020833334}, {"start": 104.11, "end": 105.33, "word": " تساوي", "probability": 0.84906005859375}, {"start": 105.33, "end": 105.95, "word": " يعني", "probability": 0.828857421875}, {"start": 105.95, "end": 106.69, "word": " قداش", "probability": 0.7179361979166666}, {"start": 106.69, "end": 106.99, "word": " في", "probability": 0.90478515625}, {"start": 106.99, "end": 107.93, "word": " عندى", "probability": 0.84326171875}, {"start": 107.93, "end": 108.53, "word": " عدد", "probability": 0.9835611979166666}, {"start": 108.53, "end": 109.77, "word": " كربونات", "probability": 0.88154296875}, {"start": 109.77, "end": 110.53, "word": " في", "probability": 0.9423828125}, {"start": 110.53, "end": 111.51, "word": " 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"probability": 0.9903971354166666}, {"start": 116.29, "end": 116.73, "word": " كانوا", "probability": 0.94091796875}, {"start": 116.73, "end": 117.51, "word": " تلاتة", "probability": 0.932861328125}, {"start": 117.51, "end": 118.17, "word": " معنى", "probability": 0.806640625}, {"start": 118.17, "end": 118.45, "word": " ذلك", "probability": 0.9892578125}, {"start": 118.45, "end": 118.95, "word": " هيكون", "probability": 0.912109375}, {"start": 118.95, "end": 119.59, "word": " اسم", "probability": 0.838623046875}, {"start": 119.59, "end": 120.03, "word": " تبعه", "probability": 0.9530029296875}, {"start": 120.03, "end": 120.41, "word": " فيه", "probability": 0.954833984375}, {"start": 120.41, "end": 121.37, "word": " propane", "probability": 0.54315185546875}], "temperature": 1.0}, {"id": 5, "seek": 14412, "start": 121.92, "end": 144.12, "text": "أو ال الديهايد كانوا تلاتة الاسم تبعه برضه هيكون فيه بروفان تلاتة الآن ال acid اللي هيطلع برضه هيكون تلاتة لا هيزيد ولا هينقص خلينا نشوف هذا الكلام يعني مثلا لو أخدنا CH3 CH2", "tokens": [10721, 2407, 2423, 2423, 16254, 11296, 25708, 25961, 14407, 6055, 1211, 9307, 3660, 2423, 32277, 2304, 6055, 3555, 3615, 3224, 4724, 43042, 3224, 39896, 30544, 8978, 3224, 4724, 32887, 5172, 7649, 6055, 1211, 9307, 3660, 6024, 48506, 2423, 8258, 13672, 1829, 39896, 9566, 1211, 3615, 4724, 43042, 3224, 39896, 30544, 6055, 1211, 9307, 3660, 20193, 39896, 11622, 25708, 49429, 39896, 1863, 4587, 9381, 16490, 1211, 9957, 995, 8717, 8592, 38688, 23758, 2423, 28820, 10943, 37495, 22653, 50113, 15040, 45164, 5551, 9778, 3215, 8315, 5995, 18, 5995, 17], "avg_logprob": -0.24005681682716717, "compression_ratio": 1.7329545454545454, "no_speech_prob": 0.00010293722152709961, "words": [{"start": 121.92, "end": 123.0, "word": "أو", "probability": 0.5168914794921875}, {"start": 123.0, "end": 123.14, "word": " ال", "probability": 0.7646484375}, {"start": 123.14, "end": 123.82, "word": " الديهايد", "probability": 0.64581298828125}, {"start": 123.82, "end": 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اللي", "probability": 0.85009765625}, {"start": 130.86, "end": 131.6, "word": " هيطلع", "probability": 0.9725341796875}, {"start": 131.6, "end": 132.34, "word": " برضه", "probability": 0.9881184895833334}, {"start": 132.34, "end": 132.76, "word": " هيكون", "probability": 0.951416015625}, {"start": 132.76, "end": 133.56, "word": " تلاتة", "probability": 0.9837646484375}, {"start": 133.56, "end": 134.48, "word": " لا", "probability": 0.28515625}, {"start": 134.48, "end": 135.28, "word": " هيزيد", "probability": 0.8743489583333334}, {"start": 135.28, "end": 136.3, "word": " ولا", "probability": 0.88623046875}, {"start": 136.3, "end": 137.0, "word": " هينقص", "probability": 0.8199462890625}, {"start": 137.0, "end": 137.92, "word": " خلينا", "probability": 0.6990966796875}, {"start": 137.92, "end": 138.66, "word": " نشوف", "probability": 0.9547526041666666}, {"start": 138.66, "end": 138.9, "word": " هذا", "probability": 0.97216796875}, {"start": 138.9, "end": 139.56, "word": " الكلام", 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152.67, "end": 153.53, "word": " اسمه", "probability": 0.8990885416666666}, {"start": 153.53, "end": 155.71, "word": " بروبان", "probability": 0.833740234375}, {"start": 155.71, "end": 156.79, "word": " البروبان", "probability": 0.82391357421875}, {"start": 156.79, "end": 157.29, "word": " بتعبر", "probability": 0.8741455078125}, {"start": 157.29, "end": 157.45, "word": " عن", "probability": 0.96875}, {"start": 157.45, "end": 158.05, "word": " العدد", "probability": 0.9622395833333334}, {"start": 158.05, "end": 158.61, "word": " all", "probability": 0.400390625}, {"start": 158.61, "end": 160.37, "word": " الان", "probability": 0.648193359375}, {"start": 160.37, "end": 160.75, "word": " لو", "probability": 0.966796875}, {"start": 160.75, "end": 161.19, "word": " بدنا", "probability": 0.64599609375}, {"start": 161.19, "end": 161.81, "word": " اكسدة", "probability": 0.8499755859375}, {"start": 161.81, "end": 162.41, "word": " بسيطة", "probability": 0.97880859375}, {"start": 162.41, "end": 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Ibrobanol إذا هل تغير عدد الذرات؟ لأ لو امشينا في الأكسدة بالكيامان O4 عند اللزوم أو من البداية بدينا بالكيامان O4 CH3 CH2 Cضم البند O OH كم ذرة كربون؟ اه هذا إيش بدو يصير؟ Ibrobanol", "tokens": [2655, 1211, 9307, 3660, 23758, 13672, 1829, 1975, 2655, 30544, 13412, 2407, 24525, 2304, 3224, 30, 286, 1443, 996, 282, 401, 11933, 15730, 8032, 1211, 6055, 17082, 13546, 6225, 3215, 3215, 32545, 2288, 9307, 22807, 5296, 10721, 45164, 1975, 2304, 8592, 1829, 8315, 8978, 16247, 4117, 3794, 41891, 20666, 4117, 1829, 10943, 7649, 422, 19, 43242, 13672, 11622, 20498, 34051, 9154, 29739, 28259, 10632, 47525, 1829, 8315, 20666, 4117, 1829, 10943, 7649, 422, 19, 5995, 18, 5995, 17, 383, 11242, 2304, 29739, 41260, 422, 13931, 9122, 2304, 29910, 25720, 9122, 25513, 11536, 22807, 1975, 3224, 23758, 11933, 1829, 8592, 47525, 2407, 7251, 9381, 13546, 22807, 286, 9120, 5144, 401], "avg_logprob": -0.27272727950052783, "compression_ratio": 1.6355140186915889, "no_speech_prob": 5.960464477539063e-08, "words": 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double bond CH2", "tokens": [3555, 9566, 16572, 28671, 13412, 2407, 10632, 20328, 17082, 48923, 3714, 46456, 46538, 3660, 37495, 22653, 3714, 16758, 28259, 8592, 20666, 4117, 5016, 12610, 3714, 16758, 28259, 8592, 20666, 4117, 5016, 12610, 35186, 6055, 2288, 7578, 45164, 50113, 15040, 47525, 10721, 2655, 39627, 15730, 9673, 31747, 3555, 45164, 47525, 10721, 2655, 39627, 15730, 9673, 31747, 3555, 5995, 18, 5995, 3834, 6086, 5995, 17], "avg_logprob": -0.17224121396429837, "compression_ratio": 1.6258992805755397, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 249.87, "end": 250.43, "word": "بطريقة", "probability": 0.95751953125}, {"start": 250.43, "end": 250.83, "word": " شوية", "probability": 0.6086018880208334}, {"start": 250.83, "end": 251.23, "word": " صغيرة", "probability": 0.984375}, {"start": 251.23, "end": 252.29, "word": " مختلفة", "probability": 0.982177734375}, {"start": 252.29, "end": 252.99, "word": " يعني", "probability": 0.75146484375}, {"start": 252.99, "end": 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acid يعني كام كربونا؟ أربعة في عندى طريقتين ممكنين في عندى طريقتين ممكنين الطريقة الأولى أنه أنا هذا أجي أفعله مع CN minus والطريقة التانية أنه أنا هذا أفعله مع green yard reagent", "tokens": [2655, 1211, 9307, 3660, 4724, 16254, 5551, 5016, 11242, 2288, 9154, 23758, 457, 3730, 299, 8258, 37495, 22653, 9122, 10943, 9122, 25513, 2407, 8315, 22807, 5551, 25513, 27884, 8978, 43242, 7578, 23032, 16572, 38149, 9957, 3714, 43020, 9957, 8978, 43242, 7578, 23032, 16572, 38149, 9957, 3714, 43020, 9957, 41950, 16572, 28671, 16247, 12610, 7578, 14739, 3224, 41850, 23758, 5551, 7435, 1829, 5551, 5172, 30241, 3224, 20449, 14589, 3175, 16070, 9566, 16572, 28671, 16712, 7649, 10632, 14739, 3224, 41850, 23758, 5551, 5172, 30241, 3224, 20449, 3092, 11682, 26949, 317], "avg_logprob": -0.2438553384180819, "compression_ratio": 1.788659793814433, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 905.12, "end": 905.88, "word": "تلاتة", "probability": 0.8184814453125}, {"start": 905.88, "end": 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ال cyanide بيعملها hydrolysis ال acid و بعدها شو هيصير CH3 CH2 CH2 و هذه ال C هي اللي ضالت هتصير C double bond O OH اذا انا ال chlorine حولتها ل CN و ال CN ع طول بتصير COOH", "tokens": [40228, 22653, 2423, 47463, 482, 4724, 1829, 25957, 1211, 11296, 15435, 356, 17122, 2423, 8258, 4032, 39182, 11296, 13412, 2407, 39896, 9381, 13546, 5995, 18, 5995, 17, 5995, 17, 4032, 29538, 2423, 383, 39896, 13672, 1829, 48812, 6027, 2655, 8032, 2655, 9381, 13546, 383, 3834, 6086, 422, 13931, 1975, 15730, 1975, 8315, 2423, 39888, 11331, 12610, 2655, 11296, 5296, 14589, 4032, 2423, 14589, 6225, 23032, 12610, 39894, 9381, 13546, 3002, 31187], "avg_logprob": -0.2894965298473835, "compression_ratio": 1.4457142857142857, "no_speech_prob": 0.0, "words": [{"start": 980.87, "end": 981.23, "word": "يعني", "probability": 0.852294921875}, {"start": 981.23, "end": 981.37, "word": " ال", "probability": 0.611328125}, {"start": 981.37, "end": 982.01, "word": " cyanide", "probability": 0.6546630859375}, {"start": 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cyanobenzene بصير acid فيها مشكلة", "tokens": [3794, 3224, 37977, 16472, 45164, 1975, 8315, 43242, 7578, 47463, 996, 11368, 1450, 4724, 9381, 13546, 44335, 78, 299, 8258, 29538, 41950, 16572, 28671, 16490, 1211, 9957, 7578, 8717, 39648, 1975, 1829, 8592, 3714, 6027, 11296, 8608, 3224, 37977, 14589, 1975, 15730, 43242, 7578, 47463, 996, 11368, 1450, 8978, 49610, 23328, 389, 1804, 1975, 2407, 6056, 31187, 8717, 2304, 25720, 36764, 24401, 4032, 8717, 2304, 25720, 1975, 2655, 1863, 9957, 389, 1804, 30767, 7578, 19446, 11331, 4117, 1829, 8315, 12174, 36150, 13412, 2407, 10632, 2423, 47463, 996, 11368, 1450, 4724, 9381, 13546, 8258, 8978, 11296, 37893, 28820, 3660], "avg_logprob": -0.2035984836443506, "compression_ratio": 1.648780487804878, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1253.78, "end": 1254.52, "word": "سهلة", "probability": 0.8304036458333334}, {"start": 1254.52, "end": 1255.22, "word": " ان", "probability": 0.464599609375}, {"start": 1255.22, "end": 1255.46, 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1685.69, "word": " هو", "probability": 0.97607421875}, {"start": 1685.69, "end": 1686.47, "word": " Cl2", "probability": 0.820068359375}], "temperature": 1.0}, {"id": 70, "seek": 171058, "start": 1693.2, "end": 1710.58, "text": "بنزين بيصير بنزويك أسد بنزين بيصير طلوين بنزويك أسد", "tokens": [3555, 1863, 11622, 9957, 4724, 1829, 9381, 13546, 44945, 11622, 45865, 4117, 5551, 3794, 3215, 44945, 11622, 9957, 4724, 1829, 9381, 13546, 23032, 1211, 2407, 9957, 44945, 11622, 45865, 4117, 5551, 3794, 3215], "avg_logprob": -0.4218750026296167, "compression_ratio": 1.6491228070175439, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1693.1999999999998, "end": 1694.6, "word": "بنزين", "probability": 0.684906005859375}, {"start": 1694.6, "end": 1696.0, "word": " بيصير", "probability": 0.57659912109375}, {"start": 1696.0, "end": 1696.56, "word": " بنزويك", "probability": 0.74359130859375}, {"start": 1696.56, "end": 1697.04, "word": " أسد", "probability": 0.77880859375}, {"start": 1697.04, "end": 1698.68, "word": " بنزين", "probability": 0.8055013020833334}, {"start": 1698.68, "end": 1706.56, "word": " بيصير", "probability": 0.7291259765625}, {"start": 1706.56, "end": 1710.08, "word": " طلوين", "probability": 0.7620849609375}, {"start": 1710.08, "end": 1710.58, "word": " بنزويك", "probability": 0.8675537109375}, {"start": 1710.58, "end": 1710.58, "word": " أسد", "probability": 0.9679361979166666}], "temperature": 1.0}, {"id": 71, "seek": 174248, "start": 1712.74, "end": 1742.48, "text": "و بعدين كيامان افور بالكيامان افور اذا هى البنزويك اسد بتلات طرق اللى بده يحفظهم اول شى يقول بنزين طلوين بنزويك اسد بنزين سيانو بنزين بنزويك اسد بنزين كلورو بنزين بنزين جرينيارد بنزويك اسد كل هذه طرق لتحضير البنزويك اسد ولا لأ كان طريقة تلاتة واضح وبهيك بننهي اليوم", "tokens": [2407, 39182, 9957, 9122, 1829, 10943, 7649, 1975, 5172, 13063, 20666, 4117, 1829, 10943, 7649, 1975, 5172, 13063, 1975, 15730, 8032, 7578, 29739, 1863, 11622, 45865, 4117, 1975, 3794, 3215, 39894, 1211, 9307, 23032, 2288, 4587, 13672, 7578, 47525, 3224, 7251, 5016, 5172, 19913, 16095, 1975, 12610, 13412, 7578, 7251, 39648, 44945, 11622, 9957, 23032, 1211, 2407, 9957, 44945, 11622, 45865, 4117, 1975, 3794, 3215, 44945, 11622, 9957, 8608, 1829, 7649, 2407, 44945, 11622, 9957, 44945, 11622, 45865, 4117, 1975, 3794, 3215, 44945, 11622, 9957, 9122, 1211, 13063, 2407, 44945, 11622, 9957, 44945, 11622, 9957, 10874, 2288, 9957, 1829, 9640, 3215, 44945, 11622, 45865, 4117, 1975, 3794, 3215, 28242, 29538, 23032, 2288, 4587, 5296, 2655, 5016, 11242, 13546, 29739, 1863, 11622, 45865, 4117, 1975, 3794, 3215, 49429, 5296, 10721, 25961, 23032, 16572, 28671, 6055, 1211, 9307, 3660, 4032, 46958, 5016, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498], "avg_logprob": -0.20157284787948557, "compression_ratio": 2.3173076923076925, "no_speech_prob": 2.086162567138672e-06, "words": [{"start": 1712.74, "end": 1712.98, "word": "و", "probability": 0.673828125}, {"start": 1712.98, "end": 1713.54, "word": " بعدين", "probability": 0.87158203125}, {"start": 1713.54, "end": 1714.16, "word": " كيامان", "probability": 0.6718597412109375}, {"start": 1714.16, "end": 1714.42, "word": " افور", "probability": 0.6837565104166666}, {"start": 1714.42, "end": 1715.14, "word": " بالكيامان", "probability": 0.828173828125}, {"start": 1715.14, "end": 1715.72, "word": " افور", "probability": 0.96142578125}, {"start": 1715.72, "end": 1716.36, "word": " اذا", "probability": 0.6888427734375}, {"start": 1716.36, "end": 1716.58, "word": " هى", "probability": 0.404541015625}, {"start": 1716.58, "end": 1717.12, "word": " البنزويك", "probability": 0.773828125}, {"start": 1717.12, "end": 1717.42, "word": " اسد", "probability": 0.6758626302083334}, {"start": 1717.42, "end": 1717.9, "word": " بتلات", "probability": 0.775390625}, {"start": 1717.9, "end": 1718.3, "word": " طرق", "probability": 0.943359375}, {"start": 1718.3, "end": 1719.22, "word": " اللى", "probability": 0.947998046875}, {"start": 1719.22, "end": 1719.42, "word": " بده", "probability": 0.82958984375}, {"start": 1719.42, "end": 1719.94, "word": " يحفظهم", "probability": 0.87294921875}, {"start": 1719.94, "end": 1720.24, "word": " اول", "probability": 0.58251953125}, {"start": 1720.24, "end": 1720.46, "word": " شى", "probability": 0.44183349609375}, {"start": 1720.46, "end": 1720.86, "word": " يقول", "probability": 0.779296875}, {"start": 1720.86, "end": 1722.48, "word": " بنزين", "probability": 0.9358723958333334}, {"start": 1722.48, "end": 1723.14, "word": " طلوين", "probability": 0.81219482421875}, {"start": 1723.14, "end": 1724.76, "word": " بنزويك", "probability": 0.97119140625}, {"start": 1724.76, "end": 1725.18, "word": " اسد", "probability": 0.7816569010416666}, {"start": 1725.18, "end": 1726.0, "word": " بنزين", "probability": 0.962890625}, {"start": 1726.0, "end": 1726.5, "word": " سيانو", "probability": 0.9013671875}, {"start": 1726.5, "end": 1727.16, "word": " بنزين", "probability": 0.9755859375}, {"start": 1727.16, "end": 1728.54, "word": " بنزويك", "probability": 0.9837646484375}, {"start": 1728.54, "end": 1728.92, "word": " اسد", "probability": 0.8642578125}, {"start": 1728.92, "end": 1729.58, "word": " بنزين", "probability": 0.9822591145833334}, {"start": 1729.58, "end": 1730.0, "word": " كلورو", "probability": 0.8541259765625}, {"start": 1730.0, "end": 1730.44, "word": " بنزين", "probability": 0.97509765625}, {"start": 1730.44, "end": 1730.96, "word": " بنزين", "probability": 0.8070475260416666}, {"start": 1730.96, "end": 1731.9, "word": " جرينيارد", "probability": 0.801513671875}, {"start": 1731.9, "end": 1732.72, "word": " بنزويك", "probability": 0.9842529296875}, {"start": 1732.72, "end": 1733.1, "word": " اسد", "probability": 0.8470052083333334}, {"start": 1733.1, "end": 1733.42, "word": " كل", "probability": 0.8798828125}, {"start": 1733.42, "end": 1733.62, "word": " هذه", "probability": 0.6982421875}, {"start": 1733.62, "end": 1734.02, "word": " طرق", "probability": 0.9109700520833334}, {"start": 1734.02, "end": 1734.86, "word": " لتحضير", "probability": 0.97138671875}, {"start": 1734.86, "end": 1735.42, "word": " البنزويك", "probability": 0.96865234375}, {"start": 1735.42, "end": 1735.72, "word": " اسد", "probability": 0.8688151041666666}, {"start": 1735.72, "end": 1735.9, "word": " ولا", "probability": 0.8134765625}, {"start": 1735.9, "end": 1736.38, "word": " لأ", "probability": 0.90087890625}, {"start": 1736.38, "end": 1737.18, "word": " كان", "probability": 0.384521484375}, {"start": 1737.18, "end": 1737.86, "word": " طريقة", "probability": 0.9195963541666666}, {"start": 1737.86, "end": 1739.32, "word": " تلاتة", "probability": 0.9237060546875}, {"start": 1739.32, "end": 1739.88, "word": " واضح", "probability": 0.9405924479166666}, {"start": 1739.88, "end": 1740.92, "word": " وبهيك", "probability": 0.74310302734375}, {"start": 1740.92, "end": 1741.68, "word": " بننهي", "probability": 0.947021484375}, {"start": 1741.68, "end": 1742.48, "word": " اليوم", "probability": 0.94921875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 1742.680875, "duration_after_vad": 1658.0512499999968}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d1090a3474a98c8683203dd61caabc5e96ad64d8
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_postprocess.srt
@@ -0,0 +1,1904 @@
+1
+00:00:20,210 --> 00:00:23,950
+بسم الله الرحمن الرحيم بنبدأ اليوم بالفصل السابع
+
+2
+00:00:23,950 --> 00:00:30,470
+هتلاحظوا أنه يعني هنركز كعائلة أساسية فيه على
+
+3
+00:00:30,470 --> 00:00:35,650
+مركبات ال alcohols اللي بنسميها بالعربي الكحولات
+
+4
+00:00:35,650 --> 00:00:42,850
+الآن بعض الكتب اللي بتدرس باللغة العربية هتلاقوها
+
+5
+00:00:42,850 --> 00:00:49,720
+موجودة باسم الأغوالإذا مرت عليكم هذه الكلمة يعني
+
+6
+00:00:49,720 --> 00:00:52,920
+الناس اللي جاي من السعودية بدهم يدرسوا عن ال
+
+7
+00:00:52,920 --> 00:00:57,020
+alcohols الكحولات بدل ما يقولوا الكحولات بيقولوا
+
+8
+00:00:57,020 --> 00:01:03,200
+إيش الأغوال جامع غول و بيستندوا للنص القرآن لا
+
+9
+00:01:03,200 --> 00:01:08,760
+فيها غولولهم عنها ينزفون واضح الفكرة فإذا قرأتها
+
+10
+00:01:08,760 --> 00:01:14,800
+بكتاب عربي باسم الأغوال فهي الكحولات، الآن ككيميا
+
+11
+00:01:14,800 --> 00:01:23,080
+الكحولات هي المركبات اللي ماخدة صيغة Rواضح الان
+
+12
+00:01:23,080 --> 00:01:30,020
+بيجي معها ال phenols إذا كانت ال OH متصلة بحلقة
+
+13
+00:01:30,020 --> 00:01:35,020
+أروماتية البنزين حالة خاصة بيكون نفس ال phenol لكن
+
+14
+00:01:35,020 --> 00:01:42,920
+المجموعة العامة AR بشكل عام ال AR OH يعني كل
+
+15
+00:01:42,920 --> 00:01:47,580
+المركبات الأروماتية إذا اتصلت ب OH they are
+
+16
+00:01:47,580 --> 00:01:55,420
+phenolsموازي لل alcohols لكن بإبدال ال oxygen هادى
+
+17
+00:01:55,420 --> 00:02:01,200
+ب Sulphur بيصير المركب ثيول بيصير المركب ثيول يعني
+
+18
+00:02:01,200 --> 00:02:08,060
+ماخد الصيغة العامة R RSH ثيولز ماخد الصيغة العامة
+
+19
+00:02:08,060 --> 00:02:15,060
+RSH طبعا اكيد هتقولوا طيب في موازي لل phenol بمعنى
+
+20
+00:02:15,060 --> 00:02:16,580
+اخر ايش بدى يكون ماخد AR
+
+21
+00:02:19,820 --> 00:02:25,320
+SH موجود أيضا بنسميه Theophenol
+
+22
+00:02:27,210 --> 00:02:33,170
+واضح؟ فهذه العائلات اللي طبعا الأساس فيها عائلة
+
+23
+00:02:33,170 --> 00:02:37,390
+الكحولات يعني هيكون التركيز الأكبر على الكحولات
+
+24
+00:02:37,390 --> 00:02:41,030
+اللي هي المركبات اللي ماخدة الصيغة العامة ROH من
+
+25
+00:02:41,030 --> 00:02:47,210
+الطرق بشكل خفيف للphenols للthiols للthiophenols
+
+26
+00:02:47,210 --> 00:02:53,270
+كل هذه الأشياء ان شاء الله بنقشها في هذا الفصل
+
+27
+00:02:56,090 --> 00:03:00,990
+إذا بدأنا بالكحولات .. إذا بدأنا بالكحولات و أول
+
+28
+00:03:00,990 --> 00:03:06,430
+شغلة دايما بنبدأ فيها كيف نسمي المركبات عادة بنسمي
+
+29
+00:03:06,430 --> 00:03:12,190
+الكحولات بإضافة النهاية all لاحظوا أن نظام التسمية
+
+30
+00:03:12,190 --> 00:03:15,910
+.. نظام التسمية في ال organ chemistry للناس اللي
+
+31
+00:03:15,910 --> 00:03:22,120
+بيتقنوه هو نظامبسيط جدا يعني مئات إذا ما قلناش
+
+32
+00:03:22,120 --> 00:03:27,540
+ملايين المراكبات الإنسان بتعلم قواعد بسيطة جدا
+
+33
+00:03:27,540 --> 00:03:32,840
+للتسمية وبيقدر يسيطر عليها الآن المفروض مع هذا
+
+34
+00:03:32,840 --> 00:03:37,440
+الوقت أنه صار نظام التسمية بالنسبة لناواضح في
+
+35
+00:03:37,440 --> 00:03:42,560
+عندنا سلسلة كربونية بدنا ناخد العدد تبعها بالنهاية
+
+36
+00:03:42,560 --> 00:03:48,980
+ميثين إيثين بروبين بيوتين بيوتين هكسين هبتين هدوله
+
+37
+00:03:48,980 --> 00:03:53,300
+صرنا حافظينهم الآن هذا الكلام إذا كانت السلسلة
+
+38
+00:03:53,300 --> 00:03:56,840
+كلها روابط أحدية وقلنا الkins الآن إذا صرنا في
+
+39
+00:03:56,840 --> 00:04:02,900
+الروابط الثنائية بنغير بنحط in بدل ال in في
+
+40
+00:04:02,900 --> 00:04:09,610
+الروابط الثلاثيةI الآن في الكحولات بنحط نهاية all
+
+41
+00:04:09,610 --> 00:04:14,450
+بعد شوية هنتعلم في ال aldehydes بنحط نهاية L في ال
+
+42
+00:04:14,450 --> 00:04:19,430
+ketone بنحط نهاية on في الأحماض الكربوكسيلية بنحط
+
+43
+00:04:19,430 --> 00:04:24,390
+نهاية oic acid بمعنى لو أنا رسمت خمس درات كربون
+
+44
+00:04:24,390 --> 00:04:29,690
+بقدر اقول ان المركبات اللي منهم عند اللزوم مثيل
+
+45
+00:04:30,860 --> 00:04:39,680
+للألكين ميثين اعفوا بنتين I mean بنتين بنتين بنتين
+
+46
+00:04:39,680 --> 00:04:42,860
+طبعا بحدد وين موقع ال double bond ده قصة بسيطة
+
+47
+00:04:42,860 --> 00:04:50,580
+بنتاي بنتانول بنتانال لل الديهايد بنتانون لل كيتون
+
+48
+00:04:50,580 --> 00:04:56,970
+بنتانوك أسد فصارت القصة فقط هي نهايةبتتغير في
+
+49
+00:04:56,970 --> 00:05:01,750
+نهاية الاسم و بنقدر نسمي المراكبات انتبهوا جيدا ان
+
+50
+00:05:01,750 --> 00:05:05,870
+ال all اللي بنستعمله انه نهاية الكحولات مافيش فيها
+
+51
+00:05:05,870 --> 00:05:13,330
+E في الآخر يعني OL بدون E ليش هتوجهنا المراكبات
+
+52
+00:05:13,770 --> 00:05:20,050
+بتنتهي ب OLE هذه مركبات حلقية تحتوي على حلقات
+
+53
+00:05:20,050 --> 00:05:24,430
+خماسية خارج موضوع دراستنا زي لما تسمعوا عن بعض
+
+54
+00:05:24,430 --> 00:05:29,870
+الأدوية مثلا المضادة للفطريات الدكتازول
+
+55
+00:05:29,870 --> 00:05:33,690
+والفلوكانازول الناس اللي عندهم فطريات أحيانا بين
+
+56
+00:05:33,690 --> 00:05:39,560
+أصابع رجليهم بيشتريوامضاد للفطريات دكتازول مشهور
+
+57
+00:05:39,560 --> 00:05:45,040
+كتير في البلد flucanazole هدولة هتلاحظوا اسمهم OLE
+
+58
+00:05:45,040 --> 00:05:50,580
+OLE هذه عائلة ثانية عائلة مركبات بحلقات يشمالها
+
+59
+00:05:50,580 --> 00:05:56,980
+خماسية فالكحولات اللي عندنا نهايتهم all الان لو
+
+60
+00:05:56,980 --> 00:06:03,680
+اجينا بدنا نسمي ب carbon واحد هنقول مثان allو هكذا
+
+61
+00:06:03,680 --> 00:06:08,060
+الان لاحظوا ال common nomenclature و مرات كتير
+
+62
+00:06:08,060 --> 00:06:12,920
+بنقولكوا ايش الاسم الشائع للمركب ايضا لها بشكل عام
+
+63
+00:06:12,920 --> 00:06:19,800
+قاعدة القاعدة تبعتها ذكر المجموعة ال alkyl group و
+
+64
+00:06:19,800 --> 00:06:25,300
+بعدين بنحط نهاية يعني لو كان هذا المركب CH3Cl كنت
+
+65
+00:06:25,300 --> 00:06:28,800
+اقول ال common nomenclature له مثل ال chloride
+
+66
+00:06:28,800 --> 00:06:35,950
+الان لما بيصير CH3OHمثل و ال OH عائلة الألكوهول
+
+67
+00:06:35,950 --> 00:06:40,250
+فبصير مثل ألكوهول و هكذا ف ال common nomenclature
+
+68
+00:06:40,250 --> 00:06:48,750
+بشكل عام بتيجي بذكر المجموعة و بعدها العائلة واضح؟
+
+69
+00:06:48,750 --> 00:06:52,590
+نفس الاشي هتلاحظوا مثلا في ال aldehydes
+
+70
+00:06:52,590 --> 00:07:00,950
+بروبلالديهيد مثلا بروبل المجموعة الديهيدالعائلة و
+
+71
+00:07:00,950 --> 00:07:06,830
+بال كيتون و بال أسد و بال كلورايتس و بالبرومايتس
+
+72
+00:07:08,520 --> 00:07:13,980
+توجه عام الان لو اتيت هنا اتطلعت هذا إيثانول طبعا
+
+73
+00:07:13,980 --> 00:07:19,200
+المجموعة إيثل بناء على ذلك بيكون إيثل ألكول هذا
+
+74
+00:07:19,200 --> 00:07:23,700
+البروبانول الان لاحظوا البروبانول الالكول ممكن
+
+75
+00:07:23,700 --> 00:07:26,580
+تكون ال OH على الكاربون الأولى أو على الكاربون
+
+76
+00:07:26,580 --> 00:07:30,880
+الثانية ولذلك بلزم نوضح بالترقيم فبنقول one
+
+77
+00:07:30,880 --> 00:07:36,890
+probanol و two probanolواضح؟ ال alcohol من
+
+78
+00:07:36,890 --> 00:07:41,470
+المركبات زيها زي ال alkenes اللي مرات كتير لازم
+
+79
+00:07:41,470 --> 00:07:45,870
+نوضح موقع المجموعة الوظيفية باستعمال ايش؟ أرقام
+
+80
+00:07:45,870 --> 00:07:50,290
+طبعا هنا لما قلنا one probanol لو كنا بدنا نسميه
+
+81
+00:07:50,290 --> 00:07:54,070
+بالاسم الشائع ال common name المجموعة هذه probel
+
+82
+00:07:54,070 --> 00:08:00,370
+.. probel alcohol الآن هذا two probanolأيزو برو
+
+83
+00:08:00,370 --> 00:08:01,430
+بالالكهول
+
+84
+00:08:15,670 --> 00:08:19,770
+CH حملة تنتين CH3 و كمان كربونة يعني العدد الكلي
+
+85
+00:08:19,770 --> 00:08:25,310
+أربعة إذا هذا شو بدي أسميه Isobutyl يمكن ال I
+
+86
+00:08:25,310 --> 00:08:30,290
+رايحة Isobutyl alcohol طبعا لو بدي أسميه أيوبكنومي
+
+87
+00:08:30,290 --> 00:08:35,990
+كليتشار بدي أسميه بالترقيم و ال OH بدي أكون ماخدة
+
+88
+00:08:35,990 --> 00:08:40,290
+أقل ترقيم يعني بدي أقول واحد اتنين تلاتة إذا هذا
+
+89
+00:08:40,290 --> 00:08:45,440
+one-probanolوانبروبانول على نمر اتنين شو بيحمل
+
+90
+00:08:45,440 --> 00:08:51,200
+الوانبروبانول مثل هاي أطول سلسلة واحد اتنين تلاتة
+
+91
+00:08:51,200 --> 00:08:57,520
+two مثل وانبروبانول فلازم احدد موقع ال ايش ال OH
+
+92
+00:08:57,520 --> 00:09:02,800
+two مثل وانبروبانوللو بننظر لهذا المركب على سبيل
+
+93
+00:09:02,800 --> 00:09:06,460
+المثال كمجموعة لو كنت بدي ال common nomenclature
+
+94
+00:09:06,460 --> 00:09:11,080
+له كمجموعة معروفة tertiary butyl اذا tertiary
+
+95
+00:09:11,080 --> 00:09:14,640
+butyl alcohol طب لو بدي اسميه بال iubac
+
+96
+00:09:14,640 --> 00:09:18,360
+nomenclature مرة تانية بدي اطول سلسلة خليني افترض
+
+97
+00:09:18,360 --> 00:09:24,700
+هي اطول سلسلة واحد اتنين تلاتة اذا هذا a-probanol
+
+98
+00:09:25,770 --> 00:09:31,010
+تو بروبانول لأن ال OH طالعة من موقع اتنين و على
+
+99
+00:09:31,010 --> 00:09:34,730
+اتنين ايضا ايش في عندكم مثل اذا two methyl two
+
+100
+00:09:34,730 --> 00:09:37,370
+probanol is tertiary butyl alcohol
+
+101
+00:09:45,170 --> 00:09:48,790
+الـ Common Nomenclature هو الـ tertiary butyl
+
+102
+00:09:48,790 --> 00:09:52,950
+alcohol في الـ Common Nomenclature الآن هذا
+
+103
+00:09:52,950 --> 00:09:57,150
+المُركّب لو بدأ أطلع على المجموعة اللي فيه لما
+
+104
+00:09:57,150 --> 00:10:02,690
+درفنا ال الكينز أخدنا مجموعتين أخدنا الفينل والألل
+
+105
+00:10:02,690 --> 00:10:06,870
+قلنا الألل اللي هو البروبين اللي بنخص منه هيدروجين
+
+106
+00:10:06,870 --> 00:10:10,780
+من هذا الموقعكل هذا الكلام السكوت اللي بلاحظه على
+
+107
+00:10:10,780 --> 00:10:15,740
+بعض الوجوه اللي أنا مارجعتش كتير هذه مشكلتها واضح؟
+
+108
+00:10:15,740 --> 00:10:20,700
+بدكوا تكونوا متذاكرين هذه المجموعة أخدناها بهذا
+
+109
+00:10:20,700 --> 00:10:25,380
+الشكل اسمها إيش؟ ألل الآن إذا إجي عليها chlorine
+
+110
+00:10:26,360 --> 00:10:30,580
+ألل كلورايت إذا إتي عليها بروم ألل برومايت إذا إتي
+
+111
+00:10:30,580 --> 00:10:36,960
+عليها OH ألل Alcohol فمن ناحية ال Alcohol اعرفنا
+
+112
+00:10:36,960 --> 00:10:42,520
+الآن لو كنا هذا ال ال alcohol بدنا نسميه بال Iopac
+
+113
+00:10:42,520 --> 00:10:48,840
+Nomenclature هنلاحظ إن في عندنا مجمعتين وظيفيتين
+
+114
+00:10:48,840 --> 00:10:53,280
+بدنا ننتبهالان التقاء المجموعات الوظيفية في
+
+115
+00:10:53,280 --> 00:10:58,520
+المركبات هذه تماما زى التقاء المجموعات الوظيفية
+
+116
+00:10:58,520 --> 00:11:02,660
+لما درسنا ال aromatic compounds متذكرين؟ اه قولنا
+
+117
+00:11:02,660 --> 00:11:07,420
+أبسط إشي ال alkanes بعدين ال alkenes و ال alkynes
+
+118
+00:11:07,420 --> 00:11:13,460
+بعدين مثلا ال OH بعدين ال ketone بعدين ال aldehyde
+
+119
+00:11:13,460 --> 00:11:19,890
+بعدين ال acidOkay فلو أنا بدي أجي أطلع أنه عندي OH
+
+120
+00:11:19,890 --> 00:11:27,370
+وعندي ال keen مين بده تكون العائلة ال OH وبناء على
+
+121
+00:11:27,370 --> 00:11:33,050
+ذلك المركب اللي عنده لازم ياخد النهاية all لأن
+
+122
+00:11:33,050 --> 00:11:37,950
+الشيء بتسمى باسم عائلته بياخد النهاية all طبعا هذا
+
+123
+00:11:37,950 --> 00:11:41,490
+لو بدي أطلع عليه واحد و الترقيم من وين هيكون؟
+
+124
+00:11:41,710 --> 00:11:46,310
+بنعندى الالكول واحد اتنين تلاتة طبعا بينا نسميه
+
+125
+00:11:46,310 --> 00:11:51,950
+بروبان all هو فيه double bond فبدل ال a بروبين
+
+126
+00:11:51,950 --> 00:11:58,050
+بيصير بروبين ال يعني لو مافيش عند انا هذا double
+
+127
+00:11:58,050 --> 00:12:02,910
+bond ايش كنت استعمل حرف ال a الآن صار double bond
+
+128
+00:12:02,910 --> 00:12:10,150
+ال الكن صار الكن صار بروبين all واضح بروبين all
+
+129
+00:12:10,150 --> 00:12:18,000
+لاحظواالعائلة إيش؟ all و هو فيه ألكين، الآن ال all
+
+130
+00:12:18,000 --> 00:12:24,470
+لازم نحدد موقعها و ال ألكين لازم نحدد موقعهابتدخل
+
+131
+00:12:24,470 --> 00:12:29,550
+الأرقام ال all على أي موقع جاية على واحد فبنكتب
+
+132
+00:12:29,550 --> 00:12:34,830
+two prob in one all بمعنى أن ال in موجودة على موقع
+
+133
+00:12:34,830 --> 00:12:39,890
+اتنين وال all على موقع واحد مرات هذا ممكن تشوفوه
+
+134
+00:12:39,890 --> 00:12:45,670
+بطريقة تانية يعني يكتبوه a prob و بعدين in و بعدين
+
+135
+00:12:45,670 --> 00:12:52,100
+all و يحددوا أن ال in على أي موقع اتنينع اتنين و
+
+136
+00:12:52,100 --> 00:12:56,080
+ال all على اي موقع لاحظوا اختلاف بسيط هنا في
+
+137
+00:12:56,080 --> 00:13:00,160
+الكتاب يعني عملنا تقطيع في الاسم حددنا وين ال in و
+
+138
+00:13:00,160 --> 00:13:05,100
+وين ال all هنا نفس الاشي و فهمنا ضمنا ان اتنين
+
+139
+00:13:05,100 --> 00:13:11,180
+اللي كتبت برا هي تعنيموقع ال in و ال all جنبها ف
+
+140
+00:13:11,180 --> 00:13:16,000
+two probine one all او prob two in one all هو نفس
+
+141
+00:13:16,000 --> 00:13:20,560
+الاسم يعني طريقتين لكتابة نفس الاسم في كتير طلاب
+
+142
+00:13:20,560 --> 00:13:25,320
+بيحبوا يقولوا في الأول هذا كله probine all جنب ال
+
+143
+00:13:25,320 --> 00:13:30,140
+in بالظبط بيحطوا الرقم جنب ال all بالظبط بيحطوا
+
+144
+00:13:30,140 --> 00:13:32,140
+الرقم تبعها
+
+145
+00:13:35,230 --> 00:13:39,650
+فهذه الطريقة اللي احنا بنستعملها لما بلتقى عندنا
+
+146
+00:13:39,650 --> 00:13:44,370
+اكثر من مجموعة وظيفية لاحظوا بدي اجي مباشرة على
+
+147
+00:13:44,370 --> 00:13:50,650
+هذا المثال لانه على نفس الفكرة طلع هذا المثال ايش
+
+148
+00:13:50,650 --> 00:13:58,180
+العائلات اللي موجودة فيه؟ال all و ال I ال ال مين
+
+149
+00:13:58,180 --> 00:14:04,120
+أعلى في الأولوية ال all إذا لو عديت العدد لكل واحد
+
+150
+00:14:04,120 --> 00:14:11,880
+اتنين تلاتة أربعة خمسة إيش هيكون كمركب؟ بين two
+
+151
+00:14:11,880 --> 00:14:17,960
+all بين two all هيني ذكرت المجموعتين لما أنا أقول
+
+152
+00:14:17,960 --> 00:14:21,240
+بين I
+
+153
+00:14:22,480 --> 00:14:29,500
+all هذه المجموعتين في I و في all الآن بلزم أن احدد
+
+154
+00:14:29,500 --> 00:14:36,960
+موقعهم ال all على اي موقع و ال I على تلاتة بنت
+
+155
+00:14:36,960 --> 00:14:42,140
+اثري I one all او لو كتبت اثري بنتين بتفهم ان ال
+
+156
+00:14:42,140 --> 00:14:47,160
+three هذي بتحدد موقع ال I اثري بنتين one all او
+
+157
+00:14:47,160 --> 00:14:52,500
+بنت اثري I one all نفس الفكرة تماماواضح؟ نفس
+
+158
+00:14:52,500 --> 00:14:57,360
+المُركّب فهذا الكلام اللي بيصير عندنا لما بلتقي
+
+159
+00:14:57,360 --> 00:15:05,380
+أكثر من مجموعة وظيفية الان ممكن يكون عندي alcohol
+
+160
+00:15:05,380 --> 00:15:13,120
+على حلقات ال alcohol على الحلقة .. الحلقة مش زي
+
+161
+00:15:13,120 --> 00:15:18,620
+السلسلةالحلقة ما لهاش بداية و نهاية يعني لما يكون
+
+162
+00:15:18,620 --> 00:15:24,200
+عندي انا خمس درات كربون كسلسلة باجي بقول بضحوط ال
+
+163
+00:15:24,200 --> 00:15:31,460
+OH هنا بسميه one بنتانول هنا two بنتانول three
+
+164
+00:15:31,460 --> 00:15:35,760
+بنتانول برجع طبعا two بنتانول اذا في عندي في
+
+165
+00:15:35,760 --> 00:15:40,150
+السلسلةone pentanol و two pentanol و three
+
+166
+00:15:40,150 --> 00:15:46,600
+pentanol لكن لو هذه السلسلة صارت حلقة خماسيةالان
+
+167
+00:15:46,600 --> 00:15:50,420
+سواء كتبة ال او اتش هان او هان او هان او هان او
+
+168
+00:15:50,420 --> 00:15:54,220
+هان جميع المواقع متكافئة مافيش فيها موقع واحد يعني
+
+169
+00:15:54,220 --> 00:15:58,800
+مابيقدرش الإنسان الحلقة يقول وين بدايتها ولذلك هذا
+
+170
+00:15:58,800 --> 00:16:04,200
+بتسمى cyclopentanol بدون ما نحطله one أو two لأن
+
+171
+00:16:04,200 --> 00:16:11,240
+كل المواقع واحد واضح؟ cyclopentanol لكن وقتش بيلزم
+
+172
+00:16:11,240 --> 00:16:16,930
+ترقيملو كان عندى اكتر من مجموعة عشان اشوف انه هذه
+
+173
+00:16:16,930 --> 00:16:23,610
+المجموعات انه هذه المجموعات هل يا ترى واحد اتنين
+
+174
+00:16:23,610 --> 00:16:27,250
+ولا واحد تلاتة ايش العلاقة بينها يعني لو كان
+
+175
+00:16:27,250 --> 00:16:31,030
+المركب بهذا الشكل والمجموعتين على جهة واحدة هذا
+
+176
+00:16:31,030 --> 00:16:38,930
+ايش هسميه one two cyclopentane by all all و all
+
+177
+00:16:39,860 --> 00:16:44,680
+Diol واضح؟ one two cycle وبنتين ديول وحنقول إيش
+
+178
+00:16:44,680 --> 00:16:52,140
+مالهم؟ sis طبعا ممكن نتخيل مركب بهذا الشكل لو
+
+179
+00:16:52,140 --> 00:16:58,860
+افترضنا هنا في عندنا OH وهنا في عندنا CL وإيجا
+
+180
+00:16:58,860 --> 00:17:05,680
+بدنا نسميه الآن أكيد ال alcohol أساس أقوى من ال CL
+
+181
+00:17:05,680 --> 00:17:12,110
+إذا المركب إيش هيكون؟cyclopentanol بتخيلوا من وين
+
+182
+00:17:12,110 --> 00:17:17,070
+بيبدأ الترقيم؟ و
+
+183
+00:17:17,070 --> 00:17:23,270
+بناء على ذلك مثل هذا المركب هيصير three .. فيش
+
+184
+00:17:23,270 --> 00:17:31,050
+ميتة ميتة في البنزينة خلصنا منها بس في البنزينة مش
+
+185
+00:17:31,050 --> 00:17:37,190
+في الحلقات إذا هذا three chloro cyclopentanol
+
+186
+00:17:37,370 --> 00:17:44,590
+بنتانول مش بنتين Cyclopentanol خلاص مابنكتبش one
+
+187
+00:17:44,590 --> 00:17:48,150
+لأنه يفهم ضمنا أن الترقيم بدأ من عندها يعني
+
+188
+00:17:48,150 --> 00:17:52,770
+مابنكتبش three chloro cyclopentane one all أو one
+
+189
+00:17:52,770 --> 00:17:57,310
+cyclopentanol لأ three chloro cyclopentanol و هكذا
+
+190
+00:17:57,310 --> 00:17:58,110
+واضح؟
+
+191
+00:18:00,740 --> 00:18:06,080
+الان احيانا بلتقي عندى الجزء ال aliphatic مع ال
+
+192
+00:18:06,080 --> 00:18:10,320
+aromatic وسبق احنا لما أخدنا ال aromatic compounds
+
+193
+00:18:10,320 --> 00:18:16,020
+نوّهنا لهذه النقطة قولنا انه ممكن نسمي المركب بأحد
+
+194
+00:18:16,020 --> 00:18:21,560
+طريقين اما ان نعتبر الأساس بنزين و اكتشف نعتبر
+
+195
+00:18:21,560 --> 00:18:26,600
+الأساس بنزينإذا هذه المجموعة اللي موجودة سهلة ولها
+
+196
+00:18:26,600 --> 00:18:31,460
+اسم بسيط عارفينه طب إذا مش مجموعة سهلة وملاش اسم
+
+197
+00:18:31,460 --> 00:18:39,480
+بسيط بعتبر نفسي بتعامل مع المركب كالكين بتعامل مع
+
+198
+00:18:39,480 --> 00:18:45,620
+المركب كالكين هذا الالكين هيطول سلسلة فيه في نمرة
+
+199
+00:18:45,620 --> 00:18:50,780
+واحد اتنين ويحمل مجموعة ايش اسم هذه المجموعة فنل
+
+200
+00:18:51,570 --> 00:18:56,330
+البنزينة اللى خصمنا منها H كمجموعة شو بنسميها؟ فنل
+
+201
+00:18:56,330 --> 00:18:59,970
+طبعا لاحظوا المركب اللى فيه ذرتين كربون هو اي
+
+202
+00:18:59,970 --> 00:19:06,470
+مركب؟ الاثانول اذا هذا لو كنا بنسميه شو هنسميه؟
+
+203
+00:19:06,470 --> 00:19:08,790
+two phenyl اثانول
+
+204
+00:19:11,950 --> 00:19:16,070
+يفهم على طول مباشرة طالما كتبنا two أن الـ O على
+
+205
+00:19:16,070 --> 00:19:22,430
+واحد و هذا على اتنين لاحظوا لو مثلا جبنا مركب شبيه
+
+206
+00:19:22,430 --> 00:19:29,390
+فيه بهذا الشكل هاي ذارتين كربون و حطينا الـ OH هنا
+
+207
+00:19:29,390 --> 00:19:30,970
+و البنزينة هنا
+
+208
+00:19:35,020 --> 00:19:39,080
+لاحظوا هذا isomer .. structural isomer كربون تنتين
+
+209
+00:19:39,080 --> 00:19:42,140
+كانت ال O H على الكربون الأولى و البنزينة على
+
+210
+00:19:42,140 --> 00:19:45,080
+التانية حطينا ال O H على الأولى و البنزينة على
+
+211
+00:19:45,080 --> 00:19:53,120
+الأولى فلو بدنا نيجي نقول بدنا نسمي هذا one phenyl
+
+212
+00:19:53,120 --> 00:20:00,180
+one ethanol مواد هيك إيثانول
+
+213
+00:20:03,690 --> 00:20:10,650
+عشان نضع رقم وان فينيل وان إيثانول واضح؟ وان فينيل
+
+214
+00:20:10,650 --> 00:20:14,350
+وان إيثانول عشان التوضيح يعني دائما في موضوع
+
+215
+00:20:14,350 --> 00:20:19,430
+الأرقام إذا حسيت أن في شيء confusing لازمة أرقام
+
+216
+00:20:19,430 --> 00:20:25,250
+إضافية نضعها مش لازمة أرقام إضافية مافيش داعي أن
+
+217
+00:20:25,250 --> 00:20:29,470
+نضع الأرقام مايتضح بدون أرقام لا نستعمل له الأرقام
+
+218
+00:20:29,470 --> 00:20:35,310
+يعني هنابتمشي بدون أرقام بيبطل فيه لزوم ان اكتب
+
+219
+00:20:35,310 --> 00:20:39,490
+one على سبيل المثال one cyclopentanol خلاص
+
+220
+00:20:39,490 --> 00:20:45,030
+فالأرقام عندها غرض ايش الغرض تبعها التوضيح لما
+
+221
+00:20:45,030 --> 00:20:49,350
+بيصير في لبس معين بحتاج ان نحط الأرقام عشان نوضح
+
+222
+00:20:49,350 --> 00:20:56,350
+بنستعملها طبعا ال aromatic alcohol انجاز التعبير
+
+223
+00:20:56,350 --> 00:21:03,280
+الأساس فيهمالفينول مر علينا تسميته وقلنا لو ال OH
+
+224
+00:21:03,280 --> 00:21:08,480
+مع ال نيترو مين الأساس الفينول إذا هذا para-nitro
+
+225
+00:21:08,480 --> 00:21:14,260
+أو four-nitroفينول لكن بدكوا تنتبهوا لنقطة أن نفس
+
+226
+00:21:14,260 --> 00:21:21,020
+هذه الفينول لو انوجدت مع مجموعات أعلى منها هترجع
+
+227
+00:21:21,020 --> 00:21:26,620
+لأصلها يعني هذه حامض C double bond O OH acidو
+
+228
+00:21:26,620 --> 00:21:31,380
+Alcohol من الأعلى؟ ال acid ولذلك هذا المُركّب
+
+229
+00:21:31,380 --> 00:21:35,620
+Benzoic acid على موقع Ortho، إيش عندكم؟
+
+230
+00:21:39,360 --> 00:21:44,420
+Orthohydroxy benzoic acid أو two hydroxy benzoic
+
+231
+00:21:44,420 --> 00:21:51,020
+acid طبعا هذا ماخد اسم شهرة salicylic acid ماخد
+
+232
+00:21:51,020 --> 00:21:54,720
+اسم شهرة ايش؟ salicylic acid ال salicylic acid هو
+
+233
+00:21:54,720 --> 00:21:59,760
+الحامض اللي بيطلو عادة من شجر الصفصاف وهو أساس
+
+234
+00:21:59,760 --> 00:22:05,680
+تحضير الأسبيرين هو أساس تحضير الأسبيرينيعني
+
+235
+00:22:05,680 --> 00:22:11,960
+الأسبيرين عادة بيشتقوا من هذا الحامض بيبدلوا ال H
+
+236
+00:22:11,960 --> 00:22:16,400
+اللي موجودة هنا على ال OH شايفين هذه ال OH هذه ال
+
+237
+00:22:16,400 --> 00:22:20,140
+H بنبدلها و بنحط مكانها هذه المجموعة
+
+238
+00:22:23,720 --> 00:22:26,920
+الناس اللي حفظوا معنا هذه المجموعة أخدناها لجامن
+
+239
+00:22:26,920 --> 00:22:32,840
+الـ acetic acid أسيتل فبصير المركب بدل salicylic
+
+240
+00:22:32,840 --> 00:22:35,140
+acid أسيتو
+
+241
+00:22:37,400 --> 00:22:42,540
+acetosalicylic acid هو الاسبيرين واضح فالاسبيرين
+
+242
+00:22:42,540 --> 00:22:47,480
+هو ال salicylic acid لكن انا شيلت منه ال H وحطيت
+
+243
+00:22:47,480 --> 00:22:52,940
+مكانها C double bond O CH3 فبصير الاسم المشهور
+
+244
+00:22:52,940 --> 00:23:00,080
+للاسبيرين ايش acetosalicylic acidacetosalicylic
+
+245
+00:23:00,080 --> 00:23:04,860
+acid المثال الأخير اللي موجود في هذا ال slide هو
+
+246
+00:23:04,860 --> 00:23:10,280
+التقاء الديهايد مع الكهول لحظة متذكرين لما قلنا
+
+247
+00:23:10,280 --> 00:23:16,280
+الكهول الديهايدي ماكتبوش COH CHO وهذا لو كنا
+
+248
+00:23:16,280 --> 00:23:21,960
+بنفسرها بال structure كيف بنفسرها بنفسرها C double
+
+249
+00:23:21,960 --> 00:23:29,730
+bond OHهذه تفاصيلها C double bond OH لما بنكتبها
+
+250
+00:23:29,730 --> 00:23:34,750
+كتابة كيف بنكتبها CHO فهذه مجموعة ال الديهايد الان
+
+251
+00:23:34,750 --> 00:23:39,350
+ال الديهايد أعلى من الألكوهول ولذلك المركب اللي
+
+252
+00:23:39,350 --> 00:23:46,490
+عندي هنا بنز الديهايد على موقع متا هيدروكسي
+
+253
+00:23:46,490 --> 00:23:50,050
+متا هيدروكسي بنز الديهايد
+
+254
+00:23:54,320 --> 00:23:59,120
+هذا بشكل عام بالنسبة لتسمية الكحولات و ال phenols
+
+255
+00:23:59,120 --> 00:24:04,180
+لما نصل لل thyols اللي فيهم SH بناخد تسميتهم بشكل
+
+256
+00:24:04,180 --> 00:24:05,240
+منفصل
+
+257
+00:24:07,650 --> 00:24:14,410
+الان كنا عارفين شغلة ان الكحولات طالما فيهم OH إذا
+
+258
+00:24:14,410 --> 00:24:19,550
+اللي بيعملوا إيش هيدروجين bonding بيعملوا هيدروجين
+
+259
+00:24:19,550 --> 00:24:23,530
+bonding اللي مقصود بالهيدروجين bonding أن ذرة
+
+260
+00:24:23,530 --> 00:24:27,330
+الهيدروجين في الكحولات تحديدا بتكون محصورة بين
+
+261
+00:24:27,330 --> 00:24:32,400
+ذرتين أكسجينوبشكل عام إذا إنتوا متذكرين من المدارس
+
+262
+00:24:32,400 --> 00:24:37,380
+الـ hydrogen bonding بيكون إذا حصرت الهيدروجين بين
+
+263
+00:24:37,380 --> 00:24:43,440
+electronegative atoms محددة تلت ذرات شو هما؟
+
+264
+00:24:43,440 --> 00:24:48,680
+Oxygen و Nitrogen و Fluor سواء كان على اليمين أو
+
+265
+00:24:48,680 --> 00:24:52,360
+الشمال يعني بين تنتين Oxygen، بين تنتين Nitrogen،
+
+266
+00:24:52,360 --> 00:24:55,260
+بين تنتين Fluor، بين Oxygen وNitrogen، Oxygen و
+
+267
+00:24:55,260 --> 00:25:00,810
+Fluor الهيدروجين لما بتحصربين ذرتين
+
+268
+00:25:00,810 --> 00:25:05,130
+electronegative بهذا الشكل بتكون رابطة أساسية
+
+269
+00:25:05,130 --> 00:25:10,270
+رابطة أساسية مع ذرة و رابطة هيدروجينية مع الذرة
+
+270
+00:25:10,270 --> 00:25:15,130
+التانية يعني لو كنا بدنا نوضح بالظبط ال hydrogen
+
+271
+00:25:15,130 --> 00:25:20,670
+bonding في الألكوهول حتى ما نتغلب هيكون بهذا الشكل
+
+272
+00:25:20,670 --> 00:25:23,350
+ال hydrogen bonding في الألكوهول تخيلوا مثلا
+
+273
+00:25:23,350 --> 00:25:27,990
+الميثانول CH3O
+
+274
+00:25:29,040 --> 00:25:34,620
+H هذا الجزء و في كم زوج إلكتروناتها اتنين الان لو
+
+275
+00:25:34,620 --> 00:25:43,280
+بدى اجيب انا جزء كحول تاني CH3 OH وهي كمان زوجين
+
+276
+00:25:43,280 --> 00:25:53,130
+إلكترونات الان هذا جزء و هذاهذه الروابط الـ OH
+
+277
+00:25:53,130 --> 00:25:57,370
+اللي هنا رابطة أصلية Intramolecular bond و الـ OH
+
+278
+00:25:57,370 --> 00:26:01,510
+اللي هنا Intramolecular bond لو أنا إجيت أعملت بين
+
+279
+00:26:01,510 --> 00:26:07,070
+هذه الـ H و هذا زوج الإلكترونات رابطة هذا الرابطة
+
+280
+00:26:07,070 --> 00:26:13,230
+الهيدروجينية هذا الـ hydrogen bondهذا الهيدروجين
+
+281
+00:26:13,230 --> 00:26:18,630
+بوند الان لاحظوا معي ان الهيدروجين بوند ولا بحال
+
+282
+00:26:18,630 --> 00:26:23,090
+من الأحوال قوتها بتصل لقوة هذه الرابطة الأساسية
+
+283
+00:26:23,090 --> 00:26:27,450
+يعني هذه الهيدروجين بوند اللي بين الجزيئين قوتها
+
+284
+00:26:27,450 --> 00:26:32,070
+تقريبا بين خمسة لعشرة في المية من قوة الرابطة
+
+285
+00:26:32,070 --> 00:26:38,900
+الأصلية اللي هنا يعني هذه مقارنة بهذه خمسةالى 10%
+
+286
+00:26:38,900 --> 00:26:43,280
+من قوة الرابط الاصلية لهنا بناء على ذلك لو احنا
+
+287
+00:26:43,280 --> 00:26:49,460
+بدنا نعمل عملية تسخين او غليان نكسر روابط بالطاقة
+
+288
+00:26:49,460 --> 00:26:55,080
+اى رابط اللى بدأت نكسر هادي وبطير هذا الكحول لوحده
+
+289
+00:26:55,080 --> 00:26:59,840
+وبطير بتبخر هذا الكحول لوحدهبس ماحد بيقول اللي
+
+290
+00:26:59,840 --> 00:27:05,680
+بنكسر هذه الرابطة بالغليان، الغليان بيكسر الروابط
+
+291
+00:27:05,680 --> 00:27:10,040
+الـ Intermolecular forces، الروابط بين الجزيئات،
+
+292
+00:27:10,040 --> 00:27:14,080
+هذا جزيء و هذا جزيء بينهم رابطة ضعيفة هي اللي
+
+293
+00:27:14,080 --> 00:27:19,070
+بتتفكك و بتنكسر، بس بالتأكيدمش ال intramolecular
+
+294
+00:27:19,070 --> 00:27:22,330
+force الرابطة الأصلية اللي بتنكسر، لأ ال
+
+295
+00:27:22,330 --> 00:27:26,110
+intermolecular force يعني لو سخننا مثلا و بدنا
+
+296
+00:27:26,110 --> 00:27:30,110
+نعمل غليان أو كان بتبخر حتى مع ارتفاع الحرارة أي
+
+297
+00:27:30,110 --> 00:27:35,190
+رابطة اللي بتنكسر، هذه الرابطة بيصير كل جزء ينفصل
+
+298
+00:27:35,190 --> 00:27:41,000
+لإيش؟ لوحده، واضح؟طبعا انتبهوا معي وجود ال
+
+299
+00:27:41,000 --> 00:27:47,460
+hydrogen bond هادي بتخلي الكحول جزيئاته مترابطة
+
+300
+00:27:47,460 --> 00:27:52,040
+اذا نقطة غليانه نسبيا ايش بتكون عالية يعني هذا
+
+301
+00:27:52,040 --> 00:27:56,580
+الميثانول على سبيل المثال نقطة غليانه 65 درجة
+
+302
+00:27:56,580 --> 00:28:02,190
+مئويةمقارنة بمركبات مش فيها hydrogen bonding زي ال
+
+303
+00:28:02,190 --> 00:28:07,630
+الكنز تعتبر نقطة غليان عالية طيب لو قلنا بدنا
+
+304
+00:28:07,630 --> 00:28:13,610
+نقارن هذا الميثانول بالمية طب ليش؟ مع العلم أن
+
+305
+00:28:13,610 --> 00:28:20,130
+وزنها الجزائي أقل و
+
+306
+00:28:20,130 --> 00:28:24,800
+أنا هيدروجينيةعندى تلتين رابطين زى ما .. الميه
+
+307
+00:28:24,800 --> 00:28:29,020
+عندها الإمكانية بالظبط تعمل رابطتين هيدروجينيتين
+
+308
+00:28:29,020 --> 00:28:34,140
+مش رابط يعني الجزيئات بتترابط بشكل أقوى لما انتوا
+
+309
+00:28:34,140 --> 00:28:40,860
+بدكم تقولوا فى عندكم OHH نفترض الآن هذا الجزيئ لو
+
+310
+00:28:40,860 --> 00:28:47,560
+بدى أجيبله جزيئ تانى بهذا الشكل OHH وهنا كمان OHH
+
+311
+00:28:47,560 --> 00:28:49,740
+هى تلت جزيئات نفترض
+
+312
+00:28:52,840 --> 00:28:57,600
+الان هنا في عندي أزواج إلكترونات بيصير رابطة
+
+313
+00:28:57,600 --> 00:29:02,380
+هيدروجينية من هنا إذا أنا لو هذا بدي أفكه كام
+
+314
+00:29:02,380 --> 00:29:07,300
+رابطة هيدروجينية بدي أكسر؟ تنتين مش واحدة فالمي
+
+315
+00:29:07,300 --> 00:29:14,220
+لأنها H2 بيكون فيها روابط هيدروجينية إيش؟ أكتر من
+
+316
+00:29:14,220 --> 00:29:20,840
+الكحولاتلاحظوا يعني لو الإنسان بده يحكي شوية بمنطق
+
+317
+00:29:20,840 --> 00:29:27,440
+الفلسفة .. بمنطق الفلسفة الميه
+
+318
+00:29:27,440 --> 00:29:36,700
+يمكن مشروب لذيذ و أحل الحلال تمام؟ و الكحولات
+
+319
+00:29:36,700 --> 00:29:43,800
+بعضهاسام وبعضها خمر وبعضها مفيد يعني الكحولات
+
+320
+00:29:43,800 --> 00:29:50,300
+ماحدش يستعمل المصطلح الحديث إنه الكحولات بشكل عام
+
+321
+00:29:50,300 --> 00:29:57,460
+ضارة أو الكحولات محرمة لأ الكحولات عائلة عائلة
+
+322
+00:29:57,460 --> 00:30:04,440
+كبيرة هذه العائلة في منها مواد سامة في منها مواد
+
+323
+00:30:04,440 --> 00:30:11,100
+مسكرة في منها مواد مفيدةواضح؟ في منها مواد سامة
+
+324
+00:30:11,100 --> 00:30:16,420
+وفي مسكر وفي مفيد حسب طبيعة ال ايش ال R أو
+
+325
+00:30:16,420 --> 00:30:21,960
+المجموعة الان لو انا بدأ اتخيل ان الكحولات بنائها
+
+326
+00:30:21,960 --> 00:30:26,460
+الأساسي ال O H و اجي اقول أبسط الكحولات .. أبسط
+
+327
+00:30:26,460 --> 00:30:34,300
+الكحولات يعني هي عندي O H .. O H .. O H الان خليني
+
+328
+00:30:34,300 --> 00:30:43,510
+اجي احط هناقبل ال CH3 H أحط هنا CH3 و أحط هنا CH2
+
+329
+00:30:43,510 --> 00:30:51,780
+CH3لاحظوا أبسط مركّب هيكون الميّه طبعا الميّه ما
+
+330
+00:30:51,780 --> 00:30:55,980
+بنصنفهاش احنا مركّب عضوي لسبب بسيط ان مافيش فيها
+
+331
+00:30:55,980 --> 00:31:00,200
+carbon المركّب العضوي فيه carbon لكن لو الإنسان
+
+332
+00:31:00,200 --> 00:31:06,300
+بتأمل من ناحية الخواص الميّه كتير في خواصها بتشبه
+
+333
+00:31:06,300 --> 00:31:10,450
+الكحولاتكخواص كيميائية يعني لو بدأت أتكلم عن نقطة
+
+334
+00:31:10,450 --> 00:31:14,770
+غليان مرتفعة لو بدأ أتكلم عن تفاعل مع السوديوم لو
+
+335
+00:31:14,770 --> 00:31:19,490
+بدأ أتكلم بعد شوية لما أخد الحامضية هلاحظ أن
+
+336
+00:31:19,490 --> 00:31:24,310
+حامضية الماء زي حامضية الكحولات بالظبط يعني نفس
+
+337
+00:31:24,310 --> 00:31:29,630
+القوة الحامضية عشان هيك بنقول للبني آدم غسل بالمية
+
+338
+00:31:29,630 --> 00:31:34,350
+إيدك بنضره ولا لأ؟ بندرهش كلنا بنغسل بالمية طب
+
+339
+00:31:34,350 --> 00:31:39,160
+الكحولات؟بعد شوية لما تصيروا تعملوا مزارع بكتيريا
+
+340
+00:31:39,160 --> 00:31:41,840
+اللي بتخصصوا تحاليل طبية و إشي بعد ما يشتغلوا
+
+341
+00:31:41,840 --> 00:31:44,860
+بالبكتيريا بدهم يطهروا إيديهم بإيش بيغسلوا
+
+342
+00:31:44,860 --> 00:31:50,960
+بالإيثانول بالإيثانول اللي هو الكحول نفسه تبع
+
+343
+00:31:50,960 --> 00:31:56,420
+الخمر بيغسله فيه واضح؟ الآن لاحظوا أن الماء شراط
+
+344
+00:31:56,420 --> 00:32:04,660
+الميثانول poisonous الإيثانول
+
+345
+00:32:05,860 --> 00:32:10,060
+اللي هو الخمرة الاثانول
+
+346
+00:32:10,060 --> 00:32:13,760
+المكون الأساسي هو اللي بيسبب الاسكار في الخمر
+
+347
+00:32:13,760 --> 00:32:21,200
+والميه اللي هي أبسط مشروب فيهم الميه
+
+348
+00:32:21,200 --> 00:32:27,540
+مشروب جيد وممتاز هيجيكم كمان فكرة طالما ذكرنا هذا
+
+349
+00:32:27,540 --> 00:32:36,600
+الكلام هيجيكم كمان فكرة ان الاثانول في مشكلةإن هو
+
+350
+00:32:36,600 --> 00:32:42,540
+من أفضل المذيبات لإجراء التفاعلات الكيميائية ومطهر
+
+351
+00:32:42,540 --> 00:32:47,280
+يعني أنا بدي إياه يكون متوفر وبسعر رخيص يعني ال
+
+352
+00:32:47,280 --> 00:32:53,180
+letter يكون مثلا بتلاتة أربعة shekel بدولار واضح؟
+
+353
+00:32:58,850 --> 00:33:06,070
+بنغسل الأوان الذجاجية بالإيثانول بالإيثانول
+
+354
+00:33:06,070 --> 00:33:07,350
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+355
+00:33:07,350 --> 00:33:07,510
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+356
+00:33:07,510 --> 00:33:08,990
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+357
+00:33:08,990 --> 00:33:11,110
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+358
+00:33:11,110 --> 00:33:14,620
+بالإيثانول بالإصناعة الخمور هذه بحث ذاتها علم يعني
+
+359
+00:33:14,620 --> 00:33:19,560
+ملايين الفدانات بتكون مزروعة عنب اللي بيعملوا منه
+
+360
+00:33:19,560 --> 00:33:23,440
+الخمر و بدهوا مياه تكون بسعر غالي و زجاجة النبيذ
+
+361
+00:33:23,440 --> 00:33:27,100
+بسعر معين طب هى الاساس اللى فيها اللى بيعمل كل
+
+362
+00:33:27,100 --> 00:33:32,400
+المشاكل مين ال Ethanol اذا ال Ethanol صار مطلوب
+
+363
+00:33:32,400 --> 00:33:36,380
+عند العلماء و عند الكيميائين و عند الصناعة انه
+
+364
+00:33:36,380 --> 00:33:42,680
+ينباع رخيصو ممكن يتحضروا ينباع رخيص ومطلوب عند
+
+365
+00:33:42,680 --> 00:33:49,920
+الناس اللي بيصنعوا الخمر انه ينباع ايش؟ غالب لأنه
+
+366
+00:33:49,920 --> 00:33:54,300
+هذه صناعة في العالم الغربي و بدها تربح طب ايش
+
+367
+00:33:54,300 --> 00:33:57,940
+الحل؟ العالم والكيميائي بيقول بدي ايه ايه ايه ايه
+
+368
+00:33:57,940 --> 00:33:58,840
+ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه
+
+369
+00:33:58,840 --> 00:34:06,690
+ايه ايه ايه ايه ايه ايه ايه ايه ايهجالوا بسيطة
+
+370
+00:34:06,690 --> 00:34:14,050
+للكيميائيين جالولهم بنبيعكم إيثانول رخيص بس بشرط
+
+371
+00:34:14,050 --> 00:34:21,280
+عارفين إيش الشرط انسموا اللي ما تشربوهوشيعني هم
+
+372
+00:34:21,280 --> 00:34:24,220
+بدوا ميثاق أنه اللي بده يشرب إيثانول و اللي بده
+
+373
+00:34:24,220 --> 00:34:28,180
+يشرب خمره بده يدفع كتير طب ييجي بني آدم بده يلحق
+
+374
+00:34:28,180 --> 00:34:32,340
+عليهم بالله بيعوني إيثانول أنا بدي أستعمله للصناعة
+
+375
+00:34:32,340 --> 00:34:38,000
+و يروح يشربه برخيص خسروا الجماعة فقالوا بنبيعكيا
+
+376
+00:34:38,000 --> 00:34:44,900
+للصناعة بس ما تشربوش في ثقة متبادلة أنه يلتزم طب
+
+377
+00:34:44,900 --> 00:34:51,240
+إيش عملوه؟ قالوا بنحط فيه شوية سماللي لو شربته
+
+378
+00:34:51,240 --> 00:34:56,780
+تموت، تبقوا معاه، يعني لو الواحد شرب الاثانول بتاع
+
+379
+00:34:56,780 --> 00:35:03,800
+المختبر، بده يموت، إذا الإنسان شرب اثانول المختبر،
+
+380
+00:35:03,800 --> 00:35:07,240
+شو بده يصير فيه؟ بده يموت، طب إيش السم اللي بدكوا
+
+381
+00:35:07,240 --> 00:35:11,920
+تحطوه في الاثانول؟ جالي شوية ميثانول صغيرة،
+
+382
+00:35:11,920 --> 00:35:18,250
+الميثانول سام، يا بيموت يا بيعمىواضح؟ فال Ethanol
+
+383
+00:35:18,250 --> 00:35:21,330
+اللي في المختبر .. ال Ethanol اللي في المختبر
+
+384
+00:35:21,330 --> 00:35:26,570
+مسموم ممنوع أن البني أدم يشربه مخلوط بشوية إيش؟
+
+385
+00:35:26,570 --> 00:35:31,470
+Methanol. الآن إذا إجا لا سمح الله واحد جاهل بده
+
+386
+00:35:31,470 --> 00:35:35,510
+يحضر خمرة للغلابة و الفجرة و جاب منها ال Ethanol
+
+387
+00:35:35,510 --> 00:35:40,090
+الارخيص و حط في جزايز و باع و يلا اشربه شو بده
+
+388
+00:35:40,090 --> 00:35:48,340
+يصير فيهم؟ بدهم يموتواواضح؟ شو بده يصير فيهم؟ بدهم
+
+389
+00:35:48,340 --> 00:36:00,480
+يموتوا ويعيادوا بالله على أي حال، هذا الحادث مش
+
+390
+00:36:00,480 --> 00:36:06,270
+زمان صارجابل سنتين بس في ال 2013 عملها واحد
+
+391
+00:36:06,270 --> 00:36:10,750
+بالليبيا اول ما الدنيا صارت فوضى هناك راح اعمل هذا
+
+392
+00:36:10,750 --> 00:36:15,830
+الكلام و اقرأ التقرير لان انا بفرجيكوا تقرير من
+
+393
+00:36:15,830 --> 00:36:25,630
+تقرير حديث يعني لو بتطلع التاريخ 13.03.2003 2013
+
+394
+00:36:25,630 --> 00:36:26,950
+بالظبط
+
+395
+00:36:28,750 --> 00:36:34,410
+قدرين تقرأوا العنوان؟ ارتفاع عدد الموتى بسبب الخمر
+
+396
+00:36:34,410 --> 00:36:41,610
+المغشوشة لستين و هذا الكلام بتلت عشر تلاتة تداولته
+
+397
+00:36:41,610 --> 00:36:47,510
+وكلات الأنباء و ليش وصلوا لستين حالة و أكتر من
+
+398
+00:36:47,510 --> 00:36:52,310
+سبعميت حالة تسمم لأنهم
+
+399
+00:36:53,460 --> 00:36:58,040
+التسمم نجب عن مادة نجمة عن مادة مشروب كحول محل
+
+400
+00:36:58,040 --> 00:37:03,500
+الصناع والميثانول الذي يستخدم ايضا كوقود يضاف
+
+401
+00:37:03,500 --> 00:37:05,420
+احيانا بكميات صغيرة
+
+402
+00:37:13,840 --> 00:37:18,100
+يضاف أحيانا بكميات صغيرة في المشروبات الكحولية
+
+403
+00:37:18,100 --> 00:37:23,820
+التي تنتج سرا هو مش لزيادة المفعول يضاف يضاف أساسا
+
+404
+00:37:23,820 --> 00:37:29,800
+كتسميم لإيش لل إيثانول عشان الناس مايشربوش، الآن
+
+405
+00:37:29,800 --> 00:37:34,880
+هذا جاب إيثانول من تبع الكيمويات حطه عم الخمرة
+
+406
+00:37:36,080 --> 00:37:40,080
+ماتوا الناس اللي شربوا بالإضافة للناس اللي اتسمموا
+
+407
+00:37:40,080 --> 00:37:44,540
+و اللي أصيبوا بالإيش؟ بالعمى .. بالعمى و لذلك حتى
+
+408
+00:37:44,540 --> 00:37:48,240
+و أنتم تشتغلوا في المختبر نفترض أنكم كنتوا بتسخنوا
+
+409
+00:37:48,240 --> 00:37:53,060
+شغلة فيها إيثانول ما تعرضوش أنفسكم كتير لبخار
+
+410
+00:37:53,060 --> 00:37:58,680
+الإيثانولاللي تتنفسوا إيثانول يدخل لجسمكم من خلال
+
+411
+00:37:58,680 --> 00:38:03,660
+الجهاز التنفسي و يصل لعينيكم واضح؟ مثل هذه التجارب
+
+412
+00:38:03,660 --> 00:38:08,060
+و الأشياء لازم كيف تنشغل بخزانة أبخرة تشفطها مش
+
+413
+00:38:08,060 --> 00:38:13,300
+بني آدم بيعمل تجربة و بيسخن إيثانول و بيشتغل بدون
+
+414
+00:38:13,300 --> 00:38:17,040
+ما يعرف اللي بيشتغل كيميا هذه الكيميائيات بيتعامل
+
+415
+00:38:17,040 --> 00:38:22,520
+معاها كيف؟بأسلوب ضمن التحذيرات قبل ما بيمسك المادة
+
+416
+00:38:22,520 --> 00:38:27,600
+الإنسان بيكون فهمها و قرأ التحذيرات اللي عليها طيب
+
+417
+00:38:27,600 --> 00:38:33,020
+كيف يأتي السام يعني و بغسك يديه ممكن طبعا يعني؟ هو
+
+418
+00:38:33,020 --> 00:38:38,550
+ما بيأثرش في التغسيلفي التغسيل بأثرش لما يتناول من
+
+419
+00:38:38,550 --> 00:38:42,190
+الفم و يمتص جوا الجسم يعني مابتصيرش نسبة
+
+420
+00:38:42,190 --> 00:38:46,030
+absorption كبيرة اللى يدخل على الجسم بالذات اللى
+
+421
+00:38:46,030 --> 00:38:50,510
+هو بنسبة جليلة لكن لما بيتاخد كمشروب كلها النسبة
+
+422
+00:38:50,510 --> 00:38:55,430
+الجليلة بتيجي بتدخل الجسم طبعا أفضل كتير لو كنا
+
+423
+00:38:55,430 --> 00:39:01,010
+كمان بنغسل بإيثانول ناقي اللى مايصيرشنسبة ال
+
+424
+00:39:01,010 --> 00:39:04,270
+absorption الخفيفة لكن الواقع اللي موجود ان ال
+
+425
+00:39:04,270 --> 00:39:10,730
+ethanol الطبي بالذات ال ethanol المختبرة و عشان
+
+426
+00:39:10,730 --> 00:39:15,550
+هيك لما مرات بيجيبوا ethanol معين لصناعة الأدويات
+
+427
+00:39:16,370 --> 00:39:20,230
+بيكتبوا ان هذا إيثانول بنفع لصناعة الأدوية بيكون
+
+428
+00:39:20,230 --> 00:39:24,630
+مش فيه سموم ممكن يدوبوا فيه أدوية والموضوع خلاف في
+
+429
+00:39:24,630 --> 00:39:28,350
+موضوع انه يجوز استعماله او لا وقدر الإمكان الإنسان
+
+430
+00:39:28,350 --> 00:39:33,330
+لازم يتجنب الدواء اللي مدوب بإيثانول ما لم يكن
+
+431
+00:39:33,330 --> 00:39:39,130
+هناك يعني ضرورة يعني شديدة جدا و البدائل كتيرة في
+
+432
+00:39:39,130 --> 00:39:41,550
+كل الأحوال واضح الفكرة؟
+
+433
+00:39:49,990 --> 00:39:54,530
+الان في موضوع الـ hydrogen bonding قولنا بيخلي
+
+434
+00:39:54,530 --> 00:39:58,250
+نقاط الغليان مرتفعة يعني لو انا بدأ اطلع على
+
+435
+00:39:58,250 --> 00:40:04,330
+الميثانول 65 زادت كربونا الإيثانول بيصير 78
+
+436
+00:40:04,330 --> 00:40:10,030
+البروبانول 97 طبعا هذا كلام منطقي كل ما بتكبر
+
+437
+00:40:10,030 --> 00:40:14,970
+السلسلة شو بيصيرها نقطة الغليان؟بتزيد الان لو
+
+438
+00:40:14,970 --> 00:40:20,210
+اجينا نقارن الموضوع بذائبية هذه المراكبات في الميه
+
+439
+00:40:20,210 --> 00:40:24,690
+هذه المراكبات تمتاز انها مكونا من جزئين الجزء
+
+440
+00:40:24,690 --> 00:40:29,610
+الاول ال O H خلينا نعلمها بالاحمر في كل المراكبات
+
+441
+00:40:29,610 --> 00:40:36,030
+هذا جزء ال O H جزء ايش بنقول عنه احنا polar الان
+
+442
+00:40:36,030 --> 00:40:37,650
+الجزء التاني
+
+443
+00:40:47,350 --> 00:40:52,590
+السلسلة طولت فانجزوا اللي بيزيد قاعد ال non polar
+
+444
+00:40:56,610 --> 00:41:02,210
+ربما نستطيع ان نقول ان هذا الجزء polar يعني الجزء
+
+445
+00:41:02,210 --> 00:41:06,450
+ال polar فيه متغلب لكن لما تكبر السلسلة كتير الجزء
+
+446
+00:41:06,450 --> 00:41:12,330
+بالمجمل شو بنعمله؟ non polar بناء على ذلك الميه ال
+
+447
+00:41:12,330 --> 00:41:19,850
+H2O polar رجاء نقوله polar مش بولر مش بنانا،
+
+448
+00:41:19,850 --> 00:41:22,930
+pencil اه polar
+
+449
+00:41:25,090 --> 00:41:31,840
+لاحظوا القاعدة ايش بتقول Likedissolves like الان
+
+450
+00:41:31,840 --> 00:41:36,080
+هذا اعتبرنا polar بدوب في الميه هذا زيه هذا زيه
+
+451
+00:41:36,080 --> 00:41:41,100
+هذا اعتبرنا ايش non polar بدوب في الميه لأ و بناء
+
+452
+00:41:41,100 --> 00:41:45,280
+على ذلك بنصير قادرين نتخيل ليش ال methanol و ال
+
+453
+00:41:45,280 --> 00:41:48,460
+ethanol و ال probanol اللي هي الكحولات الصغيرة
+
+454
+00:41:48,460 --> 00:41:52,900
+بتدوب في الميه هذه الكحولات اللي في أول السلسلة
+
+455
+00:41:52,900 --> 00:41:58,820
+بنسميها احنا ايش lower alcohol يعني الكحولات الاش
+
+456
+00:41:59,790 --> 00:42:05,010
+لصغيرة و هذه الكحولات اللى تحت شو بنسميها higher
+
+457
+00:42:05,010 --> 00:42:09,750
+alcohols الان مين اللى بيدوبوا في الميه ال lower
+
+458
+00:42:09,750 --> 00:42:13,930
+alcohols ولا ال higher alcohols ال lower alcohols
+
+459
+00:42:13,930 --> 00:42:18,330
+are water soluble because they are considered to
+
+460
+00:42:18,330 --> 00:42:25,460
+be polar however higher alcohols arenon-polar and
+
+461
+00:42:25,460 --> 00:42:30,540
+so they are water insoluble الان بيستعملوا بدل
+
+462
+00:42:30,540 --> 00:42:33,520
+soluble و insoluble كلمة تانية عارفين شو بيسموها
+
+463
+00:42:33,520 --> 00:42:39,120
+missable missable لما نحط سائلين مع بعض و ينخلطوا
+
+464
+00:42:39,120 --> 00:42:44,140
+مع بعض بنستعملها بين السوائلفلما نقول completely
+
+465
+00:42:44,140 --> 00:42:49,780
+miscible يعني زي سائلين نحطهم في بعض و يخلطوا 100%
+
+466
+00:42:49,780 --> 00:42:54,220
+مثلا لو عمنا حطينا الاسيتون مع الميه الاسيتون
+
+467
+00:42:54,220 --> 00:42:57,340
+بيدوب في الميه الاثانول مع الميه الميثانول مع
+
+468
+00:42:57,340 --> 00:43:02,190
+الميه they are miscible لكن لو حطينا ال oilمع
+
+469
+00:43:02,190 --> 00:43:08,190
+الميّه بيكونوا immiscible أو non miscible يعني ما
+
+470
+00:43:08,190 --> 00:43:11,850
+بيدوبوش في بعض ف miscible تستعمل التعبير عن
+
+471
+00:43:11,850 --> 00:43:16,410
+السوائل اللي بتخلق مع بعضها البعض واضح؟ زي
+
+472
+00:43:16,410 --> 00:43:22,650
+soluble, miscibleالـ Hydrogen Bonding حكيناه
+
+473
+00:43:22,650 --> 00:43:25,970
+ووضحناه الآن ال acidity of alcohols الحقيقة موضوع
+
+474
+00:43:25,970 --> 00:43:30,630
+كبير يعني ربما يحتاج محاضرة كاملة بنبدأ فيه المرة
+
+475
+00:43:30,630 --> 00:43:35,090
+القادمة حمضية الكحولات إذا كان بإمكانك تراجعوا
+
+476
+00:43:35,090 --> 00:43:39,530
+مفهوم الحمضية مما تعلمته سابقا بيكون جيد
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8cf7712c4f942fec41da6272a8b6bbc92ced999f
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/VF-0zNtg5Zg_raw.srt
@@ -0,0 +1,1920 @@
+1
+00:00:20,210 --> 00:00:23,950
+بسم الله الرحمن الرحيم بنبدأ اليوم بالفصل السابع
+
+2
+00:00:23,950 --> 00:00:30,470
+هتلاحظوا أنه يعني هنركز كعائلة أساسية فيه على
+
+3
+00:00:30,470 --> 00:00:35,650
+مركبات ال alcohols اللي بنسميها بالعربي الكحولات
+
+4
+00:00:35,650 --> 00:00:42,850
+الآن بعض الكتب اللي بتدرس باللغة العربية هتلاقوها
+
+5
+00:00:42,850 --> 00:00:49,720
+موجودة باسم الأغوالإذا مرت عليكم هذه الكلمة يعني
+
+6
+00:00:49,720 --> 00:00:52,920
+الناس اللي جاي من السعودية بدهم يدرسوا عن ال
+
+7
+00:00:52,920 --> 00:00:57,020
+alcohols الكحولات بدل ما يقولوا الكحولات بيقولوا
+
+8
+00:00:57,020 --> 00:01:03,200
+إيش الأغوال جامع غول و بيستندوا للنص القرآن لا
+
+9
+00:01:03,200 --> 00:01:08,760
+فيها غولولهم عنها ينزفون واضح الفكرة فإذا قرأتها
+
+10
+00:01:08,760 --> 00:01:14,800
+بكتاب عربي باسم الأغوال فهي الكحولات، الآن ككيميا
+
+11
+00:01:14,800 --> 00:01:23,080
+الكحولات هي المركبات اللي ماخدة صيغة Rواضح الان
+
+12
+00:01:23,080 --> 00:01:30,020
+بيجي معها ال phenols إذا كانت ال OH متصلة بحلقة
+
+13
+00:01:30,020 --> 00:01:35,020
+أروماتية البنزين حالة خاصة بيكون نفس ال phenol لكن
+
+14
+00:01:35,020 --> 00:01:42,920
+المجموعة العامة AR بشكل عام ال AR OH يعني كل
+
+15
+00:01:42,920 --> 00:01:47,580
+المركبات الأروماتية إذا اتصلت ب OH they are
+
+16
+00:01:47,580 --> 00:01:55,420
+phenolsموازي لل alcohols لكن بإبدال ال oxygen هادى
+
+17
+00:01:55,420 --> 00:02:01,200
+ب Sulphur بيصير المركب ثيول بيصير المركب ثيول يعني
+
+18
+00:02:01,200 --> 00:02:08,060
+ماخد الصيغة العامة R RSH ثيولز ماخد الصيغة العامة
+
+19
+00:02:08,060 --> 00:02:15,060
+RSH طبعا اكيد هتقولوا طيب في موازي لل phenol بمعنى
+
+20
+00:02:15,060 --> 00:02:16,580
+اخر ايش بدى يكون ماخد AR
+
+21
+00:02:19,820 --> 00:02:25,320
+SH موجود أيضا بنسميه Theophenol
+
+22
+00:02:27,210 --> 00:02:33,170
+واضح؟ فهذه العائلات اللي طبعا الأساس فيها عائلة
+
+23
+00:02:33,170 --> 00:02:37,390
+الكحولات يعني هيكون التركيز الأكبر على الكحولات
+
+24
+00:02:37,390 --> 00:02:41,030
+اللي هي المركبات اللي ماخدة الصيغة العامة ROH من
+
+25
+00:02:41,030 --> 00:02:47,210
+الطرق بشكل خفيف للphenols للthiols للthiophenols
+
+26
+00:02:47,210 --> 00:02:53,270
+كل هذه الأشياء ان شاء الله بنقشها في هذا الفصل
+
+27
+00:02:56,090 --> 00:03:00,990
+إذا بدأنا بالكحولات .. إذا بدأنا بالكحولات و أول
+
+28
+00:03:00,990 --> 00:03:06,430
+شغلة دايما بنبدأ فيها كيف نسمي المركبات عادة بنسمي
+
+29
+00:03:06,430 --> 00:03:12,190
+الكحولات بإضافة النهاية all لاحظوا أن نظام التسمية
+
+30
+00:03:12,190 --> 00:03:15,910
+.. نظام التسمية في ال organ chemistry للناس اللي
+
+31
+00:03:15,910 --> 00:03:22,120
+بيتقنوه هو نظامبسيط جدا يعني مئات إذا ما قلناش
+
+32
+00:03:22,120 --> 00:03:27,540
+ملايين المراكبات الإنسان بتعلم قواعد بسيطة جدا
+
+33
+00:03:27,540 --> 00:03:32,840
+للتسمية وبيقدر يسيطر عليها الآن المفروض مع هذا
+
+34
+00:03:32,840 --> 00:03:37,440
+الوقت أنه صار نظام التسمية بالنسبة لناواضح في
+
+35
+00:03:37,440 --> 00:03:42,560
+عندنا سلسلة كربونية بدنا ناخد العدد تبعها بالنهاية
+
+36
+00:03:42,560 --> 00:03:48,980
+ميثين إيثين بروبين بيوتين بيوتين هكسين هبتين هدوله
+
+37
+00:03:48,980 --> 00:03:53,300
+صرنا حافظينهم الآن هذا الكلام إذا كانت السلسلة
+
+38
+00:03:53,300 --> 00:03:56,840
+كلها روابط أحدية وقلنا الkins الآن إذا صرنا في
+
+39
+00:03:56,840 --> 00:04:02,900
+الروابط الثنائية بنغير بنحط in بدل ال in في
+
+40
+00:04:02,900 --> 00:04:09,610
+الروابط الثلاثيةI الآن في الكحولات بنحط نهاية all
+
+41
+00:04:09,610 --> 00:04:14,450
+بعد شوية هنتعلم في ال aldehydes بنحط نهاية L في ال
+
+42
+00:04:14,450 --> 00:04:19,430
+ketone بنحط نهاية on في الأحماض الكربوكسيلية بنحط
+
+43
+00:04:19,430 --> 00:04:24,390
+نهاية oic acid بمعنى لو أنا رسمت خمس درات كربون
+
+44
+00:04:24,390 --> 00:04:29,690
+بقدر اقول ان المركبات اللي منهم عند اللزوم مثيل
+
+45
+00:04:30,860 --> 00:04:39,680
+للألكين ميثين اعفوا بنتين I mean بنتين بنتين بنتين
+
+46
+00:04:39,680 --> 00:04:42,860
+طبعا بحدد وين موقع ال double bond ده قصة بسيطة
+
+47
+00:04:42,860 --> 00:04:50,580
+بنتاي بنتانول بنتانال لل الديهايد بنتانون لل كيتون
+
+48
+00:04:50,580 --> 00:04:56,970
+بنتانوك أسد فصارت القصة فقط هي نهايةبتتغير في
+
+49
+00:04:56,970 --> 00:05:01,750
+نهاية الاسم و بنقدر نسمي المراكبات انتبهوا جيدا ان
+
+50
+00:05:01,750 --> 00:05:05,870
+ال all اللي بنستعمله انه نهاية الكحولات مافيش فيها
+
+51
+00:05:05,870 --> 00:05:13,330
+E في الآخر يعني OL بدون E ليش هتوجهنا المراكبات
+
+52
+00:05:13,770 --> 00:05:20,050
+بتنتهي ب OLE هذه مركبات حلقية تحتوي على حلقات
+
+53
+00:05:20,050 --> 00:05:24,430
+خماسية خارج موضوع دراستنا زي لما تسمعوا عن بعض
+
+54
+00:05:24,430 --> 00:05:29,870
+الأدوية مثلا المضادة للفطريات الدكتازول
+
+55
+00:05:29,870 --> 00:05:33,690
+والفلوكانازول الناس اللي عندهم فطريات أحيانا بين
+
+56
+00:05:33,690 --> 00:05:39,560
+أصابع رجليهم بيشتريوامضاد للفطريات دكتازول مشهور
+
+57
+00:05:39,560 --> 00:05:45,040
+كتير في البلد flucanazole هدولة هتلاحظوا اسمهم OLE
+
+58
+00:05:45,040 --> 00:05:50,580
+OLE هذه عائلة ثانية عائلة مركبات بحلقات يشمالها
+
+59
+00:05:50,580 --> 00:05:56,980
+خماسية فالكحولات اللي عندنا نهايتهم all الان لو
+
+60
+00:05:56,980 --> 00:06:03,680
+اجينا بدنا نسمي ب carbon واحد هنقول مثان allو هكذا
+
+61
+00:06:03,680 --> 00:06:08,060
+الان لاحظوا ال common nomenclature و مرات كتير
+
+62
+00:06:08,060 --> 00:06:12,920
+بنقولكوا ايش الاسم الشائع للمركب ايضا لها بشكل عام
+
+63
+00:06:12,920 --> 00:06:19,800
+قاعدة القاعدة تبعتها ذكر المجموعة ال alkyl group و
+
+64
+00:06:19,800 --> 00:06:25,300
+بعدين بنحط نهاية يعني لو كان هذا المركب CH3Cl كنت
+
+65
+00:06:25,300 --> 00:06:28,800
+اقول ال common nomenclature له مثل ال chloride
+
+66
+00:06:28,800 --> 00:06:35,950
+الان لما بيصير CH3OHمثل و ال OH عائلة الألكوهول
+
+67
+00:06:35,950 --> 00:06:40,250
+فبصير مثل ألكوهول و هكذا ف ال common nomenclature
+
+68
+00:06:40,250 --> 00:06:48,750
+بشكل عام بتيجي بذكر المجموعة و بعدها العائلة واضح؟
+
+69
+00:06:48,750 --> 00:06:52,590
+نفس الاشي هتلاحظوا مثلا في ال aldehydes
+
+70
+00:06:52,590 --> 00:07:00,950
+بروبلالديهيد مثلا بروبل المجموعة الديهيدالعائلة و
+
+71
+00:07:00,950 --> 00:07:06,830
+بال كيتون و بال أسد و بال كلورايتس و بالبرومايتس
+
+72
+00:07:08,520 --> 00:07:13,980
+توجه عام الان لو اتيت هنا اتطلعت هذا إيثانول طبعا
+
+73
+00:07:13,980 --> 00:07:19,200
+المجموعة إيثل بناء على ذلك بيكون إيثل ألكول هذا
+
+74
+00:07:19,200 --> 00:07:23,700
+البروبانول الان لاحظوا البروبانول الالكول ممكن
+
+75
+00:07:23,700 --> 00:07:26,580
+تكون ال OH على الكاربون الأولى أو على الكاربون
+
+76
+00:07:26,580 --> 00:07:30,880
+الثانية ولذلك بلزم نوضح بالترقيم فبنقول one
+
+77
+00:07:30,880 --> 00:07:36,890
+probanol و two probanolواضح؟ ال alcohol من
+
+78
+00:07:36,890 --> 00:07:41,470
+المركبات زيها زي ال alkenes اللي مرات كتير لازم
+
+79
+00:07:41,470 --> 00:07:45,870
+نوضح موقع المجموعة الوظيفية باستعمال ايش؟ أرقام
+
+80
+00:07:45,870 --> 00:07:50,290
+طبعا هنا لما قلنا one probanol لو كنا بدنا نسميه
+
+81
+00:07:50,290 --> 00:07:54,070
+بالاسم الشائع ال common name المجموعة هذه probel
+
+82
+00:07:54,070 --> 00:08:00,370
+.. probel alcohol الآن هذا two probanolأيزو برو
+
+83
+00:08:00,370 --> 00:08:01,430
+بالالكهول
+
+84
+00:08:15,670 --> 00:08:19,770
+CH حملة تنتين CH3 و كمان كربونة يعني العدد الكلي
+
+85
+00:08:19,770 --> 00:08:25,310
+أربعة إذا هذا شو بدي أسميه Isobutyl يمكن ال I
+
+86
+00:08:25,310 --> 00:08:30,290
+رايحة Isobutyl alcohol طبعا لو بدي أسميه أيوبكنومي
+
+87
+00:08:30,290 --> 00:08:35,990
+كليتشار بدي أسميه بالترقيم و ال OH بدي أكون ماخدة
+
+88
+00:08:35,990 --> 00:08:40,290
+أقل ترقيم يعني بدي أقول واحد اتنين تلاتة إذا هذا
+
+89
+00:08:40,290 --> 00:08:45,440
+one-probanolوانبروبانول على نمر اتنين شو بيحمل
+
+90
+00:08:45,440 --> 00:08:51,200
+الوانبروبانول مثل هاي أطول سلسلة واحد اتنين تلاتة
+
+91
+00:08:51,200 --> 00:08:57,520
+two مثل وانبروبانول فلازم احدد موقع ال ايش ال OH
+
+92
+00:08:57,520 --> 00:09:02,800
+two مثل وانبروبانوللو بننظر لهذا المركب على سبيل
+
+93
+00:09:02,800 --> 00:09:06,460
+المثال كمجموعة لو كنت بدي ال common nomenclature
+
+94
+00:09:06,460 --> 00:09:11,080
+له كمجموعة معروفة tertiary butyl اذا tertiary
+
+95
+00:09:11,080 --> 00:09:14,640
+butyl alcohol طب لو بدي اسميه بال iubac
+
+96
+00:09:14,640 --> 00:09:18,360
+nomenclature مرة تانية بدي اطول سلسلة خليني افترض
+
+97
+00:09:18,360 --> 00:09:24,700
+هي اطول سلسلة واحد اتنين تلاتة اذا هذا a-probanol
+
+98
+00:09:25,770 --> 00:09:31,010
+تو بروبانول لأن ال OH طالعة من موقع اتنين و على
+
+99
+00:09:31,010 --> 00:09:34,730
+اتنين ايضا ايش في عندكم مثل اذا two methyl two
+
+100
+00:09:34,730 --> 00:09:37,370
+probanol is tertiary butyl alcohol
+
+101
+00:09:45,170 --> 00:09:48,790
+الـ Common Nomenclature هو الـ tertiary butyl
+
+102
+00:09:48,790 --> 00:09:52,950
+alcohol في الـ Common Nomenclature الآن هذا
+
+103
+00:09:52,950 --> 00:09:57,150
+المُركّب لو بدأ أطلع على المجموعة اللي فيه لما
+
+104
+00:09:57,150 --> 00:10:02,690
+درفنا ال الكينز أخدنا مجموعتين أخدنا الفينل والألل
+
+105
+00:10:02,690 --> 00:10:06,870
+قلنا الألل اللي هو البروبين اللي بنخص منه هيدروجين
+
+106
+00:10:06,870 --> 00:10:10,780
+من هذا الموقعكل هذا الكلام السكوت اللي بلاحظه على
+
+107
+00:10:10,780 --> 00:10:15,740
+بعض الوجوه اللي أنا مارجعتش كتير هذه مشكلتها واضح؟
+
+108
+00:10:15,740 --> 00:10:20,700
+بدكوا تكونوا متذاكرين هذه المجموعة أخدناها بهذا
+
+109
+00:10:20,700 --> 00:10:25,380
+الشكل اسمها إيش؟ ألل الآن إذا إجي عليها chlorine
+
+110
+00:10:26,360 --> 00:10:30,580
+ألل كلورايت إذا إتي عليها بروم ألل برومايت إذا إتي
+
+111
+00:10:30,580 --> 00:10:36,960
+عليها OH ألل Alcohol فمن ناحية ال Alcohol اعرفنا
+
+112
+00:10:36,960 --> 00:10:42,520
+الآن لو كنا هذا ال ال alcohol بدنا نسميه بال Iopac
+
+113
+00:10:42,520 --> 00:10:48,840
+Nomenclature هنلاحظ إن في عندنا مجمعتين وظيفيتين
+
+114
+00:10:48,840 --> 00:10:53,280
+بدنا ننتبهالان التقاء المجموعات الوظيفية في
+
+115
+00:10:53,280 --> 00:10:58,520
+المركبات هذه تماما زى التقاء المجموعات الوظيفية
+
+116
+00:10:58,520 --> 00:11:02,660
+لما درسنا ال aromatic compounds متذكرين؟ اه قولنا
+
+117
+00:11:02,660 --> 00:11:07,420
+أبسط إشي ال alkanes بعدين ال alkenes و ال alkynes
+
+118
+00:11:07,420 --> 00:11:13,460
+بعدين مثلا ال OH بعدين ال ketone بعدين ال aldehyde
+
+119
+00:11:13,460 --> 00:11:19,890
+بعدين ال acidOkay فلو أنا بدي أجي أطلع أنه عندي OH
+
+120
+00:11:19,890 --> 00:11:27,370
+وعندي ال keen مين بده تكون العائلة ال OH وبناء على
+
+121
+00:11:27,370 --> 00:11:33,050
+ذلك المركب اللي عنده لازم ياخد النهاية all لأن
+
+122
+00:11:33,050 --> 00:11:37,950
+الشيء بتسمى باسم عائلته بياخد النهاية all طبعا هذا
+
+123
+00:11:37,950 --> 00:11:41,490
+لو بدي أطلع عليه واحد و الترقيم من وين هيكون؟
+
+124
+00:11:41,710 --> 00:11:46,310
+بنعندى الالكول واحد اتنين تلاتة طبعا بينا نسميه
+
+125
+00:11:46,310 --> 00:11:51,950
+بروبان all هو فيه double bond فبدل ال a بروبين
+
+126
+00:11:51,950 --> 00:11:58,050
+بيصير بروبين ال يعني لو مافيش عند انا هذا double
+
+127
+00:11:58,050 --> 00:12:02,910
+bond ايش كنت استعمل حرف ال a الآن صار double bond
+
+128
+00:12:02,910 --> 00:12:10,150
+ال الكن صار الكن صار بروبين all واضح بروبين all
+
+129
+00:12:10,150 --> 00:12:18,000
+لاحظواالعائلة إيش؟ all و هو فيه ألكين، الآن ال all
+
+130
+00:12:18,000 --> 00:12:24,470
+لازم نحدد موقعها و ال ألكين لازم نحدد موقعهابتدخل
+
+131
+00:12:24,470 --> 00:12:29,550
+الأرقام ال all على أي موقع جاية على واحد فبنكتب
+
+132
+00:12:29,550 --> 00:12:34,830
+two prob in one all بمعنى أن ال in موجودة على موقع
+
+133
+00:12:34,830 --> 00:12:39,890
+اتنين وال all على موقع واحد مرات هذا ممكن تشوفوه
+
+134
+00:12:39,890 --> 00:12:45,670
+بطريقة تانية يعني يكتبوه a prob و بعدين in و بعدين
+
+135
+00:12:45,670 --> 00:12:52,100
+all و يحددوا أن ال in على أي موقع اتنينع اتنين و
+
+136
+00:12:52,100 --> 00:12:56,080
+ال all على اي موقع لاحظوا اختلاف بسيط هنا في
+
+137
+00:12:56,080 --> 00:13:00,160
+الكتاب يعني عملنا تقطيع في الاسم حددنا وين ال in و
+
+138
+00:13:00,160 --> 00:13:05,100
+وين ال all هنا نفس الاشي و فهمنا ضمنا ان اتنين
+
+139
+00:13:05,100 --> 00:13:11,180
+اللي كتبت برا هي تعنيموقع ال in و ال all جنبها ف
+
+140
+00:13:11,180 --> 00:13:16,000
+two probine one all او prob two in one all هو نفس
+
+141
+00:13:16,000 --> 00:13:20,560
+الاسم يعني طريقتين لكتابة نفس الاسم في كتير طلاب
+
+142
+00:13:20,560 --> 00:13:25,320
+بيحبوا يقولوا في الأول هذا كله probine all جنب ال
+
+143
+00:13:25,320 --> 00:13:30,140
+in بالظبط بيحطوا الرقم جنب ال all بالظبط بيحطوا
+
+144
+00:13:30,140 --> 00:13:32,140
+الرقم تبعها
+
+145
+00:13:35,230 --> 00:13:39,650
+فهذه الطريقة اللي احنا بنستعملها لما بلتقى عندنا
+
+146
+00:13:39,650 --> 00:13:44,370
+اكثر من مجموعة وظيفية لاحظوا بدي اجي مباشرة على
+
+147
+00:13:44,370 --> 00:13:50,650
+هذا المثال لانه على نفس الفكرة طلع هذا المثال ايش
+
+148
+00:13:50,650 --> 00:13:58,180
+العائلات اللي موجودة فيه؟ال all و ال I ال ال مين
+
+149
+00:13:58,180 --> 00:14:04,120
+أعلى في الأولوية ال all إذا لو عديت العدد لكل واحد
+
+150
+00:14:04,120 --> 00:14:11,880
+اتنين تلاتة أربعة خمسة إيش هيكون كمركب؟ بين two
+
+151
+00:14:11,880 --> 00:14:17,960
+all بين two all هيني ذكرت المجموعتين لما أنا أقول
+
+152
+00:14:17,960 --> 00:14:21,240
+بين I
+
+153
+00:14:22,480 --> 00:14:29,500
+all هذه المجموعتين في I و في all الآن بلزم أن احدد
+
+154
+00:14:29,500 --> 00:14:36,960
+موقعهم ال all على اي موقع و ال I على تلاتة بنت
+
+155
+00:14:36,960 --> 00:14:42,140
+اثري I one all او لو كتبت اثري بنتين بتفهم ان ال
+
+156
+00:14:42,140 --> 00:14:47,160
+three هذي بتحدد موقع ال I اثري بنتين one all او
+
+157
+00:14:47,160 --> 00:14:52,500
+بنت اثري I one all نفس الفكرة تماماواضح؟ نفس
+
+158
+00:14:52,500 --> 00:14:57,360
+المُركّب فهذا الكلام اللي بيصير عندنا لما بلتقي
+
+159
+00:14:57,360 --> 00:15:05,380
+أكثر من مجموعة وظيفية الان ممكن يكون عندي alcohol
+
+160
+00:15:05,380 --> 00:15:13,120
+على حلقات ال alcohol على الحلقة .. الحلقة مش زي
+
+161
+00:15:13,120 --> 00:15:18,620
+السلسلةالحلقة ما لهاش بداية و نهاية يعني لما يكون
+
+162
+00:15:18,620 --> 00:15:24,200
+عندي انا خمس درات كربون كسلسلة باجي بقول بضحوط ال
+
+163
+00:15:24,200 --> 00:15:31,460
+OH هنا بسميه one بنتانول هنا two بنتانول three
+
+164
+00:15:31,460 --> 00:15:35,760
+بنتانول برجع طبعا two بنتانول اذا في عندي في
+
+165
+00:15:35,760 --> 00:15:40,150
+السلسلةone pentanol و two pentanol و three
+
+166
+00:15:40,150 --> 00:15:46,600
+pentanol لكن لو هذه السلسلة صارت حلقة خماسيةالان
+
+167
+00:15:46,600 --> 00:15:50,420
+سواء كتبة ال او اتش هان او هان او هان او هان او
+
+168
+00:15:50,420 --> 00:15:54,220
+هان جميع المواقع متكافئة مافيش فيها موقع واحد يعني
+
+169
+00:15:54,220 --> 00:15:58,800
+مابيقدرش الإنسان الحلقة يقول وين بدايتها ولذلك هذا
+
+170
+00:15:58,800 --> 00:16:04,200
+بتسمى cyclopentanol بدون ما نحطله one أو two لأن
+
+171
+00:16:04,200 --> 00:16:11,240
+كل المواقع واحد واضح؟ cyclopentanol لكن وقتش بيلزم
+
+172
+00:16:11,240 --> 00:16:16,930
+ترقيملو كان عندى اكتر من مجموعة عشان اشوف انه هذه
+
+173
+00:16:16,930 --> 00:16:23,610
+المجموعات انه هذه المجموعات هل يا ترى واحد اتنين
+
+174
+00:16:23,610 --> 00:16:27,250
+ولا واحد تلاتة ايش العلاقة بينها يعني لو كان
+
+175
+00:16:27,250 --> 00:16:31,030
+المركب بهذا الشكل والمجموعتين على جهة واحدة هذا
+
+176
+00:16:31,030 --> 00:16:38,930
+ايش هسميه one two cyclopentane by all all و all
+
+177
+00:16:39,860 --> 00:16:44,680
+Diol واضح؟ one two cycle وبنتين ديول وحنقول إيش
+
+178
+00:16:44,680 --> 00:16:52,140
+مالهم؟ sis طبعا ممكن نتخيل مركب بهذا الشكل لو
+
+179
+00:16:52,140 --> 00:16:58,860
+افترضنا هنا في عندنا OH وهنا في عندنا CL وإيجا
+
+180
+00:16:58,860 --> 00:17:05,680
+بدنا نسميه الآن أكيد ال alcohol أساس أقوى من ال CL
+
+181
+00:17:05,680 --> 00:17:12,110
+إذا المركب إيش هيكون؟cyclopentanol بتخيلوا من وين
+
+182
+00:17:12,110 --> 00:17:17,070
+بيبدأ الترقيم؟ و
+
+183
+00:17:17,070 --> 00:17:23,270
+بناء على ذلك مثل هذا المركب هيصير three .. فيش
+
+184
+00:17:23,270 --> 00:17:31,050
+ميتة ميتة في البنزينة خلصنا منها بس في البنزينة مش
+
+185
+00:17:31,050 --> 00:17:37,190
+في الحلقات إذا هذا three chloro cyclopentanol
+
+186
+00:17:37,370 --> 00:17:44,590
+بنتانول مش بنتين Cyclopentanol خلاص مابنكتبش one
+
+187
+00:17:44,590 --> 00:17:48,150
+لأنه يفهم ضمنا أن الترقيم بدأ من عندها يعني
+
+188
+00:17:48,150 --> 00:17:52,770
+مابنكتبش three chloro cyclopentane one all أو one
+
+189
+00:17:52,770 --> 00:17:57,310
+cyclopentanol لأ three chloro cyclopentanol و هكذا
+
+190
+00:17:57,310 --> 00:17:58,110
+واضح؟
+
+191
+00:18:00,740 --> 00:18:06,080
+الان احيانا بلتقي عندى الجزء ال aliphatic مع ال
+
+192
+00:18:06,080 --> 00:18:10,320
+aromatic وسبق احنا لما أخدنا ال aromatic compounds
+
+193
+00:18:10,320 --> 00:18:16,020
+نوّهنا لهذه النقطة قولنا انه ممكن نسمي المركب بأحد
+
+194
+00:18:16,020 --> 00:18:21,560
+طريقين اما ان نعتبر الأساس بنزين و اكتشف نعتبر
+
+195
+00:18:21,560 --> 00:18:26,600
+الأساس بنزينإذا هذه المجموعة اللي موجودة سهلة ولها
+
+196
+00:18:26,600 --> 00:18:31,460
+اسم بسيط عارفينه طب إذا مش مجموعة سهلة وملاش اسم
+
+197
+00:18:31,460 --> 00:18:39,480
+بسيط بعتبر نفسي بتعامل مع المركب كالكين بتعامل مع
+
+198
+00:18:39,480 --> 00:18:45,620
+المركب كالكين هذا الالكين هيطول سلسلة فيه في نمرة
+
+199
+00:18:45,620 --> 00:18:50,780
+واحد اتنين ويحمل مجموعة ايش اسم هذه المجموعة فنل
+
+200
+00:18:51,570 --> 00:18:56,330
+البنزينة اللى خصمنا منها H كمجموعة شو بنسميها؟ فنل
+
+201
+00:18:56,330 --> 00:18:59,970
+طبعا لاحظوا المركب اللى فيه ذرتين كربون هو اي
+
+202
+00:18:59,970 --> 00:19:06,470
+مركب؟ الاثانول اذا هذا لو كنا بنسميه شو هنسميه؟
+
+203
+00:19:06,470 --> 00:19:08,790
+two phenyl اثانول
+
+204
+00:19:11,950 --> 00:19:16,070
+يفهم على طول مباشرة طالما كتبنا two أن الـ O على
+
+205
+00:19:16,070 --> 00:19:22,430
+واحد و هذا على اتنين لاحظوا لو مثلا جبنا مركب شبيه
+
+206
+00:19:22,430 --> 00:19:29,390
+فيه بهذا الشكل هاي ذارتين كربون و حطينا الـ OH هنا
+
+207
+00:19:29,390 --> 00:19:30,970
+و البنزينة هنا
+
+208
+00:19:35,020 --> 00:19:39,080
+لاحظوا هذا isomer .. structural isomer كربون تنتين
+
+209
+00:19:39,080 --> 00:19:42,140
+كانت ال O H على الكربون الأولى و البنزينة على
+
+210
+00:19:42,140 --> 00:19:45,080
+التانية حطينا ال O H على الأولى و البنزينة على
+
+211
+00:19:45,080 --> 00:19:53,120
+الأولى فلو بدنا نيجي نقول بدنا نسمي هذا one phenyl
+
+212
+00:19:53,120 --> 00:20:00,180
+one ethanol مواد هيك إيثانول
+
+213
+00:20:03,690 --> 00:20:10,650
+عشان نضع رقم وان فينيل وان إيثانول واضح؟ وان فينيل
+
+214
+00:20:10,650 --> 00:20:14,350
+وان إيثانول عشان التوضيح يعني دائما في موضوع
+
+215
+00:20:14,350 --> 00:20:19,430
+الأرقام إذا حسيت أن في شيء confusing لازمة أرقام
+
+216
+00:20:19,430 --> 00:20:25,250
+إضافية نضعها مش لازمة أرقام إضافية مافيش داعي أن
+
+217
+00:20:25,250 --> 00:20:29,470
+نضع الأرقام مايتضح بدون أرقام لا نستعمل له الأرقام
+
+218
+00:20:29,470 --> 00:20:35,310
+يعني هنابتمشي بدون أرقام بيبطل فيه لزوم ان اكتب
+
+219
+00:20:35,310 --> 00:20:39,490
+one على سبيل المثال one cyclopentanol خلاص
+
+220
+00:20:39,490 --> 00:20:45,030
+فالأرقام عندها غرض ايش الغرض تبعها التوضيح لما
+
+221
+00:20:45,030 --> 00:20:49,350
+بيصير في لبس معين بحتاج ان نحط الأرقام عشان نوضح
+
+222
+00:20:49,350 --> 00:20:56,350
+بنستعملها طبعا ال aromatic alcohol انجاز التعبير
+
+223
+00:20:56,350 --> 00:21:03,280
+الأساس فيهمالفينول مر علينا تسميته وقلنا لو ال OH
+
+224
+00:21:03,280 --> 00:21:08,480
+مع ال نيترو مين الأساس الفينول إذا هذا para-nitro
+
+225
+00:21:08,480 --> 00:21:14,260
+أو four-nitroفينول لكن بدكوا تنتبهوا لنقطة أن نفس
+
+226
+00:21:14,260 --> 00:21:21,020
+هذه الفينول لو انوجدت مع مجموعات أعلى منها هترجع
+
+227
+00:21:21,020 --> 00:21:26,620
+لأصلها يعني هذه حامض C double bond O OH acidو
+
+228
+00:21:26,620 --> 00:21:31,380
+Alcohol من الأعلى؟ ال acid ولذلك هذا المُركّب
+
+229
+00:21:31,380 --> 00:21:35,620
+Benzoic acid على موقع Ortho، إيش عندكم؟
+
+230
+00:21:39,360 --> 00:21:44,420
+Orthohydroxy benzoic acid أو two hydroxy benzoic
+
+231
+00:21:44,420 --> 00:21:51,020
+acid طبعا هذا ماخد اسم شهرة salicylic acid ماخد
+
+232
+00:21:51,020 --> 00:21:54,720
+اسم شهرة ايش؟ salicylic acid ال salicylic acid هو
+
+233
+00:21:54,720 --> 00:21:59,760
+الحامض اللي بيطلو عادة من شجر الصفصاف وهو أساس
+
+234
+00:21:59,760 --> 00:22:05,680
+تحضير الأسبيرين هو أساس تحضير الأسبيرينيعني
+
+235
+00:22:05,680 --> 00:22:11,960
+الأسبيرين عادة بيشتقوا من هذا الحامض بيبدلوا ال H
+
+236
+00:22:11,960 --> 00:22:16,400
+اللي موجودة هنا على ال OH شايفين هذه ال OH هذه ال
+
+237
+00:22:16,400 --> 00:22:20,140
+H بنبدلها و بنحط مكانها هذه المجموعة
+
+238
+00:22:23,720 --> 00:22:26,920
+الناس اللي حفظوا معنا هذه المجموعة أخدناها لجامن
+
+239
+00:22:26,920 --> 00:22:32,840
+الـ acetic acid أسيتل فبصير المركب بدل salicylic
+
+240
+00:22:32,840 --> 00:22:35,140
+acid أسيتو
+
+241
+00:22:37,400 --> 00:22:42,540
+acetosalicylic acid هو الاسبيرين واضح فالاسبيرين
+
+242
+00:22:42,540 --> 00:22:47,480
+هو ال salicylic acid لكن انا شيلت منه ال H وحطيت
+
+243
+00:22:47,480 --> 00:22:52,940
+مكانها C double bond O CH3 فبصير الاسم المشهور
+
+244
+00:22:52,940 --> 00:23:00,080
+للاسبيرين ايش acetosalicylic acidacetosalicylic
+
+245
+00:23:00,080 --> 00:23:04,860
+acid المثال الأخير اللي موجود في هذا ال slide هو
+
+246
+00:23:04,860 --> 00:23:10,280
+التقاء الديهايد مع الكهول لحظة متذكرين لما قلنا
+
+247
+00:23:10,280 --> 00:23:16,280
+الكهول الديهايدي ماكتبوش COH CHO وهذا لو كنا
+
+248
+00:23:16,280 --> 00:23:21,960
+بنفسرها بال structure كيف بنفسرها بنفسرها C double
+
+249
+00:23:21,960 --> 00:23:29,730
+bond OHهذه تفاصيلها C double bond OH لما بنكتبها
+
+250
+00:23:29,730 --> 00:23:34,750
+كتابة كيف بنكتبها CHO فهذه مجموعة ال الديهايد الان
+
+251
+00:23:34,750 --> 00:23:39,350
+ال الديهايد أعلى من الألكوهول ولذلك المركب اللي
+
+252
+00:23:39,350 --> 00:23:46,490
+عندي هنا بنز الديهايد على موقع متا هيدروكسي
+
+253
+00:23:46,490 --> 00:23:50,050
+متا هيدروكسي بنز الديهايد
+
+254
+00:23:54,320 --> 00:23:59,120
+هذا بشكل عام بالنسبة لتسمية الكحولات و ال phenols
+
+255
+00:23:59,120 --> 00:24:04,180
+لما نصل لل thyols اللي فيهم SH بناخد تسميتهم بشكل
+
+256
+00:24:04,180 --> 00:24:05,240
+منفصل
+
+257
+00:24:07,650 --> 00:24:14,410
+الان كنا عارفين شغلة ان الكحولات طالما فيهم OH إذا
+
+258
+00:24:14,410 --> 00:24:19,550
+اللي بيعملوا إيش هيدروجين bonding بيعملوا هيدروجين
+
+259
+00:24:19,550 --> 00:24:23,530
+bonding اللي مقصود بالهيدروجين bonding أن ذرة
+
+260
+00:24:23,530 --> 00:24:27,330
+الهيدروجين في الكحولات تحديدا بتكون محصورة بين
+
+261
+00:24:27,330 --> 00:24:32,400
+ذرتين أكسجينوبشكل عام إذا إنتوا متذكرين من المدارس
+
+262
+00:24:32,400 --> 00:24:37,380
+الـ hydrogen bonding بيكون إذا حصرت الهيدروجين بين
+
+263
+00:24:37,380 --> 00:24:43,440
+electronegative atoms محددة تلت ذرات شو هما؟
+
+264
+00:24:43,440 --> 00:24:48,680
+Oxygen و Nitrogen و Fluor سواء كان على اليمين أو
+
+265
+00:24:48,680 --> 00:24:52,360
+الشمال يعني بين تنتين Oxygen، بين تنتين Nitrogen،
+
+266
+00:24:52,360 --> 00:24:55,260
+بين تنتين Fluor، بين Oxygen وNitrogen، Oxygen و
+
+267
+00:24:55,260 --> 00:25:00,810
+Fluor الهيدروجين لما بتحصربين ذرتين
+
+268
+00:25:00,810 --> 00:25:05,130
+electronegative بهذا الشكل بتكون رابطة أساسية
+
+269
+00:25:05,130 --> 00:25:10,270
+رابطة أساسية مع ذرة و رابطة هيدروجينية مع الذرة
+
+270
+00:25:10,270 --> 00:25:15,130
+التانية يعني لو كنا بدنا نوضح بالظبط ال hydrogen
+
+271
+00:25:15,130 --> 00:25:20,670
+bonding في الألكوهول حتى ما نتغلب هيكون بهذا الشكل
+
+272
+00:25:20,670 --> 00:25:23,350
+ال hydrogen bonding في الألكوهول تخيلوا مثلا
+
+273
+00:25:23,350 --> 00:25:27,990
+الميثانول CH3O
+
+274
+00:25:29,040 --> 00:25:34,620
+H هذا الجزء و في كم زوج إلكتروناتها اتنين الان لو
+
+275
+00:25:34,620 --> 00:25:43,280
+بدى اجيب انا جزء كحول تاني CH3 OH وهي كمان زوجين
+
+276
+00:25:43,280 --> 00:25:53,130
+إلكترونات الان هذا جزء و هذاهذه الروابط الـ OH
+
+277
+00:25:53,130 --> 00:25:57,370
+اللي هنا رابطة أصلية Intramolecular bond و الـ OH
+
+278
+00:25:57,370 --> 00:26:01,510
+اللي هنا Intramolecular bond لو أنا إجيت أعملت بين
+
+279
+00:26:01,510 --> 00:26:07,070
+هذه الـ H و هذا زوج الإلكترونات رابطة هذا الرابطة
+
+280
+00:26:07,070 --> 00:26:13,230
+الهيدروجينية هذا الـ hydrogen bondهذا الهيدروجين
+
+281
+00:26:13,230 --> 00:26:18,630
+بوند الان لاحظوا معي ان الهيدروجين بوند ولا بحال
+
+282
+00:26:18,630 --> 00:26:23,090
+من الأحوال قوتها بتصل لقوة هذه الرابطة الأساسية
+
+283
+00:26:23,090 --> 00:26:27,450
+يعني هذه الهيدروجين بوند اللي بين الجزيئين قوتها
+
+284
+00:26:27,450 --> 00:26:32,070
+تقريبا بين خمسة لعشرة في المية من قوة الرابطة
+
+285
+00:26:32,070 --> 00:26:38,900
+الأصلية اللي هنا يعني هذه مقارنة بهذه خمسةالى 10%
+
+286
+00:26:38,900 --> 00:26:43,280
+من قوة الرابط الاصلية لهنا بناء على ذلك لو احنا
+
+287
+00:26:43,280 --> 00:26:49,460
+بدنا نعمل عملية تسخين او غليان نكسر روابط بالطاقة
+
+288
+00:26:49,460 --> 00:26:55,080
+اى رابط اللى بدأت نكسر هادي وبطير هذا الكحول لوحده
+
+289
+00:26:55,080 --> 00:26:59,840
+وبطير بتبخر هذا الكحول لوحدهبس ماحد بيقول اللي
+
+290
+00:26:59,840 --> 00:27:05,680
+بنكسر هذه الرابطة بالغليان، الغليان بيكسر الروابط
+
+291
+00:27:05,680 --> 00:27:10,040
+الـ Intermolecular forces، الروابط بين الجزيئات،
+
+292
+00:27:10,040 --> 00:27:14,080
+هذا جزيء و هذا جزيء بينهم رابطة ضعيفة هي اللي
+
+293
+00:27:14,080 --> 00:27:19,070
+بتتفكك و بتنكسر، بس بالتأكيدمش ال intramolecular
+
+294
+00:27:19,070 --> 00:27:22,330
+force الرابطة الأصلية اللي بتنكسر، لأ ال
+
+295
+00:27:22,330 --> 00:27:26,110
+intermolecular force يعني لو سخننا مثلا و بدنا
+
+296
+00:27:26,110 --> 00:27:30,110
+نعمل غليان أو كان بتبخر حتى مع ارتفاع الحرارة أي
+
+297
+00:27:30,110 --> 00:27:35,190
+رابطة اللي بتنكسر، هذه الرابطة بيصير كل جزء ينفصل
+
+298
+00:27:35,190 --> 00:27:41,000
+لإيش؟ لوحده، واضح؟طبعا انتبهوا معي وجود ال
+
+299
+00:27:41,000 --> 00:27:47,460
+hydrogen bond هادي بتخلي الكحول جزيئاته مترابطة
+
+300
+00:27:47,460 --> 00:27:52,040
+اذا نقطة غليانه نسبيا ايش بتكون عالية يعني هذا
+
+301
+00:27:52,040 --> 00:27:56,580
+الميثانول على سبيل المثال نقطة غليانه 65 درجة
+
+302
+00:27:56,580 --> 00:28:02,190
+مئويةمقارنة بمركبات مش فيها hydrogen bonding زي ال
+
+303
+00:28:02,190 --> 00:28:07,630
+الكنز تعتبر نقطة غليان عالية طيب لو قلنا بدنا
+
+304
+00:28:07,630 --> 00:28:13,610
+نقارن هذا الميثانول بالمية طب ليش؟ مع العلم أن
+
+305
+00:28:13,610 --> 00:28:20,130
+وزنها الجزائي أقل و
+
+306
+00:28:20,130 --> 00:28:24,800
+أنا هيدروجينيةعندى تلتين رابطين زى ما .. الميه
+
+307
+00:28:24,800 --> 00:28:29,020
+عندها الإمكانية بالظبط تعمل رابطتين هيدروجينيتين
+
+308
+00:28:29,020 --> 00:28:34,140
+مش رابط يعني الجزيئات بتترابط بشكل أقوى لما انتوا
+
+309
+00:28:34,140 --> 00:28:40,860
+بدكم تقولوا فى عندكم OHH نفترض الآن هذا الجزيئ لو
+
+310
+00:28:40,860 --> 00:28:47,560
+بدى أجيبله جزيئ تانى بهذا الشكل OHH وهنا كمان OHH
+
+311
+00:28:47,560 --> 00:28:49,740
+هى تلت جزيئات نفترض
+
+312
+00:28:52,840 --> 00:28:57,600
+الان هنا في عندي أزواج إلكترونات بيصير رابطة
+
+313
+00:28:57,600 --> 00:29:02,380
+هيدروجينية من هنا إذا أنا لو هذا بدي أفكه كام
+
+314
+00:29:02,380 --> 00:29:07,300
+رابطة هيدروجينية بدي أكسر؟ تنتين مش واحدة فالمي
+
+315
+00:29:07,300 --> 00:29:14,220
+لأنها H2 بيكون فيها روابط هيدروجينية إيش؟ أكتر من
+
+316
+00:29:14,220 --> 00:29:20,840
+الكحولاتلاحظوا يعني لو الإنسان بده يحكي شوية بمنطق
+
+317
+00:29:20,840 --> 00:29:27,440
+الفلسفة .. بمنطق الفلسفة الميه
+
+318
+00:29:27,440 --> 00:29:36,700
+يمكن مشروب لذيذ و أحل الحلال تمام؟ و الكحولات
+
+319
+00:29:36,700 --> 00:29:43,800
+بعضهاسام وبعضها خمر وبعضها مفيد يعني الكحولات
+
+320
+00:29:43,800 --> 00:29:50,300
+ماحدش يستعمل المصطلح الحديث إنه الكحولات بشكل عام
+
+321
+00:29:50,300 --> 00:29:57,460
+ضارة أو الكحولات محرمة لأ الكحولات عائلة عائلة
+
+322
+00:29:57,460 --> 00:30:04,440
+كبيرة هذه العائلة في منها مواد سامة في منها مواد
+
+323
+00:30:04,440 --> 00:30:11,100
+مسكرة في منها مواد مفيدةواضح؟ في منها مواد سامة
+
+324
+00:30:11,100 --> 00:30:16,420
+وفي مسكر وفي مفيد حسب طبيعة ال ايش ال R أو
+
+325
+00:30:16,420 --> 00:30:21,960
+المجموعة الان لو انا بدأ اتخيل ان الكحولات بنائها
+
+326
+00:30:21,960 --> 00:30:26,460
+الأساسي ال O H و اجي اقول أبسط الكحولات .. أبسط
+
+327
+00:30:26,460 --> 00:30:34,300
+الكحولات يعني هي عندي O H .. O H .. O H الان خليني
+
+328
+00:30:34,300 --> 00:30:43,510
+اجي احط هناقبل ال CH3 H أحط هنا CH3 و أحط هنا CH2
+
+329
+00:30:43,510 --> 00:30:51,780
+CH3لاحظوا أبسط مركّب هيكون الميّه طبعا الميّه ما
+
+330
+00:30:51,780 --> 00:30:55,980
+بنصنفهاش احنا مركّب عضوي لسبب بسيط ان مافيش فيها
+
+331
+00:30:55,980 --> 00:31:00,200
+carbon المركّب العضوي فيه carbon لكن لو الإنسان
+
+332
+00:31:00,200 --> 00:31:06,300
+بتأمل من ناحية الخواص الميّه كتير في خواصها بتشبه
+
+333
+00:31:06,300 --> 00:31:10,450
+الكحولاتكخواص كيميائية يعني لو بدأت أتكلم عن نقطة
+
+334
+00:31:10,450 --> 00:31:14,770
+غليان مرتفعة لو بدأ أتكلم عن تفاعل مع السوديوم لو
+
+335
+00:31:14,770 --> 00:31:19,490
+بدأ أتكلم بعد شوية لما أخد الحامضية هلاحظ أن
+
+336
+00:31:19,490 --> 00:31:24,310
+حامضية الماء زي حامضية الكحولات بالظبط يعني نفس
+
+337
+00:31:24,310 --> 00:31:29,630
+القوة الحامضية عشان هيك بنقول للبني آدم غسل بالمية
+
+338
+00:31:29,630 --> 00:31:34,350
+إيدك بنضره ولا لأ؟ بندرهش كلنا بنغسل بالمية طب
+
+339
+00:31:34,350 --> 00:31:39,160
+الكحولات؟بعد شوية لما تصيروا تعملوا مزارع بكتيريا
+
+340
+00:31:39,160 --> 00:31:41,840
+اللي بتخصصوا تحاليل طبية و إشي بعد ما يشتغلوا
+
+341
+00:31:41,840 --> 00:31:44,860
+بالبكتيريا بدهم يطهروا إيديهم بإيش بيغسلوا
+
+342
+00:31:44,860 --> 00:31:50,960
+بالإيثانول بالإيثانول اللي هو الكحول نفسه تبع
+
+343
+00:31:50,960 --> 00:31:56,420
+الخمر بيغسله فيه واضح؟ الآن لاحظوا أن الماء شراط
+
+344
+00:31:56,420 --> 00:32:04,660
+الميثانول poisonous الإيثانول
+
+345
+00:32:05,860 --> 00:32:10,060
+اللي هو الخمرة الاثانول
+
+346
+00:32:10,060 --> 00:32:13,760
+المكون الأساسي هو اللي بيسبب الاسكار في الخمر
+
+347
+00:32:13,760 --> 00:32:21,200
+والميه اللي هي أبسط مشروب فيهم الميه
+
+348
+00:32:21,200 --> 00:32:27,540
+مشروب جيد وممتاز هيجيكم كمان فكرة طالما ذكرنا هذا
+
+349
+00:32:27,540 --> 00:32:36,600
+الكلام هيجيكم كمان فكرة ان الاثانول في مشكلةإن هو
+
+350
+00:32:36,600 --> 00:32:42,540
+من أفضل المذيبات لإجراء التفاعلات الكيميائية ومطهر
+
+351
+00:32:42,540 --> 00:32:47,280
+يعني أنا بدي إياه يكون متوفر وبسعر رخيص يعني ال
+
+352
+00:32:47,280 --> 00:32:53,180
+letter يكون مثلا بتلاتة أربعة shekel بدولار واضح؟
+
+353
+00:32:58,850 --> 00:33:06,070
+بنغسل الأوان الذجاجية بالإيثانول بالإيثانول
+
+354
+00:33:06,070 --> 00:33:06,070
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+355
+00:33:06,070 --> 00:33:07,350
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+356
+00:33:07,350 --> 00:33:07,350
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+357
+00:33:07,350 --> 00:33:07,350
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+358
+00:33:07,350 --> 00:33:07,510
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+359
+00:33:07,510 --> 00:33:08,990
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+360
+00:33:08,990 --> 00:33:11,110
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+361
+00:33:11,110 --> 00:33:11,110
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+362
+00:33:11,110 --> 00:33:14,620
+بالإيثانول بالإصناعة الخمور هذه بحث ذاتها علم يعني
+
+363
+00:33:14,620 --> 00:33:19,560
+ملايين الفدانات بتكون مزروعة عنب اللي بيعملوا منه
+
+364
+00:33:19,560 --> 00:33:23,440
+الخمر و بدهوا مياه تكون بسعر غالي و زجاجة النبيذ
+
+365
+00:33:23,440 --> 00:33:27,100
+بسعر معين طب هى الاساس اللى فيها اللى بيعمل كل
+
+366
+00:33:27,100 --> 00:33:32,400
+المشاكل مين ال Ethanol اذا ال Ethanol صار مطلوب
+
+367
+00:33:32,400 --> 00:33:36,380
+عند العلماء و عند الكيميائين و عند الصناعة انه
+
+368
+00:33:36,380 --> 00:33:42,680
+ينباع رخيصو ممكن يتحضروا ينباع رخيص ومطلوب عند
+
+369
+00:33:42,680 --> 00:33:49,920
+الناس اللي بيصنعوا الخمر انه ينباع ايش؟ غالب لأنه
+
+370
+00:33:49,920 --> 00:33:54,300
+هذه صناعة في العالم الغربي و بدها تربح طب ايش
+
+371
+00:33:54,300 --> 00:33:57,940
+الحل؟ العالم والكيميائي بيقول بدي ايه ايه ايه ايه
+
+372
+00:33:57,940 --> 00:33:58,840
+ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه
+
+373
+00:33:58,840 --> 00:34:06,690
+ايه ايه ايه ايه ايه ايه ايه ايه ايهجالوا بسيطة
+
+374
+00:34:06,690 --> 00:34:14,050
+للكيميائيين جالولهم بنبيعكم إيثانول رخيص بس بشرط
+
+375
+00:34:14,050 --> 00:34:21,280
+عارفين إيش الشرط انسموا اللي ما تشربوهوشيعني هم
+
+376
+00:34:21,280 --> 00:34:24,220
+بدوا ميثاق أنه اللي بده يشرب إيثانول و اللي بده
+
+377
+00:34:24,220 --> 00:34:28,180
+يشرب خمره بده يدفع كتير طب ييجي بني آدم بده يلحق
+
+378
+00:34:28,180 --> 00:34:32,340
+عليهم بالله بيعوني إيثانول أنا بدي أستعمله للصناعة
+
+379
+00:34:32,340 --> 00:34:38,000
+و يروح يشربه برخيص خسروا الجماعة فقالوا بنبيعكيا
+
+380
+00:34:38,000 --> 00:34:44,900
+للصناعة بس ما تشربوش في ثقة متبادلة أنه يلتزم طب
+
+381
+00:34:44,900 --> 00:34:51,240
+إيش عملوه؟ قالوا بنحط فيه شوية سماللي لو شربته
+
+382
+00:34:51,240 --> 00:34:56,780
+تموت، تبقوا معاه، يعني لو الواحد شرب الاثانول بتاع
+
+383
+00:34:56,780 --> 00:35:03,800
+المختبر، بده يموت، إذا الإنسان شرب اثانول المختبر،
+
+384
+00:35:03,800 --> 00:35:07,240
+شو بده يصير فيه؟ بده يموت، طب إيش السم اللي بدكوا
+
+385
+00:35:07,240 --> 00:35:11,920
+تحطوه في الاثانول؟ جالي شوية ميثانول صغيرة،
+
+386
+00:35:11,920 --> 00:35:18,250
+الميثانول سام، يا بيموت يا بيعمىواضح؟ فال Ethanol
+
+387
+00:35:18,250 --> 00:35:21,330
+اللي في المختبر .. ال Ethanol اللي في المختبر
+
+388
+00:35:21,330 --> 00:35:26,570
+مسموم ممنوع أن البني أدم يشربه مخلوط بشوية إيش؟
+
+389
+00:35:26,570 --> 00:35:31,470
+Methanol. الآن إذا إجا لا سمح الله واحد جاهل بده
+
+390
+00:35:31,470 --> 00:35:35,510
+يحضر خمرة للغلابة و الفجرة و جاب منها ال Ethanol
+
+391
+00:35:35,510 --> 00:35:40,090
+الارخيص و حط في جزايز و باع و يلا اشربه شو بده
+
+392
+00:35:40,090 --> 00:35:48,340
+يصير فيهم؟ بدهم يموتواواضح؟ شو بده يصير فيهم؟ بدهم
+
+393
+00:35:48,340 --> 00:36:00,480
+يموتوا ويعيادوا بالله على أي حال، هذا الحادث مش
+
+394
+00:36:00,480 --> 00:36:06,270
+زمان صارجابل سنتين بس في ال 2013 عملها واحد
+
+395
+00:36:06,270 --> 00:36:10,750
+بالليبيا اول ما الدنيا صارت فوضى هناك راح اعمل هذا
+
+396
+00:36:10,750 --> 00:36:15,830
+الكلام و اقرأ التقرير لان انا بفرجيكوا تقرير من
+
+397
+00:36:15,830 --> 00:36:25,630
+تقرير حديث يعني لو بتطلع التاريخ 13.03.2003 2013
+
+398
+00:36:25,630 --> 00:36:26,950
+بالظبط
+
+399
+00:36:28,750 --> 00:36:34,410
+قدرين تقرأوا العنوان؟ ارتفاع عدد الموتى بسبب الخمر
+
+400
+00:36:34,410 --> 00:36:41,610
+المغشوشة لستين و هذا الكلام بتلت عشر تلاتة تداولته
+
+401
+00:36:41,610 --> 00:36:47,510
+وكلات الأنباء و ليش وصلوا لستين حالة و أكتر من
+
+402
+00:36:47,510 --> 00:36:52,310
+سبعميت حالة تسمم لأنهم
+
+403
+00:36:53,460 --> 00:36:58,040
+التسمم نجب عن مادة نجمة عن مادة مشروب كحول محل
+
+404
+00:36:58,040 --> 00:37:03,500
+الصناع والميثانول الذي يستخدم ايضا كوقود يضاف
+
+405
+00:37:03,500 --> 00:37:05,420
+احيانا بكميات صغيرة
+
+406
+00:37:13,840 --> 00:37:18,100
+يضاف أحيانا بكميات صغيرة في المشروبات الكحولية
+
+407
+00:37:18,100 --> 00:37:23,820
+التي تنتج سرا هو مش لزيادة المفعول يضاف يضاف أساسا
+
+408
+00:37:23,820 --> 00:37:29,800
+كتسميم لإيش لل إيثانول عشان الناس مايشربوش، الآن
+
+409
+00:37:29,800 --> 00:37:34,880
+هذا جاب إيثانول من تبع الكيمويات حطه عم الخمرة
+
+410
+00:37:36,080 --> 00:37:40,080
+ماتوا الناس اللي شربوا بالإضافة للناس اللي اتسمموا
+
+411
+00:37:40,080 --> 00:37:44,540
+و اللي أصيبوا بالإيش؟ بالعمى .. بالعمى و لذلك حتى
+
+412
+00:37:44,540 --> 00:37:48,240
+و أنتم تشتغلوا في المختبر نفترض أنكم كنتوا بتسخنوا
+
+413
+00:37:48,240 --> 00:37:53,060
+شغلة فيها إيثانول ما تعرضوش أنفسكم كتير لبخار
+
+414
+00:37:53,060 --> 00:37:58,680
+الإيثانولاللي تتنفسوا إيثانول يدخل لجسمكم من خلال
+
+415
+00:37:58,680 --> 00:38:03,660
+الجهاز التنفسي و يصل لعينيكم واضح؟ مثل هذه التجارب
+
+416
+00:38:03,660 --> 00:38:08,060
+و الأشياء لازم كيف تنشغل بخزانة أبخرة تشفطها مش
+
+417
+00:38:08,060 --> 00:38:13,300
+بني آدم بيعمل تجربة و بيسخن إيثانول و بيشتغل بدون
+
+418
+00:38:13,300 --> 00:38:17,040
+ما يعرف اللي بيشتغل كيميا هذه الكيميائيات بيتعامل
+
+419
+00:38:17,040 --> 00:38:22,520
+معاها كيف؟بأسلوب ضمن التحذيرات قبل ما بيمسك المادة
+
+420
+00:38:22,520 --> 00:38:27,600
+الإنسان بيكون فهمها و قرأ التحذيرات اللي عليها طيب
+
+421
+00:38:27,600 --> 00:38:33,020
+كيف يأتي السام يعني و بغسك يديه ممكن طبعا يعني؟ هو
+
+422
+00:38:33,020 --> 00:38:38,550
+ما بيأثرش في التغسيلفي التغسيل بأثرش لما يتناول من
+
+423
+00:38:38,550 --> 00:38:42,190
+الفم و يمتص جوا الجسم يعني مابتصيرش نسبة
+
+424
+00:38:42,190 --> 00:38:46,030
+absorption كبيرة اللى يدخل على الجسم بالذات اللى
+
+425
+00:38:46,030 --> 00:38:50,510
+هو بنسبة جليلة لكن لما بيتاخد كمشروب كلها النسبة
+
+426
+00:38:50,510 --> 00:38:55,430
+الجليلة بتيجي بتدخل الجسم طبعا أفضل كتير لو كنا
+
+427
+00:38:55,430 --> 00:39:01,010
+كمان بنغسل بإيثانول ناقي اللى مايصيرشنسبة ال
+
+428
+00:39:01,010 --> 00:39:04,270
+absorption الخفيفة لكن الواقع اللي موجود ان ال
+
+429
+00:39:04,270 --> 00:39:10,730
+ethanol الطبي بالذات ال ethanol المختبرة و عشان
+
+430
+00:39:10,730 --> 00:39:15,550
+هيك لما مرات بيجيبوا ethanol معين لصناعة الأدويات
+
+431
+00:39:16,370 --> 00:39:20,230
+بيكتبوا ان هذا إيثانول بنفع لصناعة الأدوية بيكون
+
+432
+00:39:20,230 --> 00:39:24,630
+مش فيه سموم ممكن يدوبوا فيه أدوية والموضوع خلاف في
+
+433
+00:39:24,630 --> 00:39:28,350
+موضوع انه يجوز استعماله او لا وقدر الإمكان الإنسان
+
+434
+00:39:28,350 --> 00:39:33,330
+لازم يتجنب الدواء اللي مدوب بإيثانول ما لم يكن
+
+435
+00:39:33,330 --> 00:39:39,130
+هناك يعني ضرورة يعني شديدة جدا و البدائل كتيرة في
+
+436
+00:39:39,130 --> 00:39:41,550
+كل الأحوال واضح الفكرة؟
+
+437
+00:39:49,990 --> 00:39:54,530
+الان في موضوع الـ hydrogen bonding قولنا بيخلي
+
+438
+00:39:54,530 --> 00:39:58,250
+نقاط الغليان مرتفعة يعني لو انا بدأ اطلع على
+
+439
+00:39:58,250 --> 00:40:04,330
+الميثانول 65 زادت كربونا الإيثانول بيصير 78
+
+440
+00:40:04,330 --> 00:40:10,030
+البروبانول 97 طبعا هذا كلام منطقي كل ما بتكبر
+
+441
+00:40:10,030 --> 00:40:14,970
+السلسلة شو بيصيرها نقطة الغليان؟بتزيد الان لو
+
+442
+00:40:14,970 --> 00:40:20,210
+اجينا نقارن الموضوع بذائبية هذه المراكبات في الميه
+
+443
+00:40:20,210 --> 00:40:24,690
+هذه المراكبات تمتاز انها مكونا من جزئين الجزء
+
+444
+00:40:24,690 --> 00:40:29,610
+الاول ال O H خلينا نعلمها بالاحمر في كل المراكبات
+
+445
+00:40:29,610 --> 00:40:36,030
+هذا جزء ال O H جزء ايش بنقول عنه احنا polar الان
+
+446
+00:40:36,030 --> 00:40:37,650
+الجزء التاني
+
+447
+00:40:47,350 --> 00:40:52,590
+السلسلة طولت فانجزوا اللي بيزيد قاعد ال non polar
+
+448
+00:40:56,610 --> 00:41:02,210
+ربما نستطيع ان نقول ان هذا الجزء polar يعني الجزء
+
+449
+00:41:02,210 --> 00:41:06,450
+ال polar فيه متغلب لكن لما تكبر السلسلة كتير الجزء
+
+450
+00:41:06,450 --> 00:41:12,330
+بالمجمل شو بنعمله؟ non polar بناء على ذلك الميه ال
+
+451
+00:41:12,330 --> 00:41:19,850
+H2O polar رجاء نقوله polar مش بولر مش بنانا،
+
+452
+00:41:19,850 --> 00:41:22,930
+pencil اه polar
+
+453
+00:41:25,090 --> 00:41:31,840
+لاحظوا القاعدة ايش بتقول Likedissolves like الان
+
+454
+00:41:31,840 --> 00:41:36,080
+هذا اعتبرنا polar بدوب في الميه هذا زيه هذا زيه
+
+455
+00:41:36,080 --> 00:41:41,100
+هذا اعتبرنا ايش non polar بدوب في الميه لأ و بناء
+
+456
+00:41:41,100 --> 00:41:45,280
+على ذلك بنصير قادرين نتخيل ليش ال methanol و ال
+
+457
+00:41:45,280 --> 00:41:48,460
+ethanol و ال probanol اللي هي الكحولات الصغيرة
+
+458
+00:41:48,460 --> 00:41:52,900
+بتدوب في الميه هذه الكحولات اللي في أول السلسلة
+
+459
+00:41:52,900 --> 00:41:58,820
+بنسميها احنا ايش lower alcohol يعني الكحولات الاش
+
+460
+00:41:59,790 --> 00:42:05,010
+لصغيرة و هذه الكحولات اللى تحت شو بنسميها higher
+
+461
+00:42:05,010 --> 00:42:09,750
+alcohols الان مين اللى بيدوبوا في الميه ال lower
+
+462
+00:42:09,750 --> 00:42:13,930
+alcohols ولا ال higher alcohols ال lower alcohols
+
+463
+00:42:13,930 --> 00:42:18,330
+are water soluble because they are considered to
+
+464
+00:42:18,330 --> 00:42:25,460
+be polar however higher alcohols arenon-polar and
+
+465
+00:42:25,460 --> 00:42:30,540
+so they are water insoluble الان بيستعملوا بدل
+
+466
+00:42:30,540 --> 00:42:33,520
+soluble و insoluble كلمة تانية عارفين شو بيسموها
+
+467
+00:42:33,520 --> 00:42:39,120
+missable missable لما نحط سائلين مع بعض و ينخلطوا
+
+468
+00:42:39,120 --> 00:42:44,140
+مع بعض بنستعملها بين السوائلفلما نقول completely
+
+469
+00:42:44,140 --> 00:42:49,780
+miscible يعني زي سائلين نحطهم في بعض و يخلطوا 100%
+
+470
+00:42:49,780 --> 00:42:54,220
+مثلا لو عمنا حطينا الاسيتون مع الميه الاسيتون
+
+471
+00:42:54,220 --> 00:42:57,340
+بيدوب في الميه الاثانول مع الميه الميثانول مع
+
+472
+00:42:57,340 --> 00:43:02,190
+الميه they are miscible لكن لو حطينا ال oilمع
+
+473
+00:43:02,190 --> 00:43:08,190
+الميّه بيكونوا immiscible أو non miscible يعني ما
+
+474
+00:43:08,190 --> 00:43:11,850
+بيدوبوش في بعض ف miscible تستعمل التعبير عن
+
+475
+00:43:11,850 --> 00:43:16,410
+السوائل اللي بتخلق مع بعضها البعض واضح؟ زي
+
+476
+00:43:16,410 --> 00:43:22,650
+soluble, miscibleالـ Hydrogen Bonding حكيناه
+
+477
+00:43:22,650 --> 00:43:25,970
+ووضحناه الآن ال acidity of alcohols الحقيقة موضوع
+
+478
+00:43:25,970 --> 00:43:30,630
+كبير يعني ربما يحتاج محاضرة كاملة بنبدأ فيه المرة
+
+479
+00:43:30,630 --> 00:43:35,090
+القادمة حمضية الكحولات إذا كان بإمكانك تراجعوا
+
+480
+00:43:35,090 --> 00:43:39,530
+مفهوم الحمضية مما تعلمته سابقا بيكون جيد
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..cd9a7f815ca6f68d3936894f12a8434e2ec2fdab
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.json
@@ -0,0 +1 @@
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1.0}, {"id": 12, "seek": 30252, "start": 285.2, "end": 302.52, "text": "بالاختصار هيرجع ايش؟ هيرجع لالكول وسبق احنا انه وضحنا معنى الأكسادة ان هي في النهاية اما انها زيادة في المحتوى الاكسوجيني او نقص في محتوى الهيدروجيني", "tokens": [3555, 6027, 47283, 2655, 9381, 9640, 8032, 13546, 7435, 3615, 1975, 1829, 8592, 22807, 8032, 13546, 7435, 3615, 5296, 6027, 4117, 12610, 4032, 35457, 4587, 1975, 5016, 8315, 16472, 3224, 4032, 11242, 5016, 8315, 20449, 1863, 7578, 16247, 4117, 3794, 18513, 3660, 16472, 39896, 8978, 28239, 11296, 10632, 1975, 15042, 16472, 11296, 30767, 1829, 18513, 3660, 8978, 9673, 33753, 2407, 7578, 42963, 4117, 3794, 29245, 9957, 1829, 1975, 2407, 8717, 4587, 9381, 8978, 3714, 33753, 2407, 7578, 2423, 3224, 25708, 2288, 29245, 9957, 1829], "avg_logprob": -0.21783087604186113, "compression_ratio": 1.832214765100671, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 285.2, "end": 286.16, "word": "بالاختصار", "probability": 0.8638509114583334}, {"start": 286.16, "end": 287.56, "word": " هيرجع", "probability": 0.787261962890625}, {"start": 287.56, "end": 288.0, "word": " ايش؟", "probability": 0.649627685546875}, {"start": 288.0, "end": 288.84, "word": " هيرجع", "probability": 0.94873046875}, {"start": 288.84, "end": 290.02, "word": " لالكول", "probability": 0.6729736328125}, {"start": 290.02, "end": 290.82, "word": " وسبق", "probability": 0.8030598958333334}, {"start": 290.82, "end": 291.16, "word": " احنا", "probability": 0.9306640625}, {"start": 291.16, "end": 291.74, "word": " انه", "probability": 0.70458984375}, {"start": 291.74, "end": 292.24, "word": " وضحنا", "probability": 0.970458984375}, {"start": 292.24, "end": 292.6, "word": " معنى", "probability": 0.9422200520833334}, {"start": 292.6, "end": 293.42, "word": " الأكسادة", "probability": 0.6673583984375}, {"start": 293.42, "end": 293.74, "word": " ان", "probability": 0.86083984375}, {"start": 293.74, "end": 293.94, "word": " هي", "probability": 0.2464599609375}, {"start": 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cinnamon cinnamon يعني جرفة", "tokens": [2407, 46958, 5016, 22807, 8978, 30767, 36081, 37893, 3224, 13063, 24525, 2304, 3224, 30767, 36081, 13672, 2407, 11622, 45164, 5551, 3794, 2288, 8315, 13672, 2407, 11622, 4724, 1829, 9566, 1211, 3615, 9154, 3224, 30767, 36081, 13672, 1829, 31439, 2423, 44335, 16798, 68, 3495, 1479, 23758, 2423, 16798, 68, 3495, 1479, 13672, 1829, 13412, 995, 33911, 9957, 3224, 383, 3834, 6086, 13931, 20449, 11331, 1211, 28671, 44945, 11622, 9957, 4032, 3834, 6086, 23758, 3714, 31747, 3555, 9122, 10943, 1211, 23758, 24525, 2304, 3224, 6539, 5378, 304, 1479, 3495, 1479, 6539, 5378, 304, 1479, 3495, 1479, 10874, 995, 10632, 9154, 2423, 6539, 5378, 266, 6539, 5378, 266, 37495, 22653, 10874, 28480, 3660], "avg_logprob": -0.16905967850942868, "compression_ratio": 1.7677725118483412, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 336.32, "end": 337.0, "word": "واضح؟", "probability": 0.6759033203125}, {"start": 337.0, "end": 337.24, "word": " في", 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32277, 1829, 13672, 1829, 4724, 40228, 9566, 1829, 25724, 28480, 3660, 2423, 16572, 5016, 3660, 6055, 3555, 34268, 11296, 5296, 33456, 25724, 28480, 3660, 24525, 2304, 11296, 22969, 31439, 8608, 2304, 2407, 3224, 11933, 1829, 8592, 22807], "avg_logprob": -0.14554687678813935, "compression_ratio": 1.3916666666666666, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 361.48, "end": 362.74, "word": "واضح؟", "probability": 0.8936767578125}, {"start": 362.74, "end": 363.56, "word": " فهو", "probability": 0.95361328125}, {"start": 363.56, "end": 364.68, "word": " المركب", "probability": 0.833984375}, {"start": 364.68, "end": 365.64, "word": " الأساسي", "probability": 0.97216796875}, {"start": 365.64, "end": 365.88, "word": " اللي", "probability": 0.829833984375}, {"start": 365.88, "end": 366.36, "word": " بيعطي", "probability": 0.9271240234375}, {"start": 366.36, "end": 367.02, "word": " الجرفة", "probability": 0.8831380208333334}, {"start": 367.02, "end": 368.3, "word": " الريحة", "probability": 0.9078369140625}, {"start": 368.3, "end": 368.98, "word": " تبعتها", "probability": 0.96435546875}, {"start": 368.98, "end": 369.48, "word": " لأن", "probability": 0.615966796875}, {"start": 369.48, "end": 369.96, "word": " الجرفة", "probability": 0.95556640625}, {"start": 369.96, "end": 370.36, "word": " اسمها", "probability": 0.9658203125}, {"start": 370.36, "end": 370.98, "word": " cinnamon", "probability": 0.329833984375}, {"start": 370.98, "end": 371.78, "word": " هو", "probability": 0.63671875}, {"start": 371.78, "end": 372.24, "word": " سموه", "probability": 0.8697509765625}, {"start": 372.24, "end": 373.1, "word": " إيش؟", "probability": 0.8765869140625}], "temperature": 1.0}, {"id": 17, "seek": 40060, "start": 373.48, "end": 400.6, "text": "cinnamaldehyde مثلا بالالماني الجرفة اسمها zimt فبيسموه zimt aldehyde واضح zimt aldehyde هنا cinnamon cinnamaldehyde واضح فهذه الجرفة اللي احنا بنتناولها في النهاية هي aldehyde مر علينا سابقا ان الفانيلة هي عبارة عن aromatic aldehyde عليه مجموعة هيدروكسي وميثوكسي الفانيلين", "tokens": [20021, 5378, 304, 1479, 3495, 1479, 50113, 15040, 20666, 45340, 7649, 1829, 25724, 28480, 3660, 24525, 2304, 11296, 710, 332, 83, 6156, 21292, 38251, 2407, 3224, 710, 332, 83, 16798, 68, 3495, 1479, 4032, 46958, 5016, 710, 332, 83, 16798, 68, 3495, 1479, 34105, 6539, 5378, 266, 6539, 5378, 304, 1479, 3495, 1479, 4032, 46958, 5016, 6156, 3224, 24192, 25724, 28480, 3660, 13672, 1829, 1975, 5016, 8315, 44945, 2655, 8315, 12610, 11296, 8978, 28239, 11296, 10632, 39896, 16798, 68, 3495, 1479, 3714, 2288, 25894, 8315, 8608, 16758, 4587, 995, 16472, 27188, 7649, 26895, 3660, 39896, 6225, 3555, 9640, 3660, 18871, 45831, 16798, 68, 3495, 1479, 47356, 3714, 7435, 2304, 2407, 27884, 8032, 25708, 32887, 4117, 3794, 1829, 4032, 2304, 1829, 12984, 2407, 4117, 3794, 1829, 27188, 7649, 26895, 9957], "avg_logprob": -0.22199518726422238, "compression_ratio": 1.91324200913242, "no_speech_prob": 5.364418029785156e-07, "words": 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الان احنا اتفقنا لما بدى يعمل hydrate هدول المجمعتين مافيش فيهم تغيير طب ها شو بدى يصير ال C double bond O بتصير O H والمية بتضيف O H هذا بتصير benz aldehyde hydrate", "tokens": [3224, 1829, 2423, 44335, 16798, 68, 3495, 1479, 383, 3834, 6086, 422, 389, 2423, 7649, 1975, 5016, 8315, 1975, 2655, 5172, 4587, 8315, 5296, 15042, 47525, 7578, 7251, 25957, 1211, 5796, 4404, 8032, 3215, 12610, 9673, 7435, 2304, 34268, 9957, 19446, 41185, 8592, 8978, 16095, 6055, 17082, 1829, 13546, 23032, 3555, 8032, 995, 13412, 2407, 47525, 7578, 7251, 9381, 13546, 2423, 383, 3834, 6086, 422, 39894, 9381, 13546, 422, 389, 16070, 2304, 10632, 39894, 11242, 33911, 422, 389, 23758, 39894, 9381, 13546, 44335, 16798, 68, 3495, 1479, 5796, 4404], "avg_logprob": -0.2678819358348846, "compression_ratio": 1.6054054054054054, "no_speech_prob": 0.0, "words": [{"start": 1058.13, "end": 1058.51, "word": "هي", "probability": 0.56866455078125}, {"start": 1058.51, "end": 1058.63, "word": " ال", "probability": 0.71484375}, 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"temperature": 1.0}, {"id": 48, "seek": 113604, "start": 1110.9, "end": 1136.04, "text": "و لذلك هذا التفاعل بيصير نوعا ما تفاعل نظري مش تفاعل عملي يعني بيكون هذا ال الديهيد او ال ketone موجود بالنسبة 99.9% و هذا موجود بالنسبة قليلة جدا و لذلك معظم ال الديهيد و ال ketones بيكون ال position of equilibrium اتجاه الاتزان فيها هل هو باتجاه ال hydrate و لا باتجاه ال الديهيد او ال ketone", "tokens": [2407, 5296, 8848, 23275, 23758, 16712, 5172, 995, 30241, 4724, 1829, 9381, 13546, 8717, 45367, 995, 19446, 6055, 5172, 995, 30241, 8717, 19913, 16572, 37893, 6055, 5172, 995, 30241, 6225, 2304, 20292, 37495, 22653, 4724, 1829, 30544, 23758, 2423, 2423, 16254, 3224, 25708, 1975, 2407, 2423, 14979, 546, 3714, 29245, 23328, 20666, 1863, 35457, 3660, 11803, 13, 24, 4, 4032, 23758, 3714, 29245, 23328, 20666, 1863, 35457, 3660, 12174, 20292, 37977, 10874, 28259, 4032, 5296, 8848, 23275, 20449, 19913, 2304, 2423, 2423, 16254, 3224, 25708, 4032, 2423, 14979, 2213, 4724, 1829, 30544, 2423, 2535, 295, 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لأ؟ أكيد لأن high carbon حاملة OH", "tokens": [31187, 1975, 5016, 8315, 12174, 1211, 8315, 8978, 28242, 16247, 5016, 2407, 6027, 11778, 16373, 15042, 2423, 383, 3834, 6086, 422, 39894, 9381, 13546, 13931, 7251, 43020, 8978, 28242, 16247, 2304, 12984, 37977, 21136, 16758, 28671, 12602, 38251, 8315, 11296, 20666, 10721, 9778, 11242, 2288, 4032, 2423, 14962, 49242, 8032, 26108, 2304, 39627, 15730, 25124, 28820, 6024, 48506, 23758, 9673, 31747, 3555, 13672, 1829, 44650, 30544, 43242, 3224, 36632, 11242, 995, 8636, 326, 302, 304, 49429, 5296, 10721, 22807, 5551, 4117, 25708, 5296, 33456, 1090, 5954, 11331, 10943, 37977, 13931], "avg_logprob": -0.2529189580089443, "compression_ratio": 1.5304347826086957, "no_speech_prob": 0.0, "words": [{"start": 1633.01, "end": 1633.57, "word": "OH", "probability": 0.1492919921875}, {"start": 1633.57, "end": 1633.95, "word": " احنا", "probability": 0.7135416666666666}, {"start": 1633.95, "end": 1634.21, "word": " قلنا", "probability": 0.89453125}, {"start": 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"هذا", "probability": 0.876953125}, {"start": 1661.7, "end": 1663.26, "word": " Hemacetal", "probability": 0.627227783203125}, {"start": 1663.26, "end": 1663.78, "word": " لكن", "probability": 0.591796875}, {"start": 1663.78, "end": 1664.52, "word": " التفاعل", "probability": 0.93505859375}, {"start": 1664.52, "end": 1664.96, "word": " بهذه", "probability": 0.613525390625}, {"start": 1664.96, "end": 1665.56, "word": " الحالة", "probability": 0.9720052083333334}, {"start": 1665.56, "end": 1667.54, "word": " Intramolecular", "probability": 0.7440185546875}, {"start": 1667.54, "end": 1668.3, "word": " reaction", "probability": 0.63525390625}, {"start": 1668.3, "end": 1669.28, "word": " الان", "probability": 0.54010009765625}, {"start": 1669.28, "end": 1669.94, "word": " هذا", "probability": 0.85693359375}, {"start": 1669.94, "end": 1670.84, "word": " التفاعل", "probability": 0.9708251953125}, {"start": 1670.84, "end": 1671.8, "word": " جزء", "probability": 0.97119140625}, {"start": 1671.8, "end": 1672.0, "word": " من", "probability": 0.99169921875}, {"start": 1672.0, "end": 1672.98, "word": " أهميته", "probability": 0.923828125}, {"start": 1672.98, "end": 1673.84, "word": " انه", "probability": 0.5780029296875}, {"start": 1673.84, "end": 1673.94, "word": " في", "probability": 0.9404296875}, {"start": 1673.94, "end": 1674.08, "word": " ال", "probability": 0.904296875}, {"start": 1674.08, "end": 1675.04, "word": " biochemistry", "probability": 0.872802734375}], "temperature": 1.0}, {"id": 70, "seek": 170253, "start": 1676.87, "end": 1702.53, "text": "إذا عندكم فكرة خفيفة أو هيمر عليكم لما بناخد السكريات ال sugars احنا قولنا ال sugars they are polyhydroxy aldehydes او كيتون هى عبارة عن الديهيد او كيتون مع مجموعات اوقاتش كبيرة الديهيد لحاله بيعملش sugar ومجموعات اوقاتش كتيرة لحالها بتعملش ايش sugar فال sugar عبارة عن ايش", "tokens": [28814, 15730, 43242, 24793, 6156, 4117, 25720, 16490, 5172, 33911, 3660, 34051, 39896, 29973, 25894, 24793, 5296, 15042, 44945, 47283, 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فكرة", "probability": 0.9949544270833334}, {"start": 1677.87, "end": 1678.39, "word": " خفيفة", "probability": 0.9837646484375}, {"start": 1678.39, "end": 1678.57, "word": " أو", "probability": 0.779296875}, {"start": 1678.57, "end": 1679.13, "word": " هيمر", "probability": 0.639404296875}, {"start": 1679.13, "end": 1679.87, "word": " عليكم", "probability": 0.968994140625}, {"start": 1679.87, "end": 1680.49, "word": " لما", "probability": 0.880615234375}, {"start": 1680.49, "end": 1680.95, "word": " بناخد", "probability": 0.96875}, {"start": 1680.95, "end": 1682.07, "word": " السكريات", "probability": 0.946044921875}, {"start": 1682.07, "end": 1682.23, "word": " ال", "probability": 0.462890625}, {"start": 1682.23, "end": 1682.73, "word": " sugars", "probability": 0.7275390625}, {"start": 1682.73, "end": 1683.19, "word": " احنا", "probability": 0.8678385416666666}, {"start": 1683.19, "end": 1683.49, "word": " قولنا", "probability": 0.8509114583333334}, {"start": 1683.49, "end": 1683.61, "word": " ال", "probability": 0.59814453125}, {"start": 1683.61, "end": 1684.11, "word": " sugars", "probability": 0.97216796875}, {"start": 1684.11, "end": 1684.71, "word": " they", "probability": 0.60400390625}, {"start": 1684.71, "end": 1685.33, "word": " are", "probability": 0.95751953125}, {"start": 1685.33, "end": 1687.07, "word": " polyhydroxy", "probability": 0.72607421875}, {"start": 1687.07, "end": 1687.89, "word": " aldehydes", "probability": 0.805419921875}, {"start": 1687.89, "end": 1688.15, "word": " او", "probability": 0.80224609375}, {"start": 1688.15, "end": 1688.67, "word": " كيتون", "probability": 0.7600911458333334}, {"start": 1688.67, "end": 1689.29, "word": " هى", "probability": 0.621337890625}, {"start": 1689.29, "end": 1689.73, "word": " عبارة", "probability": 0.989501953125}, {"start": 1689.73, "end": 1689.95, "word": " عن", "probability": 0.99462890625}, {"start": 1689.95, "end": 1690.85, "word": " الديهيد", "probability": 0.62445068359375}, {"start": 1690.85, "end": 1691.37, "word": " او", "probability": 0.97265625}, {"start": 1691.37, "end": 1691.83, "word": " كيتون", "probability": 0.9658203125}, {"start": 1691.83, "end": 1692.05, "word": " مع", "probability": 0.98681640625}, {"start": 1692.05, "end": 1692.89, "word": " مجموعات", "probability": 0.97685546875}, {"start": 1692.89, "end": 1693.79, "word": " اوقاتش", "probability": 0.70843505859375}, {"start": 1693.79, "end": 1694.19, "word": " كبيرة", "probability": 0.98828125}, {"start": 1694.19, "end": 1694.67, "word": " الديهيد", "probability": 0.89599609375}, {"start": 1694.67, "end": 1695.09, "word": " لحاله", "probability": 0.9761962890625}, {"start": 1695.09, "end": 1695.61, "word": " بيعملش", "probability": 0.87646484375}, {"start": 1695.61, "end": 1696.03, "word": " sugar", "probability": 0.71044921875}, {"start": 1696.03, "end": 1697.51, "word": " ومجموعات", "probability": 0.8773600260416666}, {"start": 1697.51, "end": 1698.01, "word": " اوقاتش", "probability": 0.9383544921875}, {"start": 1698.01, "end": 1698.37, "word": " كتيرة", "probability": 0.9264322916666666}, {"start": 1698.37, "end": 1698.85, "word": " لحالها", "probability": 0.9884033203125}, {"start": 1698.85, "end": 1699.53, "word": " بتعملش", "probability": 0.952392578125}, {"start": 1699.53, "end": 1699.89, "word": " ايش", "probability": 0.7294108072916666}, {"start": 1699.89, "end": 1700.67, "word": " sugar", "probability": 0.289794921875}, {"start": 1700.67, "end": 1701.23, "word": " فال", "probability": 0.84228515625}, {"start": 1701.23, "end": 1701.49, "word": " sugar", "probability": 0.92919921875}, {"start": 1701.49, "end": 1701.93, "word": " عبارة", "probability": 0.996826171875}, {"start": 1701.93, "end": 1702.13, "word": " عن", "probability": 0.984375}, {"start": 1702.13, "end": 1702.53, "word": " ايش", "probability": 0.9484049479166666}], "temperature": 1.0}, {"id": 71, "seek": 171583, "start": 1703.75, "end": 1715.83, "text": "موجود فيه يا الديهايد يا كيتون ومجموعات OH's الآن طالما وجد فيه على جهة معينة الديهايد او كيتون هي C double bond او نتخيل هيك وع الجهة التانية", "tokens": [2304, 29245, 23328, 8978, 3224, 7251, 995, 2423, 16254, 11296, 25708, 35186, 9122, 36081, 11536, 4032, 2304, 7435, 2304, 45367, 9307, 13931, 311, 6024, 48506, 23032, 6027, 15042, 49610, 3215, 8978, 3224, 15844, 10874, 3224, 3660, 20449, 9957, 3660, 2423, 16254, 11296, 25708, 1975, 2407, 9122, 36081, 11536, 39896, 383, 3834, 6086, 1975, 2407, 8717, 2655, 9778, 26895, 39896, 4117, 4032, 3615, 25724, 3224, 3660, 16712, 7649, 10632], "avg_logprob": -0.3453351328338402, "compression_ratio": 1.5816993464052287, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1703.75, "end": 1704.37, "word": "موجود", "probability": 0.7300211588541666}, {"start": 1704.37, "end": 1704.73, "word": " فيه", "probability": 0.6978759765625}, {"start": 1704.73, "end": 1704.85, "word": " يا", "probability": 0.30157470703125}, {"start": 1704.85, "end": 1705.41, "word": " الديهايد", "probability": 0.724853515625}, {"start": 1705.41, "end": 1705.59, "word": " يا", "probability": 0.257080078125}, {"start": 1705.59, "end": 1706.13, "word": " كيتون", "probability": 0.8232421875}, {"start": 1706.13, "end": 1707.03, "word": " ومجموعات", "probability": 0.930419921875}, {"start": 1707.03, "end": 1707.95, "word": " OH's", "probability": 0.375244140625}, {"start": 1707.95, "end": 1708.47, "word": " الآن", "probability": 0.55535888671875}, {"start": 1708.47, "end": 1709.01, "word": " طالما", "probability": 0.962890625}, {"start": 1709.01, "end": 1709.45, "word": " وجد", "probability": 0.6591796875}, {"start": 1709.45, "end": 1709.99, "word": " فيه", "probability": 0.902099609375}, {"start": 1709.99, "end": 1710.17, "word": " على", "probability": 0.8173828125}, {"start": 1710.17, "end": 1710.55, "word": " جهة", "probability": 0.9866536458333334}, {"start": 1710.55, "end": 1711.29, "word": " معينة", "probability": 0.9754231770833334}, {"start": 1711.29, "end": 1711.97, "word": " الديهايد", "probability": 0.94775390625}, {"start": 1711.97, "end": 1712.23, "word": " او", "probability": 0.84033203125}, {"start": 1712.23, "end": 1712.63, "word": " كيتون", "probability": 0.9376627604166666}, {"start": 1712.63, "end": 1712.81, "word": " هي", "probability": 0.1904296875}, {"start": 1712.81, "end": 1713.03, "word": " C", "probability": 0.464111328125}, {"start": 1713.03, "end": 1713.25, "word": " double", "probability": 0.211181640625}, {"start": 1713.25, "end": 1713.59, "word": " bond", "probability": 0.93505859375}, {"start": 1713.59, "end": 1713.77, "word": " او", "probability": 0.5384521484375}, {"start": 1713.77, "end": 1714.19, "word": " نتخيل", "probability": 0.89990234375}, {"start": 1714.19, "end": 1714.49, "word": " هيك", "probability": 0.880615234375}, {"start": 1714.49, "end": 1714.95, "word": " وع", "probability": 0.806884765625}, {"start": 1714.95, "end": 1715.33, "word": " الجهة", "probability": 0.7226155598958334}, {"start": 1715.33, "end": 1715.83, "word": " التانية", "probability": 0.9876302083333334}], "temperature": 1.0}, {"id": 72, "seek": 173896, "start": 1717.06, "end": 1738.96, "text": "أو أتشز ممكن هذه ال أو أتشز تسكر على ال الديهايد أو ال كيتون أكيد بتعمل في هذه الحالة hemeacetal بس لما تسكر بدل ما ال sugar كان عامل سلسلة بهذا الشكل ال chain بيصير إيش in the cyclic form كل كمار عليكوا أن السكر بيكون في ال chain form", "tokens": [10721, 2407, 5551, 2655, 8592, 11622, 3714, 43020, 29538, 2423, 34051, 5551, 2655, 8592, 11622, 6055, 3794, 37983, 15844, 2423, 2423, 16254, 11296, 25708, 34051, 2423, 9122, 36081, 11536, 5551, 4117, 25708, 39894, 25957, 1211, 8978, 29538, 21542, 6027, 3660, 415, 1398, 326, 302, 304, 4724, 3794, 5296, 15042, 6055, 3794, 37983, 47525, 1211, 19446, 2423, 5076, 25961, 6225, 10943, 1211, 8608, 1211, 3794, 37977, 39627, 15730, 25124, 28820, 2423, 5021, 4724, 1829, 9381, 13546, 11933, 1829, 8592, 294, 264, 38154, 1050, 1254, 28242, 9122, 2304, 9640, 25894, 4117, 14407, 14739, 21136, 37983, 4724, 1829, 30544, 8978, 2423, 5021, 1254], "avg_logprob": -0.26779083332212844, "compression_ratio": 1.7453703703703705, "no_speech_prob": 0.0, "words": [{"start": 1717.06, "end": 1717.4, "word": "أو", "probability": 0.4790802001953125}, {"start": 1717.4, "end": 1718.04, "word": " أتشز", "probability": 0.72125244140625}, {"start": 1718.04, "end": 1718.7, "word": " ممكن", "probability": 0.720947265625}, {"start": 1718.7, "end": 1719.06, "word": " هذه", "probability": 0.744140625}, {"start": 1719.06, "end": 1719.24, "word": " ال", "probability": 0.7255859375}, {"start": 1719.24, "end": 1719.38, "word": " أو", "probability": 0.1678466796875}, {"start": 1719.38, "end": 1719.88, "word": " أتشز", "probability": 0.9578857421875}, {"start": 1719.88, "end": 1720.48, "word": " تسكر", "probability": 0.7117513020833334}, {"start": 1720.48, "end": 1720.98, "word": " على", "probability": 0.7900390625}, {"start": 1720.98, "end": 1721.12, "word": " ال", "probability": 0.76171875}, {"start": 1721.12, "end": 1721.58, "word": " الديهايد", "probability": 0.6976318359375}, {"start": 1721.58, "end": 1721.76, "word": " أو", "probability": 0.59228515625}, {"start": 1721.76, "end": 1721.92, "word": " ال", "probability": 0.55419921875}, {"start": 1721.92, "end": 1722.42, "word": " كيتون", "probability": 0.8084309895833334}, {"start": 1722.42, "end": 1723.62, "word": " أكيد", "probability": 0.7836100260416666}, {"start": 1723.62, "end": 1724.4, "word": " بتعمل", "probability": 0.8699544270833334}, {"start": 1724.4, "end": 1724.52, "word": " في", "probability": 0.85546875}, {"start": 1724.52, "end": 1724.74, "word": " هذه", "probability": 0.8896484375}, {"start": 1724.74, "end": 1725.6, "word": " الحالة", "probability": 0.984375}, {"start": 1725.6, "end": 1726.64, "word": " hemeacetal", "probability": 0.6638916015625}, {"start": 1726.64, "end": 1727.14, "word": " بس", "probability": 0.917236328125}, {"start": 1727.14, "end": 1727.34, "word": " لما", "probability": 0.961669921875}, {"start": 1727.34, "end": 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Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone Cyclohexanone", "tokens": [34, 6277, 1445, 292, 2044, 45164, 6225, 42213, 39237, 20449, 2423, 39184, 10295, 66, 752, 675, 87, 282, 546, 8032, 8848, 1829, 2423, 39184, 383, 3834, 6086, 422, 11933, 1829, 8592, 8032, 2655, 9381, 13546, 22807, 13931, 37037, 1829, 2423, 39184, 2033, 13412, 2407, 8032, 38251, 1829, 3224, 22807, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 10295, 66, 752, 675, 87, 282, 546, 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{"start": 2243.53, "end": 2243.65, "word": " Cyclohexanone", "probability": 0.9896065848214286}, {"start": 2243.65, "end": 2243.81, "word": " Cyclohexanone", "probability": 0.9905133928571429}, {"start": 2243.81, "end": 2243.81, "word": " Cyclohexanone", "probability": 0.9911411830357143}, {"start": 2243.81, "end": 2244.51, "word": " Cyclohexanone", "probability": 0.9917689732142857}, {"start": 2244.51, "end": 2244.51, "word": " Cyclohexanone", "probability": 0.9921875}, {"start": 2244.51, "end": 2245.03, "word": " Cyclohexanone", "probability": 0.9924665178571429}, {"start": 2245.03, "end": 2246.93, "word": " Cyclohexanone", "probability": 0.9928152901785714}, {"start": 2246.93, "end": 2246.93, "word": " Cyclohexanone", "probability": 0.9930943080357143}, {"start": 2246.93, "end": 2246.93, "word": " Cyclohexanone", "probability": 0.9933733258928571}, {"start": 2246.93, "end": 2246.93, "word": " Cyclohexanone", "probability": 0.9937220982142857}, {"start": 2246.93, "end": 2246.93, 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"probability": 0.86572265625}, {"start": 2281.86, "end": 2282.1, "word": " صح", "probability": 0.987548828125}, {"start": 2282.1, "end": 2282.3, "word": " ولا", "probability": 0.953125}, {"start": 2282.3, "end": 2282.6, "word": " لأ", "probability": 0.90283203125}], "temperature": 1.0}, {"id": 96, "seek": 231333, "start": 2284.59, "end": 2313.33, "text": "لازم في الأصل تكون عارفة الـ Benzaldehyde مجرد ما نقولها سيانو هيدرين الـ C بابل بوند O OH OHIJNQCN مش عملية صعبة Benzaldehyde cyanohydrin واضح الفكرة؟ لاحظوا أنا كاتب له common name نفس الـ Benzaldehyde cyanohydrin له common name Manbilonitride", "tokens": [1211, 31377, 2304, 8978, 16247, 36520, 6055, 30544, 6225, 9640, 5172, 3660, 2423, 39184, 3964, 89, 304, 1479, 3495, 1479, 3714, 7435, 2288, 3215, 19446, 8717, 39648, 11296, 8608, 1829, 7649, 2407, 8032, 25708, 2288, 9957, 2423, 39184, 383, 4724, 16758, 1211, 4724, 11536, 3215, 422, 13931, 13931, 40, 41, 45, 48, 34, 45, 37893, 6225, 42213, 10632, 20328, 3615, 49401, 3964, 89, 304, 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قولنا oil of almond اللوز بالانجليزي بالالماني mandel ومن هنا استعمل mandilo nitral mandel من اللوز يعني كتير من ال common name علاقة في إيش", "tokens": [22396, 10720, 7411, 338, 20666, 45340, 7649, 1829, 37495, 22653, 5296, 2407, 11622, 16472, 2655, 14407, 39894, 15730, 37983, 9957, 12174, 36150, 13412, 2407, 10632, 5296, 15042, 5551, 9778, 3215, 8315, 2423, 44335, 304, 1479, 3495, 1479, 12174, 12610, 8315, 3184, 295, 29506, 2423, 1211, 2407, 11622, 20666, 7649, 7435, 20292, 11622, 1829, 20666, 45340, 7649, 1829, 7411, 338, 4032, 27842, 34105, 44713, 25957, 1211, 7411, 10720, 10900, 2155, 7411, 338, 9154, 13672, 2407, 11622, 37495, 22653, 9122, 2655, 13546, 9154, 2423, 2689, 1315, 11203, 995, 28671, 8978, 11933, 1829, 8592], "avg_logprob": -0.26222826734833093, "compression_ratio": 1.6748768472906403, "no_speech_prob": 0.0, "words": [{"start": 2314.29, "end": 2315.15, "word": "mandilo", "probability": 0.3641357421875}, {"start": 2315.15, "end": 2316.23, "word": " mandel", 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"word": " قولنا", "probability": 0.8030598958333334}, {"start": 2325.79, "end": 2326.19, "word": " oil", "probability": 0.8525390625}, {"start": 2326.19, "end": 2326.75, "word": " of", "probability": 0.96728515625}, {"start": 2326.75, "end": 2327.45, "word": " almond", "probability": 0.72412109375}, {"start": 2327.45, "end": 2329.99, "word": " اللوز", "probability": 0.68499755859375}, {"start": 2329.99, "end": 2330.83, "word": " بالانجليزي", "probability": 0.9318033854166666}, {"start": 2330.83, "end": 2331.87, "word": " بالالماني", "probability": 0.950439453125}, {"start": 2331.87, "end": 2333.35, "word": " mandel", "probability": 0.828857421875}, {"start": 2333.35, "end": 2333.91, "word": " ومن", "probability": 0.774658203125}, {"start": 2333.91, "end": 2334.17, "word": " هنا", "probability": 0.98291015625}, {"start": 2334.17, "end": 2334.83, "word": " استعمل", "probability": 0.9378255208333334}, {"start": 2334.83, "end": 2335.53, "word": " mandilo", "probability": 0.72900390625}, 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"start": 2655.36, "end": 2671.48, "text": "الومينوم هايدرايد يعني نفسه ممكن تلاقوه تحت اسم ليثيام ألومينوم هايدرايد أو ليثيام تيترا هايدرايد و ألومينيت وهذا بيسموه صوديوم بورو هايدرايد مش بورون", "tokens": [6027, 20498, 9957, 20498, 8032, 995, 25708, 23557, 25708, 37495, 22653, 8717, 36178, 3224, 3714, 43020, 6055, 15040, 4587, 2407, 3224, 6055, 33753, 24525, 2304, 32239, 12984, 1829, 10943, 5551, 1211, 20498, 9957, 20498, 8032, 995, 25708, 23557, 25708, 34051, 32239, 12984, 1829, 10943, 6055, 36081, 23557, 8032, 995, 25708, 23557, 25708, 4032, 5551, 1211, 20498, 9957, 36081, 37037, 15730, 4724, 1829, 38251, 2407, 3224, 20328, 2407, 16254, 20498, 4724, 13063, 2407, 8032, 995, 25708, 23557, 25708, 37893, 4724, 13063, 11536], "avg_logprob": -0.2627667570259513, "compression_ratio": 2.036764705882353, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 2655.36, "end": 2656.14, "word": "الومينوم", "probability": 0.55133056640625}, {"start": 2656.14, "end": 2657.66, "word": " 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تيترا", "probability": 0.79248046875}, {"start": 2664.84, "end": 2665.44, "word": " هايدرايد", "probability": 0.95185546875}, {"start": 2665.44, "end": 2665.54, "word": " و", "probability": 0.615234375}, {"start": 2665.54, "end": 2666.08, "word": " ألومينيت", "probability": 0.73291015625}, {"start": 2666.08, "end": 2666.7, "word": " وهذا", "probability": 0.81103515625}, {"start": 2666.7, "end": 2667.34, "word": " بيسموه", "probability": 0.933984375}, {"start": 2667.34, "end": 2668.14, "word": " صوديوم", "probability": 0.7750244140625}, {"start": 2668.14, "end": 2669.26, "word": " بورو", "probability": 0.9134114583333334}, {"start": 2669.26, "end": 2670.08, "word": " هايدرايد", "probability": 0.861865234375}, {"start": 2670.08, "end": 2671.08, "word": " مش", "probability": 0.8359375}, {"start": 2671.08, "end": 2671.48, "word": " بورون", "probability": 0.79296875}], "temperature": 1.0}, {"id": 112, "seek": 269731, "start": 2672.57, "end": 2697.31, "text": "Borohydride فإذا سمعتوا Sodium Borohydride أو Sodium Tetrahydride و Borate نفس الاسم Lithium Tetrahydride و Aluminate أو Lithium Aluminum Hydride نفس الاسم و مرات كتير حتى الاسم هذا Sodium Borohydride و عادة مش هيكونوا عاملينه زيك هتلاعظوا على السهم مكتوب عندكم NABH4", "tokens": [33, 284, 1445, 6655, 25502, 6156, 28814, 15730, 8608, 2304, 34268, 14407, 42059, 2197, 13739, 1445, 6655, 25502, 34051, 42059, 2197, 31580, 15688, 6655, 25502, 4032, 13739, 473, 8717, 36178, 2423, 32277, 2304, 32577, 2197, 31580, 15688, 6655, 25502, 4032, 967, 7112, 473, 34051, 32577, 2197, 967, 7112, 449, 24231, 25502, 8717, 36178, 2423, 32277, 2304, 4032, 3714, 2288, 9307, 9122, 2655, 13546, 11331, 49975, 2423, 32277, 2304, 23758, 42059, 2197, 13739, 1445, 6655, 25502, 4032, 6225, 18513, 3660, 37893, 39896, 30544, 14407, 6225, 10943, 1211, 9957, 3224, 30767, 1829, 4117, 8032, 2655, 15040, 3615, 19913, 14407, 15844, 21136, 16095, 3714, 4117, 2655, 37746, 43242, 24793, 426, 13868, 39, 19], "avg_logprob": -0.19214527161271722, 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2678.77, "word": " نفس", "probability": 0.9765625}, {"start": 2678.77, "end": 2679.25, "word": " الاسم", "probability": 0.783203125}, {"start": 2679.25, "end": 2681.01, "word": " Lithium", "probability": 0.785400390625}, {"start": 2681.01, "end": 2681.97, "word": " Tetrahydride", "probability": 0.8717041015625}, {"start": 2681.97, "end": 2682.05, "word": " و", "probability": 0.3291015625}, {"start": 2682.05, "end": 2682.67, "word": " Aluminate", "probability": 0.8507486979166666}, {"start": 2682.67, "end": 2682.85, "word": " أو", "probability": 0.7509765625}, {"start": 2682.85, "end": 2683.33, "word": " Lithium", "probability": 0.9267578125}, {"start": 2683.33, "end": 2683.87, "word": " Aluminum", "probability": 0.8507486979166666}, {"start": 2683.87, "end": 2684.47, "word": " Hydride", "probability": 0.65869140625}, {"start": 2684.47, "end": 2684.77, "word": " نفس", "probability": 0.97314453125}, {"start": 2684.77, "end": 2685.85, "word": " الاسم", "probability": 0.9015299479166666}, 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اه اذا هل جيتها بنصير نكتب reduction عشان تكون واضحة الأمور معاكم قبل الديهايدs produces primary alcohol", "tokens": [27375, 822, 7658, 1975, 15730, 16472, 2655, 3555, 3224, 14407, 20449, 1829, 10874, 25708, 995, 16472, 3224, 5296, 15042, 2423, 3224, 7435, 20498, 46811, 15844, 2423, 2423, 16254, 11296, 25708, 6225, 995, 16254, 1975, 2655, 4117, 12610, 1975, 3224, 1975, 15730, 8032, 1211, 10874, 36081, 11296, 44945, 9381, 13546, 8717, 4117, 2655, 3555, 11004, 6225, 8592, 7649, 6055, 30544, 4032, 46958, 5016, 3660, 16247, 2304, 13063, 20449, 995, 24793, 12174, 36150, 2423, 16254, 11296, 25708, 82, 14725, 6194, 7658], "avg_logprob": -0.24843748658895493, "compression_ratio": 1.5797872340425532, "no_speech_prob": 0.0, "words": [{"start": 2751.01, "end": 2751.83, "word": "secondary", "probability": 0.76318359375}, {"start": 2751.83, "end": 2752.37, "word": " alcohol", "probability": 0.869140625}, {"start": 2752.37, "end": 2752.87, "word": " اذا", "probability": 0.581787109375}, {"start": 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"end": 2800.24, "word": " ال", "probability": 0.7021484375}, {"start": 2800.24, "end": 2801.04, "word": " الديهايد", "probability": 0.603515625}, {"start": 2801.04, "end": 2801.28, "word": " لما", "probability": 0.7283935546875}, {"start": 2801.28, "end": 2801.8, "word": " بنعمله", "probability": 0.95849609375}, {"start": 2801.8, "end": 2802.44, "word": " reduction", "probability": 0.9208984375}, {"start": 2802.44, "end": 2804.76, "word": " بالهيدرايد", "probability": 0.627587890625}, {"start": 2804.76, "end": 2805.04, "word": " بده", "probability": 0.4464111328125}, {"start": 2805.04, "end": 2805.24, "word": " يصير", "probability": 0.9274088541666666}, {"start": 2805.24, "end": 2805.8, "word": " عنده", "probability": 0.98291015625}, {"start": 2805.8, "end": 2807.26, "word": " primary", "probability": 0.51220703125}, {"start": 2807.26, "end": 2807.96, "word": " alcohol", "probability": 0.88232421875}, {"start": 2807.96, "end": 2808.46, "word": " و", "probability": 0.642578125}, {"start": 2808.46, "end": 2808.68, "word": " ال", "probability": 0.625}, {"start": 2808.68, "end": 2809.28, "word": " ketone", "probability": 0.56146240234375}, {"start": 2809.28, "end": 2809.56, "word": " لما", "probability": 0.98388671875}, {"start": 2809.56, "end": 2810.08, "word": " بنعمله", "probability": 0.9759114583333334}, {"start": 2810.08, "end": 2810.6, "word": " reduction", "probability": 0.98876953125}, {"start": 2810.6, "end": 2810.9, "word": " بال", "probability": 0.966796875}, {"start": 2810.9, "end": 2811.62, "word": " الديهايد", "probability": 0.9195556640625}, {"start": 2811.62, "end": 2812.46, "word": " بده", "probability": 0.824951171875}, {"start": 2812.46, "end": 2812.64, "word": " يصير", "probability": 0.9869791666666666}, {"start": 2812.64, "end": 2813.34, "word": " عنده", "probability": 0.9755859375}, {"start": 2813.34, "end": 2814.24, "word": " secondary", "probability": 0.9501953125}, {"start": 2814.24, "end": 2815.06, "word": " alcohol", "probability": 0.900390625}, {"start": 2815.06, "end": 2815.92, "word": " لاحظوا", "probability": 0.8857421875}, {"start": 2815.92, "end": 2816.08, "word": " هذا", "probability": 0.935546875}, {"start": 2816.08, "end": 2816.68, "word": " الكلام", "probability": 0.9632161458333334}, {"start": 2816.68, "end": 2817.66, "word": " بفيدكم", "probability": 0.884521484375}, {"start": 2817.66, "end": 2818.02, "word": " سواء", "probability": 0.9640299479166666}, {"start": 2818.02, "end": 2818.48, "word": " بجمل", "probability": 0.6729329427083334}, {"start": 2818.48, "end": 2818.8, "word": " صح", "probability": 0.9921875}, {"start": 2818.8, "end": 2818.94, "word": " و", "probability": 0.63427734375}, {"start": 2818.94, "end": 2819.34, "word": " غلط", "probability": 0.9580078125}, {"start": 2819.34, "end": 2819.96, "word": " بأكمل", "probability": 0.818115234375}, {"start": 2819.96, "end": 2820.56, "word": " معادلة", "probability": 0.9825846354166666}, {"start": 2820.56, "end": 2821.08, "word": " او", "probability": 0.773681640625}, {"start": 2821.08, "end": 2821.6, "word": " حتى", "probability": 0.871337890625}, {"start": 2821.6, "end": 2822.06, "word": " لو", "probability": 0.96435546875}, {"start": 2822.06, "end": 2822.32, "word": " احنا", "probability": 0.91259765625}, {"start": 2822.32, "end": 2822.96, "word": " سألناكوا", "probability": 0.8898111979166666}, {"start": 2822.96, "end": 2823.4, "word": " سؤال", "probability": 0.978515625}, {"start": 2823.4, "end": 2823.82, "word": " how", "probability": 0.7421875}, {"start": 2823.82, "end": 2824.16, "word": " can", "probability": 0.9130859375}, {"start": 2824.16, "end": 2824.4, "word": " you", "probability": 0.9560546875}, {"start": 2824.4, "end": 2824.94, "word": " prepare", "probability": 0.943359375}, {"start": 2824.94, "end": 2825.22, "word": " the", "probability": 0.93212890625}, {"start": 2825.22, "end": 2825.76, "word": " following", "probability": 0.88037109375}, {"start": 2825.76, "end": 2826.74, "word": " compound", "probability": 0.947265625}], "temperature": 1.0}, {"id": 118, "seek": 285669, "start": 2828.25, "end": 2856.69, "text": "واضح؟ لما تشوفوا أن الناتج اللي عندكم primary alcohol إذا بتقدروا تفكروا أنه ممكن يكون إيجا من وين لما تشوفوا الناتج اللي عندكم secondary alcohol إذا ممكن يكون إيجا من وين من كيتون واضح الفكرة؟ بنقف عند هذه النقطة المرة القادمة إن شاء الله بنحكي عن تفاعل الديهيدس والكيتون مع متفاعل اسمه green yard reagent عمرنا حكينا عنه؟", "tokens": [2407, 46958, 5016, 22807, 5296, 15042, 6055, 8592, 38688, 14407, 14739, 28239, 9307, 7435, 13672, 1829, 43242, 24793, 6194, 7658, 11933, 15730, 39894, 28543, 2288, 14407, 6055, 5172, 37983, 14407, 14739, 3224, 3714, 43020, 7251, 30544, 11933, 1829, 7435, 995, 9154, 4032, 9957, 5296, 15042, 6055, 8592, 38688, 14407, 28239, 9307, 7435, 13672, 1829, 43242, 24793, 11396, 7658, 11933, 15730, 3714, 43020, 7251, 30544, 11933, 1829, 7435, 995, 9154, 4032, 9957, 9154, 9122, 36081, 11536, 4032, 46958, 5016, 27188, 4117, 25720, 22807, 44945, 4587, 5172, 43242, 29538, 28239, 47432, 3660, 9673, 25720, 25062, 18513, 46007, 36145, 13412, 16606, 21984, 44945, 5016, 4117, 1829, 18871, 6055, 5172, 995, 30241, 2423, 16254, 3224, 25708, 3794, 16070, 4117, 36081, 11536, 20449, 44650, 5172, 995, 30241, 24525, 2304, 3224, 3092, 11682, 26949, 317, 6225, 29973, 8315, 11331, 4117, 1829, 8315, 18871, 3224, 22807], "avg_logprob": -0.1834821442408221, "compression_ratio": 2.0185873605947955, "no_speech_prob": 0.0, "words": [{"start": 2828.25, "end": 2828.99, "word": "واضح؟", "probability": 0.7799072265625}, {"start": 2828.99, "end": 2829.21, "word": " لما", "probability": 0.857666015625}, {"start": 2829.21, "end": 2829.63, "word": " تشوفوا", "probability": 0.966064453125}, {"start": 2829.63, "end": 2829.71, "word": " أن", "probability": 0.38037109375}, {"start": 2829.71, "end": 2830.19, "word": " الناتج", "probability": 0.7259928385416666}, {"start": 2830.19, "end": 2830.35, "word": " اللي", "probability": 0.8193359375}, {"start": 2830.35, "end": 2830.63, "word": " عندكم", "probability": 0.955078125}, {"start": 2830.63, "end": 2831.15, "word": " primary", "probability": 0.492431640625}, {"start": 2831.15, "end": 2831.97, "word": " alcohol", "probability": 0.83837890625}, {"start": 2831.97, "end": 2832.61, "word": " إذا", "probability": 0.69189453125}, {"start": 2832.61, "end": 2833.17, "word": " بتقدروا", "probability": 0.9326171875}, {"start": 2833.17, "end": 2833.67, "word": " تفكروا", "probability": 0.95654296875}, {"start": 2833.67, "end": 2833.89, "word": " أنه", "probability": 0.802490234375}, {"start": 2833.89, "end": 2834.19, "word": " ممكن", "probability": 0.931640625}, {"start": 2834.19, "end": 2834.47, "word": " يكون", "probability": 0.85888671875}, {"start": 2834.47, "end": 2834.77, "word": " إيجا", "probability": 0.7686767578125}, {"start": 2834.77, "end": 2834.89, "word": " من", "probability": 0.99169921875}, {"start": 2834.89, "end": 2835.21, "word": " وين", "probability": 0.922119140625}, {"start": 2835.21, "end": 2836.53, "word": " لما", "probability": 0.5748291015625}, {"start": 2836.53, "end": 2836.85, "word": " تشوفوا", "probability": 0.98876953125}, {"start": 2836.85, "end": 2837.21, "word": " الناتج", "probability": 0.8981119791666666}, {"start": 2837.21, "end": 2837.35, "word": " اللي", "probability": 0.991943359375}, {"start": 2837.35, "end": 2837.77, "word": " عندكم", "probability": 0.987060546875}, {"start": 2837.77, "end": 2838.59, "word": " secondary", "probability": 0.91748046875}, {"start": 2838.59, "end": 2839.43, "word": " alcohol", "probability": 0.86962890625}, {"start": 2839.43, "end": 2839.93, "word": " إذا", "probability": 0.96435546875}, {"start": 2839.93, "end": 2840.31, "word": " ممكن", "probability": 0.97998046875}, {"start": 2840.31, "end": 2840.55, "word": " يكون", "probability": 0.98291015625}, {"start": 2840.55, "end": 2840.85, "word": " إيجا", "probability": 0.976318359375}, {"start": 2840.85, "end": 2841.01, "word": " من", "probability": 0.9931640625}, {"start": 2841.01, "end": 2841.33, "word": " وين", "probability": 0.897216796875}, {"start": 2841.33, "end": 2842.47, "word": " من", "probability": 0.62744140625}, {"start": 2842.47, "end": 2843.11, "word": " كيتون", "probability": 0.695068359375}, {"start": 2843.11, "end": 2843.95, "word": " واضح", "probability": 0.9069010416666666}, {"start": 2843.95, "end": 2844.97, "word": " الفكرة؟", "probability": 0.8421630859375}, {"start": 2844.97, "end": 2845.43, "word": " بنقف", "probability": 0.80517578125}, {"start": 2845.43, "end": 2845.65, "word": " عند", "probability": 0.98291015625}, {"start": 2845.65, "end": 2845.87, "word": " هذه", "probability": 0.76318359375}, {"start": 2845.87, "end": 2846.33, "word": " النقطة", "probability": 0.984375}, {"start": 2846.33, "end": 2846.65, "word": " المرة", "probability": 0.892822265625}, {"start": 2846.65, "end": 2847.61, "word": " القادمة", "probability": 0.9892578125}, {"start": 2847.61, "end": 2847.79, "word": " إن", "probability": 0.432861328125}, {"start": 2847.79, "end": 2847.95, "word": " شاء", "probability": 0.96630859375}, {"start": 2847.95, "end": 2848.11, "word": " الله", "probability": 0.95751953125}, {"start": 2848.11, "end": 2849.21, "word": " بنحكي", "probability": 0.91943359375}, {"start": 2849.21, "end": 2849.51, "word": " عن", "probability": 0.98779296875}, {"start": 2849.51, "end": 2850.19, "word": " تفاعل", "probability": 0.9427490234375}, {"start": 2850.19, "end": 2850.83, "word": " الديهيدس", "probability": 0.658349609375}, {"start": 2850.83, "end": 2851.57, "word": " والكيتون", "probability": 0.8038330078125}, {"start": 2851.57, "end": 2852.23, "word": " مع", "probability": 0.759765625}, {"start": 2852.23, "end": 2853.23, "word": " متفاعل", "probability": 0.886474609375}, {"start": 2853.23, "end": 2853.87, "word": " اسمه", "probability": 0.9244791666666666}, {"start": 2853.87, "end": 2854.31, "word": " green", "probability": 0.364990234375}, {"start": 2854.31, "end": 2854.69, "word": " yard", "probability": 0.335693359375}, {"start": 2854.69, "end": 2855.27, "word": " reagent", "probability": 0.878662109375}, {"start": 2855.27, "end": 2855.67, "word": " عمرنا", "probability": 0.939453125}, {"start": 2855.67, "end": 2856.11, "word": " حكينا", "probability": 0.98974609375}, {"start": 2856.11, "end": 2856.69, "word": " عنه؟", "probability": 0.94287109375}], "temperature": 1.0}, {"id": 119, "seek": 286622, "start": 2857.32, "end": 2866.22, "text": "بنعرفه المرة الجاية وبنشوف كيف بتفاعل ال الديهيد والكيتون مع ال green yard reagent شكرا", "tokens": [3555, 1863, 3615, 28480, 3224, 9673, 25720, 25724, 995, 10632, 46599, 1863, 8592, 38688, 9122, 33911, 39894, 5172, 995, 30241, 2423, 2423, 16254, 3224, 25708, 16070, 4117, 36081, 11536, 20449, 2423, 3092, 11682, 26949, 317, 13412, 4117, 23557], "avg_logprob": -0.20592948565116295, "compression_ratio": 1.2743362831858407, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2857.32, "end": 2858.04, "word": "بنعرفه", "probability": 0.9056640625}, {"start": 2858.04, "end": 2858.34, "word": " المرة", "probability": 0.928466796875}, {"start": 2858.34, "end": 2858.92, "word": " الجاية", "probability": 0.94140625}, {"start": 2858.92, "end": 2859.74, "word": " وبنشوف", "probability": 0.84423828125}, {"start": 2859.74, "end": 2860.0, "word": " كيف", "probability": 0.96826171875}, {"start": 2860.0, "end": 2860.74, "word": " بتفاعل", "probability": 0.81536865234375}, {"start": 2860.74, "end": 2861.26, "word": " ال", "probability": 0.8857421875}, {"start": 2861.26, "end": 2861.86, "word": " الديهيد", "probability": 0.71221923828125}, {"start": 2861.86, "end": 2862.66, "word": " والكيتون", "probability": 0.7459716796875}, {"start": 2862.66, "end": 2863.3, "word": " مع", "probability": 0.93017578125}, {"start": 2863.3, "end": 2863.68, "word": " ال", "probability": 0.859375}, {"start": 2863.68, "end": 2864.04, "word": " green", "probability": 0.45703125}, {"start": 2864.04, "end": 2864.44, "word": " yard", "probability": 0.73681640625}, {"start": 2864.44, "end": 2865.48, "word": " reagent", "probability": 0.8505859375}, {"start": 2865.48, "end": 2866.22, "word": " شكرا", "probability": 0.92578125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2867.01425, "duration_after_vad": 2750.2293749999894}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b0ab76fbc41eb0eb433ee7322cf3a1d9a5cd0846
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/YZU5twA1Dw4_raw.srt
@@ -0,0 +1,2140 @@
+1
+00:00:19,470 --> 00:00:24,730
+بسم الله الرحمن الرحيم بدأنا من محاضرة او محاضرتين
+
+2
+00:00:24,730 --> 00:00:28,470
+في موضوع ال الديهيدس والكيتونز اتعرفنا عليهم ليش
+
+3
+00:00:28,470 --> 00:00:34,430
+اتصنفوا مع بعض تسمية ال الديهيدس والكيتونز طرق
+
+4
+00:00:34,430 --> 00:00:38,690
+صناعية لتحضير اشهر ال الديهيدس والكيتونز كان اخر
+
+5
+00:00:38,690 --> 00:00:44,270
+شيء اتكلمنا عنه الان في المختبر الطرق العامة
+
+6
+00:00:44,270 --> 00:00:49,420
+لتحضير ال الديهيدس والكيتونزإذا بنستعرضها مع بعض
+
+7
+00:00:49,420 --> 00:00:53,560
+بنلاحظ أن هذه الأشياء مرت علينا الحقيقة يعني
+
+8
+00:00:53,560 --> 00:00:58,080
+الطريقة الأولى لتحضير ال aldehydes و ال ketones من
+
+9
+00:00:58,080 --> 00:01:03,300
+أجسدة الكحولات لما أخدنا ال alcohols قلنا أن ال
+
+10
+00:01:03,300 --> 00:01:06,880
+alcohols they are either primary, secondary or
+
+11
+00:01:06,880 --> 00:01:13,120
+tertiary وقلنا أن ال primaryبصيروا باستعمال ال BCC
+
+12
+00:01:13,120 --> 00:01:16,960
+الديهيدز و ممكن يمدوا اكتر لو كان العامل مؤاكسد
+
+13
+00:01:16,960 --> 00:01:20,660
+اقوى بصيروا acids هذا مش الموضوع هنا ال secondary
+
+14
+00:01:20,660 --> 00:01:26,500
+alcohol باستعمال كيامانو 4 او كيتو كروميون 2
+
+15
+00:01:27,340 --> 00:01:33,400
+برمجانات البوتاسيوم كيتو كروميوم 207 بوتاسيوم داي
+
+16
+00:01:33,400 --> 00:01:37,940
+كروميت أو كروميك أكسيد بيصيروا كيتون فهذا أكسد
+
+17
+00:01:37,940 --> 00:01:42,720
+بالالكوهولز هي طريقة في انها لتحضير ال الديهايد
+
+18
+00:01:42,720 --> 00:01:45,520
+والكيتون من ال primer بناخد ال الديهايد ومن
+
+19
+00:01:45,520 --> 00:01:50,730
+السكندر بناخدالكيتون هذه طريقة مرت علينا سابقا
+
+20
+00:01:50,730 --> 00:01:58,450
+الاروماتيك كيتون أخدناهم كنا انحضر الاسيتوفينون
+
+21
+00:01:58,450 --> 00:02:06,640
+مثلا من استعمال ال acid halidesR-C-O-C-L هذي C-O
+
+22
+00:02:06,640 --> 00:02:10,700
+معناها C double bond و C-L في وجود ألومنيوم
+
+23
+00:02:10,700 --> 00:02:14,400
+الكلورايد الألومنيوم الكلورايد بيسحب الكلور و
+
+24
+00:02:14,400 --> 00:02:18,280
+بيعمل عندنا الايون الموجب و بيصير Electrophilic
+
+25
+00:02:18,280 --> 00:02:22,920
+Substitution اللي سمناه Friedel Crafts Acylation
+
+26
+00:02:22,920 --> 00:02:26,700
+واضح سمناه Friedel Crafts Acylation أخدنا Friedel
+
+27
+00:02:26,700 --> 00:02:30,720
+Crafts Alkylation و Acylation في شبطر الاروماتيك
+
+28
+00:02:31,490 --> 00:02:38,470
+from alkynes اخدنا احنا ان ال alkynes بيضيفوا مية
+
+29
+00:02:38,470 --> 00:02:42,090
+المية اللى بيضيفوها ممكن تكون حسب قاعدة
+
+30
+00:02:42,090 --> 00:02:46,390
+Markovnikov يضيف HOO يصير اندي double bond او Anti
+
+31
+00:02:46,390 --> 00:02:51,070
+Markovnikov HOH و في كل الأحوال لما يصير اندي in
+
+32
+00:02:51,070 --> 00:02:55,810
+all يعني هذا ال alkyne لو ضفنا عليه HOOH بدو يصير
+
+33
+00:02:55,810 --> 00:03:03,290
+double bondInol أخدنا أن Inol يعمل توتوميريزم
+
+34
+00:03:03,290 --> 00:03:08,550
+لكيتون أو لالديهيد سمناها keto inol توتوميريزم
+
+35
+00:03:08,550 --> 00:03:12,050
+يعني بهذا المثال لما نضيف الميه في وجود الحامض
+
+36
+00:03:12,050 --> 00:03:17,090
+فالإضافة بمرحلتها الأولى Markov-Nikov addition لما
+
+37
+00:03:17,090 --> 00:03:21,850
+نعمل التوتوميريزم ال COH بتصير C double bond O
+
+38
+00:03:21,850 --> 00:03:25,830
+يعني هذا بنرجع في الفصل التالت هذا بنرجع في الفصل
+
+39
+00:03:25,830 --> 00:03:30,800
+الرابع هذا بنرجع في الفصلالسابق كل هذه طرق تحضير
+
+40
+00:03:30,800 --> 00:03:36,580
+الالديهيد والكيتون مرت معناه وهذه الميزة الحقيقة
+
+41
+00:03:36,580 --> 00:03:41,540
+موجودة في ال organ ال chemistry انه انا في اندي شي
+
+42
+00:03:41,540 --> 00:03:45,300
+اسمه functional group interconvergent يعني اتحول
+
+43
+00:03:45,300 --> 00:03:51,180
+من شغلة لشغلة من كحول لالديهيد من كحول الى كيتون
+
+44
+00:03:51,180 --> 00:03:57,130
+من الكاين الى كيتونالان طالما صار عندى مسميين
+
+45
+00:03:57,130 --> 00:04:01,670
+طالما صار عندى مسميين اذا الشغل هتمر عندى مرتين
+
+46
+00:04:01,670 --> 00:04:04,150
+يعني لما انا بقول ان انا عندى كحول بده يصير
+
+47
+00:04:04,150 --> 00:04:07,530
+aldehyde او كيتون هتلاقوا انحنا نذكرها لما بنحكي
+
+48
+00:04:07,530 --> 00:04:10,990
+عن ال alcohol كتفاعل و نذكرها لما بنحكي عن ال
+
+49
+00:04:10,990 --> 00:04:15,290
+aldehydes و ال ketones كطريقة للتحضير بعد شوية
+
+50
+00:04:15,290 --> 00:04:18,690
+هنيجي على ال aldehydes و ال ketones طالما هذه
+
+51
+00:04:18,690 --> 00:04:25,320
+العملية أكسدة طب لو رجعنا فيها رجوعهتصير تفاعل لل
+
+52
+00:04:25,320 --> 00:04:28,060
+الديهيد والكيتون هلاحظ ان ال reduction of
+
+53
+00:04:28,060 --> 00:04:31,700
+aldehydes and ketones produces ايش؟ alcohol
+
+54
+00:04:31,700 --> 00:04:36,960
+فالعملية عملية متعاكسة وعشان كده الكلام بنشوفه
+
+55
+00:04:36,960 --> 00:04:41,820
+باكثر من مكان alcohol صار الديهيد او كيتون بالاكسة
+
+56
+00:04:41,820 --> 00:04:48,000
+ده الآن طب الديهيد او كيتونبالاختصار هيرجع ايش؟
+
+57
+00:04:48,000 --> 00:04:53,740
+هيرجع لالكول وسبق احنا انه وضحنا معنى الأكسادة ان
+
+58
+00:04:53,740 --> 00:05:00,020
+هي في النهاية اما انها زيادة في المحتوى الاكسوجيني
+
+59
+00:05:00,020 --> 00:05:05,940
+او نقص في محتوى الهيدروجينيالان هذه ال aldehydes و
+
+60
+00:05:05,940 --> 00:05:10,920
+ال ketones خلينا نقول في النهاية هي و كل الكيميا
+
+61
+00:05:10,920 --> 00:05:15,680
+لازم نفهمها من منطق التطبيق العملي يعني هي بتبدأ
+
+62
+00:05:15,680 --> 00:05:19,680
+معناه ربوز لكن في النهاية بواقع الحياة بتنتهي انها
+
+63
+00:05:19,680 --> 00:05:25,170
+مركباتالها وجود في الحياة العملية، الها تطبيق على
+
+64
+00:05:25,170 --> 00:05:28,790
+سبيل المثال ال Benzaldehyde هذا Aldehyde
+
+65
+00:05:28,790 --> 00:05:33,670
+Benzaldehyde هذا هو عبارة عن ال oil of almonds هو
+
+66
+00:05:33,670 --> 00:05:39,600
+زيت اللوزواضح؟ في زيت مشهور اسمه زيت اللوز لو
+
+67
+00:05:39,600 --> 00:05:43,740
+أسرنا اللوز بيطلع منه زيت اللي هو ال benz aldehyde
+
+68
+00:05:43,740 --> 00:05:49,140
+هذا ال aldehyde اللي شايفينه C double bond OH مع
+
+69
+00:05:49,140 --> 00:05:54,000
+حلقة بنزين و double bond هذا مركب كامل هذا اسمه
+
+70
+00:05:54,000 --> 00:05:58,880
+cinnamaldehyde cinnamaldehyde جاية من ال cinnamon
+
+71
+00:05:58,880 --> 00:06:05,880
+cinnamon يعني جرفةواضح؟ فهو المركب الأساسي اللي
+
+72
+00:06:05,880 --> 00:06:10,360
+بيعطي الجرفة الريحة تبعتها لأن الجرفة اسمها
+
+73
+00:06:10,360 --> 00:06:16,560
+cinnamon هو سموه إيش؟cinnamaldehyde مثلا بالالماني
+
+74
+00:06:16,560 --> 00:06:22,480
+الجرفة اسمها zimt فبيسموه zimt aldehyde واضح zimt
+
+75
+00:06:22,480 --> 00:06:27,300
+aldehyde هنا cinnamon cinnamaldehyde واضح فهذه
+
+76
+00:06:27,300 --> 00:06:31,620
+الجرفة اللي احنا بنتناولها في النهاية هي aldehyde
+
+77
+00:06:31,620 --> 00:06:36,180
+مر علينا سابقا ان الفانيلة هي عبارة عن aromatic
+
+78
+00:06:36,180 --> 00:06:40,600
+aldehyde عليه مجموعة هيدروكسي وميثوكسي الفانيلين
+
+79
+00:06:41,300 --> 00:06:47,120
+الان كتير ناس بيحبوا زيت النعناع sperminate oil
+
+80
+00:06:47,120 --> 00:06:51,220
+اللى بدخل فى مشتقات كتيرة و لعلاج الزور هذا عبارة
+
+81
+00:06:51,220 --> 00:06:54,680
+عن كيتون هى فيه ال C double bond O اللى بنسميه
+
+82
+00:06:54,680 --> 00:06:59,960
+carbonالمركب الكيميائي carbon لكن هذا ال carbon هو
+
+83
+00:06:59,960 --> 00:07:05,500
+ال sperm in it oil هو زيت النعمة واضح هذا المركب
+
+84
+00:07:05,500 --> 00:07:08,960
+لاحظوا بتلاحظوه مركب كبير لكن انا بهمن المجموعة
+
+85
+00:07:08,960 --> 00:07:12,280
+الوظيفية في نهاية المجموعة الوظيفية ايش فيه C
+
+86
+00:07:12,280 --> 00:07:17,240
+double bond O كيتون finally كيتون هذا ال camphor
+
+87
+00:07:17,240 --> 00:07:21,720
+الكفور واضح اللي بيستعملوه لعلاج الرجلين و ما إلى
+
+88
+00:07:21,720 --> 00:07:28,840
+ذلك الآن مش ضايل عندنا غير مينغير البحتري عاد
+
+89
+00:07:28,840 --> 00:07:34,560
+الربيع الى الدنيا بموقبه فزينت واكتست بالسندس
+
+90
+00:07:34,560 --> 00:07:38,580
+الشجر اه الياسمين الياسمين خلال أسبوعين اللي عندهم
+
+91
+00:07:38,580 --> 00:07:44,570
+ياسمينة هيلاحظوا كل الياسمينة إيش تصيربيضة من إيش؟
+
+92
+00:07:44,570 --> 00:07:50,590
+أه هي الياسمون كيتو واضح؟ ملاحظين مركب معين هذا
+
+93
+00:07:50,590 --> 00:07:56,910
+اللي هو الياسمون من ال oil of ياسمين من زيت
+
+94
+00:07:56,910 --> 00:08:01,190
+الياسمين بنطول هذا المركب الأساسي اللي بيعطيها
+
+95
+00:08:01,190 --> 00:08:04,790
+الريحة الكويسة سواء عملنا منه أطور أو الناس حتى
+
+96
+00:08:04,790 --> 00:08:11,500
+بيشموها و هي على الشجر ريحة جيدةفهذه المراكبات
+
+97
+00:08:11,500 --> 00:08:16,860
+الحقيقة يعني إلها مجال كبير في التطبيق طبعا أكيد
+
+98
+00:08:16,860 --> 00:08:20,060
+إلها مجالات في أشياء كتيرة غير هيك في أدوية في
+
+99
+00:08:20,060 --> 00:08:24,280
+الصناعة ولذلك إحنا بندرسها بعنق و بنتعرف عليها
+
+100
+00:08:24,280 --> 00:08:31,560
+الآن لو بدنا نيجي بعد هيك لتفاعلات ال aldehydes و
+
+101
+00:08:31,560 --> 00:08:38,080
+ال ketones قلنا بشكل عام الأمر مختصر فيهكلمة واحدة
+
+102
+00:08:38,080 --> 00:08:43,900
+اللي هي addition واضح طبعا لو اجينا بدنا ندقق في
+
+103
+00:08:43,900 --> 00:08:48,540
+كلمة ال addition in eucleophilic addition بمعنى
+
+104
+00:08:48,540 --> 00:08:54,820
+المهاجم لازم يكون ايش؟اليوكليوفايل ليش المهاجم
+
+105
+00:08:54,820 --> 00:08:59,660
+لازم يكون اليوكليوفايل لأن الالدهايد والكيتون فيهم
+
+106
+00:08:59,660 --> 00:09:03,060
+السيضة بالبوند او اللي موجودة لو اتطلعنا علي اي
+
+107
+00:09:03,060 --> 00:09:07,040
+مكان ارسمها بشكل اوضح السيضة بالبوند او لو اتطلع
+
+108
+00:09:07,040 --> 00:09:10,420
+السلبية هذا الطرف partially positive هذا partially
+
+109
+00:09:10,420 --> 00:09:16,870
+negative الان اللي بدو يهاجم عادةاليوكليوفايل واضح
+
+110
+00:09:16,870 --> 00:09:21,210
+اللي بيهاجم عادة نيوكليوفايل لما يهاجم هنا زوج
+
+111
+00:09:21,210 --> 00:09:25,430
+الإلكترونات هذا بتتحرك بيصف النتيجة ان هي carbon
+
+112
+00:09:25,430 --> 00:09:33,470
+OH نيوكليوفايل الان في عند اصلا مجموعتين تانين هنا
+
+113
+00:09:33,470 --> 00:09:37,350
+مش رسموهم دولة مافيش عليهم أي تغيير
+
+114
+00:09:38,710 --> 00:09:42,830
+الخلاصة أن التفاعل الأساسي لـ aldehydes و لـ
+
+115
+00:09:42,830 --> 00:09:48,430
+ketones كان هناك double bond و أصبحت تنتين single
+
+116
+00:09:48,430 --> 00:09:53,550
+bond واحدة OH واحدة نيوكليوفايل بكل الأحوال هنا
+
+117
+00:09:53,550 --> 00:09:57,690
+عدد الروابط أربعة و هنا عدد الروابط أربعة فال
+
+118
+00:09:57,690 --> 00:10:04,000
+double bond O تصبحوبصير عنده رابطة جديدة مع ال
+
+119
+00:10:04,000 --> 00:10:09,580
+file واضح الفكرة هذا هو التفاعل اللي هيظل يتكرر
+
+120
+00:10:09,580 --> 00:10:17,260
+بناء على ذلك بصير الان كل هذه المحاضرةهتحكي شغلة
+
+121
+00:10:17,260 --> 00:10:21,260
+واحدة بسيطة اللي بيفهمها بيقدر إذا مستعجل يروح
+
+122
+00:10:21,260 --> 00:10:24,640
+يمشي إنه إيش أنواع الـ nucleophile اللي بتهاجم
+
+123
+00:10:24,640 --> 00:10:28,140
+أعطونا أمثلة بنقول نمروا واحد الميّه، نمروا اتنين
+
+124
+00:10:28,140 --> 00:10:31,260
+الكحول، نمروا تلاتة الـCr، نمروا أربعة الـH-,
+
+125
+00:10:31,260 --> 00:10:36,000
+نمروا خمسة كذا، نمروا ستة كذا فبكل المحاضرة هذه
+
+126
+00:10:36,000 --> 00:10:40,880
+فقط احنا بدنا نحتفظ بهذا ال frame إن هدول
+
+127
+00:10:40,880 --> 00:10:44,200
+المجموعتين في الأساس ماتغيروش الـC double bond O
+
+128
+00:10:44,200 --> 00:10:51,110
+صارت OHانغيّر هذه المجموعة واضحة الفكرة؟ بمعنى لو
+
+129
+00:10:51,110 --> 00:10:55,370
+انا الآن بقولكوا ان النيوكليوفايل كان ميّه ايش
+
+130
+00:10:55,370 --> 00:11:01,110
+هنحط هنا؟ OH بيصير عائلة اسمها الهيدريت اللي فيها
+
+131
+00:11:01,110 --> 00:11:04,010
+كاربون حاملة انت نواتش بحكي بالتفصيل ماتستعجلوش
+
+132
+00:11:04,010 --> 00:11:11,350
+الآن طب لو ضفنا كحول؟ OR بيصير عائلة جديدة اسمها
+
+133
+00:11:11,350 --> 00:11:15,570
+سيانهيدريل شوف كيف البساطة طب لو ضفنا CM؟
+
+134
+00:11:18,510 --> 00:11:26,090
+لحظة لو سمحتوا لو ضفنا OR بيصير عندنا عائلة اسمها
+
+135
+00:11:26,090 --> 00:11:29,570
+hemacetal انا قلت cyanohedrin hemacetal طيب لو
+
+136
+00:11:29,570 --> 00:11:37,070
+ضفنا CN cyanohedrin بيسموها لو ضفنا H minus هذه
+
+137
+00:11:37,070 --> 00:11:46,110
+عملية الاختزال H برجعلك كحول واضح؟ لو ضفنا Amin
+
+138
+00:11:46,860 --> 00:11:53,400
+أمونيا انا H2 متعودين انتوا لنيوترا ليوكليوفايل شو
+
+139
+00:11:53,400 --> 00:12:01,380
+هيصير هيفقد H و هكذا فكل الأمثلة اللي هنحكيها
+
+140
+00:12:01,380 --> 00:12:05,020
+هتكون ماخدة هذا الإطار العام كل الأمثلة اللي
+
+141
+00:12:05,020 --> 00:12:08,700
+هنحكيها هتاخد هذا الإطار العام البسيط
+
+142
+00:12:11,390 --> 00:12:18,850
+بفيد شغلة أن هذا التفاعل بشكل عام بتم له catalysis
+
+143
+00:12:18,850 --> 00:12:23,970
+يعني تسريع بإضافة H plus عشان هيك في معظم الحالات
+
+144
+00:12:23,970 --> 00:12:29,910
+هتلاحظوا على سهم التفاعل موجود عنده في وجود إيشأتش
+
+145
+00:12:29,910 --> 00:12:37,090
+بلس وظيفتها أن تعمل تسريع للتفاعل لاحظوا لو أنا
+
+146
+00:12:37,090 --> 00:12:40,710
+كان عندي الديهيد او كيتون وضفت عليه أتش بلس الأتش
+
+147
+00:12:40,710 --> 00:12:46,140
+بلس وين هتروح على الموجة ولا على الأكسجين السالبع
+
+148
+00:12:46,140 --> 00:12:51,580
+الأكسجل موجب على سالب هتصير بهذا الشكل و لو حركنا
+
+149
+00:12:51,580 --> 00:12:54,860
+زوج الألكترونات تعملنا resonance هلاحظ أنه أنا
+
+150
+00:12:54,860 --> 00:12:59,720
+بصير عند الكاربون موجبة full positive charge الآن
+
+151
+00:12:59,720 --> 00:13:03,880
+قبل شوية لما رسمنا احنا كنا نقول هنا إيش شحنة إيش
+
+152
+00:13:03,880 --> 00:13:11,060
+مالها partial charge ال acidلما اجى اضاف ال H plus
+
+153
+00:13:11,060 --> 00:13:16,060
+هنا خلى هذا ال carbon موجب كامل الان ال
+
+154
+00:13:16,060 --> 00:13:22,200
+nucleophile انه افضل له اهاجم على موجب جزء ولا على
+
+155
+00:13:22,200 --> 00:13:26,900
+موجب كامل اهاجم على موجب كامل التجادب ايش بيكون
+
+156
+00:13:26,900 --> 00:13:31,320
+اقوى والتفاعل اسرع هاي بالظبط اللي بيعملوا ال acid
+
+157
+00:13:31,320 --> 00:13:37,720
+الان الناتج النهائي مافيش فيه خلافالناتج النهائي
+
+158
+00:13:37,720 --> 00:13:42,280
+هو نفس الناتج لكن دائما لما بتقرأوا التفاعل
+
+159
+00:13:42,280 --> 00:13:45,840
+هتلاحظوا انه على السهم في عندكم ايش اتش بلس اتش
+
+160
+00:13:45,840 --> 00:13:50,520
+بلس هذه الاتش بلس عبارة عن catalyst بتسرع ايش
+
+161
+00:13:50,520 --> 00:13:57,040
+التفاعل بالطريقة اللي حكيناها الان لو بدأنا ناخد
+
+162
+00:13:57,040 --> 00:14:01,220
+امثلة هاي هذه ال carbon في ال aldehyde موجبة اجت
+
+163
+00:14:01,220 --> 00:14:07,400
+الميه تهاجمأول الـ Eucalyptus ناخد الميّه الـ C
+
+164
+00:14:07,400 --> 00:14:13,760
+double bond O شو بتصير؟ OH نحطها بالأخضر و الميّه
+
+165
+00:14:13,760 --> 00:14:16,280
+هتضيف
+
+166
+00:14:17,080 --> 00:14:23,100
+OH في النهاية واضح هاي صار عندنا استيظة بال bond O
+
+167
+00:14:23,100 --> 00:14:27,960
+صارت OH والمية كان يوكليوفال بتضيف OH الان هنا
+
+168
+00:14:27,960 --> 00:14:34,580
+اتكون عندى مركب على نفس ذرة الكربون تبعته كام OH؟
+
+169
+00:14:34,580 --> 00:14:40,480
+تلتين هذه المركبات اللى على نفس ذرة الكربون فيها
+
+170
+00:14:40,480 --> 00:14:47,840
+تلتين OH بنعطيها اسم hydratesواضح فال hydrate لو
+
+171
+00:14:47,840 --> 00:14:52,800
+قلتلكوا ارسمولي شكل عام لل hydrate معنى ذلك تحطوا
+
+172
+00:14:52,800 --> 00:14:59,420
+carbon على نفس ال carbon تنتين O H's يمكن انتوا
+
+173
+00:14:59,420 --> 00:15:05,340
+سابقا مر عليكم انه يكون عندى في المركب تنتين O H's
+
+174
+00:15:05,340 --> 00:15:12,440
+على ذرات متجاورة زي هيك هذا المركب لما انا كنت
+
+175
+00:15:12,440 --> 00:15:20,400
+اسميهماذا كنت أسميه؟ داي أول داي أول و لأنه
+
+176
+00:15:20,400 --> 00:15:29,620
+كربونتين اثان داي أولواضح إيثان دايول على نمرة
+
+177
+00:15:29,620 --> 00:15:32,360
+واحد وعن نمرة اتنين ممكن تكتبوا one two إيثان
+
+178
+00:15:32,360 --> 00:15:37,980
+دايول تمام لكن لما يكونوا مجموعتين ال OH على نفس
+
+179
+00:15:37,980 --> 00:15:41,860
+ال carbon بنسمي عائلة جديدة هذه العائلة إيش
+
+180
+00:15:41,860 --> 00:15:47,620
+بنسميها hydrate الان المركب نفسه بنسميه نسبة ال
+
+181
+00:15:47,620 --> 00:15:51,140
+aldehyde الأصلي يعني هذا ال aldehyde الأصلي الآن
+
+182
+00:15:51,140 --> 00:15:55,620
+formaldehydeبتذكروا لما قلنا ال formaldehyde غاز
+
+183
+00:15:55,620 --> 00:16:00,400
+ملدوبه في الميه عملية اذابته في الميه هي ان الميه
+
+184
+00:16:00,400 --> 00:16:04,880
+تتفاعل عليه تعمل هان OH و تخلص سيضا من البند OH
+
+185
+00:16:04,880 --> 00:16:11,560
+هذا ال formaldehyde هيدريت طب لو كان acetaldehyde
+
+186
+00:16:11,560 --> 00:16:16,700
+واحدة من دول ال حزب ده تصير CH3 و هكذا الان لاحظوا
+
+187
+00:16:16,700 --> 00:16:22,380
+معي ان ال hydrate تفاعل تكوينه متفاعل ايش
+
+188
+00:16:23,760 --> 00:16:28,200
+Equilibrium reaction يعني لا يتم بشكل كامل بيكون
+
+189
+00:16:28,200 --> 00:16:34,020
+موجود ال الديهيد مع الميه مع الهيدرين بنسبة معينة
+
+190
+00:16:34,020 --> 00:16:40,200
+الان في حالة ال formaldehyde بيصل لإن هذا يتفاعل
+
+191
+00:16:40,200 --> 00:16:45,550
+بنسبة 37% عشان ايه بيصير لكم الفورمالينهو نفس الـ
+
+192
+00:16:45,550 --> 00:16:48,910
+Formal Dehydrate الـ Formalin اللي أخدنا بنستعمله
+
+193
+00:16:48,910 --> 00:16:53,390
+لحفظ الأنسجة وغيرها هو نفسه ال Formal Dehydrate
+
+194
+00:16:53,390 --> 00:16:56,730
+اللي هو ال Formal Dehydrate اتدوب في الميه عمل هذا
+
+195
+00:16:56,730 --> 00:17:01,790
+الشكل ال Formalin واضح الفكرة؟ وهذا التفاعل زي ما
+
+196
+00:17:01,790 --> 00:17:07,950
+قلنا عنه تفاعل عكسي الآن هل يترا في كل ال ال
+
+197
+00:17:07,950 --> 00:17:12,300
+Dehydrates و ال Ketones ممكن يتكون هيدريتز؟من
+
+198
+00:17:12,300 --> 00:17:17,260
+ناحية نظرية بالورقة والقلم اه يعني انا بقدر
+
+199
+00:17:17,260 --> 00:17:21,260
+اقولكوا اي aldehyde في الدنيا ارسموله hydrate
+
+200
+00:17:21,260 --> 00:17:26,620
+الاصل انكم تعرفوا تعملوا hydrate له مثلا لو اجاكم
+
+201
+00:17:26,620 --> 00:17:32,020
+في الامتحان ارسمولنا benz aldehyde hydrate المنطلق
+
+202
+00:17:32,020 --> 00:17:38,630
+تبعكم لازم تكونوا عارفين ال benz aldehydeهي ال
+
+203
+00:17:38,630 --> 00:17:44,210
+benz aldehyde C double bond O H الان احنا اتفقنا
+
+204
+00:17:44,210 --> 00:17:49,230
+لما بدى يعمل hydrate هدول المجمعتين مافيش فيهم
+
+205
+00:17:49,230 --> 00:17:56,450
+تغيير طب ها شو بدى يصير ال C double bond O بتصير O
+
+206
+00:17:56,450 --> 00:18:05,030
+H والمية بتضيف O H هذا بتصير benz aldehyde hydrate
+
+207
+00:18:05,890 --> 00:18:11,750
+و هكذا يعني بنفس هذه الطريقة ممكن نرسم لأي ألديهيد
+
+208
+00:18:11,750 --> 00:18:15,850
+أو كيتون هيدريت لو قولنا أسيتون هيدريت أسيتالديهيد
+
+209
+00:18:15,850 --> 00:18:21,210
+هيدريت لكن الحقيقة معظم الهيدريت بشكل عام they are
+
+210
+00:18:21,210 --> 00:18:26,930
+unstable يعني في حالة الإتزان اللي بيوجد بشكل أكبر
+
+211
+00:18:26,930 --> 00:18:33,280
+كتير جدا هو الألديهيدو لذلك هذا التفاعل بيصير نوعا
+
+212
+00:18:33,280 --> 00:18:37,200
+ما تفاعل نظري مش تفاعل عملي يعني بيكون هذا ال
+
+213
+00:18:37,200 --> 00:18:42,160
+الديهيد او ال ketone موجود بالنسبة 99.9% و هذا
+
+214
+00:18:42,160 --> 00:18:46,780
+موجود بالنسبة قليلة جدا و لذلك معظم ال الديهيد و
+
+215
+00:18:46,780 --> 00:18:50,820
+ال ketones بيكون ال position of equilibrium اتجاه
+
+216
+00:18:50,820 --> 00:18:54,580
+الاتزان فيها هل هو باتجاه ال hydrate و لا باتجاه
+
+217
+00:18:54,580 --> 00:18:56,040
+ال الديهيد او ال ketone
+
+218
+00:18:58,860 --> 00:19:04,840
+واضح الفكرة؟ لكن نظريا كل شيء له hydrate الان مثلا
+
+219
+00:19:04,840 --> 00:19:10,420
+هذا المركب تطلع عليه carbon حملة تين و H إذا هذا
+
+220
+00:19:10,420 --> 00:19:15,120
+hydrate ولا لأ؟ Hydrate طب الآن لو قلت لواحدة
+
+221
+00:19:15,120 --> 00:19:22,520
+فيكوا هذا ال hydrate من أي الديهيد جاي كيف
+
+222
+00:19:22,520 --> 00:19:28,900
+بدى تعمل؟ بدى تخلي الرابطتين اللي موجودات ال Hو ال
+
+223
+00:19:28,900 --> 00:19:34,800
+C اللي حاملة تلاتة كلور يعني CCLCLCL و تحط هنا
+
+224
+00:19:34,800 --> 00:19:41,420
+double bond O هذا مركب موازل ال acetaldehyde لكن
+
+225
+00:19:41,420 --> 00:19:46,160
+ابدلت تلت ذرات الهيدروجين فيه بكلور فبصير اسمه ايش
+
+226
+00:19:46,160 --> 00:19:53,340
+اكلورال اكلورال لما اعمل من ال اكلورال هيدريت
+
+227
+00:19:53,340 --> 00:20:01,450
+باضافة الميهبيصير ايش اسمه اكلورال هايدريت فانا ال
+
+228
+00:20:01,450 --> 00:20:05,770
+الديهايدي اللي عندي اكلورال لما اعمله اضافة ميه
+
+229
+00:20:05,770 --> 00:20:10,950
+بيصير اكلورال هايدريت واضح لما اعمله اضافة ميه
+
+230
+00:20:10,950 --> 00:20:15,530
+بيصير اكلورال هايدريت هذا ال اكلورال هايدريت مادة
+
+231
+00:20:15,530 --> 00:20:19,650
+تستعمل في التخدير و عادة في التخدير في الطب
+
+232
+00:20:19,650 --> 00:20:24,090
+البيطري يعني لما يعملوا عمليات جراحية للحيوانات
+
+233
+00:20:24,090 --> 00:20:28,860
+الكبيرة الضخمةبيعطوها chloral hydrate كمخدر فيلو
+
+234
+00:20:28,860 --> 00:20:36,660
+ما إلى ذلك واضح؟ فهذا بالنسبة لل hydrate الأن كتير
+
+235
+00:20:36,660 --> 00:20:40,160
+مرات بنيجي بنقول للطالب في الامتحان النهار or some
+
+236
+00:20:40,160 --> 00:20:44,420
+general structure of hydrate بشكل عام شو بده يحط
+
+237
+00:20:44,420 --> 00:20:53,080
+الليه؟ carbon حاملة تنتلؤ أدشز واضح؟طيب لو اتينا ل
+
+238
+00:20:53,080 --> 00:20:59,680
+ال alcohol كيف بتتفاعل برضه إضافة الآن على طول
+
+239
+00:20:59,680 --> 00:21:05,140
+السيباب البندقوس شو هتصير OH و ال nucleophile اللي
+
+240
+00:21:05,140 --> 00:21:12,520
+هيهاجم OR لاحظوا هنا صار عندى ذرة carbon بتحمل مش
+
+241
+00:21:12,520 --> 00:21:21,470
+تنتين OHOH و OR يعني كأن هذا المركب هو عبارة عن
+
+242
+00:21:21,470 --> 00:21:28,230
+كحول و إيثر بنفس الوقت كاربون بتحمل OH هذا ألكوهول
+
+243
+00:21:28,960 --> 00:21:36,180
+و carbon OR هذا ether واضح فهذا المركب كأنه كحول و
+
+244
+00:21:36,180 --> 00:21:40,680
+ether و هذه العملية إضافة ليش إضافة هذه العملية
+
+245
+00:21:40,680 --> 00:21:44,200
+لأن ال double bond صارت single bond هذه الإضافة
+
+246
+00:21:44,200 --> 00:21:47,900
+ببساطة ال double bond single bond إضافة خلصنا الآن
+
+247
+00:21:47,900 --> 00:21:53,240
+هذا اللي فيه ال carbon بتحمل OH و OR بنسميه
+
+248
+00:21:53,240 --> 00:22:00,690
+hemiacetalيعني إيش؟ نص أسيتال مش أسيتال كامل، الآن
+
+249
+00:22:00,690 --> 00:22:06,190
+لما أي شغل نقول هذا نص أسيتال حيصير التفكير عندكم
+
+250
+00:22:06,190 --> 00:22:12,030
+طب هو إيش الأسيتال؟ الكامل، إذا في بالدنيا نص
+
+251
+00:22:12,030 --> 00:22:17,430
+أسيتال، إذا أكيد في الدنيا في إيش؟ أسيتال كامل،
+
+252
+00:22:17,430 --> 00:22:21,750
+hemacetal نص أسيتال، طب وإيش الأسيتال الكامل؟
+
+253
+00:22:24,180 --> 00:22:32,080
+إتنين إيثر لو هذا المركب نفسه الـ hemacetal فعلناه
+
+254
+00:22:32,080 --> 00:22:37,480
+مع زيادة من الكحول فعلناه مع زيادة من الكحول الآن
+
+255
+00:22:37,480 --> 00:22:41,960
+مرة تانية بيجي الكحول في هذه الحالة بيعمل تفاعل
+
+256
+00:22:41,960 --> 00:22:46,800
+تاني بيهاجم على الكربون الموجبة وبيطرد الـ OH الآن
+
+257
+00:22:46,800 --> 00:22:51,180
+هذا التفاعل مجموعة داخلة مجموعة طالعة شو بنسمي
+
+258
+00:22:51,180 --> 00:22:51,920
+احنا substitution
+
+259
+00:22:55,450 --> 00:22:58,630
+substitution هذا التفاعل double bond صارت single
+
+260
+00:22:58,630 --> 00:23:04,590
+bond شو كنا مسمينه addition الان بدلنا ال OH ب OR
+
+261
+00:23:04,590 --> 00:23:11,090
+شو صار موجود عندك على الكربون تنتين
+
+262
+00:23:11,090 --> 00:23:18,370
+OR داي إيثر هذا الأسيتال الكامل واضح هذا هو
+
+263
+00:23:18,370 --> 00:23:25,730
+الأسيتال الكامل اللي هو كربون بتحملTentenor و
+
+264
+00:23:25,730 --> 00:23:31,770
+التفاعل لتكوين الاسيتال يتم من خلال الهيمياسيتال
+
+265
+00:23:31,770 --> 00:23:36,870
+مع مزيد من الكحول فالتفاعل في هذه الحالة
+
+266
+00:23:36,870 --> 00:23:41,850
+substitution لاحظوا انا الان كم عائلة جديدة اتعرفت
+
+267
+00:23:41,850 --> 00:23:47,490
+عليها خدوهم بالتدريج Carbon Carbon Carbon Carbon
+
+268
+00:23:47,490 --> 00:23:48,990
+حاملة Tentenor
+
+269
+00:23:51,050 --> 00:23:57,350
+أه carbon حاملة OH و OR همي أسيتال carbon حاملة OR
+
+270
+00:23:57,350 --> 00:24:06,530
+و OR أسيتال شفتم كيف بالمقارنة hydrate أسيتال وهذا
+
+271
+00:24:06,530 --> 00:24:12,720
+اللي بين بينهيمي أسيتال هيدريت وهذا أسيتال وهذا
+
+272
+00:24:12,720 --> 00:24:18,320
+هيمي أسيتال الآن لو أجينا نسألكم الهيدريت كيف
+
+273
+00:24:18,320 --> 00:24:25,440
+بيتكون من إضافة الماء على ال الديهيد أو الكيتون
+
+274
+00:24:25,440 --> 00:24:29,300
+لحظوا الكلمات اللي باستعملها لما نفجر نسأل هيدريت
+
+275
+00:24:29,300 --> 00:24:30,260
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+276
+00:24:30,260 --> 00:24:31,960
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+277
+00:24:31,960 --> 00:24:32,140
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+278
+00:24:32,140 --> 00:24:32,140
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+279
+00:24:32,140 --> 00:24:34,240
+هيدريت هيدريت هيدريت هيدريت هيدby addition
+
+280
+00:24:34,240 --> 00:24:40,000
+reaction الـ hemacetal is formed also by addition
+
+281
+00:24:40,000 --> 00:24:43,760
+reaction على ال الديهيد والكيتون ال acetal
+
+282
+00:24:43,760 --> 00:24:51,340
+substitution reaction على ال hemacetal واضح ال
+
+283
+00:24:51,340 --> 00:24:55,480
+acetal هو عبارة عن عملية إبدال ال OH اللي موجودة
+
+284
+00:24:55,480 --> 00:25:00,120
+في ال hemacetal واضح هذه التفاعلات والعائلات
+
+285
+00:25:00,120 --> 00:25:01,740
+الجديدة والمسميات
+
+286
+00:25:07,510 --> 00:25:14,790
+الان هذا الحقيقة تفاعل الاسيتال والهيمياسيتال
+
+287
+00:25:14,790 --> 00:25:22,070
+تفاعل مهم جدا ممكن ايضا طالما المكونات تبعته كحول
+
+288
+00:25:22,070 --> 00:25:27,670
+بيهاجم على ايش الديهايد او كيتون الان لو انا
+
+289
+00:25:27,670 --> 00:25:31,150
+اتخيلت هي الديهايد او كيتون كحول هاجم عليه شو
+
+290
+00:25:31,150 --> 00:25:36,710
+الناتج؟Hemiacetal طيب السؤال لو ال الديهايد و ال
+
+291
+00:25:36,710 --> 00:25:40,930
+alcohol بنفس الجزئ يعني تخيلنا هيك جزئ سلسلة على
+
+292
+00:25:40,930 --> 00:25:46,330
+أحد أطرافها الديهايد و على الطرف التاني OH و إجت
+
+293
+00:25:46,330 --> 00:25:52,170
+فاعل هذه هاجمتها و السيطة بالبندق شو صارت OH هذا
+
+294
+00:25:52,170 --> 00:25:56,370
+التفاعل بنسميه Intermolecular ولا Intramolecular
+
+295
+00:25:57,570 --> 00:26:00,950
+Intramolecular شو يعني Intramolecular تفاعل بين
+
+296
+00:26:00,950 --> 00:26:06,430
+جزئين مفصولين تماما هذا جزء و هذا جزء جاء الجزئين
+
+297
+00:26:06,430 --> 00:26:10,150
+المفصولين تماما يتفاعلوا مع بعض هذا Intermolecular
+
+298
+00:26:10,150 --> 00:26:15,510
+بين جزئين مفصولين الان لو هذا الجزء و هذا الجزء
+
+299
+00:26:15,510 --> 00:26:21,430
+ممسكين بنفس السلسلة زي هذا المثال لاحظوا هذه سلسلة
+
+300
+00:26:21,430 --> 00:26:28,570
+واضح على أحد أطرافهاالديهايد وعلى الطرف الثاني
+
+301
+00:26:28,570 --> 00:26:32,790
+كحول فالجزئين اللي بدهم يتفاعلوا موجودين بنفس
+
+302
+00:26:32,790 --> 00:26:36,830
+المركب مش بمركبين مختلفين في هذه الحالة إذا
+
+303
+00:26:36,830 --> 00:26:40,730
+الجزئين اللي بتفاعلوا بنفس المركب على طول التفاعل
+
+304
+00:26:40,730 --> 00:26:47,380
+إيش أنا بأوصفه Intramolecular reactionفالـ
+
+305
+00:26:47,380 --> 00:26:51,120
+Intramolecular معناه ذلك أن الجزئين اللي بتفعلوا
+
+306
+00:26:51,120 --> 00:26:55,860
+بنفس الجزئ لكن الـ Intermolecular لأ جزئين مفصلين
+
+307
+00:26:55,860 --> 00:27:00,780
+و بيجوا يتفعلوا مع بعض واضح؟ هذا الأمر موجود كتير
+
+308
+00:27:00,780 --> 00:27:05,620
+الآن خلّيت الكحول و الالدهايد بنفس الجزئ التفاعل
+
+309
+00:27:05,620 --> 00:27:10,540
+أكيد إضافة الكحول بده يهاجم هنا و هاد السيطة بالـ
+
+310
+00:27:10,540 --> 00:27:16,270
+Bond O شو بده تصيرOH احنا قلنا في كل الأحوال دائما
+
+311
+00:27:16,270 --> 00:27:20,310
+ال C double bond O بتصير OH يمكن في كل الأمثلة
+
+312
+00:27:20,310 --> 00:27:25,690
+السابقة رسمناها بالأخضر و ال nucleophile هاجم بهذا
+
+313
+00:27:25,690 --> 00:27:32,110
+الشكل الآن هذا المركب اللي متكون عنده أيضا
+
+314
+00:27:32,110 --> 00:27:37,370
+hemacetal ولا لأ؟ أكيد لأن high carbon حاملة OH
+
+315
+00:27:41,220 --> 00:27:45,560
+هذا Hemacetal لكن التفاعل بهذه الحالة
+
+316
+00:27:45,560 --> 00:27:52,000
+Intramolecular reaction الان هذا التفاعل جزء من
+
+317
+00:27:52,000 --> 00:27:58,390
+أهميته انه في ال biochemistryإذا عندكم فكرة خفيفة
+
+318
+00:27:58,390 --> 00:28:03,190
+أو هيمر عليكم لما بناخد السكريات ال sugars احنا
+
+319
+00:28:03,190 --> 00:28:08,150
+قولنا ال sugars they are polyhydroxy aldehydes او
+
+320
+00:28:08,150 --> 00:28:12,890
+كيتون هى عبارة عن الديهيد او كيتون مع مجموعات
+
+321
+00:28:12,890 --> 00:28:17,510
+اوقاتش كبيرة الديهيد لحاله بيعملش sugar ومجموعات
+
+322
+00:28:17,510 --> 00:28:21,490
+اوقاتش كتيرة لحالها بتعملش ايش sugar فال sugar
+
+323
+00:28:21,490 --> 00:28:26,130
+عبارة عن ايشموجود فيه يا الديهايد يا كيتون
+
+324
+00:28:26,130 --> 00:28:31,290
+ومجموعات OH's الآن طالما وجد فيه على جهة معينة
+
+325
+00:28:31,290 --> 00:28:34,950
+الديهايد او كيتون هي C double bond او نتخيل هيك وع
+
+326
+00:28:34,950 --> 00:28:40,980
+الجهة التانيةأو أتشز ممكن هذه ال أو أتشز تسكر على
+
+327
+00:28:40,980 --> 00:28:45,600
+ال الديهايد أو ال كيتون أكيد بتعمل في هذه الحالة
+
+328
+00:28:45,600 --> 00:28:49,520
+hemeacetal بس لما تسكر بدل ما ال sugar كان عامل
+
+329
+00:28:49,520 --> 00:28:54,480
+سلسلة بهذا الشكل ال chain بيصير إيش in the cyclic
+
+330
+00:28:54,480 --> 00:28:58,440
+form كل كمار عليكوا أن السكر بيكون في ال chain
+
+331
+00:28:58,440 --> 00:29:06,430
+formكسلسلة و بيكون بـ Cyclic Form كحلقة الآن عملية
+
+332
+00:29:06,430 --> 00:29:12,090
+إغلاق السكر هي عملية تفاعل Hemacetal Formation
+
+333
+00:29:12,090 --> 00:29:17,890
+Hemacetal Formation هاي السكر اللي مسكر الجلوكوز
+
+334
+00:29:17,890 --> 00:29:22,650
+هذا منظر الجلوكوز اللي مسكر لاحظوا هذه ال carbon
+
+335
+00:29:22,650 --> 00:29:32,570
+تحديدا اللي هنا هي فيها OHو OR اللى هو alcohol و
+
+336
+00:29:32,570 --> 00:29:36,910
+ether طب لو قولنا لأى حد اذكرنا كيف هذه كانت قبل
+
+337
+00:29:36,910 --> 00:29:43,250
+التفاعل قبل ما يسكر كانت هذه C double bond O وكانت
+
+338
+00:29:43,250 --> 00:29:52,240
+هذه OH وماكنش فيه رابطةكانت هذه C double bond O L
+
+339
+00:29:52,240 --> 00:29:57,780
+D I و هذه O H فهذه ال O H سكرت هنا و C double bond
+
+340
+00:29:57,780 --> 00:30:05,240
+O صارتOH بهذا الشكل فلو اجينا سألناكوا سؤال
+
+341
+00:30:05,240 --> 00:30:10,260
+وقلنالكم cyclic glucose انتبهوا معايا هاي ال
+
+342
+00:30:10,260 --> 00:30:14,480
+glucose اللي مسكرة تكونوا فاهمين العائلات كويسة
+
+343
+00:30:14,480 --> 00:30:20,420
+cyclic glucose is a hydrate يعني في تنتين OH على
+
+344
+00:30:20,420 --> 00:30:21,140
+الكربون
+
+345
+00:30:25,890 --> 00:30:30,950
+cyclic glucose is a hydrate no cyclic glucose is
+
+346
+00:30:30,950 --> 00:30:38,450
+an acetal في تنتين OR برضه false cyclic glucose is
+
+347
+00:30:38,450 --> 00:30:48,340
+a hemacetal في OH و OR واضحة الفكرةالان ممكن نسأل
+
+348
+00:30:48,340 --> 00:30:54,180
+السؤال بطريقة تانية Cyclic glucose is formed by a
+
+349
+00:30:54,180 --> 00:30:55,960
+substitution reaction
+
+350
+00:30:58,930 --> 00:31:03,610
+by an addition reaction شوف كيف اللي بيفهم شغلة
+
+351
+00:31:03,610 --> 00:31:07,770
+بيحس انه ممكن نسأل عن الشغلة بقالف طريق أنا مش
+
+352
+00:31:07,770 --> 00:31:10,610
+الفكرة ان اخوفكم من الأسئلة و الانتحانات بقدر ما
+
+353
+00:31:10,610 --> 00:31:16,130
+اني بركز المعلومة عندكم ان هذه فعلا كانت C double
+
+354
+00:31:16,130 --> 00:31:20,430
+bond O و هذه فعلا كانت OH هذا alcohol و هذا
+
+355
+00:31:20,430 --> 00:31:23,750
+aldehyde الآن ال alcohol و ال aldehyde بيتفاعلوا
+
+356
+00:31:23,750 --> 00:31:31,560
+تفاعل ايش اضافة بكونه hemiacetalواضح؟ الآن بعد ما
+
+357
+00:31:31,560 --> 00:31:37,160
+اتكون الـ hemacetal هذا وصار هنا في OR و OH ممكن
+
+358
+00:31:37,160 --> 00:31:44,040
+يصير تفاعل تاني تبدل في ال OH ل OR مع كحول تاني
+
+359
+00:31:44,040 --> 00:31:48,260
+خارجي يعني افترضوا ناس جابوا ميثانول وفعلوا مع هذا
+
+360
+00:31:48,260 --> 00:31:55,530
+شو هيعمل الميثانول؟هيشيل ال OH يخليها OR صار عندكم
+
+361
+00:31:55,530 --> 00:32:01,890
+OR OR أسيتال بس ب substitution reaction تاني واضح
+
+362
+00:32:01,890 --> 00:32:06,350
+انما ال cyclic glucose في نص الطريق هو عبارة عن
+
+363
+00:32:06,350 --> 00:32:11,500
+ايش؟Hemiacetal Cyclic Glucose is Hemiacetal ممكن
+
+364
+00:32:11,500 --> 00:32:15,920
+تحويله ل Acetal بالتفاعل مع الكحول أكيد لأن احنا
+
+365
+00:32:15,920 --> 00:32:20,820
+قلنا التفاعل ع مرحلتين إضافة ثم إبدال أنا لما وصلت
+
+366
+00:32:20,820 --> 00:32:24,900
+ل Hemacetal عملت الإضافة الآن إذا الإنسان بيجيب
+
+367
+00:32:24,900 --> 00:32:30,860
+كحول و حامض و بيسخنه ممكن يعمل إيش الإبدال و يحوله
+
+368
+00:32:30,860 --> 00:32:37,360
+إلى Acetal كاملهنا في عندى على هذه النقطة كمان
+
+369
+00:32:37,360 --> 00:32:46,320
+مثال جميل انه انا جبت ال Acetone كيتون مع Ethylene
+
+370
+00:32:46,320 --> 00:32:51,740
+Glycol او اللى سميناه Ethanediol هذا المركب كام OH
+
+371
+00:32:51,740 --> 00:32:58,200
+فيهTintin يعني كأنه هذا Dialcohol الان لما فعلنا
+
+372
+00:32:58,200 --> 00:33:03,200
+اعطانا هذا المركب المغلق يمكن واحدة تقول طب كيف تم
+
+373
+00:33:03,200 --> 00:33:08,600
+هذا التفاعل؟ بنقول بهدوء ممكن نفهم كيف تم الان
+
+374
+00:33:08,600 --> 00:33:13,540
+نتعامل مع هذا كيتون و مع هذا الكهول كيف الكهول
+
+375
+00:33:13,540 --> 00:33:17,700
+بتفاعل على الكيتون او على الديهايد بال addition
+
+376
+00:33:17,700 --> 00:33:24,310
+هذه بتيجي تضيف هنا و هذه بتصيرOH إذا لو قلنا شو
+
+377
+00:33:24,310 --> 00:33:32,770
+الناتج اللي في هذه الحالة بيصير C OH CH3 CH3 هذا
+
+378
+00:33:32,770 --> 00:33:37,590
+الجزء اللي كان أسيتون والجزء التاني هو عبارة عن O
+
+379
+00:33:37,590 --> 00:33:48,890
+CH2 CH2 OH هاي كحول اتفاعل مع كيتون ال C double
+
+380
+00:33:48,890 --> 00:33:54,500
+bond O صارتOH والكحول اتفاعل هنا الان الكحول نفسه
+
+381
+00:33:54,500 --> 00:34:00,220
+في داخله OH تاني يعني كأن الكحول كحولين في بعض في
+
+382
+00:34:00,220 --> 00:34:04,740
+مجموعتين OH هذا المركب اللي هنا carbon حاملة OH و
+
+383
+00:34:04,740 --> 00:34:10,660
+OR شو عبارة عن ايش Himacetal الان ممكن يعمل كمان
+
+384
+00:34:10,660 --> 00:34:16,680
+تفاعل ان هذه تهاجم هنا و تحل محل هذه ابدال
+
+385
+00:34:17,800 --> 00:34:21,920
+و انت بتطلع عندى هذا المركب لحظة هذا المركب carbon
+
+386
+00:34:21,920 --> 00:34:27,680
+حاملة OR و OR اذا هذا عبارة عن ايش
+
+387
+00:34:30,910 --> 00:34:36,990
+Hemiacetal لاحظوا هنا اعملت التفاعل على مرتين لكن
+
+388
+00:34:36,990 --> 00:34:42,970
+مش من كحولين مفصلين لأ الكحولين موجودين بإيش؟ بنفس
+
+389
+00:34:42,970 --> 00:34:47,330
+الجزء نفس الجزء فيه تن تن و اتش يعني كأنه الجزء زي
+
+390
+00:34:47,330 --> 00:34:53,410
+ما بيقولوا اليوم في الدعايات إيش؟ two in oneطالما
+
+391
+00:34:53,410 --> 00:34:58,470
+في اتنين OH اذا صار عبارة عن كحولين في نفس الجزء
+
+392
+00:34:58,470 --> 00:35:03,710
+طالما مجمعتين OH الكحول OH هذا في OH OH صار كحولين
+
+393
+00:35:03,710 --> 00:35:09,650
+اتفاعل في المرة الأولى بالاضافة و في المرة الثانية
+
+394
+00:35:09,650 --> 00:35:15,380
+بالابدالةشوفنا كيف ادول التفاعلين تموا addition
+
+395
+00:35:15,380 --> 00:35:19,640
+followed by substitution الان هذا المركب اتجه من
+
+396
+00:35:19,640 --> 00:35:23,360
+الاسيتون و من الاثيلين جليكول عشان يسموه اسيتون
+
+397
+00:35:23,360 --> 00:35:28,820
+اثيلين جليكول لاحظوا ايش استعمله اسيتال منطق
+
+398
+00:35:28,820 --> 00:35:32,480
+اسيتال لانه OR و OR اسيتال
+
+399
+00:35:42,600 --> 00:35:48,900
+الان من التفاعلات انه نستعمل نيكليوفايل مجموعة ال
+
+400
+00:35:48,900 --> 00:35:52,680
+CNI و بتذكروا احنا لما أخدنا ال CNI تقولنا بتتفاعل
+
+401
+00:35:52,680 --> 00:35:56,460
+من اي طرف من الكربون ولا من ال نيتروجين من الكربون
+
+402
+00:35:56,460 --> 00:36:01,200
+كل اللي مطلوب انه ال CN تهاجم هنا و الصيدة بال
+
+403
+00:36:01,200 --> 00:36:06,580
+bond O تصير OH الان صار عندى عائلة جديدة على
+
+404
+00:36:06,580 --> 00:36:13,040
+الكربون ايش المجمعتين اللي موجودين CNN و OHو OH
+
+405
+00:36:13,040 --> 00:36:20,700
+لاحظوا C و تلتين OH هيدريت OH و OR هيمي أسيتال OR
+
+406
+00:36:20,700 --> 00:36:27,340
+و OR أسيتال الان OH و CNN بسميها سيانو هيدرين
+
+407
+00:36:27,340 --> 00:36:37,760
+بسميها سيانو هيدرين واضح سيانو هيدرين الان
+
+408
+00:36:39,440 --> 00:36:43,880
+لو عملنا التفاعل مع الاسيتالديهيد هذا المركب شو
+
+409
+00:36:43,880 --> 00:36:51,320
+هسميه اسيتالديهيد سيانوهيدرين لو عملت التفاعل مع
+
+410
+00:36:51,320 --> 00:36:57,100
+الاسيتون هذا المركب ايش هسميه اسيتون هاي جزء
+
+411
+00:36:57,100 --> 00:37:05,520
+الاسيتون مش الاسيتون عبارة عن CH3CCH3 بدون ال
+
+412
+00:37:05,520 --> 00:37:10,950
+oxygen اسيتونCyanohedron لو عملتم مع الـ
+
+413
+00:37:10,950 --> 00:37:16,250
+Cyclohexanone هذي الـ C double bond O إيش هتصير؟
+
+414
+00:37:16,250 --> 00:37:21,650
+OH وهي الـ Cl شو هسميه؟ Cyclohexanone
+
+415
+00:37:21,650 --> 00:37:23,470
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+416
+00:37:23,470 --> 00:37:23,530
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+417
+00:37:23,530 --> 00:37:23,810
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+418
+00:37:23,810 --> 00:37:24,510
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+419
+00:37:24,510 --> 00:37:26,930
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+420
+00:37:26,930 --> 00:37:26,930
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+421
+00:37:26,930 --> 00:37:27,010
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+422
+00:37:27,010 --> 00:37:31,690
+Cyclohexanone
+
+423
+00:37:31,690 --> 00:37:37,790
+Cyclohexanone Cyclohexanone
+
+424
+00:37:40,220 --> 00:37:47,620
+الدهايد بنزالدهايد سيانو هيدرل يعني لو قلنا لأي
+
+425
+00:37:47,620 --> 00:37:53,440
+واحدة أرسمينا بنزالدهايد سيانو هيدرل في الامتحان
+
+426
+00:37:53,440 --> 00:37:58,360
+بدا تيجي تفكر تتخيل بسهولة ماتاخدش وقت منكوا
+
+427
+00:37:58,360 --> 00:38:05,530
+ببساطة هاي ال بنزالدهايد صح ولا لألازم في الأصل
+
+428
+00:38:05,530 --> 00:38:09,390
+تكون عارفة الـ Benzaldehyde مجرد ما نقولها سيانو
+
+429
+00:38:09,390 --> 00:38:17,490
+هيدرين الـ C بابل بوند O OH OHIJNQCN مش عملية صعبة
+
+430
+00:38:17,490 --> 00:38:23,090
+Benzaldehyde cyanohydrin واضح الفكرة؟ لاحظوا أنا
+
+431
+00:38:23,090 --> 00:38:27,650
+كاتب له common name نفس
+
+432
+00:38:27,650 --> 00:38:30,830
+الـ Benzaldehyde cyanohydrin له common name
+
+433
+00:38:30,830 --> 00:38:33,330
+Manbilonitride
+
+434
+00:38:34,290 --> 00:38:42,750
+mandilo mandel بالالماني يعني لوز انتوا بتذاكرين
+
+435
+00:38:42,750 --> 00:38:46,750
+قبل شوية لما أخدنا ال benzaldehyde قولنا oil of
+
+436
+00:38:46,750 --> 00:38:54,170
+almond اللوز بالانجليزي بالالماني mandel ومن هنا
+
+437
+00:38:54,170 --> 00:38:58,950
+استعمل mandilo nitral mandel من اللوز يعني كتير من
+
+438
+00:38:58,950 --> 00:39:04,150
+ال common name علاقة في إيشفي أصل المركب من أي
+
+439
+00:39:04,150 --> 00:39:08,130
+منطقة نباتية اشتهر ان هذا المركب انفصل
+
+440
+00:39:08,130 --> 00:39:12,990
+فالمنديلونيترال هو ال benzaldehyde cyanohydrin
+
+441
+00:39:12,990 --> 00:39:14,370
+واضح الفكرة؟
+
+442
+00:39:20,340 --> 00:39:24,120
+اتخيلوا عاد كيف الطالب لما بيبعد عن الكلام احنا
+
+443
+00:39:24,120 --> 00:39:28,320
+مرة جيبناله سؤال في الامتحان ارسم العائلة العامة و
+
+444
+00:39:28,320 --> 00:39:33,940
+كتبناله Hydrate, Hemacetal, Acetal وCyanohydrin
+
+445
+00:39:33,940 --> 00:39:37,420
+انا بدي احط هدوله و هنا يعمل شرط اما يكتبليش اشي
+
+446
+00:39:37,420 --> 00:39:42,240
+يعني في مجبوعتين صعبة ولا سهلة؟ سهلة جدا .. سهلة
+
+447
+00:39:42,240 --> 00:39:45,020
+جدا .. الآن
+
+448
+00:39:46,660 --> 00:39:53,640
+بنجي لنيكليوفايل جديد هذا النيكليوفايل الجديد هو H
+
+449
+00:39:53,640 --> 00:40:01,080
+- متذكرين انتوا انه احنا لما حكينا عن الهيدروجين،
+
+450
+00:40:01,080 --> 00:40:07,580
+قولنا الهيدروجين بيدا تمر علينا بكم شكل؟ تلت أشكال
+
+451
+00:40:07,580 --> 00:40:10,700
+H plus وH
+
+452
+00:40:14,320 --> 00:40:19,580
+و أعطناهم أسماء الـ H بلس شو قلنا عنها البروتون
+
+453
+00:40:19,580 --> 00:40:25,480
+اللي بيفقد الحامض و الـ H هيدروجين أتم الـ H minus
+
+454
+00:40:25,480 --> 00:40:30,880
+هيدرايد أنيون الان مين في هدولة التلاتة
+
+455
+00:40:30,880 --> 00:40:38,080
+نيوكليوفاين الهيدرايد أنيون طيب انتهت الكلام طالما
+
+456
+00:40:38,080 --> 00:40:44,480
+الهيدرايد أنيوناليوكليوفايل لو أخدت الديهيد زي هذا
+
+457
+00:40:44,480 --> 00:40:48,040
+خلّيني أقول ال Acetaldehyde وهي ال H وحملة ال
+
+458
+00:40:48,040 --> 00:40:52,860
+minus وقلتلكوا أكمل المعادلة ال hydride بدو يتفعل
+
+459
+00:40:52,860 --> 00:40:59,320
+مع هذا شو هيعمل ال C double bond O هتصير O H هي
+
+460
+00:40:59,320 --> 00:41:03,480
+باللون الأخضر واليوكليوفايل بهذه الحالة هو عبارة
+
+461
+00:41:03,480 --> 00:41:12,270
+عن إيش ال Hما العائلة الجديدة اللتي تكونت هنا؟كحول
+
+462
+00:41:12,270 --> 00:41:17,650
+هذه عملية الاختزال الار بيصير السؤال هو بالدنيا
+
+463
+00:41:17,650 --> 00:41:23,870
+بينباع H- لحاله؟ لأ بينباع على شكل المراكبات
+
+464
+00:41:23,870 --> 00:41:29,970
+المراكبات اللي بتكون مصدر للhydride anion موجود
+
+465
+00:41:29,970 --> 00:41:33,930
+منها وتستعمل كعوامل مختزلة لحظوا هذه العملية
+
+466
+00:41:33,930 --> 00:41:38,410
+اختزال لأن C double bond O صارت OH واحدة نقص في
+
+467
+00:41:38,410 --> 00:41:44,610
+محتوىالأكسوجين وزيادة في محتوى الهيدروجين أنا زيدت
+
+468
+00:41:44,610 --> 00:41:49,430
+هنا H وزيدت هنا H هايهم تنتين هذا الاختزال بعينه
+
+469
+00:41:49,430 --> 00:41:54,690
+مظبوط ولا لأ الآن العوامل المختزلة عادة بتكون
+
+470
+00:41:54,690 --> 00:41:58,410
+هيدرايد أو ممكن الإنسان يعملها بإضافة الهيدروجين
+
+471
+00:41:58,410 --> 00:42:02,120
+هنا إحنا إيش اللي بنستعمله الهيدرايدلحظوا من
+
+472
+00:42:02,120 --> 00:42:06,320
+الهيدرايتز اللي مشهورة جدا هذا المركّب الليثيام
+
+473
+00:42:06,320 --> 00:42:12,340
+والألمنيوم اللي متصل ب 4H- لحظوا الألمنيوم بوضعه
+
+474
+00:42:12,340 --> 00:42:18,880
+الطبيعي بيكون ايش تلاتة موجة حطوا عليه 4H- كل ال
+
+475
+00:42:18,880 --> 00:42:23,920
+ايون شو هيصفاه minus عشان يطلع الجزية متعادلة
+
+476
+00:42:23,920 --> 00:42:31,420
+بحطله lithium plusهذا بيصير Lithium Tetrahydride
+
+477
+00:42:31,420 --> 00:42:39,180
+Aluminate طبعا الات هي نهاية إيش؟ الايون السالب مش
+
+478
+00:42:39,180 --> 00:42:43,440
+أخدنا احنا الايونات السالبة سولفات، كربونات،
+
+479
+00:42:43,440 --> 00:42:50,230
+نيترات، أسيتات، الآن هنا قولنا إيش؟ Aluminateكل
+
+480
+00:42:50,230 --> 00:42:57,290
+عمره بنقول سلفيت SO4 minus minus نيتريت NO3 minus
+
+481
+00:42:57,290 --> 00:43:03,170
+فال eight نهاية ال ايش ال ايون السالب الان هذا
+
+482
+00:43:03,170 --> 00:43:07,050
+الجزء متعادل لان عندي ليثيام plus والالمنيوم تلاتة
+
+483
+00:43:07,050 --> 00:43:12,770
+plus هاي أربعة موجب وال H أربعة minus صف الجزء كله
+
+484
+00:43:12,770 --> 00:43:18,190
+ايش ليثيام تترا هيدرايدو ألمينيت أو هذا من البورون
+
+485
+00:43:18,950 --> 00:43:26,130
+Sodium Tetrahydride من البرون بوريت مش من البروم
+
+486
+00:43:26,130 --> 00:43:31,350
+البرون لما تمشوا في أول الجدول الدوري العنصر
+
+487
+00:43:31,350 --> 00:43:35,890
+الخامس يعني تطلعوا على عناصر الجدول الدوري H بعدين
+
+488
+00:43:35,890 --> 00:43:41,590
+helium بعدين lithium بعدين beryllium بعدين boron
+
+489
+00:43:41,590 --> 00:43:48,520
+واضح؟ اه ال boronSodium tetrahydride borate الان
+
+490
+00:43:48,520 --> 00:43:52,160
+هذول الحقيقة بياخدوا كمان اسماء تانية لو سمعتهم
+
+491
+00:43:52,160 --> 00:43:55,700
+بأي اسمين هذول من أشهر العوامل المختز ل ال
+
+492
+00:43:55,700 --> 00:44:02,140
+hydrides هم ببساطة مصدر ل إيش ل H minus يعني احنا
+
+493
+00:44:02,140 --> 00:44:06,840
+بنفهمه مصدر ل H minus هذا بيسموه ال lithium
+
+494
+00:44:06,840 --> 00:44:13,460
+tetrahydride aluminate بيسموه lithium aluminum
+
+495
+00:44:13,460 --> 00:44:20,740
+hydrideالومينوم هايدرايد يعني نفسه ممكن تلاقوه تحت
+
+496
+00:44:20,740 --> 00:44:24,840
+اسم ليثيام ألومينوم هايدرايد أو ليثيام تيترا
+
+497
+00:44:24,840 --> 00:44:29,260
+هايدرايد و ألومينيت وهذا بيسموه صوديوم بورو
+
+498
+00:44:29,260 --> 00:44:35,230
+هايدرايد مش بورونBorohydride فإذا سمعتوا Sodium
+
+499
+00:44:35,230 --> 00:44:38,770
+Borohydride أو Sodium Tetrahydride و Borate نفس
+
+500
+00:44:38,770 --> 00:44:43,330
+الاسم Lithium Tetrahydride و Aluminate أو Lithium
+
+501
+00:44:43,330 --> 00:44:47,690
+Aluminum Hydride نفس الاسم و مرات كتير حتى الاسم
+
+502
+00:44:47,690 --> 00:44:52,530
+هذا Sodium Borohydride و عادة مش هيكونوا عاملينه
+
+503
+00:44:52,530 --> 00:44:57,310
+زيك هتلاعظوا على السهم مكتوب عندكم NABH4
+
+504
+00:44:58,940 --> 00:45:05,980
+وهنا هتلاحظوا Lithium Aluminum H4 اذا شفتوا هذا او
+
+505
+00:45:05,980 --> 00:45:09,780
+هذا هذا Sodium Borohydride Lithium Aluminum
+
+506
+00:45:09,780 --> 00:45:16,560
+Hydride شوفوا مثلها Sodium Borohydride Lithium
+
+507
+00:45:16,560 --> 00:45:21,220
+Aluminum Hydride هدوله الشرعوه المختزلة هم في
+
+508
+00:45:21,220 --> 00:45:27,990
+النهاية مصدر لإيش؟لل H- الان ال H- لما هاجم على ال
+
+509
+00:45:27,990 --> 00:45:34,850
+aldehyde عملوا ايش؟ كحول وهذه عملية الاختزال عكس
+
+510
+00:45:34,850 --> 00:45:40,150
+عملية ايش؟ الاكسادة هذه عملية الاختزال عكس عملية
+
+511
+00:45:40,150 --> 00:45:47,190
+الاكسادة هي reducing agents طبعا لو ال H- هاجم على
+
+512
+00:45:47,190 --> 00:45:53,490
+كيتون هيعملوا ايش؟secondary alcohol اذا انتبهوا
+
+513
+00:45:53,490 --> 00:45:59,030
+معي جيدا انه لما الهجوم تم على ال الديهايد عادي
+
+514
+00:45:59,030 --> 00:46:06,550
+اتكول اه اذا هل جيتها بنصير نكتب reduction عشان
+
+515
+00:46:06,550 --> 00:46:11,950
+تكون واضحة الأمور معاكم قبل الديهايدs produces
+
+516
+00:46:11,950 --> 00:46:19,070
+primary alcoholreduction of aldehydes produces
+
+517
+00:46:19,070 --> 00:46:23,950
+primary alcohols الان تحتها هيصير reduction of
+
+518
+00:46:23,950 --> 00:46:28,890
+كيتون ايش
+
+519
+00:46:28,890 --> 00:46:35,050
+produces secondary alcohols هو كل درسنا aldehydes
+
+520
+00:46:35,050 --> 00:46:40,240
+او كيتون ولا في غيرهم؟أذا بدنا نكون عارفين ان ال
+
+521
+00:46:40,240 --> 00:46:45,240
+الديهايد لما بنعمله reduction بالهيدرايد بده يصير
+
+522
+00:46:45,240 --> 00:46:50,080
+عنده primary alcohol و ال ketone لما بنعمله
+
+523
+00:46:50,080 --> 00:46:54,240
+reduction بال الديهايد بده يصير عنده secondary
+
+524
+00:46:54,240 --> 00:46:58,940
+alcohol لاحظوا هذا الكلام بفيدكم سواء بجمل صح و
+
+525
+00:46:58,940 --> 00:47:03,820
+غلط بأكمل معادلة او حتى لو احنا سألناكوا سؤال how
+
+526
+00:47:03,820 --> 00:47:09,210
+can you prepare the following compoundواضح؟ لما
+
+527
+00:47:09,210 --> 00:47:12,610
+تشوفوا أن الناتج اللي عندكم primary alcohol إذا
+
+528
+00:47:12,610 --> 00:47:16,530
+بتقدروا تفكروا أنه ممكن يكون إيجا من وين لما
+
+529
+00:47:16,530 --> 00:47:19,930
+تشوفوا الناتج اللي عندكم secondary alcohol إذا
+
+530
+00:47:19,930 --> 00:47:25,430
+ممكن يكون إيجا من وين من كيتون واضح الفكرة؟ بنقف
+
+531
+00:47:25,430 --> 00:47:29,510
+عند هذه النقطة المرة القادمة إن شاء الله بنحكي عن
+
+532
+00:47:29,510 --> 00:47:34,690
+تفاعل الديهيدس والكيتون مع متفاعل اسمه green yard
+
+533
+00:47:34,690 --> 00:47:39,740
+reagent عمرنا حكينا عنه؟بنعرفه المرة الجاية وبنشوف
+
+534
+00:47:39,740 --> 00:47:44,440
+كيف بتفاعل ال الديهيد والكيتون مع ال green yard
+
+535
+00:47:44,440 --> 00:47:46,220
+reagent شكرا
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..a06edd19fb44e491212b9dcf2d41eae9c2b33efe
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/deKbe0lopF8_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2188, "start": 20.28, "end": 21.88, "text": "بسم الله الرحمن الرحيم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640], "avg_logprob": -0.04143066443502903, "compression_ratio": 1.0789473684210527, "no_speech_prob": 0.0, "words": [{"start": 20.28, "end": 20.86, "word": "بسم", "probability": 0.898193359375}, {"start": 20.86, "end": 21.06, "word": " الله", "probability": 0.9677734375}, {"start": 21.06, "end": 21.44, "word": " الرحمن", "probability": 0.9816080729166666}, {"start": 21.44, "end": 21.88, "word": " الرحيم", "probability": 0.99462890625}], "temperature": 1.0}, {"id": 2, "seek": 5137, "start": 22.71, "end": 51.37, "text": "في موضوع ال alcohols اللى بدأنا فيه المرة الماضية موضوع ال acidity of alcohols او حمضية الكحولات هو موضوع مهم جدا الان يمكن موضوع ال acidity كمان يمر علينا باكثر من موقع في ال organ chemistry ربما بشكل أساسي في ال carboxylic acids يمر علينا موضوع ال acidity", "tokens": [41185, 3714, 2407, 11242, 45367, 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ربما حسب التدرج اللي اتعلمته في المدارس أول ما بيمر على الناس ال Arrhenius definition تعريف Arrhenius للحمض و القلوي خلنا نشوفه ال Arrhenius definition من خلال مثال", "tokens": [27842, 37279, 16572, 5172, 3714, 9640, 25894, 24793, 5551, 4117, 2655, 2288, 9154, 37279, 16572, 5172, 24976, 35571, 11242, 13412, 2407, 31439, 21542, 2304, 11242, 4032, 13412, 2407, 25062, 1211, 45865, 12602, 3555, 15042, 11331, 35457, 16712, 3215, 47341, 13672, 1829, 1975, 2655, 3615, 19528, 47395, 8978, 9673, 3215, 9640, 3794, 5551, 12610, 19446, 4724, 1829, 29973, 15844, 2423, 8315, 3794, 2423, 1587, 81, 2932, 4872, 7123, 37279, 16572, 5172, 1587, 81, 2932, 4872, 24976, 35571, 11242, 4032, 25062, 1211, 45865, 16490, 1211, 8315, 8717, 8592, 38688, 3224, 2423, 1587, 81, 2932, 4872, 7123, 9154, 16490, 1211, 6027, 50113, 6027], "avg_logprob": -0.13551980552106802, "compression_ratio": 1.8865979381443299, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 110.85, "end": 111.15, "word": "من", 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"start": 242.8, "end": 258.02, "text": "خلّى تعريف الحامض زى ما هو اللى بيعطى H بلس فى التأيون واضح فالحامض عند لوري برويستن شو بيعطينى H بلس وبناء على ذلك وين بده يكون الحمض الـHCl كله عنده حامض", "tokens": [9778, 1211, 11703, 7578, 37279, 16572, 5172, 21542, 10943, 11242, 30767, 7578, 19446, 31439, 13672, 7578, 4724, 40228, 9566, 7578, 389, 4724, 1211, 3794, 6156, 7578, 16712, 10721, 1829, 11536, 4032, 46958, 5016, 6156, 6027, 5016, 10943, 11242, 43242, 5296, 13063, 1829, 4724, 32887, 1829, 14851, 1863, 13412, 2407, 4724, 1829, 3615, 9566, 9957, 7578, 389, 4724, 1211, 3794, 46599, 1863, 16606, 15844, 29910, 23275, 4032, 9957, 47525, 3224, 7251, 30544, 21542, 2304, 11242, 2423, 39184, 39, 9966, 28242, 3224, 43242, 3224, 11331, 10943, 11242], "avg_logprob": -0.23219477385282516, "compression_ratio": 1.6606060606060606, "no_speech_prob": 0.0, "words": [{"start": 242.8, "end": 243.22, "word": "خلّى", "probability": 0.8565673828125}, {"start": 243.22, "end": 243.6, "word": " تعريف", 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"text": "زي ما أتيت هنا وأخدت مركز القوة هذا تعالي ناخد مركز القوة الـ H Plus", "tokens": [11622, 1829, 19446, 5551, 31371, 2655, 34105, 36725, 9778, 3215, 2655, 3714, 31747, 11622, 25062, 2407, 3660, 23758, 37279, 6027, 1829, 8717, 47283, 3215, 3714, 31747, 11622, 25062, 2407, 3660, 2423, 39184, 389, 7721], "avg_logprob": -0.3888392874172756, "compression_ratio": 1.2857142857142858, "no_speech_prob": 0.0, "words": [{"start": 397.76, "end": 398.74, "word": "زي", "probability": 0.621826171875}, {"start": 398.74, "end": 398.86, "word": " ما", "probability": 0.82080078125}, {"start": 398.86, "end": 399.34, "word": " أتيت", "probability": 0.589599609375}, {"start": 399.34, "end": 399.56, "word": " هنا", "probability": 0.7333984375}, {"start": 399.56, "end": 400.14, "word": " وأخدت", "probability": 0.7818603515625}, {"start": 400.14, "end": 400.66, "word": " مركز", "probability": 0.9484049479166666}, {"start": 400.66, "end": 401.22, "word": " القوة", "probability": 0.9742838541666666}, 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Lewis هو H بلس", "tokens": [6027, 39184, 13931, 12, 6156, 4117, 33456, 3224, 5551, 9778, 1211, 2655, 9154, 23758, 25724, 11622, 38207, 16247, 3794, 32277, 1829, 8978, 3224, 4032, 27842, 23758, 25724, 11622, 38207, 16247, 3794, 32277, 1829, 8978, 3224, 13672, 1829, 39896, 11331, 38436, 28671, 2423, 39184, 2533, 17437, 299, 5367, 37495, 22653, 29538, 45164, 6225, 42213, 2655, 5296, 11296, 2533, 17437, 299, 5367, 2423, 39184, 6056, 16070, 39184, 2033, 28242, 16095, 9154, 13412, 9566, 3555, 3224, 39896, 6225, 3555, 9640, 3660, 18871, 389, 4724, 1211, 3794, 30767, 16373, 3215, 13931, 12, 39894, 3615, 9566, 1829, 8315, 389, 17, 46, 46599, 1863, 16606, 15844, 29910, 23275, 2423, 8258, 43242, 17412, 31439, 389, 4724, 1211, 3794], "avg_logprob": -0.21372767670878343, "compression_ratio": 1.6722689075630253, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 409.96, "end": 410.28, "word": "الـ", "probability": 0.52587890625}, {"start": 410.28, "end": 410.44, "word": " OH", 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كتبت", "probability": 0.9959716796875}, {"start": 497.7, "end": 498.04, "word": " A", "probability": 0.8017578125}, {"start": 498.04, "end": 498.66, "word": " plus", "probability": 0.91748046875}, {"start": 498.66, "end": 499.74, "word": " زائد", "probability": 0.8351236979166666}, {"start": 499.74, "end": 500.2, "word": " مثلا", "probability": 0.984130859375}, {"start": 500.2, "end": 500.72, "word": " X", "probability": 0.9599609375}, {"start": 500.72, "end": 501.58, "word": " minus", "probability": 0.98828125}], "temperature": 1.0}, {"id": 23, "seek": 52529, "start": 503.87, "end": 525.29, "text": "هذا بيعطي إلكترونات إذا هذا بيحصل هذا بيكتسب إلكترونات إذا هذا أسد واضح و لذلك إذا بتذكروا لما أخدنا على سبيل المثال في chapter ال aromatic compounds مركب زي ال FECL3 قلنا إن ال FECL3 كام إلكترون كان حوله", "tokens": [3224, 15730, 4724, 1829, 3615, 9566, 1829, 11933, 23275, 2655, 2288, 11536, 9307, 11933, 15730, 23758, 4724, 1829, 5016, 36520, 23758, 4724, 1829, 4117, 2655, 35457, 11933, 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519.17, "word": " ال", "probability": 0.68310546875}, {"start": 519.17, "end": 520.53, "word": " FECL3", "probability": 0.81591796875}, {"start": 520.53, "end": 521.81, "word": " قلنا", "probability": 0.6890462239583334}, {"start": 521.81, "end": 521.97, "word": " إن", "probability": 0.32080078125}, {"start": 521.97, "end": 522.11, "word": " ال", "probability": 0.6357421875}, {"start": 522.11, "end": 523.65, "word": " FECL3", "probability": 0.9674072265625}, {"start": 523.65, "end": 523.95, "word": " كام", "probability": 0.67333984375}, {"start": 523.95, "end": 524.53, "word": " إلكترون", "probability": 0.99052734375}, {"start": 524.53, "end": 524.79, "word": " كان", "probability": 0.943359375}, {"start": 524.79, "end": 525.29, "word": " حوله", "probability": 0.966796875}], "temperature": 1.0}, {"id": 24, "seek": 55102, "start": 527.04, "end": 551.02, "text": "6 electron sextant الوضع الطبيعي كم يكون 8 و بناء على ذلك اعتبرنا Lewis acid فلما نيجي نقول له ال aromatic compounds كيف كانوا 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"probability": 0.9384765625}, {"start": 550.22, "end": 550.54, "word": " كان", "probability": 0.9814453125}, {"start": 550.54, "end": 551.02, "word": " يعطي", "probability": 0.9801432291666666}], "temperature": 1.0}, {"id": 25, "seek": 56803, "start": 551.81, "end": 568.03, "text": "سيال مع إلكتروناتها كأنه هذه ال base هو بيكتسب السيال مع إلكتروناتها بيصير تمان إلكترونات حوله بدل ستة فهذا acid وهذا الجزء كأنه تعامل ك base وعشان تقولنا أن ال aromatic reactions", "tokens": [3794, 1829, 6027, 20449, 11933, 23275, 2655, 2288, 11536, 9307, 11296, 9122, 33456, 3224, 29538, 2423, 3096, 31439, 4724, 1829, 4117, 2655, 35457, 21136, 1829, 6027, 20449, 11933, 23275, 2655, 2288, 11536, 9307, 11296, 4724, 1829, 9381, 13546, 46811, 7649, 11933, 23275, 2655, 2288, 11536, 9307, 11331, 12610, 3224, 47525, 1211, 8608, 2655, 3660, 6156, 3224, 15730, 8258, 37037, 15730, 25724, 11622, 38207, 9122, 33456, 3224, 37279, 10943, 1211, 9122, 3096, 4032, 3615, 8592, 7649, 6055, 39648, 8315, 14739, 2423, 45831, 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"word": " كأنه", "probability": 0.8387044270833334}, {"start": 563.61, "end": 564.29, "word": " تعامل", "probability": 0.8233235677083334}, {"start": 564.29, "end": 564.81, "word": " ك", "probability": 0.990234375}, {"start": 564.81, "end": 565.27, "word": " base", "probability": 0.76904296875}, {"start": 565.27, "end": 566.25, "word": " وعشان", "probability": 0.9066162109375}, {"start": 566.25, "end": 566.63, "word": " تقولنا", "probability": 0.7349853515625}, {"start": 566.63, "end": 566.77, "word": " أن", "probability": 0.466552734375}, {"start": 566.77, "end": 566.87, "word": " ال", "probability": 0.89111328125}, {"start": 566.87, "end": 567.21, "word": " aromatic", "probability": 0.86376953125}, {"start": 567.21, "end": 568.03, "word": " reactions", "probability": 0.8271484375}], "temperature": 1.0}, {"id": 26, "seek": 58589, "start": 568.23, "end": 585.89, "text": "بتم في وجود ال FECL3 أو الألمنيوم الكلوريد الآن الإنسان مابدوش يكتب FECL3 أو الألمنيوم الكلوريد بيقول ببساطة the chlorination of aromatic compounds occurs by using Cl2 with a Lewis acid", "tokens": [3555, 39237, 8978, 49610, 23328, 2423, 479, 8140, 43, 18, 34051, 16247, 19528, 22653, 20498, 33251, 1211, 13063, 25708, 6024, 48506, 33688, 1863, 3794, 7649, 3714, 16758, 3215, 2407, 8592, 7251, 4117, 2655, 3555, 479, 8140, 43, 18, 34051, 16247, 19528, 22653, 20498, 33251, 1211, 13063, 25708, 4724, 1829, 39648, 4724, 3555, 3794, 41193, 3660, 264, 18178, 2486, 295, 45831, 21810, 11843, 538, 1228, 2033, 17, 365, 257, 17412, 8258], "avg_logprob": -0.2845510462640037, "compression_ratio": 1.4615384615384615, "no_speech_prob": 0.0, "words": [{"start": 568.23, "end": 568.67, "word": "بتم", "probability": 0.5018310546875}, {"start": 568.67, "end": 568.85, "word": " في", "probability": 0.90283203125}, {"start": 568.85, "end": 569.27, "word": " وجود", "probability": 0.986083984375}, {"start": 569.27, "end": 569.41, "word": " ال", "probability": 0.481201171875}, {"start": 569.41, "end": 570.67, "word": " FECL3", "probability": 0.60321044921875}, {"start": 570.67, "end": 571.27, "word": " أو", "probability": 0.6455078125}, {"start": 571.27, "end": 571.99, "word": " الألمنيوم", "probability": 0.656768798828125}, {"start": 571.99, "end": 572.63, "word": " الكلوريد", "probability": 0.7586669921875}, {"start": 572.63, "end": 573.23, "word": " الآن", "probability": 0.5635986328125}, {"start": 573.23, "end": 573.69, "word": " الإنسان", "probability": 0.85980224609375}, {"start": 573.69, "end": 574.05, "word": " مابدوش", "probability": 0.7447265625}, {"start": 574.05, "end": 574.29, "word": " يكتب", "probability": 0.9705810546875}, {"start": 574.29, "end": 575.13, "word": " FECL3", "probability": 0.907958984375}, {"start": 575.13, "end": 575.27, "word": " أو", "probability": 0.69970703125}, {"start": 575.27, "end": 575.69, "word": " الألمنيوم", "probability": 0.8280029296875}, {"start": 575.69, "end": 576.25, "word": " الكلوريد", "probability": 0.9315185546875}, {"start": 576.25, "end": 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"probability": 0.64697265625}, {"start": 834.19, "end": 834.79, "word": " acidity", "probability": 0.53466796875}, {"start": 834.79, "end": 835.29, "word": " constant", "probability": 0.95849609375}, {"start": 835.29, "end": 835.59, "word": " is", "probability": 0.93310546875}, {"start": 835.59, "end": 835.91, "word": " another", "probability": 0.9130859375}, {"start": 835.91, "end": 836.27, "word": " thing", "probability": 0.93408203125}, {"start": 836.27, "end": 836.65, "word": " ال", "probability": 0.54345703125}, {"start": 836.65, "end": 836.91, "word": " K", "probability": 0.301513671875}, {"start": 836.91, "end": 837.15, "word": " a", "probability": 0.267822265625}, {"start": 837.15, "end": 837.69, "word": " هذه", "probability": 0.50048828125}, {"start": 837.69, "end": 838.23, "word": " هي", "probability": 0.88134765625}, {"start": 838.23, "end": 838.65, "word": " عبارة", "probability": 0.9869384765625}, {"start": 838.65, "end": 838.89, "word": " عن", "probability": 0.9951171875}, {"start": 838.89, "end": 839.27, "word": " ثابت", "probability": 0.9939778645833334}, {"start": 839.27, "end": 839.83, "word": " الاتزان", "probability": 0.853515625}, {"start": 839.83, "end": 840.25, "word": " مضروب", "probability": 0.861328125}, {"start": 840.25, "end": 840.37, "word": " في", "probability": 0.9208984375}, {"start": 840.37, "end": 840.99, "word": " تركيز", "probability": 0.9022216796875}, {"start": 840.99, "end": 841.63, "word": " ال", "probability": 0.92578125}, {"start": 841.63, "end": 842.41, "word": " H2O", "probability": 0.8837890625}, {"start": 842.41, "end": 842.73, "word": " اللي", "probability": 0.8466796875}, {"start": 842.73, "end": 843.15, "word": " ثابت", "probability": 0.99560546875}, {"start": 843.15, "end": 843.69, "word": " الان", "probability": 0.6734619140625}, {"start": 843.69, "end": 843.87, "word": " لو", "probability": 0.98193359375}, {"start": 843.87, "end": 844.25, "word": " اتيت", "probability": 0.6985677083333334}, {"start": 844.25, "end": 844.45, "word": " على", "probability": 0.73095703125}, {"start": 844.45, "end": 844.65, "word": " ال", "probability": 0.7646484375}, {"start": 844.65, "end": 844.83, "word": " K", "probability": 0.9541015625}, {"start": 844.83, "end": 845.01, "word": " a", "probability": 0.88134765625}, {"start": 845.01, "end": 845.73, "word": " هيصير", "probability": 0.736083984375}, {"start": 845.73, "end": 846.91, "word": " ربما", "probability": 0.9676106770833334}, {"start": 846.91, "end": 847.43, "word": " التعبير", "probability": 0.9625244140625}, {"start": 847.43, "end": 847.57, "word": " اللي", "probability": 0.9189453125}, {"start": 847.57, "end": 848.05, "word": " حضرتكم", "probability": 0.654052734375}, {"start": 848.05, "end": 848.83, "word": " بتعرفوه", "probability": 0.8908203125}, {"start": 848.83, "end": 849.65, "word": " H3O", "probability": 0.8873697916666666}, {"start": 849.65, "end": 850.11, "word": " plus", "probability": 0.2203369140625}, {"start": 850.11, "end": 851.33, "word": " في", "probability": 0.78369140625}, {"start": 851.33, "end": 851.57, "word": " A", "probability": 0.5146484375}, {"start": 851.57, "end": 852.25, "word": " minus", "probability": 0.87158203125}, {"start": 852.25, "end": 852.85, "word": " على", "probability": 0.763671875}], "temperature": 1.0}, {"id": 38, "seek": 87005, "start": 854.55, "end": 870.05, "text": "هذا تعبير إيش ال K A اللي بنسميه احنا acidity constant يعني ثابت الحامض الآن ال acidity constant", "tokens": [3224, 15730, 37279, 3555, 13546, 11933, 1829, 8592, 2423, 591, 316, 13672, 1829, 44945, 38251, 1829, 3224, 1975, 5016, 8315, 8258, 507, 5754, 37495, 22653, 38637, 16758, 2655, 21542, 10943, 11242, 6024, 48506, 2423, 8258, 507, 5754], "avg_logprob": -0.24568257441646174, "compression_ratio": 1.2654867256637168, "no_speech_prob": 0.0, "words": [{"start": 854.55, "end": 855.77, "word": "هذا", "probability": 0.6431884765625}, {"start": 855.77, "end": 856.85, "word": " تعبير", "probability": 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0.9111328125}, {"start": 865.73, "end": 867.65, "word": " الآن", "probability": 0.65478515625}, {"start": 867.65, "end": 868.37, "word": " ال", "probability": 0.8330078125}, {"start": 868.37, "end": 869.19, "word": " acidity", "probability": 0.991943359375}, {"start": 869.19, "end": 870.05, "word": " constant", "probability": 0.96826171875}], "temperature": 1.0}, {"id": 39, "seek": 89206, "start": 871.96, "end": 892.06, "text": "و كل مكان أعلى كل مكان الحامض بتأيين أكثر والحامض اللي بتأيين أكثر بالتعريف والحامض الاش الأقوى بناء على ذلك لو أنا بدي أعمل مقارنة لحامضين مين اللي بدي يكون أقوى اللي له K A أعلى", "tokens": [2407, 28242, 3714, 41361, 5551, 3615, 23942, 28242, 3714, 41361, 21542, 10943, 11242, 39894, 10721, 1829, 9957, 5551, 4117, 49115, 16070, 5016, 10943, 11242, 13672, 1829, 39894, 10721, 1829, 9957, 5551, 4117, 49115, 20666, 2655, 3615, 16572, 5172, 16070, 5016, 10943, 11242, 2423, 33599, 16247, 4587, 2407, 7578, 44945, 16606, 15844, 29910, 23275, 45164, 41850, 4724, 16254, 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"word": " أكثر", "probability": 0.9069010416666666}, {"start": 876.88, "end": 877.42, "word": " والحامض", "probability": 0.715087890625}, {"start": 877.42, "end": 877.54, "word": " اللي", "probability": 0.85400390625}, {"start": 877.54, "end": 878.02, "word": " بتأيين", "probability": 0.9581298828125}, {"start": 878.02, "end": 878.42, "word": " أكثر", "probability": 0.9015299479166666}, {"start": 878.42, "end": 879.06, "word": " بالتعريف", "probability": 0.9197265625}, {"start": 879.06, "end": 879.64, "word": " والحامض", "probability": 0.819091796875}, {"start": 879.64, "end": 880.14, "word": " الاش", "probability": 0.552001953125}, {"start": 880.14, "end": 881.08, "word": " الأقوى", "probability": 0.883056640625}, {"start": 881.08, "end": 881.74, "word": " بناء", "probability": 0.804931640625}, {"start": 881.74, "end": 882.0, "word": " على", "probability": 0.828125}, {"start": 882.0, "end": 882.5, "word": " ذلك", "probability": 0.9931640625}, {"start": 882.5, "end": 882.9, "word": " لو", "probability": 0.8818359375}, {"start": 882.9, "end": 883.12, "word": " أنا", "probability": 0.6337890625}, {"start": 883.12, "end": 883.32, "word": " بدي", "probability": 0.684814453125}, {"start": 883.32, "end": 883.68, "word": " أعمل", "probability": 0.9495442708333334}, {"start": 883.68, "end": 884.48, "word": " مقارنة", "probability": 0.99140625}, {"start": 884.48, "end": 885.56, "word": " لحامضين", "probability": 0.93974609375}, {"start": 885.56, "end": 886.64, "word": " مين", "probability": 0.91162109375}, {"start": 886.64, "end": 886.78, "word": " اللي", "probability": 0.96826171875}, {"start": 886.78, "end": 887.0, "word": " بدي", "probability": 0.799560546875}, {"start": 887.0, "end": 887.34, "word": " يكون", "probability": 0.94921875}, {"start": 887.34, "end": 888.16, "word": " أقوى", "probability": 0.9716796875}, {"start": 888.16, "end": 889.54, "word": " اللي", "probability": 0.818359375}, {"start": 889.54, "end": 889.94, "word": " له", "probability": 0.46337890625}, 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هذا الكلام لو إجينا أعطيناكم حامض HA", "tokens": [28820, 19446, 2423, 39184, 10988, 39894, 30544, 5551, 3615, 23942, 8978, 25062, 32640, 3660, 28242, 19446, 21542, 10943, 11242, 4724, 1829, 30544, 5551, 4587, 2407, 7578, 6156, 10721, 8315, 45164, 5551, 3615, 9566, 36081, 24793, 50113, 15040, 11331, 10943, 11242, 9957, 39896, 10988, 46740, 15730, 4032, 42, 64, 46740, 15730, 39894, 28543, 2288, 14407, 15844, 23032, 12610, 6055, 39648, 12610, 1829, 3714, 9957, 21542, 10943, 11242, 16247, 4587, 2407, 7578, 8978, 16095, 13672, 1829, 11933, 43761, 2423, 10988, 5551, 3615, 23942, 16490, 1211, 9957, 995, 8717, 7435, 25513, 8717, 25957, 1211, 23758, 2423, 28820, 10943, 16490, 1211, 9957, 995, 8717, 7435, 25513, 8717, 25957, 1211, 23758, 2423, 28820, 10943, 45164, 11933, 7435, 1829, 8315, 5551, 3615, 9566, 1829, 8315, 24793, 11331, 10943, 11242, 11979], "avg_logprob": -0.15737500143051147, "compression_ratio": 2.1658536585365855, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 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"text": "الان هذه تقريبا مقدمة خلنا نقول تذكير بشكل عام في مفاهيم الأحماض الان لما نيجي نتكلم عن ال alcohols هل يا ترى الكحول ممكن يكون حامض ولا لأ؟", "tokens": [6027, 7649, 29538, 6055, 4587, 16572, 3555, 995, 3714, 28543, 46007, 16490, 1211, 8315, 8717, 39648, 6055, 8848, 4117, 13546, 4724, 8592, 28820, 6225, 10943, 8978, 3714, 5172, 40294, 32640, 16247, 35571, 46958, 2423, 7649, 5296, 15042, 8717, 1829, 7435, 1829, 8717, 2655, 4117, 19528, 18871, 2423, 7658, 82, 8032, 1211, 35186, 6055, 2288, 7578, 33251, 5016, 12610, 3714, 43020, 7251, 30544, 11331, 10943, 11242, 49429, 5296, 10721, 22807], "avg_logprob": -0.13783481610672815, "compression_ratio": 1.5093167701863355, "no_speech_prob": 0.0, "words": [{"start": 1244.56, "end": 1245.1, "word": "الان", "probability": 0.8134765625}, {"start": 1245.1, "end": 1245.64, "word": " هذه", "probability": 0.63623046875}, {"start": 1245.64, "end": 1246.44, "word": " تقريبا", "probability": 0.99208984375}, {"start": 1246.44, "end": 1247.88, 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ممكن اعتبرها كأن أبسط كحول هنا قلت H O R وهنا H O H يعني كأن ال R هذه H عشان هي أبسط إيش", "tokens": [40228, 22653, 45164, 5551, 9778, 3215, 2655, 8717, 36178, 29538, 9673, 3615, 18513, 37977, 9673, 10632, 9122, 35571, 11242, 389, 422, 389, 20193, 5016, 19913, 14407, 5296, 15042, 9673, 25720, 9673, 46958, 10632, 12174, 1211, 2655, 23275, 14407, 14739, 9673, 10632, 6156, 1211, 3794, 5172, 25528, 3714, 43020, 1975, 34268, 26890, 11296, 9122, 33456, 5551, 3555, 3794, 9566, 9122, 5016, 12610, 34105, 12174, 1211, 2655, 389, 422, 497, 37037, 8315, 389, 422, 389, 37495, 22653, 9122, 33456, 2423, 497, 29538, 389, 6225, 8592, 7649, 39896, 5551, 3555, 3794, 9566, 11933, 1829, 8592], "avg_logprob": -0.20010080388797227, "compression_ratio": 1.8, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1302.43, "end": 1302.83, "word": "يعني", "probability": 0.9208984375}, {"start": 1302.83, "end": 1302.93, "word": " لو", "probability": 0.6865234375}, {"start": 1302.93, "end": 1303.27, "word": 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"probability": 0.7605794270833334}, {"start": 2249.08, "end": 2249.3, "word": " بس", "probability": 0.9140625}, {"start": 2249.3, "end": 2249.66, "word": " مفرج", "probability": 0.8981119791666666}, {"start": 2249.66, "end": 2249.84, "word": " ال", "probability": 0.7265625}, {"start": 2249.84, "end": 2250.16, "word": " sulfur", "probability": 0.50048828125}, {"start": 2250.16, "end": 2250.36, "word": " و", "probability": 0.71240234375}, {"start": 2250.36, "end": 2250.48, "word": " ال", "probability": 0.88916015625}, {"start": 2250.48, "end": 2250.96, "word": " oxygen", "probability": 0.791015625}, {"start": 2250.96, "end": 2251.44, "word": " طب", "probability": 0.861328125}, {"start": 2251.44, "end": 2251.5, "word": " ما", "probability": 0.88525390625}, {"start": 2251.5, "end": 2251.64, "word": " هي", "probability": 0.86865234375}, {"start": 2251.64, "end": 2251.84, "word": " ال", "probability": 0.8544921875}, {"start": 2251.84, "end": 2252.84, "word": " sulfur؟", "probability": 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"probability": 0.7294921875}, {"start": 2262.55, "end": 2263.29, "word": " فصّال", "probability": 0.63983154296875}, {"start": 2263.29, "end": 2263.45, "word": " لي", "probability": 0.73779296875}, {"start": 2263.45, "end": 2263.73, "word": " ليش", "probability": 0.7978515625}, {"start": 2263.73, "end": 2263.91, "word": " ال", "probability": 0.732421875}, {"start": 2263.91, "end": 2265.19, "word": " RSH", "probability": 0.618896484375}, {"start": 2265.19, "end": 2266.11, "word": " أقوى", "probability": 0.9576416015625}, {"start": 2266.11, "end": 2266.41, "word": " من", "probability": 0.9921875}, {"start": 2266.41, "end": 2266.77, "word": " ال", "probability": 0.791015625}, {"start": 2266.77, "end": 2268.85, "word": " ROH", "probability": 0.3931884765625}, {"start": 2268.85, "end": 2269.25, "word": " و", "probability": 0.66748046875}, {"start": 2269.25, "end": 2269.57, "word": " ليش", "probability": 0.8193359375}, {"start": 2269.57, "end": 2269.79, "word": " ال", "probability": 0.9375}, {"start": 2269.79, "end": 2272.01, "word": " ARSH", "probability": 0.783447265625}, {"start": 2272.01, "end": 2272.57, "word": " أقوى", "probability": 0.9798583984375}, {"start": 2272.57, "end": 2272.81, "word": " من", "probability": 0.99609375}, {"start": 2272.81, "end": 2273.05, "word": " ال", "probability": 0.90869140625}, {"start": 2273.05, "end": 2275.13, "word": " AROH", "probability": 0.8671875}, {"start": 2275.13, "end": 2276.09, "word": " ال", "probability": 0.396728515625}, {"start": 2276.09, "end": 2276.41, "word": " size", "probability": 0.8486328125}, {"start": 2276.41, "end": 2276.59, "word": " اللي", "probability": 0.8544921875}, {"start": 2276.59, "end": 2277.01, "word": " فصّال", "probability": 0.8763427734375}, {"start": 2277.01, "end": 2277.43, "word": " ليها", "probability": 0.790283203125}, {"start": 2277.43, "end": 2278.57, "word": " الحجم", "probability": 0.9298502604166666}], "temperature": 1.0}, {"id": 100, "seek": 229786, "start": 2279.42, "end": 2297.86, "text": "الحجم الكبير أقدر على حمل الشحنة الحجم الكبير أقدر على حمل الشحنة الآن خليني أجي لل resonance و بدي أقارن أنا الاثانول مع حمض الخلق لاحظوا الاثانول إيش صيبته؟", "tokens": [6027, 5016, 7435, 2304, 33251, 3555, 13546, 5551, 28543, 2288, 15844, 11331, 42213, 25124, 5016, 1863, 3660, 21542, 7435, 2304, 33251, 3555, 13546, 5551, 28543, 2288, 15844, 11331, 42213, 25124, 5016, 1863, 3660, 6024, 48506, 16490, 1211, 9957, 1829, 5551, 7435, 1829, 24976, 30944, 4032, 4724, 16254, 5551, 4587, 9640, 1863, 41850, 2423, 5718, 104, 7649, 12610, 20449, 11331, 2304, 11242, 33962, 1211, 4587, 20193, 5016, 19913, 14407, 2423, 5718, 104, 7649, 12610, 11933, 1829, 8592, 20328, 1829, 3555, 47395, 22807], "avg_logprob": -0.19588413998121168, "compression_ratio": 1.8355263157894737, "no_speech_prob": 0.0, "words": [{"start": 2279.42, "end": 2280.0, "word": "الحجم", "probability": 0.974365234375}, {"start": 2280.0, "end": 2280.54, "word": " الكبير", "probability": 0.9860026041666666}, {"start": 2280.54, "end": 2281.02, "word": " أقدر", "probability": 0.8955078125}, {"start": 2281.02, "end": 2281.22, "word": " على", "probability": 0.90283203125}, {"start": 2281.22, "end": 2281.56, "word": " حمل", "probability": 0.866455078125}, {"start": 2281.56, "end": 2283.42, "word": " الشحنة", "probability": 0.9051513671875}, {"start": 2283.42, "end": 2284.2, "word": " الحجم", "probability": 0.75341796875}, {"start": 2284.2, "end": 2284.6, "word": " الكبير", "probability": 0.9820963541666666}, {"start": 2284.6, "end": 2285.02, "word": " أقدر", "probability": 0.9853515625}, {"start": 2285.02, "end": 2285.22, "word": " على", "probability": 0.91259765625}, {"start": 2285.22, "end": 2285.62, "word": " حمل", "probability": 0.9638671875}, {"start": 2285.62, "end": 2287.66, "word": " الشحنة", "probability": 0.984130859375}, {"start": 2287.66, "end": 2288.94, "word": " الآن", "probability": 0.6409912109375}, {"start": 2288.94, "end": 2289.62, "word": " خليني", "probability": 0.8291015625}, {"start": 2289.62, "end": 2290.06, "word": " أجي", "probability": 0.8321940104166666}, {"start": 2290.06, "end": 2290.4, "word": " لل", "probability": 0.89794921875}, {"start": 2290.4, "end": 2291.06, "word": " resonance", "probability": 0.740234375}, {"start": 2291.06, "end": 2292.28, "word": " و", "probability": 0.580078125}, {"start": 2292.28, "end": 2292.5, "word": " بدي", "probability": 0.5706787109375}, {"start": 2292.5, "end": 2293.04, "word": " أقارن", "probability": 0.9600830078125}, {"start": 2293.04, "end": 2293.3, "word": " أنا", "probability": 0.418212890625}, {"start": 2293.3, "end": 2293.96, "word": " الاثانول", "probability": 0.733056640625}, {"start": 2293.96, "end": 2294.22, "word": " مع", "probability": 0.372314453125}, {"start": 2294.22, "end": 2294.5, "word": " حمض", "probability": 0.88330078125}, {"start": 2294.5, "end": 2295.52, "word": " الخلق", "probability": 0.8802083333333334}, {"start": 2295.52, "end": 2296.26, "word": " لاحظوا", "probability": 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"compression_ratio": 1.5067567567567568, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2298.53, "end": 2299.77, "word": "CH3", "probability": 0.695068359375}, {"start": 2299.77, "end": 2301.55, "word": " CH2", "probability": 0.7470703125}, {"start": 2301.55, "end": 2303.17, "word": " OH", "probability": 0.890625}, {"start": 2303.17, "end": 2304.01, "word": " وحمض", "probability": 0.56396484375}, {"start": 2304.01, "end": 2304.51, "word": " الخلب", "probability": 0.7149658203125}, {"start": 2304.51, "end": 2306.49, "word": " CH3", "probability": 0.96240234375}, {"start": 2306.49, "end": 2307.29, "word": " C", "probability": 0.630859375}, {"start": 2307.29, "end": 2307.93, "word": " O", "probability": 0.047149658203125}, {"start": 2307.93, "end": 2309.97, "word": " OH", "probability": 0.51025390625}, {"start": 2309.97, "end": 2310.75, "word": " الآن", "probability": 0.5819091796875}, {"start": 2310.75, "end": 2311.63, "word": " اتفقنا", "probability": 0.93154296875}, {"start": 2311.63, "end": 2311.93, "word": " انه", "probability": 0.705810546875}, {"start": 2311.93, "end": 2312.09, "word": " لما", "probability": 0.929443359375}, {"start": 2312.09, "end": 2312.39, "word": " بدنا", "probability": 0.81591796875}, {"start": 2312.39, "end": 2312.97, "word": " نقارن", "probability": 0.9940185546875}, {"start": 2312.97, "end": 2313.55, "word": " ال", "probability": 0.76513671875}, {"start": 2313.55, "end": 2313.75, "word": " H", "probability": 0.90234375}, {"start": 2313.75, "end": 2314.27, "word": " Plus", "probability": 0.1453857421875}, {"start": 2314.27, "end": 2315.47, "word": " مش", "probability": 0.85205078125}, {"start": 2315.47, "end": 2316.29, "word": " لازماني", "probability": 0.84873046875}, {"start": 2316.29, "end": 2317.13, "word": " بدي", "probability": 0.59637451171875}, {"start": 2317.13, "end": 2317.85, "word": " اشيلها", "probability": 0.86456298828125}, {"start": 2317.85, "end": 2318.13, "word": " و", "probability": 0.73193359375}, 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الشحن السالب على هذا ال oxygen هذا لأ له اتين", "tokens": [6027, 7649, 8032, 2655, 15040, 5016, 19913, 14407, 34105, 2423, 1975, 1829, 11536, 21136, 6027, 3555, 23758, 3714, 29245, 23328, 15844, 2423, 9169, 37893, 12174, 18513, 2288, 7251, 2655, 5016, 31747, 37495, 22653, 23758, 5551, 8592, 3555, 3224, 29739, 22653, 1975, 40448, 20449, 3224, 11331, 42213, 4724, 3794, 11933, 25708, 3224, 16712, 7649, 10632, 3714, 47432, 2407, 27884, 23032, 12610, 41950, 16572, 4587, 39896, 11242, 1211, 3224, 11933, 1829, 8592, 22807, 11331, 10943, 1211, 25124, 5016, 1863, 21136, 6027, 3555, 15844, 23758, 2423, 9169, 23758, 5296, 10721, 46740, 1975, 2655, 9957], "avg_logprob": -0.2131453870755175, "compression_ratio": 1.7692307692307692, "no_speech_prob": 0.0, "words": [{"start": 2326.8699999999994, "end": 2327.6299999999997, "word": "الان", "probability": 0.791015625}, {"start": 2327.6299999999997, "end": 2328.39, "word": " هتلاحظوا", "probability": 0.8361409505208334}, {"start": 2328.39, "end": 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\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/di-xbM-HbNU_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/di-xbM-HbNU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..113e6db8580a7a6a78dd7c4cdb91328115f59e55
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/di-xbM-HbNU_raw.srt
@@ -0,0 +1,2096 @@
+1
+00:00:18,700 --> 00:00:22,900
+بسم الله الرحمن الرحيم، اليوم ان شاء الله هنبتدأ
+
+2
+00:00:22,900 --> 00:00:28,300
+الفصل الأخير في ال course اللي بأمل أن نكون يعني
+
+3
+00:00:28,300 --> 00:00:32,740
+استفدنا منه واستمتعنا فيه على مدى ثلاث أو أربع
+
+4
+00:00:32,740 --> 00:00:38,220
+شهور course الكيمياء الأضوية العامة والكيمياء يعني
+
+5
+00:00:38,220 --> 00:00:43,140
+مقدمة في الكيمياء الحيوية العامةالفصل هذا بعنوان
+
+6
+00:00:43,140 --> 00:00:49,360
+amino acids, peptides and proteins، طبعا هو مش تلت
+
+7
+00:00:49,360 --> 00:00:56,860
+عنوين، لأهي ال amino acids الأحماض الأمينية الوحدة
+
+8
+00:00:56,860 --> 00:01:02,640
+البسيطة إذا اتحد عندي عدد قليل من ال amino acids
+
+9
+00:01:02,640 --> 00:01:07,080
+بيعملوا ال peptides يعني أربعة، خمسة، عشرة، خمس،
+
+10
+00:01:07,080 --> 00:01:12,280
+تعش هدولة بيعملوا ال peptides الآن إذا صاروا بال
+
+11
+00:01:12,280 --> 00:01:17,880
+آلاف وأحيانا بعشرات الآلاف بصير الجزء كبير جدا
+
+12
+00:01:17,880 --> 00:01:23,530
+بنسمي إيش ال proteinفالبروتين الان كبير جدا لو بده
+
+13
+00:01:23,530 --> 00:01:28,690
+يتكسر بالعكس هيتكسر لpeptides و ال peptides لو
+
+14
+00:01:28,690 --> 00:01:34,670
+بدها تتكسر هتتكسر ل amino acids فالوحدة الأساسية
+
+15
+00:01:34,670 --> 00:01:42,480
+هتكون ال aminoو لذلك أمر طبيعي جدا ان نبدأ الفصل
+
+16
+00:01:42,480 --> 00:01:47,900
+هذا ان نتعرف على ال amino acids معنى amino acids
+
+17
+00:01:47,900 --> 00:01:54,220
+أحماض عضوية عادية لكن فيها مجموعة الأمين بشكل عام
+
+18
+00:01:54,220 --> 00:02:01,940
+مجموعة ال NH2 الآن من الناحية النظرية البحثة لو
+
+19
+00:02:01,940 --> 00:02:08,870
+انا بحكي عن حامض عضويوفي مجموعة امين معنا ذلك بقدر
+
+20
+00:02:08,870 --> 00:02:14,250
+اتوقع ان يكون عندى عدد لا نهائى من ال amino acids
+
+21
+00:02:14,250 --> 00:02:20,070
+واضح يعني لو بدى اقول قداش العدد النظري المتوقع من
+
+22
+00:02:20,070 --> 00:02:23,910
+ال amino acids لما انا اجي اقول هاي مجموعة الحامض
+
+23
+00:02:23,910 --> 00:02:29,470
+سيضة بال bond O OH و بعدين احط هنا carbons
+
+24
+00:02:31,380 --> 00:02:36,140
+الان حسب ما يكون في عندى و الله اذا في هنا مجموعة
+
+25
+00:02:36,140 --> 00:02:40,920
+amino ممكن يكون هنا مجموعة amino هنا هنا لاحظوا
+
+26
+00:02:40,920 --> 00:02:44,000
+معنى بتيجي نقطة كتير مهمه ان انا لما بحط amino
+
+27
+00:02:44,000 --> 00:02:50,200
+بكون في عندي كمان R groups واضح فنظريا ال amino
+
+28
+00:02:50,200 --> 00:02:56,730
+acids اكترالان بنجيب نتطلع وين مجموعة الأمين
+
+29
+00:02:56,730 --> 00:03:02,030
+مجموعة ال N H2 والله إذا كانت هذه مجموعة الأمين
+
+30
+00:03:02,030 --> 00:03:06,470
+على أول carbon بعد ال C double bond O احنا اتعلمنا
+
+31
+00:03:06,470 --> 00:03:11,090
+ان هذا ال carbon هي ال alpha carbon لكن بالتأكيد
+
+32
+00:03:11,090 --> 00:03:14,410
+ممكن ماتكونش على أول carbon ممكن تكون على ثاني
+
+33
+00:03:14,410 --> 00:03:20,940
+carbonوأجد عن إيش هنحكي؟ Beta Amino Acids على اللي
+
+34
+00:03:20,940 --> 00:03:26,940
+بعدها Gamma Delta فال Amino Acids ال Amino Acids
+
+35
+00:03:26,940 --> 00:03:33,780
+بهذا المنطق اكتار الآن اللي موجودين في البروتينات
+
+36
+00:03:41,580 --> 00:03:45,360
+اللي موجودين في البروتينات تحديدا هم ال alpha
+
+37
+00:03:45,360 --> 00:03:50,400
+amino acids يعني اللي فيهم مجموعة الأمين على ال
+
+38
+00:03:50,400 --> 00:03:54,000
+carbon alpha و احنا سبق عرفنا ال carbon alpha بال
+
+39
+00:03:54,000 --> 00:03:57,220
+acids و بال aldehydes و بال ketones قلنا هي ال
+
+40
+00:03:57,220 --> 00:04:01,400
+carbon المجاورة لل seed of the bond O لو كنا بنعد
+
+41
+00:04:01,400 --> 00:04:05,280
+بال ayobac بتكون ال alpha carbon هي ال carbon رقم
+
+42
+00:04:05,280 --> 00:04:09,320
+اتنين لأن احنا بنعد في ال ayobac من ال seed of the
+
+43
+00:04:09,320 --> 00:04:15,360
+bond Oيعني فال amino group موجودة على ال carbon
+
+44
+00:04:15,360 --> 00:04:19,800
+رقم اتنين او على ال carbon الفة هذا الكلام في وين؟
+
+45
+00:04:19,800 --> 00:04:23,940
+في ال amino acids اللي موجودين في البروتينات لكن
+
+46
+00:04:23,940 --> 00:04:30,660
+لو قلنا لطالب في الامتحان الدروق general structure
+
+47
+00:04:30,660 --> 00:04:37,620
+for a beta amino acidهذا جيبنا سؤال مرة اوكي هي
+
+48
+00:04:37,620 --> 00:04:43,080
+انها C double bond O OH بنمشي بهذا الشكل هي alpha
+
+49
+00:04:43,080 --> 00:04:50,820
+هي beta اذا نحط ال amino group على ال carbon beta
+
+50
+00:04:50,820 --> 00:04:54,740
+هذا beta amino acid لو قلنا لغاها مابدوا يحطوا على
+
+51
+00:04:54,740 --> 00:04:59,400
+اللي بعدها واضح لكن اللي موجودين في البروتينات اي
+
+52
+00:04:59,400 --> 00:05:05,440
+نوع ال alpha amino acidsواضح؟ زي ما حكينا احنا ان
+
+53
+00:05:05,440 --> 00:05:10,080
+ال peptides عدت amino acids مع بعض و ال proteins
+
+54
+00:05:10,080 --> 00:05:16,040
+many amino acids مع بعض الان لما نيجي نكسر ال
+
+55
+00:05:16,040 --> 00:05:18,740
+protein زي ما قلنا ممكن يعطينا peptide و ال
+
+56
+00:05:18,740 --> 00:05:22,720
+peptide ممكن يكسره الوحدات الاولية هنصف بال ايش؟
+
+57
+00:05:22,720 --> 00:05:26,700
+بال amino acids الان هذه ال amino acids ايش
+
+58
+00:05:26,700 --> 00:05:30,960
+مواصفاتها؟ المواصفة الاولى ان كلهم الف amino acids
+
+59
+00:05:31,860 --> 00:05:36,960
+الشغل التاني ان ال amino acids اللي بيطلعوا عندنا
+
+60
+00:05:36,960 --> 00:05:41,840
+they are optically active يعني فيهم chiral center
+
+61
+00:05:41,840 --> 00:05:46,140
+ما عدا واحد بيكونوا فيه المجموعتين زي بعض يعني
+
+62
+00:05:46,140 --> 00:05:50,480
+مافيش فيه أربع مجموعات مختلفة هذا الواحد اللي
+
+63
+00:05:50,480 --> 00:05:54,940
+هنتعرف عليه هو ال glycine فباقي ال amino acids
+
+64
+00:05:54,940 --> 00:05:59,880
+كلهم they areoptically active they contain chiral
+
+65
+00:05:59,880 --> 00:06:05,380
+centers فيهم chiral centers الآن بيجينا شغلة طالما
+
+66
+00:06:05,380 --> 00:06:09,380
+بدنا نقول chiral center متذكرين لما اتكلمنا عن ال
+
+67
+00:06:09,380 --> 00:06:13,620
+sugars واستبدلنا المصطلح يعني في ال biochemistry
+
+68
+00:06:13,620 --> 00:06:19,940
+ال R و ال S ب D و L فلما اتكلمنا عن ال sugars احنا
+
+69
+00:06:19,940 --> 00:06:25,630
+اتفقنا ان نحط اعلى مجموعة للأعلى اللي هي مجموعةالـ
+
+70
+00:06:25,630 --> 00:06:29,650
+aldehyde بعدين ال sugars بيميزها على الكربون اللى
+
+71
+00:06:29,650 --> 00:06:33,630
+باقى ده H و OH و بعدين بنحط rest of the molecule
+
+72
+00:06:33,630 --> 00:06:40,090
+الآن إذا حطينا ال OH على اليمين كنا نقول في عندنا
+
+73
+00:06:40,090 --> 00:06:45,150
+D و إذا حطينا على الشمال كنا نقول في عندنا L الآن
+
+74
+00:06:45,150 --> 00:06:49,450
+بنفس المنطق بنعمل ال amino acids لكن شو المجموعة
+
+75
+00:06:49,450 --> 00:06:55,600
+اللى بنحطها لأعلى؟بدل ال الديهايد مجموعة الحامض
+
+76
+00:06:55,600 --> 00:06:59,860
+يعني ال amino acids في حامض برسم المجموعة الحامض
+
+77
+00:06:59,860 --> 00:07:04,420
+هذه لأعلى الآن بعد مجموعة الحامض ال carbon Alpha
+
+78
+00:07:04,420 --> 00:07:11,080
+متصلة ب H و متصلة ب NH2 و متصلة ب R group تاني
+
+79
+00:07:11,080 --> 00:07:14,960
+يعني هي بتميز و بتخلي عدد ال amino acids infinity
+
+80
+00:07:14,960 --> 00:07:19,780
+ليش أنا بقول العدد infinity يعني هذا الجزء CO2 H
+
+81
+00:07:19,780 --> 00:07:25,700
+ثابتالـ H ثابتة، الآن الـ H2 ثابتة، الآن الـ Amino
+
+82
+00:07:25,700 --> 00:07:30,600
+acid عن التاني بتغيره بإيش؟ بالـ R طالما في عندي
+
+83
+00:07:30,600 --> 00:07:36,110
+متغيّد، الـ R ممكن تكون عدد لا نهائيواضح ال R ممكن
+
+84
+00:07:36,110 --> 00:07:40,210
+تكون عدد لا نهاية الان احنا بنيجي بنرسم بهذا الشكل
+
+85
+00:07:40,210 --> 00:07:44,470
+عشان الكل يفهم على بعضه اذا حطينا ال N H2 على
+
+86
+00:07:44,470 --> 00:07:49,230
+اليمين بنقول هذا D Amino Acid اذا حطينا ال N H2
+
+87
+00:07:49,230 --> 00:07:54,890
+على اليسار بنقول هذا ايش ال Amino Acids الان ال
+
+88
+00:07:54,890 --> 00:07:59,770
+Amino Acids اللي بيطلعوا من ال proteins كلهم L مش
+
+89
+00:07:59,770 --> 00:08:07,980
+D هذا خلق اللههك ربنا خلقهم يعني لاحظوا أنه لما
+
+90
+00:08:07,980 --> 00:08:11,020
+بنيجي الحل للبروتين بنلاحظ أنه كل ال amino acids
+
+91
+00:08:11,020 --> 00:08:14,600
+اللي طلع عندنا Alpha amino acids وكل ال amino
+
+92
+00:08:14,600 --> 00:08:20,080
+acids اللي طلع عندنا ال amino acids واضح؟ الآن
+
+93
+00:08:20,080 --> 00:08:28,500
+بنيجي لنقطة تانية أنه طالما أن هذا ال R متغير
+
+94
+00:08:29,120 --> 00:08:32,920
+ممكن تاخد أي إشي أتش مثل إثالبروبيل إيزوبروبيل و
+
+95
+00:08:32,920 --> 00:08:37,160
+كبرو زي ما بدكم معناه ذلك من الناحية النظرية كده
+
+96
+00:08:37,160 --> 00:08:44,680
+اندي أمينو أسيد حتى ألفةعدد لانهائي لكن بالواقع
+
+97
+00:08:44,680 --> 00:08:48,680
+التجريبي لما بيعملوا hydrolysis ل ال proteins
+
+98
+00:08:48,680 --> 00:08:53,380
+وبيفصلوا ال amino acids اللي نشأت من تميق ال
+
+99
+00:08:53,380 --> 00:08:57,200
+protein و تكسره لوحدته الأولية لاحظوا ان في عندنا
+
+100
+00:08:57,200 --> 00:09:02,620
+عشرين amino acid هذا الكلام بسهل الشغل علينا يعني
+
+101
+00:09:02,620 --> 00:09:06,980
+تخيل لو كانوا الف و كل واحد بده تشخيص مشكلة لكن
+
+102
+00:09:08,010 --> 00:09:13,070
+بشكل عام كل بروتينات ملفة حوالين ال 20 amino acids
+
+103
+00:09:13,070 --> 00:09:20,010
+هدولة اللي بشكل عام موجودين في البروتينات الان من
+
+104
+00:09:20,010 --> 00:09:24,450
+هدولة ال amino acids العشرينعلى خلاف بسيط من
+
+105
+00:09:24,450 --> 00:09:29,330
+العلماء مش مشكلة خلّيني أتزم بالكلام في 12 amino
+
+106
+00:09:29,330 --> 00:09:33,530
+acid ممكن يتحضروا في الجسم يعني الإنسان ممكن
+
+107
+00:09:33,530 --> 00:09:38,390
+يحضرهم من نقطة السفر وفي 8 amino acids الجسم
+
+108
+00:09:38,390 --> 00:09:43,450
+بيحضرهمش طب هدولة اللي بيحضرهمش الجسم لازم ياخدهم
+
+109
+00:09:43,450 --> 00:09:48,890
+جاهزين من برا من وين هياخدهم؟ من الغذابةأنواع من
+
+110
+00:09:48,890 --> 00:09:52,750
+الغذاء فيها هذه ال amino acids الآن هدولة التمانية
+
+111
+00:09:52,750 --> 00:09:56,790
+amino acids that cannot be synthesized in the body
+
+112
+00:09:56,790 --> 00:10:00,610
+they are called essential amino acids الأحماض
+
+113
+00:10:00,610 --> 00:10:05,350
+الأمينية الأساسية فلما نقول إيش معنى essential
+
+114
+00:10:05,350 --> 00:10:09,730
+amino acids the amino acids that cannot be
+
+115
+00:10:09,730 --> 00:10:13,830
+synthesized in the body and must be obtained from
+
+116
+00:10:13,830 --> 00:10:18,390
+the dietin the form of protein لازم ناخدها من
+
+117
+00:10:18,390 --> 00:10:22,290
+الغذاء على شكل البروتينات، الغذاء الحيواني اللي
+
+118
+00:10:22,290 --> 00:10:25,850
+بنتغدأه، والغذاء النباتي، بروتينات حيوانية أو
+
+119
+00:10:25,850 --> 00:10:32,460
+نباتيةهدول ال amino acids العشرين بدنا نتعرف عليهم
+
+120
+00:10:32,460 --> 00:10:37,440
+جيدا، طبعا كل واحد له اسم، و دائما الناس بيحبوا
+
+121
+00:10:37,440 --> 00:10:41,920
+إيش؟ يختصروا الأسماء، يعني هيمروا علينا glycine,
+
+122
+00:10:41,980 --> 00:10:46,880
+alanine, cysteine, tryptophan, saline, valineاكتار
+
+123
+00:10:46,880 --> 00:10:52,960
+واضح؟ الان فى لهم نوعين من الاختصار فى اختصار لهم
+
+124
+00:10:52,960 --> 00:10:58,240
+بتلت حروف وفى اختصار لهم بحرف واحد بنسميه three
+
+125
+00:10:58,240 --> 00:11:03,100
+letter abbreviation اختصار الاسم لتلت حروف وفى
+
+126
+00:11:03,100 --> 00:11:08,140
+اننا نختصره لحرف واحد one letter abbreviation بشكل
+
+127
+00:11:08,140 --> 00:11:13,830
+عام اذا انا كنتربما المحاضرة السابقة قلتلكوا مشكلة
+
+128
+00:11:13,830 --> 00:11:20,310
+البروتينات ان they are not polymers فلازم اعمللهم
+
+129
+00:11:20,310 --> 00:11:24,650
+ايش؟ sequence ترتيب مين جاي اول واحد التاني التالت
+
+130
+00:11:24,650 --> 00:11:30,070
+الرابع الان اذا انا بدي ارسم peptide صغير يعني ال
+
+131
+00:11:30,070 --> 00:11:34,470
+peptide بيكون عادة تمانية تسعة عشرة خمستاشر amino
+
+132
+00:11:34,470 --> 00:11:39,920
+acid بستعمل three letter abbreviation واضح؟وإذا
+
+133
+00:11:39,920 --> 00:11:43,660
+بدى استعمل البروتين لبروتين بالمئات اللي لم يكن
+
+134
+00:11:43,660 --> 00:11:47,460
+بالألاف بستعمل ال one letter abbreviation فاللي
+
+135
+00:11:47,460 --> 00:11:52,320
+بدى يرسم ببتايد عادة بيستعمل اختصار تلت حروف اللي
+
+136
+00:11:52,320 --> 00:11:59,080
+بدى يرسم البروتين بيستخدم اختصار الحرف الواحد الان
+
+137
+00:11:59,080 --> 00:12:05,320
+لو اجينا بدنا نتعرف على هدول ال amino acids لاحظوا
+
+138
+00:12:05,320 --> 00:12:12,100
+ان احنا اتفقنا ان ال amino acidsفيهم أكتر من شيء
+
+139
+00:12:12,100 --> 00:12:16,080
+مشترك يعني مجموعة ال acid مشتركة ال carbon اللي
+
+140
+00:12:16,080 --> 00:12:20,960
+جنبها مشتركة و غالبا بتحمل H و أنا H2 و يمكن معادة
+
+141
+00:12:20,960 --> 00:12:25,420
+أمينو أسد واحد بيظل عندنا الاختلاف وين؟ في ال R
+
+142
+00:12:25,420 --> 00:12:30,100
+group بيظل عندنا الاختلاف في ال R group الآن بنيجي
+
+143
+00:12:30,100 --> 00:12:33,300
+إذا كانت ال R أبسط شيء عندنا في ال organ ال
+
+144
+00:12:33,300 --> 00:12:38,350
+chemistry اللي هي ال Hتمام؟ ال amino acid بيكون هو
+
+145
+00:12:38,350 --> 00:12:44,670
+ال glycine واضح؟ بياخد اختصارين ال gly او ال j
+
+146
+00:12:44,670 --> 00:12:50,930
+واضح؟ الان لاحظوا معي ال glycine تحديدا لو طلعنا
+
+147
+00:12:50,930 --> 00:12:55,110
+على ال carbon اللي هنا هذا ال carbon
+
+148
+00:12:58,040 --> 00:13:03,760
+في H و H مافيش في عليه four different groups عشان
+
+149
+00:13:03,760 --> 00:13:08,020
+هيك ال glycine does not contain a chiral center so
+
+150
+00:13:08,020 --> 00:13:12,620
+it is not a chiral molecule مش chiral optically
+
+151
+00:13:12,620 --> 00:13:20,990
+inactive مع ده ال glycine كلهم هيكونواthey contain
+
+152
+00:13:20,990 --> 00:13:24,670
+chiral centers and they are optically active الآن
+
+153
+00:13:24,670 --> 00:13:30,450
+نمشي بسرعة لو بدنا نشوف الحامض الأميني لبعده اللي
+
+154
+00:13:30,450 --> 00:13:35,850
+في مجموعة المثل أبسط المجموعات المثل بيصير اسمه
+
+155
+00:13:35,850 --> 00:13:38,590
+الانين لاحظوا ما تقولوش أنين
+
+156
+00:13:41,140 --> 00:13:45,340
+حاجة تانية في الـ aromatic compounds الانين الانين
+
+157
+00:13:45,340 --> 00:13:51,120
+بياخد الاختصار ال أو ا في مجموعة المثل لو كان في
+
+158
+00:13:51,120 --> 00:13:56,480
+مجموعة ال isopropyl بيصير اسمه valine لو كان في
+
+159
+00:13:56,480 --> 00:14:01,820
+مجموعة ال isobutyl بيصير اسمه ليوسين طبعا هذا ايه
+
+160
+00:14:01,820 --> 00:14:06,900
+الاختصار value في ال EU إذا كان في مجموعة ال
+
+161
+00:14:06,900 --> 00:14:13,600
+secondary butyl بيصير اسمه isoleucineواضح؟ لاحظوا
+
+162
+00:14:13,600 --> 00:14:17,100
+كل هذه المجموعات in principle they are simple
+
+163
+00:14:17,100 --> 00:14:20,560
+alkyl groups يعني كلها مرت علينا لما أخدنا ال
+
+164
+00:14:20,560 --> 00:14:25,240
+alkyl groups مثل بروبل مثل ايزو بروبل ايزو بيوتل
+
+165
+00:14:25,240 --> 00:14:29,540
+سكندر بيوتل they are simple alkyl groups هذه
+
+166
+00:14:29,540 --> 00:14:34,970
+المجموعة الأولى من ال amino acidsالان بعد هيك في
+
+167
+00:14:34,970 --> 00:14:40,950
+عندي amino acids ال R تبعتهم بتحمل OH يعني غير ال
+
+168
+00:14:40,950 --> 00:14:48,000
+amino و غير ال acid فيهم alcohol واضح؟فيهم ال
+
+169
+00:14:48,000 --> 00:14:52,160
+amino أكيد موجودة وال acid أكيد موجود هذا لا خلاف
+
+170
+00:14:52,160 --> 00:14:56,600
+فيه لكن يضاف اللي هو منه على ال R group في عنده
+
+171
+00:14:56,600 --> 00:15:04,400
+إيش ال alcohol فمنهم السيرين CH2OH ومنهم الثريونين
+
+172
+00:15:04,400 --> 00:15:13,350
+CHOHCH3 تمام؟بعد هيك بيجيني مجموعات فيهم كبريت
+
+173
+00:15:13,350 --> 00:15:21,230
+sulfur فيهم كبريت منهم الستين CH2SH ومنهم
+
+174
+00:15:21,230 --> 00:15:26,570
+الميثيونين CH2CH2SCH3
+
+175
+00:15:26,570 --> 00:15:34,250
+طبعا هتقولوا هدولةاكتار هل يا تورا مطلوب نحفظ كلها
+
+176
+00:15:34,250 --> 00:15:39,850
+ال amino acids؟ لأ لكن انا بقدر اطلب منكم اي amino
+
+177
+00:15:39,850 --> 00:15:42,530
+acid يعني انا ممكن بعديك اجي اقولكوا ارسموا
+
+178
+00:15:42,530 --> 00:15:47,330
+بيبتايد من خمسة amino acids هنكون اتعلمنا انه في
+
+179
+00:15:47,330 --> 00:15:52,940
+هيكل مشترك و ان الاختلاف فقطفي الـ R group فلو
+
+180
+00:15:52,940 --> 00:15:57,740
+أتيت قلتلكوا مثلا الانين بين جثين الـR بتساوي مثل
+
+181
+00:15:57,740 --> 00:16:02,840
+خلاص ان عرف لإن الاختلاف بينهم بس بإيش بالمثل او
+
+182
+00:16:02,840 --> 00:16:09,660
+مثلا فالين R بتساوي isopropyl الأصل أنه يقدر
+
+183
+00:16:09,660 --> 00:16:14,960
+الإنسان يرسمه لكن على أقل تقدير على أقل تقدير بدنا
+
+184
+00:16:14,960 --> 00:16:21,130
+تكونوا بالتأكيد تعرفوا ال glycineالأول H الالانين
+
+185
+00:16:21,130 --> 00:16:31,050
+اللي هو المثل الستينالـ CH2SH الستين بالذات لأنه
+
+186
+00:16:31,050 --> 00:16:35,390
+بعد هيك هنلاحظ أنه له أهمية كبيرة في شكل البروتين
+
+187
+00:16:35,390 --> 00:16:39,610
+بيعمل داي سالفايد بونتز متذاكرين لما أخدنا الثيولز
+
+188
+00:16:39,610 --> 00:16:43,390
+كانوا يعملوا داي سالفايد بونتز الآن اللي مطلوبين
+
+189
+00:16:43,390 --> 00:16:47,530
+يعني ممكن أقولكوا أرسمولي ألانين سستين أو اعملولي
+
+190
+00:16:47,530 --> 00:16:51,290
+بيبتايد من السستين بدون ما أعطيكوا المجموعة خلاص
+
+191
+00:16:51,290 --> 00:16:54,030
+نكون عارفين أن السستين هو اللي فيه مجموعة
+
+192
+00:16:57,230 --> 00:17:05,070
+الألانين في مثل لجليسين في H ما عدا ذلك لو بدنا أي
+
+193
+00:17:05,070 --> 00:17:09,670
+شيء بس بنعطيكوا بين جثين ال R group بتقدروا تكملوا
+
+194
+00:17:09,670 --> 00:17:17,090
+رسم ال amino acidالآن بجينة حامض اسمه إبرولين هذا
+
+195
+00:17:17,090 --> 00:17:23,750
+شوية صغيرة بختلف عنهم انه مافيش فيه NH2 هو CH NH
+
+196
+00:17:23,750 --> 00:17:28,700
+ومسكر على ال NH2 يعني عامل حلقةيعني كل ال amino
+
+197
+00:17:28,700 --> 00:17:34,760
+acids لما ترسموهم هترسم مجموعة الحامض و بعدين CH و
+
+198
+00:17:34,760 --> 00:17:39,960
+NH2 مع ذا هذا البرولين بتكون ال NH مسكرة على باقى
+
+199
+00:17:39,960 --> 00:17:47,580
+الجزء بالشكل اللى موجود الان هذا البرولين ماخد
+
+200
+00:17:47,580 --> 00:17:51,860
+الاختصار برو او بي بجينة الفينلالانين
+
+201
+00:17:53,330 --> 00:17:58,250
+لاحظوا لو هذه كانت CH3، إيش اسم ال amino acid؟
+
+202
+00:17:58,250 --> 00:18:03,070
+الالانين، شيلنا منها H و حطينا فينل، صار فينل
+
+203
+00:18:03,070 --> 00:18:08,230
+الالانين، واضح؟ يعني برضه ال فينل الالانين، لإنه
+
+204
+00:18:08,230 --> 00:18:13,940
+مختصر من الالانين، بصير مطلوب منهانعرفه، ليش؟ لأن
+
+205
+00:18:13,940 --> 00:18:18,720
+اللي عرف الألانين أن الـR تبعته CH3 لما أنا أقول
+
+206
+00:18:18,720 --> 00:18:23,380
+له فنل ألانين، بشيل H و بحط مجموعة الفنل، صار
+
+207
+00:18:23,380 --> 00:18:27,440
+الفنل ألانين، فاللي عرف الألانين وعارف من الكيميا
+
+208
+00:18:27,440 --> 00:18:35,530
+العامة مجموعة الفنل، بقدر يعرف الفنل ألانينبيجينا
+
+209
+00:18:35,530 --> 00:18:39,310
+الـ Tyrosine في هذه المجموعة CH2 في الـ OH لـ
+
+210
+00:18:39,310 --> 00:18:44,950
+tryptophan في حلقة كبيرة بنسميها Endol مع CH2 مش
+
+211
+00:18:44,950 --> 00:18:53,640
+مطموض نحفظهم طبعا، الآن في مجموعة أحماض فيهممجموعة
+
+212
+00:18:53,640 --> 00:18:58,660
+حمب تانية يعني غير ال acid group و ال amino group
+
+213
+00:18:58,660 --> 00:19:02,400
+اللي هم أساسيات هدولة لاحظوا اللي رسمينهم بالأزرق
+
+214
+00:19:02,400 --> 00:19:06,600
+في كل الرسمات يعني هدولة مشتركين بيجي في ال R
+
+215
+00:19:06,600 --> 00:19:11,460
+group نفسها مجموعة حمب تانية يعني غير هذه CO2H
+
+216
+00:19:11,460 --> 00:19:15,080
+تبعت ال amino acid في هنا كمان مجموعة تانية يعني
+
+217
+00:19:15,080 --> 00:19:19,380
+صار CH2COOH فصار في another
+
+218
+00:19:22,610 --> 00:19:28,750
+هدولة منهم الحمض الأول CH2COH اسمه Aspartic Acid و
+
+219
+00:19:28,750 --> 00:19:34,900
+لو كان مجمعتين CH ورا بعض بيصير Glutamic Acidلو
+
+220
+00:19:34,900 --> 00:19:39,280
+كان مشتق من الأحماض تذكروا لما أخدنا الأحماض قولنا
+
+221
+00:19:39,280 --> 00:19:43,580
+assets and their derivatives و منها الأمد و ما إلى
+
+222
+00:19:43,580 --> 00:19:49,060
+ذلك فلو كان بهذا الشكل ماخد شكل الأمد بيكون اسمه
+
+223
+00:19:49,060 --> 00:19:55,460
+أسبارجين و لو كان أمد بزيادة CH2 يعني بيصير
+
+224
+00:19:55,460 --> 00:20:00,700
+glutamine بيصير glutamine لحظةبتقدروا تشوفوا ال
+
+225
+00:20:00,700 --> 00:20:05,160
+glutamic acid كربونتين CH2 CH2 وبعدين حامض ل
+
+226
+00:20:05,160 --> 00:20:10,080
+glutamine CH2 CH2 وبعدين الأمد تبعه لذلك إيش سموه
+
+227
+00:20:10,080 --> 00:20:16,680
+glutamine إله اختصار الآن في أحماض تانية فيهم غير
+
+228
+00:20:16,680 --> 00:20:23,230
+ال NH2 هذه مجموعة NH2 تانية مش أمد أمينلحظوا الـ
+
+229
+00:20:23,230 --> 00:20:27,650
+NH2 الأمد بتخلف عن الأمين يعني هذه أمد وقلنا عنها
+
+230
+00:20:27,650 --> 00:20:33,050
+unreactive group متذكرين لما أخدنا الأمد قلنا انه
+
+231
+00:20:33,050 --> 00:20:38,230
+unreactive لأ في بيكون فيهم أمين عادية NH2 تانية
+
+232
+00:20:38,230 --> 00:20:44,640
+منهم اللايسين بالشكل اللي موجود منهم الارجينينفيه
+
+233
+00:20:44,640 --> 00:20:49,380
+أكثر من NH ومنهم الهستيدين هي أنا بتلاحظوا برضه
+
+234
+00:20:49,380 --> 00:20:58,080
+فيه NH NH NH أو NH2 هذي كلها amino acids فزي ما
+
+235
+00:20:58,080 --> 00:21:02,680
+بتلاحظوا انه بتصنيف ال amino acids التركيز على
+
+236
+00:21:02,680 --> 00:21:06,220
+إيش؟ على ال R group يعني ال R ممكن تكون simple
+
+237
+00:21:06,220 --> 00:21:10,960
+alkyl groupممكن تحتوي على OH ممكن تحتوي على
+
+238
+00:21:10,960 --> 00:21:16,680
+مجموعات aromatic ممكن تحتوي على مجموعة حمضية تانية
+
+239
+00:21:16,680 --> 00:21:22,480
+ممكن تحتوي على مجموعة قاعدية تانية واضح هذا
+
+240
+00:21:22,480 --> 00:21:31,670
+بالنسبة للتعريف بال amino acids بشكل عامالان لو
+
+241
+00:21:31,670 --> 00:21:36,310
+اجينا بدينا في ال acid-base properties لل amino
+
+242
+00:21:36,310 --> 00:21:45,450
+acids ال amino acids هم خليط من حمض و قاعدة ماشي
+
+243
+00:21:45,450 --> 00:21:51,850
+ال amino group is a basic group لما درسناها و أبسط
+
+244
+00:21:51,850 --> 00:21:57,700
+basic group منها ال ammoniaتحمل زوج إلكترونات
+
+245
+00:21:57,700 --> 00:22:05,040
+وجاهز إنها تستقبل إيش بروتون والأحماض acids الآن
+
+246
+00:22:05,040 --> 00:22:12,340
+لو أنا بشكل منفصل إجيت قلتلكم حمض زائد قاعدة يعني
+
+247
+00:22:12,340 --> 00:22:20,860
+HCL زائد أمونيا أو acetic acid زائد أمونياماشي
+
+248
+00:22:20,860 --> 00:22:26,360
+الحمض مع القاعدة بتفاعل وش بيعطوني ملح و ماء ممتاز
+
+249
+00:22:26,360 --> 00:22:32,060
+جدا الان في ال amino acids الحمض و القاعدة نوجدوا
+
+250
+00:22:32,060 --> 00:22:39,960
+في جزء واحد واضح ال amino group basic و ال COOH
+
+251
+00:22:39,960 --> 00:22:48,510
+acidic ال amino group بتحب تكتسببروتون هاي معناه
+
+252
+00:22:48,510 --> 00:22:54,950
+base و COH بتفقد بروتون طب هدول اتنين انحطوا في
+
+253
+00:22:54,950 --> 00:23:02,350
+جزء واحد اذا بالوضع الطبيعي تلقائيا بيعملوا تفاعل
+
+254
+00:23:02,350 --> 00:23:06,870
+داخلي طالما انه انوجد ال acidic group و ال basic
+
+255
+00:23:06,870 --> 00:23:11,110
+group بنفس الجزء بيعملوا التفاعل بينهم و بين بعض
+
+256
+00:23:11,110 --> 00:23:17,010
+المجموعة الحامضية بتفقد ال H و مين بيكتسبهالقاعدة
+
+257
+00:23:17,010 --> 00:23:24,310
+و لذلك بالوضع الطبيعي هذا الحامض بدل ما يكون C
+
+258
+00:23:24,310 --> 00:23:30,930
+double bond O OH بيفقد ال H بيصير CO2 minus يعني C
+
+259
+00:23:30,930 --> 00:23:35,870
+double bond O O minus لأن ال H اللي فقدها هنا مين
+
+260
+00:23:35,870 --> 00:23:42,730
+بده يتسبها القاعدة بدل ما هي NH2 بتصير NH3 plus
+
+261
+00:23:43,440 --> 00:23:49,180
+واضح؟ وبناء على ذلك في الوضع الطبيعي المتعدل ال
+
+262
+00:23:49,180 --> 00:23:56,460
+amino acids ما برسموهش بهذا الشكل يعني RCHC
+
+263
+00:23:56,460 --> 00:24:03,800
+double bond O OH هنا ال N H2بنرسمه مش زيك، بنقول
+
+264
+00:24:03,800 --> 00:24:08,220
+هذا حامض بده يفقد، هذه قاعدة بده تكتسب، وقاعدين
+
+265
+00:24:08,220 --> 00:24:11,920
+جان بعض، شو اللي بيمنعهم يفقدوا ويكتسبوا؟ بناء على
+
+266
+00:24:11,920 --> 00:24:17,380
+ذلك، بيتم إنه هذه بتفقد منها، وبتيجي وين؟ على هذا
+
+267
+00:24:17,380 --> 00:24:21,560
+الوضع، ففي ال neutral form حقيقة ما بنوجدش ال
+
+268
+00:24:21,560 --> 00:24:25,720
+amino acids بهذا الشكل، لأ بنوجد بهذا الشكل، فقد
+
+269
+00:24:25,720 --> 00:24:31,940
+لبروتون منها، واكتسبته إيش؟الـ Base واضح؟ و الآن
+
+270
+00:24:31,940 --> 00:24:37,460
+هذا الشكل بنقول عنه احنا Dipolar Ionic Form يعني
+
+271
+00:24:37,460 --> 00:24:43,820
+شكل فيه قطبين و بياخد اسم تاني جاي من الألماني
+
+272
+00:24:43,820 --> 00:24:47,900
+Zwitter Ionic Zwitter اش يعني Zwitter؟
+
+273
+00:24:51,140 --> 00:24:57,060
+سفيتر ionic form هذا المصطلح بيمر معاكم كتير سفيتر
+
+274
+00:24:57,060 --> 00:25:04,310
+من svay svay بالالماني معناها إيش؟اتنين, zwei يعني
+
+275
+00:25:04,310 --> 00:25:08,630
+اتنين يعني لما احنا بنعد بالعرب ايش بنقول؟ واحد,
+
+276
+00:25:08,690 --> 00:25:12,970
+اتنين, تلاتة, اربعة و بالانجليزي one, two, three,
+
+277
+00:25:13,170 --> 00:25:17,870
+four بالالماني eins, zwei, drei, vier, fünf,
+
+278
+00:25:18,030 --> 00:25:22,690
+sechs, sieben, acht, neun, zehn ف zwei يعني اتنين
+
+279
+00:25:22,690 --> 00:25:29,300
+فمنها ايجاZwitter Ionic لحظة دي بتنقرق Z و هذه ال
+
+280
+00:25:29,300 --> 00:25:37,440
+W V مش Zwitter لأ Zwitter واضح ال W الألمان شو
+
+281
+00:25:37,440 --> 00:25:44,760
+بيقرؤوها V و ال V إيش بيقرؤوها F عشان هيك اللي
+
+282
+00:25:44,760 --> 00:25:47,760
+عندهم السيارة هذه ال Volkswagen
+
+283
+00:25:50,020 --> 00:25:53,000
+إذا بدهم يقرؤوها بلغة الإنجليز بدهم يقرؤوا
+
+284
+00:25:53,000 --> 00:25:59,240
+Volkswagen بس هي باللغة الألمانية Volkswagen ال V
+
+285
+00:25:59,240 --> 00:26:06,880
+تقرأ F و ال W V Volkswagen Volkswagen يعني سيارة و
+
+286
+00:26:06,880 --> 00:26:10,240
+Volkswagen شعب
+
+287
+00:26:10,240 --> 00:26:15,080
+يعني تاكس الشعب سيارة الشعب سيارة البسيطة عارفينهم
+
+288
+00:26:15,080 --> 00:26:19,870
+ال Volkswagen اللي منهم الباصات و ال ..هذه
+
+289
+00:26:19,870 --> 00:26:23,650
+السيارات الكتيرة Volkswagen هذي svitar ionic
+
+290
+00:26:23,650 --> 00:26:30,430
+structure فلو سألناكم ان ال amino acids are better
+
+291
+00:26:30,430 --> 00:26:35,710
+represented by a dipolar ion structure معناه
+
+292
+00:26:35,710 --> 00:26:39,970
+dipolar ion structure svitar ionic structure عرفنا
+
+293
+00:26:39,970 --> 00:26:43,610
+ايش معناه هذا المصطلح؟ بتكرر كتير معكم بالمناسبة
+
+294
+00:26:44,390 --> 00:26:49,590
+تمام هذا الوضع في الـ neutral form طيب لو اجينا ال
+
+295
+00:26:49,590 --> 00:26:54,550
+amino acid احنا حطينا عليه H plus يعني زدناله H
+
+296
+00:26:54,550 --> 00:27:00,050
+plus من الخارج يعني بدون ما نحطله لا H plus ولا OH
+
+297
+00:27:00,050 --> 00:27:05,510
+minus يعني نسيبه زي ما هو هو حل مشكلته لحاله فقد H
+
+298
+00:27:05,510 --> 00:27:10,170
+من جهة و حطه بجهة تانية واضح؟و هذا الكلام كله في
+
+299
+00:27:10,170 --> 00:27:13,190
+الـ neutral form ماضفناش عليه إش بالبرا طب لو ضفنا
+
+300
+00:27:13,190 --> 00:27:19,450
+له H plus إضافية وين هتروح الـ H plus؟ على ال O
+
+301
+00:27:19,450 --> 00:27:24,490
+minus و لذلك لو ضفنا H plus هيصير بهذا الشكل الآن
+
+302
+00:27:24,490 --> 00:27:29,250
+لاحظوا لما أنا ضفت له H plus هذا متعادل ليش؟ لأنه
+
+303
+00:27:29,250 --> 00:27:34,110
+في موجب و سالب جد بعض الآن متعادل زاد H plus
+
+304
+00:27:34,110 --> 00:27:40,700
+متعادل زاد موجبأيش المحصلة موجب فهي لما فعلنا إجت
+
+305
+00:27:40,700 --> 00:27:45,580
+ال H plus اللي ضفناها هنا H plus عدلة ال O minus
+
+306
+00:27:45,580 --> 00:27:51,640
+دلوا موجب فبال acidic form بيكون ال amino acids
+
+307
+00:27:52,780 --> 00:27:57,480
+موجبة إيش شحنتها موجبة لاحظوا هذه الأسئلة اللي
+
+308
+00:27:57,480 --> 00:28:00,980
+بتكونوا تسألوها انتوا بالصح و الغلط in acidic
+
+309
+00:28:00,980 --> 00:28:09,320
+medium the amino acids are positive واضح amino
+
+310
+00:28:09,320 --> 00:28:14,530
+acid at low pH ال low pH معناهاacidic ايش بيكونوا؟
+
+311
+00:28:14,530 --> 00:28:19,170
+positive الان لو افترضنا هذا ال amino acid بعد ما
+
+312
+00:28:19,170 --> 00:28:23,670
+حطينا عليه حامض بزيادة وصار موجب اجينا بدينا بدنا
+
+313
+00:28:23,670 --> 00:28:28,510
+نسحب منه ال Hات كيف بنسحبهم؟ شو اللي بيسحب ال H
+
+314
+00:28:28,510 --> 00:28:33,870
+plus؟ OH minus فلو فعلت أنا مع OH minus هتيجي تسحب
+
+315
+00:28:33,870 --> 00:28:39,950
+هذه اللي اجت OH minus مع ال H؟ هتعطيني H2O و هيرجع
+
+316
+00:28:39,950 --> 00:28:49,700
+للوضع؟المتعادل طب لو زته كمان OH minus هياخد هذه
+
+317
+00:28:50,900 --> 00:28:55,760
+هياخد القدش اللي زي دهانة، شو هيصير؟ سالب فبناء
+
+318
+00:28:55,760 --> 00:29:01,180
+على ذلك بيصير عند أنا قاعدة بسيطة كتير ان ال amino
+
+319
+00:29:01,180 --> 00:29:08,940
+acids في الوسط الحامضي بيكونوا مجابين، في الوسط
+
+320
+00:29:08,940 --> 00:29:17,250
+القاعدي بيكونوا سالبين، واضح؟ سالبو طبعا بدون ما
+
+321
+00:29:17,250 --> 00:29:21,550
+نضيف عليهم من برا لا حمض ولا قاعدة بيكونوا إيش؟
+
+322
+00:29:21,550 --> 00:29:30,150
+neutral بس في zwitterionic form واضح؟ في شكل ثنائي
+
+323
+00:29:30,150 --> 00:29:33,050
+القطبية، هاي معناه zwitterionic form
+
+324
+00:29:38,320 --> 00:29:43,320
+هي هنا كمان مثال تأكيدي تماما للمثال السابق هو
+
+325
+00:29:43,320 --> 00:29:50,620
+أعطاني amino acid موجة طبعا بدناش ننسا احنا شغلة
+
+326
+00:29:50,620 --> 00:29:54,440
+انه فيش اشي في الدنيا .. فيش اشي في الدنيا بنباع
+
+327
+00:29:55,130 --> 00:29:59,910
+موجب أو سالب يعني لما هنا كنا نقولكوا اضيفوا H
+
+328
+00:29:59,910 --> 00:30:04,390
+plus مافيش H plus بتنجب لحالها و بتلبعها عادة لما
+
+329
+00:30:04,390 --> 00:30:08,230
+نقول اضيف H plus من وين بنجيبها؟ من HCL يعني كان
+
+330
+00:30:08,230 --> 00:30:13,210
+في معاه CL minus وبناء على ذلك لما هذه عملة الايون
+
+331
+00:30:13,210 --> 00:30:20,210
+الموجب كل هذا الجزء الموجب كان فيله CL minus مرافق
+
+332
+00:30:21,300 --> 00:30:27,000
+واضح؟ لكن أنا كنت مختصر الـCl- كده لأن أنا مهتم
+
+333
+00:30:27,000 --> 00:30:30,860
+بجزء الـ amino acid مش بالجزء التاني، واضح؟ بس
+
+334
+00:30:30,860 --> 00:30:34,460
+مافيش H بلس في الكون بتلبع لحالها، يعني الـH بلس
+
+335
+00:30:34,460 --> 00:30:38,100
+جاية من وين؟ من acid، خلّيني أقول HCl، فلو كنت
+
+336
+00:30:38,100 --> 00:30:44,560
+أعطي الـHCl، حيكون هذا موجة ومعه Cl ثالث، الآن لو
+
+337
+00:30:44,560 --> 00:30:49,620
+أخدنا مثل، هاي الـ amino acid الالانينفى nh3 plus
+
+338
+00:30:49,620 --> 00:30:54,560
+cl minus لما نيجى نفعله مع ال N A O H شو اللى بدى
+
+339
+00:30:54,560 --> 00:31:03,480
+يصير ال O H minus بدى تاخد ال H شو عملت ليه H 2 O
+
+340
+00:31:03,480 --> 00:31:06,680
+ال N A plus مع ال C L minus
+
+341
+00:31:11,850 --> 00:31:20,330
+الحمض يبقى في وضعه نيوترال وليس جابوسالد الاسفتر
+
+342
+00:31:20,330 --> 00:31:25,170
+ايونيك نيوترال الان هذا نفسه نيوترال لو اجينا كمان
+
+343
+00:31:25,170 --> 00:31:34,480
+مرة زدناله NAOH شو حيصير ال OH- هتاخدوحدة من هدولة
+
+344
+00:31:34,480 --> 00:31:41,100
+ال H's هتعطيني H2O هيصير بناء على ذلك هذي أنا H2
+
+345
+00:31:41,100 --> 00:31:45,860
+متعادلة بس أنا في عندى minus ال minus بالزمعيون
+
+346
+00:31:45,860 --> 00:31:46,620
+مرافق
+
+347
+00:31:50,390 --> 00:31:54,910
+فهذه المعادلات الحقيقة بلزم انكوا تتدربوا عليها
+
+348
+00:31:54,910 --> 00:31:58,710
+كيف ان ال amino acid بيكتسب بروتون كيف بيفقد
+
+349
+00:31:58,710 --> 00:32:02,870
+بروتون من خلال التفاعل مع حامض بيكتسب بروتونات من
+
+350
+00:32:02,870 --> 00:32:07,070
+خلال التفاعل مع القاعدة بيفقد بروتونات ما لم
+
+351
+00:32:07,070 --> 00:32:10,670
+تكتبوا و تتدربوا بهدوء على هذه المعادلات مش
+
+352
+00:32:10,670 --> 00:32:14,830
+هتتقنوا يعني مرات بنجيبلكوا أكمل المعادلات زي هيك
+
+353
+00:32:14,830 --> 00:32:20,270
+حطيلكوا amino acidع شكل Salt يعني كنا ضايفينله
+
+354
+00:32:20,270 --> 00:32:26,030
+أساسا HCL فعلوه مع NUH مرة أو مرتين يعني بنسبة
+
+355
+00:32:26,030 --> 00:32:31,490
+واحد او بنسبة اتنين اول NUH بتواصلنا لهنا تاني
+
+356
+00:32:31,490 --> 00:32:38,510
+فاعل واضح هذا الكلام وظيفة الطالب انه يتدرب عليه
+
+357
+00:32:38,510 --> 00:32:46,720
+الانمن الكلام هذا كله هنيجي لمحصلة مهمة جدا
+
+358
+00:32:46,720 --> 00:32:50,640
+المحصلة المهمة جدا احنا قلنا انه في ال acidic
+
+359
+00:32:50,640 --> 00:32:54,440
+condition
+
+360
+00:32:54,440 --> 00:33:00,560
+يعني في موضع حامض ال amino acid شو بيكون موجب و في
+
+361
+00:33:00,560 --> 00:33:09,680
+basic condition سالب طبعا معنى acidic low pHالان
+
+362
+00:33:09,680 --> 00:33:15,940
+كون ال amino acid صار ممكن يكون موجود
+
+363
+00:33:17,410 --> 00:33:22,230
+متعادل الـ zwitterionic يعني فيه الموجب والسالب أو
+
+364
+00:33:22,230 --> 00:33:28,450
+بس فيه كأمينو أسد الموجب أو بس فيه كأمينو أسد
+
+365
+00:33:28,450 --> 00:33:34,790
+السالب هذا الكلام بيوفرلي تقنية لفصل إيش ال amino
+
+366
+00:33:34,790 --> 00:33:41,670
+acids قبل ما نصل لهذا الكلام خلينا نقول ان ال BH
+
+367
+00:33:45,180 --> 00:33:50,480
+اللي بيكون عندها ال amino acid neutral سبعة ..
+
+368
+00:33:50,480 --> 00:33:54,360
+بنسميها .. لأ مش سبعة مختلفة .. مختلفة لأن ال
+
+369
+00:33:54,360 --> 00:33:59,320
+amino acid نفسه في مجموعات بتخليه acidic و basic
+
+370
+00:33:59,320 --> 00:34:04,060
+إضافية ال BH اللي بيكون عندها neutral ال amino
+
+371
+00:34:04,060 --> 00:34:08,120
+acid خلينا نقول هيك ال BH اللي بيكون عندها ال
+
+372
+00:34:08,120 --> 00:34:13,390
+amino acid إيش؟الـ neutral بتقول عنها الـ
+
+373
+00:34:13,390 --> 00:34:18,830
+isoelectric point واضح فال isoelectric point اللي
+
+374
+00:34:18,830 --> 00:34:24,550
+هي ال pH اللي بيكون عندها ال amino acid متعدل
+
+375
+00:34:24,550 --> 00:34:30,990
+isoelectric point الان كل amino acid له
+
+376
+00:34:30,990 --> 00:34:37,130
+isoelectric point خاصة فيه لكل ال amino acids
+
+377
+00:34:38,900 --> 00:34:43,840
+هتلاحظوا ان الـ isoelectric point تبعتهم موجودة في
+
+378
+00:34:43,840 --> 00:34:50,100
+الجدوة المحطوطة بين جثين يعني اتطلعوا للجليسين وين
+
+379
+00:34:50,100 --> 00:34:54,840
+بيكون ال amino acid متعادل بالسفتر ايونك and BH؟
+
+380
+00:34:54,840 --> 00:35:01,320
+ستة للالانين ستة للفالين ستة للسيرين مثلا خمسة
+
+381
+00:35:01,320 --> 00:35:09,930
+وسبعة للستين خمسةمجيوسة الان لاحظوا لما يكون عند
+
+382
+00:35:09,930 --> 00:35:14,930
+انا بعض ال amino acids فيهم مجموعة حمضية تانية
+
+383
+00:35:14,930 --> 00:35:20,330
+بتصير ال isoelectric point منخفضة بتصير تلاتة يعني
+
+384
+00:35:20,330 --> 00:35:23,550
+بيقاتش تلاتة بيكونوا متعادلين لما يكون فيهم مجموعة
+
+385
+00:35:23,550 --> 00:35:27,350
+قاعدية تانية بتصير ال isoelectric point عقلهم عالي
+
+386
+00:35:27,350 --> 00:35:33,490
+عند تسعة وعند عشرة تقريبا واضح فكل amino acid الان
+
+387
+00:35:34,530 --> 00:35:39,990
+بنفهم ان هو له isoelectric point ال بي اتش اللى
+
+388
+00:35:39,990 --> 00:35:46,430
+بيكون عندها متعادل الان اقل من ال isoelectric
+
+389
+00:35:46,430 --> 00:35:54,210
+point هذه ال بي اتش ايش بيصير موجب اعلى منها سالب
+
+390
+00:35:54,210 --> 00:35:58,810
+يعني صار في عند انا ال isoelectric point لل amino
+
+391
+00:35:58,810 --> 00:36:08,130
+acid ال isoelectric pointالآن هذه neutral أقل منها
+
+392
+00:36:08,130 --> 00:36:17,310
+موجب أعلى منها سالف واضح؟ وبناء على ذلك لو أنا جيت
+
+393
+00:36:17,310 --> 00:36:22,750
+سألت مثلا للستين شو ال isoelectric point قبل شوية
+
+394
+00:36:22,750 --> 00:36:29,560
+حكيناها ستةلسستين ستة الان لو سألتكم و قولتلكم
+
+395
+00:36:29,560 --> 00:36:35,880
+السستين عند بي اتش اربعة شو بيكون موجب السستين عند
+
+396
+00:36:35,880 --> 00:36:41,620
+بي اتش تسعة او تمانية سالب واضحهذه معناه الكلام
+
+397
+00:36:41,620 --> 00:36:49,000
+يعني BH6 الستين ال neutral بيكون
+
+398
+00:36:49,000 --> 00:36:55,120
+موجب ال BH أعلى بيكون H سالب الآن هذا الموضوع أن
+
+399
+00:36:55,120 --> 00:37:00,200
+ال amino acid ممكن نتحكم فيه يعني الستين أنا
+
+400
+00:37:00,200 --> 00:37:05,620
+بتغيير ال BH قاعد بقدر أخليه مرة يكون موجب مرة
+
+401
+00:37:05,620 --> 00:37:10,240
+يكون متعادل مرة يكون سالب ولا لأأنا اللي بتحكم في
+
+402
+00:37:10,240 --> 00:37:13,400
+ال بي أتش كيف الواحد بتحكم في ال بي أتش بيحط حمض
+
+403
+00:37:13,400 --> 00:37:17,540
+أو قاعدة أو بزيدها أو بنجسها يعني قمر سهل عمليا
+
+404
+00:37:17,540 --> 00:37:24,940
+فكأنه ال بي أتش صار إلها إشي تابع إنه يكونموجب أو
+
+405
+00:37:24,940 --> 00:37:29,820
+سالب الآن جثة الموجب والسالب كتير بتفرج معناه ليش؟
+
+406
+00:37:29,820 --> 00:37:35,560
+لأنه أخدوا منها .. من فكرتها تقنية عامة لفصل ال
+
+407
+00:37:35,560 --> 00:37:41,380
+amino acids عن بعضهم البعض الموجبلو حطيته في مجال
+
+408
+00:37:41,380 --> 00:37:45,780
+كهربائي، في موجة بوسالب، هيروح وين؟ على السالب،
+
+409
+00:37:45,780 --> 00:37:51,400
+والسالب هيروح وين؟ على الموجب، وبناء على ذلك هذا
+
+410
+00:37:51,400 --> 00:37:55,500
+الكلام بيصير أساس لطريقة، لفصل
+
+411
+00:37:58,240 --> 00:38:01,600
+الأمينو أسد هي أنا تعريف ال isoelectric point بس
+
+412
+00:38:01,600 --> 00:38:06,220
+عشان تكونوا متذكرينها is the pH at which the amino
+
+413
+00:38:06,220 --> 00:38:09,520
+acid will be dipolar and have in it its charge
+
+414
+00:38:09,520 --> 00:38:14,780
+equal to zero الأن لما يكون ديبولر و شحنته سفر لو
+
+415
+00:38:14,780 --> 00:38:18,920
+حطيته بوسط كهربا يعني حاطيت قطبين كهربا موجب و
+
+416
+00:38:18,920 --> 00:38:23,710
+سالبو ال بي اتش تبعته ع ال isoelectric point يعني
+
+417
+00:38:23,710 --> 00:38:28,710
+هو متعادل بيروح يمين ولا شمال ولا بيقعد مكانه الان
+
+418
+00:38:28,710 --> 00:38:34,550
+لو كانت ال بي اتش قليلة بمعنى كان موجب و وجدت وين
+
+419
+00:38:34,550 --> 00:38:38,830
+هيروح الموجب؟ على السالب على ال cathode و لو كانت
+
+420
+00:38:38,830 --> 00:38:43,990
+ال بي اتش عالية كان سالب وين هيروح السالب؟ على ال
+
+421
+00:38:43,990 --> 00:38:49,960
+anode مش ال anode هو القطبالموجب والكثود هو القطب
+
+422
+00:38:49,960 --> 00:38:55,600
+السالق وبناء على ذلك بتصير هذه طريقة يمكن من
+
+423
+00:38:55,600 --> 00:39:01,120
+خلالها ان نفصل ال amino acids عن بعض بنسميها ال ال
+
+424
+00:39:01,120 --> 00:39:03,260
+Electrophoresis
+
+425
+00:39:04,140 --> 00:39:07,140
+و هذه طريقة أساسية للناس اللي بيشتغلوا في الكيميا
+
+426
+00:39:07,140 --> 00:39:10,780
+في البروتينات و في ال amino acids بفصلوا من خلالها
+
+427
+00:39:10,780 --> 00:39:15,880
+هي فصل ال amino acids و فصل لبروتينات كهربيا
+
+428
+00:39:15,880 --> 00:39:22,080
+اعتمادا على ايش على شحنتهم الان شحنتهم تعتمد على
+
+429
+00:39:22,080 --> 00:39:28,540
+ال BH اذا انا بقدر اقول هو فصل كهربي لل amino
+
+430
+00:39:28,540 --> 00:39:33,400
+acids او لبروتينات اعتمادا على ال BH في المحصلة
+
+431
+00:39:34,600 --> 00:39:38,380
+واضح؟ هو الفصل اعتمادا على الشحنة انه يروح اشمال
+
+432
+00:39:38,380 --> 00:39:47,160
+او يمين، لكن الشحنة معتمدة على الـ BH ناخد مثالهذا
+
+433
+00:39:47,160 --> 00:39:50,120
+اللي سمناه الـ Electrophoresis is a method for
+
+434
+00:39:50,120 --> 00:39:53,620
+separating amino acids and proteins based on their
+
+435
+00:39:53,620 --> 00:39:58,380
+charge differences طبعا الـ isoelectric point عادة
+
+436
+00:39:58,380 --> 00:40:02,980
+بيعتور رمز بي لو قلنا ال isoelectric point
+
+437
+00:40:02,980 --> 00:40:10,460
+للأسبارتك أسد تلاتة تمام؟ الآن دائما جربوا أنتوا
+
+438
+00:40:10,460 --> 00:40:17,020
+ارسموا زي خط الأعدادتمام؟ الآن هذه الـ isoelectric
+
+439
+00:40:17,020 --> 00:40:24,380
+point للأسبارتك أسد اللي تلاتة عند BH تلاتة شو
+
+440
+00:40:24,380 --> 00:40:29,380
+بيكون الأسبارتك أسد؟ neutral بناء على ذلك لو حطينا
+
+441
+00:40:29,380 --> 00:40:35,640
+الأسبارتك أسد على BH3 و في وسطكهربائي كسودوانوت
+
+442
+00:40:35,640 --> 00:40:40,880
+هيتحرك؟ لأ هو الان بيجي بيسألني بيقول يا تورا على
+
+443
+00:40:40,880 --> 00:40:47,360
+BH5 وين هيروح؟ على الموجة الان انتبهوا معاه إيش
+
+444
+00:40:47,360 --> 00:40:51,840
+اللي عملوا قال طيب لو مخلوط عندي حامضين أسبارتك
+
+445
+00:40:51,840 --> 00:40:57,240
+أسد خلينا هيك نقول هذا الأسبارتك أسد ال BH ال
+
+446
+00:40:57,240 --> 00:41:02,900
+isoelectric point تبعته تلاتة مخلوط مع الألانين
+
+447
+00:41:05,540 --> 00:41:09,620
+القلانين عارفينه القلانين؟ قداش للقلانين ال
+
+448
+00:41:09,620 --> 00:41:18,120
+isoelectric point؟ ستة من الجدول ستة واضح؟ شفتوها؟
+
+449
+00:41:19,750 --> 00:41:25,710
+الالانين عند ستة بيكون متعادل، بتفرج على حاله، صح؟
+
+450
+00:41:25,710 --> 00:41:31,530
+والاسبارتك أسد عند تلاتة بيكون متعادل، بتفرج على
+
+451
+00:41:31,530 --> 00:41:36,390
+حاله، الآن لو إجيت قلت أطلع الاسبارتك أسد لوحده،
+
+452
+00:41:36,390 --> 00:41:43,230
+فوق التلاتة، شو بيكون؟ سالد، تحت التلاتة؟ موجب، لو
+
+453
+00:41:43,230 --> 00:41:45,250
+إجيت على الالانين
+
+454
+00:41:49,340 --> 00:41:56,080
+لو إجيت على الأنانين تحت الستة موجب فوق الستة سالب
+
+455
+00:41:56,080 --> 00:42:01,580
+الآن لو إجيت هدول الاتنين بدي أفصلهم عن بعض بضلني
+
+456
+00:42:01,580 --> 00:42:09,040
+أغير ال bh تغيير ذكي خليني أقول وصلت ال bh لخمسة
+
+457
+00:42:09,040 --> 00:42:15,340
+صار كل المحلول ال bh تبعته خمسة الآن قولولي أنتوا
+
+458
+00:42:15,340 --> 00:42:21,310
+عند خمسة شو بده يكون ال aspartic acid؟سالب فوق
+
+459
+00:42:21,310 --> 00:42:29,710
+التلاتة سالب واضح هيك موجب و عند ستة شو بده يكون
+
+460
+00:42:29,710 --> 00:42:34,150
+القلانين متعادل
+
+461
+00:42:34,150 --> 00:42:39,950
+عند ستة أقل من ستة موجب أعلى من ستة سالب الآن لما
+
+462
+00:42:39,950 --> 00:42:47,400
+أجي أقولكوا عند الخمسة هناتطلعوا معي الألانين موجب
+
+463
+00:42:47,400 --> 00:42:52,300
+الأسبارتك أسد سالب بناء على ذلك هذا الخليط لو
+
+464
+00:42:52,300 --> 00:42:56,500
+اتحكمت في ال بي اتش تبعته خليتها خمسة و حطيت له
+
+465
+00:42:56,500 --> 00:43:01,580
+قطبين كهربا وين هيروح الأسبارتك أسد على قطب الموجب
+
+466
+00:43:01,580 --> 00:43:05,700
+وين هيروح الألانين على قطب السالب انفصلوا عن بعض
+
+467
+00:43:05,700 --> 00:43:12,460
+ولا لأبنفصله طالما طلع هنا مختلف إذا بينفصله طيب
+
+468
+00:43:12,460 --> 00:43:17,780
+الآن انتبهوا معي جيدا حتى نفهم الطريقة بالظبط طبعا
+
+469
+00:43:17,780 --> 00:43:20,460
+احنا قولنا ال aspartic acid فوق التلاتة إيه شو بده
+
+470
+00:43:20,460 --> 00:43:26,040
+يكون؟ تلاتة و ال alanine تحت الستة شو بده يكون؟
+
+471
+00:43:26,040 --> 00:43:32,160
+موجة موجة الآن الإنسان اللي مش ذكي و بده يفصل هدول
+
+472
+00:43:32,160 --> 00:43:42,040
+عن بعضبنقوله اخترنا بي اتش مناسبة للفصل اذا حد اجى
+
+473
+00:43:42,040 --> 00:43:46,600
+جال انا والله بدي اخلي ال بي اتش تبعتهم اتنين ايش
+
+474
+00:43:46,600 --> 00:43:51,020
+رأيكوا؟ اتطلعوا
+
+475
+00:43:51,020 --> 00:43:54,780
+عما عند التنين، التنين موجبين، مش هيفصلوا
+
+476
+00:43:57,210 --> 00:44:01,510
+الان لو اجه واحد قال لأ و الله انا بدي افصلهم عند
+
+477
+00:44:01,510 --> 00:44:07,370
+BH تمانية اتنين سالب اذا اللي بده يختار ال BH
+
+478
+00:44:07,370 --> 00:44:12,850
+المناسبة لفصلهم لازم يختارها بين إيش؟ في المنطقة
+
+479
+00:44:12,850 --> 00:44:16,620
+اللي بيختلفوا فيهاشفتوا كيف لما بنفصل two amino
+
+480
+00:44:16,620 --> 00:44:23,400
+acids عن بعض بحط خط الأعداد باجلة الأول بعمل موجب
+
+481
+00:44:23,400 --> 00:44:27,940
+أقل من ال isoelectric point سالب أكتر باجلة التاني
+
+482
+00:44:27,940 --> 00:44:32,700
+نفس الاشي هاي ال isoelectric point أقل منها موجب
+
+483
+00:44:32,700 --> 00:44:38,500
+أكتر منها سالب الآن ال BH اللي بتفصل اللي بيختلفوا
+
+484
+00:44:38,500 --> 00:44:45,010
+فيهايعني أي BH بين التلاتة والستة بيكون فيها هذا
+
+485
+00:44:45,010 --> 00:44:49,890
+سالب وبيكون فيها هذا موجب تصبح للفصل لكن لو قولت
+
+486
+00:44:49,890 --> 00:44:53,550
+أقل من التلاتة التانين موجبين لو قولت أعلى من
+
+487
+00:44:53,550 --> 00:44:59,590
+الستة التانين سالبين ولذلك لما نعطي مثال ونقول
+
+488
+00:44:59,590 --> 00:45:04,470
+choose the appropriate BH for separating this
+
+489
+00:45:04,470 --> 00:45:12,380
+mixtureبدي أرسم خط الأعداد بيصير الأمر سهل جدا،
+
+490
+00:45:12,380 --> 00:45:20,280
+واضح؟ خلّيني أخد مثال تاني، هذا المثال التاني قال
+
+491
+00:45:20,280 --> 00:45:27,840
+بدنا تفصلونا ل glycine و lycine، طبعا أنا أسهل إشي
+
+492
+00:45:27,840 --> 00:45:33,390
+عندىان اعمل خط الاعداد اتخيل اني بدي احط ال
+
+493
+00:45:33,390 --> 00:45:39,210
+glycine مثلا هنا وال glycine هنا الان هيلزمني من
+
+494
+00:45:39,210 --> 00:45:45,830
+الجداول جداش ال isoelectric point لل glycine احنا
+
+495
+00:45:45,830 --> 00:45:54,610
+احفظنا لل glycine 6 ممتاز طب لل glycine مين شفتلنا
+
+496
+00:45:54,610 --> 00:45:56,290
+إياها 9.7
+
+497
+00:46:00,380 --> 00:46:05,780
+هذه تسعة و سبعة واضح؟ ارسموا بهذا الشكل و تحلوا
+
+498
+00:46:05,780 --> 00:46:08,860
+المسألة معاكم سهولة هاي ال glycine له ال
+
+499
+00:46:08,860 --> 00:46:12,480
+isoelectric point ستة ال glycine تسعة و سبعة الآن
+
+500
+00:46:12,480 --> 00:46:18,780
+بعد هيك هذه النقطة اللي بيكون عندها neutral أقل
+
+501
+00:46:18,780 --> 00:46:26,500
+منها أعلى منها سالم واضح؟ الآن بالنسبة لل glycine
+
+502
+00:46:26,500 --> 00:46:30,750
+هذه النقطة اللي بيكون عندها neutralneutral اقل
+
+503
+00:46:30,750 --> 00:46:35,030
+منها موجب
+
+504
+00:46:35,030 --> 00:46:42,010
+اعلى منها سالم الان لما اجي انا اقول لو انا بدي
+
+505
+00:46:42,010 --> 00:46:48,390
+افصلهم اي BH بتنفع معاه السبعة ممتازة التمانية
+
+506
+00:46:48,390 --> 00:46:54,440
+ممتازة بين الستةو التسعة و سبعة بين ال isoelectric
+
+507
+00:46:54,440 --> 00:46:59,160
+points تبعتهم واضح لكن لو أخدت أقل من الستة
+
+508
+00:46:59,160 --> 00:47:03,020
+التانين في موجبين مش هيفصلوا التانين موجب يعني
+
+509
+00:47:03,020 --> 00:47:06,380
+التانين هيروحوا على ال cathode و لو أخدت أكتر من
+
+510
+00:47:06,380 --> 00:47:09,660
+التسعة و سبعة تانين سالم التانين هيروحوا على ال
+
+511
+00:47:09,660 --> 00:47:13,190
+anode مع بعض مش هيفصلوافانا بتطلع وين بيكونوا
+
+512
+00:47:13,190 --> 00:47:17,670
+مختلفين باخد I BH مناسبة عادة بياخدوها ال between
+
+513
+00:47:17,670 --> 00:47:21,850
+الناس اللي بيشتغلوا طبعا بهذه الطريقة ممكن نفصل
+
+514
+00:47:21,850 --> 00:47:26,400
+كمان مش بس اتنيناكتر من اتنين تلاتة او اربعة او
+
+515
+00:47:26,400 --> 00:47:31,740
+خمسة احيانا لما بيعملوا الفصل بيفصلوا واحد بيودوه
+
+516
+00:47:31,740 --> 00:47:34,980
+على السالب و اتنين مع بعض على الموجة بعد ذلك
+
+517
+00:47:34,980 --> 00:47:39,000
+الاتنين اللي ودوه مع الموجة يعيدوا الفصل انا مش
+
+518
+00:47:39,000 --> 00:47:43,120
+هنحول احنا الى ايش الى مختبر يعني احنا بيكفينا
+
+519
+00:47:43,120 --> 00:47:47,860
+الفكرة العامة بتاعة الفكرة العامة صارت واضحة شهو
+
+520
+00:47:47,860 --> 00:47:52,640
+ال ال Electrophoresis هو طريقة لفصل ال amino acids
+
+521
+00:47:52,640 --> 00:47:59,580
+و البروتيناتاعتمادا على ال بي اتش ال بي اتش هي
+
+522
+00:47:59,580 --> 00:48:07,020
+اللي بتغير ايش الشحنات و بتوجه كل واحد باتجاه مجال
+
+523
+00:48:07,020 --> 00:48:12,640
+كهربي محدد ابهيك بننهي المرة اللي جاي بنبدأ في
+
+524
+00:48:12,640 --> 00:48:14,880
+تفاعلات ال amino acids
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..8a06adf79a4985df8d654ffe7d661b3938145a66
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/fva5m01JkUs_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2102, "start": 19.62, "end": 21.02, "text": "بسم الله الرحمن الرحيم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640], "avg_logprob": -0.03342285230755806, "compression_ratio": 1.0789473684210527, "no_speech_prob": 0.0, "words": [{"start": 19.62, "end": 20.02, "word": "بسم", "probability": 0.91259765625}, {"start": 20.02, "end": 20.22, "word": " الله", "probability": 0.9716796875}, {"start": 20.22, "end": 20.58, "word": " الرحمن", "probability": 0.9777018229166666}, {"start": 20.58, "end": 21.02, "word": " الرحيم", "probability": 0.99365234375}], "temperature": 1.0}, {"id": 2, "seek": 5184, "start": 22.74, "end": 51.84, "text": "مازلنا احنا بنتكلم في موضوع الأحماض ومشتقاتها المرة الماضية اتكلمنا عن ال E-stars وطرق تحضيرهم وبدأنا في موضوع تفاعلات ال E-stars قولنا أول شيء أن التفاعل الأساسي اللي هيتكرر معنا في كل هذا الفصل للأحماض وجميع مشتقاتها وتفاعل الإجدال فكان أول تفاعل أخدناه عن ال E-stars ال ammonolysis يعني أن نبدل ال OR", "tokens": [2304, 31377, 1211, 8315, 1975, 5016, 8315, 44945, 2655, 4117, 19528, 8978, 3714, 2407, 11242, 45367, 16247, 35571, 46958, 4032, 2304, 8592, 2655, 4587, 9307, 11296, 9673, 25720, 9673, 46958, 10632, 1975, 2655, 4117, 19528, 8315, 18871, 2423, 462, 12, 46903, 4032, 9566, 2288, 4587, 6055, 5016, 11242, 13546, 16095, 4032, 44510, 10721, 8315, 8978, 3714, 2407, 11242, 45367, 6055, 5172, 995, 30241, 9307, 2423, 462, 12, 46903, 12174, 12610, 8315, 5551, 12610, 44049, 38207, 14739, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 13672, 1829, 8032, 36081, 37983, 2288, 20449, 8315, 8978, 28242, 23758, 27188, 36520, 24976, 10721, 35571, 46958, 4032, 7435, 2304, 40228, 37893, 2655, 4587, 9307, 11296, 4032, 2655, 5172, 995, 30241, 33688, 7435, 3215, 6027, 6156, 41361, 5551, 12610, 6055, 5172, 995, 30241, 5551, 9778, 3215, 8315, 3224, 18871, 2423, 462, 12, 46903, 2423, 36431, 401, 4642, 37495, 22653, 14739, 8717, 44510, 1211, 2423, 19654], "avg_logprob": -0.15781250635782879, "compression_ratio": 2.0077220077220077, "no_speech_prob": 0.311279296875, "words": [{"start": 22.74, "end": 23.66, "word": "مازلنا", "probability": 0.81500244140625}, {"start": 23.66, "end": 23.92, "word": " احنا", "probability": 0.8824869791666666}, {"start": 23.92, "end": 24.46, "word": " بنتكلم", "probability": 0.9215087890625}, {"start": 24.46, "end": 24.62, "word": " في", "probability": 0.85791015625}, {"start": 24.62, "end": 25.0, "word": " موضوع", "probability": 0.9949951171875}, {"start": 25.0, "end": 25.5, "word": " الأحماض", "probability": 0.9103190104166666}, {"start": 25.5, "end": 26.46, "word": " ومشتقاتها", "probability": 0.8869280133928571}, {"start": 26.46, "end": 27.44, "word": " المرة", "probability": 0.90185546875}, {"start": 27.44, "end": 27.82, "word": " الماضية", "probability": 0.9615885416666666}, {"start": 27.82, "end": 28.34, "word": " اتكلمنا", "probability": 0.93173828125}, {"start": 28.34, "end": 28.54, "word": " عن", "probability": 0.9931640625}, {"start": 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"end": 1244.39, "text": "الـ HCL نيجي للعائلة اللي بعدها", "tokens": [6027, 39184, 389, 22458, 8717, 1829, 7435, 1829, 24976, 3615, 16373, 37977, 13672, 1829, 45030, 3215, 11296], "avg_logprob": -0.2879774272441864, "compression_ratio": 0.9310344827586207, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1236.29, "end": 1236.69, "word": "الـ", "probability": 0.8759765625}, {"start": 1236.69, "end": 1237.25, "word": " HCL", "probability": 0.5880126953125}, {"start": 1237.25, "end": 1241.83, "word": " نيجي", "probability": 0.77044677734375}, {"start": 1241.83, "end": 1243.55, "word": " للعائلة", "probability": 0.8154296875}, {"start": 1243.55, "end": 1243.75, "word": " اللي", "probability": 0.858642578125}, {"start": 1243.75, "end": 1244.39, "word": " بعدها", "probability": 0.7568359375}], "temperature": 1.0}, {"id": 54, "seek": 127032, "start": 1245.2, "end": 1270.32, "text": "من ال derivatives اللي هي ال acid anhydrides ال acid anhydrides بتيجي من تفاعل جزيئين من الحامض مع بعضهم البعض لاحظوا في موضوع ال acid anhydrides من ناحية المبدأ من ناحية المبدأ هناك شبه الطالب المنتبه بموضوع ال ether", "tokens": [27842, 2423, 33733, 13672, 1829, 39896, 2423, 8258, 18931, 6655, 81, 1875, 2423, 8258, 18931, 6655, 81, 1875, 39894, 1829, 7435, 1829, 9154, 6055, 5172, 995, 30241, 10874, 11622, 1829, 19986, 9957, 9154, 21542, 10943, 11242, 20449, 45030, 11242, 16095, 29739, 3615, 11242, 20193, 5016, 19913, 14407, 8978, 3714, 2407, 11242, 45367, 2423, 8258, 18931, 6655, 81, 1875, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 34105, 4117, 13412, 3555, 3224, 41950, 6027, 3555, 9673, 29399, 3555, 3224, 4724, 2304, 2407, 11242, 45367, 2423, 37096], "avg_logprob": -0.10011888773221037, "compression_ratio": 1.9096045197740112, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1245.2, "end": 1245.62, "word": "من", "probability": 0.7158203125}, {"start": 1245.62, "end": 1246.48, "word": " ال", "probability": 0.73974609375}, 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"text": "نفترض CH3 هاي Acetic Acid جزئ و هاي Acetic Acid كمان جزئ هاي الجزئين خلصنا واضح؟ الآن هذا بده ييجي من خلال الـ OH اللي هي الـ nucleophile إهاجمها يطرد الـ OH هذا تفاعل الإبدال ولا لأ؟ هذا تفاعل الإبدال بناء على ذلك لما تطرد الـ OH من هنا مع الـ H هذه", "tokens": [1863, 5172, 2655, 43042, 5995, 18, 8032, 47302, 5097, 3532, 5097, 327, 10874, 11622, 19986, 4032, 8032, 47302, 5097, 3532, 5097, 327, 9122, 2304, 7649, 10874, 11622, 19986, 8032, 47302, 25724, 11622, 19986, 9957, 16490, 1211, 9381, 8315, 4032, 46958, 5016, 22807, 6024, 48506, 23758, 47525, 3224, 7251, 1829, 7435, 1829, 9154, 16490, 1211, 6027, 2423, 39184, 13931, 13672, 1829, 39896, 2423, 39184, 14962, 49242, 11933, 3224, 26108, 2304, 11296, 7251, 9566, 2288, 3215, 2423, 39184, 13931, 23758, 6055, 5172, 995, 30241, 33688, 44510, 6027, 49429, 5296, 10721, 22807, 23758, 6055, 5172, 995, 30241, 33688, 44510, 6027, 44945, 16606, 15844, 29910, 23275, 5296, 15042, 6055, 9566, 2288, 3215, 2423, 39184, 13931, 9154, 34105, 20449, 2423, 39184, 389, 29538], "avg_logprob": -0.19971113570597993, "compression_ratio": 1.8755760368663594, "no_speech_prob": 0.0, "words": [{"start": 1372.32, "end": 1372.9, "word": "نفترض", "probability": 0.8831787109375}, {"start": 1372.9, "end": 1373.82, "word": " CH3", "probability": 0.888427734375}, {"start": 1373.82, "end": 1374.48, "word": " هاي", "probability": 0.459228515625}, {"start": 1374.48, "end": 1374.98, "word": " Acetic", "probability": 0.5513916015625}, {"start": 1374.98, "end": 1375.34, "word": " Acid", "probability": 0.771484375}, {"start": 1375.34, "end": 1375.76, "word": " جزئ", "probability": 0.7490234375}, {"start": 1375.76, "end": 1376.2, "word": " و", "probability": 0.30908203125}, {"start": 1376.2, "end": 1376.46, "word": " هاي", "probability": 0.891357421875}, {"start": 1376.46, "end": 1376.9, "word": " Acetic", "probability": 0.94091796875}, {"start": 1376.9, "end": 1377.94, "word": " Acid", "probability": 0.972900390625}, {"start": 1377.94, "end": 1378.76, "word": " كمان", "probability": 0.86669921875}, {"start": 1378.76, "end": 1379.16, "word": " جزئ", "probability": 0.9549153645833334}, {"start": 1379.16, "end": 1379.44, "word": " هاي", "probability": 0.63330078125}, {"start": 1379.44, "end": 1380.04, "word": " الجزئين", "probability": 0.9066162109375}, {"start": 1380.04, "end": 1380.64, "word": " خلصنا", "probability": 0.9608154296875}, {"start": 1380.64, "end": 1381.58, "word": " واضح؟", "probability": 0.80450439453125}, {"start": 1381.58, "end": 1381.98, "word": " الآن", "probability": 0.6265869140625}, {"start": 1381.98, "end": 1382.7, "word": " هذا", "probability": 0.818359375}, {"start": 1382.7, "end": 1383.1, "word": " بده", "probability": 0.62646484375}, {"start": 1383.1, "end": 1383.38, "word": " ييجي", "probability": 0.9556884765625}, {"start": 1383.38, "end": 1383.5, "word": " من", "probability": 0.99755859375}, {"start": 1383.5, "end": 1383.94, "word": " خلال", "probability": 0.9876302083333334}, {"start": 1383.94, 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"end": 1391.26, "word": " الإبدال", "probability": 0.8318684895833334}, {"start": 1391.26, "end": 1391.46, "word": " ولا", "probability": 0.77880859375}, {"start": 1391.46, "end": 1392.38, "word": " لأ؟", "probability": 0.8458658854166666}, {"start": 1392.38, "end": 1392.58, "word": " هذا", "probability": 0.95361328125}, {"start": 1392.58, "end": 1393.14, "word": " تفاعل", "probability": 0.9534912109375}, {"start": 1393.14, "end": 1393.92, "word": " الإبدال", "probability": 0.9718424479166666}, {"start": 1393.92, "end": 1394.72, "word": " بناء", "probability": 0.920654296875}, {"start": 1394.72, "end": 1394.9, "word": " على", "probability": 0.68408203125}, {"start": 1394.9, "end": 1395.16, "word": " ذلك", "probability": 0.994384765625}, {"start": 1395.16, "end": 1395.38, "word": " لما", "probability": 0.89453125}, {"start": 1395.38, "end": 1395.88, "word": " تطرد", "probability": 0.9708251953125}, {"start": 1395.88, "end": 1396.12, "word": " الـ", "probability": 0.931396484375}, {"start": 1396.12, "end": 1396.48, "word": " OH", "probability": 0.916015625}, {"start": 1396.48, "end": 1396.78, "word": " من", "probability": 0.98828125}, {"start": 1396.78, "end": 1397.12, "word": " هنا", "probability": 0.96484375}, {"start": 1397.12, "end": 1397.7, "word": " مع", "probability": 0.9716796875}, {"start": 1397.7, "end": 1397.98, "word": " الـ", "probability": 0.9462890625}, {"start": 1397.98, "end": 1398.34, "word": " H", "probability": 0.90771484375}, {"start": 1398.34, "end": 1398.92, "word": " هذه", "probability": 0.576171875}], "temperature": 1.0}, {"id": 61, "seek": 141510, "start": 1401.66, "end": 1415.1, "text": "الجزء الأول اللي مبين بالأسود هي CH3COO والجزء التاني OCOO", "tokens": [6027, 7435, 11622, 38207, 16247, 12610, 13672, 1829, 3714, 3555, 9957, 20666, 10721, 3794, 23328, 39896, 5995, 18, 34, 3783, 16070, 7435, 11622, 38207, 16712, 7649, 1829, 422, 34, 3783], "avg_logprob": -0.2978830760525119, "compression_ratio": 1.2435897435897436, "no_speech_prob": 7.152557373046875e-07, "words": [{"start": 1401.6599999999999, "end": 1403.06, "word": "الجزء", "probability": 0.79730224609375}, {"start": 1403.06, "end": 1403.72, "word": " الأول", "probability": 0.93359375}, {"start": 1403.72, "end": 1404.92, "word": " اللي", "probability": 0.63671875}, {"start": 1404.92, "end": 1405.28, "word": " مبين", "probability": 0.8155924479166666}, {"start": 1405.28, "end": 1406.0, "word": " بالأسود", "probability": 0.9364013671875}, {"start": 1406.0, "end": 1406.32, "word": " هي", "probability": 0.4404296875}, {"start": 1406.32, "end": 1409.94, "word": " CH3COO", "probability": 0.70458984375}, {"start": 1409.94, "end": 1411.46, "word": " والجزء", "probability": 0.832763671875}, {"start": 1411.46, "end": 1412.1, "word": " التاني", "probability": 0.9554036458333334}, {"start": 1412.1, "end": 1415.1, "word": " OCOO", "probability": 0.6630045572916666}], "temperature": 1.0}, {"id": 62, "seek": 144362, "start": 1416.52, "end": 1443.62, "text": "CH3 هيتكون عندى الـ Symmetrical Anhydride اتكون عندى الـ Symmetrical Anhydride لاحظوا انه مجموعة الانهيدريد كمجموعة عبارة عن ايش C double bond O O C double bond O يعني لو بدى اقول ال ether كانت O متصلة بتنتين R طيب الانهيدريد هى", "tokens": [5462, 18, 39896, 2655, 30544, 43242, 7578, 2423, 39184, 3902, 2174, 32283, 1107, 21591, 25502, 1975, 2655, 30544, 43242, 7578, 2423, 39184, 3902, 2174, 32283, 23574, 6655, 25502, 20193, 5016, 19913, 14407, 16472, 3224, 3714, 7435, 2304, 2407, 27884, 2423, 7649, 3224, 25708, 2288, 25708, 9122, 2304, 7435, 2304, 2407, 27884, 6225, 3555, 9640, 3660, 18871, 1975, 1829, 8592, 383, 3834, 6086, 422, 422, 383, 3834, 6086, 422, 37495, 22653, 45164, 47525, 7578, 1975, 39648, 2423, 37096, 25961, 2655, 422, 44650, 36520, 3660, 39894, 29399, 9957, 497, 23032, 1829, 3555, 2423, 7649, 3224, 25708, 2288, 25708, 8032, 7578], "avg_logprob": -0.2877209662186979, "compression_ratio": 1.7085427135678393, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1416.52, "end": 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0.9195556640625}, {"start": 1425.24, "end": 1425.72, "word": " انه", "probability": 0.7470703125}, {"start": 1425.72, "end": 1426.84, "word": " مجموعة", "probability": 0.9453125}, {"start": 1426.84, "end": 1427.86, "word": " الانهيدريد", "probability": 0.800537109375}, {"start": 1427.86, "end": 1428.9, "word": " كمجموعة", "probability": 0.9229329427083334}, {"start": 1428.9, "end": 1429.62, "word": " عبارة", "probability": 0.989990234375}, {"start": 1429.62, "end": 1429.82, "word": " عن", "probability": 0.98876953125}, {"start": 1429.82, "end": 1430.26, "word": " ايش", "probability": 0.7779947916666666}, {"start": 1430.26, "end": 1431.3, "word": " C", "probability": 0.329345703125}, {"start": 1431.3, "end": 1431.58, "word": " double", "probability": 0.2459716796875}, {"start": 1431.58, "end": 1432.02, "word": " bond", "probability": 0.93798828125}, {"start": 1432.02, "end": 1432.36, "word": " O", "probability": 0.939453125}, {"start": 1432.36, "end": 1432.84, "word": " O", "probability": 0.568359375}, {"start": 1432.84, "end": 1433.32, "word": " C", "probability": 0.81884765625}, {"start": 1433.32, "end": 1433.56, "word": " double", "probability": 0.90771484375}, {"start": 1433.56, "end": 1433.96, "word": " bond", "probability": 0.982421875}, {"start": 1433.96, "end": 1434.34, "word": " O", "probability": 0.97705078125}, {"start": 1434.34, "end": 1434.98, "word": " يعني", "probability": 0.874267578125}, {"start": 1434.98, "end": 1435.06, "word": " لو", "probability": 0.82568359375}, {"start": 1435.06, "end": 1435.26, "word": " بدى", "probability": 0.69677734375}, {"start": 1435.26, "end": 1435.48, "word": " اقول", "probability": 0.8994140625}, {"start": 1435.48, "end": 1436.04, "word": " ال", "probability": 0.89306640625}, {"start": 1436.04, "end": 1436.48, "word": " ether", "probability": 0.426513671875}, {"start": 1436.48, "end": 1437.42, "word": " كانت", "probability": 0.967529296875}, {"start": 1437.42, "end": 1437.58, "word": " O", "probability": 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"start": 2176.72, "end": 2202.5, "text": "الآن بنسبة 70% منكم عندهم فهم ولكن عندهم خطأ في التنفيذ لأنهم مادربوش إيديهم يكتبوا كان الجواب اللي كتب بهذا الشكل الان انتوا بتحكوا لكن انا عندى إحصائية", "tokens": [6027, 148, 48506, 4724, 1863, 35457, 3660, 5285, 4, 9154, 24793, 43242, 16095, 6156, 16095, 35525, 19452, 43242, 16095, 16490, 9566, 10721, 8978, 16712, 1863, 41185, 8848, 5296, 33456, 16095, 3714, 18513, 25513, 2407, 8592, 11933, 1829, 16254, 16095, 7251, 4117, 2655, 3555, 14407, 25961, 25724, 14407, 3555, 13672, 1829, 9122, 2655, 3555, 39627, 15730, 25124, 28820, 2423, 7649, 16472, 2655, 14407, 39894, 5016, 4117, 14407, 44381, 1975, 8315, 43242, 7578, 11933, 5016, 9381, 16373, 10632], "avg_logprob": -0.18323864333041304, "compression_ratio": 1.6626506024096386, "no_speech_prob": 0.0, "words": [{"start": 2176.7200000000003, "end": 2177.8, "word": "الآن", "probability": 0.70166015625}, {"start": 2177.8, "end": 2178.88, "word": " بنسبة", "probability": 0.77899169921875}, {"start": 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"end": 2186.48, "word": " إيديهم", "probability": 0.8028564453125}, {"start": 2186.48, "end": 2187.12, "word": " يكتبوا", "probability": 0.97509765625}, {"start": 2187.12, "end": 2187.62, "word": " كان", "probability": 0.818359375}, {"start": 2187.62, "end": 2188.3, "word": " الجواب", "probability": 0.9669596354166666}, {"start": 2188.3, "end": 2188.5, "word": " اللي", "probability": 0.9296875}, {"start": 2188.5, "end": 2189.04, "word": " كتب", "probability": 0.9007161458333334}, {"start": 2189.04, "end": 2189.84, "word": " بهذا", "probability": 0.973876953125}, {"start": 2189.84, "end": 2190.42, "word": " الشكل", "probability": 0.98828125}, {"start": 2190.42, "end": 2200.28, "word": " الان", "probability": 0.375}, {"start": 2200.28, "end": 2200.6, "word": " انتوا", "probability": 0.6898600260416666}, {"start": 2200.6, "end": 2201.06, "word": " بتحكوا", "probability": 0.954833984375}, {"start": 2201.06, "end": 2201.3, "word": " لكن", "probability": 0.8310546875}, {"start": 2201.3, "end": 2201.52, "word": " انا", "probability": 0.753662109375}, {"start": 2201.52, "end": 2201.78, "word": " عندى", "probability": 0.5589599609375}, {"start": 2201.78, "end": 2202.5, "word": " إحصائية", "probability": 0.93505859375}], "temperature": 1.0}, {"id": 94, "seek": 222590, "start": 2203.54, "end": 2225.9, "text": "أنا بعمل إحصائية كيف بتكتبوا، 70% منكم كتبوا بهذا الشكل، لا هذه ال carbon أربع روابط ولا هذه أربع روابط ولا محل مكانة ال CL عملوا التفاعل كل هذه الأشياء ليش؟ لأنه مافيش تطبيق، الأصل أنه هنا نكون كاتبين CH2 CH3", "tokens": [10721, 8315, 4724, 25957, 1211, 11933, 5016, 9381, 16373, 10632, 9122, 33911, 39894, 4117, 2655, 3555, 14407, 12399, 5285, 4, 9154, 24793, 9122, 2655, 3555, 14407, 39627, 15730, 25124, 28820, 12399, 20193, 29538, 2423, 5954, 5551, 25513, 3615, 12602, 14407, 3555, 9566, 49429, 29538, 5551, 25513, 3615, 12602, 14407, 3555, 9566, 49429, 3714, 5016, 1211, 3714, 41361, 3660, 2423, 12855, 6225, 42213, 14407, 16712, 5172, 995, 30241, 28242, 29538, 16247, 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{"start": 2207.12, "end": 2207.6, "word": " كتبوا", "probability": 0.994140625}, {"start": 2207.6, "end": 2208.06, "word": " بهذا", "probability": 0.96337890625}, {"start": 2208.06, "end": 2208.92, "word": " الشكل،", "probability": 0.87353515625}, {"start": 2208.92, "end": 2209.06, "word": " لا", "probability": 0.88232421875}, {"start": 2209.06, "end": 2209.4, "word": " هذه", "probability": 0.646484375}, {"start": 2209.4, "end": 2209.56, "word": " ال", "probability": 0.79736328125}, {"start": 2209.56, "end": 2209.88, "word": " carbon", "probability": 0.55224609375}, {"start": 2209.88, "end": 2210.32, "word": " أربع", "probability": 0.9010416666666666}, {"start": 2210.32, "end": 2210.86, "word": " روابط", "probability": 0.967529296875}, {"start": 2210.86, "end": 2211.08, "word": " ولا", "probability": 0.6572265625}, {"start": 2211.08, "end": 2211.34, "word": " هذه", "probability": 0.84521484375}, {"start": 2211.34, "end": 2211.7, "word": " أربع", "probability": 0.9485677083333334}, {"start": 2211.7, "end": 2212.3, "word": " روابط", "probability": 0.9918212890625}, {"start": 2212.3, "end": 2212.76, "word": " ولا", "probability": 0.70751953125}, {"start": 2212.76, "end": 2213.2, "word": " محل", "probability": 0.8981119791666666}, {"start": 2213.2, "end": 2213.78, "word": " مكانة", "probability": 0.80419921875}, {"start": 2213.78, "end": 2213.94, "word": " ال", "probability": 0.9443359375}, {"start": 2213.94, "end": 2214.18, "word": " CL", "probability": 0.5966796875}, {"start": 2214.18, "end": 2214.7, "word": " عملوا", "probability": 0.9283854166666666}, {"start": 2214.7, "end": 2215.44, "word": " التفاعل", "probability": 0.935791015625}, {"start": 2215.44, "end": 2217.18, "word": " كل", "probability": 0.50537109375}, {"start": 2217.18, "end": 2217.42, "word": " هذه", "probability": 0.98193359375}, {"start": 2217.42, "end": 2217.96, "word": " الأشياء", "probability": 0.99560546875}, {"start": 2217.96, "end": 2218.74, "word": " ليش؟", "probability": 0.8722330729166666}, {"start": 2218.74, "end": 2219.0, "word": " لأنه", "probability": 0.8361002604166666}, {"start": 2219.0, "end": 2219.28, "word": " مافيش", "probability": 0.94873046875}, {"start": 2219.28, "end": 2220.72, "word": " تطبيق،", "probability": 0.88916015625}, {"start": 2220.72, "end": 2221.16, "word": " الأصل", "probability": 0.8486328125}, {"start": 2221.16, "end": 2221.46, "word": " أنه", "probability": 0.748291015625}, {"start": 2221.46, "end": 2221.84, "word": " هنا", "probability": 0.951171875}, {"start": 2221.84, "end": 2222.92, "word": " نكون", "probability": 0.58880615234375}, {"start": 2222.92, "end": 2223.38, "word": " كاتبين", "probability": 0.805419921875}, {"start": 2223.38, "end": 2224.22, "word": " CH2", "probability": 0.9462890625}, {"start": 2224.22, "end": 2225.9, "word": " CH3", "probability": 0.7978515625}], "temperature": 1.0}, {"id": 95, "seek": 225642, "start": 2227.28, "end": 2256.42, "text": "الان لما جيبنالكم فاعله مع CH3CWOCL الاصل بدكوا تحطه من هنا من محل ال CL يعني تحطه CWOCL ربما خمسين في المية منكم حطوا هنا CWO وحطوا هنا CH3 بهذا الشكل بهذا الشكل", "tokens": [6027, 7649, 5296, 15042, 10874, 1829, 3555, 8315, 23275, 2304, 6156, 995, 30241, 3224, 20449, 5995, 18, 34, 54, 46, 22458, 2423, 33546, 1211, 47525, 4117, 14407, 6055, 5016, 9566, 3224, 9154, 34105, 9154, 3714, 5016, 1211, 2423, 12855, 37495, 22653, 6055, 5016, 9566, 3224, 383, 54, 46, 22458, 12602, 3555, 15042, 16490, 2304, 3794, 9957, 8978, 9673, 10632, 9154, 24793, 11331, 9566, 14407, 34105, 383, 54, 46, 4032, 5016, 9566, 14407, 34105, 5995, 18, 39627, 15730, 25124, 28820, 39627, 15730, 25124, 28820], "avg_logprob": -0.2070312476938679, "compression_ratio": 1.7261146496815287, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2227.28, "end": 2227.9, "word": "الان", "probability": 0.77734375}, {"start": 2227.9, "end": 2228.38, "word": " لما", "probability": 0.826171875}, {"start": 2228.38, "end": 2229.1, "word": " جيبنالكم", "probability": 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"seek": 259505, "start": 2567.87, "end": 2595.05, "text": "هدولة التلت أحماض موجودين و سمناهم اللي على ال Ortho سمناه Phthalic Acid و اللي على ال NETA Isophthalic Acid و اللي على البارا Terephthalic Acid و قولنالكوا احفظوهم الآن لو يا ترى إجينا نسخن هدولة التلاتة مين فكركوا منهم اللي ممكن يعمل Unhydrate؟", "tokens": [3224, 3215, 12610, 3660, 16712, 1211, 2655, 5551, 35571, 46958, 3714, 29245, 23328, 9957, 4032, 8608, 2304, 8315, 16095, 13672, 1829, 15844, 2423, 27554, 78, 8608, 2304, 8315, 3224, 430, 49123, 299, 5097, 327, 4032, 13672, 1829, 15844, 2423, 426, 4850, 32, 286, 539, 950, 392, 304, 299, 5097, 327, 4032, 13672, 1829, 15844, 29739, 9640, 995, 314, 323, 79, 49123, 299, 5097, 327, 4032, 12174, 12610, 8315, 23275, 14407, 1975, 5016, 5172, 19913, 2407, 16095, 6024, 48506, 45164, 35186, 6055, 2288, 7578, 11933, 7435, 1829, 8315, 8717, 3794, 9778, 1863, 8032, 3215, 12610, 3660, 16712, 1211, 9307, 3660, 3714, 9957, 6156, 37983, 4117, 14407, 9154, 16095, 13672, 1829, 3714, 43020, 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الأورثو لأن هدول بعاد عن بعض مابيجوش فهذا بيعملش أنهيدريد ال isothelic acid و ال teraphthalic acid بيعملش أنهيدريد هذا بيعمل أنهيدريد لو قلنالكوا أرسم الانهيدريد الناتج", "tokens": [6027, 10721, 13063, 12984, 2407, 49429, 2423, 22653, 2655, 995, 49429, 29739, 9640, 995, 4724, 3794, 16247, 13063, 12984, 2407, 5296, 33456, 8032, 3215, 12610, 45030, 18513, 18871, 45030, 11242, 3714, 16758, 1829, 7435, 2407, 8592, 6156, 3224, 15730, 4724, 1829, 25957, 1211, 8592, 14739, 3224, 25708, 2288, 25708, 2423, 307, 900, 338, 299, 8258, 4032, 2423, 1796, 569, 49123, 299, 8258, 4724, 1829, 25957, 1211, 8592, 14739, 3224, 25708, 2288, 25708, 23758, 4724, 1829, 25957, 1211, 14739, 3224, 25708, 2288, 25708, 45164, 12174, 1211, 8315, 23275, 14407, 5551, 2288, 38251, 2423, 7649, 3224, 25708, 2288, 25708, 2423, 8315, 2655, 7435], "avg_logprob": -0.24433210419089185, "compression_ratio": 1.9157303370786516, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2596.03, "end": 2597.07, "word": 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"word": " مابيجوش", "probability": 0.843017578125}, {"start": 2604.61, "end": 2605.37, "word": " فهذا", "probability": 0.80810546875}, {"start": 2605.37, "end": 2606.09, "word": " بيعملش", "probability": 0.94716796875}, {"start": 2606.09, "end": 2607.07, "word": " أنهيدريد", "probability": 0.6462890625}, {"start": 2607.07, "end": 2607.61, "word": " ال", "probability": 0.73681640625}, {"start": 2607.61, "end": 2608.65, "word": " isothelic", "probability": 0.6292724609375}, {"start": 2608.65, "end": 2609.09, "word": " acid", "probability": 0.92919921875}, {"start": 2609.09, "end": 2609.53, "word": " و", "probability": 0.66357421875}, {"start": 2609.53, "end": 2609.69, "word": " ال", "probability": 0.6005859375}, {"start": 2609.69, "end": 2610.55, "word": " teraphthalic", "probability": 0.549346923828125}, {"start": 2610.55, "end": 2610.83, "word": " acid", "probability": 0.97021484375}, {"start": 2610.83, "end": 2611.37, "word": " بيعملش", "probability": 0.9291015625}, {"start": 2611.37, 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{"start": 2634.45, "end": 2634.91, "word": " بيصير", "probability": 0.9813232421875}, {"start": 2634.91, "end": 2635.21, "word": " ايش", "probability": 0.720703125}, {"start": 2635.21, "end": 2637.33, "word": " اسمه", "probability": 0.9443359375}, {"start": 2637.33, "end": 2638.85, "word": " افثالك", "probability": 0.643017578125}, {"start": 2638.85, "end": 2641.81, "word": " انهيدريد", "probability": 0.86591796875}], "temperature": 1.0}, {"id": 111, "seek": 266206, "start": 2644.12, "end": 2662.06, "text": "أفثالك أنهايدرايد واضح طبعا هذه ال mix انهايدرايد حكينا عنها كيف بتتحضر واحد O minus والتاني CL وهي تسميتهم acidic benzoic anhydride حكينا عنه", "tokens": [10721, 5172, 12984, 6027, 4117, 14739, 11296, 25708, 23557, 25708, 4032, 46958, 5016, 23032, 3555, 3615, 995, 29538, 2423, 2890, 16472, 11296, 25708, 23557, 25708, 11331, 4117, 1829, 8315, 18871, 11296, 9122, 33911, 39894, 2655, 5016, 11242, 2288, 36764, 24401, 422, 3175, 16070, 2655, 7649, 1829, 12855, 37037, 1829, 6055, 38251, 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"word": " عنها", "probability": 0.98388671875}, {"start": 2654.64, "end": 2654.86, "word": " كيف", "probability": 0.94921875}, {"start": 2654.86, "end": 2655.72, "word": " بتتحضر", "probability": 0.848974609375}, {"start": 2655.72, "end": 2656.76, "word": " واحد", "probability": 0.854736328125}, {"start": 2656.76, "end": 2656.96, "word": " O", "probability": 0.357177734375}, {"start": 2656.96, "end": 2657.36, "word": " minus", "probability": 0.23291015625}, {"start": 2657.36, "end": 2657.88, "word": " والتاني", "probability": 0.77734375}, {"start": 2657.88, "end": 2658.2, "word": " CL", "probability": 0.462158203125}, {"start": 2658.2, "end": 2658.72, "word": " وهي", "probability": 0.5098876953125}, {"start": 2658.72, "end": 2659.44, "word": " تسميتهم", "probability": 0.8685302734375}, {"start": 2659.44, "end": 2659.9, "word": " acidic", "probability": 0.476318359375}, {"start": 2659.9, "end": 2660.52, "word": " benzoic", "probability": 0.6573893229166666}, {"start": 2660.52, "end": 2661.16, "word": " anhydride", "probability": 0.8435872395833334}, {"start": 2661.16, "end": 2661.64, "word": " حكينا", "probability": 0.9854736328125}, {"start": 2661.64, "end": 2662.06, "word": " عنه", "probability": 0.9794921875}], "temperature": 1.0}, {"id": 112, "seek": 269360, "start": 2669.52, "end": 2693.6, "text": "طبعا لو كنا بدنا ندرس تفاعلات الانهيدريد واحدة تختصر تفاعلات الانهيدريد بكلمة شو هتقول عنهم substitution reaction طبعا ال substitution بده يتم هان و نطرد كل هذه المجموعة بتخرج على شكل إيش", "tokens": [9566, 3555, 3615, 995, 45164, 9122, 8315, 47525, 8315, 8717, 3215, 2288, 3794, 6055, 5172, 995, 30241, 9307, 2423, 7649, 3224, 25708, 2288, 25708, 36764, 24401, 3660, 6055, 46456, 9381, 2288, 6055, 5172, 995, 30241, 9307, 2423, 7649, 3224, 25708, 2288, 25708, 4724, 4117, 19528, 3660, 13412, 2407, 8032, 2655, 39648, 18871, 16095, 35827, 5480, 23032, 3555, 3615, 995, 2423, 35827, 47525, 3224, 7251, 39237, 8032, 7649, 4032, 8717, 9566, 2288, 3215, 28242, 29538, 9673, 7435, 2304, 2407, 27884, 39894, 34740, 7435, 15844, 13412, 28820, 11933, 1829, 8592], "avg_logprob": -0.1534410085570946, "compression_ratio": 1.7277777777777779, "no_speech_prob": 0.0, "words": [{"start": 2669.52, "end": 2670.12, "word": "طبعا", "probability": 0.8973388671875}, {"start": 2670.12, "end": 2670.98, "word": " لو", "probability": 0.5732421875}, {"start": 2670.98, "end": 2671.3, "word": " كنا", "probability": 0.93896484375}, {"start": 2671.3, "end": 2671.6, "word": " بدنا", "probability": 0.92724609375}, {"start": 2671.6, "end": 2672.22, "word": " ندرس", "probability": 0.9866943359375}, {"start": 2672.22, "end": 2673.24, "word": " تفاعلات", "probability": 0.89658203125}, {"start": 2673.24, "end": 2674.3, "word": " الانهيدريد", "probability": 0.7515869140625}, {"start": 2674.3, "end": 2676.74, "word": " واحدة", "probability": 0.8997395833333334}, {"start": 2676.74, "end": 2677.32, "word": " تختصر", "probability": 0.9794921875}, {"start": 2677.32, "end": 2677.98, "word": " تفاعلات", "probability": 0.92265625}, {"start": 2677.98, "end": 2678.76, "word": " الانهيدريد", "probability": 0.9649251302083334}, {"start": 2678.76, "end": 2679.3, "word": " بكلمة", "probability": 0.9144287109375}, {"start": 2679.3, "end": 2679.5, "word": " شو", "probability": 0.6707763671875}, {"start": 2679.5, "end": 2679.82, "word": " هتقول", "probability": 0.9134114583333334}, {"start": 2679.82, "end": 2680.34, "word": " عنهم", "probability": 0.961181640625}, {"start": 2680.34, "end": 2683.2, "word": " substitution", "probability": 0.332763671875}, {"start": 2683.2, "end": 2685.14, "word": " reaction", "probability": 0.87841796875}, {"start": 2685.14, "end": 2686.24, "word": " طبعا", "probability": 0.9461669921875}, {"start": 2686.24, "end": 2686.42, "word": " ال", "probability": 0.916015625}, {"start": 2686.42, "end": 2686.98, "word": " substitution", "probability": 0.94189453125}, {"start": 2686.98, "end": 2687.38, "word": " بده", "probability": 0.6527099609375}, {"start": 2687.38, "end": 2687.66, "word": " يتم", "probability": 0.95703125}, {"start": 2687.66, "end": 2688.12, "word": " هان", "probability": 0.597412109375}, {"start": 2688.12, "end": 2690.12, "word": " و", "probability": 0.92626953125}, {"start": 2690.12, "end": 2690.7, "word": " نطرد", "probability": 0.8470458984375}, {"start": 2690.7, "end": 2691.02, "word": " كل", "probability": 0.962890625}, {"start": 2691.02, "end": 2691.4, "word": " هذه", "probability": 0.95654296875}, {"start": 2691.4, "end": 2692.08, "word": " المجموعة", "probability": 0.91875}, {"start": 2692.08, "end": 2692.56, "word": " بتخرج", "probability": 0.91162109375}, {"start": 2692.56, "end": 2692.76, "word": " على", "probability": 0.88427734375}, {"start": 2692.76, "end": 2693.16, "word": " شكل", "probability": 0.986083984375}, {"start": 2693.16, "end": 2693.6, "word": " إيش", "probability": 0.7996419270833334}], "temperature": 1.0}, {"id": 113, "seek": 271800, "start": 2694.36, "end": 2718.0, "text": "حمض مع الأموليا بيعطيني أمد مثلا مع الكحول بيعطيني Easter مع الميه بيعطيني ال acid التاني و هكذا من هذه النقطة ان شاء الله المرة القادمة بنبدأ بنأكد عليها بس بتكونوا تدربتوا عليها تفاعلات ال acid anhydrides بال substitution بالإبدال", "tokens": [35571, 11242, 20449, 16247, 2304, 12610, 25528, 4724, 40228, 9566, 9957, 1829, 5551, 2304, 3215, 50113, 15040, 20449, 33251, 5016, 12610, 4724, 40228, 9566, 9957, 1829, 9403, 20449, 9673, 1829, 3224, 4724, 40228, 9566, 9957, 1829, 2423, 8258, 16712, 7649, 1829, 4032, 8032, 4117, 15730, 9154, 29538, 28239, 47432, 3660, 16472, 13412, 16606, 21984, 9673, 25720, 25062, 18513, 46007, 44945, 44510, 10721, 44945, 10721, 4117, 3215, 25894, 11296, 4724, 3794, 39894, 30544, 14407, 6055, 3215, 25513, 2655, 14407, 25894, 11296, 6055, 5172, 995, 30241, 9307, 2423, 8258, 364, 3495, 16753, 1875, 20666, 35827, 20666, 28814, 44510, 6027], "avg_logprob": -0.1846301075147123, "compression_ratio": 1.768181818181818, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2694.36, "end": 2695.02, "word": "حمض", "probability": 0.859130859375}, {"start": 2695.02, "end": 2696.02, "word": " مع", "probability": 0.6884765625}, {"start": 2696.02, "end": 2696.66, "word": " الأموليا", "probability": 0.657073974609375}, {"start": 2696.66, "end": 2697.36, "word": " بيعطيني", "probability": 0.766796875}, {"start": 2697.36, "end": 2697.86, "word": " أمد", "probability": 0.7176106770833334}, {"start": 2697.86, "end": 2698.36, "word": " مثلا", "probability": 0.892822265625}, {"start": 2698.36, "end": 2698.58, "word": " مع", "probability": 0.86669921875}, {"start": 2698.58, "end": 2699.36, "word": " الكحول", "probability": 0.9873046875}, {"start": 2699.36, "end": 2700.0, "word": " بيعطيني", "probability": 0.94697265625}, {"start": 2700.0, "end": 2700.36, "word": " Easter", "probability": 0.31591796875}, {"start": 2700.36, "end": 2700.68, "word": " مع", "probability": 0.78759765625}, {"start": 2700.68, "end": 2701.16, "word": " الميه", "probability": 0.8427734375}, {"start": 2701.16, "end": 2701.74, "word": " بيعطيني", "probability": 0.96953125}, {"start": 2701.74, "end": 2701.86, "word": " ال", "probability": 0.9453125}, {"start": 2701.86, "end": 2702.18, "word": " acid", "probability": 0.76953125}, {"start": 2702.18, "end": 2702.94, "word": " التاني", "probability": 0.89599609375}, {"start": 2702.94, "end": 2703.34, "word": " و", "probability": 0.7587890625}, {"start": 2703.34, "end": 2703.86, "word": " هكذا", "probability": 0.8917643229166666}, {"start": 2703.86, "end": 2704.92, "word": " من", "probability": 0.85791015625}, {"start": 2704.92, "end": 2705.24, "word": " هذه", "probability": 0.896484375}, {"start": 2705.24, "end": 2705.7, "word": " النقطة", "probability": 0.9420572916666666}, {"start": 2705.7, "end": 2705.84, "word": " ان", "probability": 0.70458984375}, {"start": 2705.84, "end": 2706.02, "word": " شاء", "probability": 0.960205078125}, {"start": 2706.02, "end": 2706.14, "word": " الله", "probability": 0.94775390625}, {"start": 2706.14, "end": 2706.6, "word": " المرة", "probability": 0.9697265625}, {"start": 2706.6, "end": 2707.28, "word": " القادمة", "probability": 0.9925130208333334}, {"start": 2707.28, "end": 2708.28, "word": " بنبدأ", "probability": 0.6627604166666666}, {"start": 2708.28, "end": 2709.1, "word": " بنأكد", "probability": 0.9210205078125}, {"start": 2709.1, "end": 2709.96, "word": " عليها", "probability": 0.98974609375}, {"start": 2709.96, "end": 2710.64, "word": " بس", "probability": 0.915283203125}, {"start": 2710.64, "end": 2711.08, "word": " بتكونوا", "probability": 0.9000651041666666}, {"start": 2711.08, "end": 2711.7, "word": " تدربتوا", "probability": 0.84111328125}, {"start": 2711.7, "end": 2712.24, "word": " عليها", "probability": 0.9912109375}, {"start": 2712.24, "end": 2713.7, "word": " تفاعلات", "probability": 0.91572265625}, {"start": 2713.7, "end": 2714.48, "word": " ال", "probability": 0.98583984375}, {"start": 2714.48, "end": 2714.96, "word": " acid", "probability": 0.9775390625}, {"start": 2714.96, "end": 2716.22, "word": " anhydrides", "probability": 0.63262939453125}, {"start": 2716.22, "end": 2716.52, "word": " بال", "probability": 0.95751953125}, {"start": 2716.52, "end": 2717.22, "word": " substitution", "probability": 0.73828125}, {"start": 2717.22, "end": 2718.0, "word": " بالإبدال", "probability": 0.8319091796875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2719.05675, "duration_after_vad": 2588.9187499999916}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b2e90e18512e8133626ac5ab048d29f286e7ee34
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_postprocess.srt
@@ -0,0 +1,1896 @@
+1
+00:00:20,180 --> 00:00:26,240
+بسم الله الرحمن الرحيم الفصل التاسع موضوعه ال
+
+2
+00:00:26,240 --> 00:00:31,480
+aldehydes and ketones طبعا ال aldehydes and
+
+3
+00:00:31,480 --> 00:00:36,420
+ketones ربما انتوا اتلاحظوا انه عائلتين مش عائلة
+
+4
+00:00:36,420 --> 00:00:41,000
+واحدة لو اطلعنا هنلاقي ان ال aldehydes و ال
+
+5
+00:00:41,000 --> 00:00:47,000
+ketones هم جزء من عائلة اكبر جزء من عائلة اكبر
+
+6
+00:00:47,000 --> 00:00:53,230
+اسمهاالكربونيل containing compounds يعني المركبات
+
+7
+00:00:53,230 --> 00:00:56,870
+اللى بتحتوي على مجموعة الكربونيل الان ايش مجموعة
+
+8
+00:00:56,870 --> 00:01:02,490
+الكربونيل مجموعة الكربونيل هي ال C double bond O
+
+9
+00:01:02,490 --> 00:01:08,130
+واضح ال C double bond O هي المجموعة اللى اسمها ايش
+
+10
+00:01:08,130 --> 00:01:15,110
+كربونيلالان كتير في مراكبات .. كتير في مراكبات
+
+11
+00:01:15,110 --> 00:01:19,530
+فيهم هذه المجموعة الـ C double bond O يعني من هدول
+
+12
+00:01:19,530 --> 00:01:23,910
+المراكبات الـ aldehydes لما يكون عند الـ C double
+
+13
+00:01:23,910 --> 00:01:28,970
+bond O مجموعة R وH على الجهة التانية منهم الـ
+
+14
+00:01:28,970 --> 00:01:32,110
+ketones لما تكون الـ C double bond O محشورة بين
+
+15
+00:01:32,110 --> 00:01:36,990
+مجمعتين Rمنهم الـ Carboxylic Acids الـ C double
+
+16
+00:01:36,990 --> 00:01:41,750
+bond O متصلة بـ OH الان المراكبات اللي ضايلة
+
+17
+00:01:41,750 --> 00:01:46,030
+بنسميها مشتقات من الـ Carboxylic Acids منها الـ E
+
+18
+00:01:46,030 --> 00:01:49,970
+star C double bond O OR منها الامد C double bond O
+
+19
+00:01:49,970 --> 00:01:57,970
+NH2 منها ال Acid C double bond OCL وفي كمان مركب
+
+20
+00:01:57,970 --> 00:02:03,030
+أيضا موجود ومشهور ولو مش مكتوب هنا R C double bond
+
+21
+00:02:03,030 --> 00:02:09,150
+O O C double bond O R تانية هذا بنسميه acid
+
+22
+00:02:09,150 --> 00:02:15,610
+anhydride بنسميه acid anhydride
+
+23
+00:02:17,770 --> 00:02:23,130
+الان اللى بتطلع على هذه العائلة الكبيرة كتير خلينا
+
+24
+00:02:23,130 --> 00:02:27,630
+نسميه عائلة ال carbonyl compounds هيلحظ انه احنا
+
+25
+00:02:27,630 --> 00:02:31,890
+صارنا بنحكي عن عائلات فرعية موجودة فيها واحد اتنين
+
+26
+00:02:31,890 --> 00:02:38,890
+تلاتة اربع خمسة ستةسبعة يعني عدد كبير من العائلات
+
+27
+00:02:38,890 --> 00:02:42,710
+الفرعية جوا العائلة العاملة هي عائلة الاش ال
+
+28
+00:02:42,710 --> 00:02:46,390
+carbonyl compounds المركبات اللي بتحتوي على مجموعة
+
+29
+00:02:46,390 --> 00:02:53,690
+ال C double bond O لحسن الحظ ان هدول العائلات
+
+30
+00:02:54,350 --> 00:03:01,030
+يقسموا أو يجمعوا إلى عائلتين ال الديهيدس والكيتونز
+
+31
+00:03:01,030 --> 00:03:04,790
+في كل كتب الكيميا العضوية بتلاقوهم محطوطين مع بعض
+
+32
+00:03:04,790 --> 00:03:11,170
+في شبتر واحد والأحماض ومشتقاتها بنسميها assets and
+
+33
+00:03:11,170 --> 00:03:15,710
+their derivatives ال acid derivatives يعني هدولة
+
+34
+00:03:15,710 --> 00:03:19,290
+derivatives لل acid مشتقات derivative يعني إيش؟
+
+35
+00:03:19,970 --> 00:03:25,510
+الاسد ديريفاتيف لو قلنا لكم شو هم الاستر الامد
+
+36
+00:03:25,510 --> 00:03:32,190
+الاسد هيلايد والاسد انهيدريد هدولة الخمسة بنحط
+
+37
+00:03:32,190 --> 00:03:38,330
+بعيلة واحدةلاحظوا صار عندى تقسيم بدل ما هو ل سبع
+
+38
+00:03:38,330 --> 00:03:43,370
+عائلات كلها مختلفة حاطناهم بإيش؟ بعائلتين فقط
+
+39
+00:03:43,370 --> 00:03:48,850
+الهيتز و الفيتون عائلة الاسيتز و مصادرهم كلهم دول
+
+40
+00:03:48,850 --> 00:03:53,290
+عائلة و لذلك عادة في الكيميا العضوية في غالب الكتب
+
+41
+00:03:53,290 --> 00:03:56,630
+هتلاقي انه بنعمل عن كل هذه المركبات chapter يعني
+
+42
+00:03:56,630 --> 00:04:01,490
+فاصلين هدول بنحطه بفصل لحالهم و هدول بنحطه بفصل
+
+43
+00:04:01,490 --> 00:04:02,710
+لحالهم
+
+44
+00:04:05,560 --> 00:04:10,240
+لسه بإمكاننا نبسط الموضوع بإمكاننا نبسط الموضوع
+
+45
+00:04:10,240 --> 00:04:16,230
+أكثر كثير من هيكنقول ليش هذه التقسيمة و كيف أنا
+
+46
+00:04:16,230 --> 00:04:20,450
+الاشي الكتير بدي أسهل التعامل معه بنقول هذه
+
+47
+00:04:20,450 --> 00:04:26,050
+التقسيمة قائمة على كلمتين فقط كلمتين اللي بيفهم
+
+48
+00:04:26,050 --> 00:04:31,150
+دول الكلمتين بنقدر نقول عنه أنه فيهم ست إلى سبع
+
+49
+00:04:31,150 --> 00:04:36,090
+محاضرات للأمام هنضلنا نعيد و نزيد فيهم بنفس
+
+50
+00:04:36,090 --> 00:04:42,790
+الكلمتينواضح؟ صعب على البني آدم يفهم كلمتين كان
+
+51
+00:04:42,790 --> 00:04:48,130
+زمان برنامج بالتلفزيون بالإذاعة اسمه كلمتين و بس
+
+52
+00:04:48,130 --> 00:04:52,630
+خلوه و ميرك معاكم مين اللي كان يقدم هذا البرنامج
+
+53
+00:04:52,630 --> 00:04:58,330
+زمان اسأله الآباء والأجداد المهم ايش الكلمتين
+
+54
+00:04:58,330 --> 00:05:06,290
+المرتبطات بكل هذه العائلات الكلمة الأولىخاصة بأهم
+
+55
+00:05:06,290 --> 00:05:12,070
+تفاعل أساسي لهدول المركبات اللي هم ال aldehydes و
+
+56
+00:05:12,070 --> 00:05:19,630
+ال ketones بيتفاعلوا تفاعل ال addition الإضافة ال
+
+57
+00:05:19,630 --> 00:05:24,730
+addition و الكلمة التانية لهدول الخمسة اللي ضايقين
+
+58
+00:05:24,730 --> 00:05:29,750
+معهم ال unhydrate اللي شطبناه بتفاعلوا تفاعل ال
+
+59
+00:05:29,750 --> 00:05:32,930
+substitution الإبدال تمام؟
+
+60
+00:05:37,060 --> 00:05:43,120
+إذن سبب تقسيم هدول السبع مركبات إلى عائلات يعني
+
+61
+00:05:43,120 --> 00:05:46,440
+أحيانا الإنسان كان ممكن يسأل إذا السبعة بدنا
+
+62
+00:05:46,440 --> 00:05:50,180
+نعملهم عيلتين أو شبترين كان خلينا أربعة في شبتر
+
+63
+00:05:50,180 --> 00:05:56,620
+وتلاتة في شبتر تاني ليش خلينا اتنين وخمسة تمام؟ لأ
+
+64
+00:05:56,620 --> 00:06:03,470
+التقسيم مش تقسيم عددي التقسيم تقسيم وظيفي بمعنىإيش
+
+65
+00:06:03,470 --> 00:06:10,370
+التفاعل الأساسي لهذه العائلة هو تفاعل الإضافة؟ إيش
+
+66
+00:06:10,370 --> 00:06:16,450
+التفاعل الأساسي لهذه العائلة هو تفاعل الإبدال؟
+
+67
+00:06:16,450 --> 00:06:21,310
+ولذلك لو أي طالب organic chemistry بده يدخل مقابل
+
+68
+00:06:21,310 --> 00:06:25,510
+التوظيف، مانعش يمسك ورق و جلم و يكتب، لكن أبسط
+
+69
+00:06:25,510 --> 00:06:29,510
+سؤال بده يسأله ببساطة إيش التفاعل الأساسي
+
+70
+00:06:29,510 --> 00:06:33,660
+للالدهايتز والكيتونز؟ماعرفش يجاوب ايش التفاعل
+
+71
+00:06:33,660 --> 00:06:38,720
+الأساسي لل assets ومش رقاتها ماعرفش يجاوب نراكم في
+
+72
+00:06:38,720 --> 00:06:43,750
+السنة القادمةبالزمش يكون دراسة organic واضح اهتموا
+
+73
+00:06:43,750 --> 00:06:48,950
+كتير بهدول الكلمتين اللي بيفهموهم جيدا بيكونوا
+
+74
+00:06:48,950 --> 00:06:53,530
+فاهموا سبع عائلات اللي بيفهموا دول الكلمتين جيدا
+
+75
+00:06:53,530 --> 00:06:58,350
+بيكونوا فاهموا ايش سبع عائلات ولذلك خلينا نتعمق
+
+76
+00:06:58,350 --> 00:07:03,070
+اكتر بفهم هدول الكلمتين خلينا نتعمق اكتر بفهم هدول
+
+77
+00:07:03,070 --> 00:07:07,280
+الكلمتين الان احنا قولنا ايش ال carbonyl groupالـ
+
+78
+00:07:07,280 --> 00:07:11,960
+C double bond O طب لو كتبنا تحت الكربونيل C double
+
+79
+00:07:11,960 --> 00:07:17,120
+bond O ورجعنا للكلام اللي بنعرفه بخصوص السالبية
+
+80
+00:07:17,120 --> 00:07:22,640
+مين أكثر سالبية؟ ال oxygen مين أقل سالبية؟ ال
+
+81
+00:07:22,640 --> 00:07:26,880
+carbon إذا هذه ال carbon partially positive و هذه
+
+82
+00:07:26,880 --> 00:07:32,180
+ال oxygen partially negative واضح؟ الآن المحور
+
+83
+00:07:32,180 --> 00:07:36,410
+الأساسيفي فهم الكيميا كاملة تبعتي السبع عائلات
+
+84
+00:07:36,410 --> 00:07:43,210
+هدولة بينطلق من انه ال carbon موجبة يعني يمكن أهم
+
+85
+00:07:43,210 --> 00:07:49,530
+كلمة في فهم هذه العائلات السبعة كلها مجتمعة يعني
+
+86
+00:07:49,530 --> 00:07:54,250
+في فهم ال two chapters ان نقول ان هذا ال carbon
+
+87
+00:07:54,250 --> 00:07:59,030
+هاي بدنا نعلمها فيهم كلهم باللون الأحمر اشمالها
+
+88
+00:07:59,030 --> 00:08:07,920
+موجبةالان من باب تحصيل الحاصل الموجب لما يتفاعل ..
+
+89
+00:08:07,920 --> 00:08:14,280
+بنفتح بس على واحدة منهم الموجب لما يتفاعل ايش بده؟
+
+90
+00:08:14,280 --> 00:08:20,460
+بلغة الكيميا ال يوكليوفالالموجب لما يتفاعل بده
+
+91
+00:08:20,460 --> 00:08:24,980
+سالب بده نيوكليوفايل بناء على ذلك طالما جميعهم
+
+92
+00:08:24,980 --> 00:08:29,260
+عندهم ال carbon الموجبة إذا جميعهم تفاعلهم الأساسي
+
+93
+00:08:29,260 --> 00:08:33,580
+بيستنوا نيوكليوفايل واضح؟ يعني بدي أجيب ان
+
+94
+00:08:33,580 --> 00:08:40,360
+نيوكليوفايل و هذا عليه زوجمن الالكترونات زي ما
+
+95
+00:08:40,360 --> 00:08:43,500
+انتوا عارفين سواء كان مشحون او متعادل مش موضوعنا
+
+96
+00:08:43,500 --> 00:08:47,480
+.. وين بده يروح يجري يهاجم ال nucleophile على ال
+
+97
+00:08:47,480 --> 00:08:52,420
+carbon نفس ال nucleophile .. نفس ال nucleophile
+
+98
+00:08:52,420 --> 00:08:59,670
+على ال carbonالان هذا الـ nucleophile لما بيهاجم
+
+99
+00:08:59,670 --> 00:09:04,370
+على الكربون مرة هيعمل تفاعل إضافة في الحالتين
+
+100
+00:09:04,370 --> 00:09:08,870
+الأولانيات و في باقى الحالات هيعمل تفاعل إبدال إذا
+
+101
+00:09:08,870 --> 00:09:13,530
+لو جينا سألناكم قولنا لكم ال aldehydes بيعملوا
+
+102
+00:09:13,530 --> 00:09:19,150
+addition بتقولوا صحو ال acids و المشتقاتة بيعملوا
+
+103
+00:09:19,150 --> 00:09:24,510
+substitution صح لو سألنا هل يا ترى ال eucleophilic
+
+104
+00:09:24,510 --> 00:09:27,850
+addition و ال eucleophilic substitution ولا ال
+
+105
+00:09:27,850 --> 00:09:30,630
+electrophilic addition و ال electrophilic
+
+106
+00:09:30,630 --> 00:09:35,440
+substitution؟ ال eucleophilicإذن الآن بنقدر نزيد
+
+107
+00:09:35,440 --> 00:09:40,440
+كلمة إن ال الديهايدز تفاعلهم الأساسي اللي بديها
+
+108
+00:09:40,440 --> 00:09:45,340
+بالظبط الـ Eucleophilic addition وفهمنا ليش؟ ال
+
+109
+00:09:45,340 --> 00:09:50,460
+Eucleophilic addition و الأحماض و مشتقاتها تفاعلهم
+
+110
+00:09:50,460 --> 00:09:56,390
+الأساسي ال Eucleophilic substitution واضح؟لحد الآن
+
+111
+00:09:56,390 --> 00:10:02,230
+تمام الان بيصير ايش الناتج اللى بده يتكون عندى ايش
+
+112
+00:10:02,230 --> 00:10:06,510
+الناتج اللى بده يتكون في حالة ما كنا بنحكي عن ال
+
+113
+00:10:06,510 --> 00:10:10,870
+aldehydes و ال ketones addition معناه ان ال C
+
+114
+00:10:10,870 --> 00:10:15,070
+double bond O او ال double bond تصير single bondمش
+
+115
+00:10:15,070 --> 00:10:18,050
+هيك احنا قولنا ال addition يعني مجرد ماذا ال
+
+116
+00:10:18,050 --> 00:10:21,830
+nucleophile يهاجم هنا ويعمل رابطة هل معقول يصير
+
+117
+00:10:21,830 --> 00:10:26,290
+عندي خمس روابط؟ لأ، إذا هذه الرابطة بتتحرك تصبح O
+
+118
+00:10:26,290 --> 00:10:31,470
+minus بتصفح OH بتاخد H من اللي ال nucleophile أو
+
+119
+00:10:31,470 --> 00:10:36,310
+من ال solvent إذا الناتج اللي هيصير عندي ناتج ال
+
+120
+00:10:36,310 --> 00:10:40,310
+addition ببساطة إنه سيضة بال bond O تبعت ال ketone
+
+121
+00:10:40,310 --> 00:10:43,830
+أو تبعت ال aldehyde شو بده تصير؟ OH
+
+122
+00:10:46,820 --> 00:10:50,500
+شوفت وين ال addition هنا تم ال addition double
+
+123
+00:10:50,500 --> 00:10:56,980
+single إضافة شو هو ال addition تحويل ال double
+
+124
+00:10:56,980 --> 00:11:00,520
+bond إلى single bond إذا في ال aldehydes و ال
+
+125
+00:11:00,520 --> 00:11:05,060
+ketones ال C double bond O هتصير OH طبّاق
+
+126
+00:11:05,060 --> 00:11:12,240
+المجموعات R زي ما هي H أو R زي ما هي و اللي إجه
+
+127
+00:11:12,240 --> 00:11:14,900
+هنا ال nucleophile
+
+128
+00:11:17,240 --> 00:11:20,840
+مشهور الـ nucleophile اللي هاجمه عام الرابط إذا
+
+129
+00:11:20,840 --> 00:11:26,440
+هذا الشكل العام تبع نتيجة تفاعل ال الديهيد أو ال
+
+130
+00:11:26,440 --> 00:11:30,400
+ketones يعني لو إجينا قولنا مثلا لل nucleophile
+
+131
+00:11:30,400 --> 00:11:32,900
+H2O
+
+132
+00:11:35,400 --> 00:11:39,820
+ماذا سيحصل؟ هذه في كل الأحوال ستصبح OH مع كل أنواع
+
+133
+00:11:39,820 --> 00:11:44,040
+الـ nucleophiles لكن الـ H2O ماذا تضع هنا؟ OH
+
+134
+00:11:44,040 --> 00:11:48,140
+دائما الـ nucleophile المتعدد سنخصه من OH ولو قلنا
+
+135
+00:11:48,140 --> 00:11:53,420
+لـ nucleophile OH-, سيضع أيضًا OH و بعد ذلك نضع
+
+136
+00:11:53,420 --> 00:11:57,880
+acid ستصبح هذه OH إذا لو لـ nucleophile H2O أو H-,
+
+137
+00:11:57,880 --> 00:12:02,700
+سيصبح عندكم على الكربون OH من الألديهيد الأصلي و
+
+138
+00:12:02,700 --> 00:12:10,190
+OHالمهاجمة لو النيوكليوفايل الكهول شوف دي جهانة OR
+
+139
+00:12:10,190 --> 00:12:17,210
+هذه OH لا خلافة فيها ثابتة هذه ثابتة اللي هي ال C
+
+140
+00:12:17,210 --> 00:12:20,290
+double bond O لكن أنا بقول النيوكليوفايل الميا
+
+141
+00:12:20,290 --> 00:12:29,950
+بتحط OH الكحول بيحط OR ال HCl بيحط Cl و هكذا واضحة
+
+142
+00:12:29,950 --> 00:12:36,010
+الفكرة؟هي هذا الشكل العام تبع تفاعل إضافة وهو الذي
+
+143
+00:12:36,010 --> 00:12:41,130
+يميز جميع تفاعلات ال device و ال ketones و هناخد
+
+144
+00:12:41,130 --> 00:12:46,210
+أمثلة تصير كلها تكرار نضل نعيد يقول بيعمل إضافة و
+
+145
+00:12:46,210 --> 00:12:52,290
+بس في كل الأمثلة اللي بناخدها إيش بتصير القصة؟هنا
+
+146
+00:12:52,290 --> 00:12:55,470
+نقول ايه شو هو لليوكليوفايل؟ اذا كان ليوكليوفايل
+
+147
+00:12:55,470 --> 00:12:58,450
+ماء فهذه كذا، اذا كان الكول هذه كذا، اذا كان
+
+148
+00:12:58,450 --> 00:13:02,870
+سياناد كذا، اذا كان هايدرايد هذه كذا، يعني فقط هذا
+
+149
+00:13:02,870 --> 00:13:07,450
+المتغير الوحيد حيصفى عندكم شو هو ليوكليوفايل؟
+
+150
+00:13:07,450 --> 00:13:13,950
+واضح؟ الان لو اجينا وقلنا نفس ليوكليوفايل بده
+
+151
+00:13:13,950 --> 00:13:20,770
+يهاجم علىالكيتون على الكربون الحمراء عفوا على
+
+152
+00:13:20,770 --> 00:13:24,870
+الاسد لأ ما هو الكيتون زي الألدياد خلصنا منه على
+
+153
+00:13:24,870 --> 00:13:31,630
+الاسد أو مشتقاته إيش بيكون التفاعل؟ هذا بيجي هنا و
+
+154
+00:13:31,630 --> 00:13:38,020
+يطرد المجموعة هذهواضح؟ طبعا O H minus لما تترد
+
+155
+00:13:38,020 --> 00:13:43,920
+تاخد H من برا شو هتصير؟ O R minus لما تترد تاخد H
+
+156
+00:13:43,920 --> 00:13:51,460
+R O H كحول N H 2 لما تترد N H 3 C L minus لما يترد
+
+157
+00:13:51,460 --> 00:13:57,140
+C L اذا صار عندى هذه المجموعة هي اللتي تستبدل اللى
+
+158
+00:13:57,140 --> 00:14:03,380
+جنب ايش اللى جنب الصيغة بال bond O بناء على ذلك
+
+159
+00:14:03,380 --> 00:14:09,940
+الناتج ايش هيكون؟R C double bond O هذه ما زالت زي
+
+160
+00:14:09,940 --> 00:14:15,140
+ما هي لكن بدل ال OH او ال OR او ال NH2 whatever
+
+161
+00:14:15,140 --> 00:14:21,120
+whatever صار إبدال enucleophile نيو ن أيه صوديوم
+
+162
+00:14:21,120 --> 00:14:25,480
+نيوكليوفايل واضح يعني شيلنا هذه المجموعة و حطينا
+
+163
+00:14:25,480 --> 00:14:29,880
+مكانها إيش نيوكليوفايل هذا substitution ولا لأ
+
+164
+00:14:29,880 --> 00:14:35,430
+مجموعة جاية مجموعة طالعةواضحك الفكرة و الجزء اللي
+
+165
+00:14:35,430 --> 00:14:39,390
+طلع بياخد H بطلع على شكل ماء على شكل أمونيا على
+
+166
+00:14:39,390 --> 00:14:45,380
+شكل كحول على شكل HClهذا الكلام بتلاقوه بتكرر في كل
+
+167
+00:14:45,380 --> 00:14:50,660
+عائلات الأحماض ومشتقاتها إذا لو احنا كنا حتى
+
+168
+00:14:50,660 --> 00:14:55,280
+chapter 9 هذا اللي بدنا نبدأ فيه بدنا نعطيه عنوان
+
+169
+00:14:55,280 --> 00:14:59,820
+جديد ال dehydes and ketones بين قصين إيش بدنا نكتب
+
+170
+00:14:59,820 --> 00:15:04,300
+ال eucleophilic addition لو كنا في chapter 10 بدنا
+
+171
+00:15:04,300 --> 00:15:08,460
+نقول acids and their derivatives بين قصين ال
+
+172
+00:15:08,460 --> 00:15:12,910
+eucleophilic substitutionاللي فهموا هدولا الكلمتين
+
+173
+00:15:12,910 --> 00:15:19,430
+جيدا واتدربوا عليهم بيقدروا يتريحوا أربع أو خمس
+
+174
+00:15:19,430 --> 00:15:24,370
+محاضرات جاية خلاص بيصيروا بس بتذكروا الكلام اللي
+
+175
+00:15:24,370 --> 00:15:29,230
+قاله الشاعر الجاهلي ما ترانا نقوله إلا معادا من
+
+176
+00:15:29,230 --> 00:15:36,720
+قولنا .. إيش؟ مكرورةبس بنبقى بنقول addition of
+
+177
+00:15:36,720 --> 00:15:42,640
+chapter يعني هتشبعه من كلمة addition of chapter
+
+178
+00:15:43,830 --> 00:15:47,630
+وتشبعوا من كلمة substitution in chapter واضحة
+
+179
+00:15:47,630 --> 00:15:53,230
+الفكرة ما عدا ذلك بيصير كله بالنسبة لنا رتوش بسيطة
+
+180
+00:15:53,230 --> 00:15:56,390
+يعني كيف نسمي ال aldehydes ال ketones إيش أشهر ما
+
+181
+00:15:56,390 --> 00:16:00,590
+هو موجود فيها إيش تطبيقاتها كله تعتبر أشياء بسيطة
+
+182
+00:16:00,590 --> 00:16:06,110
+الفكرة الأساسية لعبلة التصنيف هي متعلقة بطبيعة
+
+183
+00:16:06,110 --> 00:16:13,100
+التفاعل الأساسي لكل عائلة واضحة هذه الفكرةالان لو
+
+184
+00:16:13,100 --> 00:16:18,580
+اتينا مثلا لخواص ال aldehydes و ال ketones بشكل
+
+185
+00:16:18,580 --> 00:16:24,580
+عام لاحظوا كتب عنهم moderately polar يعني متوسطي
+
+186
+00:16:24,580 --> 00:16:30,840
+القطبية الان هو يقارن بين ايش؟ بين شغلتين بين ال R
+
+187
+00:16:30,840 --> 00:16:35,140
+اللي هي ال alkanes لحالها اللي فيها ال London
+
+188
+00:16:35,140 --> 00:16:44,180
+forces و بين ال alcohols اللي فيها ال OHواضح؟ ال
+
+189
+00:16:44,180 --> 00:16:48,480
+alcohols اللي فيها ال OH هيدروجين bonding واضحة
+
+190
+00:16:48,480 --> 00:16:53,080
+الفكرة؟ هنا إيش نوع ال bonding؟ هيدروجين bonding
+
+191
+00:16:53,080 --> 00:17:01,480
+ممتاز وفي ال alkanes لندن forces طب في الألدهات و
+
+192
+00:17:01,480 --> 00:17:03,780
+ال ketones اللي إلها partial positive و partial
+
+193
+00:17:03,780 --> 00:17:08,280
+negative Dipole-dipole attraction اللي تيجي in
+
+194
+00:17:08,280 --> 00:17:16,870
+between Dipole-dipole اللي هيبالظبطواللي ال
+
+195
+00:17:16,870 --> 00:17:20,510
+hydrogen bonding أقوى أنواعها وبناء على ذلك هم
+
+196
+00:17:20,510 --> 00:17:24,610
+أصبحوا moderately polar الان كونهم moderately
+
+197
+00:17:24,610 --> 00:17:28,890
+polar هذا الكلام على طول بنعكس على ايش؟ على نقطة
+
+198
+00:17:28,890 --> 00:17:34,290
+الغليان على نقطة الغليان يعني مثلا لو احنا بدنا
+
+199
+00:17:34,290 --> 00:17:39,270
+نيجي نعمل مقارنة بدنا نيجي نعمل مقارنة بين أشياء
+
+200
+00:17:39,270 --> 00:17:46,320
+شبه متساوية شبه متساوية في الوزن الجزائييعني خدوا
+
+201
+00:17:46,320 --> 00:17:55,400
+على سبيل المثال الميثانول ايش صيغته العامة CH3OH
+
+202
+00:17:55,400 --> 00:18:07,020
+خدوا على سبيل المثال ال formaldehyde CH3OH
+
+203
+00:18:07,020 --> 00:18:08,000
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+204
+00:18:08,000 --> 00:18:11,180
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+205
+00:18:11,180 --> 00:18:12,160
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+206
+00:18:12,160 --> 00:18:12,260
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+207
+00:18:12,260 --> 00:18:18,210
+CH3OH CH3OH CH3CH3 CH3 هدول التلت مركبات يكاف
+
+208
+00:18:18,210 --> 00:18:22,910
+يكونوا متساويين في إيش؟ في الوزن الجزية لو حسبته
+
+209
+00:18:22,910 --> 00:18:29,330
+هنا اتناش و تلاتة خمستاش و ستاش و ستاش، كدش هنا
+
+210
+00:18:29,330 --> 00:18:34,170
+الوزن؟ اتنين و تلاتين لو أجينا على ال formaldehyde
+
+211
+00:18:34,170 --> 00:18:42,130
+ستاش و اتناش و اتنينتلاتين لو اجينا على هذا خمستعش
+
+212
+00:18:42,130 --> 00:18:46,430
+خمستعش تلاتين يعني يكاد يكون ال molecular weight
+
+213
+00:18:46,430 --> 00:18:54,350
+لهم ايش ماله متساوي لكن لو اجينا لو اجينا ل .. ال
+
+214
+00:18:54,350 --> 00:18:58,570
+boiling point لهم التلاتة مين اعلى واحد هيكون
+
+215
+00:18:58,570 --> 00:19:05,490
+الكحول الكحول boiling point خمسة وستينالميثانول
+
+216
+00:19:05,490 --> 00:19:14,670
+هذا الاثانول بيعلق بيصير قداش تقريبا 78 اه الان لو
+
+217
+00:19:14,670 --> 00:19:19,750
+اجينا على ال formaldehyde ال formaldehyde غاز لكن
+
+218
+00:19:19,750 --> 00:19:23,710
+مش كتير منخفضة نقطة غليانه يعني قوله مثلا ناقص
+
+219
+00:19:23,710 --> 00:19:27,370
+عشرين انا مش متأكد بإمكانكوا تبحثوا عنها او نجيبها
+
+220
+00:19:27,370 --> 00:19:32,290
+مرة تانية تعالوا على الاثانهتلاقو ناجس 100 ولا
+
+221
+00:19:32,290 --> 00:19:38,130
+ناجس 120 تقريبا هانا بحثوا تطلعوا كيف ال boiling
+
+222
+00:19:38,130 --> 00:19:41,970
+point بتتغير إذا ال boiling point مرتبطة بإيش
+
+223
+00:19:41,970 --> 00:19:46,350
+مرتبطة بالقطبية بس هذه القيم خليني أقول تقريبية
+
+224
+00:19:46,350 --> 00:19:51,190
+ممكن مرة تانية نجيب القيم الدقيقة واضحة الفكرة ف
+
+225
+00:19:51,190 --> 00:19:57,930
+ال polarity أطول إلى انعكاس علىالقطبية الان طيب و
+
+226
+00:19:57,930 --> 00:20:03,370
+الان عكس على شغل تاني البولاريكي شو هي الذائبية و
+
+227
+00:20:03,370 --> 00:20:09,470
+القاعدة العامة في الموضوع ايش like dissolves like
+
+228
+00:20:09,470 --> 00:20:15,950
+الان اكتر حاجة فيها قطبية ايش الكحولات اللي فيها O
+
+229
+00:20:15,950 --> 00:20:20,190
+H's و بتذكروا حتى لما قلنا عن الكحولات قلنا
+
+230
+00:20:20,190 --> 00:20:26,280
+مابدناش ننسى ان الكحولفي المجمعتين في الجزء القطبي
+
+231
+00:20:26,280 --> 00:20:33,200
+ال R والجزء القطبي ال OH والجزء غير القطبي ال R
+
+232
+00:20:33,200 --> 00:20:37,020
+وبناء على ذلك ال lower alcohols كانت water soluble
+
+233
+00:20:37,020 --> 00:20:42,000
+وال higher alcohols كانت water solubleتذكرين هذه
+
+234
+00:20:42,000 --> 00:20:46,180
+المعلومة؟ الكلام نفسه بتكرر وين؟ في ال ketones
+
+235
+00:20:46,180 --> 00:20:50,400
+برضه ال ketones فيهم جزء قطبة ال C double bond O و
+
+236
+00:20:50,400 --> 00:20:54,780
+فيهم ال R لما تصير ال R هذه كبيرة بيبطلوا يدوبوا
+
+237
+00:20:54,780 --> 00:20:57,840
+في الميه بس R صغيرة يعني مثل و مثل بيصير ال
+
+238
+00:20:57,840 --> 00:21:03,660
+acetone ال acetone بدوب في الميهلكن خلوها إثل و
+
+239
+00:21:03,660 --> 00:21:07,760
+إثل، إبروبل و إبروبل، فينل و إثل، كبرت، بتبطل
+
+240
+00:21:07,760 --> 00:21:12,140
+الدوب في المياه، واضح؟ فال lower molecular weight
+
+241
+00:21:12,140 --> 00:21:14,540
+species، يعني الأشياء اللي ال molecular weight
+
+242
+00:21:14,540 --> 00:21:18,560
+فيها إجليل في الأذيهات والكيتونز، بتكون إيش؟ water
+
+243
+00:21:18,560 --> 00:21:23,320
+soluble، كل ما ال R كبرت، بتبطل، يعني زي زي إيش؟
+
+244
+00:21:23,320 --> 00:21:27,720
+الكحولاتفمن ال الديهيدس اللي بيدوبوا في الميا بشكل
+
+245
+00:21:27,720 --> 00:21:30,600
+عام ال formaldehyde بيدوب في الميا بيعطي ال
+
+246
+00:21:30,600 --> 00:21:34,340
+formalin ال acetaldehyde نسبيا بيدوب بعد هيك بيبطل
+
+247
+00:21:34,340 --> 00:21:38,000
+يدوب من ال ketones ال acetone بيدوب في الميا بعد
+
+248
+00:21:38,000 --> 00:21:43,270
+هيكلما يكبروا ببطله يدوبوا واضح فال low molecular
+
+249
+00:21:43,270 --> 00:21:45,830
+weight species are soluble in water and the
+
+250
+00:21:45,830 --> 00:21:50,270
+solubility decreases بتنقص as the R chain gets
+
+251
+00:21:50,270 --> 00:21:54,570
+longer كل ما كبرت ال R كل ما قلت التأبية وهذا
+
+252
+00:21:54,570 --> 00:21:58,710
+الكلام أيضا في الكحولات لاحظنا واضح الفكرة هذا
+
+253
+00:21:58,710 --> 00:22:02,710
+الكلام أيضا لاحظنا في الكحولات
+
+254
+00:22:06,830 --> 00:22:09,910
+طيب كيف بنسمي ال الديهايد و ال ketones؟ احنا قولنا
+
+255
+00:22:09,910 --> 00:22:14,510
+أساسا كل نظام التسمية في الكيميا العضوية نظام سهل
+
+256
+00:22:14,510 --> 00:22:20,230
+ليش سهل؟ لأنه مبني على ذكر طول السلسلة منتهي برمز
+
+257
+00:22:20,230 --> 00:22:28,770
+للمجموعة الوظيفية ال ال K نهايته L E I O للكحول ال
+
+258
+00:22:28,770 --> 00:22:35,330
+L ل ال الديهايد L و ل ال ketone Oوالذلك ال الديهيد
+
+259
+00:22:35,330 --> 00:22:40,670
+اللى متكون من كربونة واحدة بنقول مثانال مثانال
+
+260
+00:22:40,670 --> 00:22:45,130
+ماخد common name formaldehyde الان لو صاروا
+
+261
+00:22:45,130 --> 00:22:51,120
+كربونتينإيه ثانال؟ أسيتالديهيد الكمونومتينام لو
+
+262
+00:22:51,120 --> 00:22:56,400
+صاروا تلاتة بروبانال بروبيونالديهيد لو صاروا أربعة
+
+263
+00:22:56,400 --> 00:23:01,860
+بيوتانال بيوتيرالديهيد بيوتيرالديهيد الآن لاحظوا
+
+264
+00:23:01,860 --> 00:23:07,320
+هتلاحظوا الفرقبين ال aldehydes و الكحولات يعني في
+
+265
+00:23:07,320 --> 00:23:11,520
+الكحول كنا نقول ethanol, methanol, ethanol,
+
+266
+00:23:11,620 --> 00:23:15,320
+propanol, butanol وهنا بنقول methanol, ethanol,
+
+267
+00:23:15,440 --> 00:23:20,740
+propanol, butanol وين الفرق؟ لأ في فرق تاني أنا
+
+268
+00:23:20,740 --> 00:23:24,760
+عارف ال all و ال al هذه الفرق لكن في فرق تاني
+
+269
+00:23:24,760 --> 00:23:32,360
+الاسم كامل هنافي الكحولات لما أجي أقول بروبانول
+
+270
+00:23:32,360 --> 00:23:36,440
+بكفي؟
+
+271
+00:23:36,440 --> 00:23:42,640
+آه الكحول تلت ذرات كربون الآن هل يتر الأو اتش فيه
+
+272
+00:23:42,640 --> 00:23:47,480
+على واحد؟ one probanol و لا على اتنين؟ two
+
+273
+00:23:47,480 --> 00:23:52,360
+probanol واضح؟ إذا البروبانول في الكحولات منه
+
+274
+00:23:52,360 --> 00:23:59,290
+اتنين و البيوتانول كمان لو صار هذه اربع كربوناتهل
+
+275
+00:23:59,290 --> 00:24:05,490
+الكحول هنا one بيوتانول
+
+276
+00:24:05,490 --> 00:24:10,050
+ولا two بيوتانول ولا two بيوتانول من هنا مش تلاتة
+
+277
+00:24:10,050 --> 00:24:18,590
+ال بيوتانول منه كم الكحول واضح؟ لتشين المتسلسل
+
+278
+00:24:18,590 --> 00:24:23,430
+يعني لو اجاكوا سؤال في الامتحان انه لتشين بيوتانول
+
+279
+00:24:23,430 --> 00:24:30,280
+اللي زي هيك كم كحول بالمجمل منه اتنينهك هتكون
+
+280
+00:24:30,280 --> 00:24:34,660
+جوابته غلط واضح؟
+
+281
+00:24:34,660 --> 00:24:41,060
+ليش؟ مين تقول لي ليش الغلط؟
+
+282
+00:24:41,060 --> 00:24:47,860
+لحظة أنا قلت المتسلسل، بعرف أنه في ISO و في
+
+283
+00:24:47,860 --> 00:24:53,750
+tertiary، هذه قصة تانيةما بدكوا تظلوا تعودوا اه ال
+
+284
+00:24:53,750 --> 00:24:55,910
+chiral center مش ال cis و ال trans ال cis و ال
+
+285
+00:24:55,910 --> 00:24:58,910
+trans كل ما يلي علاقة بالضبط بالبونس و بالحلقات ال
+
+286
+00:24:58,910 --> 00:25:03,870
+chiral center لما بيصير هذا هنا و بحط O H و H ع
+
+287
+00:25:03,870 --> 00:25:08,510
+طول صار عندى ROS من ال two butanol ال two butanol
+
+288
+00:25:08,510 --> 00:25:12,390
+منه ROS ال one butanol مافيش فيه chiral center one
+
+289
+00:25:12,390 --> 00:25:18,170
+butanolواضح؟ طبعا ما بننساش أنه فيه isobutanol و
+
+290
+00:25:18,170 --> 00:25:22,790
+tertiarybutanol كل هدول الأشياء لازم تكونوا
+
+291
+00:25:22,790 --> 00:25:27,470
+عارفينها الان ال aldehydes اللي جابنا للكلام ال
+
+292
+00:25:27,470 --> 00:25:32,190
+aldehydes لأ مافيش منها واحد و اتنين لأن مجموعة ال
+
+293
+00:25:32,190 --> 00:25:36,730
+aldehydes لا تكون الا على نمرة واحد و لانها لا
+
+294
+00:25:36,730 --> 00:25:41,310
+تكون الا على نمرة واحد بنحط ال hash رقميعني ما
+
+295
+00:25:41,310 --> 00:25:46,110
+إجيناش كتبنا إيثان وان قالب روبان وان قالب يوتان
+
+296
+00:25:46,110 --> 00:25:49,510
+وان قالب لأنها لا تكون إلا على واحد فالاشي اللي
+
+297
+00:25:49,510 --> 00:25:54,830
+معروف ضلنا بلزم نكتبه واضح؟ ومثل ال الديهايد
+
+298
+00:25:54,830 --> 00:25:59,210
+بالمناسبة اللي ما بيكونش إلا على نمرة واحد وفقط
+
+299
+00:25:59,210 --> 00:26:07,770
+على واحد ال acid الحامض الحامض ما بيكون إلا على
+
+300
+00:26:07,770 --> 00:26:09,370
+الطرف
+
+301
+00:26:11,040 --> 00:26:15,620
+هيو زي هيو ولا ممكن يكون c double bond o o h في
+
+302
+00:26:15,620 --> 00:26:21,440
+النص مستحيل طب الحامض لو اجيت رقمت من هنا واحد
+
+303
+00:26:21,440 --> 00:26:25,500
+اتنين تلاتة اربعة و بدي اسميه طبعا هقول اكيد
+
+304
+00:26:25,500 --> 00:26:30,580
+بيوتان مافيش فيها لقاش هتقولي اللي هو الحامض ايش
+
+305
+00:26:30,580 --> 00:26:39,300
+نهايته اوك اسدأوك أسد بيوتانووك أسد الان هل يا ترى
+
+306
+00:26:39,300 --> 00:26:44,360
+بنحط بيوتان وان أوك أسد لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+307
+00:26:44,360 --> 00:26:45,200
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+308
+00:26:45,200 --> 00:26:46,700
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+309
+00:26:46,700 --> 00:26:47,880
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+310
+00:26:47,880 --> 00:26:48,340
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+311
+00:26:48,340 --> 00:26:52,440
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ ل
+
+312
+00:26:55,860 --> 00:27:00,100
+لأ ممكن يكون على موقع اتنين او تلاتة او اكتر يعني
+
+313
+00:27:00,100 --> 00:27:03,900
+في ال ketone بعد شوية هتلاحظوا لو كان عندنا خمس
+
+314
+00:27:03,900 --> 00:27:11,720
+ذرات كربون او ستة كم ذرة اللي رسمناهم واحد
+
+315
+00:27:11,720 --> 00:27:17,200
+اتنين تلاتة اربعة خمسة ستة سبعة و اجينا قولنا من
+
+316
+00:27:17,200 --> 00:27:24,440
+هذا المركب كسلسلة كم ketone بقدر اطلعلو قولت كام
+
+317
+00:27:24,440 --> 00:27:29,620
+الديهايد بقدر أعمل منه؟ واحد اسمه Heptanal و الـ C
+
+318
+00:27:29,620 --> 00:27:33,140
+double bond هو Hannah و Jamal لو قولت كام Acid
+
+319
+00:27:33,140 --> 00:27:39,020
+بقدر أطلع؟ Acid، واحد Heptanoic Acid لو قولت كام
+
+320
+00:27:39,020 --> 00:27:43,500
+كيتون؟ إذا إجت Hannah، two Heptanon وإذا إجت
+
+321
+00:27:43,500 --> 00:27:47,880
+Hannah، three Heptanon وإذا إجت Hannah، four
+
+322
+00:27:47,880 --> 00:27:56,330
+Heptanon one, twotwo عفوا واحد اتنين تلات عفوا two
+
+323
+00:27:56,330 --> 00:28:01,070
+و three و four اذا صار عندى two هبتانون و three
+
+324
+00:28:01,070 --> 00:28:05,490
+هبتانون و four هبتانون الا لو اجت هنا بتصير three
+
+325
+00:28:05,490 --> 00:28:08,470
+هبتانون من الجهة التانية او لو اجت هنا two هبتانون
+
+326
+00:28:08,470 --> 00:28:12,490
+من الجهة التانية اذا من هذا صار عندى اكتر من كيتون
+
+327
+00:28:12,490 --> 00:28:16,930
+فالكيتون يحتاج الى ترقيم لما بيلزم بينما ال
+
+328
+00:28:16,930 --> 00:28:22,270
+الديهايد لا يكون الا على موقع واحدوأبعد الفكرة
+
+329
+00:28:22,270 --> 00:28:27,970
+ومثل الديهيد ال acid ومثل ال ketone ال alcohol إذا
+
+330
+00:28:27,970 --> 00:28:32,990
+الأشياء اللي احنا بنسمي بلزم نحطلها أرقام اللي أنا
+
+331
+00:28:32,990 --> 00:28:35,750
+خدوها كلها مين يذكرنا في الأشياء اللي بلزمها
+
+332
+00:28:35,750 --> 00:28:42,450
+أرقامه الأشياء اللي مابلزمها ال alkeneيلزموا أرقام
+
+333
+00:28:42,450 --> 00:28:47,310
+انتبهوا معايا هاي سبع كاربونات لو كنت بعمل الكيل
+
+334
+00:28:47,310 --> 00:28:52,670
+ممكن يكون هنا او هنا او هنا اذا ال الكيل بيلزموا
+
+335
+00:28:52,670 --> 00:28:59,370
+أرقام ال الكاين one-heptane, two-heptane, three
+
+336
+00:28:59,370 --> 00:29:05,030
+-heptane يلزموا أرقام ال alcohol one-heptanol, two
+
+337
+00:29:05,030 --> 00:29:08,690
+-heptanol, three-heptanol, four-heptanol يلزموا
+
+338
+00:29:08,690 --> 00:29:14,920
+أرقامالكيتون two-heptanone، three-heptanone، four
+
+339
+00:29:14,920 --> 00:29:20,340
+-heptanone يلزم أرقام، إذا الالكيل والالكايد
+
+340
+00:29:20,340 --> 00:29:25,760
+والالكول والكيتون هدولة بلزمهم أرقام، لكن لو كنت
+
+341
+00:29:25,760 --> 00:29:30,960
+بحكي عن الديهيد، لأ، هبتنال فقط عن إمرأة واحدة
+
+342
+00:29:31,450 --> 00:29:36,250
+acid, heptanoic acid فالالدهاد والاسد ما بيكونوا
+
+343
+00:29:36,250 --> 00:29:54,710
+غير على موقع واحد واضحة تاني الفكرة حابين
+
+344
+00:29:54,710 --> 00:30:02,640
+تسمعوا الجوابلا بأس السؤال اللي سألته زملتكم أنه
+
+345
+00:30:02,640 --> 00:30:07,460
+لو كان في عندها رابطة ثلاثية و رابطة ثنائية كيف
+
+346
+00:30:07,460 --> 00:30:12,600
+بدي أسم المركب؟ تمام؟ لو عندي رابطة ثلاثية و رابطة
+
+347
+00:30:12,600 --> 00:30:16,800
+ثنائية كيف بدي أسم المركب؟ المركب بدي يكون في ال
+
+348
+00:30:16,800 --> 00:30:23,190
+keen و ال kind، الآن alphabeticalال E قبل ال I،
+
+349
+00:30:23,190 --> 00:30:26,570
+يعني لو كان بسبع ذرات، في double bond و triple
+
+350
+00:30:26,570 --> 00:30:32,170
+bond، إيش هيتسمى؟ هبتين I، يعني بتكونوا تتخيلوه،
+
+351
+00:30:32,170 --> 00:30:37,410
+سبع ذرات بهذا الشكل، بتأكدوا حيكون لإنه سبعة جاب
+
+352
+00:30:37,410 --> 00:30:43,720
+كلمة إيش؟ هبتسبع ذرات إيش هيجيبه؟ Hept لما يكون في
+
+353
+00:30:43,720 --> 00:30:48,960
+double bond ال double bond إيش هيجيبه؟ En لما يكون
+
+354
+00:30:48,960 --> 00:30:56,120
+في triple bond ل triple bond إيش هيجيبه؟ Ein زي
+
+355
+00:30:56,120 --> 00:31:01,490
+هيك لازم اسمه يبينحاجة بتعبر عن العدد بعدين عن
+
+356
+00:31:01,490 --> 00:31:05,650
+الألكين بعدين عن الألكاين هذا الكلام هذا الكلام
+
+357
+00:31:05,650 --> 00:31:12,530
+ككتابة اسم و كذكر مجموعات لكن بيجي سؤال لما بدي
+
+358
+00:31:12,530 --> 00:31:19,920
+أرقم أحدد وين موقع ال E وين موقع ال Iهذه لها جثة
+
+359
+00:31:19,920 --> 00:31:25,080
+تانية و الموقع ال ال و الموقع ال I هذه لها جثة
+
+360
+00:31:25,080 --> 00:31:28,680
+تانية الآن القصة بتقول القات يعني خليني أعمل سبعة
+
+361
+00:31:28,680 --> 00:31:35,560
+واحد اتنين تلاتة اربع خمسة ستة سبعة و حطيت هذه زي
+
+362
+00:31:35,560 --> 00:31:37,300
+هيك و حطيت هنا triple bond
+
+363
+00:31:40,170 --> 00:31:44,050
+هذا heaped in I الان من وان بده ارقمه من هنا ولا
+
+364
+00:31:44,050 --> 00:31:50,230
+من هناك بنقول بنرقمه من الأقرب لأحد الأطراف يعني
+
+365
+00:31:50,230 --> 00:31:53,430
+تكون سواء double او triple اقرب يعني هنا لو عديت
+
+366
+00:31:53,430 --> 00:31:56,130
+واحد اتنين اول multiple point بتقابلني هنا عن
+
+367
+00:31:56,130 --> 00:31:59,930
+امرأة كم؟ تلاتة اول واحدة بتقابلني عن امرأة ايش؟
+
+368
+00:31:59,930 --> 00:32:04,110
+واحد وبناء على ذلك هرقم واحد اتنين تلاتة اربعة
+
+369
+00:32:04,110 --> 00:32:14,600
+خمسة ستة سبعة فهذا هيكون heapedone in أربعة I هبت
+
+370
+00:32:14,600 --> 00:32:23,520
+one in four I واضح طبعا لو انعكس سجلوا هذا الشغل ب
+
+371
+00:32:23,520 --> 00:32:31,160
+ثانية بقول برقم من الأقرب لأحد الأطراف الأقرب
+
+372
+00:32:31,160 --> 00:32:35,760
+بشتغل عليه تمام يعني هذا المركب .. بصوا بري ثانية
+
+373
+00:32:35,760 --> 00:32:41,500
+يا هودايعني هذا المركب نفسه الآن لو كان زي هيك ايش
+
+374
+00:32:41,500 --> 00:32:45,740
+رأيكم؟ هيظلوا على نفس الترقيم؟ اه .. اه .. اه ..
+
+375
+00:32:45,740 --> 00:32:45,840
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+376
+00:32:45,840 --> 00:32:46,020
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+377
+00:32:46,020 --> 00:32:47,260
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+378
+00:32:47,260 --> 00:32:47,540
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+379
+00:32:47,540 --> 00:32:48,040
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+380
+00:32:48,040 --> 00:32:48,460
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+381
+00:32:48,460 --> 00:32:52,340
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. ا
+
+382
+00:32:53,210 --> 00:32:58,710
+يعني مافيش تسمية نهائية تكون I'm in هذه ضد ال
+
+383
+00:32:58,710 --> 00:33:01,910
+alphabetical دائما الاتقاء ال double و ال triple
+
+384
+00:33:01,910 --> 00:33:06,210
+bond يجب أن تكون إيش؟ in I'm مافيش إشي في الكون
+
+385
+00:33:06,210 --> 00:33:11,990
+اسمه I'm in ضد ال alphabetical واضح؟ الآن الترقيم
+
+386
+00:33:11,990 --> 00:33:16,190
+هلجيته؟ هذي جاي ع نمره واحد لو بتعد من هنا بتجي ع
+
+387
+00:33:16,190 --> 00:33:19,770
+نمره واحد اتنين تلاتة إذا هذا الترقيم الصح وجدت
+
+388
+00:33:19,770 --> 00:33:22,470
+هذا المركب لما بده يتسمى مرة تانية
+
+389
+00:33:26,270 --> 00:33:34,090
+لاحظوا in و i عشان يتقارنوا المركبين الان هذا ال
+
+390
+00:33:34,090 --> 00:33:40,250
+in تبع وين اربعة و ال i تبع واحد خلصنا من المركب
+
+391
+00:33:40,250 --> 00:33:46,310
+اللي قبله ماناش فيه هذا بيصير اسمه four in one i
+
+392
+00:33:46,310 --> 00:33:51,450
+فتسمية ال double و ال triple bond إذا التقوا مع
+
+393
+00:33:51,450 --> 00:33:57,650
+بعضيجب أن يُذكروا in I ويجب أن يكون الترقيم من
+
+394
+00:33:57,650 --> 00:34:01,910
+الأقرب إلى أحد الأطراف الآن بيجوا الناس الاش
+
+395
+00:34:01,910 --> 00:34:09,090
+الملولوين عارفين هم؟ اه دول تعون لو بيقولوا طيب يا
+
+396
+00:34:09,090 --> 00:34:14,470
+تورا لو كانوا التنتين على نفس البعد يعني لو حطيت
+
+397
+00:34:14,470 --> 00:34:20,920
+هنا نشطب هدول احنا الآن مش عارفينأه لو كانوا
+
+398
+00:34:20,920 --> 00:34:25,600
+التنتين على نفس البعد حطيتها الرابطة و هالرابطة
+
+399
+00:34:25,600 --> 00:34:30,900
+جيت هنا عديت واحد هاي أول ما بلجي واحدة منه مع
+
+400
+00:34:30,900 --> 00:34:36,320
+نمرقاش اتنين و هنا واحد اتنين على اليمين اتنين و
+
+401
+00:34:36,320 --> 00:34:39,300
+على الشمال اتنين و أكتب نعطي الأولوية لا إيش في
+
+402
+00:34:39,300 --> 00:34:43,880
+الترخيم للتنائية إذا تساوإذا تساوى الأولوي
+
+403
+00:34:43,880 --> 00:34:48,900
+للثنائية فمثل هذا المركب برضه هيكون hip و in و I
+
+404
+00:34:48,900 --> 00:34:53,160
+ان هذا مما لا خلافة فيه كلمة in و I الآن الترقيم
+
+405
+00:34:53,160 --> 00:34:59,180
+لأ بنخليه إذا تساوى المرور على الرابطة الثنائية
+
+406
+00:34:59,180 --> 00:35:08,100
+قبل الرابطة الثلاثية إذا هذا بيكون two in five
+
+407
+00:35:08,100 --> 00:35:15,930
+I واضح الفكرةفهذا الكلام لو انتقى رابطة ثنائية أو
+
+408
+00:35:15,930 --> 00:35:22,750
+ثلاثية يذكره قولا واحدا in I الترقيم من الأقرب
+
+409
+00:35:22,750 --> 00:35:26,610
+لأحد الأطراف بغض النظر كرابطة زوجية أو ثنائية إلا
+
+410
+00:35:26,610 --> 00:35:32,130
+إذا تساووا فالأفضلية هتكون لإيش ال in بتكون مفضلة
+
+411
+00:35:32,130 --> 00:35:37,070
+على ال I احنا هذه المعلومة كنا مختصرينها طالما
+
+412
+00:35:37,070 --> 00:35:40,410
+سألت زمنكوا فيها فصرنا ضايفينها
+
+413
+00:35:44,460 --> 00:35:48,380
+لاحظوا معي ال الديهايد لما تيجي على ال aromatic
+
+414
+00:35:48,380 --> 00:35:54,960
+compounds أخدنا تسميتها يعني هذا benzaldehyde هنا
+
+415
+00:35:54,960 --> 00:35:59,520
+التقاء الديهايد مع الكهول ال الديهايد أقوى من
+
+416
+00:35:59,520 --> 00:36:08,220
+الكهول وعشان هيصير two-hydroxy benzaldehyde
+
+417
+00:36:08,220 --> 00:36:09,540
+شوف الحرف ال بيه رايح
+
+418
+00:36:12,860 --> 00:36:17,280
+2-hydroxybenzaldehyde اللي هو اسمه salicyldehyde
+
+419
+00:36:17,280 --> 00:36:20,720
+يمكن مار عليك انتوا salicylic acid لما تكون هذه OH
+
+420
+00:36:20,720 --> 00:36:25,560
+و هذا acid لو كان الديهايد salicyldehyde مثلا هذا
+
+421
+00:36:25,560 --> 00:36:29,940
+المركب في الديهايد و OH او مثل من اعلى واحدة ال
+
+422
+00:36:29,940 --> 00:36:36,840
+الديهايد اذا مركبي كله هذا اسمهبنزالدهيد ايش بيحمل
+
+423
+00:36:36,840 --> 00:36:42,320
+على نمرة أربعة؟ هيدروكسي وع نمرة تلاتة؟ ميثوكسي
+
+424
+00:36:42,320 --> 00:36:46,860
+إذا هذا لو بدأ أسميه اسم كامل، إيش هقول؟ four
+
+425
+00:36:46,860 --> 00:36:55,780
+-hydroxy three-methoxy، بنستعمل بهرة وميتا؟ four
+
+426
+00:36:55,780 --> 00:37:01,280
+-hydroxy، three-methoxy، benzaldehyde، اللي هو
+
+427
+00:37:01,280 --> 00:37:08,950
+مركب إيش؟الفانيلا يعني الفانيلا هي نفس الاسم تبعها
+
+428
+00:37:08,950 --> 00:37:16,070
+4-hydroxy-3-methoxy-benzaldehyde الآن أخر شغلة بدي
+
+429
+00:37:16,070 --> 00:37:23,250
+أحكيها لو يا ترى إجا الكحول أو الالديهايد أو
+
+430
+00:37:23,250 --> 00:37:29,710
+الكيتون على حلقة لاحظوا معي بدي أخد دراسة مقارنة
+
+431
+00:37:29,710 --> 00:37:38,320
+للثلاثة كحولالديهاي كيتون ييجوا على حلقة نفترض على
+
+432
+00:37:38,320 --> 00:37:46,280
+سايكلوبنتين خلّينا نتطلع بالشكل القاتل هنعمل هنعمل
+
+433
+00:37:46,280 --> 00:37:51,220
+تلت مرات الكلام الآن هي السايكلوبنتين عملناها مرة
+
+434
+00:37:51,220 --> 00:38:02,620
+مرتين تلاتة في مرة حطينا عليها إيش مجموعة OH هذا
+
+435
+00:38:02,620 --> 00:38:08,930
+إيشكحول و في المرة حاطينا عليها C double bond O
+
+436
+00:38:08,930 --> 00:38:13,730
+هذا كيتون في المرة التالتة اجينا نحط عليهم
+
+437
+00:38:13,730 --> 00:38:18,170
+الديهايد ال الديهايد شو هو كيف بقدر احط انا هنا
+
+438
+00:38:18,170 --> 00:38:23,920
+الديهايد جربوامافيش غير ان كل مجموعة ال الديهايد
+
+439
+00:38:23,920 --> 00:38:29,900
+اطلعها برا يعني اطلع برا C double bond O H شوفتوا
+
+440
+00:38:29,900 --> 00:38:33,660
+الفرق بينهم كيف ان انا هنا حطيت O مشبوكة مباشرة
+
+441
+00:38:33,660 --> 00:38:37,680
+بالحلقة هنا حطيت C double bond O مشبوكة مباشرة
+
+442
+00:38:37,680 --> 00:38:41,960
+بالحلقة هنا مافيش طريقة ان اطلع الديهايد ال oxygen
+
+443
+00:38:41,960 --> 00:38:46,100
+فيه مشبوكة مباشرة بالحلقة فبطلع كل مجموعة ال
+
+444
+00:38:46,100 --> 00:38:53,320
+الديهايد براواضح؟ اللي هي مع Carbon هذي زادت عن
+
+445
+00:38:53,320 --> 00:38:57,620
+هذي بإيش؟ ب Carbon ولذلك هذا لما بدنا نسميه
+
+446
+00:38:57,620 --> 00:39:02,560
+Cyclopentanol
+
+447
+00:39:02,560 --> 00:39:08,340
+تان و بنضيف النهاية تبعته All Cyclopentanol خلصنا
+
+448
+00:39:08,340 --> 00:39:16,050
+هذا لما بدنا نسميه نفس الفكرة Cycloبنتان وبنحطله
+
+449
+00:39:16,050 --> 00:39:23,250
+نهاية ال ketone بنتانون وخلصنا هذا لما بدي اسميه
+
+450
+00:39:23,250 --> 00:39:30,330
+.. لأ بسميهوش cycle بالتنالليش؟ لأنه إجي عليه
+
+451
+00:39:30,330 --> 00:39:33,690
+مجموعة كاملة خارجية، إجي عليه كمان carbon، C
+
+452
+00:39:33,690 --> 00:39:39,350
+double bond OH، بنسميه Cyclopenten-carb-aldehyde
+
+453
+00:39:39,350 --> 00:39:43,410
+لأنه إجت carbon زيادة عن اللي جابله، ولذلك هذا إيش
+
+454
+00:39:43,410 --> 00:39:50,910
+بده يتسمى؟ Cyclopenten-carb-aldehyde
+
+455
+00:39:53,820 --> 00:39:58,780
+ملاحظين الفرق بينهم؟ أنه أنا مابقدرش أشبك أكسوجين
+
+456
+00:39:58,780 --> 00:40:02,560
+الالديهايد مباشرة بالحلقة إلا من خلال ذرة كربون
+
+457
+00:40:02,560 --> 00:40:07,620
+ولذلك بنسميه Cyclopentane Carbaldehyde شفتوا الفرق
+
+458
+00:40:07,620 --> 00:40:11,500
+بين الكحول والكيتون والالديهايد لو يجي على حلقة؟
+
+459
+00:40:12,310 --> 00:40:16,630
+الان لو واحدة فيكم شاطرة بعد ما نختم المحاضرة بذكر
+
+460
+00:40:16,630 --> 00:40:20,210
+الله اتقولي كمان اخر مثال عشان نسكر هذه النقطة
+
+461
+00:40:20,210 --> 00:40:26,510
+المفروض يلحق هدولة كلهم ايش هيكون ال acid ال acid
+
+462
+00:40:26,510 --> 00:40:32,070
+لو بده ييجي على الحلقة كيف بده ييجي زي ال aldehyde
+
+463
+00:40:32,070 --> 00:40:37,150
+ال acid لو بده ييجي على الحلقة بده ييجي كله معلج
+
+464
+00:40:37,150 --> 00:40:38,010
+على الحلقة
+
+465
+00:40:42,740 --> 00:40:46,200
+ماقدرش أحطه على نفس الحلقة الأكسجينة المتصلة ولذلك
+
+466
+00:40:46,200 --> 00:40:49,820
+لما بدي أسميه بدي أسميه بشكل موازن لنظام ال
+
+467
+00:40:49,820 --> 00:40:57,680
+الديهايد إيش وجدت حاجة أقول عنه؟ Cyclo .. بنتين ..
+
+468
+00:40:57,680 --> 00:41:03,300
+Carboxylic acid كمان Carboxylic acid
+
+469
+00:41:05,250 --> 00:41:09,150
+شوفتوا كيف مقارنة الأمور بتيجي الكحول والكيتون
+
+470
+00:41:09,150 --> 00:41:11,750
+بيجيوا مباشرة على الحلقة فبنقول cyclopentanol
+
+471
+00:41:11,750 --> 00:41:16,090
+وcyclopentanol ال aldehyde لأ cyclopentane وcarb
+
+472
+00:41:16,090 --> 00:41:20,670
+aldehyde ال acid cyclopentane وcarboxylic acid
+
+473
+00:41:20,670 --> 00:41:26,650
+واضحة الفكرة وبهيك بننهي المحاضرة اليوم المرة اللي
+
+474
+00:41:26,650 --> 00:41:29,970
+جاي بنستمر في موضوع التسمية وموضوع ال aldehydes
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..cb50ad256d4a4255679a2ff2158f2b7afb875bbd
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hJ0uUjaPUvk_raw.json
@@ -0,0 +1 @@
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329.11, "end": 329.75, "word": " ال", "probability": 0.88671875}, {"start": 329.75, "end": 330.65, "word": " substitution", "probability": 0.96435546875}, {"start": 330.65, "end": 332.27, "word": " الإبدال", "probability": 0.80908203125}, {"start": 332.27, "end": 332.93, "word": " تمام؟", "probability": 0.8248697916666666}], "temperature": 1.0}, {"id": 15, "seek": 36238, "start": 337.06, "end": 362.38, "text": "إذن سبب تقسيم هدول السبع مركبات إلى عائلات يعني أحيانا الإنسان كان ممكن يسأل إذا السبعة بدنا نعملهم عيلتين أو شبترين كان خلينا أربعة في شبتر وتلاتة في شبتر تاني ليش خلينا اتنين وخمسة تمام؟ لأ التقسيم مش تقسيم عددي التقسيم تقسيم وظيفي بمعنى", "tokens": [28814, 8848, 1863, 8608, 3555, 3555, 6055, 4587, 3794, 32640, 8032, 3215, 12610, 21136, 3555, 3615, 3714, 31747, 3555, 9307, 30731, 6225, 16373, 1211, 9307, 37495, 22653, 5551, 5016, 1829, 7649, 995, 33688, 1863, 3794, 7649, 25961, 3714, 43020, 7251, 3794, 10721, 1211, 11933, 15730, 21136, 3555, 27884, 47525, 8315, 8717, 25957, 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"end": 1055.47, "word": " نعمل", "probability": 0.9903971354166666}, {"start": 1055.47, "end": 1056.35, "word": " مقارنة", "probability": 0.988671875}, {"start": 1056.35, "end": 1056.71, "word": " بدنا", "probability": 0.765625}, {"start": 1056.71, "end": 1056.93, "word": " نيجي", "probability": 0.996337890625}, {"start": 1056.93, "end": 1057.27, "word": " نعمل", "probability": 0.9967447916666666}, {"start": 1057.27, "end": 1058.17, "word": " مقارنة", "probability": 0.99462890625}, {"start": 1058.17, "end": 1058.61, "word": " بين", "probability": 0.87646484375}, {"start": 1058.61, "end": 1059.27, "word": " أشياء", "probability": 0.964111328125}, {"start": 1059.27, "end": 1060.19, "word": " شبه", "probability": 0.9612630208333334}, {"start": 1060.19, "end": 1062.03, "word": " متساوية", "probability": 0.9693359375}, {"start": 1062.03, "end": 1062.63, "word": " شبه", "probability": 0.837890625}, {"start": 1062.63, "end": 1063.51, "word": " متساوية", "probability": 0.98828125}, {"start": 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1348.77, "end": 1348.93, "word": " L", "probability": 0.352294921875}, {"start": 1348.93, "end": 1349.03, "word": " ل", "probability": 0.404541015625}, {"start": 1349.03, "end": 1349.11, "word": " ال", "probability": 0.9326171875}, {"start": 1349.11, "end": 1349.77, "word": " الديهايد", "probability": 0.899658203125}, {"start": 1349.77, "end": 1350.71, "word": " L", "probability": 0.830078125}, {"start": 1350.71, "end": 1351.15, "word": " و", "probability": 0.58447265625}, {"start": 1351.15, "end": 1351.29, "word": " ل", "probability": 0.69384765625}, {"start": 1351.29, "end": 1351.45, "word": " ال", "probability": 0.8173828125}, {"start": 1351.45, "end": 1352.03, "word": " ketone", "probability": 0.8447265625}, {"start": 1352.03, "end": 1352.57, "word": " O", "probability": 0.5546875}], "temperature": 1.0}, {"id": 59, "seek": 136611, "start": 1353.63, "end": 1366.11, "text": "والذلك ال الديهيد اللى متكون من كربونة واحدة بنقول مثانال مثانال ماخد common name formaldehyde الان لو صاروا كربونتين", "tokens": [2407, 6027, 8848, 23275, 2423, 2423, 16254, 3224, 25708, 13672, 7578, 44650, 30544, 9154, 9122, 25513, 11536, 3660, 36764, 24401, 3660, 44945, 39648, 50113, 7649, 6027, 50113, 7649, 6027, 3714, 47283, 3215, 2689, 1315, 9860, 1479, 3495, 1479, 2423, 7649, 45164, 20328, 9640, 14407, 9122, 25513, 11536, 2655, 9957], "avg_logprob": -0.3215625, "compression_ratio": 1.4477611940298507, "no_speech_prob": 0.0, "words": [{"start": 1353.63, "end": 1354.39, "word": "والذلك", "probability": 0.66937255859375}, {"start": 1354.39, "end": 1354.83, "word": " ال", "probability": 0.640625}, {"start": 1354.83, "end": 1355.33, "word": " الديهيد", "probability": 0.65557861328125}, {"start": 1355.33, "end": 1355.45, "word": " اللى", "probability": 0.5283203125}, {"start": 1355.45, "end": 1355.81, "word": " متكون", "probability": 0.70263671875}, {"start": 1355.81, "end": 1355.99, "word": " من", "probability": 0.96533203125}, {"start": 1355.99, "end": 1356.53, "word": " كربونة", 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"word": " و", "probability": 0.5166015625}, {"start": 1487.74, "end": 1487.86, "word": " في", "probability": 0.6953125}, {"start": 1487.86, "end": 1489.2, "word": " tertiary،", "probability": 0.7613932291666666}, {"start": 1489.2, "end": 1489.32, "word": " هذه", "probability": 0.58740234375}, {"start": 1489.32, "end": 1489.74, "word": " قصة", "probability": 0.7811686197916666}, {"start": 1489.74, "end": 1490.28, "word": " تانية", "probability": 0.9762369791666666}], "temperature": 1.0}, {"id": 65, "seek": 151309, "start": 1491.95, "end": 1513.09, "text": "ما بدكوا تظلوا تعودوا اه ال chiral center مش ال cis و ال trans ال cis و ال trans كل ما يلي علاقة بالضبط بالبونس و بالحلقات ال chiral center لما بيصير هذا هنا و بحط O H و H ع طول صار عندى ROS من ال two butanol ال two butanol منه ROS ال one butanol مافيش فيه chiral center one butanol", "tokens": [15042, 47525, 4117, 14407, 6055, 19913, 1211, 14407, 37279, 23328, 14407, 1975, 3224, 2423, 23782, 304, 3056, 37893, 2423, 37847, 4032, 2423, 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"end": 1493.61, "word": " اه", "probability": 0.51177978515625}, {"start": 1493.61, "end": 1493.75, "word": " ال", "probability": 0.5244140625}, {"start": 1493.75, "end": 1494.11, "word": " chiral", "probability": 0.7442626953125}, {"start": 1494.11, "end": 1494.45, "word": " center", "probability": 0.76025390625}, {"start": 1494.45, "end": 1494.69, "word": " مش", "probability": 0.89453125}, {"start": 1494.69, "end": 1494.87, "word": " ال", "probability": 0.8935546875}, {"start": 1494.87, "end": 1495.03, "word": " cis", "probability": 0.45703125}, {"start": 1495.03, "end": 1495.19, "word": " و", "probability": 0.93798828125}, {"start": 1495.19, "end": 1495.23, "word": " ال", "probability": 0.3173828125}, {"start": 1495.23, "end": 1495.49, "word": " trans", "probability": 0.88427734375}, {"start": 1495.49, "end": 1495.63, "word": " ال", "probability": 0.15869140625}, {"start": 1495.63, "end": 1495.77, "word": " cis", "probability": 0.87109375}, {"start": 1495.77, "end": 1495.89, "word": " و", "probability": 0.98046875}, {"start": 1495.89, "end": 1495.91, "word": " ال", "probability": 0.81689453125}, {"start": 1495.91, "end": 1496.15, "word": " trans", "probability": 0.93017578125}, {"start": 1496.15, "end": 1496.39, "word": " كل", "probability": 0.6591796875}, {"start": 1496.39, "end": 1496.49, "word": " ما", "probability": 0.9052734375}, {"start": 1496.49, "end": 1496.61, "word": " يلي", "probability": 0.3017578125}, {"start": 1496.61, "end": 1496.97, "word": " علاقة", "probability": 0.90087890625}, {"start": 1496.97, "end": 1497.31, "word": " بالضبط", "probability": 0.8052978515625}, {"start": 1497.31, "end": 1497.75, "word": " بالبونس", "probability": 0.6680908203125}, {"start": 1497.75, "end": 1497.83, "word": " و", "probability": 0.7294921875}, {"start": 1497.83, "end": 1498.51, "word": " بالحلقات", "probability": 0.87578125}, {"start": 1498.51, "end": 1498.91, "word": " ال", "probability": 0.6123046875}, {"start": 1498.91, "end": 1499.39, "word": " chiral", "probability": 0.963623046875}, {"start": 1499.39, "end": 1499.91, "word": " center", "probability": 0.919921875}, {"start": 1499.91, "end": 1500.45, "word": " لما", "probability": 0.9384765625}, {"start": 1500.45, "end": 1500.87, "word": " بيصير", "probability": 0.8380126953125}, {"start": 1500.87, "end": 1501.39, "word": " هذا", "probability": 0.92138671875}, {"start": 1501.39, "end": 1501.95, "word": " هنا", "probability": 0.7265625}, {"start": 1501.95, "end": 1502.09, "word": " و", "probability": 0.876953125}, {"start": 1502.09, "end": 1502.55, "word": " بحط", "probability": 0.9562174479166666}, {"start": 1502.55, "end": 1502.83, "word": " O", "probability": 0.36328125}, {"start": 1502.83, "end": 1503.21, "word": " H", "probability": 0.44091796875}, {"start": 1503.21, "end": 1503.39, "word": " و", "probability": 0.79443359375}, {"start": 1503.39, "end": 1503.69, "word": " H", "probability": 0.82080078125}, {"start": 1503.69, "end": 1503.87, "word": " ع", "probability": 0.72509765625}, {"start": 1503.87, "end": 1504.07, "word": " طول", "probability": 0.8564453125}, {"start": 1504.07, "end": 1504.35, "word": " صار", "probability": 0.925048828125}, {"start": 1504.35, "end": 1504.65, "word": " عندى", "probability": 0.76806640625}, {"start": 1504.65, "end": 1505.07, "word": " ROS", "probability": 0.52978515625}, {"start": 1505.07, "end": 1505.37, "word": " من", "probability": 0.99267578125}, {"start": 1505.37, "end": 1505.51, "word": " ال", "probability": 0.9580078125}, {"start": 1505.51, "end": 1505.69, "word": " two", "probability": 0.57421875}, {"start": 1505.69, "end": 1506.47, "word": " butanol", "probability": 0.8068033854166666}, {"start": 1506.47, "end": 1507.65, "word": " ال", "probability": 0.939453125}, {"start": 1507.65, "end": 1507.83, "word": " two", "probability": 0.74560546875}, {"start": 1507.83, "end": 1508.51, "word": " butanol", "probability": 0.9736328125}, {"start": 1508.51, "end": 1508.99, "word": " منه", "probability": 0.906982421875}, {"start": 1508.99, "end": 1509.61, "word": " ROS", "probability": 0.63427734375}, {"start": 1509.61, "end": 1510.27, "word": " ال", "probability": 0.97998046875}, {"start": 1510.27, "end": 1510.43, "word": " one", "probability": 0.966796875}, {"start": 1510.43, "end": 1510.95, "word": " butanol", "probability": 0.9759114583333334}, {"start": 1510.95, "end": 1511.15, "word": " مافيش", "probability": 0.7291666666666666}, {"start": 1511.15, "end": 1511.31, "word": " فيه", "probability": 0.89794921875}, {"start": 1511.31, "end": 1511.73, "word": " chiral", "probability": 0.936767578125}, {"start": 1511.73, "end": 1512.15, "word": " center", "probability": 0.931640625}, {"start": 1512.15, "end": 1512.39, "word": " one", "probability": 0.630859375}, {"start": 1512.39, "end": 1513.09, "word": " butanol", "probability": 0.9723307291666666}], "temperature": 1.0}, {"id": 66, "seek": 153959, "start": 1513.95, "end": 1539.59, "text": "واضح؟ طبعا ما بننساش أنه فيه isobutanol و tertiarybutanol كل هدول الأشياء لازم تكونوا عارفينها الان ال aldehydes اللي جابنا للكلام ال aldehydes لأ مافيش منها واحد و اتنين لأن مجموعة ال aldehydes لا تكون الا على نمرة واحد و لانها لا تكون الا على نمرة واحد بنحط ال hash رقم", "tokens": [2407, 46958, 5016, 22807, 23032, 3555, 3615, 995, 19446, 44945, 1863, 3794, 33599, 14739, 3224, 8978, 3224, 307, 996, 30624, 401, 4032, 38726, 29104, 5955, 282, 401, 28242, 8032, 3215, 12610, 16247, 8592, 1829, 16606, 5296, 31377, 2304, 6055, 30544, 14407, 6225, 9640, 5172, 9957, 11296, 2423, 7649, 2423, 16798, 68, 3495, 14792, 13672, 1829, 10874, 16758, 8315, 24976, 28820, 10943, 2423, 16798, 68, 3495, 14792, 5296, 10721, 19446, 41185, 8592, 9154, 11296, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 5296, 33456, 3714, 7435, 2304, 2407, 27884, 2423, 16798, 68, 3495, 14792, 20193, 6055, 30544, 42963, 15844, 8717, 2304, 25720, 36764, 24401, 4032, 5296, 7649, 11296, 20193, 6055, 30544, 42963, 15844, 8717, 2304, 25720, 36764, 24401, 44945, 5016, 9566, 2423, 22019, 12602, 4587, 2304], "avg_logprob": -0.1916250057220459, "compression_ratio": 1.9039301310043668, "no_speech_prob": 0.0, "words": [{"start": 1513.95, "end": 1514.71, "word": "واضح؟", "probability": 0.80194091796875}, {"start": 1514.71, "end": 1515.33, "word": " طبعا", "probability": 0.9683837890625}, {"start": 1515.33, "end": 1515.91, "word": " ما", "probability": 0.70703125}, {"start": 1515.91, "end": 1516.49, "word": " بننساش", "probability": 0.8856201171875}, {"start": 1516.49, "end": 1516.67, "word": " أنه", "probability": 0.4420166015625}, {"start": 1516.67, "end": 1516.89, "word": " فيه", "probability": 0.73388671875}, {"start": 1516.89, "end": 1518.03, "word": " isobutanol", "probability": 0.767822265625}, {"start": 1518.03, "end": 1518.17, "word": " و", "probability": 0.84619140625}, {"start": 1518.17, "end": 1519.41, "word": " tertiarybutanol", "probability": 0.809375}, {"start": 1519.41, "end": 1519.65, "word": " كل", "probability": 0.50048828125}, {"start": 1519.65, "end": 1520.03, "word": " هدول", "probability": 0.8898111979166666}, {"start": 1520.03, "end": 1521.63, "word": " الأشياء", "probability": 0.826171875}, {"start": 1521.63, "end": 1522.49, "word": " لازم", "probability": 0.9744466145833334}, {"start": 1522.49, "end": 1522.79, "word": " تكونوا", "probability": 0.9860026041666666}, {"start": 1522.79, "end": 1523.35, "word": " عارفينها", "probability": 0.98916015625}, {"start": 1523.35, "end": 1524.15, "word": " الان", "probability": 0.461181640625}, {"start": 1524.15, "end": 1524.41, "word": " ال", "probability": 0.96435546875}, {"start": 1524.41, "end": 1525.33, "word": " aldehydes", "probability": 0.68634033203125}, {"start": 1525.33, "end": 1525.57, "word": " اللي", "probability": 0.85205078125}, {"start": 1525.57, "end": 1525.95, "word": " جابنا", "probability": 0.9236653645833334}, {"start": 1525.95, "end": 1527.13, "word": " للكلام", "probability": 0.9176432291666666}, {"start": 1527.13, "end": 1527.47, "word": " ال", "probability": 0.716796875}, {"start": 1527.47, "end": 1528.63, "word": " aldehydes", "probability": 0.92431640625}, {"start": 1528.63, "end": 1529.25, "word": " لأ", "probability": 0.88134765625}, {"start": 1529.25, "end": 1529.69, "word": " مافيش", "probability": 0.8953450520833334}, {"start": 1529.69, "end": 1529.93, "word": " منها", "probability": 0.813232421875}, {"start": 1529.93, "end": 1530.21, "word": " واحد", "probability": 0.9638671875}, {"start": 1530.21, "end": 1530.37, "word": " و", "probability": 0.9130859375}, {"start": 1530.37, "end": 1530.75, "word": " اتنين", "probability": 0.8775634765625}, {"start": 1530.75, "end": 1531.27, "word": " لأن", "probability": 0.87890625}, {"start": 1531.27, "end": 1532.03, "word": " مجموعة", "probability": 0.9453125}, {"start": 1532.03, "end": 1532.19, "word": " ال", "probability": 0.955078125}, {"start": 1532.19, "end": 1532.77, "word": " aldehydes", "probability": 0.8629150390625}, {"start": 1532.77, "end": 1532.95, "word": " لا", "probability": 0.53271484375}, {"start": 1532.95, "end": 1533.31, "word": " تكون", "probability": 0.94140625}, {"start": 1533.31, "end": 1533.49, "word": " الا", "probability": 0.541015625}, {"start": 1533.49, "end": 1533.73, "word": " على", "probability": 0.79931640625}, {"start": 1533.73, "end": 1534.07, "word": " نمرة", "probability": 0.7958984375}, {"start": 1534.07, "end": 1534.75, "word": " واحد", "probability": 0.9853515625}, {"start": 1534.75, "end": 1536.17, "word": " و", "probability": 0.489013671875}, {"start": 1536.17, "end": 1536.59, "word": " لانها", "probability": 0.6829427083333334}, {"start": 1536.59, "end": 1536.73, "word": " لا", "probability": 0.84228515625}, {"start": 1536.73, "end": 1537.17, "word": " تكون", "probability": 0.978271484375}, {"start": 1537.17, "end": 1537.39, "word": " الا", "probability": 0.90185546875}, {"start": 1537.39, "end": 1537.63, "word": " على", "probability": 0.82666015625}, {"start": 1537.63, "end": 1537.93, "word": " نمرة", "probability": 0.9309895833333334}, {"start": 1537.93, "end": 1538.31, "word": " واحد", "probability": 0.990478515625}, {"start": 1538.31, "end": 1538.73, "word": " بنحط", "probability": 0.8875325520833334}, {"start": 1538.73, "end": 1538.89, "word": " ال", "probability": 0.943359375}, {"start": 1538.89, "end": 1539.09, "word": " hash", "probability": 0.6455078125}, {"start": 1539.09, "end": 1539.59, "word": " رقم", "probability": 0.9597981770833334}], "temperature": 1.0}, {"id": 67, "seek": 156937, "start": 1540.35, "end": 1569.37, "text": "يعني ما إجيناش كتبنا إيثان وان قالب روبان وان قالب يوتان وان قالب لأنها لا تكون إلا على واحد فالاشي اللي معروف ضلنا بلزم نكتبه واضح؟ ومثل ال الديهايد بالمناسبة اللي ما بيكونش إلا على نمرة واحد وفقط على واحد ال acid الحامض الحامض ما بيكون إلا على الطرف", "tokens": [40228, 22653, 19446, 11933, 7435, 1829, 8315, 8592, 9122, 2655, 3555, 8315, 11933, 1829, 12984, 7649, 4032, 7649, 12174, 6027, 3555, 12602, 37746, 7649, 4032, 7649, 12174, 6027, 3555, 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"word": " الكهول", "probability": 0.826171875}, {"start": 2160.3, "end": 2161.64, "word": " وعشان", "probability": 0.82305908203125}, {"start": 2161.64, "end": 2162.26, "word": " هيصير", "probability": 0.6830240885416666}, {"start": 2162.26, "end": 2163.14, "word": " two", "probability": 0.5869140625}, {"start": 2163.14, "end": 2164.32, "word": "-hydroxy", "probability": 0.7882080078125}, {"start": 2164.32, "end": 2168.22, "word": " benzaldehyde", "probability": 0.9330078125}, {"start": 2168.22, "end": 2168.42, "word": " شوف", "probability": 0.45672607421875}, {"start": 2168.42, "end": 2168.78, "word": " الحرف", "probability": 0.767333984375}, {"start": 2168.78, "end": 2168.94, "word": " ال", "probability": 0.78515625}, {"start": 2168.94, "end": 2169.14, "word": " بيه", "probability": 0.7451171875}, {"start": 2169.14, "end": 2169.54, "word": " رايح", "probability": 0.9637044270833334}], "temperature": 1.0}, {"id": 92, "seek": 219354, "start": 2172.86, "end": 2193.54, "text": "2-hydroxybenzaldehyde اللي هو اسمه salicyldehyde يمكن مار عليك انتوا salicylic acid لما تكون هذه OH و هذا acid لو كان الديهايد salicyldehyde مثلا هذا المركب في الديهايد و OH او مثل من اعلى واحدة ال الديهايد اذا مركبي كله هذا اسمه", "tokens": [17, 12, 21591, 340, 12876, 1799, 89, 304, 1479, 3495, 1479, 13672, 1829, 31439, 24525, 2304, 3224, 1845, 2632, 348, 68, 3495, 1479, 7251, 43020, 3714, 9640, 25894, 4117, 16472, 2655, 14407, 1845, 2632, 1050, 8258, 5296, 15042, 6055, 30544, 29538, 13931, 4032, 23758, 8258, 45164, 25961, 2423, 16254, 11296, 25708, 1845, 2632, 348, 68, 3495, 1479, 50113, 15040, 23758, 9673, 31747, 3555, 8978, 2423, 16254, 11296, 25708, 4032, 13931, 1975, 2407, 50113, 1211, 9154, 1975, 3615, 23942, 36764, 24401, 3660, 2423, 2423, 16254, 11296, 25708, 1975, 15730, 3714, 31747, 21292, 28242, 3224, 23758, 24525, 2304, 3224], "avg_logprob": -0.3147321413366162, "compression_ratio": 1.7676767676767677, "no_speech_prob": 0.0, "words": [{"start": 2172.8600000000006, "end": 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الالديهايد أو الكيتون على حلقة لاحظوا معي بدي أخد دراسة مقارنة للثلاثة كحول", "tokens": [6027, 5172, 7649, 1829, 15040, 37495, 22653, 27188, 7649, 1829, 15040, 39896, 8717, 36178, 2423, 32277, 2304, 6055, 3555, 3615, 11296, 1017, 12, 21591, 340, 12876, 12, 18, 12, 76, 3293, 5230, 88, 12, 1799, 89, 304, 1479, 3495, 1479, 6024, 48506, 5551, 34740, 13412, 17082, 37977, 4724, 16254, 5551, 5016, 4117, 1829, 11296, 45164, 35186, 6055, 2288, 7578, 11933, 7435, 995, 33251, 5016, 12610, 34051, 2423, 6027, 16254, 11296, 25708, 34051, 33251, 36081, 11536, 15844, 11331, 1211, 28671, 20193, 5016, 19913, 14407, 20449, 1829, 4724, 16254, 5551, 9778, 3215, 11778, 23557, 3794, 3660, 3714, 4587, 9640, 1863, 3660, 24976, 12984, 1211, 5718, 104, 3660, 9122, 5016, 12610], "avg_logprob": -0.22233370903435104, "compression_ratio": 1.6183574879227054, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2224.19, "end": 2224.95, "word": "الفانيلا", "probability": 0.695703125}, {"start": 2224.95, "end": 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236698, "start": 2353.23, "end": 2366.99, "text": "بنتان وبنحطله نهاية ال ketone بنتانون وخلصنا هذا لما بدي اسميه .. لأ بسميهوش cycle بالتنال", "tokens": [3555, 29399, 7649, 46599, 1863, 5016, 9566, 43761, 8717, 11296, 10632, 2423, 14979, 546, 4724, 29399, 7649, 11536, 4032, 9778, 1211, 9381, 8315, 23758, 5296, 15042, 4724, 16254, 24525, 2304, 1829, 3224, 4386, 5296, 10721, 4724, 38251, 1829, 3224, 2407, 8592, 6586, 20666, 2655, 1863, 6027], "avg_logprob": -0.3500664842889664, "compression_ratio": 1.2991452991452992, "no_speech_prob": 0.0, "words": [{"start": 2353.23, "end": 2354.57, "word": "بنتان", "probability": 0.8035481770833334}, {"start": 2354.57, "end": 2356.05, "word": " وبنحطله", "probability": 0.631201171875}, {"start": 2356.05, "end": 2356.47, "word": " نهاية", "probability": 0.9469401041666666}, {"start": 2356.47, "end": 2356.67, "word": " ال", "probability": 0.8837890625}, {"start": 2356.67, "end": 2357.23, "word": " ketone", "probability": 0.6370849609375}, {"start": 2357.23, "end": 2358.53, "word": " بنتانون", "probability": 0.783721923828125}, {"start": 2358.53, "end": 2360.07, "word": " وخلصنا", "probability": 0.91884765625}, {"start": 2360.07, "end": 2361.17, "word": " هذا", "probability": 0.7060546875}, {"start": 2361.17, "end": 2361.41, "word": " لما", "probability": 0.920654296875}, {"start": 2361.41, "end": 2361.73, "word": " بدي", "probability": 0.6876220703125}, {"start": 2361.73, "end": 2363.25, "word": " اسميه", "probability": 0.774658203125}, {"start": 2363.25, "end": 2364.21, "word": " ..", "probability": 0.3115234375}, {"start": 2364.21, "end": 2364.81, "word": " لأ", "probability": 0.833251953125}, {"start": 2364.81, "end": 2365.89, "word": " بسميهوش", "probability": 0.6991373697916666}, {"start": 2365.89, "end": 2366.23, "word": " cycle", "probability": 0.1968994140625}, {"start": 2366.23, "end": 2366.99, "word": " بالتنال", "probability": 0.7021484375}], "temperature": 1.0}, {"id": 100, "seek": 239091, "start": 2368.17, "end": 2390.91, "text": "ليش؟ لأنه إجي عليه مجموعة كاملة خارجية، إجي عليه كمان carbon، C double bond OH، بنسميه Cyclopenten-carb-aldehyde لأنه إجت carbon زيادة عن اللي جابله، ولذلك هذا إيش بده يتسمى؟ Cyclopenten-carb-aldehyde", "tokens": [20292, 8592, 22807, 5296, 33456, 3224, 11933, 7435, 1829, 47356, 3714, 7435, 2304, 2407, 27884, 9122, 10943, 37977, 16490, 9640, 7435, 10632, 12399, 11933, 7435, 1829, 47356, 9122, 2304, 7649, 5954, 12399, 383, 3834, 6086, 13931, 12399, 44945, 38251, 1829, 3224, 10295, 3474, 404, 317, 268, 12, 6166, 65, 12, 304, 1479, 3495, 1479, 5296, 33456, 3224, 11933, 7435, 2655, 5954, 30767, 1829, 18513, 3660, 18871, 13672, 1829, 10874, 16758, 43761, 12399, 35525, 8848, 23275, 23758, 11933, 1829, 8592, 47525, 3224, 7251, 2655, 38251, 7578, 22807, 49173, 404, 317, 268, 12, 6166, 65, 12, 304, 1479, 3495, 1479], "avg_logprob": -0.21227904612367804, "compression_ratio": 1.5416666666666667, "no_speech_prob": 0.0, "words": [{"start": 2368.17, "end": 2368.91, "word": "ليش؟", "probability": 0.7708333333333334}, {"start": 2368.91, "end": 2369.35, "word": " لأنه", "probability": 0.8404947916666666}, {"start": 2369.35, "end": 2370.07, "word": " إجي", "probability": 0.5015462239583334}, {"start": 2370.07, "end": 2370.33, "word": " عليه", "probability": 0.93017578125}, {"start": 2370.33, "end": 2370.91, "word": " مجموعة", "probability": 0.95}, {"start": 2370.91, "end": 2371.45, "word": " كاملة", "probability": 0.99169921875}, {"start": 2371.45, "end": 2372.19, "word": " خارجية،", "probability": 0.859765625}, {"start": 2372.19, "end": 2372.37, "word": " إجي", "probability": 0.8707682291666666}, {"start": 2372.37, "end": 2372.57, "word": " عليه", "probability": 0.99169921875}, {"start": 2372.57, "end": 2372.93, "word": " كمان", "probability": 0.9944661458333334}, {"start": 2372.93, "end": 2373.55, "word": " carbon،", "probability": 0.67822265625}, {"start": 2373.55, "end": 2373.69, "word": " C", "probability": 0.419677734375}, {"start": 2373.69, "end": 2373.89, "word": " double", "probability": 0.5537109375}, {"start": 2373.89, "end": 2374.13, "word": " bond", "probability": 0.82861328125}, {"start": 2374.13, "end": 2374.67, "word": " OH،", "probability": 0.60791015625}, {"start": 2374.67, "end": 2375.81, "word": " بنسميه", "probability": 0.968994140625}, {"start": 2375.81, "end": 2377.51, "word": " Cyclopenten", "probability": 0.5794921875}, {"start": 2377.51, "end": 2378.41, "word": "-carb", "probability": 0.5738118489583334}, {"start": 2378.41, "end": 2379.35, "word": "-aldehyde", "probability": 0.8953125}, {"start": 2379.35, "end": 2380.07, "word": " لأنه", "probability": 0.7151692708333334}, {"start": 2380.07, "end": 2380.53, "word": " إجت", "probability": 0.91357421875}, {"start": 2380.53, "end": 2381.03, "word": " carbon", "probability": 0.83447265625}, {"start": 2381.03, "end": 2381.51, "word": " زيادة", "probability": 0.8902587890625}, {"start": 2381.51, "end": 2381.69, "word": " عن", "probability": 0.94580078125}, {"start": 2381.69, 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خلال ذرة كربون ولذلك بنسميه Cyclopentane Carbaldehyde شفتوا الفرق بين الكحول والكيتون والالديهايد لو يجي على حلقة؟", "tokens": [2304, 15040, 5016, 19913, 9957, 27188, 2288, 4587, 49374, 16095, 22807, 14739, 3224, 41850, 3714, 16758, 28543, 2288, 8592, 5551, 8592, 3555, 4117, 5551, 4117, 3794, 29245, 9957, 2423, 6027, 16254, 11296, 25708, 3714, 3555, 33599, 25720, 20666, 5016, 1211, 28671, 11933, 15040, 9154, 16490, 1211, 6027, 29910, 25720, 9122, 25513, 11536, 35525, 8848, 23275, 44945, 38251, 1829, 3224, 10295, 3474, 404, 317, 1929, 2741, 2645, 1479, 3495, 1479, 13412, 5172, 2655, 14407, 27188, 2288, 4587, 49374, 33251, 5016, 12610, 16070, 4117, 36081, 11536, 16070, 6027, 16254, 11296, 25708, 45164, 7251, 7435, 1829, 15844, 11331, 1211, 28671, 22807], "avg_logprob": -0.22253788330338217, "compression_ratio": 1.6715686274509804, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2393.82, "end": 2394.4, "word": "ملاحظين", "probability": 0.8228515625}, {"start": 2394.4, "end": 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2401.32, "end": 2401.62, "word": " خلال", "probability": 0.9930013020833334}, {"start": 2401.62, "end": 2401.92, "word": " ذرة", "probability": 0.808837890625}, {"start": 2401.92, "end": 2402.56, "word": " كربون", "probability": 0.9208984375}, {"start": 2402.56, "end": 2403.48, "word": " ولذلك", "probability": 0.7819010416666666}, {"start": 2403.48, "end": 2403.98, "word": " بنسميه", "probability": 0.9423828125}, {"start": 2403.98, "end": 2404.86, "word": " Cyclopentane", "probability": 0.6794189453125}, {"start": 2404.86, "end": 2406.38, "word": " Carbaldehyde", "probability": 0.76806640625}, {"start": 2406.38, "end": 2407.32, "word": " شفتوا", "probability": 0.71234130859375}, {"start": 2407.32, "end": 2407.62, "word": " الفرق", "probability": 0.99169921875}, {"start": 2407.62, "end": 2407.82, "word": " بين", "probability": 0.97998046875}, {"start": 2407.82, "end": 2408.48, "word": " الكحول", "probability": 0.9943033854166666}, {"start": 2408.48, "end": 2409.52, "word": " والكيتون", 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2431.27, "end": 2432.07, "word": " aldehyde", "probability": 0.7794189453125}, {"start": 2432.07, "end": 2434.53, "word": " ال", "probability": 0.95947265625}, {"start": 2434.53, "end": 2434.95, "word": " acid", "probability": 0.986328125}, {"start": 2434.95, "end": 2435.17, "word": " لو", "probability": 0.9921875}, {"start": 2435.17, "end": 2435.39, "word": " بده", "probability": 0.966796875}, {"start": 2435.39, "end": 2435.55, "word": " ييجي", "probability": 0.908203125}, {"start": 2435.55, "end": 2435.67, "word": " على", "probability": 0.8935546875}, {"start": 2435.67, "end": 2436.01, "word": " الحلقة", "probability": 0.9874674479166666}, {"start": 2436.01, "end": 2436.23, "word": " بده", "probability": 0.9013671875}, {"start": 2436.23, "end": 2436.37, "word": " ييجي", "probability": 0.947998046875}, {"start": 2436.37, "end": 2436.67, "word": " كله", "probability": 0.856201171875}, {"start": 2436.67, "end": 2437.15, "word": " معلج", "probability": 0.8224283854166666}, {"start": 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Carboxylic acid كمان Carboxylic acid", "tokens": [15042, 28543, 2288, 8592, 5551, 5016, 9566, 3224, 15844, 8717, 36178, 21542, 1211, 28671, 16247, 4117, 3794, 7435, 9957, 3660, 9673, 2655, 36520, 3660, 35525, 8848, 23275, 5296, 15042, 4724, 16254, 5551, 38251, 1829, 3224, 4724, 16254, 5551, 38251, 1829, 3224, 4724, 8592, 28820, 3714, 2407, 31377, 1863, 5296, 1863, 19913, 10943, 2423, 2423, 16254, 11296, 25708, 11933, 1829, 8592, 49610, 3215, 2655, 11331, 26108, 3660, 5551, 39648, 18871, 3224, 22807, 10295, 66, 752, 4386, 4724, 29399, 9957, 4386, 2741, 4995, 88, 1050, 8258, 9122, 2304, 7649, 2741, 4995, 88, 1050, 8258], "avg_logprob": -0.23655914234858688, "compression_ratio": 1.5336787564766838, "no_speech_prob": 0.0, "words": [{"start": 2442.74, "end": 2443.26, "word": "ماقدرش", "probability": 0.74261474609375}, {"start": 2443.26, "end": 2443.6, "word": " أحطه", "probability": 0.8751220703125}, {"start": 2443.6, "end": 2443.74, "word": " على", "probability": 0.822265625}, {"start": 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\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..4c342af0b63b9b65c1322fa5acc09dd6d0cbd7da
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/hQvSO3g5Za4_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3925, "start": 19.49, "end": 39.25, "text": "بسم الله الرحمن الرحيم المرة الماضية بدينا في موضوع ال carbohydrates بدينا في موضوع ال carbohydrates وقولنا انه امكوانين من carbon و ما .. و بعدين طبعا بدينا في ال sugars", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 1829, 8315, 8978, 3714, 2407, 11242, 45367, 2423, 36817, 47525, 1829, 8315, 8978, 3714, 2407, 11242, 45367, 2423, 36817, 4032, 39648, 8315, 16472, 3224, 1975, 2304, 4117, 2407, 7649, 9957, 9154, 5954, 4032, 19446, 4386, 4032, 39182, 9957, 23032, 3555, 3615, 995, 47525, 1829, 8315, 8978, 2423, 37551], "avg_logprob": -0.14636230375617743, "compression_ratio": 1.8243243243243243, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 19.49, "end": 19.83, "word": "بسم", "probability": 0.929931640625}, {"start": 19.83, "end": 19.97, "word": " الله", "probability": 0.9697265625}, {"start": 19.97, "end": 20.31, "word": " الرحمن", 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68.67, "word": " dihyde", "probability": 0.6520182291666666}, {"start": 68.67, "end": 69.47, "word": " و", "probability": 0.947265625}, {"start": 69.47, "end": 70.33, "word": " رسمنا", "probability": 0.97216796875}, {"start": 70.33, "end": 71.69, "word": " بطرق", "probability": 0.8839111328125}, {"start": 71.69, "end": 72.81, "word": " مختلفة", "probability": 0.9954833984375}, {"start": 72.81, "end": 74.75, "word": " شوفنا", "probability": 0.8487955729166666}, {"start": 74.75, "end": 75.15, "word": " كيف", "probability": 0.982666015625}, {"start": 75.15, "end": 76.91, "word": " المركبات", "probability": 0.9114990234375}, {"start": 76.91, "end": 77.31, "word": " هذه", "probability": 0.7509765625}, {"start": 77.31, "end": 78.17, "word": " ممكن", "probability": 0.9921875}, {"start": 78.17, "end": 78.75, "word": " تكون", "probability": 0.98974609375}], "temperature": 1.0}, {"id": 4, "seek": 10614, "start": 79.34, "end": 106.14, "text": "D أو L في المرحلة الأولى و لو قلنا لو عندنا one chiral center بيصير في عندنا مركبين بعد هيك قصة ال D و L بتستمر بزيادة ال chiral center و بيبدأ العدد يزيد فبناء على ذلك بناء على ذلك فبموضوع ال sugars", "tokens": [35, 34051, 441, 8978, 9673, 2288, 5016, 37977, 16247, 12610, 7578, 4032, 45164, 12174, 1211, 8315, 45164, 43242, 8315, 472, 23782, 304, 3056, 4724, 1829, 9381, 13546, 8978, 43242, 8315, 3714, 31747, 3555, 9957, 39182, 39896, 4117, 12174, 9381, 3660, 2423, 413, 4032, 441, 39894, 14851, 29973, 4724, 11622, 1829, 18513, 3660, 2423, 23782, 304, 3056, 4032, 4724, 1829, 44510, 10721, 18863, 3215, 3215, 7251, 11622, 25708, 6156, 3555, 1863, 16606, 15844, 29910, 23275, 44945, 16606, 15844, 29910, 23275, 6156, 3555, 2304, 2407, 11242, 45367, 2423, 37551], "avg_logprob": -0.24751421639865095, "compression_ratio": 1.6789473684210525, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 79.34, "end": 79.84, "word": "D", "probability": 0.477294921875}, {"start": 79.84, "end": 80.94, "word": " أو", "probability": 0.51220703125}, 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"probability": 0.77471923828125}, {"start": 86.18, "end": 86.28, "word": " في", "probability": 0.626953125}, {"start": 86.28, "end": 86.72, "word": " عندنا", "probability": 0.89697265625}, {"start": 86.72, "end": 87.84, "word": " مركبين", "probability": 0.9237060546875}, {"start": 87.84, "end": 88.84, "word": " بعد", "probability": 0.69775390625}, {"start": 88.84, "end": 89.26, "word": " هيك", "probability": 0.52447509765625}, {"start": 89.26, "end": 89.84, "word": " قصة", "probability": 0.9856770833333334}, {"start": 89.84, "end": 89.98, "word": " ال", "probability": 0.6884765625}, {"start": 89.98, "end": 90.08, "word": " D", "probability": 0.791015625}, {"start": 90.08, "end": 90.24, "word": " و", "probability": 0.60986328125}, {"start": 90.24, "end": 90.54, "word": " L", "probability": 0.53076171875}, {"start": 90.54, "end": 91.32, "word": " بتستمر", "probability": 0.88671875}, {"start": 91.32, "end": 92.0, "word": " بزيادة", "probability": 0.98251953125}, {"start": 92.0, "end": 92.18, "word": " ال", "probability": 0.703125}, {"start": 92.18, "end": 92.6, "word": " chiral", "probability": 0.87646484375}, {"start": 92.6, "end": 92.92, "word": " center", "probability": 0.8828125}, {"start": 92.92, "end": 93.08, "word": " و", "probability": 0.7763671875}, {"start": 93.08, "end": 93.38, "word": " بيبدأ", "probability": 0.75927734375}, {"start": 93.38, "end": 93.94, "word": " العدد", "probability": 0.9720052083333334}, {"start": 93.94, "end": 94.58, "word": " يزيد", "probability": 0.9884440104166666}, {"start": 94.58, "end": 95.44, "word": " فبناء", "probability": 0.9019775390625}, {"start": 95.44, "end": 95.74, "word": " على", "probability": 0.8994140625}, {"start": 95.74, "end": 96.34, "word": " ذلك", "probability": 0.991455078125}, {"start": 96.34, "end": 96.9, "word": " بناء", "probability": 0.680419921875}, {"start": 96.9, "end": 97.18, "word": " على", "probability": 0.95556640625}, {"start": 97.18, "end": 99.66, "word": " ذلك", "probability": 0.99267578125}, 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"end": 163.83, "word": " center", "probability": 0.93896484375}, {"start": 163.83, "end": 164.67, "word": " أربعة", "probability": 0.7657877604166666}, {"start": 164.67, "end": 165.25, "word": " بيقدروا", "probability": 0.7392578125}, {"start": 165.25, "end": 165.51, "word": " إلى", "probability": 0.7109375}], "temperature": 1.0}, {"id": 7, "seek": 18134, "start": 167.44, "end": 181.34, "text": "الان طالما ان السكر عبارة عن الكهول و الديهايد لو جربنا نجعل الكهول يسكر على الديهايد هيعمل a new chiral center هيصير اندفع", "tokens": [6027, 7649, 23032, 6027, 15042, 16472, 21136, 37983, 6225, 3555, 9640, 3660, 18871, 33251, 3224, 12610, 4032, 2423, 16254, 11296, 25708, 45164, 10874, 25513, 8315, 8717, 7435, 30241, 33251, 3224, 12610, 7251, 3794, 37983, 15844, 2423, 16254, 11296, 25708, 8032, 1829, 25957, 1211, 257, 777, 23782, 304, 3056, 8032, 1829, 9381, 13546, 16472, 3215, 5172, 3615], "avg_logprob": -0.3034539390028569, "compression_ratio": 1.5407407407407407, "no_speech_prob": 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"text": "خمسة كايرال سنترز وجدت بنتوقع انه لسكر مكون من ست ذرات كربون بهذا الشكل يكون عنده اتنين و تلاتين ايزومات طبعا لما تمت عملية الاغلاق لما تمت عملية اغلاق الالكول على ال الديهايد", "tokens": [9778, 2304, 3794, 3660, 9122, 995, 13546, 6027, 8608, 29399, 2288, 11622, 49610, 3215, 2655, 4724, 29399, 30543, 3615, 16472, 3224, 5296, 3794, 37983, 3714, 4117, 2407, 1863, 9154, 8608, 2655, 29910, 2288, 9307, 9122, 25513, 11536, 39627, 15730, 25124, 28820, 7251, 30544, 43242, 3224, 1975, 2655, 1863, 9957, 4032, 6055, 1211, 9307, 9957, 1975, 1829, 11622, 20498, 9307, 23032, 3555, 3615, 995, 5296, 15042, 46811, 2655, 6225, 42213, 10632, 2423, 5718, 118, 15040, 4587, 5296, 15042, 46811, 2655, 6225, 42213, 10632, 1975, 17082, 15040, 4587, 2423, 6027, 4117, 12610, 15844, 2423, 2423, 16254, 11296, 25708], "avg_logprob": -0.2453286033315757, "compression_ratio": 1.8705882352941177, "no_speech_prob": 0.0, "words": [{"start": 181.62, "end": 182.26, "word": "خمسة", "probability": 0.8182373046875}, 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"end": 189.46, "word": " الشكل", "probability": 0.9921875}, {"start": 189.46, "end": 190.14, "word": " يكون", "probability": 0.9326171875}, {"start": 190.14, "end": 190.82, "word": " عنده", "probability": 0.904541015625}, {"start": 190.82, "end": 191.36, "word": " اتنين", "probability": 0.86572265625}, {"start": 191.36, "end": 191.46, "word": " و", "probability": 0.736328125}, {"start": 191.46, "end": 192.14, "word": " تلاتين", "probability": 0.947265625}, {"start": 192.14, "end": 193.36, "word": " ايزومات", "probability": 0.68916015625}, {"start": 193.36, "end": 194.16, "word": " طبعا", "probability": 0.9464111328125}, {"start": 194.16, "end": 194.62, "word": " لما", "probability": 0.879638671875}, {"start": 194.62, "end": 195.08, "word": " تمت", "probability": 0.983154296875}, {"start": 195.08, "end": 195.6, "word": " عملية", "probability": 0.986328125}, {"start": 195.6, "end": 196.48, "word": " الاغلاق", "probability": 0.781884765625}, {"start": 196.48, "end": 196.9, "word": " لما", "probability": 0.73291015625}, {"start": 196.9, "end": 197.32, "word": " تمت", "probability": 0.983154296875}, {"start": 197.32, "end": 197.76, "word": " عملية", "probability": 0.9754231770833334}, {"start": 197.76, "end": 198.3, "word": " اغلاق", "probability": 0.984130859375}, {"start": 198.3, "end": 199.2, "word": " الالكول", "probability": 0.7208251953125}, {"start": 199.2, "end": 200.24, "word": " على", "probability": 0.86669921875}, {"start": 200.24, "end": 200.58, "word": " ال", "probability": 0.9501953125}, {"start": 200.58, "end": 201.54, "word": " الديهايد", "probability": 0.703857421875}], "temperature": 1.0}, {"id": 9, "seek": 21844, "start": 201.96, "end": 218.44, "text": "بهذا الشكل اتكون عندى هنا ال new chiral center وقولنا الكاربون هذه اللى بتعمل ال new chiral center شو بنسميها احنا انوميرك كاربون الان معنى new chiral center ان هو ال OH هذى بنسميها اما لأعلى", "tokens": [3555, 3224, 15730, 25124, 28820, 1975, 2655, 30544, 43242, 7578, 34105, 2423, 777, 23782, 304, 3056, 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210.74, "end": 210.92, "word": " شو", "probability": 0.7998046875}, {"start": 210.92, "end": 211.4, "word": " بنسميها", "probability": 0.918701171875}, {"start": 211.4, "end": 211.7, "word": " احنا", "probability": 0.9602864583333334}, {"start": 211.7, "end": 212.84, "word": " انوميرك", "probability": 0.6132965087890625}, {"start": 212.84, "end": 213.32, "word": " كاربون", "probability": 0.9700927734375}, {"start": 213.32, "end": 214.14, "word": " الان", "probability": 0.6695556640625}, {"start": 214.14, "end": 214.8, "word": " معنى", "probability": 0.8631184895833334}, {"start": 214.8, "end": 214.98, "word": " new", "probability": 0.705078125}, {"start": 214.98, "end": 215.46, "word": " chiral", "probability": 0.974365234375}, {"start": 215.46, "end": 215.78, "word": " center", "probability": 0.92236328125}, {"start": 215.78, "end": 215.96, "word": " ان", "probability": 0.280517578125}, {"start": 215.96, "end": 216.08, "word": " هو", "probability": 0.52587890625}, {"start": 216.08, 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الشكل على هيئة الكرسي بتكون موجودة وين؟ في ال axial ولا في ال equatorial؟ في ال equatorial ال equatorial is not a sterically hindered molecule", "tokens": [2407, 46958, 5016, 6156, 35457, 3555, 6024, 104, 3555, 9307, 5296, 2423, 9861, 16472, 2423, 13931, 25724, 16254, 41891, 29538, 13672, 1829, 1975, 2655, 30544, 2655, 43242, 1829, 34105, 45164, 12602, 38251, 2655, 25124, 28820, 15844, 39896, 19986, 3660, 33251, 2288, 3794, 1829, 39894, 30544, 3714, 29245, 23328, 3660, 4032, 9957, 22807, 8978, 2423, 46851, 49429, 8978, 2423, 45544, 831, 22807, 8978, 2423, 45544, 831, 2423, 45544, 831, 307, 406, 257, 18924, 984, 20138, 4073, 15582], "avg_logprob": -0.24411525509574197, "compression_ratio": 1.5804878048780489, "no_speech_prob": 0.0, "words": [{"start": 737.87, "end": 738.41, "word": "واضح", "probability": 0.958984375}, {"start": 738.41, "end": 739.57, "word": " فسبب", "probability": 0.783935546875}, {"start": 739.57, "end": 740.39, "word": " الثبات", "probability": 0.9559326171875}, 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مشكلة", "probability": 0.9752604166666666}], "temperature": 1.0}, {"id": 59, "seek": 137684, "start": 1361.2, "end": 1376.84, "text": "فتفاعل الكحول مع أي واحد من الأحماض ومشتقاتها بيعطيني إيه؟ Easter كحول مع أسد، كحول مع أسد كلورايت، كحول مع أنهايدرايت، كحول مع Easter، يمكن أنا تقوله يا الله Easter أعطى", "tokens": [5172, 2655, 5172, 995, 30241, 33251, 5016, 12610, 20449, 36632, 36764, 24401, 9154, 16247, 35571, 46958, 4032, 2304, 8592, 2655, 4587, 9307, 11296, 4724, 40228, 9566, 1829, 22653, 11933, 1829, 3224, 22807, 9403, 9122, 5016, 12610, 20449, 5551, 3794, 3215, 12399, 9122, 5016, 12610, 20449, 5551, 3794, 3215, 9122, 1211, 13063, 995, 36081, 12399, 9122, 5016, 12610, 20449, 14739, 3224, 995, 25708, 23557, 36081, 12399, 9122, 5016, 12610, 20449, 9403, 12399, 7251, 43020, 41850, 6055, 39648, 3224, 35186, 21984, 9403, 5551, 3615, 9566, 7578], "avg_logprob": -0.24669117787305048, "compression_ratio": 1.8364779874213837, "no_speech_prob": 0.0, "words": [{"start": 1361.2, "end": 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"word": " ال", "probability": 0.841796875}, {"start": 2317.75, "end": 2318.37, "word": " OH", "probability": 0.857421875}, {"start": 2318.37, "end": 2319.33, "word": " صارت", "probability": 0.9659830729166666}, {"start": 2319.33, "end": 2320.51, "word": " OR", "probability": 0.89697265625}, {"start": 2320.51, "end": 2322.47, "word": " واضح؟", "probability": 0.8839111328125}], "temperature": 1.0}, {"id": 99, "seek": 233835, "start": 2322.89, "end": 2338.35, "text": "بدل ما كانت او متصلة ب اتش صارت او متصلة بار بنسميهم glycosides طبعا في أمثلة هتمروا معاكم بعدين في أماكن تانية أنه يا تورا لو حطينا هنا ال متصلة بار", "tokens": [44510, 1211, 19446, 25961, 2655, 1975, 2407, 44650, 36520, 3660, 4724, 1975, 2655, 8592, 20328, 9640, 2655, 1975, 2407, 44650, 36520, 3660, 4724, 9640, 44945, 38251, 1829, 16095, 22633, 6877, 1875, 23032, 3555, 3615, 995, 8978, 5551, 2304, 12984, 37977, 8032, 39237, 2288, 14407, 20449, 995, 24793, 39182, 9957, 8978, 5551, 15042, 19452, 6055, 7649, 10632, 14739, 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"word": " متصلة", "probability": 0.96484375}, {"start": 2327.53, "end": 2328.33, "word": " بار", "probability": 0.763671875}, {"start": 2328.33, "end": 2329.23, "word": " بنسميهم", "probability": 0.85064697265625}, {"start": 2329.23, "end": 2330.91, "word": " glycosides", "probability": 0.7841796875}, {"start": 2330.91, "end": 2331.67, "word": " طبعا", "probability": 0.9176025390625}, {"start": 2331.67, "end": 2331.93, "word": " في", "probability": 0.76611328125}, {"start": 2331.93, "end": 2332.39, "word": " أمثلة", "probability": 0.9005126953125}, {"start": 2332.39, "end": 2332.93, "word": " هتمروا", "probability": 0.687255859375}, {"start": 2332.93, "end": 2333.37, "word": " معاكم", "probability": 0.8138020833333334}, {"start": 2333.37, "end": 2333.87, "word": " بعدين", "probability": 0.7313232421875}, {"start": 2333.87, "end": 2333.97, "word": " في", "probability": 0.8916015625}, {"start": 2333.97, "end": 2334.37, "word": " أماكن", "probability": 0.9527994791666666}, {"start": 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غلايكو سايتس عادية معنى ذلك أنا بدي سكر و مرسوم عليه على هذا الموقع تحديدا OR لاحظوا أن التفاعل مع الميثانول ما بيغير هدول ال OHS", "tokens": [3555, 1863, 9381, 13546, 8717, 39648, 18871, 11296, 364, 38353, 6877, 1875, 37495, 22653, 32771, 15040, 1829, 4117, 2407, 8608, 995, 36081, 3794, 4724, 3794, 9154, 16490, 1211, 6027, 29910, 25720, 11933, 1829, 8592, 8717, 36081, 2288, 29245, 9957, 4724, 3794, 11933, 15730, 12174, 12610, 8315, 9122, 19528, 3660, 32771, 15040, 1829, 4117, 2407, 8608, 995, 36081, 3794, 6225, 18513, 10632, 20449, 1863, 7578, 29910, 23275, 41850, 4724, 16254, 8608, 37983, 4032, 3714, 2288, 3794, 20498, 47356, 15844, 23758, 9673, 30543, 3615, 6055, 5016, 16254, 28259, 19654, 20193, 5016, 19913, 14407, 14739, 16712, 5172, 995, 30241, 20449, 9673, 1829, 12984, 7649, 12610, 19446, 4724, 1829, 17082, 13546, 8032, 3215, 12610, 2423, 422, 12527], "avg_logprob": -0.19997259268635198, "compression_ratio": 1.6355932203389831, "no_speech_prob": 0.0, "words": [{"start": 2340.61, 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{"start": 2346.15, "end": 2347.27, "word": " نيتروجين", "probability": 0.778466796875}, {"start": 2347.27, "end": 2347.69, "word": " بس", "probability": 0.874267578125}, {"start": 2347.69, "end": 2347.87, "word": " إذا", "probability": 0.959228515625}, {"start": 2347.87, "end": 2348.17, "word": " قولنا", "probability": 0.8888346354166666}, {"start": 2348.17, "end": 2348.65, "word": " كلمة", "probability": 0.9856770833333334}, {"start": 2348.65, "end": 2349.43, "word": " غلايكو", "probability": 0.80009765625}, {"start": 2349.43, "end": 2349.85, "word": " سايتس", "probability": 0.9853515625}, {"start": 2349.85, "end": 2350.45, "word": " عادية", "probability": 0.9685872395833334}, {"start": 2350.45, "end": 2351.13, "word": " معنى", "probability": 0.751220703125}, {"start": 2351.13, "end": 2351.43, "word": " ذلك", "probability": 0.99365234375}, {"start": 2351.43, "end": 2351.79, "word": " أنا", "probability": 0.77783203125}, {"start": 2351.79, "end": 2352.45, "word": " بدي", "probability": 0.857421875}, {"start": 2352.45, "end": 2353.11, "word": " سكر", "probability": 0.888671875}, {"start": 2353.11, "end": 2353.49, "word": " و", "probability": 0.9580078125}, {"start": 2353.49, "end": 2353.91, "word": " مرسوم", "probability": 0.8681640625}, {"start": 2353.91, "end": 2354.21, "word": " عليه", "probability": 0.982421875}, {"start": 2354.21, "end": 2354.47, "word": " على", "probability": 0.927734375}, {"start": 2354.47, "end": 2354.79, "word": " هذا", "probability": 0.93994140625}, {"start": 2354.79, "end": 2355.23, "word": " الموقع", "probability": 0.9869791666666666}, {"start": 2355.23, "end": 2355.75, "word": " تحديدا", "probability": 0.8560791015625}, {"start": 2355.75, "end": 2356.13, "word": " OR", "probability": 0.72021484375}, {"start": 2356.13, "end": 2357.05, "word": " لاحظوا", "probability": 0.86614990234375}, {"start": 2357.05, "end": 2357.21, "word": " أن", "probability": 0.66162109375}, {"start": 2357.21, "end": 2357.75, "word": " التفاعل", "probability": 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بنسميها؟ Glycosidic bond موجودة ويلها أهمية جزء كبير من أهمية هذه المنطقة أنه لما بعدك السكريات بدهم يبدوا يعملوا dimers مع بعض يتحدوا هنلاحظ فائدة هذه ال glycosidic bond لأنه بربطوا من خلالها واضح؟ يربطوا مع بعض من خلالها", "tokens": [2304, 3615, 2423, 13931, 20328, 9640, 2655, 44650, 36520, 3660, 20449, 1975, 1829, 8592, 22807, 20449, 2423, 19654, 13412, 2407, 44945, 38251, 1829, 11296, 22807, 460, 356, 6877, 327, 299, 6086, 3714, 29245, 23328, 3660, 4032, 26895, 11296, 5551, 16095, 10632, 10874, 11622, 38207, 9122, 3555, 13546, 9154, 5551, 16095, 10632, 29538, 9673, 1863, 9566, 28671, 14739, 3224, 5296, 15042, 39182, 4117, 21136, 4117, 16572, 9307, 47525, 16095, 7251, 44510, 14407, 7251, 25957, 1211, 14407, 5013, 433, 20449, 45030, 11242, 7251, 2655, 24401, 14407, 8032, 1863, 15040, 5016, 19913, 6156, 16373, 41891, 29538, 2423, 22633, 6877, 327, 299, 6086, 5296, 33456, 3224, 4724, 25513, 9566, 14407, 9154, 16490, 1211, 6027, 11296, 4032, 46958, 5016, 22807, 7251, 25513, 9566, 14407, 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0.84521484375}, {"start": 2402.42, "end": 2403.08, "word": " المنطقة", "probability": 0.9910888671875}, {"start": 2403.08, "end": 2403.66, "word": " أنه", "probability": 0.7144775390625}, {"start": 2403.66, "end": 2403.84, "word": " لما", "probability": 0.9521484375}, {"start": 2403.84, "end": 2404.36, "word": " بعدك", "probability": 0.6796875}, {"start": 2404.36, "end": 2405.3, "word": " السكريات", "probability": 0.971923828125}, {"start": 2405.3, "end": 2405.78, "word": " بدهم", "probability": 0.616943359375}, {"start": 2405.78, "end": 2406.18, "word": " يبدوا", "probability": 0.7608235677083334}, {"start": 2406.18, "end": 2406.68, "word": " يعملوا", "probability": 0.9827880859375}, {"start": 2406.68, "end": 2407.4, "word": " dimers", "probability": 0.59307861328125}, {"start": 2407.4, "end": 2407.66, "word": " مع", "probability": 0.98095703125}, {"start": 2407.66, "end": 2408.02, "word": " بعض", "probability": 0.9990234375}, {"start": 2408.02, "end": 2408.7, "word": " يتحدوا", "probability": 0.9151611328125}, {"start": 2408.7, "end": 2409.54, "word": " هنلاحظ", "probability": 0.9154296875}, {"start": 2409.54, "end": 2410.14, "word": " فائدة", "probability": 0.9817708333333334}, {"start": 2410.14, "end": 2410.48, "word": " هذه", "probability": 0.3974609375}, {"start": 2410.48, "end": 2410.58, "word": " ال", "probability": 0.8076171875}, {"start": 2410.58, "end": 2411.42, "word": " glycosidic", "probability": 0.8731689453125}, {"start": 2411.42, "end": 2411.56, "word": " bond", "probability": 0.95166015625}, {"start": 2411.56, "end": 2411.88, "word": " لأنه", "probability": 0.8401692708333334}, {"start": 2411.88, "end": 2412.26, "word": " بربطوا", "probability": 0.8045654296875}, {"start": 2412.26, "end": 2412.42, "word": " من", "probability": 0.99560546875}, {"start": 2412.42, "end": 2413.02, "word": " خلالها", "probability": 0.9967041015625}, {"start": 2413.02, "end": 2414.08, "word": " واضح؟", "probability": 0.921142578125}, {"start": 2414.08, "end": 2414.52, "word": " يربطوا", "probability": 0.925537109375}, {"start": 2414.52, "end": 2414.62, "word": " مع", "probability": 0.99072265625}, {"start": 2414.62, "end": 2414.86, "word": " بعض", "probability": 0.998291015625}, {"start": 2414.86, "end": 2415.0, "word": " من", "probability": 0.998046875}, {"start": 2415.0, "end": 2415.44, "word": " خلالها", "probability": 0.9954833984375}], "temperature": 1.0}, {"id": 103, "seek": 243448, "start": 2417.16, "end": 2434.48, "text": "لو اجينا رسمنالكم مركب هذا sugar من الجولوكوز هل هذا يا تورا فيه glycosidic bond ولا لأ تطلع عليه هاي carbon او", "tokens": [1211, 2407, 1975, 7435, 1829, 8315, 12602, 38251, 8315, 23275, 2304, 3714, 31747, 3555, 23758, 5076, 9154, 25724, 12610, 2407, 4117, 2407, 11622, 8032, 1211, 23758, 35186, 6055, 13063, 995, 8978, 3224, 22633, 6877, 327, 299, 6086, 49429, 5296, 10721, 6055, 9566, 1211, 3615, 47356, 8032, 47302, 5954, 1975, 2407], "avg_logprob": -0.321997556031919, "compression_ratio": 1.2941176470588236, "no_speech_prob": 0.0, "words": [{"start": 2417.16, "end": 2417.62, "word": "لو", "probability": 0.91064453125}, {"start": 2417.62, "end": 2418.34, "word": " اجينا", "probability": 0.61627197265625}, {"start": 2418.34, "end": 2419.16, "word": " رسمنالكم", "probability": 0.8341796875}, {"start": 2419.16, "end": 2419.7, "word": " مركب", "probability": 0.73779296875}, {"start": 2419.7, "end": 2419.96, "word": " هذا", "probability": 0.4970703125}, {"start": 2419.96, "end": 2420.5, "word": " sugar", "probability": 0.52392578125}, {"start": 2420.5, "end": 2422.7, "word": " من", "probability": 0.97900390625}, {"start": 2422.7, "end": 2423.72, "word": " الجولوكوز", "probability": 0.8709309895833334}, {"start": 2423.72, "end": 2424.96, "word": " هل", "probability": 0.862548828125}, {"start": 2424.96, "end": 2425.18, "word": " هذا", "probability": 0.94482421875}, {"start": 2425.18, "end": 2425.34, "word": " يا", "probability": 0.2215576171875}, {"start": 2425.34, "end": 2425.84, "word": " تورا", 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الصفصاف لما كانوا بيغلو شجر الصفصاف بيطلع هذا المركب كانوا ياخدوله الصداع الناس الزمان فيه glycosidic bond لاحظوا اللى بتتأمل فيه بشكل بشكل قوى هتلاحظ ان هذا بيشبه ايش الاسميرين", "tokens": [24437, 4351, 1975, 15730, 23758, 9673, 31747, 3555, 13672, 7578, 24525, 2304, 3224, 8608, 6027, 1829, 3794, 9957, 9154, 13412, 7435, 2288, 31767, 5172, 9381, 31845, 5296, 15042, 25961, 14407, 4724, 1829, 17082, 1211, 2407, 13412, 7435, 2288, 31767, 5172, 9381, 31845, 4724, 1829, 9566, 1211, 3615, 23758, 9673, 31747, 3555, 25961, 14407, 7251, 47283, 3215, 12610, 3224, 31767, 28259, 3615, 2423, 8315, 3794, 6024, 110, 2304, 7649, 8978, 3224, 22633, 6877, 327, 299, 6086, 20193, 5016, 19913, 14407, 13672, 7578, 39894, 2655, 10721, 42213, 8978, 3224, 4724, 8592, 28820, 4724, 8592, 28820, 12174, 2407, 7578, 8032, 2655, 15040, 5016, 19913, 16472, 23758, 4724, 1829, 8592, 3555, 3224, 1975, 1829, 8592, 2423, 32277, 2304, 13546, 9957], "avg_logprob": -0.19070512616736257, "compression_ratio": 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"end": 2450.36, "word": " فيه", "probability": 0.747802734375}, {"start": 2450.36, "end": 2451.34, "word": " glycosidic", "probability": 0.8314208984375}, {"start": 2451.34, "end": 2451.62, "word": " bond", "probability": 0.9326171875}, {"start": 2451.62, "end": 2452.26, "word": " لاحظوا", "probability": 0.83056640625}, {"start": 2452.26, "end": 2452.44, "word": " اللى", "probability": 0.984375}, {"start": 2452.44, "end": 2453.12, "word": " بتتأمل", "probability": 0.93359375}, {"start": 2453.12, "end": 2453.38, "word": " فيه", "probability": 0.971435546875}, {"start": 2453.38, "end": 2453.98, "word": " بشكل", "probability": 0.9913736979166666}, {"start": 2453.98, "end": 2455.0, "word": " بشكل", "probability": 0.8483072916666666}, {"start": 2455.0, "end": 2455.98, "word": " قوى", "probability": 0.6215006510416666}, {"start": 2455.98, "end": 2457.48, "word": " هتلاحظ", "probability": 0.97373046875}, {"start": 2457.48, "end": 2457.6, "word": " ان", "probability": 0.60791015625}, {"start": 2457.6, "end": 2457.88, "word": " هذا", "probability": 0.603515625}, {"start": 2457.88, "end": 2458.46, "word": " بيشبه", "probability": 0.9447265625}, {"start": 2458.46, "end": 2458.9, "word": " ايش", "probability": 0.7821451822916666}, {"start": 2458.9, "end": 2462.04, "word": " الاسميرين", "probability": 0.613134765625}], "temperature": 1.0}, {"id": 105, "seek": 248723, "start": 2463.92, "end": 2487.24, "text": "تذكروا الاسبيرين كان بنزينة و COOH و CH2O و بعدين أوهانة OH نخليها OCOC double bond Oacetyl يعني وجود البنزينة و ال orthoposition هذا بشبه أي دوة؟ بشبه الاسبيرين هذا مثلا منتج طبيعي فيه glycosidic bond ولا لأ؟ هيها", "tokens": [2655, 8848, 37983, 14407, 2423, 32277, 3555, 13546, 9957, 25961, 44945, 11622, 9957, 3660, 4032, 3002, 31187, 4032, 5995, 17, 46, 4032, 39182, 9957, 34051, 3224, 7649, 3660, 13931, 8717, 9778, 20292, 11296, 422, 12322, 34, 3834, 6086, 422, 326, 2210, 75, 37495, 22653, 49610, 23328, 29739, 1863, 11622, 9957, 3660, 4032, 2423, 19052, 404, 5830, 23758, 4724, 8592, 3555, 3224, 36632, 11778, 2407, 3660, 22807, 4724, 8592, 3555, 3224, 2423, 32277, 3555, 13546, 9957, 23758, 50113, 15040, 9154, 2655, 7435, 23032, 21292, 3615, 1829, 8978, 3224, 22633, 6877, 327, 299, 6086, 49429, 5296, 10721, 22807, 39896, 11296], "avg_logprob": -0.24116161917195175, "compression_ratio": 1.5159817351598173, "no_speech_prob": 0.0, "words": [{"start": 2463.92, "end": 2464.6, "word": "تذكروا", "probability": 0.8316650390625}, {"start": 2464.6, "end": 2465.3, "word": " الاسبيرين", "probability": 0.765234375}, {"start": 2465.3, "end": 2465.58, "word": " كان", "probability": 0.91259765625}, {"start": 2465.58, "end": 2466.48, "word": " بنزينة", "probability": 0.8582763671875}, {"start": 2466.48, "end": 2466.74, "word": " و", "probability": 0.955078125}, {"start": 2466.74, "end": 2467.82, "word": " COOH", "probability": 0.6387939453125}, {"start": 2467.82, "end": 2468.26, "word": " و", "probability": 0.93017578125}, {"start": 2468.26, "end": 2469.88, "word": " CH2O", "probability": 0.90087890625}, {"start": 2469.88, "end": 2470.34, "word": " و", "probability": 0.78662109375}, {"start": 2470.34, "end": 2470.96, "word": " بعدين", "probability": 0.669677734375}, {"start": 2470.96, "end": 2471.54, "word": " أوهانة", "probability": 0.7462158203125}, {"start": 2471.54, "end": 2472.12, "word": " OH", "probability": 0.9248046875}, {"start": 2472.12, "end": 2473.04, "word": " نخليها", "probability": 0.8607177734375}, {"start": 2473.04, "end": 2473.56, "word": " OCOC", "probability": 0.5084635416666666}, {"start": 2473.56, "end": 2473.8, "word": " double", "probability": 0.377685546875}, {"start": 2473.8, "end": 2474.12, "word": " bond", "probability": 0.92041015625}, {"start": 2474.12, "end": 2475.04, "word": " Oacetyl", "probability": 0.5487060546875}, {"start": 2475.04, "end": 2475.5, "word": " يعني", "probability": 0.7646484375}, {"start": 2475.5, "end": 2476.04, "word": " وجود", "probability": 0.983154296875}, {"start": 2476.04, "end": 2477.0, 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{"start": 2566.8, "end": 2566.92, "word": " الله", "probability": 0.95654296875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2567.61625, "duration_after_vad": 2471.4118749999902}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..66f7c165203597f427c94457ea613da8b2ab0469
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_postprocess.srt
@@ -0,0 +1,2200 @@
+1
+00:00:20,770 --> 00:00:26,070
+بسم الله الرحمن الرحيم المرة الماضية بدأنا معكم في
+
+2
+00:00:26,070 --> 00:00:30,810
+الفصل الثاني بونوان ال alkanes and cycloalkanes
+
+3
+00:00:30,810 --> 00:00:37,130
+ربما حكينا فكرة في البداية عن تصنيفات ال alkanes
+
+4
+00:00:37,130 --> 00:00:41,350
+أو ال hydrocarbons ل saturated alkanes بقولنا
+
+5
+00:00:41,350 --> 00:00:46,350
+هدولة نوعين اللي همالالكينز والسايكلوالكينز و
+
+6
+00:00:46,350 --> 00:00:50,110
+unsaturated hydrocarbons اللي منها المراكبات اللي
+
+7
+00:00:50,110 --> 00:00:52,470
+فيها double bond و triple bond في الالكينز
+
+8
+00:00:52,470 --> 00:00:59,290
+والالكاينز بدنا نتعرف على الالكينز وقلنا هذه سلاسل
+
+9
+00:00:59,290 --> 00:01:05,200
+وممكن أن تكون مراكباتمتفرعة وهذا يؤدي الى تكون عدد
+
+10
+00:01:05,200 --> 00:01:11,340
+كبير جدا من ال isomers او المتشكلات ال isomers زى
+
+11
+00:01:11,340 --> 00:01:16,780
+ما اتفقنا فى ال alkanes بتبدأ تظهر وقتاش لما بنصل
+
+12
+00:01:16,780 --> 00:01:20,080
+لاربع ذرات كربون يعنى لو عندنا ذرة كربون واحدة
+
+13
+00:01:20,080 --> 00:01:24,480
+عندنا مركب واحد فقط ميثين بعدين ايثين بروبين هذا
+
+14
+00:01:24,480 --> 00:01:28,900
+منه مركب واحد لكن لما ابدي اجى احط اربع ذرات كربون
+
+15
+00:01:28,900 --> 00:01:34,130
+ارتبهمصار في عنده احتمالين لترتيبهم اما ان يرتبوا
+
+16
+00:01:34,130 --> 00:01:39,850
+بشكل متسلسل chain structure و بيكون اسم المركب
+
+17
+00:01:39,850 --> 00:01:45,210
+بيوتين او بشكل branch و بيكون اسم المركب ايزو
+
+18
+00:01:45,210 --> 00:01:48,770
+بيوتين و اتكلمنا بعد هيك عن البنتين انه بيكون
+
+19
+00:01:48,770 --> 00:01:53,930
+تلاتة isomers و بعد ذلك اعطيناكم واجب انكوا تجربوا
+
+20
+00:01:53,930 --> 00:02:00,170
+انتوا تتعبوا و ترسموا الخمسةstructures of hexane
+
+21
+00:02:00,170 --> 00:02:06,010
+والمفروض يكون الأمر بالنسبة لكم مش صعب كثير انه
+
+22
+00:02:06,010 --> 00:02:10,830
+تجيبوا 6 ذرات كربون تجربوا ما لم تعملوا هذا الأمر
+
+23
+00:02:10,830 --> 00:02:14,230
+بالإيد و بالجلم لرصاص و بالورق و تتعبوا فيه كثير
+
+24
+00:02:14,230 --> 00:02:20,770
+مابفيدش ان انا اعمله بكل الأحوال هذه وجفنا
+
+25
+00:02:20,770 --> 00:02:26,630
+اخر شي عند ال structure ofميثين وقولنا ان الميثين
+
+26
+00:02:26,630 --> 00:02:32,290
+ماخد الـ tetrahedral structure اللي له أربعة أوجه
+
+27
+00:02:32,290 --> 00:02:38,390
+وهذا أفضل شئ نتعامل معه نرسمه بسهولة اننا نعمله
+
+28
+00:02:38,390 --> 00:02:41,810
+بالشكل اللي موجود بين اديكم تخيل انه عندنا مستويين
+
+29
+00:02:41,960 --> 00:02:48,200
+مستوى أفقي للأمام ومستوى متعامد عليه للخلف هذا
+
+30
+00:02:48,200 --> 00:02:51,960
+المستوى الأفقي للأمام بيكون فيه ذارتين هيدروجين في
+
+31
+00:02:51,960 --> 00:02:56,880
+زاوية 109.5 والمستوى الخلفي أيضا في ذارتين
+
+32
+00:02:56,880 --> 00:03:02,320
+هيدروجينبزاوية 109.5، الآن باقي الزاوية أيضًا 109
+
+33
+00:03:02,320 --> 00:03:05,940
+.5، يعني لو واحد .. لو واحدة بدأ تاخد بين هذه
+
+34
+00:03:05,940 --> 00:03:08,260
+الهيدروجين اللي في المستوى الأمامي و اللي في
+
+35
+00:03:08,260 --> 00:03:14,100
+المستوى الخلفي و انقيس الزاوية 109.5اللي اتوقفنا
+
+36
+00:03:14,100 --> 00:03:19,020
+عنده كيف يرسم هذا الشكل بالفراغ كيف يرسم هذا الشكل
+
+37
+00:03:19,020 --> 00:03:23,860
+بالفراغ قولنا أفضل شيء أنه نرسمه بهذه الطريقة
+
+38
+00:03:23,860 --> 00:03:29,920
+نستعمل ال wedges أو الأسافير بحيث أنه الأشياء اللي
+
+39
+00:03:29,920 --> 00:03:34,400
+للأمام عادة بنعملها ب solid wedge و الأشياء اللي
+
+40
+00:03:34,400 --> 00:03:39,360
+للخلف عادة بنعملها ب dashed wedgeواضح؟ وهذا اللي
+
+41
+00:03:39,360 --> 00:03:43,860
+موجود عندنا الان اذا احنا بندقيق شوية في هذا الشكل
+
+42
+00:03:43,860 --> 00:03:49,360
+هنلاحظ ان الوجه له رأس head و له base قاعدة
+
+43
+00:03:49,360 --> 00:03:56,250
+القاعدة اللي هي عريضة زي هذه و الرأساللي بيكون
+
+44
+00:03:56,250 --> 00:04:02,030
+رفيع هل يا ترى هناك معنى لما انا اجي ارسم مثلا هذا
+
+45
+00:04:02,030 --> 00:04:07,370
+solid wedge تكون القاعدة فيه على جهة الهيدروجين و
+
+46
+00:04:07,370 --> 00:04:11,650
+الرأس على جهة الكاربون لما اجي ارسم ورا ال dashed
+
+47
+00:04:11,650 --> 00:04:16,690
+wedge تكون القاعدة على جهة الكاربون و الرأس على
+
+48
+00:04:16,690 --> 00:04:22,210
+جهة الهيدروجين هذا الكلام بالتأكيد له معنى شو
+
+49
+00:04:22,210 --> 00:04:27,730
+معنى؟ هذا تعبير عنالرسم في الفراغ دائما احنا
+
+50
+00:04:27,730 --> 00:04:32,070
+متعودين .. دائما احنا متعودين ان الشغلة اللى بتكون
+
+51
+00:04:32,070 --> 00:04:37,590
+قريبة علينا كبيرة بتبين كل ما بعدت عننا بتبين ايش
+
+52
+00:04:37,590 --> 00:04:41,150
+صغيرة يعني الناس اللى بيشوفوا الطائرة في المطار
+
+53
+00:04:41,150 --> 00:04:46,710
+طيارة كبيرة بتاخد خمسمية راكب واضح؟ لما بتبعد كتير
+
+54
+00:04:46,710 --> 00:04:53,610
+في السماء بتشوفوا الطائرة نقطة فكل شيء قريب علينا
+
+55
+00:04:54,670 --> 00:05:00,010
+كبير كلما بقعد صغر حتى لو انتوا بترسموا شارع مثلا
+
+56
+00:05:00,010 --> 00:05:02,950
+متعودين انكوا تقولوا هاي الإنسان هنا اللي بترسم
+
+57
+00:05:02,950 --> 00:05:09,970
+الشارع يبدأ الشارع عريض و كل ما بيبعد بيصير إيش؟
+
+58
+00:05:10,790 --> 00:05:16,210
+يصغر الان هذه الأشياء أيضا تعبير عن هذا الأمر يعني
+
+59
+00:05:16,210 --> 00:05:20,590
+لو انا امسكت هذا الشكل زي هيك هاي اللي موجودين في
+
+60
+00:05:20,590 --> 00:05:25,670
+المستوى الأفقي الان ايش القريب عليكم ذرات
+
+61
+00:05:25,670 --> 00:05:31,710
+الهيدروجين و كل ما بتروحوا على الكاربون بتبتعدوا
+
+62
+00:05:32,390 --> 00:05:38,870
+واضح و لذلك الوجه لما رسمناه خلناه عريض من عند
+
+63
+00:05:38,870 --> 00:05:43,430
+الهيدروجين و كل ما راح الكربون بيبعد بيصير ماخد
+
+64
+00:05:43,430 --> 00:05:49,690
+ايش؟ رأس المثلث فلاحظوا قريب و بيبعد عشان هيك
+
+65
+00:05:49,690 --> 00:05:55,830
+رسمناه عريض و بيصغر لو اجيت على الهيدروجين اللي في
+
+66
+00:05:55,830 --> 00:06:01,480
+الخلفأيش القريب عليكم اكثر ال carbon ولا ال
+
+67
+00:06:01,480 --> 00:06:05,580
+hydrogen؟ ال carbon و كل ما بتروحوا باتجاه ال
+
+68
+00:06:05,580 --> 00:06:12,000
+hydrogen بتبعدوا و لذلك هذا قريب بيبتعد، اذا ال
+
+69
+00:06:12,000 --> 00:06:18,780
+wedge تبعه سيبدأ كبيرامن عند الكربون و يصغر فلو
+
+70
+00:06:18,780 --> 00:06:23,900
+رسمت هذا بشكل معاكس بتكونوا بتعملوا غلط وهذا بيصير
+
+71
+00:06:23,900 --> 00:06:28,120
+جزء لما بترسموا أشكال دائما الشيء القريب عليكم
+
+72
+00:06:28,120 --> 00:06:32,280
+اعملوا الوجه تبعه قاعدته باتجاهكم و كل ما بيبعد
+
+73
+00:06:32,280 --> 00:06:39,000
+بيصغر واضح هذه الفكرة فهذا أمر يجب ان ينتبه له شكل
+
+74
+00:06:39,000 --> 00:06:44,200
+الوجه اللي للأمام و اللي للخلف الان ابتيجي نقطة
+
+75
+00:06:44,200 --> 00:06:50,590
+كثير مهمةلما احنا اضطرنا اضطرارا نرسم الشكل بهذه
+
+76
+00:06:50,590 --> 00:06:55,830
+الطريقة ليش؟ لأنه في اللوح مافيش إمكانية لشيء
+
+77
+00:06:55,830 --> 00:07:00,490
+الفراغي يعني مافيش عندي إمكانية أطلع هدول للأمام و
+
+78
+00:07:00,490 --> 00:07:06,090
+أرجع هدول للخلف فهذه الرسمة غير حقيقية الآن لما
+
+79
+00:07:06,090 --> 00:07:10,310
+باجي بقولكوا بدي أقيس الزوايا مابتكونش تقيسوا
+
+80
+00:07:10,310 --> 00:07:15,560
+الزوايا على أساس الشكلاللي مبين عندكم تقيسوها على
+
+81
+00:07:15,560 --> 00:07:20,120
+أساس الشكل الفراغي اللي موجود في ذهنكم ولذلك لما
+
+82
+00:07:20,120 --> 00:07:25,420
+أقول الزاوية بين الهيدروجين والكاربون والهيدروجين
+
+83
+00:07:25,420 --> 00:07:36,470
+على الرسمة مبينة 180180 لكن هي حقيقة جديش 109.5
+
+84
+00:07:36,470 --> 00:07:40,990
+كذلك الحال لو جيت قلتلكوا بدي الزاوية بين
+
+85
+00:07:40,990 --> 00:07:46,430
+الهيدروجين والكاربون والهيدروجين الآن على الرسمة
+
+86
+00:07:47,810 --> 00:07:54,230
+الزاوية كانت 180 لكنها حقيقة 109.5 فلو كنت معلم
+
+87
+00:07:54,230 --> 00:07:59,870
+بالأزرق و قلت له اكتبوا الزاوية ستكتبوها 109.5 مش
+
+88
+00:07:59,870 --> 00:08:06,040
+180 مابناش نخلط هذه الغلطةلو تخيلنا القاعدة ايضا
+
+89
+00:08:06,040 --> 00:08:11,680
+لو انا اجيت قلتلكم بدي الزاوية بين هذه الهيدروجين
+
+90
+00:08:11,680 --> 00:08:15,440
+اللي في المستوى الأفقي وهذه الهيدروجين الخلفية
+
+91
+00:08:15,440 --> 00:08:22,980
+الان هدولة هنا انبينين تسعين لكن هم حقيقة مية
+
+92
+00:08:22,980 --> 00:08:28,000
+وتسعة و نص ايضا واضح؟
+
+93
+00:08:29,450 --> 00:08:35,470
+فيجب الانتباه لهذا الأمر أن هذا الشكل ليس في مستوى
+
+94
+00:08:35,470 --> 00:08:40,630
+واحد وانما شكل في الفراغ وعندما تحدد الزوايا تبعته
+
+95
+00:08:40,630 --> 00:08:44,790
+يجب أن تحدد من الذهن تبعكه اللي اتعلم ان جميع
+
+96
+00:08:44,790 --> 00:08:50,970
+زوايا الـ tetrahedral structure قيمتها 109.5 كل
+
+97
+00:08:50,970 --> 00:08:55,970
+ذرة بعيدة عن التانيةمن خلال الكربون بزاوية 109.5
+
+98
+00:08:55,970 --> 00:09:03,410
+لا في زاوية شكل الميثين 90 ولا في زاوية 180 جميع
+
+99
+00:09:03,410 --> 00:09:07,510
+زاوية هيدروجين كربون هيدروجين من أي جهة بتاخدوها
+
+100
+00:09:07,510 --> 00:09:15,430
+قيمتها 109.5 هذا
+
+101
+00:09:15,430 --> 00:09:22,950
+بالنسبة لشكل الميثينإذا رجعنا لهذه ال slide اللي
+
+102
+00:09:22,950 --> 00:09:26,150
+اتكلمنا فيها عن ال الكانز بالتفصيل المميل قلنا
+
+103
+00:09:26,150 --> 00:09:30,690
+عندنا ميثين إيثين بروبين لحد البيوتين صار في عندنا
+
+104
+00:09:30,690 --> 00:09:36,330
+كام مركب اتنين الآن هدول بنسميهم الكانز من ال
+
+105
+00:09:36,330 --> 00:09:41,350
+الكانز بنطلع شغلة بنقولها ال kilogram لو يا ترى
+
+106
+00:09:41,350 --> 00:09:45,730
+احنا في نيتنا أنه بدنا نعمل تفاعل لما بدنا نعمل
+
+107
+00:09:45,730 --> 00:09:51,350
+التفاعل أول شيء أول شيء بدنا نعملهإنه بدنا نشيل
+
+108
+00:09:51,350 --> 00:09:58,870
+ذرة هيدروجين مثلا عشان نحط مكانها ذرة كلور الآن
+
+109
+00:09:58,870 --> 00:10:02,990
+لما أنا بشيل هيدروجين من الألكان يعني بدل ما
+
+110
+00:10:02,990 --> 00:10:12,030
+الميثين مثلا CH4 شو بده يصير CH3 وفي مكان سترتبط
+
+111
+00:10:12,030 --> 00:10:15,670
+به الذرة الجديدة نفترض اللي هي ذرة الكلور ممكن
+
+112
+00:10:15,670 --> 00:10:21,400
+نتخيل أنه لونها أخضرالان الالكين ناقص الهيدروجين
+
+113
+00:10:21,400 --> 00:10:27,180
+بسميه الكل جروب دائما الالكين ناقص الهيدروجين الكل
+
+114
+00:10:27,180 --> 00:10:32,520
+جروب فمن الميثين بطول مجموعة بسميها ايش مثل يعني
+
+115
+00:10:32,520 --> 00:10:40,940
+بستبدل ال N ب Y L بدل مثل N بصير مثل جروب دائما كل
+
+116
+00:10:41,530 --> 00:10:46,570
+نهاية اسم او شغلة فيها ال YL فانا بحكي عن الكلجروب
+
+117
+00:10:46,570 --> 00:10:52,330
+يعني ال cane مخصوم منه ذرة هيدروجين واضح؟ الان
+
+118
+00:10:52,330 --> 00:10:57,450
+لاحظوا لو هذه الذرة اتيت اعمل مركب طبعا المثل
+
+119
+00:10:57,450 --> 00:11:02,730
+مجموعة لكن لا تكون مركب يعني انا لما اخص منها
+
+120
+00:11:02,730 --> 00:11:07,290
+هيدروجينمباشرة مكانها الهيدروجين شو هتيجي تحط
+
+121
+00:11:07,290 --> 00:11:12,550
+اكلور نفترض الان لو كونت هذا المركب و بدي اعطيه
+
+122
+00:11:12,550 --> 00:11:19,010
+اسم باجي بسأل هذه المجموعة شو اسمها مثل وفي عند
+
+123
+00:11:19,010 --> 00:11:24,910
+اكلور فبقول المركب مثل اكلورايدبصير في ال common
+
+124
+00:11:24,910 --> 00:11:29,510
+nomenclature يعني التسمية المشهورة انه انا لو هنا
+
+125
+00:11:29,510 --> 00:11:34,110
+شيلت hydrogen و افترض و حطيت chlorine ايش هاسم
+
+126
+00:11:34,110 --> 00:11:41,070
+المركب اللي عندى مثل chloride هذه التسميةبنقول
+
+127
+00:11:41,070 --> 00:11:44,890
+عنها احنا ايش common nomenclature، ايش يعني
+
+128
+00:11:44,890 --> 00:11:49,350
+common؟ تسمية مشهورة، مش تسمية حسب القواعد، هناخد
+
+129
+00:11:49,350 --> 00:11:52,890
+نوعين من التسمية، في تسمية بنسميها IUPAC
+
+130
+00:11:52,890 --> 00:11:56,820
+Nomenclatureالتسمية لحسب القواعد اللي بنتعلمها
+
+131
+00:11:56,820 --> 00:12:00,620
+الآن وفيكم ال nomenclature التسمية المشهورة الان
+
+132
+00:12:00,620 --> 00:12:05,620
+التسمية المشهورة في مثل هذه المراكبات كيف بتتم من
+
+133
+00:12:05,620 --> 00:12:11,140
+خلال ذكر اسم المجموعة و بعد هيك بذكر اسم الهالوجين
+
+134
+00:12:11,140 --> 00:12:15,480
+فمن ال مثل لما شيلت هيدروجين صارت مثل حطيت بدلها
+
+135
+00:12:15,480 --> 00:12:20,380
+كلوه بيصير المراكب مثل كلورايد لو حطيت بدلها بروم
+
+136
+00:12:21,110 --> 00:12:27,190
+مثل البروميد و هكذا واضح؟ الان بنفس المنطق لو اجيت
+
+137
+00:12:27,190 --> 00:12:32,770
+على الاثين كام هيدروجين في الاثين بالمجمل؟ ستة
+
+138
+00:12:32,770 --> 00:12:37,170
+لاحظوا الست ذرات هيدروجين اللي في الاثين كلهم زي
+
+139
+00:12:37,170 --> 00:12:40,990
+بعض متكافئات يعني لو شيلت اي واحدة منهم هعمل
+
+140
+00:12:40,990 --> 00:12:47,670
+مجموعة شو هسميها؟ اثل زي ما انا شيلت من الميثين من
+
+141
+00:12:47,670 --> 00:12:53,840
+الأربع المتكافئات هدولةهيدروجينة وسميت المجموعة
+
+142
+00:12:53,840 --> 00:12:58,860
+مثل بقدر انا من ال اثين ايضا اشيل هيدروجينة الست
+
+143
+00:12:58,860 --> 00:13:01,880
+هيدروجينات زي بعض اي واحدة بنشيلها بتعطينا نفس
+
+144
+00:13:01,880 --> 00:13:07,080
+المجموعة هنكون مجموعة اثل لو افترضنا هذه المجموعة
+
+145
+00:13:07,080 --> 00:13:10,740
+مكان الهيدروجين اللي شيلناها حطينا كلور شو هيصير
+
+146
+00:13:10,740 --> 00:13:18,440
+مثلا مركبة اثل كلورايد و هكذا طيب لو اجينا بعد هيك
+
+147
+00:13:18,440 --> 00:13:24,620
+للبروبينوقلنا من مركب البروبين بدنا نشيل هيدروجين
+
+148
+00:13:24,620 --> 00:13:32,000
+ونعمل مجموعة بروبين مثل مثل اثان اثل بروبين بروبين
+
+149
+00:13:32,000 --> 00:13:39,000
+بيوتين بيوتل هتلاحظوا انه هيبدأ يصير عندى مشكلة
+
+150
+00:13:39,000 --> 00:13:46,610
+صغيرة انهالبروبين في كام هيدروجين؟ تمانية هي تلاتة
+
+151
+00:13:46,610 --> 00:13:50,870
+و تلاتة زي بعض وفي هنا الهيدروجينتين اللي اتفقنا
+
+152
+00:13:50,870 --> 00:13:56,470
+انه اختصرناهم في الكتابة اذا شكله العام CH3 CH2
+
+153
+00:13:56,470 --> 00:14:02,830
+CH3 تمان هيدروجينات هذولة تمان هيدروجينات كام نوع؟
+
+154
+00:14:04,020 --> 00:14:07,900
+عبارة عن نوعين التلاتة هذول والتلاتة هذول اللي على
+
+155
+00:14:07,900 --> 00:14:12,400
+الطرف زي بعض وهذه اللي موجودين في النص زي بعض فال
+
+156
+00:14:12,400 --> 00:14:16,960
+تمان هيدروجينات تعون لبروبين نوعين ستة زي بعض
+
+157
+00:14:16,960 --> 00:14:21,800
+وتنتين زي بعض لو شيلت أي واحدة من هان او من هان
+
+158
+00:14:21,800 --> 00:14:26,640
+هعمل مجموعة ولو شيلت واحدة من هان هعمل مجموعة
+
+159
+00:14:26,640 --> 00:14:30,880
+ولذلك بتلاحظوا انه لما باجي بشيل هيدروجين من
+
+160
+00:14:30,880 --> 00:14:35,460
+البروبين بعمل مجموعتيناذا شيلت من الطرف وهي جاهز
+
+161
+00:14:35,460 --> 00:14:39,420
+انه يشبك من هنا من هنا خصمة الهيدروجين هذه معناه
+
+162
+00:14:39,420 --> 00:14:44,140
+الكلام هذا بسميها مجموعة البروبيل ولو بدي اشيل من
+
+163
+00:14:44,140 --> 00:14:50,220
+النص بدي تصير ايزو بروبيل فلاحظوا معي لو بعد هيك
+
+164
+00:14:50,220 --> 00:14:56,360
+اجينا نعمل مركب نضيف كلور ممكن ناس يقولوا حطلي
+
+165
+00:14:56,360 --> 00:15:02,420
+كلور هانأو محل الهيدروجين اللي شلتها في الحالة
+
+166
+00:15:02,420 --> 00:15:06,600
+الأولى شو هيصير اسم المُركّب؟ Isopropyl chloride
+
+167
+00:15:06,600 --> 00:15:11,240
+في الحالة التانية إيش هيصير اسم المُركّب؟
+
+168
+00:15:11,240 --> 00:15:13,020
+Isopropyl chloride
+
+169
+00:15:15,840 --> 00:15:20,340
+واضح؟ و لذلك بدكوا تكونوا منتبهين أن التلات
+
+170
+00:15:20,340 --> 00:15:27,720
+كربونات كم ألكين منهم؟ واحد .. كم ألكين؟ واحد اسمه
+
+171
+00:15:27,720 --> 00:15:33,900
+بروبيل .. كم ألكي لجروب؟ تنتين .. اسمهم بروبيل و
+
+172
+00:15:33,900 --> 00:15:38,660
+ايزو بروبيل .. واضح؟هذا الكلام أكيد بحاجة إلى
+
+173
+00:15:38,660 --> 00:15:44,120
+تدريب وحفظ بعد شوية بنجي على أربع ذرات كربون هنقول
+
+174
+00:15:44,120 --> 00:15:50,960
+الأربع ذرات كربون أساسا منهم كم مركب اتنين بيوتين
+
+175
+00:15:50,960 --> 00:15:57,500
+و ايزو بيوتين طب كم الكل جروب منهم؟ بدي أجي أطلع
+
+176
+00:15:57,500 --> 00:16:05,510
+هنا كم هيدروجين عندى؟في البيوتين العادى عشرة تلاتة
+
+177
+00:16:05,510 --> 00:16:10,950
+و اتنين و اتنين و تلاتة الان هدولة المختصرين لو
+
+178
+00:16:10,950 --> 00:16:18,270
+بيناهم بالاحمر وسألنا العشرة هيدروجين هدولة كام
+
+179
+00:16:18,270 --> 00:16:27,350
+نوع كام نوع هدول العشر هيدروجين نوعين كام نوع كداش
+
+180
+00:16:27,350 --> 00:16:34,450
+و كداشستة زي بعض اللي على الطرف والاربعة هدول زي
+
+181
+00:16:34,450 --> 00:16:38,410
+بعض يعني لو شيلت hydrogen من هان او هان او هان او
+
+182
+00:16:38,410 --> 00:16:44,130
+هدول نفس الاشي هيعطيني مجموعة اش اسمها الـbutyl
+
+183
+00:16:44,130 --> 00:16:48,190
+ولو شيلت اي واحدة من هدول الاربعة هادي او هادي او
+
+184
+00:16:48,190 --> 00:16:52,030
+هادي او هادي كأن بكون شيلت عن موقع اتنين يعني من
+
+185
+00:16:52,030 --> 00:16:55,490
+هان او من هان بشيل عن موقع واحد من هان او من هان
+
+186
+00:16:55,490 --> 00:17:02,320
+بشيل عن موقع اتنينصار عندى من نفس البيوتين العادى
+
+187
+00:17:02,320 --> 00:17:08,340
+كام مجموعة؟ تنتين واحدة بسميها butyl واحدة بسميها
+
+188
+00:17:08,340 --> 00:17:12,060
+secondary butyl secondary اللى احنا شيلنا فيها
+
+189
+00:17:12,060 --> 00:17:16,410
+الهيدروجين من carbon 2الـ Butyl اللي شيلنا فيها
+
+190
+00:17:16,410 --> 00:17:21,910
+الهيدروجين من Carbon-1 مرات كتيرة هتلاحظوا إضافة و
+
+191
+00:17:21,910 --> 00:17:26,270
+ممكن تقرؤوها في بعض الكتب أن هذا الـ Butane بيروح
+
+192
+00:17:26,270 --> 00:17:32,850
+و بيحطه قدام حرف الـ N معناه بيوتين عادي المتسلسل
+
+193
+00:17:32,850 --> 00:17:37,530
+فالـ N هذي جاية من كلمة إيش؟ Normal لـ Butane
+
+194
+00:17:37,530 --> 00:17:41,270
+العادي و المجموعة تبعته هتلاحظوا مرات بيحطوا
+
+195
+00:17:41,270 --> 00:17:46,390
+قدامها حرف الـ Nفإذا قرأنا بيوتين هو نفسه
+
+196
+00:17:46,390 --> 00:17:51,270
+الانبيوتين المتسلسل وإذا قرأنا المجموعة بيوتين هي
+
+197
+00:17:51,270 --> 00:17:55,770
+نفسها الانبيوتين يعني البيوتين العادية اللي من نمر
+
+198
+00:17:55,770 --> 00:18:01,690
+واحد منها شيلنا ذرة إيش الهيدروجين الآن لو حطينا
+
+199
+00:18:01,690 --> 00:18:06,300
+هنا كلور شو هتسمي المركب؟Butylic chloride طب لو
+
+200
+00:18:06,300 --> 00:18:11,440
+حطينا هنا secondary butylic chloride الان لو اجينا
+
+201
+00:18:11,440 --> 00:18:15,120
+على ال isomers التانى اللى من اربع كربونات اللى
+
+202
+00:18:15,120 --> 00:18:21,640
+اسمه ايش ايزو بيوتين و سألنا كام هيدروجين فيه اكيد
+
+203
+00:18:21,640 --> 00:18:27,900
+عشرة لأنه التنين C4H10 طيب اللى مبينين تسعة وين
+
+204
+00:18:27,900 --> 00:18:34,190
+العاشرةالمختصرة هنا عشان يكتمل الشكل الان هدول
+
+205
+00:18:34,190 --> 00:18:41,090
+العشر هيدروجينات كام نوع؟ إذا بتطلع عليهم ممتازة
+
+206
+00:18:41,090 --> 00:18:49,180
+نوعين التسعة هدول زي بعضوهذا الهيدروجين نوع تاني
+
+207
+00:18:49,180 --> 00:18:52,680
+لأن هذا على الطرف وهذا على الطرف وهذا على الطرف
+
+208
+00:18:52,680 --> 00:18:57,020
+وهذا جاء في قلب الجزء فهذه نوع و هذول التسعة زي
+
+209
+00:18:57,020 --> 00:19:01,440
+بعض بناء على ذلك لو شيلنا أي واحدة من هذول هنعمل
+
+210
+00:19:01,440 --> 00:19:09,160
+مجموعةماذا نسمي المجموعة؟ انظروا معي هنا CH3 CH
+
+211
+00:19:09,160 --> 00:19:12,920
+CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+212
+00:19:12,920 --> 00:19:13,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+213
+00:19:13,020 --> 00:19:13,200
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+214
+00:19:13,200 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+215
+00:19:13,560 --> 00:19:15,980
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+216
+00:19:15,980 --> 00:19:20,860
+CH2 CH2 CH2 CH2 CH2والعدد كله أربعة إذا هذه
+
+217
+00:19:20,860 --> 00:19:27,200
+المجموعة إيش اسمها Isobutyl هذه المجموعة اسمها
+
+218
+00:19:27,200 --> 00:19:30,680
+Isobutyl اللي شيلنا فيها هيدروجين سواء من هنا أو
+
+219
+00:19:30,680 --> 00:19:36,160
+من هنا أو من هنا هي Iso هذا الشكل بيعني Iso هذا
+
+220
+00:19:36,160 --> 00:19:40,120
+التفرع كاربون طالع منها مجموعتين مثل Iso لاحظوا
+
+221
+00:19:40,120 --> 00:19:46,290
+هنا كان عندكم تقريبا نفس الاشي انتبهوا معيcarbon
+
+222
+00:19:46,290 --> 00:19:50,190
+منها مجموعتين مثل شو قلنا ايزو العدد الكلي لل
+
+223
+00:19:50,190 --> 00:19:56,810
+carbons كم كان تلاتة ولذلك سمناها ايزو بروبل الان
+
+224
+00:19:56,810 --> 00:20:01,790
+carbon طالع منها مجموعتين مثل ايزو و العدد الكلي
+
+225
+00:20:01,790 --> 00:20:08,630
+اربعة اذا صارت ايزوبيوتل لو الان بدى اقولها واحدة
+
+226
+00:20:08,630 --> 00:20:13,050
+طيب ال ISO pentel مثلا او ال ISO hexel بتقدر
+
+227
+00:20:13,050 --> 00:20:21,410
+ترسمها اه ع طول بقول هي ال ISO CH3 CH3
+
+228
+00:20:21,410 --> 00:20:26,290
+CH3 الان هكذا صار عندى ISO لو قولت ISO pentel جداش
+
+229
+00:20:26,290 --> 00:20:33,220
+بدى يكون عندى خمسة خمسة اذا بدي كمان هنا CH2CH2 و
+
+230
+00:20:33,220 --> 00:20:37,100
+من هنا شيلت الهيدروجين خليني هادي مثلا لو حطيت
+
+231
+00:20:37,100 --> 00:20:41,720
+كلور هنا كل
+
+232
+00:20:41,720 --> 00:20:51,680
+المركب ايش حيصير ايزو اربعة خمسة بنتل اكلورايد لو
+
+233
+00:20:51,680 --> 00:20:59,960
+حطيت الكلور هنا ايزو بيتل اكلورايد واضح بهذا الشكل
+
+234
+00:20:59,960 --> 00:21:00,300
+بيكون
+
+235
+00:21:03,730 --> 00:21:08,510
+جزء ال ISO التلاتة هدول، الآن إذا بس صفيت عليهم
+
+236
+00:21:08,510 --> 00:21:13,470
+بقول ISO Propyl، زيدت Carbon؟ ISO Butyl، زيدت
+
+237
+00:21:13,470 --> 00:21:17,810
+Carbon؟ ISO Bentyl، الآن هنا بدكوا تنتبهوا، إذا
+
+238
+00:21:17,810 --> 00:21:23,250
+كان عندي شئ بينتهي بالنهاية YL، بحكي عن مجموعة،
+
+239
+00:21:23,250 --> 00:21:28,110
+إذا كان عندي شئ بينتهي بالنهاية N؟بحكي عن ال cane
+
+240
+00:21:28,110 --> 00:21:34,110
+يعني مثلا لو قلنا لطالبة بدنا رسمة ال ISO أكتين
+
+241
+00:21:34,110 --> 00:21:42,950
+اتخيلوا أجاكوا في الامتحان بدي ISO أكتين بتغلبش
+
+242
+00:21:42,950 --> 00:21:49,970
+مباشرة ال ISO كيف شكلها CH3 CH3
+
+243
+00:21:50,800 --> 00:21:56,600
+الان هى صار عندى جزء ال ISO بدي اكمل ل ألكين كم
+
+244
+00:21:56,600 --> 00:22:01,280
+carbon بدى يصير المجموع الكله تمانية اذا هى تلاتة
+
+245
+00:22:01,280 --> 00:22:09,160
+اربعة خمسة ستة سبعة تمانية وهنا بكتب ايش CH3 مش
+
+246
+00:22:09,160 --> 00:22:15,190
+شايل ولا هيدروجينه منه ليش لأنه نهاية N الكينلكن
+
+247
+00:22:15,190 --> 00:22:19,130
+لو كنت بدي الـ iso-octal group من وين هشيل
+
+248
+00:22:19,130 --> 00:22:25,890
+الهيدروجينة؟ من هذه الأخيرة واضح؟ الآن إذا هاي تسع
+
+249
+00:22:25,890 --> 00:22:28,410
+هيدروجينات زي بعض لو شيلت منهم هيدروجينة بطلّق
+
+250
+00:22:28,410 --> 00:22:33,370
+مجموعة isobutyl طب لو شيلت هيدروجين من النص بطلّق
+
+251
+00:22:33,370 --> 00:22:38,270
+مجموعة فيها ذرة الكاربون هذه متصلة بتلت مجموعات
+
+252
+00:22:38,270 --> 00:22:46,250
+CH3 بنسميها tertiarybutylTertiarybutyl مرات
+
+253
+00:22:46,250 --> 00:22:51,210
+بيكتبوا ترت اختصارا و مرات بيحطوا T يعني ممكن
+
+254
+00:22:51,210 --> 00:22:59,700
+تلاقوا Tبيوتل أو تيرت بيوتل تيرتشار بيوتل في كل
+
+255
+00:22:59,700 --> 00:23:04,080
+الأحوال لما نحتاج نشوف هذه الأشياء من ناحية
+
+256
+00:23:04,080 --> 00:23:08,680
+alphabetical أي حرف اللي بنعتمده لأنه بعد شوية لما
+
+257
+00:23:08,680 --> 00:23:13,500
+نسمي المراكبات يلزمنا الترتيب ال alphabetical
+
+258
+00:23:13,500 --> 00:23:19,200
+لبيوتل حتى لو كنتي بتاعة بيوتل هي حرف إيشالـ
+
+259
+00:23:19,200 --> 00:23:23,400
+secondary butyl حرف بيه، ال tertiary butyl حرف
+
+260
+00:23:23,400 --> 00:23:30,960
+بيه، ال isobutyl حرف I، ال isobutyl حرف I مش حرف
+
+261
+00:23:30,960 --> 00:23:36,520
+بيهواضح ال isobutyl لو قلتلكوا alphabetically ايش
+
+262
+00:23:36,520 --> 00:23:40,760
+اول اشي باعتمدوا فيها I لكن tertiary butyl باهمل
+
+263
+00:23:40,760 --> 00:23:45,340
+ال T وتعامل على انه حرف الأول B من ناحية
+
+264
+00:23:45,340 --> 00:23:50,720
+alphabetical و لو حطينا هنا Chlor في شغلات مرات مش
+
+265
+00:23:50,720 --> 00:23:55,780
+بحاجة لفهم بحاجة انكم تحفظوها زي هيك تمام يعني مش
+
+266
+00:23:55,780 --> 00:23:58,600
+قصة tertiary butyl alphabetically
+
+267
+00:24:00,680 --> 00:24:09,180
+B Isobutyl خلصنا واضح؟
+
+268
+00:24:09,180 --> 00:24:13,220
+مرات كتير في التسمية في ناس بصروا على ان بعض
+
+269
+00:24:13,220 --> 00:24:17,180
+الأشياء بدهم يفهموها مش كل شيء في التسمية مش كل
+
+270
+00:24:17,180 --> 00:24:22,020
+شيء في التسمية بيفهم يعني لما اجي اقول والله انت
+
+271
+00:24:22,020 --> 00:24:29,660
+اسمك هدا ليش سموكي هدا خلاص هدا خلاصواحدة تيجي
+
+272
+00:24:29,660 --> 00:24:36,640
+تقولي طب ليش سموه بروبين؟ كان سموه نوبا كلين، ليش
+
+273
+00:24:36,640 --> 00:24:43,120
+سموه بروبين؟مش كل شيء في التسمية بالذات أحيانا
+
+274
+00:24:43,120 --> 00:24:46,900
+بتلاقوا إله منطق وقاعدة زي ما أنتوا أهلكوا سموكم
+
+275
+00:24:46,900 --> 00:24:52,280
+واضح؟ زي ما أهلكوا سموكم كان في شيء معين خلهم
+
+276
+00:24:52,280 --> 00:24:58,620
+يسموا مركب معين بنزين كان في شيء معين حادث صديق
+
+277
+00:24:58,620 --> 00:25:04,780
+اللي بيرجع لتاريخ العلوم أحيانا ممكن بلحظة من
+
+278
+00:25:04,780 --> 00:25:11,700
+اللحظات يلاقي هذا الأصلواللي بيرجع لتاريخ الأسماء
+
+279
+00:25:11,700 --> 00:25:16,280
+اللي بيرجع لتاريخ الأسماء ممكن يلاقي أصل لأسماءكم
+
+280
+00:25:16,280 --> 00:25:22,460
+حتى لو أنتم مش عارفينه يعني ممكن لمن ولدتوا كان
+
+281
+00:25:22,460 --> 00:25:26,860
+متوفي عامة إلكم اسمها هودا إكراما إليها سموكوا
+
+282
+00:25:26,860 --> 00:25:30,940
+هودا الآن أنا بالنسبة إيه هذه المعلومة؟ مابعرفاش
+
+283
+00:25:30,940 --> 00:25:35,220
+ولذلك خدوا تسمية العناصر مرة بتلاقي العنصر بيقوله
+
+284
+00:25:35,220 --> 00:25:41,090
+مسمى على اسم مدينةمر على اسم بني آدم اللي اكتشفه،
+
+285
+00:25:41,090 --> 00:25:46,550
+مر على اسم كذا، فأصل الاسم قد لا نعرفه، قد يكون له
+
+286
+00:25:46,550 --> 00:25:52,930
+أصل، لكن احنا ايش؟ ما بنعرفوش، الأن بالنسبة لنا
+
+287
+00:25:52,930 --> 00:25:58,990
+هذه سيارة مرسيدس، اسم، لكن يا تورا لو أعطيتكوا
+
+288
+00:25:58,990 --> 00:26:02,170
+واجب، ليش سموا ال مرسيدس مرسيدس؟
+
+289
+00:26:05,190 --> 00:26:10,310
+فتشوا عليه و هتقولي الجواب المرة الجاية هتلاحظوا
+
+290
+00:26:10,310 --> 00:26:15,530
+إنه إله اسم ومسمى على اسم واحدة وكذا إله أصل بس مش
+
+291
+00:26:15,530 --> 00:26:18,150
+كتير بهمن الأصل في لحظة من لحظات بلاش نضيع وقت
+
+292
+00:26:18,150 --> 00:26:24,610
+كتير الآن هذه المجموعات يجب أن تتدربوا عليها يجب
+
+293
+00:26:24,610 --> 00:26:29,810
+أنكم تحفظوها بشكل جيد هذا الكلام كيف بيجي بالتدريب
+
+294
+00:26:29,810 --> 00:26:33,490
+كيف بيجي بالتدريب الآن
+
+295
+00:26:34,940 --> 00:26:39,940
+بعد ما أخدنا ال الكانز البسيطة و ال alkyl groups
+
+296
+00:26:39,940 --> 00:26:45,120
+البسيطة بدنا ناخد تسمية ال الكانز بال IUPAC system
+
+297
+00:26:45,120 --> 00:26:50,360
+حتى لو كبرت و صارت متفرعة واضح؟ يعني تسمية ال
+
+298
+00:26:50,360 --> 00:26:54,340
+الكانز الكبيرة اللي مامرتش علينا بال IUPAC system
+
+299
+00:26:54,730 --> 00:27:00,050
+ال ايوبك سيستم بيعتمد على ان نبحث عن اطول سلسلة
+
+300
+00:27:00,050 --> 00:27:05,330
+كربونية و اسم عليها يعني لو اطول سلسلة تلاتة نهاية
+
+301
+00:27:05,330 --> 00:27:11,110
+الاسم عندى ابروبين لو اربعة بيوتين تمانية اكتيل
+
+302
+00:27:12,590 --> 00:27:17,830
+فالشيء الأول بيقولنا choose the largest continuous
+
+303
+00:27:17,830 --> 00:27:23,090
+chain الان رجاء ماحدش يفهم السلسلة أن انتوا
+
+304
+00:27:23,090 --> 00:27:28,550
+بتكونوا تشوفوها مرسومة عدل بشكل أفقي أو بشكل عمودي
+
+305
+00:27:28,550 --> 00:27:33,350
+هذا الشيء ليس له معنى أنها تكون أفقي أو عمودي أو
+
+306
+00:27:33,350 --> 00:27:38,740
+مائلة معنى سلسلةذرات كربون ورا بعض بأي طريقة انا
+
+307
+00:27:38,740 --> 00:27:43,180
+ارسمهم هذا الكلام لا معنى له كله ممكن يعني لو بدأ
+
+308
+00:27:43,180 --> 00:27:48,920
+احكي مثلا عن خمسة لو بدأ احكي عن خمسة هذه سلسلة من
+
+309
+00:27:48,920 --> 00:27:59,380
+خمسة تمام وهذه سلسلة من خمسة وممكن ناخد كمان هذه
+
+310
+00:27:59,380 --> 00:28:05,360
+بهذا الشكلسلسلة من الخمسة و ممكن نرسمها بطريقة
+
+311
+00:28:05,360 --> 00:28:12,440
+تانيةسلسلة من خمسة فمعنى سلسلة ذرات متتالية وليس
+
+312
+00:28:12,440 --> 00:28:15,740
+الطريقة المرسومة بعض الناس بيقول سلسلة يعني بيشوفه
+
+313
+00:28:15,740 --> 00:28:21,800
+هيك حسب نظره أفقي أو عمودي لأ لأ معنى سلسلة كام
+
+314
+00:28:21,800 --> 00:28:25,360
+ذرة كربون متتالية فاهمنا إيش معنى سلسلة فلو قولت
+
+315
+00:28:25,360 --> 00:28:29,220
+هنا أما أطول سلسلة واحد اتنين تلاتة أربعة خمسة
+
+316
+00:28:29,220 --> 00:28:33,060
+واحد اتنين تلاتة أربعة خمسة واحد اتنين تلاتة أربعة
+
+317
+00:28:33,060 --> 00:28:36,580
+خمسة واحد اتنين تلاتة أربعة خمسة ابلاحظين مرسومين
+
+318
+00:28:36,580 --> 00:28:43,470
+بطرقمختلفة لكن بالنسبة لي معنى أطول سلسلة أطول عدد
+
+319
+00:28:43,470 --> 00:28:47,870
+متتالي من ذرات الكربون كيف يرتسموا مش مشكلة واضح و
+
+320
+00:28:47,870 --> 00:28:52,010
+لذلك بعد شوية اشوفوا مثلا هذا المركب هين اتكلمت عن
+
+321
+00:28:52,010 --> 00:28:58,190
+سلسلة اللي ماعطيها اللون الأحمر ولو مش مبينة بشكل
+
+322
+00:28:58,190 --> 00:29:04,370
+مستقيم بالنسبة لكم هذا شيء ما لهش معنى الآنحسب
+
+323
+00:29:04,370 --> 00:29:08,130
+أطول سلسلة بيكون اسم المُركّب لو كان عندنا تلاتة
+
+324
+00:29:08,130 --> 00:29:13,050
+نهاية المُركّب ابرو بين خمسة بينتين و هكذا طيب لما
+
+325
+00:29:13,050 --> 00:29:17,370
+بيصير في عندي سلسلة هذه السلسلة أكيد بيتفرع منها
+
+326
+00:29:17,370 --> 00:29:23,010
+شغلات هذه بسميها أنا الأشياء المتفرعة من السلسلة
+
+327
+00:29:23,010 --> 00:29:26,870
+اللي طالعة من أطول سلسلة carbon بقول عنها
+
+328
+00:29:26,870 --> 00:29:31,980
+substituent هذه كلمة هتصير اتمر عليكمكثير
+
+329
+00:29:31,980 --> 00:29:38,040
+Substituents اللي هي الأشياء المبدلة الان كام
+
+330
+00:29:38,040 --> 00:29:43,460
+Substituents على هذا المركب متفرع منه؟ اتنين هدولة
+
+331
+00:29:43,460 --> 00:29:48,920
+ال Substituents لازم انا اوضحهم او اوضح من اي نقطة
+
+332
+00:29:48,920 --> 00:29:53,060
+تفرعوا من اي مكان تفرعوا طب لما هذي بدي اعطيها اسم
+
+333
+00:29:53,060 --> 00:29:57,820
+هعطيها Chloro لما هذي بدي اعطيها اسم هعطيها Abromo
+
+334
+00:29:57,820 --> 00:30:02,830
+بعدين بدي اقول لك Chloro من وين اتفرعت؟من أي موقع
+
+335
+00:30:02,830 --> 00:30:08,690
+لبرومو من وين اتفرعت اذا بالزمن ترقيم لهالسلسلة
+
+336
+00:30:08,690 --> 00:30:12,950
+طالما بحكي سلسلة إذا عندي احتمالين ترقيم ممكن أبدأ
+
+337
+00:30:12,950 --> 00:30:17,770
+من هنا واحد اتنين تلاتة أربعة خمسة أو من هنا واحد
+
+338
+00:30:17,770 --> 00:30:23,130
+اتنين تلاتة أربعة خمسة من أي جهة بدي أبدأ الجهة
+
+339
+00:30:23,130 --> 00:30:26,910
+اللي بتخلي ال substituents أرقامهم أقل ما يمكن
+
+340
+00:30:26,910 --> 00:30:30,230
+يعني لو بدأت من هنا زي ما احنا عاملين ال chlorine
+
+341
+00:30:30,230 --> 00:30:34,280
+على اتنين و ال brom على تلاتة اتنين و تلاتةخمسة لو
+
+342
+00:30:34,280 --> 00:30:38,600
+بدأت منها ان واحد اتنين تلاتة اربعة صارت هذه على
+
+343
+00:30:38,600 --> 00:30:43,840
+تلاتة وهذه على اربعة تلاتة واربعة اذا ماهو اقل
+
+344
+00:30:43,840 --> 00:30:50,900
+ترقيم هذا ولذلك لما بدي ارقم دائما عند احتمالين
+
+345
+00:30:50,900 --> 00:30:56,220
+الاحتمال اللي بدي اختارهالـ lowest possible
+
+346
+00:30:56,220 --> 00:31:00,780
+numbering أقل احتمال بيعطي الـ substituents أرقام
+
+347
+00:31:00,780 --> 00:31:05,640
+طب اعرفنا الأرقام و اعرفنا الآن انه صار عندنا على
+
+348
+00:31:05,640 --> 00:31:13,800
+موقع اتنين ذرة اكلورو مظبوط ولا لأ اكلورو وع موقع
+
+349
+00:31:13,800 --> 00:31:20,410
+تلاتة ذرة ابروموبدي اكتب الاسم كامل الاسم عادة
+
+350
+00:31:20,410 --> 00:31:26,130
+بنبدأ في كتابته من الخلف للامام اول كلمة في الاسم
+
+351
+00:31:26,130 --> 00:31:30,970
+انه عندي خمسة اذا مركبه بنتين يعني اول شي بدي ابدأ
+
+352
+00:31:30,970 --> 00:31:36,070
+اكتبه بنتين هذا البنتين الان بيحمل برومو و كلورو
+
+353
+00:31:36,070 --> 00:31:41,630
+مين بدي اذكره في الاول ال alphabetical اللي بيظهر
+
+354
+00:31:41,630 --> 00:31:47,510
+اولا مين بيجي قبل ال B ولا ال Cالـ B A B C D
+
+355
+00:31:47,510 --> 00:31:51,090
+شوفتوا قبل شوية ليش أنا نبهت كل ال alphabetical في
+
+356
+00:31:51,090 --> 00:31:58,010
+المجموعات أه إذا هذا هيكون three bromo two
+
+357
+00:31:58,010 --> 00:32:03,430
+chlorobentain واضح؟ لأن أنا عندي كام substituent؟
+
+358
+00:32:03,430 --> 00:32:10,670
+هذه و هذه كيف بأذكرهم؟list substituents
+
+359
+00:32:10,670 --> 00:32:15,830
+alphabetically أذكرهم alphabetically أذكر ال B قبل
+
+360
+00:32:15,830 --> 00:32:22,650
+ال C قبل ال D قبل ال E و هكذا طبعا هنا اجتمل الاسم
+
+361
+00:32:22,650 --> 00:32:26,930
+بضيف معلومة أنه لو من مجموعة معينة كان في عندي
+
+362
+00:32:26,930 --> 00:32:33,400
+تنتينبدي أستعمل لمضاي، لو كان في عندي تلاتة ا try،
+
+363
+00:32:33,400 --> 00:32:38,700
+لو عندي أربعة تترى، و هكذا، واضح؟ انشوف أمثلة
+
+364
+00:32:38,700 --> 00:32:46,820
+إضافية، انشوفأمثلة إضافية مثلا هاي مثال أصعب شغلة
+
+365
+00:32:46,820 --> 00:32:52,220
+أنه فعلا طول أطول سلسلة يعني لو إجيت بدي أطول
+
+366
+00:32:52,220 --> 00:32:57,460
+سلسلة ممكن أعد واحد اتنين تلاتة واحد اتنين تلاتة
+
+367
+00:32:57,460 --> 00:33:03,340
+أربعة خمسة واحد اتنين تلاتة أربعة خمسة احتمالات
+
+368
+00:33:03,340 --> 00:33:07,780
+كتيرة بدي أضلني أجرب لحد ما فعلا ألاقي أطول سلسلة
+
+369
+00:33:07,780 --> 00:33:14,930
+واحد اتنين تلاتة أربعة خمسة ستة سبعةإذا مركّب إيش؟
+
+370
+00:33:14,930 --> 00:33:15,730
+هبتين
+
+371
+00:33:23,230 --> 00:33:37,450
+مثل مثل مثل مثل مثل مثل مثل مثل
+
+372
+00:33:46,950 --> 00:33:51,550
+إذا من هنا لازم أرقم فالمثلز اللي عندي وين موجودين
+
+373
+00:33:51,550 --> 00:33:57,350
+على اتنين واربعة هيصير مركبة two four dimethyl
+
+374
+00:33:57,350 --> 00:34:02,850
+heptane two four dimethyl heptane الان هاي مركب
+
+375
+00:34:02,850 --> 00:34:10,610
+تاني بتجارب كتير هتكتشف ان هاي أطول سلسلة سبعة ايش
+
+376
+00:34:10,610 --> 00:34:11,750
+بيتفرع منها
+
+377
+00:34:14,510 --> 00:34:24,070
+هذه المجموعة اللي مرت علينا ايزو بروبل و مثل الان
+
+378
+00:34:24,070 --> 00:34:30,410
+ايزو بروبل حرف I و المثل حرف M و المركب هبتين و I
+
+379
+00:34:30,410 --> 00:34:36,870
+قبل ال M اذا حيصير اسم المركب for aizobrobel انها
+
+380
+00:34:36,870 --> 00:34:38,530
+موجودة على موقع اربعة
+
+381
+00:34:41,630 --> 00:34:46,510
+لاحظوا في كل التسمية لو تطبعوا على الكمبيوتر في أي
+
+382
+00:34:46,510 --> 00:34:54,490
+فراغولا فراغ دائما قبل الرقم وبعد الرقم بتحطه شرطة
+
+383
+00:34:54,490 --> 00:34:58,330
+ما عدا إذا كنا بنحط في أول الإسم بتكون الشرطة فقط
+
+384
+00:34:58,330 --> 00:35:04,170
+بعد الرقم بدون أي فراغات يعني هذا كله متصل بعض
+
+385
+00:35:04,170 --> 00:35:08,830
+كتابة من هنا لهنا مافيش عندي فراغات لو بكتب اسم
+
+386
+00:35:08,830 --> 00:35:14,550
+هذا المركب على الكمبيوتر قبل الرقم شرطة وبعده شرطة
+
+387
+00:35:14,550 --> 00:35:21,380
+ما لم يكن الرقمفي الأول فبس بيكون فيه بعده شرطة
+
+388
+00:35:22,430 --> 00:35:27,630
+الان في عندكم امثلة كتير بإمكانكوا تتدربوا عليها
+
+389
+00:35:27,630 --> 00:35:31,250
+ماعطيكوا انا في الواجبات بالذات في الامتحانات
+
+390
+00:35:31,250 --> 00:35:35,270
+السابقة اللي موجودة عندكم كل امتحان بتلاقي عليه
+
+391
+00:35:35,270 --> 00:35:40,310
+اربع خمس مركبات كيف تسموهم مالم تتدربوا على حفظ
+
+392
+00:35:40,310 --> 00:35:44,890
+أسماء ال الkins على حفظ المجموعات على كيف تسموا
+
+393
+00:35:44,890 --> 00:35:48,970
+مركب مش هتقدروا تطبقوا يعني لازم لو واحد كنتوا
+
+394
+00:35:48,970 --> 00:35:50,210
+تدرسوا و تتدربوا أكثر
+
+395
+00:35:54,510 --> 00:35:58,250
+لأ لأ اعتمدي على اللي احنا بنشرحه بشكل اكبر
+
+396
+00:35:58,250 --> 00:36:02,370
+واعتمدي على الامتحانات الكتيرة اللي موجودة عندكم
+
+397
+00:36:02,370 --> 00:36:08,470
+بتعطيكي اسئلة وافية في الموضوع الآن بنيجي لنقطة
+
+398
+00:36:08,470 --> 00:36:14,350
+خاصة صغيرة بنضيفها في هذا الموضوع أحيانا بنيجي
+
+399
+00:36:14,350 --> 00:36:20,410
+نبحث عن أطول سلسلة بنلاحظ أنه بيطلع عندنا احتمالين
+
+400
+00:36:20,410 --> 00:36:27,520
+مش احتمال واحدمثلا هذا المركب هو نفسه هذا المركب
+
+401
+00:36:27,520 --> 00:36:31,440
+تماما لو بتتطلع عليه يعني احنا رسمنا المركب هذا
+
+402
+00:36:31,440 --> 00:36:36,460
+عملنا له نسخ و لاصق هنا لما نيجي نبحث عن أطول
+
+403
+00:36:36,460 --> 00:36:41,680
+سلسلة عدنا كتير هيقولنا واحد اتنين تلاتة اربعة
+
+404
+00:36:41,680 --> 00:36:47,800
+خمسة ستة سبعة اجت طالبة تانية عدت من هنا واحد
+
+405
+00:36:47,800 --> 00:36:55,600
+اتنين تلاتة اربعة خمسة ستة سبعةطب يا تورا بدي
+
+406
+00:36:55,600 --> 00:37:00,820
+أختار هذه السلسلة و لا بدي أختار هذه السلسلة طلع
+
+407
+00:37:00,820 --> 00:37:05,780
+عندك أكتر من سلسلة سبعة في عندنا قاعدة بتقول if
+
+408
+00:37:05,780 --> 00:37:09,760
+there are two equal along continuous chains يعني
+
+409
+00:37:09,760 --> 00:37:13,180
+لو في عندكوا سلسلتين متساويات في الطول في
+
+410
+00:37:13,180 --> 00:37:16,780
+الاحتمالات ا choose the one with most branches
+
+411
+00:37:16,780 --> 00:37:21,820
+اختار السلسلة اللي فيها تفرعات أكتريعني لو اتطلعت
+
+412
+00:37:21,820 --> 00:37:28,340
+على السلسلة هذه، كم تفرع طالع منها؟ اتنين، شغلتين
+
+413
+00:37:28,340 --> 00:37:31,540
+طالعين منها، لو اتطلعت على السلسلة هذه، كم تفرع
+
+414
+00:37:31,540 --> 00:37:37,980
+طالع منها؟ مجموعة واحدة، واضح؟ هذه طالع منها فقط
+
+415
+00:37:37,980 --> 00:37:42,240
+تفرع واحد، هيو، هنا طالع تفرعين، ابن اختار اللي
+
+416
+00:37:42,240 --> 00:37:47,000
+فيهاتفرعين طبعا لما نختار او ناخد ال lower
+
+417
+00:37:47,000 --> 00:37:51,640
+numbering على نمرة تلاتة في عندي مجموعة CH2 CH3
+
+418
+00:37:51,640 --> 00:37:55,600
+هذه اللي بيقول عنها إثل وعن نمرة اتنين المثل three
+
+419
+00:37:55,600 --> 00:38:00,300
+ethyl two methyl heptane بينما لو واحدة اختارت هذه
+
+420
+00:38:00,300 --> 00:38:04,220
+هتقول heptane على نمرة تلاتة هذه المجموعة
+
+421
+00:38:04,220 --> 00:38:09,520
+isopropyl فهذا الاسم three isopropyl heptane is
+
+422
+00:38:09,520 --> 00:38:14,650
+not a correct nameممكن واحدة في الامتحان تعمله،
+
+423
+00:38:14,650 --> 00:38:18,230
+تعتقد أنها عملت جيدا، في الآخر تتفاجأ أنه غلط
+
+424
+00:38:18,230 --> 00:38:22,670
+بالكامل، ليش؟ لأنها مانتبهتش أنه عندها سلسلتين،
+
+425
+00:38:22,670 --> 00:38:26,690
+ممكن يكونوا سبعة، وأنه لو أخدت من هنا، اللي هي هذه
+
+426
+00:38:26,690 --> 00:38:30,130
+السلسلة، هذه فيها ال most branches، فيها التفرعات
+
+427
+00:38:30,130 --> 00:38:34,390
+الأكثرولذلك اللي بده يشتغل في التسمية بده يكون
+
+428
+00:38:34,390 --> 00:38:39,610
+منتبه أنه فعلا لجأ أطول سلسلة واتأكد أنه مافيش
+
+429
+00:38:39,610 --> 00:38:45,150
+غيرها، لو لجأت إنتين بنفس الطول، بده يختار الأكثر
+
+430
+00:38:45,150 --> 00:38:52,310
+تفرعا، بده يختار السلسلة الأكثر تفرعا، واضح هذا
+
+431
+00:38:52,310 --> 00:39:00,220
+الكلام؟ ممكن نجرب ما أعطيكممثال حتى نشوف انكم
+
+432
+00:39:00,220 --> 00:39:18,060
+أتقنتوا هذا الكلام ولا لا هذا
+
+433
+00:39:18,060 --> 00:39:23,040
+مركب ابدأوا
+
+434
+00:39:23,040 --> 00:39:24,780
+فاكروا فيه وشوفوا
+
+435
+00:39:27,090 --> 00:39:33,530
+أيش أطول سلسلة موجودة فيه و
+
+436
+00:39:33,530 --> 00:39:38,610
+أول ما نعملها بأنصح اكون معاكم قلم فوسفور اتعلموا
+
+437
+00:39:38,610 --> 00:39:44,350
+عليها عشان تقدروا تشوفوا كل ما يتفرع منها واضح؟
+
+438
+00:39:44,350 --> 00:39:49,650
+الآن أكيد هتبدو تعدوا أنتوا واحد تنين تلاتة أربعة
+
+439
+00:39:49,650 --> 00:39:53,310
+أكيد لو قلتوا تلاتة تلاتة أربعة تلاتة أربعة نفس
+
+440
+00:39:53,310 --> 00:40:02,770
+الأشي أوواحد اتنين تلاتة او واحد اتنين تلاتة اربعة
+
+441
+00:40:02,770 --> 00:40:11,370
+خمسة ستة ايش رأيكوا او اي واحدة من هدول هادي زي
+
+442
+00:40:11,370 --> 00:40:14,650
+هادي زي هادي ماهم تلات اطراف واحد اتنين واحد اتنين
+
+443
+00:40:14,650 --> 00:40:22,090
+واحد اتنين اي واحدة بتاخدوها مافيش فيه مشكلة منها
+
+444
+00:40:23,210 --> 00:40:27,150
+أي واحدة من هدولة بيمشي تكون المرة واحدة لأنها
+
+445
+00:40:27,150 --> 00:40:33,650
+وادي وادي زي بعض واحد تانين تلاتة أربعة خمسة ستة
+
+446
+00:40:33,650 --> 00:40:39,630
+سبعة اه الآن هي أطول سلسلة خليني أعلمها و بأنصحكوا
+
+447
+00:40:39,630 --> 00:40:44,630
+لو عندكم طلم فسفور أسفر اتعلموها هي أطول سلسلة
+
+448
+00:40:44,630 --> 00:40:51,050
+عشان نقدر نشوف كام تفرع طالع منها هذه السلسلةاربع
+
+449
+00:40:51,050 --> 00:41:01,330
+انا مع الكلور هذه CH3 وهذه CH3 وهذه CH3 وهنا
+
+450
+00:41:01,330 --> 00:41:06,010
+الكلور اربع تفرعات طالع منها طب لو بدى اعطيها اقل
+
+451
+00:41:06,010 --> 00:41:16,080
+ترقيم من فضل من فضل اكيد واحدتلاتة اربعة خمسة ستة
+
+452
+00:41:16,080 --> 00:41:21,160
+سبعة الان لو بدنا نكتب الاسم كاملا كيف بدنا نبدأ
+
+453
+00:41:21,160 --> 00:41:27,880
+نكتب الاسم؟ من الخلف للامام ايش مركب طالما سبعة؟
+
+454
+00:41:27,880 --> 00:41:35,360
+هبتين الان هذا الهبتين كم نوع من المجموعات يحمل؟
+
+455
+00:41:35,360 --> 00:41:44,910
+نوعين اكلوروومثل ومثل ومثل اتراي مثل اذا هذا حقيقة
+
+456
+00:41:44,910 --> 00:41:54,550
+الـ C في الأول الكلورو اتراي مثل الان الكلورو وين
+
+457
+00:41:54,550 --> 00:42:01,870
+موقعها على نمرة أربعة four شرطة كلورو ال اتراي مثل
+
+458
+00:42:01,870 --> 00:42:10,930
+وين موجودين على اتنينو اتنين و تلاتة لازم احدد
+
+459
+00:42:10,930 --> 00:42:15,330
+تلات ارقام طالما try مثل لازم التلات ارقام بينه
+
+460
+00:42:15,330 --> 00:42:21,090
+اذا هنا فعلا بدي اكتب شرطة اتنين اتنين تلاتة هدف
+
+461
+00:42:21,090 --> 00:42:27,650
+هذا الموقع ان انا اكتبها صح هتكون اتنين اتنين
+
+462
+00:42:27,650 --> 00:42:32,090
+تلاتة try مثل
+
+463
+00:42:37,340 --> 00:42:47,340
+4-chloro-2-2-3-trimethylheptane
+
+464
+00:42:52,160 --> 00:42:56,040
+ماحدش يغلط .. مرات كتير بعض الناس اللي بيحفظوا
+
+465
+00:42:56,040 --> 00:42:59,400
+مجموعات شو الغلط اللي بيجعوا فيه، مابيبحثوش عن
+
+466
+00:42:59,400 --> 00:43:02,480
+أطول سلسلة، بيجوا و بيقولوا اه هذه ال carbon اللي
+
+467
+00:43:02,480 --> 00:43:06,300
+حملة تلت مجموعات tertiary-butyl وهذه السلسلة
+
+468
+00:43:07,580 --> 00:43:11,460
+وبالتالي بيسموه hexane وحمل على نمرة 2 tertiary
+
+469
+00:43:11,460 --> 00:43:16,920
+butyl بالفعش أنا مابخدش أسماء المجموعات إلا بعد ما
+
+470
+00:43:16,920 --> 00:43:23,700
+أحدد أطول سلسلة دائما نمرة واحد حدده أطول سلسلة
+
+471
+00:43:23,700 --> 00:43:28,340
+بعض الناس بيغلط بيجي بيقول لأ هذه تعتبر مجموعة في
+
+472
+00:43:28,340 --> 00:43:32,830
+البداية يعني لو أنا هنا كنت كاتب CH3بروح و بقول
+
+473
+00:43:32,830 --> 00:43:36,210
+ادي مجموعة مثل لأ دي جزء من السلسلة بنفعش اسميها
+
+474
+00:43:36,210 --> 00:43:41,110
+مجموعة هذه من الأخطاء الشائع لبعض الناس بيجي بعمل
+
+475
+00:43:41,110 --> 00:43:44,650
+الترقيم من هان و بعدين بيقول على نمر واحد في عندي
+
+476
+00:43:44,650 --> 00:43:50,950
+try مثل .. لأ مش هيك تأخذه لازم أفتش عليه أطول
+
+477
+00:43:50,950 --> 00:43:54,630
+سلسلة و بعدين أشوف إيش في عندي مجموعات حسب ما
+
+478
+00:43:54,630 --> 00:43:59,010
+اتعلمت بأعمل التسمية تبعي
+
+479
+00:44:04,700 --> 00:44:10,980
+هذه تقريبا فكرة عن ال الكنز بشكل عام لو اتكلمنا عن
+
+480
+00:44:10,980 --> 00:44:15,960
+ال physical properties of الكنز هنلاحظ القاتل اول
+
+481
+00:44:15,960 --> 00:44:23,940
+شئ ال الكنز هم water insoluble ليش؟ لان دائما ال
+
+482
+00:44:23,940 --> 00:44:31,440
+الكنز تتذكر انهم non polar والمية polar حسب قاعدة
+
+483
+00:44:31,440 --> 00:44:36,250
+like dissolves likeالالكينز لا يدوبون في المياه
+
+484
+00:44:36,250 --> 00:44:40,590
+ولذلك من هؤلاء الالكينز على سبيل المثال البنزين
+
+485
+00:44:40,590 --> 00:44:44,890
+اللي هو أقود السيارات واضح هل يا تورا هذا بيدوب في
+
+486
+00:44:44,890 --> 00:44:49,090
+المياه ولا بيعمل طبقة تانية بيعمل طبقة تانية هنا
+
+487
+00:44:49,090 --> 00:44:54,810
+خليني أنبه لنقطة خطأ شائعلأنه احنا باللغة العربية
+
+488
+00:44:54,810 --> 00:44:59,330
+بنستعمل كلمة بنزين لما بنعب السيارة بنقول بنزين
+
+489
+00:44:59,330 --> 00:45:05,310
+فناس كتير بيخطئوا و بيفكروا انه احنا بنعب السيارة
+
+490
+00:45:05,310 --> 00:45:09,150
+البنزين هذا اللي مار عليكم اللي هو البنزين العطري
+
+491
+00:45:09,150 --> 00:45:16,230
+هذا الكلام خطأ طب ايش اسم هو بالانجليزي وقود
+
+492
+00:45:16,230 --> 00:45:23,650
+السيارات ال fuel اسمه جازولينأحنا بالعربي هذا
+
+493
+00:45:23,650 --> 00:45:29,390
+الجازولين بنقول عنه بنزين لكن هو حقيقة خليط من
+
+494
+00:45:29,390 --> 00:45:35,870
+الالكينز بشكل أساسي مركبين من الالكينز هو خليط من
+
+495
+00:45:35,870 --> 00:45:40,190
+الهيبتين والايزو
+
+496
+00:45:40,190 --> 00:45:40,710
+أكتين
+
+497
+00:45:43,660 --> 00:45:48,340
+فالجازولين اللي هو وقود السيارات اللي احنا بنعبيه
+
+498
+00:45:48,340 --> 00:45:52,180
+باللغة العربية متعودين نقول عنه بنزين مالوش هذا ال
+
+499
+00:45:52,180 --> 00:45:56,020
+structure ولا له علاقة بهذا ال structure لأ
+
+500
+00:45:56,020 --> 00:46:02,000
+gasoline is a mixture of alkanes الجازولين وقود
+
+501
+00:46:02,000 --> 00:46:05,780
+السيارات اللي بنعبيه هو خليط من ال alkanes شو ما
+
+502
+00:46:05,780 --> 00:46:10,480
+دول ال alkanes؟الهبتين وال ايزو اكتين و بتهيألي
+
+503
+00:46:10,480 --> 00:46:15,020
+اليوم احنا رسمنا شكل الهبتين سبع كربونات و رسمنا
+
+504
+00:46:15,020 --> 00:46:18,900
+شكل ال ايزو اكتين اللي فيه مجموعة ال ايزو و بنكمل
+
+505
+00:46:18,900 --> 00:46:24,500
+لكم كربونات تمانية الان هدولة الكنز لو أخدنا هذا
+
+506
+00:46:24,500 --> 00:46:29,880
+الجازولين وقود السيارات و حطناه فوق ميهبيخلط
+
+507
+00:46:29,880 --> 00:46:34,640
+معاها، بيدوب فيها؟ لأ، فإذا الالكينز they are
+
+508
+00:46:34,640 --> 00:46:39,880
+water insoluble، ليش؟ لأن هدول المركبات، القوة
+
+509
+00:46:39,880 --> 00:46:46,010
+اللي فيهم، London forces، بينما الميهالهيدروجين
+
+510
+00:46:46,010 --> 00:46:52,810
+بوندنج فيها الميّه بولر والالكينز نان بولر فالبولر
+
+511
+00:46:52,810 --> 00:46:57,370
+والنان بولر بخلطوش مع بعض are water insoluble طبعا
+
+512
+00:46:57,370 --> 00:47:02,000
+كونوا القوة اللي موجودة فيهم ضعيفةاللي هي أضعف نوع
+
+513
+00:47:02,000 --> 00:47:05,440
+من القوة الـ London Forces معناه ذلك الجزيئات
+
+514
+00:47:05,440 --> 00:47:10,880
+بتاعتهم ممسوقة ببعضها بقوة ولا بقوة ضعيفة؟ بقوة
+
+515
+00:47:10,880 --> 00:47:16,160
+ضعيفة، هذا بيقدر إلى إنها بتتبخر بشكل سريع وإلى أن
+
+516
+00:47:16,160 --> 00:47:22,000
+نقطة الغليان تبعتها أيضا منخفضة جدا ولذلك لو أنا
+
+517
+00:47:22,000 --> 00:47:25,380
+إجيت اتطلعت على ال canes اللي في الجدول هلاحظ ال
+
+518
+00:47:25,380 --> 00:47:32,540
+methane غازالإيثين غاز، البروبين غاز، البيوتين
+
+519
+00:47:32,540 --> 00:47:36,600
+غاز، اللي هو الغاز المنزلي، غاز الطهي المنزلي، هو
+
+520
+00:47:36,600 --> 00:47:41,740
+البيوتين البنتين بيبدأ يصير سائل بنقطة غليان حوالي
+
+521
+00:47:41,740 --> 00:47:46,500
+36 درجة مؤوية، نقطة غليان منخفضة البنزين نفسه نقطة
+
+522
+00:47:46,500 --> 00:47:49,920
+غليانه منخفضة، ولذلك بيتبقر بسرعة وبيعمل حرائق
+
+523
+00:47:49,920 --> 00:47:56,570
+بسرعةواضح؟ كل هذا الكلام لأن القوة الترابط اللي
+
+524
+00:47:56,570 --> 00:48:01,070
+موجودة فيه هي ال London forces اللي هي أضعف أنواع
+
+525
+00:48:01,070 --> 00:48:05,550
+قوة الترابط فالجزيئات غير مترابطة بقوة و من هنا
+
+526
+00:48:05,550 --> 00:48:10,910
+بيكون ال alkanes لهم low boiling points بالتأكيد
+
+527
+00:48:10,910 --> 00:48:15,720
+ال cane من ذرةنقطة غليانه اقل من ذرتين اقل من
+
+528
+00:48:15,720 --> 00:48:20,460
+تلاتة وكل ما يبدو يزيدوا عدد ذرات الالكين ايش
+
+529
+00:48:20,460 --> 00:48:26,020
+بيصيلا نقطة الغليان بتزيد واضح؟أخر نقطة اليوم
+
+530
+00:48:26,020 --> 00:48:31,560
+بنحكيها أن الالكينز لنفس المركب يعني لنفس العدد
+
+531
+00:48:31,560 --> 00:48:36,580
+الخمسة مثلا ممكن تكون chain متسلسلة و ممكن تكون
+
+532
+00:48:36,580 --> 00:48:39,900
+branched معناة chain مرة تانية أن الخمسة ورا بعض
+
+533
+00:48:39,900 --> 00:48:44,020
+branched هي عندي واحد اتنين تلاتة مثلا في البنتين
+
+534
+00:48:44,020 --> 00:48:49,800
+و من موقع اتنين اعملت تفرعينهنا خمس ذرات وهنا خمس
+
+535
+00:48:49,800 --> 00:48:53,560
+ذرات الخمس هذول جايين إيش؟ ورا بعض بقول عنهم chain
+
+536
+00:48:53,560 --> 00:49:00,140
+compounds هذول برانش دائما بنقول برانش الكنز have
+
+537
+00:49:00,140 --> 00:49:02,840
+lower boiling points than the corresponding long
+
+538
+00:49:02,840 --> 00:49:10,620
+chain of kens يعني هذا و هذا له نفس الصيغة C5H12
+
+539
+00:49:10,620 --> 00:49:17,970
+لكن مين له نقطة غليان أعلى؟الـ Chain أقل ال branch
+
+540
+00:49:17,970 --> 00:49:23,330
+ليش؟ لأن ال branch بيكون عامل زي الكورة الآن
+
+541
+00:49:23,330 --> 00:49:27,990
+تخيلوا لو حطيتوا أنتوا نفسكم تلت كورات هيك فوق بعض
+
+542
+00:49:27,990 --> 00:49:33,130
+بهذا الشكل هل يتورا بينهم مسافات ارتباط قوية كتير؟
+
+543
+00:49:33,130 --> 00:49:37,620
+هاي بس سطح الارتباطواضحة الفكرة؟ فالجزء اللي
+
+544
+00:49:37,620 --> 00:49:42,220
+branched بصير أعمل زي الكورة، الآن الكورات بحطها
+
+545
+00:49:42,220 --> 00:49:45,880
+بشكل تستقر فوق بعض، يعني أنا بقدر أحطها دولة تلاتة
+
+546
+00:49:45,880 --> 00:49:51,610
+فوق بعض ويثبتوا؟ لأليش؟ لأنه مافيش سطح التقاء كبير
+
+547
+00:49:51,610 --> 00:49:55,730
+بينهم ولذلك الـbranched alkanes they have lower
+
+548
+00:49:55,730 --> 00:49:59,170
+boiling points than the corresponding long chain
+
+549
+00:49:59,170 --> 00:50:03,210
+alkanes هذه مبادئ عامة بال physical properties
+
+550
+00:50:03,210 --> 00:50:06,090
+للالكنز وبهيك بننهي اليوم ان شاء الله
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..0bc2fc225acaaa5ba7d8b247a9640a6c2c15948f
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.json
@@ -0,0 +1 @@
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بيعني Iso هذا التفرع كاربون طالع منها مجموعتين مثل Iso لاحظوا هنا كان عندكم تقريبا نفس الاشي انتبهوا معي", "tokens": [2407, 6027, 22488, 3215, 28242, 3224, 5551, 25513, 27884, 11933, 15730, 29538, 9673, 7435, 2304, 2407, 27884, 11933, 1829, 8592, 24525, 2304, 11296, 286, 539, 5955, 5088, 29538, 9673, 7435, 2304, 2407, 27884, 24525, 2304, 11296, 286, 539, 5955, 5088, 13672, 1829, 13412, 26895, 8315, 8978, 11296, 8032, 25708, 2288, 29245, 9957, 8608, 2407, 16606, 9154, 34105, 34051, 9154, 34105, 34051, 9154, 34105, 39896, 286, 539, 23758, 25124, 28820, 4724, 40228, 22653, 286, 539, 23758, 16712, 5172, 2288, 3615, 9122, 9640, 3555, 11536, 23032, 6027, 3615, 9154, 11296, 3714, 7435, 2304, 2407, 34268, 9957, 50113, 1211, 286, 539, 20193, 5016, 19913, 14407, 34105, 25961, 43242, 24793, 6055, 4587, 16572, 3555, 995, 8717, 36178, 2423, 33599, 1829, 16472, 2655, 3555, 3224, 14407, 20449, 1829], "avg_logprob": -0.19065019716658899, "compression_ratio": 2.0045045045045047, "no_speech_prob": 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"probability": 0.9646484375}, {"start": 1358.27, "end": 1359.15, "word": " CH3", "probability": 0.96484375}, {"start": 1359.15, "end": 1361.29, "word": " بنسميها", "probability": 0.9158935546875}, {"start": 1361.29, "end": 1363.35, "word": " tertiarybutyl", "probability": 0.7918701171875}], "temperature": 1.0}, {"id": 59, "seek": 137289, "start": 1364.11, "end": 1372.89, "text": "Tertiarybutyl مرات بيكتبوا ترت اختصارا و مرات بيحطوا T يعني ممكن تلاقوا T", "tokens": [51, 911, 29104, 5955, 5088, 3714, 2288, 9307, 4724, 1829, 4117, 2655, 3555, 14407, 6055, 43500, 1975, 46456, 9381, 9640, 995, 4032, 3714, 2288, 9307, 4724, 1829, 5016, 9566, 14407, 314, 37495, 22653, 3714, 43020, 6055, 15040, 4587, 14407, 314], "avg_logprob": -0.2705792682926829, "compression_ratio": 1.202020202020202, "no_speech_prob": 0.0, "words": [{"start": 1364.11, "end": 1365.55, "word": "Tertiarybutyl", "probability": 0.5654296875}, {"start": 1365.55, "end": 1366.25, "word": " مرات", "probability": 0.73974609375}, {"start": 1366.25, "end": 1366.87, "word": " بيكتبوا", "probability": 0.8538411458333334}, {"start": 1366.87, "end": 1367.37, "word": " ترت", "probability": 0.58935546875}, {"start": 1367.37, "end": 1369.13, "word": " اختصارا", "probability": 0.92109375}, {"start": 1369.13, "end": 1369.21, "word": " و", "probability": 0.9169921875}, {"start": 1369.21, "end": 1369.51, "word": " مرات", "probability": 0.9010416666666666}, {"start": 1369.51, "end": 1369.99, "word": " بيحطوا", "probability": 0.79814453125}, {"start": 1369.99, "end": 1370.21, "word": " T", "probability": 0.5380859375}, {"start": 1370.21, "end": 1370.89, "word": " يعني", "probability": 0.859619140625}, {"start": 1370.89, "end": 1371.21, "word": " ممكن", "probability": 0.9736328125}, {"start": 1371.21, "end": 1372.25, "word": " تلاقوا", "probability": 0.8638916015625}, {"start": 1372.25, "end": 1372.89, "word": " T", "probability": 0.7119140625}], "temperature": 1.0}, {"id": 60, "seek": 139772, "start": 1374.5, "end": 1397.72, "text": "بيوتل أو تيرت بيوتل تيرتشار بيوتل في كل الأحوال لما نحتاج نشوف هذه الأشياء من ناحية alphabetical أي حرف اللي بنعتمده لأنه بعد شوية لما نسمي المراكبات يلزمنا الترتيب ال alphabetical لبيوتل حتى لو كنتي بتاعة بيوتل هي حرف إيش", "tokens": [3555, 1829, 35473, 1211, 34051, 6055, 13546, 2655, 4724, 1829, 35473, 1211, 6055, 13546, 2655, 8592, 9640, 4724, 1829, 35473, 1211, 8978, 28242, 16247, 5016, 2407, 6027, 5296, 15042, 8717, 33753, 26108, 8717, 8592, 38688, 29538, 16247, 8592, 1829, 16606, 9154, 8717, 39319, 10632, 23339, 804, 36632, 11331, 28480, 13672, 1829, 44945, 34268, 2304, 3215, 3224, 5296, 33456, 3224, 39182, 13412, 2407, 10632, 5296, 15042, 8717, 38251, 1829, 9673, 23557, 4117, 3555, 9307, 7251, 1211, 11622, 2304, 8315, 16712, 2288, 31371, 3555, 2423, 23339, 804, 5296, 21292, 35473, 1211, 11331, 49975, 45164, 9122, 29399, 1829, 39894, 995, 27884, 4724, 1829, 35473, 1211, 39896, 11331, 28480, 11933, 1829, 8592], "avg_logprob": -0.20541857688798817, "compression_ratio": 1.7887323943661972, "no_speech_prob": 0.0, "words": [{"start": 1374.5, "end": 1375.36, "word": "بيوتل", "probability": 0.5971832275390625}, {"start": 1375.36, "end": 1376.04, "word": " أو", "probability": 0.7099609375}, {"start": 1376.04, "end": 1376.94, "word": " تيرت", "probability": 0.6182454427083334}, {"start": 1376.94, "end": 1377.56, "word": " بيوتل", "probability": 0.84228515625}, {"start": 1377.56, "end": 1378.18, "word": " تيرتشار", "probability": 0.7025390625}, {"start": 1378.18, "end": 1378.78, "word": " بيوتل", "probability": 0.9644775390625}, {"start": 1378.78, "end": 1379.46, "word": " في", "probability": 0.440185546875}, {"start": 1379.46, "end": 1379.7, "word": " كل", "probability": 0.978515625}, {"start": 1379.7, "end": 1380.42, "word": " الأحوال", "probability": 0.9879150390625}, {"start": 1380.42, "end": 1381.06, "word": " لما", "probability": 0.7117919921875}, {"start": 1381.06, "end": 1381.62, "word": " نحتاج", "probability": 0.98193359375}, {"start": 1381.62, "end": 1382.16, "word": " نشوف", "probability": 0.9606119791666666}, {"start": 1382.16, "end": 1382.64, "word": " هذه", "probability": 0.8740234375}, {"start": 1382.64, "end": 1383.26, "word": " الأشياء", "probability": 0.9921875}, {"start": 1383.26, "end": 1383.62, "word": " من", "probability": 0.98779296875}, {"start": 1383.62, "end": 1384.08, "word": " ناحية", "probability": 0.9835611979166666}, {"start": 1384.08, "end": 1385.16, "word": " alphabetical", "probability": 0.767578125}, {"start": 1385.16, "end": 1385.72, "word": " أي", "probability": 0.71826171875}, {"start": 1385.72, "end": 1386.08, "word": " حرف", "probability": 0.996337890625}, {"start": 1386.08, "end": 1386.26, "word": " اللي", "probability": 0.91357421875}, {"start": 1386.26, "end": 1387.34, "word": " بنعتمده", "probability": 0.9494140625}, {"start": 1387.34, "end": 1388.04, "word": " لأنه", "probability": 0.7615559895833334}, {"start": 1388.04, "end": 1388.2, "word": " بعد", "probability": 0.87841796875}, {"start": 1388.2, "end": 1388.48, "word": " شوية", "probability": 0.9475911458333334}, {"start": 1388.48, "end": 1388.68, "word": " لما", "probability": 0.974609375}, {"start": 1388.68, "end": 1389.04, "word": " نسمي", "probability": 0.9025065104166666}, {"start": 1389.04, "end": 1389.78, "word": " المراكبات", "probability": 0.848828125}, {"start": 1389.78, "end": 1391.98, "word": " يلزمنا", "probability": 0.87216796875}, {"start": 1391.98, "end": 1392.48, "word": " الترتيب", "probability": 0.9267578125}, {"start": 1392.48, "end": 1392.6, "word": " ال", "probability": 0.876953125}, {"start": 1392.6, "end": 1393.5, "word": " alphabetical", "probability": 0.92724609375}, {"start": 1393.5, "end": 1394.78, "word": " لبيوتل", "probability": 0.834228515625}, {"start": 1394.78, "end": 1395.66, "word": " حتى", "probability": 0.87451171875}, {"start": 1395.66, "end": 1395.84, "word": " لو", "probability": 0.99267578125}, {"start": 1395.84, "end": 1396.14, "word": " كنتي", "probability": 0.7764485677083334}, {"start": 1396.14, "end": 1396.36, "word": " بتاعة", "probability": 0.5659586588541666}, {"start": 1396.36, "end": 1396.78, "word": " بيوتل", "probability": 0.974609375}, {"start": 1396.78, "end": 1396.88, "word": " هي", "probability": 0.837890625}, {"start": 1396.88, "end": 1397.28, "word": " حرف", "probability": 0.995849609375}, {"start": 1397.28, "end": 1397.72, "word": " إيش", "probability": 0.7858072916666666}], "temperature": 1.0}, {"id": 61, "seek": 141136, "start": 1398.26, "end": 1411.36, "text": "الـ secondary butyl حرف بيه، ال tertiary butyl حرف بيه، ال isobutyl حرف I، ال isobutyl حرف I مش حرف بيه", "tokens": [6027, 39184, 11396, 457, 5088, 11331, 28480, 4724, 1829, 3224, 12399, 2423, 38726, 29104, 457, 5088, 11331, 28480, 4724, 1829, 3224, 12399, 2423, 307, 996, 325, 5088, 11331, 28480, 286, 12399, 2423, 307, 996, 325, 5088, 11331, 28480, 286, 37893, 11331, 28480, 4724, 1829, 3224], "avg_logprob": -0.2530570619780084, "compression_ratio": 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1405.0, "word": " isobutyl", "probability": 0.72674560546875}, {"start": 1405.0, "end": 1405.58, "word": " حرف", "probability": 0.98681640625}, {"start": 1405.58, "end": 1407.4, "word": " I،", "probability": 0.616943359375}, {"start": 1407.4, "end": 1407.8, "word": " ال", "probability": 0.77392578125}, {"start": 1407.8, "end": 1408.8, "word": " isobutyl", "probability": 0.968994140625}, {"start": 1408.8, "end": 1409.18, "word": " حرف", "probability": 0.98974609375}, {"start": 1409.18, "end": 1409.62, "word": " I", "probability": 0.990234375}, {"start": 1409.62, "end": 1410.58, "word": " مش", "probability": 0.482421875}, {"start": 1410.58, "end": 1410.96, "word": " حرف", "probability": 0.84033203125}, {"start": 1410.96, "end": 1411.36, "word": " بيه", "probability": 0.8932291666666666}], "temperature": 1.0}, {"id": 62, "seek": 143860, "start": 1412.18, "end": 1438.6, "text": "واضح ال isobutyl لو قلتلكوا alphabetically ايش اول اشي باعتمدوا فيها I لكن tertiary butyl باهمل ال T وتعامل على انه حرف الأول B من ناحية alphabetical و لو حطينا هنا Chlor في شغلات مرات مش بحاجة لفهم بحاجة انكم تحفظوها زي هيك تمام يعني مش قصة tertiary butyl alphabetically", "tokens": [2407, 46958, 5016, 2423, 307, 996, 325, 5088, 45164, 12174, 1211, 2655, 23275, 14407, 23339, 984, 1975, 1829, 8592, 1975, 12610, 1975, 8592, 1829, 4724, 995, 34268, 2304, 3215, 14407, 8978, 11296, 286, 44381, 38726, 29104, 457, 5088, 4724, 995, 16095, 1211, 2423, 314, 34683, 3615, 10943, 1211, 15844, 16472, 3224, 11331, 28480, 16247, 12610, 363, 9154, 8717, 39319, 10632, 23339, 804, 4032, 45164, 11331, 9566, 1829, 8315, 34105, 761, 6746, 8978, 13412, 17082, 1211, 9307, 3714, 2288, 9307, 37893, 4724, 5016, 26108, 3660, 5296, 5172, 16095, 4724, 5016, 26108, 3660, 16472, 24793, 6055, 5016, 5172, 19913, 2407, 11296, 30767, 1829, 39896, 4117, 6055, 15042, 2304, 37495, 22653, 37893, 12174, 9381, 3660, 38726, 29104, 457, 5088, 23339, 984], "avg_logprob": -0.20824579331053406, "compression_ratio": 1.6374501992031874, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1412.18, "end": 1412.72, "word": "واضح", "probability": 0.9381510416666666}, {"start": 1412.72, "end": 1413.4, "word": " ال", "probability": 0.38037109375}, {"start": 1413.4, "end": 1414.44, "word": " isobutyl", "probability": 0.6898193359375}, {"start": 1414.44, "end": 1414.82, "word": " لو", "probability": 0.71533203125}, {"start": 1414.82, "end": 1415.34, "word": " قلتلكوا", "probability": 0.8015625}, {"start": 1415.34, "end": 1416.3, "word": " alphabetically", "probability": 0.888671875}, {"start": 1416.3, "end": 1416.52, "word": " ايش", "probability": 0.8338216145833334}, {"start": 1416.52, "end": 1416.8, "word": " اول", "probability": 0.860107421875}, {"start": 1416.8, "end": 1417.06, "word": " اشي", "probability": 0.8984375}, {"start": 1417.06, "end": 1417.68, "word": " باعتمدوا", "probability": 0.8527018229166666}, {"start": 1417.68, "end": 1418.1, "word": " فيها", "probability": 0.977783203125}, {"start": 1418.1, "end": 1418.78, "word": " I", "probability": 0.5263671875}, {"start": 1418.78, "end": 1419.34, "word": " لكن", "probability": 0.50537109375}, {"start": 1419.34, "end": 1419.9, "word": " tertiary", "probability": 0.87451171875}, {"start": 1419.9, "end": 1420.28, "word": " butyl", "probability": 0.774658203125}, {"start": 1420.28, "end": 1420.76, "word": " باهمل", "probability": 0.812744140625}, {"start": 1420.76, "end": 1420.96, "word": " ال", "probability": 0.69140625}, {"start": 1420.96, "end": 1421.18, "word": " T", "probability": 0.95166015625}, {"start": 1421.18, "end": 1422.12, "word": " وتعامل", "probability": 0.83966064453125}, {"start": 1422.12, "end": 1422.32, "word": " على", "probability": 0.90869140625}, {"start": 1422.32, "end": 1422.82, "word": " انه", "probability": 0.807373046875}, {"start": 1422.82, "end": 1423.28, "word": " حرف", "probability": 0.9873046875}, {"start": 1423.28, "end": 1423.92, "word": " الأول", "probability": 0.75341796875}, {"start": 1423.92, "end": 1424.68, "word": " B", "probability": 0.375}, {"start": 1424.68, "end": 1424.86, "word": " من", "probability": 0.9765625}, {"start": 1424.86, "end": 1425.34, "word": " ناحية", "probability": 0.9890950520833334}, {"start": 1425.34, "end": 1426.36, "word": " alphabetical", "probability": 0.9111328125}, {"start": 1426.36, "end": 1426.88, "word": " و", "probability": 0.62841796875}, {"start": 1426.88, "end": 1427.02, "word": " لو", "probability": 0.64013671875}, {"start": 1427.02, "end": 1427.44, "word": " حطينا", "probability": 0.83447265625}, {"start": 1427.44, "end": 1427.66, "word": " هنا", "probability": 0.978515625}, {"start": 1427.66, "end": 1428.22, "word": " Chlor", "probability": 0.57806396484375}, {"start": 1428.22, "end": 1429.46, "word": " في", "probability": 0.56640625}, {"start": 1429.46, "end": 1430.02, "word": " شغلات", "probability": 0.9691162109375}, {"start": 1430.02, "end": 1430.5, "word": " مرات", "probability": 0.9650065104166666}, {"start": 1430.5, "end": 1430.72, "word": " مش", "probability": 0.9873046875}, {"start": 1430.72, "end": 1431.26, "word": " بحاجة", "probability": 0.9935302734375}, {"start": 1431.26, "end": 1431.64, "word": " لفهم", "probability": 0.9163411458333334}, {"start": 1431.64, "end": 1432.08, "word": " بحاجة", "probability": 0.9334716796875}, {"start": 1432.08, "end": 1432.3, "word": " انكم", "probability": 0.546630859375}, {"start": 1432.3, "end": 1433.22, "word": " تحفظوها", "probability": 0.8865559895833334}, {"start": 1433.22, "end": 1433.52, "word": " زي", "probability": 0.94921875}, {"start": 1433.52, "end": 1434.04, "word": " هيك", "probability": 0.94970703125}, {"start": 1434.04, "end": 1435.24, "word": " تمام", "probability": 0.7560221354166666}, {"start": 1435.24, "end": 1435.58, "word": " يعني", "probability": 0.6561279296875}, {"start": 1435.58, "end": 1435.78, "word": " مش", "probability": 0.90283203125}, {"start": 1435.78, "end": 1436.18, "word": " قصة", "probability": 0.8986002604166666}, {"start": 1436.18, 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2946.42, "end": 2946.82, "word": " نفس", "probability": 0.927978515625}, {"start": 2946.82, "end": 2947.36, "word": " الصيغة", "probability": 0.9300537109375}, {"start": 2947.36, "end": 2950.62, "word": " C5H12", "probability": 0.8646240234375}, {"start": 2950.62, "end": 2951.38, "word": " لكن", "probability": 0.90771484375}, {"start": 2951.38, "end": 2951.78, "word": " مين", "probability": 0.9482421875}, {"start": 2951.78, "end": 2952.04, "word": " له", "probability": 0.91162109375}, {"start": 2952.04, "end": 2952.46, "word": " نقطة", "probability": 0.97265625}, {"start": 2952.46, "end": 2953.26, "word": " غليان", "probability": 0.9508463541666666}, {"start": 2953.26, "end": 2954.46, "word": " أعلى؟", "probability": 0.923828125}], "temperature": 1.0}, {"id": 128, "seek": 297465, "start": 2955.17, "end": 2974.65, "text": "الـ Chain أقل ال branch ليش؟ لأن ال branch بيكون عامل زي الكورة الآن تخيلوا لو حطيتوا أنتوا نفسكم تلت كورات هيك فوق بعض بهذا الشكل هل يتورا بينهم مسافات ارتباط قوية كتير؟ هاي بس سطح الارتباط", "tokens": [6027, 39184, 33252, 5551, 4587, 1211, 2423, 9819, 32239, 8592, 22807, 5296, 33456, 2423, 9819, 4724, 1829, 30544, 6225, 10943, 1211, 30767, 1829, 33251, 13063, 3660, 6024, 48506, 6055, 9778, 26895, 14407, 45164, 11331, 9566, 36081, 14407, 14739, 2655, 14407, 8717, 36178, 24793, 6055, 1211, 2655, 9122, 13063, 9307, 39896, 4117, 6156, 30543, 45030, 11242, 39627, 15730, 25124, 28820, 8032, 1211, 7251, 2655, 13063, 995, 49374, 16095, 47524, 31845, 9307, 1975, 43500, 3555, 41193, 12174, 2407, 10632, 9122, 2655, 13546, 22807, 8032, 47302, 4724, 3794, 8608, 9566, 5016, 2423, 9640, 2655, 3555, 41193], "avg_logprob": -0.19498005889831704, "compression_ratio": 1.6598984771573604, "no_speech_prob": 2.9206275939941406e-06, "words": [{"start": 2955.17, "end": 2955.43, "word": "الـ", "probability": 0.4093017578125}, {"start": 2955.43, "end": 2955.87, "word": " Chain", "probability": 0.38330078125}, {"start": 2955.87, "end": 2956.63, "word": " أقل", "probability": 0.9013671875}, {"start": 2956.63, "end": 2957.53, "word": " ال", "probability": 0.479736328125}, {"start": 2957.53, "end": 2957.97, "word": " branch", "probability": 0.53271484375}, {"start": 2957.97, "end": 2959.05, "word": " ليش؟", "probability": 0.619873046875}, {"start": 2959.05, "end": 2959.51, "word": " لأن", "probability": 0.93701171875}, {"start": 2959.51, "end": 2960.15, "word": " ال", "probability": 0.927734375}, {"start": 2960.15, "end": 2960.83, "word": " branch", "probability": 0.8701171875}, {"start": 2960.83, "end": 2961.59, "word": " بيكون", "probability": 0.87744140625}, {"start": 2961.59, "end": 2961.97, "word": " عامل", "probability": 0.9949544270833334}, {"start": 2961.97, "end": 2962.27, "word": " زي", "probability": 0.972412109375}, {"start": 2962.27, "end": 2962.83, "word": " الكورة", "probability": 0.82373046875}, {"start": 2962.83, "end": 2963.33, "word": " الآن", "probability": 0.5791015625}, {"start": 2963.33, "end": 2963.83, "word": " تخيلوا", "probability": 0.955078125}, {"start": 2963.83, "end": 2963.99, "word": " لو", "probability": 0.98876953125}, {"start": 2963.99, "end": 2964.55, "word": " حطيتوا", "probability": 0.9129638671875}, {"start": 2964.55, "end": 2965.21, "word": " أنتوا", "probability": 0.6741536458333334}, {"start": 2965.21, "end": 2965.91, "word": " نفسكم", "probability": 0.96826171875}, {"start": 2965.91, "end": 2966.57, "word": " تلت", "probability": 0.8680013020833334}, {"start": 2966.57, "end": 2967.05, "word": " كورات", "probability": 0.9765625}, {"start": 2967.05, "end": 2967.31, "word": " هيك", "probability": 0.75}, {"start": 2967.31, "end": 2967.53, "word": " فوق", "probability": 0.979248046875}, {"start": 2967.53, "end": 2967.99, "word": " بعض", "probability": 0.993408203125}, {"start": 2967.99, "end": 2968.67, "word": " بهذا", "probability": 0.88623046875}, {"start": 2968.67, "end": 2969.15, "word": " الشكل", "probability": 0.9921875}, {"start": 2969.15, "end": 2969.65, "word": " هل", "probability": 0.77734375}, {"start": 2969.65, "end": 2970.11, "word": " يتورا", "probability": 0.71142578125}, {"start": 2970.11, "end": 2970.41, "word": " بينهم", "probability": 0.967529296875}, {"start": 2970.41, "end": 2970.97, "word": " مسافات", "probability": 0.9669596354166666}, {"start": 2970.97, "end": 2971.51, "word": " ارتباط", "probability": 0.9600830078125}, {"start": 2971.51, "end": 2972.01, "word": " قوية", "probability": 0.9796549479166666}, {"start": 2972.01, "end": 2973.13, "word": " كتير؟", "probability": 0.899658203125}, {"start": 2973.13, "end": 2973.29, "word": " هاي", "probability": 0.675537109375}, {"start": 2973.29, "end": 2973.79, "word": " بس", "probability": 0.7376708984375}, {"start": 2973.79, "end": 2974.09, "word": " سطح", "probability": 0.96728515625}, {"start": 2974.09, "end": 2974.65, "word": " الارتباط", "probability": 0.95498046875}], "temperature": 1.0}, {"id": 129, "seek": 298828, "start": 2975.6, "end": 2988.28, "text": "واضحة الفكرة؟ فالجزء اللي branched بصير أعمل زي الكورة، الآن الكورات بحطها بشكل تستقر فوق بعض، يعني أنا بقدر أحطها دولة تلاتة فوق بعض ويثبتوا؟ لأ", "tokens": [2407, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 6156, 6027, 7435, 11622, 38207, 13672, 1829, 9819, 292, 4724, 9381, 13546, 5551, 25957, 1211, 30767, 1829, 33251, 13063, 3660, 12399, 6024, 48506, 33251, 13063, 9307, 4724, 5016, 9566, 11296, 4724, 8592, 28820, 6055, 14851, 4587, 2288, 6156, 30543, 45030, 11242, 12399, 37495, 22653, 41850, 4724, 28543, 2288, 5551, 5016, 9566, 11296, 11778, 12610, 3660, 6055, 1211, 9307, 3660, 6156, 30543, 45030, 11242, 4032, 1829, 12984, 3555, 2655, 14407, 22807, 5296, 10721], "avg_logprob": -0.1556712904094178, "compression_ratio": 1.5389221556886228, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2975.6, "end": 2976.1, "word": "واضحة", "probability": 0.869873046875}, {"start": 2976.1, "end": 2976.92, "word": " الفكرة؟", "probability": 0.8798828125}, {"start": 2976.92, "end": 2977.5, "word": " فالجزء", "probability": 0.87958984375}, {"start": 2977.5, "end": 2977.62, "word": " اللي", "probability": 0.5662841796875}, {"start": 2977.62, "end": 2978.14, "word": " branched", "probability": 0.727294921875}, {"start": 2978.14, "end": 2978.58, "word": " بصير", "probability": 0.7815755208333334}, {"start": 2978.58, "end": 2979.0, "word": " أعمل", "probability": 0.7941080729166666}, {"start": 2979.0, "end": 2979.28, "word": " زي", "probability": 0.96337890625}, {"start": 2979.28, "end": 2980.08, "word": " الكورة،", "probability": 0.8494873046875}, {"start": 2980.08, "end": 2980.54, "word": " الآن", "probability": 0.7017822265625}, {"start": 2980.54, "end": 2981.48, "word": " الكورات", "probability": 0.97412109375}, {"start": 2981.48, "end": 2982.22, "word": " بحطها", "probability": 0.971435546875}, {"start": 2982.22, "end": 2982.84, "word": " بشكل", "probability": 0.9215494791666666}, {"start": 2982.84, "end": 2983.64, "word": " تستقر", "probability": 0.8663330078125}, {"start": 2983.64, "end": 2983.86, "word": " فوق", "probability": 0.97021484375}, {"start": 2983.86, "end": 2984.2, "word": " بعض،", "probability": 0.9342447916666666}, {"start": 2984.2, "end": 2984.28, "word": " يعني", "probability": 0.97412109375}, {"start": 2984.28, "end": 2984.48, "word": " أنا", "probability": 0.7705078125}, {"start": 2984.48, "end": 2984.82, "word": " بقدر", "probability": 0.9752604166666666}, {"start": 2984.82, "end": 2985.2, "word": " أحطها", "probability": 0.873046875}, {"start": 2985.2, "end": 2985.48, "word": " دولة", "probability": 0.8968098958333334}, {"start": 2985.48, "end": 2985.88, "word": " تلاتة", "probability": 0.86181640625}, {"start": 2985.88, "end": 2986.12, "word": " فوق", "probability": 0.979248046875}, {"start": 2986.12, "end": 2986.48, "word": " بعض", "probability": 0.99462890625}, {"start": 2986.48, "end": 2987.84, "word": " ويثبتوا؟", "probability": 0.8602818080357143}, {"start": 2987.84, "end": 2988.28, "word": " لأ", "probability": 0.886962890625}], "temperature": 1.0}, {"id": 130, "seek": 300609, "start": 2989.13, "end": 3006.09, "text": "ليش؟ لأنه مافيش سطح التقاء كبير بينهم ولذلك الـbranched alkanes they have lower boiling points than the corresponding long chain alkanes هذه مبادئ عامة بال physical properties للالكنز وبهيك بننهي اليوم ان شاء الله", "tokens": [20292, 8592, 22807, 5296, 33456, 3224, 19446, 41185, 8592, 8608, 9566, 5016, 16712, 4587, 16606, 9122, 3555, 13546, 49374, 16095, 35525, 8848, 23275, 2423, 39184, 1443, 4778, 292, 419, 5225, 279, 436, 362, 3126, 16208, 2793, 813, 264, 11760, 938, 5021, 419, 5225, 279, 29538, 3714, 3555, 18513, 19986, 6225, 10943, 3660, 20666, 4001, 7221, 24976, 6027, 19452, 11622, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984], "avg_logprob": -0.26520269062068014, "compression_ratio": 1.360730593607306, "no_speech_prob": 0.0, "words": [{"start": 2989.13, "end": 2989.59, "word": "ليش؟", "probability": 0.6493326822916666}, {"start": 2989.59, "end": 2989.77, "word": " لأنه", "probability": 0.7687174479166666}, {"start": 2989.77, "end": 2990.13, "word": " مافيش", "probability": 0.9306640625}, {"start": 2990.13, "end": 2990.55, "word": " سطح", "probability": 0.9645182291666666}, {"start": 2990.55, "end": 2991.13, "word": " التقاء", "probability": 0.7957356770833334}, {"start": 2991.13, "end": 2991.61, "word": " كبير", "probability": 0.9837239583333334}, {"start": 2991.61, "end": 2992.19, "word": " بينهم", "probability": 0.968994140625}, {"start": 2992.19, "end": 2993.21, "word": " ولذلك", "probability": 0.8274739583333334}, {"start": 2993.21, "end": 2994.25, "word": " الـbranched", "probability": 0.65712890625}, {"start": 2994.25, "end": 2994.83, "word": " alkanes", "probability": 0.655029296875}, {"start": 2994.83, "end": 2995.11, "word": " they", "probability": 0.1942138671875}, {"start": 2995.11, "end": 2995.37, "word": " have", "probability": 0.9599609375}, {"start": 2995.37, "end": 2995.73, "word": " lower", "probability": 0.84814453125}, {"start": 2995.73, "end": 2996.11, "word": " boiling", "probability": 0.9599609375}, {"start": 2996.11, "end": 2996.53, "word": " points", "probability": 0.85791015625}, {"start": 2996.53, "end": 2996.75, "word": " than", "probability": 0.935546875}, {"start": 2996.75, "end": 2996.95, "word": " the", "probability": 0.86474609375}, {"start": 2996.95, "end": 2997.79, "word": " corresponding", "probability": 0.67919921875}, {"start": 2997.79, "end": 2998.65, "word": " long", "probability": 0.456298828125}, {"start": 2998.65, "end": 2999.17, "word": " chain", "probability": 0.84375}, {"start": 2999.17, "end": 3000.07, "word": " alkanes", "probability": 0.8976236979166666}, {"start": 3000.07, "end": 3000.61, "word": " هذه", "probability": 0.6943359375}, {"start": 3000.61, "end": 3001.73, "word": " مبادئ", "probability": 0.951904296875}, {"start": 3001.73, "end": 3002.11, "word": " عامة", "probability": 0.9959309895833334}, {"start": 3002.11, "end": 3002.23, "word": " بال", "probability": 0.70556640625}, {"start": 3002.23, "end": 3002.63, "word": " physical", "probability": 0.463134765625}, {"start": 3002.63, "end": 3003.21, "word": " properties", "probability": 0.69189453125}, {"start": 3003.21, "end": 3004.15, "word": " للالكنز", "probability": 0.555908203125}, {"start": 3004.15, "end": 3004.93, "word": " وبهيك", "probability": 0.8045654296875}, {"start": 3004.93, "end": 3005.31, "word": " بننهي", "probability": 0.928466796875}, {"start": 3005.31, "end": 3005.59, "word": " اليوم", "probability": 0.968017578125}, {"start": 3005.59, "end": 3005.73, "word": " ان", "probability": 0.51904296875}, {"start": 3005.73, "end": 3005.99, "word": " شاء", "probability": 0.9736328125}, {"start": 3005.99, "end": 3006.09, "word": " الله", "probability": 0.9453125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3006.89125, "duration_after_vad": 2900.3418749999923}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c8c4d934a7f4dc8383bcc7c8870547450df2cb4a
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/pdzlULxzAp0_raw.srt
@@ -0,0 +1,2212 @@
+1
+00:00:20,770 --> 00:00:26,070
+بسم الله الرحمن الرحيم المرة الماضية بدأنا معكم في
+
+2
+00:00:26,070 --> 00:00:30,810
+الفصل الثاني بونوان ال alkanes and cycloalkanes
+
+3
+00:00:30,810 --> 00:00:37,130
+ربما حكينا فكرة في البداية عن تصنيفات ال alkanes
+
+4
+00:00:37,130 --> 00:00:41,350
+أو ال hydrocarbons ل saturated alkanes بقولنا
+
+5
+00:00:41,350 --> 00:00:46,350
+هدولة نوعين اللي همالالكينز والسايكلوالكينز و
+
+6
+00:00:46,350 --> 00:00:50,110
+unsaturated hydrocarbons اللي منها المراكبات اللي
+
+7
+00:00:50,110 --> 00:00:52,470
+فيها double bond و triple bond في الالكينز
+
+8
+00:00:52,470 --> 00:00:59,290
+والالكاينز بدنا نتعرف على الالكينز وقلنا هذه سلاسل
+
+9
+00:00:59,290 --> 00:01:05,200
+وممكن أن تكون مراكباتمتفرعة وهذا يؤدي الى تكون عدد
+
+10
+00:01:05,200 --> 00:01:11,340
+كبير جدا من ال isomers او المتشكلات ال isomers زى
+
+11
+00:01:11,340 --> 00:01:16,780
+ما اتفقنا فى ال alkanes بتبدأ تظهر وقتاش لما بنصل
+
+12
+00:01:16,780 --> 00:01:20,080
+لاربع ذرات كربون يعنى لو عندنا ذرة كربون واحدة
+
+13
+00:01:20,080 --> 00:01:24,480
+عندنا مركب واحد فقط ميثين بعدين ايثين بروبين هذا
+
+14
+00:01:24,480 --> 00:01:28,900
+منه مركب واحد لكن لما ابدي اجى احط اربع ذرات كربون
+
+15
+00:01:28,900 --> 00:01:34,130
+ارتبهمصار في عنده احتمالين لترتيبهم اما ان يرتبوا
+
+16
+00:01:34,130 --> 00:01:39,850
+بشكل متسلسل chain structure و بيكون اسم المركب
+
+17
+00:01:39,850 --> 00:01:45,210
+بيوتين او بشكل branch و بيكون اسم المركب ايزو
+
+18
+00:01:45,210 --> 00:01:48,770
+بيوتين و اتكلمنا بعد هيك عن البنتين انه بيكون
+
+19
+00:01:48,770 --> 00:01:53,930
+تلاتة isomers و بعد ذلك اعطيناكم واجب انكوا تجربوا
+
+20
+00:01:53,930 --> 00:02:00,170
+انتوا تتعبوا و ترسموا الخمسةstructures of hexane
+
+21
+00:02:00,170 --> 00:02:06,010
+والمفروض يكون الأمر بالنسبة لكم مش صعب كثير انه
+
+22
+00:02:06,010 --> 00:02:10,830
+تجيبوا 6 ذرات كربون تجربوا ما لم تعملوا هذا الأمر
+
+23
+00:02:10,830 --> 00:02:14,230
+بالإيد و بالجلم لرصاص و بالورق و تتعبوا فيه كثير
+
+24
+00:02:14,230 --> 00:02:20,770
+مابفيدش ان انا اعمله بكل الأحوال هذه وجفنا
+
+25
+00:02:20,770 --> 00:02:26,630
+اخر شي عند ال structure ofميثين وقولنا ان الميثين
+
+26
+00:02:26,630 --> 00:02:32,290
+ماخد الـ tetrahedral structure اللي له أربعة أوجه
+
+27
+00:02:32,290 --> 00:02:38,390
+وهذا أفضل شئ نتعامل معه نرسمه بسهولة اننا نعمله
+
+28
+00:02:38,390 --> 00:02:41,810
+بالشكل اللي موجود بين اديكم تخيل انه عندنا مستويين
+
+29
+00:02:41,960 --> 00:02:48,200
+مستوى أفقي للأمام ومستوى متعامد عليه للخلف هذا
+
+30
+00:02:48,200 --> 00:02:51,960
+المستوى الأفقي للأمام بيكون فيه ذارتين هيدروجين في
+
+31
+00:02:51,960 --> 00:02:56,880
+زاوية 109.5 والمستوى الخلفي أيضا في ذارتين
+
+32
+00:02:56,880 --> 00:03:02,320
+هيدروجينبزاوية 109.5، الآن باقي الزاوية أيضًا 109
+
+33
+00:03:02,320 --> 00:03:05,940
+.5، يعني لو واحد .. لو واحدة بدأ تاخد بين هذه
+
+34
+00:03:05,940 --> 00:03:08,260
+الهيدروجين اللي في المستوى الأمامي و اللي في
+
+35
+00:03:08,260 --> 00:03:14,100
+المستوى الخلفي و انقيس الزاوية 109.5اللي اتوقفنا
+
+36
+00:03:14,100 --> 00:03:19,020
+عنده كيف يرسم هذا الشكل بالفراغ كيف يرسم هذا الشكل
+
+37
+00:03:19,020 --> 00:03:23,860
+بالفراغ قولنا أفضل شيء أنه نرسمه بهذه الطريقة
+
+38
+00:03:23,860 --> 00:03:29,920
+نستعمل ال wedges أو الأسافير بحيث أنه الأشياء اللي
+
+39
+00:03:29,920 --> 00:03:34,400
+للأمام عادة بنعملها ب solid wedge و الأشياء اللي
+
+40
+00:03:34,400 --> 00:03:39,360
+للخلف عادة بنعملها ب dashed wedgeواضح؟ وهذا اللي
+
+41
+00:03:39,360 --> 00:03:43,860
+موجود عندنا الان اذا احنا بندقيق شوية في هذا الشكل
+
+42
+00:03:43,860 --> 00:03:49,360
+هنلاحظ ان الوجه له رأس head و له base قاعدة
+
+43
+00:03:49,360 --> 00:03:56,250
+القاعدة اللي هي عريضة زي هذه و الرأساللي بيكون
+
+44
+00:03:56,250 --> 00:04:02,030
+رفيع هل يا ترى هناك معنى لما انا اجي ارسم مثلا هذا
+
+45
+00:04:02,030 --> 00:04:07,370
+solid wedge تكون القاعدة فيه على جهة الهيدروجين و
+
+46
+00:04:07,370 --> 00:04:11,650
+الرأس على جهة الكاربون لما اجي ارسم ورا ال dashed
+
+47
+00:04:11,650 --> 00:04:16,690
+wedge تكون القاعدة على جهة الكاربون و الرأس على
+
+48
+00:04:16,690 --> 00:04:22,210
+جهة الهيدروجين هذا الكلام بالتأكيد له معنى شو
+
+49
+00:04:22,210 --> 00:04:27,730
+معنى؟ هذا تعبير عنالرسم في الفراغ دائما احنا
+
+50
+00:04:27,730 --> 00:04:32,070
+متعودين .. دائما احنا متعودين ان الشغلة اللى بتكون
+
+51
+00:04:32,070 --> 00:04:37,590
+قريبة علينا كبيرة بتبين كل ما بعدت عننا بتبين ايش
+
+52
+00:04:37,590 --> 00:04:41,150
+صغيرة يعني الناس اللى بيشوفوا الطائرة في المطار
+
+53
+00:04:41,150 --> 00:04:46,710
+طيارة كبيرة بتاخد خمسمية راكب واضح؟ لما بتبعد كتير
+
+54
+00:04:46,710 --> 00:04:53,610
+في السماء بتشوفوا الطائرة نقطة فكل شيء قريب علينا
+
+55
+00:04:54,670 --> 00:05:00,010
+كبير كلما بقعد صغر حتى لو انتوا بترسموا شارع مثلا
+
+56
+00:05:00,010 --> 00:05:02,950
+متعودين انكوا تقولوا هاي الإنسان هنا اللي بترسم
+
+57
+00:05:02,950 --> 00:05:09,970
+الشارع يبدأ الشارع عريض و كل ما بيبعد بيصير إيش؟
+
+58
+00:05:10,790 --> 00:05:16,210
+يصغر الان هذه الأشياء أيضا تعبير عن هذا الأمر يعني
+
+59
+00:05:16,210 --> 00:05:20,590
+لو انا امسكت هذا الشكل زي هيك هاي اللي موجودين في
+
+60
+00:05:20,590 --> 00:05:25,670
+المستوى الأفقي الان ايش القريب عليكم ذرات
+
+61
+00:05:25,670 --> 00:05:31,710
+الهيدروجين و كل ما بتروحوا على الكاربون بتبتعدوا
+
+62
+00:05:32,390 --> 00:05:38,870
+واضح و لذلك الوجه لما رسمناه خلناه عريض من عند
+
+63
+00:05:38,870 --> 00:05:43,430
+الهيدروجين و كل ما راح الكربون بيبعد بيصير ماخد
+
+64
+00:05:43,430 --> 00:05:49,690
+ايش؟ رأس المثلث فلاحظوا قريب و بيبعد عشان هيك
+
+65
+00:05:49,690 --> 00:05:55,830
+رسمناه عريض و بيصغر لو اجيت على الهيدروجين اللي في
+
+66
+00:05:55,830 --> 00:06:01,480
+الخلفأيش القريب عليكم اكثر ال carbon ولا ال
+
+67
+00:06:01,480 --> 00:06:05,580
+hydrogen؟ ال carbon و كل ما بتروحوا باتجاه ال
+
+68
+00:06:05,580 --> 00:06:12,000
+hydrogen بتبعدوا و لذلك هذا قريب بيبتعد، اذا ال
+
+69
+00:06:12,000 --> 00:06:18,780
+wedge تبعه سيبدأ كبيرامن عند الكربون و يصغر فلو
+
+70
+00:06:18,780 --> 00:06:23,900
+رسمت هذا بشكل معاكس بتكونوا بتعملوا غلط وهذا بيصير
+
+71
+00:06:23,900 --> 00:06:28,120
+جزء لما بترسموا أشكال دائما الشيء القريب عليكم
+
+72
+00:06:28,120 --> 00:06:32,280
+اعملوا الوجه تبعه قاعدته باتجاهكم و كل ما بيبعد
+
+73
+00:06:32,280 --> 00:06:39,000
+بيصغر واضح هذه الفكرة فهذا أمر يجب ان ينتبه له شكل
+
+74
+00:06:39,000 --> 00:06:44,200
+الوجه اللي للأمام و اللي للخلف الان ابتيجي نقطة
+
+75
+00:06:44,200 --> 00:06:50,590
+كثير مهمةلما احنا اضطرنا اضطرارا نرسم الشكل بهذه
+
+76
+00:06:50,590 --> 00:06:55,830
+الطريقة ليش؟ لأنه في اللوح مافيش إمكانية لشيء
+
+77
+00:06:55,830 --> 00:07:00,490
+الفراغي يعني مافيش عندي إمكانية أطلع هدول للأمام و
+
+78
+00:07:00,490 --> 00:07:06,090
+أرجع هدول للخلف فهذه الرسمة غير حقيقية الآن لما
+
+79
+00:07:06,090 --> 00:07:10,310
+باجي بقولكوا بدي أقيس الزوايا مابتكونش تقيسوا
+
+80
+00:07:10,310 --> 00:07:15,560
+الزوايا على أساس الشكلاللي مبين عندكم تقيسوها على
+
+81
+00:07:15,560 --> 00:07:20,120
+أساس الشكل الفراغي اللي موجود في ذهنكم ولذلك لما
+
+82
+00:07:20,120 --> 00:07:25,420
+أقول الزاوية بين الهيدروجين والكاربون والهيدروجين
+
+83
+00:07:25,420 --> 00:07:36,470
+على الرسمة مبينة 180180 لكن هي حقيقة جديش 109.5
+
+84
+00:07:36,470 --> 00:07:40,990
+كذلك الحال لو جيت قلتلكوا بدي الزاوية بين
+
+85
+00:07:40,990 --> 00:07:46,430
+الهيدروجين والكاربون والهيدروجين الآن على الرسمة
+
+86
+00:07:47,810 --> 00:07:54,230
+الزاوية كانت 180 لكنها حقيقة 109.5 فلو كنت معلم
+
+87
+00:07:54,230 --> 00:07:59,870
+بالأزرق و قلت له اكتبوا الزاوية ستكتبوها 109.5 مش
+
+88
+00:07:59,870 --> 00:08:06,040
+180 مابناش نخلط هذه الغلطةلو تخيلنا القاعدة ايضا
+
+89
+00:08:06,040 --> 00:08:11,680
+لو انا اجيت قلتلكم بدي الزاوية بين هذه الهيدروجين
+
+90
+00:08:11,680 --> 00:08:15,440
+اللي في المستوى الأفقي وهذه الهيدروجين الخلفية
+
+91
+00:08:15,440 --> 00:08:22,980
+الان هدولة هنا انبينين تسعين لكن هم حقيقة مية
+
+92
+00:08:22,980 --> 00:08:28,000
+وتسعة و نص ايضا واضح؟
+
+93
+00:08:29,450 --> 00:08:35,470
+فيجب الانتباه لهذا الأمر أن هذا الشكل ليس في مستوى
+
+94
+00:08:35,470 --> 00:08:40,630
+واحد وانما شكل في الفراغ وعندما تحدد الزوايا تبعته
+
+95
+00:08:40,630 --> 00:08:44,790
+يجب أن تحدد من الذهن تبعكه اللي اتعلم ان جميع
+
+96
+00:08:44,790 --> 00:08:50,970
+زوايا الـ tetrahedral structure قيمتها 109.5 كل
+
+97
+00:08:50,970 --> 00:08:55,970
+ذرة بعيدة عن التانيةمن خلال الكربون بزاوية 109.5
+
+98
+00:08:55,970 --> 00:09:03,410
+لا في زاوية شكل الميثين 90 ولا في زاوية 180 جميع
+
+99
+00:09:03,410 --> 00:09:07,510
+زاوية هيدروجين كربون هيدروجين من أي جهة بتاخدوها
+
+100
+00:09:07,510 --> 00:09:15,430
+قيمتها 109.5 هذا
+
+101
+00:09:15,430 --> 00:09:22,950
+بالنسبة لشكل الميثينإذا رجعنا لهذه ال slide اللي
+
+102
+00:09:22,950 --> 00:09:26,150
+اتكلمنا فيها عن ال الكانز بالتفصيل المميل قلنا
+
+103
+00:09:26,150 --> 00:09:30,690
+عندنا ميثين إيثين بروبين لحد البيوتين صار في عندنا
+
+104
+00:09:30,690 --> 00:09:36,330
+كام مركب اتنين الآن هدول بنسميهم الكانز من ال
+
+105
+00:09:36,330 --> 00:09:41,350
+الكانز بنطلع شغلة بنقولها ال kilogram لو يا ترى
+
+106
+00:09:41,350 --> 00:09:45,730
+احنا في نيتنا أنه بدنا نعمل تفاعل لما بدنا نعمل
+
+107
+00:09:45,730 --> 00:09:51,350
+التفاعل أول شيء أول شيء بدنا نعملهإنه بدنا نشيل
+
+108
+00:09:51,350 --> 00:09:58,870
+ذرة هيدروجين مثلا عشان نحط مكانها ذرة كلور الآن
+
+109
+00:09:58,870 --> 00:10:02,990
+لما أنا بشيل هيدروجين من الألكان يعني بدل ما
+
+110
+00:10:02,990 --> 00:10:12,030
+الميثين مثلا CH4 شو بده يصير CH3 وفي مكان سترتبط
+
+111
+00:10:12,030 --> 00:10:15,670
+به الذرة الجديدة نفترض اللي هي ذرة الكلور ممكن
+
+112
+00:10:15,670 --> 00:10:21,400
+نتخيل أنه لونها أخضرالان الالكين ناقص الهيدروجين
+
+113
+00:10:21,400 --> 00:10:27,180
+بسميه الكل جروب دائما الالكين ناقص الهيدروجين الكل
+
+114
+00:10:27,180 --> 00:10:32,520
+جروب فمن الميثين بطول مجموعة بسميها ايش مثل يعني
+
+115
+00:10:32,520 --> 00:10:40,940
+بستبدل ال N ب Y L بدل مثل N بصير مثل جروب دائما كل
+
+116
+00:10:41,530 --> 00:10:46,570
+نهاية اسم او شغلة فيها ال YL فانا بحكي عن الكلجروب
+
+117
+00:10:46,570 --> 00:10:52,330
+يعني ال cane مخصوم منه ذرة هيدروجين واضح؟ الان
+
+118
+00:10:52,330 --> 00:10:57,450
+لاحظوا لو هذه الذرة اتيت اعمل مركب طبعا المثل
+
+119
+00:10:57,450 --> 00:11:02,730
+مجموعة لكن لا تكون مركب يعني انا لما اخص منها
+
+120
+00:11:02,730 --> 00:11:07,290
+هيدروجينمباشرة مكانها الهيدروجين شو هتيجي تحط
+
+121
+00:11:07,290 --> 00:11:12,550
+اكلور نفترض الان لو كونت هذا المركب و بدي اعطيه
+
+122
+00:11:12,550 --> 00:11:19,010
+اسم باجي بسأل هذه المجموعة شو اسمها مثل وفي عند
+
+123
+00:11:19,010 --> 00:11:24,910
+اكلور فبقول المركب مثل اكلورايدبصير في ال common
+
+124
+00:11:24,910 --> 00:11:29,510
+nomenclature يعني التسمية المشهورة انه انا لو هنا
+
+125
+00:11:29,510 --> 00:11:34,110
+شيلت hydrogen و افترض و حطيت chlorine ايش هاسم
+
+126
+00:11:34,110 --> 00:11:41,070
+المركب اللي عندى مثل chloride هذه التسميةبنقول
+
+127
+00:11:41,070 --> 00:11:44,890
+عنها احنا ايش common nomenclature، ايش يعني
+
+128
+00:11:44,890 --> 00:11:49,350
+common؟ تسمية مشهورة، مش تسمية حسب القواعد، هناخد
+
+129
+00:11:49,350 --> 00:11:52,890
+نوعين من التسمية، في تسمية بنسميها IUPAC
+
+130
+00:11:52,890 --> 00:11:56,820
+Nomenclatureالتسمية لحسب القواعد اللي بنتعلمها
+
+131
+00:11:56,820 --> 00:12:00,620
+الآن وفيكم ال nomenclature التسمية المشهورة الان
+
+132
+00:12:00,620 --> 00:12:05,620
+التسمية المشهورة في مثل هذه المراكبات كيف بتتم من
+
+133
+00:12:05,620 --> 00:12:11,140
+خلال ذكر اسم المجموعة و بعد هيك بذكر اسم الهالوجين
+
+134
+00:12:11,140 --> 00:12:15,480
+فمن ال مثل لما شيلت هيدروجين صارت مثل حطيت بدلها
+
+135
+00:12:15,480 --> 00:12:20,380
+كلوه بيصير المراكب مثل كلورايد لو حطيت بدلها بروم
+
+136
+00:12:21,110 --> 00:12:27,190
+مثل البروميد و هكذا واضح؟ الان بنفس المنطق لو اجيت
+
+137
+00:12:27,190 --> 00:12:32,770
+على الاثين كام هيدروجين في الاثين بالمجمل؟ ستة
+
+138
+00:12:32,770 --> 00:12:37,170
+لاحظوا الست ذرات هيدروجين اللي في الاثين كلهم زي
+
+139
+00:12:37,170 --> 00:12:40,990
+بعض متكافئات يعني لو شيلت اي واحدة منهم هعمل
+
+140
+00:12:40,990 --> 00:12:47,670
+مجموعة شو هسميها؟ اثل زي ما انا شيلت من الميثين من
+
+141
+00:12:47,670 --> 00:12:53,840
+الأربع المتكافئات هدولةهيدروجينة وسميت المجموعة
+
+142
+00:12:53,840 --> 00:12:58,860
+مثل بقدر انا من ال اثين ايضا اشيل هيدروجينة الست
+
+143
+00:12:58,860 --> 00:13:01,880
+هيدروجينات زي بعض اي واحدة بنشيلها بتعطينا نفس
+
+144
+00:13:01,880 --> 00:13:07,080
+المجموعة هنكون مجموعة اثل لو افترضنا هذه المجموعة
+
+145
+00:13:07,080 --> 00:13:10,740
+مكان الهيدروجين اللي شيلناها حطينا كلور شو هيصير
+
+146
+00:13:10,740 --> 00:13:18,440
+مثلا مركبة اثل كلورايد و هكذا طيب لو اجينا بعد هيك
+
+147
+00:13:18,440 --> 00:13:24,620
+للبروبينوقلنا من مركب البروبين بدنا نشيل هيدروجين
+
+148
+00:13:24,620 --> 00:13:32,000
+ونعمل مجموعة بروبين مثل مثل اثان اثل بروبين بروبين
+
+149
+00:13:32,000 --> 00:13:39,000
+بيوتين بيوتل هتلاحظوا انه هيبدأ يصير عندى مشكلة
+
+150
+00:13:39,000 --> 00:13:46,610
+صغيرة انهالبروبين في كام هيدروجين؟ تمانية هي تلاتة
+
+151
+00:13:46,610 --> 00:13:50,870
+و تلاتة زي بعض وفي هنا الهيدروجينتين اللي اتفقنا
+
+152
+00:13:50,870 --> 00:13:56,470
+انه اختصرناهم في الكتابة اذا شكله العام CH3 CH2
+
+153
+00:13:56,470 --> 00:14:02,830
+CH3 تمان هيدروجينات هذولة تمان هيدروجينات كام نوع؟
+
+154
+00:14:04,020 --> 00:14:07,900
+عبارة عن نوعين التلاتة هذول والتلاتة هذول اللي على
+
+155
+00:14:07,900 --> 00:14:12,400
+الطرف زي بعض وهذه اللي موجودين في النص زي بعض فال
+
+156
+00:14:12,400 --> 00:14:16,960
+تمان هيدروجينات تعون لبروبين نوعين ستة زي بعض
+
+157
+00:14:16,960 --> 00:14:21,800
+وتنتين زي بعض لو شيلت أي واحدة من هان او من هان
+
+158
+00:14:21,800 --> 00:14:26,640
+هعمل مجموعة ولو شيلت واحدة من هان هعمل مجموعة
+
+159
+00:14:26,640 --> 00:14:30,880
+ولذلك بتلاحظوا انه لما باجي بشيل هيدروجين من
+
+160
+00:14:30,880 --> 00:14:35,460
+البروبين بعمل مجموعتيناذا شيلت من الطرف وهي جاهز
+
+161
+00:14:35,460 --> 00:14:39,420
+انه يشبك من هنا من هنا خصمة الهيدروجين هذه معناه
+
+162
+00:14:39,420 --> 00:14:44,140
+الكلام هذا بسميها مجموعة البروبيل ولو بدي اشيل من
+
+163
+00:14:44,140 --> 00:14:50,220
+النص بدي تصير ايزو بروبيل فلاحظوا معي لو بعد هيك
+
+164
+00:14:50,220 --> 00:14:56,360
+اجينا نعمل مركب نضيف كلور ممكن ناس يقولوا حطلي
+
+165
+00:14:56,360 --> 00:15:02,420
+كلور هانأو محل الهيدروجين اللي شلتها في الحالة
+
+166
+00:15:02,420 --> 00:15:06,600
+الأولى شو هيصير اسم المُركّب؟ Isopropyl chloride
+
+167
+00:15:06,600 --> 00:15:11,240
+في الحالة التانية إيش هيصير اسم المُركّب؟
+
+168
+00:15:11,240 --> 00:15:13,020
+Isopropyl chloride
+
+169
+00:15:15,840 --> 00:15:20,340
+واضح؟ و لذلك بدكوا تكونوا منتبهين أن التلات
+
+170
+00:15:20,340 --> 00:15:27,720
+كربونات كم ألكين منهم؟ واحد .. كم ألكين؟ واحد اسمه
+
+171
+00:15:27,720 --> 00:15:33,900
+بروبيل .. كم ألكي لجروب؟ تنتين .. اسمهم بروبيل و
+
+172
+00:15:33,900 --> 00:15:38,660
+ايزو بروبيل .. واضح؟هذا الكلام أكيد بحاجة إلى
+
+173
+00:15:38,660 --> 00:15:44,120
+تدريب وحفظ بعد شوية بنجي على أربع ذرات كربون هنقول
+
+174
+00:15:44,120 --> 00:15:50,960
+الأربع ذرات كربون أساسا منهم كم مركب اتنين بيوتين
+
+175
+00:15:50,960 --> 00:15:57,500
+و ايزو بيوتين طب كم الكل جروب منهم؟ بدي أجي أطلع
+
+176
+00:15:57,500 --> 00:16:05,510
+هنا كم هيدروجين عندى؟في البيوتين العادى عشرة تلاتة
+
+177
+00:16:05,510 --> 00:16:10,950
+و اتنين و اتنين و تلاتة الان هدولة المختصرين لو
+
+178
+00:16:10,950 --> 00:16:18,270
+بيناهم بالاحمر وسألنا العشرة هيدروجين هدولة كام
+
+179
+00:16:18,270 --> 00:16:27,350
+نوع كام نوع هدول العشر هيدروجين نوعين كام نوع كداش
+
+180
+00:16:27,350 --> 00:16:34,450
+و كداشستة زي بعض اللي على الطرف والاربعة هدول زي
+
+181
+00:16:34,450 --> 00:16:38,410
+بعض يعني لو شيلت hydrogen من هان او هان او هان او
+
+182
+00:16:38,410 --> 00:16:44,130
+هدول نفس الاشي هيعطيني مجموعة اش اسمها الـbutyl
+
+183
+00:16:44,130 --> 00:16:48,190
+ولو شيلت اي واحدة من هدول الاربعة هادي او هادي او
+
+184
+00:16:48,190 --> 00:16:52,030
+هادي او هادي كأن بكون شيلت عن موقع اتنين يعني من
+
+185
+00:16:52,030 --> 00:16:55,490
+هان او من هان بشيل عن موقع واحد من هان او من هان
+
+186
+00:16:55,490 --> 00:17:02,320
+بشيل عن موقع اتنينصار عندى من نفس البيوتين العادى
+
+187
+00:17:02,320 --> 00:17:08,340
+كام مجموعة؟ تنتين واحدة بسميها butyl واحدة بسميها
+
+188
+00:17:08,340 --> 00:17:12,060
+secondary butyl secondary اللى احنا شيلنا فيها
+
+189
+00:17:12,060 --> 00:17:16,410
+الهيدروجين من carbon 2الـ Butyl اللي شيلنا فيها
+
+190
+00:17:16,410 --> 00:17:21,910
+الهيدروجين من Carbon-1 مرات كتيرة هتلاحظوا إضافة و
+
+191
+00:17:21,910 --> 00:17:26,270
+ممكن تقرؤوها في بعض الكتب أن هذا الـ Butane بيروح
+
+192
+00:17:26,270 --> 00:17:32,850
+و بيحطه قدام حرف الـ N معناه بيوتين عادي المتسلسل
+
+193
+00:17:32,850 --> 00:17:37,530
+فالـ N هذي جاية من كلمة إيش؟ Normal لـ Butane
+
+194
+00:17:37,530 --> 00:17:41,270
+العادي و المجموعة تبعته هتلاحظوا مرات بيحطوا
+
+195
+00:17:41,270 --> 00:17:46,390
+قدامها حرف الـ Nفإذا قرأنا بيوتين هو نفسه
+
+196
+00:17:46,390 --> 00:17:51,270
+الانبيوتين المتسلسل وإذا قرأنا المجموعة بيوتين هي
+
+197
+00:17:51,270 --> 00:17:55,770
+نفسها الانبيوتين يعني البيوتين العادية اللي من نمر
+
+198
+00:17:55,770 --> 00:18:01,690
+واحد منها شيلنا ذرة إيش الهيدروجين الآن لو حطينا
+
+199
+00:18:01,690 --> 00:18:06,300
+هنا كلور شو هتسمي المركب؟Butylic chloride طب لو
+
+200
+00:18:06,300 --> 00:18:11,440
+حطينا هنا secondary butylic chloride الان لو اجينا
+
+201
+00:18:11,440 --> 00:18:15,120
+على ال isomers التانى اللى من اربع كربونات اللى
+
+202
+00:18:15,120 --> 00:18:21,640
+اسمه ايش ايزو بيوتين و سألنا كام هيدروجين فيه اكيد
+
+203
+00:18:21,640 --> 00:18:27,900
+عشرة لأنه التنين C4H10 طيب اللى مبينين تسعة وين
+
+204
+00:18:27,900 --> 00:18:34,190
+العاشرةالمختصرة هنا عشان يكتمل الشكل الان هدول
+
+205
+00:18:34,190 --> 00:18:41,090
+العشر هيدروجينات كام نوع؟ إذا بتطلع عليهم ممتازة
+
+206
+00:18:41,090 --> 00:18:49,180
+نوعين التسعة هدول زي بعضوهذا الهيدروجين نوع تاني
+
+207
+00:18:49,180 --> 00:18:52,680
+لأن هذا على الطرف وهذا على الطرف وهذا على الطرف
+
+208
+00:18:52,680 --> 00:18:57,020
+وهذا جاء في قلب الجزء فهذه نوع و هذول التسعة زي
+
+209
+00:18:57,020 --> 00:19:01,440
+بعض بناء على ذلك لو شيلنا أي واحدة من هذول هنعمل
+
+210
+00:19:01,440 --> 00:19:09,160
+مجموعةماذا نسمي المجموعة؟ انظروا معي هنا CH3 CH
+
+211
+00:19:09,160 --> 00:19:12,920
+CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+212
+00:19:12,920 --> 00:19:12,920
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+213
+00:19:12,920 --> 00:19:13,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+214
+00:19:13,020 --> 00:19:13,200
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+215
+00:19:13,200 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+216
+00:19:13,560 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+217
+00:19:13,560 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+218
+00:19:13,560 --> 00:19:15,980
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+219
+00:19:15,980 --> 00:19:20,860
+CH2 CH2 CH2 CH2 CH2والعدد كله أربعة إذا هذه
+
+220
+00:19:20,860 --> 00:19:27,200
+المجموعة إيش اسمها Isobutyl هذه المجموعة اسمها
+
+221
+00:19:27,200 --> 00:19:30,680
+Isobutyl اللي شيلنا فيها هيدروجين سواء من هنا أو
+
+222
+00:19:30,680 --> 00:19:36,160
+من هنا أو من هنا هي Iso هذا الشكل بيعني Iso هذا
+
+223
+00:19:36,160 --> 00:19:40,120
+التفرع كاربون طالع منها مجموعتين مثل Iso لاحظوا
+
+224
+00:19:40,120 --> 00:19:46,290
+هنا كان عندكم تقريبا نفس الاشي انتبهوا معيcarbon
+
+225
+00:19:46,290 --> 00:19:50,190
+منها مجموعتين مثل شو قلنا ايزو العدد الكلي لل
+
+226
+00:19:50,190 --> 00:19:56,810
+carbons كم كان تلاتة ولذلك سمناها ايزو بروبل الان
+
+227
+00:19:56,810 --> 00:20:01,790
+carbon طالع منها مجموعتين مثل ايزو و العدد الكلي
+
+228
+00:20:01,790 --> 00:20:08,630
+اربعة اذا صارت ايزوبيوتل لو الان بدى اقولها واحدة
+
+229
+00:20:08,630 --> 00:20:13,050
+طيب ال ISO pentel مثلا او ال ISO hexel بتقدر
+
+230
+00:20:13,050 --> 00:20:21,410
+ترسمها اه ع طول بقول هي ال ISO CH3 CH3
+
+231
+00:20:21,410 --> 00:20:26,290
+CH3 الان هكذا صار عندى ISO لو قولت ISO pentel جداش
+
+232
+00:20:26,290 --> 00:20:33,220
+بدى يكون عندى خمسة خمسة اذا بدي كمان هنا CH2CH2 و
+
+233
+00:20:33,220 --> 00:20:37,100
+من هنا شيلت الهيدروجين خليني هادي مثلا لو حطيت
+
+234
+00:20:37,100 --> 00:20:41,720
+كلور هنا كل
+
+235
+00:20:41,720 --> 00:20:51,680
+المركب ايش حيصير ايزو اربعة خمسة بنتل اكلورايد لو
+
+236
+00:20:51,680 --> 00:20:59,960
+حطيت الكلور هنا ايزو بيتل اكلورايد واضح بهذا الشكل
+
+237
+00:20:59,960 --> 00:21:00,300
+بيكون
+
+238
+00:21:03,730 --> 00:21:08,510
+جزء ال ISO التلاتة هدول، الآن إذا بس صفيت عليهم
+
+239
+00:21:08,510 --> 00:21:13,470
+بقول ISO Propyl، زيدت Carbon؟ ISO Butyl، زيدت
+
+240
+00:21:13,470 --> 00:21:17,810
+Carbon؟ ISO Bentyl، الآن هنا بدكوا تنتبهوا، إذا
+
+241
+00:21:17,810 --> 00:21:23,250
+كان عندي شئ بينتهي بالنهاية YL، بحكي عن مجموعة،
+
+242
+00:21:23,250 --> 00:21:28,110
+إذا كان عندي شئ بينتهي بالنهاية N؟بحكي عن ال cane
+
+243
+00:21:28,110 --> 00:21:34,110
+يعني مثلا لو قلنا لطالبة بدنا رسمة ال ISO أكتين
+
+244
+00:21:34,110 --> 00:21:42,950
+اتخيلوا أجاكوا في الامتحان بدي ISO أكتين بتغلبش
+
+245
+00:21:42,950 --> 00:21:49,970
+مباشرة ال ISO كيف شكلها CH3 CH3
+
+246
+00:21:50,800 --> 00:21:56,600
+الان هى صار عندى جزء ال ISO بدي اكمل ل ألكين كم
+
+247
+00:21:56,600 --> 00:22:01,280
+carbon بدى يصير المجموع الكله تمانية اذا هى تلاتة
+
+248
+00:22:01,280 --> 00:22:09,160
+اربعة خمسة ستة سبعة تمانية وهنا بكتب ايش CH3 مش
+
+249
+00:22:09,160 --> 00:22:15,190
+شايل ولا هيدروجينه منه ليش لأنه نهاية N الكينلكن
+
+250
+00:22:15,190 --> 00:22:19,130
+لو كنت بدي الـ iso-octal group من وين هشيل
+
+251
+00:22:19,130 --> 00:22:25,890
+الهيدروجينة؟ من هذه الأخيرة واضح؟ الآن إذا هاي تسع
+
+252
+00:22:25,890 --> 00:22:28,410
+هيدروجينات زي بعض لو شيلت منهم هيدروجينة بطلّق
+
+253
+00:22:28,410 --> 00:22:33,370
+مجموعة isobutyl طب لو شيلت هيدروجين من النص بطلّق
+
+254
+00:22:33,370 --> 00:22:38,270
+مجموعة فيها ذرة الكاربون هذه متصلة بتلت مجموعات
+
+255
+00:22:38,270 --> 00:22:46,250
+CH3 بنسميها tertiarybutylTertiarybutyl مرات
+
+256
+00:22:46,250 --> 00:22:51,210
+بيكتبوا ترت اختصارا و مرات بيحطوا T يعني ممكن
+
+257
+00:22:51,210 --> 00:22:59,700
+تلاقوا Tبيوتل أو تيرت بيوتل تيرتشار بيوتل في كل
+
+258
+00:22:59,700 --> 00:23:04,080
+الأحوال لما نحتاج نشوف هذه الأشياء من ناحية
+
+259
+00:23:04,080 --> 00:23:08,680
+alphabetical أي حرف اللي بنعتمده لأنه بعد شوية لما
+
+260
+00:23:08,680 --> 00:23:13,500
+نسمي المراكبات يلزمنا الترتيب ال alphabetical
+
+261
+00:23:13,500 --> 00:23:19,200
+لبيوتل حتى لو كنتي بتاعة بيوتل هي حرف إيشالـ
+
+262
+00:23:19,200 --> 00:23:23,400
+secondary butyl حرف بيه، ال tertiary butyl حرف
+
+263
+00:23:23,400 --> 00:23:30,960
+بيه، ال isobutyl حرف I، ال isobutyl حرف I مش حرف
+
+264
+00:23:30,960 --> 00:23:36,520
+بيهواضح ال isobutyl لو قلتلكوا alphabetically ايش
+
+265
+00:23:36,520 --> 00:23:40,760
+اول اشي باعتمدوا فيها I لكن tertiary butyl باهمل
+
+266
+00:23:40,760 --> 00:23:45,340
+ال T وتعامل على انه حرف الأول B من ناحية
+
+267
+00:23:45,340 --> 00:23:50,720
+alphabetical و لو حطينا هنا Chlor في شغلات مرات مش
+
+268
+00:23:50,720 --> 00:23:55,780
+بحاجة لفهم بحاجة انكم تحفظوها زي هيك تمام يعني مش
+
+269
+00:23:55,780 --> 00:23:58,600
+قصة tertiary butyl alphabetically
+
+270
+00:24:00,680 --> 00:24:09,180
+B Isobutyl خلصنا واضح؟
+
+271
+00:24:09,180 --> 00:24:13,220
+مرات كتير في التسمية في ناس بصروا على ان بعض
+
+272
+00:24:13,220 --> 00:24:17,180
+الأشياء بدهم يفهموها مش كل شيء في التسمية مش كل
+
+273
+00:24:17,180 --> 00:24:22,020
+شيء في التسمية بيفهم يعني لما اجي اقول والله انت
+
+274
+00:24:22,020 --> 00:24:29,660
+اسمك هدا ليش سموكي هدا خلاص هدا خلاصواحدة تيجي
+
+275
+00:24:29,660 --> 00:24:36,640
+تقولي طب ليش سموه بروبين؟ كان سموه نوبا كلين، ليش
+
+276
+00:24:36,640 --> 00:24:43,120
+سموه بروبين؟مش كل شيء في التسمية بالذات أحيانا
+
+277
+00:24:43,120 --> 00:24:46,900
+بتلاقوا إله منطق وقاعدة زي ما أنتوا أهلكوا سموكم
+
+278
+00:24:46,900 --> 00:24:52,280
+واضح؟ زي ما أهلكوا سموكم كان في شيء معين خلهم
+
+279
+00:24:52,280 --> 00:24:58,620
+يسموا مركب معين بنزين كان في شيء معين حادث صديق
+
+280
+00:24:58,620 --> 00:25:04,780
+اللي بيرجع لتاريخ العلوم أحيانا ممكن بلحظة من
+
+281
+00:25:04,780 --> 00:25:11,700
+اللحظات يلاقي هذا الأصلواللي بيرجع لتاريخ الأسماء
+
+282
+00:25:11,700 --> 00:25:16,280
+اللي بيرجع لتاريخ الأسماء ممكن يلاقي أصل لأسماءكم
+
+283
+00:25:16,280 --> 00:25:22,460
+حتى لو أنتم مش عارفينه يعني ممكن لمن ولدتوا كان
+
+284
+00:25:22,460 --> 00:25:26,860
+متوفي عامة إلكم اسمها هودا إكراما إليها سموكوا
+
+285
+00:25:26,860 --> 00:25:30,940
+هودا الآن أنا بالنسبة إيه هذه المعلومة؟ مابعرفاش
+
+286
+00:25:30,940 --> 00:25:35,220
+ولذلك خدوا تسمية العناصر مرة بتلاقي العنصر بيقوله
+
+287
+00:25:35,220 --> 00:25:41,090
+مسمى على اسم مدينةمر على اسم بني آدم اللي اكتشفه،
+
+288
+00:25:41,090 --> 00:25:46,550
+مر على اسم كذا، فأصل الاسم قد لا نعرفه، قد يكون له
+
+289
+00:25:46,550 --> 00:25:52,930
+أصل، لكن احنا ايش؟ ما بنعرفوش، الأن بالنسبة لنا
+
+290
+00:25:52,930 --> 00:25:58,990
+هذه سيارة مرسيدس، اسم، لكن يا تورا لو أعطيتكوا
+
+291
+00:25:58,990 --> 00:26:02,170
+واجب، ليش سموا ال مرسيدس مرسيدس؟
+
+292
+00:26:05,190 --> 00:26:10,310
+فتشوا عليه و هتقولي الجواب المرة الجاية هتلاحظوا
+
+293
+00:26:10,310 --> 00:26:15,530
+إنه إله اسم ومسمى على اسم واحدة وكذا إله أصل بس مش
+
+294
+00:26:15,530 --> 00:26:18,150
+كتير بهمن الأصل في لحظة من لحظات بلاش نضيع وقت
+
+295
+00:26:18,150 --> 00:26:24,610
+كتير الآن هذه المجموعات يجب أن تتدربوا عليها يجب
+
+296
+00:26:24,610 --> 00:26:29,810
+أنكم تحفظوها بشكل جيد هذا الكلام كيف بيجي بالتدريب
+
+297
+00:26:29,810 --> 00:26:33,490
+كيف بيجي بالتدريب الآن
+
+298
+00:26:34,940 --> 00:26:39,940
+بعد ما أخدنا ال الكانز البسيطة و ال alkyl groups
+
+299
+00:26:39,940 --> 00:26:45,120
+البسيطة بدنا ناخد تسمية ال الكانز بال IUPAC system
+
+300
+00:26:45,120 --> 00:26:50,360
+حتى لو كبرت و صارت متفرعة واضح؟ يعني تسمية ال
+
+301
+00:26:50,360 --> 00:26:54,340
+الكانز الكبيرة اللي مامرتش علينا بال IUPAC system
+
+302
+00:26:54,730 --> 00:27:00,050
+ال ايوبك سيستم بيعتمد على ان نبحث عن اطول سلسلة
+
+303
+00:27:00,050 --> 00:27:05,330
+كربونية و اسم عليها يعني لو اطول سلسلة تلاتة نهاية
+
+304
+00:27:05,330 --> 00:27:11,110
+الاسم عندى ابروبين لو اربعة بيوتين تمانية اكتيل
+
+305
+00:27:12,590 --> 00:27:17,830
+فالشيء الأول بيقولنا choose the largest continuous
+
+306
+00:27:17,830 --> 00:27:23,090
+chain الان رجاء ماحدش يفهم السلسلة أن انتوا
+
+307
+00:27:23,090 --> 00:27:28,550
+بتكونوا تشوفوها مرسومة عدل بشكل أفقي أو بشكل عمودي
+
+308
+00:27:28,550 --> 00:27:33,350
+هذا الشيء ليس له معنى أنها تكون أفقي أو عمودي أو
+
+309
+00:27:33,350 --> 00:27:38,740
+مائلة معنى سلسلةذرات كربون ورا بعض بأي طريقة انا
+
+310
+00:27:38,740 --> 00:27:43,180
+ارسمهم هذا الكلام لا معنى له كله ممكن يعني لو بدأ
+
+311
+00:27:43,180 --> 00:27:48,920
+احكي مثلا عن خمسة لو بدأ احكي عن خمسة هذه سلسلة من
+
+312
+00:27:48,920 --> 00:27:59,380
+خمسة تمام وهذه سلسلة من خمسة وممكن ناخد كمان هذه
+
+313
+00:27:59,380 --> 00:28:05,360
+بهذا الشكلسلسلة من الخمسة و ممكن نرسمها بطريقة
+
+314
+00:28:05,360 --> 00:28:12,440
+تانيةسلسلة من خمسة فمعنى سلسلة ذرات متتالية وليس
+
+315
+00:28:12,440 --> 00:28:15,740
+الطريقة المرسومة بعض الناس بيقول سلسلة يعني بيشوفه
+
+316
+00:28:15,740 --> 00:28:21,800
+هيك حسب نظره أفقي أو عمودي لأ لأ معنى سلسلة كام
+
+317
+00:28:21,800 --> 00:28:25,360
+ذرة كربون متتالية فاهمنا إيش معنى سلسلة فلو قولت
+
+318
+00:28:25,360 --> 00:28:29,220
+هنا أما أطول سلسلة واحد اتنين تلاتة أربعة خمسة
+
+319
+00:28:29,220 --> 00:28:33,060
+واحد اتنين تلاتة أربعة خمسة واحد اتنين تلاتة أربعة
+
+320
+00:28:33,060 --> 00:28:36,580
+خمسة واحد اتنين تلاتة أربعة خمسة ابلاحظين مرسومين
+
+321
+00:28:36,580 --> 00:28:43,470
+بطرقمختلفة لكن بالنسبة لي معنى أطول سلسلة أطول عدد
+
+322
+00:28:43,470 --> 00:28:47,870
+متتالي من ذرات الكربون كيف يرتسموا مش مشكلة واضح و
+
+323
+00:28:47,870 --> 00:28:52,010
+لذلك بعد شوية اشوفوا مثلا هذا المركب هين اتكلمت عن
+
+324
+00:28:52,010 --> 00:28:58,190
+سلسلة اللي ماعطيها اللون الأحمر ولو مش مبينة بشكل
+
+325
+00:28:58,190 --> 00:29:04,370
+مستقيم بالنسبة لكم هذا شيء ما لهش معنى الآنحسب
+
+326
+00:29:04,370 --> 00:29:08,130
+أطول سلسلة بيكون اسم المُركّب لو كان عندنا تلاتة
+
+327
+00:29:08,130 --> 00:29:13,050
+نهاية المُركّب ابرو بين خمسة بينتين و هكذا طيب لما
+
+328
+00:29:13,050 --> 00:29:17,370
+بيصير في عندي سلسلة هذه السلسلة أكيد بيتفرع منها
+
+329
+00:29:17,370 --> 00:29:23,010
+شغلات هذه بسميها أنا الأشياء المتفرعة من السلسلة
+
+330
+00:29:23,010 --> 00:29:26,870
+اللي طالعة من أطول سلسلة carbon بقول عنها
+
+331
+00:29:26,870 --> 00:29:31,980
+substituent هذه كلمة هتصير اتمر عليكمكثير
+
+332
+00:29:31,980 --> 00:29:38,040
+Substituents اللي هي الأشياء المبدلة الان كام
+
+333
+00:29:38,040 --> 00:29:43,460
+Substituents على هذا المركب متفرع منه؟ اتنين هدولة
+
+334
+00:29:43,460 --> 00:29:48,920
+ال Substituents لازم انا اوضحهم او اوضح من اي نقطة
+
+335
+00:29:48,920 --> 00:29:53,060
+تفرعوا من اي مكان تفرعوا طب لما هذي بدي اعطيها اسم
+
+336
+00:29:53,060 --> 00:29:57,820
+هعطيها Chloro لما هذي بدي اعطيها اسم هعطيها Abromo
+
+337
+00:29:57,820 --> 00:30:02,830
+بعدين بدي اقول لك Chloro من وين اتفرعت؟من أي موقع
+
+338
+00:30:02,830 --> 00:30:08,690
+لبرومو من وين اتفرعت اذا بالزمن ترقيم لهالسلسلة
+
+339
+00:30:08,690 --> 00:30:12,950
+طالما بحكي سلسلة إذا عندي احتمالين ترقيم ممكن أبدأ
+
+340
+00:30:12,950 --> 00:30:17,770
+من هنا واحد اتنين تلاتة أربعة خمسة أو من هنا واحد
+
+341
+00:30:17,770 --> 00:30:23,130
+اتنين تلاتة أربعة خمسة من أي جهة بدي أبدأ الجهة
+
+342
+00:30:23,130 --> 00:30:26,910
+اللي بتخلي ال substituents أرقامهم أقل ما يمكن
+
+343
+00:30:26,910 --> 00:30:30,230
+يعني لو بدأت من هنا زي ما احنا عاملين ال chlorine
+
+344
+00:30:30,230 --> 00:30:34,280
+على اتنين و ال brom على تلاتة اتنين و تلاتةخمسة لو
+
+345
+00:30:34,280 --> 00:30:38,600
+بدأت منها ان واحد اتنين تلاتة اربعة صارت هذه على
+
+346
+00:30:38,600 --> 00:30:43,840
+تلاتة وهذه على اربعة تلاتة واربعة اذا ماهو اقل
+
+347
+00:30:43,840 --> 00:30:50,900
+ترقيم هذا ولذلك لما بدي ارقم دائما عند احتمالين
+
+348
+00:30:50,900 --> 00:30:56,220
+الاحتمال اللي بدي اختارهالـ lowest possible
+
+349
+00:30:56,220 --> 00:31:00,780
+numbering أقل احتمال بيعطي الـ substituents أرقام
+
+350
+00:31:00,780 --> 00:31:05,640
+طب اعرفنا الأرقام و اعرفنا الآن انه صار عندنا على
+
+351
+00:31:05,640 --> 00:31:13,800
+موقع اتنين ذرة اكلورو مظبوط ولا لأ اكلورو وع موقع
+
+352
+00:31:13,800 --> 00:31:20,410
+تلاتة ذرة ابروموبدي اكتب الاسم كامل الاسم عادة
+
+353
+00:31:20,410 --> 00:31:26,130
+بنبدأ في كتابته من الخلف للامام اول كلمة في الاسم
+
+354
+00:31:26,130 --> 00:31:30,970
+انه عندي خمسة اذا مركبه بنتين يعني اول شي بدي ابدأ
+
+355
+00:31:30,970 --> 00:31:36,070
+اكتبه بنتين هذا البنتين الان بيحمل برومو و كلورو
+
+356
+00:31:36,070 --> 00:31:41,630
+مين بدي اذكره في الاول ال alphabetical اللي بيظهر
+
+357
+00:31:41,630 --> 00:31:47,510
+اولا مين بيجي قبل ال B ولا ال Cالـ B A B C D
+
+358
+00:31:47,510 --> 00:31:51,090
+شوفتوا قبل شوية ليش أنا نبهت كل ال alphabetical في
+
+359
+00:31:51,090 --> 00:31:58,010
+المجموعات أه إذا هذا هيكون three bromo two
+
+360
+00:31:58,010 --> 00:32:03,430
+chlorobentain واضح؟ لأن أنا عندي كام substituent؟
+
+361
+00:32:03,430 --> 00:32:10,670
+هذه و هذه كيف بأذكرهم؟list substituents
+
+362
+00:32:10,670 --> 00:32:15,830
+alphabetically أذكرهم alphabetically أذكر ال B قبل
+
+363
+00:32:15,830 --> 00:32:22,650
+ال C قبل ال D قبل ال E و هكذا طبعا هنا اجتمل الاسم
+
+364
+00:32:22,650 --> 00:32:26,930
+بضيف معلومة أنه لو من مجموعة معينة كان في عندي
+
+365
+00:32:26,930 --> 00:32:33,400
+تنتينبدي أستعمل لمضاي، لو كان في عندي تلاتة ا try،
+
+366
+00:32:33,400 --> 00:32:38,700
+لو عندي أربعة تترى، و هكذا، واضح؟ انشوف أمثلة
+
+367
+00:32:38,700 --> 00:32:46,820
+إضافية، انشوفأمثلة إضافية مثلا هاي مثال أصعب شغلة
+
+368
+00:32:46,820 --> 00:32:52,220
+أنه فعلا طول أطول سلسلة يعني لو إجيت بدي أطول
+
+369
+00:32:52,220 --> 00:32:57,460
+سلسلة ممكن أعد واحد اتنين تلاتة واحد اتنين تلاتة
+
+370
+00:32:57,460 --> 00:33:03,340
+أربعة خمسة واحد اتنين تلاتة أربعة خمسة احتمالات
+
+371
+00:33:03,340 --> 00:33:07,780
+كتيرة بدي أضلني أجرب لحد ما فعلا ألاقي أطول سلسلة
+
+372
+00:33:07,780 --> 00:33:14,930
+واحد اتنين تلاتة أربعة خمسة ستة سبعةإذا مركّب إيش؟
+
+373
+00:33:14,930 --> 00:33:15,730
+هبتين
+
+374
+00:33:23,230 --> 00:33:37,450
+مثل مثل مثل مثل مثل مثل مثل مثل
+
+375
+00:33:46,950 --> 00:33:51,550
+إذا من هنا لازم أرقم فالمثلز اللي عندي وين موجودين
+
+376
+00:33:51,550 --> 00:33:57,350
+على اتنين واربعة هيصير مركبة two four dimethyl
+
+377
+00:33:57,350 --> 00:34:02,850
+heptane two four dimethyl heptane الان هاي مركب
+
+378
+00:34:02,850 --> 00:34:10,610
+تاني بتجارب كتير هتكتشف ان هاي أطول سلسلة سبعة ايش
+
+379
+00:34:10,610 --> 00:34:11,750
+بيتفرع منها
+
+380
+00:34:14,510 --> 00:34:24,070
+هذه المجموعة اللي مرت علينا ايزو بروبل و مثل الان
+
+381
+00:34:24,070 --> 00:34:30,410
+ايزو بروبل حرف I و المثل حرف M و المركب هبتين و I
+
+382
+00:34:30,410 --> 00:34:36,870
+قبل ال M اذا حيصير اسم المركب for aizobrobel انها
+
+383
+00:34:36,870 --> 00:34:38,530
+موجودة على موقع اربعة
+
+384
+00:34:41,630 --> 00:34:46,510
+لاحظوا في كل التسمية لو تطبعوا على الكمبيوتر في أي
+
+385
+00:34:46,510 --> 00:34:54,490
+فراغولا فراغ دائما قبل الرقم وبعد الرقم بتحطه شرطة
+
+386
+00:34:54,490 --> 00:34:58,330
+ما عدا إذا كنا بنحط في أول الإسم بتكون الشرطة فقط
+
+387
+00:34:58,330 --> 00:35:04,170
+بعد الرقم بدون أي فراغات يعني هذا كله متصل بعض
+
+388
+00:35:04,170 --> 00:35:08,830
+كتابة من هنا لهنا مافيش عندي فراغات لو بكتب اسم
+
+389
+00:35:08,830 --> 00:35:14,550
+هذا المركب على الكمبيوتر قبل الرقم شرطة وبعده شرطة
+
+390
+00:35:14,550 --> 00:35:21,380
+ما لم يكن الرقمفي الأول فبس بيكون فيه بعده شرطة
+
+391
+00:35:22,430 --> 00:35:27,630
+الان في عندكم امثلة كتير بإمكانكوا تتدربوا عليها
+
+392
+00:35:27,630 --> 00:35:31,250
+ماعطيكوا انا في الواجبات بالذات في الامتحانات
+
+393
+00:35:31,250 --> 00:35:35,270
+السابقة اللي موجودة عندكم كل امتحان بتلاقي عليه
+
+394
+00:35:35,270 --> 00:35:40,310
+اربع خمس مركبات كيف تسموهم مالم تتدربوا على حفظ
+
+395
+00:35:40,310 --> 00:35:44,890
+أسماء ال الkins على حفظ المجموعات على كيف تسموا
+
+396
+00:35:44,890 --> 00:35:48,970
+مركب مش هتقدروا تطبقوا يعني لازم لو واحد كنتوا
+
+397
+00:35:48,970 --> 00:35:50,210
+تدرسوا و تتدربوا أكثر
+
+398
+00:35:54,510 --> 00:35:58,250
+لأ لأ اعتمدي على اللي احنا بنشرحه بشكل اكبر
+
+399
+00:35:58,250 --> 00:36:02,370
+واعتمدي على الامتحانات الكتيرة اللي موجودة عندكم
+
+400
+00:36:02,370 --> 00:36:08,470
+بتعطيكي اسئلة وافية في الموضوع الآن بنيجي لنقطة
+
+401
+00:36:08,470 --> 00:36:14,350
+خاصة صغيرة بنضيفها في هذا الموضوع أحيانا بنيجي
+
+402
+00:36:14,350 --> 00:36:20,410
+نبحث عن أطول سلسلة بنلاحظ أنه بيطلع عندنا احتمالين
+
+403
+00:36:20,410 --> 00:36:27,520
+مش احتمال واحدمثلا هذا المركب هو نفسه هذا المركب
+
+404
+00:36:27,520 --> 00:36:31,440
+تماما لو بتتطلع عليه يعني احنا رسمنا المركب هذا
+
+405
+00:36:31,440 --> 00:36:36,460
+عملنا له نسخ و لاصق هنا لما نيجي نبحث عن أطول
+
+406
+00:36:36,460 --> 00:36:41,680
+سلسلة عدنا كتير هيقولنا واحد اتنين تلاتة اربعة
+
+407
+00:36:41,680 --> 00:36:47,800
+خمسة ستة سبعة اجت طالبة تانية عدت من هنا واحد
+
+408
+00:36:47,800 --> 00:36:55,600
+اتنين تلاتة اربعة خمسة ستة سبعةطب يا تورا بدي
+
+409
+00:36:55,600 --> 00:37:00,820
+أختار هذه السلسلة و لا بدي أختار هذه السلسلة طلع
+
+410
+00:37:00,820 --> 00:37:05,780
+عندك أكتر من سلسلة سبعة في عندنا قاعدة بتقول if
+
+411
+00:37:05,780 --> 00:37:09,760
+there are two equal along continuous chains يعني
+
+412
+00:37:09,760 --> 00:37:13,180
+لو في عندكوا سلسلتين متساويات في الطول في
+
+413
+00:37:13,180 --> 00:37:16,780
+الاحتمالات ا choose the one with most branches
+
+414
+00:37:16,780 --> 00:37:21,820
+اختار السلسلة اللي فيها تفرعات أكتريعني لو اتطلعت
+
+415
+00:37:21,820 --> 00:37:28,340
+على السلسلة هذه، كم تفرع طالع منها؟ اتنين، شغلتين
+
+416
+00:37:28,340 --> 00:37:31,540
+طالعين منها، لو اتطلعت على السلسلة هذه، كم تفرع
+
+417
+00:37:31,540 --> 00:37:37,980
+طالع منها؟ مجموعة واحدة، واضح؟ هذه طالع منها فقط
+
+418
+00:37:37,980 --> 00:37:42,240
+تفرع واحد، هيو، هنا طالع تفرعين، ابن اختار اللي
+
+419
+00:37:42,240 --> 00:37:47,000
+فيهاتفرعين طبعا لما نختار او ناخد ال lower
+
+420
+00:37:47,000 --> 00:37:51,640
+numbering على نمرة تلاتة في عندي مجموعة CH2 CH3
+
+421
+00:37:51,640 --> 00:37:55,600
+هذه اللي بيقول عنها إثل وعن نمرة اتنين المثل three
+
+422
+00:37:55,600 --> 00:38:00,300
+ethyl two methyl heptane بينما لو واحدة اختارت هذه
+
+423
+00:38:00,300 --> 00:38:04,220
+هتقول heptane على نمرة تلاتة هذه المجموعة
+
+424
+00:38:04,220 --> 00:38:09,520
+isopropyl فهذا الاسم three isopropyl heptane is
+
+425
+00:38:09,520 --> 00:38:14,650
+not a correct nameممكن واحدة في الامتحان تعمله،
+
+426
+00:38:14,650 --> 00:38:18,230
+تعتقد أنها عملت جيدا، في الآخر تتفاجأ أنه غلط
+
+427
+00:38:18,230 --> 00:38:22,670
+بالكامل، ليش؟ لأنها مانتبهتش أنه عندها سلسلتين،
+
+428
+00:38:22,670 --> 00:38:26,690
+ممكن يكونوا سبعة، وأنه لو أخدت من هنا، اللي هي هذه
+
+429
+00:38:26,690 --> 00:38:30,130
+السلسلة، هذه فيها ال most branches، فيها التفرعات
+
+430
+00:38:30,130 --> 00:38:34,390
+الأكثرولذلك اللي بده يشتغل في التسمية بده يكون
+
+431
+00:38:34,390 --> 00:38:39,610
+منتبه أنه فعلا لجأ أطول سلسلة واتأكد أنه مافيش
+
+432
+00:38:39,610 --> 00:38:45,150
+غيرها، لو لجأت إنتين بنفس الطول، بده يختار الأكثر
+
+433
+00:38:45,150 --> 00:38:52,310
+تفرعا، بده يختار السلسلة الأكثر تفرعا، واضح هذا
+
+434
+00:38:52,310 --> 00:39:00,220
+الكلام؟ ممكن نجرب ما أعطيكممثال حتى نشوف انكم
+
+435
+00:39:00,220 --> 00:39:18,060
+أتقنتوا هذا الكلام ولا لا هذا
+
+436
+00:39:18,060 --> 00:39:23,040
+مركب ابدأوا
+
+437
+00:39:23,040 --> 00:39:24,780
+فاكروا فيه وشوفوا
+
+438
+00:39:27,090 --> 00:39:33,530
+أيش أطول سلسلة موجودة فيه و
+
+439
+00:39:33,530 --> 00:39:38,610
+أول ما نعملها بأنصح اكون معاكم قلم فوسفور اتعلموا
+
+440
+00:39:38,610 --> 00:39:44,350
+عليها عشان تقدروا تشوفوا كل ما يتفرع منها واضح؟
+
+441
+00:39:44,350 --> 00:39:49,650
+الآن أكيد هتبدو تعدوا أنتوا واحد تنين تلاتة أربعة
+
+442
+00:39:49,650 --> 00:39:53,310
+أكيد لو قلتوا تلاتة تلاتة أربعة تلاتة أربعة نفس
+
+443
+00:39:53,310 --> 00:40:02,770
+الأشي أوواحد اتنين تلاتة او واحد اتنين تلاتة اربعة
+
+444
+00:40:02,770 --> 00:40:11,370
+خمسة ستة ايش رأيكوا او اي واحدة من هدول هادي زي
+
+445
+00:40:11,370 --> 00:40:14,650
+هادي زي هادي ماهم تلات اطراف واحد اتنين واحد اتنين
+
+446
+00:40:14,650 --> 00:40:22,090
+واحد اتنين اي واحدة بتاخدوها مافيش فيه مشكلة منها
+
+447
+00:40:23,210 --> 00:40:27,150
+أي واحدة من هدولة بيمشي تكون المرة واحدة لأنها
+
+448
+00:40:27,150 --> 00:40:33,650
+وادي وادي زي بعض واحد تانين تلاتة أربعة خمسة ستة
+
+449
+00:40:33,650 --> 00:40:39,630
+سبعة اه الآن هي أطول سلسلة خليني أعلمها و بأنصحكوا
+
+450
+00:40:39,630 --> 00:40:44,630
+لو عندكم طلم فسفور أسفر اتعلموها هي أطول سلسلة
+
+451
+00:40:44,630 --> 00:40:51,050
+عشان نقدر نشوف كام تفرع طالع منها هذه السلسلةاربع
+
+452
+00:40:51,050 --> 00:41:01,330
+انا مع الكلور هذه CH3 وهذه CH3 وهذه CH3 وهنا
+
+453
+00:41:01,330 --> 00:41:06,010
+الكلور اربع تفرعات طالع منها طب لو بدى اعطيها اقل
+
+454
+00:41:06,010 --> 00:41:16,080
+ترقيم من فضل من فضل اكيد واحدتلاتة اربعة خمسة ستة
+
+455
+00:41:16,080 --> 00:41:21,160
+سبعة الان لو بدنا نكتب الاسم كاملا كيف بدنا نبدأ
+
+456
+00:41:21,160 --> 00:41:27,880
+نكتب الاسم؟ من الخلف للامام ايش مركب طالما سبعة؟
+
+457
+00:41:27,880 --> 00:41:35,360
+هبتين الان هذا الهبتين كم نوع من المجموعات يحمل؟
+
+458
+00:41:35,360 --> 00:41:44,910
+نوعين اكلوروومثل ومثل ومثل اتراي مثل اذا هذا حقيقة
+
+459
+00:41:44,910 --> 00:41:54,550
+الـ C في الأول الكلورو اتراي مثل الان الكلورو وين
+
+460
+00:41:54,550 --> 00:42:01,870
+موقعها على نمرة أربعة four شرطة كلورو ال اتراي مثل
+
+461
+00:42:01,870 --> 00:42:10,930
+وين موجودين على اتنينو اتنين و تلاتة لازم احدد
+
+462
+00:42:10,930 --> 00:42:15,330
+تلات ارقام طالما try مثل لازم التلات ارقام بينه
+
+463
+00:42:15,330 --> 00:42:21,090
+اذا هنا فعلا بدي اكتب شرطة اتنين اتنين تلاتة هدف
+
+464
+00:42:21,090 --> 00:42:27,650
+هذا الموقع ان انا اكتبها صح هتكون اتنين اتنين
+
+465
+00:42:27,650 --> 00:42:32,090
+تلاتة try مثل
+
+466
+00:42:37,340 --> 00:42:47,340
+4-chloro-2-2-3-trimethylheptane
+
+467
+00:42:52,160 --> 00:42:56,040
+ماحدش يغلط .. مرات كتير بعض الناس اللي بيحفظوا
+
+468
+00:42:56,040 --> 00:42:59,400
+مجموعات شو الغلط اللي بيجعوا فيه، مابيبحثوش عن
+
+469
+00:42:59,400 --> 00:43:02,480
+أطول سلسلة، بيجوا و بيقولوا اه هذه ال carbon اللي
+
+470
+00:43:02,480 --> 00:43:06,300
+حملة تلت مجموعات tertiary-butyl وهذه السلسلة
+
+471
+00:43:07,580 --> 00:43:11,460
+وبالتالي بيسموه hexane وحمل على نمرة 2 tertiary
+
+472
+00:43:11,460 --> 00:43:16,920
+butyl بالفعش أنا مابخدش أسماء المجموعات إلا بعد ما
+
+473
+00:43:16,920 --> 00:43:23,700
+أحدد أطول سلسلة دائما نمرة واحد حدده أطول سلسلة
+
+474
+00:43:23,700 --> 00:43:28,340
+بعض الناس بيغلط بيجي بيقول لأ هذه تعتبر مجموعة في
+
+475
+00:43:28,340 --> 00:43:32,830
+البداية يعني لو أنا هنا كنت كاتب CH3بروح و بقول
+
+476
+00:43:32,830 --> 00:43:36,210
+ادي مجموعة مثل لأ دي جزء من السلسلة بنفعش اسميها
+
+477
+00:43:36,210 --> 00:43:41,110
+مجموعة هذه من الأخطاء الشائع لبعض الناس بيجي بعمل
+
+478
+00:43:41,110 --> 00:43:44,650
+الترقيم من هان و بعدين بيقول على نمر واحد في عندي
+
+479
+00:43:44,650 --> 00:43:50,950
+try مثل .. لأ مش هيك تأخذه لازم أفتش عليه أطول
+
+480
+00:43:50,950 --> 00:43:54,630
+سلسلة و بعدين أشوف إيش في عندي مجموعات حسب ما
+
+481
+00:43:54,630 --> 00:43:59,010
+اتعلمت بأعمل التسمية تبعي
+
+482
+00:44:04,700 --> 00:44:10,980
+هذه تقريبا فكرة عن ال الكنز بشكل عام لو اتكلمنا عن
+
+483
+00:44:10,980 --> 00:44:15,960
+ال physical properties of الكنز هنلاحظ القاتل اول
+
+484
+00:44:15,960 --> 00:44:23,940
+شئ ال الكنز هم water insoluble ليش؟ لان دائما ال
+
+485
+00:44:23,940 --> 00:44:31,440
+الكنز تتذكر انهم non polar والمية polar حسب قاعدة
+
+486
+00:44:31,440 --> 00:44:36,250
+like dissolves likeالالكينز لا يدوبون في المياه
+
+487
+00:44:36,250 --> 00:44:40,590
+ولذلك من هؤلاء الالكينز على سبيل المثال البنزين
+
+488
+00:44:40,590 --> 00:44:44,890
+اللي هو أقود السيارات واضح هل يا تورا هذا بيدوب في
+
+489
+00:44:44,890 --> 00:44:49,090
+المياه ولا بيعمل طبقة تانية بيعمل طبقة تانية هنا
+
+490
+00:44:49,090 --> 00:44:54,810
+خليني أنبه لنقطة خطأ شائعلأنه احنا باللغة العربية
+
+491
+00:44:54,810 --> 00:44:59,330
+بنستعمل كلمة بنزين لما بنعب السيارة بنقول بنزين
+
+492
+00:44:59,330 --> 00:45:05,310
+فناس كتير بيخطئوا و بيفكروا انه احنا بنعب السيارة
+
+493
+00:45:05,310 --> 00:45:09,150
+البنزين هذا اللي مار عليكم اللي هو البنزين العطري
+
+494
+00:45:09,150 --> 00:45:16,230
+هذا الكلام خطأ طب ايش اسم هو بالانجليزي وقود
+
+495
+00:45:16,230 --> 00:45:23,650
+السيارات ال fuel اسمه جازولينأحنا بالعربي هذا
+
+496
+00:45:23,650 --> 00:45:29,390
+الجازولين بنقول عنه بنزين لكن هو حقيقة خليط من
+
+497
+00:45:29,390 --> 00:45:35,870
+الالكينز بشكل أساسي مركبين من الالكينز هو خليط من
+
+498
+00:45:35,870 --> 00:45:40,190
+الهيبتين والايزو
+
+499
+00:45:40,190 --> 00:45:40,710
+أكتين
+
+500
+00:45:43,660 --> 00:45:48,340
+فالجازولين اللي هو وقود السيارات اللي احنا بنعبيه
+
+501
+00:45:48,340 --> 00:45:52,180
+باللغة العربية متعودين نقول عنه بنزين مالوش هذا ال
+
+502
+00:45:52,180 --> 00:45:56,020
+structure ولا له علاقة بهذا ال structure لأ
+
+503
+00:45:56,020 --> 00:46:02,000
+gasoline is a mixture of alkanes الجازولين وقود
+
+504
+00:46:02,000 --> 00:46:05,780
+السيارات اللي بنعبيه هو خليط من ال alkanes شو ما
+
+505
+00:46:05,780 --> 00:46:10,480
+دول ال alkanes؟الهبتين وال ايزو اكتين و بتهيألي
+
+506
+00:46:10,480 --> 00:46:15,020
+اليوم احنا رسمنا شكل الهبتين سبع كربونات و رسمنا
+
+507
+00:46:15,020 --> 00:46:18,900
+شكل ال ايزو اكتين اللي فيه مجموعة ال ايزو و بنكمل
+
+508
+00:46:18,900 --> 00:46:24,500
+لكم كربونات تمانية الان هدولة الكنز لو أخدنا هذا
+
+509
+00:46:24,500 --> 00:46:29,880
+الجازولين وقود السيارات و حطناه فوق ميهبيخلط
+
+510
+00:46:29,880 --> 00:46:34,640
+معاها، بيدوب فيها؟ لأ، فإذا الالكينز they are
+
+511
+00:46:34,640 --> 00:46:39,880
+water insoluble، ليش؟ لأن هدول المركبات، القوة
+
+512
+00:46:39,880 --> 00:46:46,010
+اللي فيهم، London forces، بينما الميهالهيدروجين
+
+513
+00:46:46,010 --> 00:46:52,810
+بوندنج فيها الميّه بولر والالكينز نان بولر فالبولر
+
+514
+00:46:52,810 --> 00:46:57,370
+والنان بولر بخلطوش مع بعض are water insoluble طبعا
+
+515
+00:46:57,370 --> 00:47:02,000
+كونوا القوة اللي موجودة فيهم ضعيفةاللي هي أضعف نوع
+
+516
+00:47:02,000 --> 00:47:05,440
+من القوة الـ London Forces معناه ذلك الجزيئات
+
+517
+00:47:05,440 --> 00:47:10,880
+بتاعتهم ممسوقة ببعضها بقوة ولا بقوة ضعيفة؟ بقوة
+
+518
+00:47:10,880 --> 00:47:16,160
+ضعيفة، هذا بيقدر إلى إنها بتتبخر بشكل سريع وإلى أن
+
+519
+00:47:16,160 --> 00:47:22,000
+نقطة الغليان تبعتها أيضا منخفضة جدا ولذلك لو أنا
+
+520
+00:47:22,000 --> 00:47:25,380
+إجيت اتطلعت على ال canes اللي في الجدول هلاحظ ال
+
+521
+00:47:25,380 --> 00:47:32,540
+methane غازالإيثين غاز، البروبين غاز، البيوتين
+
+522
+00:47:32,540 --> 00:47:36,600
+غاز، اللي هو الغاز المنزلي، غاز الطهي المنزلي، هو
+
+523
+00:47:36,600 --> 00:47:41,740
+البيوتين البنتين بيبدأ يصير سائل بنقطة غليان حوالي
+
+524
+00:47:41,740 --> 00:47:46,500
+36 درجة مؤوية، نقطة غليان منخفضة البنزين نفسه نقطة
+
+525
+00:47:46,500 --> 00:47:49,920
+غليانه منخفضة، ولذلك بيتبقر بسرعة وبيعمل حرائق
+
+526
+00:47:49,920 --> 00:47:56,570
+بسرعةواضح؟ كل هذا الكلام لأن القوة الترابط اللي
+
+527
+00:47:56,570 --> 00:48:01,070
+موجودة فيه هي ال London forces اللي هي أضعف أنواع
+
+528
+00:48:01,070 --> 00:48:05,550
+قوة الترابط فالجزيئات غير مترابطة بقوة و من هنا
+
+529
+00:48:05,550 --> 00:48:10,910
+بيكون ال alkanes لهم low boiling points بالتأكيد
+
+530
+00:48:10,910 --> 00:48:15,720
+ال cane من ذرةنقطة غليانه اقل من ذرتين اقل من
+
+531
+00:48:15,720 --> 00:48:20,460
+تلاتة وكل ما يبدو يزيدوا عدد ذرات الالكين ايش
+
+532
+00:48:20,460 --> 00:48:26,020
+بيصيلا نقطة الغليان بتزيد واضح؟أخر نقطة اليوم
+
+533
+00:48:26,020 --> 00:48:31,560
+بنحكيها أن الالكينز لنفس المركب يعني لنفس العدد
+
+534
+00:48:31,560 --> 00:48:36,580
+الخمسة مثلا ممكن تكون chain متسلسلة و ممكن تكون
+
+535
+00:48:36,580 --> 00:48:39,900
+branched معناة chain مرة تانية أن الخمسة ورا بعض
+
+536
+00:48:39,900 --> 00:48:44,020
+branched هي عندي واحد اتنين تلاتة مثلا في البنتين
+
+537
+00:48:44,020 --> 00:48:49,800
+و من موقع اتنين اعملت تفرعينهنا خمس ذرات وهنا خمس
+
+538
+00:48:49,800 --> 00:48:53,560
+ذرات الخمس هذول جايين إيش؟ ورا بعض بقول عنهم chain
+
+539
+00:48:53,560 --> 00:49:00,140
+compounds هذول برانش دائما بنقول برانش الكنز have
+
+540
+00:49:00,140 --> 00:49:02,840
+lower boiling points than the corresponding long
+
+541
+00:49:02,840 --> 00:49:10,620
+chain of kens يعني هذا و هذا له نفس الصيغة C5H12
+
+542
+00:49:10,620 --> 00:49:17,970
+لكن مين له نقطة غليان أعلى؟الـ Chain أقل ال branch
+
+543
+00:49:17,970 --> 00:49:23,330
+ليش؟ لأن ال branch بيكون عامل زي الكورة الآن
+
+544
+00:49:23,330 --> 00:49:27,990
+تخيلوا لو حطيتوا أنتوا نفسكم تلت كورات هيك فوق بعض
+
+545
+00:49:27,990 --> 00:49:33,130
+بهذا الشكل هل يتورا بينهم مسافات ارتباط قوية كتير؟
+
+546
+00:49:33,130 --> 00:49:37,620
+هاي بس سطح الارتباطواضحة الفكرة؟ فالجزء اللي
+
+547
+00:49:37,620 --> 00:49:42,220
+branched بصير أعمل زي الكورة، الآن الكورات بحطها
+
+548
+00:49:42,220 --> 00:49:45,880
+بشكل تستقر فوق بعض، يعني أنا بقدر أحطها دولة تلاتة
+
+549
+00:49:45,880 --> 00:49:51,610
+فوق بعض ويثبتوا؟ لأليش؟ لأنه مافيش سطح التقاء كبير
+
+550
+00:49:51,610 --> 00:49:55,730
+بينهم ولذلك الـbranched alkanes they have lower
+
+551
+00:49:55,730 --> 00:49:59,170
+boiling points than the corresponding long chain
+
+552
+00:49:59,170 --> 00:50:03,210
+alkanes هذه مبادئ عامة بال physical properties
+
+553
+00:50:03,210 --> 00:50:06,090
+للالكنز وبهيك بننهي اليوم ان شاء الله
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..14e63a092d27f7f869641d58d03fe8277da43831
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4389, "start": 19.57, "end": 43.89, "text": "بسم الله الرحمن الرحيم اليوم ضيلنا أشياء بسيطة في موضوع ال amines قبل ما ننتقل لجزء ال biochemistry طبعا اتفقنا المرة الماضية أن ال amines هم مراكبات ال nitrogen من أهم الأشياء اللي بتميزهم هو وجود إيش", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 48812, 26895, 8315, 5551, 8592, 1829, 16606, 4724, 3794, 1829, 9566, 3660, 8978, 3714, 2407, 11242, 45367, 2423, 669, 1652, 12174, 36150, 19446, 8717, 29399, 4587, 1211, 5296, 7435, 11622, 38207, 2423, 12198, 48353, 23032, 3555, 3615, 995, 1975, 2655, 5172, 4587, 8315, 9673, 25720, 9673, 46958, 10632, 14739, 2423, 669, 1652, 8032, 2304, 3714, 23557, 4117, 3555, 9307, 2423, 17903, 9154, 5551, 16095, 16247, 8592, 1829, 16606, 13672, 1829, 39894, 2304, 1829, 11622, 16095, 31439, 49610, 23328, 11933, 1829, 8592], "avg_logprob": -0.07627688011815471, "compression_ratio": 1.6372549019607843, "no_speech_prob": 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الحالة لو دوبنا ال ammonia مثلا في ال HCl ال ammonia هتاخد H من هنا هصير عندى ammonium ion مع ال Cl minus ammonium chloride يمكن هذا ما معاكم في المدرسة انه بإمكاننا احنا نجيب نقطة", "tokens": [4117, 8848, 23275, 21542, 6027, 3660, 45164, 11778, 37746, 8315, 2423, 46833, 50113, 15040, 8978, 2423, 389, 9966, 2423, 46833, 8032, 2655, 47283, 3215, 389, 9154, 34105, 8032, 9381, 13546, 43242, 7578, 36431, 2197, 17437, 20449, 2423, 2033, 3175, 36431, 2197, 35434, 7251, 43020, 23758, 19446, 20449, 995, 24793, 8978, 9673, 3215, 2288, 3794, 3660, 16472, 3224, 4724, 28814, 2304, 41361, 8315, 1975, 5016, 8315, 8717, 7435, 1829, 3555, 8717, 47432, 3660], "avg_logprob": -0.2669092498413504, "compression_ratio": 1.540983606557377, "no_speech_prob": 0.0, "words": [{"start": 321.55, "end": 322.09, "word": "كذلك", "probability": 0.7384440104166666}, {"start": 322.09, "end": 322.51, "word": " الحالة", "probability": 0.569091796875}, {"start": 322.51, "end": 322.59, "word": " لو", "probability": 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HCl لما يلتجوا مع بعض ال ammonia مع ال HCl شو هيعملوا؟ ammonium chloride ال ammonium chloride إيش لونه؟ تذكروا شغل المدرسة؟", "tokens": [27842, 2423, 46833, 9154, 3714, 5016, 1211, 12610, 2423, 46833, 8717, 5016, 9566, 11296, 34105, 8717, 47432, 3660, 9154, 2423, 389, 9966, 8717, 5016, 9566, 3224, 34105, 4032, 8717, 3794, 1829, 3555, 16095, 10874, 7649, 3555, 45030, 11242, 39894, 2655, 3555, 34740, 4386, 39894, 2655, 3555, 34740, 2423, 46833, 39894, 2655, 3555, 34740, 2423, 389, 9966, 5296, 15042, 7251, 1211, 2655, 7435, 14407, 20449, 45030, 11242, 2423, 46833, 20449, 2423, 389, 9966, 13412, 2407, 39896, 25957, 1211, 14407, 22807, 36431, 2197, 35434, 2423, 36431, 2197, 35434, 11933, 1829, 8592, 5296, 11536, 3224, 22807, 6055, 8848, 37983, 14407, 13412, 17082, 1211, 9673, 3215, 2288, 3794, 3660, 22807], "avg_logprob": -0.14398364123897017, "compression_ratio": 1.8522167487684729, "no_speech_prob": 0.0, "words": [{"start": 340.4, "end": 340.74, "word": "من", "probability": 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"probability": 0.99169921875}, {"start": 352.1, "end": 352.6, "word": " HCl", "probability": 0.893310546875}, {"start": 352.6, "end": 353.18, "word": " لما", "probability": 0.935302734375}, {"start": 353.18, "end": 353.68, "word": " يلتجوا", "probability": 0.9455078125}, {"start": 353.68, "end": 353.86, "word": " مع", "probability": 0.99609375}, {"start": 353.86, "end": 354.28, "word": " بعض", "probability": 0.997802734375}, {"start": 354.28, "end": 354.42, "word": " ال", "probability": 0.9736328125}, {"start": 354.42, "end": 354.76, "word": " ammonia", "probability": 0.986328125}, {"start": 354.76, "end": 354.92, "word": " مع", "probability": 0.8896484375}, {"start": 354.92, "end": 355.06, "word": " ال", "probability": 0.9951171875}, {"start": 355.06, "end": 355.54, "word": " HCl", "probability": 0.911865234375}, {"start": 355.54, "end": 355.74, "word": " شو", "probability": 0.929931640625}, {"start": 355.74, "end": 357.08, "word": " هيعملوا؟", "probability": 0.7958984375}, {"start": 357.08, "end": 357.62, "word": " ammonium", "probability": 0.6268310546875}, {"start": 357.62, "end": 358.18, "word": " chloride", "probability": 0.89013671875}, {"start": 358.18, "end": 358.38, "word": " ال", "probability": 0.68603515625}, {"start": 358.38, "end": 358.76, "word": " ammonium", "probability": 0.98779296875}, {"start": 358.76, "end": 359.26, "word": " chloride", "probability": 0.9931640625}, {"start": 359.26, "end": 359.56, "word": " إيش", "probability": 0.7685546875}, {"start": 359.56, "end": 362.66, "word": " لونه؟", "probability": 0.9503173828125}, {"start": 362.66, "end": 363.28, "word": " تذكروا", "probability": 0.8291015625}, {"start": 363.28, "end": 363.56, "word": " شغل", "probability": 0.9930013020833334}, {"start": 363.56, "end": 364.58, "word": " المدرسة؟", "probability": 0.978759765625}], "temperature": 1.0}, {"id": 16, "seek": 37647, "start": 365.19, "end": 376.47, "text": "أبيض و لذلك كنا نقول أنه ال ammonia مع ال HCl بيعطوا سحب بيضاء من ال ammonium chloride بهذا النص مرت عليكم في المدرسة ولا لأ؟", "tokens": [10721, 21292, 11242, 4032, 5296, 8848, 23275, 9122, 8315, 8717, 39648, 14739, 3224, 2423, 46833, 20449, 2423, 389, 9966, 4724, 40228, 9566, 14407, 8608, 5016, 3555, 4724, 1829, 11242, 16606, 9154, 2423, 36431, 2197, 35434, 39627, 15730, 28239, 9381, 3714, 43500, 25894, 24793, 8978, 9673, 3215, 2288, 3794, 3660, 49429, 5296, 10721, 22807], "avg_logprob": -0.20037616347825085, "compression_ratio": 1.3178807947019868, "no_speech_prob": 0.0, "words": [{"start": 365.19, "end": 365.93, "word": "أبيض", "probability": 0.8761393229166666}, {"start": 365.93, "end": 366.43, "word": " و", "probability": 0.3427734375}, {"start": 366.43, "end": 366.89, "word": " لذلك", "probability": 0.91650390625}, {"start": 366.89, "end": 367.13, "word": " كنا", "probability": 0.97021484375}, {"start": 367.13, "end": 367.45, "word": " نقول", "probability": 0.90771484375}, {"start": 367.45, "end": 367.79, "word": " أنه", "probability": 0.52978515625}, 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"word": " اتنين", "probability": 0.88916015625}, {"start": 578.57, "end": 579.35, "word": " بالعشرة", "probability": 0.9630126953125}, {"start": 579.35, "end": 580.41, "word": " الان", "probability": 0.6466064453125}, {"start": 580.41, "end": 581.33, "word": " لاحظوا", "probability": 0.9603271484375}, {"start": 581.33, "end": 581.63, "word": " ع", "probability": 0.29931640625}, {"start": 581.63, "end": 581.93, "word": " طول", "probability": 0.8466796875}, {"start": 581.93, "end": 582.93, "word": " ملاحظة", "probability": 0.98837890625}, {"start": 582.93, "end": 583.83, "word": " الأمينز", "probability": 0.80572509765625}, {"start": 583.83, "end": 583.97, "word": " اللي", "probability": 0.802978515625}, {"start": 583.97, "end": 584.09, "word": " في", "probability": 0.85498046875}, {"start": 584.09, "end": 584.63, "word": " الأول", "probability": 0.92431640625}, {"start": 584.63, "end": 585.41, "word": " مثل", "probability": 0.97900390625}, {"start": 585.41, "end": 586.01, "word": " أمين", "probability": 0.9059244791666666}, {"start": 586.01, "end": 586.31, "word": " ضاي", "probability": 0.41021728515625}, {"start": 586.31, "end": 586.71, "word": " مثل", "probability": 0.989013671875}, {"start": 586.71, "end": 587.21, "word": " أمين", "probability": 0.9833984375}, {"start": 587.21, "end": 587.65, "word": " و", "probability": 0.68359375}, {"start": 587.65, "end": 588.09, "word": " لحد", "probability": 0.97900390625}, {"start": 588.09, "end": 589.07, "word": " الأللين", "probability": 0.9385986328125}, {"start": 589.07, "end": 589.53, "word": " هنا", "probability": 0.92333984375}, {"start": 589.53, "end": 590.55, "word": " صار", "probability": 0.93896484375}, {"start": 590.55, "end": 590.89, "word": " عندى", "probability": 0.775634765625}, {"start": 590.89, "end": 591.37, "word": " تغير", "probability": 0.97216796875}, {"start": 591.37, "end": 591.89, "word": " كتير", "probability": 0.98876953125}, {"start": 591.89, "end": 592.15, "word": " يعني", "probability": 0.845458984375}, {"start": 592.15, "end": 592.57, "word": " لحد", "probability": 0.97705078125}, {"start": 592.57, "end": 593.13, "word": " هدولة", "probability": 0.930908203125}, {"start": 593.13, "end": 593.69, "word": " كلهم", "probability": 0.98876953125}], "temperature": 1.0}, {"id": 27, "seek": 61741, "start": 594.83, "end": 617.41, "text": "كانت ال بي كي بي قليلة تلاتة تلاتة أربعة لما صرت فيه الانليل و التوابع صرت تسعة الان هدول ايش بيفرقوا عن بعض لحد هذا الخط هدول اللي فوق aliphatic amines اللي تحت aromatic amines واضح؟ اذا هذه منطقات", "tokens": [41361, 2655, 2423, 4724, 1829, 9122, 1829, 4724, 1829, 12174, 20292, 37977, 6055, 1211, 9307, 3660, 6055, 1211, 9307, 3660, 5551, 25513, 27884, 5296, 15042, 20328, 43500, 8978, 3224, 2423, 7649, 20292, 1211, 4032, 16712, 14407, 3555, 3615, 20328, 43500, 6055, 3794, 27884, 2423, 7649, 8032, 3215, 12610, 1975, 1829, 8592, 4724, 33911, 2288, 4587, 14407, 18871, 45030, 11242, 5296, 24401, 23758, 33962, 9566, 8032, 3215, 12610, 13672, 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0.8250325520833334}, {"start": 598.81, "end": 599.83, "word": " لما", "probability": 0.9033203125}, {"start": 599.83, "end": 600.21, "word": " صرت", "probability": 0.911376953125}, {"start": 600.21, "end": 600.73, "word": " فيه", "probability": 0.763671875}, {"start": 600.73, "end": 601.59, "word": " الانليل", "probability": 0.6300048828125}, {"start": 601.59, "end": 601.71, "word": " و", "probability": 0.3125}, {"start": 601.71, "end": 602.21, "word": " التوابع", "probability": 0.9188232421875}, {"start": 602.21, "end": 602.55, "word": " صرت", "probability": 0.873291015625}, {"start": 602.55, "end": 603.13, "word": " تسعة", "probability": 0.9744466145833334}, {"start": 603.13, "end": 603.73, "word": " الان", "probability": 0.625}, {"start": 603.73, "end": 604.07, "word": " هدول", "probability": 0.8678385416666666}, {"start": 604.07, "end": 604.39, "word": " ايش", "probability": 0.585205078125}, {"start": 604.39, "end": 605.03, "word": " بيفرقوا", "probability": 0.84619140625}, {"start": 605.03, "end": 605.21, "word": " عن", "probability": 0.9833984375}, {"start": 605.21, "end": 605.79, "word": " بعض", "probability": 0.994384765625}, {"start": 605.79, "end": 607.25, "word": " لحد", "probability": 0.898681640625}, {"start": 607.25, "end": 607.55, "word": " هذا", "probability": 0.89599609375}, {"start": 607.55, "end": 608.05, "word": " الخط", "probability": 0.9833984375}, {"start": 608.05, "end": 609.03, "word": " هدول", "probability": 0.9462890625}, {"start": 609.03, "end": 609.23, "word": " اللي", "probability": 0.90625}, {"start": 609.23, "end": 609.67, "word": " فوق", "probability": 0.990478515625}, {"start": 609.67, "end": 610.61, "word": " aliphatic", "probability": 0.5916341145833334}, {"start": 610.61, "end": 611.35, "word": " amines", "probability": 0.81640625}, {"start": 611.35, "end": 611.97, "word": " اللي", "probability": 0.944580078125}, {"start": 611.97, "end": 612.45, "word": " تحت", "probability": 0.98046875}, {"start": 612.45, "end": 613.67, "word": " aromatic", "probability": 0.84814453125}, {"start": 613.67, "end": 614.51, "word": " amines", "probability": 0.917724609375}, {"start": 614.51, "end": 615.43, "word": " واضح؟", "probability": 0.79620361328125}, {"start": 615.43, "end": 616.05, "word": " اذا", "probability": 0.73193359375}, {"start": 616.05, "end": 616.65, "word": " هذه", "probability": 0.82958984375}, {"start": 616.65, "end": 617.41, "word": " منطقات", "probability": 0.7760009765625}], "temperature": 1.0}, {"id": 28, "seek": 63491, "start": 618.35, "end": 634.91, "text": "الالفاتك أمين هذي منطقة ال aromatic amines لو إجينا سألنا مين بيكونوا ك basis أقوى الالفاتك أمين ولا ال aromatic amines؟ الالفاتك أمين", "tokens": [6027, 6027, 5172, 9307, 4117, 5551, 2304, 9957, 8032, 8848, 1829, 9154, 9566, 28671, 2423, 45831, 669, 1652, 45164, 11933, 7435, 1829, 8315, 8608, 10721, 1211, 8315, 3714, 9957, 4724, 1829, 30544, 14407, 9122, 5143, 5551, 4587, 2407, 7578, 2423, 6027, 5172, 9307, 4117, 5551, 2304, 9957, 49429, 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"probability": 0.9012451171875}, {"start": 625.25, "end": 626.05, "word": " مين", "probability": 0.96826171875}, {"start": 626.05, "end": 626.89, "word": " بيكونوا", "probability": 0.96240234375}, {"start": 626.89, "end": 627.17, "word": " ك", "probability": 0.92041015625}, {"start": 627.17, "end": 627.87, "word": " basis", "probability": 0.4580078125}, {"start": 627.87, "end": 629.13, "word": " أقوى", "probability": 0.9732666015625}, {"start": 629.13, "end": 630.27, "word": " الالفاتك", "probability": 0.7444580078125}, {"start": 630.27, "end": 630.85, "word": " أمين", "probability": 0.939453125}, {"start": 630.85, "end": 631.47, "word": " ولا", "probability": 0.7685546875}, {"start": 631.47, "end": 631.69, "word": " ال", "probability": 0.93408203125}, {"start": 631.69, "end": 632.23, "word": " aromatic", "probability": 0.9541015625}, {"start": 632.23, "end": 633.43, "word": " amines؟", "probability": 0.78271484375}, {"start": 633.43, "end": 634.47, "word": " الالفاتك", "probability": 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"word": " ممكن", "probability": 0.83642578125}, {"start": 663.94, "end": 664.84, "word": " نكمل", "probability": 0.91748046875}, {"start": 664.84, "end": 665.12, "word": " لكم،", "probability": 0.5358072916666666}, {"start": 665.12, "end": 665.66, "word": " نقولكم", "probability": 0.8494466145833334}, {"start": 665.66, "end": 666.08, "word": " إيش", "probability": 0.776611328125}, {"start": 666.08, "end": 666.84, "word": " ال", "probability": 0.50146484375}, {"start": 666.84, "end": 667.18, "word": " due", "probability": 0.51953125}, {"start": 667.18, "end": 667.82, "word": " to", "probability": 0.2734375}, {"start": 667.82, "end": 668.72, "word": " بسبب", "probability": 0.9713541666666666}, {"start": 668.72, "end": 669.34, "word": " إيش؟", "probability": 0.9056396484375}, {"start": 669.34, "end": 670.54, "word": " ليش", "probability": 0.8935546875}, {"start": 670.54, "end": 672.08, "word": " بدنا", "probability": 0.6165771484375}, {"start": 672.08, "end": 672.58, "word": " نحكي", 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الضعف اللي بين لضعاف أساساً بسبب إيش؟ ال inductive effect", "tokens": [9566, 3555, 3615, 995, 14111, 4724, 8592, 28820, 6225, 10943, 28242, 16095, 7251, 34268, 26890, 14407, 48812, 3615, 31845, 12399, 32239, 8592, 22807, 5296, 33456, 28242, 16095, 8978, 16095, 30944, 12399, 28242, 16095, 7251, 34268, 26890, 14407, 9122, 5143, 48812, 3615, 31845, 12399, 44381, 36764, 24401, 5551, 11242, 3615, 5172, 9154, 16712, 7649, 1829, 5551, 11242, 3615, 5172, 9154, 16712, 6027, 2655, 12399, 16247, 1863, 6156, 2288, 4587, 6024, 114, 3615, 5172, 13672, 1829, 49374, 5296, 11242, 3615, 31845, 5551, 3794, 32277, 995, 14111, 4724, 35457, 3555, 11933, 1829, 8592, 22807, 2423, 31612, 488, 1802], "avg_logprob": -0.15315754882370433, "compression_ratio": 1.7837837837837838, "no_speech_prob": 0.0, "words": [{"start": 1207.81, "end": 1208.39, "word": "طبعاً", "probability": 0.788671875}, {"start": 1208.39, "end": 1209.01, "word": " بشكل", "probability": 0.9324544270833334}, {"start": 1209.01, "end": 1209.51, 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1223.25, "word": " الضعف", "probability": 0.947998046875}, {"start": 1223.25, "end": 1223.61, "word": " اللي", "probability": 0.938720703125}, {"start": 1223.61, "end": 1223.85, "word": " بين", "probability": 0.99560546875}, {"start": 1223.85, "end": 1224.79, "word": " لضعاف", "probability": 0.754364013671875}, {"start": 1224.79, "end": 1226.61, "word": " أساساً", "probability": 0.86328125}, {"start": 1226.61, "end": 1227.31, "word": " بسبب", "probability": 0.9254557291666666}, {"start": 1227.31, "end": 1228.43, "word": " إيش؟", "probability": 0.8580322265625}, {"start": 1228.43, "end": 1228.55, "word": " ال", "probability": 0.9033203125}, {"start": 1228.55, "end": 1229.21, "word": " inductive", "probability": 0.888671875}, {"start": 1229.21, "end": 1229.71, "word": " effect", "probability": 0.95068359375}], "temperature": 1.0}, {"id": 52, "seek": 124415, "start": 1230.49, "end": 1244.15, "text": "لكن لو أنا باجي بسألكم والله بشكل عام ال nitroaniline is a weak base، ليش؟ هتقولولي ال resonance مصيبة؟", "tokens": [1211, 19452, 45164, 41850, 4724, 26108, 1829, 4724, 3794, 10721, 23275, 2304, 16070, 43761, 4724, 8592, 28820, 6225, 10943, 2423, 10900, 340, 282, 388, 533, 307, 257, 5336, 3096, 12399, 32239, 8592, 22807, 8032, 2655, 39648, 12610, 1829, 2423, 30944, 3714, 9381, 1829, 49401, 22807], "avg_logprob": -0.1842730945867041, "compression_ratio": 1.2, "no_speech_prob": 0.0, "words": [{"start": 1230.49, "end": 1230.91, "word": "لكن", "probability": 0.8544921875}, {"start": 1230.91, "end": 1231.09, "word": " لو", "probability": 0.966796875}, {"start": 1231.09, "end": 1231.33, "word": " أنا", "probability": 0.58935546875}, {"start": 1231.33, "end": 1231.67, "word": " باجي", "probability": 0.9404296875}, {"start": 1231.67, "end": 1232.45, "word": " بسألكم", "probability": 0.8916015625}, {"start": 1232.45, "end": 1233.13, "word": " والله", "probability": 0.75}, {"start": 1233.13, "end": 1233.77, "word": " بشكل", "probability": 0.9752604166666666}, {"start": 1233.77, 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1.0}, {"id": 53, "seek": 126994, "start": 1244.88, "end": 1269.94, "text": "و الحاجات هم صيبة تانية ال nitro يعني صار سبب ضعفه شغل فيه ال resonance و ال inductive effect لكن لو كنت بدأ اقارنه مثلا مع ال methyl aniline لأ بقول ما هو ال resonance و ال resonance هم عامل مشترك بطل هو اللي مفرج صار إيش اللي مفرج؟ شكل أساسي ال inductive effect واضحة الفكرة؟", "tokens": [2407, 21542, 26108, 9307, 8032, 2304, 20328, 1829, 49401, 6055, 7649, 10632, 2423, 10900, 340, 37495, 22653, 20328, 9640, 8608, 3555, 3555, 48812, 3615, 5172, 3224, 13412, 17082, 1211, 8978, 3224, 2423, 30944, 4032, 2423, 31612, 488, 1802, 44381, 45164, 9122, 29399, 47525, 10721, 1975, 4587, 9640, 1863, 3224, 50113, 15040, 20449, 2423, 48441, 364, 388, 533, 5296, 10721, 4724, 39648, 19446, 31439, 2423, 30944, 4032, 2423, 30944, 8032, 2304, 6225, 10943, 1211, 37893, 2655, 31747, 4724, 9566, 1211, 31439, 13672, 1829, 3714, 5172, 47341, 20328, 9640, 11933, 1829, 8592, 13672, 1829, 3714, 5172, 47341, 22807, 13412, 28820, 5551, 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"probability": 0.9775390625}, {"start": 1258.5, "end": 1259.02, "word": " resonance", "probability": 0.982421875}, {"start": 1259.02, "end": 1259.24, "word": " و", "probability": 0.837890625}, {"start": 1259.24, "end": 1259.34, "word": " ال", "probability": 0.953125}, {"start": 1259.34, "end": 1259.7, "word": " resonance", "probability": 0.978515625}, {"start": 1259.7, "end": 1260.06, "word": " هم", "probability": 0.5208740234375}, {"start": 1260.06, "end": 1260.38, "word": " عامل", "probability": 0.9934895833333334}, {"start": 1260.38, "end": 1260.9, "word": " مشترك", "probability": 0.96630859375}, {"start": 1260.9, "end": 1261.34, "word": " بطل", "probability": 0.9083658854166666}, {"start": 1261.34, "end": 1261.5, "word": " هو", "probability": 0.978515625}, {"start": 1261.5, "end": 1261.72, "word": " اللي", "probability": 0.9306640625}, {"start": 1261.72, "end": 1262.22, "word": " مفرج", "probability": 0.826171875}, {"start": 1262.22, "end": 1262.98, "word": " صار", "probability": 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{"start": 1554.02, "end": 1554.44, "word": " مع", "probability": 0.89404296875}, {"start": 1554.44, "end": 1554.66, "word": " ال", "probability": 0.8984375}, {"start": 1554.66, "end": 1555.36, "word": " amines", "probability": 0.5557861328125}, {"start": 1555.36, "end": 1555.64, "word": " لما", "probability": 0.789794921875}, {"start": 1555.64, "end": 1555.98, "word": " تكون", "probability": 0.987548828125}, {"start": 1555.98, "end": 1556.14, "word": " ال", "probability": 0.93603515625}, {"start": 1556.14, "end": 1556.38, "word": " H", "probability": 0.75244140625}, {"start": 1556.38, "end": 1556.54, "word": " و", "probability": 0.77099609375}, {"start": 1556.54, "end": 1556.66, "word": " ال", "probability": 0.5771484375}, {"start": 1556.66, "end": 1557.06, "word": " OH", "probability": 0.83544921875}, {"start": 1557.06, "end": 1557.6, "word": " جانب", "probability": 0.8758138020833334}, {"start": 1557.6, "end": 1557.96, "word": " بعض،", "probability": 0.7942708333333334}, {"start": 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"قولنا احنا كل N H2 مع C double bond O ماصيرها النهائي C double bond O الديهيد او كيتون تصير C double bond N CH2 CH3 بصير ال shift basis وقولنا ان التفاعل بهذه الحالة ايش بنقول عنه addition elimination", "tokens": [39648, 8315, 1975, 5016, 8315, 28242, 426, 389, 17, 20449, 383, 3834, 6086, 422, 19446, 9381, 13546, 11296, 28239, 3224, 16373, 1829, 383, 3834, 6086, 422, 2423, 16254, 3224, 25708, 1975, 2407, 9122, 36081, 11536, 6055, 9381, 13546, 383, 3834, 6086, 426, 5995, 17, 5995, 18, 4724, 9381, 13546, 2423, 5513, 5143, 4032, 39648, 8315, 16472, 16712, 5172, 995, 30241, 39627, 24192, 21542, 6027, 3660, 1975, 1829, 8592, 44945, 39648, 18871, 3224, 4500, 29224], "avg_logprob": -0.32937499205271403, "compression_ratio": 1.559782608695652, "no_speech_prob": 0.0, "words": [{"start": 1568.45, "end": 1568.93, "word": "قولنا", "probability": 0.53009033203125}, {"start": 1568.93, "end": 1569.19, "word": " احنا", "probability": 0.7599283854166666}, {"start": 1569.19, "end": 1569.47, "word": " 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"probability": 0.96484375}, {"start": 1573.61, "end": 1573.79, "word": " O", "probability": 0.9501953125}, {"start": 1573.79, "end": 1574.35, "word": " الديهيد", "probability": 0.70416259765625}, {"start": 1574.35, "end": 1574.59, "word": " او", "probability": 0.897216796875}, {"start": 1574.59, "end": 1575.07, "word": " كيتون", "probability": 0.8253580729166666}, {"start": 1575.07, "end": 1576.31, "word": " تصير", "probability": 0.88623046875}, {"start": 1576.31, "end": 1577.13, "word": " C", "probability": 0.791015625}, {"start": 1577.13, "end": 1577.45, "word": " double", "probability": 0.9033203125}, {"start": 1577.45, "end": 1577.99, "word": " bond", "probability": 0.974609375}, {"start": 1577.99, "end": 1578.65, "word": " N", "probability": 0.974609375}, {"start": 1578.65, "end": 1580.41, "word": " CH2", "probability": 0.780517578125}, {"start": 1580.41, "end": 1581.23, "word": " CH3", "probability": 0.908203125}, {"start": 1581.23, "end": 1581.63, "word": " بصير", "probability": 0.67626953125}, {"start": 1581.63, "end": 1581.81, "word": " ال", "probability": 0.1715087890625}, {"start": 1581.81, "end": 1582.13, "word": " shift", "probability": 0.37890625}, {"start": 1582.13, "end": 1582.75, "word": " basis", "probability": 0.5732421875}, {"start": 1582.75, "end": 1583.79, "word": " وقولنا", "probability": 0.8548177083333334}, {"start": 1583.79, "end": 1583.93, "word": " ان", "probability": 0.76171875}, {"start": 1583.93, "end": 1584.59, "word": " التفاعل", "probability": 0.924072265625}, {"start": 1584.59, "end": 1584.95, "word": " بهذه", "probability": 0.571044921875}, {"start": 1584.95, "end": 1585.37, "word": " الحالة", "probability": 0.95654296875}, {"start": 1585.37, "end": 1585.57, "word": " ايش", "probability": 0.818359375}, {"start": 1585.57, "end": 1586.01, "word": " بنقول", "probability": 0.847412109375}, {"start": 1586.01, "end": 1586.51, "word": " عنه", "probability": 0.970703125}, {"start": 1586.51, "end": 1587.59, "word": " addition", "probability": 0.72607421875}, {"start": 1587.59, "end": 1590.37, "word": " elimination", "probability": 0.45068359375}], "temperature": 1.0}, {"id": 66, "seek": 160815, "start": 1591.67, "end": 1608.15, "text": "نسيته تفاعل تكوين الأكزينز والهيدرازونز والسمي كربازونز كل ال N-H2 مع ال C double bond O الديهيدوكيتون كانت تعمل C double bond N على خطوتين لكن في الأساس أن الأمين تفاعل كإيش؟", "tokens": [1863, 3794, 36081, 3224, 6055, 5172, 995, 30241, 6055, 4117, 2407, 9957, 16247, 4117, 11622, 9957, 11622, 16070, 3224, 25708, 2288, 31377, 11536, 11622, 16070, 38251, 1829, 9122, 25513, 31377, 11536, 11622, 28242, 2423, 426, 12, 39, 17, 20449, 2423, 383, 3834, 6086, 422, 2423, 16254, 3224, 25708, 2407, 4117, 36081, 11536, 25961, 2655, 6055, 25957, 1211, 383, 3834, 6086, 426, 15844, 16490, 9566, 35473, 9957, 44381, 8978, 16247, 3794, 32277, 14739, 16247, 2304, 9957, 6055, 5172, 995, 30241, 9122, 28814, 1829, 8592, 22807], "avg_logprob": -0.2680147142971263, "compression_ratio": 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{"start": 1598.03, "end": 1598.31, "word": " مع", "probability": 0.97119140625}, {"start": 1598.31, "end": 1598.53, "word": " ال", "probability": 0.82666015625}, {"start": 1598.53, "end": 1598.67, "word": " C", "probability": 0.28955078125}, {"start": 1598.67, "end": 1598.85, "word": " double", "probability": 0.446533203125}, {"start": 1598.85, "end": 1599.25, "word": " bond", "probability": 0.93896484375}, {"start": 1599.25, "end": 1599.57, "word": " O", "probability": 0.95263671875}, {"start": 1599.57, "end": 1600.69, "word": " الديهيدوكيتون", "probability": 0.676910400390625}, {"start": 1600.69, "end": 1601.27, "word": " كانت", "probability": 0.937255859375}, {"start": 1601.27, "end": 1601.59, "word": " تعمل", "probability": 0.9816080729166666}, {"start": 1601.59, "end": 1601.81, "word": " C", "probability": 0.76806640625}, {"start": 1601.81, "end": 1601.99, "word": " double", "probability": 0.91455078125}, {"start": 1601.99, "end": 1602.37, "word": " bond", "probability": 0.97119140625}, {"start": 1602.37, "end": 1602.53, "word": " N", "probability": 0.96337890625}, {"start": 1602.53, "end": 1602.73, "word": " على", "probability": 0.8720703125}, {"start": 1602.73, "end": 1603.41, "word": " خطوتين", "probability": 0.85845947265625}, {"start": 1603.41, "end": 1604.19, "word": " لكن", "probability": 0.82177734375}, {"start": 1604.19, "end": 1604.45, "word": " في", "probability": 0.91943359375}, {"start": 1604.45, "end": 1605.45, "word": " الأساس", "probability": 0.9401041666666666}, {"start": 1605.45, "end": 1606.13, "word": " أن", "probability": 0.591796875}, {"start": 1606.13, "end": 1606.79, "word": " الأمين", "probability": 0.8118489583333334}, {"start": 1606.79, "end": 1607.41, "word": " تفاعل", "probability": 0.9718017578125}, {"start": 1607.41, "end": 1608.15, "word": " كإيش؟", "probability": 0.85517578125}], "temperature": 1.0}, {"id": 67, "seek": 163448, "start": 1608.98, "end": 1634.48, "text": "كان uqlu5 وعمل addition الان بعد هيك ان ال addition اتبع ال elimination هذا امر ايش تاني هذا المحصلة النهائية لكن ال addition ادشن و ال uqlu5 ال uqlu5 فال amines تفاعلهم الأساسي بنقول هو ايش they react as uqlu5 as uqlu5 واضح؟", "tokens": [41361, 344, 80, 2781, 20, 4032, 25957, 1211, 4500, 2423, 7649, 39182, 39896, 4117, 16472, 2423, 4500, 1975, 2655, 3555, 3615, 2423, 29224, 23758, 1975, 29973, 1975, 1829, 8592, 6055, 7649, 1829, 23758, 9673, 5016, 36520, 3660, 28239, 3224, 16373, 10632, 44381, 2423, 4500, 1975, 3215, 8592, 1863, 4032, 2423, 344, 80, 2781, 20, 2423, 344, 80, 2781, 20, 6156, 6027, 669, 1652, 6055, 5172, 995, 30241, 16095, 16247, 3794, 32277, 1829, 44945, 39648, 31439, 1975, 1829, 8592, 436, 4515, 382, 344, 80, 2781, 20, 382, 344, 80, 2781, 20, 4032, 46958, 5016, 22807], "avg_logprob": -0.2791118521439402, "compression_ratio": 1.6785714285714286, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1608.98, "end": 1609.28, "word": "كان", "probability": 0.80810546875}, {"start": 1609.28, "end": 1610.44, "word": " 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"probability": 0.437744140625}, {"start": 1620.98, "end": 1621.72, "word": " uqlu5", "probability": 0.9527587890625}, {"start": 1621.72, "end": 1621.88, "word": " ال", "probability": 0.705078125}, {"start": 1621.88, "end": 1622.78, "word": " uqlu5", "probability": 0.9798583984375}, {"start": 1622.78, "end": 1623.48, "word": " فال", "probability": 0.868408203125}, {"start": 1623.48, "end": 1624.1, "word": " amines", "probability": 0.5814208984375}, {"start": 1624.1, "end": 1624.84, "word": " تفاعلهم", "probability": 0.8880859375}, {"start": 1624.84, "end": 1625.52, "word": " الأساسي", "probability": 0.81939697265625}, {"start": 1625.52, "end": 1625.8, "word": " بنقول", "probability": 0.789794921875}, {"start": 1625.8, "end": 1625.98, "word": " هو", "probability": 0.82421875}, {"start": 1625.98, "end": 1627.3, "word": " ايش", "probability": 0.8304036458333334}, {"start": 1627.3, "end": 1627.58, "word": " they", "probability": 0.52392578125}, {"start": 1627.58, "end": 1628.46, "word": " react", "probability": 0.92041015625}, {"start": 1628.46, "end": 1629.24, "word": " as", "probability": 0.97802734375}, {"start": 1629.24, "end": 1630.84, "word": " uqlu5", "probability": 0.82696533203125}, {"start": 1630.84, "end": 1632.24, "word": " as", "probability": 0.55859375}, {"start": 1632.24, "end": 1633.2, "word": " uqlu5", "probability": 0.968017578125}, {"start": 1633.2, "end": 1634.48, "word": " واضح؟", "probability": 0.8817138671875}], "temperature": 1.0}, {"id": 68, "seek": 166584, "start": 1636.42, "end": 1665.84, "text": "لكن لو جينا سألناكم ال reaction of amines with aldehydes and ketones is a nucleophilic addition in a brain cell واضح؟ انه بعدك followed by elimination على أنه الرأس مرة تبسيط واضح؟ with acids and their derivatives a nucleophilic substitution with alkyl halides برضه nucleophilic substitution", "tokens": [1211, 19452, 45164, 10874, 1829, 8315, 8608, 10721, 1211, 8315, 24793, 2423, 5480, 295, 669, 1652, 365, 16798, 68, 3495, 14792, 293, 14979, 2213, 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2170.46, "end": 2170.94, "word": "يعني", "probability": 0.9501953125}, {"start": 2170.94, "end": 2171.66, "word": " بتكون", "probability": 0.9150390625}, {"start": 2171.66, "end": 2172.12, "word": " عشر", "probability": 0.93359375}, {"start": 2172.12, "end": 2174.08, "word": " كربونات،", "probability": 0.7752482096354166}, {"start": 2174.08, "end": 2174.82, "word": " اتنائش،", "probability": 0.833740234375}, {"start": 2174.82, "end": 2175.12, "word": " اربعة", "probability": 0.6787109375}, {"start": 2175.12, "end": 2175.5, "word": " عاشر،", "probability": 0.717529296875}, {"start": 2175.5, "end": 2175.76, "word": " ستة", "probability": 0.84619140625}, {"start": 2175.76, "end": 2176.0, "word": " عاشر،", "probability": 0.9342041015625}, {"start": 2176.0, "end": 2176.32, "word": " تمانة", "probability": 0.6844889322916666}, {"start": 2176.32, "end": 2176.7, "word": " عاشر،", "probability": 0.969970703125}, {"start": 2176.7, "end": 2177.22, "word": " اشرين", "probability": 0.714599609375}, 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"end": 2183.76, "word": " هذه", "probability": 0.73193359375}, {"start": 2183.76, "end": 2184.58, "word": " المركبات", "probability": 0.84661865234375}, {"start": 2184.58, "end": 2185.62, "word": " التمتاز", "probability": 0.94384765625}, {"start": 2185.62, "end": 2186.14, "word": " ان", "probability": 0.69140625}, {"start": 2186.14, "end": 2186.58, "word": " فيها", "probability": 0.916259765625}, {"start": 2186.58, "end": 2187.18, "word": " طرف", "probability": 0.996337890625}, {"start": 2187.18, "end": 2189.48, "word": " polar", "probability": 0.91796875}, {"start": 2189.48, "end": 2191.8, "word": " و", "probability": 0.94189453125}, {"start": 2191.8, "end": 2192.3, "word": " طرف", "probability": 0.8984375}, {"start": 2192.3, "end": 2193.5, "word": " non", "probability": 0.97119140625}, {"start": 2193.5, "end": 2193.98, "word": " polar", "probability": 0.51318359375}], "temperature": 1.0}, {"id": 91, "seek": 220282, "start": 2195.86, "end": 2202.82, "text": "الـ R في الـ fatty acids الـ non-polar الكبير، خلّينا نقول من عشرة و فوق", "tokens": [6027, 39184, 497, 8978, 2423, 39184, 24898, 21667, 2423, 39184, 2107, 12, 12892, 289, 33251, 3555, 13546, 12399, 16490, 1211, 11703, 9957, 995, 8717, 39648, 9154, 6225, 8592, 25720, 4032, 6156, 30543], "avg_logprob": -0.27296401515151514, "compression_ratio": 1.0679611650485437, "no_speech_prob": 0.0, "words": [{"start": 2195.86, "end": 2196.3, "word": "الـ", "probability": 0.703857421875}, {"start": 2196.3, "end": 2196.62, "word": " R", "probability": 0.64453125}, {"start": 2196.62, "end": 2197.52, "word": " في", "probability": 0.8154296875}, {"start": 2197.52, "end": 2197.76, "word": " الـ", "probability": 0.5850830078125}, {"start": 2197.76, "end": 2198.04, "word": " fatty", "probability": 0.344482421875}, {"start": 2198.04, "end": 2198.72, "word": " acids", "probability": 0.6494140625}, {"start": 2198.72, "end": 2199.26, "word": " الـ", "probability": 0.7666015625}, {"start": 2199.26, "end": 2199.4, "word": " non", "probability": 0.64794921875}, {"start": 2199.4, "end": 2199.8, "word": "-polar", "probability": 0.8408203125}, {"start": 2199.8, "end": 2200.82, "word": " الكبير،", "probability": 0.8463134765625}, {"start": 2200.82, "end": 2201.48, "word": " خلّينا", "probability": 0.80966796875}, {"start": 2201.48, "end": 2201.68, "word": " نقول", "probability": 0.994140625}, {"start": 2201.68, "end": 2201.84, "word": " من", "probability": 0.9462890625}, {"start": 2201.84, "end": 2202.28, "word": " عشرة", "probability": 0.87451171875}, {"start": 2202.28, "end": 2202.42, "word": " و", "probability": 0.97021484375}, {"start": 2202.42, "end": 2202.82, "word": " فوق", "probability": 0.6522216796875}], "temperature": 1.0}, {"id": 92, "seek": 222888, "start": 2204.38, "end": 2228.88, "text": "وبناء على ذلك الجزيء بمجمله يغلب عليه الـ non-polar part فبصير water soluble ولا insoluble؟ بصير non-polar طالما صار non-polar صار water insoluble بصير دوب في ال organic solvent إذا هذه الجزيئات اللي فيها القاري الكبيرة هي اللي بنسميها الـ fatty acids", "tokens": [37746, 1863, 16606, 15844, 29910, 23275, 25724, 11622, 1829, 38207, 4724, 2304, 7435, 42213, 3224, 7251, 17082, 46152, 47356, 2423, 39184, 2107, 12, 12892, 289, 644, 6156, 3555, 9381, 13546, 1281, 24807, 638, 49429, 1028, 39754, 638, 22807, 4724, 9381, 13546, 2107, 12, 12892, 289, 23032, 6027, 15042, 20328, 9640, 2107, 12, 12892, 289, 20328, 9640, 1281, 1028, 39754, 638, 4724, 9381, 13546, 11778, 37746, 8978, 2423, 10220, 33575, 11933, 15730, 29538, 25724, 11622, 1829, 19986, 9307, 13672, 1829, 8978, 11296, 25062, 9640, 1829, 33251, 3555, 48923, 39896, 13672, 1829, 44945, 38251, 1829, 11296, 2423, 39184, 24898, 21667], "avg_logprob": -0.2788825865947839, "compression_ratio": 1.6415929203539823, "no_speech_prob": 0.0, "words": [{"start": 2204.38, "end": 2205.06, "word": "وبناء", "probability": 0.794921875}, {"start": 2205.06, "end": 2205.48, "word": " على", "probability": 0.751953125}, {"start": 2205.48, "end": 2206.18, "word": " 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"end": 2221.2, "word": " بصير", "probability": 0.7610677083333334}, {"start": 2221.2, "end": 2221.42, "word": " دوب", "probability": 0.78857421875}, {"start": 2221.42, "end": 2221.58, "word": " في", "probability": 0.92333984375}, {"start": 2221.58, "end": 2221.68, "word": " ال", "probability": 0.71728515625}, {"start": 2221.68, "end": 2222.16, "word": " organic", "probability": 0.83154296875}, {"start": 2222.16, "end": 2222.8, "word": " solvent", "probability": 0.763671875}, {"start": 2222.8, "end": 2223.48, "word": " إذا", "probability": 0.600341796875}, {"start": 2223.48, "end": 2224.54, "word": " هذه", "probability": 0.84130859375}, {"start": 2224.54, "end": 2225.54, "word": " الجزيئات", "probability": 0.95869140625}, {"start": 2225.54, "end": 2225.74, "word": " اللي", "probability": 0.784423828125}, {"start": 2225.74, "end": 2226.12, "word": " فيها", "probability": 0.979248046875}, {"start": 2226.12, "end": 2226.64, "word": " القاري", "probability": 0.6139322916666666}, {"start": 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التفاعل، الآن هاي كحول في الجليسرين و هاي حمض، خليهم يتفاعلوا", "tokens": [2407, 46958, 5016, 22807, 8032, 2304, 4724, 3555, 3794, 41193, 3660, 9122, 25513, 2407, 4117, 3794, 26895, 4117, 5551, 3794, 1863, 3794, 9122, 3555, 9640, 12399, 6024, 48506, 45164, 5551, 7435, 1829, 8315, 4032, 12174, 12610, 8315, 9122, 5016, 12610, 30767, 16373, 3215, 11331, 2304, 11242, 12399, 13412, 2407, 4724, 40228, 9566, 1829, 22653, 22807, 11933, 1829, 14851, 2288, 12399, 45164, 5551, 9778, 3215, 8315, 36632, 9122, 5016, 12610, 30767, 16373, 3215, 11331, 2304, 11242, 12399, 11933, 1829, 14851, 2288, 12399, 23758, 5551, 9778, 3215, 8315, 16712, 5172, 995, 30241, 12399, 6024, 48506, 8032, 47302, 9122, 5016, 12610, 8978, 25724, 20292, 3794, 2288, 9957, 4032, 8032, 47302, 11331, 2304, 11242, 12399, 16490, 20292, 16095, 7251, 2655, 5172, 995, 30241, 14407], "avg_logprob": -0.21410123868422073, "compression_ratio": 1.9565217391304348, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2266.07, 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خلال", "probability": 0.9952799479166666}, {"start": 2986.39, "end": 2986.61, "word": " أنه", "probability": 0.4925537109375}, {"start": 2986.61, "end": 2986.71, "word": " أنا", "probability": 0.716796875}, {"start": 2986.71, "end": 2987.27, "word": " بستفيد", "probability": 0.8802490234375}, {"start": 2987.27, "end": 2987.45, "word": " من", "probability": 0.98828125}, {"start": 2987.45, "end": 2988.09, "word": " التفاعل", "probability": 0.9146728515625}, {"start": 2988.09, "end": 2988.67, "word": " الأصلي", "probability": 0.7545572916666666}, {"start": 2988.67, "end": 2988.75, "word": " اللي", "probability": 0.96435546875}, {"start": 2988.75, "end": 2989.13, "word": " أخدته", "probability": 0.94873046875}, {"start": 2989.13, "end": 2989.21, "word": " في", "probability": 0.904296875}, {"start": 2989.21, "end": 2989.59, "word": " شبتر", "probability": 0.78741455078125}, {"start": 2989.59, "end": 2990.11, "word": " واحد", "probability": 0.93017578125}, {"start": 2990.11, "end": 2990.65, "word": " أنه", "probability": 0.676025390625}, {"start": 2990.65, "end": 2991.25, "word": " الألكيز", "probability": 0.63677978515625}, {"start": 2991.25, "end": 2991.73, "word": " بتحض", "probability": 0.5010986328125}, {"start": 2991.73, "end": 2991.89, "word": " مع", "probability": 0.80517578125}, {"start": 2991.89, "end": 2992.13, "word": " ال", "probability": 0.63916015625}, {"start": 2992.13, "end": 2993.95, "word": " oxygen", "probability": 0.2073974609375}, {"start": 2993.95, "end": 2994.31, "word": " و", "probability": 0.56884765625}, {"start": 2994.31, "end": 2994.47, "word": " ال", "probability": 0.52294921875}, {"start": 2994.47, "end": 2995.35, "word": " combustion", "probability": 0.87158203125}, {"start": 2995.35, "end": 2996.67, "word": " طلعوا", "probability": 0.8939208984375}, {"start": 2996.67, "end": 2996.91, "word": " ثانو", "probability": 0.8336588541666666}, {"start": 2996.91, "end": 2997.11, "word": " أكسيد", "probability": 0.848388671875}, {"start": 2997.11, "end": 2997.53, "word": " كربون", "probability": 0.9375}, {"start": 2997.53, "end": 2997.65, "word": " و", "probability": 0.98876953125}, {"start": 2997.65, "end": 2997.97, "word": " ميه", "probability": 0.71630859375}, {"start": 2997.97, "end": 2998.15, "word": " و", "probability": 0.9931640625}, {"start": 2998.15, "end": 2998.63, "word": " حرارة", "probability": 0.980712890625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2999.693, "duration_after_vad": 2875.9274999999875}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d63786d546ffad1946dfdf895f0101f76e774594
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/qMxA2LgN_Fc_raw.srt
@@ -0,0 +1,2208 @@
+1
+00:00:19,570 --> 00:00:26,370
+بسم الله الرحمن الرحيم اليوم ضيلنا أشياء بسيطة في
+
+2
+00:00:26,370 --> 00:00:30,890
+موضوع ال amines قبل ما ننتقل لجزء ال biochemistry
+
+3
+00:00:30,890 --> 00:00:36,850
+طبعا اتفقنا المرة الماضية أن ال amines هم مراكبات
+
+4
+00:00:36,850 --> 00:00:43,470
+ال nitrogen من أهم الأشياء اللي بتميزهم هو وجود
+
+5
+00:00:43,470 --> 00:00:47,730
+إيشالـ lone pair of electrons اللي موجودة على الـ
+
+6
+00:00:47,730 --> 00:00:52,910
+Nitrogens طالما في عليهم lone pair of electrons و
+
+7
+00:00:52,910 --> 00:00:56,150
+ال base is electron donor يعني ال base هي اللي
+
+8
+00:00:56,150 --> 00:01:02,370
+بتعطي إلكترونات فال amines arebasis واضح سبب أنه
+
+9
+00:01:02,370 --> 00:01:06,730
+بالأمينز قواعد هو وجود أزواج الإلكترونات فهم
+
+10
+00:01:06,730 --> 00:01:11,010
+كقاعدة بيعطوا أزواج إلكترونات هذا ضمن تعريف إيش
+
+11
+00:01:11,010 --> 00:01:19,710
+Lewis definition الآن لو إجالهم H plus عندي زوج
+
+12
+00:01:19,710 --> 00:01:23,270
+إلكترونات والـ H مش حاملة إلكترونات شو هيعملوا
+
+13
+00:01:23,270 --> 00:01:28,420
+فيها؟هيتفاعلوا معها هتصير الرابط المتكونة
+
+14
+00:01:28,420 --> 00:01:31,840
+Coordinated Covalent bond بمعنى ان زوجين
+
+15
+00:01:31,840 --> 00:01:37,940
+الالكترونات من النيتروجين والـ H بلس لما تتفاعل
+
+16
+00:01:37,940 --> 00:01:43,340
+معها بتكون مش حاملة الالكترونات ولذلك مثلا هنا
+
+17
+00:01:43,340 --> 00:01:48,380
+ارسملكوا كيف الأمونيا لو اتفاعل معها H بلس لاحظوا
+
+18
+00:01:48,380 --> 00:01:52,990
+الأمونيا الأن H3أساساً الـNitrogen في مداره
+
+19
+00:01:52,990 --> 00:01:57,070
+الخارجي خمس إلكترونات، فلو تخيلتم اللي كانوا
+
+20
+00:01:57,070 --> 00:02:00,470
+باللون الأزرق، تلاتة منهم عملوا روابط مع
+
+21
+00:02:00,470 --> 00:02:03,670
+الـHydrogen، فهذه الرابطة مع الـHydrogen في
+
+22
+00:02:03,670 --> 00:02:07,510
+الأمونيا أصلاً، إلكترون من الـNitrogen وإلكترون من
+
+23
+00:02:07,510 --> 00:02:11,040
+الـHydrogen، اللي بيانه بالأخضركذلك الرابط الثاني
+
+24
+00:02:11,040 --> 00:02:15,520
+والرابط الثالثة بقى عندي زوج إلكترونات إجاله H من
+
+25
+00:02:15,520 --> 00:02:21,180
+الخارج الـH إجت بدون إلكترونات بناء على ذلك الرابط
+
+26
+00:02:21,180 --> 00:02:24,560
+اللي هنا إيش بده تصير Coordinate Covalent bond
+
+27
+00:02:24,560 --> 00:02:29,460
+بمعنى أصلها أنه two electrons from the nitrogen
+
+28
+00:02:29,460 --> 00:02:35,300
+and no electron from hydrogen طبعا هذا بيخلي برضه
+
+29
+00:02:35,300 --> 00:02:41,700
+ال aminesباسيز بمفهوم لوري برونستيد definition
+
+30
+00:02:41,700 --> 00:02:47,240
+ليش؟ لأنه بمفهومه إن الحامض هو اللي بيعطي H plus
+
+31
+00:02:47,240 --> 00:02:53,180
+والباس هي اللي بتكتسب H plus الآن هذه اكتسبت H
+
+32
+00:02:53,180 --> 00:02:57,600
+plus ولا لأ؟ إذا أيضا ضمن تعريف لوري برونستيد
+
+33
+00:02:57,600 --> 00:03:03,860
+definition بتكون هذه base لكن لاحظوا ضمن تعريف
+
+34
+00:03:03,860 --> 00:03:09,080
+Arrheniusإن الـ base لازم يكون فيها OH- الأمونية
+
+35
+00:03:09,080 --> 00:03:13,420
+ما انحسبتش base و لذلك اتدرجوا في تعريفية الأحماض
+
+36
+00:03:13,420 --> 00:03:17,740
+يعني كان أقدم تعريف Arrhenius depression كان حاصر
+
+37
+00:03:17,740 --> 00:03:22,280
+ال bases في المواد ال hydroxides اللي بيعطوا ال OH
+
+38
+00:03:22,280 --> 00:03:29,060
+- بعد إكسرنا نقول لأ هو كل حاجة بتكتسب H plus يمكن
+
+39
+00:03:29,060 --> 00:03:33,960
+أننا نعتبرها base أساسا ال OH- كانت تكتسب H plus و
+
+40
+00:03:33,960 --> 00:03:39,160
+تعمل ميهواضح طب ما الأن H3 كمان بتكتسب جعب H plus
+
+41
+00:03:39,160 --> 00:03:47,280
+واضح الفكرة وإجا اللي هو Lewis definition أكتر
+
+42
+00:03:47,280 --> 00:03:51,440
+تخصيصا وقال أن ال base اللي فيه أزواج إلكترونات
+
+43
+00:03:51,440 --> 00:03:55,340
+مافيش تناقض ما بين التعريفات لكن فيه نظرة أكتر
+
+44
+00:03:55,340 --> 00:04:00,790
+تخصيصيةالان عشانك لو حطينا ال ammonia مع الميه
+
+45
+00:04:00,790 --> 00:04:05,510
+طبعا الميه هنا حاطين ال H3O plus كلكوا عارفين ان
+
+46
+00:04:05,510 --> 00:04:11,070
+الميه ايش هي أساسا H2O لكن هو اتخيل نسبة التأيون
+
+47
+00:04:11,070 --> 00:04:17,430
+اللي هي بسيطة جدا اللي درستها في الميه ان H2O زائد
+
+48
+00:04:17,430 --> 00:04:23,450
+H2O بتفاعل اتزان بطلع نسبة بسيطة جدا من H3O plus
+
+49
+00:04:23,450 --> 00:04:30,600
+زائد OH minusعشان يك هو لما هنا بيكتب h3o plus
+
+50
+00:04:30,600 --> 00:04:36,820
+هالنسبة البسيطة جدا اللي اتكونت من يعني تفاعل
+
+51
+00:04:36,820 --> 00:04:41,950
+الميه مع بعضها، اذا هنا ايش بتفترض انه موجود؟هو H
+
+52
+00:04:41,950 --> 00:04:46,770
+minus كمان ولذلك لما تيجي الأمونيا من الميه هدم ال
+
+53
+00:04:46,770 --> 00:04:52,590
+H3O plus تاخد ال H plus تعمل ان H4 plus زاد H2O هو
+
+54
+00:04:52,590 --> 00:04:57,370
+أساسا في ايون موجب بكل حاله لأ هو الموجب كان معاه
+
+55
+00:04:57,370 --> 00:05:02,330
+سالب الآن لما صارت الأمونيوم ايون هانا موجب ايش
+
+56
+00:05:02,330 --> 00:05:07,500
+صار معاه؟سالم و لذلك احنا سنقول ان الامونيا لما
+
+57
+00:05:07,500 --> 00:05:14,600
+ندوبها في الميه بتعطي امونيوم هيدروكسيد واضح؟ الكل
+
+58
+00:05:14,600 --> 00:05:19,220
+بيعرف ان احنا بندوب الامونيا في الميه بتعطي ايش؟
+
+59
+00:05:19,220 --> 00:05:23,750
+امونيوم هيدروكسيدكذلك الحالة لو دوبنا ال ammonia
+
+60
+00:05:23,750 --> 00:05:29,390
+مثلا في ال HCl ال ammonia هتاخد H من هنا هصير عندى
+
+61
+00:05:29,390 --> 00:05:34,510
+ammonium ion مع ال Cl minus ammonium chloride يمكن
+
+62
+00:05:34,510 --> 00:05:39,130
+هذا ما معاكم في المدرسة انه بإمكاننا احنا نجيب
+
+63
+00:05:39,130 --> 00:05:44,180
+نقطةمن ال ammonia من محلول ال ammonia نحطها هنا
+
+64
+00:05:44,180 --> 00:05:49,760
+نقطة من ال HCl نحطه هنا و نسيبهم جانب بعض بتتبخر
+
+65
+00:05:49,760 --> 00:05:53,860
+.. بتتبخر ال ammonia بتتبخر ال HCl لما يلتجوا مع
+
+66
+00:05:53,860 --> 00:05:57,620
+بعض ال ammonia مع ال HCl شو هيعملوا؟ ammonium
+
+67
+00:05:57,620 --> 00:06:02,660
+chloride ال ammonium chloride إيش لونه؟
+
+68
+00:06:02,660 --> 00:06:08,310
+تذكروا شغل المدرسة؟أبيض و لذلك كنا نقول أنه ال
+
+69
+00:06:08,310 --> 00:06:12,810
+ammonia مع ال HCl بيعطوا سحب بيضاء من ال ammonium
+
+70
+00:06:12,810 --> 00:06:18,820
+chloride بهذا النص مرت عليكم في المدرسة ولا لأ؟سحب
+
+71
+00:06:18,820 --> 00:06:23,780
+.. سحب بيضاء أو بقعة بيضة هم عادة بيعملوها .. عادة
+
+72
+00:06:23,780 --> 00:06:28,660
+بيعملوا هذه الشغلة كتجربة .. كتجربة بيجيبوا انبوبة
+
+73
+00:06:28,660 --> 00:06:32,500
+بهذا الشكل بيجيبوا انبوبة زجاجية مفتوحة الطرفين
+
+74
+00:06:32,500 --> 00:06:38,270
+بهذا الشكل بيحطوا هنا نقطة أمونياو بيحطوا هان طبعا
+
+75
+00:06:38,270 --> 00:06:41,090
+أمونيا البعض هيقوللي غاز أمونيا مدور باب ميه
+
+76
+00:06:41,090 --> 00:06:44,970
+أمونيا ميكروفسيت بيطلع أمونيا واضح؟ و بيحطوا هنا
+
+77
+00:06:44,970 --> 00:06:49,430
+HCl الآن بيمشوا بتبخر الغازين هذا بتبخر و هذا
+
+78
+00:06:49,430 --> 00:06:53,570
+بتبخر و سرعته بتعتمد على ال molecular weight تبعه
+
+79
+00:06:53,570 --> 00:06:58,050
+اللي ال molecular weight تبعه الجيل بيمشي إيش بطيء
+
+80
+00:06:58,050 --> 00:07:00,890
+فهذا بيمشي له شوية هنا هذا بيمشي له شوية هنا لما
+
+81
+00:07:00,890 --> 00:07:05,280
+بيلتقواإيش بدهم يعملوه اموريو ميكلورايت فجأة
+
+82
+00:07:05,280 --> 00:07:09,640
+بيصيروا الناس يشوفوا هنا إيش ابخرة بيضاء واضح
+
+83
+00:07:09,640 --> 00:07:15,310
+بيصيروا يشوفوا ابخرة بيضاء هذه الأبخرة هيالأمونيوم
+
+84
+00:07:15,310 --> 00:07:19,250
+كلورايت لو انتوا بتاخدوا معمل general chemistry
+
+85
+00:07:19,250 --> 00:07:22,410
+بتكون تجربة بتعملواها بتجيبوا الأنبوبة و بتحطوهم
+
+86
+00:07:22,410 --> 00:07:27,450
+بتشوفوا بعينكم و عشان دائما بنقول التعليم الجامعي
+
+87
+00:07:27,450 --> 00:07:32,150
+لا يجب أن ينفصل بحال من الأحوال اللي عاملة عن
+
+88
+00:07:32,150 --> 00:07:36,290
+الجزء النظري في أي خطة تدريسية
+
+89
+00:07:40,010 --> 00:07:45,710
+طالما قلنا ان ال amines are bases معناه ذلك زي ما
+
+90
+00:07:45,710 --> 00:07:50,130
+ال acids كنا نقول عنهم acids ويلهم BKA ال amines
+
+91
+00:07:50,130 --> 00:07:57,350
+بيكونيلهم BKB واضح؟ BKB وقلنا كل ما كانت في ال
+
+92
+00:07:57,350 --> 00:08:02,150
+acids ال BKA أقل كل ما كان الحامض أقوى الآن في ال
+
+93
+00:08:02,150 --> 00:08:07,530
+bases بنقول كل ما ال BKB بتكون أقل كل ما القاعدة
+
+94
+00:08:07,530 --> 00:08:12,460
+أيضا بتكون أقوى واضح؟الجدول اللى موجود عندنا حقيقة
+
+95
+00:08:12,460 --> 00:08:22,240
+مش كاتبنا ال BKB كاتب ال BKA ل ال conjugate acid
+
+96
+00:08:22,240 --> 00:08:26,700
+conjugate acid يعني الحمض المرافق عادة بين ال acid
+
+97
+00:08:26,700 --> 00:08:32,620
+و ال base المرافقة بيكون الفرق إيش؟هيدروجين يعني
+
+98
+00:08:32,620 --> 00:08:38,560
+انا لما بدي اقول nh4 plus هذا الاسل ال base
+
+99
+00:08:38,560 --> 00:08:45,500
+المرافقة nh3 و هكذا بناء على ذلك هدولة اللي بيكي
+
+100
+00:08:45,500 --> 00:08:53,100
+ايه و بيكي بيه كلنا عارفين ان بيكي ايهزائد ال BKB
+
+101
+00:08:53,100 --> 00:08:59,420
+بساوي 14 بناء على ذلك لو احنا كنا لهذه المجموعة من
+
+102
+00:08:59,420 --> 00:09:07,300
+ال Amines بدنا نشوف ال BKB بدنا نطرح من 14 يعني
+
+103
+00:09:07,300 --> 00:09:13,900
+مثلا لل Ammonia ال BKB أربعة و سبعة للميث الأمين
+
+104
+00:09:15,270 --> 00:09:21,390
+تلاتة و أربعة بالعشرة نفترض للضايف مثل أميل تلاتة
+
+105
+00:09:21,390 --> 00:09:25,870
+و تلاتة بالعشرة لو أجينا مقارنة مثلا مع الأنليل
+
+106
+00:09:25,870 --> 00:09:34,290
+حوالي تسعة و أربعة بالعشرةالان لو اجينا للان مثل
+
+107
+00:09:34,290 --> 00:09:40,410
+الأللين ايضا حوالي تسعة و اتنين بالعشرة الان
+
+108
+00:09:40,410 --> 00:09:46,010
+لاحظوا ع طول ملاحظة الأمينز اللي في الأول مثل أمين
+
+109
+00:09:46,010 --> 00:09:51,890
+ضاي مثل أمين و لحد الأللين هنا صار عندى تغير كتير
+
+110
+00:09:51,890 --> 00:09:57,550
+يعني لحد هدولة كلهمكانت ال بي كي بي قليلة تلاتة
+
+111
+00:09:57,550 --> 00:10:03,130
+تلاتة أربعة لما صرت فيه الانليل و التوابع صرت تسعة
+
+112
+00:10:03,130 --> 00:10:09,030
+الان هدول ايش بيفرقوا عن بعض لحد هذا الخط هدول
+
+113
+00:10:09,030 --> 00:10:14,510
+اللي فوق aliphatic amines اللي تحت aromatic amines
+
+114
+00:10:14,510 --> 00:10:22,190
+واضح؟ اذا هذه منطقاتالالفاتك أمين هذي منطقة ال
+
+115
+00:10:22,190 --> 00:10:27,870
+aromatic amines لو إجينا سألنا مين بيكونوا ك basis
+
+116
+00:10:27,870 --> 00:10:33,430
+أقوى الالفاتك أمين ولا ال aromatic amines؟
+
+117
+00:10:33,430 --> 00:10:40,000
+الالفاتك أمينليش؟ لأنه كل ما ال BKB بتكون أقل كل
+
+118
+00:10:40,000 --> 00:10:45,500
+ما كانت القاعدة أقوى، إذا ال aliphatic amines are
+
+119
+00:10:45,500 --> 00:10:50,460
+stronger bases than aromatic amines، يعني لما نجيب
+
+120
+00:10:50,460 --> 00:10:54,740
+ال QA سؤال صح و غلط ال aliphatic amines are فراغ
+
+121
+00:10:54,740 --> 00:11:00,120
+bases than aromatic amines، they arestronger basis
+
+122
+00:11:00,120 --> 00:11:05,660
+هذا عرفناها، الآن بعد كمان ممكن نكمل لكم، نقولكم
+
+123
+00:11:05,660 --> 00:11:14,120
+إيش ال due to بسبب إيش؟ ليش بدنا نحكي غلط؟ بدنا
+
+124
+00:11:14,120 --> 00:11:19,180
+نحكي غلط؟ ليش ال aliphatic a means
+
+125
+00:11:22,420 --> 00:11:27,220
+أقوى كقواعد من ال aromatic amines بهمش بدي أعلق
+
+126
+00:11:27,220 --> 00:11:32,260
+على الخطأ اللي عملته بدي أعلق على الخطأ اللي عملته
+
+127
+00:11:32,260 --> 00:11:38,140
+عشان ما تكرروهش رجاء انا لما بقول انه بسبب فواحدة
+
+128
+00:11:38,140 --> 00:11:44,020
+جالتلي ع طول بسبب ال BKB هذا الكلام غير بقبول منكم
+
+129
+00:11:44,020 --> 00:11:48,400
+انا لما قرأت ال BKB
+
+130
+00:11:50,390 --> 00:11:54,430
+لقيت هذه جليلة و هذه عالية قولت ال aromatic amines
+
+131
+00:11:54,430 --> 00:12:00,510
+أقوى من ال aromatic amines زي ما أجي على اتنين بني
+
+132
+00:12:00,510 --> 00:12:04,830
+أدمين أطفال against طولهم هذا طوله متر و هذا طوله
+
+133
+00:12:04,830 --> 00:12:10,750
+سبعين الآن اللي طوله متر بقول عنه أطول من اللي
+
+134
+00:12:10,750 --> 00:12:15,230
+طوله سبعين الان لما أقولكم ليش ماحدش يقوللي أنه
+
+135
+00:12:15,230 --> 00:12:20,930
+طوله مترthis is nonsense ممكن تقولولي لأنه في
+
+136
+00:12:20,930 --> 00:12:25,730
+العمر أكبر يمكن يكون هذا السبب هذا بيصير سبب لو
+
+137
+00:12:25,730 --> 00:12:29,670
+اتنين بنفس العمر ممكن تقولولي وراثيا هذا كل أسر
+
+138
+00:12:29,670 --> 00:12:33,750
+تطويل هذا أسر .. هيك بيصير سبب بس إن أجيب لقياسه
+
+139
+00:12:33,750 --> 00:12:38,410
+وأقول عنه سبب بسبب ال BKB لو أنا أساسا استنتجت أن
+
+140
+00:12:38,410 --> 00:12:43,790
+هذا أقوى من هذا لأن ال BKB هنا أقل من هنا إذا هذا
+
+141
+00:12:43,790 --> 00:12:44,270
+أقوى
+
+142
+00:12:47,630 --> 00:12:55,650
+بدي كلام إيش؟ بدي كلام كيمية طبعا معنى بيس إنه
+
+143
+00:12:55,650 --> 00:12:59,650
+بتعطي إلكترونات إذا للسبب شيء يمنع من إعطاء
+
+144
+00:12:59,650 --> 00:13:06,400
+الإلكترونات أو يقلل إعطاء الإلكترونات، واضح؟السبب
+
+145
+00:13:06,400 --> 00:13:10,740
+شيء يمنع أو يقلل من إعطاء الإلكترونات هذا السبب
+
+146
+00:13:10,740 --> 00:13:14,400
+فعلا ممكن يكون inductive effect و فعلا ممكن يكون
+
+147
+00:13:14,400 --> 00:13:18,980
+resonance effect في حالة ال aliphatic amines وهي
+
+148
+00:13:18,980 --> 00:13:23,820
+بالقاري المركبين بيشيبوا بعض القليلين مثلا ال BKA
+
+149
+00:13:23,820 --> 00:13:27,740
+تبعت الحامض المرافق له أربعة و ستة يعني ال BKB
+
+150
+00:13:27,740 --> 00:13:33,980
+تبعته جداشتسعة وأربعة هانا لل .. لل Cyclohex
+
+151
+00:13:33,980 --> 00:13:39,400
+الأمين، هذا ألفتك، مافي double bonds، Cyclic
+
+152
+00:13:39,400 --> 00:13:43,700
+alkanes are ألفتك، هذا كدهش؟ أربعة واتنين، مين
+
+153
+00:13:43,700 --> 00:13:48,730
+كباس أقوى؟ ال Cyclohex الأمين ولا الألليين؟الـ
+
+154
+00:13:48,730 --> 00:13:53,770
+Cyclohexane الأمين أقوى الآن السبب أن هذا زوج
+
+155
+00:13:53,770 --> 00:13:58,830
+الإلكترونات بدل ما يكون جاهز يطلع برا و يتفاعل برا
+
+156
+00:13:58,830 --> 00:14:04,310
+قاعد بيعمل resonance جوا الجزء هذا زوج الإلكترونات
+
+157
+00:14:04,310 --> 00:14:09,660
+بيطلع للخارججاهز إنه يُعطى للخارج و ال base هي
+
+158
+00:14:09,660 --> 00:14:15,220
+اللي بتعطي إيش إلكترونات فهذا بدل ما يروح للخارج و
+
+159
+00:14:15,220 --> 00:14:20,640
+يظهر قوة المركب ك base قاعد بيجي بلوف هنا و بيعمل
+
+160
+00:14:20,640 --> 00:14:24,360
+resonance .. resonance تاني بيصير مرة minus على ال
+
+161
+00:14:24,360 --> 00:14:26,420
+carbon مرة على ال carbon التاني مرة على ال carbon
+
+162
+00:14:26,420 --> 00:14:32,020
+التالتة إذا هو قاعد المجهود تبع وين؟ جوا الجزء
+
+163
+00:14:32,020 --> 00:14:37,990
+فبالنسبة للخارجهو لا يعطي إلكترونات هو قاعد بيعمل
+
+164
+00:14:37,990 --> 00:14:41,990
+resonance جوا الجزئ فما بيعطي إلكترونات للخارج ال
+
+165
+00:14:41,990 --> 00:14:46,870
+basic اللي بتعطي إلكترونات لمن؟ للخارج هذا إذا
+
+166
+00:14:46,870 --> 00:14:51,650
+بيكون سبب .. هذا بيكون سبب اللي هو ليش ال alphatic
+
+167
+00:14:51,650 --> 00:14:54,850
+amines are more basic than aromatic amines because
+
+168
+00:14:54,850 --> 00:15:01,710
+of resonance تمام؟ الآن البعض منكم اتكلم كلمة جيدة
+
+169
+00:15:01,710 --> 00:15:08,080
+قال ال inductive effectممكن يكون في مكان تاني غير
+
+170
+00:15:08,080 --> 00:15:12,840
+هذا الان حتى نفهم ال inductive effect حتى نفهم ال
+
+171
+00:15:12,840 --> 00:15:18,200
+inductive effect جيدا انتوا بتكونوا تتخيلوا
+
+172
+00:15:18,200 --> 00:15:26,720
+نيتروجين و عليها زوج إلكترونات و تلت روابط تمام؟
+
+173
+00:15:26,720 --> 00:15:32,040
+إيش اللي ممكن يزيد القاعدية تبعتها و إيش اللي ممكن
+
+174
+00:15:32,040 --> 00:15:41,510
+ينجس؟أي مجموعة تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+175
+00:15:41,510 --> 00:15:48,750
+تقدر تقدر تقدر
+
+176
+00:15:48,750 --> 00:15:49,430
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+177
+00:15:49,430 --> 00:15:49,450
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+178
+00:15:49,450 --> 00:15:49,570
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+179
+00:15:49,570 --> 00:15:49,690
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+180
+00:15:49,690 --> 00:15:49,710
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+181
+00:15:49,710 --> 00:15:53,850
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+182
+00:15:53,850 --> 00:16:02,860
+تقدر تقدر تincreases basicity لأنه زدت كمية
+
+183
+00:16:02,860 --> 00:16:12,420
+الإلكترونات increases او increase basicity الان لو
+
+184
+00:16:12,420 --> 00:16:18,380
+كان عندى electron with drawing groups with drawing
+
+185
+00:16:18,380 --> 00:16:24,220
+مجموعات ساحبة للإلكترونات يعني إذا أنا عندى كمية
+
+186
+00:16:24,220 --> 00:16:28,740
+الإلكترونات إجت أشياء ساحبتهاإيش هيعمله في ال
+
+187
+00:16:28,740 --> 00:16:37,240
+basicity؟ decrease basicity واضحة الفكرة المجموعات
+
+188
+00:16:37,240 --> 00:16:41,300
+المعطية للإلكترونات بتزيد كمية الإلكترونات بتزيد
+
+189
+00:16:41,300 --> 00:16:46,080
+الإعقاء بتزيد القاعدية المجموعات الساحبة تقلل كمية
+
+190
+00:16:46,080 --> 00:16:50,640
+الإلكترونات تقلل ما يُعطى للخارج وبالتالي تقلل
+
+191
+00:16:50,640 --> 00:16:55,480
+إيش؟ القاعدية واضحة هذه الفكرة؟ واضحة؟
+
+192
+00:17:01,610 --> 00:17:06,190
+طبعا هتلاحظوا القمر هنا عكس ايش ال acidity للناس
+
+193
+00:17:06,190 --> 00:17:12,530
+اللي بدهم ينتبهوا ويعملوا مقارنة خلينا نعطي مثال
+
+194
+00:17:12,530 --> 00:17:21,590
+لو اجيت انا اعطيت هدولة المثالين F الأمين لاحظوا
+
+195
+00:17:21,590 --> 00:17:27,020
+هاي ال F الأمين وين زوج ال electronic اللي عليهعلى
+
+196
+00:17:27,020 --> 00:17:35,580
+الـ Nitrogen و أعطيت Chloroethelamine هاي
+
+197
+00:17:35,580 --> 00:17:41,040
+أنا فيه الاتنين Aliphatic واضح بطلت الفكرة
+
+198
+00:17:41,040 --> 00:17:44,800
+Aliphatic و Aromatic الاتنين إيش مالهم؟ Aliphatic
+
+199
+00:17:44,800 --> 00:17:50,160
+مين بدو يكون stronger base بالتجربة الـ Ethelamine
+
+200
+00:17:50,160 --> 00:17:57,430
+أقوى من الchloroethelamine الآن إيش السبب؟اه هنا
+
+201
+00:17:57,430 --> 00:18:03,010
+في عندى CL، إيش بتعمل ال CL في الإلكترونات؟ بتسحب
+
+202
+00:18:03,010 --> 00:18:06,810
+الإلكترونات، يعني لو افترضتوا كانت كمية
+
+203
+00:18:06,810 --> 00:18:10,870
+الإلكترونات كرقم عشوائي، هنا عشرة، ال CL سحبت إلى
+
+204
+00:18:10,870 --> 00:18:14,190
+منهم اتنين، صف يوجد إيش؟ تمانية، إذا وين
+
+205
+00:18:14,190 --> 00:18:20,630
+الإلكترونات أكثر؟أه بينما لاحظ لو إجيت أنا حطيت
+
+206
+00:18:20,630 --> 00:18:24,730
+مثل و مثل بيعطوا إلكترونات شو بده يصير لل BCCT؟
+
+207
+00:18:24,730 --> 00:18:31,290
+بده يزيد إذا المجموعات الساحبة تقلل القاعدية
+
+208
+00:18:31,290 --> 00:18:36,530
+والمجموعات المعطية تزيد القاعدية طبعا بشرط إنكوا
+
+209
+00:18:36,530 --> 00:18:40,550
+لما تعملوا المقارنات قارنوا أشياء متحدة من جوانب
+
+210
+00:18:40,550 --> 00:18:44,210
+أخرى يعني أنا لما عملت هذه المقارنة ساحب ومعطي
+
+211
+00:18:44,210 --> 00:18:49,850
+قارنت ألفتكممكن اكرر العملية اقارن aromatic مع
+
+212
+00:18:49,850 --> 00:18:56,350
+aromatic يعني لو اخدت الانيلين والنيتروانيلين
+
+213
+00:18:56,350 --> 00:19:02,830
+والميثلانيلين اللي هو البراتوليدين اسمه الآن هدول
+
+214
+00:19:02,830 --> 00:19:06,150
+التلاتة فيهم resonance إذا ال resonance مش هيكون
+
+215
+00:19:06,150 --> 00:19:10,030
+هو السبب وهدول التلاتة القاعدية تبعتهم من ناحية
+
+216
+00:19:10,030 --> 00:19:12,550
+المبدأ قليلة
+
+217
+00:19:13,930 --> 00:19:17,630
+ليش؟ لأنه فيهم resonance لكن في القاعدية القليلة
+
+218
+00:19:17,630 --> 00:19:20,850
+واحد منهم أقل من التاني أقل من التالت يعني التلاتة
+
+219
+00:19:20,850 --> 00:19:27,310
+ك basis إضعاف لكن في واحد أفضل من التاني أفضل من
+
+220
+00:19:27,310 --> 00:19:31,970
+التالت الآن خلّينا نيجي نتطلع المثل كمجموعة شو
+
+221
+00:19:31,970 --> 00:19:37,890
+بتعمل؟ بتعطي إلكترونات إذا معنا الإلكترونات بـ 0
+
+222
+00:19:37,890 --> 00:19:44,130
+الـ H نعتبرها متعادلة الـ Nitroبتسحب، إذا وين أعلى
+
+223
+00:19:44,130 --> 00:19:51,430
+الإلكترونات؟ في الميثلانيلين، بعده الانيلين، بعده
+
+224
+00:19:51,430 --> 00:19:57,870
+النيترو، فك basis الميثلانيلين أعلى من الانيلين،
+
+225
+00:19:57,870 --> 00:20:02,350
+أعلى من النيتروانيلين، الآن هنا لما ابدأ أقول شو
+
+226
+00:20:02,350 --> 00:20:10,330
+السبب؟ ال inductive effectطبعاً بشكل عام كلهم
+
+227
+00:20:10,330 --> 00:20:17,630
+يعتبروا ضعاف، ليش؟ لأن كلهم فيهم resonance، كلهم
+
+228
+00:20:17,630 --> 00:20:21,050
+يعتبروا ك basis ضعاف، لكن واحد أضعف من التاني أضعف
+
+229
+00:20:21,050 --> 00:20:26,610
+من التالت، الأن فرق الضعف اللي بين لضعاف أساساً
+
+230
+00:20:26,610 --> 00:20:31,670
+بسبب إيش؟ ال inductive effectلكن لو أنا باجي
+
+231
+00:20:31,670 --> 00:20:38,370
+بسألكم والله بشكل عام ال nitroaniline is a weak
+
+232
+00:20:38,370 --> 00:20:45,560
+base، ليش؟ هتقولولي ال resonance مصيبة؟و الحاجات
+
+233
+00:20:45,560 --> 00:20:50,980
+هم صيبة تانية ال nitro يعني صار سبب ضعفه شغل فيه
+
+234
+00:20:50,980 --> 00:20:55,280
+ال resonance و ال inductive effect لكن لو كنت بدأ
+
+235
+00:20:55,280 --> 00:20:58,500
+اقارنه مثلا مع ال methyl aniline لأ بقول ما هو ال
+
+236
+00:20:58,500 --> 00:21:01,720
+resonance و ال resonance هم عامل مشترك بطل هو اللي
+
+237
+00:21:01,720 --> 00:21:07,920
+مفرج صار إيش اللي مفرج؟ شكل أساسي ال inductive
+
+238
+00:21:07,920 --> 00:21:09,940
+effect واضحة الفكرة؟
+
+239
+00:21:17,860 --> 00:21:23,620
+أخر شغلة في هذا الفصل، لو قلنا تفاعلات الـ Amines،
+
+240
+00:21:23,620 --> 00:21:28,240
+تفاعلات الـ Amines مروا علينا بدل المر ألف طالما
+
+241
+00:21:28,240 --> 00:21:33,140
+في زوج إلكترونات، إذا الـ Amines بيعملوا as الـ
+
+242
+00:21:33,140 --> 00:21:39,880
+Eucleophiles، واضح؟إذا بدكم تحكوا عن الكليهيليتز،
+
+243
+00:21:39,880 --> 00:21:44,120
+بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن الديهيد
+
+244
+00:21:44,120 --> 00:21:48,260
+وكيتون، بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن
+
+245
+00:21:48,260 --> 00:21:52,660
+كاربوكسيليك أسيتس ومشتقاتها، بتفعلوا كنيكليوفييل،
+
+246
+00:21:52,660 --> 00:21:56,280
+وكل الأمثلة مرت علينا، الآن مع الالكليهيليتز
+
+247
+00:21:56,280 --> 00:22:00,700
+بيعملوا النيكليوفيليك سبستيوشن، مع الديهيدس وكيتون
+
+248
+00:22:01,680 --> 00:22:06,140
+بيعملوه الـ Eucleophilic addition مع الـ E stars
+
+249
+00:22:06,140 --> 00:22:10,340
+ومشتقاتها بيعملوه مرة تانية الـ Eucleophilic
+
+250
+00:22:10,340 --> 00:22:14,900
+substitution يعني هاي نشوف عدة أمثلة هاي هذا أمين
+
+251
+00:22:14,900 --> 00:22:20,260
+RNH2 مع أسد الكلورايد هاي الـ Eucleophile هاجم طرد
+
+252
+00:22:20,260 --> 00:22:24,360
+الـ Cl هذا عبارة عن إيش الـ Eucleophilic
+
+253
+00:22:24,360 --> 00:22:29,520
+substitution على أسد الكلورايد هذا primary أمين طب
+
+254
+00:22:29,520 --> 00:22:33,230
+لو secondary أمينبرضه الـ Eucleophilic
+
+255
+00:22:33,230 --> 00:22:38,230
+Substitution على أسد إكلورايد مافيش فيها إشي لو
+
+256
+00:22:38,230 --> 00:22:41,710
+شوفناه مُركّب تاني برضه هذا سكندريامين مع أسد
+
+257
+00:22:41,710 --> 00:22:46,590
+إكلورايد الـ Eucleophilic Substitution لو شوفنا
+
+258
+00:22:46,590 --> 00:22:51,150
+أنيلين مع أسد أنهيدرايد بده يهاجمها نطوط رد هادي
+
+259
+00:22:51,150 --> 00:22:55,850
+الـ Eucleophilic Substitution واضح؟ كل هذه
+
+260
+00:22:55,850 --> 00:22:59,250
+التفاعلات حقيقة سبع
+
+261
+00:23:00,470 --> 00:23:07,030
+ومرت علينا في أي منطقة لما اتكلمنا على الأحماط
+
+262
+00:23:07,030 --> 00:23:13,130
+ومشتقاتها ربما البعض يقول طيب ذكرنا بأمثلة على ال
+
+263
+00:23:13,130 --> 00:23:16,630
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+264
+00:23:16,630 --> 00:23:17,190
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+265
+00:23:17,190 --> 00:23:17,190
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+266
+00:23:17,190 --> 00:23:17,570
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+267
+00:23:17,570 --> 00:23:24,530
+ال ال ال ال ال
+
+268
+00:23:24,530 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+269
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+270
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+271
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+272
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+273
+00:23:29,470 --> 00:23:29,490
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+274
+00:23:31,660 --> 00:23:42,460
+CH3 CH2 NH2 هذا primary امين زائد هذا المركب و
+
+275
+00:23:42,460 --> 00:23:49,980
+حامل هنا ب R هذا يعتبر ايش الكلهيلايت هذا في
+
+276
+00:23:49,980 --> 00:23:53,520
+النهاية الكلهيلايت و لو حلقة خمسية كيف هتعملوا
+
+277
+00:23:56,960 --> 00:24:03,400
+واضح؟ وطالما الـ nucleophile neutral كمحص لإيش
+
+278
+00:24:03,400 --> 00:24:11,020
+هيكون؟ يفقد CH2 CH3 أكيد الـ H اللي فقدها مع ال PR
+
+279
+00:24:11,020 --> 00:24:17,940
+إيش هتعمل؟ HPR هذا من chapter 6 الـ nucleophilic
+
+280
+00:24:17,940 --> 00:24:22,820
+substitution ofAlkyl Halides الوثيقة الوثيقة
+
+281
+00:24:22,820 --> 00:24:27,820
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+282
+00:24:27,820 --> 00:24:30,180
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+283
+00:24:30,180 --> 00:24:31,120
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+284
+00:24:31,120 --> 00:24:31,460
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+285
+00:24:31,460 --> 00:24:36,880
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+286
+00:24:36,880 --> 00:24:41,160
+الوثيقة
+
+287
+00:24:41,160 --> 00:24:45,820
+الوثيقة
+
+288
+00:24:45,820 --> 00:24:47,480
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+289
+00:24:47,480 --> 00:24:49,140
+الوثيقة الوثيقة الوثيقة الوثيناخد كمان مرنو
+
+290
+00:24:49,140 --> 00:24:53,960
+سايكليك كيتون او الديهايد هى C double bond O C
+
+291
+00:24:53,960 --> 00:25:01,580
+double bond O زائد CH3 CH2
+
+292
+00:25:01,580 --> 00:25:08,720
+NH2 تخيلوا اجتكوا اكمل هذه المعادلة كيف هتكملوها؟
+
+293
+00:25:08,720 --> 00:25:12,260
+اه بدكم اتهاجموها على ال الديهايد او ال كيتون و
+
+294
+00:25:12,260 --> 00:25:16,540
+هذه تصير OH اذا للناتج اللى عندى
+
+295
+00:25:22,140 --> 00:25:30,100
+بدي يصير عندى OH OHANA NH
+
+296
+00:25:30,100 --> 00:25:39,120
+CH2 CH3 مش هذا اللي بدي يصير لكن الطالب الشاطر
+
+297
+00:25:39,120 --> 00:25:45,900
+اتعلمت كمان شغلة ان هذا هو تفاعل ل nucleophilic
+
+298
+00:25:45,900 --> 00:25:46,780
+addition
+
+299
+00:25:49,140 --> 00:25:54,660
+هذا هو تفاعل الـ Eucleophilic addition الآن مع ال
+
+300
+00:25:54,660 --> 00:25:58,600
+amines لما تكون ال H و ال OH جانب بعض، ايش
+
+301
+00:25:58,600 --> 00:26:05,460
+اتعلمنا؟ بيروح و بيفقد جزء ماء و بعمل double bond
+
+302
+00:26:08,450 --> 00:26:12,470
+قولنا احنا كل N H2 مع C double bond O ماصيرها
+
+303
+00:26:12,470 --> 00:26:17,130
+النهائي C double bond O الديهيد او كيتون تصير C
+
+304
+00:26:17,130 --> 00:26:23,790
+double bond N CH2 CH3 بصير ال shift basis وقولنا
+
+305
+00:26:23,790 --> 00:26:27,590
+ان التفاعل بهذه الحالة ايش بنقول عنه addition
+
+306
+00:26:27,590 --> 00:26:30,370
+elimination
+
+307
+00:26:31,670 --> 00:26:35,830
+نسيته تفاعل تكوين الأكزينز والهيدرازونز والسمي
+
+308
+00:26:35,830 --> 00:26:39,570
+كربازونز كل ال N-H2 مع ال C double bond O
+
+309
+00:26:39,570 --> 00:26:43,410
+الديهيدوكيتون كانت تعمل C double bond N على خطوتين
+
+310
+00:26:43,410 --> 00:26:51,100
+لكن في الأساس أن الأمين تفاعل كإيش؟كان uqlu5 وعمل
+
+311
+00:26:51,100 --> 00:26:54,760
+addition الان بعد هيك ان ال addition اتبع ال
+
+312
+00:26:54,760 --> 00:26:58,960
+elimination هذا امر ايش تاني هذا المحصلة النهائية
+
+313
+00:26:58,960 --> 00:27:03,480
+لكن ال addition ادشن و ال uqlu5 ال uqlu5 فال
+
+314
+00:27:03,480 --> 00:27:09,240
+amines تفاعلهم الأساسي بنقول هو ايش they react as
+
+315
+00:27:09,240 --> 00:27:14,480
+uqlu5 as uqlu5 واضح؟
+
+316
+00:27:16,420 --> 00:27:20,000
+لكن لو جينا سألناكم ال reaction of amines with
+
+317
+00:27:20,000 --> 00:27:25,120
+aldehydes and ketones is a nucleophilic addition
+
+318
+00:27:25,120 --> 00:27:30,600
+in a brain cell واضح؟ انه بعدك followed by
+
+319
+00:27:30,600 --> 00:27:34,700
+elimination على أنه الرأس مرة تبسيط واضح؟ with
+
+320
+00:27:34,700 --> 00:27:39,920
+acids and their derivatives a nucleophilic
+
+321
+00:27:39,920 --> 00:27:44,620
+substitution with alkyl halides برضه nucleophilic
+
+322
+00:27:44,620 --> 00:27:45,840
+substitution
+
+323
+00:27:56,390 --> 00:28:01,410
+بهيك بنكون خلصنا الفكرة أو الكلام المختصر اللى
+
+324
+00:28:01,410 --> 00:28:07,510
+بنشرحه عن ال amines و
+
+325
+00:28:07,510 --> 00:28:11,670
+بنلتقل مباشرة
+
+326
+00:28:11,670 --> 00:28:15,970
+لفصل
+
+327
+00:28:15,970 --> 00:28:22,850
+الخامس عشر اللى هو يعتبر بداية ال general
+
+328
+00:28:22,850 --> 00:28:28,890
+biochemistry اللى بنحكي عنهاlimits and detergents
+
+329
+00:28:28,890 --> 00:28:37,110
+limits and detergents الان ال limits معناها
+
+330
+00:28:37,110 --> 00:28:41,190
+بالعربي الدهون اش
+
+331
+00:28:41,190 --> 00:28:50,630
+اللي تلغيه ال libidab اسمها ال libidab دهون اه في
+
+332
+00:28:50,630 --> 00:28:55,570
+مشكلة عندكوا في الورق؟أنا عند ال slides خلص و أنت
+
+333
+00:28:55,570 --> 00:29:07,090
+عندك إشي؟ من وين صورته؟ أي شباته؟ مالغيين
+
+334
+00:29:07,090 --> 00:29:13,300
+هدولة، مشيولين عن .. مش موجودين في الزمالةلأ لأ
+
+335
+00:29:13,300 --> 00:29:18,440
+هدولة ال slides اللي معكم زيادة فيهم بس كلمة واحدة
+
+336
+00:29:18,440 --> 00:29:22,940
+احنا شرحناها كتابة how to prepare phenol هي اللي
+
+337
+00:29:22,940 --> 00:29:27,740
+كنا مهتمين فيها متذاكرين المرة الماضية قولنالكم
+
+338
+00:29:27,740 --> 00:29:32,240
+كيف تحضروا ال phenol فقط لحد هنا وبنخلص مافيش اندي
+
+339
+00:29:32,240 --> 00:29:37,420
+انا عن ال computer الان ننتقل للفصل الخامس عشر
+
+340
+00:29:37,420 --> 00:29:42,280
+limits and detergentsالـ Libids الدهون الـ
+
+341
+00:29:42,280 --> 00:29:48,420
+detergents المنظفات الصناعية المنظفات الصناعية
+
+342
+00:29:48,420 --> 00:29:51,400
+الصوابين و الأشياء اللي بتكون في الشنب و غيرها و
+
+343
+00:29:51,400 --> 00:29:57,520
+غيراتها و هتلاحظوا انه في علاقة بين الدهون و بينال
+
+344
+00:29:57,520 --> 00:30:03,160
+detergents و ربما كلكم اتذكرين اساسا ان الصابون
+
+345
+00:30:03,160 --> 00:30:08,220
+عادة من وين كانوا بيجيبوها؟ من زيت الزتون .. زيت
+
+346
+00:30:08,220 --> 00:30:14,650
+الزتون، دهون والصابونمنظف طبعا soap الآن صاروا
+
+347
+00:30:14,650 --> 00:30:19,070
+يعملوا أشياء صناعية بنسميها synthetic detergents
+
+348
+00:30:19,070 --> 00:30:23,590
+يعني منظفات صناعية كل هذا الكلام هيكون جزء من
+
+349
+00:30:23,590 --> 00:30:30,270
+الكلام اللي هنناقشه في هذا الشركة الآن لو إجينا و
+
+350
+00:30:30,270 --> 00:30:38,380
+قولنا إيش هم ال livids إيش هم الدهونلاحظوا أنه
+
+351
+00:30:38,380 --> 00:30:42,140
+الأن بنبدأ شوية نختلف عن ال organic chemistry يعني
+
+352
+00:30:42,140 --> 00:30:45,760
+في ال organic chemistry كل chapter لما كنا نجيب
+
+353
+00:30:45,760 --> 00:30:50,080
+عائلة كنا نميز العائلة بالمجموعة الوظيفية اللي
+
+354
+00:30:50,080 --> 00:30:54,780
+موجودة فيها يعني نقول ال alcohols OH ال aldehydes
+
+355
+00:30:54,780 --> 00:31:00,490
+يضا بالبنض OC double bond O of R of R الاسد C
+
+356
+00:31:00,490 --> 00:31:04,830
+double bond O O H هناك كان التصنيف اعتمادا على ايش
+
+357
+00:31:04,830 --> 00:31:11,010
+المجموعة الوظيفية الان لما باجي بقول ال libids هل
+
+358
+00:31:11,010 --> 00:31:16,790
+يا ترى ال libids كعائلة تحكمها مجموعة وظيفية واحدة
+
+359
+00:31:16,790 --> 00:31:19,870
+يعني في الآخر الواحدة تيجي تقولي C double bond
+
+360
+00:31:19,870 --> 00:31:26,780
+ONH4 C double bond OSHهل تصنيف ال limits منطلق من
+
+361
+00:31:26,780 --> 00:31:29,980
+ال functional groups من المجموعات الوظيفية
+
+362
+00:31:29,980 --> 00:31:35,710
+الجوانب؟الـ Libids هي عائلة من المنتجات الطبيعية
+
+363
+00:31:35,710 --> 00:31:41,070
+بشكل عام Natural Products عائلة كبيرة جدا و ينضوي
+
+364
+00:31:41,070 --> 00:31:47,030
+تحتها تفرعات كتيرة هدولة بيمتازوا بشكل عام ..
+
+365
+00:31:47,030 --> 00:31:51,490
+بيمتازوا بشكل عام المراكبات المنتجة طبيعيا انه
+
+366
+00:31:51,490 --> 00:31:56,230
+بتدوب في ال organic solvents زي ال ether,
+
+367
+00:31:56,450 --> 00:32:00,330
+chloroform, أسيتون, بنزين وبشكل عام بدوبوش في
+
+368
+00:32:00,330 --> 00:32:05,710
+الميهإذا هنا اللي ميزهم كعائلة إن هما منتجات
+
+369
+00:32:05,710 --> 00:32:12,190
+طبيعية وشغل تانية soluble in organic solvents يعني
+
+370
+00:32:12,190 --> 00:32:19,870
+أنا بدي إن they are natural و soluble in non-polar
+
+371
+00:32:19,870 --> 00:32:24,370
+organic solvents insoluble in water
+
+372
+00:32:27,950 --> 00:32:31,530
+اللي أنا بدياهم عن ال limits they are natural
+
+373
+00:32:31,530 --> 00:32:37,510
+compounds soluble in non-polar organic solvents
+
+374
+00:32:37,510 --> 00:32:43,050
+insoluble in water طبعا طالما كانوا soluble in non
+
+375
+00:32:43,050 --> 00:32:46,090
+-polar organic solvents إذا انتوا هتستنتجوا ان هم
+
+376
+00:32:46,090 --> 00:32:51,790
+non-polar ليش؟ لأنه likelike واضح إذا هما non
+
+377
+00:32:51,790 --> 00:32:55,910
+polar و بدوبوا فيه ال non polar solvents الانب
+
+378
+00:32:55,910 --> 00:33:00,370
+يندرج تحتهم الحقيقة مجموعة كبيرة من المراكبات منهم
+
+379
+00:33:00,370 --> 00:33:05,090
+اللي بنسميه ال fatty acids الأحماض الدهنية بنشوف
+
+380
+00:33:05,090 --> 00:33:08,510
+شو هي ال fatty acids منهم ال soaps and detergents
+
+381
+00:33:08,510 --> 00:33:13,370
+الصوابين و المنظفات منهم ال fats and oils الدهون و
+
+382
+00:33:13,370 --> 00:33:18,770
+الزيون منهم ال waxes الشموةمنهم الـ Phospholipids
+
+383
+00:33:18,770 --> 00:33:23,330
+بنسميها Phospholipids منهم الـ Icosanoids مركبات
+
+384
+00:33:23,330 --> 00:33:28,590
+انكونا من عشرين ذرة كربون منهم Terbenes مجموعة
+
+385
+00:33:28,590 --> 00:33:34,590
+مركبات بتحده بصفة معينة بنشوفها وجود isoprene unit
+
+386
+00:33:34,590 --> 00:33:40,400
+منهم الستيرويد مركبات ممتازة وجود أربع حلقاتمنهم
+
+387
+00:33:40,400 --> 00:33:45,620
+بعض ال vitamins أشياء منوعة مافيش خاسم مشترك بينها
+
+388
+00:33:45,620 --> 00:33:50,980
+كل هدولة من ناحية المبدأ natural productsSoluble
+
+389
+00:33:50,980 --> 00:33:54,940
+in organic solvents and soluble in water are
+
+390
+00:33:54,940 --> 00:33:57,580
+classified as lipids
+
+391
+00:34:20,310 --> 00:34:24,990
+يعني التلات أشياء بنفهموا مع بعض، واضح؟ يعني اللي
+
+392
+00:34:24,990 --> 00:34:28,150
+بده يفهم ال fatty acids، بده يفهم ال fats، اللي
+
+393
+00:34:28,150 --> 00:34:30,890
+بده يفهم ال fats، بده يفهم ال oils، اللي بده يفهم
+
+394
+00:34:30,890 --> 00:34:33,110
+ال fats و ال oils، بده يفهم ال soaps و ال
+
+395
+00:34:33,110 --> 00:34:38,310
+detergents، التلاتة هتلاحظوا أن فيهم إيش؟ قاسم
+
+396
+00:34:38,310 --> 00:34:45,240
+مشترك، التلاتة هتلاحظوا أن فيهم قاسم مشتركوعشان
+
+397
+00:34:45,240 --> 00:34:51,440
+هيك خلّينا نبدأ بال fats and oils الآن بشكل عام
+
+398
+00:34:51,440 --> 00:34:57,640
+الدهون والزيوت أشهر شيء موجودين فيه على شكل اللي
+
+399
+00:34:57,640 --> 00:35:04,700
+بنسميه triglycerides إيش هما ال triglycerides؟ ال
+
+400
+00:35:04,700 --> 00:35:13,120
+triglycerides ببساطة عبارة عن إيسترز ل .. ال ..
+
+401
+00:35:14,640 --> 00:35:20,620
+للجليسارين طبعا كلكم اتذكرين انه احنا ايش اخدنا
+
+402
+00:35:20,620 --> 00:35:27,380
+الجليسارين سابقا قلنا تلات ذرات كربون تلات ذرات
+
+403
+00:35:27,380 --> 00:35:34,660
+كربون فيهم OH OH OH عشانك الجليسارول one two three
+
+404
+00:35:34,660 --> 00:35:41,880
+بروبان الترايول مظبوط ولا لأ one two three بروبان
+
+405
+00:35:41,880 --> 00:35:48,090
+الترايولهذا ال glycerin في الأساس اتفاعل مع أشياء
+
+406
+00:35:48,090 --> 00:35:53,850
+بنسميها fatty acids هتيجي تقولون احنا اتعلمنا ال
+
+407
+00:35:53,850 --> 00:35:58,370
+carboxylic acids اللي صيغتهم العامة C double bond
+
+408
+00:35:58,370 --> 00:36:04,570
+O OH متصلين في R بنقول ال fatty acids هم نفسهم
+
+409
+00:36:04,570 --> 00:36:14,080
+ولكن ال R تبعتهم كبيرةيعني بتكون عشر كربونات،
+
+410
+00:36:14,080 --> 00:36:17,220
+اتنائش، اربعة عاشر، ستة عاشر، تمانة عاشر، اشرين
+
+411
+00:36:17,220 --> 00:36:22,780
+الآن كلكم اتذكرين انه في ال alcohol و في ال acids
+
+412
+00:36:22,780 --> 00:36:32,300
+قولنا هذه المركبات التمتاز ان فيها طرف polar و طرف
+
+413
+00:36:32,300 --> 00:36:39,800
+non polarالـ R في الـ fatty acids الـ non-polar
+
+414
+00:36:39,800 --> 00:36:46,180
+الكبير، خلّينا نقول من عشرة و فوقوبناء على ذلك
+
+415
+00:36:46,180 --> 00:36:52,280
+الجزيء بمجمله يغلب عليه الـ non-polar part فبصير
+
+416
+00:36:52,280 --> 00:36:56,480
+water soluble ولا insoluble؟ بصير non-polar طالما
+
+417
+00:36:56,480 --> 00:37:01,680
+صار non-polar صار water insoluble بصير دوب في ال
+
+418
+00:37:01,680 --> 00:37:06,640
+organic solvent إذا هذه الجزيئات اللي فيها القاري
+
+419
+00:37:06,640 --> 00:37:10,190
+الكبيرة هي اللي بنسميها الـ fatty acidsفال fatty
+
+420
+00:37:10,190 --> 00:37:17,150
+acids ببساطة هي أحماض كربوكسيلية بسلسلة طويلة
+
+421
+00:37:17,150 --> 00:37:24,080
+وبناء على ذلك أصبحت هذه الأحماض non polarما بتدوبش
+
+422
+00:37:24,080 --> 00:37:27,220
+في الميه وعشان هيك بتدوبش في الميه بتدوب في
+
+423
+00:37:27,220 --> 00:37:33,500
+المراكبات العضوية عشان هيك سمنها مواد ايش؟ دهنية
+
+424
+00:37:33,500 --> 00:37:38,620
+او احماض دهنية فهما الأحماض الدهنية مجموعتهم
+
+425
+00:37:38,620 --> 00:37:42,600
+الأساسية زي ال carboxylic acids COOH هما
+
+426
+00:37:42,600 --> 00:37:49,330
+carboxylic acids اكبرواضح؟ هم ببساطة كربوكسيلك
+
+427
+00:37:49,330 --> 00:37:55,190
+أسنس كبار، الآن لو أجينا و قولنا كحول زائد حمض، شو
+
+428
+00:37:55,190 --> 00:38:04,910
+بيعطيني؟ إيستر، لو أخدنا أي كحول زائد حمض، إيستر،
+
+429
+00:38:04,910 --> 00:38:08,410
+هذا أخدنا التفاعل، الآن هاي كحول في الجليسرين و
+
+430
+00:38:08,410 --> 00:38:13,690
+هاي حمض، خليهم يتفاعلواهذه الكحولة اتفاعل، ماذا
+
+431
+00:38:13,690 --> 00:38:21,550
+سيعطينا؟ CH2O C double bond OR هذا Easter ولا لا؟
+
+432
+00:38:21,550 --> 00:38:28,430
+و هذا؟ Easter تاني على الكحولة و هذا؟يستار تالت،
+
+433
+00:38:28,430 --> 00:38:33,570
+إذا كم إيستار عمل لجليسارين؟ لأنه فيه تلاتة أواتشز
+
+434
+00:38:33,570 --> 00:38:40,410
+عمل تلاتة إيستار الآن هذه المركبات بنسميها احنا
+
+435
+00:38:40,410 --> 00:38:46,410
+الـ triglycerides الـ tri لأنهم تلاتة، الجليساريدز
+
+436
+00:38:46,410 --> 00:38:49,150
+لأنهم إيستارز of جليسارين
+
+437
+00:38:51,280 --> 00:38:55,480
+اعرفنا إذا ليش الـ triglycerides؟ لأنه there are E
+
+438
+00:38:55,480 --> 00:39:02,700
+stars of glycerin وكم E star؟ هان و هان و هان، إذا
+
+439
+00:39:02,700 --> 00:39:08,690
+هذه الـ triglycerides هي عبارة عن الفات والـ oilهي
+
+440
+00:39:08,690 --> 00:39:12,230
+عبارة عن الزيت و الذهن و الزبدة و السمنة و زيت
+
+441
+00:39:12,230 --> 00:39:16,270
+الزتون و زيت عباد الشمس هو عبارة عن الـ
+
+442
+00:39:16,270 --> 00:39:19,310
+Triglycerides الميزة الأساسية اللي بتبقى بالكم
+
+443
+00:39:19,310 --> 00:39:26,230
+متذاكرينها فيه ان القعر هذه طويلة لأن القعر طويلة
+
+444
+00:39:26,230 --> 00:39:31,030
+كله water soluble ولا insoluble عشان هيك الزيت
+
+445
+00:39:31,030 --> 00:39:39,160
+الزيرج زيت الزتون بخلط مع الميه لأ واضح ف ..لاحظوا
+
+446
+00:39:39,160 --> 00:39:43,600
+اللي فهم هذا الكلام، بلاحظ العلاقة ما بين الـ
+
+447
+00:39:43,600 --> 00:39:46,800
+triglycerides و الـ fatty acids، انه انا لو عملت
+
+448
+00:39:46,800 --> 00:39:51,200
+هيدروليسيز، لو كسرت الـ triglycerides، سخنتهم
+
+449
+00:39:51,200 --> 00:39:55,280
+بالسوديوم هيدروكسيد و ضفت عليهم بعدين حامض، عاش
+
+450
+00:39:55,280 --> 00:40:02,420
+بحصل؟ بحصل على ال glycerin أو ال glycerol و ال
+
+451
+00:40:02,420 --> 00:40:10,380
+fatty acidsبحصل على ال glycerol و ال fatty acids
+
+452
+00:40:10,380 --> 00:40:17,060
+واضح الفكرة؟ اذا ال fatty acids هما في الأساس جزء
+
+453
+00:40:17,060 --> 00:40:22,280
+من ال tri glycerides بالتكسير بحصل على glycerin و
+
+454
+00:40:22,280 --> 00:40:27,600
+بحصل على fatty acid واضح الفكرة؟
+
+455
+00:40:29,710 --> 00:40:34,910
+خلّينا شوية صغيرة نخرج عن السياق خلّينا شوية صغيرة
+
+456
+00:40:34,910 --> 00:40:41,870
+نخرج عن السياق الان جزء ال الكانز نرجع لل الكانز
+
+457
+00:40:41,870 --> 00:40:48,790
+مش هذا الجزء الأحمر هو عبارة عن الكانز طيب أول
+
+458
+00:40:48,790 --> 00:40:54,150
+chapter أخدناه في الكيميا العضوية شو كان؟الكينز،
+
+459
+00:40:54,150 --> 00:41:02,530
+وإيش أهم تفاعلات ال الكينز اللي احنا أخدناها؟ ان
+
+460
+00:41:02,530 --> 00:41:08,710
+ال الكينز بنحرقهم في وجود ال oxygen، بيعطونا ثاني
+
+461
+00:41:08,710 --> 00:41:15,970
+أكسيد الكربون وماء وحرارةطيب هذه المراكبات اللي
+
+462
+00:41:15,970 --> 00:41:20,090
+قال فيها Alkanes واحدة مين كنتيش تتخيل القاتل انه
+
+463
+00:41:20,090 --> 00:41:25,970
+حطينا السيرج على النار بدنا نولع السيرج حد بيمنعنا
+
+464
+00:41:25,970 --> 00:41:36,930
+يعني سيرج زائد Oxygen شو هيعطيني CO2 زائد H2O زائد
+
+465
+00:41:36,930 --> 00:41:43,730
+Heatمش هذه الـ aliphatic compounds الحمرة بتنحرج
+
+466
+00:41:43,730 --> 00:41:48,730
+وبتعطيني ثانو أكسيد كربون وميه وحرارة؟ إذا الـ
+
+467
+00:41:48,730 --> 00:41:53,790
+seerage ممكن ينحرج ويعطيني ثانو أكسيد كربون وميه
+
+468
+00:41:53,790 --> 00:41:59,530
+وحرارة؟ ولا مش ممكن؟ بتشوفوه بنحرج في الدار و
+
+469
+00:41:59,530 --> 00:42:04,530
+بتكونوا تنتبهوا لما بتشتغلوا؟ طب كويس الآن لو واحد
+
+470
+00:42:04,530 --> 00:42:11,060
+مخه مش مريحه أو الحصار مش مريحهوجطعوا البنزين ..
+
+471
+00:42:11,060 --> 00:42:15,720
+جطعوا السولار عن البلد وإيجى حط في سيارة ال مرسيدس
+
+472
+00:42:15,720 --> 00:42:18,920
+تبعته اللي بتمشي على السولار ولا في ال bus؟ سيرج
+
+473
+00:42:18,920 --> 00:42:25,740
+.. سيرج ومشى .. بيمشي ولا لأ؟ بيمشي .. بيمشي ..
+
+474
+00:42:25,740 --> 00:42:32,920
+بيمشي وعشان هيك في غزة في ظروف الحصار لما عدم
+
+475
+00:42:32,920 --> 00:42:38,270
+الوقودوكانوا بعض الباصات والسيارات المرسيدس مضطرة
+
+476
+00:42:38,270 --> 00:42:45,030
+تمشي حطوا searage في السيارة واشتغلت ومشيت صح لكن
+
+477
+00:42:45,030 --> 00:42:54,350
+كان عندكم مشكلة الشيء انه طلعت رائحة فظيعة جدا و
+
+478
+00:42:54,350 --> 00:42:58,850
+الناس كانت بتنخنيهمظبوط ولا لأ؟ طب هم الناس
+
+479
+00:42:58,850 --> 00:43:02,030
+مانخنجوش من ال solar العادى و من البنزين يعنى،
+
+480
+00:43:02,030 --> 00:43:05,990
+يقولوا تأثيرات سلبية، لكن مابتصلش لإنه الناس
+
+481
+00:43:05,990 --> 00:43:11,650
+ينخنجوا، إيش اللي صار إذا لما احنا ولّعنا السيرج؟
+
+482
+00:43:11,650 --> 00:43:16,210
+اه، اللي صار لما ولّعنا السيرج، إنه السيرج جزءين،
+
+483
+00:43:16,210 --> 00:43:22,310
+هذا الجزء هو اللي عمل كوقودهذا الجزء التابع لـ
+
+484
+00:43:22,310 --> 00:43:28,990
+Glycerin راح يعمل مصيبة هذا بالحرق بيعطي مركب تاني
+
+485
+00:43:28,990 --> 00:43:36,990
+CH ضب البند OH CH ضب البند CH2 بنسميه أكرولين و لا
+
+486
+00:43:36,990 --> 00:43:42,450
+أكرالدهايد هذا المركب هو اللي ريحته كانت سيئة و
+
+487
+00:43:42,450 --> 00:43:49,350
+يطلع على الشوارع و غيره و غيراته و خنج الناسواضحة
+
+488
+00:43:49,350 --> 00:43:55,130
+الفكرة؟ فالغلطة اللى كانت ان الناس لما اجوا يحرقوا
+
+489
+00:43:55,130 --> 00:44:01,330
+ال series في متورات السيارات حرقوا ايش؟ الجزء اللى
+
+490
+00:44:01,330 --> 00:44:06,110
+عادة بيعطيه الطاقة والجزء الجيد زائد الجزء ايش؟
+
+491
+00:44:06,110 --> 00:44:12,470
+السام والدار فطلعت عندهم حرارة ومشيت السيارة وكل
+
+492
+00:44:12,470 --> 00:44:16,810
+اشي لكن طلع عندهم كمان هذا المركب انتشر في الجو
+
+493
+00:44:16,810 --> 00:44:24,620
+خلق الناسواضحة الفكرة؟ طيب الآن لو في ناس بيفكروا
+
+494
+00:44:24,620 --> 00:44:31,940
+جيدا وقالوا يا تورا بدنا نحل المشكلة نطلع وقود من
+
+495
+00:44:31,940 --> 00:44:40,080
+الزيت ومن السيرج بيقدروا يعمله؟ لو إنهم في الأول
+
+496
+00:44:40,850 --> 00:44:46,750
+عملوا القاتل فصلوا هدول المركبين عن بعض يعني جابوا
+
+497
+00:44:46,750 --> 00:44:51,630
+ال searage قبل ما يحطوا كله في ماتور السيارة قبل
+
+498
+00:44:51,630 --> 00:44:57,410
+ما يحطوا كله في ماتور السيارة كسروا نصين الأن هذا
+
+499
+00:44:57,410 --> 00:45:04,480
+النصالمفيد هذا ال fuel هذا الوقود وهذا إيش؟
+
+500
+00:45:04,480 --> 00:45:08,860
+الجليسيرين الآن أنا لما أكسره بداية قبل ما أحطه في
+
+501
+00:45:08,860 --> 00:45:13,340
+موتور السيارة الجليسيرين صار على جانب بفصله ولا
+
+502
+00:45:13,340 --> 00:45:17,600
+مابفصلوش بفصله باخده و باستفيد منه كمان بعمل منه
+
+503
+00:45:17,600 --> 00:45:21,220
+كريمات مش كل كريمات و شامبوات فيها جليسيرين عشان
+
+504
+00:45:21,220 --> 00:45:27,850
+نعمة الإيدين يعني أنا مش بس اتخلصت من ضرر حرقهأنا
+
+505
+00:45:27,850 --> 00:45:32,470
+أخدته واستفادت منه وهذا الجزء عادة بيفصله على شكل
+
+506
+00:45:32,470 --> 00:45:39,650
+E star أو إثل أو إثل أو إثل واضح؟
+
+507
+00:45:39,650 --> 00:45:43,250
+يعني لما يعملوا التكسير بيفصلوا على شكل E star هذا
+
+508
+00:45:43,250 --> 00:45:50,610
+بناخده كوقود اليوم هذا الوقود اللي أخدنا إيش
+
+509
+00:45:50,610 --> 00:45:57,770
+بيسموه؟بيو ديزل بيو ديزل إيش يعني بيو ديزل يعني
+
+510
+00:45:57,770 --> 00:46:03,910
+الديزل الحيو اللي جاي من الزيوت هتقولولي في ديزل
+
+511
+00:46:03,910 --> 00:46:11,610
+بالطول من الزيت الجواب آه اليوم طائرات وسيارات
+
+512
+00:46:11,610 --> 00:46:17,370
+طائرات كاملة بتمشي على بيو ديزل بطوله من الزيوت
+
+513
+00:46:17,960 --> 00:46:23,540
+طبعا هالياطورة احنا ملاقين زيت ناكله سيرج و زيت
+
+514
+00:46:23,540 --> 00:46:29,620
+ناكله لما نحوله لوخود؟ الجواب اه كيف؟ الزيوت مش بس
+
+515
+00:46:29,620 --> 00:46:34,760
+كله مأكولة edible مأكول في زيوت inedibleزيوت لا
+
+516
+00:46:34,760 --> 00:46:40,480
+تؤكل تمام؟ بيزرعوها في أماكن كبيرة في الهند و في
+
+517
+00:46:40,480 --> 00:46:44,580
+غيرها و في غيراتها مثل مثلا زيت الجاتروفة و زيت
+
+518
+00:46:44,580 --> 00:46:49,520
+الكامليانة و زيت كذا في زيوت تؤكل و زيوت لا تؤكل
+
+519
+00:46:49,520 --> 00:46:54,800
+الزيوت اللتي لا تؤكل هي اللي بيحضروا منها المنظفات
+
+520
+00:46:54,800 --> 00:47:00,740
+و هي اللي بيحولوها لإيش؟ ل bio diesel و أشهرها زيت
+
+521
+00:47:00,740 --> 00:47:08,350
+اسمه الجاتروفةGatrofa Oil أشرب هذه الزيوت .. زيت
+
+522
+00:47:08,350 --> 00:47:13,010
+بنسميه إيش؟ زيت الجاتروفا فلاحظوا أنتوا كيف منطق
+
+523
+00:47:13,010 --> 00:47:17,350
+التفكير و منطق حل المشكلة في العلم أنه أنا فهمت
+
+524
+00:47:17,350 --> 00:47:22,450
+بداية .. أنه أنا فهمت بداية أن الحرارة بتجيني من
+
+525
+00:47:22,450 --> 00:47:29,170
+حرق هذا واضح؟الحرارة بتجيني من حرق هذا لكن هذا
+
+526
+00:47:29,170 --> 00:47:34,090
+موجود مع مركب تاني سام لما فصلته من الصين صار
+
+527
+00:47:34,090 --> 00:47:37,370
+بإمكاني أخد هذا و أسميه biodiesel و أحرب ولا لأ
+
+528
+00:47:37,370 --> 00:47:44,590
+الآن ضايقلي عشرين ثانية أحكيهم عارفين شو هم؟
+
+529
+00:47:44,590 --> 00:47:52,180
+العشرين ثانية اللي بدنا نحكيهم و نخلصالعشرين ثانية
+
+530
+00:47:52,180 --> 00:47:56,160
+اللي بنحكيهم و بنخلص القاتل اتخيلوا لو أخدتوا هذا
+
+531
+00:47:56,160 --> 00:48:03,780
+ال Easter و حطيتوا هنا سلسلة طويلة و حطيتوا هنا
+
+532
+00:48:03,780 --> 00:48:11,850
+كمان سلسلة طويلة هذه السلاسل ايش بتعمل؟بتولع مع ال
+
+533
+00:48:11,850 --> 00:48:17,110
+Oxygen و بتعطي حرارة و إضاءة و إشي هذه المركبات ال
+
+534
+00:48:17,110 --> 00:48:22,090
+E Stars اللي فيها سلسلة طويلة يمين و سلسلة طويلة
+
+535
+00:48:22,090 --> 00:48:30,910
+الشمال عارفين هي إيش؟ هي الشمع ال wax الآن أنا لما
+
+536
+00:48:30,910 --> 00:48:37,390
+بولع الشمع حقيقة إيش بولع؟ السلاسل الألفاتية
+
+537
+00:48:40,000 --> 00:48:45,380
+وبهك بيكون يعرفنا إيش هو الشمع الشمع هو Easter لكن
+
+538
+00:48:45,380 --> 00:48:50,160
+هذا ال Easter بسلسلتين كبار هانا وإحنا عرفنا إنه
+
+539
+00:48:50,160 --> 00:48:55,180
+هذه السلاسل لما بتولع هي اللي بتعطينا شوية الحرارة
+
+540
+00:48:55,180 --> 00:48:57,880
+و ثاني أكسيد الكربون و الميه مش مهمين أهم شيء
+
+541
+00:48:57,880 --> 00:49:02,720
+الحرارة و الإضاءة واضح؟ فلو قلنا لكم إيش ال wax
+
+542
+00:49:02,720 --> 00:49:12,010
+بالظبط ال wax areأو الواكس هم أسطارين مع شبكات
+
+543
+00:49:12,010 --> 00:49:16,370
+طويلة أو شبكات ألفاتية طويلة يعني اللي بيميزهم
+
+544
+00:49:16,370 --> 00:49:21,530
+الشبكات الطويلة الشبكات الألفاتية وكلنا عارفين
+
+545
+00:49:21,530 --> 00:49:25,810
+الأن الشبكات الألفاتية إيش بنعمل فيها هي اللي
+
+546
+00:49:25,810 --> 00:49:30,250
+بنولعها و بتعطينا الطاقة هي اللي بنولعها و بتعطينا
+
+547
+00:49:30,250 --> 00:49:34,850
+الطاقةفبكون هذا هو إيش الشمال فلاحظوا كيف أنا
+
+548
+00:49:34,850 --> 00:49:41,570
+استفدت من ال sealage كوقود كيف أنا استفدت كمان من
+
+549
+00:49:41,570 --> 00:49:46,710
+ال wax أنه أولعه و يطلعلي حرارة من خلال أنه أنا
+
+550
+00:49:46,710 --> 00:49:50,110
+بستفيد من التفاعل الأصلي اللي أخدته في شبتر واحد
+
+551
+00:49:50,110 --> 00:49:55,350
+أنه الألكيز بتحض مع ال oxygen و ال combustion
+
+552
+00:49:55,350 --> 00:49:58,630
+طلعوا ثانو أكسيد كربون و ميه و حرارة
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..daad7ff8cbc5da3d47e2e9ddb2670ea5b55c11f3
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3413, "start": 19.47, "end": 34.13, "text": "بسم الله الرحمن الرحيم بنكمل اليوم في موضوع ال aldehydes و ال ketones و ربما كلكم الذاكرين أنه التفاعل الأساسي لل aldehydes و ال ketones كان", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 4724, 1863, 24793, 1211, 45595, 20498, 8978, 3714, 2407, 11242, 45367, 2423, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 4032, 12602, 3555, 15042, 28242, 24793, 32545, 995, 37983, 9957, 14739, 3224, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 24976, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 25961], "avg_logprob": -0.1489583266278108, "compression_ratio": 1.60431654676259, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 19.47, "end": 19.71, "word": "بسم", "probability": 0.919677734375}, {"start": 19.71, "end": 19.89, "word": " الله", "probability": 0.95703125}, {"start": 19.89, "end": 20.25, "word": " الرحمن", "probability": 0.9500325520833334}, {"start": 20.25, "end": 20.73, "word": " الرحيم", "probability": 0.9928385416666666}, {"start": 20.73, "end": 23.31, "word": " بنكمل", "probability": 0.74444580078125}, {"start": 23.31, "end": 23.73, "word": " اليوم", "probability": 0.948974609375}, {"start": 23.73, "end": 24.09, "word": " في", "probability": 0.841796875}, {"start": 24.09, "end": 24.57, "word": " موضوع", "probability": 0.991455078125}, {"start": 24.57, "end": 24.71, "word": " ال", "probability": 0.90673828125}, {"start": 24.71, "end": 25.51, "word": " aldehydes", "probability": 0.72210693359375}, {"start": 25.51, "end": 26.03, "word": " و", "probability": 0.63427734375}, {"start": 26.03, "end": 26.17, "word": " ال", "probability": 0.8623046875}, {"start": 26.17, "end": 26.77, "word": " ketones", "probability": 0.852783203125}, {"start": 26.77, "end": 27.85, "word": " و", "probability": 0.8935546875}, {"start": 27.85, "end": 28.25, "word": " ربما", "probability": 0.9396158854166666}, {"start": 28.25, "end": 28.67, "word": " كلكم", 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cyanide مثلا ال H- لعملية ال reduction", "tokens": [39, 268, 1004, 2160, 5317, 388, 299, 5349, 849, 5551, 9778, 3215, 8315, 6225, 41891, 5551, 2304, 12984, 37977, 6225, 9673, 2407, 11242, 45367, 11933, 11242, 31845, 3660, 9673, 16606, 33251, 5016, 12610, 2423, 47463, 482, 50113, 15040, 2423, 389, 12, 5296, 25957, 1211, 10632, 2423, 11004], "avg_logprob": -0.3164062487582366, "compression_ratio": 1.2058823529411764, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 34.91, "end": 36.15, "word": "Heniocleophilic", "probability": 0.6049630301339286}, {"start": 36.15, "end": 36.69, "word": " Addition", "probability": 0.6605224609375}, {"start": 36.69, "end": 40.89, "word": " أخدنا", "probability": 0.702850341796875}, {"start": 40.89, "end": 41.21, "word": " عدة", "probability": 0.91259765625}, {"start": 41.21, "end": 42.01, "word": " أمثلة", "probability": 0.9473876953125}, {"start": 42.01, "end": 42.75, "word": " ع", "probability": 0.1900634765625}, {"start": 42.75, "end": 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74.13, "end": 84.99, "text": "بحط OH كحول بحط Oethyl أو OR in general فعلا ال cyanide بحط CN minus ال hydride بحط", "tokens": [3555, 5016, 9566, 13931, 9122, 5016, 12610, 4724, 5016, 9566, 422, 3293, 5088, 34051, 19654, 294, 2674, 6156, 3615, 15040, 2423, 47463, 482, 4724, 5016, 9566, 14589, 3175, 2423, 5796, 25502, 4724, 5016, 9566], "avg_logprob": -0.3477678486279079, "compression_ratio": 1.1473684210526316, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 74.13, "end": 74.63, "word": "بحط", "probability": 0.5685628255208334}, {"start": 74.63, "end": 75.25, "word": " OH", "probability": 0.8662109375}, {"start": 75.25, "end": 76.51, "word": " كحول", "probability": 0.8702799479166666}, {"start": 76.51, "end": 77.45, "word": " بحط", "probability": 0.9583333333333334}, {"start": 77.45, "end": 78.93, "word": " Oethyl", "probability": 0.4264933268229167}, {"start": 78.93, "end": 79.19, "word": " أو", "probability": 0.78076171875}, {"start": 79.19, "end": 79.81, "word": " OR", 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"text": "أتش ماينوس الان في عندنا اضافتين واحدة من هذول الاضافتين التفاعل مع green yard reagent واضح عادة هذا المتفاعل يمكن ماعندكم مش خبرة عنه بنتعرف عليه شو هو green yard reagent", "tokens": [10721, 2655, 8592, 19446, 9957, 41779, 2423, 7649, 8978, 43242, 8315, 1975, 11242, 31845, 2655, 9957, 36764, 24401, 3660, 9154, 8032, 8848, 12610, 2423, 46958, 31845, 2655, 9957, 16712, 5172, 995, 30241, 20449, 3092, 11682, 26949, 317, 4032, 46958, 5016, 6225, 18513, 3660, 23758, 9673, 2655, 5172, 995, 30241, 7251, 43020, 19446, 3615, 41260, 24793, 37893, 16490, 3555, 25720, 18871, 3224, 44945, 2655, 3615, 28480, 47356, 13412, 2407, 31439, 3092, 11682, 26949, 317], "avg_logprob": -0.33086993444610285, "compression_ratio": 1.6184971098265897, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 85.91, "end": 86.43, "word": "أتش", "probability": 0.5946451822916666}, {"start": 86.43, "end": 87.01, "word": " ماينوس", "probability": 0.7781575520833334}, {"start": 87.01, "end": 87.87, "word": 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540.62, "end": 541.32, "word": " dehyde", "probability": 0.6951497395833334}, {"start": 541.32, "end": 541.84, "word": " هذه", "probability": 0.62939453125}, {"start": 541.84, "end": 542.1, "word": " بدها", "probability": 0.6405029296875}, {"start": 542.1, "end": 542.62, "word": " تصير", "probability": 0.9811197916666666}, {"start": 542.62, "end": 543.94, "word": " OH", "probability": 0.83447265625}, {"start": 543.94, "end": 544.38, "word": " و", "probability": 0.86474609375}, {"start": 544.38, "end": 544.6, "word": " بده", "probability": 0.638916015625}, {"start": 544.6, "end": 544.86, "word": " يحط", "probability": 0.9796549479166666}, {"start": 544.86, "end": 545.58, "word": " عندها", "probability": 0.990966796875}, {"start": 545.58, "end": 547.0, "word": " مجموعة", "probability": 0.96240234375}, {"start": 547.0, "end": 547.2, "word": " ال", "probability": 0.9677734375}, {"start": 547.2, "end": 547.58, "word": " aethyl", "probability": 0.92333984375}, {"start": 547.58, "end": 547.98, "word": " هاي", "probability": 0.561279296875}, {"start": 547.98, "end": 548.5, "word": " مجموعة", "probability": 0.9611328125}, {"start": 548.5, "end": 548.68, "word": " ال", "probability": 0.9931640625}, {"start": 548.68, "end": 549.2, "word": " aethyl", "probability": 0.9588216145833334}, {"start": 549.2, "end": 551.82, "word": " شايفينها", "probability": 0.97421875}, {"start": 551.82, "end": 553.06, "word": " و", "probability": 0.38427734375}, {"start": 553.06, "end": 553.36, "word": " هنا", "probability": 0.81884765625}, {"start": 553.36, "end": 554.64, "word": " CH2", "probability": 0.954833984375}, {"start": 554.64, "end": 555.5, "word": " OH", "probability": 0.55908203125}, {"start": 555.5, "end": 556.24, "word": " هذه", "probability": 0.43994140625}, {"start": 556.24, "end": 556.96, "word": " ثابتة", "probability": 0.970703125}], "temperature": 1.0}, {"id": 25, "seek": 58666, "start": 557.84, "end": 586.66, "text": "واضح؟ إذا هو حط مجموعة الـ ethylene لاحظوا الآن ال green yard مع ال formaldehyde كوالي كحول إيش نوع هذا الكحول؟ primary alcohol طيب خليني أفعل ال green yard مع أي aldehyde تاني غير ال formaldehyde يعني acetaldehyde هذا, ibropenaldehyde, benzaldehyde طبعا هيحط برضه مجموعة", "tokens": [2407, 46958, 5016, 22807, 11933, 15730, 31439, 11331, 9566, 3714, 7435, 2304, 2407, 27884, 2423, 39184, 1030, 3495, 21323, 5296, 39319, 19913, 14407, 6024, 48506, 2423, 3092, 11682, 20449, 2423, 9860, 1479, 3495, 1479, 9122, 2407, 6027, 1829, 9122, 5016, 12610, 11933, 1829, 8592, 8717, 45367, 23758, 33251, 5016, 12610, 22807, 6194, 7658, 23032, 1829, 3555, 16490, 1211, 9957, 1829, 5551, 5172, 30241, 2423, 3092, 11682, 20449, 36632, 16798, 68, 3495, 1479, 6055, 7649, 1829, 32771, 13546, 2423, 9860, 1479, 3495, 1479, 37495, 22653, 37848, 304, 1479, 3495, 1479, 23758, 11, 39073, 1513, 268, 304, 1479, 3495, 1479, 11, 44335, 304, 1479, 3495, 1479, 23032, 3555, 3615, 995, 39896, 5016, 9566, 4724, 43042, 3224, 3714, 7435, 2304, 2407, 27884], "avg_logprob": 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{"start": 569.32, "end": 570.16, "word": " طيب", "probability": 0.8743489583333334}, {"start": 570.16, "end": 570.78, "word": " خليني", "probability": 0.82421875}, {"start": 570.78, "end": 571.28, "word": " أفعل", "probability": 0.923828125}, {"start": 571.28, "end": 571.5, "word": " ال", "probability": 0.8916015625}, {"start": 571.5, "end": 571.78, "word": " green", "probability": 0.9072265625}, {"start": 571.78, "end": 572.2, "word": " yard", "probability": 0.8857421875}, {"start": 572.2, "end": 572.66, "word": " مع", "probability": 0.978515625}, {"start": 572.66, "end": 572.88, "word": " أي", "probability": 0.9716796875}, {"start": 572.88, "end": 573.96, "word": " aldehyde", "probability": 0.754791259765625}, {"start": 573.96, "end": 574.82, "word": " تاني", "probability": 0.9798177083333334}, {"start": 574.82, "end": 576.32, "word": " غير", "probability": 0.83203125}, {"start": 576.32, "end": 576.74, "word": " ال", "probability": 0.90625}, {"start": 576.74, "end": 578.0, "word": " 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خلّيه يتفاعل مع ال كيتون مع هذا الاسيتون شو هيحط مجموعة ال إثل تيرتشاري الكحول واضح؟", "tokens": [6027, 28814, 12984, 1211, 37037, 1829, 10874, 11622, 38207, 2423, 2423, 16254, 11296, 25708, 25961, 2655, 9122, 9640, 3555, 11536, 44650, 36520, 8978, 11296, 389, 4032, 5462, 18, 4032, 9381, 9640, 2655, 13931, 6024, 48506, 11933, 1829, 8592, 9122, 2407, 11703, 1211, 5296, 11296, 8608, 19452, 3215, 2288, 1829, 33251, 5016, 12610, 23032, 3555, 16490, 1211, 11703, 1829, 3224, 7251, 2655, 5172, 995, 30241, 20449, 2423, 9122, 36081, 11536, 20449, 23758, 2423, 32277, 36081, 11536, 13412, 2407, 39896, 5016, 9566, 3714, 7435, 2304, 2407, 27884, 2423, 11933, 12984, 1211, 6055, 13546, 2655, 8592, 9640, 1829, 33251, 5016, 12610, 4032, 46958, 5016, 22807], "avg_logprob": -0.34071601478798874, "compression_ratio": 1.649746192893401, "no_speech_prob": 0.0, "words": [{"start": 588.8799999999999, "end": 589.8199999999999, "word": "الإثل", "probability": 0.630218505859375}, {"start": 589.8199999999999, 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MgBr MgBr و هذه إيش ناقصها هاخد CH3 MgBr", "tokens": [10721, 3555, 46309, 4724, 9566, 12610, 7578, 8608, 37440, 3660, 45595, 20498, 34892, 16758, 3615, 3224, 5551, 3794, 36081, 38688, 9957, 11536, 11933, 15730, 23758, 5551, 3794, 36081, 11536, 23758, 5551, 3794, 36081, 38688, 9957, 11536, 6024, 48506, 8032, 3215, 12610, 3660, 5296, 15042, 41850, 4724, 16254, 5551, 5172, 30241, 16095, 29538, 11933, 1829, 8592, 8717, 995, 4587, 9381, 11296, 3714, 7435, 2304, 2407, 27884, 11933, 1829, 8592, 11933, 15730, 8032, 47283, 3215, 8978, 1863, 2423, 4386, 376, 70, 22170, 376, 70, 22170, 4032, 29538, 11933, 1829, 8592, 8717, 995, 4587, 9381, 11296, 8032, 47283, 3215, 5995, 18, 376, 70, 22170], "avg_logprob": -0.30744484154617086, "compression_ratio": 1.8192090395480225, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 836.36, "end": 836.84, "word": "أبشر", "probability": 0.6849772135416666}, {"start": 836.84, "end": 837.32, "word": " بطولى", "probability": 0.83673095703125}, {"start": 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"probability": 0.258544921875}, {"start": 852.84, "end": 853.96, "word": " MgBr", "probability": 0.512939453125}, {"start": 853.96, "end": 855.62, "word": " MgBr", "probability": 0.8255208333333334}, {"start": 855.62, "end": 856.76, "word": " و", "probability": 0.56689453125}, {"start": 856.76, "end": 857.04, "word": " هذه", "probability": 0.55908203125}, {"start": 857.04, "end": 857.24, "word": " إيش", "probability": 0.9749348958333334}, {"start": 857.24, "end": 857.82, "word": " ناقصها", "probability": 0.99541015625}, {"start": 857.82, "end": 859.38, "word": " هاخد", "probability": 0.6034342447916666}, {"start": 859.38, "end": 861.94, "word": " CH3", "probability": 0.7017822265625}, {"start": 861.94, "end": 864.6, "word": " MgBr", "probability": 0.9519856770833334}], "temperature": 1.0}, {"id": 37, "seek": 87956, "start": 867.78, "end": 879.56, "text": "واضح؟ مجمعتين بدهم يكونوا على الكيتون والتالتة بدي اجيبها من ال green yard و اعملوا اي خلطة انتوا بتكونوا معاها واضحة في هذه النقطة؟", "tokens": [2407, 46958, 5016, 22807, 3714, 7435, 2304, 34268, 9957, 47525, 16095, 7251, 30544, 14407, 15844, 33251, 36081, 11536, 16070, 2655, 6027, 2655, 3660, 4724, 16254, 1975, 7435, 1829, 3555, 11296, 9154, 2423, 3092, 11682, 4032, 1975, 25957, 1211, 14407, 1975, 1829, 16490, 1211, 9566, 3660, 16472, 2655, 14407, 39894, 30544, 14407, 20449, 995, 11296, 4032, 46958, 5016, 3660, 8978, 29538, 28239, 47432, 3660, 22807], "avg_logprob": -0.2966346153846154, "compression_ratio": 1.5364238410596027, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 867.7800000000001, "end": 868.5600000000001, "word": "واضح؟", "probability": 0.812255859375}, {"start": 868.5600000000001, "end": 869.34, "word": " مجمعتين", "probability": 0.86484375}, {"start": 869.34, "end": 870.28, "word": " بدهم", "probability": 0.5537109375}, {"start": 870.28, "end": 870.66, "word": " يكونوا", "probability": 0.9716796875}, {"start": 870.66, "end": 870.88, "word": " على", "probability": 0.8388671875}, 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أسد هو تفاعل لل الديهيد و الكيتون صارنا عارفينه طيب ال secondary alcohol كانوا يتأكسدوا لإيش لكيتون ال كيتون بتتأكسد أكسدة إضافية لأ إذا هاي الموضوع أكسدت ال الديهيد و الكيتون ان ال الديهيد بيصيروا أسد و الكيتون بتأكسدوش خلصنا", "tokens": [10721, 3224, 9122, 8315, 8717, 39648, 33251, 5016, 12610, 4724, 1829, 9381, 13546, 2423, 2423, 16254, 3224, 25708, 4032, 2423, 2423, 16254, 3224, 25708, 5551, 3794, 3215, 2423, 2423, 16254, 3224, 25708, 5551, 3794, 3215, 31439, 6055, 5172, 995, 30241, 24976, 2423, 16254, 3224, 25708, 4032, 33251, 36081, 11536, 20328, 9640, 8315, 6225, 9640, 5172, 9957, 3224, 23032, 1829, 3555, 2423, 11396, 7658, 25961, 14407, 7251, 2655, 10721, 4117, 3794, 3215, 14407, 5296, 28814, 1829, 8592, 5296, 4117, 36081, 11536, 2423, 9122, 36081, 11536, 39894, 2655, 10721, 4117, 3794, 3215, 5551, 4117, 3794, 41891, 11933, 11242, 31845, 10632, 5296, 10721, 11933, 15730, 8032, 47302, 9673, 2407, 11242, 45367, 5551, 4117, 3794, 3215, 2655, 2423, 2423, 16254, 3224, 25708, 4032, 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"word": " صارنا", "probability": 0.705078125}, {"start": 948.97, "end": 949.57, "word": " عارفينه", "probability": 0.97919921875}, {"start": 949.57, "end": 950.21, "word": " طيب", "probability": 0.8649088541666666}, {"start": 950.21, "end": 950.43, "word": " ال", "probability": 0.83544921875}, {"start": 950.43, "end": 950.89, "word": " secondary", "probability": 0.92822265625}, {"start": 950.89, "end": 951.61, "word": " alcohol", "probability": 0.87255859375}, {"start": 951.61, "end": 952.21, "word": " كانوا", "probability": 0.71630859375}, {"start": 952.21, "end": 952.77, "word": " يتأكسدوا", "probability": 0.9079938616071429}, {"start": 952.77, "end": 953.25, "word": " لإيش", "probability": 0.9156494140625}, {"start": 953.25, "end": 954.55, "word": " لكيتون", "probability": 0.77984619140625}, {"start": 954.55, "end": 954.97, "word": " ال", "probability": 0.64892578125}, {"start": 954.97, "end": 955.41, "word": " كيتون", "probability": 0.8951822916666666}, {"start": 955.41, "end": 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1201.63, "end": 1202.23, "word": " بتم", "probability": 0.766357421875}, {"start": 1202.23, "end": 1202.91, "word": " حذف", "probability": 0.9845377604166666}], "temperature": 1.0}, {"id": 51, "seek": 122463, "start": 1203.83, "end": 1224.63, "text": "ال OH مع ال H على شكل جزيء ماء هاي ال OH هذه مع ال H اللي هنا ع شكل جزيء ماء لما بدوا ينحفوا شو بدوا يصير مكانهم double bond هاني شلتم شلتم شلتم ايش بده احط مكانهم double bond", "tokens": [6027, 13931, 20449, 2423, 389, 15844, 13412, 28820, 10874, 11622, 1829, 38207, 3714, 16606, 8032, 47302, 2423, 13931, 29538, 20449, 2423, 389, 13672, 1829, 34105, 6225, 13412, 28820, 10874, 11622, 1829, 38207, 3714, 16606, 5296, 15042, 47525, 14407, 7251, 1863, 5016, 5172, 14407, 13412, 2407, 47525, 14407, 7251, 9381, 13546, 3714, 41361, 16095, 3834, 6086, 8032, 7649, 1829, 13412, 1211, 39237, 13412, 1211, 39237, 13412, 1211, 39237, 1975, 1829, 8592, 47525, 3224, 1975, 5016, 9566, 3714, 41361, 16095, 3834, 6086], "avg_logprob": -0.2353395061728395, 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بدوا", "probability": 0.5902099609375}, {"start": 1214.03, "end": 1214.53, "word": " ينحفوا", "probability": 0.86708984375}, {"start": 1214.53, "end": 1214.71, "word": " شو", "probability": 0.875732421875}, {"start": 1214.71, "end": 1214.91, "word": " بدوا", "probability": 0.794677734375}, {"start": 1214.91, "end": 1215.17, "word": " يصير", "probability": 0.9397786458333334}, {"start": 1215.17, "end": 1215.91, "word": " مكانهم", "probability": 0.94677734375}, {"start": 1215.91, "end": 1217.07, "word": " double", "probability": 0.267578125}, {"start": 1217.07, "end": 1217.65, "word": " bond", "probability": 0.94775390625}, {"start": 1217.65, "end": 1219.79, "word": " هاني", "probability": 0.9005533854166666}, {"start": 1219.79, "end": 1220.13, "word": " شلتم", "probability": 0.8727213541666666}, {"start": 1220.13, "end": 1220.51, "word": " شلتم", "probability": 0.93896484375}, {"start": 1220.51, "end": 1220.91, "word": " شلتم", "probability": 0.97802734375}, {"start": 1220.91, "end": 1221.43, "word": " ايش", "probability": 0.7083333333333334}, {"start": 1221.43, "end": 1221.57, "word": " بده", "probability": 0.63037109375}, {"start": 1221.57, "end": 1221.81, "word": " احط", "probability": 0.8777669270833334}, {"start": 1221.81, "end": 1222.55, "word": " مكانهم", "probability": 0.9944661458333334}, {"start": 1222.55, "end": 1224.25, "word": " double", "probability": 0.5224609375}, {"start": 1224.25, "end": 1224.63, "word": " bond", "probability": 0.95556640625}], "temperature": 1.0}, {"id": 52, "seek": 124391, "start": 1226.57, "end": 1243.91, "text": "واضح؟ إذا بعد ال addition صار عندي تفاعل elimination وعشان هيك العنوان اللي عندكم كان إيش addition elimination reactions of aldehydes and ketones هذه مع أي مركبات بتصير؟", "tokens": [2407, 46958, 5016, 22807, 11933, 15730, 39182, 2423, 4500, 20328, 9640, 18871, 16254, 6055, 5172, 995, 30241, 29224, 4032, 3615, 8592, 7649, 39896, 4117, 18863, 1863, 2407, 7649, 13672, 1829, 43242, 24793, 25961, 11933, 1829, 8592, 4500, 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"probability": 0.8555908203125}, {"start": 1241.07, "end": 1241.29, "word": " and", "probability": 0.94189453125}, {"start": 1241.29, "end": 1241.67, "word": " ketones", "probability": 0.83349609375}, {"start": 1241.67, "end": 1242.19, "word": " هذه", "probability": 0.36865234375}, {"start": 1242.19, "end": 1242.39, "word": " مع", "probability": 0.98291015625}, {"start": 1242.39, "end": 1242.51, "word": " أي", "probability": 0.68603515625}, {"start": 1242.51, "end": 1243.15, "word": " مركبات", "probability": 0.848876953125}, {"start": 1243.15, "end": 1243.91, "word": " بتصير؟", "probability": 0.9691162109375}], "temperature": 1.0}, {"id": 53, "seek": 125715, "start": 1244.63, "end": 1257.15, "text": "مع الان H2 اللى متصل فيها أي X كانت الان بيجي السؤال من ناحية السهولة هل يا ترى كل مرة عشان نكتب الجواب الصح", "tokens": [2304, 3615, 2423, 7649, 389, 17, 13672, 7578, 44650, 36520, 8978, 11296, 36632, 1783, 25961, 2655, 2423, 7649, 4724, 1829, 7435, 1829, 21136, 33604, 6027, 9154, 8717, 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"word": " كانت", "probability": 0.986572265625}, {"start": 1249.33, "end": 1250.15, "word": " الان", "probability": 0.627197265625}, {"start": 1250.15, "end": 1250.73, "word": " بيجي", "probability": 0.9468994140625}, {"start": 1250.73, "end": 1251.31, "word": " السؤال", "probability": 0.9918619791666666}, {"start": 1251.31, "end": 1251.85, "word": " من", "probability": 0.9794921875}, {"start": 1251.85, "end": 1252.37, "word": " ناحية", "probability": 0.9864908854166666}, {"start": 1252.37, "end": 1253.33, "word": " السهولة", "probability": 0.9935302734375}, {"start": 1253.33, "end": 1253.73, "word": " هل", "probability": 0.826171875}, {"start": 1253.73, "end": 1253.91, "word": " يا", "probability": 0.61572265625}, {"start": 1253.91, "end": 1254.23, "word": " ترى", "probability": 0.82421875}, {"start": 1254.23, "end": 1254.47, "word": " كل", "probability": 0.98583984375}, {"start": 1254.47, "end": 1254.93, "word": " مرة", "probability": 0.9873046875}, {"start": 1254.93, "end": 1255.53, 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بناء على ذلك بنقدر نستنتج استنتاج بسيط جدا ان ال hydrazines بيصيروا hydrazones طب ناخد مثال تاني خلينا نحط هنا H ونحط هنا phenyl في الناتج ايش هيكون عندي هنا H و phenyl", "tokens": [2407, 44945, 16606, 15844, 29910, 23275, 44945, 28543, 2288, 8717, 14851, 29399, 7435, 44713, 29399, 26108, 4724, 3794, 1829, 9566, 10874, 28259, 16472, 2423, 5796, 30695, 1652, 4724, 1829, 9381, 13546, 14407, 5796, 30695, 2213, 23032, 3555, 8717, 47283, 3215, 50113, 6027, 6055, 7649, 1829, 16490, 20292, 8315, 8717, 5016, 9566, 34105, 389, 4032, 1863, 5016, 9566, 34105, 7279, 5088, 8978, 28239, 9307, 7435, 1975, 1829, 8592, 39896, 30544, 43242, 1829, 34105, 389, 4032, 7279, 5088], "avg_logprob": -0.20799513064421615, "compression_ratio": 1.5780346820809248, "no_speech_prob": 0.0, "words": [{"start": 1600.98, "end": 1601.2, "word": "و", "probability": 0.382568359375}, {"start": 1601.2, "end": 1601.58, "word": " بناء", "probability": 0.93701171875}, {"start": 1601.58, "end": 1601.88, "word": " على", 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{"id": 72, "seek": 172792, "start": 1713.32, "end": 1727.92, "text": "هيدرازون بدل ما كان الاسم عندى oen بدو يصير ايش بنزالديهيدفينالهيدرازون بنزالديهيدفينالهيدرازون الان", "tokens": [3224, 25708, 2288, 31377, 11536, 47525, 1211, 19446, 25961, 2423, 32277, 2304, 43242, 7578, 277, 268, 47525, 2407, 7251, 9381, 13546, 1975, 1829, 8592, 44945, 11622, 6027, 16254, 3224, 25708, 5172, 9957, 6027, 3224, 25708, 2288, 31377, 11536, 44945, 11622, 6027, 16254, 3224, 25708, 5172, 9957, 6027, 3224, 25708, 2288, 31377, 11536, 2423, 7649], "avg_logprob": -0.3116477381099354, "compression_ratio": 1.8137254901960784, "no_speech_prob": 0.0, "words": [{"start": 1713.32, "end": 1714.26, "word": "هيدرازون", "probability": 0.77266845703125}, {"start": 1714.26, "end": 1714.76, "word": " بدل", "probability": 0.92236328125}, {"start": 1714.76, "end": 1714.96, "word": " ما", "probability": 0.89794921875}, {"start": 1714.96, "end": 1715.16, "word": " كان", "probability": 0.95556640625}, {"start": 1715.16, "end": 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"probability": 0.8336588541666666}, {"start": 2192.99, "end": 2194.75, "word": " كربازايد", "probability": 0.94892578125}, {"start": 2194.75, "end": 2196.85, "word": " طب", "probability": 0.88525390625}, {"start": 2196.85, "end": 2196.95, "word": " و", "probability": 0.6494140625}, {"start": 2196.95, "end": 2197.45, "word": " الناتج", "probability": 0.8702392578125}, {"start": 2197.45, "end": 2197.61, "word": " اللي", "probability": 0.936767578125}, {"start": 2197.61, "end": 2197.95, "word": " بتطلع", "probability": 0.7216796875}, {"start": 2197.95, "end": 2198.15, "word": " من", "probability": 0.990234375}, {"start": 2198.15, "end": 2198.59, "word": " السيمي", "probability": 0.8230794270833334}, {"start": 2198.59, "end": 2199.47, "word": " كربازايد", "probability": 0.956640625}], "temperature": 1.0}, {"id": 89, "seek": 222511, "start": 2200.31, "end": 2225.11, "text": "Semi-carbazone زي هيدرازين هيدرازون Carbazide Carbazone إذا هذا المركب كاملا الأن لو بدنا نسميه شو هنسميه؟ Cyclobentanone Semi-carbazone", "tokens": [50, 13372, 12, 6166, 65, 921, 546, 30767, 1829, 8032, 25708, 2288, 31377, 9957, 8032, 25708, 2288, 31377, 11536, 2741, 65, 921, 482, 2741, 65, 921, 546, 11933, 15730, 23758, 9673, 31747, 3555, 9122, 10943, 15040, 16247, 1863, 45164, 47525, 8315, 8717, 38251, 1829, 3224, 13412, 2407, 8032, 1863, 38251, 1829, 3224, 22807, 10295, 66, 752, 65, 317, 282, 546, 318, 13372, 12, 6166, 65, 921, 546], "avg_logprob": -0.2879135994350209, "compression_ratio": 1.3732394366197183, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2200.31, "end": 2200.91, "word": "Semi", "probability": 0.57586669921875}, {"start": 2200.91, "end": 2202.59, "word": "-carbazone", "probability": 0.643505859375}, {"start": 2202.59, "end": 2203.69, "word": " زي", "probability": 0.892822265625}, {"start": 2203.69, "end": 2204.73, "word": " هيدرازين", "probability": 0.86787109375}, {"start": 2204.73, "end": 2206.19, "word": " هيدرازون", "probability": 0.9013671875}, {"start": 2206.19, "end": 2207.45, "word": " Carbazide", "probability": 0.72418212890625}, {"start": 2207.45, "end": 2208.29, "word": " Carbazone", "probability": 0.83819580078125}, {"start": 2208.29, "end": 2208.83, "word": " إذا", "probability": 0.692626953125}, {"start": 2208.83, "end": 2209.21, "word": " هذا", "probability": 0.95458984375}, {"start": 2209.21, "end": 2209.95, "word": " المركب", "probability": 0.9093424479166666}, {"start": 2209.95, "end": 2210.65, "word": " كاملا", "probability": 0.8904622395833334}, {"start": 2210.65, "end": 2211.13, "word": " الأن", "probability": 0.60015869140625}, {"start": 2211.13, "end": 2211.29, "word": " لو", "probability": 0.9677734375}, {"start": 2211.29, "end": 2211.57, "word": " بدنا", "probability": 0.974365234375}, {"start": 2211.57, "end": 2212.09, "word": " نسميه", "probability": 0.990966796875}, {"start": 2212.09, "end": 2212.25, "word": " شو", "probability": 0.767333984375}, {"start": 2212.25, "end": 2214.61, "word": " هنسميه؟", "probability": 0.8191731770833334}, {"start": 2214.61, "end": 2220.45, "word": " Cyclobentanone", "probability": 0.6683872767857143}, {"start": 2220.45, "end": 2222.51, "word": " Semi", "probability": 0.56036376953125}, {"start": 2222.51, "end": 2225.11, "word": "-carbazone", "probability": 0.90556640625}], "temperature": 1.0}, {"id": 90, "seek": 225092, "start": 2227.49, "end": 2250.93, "text": "cyclobentanone-semicarbazone هذا هو ال slide الأخير", "tokens": [1344, 3474, 996, 317, 282, 546, 12, 19872, 7953, 65, 921, 546, 23758, 31439, 2423, 4137, 16247, 9778, 13546], "avg_logprob": -0.4980468720197678, "compression_ratio": 0.9411764705882353, "no_speech_prob": 0.0, "words": [{"start": 2227.49, "end": 2228.89, "word": "cyclobentanone", "probability": 0.6944986979166666}, {"start": 2228.89, "end": 2230.29, "word": "-semicarbazone", "probability": 0.7027180989583334}, {"start": 2230.29, "end": 2237.29, "word": " هذا", "probability": 0.2391357421875}, {"start": 2237.29, "end": 2249.31, 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{"start": 2267.98, "end": 2268.96, "word": " oxime", "probability": 0.4710693359375}, {"start": 2268.96, "end": 2269.58, "word": " ال", "probability": 0.6298828125}, {"start": 2269.58, "end": 2270.44, "word": " semi", "probability": 0.6416015625}, {"start": 2270.44, "end": 2271.26, "word": " carbazide", "probability": 0.7403971354166666}, {"start": 2271.26, "end": 2271.8, "word": " بيعطي", "probability": 0.982666015625}, {"start": 2271.8, "end": 2272.24, "word": " semi", "probability": 0.8251953125}, {"start": 2272.24, "end": 2273.76, "word": " carbazone", "probability": 0.8551432291666666}, {"start": 2273.76, "end": 2274.16, "word": " ال", "probability": 0.98095703125}, {"start": 2274.16, "end": 2275.1, "word": " hydrazines", "probability": 0.6344401041666666}, {"start": 2275.1, "end": 2276.28, "word": " بيعطي", "probability": 0.949462890625}, {"start": 2276.28, "end": 2278.22, "word": " hydrazones", "probability": 0.7740885416666666}, {"start": 2278.22, "end": 2279.8, "word": " واضح؟", "probability": 0.77960205078125}, {"start": 2279.8, "end": 2280.2, "word": " مرة", "probability": 0.961669921875}, {"start": 2280.2, "end": 2280.5, "word": " تانية", "probability": 0.951171875}, {"start": 2280.5, "end": 2280.88, "word": " نعيدهم", "probability": 0.816650390625}, {"start": 2280.88, "end": 2281.04, "word": " مع", "probability": 0.99169921875}, {"start": 2281.04, "end": 2281.48, "word": " بعض", "probability": 0.99365234375}, {"start": 2281.48, "end": 2282.16, "word": " ال", "probability": 0.96533203125}, {"start": 2282.16, "end": 2283.02, "word": " hydrazine", "probability": 0.7677408854166666}], "temperature": 1.0}, {"id": 92, "seek": 231387, "start": 2284.69, "end": 2313.87, "text": "والهيدروكس الأمين أكزيم والسمي كربازايد سيمي كربازون والأمين اللي هي متصلة بR امين امين بس واضح لو نعطي مثال ولا نقول الله يعطيكوا العافية بنعطي مثلين بنعطي مثلين و بنخلص اليوم إجاكم سؤال أرسموا إيثانال أكزيم", "tokens": [2407, 6027, 3224, 25708, 2288, 2407, 4117, 3794, 16247, 2304, 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"word": " أكزيم", "probability": 0.7474365234375}, {"start": 2287.65, "end": 2288.15, "word": " والسمي", "probability": 0.4322102864583333}, {"start": 2288.15, "end": 2288.89, "word": " كربازايد", "probability": 0.7615234375}, {"start": 2288.89, "end": 2289.85, "word": " سيمي", "probability": 0.7334798177083334}, {"start": 2289.85, "end": 2290.57, "word": " كربازون", "probability": 0.9095458984375}, {"start": 2290.57, "end": 2291.73, "word": " والأمين", "probability": 0.804443359375}, {"start": 2291.73, "end": 2292.33, "word": " اللي", "probability": 0.5167236328125}, {"start": 2292.33, "end": 2292.51, "word": " هي", "probability": 0.31298828125}, {"start": 2292.51, "end": 2293.13, "word": " متصلة", "probability": 0.9064127604166666}, {"start": 2293.13, "end": 2293.65, "word": " بR", "probability": 0.56134033203125}, {"start": 2293.65, "end": 2295.17, "word": " امين", "probability": 0.6746419270833334}, {"start": 2295.17, "end": 2296.05, "word": " امين", "probability": 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إثل كيتون فين الهيدرازون يلا نجلوني إيثانال عارفين الإيثانال؟", "tokens": [2407, 28814, 7435, 7649, 995, 21136, 33604, 6027, 1975, 2288, 38251, 3224, 11778, 47302, 11933, 12984, 1211, 9122, 36081, 11536, 8978, 1863, 2423, 3224, 25708, 2288, 31377, 11536, 7251, 15040, 8717, 7435, 1211, 11536, 1829, 11933, 1829, 12984, 7649, 6027, 6225, 9640, 5172, 9957, 33688, 1829, 12984, 7649, 6027, 22807], "avg_logprob": -0.3069853081422694, "compression_ratio": 1.5339805825242718, "no_speech_prob": 0.0, "words": [{"start": 2315.52, "end": 2316.38, "word": "وإجانا", "probability": 0.556640625}, {"start": 2316.38, "end": 2316.9, "word": " السؤال", "probability": 0.9187825520833334}, {"start": 2316.9, "end": 2318.24, "word": " ارسمه", "probability": 0.8052978515625}, {"start": 2318.24, "end": 2321.22, "word": " داي", "probability": 0.383575439453125}, {"start": 2321.22, "end": 2321.92, "word": " إثل", "probability": 0.6016438802083334}, {"start": 2321.92, "end": 2324.44, "word": " كيتون", 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2405.65, "word": " إشي", "probability": 0.8468424479166666}, {"start": 2405.65, "end": 2406.37, "word": " هتكون", "probability": 0.9513346354166666}, {"start": 2406.37, "end": 2407.07, "word": " أتقنطوه", "probability": 0.7977120535714286}, {"start": 2407.07, "end": 2407.35, "word": " لان", "probability": 0.591064453125}, {"start": 2407.35, "end": 2407.61, "word": " لكن", "probability": 0.72265625}, {"start": 2407.61, "end": 2407.77, "word": " في", "probability": 0.859375}, {"start": 2407.77, "end": 2408.35, "word": " المحاضرة", "probability": 0.9854736328125}, {"start": 2408.35, "end": 2408.51, "word": " اللي", "probability": 0.644287109375}, {"start": 2408.51, "end": 2408.71, "word": " جاية", "probability": 0.8564453125}, {"start": 2408.71, "end": 2408.91, "word": " لما", "probability": 0.92333984375}, {"start": 2408.91, "end": 2409.75, "word": " تتدربوا", "probability": 0.9791015625}, {"start": 2409.75, "end": 2410.13, "word": " و", "probability": 0.82666015625}, {"start": 2410.13, "end": 2410.25, "word": " ال", "probability": 0.85791015625}, {"start": 2410.25, "end": 2410.63, "word": " organic", "probability": 0.568359375}, {"start": 2410.63, "end": 2411.29, "word": " تدريب", "probability": 0.988525390625}, {"start": 2411.29, "end": 2411.37, "word": " و", "probability": 0.403076171875}, {"start": 2411.37, "end": 2412.05, "word": " كتابة", "probability": 0.9644775390625}, {"start": 2412.05, "end": 2412.69, "word": " أكيد", "probability": 0.8902994791666666}, {"start": 2412.69, "end": 2412.85, "word": " ان", "probability": 0.6748046875}, {"start": 2412.85, "end": 2413.03, "word": " شاء", "probability": 0.968994140625}, {"start": 2413.03, "end": 2413.11, "word": " الله", "probability": 0.953125}, {"start": 2413.11, "end": 2413.39, "word": " كل", "probability": 0.98095703125}, {"start": 2413.39, "end": 2413.99, "word": " شيء", "probability": 0.60498046875}, {"start": 2413.99, "end": 2415.31, "word": " بتتقنوه", "probability": 0.9608561197916666}, {"start": 2415.31, "end": 2416.11, "word": " بهيك", "probability": 0.6512858072916666}, {"start": 2416.11, "end": 2417.39, "word": " بننتهي", "probability": 0.9332275390625}, {"start": 2417.39, "end": 2417.79, "word": " من", "probability": 0.990234375}, {"start": 2417.79, "end": 2418.35, "word": " درس", "probability": 0.9884440104166666}, {"start": 2418.35, "end": 2418.55, "word": " ال", "probability": 0.94970703125}, {"start": 2418.55, "end": 2419.41, "word": " aldehydes", "probability": 0.7137451171875}, {"start": 2419.41, "end": 2419.87, "word": " و", "probability": 0.88916015625}, {"start": 2419.87, "end": 2420.01, "word": " ال", "probability": 0.87353515625}, {"start": 2420.01, "end": 2420.55, "word": " ketones", "probability": 0.823974609375}, {"start": 2420.55, "end": 2420.69, "word": " و", "probability": 0.95556640625}, {"start": 2420.69, "end": 2420.79, "word": " ان", "probability": 0.82373046875}, {"start": 2420.79, "end": 2421.01, "word": " شاء", "probability": 0.990478515625}, {"start": 2421.01, "end": 2421.33, "word": " الله", "probability": 0.9560546875}, {"start": 2421.33, "end": 2422.19, "word": " يوم", "probability": 0.993408203125}, {"start": 2422.19, "end": 2422.93, "word": " السبت", "probability": 0.9558919270833334}], "temperature": 1.0}, {"id": 97, "seek": 244798, "start": 2423.74, "end": 2447.98, "text": "في عندنا مراجعة للامتحانات النصفية كونوا مجاهزينها او ساحبينها ع ورق و حلينها احنا بنحلها انا قدامكم و بنناقش اي مشكلة فيها و بعد هيك ان شاء الله بنبدأ في موضوع الأحماض و مستقبلها و الامتحان لنهاية الفصل السادس حكينا بوضوح الامتحان لنهاية الفصل السادس اذا سمحت", "tokens": [41185, 43242, 8315, 3714, 2288, 26108, 27884, 24976, 10943, 2655, 5016, 7649, 9307, 28239, 9381, 5172, 10632, 9122, 11536, 14407, 3714, 7435, 40294, 11622, 9957, 11296, 1975, 2407, 8608, 39319, 3555, 9957, 11296, 6225, 4032, 2288, 4587, 4032, 11331, 1211, 9957, 11296, 1975, 5016, 8315, 44945, 5016, 1211, 11296, 1975, 8315, 12174, 3215, 10943, 24793, 4032, 44945, 8315, 4587, 8592, 1975, 1829, 37893, 28820, 3660, 8978, 11296, 4032, 39182, 39896, 4117, 16472, 13412, 16606, 21984, 44945, 44510, 10721, 8978, 3714, 2407, 11242, 45367, 16247, 35571, 46958, 4032, 3714, 14851, 4587, 36150, 11296, 4032, 2423, 10943, 2655, 5016, 7649, 5296, 1863, 11296, 10632, 27188, 36520, 21136, 18513, 3794, 11331, 4117, 1829, 8315, 4724, 2407, 11242, 2407, 5016, 2423, 10943, 2655, 5016, 7649, 5296, 1863, 11296, 10632, 27188, 36520, 21136, 18513, 3794, 1975, 15730, 8608, 2304, 33753], "avg_logprob": -0.13740809360409484, "compression_ratio": 2.0973451327433628, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 2423.74, "end": 2423.98, "word": "في", "probability": 0.67724609375}, {"start": 2423.98, "end": 2424.38, "word": " عندنا", "probability": 0.982666015625}, {"start": 2424.38, "end": 2425.24, "word": " مراجعة", "probability": 0.960205078125}, {"start": 2425.24, "end": 2426.46, "word": " للامتحانات", "probability": 0.8868408203125}, {"start": 2426.46, "end": 2427.06, "word": " النصفية", "probability": 0.975341796875}, {"start": 2427.06, "end": 2427.46, "word": " كونوا", "probability": 0.80224609375}, {"start": 2427.46, "end": 2428.46, "word": " مجاهزينها", "probability": 0.8374837239583334}, {"start": 2428.46, "end": 2428.72, "word": " او", "probability": 0.708984375}, {"start": 2428.72, "end": 2429.36, "word": " ساحبينها", "probability": 0.844921875}, {"start": 2429.36, "end": 2429.46, "word": " ع", "probability": 0.8564453125}, {"start": 2429.46, "end": 2429.84, "word": " ورق", "probability": 0.8876953125}, {"start": 2429.84, "end": 2429.96, "word": " و", "probability": 0.9794921875}, {"start": 2429.96, "end": 2430.68, "word": " حلينها", "probability": 0.7738037109375}, {"start": 2430.68, "end": 2431.42, "word": " احنا", "probability": 0.9305013020833334}, {"start": 2431.42, "end": 2431.88, "word": " بنحلها", "probability": 0.9656982421875}, {"start": 2431.88, "end": 2432.14, "word": " انا", "probability": 0.65966796875}, {"start": 2432.14, "end": 2432.82, "word": " قدامكم", "probability": 0.976318359375}, {"start": 2432.82, "end": 2432.98, "word": " و", "probability": 0.90380859375}, {"start": 2432.98, "end": 2433.52, "word": " بنناقش", "probability": 0.96630859375}, {"start": 2433.52, "end": 2433.74, "word": " اي", "probability": 0.918212890625}, {"start": 2433.74, "end": 2434.22, "word": " مشكلة", "probability": 0.97802734375}, {"start": 2434.22, "end": 2434.62, "word": " فيها", "probability": 0.98974609375}, {"start": 2434.62, "end": 2435.4, "word": " و", "probability": 0.73388671875}, {"start": 2435.4, "end": 2435.7, "word": " بعد", "probability": 0.92236328125}, {"start": 2435.7, "end": 2436.0, "word": " هيك", "probability": 0.692626953125}, {"start": 2436.0, "end": 2436.14, "word": " ان", "probability": 0.861328125}, {"start": 2436.14, "end": 2436.36, "word": " شاء", "probability": 0.979248046875}, {"start": 2436.36, "end": 2436.48, "word": " الله", "probability": 0.94580078125}, {"start": 2436.48, "end": 2436.98, "word": " بنبدأ", "probability": 0.9777018229166666}, {"start": 2436.98, "end": 2437.14, "word": " في", "probability": 0.900390625}, {"start": 2437.14, "end": 2437.52, "word": " موضوع", "probability": 0.9945068359375}, {"start": 2437.52, "end": 2438.16, "word": " الأحماض", "probability": 0.7822265625}, {"start": 2438.16, "end": 2438.3, "word": " و", "probability": 0.994140625}, {"start": 2438.3, "end": 2439.22, "word": " مستقبلها", "probability": 0.62216796875}, {"start": 2439.22, "end": 2439.38, "word": " و", "probability": 0.5419921875}, {"start": 2439.38, "end": 2440.12, "word": " الامتحان", "probability": 0.9578125}, {"start": 2440.12, "end": 2440.8, "word": " لنهاية", "probability": 0.957763671875}, {"start": 2440.8, "end": 2441.3, "word": " الفصل", "probability": 0.940673828125}, {"start": 2441.3, "end": 2442.02, "word": " السادس", "probability": 0.9599609375}, {"start": 2442.02, "end": 2442.52, "word": " حكينا", "probability": 0.95458984375}, {"start": 2442.52, "end": 2443.16, "word": " بوضوح", "probability": 0.971484375}, {"start": 2443.16, "end": 2445.26, "word": " الامتحان", "probability": 0.9583984375}, {"start": 2445.26, "end": 2445.88, "word": " لنهاية", "probability": 0.971923828125}, {"start": 2445.88, "end": 2446.44, "word": " الفصل", "probability": 0.98681640625}, {"start": 2446.44, "end": 2447.28, "word": " السادس", "probability": 0.9807942708333334}, {"start": 2447.28, "end": 2447.56, "word": " اذا", "probability": 0.693115234375}, {"start": 2447.56, "end": 2447.98, "word": " سمحت", "probability": 0.9532877604166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2449.61225, "duration_after_vad": 2332.394374999992}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4adc0e525ea98578e86ba889562aaaf66dd92f29
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/sAaNw--MBo4_raw.srt
@@ -0,0 +1,1652 @@
+1
+00:00:19,470 --> 00:00:24,710
+بسم الله الرحمن الرحيم بنكمل اليوم في موضوع ال
+
+2
+00:00:24,710 --> 00:00:30,170
+aldehydes و ال ketones و ربما كلكم الذاكرين أنه
+
+3
+00:00:30,170 --> 00:00:34,130
+التفاعل الأساسي لل aldehydes و ال ketones كان
+
+4
+00:00:34,910 --> 00:00:40,890
+Heniocleophilic Addition أخدنا
+
+5
+00:00:40,890 --> 00:00:47,150
+عدة أمثلة ع الموضوع إضافة الماء الكحول ال cyanide
+
+6
+00:00:47,150 --> 00:00:53,200
+مثلا ال H- لعملية ال reductionواليوم هناخد بشكل
+
+7
+00:00:53,200 --> 00:00:58,440
+أساسي كمان مثلين على هذا الموضوع يعني للناس اللي
+
+8
+00:00:58,440 --> 00:01:03,180
+بيحبوا الصور الكلية وبيفهموا الموضوع بالصورة
+
+9
+00:01:03,180 --> 00:01:06,980
+الكلية مش بالصورة الجزائية أو الجزئية خلينا نقول
+
+10
+00:01:06,980 --> 00:01:13,120
+كأنه كل تفاعلات الكحولات لو بدكم تسجلوها إضافة ما
+
+11
+00:01:14,130 --> 00:01:21,730
+بحط OH كحول بحط Oethyl أو OR in general فعلا ال
+
+12
+00:01:21,730 --> 00:01:27,870
+cyanide بحط CN minus ال hydride بحطأتش ماينوس الان
+
+13
+00:01:27,870 --> 00:01:33,370
+في عندنا اضافتين واحدة من هذول الاضافتين التفاعل
+
+14
+00:01:33,370 --> 00:01:39,450
+مع green yard reagent واضح عادة هذا المتفاعل يمكن
+
+15
+00:01:39,450 --> 00:01:43,270
+ماعندكم مش خبرة عنه بنتعرف عليه شو هو green yard
+
+16
+00:01:43,270 --> 00:01:47,020
+reagentإذا بتلاحظوا reaction of aldehydes and
+
+17
+00:01:47,020 --> 00:01:51,340
+ketones with Grignard reagent ربما تقرأوا الكلمة
+
+18
+00:01:51,340 --> 00:01:57,260
+كأنها Grignard لكن عادة احنا بنقولها ايش Grignard
+
+19
+00:01:57,260 --> 00:02:06,290
+reagent هذا متفاعل اللي عمله لأنه مهم كتيراخد عليه
+
+20
+00:02:06,290 --> 00:02:13,430
+جائزة نوبل في الكيميا عشانك جربه ممكن تفهمه جيدا و
+
+21
+00:02:13,430 --> 00:02:19,730
+الكلام مش جديد يعني في ال 1911 تقريبا قبل أكثر من
+
+22
+00:02:20,620 --> 00:02:25,320
+ميت سنة بتعرف جائزة نوبل بدت من ال 1900 تقريبا
+
+23
+00:02:25,320 --> 00:02:31,620
+فبال 1911 أخد عليه جائزة نوبل ايش هو ال green yard
+
+24
+00:02:31,620 --> 00:02:38,120
+reagent بالظبط الان لو أخدنا احنا اي مركب متصل
+
+25
+00:02:38,120 --> 00:02:45,980
+بهالوجل RX او ARX بتحبوا تاخدوهم بالصيغة العامة
+
+26
+00:02:45,980 --> 00:02:54,100
+بمشي الحال يعني بقول RX اوARX بتحبوا تاخدوهم بمثال
+
+27
+00:02:54,100 --> 00:03:00,600
+بيمشي الحال برضه يعني مثلا نقول CH3CH2CL
+
+28
+00:03:00,600 --> 00:03:06,580
+هايه بمثال واضح CH3CH2PR
+
+29
+00:03:06,580 --> 00:03:13,120
+هذا RX ولا لأ؟ RX ولو بدي انا ARX مثلا اخد فنل
+
+30
+00:03:13,120 --> 00:03:24,730
+بنزينة فنل PR او فنل CLالان لو اخدنا RX او ARX
+
+31
+00:03:24,730 --> 00:03:29,590
+وفعلناهم مع بودرة المغنيسيوم في ظروف جافة في
+
+32
+00:03:29,590 --> 00:03:33,810
+solvent ال ether يعني هدولا بنافعلهم مع ايش؟
+
+33
+00:03:33,810 --> 00:03:40,970
+مغنيسيوم MG و عادة بستعملوا solvent ether والاصل
+
+34
+00:03:40,970 --> 00:03:47,370
+يكون dry ether واضح؟ الان هذا بيتفعل بيعطينا الشكل
+
+35
+00:03:47,370 --> 00:03:59,110
+القاتل بيعطيناCH3 CH2 CH3
+
+36
+00:03:59,110 --> 00:03:59,410
+CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH3 CH3 CH3 CH3
+
+37
+00:03:59,410 --> 00:04:00,690
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+38
+00:04:00,690 --> 00:04:02,730
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+39
+00:04:02,730 --> 00:04:03,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+40
+00:04:03,130 --> 00:04:03,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+41
+00:04:03,130 --> 00:04:03,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+42
+00:04:03,130 --> 00:04:03,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+43
+00:04:03,130 --> 00:04:07,610
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+44
+00:04:07,610 --> 00:04:11,670
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+45
+00:04:11,670 --> 00:04:16,080
+CH3 CH3greenyard reagent الان لو كنت بدى اسميه
+
+46
+00:04:16,080 --> 00:04:20,860
+بمشي فيه من الشمال لليمين هذه المجموعة شو هي ايه
+
+47
+00:04:20,860 --> 00:04:29,040
+فين ماجنيسيوم برومايو هذا فنل ماجنيسيوم برومايو
+
+48
+00:04:29,040 --> 00:04:35,000
+ومثلها مثيل وبروبيل وايزوبروبيل وهكذا هذا هو ال
+
+49
+00:04:35,000 --> 00:04:39,320
+greenyard reagent عرفنا بالظبط شو هو الان هذا ال
+
+50
+00:04:39,320 --> 00:04:45,030
+greenyard reagentماذا هو الفائدة التي جعل الناس
+
+51
+00:04:45,030 --> 00:04:52,270
+يعطوه جائزة نوبل في الكيميا للعالم هذا؟ ال
+
+52
+00:04:52,270 --> 00:04:57,070
+greenery agent هو عبارة عن carbon nucleophile يعني
+
+53
+00:04:57,070 --> 00:05:02,450
+انا لما بدي اتعامل معه بدي اخده بهذا الشكل أنسى ال
+
+54
+00:05:02,450 --> 00:05:03,230
+MgBr
+
+55
+00:05:05,600 --> 00:05:09,900
+بدي أخده بهذا الشكل الان هو بهذا الشكل صار بيمثل
+
+56
+00:05:09,900 --> 00:05:17,120
+لي CH3 CH2 وزوج إلكترونات على الكاربون فهو carbon
+
+57
+00:05:17,120 --> 00:05:22,140
+nucleophile أو أخده بهذا الشكليعني هو صح موجود
+
+58
+00:05:22,140 --> 00:05:26,820
+كمركب لكن في لحظة التفاعل يعني تخيلوا بالظبط a
+
+59
+00:05:26,820 --> 00:05:31,400
+green yard reagent كأنه هذا القلم الآن هذا الجزء
+
+60
+00:05:31,400 --> 00:05:35,360
+اللي فيه ال nucleophile هو اللي بيجي يتفاعل و يعمل
+
+61
+00:05:35,360 --> 00:05:41,160
+addition و ال MgBr ما انه ملها واضح؟فكأنه يمثل هذا
+
+62
+00:05:41,160 --> 00:05:43,900
+القلم مع الغطاية، الان انا مهتم بالغطاية ولا
+
+63
+00:05:43,900 --> 00:05:48,020
+بالقلم؟ الان انا من ال green yardary agent بإيش
+
+64
+00:05:48,020 --> 00:05:53,820
+مهتم؟ بال R مع إلكتروناتها أو بال AR مع
+
+65
+00:05:53,820 --> 00:05:59,420
+إلكتروناتهاواضحة الفكرة؟ الان لما بدي اجي اقول ان
+
+66
+00:05:59,420 --> 00:06:05,240
+هذا ال R مع إلكتروناتها او ال AR مع إلكتروناتها
+
+67
+00:06:05,240 --> 00:06:08,960
+بدها تيجي تتفاعل مع الديهيد او الكيتون هي أصبحت
+
+68
+00:06:08,960 --> 00:06:14,800
+نيوكليوفاين الان كيف بتيجي و اين بتيجي تهاجم؟ هاي
+
+69
+00:06:14,800 --> 00:06:22,590
+ال R بدها تهاجم هنا وهذه ايش بدها تصير؟OH في
+
+70
+00:06:22,590 --> 00:06:26,770
+النهاية طبعا هو هنا كتبلكوا التفاعل بالتفصيل ان
+
+71
+00:06:26,770 --> 00:06:31,290
+اول ما بتهاجم هنا بتصير OMGPR بعدين بنضيف عليه
+
+72
+00:06:31,290 --> 00:06:35,990
+نقطة ميه و حامض فبتصفى OH الان هي نتيجة نهائية
+
+73
+00:06:35,990 --> 00:06:40,130
+يعني هذه الشغل تفصيل جوا التفاعل احنا مش مهتمين
+
+74
+00:06:40,130 --> 00:06:43,410
+فيها بدنا في النهاية نتيجة نهائية متذكرين المرة
+
+75
+00:06:43,410 --> 00:06:48,810
+الماضية لما كنا نقولكم كل CW bond O ايش بتصير وكنا
+
+76
+00:06:48,810 --> 00:06:56,310
+نحطها بمربع أخضرو النيوكليوفايل بيهاجم هاي
+
+77
+00:06:56,310 --> 00:07:01,330
+نيوكليوفايل و السيطة بالبنط O صارت OH الآن ال R و
+
+78
+00:07:01,330 --> 00:07:08,210
+ال R' ما تدخلوش احنا كل اللي عملناه الحقيقة في
+
+79
+00:07:08,210 --> 00:07:11,930
+التفاعلات كل اللي عملناه في التفاعلات تبع ال
+
+80
+00:07:11,930 --> 00:07:16,690
+aldehydes و ال ketones هو فقط تغيير اللي هان يعني
+
+81
+00:07:16,690 --> 00:07:20,310
+كل اللي درسنا قولنا لما تكون هذه مياه بده يكون هنا
+
+82
+00:07:22,430 --> 00:07:27,930
+OH لما يكون كحول OR لما يكون cyanide CN لما يكون
+
+83
+00:07:27,930 --> 00:07:32,970
+hydride H الان لما يكون green yard R
+
+84
+00:07:36,320 --> 00:07:40,660
+وبعد شوية هنجيب نيتروجين نيوكليوفايل يتحد هنا
+
+85
+00:07:40,660 --> 00:07:45,980
+بنكون خلصنا الشطر الألديهيد والكيتونز فكل شغلنا
+
+86
+00:07:45,980 --> 00:07:52,340
+الحقيقة هو عبارة عن أمثلة لنفس التفاعل أمثلة لنفس
+
+87
+00:07:52,340 --> 00:07:56,820
+التفاعل فقط تغيير النيوكليوفايل في كل الأحوال عندي
+
+88
+00:07:56,820 --> 00:08:00,500
+addition و ال C double bond O بتصير OH هذا عام
+
+89
+00:08:00,500 --> 00:08:05,030
+مشترك لكن النيوكليوفايل مارا يكون كذا كذا كذااليوم
+
+90
+00:08:05,030 --> 00:08:09,050
+ايش لنيو كليو فايل تبعنا ل green yard ray agent
+
+91
+00:08:09,050 --> 00:08:15,630
+اللي هو R مع إلكتروناتها او AR مع إلكتروناتها و
+
+92
+00:08:15,630 --> 00:08:19,850
+عرفنا كيف بتحضر يعني لو كنا بديني ب RX كتبنا مع ال
+
+93
+00:08:19,850 --> 00:08:25,790
+MG بنكتب RMGX بعدين لما بنفعله ايش بناخد منه بس ال
+
+94
+00:08:25,790 --> 00:08:34,190
+R ال RMGX مش موضوعنا الآن هذا التفاعل حقيقةمهم
+
+95
+00:08:34,190 --> 00:08:40,270
+كتير ليش؟ خلّينا نجرب نفس الـgreenyard reagent على
+
+96
+00:08:40,270 --> 00:08:44,770
+أنواع مختلفة من الالديهيدس والكيتونز نقول
+
+97
+00:08:44,770 --> 00:08:48,410
+الـgreenyard reagent تبعنا إثل الـRGBR يعني إثل
+
+98
+00:08:48,410 --> 00:08:52,430
+مجليسيامبروميدل الآن هذا إيش هيحُك اليوكليوفاين؟
+
+99
+00:08:53,400 --> 00:08:59,020
+مجموعة ال aethyl لو فعلنا مع ال formaldehyde اللي
+
+100
+00:08:59,020 --> 00:09:05,580
+هو أبسط ال dehyde هذه بدها تصير OH و بده يحط عندها
+
+101
+00:09:05,580 --> 00:09:13,060
+مجموعة ال aethyl هاي مجموعة ال aethyl شايفينها و
+
+102
+00:09:13,060 --> 00:09:20,200
+هنا CH2 OH هذه ثابتةواضح؟ إذا هو حط مجموعة الـ
+
+103
+00:09:20,200 --> 00:09:22,660
+ethylene لاحظوا الآن ال green yard مع ال
+
+104
+00:09:22,660 --> 00:09:28,120
+formaldehyde كوالي كحول إيش نوع هذا الكحول؟
+
+105
+00:09:28,120 --> 00:09:32,880
+primary alcohol طيب خليني أفعل ال green yard مع أي
+
+106
+00:09:32,880 --> 00:09:40,060
+aldehyde تاني غير ال formaldehyde يعني
+
+107
+00:09:40,060 --> 00:09:44,360
+acetaldehyde هذا, ibropenaldehyde, benzaldehyde
+
+108
+00:09:44,360 --> 00:09:51,840
+طبعا هيحط برضه مجموعةالإثل وهي جزء ال الديهايد
+
+109
+00:09:51,840 --> 00:09:56,320
+كانت كاربون متصل فيها H وCH3 وصارت OH الآن إيش
+
+110
+00:09:56,320 --> 00:10:02,760
+كوّل لها سكندري الكحول طب خلّيه يتفاعل مع ال كيتون
+
+111
+00:10:02,760 --> 00:10:10,200
+مع هذا الاسيتون شو هيحط مجموعة ال إثل تيرتشاري
+
+112
+00:10:10,200 --> 00:10:17,710
+الكحول واضح؟إذن الآن صرنا فاهمين ليش greenery
+
+113
+00:10:17,710 --> 00:10:21,810
+agent موضوع مهم لأن هو بالنسبة لنا بيمثل طريقة
+
+114
+00:10:21,810 --> 00:10:26,910
+لتحضير كل أنواع الكحولات يعني لو بدى primary
+
+115
+00:10:26,910 --> 00:10:32,610
+alcohol بدى أنطلق من ال formaldehyde تمام؟ لو بدى
+
+116
+00:10:32,610 --> 00:10:39,150
+secondary alcohol بدى أنطلق من أي aldehyde تاني
+
+117
+00:10:39,150 --> 00:10:44,410
+غيرغير ال formaldehyde لأن ال formaldehyde بيعطي
+
+118
+00:10:44,410 --> 00:10:47,710
+ال alcohol برايمر كل ال aldehydes التانية بيعطيه
+
+119
+00:10:48,170 --> 00:10:53,850
+secondary لو بدى tertiary alcohol بدى كيت بيعطينى
+
+120
+00:10:53,850 --> 00:10:58,830
+بدى اتفاعل مع او بدى تم التفاعل مع الكيتون وبناء
+
+121
+00:10:58,830 --> 00:11:03,810
+على ذلك لو قلنالكوا اكمل المعادلة او مثلا كيف تحضر
+
+122
+00:11:03,810 --> 00:11:10,910
+كحول معين كيف بدى يكون الجواب تبعنا باستعمال طريقة
+
+123
+00:11:10,910 --> 00:11:15,710
+ingredient باستعمال طريقة ingredient خلينا ناخد
+
+124
+00:11:17,360 --> 00:11:23,800
+مثال او اكتر على هذا الموضوع حتى انرسخ هذا الكلام
+
+125
+00:11:23,800 --> 00:11:32,360
+يعني لو اجينا سألناكم عندكم هذا الكحول فينيل CH2OH
+
+126
+00:11:32,360 --> 00:11:39,860
+how can you prepare this alcohol فكرولي ان انتوا
+
+127
+00:11:39,860 --> 00:11:44,080
+بتكونوا تحضروا هذا الكحول بطريقة السيد الجرين يعني
+
+128
+00:11:45,470 --> 00:11:51,690
+ماشي اللي هنقوله ايش
+
+129
+00:11:51,690 --> 00:12:00,310
+نوع هذا الكحول ال primary اذا انا لازمني ال CH2 و
+
+130
+00:12:00,310 --> 00:12:04,990
+ال double bond all formaldehyde و بدي افعله مع اي
+
+131
+00:12:04,990 --> 00:12:11,970
+green yardary agent مع فنل MgBr
+
+132
+00:12:14,230 --> 00:12:17,290
+فنل مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر
+
+133
+00:12:17,290 --> 00:12:19,310
+مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر
+
+134
+00:12:19,310 --> 00:12:20,190
+مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر
+
+135
+00:12:20,190 --> 00:12:20,190
+مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجبر مجدر مجدر
+
+136
+00:12:20,190 --> 00:12:25,610
+مجدر مجدر مجدر
+
+137
+00:12:25,610 --> 00:12:26,890
+مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر
+
+138
+00:12:26,890 --> 00:12:32,990
+مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر مجدر
+
+139
+00:12:32,990 --> 00:12:35,270
+مجدر
+
+140
+00:12:43,630 --> 00:12:49,690
+وكان السؤال بالشكل القاتى how can you prepare this
+
+141
+00:12:49,690 --> 00:12:57,390
+alcohol from two different compounds يعني بده يعمل
+
+142
+00:12:57,390 --> 00:13:01,010
+مركبين والمركبين معروفين جيدا بالنسبة إلينا كيف
+
+143
+00:13:01,010 --> 00:13:05,930
+بنحضر هذا الكحول من مركبين مختلفين two different
+
+144
+00:13:05,930 --> 00:13:12,390
+ketones الان
+
+145
+00:13:13,490 --> 00:13:17,790
+وحدة قالت ممكن نستعمل هذا ال C double bond O حاملة
+
+146
+00:13:17,790 --> 00:13:24,550
+تنتهي CH3 وحدة حاملة CH3 وحدة فنل C double bond O
+
+147
+00:13:24,550 --> 00:13:33,870
+CH3 و هذه فنل هذا المركب شو اسمه؟ خلينا في اللي
+
+148
+00:13:33,870 --> 00:13:34,630
+بنعرفه
+
+149
+00:13:37,180 --> 00:13:42,240
+اسيتون اسيتون ماحد بيقول عنه provenone واضح؟
+
+150
+00:13:42,240 --> 00:13:47,860
+اسيتون و هذا يلا
+
+151
+00:13:47,860 --> 00:13:53,600
+بتحكوا بعد يومين فين ال C-double bond OCH3؟
+
+152
+00:13:53,600 --> 00:13:58,740
+أسيتوفينونأبشر بطولى سلامة اليوم الرابعه
+
+153
+00:13:58,740 --> 00:14:05,060
+أسيتوفينون إذا هذا أسيتون هذا أسيتوفينون الآن
+
+154
+00:14:05,060 --> 00:14:09,500
+هدولة لما أنا بدي أفعلهم هذه إيش ناقصها مجموعة إيش
+
+155
+00:14:09,500 --> 00:14:19,380
+إذا هاخد فين ال .. MgBr MgBr و هذه إيش ناقصها هاخد
+
+156
+00:14:19,380 --> 00:14:24,600
+CH3 MgBr
+
+157
+00:14:27,780 --> 00:14:32,200
+واضح؟ مجمعتين بدهم يكونوا على الكيتون والتالتة بدي
+
+158
+00:14:32,200 --> 00:14:35,580
+اجيبها من ال green yard و اعملوا اي خلطة انتوا
+
+159
+00:14:35,580 --> 00:14:42,930
+بتكونوا معاها واضحة في هذه النقطة؟إذا مش صعب ان
+
+160
+00:14:42,930 --> 00:14:47,610
+نحضر primary او secondary او tertiary alcohol قطعة
+
+161
+00:14:47,610 --> 00:14:51,670
+من القطع هنجيبها من وين؟ من ال grill yard و الباقي
+
+162
+00:14:51,670 --> 00:14:57,730
+بيكون جزء ال aldehyde او ال ketone اللي هيكون
+
+163
+00:14:57,730 --> 00:14:59,830
+موجود عندنا و نبدأ فيه
+
+164
+00:15:09,860 --> 00:15:14,140
+الان بنجي لنقطة جديدة لكن مرت علينا مش هناخد فيها
+
+165
+00:15:14,140 --> 00:15:18,580
+كتير Oxidation of aldehydes and ketones مر علينا
+
+166
+00:15:18,580 --> 00:15:23,500
+احنا ان ال primary alcohol كانت تتأكسد لايش
+
+167
+00:15:23,500 --> 00:15:26,760
+لالدهيد
+
+168
+00:15:26,760 --> 00:15:30,620
+و اذا استعملنا عامل مؤكسد قوي الالدهيد شو بيصير؟
+
+169
+00:15:30,620 --> 00:15:34,980
+acid خلاص اذا الجزء اللى بدنا يهو ال الديهيد كان
+
+170
+00:15:34,980 --> 00:15:40,260
+بي oxidizeto acids مرت علينا في جزء ال alcohol ولا
+
+171
+00:15:40,260 --> 00:15:44,230
+لأ؟أه كنا نقول الكحول بيصير ال الديهيد و ال
+
+172
+00:15:44,230 --> 00:15:48,050
+الديهيد أسد ال الديهيد أسد هو تفاعل لل الديهيد و
+
+173
+00:15:48,050 --> 00:15:51,610
+الكيتون صارنا عارفينه طيب ال secondary alcohol
+
+174
+00:15:51,610 --> 00:15:56,510
+كانوا يتأكسدوا لإيش لكيتون ال كيتون بتتأكسد أكسدة
+
+175
+00:15:56,510 --> 00:16:00,970
+إضافية لأ إذا هاي الموضوع أكسدت ال الديهيد و
+
+176
+00:16:00,970 --> 00:16:05,130
+الكيتون ان ال الديهيد بيصيروا أسد و الكيتون
+
+177
+00:16:05,130 --> 00:16:11,700
+بتأكسدوش خلصناواضح؟ وكل هذه الفكرة مرت علينا في أي
+
+178
+00:16:11,700 --> 00:16:18,260
+منطقة؟ في منطقة الكحولات كل هذه الفكرة مرت علينا
+
+179
+00:16:18,260 --> 00:16:21,080
+في منطقة الكحولات ليش؟ لأننا كنا نقول primary
+
+180
+00:16:21,080 --> 00:16:25,980
+alcohol، aldehyde acid secondary alcohol، ketone،
+
+181
+00:16:25,980 --> 00:16:31,140
+stop tertiary alcohol من الأساس مافيش أكسة ده،
+
+182
+00:16:31,140 --> 00:16:37,560
+واضح؟الان بنجي الى التفاعل الأخير لل ال الديهايتز
+
+183
+00:16:37,560 --> 00:16:43,200
+والكيتونز اللى هو التفاعل مع مركبات ال نيتروجين مع
+
+184
+00:16:43,200 --> 00:16:48,120
+ال نيتروجين ال يوكليوفايلز طبعا أشهر المركبات اللى
+
+185
+00:16:48,120 --> 00:16:54,760
+هتمر علينا غير الأمونيا الامونيا NH3 تمام؟ الان
+
+186
+00:16:54,760 --> 00:16:58,940
+انا لو أخدت من الأمونيا derivative لو أخدت من
+
+187
+00:16:58,940 --> 00:17:04,990
+الأمونيا derivative هخلى NH2و محل ال H التالتة احط
+
+188
+00:17:04,990 --> 00:17:09,350
+اشي معين خليني اسمي X يعني تطلعوا هذه احدى مشتقات
+
+189
+00:17:09,350 --> 00:17:16,030
+الأمونيا NH2 متصلة بإيش؟ ب X في الأمونيا ال X إيش
+
+190
+00:17:16,030 --> 00:17:23,510
+بتكون؟ Hydrogen الان ممكن ال X تكون مثل إثل ممكن
+
+191
+00:17:23,510 --> 00:17:29,270
+تكون NH2 تانية ممكن تكون R ممكن تكون OH ممكن تكون
+
+192
+00:17:29,270 --> 00:17:36,430
+ARاعتبروها X وكل اشي فيها ال X ممكن بيصير التفاعل
+
+193
+00:17:36,430 --> 00:17:40,830
+تبعنا للناس اللي بدهم يفهموه يقولوا ال X بتضلها
+
+194
+00:17:40,830 --> 00:17:46,970
+إيش؟ X مالنا و مالها كيف ال N H2 بتتفاعل مع ال C
+
+195
+00:17:46,970 --> 00:17:54,610
+double bond O واضح الكلام؟ كيف ال N H2 بتتفاعل مع
+
+196
+00:17:54,610 --> 00:18:00,470
+ال C double bond O الآن ال nitrogen هذاIn UQ5
+
+197
+00:18:00,470 --> 00:18:05,670
+بيحمل زوج إلكترونات وبناء على ذلك لما بنفعله مع C
+
+198
+00:18:05,670 --> 00:18:09,770
+double bond O بده يهاجم عليها هنا و ال C double
+
+199
+00:18:09,770 --> 00:18:16,730
+bond O تصير OH فاللي هيتكون عنده حقيقة بنص الطريق
+
+200
+00:18:16,730 --> 00:18:23,860
+هو المركب القاتل اللي هيكون فيه عنده C Oأتش هنا
+
+201
+00:18:23,860 --> 00:18:33,840
+إيش موجود عندى OH وهنا خلّينا نقول N H متصلة بال X
+
+202
+00:18:33,840 --> 00:18:40,660
+وهنا المجموعتين اللى عندى واضح هذا ال N H المتصلة
+
+203
+00:18:40,660 --> 00:18:45,800
+بال X والمجموعتين اللى عندى واضح ولا لأ ولا أرسمه
+
+204
+00:18:45,800 --> 00:18:50,440
+بالطريقة اللى أنتم متعودين عليهاهذه الكربون متصل
+
+205
+00:18:50,440 --> 00:18:58,320
+فيها مجموعتين هذه شو صارت OH وهنا NHX
+
+206
+00:18:58,320 --> 00:19:06,500
+واضح؟ وهذه كنا نحطها بالأخضر وهذا لليوكليوفايل
+
+207
+00:19:06,500 --> 00:19:12,160
+اللي تم الهجوم عليه الآن هذا التفاعل شو نوعه؟
+
+208
+00:19:13,370 --> 00:19:17,590
+addition reaction هذا تفاعل addition هذا
+
+209
+00:19:17,590 --> 00:19:24,050
+النيوكليوفايل واضح الفكرة ماجيبناش إش جديد الآن في
+
+210
+00:19:24,050 --> 00:19:29,330
+حالة ال nitrogen نيوكليوفايل والان H2 بعد ما بتم
+
+211
+00:19:29,330 --> 00:19:35,610
+هذا ال addition عادة وبشكل تلقائي بتم تفاعل تاني
+
+212
+00:19:35,970 --> 00:19:38,950
+ولذلك الناتج ما بيقفش عند ال addition يعني لو
+
+213
+00:19:38,950 --> 00:19:43,430
+الناتج بيقف عند ال addition الأمر بصير بتم تفاعل
+
+214
+00:19:43,430 --> 00:19:48,390
+تاني تلقائي هذا التفاعل التاني التلقائي في عندكم
+
+215
+00:19:48,390 --> 00:19:53,590
+هنا OH وفي عندنا هنا جنبها على الذرة المجاورة هدول
+
+216
+00:19:53,590 --> 00:19:57,890
+ذرتين متجاورتين carbon و nitrogen صح؟ على ال
+
+217
+00:19:57,890 --> 00:20:04,150
+carbon عندكم OH وعلى ال nitrogen H الآن بتم حذفال
+
+218
+00:20:04,150 --> 00:20:11,990
+OH مع ال H على شكل جزيء ماء هاي ال OH هذه مع ال H
+
+219
+00:20:11,990 --> 00:20:14,910
+اللي هنا ع شكل جزيء ماء لما بدوا ينحفوا شو بدوا
+
+220
+00:20:14,910 --> 00:20:21,430
+يصير مكانهم double bond هاني شلتم شلتم شلتم ايش
+
+221
+00:20:21,430 --> 00:20:28,990
+بده احط مكانهم double bondواضح؟ إذا بعد ال
+
+222
+00:20:28,990 --> 00:20:34,170
+addition صار عندي تفاعل elimination وعشان هيك
+
+223
+00:20:34,170 --> 00:20:38,690
+العنوان اللي عندكم كان إيش addition elimination
+
+224
+00:20:38,690 --> 00:20:42,510
+reactions of aldehydes and ketones هذه مع أي
+
+225
+00:20:42,510 --> 00:20:49,330
+مركبات بتصير؟مع الان H2 اللى متصل فيها أي X كانت
+
+226
+00:20:49,330 --> 00:20:54,930
+الان بيجي السؤال من ناحية السهولة هل يا ترى كل مرة
+
+227
+00:20:54,930 --> 00:21:00,380
+عشان نكتب الجواب الصحبدنا نقعد نتخيل الحالة
+
+228
+00:21:00,380 --> 00:21:04,520
+الوسيطة ونقول تمت الإضافة ونرسم الناتج وبعدين بتم
+
+229
+00:21:04,520 --> 00:21:08,980
+الحدف و تاخدوا خمس دقائق وانتوا تكتبوا الجواب لأ
+
+230
+00:21:08,980 --> 00:21:13,960
+بإمكاننا من ناحية تطبيقية نعمل الأمر بطريقة سهلة
+
+231
+00:21:13,960 --> 00:21:19,080
+جداالأمر بطريقة سهلة جدا اللي بيشمل العمليتين انه
+
+232
+00:21:19,080 --> 00:21:23,600
+دائما تخيلوا C double bond O والان H2 جايين بهذا
+
+233
+00:21:23,600 --> 00:21:27,980
+الشكل الان خلوها تصير C double bond N لاحظوا ايش
+
+234
+00:21:27,980 --> 00:21:37,060
+انا حدفت H2O فخلو بدل ما مكتوب عندكم C double bond
+
+235
+00:21:37,060 --> 00:21:43,480
+O خلوها C double bond N والان متصلة ب Xإذا هذا
+
+236
+00:21:43,480 --> 00:21:49,020
+التفاعل صار أسهل تفاعل فيهم نتيجته النهائية أنه في
+
+237
+00:21:49,020 --> 00:21:54,000
+التفاعل مع ال N H2 بدل ما كان عنده C double bond O
+
+238
+00:21:54,000 --> 00:22:02,360
+بتصير C double bond N واضحة الفكرة و ال N بأي X
+
+239
+00:22:02,360 --> 00:22:07,580
+متصلة يعتبر موضوع بسيط بس كنتيجة أنه C double bond
+
+240
+00:22:07,580 --> 00:22:15,640
+O بتصير C double bond Nأبتدت أن نكون كفكرة إلتهينا
+
+241
+00:22:15,640 --> 00:22:22,020
+من هذه التفاعلات ولكن الآن نريد أن نعرف أسماء
+
+242
+00:22:22,020 --> 00:22:27,970
+الأشياء التي تتفاعل عادةأو بمعنى آخر خلّينا نقول
+
+243
+00:22:27,970 --> 00:22:32,710
+نعطي أمثلة على ال X إيش ممكن تكون ال X واضحة
+
+244
+00:22:32,710 --> 00:22:37,950
+الفكرة؟ إيش ممكن تكون ال X؟ الآن هذه عندي دائما و
+
+245
+00:22:37,950 --> 00:22:42,270
+أبدا unatched two نتفق ال unatched two نحطها وين؟
+
+246
+00:22:44,150 --> 00:22:48,970
+بمربع أخضر هذه اللي فاهمين هي ال N H 2 ال N متصلة
+
+247
+00:22:48,970 --> 00:22:55,090
+ب X ال X في هذا المثال شو هي N H 2 تانية ال N هذي
+
+248
+00:22:55,090 --> 00:22:58,950
+ال N H 2 اللي متصلة ب N H 2 تانية المركب بسميه
+
+249
+00:22:58,950 --> 00:23:06,810
+هيدرازين okay هيدرازين طيب لو ال N H 2 تانية كانت
+
+250
+00:23:06,810 --> 00:23:14,290
+متصلة ب N H phenyl يعني ال X عبارة عن إيش؟ان اتش
+
+251
+00:23:14,290 --> 00:23:20,770
+فينيل هذي ال X كلها واضح بيصير اسمه فينيل هيدرازيل
+
+252
+00:23:22,460 --> 00:23:26,180
+أكيد هدول فيش نقاش انه كل اشي اللي انا بدي احكيه
+
+253
+00:23:26,180 --> 00:23:32,400
+بده ينحفظ بالظبط فينل هيدرازين طيب هذه ال N-H2
+
+254
+00:23:32,400 --> 00:23:37,320
+نفسها لو اتصلت ب N-H حاملة فينل وعالفينل على نمره
+
+255
+00:23:37,320 --> 00:23:42,120
+واحد اتنين تلاتة اربعة نيترو نايترو شو هنيجي
+
+256
+00:23:42,120 --> 00:23:51,480
+نسميه؟ two four dinitro فينل هيدرازين واضح؟
+
+257
+00:23:53,580 --> 00:23:58,160
+Two for dinitrophin الهيدرازين الان لو جيبنا لأي
+
+258
+00:23:58,160 --> 00:24:02,760
+واحد من هدول هذا او هذا او هذا كيتون C double bond
+
+259
+00:24:02,760 --> 00:24:06,480
+O وقلنا بدنا نكمل المعادلة احنا و احنا مغمضين
+
+260
+00:24:06,480 --> 00:24:12,720
+متعودين ان هال C double bond O تصير C double bond
+
+261
+00:24:12,720 --> 00:24:18,210
+N خلص الجوابالـ C double bond O بتصير C double
+
+262
+00:24:18,210 --> 00:24:22,370
+bond N و بنحدث الـ H طوله طيب الآن لما اتكون هذا
+
+263
+00:24:22,370 --> 00:24:30,250
+المركب عندى هذا نتج من تفاعل الديهيد او كيتون
+
+264
+00:24:30,250 --> 00:24:39,130
+الديهيد او كيتون يعني انا حاطينهم بصيغة ايش R يعني
+
+265
+00:24:39,130 --> 00:24:43,470
+ممكن تكون H و H H و مثل مثل و مثل اثل و اثل
+
+266
+00:24:44,950 --> 00:24:50,250
+أتشوفينيل مثلوفينيل كل احتمالات واردة الان المركب
+
+267
+00:24:50,250 --> 00:24:53,070
+اللى بيلتج عندى اللى فيه ال c double bond او الان
+
+268
+00:24:53,070 --> 00:24:57,330
+ايش بدي اسميه بسمي اسم ال الديهايد او ال كيتون
+
+269
+00:24:57,330 --> 00:25:03,870
+اللى كوّنه و بحط النهاية اسم هذا لكن بدل ما اقول
+
+270
+00:25:03,870 --> 00:25:09,970
+in بقول on يعني لو كان متفاعل مع NH2 و NH2 بسميه
+
+271
+00:25:09,970 --> 00:25:13,510
+الديهايد او كيتون هيدرازون
+
+272
+00:25:14,360 --> 00:25:20,800
+لو مع هذا فينيل هيدرازون لو مع هذا two four
+
+273
+00:25:20,800 --> 00:25:26,220
+dinitrophenylheidrazone فالنتج مااخد نفس الاسم لكن
+
+274
+00:25:26,220 --> 00:25:36,360
+بنهاية on بدل نهاية in خلينا الان نشوفه بامثلة
+
+275
+00:25:36,360 --> 00:25:41,450
+اكتر يعني بدون ال R و ال Rبأمثلة اقصوا بريد جيجا
+
+276
+00:25:41,450 --> 00:25:45,090
+اقصوا بريد جيجا الأمثلة بتوضح حالها لحالها اقصوا
+
+277
+00:25:45,090 --> 00:25:49,110
+بريد جيجا ان الله يحبه الصابرين والصابرات كمان
+
+278
+00:25:49,110 --> 00:25:59,990
+ربنا بيحبهم يعني
+
+279
+00:25:59,990 --> 00:26:09,310
+لو اجينا هنا حقينا هذه CH3 CH3 هذا المركب شو اسمه
+
+280
+00:26:12,370 --> 00:26:19,830
+اسيتون وهذا هيدرازين
+
+281
+00:26:19,830 --> 00:26:27,190
+الان المركب اللي نشأ منهم شو بدي اسميه اسيتون
+
+282
+00:26:27,190 --> 00:26:35,630
+هيدرازون مش هيدرازين بيصيروا التانين مع بعض اسيتون
+
+283
+00:26:35,630 --> 00:26:39,510
+هيدرازون
+
+284
+00:26:40,980 --> 00:26:47,800
+و بناء على ذلك بنقدر نستنتج استنتاج بسيط جدا ان ال
+
+285
+00:26:47,800 --> 00:26:53,480
+hydrazines بيصيروا hydrazones طب ناخد مثال تاني
+
+286
+00:26:53,480 --> 00:26:58,960
+خلينا نحط هنا H ونحط هنا phenyl في الناتج ايش
+
+287
+00:26:58,960 --> 00:27:07,380
+هيكون عندي هنا H و phenylلو قولنا لواحدة سمينا ال
+
+288
+00:27:07,380 --> 00:27:14,520
+الديهيد او ال كيتون سمي هذا سمي الناتج واضحة
+
+289
+00:27:14,520 --> 00:27:18,560
+الفكرة؟ اتفضلي ايش هذا بنسميه؟ فينيل C double bond
+
+290
+00:27:18,560 --> 00:27:23,940
+OH فينيل
+
+291
+00:27:23,940 --> 00:27:29,200
+C double bond OH ايش اسمه؟ الاسيتوفينون اللي فيه
+
+292
+00:27:29,200 --> 00:27:30,080
+CH3
+
+293
+00:27:42,220 --> 00:27:48,360
+بنزالدهيد بنزالدهيد بنزالدهيد
+
+294
+00:27:48,360 --> 00:27:56,880
+ممتازة الآن هذا إيش اسمه؟
+
+295
+00:27:56,880 --> 00:28:02,180
+أخدناله اسم قبل شوية فنل هيدرازين
+
+296
+00:28:04,140 --> 00:28:13,040
+فنل هيدرازين فنل هيدرازين الآن الناتج اللي ناتج من
+
+297
+00:28:13,040 --> 00:28:18,680
+التنين ايش هيكون اسمه بنز الديهيد فنل هيدرازون بنز
+
+298
+00:28:18,680 --> 00:28:24,920
+الديهيد فنل هيدرازون هاي جزء بنز الديهيد وفنل
+
+299
+00:28:24,920 --> 00:28:31,840
+هيدرازون بنز الديهيد فنل
+
+300
+00:28:33,320 --> 00:28:38,180
+هيدرازون بدل ما كان الاسم عندى oen بدو يصير ايش
+
+301
+00:28:38,180 --> 00:28:42,300
+بنزالديهيدفينالهيدرازون
+
+302
+00:28:42,300 --> 00:28:45,860
+بنزالديهيدفينالهيدرازون
+
+303
+00:28:45,860 --> 00:28:47,920
+الان
+
+304
+00:29:00,620 --> 00:29:06,560
+لو مثلا اجينا وقلنالكوا لو سمحتوا نختبركوا شطرين
+
+305
+00:29:06,560 --> 00:29:12,280
+ولا لا ارسمولنا Cyclohexanone 2,4
+
+306
+00:29:12,280 --> 00:29:22,440
+-dinitrophenylhydrazone هيك ايجاكم Cyclohexanone
+
+307
+00:29:22,440 --> 00:29:29,520
+2,4-dinitrophenyl
+
+308
+00:29:33,300 --> 00:29:39,480
+هيدرازون كل هذا اسم بني آدم مؤدب بدنا نور اسمه
+
+309
+00:29:39,480 --> 00:29:46,380
+السياسة العامة cut and conquer فرق تسد جزقوها ال
+
+310
+00:29:46,380 --> 00:29:52,100
+Cyclohexanone أصلا
+
+311
+00:29:52,100 --> 00:29:58,980
+كان زي هيك CWO بس احنا عرفنا بعد العقلة ال CWO إيش
+
+312
+00:29:58,980 --> 00:30:05,270
+بتصير؟C double bond N هاي حطينا ال N لما نكمل ال 2
+
+313
+00:30:05,270 --> 00:30:12,250
+,4-dinitrophenylhydrazone بدنا نحط N H حاملة فنل
+
+314
+00:30:12,250 --> 00:30:23,190
+وعلى موقع 2 بالفنل N O 2 و N O 2 طبعا اللي بتدرب
+
+315
+00:30:23,190 --> 00:30:27,710
+عليهم بيتقنهم هاي Cyclohexanone 2,4
+
+316
+00:30:27,710 --> 00:30:29,830
+-dinitrophenylhydrazone
+
+317
+00:30:34,850 --> 00:30:58,890
+واضحة الفكرة طيب
+
+318
+00:30:58,890 --> 00:31:05,400
+لو كان السؤالعشان تشوفوا العلم مبني على بعضه
+
+319
+00:31:05,400 --> 00:31:14,440
+ارسموا Cyclohexane Carb Aldehyde Hydrazol خلصنا
+
+320
+00:31:14,440 --> 00:31:23,540
+من هذا؟ Cyclohexane
+
+321
+00:31:23,540 --> 00:31:31,800
+Carb Aldehyde Cyclohexane Carb Aldehyde
+
+322
+00:31:36,170 --> 00:31:41,950
+Hydrazone كلمة واحدة
+
+323
+00:31:41,950 --> 00:31:47,490
+طبعا اللي بتعرفش ال Cyclohexane لحاله ولو بتعرفش
+
+324
+00:31:47,490 --> 00:31:51,370
+ال Hydrazone لحاله مش هترسم طبعا هذا Cyclohexane
+
+325
+00:31:51,370 --> 00:31:55,950
+إيش؟ Carb Aldehyde كلكوا لازم تكونوا متذكرين أنه
+
+326
+00:31:55,950 --> 00:32:00,410
+إحنا لما حكينا عن ال aldehydes مع الحلقة قلنا ال
+
+327
+00:32:00,410 --> 00:32:07,610
+aldehyde بيكون معلق تعليج على الحلقةيعني الـ
+
+328
+00:32:07,610 --> 00:32:11,010
+Cyclohexane كربلديهيد لو قلب لحاله زي هيك وهذه C
+
+329
+00:32:11,010 --> 00:32:16,750
+double bond O الأن لما تصير Hydrazone هتصير C
+
+330
+00:32:16,750 --> 00:32:21,530
+double bond N ولما يكون .. بس كلمة Hydrazone لحاله
+
+331
+00:32:21,530 --> 00:32:27,890
+بدون ولا إشي تاني N H 2 لو كانت فين ال Hydrazone؟
+
+332
+00:32:27,890 --> 00:32:33,940
+بدي أحط فين ال .. طب لو قلتلكوا مثل Hydrazoneهتمثل
+
+333
+00:32:33,940 --> 00:32:39,440
+لو قولت اتل هيدرازون اتل لو قولت أسيتل هيدرازون
+
+334
+00:32:39,440 --> 00:32:46,480
+أسيتل حد مايعرفش الأسيتل C double bond O CH3 Form
+
+335
+00:32:46,480 --> 00:32:53,940
+الهيدرازون C double bond O H3 و هكذا واضحة الفكرة
+
+336
+00:32:53,940 --> 00:33:00,930
+يعني اتعمقنا كتير كتير زيادة في الموضوع الآنطيب
+
+337
+00:33:00,930 --> 00:33:06,650
+ناخد مشتقة تانية ناخد مشتقة تانية لو يا تورا
+
+338
+00:33:06,650 --> 00:33:12,430
+ماكانش عندى مع ال N H2 N H2 تانية لو كان عندى O H
+
+339
+00:33:12,430 --> 00:33:19,710
+لاحظوا هى عندى ال N H2 بس ايش ال X اللى هنا O H
+
+340
+00:33:19,710 --> 00:33:23,330
+هذا بنسمي Hydroxylamine
+
+341
+00:33:24,660 --> 00:33:30,340
+ماذا نسميه؟ هيدروكسل أمين هي الهيدروكسل وهي الأمين
+
+342
+00:33:30,340 --> 00:33:33,420
+لما بده يتفاعل ال C double bond اوه بتحصل في
+
+343
+00:33:33,420 --> 00:33:39,280
+النهاية C double bond L لما بدنا نسمي المركب بدنا
+
+344
+00:33:39,280 --> 00:33:45,300
+نقول ال الديهيد او ال كيتون والان
+
+345
+00:33:45,300 --> 00:33:49,460
+على هذا الجزء بنكتب كلمة واحدة أكزيم
+
+346
+00:33:51,630 --> 00:33:56,990
+يعني ال c double volt n o h ايش بنسميها اكزيم
+
+347
+00:33:56,990 --> 00:34:01,850
+اكزيم الان
+
+348
+00:34:01,850 --> 00:34:12,490
+واحدة
+
+349
+00:34:12,490 --> 00:34:19,470
+تقول اي جانا هذا في الامتحان رسمه أسيتوفينون اكزيم
+
+350
+00:34:20,940 --> 00:34:27,060
+اللي بدي يرسم بدي يقول هاي ال Acetophenon فينل و
+
+351
+00:34:27,060 --> 00:34:34,200
+CH3 و متصل بـ C double bond O أصلا عشان يكون
+
+352
+00:34:34,200 --> 00:34:41,680
+Acetophenon الأهم لما يصير أكزيم NOH و مثل و
+
+353
+00:34:41,680 --> 00:34:44,420
+Cyclohexanone أكزيم و Cyclopentanone أكزيم و كل
+
+354
+00:34:44,420 --> 00:34:51,160
+الأكزيمات إذا العملية سهلة ولا مش سهلةهنا أخدنا
+
+355
+00:34:51,160 --> 00:35:01,640
+مشتقة الهيدرازون ومشتقة الأكزيم طب
+
+356
+00:35:01,640 --> 00:35:07,560
+لو كانت هذه R يعني مثل ولا إثل؟ ايش بدي يكون
+
+357
+00:35:07,560 --> 00:35:13,000
+الجواب؟ R مثل أو إثل كعائلة بيسموها shift base
+
+358
+00:35:13,000 --> 00:35:20,500
+نتغلب أكتر بالاسماء تبعتها الآن بيضل عندىكل هدولة
+
+359
+00:35:20,500 --> 00:35:25,040
+موجودين يمكن ضلت عندي شغلة واحدة اخرى لو كانت هذه
+
+360
+00:35:25,040 --> 00:35:36,420
+unh2 unh c double bond o unh2 هذا مركب شوية ايش
+
+361
+00:35:36,420 --> 00:35:41,840
+ماله كبير لكن انا المهم عندي فيه ان هذه ال unh2 كل
+
+362
+00:35:41,840 --> 00:35:46,700
+هدولة يعتبروا x واحدة هتقول في تلتين unh2 في واحدة
+
+363
+00:35:46,700 --> 00:35:51,420
+هنا اقريبة على c double bond o واحدةبعيدة مين اللي
+
+364
+00:35:51,420 --> 00:35:55,140
+بتتفعل مع الالدهاد او الـ Ketone؟ هذه البعيدة
+
+365
+00:35:55,140 --> 00:35:58,060
+وبناء على ذلك لو هذا قلتلكوا فعلومة عن
+
+366
+00:35:58,060 --> 00:36:05,700
+الـcyclobentanone كيف هنكتب الجواب؟ زي ما اتعودنا
+
+367
+00:36:05,700 --> 00:36:09,960
+تماما، نحط الـcyclobentane
+
+368
+00:36:09,960 --> 00:36:17,540
+والسيضة بالبند او تصير سيضة بالبند and ونكمل
+
+369
+00:36:19,990 --> 00:36:26,670
+MHCW.O NH2 بيصير .. طب إيش اسم هذا و إيش اسم هذا
+
+370
+00:36:26,670 --> 00:36:37,450
+هذا اسمه سيمي كربازايد سيمي كربازايد طب و الناتج
+
+371
+00:36:37,450 --> 00:36:43,690
+اللي بتطلع من السيمي كربازايدSemi-carbazone زي
+
+372
+00:36:43,690 --> 00:36:49,210
+هيدرازين هيدرازون Carbazide Carbazone إذا هذا
+
+373
+00:36:49,210 --> 00:36:54,610
+المركب كاملا الأن لو بدنا نسميه شو هنسميه؟
+
+374
+00:36:54,610 --> 00:37:00,450
+Cyclobentanone
+
+375
+00:37:00,450 --> 00:37:05,110
+Semi-carbazone
+
+376
+00:37:07,490 --> 00:37:17,290
+cyclobentanone-semicarbazone هذا
+
+377
+00:37:17,290 --> 00:37:29,310
+هو
+
+378
+00:37:29,310 --> 00:37:30,930
+ال slide الأخير
+
+379
+00:37:34,700 --> 00:37:41,500
+بتلخص لي كل الدارس انه ال amine اللي هو متصل في ال
+
+380
+00:37:41,500 --> 00:37:47,980
+NH2R بيعطي كعائلة عامة امين ال hydroxylamine بيعطي
+
+381
+00:37:47,980 --> 00:37:54,160
+oxime ال semi carbazide بيعطي semi carbazone ال
+
+382
+00:37:54,160 --> 00:38:00,880
+hydrazines بيعطي hydrazones واضح؟ مرة تانية نعيدهم
+
+383
+00:38:00,880 --> 00:38:08,150
+مع بعض ال hydrazineوالهيدروكس الأمين أكزيم والسمي
+
+384
+00:38:08,150 --> 00:38:13,650
+كربازايد سيمي كربازون والأمين اللي هي متصلة بR
+
+385
+00:38:13,650 --> 00:38:22,570
+امين امين بس واضح لو نعطي مثال ولا نقول الله
+
+386
+00:38:22,570 --> 00:38:27,630
+يعطيكوا العافية بنعطي مثلين بنعطي مثلين و بنخلص
+
+387
+00:38:27,630 --> 00:38:33,870
+اليوم إجاكم سؤال أرسموا إيثانال أكزيم
+
+388
+00:38:35,520 --> 00:38:48,140
+وإجانا السؤال ارسمه داي إثل كيتون فين الهيدرازون
+
+389
+00:38:48,140 --> 00:38:54,420
+يلا
+
+390
+00:38:54,420 --> 00:39:06,030
+نجلوني إيثانال عارفين الإيثانال؟اللي هو CHCH3
+
+391
+00:39:06,030 --> 00:39:11,410
+اللي هو ال Acetaldehyde وهذه كانت C double bond O
+
+392
+00:39:11,410 --> 00:39:16,310
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+393
+00:39:16,310 --> 00:39:16,790
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+394
+00:39:16,790 --> 00:39:16,810
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+395
+00:39:16,810 --> 00:39:18,510
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+396
+00:39:18,510 --> 00:39:18,890
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+397
+00:39:18,890 --> 00:39:18,890
+ان او اتش ان او اتش ان او اتش ان او اتش ان او اتش
+
+398
+00:39:18,890 --> 00:39:26,070
+ان او اتش ان او اتش ان او اتش ان
+
+399
+00:39:26,070 --> 00:39:30,520
+اهو الـ 3-bentanone هو داي إثل كيتون إيش بده أحط؟
+
+400
+00:39:30,520 --> 00:39:35,700
+هاي الـ ketone C double bond O وهي مجموعة إثل وهي
+
+401
+00:39:35,700 --> 00:39:41,940
+مجموعة إثل مش CH2 CH3 إثل CH2 CH3 إثل داي إثل
+
+402
+00:39:41,940 --> 00:39:48,960
+كيتون الآن بده منه فين
+
+403
+00:39:48,960 --> 00:39:53,100
+الهيدرازون؟ أكيد هيكون
+
+404
+00:40:03,390 --> 00:40:07,770
+طبعا أنا بتوقعش ان كل إشي هتكون أتقنطوه لان لكن في
+
+405
+00:40:07,770 --> 00:40:11,290
+المحاضرة اللي جاية لما تتدربوا و ال organic تدريب
+
+406
+00:40:11,290 --> 00:40:16,110
+و كتابة أكيد ان شاء الله كل شيء بتتقنوه بهيك
+
+407
+00:40:16,110 --> 00:40:21,010
+بننتهي من درس ال aldehydes و ال ketones و ان شاء
+
+408
+00:40:21,010 --> 00:40:27,060
+الله يوم السبتفي عندنا مراجعة للامتحانات النصفية
+
+409
+00:40:27,060 --> 00:40:31,420
+كونوا مجاهزينها او ساحبينها ع ورق و حلينها احنا
+
+410
+00:40:31,420 --> 00:40:36,000
+بنحلها انا قدامكم و بنناقش اي مشكلة فيها و بعد هيك
+
+411
+00:40:36,000 --> 00:40:39,380
+ان شاء الله بنبدأ في موضوع الأحماض و مستقبلها و
+
+412
+00:40:39,380 --> 00:40:45,260
+الامتحان لنهاية الفصل السادس حكينا بوضوح الامتحان
+
+413
+00:40:45,260 --> 00:40:47,980
+لنهاية الفصل السادس اذا سمحت
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..96706e81a5bccd271205b0808ba9abc29ebba8e0
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tPLixEuHFSU_raw.srt
@@ -0,0 +1,2084 @@
+1
+00:00:20,690 --> 00:00:23,670
+بسم الله الرحمن الرحيم، في موضوع الـ
+
+2
+00:00:23,670 --> 00:00:27,290
+Stereochemistry، آخر شغلة أتكلمنا عنها
+
+3
+00:00:30,440 --> 00:00:36,360
+كانت موضوع الخواص الفيزيائية ربما لل enantiomers
+
+4
+00:00:36,360 --> 00:00:41,000
+وقولنا ان ال enantiomers بيشتركوا في كل الخواص
+
+5
+00:00:41,000 --> 00:00:47,360
+الفيزيائية ما عدا خاصية ال rotation of polarized
+
+6
+00:00:47,360 --> 00:00:53,460
+light تدوير الضوء المستخدم في المستوى طبعا شرحنا
+
+7
+00:00:54,200 --> 00:00:59,300
+بشكل مبسط جهاز ال بولاريميتر وقلنا لو في عندنا two
+
+8
+00:00:59,300 --> 00:01:03,760
+انان شمارز حاطناهم في مسار الضوء تبع ال بولاريميتر
+
+9
+00:01:03,760 --> 00:01:09,780
+نفس الكمية واحد هيلف الضوء لليمين هيكون المركب
+
+10
+00:01:09,780 --> 00:01:14,630
+dextrorotatory أو positive التاني هيلف للشمالعشان
+
+11
+00:01:14,630 --> 00:01:18,610
+نتخلص من فكرة اننا نضل نقول حطينا نفس الكمية
+
+12
+00:01:18,610 --> 00:01:23,630
+اعرفنا شئ سمناه الدوران النوعى او ال specific
+
+13
+00:01:23,630 --> 00:01:27,770
+rotation ال specific rotation بمنطق الخواص بمنطق
+
+14
+00:01:27,770 --> 00:01:31,890
+الخواص هو عبارة عن intensive probability بمنطق
+
+15
+00:01:31,890 --> 00:01:34,750
+الخواص هو عبارة عن intensive probability يعني
+
+16
+00:01:34,750 --> 00:01:40,660
+المركب الواحد لهspecific rotation واحد ولذلك ربما
+
+17
+00:01:40,660 --> 00:01:46,980
+اعطناكوا homework وقلنا لكم شوفولنا مثلا ال R2
+
+18
+00:01:46,980 --> 00:01:53,240
+butanol قداش الزاوية تبعته هذه الزاوية بتكون عبارة
+
+19
+00:01:53,240 --> 00:01:57,840
+عن شئ تجريبي ماعرفش في ناس جدروا يصلوا لهذه
+
+20
+00:01:57,840 --> 00:01:58,380
+الزاوية
+
+21
+00:02:00,890 --> 00:02:10,130
+الان تلتعش وتسعة سالب ولا موجب الان
+
+22
+00:02:10,130 --> 00:02:15,490
+وضحتلكوا انا لاحظوا يعني بكل وضوح قلتلكم اللي
+
+23
+00:02:15,490 --> 00:02:21,770
+بيعرف اللي بيعرف زاوية بيعرف التانية يعني اذا انا
+
+24
+00:02:21,770 --> 00:02:29,220
+كنت معطيكم في الواجبزاوية المُركّب الـR فتحته النت
+
+25
+00:02:29,220 --> 00:02:35,360
+وجدت الـS-13 وكذا إذا الـR هتكون الـPlus العكس
+
+26
+00:02:35,360 --> 00:02:42,380
+واضح؟ وانتهى على
+
+27
+00:02:42,380 --> 00:02:52,800
+أي حال فتش ربما بشكل أداء ليش؟
+
+28
+00:02:54,350 --> 00:02:59,050
+معنى ذلك اتقانكوا لعملية البحث .. اتقانكوا لعملية
+
+29
+00:02:59,050 --> 00:03:03,930
+البحث ضعيف يعني انا بهمني ان انتوا تتعبوا انا
+
+30
+00:03:03,930 --> 00:03:08,750
+بهمني في النهاية ان انتوا .. ان انتوا تتعبوا يعني
+
+31
+00:03:08,750 --> 00:03:13,270
+ان اقولكوا specific rotation ل ال tube eutanol و
+
+32
+00:03:13,270 --> 00:03:19,170
+تقولوا اتغلبنا معنى ذلك ما تقلتوشممكن في عصر
+
+33
+00:03:19,170 --> 00:03:23,210
+المعلومات ناس مايقدروش يطولوا ل specific rotation
+
+34
+00:03:23,210 --> 00:03:28,090
+لتو بيوتانول او لتو كلورو بيوتانول هذه معلومة
+
+35
+00:03:28,090 --> 00:03:32,690
+ثابتة زي ما اجي اقولكم تماما ايش نقطة الغليان ايش
+
+36
+00:03:32,690 --> 00:03:36,410
+نقطة الانصحار ايش نقطة كده كل هذه المعلومات
+
+37
+00:03:36,410 --> 00:03:41,970
+معلومات متوفرة وموجودة على ال net مش ممكن الا انكم
+
+38
+00:03:41,970 --> 00:03:49,720
+تطولوها تمام بكل الأحوال لما اللاجئلأيزومر معين ل
+
+39
+00:03:49,720 --> 00:03:53,920
+specific rotation كأنه انا عندى لأيزومر التانى
+
+40
+00:03:53,920 --> 00:03:58,760
+مباشرة يعني لما يكون واحد موجب بمقدار معين التانى
+
+41
+00:03:58,760 --> 00:04:05,060
+بيكون سالب بنفس المقدار الان لاحظوا معايا لو حطينا
+
+42
+00:04:05,060 --> 00:04:10,150
+المركب الموجبأو أحد ال enantiomers في البولاريميتر
+
+43
+00:04:10,150 --> 00:04:15,350
+بلوف ايش؟ الضوء هذا الجزء اللي بلوف الضوء الآن
+
+44
+00:04:15,350 --> 00:04:21,830
+بنقول عنه مصطلح chiral molecule هنا كنت بنتبه ان
+
+45
+00:04:21,830 --> 00:04:26,970
+انا استعمل كلمة chiral مرتين مرة لما انا حكيت عن
+
+46
+00:04:26,970 --> 00:04:31,330
+chiral carbonالكايرال كاربون هي الكاربون اللي
+
+47
+00:04:31,330 --> 00:04:36,170
+عليها أربع مجموعات مختلفة لما بحكي عن كايرال
+
+48
+00:04:36,170 --> 00:04:41,230
+موليكيول الكايرال موليكيول هو الجزير اللي بيعمل
+
+49
+00:04:41,230 --> 00:04:45,750
+دوران للضوء إذا هو أحد ال enantiomersلما بيوجد
+
+50
+00:04:45,750 --> 00:04:50,890
+لحاله نحط احنا احد المركبات في مسار الضوء يعمل
+
+51
+00:04:50,890 --> 00:04:55,530
+دوران للضوء بنقول هذا المركب كايرال موليكيول
+
+52
+00:04:55,530 --> 00:04:58,750
+فالكايرال موليكيول هو اللي بيعمل دوران للضوء الآن
+
+53
+00:04:58,750 --> 00:05:02,370
+طالما انه دخل الضوء فيه وعمله دوران بنقول عنه
+
+54
+00:05:02,370 --> 00:05:06,610
+optically active يعني بدل ما نستعمل مصطلح بيعمل
+
+55
+00:05:06,610 --> 00:05:10,390
+دوران للضوء بنقول optically active فمعنى كلمة
+
+56
+00:05:10,390 --> 00:05:19,400
+optically active it rotateslight هو بيلف ايش؟ بيلف
+
+57
+00:05:19,400 --> 00:05:23,320
+في الضوء سواء لف الضوء شمال او لف الضوء يمين هو
+
+58
+00:05:23,320 --> 00:05:27,020
+بيكون ايش؟ optically active لاحظوا معي ايش
+
+59
+00:05:27,020 --> 00:05:31,700
+المركبات اللي بتكون optically inactive المركبات
+
+60
+00:05:31,700 --> 00:05:35,720
+اللي مافيش فيها كل هذه الظاهرة مابديش انا انسى ان
+
+61
+00:05:35,720 --> 00:05:38,980
+بداية ظاهرة ال enantiomers كانت بتتطلب كايرال
+
+62
+00:05:38,980 --> 00:05:44,880
+كاربونعشان يصير من المركب اتنين ROS و بعدين واحد
+
+63
+00:05:44,880 --> 00:05:49,040
+منهم موجب واحد سالب كان بتطلب كيرال كاربون طب لو
+
+64
+00:05:49,040 --> 00:05:52,980
+انا حاطيت مركب زي على سبيل المثال ال carbon
+
+65
+00:05:52,980 --> 00:05:54,040
+tetrachloride
+
+66
+00:05:56,090 --> 00:06:01,350
+هل هذا يا ترى باربع ذرات متشابهة في كايرال كاربون؟
+
+67
+00:06:01,350 --> 00:06:05,850
+في منه اتنين؟ مافيش منه غير واحد، اذا هذا لو انا
+
+68
+00:06:05,850 --> 00:06:09,350
+حاطيته بمسار الضوء، بيكون optically active ولا
+
+69
+00:06:09,350 --> 00:06:14,170
+inactive؟ inactive، لو انا حاطيت ميه في مسار الضوء
+
+70
+00:06:15,320 --> 00:06:19,260
+بكون Optically Active ولا Inactive؟ Inactive لو
+
+71
+00:06:19,260 --> 00:06:25,280
+انا حطيت مثلا Dichloromethane CH2 Cl2 بكون
+
+72
+00:06:25,280 --> 00:06:29,960
+Optically Active ولا Inactive؟ Inactive لأنه عشان
+
+73
+00:06:29,960 --> 00:06:33,920
+يبدأ يصير أحد ال enantiomers في وجود chiral center
+
+74
+00:06:33,920 --> 00:06:37,960
+واحد المفروض يكون عندى أربع مجموعات مختلفة فخلينا
+
+75
+00:06:37,960 --> 00:06:43,840
+نقول انه نسبة كبيرة جدا من المراكبات العضوية أساسا
+
+76
+00:06:44,940 --> 00:06:50,300
+بتكون A chiral لاحظوا معاه هنا بنيجي لنقطة كتير
+
+77
+00:06:50,300 --> 00:06:55,220
+مهمة لما وصفنا مركب انه chiral بمعنى هو أحد
+
+78
+00:06:56,430 --> 00:07:01,010
+الإنانشومارز يعني كلمة chiral بتكون لما بيكون عندى
+
+79
+00:07:01,010 --> 00:07:05,730
+two enanchomars هذا المركب لو حاطيته لحاله بقول
+
+80
+00:07:05,730 --> 00:07:10,650
+عنه chiral بلف الضوء بزاوية معينة الآن ال
+
+81
+00:07:10,650 --> 00:07:14,530
+enanchomar التاني لو حاطيته في ال polarimeter برضه
+
+82
+00:07:14,530 --> 00:07:20,900
+chiral بنسميه بلف الضوء ولكن باتجاهمعاكس إذا صار
+
+83
+00:07:20,900 --> 00:07:24,840
+عندى مركب chiral و مركب chiral طيب لو حطيت مركب من
+
+84
+00:07:24,840 --> 00:07:28,660
+الأساس مافيه chiral center بلفش الضوء وجدت إيش بدى
+
+85
+00:07:28,660 --> 00:07:34,840
+أسمي هذا المركب A chiral هنا ال A بتصير أداة نفي
+
+86
+00:07:34,840 --> 00:07:38,840
+لاحظوا معناه .. لاحظوا معناه بتكونوا فاهمين شوية
+
+87
+00:07:38,840 --> 00:07:44,420
+باللغة الإنجليزية أدوات النكرة و أدوات المعرفة
+
+88
+00:07:44,420 --> 00:07:50,840
+يعني المركب هنا .. المركب هناكايرال ال a اللي
+
+89
+00:07:50,840 --> 00:07:56,260
+موجودة فيه هي أداة نكرة ولذلك إذا أنا مثلا بدي أجي
+
+90
+00:07:56,260 --> 00:08:00,340
+أحكي باللغة الإنقليزية أقول this is a chiral
+
+91
+00:08:00,340 --> 00:08:05,900
+compound معناه ذلك هذا مركب بلف الضوء ال a أداة
+
+92
+00:08:05,900 --> 00:08:09,880
+نكرة زي ما بنيجي نقول this is a table this is a
+
+93
+00:08:09,880 --> 00:08:14,220
+pen واضح الفكرة؟ الآن لو كنت بدي أحكي عن مركب زي
+
+94
+00:08:14,220 --> 00:08:20,470
+هذا شو بدي أقول عنه؟أكايرل، الآن هنا أكايرل كلمة
+
+95
+00:08:20,470 --> 00:08:24,470
+واحدة لما بدي استعمل إلها أذات نكرة بالإنقليزي بدي
+
+96
+00:08:24,470 --> 00:08:31,670
+أحفظ قدامها أن صارت هذه الكلمة كلمة واحدة أكايرل
+
+97
+00:08:32,460 --> 00:08:35,220
+فالكلمة اللى عندى للمركب اللى بيكون optically
+
+98
+00:08:35,220 --> 00:08:40,180
+active كايران ال optically inactive أكايرة الكلمة
+
+99
+00:08:40,180 --> 00:08:43,580
+واحدة الآن حسب قواعد اللغة الإنجليزية ان هنا بتدخل
+
+100
+00:08:43,580 --> 00:08:49,040
+أداة ناكرة ال a و هنا بتدخل أداة ناكرة ال m فإذا
+
+101
+00:08:49,040 --> 00:08:53,180
+كنتوا بتسمعوا أو بتقرؤوا بتكونوا منتبهين لهذا
+
+102
+00:08:53,180 --> 00:09:00,100
+الكلام ال m طيب يا تورا لو أنا حطيتمن ال two
+
+103
+00:09:00,100 --> 00:09:05,500
+enantiomers خليط متساوي يعني جبت كمية من ال
+
+104
+00:09:05,500 --> 00:09:08,700
+enantiomer الأول و كمية من ال enantiomer التاني و
+
+105
+00:09:08,700 --> 00:09:12,300
+حطيتهم مع بعض في ال polarimeter عملت منهم mixture
+
+106
+00:09:12,300 --> 00:09:18,120
+هذا الخليط المتساوي بيسموه racemic mixture فمعنى
+
+107
+00:09:18,120 --> 00:09:22,180
+racemic mixture او racemic modification هو خليط
+
+108
+00:09:22,180 --> 00:09:26,400
+متساوي من ال two enantiomers هل يا ترى هذا الخليط
+
+109
+00:09:26,400 --> 00:09:30,580
+المتساويبكون optically active ولا optically
+
+110
+00:09:30,580 --> 00:09:37,700
+inactive؟ optically inactive، ليش؟ لأن واحد بيلف
+
+111
+00:09:37,700 --> 00:09:41,880
+الضوء يمين، التاني بيلف الضوء شمال، المحص لزفر
+
+112
+00:09:43,230 --> 00:09:48,550
+واضح؟ زي تماما ما بنيجي بنقول واحد بيبني واحد
+
+113
+00:09:48,550 --> 00:09:54,410
+بيهدم ايش في نهاية المحصلة؟ صفر متى يبلغ البنيانو؟
+
+114
+00:09:54,410 --> 00:10:00,630
+تماما هو أنت تبني وغيرك يهدم واضح الفكرة؟ ولذلك
+
+115
+00:10:00,630 --> 00:10:04,650
+إذا كان عندى خليط متساوي .. إذا كان عندى خليط
+
+116
+00:10:04,650 --> 00:10:11,560
+متساوي من ال two enansomers بتكون إيش؟الخليط
+
+117
+00:10:11,560 --> 00:10:16,780
+chiral ولا achiral كله optically active ولا
+
+118
+00:10:16,780 --> 00:10:20,480
+optically inactive؟ optically inactive طبعا هنا
+
+119
+00:10:20,480 --> 00:10:26,740
+ممكن يجيني السؤال طب يا تورا لو كان عندي خليط بنسب
+
+120
+00:10:26,740 --> 00:10:28,300
+غير متساوية
+
+121
+00:10:30,330 --> 00:10:36,830
+يعني مثلا خلطت من ال isomer الموجب نسبة 70% من ال
+
+122
+00:10:36,830 --> 00:10:42,110
+isomer السالب نسبة 30% هذا الخليط
+
+123
+00:10:44,420 --> 00:10:50,400
+هيكون optically active هذا الخليط هيكون optically
+
+124
+00:10:50,400 --> 00:10:57,780
+active ولكن بشكل ايش؟ جزئي بشكل جزئي تماما زي ما
+
+125
+00:10:57,780 --> 00:11:01,460
+بنيجي نقول مثلا بني ادم الله ربح سبعين كذا خسر
+
+126
+00:11:01,460 --> 00:11:07,660
+تلاتين كدهش في النهاية؟المربح 40 ولذلك هنا نسبة
+
+127
+00:11:07,660 --> 00:11:13,120
+الزيادة 40% موجب بنضربها في الزاوية الأصلية يعني
+
+128
+00:11:13,120 --> 00:11:18,780
+لو افترضت مثلا المركب النقي زاويته 20 هذه العشرين
+
+129
+00:11:18,780 --> 00:11:24,300
+للمركب الاش النقي لو وضعته زي ما هو وضعت أحد
+
+130
+00:11:24,300 --> 00:11:28,980
+الانانشومارز زاويته زائد عشرين الانانشومارز التاني
+
+131
+00:11:28,980 --> 00:11:34,690
+وضعته زاويتهنقص عشرين طب لو عملت خليط من التنين
+
+132
+00:11:34,690 --> 00:11:38,430
+سبعين في المية موجب تلاتين في المية سالب هذا
+
+133
+00:11:38,430 --> 00:11:44,120
+الخليط كده هتكون الزاوية تبعته؟لاحظوا انا في عندي
+
+134
+00:11:44,120 --> 00:11:49,360
+فرق اربعين في المية موجب هقول اربعين على مية ضرب
+
+135
+00:11:49,360 --> 00:11:53,360
+العشرين فالزاوية هتكون اقل من عشرين بالتأكيد
+
+136
+00:11:53,360 --> 00:11:59,540
+العشرين لأ النقي تماما لان انا عندي جزء من هذا جزء
+
+137
+00:11:59,540 --> 00:12:02,700
+اربعين في المية بس موجب فالاربعين في المية من
+
+138
+00:12:02,700 --> 00:12:09,990
+العشرين كده هتطلع نضربها تمانيةفهذا الخليط زاوية و
+
+139
+00:12:09,990 --> 00:12:14,570
+هتكون تمانية الان موجب ولا سالب؟ بالتأكيد هتتبع
+
+140
+00:12:14,570 --> 00:12:18,170
+الأعلى يعني لو حطيت كمية كبيرة من الموجب و قليلة
+
+141
+00:12:18,170 --> 00:12:21,730
+من السالب فالخليط موجب يعني الإشارة على طول بنحطها
+
+142
+00:12:21,730 --> 00:12:26,650
+مابدهاش حساب واحد ربح كتير و خسر أقل فهو رابح واحد
+
+143
+00:12:26,650 --> 00:12:31,410
+خسر كتير و ربح أقل فهو خاسر الآن بتطلع أنا أعلى
+
+144
+00:12:31,410 --> 00:12:35,310
+الموجب ولا السالب؟ إذا الخليط اللي عندي موجب لكن
+
+145
+00:12:35,310 --> 00:12:40,060
+مش هيصل للموجب النقل مش هيصل لعشرينواضح؟ أنا بقول
+
+146
+00:12:40,060 --> 00:12:44,920
+هنا في عندي تلاتين سالبات بتشطبك بقالها تلاتين
+
+147
+00:12:44,920 --> 00:12:49,460
+موجة بقىهدولة شطبوا بعض يعني كأنه في عندي تلاتين
+
+148
+00:12:49,460 --> 00:12:52,180
+في المية بيلفوا باتجاه و التلاتين باتجاه تاني
+
+149
+00:12:52,180 --> 00:12:55,220
+هدولة شطبوا بعض لما نشطب التلاتين السالبة مع
+
+150
+00:12:55,220 --> 00:12:59,180
+تلاتين اقبالها موجبة جداش ضال عندي اربعين من
+
+151
+00:12:59,180 --> 00:13:03,540
+الموجبة اربعين على مية ضارب عشرين بنقدر نحسب كمان
+
+152
+00:13:03,540 --> 00:13:09,780
+زاوية الخليط اذا دائما و ابدا زاوية الخليط اقل ولا
+
+153
+00:13:09,780 --> 00:13:14,380
+اكثر من الزاوية النقية اقل لاحظوا معي لو هالخليط
+
+154
+00:13:14,380 --> 00:13:22,640
+وصل خمسين و خمسينعندما تصبح زاويته صفر رسمك
+
+155
+00:13:22,640 --> 00:13:28,760
+ميكس شرف او رسمك موديفيكشنالخمسين وخمسين شطبوا بعض
+
+156
+00:13:28,760 --> 00:13:35,220
+تماما زي إنسان ربح خمسين دينار الصبح وخسر خمسين
+
+157
+00:13:35,220 --> 00:13:40,620
+دينار آخر النهار، إيش بيروح؟ صفر، لفنا خمسين موجب
+
+158
+00:13:40,620 --> 00:13:43,820
+و بعدين خمسين سلم، بنينا خمسين حجر و هدينا خمسين
+
+159
+00:13:43,820 --> 00:13:50,950
+حجر، شو المحصلة؟ صفر، واضح؟هذا بالنسبة لمعنى
+
+160
+00:13:50,950 --> 00:13:54,770
+كايرال موليكيول و أكايرال موليكيول و راسيمك ميكشر
+
+161
+00:13:54,770 --> 00:13:58,570
+ولذلك يجب أن تكونوا مميزين أن كلمة كايرال مرت معنى
+
+162
+00:13:58,570 --> 00:14:03,450
+في كام اتجاه كايرال كاربون معناها أربع مجموعات
+
+163
+00:14:03,450 --> 00:14:09,230
+مختلفة كايرال موليكيول معناه بلوف الضوء معناه بلوف
+
+164
+00:14:09,230 --> 00:14:15,950
+الضوء هذا الكلام كله متعلق بقصة ال rotationوهو
+
+165
+00:14:15,950 --> 00:14:19,970
+خاصية فيزيائية بالمناسبة معنى خاصية فيزيائية ان
+
+166
+00:14:19,970 --> 00:14:22,810
+انا لو بعد ما خدتها المركب وحطيته في ال
+
+167
+00:14:22,810 --> 00:14:26,690
+polarimeter وعملت كل القياسات باسترده زي ما هو ولا
+
+168
+00:14:26,690 --> 00:14:31,610
+لأ انا ماعملت عليه تفاعل هذا الكلام بيقودنا مباشرة
+
+169
+00:14:31,610 --> 00:14:36,770
+لشغلتانية ال enantiomersiatura من ناحية الخواص
+
+170
+00:14:36,770 --> 00:14:43,360
+الكيميائية هل بيختلفوا ولا لأيعني ال chemical
+
+171
+00:14:43,360 --> 00:14:48,580
+properties of enantiomers الخواص الكيميائية لل
+
+172
+00:14:48,580 --> 00:14:54,020
+enantiomers أسهل شيء ممكن نفهم من خلاله الموضوع
+
+173
+00:14:54,020 --> 00:14:59,560
+أسهل شيء ممكن نفهم من خلاله الموضوع عارفين شو هو؟
+
+174
+00:14:59,560 --> 00:15:04,300
+هعطيكم مثال أو مثلين من الحياة مثال أو مثلين من
+
+175
+00:15:04,300 --> 00:15:10,730
+الحياةمرات بيكون عندنا عدسات للنضارات عدسات محدبة
+
+176
+00:15:10,730 --> 00:15:14,470
+ممكن نستعملها نجمع الأشعة أو ممكن بعض الأطفال
+
+177
+00:15:14,470 --> 00:15:19,230
+الصغار يجمعوا الأشعة أو يحرجوا ورقة بالعدسة بيصير
+
+178
+00:15:19,230 --> 00:15:20,210
+ولا لأ؟
+
+179
+00:15:36,480 --> 00:15:39,820
+ولا صورتها غير المتطابقة في المرآة الإنانش
+
+180
+00:15:39,820 --> 00:15:44,700
+ومرتبعها؟ مابفرقش يعني لو فكنا العدستين من
+
+181
+00:15:44,700 --> 00:15:48,840
+النظارات وقولنا للطلاب يتعلموا ويركزوا أشعة الشمس
+
+182
+00:15:48,840 --> 00:15:52,780
+على البقرة استعملوها العدسة الاتنين هيحرجوا الورقة
+
+183
+00:15:52,780 --> 00:15:58,260
+إذا هنا اتنين اختلفوا ولا لأ؟ مااختلفوش طيب كويس
+
+184
+00:15:58,260 --> 00:16:03,860
+لو افترضنا على سبيل المثال إنه إنسان بيشتري أبواب
+
+185
+00:16:03,860 --> 00:16:08,950
+سياراتقديمة، بيشتريها بالكيلو، الباب وزنه عشرين
+
+186
+00:16:08,950 --> 00:16:14,090
+كيلو، يا ترى لو جيبناله الباب الأمامي اليمين أو
+
+187
+00:16:14,090 --> 00:16:19,950
+الباب الأمامي الشمال، بيفرق عنده؟ هو بيشتريهم حديد
+
+188
+00:16:19,950 --> 00:16:25,990
+خردو في النهاية؟بدوا يسارهم وانتهى افرج انه يشتري
+
+189
+00:16:25,990 --> 00:16:29,970
+باب يمين ولا باب شمال؟ مايفرقش، اذا ممكن مايفرقوش
+
+190
+00:16:29,970 --> 00:16:34,790
+طب وين بيفرق معه انه يشتري باب سيارة يمين او شمال؟
+
+191
+00:16:34,790 --> 00:16:39,030
+لما يكون في عنده السيارة الكايرة اللي فيها ايضا
+
+192
+00:16:39,030 --> 00:16:45,150
+الفتحات مصممة يمين وشمال واجتها بيصيربيفرق عنده
+
+193
+00:16:45,150 --> 00:16:48,710
+لهذه الجهة بدي الباب اليمين لهذه الجهة بدي الباب
+
+194
+00:16:48,710 --> 00:16:53,710
+الشمال إذا كأنه الفتحات تبعون بواب السيارة كايرال
+
+195
+00:16:53,710 --> 00:17:00,110
+والبواب كايرال الان كل إشي بدي أحطه في مكانه وقتها
+
+196
+00:17:00,110 --> 00:17:04,650
+بيصير عند الفرق تماما زي ما أجي أنا أتكلم يعني
+
+197
+00:17:04,650 --> 00:17:13,120
+عفوا عن أقدام الأحذية الأحذية كايرالواضحة؟ و
+
+198
+00:17:13,120 --> 00:17:15,760
+الأقدام كايرل .. كايرل .. كايرل .. كايرل .. كايرل
+
+199
+00:17:15,760 --> 00:17:16,780
+.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل ..
+
+200
+00:17:16,780 --> 00:17:19,380
+كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. كايرل
+
+201
+00:17:19,380 --> 00:17:22,580
+.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل ..
+
+202
+00:17:22,580 --> 00:17:22,820
+كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. كايرل
+
+203
+00:17:22,820 --> 00:17:22,820
+.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل ..
+
+204
+00:17:22,820 --> 00:17:22,820
+كايرل .. كايرل .. كايرل .. كايرل .. كايرل .. كايرل
+
+205
+00:17:22,820 --> 00:17:25,660
+.. كايرل .. كايرل .. كايرل .. كايرل .. كايرل ..
+
+206
+00:17:25,710 --> 00:17:30,490
+طيب، هذا الكلام وين أكتر ما بيوجد؟ بيوجد في ال
+
+207
+00:17:30,490 --> 00:17:34,030
+biological systems، في النظم البيولوجية أنه في
+
+208
+00:17:34,030 --> 00:17:38,490
+النظم البيولوجية ال enzymes و ال receptors في
+
+209
+00:17:38,490 --> 00:17:42,330
+أحيان كثيرة كايرا يعني افترضوا مثلا عندي أنا
+
+210
+00:17:42,330 --> 00:17:47,590
+receptor موجب هذا ال receptor الموجب من خواصه أنه
+
+211
+00:17:47,590 --> 00:17:53,470
+بتفاعل مع دوة ال drugبتفعل مع دوة drug ال drug
+
+212
+00:17:53,470 --> 00:17:59,310
+ممكن يكون موجب ممكن يكون ثالث فيه منه اتنين الان
+
+213
+00:17:59,310 --> 00:18:04,740
+خلينا نفترض ان هذا ال receptor الموجببتفاعل مع
+
+214
+00:18:04,740 --> 00:18:08,900
+الدوى الموجب فلو جبتله الدوى الموجب بتفاعل معه
+
+215
+00:18:08,900 --> 00:18:12,320
+وبيؤدي لتأثيره بطيب البني آدم لو جبتله الدوى
+
+216
+00:18:12,320 --> 00:18:15,980
+السالم واحد
+
+217
+00:18:15,980 --> 00:18:20,180
+من اتنين ممكن يكون مافيش تفاعل بالمرة ومافيش أثر
+
+218
+00:18:20,180 --> 00:18:24,160
+بالمرة وممكن يتفاعل معه بطريقة معاتسة ويؤدي إلى
+
+219
+00:18:24,160 --> 00:18:30,950
+ضرر واضح؟حسب طبيعة الأدوية وحسب الـ Receptor
+
+220
+00:18:30,950 --> 00:18:34,370
+المعني ولذلك هذه النقطة أكثر ما بتواجهنا في
+
+221
+00:18:34,370 --> 00:18:39,810
+الكيميا وفي الأدوية أنه بيجوا بيدرسوا كل مركب من
+
+222
+00:18:39,810 --> 00:18:44,190
+التنين أنه فيهم اللي له الفاعلية ولذلك كثير من
+
+223
+00:18:44,190 --> 00:18:47,230
+الأدوية لما بتيجوا بتقرأوا الدوة الفعال بتلاقوا ال
+
+224
+00:18:47,230 --> 00:18:51,250
+R مثلا في مركب تاني الدوة الفعال ال S في مركب تالت
+
+225
+00:18:51,250 --> 00:18:55,700
+ال R في مركب رابع ال S حسب طبيعة إيش الدوةالان
+
+226
+00:18:55,700 --> 00:18:59,480
+بيصير السؤال طيب إذا هذا هو المركب الفعال اللى
+
+227
+00:18:59,480 --> 00:19:04,420
+يستخدم كعلاج المركب التانى شو بده يكون؟ممكن يكون
+
+228
+00:19:04,420 --> 00:19:09,780
+عديم الفائدة يعني حضوره زي غيابه لا يؤذي ولا يضر و
+
+229
+00:19:09,780 --> 00:19:15,480
+ممكن يكون مؤذى و مضر و يعمل مشاكل الآن تعون
+
+230
+00:19:15,480 --> 00:19:21,060
+الكيميا بيشتغلوا بالشكل القاتل إذا مركب منهم دوة و
+
+231
+00:19:21,060 --> 00:19:24,980
+التاني لا يضر بدل ما يفصلوهم انتوا لاحظوا لما حض
+
+232
+00:19:24,980 --> 00:19:28,870
+المركب طلعوا عندي خليط من التنينهنتعلم انه لما
+
+233
+00:19:28,870 --> 00:19:32,970
+نحضر الدواء بيطلع التانين خليط عملية الفصل عملية
+
+234
+00:19:32,970 --> 00:19:37,570
+صعبة و مكلفة ماديا كتير الان من هدولة مين المفيد
+
+235
+00:19:37,570 --> 00:19:42,550
+خلينا نفترض هذا الانانشومر التاني إذا كان مابضرش
+
+236
+00:19:42,550 --> 00:19:47,110
+سيبه معه بيأكلوا البني آدم و بيخرجوا من البني آدم
+
+237
+00:19:47,110 --> 00:19:52,640
+بدون ما يؤدي لأي ضرربيعطوا الدواء وبيعطوا التاني،
+
+238
+00:19:52,640 --> 00:19:56,700
+هم عارفين ان هذا التاني مش هيضر .. ان هذا التاني
+
+239
+00:19:56,700 --> 00:20:00,820
+مش هيضر هذا الكلام بالمناسبة مثلا بيعملوه في دواء
+
+240
+00:20:00,820 --> 00:20:06,020
+زي الابوبروفين ربما انتوا لما مار علينا جزء
+
+241
+00:20:06,020 --> 00:20:10,380
+الابوبروفين متذكرينه؟ و انا هفرجيكواياه في ال
+
+242
+00:20:10,380 --> 00:20:14,540
+aromatic compounds ارجعولهلو اتطلعتوا على
+
+243
+00:20:14,540 --> 00:20:18,000
+الابوبروفن او الاتروفن هتلاقوا فيه chiral center
+
+244
+00:20:18,000 --> 00:20:22,340
+فيه منه اتنين لان واحد منهم مفيد و بضيع الصداع
+
+245
+00:20:22,340 --> 00:20:28,000
+التاني مالوش تأثير واضح بيسيبوه مع بعض و بيعطوا
+
+246
+00:20:28,000 --> 00:20:31,400
+البني ادم اللي هو يستفيد من المفيد و يخرج الآخر
+
+247
+00:20:31,400 --> 00:20:36,630
+لمصيبة الكبيرة وين بتصير؟لو كان واحد منهم مفيد
+
+248
+00:20:36,630 --> 00:20:43,010
+والتاني ضار يجب حينها أن يفصل فصلا كاملا الضار
+
+249
+00:20:43,010 --> 00:20:48,730
+ويعطى الإنسان المفيد واضحة الفكرة؟ إذا أغلطنا بهذه
+
+250
+00:20:48,730 --> 00:20:53,210
+الشغلة، إيش حيصير فينا؟ حيصير فينا المقاس التالية
+
+251
+00:20:53,210 --> 00:20:57,750
+هذا مقال كتباه
+
+252
+00:21:03,190 --> 00:21:10,030
+دكتورة عن عقار هذا العقار ربما موجود هنا اسمه
+
+253
+00:21:10,030 --> 00:21:19,430
+الثاليدو أميد هذا قصته في الكيميا قصة مشهورة
+
+254
+00:21:19,430 --> 00:21:26,750
+كتير هذا هو العقار الثاليدو أميد الآن هذا الثاليدو
+
+255
+00:21:26,750 --> 00:21:32,540
+أميد في Cairo Center هنا واحدةيعني لما نطلع في
+
+256
+00:21:32,540 --> 00:21:37,140
+الشكل تبعه فيه chiral center واحدة إذا صار فيه منه
+
+257
+00:21:37,140 --> 00:21:46,100
+مركب R وصار منه مركب S الآن المركب R مفيد ولمين
+
+258
+00:21:46,100 --> 00:21:50,300
+المركب R مفيد تقريبا اخترع هذا الدواء في سنة 1953
+
+259
+00:21:50,300 --> 00:21:56,940
+للنساء الحوامل بضيع عندهم الصداع المصاحب للحملنزل
+
+260
+00:21:56,940 --> 00:22:01,600
+السوق بدون ما تستكمل الدراسات الكاملة عليه في آخر
+
+261
+00:22:01,600 --> 00:22:07,920
+الخمسينات طلعت المصيبة أن المركب التاني الـ S هذا
+
+262
+00:22:07,920 --> 00:22:12,300
+بيخترق المشيمة و بيأثر على الأجنة اللي في بطون
+
+263
+00:22:12,300 --> 00:22:17,190
+الأمهات لأنهم بياخدوا الأمهات الحواملعشان الصداع
+
+264
+00:22:17,190 --> 00:22:21,750
+ما انتبهوش ما استكملوش الدراسات تبع الدواء فطلع
+
+265
+00:22:21,750 --> 00:22:26,350
+المركب الثاني بأثر على الأجنة، الآن عدد كبير من
+
+266
+00:22:26,350 --> 00:22:31,350
+النساء استعملوا بدأت أوروبا تتواجه بالأجنة
+
+267
+00:22:31,350 --> 00:22:36,920
+المشوهينتقريبا سنة و نص سنتين ستين و واحد و ستين
+
+268
+00:22:36,920 --> 00:22:41,000
+نهاية التسعة و خمسين مباشرة من أول ما انتبهولها مع
+
+269
+00:22:41,000 --> 00:22:45,360
+الواحد و ستين أوقفوا استعمال الدواء على طول لكن
+
+270
+00:22:45,360 --> 00:22:49,960
+بعد ما طلع عندهم جيل كامل من الأطفال المشواهين
+
+271
+00:22:49,960 --> 00:22:54,520
+ملمش أيديهم فقط لغلطة زي هيك انه كانوا يعطوا
+
+272
+00:22:54,520 --> 00:23:00,400
+الدواء و معاهالإينان شمار .. الإينان شمار إيش
+
+273
+00:23:00,400 --> 00:23:06,980
+اتضارت و ربما لو الصورة واضحة عندكم في أسماء
+
+274
+00:23:06,980 --> 00:23:12,780
+مشهورة في هذا المجال يعني هذا الإنسان يمكن مش واضح
+
+275
+00:23:12,780 --> 00:23:17,480
+كده بس اتطلعوا الإيدين بتاعونه بصار جدا الإيدين
+
+276
+00:23:17,480 --> 00:23:23,060
+بتاعونه اتطلعوا عليه بالصور بالنتبتنبسطوا، بتلاقوا
+
+277
+00:23:23,060 --> 00:23:28,240
+كتير، ليش؟ لأن هذا مذيع مشهور جدا، مذيع مشهور جدا
+
+278
+00:23:28,240 --> 00:23:34,420
+في ال BBC ومحرر أخبار في النهاية اسمه Adams Spank
+
+279
+00:23:34,420 --> 00:23:38,780
+Adams Spank اللي بدهم يقرأوا عن قصته Adams Spank
+
+280
+00:23:38,780 --> 00:23:44,790
+موليد ال 61يعني الحامل صار في الستين الام أخدت
+
+281
+00:23:44,790 --> 00:23:49,150
+الدواء هو موليد الواحد والستين بدون إيدين وبعين
+
+282
+00:23:49,150 --> 00:23:55,430
+يعني فيها إيش عوى كذلك الحال لو بدأ أطلع على أسماء
+
+283
+00:23:55,430 --> 00:24:00,790
+تانية هاي Adams Smug شايفين العين هنا شوية مافيش
+
+284
+00:24:00,790 --> 00:24:09,710
+إيدين هذا بني آدم مش بدخل سيجارة هذا برسم الريشة
+
+285
+00:24:09,710 --> 00:24:15,170
+في تمه لأنه مالوش إيدينرسام شهير ويله معارض شهيرة
+
+286
+00:24:15,170 --> 00:24:19,670
+برضه موليد ال واحد و ستين من غلطة زي هذه برضه
+
+287
+00:24:19,670 --> 00:24:23,650
+موليد ال واحد و ستين و هي المعرض الفني تبعه و هذا
+
+288
+00:24:23,650 --> 00:24:28,950
+بامالي الكوجادرين اللي تشوفوه هذا بيعزف ع الجثار
+
+289
+00:24:28,950 --> 00:24:36,790
+برجله ليش؟ برضه لأنه مالوش أطراف مالوش إيدين إيدين
+
+290
+00:24:36,790 --> 00:24:43,050
+و غير الإيدين كمان إيدين و عينينو جوزي أنتونيو
+
+291
+00:24:43,050 --> 00:24:47,130
+عازف شهير جدا من نيكاراجوا و ربما البعض سمع له
+
+292
+00:24:47,130 --> 00:24:52,480
+موسيقىعازف مشهور هدولة كلهم عايشين ولذلك من سنين
+
+293
+00:24:52,480 --> 00:24:56,640
+بسيطة الألمان عملوا فيلم عن هذا الموضوع واحتجوا
+
+294
+00:24:56,640 --> 00:25:01,980
+الشعب الألماني ليش؟ لأنه ذكروهم بالمقساة اللي مرت
+
+295
+00:25:01,980 --> 00:25:06,160
+في عام واحد وستين اتنين وستين مقسات الأجنة
+
+296
+00:25:06,160 --> 00:25:10,340
+المشوهين كل هذا الكلام لأن استعملنا الدوة الغلط
+
+297
+00:25:10,340 --> 00:25:16,090
+الفكرة ببساطةمرة تانية تشبه قصة المفتاح والذرفيل
+
+298
+00:25:16,090 --> 00:25:20,990
+الذرفيل كايرة الفراغي بيده مفتاح معين يتطابق معاه
+
+299
+00:25:20,990 --> 00:25:27,670
+نجيب المفتاح التاني مابفتحش مستفدناش اشي و لذلك في
+
+300
+00:25:27,670 --> 00:25:34,970
+الخواص الكيميائية ال enantiomers لهم نفس الخواص
+
+301
+00:25:34,970 --> 00:25:40,840
+الكيميائية ما عدااذا اتفعلوا مع مركبات فراغية زيهم
+
+302
+00:25:40,840 --> 00:25:45,680
+يعني لما بتفعل ال chiral مع ال chiral اشي ماخد
+
+303
+00:25:45,680 --> 00:25:49,000
+اتجاه فراغي شمال او يمين مع اشي ماخد اتجاه فراغي
+
+304
+00:25:49,000 --> 00:25:52,880
+شمال او يمين بيصير الاختلاف زي الزرفيل بتاع الباب
+
+305
+00:25:52,880 --> 00:25:57,820
+في شمال ويمين جوا والمفتاح في شمال ويمين بيصير
+
+306
+00:25:57,820 --> 00:26:04,160
+مفتاح معينلذرفي المعين واحد تاني مابظبطش او بادى
+
+307
+00:26:04,160 --> 00:26:08,340
+الى مشاكل ولذلك في الخواص الكيميائى المحاصلة اللى
+
+308
+00:26:08,340 --> 00:26:12,500
+بنقولها ان ال enantiomers they have the same
+
+309
+00:26:12,500 --> 00:26:16,780
+chemical the same chemical properties except when
+
+310
+00:26:16,780 --> 00:26:19,880
+they react with other chiral molecules لما يصير
+
+311
+00:26:19,880 --> 00:26:24,630
+التفاعل بين chiral و chiral وجعت المشكلةواضح
+
+312
+00:26:24,630 --> 00:26:31,030
+الفكرة؟ هذا كلام عام جدا لكن بحياتكوا .. يعني بأمل
+
+313
+00:26:31,030 --> 00:26:34,990
+أنه هتصيروا تشوفوا كتير هذه المسميات هتصيروا
+
+314
+00:26:34,990 --> 00:26:38,730
+تقرأوا كتير على الأدوية مكتوب عليها R و بين جثين
+
+315
+00:26:38,730 --> 00:26:42,330
+موجة بقى أو سالب و S و بين جثين موجة بقى أو سالب
+
+316
+00:26:42,330 --> 00:26:52,230
+فنكون عارفين كل هذه المصطلحات فليدو أمد فليدو
+
+317
+00:26:56,400 --> 00:27:03,260
+ثليده أمن لو قرأته قصة الثليده أمن قصة كبيرة جدا
+
+318
+00:27:03,260 --> 00:27:09,540
+بلاش ممكن نروح على شغلة تانية بسيطة جدا ربما مرت
+
+319
+00:27:09,540 --> 00:27:19,740
+عليكم كتير مر عليكم هذا اللي موجود هنا في الصورة
+
+320
+00:27:19,740 --> 00:27:27,120
+قادرين تشوفوه الفطرالفطر تبع البيتزا، الان متعودين
+
+321
+00:27:27,120 --> 00:27:31,500
+تقولوا ان الفطر في منه كويس و في منه سام، مظبوط؟
+
+322
+00:27:31,500 --> 00:27:37,820
+الان الكويس والسام فيهم نفس المركب، نفس المركب،
+
+323
+00:27:37,820 --> 00:27:42,880
+تحديدا من ناحية كيميائية هذا هو المركب، واضح؟ من
+
+324
+00:27:42,880 --> 00:27:44,040
+ناحية كيميائية
+
+325
+00:27:47,540 --> 00:27:52,000
+هذا هو المركب، شايفينه؟ هاي المركب، الآن هذا
+
+326
+00:27:52,000 --> 00:27:59,860
+المركب في chiral center واحد، هذا واحد
+
+327
+00:27:59,860 --> 00:28:08,010
+منهم بيكون اكويس والتاني بيكون poisonous، سابفقط
+
+328
+00:28:08,010 --> 00:28:12,330
+بيختلفوا بال chiral center يعني نفس الجزء هذا اللي
+
+329
+00:28:12,330 --> 00:28:17,110
+بنسميه one octane three all ال R منه اللي كويس و
+
+330
+00:28:17,110 --> 00:28:22,590
+التاني ال 7 و انتوا دائما كانوا يحذروكوا في دراسة
+
+331
+00:28:22,590 --> 00:28:27,330
+النبات و انه احذروا الفطر اللي بيكون عادة شكله زي
+
+332
+00:28:27,330 --> 00:28:32,650
+المثلث يعني الفطر العادي هذا ال okay هذا العامل
+
+333
+00:28:32,650 --> 00:28:37,240
+مشكلة الآن هذولا فيهم نفس الهوركبنفس المُركّب اللي
+
+334
+00:28:37,240 --> 00:28:41,080
+خلّه مُركّب كويس ومُركّب سام انه هذا انانشومر وهذا
+
+335
+00:28:41,080 --> 00:28:45,660
+انانشومر تاني شوفوا هذا الفرق البسيط جدا اللي
+
+336
+00:28:45,660 --> 00:28:49,740
+بمرهانة قعد يؤثر على الأدوية ويؤثر على حياة الناس
+
+337
+00:28:49,740 --> 00:28:54,120
+هو فرق أساسي في فهم الكيمياء ولذلك يعني ال stereo
+
+338
+00:28:54,120 --> 00:28:59,980
+chemistry مش قصة يعني قصة شيء أحيانا صعب أو شيء
+
+339
+00:28:59,980 --> 00:29:05,490
+ممتع على جانب لإن فيه صميمفهم الكيمياء و في صميم
+
+340
+00:29:05,490 --> 00:29:11,470
+فهم الأدوية ان نكون فاهمين هذه الأمور المتعلقة بال
+
+341
+00:29:11,470 --> 00:29:18,890
+stereo chemistry طبعا الانسان كل ما بيتعب من شغلة
+
+342
+00:29:18,890 --> 00:29:24,270
+بيقول واجتاش بدنا نخلص من الشغلة اول ما بيحس انه
+
+343
+00:29:24,270 --> 00:29:30,310
+بده يخلص من الشغلة بيكتشف نقطة بسيطة جدا ان هو لسه
+
+344
+00:29:30,310 --> 00:29:36,330
+ماخدش من الموضوع نقطةأول ما بيحس أنه جربنا نخلص من
+
+345
+00:29:36,330 --> 00:29:40,950
+هالشغلة هو ما أخدش من الموضوع نقطة، ليش؟ لأنه أنا
+
+346
+00:29:40,950 --> 00:29:47,670
+تكلمت عن جزء في chiral centers واحد، قولت بيقدّي
+
+347
+00:29:47,670 --> 00:29:52,990
+لكم إينان شمار؟ إتنين، طيب يا تورة الآن لو أجيت و
+
+348
+00:29:52,990 --> 00:29:58,350
+أتكلمت عن ال chiral centers ال chiral centers
+
+349
+00:29:58,350 --> 00:30:02,190
+والإينان
+
+350
+00:30:02,190 --> 00:30:12,790
+شمارأو ال products ال stereo isomers لما
+
+351
+00:30:12,790 --> 00:30:17,690
+كان في عندى one chiral center كم واحد كانوا؟ طب يا
+
+352
+00:30:17,690 --> 00:30:19,910
+تورا لو صاروا اتنين، لو صاروا تلاتة، لو صاروا
+
+353
+00:30:19,910 --> 00:30:23,490
+أربعة، لو صاروا خمسة، لو صاروا ستة، كده بده يصير
+
+354
+00:30:23,490 --> 00:30:28,180
+عندى؟يعني جزء فيه تلاتة اربعة خمسة chiral centers
+
+355
+00:30:28,180 --> 00:30:33,060
+في عندى علاقة بتقوللي ال maximum possible number
+
+356
+00:30:33,060 --> 00:30:40,680
+of stereoisomers two to the N بحيث انه هذي ايش ال
+
+357
+00:30:40,680 --> 00:30:51,790
+N اتنين اقص واحد اتنين اقص اتنين اربعة2-3 8 2-4 16
+
+358
+00:30:51,790 --> 00:30:59,050
+2-5 32 لما يبدأ يجينا مركب في خمسة chiral centers
+
+359
+00:30:59,050 --> 00:31:06,510
+هنكتشف أنه في منه 32 isomers هذول 32 isomers ممكن
+
+360
+00:31:06,510 --> 00:31:10,990
+واحد منهم يكون مفيد و بنستفيد منه والواحد و
+
+361
+00:31:10,990 --> 00:31:15,200
+التلاتين التانين بقابلهلاحظوا قداش الكلام بيصير
+
+362
+00:31:15,200 --> 00:31:20,440
+مرهق وهذا الكلام هيمر معكم على سبيل المثال الخامسة
+
+363
+00:31:20,440 --> 00:31:27,400
+لما ندرس ال biochemistry السكر اللي مكوّن من ست
+
+364
+00:31:27,400 --> 00:31:32,500
+درات كربون لما يكون في الشكل الحلقي في خمسة chiral
+
+365
+00:31:32,500 --> 00:31:39,340
+centers في منه اتنين و تلاتين isomersتخيلوا أنه
+
+366
+00:31:39,340 --> 00:31:44,700
+بدنا نتعلم لما نيجي ناخد السكر السداسي الماخد
+
+367
+00:31:44,700 --> 00:31:52,800
+الصيغة العامة C6H12O6 بدنا نرسم مش مركب واحد اتنين
+
+368
+00:31:52,800 --> 00:31:58,220
+و تلاتين مركب و نعرفهم و نميزهم بالاسم الان لما
+
+369
+00:31:58,220 --> 00:32:01,420
+المريض بيروح على المستشفى لما المريض بيروح على
+
+370
+00:32:01,420 --> 00:32:04,760
+المستشفى و بيقولوا بدنا نعطيه محلول سكر بتعرفوا
+
+371
+00:32:04,760 --> 00:32:10,490
+بيعطيه واحد من الاتنين و تلاتينواحد من ال 32 هدولة
+
+372
+00:32:10,490 --> 00:32:16,370
+واضح و الباقي مش هم اللي بيعطيها فالموضوع بيصير
+
+373
+00:32:16,370 --> 00:32:21,790
+بهذا الشكل كبير طبعا اللي بده يتدرج في الكلام يبدأ
+
+374
+00:32:21,790 --> 00:32:26,190
+يعطي مثال على اتنين chiral centers الان انا هنا
+
+375
+00:32:26,190 --> 00:32:31,390
+مابقولش ان هذا عدد ال isomers بقول هذا ال maximum
+
+376
+00:32:31,390 --> 00:32:38,340
+possible يعني هذاأعلى ما يمكن من ال isomers بس
+
+377
+00:32:38,340 --> 00:32:44,130
+ممكن يكون أقل منهيعني لما بيكون فيه اتنين chiral
+
+378
+00:32:44,130 --> 00:32:48,710
+centers ممكن يكون عنده العدد الأقصى أربعة و مرات
+
+379
+00:32:48,710 --> 00:32:53,490
+بيكونوا تلاتة و هكذا ممكن يقولوا واحد مابدناش
+
+380
+00:32:53,490 --> 00:32:58,790
+نتجاوز بس التلين يعني بدنا نشرح مثالين مثال لما
+
+381
+00:32:58,790 --> 00:33:02,790
+يكون عنده two chiral centers و عنده أربعة isomers
+
+382
+00:33:02,790 --> 00:33:07,230
+و مثال لما بيكون عنده two chiral centers بس ال
+
+383
+00:33:07,230 --> 00:33:11,430
+isomersتلاتة يعني بيطلع منهم في هذه الحالة اتنين
+
+384
+00:33:11,430 --> 00:33:16,710
+طلعوا شبه بعض نفس الاشياء واضح فبصير الدارس تبعنا
+
+385
+00:33:16,710 --> 00:33:23,630
+المركبات اللي فيهاأكتر من chiral centers والمثال
+
+386
+00:33:23,630 --> 00:33:26,770
+اللى بدنا نبدأ فيه لما يكون عندى two chiral
+
+387
+00:33:26,770 --> 00:33:32,650
+centers او centers لاحظوا ان هذا الكلام بيجيبنا
+
+388
+00:33:32,650 --> 00:33:41,000
+لنقطة ان انتوا لما بتتعلموا العلم بتتعلموا كيفبنوع
+
+389
+00:33:41,000 --> 00:33:46,340
+من البساطة بتتعلموا بنوع من البساطة في الأول يعني
+
+390
+00:33:46,340 --> 00:33:52,420
+بنعطيكوا جزء من العلم وبنخبي عنكم أجزاء بنعطيكوا
+
+391
+00:33:52,420 --> 00:33:57,340
+جزء وبنخبي عنكم أجزاء يعني لو جيبت سؤال احنا
+
+392
+00:33:57,340 --> 00:34:00,680
+اتعودنا ان نجاوبه وممكن اعطيتكوا ياهو ميركو سلمته
+
+393
+00:34:00,680 --> 00:34:05,960
+وقلتلكوا مركب البنتين لو عملتله monochlorination
+
+394
+00:34:07,760 --> 00:34:12,900
+هي واحد، اتنين، تلاتة، اربعة، خمسة كام ناتج عندي
+
+395
+00:34:12,900 --> 00:34:17,980
+من الـ monoclonation؟ اعملتوا؟ تلاتة واحدة ما زالت
+
+396
+00:34:17,980 --> 00:34:23,480
+بتقول تلاتة إذا حطيت هنا كلور، مُركّب وإذا حطيت
+
+397
+00:34:23,480 --> 00:34:27,600
+هنا مُركّب وإذا حطيت هنا مُركّب وسمناهم one
+
+398
+00:34:27,600 --> 00:34:33,360
+chloro, two chloro, three chloro الآن لاحظوا معي
+
+399
+00:34:33,360 --> 00:34:36,300
+لو هذا الكلام أنا إجيته طبقته
+
+400
+00:34:40,720 --> 00:34:44,160
+هذا مُركّب البنتين و افترض ان انا بعمل الكلور هاي
+
+401
+00:34:44,160 --> 00:34:47,080
+الكلور عن إمرأة واحد، هاي الكلور عن إمرأة اتنين،
+
+402
+00:34:47,080 --> 00:34:52,280
+هاي الكلور عن إمرأة تلاتة بتقصيروا الآن، بتقولوا،
+
+403
+00:34:52,280 --> 00:35:02,440
+في عندي chiral centers ولا لأ؟ هنا CH2 CH2 CH2 CH2
+
+404
+00:35:02,440 --> 00:35:06,180
+CH3 إذا مافيش ولا chiral center، إذا هذا فعلا
+
+405
+00:35:06,180 --> 00:35:12,290
+مُركّب واحد، الواحد كلوره بينتينالان هنا حطوا
+
+406
+00:35:12,290 --> 00:35:18,170
+القدش لناقصة في Cairo Center إذا هذا مركبين في من
+
+407
+00:35:18,170 --> 00:35:22,430
+واحد R و واحد S يعني لو روحتوا تشتريوا مركب اسمه
+
+408
+00:35:22,430 --> 00:35:28,130
+two chlorobentain هتلاقوا مركبين البياح هيقولكم في
+
+409
+00:35:28,130 --> 00:35:31,070
+مركب اسمه R two chlorobentain و S two
+
+410
+00:35:31,070 --> 00:35:34,170
+chlorobentain بس فيش مركب اسم two chlorobentain
+
+411
+00:35:34,970 --> 00:35:38,470
+واضح؟ يا بدي يكون R يا بدي يكون S لأنه في كايرال
+
+412
+00:35:38,470 --> 00:35:44,770
+سنتر طيب هذا المركب لأ لأنه اثل او اثل CH2 CH3
+
+413
+00:35:44,770 --> 00:35:47,210
+اللي هي مجموعة ايش الاثل
+
+414
+00:35:49,150 --> 00:35:53,910
+و هذه إثل فحامل HUC قالوا إثل و إثل إذا هذا فيش
+
+415
+00:35:53,910 --> 00:35:59,650
+منه غير مركّب الآن لو أنا إجيت سألتكم عادة أن الـ
+
+416
+00:35:59,650 --> 00:36:03,750
+monochlorination للوان بنتين بيعطيني
+
+417
+00:36:03,750 --> 00:36:09,450
+chemistructural isomers4 أربع لأ تلاتة لاحظوا
+
+418
+00:36:09,450 --> 00:36:14,010
+معايا ال structural isomers اللي بيختلفوا في ترتيب
+
+419
+00:36:14,010 --> 00:36:18,590
+مواقع الذرات من ناحية ال structure لكلور يا ع واحد
+
+420
+00:36:18,590 --> 00:36:23,170
+يا ع اتنين يا ع تلاتة هذا المركب هيكون اسمته two
+
+421
+00:36:23,170 --> 00:36:27,190
+chlorobentain والتاني two chlorobentain الآن ال R
+
+422
+00:36:27,190 --> 00:36:32,930
+و ال S stereo isomersولذلك، بدكم تنتبه لو أنا
+
+423
+00:36:32,930 --> 00:36:36,530
+بقولكوا بيعطيني كام structural isomers، ثلاثة، لكن
+
+424
+00:36:36,530 --> 00:36:41,250
+لو قلتلكم ال total number of isomers، أربعة، ال
+
+425
+00:36:41,250 --> 00:36:44,630
+total number of isomers، أربعة، لأن هذا واحد، هذا
+
+426
+00:36:44,630 --> 00:36:52,380
+في منه تنين، Rs، وهذا واحد، واضح الفكرة؟الان لو
+
+427
+00:36:52,380 --> 00:36:57,480
+اتينا احنا بدنا نزيد خطوة بدنا نقول it's two
+
+428
+00:36:57,480 --> 00:37:03,900
+chlorobentains بس نعمله dichlorination مش
+
+429
+00:37:03,900 --> 00:37:09,900
+monochlorination ربما ان انتوا حليتوا السؤال لكن
+
+430
+00:37:09,900 --> 00:37:17,070
+بدون ماشيبدون ما تاخدوا الاستيريو كيميستر بعين
+
+431
+00:37:17,070 --> 00:37:20,970
+الاعتبار يعني ممكن تفكروا تحطوا تنتين كلور هنا او
+
+432
+00:37:20,970 --> 00:37:24,650
+تنتين هنا او تنتين هنا او واحدة و واحدة واحدة
+
+433
+00:37:24,650 --> 00:37:27,450
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+434
+00:37:27,450 --> 00:37:27,730
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+435
+00:37:27,730 --> 00:37:27,990
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+436
+00:37:27,990 --> 00:37:29,050
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+437
+00:37:29,050 --> 00:37:31,090
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+438
+00:37:31,090 --> 00:37:37,070
+واحدة واحدة واحدة واحدة واحدة واحدة واحدة واحدة
+
+439
+00:37:37,070 --> 00:37:41,490
+واحدة واحدة واحدة واحدة واحدةهذا مش هيكون في منه
+
+440
+00:37:41,490 --> 00:37:46,650
+إلى واحد او التنتين هان او التنتين هان طبعا هان زي
+
+441
+00:37:46,650 --> 00:37:49,910
+هان و هان زي هان بعدين ممكن تحطوا كلور ع واحد و ع
+
+442
+00:37:49,910 --> 00:37:54,510
+اتنين بيصير عندى one chiral center اللى هنا وجد
+
+443
+00:37:54,510 --> 00:37:57,850
+هذا المركب اللى فيه هنا كلور هنا كلور كم مركب منه
+
+444
+00:37:57,850 --> 00:38:03,810
+اتنين ممكن تحطه هان و هان بيصير برضه عندكم one
+
+445
+00:38:03,810 --> 00:38:08,690
+chiral center في منه جديش اتنين ممكن تحطه هان و
+
+446
+00:38:08,690 --> 00:38:14,080
+هانبرضه عندكم one chiral center فى منه اتنين ممكن
+
+447
+00:38:14,080 --> 00:38:17,660
+تحطوا هنا و هنا تخيلوا لما تحطوا هنا CL ما زال
+
+448
+00:38:17,660 --> 00:38:24,300
+عندكم CH2 مش chiral و CH2 و CH2 و CH2 و هنا CH2CL
+
+449
+00:38:24,300 --> 00:38:29,860
+مش chiral اذا لو انا جبتلكوا سؤال ال one five
+
+450
+00:38:29,860 --> 00:38:36,100
+dichlorobentane has two stereoisomers طلعوا معاه
+
+451
+00:38:36,100 --> 00:38:41,170
+هي كلور هي كلورشوفوا هنا كم كايرال سنتر فيه
+
+452
+00:38:41,170 --> 00:38:45,250
+CH2H2H2H2
+
+453
+00:38:45,250 --> 00:38:49,210
+ولا كايرال سنتر إذا ال 1,5 ده يكلوره بين 2 فيه
+
+454
+00:38:49,210 --> 00:38:53,710
+مركب واحد لكن لو أنا كنت مثلا باجي بسألكم ال 1,2
+
+455
+00:38:53,710 --> 00:39:03,210
+هيكلور أكيد هنا H هنا CL هتكون مكملة H2 HH صح ولا
+
+456
+00:39:03,210 --> 00:39:10,610
+لأ هذا كم مركب منه 2لأ و هذا مش chiral هذا بس one
+
+457
+00:39:10,610 --> 00:39:19,370
+chiral center فيه هذا مش chiral هذا CH2 و هذه H2 و
+
+458
+00:39:19,370 --> 00:39:23,590
+هذه H2 و هذه H3 one chiral center إذا ال one two
+
+459
+00:39:23,590 --> 00:39:29,710
+dichloro بينتين في منه كام مركب اتنين ارقص الآن لو
+
+460
+00:39:29,710 --> 00:39:34,070
+إجيت لواحد من هدول المجموعة و اتأملوا جيدا
+
+461
+00:39:36,880 --> 00:39:44,160
+وقلنا لكوا سمونا المركب التالي هذا
+
+462
+00:39:44,160 --> 00:39:48,040
+اتنين
+
+463
+00:39:48,040 --> 00:39:49,540
+ثلاثة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+464
+00:39:49,540 --> 00:39:49,620
+تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+465
+00:39:49,620 --> 00:39:50,060
+تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+466
+00:39:50,060 --> 00:39:50,980
+تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين
+
+467
+00:39:50,980 --> 00:39:56,440
+تلاتة اتنين تلاتة
+
+468
+00:39:56,440 --> 00:39:56,780
+اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين تلاتة
+
+469
+00:39:56,780 --> 00:40:01,900
+اتنين تلاتة اتنين تلاتة اتنين تلاتة اتنين ت
+
+470
+00:40:05,330 --> 00:40:10,730
+هذه حملة مثل و H و CL و مجموعة كبيرة إذا هذه كايرا
+
+471
+00:40:10,730 --> 00:40:16,690
+و هذه حملة كلور و H و CH2 و CH3 و CHCL و CH3 أربع
+
+472
+00:40:16,690 --> 00:40:21,990
+مجموعات كايرا two chiral centers maximum بنتوقع
+
+473
+00:40:21,990 --> 00:40:26,650
+أربعة و حقيقة هنكتشف إن هدولة أربع مركبات
+
+474
+00:40:30,150 --> 00:40:34,470
+اللي كنا بنفكره و بنكتب ان هو مراكب واحد ال two
+
+475
+00:40:34,470 --> 00:40:38,330
+three dichlorobentain هتلاحظوا انه اربع مراكبات
+
+476
+00:40:38,330 --> 00:40:41,250
+يعني لو روحتوا على الدكانة تشتريوا two three
+
+477
+00:40:41,250 --> 00:40:43,570
+dichlorobentain لو سمحت بيعلى two three
+
+478
+00:40:43,570 --> 00:40:47,270
+dichlorobentain بيفتش مابلاقيش مراكب في الكون هيك
+
+479
+00:40:47,270 --> 00:40:51,250
+لو واحده اسمه two three dichlorobentain هيلاقيهم
+
+480
+00:40:51,250 --> 00:40:58,190
+اسمهم ROR SOS ROS SOR هتقولوا كيف هدولة ابن اتعلم
+
+481
+00:41:03,030 --> 00:41:07,570
+نرسمهم الان متشوقين انكوا تشوفوا شو مع الاربع
+
+482
+00:41:07,570 --> 00:41:13,150
+مركبات العملية بسيطة اتطلعوا مع هاي البنتين carbon
+
+483
+00:41:13,150 --> 00:41:20,730
+CH3 CH حملة CL CH حملة CL و إثل يعني CH2 CH3 ع
+
+484
+00:41:20,730 --> 00:41:24,960
+موقع اتنين وع موقع تلتة عندكم كلور ولا لأهي على
+
+485
+00:41:24,960 --> 00:41:29,560
+اتنين كلور و على تلاتة كلور الان حطوهم عكس بعض و
+
+486
+00:41:29,560 --> 00:41:34,100
+اعملوا صورتهم في المرايا صار هذا مركب و هذا مركب
+
+487
+00:41:34,100 --> 00:41:40,800
+غير متطابقين على بعض و حطوهم جنب بعض الكلور شايفين
+
+488
+00:41:40,800 --> 00:41:46,080
+الكلور عكس بعض و صورتهم في المرايا جنب بعض و
+
+489
+00:41:46,080 --> 00:41:52,520
+صورتهم في المراياكام مراكب صاروا؟ أربعة، الآن كل
+
+490
+00:41:52,520 --> 00:41:55,240
+اللي موجود عند الأربع مراكبات اسمهم two three
+
+491
+00:41:55,240 --> 00:41:59,000
+dichlorobentane باجي بسمي من هنا واحد اتنين تلاتة
+
+492
+00:41:59,000 --> 00:42:05,760
+اربعة لما بدي اقول هذا اتنين بدي احددها R ولا S و
+
+493
+00:42:05,760 --> 00:42:11,360
+تلاتة بدي احددها R ولا Sبسأل نفسي وين أقل مجموعة
+
+494
+00:42:11,360 --> 00:42:16,680
+على اتنين انا امركز الان على اتنين ال H شطبناها
+
+495
+00:42:16,680 --> 00:42:23,420
+قول انا على الجانب هنعكس الان عندكم Cl و Carbon و
+
+496
+00:42:23,420 --> 00:42:27,740
+CH3 طبعا هذه ال Carbon حملة Cl و هذه الحملة H اذا
+
+497
+00:42:27,740 --> 00:42:47,970
+كيف همشيأس أس أس أس أس أس أس أس أس أس أس
+
+498
+00:42:47,970 --> 00:42:54,580
+أس أس أس أس أس أس أس أس أس أس أس أسالـ H و الأعلى
+
+499
+00:42:54,580 --> 00:43:02,700
+مجموعة الـ Cl بعدها الكربون اللي حمله Cl بعدها هذه
+
+500
+00:43:02,700 --> 00:43:08,840
+الـ Ethyl CH2 CH3 أنا أعلى كربون بتحمل Cl ولا
+
+501
+00:43:08,840 --> 00:43:13,200
+كربون بتحمل H و H و C كربون بتحمل Cl مش فيها نقاش
+
+502
+00:43:13,200 --> 00:43:18,790
+الآن هاي واحد هذه كلها كمجموعة اتنينهذه تلات
+
+503
+00:43:18,790 --> 00:43:24,710
+مجموعات هذي واحد هذي اتنين هذي تلاتة ال R لما نمشي
+
+504
+00:43:24,710 --> 00:43:30,870
+بهذا الشكل واحد اتنين تلاتة شو مبينه بكتب 3R هذول
+
+505
+00:43:30,870 --> 00:43:36,090
+عكسهم هتلاقوهم 2S 3S بإمكانكوا في البيت الأن
+
+506
+00:43:36,090 --> 00:43:43,020
+تروحوا تحددوا كل هذه المواقعاعملوهم بهدوء هتلاحظوا
+
+507
+00:43:43,020 --> 00:43:47,080
+ان الأربع مركبات اللي موجودة هنا الاربع مركبات
+
+508
+00:43:47,080 --> 00:43:50,600
+اللي موجودة هنا two R ثري R وصورته في المرايا two
+
+509
+00:43:50,600 --> 00:43:55,060
+S ثري S دابن الصورة في المرايا أشمالها عكس يعني ال
+
+510
+00:43:55,060 --> 00:43:59,740
+R أقبالها S و ال R أقبالها S و بعدين ال two R ثري
+
+511
+00:43:59,740 --> 00:44:04,340
+S و أقبالها two S three R يعني ال two R two S و ال
+
+512
+00:44:04,340 --> 00:44:09,760
+three S three R مش أنا قولت كل نقطةعكس التانية في
+
+513
+00:44:09,760 --> 00:44:14,620
+المراية هل يترفيب هذه الرموز أي رمزين متشابهين؟
+
+514
+00:44:14,620 --> 00:44:20,680
+إذا هدولة كام مركبة؟ أربع مركبات اتخيلوا عاد لو
+
+515
+00:44:20,680 --> 00:44:24,960
+واحد من هدولة الدوة و الباقين بضره أنه أنا اللي
+
+516
+00:44:24,960 --> 00:44:29,060
+بدي استعمله، هنفترض أن الدوة كان 2S 3S، بس هذا
+
+517
+00:44:29,060 --> 00:44:33,530
+اللي بدي استعمله، هذا لأ، هذا لأ، هذا لأواضحة
+
+518
+00:44:33,530 --> 00:44:36,830
+الفكرة شوما الأربع مركبات المرة الجاية ان شاء الله
+
+519
+00:44:36,830 --> 00:44:41,450
+انطلاقا من هذه النقطة بشرط تكونوا اتدربتوا على
+
+520
+00:44:41,450 --> 00:44:45,570
+تسمية المركبات وعلى تحديد ال chiral centers بشكل
+
+521
+00:44:45,570 --> 00:44:48,950
+أكبر بنستمر انطلاقا من هذه النقطة
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..4e5643e2f5e21775c49780820dec063cd21b9776
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.json
@@ -0,0 +1 @@
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هنا يعني لو قولنا HPRCH3 مثلا floor okay", "tokens": [1211, 2407, 1975, 5172, 2655, 43042, 8315, 8717, 25957, 1211, 50113, 6027, 16472, 5551, 4117, 3215, 8978, 3224, 29538, 27188, 4117, 25720, 16490, 1211, 11703, 9957, 995, 8717, 44510, 10721, 50113, 15040, 4724, 2304, 7435, 2304, 2407, 27884, 1975, 4587, 1211, 3714, 7435, 2304, 2407, 27884, 6055, 30544, 34105, 37495, 22653, 45164, 12174, 12610, 8315, 389, 15958, 5462, 18, 50113, 15040, 4123, 1392], "avg_logprob": -0.2365722726099193, "compression_ratio": 1.3548387096774193, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 244.95, "end": 245.45, "word": "لو", "probability": 0.7061767578125}, {"start": 245.45, "end": 246.25, "word": " افترضنا", "probability": 0.91923828125}, {"start": 246.25, "end": 246.85, "word": " نعمل", "probability": 0.873046875}, {"start": 246.85, "end": 247.47, "word": " مثال", "probability": 0.982177734375}, {"start": 247.47, "end": 247.71, "word": " ان", "probability": 0.2152099609375}, {"start": 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{"start": 262.12, "end": 262.86, "word": " المركب", "probability": 0.8326822916666666}, {"start": 262.86, "end": 263.3, "word": " لو", "probability": 0.84423828125}, {"start": 263.3, "end": 263.8, "word": " بهذا", "probability": 0.927490234375}, {"start": 263.8, "end": 264.26, "word": " الشكل", "probability": 0.987060546875}, {"start": 264.26, "end": 264.82, "word": " إجيانا", "probability": 0.5888671875}, {"start": 264.82, "end": 264.94, "word": " في", "probability": 0.923828125}, {"start": 264.94, "end": 265.52, "word": " الامتحان", "probability": 0.929296875}, {"start": 265.52, "end": 265.74, "word": " name", "probability": 0.38818359375}, {"start": 265.74, "end": 265.94, "word": " the", "probability": 0.4990234375}, {"start": 265.94, "end": 266.32, "word": " following", "probability": 0.89111328125}, {"start": 266.32, "end": 266.98, "word": " compound", "probability": 0.9521484375}, {"start": 266.98, "end": 267.84, "word": " سمى", "probability": 0.618408203125}, {"start": 267.84, 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الذرات", "probability": 0.8728841145833334}, {"start": 275.2, "end": 275.32, "word": " و", "probability": 0.5986328125}, {"start": 275.32, "end": 275.68, "word": " أطول", "probability": 0.9119466145833334}, {"start": 275.68, "end": 276.52, "word": " سلسلة", "probability": 0.971923828125}, {"start": 276.52, "end": 276.76, "word": " و", "probability": 0.97265625}, {"start": 276.76, "end": 278.44, "word": " مواقع", "probability": 0.82037353515625}, {"start": 278.44, "end": 279.16, "word": " الذرات", "probability": 0.9669596354166666}, {"start": 279.16, "end": 279.58, "word": " هذا", "probability": 0.87109375}, {"start": 279.58, "end": 279.98, "word": " انكون", "probability": 0.462890625}, {"start": 279.98, "end": 280.14, "word": " من", "probability": 0.98974609375}, {"start": 280.14, "end": 280.4, "word": " كام", "probability": 0.893310546875}, {"start": 280.4, "end": 281.14, "word": " carbon؟", "probability": 0.65087890625}, {"start": 281.14, "end": 282.44, "word": " واحد", "probability": 0.6884765625}, {"start": 282.44, "end": 283.22, "word": " اتنين", "probability": 0.8719482421875}, {"start": 283.22, "end": 283.66, "word": " على", "probability": 0.5576171875}, {"start": 283.66, "end": 283.98, "word": " نمرة", "probability": 0.8367513020833334}, {"start": 283.98, "end": 284.36, "word": " واحد", "probability": 0.991943359375}, {"start": 284.36, "end": 285.06, "word": " عندى", "probability": 0.6455078125}, {"start": 285.06, "end": 286.1, "word": " بروم", "probability": 0.6083577473958334}, {"start": 286.1, "end": 286.78, "word": " و", "probability": 0.95751953125}, {"start": 286.78, "end": 287.26, "word": " floor", "probability": 0.31591796875}, {"start": 287.26, "end": 287.8, "word": " إذا", "probability": 0.7587890625}, {"start": 287.8, "end": 288.14, "word": " هذا", "probability": 0.90087890625}, {"start": 288.14, "end": 288.98, "word": " كمركب", "probability": 0.8948974609375}, {"start": 288.98, "end": 289.94, "word": " وانبرومه", "probability": 0.81376953125}], "temperature": 1.0}, {"id": 12, "seek": 31852, "start": 291.97, "end": 318.53, "text": "وان فلورو اثان واضح هاي carbon one وcarbon two وان برومو وان فلورو اثان الآن بعد هيك بتطلع هل هذا ال carbon في chiral center ولا لأ بمعنى ان في carbon تحمل اربع مجموعات مختلفة", "tokens": [2407, 7649, 6156, 1211, 13063, 2407, 1975, 12984, 7649, 4032, 46958, 5016, 8032, 47302, 5954, 472, 4032, 39294, 732, 4032, 7649, 4724, 2288, 20498, 2407, 4032, 7649, 6156, 1211, 13063, 2407, 1975, 12984, 7649, 6024, 48506, 39182, 39896, 4117, 39894, 9566, 1211, 3615, 8032, 1211, 23758, 2423, 5954, 8978, 23782, 304, 3056, 49429, 5296, 10721, 4724, 2304, 3615, 1863, 7578, 16472, 8978, 5954, 6055, 35571, 1211, 1975, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660], "avg_logprob": -0.24999999245510826, "compression_ratio": 1.611764705882353, "no_speech_prob": 0.0, "words": [{"start": 291.97, "end": 292.39, "word": "وان", "probability": 0.237548828125}, {"start": 292.39, "end": 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" اثان", "probability": 0.9723307291666666}, {"start": 306.65, "end": 307.63, "word": " الآن", "probability": 0.58990478515625}, {"start": 307.63, "end": 308.07, "word": " بعد", "probability": 0.908203125}, {"start": 308.07, "end": 308.67, "word": " هيك", "probability": 0.913818359375}, {"start": 308.67, "end": 309.51, "word": " بتطلع", "probability": 0.892333984375}, {"start": 309.51, "end": 309.95, "word": " هل", "probability": 0.941650390625}, {"start": 309.95, "end": 310.23, "word": " هذا", "probability": 0.93798828125}, {"start": 310.23, "end": 310.47, "word": " ال", "probability": 0.7529296875}, {"start": 310.47, "end": 310.93, "word": " carbon", "probability": 0.86083984375}, {"start": 310.93, "end": 311.47, "word": " في", "probability": 0.974609375}, {"start": 311.47, "end": 312.29, "word": " chiral", "probability": 0.548858642578125}, {"start": 312.29, "end": 312.85, "word": " center", "probability": 0.8662109375}, {"start": 312.85, "end": 313.17, "word": " ولا", 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واضح إنها ال H أقل مجموعة already موجودة للخلف برتب المجموعات التلاتة التانين الأعلى فالأقل فالأقل", "tokens": [2304, 3555, 33599, 25720, 44945, 5016, 9566, 25894, 11296, 8717, 7435, 46007, 11933, 15730, 23758, 9673, 31747, 3555, 39896, 30544, 36764, 24401, 9154, 1975, 2655, 1863, 9957, 35186, 497, 35186, 318, 4724, 26108, 1829, 39894, 9566, 1211, 3615, 14739, 39896, 5551, 4587, 1211, 3714, 7435, 2304, 2407, 27884, 44650, 36520, 3660, 3714, 3555, 33599, 25720, 20666, 39294, 2423, 389, 2423, 11568, 2423, 4123, 2423, 5995, 18, 4032, 46958, 5016, 36145, 11296, 2423, 389, 5551, 4587, 1211, 3714, 7435, 2304, 2407, 27884, 1217, 3714, 29245, 23328, 3660, 24976, 9778, 46538, 4724, 43500, 3555, 9673, 7435, 2304, 45367, 9307, 16712, 1211, 9307, 3660, 16712, 7649, 9957, 16247, 3615, 23942, 6156, 6027, 10721, 4587, 1211, 6156, 6027, 10721, 4587, 1211], "avg_logprob": -0.15174787415791366, "compression_ratio": 1.7322175732217573, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 319.15, 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R", "probability": 0.6181640625}, {"start": 326.01, "end": 326.57, "word": " يا", "probability": 0.9130859375}, {"start": 326.57, "end": 326.97, "word": " S", "probability": 0.9853515625}, {"start": 326.97, "end": 327.59, "word": " باجي", "probability": 0.8819986979166666}, {"start": 327.59, "end": 328.21, "word": " بتطلع", "probability": 0.8275146484375}, {"start": 328.21, "end": 328.69, "word": " أن", "probability": 0.640625}, {"start": 328.69, "end": 328.85, "word": " هي", "probability": 0.46484375}, {"start": 328.85, "end": 329.33, "word": " أقل", "probability": 0.93505859375}, {"start": 329.33, "end": 329.93, "word": " مجموعة", "probability": 0.953125}, {"start": 329.93, "end": 330.55, "word": " متصلة", "probability": 0.9093424479166666}, {"start": 330.55, "end": 331.11, "word": " مباشرة", "probability": 0.9853515625}, {"start": 331.11, "end": 331.61, "word": " بالcarbon", "probability": 0.574951171875}, {"start": 331.61, "end": 331.83, "word": " ال", "probability": 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"probability": 0.6322021484375}, {"start": 828.87, "end": 829.55, "word": " center", "probability": 0.71875}, {"start": 829.55, "end": 830.21, "word": " كمان", "probability": 0.9716796875}, {"start": 830.21, "end": 831.45, "word": " يعني", "probability": 0.890869140625}, {"start": 831.45, "end": 831.59, "word": " في", "probability": 0.9072265625}, {"start": 831.59, "end": 832.29, "word": " شغلتين", "probability": 0.8712890625}, {"start": 832.29, "end": 832.43, "word": " ال", "probability": 0.31689453125}, {"start": 832.43, "end": 832.83, "word": " stereo", "probability": 0.43603515625}, {"start": 832.83, "end": 833.63, "word": " chemistry", "probability": 0.62646484375}, {"start": 833.63, "end": 836.07, "word": " واضح؟", "probability": 0.79486083984375}, {"start": 836.07, "end": 836.25, "word": " مش", "probability": 0.85205078125}, {"start": 836.25, "end": 836.45, "word": " ال", "probability": 0.93017578125}, {"start": 836.45, "end": 836.63, "word": " cis", "probability": 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852.44, "word": " ما", "probability": 0.72509765625}, {"start": 852.44, "end": 852.9, "word": " نتوقف", "probability": 0.85400390625}, {"start": 852.9, "end": 853.0, "word": " في", "probability": 0.45361328125}, {"start": 853.0, "end": 853.08, "word": " ال", "probability": 0.9248046875}, {"start": 853.08, "end": 853.5, "word": " stereo", "probability": 0.61962890625}, {"start": 853.5, "end": 854.22, "word": " chemistry", "probability": 0.64697265625}, {"start": 854.22, "end": 855.42, "word": " خلينا", "probability": 0.8123372395833334}, {"start": 855.42, "end": 856.0, "word": " نشوف", "probability": 0.9698893229166666}, {"start": 856.0, "end": 856.68, "word": " السلسلة", "probability": 0.980224609375}, {"start": 856.68, "end": 857.28, "word": " المركبة", "probability": 0.7537434895833334}, {"start": 857.28, "end": 858.02, "word": " كسلسلة", "probability": 0.95810546875}, {"start": 858.02, "end": 858.22, "word": " ايش", "probability": 0.7298177083333334}, {"start": 858.22, "end": 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2407, 36081, 3224, 1975, 15730, 5296, 7435, 2655, 2423, 497, 2423, 318, 6225, 4117, 3794, 11296, 4032, 1975, 15730, 5296, 7435, 2655, 2423, 318, 2423, 497, 6225, 4117, 3794, 11296, 20193, 5016, 19913, 14407, 20193, 7251, 46456, 46538, 14407, 8978, 25062, 32640, 3660, 35525, 19452, 7251, 46456, 46538, 14407, 8978, 2423, 9307, 7435, 40294], "avg_logprob": -0.15429687534924597, "compression_ratio": 2.076923076923077, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2507.49, "end": 2508.25, "word": "واضح؟", "probability": 0.896484375}, {"start": 2508.25, "end": 2508.65, "word": " يعني", "probability": 0.882568359375}, {"start": 2508.65, "end": 2508.83, "word": " لو", "probability": 0.9638671875}, {"start": 2508.83, "end": 2509.15, "word": " واحدة", "probability": 0.9842122395833334}, {"start": 2509.15, "end": 2509.67, "word": " فتشت", "probability": 0.972412109375}, {"start": 2509.67, "end": 2509.81, "word": " على", "probability": 0.63623046875}, {"start": 2509.81, "end": 2510.45, "word": " الكمبيوتر", "probability": 0.9583984375}, {"start": 2510.45, "end": 2510.57, "word": " و", "probability": 0.66064453125}, {"start": 2510.57, "end": 2511.21, "word": " بتفتش", "probability": 0.7781982421875}, {"start": 2511.21, "end": 2511.61, "word": " ايش", "probability": 0.68017578125}, {"start": 2511.61, "end": 2511.95, "word": " زاوية", "probability": 0.9222412109375}, {"start": 2511.95, "end": 2512.51, "word": " مركب", "probability": 0.7814127604166666}, {"start": 2512.51, "end": 2512.67, "word": " ال", "probability": 0.9599609375}, {"start": 2512.67, "end": 2512.95, "word": " R", "probability": 0.53515625}, {"start": 2512.95, "end": 2513.71, "word": " لجت", "probability": 0.7996419270833334}, {"start": 2513.71, "end": 2514.19, "word": " زاوية", "probability": 0.9873046875}, {"start": 2514.19, "end": 2514.43, "word": " ال", "probability": 0.970703125}, {"start": 2514.43, "end": 2514.77, "word": " S", "probability": 0.98095703125}, {"start": 2514.77, "end": 2515.83, "word": " تبقى", "probability": 0.687347412109375}, {"start": 2515.83, "end": 2515.97, "word": " لها", "probability": 0.76708984375}, {"start": 2515.97, "end": 2516.39, "word": " ساعتين", "probability": 0.957763671875}, {"start": 2516.39, "end": 2516.83, "word": " تفتش", "probability": 0.937744140625}, {"start": 2516.83, "end": 2517.01, "word": " على", "probability": 0.7900390625}, {"start": 2517.01, "end": 2517.51, "word": " مركب", "probability": 0.9853515625}, {"start": 2517.51, "end": 2517.63, "word": " ال", "probability": 0.98974609375}, {"start": 2517.63, "end": 2517.79, "word": " R", "probability": 0.97802734375}, {"start": 2517.79, "end": 2517.99, "word": " قد", "probability": 0.6435546875}, {"start": 2517.99, "end": 2518.17, "word": " ايش", "probability": 0.7909342447916666}, {"start": 2518.17, "end": 2518.81, "word": " زاويته", "probability": 0.93515625}, {"start": 2518.81, "end": 2519.77, "word": " اذا", "probability": 0.661865234375}, {"start": 2519.77, "end": 2520.17, "word": " لجت", "probability": 0.8720703125}, {"start": 2520.17, "end": 2520.43, "word": " ال", "probability": 0.9775390625}, {"start": 2520.43, "end": 2521.55, "word": " R", "probability": 0.97509765625}, {"start": 2521.55, "end": 2522.57, "word": " ال", "probability": 0.54931640625}, {"start": 2522.57, "end": 2522.81, "word": " S", "probability": 0.974609375}, {"start": 2522.81, "end": 2523.17, "word": " عكسها", "probability": 0.981689453125}, {"start": 2523.17, "end": 2523.27, "word": " و", "probability": 0.6875}, {"start": 2523.27, "end": 2523.41, "word": " اذا", "probability": 0.8515625}, {"start": 2523.41, "end": 2523.73, "word": " لجت", "probability": 0.9892578125}, {"start": 2523.73, "end": 2523.87, "word": " ال", "probability": 0.98876953125}, {"start": 2523.87, "end": 2524.25, "word": " S", "probability": 0.9873046875}, {"start": 2524.25, "end": 2524.95, "word": " ال", "probability": 0.92822265625}, {"start": 2524.95, "end": 2525.15, "word": " R", "probability": 0.97314453125}, {"start": 2525.15, "end": 2526.21, "word": " عكسها", "probability": 0.99609375}, {"start": 2526.21, "end": 2527.29, "word": " لاحظوا", "probability": 0.94970703125}, {"start": 2527.29, "end": 2527.55, "word": " لا", "probability": 0.66357421875}, {"start": 2527.55, "end": 2528.37, "word": " يختلفوا", "probability": 0.9892578125}, {"start": 2528.37, "end": 2528.57, "word": " في", "probability": 0.97509765625}, {"start": 2528.57, "end": 2529.45, "word": " القيمة", "probability": 0.9775390625}, {"start": 2529.45, "end": 2530.07, "word": " ولكن", "probability": 0.82080078125}, {"start": 2530.07, "end": 2530.65, "word": " يختلفوا", "probability": 0.98828125}, {"start": 2530.65, "end": 2530.77, "word": " في", "probability": 0.97802734375}, {"start": 2530.77, "end": 2532.97, "word": " الاتجاه", "probability": 0.69482421875}], "temperature": 1.0}, {"id": 109, "seek": 255673, "start": 2533.71, "end": 2556.73, "text": "جربوا وشوفوا كيف هذه المراكبات بتنكتب هدولا خاصيتين لازم يكونوا معروفين عن المراكب ال configuration يحدد من الأولويات و ال rotation يحدد بال إيش بالتجربة باستعمال جهاز البولاري ميتر وبهيك بننهي اليوم ان شاء الله و بنكمل", "tokens": [7435, 25513, 14407, 4032, 8592, 38688, 14407, 9122, 33911, 29538, 9673, 23557, 4117, 3555, 9307, 39894, 1863, 4117, 2655, 3555, 8032, 3215, 12610, 995, 16490, 33546, 36081, 9957, 5296, 31377, 2304, 7251, 30544, 14407, 20449, 32887, 5172, 9957, 18871, 9673, 23557, 4117, 3555, 2423, 11694, 7251, 24401, 3215, 9154, 16247, 12610, 45865, 9307, 4032, 2423, 12447, 7251, 24401, 3215, 20666, 11933, 1829, 8592, 20666, 2655, 7435, 25513, 3660, 4724, 995, 14851, 25957, 6027, 10874, 3224, 31377, 29739, 12610, 9640, 1829, 3714, 36081, 2288, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984, 4032, 44945, 24793, 1211], "avg_logprob": -0.18903186727388233, "compression_ratio": 1.7397260273972603, "no_speech_prob": 0.0, "words": [{"start": 2533.71, "end": 2534.35, "word": "جربوا", "probability": 0.8395182291666666}, {"start": 2534.35, "end": 2534.85, "word": " وشوفوا", "probability": 0.850341796875}, {"start": 2534.85, "end": 2535.09, "word": " كيف", "probability": 0.96142578125}, {"start": 2535.09, "end": 2535.35, "word": " هذه", "probability": 0.84326171875}, {"start": 2535.35, "end": 2536.11, "word": " المراكبات", "probability": 0.882177734375}, {"start": 2536.11, "end": 2536.83, "word": " بتنكتب", "probability": 0.823486328125}, {"start": 2536.83, "end": 2537.49, "word": " هدولا", "probability": 0.676025390625}, {"start": 2537.49, "end": 2538.15, "word": " خاصيتين", "probability": 0.8687744140625}, {"start": 2538.15, "end": 2538.49, "word": " لازم", "probability": 0.9723307291666666}, {"start": 2538.49, "end": 2538.83, "word": " يكونوا", "probability": 0.9729817708333334}, {"start": 2538.83, "end": 2539.75, "word": " معروفين", "probability": 0.9466552734375}, {"start": 2539.75, "end": 2540.51, "word": " عن", "probability": 0.98876953125}, {"start": 2540.51, "end": 2541.29, "word": " المراكب", "probability": 0.9427490234375}, {"start": 2541.29, "end": 2541.69, "word": " ال", "probability": 0.8681640625}, {"start": 2541.69, "end": 2542.51, "word": " configuration", "probability": 0.74755859375}, {"start": 2542.51, "end": 2543.47, "word": " يحدد", "probability": 0.9720052083333334}, {"start": 2543.47, "end": 2543.65, "word": " من", "probability": 0.98681640625}, {"start": 2543.65, "end": 2544.65, "word": " الأولويات", "probability": 0.92626953125}, {"start": 2544.65, "end": 2545.31, "word": " و", "probability": 0.697265625}, {"start": 2545.31, "end": 2545.73, "word": " ال", "probability": 0.8798828125}, {"start": 2545.73, "end": 2546.27, "word": " rotation", "probability": 0.990234375}, {"start": 2546.27, "end": 2547.85, "word": " يحدد", "probability": 0.98828125}, {"start": 2547.85, "end": 2548.07, "word": " بال", "probability": 0.8896484375}, {"start": 2548.07, "end": 2548.49, "word": " إيش", "probability": 0.6964518229166666}, {"start": 2548.49, "end": 2550.07, "word": " بالتجربة", "probability": 0.901953125}, {"start": 2550.07, "end": 2550.89, "word": " باستعمال", "probability": 0.96494140625}, {"start": 2550.89, "end": 2551.59, "word": " جهاز", "probability": 0.9752604166666666}, {"start": 2551.59, "end": 2552.85, "word": " البولاري", "probability": 0.7064208984375}, {"start": 2552.85, "end": 2553.27, "word": " ميتر", "probability": 0.7228190104166666}, {"start": 2553.27, "end": 2554.67, "word": " وبهيك", "probability": 0.8487548828125}, {"start": 2554.67, "end": 2555.43, "word": " بننهي", "probability": 0.912353515625}, {"start": 2555.43, "end": 2555.79, "word": " اليوم", "probability": 0.962890625}, {"start": 2555.79, "end": 2555.93, "word": " ان", "probability": 0.224365234375}, {"start": 2555.93, "end": 2556.13, "word": " شاء", "probability": 0.966064453125}, {"start": 2556.13, "end": 2556.19, "word": " الله", "probability": 0.955078125}, {"start": 2556.19, "end": 2556.29, "word": " و", "probability": 0.74853515625}, {"start": 2556.29, "end": 2556.73, "word": " بنكمل", "probability": 0.8419596354166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2557.562, "duration_after_vad": 2469.1349999999925}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..50788cd22a88b80dd510c57a69d3fc6fc2612d61
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tRXl66rgvqA_raw.srt
@@ -0,0 +1,1912 @@
+1
+00:00:21,400 --> 00:00:26,380
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry
+
+2
+00:00:26,380 --> 00:00:31,980
+اللى بدأنا فيه المرة الماضية المرة الماضية اتكلمنا
+
+3
+00:00:31,980 --> 00:00:36,300
+طبعا على تصنيف ال isomers ايش معنى structural
+
+4
+00:00:36,300 --> 00:00:39,980
+isomers و stereo isomers وقولنا ان ال stereo
+
+5
+00:00:39,980 --> 00:00:44,850
+isomers نوعينانانشو مارس ودياستيريو مارس
+
+6
+00:00:44,850 --> 00:00:48,070
+الدياستيريو مارس كنا اتكلمنا عنهم سابق و نعطينا
+
+7
+00:00:48,070 --> 00:00:52,510
+عنهم امثلة من ال CC trans compounds و ما إلى ذلك
+
+8
+00:00:52,510 --> 00:00:57,130
+عرفنا بالظبط ايش بنعنى بانانشو مارس طبعا جزء من
+
+9
+00:00:57,130 --> 00:01:02,290
+الموضوع ان نكون فاهمين علاقة المركبات بعضها بعض من
+
+10
+00:01:02,290 --> 00:01:08,040
+خلال المرأة فإذا كانت المركبات زي ما حكيناnon
+
+11
+00:01:08,040 --> 00:01:11,540
+-sober imposible mirror image stereo isomers هذوله
+
+12
+00:01:11,540 --> 00:01:16,280
+سمناهم إيش Inertiomers و بتكلمنا عن إنه هذه
+
+13
+00:01:16,280 --> 00:01:20,020
+الإمكانية ممكن تكون موجودة لما يكون عند كايرال
+
+14
+00:01:20,020 --> 00:01:26,080
+سنتر معنى كايرال سنتر هي ذرة كربون تحمل أربع
+
+15
+00:01:26,080 --> 00:01:30,780
+مجموعات مختلفة هي مثلا عندنا الآن أربع مجموعات
+
+16
+00:01:30,780 --> 00:01:34,440
+مختلفة يعني إذا بتلاحظوا هذا الكربون عادة الكايرال
+
+17
+00:01:34,440 --> 00:01:40,410
+سنتر بنحطلها نجمةهذا الكربون بتحمل مجموعة و بتحمل
+
+18
+00:01:40,410 --> 00:01:44,090
+كربون متصلة بالدوبل بوند و بتحمل CH2 و بتحمل H
+
+19
+00:01:44,090 --> 00:01:49,850
+هذول أربع مجموعات مختلفة مع ذلك لو اتطلعنا في كل
+
+20
+00:01:49,850 --> 00:01:54,690
+الجزيء مافيش غير هذا الكربون هذا المثال أيضا لو
+
+21
+00:01:54,690 --> 00:01:58,610
+بتطلع الكربون اللي هنا Cl, Methyl, CH2, CH2,
+
+22
+00:01:58,650 --> 00:02:02,950
+Potassium و H أربع مجموعات مختلفة فهذا في منه
+
+23
+00:02:02,950 --> 00:02:09,370
+مركبين ROSهذا في منه مركبين R وS اي مركب مافيش فيه
+
+24
+00:02:09,370 --> 00:02:13,050
+اربع مجموعات مختلفة حوالين carbon هيكون منه ايش
+
+25
+00:02:13,050 --> 00:02:20,370
+مركب مركب واحد فقط الان كان ضروري جدا نقدر نميز
+
+26
+00:02:20,370 --> 00:02:25,490
+المركبين وقلنا ان التمييز بينهم من خلال ال
+
+27
+00:02:25,490 --> 00:02:32,090
+configuration ال configuration احدد 1R 1S الطريقة
+
+28
+00:02:32,610 --> 00:02:36,170
+انه انا امسك المركب .. انه انا امسك المركب اخلى
+
+29
+00:02:36,170 --> 00:02:41,270
+المجموعة الأقل للخلف و اتحرك حسب الأولويات اللى
+
+30
+00:02:41,270 --> 00:02:45,410
+اتعلمناها اللى كان انجلد برولوج رولز إذا بتحرك مع
+
+31
+00:02:45,410 --> 00:02:50,390
+عقاري بالساعة المركب بعطي وصف R وإذا بتحرك عكس
+
+32
+00:02:50,390 --> 00:02:55,000
+عقاري بالساعة بعطي المركب الوصفS هذا الكلام إذا
+
+33
+00:02:55,000 --> 00:02:59,880
+فيه معنى model إذا مافيش معنى model إذا مافيش معنى
+
+34
+00:02:59,880 --> 00:03:05,080
+model بدنا نتذكر إنه إحنا بنرسم المركب بهذا الشكل
+
+35
+00:03:05,080 --> 00:03:10,240
+واتفقنا إنه مش planner المركب يعني لما نرسمه زي
+
+36
+00:03:10,240 --> 00:03:15,040
+هيك هو حقيقة شكل فراغي بهذا الشكل في مجمعتين
+
+37
+00:03:15,040 --> 00:03:21,470
+للأمام وفي مجمعتين للخلففخلّينا نضل مركزين كتير
+
+38
+00:03:21,470 --> 00:03:25,410
+على هذه النقطة أن هذه المجموعة اللي موجودة هنا أو
+
+39
+00:03:25,410 --> 00:03:31,070
+هنا هي للأمام و المجموعة اللي موجودة هنا هي للخلف
+
+40
+00:03:31,070 --> 00:03:37,580
+بناء على ذلك لو أقل مجموعة وجدت على هذا المحورفهي
+
+41
+00:03:37,580 --> 00:03:42,180
+للخلف بتحرك في التلت مجموعات التانين الأعلى فالأقل
+
+42
+00:03:42,180 --> 00:03:46,080
+فالأقل وبكتب ال configuration مباشرة الآن لو أقل
+
+43
+00:03:46,080 --> 00:03:50,760
+مجموعة وجدت على الجنبين فهي للأمام يعني نتيجتها
+
+44
+00:03:50,760 --> 00:03:56,200
+هتطلع معكوسة وبناء على ذلك هتحرك في التلت مجموعات
+
+45
+00:03:56,200 --> 00:04:01,500
+التانين و أكتب عكس اللي بيطلع معاه عشان أصحح أن
+
+46
+00:04:01,500 --> 00:04:06,850
+هذه المجموعة أساسا مرسومة للأماملو افترضنا نعمل
+
+47
+00:04:06,850 --> 00:04:10,810
+مثال ان أكد فيه هذه الفكرة خلّينا نبدأ مثلا
+
+48
+00:04:10,810 --> 00:04:16,790
+بمجموعة اقل مجموعة تكون هنا يعني لو قولنا HPRCH3
+
+49
+00:04:16,790 --> 00:04:19,670
+مثلا floor okay
+
+50
+00:04:21,380 --> 00:04:25,520
+لحظوا هذا المركب لو بهذا الشكل إجيانا في الامتحان
+
+51
+00:04:25,520 --> 00:04:29,640
+name the following compound سمى المركب هذا طبعا
+
+52
+00:04:29,640 --> 00:04:34,320
+أول شي بدنا نسميه الكيميا العادية اللي هي تحديد
+
+53
+00:04:34,320 --> 00:04:40,140
+الذرات و أطول سلسلة و مواقع الذرات هذا انكون من
+
+54
+00:04:40,140 --> 00:04:46,780
+كام carbon؟ واحد اتنين على نمرة واحد عندى بروم و
+
+55
+00:04:46,780 --> 00:04:57,470
+floor إذا هذا كمركب وانبرومهوان فلورو اثان
+
+56
+00:04:57,470 --> 00:05:05,390
+واضح هاي carbon one وcarbon two وان برومو وان
+
+57
+00:05:05,390 --> 00:05:11,470
+فلورو اثان الآن بعد هيك بتطلع هل هذا ال carbon في
+
+58
+00:05:11,470 --> 00:05:17,350
+chiral center ولا لأ بمعنى ان في carbon تحمل اربع
+
+59
+00:05:17,350 --> 00:05:22,810
+مجموعات مختلفةمباشرة بنحط عليها نجمة إذا هذا
+
+60
+00:05:22,810 --> 00:05:28,690
+المركب هيكون واحد من اتنين يا R يا S باجي بتطلع أن
+
+61
+00:05:28,690 --> 00:05:33,290
+هي أقل مجموعة متصلة مباشرة بالcarbon ال H ال PR ال
+
+62
+00:05:33,290 --> 00:05:38,650
+floor ال CH3 واضح إنها ال H أقل مجموعة already
+
+63
+00:05:38,650 --> 00:05:43,650
+موجودة للخلف برتب المجموعات التلاتة التانين الأعلى
+
+64
+00:05:43,650 --> 00:05:50,460
+فالأقل فالأقلطبعا الأعلى لبروم بعدها لفلور بعدها
+
+65
+00:05:50,460 --> 00:05:56,960
+الكاربون إذا هاي واحد هاي تانين هاي تلاتة و بتحرك
+
+66
+00:05:56,960 --> 00:06:04,200
+واحد اتنين تلاتة كيف أنا ماشي؟ عكس عقارب الساعة
+
+67
+00:06:04,200 --> 00:06:10,880
+إذا هذا المركب S هيك بيصير الاسم تبعه كامل هذا
+
+68
+00:06:10,880 --> 00:06:18,070
+المركب S one bromo one floro E2واضح الفكرة؟ خلينا
+
+69
+00:06:18,070 --> 00:06:24,330
+ناخد مثال او مثلين ان اكد على هذه النقطة بيهمني
+
+70
+00:06:24,330 --> 00:06:29,770
+يصير انكم اتقان لهذه النقطة تحديدا لو افترضنا اننا
+
+71
+00:06:29,770 --> 00:06:32,410
+رسمنا مركب بهذا الشكل
+
+72
+00:06:48,630 --> 00:07:00,430
+وإجانة هذا المركب وسم المركب تسمية كاملة لحظوا
+
+73
+00:07:00,430 --> 00:07:04,830
+الناس المستعجلة قاعدة بتعطي إجابات غلط الكيميا
+
+74
+00:07:04,830 --> 00:07:09,870
+علم، systematic، بدنا نمشي فيه خطوة خطوة بدنا نقول
+
+75
+00:07:09,870 --> 00:07:16,690
+في الأول ما نوع المركبالكيل في double point إذا
+
+76
+00:07:16,690 --> 00:07:20,690
+يجب البحث عن أطول سلسلة تحتوي على ال double point
+
+77
+00:07:20,690 --> 00:07:23,770
+واحد،
+
+78
+00:07:23,770 --> 00:07:29,450
+اتنين، تلاتة، أربعة، خمسة إذا المركب اللي عندي
+
+79
+00:07:29,450 --> 00:07:35,870
+حقيقة بنتين هي أطول سلسلة أي بنتين؟
+
+80
+00:07:38,710 --> 00:07:42,690
+one بنتين يعني ال double bond اللي فيه على موقع
+
+81
+00:07:42,690 --> 00:07:50,690
+واحد اذا هذا one بنتين من وين الترقيم بالتأكيد
+
+82
+00:07:50,690 --> 00:07:56,650
+واحد اتنين تلاتة اربعة خمسة الان هذا عليه
+
+83
+00:07:56,650 --> 00:08:04,560
+substituentsعلى موقع تلاتة اكلور وعلى موقع تلاتة
+
+84
+00:08:04,560 --> 00:08:09,480
+مثل اذا ايش اسمه كمركب بيصير تلاتة اكلور تلاتة مثل
+
+85
+00:08:09,480 --> 00:08:14,860
+تلاتة اكلور تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+86
+00:08:14,860 --> 00:08:18,840
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+87
+00:08:18,840 --> 00:08:21,280
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+88
+00:08:21,280 --> 00:08:22,140
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+89
+00:08:22,140 --> 00:08:23,100
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة مثل تلاتة
+
+90
+00:08:23,100 --> 00:08:28,440
+مثل تلاتة مثل تلاتة مثل تلاتة مثل تل
+
+91
+00:08:29,570 --> 00:08:35,150
+مافيش غيرها نهائيًا، مافيش غيرها نهائيًا، الآن بدي
+
+92
+00:08:35,150 --> 00:08:38,410
+أطلع على المجموعات الأربعة اللي على هذا ال carbon
+
+93
+00:08:38,410 --> 00:08:44,430
+أنهي أقل مجموعة، عندي halogenو carbon و carbon و
+
+94
+00:08:44,430 --> 00:08:49,810
+carbon أكيد ال halogen هي المجموعة الأعلى نمرة
+
+95
+00:08:49,810 --> 00:08:54,650
+واحد خلصت من ال halogen الآن ال carbons carbon
+
+96
+00:08:54,650 --> 00:08:58,210
+متصلة ب اتنين carbons ولا carbon متصلة ب carbon
+
+97
+00:08:58,210 --> 00:09:04,710
+ولا carbon متصلة ب etches المتصلة بال carbon مرتين
+
+98
+00:09:04,710 --> 00:09:13,160
+هي نمرة اتنين هذه اللي بيبين ك ethylنمرة 3 هذه
+
+99
+00:09:13,160 --> 00:09:22,700
+نمرة 2 هذه نمرة 4 الألوان أصغر مجموعة ال CH3 في
+
+100
+00:09:22,700 --> 00:09:28,500
+هذه الحالة أصغر مجموعة ال CH3 لاحظوا اكتبوا جنبه
+
+101
+00:09:28,500 --> 00:09:33,340
+عشان ما تغلطوش موجودة للأمام إذا اللي بيطلع عندكم
+
+102
+00:09:33,340 --> 00:09:36,500
+بس تكتبوا عكسه عشان تطلعوا ال configuration الصح
+
+103
+00:09:37,530 --> 00:09:45,610
+واضح؟ فلما انا بمشي واحد اتنين تلاتة R اذا S هذا
+
+104
+00:09:45,610 --> 00:09:59,190
+المركب زيه اللي هيكون اسمه الكلام
+
+105
+00:09:59,190 --> 00:10:07,570
+جميل وكمان مثال بضر ولا ما بضر؟كمان مثال مابضرش
+
+106
+00:10:07,570 --> 00:10:16,830
+خلنا ناخد كمان مثال أي سؤال على السريع ايه
+
+107
+00:10:16,830 --> 00:10:24,390
+السؤال؟ السبق
+
+108
+00:10:24,390 --> 00:10:29,130
+اتفقنا العلم كامل و هذا الكلام مش موضوع ان نسأل
+
+109
+00:10:29,130 --> 00:10:34,710
+عنه ايش اعمل في الامتحان و كيف اسلحالجواب زي هيك
+
+110
+00:10:34,710 --> 00:10:39,990
+كامل، الآن ما عدا هيك العشرة بتصير تمانية و سبعة و
+
+111
+00:10:39,990 --> 00:10:45,690
+ستة، هذا بيبطل موضوعكم أستاذ ليش رقمت هناك اتنين و
+
+112
+00:10:45,690 --> 00:10:50,920
+هالتلاتة؟ الأجين و الأتلاتة عايشون؟هذا الكلام سبق
+
+113
+00:10:50,920 --> 00:10:55,620
+أننا أخدناه لما كنا بنحكي عن كان English Dibrelog
+
+114
+00:10:55,620 --> 00:11:01,360
+Rules والأصل أن الطالب يكون متذكره من هذه المنطقة،
+
+115
+00:11:01,360 --> 00:11:06,720
+يكون مراجع ومتذكر كويس، الآن هذه carbon تتصل
+
+116
+00:11:06,720 --> 00:11:14,560
+بماذا؟ بH و بcarbonو ب carbon هذه ال carbon تتصل
+
+117
+00:11:14,560 --> 00:11:20,040
+بماذا؟ ب H و ب carbon لاحظوا الطالب اللي مابيرجعش
+
+118
+00:11:20,040 --> 00:11:27,730
+كويس بيجي يسأل في نقطةقديمة الكيميا مبنية على بعض
+
+119
+00:11:27,730 --> 00:11:32,910
+يعني في هذا المثال جيبنا طول السلسلة من chapter ال
+
+120
+00:11:32,910 --> 00:11:35,490
+alkanes جيبنا ال double bond و مكانها من chapter
+
+121
+00:11:35,490 --> 00:11:38,830
+ال alkanes جيبنا ترتيب الأولويات من chapter ال
+
+122
+00:11:38,830 --> 00:11:42,970
+alkanes جيبنا ال R و ال S من chapter خمسةالان
+
+123
+00:11:42,970 --> 00:11:47,870
+مابنقدرش احنا ننسى الكلام السابق اللى اتعلمناه
+
+124
+00:11:47,870 --> 00:11:52,490
+واضح هذه النقطة خلينا نعطى مثال تانى لو مثلا اجينا
+
+125
+00:11:52,490 --> 00:12:02,610
+كتبنا carbon C triple bond C CH3 وحطينا كمان هنا
+
+126
+00:12:02,610 --> 00:12:12,350
+CH3 وحطينا كمان هنا على سبيل المثالخليها دي double
+
+127
+00:12:12,350 --> 00:12:18,050
+bond زي
+
+128
+00:12:18,050 --> 00:12:21,050
+هيك و حطينا هنا chlorine
+
+129
+00:12:26,900 --> 00:12:31,620
+لاحظوا هذا مركّب بتكون تعرفوا في الأول تتأملوا
+
+130
+00:12:31,620 --> 00:12:36,920
+بشكل عام على أي تسمية بتكون تسموها البعض هيفكر أنه
+
+131
+00:12:36,920 --> 00:12:41,460
+فيه بنزين لكن صعب أن نلاقي اسم لهذه المجموعة لذلك
+
+132
+00:12:41,460 --> 00:12:47,240
+ما بنسميه كمشتقة بنزين بنبحث عنه كمركب متسلسل
+
+133
+00:12:47,240 --> 00:12:52,880
+كمركب متسلسل هذاإتنين بنتين .. إتنين بنتين ..
+
+134
+00:12:52,880 --> 00:13:01,300
+إتنين بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين
+
+135
+00:13:01,300 --> 00:13:01,720
+بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين بنتين
+
+136
+00:13:01,720 --> 00:13:02,400
+.. إتنين بنتين .. إتنين بنتين .. إتنين بنتين ..
+
+137
+00:13:02,400 --> 00:13:02,520
+إتنين بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين
+
+138
+00:13:02,520 --> 00:13:02,960
+بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين بنتين
+
+139
+00:13:02,960 --> 00:13:03,100
+.. إتنين بنتين .. إتنين بنتين .. إتنين بنتين ..
+
+140
+00:13:03,100 --> 00:13:05,820
+إتنين بنتين .. إتنين بنتين .. إتنين بنتين .. إتنين
+
+141
+00:13:05,820 --> 00:13:11,200
+بنتين .. إتنين بنتين .. إتنين بنتين ..يكون مبين في
+
+142
+00:13:11,200 --> 00:13:15,860
+الـ S والـ Trans والـ Z والـ E مثلا بهذا الشكل هاي
+
+143
+00:13:15,860 --> 00:13:21,360
+carbon ممكن تلاقوه بهذا الشكل تجمع كل الكلام اللي
+
+144
+00:13:21,360 --> 00:13:26,540
+انتوا اتعلمتهوا
+
+145
+00:13:26,540 --> 00:13:33,020
+الان
+
+146
+00:13:33,020 --> 00:13:40,390
+لاحظوا هذا المركب ايش موجود فيه ال keenوالألكين في
+
+147
+00:13:40,390 --> 00:13:44,110
+مجموعتين مختلفات و مجموعتين مختلفات إذا حتبدوا
+
+148
+00:13:44,110 --> 00:13:49,550
+تفكروا بالـ Cis و Trans أو Z و E في chiral center
+
+149
+00:13:49,550 --> 00:13:56,250
+كمان يعني في شغلتين ال stereo chemistry واضح؟ مش
+
+150
+00:13:56,250 --> 00:14:01,580
+ال cis و ال trans بيعطيني ال diastereomers ال Zو
+
+151
+00:14:01,580 --> 00:14:04,280
+ال E أو ال cis و ال trans و ال chiral center
+
+152
+00:14:04,280 --> 00:14:09,460
+بيعطيني R و S لان هذا في bubble bond و في ال
+
+153
+00:14:09,460 --> 00:14:13,500
+chiral center موجودة هنا قبل ما نتوقف في ال stereo
+
+154
+00:14:13,500 --> 00:14:18,220
+chemistry خلينا نشوف السلسلة المركبة كسلسلة ايش
+
+155
+00:14:18,220 --> 00:14:24,670
+بده اسمي انابدي أطول سلسلة مزال بسمع كلمات بنتين
+
+156
+00:14:24,670 --> 00:14:31,450
+واحد اتنين تلاتة اربعة خمسة هي أطول سلسلة و العد
+
+157
+00:14:31,450 --> 00:14:37,690
+من هنا عشان نخليها ايش two بنتين اذا هنا كلمة two
+
+158
+00:14:37,690 --> 00:14:45,810
+بنتين سليمة الان هذه أطول سلسلة ايش بتحمل بإمكانك
+
+159
+00:14:45,810 --> 00:14:54,360
+تطلع نهاية كسلسلةهذه كلها السلسلة على موقع اربعة
+
+160
+00:14:54,360 --> 00:15:01,540
+عندى فيها four chloro four
+
+161
+00:15:01,540 --> 00:15:09,440
+phenyl four chloro four phenyl two pentene الان
+
+162
+00:15:09,440 --> 00:15:15,990
+خلصت المواقع دل عندى جزءالاستيريو كيميسترا جزء
+
+163
+00:15:15,990 --> 00:15:21,990
+الاستيريو كيميسترا كيف شكل المجموعات هنا هنجي نقول
+
+164
+00:15:21,990 --> 00:15:29,530
+اكش ولا مثل؟ مين اعلى؟ مثل واضحة اذا هذه المجموعة
+
+165
+00:15:29,530 --> 00:15:33,330
+خلينا نقول الاعلى الكاربون هذا اكش ولا كاربون؟
+
+166
+00:15:33,330 --> 00:15:37,530
+كاربون هذا الاعلى الان الاعلى على جهة واحدة ولا
+
+167
+00:15:37,530 --> 00:15:43,640
+على جهتين متعاكستين؟على جهتين متعاكستين هاي هذه
+
+168
+00:15:43,640 --> 00:15:50,000
+على جهة وهذه على الجهة التانية إذا المركب هذا E او
+
+169
+00:15:50,000 --> 00:15:55,480
+Trans احنا قولنا إذا المركب فيه شوية تعمل E الآن
+
+170
+00:15:55,480 --> 00:16:02,220
+ضال عندى حوالين ال chiral center هالمركب هذا R ولا
+
+171
+00:16:02,220 --> 00:16:09,240
+Sواضح؟ بدي أجي أطلع على هذه الـ carbon و أقول وين
+
+172
+00:16:09,240 --> 00:16:13,960
+أقل مجموعة و وين أعلى مجموعة الان الهالوجين كاربون
+
+173
+00:16:13,960 --> 00:16:22,040
+كاربون كاربون إذا نمرة واحد الهالوجين بعد هيك
+
+174
+00:16:22,040 --> 00:16:28,160
+خلّينا نتذكر إنه في البنزينة الكاربون ما بنشتغل
+
+175
+00:16:28,160 --> 00:16:32,060
+على مجموع إطلاقا للناس اللي بدوا يقولوا C6H6 بدوا
+
+176
+00:16:32,060 --> 00:16:36,930
+يمشوا بالاتجاه الغلطلأ لأ أنا بشوفها متصلة بإيش
+
+177
+00:16:36,930 --> 00:16:41,970
+الآن هذه ال carbon واحدة تقول يا متصلة بكم ذرة
+
+178
+00:16:41,970 --> 00:16:46,830
+متصلة ب carbon و ب carbon تانية من خلال ال double
+
+179
+00:16:46,830 --> 00:16:51,250
+bond و ب carbon تالتة هي ال carbon هذه متصلة ب
+
+180
+00:16:51,250 --> 00:16:55,550
+carbon كمان carbon ال double bond هيك منفسرة كمان
+
+181
+00:16:55,550 --> 00:16:59,670
+carbon متصلة تلت مرات بال carbon طب هذه ال carbon
+
+182
+00:16:59,670 --> 00:17:06,550
+ب carbonوب carbon وب H إذا مين أعلى لمتصلة بتلاتة
+
+183
+00:17:06,550 --> 00:17:10,950
+carbon ولا لمتصلة بتنين carbon اه هذه متصلة carbon
+
+184
+00:17:10,950 --> 00:17:16,030
+اتنين تلاتة انا واحد اتنين هذه متصلة بتلاتة H إذا
+
+185
+00:17:16,030 --> 00:17:21,590
+هذه أقل المجموعات مين أعلى مجموعة هتكون في التلاتة
+
+186
+00:17:21,590 --> 00:17:29,610
+اللي ضاله البنزينة هتاخد نمرة اتنين بعدها هذه
+
+187
+00:17:29,610 --> 00:17:38,780
+المجموعة كلهاهتاخد نمرة تلاتة بعدها هذه المجموعة
+
+188
+00:17:38,780 --> 00:17:47,680
+نمرة أربعة الآن أي مجموعة الأصغر موجودة للخالق إذا
+
+189
+00:17:47,680 --> 00:17:52,300
+بدي أمشي واحد اتنين تلاتة أشوف أنا مع أقارب الساعة
+
+190
+00:17:52,300 --> 00:17:58,240
+ولا ضد أقارب الساعة واحد اتنين تلاتة هاي واحد كيف
+
+191
+00:17:58,240 --> 00:18:00,960
+بمشي على اتنين اتنين
+
+192
+00:18:02,730 --> 00:18:11,410
+تلاتة واحد اثنين تلاتة اذا المركب اللي عنده S واضح
+
+193
+00:18:11,410 --> 00:18:14,610
+S
+
+194
+00:18:14,610 --> 00:18:25,070
+و E جيبت كل ال stereo chemistry تبعته ال
+
+195
+00:18:25,070 --> 00:18:31,250
+A درس في chapter تلاتة بترجعي في chapter تلاتةلأنه
+
+196
+00:18:31,250 --> 00:18:36,190
+برضه الناس بتفرج علينا على ال video لازم يكون واضح
+
+197
+00:18:36,190 --> 00:18:41,690
+للناس حتى اللي بيسمعوني بالخارج أنه الشيء السابق
+
+198
+00:18:41,690 --> 00:18:47,730
+ما كان فهمه أن يراجع سابقا و لذلك نعلم احنا في
+
+199
+00:18:47,730 --> 00:18:53,020
+التربية و نتعلم أن نعلم الطلابأي معلومة الطالب
+
+200
+00:18:53,020 --> 00:18:57,700
+مابفهمهاش وانا بشرحها، إذا عنده مشكلة في المعلومة
+
+201
+00:18:57,700 --> 00:19:02,780
+السابقة، الآن المعلومة السابقة طبيعة الجامعة أن
+
+202
+00:19:02,780 --> 00:19:07,420
+المدرس لا يعيد المعلومة السابقةفي دارس موجود الآن
+
+203
+00:19:07,420 --> 00:19:13,120
+يعني إذا كان المدرس درسكم معنى الديمقراطية سابقا و
+
+204
+00:19:13,120 --> 00:19:17,500
+بدأ الآن يحكي عن علاقة الديمقراطية بالرأسمالية مش
+
+205
+00:19:17,500 --> 00:19:20,600
+معقول أنه يروح يفتح محاضرة جديدة بعنوان
+
+206
+00:19:20,600 --> 00:19:24,380
+الديمقراطية و هو بده يشرح علاقة الديمقراطية
+
+207
+00:19:24,380 --> 00:19:30,630
+بالرأسماليةفارجو أن ننتبه لهذا الأمر جيدا، بظل
+
+208
+00:19:30,630 --> 00:19:34,650
+دائما عند الطالب أسئلة بيرجع لوحده في البيت
+
+209
+00:19:34,650 --> 00:19:39,370
+بيجاوبها أو بيمر على أستاذ بخارج وقت الحصة، ليس من
+
+210
+00:19:39,370 --> 00:19:44,990
+الضروري أن يفهم كل شيء في هذه اللحظة، بالذات إذا
+
+211
+00:19:44,990 --> 00:19:51,100
+الأمر تعلق بمجموعة .. بمعلومة سابقة هو نسيهاهيك
+
+212
+00:19:51,100 --> 00:19:56,020
+الجامعة وهيك الدنيا وفي كل الأحوال انتوا بتكونوا
+
+213
+00:19:56,020 --> 00:20:00,420
+تتعودوا على نظام الجامعة لأنكوا طلاب جدود سنة أولى
+
+214
+00:20:00,420 --> 00:20:07,870
+بس المدرس مش لازم يرجع فيكم لنظام المدرسةأمر طبيعي
+
+215
+00:20:07,870 --> 00:20:11,870
+في الجامعة انه بتسمعوا بتحسوا ان خانتكوا معلومة
+
+216
+00:20:11,870 --> 00:20:17,270
+معلومتين موجود عندكم مراجعة بهدوء لها المعلومة
+
+217
+00:20:17,270 --> 00:20:21,670
+السابقة او في اسوأ الاحتمالات ماحصلش بتروحوا على
+
+218
+00:20:21,670 --> 00:20:25,850
+المكتب عند المدرس تفهم المعلومة السابقة فارجو ان
+
+219
+00:20:25,850 --> 00:20:33,470
+ننتبه لهذا الأمر جيدا الان اتفقنا احنا ان في عندنا
+
+220
+00:20:33,470 --> 00:20:39,650
+مركباتROS يعني لو عندي chiral center كام مركب عندى
+
+221
+00:20:39,650 --> 00:20:45,070
+اتنين هدولة كل عنهم enantiomers الان بتهمنا شغلة
+
+222
+00:20:45,070 --> 00:20:51,910
+ايش العلاقة بين ال enantiomers من ناحية الخواص
+
+223
+00:20:51,910 --> 00:20:56,790
+الفيزيائية و من ناحية الخواص الكيميائية يمكن هذا
+
+224
+00:20:56,790 --> 00:21:02,770
+ال slide موجودة شوية للامام هتلاحظوا بس احنا بدنا
+
+225
+00:21:02,770 --> 00:21:08,160
+نشوف ال enantiomers دولةمن ناحية خواص فيزيائية و
+
+226
+00:21:08,160 --> 00:21:11,740
+من ناحية خواص كيميائية بإيش بيختلفوا و بعد ذلك
+
+227
+00:21:11,740 --> 00:21:15,440
+برضه بدي أشوف ال diastereomers من ناحية خواص
+
+228
+00:21:15,440 --> 00:21:20,980
+فيزيائية و من ناحية خواص كيميائية بإيش بيختلفوا
+
+229
+00:21:20,980 --> 00:21:29,640
+واضح؟ الآن طبعا ع السريع بتكونوا عارفين إيش معنى
+
+230
+00:21:29,640 --> 00:21:35,010
+خواص فيزيائية و إيش معنى خواص كيميائيةاحنا بنقول
+
+231
+00:21:35,010 --> 00:21:40,290
+الخواص الفيزيائية هي الخواص التي يمكن أن نقيسها
+
+232
+00:21:40,290 --> 00:21:45,310
+دون أن نغير في تركيب المادة يعني المادة بتضال زي
+
+233
+00:21:45,310 --> 00:21:51,190
+ما هي على سبيل المثال عندي ماءبدي أقيسله الحجم،
+
+234
+00:21:51,190 --> 00:21:55,170
+قست الحجم بعد ما قسته، الماء ما زال زي ما هو ولا
+
+235
+00:21:55,170 --> 00:22:00,770
+لأ؟ بدي أقيسله الكتلة، قست الكتلة، الماء ما زال زي
+
+236
+00:22:00,770 --> 00:22:05,310
+ما هو ولا لأ؟ بدي أقيسله الكثافة، قسمت الكتلة على
+
+237
+00:22:05,310 --> 00:22:11,190
+الحجم، والماء ما زالة؟موجودا بدا قص معامل الانكسار
+
+238
+00:22:11,190 --> 00:22:17,530
+جبت الماء و حطيته في وعاء و أسقطت عليه الضوء و قصت
+
+239
+00:22:17,530 --> 00:22:21,910
+زاوية الانكسار او معامل الانكسار بعد هيك لو بد
+
+240
+00:22:21,910 --> 00:22:26,310
+الماء الماء ما زال موجودا اذا كل القياسات عملتها
+
+241
+00:22:26,310 --> 00:22:30,850
+من غير ما اغير في تركيب الماء بهذا الشكل تكون
+
+242
+00:22:30,850 --> 00:22:35,790
+الخاصيةفيزيائية إذا ال physical probity is a
+
+243
+00:22:35,790 --> 00:22:39,350
+probity that can be measured without changing the
+
+244
+00:22:39,350 --> 00:22:42,790
+chemical makeup of the substance لكن لو كنت أقول
+
+245
+00:22:42,790 --> 00:22:46,010
+إيش يعني chemical probity ال chemical probity
+
+246
+00:22:46,010 --> 00:22:50,530
+تفاعل والتفاعل يغير المادة أبسط تعريف لل chemical
+
+247
+00:22:50,530 --> 00:22:54,930
+probity هي تفاعل يعني لو مثلا إجيت قولت الماء مع
+
+248
+00:22:54,930 --> 00:22:59,300
+الصوديومبقول والله خلّينا نحط صوديوم على ميّه
+
+249
+00:22:59,300 --> 00:23:03,300
+حطينا صوديوم على كمية ميّه صغيرة بحذر لأنه التفاعل
+
+250
+00:23:03,300 --> 00:23:08,160
+خطير لاحظنا أنه بينطلق غاز هيدروجين وممكن كمان
+
+251
+00:23:08,160 --> 00:23:12,180
+يشتعل مع حرارة التفاعل ويعمل عندنا فرقعة وبتكون
+
+252
+00:23:12,180 --> 00:23:16,000
+هيدروكسيد الصوديوم وما إلى ذلك الآن بعد ما خلصنا
+
+253
+00:23:16,000 --> 00:23:21,940
+هالكلام اجينا قلنالكم لو سمحتوا راجعولنا الميّهأي
+
+254
+00:23:21,940 --> 00:23:26,860
+مية؟ المية اتفعلت المية صارت هيدروكسيد السوديوم
+
+255
+00:23:26,860 --> 00:23:31,080
+إذا أنا لما درست الخاصية الكيميائية فعلت المية ف
+
+256
+00:23:32,350 --> 00:23:37,010
+خلصت الميه، اتغيرت تركيبها، لكن لما جابلي شوية جسد
+
+257
+00:23:37,010 --> 00:23:41,810
+خمس، ست خواص فيزيائية كتلة وحجم ومعامل انكسار وما
+
+258
+00:23:41,810 --> 00:23:46,470
+إلى ذلك، الميه غيرت فيها إشي، إذا نفهمنا إيش الفرق
+
+259
+00:23:46,470 --> 00:23:50,290
+بين الخواص الفيزيائي والكيميائي، الآن لو إجينا
+
+260
+00:23:50,290 --> 00:23:55,240
+بنتكلم على الانانش ومرز و الخواص الفيزيائيبنقول
+
+261
+00:23:55,240 --> 00:23:59,280
+احنا الانانشو مارز they have the same physical
+
+262
+00:23:59,280 --> 00:24:03,020
+properties except for direction of rotation of a
+
+263
+00:24:03,020 --> 00:24:08,200
+plane polarized light يعني هناك عدد كبير من الخواص
+
+264
+00:24:08,200 --> 00:24:12,140
+الفيزيائية، قولوا خمسين خصية ما إلى ذلك مايفرجش
+
+265
+00:24:12,140 --> 00:24:16,060
+عندنا ال two enansho marz اللي هما هيكونوا واحد
+
+266
+00:24:16,060 --> 00:24:23,640
+منهم R والتاني S يشتركوا في جميع الخواص الفيزيائية
+
+267
+00:24:23,890 --> 00:24:31,990
+مثل الكثافة مثل نقطة الغليان مثل نقطة الانصحار مثل
+
+268
+00:24:31,990 --> 00:24:37,850
+معامل الانكسار كلهم لو اتيت against لهم يشتركوافي
+
+269
+00:24:37,850 --> 00:24:44,710
+جميع الخواص الفيزيائية ما عدا خاصية واحدة فقط هذه
+
+270
+00:24:44,710 --> 00:24:49,450
+الخاصية احنا ممكن نقول عنها بالعربي خاصية اللي
+
+271
+00:24:49,450 --> 00:24:54,470
+علاقة بالفيزيا خاصية تدوير الضوء المستقطب في مستوى
+
+272
+00:24:54,470 --> 00:25:01,350
+واحدخاصية ضوئية بندرسها احنا بالفيزيا الان بدنا
+
+273
+00:25:01,350 --> 00:25:07,210
+نفهم ايش معناه ببساطة طبعا هذه الخاصية الفيزيائية
+
+274
+00:25:07,210 --> 00:25:14,020
+هذه الخاصية الفيزيائية الحقيقة احنا بنقيسهامن خلال
+
+275
+00:25:14,020 --> 00:25:18,880
+جهاز .. جهاز تدوير الضوء او بنسميه احنا البولاري
+
+276
+00:25:18,880 --> 00:25:24,840
+ميتر اش بنسميه الجهاز اللي بنقيس فيه البولاري ميتر
+
+277
+00:25:24,840 --> 00:25:31,480
+جهاز تدوير الضوء ببساطة هذا الجهاز بنجيب فيه ضوء
+
+278
+00:25:32,210 --> 00:25:36,810
+والضوء بنمرره على مستقطب بيصير ال vibration تبعه
+
+279
+00:25:36,810 --> 00:25:40,090
+باتجاه واحد، يعني تخيلوا أن هذا اللي موجود بإيدي
+
+280
+00:25:40,090 --> 00:25:44,530
+هو شعاع الضوء، الآن شعاع الضوء بيمشي للأمام، و
+
+281
+00:25:44,530 --> 00:25:50,790
+شعاع الضوء موجة كهرومغناطيسية، و الموجة إلها إيش؟
+
+282
+00:25:50,790 --> 00:25:55,590
+اهتزاز أو تردد، الآن أول ما بيطلع شعاع الضوء بيكون
+
+283
+00:25:55,590 --> 00:26:00,790
+يهتز بجميع الاتجاهاتيعني بهذا الشكل وبهذا الشكل
+
+284
+00:26:00,790 --> 00:26:06,070
+وبهذا الشكل وبهذا الشكل بنمرره على جهاز في الضوء
+
+285
+00:26:06,070 --> 00:26:10,470
+اسمه Polarimeter ال Polarimeter أسهل شيء ممكن
+
+286
+00:26:10,470 --> 00:26:18,110
+تتخيلوا فيه أنه مثل شيء معين فيه فتحة في النص يعني
+
+287
+00:26:18,110 --> 00:26:23,630
+زي هيك شايفين هذه الورقة؟الان هى فيها فتحة او slit
+
+288
+00:26:23,630 --> 00:26:28,590
+الان لو انا عند الضوء هنا يهتز بجميع الاتجاهات
+
+289
+00:26:28,590 --> 00:26:34,990
+بهذا الشكل واضح مررته على البولاريمتر فى فتحة اى
+
+290
+00:26:34,990 --> 00:26:37,910
+اهتزاز اللى بده يطلع من هذه الفتحة
+
+291
+00:26:40,630 --> 00:26:46,970
+فقط اهتزاز واحد الباقي كله ايش هينحجز بناء على ذلك
+
+292
+00:26:46,970 --> 00:26:50,770
+الضوء قبل ما يمر على ال polarimeter بنسميه
+
+293
+00:26:50,770 --> 00:26:54,850
+unpolarized light يعني اول ما بيطلع هنا بيكون عند
+
+294
+00:26:54,850 --> 00:27:01,050
+ال light unpolarized يهتز في جميع الاتجاهات مررتوا
+
+295
+00:27:01,050 --> 00:27:05,500
+على ال polarimeter اللي فيهمفتحة طبعا بيكون من
+
+296
+00:27:05,500 --> 00:27:09,600
+خلال بلورات بس ناخد الفكرة البساطة صار يهتز الضوء
+
+297
+00:27:09,600 --> 00:27:16,140
+في اتجاه واحد فبنسميه polarized light اذا صار عنده
+
+298
+00:27:16,140 --> 00:27:22,640
+الضوء polarized يهتز في اتجاه واحد unpolarized
+
+299
+00:27:22,640 --> 00:27:30,200
+يهتز في اتجاهفي جميع الاتجاهات الان هذا الضوء اللي
+
+300
+00:27:30,200 --> 00:27:35,320
+بيقول polarized بمرره على المركب تبعي مش انا اتفقت
+
+301
+00:27:35,320 --> 00:27:41,630
+ان عندي مركبينواحد R واحد S بجيب المركب بدوبه
+
+302
+00:27:41,630 --> 00:27:46,170
+بمحلول بحطه في أنبوبة زجاجية عادة زي هذا الجلم
+
+303
+00:27:46,170 --> 00:27:50,650
+يعني الأنبوبة طولها عادة عشرة سنتيمتر لغطاية زي
+
+304
+00:27:50,650 --> 00:27:55,750
+هيك بندوب المركب absorbent بنحطه و بنسكر عليه
+
+305
+00:27:55,750 --> 00:27:59,810
+بالغطاية بنحطه في مسار الضوء الآن تخيلوا الضوء كيف
+
+306
+00:27:59,810 --> 00:28:05,400
+قاعد بحتزفى مستوى واحد لما يمر فى أحد هدولة
+
+307
+00:28:05,400 --> 00:28:12,160
+الانانشو مارز بيروح بلوف طلعوا معاه كان يهتز بهذا
+
+308
+00:28:12,160 --> 00:28:18,460
+الاتجاه مر بيطلع يهتز باتجاه مختلف ملاحظين؟ طيب
+
+309
+00:28:18,460 --> 00:28:23,060
+السؤال لو ياتورا مر بمركب مافيش منه R.O.S يعني
+
+310
+00:28:23,060 --> 00:28:25,760
+بمية بيظله
+
+311
+00:28:26,790 --> 00:28:31,170
+بهذا الشكل بمر الميه بيتأثرش عليه بيطلع احتزازه
+
+312
+00:28:31,170 --> 00:28:38,430
+بنفس الشكل لكن لو ماربل ار بيلوف بيصيله عملية ايش
+
+313
+00:28:38,430 --> 00:28:45,430
+روتيشن الان احنا بنقدر نستقبل الشعاع الضوءي ونشوف
+
+314
+00:28:45,430 --> 00:28:51,370
+كده زاويةالدوران اللى لفها يعني هيه بهذا الشكل
+
+315
+00:28:51,370 --> 00:28:55,950
+لفها القدر عشرين درجة تلاتين اربعين بنقدر هذا
+
+316
+00:28:55,950 --> 00:28:59,870
+الكلام نعمله تطبيقيا من خلال جهاز ال polarimeter
+
+317
+00:28:59,870 --> 00:29:05,130
+اللى بنلاحظه القاتلإنه لو واحد من هدولة
+
+318
+00:29:05,130 --> 00:29:10,390
+الانانشومارز كان بيلف الضوء باتجاه معين وبزاوية
+
+319
+00:29:10,390 --> 00:29:15,370
+معينة نفترض بيلف الضوء باتجاه اليمين بزاوية تلاتين
+
+320
+00:29:15,370 --> 00:29:22,010
+درجة المركب التاني نفس الكمية منه بتلف الضوء
+
+321
+00:29:22,010 --> 00:29:28,390
+بالاتجاه المعاكس بنفس المقدار إذا الاختلاف الآن
+
+322
+00:29:28,390 --> 00:29:33,490
+بمقدار الدوران بين المركبين ال R و ال Sلأ إذا
+
+323
+00:29:33,490 --> 00:29:39,870
+استعملت نفس الكمية فقط الاختلاف يكون بماذا؟ باتجاه
+
+324
+00:29:39,870 --> 00:29:45,830
+الدوران فواحد منهم بلف الضوء باتجاه اليمين وواحد
+
+325
+00:29:45,830 --> 00:29:48,410
+منهم بلف الضوء يعني لو أنا اتخيلت أنه عندي زي
+
+326
+00:29:48,410 --> 00:29:53,030
+مانجلة أو ما إلى ذلك إذا واحد منهم لف الضوء بهذا
+
+327
+00:29:53,030 --> 00:29:57,770
+الاتجاه تلاتين درجة التاني بلف الضوء بهذا الاتجاه
+
+328
+00:29:57,770 --> 00:30:05,350
+ناقص تلاتينطبعا الشرط ان انا استعمل نفس الكمية من
+
+329
+00:30:05,350 --> 00:30:09,690
+المركبين واضح؟ الشرط ان انا استعمل نفس الكمية من
+
+330
+00:30:09,690 --> 00:30:14,410
+المركبين ولذلك لو انتوا انتبهتوا لما انا حكيت عن
+
+331
+00:30:14,410 --> 00:30:18,230
+الخاصية الفيزيائية الجولية بيختلفوا بال direction
+
+332
+00:30:18,230 --> 00:30:24,730
+of rotation اتجاه التدوير ماقلتش بال amount of
+
+333
+00:30:24,730 --> 00:30:31,140
+rotationنفس الكمية من ال R و نفس الكمية من ال S
+
+334
+00:30:31,140 --> 00:30:36,240
+بيختلفوا بس بالاتجاه واحدة بتلفه على اليمين
+
+335
+00:30:36,240 --> 00:30:43,220
+والتانية بتلفه لليسار لكن ما بيختلفوا بالمقدار هذا
+
+336
+00:30:43,220 --> 00:30:47,100
+هو الاختلاف ما بين ال enantiomers بال physical
+
+337
+00:30:47,100 --> 00:30:50,700
+Proparities واحد بيلف على اليمين و واحد بيلف على
+
+338
+00:30:50,700 --> 00:30:59,490
+اليسارالان إذا هذه الفكرة وهي الأساس أصبحت واضحة
+
+339
+00:30:59,490 --> 00:31:04,210
+خلّينا الآن نضيف عليها شوية أفكار بسيطة لما
+
+340
+00:31:04,210 --> 00:31:10,170
+اتكلمنا على الكمية مش احنا قلنا بندوّببندوّب كمية
+
+341
+00:31:10,170 --> 00:31:12,910
+من المُركّب وبنحطها في الأنبوبة تبع
+
+342
+00:31:12,910 --> 00:31:18,270
+الـPolarimeter؟ طيب، أنا ممكن أدوّب كمية صغيرة؟
+
+343
+00:31:18,270 --> 00:31:22,090
+ممكن أكتر؟ ممكن أكتر؟ ممكن أكتر؟ يعني ممكن أعمل
+
+344
+00:31:22,090 --> 00:31:28,190
+عدد كبير من التركيز؟ أكيد، خلّيني أقول مثلا، لو
+
+345
+00:31:28,190 --> 00:31:30,610
+أعمل التركيز واحد، concentration one,
+
+346
+00:31:30,730 --> 00:31:32,910
+concentration two, concentration three,
+
+347
+00:31:33,250 --> 00:31:37,480
+concentration fourبقدر اعمل اكتر من التركيز و
+
+348
+00:31:37,480 --> 00:31:42,020
+خلّيني افترض ان التركيز بتزيد بهذا الشكل و انا
+
+349
+00:31:42,020 --> 00:31:45,720
+بجيس الزاوية للمركب اللي عملت منه اكتر من التركيز
+
+350
+00:31:45,720 --> 00:31:51,030
+الزاوية اللي بقيسها بعطيها رمز Alphaتمام ل
+
+351
+00:31:51,030 --> 00:31:56,750
+Concentration 1 بقيس زاوية Alpha 1 ل Concentration
+
+352
+00:31:56,750 --> 00:32:01,270
+2 Alpha 2 ل Concentration 3 Alpha 3 ل
+
+353
+00:32:01,270 --> 00:32:05,770
+Concentration 4 Alpha 4 يعني صار عندى اكتر من
+
+354
+00:32:05,770 --> 00:32:10,270
+زاوية الدوران هذه ال Alpha بقول عنها Observed
+
+355
+00:32:10,270 --> 00:32:15,090
+Rotation اللى هو Observed
+
+356
+00:32:15,850 --> 00:32:20,130
+rotation اللى هو الدوران اللى انا لاحظته بالجهاز
+
+357
+00:32:20,130 --> 00:32:26,410
+هل معقول يا تورا انه يكون عندى لكل تركيز اكثر
+
+358
+00:32:26,410 --> 00:32:32,090
+زاوية لكل تركيز معين زاوية معينة الجواب اه وبسيط
+
+359
+00:32:32,090 --> 00:32:37,430
+جدا اتخيلوا واتذكروا معايا لو كان عندكم على سبيل
+
+360
+00:32:37,430 --> 00:32:45,590
+المثال خمس أحجام من الميهكباية، شاف، طنجرة، كل
+
+361
+00:32:45,590 --> 00:32:52,350
+واحدة فيها ميّه الحجم الأول له كتلة أولى الحجم
+
+362
+00:32:52,350 --> 00:32:58,190
+التاني له كتلة تانية الحجم التالت له كتلة تالتة
+
+363
+00:32:58,190 --> 00:33:01,370
+مظبوط ولا لأ الكتلة و الحجم بيعتمدوا على كمية
+
+364
+00:33:01,370 --> 00:33:09,390
+المادة، مقدارها الآن إذا لكل حجم كتلة لكل تركيز
+
+365
+00:33:10,220 --> 00:33:15,400
+زاوية الآن الحجم والكتلة عمري ما أخدتهم أنا كخاصية
+
+366
+00:33:15,400 --> 00:33:21,140
+أعرف من خلالهم المية لماذا؟ لأن الماء له عدد لا
+
+367
+00:33:21,140 --> 00:33:27,540
+نهائي من الكتل وله عدد لا نهائي من الأحجام واضح؟
+
+368
+00:33:27,540 --> 00:33:31,440
+طب هايش الخاصية اللي في منها بس قيمة واحدة للمية
+
+369
+00:33:31,440 --> 00:33:39,400
+لا تعتمد على المقدار ال density الكثافة لو جبت أنا
+
+370
+00:33:40,220 --> 00:33:45,140
+كل كتلة قِستة يعني لو عملت 100 حجم و قِستلهم 100
+
+371
+00:33:45,140 --> 00:33:47,740
+كتلة كل مرة الكتلة على الحجم الكتلة على الحجم
+
+372
+00:33:47,740 --> 00:33:51,220
+الكتلة على الحجم الكتلة على الحجم نفس المقدار
+
+373
+00:33:51,220 --> 00:33:55,520
+تماما ال density إذا الكتلة و الحجم يعتمدوا على
+
+374
+00:33:55,520 --> 00:33:59,400
+المقدار منهم عدد لنهائي موجود لأي مادة لكن ال
+
+375
+00:33:59,400 --> 00:34:03,780
+density للميه لو سألتكم عند الحرارة العادية كم
+
+376
+00:34:03,780 --> 00:34:08,550
+كثافة الماء1 جرام لكل سنتمتر مكعب
+
+377
+00:34:12,120 --> 00:34:17,440
+فقط لغير هو اللي بنسجله كخاصية للمق في الكتب الأن
+
+378
+00:34:17,440 --> 00:34:23,700
+نفس الكلام تماما لكل تركيز زاوية دوران طيب يا تورا
+
+379
+00:34:23,700 --> 00:34:29,380
+لو أنا بعد هيك بدي مقدار واحد للمركب أنا صار عند
+
+380
+00:34:29,380 --> 00:34:34,160
+ألف واحد ألف اتنين ألف تلات ألف أربعة باجي بعرف
+
+381
+00:34:34,160 --> 00:34:41,730
+كمية بسميها ل specific rotation الدوران النوعيالان
+
+382
+00:34:41,730 --> 00:34:45,410
+الـ specific rotation بيساوي الـ observed rotation
+
+383
+00:34:45,410 --> 00:34:51,490
+الألفة مقسوم على طول الأنبوبة بالديسميتر بتعرف
+
+384
+00:34:51,490 --> 00:34:55,530
+الديسميتر كام سانتي؟ عشرة سانتي يعني واحد في عشر
+
+385
+00:34:55,530 --> 00:34:59,810
+أقصى ناقص واحد من المتر وإحنا عادة الأنبوبة
+
+386
+00:34:59,810 --> 00:35:04,600
+عاملينها ديسميتر يعني بتكون القيمة جديش؟وحد ديسمتر
+
+387
+00:35:04,600 --> 00:35:09,660
+على التركيز للمادة بالإجرام لكل ملل، لاحظوا قسمة
+
+388
+00:35:09,660 --> 00:35:14,500
+الالف على التركيز كعلمي الف واحد على C واحد، الف
+
+389
+00:35:14,500 --> 00:35:17,020
+اتنين على C اتنين، الف تلاتة على C تلاتة، الف
+
+390
+00:35:17,020 --> 00:35:22,320
+أربعة على C أربعة، خلّيت طول الأنبوبة نفس الشيء،
+
+391
+00:35:22,320 --> 00:35:28,000
+الآن بيطلع عندSpecific rotation الان هذه بتطلع نفس
+
+392
+00:35:28,000 --> 00:35:31,340
+القيمة نفس القيمة نفس القيمة نفس القيمة تماما زي
+
+393
+00:35:31,340 --> 00:35:36,050
+ما كان عندكم كتل كتير و حجام كتيرDensity واحدة
+
+394
+00:35:36,050 --> 00:35:41,430
+الان تركيزي كتيرة Alpha كتيرة لكن لما اقسم ال
+
+395
+00:35:41,430 --> 00:35:44,810
+alpha على ال concentration مضروب في طول الأنبوبة و
+
+396
+00:35:44,810 --> 00:35:48,390
+احنا موحدينه عشان نريح حالنا بطلع عندى بس زاوية
+
+397
+00:35:48,390 --> 00:35:53,070
+واحدة اسمها ال specific rotation الان هذه الزاوية
+
+398
+00:35:53,070 --> 00:35:56,830
+بتصير جزء من خواص المركب يعني يوم ما اقول ان في
+
+399
+00:35:56,830 --> 00:36:03,770
+عندى مركبكايرال بقول زاويتها لجد، الآن بدا تكون يا
+
+400
+00:36:03,770 --> 00:36:09,330
+موجبة، يا إيش؟ سالبة، إذا كانت دوران على اليمين،
+
+401
+00:36:09,330 --> 00:36:15,010
+إبناعته، plus ووقتها المركب اللي بلوف على اليمين
+
+402
+00:36:17,190 --> 00:36:20,570
+المُركّب مش احنا يقول إن واحد بده يلف على اليمين
+
+403
+00:36:20,570 --> 00:36:26,270
+والتاني على الشمال الآن ما هي الزاوية المتساوية
+
+404
+00:36:26,270 --> 00:36:31,130
+للتانين ال alpha ولا ال specific rotation ال
+
+405
+00:36:31,130 --> 00:36:35,030
+specific rotation اللي هي ال alpha اللي بين جثين
+
+406
+00:36:35,030 --> 00:36:40,570
+الآن هدولة المُركّبين لو واحد كان منهم زائد تلاتين
+
+407
+00:36:40,570 --> 00:36:47,310
+هيلف على اليمين التاني منهم ناقص تلاتينالان المركب
+
+408
+00:36:47,310 --> 00:36:50,970
+اللى بلوف على اليمين بنعطيه إشارة موجب بنصير نكتب
+
+409
+00:36:50,970 --> 00:36:54,910
+قدامه موجب ومقدار الزاوية وبنعطيه وصف
+
+410
+00:36:54,910 --> 00:36:58,930
+Dextrorotatory إيش يعني Dextrorotatory
+
+411
+00:36:58,930 --> 00:37:07,520
+Dextrorotatory يعني يقولبلف الضوع اليمين والمركب
+
+412
+00:37:07,520 --> 00:37:12,720
+التاني ال minus بنعطيه اسم Levo Rotatory إذا
+
+413
+00:37:12,720 --> 00:37:17,500
+المركبات صاروا نوعين واحد بيلف يمين بيعطيه إشارة
+
+414
+00:37:17,500 --> 00:37:22,040
+الموجبة واحد بيلف إشمال بيعطيه إشارة السلبة واحد
+
+415
+00:37:22,040 --> 00:37:28,850
+منهم موجب والتاني منهمسالب واضح الموجب بقول عنه
+
+416
+00:37:28,850 --> 00:37:33,550
+Dextrorotatory السالب بقول عنه Levorotatory الأن
+
+417
+00:37:33,550 --> 00:37:40,250
+انتبهوا معاه عشان نعمل هذا الكلام احنا جاعدين في
+
+418
+00:37:40,250 --> 00:37:45,070
+المختبر و لا لأ و عندنا جهاز يعني كيف جيس اتلا
+
+419
+00:37:45,070 --> 00:37:50,910
+مركب انه كان plus 30 او minus 30 في المختبر اذا
+
+420
+00:37:50,910 --> 00:37:56,980
+هذه النتيجة تعتبر نتيجةتجريبية طب لما انا كنت احدد
+
+421
+00:37:56,980 --> 00:38:03,060
+المركب انه R ولا S ايش كنت اعمل اشوف المجموعات
+
+422
+00:38:03,060 --> 00:38:08,800
+والوفهم لصغيرة لخالف الأعلى فالاقل فالاقل ولذلك
+
+423
+00:38:08,800 --> 00:38:14,260
+هنا بيجيني سؤال كتير مهم هل يا ترى هناك علاقة ما
+
+424
+00:38:14,260 --> 00:38:22,540
+بين ان المركب يكون R او S ويطلع موجب او سالبالجواب
+
+425
+00:38:22,540 --> 00:38:27,720
+بالتأكيد لأ يعني المُركّب أن R و S هذه أولوية
+
+426
+00:38:27,720 --> 00:38:32,460
+المجموعات أن موجب و سالب هذا قياس في مختبر ففي
+
+427
+00:38:32,460 --> 00:38:38,640
+مُركّبات R و موجبة و في مُركّبات R و سالبة و في
+
+428
+00:38:38,640 --> 00:38:44,620
+مُركّبات S و موجبة و في مُركّبات S و سالبة ولذلك
+
+429
+00:38:44,620 --> 00:38:50,060
+لو أنا بدي أصيغها بجملة بقول there is no relation
+
+430
+00:38:52,390 --> 00:38:59,730
+مافيش علاقة مافيش
+
+431
+00:38:59,730 --> 00:39:01,170
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+432
+00:39:01,170 --> 00:39:01,450
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+433
+00:39:01,450 --> 00:39:01,550
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+434
+00:39:01,550 --> 00:39:01,550
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+435
+00:39:01,550 --> 00:39:01,550
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+436
+00:39:01,550 --> 00:39:01,710
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+437
+00:39:01,710 --> 00:39:02,050
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+438
+00:39:02,050 --> 00:39:02,470
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيش
+
+439
+00:39:02,470 --> 00:39:03,060
+علاقة مافيش علاقة مافيش علاقة مافيش علاقة مافيمش
+
+440
+00:39:03,060 --> 00:39:07,280
+الزام ان ال R تكون موجب او ال S سالب لأ هذا موضوع
+
+441
+00:39:07,280 --> 00:39:12,100
+و هذا موضوع الموجب و السالب بقيسه بالجهاز ال R و
+
+442
+00:39:12,100 --> 00:39:18,820
+ال S بحددهم بإيش بالأولويات و لذلك بتلاحظوا انه لو
+
+443
+00:39:18,820 --> 00:39:24,120
+بتفتشوا على مركب معين في كتالوج كيمويات مركب معين
+
+444
+00:39:24,120 --> 00:39:27,100
+في كتالوج كيمويات ممكن على ال computer تكتبوه
+
+445
+00:39:27,100 --> 00:39:34,650
+حيصير معرفي بشغلتينمكتوب عندكم R وجنبها نفترض plus
+
+446
+00:39:34,650 --> 00:39:40,690
+30 ممكن يكون R minus 30 الآن سويا انا اعطيكم
+
+447
+00:39:40,690 --> 00:39:45,930
+homework ادخلوا على الكمبيوتر و اكتبوا اسم مركبين
+
+448
+00:39:45,930 --> 00:39:51,290
+هذول المركبين كايرال هذول المركبين لو كان عندكم
+
+449
+00:39:51,290 --> 00:39:55,830
+carbon تنتين تلاتة أربعة وهي carbon تنتين تلاتة
+
+450
+00:39:55,830 --> 00:40:02,490
+أربعة لو حطيت هنا chlorineافترض OH وحطيت هنا OH و
+
+451
+00:40:02,490 --> 00:40:07,310
+هنا H وكملوا
+
+452
+00:40:07,310 --> 00:40:17,370
+المركب يعني CH3 CH2 CH3 و هذا CH3 CH2 CH3 الآن
+
+453
+00:40:17,370 --> 00:40:24,370
+هذولا المركبين chiral ولا لأ؟ chiral الآن هذا
+
+454
+00:40:24,370 --> 00:40:30,080
+المركب اسمه two-chlorobutaneبتقدر تحددوله ROS
+
+455
+00:40:30,080 --> 00:40:34,640
+بالقواعد اللي اتعلمتوهم؟ حددوا ايه له ROS؟ وهذا
+
+456
+00:40:34,640 --> 00:40:41,320
+اسمه Top-Butanol بنقدر نحددله ROS؟ بنقدر، اذا ان
+
+457
+00:40:41,320 --> 00:40:47,150
+انا احدد للمركب ROS من وين بجيبهم؟من المجموعات
+
+458
+00:40:47,150 --> 00:40:51,870
+والأولويات الآن بعد هيك لما تحددوا نفترض هذا طلع R
+
+459
+00:40:51,870 --> 00:40:57,430
+روحوا شوفولي ال R-2-chlorobutane بالكتالوجي من
+
+460
+00:40:57,430 --> 00:41:02,890
+الكمبيوتر قدش قيمة ال alpha تبعته وبعدها نفترض هذا
+
+461
+00:41:02,890 --> 00:41:08,490
+طلع S or whatever 2-butanol شوفولي من الكتالوجي
+
+462
+00:41:08,490 --> 00:41:12,790
+اضربه على ال google search نفترض كام S-2-butanol
+
+463
+00:41:12,790 --> 00:41:20,040
+او R-2-butanol شوفوليجداش الزاوية تبعته واضح؟ الان
+
+464
+00:41:20,040 --> 00:41:24,740
+خليكم معاه لو افترضنا هذا المركب او ممكن نعمله
+
+465
+00:41:24,740 --> 00:41:29,540
+بسهولة ايه موجود هذه هنا واحد اتنين تلاتة هذا R
+
+466
+00:41:29,540 --> 00:41:35,340
+راحت واحدة فتشت في الكمبيوتر لجت ان ال S2 كلورو
+
+467
+00:41:35,340 --> 00:41:41,240
+بيوتين ناقص عشرين مالجتش ال R بتحل ال .. بتحل ال
+
+468
+00:41:41,240 --> 00:41:48,650
+homework ولا لأ؟إذا عرف واحد التاني عكسهواضح؟ يعني
+
+469
+00:41:48,650 --> 00:41:52,510
+لو واحدة فتشت على الكمبيوتر و بتفتش ايش زاوية مركب
+
+470
+00:41:52,510 --> 00:41:57,510
+ال R لجت زاوية ال S تبقى لها ساعتين تفتش على مركب
+
+471
+00:41:57,510 --> 00:42:03,410
+ال R قد ايش زاويته اذا لجت ال R ال S عكسها و اذا
+
+472
+00:42:03,410 --> 00:42:09,450
+لجت ال S ال R عكسها لاحظوا لا يختلفوا في القيمة
+
+473
+00:42:09,450 --> 00:42:15,350
+ولكن يختلفوا في الاتجاهجربوا وشوفوا كيف هذه
+
+474
+00:42:15,350 --> 00:42:19,750
+المراكبات بتنكتب هدولا خاصيتين لازم يكونوا معروفين
+
+475
+00:42:19,750 --> 00:42:25,730
+عن المراكب ال configuration يحدد من الأولويات و ال
+
+476
+00:42:25,730 --> 00:42:31,590
+rotation يحدد بال إيش بالتجربة باستعمال جهاز
+
+477
+00:42:31,590 --> 00:42:36,290
+البولاري ميتر وبهيك بننهي اليوم ان شاء الله و
+
+478
+00:42:36,290 --> 00:42:36,730
+بنكمل
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tov4h-a7-Pc_postprocess.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tov4h-a7-Pc_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..49fb3801714f5bcfa88e6a66293f732a1bc79df1
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/tov4h-a7-Pc_postprocess.srt
@@ -0,0 +1,2364 @@
+1
+00:00:20,810 --> 00:00:27,390
+بسم الله الرحمن الرحيم بعد ما اتعرفنا في المرات
+
+2
+00:00:27,390 --> 00:00:37,590
+الماضية على الأحماض الأمينية و تفاعلاتها اليوم
+
+3
+00:00:37,590 --> 00:00:43,210
+ان شاء الله هنتعرف كيف هذه الأحماض الأمينية طبعا
+
+4
+00:00:43,210 --> 00:00:49,650
+بتتحد مع بعضها البعضبشكل متتابع لتكوين ال peptides
+
+5
+00:00:49,650 --> 00:00:56,850
+وأكبر منهم طبعا بيكونوا إيش ال proteins بالنسبة ل
+
+6
+00:00:56,850 --> 00:01:02,130
+ال proteins زي ما انتوا عارفين اللهم أهمية
+
+7
+00:01:02,130 --> 00:01:07,510
+بيولوجية جزيئات أساسيةمثلا في الأشياء اللي بنسميها
+
+8
+00:01:07,510 --> 00:01:12,150
+structural tissues، الأنسجة البنائية الأساسية،
+
+9
+00:01:12,150 --> 00:01:17,390
+العضلات، ال muscles، ال skin، الجلد، ال nails،
+
+10
+00:01:17,390 --> 00:01:23,070
+الأضافر، ال hair، الشعر، كل هذا يصنفوا على أنه
+
+11
+00:01:23,070 --> 00:01:27,150
+إيش؟ ال proteins and they are structural tissuesفي
+
+12
+00:01:27,150 --> 00:01:31,850
+عندنا transport molecules الجزيئات الناقلة من
+
+13
+00:01:31,850 --> 00:01:37,130
+أمثلتها مثلا ال hemoglobin في عندنا ال enzymes
+
+14
+00:01:37,130 --> 00:01:42,010
+اللي هي ال biological catalyst أيضا هذه ال
+
+15
+00:01:42,010 --> 00:01:47,970
+proteins الآن لما بنيجي نتكلم عن ال protein بشكل
+
+16
+00:01:47,970 --> 00:01:54,270
+عام بنتكلم الحقيقة عن أربع أشكال لل protein يعني
+
+17
+00:01:54,270 --> 00:01:58,560
+هيمروا معاكم مصطلحاتprimary structure of protein
+
+18
+00:01:58,560 --> 00:02:02,520
+secondary structure of protein tertiary structure
+
+19
+00:02:02,520 --> 00:02:06,000
+of protein and quaternary structure of protein
+
+20
+00:02:06,000 --> 00:02:11,740
+والمفروض فينا ان نفهم ايش معنى هذه الأشكال وهذا
+
+21
+00:02:11,740 --> 00:02:17,520
+تقريبا هيكون محور الدرس اليوم ايش معنى اللي هي
+
+22
+00:02:17,520 --> 00:02:20,940
+أشكال البروتين ال primary structure شو معنى ال
+
+23
+00:02:20,940 --> 00:02:27,410
+secondary tertiary quaternary الان لو بدنا نبدأأول
+
+24
+00:02:27,410 --> 00:02:32,070
+شيء في ال primary structure of proteins المقصود
+
+25
+00:02:32,070 --> 00:02:38,350
+فيه ال amino acid sequence يعني كيف الأحماض
+
+26
+00:02:38,350 --> 00:02:42,950
+الأمينية مرتبة في هذا ال protein أو في الأصغر منه
+
+27
+00:02:42,950 --> 00:02:48,010
+اللي هو إيش ال peptide طبعا إحنا اتفقنا سابقا إن
+
+28
+00:02:48,010 --> 00:02:52,510
+ال amino acid إلهtwo abbreviations three letter
+
+29
+00:02:52,510 --> 00:02:57,590
+abbreviation عادة بنستعمله للتعبير عن الـpeptide و
+
+30
+00:02:57,590 --> 00:03:00,530
+one letter abbreviation عادة بنستعمله للتعبير عن
+
+31
+00:03:00,530 --> 00:03:05,110
+البروتين طبعا
+
+32
+00:03:05,110 --> 00:03:11,490
+كيف بيحددوا ال primary structure of بروتين يعني
+
+33
+00:03:11,490 --> 00:03:19,010
+نفترض بروتين في الف amino acid الف وحدةقبعا هدولة
+
+34
+00:03:19,010 --> 00:03:25,790
+الألف واحدة هتلاحظوا ان هما في النهاية من عشرين
+
+35
+00:03:25,790 --> 00:03:31,770
+amino acid مش هيك احنا اتفقنا بمعنى انه مثلا amino
+
+36
+00:03:31,770 --> 00:03:37,590
+acid glycine نفترض فيه منه خمسين مرة متكررواضح؟
+
+37
+00:03:37,590 --> 00:03:42,230
+أمينو أسد ليسين افترض تلاتين مرة أمينو أسد
+
+38
+00:03:42,230 --> 00:03:48,330
+تريبتوفان ممكن نقول ستين مرة الآن هدولة في النهاية
+
+39
+00:03:48,330 --> 00:03:54,470
+بيجمعوا ايش؟ بيجمعوا البروتين اللي مكون من الف
+
+40
+00:03:54,470 --> 00:03:59,850
+أمينو أسد واضح الفكرة؟ يعني لو انا يمكن اتعودنا
+
+41
+00:03:59,850 --> 00:04:03,850
+احنا ان نتخيل انه بهذا الشكل كأننا بنعمل ايش؟
+
+42
+00:04:05,160 --> 00:04:11,400
+ببتايد او بروتين الان لو جيبت انا عشرين نوع من هذه
+
+43
+00:04:11,400 --> 00:04:15,560
+الاجلام من نوع اربعين من نوع خمسين من نوع سبعين من
+
+44
+00:04:15,560 --> 00:04:22,040
+نوع تمانين لحد ما كان المجموع الكل قداش الف وطلبت
+
+45
+00:04:22,040 --> 00:04:28,220
+من اي شخص انه تعالى يعمل اليهم سلسلة بروتين هل
+
+46
+00:04:28,220 --> 00:04:33,760
+عقلا بتتوقعوا انه ممكن اتنين يعملوا نفس الشيء
+
+47
+00:04:35,760 --> 00:04:40,900
+مستحيل، يعني هذه تعتبر صدفة مستحيلة، ليش؟ لأن كل
+
+48
+00:04:40,900 --> 00:04:46,400
+واحد بيحطهم بشكل معين، بيعمل sequence معينة، الآن
+
+49
+00:04:46,400 --> 00:04:51,220
+تخيلوا إنه في الدنياهذه الـ sequence لبروتين محدد
+
+50
+00:04:51,220 --> 00:04:55,780
+هي sequence ثابتة او لإنزايم محدد هي sequence
+
+51
+00:04:55,780 --> 00:05:00,160
+ثابتة يعني مانفعش نيجي نقول والله الانسولين و
+
+52
+00:05:00,160 --> 00:05:04,520
+بعدين كل انسولين مختلف عن التاني لأ لما نقول
+
+53
+00:05:04,520 --> 00:05:09,740
+انسولين هيكون له sequence ثابت الآن هذه ال
+
+54
+00:05:09,740 --> 00:05:15,530
+sequence الثابتة لازم يتعرفوا عليهابالمرحلة الأولى
+
+55
+00:05:15,530 --> 00:05:20,670
+و بعد هيك إذا و الله لازمهم انهم يقدروا يجمعوا ال
+
+56
+00:05:20,670 --> 00:05:24,290
+amino acids و يحضروها كان بها إذا حسوا ان القمر
+
+57
+00:05:24,290 --> 00:05:28,590
+فيه غلبة كتير و في عنده مصدر طبيعي ممكن يعطينا
+
+58
+00:05:28,590 --> 00:05:32,130
+انسليل زي الأبقار و ما إلى ذلك بروحوا بيجيبوه
+
+59
+00:05:32,130 --> 00:05:37,630
+المصدر الطبيعي محضر و جاهز فبتصير من أصعب الشغلات
+
+60
+00:05:37,630 --> 00:05:44,030
+في موضوعHow to determine the primary structure of
+
+61
+00:05:44,030 --> 00:05:49,890
+a protein يعني كيف انا بدي طرق اني احدد هذا الشكل
+
+62
+00:05:49,890 --> 00:05:56,430
+الان المرحلة الاولى لو انا حطيت ال protein بحمض
+
+63
+00:05:56,430 --> 00:06:03,110
+محرارة كسرتهلأ الأحماض اللي متكون منها طبعا مش
+
+64
+00:06:03,110 --> 00:06:06,610
+ضروري ال protein او ال peptide يكون من ال 20 amino
+
+65
+00:06:06,610 --> 00:06:13,050
+acid ممكن من اقل ممكن من 14 من 8 من 15 حسب نوعه
+
+66
+00:06:13,050 --> 00:06:17,930
+تمام؟ في هذه الحالة بدون حطوا ال protein يغلو مع
+
+67
+00:06:17,930 --> 00:06:25,290
+الحامض لمدة حوالي 24 ساعة بتتكسركل ايش؟ كل ال
+
+68
+00:06:25,290 --> 00:06:28,430
+peptide bonds و لاحظوا متذاكرين احنا لما أخدنا ال
+
+69
+00:06:28,430 --> 00:06:31,550
+amide bond قولنا ال amide bond بالتسخين الطويل
+
+70
+00:06:31,550 --> 00:06:35,750
+تتكسر و ال peptide bond is an amide bond في
+
+71
+00:06:35,750 --> 00:06:40,370
+النهاية اذا هيني انا كسرته طلع عندى من الأخضر مثلا
+
+72
+00:06:40,370 --> 00:06:45,050
+اتنين من الأسود تلاتة من الأحمر glycine واضح بعد
+
+73
+00:06:45,050 --> 00:06:52,770
+هيك ابقى جهزة معينةسهلة أجهزة كروماتوغرافي نمرر و
+
+74
+00:06:52,770 --> 00:06:56,590
+نعرف كم نوع amino acid عندك بقى لكل نوع amino acid
+
+75
+00:06:56,590 --> 00:06:57,470
+اللي بيعطي نبيك
+
+76
+00:07:02,690 --> 00:07:09,270
+الأطياف 1,2,3,4,5,6,7,8 يعني هذا بيبتايد مكون من
+
+77
+00:07:09,270 --> 00:07:13,930
+كام نوع من ال amino acids من تمانية الآن حسب كوبر
+
+78
+00:07:13,930 --> 00:07:18,470
+هذه بتكون هذه التعبير عن جداش عندي أعداد يعني
+
+79
+00:07:18,470 --> 00:07:23,080
+نفترضهذه بتمثل أربعة، وهذه بتمثل ستة، وهذه تمثل
+
+80
+00:07:23,080 --> 00:07:28,560
+تمانية، بجمعه حسب العدد الكلي، فالان صرنا عارفين
+
+81
+00:07:28,560 --> 00:07:33,560
+المكونات الفردية، يعني المكونات الفردية انها تنعرف
+
+82
+00:07:33,560 --> 00:07:40,420
+ليستأمرا صعبا بالنسبة للكيميا ايه واضح اطلاقا مش
+
+83
+00:07:40,420 --> 00:07:45,580
+امر صعب يعني انا بدي اسهل عليكم لو عملتلكم على
+
+84
+00:07:45,580 --> 00:07:54,480
+سبيل المثال هذا ال ال بروتيل او ال peptide واضح؟
+
+85
+00:07:54,480 --> 00:08:00,310
+الآن و اجيت عملتله ال hydrolysis كسرتهو بعد هي
+
+86
+00:08:00,310 --> 00:08:04,270
+قلتلكوا اعملولي المكونات الفردية تبعته هتقولولي في
+
+87
+00:08:04,270 --> 00:08:08,290
+اتنين Glycine في واحد Alanine في واحد Tyrosine في
+
+88
+00:08:08,290 --> 00:08:15,070
+واحد Valine اربع انواع واضح؟ لكن السؤال الصعب لو
+
+89
+00:08:15,070 --> 00:08:20,330
+انا الآن بقولكم كيف كانوا هدولة مرتبين ولا حد فيكم
+
+90
+00:08:20,330 --> 00:08:25,020
+اتطلع و متأكد كيف كانوا مرتبين ولا حتى انايمكن في
+
+91
+00:08:25,020 --> 00:08:29,060
+عندنا الكاميرا لو كنا بنرجع بالتسجيل بنقدر نشوف
+
+92
+00:08:29,060 --> 00:08:33,420
+كيف كانوا مرتبين لكن ماحد فينا عارف واضح ماحد فينا
+
+93
+00:08:33,420 --> 00:08:37,520
+عارف كيف كانوا مرتبين ففكرة ان اكسرهم و اعرفهم
+
+94
+00:08:37,520 --> 00:08:41,740
+بالظبط جديش العدد الكلي تباعهم و العدد الكلي مكون
+
+95
+00:08:41,740 --> 00:08:47,080
+من اي amino acids هذه الفكرةممكن أو بسيطة
+
+96
+00:08:47,080 --> 00:08:53,760
+كيميائيا، لكن الفكرة الأصعب، الـ sequence تبعتهم
+
+97
+00:08:53,760 --> 00:08:57,720
+اللي كانت موجودة، هذه الفكرة الأصعب
+
+98
+00:08:59,850 --> 00:09:05,370
+اللي أخدت تجارب لحد ما قدروا يحددوا الـ sequences
+
+99
+00:09:05,370 --> 00:09:11,410
+من التجارب هذه من التجارب الأولية اللي بدأوا
+
+100
+00:09:11,410 --> 00:09:15,950
+يستعملوها لتحديد الـ sequences كان في عنده طريقة
+
+101
+00:09:15,950 --> 00:09:19,050
+سيد زانجر method زانجر method
+
+102
+00:09:21,560 --> 00:09:27,080
+اتذكروا معنا شغلة انه احنا لما اتكلمنا عن ال
+
+103
+00:09:27,080 --> 00:09:33,080
+بيبتايد اذا بتذكروا قلنا انه ال بيبتايد له
+
+104
+00:09:36,520 --> 00:09:42,560
+terminal و C terminal مظبوط ولا لا الآن ال method
+
+105
+00:09:42,560 --> 00:09:50,960
+زانجر ماعملتش شغل كتير لنا عملت شغلة بسيطة جدا بس
+
+106
+00:09:50,960 --> 00:09:57,260
+قال انا بقدر اساعدكم اقولكم مين اول amino acid and
+
+107
+00:09:57,260 --> 00:10:01,900
+terminal يعني بس بيقولي ان ال and terminal هو مثلا
+
+108
+00:10:01,900 --> 00:10:08,110
+نجليسين او tryptophan و بعد هيكبيعجز، الآن كيف
+
+109
+00:10:08,110 --> 00:10:13,270
+ممكن زانجر يعمل هذه الطريقة، يحدد لأي واحد، يعني
+
+110
+00:10:13,270 --> 00:10:17,510
+هم لما يتكسروا، بتقولوا هدولة خمسة، لكن مين كان
+
+111
+00:10:17,510 --> 00:10:24,470
+فيهم الـand terminal؟ مش عارفين، واضح؟ الآن method
+
+112
+00:10:24,470 --> 00:10:30,390
+زانجر بتعرف النيةواضح فزانجر method فقط بتقدر
+
+113
+00:10:30,390 --> 00:10:36,130
+تقولنا من ال N terminal ال N كفكرة بعيدا عن
+
+114
+00:10:36,130 --> 00:10:40,490
+المعادلات الكيميائية ايش اللي بيعمله زانجر زانجر
+
+115
+00:10:40,490 --> 00:10:46,130
+بيجي بيجيب مادة خارجية بتتفاعل مع ال N H2 ال N في
+
+116
+00:10:46,130 --> 00:10:52,330
+كل هذا الجزء وين موجود N H2في الـ Unterminal اللي
+
+117
+00:10:52,330 --> 00:10:56,810
+هنا Unetched Unreactive هذه Unetched هذه Unetched
+
+118
+00:10:56,810 --> 00:11:02,990
+هذه Unetched صارت Unreactive في فقط Unetched واحدة
+
+119
+00:11:02,990 --> 00:11:08,990
+الان بيجيب مادة كيميائية غريبة و بيعمل تفاعل لهذه
+
+120
+00:11:08,990 --> 00:11:14,070
+المادة مع ال Unetched بيصير ولا لأ هيجيب المادة و
+
+121
+00:11:14,070 --> 00:11:20,560
+هيعمللها تفاعل شبكهامع ال N H2 لاحظوا ال N
+
+122
+00:11:20,560 --> 00:11:24,720
+Terminal صار مشبوك فيه مادة و لا لأ مادة معينة ال
+
+123
+00:11:24,720 --> 00:11:32,060
+N بعد هيك بكسر ال protein كسرنا واحد اتنين تلاتة
+
+124
+00:11:33,070 --> 00:11:38,010
+وبيجي بيفحص الان هيلاجي هذا amino acid معروف عند
+
+125
+00:11:38,010 --> 00:11:42,390
+هذا amino acid صفات هذا هذا الان هيلاجي فيهم واحد
+
+126
+00:11:42,390 --> 00:11:47,710
+مرتبط بالمادة اللي عملت تفاعل معها اللي مرتبط
+
+127
+00:11:47,710 --> 00:11:51,830
+بالمادة هذه هو مين بيكون ال unterminal واضح
+
+128
+00:11:51,830 --> 00:11:56,410
+الفكرة؟بيظل اذا احنا هذا الكلام اللي عملناه بدون
+
+129
+00:11:56,410 --> 00:12:00,610
+ما نحكي اسماء مواد ان نعرف شو هي المادة اللي
+
+130
+00:12:00,610 --> 00:12:04,890
+بتتفاعل مع ال N-H2 بترتبط معها و لما يتكسر بيظلوا
+
+131
+00:12:04,890 --> 00:12:11,050
+مشابكين التنتين مع بعض، واضح الفكرة؟هذه المادة هي
+
+132
+00:12:11,050 --> 00:12:16,650
+2,4-dinitrofluorobenzene يعني لو انا طلعت على هذا
+
+133
+00:12:16,650 --> 00:12:20,850
+المركب الفلورو بنزين واحد اتنين تلاتة اربعة على
+
+134
+00:12:20,850 --> 00:12:25,490
+نمرة اتنين واربعة في عندى dinitrofluorobenzene لما
+
+135
+00:12:25,490 --> 00:12:31,720
+اجى افعله مع ال aminoترمينال لأنه مع الأشياء
+
+136
+00:12:31,720 --> 00:12:35,980
+التانية بتفعلش بتصل مكان ل floor بيحل محل ل floor
+
+137
+00:12:35,980 --> 00:12:41,820
+فلاحظوا هاي ال ال anterminal amino acid صار متصل
+
+138
+00:12:41,820 --> 00:12:48,880
+مع إيش؟ مع المادة الغريبة اللي جيبناها من برا هذه
+
+139
+00:12:48,880 --> 00:12:54,360
+المادة بنسميها Zangari agentهو الـ reagent اللي
+
+140
+00:12:54,360 --> 00:12:58,840
+استعملوه زنجاب الان لما بنيجي بنعمل عملية التكسر
+
+141
+00:12:58,840 --> 00:13:03,940
+كل ال amino acids بيطلعوا على شكل amino acids
+
+142
+00:13:03,940 --> 00:13:11,420
+عادية ما عدت ال unterminal بيطلع ملتصق في ال 2,4
+
+143
+00:13:11,420 --> 00:13:16,740
+-dinitrobenzene فالملتصق بال 2,4-dinitrobenzene ع
+
+144
+00:13:16,740 --> 00:13:21,500
+طول بنقول هذا كان ال unterminal طبعا انتوا تخيلوا
+
+145
+00:13:23,180 --> 00:13:28,660
+إنه لو في عنده ميت أمينو أسد في بيبتايد و لا ألف
+
+146
+00:13:28,660 --> 00:13:33,920
+أمينو أسد في بروتين لناس بدوا يدرجوا في العلم إنه
+
+147
+00:13:33,920 --> 00:13:37,560
+بس يعرفوا مين أول واحد و بعد هيك اتكسر و خلاص
+
+148
+00:13:37,560 --> 00:13:43,020
+بطلنا جادرين نعرف لكن هذا بحد ذاته كان إنجاز في
+
+149
+00:13:43,020 --> 00:13:49,560
+وقته لكن مابكفيش يعني مابحنش الشكلواضح الشكل أني
+
+150
+00:13:49,560 --> 00:13:56,200
+بدي أعرف الألف مرتبين مش بس أعرف مين أول واحد فيهم
+
+151
+00:13:56,200 --> 00:14:03,680
+ولذلك إجت طريقة هذه المعادلة بتهيألي بشكل واضح هاي
+
+152
+00:14:03,680 --> 00:14:06,820
+اللي هو الـ 2,4-dinitrobenzene اللي هو الـ Zangar
+
+153
+00:14:06,820 --> 00:14:16,730
+reagent خلينا هيك نسميه ال Zangar reagentلما احنا
+
+154
+00:14:16,730 --> 00:14:21,650
+فعلنا مع البروتين فقط يتفاعل مع الـ unatched الـ
+
+155
+00:14:21,650 --> 00:14:26,670
+unterminal بيعطينا ده الشكل لما نكسر زي ما اتفقنا
+
+156
+00:14:26,670 --> 00:14:30,390
+فقط الـ unterminal ال amino acid بيكون متحد معاه
+
+157
+00:14:30,390 --> 00:14:36,860
+والباقي بيطلعوا amino acids اديينهذا الكلام بعد
+
+158
+00:14:36,860 --> 00:14:42,980
+ذلك اتطور بطريقة افضل كثير من خلال العالم Edman
+
+159
+00:14:42,980 --> 00:14:49,980
+عمل Edman's reagent الآن ال Edman's reagent الشغل
+
+160
+00:14:49,980 --> 00:14:55,140
+اللي اشتغله اجمل كثير يمكن ايش اللي اشتغله جاب
+
+161
+00:14:55,140 --> 00:15:01,720
+reagent بيجي يتفاعل ايضا مع ال unterminal amino
+
+162
+00:15:01,720 --> 00:15:07,120
+acidتمام خلّينا نفترض هذا ال reagent مرة تانية
+
+163
+00:15:07,120 --> 00:15:15,660
+اللي جابه السيد مين ادمان هيه اتفاعل وصار شابك مع
+
+164
+00:15:15,660 --> 00:15:23,080
+ال unterminal amino acid بعد هيك هذا ال reagent
+
+165
+00:15:23,080 --> 00:15:30,620
+تبعه بيكسر فقط هو ال unterminal amino acidو بيظل
+
+166
+00:15:30,620 --> 00:15:35,960
+باقي ال protein ممسوك، مابتكسرش كله واضح؟ إذ
+
+167
+00:15:35,960 --> 00:15:40,180
+هايدرولز خفيف بس بيكسر هذا مع هذا و بيطلع هذا على
+
+168
+00:15:40,180 --> 00:15:44,540
+شكل إيش حلقة، هنشوف كيف التفاصيل، الآن هذا اللي
+
+169
+00:15:44,540 --> 00:15:49,240
+طلع بنقدر ناخده و نحلله لحاله و نعرفه؟ أه، الآن
+
+170
+00:15:49,240 --> 00:15:55,290
+بنعيد التفاعلبنجيب الـ Edmund's reagent مرة تانية،
+
+171
+00:15:55,290 --> 00:15:59,570
+اذا احنا عرفنا أول واحد، بنعود الفعل الجزء المتبقى
+
+172
+00:15:59,570 --> 00:16:05,950
+مع Edmund's reagent، هيتحد معاه وكسربس ال
+
+173
+00:16:05,950 --> 00:16:10,450
+unterminal اللي عرفنا نمرة اتنين بعد هيك كمان مرة
+
+174
+00:16:10,450 --> 00:16:16,070
+بنعرف نمرة تلاتة لاحظوا تعريف Edman's reagent is a
+
+175
+00:16:16,070 --> 00:16:21,610
+reagent that clips off يعني بيقطع واضح؟ that clips
+
+176
+00:16:21,610 --> 00:16:26,350
+off just one amino acid at a time يعني في كل مرة
+
+177
+00:16:26,350 --> 00:16:31,170
+بتفاعل مع ال amino acid الطرفاني و بيقصه بس بيخلي
+
+178
+00:16:31,170 --> 00:16:35,650
+ايش ال protein مرة تانية تالتة رابعةفي النهاية
+
+179
+00:16:35,650 --> 00:16:43,470
+بنقدر ايش؟ بنعرف الترتيب تبعهم الان بالنسبة لفكرة
+
+180
+00:16:43,470 --> 00:16:49,390
+التفاعل الكيميائي هي في المحصلة فكرة كيميائية مش
+
+181
+00:16:49,390 --> 00:16:53,890
+صعبة كتير ال reagents اللي هو ال Edmans reagent
+
+182
+00:16:53,890 --> 00:17:01,330
+اسمه هين رسمينه بالأحمرفنل ايزو سيانيت ايش اسمه
+
+183
+00:17:01,330 --> 00:17:07,770
+فنل ايزو سيانيت ايش اللي بيميز الفنل ايزو سيانيت
+
+184
+00:17:07,770 --> 00:17:13,610
+هذا لاحظوا هذا الفنل ايزو سيانيت الكاربون تبعته
+
+185
+00:17:13,610 --> 00:17:21,050
+موجود بين ذرتين electronegative كبريتونيتروجين
+
+186
+00:17:21,050 --> 00:17:26,550
+عشان هيك هذه الكاربون is a highly positive carbon
+
+187
+00:17:28,170 --> 00:17:30,550
+هذا الكربون موجبة الكربون الكربون الكربون الكربون
+
+188
+00:17:30,550 --> 00:17:32,070
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+189
+00:17:32,070 --> 00:17:32,150
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+190
+00:17:32,150 --> 00:17:34,610
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+191
+00:17:34,610 --> 00:17:35,090
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+192
+00:17:35,090 --> 00:17:37,050
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+193
+00:17:37,050 --> 00:17:38,850
+الكربون الكربون الكربون الكربون الكربون الكربون
+
+194
+00:17:38,850 --> 00:17:39,070
+الكربون الكربون الكربون الكربون كربون كربون كربون
+
+195
+00:17:39,070 --> 00:17:53,490
+كربون كربون كربون كربون كربون كربون كربون
+
+196
+00:17:54,430 --> 00:17:59,630
+في زوج الالكترونات والكربون بصفتها محصورة بين
+
+197
+00:17:59,630 --> 00:18:05,030
+ذرتين سالبات إذا هي موجبة فلما هذا التفاعل بده يتم
+
+198
+00:18:05,030 --> 00:18:10,730
+بتقدروا تخيلوها إيه هذه هاجمت إجت وين؟ على الكربون
+
+199
+00:18:10,730 --> 00:18:14,890
+اللي هنا هذا زوج الالكترونات بتتحرك بيجي على الان
+
+200
+00:18:14,890 --> 00:18:20,730
+بتصير on minus هذا بتفقد H الان بتكتسبها واضح؟
+
+201
+00:18:20,730 --> 00:18:26,190
+فبصير عند هذا الجزءلاحظوا التفاعل منطقي يعني لو
+
+202
+00:18:26,190 --> 00:18:32,810
+اتطلعتوا كان عندى phenyl NCS وكانت هذه NH2 نقيت
+
+203
+00:18:32,810 --> 00:18:38,010
+التفاعل هذه صارت NH و الـH انتقلت هنا في ذرات
+
+204
+00:18:38,010 --> 00:18:43,530
+اختفت كانت هذه NH2 وكانت هذه phenyl NCS هيوم
+
+205
+00:18:43,530 --> 00:18:50,190
+اتفاعلوا بهذا الشكل الان هذا لو فعلته مع HCl ومية
+
+206
+00:18:52,270 --> 00:19:00,010
+بيكسر بشكل معين ان هذا ال نيتروجين عليها
+
+207
+00:19:00,010 --> 00:19:03,470
+زوج إلكترونات بتهاجم على هذا ال C double bond و
+
+208
+00:19:03,470 --> 00:19:09,290
+بتعمل حلقة و بتكسرالجزء الأول بتطلع ع شكل حلقة الـ
+
+209
+00:19:09,290 --> 00:19:13,410
+C double bond O موجة بسيه وهذا النيتروجين عليه زوج
+
+210
+00:19:13,410 --> 00:19:16,770
+الإلكترونات فبتكسر و بتطلع هذا ع شكل حلقة لاحظوا
+
+211
+00:19:16,770 --> 00:19:22,550
+هنا إيش موجود عندى ال amino acid الأزرق الأول متحد
+
+212
+00:19:22,550 --> 00:19:29,130
+مع ال Edmans reagent الفينيليايزوسيانات وباقى
+
+213
+00:19:29,130 --> 00:19:36,850
+لبروتين زي ما هو فانا لما بفصل هذا بعرفأيش ال
+
+214
+00:19:36,850 --> 00:19:40,330
+amino acid طالما فصلته لحاله مش عملية صعبة الان
+
+215
+00:19:40,330 --> 00:19:44,730
+بعيد الكلام هيفصل ال amino acid اللي بعده مع انفنل
+
+216
+00:19:44,730 --> 00:19:52,940
+NCO كمان مرة كمان مرة بهيك بنقدر ايش نعملنعرف كل
+
+217
+00:19:52,940 --> 00:19:57,580
+ال sequence، بنقدر نعرف كل ال sequence، واضحة
+
+218
+00:19:57,580 --> 00:20:01,340
+الفكرة؟ من خلال ال Edmund's reagent لأنه بياخدهم
+
+219
+00:20:01,340 --> 00:20:05,300
+واحد واحد، الآن طبعا بإمكانكوا تتخيلوا أنتوا أن
+
+220
+00:20:05,300 --> 00:20:08,840
+هذا الكلام بده شخص في المختبر يقعد ويفصل ويشتغل
+
+221
+00:20:08,840 --> 00:20:11,780
+ويفصل ويعود ويعيد التفاعل ويفصل، كل هذا الكلام
+
+222
+00:20:11,780 --> 00:20:16,380
+الآن على أجهزة بنعمل automaticيعني بنحط ل protein
+
+223
+00:20:16,380 --> 00:20:21,320
+و عندنا أجهزة sequencing نفسها automatic بتضيف ال
+
+224
+00:20:21,320 --> 00:20:24,680
+reagent و بتعمل و بتفصل و بتتعرف على الأول بعدين
+
+225
+00:20:24,680 --> 00:20:27,360
+على التاني بعدين على التالت طبعا الدنيا كتير
+
+226
+00:20:27,360 --> 00:20:31,420
+متطورة في هذا المجال واضح؟ يعني مش شغل في المختبر
+
+227
+00:20:31,420 --> 00:20:36,780
+و أقعد فيه أشهر و سنين لأ كل شغل بنشغل automatic
+
+228
+00:20:36,780 --> 00:20:43,990
+بس هذه الفكرة الأساسية تبعته الآن هناما بنقدرش
+
+229
+00:20:43,990 --> 00:20:51,190
+نترك هذه الفكرة إلا نحكي عن نقطة يمكن كثير مهمة
+
+230
+00:20:51,190 --> 00:20:56,750
+مالهاش علاقة في موضوع البروتينات أو يمكن أقول لأ
+
+231
+00:20:56,750 --> 00:21:02,390
+إلها علاقة في موضوع البروتينات ابن عمه بس ابن عمه
+
+232
+00:21:02,390 --> 00:21:09,880
+الصغيرللفنل ايزو ثيو سيانات فنل ايزو ثيو سيانات
+
+233
+00:21:09,880 --> 00:21:14,280
+اللي هو ابن عم صغير ايش هذا ابن عم الصغير مين هو
+
+234
+00:21:14,280 --> 00:21:24,020
+CH3MCOO
+
+235
+00:21:24,020 --> 00:21:31,070
+هد مين بطلع؟ابن عمه الصغير طب لو بدنا نسميه هذه
+
+236
+00:21:31,070 --> 00:21:36,010
+ايزو سيانات هذه ايزو ثايو سيانات اللي فيها اكسجين
+
+237
+00:21:36,010 --> 00:21:41,090
+ايزو سيانات اللي فيها كبريت ايزو ثايو سيانات ثنل
+
+238
+00:21:41,090 --> 00:21:46,570
+ايزو ثايو سيانات مثل ايزو سيانات تعرفنا هذا ايش
+
+239
+00:21:46,570 --> 00:21:58,470
+اسمه مثل ايزو سيانات اذا المثل ايزو سياناتبكون ابن
+
+240
+00:21:58,470 --> 00:22:05,070
+عمه الصغير لمين؟ للفنل ايزوثيو سيانيت لأن جزء
+
+241
+00:22:05,070 --> 00:22:11,350
+الصغير لأن جزء الصغير المثل ايزو سيانيت بكون عبارة
+
+242
+00:22:11,350 --> 00:22:18,310
+عن غاز بكون عبارة عن غاز بتطير
+
+243
+00:22:20,680 --> 00:22:26,440
+هذا الغاز بيستعمله في مصانع المبيدات بيستعمله في
+
+244
+00:22:26,440 --> 00:22:31,880
+مصانع المبيدات الحشرية وغيرها وغيراتها طبعا
+
+245
+00:22:31,880 --> 00:22:40,060
+اتخيلوا لو هذا الغاز اجا على بروتين زي كل الأشياء
+
+246
+00:22:40,060 --> 00:22:44,780
+اللي موجودة في جسم الإنسان وين مصدر قوته لهذا
+
+247
+00:22:44,780 --> 00:22:53,220
+الغاز ال carbon ال carbonالموجبة والبروتينات اللي
+
+248
+00:22:53,220 --> 00:22:58,280
+في جسم الإنسان والجزيئات اللي في الجسم كلها فيها
+
+249
+00:22:58,280 --> 00:23:02,600
+نيتروجين إيش حيصير؟ هتتفاعل هالجزيئات هذه اللي في
+
+250
+00:23:02,600 --> 00:23:07,440
+جسم الإنسان مع هذا على الكاربون الموجبة هي فيها
+
+251
+00:23:07,440 --> 00:23:10,520
+نيتروجين سالبة على الكاربون الموجبة نفس الفكرة
+
+252
+00:23:10,520 --> 00:23:13,800
+نيتروجين سالبة على الكاربون الموجبة مش هذا بروتين
+
+253
+00:23:14,940 --> 00:23:18,640
+صح ولا لا؟ طب و البني آدم مافيش فيه بروتينات؟ فلو
+
+254
+00:23:18,640 --> 00:23:25,780
+بني آدم شم هذا الغاز إيش هيصير؟ هتيجي البروتينات
+
+255
+00:23:25,780 --> 00:23:28,780
+تتفاعل مع هذا، الآن البروتينات عشان البني آدم
+
+256
+00:23:28,780 --> 00:23:32,260
+يستفيد منها لازم تكون بصورتها الطبيعية، بنفع تكون
+
+257
+00:23:32,260 --> 00:23:36,220
+متفاعلة مع أشياء تانية، شو هيصير في البني آدم؟
+
+258
+00:23:38,260 --> 00:23:43,840
+هيموت، هيتسمم، هيتسمم ويموت هذا اللي صار، هذا
+
+259
+00:23:43,840 --> 00:23:50,960
+الكلام بالظبط اللي صار في أكبر كارثة كيميائية تصنف
+
+260
+00:23:50,960 --> 00:23:56,740
+في التاريخ يعني خلال ساعات قليلة، ساعتين، تلاتة
+
+261
+00:23:56,740 --> 00:23:59,160
+قتلت عشرين ألف واحد
+
+262
+00:24:02,240 --> 00:24:10,120
+إنه مصنع للأسف الشديد في الهند حطوه قريب من السكان
+
+263
+00:24:10,120 --> 00:24:16,620
+في منطقة سكانية مزدحمة و المصنع مبيدات حشرية قريب
+
+264
+00:24:16,620 --> 00:24:21,320
+من السكان حطوه جنب أي مدينة في الهند جنب مدينة
+
+265
+00:24:21,320 --> 00:24:22,940
+بوبالي
+
+266
+00:24:24,330 --> 00:24:29,210
+حطوه جنب مدينة بوبال، بوبال مدينة وين موجودة؟ في
+
+267
+00:24:29,210 --> 00:24:37,330
+الهند وصهريش قديمة متآكلة انفجر صهريش، نفس غاز على
+
+268
+00:24:37,330 --> 00:24:38,050
+السكان
+
+269
+00:24:40,620 --> 00:24:45,840
+مات عشرين ألف غير الناس اللي أصيبوا بالعمى و
+
+270
+00:24:45,840 --> 00:24:53,060
+العهات و الأشياء الكثيرة هذا الكلام في يوم تلاتة
+
+271
+00:24:53,060 --> 00:25:00,060
+لأربعة ليلة تلاتة أربعة اتناشر الف تسعمية و تلاتة
+
+272
+00:25:00,060 --> 00:25:07,390
+و تمانية واضح؟ هذه كانت أكبر كارثة كيميائيةولذلك
+
+273
+00:25:07,390 --> 00:25:12,250
+لما بتتطلعوا على الناس الخضر تعون البيئة بيطلعوا
+
+274
+00:25:12,250 --> 00:25:17,810
+بمظاهرات بتلاقوهم دايما حاملين لافتات على أكبر
+
+275
+00:25:17,810 --> 00:25:25,030
+الكوارث اللي حصلت، الكوارث البيئية، تلت لافتات
+
+276
+00:25:25,030 --> 00:25:27,790
+أساسية بتنحمل، شو هي؟
+
+277
+00:25:31,070 --> 00:25:34,890
+لافتة بتلاقي و مكتوب عليها بوبال شو معنى بوبال
+
+278
+00:25:34,890 --> 00:25:42,530
+نفهم لافتة تانية مكتوب عنها Chernobyl المفاعل اللي
+
+279
+00:25:42,530 --> 00:25:47,570
+عمل الكارثة البيئية في أوكرانيا واللافتة التالتة
+
+280
+00:25:47,570 --> 00:25:53,710
+مكتوب عليها نجازاكي وهيروشيما اه مين اللي عمل
+
+281
+00:25:53,710 --> 00:25:58,390
+نجازاكي وهيروشيما remember it
+
+282
+00:26:01,560 --> 00:26:08,900
+واضح؟ هذه أشهر الكوارث البيئية نجزاكي
+
+283
+00:26:08,900 --> 00:26:15,560
+وهيروشيما هذه كارثة صناعة متعمدة كارثة صناعة
+
+284
+00:26:15,560 --> 00:26:24,180
+متعمدة إبادة مدن كاملة يعني يمكن بوبال و تشيرنوبل
+
+285
+00:26:24,180 --> 00:26:30,340
+يصنفوا عليها كوارث إحمادلكن نجازاكي و هيروشيما هي
+
+286
+00:26:30,340 --> 00:26:37,100
+جرائم حرب جرائم حرب كاملة شوفتوا الجزيئات الصغيرة
+
+287
+00:26:37,100 --> 00:26:41,940
+كيف بتعملوا الأفكار العلمية كيف متصلة ببعض هالبعض
+
+288
+00:26:41,940 --> 00:26:48,000
+زي ما البروتين بتتحد على الكربونة تبعت الفينل ايزو
+
+289
+00:26:48,000 --> 00:26:52,960
+سيانيت البروتين تبع البني آدم اتحد على كربونة
+
+290
+00:26:52,960 --> 00:26:56,280
+الميثل ايزو سيانيت بس المشكلة ان الميثل ايزو
+
+291
+00:26:56,280 --> 00:27:05,970
+سيانيتغاز انتشر في الأجواء بسهولة ولذلك آذى ناس
+
+292
+00:27:05,970 --> 00:27:11,950
+كتير الفينال ايزوسيانيت سائل يعني بيضل فى منطقة
+
+293
+00:27:11,950 --> 00:27:16,430
+المختبر فى خزانة أبخرة بعمل التفاعل بتحكم فيه لكن
+
+294
+00:27:16,430 --> 00:27:22,270
+الميثل ايزوسيانيت غاز والغاز ايش بيعمل؟ بنتشر
+
+295
+00:27:22,270 --> 00:27:24,810
+بنتشر فى كل المختبر
+
+296
+00:27:26,680 --> 00:27:34,540
+الان بيجينا كمان شغلة مساعدة .. شغلة مساعدة لتحديد
+
+297
+00:27:34,540 --> 00:27:38,360
+ال sequence هذه الشغلة Eclavage of Selected
+
+298
+00:27:38,360 --> 00:27:43,100
+Peptide Bonds انه انا لما يكون عندى بروتيل كبير
+
+299
+00:27:43,100 --> 00:27:48,860
+ممكن البروتيل الكبير هذا اجسمه لاربع خمس قطع وكل
+
+300
+00:27:48,860 --> 00:27:53,960
+قطعة اقعد احلي لو بعدين بجمع المجموع تبعهم واضح؟
+
+301
+00:27:54,420 --> 00:27:59,940
+يعني اتخيلوا مرة تانية ان هاي عندى نفترض بيبتايد
+
+302
+00:27:59,940 --> 00:28:04,980
+كبير لو انا اعملت القاتل اجيت اعملته مثلا قطعتين
+
+303
+00:28:04,980 --> 00:28:11,840
+وعرفتهم كسرتهم من مكان معين واضح؟ الآن بعد هيك
+
+304
+00:28:11,840 --> 00:28:15,020
+بحدد هذه ال sequence الأولى بحدد ال sequence
+
+305
+00:28:15,020 --> 00:28:19,760
+التانية بجمعهم بطلع إيش كل ال بيبتايد الفكرة بصير
+
+306
+00:28:19,760 --> 00:28:24,460
+أنه بدي أنزين معين يكسروا من مكان معينفي عند
+
+307
+00:28:24,460 --> 00:28:27,720
+انزيمات كل واحد فيها متخصص يكسر من مكان معين
+
+308
+00:28:27,720 --> 00:28:32,120
+هيتخيلوا انه في انزيم بيكون بيكسر من عند الأزراج
+
+309
+00:28:32,120 --> 00:28:38,200
+مع الأسود في هذه الحالة وين في أزراج مع أسود بس
+
+310
+00:28:38,200 --> 00:28:42,840
+هان بيكسروا من هان واضح؟ كذلك الحال في الانزيمات
+
+311
+00:28:42,840 --> 00:28:49,950
+اللي في الجسم يعني مثلا لتربسين لتربسينبيكسر من
+
+312
+00:28:49,950 --> 00:28:54,750
+عند الـ Carboxyl side of Lysine and Arginine من
+
+313
+00:28:54,750 --> 00:28:58,510
+عند الـ Carboxyl side يعني السيطرة بالـ Bond O تبع
+
+314
+00:28:58,510 --> 00:29:03,750
+الـ Lysine و الـ Arginine الـ Chemotrypsin بيكسر
+
+315
+00:29:03,750 --> 00:29:07,050
+من الـ Carboxyl side للفنلالانين والتيروسين
+
+316
+00:29:07,050 --> 00:29:09,270
+والتريبتوفان
+
+317
+00:29:10,090 --> 00:29:13,830
+السيانوجين برومايد بيكسر من الكربوكس الصيد
+
+318
+00:29:13,830 --> 00:29:19,350
+للميثيونين الكربوكس بيبتدز بيكسر من ال C-terminal
+
+319
+00:29:19,350 --> 00:29:25,930
+بيكسر ال C-terminal amino acid يعني بيطلع له آخر
+
+320
+00:29:25,930 --> 00:29:33,210
+واحد واضح؟ وبناء على ذلك لو احنا مثلا بدنا نيجي
+
+321
+00:29:33,210 --> 00:29:40,220
+نطلع هنا على مثال هاي في عندناببتايد مكوّن من عدة
+
+322
+00:29:40,220 --> 00:29:44,260
+amino acid طبعا دائما بتكون تتخيلوا أنه في ال
+
+323
+00:29:44,260 --> 00:29:49,360
+amino acid هذا الأن terminal وهنا ال C terminal
+
+324
+00:29:51,060 --> 00:29:56,400
+واضح؟ يعني كل amino acid مش بيبين الجزء تبعه N H C
+
+325
+00:29:56,400 --> 00:30:03,680
+H A C double bond O و متحد اذا هذا اللي على الشمال
+
+326
+00:30:03,680 --> 00:30:10,750
+ال N terminal هذا اللي على اليمينالـ C Terminal و
+
+327
+00:30:10,750 --> 00:30:13,930
+هكذا الـ Amino Acid اللي بعده و اللي بعده فلو احنا
+
+328
+00:30:13,930 --> 00:30:18,750
+اتينا و اتطلعنا على هذا ال Amino Acid Alanine,
+
+329
+00:30:18,830 --> 00:30:22,410
+Glycine, Tyrosine, Tryptophan, Serine, Glycine إلى
+
+330
+00:30:22,410 --> 00:30:26,630
+اخرها و اتينا و قلنا بدنا نشوف كيف تكسر مثلا مع
+
+331
+00:30:26,630 --> 00:30:31,130
+الـ Trypsin مع الـ Chemotrypsin مع الـ Cyanogen
+
+332
+00:30:31,130 --> 00:30:41,560
+Bromideيمكن المدى طيب لو اجينا ل .. لتربسيل من وين
+
+333
+00:30:41,560 --> 00:30:49,020
+بيكسل ال lycine نكتبهم هنا و ال arginine lycine و
+
+334
+00:30:49,020 --> 00:30:55,360
+arginine من عند ..الكاربوكسل سايد فانا الآن لو
+
+335
+00:30:55,360 --> 00:30:59,200
+اجيت اطلعت وين في عندي ليسين و وين في عندي أرغنين
+
+336
+00:30:59,200 --> 00:31:03,320
+الانينيجليسين تايروسين تريبتوفانسيرين ليسين هي
+
+337
+00:31:03,320 --> 00:31:12,520
+ليسين الان ايش له ليسين N و C هو بيكسر من وين اذا
+
+338
+00:31:12,520 --> 00:31:19,120
+هى ناتج تكسر له هيجيب لهذه القطة على وحدها وهذه
+
+339
+00:31:19,120 --> 00:31:24,460
+القطة على وحدهاواضح؟ فهتشوفوا الجزء الأول اللي هو
+
+340
+00:31:24,460 --> 00:31:27,520
+لحد اللايسين والجزء التاني اللايسين اليوسين
+
+341
+00:31:27,520 --> 00:31:33,480
+ميثيون، واضحة الفكرة؟ طيب ليش بيتنا مكسرة من
+
+342
+00:31:33,480 --> 00:31:37,450
+البروتين؟ يعني إيش الناس؟الان هذا التفصيل مش
+
+343
+00:31:37,450 --> 00:31:42,390
+موضوعنا يعني هذه انزيمات ربنا خلقها specific لغرض
+
+344
+00:31:42,390 --> 00:31:46,990
+معين انا ماعنديش فكرة اكثر انه ليش هذه الانتقائية
+
+345
+00:31:46,990 --> 00:31:52,650
+سؤالي تحديدا ليش هذه الانتقائية تمام ترجع ايش هو
+
+346
+00:31:52,650 --> 00:31:56,910
+شكل الانزيم وكيف الروابط بتكون متناسبة مع بعض انها
+
+347
+00:31:56,910 --> 00:32:00,990
+تكسر مش هي الموضوع احنا بناخد نتيجة الان كنتيجة
+
+348
+00:32:02,350 --> 00:32:08,230
+مثبتة لـ Trypsin من وين بيكسر من هذه النقطة الان
+
+349
+00:32:08,230 --> 00:32:11,290
+احنا
+
+350
+00:32:11,290 --> 00:32:16,070
+متفقين معاكم متفقين معاكم و احنا بنحكي ما تسألونيش
+
+351
+00:32:16,070 --> 00:32:22,290
+شو تحفظه للامتحان واضح؟ افهمتوا الفكرة العامة هان؟
+
+352
+00:32:22,290 --> 00:32:27,360
+هي فكرة تجزئة للمساعدة في عمل إيش؟الـ sequence
+
+353
+00:32:27,360 --> 00:32:31,260
+الان في النهاية صرنا جادرين نقرا في ال sequences
+
+354
+00:32:31,260 --> 00:32:36,340
+ولا لأ بالتأكيد الان الناس اللي عملوا زي هيك جدروا
+
+355
+00:32:36,340 --> 00:32:42,460
+انهم يحددوا بعض الأشكال يعني على سبيل المثال هذا
+
+356
+00:32:42,460 --> 00:32:49,400
+الانسولين حددوا الشكل تبعه هو عبارة عن سلسلتين
+
+357
+00:32:49,400 --> 00:32:52,980
+هيوم متحدين و في مناطق معينة لما بيجي
+
+358
+00:32:56,210 --> 00:33:01,570
+60×60 سواء بيشبكوا السلسلتين ببعض أو بيعملوا حتى
+
+359
+00:33:01,570 --> 00:33:06,210
+ارتباط داخل يعني لاحظوا هذا 60×60 في نفس السلسلة
+
+360
+00:33:06,210 --> 00:33:12,830
+هذه عملوا die sulfide bond او او لو اجت 60×60 ببعض
+
+361
+00:33:12,830 --> 00:33:17,150
+برضه بيعملوا die sulfide bond الان هذا بيصير
+
+362
+00:33:17,150 --> 00:33:20,930
+السلسلتين اللي من 20 امينواسد و من 30 امينواسد
+
+363
+00:33:20,930 --> 00:33:24,370
+الشكل تبع ايش الانسونات
+
+364
+00:33:25,780 --> 00:33:32,000
+هذا اتكلمنا عنه المرة الماضية شكل الأوكزي توسين كل
+
+365
+00:33:32,000 --> 00:33:36,240
+هذا الكلام نتيجة تطور بهالعلم مابدناش ننسى شغله ان
+
+366
+00:33:36,240 --> 00:33:41,600
+انتوا الآن بتاخدوا مقدمة بسيطة جدا اللي بده بعد
+
+367
+00:33:41,600 --> 00:33:45,920
+هيك يشتغل بهذا الكلام بده ياخد biochemistry one و
+
+368
+00:33:45,920 --> 00:33:49,040
+two و three و analytical methods يتخصص
+
+369
+00:33:49,040 --> 00:33:55,090
+biochemistry ممكن البعض فيكمالان يبدأ يحب هذه
+
+370
+00:33:55,090 --> 00:34:00,330
+المنطقة و بالتالي يطلب انه يتخصص biochemistry و ال
+
+371
+00:34:00,330 --> 00:34:07,930
+biochemistry بالمناسبة من التخصصات العجيبة ليش؟
+
+372
+00:34:07,930 --> 00:34:12,930
+انتبهوا معي لأن ال biochemistry ابتبنى على عدة
+
+373
+00:34:12,930 --> 00:34:15,990
+تخصصات يعني عادة ال chemistry اللى بده يعمل
+
+374
+00:34:15,990 --> 00:34:20,730
+ماجستير و دكتوراه في الكيميا لازم يكون مخلص كيميا
+
+375
+00:34:21,740 --> 00:34:25,080
+بيعمل ماجستير ودكتوراه في الكيميا الآن ال
+
+376
+00:34:25,080 --> 00:34:31,360
+biochemistry لأ خريج biology بيكمل biochemistry
+
+377
+00:34:31,360 --> 00:34:36,740
+خريج زراعة بيكمل biochemistry خريج تحاليل طبية
+
+378
+00:34:36,740 --> 00:34:39,800
+بيكمل biochemistry وفي جزء في التحاليل الطبية
+
+379
+00:34:39,800 --> 00:34:44,620
+biochemistry طبيب بيكمل biochemistry وفي جزء في
+
+380
+00:34:44,620 --> 00:34:49,810
+الطب biochemistry واضح؟كل هدولة ممكن انهم يكملوا
+
+381
+00:34:49,810 --> 00:34:52,770
+biochemistry عشانك حتى لو بتتطلعوا على الدكاترة
+
+382
+00:34:52,770 --> 00:34:55,610
+اللي عندهم biochemistry نفترض في الجامعة او في
+
+383
+00:34:55,610 --> 00:34:59,350
+الجامعات بشكل عام هتلاقوا ان فلان اصلا طبيب فلان
+
+384
+00:34:59,350 --> 00:35:04,170
+زراعة فلان تحاليل طبية الآن خلينا نقول ربع اللي
+
+385
+00:35:04,170 --> 00:35:09,260
+بيعملوا masterتحاليل طبية هم حقيقة بيكملوا
+
+386
+00:35:09,260 --> 00:35:13,060
+biochemistry جزء تاني بيروح بيكمل hematology او
+
+387
+00:35:13,060 --> 00:35:18,040
+microbiology واضح الفكرة فال biochemistry بتبنى
+
+388
+00:35:18,040 --> 00:35:23,560
+على اكتر من تخصص biology chemistry biochemistry
+
+389
+00:35:23,560 --> 00:35:30,200
+biotechnologyزراعة طب طب بيطري كله بيكمل ال
+
+390
+00:35:30,200 --> 00:35:34,780
+biochemistry و كلهم يعني بيشتغلوا في مجالات اللي
+
+391
+00:35:34,780 --> 00:35:37,900
+لها علاقة في ال biochemistry لأن هو في النهاية علم
+
+392
+00:35:37,900 --> 00:35:44,480
+واسع يعني علم إيش علم الحياة الآن بنيجي لل
+
+393
+00:35:44,480 --> 00:35:48,440
+secondary structure of proteins احنا الآن عرفنا ال
+
+394
+00:35:48,440 --> 00:35:54,760
+sequence ال sequence شو هي amino acidsمختلفة
+
+395
+00:35:54,760 --> 00:36:01,520
+متتالية لازم نعرفها هاي عملنا sequence
+
+396
+00:36:01,520 --> 00:36:07,440
+هذا peptideبتطلع عليه اعمله له sequence إجليسين
+
+397
+00:36:07,440 --> 00:36:12,160
+ألانين تيروسين كذا كذا كذا اعمله و خلصنا معرفة
+
+398
+00:36:12,160 --> 00:36:15,980
+الترتيب هو اللي بنسمي احنا ايش ال primary
+
+399
+00:36:15,980 --> 00:36:19,400
+structure اذا ال primary structure هو معرفة ال
+
+400
+00:36:19,400 --> 00:36:24,120
+sequence خلصنا منه الآن بعد هيك هذا كيف بده يصير
+
+401
+00:36:24,120 --> 00:36:28,180
+في الدنيا بده يظله على شكل خط ولا بده ياخد أشكال
+
+402
+00:36:28,180 --> 00:36:35,920
+تانيةهذا بيعمل نفسه بأشكال تانية منها ال secondary
+
+403
+00:36:35,920 --> 00:36:40,760
+structure of proteins في ال secondary structure of
+
+404
+00:36:40,760 --> 00:36:47,580
+protein هذا ممكن ياخد شكل ال helix و ممكن ياخد شكل
+
+405
+00:36:47,580 --> 00:36:52,920
+ال bladed sheath زي الدرج يا بيعمل حاله زي ال
+
+406
+00:36:52,920 --> 00:36:57,690
+helix تطلعوا كيف ال helix هيك بده يلف حالهHelix أو
+
+407
+00:36:57,690 --> 00:37:02,950
+زي الدرج يعني هيك طالع نازل طالع نازل واضح؟ هي
+
+408
+00:37:02,950 --> 00:37:07,630
+كأنه هي القاعدة هيك زي الدرج واضح؟ بنسميه إيش؟
+
+409
+00:37:07,630 --> 00:37:14,610
+Ablated Sheet الآن ال helix نوعان إيش ماله ال
+
+410
+00:37:14,610 --> 00:37:19,410
+helix؟ نقوة ولا نوعين؟ Alpha و Beta مروا عليكم
+
+411
+00:37:19,410 --> 00:37:24,430
+وين؟في الأحياء تعرفوا تعملوهم في البيت لو قلنا
+
+412
+00:37:24,430 --> 00:37:30,850
+لكوا يعملوا Alpha و Beta كيف؟
+
+413
+00:37:30,850 --> 00:37:37,030
+الآن هاي هدولة ال helixات لو أعطيتكوا إياهم مين
+
+414
+00:37:37,030 --> 00:37:41,770
+بده يعرف لمين ال Alpha ومين ال Beta اللي الدوران
+
+415
+00:37:41,770 --> 00:37:45,870
+تبعه إذا مشيت فيه مع أقارب الساعة بنسميه Alpha
+
+416
+00:37:45,870 --> 00:37:50,390
+helix اتطلعوا معاه هيك اتطلعوا كيف أنا بمشي
+
+417
+00:37:53,580 --> 00:37:59,700
+لاحظين كيف الدوران مع أقارب الساعة طبعا لو جلبته
+
+418
+00:37:59,700 --> 00:38:05,100
+برضه هيظل مع أقارب الساعة من أي شكل الآن لو مسكت
+
+419
+00:38:05,100 --> 00:38:13,620
+ال helix التاني طلعوا عكس أقارب الساعة هذا اللي مع
+
+420
+00:38:13,620 --> 00:38:18,380
+أقارب الساعة Alpha helix العكس أقارب الساعة Beta
+
+421
+00:38:18,380 --> 00:38:25,100
+helix واضح؟ الآن كيف بيكونوا موجودينالـ Amino
+
+422
+00:38:25,100 --> 00:38:31,280
+Acids لما بيلفوا على شكل Alpha Helix واضح؟ طبعا
+
+423
+00:38:31,280 --> 00:38:37,280
+أول ما بنقول Alpha Helix هنتواجه بمشكلة تقولولي
+
+424
+00:38:37,280 --> 00:38:42,420
+هاي زي حبل هالتليفون هذا واضح؟ فهذا شكله إيش حبل
+
+425
+00:38:42,420 --> 00:38:48,100
+التليفون Beta Helix المهم الآن ليش؟ لأنه انا لو
+
+426
+00:38:48,100 --> 00:38:52,240
+مسكت هاي ال Primary Structure وإجيت بدي أعمل و
+
+427
+00:38:52,240 --> 00:38:57,850
+ألفه Alpha Helixلاحظوا إيش اللي قاعد يصير؟ كل ما
+
+428
+00:38:57,850 --> 00:39:03,410
+بعمله بيوجع فوق بعضه جادر أنا الأن أعمله Alpha
+
+429
+00:39:03,410 --> 00:39:08,350
+Helix؟ طب إيش اللي بيثبته أنه يصير على شكل Alpha
+
+430
+00:39:08,350 --> 00:39:15,230
+Helix؟ أنه هنا بتيجي بين هذه و هذه و هذه و هذه و
+
+431
+00:39:15,230 --> 00:39:19,910
+هذه روابط هيدروجينية و disulfide bonds لو هذه
+
+432
+00:39:19,910 --> 00:39:25,120
+اتكسرت كله بيجي على بعضهواضح الفكرة؟ إذا اللي
+
+433
+00:39:25,120 --> 00:39:30,980
+بيثبت .. اللي بيثبت الشكل على شكل الـ Alpha Helix
+
+434
+00:39:30,980 --> 00:39:35,580
+هي حقيقة الروابط الهيدروجينية و الـ disulfide
+
+435
+00:39:35,580 --> 00:39:39,560
+bonds هتقولولي من وين الروابط الهيدروجينية؟ سهل مش
+
+436
+00:39:39,560 --> 00:39:44,420
+انتوا في عندكوا أماكن فيها C double bond O و أماكن
+
+437
+00:39:44,420 --> 00:39:51,600
+فيها N H في اللفات الآن لما هدولة بينوجدواالـ N H
+
+438
+00:39:51,600 --> 00:39:55,840
+مع الـ C double bond O شو بيعمله؟ الـ hydrogen
+
+439
+00:39:55,840 --> 00:40:00,460
+bonding فالـ hydrogen bonding هو حقيقة المثبت الـ
+
+440
+00:40:00,460 --> 00:40:05,260
+alpha helix واضح؟ هاي مثلا هنا إذا بتيجوا بتطلعوا
+
+441
+00:40:05,260 --> 00:40:08,720
+هاي C double bond O إحنا متعودين دائما اتفقنا
+
+442
+00:40:08,720 --> 00:40:13,140
+معاكم في الكيميا حتى عشان يفهموا الناس ع بعض إيش
+
+443
+00:40:13,140 --> 00:40:20,310
+بيعملوا؟ لما بيرسموا الـ Oxygen بيرسموه أحمرفي
+
+444
+00:40:20,310 --> 00:40:23,470
+الرسمات في ال molecular structures صار standard
+
+445
+00:40:23,470 --> 00:40:27,830
+يفهموا الكيميائين على بعض ال nitrogen ال oxygen
+
+446
+00:40:27,830 --> 00:40:34,330
+أحمر و ال nitrogen أزرق يعني لما تشوفوا ذره زرقه
+
+447
+00:40:34,330 --> 00:40:41,910
+قولوا هذه إيش نيتروجين و حمرة هذه oxygen الآن اللي
+
+448
+00:40:41,910 --> 00:40:45,770
+بتكون نوعا ما grey هيك سكنه و صغيرة هذه ال
+
+449
+00:40:45,770 --> 00:40:51,210
+hydrogen هي أنا فيه hydrogen إذاالخلاصة هي الشكل
+
+450
+00:40:51,210 --> 00:40:57,510
+هي Oxygen وهي نيتروجين وهي بينهم إيش ال hydrogen
+
+451
+00:40:57,510 --> 00:41:03,550
+bonding هي بينهم ال hydrogen bonding اللي هي بتكون
+
+452
+00:41:03,550 --> 00:41:12,070
+عادة ما بين ال Oxygen وهذه اللي ضعيفة هذه رابط
+
+453
+00:41:12,070 --> 00:41:17,240
+أصلية اللي مع ال nitrogen لأنه أساسا هي N Hفالـ
+
+454
+00:41:17,240 --> 00:41:25,640
+hydrogen bonding وينها؟ OH هذه الروابط بالاضافة لـ
+
+455
+00:41:25,640 --> 00:41:31,380
+disulfide bonds هم اللي بيعملولي إيش؟ الشكل الـ
+
+456
+00:41:31,380 --> 00:41:34,480
+alpha helix الآن لاحظوا هذا ال alpha helix درسينه
+
+457
+00:41:34,480 --> 00:41:39,200
+كويس يعني كل turn فيه عارفين إيش يعني turn؟ يعني
+
+458
+00:41:39,200 --> 00:41:44,250
+لو جيت من هذه النقطة لهذه النقطة لفة كاملةاسمها
+
+459
+00:41:44,250 --> 00:41:49,170
+ايش تيرن كل تيرن فيها تلاتة وستة من عشرة amino
+
+460
+00:41:49,170 --> 00:41:54,390
+acids يمكن البعض يقول طب ما هم ال amino acids مش
+
+461
+00:41:54,390 --> 00:41:59,610
+متساويات كيف بالظبط كل تيرن جد التانية مية في
+
+462
+00:41:59,610 --> 00:42:08,410
+المية مين تعطيني تفسير لأ
+
+463
+00:42:08,410 --> 00:42:11,410
+ليش كل تيرن جد التانية
+
+464
+00:42:14,220 --> 00:42:19,640
+رغم انه انا مابحكيش .. انا مابحكيش عن amino acid
+
+465
+00:42:19,640 --> 00:42:26,400
+واحد polymer عامل to the N واضحة الفكرة؟ انا بحكي
+
+466
+00:42:26,400 --> 00:42:29,420
+عن different .. different amino acids يعني هدولة
+
+467
+00:42:29,420 --> 00:42:33,340
+التلاتة وستة من عشرة ممكن يكونوا alanine، glycine،
+
+468
+00:42:33,340 --> 00:42:37,440
+tryptophan التلاتة وستة مع جزء من اللي بعده ممكن
+
+469
+00:42:37,440 --> 00:42:43,340
+يكونوا valine، كذا كذا لكن كل turn جدت تانية، ليش؟
+
+470
+00:42:57,750 --> 00:43:03,530
+أه اتفقنا احنا انه لما بنكون ال peptide في عندى
+
+471
+00:43:03,530 --> 00:43:11,450
+جزء ثابت الجزء الثابت الجزء الثابت اللي هو ايش N C
+
+472
+00:43:11,450 --> 00:43:19,700
+C double bond Oوكمان N C C double bond O ال R هذه
+
+473
+00:43:19,700 --> 00:43:25,540
+انها تكون مثلا H انها تكون CH3 طال على برا فهذا
+
+474
+00:43:25,540 --> 00:43:30,940
+الجزء الثابت في الهيكل ثابت N C C double bond O
+
+475
+00:43:30,940 --> 00:43:35,020
+فكأنه عندي تلاتة وستة من عشرة N C C double bond O
+
+476
+00:43:35,020 --> 00:43:42,480
+ال R طال على برا مش داخلة في السلسلة واضح ال R
+
+477
+00:43:43,570 --> 00:43:49,610
+طالعة للخارج لكن المتكرر تلاتة و ستة من عشرة من
+
+478
+00:43:49,610 --> 00:43:55,370
+وحدة ال NCC double bond واضح الفكرة؟ و هدولة
+
+479
+00:43:55,370 --> 00:43:59,890
+معروفة طولهم كمان خمسة و أربعة من عشرة أنجستروم
+
+480
+00:43:59,890 --> 00:44:04,450
+بير تيرن يعني كل لفة خمسة و أربعة من عشرة أنجستروم
+
+481
+00:44:04,450 --> 00:44:10,170
+زي ما انتوا ملاحظين انه يعني ال alpha helix محدد
+
+482
+00:44:10,170 --> 00:44:16,780
+تماما و واضحعند الناس اللي بيشتغلوا فيه الان
+
+483
+00:44:16,780 --> 00:44:22,400
+الاحتمال التاني انه ممكن يكونوا ايش بـlated sheet
+
+484
+00:44:22,400 --> 00:44:28,260
+زي الدرج بهذا الشكل و ايضا محددين و بتمسكوا
+
+485
+00:44:28,260 --> 00:44:33,100
+بـhydrogen bonding و لاحظوا لما بيكونوا زي الدرج
+
+486
+00:44:33,100 --> 00:44:38,640
+بيكونوا سلسلتين اقبال بعض و بيشبكوا بـhydrogen
+
+487
+00:44:38,640 --> 00:44:44,690
+bonding اذا ال secondary structure لبروتينيا إما
+
+488
+00:44:44,690 --> 00:44:50,230
+Alpha Helix أو Pleated Sheet الآن اعرفنا ال
+
+489
+00:44:50,230 --> 00:44:54,250
+secondary structure نيجي على ال tertiary structure
+
+490
+00:44:54,250 --> 00:44:57,990
+قولنا Alpha Helix هي Alpha Helix يا ترها ال Alpha
+
+491
+00:44:57,990 --> 00:45:04,190
+Helix هذا كيف بيكون موجود هي هيك Alpha Helix ولا
+
+492
+00:45:04,190 --> 00:45:12,310
+لأ طب و هيك Alpha Helix ولا لأ يعني ببساطة اتخيلوا
+
+493
+00:45:12,310 --> 00:45:20,630
+الحياةعارفين الحياة؟ الصعبان الصعبان لما بيكون هيك
+
+494
+00:45:20,630 --> 00:45:28,490
+عدل بتخافوا منه ولا لأ طب و لما يكون ملف في حاله و
+
+495
+00:45:28,490 --> 00:45:34,190
+مكور هذا صعبان وهذا صعبان و في الحالتين بتخافوا
+
+496
+00:45:34,190 --> 00:45:38,530
+منه الآن ال alpha helix نفس الفكرة يا إما بيكون
+
+497
+00:45:38,530 --> 00:45:46,080
+مكور حاله بنقول عنه globular كراويأو بيكون بهذا
+
+498
+00:45:46,080 --> 00:45:52,640
+الشكل بنقول عنه fibrous خيطي واضح؟ فبعد ما انا
+
+499
+00:45:52,640 --> 00:45:56,220
+عملت ال alpha helix هل يا ترى ال alpha helix بيكون
+
+500
+00:45:56,220 --> 00:46:03,520
+زي الحيا العدلة ولا اللي في الشتاء امكورة حالها؟
+
+501
+00:46:03,520 --> 00:46:07,360
+اذا بيصير عندى ال tertiary structure ان بعد ما انا
+
+502
+00:46:07,360 --> 00:46:13,960
+عرفت ال sequence ال primary اعملت helixsecondary
+
+503
+00:46:13,960 --> 00:46:20,040
+الان هذا ال helix يكون كراوي ولا خيطي هذا ايش بقول
+
+504
+00:46:20,040 --> 00:46:24,040
+عنه ال tertiary structure فعيصير عند ال tertiary
+
+505
+00:46:24,040 --> 00:46:28,920
+structure لل proteins is either fibrous or
+
+506
+00:46:28,920 --> 00:46:34,140
+globular نفس ال alpha helix بعد ما صار alpha helix
+
+507
+00:46:34,140 --> 00:46:38,620
+تخيلوه ببساطة زي حبل التليفون مكور على بعض ولا زي
+
+508
+00:46:38,620 --> 00:46:45,800
+الخيطfibrous or globular طبعا حسب نوع البروتينات
+
+509
+00:46:45,800 --> 00:46:51,920
+لاحظوا الفيبروس بيكونه water insoluble هي
+
+510
+00:46:51,920 --> 00:46:56,820
+البروتينات اللتي لا تدوب في الماء من أمثلتها
+
+511
+00:46:56,820 --> 00:47:03,620
+الكريتينز اللي هي ال protective tissues ال hair ال
+
+512
+00:47:03,620 --> 00:47:08,190
+nailsالـ Collagens اللي هي الـ connective tissues
+
+513
+00:47:08,190 --> 00:47:12,130
+لـ blood vessels الأوعية الدموية لاحظوا سبحان الله
+
+514
+00:47:12,130 --> 00:47:16,790
+كيف الـ Hemoglobin بروتين و الوعاء الدموي بروتين
+
+515
+00:47:16,790 --> 00:47:21,830
+الآن و بيمشي فيهم ميه ال Hemoglobin بدوب في الميه
+
+516
+00:47:21,830 --> 00:47:26,710
+الوعاء الدموي من يوم الإنسان ينولد لحد ما يموت و
+
+517
+00:47:26,710 --> 00:47:34,130
+الميه ماشية في قلبه و بيدوبش ماشي الدموسط ماء؟ من
+
+518
+00:47:34,130 --> 00:47:37,830
+يوم ما الإنسان ينولد لحد ما الإنسان يموت والدم
+
+519
+00:47:37,830 --> 00:47:42,510
+ماشي وهو الوعاء الدموي مش عماله إيش يدوب إذا
+
+520
+00:47:42,510 --> 00:47:46,030
+الوعاء الدموي ال blood vessel water soluble ولا
+
+521
+00:47:46,030 --> 00:47:52,150
+insoluble هذا من نوع إيش ال fibrous proteins بينما
+
+522
+00:47:52,150 --> 00:47:57,510
+ال hemoglobin مثلا globular protein water soluble
+
+523
+00:47:57,510 --> 00:48:03,230
+بيمشي مع ال إيش؟ مع الدمزي ال enzymes ال hormones
+
+524
+00:48:03,230 --> 00:48:07,770
+ل transport proteins storage proteins الآن هدول
+
+525
+00:48:07,770 --> 00:48:13,550
+ايش اللي بيميزهم في انه في الشكل الكراوي هذا بتكون
+
+526
+00:48:13,550 --> 00:48:17,790
+ال polar are groups outside يعني هذا لما بيعمل كرة
+
+527
+00:48:17,790 --> 00:48:23,490
+تمام مش في انا عندي are groups في ال globular هذي
+
+528
+00:48:23,490 --> 00:48:28,390
+ال are groups ال polar للخارج فلما تيجي مية polar
+
+529
+00:48:30,110 --> 00:48:34,570
+والميّه بولر Like Dissolve، Dissolves Like، اذا
+
+530
+00:48:34,570 --> 00:48:37,730
+صاروا بيدوبوا في الميّه، صاروا ايش بيعملوا؟
+
+531
+00:48:37,730 --> 00:48:42,270
+بيدوبوا في الميّه، بينما في ال fibrous ال water ..
+
+532
+00:48:42,270 --> 00:48:47,070
+ال boiler للداخل،
+
+533
+00:48:47,070 --> 00:48:51,850
+بناء على ذلك هييجي الشكل العام يلاقي ميّه بولر لكن
+
+534
+00:48:51,850 --> 00:48:58,050
+هيتواجه ال non-polar groupsالان لاحظوا كيف جثة ال
+
+535
+00:48:58,050 --> 00:49:03,470
+polarity بتفرج لل texture بتخلي واحد كروي و يدوب
+
+536
+00:49:03,470 --> 00:49:10,130
+في الميه و يمشي و التاني يكون fibrous و water
+
+537
+00:49:10,130 --> 00:49:13,790
+insoluble فال hemoglobin بروتيل و الوعاء الدوموي
+
+538
+00:49:13,790 --> 00:49:18,630
+بروتيل ال hemoglobin دايم و الوعاء الدوموي مش دايم
+
+539
+00:49:18,630 --> 00:49:25,730
+الشعر و الأضافر و الجلدما بدوبوش ولا كان البني آدم
+
+540
+00:49:25,730 --> 00:49:34,650
+كل ما بتغسل بتلاشى اه ملاحظين هذا اذا احنا اللي
+
+541
+00:49:34,650 --> 00:49:38,630
+بنسمي ال tertiary structure of proteins is either
+
+542
+00:49:38,630 --> 00:49:45,650
+globular or fibrous بيجينا اخر شغلةطبعا و انا ما
+
+543
+00:49:45,650 --> 00:49:50,150
+اعطيكم نقطة بسيطة انه لو اتطلعتوا انتوا حتى على
+
+544
+00:49:50,150 --> 00:49:53,650
+الحبل اللي معي عشان هذا يصير يعمل كرة عشان هذا
+
+545
+00:49:53,650 --> 00:49:58,850
+يصير يعمل كرة بدوا يتن من اماكن معينة اتطلعوا هاي
+
+546
+00:49:58,850 --> 00:50:03,230
+من هذا المكان بيعمل turn من هذا المكان بيعمل turn
+
+547
+00:50:03,230 --> 00:50:08,290
+تاني من هنا بيعمل turn ثالث من اي نقطة تحديدا بيتن
+
+548
+00:50:09,810 --> 00:50:13,410
+واضح؟ مش هذا لما بيعمل الشكل ال globular قاعد
+
+549
+00:50:13,410 --> 00:50:17,910
+بيتنه؟ طلعوا شايفينه كيف؟ تلقاه بيتنه من هنا من أي
+
+550
+00:50:17,910 --> 00:50:23,450
+نقطة بيتنه؟ بيتنه من عند ال amino acid لبرولين
+
+551
+00:50:23,450 --> 00:50:31,150
+البرولين الوحيد اللي قلنا انه مافيش فيه NH2 فيه NH
+
+552
+00:50:32,660 --> 00:50:37,340
+و بناء على ذلك كل ال amino acids اللي فيها أساسا
+
+553
+00:50:37,340 --> 00:50:41,920
+un-H2 و في الوحيد البرولين فيه un-H هدول لما
+
+554
+00:50:41,920 --> 00:50:47,940
+بيعملوا ال peptide هيخسروا H، شو حيظل عنده هنا؟ un
+
+555
+00:50:47,940 --> 00:50:52,600
+-H هذا لما يعمل شو حيظل؟ من عند البرولين مفيش
+
+556
+00:50:52,600 --> 00:50:58,940
+hydrogen bonding هنا في hydrogen bonding مازال في
+
+557
+00:50:58,940 --> 00:51:03,770
+H، لحظة هي عند البرولينهذا الـ Peptide bond اللي
+
+558
+00:51:03,770 --> 00:51:10,210
+عند البرولين فيه un-etched؟ إذا لم يكن تاني، فهي
+
+559
+00:51:10,210 --> 00:51:15,970
+Amino Acid تاني، فهي un-etched؟ فهي un-etched،
+
+560
+00:51:15,970 --> 00:51:20,980
+كانت un-etched تمو، ضال، un-etched، هذا كانأنا
+
+561
+00:51:20,980 --> 00:51:25,360
+أكتر أنا فعند البرولين مافيش hydrogen bonding وين
+
+562
+00:51:25,360 --> 00:51:28,080
+مافيش hydrogen bonding الجثيات بتتنيه مش احنا
+
+563
+00:51:28,080 --> 00:51:31,860
+قولنا لماسك ال helix ال hydrogen bonding الآن عند
+
+564
+00:51:31,860 --> 00:51:36,200
+البرولين مافيش hydrogen bonding من عنده بيصير إيش
+
+565
+00:51:36,200 --> 00:51:40,580
+التانية عارفين الحديث اللي بيقول أو المقولة اللي
+
+566
+00:51:40,580 --> 00:51:46,940
+بتقول من هناتأتي إيش؟ الهزيمة مقولة صلاح الدين لما
+
+567
+00:51:46,940 --> 00:51:49,980
+لجى الخيمة اللى بتجرهاش القرآن الكريم قال من هنا
+
+568
+00:51:49,980 --> 00:51:54,720
+تأتي الهزيمة ومن أين يأتي الانثناء في ال globular؟
+
+569
+00:51:54,720 --> 00:52:00,000
+من عند البرولين بسبب عدم وجود ال hydrogen bonding
+
+570
+00:52:00,000 --> 00:52:05,830
+أخر شغلةأخر slide، في عندنا شيء بنسميه
+
+571
+00:52:05,830 --> 00:52:09,910
+الـquaternary structure of proteins الـquaternary
+
+572
+00:52:09,910 --> 00:52:14,790
+structure of proteins هو عبارة عن aggregate تجمع
+
+573
+00:52:14,790 --> 00:52:22,150
+لعدة أشكال، يعني مثلا من أمثلته في ال .. ال
+
+574
+00:52:22,150 --> 00:52:26,170
+hemoglobin في ال hemoglobin، هين عملت أنا كرة،
+
+575
+00:52:26,170 --> 00:52:32,270
+globular structure تمام؟الـ Hemoglobin حقيقة عبارة
+
+576
+00:52:32,270 --> 00:52:33,770
+عن نوعين
+
+577
+00:52:35,830 --> 00:52:40,690
+نوعين من الكورات خلينا نتخيله بهذا الشكل طبعا فيهم
+
+578
+00:52:40,690 --> 00:52:44,850
+سلاسل amino acids واحدة بنسميها alpha unit فيها
+
+579
+00:52:44,850 --> 00:52:50,730
+141 amino acid وعملة كورة معينة والتانية ال beta
+
+580
+00:52:50,730 --> 00:52:57,690
+unit 146 amino acid فلاحظوا ال 141 عملالها كورة و
+
+581
+00:52:57,690 --> 00:53:02,010
+ال 146 عمل كورة واحدة سمينها alpha والتانية beta
+
+582
+00:53:02,010 --> 00:53:07,530
+الآن ال hemoglobin بالمجمل هو عبارة عن إيش؟سلسلتين
+
+583
+00:53:07,530 --> 00:53:13,930
+Alpha مع سلسلتين Beta موجودين على شكل tetrahedral
+
+584
+00:53:13,930 --> 00:53:20,850
+arrangement متذكرين التتراهيدرال اللي اتعلمناه زي
+
+585
+00:53:20,850 --> 00:53:28,010
+هيك هاي كرة تنتين نفترض Alpha و Alpha زي هيك يعني
+
+586
+00:53:28,010 --> 00:53:30,310
+ال Hemoglobin تنتين Alpha
+
+587
+00:53:38,910 --> 00:53:45,880
+الشيء الجميل ان احنا بدأنا ال courseفي المحاضرة
+
+588
+00:53:45,880 --> 00:53:51,220
+الأولى بال tetrahedral structure والان ننهي ال
+
+589
+00:53:51,220 --> 00:53:56,280
+course بال tetrahedral arrangement اللى موجودة في
+
+590
+00:53:56,280 --> 00:53:59,700
+ال hemoglobin الدرس القادم ان شاء الله بيكون
+
+591
+00:53:59,700 --> 00:54:01,560
+مراجعة وحل امتحانات
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..ab5049a9c1ee46e3f328ab2e7517035a38f7572b
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 5005, "start": 20.99, "end": 50.05, "text": "بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في تفاعلات ال alkenes وقلنا اللى بينظر للموضوع نظرة كلية الموضوع بسيط الموضوع انه double bond هيوم رابطتين بالاضافة بتصير single bond هذه العملية شو بنسميها عملية addition عملية addition واتفقنا ان في ال addition فى عندنا مكونات لل addition فى عندنا ال alkene", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 1975, 2655, 4117, 19528, 8315, 8978, 6055, 5172, 995, 30241, 9307, 2423, 419, 2653, 279, 4032, 4587, 1211, 8315, 13672, 7578, 4724, 9957, 19913, 2288, 5296, 19528, 2407, 11242, 45367, 8717, 19913, 25720, 28242, 10632, 9673, 2407, 11242, 45367, 4724, 3794, 1829, 9566, 9673, 2407, 11242, 45367, 16472, 3224, 3834, 6086, 8032, 1829, 20498, 12602, 16758, 9566, 2655, 9957, 20666, 46958, 31845, 3660, 39894, 9381, 13546, 2167, 6086, 29538, 18863, 42213, 10632, 13412, 2407, 44945, 38251, 1829, 11296, 6225, 42213, 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"probability": 0.9943033854166666}, {"start": 747.06, "end": 747.6, "word": " قاعدة", "probability": 0.990966796875}, {"start": 747.6, "end": 748.06, "word": " Markov", "probability": 0.9814453125}, {"start": 748.06, "end": 748.52, "word": " Nikov", "probability": 0.94384765625}], "temperature": 1.0}, {"id": 31, "seek": 75466, "start": 749.48, "end": 754.66, "text": "الناتج ببساطة نفس اللي موجود عندكم بدل كلمة OH اللي بالأحمر شو بتحطه", "tokens": [6027, 1863, 9307, 7435, 4724, 3555, 3794, 41193, 3660, 8717, 36178, 13672, 1829, 3714, 29245, 23328, 43242, 24793, 47525, 1211, 9122, 19528, 3660, 13931, 13672, 1829, 20666, 10721, 5016, 29973, 13412, 2407, 39894, 5016, 9566, 3224], "avg_logprob": -0.21811655566499039, "compression_ratio": 1.2577319587628866, "no_speech_prob": 0.0, "words": [{"start": 749.48, "end": 750.16, "word": "الناتج", "probability": 0.6900634765625}, {"start": 750.16, "end": 750.8, "word": " ببساطة", "probability": 0.91806640625}, {"start": 750.8, "end": 751.1, "word": " نفس", "probability": 0.9345703125}, {"start": 751.1, "end": 751.28, "word": " اللي", "probability": 0.669677734375}, {"start": 751.28, "end": 751.66, "word": " موجود", "probability": 0.9378255208333334}, {"start": 751.66, "end": 752.02, "word": " عندكم", "probability": 0.9716796875}, {"start": 752.02, "end": 752.36, "word": " بدل", "probability": 0.901611328125}, {"start": 752.36, "end": 752.78, "word": " كلمة", "probability": 0.9658203125}, {"start": 752.78, "end": 753.02, "word": " OH", "probability": 0.52587890625}, {"start": 753.02, "end": 753.34, "word": " اللي", "probability": 0.885986328125}, {"start": 753.34, "end": 753.76, "word": " بالأحمر", "probability": 0.908935546875}, {"start": 753.76, "end": 753.96, "word": " شو", "probability": 0.6455078125}, {"start": 753.96, "end": 754.66, "word": " بتحطه", "probability": 0.78326416015625}], "temperature": 1.0}, {"id": 32, "seek": 79034, "start": 761.06, "end": 790.34, "text": "إذا إضافة الماء أو إضافة الـ HPR يمكن أن تتم بطريقة ولا بطريقتين وهنا بيصير مهم عندي جدا أن أنتبه لل reactant للمتفاعل يعني لو احنا مرات بدنا نسألكوا عن هذا الموضوع ممكن نجيبلكوا ال reactant مع هذا نقولكوا اكتبوا النتيجة ممكن نجيب هذا ال reactant و ال product و نقولكوا شو اللي استعملته كمتفاعل كتبولي ال reactant اللي على السهل", "tokens": [28814, 15730, 11933, 11242, 31845, 3660, 9673, 16606, 34051, 11933, 11242, 31845, 3660, 2423, 39184, 12557, 49, 7251, 43020, 14739, 6055, 39237, 4724, 9566, 16572, 28671, 49429, 4724, 9566, 16572, 38149, 9957, 37037, 8315, 4724, 1829, 9381, 13546, 3714, 16095, 18871, 16254, 10874, 28259, 14739, 5551, 29399, 3555, 3224, 24976, 4515, 394, 5296, 19528, 2655, 5172, 995, 30241, 37495, 22653, 45164, 1975, 5016, 8315, 3714, 2288, 9307, 47525, 8315, 8717, 3794, 10721, 23275, 14407, 18871, 23758, 9673, 2407, 11242, 45367, 3714, 43020, 8717, 7435, 1829, 3555, 23275, 14407, 2423, 4515, 394, 20449, 23758, 8717, 39648, 4117, 14407, 1975, 4117, 2655, 3555, 14407, 28239, 31371, 7435, 3660, 3714, 43020, 8717, 7435, 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0.98095703125}, {"start": 782.98, "end": 783.1, "word": " ال", "probability": 0.96484375}, {"start": 783.1, "end": 783.64, "word": " reactant", "probability": 0.990478515625}, {"start": 783.64, "end": 783.8, "word": " و", "probability": 0.8603515625}, {"start": 783.8, "end": 783.9, "word": " ال", "probability": 0.8935546875}, {"start": 783.9, "end": 784.36, "word": " product", "probability": 0.96435546875}, {"start": 784.36, "end": 784.72, "word": " و", "probability": 0.9814453125}, {"start": 784.72, "end": 785.08, "word": " نقولكوا", "probability": 0.9239501953125}, {"start": 785.08, "end": 785.26, "word": " شو", "probability": 0.93994140625}, {"start": 785.26, "end": 785.4, "word": " اللي", "probability": 0.9482421875}, {"start": 785.4, "end": 786.3, "word": " استعملته", "probability": 0.9451904296875}, {"start": 786.3, "end": 787.36, "word": " كمتفاعل", "probability": 0.8946126302083334}, {"start": 787.36, "end": 789.04, "word": " كتبولي", "probability": 0.68095703125}, {"start": 789.04, "end": 789.14, "word": " ال", "probability": 0.939453125}, {"start": 789.14, "end": 789.7, "word": " reactant", "probability": 0.986572265625}, {"start": 789.7, "end": 789.88, "word": " اللي", "probability": 0.96337890625}, {"start": 789.88, "end": 790.0, "word": " على", "probability": 0.72509765625}, {"start": 790.0, "end": 790.34, "word": " السهل", "probability": 0.5555013020833334}], "temperature": 1.0}, {"id": 33, "seek": 81254, "start": 791.08, "end": 812.54, "text": "واضحك الصورة؟ طبعا لو إجينا سألنا هذه النواتج ال markovnikov product هذا بيسموه markovnikov product و ال antimarkovnikov product ما العلاقة بينهما؟ isomers أي نوع من ال isomers هذا اللي بقصدي", "tokens": [2407, 46958, 5016, 4117, 31767, 13063, 3660, 22807, 23032, 3555, 3615, 995, 45164, 11933, 7435, 1829, 8315, 8608, 10721, 1211, 8315, 29538, 28239, 2407, 9307, 7435, 2423, 1491, 5179, 13123, 5179, 1674, 23758, 4724, 1829, 38251, 2407, 3224, 1491, 5179, 13123, 5179, 1674, 4032, 2423, 46141, 809, 5179, 13123, 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"probability": 0.5185546875}, {"start": 796.68, "end": 797.64, "word": " markovnikov", "probability": 0.68328857421875}, {"start": 797.64, "end": 798.18, "word": " product", "probability": 0.79443359375}, {"start": 798.18, "end": 798.5, "word": " هذا", "probability": 0.669921875}, {"start": 798.5, "end": 798.92, "word": " بيسموه", "probability": 0.87177734375}, {"start": 798.92, "end": 799.6, "word": " markovnikov", "probability": 0.898681640625}, {"start": 799.6, "end": 800.1, "word": " product", "probability": 0.955078125}, {"start": 800.1, "end": 800.5, "word": " و", "probability": 0.59814453125}, {"start": 800.5, "end": 800.66, "word": " ال", "probability": 0.8779296875}, {"start": 800.66, "end": 801.7, "word": " antimarkovnikov", "probability": 0.843994140625}, {"start": 801.7, "end": 802.22, "word": " product", "probability": 0.9638671875}, {"start": 802.22, "end": 802.36, "word": " ما", "probability": 0.68017578125}, {"start": 802.36, "end": 802.92, "word": " العلاقة", "probability": 0.9606119791666666}, {"start": 802.92, "end": 806.02, "word": " بينهما؟", "probability": 0.78436279296875}, {"start": 806.02, "end": 810.0, "word": " isomers", "probability": 0.738525390625}, {"start": 810.0, "end": 810.32, "word": " أي", "probability": 0.53466796875}, {"start": 810.32, "end": 810.68, "word": " نوع", "probability": 0.996826171875}, {"start": 810.68, "end": 810.9, "word": " من", "probability": 0.99609375}, {"start": 810.9, "end": 811.06, "word": " ال", "probability": 0.95654296875}, {"start": 811.06, "end": 811.7, "word": " isomers", "probability": 0.958984375}, {"start": 811.7, "end": 811.92, "word": " هذا", "probability": 0.7802734375}, {"start": 811.92, "end": 812.06, "word": " اللي", "probability": 0.97705078125}, {"start": 812.06, "end": 812.54, "word": " بقصدي", "probability": 0.86279296875}], "temperature": 1.0}, {"id": 34, "seek": 84521, "start": 816.07, "end": 845.21, "text": "الـ Markovnikov's product والـ Antimarkovnikov's product They are isomers ليش؟ لأنه نفس الذرات وحطيت H و OH حطيت ال H و OH بنفس المواقع ولا بمواقع مختلفة طالما مواقع مختلفة Different bonding عطول الجواب Structural isomers They are structural isomers", "tokens": [6027, 39184, 3934, 5179, 13123, 5179, 311, 1674, 16070, 39184, 5130, 332, 809, 5179, 13123, 5179, 311, 1674, 814, 366, 307, 298, 433, 32239, 8592, 22807, 5296, 33456, 3224, 8717, 36178, 32545, 2288, 9307, 4032, 5016, 9566, 36081, 389, 4032, 13931, 11331, 9566, 36081, 2423, 389, 4032, 13931, 4724, 1863, 36178, 9673, 14407, 4587, 3615, 49429, 4724, 2304, 14407, 4587, 3615, 3714, 46456, 46538, 3660, 23032, 6027, 15042, 3714, 14407, 4587, 3615, 3714, 46456, 46538, 3660, 20825, 28824, 6225, 9566, 12610, 25724, 14407, 3555, 745, 1757, 1807, 307, 298, 433, 814, 366, 15067, 307, 298, 433], "avg_logprob": -0.2139175208573489, "compression_ratio": 1.6650246305418719, "no_speech_prob": 0.0, "words": [{"start": 816.07, "end": 816.47, "word": "الـ", "probability": 0.435791015625}, {"start": 816.47, "end": 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"probability": 0.9884765625}, {"start": 831.25, "end": 832.25, "word": " مختلفة", "probability": 0.992919921875}, {"start": 832.25, "end": 833.97, "word": " طالما", "probability": 0.9108072916666666}, {"start": 833.97, "end": 834.77, "word": " مواقع", "probability": 0.9820556640625}, {"start": 834.77, "end": 835.71, "word": " مختلفة", "probability": 0.991455078125}, {"start": 835.71, "end": 836.41, "word": " Different", "probability": 0.349365234375}, {"start": 836.41, "end": 837.67, "word": " bonding", "probability": 0.83349609375}, {"start": 837.67, "end": 838.25, "word": " عطول", "probability": 0.6844889322916666}, {"start": 838.25, "end": 839.17, "word": " الجواب", "probability": 0.9793294270833334}, {"start": 839.17, "end": 840.91, "word": " Structural", "probability": 0.91748046875}, {"start": 840.91, "end": 842.89, "word": " isomers", "probability": 0.9661458333333334}, {"start": 842.89, "end": 843.47, "word": " They", "probability": 0.7275390625}, {"start": 843.47, "end": 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{"start": 1927.88, "end": 1928.44, "word": " بروبين", "probability": 0.9822998046875}, {"start": 1928.44, "end": 1928.9, "word": " أكسيد،", "probability": 0.988671875}, {"start": 1928.9, "end": 1930.3, "word": " بروبين", "probability": 0.98046875}, {"start": 1930.3, "end": 1931.04, "word": " أكس", "probability": 0.9959309895833334}], "temperature": 1.0}, {"id": 81, "seek": 195470, "start": 1931.88, "end": 1954.7, "text": "ما هذا الالكين؟ واحد CH2 double bond CH CH3 هذا الابروبيل و لذلك بيصير ابروبيل أكسيد فلو جيبنالكم مثلا سؤال ابروبيل أكسيد is also called وقتها بتقولوا 2-methyl oxirane 2-methyl oxirane is also called", "tokens": [15042, 23758, 2423, 6027, 4117, 9957, 22807, 36764, 24401, 5995, 17, 3834, 6086, 5995, 5995, 18, 23758, 2423, 16758, 32887, 21292, 1211, 4032, 5296, 8848, 23275, 4724, 1829, 9381, 13546, 48127, 32887, 21292, 1211, 5551, 4117, 3794, 25708, 6156, 1211, 2407, 10874, 1829, 3555, 8315, 23275, 2304, 50113, 15040, 8608, 33604, 6027, 48127, 32887, 21292, 1211, 5551, 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ابروبيل", "probability": 0.8106689453125}, {"start": 1946.1, "end": 1946.82, "word": " أكسيد", "probability": 0.9859619140625}, {"start": 1946.82, "end": 1947.12, "word": " is", "probability": 0.65673828125}, {"start": 1947.12, "end": 1947.9, "word": " also", "probability": 0.87646484375}, {"start": 1947.9, "end": 1948.7, "word": " called", "probability": 0.923828125}, {"start": 1948.7, "end": 1949.3, "word": " وقتها", "probability": 0.5801595052083334}, {"start": 1949.3, "end": 1950.14, "word": " بتقولوا", "probability": 0.6805826822916666}, {"start": 1950.14, "end": 1950.78, "word": " 2", "probability": 0.1497802734375}, {"start": 1950.78, "end": 1951.2, "word": "-methyl", "probability": 0.73175048828125}, {"start": 1951.2, "end": 1951.94, "word": " oxirane", "probability": 0.8427734375}, {"start": 1951.94, "end": 1952.36, "word": " 2", "probability": 0.468017578125}, {"start": 1952.36, "end": 1952.78, "word": "-methyl", "probability": 0.948486328125}, {"start": 1952.78, "end": 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"word": " nomenclature", "probability": 0.9345703125}], "temperature": 1.0}, {"id": 84, "seek": 202127, "start": 1997.15, "end": 2021.27, "text": "يستعمل عن طلاب الكيميا للـ heterocyclic compounds واضح؟ hence Vedman system of nomenclature الآن خلينا ناخد أمثلة انسهل الموضوع هي كذا مثال جيبنا أكمل مع pear acid شو عرفني pear acid؟ تلت أكسوجينات في كل الأحوال شو اللي بدى أعمله؟ أشيل ال double bond؟", "tokens": [1829, 14851, 25957, 1211, 18871, 23032, 15040, 3555, 33251, 32640, 25528, 24976, 39184, 20789, 31078, 66, 1050, 21810, 4032, 46958, 5016, 22807, 16678, 26084, 1601, 1185, 295, 297, 4726, 3474, 1503, 6024, 48506, 16490, 20292, 8315, 8717, 47283, 3215, 5551, 2304, 12984, 37977, 16472, 3794, 3224, 1211, 9673, 2407, 11242, 45367, 39896, 9122, 15730, 50113, 6027, 10874, 1829, 3555, 8315, 5551, 24793, 1211, 20449, 37320, 8258, 13412, 2407, 6225, 28480, 22653, 37320, 8258, 22807, 6055, 1211, 2655, 5551, 4117, 3794, 29245, 9957, 9307, 8978, 28242, 16247, 5016, 2407, 6027, 13412, 2407, 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2421.12, "word": " هات", "probability": 0.3155517578125}, {"start": 2421.12, "end": 2421.64, "word": " بتتدربوا", "probability": 0.861865234375}, {"start": 2421.64, "end": 2422.04, "word": " عليها", "probability": 0.985595703125}, {"start": 2422.04, "end": 2422.84, "word": " بنشوف", "probability": 0.9505208333333334}, {"start": 2422.84, "end": 2423.12, "word": " كيف", "probability": 0.96435546875}, {"start": 2423.12, "end": 2423.24, "word": " ال", "probability": 0.95751953125}, {"start": 2423.24, "end": 2423.48, "word": " ring", "probability": 0.8955078125}, {"start": 2423.48, "end": 2423.98, "word": " opening", "probability": 0.84375}, {"start": 2423.98, "end": 2424.68, "word": " بيصير", "probability": 0.964599609375}, {"start": 2424.68, "end": 2425.9, "word": " باكثر", "probability": 0.825927734375}, {"start": 2425.9, "end": 2426.1, "word": " من", "probability": 0.99169921875}, {"start": 2426.1, "end": 2426.6, "word": " مثل", "probability": 0.7705078125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2427.7855, "duration_after_vad": 2323.9356249999914}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.srt b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8f1fe0fce9342c67c52a03da635410dcc4b62926
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/xernIeM-sgU_raw.srt
@@ -0,0 +1,1848 @@
+1
+00:00:20,990 --> 00:00:24,950
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:24,950 --> 00:00:29,290
+تفاعلات ال alkenes وقلنا اللى بينظر للموضوع نظرة
+
+3
+00:00:29,290 --> 00:00:34,610
+كلية الموضوع بسيط الموضوع انه double bond هيوم
+
+4
+00:00:34,610 --> 00:00:40,230
+رابطتين بالاضافة بتصير single bond هذه العملية شو
+
+5
+00:00:40,230 --> 00:00:46,110
+بنسميها عملية addition عملية addition واتفقنا ان
+
+6
+00:00:46,110 --> 00:00:48,810
+في ال addition فى عندنا مكونات لل addition فى
+
+7
+00:00:48,810 --> 00:00:52,730
+عندنا ال alkeneو في عندنا ال reagent وهذا ممكن
+
+8
+00:00:52,730 --> 00:00:56,610
+يكون symmetric و لا unsymmetric وهذا نفس الشيء و
+
+9
+00:00:56,610 --> 00:00:59,610
+دائما قلنا بدنا ننتبه لو كان في عندنا
+
+10
+00:00:59,610 --> 00:01:03,550
+unsymmetrical alkene مع unsymmetrical reagent
+
+11
+00:01:03,550 --> 00:01:09,070
+بنتوقع انه بيكون عندنا two products الآن هنبدأ
+
+12
+00:01:09,070 --> 00:01:13,510
+ناخد أمثلة على هذا الموضوع تحديدا لو بدنا نتكلم
+
+13
+00:01:13,510 --> 00:01:18,580
+على إضافة الماءإضافة الماء، الماء بيضيف جزء إيه؟
+
+14
+00:01:18,580 --> 00:01:25,940
+بيضيف H و O H هذه العملية بنسميها hydration لاحظوا
+
+15
+00:01:25,940 --> 00:01:30,780
+أنه عمليات الإضافة حسب ال reagent يعني المرة
+
+16
+00:01:30,780 --> 00:01:35,840
+الماضية إحنا لما إضفنا ال hydrogen عملية إضافة ال
+
+17
+00:01:35,840 --> 00:01:42,940
+hydrogen hydrogenation اسمها واضح؟عملية إضافة
+
+18
+00:01:42,940 --> 00:01:49,120
+الهيدروجين الان ممكن نضيف الهالوجين بشكل عام
+
+19
+00:01:49,120 --> 00:01:57,020
+بنسميها الهالوجيناشن طبعا بشكل خاص إكلوريناشن
+
+20
+00:01:57,020 --> 00:02:05,100
+بروميناشن و هكذا ممكن نضيف الميه بنسميها هيدريشن
+
+21
+00:02:05,100 --> 00:02:14,210
+إضافة الميهHydration واضح؟ ممكن نضيف HX خلّينا
+
+22
+00:02:14,210 --> 00:02:22,530
+نقول HBR و لا HCL على الطرفين الرابطة HX بنسميها
+
+23
+00:02:22,530 --> 00:02:27,530
+Hydro لأن فيها Hydrogen Hydro وHalogen
+
+24
+00:02:27,530 --> 00:02:34,730
+Halogenation Hydro Halogenation كل هذه العمليات هي
+
+25
+00:02:34,730 --> 00:02:40,670
+عمليات إيش؟إضافة إذا إليها أسماء hydrogenation,
+
+26
+00:02:40,750 --> 00:02:44,430
+halogenation, hydration, hydrohalogenation
+
+27
+00:02:44,430 --> 00:02:49,010
+ابتفاعلات تانية هنتعلمها بعدين و هتلاحظوا إنه في
+
+28
+00:02:49,010 --> 00:02:53,430
+الكيميا العضوية دائما عندكم الشغلات المتعاكسة
+
+29
+00:02:53,430 --> 00:02:57,770
+بمعنىان ال double bond لما اضيف عليها reagent
+
+30
+00:02:57,770 --> 00:03:01,370
+بتصير single bond يعني لو افترضنا ان هاي double
+
+31
+00:03:01,370 --> 00:03:06,030
+bond اضفت عليها reagent الناتج single bond الان لو
+
+32
+00:03:06,030 --> 00:03:11,470
+هذه ال single bond ابتفاعل تاني رفعت منها شغلتين
+
+33
+00:03:11,470 --> 00:03:16,510
+هتصير double bond اذا انا ممكن اعمل اضافة و ممكن
+
+34
+00:03:16,510 --> 00:03:22,760
+اعمل حذفواضح ال elimination بسميه فزي ما في عند ا
+
+35
+00:03:22,760 --> 00:03:28,840
+addition في عند كمان عكسه elimination هذه عمليات
+
+36
+00:03:28,840 --> 00:03:34,860
+ال elimination أيضا لها أسماء بمعنى لو كنا بنحذف
+
+37
+00:03:34,860 --> 00:03:39,240
+ذرتين هيدروجين و بنعمل double bond تاني هنسمي
+
+38
+00:03:39,240 --> 00:03:44,880
+العملية dehydrogenation هستخدم ل prefix دي هذا
+
+39
+00:03:44,880 --> 00:03:51,360
+للنفيD فحقول dehydrogenation لو كنت برفع زرتين
+
+40
+00:03:51,360 --> 00:03:58,300
+كلور او بروم Dehydrogenation لو كنت برفع HOH
+
+41
+00:03:58,300 --> 00:04:03,900
+Dehydration هذه الكلمة الشهيرة نزع الماء
+
+42
+00:04:03,900 --> 00:04:07,520
+Dehydration
+
+43
+00:04:08,520 --> 00:04:12,700
+لو كنا بنرفع ال .. ال hydrogen وال halogen
+
+44
+00:04:12,700 --> 00:04:17,120
+dehydrohalogenation واضح؟ dehydrohalogenation
+
+45
+00:04:17,120 --> 00:04:21,640
+ولذلك بتلاقوا هذه الكلمة انتبهولها جيدا واحفظوها
+
+46
+00:04:21,640 --> 00:04:26,460
+انتوا في المستقبل بتصيروا أمهات dehydration لما
+
+47
+00:04:26,460 --> 00:04:30,620
+الأطفال الصغار بيمرضوا بتروح فيهم على المستشفيات
+
+48
+00:04:30,620 --> 00:04:35,630
+بيكون ..عندهم جفاف فالطبيب ايش بيقول عنه عنده
+
+49
+00:04:35,630 --> 00:04:40,070
+dehydration يعني فقد الماء اللي عنده صار عنده جفاف
+
+50
+00:04:40,070 --> 00:04:44,350
+فبيسموها بالانجليزي ايش الجفاف dehydration يعني
+
+51
+00:04:44,350 --> 00:04:48,370
+ايه تسمعوا عن الطفل عنده dehydration لازم تعطوه
+
+52
+00:04:48,370 --> 00:04:53,830
+ايش محليل الان اول شئ بدنا نبدأ فيه ال hydration
+
+53
+00:04:53,830 --> 00:04:57,750
+اضافة الماء الان اضافة الماء على طرفين الرابط
+
+54
+00:04:57,750 --> 00:05:05,860
+الزوجية شو هيحط عندهH و OH واضح القصة طبعا في كل
+
+55
+00:05:05,860 --> 00:05:09,920
+شيء في تفاصيل كثيرة لكن احنا احيانا بنتجوزها في ال
+
+56
+00:05:09,920 --> 00:05:12,880
+course العام يعني كيف بنضافه مش مشكلة المهم ان ال
+
+57
+00:05:12,880 --> 00:05:17,600
+double bond راحت ال bi bond ألغيت صارت two new
+
+58
+00:05:17,600 --> 00:05:24,160
+sigma bonds واحدة H واحدة OH هذا التفاعل بشكل عام
+
+59
+00:05:24,160 --> 00:05:31,000
+الان لو اتيت للتفاعل بحالة خاصةأتطلعت على هذا الـ
+
+60
+00:05:31,000 --> 00:05:35,620
+Alkene اللي هو الـ Isobutyl الان لو اتطلعت على هذا
+
+61
+00:05:35,620 --> 00:05:40,380
+ال Isobutyl هتلاحظوا انه Unsymmetrical الكين بمعنى
+
+62
+00:05:40,380 --> 00:05:43,860
+لو اتيت في نص ال bubble bond اتخيلت اني بدأ اجسم
+
+63
+00:05:43,860 --> 00:05:50,680
+نصين هلعنى C ايش بتحمل؟H و H مختصرات وهنا C بتحمل
+
+64
+00:05:50,680 --> 00:05:57,620
+CH3 و CH3 طيب لما أنا بدي أضيف الميه نتخيل الميه
+
+65
+00:05:57,620 --> 00:06:02,560
+هدول الجزئين الأزرق و الأحمر بدي أضيف الميه هل يا
+
+66
+00:06:02,560 --> 00:06:07,620
+تورا ال H نعتبرها الزرقه نعتبر ال H الزرقه و ال OH
+
+67
+00:06:07,620 --> 00:06:12,980
+الحمره هل يا تورا بدي أحط هنا ال H و هنا ال OH ولا
+
+68
+00:06:12,980 --> 00:06:15,200
+هنا ال H و هنا ال OH
+
+69
+00:06:19,900 --> 00:06:24,640
+من الناحية النظرية البحتة، من ناحية النظرية
+
+70
+00:06:24,640 --> 00:06:29,560
+البحتة، لو احنا بنقول لطفل صغير تعال شيل هادي وحق
+
+71
+00:06:29,560 --> 00:06:36,060
+التنتين، ممكن يعمل هيك و ممكن يعمل هيك، من ناحية
+
+72
+00:06:36,060 --> 00:06:41,000
+النظرية البحتة، الأمرين ممكنين، مافيش فيهم ولا
+
+73
+00:06:41,000 --> 00:06:47,280
+مشكلةالان هدولة الأمرين احنا اعطيناهم اسماء قولنا
+
+74
+00:06:47,280 --> 00:06:53,500
+اذا بنضيف الهيدروجين على الكربون اللى بتحمل
+
+75
+00:06:53,500 --> 00:06:57,520
+هيدروجين اكثر هذه الان لو فصلناها بشكل كامل هي
+
+76
+00:06:57,520 --> 00:07:03,850
+عبارة عن C بتحمل H وHتمام؟ هذه C لا تحمل اش ولا
+
+77
+00:07:03,850 --> 00:07:08,950
+اتش لو ضفنا الهيدروجين على الكاربون اللي حامل
+
+78
+00:07:08,950 --> 00:07:13,630
+هيدروجين اكثر بنقول هذه الإضافة حسب قواعد
+
+79
+00:07:13,630 --> 00:07:17,650
+Markovnikov أو حسب قاعدة Markovnikov وقتها بروح
+
+80
+00:07:17,650 --> 00:07:22,190
+بحط ال H هنا نفترض باللون الأزرق و ال O أتش هنا و
+
+81
+00:07:22,190 --> 00:07:28,710
+بطلع عندى ناتج واضح؟ ان جرب نعمل الجواب لو جربنا
+
+82
+00:07:28,710 --> 00:07:36,900
+هنحط CCH3 CH3 وهذه ستصبح single bond CH2 هذا ما
+
+83
+00:07:36,900 --> 00:07:46,540
+كان موجود أصلا كله ما جاء عليه H و OH الأن بهذا
+
+84
+00:07:46,540 --> 00:07:50,560
+الشكل الهيدروجين جاء على أي كربون على اللي حملة
+
+85
+00:07:50,560 --> 00:07:56,940
+هيدروجين أكتر وهذه الإضافة بنسميها إضافة حسب قاعدة
+
+86
+00:07:56,940 --> 00:07:58,140
+Markov-Nikov
+
+87
+00:08:05,760 --> 00:08:11,760
+ماركوف نيكوفز اديشن اضافة ماركوف نيكوفز اضافة
+
+88
+00:08:11,760 --> 00:08:12,480
+ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف
+
+89
+00:08:12,480 --> 00:08:14,080
+نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز
+
+90
+00:08:14,080 --> 00:08:14,240
+اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة
+
+91
+00:08:14,240 --> 00:08:14,300
+ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف
+
+92
+00:08:14,300 --> 00:08:15,260
+نيكوفز اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز
+
+93
+00:08:15,260 --> 00:08:19,420
+اضافة ماركوف نيكوفز اضافة ماركوف نيكوفز اضافة
+
+94
+00:08:19,420 --> 00:08:26,320
+ماركوف نيكوفز اضافCH3 CH3 وهخلّي هذه single bond
+
+95
+00:08:26,320 --> 00:08:31,380
+CH2 هاي الألكين الأصلي و أحطهم بالعكس يعني ال H
+
+96
+00:08:31,380 --> 00:08:41,120
+هنا و ال OH هنا إيش
+
+97
+00:08:41,120 --> 00:08:49,170
+المانع؟مش مانع هاي إضافة مية وهي إضافة مية هذه
+
+98
+00:08:49,170 --> 00:08:54,330
+الإضافة بنعطيها اسم بنقولها Anti-Markovnikov
+
+99
+00:08:54,330 --> 00:08:58,650
+addition إضافة عكس قاعدة Markovnikov
+
+100
+00:09:03,760 --> 00:09:07,420
+Nikov's addition إذا يمكن أن تكون الإضافة زيك
+
+101
+00:09:07,420 --> 00:09:10,380
+ويمكن أن تكون زيك هتقولوا طب وإحنا شو بده يعرفنا
+
+102
+00:09:10,380 --> 00:09:16,380
+كيف نعمل الإضافة بنقول أه حسب ال reagent المستعمل
+
+103
+00:09:16,380 --> 00:09:22,200
+الماء يمكن أن يضيف بهذا الشكل وينتج المركب اللي
+
+104
+00:09:22,200 --> 00:09:25,960
+أمامنا هنا على الجهة اليامين ويمكن أنه يضيف بالشكل
+
+105
+00:09:25,960 --> 00:09:31,500
+التاني وينتج مركب تانيممكن يعطي ناتج إضافة حسب
+
+106
+00:09:31,500 --> 00:09:35,480
+قاعدة Markovnikov وممكن يعطي عكسها هتقولولنا طب
+
+107
+00:09:35,480 --> 00:09:39,440
+وقت إيش بيعمل هيك ووقت إيش بيعمل هيك الجواب بسيط
+
+108
+00:09:39,440 --> 00:09:42,680
+لأ وإحنا بنحكي الصورة الكلية اللي تفهم من خلالها
+
+109
+00:09:42,680 --> 00:09:46,440
+إذا كانت إضافة الماء يعني هنا على السهم كتبنا
+
+110
+00:09:46,440 --> 00:09:51,980
+الماء في وجود الحامض H plus فإنه يضيف حسب قاعدة
+
+111
+00:09:51,980 --> 00:09:57,190
+Markovnikovإذا عرفنا ما الشرط الذي من خلاله تتم
+
+112
+00:09:57,190 --> 00:10:02,570
+الإضافة حسب قاعدة Markov Nikov أن نضيف الماء في
+
+113
+00:10:02,570 --> 00:10:08,950
+وجود كمية قليلة من الحامض وجدها بنضيف حسب قاعدة
+
+114
+00:10:08,950 --> 00:10:17,600
+Markov Nikovالان طب كيف بضيف عكس قاعدة Markovnikov
+
+115
+00:10:17,600 --> 00:10:21,200
+إذا
+
+116
+00:10:21,200 --> 00:10:28,020
+ضفنا الماء باستعمال reagent مختلف طبعا ظروف كاملة
+
+117
+00:10:28,020 --> 00:10:34,520
+مختلفة باستعمال مركب ال borane اللي بنقوله BH3طبعا
+
+118
+00:10:34,520 --> 00:10:39,660
+بعد هيكذا البرين بنحط عليه H2O2 هيدروجين بيروكسايد
+
+119
+00:10:39,660 --> 00:10:46,180
+لو ضفنا في وجود هذه المتفاعلات بضيف عكس قاعدة
+
+120
+00:10:46,180 --> 00:10:52,160
+ماركوف نيكوفطبعا ربما الآن بدت الصورة تتضح لكم
+
+121
+00:10:52,160 --> 00:10:56,980
+لأنه انا حاسس الصمت عندكم لأن انتوا اتعلمتوا نص
+
+122
+00:10:56,980 --> 00:11:01,180
+المعلومة بالثانوية انه الإضافة فقط حسب قاعدة
+
+123
+00:11:01,180 --> 00:11:05,560
+Markovnikov حسب قاعدة Markovnikov ضمن هذا الشرط
+
+124
+00:11:05,560 --> 00:11:11,480
+غير الشرط تحصل على إضافة عكس قاعدة Markovnikov إذا
+
+125
+00:11:11,480 --> 00:11:17,710
+الأمرين ممكنين واضح؟ اللي اتعلمتوا بالثانويةنص
+
+126
+00:11:17,710 --> 00:11:23,030
+القصة مش كل القصة، واضح؟ اللي اتعلمته بالثانوية
+
+127
+00:11:23,030 --> 00:11:29,390
+نصف هذه القصة مش كلها فقط، الآن احنا استكملنا
+
+128
+00:11:29,390 --> 00:11:32,850
+القصة لكم، اننا نقولكم لأ والله يا المية بتضيف
+
+129
+00:11:34,860 --> 00:11:39,160
+الميّه بتضيف بالطريقتين هذا الكلام بعد شوية
+
+130
+00:11:39,160 --> 00:11:43,520
+هتلاحظوه مش بسمع الميّه هذا الكلام بعد شوية
+
+131
+00:11:43,520 --> 00:11:49,200
+هتلاحظوه مش بسمع الميّه هتلاحظوه حتى مع ال HPR على
+
+132
+00:11:49,200 --> 00:11:52,920
+سبيل المثال يعني لو أخذنا نفس ال ال keen اللي كان
+
+133
+00:11:52,920 --> 00:11:56,820
+عندنا هان عارفينه ال C double bond C
+
+134
+00:11:59,940 --> 00:12:08,040
+CH3 و CH3 و قلنا بدنا نكمله باتجاهين مع الـHBr و
+
+135
+00:12:08,040 --> 00:12:13,520
+هنا كمان كتبنا HBr لو قلنا بدنا نكمل التفاعل مع
+
+136
+00:12:13,520 --> 00:12:20,460
+HBr في وجود H Plus سيضيف حسب قاعدة Markov Nikov و
+
+137
+00:12:20,460 --> 00:12:24,520
+لو قلنا بدنا نكمل التفاعل مع الـHBr في وجود
+
+138
+00:12:24,520 --> 00:12:30,160
+بيروكسايد سيضيف عكس قاعدة Markov Nikovالناتج
+
+139
+00:12:30,160 --> 00:12:33,340
+ببساطة نفس اللي موجود عندكم بدل كلمة OH اللي
+
+140
+00:12:33,340 --> 00:12:34,660
+بالأحمر شو بتحطه
+
+141
+00:12:41,060 --> 00:12:46,580
+إذا إضافة الماء أو إضافة الـ HPR يمكن أن تتم
+
+142
+00:12:46,580 --> 00:12:51,360
+بطريقة ولا بطريقتين وهنا بيصير مهم عندي جدا أن
+
+143
+00:12:51,360 --> 00:12:55,460
+أنتبه لل reactant للمتفاعل يعني لو احنا مرات بدنا
+
+144
+00:12:55,460 --> 00:12:59,840
+نسألكوا عن هذا الموضوع ممكن نجيبلكوا ال reactant
+
+145
+00:12:59,840 --> 00:13:03,100
+مع هذا نقولكوا اكتبوا النتيجة ممكن نجيب هذا ال
+
+146
+00:13:03,100 --> 00:13:06,300
+reactant و ال product و نقولكوا شو اللي استعملته
+
+147
+00:13:06,300 --> 00:13:11,620
+كمتفاعل كتبولي ال reactant اللي على السهلواضحك
+
+148
+00:13:11,620 --> 00:13:16,680
+الصورة؟ طبعا لو إجينا سألنا هذه النواتج ال
+
+149
+00:13:16,680 --> 00:13:20,100
+markovnikov product هذا بيسموه markovnikov product
+
+150
+00:13:20,100 --> 00:13:26,020
+و ال antimarkovnikov product ما العلاقة بينهما؟
+
+151
+00:13:26,020 --> 00:13:30,000
+isomers
+
+152
+00:13:30,000 --> 00:13:32,540
+أي نوع من ال isomers هذا اللي بقصدي
+
+153
+00:13:36,070 --> 00:13:40,470
+الـ Markovnikov's product والـ Antimarkovnikov's
+
+154
+00:13:40,470 --> 00:13:45,250
+product They are isomers ليش؟ لأنه نفس الذرات
+
+155
+00:13:45,250 --> 00:13:50,610
+وحطيت H و OH حطيت ال H و OH بنفس المواقع ولا
+
+156
+00:13:50,610 --> 00:13:57,670
+بمواقع مختلفة طالما مواقع مختلفة Different bonding
+
+157
+00:13:57,670 --> 00:14:04,290
+عطول الجواب Structural isomers They are structural
+
+158
+00:14:04,290 --> 00:14:09,910
+isomersمش فيها نقاش مش ارتبطوا الذرات من مواقع
+
+159
+00:14:09,910 --> 00:14:13,210
+مختلفة هنا الهيدروجين على الأولى و ال OH على
+
+160
+00:14:13,210 --> 00:14:17,470
+التانية هنا ال OH على الأولى و ال H على التانية صح
+
+161
+00:14:17,470 --> 00:14:20,570
+ولا لأ different bonding different names
+
+162
+00:14:20,570 --> 00:14:27,490
+structural isomers واضح إذا فكرة إضافة ال
+
+163
+00:14:27,490 --> 00:14:33,850
+unsymmetrical agents ممكن تضيفطريقتين ماركوف نيكوف
+
+164
+00:14:33,850 --> 00:14:37,450
+وانتي ماركوف نيكوف حسب ظروف التفاعل شو الأمثلة
+
+165
+00:14:37,450 --> 00:14:43,840
+المطلوب من ان اعرفها الماءو ال HVR بدون تفاصيل
+
+166
+00:14:43,840 --> 00:14:47,600
+الميكانيزم اللي أحيانا ممكن تلاقوها موجودة عندكم
+
+167
+00:14:47,600 --> 00:14:50,920
+يعني أنا في النهاية ال course general organic
+
+168
+00:14:50,920 --> 00:14:56,340
+course بهمني تصلوا فيه للنتيجة بشكل عام ولذلك على
+
+169
+00:14:56,340 --> 00:14:59,960
+طول الآن ممكن ناخد أمثلة إضافية و تشوفوا كيف
+
+170
+00:14:59,960 --> 00:15:04,520
+الأمثلة الإضافية بنكملها بدون ما ندخل بتفاصيل كيف
+
+171
+00:15:04,520 --> 00:15:08,260
+تمت العملية المهم عنده النتج
+
+172
+00:15:19,100 --> 00:15:22,820
+الشرط اللي بتتم فيه الإضافة عكس قاعدة Markovnikov
+
+173
+00:15:22,820 --> 00:15:27,160
+موجود في هذا ال slide لاحظوا لأنه بضيف مركب اسمه
+
+174
+00:15:27,160 --> 00:15:32,960
+BH3 ال بي بورون مش بروم انتبه بورون ال بورون لما
+
+175
+00:15:32,960 --> 00:15:36,760
+تيجي على الجدول الدوري في أوله اللي هو العنصر
+
+176
+00:15:36,760 --> 00:15:43,920
+الخامس هيدروجين هيليوم ليثيوم بيريليوم بورونBoron
+
+177
+00:15:43,920 --> 00:15:50,200
+الأنصار الخامس تمام لما يكون BH3 بنسميه borane هذا
+
+178
+00:15:50,200 --> 00:15:52,500
+بنسميه بورين
+
+179
+00:15:55,140 --> 00:16:01,340
+الان هذا ال borane في وجود solvent THF اسمه تترا
+
+180
+00:16:01,340 --> 00:16:04,640
+هيدرو فيوران solvent مش مشكلة بالنسبالي ان كل
+
+181
+00:16:04,640 --> 00:16:11,000
+تفاعل بتم في وجود مضيب بنضيف ال borane مع ال THF
+
+182
+00:16:11,000 --> 00:16:15,240
+في خطوة أولى بنحركهم لفترة معينة و بعدين على نفس
+
+183
+00:16:15,240 --> 00:16:23,390
+التفاعل بنضيف H2O2 hydrogen peroxideماء الأكسجين
+
+184
+00:16:23,390 --> 00:16:26,050
+اللي بيستعملوها بتثبيت الشعر وغيرها في basic
+
+185
+00:16:26,050 --> 00:16:32,110
+medium في وجود OH- الان انا دائما بهمني تفهمين
+
+186
+00:16:32,110 --> 00:16:36,450
+الفكرة الرئيسية يعني ماتوهوش كتير في التفاصيل
+
+187
+00:16:36,450 --> 00:16:39,530
+ولذلك لما انا بكون بدي افهم الفكرة الرئيسية لو
+
+188
+00:16:39,530 --> 00:16:43,730
+واحدة فكرت كل هدول وقعدت بتحفظهم بتوه لأ انا بهمني
+
+189
+00:16:43,730 --> 00:16:47,850
+ببساطة في الأول الفكرة الأساسية ان الماء يضيف
+
+190
+00:16:47,850 --> 00:16:52,800
+بطريقتين واضحة ولا لأيضيف Markovnikov في وجود H+,
+
+191
+00:16:52,800 --> 00:16:57,700
+واضح ولا لأ؟ وبقول ببساطة يضيف Anti-Markovnikov
+
+192
+00:16:57,700 --> 00:17:01,480
+بطريقة البرون، الآن أنا اللي بسميها طريقة البرون،
+
+193
+00:17:01,480 --> 00:17:05,660
+لأن طريقة البرون مجموعة من الأشياء موجودة في الكتب
+
+194
+00:17:05,660 --> 00:17:08,560
+وما إلى ذلك، وبنكتوب الكتابة على السهم، مابديش
+
+195
+00:17:08,560 --> 00:17:13,450
+أتقوه إن أقعد أحفظ هدولة بدون ما أكون فهمت؟الشئ
+
+196
+00:17:13,450 --> 00:17:17,570
+الرئيسي كذلك الحالة لبروم ال HPR عفوا بيضيف
+
+197
+00:17:17,570 --> 00:17:22,810
+بطريقتين في وجود H plus ماركوفنيكوف في وجود مواد
+
+198
+00:17:22,810 --> 00:17:27,350
+بيسميها البروكسايد فوق الأكسد انتي ماركوفنيكوف
+
+199
+00:17:27,350 --> 00:17:31,570
+يعني هتلاحظوا ان عندكم HPR و مكتوب لك بيروكسايد
+
+200
+00:17:31,570 --> 00:17:39,330
+اذا وجدتها التنفيذ انتي ماركوفنيكوفسابقا كان عندى
+
+201
+00:17:39,330 --> 00:17:43,290
+ناس ممتازين اللى بيحاولوا يفهموا الأمور في الأول
+
+202
+00:17:43,290 --> 00:17:46,110
+بالصورة الكلية قبل ما يخوضوا بالتفاصيل بعض منكم
+
+203
+00:17:46,110 --> 00:17:49,370
+بيتعب لإنه بيصير يخوض بالتفاصيل و الأشياء قبل ما
+
+204
+00:17:49,370 --> 00:17:53,770
+يفهم الصورة الكلية هدولة الناس الممتازين طلبت منهم
+
+205
+00:17:53,770 --> 00:17:57,570
+كان شعراء انه يلخصوا ال organ ال chemistry شعرا
+
+206
+00:17:58,290 --> 00:18:03,030
+بلغة بسيطة وهذا اللي بنصحكم يوم الامتحان تدرسوه ما
+
+207
+00:18:03,030 --> 00:18:06,610
+تقعدوش بس تكتبوا الأشياء دي و تفهموا لا افهموا
+
+208
+00:18:06,610 --> 00:18:11,170
+الأفكار الرئيسية الأفكار الرئيسية ببساطة اللي قلنا
+
+209
+00:18:11,170 --> 00:18:16,490
+ساعتين فيها تفهم بدقيقتين ال double bond تفعلها
+
+210
+00:18:16,490 --> 00:18:22,100
+الأساس إضافةالهيدروجين يضيف بشكل متماثل من جهة
+
+211
+00:18:22,100 --> 00:18:27,760
+واحدة البرومين يضيف من جهتين الأشياء زي الـH2O و
+
+212
+00:18:27,760 --> 00:18:31,900
+الـHBr ممكن تضيف مع قاعدة ماركوف نيكوف عكس قاعدة
+
+213
+00:18:31,900 --> 00:18:35,180
+ماركوف نيكوف تضيف مع قاعدة ماركوف نيكوف في وجود
+
+214
+00:18:35,180 --> 00:18:40,120
+الحامض تضيف عكس قاعدة ماركوف نيكوف الماء في وجود
+
+215
+00:18:40,120 --> 00:18:43,480
+البرون و الـHBr في وجود البروكسايد
+
+216
+00:18:45,830 --> 00:18:49,310
+هذا كل الكلام اللي احنا حكيناه ماحكيناش ولا كلمة
+
+217
+00:18:49,310 --> 00:18:53,170
+غيره بهذا الشكل بتصير ال organic عندكم سهلة و
+
+218
+00:18:53,170 --> 00:18:58,870
+ممتعة هعندي HPR طبعا ال HPR في نهاية بده يحط H و
+
+219
+00:18:58,870 --> 00:19:03,970
+PR ع دابل بوند هذه كانت CH2 صارت CH3 و انا PR هذا
+
+220
+00:19:03,970 --> 00:19:12,370
+مثال عام لكن لو اجينا على مثال متخصص زي هذا المثال
+
+221
+00:19:12,370 --> 00:19:21,590
+هذا الكربون كام هيدروجين عليهامباشر هذه واحدة
+
+222
+00:19:21,590 --> 00:19:24,070
+طلع هذه متصلة ب carbon
+
+223
+00:19:27,380 --> 00:19:33,680
+بعد انا بحكي عن الاتصال المباشر مش موراء ما بعد
+
+224
+00:19:33,680 --> 00:19:38,460
+بعد حيفا شو مالي و ماله هذا اه هنا هيدروجين تان
+
+225
+00:19:38,460 --> 00:19:42,400
+مباشر هنا هيدروجين و كرمون مين عليها هيدروجين اكثر
+
+226
+00:19:42,400 --> 00:19:48,780
+هذه بناء على ذلك لما انا بقول بدي اضيف HPR في وجود
+
+227
+00:19:48,780 --> 00:19:53,320
+H Plus وين اجت الهيدروجين؟ بهذا الشكل وين اجت ال
+
+228
+00:19:53,320 --> 00:20:02,760
+PR؟ بهذا الشكل واضح؟هي اللي بديها دلوقت بتجي
+
+229
+00:20:02,760 --> 00:20:09,060
+بالجهتين، من فوق و من تحت، قليلا بس شويه هذه
+
+230
+00:20:09,060 --> 00:20:14,000
+الفكرة متطورة اكثر من ان ابيع فيها بقى بتيجي من
+
+231
+00:20:14,000 --> 00:20:17,260
+فوق و من تحت يعنى، بس مش موضوعنا لإنه علاقة
+
+232
+00:20:17,260 --> 00:20:22,410
+بالستيل و كيميسترا، الآن هاي مركب تانيهي عندكم
+
+233
+00:20:22,410 --> 00:20:27,170
+double bond وين الطرفين ال double bond؟ هدى و هدى،
+
+234
+00:20:27,170 --> 00:20:33,570
+الآن هنا في شيء مش مرسوم ولا لأ؟ أكيد ال H الأكيد
+
+235
+00:20:33,570 --> 00:20:35,150
+ال H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال
+
+236
+00:20:35,150 --> 00:20:35,390
+H الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+237
+00:20:35,390 --> 00:20:35,870
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+238
+00:20:35,870 --> 00:20:35,890
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+239
+00:20:35,890 --> 00:20:36,110
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+240
+00:20:36,110 --> 00:20:36,610
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+241
+00:20:36,610 --> 00:20:36,610
+الأكيد ال H الأكيد ال H الأكيد ال H الأكيد ال H
+
+242
+00:20:36,610 --> 00:20:39,010
+الأكيد ال H ال أكيد ال H ال أكيد ال H ال أكيد ال H
+
+243
+00:20:39,010 --> 00:20:44,980
+ال أكيد ال H ال أكيد ال H الإذا لو أنا كنت بدى
+
+244
+00:20:44,980 --> 00:20:51,000
+أكمل HPR في وجود H Plus كيف سأكتب الناتج؟ يعني لو
+
+245
+00:20:51,000 --> 00:20:57,060
+أنه أكمل المعادلة HPR H Plus بدى أحط الهيدروجين ع
+
+246
+00:20:57,060 --> 00:21:02,360
+اللي حاملة هيدروجين أكتر يعني بدى أحطها ناسيه H3
+
+247
+00:21:02,360 --> 00:21:12,340
+وH هدولة اللي كانوا أصلا وجدت بدى أحط ال H تحتو ال
+
+248
+00:21:12,340 --> 00:21:18,800
+PR على هذا الكربون هذه إضافة ماركوفنيكوف الان لما
+
+249
+00:21:18,800 --> 00:21:24,560
+نيجي نعطيكم كملوا المعادلة HPR في وجود البروكسايد
+
+250
+00:21:24,560 --> 00:21:29,300
+بدي أحط بالعكس بدي أحط بالعكس ولذلك لو بتيجي
+
+251
+00:21:29,300 --> 00:21:33,080
+تتطلعوا هنا وين ال PR موجودة على أي كربون
+
+252
+00:21:35,850 --> 00:21:39,270
+هيها طبعا هو ورا السماء مرة لتحت و مرة لفوق هذا
+
+253
+00:21:39,270 --> 00:21:43,710
+السؤال الذكي اللي سألته زملتكوا بس بدناش نطول فيه
+
+254
+00:21:43,710 --> 00:21:46,830
+بيجعل
+
+255
+00:21:46,830 --> 00:21:51,550
+جهتين مش فيها مشكلة بس في كل الأحوال على أي carbon
+
+256
+00:21:51,550 --> 00:21:56,560
+إجت ال PRعلى حملة الهيدروجين على أي كاربون إجت
+
+257
+00:21:56,560 --> 00:22:00,840
+الهيدروجين على اللي أقل هذي Markov Nikov ولا أنت
+
+258
+00:22:00,840 --> 00:22:05,680
+Markov Nikov؟ أنا مابديش ياكلتوه في الشكل فوق و
+
+259
+00:22:05,680 --> 00:22:11,140
+تحت، حطوهم بس بالموقع الصح و غلط و مكفي، واضح؟
+
+260
+00:22:11,140 --> 00:22:15,140
+يعني لما بنكمل هذه المعادلة، ببساطة إيش يكون
+
+261
+00:22:15,140 --> 00:22:24,560
+الجواب؟ هنا ال H وهنا ال PRهك النتج بدون يصفر اكتر
+
+262
+00:22:24,560 --> 00:22:29,580
+من هيك تفصيل مابلزمنيش هذه مع ولا عكس Markovnikov
+
+263
+00:22:29,580 --> 00:22:33,700
+لما يكون هيك جوابه لغير ال double bond عكس
+
+264
+00:22:33,700 --> 00:22:38,500
+Markovnikov هنا ال H هنا ال PR مع Markovnikov
+
+265
+00:22:38,500 --> 00:22:39,200
+فاهمنا؟
+
+266
+00:22:50,600 --> 00:22:58,020
+بيجينا بعد هذه الإضافة إضافة جديدة هذه الإضافة
+
+267
+00:22:58,020 --> 00:22:59,980
+الجديدة
+
+268
+00:23:01,170 --> 00:23:07,110
+ان برضه احنا بنلغي فيها ال double bond و بنعمل two
+
+269
+00:23:07,110 --> 00:23:11,010
+new sigma bonds لكن هدول ال two new sigma bonds
+
+270
+00:23:11,010 --> 00:23:15,450
+بيكونوا على نفس ذرة ال oxygen ولذلك بيعطوني حلقة
+
+271
+00:23:15,450 --> 00:23:19,250
+ثلاثية لاحظوا هذا الكلام كيف هي عندكم carbon
+
+272
+00:23:19,250 --> 00:23:24,450
+carbon double bond صح ولا لأ الان لو فعلناها مع
+
+273
+00:23:24,450 --> 00:23:31,330
+bare acidBear بادئة معناها فوق يعني فيه ازيادة
+
+274
+00:23:31,330 --> 00:23:40,170
+الحامض العضوي كام أكسوجين فيه عادة ال acid؟ تنتيل
+
+275
+00:23:40,170 --> 00:23:44,570
+تلت روابط مع الأكسوجين يعني ال acid شكله العام
+
+276
+00:23:44,570 --> 00:23:55,300
+بهذا الشكل R C double bond O OH مشاكل الحامض؟RCOH
+
+277
+00:23:55,300 --> 00:23:59,640
+لو كانت هذه CH3 بيكون الاسيتك أسد لو كانت فنل
+
+278
+00:23:59,640 --> 00:24:05,260
+بيكون ال بنزويك أسد الان لو اجينا جنب ال COH
+
+279
+00:24:05,260 --> 00:24:12,400
+هتضيفنا كمان O يعني خلينا COOH زي هذا المركب اللي
+
+280
+00:24:12,400 --> 00:24:17,700
+هنا RCOOH
+
+281
+00:24:17,700 --> 00:24:24,640
+هذا زاد عندى بإيش؟بأكسوجينة صار فيه تلت أكسوجينات
+
+282
+00:24:24,640 --> 00:24:28,640
+هذا كام أكسوجينة في تنتين الآن هذا المركب اللي
+
+283
+00:24:28,640 --> 00:24:34,920
+صيرته العامة R C double bond O O O H بنسميه pear
+
+284
+00:24:34,920 --> 00:24:41,230
+acid فوق حامضيعني زاد فيه ال oxygen بمقدار ضرر
+
+285
+00:24:41,230 --> 00:24:46,310
+يعرفنا إيش معنى pear acid و لما نسميه بنسميه على
+
+286
+00:24:46,310 --> 00:24:49,570
+اسم الحامض الأصلي اللي كان موجود يعني لو افترضنا
+
+287
+00:24:49,570 --> 00:24:54,810
+الحامض الأصلي acidic acidبصير اللي فيه أكسجينة
+
+288
+00:24:54,810 --> 00:25:01,350
+زيادة بير أسيتك أسد، بنزويك أسد، بير بنزويك أسد،
+
+289
+00:25:01,350 --> 00:25:06,930
+يعني نفس الحامض تماما بس بنزيد عليه إيش؟ بير، يمكن
+
+290
+00:25:06,930 --> 00:25:12,590
+مرت عليكم لما أخدتوا أحماض الكلور مع الأكسجين لما
+
+291
+00:25:12,590 --> 00:25:18,510
+أخدتوا ال بيريكلوريك أسدمش كان عندكوا ClO3 لكلوريك
+
+292
+00:25:18,510 --> 00:25:25,530
+أسد لما صار ClO4 زاد أكسوجينة بيريكلوريك أسد واضح
+
+293
+00:25:25,530 --> 00:25:31,230
+فبير هنا بمعنى إيش الزيادة لو فعلنا الالكين مع
+
+294
+00:25:31,230 --> 00:25:36,480
+البر أسدمرة تانية بتنكسر ال double bond و بتعمل
+
+295
+00:25:36,480 --> 00:25:40,900
+رابطتين sigma لكن مع نفس ذرة ال oxygen اذا هذه
+
+296
+00:25:40,900 --> 00:25:48,220
+العملية ايضا عملية ايش اضافة تحويل ال by bond الى
+
+297
+00:25:48,220 --> 00:25:54,080
+two new sigma bonds اضافة ولا مش اضافة اضافة لكن
+
+298
+00:25:54,080 --> 00:25:56,880
+الان ال two new sigma bonds على نفس ال oxygen
+
+299
+00:25:56,880 --> 00:26:04,040
+فالناتج حلقة ثلاثيةالناتج حلقة ثلاثية هذه الحلقة
+
+300
+00:26:04,040 --> 00:26:10,460
+الثلاثية من ذرتين كربون و من أكسوجينة حلقة ثلاثية
+
+301
+00:26:10,460 --> 00:26:14,560
+ذرتين كربون و أكسوجينة هذه الثلاث ذرات تعونها الآن
+
+302
+00:26:14,560 --> 00:26:21,140
+هذه الحلقة الثلاثية كعائلة بيسموها ابوكسايد يعني
+
+303
+00:26:21,140 --> 00:26:25,380
+لو قلتلكم ما هي عائلة الابوكسايد لاحظوا family في
+
+304
+00:26:25,380 --> 00:26:29,660
+عندنا family و في عندنا في جوا ال family ايش أفراد
+
+305
+00:26:30,500 --> 00:26:33,720
+هك بتكون تفهموا الكيميا ان في العائلة العامة زي ال
+
+306
+00:26:33,720 --> 00:26:40,800
+ketones ال ketone family عائلة الآن جواتها acetone
+
+307
+00:26:40,800 --> 00:26:46,740
+وcyclohexanone وكذا وكذا ال alkenes عائلة جواتها
+
+308
+00:26:46,740 --> 00:26:53,910
+methane إيثين بروبين الآن ال epoxidesعائلة أيضا مش
+
+309
+00:26:53,910 --> 00:26:59,130
+اسم مركّب الابوكسايد عائلة الان طب ايش في جوات هذه
+
+310
+00:26:59,130 --> 00:27:05,730
+العائلة مركّبات؟ carbon تانو اكسوجينة وين بدو يصير
+
+311
+00:27:05,730 --> 00:27:10,630
+الخلاف؟ بدو يصير الخلاف في هدول المجموعات هل هدول
+
+312
+00:27:10,630 --> 00:27:14,130
+الأربعة هيدروجينز؟ هل واحدة فيهم مثل؟ هل تنتين
+
+313
+00:27:14,130 --> 00:27:16,910
+مثل؟ هل التلاتة مثل؟ هل الأربعة مثل؟ هل واحدة إثل؟
+
+314
+00:27:16,910 --> 00:27:23,540
+هل واحدة بروبل؟وجدتها بيصير لكل مركب اسم طب كيف
+
+315
+00:27:23,540 --> 00:27:28,760
+بنسمي كل مركب؟ العملية سهلة بنيجي بنسأل نفسنا إيش
+
+316
+00:27:28,760 --> 00:27:36,160
+اسم الألكين الأصلي تبعه اللي كونه؟والناتج لما
+
+317
+00:27:36,160 --> 00:27:39,900
+نعمله بنسميه باسم الالكين بنضيف عليه oxide يعني
+
+318
+00:27:39,900 --> 00:27:46,200
+مثلا لو كان الالكين اللي عندكم CH2 double bond CH2
+
+319
+00:27:46,200 --> 00:27:53,580
+هين حددنا مركب محدد هذا إيش اسمه اثيلين او اثيل
+
+320
+00:27:53,580 --> 00:27:59,300
+اثيلين الآن فعلنا مع ال bare acid هذا اللي موجود
+
+321
+00:27:59,300 --> 00:28:05,840
+عندناهتلتغي هذه الـ bi-bond وتعطيني أكسوجينة صار
+
+322
+00:28:05,840 --> 00:28:11,480
+عندى CH2 خلّيني نخلي الهيدروجين يخلع برا مرسومين
+
+323
+00:28:11,480 --> 00:28:14,620
+CH2
+
+324
+00:28:14,620 --> 00:28:23,280
+CH2 و هنا أكسوجين الآن هذا من أي مركب نتاج من
+
+325
+00:28:23,280 --> 00:28:30,910
+الإثالين شو بدي أسميه إثالين أكسيد نسبة للأصلإذا
+
+326
+00:28:30,910 --> 00:28:35,970
+تسمية هذه المراكبات تسمية هذه المراكبات كل فرد
+
+327
+00:28:35,970 --> 00:28:42,350
+منها كيف بسميه باسم القلقين الأصلي مضاف إليه كلمة
+
+328
+00:28:42,350 --> 00:28:49,350
+أكسايد أثالين أكسايد واضحة الفكرة ولا لأ ماشي
+
+329
+00:28:49,350 --> 00:28:53,410
+أتأكد أنها واضحة ولا لأ الآن لو اني جيبت هذا
+
+330
+00:28:53,410 --> 00:28:58,310
+المراكب في الامتحان وقلتلك لو سمحته سمولي هذا
+
+331
+00:28:58,310 --> 00:29:04,760
+المراكبزي هيك هذا جايكوا في الامتحان و أنا قلتلكوا
+
+332
+00:29:04,760 --> 00:29:11,860
+صموه واحدة
+
+333
+00:29:11,860 --> 00:29:15,960
+بس Cyclohexane
+
+334
+00:29:15,960 --> 00:29:22,210
+Oxide بتكون تقولوا هذا إيش كان أصلاهي اللي شيلت
+
+335
+00:29:22,210 --> 00:29:26,990
+هذه .. هذا أصلا كان هيك لما ضيفت عليه شيلت ال
+
+336
+00:29:26,990 --> 00:29:30,910
+double bond و حطيت ال oxygen طب زي هيك إيش اسمه؟
+
+337
+00:29:30,910 --> 00:29:41,120
+Cyclohexane شيلنا هذه صار Cyclohexane oxideواضح؟
+
+338
+00:29:41,120 --> 00:29:48,940
+إذا هذه المركبات كأفراد تسمى باسم القلقين الأصلي
+
+339
+00:29:48,940 --> 00:29:55,160
+باسم القلقين الأصلي مضاف إلى كلمة Oxide واضحة ولا
+
+340
+00:29:55,160 --> 00:30:04,340
+ما واضحت؟ واضحة تماما، الآن إلها تسمية تانية كتير
+
+341
+00:30:04,340 --> 00:30:10,260
+في ناس بياخدوا أكتر من اسم، إلها تسمية تانيةأبسط
+
+342
+00:30:10,260 --> 00:30:15,340
+مُركّب في هذه العائلة كلها أي واحد الـ ethylene
+
+343
+00:30:15,340 --> 00:30:22,620
+oxide ليش؟ لأنه هنا O CH H H H H هذا المُركّب
+
+344
+00:30:22,620 --> 00:30:27,980
+الأبسط فيهم هذا المُركّب الأبسط ماخد اسم اسمه
+
+345
+00:30:27,980 --> 00:30:37,990
+Oxirane Oxirane تمام؟Oxirane بنحفظه ايه كويس الان
+
+346
+00:30:37,990 --> 00:30:43,270
+هذا ال Oxirane بنتخيله تلت مواقع بنبدأ ترقيمه من
+
+347
+00:30:43,270 --> 00:30:50,170
+ال Oxygen بنقول واحد اتنين تلاتةبنسميه ال parent
+
+348
+00:30:50,170 --> 00:30:55,410
+compound عمرنا قولنا كلمة parent المركب الأبسط
+
+349
+00:30:55,410 --> 00:30:59,310
+دائما بنقول عنه ال parent compound الآن هذا ال
+
+350
+00:30:59,310 --> 00:31:02,610
+parent compound لو يا ترى شيلنا من هدول ال
+
+351
+00:31:02,610 --> 00:31:10,870
+hydrogen ال hydrogen واحدة وحطينا بدلها CH3 واحدة
+
+352
+00:31:10,870 --> 00:31:12,610
+تقولي ايش بدها تسمي وجتها
+
+353
+00:31:15,250 --> 00:31:20,130
+أوكز إيرين المركب الأصلي على موقع اتنين إيش إجاله
+
+354
+00:31:20,130 --> 00:31:30,210
+مثل إذا هذا بيصير two مثل أوكز إيرين أنا اعتبرت ال
+
+355
+00:31:30,210 --> 00:31:34,990
+أوكز إيرين اللي فيه أربعة هيدروجين شلت منه واحدة
+
+356
+00:31:34,990 --> 00:31:39,630
+محل ما شلت بكتب اسم المجموعة لو كان كلور two chlor
+
+357
+00:31:39,630 --> 00:31:44,780
+أوكز إيرين لو كانت إثلتوقث ال Oxirane تعرفنا كيف
+
+358
+00:31:44,780 --> 00:31:49,800
+هذا سمنها؟ الآن هي تسمية هذا المركب اللي أمامكم
+
+359
+00:31:49,800 --> 00:31:54,360
+بطريقة ال Oxirane طب لو واحدة بدأت تسميه بطريقة ال
+
+360
+00:31:54,360 --> 00:32:02,200
+Alkyl Oxide، شو هتسميه؟ بروبين أكسيد، بروبين
+
+361
+00:32:02,200 --> 00:32:04,780
+أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد،
+
+362
+00:32:04,780 --> 00:32:05,560
+بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين
+
+363
+00:32:05,560 --> 00:32:06,080
+أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين أكسيد،
+
+364
+00:32:06,080 --> 00:32:08,440
+بروبين أكسيد، بروبين أكسيد، بروبين أكسيد، بروبين
+
+365
+00:32:08,440 --> 00:32:16,320
+أكسيد، بروبين أكسما هذا الالكين؟ واحد CH2 double
+
+366
+00:32:16,320 --> 00:32:22,300
+bond CH CH3 هذا الابروبيل و لذلك بيصير ابروبيل
+
+367
+00:32:22,300 --> 00:32:27,900
+أكسيد فلو جيبنالكم مثلا سؤال ابروبيل أكسيد is also
+
+368
+00:32:27,900 --> 00:32:32,780
+called وقتها بتقولوا 2-methyl oxirane 2-methyl
+
+369
+00:32:32,780 --> 00:32:38,900
+oxirane is also calledPropyl Oxide طبعا ال Oxirans
+
+370
+00:32:38,900 --> 00:32:42,760
+هذه في الكيميا الحلقية غير المتجانسة بنستعملها
+
+371
+00:32:42,760 --> 00:32:46,480
+أكتر في الكيميا العادية المشهورة أكتر يكون تسموها
+
+372
+00:32:46,480 --> 00:32:54,720
+نسبة للالكيم و تحطو إيش Oxide الإسمين بتلاقوهم إذا
+
+373
+00:32:54,720 --> 00:33:01,620
+شفنا هذه المراكبات كيف بنحضرها و كيفبنسميها كيف
+
+374
+00:33:01,620 --> 00:33:05,560
+بنحضرها و كيف بنسميها عساريا مينندسيا هل هذه
+
+375
+00:33:05,560 --> 00:33:08,800
+التسمية بتسميها ايوباك ولا ايوباك؟ لأ لأ هي
+
+376
+00:33:08,800 --> 00:33:14,240
+التسمية اللي هي ال auxirene نظام تسمي بسموه Hans
+
+377
+00:33:14,240 --> 00:33:18,550
+Wiedemann system of nomenclatureيستعمل عن طلاب
+
+378
+00:33:18,550 --> 00:33:23,570
+الكيميا للـ heterocyclic compounds واضح؟ hence
+
+379
+00:33:23,570 --> 00:33:26,570
+Vedman system of nomenclature الآن خلينا ناخد
+
+380
+00:33:26,570 --> 00:33:32,050
+أمثلة انسهل الموضوع هي كذا مثال جيبنا أكمل مع pear
+
+381
+00:33:32,050 --> 00:33:36,950
+acid شو عرفني pear acid؟ تلت أكسوجينات في كل
+
+382
+00:33:36,950 --> 00:33:42,370
+الأحوال شو اللي بدى أعمله؟ أشيل ال double bond؟أحط
+
+383
+00:33:42,370 --> 00:33:48,510
+مكانها أكسجين أشيل ال double bond أحط أكسجين أشيل
+
+384
+00:33:48,510 --> 00:33:52,630
+ال double bond أحط أكسجين إذا الأمر سهل و بسيط ولا
+
+385
+00:33:52,630 --> 00:33:57,110
+لأ الالكيل مع ال bear acid أشيل ال double bond أحط
+
+386
+00:33:57,110 --> 00:34:02,350
+أكسجين في حلقة ثلاثية كل هذه لو إجا شخص من برة و
+
+387
+00:34:02,350 --> 00:34:07,070
+يتطلع على السبورة ويقول له شو هذه المركبات؟ شو بدي
+
+388
+00:34:07,070 --> 00:34:14,200
+يجاوبنا؟Epoxides مش العائلة ابوكسايدز فلو يوم من
+
+389
+00:34:14,200 --> 00:34:19,140
+الأيام جريتوا مثلا عائلة الابوكسايدز افبالكم بلغة
+
+390
+00:34:19,140 --> 00:34:24,740
+بسيطة الحلقات الثلاثية التي تحتوي على ذرة أكسجين
+
+391
+00:34:24,740 --> 00:34:32,280
+واحدة هي عائلة الابوكسايدز واضحة؟ الآن بنلاحظ شغلة
+
+392
+00:34:32,280 --> 00:34:36,790
+في عائلة الابوكسايدزهذه الحلقة الثلاثية حتى لو
+
+393
+00:34:36,790 --> 00:34:41,950
+عملناها باستعمال ال model هنلاحظ فيها شغل يعني لو
+
+394
+00:34:41,950 --> 00:34:47,310
+جيبنا ذرة الأكسجين هذه اللي لونها أزرق شوية مش هي
+
+395
+00:34:47,310 --> 00:34:52,470
+زرق الأكسجين وجيبنا ذرتين carbon وجربنا نعمل
+
+396
+00:34:52,470 --> 00:34:58,350
+الحلقة الثلاثية باستعمال
+
+397
+00:34:59,200 --> 00:35:04,140
+الـ Models هتلاحظوا فيها ملاحظة اتطلعوا معاه قبل
+
+398
+00:35:04,140 --> 00:35:09,600
+ما اتسكر الحلقة شوفوا كيف مترايحة الروابط فيها و
+
+399
+00:35:09,600 --> 00:35:13,960
+انا بسكر ايش قاعد بعمل؟ بضغط .. بضغط .. بضغط ..
+
+400
+00:35:13,960 --> 00:35:18,720
+بضغط .. الآن غصب عن هذه ال carbon قاعد بعمل فيها
+
+401
+00:35:18,720 --> 00:35:24,240
+زاوية لو تتخيلوا جداش مقدارها؟ ستين .. ستين ..
+
+402
+00:35:24,240 --> 00:35:28,880
+ستين .. ستين .. مية و تمانينزوايا المثلث 180 طب
+
+403
+00:35:28,880 --> 00:35:32,420
+الزاوية المترايحة خليني أفلتها شوية أسيب ال carbon
+
+404
+00:35:32,420 --> 00:35:36,320
+تترايح جداش زاوية ال carbon هذه المترايحة لها مش
+
+405
+00:35:36,320 --> 00:35:43,020
+90 انسيتوا ال tetrahedral 109.5 هذه الزاوية 109.5
+
+406
+00:35:43,020 --> 00:35:49,440
+مش هدول بكملهم اتش اتش بيكونوا .. 109.5 الزاوية
+
+407
+00:35:49,440 --> 00:35:55,990
+المترايحةهذه الـ CH2 وهذه بتكون زيها كمان CH2،
+
+408
+00:35:55,990 --> 00:36:01,750
+واضح؟ فالزاوية المتريحة 109.5، الآن أنا عشان أعمل
+
+409
+00:36:01,750 --> 00:36:05,330
+الحلقة الثلاثية، انزلت فيها لا جداش، انزلت فيها لا
+
+410
+00:36:05,330 --> 00:36:10,550
+ستين، إذا هذا ضغط شديد على الحلقة ولا لأ؟ بسميه
+
+411
+00:36:10,550 --> 00:36:14,650
+strain زي الزنبارك لما بتعصوه، strain بتصير
+
+412
+00:36:14,650 --> 00:36:20,890
+الحلقة، هذه الحلقة الـstrain لو بدت تعمل تفاعلوحد
+
+413
+00:36:20,890 --> 00:36:26,070
+مضغوط ايش التفاعل اللي بده يعمله؟
+
+414
+00:36:26,070 --> 00:36:33,450
+Ring Opening لأنها Strained لما قادش أفعلها مع
+
+415
+00:36:33,450 --> 00:36:37,190
+أشياء التفاعل اللي بتعمله Ring Opening بتحب تفتح
+
+416
+00:36:37,190 --> 00:36:41,890
+بتحب مش يظلها مسكرة فبدنا نفهم احنا ان الحلقة
+
+417
+00:36:41,890 --> 00:36:46,290
+الثلاثية هذه Strained ايش يعني Strained؟ مضغوطة
+
+418
+00:36:46,290 --> 00:36:49,030
+بتحب تعمل Ring
+
+419
+00:36:51,710 --> 00:36:56,190
+Ring Opening بتفتح، بتريح الزوايا تبعتها زي أي بني
+
+420
+00:36:56,190 --> 00:37:01,090
+آدم مضغوط برتاح للزوايا الطبيعية، الزوايا الطبيعية
+
+421
+00:37:01,090 --> 00:37:08,120
+109.5، هي الآن هنا موجودة في جداشالان بيصير السؤال
+
+422
+00:37:08,120 --> 00:37:11,980
+يا تورا ايش الشيء اللى بده يعمل ال herring opening
+
+423
+00:37:11,980 --> 00:37:16,580
+و يتفاعل معها؟ لو اطلعتوا انتوا هنا، هاي الحلقة،
+
+424
+00:37:16,580 --> 00:37:22,800
+هذا أكسوجين سلبيته عالية، هذه كربون سلبيتها أقل،
+
+425
+00:37:22,800 --> 00:37:26,540
+اذا كأنه هذا الأكسوجين سالب و الكربون و الكربون
+
+426
+00:37:26,540 --> 00:37:31,880
+هذه ايش مالهم؟ موجباتهذه نقطة كتير مهمة اذا انا
+
+427
+00:37:31,880 --> 00:37:37,560
+بقدر اتخيل الان هذه ان هذه سالبة و انا عندي على ال
+
+428
+00:37:37,560 --> 00:37:42,660
+carbon موجب و على ال carbon موجب بناء على ذلك لو
+
+429
+00:37:42,660 --> 00:37:48,460
+جبت من برا اش سالب يتفاعل وين هيروح يهجم على ال
+
+430
+00:37:48,460 --> 00:37:52,160
+carbon هذا الاش السالب اللي انا بجيبه و بسميه ال
+
+431
+00:37:52,160 --> 00:37:56,020
+eucleophile اكيد شيء عليه أزواج الإلكترونات هي سبب
+
+432
+00:37:56,020 --> 00:38:02,090
+السالبإيش بسميه الـ Eucleophile يمكن هالكلمة هذه
+
+433
+00:38:02,090 --> 00:38:08,910
+ما مرتش معاكم قبل هيك ال Eucleophile لو فصلنا شوية
+
+434
+00:38:08,910 --> 00:38:13,370
+بكلمة ال Eucleophile file من اللاتيني معناه محب
+
+435
+00:38:13,370 --> 00:38:20,300
+محب يحبو نيوكليو من نيوكلياس النواة معناه
+
+436
+00:38:20,300 --> 00:38:24,700
+نيوكليوفايل يحب النواة طب النواة اللي في قلبها
+
+437
+00:38:24,700 --> 00:38:29,780
+موجب ولا سالب؟ موجب إذا بتصير معناة كلمة
+
+438
+00:38:29,780 --> 00:38:36,260
+نيوكليوفايل يحب الموجب ما الذي يحب الموجب؟ السالب
+
+439
+00:38:36,260 --> 00:38:40,020
+أو اللي بيحمل أزواج إلكترونات فهمتوا؟ إذا
+
+440
+00:38:40,020 --> 00:38:46,310
+النيوكليوفايل ببساطة شيء سالبأو شيء بيحمل أزواج
+
+441
+00:38:46,310 --> 00:38:49,970
+إلكترونات لأنه سالب أو بيحمل أزواج إلكترونات فهو
+
+442
+00:38:49,970 --> 00:38:54,970
+يحب ال إيش؟ الموجب الآن هذه ال carbon موجبة تحب
+
+443
+00:38:54,970 --> 00:38:58,990
+إيش؟ سالب سالب لو بدي أعطيها اسم بنفس منطق ال
+
+444
+00:38:58,990 --> 00:39:04,350
+nucleophile إيش هقول؟ أكس آن أكس آن file file هذه
+
+445
+00:39:04,350 --> 00:39:09,790
+يحب ال electrophile ال electrophile فال
+
+446
+00:39:09,790 --> 00:39:16,470
+electrophile شيء موجبيحب السالب لأن يوكليوفي شئ
+
+447
+00:39:16,470 --> 00:39:20,350
+سالب يحب الموجب هدول شغلتين بتفاعلوا مع بعض يعني
+
+448
+00:39:20,350 --> 00:39:24,090
+كأنه ببساطة ممكن واحدة اللي مش كتير حابه
+
+449
+00:39:24,090 --> 00:39:28,050
+هالمصطلحين لأول واحدة تقول يعني موجب وسالب أه
+
+450
+00:39:28,050 --> 00:39:32,110
+ببساطة يعني موجب وسالب لكن احنا من اليوم وطالع في
+
+451
+00:39:32,110 --> 00:39:34,750
+ال organ ال chemistry الموجب ايش هنسميه؟
+
+452
+00:39:35,390 --> 00:39:40,390
+Electrophile والسالب ايش هنسميه النيوكليوفايل الان
+
+453
+00:39:40,390 --> 00:39:47,510
+هنقول انه النيوكليوفايل بيهاجم على ال Electrophile
+
+454
+00:39:47,510 --> 00:39:52,390
+بيعمل رابطة ممكن النيوكليوفايل يكون OH جاية من
+
+455
+00:39:52,390 --> 00:39:56,030
+الميه او تيجي من الميه فلما ييجي هذا ال OH
+
+456
+00:39:56,030 --> 00:40:00,470
+هنهيهاجم معقول يصيروا خمس روابط ولا هتكسر هذه
+
+457
+00:40:00,470 --> 00:40:10,140
+الرابطة تكسر وتفتح هتتحول ال O هذهالى OH الان بهذه
+
+458
+00:40:10,140 --> 00:40:13,220
+المنطقة راجعوا المرة اللى جايب ال road نبدأ من عند
+
+459
+00:40:13,220 --> 00:40:16,400
+هذه النقطة لكن بتكونوا اتدربتوا اكتر و بنشرح كل
+
+460
+00:40:16,400 --> 00:40:20,940
+الأمثلة ايش معنى Electrophile ايش معنى Nucleophile
+
+461
+00:40:20,940 --> 00:40:24,680
+هات بتتدربوا عليها بنشوف كيف ال ring opening بيصير
+
+462
+00:40:24,680 --> 00:40:26,600
+باكثر من مثل
+
diff --git a/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/z4_9i2lZ2eY_raw.json b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/z4_9i2lZ2eY_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..df46dbd5c82e689d8f267438dc1e0288ba3f7524
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwYFbBDsbzypuIGQeyRt9SbB/z4_9i2lZ2eY_raw.json
@@ -0,0 +1 @@
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بالتفصيل الممل أكيد هتقولوا أن هنا في عندي H وH و بعدها carbon هذه H وH و بعدها H فلو إجيتوا تقارنوا C وحملة كل هذا زي بعضه C وحملة", "tokens": [2407, 3224, 8315, 5954, 30767, 1829, 45030, 11242, 4032, 38149, 5551, 32887, 5016, 24976, 8848, 25720, 16712, 7649, 10632, 45164, 47525, 4117, 14407, 20666, 2655, 5172, 9381, 26895, 9673, 42213, 5551, 4117, 25708, 8032, 2655, 39648, 14407, 14739, 34105, 8978, 43242, 1829, 389, 4032, 39, 4032, 39182, 11296, 5954, 29538, 389, 4032, 39, 4032, 39182, 11296, 389, 6156, 1211, 2407, 11933, 7435, 36081, 14407, 6055, 4587, 9640, 1863, 14407, 383, 4032, 35571, 37977, 28242, 23758, 30767, 1829, 45030, 11242, 3224, 383, 4032, 35571, 37977], "avg_logprob": -0.25698528570287366, "compression_ratio": 1.6906077348066297, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 607.43, "end": 607.99, "word": "وهنا", "probability": 0.6519368489583334}, {"start": 607.99, "end": 609.27, "word": " carbon", "probability": 0.38134765625}, {"start": 609.27, 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122485, "start": 1201.08, "end": 1224.86, "text": "عملية الإضافة في حالة واحدة بتطلع ناتجين بدنا نكون منتبهين لها تماما، بعد ذلك بتطلع عندي ناتج واحد إذا ضفت Unsymmetric reagent على Unsymmetric alkene بتوقع ناتجين الآن بنرسمهم و بنوضحهم", "tokens": [25957, 1211, 10632, 33688, 11242, 31845, 3660, 8978, 11331, 6027, 3660, 36764, 24401, 3660, 39894, 9566, 1211, 3615, 8717, 9307, 7435, 9957, 47525, 8315, 8717, 30544, 3714, 29399, 3555, 3224, 9957, 5296, 11296, 46811, 10943, 995, 12399, 39182, 29910, 23275, 39894, 9566, 1211, 3615, 18871, 16254, 8717, 9307, 7435, 36764, 24401, 11933, 15730, 48812, 5172, 2655, 1156, 3187, 2174, 17475, 26949, 317, 15844, 1156, 3187, 2174, 17475, 37688, 1450, 39894, 30543, 3615, 8717, 9307, 7435, 9957, 6024, 48506, 44945, 2288, 38251, 16095, 4032, 44945, 2407, 11242, 5016, 16095], "avg_logprob": -0.2410463523328974, "compression_ratio": 1.5968586387434556, "no_speech_prob": 0.0, "words": [{"start": 1201.08, "end": 1201.8, "word": "عملية", "probability": 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new file mode 100644
index 0000000000000000000000000000000000000000..5827eff49024e752d3529c966e29488bf3cae63d
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/EEH3Y-pcsGg_raw.json
@@ -0,0 +1 @@
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و يسيرون بلا خوف إلا من الله تعالى و قد أتى هذا الزمان و أتى هذا الأمر و أمن الناس بعد انتشار الإسلام و دخول أهل اليمن في الإسلام", "tokens": [2407, 46811, 8592, 1829, 9154, 11296, 8608, 1829, 10721, 31371, 30767, 2304, 7649, 4032, 7251, 20498, 15844, 2423, 8315, 3794, 8608, 1829, 10721, 27842, 11536, 15844, 5551, 36178, 16095, 4032, 5551, 32887, 39319, 16095, 4032, 5551, 2304, 2407, 6027, 16095, 4032, 7251, 3794, 13546, 11536, 4724, 15040, 16490, 38688, 11933, 15040, 9154, 21984, 37279, 6027, 7578, 4032, 12174, 3215, 5551, 49975, 23758, 6024, 110, 2304, 7649, 4032, 5551, 49975, 23758, 16247, 29973, 4032, 5551, 27842, 2423, 8315, 3794, 39182, 16472, 2655, 8592, 9640, 33688, 3794, 37440, 4032, 11778, 9778, 12610, 5551, 3224, 1211, 45595, 27842, 8978, 33688, 3794, 37440], "avg_logprob": -0.10273437537252902, "compression_ratio": 2.010928961748634, "no_speech_prob": 0.0, "words": [{"start": 1489.98, "end": 1490.5, "word": "و", "probability": 0.52734375}, {"start": 1490.5, "end": 1490.96, 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"word": " مساجد", "probability": 0.88916015625}, {"start": 2479.84, "end": 2480.36, "word": " إيطاليا", "probability": 0.9078125}, {"start": 2480.36, "end": 2480.54, "word": " في", "probability": 0.87451171875}, {"start": 2480.54, "end": 2480.98, "word": " تحفيظ", "probability": 0.8675537109375}, {"start": 2480.98, "end": 2481.46, "word": " القرآن", "probability": 0.883544921875}, {"start": 2481.46, "end": 2482.34, "word": " وفي", "probability": 0.8125}, {"start": 2482.34, "end": 2483.02, "word": " دورات", "probability": 0.9803059895833334}, {"start": 2483.02, "end": 2483.58, "word": " أحكام", "probability": 0.940673828125}, {"start": 2483.58, "end": 2484.24, "word": " تأهيلية", "probability": 0.90322265625}, {"start": 2484.24, "end": 2484.88, "word": " وعليا", "probability": 0.8870849609375}, {"start": 2484.88, "end": 2485.54, "word": " بما", "probability": 0.881103515625}, {"start": 2485.54, "end": 2485.96, "word": " يؤكد", "probability": 0.994873046875}, {"start": 2485.96, "end": 2486.22, "word": " لنا", "probability": 0.935791015625}, {"start": 2486.22, "end": 2486.46, "word": " هذه", "probability": 0.96728515625}, {"start": 2486.46, "end": 2487.04, "word": " البشرة", "probability": 0.8971354166666666}, {"start": 2487.04, "end": 2487.7, "word": " من", "probability": 0.98583984375}, {"start": 2487.7, "end": 2488.06, "word": " رسول", "probability": 0.9928385416666666}, {"start": 2488.06, "end": 2488.28, "word": " الله", "probability": 0.92236328125}, {"start": 2488.28, "end": 2488.6, "word": " صلى", "probability": 0.837158203125}, {"start": 2488.6, "end": 2488.92, "word": " الله", "probability": 0.96044921875}, {"start": 2488.92, "end": 2489.4, "word": " عليه", "probability": 0.9296875}, {"start": 2489.4, "end": 2490.5, "word": " وسلم", "probability": 0.912353515625}, {"start": 2490.5, "end": 2490.84, "word": " هذه", "probability": 0.76318359375}, {"start": 2490.84, "end": 2491.64, "word": " بعض", "probability": 0.926513671875}, {"start": 2491.64, "end": 2492.66, "word": " المباشرات", "probability": 0.9373046875}, {"start": 2492.66, "end": 2493.52, "word": " القرأنية", "probability": 0.842041015625}, {"start": 2493.52, "end": 2494.3, "word": " والنبوية", "probability": 0.9244140625}], "temperature": 1.0}, {"id": 109, "seek": 251728, "start": 2494.9, "end": 2517.28, "text": "في الحديث عن النصر للإسلام والمستقبل للإسلام والمسلمين نسأل الله تعالى أن يتحقق ذلك قريبا وأن تقر عيوننا بهذا اليوم وبهذا النصر ويوم إذن يفرح المؤمنون بنصر الله والسلام عليكم ورحمة الله وبركاته", "tokens": [41185, 21542, 16254, 12984, 18871, 28239, 9381, 2288, 24976, 28814, 3794, 37440, 16070, 2304, 14851, 4587, 36150, 24976, 28814, 3794, 37440, 16070, 2304, 3794, 19528, 9957, 8717, 3794, 10721, 1211, 21984, 37279, 6027, 7578, 14739, 7251, 2655, 5016, 4587, 4587, 29910, 23275, 12174, 16572, 3555, 995, 4032, 33456, 6055, 4587, 2288, 6225, 1829, 11536, 8315, 39627, 15730, 45595, 20498, 46599, 3224, 15730, 28239, 9381, 2288, 4032, 1829, 20498, 11933, 8848, 1863, 7251, 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2507.28, "end": 2507.86, "word": " وبهذا", "probability": 0.8321940104166666}, {"start": 2507.86, "end": 2508.44, "word": " النصر", "probability": 0.9773763020833334}, {"start": 2508.44, "end": 2509.12, "word": " ويوم", "probability": 0.9562174479166666}, {"start": 2509.12, "end": 2509.68, "word": " إذن", "probability": 0.7277018229166666}, {"start": 2509.68, "end": 2510.44, "word": " يفرح", "probability": 0.9942626953125}, {"start": 2510.44, "end": 2511.44, "word": " المؤمنون", "probability": 0.9847412109375}, {"start": 2511.44, "end": 2512.14, "word": " بنصر", "probability": 0.9666341145833334}, {"start": 2512.14, "end": 2512.68, "word": " الله", "probability": 0.97705078125}, {"start": 2512.68, "end": 2513.74, "word": " والسلام", "probability": 0.9093424479166666}, {"start": 2513.74, "end": 2514.46, "word": " عليكم", "probability": 0.95556640625}, {"start": 2514.46, "end": 2515.18, "word": " ورحمة", "probability": 0.9913330078125}, {"start": 2515.18, "end": 2515.76, "word": " الله", 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\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/EEH3Y-pcsGg_raw.srt b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/EEH3Y-pcsGg_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..9543bcec67aaff9f1a1eba973e8753808b1c41d8
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/EEH3Y-pcsGg_raw.srt
@@ -0,0 +1,1928 @@
+1
+00:00:19,670 --> 00:00:23,090
+الحمد لله رب العالمين والصلاة والسلام على أشرف
+
+2
+00:00:23,090 --> 00:00:27,750
+الخلق وسيد المرسلين وسيدنا محمد وعلى آله وصحبه
+
+3
+00:00:27,750 --> 00:00:31,930
+أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت
+
+4
+00:00:31,930 --> 00:00:36,310
+العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما
+
+5
+00:00:36,310 --> 00:00:41,940
+علمتنا وازدنا علمة آمين رب العالمين أما بعدأجهتها
+
+6
+00:00:41,940 --> 00:00:46,300
+الأخوات الكريمات هذه آخر محاضرة معنا في الكتاب
+
+7
+00:00:46,300 --> 00:00:51,900
+المقرر ويبقى لنا محاضرة في الشيعة ملزمة خارج هذا
+
+8
+00:00:51,900 --> 00:00:57,300
+الكتاب وإن أردتم محاضرة أخيرة نهائية في المراجعة
+
+9
+00:00:57,300 --> 00:01:02,220
+فلكم الأمر ان شاء الله تعالى حضرتنا اليوم أنوانها
+
+10
+00:01:02,220 --> 00:01:09,870
+المستقبل للإسلام نتعرف من خلالها على المباشراتبنصر
+
+11
+00:01:09,870 --> 00:01:14,910
+الإسلامي وانتصار الإسلام والمسلمين وهي مباشرات
+
+12
+00:01:14,910 --> 00:01:20,930
+كثيرة وعديدة سنقتصر في الحديث عنها على المباشرات
+
+13
+00:01:20,930 --> 00:01:26,450
+القرآنية والمباشرات النبوية فقط ما دون ذلك موضوعات
+
+14
+00:01:26,450 --> 00:01:34,130
+مهمة ومفيدة ترجعون اليها للقراءة والاطلاعأول هذه
+
+15
+00:01:34,130 --> 00:01:37,750
+المباشرات يا أخوات وهي المباشرات القرآنية، آيات
+
+16
+00:01:37,750 --> 00:01:44,350
+كثيرة من القرآن الكريم فيها يبشر الله تعالى هذه
+
+17
+00:01:44,350 --> 00:01:50,320
+الأمة، أمة الإسلامالمسلمين تبشرهم بنصره سبحانه
+
+18
+00:01:50,320 --> 00:01:57,280
+وتعالى وغلبة دينه وهي في جوانب متعددة من هذه
+
+19
+00:01:57,280 --> 00:02:02,440
+الجوانب هناك مباشرات تؤكد لنا غلبة هذا الدين وهو
+
+20
+00:02:02,440 --> 00:02:08,500
+الإسلام وظهوره على ما عداه من الأديان في كل جانب
+
+21
+00:02:08,500 --> 00:02:12,700
+نلحظ مجموعة من الآيات مطلوب ان احفظ آية واحدة
+
+22
+00:02:12,700 --> 00:02:19,290
+كدليل لو جاء سؤال اذكره دليلا علىغلبت الدين وظهوره
+
+23
+00:02:19,290 --> 00:02:22,650
+على ما عداه من الأديان أنا بنحفظ آية واحدة وقد
+
+24
+00:02:22,650 --> 00:02:27,230
+يأتي السؤال بذكر الآية أو الدليل وعلى ماذا تدل من
+
+25
+00:02:27,230 --> 00:02:32,190
+المباشرات بجيبله العنوان اللي تحته هذه الآية ففي
+
+26
+00:02:32,190 --> 00:02:35,710
+المباشرات بغلبت الدين وظهوره على ما عداه من
+
+27
+00:02:35,710 --> 00:02:39,350
+الأديان مجموعة من الآيات منها من تقرأنا الآية
+
+28
+00:02:39,350 --> 00:02:43,290
+الأولى تفضل يا أخوتيقال قوله تعالى يريدون أن
+
+29
+00:02:43,290 --> 00:02:48,090
+يطفئوا نور الله بأكواههم ويقبل الله إلا أن يتم
+
+30
+00:02:48,090 --> 00:02:54,150
+نوره ويقبل الله إلا أن يتم نوره و لو كره الكافرون
+
+31
+00:02:54,150 --> 00:03:00,430
+كمل الآية هو الذي هو الذي أرسل رسوله بالهدى ودين
+
+32
+00:03:00,430 --> 00:03:04,350
+الحق ليظهره على الدين كله و لو كره المشرفين الله
+
+33
+00:03:04,350 --> 00:03:07,790
+أفتح عليك و برك الله فيك هذه الآية صريحة و واضحة
+
+34
+00:03:07,790 --> 00:03:15,180
+فيإرادة الله تعالى مقابل إرادة الكافرين الكافرين
+
+35
+00:03:15,180 --> 00:03:19,360
+يريدون أن يطفئوا نور الله يعني دين الله والإسلام
+
+36
+00:03:19,360 --> 00:03:25,560
+والقرآن بأفواههم بالتشكيك والصدع عن سبيل الله
+
+37
+00:03:25,560 --> 00:03:32,110
+وإرادة الله تعالى ويقبل الله إلا أن يتم نورهويقبى
+
+38
+00:03:32,110 --> 00:03:36,630
+الله إرادة الله تقبى أن تتحقق إرادة الكافرين وتقبى
+
+39
+00:03:36,630 --> 00:03:44,210
+إلا أن يتم الله نوره الإسلام لابد أن يتم هذا
+
+40
+00:03:44,210 --> 00:03:50,210
+الإسلام وينتشر بل وأن يظهر ليظهره على الدين كله
+
+41
+00:03:50,210 --> 00:03:54,570
+والظهور هنا بمعنى .. إيش معنى الظهور؟الغلبة
+
+42
+00:03:54,570 --> 00:03:59,670
+والانتصار ان ينتصر ويعلو هذا الدين على سائر
+
+43
+00:03:59,670 --> 00:04:05,230
+الأديان الباطلة المحرفة وهذا الوعد من الله تعالى
+
+44
+00:04:05,230 --> 00:04:09,590
+قد تحقق تحقق للنبي صلى الله عليه وسلم ومن بعده
+
+45
+00:04:09,590 --> 00:04:14,630
+لخلفائه الراشدين من بعده وانتصر الإسلام على الفرس
+
+46
+00:04:14,630 --> 00:04:20,950
+وعلى الروم وانتشر في بقاع الأرض كما وعد الله تعالى
+
+47
+00:04:20,950 --> 00:04:26,340
+وصدق الله وعدةأيضا في آية أخرى في هذا المجال و هذا
+
+48
+00:04:26,340 --> 00:04:30,240
+الجانب، مين من الأخوات؟ هتحب تقرألنا إياها؟ أخد
+
+49
+00:04:30,240 --> 00:04:34,560
+مرة من هنا و مرة من هنا؟ أه، مين الأخوات الورا؟ مش
+
+50
+00:04:34,560 --> 00:04:41,040
+عايزين؟ بلاش، هتفضل يا أختيمن الشيطان الرجيم ألم
+
+51
+00:04:41,040 --> 00:04:48,460
+ترى كيف ضرب الله مثلا كلمة طيبة كشجرة طيبة أصلها
+
+52
+00:04:48,460 --> 00:04:55,880
+ثابت وفرقها في السماء تؤتي أكلها كل حين بإذن ربها
+
+53
+00:04:55,880 --> 00:05:02,480
+ويضرب الله بالأمثال للناس لعلهم يتذكروا ومثل كلمة
+
+54
+00:05:02,480 --> 00:05:09,910
+خبيثة كشجرة خبيفة اشتفت من فرق الأرضالله أفتى عليك
+
+55
+00:05:09,910 --> 00:05:16,530
+وبرك الله فيك هذا مثل عظيم ضرباه الله تعالى للكلمة
+
+56
+00:05:16,530 --> 00:05:20,550
+الطيبة ولكلمة الخبيثة ويمثل الكلمة الطيبة من يا
+
+57
+00:05:20,550 --> 00:05:25,530
+أخواتي الدين الإسلام كلمة التوحيد لا إله إلا الله
+
+58
+00:05:25,530 --> 00:05:30,570
+مثل هذه الكلمة كشجرة طيبة أصل هذه الشجرة ثابتة في
+
+59
+00:05:30,570 --> 00:05:36,870
+الأرض مستقرةمتجذرة وفرعها منتشر في السماء فهذه
+
+60
+00:05:36,870 --> 00:05:40,710
+كلمة ثابتة مستقرة لا يمكن لأحد أن يقلعها أو
+
+61
+00:05:40,710 --> 00:05:46,510
+يزحزحها مقابل ومثل كلمة خبيثة كشجرة خبيثة اجتثت من
+
+62
+00:05:46,510 --> 00:05:51,350
+فوق الأرض ما لهااش قرار ما لها من قرار فاش إلى
+
+63
+00:05:51,350 --> 00:05:55,750
+جذور تثبتها لأنه كلمة خبيثة فأما الزبد فيذهب جفاء
+
+64
+00:05:55,750 --> 00:06:00,070
+وأما ماينفع الناس فيمكثه في الأرض هكذا إرادة الله
+
+65
+00:06:00,070 --> 00:06:05,520
+تعالى فهذا وعد الله تعالىوبشرة من الله تعالى بأن
+
+66
+00:06:05,520 --> 00:06:09,680
+ينتصر هذا الدين ويعلو هذا الدين ويظهر هذا الدين
+
+67
+00:06:09,680 --> 00:06:14,420
+على سائر الأديان الباطلة المحرفة التي حرف أهلها
+
+68
+00:06:14,420 --> 00:06:20,870
+وأصحابها جانب آخر من جوانبالمباشرات القرآنية هو
+
+69
+00:06:20,870 --> 00:06:26,890
+مباشرات وعده سبحانه وتعالى بالنصر للمسلمين
+
+70
+00:06:26,890 --> 00:06:30,850
+وبالتمكين لدينهم كما ذكرنا قبل قليل في كل جانب في
+
+71
+00:06:30,850 --> 00:06:35,770
+مجموعة من الآيات هنا عندي قعب هذه الآيات مين من
+
+72
+00:06:35,770 --> 00:06:41,050
+الأخوات تحب تقرأ لنا اتفضل قوله
+
+73
+00:06:41,050 --> 00:06:46,250
+تعالى يقاتلون
+
+74
+00:06:49,070 --> 00:07:02,670
+بأنهم ظلموا ربنا
+
+75
+00:07:02,670 --> 00:07:09,010
+الله له
+
+76
+00:07:09,010 --> 00:07:12,410
+الدمت
+
+77
+00:07:12,410 --> 00:07:16,290
+وبيعوا صلوات
+
+78
+00:07:37,750 --> 00:07:42,830
+الله يفتح عليك عليكم جميعاهذه الآية الكريمة فيها
+
+79
+00:07:42,830 --> 00:07:48,110
+موضعان في أولها وفي آخرها بوعد الله بنصر المؤمنين
+
+80
+00:07:48,110 --> 00:07:54,210
+في أولها وإن الله على نصرهم لقدير الله قادر على
+
+81
+00:07:54,210 --> 00:07:58,730
+نصر بل قدير صيغة مبالغة على نصر المؤمنينوفي
+
+82
+00:07:58,730 --> 00:08:03,510
+نهايتها وَلَيَنصُرَنَّ اللَّهُ مَن يَنصُرُهُ إِن
+
+83
+00:08:03,510 --> 00:08:08,570
+الله لقوي عزيز وعد محتوم مؤكد من الله تعالى بأن
+
+84
+00:08:08,570 --> 00:08:15,170
+ينصر من ينصره ونصر المؤمنين لله معناه نصر دينه
+
+85
+00:08:15,170 --> 00:08:21,010
+وتأيد دينه والسير على دينه فمن يؤيد دين الله ويتبع
+
+86
+00:08:21,010 --> 00:08:25,750
+دين الله ويسير على دين الله وينصر دين الله ينصره
+
+87
+00:08:25,750 --> 00:08:32,860
+الله تعالىو آيات كثيرة أيضا من تقرأنا كمان آية في
+
+88
+00:08:32,860 --> 00:08:38,640
+هذا المجال و هذا الجانب و لقد سبقت كلمتنا .. آه يا
+
+89
+00:08:38,640 --> 00:08:46,080
+أخوات تفضلي و لقد سبقت كلمتنا لعبادنا المرسلين
+
+90
+00:08:46,080 --> 00:08:53,430
+إنهم لهم المنصورون و إن جندناالله يفتح عليك، إذا
+
+91
+00:08:53,430 --> 00:08:59,790
+هم المنصرون والغالبون، النصر والغلب لمين؟ لرسل
+
+92
+00:08:59,790 --> 00:09:07,230
+الله المرسلين و لجند الله تعالى المؤمنينوهذا الوعد
+
+93
+00:09:07,230 --> 00:09:12,810
+ما دام من الله فهو وعد مؤكد محتوم لابد و أن يتحقق
+
+94
+00:09:12,810 --> 00:09:17,930
+وقد تحقق بالفعل هذا الوعد كما وعد الله تعالى في
+
+95
+00:09:17,930 --> 00:09:21,210
+آية أخرى دعوني أقرأها مادام تزهدوا في القراءة
+
+96
+00:09:21,210 --> 00:09:26,270
+قاعدين و بنطلبكم يقول الله عز وجلبعد أعوذ بالله من
+
+97
+00:09:26,270 --> 00:09:33,010
+الشيطان الرجيم وعد الله الذين آمنوا منكم وعملوا
+
+98
+00:09:33,010 --> 00:09:41,190
+الصالحات ليستخلفنهم في الأرض ليستخلفنهم في الأرض
+
+99
+00:09:41,190 --> 00:09:49,190
+كما استخلف الذين من قبلهم وليمكنن لهم دينهم
+
+100
+00:09:50,700 --> 00:09:55,020
+وَلَيُمَكِّنَنَّ لَهُم دِينَهُمُ اللَّذِي اغتضى
+
+101
+00:09:55,020 --> 00:09:58,580
+لَهُمْ وَلَيُبَدِّلَنَّهُمْ
+
+102
+00:09:58,580 --> 00:10:04,900
+مِن بَعْدِ خَوفِهِمْ أَمْنًا يَعْبُدُونَنِي لَا
+
+103
+00:10:04,900 --> 00:10:11,740
+يُشْرِكُونَ بِي شَيْءَ وَمَن كَفَرَ بَعْدَ ذَلِكَ
+
+104
+00:10:11,740 --> 00:10:17,500
+فَأُولَئِكَ هُمُ الْفَاسِقُونَ
+
+105
+00:10:18,840 --> 00:10:23,520
+صدق الله العظيم هذه الآية العظيمة من آيات الله وكل
+
+106
+00:10:23,520 --> 00:10:30,160
+آيات الله عظيمة فيها ثلاثة وعود من الله تعالى مش
+
+107
+00:10:30,160 --> 00:10:35,520
+وعد واحد تلت وعود ما هي هذه الوعود التلاتة وعد
+
+108
+00:10:35,520 --> 00:10:38,520
+الله الذين آمنوا منكم وعملوا الصالحات أولا
+
+109
+00:10:38,520 --> 00:10:43,080
+ليستخلفنهم في الأرض الاستخلاف في الأرض
+
+110
+00:10:45,800 --> 00:10:49,200
+وَلَيُمَكِّنَنَّ لَهُمْ دِينَهُمْ، أن يمكن لهم
+
+111
+00:10:49,200 --> 00:10:55,460
+دينهم يعني يقوي لهم دينهم تلاثة ويبدل خوفهم أمنا
+
+112
+00:10:55,460 --> 00:11:00,100
+يبدل هذا الخوف الذي كانوا فيه إلى أمن وقد تحقق ذلك
+
+113
+00:11:00,100 --> 00:11:03,500
+للمسلمين الأوائل في زمن النبي صلى الله عليه وسلم
+
+114
+00:11:03,500 --> 00:11:10,250
+حيث كانوا لا يأمنون على أنفسهم وكانوا يختفونبدينهم
+
+115
+00:11:10,250 --> 00:11:17,810
+سرًا يؤدون الواجبات والصلاة وغيرها سرًا وبعد
+
+116
+00:11:17,810 --> 00:11:24,050
+هجراتهم إلى المدينة وتقوية
+
+117
+00:11:24,050 --> 00:11:29,660
+جيش المسلمين الله تعالى أعطاهم القوة والمنعأصبحت
+
+118
+00:11:29,660 --> 00:11:34,460
+لهم الدولة والخلافة والسيادة وأمنوا بعد الخوف الذي
+
+119
+00:11:34,460 --> 00:11:40,320
+كانوا عليه وتمكن هذا الدين دين الإسلام فهذا الوعد
+
+120
+00:11:40,320 --> 00:11:45,500
+انتحقق للنبي صلى الله عليه وسلم و لأصحابه وأيضا في
+
+121
+00:11:45,500 --> 00:11:48,800
+عهد و زمن الخلفاء الراشدين و ذلك بالفتوحات
+
+122
+00:11:48,800 --> 00:11:55,270
+الإسلاميةجانب ثالث من الجوانب التي فيها المباشرات
+
+123
+00:11:55,270 --> 00:12:05,710
+القرآنية هو جانب عنوانه بارك
+
+124
+00:12:05,710 --> 00:12:09,630
+الله فيك إذا أخبر القرآن الكريم في كثير من آياته
+
+125
+00:12:09,630 --> 00:12:15,610
+يا أخوات بأن كيد الكافرين ماله ضعيف وفي ضلال
+
+126
+00:12:15,610 --> 00:12:20,670
+وسيفشل وسيهزم وسيتلاشى
+
+127
+00:12:21,960 --> 00:12:25,760
+في صدهم عن سبيل الله تعالى و آيات كثيرة في هذا
+
+128
+00:12:25,760 --> 00:12:31,100
+المجال و هذا الجانب منها قول الله تعالى فضلا ياخد
+
+129
+00:12:31,100 --> 00:12:46,380
+قراينا الله
+
+130
+00:12:46,380 --> 00:12:50,140
+يفتح
+
+131
+00:12:50,140 --> 00:12:51,340
+عليك و برك الله فيك
+
+132
+00:12:54,160 --> 00:13:00,320
+هذه الآية فيها بياء واضح لمصير ومقال الكفار الذين
+
+133
+00:13:00,320 --> 00:13:06,820
+ينفقون الأموال الطائلة في الصد عن سبيل الله إن
+
+134
+00:13:06,820 --> 00:13:12,480
+الذين كفروا ينفقون أموالهم وغايتهم وهدفهم ليصدوا
+
+135
+00:13:12,480 --> 00:13:17,020
+عن سبيل الله ليصدوا الناس عن طريق الله عن الدين
+
+136
+00:13:17,640 --> 00:13:22,400
+فربنا سبحانه وتعالى يقول فسينفقونها خليهم ينفقوه
+
+137
+00:13:22,400 --> 00:13:27,060
+وبعد ما ينفقوها ويخلصوا ثم تكون عليهم حصرة وندام
+
+138
+00:13:27,060 --> 00:13:30,840
+ياريتنا ما أنفقنا وخسرنا هالمخاسر ودفعنا اللي
+
+139
+00:13:30,840 --> 00:13:35,120
+دفعناه لأن كله طلع على الفاضل وما استفدنا من ورائه
+
+140
+00:13:35,120 --> 00:13:41,380
+شيء بل ثم يغلبون بعد أن كانوا يظنون أنهم سينتصرون
+
+141
+00:13:41,380 --> 00:13:46,690
+بهذه الأموال الطائلةوبهذا الإنفاق إذ بهم يفشلون
+
+142
+00:13:46,690 --> 00:13:52,350
+ويهزمون ثم في نهاية الأمر يوم القيامة إلى جهنم
+
+143
+00:13:52,350 --> 00:13:57,090
+يحشرون والعياذ بالله أيضا من الآيات اللي كنا
+
+144
+00:13:57,090 --> 00:13:59,730
+بنحفظها في الجزء الأخير من القرآن في الجزء العام
+
+145
+00:13:59,730 --> 00:14:08,090
+قوله تعالى بارك
+
+146
+00:14:08,090 --> 00:14:13,090
+الله فيك الله افتح عليك هذا الكيد يقابله كيد أعظم
+
+147
+00:14:13,990 --> 00:14:18,690
+بل ولا يقارن كيد الكفار الذين يكيدون للمؤمنين
+
+148
+00:14:18,690 --> 00:14:23,850
+ويدبرون للمؤمنين ويخططون للمؤمنين والمسلمين يقابله
+
+149
+00:14:23,850 --> 00:14:28,450
+كيد الله سبحانه وتعالى وشتان بين هذا الكيد وهذا
+
+150
+00:14:28,450 --> 00:14:33,010
+الكيد هذا في البلاغة فقط يسمى باب المشاكلة يعني
+
+151
+00:14:33,010 --> 00:14:39,820
+لفظ شكل اللفظ نفس الشكل يكيدونوأكيده يمكرون ويمكر
+
+152
+00:14:39,820 --> 00:14:45,040
+الله فهذا المكر وهذا الكيد ليس كما مكر وكيد البشر
+
+153
+00:14:45,040 --> 00:14:50,220
+فمكر الله وكيد الله هو مكر وكيد خير لكن مكرهم
+
+154
+00:14:50,220 --> 00:14:55,940
+وكيدهم مكر سوء وشر وخبث ولؤم وكذا فالله تعالى
+
+155
+00:14:56,630 --> 00:15:00,910
+يشاكلهم في اللفظ لكن في الحقيقة شتان ما بين مكر
+
+156
+00:15:00,910 --> 00:15:06,370
+الله وكيد الله وكيد هؤلاء الكفار فهو كيده تدبير
+
+157
+00:15:06,370 --> 00:15:12,050
+وتخطيط لعباده المؤمنين سبحانه وتعالى حيث لا يتركهم
+
+158
+00:15:12,050 --> 00:15:20,510
+وحدهم بل يقف معهم ويساندهم ذلكم وأن الله موهن كيد
+
+159
+00:15:20,510 --> 00:15:27,060
+الكافرين ايش موهن؟عملته موهنًا على واهن ضعفًا على
+
+160
+00:15:27,060 --> 00:15:30,620
+ضعف، إذا أننا موهن يعني، موت ضعيف، سيضعف الله
+
+161
+00:15:30,620 --> 00:15:34,880
+سبحانه وتعالى كيدة الكافرين، بكفي نحفظ دليل لو جاء
+
+162
+00:15:34,880 --> 00:15:40,700
+سؤال و اذكريه دليلًا على أن كيدة الكفار في ضلال
+
+163
+00:15:40,700 --> 00:15:44,680
+سيضعفه الله، سيبطله الله، من هذه الأيات السهلة
+
+164
+00:15:44,680 --> 00:15:51,380
+اللي محفوظة لدينا جميعًاهذه أخوات بعض آيات القرآن
+
+165
+00:15:51,380 --> 00:15:56,920
+وبعض الجوانب التي فيها مباشرات بانتصار الإسلام
+
+166
+00:15:56,920 --> 00:16:02,000
+والمسلمين في الجانب الآخر جانب آخر من المباشرات هي
+
+167
+00:16:02,000 --> 00:16:07,780
+جانب المباشرات النبوية إذا كان هناك تلت جوانب في
+
+168
+00:16:07,780 --> 00:16:11,780
+القرآن تعرفنا عليها فيها خمس جوانب خمس مباشرات
+
+169
+00:16:11,780 --> 00:16:18,950
+سنتعرف عليهأول هذه المباشرات في مباشرات عامة يعني
+
+170
+00:16:18,950 --> 00:16:24,150
+بصورة عامة دون تحديد أشياء كما سيأتي تحديد هذه
+
+171
+00:16:24,150 --> 00:16:28,110
+الأشياء في المباشرات الأخرى المباشرات العامة بنصر
+
+172
+00:16:28,110 --> 00:16:33,210
+الإسلام وإذلال الكافرين ومنها قوله صلى الله عليه
+
+173
+00:16:33,210 --> 00:16:40,410
+وسلم في الحديث من تقرأنا الحديث تفضل صلى الله عليه
+
+174
+00:16:40,410 --> 00:16:48,170
+وسلمبشر هذه الأمة .. أي أمة؟ الإسلامية تشارع إليها
+
+175
+00:16:48,170 --> 00:16:51,990
+بالسناء والنصر والتمكين .. إيش يعني بالسناء؟
+
+176
+00:16:51,990 --> 00:16:58,030
+بالعلو والرفع والمكانة العالية وبأن ينصرها الله
+
+177
+00:16:58,030 --> 00:17:04,370
+ويمكن له .. هذه الأمةمبشرة من قبل الله ومبشرة من
+
+178
+00:17:04,370 --> 00:17:09,070
+قبل النبي صلى الله عليه وسلم إن هذا القرآن يهدي
+
+179
+00:17:09,070 --> 00:17:13,730
+للتي هي أقوى ويبشر المؤمنين دائما ربنا بيبشر ومنهج
+
+180
+00:17:13,730 --> 00:17:16,790
+النبي صلى الله عليه وسلم كان دائما نقول بشروا ولا
+
+181
+00:17:16,790 --> 00:17:21,550
+تنفروا يسروا ولا تعسروا فهذا الدين قائم على
+
+182
+00:17:21,550 --> 00:17:27,140
+التبشيرتبشير المؤمنين وان يكونوا دائما متفائلين
+
+183
+00:17:27,140 --> 00:17:33,920
+بالنصر و بالمستقبل القريب له أيضا من هذه المباشرات
+
+184
+00:17:33,920 --> 00:17:38,040
+الجميلة تفضل نرجع إلى الأخوات مادة ما مافيش حد بده
+
+185
+00:17:38,040 --> 00:17:44,080
+شارك .. شاركوا معانا في البداية تفضل صلى
+
+186
+00:17:44,080 --> 00:17:51,800
+الله عليه و سلم ماذا يقولإيش يعني لا يبلغنا؟ ده
+
+187
+00:17:51,800 --> 00:17:56,020
+الكلمة من عنا مش من الحديث يعني بيان لمعنى لا
+
+188
+00:17:56,020 --> 00:18:01,440
+يبلغنا يعني لا يصلنا يبلغ يصل لا يبلغنا هذا الأمر
+
+189
+00:18:01,440 --> 00:18:16,760
+كمان مرة بيهيأ
+
+190
+00:18:16,760 --> 00:18:21,710
+الكفر برك الله فيك و أحسنتهذا الحديث الرائع الجميل
+
+191
+00:18:21,710 --> 00:18:27,170
+فيهبشرة عظيمة كبيرة انتبهوا يا أخوات وركزوا في هذه
+
+192
+00:18:27,170 --> 00:18:31,430
+المعاني الجميلة في هذا الحديث ليبلغن هذا الأمر
+
+193
+00:18:31,430 --> 00:18:36,450
+وهذا الأمر إشارة إلى مين؟ إلى الدين إلى الإسلام في
+
+194
+00:18:36,450 --> 00:18:39,990
+كثير من الحديث يشير النبي صلى الله عليه وسلم إلى
+
+195
+00:18:39,990 --> 00:18:44,790
+الدين بقوله هذا الأمر من أحدث في أمرنا هذا أمرنا
+
+196
+00:18:44,790 --> 00:18:49,170
+هذا يعني في ديننا هذا فالإشارة هنا إلى الدين وهنا
+
+197
+00:18:49,170 --> 00:18:54,420
+يقول ليبلغن هذا الأمرهذا الأمر يعني سيبلغ هذا
+
+198
+00:18:54,420 --> 00:18:59,940
+الدين، ايش سيبلغ كلنا؟ سيصل .. سيصل هذا الدين ما
+
+199
+00:18:59,940 --> 00:19:05,580
+بلغ الليل والنهار يعني ما وصل الليل والنهار طب
+
+200
+00:19:05,580 --> 00:19:09,620
+الليل والنهار بيصل إلى ربع الكورة الأرضية بس؟ ولا
+
+201
+00:19:09,620 --> 00:19:14,500
+إلى نصفها؟ ولا إلى ثلاثة أرباعها؟ ايه الخيار
+
+202
+00:19:14,500 --> 00:19:19,940
+الصحي؟ ولا لا شيء مما سبق؟الليل والنهار يصل إلى
+
+203
+00:19:19,940 --> 00:19:24,280
+الكرة الأرضية كلها، معناه ذلك أن الإسلام سيصل إلى
+
+204
+00:19:24,280 --> 00:19:30,460
+الكرة الأرضية كلها بموجب هذا الحديث، ليبلغن هذا
+
+205
+00:19:30,460 --> 00:19:34,460
+الأمر، هذا الدين وهذا الإسلام ما بلغ الليل والنهار
+
+206
+00:19:35,130 --> 00:19:39,290
+وبيأكد إن أكثر النبي صلى الله عليه وسلم بلوغ هذا
+
+207
+00:19:39,290 --> 00:19:46,790
+الدين لكل الأرض و لا يترك الله بيت مدر ولا وبر إيش
+
+208
+00:19:46,790 --> 00:19:50,510
+هو بيت المدر؟ وإيش هو بيت ال .. ال .. ال .. ال ..
+
+209
+00:19:50,510 --> 00:19:50,590
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+210
+00:19:50,590 --> 00:19:50,710
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+211
+00:19:50,710 --> 00:19:50,790
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+212
+00:19:50,790 --> 00:19:50,850
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+213
+00:19:50,850 --> 00:19:52,090
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+214
+00:19:52,090 --> 00:19:52,510
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+215
+00:19:52,510 --> 00:19:52,510
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+216
+00:19:52,510 --> 00:19:52,510
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+217
+00:19:52,510 --> 00:19:52,510
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+218
+00:19:52,510 --> 00:19:57,110
+.. ال .. الالمدر يعني الحجر، مين اللي بيبنيه
+
+219
+00:19:57,110 --> 00:20:01,850
+البيوت من الحجارة؟ أهله المدينة، المدن يعني زي ما
+
+220
+00:20:01,850 --> 00:20:05,870
+يقولوها في البلد، اه فيبنونا بيوتهم من الحجر
+
+221
+00:20:05,870 --> 00:20:11,430
+والوبرالصوف وهو بيت الشعر يعني الذي يبنيه البدو
+
+222
+00:20:11,430 --> 00:20:15,190
+يعني لا يترك الله بيت مدني ولا بدوي ولا حضري ولا
+
+223
+00:20:15,190 --> 00:20:21,370
+قراوي ولا .. إلا وسيدخل هذا البيت الإسلامي وإلا
+
+224
+00:20:21,370 --> 00:20:27,930
+سيسمع هذا البيت بالإسلام خاطرهم أو غصب عنه بعزي
+
+225
+00:20:27,930 --> 00:20:31,870
+عزيزي أو بذل ذليل إذا بدوا بخاطره يصير زيه زي
+
+226
+00:20:31,870 --> 00:20:34,490
+المسلمين ولهما للمسلمين وعليه ما على المسلمين
+
+227
+00:20:34,490 --> 00:20:40,090
+مابدوش غصب عنهحتى يدين الناس كلهم للإسلام ودولة
+
+228
+00:20:40,090 --> 00:20:44,330
+الإسلام ويُعطوا الجزية عن يد وهم صاغره، بتكشف،
+
+229
+00:20:44,330 --> 00:20:48,270
+ابقى على دينك، ادفع للجزية، إذا أنت ستقبل بحكم
+
+230
+00:20:48,270 --> 00:20:52,630
+الإسلام بس مذلون، أما تقبله عزيزا أفضل لك، ادخل
+
+231
+00:20:52,630 --> 00:20:57,510
+فيه، فيصبح لك عز بهذا الدين وهذا الإسلام أفضل ما
+
+232
+00:20:57,510 --> 00:21:03,540
+يُفرض عليك وتدفع الجزيةلحكم المسلمين مقابل بقائك
+
+233
+00:21:03,540 --> 00:21:08,420
+على دينك أما وجودك في هذا الدين الإسلام هو عز وان
+
+234
+00:21:08,420 --> 00:21:12,980
+لك تسأل إيه؟ ولا بتجاومي؟ ماشي احنا ماسألناش
+
+235
+00:21:12,980 --> 00:21:17,560
+السؤال عشان اتجاومي ده من الجواب بعد السؤال اه ولا
+
+236
+00:21:17,560 --> 00:21:21,400
+السؤال معروف؟ اه السؤال معروف فضل رأينا الحديث
+
+237
+00:21:21,400 --> 00:21:25,360
+الثالث في هذا المجال قال رسول الله صلى الله عليه
+
+238
+00:21:25,360 --> 00:21:27,740
+وسلم علينا الصوت مدامك بعيدة
+
+239
+00:21:30,820 --> 00:21:32,240
+صلى الله عليه وسلم
+
+240
+00:21:41,380 --> 00:21:45,480
+الله يفتعلك و بارك الله فيك على هذا القراء لأن هذا
+
+241
+00:21:45,480 --> 00:21:48,820
+الحديث يا أخوات أيضا من الأحاديث الرائعة الجميلة و
+
+242
+00:21:48,820 --> 00:21:53,680
+كل أحاديثه صلى الله عليه و سلم رائعة وجميلة بس في
+
+243
+00:21:53,680 --> 00:21:58,260
+بعض المعاني خل الواحد يعني ينجذب اليها أكثر في
+
+244
+00:21:58,260 --> 00:22:03,480
+تصوير النبي صلى الله عليه و سلم له إن الله زوا لي
+
+245
+00:22:03,480 --> 00:22:08,400
+الأرض، إيش زواها يعني؟زوى يعني جمعها، ضمها، هذه
+
+246
+00:22:08,400 --> 00:22:13,080
+الأرض المتسعة ربنا جمعها وضمها أمام النبي صلى الله
+
+247
+00:22:13,080 --> 00:22:20,000
+عليه وسلم فرأيته مشارقها ومغاربة
+
+248
+00:22:20,000 --> 00:22:23,920
+قال العلماء ليس المقصود هو الشرق والغرب، هذا مجاز
+
+249
+00:22:23,920 --> 00:22:27,240
+يعني كل جوانب، زي ما احنا نقول والله لف من الشرق
+
+250
+00:22:27,240 --> 00:22:32,040
+إلى الغربوليس من الشرق والغرب وانما المقصود هو كل
+
+251
+00:22:32,040 --> 00:22:38,760
+الأرض فرأيت مشارقها ومغاربها وإن أمتي يعني المسلمة
+
+252
+00:22:38,760 --> 00:22:45,720
+مسلمين وإن أمتي سيبلغ ملكها وحكمها وسيطرتها على
+
+253
+00:22:45,720 --> 00:22:51,700
+هذه الأرض مزوية لي منها ستملك الأرض وتحكم الأرض
+
+254
+00:22:51,700 --> 00:22:57,180
+وأعطيته الكنزين الأحمر والأبيض ايش هو الكنز
+
+255
+00:22:57,180 --> 00:23:03,810
+الأحمر؟الذهب الذهب الذهبوإيش الكنز الأبيض؟ الفضة
+
+256
+00:23:03,810 --> 00:23:08,690
+طب على إيش بيرمزوا هدولة الأحمر والأبيض؟ كنوز مين
+
+257
+00:23:08,690 --> 00:23:14,290
+ومين؟ كنوز كسرة وقيصر، كنوز الفرس والروم وقد
+
+258
+00:23:14,290 --> 00:23:20,490
+أعطيها المسلمون في زمن الخلفاء الراشدين حينما
+
+259
+00:23:20,490 --> 00:23:24,330
+فتحوا بلاد فارس وبلاد التي كانت تخضع للرومان
+
+260
+00:23:24,330 --> 00:23:31,750
+وانتصروا على الفرسي وعلى الرومهناك أيضًا أحاديث
+
+261
+00:23:31,750 --> 00:23:35,230
+أخرى كثيرة عشان الوقت بيدركنا و لسه في عندنا
+
+262
+00:23:35,230 --> 00:23:41,260
+مجالات أخرى والله ليتمن الله هذا الأمريعني هذا
+
+263
+00:23:41,260 --> 00:23:44,300
+الأمر دائما إشارة إلى مين قلناها؟ إلى الإسلام حتى
+
+264
+00:23:44,300 --> 00:23:49,940
+يسير الراكب من صنعاء إلى حضر موت لا يخاف إلا الله
+
+265
+00:23:49,940 --> 00:23:55,980
+والذئبى على غنمه ولكنكم تستعجلون سيتم هذا الأمر
+
+266
+00:23:55,980 --> 00:24:02,800
+حتى يسير ويمشي الراكب على فرسه وعلى دبته من صنعاء
+
+267
+00:24:02,800 --> 00:24:08,300
+حيث شمال اليمن إلى حضر موت حيث جنوبها لا يخاف أحدا
+
+268
+00:24:08,530 --> 00:24:13,250
+من الناس ولا من البشر إلا فقط خوفه من من من الله
+
+269
+00:24:13,250 --> 00:24:16,270
+سبحانه وتعالى و إذا كان عنده شوية غنمات بخاف على
+
+270
+00:24:16,270 --> 00:24:20,230
+مين عليهم من الذئب والذئب على غنم أما من البشر من
+
+271
+00:24:20,230 --> 00:24:24,370
+الناس من كذا من كذا مش هيخافوا طب ماحدش خدر في
+
+272
+00:24:24,370 --> 00:24:28,270
+باله إيش معنى يا أستاذ من صناعة إلى حضرامهم ليش
+
+273
+00:24:28,270 --> 00:24:33,560
+المنطقة دي و المكانما إلا حالة الأخت عرفت و كنتبهت
+
+274
+00:24:33,560 --> 00:24:39,260
+و أستنبطت أنه يكثروا فيها لصوص و قطاع الطرق اللي
+
+275
+00:24:39,260 --> 00:24:42,380
+بترسنوا الناس في هذه الطريق كانت معروفة هذه
+
+276
+00:24:42,380 --> 00:24:47,760
+المنطقة بقطاع الطرق فهذه المنطقة اللي الناس بتحسب
+
+277
+00:24:47,760 --> 00:24:51,980
+إليها ألف حساب و بتخاف توصلهاو تمشي منها سيأتي
+
+278
+00:24:51,980 --> 00:24:57,520
+زمان و يوم على الناس سيأمنون على أفسهم و أرواحهم و
+
+279
+00:24:57,520 --> 00:25:03,120
+أموالهم و يسيرون بلا خوف إلا من الله تعالى و قد
+
+280
+00:25:03,120 --> 00:25:06,820
+أتى هذا الزمان و أتى هذا الأمر و أمن الناس بعد
+
+281
+00:25:06,820 --> 00:25:11,240
+انتشار الإسلام و دخول أهل اليمن في الإسلاملا
+
+282
+00:25:11,240 --> 00:25:14,840
+تقوموا الساعة حتى يكثر فيكم المال و يفيدوا حتى
+
+283
+00:25:14,840 --> 00:25:20,720
+يخرج الراجل بزكاة ماله؟ مين يا جماعة محتاج؟ وين في
+
+284
+00:25:20,720 --> 00:25:27,080
+فقراء لهذا المال؟ فلا يجدوا أحدا يقبلها منهوحتى
+
+285
+00:25:27,080 --> 00:25:32,480
+تعود أرض العرب الصحراء القاحلة مروجا وأنهارا بعض
+
+286
+00:25:32,480 --> 00:25:36,380
+العلماء قال حدث ذلك في عهد عمرو بن عبدالعزيز لكن
+
+287
+00:25:36,380 --> 00:25:41,360
+الأرجح هو الأصح والله تعالى أعلم أن ذلك سيكون في
+
+288
+00:25:41,360 --> 00:25:47,540
+عهد وزمن المهدي المسلمين وليس إمام المنتظر عند
+
+289
+00:25:47,540 --> 00:25:51,380
+الشيعة كما سنعرف في المحاضرة القادمة إن شاء الله
+
+290
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+تعالى في الشيعةطب عشان الموضوع طويل و بنخلص نمشي
+
+291
+00:25:55,100 --> 00:25:59,880
+نقلط الجانب الثاني من المباشرات في السنة النبوية
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+292
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+المباشرات بقيام الخلافة الراشدة في فلسطين مش هعرفك
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+293
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+يا أستاذ في فلسطين اتكوا هتيعرفوا مش عرفتوا
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+294
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+هنعرفوا مع بعض و ركزوا معايا جدا و انتبهوا معايا و
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+295
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+حطوا خطوط كما قطعها انا تحتكلمات معينة في الحديث
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+296
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+يتحدث لنا عن مراحل خمسة تمر بها الأمة الإسلامية
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+297
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+آخرها هو هذا العنوان آخرها قيام الخلافة الراشدة في
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+298
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+فلسطين ثم تكون خلافة على منهاج النبوة في آخر
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+299
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+الحديث يسبق ذلك مراحل أربع تكون الخلافة آخرها
+
+300
+00:26:41,690 --> 00:26:46,170
+وخامسها فممكن يجي سؤال فى ترتيب هذه المراحل فى صح
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+301
+00:26:46,170 --> 00:26:49,710
+و غلط فى اختيار فى اوذكري هذه المراحل الواردة فى
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+302
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+هذا الحديث فانتبهوا الى هذا الترتيب المقصود فى
+
+303
+00:26:54,850 --> 00:26:57,990
+الحديث و فى السؤال لأنه ترتيب زمانى مقصود مش
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+304
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+عشوائى يعنى مين تقرأ الناقة الحديث و بعدين طبعا
+
+305
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+بنقرأ سريع و بعدين نعلق على هذا الحديث الأخت
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+306
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+ماسمعناهاش تفضل
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+307
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+وقلنا نركز في الحديثماشاء الله أن تكون ثم يرفعها
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+308
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+إذا شاء أن يرفعها ثم تكون خلافة على منهج النقوة
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+309
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+فتكون ما شاء الله أن تكون ثم يرفعها إذا شاء أن
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+310
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+يرفعها ثم تكون ملكا غعظا فيكون ما شاء الله أن يكون
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+311
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+ثم يرفعها إذا شاء أن يرفعها ثم تكون ملكا جبرية
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+312
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+فتكون ما شاء الله أن تكون ثم يرفعها إذا شاء أن
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+313
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+يرفعها ثم تكون خلافة على منهج النقوةالله يفتح عليك
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+314
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+و بارك الله فيك وأحسنتهذا الحديث طويل نوعا ما باسم
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+315
+00:27:48,980 --> 00:27:53,600
+الحديث السابق فيه حديث عن خمس مراحل كما قلنا أول
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+316
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+هذه المراحل مرحلات النبوة اضعوا خطا تحت النبوة
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+317
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+318
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+يرفعها الله إذا شاء أن يرفعها وكانت النبوة ولا لم
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+319
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+تكن نبوت مين النبي محمد صلى الله عليه وسلم وكانت
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+320
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+هذه المرحلةثم تكون خلافة على منهاج النبوة فتكون ما
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+321
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+شاء الله أن تكون ثم يرفعها الله إذا شاء أن يرفعها
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+322
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+وهي خلافة من؟ خلفاء الراشدين المهديين الأربع أبو
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+323
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+أبي بكر وعمر وعثمان وعليه رضي الله عنهم وعن
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+324
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+الصحابة أجمعين غياظة في الشيعةاللي ماتردوش عنهم
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+325
+00:28:40,530 --> 00:28:45,710
+جميعًا، انت نلاقي المرحلة التانية، ثم تكون خلاف،
+
+326
+00:28:45,710 --> 00:28:52,710
+بعد ذلك ثم تكون ملكًا عضًا عضوا عليها بالنواجذ،
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+327
+00:28:52,710 --> 00:28:57,830
+إيش عني عضًا؟عضوا يعني بتنسك فيها الناس مش راضين
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+328
+00:28:57,830 --> 00:29:02,690
+يسيبوه يعني بمعنى أنهم سيورثونها لأولادهم وأبنائهم
+
+329
+00:29:02,690 --> 00:29:08,090
+وقد كانت بعد الخلفاء الخلافاء الأربع وخلافة من
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+330
+00:29:08,090 --> 00:29:14,090
+الأمويين حيث تولى معاوى رضي الله عنه الحكم ثم جعله
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+331
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+لابن يزيد وهكذا كان الأمرنبوة خلافة راشدة ملكا عضا
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+332
+00:29:20,760 --> 00:29:24,940
+يعض عليه أهل وأصحابه يتشبثوا به ويتمسكوا به وهذا
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+333
+00:29:24,940 --> 00:29:29,990
+كناية عن حكم الوراثةما شاء الله له أن تكون ثم
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+334
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+يرفعه الله إذا شاء أن يرفعه وانتهى ثم تكونوا
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+335
+00:29:33,610 --> 00:29:38,390
+المرحلة الرابعة يا أخوات ملكا جبريا جبريا ملكا
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+336
+00:29:38,390 --> 00:29:40,650
+جبريا ملكا جبريا ملكا جبريا ملكا جبريا ملكا جبريا
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+337
+00:29:40,650 --> 00:29:44,310
+ملكا جبريا ملكا جبريا ملكا جبريا ملكا جبريا ملكا
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+338
+00:29:44,310 --> 00:29:48,010
+جبريا ملكا جبريا ملكا جبريا ملكا جبريا ملكا جبريا
+
+339
+00:29:48,010 --> 00:29:49,290
+ملكا جبريا ملكا جبريا ملكا جبريا ملكا جبريا ملكا
+
+340
+00:29:49,290 --> 00:29:55,030
+جبريا ملكا جبريا ملكا جبريا ملكا جبريا ملكا جبريا
+
+341
+00:29:55,030 --> 00:29:59,480
+ملكا جبرياوالذي يُعبّر عنه اليوم في المصالح
+
+342
+00:29:59,480 --> 00:30:04,400
+السياسي ب .. قصد ريح .. قصد ريح الديكتاتورية الحكم
+
+343
+00:30:04,400 --> 00:30:10,240
+الديكتاتوري وكان ولا لسه ماكانش؟ كان .. كان .. كان
+
+344
+00:30:10,240 --> 00:30:15,740
+ويا ريته ماكان كان واستمر طويلا عقود من الزمن 40 و
+
+345
+00:30:15,740 --> 00:30:22,320
+50 سنة ويحكم المسلمون من قبل حكام ديكتاتوريين ظلمة
+
+346
+00:30:22,320 --> 00:30:28,640
+متسلطين متجبرين قدتخلص العالم الإسلامي والعربي من
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+347
+00:30:28,640 --> 00:30:33,780
+جزء منهم والباقية على الطريق والباقية تأتي ان شاء
+
+348
+00:30:33,780 --> 00:30:42,160
+الله تعالى لكل ظالم ولكل حاكم ظالم يظلم شعبه وأمته
+
+349
+00:30:42,160 --> 00:30:46,900
+هذه الأشياء التي أخبر عنها النبي صلى الله عليه
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+350
+00:30:46,900 --> 00:30:51,020
+وسلم ولم تكن في عهده إلا النبو قد حدثت الخلافة
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+351
+00:30:51,020 --> 00:30:55,770
+حدثت والملك العاض والملك الجابريوهل هيستمر إلى يوم
+
+352
+00:30:55,770 --> 00:31:00,270
+القيامة ولا ينتهي؟ تكونوا ما شاء الله أن تكون ثم
+
+353
+00:31:00,270 --> 00:31:04,050
+يرفعوها الله والأن رفع جزء منها ما نهائيه نحن على
+
+354
+00:31:04,050 --> 00:31:07,790
+يقين أنه سيرفع الباق كما أخبر الرسول صلى الله عليه
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+355
+00:31:07,790 --> 00:31:12,210
+وسلم ليمهد ذلك إلى المرحلة الخامسة والأخيرة عنوان
+
+356
+00:31:12,210 --> 00:31:17,870
+هذه المباشرات وهي قيام الخلافةالراشدة ثم تكون
+
+357
+00:31:17,870 --> 00:31:23,850
+خلافة على منهاج النبوة كما كانت الخلافة الأولى
+
+358
+00:31:23,850 --> 00:31:29,090
+بعده صلى الله عليه وسلم على منهاج النبوة مين اللي
+
+359
+00:31:29,090 --> 00:31:34,330
+سكت الآن؟ الرسول طب مين اللي بيقول ثم سكت؟وهو
+
+360
+00:31:34,330 --> 00:31:38,330
+الحديث حذايفة بيقول بعد ما عد الخمس مراحل هذه عند
+
+361
+00:31:38,330 --> 00:31:42,770
+آخر مرحلة ثم تكون خلافة راشدة على ميناج النبوة سكت
+
+362
+00:31:42,770 --> 00:31:46,810
+يعني مافيش حاجة بعدين لأن هي آخر الأمر آخر أمر
+
+363
+00:31:46,810 --> 00:31:50,950
+المسلمين خلافة راشدة على ميناج النبوة وينها يا
+
+364
+00:31:50,950 --> 00:31:58,050
+أستاذ؟ نحن بانتظارهانحن بانتظاره وستكون بإذن الله
+
+365
+00:31:58,050 --> 00:32:01,890
+تعالى كما أخبر النبي صلى الله عليه وسلم الصادق
+
+366
+00:32:01,890 --> 00:32:07,750
+المصدوق الذي مصدق قوله وكلامه فنحن على اعتاب
+
+367
+00:32:07,750 --> 00:32:11,810
+الخلافة الراشدة التي يقودها المهدي الرجل الصالح
+
+368
+00:32:11,810 --> 00:32:17,850
+الذي وحد المسلمين فيضمن خلافة راشدة و أمة واحدة
+
+369
+00:32:17,850 --> 00:32:23,050
+وجيش واحد يقودهم الى النصر ان شاء الله تعالى طب
+
+370
+00:32:23,050 --> 00:32:26,710
+وين في فلسطين يا أستاذ تقولنا في فلسطين الحديث
+
+371
+00:32:26,710 --> 00:32:32,290
+الآخر يوضح مكان هذه الخلافة فقد ثبت ان النبي صلى
+
+372
+00:32:32,290 --> 00:32:36,690
+الله عليه وسلم وضع يده على رأس ابن حوالة عبدالله
+
+373
+00:32:36,690 --> 00:32:41,910
+ابن حوالة مش أبي حوالة صلحوهوقال يا ابن حيوانة إذا
+
+374
+00:32:41,910 --> 00:32:47,190
+رأيت الخلافة قد نزلت الأرض المقدسة فقددت الزلازل
+
+375
+00:32:47,190 --> 00:32:51,430
+والبلايا والأمور العظام والساعة يوم إذن أقربوا إلى
+
+376
+00:32:51,430 --> 00:32:56,390
+الناس من يدي هذه من رأسك جدتش إيدي جريبة من راسك
+
+377
+00:32:56,390 --> 00:33:01,370
+إذا حدثت هذه الأمور ورأيت الخلافة تنزل في الأرض
+
+378
+00:33:01,370 --> 00:33:08,990
+المقدسة اعرف إن السعملاء اقتربتوهي مقتربة من زمان
+
+379
+00:33:08,990 --> 00:33:13,190
+مقتربت الساعة وانشق القمر من يوم انشق القمر في
+
+380
+00:33:13,190 --> 00:33:15,870
+عهدي صلى الله عليه وسلم وقال عليه الصلاة والسلام
+
+381
+00:33:15,870 --> 00:33:20,550
+بعثت وأنا وساعتي كهاتين وأشارة بإصبعي الوسطى
+
+382
+00:33:20,550 --> 00:33:24,550
+والسبابة وجد ما بدنا نفرج بينهم ونفرج بينهم جدش
+
+383
+00:33:24,550 --> 00:33:29,610
+المسافة بعيدة كتير هذا مانجدش الكلام ألف و أربعمية
+
+384
+00:33:29,610 --> 00:33:35,310
+سنة و يزيد فما بقالنا اليوم جربت ولا ماربتش جربت
+
+385
+00:33:35,310 --> 00:33:41,110
+ولا قربتأه يا أستاذ السامة مش معانا جربت ولا قربت؟
+
+386
+00:33:41,110 --> 00:33:45,370
+قربت اه في ناس يقولك اه ليه وين لسه احنا و يوم
+
+387
+00:33:45,370 --> 00:33:49,310
+لجامعة يوم الله بفرج الله طاولة الحكاية لأ مش
+
+388
+00:33:49,310 --> 00:33:53,630
+مطاولة غمضوا اين و فاتحوا اين و احنا على أبواب
+
+389
+00:33:53,630 --> 00:33:58,930
+الساعةوما أمر الساعة إلا كلمح البصر أو هواقرة،
+
+390
+00:33:58,930 --> 00:34:03,950
+إنهم يراوناه بعيدا ونراه قريبا، وقد حدثت كل
+
+391
+00:34:03,950 --> 00:34:08,990
+علاماتها وأمراتها وإشارات وأشراطها الصغراء، ولم
+
+392
+00:34:08,990 --> 00:34:12,970
+يبق إلا الكبرى، والحلقة بين الصغراء والكبرى قد
+
+393
+00:34:12,970 --> 00:34:19,090
+تكون هي ظهور أو المهدي المسلمين، وبعد ذلك الأمور
+
+394
+00:34:19,090 --> 00:34:19,610
+تباعا
+
+395
+00:34:24,500 --> 00:34:29,820
+إذا رأيت الخلافة قد نزلت الأرض المقدسة والأرض
+
+396
+00:34:29,820 --> 00:34:34,080
+المقدسة في القرآن مين؟ فلسطين قال يا قوم ادخلوا
+
+397
+00:34:34,080 --> 00:34:37,880
+الأرض المقدسة التي كتب الله لكم ولا ترتدوا على
+
+398
+00:34:37,880 --> 00:34:41,140
+أعقابكم فتنقلبوا خاصة سيدنا موسى قال لقوم ادخلوا
+
+399
+00:34:41,140 --> 00:34:46,780
+الأرض المقدسة أرض فلسطين بإجماع العلماء والمفسرين
+
+400
+00:34:48,310 --> 00:34:52,990
+تنزل الخلافة يوما من الأيام في بيت المقدس في الأرض
+
+401
+00:34:52,990 --> 00:34:59,350
+بل كانت دائما بدايتها في المدينة ثم بغداد ثم دمشق
+
+402
+00:34:59,350 --> 00:35:04,190
+ولم تكن في الأرض المقدسة يوما من الأيام فسيكون
+
+403
+00:35:04,190 --> 00:35:08,670
+الخلافة الأخيرة في هذا المكان بإذن الله تعالىمن
+
+404
+00:35:08,670 --> 00:35:13,810
+المباشرات الجميلة وكل المباشرات جميلة منه صلى الله
+
+405
+00:35:13,810 --> 00:35:19,270
+عليه وسلم عظيمة المباشرات بقتال اليهود وانتصار
+
+406
+00:35:19,270 --> 00:35:24,810
+المسلمين عليهم ولا اعتقد ان احد من المسلمين اليوم
+
+407
+00:35:24,810 --> 00:35:31,310
+مش لم يقرأ او لم يمر عليه لم يحفظ هذا الحديث لا
+
+408
+00:35:31,310 --> 00:35:37,190
+تقوم الساعة حتى يقاتل المسلمون اليهود فيقتلونهم
+
+409
+00:35:38,620 --> 00:35:43,200
+فيقتلهم المسلمون فحتى يختبئ اليهودي من ورا الحجر
+
+410
+00:35:43,200 --> 00:35:48,320
+والشجر فيقول الحجر أو الشجر يا مسلم يا عبد الله
+
+411
+00:35:48,320 --> 00:35:54,020
+هذا يهودي خلفي فتعالى فاقتله إلا الغرقد فإنه من
+
+412
+00:35:54,020 --> 00:35:59,170
+شجر اليهود هذا الحديث متفق عليهفي البخاري وفي مسلم
+
+413
+00:35:59,170 --> 00:36:02,950
+وهو حديثه صحيح ومن أصحي الأحديث يجب الاعتقال به
+
+414
+00:36:02,950 --> 00:36:07,790
+والإيمان والتصديق به وله روايات متعددة أحد هذه
+
+415
+00:36:07,790 --> 00:36:11,730
+الروايات في روايات كثيرة بهذا المعنى لن تقوم
+
+416
+00:36:11,730 --> 00:36:17,090
+القيامة حتى يحدث هذا الحدث وهذه المعركة الفاصلة
+
+417
+00:36:17,090 --> 00:36:20,960
+بين المسلمين وليس الفلسطينيينالمسلمين كلهم
+
+418
+00:36:20,960 --> 00:36:27,440
+سيتجمعوا ويحتشدوا لقتال اليهود ولن يجمعهم إلا حاكم
+
+419
+00:36:27,440 --> 00:36:30,760
+واحد خليفة واحد قال العلماء هذا في زمن المهدي وهو
+
+420
+00:36:30,760 --> 00:36:35,380
+قريب ونحن بانتظار هذا الزمن في زمن الخلافة يجمع
+
+421
+00:36:35,380 --> 00:36:40,320
+بين المسلمين ويوحد وينتصر المسلمون على اليهود فهم
+
+422
+00:36:40,320 --> 00:36:46,240
+إلى زوال هذه الدولة المزعومة التي قامت بالاقتصاد
+
+423
+00:36:46,240 --> 00:36:51,220
+لأرضفلسطين كاملة ستعود هذه الأرض إلى أصحابها
+
+424
+00:36:51,220 --> 00:36:54,580
+وأهلها ان شاء الله تعالى المباشرات الرابعة وقبل
+
+425
+00:36:54,580 --> 00:36:58,720
+الأخيرة المباشرات بوجود الطائفة المنصورة في الشام
+
+426
+00:36:58,720 --> 00:37:02,940
+عامة وفي فلسطين خاصة احاديث كتيرة عشان نضيق الوقت
+
+427
+00:37:03,720 --> 00:37:09,180
+بتمور علينا يكفي لو حافظنا منها حديثا لتزال عصابة
+
+428
+00:37:09,180 --> 00:37:12,980
+من أمتي وفي رواية طائفة من أمتي هذه الروايات
+
+429
+00:37:12,980 --> 00:37:18,060
+متعددة يقاتلون على أبواب دمشق هذا الحديث جميل وله
+
+430
+00:37:18,060 --> 00:37:21,280
+خصوصية لم يقصدها الكاتب لأن الكتاب مكتوب من عشر
+
+431
+00:37:21,280 --> 00:37:26,400
+سنين بس هي اليوم يعني إشهارة جميلة لنا وللشعب
+
+432
+00:37:26,400 --> 00:37:32,000
+السورية المجروح والمكلوم والمصابالذي يعاني لا تزال
+
+433
+00:37:32,000 --> 00:37:36,740
+عصابة من أمته يقاتلون على أبواب دمشق وما حوله،
+
+434
+00:37:36,740 --> 00:37:42,340
+وعلى أبواب بيت المقدس وما حوله، لا يضرهم من خذلهم،
+
+435
+00:37:42,340 --> 00:37:47,580
+ظاهرين على الحق، إلى أن تقوم الساعة، سيبقى هؤلاءفي
+
+436
+00:37:47,580 --> 00:37:53,800
+رباط وفي جهاد ويقاتلون الكافرين والظالمين إلى آخر
+
+437
+00:37:53,800 --> 00:37:58,560
+الأحاديث في هذا المعنى وأحاديث كثيرة ترجعون اليها
+
+438
+00:37:58,560 --> 00:38:02,620
+لكي نصل إلى النقطة الخامسة والاخيرة من المباشرات
+
+439
+00:38:02,620 --> 00:38:09,770
+وهي ربما من أجمل المباشراتالتي فيها خصوصية معينة
+
+440
+00:38:09,770 --> 00:38:16,050
+سنتحدث عنها هذه المباشرات بفتح روم عاصمة إيطاليا
+
+441
+00:38:16,050 --> 00:38:23,370
+عاصمة النصرانية الكاثوليكية أحد طواقف النصارى
+
+442
+00:38:23,370 --> 00:38:29,790
+الثلاث الكاثوليكي هذه العاصمة عاصمة إيطاليا روم
+
+443
+00:38:29,790 --> 00:38:34,150
+عاصمة إيطاليا ستفتح وفتحها يعني يا أخوات إيش يعني
+
+444
+00:38:34,150 --> 00:38:39,660
+فتحها؟ تفتحيعني دخول الإسلام فيه وهذا في حديث طويل
+
+445
+00:38:39,660 --> 00:38:44,140
+في وسطه يعني نكتفي من وسطه سؤال الرسول صلى الله
+
+446
+00:38:44,140 --> 00:38:48,920
+عليه وسلم أي المدينتين تفتح أولا لو أحفظنا من هنا
+
+447
+00:38:48,920 --> 00:38:49,500
+جائز
+
+448
+00:38:52,070 --> 00:38:56,530
+اقسطنطينية او رومية كان اسمها ايه قبل ان تسمى
+
+449
+00:38:56,530 --> 00:39:00,330
+اليوم روما رومية فاجاب الرسول عليه الصلاة والسلام
+
+450
+00:39:00,330 --> 00:39:05,950
+قال مدينة هراقل تفتح اولا مين مدينة هراقل
+
+451
+00:39:05,950 --> 00:39:12,590
+القسطنطينية كانت عاصمة الدولة البيزانطية الرومانية
+
+452
+00:39:12,590 --> 00:39:18,030
+عاصمة الامبراطورية الرومانية في ذلك الوقت وكذا كان
+
+453
+00:39:18,030 --> 00:39:25,470
+اسمهافقال تفتحوا مدينة هراقل أولا ويعني ذلك أن
+
+454
+00:39:25,470 --> 00:39:30,190
+روما ستفتحوا بعدها ثانيا و القسطنطينية فتحت كما
+
+455
+00:39:30,190 --> 00:39:34,710
+وعد و أخبر و بشر النبي صلى الله عليه وسلم أم لم
+
+456
+00:39:34,710 --> 00:39:40,930
+تفتحقسطنطينية تاكدين؟ طب فى عهد مين فتحت؟ ومتى
+
+457
+00:39:40,930 --> 00:39:47,850
+فتحت؟ فتحت القسطنطينية عام 857 على هدى القادر محمد
+
+458
+00:39:47,850 --> 00:39:53,010
+الفاتح نعم اسمه محمد السلطان محمد الثانى الملقب
+
+459
+00:39:53,010 --> 00:39:57,230
+بالفاتح لأنه فتح القسطنطينية في هذا العام الهجري
+
+460
+00:39:57,230 --> 00:40:06,720
+857 هجري الموافق 1453 ميلادقرن الخامس عشر الميلاد
+
+461
+00:40:06,720 --> 00:40:13,920
+ومين قسطنطينية قديما مين هي اليوم أسطنبول أحد
+
+462
+00:40:13,920 --> 00:40:19,240
+المدن الكبرى لتركيا هي أسطنبول اليوم ودخل أهلها في
+
+463
+00:40:19,240 --> 00:40:24,080
+الإسلام و أصبحت فيها الخلافة الإسلامية على مدى
+
+464
+00:40:24,080 --> 00:40:27,940
+عقود من الزمان فكما أخبر النبي صلى الله عليه وسلم
+
+465
+00:40:27,940 --> 00:40:32,970
+بهذا الأمر وحدث فسيحدث الأمر التالي وهو الفتحروما
+
+466
+00:40:32,970 --> 00:40:37,810
+الذي نحن بانتظاره ونختم محاضرتنا بهذه المعلومة من
+
+467
+00:40:37,810 --> 00:40:42,170
+أحد دكاترة هذه الجامعة الإسلامية الكرام وقد زار
+
+468
+00:40:42,170 --> 00:40:48,390
+روما إيطاليا قبل حوالي سنتين وحدثنا وكنت جالسا وهو
+
+469
+00:40:48,390 --> 00:40:53,930
+يتحدث أنه زار هذه الدولة وهذه العاصمة وزار فيها
+
+470
+00:40:53,930 --> 00:40:59,550
+حوالي أربعين مسجد معظم مساجد روما وإيطاليا لزارة
+
+471
+00:40:59,550 --> 00:41:06,050
+مكتوب على أبواب المساجدإعلانات وبتحفيظ القرآن
+
+472
+00:41:06,050 --> 00:41:09,410
+ودورات
+
+473
+00:41:09,410 --> 00:41:14,430
+تأهيلية وعليا في أحكام التجويد هذا الكلام وين؟
+
+474
+00:41:14,430 --> 00:41:19,180
+السعودية ولا في فلسطين ولا في مصر؟ في إيطاليافي
+
+475
+00:41:19,180 --> 00:41:23,580
+مساجد إيطاليا في تحفيظ القرآن وفي دورات أحكام
+
+476
+00:41:23,580 --> 00:41:28,280
+تأهيلية وعليا بما يؤكد لنا هذه البشرة من رسول الله
+
+477
+00:41:28,280 --> 00:41:33,520
+صلى الله عليه وسلم هذه بعض المباشرات القرأنية
+
+478
+00:41:33,520 --> 00:41:39,000
+والنبويةفي الحديث عن النصر للإسلام والمستقبل
+
+479
+00:41:39,000 --> 00:41:43,340
+للإسلام والمسلمين نسأل الله تعالى أن يتحقق ذلك
+
+480
+00:41:43,340 --> 00:41:49,120
+قريبا وأن تقر عيوننا بهذا اليوم وبهذا النصر ويوم
+
+481
+00:41:49,120 --> 00:41:55,180
+إذن يفرح المؤمنون بنصر الله والسلام عليكم ورحمة
+
+482
+00:41:55,180 --> 00:41:57,280
+الله وبركاته
+
diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/EbXoqkrW0U0_raw.json b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/EbXoqkrW0U0_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..1204f891cf2b6432be89433ef50af6354350fe2f
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/EbXoqkrW0U0_raw.json
@@ -0,0 +1 @@
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0.765625}, {"start": 2311.57, "end": 2311.81, "word": " كذا", "probability": 0.745849609375}, {"start": 2311.81, "end": 2312.37, "word": " و", "probability": 0.93212890625}, {"start": 2312.37, "end": 2312.83, "word": " يثبتها", "probability": 0.88203125}, {"start": 2312.83, "end": 2313.01, "word": " في", "probability": 0.93994140625}, {"start": 2313.01, "end": 2313.51, "word": " محضر", "probability": 0.9664306640625}, {"start": 2313.51, "end": 2314.49, "word": " علشان", "probability": 0.9645182291666666}, {"start": 2314.49, "end": 2315.49, "word": " يطلق", "probability": 0.9541015625}, {"start": 2315.49, "end": 2316.03, "word": " زوجته", "probability": 0.9650065104166666}, {"start": 2316.03, "end": 2316.83, "word": " فكلها", "probability": 0.8922526041666666}, {"start": 2316.83, "end": 2317.35, "word": " قضايا", "probability": 0.9693603515625}, {"start": 2317.35, "end": 2317.93, "word": " فيها", "probability": 0.97998046875}, {"start": 2317.93, "end": 2318.55, "word": " فضائح", "probability": 0.9620361328125}, {"start": 2318.55, "end": 2319.21, "word": " و", "probability": 0.78759765625}, {"start": 2319.21, "end": 2320.43, "word": " يعني", "probability": 0.93310546875}, {"start": 2320.43, "end": 2320.87, "word": " الإسلام", "probability": 0.9187825520833334}, {"start": 2320.87, "end": 2321.51, "word": " يقبأ", "probability": 0.87744140625}, {"start": 2321.51, "end": 2322.05, "word": " هذا", "probability": 0.89697265625}, {"start": 2322.05, "end": 2323.09, "word": " النشر", "probability": 0.82275390625}, {"start": 2323.09, "end": 2323.29, "word": " و", "probability": 0.88916015625}, {"start": 2323.29, "end": 2323.55, "word": " هذه", "probability": 0.96923828125}, {"start": 2323.55, "end": 2325.03, "word": " الإشاعة", "probability": 0.8553466796875}, {"start": 2325.03, "end": 2326.01, "word": " الفاحشة", "probability": 0.988037109375}, {"start": 2326.01, "end": 2326.29, "word": " بين", "probability": 0.97705078125}, {"start": 2326.29, "end": 2327.37, "word": " المؤمنين", "probability": 0.994384765625}, {"start": 2327.37, "end": 2327.95, "word": " اتوقف", "probability": 0.842041015625}, {"start": 2327.95, "end": 2328.27, "word": " عند", "probability": 0.9921875}, {"start": 2328.27, "end": 2329.53, "word": " تعدد", "probability": 0.9041341145833334}, {"start": 2329.53, "end": 2330.23, "word": " الزوجات", "probability": 0.97314453125}, {"start": 2330.23, "end": 2330.53, "word": " لإن", "probability": 0.7952473958333334}, {"start": 2330.53, "end": 2330.95, "word": " فيها", "probability": 0.97802734375}, {"start": 2330.95, "end": 2331.51, "word": " كلام", "probability": 0.978515625}, {"start": 2331.51, "end": 2331.67, "word": " و", "probability": 0.98681640625}, {"start": 2331.67, "end": 2332.01, "word": " شجوع", "probability": 0.8024088541666666}, {"start": 2332.01, "end": 2332.33, "word": " ناخد", "probability": 0.709228515625}, {"start": 2332.33, "end": 2332.71, "word": " راحتنا", "probability": 0.8614501953125}, {"start": 2332.71, "end": 2332.83, "word": " في", "probability": 0.96240234375}, {"start": 2332.83, "end": 2333.41, "word": " الحديث", "probability": 0.99267578125}, {"start": 2333.41, "end": 2333.91, "word": " عن", "probability": 0.990234375}, {"start": 2333.91, "end": 2334.39, "word": " تعدد", "probability": 0.9630533854166666}, {"start": 2334.39, "end": 2334.93, "word": " الزوجات", "probability": 0.9727783203125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2335.5095, "duration_after_vad": 2274.549374999997}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/F7JOiOKTHOc_raw.srt b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/F7JOiOKTHOc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e9697e71b98712e99d58da5bbcb3ebf35acde207
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/F7JOiOKTHOc_raw.srt
@@ -0,0 +1,1944 @@
+1
+00:00:20,400 --> 00:00:23,240
+الحمد لله يا رب العالمين والصلاة والسلام على أشرف
+
+2
+00:00:23,240 --> 00:00:27,800
+الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحبه
+
+3
+00:00:27,800 --> 00:00:32,320
+أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت
+
+4
+00:00:32,320 --> 00:00:37,380
+العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما
+
+5
+00:00:37,380 --> 00:00:42,720
+علمتنا وازدنا علمة آمين يا رب العالمين أما بعدكنا
+
+6
+00:00:42,720 --> 00:00:46,580
+نتحدث يا أخوات في المحاضرة الماضية حول أسباب نشأة
+
+7
+00:00:46,580 --> 00:00:52,560
+العلمانية في الغرب وعرفنا أن هناك ثلاث أو ثلاثة
+
+8
+00:00:52,560 --> 00:00:56,620
+أسباب لهذه النشأة، مين اذكرنا فيهم؟ هدولة التلات
+
+9
+00:00:56,620 --> 00:01:03,760
+أسباب، تفضلي فساد العقيدة النصرانية واغيان الكنيسة
+
+10
+00:01:04,710 --> 00:01:09,410
+الثورة الفرنسية والنشاط اليهود وتحدثنا عن السبب
+
+11
+00:01:09,410 --> 00:01:16,050
+الأول باستفادة و بالتفصيل وانتهينا من الحديث عنه
+
+12
+00:01:16,050 --> 00:01:19,910
+في نهاية المحاضرة الماضية في محاضرة اليوم ان شاء
+
+13
+00:01:19,910 --> 00:01:26,390
+الله تعالى نكمل باقي هذه الأسباب وهما سببان يعني
+
+14
+00:01:26,390 --> 00:01:34,030
+متبقيان لنا السبب الأول هوالثورة الفرنسية التي
+
+15
+00:01:34,030 --> 00:01:41,990
+قامت سنة 1789 وما صاحب هذه الثورة من أفكار معادلة
+
+16
+00:01:41,990 --> 00:01:47,670
+للدين ثم السبب الثالث هو النشاط اليهودي ودور
+
+17
+00:01:47,670 --> 00:01:52,330
+اليهود في نشأة العلمانية في الغرب بعد ذلك ان شاء
+
+18
+00:01:52,330 --> 00:01:56,430
+الله تعالى نتحدث عن أسباب العلمانية في العالم
+
+19
+00:01:56,430 --> 00:02:02,140
+الإسلاميكما نتحدث أو تحدثنا و نتحدث في باقية يعني
+
+20
+00:02:02,140 --> 00:02:05,680
+الأسباب اليوم أسباب نشأة العلمانية في الغرب في
+
+21
+00:02:05,680 --> 00:02:10,340
+مقابل ذلك سنتحدث عن أسباب نشأة العلمانية في العالم
+
+22
+00:02:10,340 --> 00:02:16,460
+الإسلامينرجع إلى أسباب نشأة العلمانية في الغرب
+
+23
+00:02:16,460 --> 00:02:21,480
+والسبب الثاني بعد السبب الأول الذي انتهينا منه هو
+
+24
+00:02:21,480 --> 00:02:29,820
+الثورة الفرنسية التي قامت سنة 1789 وما صاحب هذه
+
+25
+00:02:29,820 --> 00:02:35,420
+الثورة من أفكار معادلة للدين كانت سببا واضحا من
+
+26
+00:02:35,420 --> 00:02:40,890
+أسباب نشوء أو نشأة العلمانية في الغربحيث كان من
+
+27
+00:02:40,890 --> 00:02:47,350
+شعار هذه الثورة هذا الشعار الذي أمامه اقتلوا آخر
+
+28
+00:02:47,350 --> 00:02:57,550
+ملك بأمعاء آخر قسيس مين وضح لي معنى هذا القول؟ اه
+
+29
+00:02:57,550 --> 00:03:04,380
+مين وضح ليه؟ماذا يعني اقتلوا اخر ملك بامعاء اخر
+
+30
+00:03:04,380 --> 00:03:08,280
+قسيس لو ركزنا على الملك والقسيس يعني ما بتومش لا
+
+31
+00:03:08,280 --> 00:03:11,400
+ملك ولا قسيس يعني ايش معناه هالكلام اللي هو اتخلص
+
+32
+00:03:11,400 --> 00:03:13,700
+من صفة الملك اللي هو النظام الاقتراعي واتخلص من
+
+33
+00:03:13,700 --> 00:03:17,120
+صفة الكنيسة اللي هو المتوثلة في القسيسيعني و كأنه
+
+34
+00:03:17,120 --> 00:03:22,120
+بدهم يقضوا على الملوك حتى آخرهم، فآخر واحد من
+
+35
+00:03:22,120 --> 00:03:25,380
+الملوك، هذا طبعا مثل يعني مش هيعملوا فيه، آخر واحد
+
+36
+00:03:25,380 --> 00:03:29,280
+من الملوك، بدهم يمسكوا أمعاءه، يقتلوا بيها من؟ آخر
+
+37
+00:03:29,280 --> 00:03:34,180
+واحد من القساوسة، فيقضوا على الملوك و يقضوا على
+
+38
+00:03:34,180 --> 00:03:41,410
+القساوسة، فتنتهي سلطةالملك والملوك والاباطرة
+
+39
+00:03:41,410 --> 00:03:45,930
+والقياصرة وسلطة رجال الدين ورجال الكنيسة هذا
+
+40
+00:03:45,930 --> 00:03:49,650
+الشعار الذي رفعته الثورة الفرنسية وهو شعار واضح
+
+41
+00:03:49,650 --> 00:03:54,570
+جدا في الإنقلاب على الدين والكنيسة ورجال الدين
+
+42
+00:03:54,570 --> 00:04:01,760
+ورجال الكنيسة وكان اليهود وراشعارات الثورة
+
+43
+00:04:01,760 --> 00:04:06,920
+الفرنسية وكانوا يرفعون شعار الحرية والمساواة
+
+44
+00:04:06,920 --> 00:04:12,800
+والإخاء يعني هذه الشعارات براقة لامعة ينجذب حولها
+
+45
+00:04:12,800 --> 00:04:18,160
+كثير من الناس كان وراها اليهود يدعمون هذه الثورة
+
+46
+00:04:18,160 --> 00:04:22,260
+ويغذونهاوهذا من طرف آخر يبين لنا النشاط اليهود
+
+47
+00:04:22,260 --> 00:04:27,000
+الذي سنتحدث عنه بقيت قليل كسبب منفصل ومستقل من
+
+48
+00:04:27,000 --> 00:04:31,920
+أسباب نشأة العلمانية في العالم الغربي ووضع اليهود
+
+49
+00:04:31,920 --> 00:04:39,400
+حسبما صرحوا به وحسب وثائقهم وكتبهم وضعوا مخططات
+
+50
+00:04:39,400 --> 00:04:44,480
+لهذه الثورة والتي يعني تولى أمر هذه المخططات
+
+51
+00:04:44,480 --> 00:04:48,740
+والخطط جماعة من اليهود اسمهم النورانيين من حخامات
+
+52
+00:04:48,740 --> 00:04:57,460
+اليهودو ايضا استعانوا بسادة المال و أصحاب رؤوس
+
+53
+00:04:57,460 --> 00:05:02,360
+الأموال اليهود العالميين الكبار المعروفين مثل
+
+54
+00:05:02,360 --> 00:05:09,460
+الثري الكبيرروتشيلد الأول وهذا اسم مشهور ومعروف في
+
+55
+00:05:09,460 --> 00:05:15,160
+عالم الاقتصاد والمال اليهودي الصهيوني المسيطر وذوء
+
+56
+00:05:15,160 --> 00:05:20,420
+النفوذ العالمي في الاقتصاد ثم ابنه ناتان روتشيلد
+
+57
+00:05:20,420 --> 00:05:24,640
+هدول اتنين من اليهود الكبار أصحاب رؤوس الأموال
+
+58
+00:05:24,640 --> 00:05:29,680
+كانوا يغذون هذه الثورة ويدعمون هذه الثورة للأهداف
+
+59
+00:05:29,680 --> 00:05:34,360
+ذاتها وهو فصل الدين عن الدولة والحياة والمجتمع
+
+60
+00:05:35,220 --> 00:05:38,380
+والدين المقصود هنا هو الدين النصراني ليبقى الدين
+
+61
+00:05:38,380 --> 00:05:43,400
+اليهودي مسيطرا ومتحكما ومتنفذا في العالم لأن
+
+62
+00:05:43,400 --> 00:05:46,960
+المعروف الدين النصراني أقوى وأكثر انتشارا وعددا
+
+63
+00:05:46,960 --> 00:05:51,700
+فلما يضعف نفوذ هذا الدين من يبقى في أوروبا يبقى
+
+64
+00:05:51,700 --> 00:05:57,080
+اليهود يتحكمون في المجتمعات الغربيةهذا هو الهدف
+
+65
+00:05:57,080 --> 00:06:02,900
+وهذا ما ذكرته بروتوكولاتهم في كتاب يعني يقدسه
+
+66
+00:06:02,900 --> 00:06:06,520
+اليهود وليس مقدسا يعني مش منزل من عند الله لكن
+
+67
+00:06:06,520 --> 00:06:12,560
+بيقدسه اليهود كالكتب المقدسة عندهم وهو بروتوكولات
+
+68
+00:06:12,560 --> 00:06:17,840
+حكماء صهيون بروتوكولات عبارة عن يعني قوانين وأحكام
+
+69
+00:06:18,470 --> 00:06:22,910
+وبعض المبادئ وضعها حاخامات اليهود الكبار حاخام
+
+70
+00:06:22,910 --> 00:06:28,050
+يعني حكام حكماء حاخام يعني حكيم عالم كبير حكيم من
+
+71
+00:06:28,050 --> 00:06:32,950
+حكماء اليهود اتفقوا واجتمعوا ووضعوا هذه المخططات
+
+72
+00:06:32,950 --> 00:06:37,730
+وهذه المبادئ وهذه البروتوكولات فخرج كتاب اسمه
+
+73
+00:06:37,730 --> 00:06:43,190
+بروتوكولات حكماء الصهيون وهو من أكثر الكتب يعني
+
+74
+00:06:45,720 --> 00:06:55,980
+بيانا وتوضيحا لخطط اليهود ونفسياتهم ومبادئهم التي
+
+75
+00:06:55,980 --> 00:07:01,180
+يتحكمون في العالم من خلالهايعني اذكر من هذه
+
+76
+00:07:01,180 --> 00:07:05,660
+البروتوكولات الخطيرة بروتوكول يقول خُلق العالم
+
+77
+00:07:05,660 --> 00:07:12,120
+أجمع ليكون بالحرف حميرا لبني صهيون فكذا ينظر
+
+78
+00:07:12,120 --> 00:07:17,280
+اليهود للعالم بأنهم حميرا اعزاكم الله يقودهم بني
+
+79
+00:07:17,280 --> 00:07:21,840
+صهيون ويقودهم اليهود مستعبدين مستخدمين فهذا ما
+
+80
+00:07:21,840 --> 00:07:25,740
+ذكره القرآن عن ذلك بأنهم قالوا ليس علينا في
+
+81
+00:07:25,740 --> 00:07:30,810
+الأميين سابيلسبيل يعني لا محاسبة ولا مؤاخذة في
+
+82
+00:07:30,810 --> 00:07:34,270
+الأميين يعني غير اليهود، أيش ما نعمل فيهم يعني
+
+83
+00:07:34,270 --> 00:07:38,530
+ربنا مابيأخذناه لأنهم مش يهود، هذه النظرة العنصرية
+
+84
+00:07:38,530 --> 00:07:46,230
+المزروعة في قلب وداخل ونفس اليهود من هذه
+
+85
+00:07:46,230 --> 00:07:52,770
+البرتقالات جاء تصريح رسمي واضح بأن اليهود ورا هذه
+
+86
+00:07:52,770 --> 00:07:56,090
+الثورة، من تقرأ إن هذا النص الوارد
+
+87
+00:08:02,220 --> 00:08:05,600
+الثورة الفرنسية اللي بيسميها الكبرى إن أسرار
+
+88
+00:08:05,600 --> 00:08:09,400
+فنظيمها التمهيدي معروفة لنا جيدا لأنها بيصنعلأنها
+
+89
+00:08:09,400 --> 00:08:13,820
+من صنع أي دين لأنهم دعموا هذه الثورة بهذا الهدف
+
+90
+00:08:13,820 --> 00:08:17,700
+الذي ذكرناه وكان من أهم نتائج هذه الثورة
+
+91
+00:08:17,700 --> 00:08:22,860
+وإفرازاتها فصل الدين عن الدولة وتقييد السلطان
+
+92
+00:08:22,860 --> 00:08:26,940
+السياسي للملوك والحكام وواضح من هذا الشعار اللي
+
+93
+00:08:26,940 --> 00:08:32,280
+قرأناه في الأول اقتلوا آخر ملك بأمعاء آخر قسيس
+
+94
+00:08:32,280 --> 00:08:37,680
+فيها فصل واضح للدين عن الدولة والحياةلسلطان الملوك
+
+95
+00:08:37,680 --> 00:08:43,400
+والحكام السبب الثالث والأخير من أسباب نشأة
+
+96
+00:08:43,400 --> 00:08:48,720
+العلمانية في الغرب هو النشاط اليهودي وقد سبق
+
+97
+00:08:48,720 --> 00:08:54,980
+الحديث قبل قليل يعني ربماتكلمنا عن اليهود ودور
+
+98
+00:08:54,980 --> 00:08:58,220
+اليهود اكثر ما تكلمنا عن الثورة الفرنسية نفسي يعني
+
+99
+00:08:58,220 --> 00:09:02,040
+كانوا عنوان الثورة الفرنسية لكن المحتوى و الفحوة
+
+100
+00:09:02,040 --> 00:09:06,100
+اليهود اليهود اليهود هم الذين قاموا بتغذيتها
+
+101
+00:09:06,100 --> 00:09:12,300
+ومبادئها وهم وراقها ودعموها ليه هدف واحد فقط
+
+102
+00:09:12,300 --> 00:09:16,160
+التعلق بالثورة الفرنسية هو فصل الدين عن الدولة
+
+103
+00:09:16,160 --> 00:09:21,280
+وتقييد سلطة الملوك اما عن النشاط نفسه ماذا قام
+
+104
+00:09:21,280 --> 00:09:28,280
+اليهودودورهم المباشر ربما كان دور غير مباشر لهم من
+
+105
+00:09:28,280 --> 00:09:32,900
+ورا السطار indirect هنا الدور مباشر direct واضح
+
+106
+00:09:33,610 --> 00:09:39,290
+وصريح في ان اليهود يعني سبب من أسباب نشأة
+
+107
+00:09:39,290 --> 00:09:43,450
+العلمانية في الغرب وهذا التصريح واضح من كاتب
+
+108
+00:09:43,450 --> 00:09:48,090
+أمريكي يعني كابير وليام جاي كار اسمه بيقول لقد كان
+
+109
+00:09:48,090 --> 00:09:54,560
+اليهود ورا فكرة فصل الدين عن الدولةيعني بيرجع
+
+110
+00:09:54,560 --> 00:09:59,500
+السبب في ذلك الى اليهود و دورهم و تخطيطهم و نفس
+
+111
+00:09:59,500 --> 00:10:02,880
+البروتوكولات اللتي سبقوا حتى حدثنا عنها بروتوكولات
+
+112
+00:10:02,880 --> 00:10:07,280
+حكومات صهيون بتؤكد ذلك في هذا النص .. مين تقرألنا
+
+113
+00:10:07,280 --> 00:10:12,460
+هذا النص يا أخوات؟ طبعا .. مال الشجة هذه؟ أختلف
+
+114
+00:10:12,460 --> 00:10:13,220
+الآخر، اتفضل
+
+115
+00:10:25,200 --> 00:10:31,320
+هذه تصريح من اليهود إنهم يتقلصوا هذا النفوذ الديني
+
+116
+00:10:31,320 --> 00:10:36,340
+ومبسوطين على تقليص هذا النفوذ وتضاقله روايدا
+
+117
+00:10:36,340 --> 00:10:39,960
+روايدا حتى قالوا أيضا عبارة أخرى
+
+118
+00:10:43,810 --> 00:10:52,070
+و سنحصر الدين و رجاله في أضيق نطاق و سنحصر
+
+119
+00:10:52,070 --> 00:10:55,470
+الدين و رجاله في أضيق نطاق و سنحصر الدين و رجاله
+
+120
+00:10:55,470 --> 00:11:00,910
+في أضيق نطاق و
+
+121
+00:11:00,910 --> 00:11:04,150
+سنحصر
+
+122
+00:11:04,150 --> 00:11:06,490
+الدين و رجاله في أضيق نطاق
+
+123
+00:11:09,870 --> 00:11:14,020
+اليزيخ السلطان الدين غير اليهوديةأول حاجة لا يريد
+
+124
+00:11:14,020 --> 00:11:18,560
+أحد غير اليهود يتحكم في الناس يعني فقط الدين الذي
+
+125
+00:11:18,560 --> 00:11:22,780
+يتحكم في الناس هو اليهود باقي الأديان لا يريدها و
+
+126
+00:11:22,780 --> 00:11:29,040
+هذا هو يعني فكر اليهود و عقيدتهم و نفسيتهم يعني لا
+
+127
+00:11:29,040 --> 00:11:32,340
+يريد أحد غيره و قالوا لن يدخل الجنة إلا من كان
+
+128
+00:11:32,340 --> 00:11:36,260
+يهودا أو نصارى اليهود قالوا بس اليهود و النصارى
+
+129
+00:11:36,260 --> 00:11:39,840
+قالوا بس النصارى فهذا يعني ما عند اليهود و ما عند
+
+130
+00:11:39,840 --> 00:11:46,080
+النصارى اتنينفتكون لهم كلمة الفصل النهائية في هذا
+
+131
+00:11:46,080 --> 00:11:49,640
+العالم ويحكموا
+
+132
+00:11:49,640 --> 00:11:52,520
+هذا العالم ومايكونش حدا منافس لهم في هذا الحكم
+
+133
+00:11:52,520 --> 00:11:57,380
+وبالتالي في النهاية هدف التالت انهم يحققوا السيادة
+
+134
+00:11:57,380 --> 00:12:03,000
+على الأديان كلهاحتى يكون السيادة لهم وحدهم وقد
+
+135
+00:12:03,000 --> 00:12:06,700
+نجحوا إلى حد بعيد و اليوم كلنا بنشهد و بنعرف و
+
+136
+00:12:06,700 --> 00:12:11,940
+بنسمع و بنقدر اي موقف سياسي عالمي او كبير او كذا
+
+137
+00:12:11,940 --> 00:12:16,160
+او كذا و هذا ورا اليهود و خاصة اذا ماكان ضد العرب
+
+138
+00:12:16,160 --> 00:12:21,540
+و المسلمين و بالاخص الشعب الفلسطيني من فيتو امريكي
+
+139
+00:12:21,540 --> 00:12:28,000
+و غربي و كذا بتلاقيه ورا اليهود في دعمهمنع أي قرار
+
+140
+00:12:28,000 --> 00:12:34,040
+يتخذ ضد اليهود أو السياسة اليهودية تجاه الشعب
+
+141
+00:12:34,040 --> 00:12:40,880
+الفلسطيني بهاذا نكون قد انتهينا من الحديث عن أسباب
+
+142
+00:12:40,880 --> 00:12:46,080
+نشأة العلمانية في العالم الغربي لنتقل بعد ذلك إلى
+
+143
+00:12:46,080 --> 00:12:51,640
+الحديث عن أسباب نشأة العلمانية في العالم الإسلامي
+
+144
+00:12:52,280 --> 00:12:56,820
+يعني بملاحظة بسيطة قبل أن نبدأ أو نخوض في هذه
+
+145
+00:12:56,820 --> 00:13:01,760
+الأسباب نقول هذه الملاحظة وسنكررها ربما في كل فقرة
+
+146
+00:13:01,760 --> 00:13:06,740
+وفي نهاية الحديث عن هذه الأسباب يعني إذا كان هذه
+
+147
+00:13:06,740 --> 00:13:14,800
+الملاحظة إذا كان للعالم الغربي مبرر وسبب مبرراته
+
+148
+00:13:14,800 --> 00:13:22,060
+وأسبابه لتبني العلمانية وفصل الدين عن الحياةوالكفر
+
+149
+00:13:22,060 --> 00:13:27,420
+بهذا الدين الذي يحارب العلم والعلماء ويقيدهم هل
+
+150
+00:13:27,420 --> 00:13:33,210
+للمسلمين والعالم الإسلامي هذا المبرر وهذا السبب؟هل
+
+151
+00:13:33,210 --> 00:13:37,870
+يحق لهم ويجوز لهم؟ هل هذا مبرر؟ هل الدين الموجود
+
+152
+00:13:37,870 --> 00:13:41,750
+عند المسلمين، دين الإسلام، يقف ضد العلم والعلماء
+
+153
+00:13:41,750 --> 00:13:46,430
+ويحارب العلم والعلماء ويمنع التقدم العلمي وكما كان
+
+154
+00:13:46,430 --> 00:13:51,230
+الدين النصراني المحرف ورجال الدين اللي كانوا
+
+155
+00:13:51,230 --> 00:13:54,970
+يمارسون الطغيان المختلف اللي تعرفنا عليه من خلال
+
+156
+00:13:54,970 --> 00:14:03,500
+هذه الأسباب؟ لا مبرر ولا سببمشروع لأن نستورد و
+
+157
+00:14:03,500 --> 00:14:07,940
+نأخذ و نتبنى نحن كمسلمين هذا المفهوم و هذا المبدأ
+
+158
+00:14:07,940 --> 00:14:12,520
+و هو العلمانية فنفصل في حياتنا و سياستنا و في
+
+159
+00:14:12,520 --> 00:14:16,360
+الدولة و في الحكم و في كل مجال نفصل بين الدين و
+
+160
+00:14:16,360 --> 00:14:21,580
+ذلك و كأن الدين فقط يعني عقيدة و عبادة ولا دور له
+
+161
+00:14:21,580 --> 00:14:28,430
+ولا أثر له في الحياة ولا في السياسة ولا في الحكمطب
+
+162
+00:14:28,430 --> 00:14:33,070
+نأتي إلى هذه الأسباب وهي أربعة أسباب نجمعها في
+
+163
+00:14:33,070 --> 00:14:36,630
+البداية كالعادة شوف هذه الأسباب الأربعة ثم نبدأ
+
+164
+00:14:36,630 --> 00:14:40,430
+بالتفصيل في كل واحدة منهم أول سبب ان هذه الأسباب
+
+165
+00:14:40,430 --> 00:14:44,910
+.. انحراف
+
+166
+00:14:44,910 --> 00:14:51,250
+الأمة الإسلامية انحراف عن ايش؟ عن فهم الإسلام كدين
+
+167
+00:14:51,250 --> 00:14:51,790
+شامل
+
+168
+00:14:54,560 --> 00:14:58,280
+اه ده من جدام مرة من ورا مرة من جدام فضل تخلف أو
+
+169
+00:14:58,280 --> 00:14:59,880
+تأخر الدين الإسلامي
+
+170
+00:15:27,930 --> 00:15:37,490
+العالم الإسلامييعني العصريين تلاتة تفضلي يعني
+
+171
+00:15:37,490 --> 00:15:43,330
+صادفت أو وافقت أن أوروبا يعني نهضت مع تبنيها
+
+172
+00:15:43,330 --> 00:15:46,970
+للعلمانيين فكأنه صار في رابط أنه متى نهضت أوروبا
+
+173
+00:15:46,970 --> 00:15:50,950
+حين تبنت العلمانيين فصار كأنه يعني احنا عشان نتقدم
+
+174
+00:15:50,950 --> 00:15:55,030
+و ننهض لازم نتبني العلمانية مثله صار هيك في النفس
+
+175
+00:15:55,030 --> 00:16:01,970
+يعني والسبب الرابع الأخيرالتخطيط الصليبي اليهود
+
+176
+00:16:01,970 --> 00:16:05,970
+يعني اليهود لازم في كل حاجة يظهر زي الملح في
+
+177
+00:16:05,970 --> 00:16:11,450
+الطبيخ لغنى عنه الطبيخ بستغنى عن الملح فبحشروا
+
+178
+00:16:11,450 --> 00:16:17,280
+حالهم في كل شيءوهذا ديدانهم وكما وصفهم ربنا سبحانه
+
+179
+00:16:17,280 --> 00:16:22,340
+وتعالى كلما أوقضوا نارا للحرب أطفأها الله وإيش
+
+180
+00:16:22,340 --> 00:16:27,760
+شغلتهم وعملتهم ويسعون في الأرض فساد وين في فساد؟
+
+181
+00:16:27,760 --> 00:16:32,360
+بتلاقي فيه يهود وقد صدق فيهم يوسف عليه السلام وهم
+
+182
+00:16:32,360 --> 00:16:36,920
+إخوته بنوا إسرائيل بنوا يعقوب قال لهم أنتم شر
+
+183
+00:16:36,920 --> 00:16:41,420
+مكانةانتم الشر اللي في المكان اللي بتحلوا فيه،
+
+184
+00:16:41,420 --> 00:16:46,940
+أينما تحلوا فالشر بيحل معاه، أنتم شر مكانه، يعني
+
+185
+00:16:46,940 --> 00:16:50,460
+الشر اللي بيحل في أي مكان، و بفعل وين ما بيكونوا،
+
+186
+00:16:50,460 --> 00:16:57,700
+يكون الشر و الفساد معهم، وهؤلاء هم اليهود، اليهود
+
+187
+00:16:57,700 --> 00:17:03,510
+هم اليهود، و لن يتغير قديما و حديثا و مستقبلاهذه
+
+188
+00:17:03,510 --> 00:17:08,930
+الأسباب الأربعة لنشأة العلمانية في العالم الإسلامي
+
+189
+00:17:08,930 --> 00:17:13,530
+أو تبني العالم الإسلامي للعلمانية السبب الأول
+
+190
+00:17:13,530 --> 00:17:19,750
+ياخوات هو انحراف الأمة الإسلامية عن فهم الإسلام
+
+191
+00:17:19,750 --> 00:17:25,830
+والإسلام دين شامل يشمل جميع مظاهر الحياة ليس فقط
+
+192
+00:17:25,830 --> 00:17:30,150
+الإسلام عقيدة نؤمن فيها بالله الواحد الأحد فقط
+
+193
+00:17:30,150 --> 00:17:35,920
+عقيدةولا فقط هو عبادة، صلاة و صيام و حج و زكاهة،
+
+194
+00:17:35,920 --> 00:17:40,280
+ده جزء، هو جزء هام و أساسي، و هو الأصل و الأساس،
+
+195
+00:17:40,280 --> 00:17:44,000
+العقيدة و الإيمان و العبادات الحديث تقول بني
+
+196
+00:17:44,000 --> 00:17:49,020
+الإسلام على خمس، بنيه، كالبناء الذي يبني على أسس
+
+197
+00:17:49,910 --> 00:17:54,890
+فهل الأسس هي الإسلام، هي البناء، فهل أسس أي بناء،
+
+198
+00:17:54,890 --> 00:17:59,630
+الأسسية والقواعد هي البناء ولا هي أسس البناء؟ بنى
+
+199
+00:17:59,630 --> 00:18:02,670
+الإسلام على خمس، شهادة لا إله إلا الله وأن محمد
+
+200
+00:18:02,670 --> 00:18:05,630
+رسول الله ومنها أيش؟ قام الصلاة وإيتاء الزكاة وصوم
+
+201
+00:18:05,630 --> 00:18:09,690
+رمضان والحجة، أدو الأسس الإسلام والإيمان أيضا في
+
+202
+00:18:09,690 --> 00:18:12,970
+أركانه الست، أسس الإيمان، بعد ذلك في بناء كامل
+
+203
+00:18:12,970 --> 00:18:18,360
+متكامل اسم الإسلامهذه أرسله وهذه أركانه أهم قواعد
+
+204
+00:18:18,360 --> 00:18:23,040
+أهم من الأشياء بعد ذلك في بناء كامل فهو عقيدة صحيح
+
+205
+00:18:23,040 --> 00:18:34,150
+وعبادة لكنه أيضامعاملات و أخلاق و قيم و أداب و
+
+206
+00:18:34,150 --> 00:18:40,310
+اجتماع و سياسة و اقتصاد و جهاد و دولة و حكم و شريع
+
+207
+00:18:40,310 --> 00:18:45,810
+ما فرطنا في الكتاب من شيء الله سبحانه و تعالىما
+
+208
+00:18:45,810 --> 00:18:49,650
+فرطنا في الكتاب من شيء يحتاج إليه الناس إلا و الله
+
+209
+00:18:49,650 --> 00:18:54,650
+سبحانه وتعالى قد أتى به وجاء به والنبي صلى الله
+
+210
+00:18:54,650 --> 00:18:59,910
+عليه وسلم كذلكفهذا الإسلام يا أخوان إسلامنا وديننا
+
+211
+00:18:59,910 --> 00:19:04,730
+هو دين شامل كامل يا أيها الذين آمنوا دخلوا في
+
+212
+00:19:04,730 --> 00:19:09,230
+السلم كافة والسلم في هذه الآية كما قال المفسرون عن
+
+213
+00:19:09,230 --> 00:19:13,630
+الإسلام دخلوا في الإسلام كاملا خذوه كاملا أفتؤمنون
+
+214
+00:19:13,630 --> 00:19:18,550
+ببعض الكتاب وتكفرون ببعض الفعش المؤمن المسلم الحق
+
+215
+00:19:18,550 --> 00:19:23,980
+والمؤمنة والمسلمةلابد أن تأخذ بالإسلام ككل، تفهمه
+
+216
+00:19:23,980 --> 00:19:27,420
+ككل و تطبقه ككل، مش تأخذ اللي يعجبها و اللي لا
+
+217
+00:19:27,420 --> 00:19:32,000
+يعجبها أو يأخذ اللي يعجبه و اللي لايعجبه، مش نجلة
+
+218
+00:19:32,000 --> 00:19:37,440
+حكاية يعني فالإسلام كامل، متكامل، يشمل كل مظاهر
+
+219
+00:19:37,440 --> 00:19:44,870
+الحياة، هذا المفهوم الشامل والعظيم انحصروتقسم فيه
+
+220
+00:19:44,870 --> 00:19:50,970
+تصورات وعقول وقلوب المؤمنين أو المسلمين في العالم
+
+221
+00:19:50,970 --> 00:19:55,410
+الإسلام فأصبح كأن الإسلام فقط مجموعة من العبادات
+
+222
+00:19:55,410 --> 00:20:00,150
+إذا ما أديناها أدينا كل اللذي أعلنتها الإسلاموهو
+
+223
+00:20:00,150 --> 00:20:03,510
+في المساجد حافظ عليه في الصلاة في كذا في صلاة
+
+224
+00:20:03,510 --> 00:20:06,550
+الجماعة في صلاة الجمعة فإذا ما خرج الإنسان من
+
+225
+00:20:06,550 --> 00:20:11,690
+المسجد انتهى دور الإسلام من حياته هو فقط للمسجد و
+
+226
+00:20:11,690 --> 00:20:16,270
+للصلاة و للعبادة أما الحياة فليس له دور هذا ليس هو
+
+227
+00:20:16,270 --> 00:20:22,110
+الإسلام الذي تعلمناه و فهمناه وبالتالي يقول هنا
+
+228
+00:20:22,110 --> 00:20:27,280
+كاتب الانحراف الأشد يقول انحراف الأمة الإسلاميةعن
+
+229
+00:20:27,280 --> 00:20:31,340
+فاهمة للإسلام أشد انحراف كان في العقيدة وكان في
+
+230
+00:20:31,340 --> 00:20:36,880
+التصور في العقيدة والتصور وحتى في هذه الكلمة اللي
+
+231
+00:20:36,880 --> 00:20:42,900
+يقولها الناس ويستهنون بها أو يستخفونها ويعتقدون
+
+232
+00:20:42,900 --> 00:20:48,060
+بأن النطق بها باللسان يكفي واحدة و لا إله إلا الله
+
+233
+00:20:48,060 --> 00:20:50,960
+يقول الإنسان واحد الله و لا إله إلا الله سيكون
+
+234
+00:20:50,960 --> 00:20:57,060
+خاطر يقتلك إذا كنت واحد الله أو اتقى الله أويعني
+
+235
+00:20:57,060 --> 00:20:59,640
+كأنه الكلمة هذه سهلة يعني كلمة عادية لا إله إلا
+
+236
+00:20:59,640 --> 00:21:03,420
+الله هو لا هيك أتنفط وهو لا يعلم معناها الحقيقي
+
+237
+00:21:03,420 --> 00:21:08,420
+الشامل الكامل الذي فيه هذه المعاني اللي الكاتب أو
+
+238
+00:21:08,420 --> 00:21:12,840
+المؤلف بيحاول يرسخها فيه فيها العبودية لله وحده لا
+
+239
+00:21:12,840 --> 00:21:19,340
+إله إلا الله يعني لا معبودة بحق إلا الله لا صنم
+
+240
+00:21:19,340 --> 00:21:24,820
+ولا حجر ولا شجر ولا قمر ولا بشر ولا بقر كل حرف
+
+241
+00:21:24,820 --> 00:21:29,300
+الراء جايةكل هذه المعبدات اللي عبدت لا إله لا
+
+242
+00:21:29,300 --> 00:21:34,480
+أعترف بها كآله إلا إله واحد هو الإله الحق الواحد
+
+243
+00:21:34,480 --> 00:21:39,000
+الأحد الفرد الصامد الذي لم يلد ولم يولد ولم يكن له
+
+244
+00:21:39,000 --> 00:21:43,580
+كفوا أحد ليس كمثله شيء وهو السميع البصير هذا هو
+
+245
+00:21:43,580 --> 00:21:48,800
+الإله الحق وهذا الإله أمر قال لاتعبدوا إلا إياه
+
+246
+00:21:48,800 --> 00:21:55,550
+قال إن الحكم إلا للهالحكم له زي ما هو صاحب الخلق
+
+247
+00:21:55,550 --> 00:22:01,350
+يعني هو رب فهو أيضا صاحب الأمر قال له الخلق والأمر
+
+248
+00:22:01,350 --> 00:22:06,730
+هو اللي له أن يأمرنا ويحكمنا فبالتالي المسلم
+
+249
+00:22:06,730 --> 00:22:10,190
+المؤمن لابد أن يحتكم إلى الله يحتكم إلى شرع الله
+
+250
+00:22:10,190 --> 00:22:15,610
+هذا المفهوم ماكانش موجود يعني كما أراده الله
+
+251
+00:22:15,610 --> 00:22:18,170
+سبحانه وتعالى عند المسلمين فاعتقدوا كما قلنا أن
+
+252
+00:22:18,170 --> 00:22:21,890
+الإسلام مجرد عقيدة وعبادة وخلاصوباقى هذا النوع
+
+253
+00:22:21,890 --> 00:22:25,670
+فدخلت عليهم العلمانية من هذا الباب وهي فصل الدين
+
+254
+00:22:25,670 --> 00:22:28,610
+عن الحياة الدين مالهوش علاقة بحياتنا ولا في دنيانا
+
+255
+00:22:28,610 --> 00:22:32,450
+ولا في حكمنا ولا في تشريعنا ولا .. من هنا كان
+
+256
+00:22:32,450 --> 00:22:38,890
+الانحراف في هذا التصور وفي هذا الفهم و هذه الآيات
+
+257
+00:22:38,890 --> 00:22:45,010
+الكثيرة توضح لنا يعني هذا المعنى الشامل لهذه
+
+258
+00:22:45,010 --> 00:22:49,050
+الكلمة العظيمة كلمة التوحيد كلمة لا إله إلا الله
+
+259
+00:22:51,180 --> 00:22:58,020
+تاني هذه الأسباب يا أخوات التي سببت بدخول ونشوء
+
+260
+00:22:58,020 --> 00:23:03,460
+وتبني العلمانية في العالم الإسلامي هي تخلف أو تأخر
+
+261
+00:23:03,460 --> 00:23:10,320
+نحن نفضل الكلمة العالم الإسلامي تأخره عن أيش؟ عن
+
+262
+00:23:10,320 --> 00:23:17,380
+ملاحقة العلوممدنية أو العلوم الطبيعية كما يقولونها
+
+263
+00:23:17,380 --> 00:23:21,720
+الطب والهندسة والعلوم بجميع أنواعها من فيزياء
+
+264
+00:23:21,720 --> 00:23:27,320
+وكيمياء ورياضيات وعلم اجتماع وعمران مع أن الماضي
+
+265
+00:23:27,320 --> 00:23:34,040
+والتاريخ والحضارة الإسلامية شهدت يعني نشاطا فكريا
+
+266
+00:23:34,040 --> 00:23:38,720
+وعلميا رائعا يشهد له العدو قبل الصديق الغرب الذي
+
+267
+00:23:38,720 --> 00:23:45,360
+يعاد الإسلام اليومويستدرله ولادي العلماني ويستعمر
+
+268
+00:23:45,360 --> 00:23:50,220
+بلاد المسلمين ويحتلها ونزل يحتل أجزاء منها على رأس
+
+269
+00:23:50,220 --> 00:23:54,960
+فلسطين وغيرها من بلدان المسلمين يشهد ويعرف هذا
+
+270
+00:23:54,960 --> 00:24:02,090
+الفضل لكن ما الذي حدث ان هو تقدموتطور وبنى على
+
+271
+00:24:02,090 --> 00:24:07,370
+علوم المسلمين وعلى حضارتهم وتعلم على أيديهم وتقدم
+
+272
+00:24:07,370 --> 00:24:13,510
+وتطور المسلمون مالهم مكانك سره كان قف توقفوا
+
+273
+00:24:13,510 --> 00:24:18,930
+تجمدوا صار فيه توقف عندما كانوا عليه لم يتقدموا
+
+274
+00:24:18,930 --> 00:24:26,210
+ولم يتطوروا فما هي أسباب هذا التخلف من صحة التعبير
+
+275
+00:24:26,210 --> 00:24:32,110
+أو التأخر بعبارة أدق وأفضلعن مواكبة هذه العلوم
+
+276
+00:24:32,110 --> 00:24:36,910
+التي كان عليها المسلمون و أبدعوا فيها في عدة أسباب
+
+277
+00:24:36,910 --> 00:24:42,310
+هنا في حوالي أربع أسباب على رأس هذه الأسباب واحد و
+
+278
+00:24:42,310 --> 00:24:45,710
+هذا
+
+279
+00:24:45,710 --> 00:24:50,970
+أهم سبب وأول سبب السبب الأساسي لأنهم كانوا يأخذون
+
+280
+00:24:54,480 --> 00:24:58,720
+نشاطهم والدافعية اللتي كانوا عليها والحماسة اللتي
+
+281
+00:24:58,720 --> 00:25:03,310
+كانوا ينطلقون منها من وينمن الدين من القرآن من
+
+282
+00:25:03,310 --> 00:25:06,770
+السنة القرآن يحرض على العلم كنا في أكثر من مناسبة
+
+283
+00:25:06,770 --> 00:25:10,850
+ايات الكثيرة اللي في القرآن بتدفع وتحث وتشجع على
+
+284
+00:25:10,850 --> 00:25:16,670
+العلم تحرض عليه وكذلك الأحاديث السنة النبوية ولا
+
+285
+00:25:16,670 --> 00:25:19,750
+داع لذكر حشد كبير من الأيات والأحاديث اللي انا
+
+286
+00:25:19,750 --> 00:25:23,510
+معروفة ومحفوظة عندنا كطلاب طالبات علم يعني
+
+287
+00:25:23,510 --> 00:25:27,430
+اتعلمناها وقرأناها وحافظناها فلما ابتعدوا عن هذا
+
+288
+00:25:27,430 --> 00:25:32,670
+الكتاب وعن هذه السنة ماكانت هذه الدافعية الموجودة
+
+289
+00:25:32,670 --> 00:25:37,070
+عندهم اللي كانت في الأول تدفعهم إلى هذه العلمة
+
+290
+00:25:37,070 --> 00:25:43,070
+السبب الثاني من الأسباب انصرف حكامهم إلى شهواتهم
+
+291
+00:25:43,070 --> 00:25:46,570
+ومصالحهم الشخصية هذا كمان برك الله فيه يعني سبب
+
+292
+00:25:46,570 --> 00:25:52,450
+وجهه هو مهم ان الحاكم هو القدوة والحاكم هو يعني
+
+293
+00:25:52,450 --> 00:25:57,630
+ولي الأمر والحاكم هو الذي بيده الأموروإن الله يزعب
+
+294
+00:25:57,630 --> 00:26:01,990
+السلطان لا يزعب القرآن لو كان الحاكم حاكما مسلما
+
+295
+00:26:01,990 --> 00:26:10,270
+حقا ومؤمنا حقا ويعني عادلا لقاد أمته وشعبه إلى
+
+296
+00:26:10,270 --> 00:26:15,890
+التقدم والتطور واستغال كل الإمكانيات والطاقات
+
+297
+00:26:15,890 --> 00:26:19,990
+والكفاءات الموجودة ومواد الخام والثروات الموجودة
+
+298
+00:26:19,990 --> 00:26:24,610
+في البلاد وصخرهافي خدمة الإسلام والمسلمين وتقدم
+
+299
+00:26:24,610 --> 00:26:27,590
+لكن ما كان فيه إرادة من هؤلاء الحكام على مر
+
+300
+00:26:27,590 --> 00:26:33,630
+التاريخ بعد فترة من الزمن وانشغل الحكام في مصالحهم
+
+301
+00:26:33,630 --> 00:26:37,390
+الشخصية وأهوائهم واتركوا يعني المصالح المسلمين
+
+302
+00:26:37,390 --> 00:26:41,010
+العام أيضا هؤلاء الحكام ما لهم
+
+303
+00:26:44,270 --> 00:26:47,370
+كانوا و لا يزالوا إلى وقت قريب حكام العرب
+
+304
+00:26:47,370 --> 00:26:51,150
+والمسلمين معروفين كانوا كلهم مرتبطين و مرتهنين
+
+305
+00:26:51,150 --> 00:26:57,370
+للسياسة الدولية والأوروبية والأجنبية والخارجية و
+
+306
+00:26:57,370 --> 00:27:02,850
+كأنهم يعملون وكلاء و أجراء و عملاء لمن؟ للغرب
+
+307
+00:27:02,850 --> 00:27:08,550
+والشرب و للكفار و لغير المسلمين حتى استيقظت شعوبهم
+
+308
+00:27:08,550 --> 00:27:13,970
+قريبافترة قريبة شاهدناها فيما عرف بالثورة العربية
+
+309
+00:27:13,970 --> 00:27:19,610
+والربيع العربي شعوبهم استيقظت ولفظتهم والباقية
+
+310
+00:27:19,610 --> 00:27:23,290
+تأتي والباقية على الطريق ان شاء الله مدام الحاكم
+
+311
+00:27:23,290 --> 00:27:30,150
+ظالم وعميل ووكيل للغرب والشرق والأجانب والغربيين
+
+312
+00:27:30,150 --> 00:27:35,910
+لن تقبل شعوبهم او لن يقبل شعبه بأن يحكمه ويستمر في
+
+313
+00:27:35,910 --> 00:27:42,710
+حكمهأيضًا نقطة الرابعة ولعلها يعني مهمة جدًا في
+
+314
+00:27:42,710 --> 00:27:46,950
+هذا المجال وهذا الاتجاه نناقش اليوم تعادل علماء
+
+315
+00:27:46,950 --> 00:27:50,370
+المسلمين عن الصباح التقري مجردا للواقع للواقع
+
+316
+00:27:50,370 --> 00:27:53,010
+المستحيلة تتوحى فيه معارفة بغضب باب الاجتهاد أيه
+
+317
+00:27:53,010 --> 00:27:53,530
+بمعنى؟
+
+318
+00:28:09,990 --> 00:28:16,070
+بارك الله فيك يا وحسنهذه القضية خواتب لعالها أهم
+
+319
+00:28:16,070 --> 00:28:21,150
+من أهم الأسباب بعد هذه الأسباب أو يعني مش قادرين
+
+320
+00:28:21,150 --> 00:28:25,010
+نميز و نقول هذه مهمة و أهم لأن كلها مهمة صحيح لكن
+
+321
+00:28:25,010 --> 00:28:31,230
+هذه إذا أرضناها يعني كسبب مباشر في تأخر عن التقدم
+
+322
+00:28:31,230 --> 00:28:37,850
+والتطور هو هذا الجمهور وهذا الوقوف عندما كان عليه
+
+323
+00:28:37,850 --> 00:28:42,230
+المسلمون وعدم الاجتهاد وفتح باب الاجتهاد وكأنه
+
+324
+00:28:42,230 --> 00:28:49,600
+يعني كل شيء جديد ممنون أو محرموبالتالي الغرب تقدم
+
+325
+00:28:49,600 --> 00:28:54,420
+والأوروبا تقدمت ونحن كل شيء جديد يعني نتحرج من
+
+326
+00:28:54,420 --> 00:28:58,580
+التعاطي معاه أو الدخول فيه والاقبال عليه كل اليوم
+
+327
+00:28:58,580 --> 00:29:04,420
+في ناس كثيرا ما يطلقوا يعني كلمة حق وليست لكنها
+
+328
+00:29:04,420 --> 00:29:08,880
+صحيحة ودقيقة يعني الحديث الشريف الصحيح كل بدعة
+
+329
+00:29:08,880 --> 00:29:12,300
+ضلالة وكل ضلالة في النار ويخاف من اقتحام أي شيء
+
+330
+00:29:12,300 --> 00:29:18,120
+جديد بحجة أنه بدعة ومحدثة وضلالة ولا يجوزوبالتالي
+
+331
+00:29:18,120 --> 00:29:22,060
+أغلق هذا الباب لأن هذا عالم متقدم ومتطور ويوجد
+
+332
+00:29:22,060 --> 00:29:26,670
+ثوابت صحيح ومبادئولا يمكن تجاوزها ولا يجوز تجاوزها
+
+333
+00:29:26,670 --> 00:29:29,610
+ولا اجتهادة فيها لا اجتهاد مع النص لكن في حياة
+
+334
+00:29:29,610 --> 00:29:34,110
+جديدة في عالم جديد لابد ان نواكبهم ونتطور معاهم في
+
+335
+00:29:34,110 --> 00:29:38,730
+علومنا المدنية مش نطور الدين عبنا على الاتجاه
+
+336
+00:29:38,730 --> 00:29:41,570
+التالت في مواقف المسلمين من الحضارة وهو تطوير
+
+337
+00:29:41,570 --> 00:29:45,210
+الدين لن نطور الدين نفسنا لكن نطور أنفسنا نطور
+
+338
+00:29:45,210 --> 00:29:52,140
+علومنا ونطور طريقة تعاملنا مع الواقع الجديديعني ما
+
+339
+00:29:52,140 --> 00:29:58,360
+نخاف من هذا الاقتحام لهذا العالم بل الناجح اليوم
+
+340
+00:29:58,360 --> 00:30:02,320
+هو الذي يقتحم هذه المجالات وفي آية في القرآن واضحة
+
+341
+00:30:02,320 --> 00:30:07,120
+وصريحة بتقولنا ادخلوا عليهم الباب فإذا دخلتموه
+
+342
+00:30:07,120 --> 00:30:15,320
+فإنكم غالبون قالها يعني بعض الجنود في عهدموسى عليه
+
+343
+00:30:15,320 --> 00:30:18,000
+السلام أو في عهد يوشع بن نون حينما دخلوا أرض
+
+344
+00:30:18,000 --> 00:30:21,480
+المقدسة وخافوا يدخلوها وكذا وفيها قوم جباري قالوا
+
+345
+00:30:21,480 --> 00:30:25,780
+لموسى ومن بعدها قال رجلان من الذين أنعم الله عليهم
+
+346
+00:30:25,780 --> 00:30:30,340
+ادخلوا عليهم الباب إذا دخلتموه فإنكم غالبون ممكن
+
+347
+00:30:30,340 --> 00:30:33,020
+نقوم هذه الآية أننا نقتحم هذا الباب و هذا المجال
+
+348
+00:30:34,060 --> 00:30:37,020
+يعني بعض الأشياء اللي يتشنج عندها البعض لانتخابات
+
+349
+00:30:37,020 --> 00:30:40,620
+حرام والمجلس الشورى حرام والبرلمان حرام والمش عارف
+
+350
+00:30:40,620 --> 00:30:44,460
+بيه حرام وهذا حرام والبنوك حرام والمش عارف .. هي
+
+351
+00:30:44,460 --> 00:30:48,140
+البنوك حرام مش البنوك اللي حرام المعاملة اللي داخل
+
+352
+00:30:48,140 --> 00:30:50,760
+البنوك الربوية الحرام .. ممكن احنا نعمل بنوك
+
+353
+00:30:50,760 --> 00:30:55,340
+واسلامية ونقول معاملات واسلامية يعني مش الاسم مش
+
+354
+00:30:55,340 --> 00:30:58,660
+اللفظ مش .. يعني ليس الوقوف عند الألفاظ والأشياء
+
+355
+00:30:59,370 --> 00:31:03,750
+يعني إنما الأشياء بغاياتها وأهدافها ومقاصدها يعني
+
+356
+00:31:03,750 --> 00:31:08,090
+حكم الوسائل هذه وحكم الغايات تبعتها إيش أنا غايتي
+
+357
+00:31:08,090 --> 00:31:11,310
+من هذه الوسيلة إذا هذه الوسيلة إذا غايتي منها
+
+358
+00:31:11,310 --> 00:31:17,250
+شريفة فتكون هذه الوسيلة يعني صحيحة وسليمة وحلالة
+
+359
+00:31:17,250 --> 00:31:20,790
+كالكمبيوتر اليوم والتلفزيون والدشات في أي وسيلة
+
+360
+00:31:20,790 --> 00:31:25,670
+حديثة حكمها حكم المقصد منهاإذا كان مقصدي هو النفع
+
+361
+00:31:25,670 --> 00:31:30,050
+والفائدة وكذا، يكون حكومها الحلال، إذا كان مقصدي
+
+362
+00:31:30,050 --> 00:31:34,910
+منها هو الدرر والفساد والشر والحرام واستغلاله، فهي
+
+363
+00:31:34,910 --> 00:31:39,290
+حرام، فهي وسيلة، حكومها حكم مين المقاصد، هذا الباب
+
+364
+00:31:39,290 --> 00:31:45,070
+والكلام في ذلك طويل وكبير سبب توقف وجمود وتخلف
+
+365
+00:31:45,070 --> 00:31:48,090
+العلوم نفسها، مش تخلف الإسلام ولا المسلمين ولا
+
+366
+00:31:48,090 --> 00:31:52,060
+العبارة اللي الكاتب بيستخدمها أو تأخرالعالم
+
+367
+00:31:52,060 --> 00:31:56,380
+الإسلامي عن غرقه تقدم و اقتحم و تجرأ و دخل كل هذه
+
+368
+00:31:56,380 --> 00:31:59,740
+المجالات و نجح و وصل و احنا كل شوية كنا خايفين و
+
+369
+00:31:59,740 --> 00:32:03,140
+مش قادرين و بلاش يكون و هذا يمكن حرام و يمكن حلال
+
+370
+00:32:03,140 --> 00:32:08,520
+و لا يعني ذلك أبدا التساهل لا يعني الكلام ولا في
+
+371
+00:32:08,520 --> 00:32:14,160
+لحظة كما قلنا أصول و قواعد بتحكمنا و ضوابط فيلابد
+
+372
+00:32:14,160 --> 00:32:18,200
+أن نقف عليه لكن في عالم جديد و في تطورلابد من
+
+373
+00:32:18,200 --> 00:32:22,200
+العلماء والفقهاء والمجداهدين أن يتداعوا ويجتمعوا
+
+374
+00:32:22,200 --> 00:32:27,160
+في كل جديد ويقولوا للمسلمين حكم الله في هذا الأمر
+
+375
+00:32:27,160 --> 00:32:32,240
+ويشجعهم على أي شيء جديد لا يتعارض مع الدين ومع
+
+376
+00:32:32,240 --> 00:32:35,900
+الإسلام الآن بدأ العالم الإسلامي والمسلمين
+
+377
+00:32:35,900 --> 00:32:40,580
+والعلماء يستيقظوا لذلك وفتح المسلمون على كثير من
+
+378
+00:32:40,580 --> 00:32:44,980
+الأشياء وربما بدأوا الآن يعيدوا دورهم ومجدهم الذي
+
+379
+00:32:44,980 --> 00:32:51,480
+كانوا عليهسابقا تمهيدا لالخلافة الراشدة التي بشر
+
+380
+00:32:51,480 --> 00:32:53,520
+فيها الرسول صلى الله عليه وسلم التي ستكون أخر
+
+381
+00:32:53,520 --> 00:32:56,780
+الزمان وستحكم العالم وتسيطر عليها لن نحكم العالم
+
+382
+00:32:56,780 --> 00:33:01,440
+ونحن يعني جاهلون بهذا المستوى الذي نحن عليه الغرب
+
+383
+00:33:01,440 --> 00:33:05,500
+وتقدم علينا وإحنا متأخرين نبدو أن نتقدم في جميع
+
+384
+00:33:05,500 --> 00:33:09,600
+المجالات اللي تقدم فيها الغرب ونمتلك كل الوسائل
+
+385
+00:33:09,600 --> 00:33:14,200
+اللي يمتلكها الغرب بل ونتوفق عليه ونمتلك كل القوة
+
+386
+00:33:14,200 --> 00:33:19,060
+لأن ربنا أمرنا بالإعدادما استطعنا .. قصدوا اعدوا
+
+387
+00:33:19,060 --> 00:33:22,260
+لهم ما استطعتهم من القوة و اعدوا لهم .. طب انهم
+
+388
+00:33:22,260 --> 00:33:26,080
+قوة كبيرة .. بدنا نعد نفس القوة إذا ما كانش أكتر
+
+389
+00:33:26,080 --> 00:33:30,360
+منها عشان نقدر نواجههم بكل الأسلحة و الوسائل اللي
+
+390
+00:33:30,360 --> 00:33:34,680
+هم يقاتلون و يقاومون فيه هذا هو الفهم السليم و
+
+391
+00:33:34,680 --> 00:33:38,300
+الصحيح للإسلام و لدور الإسلام و لعظمة الإسلام و
+
+392
+00:33:38,300 --> 00:33:43,040
+لأنه صالح لكل زمان و لكل مكان ليس متأخر ولا جامد
+
+393
+00:33:43,040 --> 00:33:48,040
+ولا قديم ولا رجعي ولا متخلفكما وصف من قبل أعداء
+
+394
+00:33:48,040 --> 00:33:51,380
+الإسلام من العلمانيين وأهل التغريب والمستشريقين
+
+395
+00:33:51,380 --> 00:33:55,240
+وغيرهم فوصفوا هذه الأوصاف فصار المسلمين يعني خلاص
+
+396
+00:33:55,240 --> 00:34:00,580
+كأنهم حسوا بالعقدة والذنب والتقصير وإنهم هم مش أهل
+
+397
+00:34:00,580 --> 00:34:04,680
+لهذه الحضارة والغرب والأجانب أفضل منهم واتقدموا
+
+398
+00:34:04,680 --> 00:34:10,120
+عنهموهذا ايه ليه؟ سبب يعني التأخير والتأخر اللي
+
+399
+00:34:10,120 --> 00:34:14,260
+نحن عليه وهذا ارتبط بسبب تالت وهو نهضة أوروبا
+
+400
+00:34:14,260 --> 00:34:19,820
+المادية كانت مع العلمانية فانبهر المسلمون والعالم
+
+401
+00:34:19,820 --> 00:34:23,540
+الإسلامي هذا الانبهار كيف تقدمت أوروبا و تطورت متى
+
+402
+00:34:23,540 --> 00:34:28,080
+تقدمت و متى تطورت؟ اه عندما فصلت و عزلت الدين و
+
+403
+00:34:28,080 --> 00:34:32,500
+أقصته عن الحياة لذلك المعادلة سهلة بما أنهذه
+
+404
+00:34:32,500 --> 00:34:36,480
+المعادلة، بما أن الغرب تقدم عندما فصل الدين عن
+
+405
+00:34:36,480 --> 00:34:41,640
+الدولة، إذن لكي نتقدم مثله، لابد أن نفصل الدين عن
+
+406
+00:34:41,640 --> 00:34:46,980
+الحيوانات، هذه نظرية، هذه حقيقة علمية، ولبس عليه
+
+407
+00:34:46,980 --> 00:34:51,000
+مش شيطان ذلك، وأوههم بذلك، واقتنعوا بذلك، وفكروا
+
+408
+00:34:51,000 --> 00:34:57,420
+حالهم، يعني على الصواب، وهممخطئون قل هانبئكم
+
+409
+00:34:57,420 --> 00:35:03,600
+بالاخسارين أعمالة الذين ضل سعيهم في الحياة الدنيا
+
+410
+00:35:03,600 --> 00:35:08,200
+وهم يحسبون أنهم يحسنون صناعة فكر حاله ماشي على
+
+411
+00:35:08,200 --> 00:35:11,360
+الصح هيك الصح ومش عارف حاله ماشي في طريق الضوال
+
+412
+00:35:11,360 --> 00:35:15,560
+والضياع والباطل والفساد والشرق إلى ما يفصل الدين
+
+413
+00:35:15,560 --> 00:35:20,060
+الشامل الكامل عن الحياة والسياسة والدولة وكذا ففكر
+
+414
+00:35:20,060 --> 00:35:26,720
+حاله هو هيك ماشي صحلكن القصة واضحة ومعروفة عند
+
+415
+00:35:26,720 --> 00:35:30,140
+الغرب وقلناها والان جت الملاحظة اللي قلناها في
+
+416
+00:35:30,140 --> 00:35:35,450
+الأول وقلناها هنعيدها وتتكرر معناها يعني الغربلما
+
+417
+00:35:35,450 --> 00:35:39,670
+تقدم بسبب فصله للدين عن الدولة كان ذلك الدين هو
+
+418
+00:35:39,670 --> 00:35:43,350
+الدين المحرف، الدين الباطل، فساد رجال الدين، الدين
+
+419
+00:35:43,350 --> 00:35:47,630
+اللي وقف ضد العلم، الدين اللي كذا، مش الدين، الحق،
+
+420
+00:35:47,630 --> 00:35:52,650
+الإسلام اللي يشجع ويحرب على العلم، فإذا كان لهم
+
+421
+00:35:52,650 --> 00:35:57,510
+مبررهم، فنحن كمسلمين ليس لنا هذا المبرر
+
+422
+00:36:00,470 --> 00:36:04,010
+فيه هنا نقطة ينبغي أن نصححها حتى في هذا المجال
+
+423
+00:36:04,010 --> 00:36:08,970
+وهذا الجانب هذا كلام سبب سبب واحد ربما سبب خاطئ
+
+424
+00:36:08,970 --> 00:36:14,450
+كمان جوليان أحدث هذا الأمر شعورا بأن التقدم العلمي
+
+425
+00:36:14,450 --> 00:36:19,610
+مرتبط بإقصاء الدين هيك صار في روع وفي نفس المسلمين
+
+426
+00:36:19,610 --> 00:36:25,970
+وهذا خطأ يعني مش يعني أوروبا لم تتقدم بسبب أنها
+
+427
+00:36:25,970 --> 00:36:31,190
+فصلت وعزلت الدينوإن كان هذا ربما سبب هامشي جانبي،
+
+428
+00:36:31,190 --> 00:36:35,650
+مساعد، لكن هل فقط مجرد أن تركت الدين يعني تقدمت؟
+
+429
+00:36:35,650 --> 00:36:39,350
+لأ، يعني العلم ليس له علاقة أن نترك الدين أو لا،
+
+430
+00:36:39,350 --> 00:36:42,890
+العلم general، عام، مش علاقة بالدين أو عدم الدين،
+
+431
+00:36:42,890 --> 00:36:47,030
+تتقدم في العلوم، ناخد بالأسباب، كذا، نصل، يعني في
+
+432
+00:36:47,030 --> 00:36:50,890
+أسباب موضوع أي علم، هذا الدين كان يقيد، كان ينع،
+
+433
+00:36:50,890 --> 00:36:54,770
+كان كذا، لكن التقدم نفسه، التطور نفسه، مش مرتبط
+
+434
+00:36:54,770 --> 00:36:58,280
+بالناخد بالدين ولا مناخدش،يعني ده سبب و عامل و
+
+435
+00:36:58,280 --> 00:37:03,020
+مساعد و .. و .. لكنه ليس هو السبب اللي جعل أوروبا
+
+436
+00:37:03,020 --> 00:37:07,920
+اليوم على ما هي عليه السبب يرجع إلى إيش الحقيقة؟
+
+437
+00:37:07,920 --> 00:37:12,040
+حقيقة هذا التقدم اللي شهدته أوروبا؟ متى بدأ؟ و كيف
+
+438
+00:37:12,040 --> 00:37:17,300
+نؤصل له؟ و كيف هم بعد ذلك أكملوا؟ إيش القصة؟ و إيش
+
+439
+00:37:17,300 --> 00:37:21,300
+الحقيقة؟ مين توضح ليها يا أخوات؟ فضلأوروبا بدأت
+
+440
+00:37:21,300 --> 00:37:24,000
+تلهم بعض احتكاكها بالمسلمين في الحروب الصليبية
+
+441
+00:37:24,000 --> 00:37:27,260
+واتصالها بمركز العلم والثقافة في الأندلس والشمال
+
+442
+00:37:27,260 --> 00:37:30,080
+والإفريقية بارك الله فيك و أحسن هذه القضية وهذه
+
+443
+00:37:30,080 --> 00:37:33,900
+الحقيقة وهذه الأساس هذه أساس القصة هذه قصة الحضارة
+
+444
+00:37:33,900 --> 00:37:39,660
+الغربية الأوروبية وهم يعترفون بذلك واحنا كمسلمين
+
+445
+00:37:39,660 --> 00:37:45,020
+لم نلتفت إلى ذلك أو أغفلنا ذلك ربما عامدا أو قصدا
+
+446
+00:37:45,020 --> 00:37:48,980
+عند البعض عامدا وعند البعض يعني عن غير عامد أو
+
+447
+00:37:48,980 --> 00:37:53,330
+جاهدولازلت أوروبا كما كنا بتعترف بفضل علماء
+
+448
+00:37:53,330 --> 00:37:58,530
+المسلمين عليها حدثني صديق درس الهندسة في ألمانيا
+
+449
+00:37:58,530 --> 00:38:03,790
+في كليات الطب في ألمانيا اللي كان بتعلم فيها هناك
+
+450
+00:38:03,790 --> 00:38:09,710
+أو في نفس الجامعةفي صور لعلماء المسلمين القدامى
+
+451
+00:38:09,710 --> 00:38:13,550
+وبعض القاعات مسمى باسماء ابن سينة وابن النفيس وابن
+
+452
+00:38:13,550 --> 00:38:18,590
+الهيثا في ألمانيا أكثر الدول التقدمية أو تقدما في
+
+453
+00:38:18,590 --> 00:38:23,590
+الصناعة وعلوم كثيرة وفي العلم معروفة يعني كدولة
+
+454
+00:38:23,590 --> 00:38:28,590
+أوروبية متقدمة فيها انهضة فلازالوا بيعترفوا في هذا
+
+455
+00:38:28,590 --> 00:38:32,750
+الجوإذن هم بنوا هذه الحضارة التي هم عليها ..
+
+456
+00:38:32,750 --> 00:38:36,230
+يسمونها الحضارة أو المدنية أو التقدم على علوم
+
+457
+00:38:36,230 --> 00:38:41,710
+المسلم، من هنا بدأ الكلام وبهذا
+
+458
+00:38:41,710 --> 00:38:46,860
+الاتصالالدين الذي نبذته أوروبا و كذا كما قلنا كان
+
+459
+00:38:46,860 --> 00:38:50,760
+عامل مساعد فقط يعني و ليس هو العامل الأساسي هو
+
+460
+00:38:50,760 --> 00:38:54,620
+الأصدقاء حتى نقول أه هو الدين اللي كان كذا الدين
+
+461
+00:38:54,620 --> 00:38:58,400
+اللي بمنع أو مابمنعش مش الدين اللي بمنع أو مابمنعش
+
+462
+00:38:58,400 --> 00:39:04,450
+الدين يعني إذا كان باطلا و محرفا و ضد يمنعيمنع من
+
+463
+00:39:04,450 --> 00:39:08,990
+التقدم، لكنه ليس هو سبب التقدم، سبب التقدم هو هذا
+
+464
+00:39:08,990 --> 00:39:14,570
+السبب وهذا عامل من العوامل، عامل وليس سببا أصليا
+
+465
+00:39:14,570 --> 00:39:19,390
+ولا أساسيا في التقدم أو عدم التقدم، فهو دين
+
+466
+00:39:19,390 --> 00:39:23,870
+الخرافات، دين يعني يقف ضد العلم والعلماء والإسلام
+
+467
+00:39:24,390 --> 00:39:28,450
+كدين هو بريء من كل هذا أو من هذه الصورة القاتمة
+
+468
+00:39:28,450 --> 00:39:32,850
+لهذا الدين فلا مقارنة ولا وجه للمقارنة في المنطق
+
+469
+00:39:32,850 --> 00:39:39,500
+بيقولوا عنه أو بيسموه قياسمع الفارق بما أن إذا
+
+470
+00:39:39,500 --> 00:39:45,100
+نقيص قضية على قضية بقيص قضية على قضية مختلفة ماعلا
+
+471
+00:39:45,100 --> 00:39:49,940
+بينهم بما أن أوروبا تقدمت حينما تركت الدين إذا إذا
+
+472
+00:39:49,940 --> 00:39:53,080
+أردنا أن نتقدم فلابد أن نترك الدين أنت بتقارن دين
+
+473
+00:39:53,080 --> 00:39:57,840
+مع دين في قياس بتقيصه مع الفارق بين هذا الدين و
+
+474
+00:39:57,840 --> 00:40:01,420
+هذا الدين هل هذا الدين هو نفسه هذا الدين حتى نقول
+
+475
+00:40:01,420 --> 00:40:06,820
+إذا تركناسنتقدم هذا الواهم و هذا الخطأ الشائع اللي
+
+476
+00:40:06,820 --> 00:40:11,600
+فكروا هو بسببه فهذا دين باطل و محرف و هذا دين حق
+
+477
+00:40:11,600 --> 00:40:16,880
+لم يعني يحرف لأن ربنا سبحانه وتعالى لأن الله تعالى
+
+478
+00:40:16,880 --> 00:40:23,080
+قد تكفل بحفظ هذا الدين و بهذا القرآن العظيم إن نحن
+
+479
+00:40:23,080 --> 00:40:28,220
+نزلنا الذكرة وإن له لحافظه رابع هذه الأسباب يا
+
+480
+00:40:28,220 --> 00:40:37,380
+أخوات و آخرهاهو التخطيط الصليبي اليهودي وهو يعني
+
+481
+00:40:37,380 --> 00:40:43,240
+تخطيط ماكر وخبيث
+
+482
+00:40:43,240 --> 00:40:46,920
+وسبق الحديث عن دور اليهود ونشاط اليهود في
+
+483
+00:40:46,920 --> 00:40:52,400
+العلمانية فده التخطيط يعني انا اعتقد نرجع للعضلة
+
+484
+00:40:52,400 --> 00:41:01,300
+القادمة نقف عندهم لإنه بدهشرح أوضح خلنا نكتفي بهذا
+
+485
+00:41:01,300 --> 00:41:06,560
+القدر عشان و نواصل ان شاء الله في المحاضرة القادمة
+
+486
+00:41:06,560 --> 00:41:08,240
+ان شاء الله تعالى و الله يعطيكوا العفو
+
diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/PFmoVq1AgBc_raw.json b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/PFmoVq1AgBc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..b63a951704def373f0740011e0639384bea46900
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/PFmoVq1AgBc_raw.json
@@ -0,0 +1 @@
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لعقيدتنا السليمة الصافي عقيدة أهل السنة والجماعة الفرقة والطائفة الناجية بإذن الله تعالى", "tokens": [6027, 9566, 15040, 3555, 16070, 9566, 6027, 3555, 9307, 34683, 5016, 9381, 9957, 16095, 11331, 49975, 20193, 7251, 4587, 3615, 14407, 8978, 23758, 25124, 31747, 4032, 41185, 23758, 33962, 9566, 2288, 4032, 41185, 23758, 32748, 2288, 2288, 4032, 3224, 15730, 2423, 7649, 5016, 23557, 5172, 9673, 9778, 6027, 5172, 5296, 3615, 4587, 25708, 2655, 8315, 21136, 20292, 46007, 31767, 31845, 1829, 6225, 4587, 25708, 3660, 5551, 3224, 1211, 21136, 1863, 3660, 16070, 7435, 15042, 27884, 27188, 2288, 28671, 16070, 9566, 16373, 5172, 3660, 28239, 26108, 10632, 4724, 28814, 8848, 1863, 21984, 37279, 6027, 7578], "avg_logprob": -0.0884046080865358, "compression_ratio": 1.9774011299435028, "no_speech_prob": 5.364418029785156e-07, "words": [{"start": 2170.73, "end": 2172.25, "word": "الطلاب", "probability": 0.8531494140625}, {"start": 2172.25, "end": 2173.05, "word": " والطالبات", "probability": 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\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/QSnVmdG-xDg_raw.srt b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/QSnVmdG-xDg_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..55da770a1d0c62bab8120bef985de61e57401ca2
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/QSnVmdG-xDg_raw.srt
@@ -0,0 +1,1848 @@
+1
+00:00:21,310 --> 00:00:24,990
+الحمد لله يا رب العالمين والصلاة والسلام على أشرف
+
+2
+00:00:24,990 --> 00:00:30,430
+الخلق وسيد المرسلين وسيدنا محمد وعلى آله وصحبه
+
+3
+00:00:30,430 --> 00:00:34,950
+أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت
+
+4
+00:00:34,950 --> 00:00:39,970
+العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما
+
+5
+00:00:39,970 --> 00:00:46,550
+علمتنا وازدنا علمة آمين يا رب العالمين أما بعد كنا
+
+6
+00:00:46,550 --> 00:00:51,310
+نتحدث في المحاضرة الماضية يا أخوات عنثاني وسائل
+
+7
+00:00:51,310 --> 00:00:58,430
+التغريب اللي هو وسيلة القومية والوطنية يعني
+
+8
+00:00:58,430 --> 00:01:03,150
+الوطنية مضافة عن النسخة القديمة الحقنا بالقومية
+
+9
+00:01:03,150 --> 00:01:09,110
+الوطنية أيضا تكلمنا عن أساس وأصل فكرة القومية
+
+10
+00:01:09,110 --> 00:01:12,890
+وقلنا إنها فكرة في أساسها وأصلها موجودة كفكرة
+
+11
+00:01:12,890 --> 00:01:19,000
+وكمبّأ لكن كان اسمها مختلف كان يقال لهاالعصبية
+
+12
+00:01:19,000 --> 00:01:24,860
+القبالية لأ العصبية القبالية يعني هي أشهر اسمين
+
+13
+00:01:24,860 --> 00:01:30,880
+كان يتجمع العرب قديما على العصبية القبالية عصبية
+
+14
+00:01:30,880 --> 00:01:34,400
+القبالية كانوا يتبعوا القبيلة وينتموا إليها
+
+15
+00:01:34,400 --> 00:01:40,700
+وتعصبوا إليها ورأينا كيفحينما جاء الإسلام ألغى هذا
+
+16
+00:01:40,700 --> 00:01:46,100
+التعصب لهذه الجاهلية و للفكرة الجاهلية و هي
+
+17
+00:01:46,100 --> 00:01:51,860
+العصبية القبلية و حذر من الدعوة إليها ليس مننا من
+
+18
+00:01:51,860 --> 00:01:55,700
+دع إلى عصبية و ليس مننا من قاتل على عصبية و هكذا
+
+19
+00:01:55,700 --> 00:02:01,560
+يعني كان التحذيرات من الدعوة إلى العصبية و كيف في
+
+20
+00:02:01,560 --> 00:02:06,170
+عهد الخلفاء الراشدينأيضا ذابت هذه الفوارق و هذه
+
+21
+00:02:06,170 --> 00:02:10,490
+الأجناس و هذه العصبيات فكانت تشمل دولة الإسلام و
+
+22
+00:02:10,490 --> 00:02:14,630
+خلافة الإسلام كل الأجناس العرب و العجم و الفورس و
+
+23
+00:02:14,630 --> 00:02:21,810
+الأحباش و غيرهم ثم ظهرت دعوة الوطنية التي تحدثنا
+
+24
+00:02:21,810 --> 00:02:28,800
+عنهاوالهدف منها كان ودمج المسلمين في غيرهم من أمم
+
+25
+00:02:28,800 --> 00:02:36,320
+الكفر لأن الرابطة في الوطنية والانتماء والولاء كان
+
+26
+00:02:36,320 --> 00:02:43,500
+للأرض للوطن بغض النظر عن الدين لتميز للإسلام ولدين
+
+27
+00:02:43,500 --> 00:02:48,200
+الإسلام عن غيرهم من الأديان وبالتالي إلغاء هذا
+
+28
+00:02:48,200 --> 00:02:51,560
+الدين كرابطة وكاسرة
+
+29
+00:02:53,830 --> 00:03:00,650
+وقد وصلنا إلى تعريف القومية ومن ثم تعريف الوطنية
+
+30
+00:03:00,650 --> 00:03:05,290
+في محاضرتنا اليوم نتحدث عن تعريف القومية ثم تعريف
+
+31
+00:03:05,290 --> 00:03:11,190
+الوطنية ثم نتحدث عن نشأة القومية العربية يعني نشأة
+
+32
+00:03:11,190 --> 00:03:16,510
+القومية في أوروبا هذه مش هنتكلم عنهاو سنبدأ الحديث
+
+33
+00:03:16,510 --> 00:03:22,610
+في النشأة عن نشأة القومية العربي ولكن بعد التعرف
+
+34
+00:03:22,610 --> 00:03:27,730
+على معنى القومية و معنى الوطني فلو جئنا إلى كلمة
+
+35
+00:03:27,730 --> 00:03:35,390
+القومية وجئنا بأساسها في اللغة وأساس هذه الكلمة و
+
+36
+00:03:35,390 --> 00:03:40,430
+هذا المصطلح فنجد القومية نسبة إلى إيش في اللغة؟
+
+37
+00:03:48,630 --> 00:03:53,170
+القومية الى القوم ينسب القومية الى القوم بيضيفوا
+
+38
+00:03:53,170 --> 00:03:57,710
+إليها في النسب ياء النسب و تاء التقنية كمعظم أو
+
+39
+00:03:57,710 --> 00:04:01,990
+أغلب أو أكثر المصطلحات القومية العلمانية العطنية
+
+40
+00:04:01,990 --> 00:04:05,770
+البعثية الاشتراكية و هكذا تاء التقنية تأتي في
+
+41
+00:04:05,770 --> 00:04:12,610
+المصطلحات يعني لتجعلها مصطلحا بارزاهذه الكلمة و
+
+42
+00:04:12,610 --> 00:04:16,790
+هذا المصطلح في أصله و في أساسه هل عرف العرب قديما
+
+43
+00:04:16,790 --> 00:04:20,330
+سواء في الجاهلية او في عصر الإسلام عرفوا كلمة
+
+44
+00:04:20,330 --> 00:04:24,290
+القومية و ليش كان الإسم القديم كما قلنا المسمى
+
+45
+00:04:24,290 --> 00:04:30,030
+علها العصابية كما قلنا و القبالية لكن كلمة القومية
+
+46
+00:04:31,670 --> 00:04:37,810
+أصلها وأساسها غربي أجنبي ثم ترجم إلى ما يُعرف
+
+47
+00:04:37,810 --> 00:04:41,190
+بالقومية أو اصطلح عليه باللغة القومية فإيش هو
+
+48
+00:04:41,190 --> 00:04:45,410
+الإسم الأجنبي الغربي لهذا المصطلح لأنه جاينة هذا
+
+49
+00:04:45,410 --> 00:04:48,710
+الإسم وافد أو هذا المذهب و هذا المبدأ و هذا الفكر
+
+50
+00:04:48,710 --> 00:04:54,210
+وافد من الغرب فعند أهله وأصحابه يعرف ب nationalism
+
+51
+00:04:54,210 --> 00:04:59,980
+nationalism يعني القومية بالنسبة إلى القومهذا
+
+52
+00:04:59,980 --> 00:05:02,900
+المصطلح اللي احنا تكلمنا عنه في المصطلحات الأربع
+
+53
+00:05:02,900 --> 00:05:07,220
+المطلوب مننا نحفظها ومنها هذا المصطلح بعد
+
+54
+00:05:07,220 --> 00:05:11,700
+العلمانية secularism فهي كمان المصطلح الثاني
+
+55
+00:05:11,700 --> 00:05:15,880
+nationalism بمعنى القوم يعني كلهم أربع مصطلحات
+
+56
+00:05:15,880 --> 00:05:20,380
+اللي مطلوبة منهم هذا من حيث اللغة واصل الكلمة واصل
+
+57
+00:05:20,380 --> 00:05:24,980
+هذا المصطلحولكن من ناحية الاصطلاح، ماذا تعني كلمة
+
+58
+00:05:24,980 --> 00:05:29,540
+القومية حينما نتحدث عن مذهب القومي، عن مبدأ
+
+59
+00:05:29,540 --> 00:05:33,380
+القومي، عن فكر القومي، الفكر القومي، فهي طبعا أكثر
+
+60
+00:05:33,380 --> 00:05:37,040
+من تعريفين دهان، من هذه التعريفات واحدة، فضل أختي
+
+61
+00:05:37,040 --> 00:05:42,080
+لهنا، اقرأ، تعريف الأول هنا تعرف بأنها ذاكرة يشرب
+
+62
+00:05:42,080 --> 00:05:47,110
+فيها أبناء الأصل الواحد اللي عرقيالاصل او ابناء
+
+63
+00:05:47,110 --> 00:05:51,150
+الاصل العرقي الواحد هو ما يربمين بالقوم اللي منسوب
+
+64
+00:05:51,150 --> 00:05:56,610
+اليها القومية هم ابناء الاصل العرقي الواحد واللغة
+
+65
+00:05:56,610 --> 00:06:01,630
+الواحدة كمانإيش بيشعروا هدول في هذه الظاهرة؟ في
+
+66
+00:06:01,630 --> 00:06:06,790
+هذا المبدأ والمذهب؟ يشعروا بالولاء المشترك، إذاً
+
+67
+00:06:06,790 --> 00:06:11,870
+ولاهم بناء على مين؟ إنهم أبناء أصل واحد، يعني قوم
+
+68
+00:06:11,870 --> 00:06:16,170
+واحد، وأبناء لغة واحد، إذا ما الذي وحدهم وجمعهم
+
+69
+00:06:16,170 --> 00:06:20,210
+وجعلهم ينتمون وينتسبون إلى هذا المبدأ والفكر
+
+70
+00:06:20,210 --> 00:06:24,190
+والمذهب؟ هو أصلهم اللي يرقي الواحد، وأما لغتهم
+
+71
+00:06:24,190 --> 00:06:32,020
+واحد، فكل أصحاب أصل واحد ولغة واحدةلهم قومية مميزة
+
+72
+00:06:32,020 --> 00:06:37,660
+يعني تميزهم عن غيرهم من أهل اللغات الأخرى فالعرب
+
+73
+00:06:37,660 --> 00:06:42,880
+مثلا كأصحاب لغة عربية كأصحاب لغة واحدة يسموا
+
+74
+00:06:42,880 --> 00:06:52,920
+قوميتهم بالقومية العربية من يتكلم بالفارسية اللي
+
+75
+00:06:52,920 --> 00:06:59,700
+كانت زمان بالمجوسية او الفارسية اليومتسمى قوميتهم
+
+76
+00:06:59,700 --> 00:07:05,700
+بالقومية الفارسي الذي يتكلم باللغة مثلا التركية
+
+77
+00:07:05,700 --> 00:07:10,940
+اللي هي لغة الترك طبعا هنقلهم قومية خصصة انت عرف
+
+78
+00:07:10,940 --> 00:07:14,580
+عليها بعد قليل تتعرف بالقومية .. مين بتعرف اسمها؟
+
+79
+00:07:14,580 --> 00:07:19,440
+التورانية .. بالنسبالي ليش التورانية طيب؟ تورانشاه
+
+80
+00:07:19,440 --> 00:07:28,050
+.. مين تورانشاه ده؟أحد زعماهم اسمه طوران شاه اه
+
+81
+00:07:28,050 --> 00:07:32,910
+يعني مثلنا طور طور طوران مثلا طوران طوران شاه اه
+
+82
+00:07:32,910 --> 00:07:38,950
+مين بتعرف أساس الكلمة و اللفظة؟من ايش؟ لأ التتريك
+
+83
+00:07:38,950 --> 00:07:42,850
+من الأتراك، من تركيا، لكن هي عرفت واشتهرت القومية
+
+84
+00:07:42,850 --> 00:07:48,350
+التركية بالطورانية نسبة إلى جبل .. لأ جبل طوران،
+
+85
+00:07:48,350 --> 00:07:53,950
+تاك اسمه جبل طوران أو هضبة موجودة في تركيا يرجع
+
+86
+00:07:53,950 --> 00:07:57,030
+الأتراك أصولهم وجزورهم إليه، يقولوا احنا بنرجع في
+
+87
+00:07:57,030 --> 00:08:01,080
+أصولنا وجزورنا إلى هذه الهضبة أو هذا الجبلالكبير
+
+88
+00:08:01,080 --> 00:08:04,040
+يعني عشان ما نستغربش كلمة طب بالنسبة للعرب القومية
+
+89
+00:08:04,040 --> 00:08:07,160
+العربية طب ليش للأتراك مايقولوناش القومية التركية
+
+90
+00:08:07,160 --> 00:08:12,240
+فاستلحوه واشتهروه اشتهر لفه ومصطلح القومية
+
+91
+00:08:12,240 --> 00:08:19,000
+الطوراني يعني هاي تعريف او من التعريف او التعريفات
+
+92
+00:08:19,000 --> 00:08:23,940
+في تعريف اخر قريب منه لبعض العلماء الآخرين بإيش
+
+93
+00:08:23,940 --> 00:08:24,540
+بيعرف
+
+94
+00:08:39,280 --> 00:08:46,100
+هذا التصور أو هذه الظاهرة بتمجد جماعة محدودة من
+
+95
+00:08:46,100 --> 00:08:51,890
+الناس حددناها بمين؟يعني هنا اللفظ عام محدد مخصص
+
+96
+00:08:51,890 --> 00:08:55,930
+اكتر بابناء الاصل العرق الواحد اللغة الواحدة هنفيه
+
+97
+00:08:55,930 --> 00:09:00,110
+نوع من التخصيص والتعيين هنفيه نوع من إيش التعميم
+
+98
+00:09:00,110 --> 00:09:05,450
+يمجد جماعة محدودة من الناس يضمها إطار جغرافي ثابت
+
+99
+00:09:05,450 --> 00:09:11,330
+ويجمعها ترات مشترك محدد ليش لغة ولا لون ولا جنس
+
+100
+00:09:11,330 --> 00:09:16,590
+ولا عرق ولا سورة عامةوتنتمي إلى أصول عرقية وقت في
+
+101
+00:09:16,590 --> 00:09:20,770
+جزء كبير من التعريف الثاني قريب من التعريف الأول
+
+102
+00:09:20,770 --> 00:09:24,410
+فهذا يعني صحيح و هذا صحيح لو طلب مننا تعريف
+
+103
+00:09:24,410 --> 00:09:28,130
+القومية في الإصطلاع ممكن نعرف بهذا التعريف أو
+
+104
+00:09:28,130 --> 00:09:34,520
+بالثاني برك الله فيكأما الوطنية كمصطلح و لفظ برضه
+
+105
+00:09:34,520 --> 00:09:40,320
+زي ما عرفنا معنى القومية و أصلها فكلمة وطنية نسبة
+
+106
+00:09:40,320 --> 00:09:44,940
+إلى مين؟ الوطن، إذا لما نأتي إلى تعريفة بنقول هي
+
+107
+00:09:44,940 --> 00:09:51,480
+.. تفضّال يا أختي أبناء الوطن الواحد، أه هناك
+
+108
+00:09:51,480 --> 00:09:56,500
+أبناء إيش كان؟ الجنس العرقي الواحد أو الأصل العرقي
+
+109
+00:09:56,500 --> 00:10:00,700
+الواحد، أبناء الوطن، بس، أه، كاملة؟
+
+110
+00:10:04,240 --> 00:10:09,040
+أيا كانت أصولهم، بغض النظر الآن لأ يبحث عن الأصول
+
+111
+00:10:09,040 --> 00:10:13,720
+يعني زي ما في وين أبناء الأصل الواحد، لأ الآن يعني
+
+112
+00:10:13,720 --> 00:10:16,420
+مهما كانت أصولهم، المهم اللي بيجمعهم مين؟ أرض و
+
+113
+00:10:16,420 --> 00:10:20,560
+وطن واحد، أرض و وطن واحد
+
+114
+00:10:24,070 --> 00:10:28,850
+يبقى الولاء فيها في الوطنية لمي بيكون للأرض للوطن
+
+115
+00:10:28,850 --> 00:10:35,250
+وليس للأصل العرقي الواحد لللغة الواحدة هناك بيقول
+
+116
+00:10:35,250 --> 00:10:40,170
+حتى مهما تعددت أوطانه في القومية مهما تعددت أوطانه
+
+117
+00:10:40,170 --> 00:10:45,690
+إذا في في القومية أكثر من وطنأكثر من وطن فبيضم هذه
+
+118
+00:10:45,690 --> 00:10:50,450
+الأوطان المتعددة مصطلح القومية لإن أهل هذه الأوطان
+
+119
+00:10:50,450 --> 00:10:54,790
+المتعددة يجمعهم أصل عرقي واحد ولغة واحد
+
+120
+00:10:54,790 --> 00:10:59,610
+فالفلسطينيين والمصريين وطنهم فلسطين ووطنهم مصر
+
+121
+00:10:59,610 --> 00:11:03,590
+السوريين ووطنهم سوريا الأردنيين ووطنهم .. لكن
+
+122
+00:11:03,590 --> 00:11:07,890
+لغاتهم كلهمواحد العربية الأصل اللي يرقى الواحد عرب
+
+123
+00:11:07,890 --> 00:11:11,250
+فكله مدون الدعو إلى القومية العربية لكن كل واحد له
+
+124
+00:11:11,250 --> 00:11:15,110
+وطنه الخاص فالدعو إلى القومية لسه أشمل شوية الدعو
+
+125
+00:11:15,110 --> 00:11:19,630
+إلى الوطنية مجزقة أكتر وهذا كان هو الهدف من هذه
+
+126
+00:11:19,630 --> 00:11:24,270
+الدعوات بدل أن تكون الرابط والجامعة للمسلمين هي
+
+127
+00:11:24,270 --> 00:11:29,580
+الإسلام الذي يشمل كل من هو مسلم على وجه الأرضفهي
+
+128
+00:11:29,580 --> 00:11:33,020
+رابطة أوسع و أشمل بدنا نضيق هذه الرابطة فنجعل
+
+129
+00:11:33,020 --> 00:11:38,300
+العرب وحدهم في دائرة الفرس أو العجم وحدهم في دائرة
+
+130
+00:11:38,300 --> 00:11:41,480
+الأتراك وحدهم في دائرة إذا هذا إيش بيعمل؟ في
+
+131
+00:11:41,480 --> 00:11:44,680
+الدائرة الكبيرة بيزغرها طب كمان بدنا نزغرها كمان
+
+132
+00:11:44,680 --> 00:11:48,300
+شوية إيش نعمل؟ ندعو إلى الوطني، كل واحد حرف وطن،
+
+133
+00:11:48,300 --> 00:11:52,440
+مالوش دعوة في التاني ولا كذا، بنفرق وجزء المسلمين
+
+134
+00:11:52,440 --> 00:11:59,140
+بعضهم عن بعض هذه الفكرة الخبيثةالولاء في الدعوة
+
+135
+00:11:59,140 --> 00:12:03,080
+الوطنية هو للأرض فقط للوطن
+
+136
+00:12:06,530 --> 00:12:12,310
+كما قلنا قبل قليل في الحديث عن نشأة القومية سنعرض
+
+137
+00:12:12,310 --> 00:12:17,530
+عن نشأتها في أوروبا تخفيفا عنكم فمن يعني أرادت أن
+
+138
+00:12:17,530 --> 00:12:24,050
+تستفيد من موضوع النشأة في أوروبا فلترجع اليها يعني
+
+139
+00:12:24,050 --> 00:12:28,870
+و تقرأ قراءة احنا هنبدأ من الحديث عن نشأة القومية
+
+140
+00:12:29,720 --> 00:12:34,860
+العربي التي تهمنا و الحديث الأكبر سيكون عنها و قد
+
+141
+00:12:34,860 --> 00:12:39,980
+قلنا في أثناء تعريف القومية و أصل الكلمة أنها ليست
+
+142
+00:12:39,980 --> 00:12:44,100
+في الأصل هذه الفكرة ليست فكرة عربية بل هي فكرة ايش
+
+143
+00:12:44,100 --> 00:12:50,180
+غربي اجنبي وافدة اندخلت القومية من أوروبا من الغرب
+
+144
+00:12:50,180 --> 00:12:55,420
+إلى العالم العربي و ذلك في أواخر القرن التاسع عشر
+
+145
+00:12:56,270 --> 00:13:03,690
+طيب، نشأت القومية العربية تحت عوامل أو أدق تحت
+
+146
+00:13:03,690 --> 00:13:08,910
+تأثير عاملين عوامل يعني فيه أكثر من عامل ثلاثة في
+
+147
+00:13:08,910 --> 00:13:11,670
+أكثر لكن لما نقول عاملين بنحصرهم هم عاملين اللي
+
+148
+00:13:11,670 --> 00:13:17,010
+مذكورين انهم إيش هم هدول العاملين؟ ما هم العاملين
+
+149
+00:13:17,010 --> 00:13:21,910
+اللي نشأت تحت تأثيرهم القومية العربية؟
+
+150
+00:13:27,770 --> 00:13:29,870
+مجارات القومية الطورانية وردت على سياسة التدريج
+
+151
+00:13:29,870 --> 00:13:33,690
+التي تملأتها جماعة الابتحاد المتحدة بارك الله فيك
+
+152
+00:13:33,690 --> 00:13:37,710
+اول حاجة هي ايش؟ ايش مجارات القومية الطورانية؟
+
+153
+00:13:37,710 --> 00:13:42,750
+مجاراتها يعني تقليدها تقليدها مجاراتها يعني زي ما
+
+154
+00:13:42,750 --> 00:13:47,590
+هم عاملوا فنعمل ومحسن من مين؟ اه فمجارات القومية
+
+155
+00:13:47,590 --> 00:13:51,090
+الطورانية ايه هو مصطلح الطورانية ليه؟ قلناها قبل
+
+156
+00:13:51,090 --> 00:13:55,970
+قليل ونعني بالطورانيةاللي هي من التركية وردًا على
+
+157
+00:13:55,970 --> 00:14:00,970
+سياسة التتريك فالأتراك بيرجعوا في أصولهم إلى هذه
+
+158
+00:14:00,970 --> 00:14:06,330
+القومية التورانية اللي تحدثنا عنها قبل قليل فالعرب
+
+159
+00:14:06,330 --> 00:14:11,430
+حينما نشأت القومية العرب نشأت تحت هذا التأثيرتقليد
+
+160
+00:14:11,430 --> 00:14:15,930
+إلهم ومجارا إلهم كما دعوا إلى قوميتهم، برضه إحنا
+
+161
+00:14:15,930 --> 00:14:18,910
+إلنا قومين، يعني هم أشطر من مين؟ إذا إنهم إلهم
+
+162
+00:14:18,910 --> 00:14:21,710
+قومية، إحنا برضه إلنا قومية، فصارت الحكاية كأنه
+
+163
+00:14:21,710 --> 00:14:26,170
+إيش؟ ردت فعل، عشان هيك بقول وردًا، يعني وردت فعل
+
+164
+00:14:26,170 --> 00:14:32,250
+على سياسة التتريك اللي تبنتهاجماعة وحزب الاتحاد
+
+165
+00:14:32,250 --> 00:14:37,650
+والترقي الذي حكم تركيا بعد إلغائه واسقاطه للخلافة
+
+166
+00:14:37,650 --> 00:14:42,530
+الإسلامية العثمانية فمن اللي حكم بدل الخلافة
+
+167
+00:14:42,530 --> 00:14:46,370
+العثمانية اللي كانت تحكم المسلمين حكم حزب الاتحاد
+
+168
+00:14:46,370 --> 00:14:52,990
+والترقي بزعامة العلماني القومي الكبير مصطفى كمال
+
+169
+00:14:52,990 --> 00:14:56,230
+اتاترك اللي أخذناه كنموذج للعلمانية
+
+170
+00:14:58,810 --> 00:15:02,810
+وكان أكثر أعضاء هذه الجمعية و هذا الحزب مسمى
+
+171
+00:15:02,810 --> 00:15:07,950
+بالاتحاد والتراقي من اليهود تحديدا يهود اسمهم يهود
+
+172
+00:15:07,950 --> 00:15:12,770
+الدونمة في منطقة في تركيا يعني كان يتبعها ويرجع
+
+173
+00:15:12,770 --> 00:15:18,150
+اليها هؤلاء اليهود اللي يتسمون بيهود الدونمة مع ان
+
+174
+00:15:18,150 --> 00:15:23,070
+هو في التفاصيل يعني ان في كثير منهم ليسوايعني من
+
+175
+00:15:23,070 --> 00:15:26,370
+تركيا وإنما كانوا من خارج تركيا معناه الدعوة إلى
+
+176
+00:15:26,370 --> 00:15:29,810
+قومية معناه فيه أهداف أخرى مش المقصود هي القومية
+
+177
+00:15:29,810 --> 00:15:34,470
+في ذاتها المقصود هو يعني إلغاء الخلافة الإسلامية
+
+178
+00:15:34,470 --> 00:15:40,310
+وإلغاء الرابطة الإسلامية التي تربط المسلمين بعضهم
+
+179
+00:15:40,310 --> 00:15:44,090
+بعض فبدنا بدل هذه الرابطة الكبيرة والدائرة الكبيرة
+
+180
+00:15:44,090 --> 00:15:48,670
+الواسعة بدنا نزغرها ونديقها فندعو إلى القومية
+
+181
+00:15:51,440 --> 00:15:57,500
+ورفعوا الأتراك في أثناء تبنيهم للقومية التركية أو
+
+182
+00:15:57,500 --> 00:16:04,020
+الطورانية شعار كانوا في الجاهلية أو قبل الإسلام أو
+
+183
+00:16:04,020 --> 00:16:07,820
+يدخلوا في الإسلام يتبنوه وهو الذئب الأغبر هي كان
+
+184
+00:16:07,820 --> 00:16:14,180
+شعارهم وهو معبود الأتراك رمز لمعبود الأتراك قبل
+
+185
+00:16:14,180 --> 00:16:20,360
+اعتناقهم للإسلام وبدوأو بدأوا بفرض اللغة التركية و
+
+186
+00:16:20,360 --> 00:16:26,140
+سياسة التتريك على تركيا و محاربة اللغة العربية أو
+
+187
+00:16:26,140 --> 00:16:34,080
+أي لغة حتى أخرى غير اللغة التركية و بدأ عداء أصحاب
+
+188
+00:16:34,080 --> 00:16:40,300
+هذه القومية الطورانية للدولة العثمانية و لهذه
+
+189
+00:16:40,300 --> 00:16:46,300
+الرابطة الإسلامية بعد ألغائهم للخلافة الإسلامية
+
+190
+00:16:48,500 --> 00:16:53,560
+العامل الثاني من العوامل اه تفضلي استعارة الافكار
+
+191
+00:16:53,560 --> 00:16:57,140
+والنظم الغربية او تقليد القربي في إشعارات عصي
+
+192
+00:16:57,140 --> 00:17:02,660
+لغتهم الخاص استعارة الافكار والنظم الغربية اه
+
+193
+00:17:02,660 --> 00:17:06,620
+الافكار والنظم الغربية استعارة مقنية ولا استعارة
+
+194
+00:17:06,620 --> 00:17:12,640
+تصريحية تنتهي اه تنتهي المعنى استعارة ايش عن
+
+195
+00:17:12,640 --> 00:17:16,760
+استعارةاخد استيراد و احنا شاطرين في الاستيراد لكن
+
+196
+00:17:16,760 --> 00:17:22,080
+في التصدير اه افتح الله فكل حاجة ممكن نستوردها و
+
+197
+00:17:22,080 --> 00:17:28,220
+ناخدها من الغرب و نستقبلها و نجربها نجرب بضاعتهم و
+
+198
+00:17:28,220 --> 00:17:33,140
+كل ما يعني أنتجوا الغرب و للأسف الشديد أخدناه عنهم
+
+199
+00:17:33,140 --> 00:17:39,080
+كما قال طهر حسين بحلوه و مره خيره و شرهو أصبحنا
+
+200
+00:17:39,080 --> 00:17:44,520
+نجربها هذا المجرب و معظم الأشياء اللي بنجربها عنهم
+
+201
+00:17:44,520 --> 00:17:50,580
+يعني فات معادها أو فات وقتها و صلاحيتها و تخلى
+
+202
+00:17:50,580 --> 00:17:55,640
+عنها أهلها الذين نادوا بيها و تنادوا بيها و احنا
+
+203
+00:17:55,640 --> 00:18:05,520
+بدأنا لسه ناخدها من جديد عنهم فتوافق
+
+204
+00:18:06,920 --> 00:18:13,300
+الدعوة إلى القومية العربية وباقي القوميات توافق
+
+205
+00:18:13,300 --> 00:18:18,940
+ذلك معالدعوة إلى القومية في أوروبا أو تفوق أوروبا
+
+206
+00:18:18,940 --> 00:18:23,720
+فظن المسلمون أو العرب أن تفوق أوروبا كان نتيجة
+
+207
+00:18:23,720 --> 00:18:28,660
+لتبنيهم القومية كما يعني حصل لهم في قصة العلمانين
+
+208
+00:18:28,660 --> 00:18:33,020
+يقولون لك متى تقدموا وتفوقوا الغرب حينما تخلوا عن
+
+209
+00:18:33,020 --> 00:18:38,120
+الدين وتبنوا العلماء العلمانية فإذا حتى نسيرهم و
+
+210
+00:18:38,660 --> 00:18:44,860
+يعني نكون مثلهم في هذا التقوق وفي النهضة لابد أن
+
+211
+00:18:44,860 --> 00:18:49,420
+نفعل ما فعل، أن نترك الدين جانبا حتى نصل إلى ما
+
+212
+00:18:49,420 --> 00:18:54,990
+وصلوا إليه، هون كذلك في القومينفبدأ الحديث عن
+
+213
+00:18:54,990 --> 00:18:59,170
+القومية والدعوة إلى القومية وطبعا الغرب متابع
+
+214
+00:18:59,170 --> 00:19:04,010
+ومراقب لكل ما يحدث في بلاد المسلمين فانتهز الغرب
+
+215
+00:19:04,010 --> 00:19:08,430
+هذه الفرصة مادام في ناس قاعدة بتدعوا إلى هذا الأمر
+
+216
+00:19:08,430 --> 00:19:13,130
+اللذي يجزء المسلمين ويفرق وحدتهمأحنا معنيين بذلك
+
+217
+00:19:13,130 --> 00:19:18,370
+فانتهز الفرصة قادة الغرب السياسيون وخاصة بعد
+
+218
+00:19:18,370 --> 00:19:21,630
+انهيار الأمبراطورية العثمانية وما عادتش في قوة
+
+219
+00:19:21,630 --> 00:19:26,030
+بتمنع حد أن يتدخل في شؤون المسلمين بعد أن كان
+
+220
+00:19:26,030 --> 00:19:32,220
+سلطان ونفوذ الدولة العثمانية مانعالأي أحد من
+
+221
+00:19:32,220 --> 00:19:36,520
+التدخل في شؤون المسلمين فاحتضنوا هذه الفكرة وبدأوا
+
+222
+00:19:36,520 --> 00:19:43,340
+يغذونها ويدعمونها بكتاباتهم ومؤلفاتهم ومقالاتهم
+
+223
+00:19:43,340 --> 00:19:47,420
+ورحلاتهم وجولاتهم في المدن العربية الكبرى وبدأوا
+
+224
+00:19:47,420 --> 00:19:51,900
+يتصلون بقادة وزعماء كبار لهم تأثير ونفوذ في داخل
+
+225
+00:19:51,900 --> 00:19:59,660
+هذه البلدانفي تلك الفترة والحقبة من الزمن نشبت
+
+226
+00:19:59,660 --> 00:20:05,900
+الحرب العالمية الأولى اللي كانت سنة ماذا؟ من 1914
+
+227
+00:20:05,900 --> 00:20:14,180
+ل 1918 حوالي أربع سنوات تقريبا فكانت النتيجة طبعا
+
+228
+00:20:14,180 --> 00:20:19,600
+هزيمة تركيا وألمانيا وعلافهم عليها دنجلترا وفرنسا
+
+229
+00:20:19,600 --> 00:20:24,990
+وغيرها فبدأ من هنافرصة الانشقاق عن الدولة
+
+230
+00:20:24,990 --> 00:20:32,950
+العثمانية اللي أصبحت هزيلة و مريضة و سميت بالرجل
+
+231
+00:20:32,950 --> 00:20:37,350
+المريض و بدأوا يتقاسمون تركت الرجل المريض كما سموا
+
+232
+00:20:37,350 --> 00:20:43,230
+تركيا في ذلك الوقتفانتهزت كما قلنا قبل قليل الفرصة
+
+233
+00:20:43,230 --> 00:20:48,250
+الحلفاء أو الحلفاء الغربيون انتهزوا هذه الفرصة و
+
+234
+00:20:48,250 --> 00:20:52,470
+بدأوا يشجعوا القومية بكل أجناسها و أشكالها و
+
+235
+00:20:52,470 --> 00:21:00,630
+أنواعها في هنا مقال أو قول للورنس أحد القادة
+
+236
+00:21:00,630 --> 00:21:05,730
+البريطانيين المعروفين اللي كان يتمنى في يوم من
+
+237
+00:21:05,730 --> 00:21:11,300
+الأيام أنتذوب الرابطة الدينية والإسلامية عن
+
+238
+00:21:11,300 --> 00:21:15,900
+المسلمين ويستبدلوا بدلا عنها أو منها رابطة أخرى
+
+239
+00:21:15,900 --> 00:21:19,680
+فقال كلاما مين تقرألنا كلامه اللي قاله في هذا
+
+240
+00:21:19,680 --> 00:21:23,120
+السياق اتفضل يعني واخدت طول الطريق وفكر .. طبعا في
+
+241
+00:21:23,120 --> 00:21:26,740
+كلام طويل احنا اختصرناه يعني اخدنا اللي بدنا ايه
+
+242
+00:21:26,740 --> 00:21:30,800
+منه واخدته واخدت طول الطريق وفكر واتسأل هل تتغلب
+
+243
+00:21:30,800 --> 00:21:34,070
+القوم يادات يوم على النزعة الدينية؟واضح يا أخوات
+
+244
+00:21:34,070 --> 00:21:38,370
+السؤال واضح التخطيط كان يفكر و يخطط و يقول هل
+
+245
+00:21:38,370 --> 00:21:44,110
+سيأتي يوم من الأيام لتتغلب القومية على النزعة
+
+246
+00:21:44,110 --> 00:21:48,010
+الدينية بدل ما يكون النزعة عند المسلمين هي النزعة
+
+247
+00:21:48,010 --> 00:21:51,630
+الدينية و يفكروا في دينهم و الذي يربطهم و يجمعهم
+
+248
+00:21:51,630 --> 00:21:56,130
+في هذه الدائرة الواسعة هل سيتخلى المسلمون في يوم
+
+249
+00:21:56,130 --> 00:22:00,830
+من الأيام عن هذا أو هذه الدائرة الكبيرةوينشغلوا
+
+250
+00:22:00,830 --> 00:22:05,670
+بدوائر صغيرة مهما كانت هذه الدوائر ستكون ضعيفة
+
+251
+00:22:05,670 --> 00:22:10,190
+بالنسبة للدائرة الأوسع والأكبر الدائرة الإسلامية
+
+252
+00:22:10,190 --> 00:22:15,350
+هذا يعني المخطط الخبيث اللي كان يشغل بال هؤلاء
+
+253
+00:22:15,350 --> 00:22:20,950
+القادة والزعماء الأوروبيين والغربيين في ذلك الوقت
+
+254
+00:22:20,950 --> 00:22:27,050
+ووعد الغربواللي درست فيكوا تاريخ بتعرفوا هذه
+
+255
+00:22:27,050 --> 00:22:30,330
+المعلومات اللي هنقولها وربما أصبحت من الوضوح بما
+
+256
+00:22:30,330 --> 00:22:35,210
+كان عند كثير من المثقفين والمتعلمين ان الغرب وعد
+
+257
+00:22:35,210 --> 00:22:40,030
+الشريف حسين في ذلك الوقت كان أميرا للهجاز وعده
+
+258
+00:22:40,030 --> 00:22:46,670
+بالحرية والاستقلال وأن يكون أميرا على العرب كلهم
+
+259
+00:22:46,670 --> 00:22:51,680
+قالوا ايش رأيك يا أمير؟يا شريف حسين بدل أن تكون
+
+260
+00:22:51,680 --> 00:22:56,480
+فقط والي و أمير على الحجاز و هي منطقة صغيرة بدنا
+
+261
+00:22:56,480 --> 00:23:03,270
+نكبرك و نخليك أمير على العرب كلهطبعا ده حلو يراود
+
+262
+00:23:03,270 --> 00:23:08,530
+أي زعيم أو يعني ملك أو حاكم أو قائد بدل ما يكون
+
+263
+00:23:08,530 --> 00:23:12,810
+حاكم على قطعة صغيرة من الأرض بده يحكم قطعة كبيرة و
+
+264
+00:23:12,810 --> 00:23:20,450
+يكون يعني حاكم على أكبر قدر من المساحة والأرض
+
+265
+00:23:20,450 --> 00:23:22,250
+فوعدوا
+
+266
+00:23:23,480 --> 00:23:29,800
+والاصل اللي بيوعد بيوفي بواعده فلم يوفوا بواعدهم
+
+267
+00:23:29,800 --> 00:23:34,980
+ولا بعهدهم وعدت بريطانيا اليهود وعدت بال 4 سنة
+
+268
+00:23:34,980 --> 00:23:40,240
+1917 بأن يكون هناك وطن قومي لليهود في فلسطين و
+
+269
+00:23:40,240 --> 00:23:46,780
+اوفوا بالوعد كانوا اوفياء في وعدهم اليهود ولكن
+
+270
+00:23:46,780 --> 00:23:51,300
+حينما وعدوا الشريف حسين ما الذي حدثنقضوا عهدهم
+
+271
+00:23:51,300 --> 00:23:57,240
+ونكثوا عهدهم كعادتهم مع المسلمين أو كل ما عهدوا
+
+272
+00:23:57,240 --> 00:24:01,160
+عهدا نبذوا فريق منهم اليهود والنصارى وغيرهم لا
+
+273
+00:24:01,160 --> 00:24:05,860
+يرقبون في مؤمن إلا و لا ذما لذما العهد لا يعرفوا
+
+274
+00:24:05,860 --> 00:24:09,720
+عهد ولا يرقبوا عهد ولا يتبعون عهد لأنهم يعني
+
+275
+00:24:09,720 --> 00:24:14,420
+ينقضون الميثاق نقضوا ميثاق أنبياءهم وعهود أنبياءهم
+
+276
+00:24:14,420 --> 00:24:20,360
+فكيف لا ينقضوا العهود مع المسلمين من باب أولىففي
+
+277
+00:24:20,360 --> 00:24:25,100
+ذلك الوقت صار أهل الحجاز ضد الأتراك لأنه كانوا
+
+278
+00:24:25,100 --> 00:24:29,980
+بيطمعوا أنه يكون الأمير عليهم أميرا على العرب كلهم
+
+279
+00:24:29,980 --> 00:24:32,880
+وصار أهل الشام في الشام أيضا كلهم صاروا على
+
+280
+00:24:32,880 --> 00:24:39,380
+الأتراك وفضلوا أن ينضموا إلى الكفار الحلفاء الكفار
+
+281
+00:24:39,380 --> 00:24:43,940
+على أن يبقوا في جوار الأتراك المسلمين في ذلك الوقت
+
+282
+00:24:43,940 --> 00:24:50,070
+طمعا في المنصب والدنيا والملك والسيادة والحكمعشان
+
+283
+00:24:50,070 --> 00:24:55,610
+الحكم والملكة وكذا تركوا المسلمين وانتماء إليهم
+
+284
+00:24:55,610 --> 00:25:04,800
+وانتموا ووالوا الكفار وبذلك بهذا الموقفاللي شرذم
+
+285
+00:25:04,800 --> 00:25:12,680
+وجزأ وفرق واضعف المسلمين وجعلهم ينهزمون أمام الغرب
+
+286
+00:25:12,680 --> 00:25:17,140
+وقعت بلاد المسلمين تحت سيطرات الاستعمار الغربي
+
+287
+00:25:17,140 --> 00:25:21,740
+والأوروبي وأيضا من المعروف تاريخيا جاءت فرنسا
+
+288
+00:25:21,740 --> 00:25:25,300
+وبريطانيا بعد انتهاء الحرب العالمية الأولى وشملت
+
+289
+00:25:26,070 --> 00:25:31,870
+تقاسمت وقسمت البلاد العربية فيما بينها فيما عرف
+
+290
+00:25:31,870 --> 00:25:39,670
+باتفاقية Psychos Pico المشهورة سيئة الذكر والسمعة
+
+291
+00:25:42,340 --> 00:25:47,340
+وهذه البلاد لبريطانيا وهذه البلاد لفرنسا وهذه
+
+292
+00:25:47,340 --> 00:25:51,400
+لإيطاليا وهذه معروفة وقعت مصر او كانت مصر من نصيب
+
+293
+00:25:51,400 --> 00:26:00,370
+مين الاحتلال البريطاني وكذلك العراقفلسطين كان في
+
+294
+00:26:00,370 --> 00:26:06,410
+امتداب ووقعت السوريا و لبنان و المغرب العربي و
+
+295
+00:26:06,410 --> 00:26:12,230
+تونس و الجزائر تحت الاحتلال الفرنسي و ليبيا تحت
+
+296
+00:26:12,230 --> 00:26:17,650
+الاحتلال الايطالي في ذلك الوقت قاصم هذه البلاد
+
+297
+00:26:17,650 --> 00:26:18,390
+الإسلامية
+
+298
+00:26:21,590 --> 00:26:26,170
+هذه الدعوة يا أخوات التي نحن بصددها و لازلنا في
+
+299
+00:26:26,170 --> 00:26:31,850
+الحديث عنها و هي الدعوة إلى القومية مدام فكرة ليست
+
+300
+00:26:31,850 --> 00:26:36,450
+إسلامية و فكرة وافدة و فكرة غربية و أجنبية ..
+
+301
+00:26:36,450 --> 00:26:42,560
+أوروبيةو ليست في مصلحة المسلمين لأنها تفرق في ما
+
+302
+00:26:42,560 --> 00:26:46,980
+بينهم وتجزئهم بدل أن يكونوا واحدة واحدة انما
+
+303
+00:26:46,980 --> 00:26:51,720
+المؤمنون اخو مسلم اخو مسلم صار العرب لوحدهم لوحدهم
+
+304
+00:26:51,720 --> 00:26:59,920
+و الفرص لوحدهم و كل جنس يعني لوحده هذا كان من
+
+305
+00:26:59,920 --> 00:27:04,770
+مصلحة منالمصلحة مين هذا؟ في العالم العربي
+
+306
+00:27:04,770 --> 00:27:09,610
+والإسلامي مصلحة النصارى المسيحيين هذا من مصلحتهم
+
+307
+00:27:09,610 --> 00:27:15,550
+ولذلك كان لهم دورا خبيثا واساسيا في الدعوة إلى
+
+308
+00:27:15,550 --> 00:27:22,170
+القومين وهم كانوا ورا هذه الدعوة من أول نشأتها هم
+
+309
+00:27:22,170 --> 00:27:29,930
+الذين رعوها واهتموا بهاوغذوها وتبنوها ونشروها وبعد
+
+310
+00:27:29,930 --> 00:27:34,750
+ذلك جاء من أبناء المسلمين من تبعهم في ذلك لكن
+
+311
+00:27:34,750 --> 00:27:42,490
+الفضل لهؤلاء في هذه الدعوة حسب يعني التاريخ ما
+
+312
+00:27:42,490 --> 00:27:48,990
+يذكر والباحثون أجمع الباحثون يعني اجمع ان الكثرة
+
+313
+00:27:48,990 --> 00:27:53,390
+من الرعيل الأول في الحركة القومية كانوا من أبناء
+
+314
+00:27:53,390 --> 00:27:59,410
+منالنصارى وبالأخص لبنان وسوريا تحديدا يعني لأن
+
+315
+00:27:59,410 --> 00:28:04,190
+فيها نسبة نصارى أكتر من غيرها من البلدان وكان فيها
+
+316
+00:28:04,190 --> 00:28:08,250
+يعني تلقف لهذه الدعوة وكان فيها أيضا ظروف أخرى كان
+
+317
+00:28:08,250 --> 00:28:12,170
+الإرساليات التبشيرية الفرنسية والأمريكية يعني
+
+318
+00:28:12,170 --> 00:28:17,330
+موجودة كثيرا في هذه البلاد واتصلوا بهذه الشخصيات
+
+319
+00:28:17,330 --> 00:28:22,340
+النصرانية والمسيحية المذكورة أمامنا أسماهممثل بطرس
+
+320
+00:28:22,340 --> 00:28:26,340
+البستاني و فارس الشدياق و أديب إسحاق و غيرهم لو
+
+321
+00:28:26,340 --> 00:28:31,800
+ركزنا شوية في أسمائهم بنلاحظ أسمائهم من الإسم يعني
+
+322
+00:28:31,800 --> 00:28:36,280
+إجرال مكتوب من عنوانه فالاسم بدول عصاه يعني اسم
+
+323
+00:28:36,280 --> 00:28:43,180
+بطرس و إسحاق و سليم يعني يمكن سليم شويةو تقلى و
+
+324
+00:28:43,180 --> 00:28:47,680
+جورجي و جورج و جورجي كمان في جورج و في جورجي هدول
+
+325
+00:28:47,680 --> 00:28:53,640
+يعني كلهم نصارى مسيحيين كانوا في لبنان تحديدا و
+
+326
+00:28:53,640 --> 00:28:56,740
+كانوا معروفين باتصالهم بالارساليات التبشرية اللى
+
+327
+00:28:56,740 --> 00:29:01,080
+تكلمنا عنها الفرنسية و الأمريكية و هذا الكلام ليس
+
+328
+00:29:01,080 --> 00:29:05,260
+زعما ولا افتراء ولا ادعاء هذا جاء في الموسوعة
+
+329
+00:29:05,260 --> 00:29:13,010
+العربىمنصوصا علي وموثق ان اول من دعا الى القومية
+
+330
+00:29:13,010 --> 00:29:20,470
+العربية هم الغربيونعلى أيدي بعثات التبشير في سوريا
+
+331
+00:29:20,470 --> 00:29:25,430
+ليفصلوا التركة عن العرب هذه كان الهدف يفصل الأتراك
+
+332
+00:29:25,430 --> 00:29:30,110
+عن العرب ميطلش المسلمين واحدة واحدة ويفرقوا بين
+
+333
+00:29:30,110 --> 00:29:36,110
+مين المسلمين ولم تزل الدعوة إليها في الشام والعراق
+
+334
+00:29:36,110 --> 00:29:42,650
+ولبنان الدعوة إلى القومية العربية وهناك اعترافات
+
+335
+00:29:43,400 --> 00:29:47,380
+يعني أكثر من ذلك في كتاب اسمه يقظة العرب لراجل
+
+336
+00:29:47,380 --> 00:29:54,420
+نصراني جورج أنطونيوس أيضا يرجع أول جهد منظم في
+
+337
+00:29:54,420 --> 00:30:00,480
+القومية إلى خمس شبان أو خمسة شبان درسوا في الكلية
+
+338
+00:30:00,480 --> 00:30:05,340
+البروتستانتانية ببيروت ومن اسمها وبرضه هذه الكلية
+
+339
+00:30:05,340 --> 00:30:09,820
+النصرانية البروتستانتانية احدى طواقف وفرق ومذاهب
+
+340
+00:30:09,820 --> 00:30:15,840
+النصارىو هذه الكلية تتبع الجامعة الأمريكية كون
+
+341
+00:30:15,840 --> 00:30:21,540
+هؤلاء الخمسة جمعية سرية و كانوا جميعا من النصارى
+
+342
+00:30:21,540 --> 00:30:26,460
+فالأول جهد منظم كان في حركة العرب القومية كان
+
+343
+00:30:26,460 --> 00:30:31,820
+لهؤلاء الخمسة من النصارى بما يؤكد هذه المعلومة و
+
+344
+00:30:31,820 --> 00:30:36,080
+هذه الفكرة أن أول من دعوا إلى القومية العربية
+
+345
+00:30:36,080 --> 00:30:40,120
+كانوا نصارى ولهم دور بارز و كبير فيها
+
+346
+00:30:45,250 --> 00:30:49,430
+بعد ذلك في أواخر القرن التاسع عشر أو بداية القرن
+
+347
+00:30:49,430 --> 00:30:55,230
+العشرين بدأت تظهر جمعيات قومية مش دينية ولا
+
+348
+00:30:55,230 --> 00:31:00,650
+اسلامية ولا كده تحمل هذا الاسموتركز عليه وتتبنى
+
+349
+00:31:00,650 --> 00:31:08,750
+اسم القومية وأغلب وأكثر الذين أسسوا هذه الجمعيات
+
+350
+00:31:08,750 --> 00:31:12,910
+كانوا برضه شخصيات نصرانية وفي عندى أسماء كثيرة
+
+351
+00:31:12,910 --> 00:31:18,030
+لجمعيات ومن أسسها جمعية السورية اللي أسسها بطرس
+
+352
+00:31:18,030 --> 00:31:22,250
+البستاني ونصيف اليازجي دول يعني نصار جمعية السورية
+
+353
+00:31:22,250 --> 00:31:25,290
+الجمعية العربية السورية جمعية رابطة الوطن العربي
+
+354
+00:31:25,290 --> 00:31:32,300
+كل هذه جمعياتقومية ومؤسسوها يعني واضح في أسمائهم
+
+355
+00:31:32,300 --> 00:31:37,570
+أو من أسمائهم أنهم نصارىبعد ذلك بدأ المسلمون
+
+356
+00:31:37,570 --> 00:31:42,330
+يدخلون على الخط زي ما أقول يعني بعد هذا التأسيس و
+
+357
+00:31:42,330 --> 00:31:45,470
+هذا الجهد المنظم من النصارى و إنشاء هذه الجمعية
+
+358
+00:31:45,470 --> 00:31:50,470
+بدوا المسلمين أو بعض المسلمين و أبناء المسلمين
+
+359
+00:31:50,470 --> 00:31:55,730
+يعني يقتنعوا و يعتنقوا هذا الفكر الجديد الفكر
+
+360
+00:31:55,730 --> 00:32:01,370
+القومية و دخلوا مع النصارى في ذلك
+
+361
+00:32:04,240 --> 00:32:09,490
+ثم ظهرت في العالم العربي حركات قوميةولها مؤسسون او
+
+362
+00:32:09,490 --> 00:32:19,210
+زعماء اشتهروا وكانوا رموزا لامعين في القومية وهذه
+
+363
+00:32:19,210 --> 00:32:23,230
+الأسماء اللي بنذكرها أسماء لامعة ومشهورة في تأسيس
+
+364
+00:32:23,230 --> 00:32:28,230
+القومية العربية وفي حركة البعث إذا بتسمع في حزب
+
+365
+00:32:28,230 --> 00:32:33,410
+البعث العربي الاشتراكي فكان من أهم وأبرز هؤلاء
+
+366
+00:32:33,410 --> 00:32:40,590
+ميشيل عفلقهذا الزعيم القومي و من اسمه ميشيل نصراني
+
+367
+00:32:40,590 --> 00:32:47,850
+في الأصل وهو دعا إلى القومية و أسس حزب البعث
+
+368
+00:32:47,850 --> 00:32:51,410
+العربي الاشتراكي يعني أضيف كلمة البعث كمان لأنه
+
+369
+00:32:51,410 --> 00:32:55,210
+شغر باسم البعث اللي حكم سوريا فترة طويلة ولا يزال
+
+370
+00:32:55,210 --> 00:33:00,760
+يحكمها كحزب سياسي يعني قوميو طبعا طائفته المعروفة
+
+371
+00:33:00,760 --> 00:33:05,560
+العلوية و المصيرية لكن اسم الحزب هو الحزب البعث و
+
+372
+00:33:05,560 --> 00:33:09,880
+اللي حكم العراق فترة طويلة في عهد صدام حسين أيضا
+
+373
+00:33:09,880 --> 00:33:16,420
+هذا الحزب أسسه هذا الرجل ميشيل عفلق و للتاريخ هذا
+
+374
+00:33:16,420 --> 00:33:23,000
+الرجل النصراني القومي في احدى المؤتمرات الصحفية له
+
+375
+00:33:23,000 --> 00:33:27,220
+و حدثني بذلك يعني الصديق كان يدرس في العراق في تلك
+
+376
+00:33:27,220 --> 00:33:33,980
+الفترةفكان له ابن اسمه محمد، فبيسأله في المؤتمر
+
+377
+00:33:33,980 --> 00:33:36,920
+الصحفي بعد ما خلص، بيقولوا يعني أنت إيه لك ابن
+
+378
+00:33:36,920 --> 00:33:40,320
+اسمه محمد و أنت يعني نصران و بتدعو إلى البعث و ..
+
+379
+00:33:40,320 --> 00:33:48,010
+فإيش القصة؟ فقال أنا معجب الزعيم العربي محمدكزعيم
+
+380
+00:33:48,010 --> 00:33:52,770
+عارف مش كنبي و رسول و كده انا معجب بيه فسميت واحد
+
+381
+00:33:52,770 --> 00:33:57,390
+من ولادي على اسمه هذا الراجل و حسب ما استمعته
+
+382
+00:33:57,390 --> 00:34:01,690
+بنفسي الى إذاعة مونتي كارلو قبل حوالي عشر و خمس
+
+383
+00:34:01,690 --> 00:34:09,480
+عشر سنة جابوا الخبر حينما توفي انه أسلمأسلم هذا
+
+384
+00:34:09,480 --> 00:34:14,420
+الرجل و كتم إسلامه ثلاث سنوات و أوصى أهله أن لا
+
+385
+00:34:14,420 --> 00:34:19,300
+ينشر خبر إسلامي إلا بعد أن يموت فبعد أن مات قالوا
+
+386
+00:34:19,300 --> 00:34:23,780
+هذا الخبر و يعني عطوله و وكالات الأنباء فنشروه أنه
+
+387
+00:34:23,780 --> 00:34:28,660
+كان قبل أن يموت بثلاث سنوات أعلن إسلامه يعني هذه
+
+388
+00:34:28,660 --> 00:34:33,280
+عبرة وعيظة كبيرة واحد زي هذا نصراني في الأصل قاد
+
+389
+00:34:33,280 --> 00:34:39,460
+الفكر القومي البعثيوفي النهاية يرجع إلى الحق ويسلم
+
+390
+00:34:39,460 --> 00:34:44,220
+معناه ذلك هذا الفكر كله فاشل وراصم إذا كان صاحبه
+
+391
+00:34:44,220 --> 00:34:50,960
+ومؤسسه اللي أصل له ونشره يعني يعلن إسلامه ودي قصص
+
+392
+00:34:50,960 --> 00:34:56,820
+كثيرة في إعلان إسلام كبارزعماء وقادة في أحزاب ..
+
+393
+00:34:56,820 --> 00:35:02,100
+وشوفنا ال .. روجي جارودي من كبار المستشرقين اللي
+
+394
+00:35:02,100 --> 00:35:07,940
+كان رئيس للحزب الاشتراكي او سكرتير الحزب الاشتراكي
+
+395
+00:35:07,940 --> 00:35:13,020
+الشيوعي الفرنسي نصران وشيوعي اصبح شيوعيا ثم درس
+
+396
+00:35:13,020 --> 00:35:17,620
+الإسلام واسلام والنماذج كثيرة كثيرة في هذا المجل
+
+397
+00:35:19,670 --> 00:35:23,990
+وفيه جورج حبش أو قبله أنطوان سعادة كان زعيما
+
+398
+00:35:23,990 --> 00:35:29,450
+للقوميين السوريين وجورج حبش في ذلك الوقت كان زعيما
+
+399
+00:35:29,450 --> 00:35:35,210
+للقوميين العرب هذه الحركة القومية التي تطورت
+
+400
+00:35:38,260 --> 00:35:42,660
+استبدلت بما يُعرف بالجبهة الشعبية لتحرير فلسطين
+
+401
+00:35:42,660 --> 00:35:46,580
+كانت الفكرة في البداية فكرة قومية ثم يعني بعد هيك
+
+402
+00:35:46,580 --> 00:35:52,460
+أصبحت فكرة وطنية لتحرير فلسطين وقسطنطين زرايق
+
+403
+00:35:52,460 --> 00:35:56,140
+زعيما للقومية وساطع الحسري كان رائدا ومفكرا
+
+404
+00:35:56,140 --> 00:36:01,780
+للقوميةالعربية هذه الأسماء اللامعة والرموز اللامعة
+
+405
+00:36:01,780 --> 00:36:11,820
+في الدنيا القومية يعني معروفة ومشهورة وبقيتالدعوة
+
+406
+00:36:11,820 --> 00:36:17,140
+إلى القومية العربية محصورة ضمن الأقليات الغير أو
+
+407
+00:36:17,140 --> 00:36:21,100
+غير المسلمة كان نصارى و بغيرهم لأنها من مصلحتهم لم
+
+408
+00:36:21,100 --> 00:36:24,660
+يكن الإسلام يحكمهم ولا يتحكم فيهم ولا يسيطر في
+
+409
+00:36:24,660 --> 00:36:29,780
+بلادهم فكانوا معنين بالدرجة الأولىإنه يقصوا حكم
+
+410
+00:36:29,780 --> 00:36:33,520
+الإسلام والرابط الإسلامية عشان ياخدوا حريتهم أكثر
+
+411
+00:36:33,520 --> 00:36:38,720
+ويكون لهم مالي المسلمين بالكامل مع أنهم أقلية في
+
+412
+00:36:38,720 --> 00:36:43,620
+كل المجتمعات الإسلامية فبقيت هذه الدعوة محصورة في
+
+413
+00:36:43,620 --> 00:36:48,320
+هذه الأقليات غير المسلمة وفي عدد محدود من أبناء
+
+414
+00:36:48,320 --> 00:36:51,280
+المسلمين اللي يدخلوا يدخلوا على خجل يعني أو على
+
+415
+00:36:51,280 --> 00:36:54,860
+استحياءلأنه يعني بيتعرض مع الفكرة الدينية
+
+416
+00:36:54,860 --> 00:36:58,980
+الإسلامية اللي تجعل المسلمين كلهم أخطر لماذا لأن
+
+417
+00:36:58,980 --> 00:37:03,380
+كلنا أخطر؟ لماذا فقط العرب؟ ولماذا كذا؟ ولماذا هذا
+
+418
+00:37:03,380 --> 00:37:09,080
+التجزيء؟ إلا أنه بدأ المسلمون يعني شيئا فشيئا
+
+419
+00:37:09,690 --> 00:37:13,390
+بالتدرج إلى أن أصبحوا أو خاضوا هذا التيار و هذه
+
+420
+00:37:13,390 --> 00:37:19,670
+الفكرة و هذا المبدأ و أصبحت القومية العربية تيارا
+
+421
+00:37:19,670 --> 00:37:25,090
+شعبيا تقوله المسلمون و غير المسلمين و ذلك حين
+
+422
+00:37:25,090 --> 00:37:29,730
+تبناها الرئيس المصري الراح الجمال عبد الناصر زعيم
+
+423
+00:37:29,730 --> 00:37:34,810
+القومية العربية اطلق عليه هذا اللفظ الزعيم القومي
+
+424
+00:37:34,810 --> 00:37:40,540
+زعيم القومية العربية بطل العروبةهذا أخذ هذه الشغرة
+
+425
+00:37:40,540 --> 00:37:45,020
+و هذا الإسم اللامع و اتبنى القومية العربية يعني
+
+426
+00:37:45,020 --> 00:37:49,700
+عدد كبير لبأس بيه من العرب و المسلمين حينما يعني
+
+427
+00:37:49,700 --> 00:37:55,620
+شجع عليها هذا الزعيم و هذا الرئيس عبد الناصر و صخر
+
+428
+00:37:55,620 --> 00:37:59,820
+له وسائل الإعلام و منهج التعليم و كذا و كان من
+
+429
+00:37:59,820 --> 00:38:07,080
+نتيجة هذه الفكرة و هذا الفكر و هذا المبدأ ماذايعني
+
+430
+00:38:07,080 --> 00:38:14,820
+جنى العرب من جراء القومية، ايش جنوا؟ هزيمة العرب
+
+431
+00:38:14,820 --> 00:38:19,640
+في عام 1967 كانت ضربة قاضية الحركة القومية دارك
+
+432
+00:38:19,640 --> 00:38:23,640
+الله فيك، إذا كانت في ضربة قاصدة هذه الحركة
+
+433
+00:38:23,640 --> 00:38:30,240
+باحتلال فلسطين وبهزيمة العرب عام 67 بعد ذلك جاء
+
+434
+00:38:30,240 --> 00:38:35,500
+مين؟الغزو الإسرائيلي لجنوب لبنان أو بيروت عفوا
+
+435
+00:38:35,500 --> 00:38:40,300
+وكانت في ضربة أخرى للقومية أين العرب؟ أين
+
+436
+00:38:40,300 --> 00:38:44,560
+القوميون؟ أين هذه الرابطة؟ هي دولة من دول العرب؟
+
+437
+00:38:44,560 --> 00:38:49,440
+أين أنتم يا قوميون؟ من تحرك لنصرة الشعب الفلسطيني؟
+
+438
+00:38:49,440 --> 00:38:52,040
+لا أحد سقطت القومية اللي كان يدعو عليها أولئك
+
+439
+00:38:52,040 --> 00:38:58,340
+الزعماء ثم تخلوا عن جزء من قوميتهم وهم الفلسطينيون
+
+440
+00:38:59,010 --> 00:39:03,150
+لأنه بيعتبرهم جزء من هذه القومية وكانوا يعني
+
+441
+00:39:03,150 --> 00:39:09,050
+بتشدقوا بالدعم للقضية الفلسطينية فإذ بهم يتخلون
+
+442
+00:39:09,050 --> 00:39:14,430
+ويقفون موقف المتفرج من غزو إسرائيل لبيروت عام 82 و
+
+443
+00:39:14,430 --> 00:39:19,930
+أكمل هذهالدائرة و هذا الفشل و هذه الهزيمة أيضا حرب
+
+444
+00:39:19,930 --> 00:39:25,210
+الخليج الأولى والثانية لتوجه اليها ضربة قاضية
+
+445
+00:39:25,210 --> 00:39:29,890
+ثانية أخيرة و حاسمة ولا أنتوا يعني .. يعني فكركم
+
+446
+00:39:29,890 --> 00:39:35,110
+لماذا في آخر حياة صدام حسين رفعالراية الإسلامية
+
+447
+00:39:35,110 --> 00:39:38,930
+ورفع شعار الله أكبر ورفع كذا بعد أن كان تبني
+
+448
+00:39:38,930 --> 00:39:42,830
+البعثية والقومية وكذا وجدت أن كل العرب تخلوا عنه
+
+449
+00:39:42,830 --> 00:39:47,130
+ومش حد واقف مع العراق وإلا مين المسلمين والجماعة
+
+450
+00:39:47,130 --> 00:39:50,130
+الإسلامية والتيارات الإسلامية حتى التهم في الآخر
+
+451
+00:39:50,130 --> 00:39:54,430
+أنه بيغذي الحركات الإرهابية والقاعدة وكذاليش؟ لأن
+
+452
+00:39:54,430 --> 00:39:58,930
+هؤلاء .. هذا الشعب .. هذا شعب مسلم فوقف معه يعني
+
+453
+00:39:58,930 --> 00:40:02,830
+كل المخلص و كل الحركات الجهادية و الإسلامية مع
+
+454
+00:40:02,830 --> 00:40:07,230
+الشعب العراقي في مهنته الأخيرة فعرفمن اللي على
+
+455
+00:40:07,230 --> 00:40:10,790
+الحق ومن اللي على الباطل وعرف الدعوة الصحيحة من
+
+456
+00:40:10,790 --> 00:40:15,990
+الدعوة الباطلة خاصة ان زعيم القومية و البعثية عنده
+
+457
+00:40:15,990 --> 00:40:18,450
+و هو موشيل عفلق لأنه كان في آخر حياته في العراق
+
+458
+00:40:18,450 --> 00:40:23,530
+أسلم فيعني تغير في آخر حياته كما يقول بعض الناس
+
+459
+00:40:23,530 --> 00:40:26,790
+القريبين منه اللي زاروا العراق أخيرا لأنه هذه
+
+460
+00:40:26,790 --> 00:40:32,920
+الدعوة فشلت وثبت فشل وانا اتوقف عند أهدافالفكرة
+
+461
+00:40:32,920 --> 00:40:37,660
+القومية وتصديرها إلى العالم الإسلامي في المحاضرة
+
+462
+00:40:37,660 --> 00:40:40,680
+القادمة ان شاء الله تعالى والله يعطيك العفو
+
diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/fTiOMvKkxWA_raw.srt b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/fTiOMvKkxWA_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..03f3ee89ea372866252d27906566b2053aad4fcd
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/fTiOMvKkxWA_raw.srt
@@ -0,0 +1,1900 @@
+1
+00:00:20,750 --> 00:00:24,070
+الحمد لله رب العالمين والصلاة والسلام على أشرف
+
+2
+00:00:24,070 --> 00:00:29,110
+الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحبه
+
+3
+00:00:29,110 --> 00:00:34,030
+أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت
+
+4
+00:00:34,030 --> 00:00:39,070
+العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما
+
+5
+00:00:39,070 --> 00:00:44,960
+علمتنا وازدنا علمة آمين يا رب العالمين أما بعدكنا
+
+6
+00:00:44,960 --> 00:00:48,720
+نتحدث يا أخوات في المحاضرة الماضية عن ثاني وسائل
+
+7
+00:00:48,720 --> 00:00:54,020
+التغريب وهي القومية والوطنية عرفنا فيها معنى
+
+8
+00:00:54,020 --> 00:00:58,640
+القومية وكذلك معنى الوطنية
+
+9
+00:00:59,750 --> 00:01:05,570
+وتحدثنا عن نشأة القومية العربية كيف بدأت والعوامل
+
+10
+00:01:05,570 --> 00:01:10,710
+اللي ساهمت في نشأة القومية العربية وكان على رأسها
+
+11
+00:01:10,710 --> 00:01:16,170
+عاملان أساسيا مين ذكرنا فقط بالعاملين اللي كان ورا
+
+12
+00:01:16,170 --> 00:01:19,730
+نشأة القومية العربية وان نشأة القومية العربية تحت
+
+13
+00:01:19,730 --> 00:01:25,110
+تأثير عاملين العامل الأول واحد مجرات القومية
+
+14
+00:01:25,110 --> 00:01:29,440
+القرانيةمجارات القومية الطورانية اللي هي التركية
+
+15
+00:01:29,440 --> 00:01:33,820
+هي واحد اتنين خلّي فرصة لغيرك نسمع من هنا من
+
+16
+00:01:33,820 --> 00:01:37,580
+الأخوات تفضل أخت اللي ورا استعارة الأفكار من نظم
+
+17
+00:01:37,580 --> 00:01:42,140
+الغربية ومحاولة تقليدها في بسائل نقضات غير غربية
+
+18
+00:01:42,460 --> 00:01:45,800
+استعارة الأفكار والمبادئ الغربية في كثير من
+
+19
+00:01:45,800 --> 00:01:51,920
+المبادئ والمذاهب اللي دخلت على عالمنا العربي
+
+20
+00:01:51,920 --> 00:01:57,740
+والإسلام هي مبادئ غربية ودخيلة فدخلت بطريق التأثر
+
+21
+00:01:57,740 --> 00:02:02,520
+بها واستعارتها وتجريبها في عالمنا العربي والإسلام
+
+22
+00:02:04,320 --> 00:02:10,840
+طب هذه الفكرة الوطنية المسمى بالوطنية لها أهداف من
+
+23
+00:02:10,840 --> 00:02:15,660
+تسويقها وتبنيها داخل العالم الإسلامي لماذا سوقوها
+
+24
+00:02:15,660 --> 00:02:20,860
+وجعلوا العالم الإسلامي والعربي يتبنها بديلا عن
+
+25
+00:02:20,860 --> 00:02:24,960
+الفكرة الإسلامية والمبدأ الإسلامي الذي يجمع
+
+26
+00:02:24,960 --> 00:02:30,400
+المسلمين كلهم في بوتقة واحدة وفيرابطة واحدة هي
+
+27
+00:02:30,400 --> 00:02:34,520
+رابطة العقيدة والإيمان، لماذا تصدير هذه الفكرة
+
+28
+00:02:34,520 --> 00:02:37,900
+الوطنية للعالم الإسلامي؟ هناك أهداف، في ثلاثة
+
+29
+00:02:37,900 --> 00:02:41,120
+أهداف مذكورة، بدنا نحاول نتناقش في هذه الأهداف
+
+30
+00:02:41,120 --> 00:02:45,580
+الثلاثة، أول هذه الأهداف من تصدير الفكرة الوطنية،
+
+31
+00:02:45,580 --> 00:02:49,960
+تفضليالجهاد الإسلامي هو استعمار الصليب و الصيوني
+
+32
+00:02:49,960 --> 00:02:53,360
+إلى حركات وطنية؟ بارك الله فيك، يعني بدل أن تكون
+
+33
+00:02:53,360 --> 00:02:58,780
+حركة الجهاد والمقاومة للمحتل والمستعمر حركة
+
+34
+00:02:58,780 --> 00:03:03,220
+إسلامية دينية نابعة من الإسلام والدين، بدنا نحولها
+
+35
+00:03:03,220 --> 00:03:08,260
+إلى حركة وطنية مجردة، مجرد أنه في ناس محتلين للأرض
+
+36
+00:03:08,260 --> 00:03:15,430
+فبدنا ندافع عن أرضنافولهم في ذلك يعني هدف بعيد،
+
+37
+00:03:15,430 --> 00:03:18,090
+إيش هو هذا الهدف؟ يعني ما الفرق بين أن تكون حركة
+
+38
+00:03:18,090 --> 00:03:23,410
+المقاومة أو الجهاد للمحتال دينية إسلامية و أن تكون
+
+39
+00:03:23,410 --> 00:03:26,690
+وطنية؟ ما الفرق؟ يعني إيش بيخلف الأمر؟ آه يا
+
+40
+00:03:26,690 --> 00:03:32,110
+أخوات، وين الفرق الدقيق بين الأمرين؟ تفضليأول شيء
+
+41
+00:03:32,110 --> 00:03:35,090
+لأن الحركة الوطنية لا تنظر إلى العدو على أنه صليبي
+
+42
+00:03:35,090 --> 00:03:38,810
+مستعمر أو صهيوني ذو جذور دينية في هجماته
+
+43
+00:03:38,810 --> 00:03:42,290
+الاستعمارية، ولكنها تنظر على أنه مستعمر فقط وأنه
+
+44
+00:03:42,290 --> 00:03:45,630
+جاء لاحتلال الأرض في حزبهبارك الله فيك، لا تنظروا
+
+45
+00:03:45,630 --> 00:03:50,150
+للنظرة الدينية التي يخفيها المستعمر وراها هو له
+
+46
+00:03:50,150 --> 00:03:54,690
+أهداف دينية جاء من أجلها ولا يزالون يقاتلونكم حتى
+
+47
+00:03:54,690 --> 00:03:58,610
+يردوكم عن دينكم إن استطاعوا يريدوا أن يقهروا
+
+48
+00:03:58,610 --> 00:04:02,910
+المسلمين يذلوا المسلمين يبعدوهم عن دينهم يدخلوا
+
+49
+00:04:02,910 --> 00:04:08,090
+أفكارهم الغربية والغريبة عن المسلمين فلو كان
+
+50
+00:04:08,090 --> 00:04:14,150
+الحركة وطنية ستقتصر عن الدفاع عن أرض عن وطنوربما
+
+51
+00:04:14,150 --> 00:04:22,070
+يعني تتراخى في ظل هذا الدفاع عن هذه الأرض إذا ما
+
+52
+00:04:22,070 --> 00:04:26,770
+وجدت أنها غير قادرة أو غير مكافئة لقتال العدو، لكن
+
+53
+00:04:26,770 --> 00:04:31,180
+المسلم يكون المقاتل واحدكان يقاتل بالفئة قليل كان
+
+54
+00:04:31,180 --> 00:04:34,680
+من فئة قليلة انغلبت فئة كثيرة باذن الله في عنده
+
+55
+00:04:34,680 --> 00:04:38,540
+عامل اخر غير الوطني فهو وطني وينتمي الى هذا الوطن
+
+56
+00:04:38,540 --> 00:04:44,240
+ويدافع عنه لكن في شيء زائد و هو دينه بيدعوه بيحثه
+
+57
+00:04:44,240 --> 00:04:49,000
+بيمنعه من ان يتراقى او يتقاس او يتراجع لأ بتظل
+
+58
+00:04:49,000 --> 00:04:53,060
+مستمر و بتظل قاوم عنده اخر نفس فيه هذا الفرق بين
+
+59
+00:04:53,060 --> 00:04:57,480
+من عنده الشعور الوطني فقطوهو ما عنده الشعور الديني
+
+60
+00:04:57,480 --> 00:05:02,560
+المتدفق المتحمس الذي يدفعه دائما وباستمرار إلى
+
+61
+00:05:02,560 --> 00:05:09,600
+الدوام على حركة الجهاد والمقاومة للعدو هذا النظرة
+
+62
+00:05:09,600 --> 00:05:13,860
+الدقيقة يعني اللي كان بينظرها الاستعمار عشان هيك
+
+63
+00:05:13,860 --> 00:05:17,840
+بده يحول هذه الحركات من حركات جهادية إلى حركات
+
+64
+00:05:17,840 --> 00:05:22,860
+وطنية هذا الهدف الأول في هدف أخر للمستعمر والمحتل
+
+65
+00:05:29,710 --> 00:05:35,630
+تحويل حركات الجهة للإسلام إلى حركات سياسية عن طريق
+
+66
+00:05:35,630 --> 00:05:39,080
+تحويلها إلى حركات دولة؟إذا هم بارك الله فيهم
+
+67
+00:05:39,080 --> 00:05:43,280
+بحركات الجهاد بدلا أن تكون مقاومة و بس ولا تفاوض
+
+68
+00:05:43,280 --> 00:05:48,760
+العدو بدها تتحول إلى حركة سياسية ممكن التفاوض معها
+
+69
+00:05:48,760 --> 00:05:53,120
+و ممكن إنها اتلين و ممكن إنها تتراجع و ممكن تكون
+
+70
+00:05:53,120 --> 00:05:57,880
+براجماتية تتخلع عن بعض المبادئ مقابل بعض المصالح
+
+71
+00:05:58,520 --> 00:06:03,780
+فحينما تتحول إلى حركات وطنية وحركات سياسية ايضا
+
+72
+00:06:03,780 --> 00:06:10,580
+بيتقل درجة عداءها للعدو ونظرتها للعدو فيما يُعرض
+
+73
+00:06:10,580 --> 00:06:15,640
+عليها من قضايا سياسية وممكن في الحالة دي يعني
+
+74
+00:06:15,640 --> 00:06:20,140
+التفاهم معها يكون أسهل مافيش عندها مبادئ تمنعها
+
+75
+00:06:20,140 --> 00:06:24,260
+انها تتفاوض او تتنازل او تتراجع ممكن تاخد اي حاجة
+
+76
+00:06:24,970 --> 00:06:32,990
+من حقوقه وتعترف للعدو بجزء من .. وجزء كبير من حقوق
+
+77
+00:06:32,990 --> 00:06:35,730
+المسلمين كما هي في الحالة الفلسطينية وغيرها من
+
+78
+00:06:35,730 --> 00:06:40,350
+الحالات في الحركات والجماعات الوطنية ممكن تعترف
+
+79
+00:06:40,350 --> 00:06:45,150
+واعترفت وأمر رسمي وليس سرا اعترفت بجزء كبير هذه
+
+80
+00:06:45,150 --> 00:06:51,020
+الحركات الوطنية اوجزء كبير منها بما يُعرف بدولة
+
+81
+00:06:51,020 --> 00:06:55,660
+إسرائيل التي اقتصبت فلسطين، هذه ليست دولة إسرائيل،
+
+82
+00:06:55,660 --> 00:07:00,200
+هذه فلسطين، هذه أراضي فلسطين احتلتها إسرائيل،
+
+83
+00:07:00,200 --> 00:07:04,040
+احتلتها اليهود، فإذا كنا نحن أصحاب القضية والأرض
+
+84
+00:07:04,610 --> 00:07:09,170
+نعترف لهم بشرعية احتلالهم، فهذا أمر مصيب، هذا لم
+
+85
+00:07:09,170 --> 00:07:14,490
+يفعله إلا من ينتسب إلى الوطنية أو كده، وقد فعله،
+
+86
+00:07:14,490 --> 00:07:18,430
+أما الحركات الإسلامية والجهادية لازالت مصرة على
+
+87
+00:07:18,430 --> 00:07:24,850
+موقفها، لن نعترف بإسرائيليعني هذا العنوان و هذا ال
+
+88
+00:07:24,850 --> 00:07:29,370
+.. ال .. هذه العبارة مش كلام أو فقط بل هو فعل و
+
+89
+00:07:29,370 --> 00:07:34,590
+فعل على الأرض و فعل مقاوم و جهاد هذا المسلم اللي
+
+90
+00:07:34,590 --> 00:07:38,030
+بينطلق من إسلامه و دينه لا يمكن أن يعترف للعدو أو
+
+91
+00:07:38,030 --> 00:07:43,990
+المحتل ب .. ب .. ب .. بجزء من أرضه ياخذها فضلا عن
+
+92
+00:07:44,940 --> 00:07:47,720
+نسبة كبيرة تمانية و سبعين في المية ماخد من أرض
+
+93
+00:07:47,720 --> 00:07:51,880
+فلسطين اعترف له بهذا الحق وهذا هو الفارق الواضح
+
+94
+00:07:51,880 --> 00:07:59,860
+بين الحركتين أو الاتجاهين الإسلامي و الوطن تلاتة
+
+95
+00:07:59,860 --> 00:08:06,080
+من الأهداف الوطنية فضل يا أخت تلاتة من الأهداف
+
+96
+00:08:06,080 --> 00:08:11,320
+الوطنية تلاتة من الأهداف الوطنيةبرضه هو في النهاية
+
+97
+00:08:11,320 --> 00:08:14,660
+هو تحويل الحركات وطنية، حركات سياسية ويلهم أهداف
+
+98
+00:08:14,660 --> 00:08:22,220
+منها منها تسهيل عملية التغريب في ظل حركات و جماعات
+
+99
+00:08:22,220 --> 00:08:29,570
+و أحزاب وطنية أو حتى قوميةسياسية يمكن التفاهم معها
+
+100
+00:08:29,570 --> 00:08:36,530
+وبسهولة هذه الغزو الفكري للبلاد التي تكون علاقة
+
+101
+00:08:36,530 --> 00:08:42,190
+بها تكون أسهل من حركات إسلامية أو جامعات محافظة
+
+102
+00:08:42,190 --> 00:08:47,110
+تحافظ على العقيدة وعلى الأخلاق وعلى السلوك وترفض
+
+103
+00:08:47,110 --> 00:08:53,460
+ولا تقبلأي وسيلة من وسائل التغريب سواء العلمانية
+
+104
+00:08:53,460 --> 00:08:58,520
+أو غيرها من هذه الدعاوى أما حركات وطنية فبتكون
+
+105
+00:08:58,520 --> 00:09:03,600
+يعني لا تشدد على القضية الدينية كثيرا وتسمح
+
+106
+00:09:03,600 --> 00:09:07,260
+بالحرية وبالعلمانية وهي في ذاتها أصلا حركات
+
+107
+00:09:07,260 --> 00:09:11,470
+علمانية يعني وهي التناقضيعني انت بتدعي مقاومة
+
+108
+00:09:11,470 --> 00:09:15,810
+المحتل والمستعمر والغاصب وال .. ما هو .. و ثم
+
+109
+00:09:15,810 --> 00:09:19,690
+تتبنى مين؟ تتبنى أفكار وقراءة هذه العلمانية التي
+
+110
+00:09:19,690 --> 00:09:24,590
+عليها الحركات الوطنية التي تجرّد نفسها من صفة
+
+111
+00:09:24,590 --> 00:09:29,690
+الإسلامية، مع أنهم مسلمين ولا يجوز تكفير أحد منهم،
+
+112
+00:09:29,690 --> 00:09:36,850
+لكنوهو وطني وبدو يقاوم و الوطنية اصلا من الغزو
+
+113
+00:09:36,850 --> 00:09:40,150
+الفكر و القومية من الغزو الفكر و بنستوردها منهم
+
+114
+00:09:40,150 --> 00:09:44,430
+كيف نقاومهم يعني بنفس الفكر تبعهم لابد من مقاومة
+
+115
+00:09:44,430 --> 00:09:49,330
+أفكارهم بأفكار مضادة هي أفكارنا و هي مبادئنا و هي
+
+116
+00:09:49,330 --> 00:09:52,630
+دين هم بحاربونا بعقيدة و بدين و بنطلقوا منه احنا
+
+117
+00:09:52,630 --> 00:09:56,710
+بنحاربهم بعقيدة و بدين و ننطلق منهولم نتغلب عليهم
+
+118
+00:09:56,710 --> 00:10:02,090
+إلا بهذا الأمر وهذا أيضا فارق ثالث ففي ظل حركات
+
+119
+00:10:02,090 --> 00:10:07,450
+وطنية سياسية بتسهل عملية التغريب لهؤلاء الناس ولا
+
+120
+00:10:07,450 --> 00:10:12,890
+يشعر أصحاب الفكر الوطني بأي غرابة في المجتمع اللي
+
+121
+00:10:12,890 --> 00:10:19,360
+بيكونوا فيه من هذا التغريبأما حين يتحول الجهاد إلى
+
+122
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+حركة وطنية سياسية فالحاجز بيكون أرق من الفكر
+
+123
+00:10:24,880 --> 00:10:31,460
+الإسلامي اللي بيكون مانع وحاجز للأفكار التغريبية
+
+124
+00:10:32,610 --> 00:10:36,850
+وفي أقوال وتصريحات
+
+125
+00:10:36,850 --> 00:10:42,470
+لبعض العلمانيين أو الوطنيين دعاة الوطنية بهذا
+
+126
+00:10:42,470 --> 00:10:47,930
+الأمر انه بتقبل فكر الغرب وفكر المحتل حتى أحيانا
+
+127
+00:10:47,930 --> 00:10:51,630
+والمستعمر فهذا الذي يطلقون عليه أستاذ الجيل لطفي
+
+128
+00:10:51,630 --> 00:10:55,950
+السيد يقول هذه العبارة من تقرأ لنا يا .. اللي
+
+129
+00:10:55,950 --> 00:11:00,910
+بتوحي بالكلام اللي احنا بتحدث عنه اتفضل الأخت اللي
+
+130
+00:11:00,910 --> 00:11:05,730
+وراأولياء أمورنا في الوقت الحاضر و ليس السبيل أن
+
+131
+00:11:05,730 --> 00:11:09,650
+نتعلم منهم ثم نتفاهم معاهم بل السبيل هو إيش؟ أن
+
+132
+00:11:09,650 --> 00:11:14,450
+نتعلم منهم ثم نتفاهم معاهم يعني لو طبقنا هذا
+
+133
+00:11:14,450 --> 00:11:18,190
+الكلمة على اليهود بدنا نقول إن اليهود هم أولياء
+
+134
+00:11:18,190 --> 00:11:24,710
+أمورنا في الوقت الحاضر و ليس السبيل أن نتعلم منهم
+
+135
+00:11:24,710 --> 00:11:28,230
+ثم نتفاهم معاهم هل هذا يجوز و ليه؟ نفس الكلمة لأن
+
+136
+00:11:28,230 --> 00:11:31,460
+الإنجليز كان يحتل مصر في ..تلك الفترة اللي قال
+
+137
+00:11:31,460 --> 00:11:36,080
+فيها الراجل هذا الكلام هل يكون المستعمر والمحتل
+
+138
+00:11:36,080 --> 00:11:40,560
+ولأمر المسلمين في يوم من الأيام والله تعالى يقول
+
+139
+00:11:40,560 --> 00:11:47,360
+ولن يجعل الله للكافرين على المؤمنين سبيلا لا يجوز
+
+140
+00:11:47,360 --> 00:11:52,870
+أن يكون الكافرللكافر سبيل و سلطان و حكم و ولاية
+
+141
+00:11:52,870 --> 00:11:58,250
+على المسلم، لا يجوز أن يقبل المسلم بذلك فكيف أما
+
+142
+00:11:58,250 --> 00:12:02,870
+الوطني أو غيره ممكن أن يقبل ذلك و يتفاهم معاه و
+
+143
+00:12:02,870 --> 00:12:06,930
+ممكن أن نعيش نحن و إياهم سواسيا و سواه و ممكن أن
+
+144
+00:12:06,930 --> 00:12:10,350
+يكون لهم دولة و يكون لنا دولة و نتعايش مع بعض و
+
+145
+00:12:10,350 --> 00:12:15,440
+نختلط مع بعضأي دولة هذه؟ انت تتكلم عن محتل ومستعمر
+
+146
+00:12:15,440 --> 00:12:20,680
+يحتل أرضك وبلادك كيف تتنازل له عن ذلك بكل سهولة
+
+147
+00:12:20,680 --> 00:12:24,580
+وبساطة؟ ومن خولك هذا الحق؟ هذا حق أجيال متعاقبة مش
+
+148
+00:12:24,580 --> 00:12:28,700
+حق فرد واحد مع احترامنا لكل القادة والزعماء لا
+
+149
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+يملك هذا الحق أحد من هؤلاء القادة ولا الزعماء بجر
+
+150
+00:12:32,800 --> 00:12:38,620
+قلم يروح يمضي أو يتنازل عن جزء كبير منفي فلسطين أو
+
+151
+00:12:38,620 --> 00:12:42,340
+من غيرها من الأراضي في يوم من الأيام جاء اليهود
+
+152
+00:12:42,340 --> 00:12:45,320
+إلى السلطان عبد الحميد الثاني وهو كان خليفة
+
+153
+00:12:45,320 --> 00:12:51,320
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+
+154
+00:12:51,320 --> 00:12:56,090
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+
+155
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+156
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+157
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+158
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+
+159
+00:13:13,590 --> 00:13:19,610
+و عروض كثيرفعزكم الله بسقى في وجه هذا اليهود الذي
+
+160
+00:13:19,610 --> 00:13:26,310
+جاءه وقال له إن عمل المبدع المشرط هذا لو يعني حطوه
+
+161
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+في جسدي عمل المبدع في جسدي يقطعون في تقطيع أهون
+
+162
+00:13:31,890 --> 00:13:37,030
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+
+163
+00:13:37,030 --> 00:13:40,950
+هذا الراجل لكن بعد أن ذهب وسقطت الخلافة وألغيت
+
+164
+00:13:40,950 --> 00:13:46,480
+وأسقطت وعليها the turkأصبح هناك دولة وكيان لليهود
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+165
+00:13:46,480 --> 00:13:50,500
+ووعد بالفور الذي أوفى بوعده ودعمه الأوروبيون في
+
+166
+00:13:50,500 --> 00:14:03,280
+ذلك الوقت ولازل اليهود على ما هم عليه اليوم بعد
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+167
+00:14:03,280 --> 00:14:08,480
+الحديث عن هذه الأهداف اهداف الفكر الوطني او الفكرة
+
+168
+00:14:08,480 --> 00:14:17,410
+الوطنية نتحدث عنتجاوزات الفكر الوطني والقومي معنى
+
+169
+00:14:17,410 --> 00:14:21,850
+لهم تجاوزات يعني أشياء خارج عن نطاق الدين تجاوز
+
+170
+00:14:21,850 --> 00:14:25,770
+يعني خرج عن نطاق الحد المعقول المعمول بيه فهناك
+
+171
+00:14:25,770 --> 00:14:33,310
+تجاوزات كثيرة لهذا الفكر تجعلنا يعني نعارضه ونرفضه
+
+172
+00:14:33,310 --> 00:14:41,160
+ولا نقبله بالكلية لما يحتويه من أفكارمعارضة
+
+173
+00:14:41,160 --> 00:14:46,640
+ومناقضة وتتجاوز كثير من مبادئنا اللي نؤمن بها
+
+174
+00:14:46,640 --> 00:14:51,620
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+
+175
+00:14:51,620 --> 00:14:55,520
+نحاول برضه معا .. معا أن نستعرضها من هذه التجاوزات
+
+176
+00:14:55,520 --> 00:15:00,860
+يا أخوات طبعا .. نبقى نقرا قرا عامة نجي من الأخوات
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+177
+00:15:00,860 --> 00:15:06,340
+بس معناهم مش .. تفضلفاصبغة تاريخية على الإسلام
+
+178
+00:15:06,340 --> 00:15:09,500
+اللي تم عده مرحلة ماضية من تاريخ الأمة العربية؟
+
+179
+00:15:09,500 --> 00:15:14,360
+نعم، بارك الله فيك، جزء جزء من الكلام، جعلوا
+
+180
+00:15:14,360 --> 00:15:20,160
+الإسلام مرحلة تاريخية فقط، مش عقيدة و دين و دين
+
+181
+00:15:20,160 --> 00:15:23,500
+الأمة و دين العالم، فاصبغة تاريخية على الإسلام،
+
+182
+00:15:23,500 --> 00:15:28,980
+يعني كأن الإسلام ماله مرحلة تاريخية من المراحل
+
+183
+00:15:28,980 --> 00:15:34,560
+التي مر بها من العربلأن هم قوميون والكلام على
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+184
+00:15:34,560 --> 00:15:40,220
+قوميين العرب والوطنيين العرب في داخل كيان الإسلام
+
+185
+00:15:40,220 --> 00:15:43,560
+فبيعتبروا الإسلام بينظروا إليه أن هو مرحلة من
+
+186
+00:15:43,560 --> 00:15:49,000
+المراحل الطويلة العريضة للعرب في مرحلة أو في فترة
+
+187
+00:15:49,420 --> 00:15:53,720
+يجي فيها الإسلام لكن في حاجة قبل الإسلام و ..
+
+188
+00:15:53,720 --> 00:15:56,540
+معناه في حاجة بعد الإسلام يعني؟ اه هم القوميين و
+
+189
+00:15:56,540 --> 00:16:01,420
+الوطنيين و ال .. وبالتالي هو مرحلة من الزمن و هذه
+
+190
+00:16:01,420 --> 00:16:06,120
+الخطوط وبالتالي صوروا الفكرة القومية بأن هي إيش؟
+
+191
+00:16:06,120 --> 00:16:10,020
+الفكرة الكلية الشاملة الفكرة القومية العربية هي
+
+192
+00:16:10,020 --> 00:16:15,030
+الفكرة الكلية الشاملة و جزء منهاومرحلة منها وحقبة
+
+193
+00:16:15,030 --> 00:16:18,750
+تاريخية كان الإسلام شايفين الخطورة والتجاوز ..
+
+194
+00:16:18,750 --> 00:16:21,850
+التجاوز و هذا الحد .. هذا الإسلام العظيم يجعله
+
+195
+00:16:21,850 --> 00:16:26,270
+مرحلة و القومية هي الأصل و من قبل احنا .. قبل أن
+
+196
+00:16:26,270 --> 00:16:29,970
+نكون مسلمين كانت لنا حضارة و كان لنا و كان لنا و
+
+197
+00:16:29,970 --> 00:16:33,590
+بتغنوا بما قبل الإسلام لما كان عليه العرب في
+
+198
+00:16:33,590 --> 00:16:38,830
+الجاهلين ومقابل ذلك ال .. ال .. النقطة الثانية من
+
+199
+00:16:38,830 --> 00:16:42,050
+هذه التجاوزات يقابل إطفاء الصبغة التاريخية للإسلام
+
+200
+00:16:42,050 --> 00:16:47,220
+اتنينتحاول تضخيم تاريخ الجاهلية و تاريخ العرب قبل
+
+201
+00:16:47,220 --> 00:16:50,140
+بعثة النبوية و جعله في الغالب مصدر انتماء و
+
+202
+00:16:50,140 --> 00:16:54,920
+اعتنان؟ نعم، ففي مقابل إدصاء الصبهة التاريخية
+
+203
+00:16:54,920 --> 00:17:01,240
+للإسلام، أنه التاريخ الجاهلية تضخيمهوالتصليط الضوء
+
+204
+00:17:01,240 --> 00:17:07,000
+عليه والاعتزاز به والدعوة إلى الرجوع إليه نرجع إلى
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+205
+00:17:07,000 --> 00:17:10,960
+جذورنا وأصولنا وإحنا قبل أن نكون مسلمين كنا عربا
+
+206
+00:17:10,960 --> 00:17:15,060
+وكنا كذا وكانت لنا حضارة و .. أي حضارة و أي عرب و
+
+207
+00:17:15,060 --> 00:17:18,600
+أي .. الله تعالى يصف تلك الفترة واذكروا نعمة الله
+
+208
+00:17:18,600 --> 00:17:22,400
+عليكم إذ كنتم عداء .. عداء .. إيش كان العرب قبل
+
+209
+00:17:22,400 --> 00:17:27,310
+الإسلام؟كنتم أعداء فألف بين قلوبكم بمين؟ بالإسلام
+
+210
+00:17:27,310 --> 00:17:31,770
+فأصبحت بنعمته يعني بالإسلام إخوان وعمر الفاروق
+
+211
+00:17:31,770 --> 00:17:35,830
+يقول كنا أذلة فهي العرب ماذا كان العرب قبل
+
+212
+00:17:35,830 --> 00:17:41,270
+الإسلام؟ أذل يستعبدهم الفرس والروم ويتلعبوا بهم
+
+213
+00:17:41,270 --> 00:17:45,590
+وليس لهم كيان يحسب له حساب كنا أذلة قبل الإسلام
+
+214
+00:17:45,590 --> 00:17:53,010
+فأعزن الله بالإسلاموإن ابتغينا العزة بغيره أذلنا
+
+215
+00:17:53,010 --> 00:17:56,470
+الله سبحانه وتعالى، إذا هذه العرب كانوا قبل
+
+216
+00:17:56,470 --> 00:18:01,590
+الإسلام قبائل يقاتلوا بعضها بعضا لأدفه الأسباب لأن
+
+217
+00:18:01,590 --> 00:18:08,950
+فرسا سبقت فرسا قامت حروب طاحنة بين قبائل بين بني
+
+218
+00:18:08,950 --> 00:18:13,250
+عبس وذبيان أربعين سنة استمرت وسمت بحرب داحس
+
+219
+00:18:13,250 --> 00:18:17,350
+والغبراء وحرب البسوس وغير من هذه الحروب اللي كانت
+
+220
+00:18:17,350 --> 00:18:26,790
+بينهمتلاتة من هذه التجاوزات اعطاها بوصفها انتماء
+
+221
+00:18:26,790 --> 00:18:33,090
+مضمون عقليا بيوصفها انتماء بيوصفها
+
+222
+00:18:33,090 --> 00:18:39,890
+انتماء اعطاها ايشمضمونا عقائديا بعد بدل ان تكون
+
+223
+00:18:39,890 --> 00:18:45,190
+مجرد انتماء الى القومية الى الوطنية تصبح عقيدة
+
+224
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+يتبناها الناس او يصبح لها عقيدة تصبح بديلا عن
+
+225
+00:18:49,030 --> 00:18:52,970
+اعتقاد المسلمين باسلامهم او النصارى بنصرانيتهم او
+
+226
+00:18:53,580 --> 00:18:56,860
+ينسى الإنسان عقيدته الآن و الآن عقيدته مين؟
+
+227
+00:18:56,860 --> 00:19:01,820
+قوميته، وطنيته، انتمائه إلى مين؟ إلى قوميته، إلى
+
+228
+00:19:01,820 --> 00:19:06,380
+وطنيته، ليس إلى دينه وإلى إسلامه وكذا وهذا أيضا
+
+229
+00:19:06,380 --> 00:19:11,500
+فتصبح القومية و الوطنية عقيدة أو دينا يحل محل
+
+230
+00:19:11,500 --> 00:19:19,140
+العقائد و الأديان فبقيت الدعوة القومية في بدايتها
+
+231
+00:19:19,140 --> 00:19:24,240
+دعوة إلى توحيد العرب أو توحيد العرببدون مضمون كل
+
+232
+00:19:24,240 --> 00:19:28,860
+من هو عربي ينتسب إلى القومية العربية إلى أن جاء
+
+233
+00:19:28,860 --> 00:19:32,520
+الفكر الشيوعي والاشتراكي وغزأ العالم العربي
+
+234
+00:19:32,520 --> 00:19:39,640
+والإسلامي فبحثوا عن مضمون عقائدي يتبنوه .. يتبنونه
+
+235
+00:19:39,640 --> 00:19:46,900
+في القومين فاختاروا الفكر الماركسي الشيوعي الملحد
+
+236
+00:19:46,900 --> 00:19:51,560
+اللي بيقول فيش إله ولا في دين ولا في أخلاق ولا ..
+
+237
+00:19:52,220 --> 00:19:57,780
+الذي أسس هذا الفكر هو كارل ماركس اليهودي من أبوين
+
+238
+00:19:57,780 --> 00:20:03,260
+يهوديين كان يقول إن الله والدين والأخلاق خرافة لا
+
+239
+00:20:03,260 --> 00:20:07,800
+أساس لها مش حاجة اسمها الله ولا دين ولا أخلاقناخد
+
+240
+00:20:07,800 --> 00:20:13,340
+فكره و نتبنه كقوميين في بداية القومية العربية ففي
+
+241
+00:20:13,340 --> 00:20:17,720
+الخمسينيات عقدة في بيانات اجتماع لدعاة القومية
+
+242
+00:20:17,720 --> 00:20:24,600
+العربية علشان يتبنوا محتوى عقائدي للقومية العربية
+
+243
+00:20:24,600 --> 00:20:29,440
+فبعد انتهاء هذا الاجتماع ماذا حدث؟ ايش كان من
+
+244
+00:20:29,440 --> 00:20:34,730
+نتائجه؟في نتيجتين هنا مذكورات، نتيجة الأولى واحد
+
+245
+00:20:40,260 --> 00:20:44,580
+اعتبروا هذا الفكر الاشتراكي الماركسي هو المحتوى
+
+246
+00:20:44,580 --> 00:20:48,300
+الايديولوجي الايديولوجي يعني ايش؟ الاستراتيجي لا
+
+247
+00:20:48,300 --> 00:20:52,720
+العقائد الايديولوجية يعني العقيدة العقيدة والمحتوى
+
+248
+00:20:52,720 --> 00:20:59,340
+اللي تتبنها القومية هي الشيوعي الاشتراكي اللي
+
+249
+00:20:59,340 --> 00:21:03,920
+تحدثنا عنها التي لا تؤمن لا بإله ولا بدين ولا
+
+250
+00:21:03,920 --> 00:21:11,300
+بأخلاق اتنينبعد تبني القوميين هذا الفكر، فى ناس
+
+251
+00:21:11,300 --> 00:21:15,820
+لسه عندها بقية من دين، بس عندها نزعى القومية وبدهم
+
+252
+00:21:15,820 --> 00:21:19,080
+العرب يتوحدوا ويكونوا .. لما سمعوا بهذا الأمر وإن
+
+253
+00:21:19,080 --> 00:21:23,340
+احنا بنتبنى الماركسية والاشتراكية المناقضة
+
+254
+00:21:23,340 --> 00:21:27,060
+والمعارضة للإسلام، إيش عملوا؟ نتجعل ذلك ان سحابات
+
+255
+00:21:27,060 --> 00:21:30,280
+كثيرة من مكان عمل القوى المتوجهات الماركسية وأصبحت
+
+256
+00:21:30,280 --> 00:21:34,760
+العضلة ملكة بالفكر اللساني والحاجةبارك الله فيك
+
+257
+00:21:34,760 --> 00:21:39,360
+إذا تركوا هذا العمل بدوا البعض اللي عنده بقية من
+
+258
+00:21:39,360 --> 00:21:41,940
+دين اللي عنده عقيدة مظبوط وعنده إسلام وعنده دين
+
+259
+00:21:41,940 --> 00:21:45,520
+ودخل معاهم في البداية لما لجاهم اتبنوا هذا الفكر
+
+260
+00:21:45,520 --> 00:21:48,580
+جعلهم أنا مش معاهم أنا مُنسَح أنا مسلم واعتز
+
+261
+00:21:48,580 --> 00:21:52,740
+بإسلامي وديني ومش مستعد أتخلى عن ديني وإسلامي لأجل
+
+262
+00:21:52,740 --> 00:21:56,340
+مبادئ كذا وكذا وكذا وديننا موجود في هذه المبادئ
+
+263
+00:21:56,340 --> 00:22:01,290
+وبيوحدنا وبيجمعنا فلماذا نحتاج إلى غير إيه؟مش دين
+
+264
+00:22:01,290 --> 00:22:07,290
+آخر، هذا يعني لا يؤمن بالأديان أصلا، الماركسية
+
+265
+00:22:07,290 --> 00:22:11,950
+الشيوعية لا تؤمن بالأديان كلها، مش دين، يعني ليست
+
+266
+00:22:11,950 --> 00:22:12,730
+هي دين أصلا
+
+267
+00:22:15,960 --> 00:22:20,020
+أربعة من تجاوزات الفكر القوم نرجع أه يعني مرة أخرى
+
+268
+00:22:20,020 --> 00:22:26,020
+إلى تكملة النتائج أو التجاوزات الفكر القومي و
+
+269
+00:22:26,020 --> 00:22:29,780
+الوطني تفضل يا أخت اللي هناك تفسير الإسلام بوصفه
+
+270
+00:22:29,780 --> 00:22:33,240
+للقوم من الأساس للشخصية العربية والارتقاص بالدور
+
+271
+00:22:33,240 --> 00:22:36,740
+اللي في الحياة برك الله فيك اذا وين أصبح دور
+
+272
+00:22:36,740 --> 00:22:42,160
+الإسلام في عقيدة القومية أو في الفكر القومي وين
+
+273
+00:22:42,160 --> 00:22:46,820
+راح الإسلام؟الإسلام يعني أقصى كما في العلمانين
+
+274
+00:22:46,820 --> 00:22:50,340
+اقصاءه عن الحكم والسياسة والدولة وكذا وكذا هنا
+
+275
+00:22:50,340 --> 00:22:56,880
+برضه الإسلام أقصى من دوره الذي
+
+276
+00:22:56,880 --> 00:23:00,520
+يقوم الشخصية العربية هو الذي جاء بالأخلاق الحميدة
+
+277
+00:23:00,520 --> 00:23:04,500
+والفضائل ودعا إلى حسن الخلق والمعاملة وفضلا عن
+
+278
+00:23:04,500 --> 00:23:10,990
+العقيدة التي فيه والعبادةجعل كأنه شيء ثانوي، كل
+
+279
+00:23:10,990 --> 00:23:14,310
+واحد حرفي دينه، لكن ماحدش يعني يلزمنا بالإسلام أو
+
+280
+00:23:14,310 --> 00:23:20,950
+بالدين أو .. لأن القومية يعني تجمع الأديان كلها أو
+
+281
+00:23:20,950 --> 00:23:24,830
+تجمع الأديان كلها وليس هناك .. يعني الرابطة
+
+282
+00:23:24,830 --> 00:23:29,090
+الدينية هي التي تجمع الناس في ظل القومية ولا حتى
+
+283
+00:23:29,090 --> 00:23:33,970
+في الوطنية كمانوهم بيقولوا حتى النصراني لن يقبل
+
+284
+00:23:33,970 --> 00:23:38,430
+اللي يعني على دينه لن يقبل بأن تكون القومية بديلا
+
+285
+00:23:38,430 --> 00:23:42,790
+له عن دينه ويقولوا اترك دينك وصير الآن قوم، دينك
+
+286
+00:23:42,790 --> 00:23:46,710
+الآن القومي، فكيف بالمسلم؟ من باب أولى، اللي يقبل
+
+287
+00:23:46,710 --> 00:23:53,670
+المسلم أن يترك دينه للقومية ليكون بديلا عن من؟ عن
+
+288
+00:23:53,670 --> 00:23:59,330
+الإسلام، تكون القومية بديلا عن الإسلامأي أن
+
+289
+00:23:59,330 --> 00:24:03,150
+الوطنية لن تكون مقبولة لا من المسلم ولا من غير
+
+290
+00:24:03,150 --> 00:24:09,930
+المسلم بديلا عن دينه وقبل أن ننتهي من هذه النقطة
+
+291
+00:24:09,930 --> 00:24:16,010
+فقط للتوضيحو نحن نتحدث عن هذا الكلام و نرد على
+
+292
+00:24:16,010 --> 00:24:20,990
+القومية و القوميين و الوطنية و الوطنيين لسنا ضد
+
+293
+00:24:20,990 --> 00:24:26,070
+الكلمة أو لسنا ضد تجمع العرب ولا لسنا ضد أن يتجمع
+
+294
+00:24:26,070 --> 00:24:31,720
+أهل البلد دلوقت نحن مع الوطنية كنزع و كعاطفةنتجمع
+
+295
+00:24:31,720 --> 00:24:35,280
+فيها من أجل قضايانا الوطنية ونتفهم على قضايانا
+
+296
+00:24:35,280 --> 00:24:39,840
+الوطنية وندافع عن وطننا .. هذه النزعة مطلوب نحن ضد
+
+297
+00:24:39,840 --> 00:24:44,160
+أن تتحول هذه النزعة من نزعة وعاطفة ومحبة للوطن
+
+298
+00:24:44,160 --> 00:24:49,820
+ودفاع عنه إلى رابطة بديلة عن الدين أو الإسلام الذي
+
+299
+00:24:49,820 --> 00:24:53,470
+هو دينالأغلبية والأكثرية احنا ماذا بدنا نفرض ونفرض
+
+300
+00:24:53,470 --> 00:24:58,210
+هو الناس بطبيعهم أو يعني الناس بواقعهم مسلمون
+
+301
+00:24:58,210 --> 00:25:01,610
+معظمهم أكثرهم والحديث عن البلاد العربية
+
+302
+00:25:01,610 --> 00:25:05,590
+والإسلاميين التي فيها الأغلبية والأكثرية مسلمون
+
+303
+00:25:05,590 --> 00:25:10,700
+لماذا نجعلهم يتخلوا عنعقيدتهم ودينهم اللذي يجمعهم
+
+304
+00:25:10,700 --> 00:25:16,000
+ونختار لهم رابطة تجمعهم مع غيرهم انتوا زيكوا زي
+
+305
+00:25:16,000 --> 00:25:20,480
+اليهود زي النصارى زي كذا زي زي مافيش فرق بينهم كيف
+
+306
+00:25:20,480 --> 00:25:24,720
+لا فرق بين مسلم ومسيحي وكذا في العقيدة وفي الدين
+
+307
+00:25:24,720 --> 00:25:28,020
+لا فرق بينهم في المواطنة كلهم أصحاب بطن واحد
+
+308
+00:25:28,020 --> 00:25:33,060
+وبدافوا عنه ولهم حقوقهم و .. لكن كدين وعقيدة لأ في
+
+309
+00:25:33,060 --> 00:25:37,440
+فرقه فرق كبير نحن الأغلبية و الأكثرية لابد أن نحكم
+
+310
+00:25:37,880 --> 00:25:41,480
+الحكم يجب أن يكون الأغلبية والأكثرية حتى في
+
+311
+00:25:41,480 --> 00:25:46,460
+مبادئهم الديمقراطية التي تعني حكم الأغلبية للأقلية
+
+312
+00:25:47,330 --> 00:25:53,010
+الأغلبية هم مسلمون والأغلبية يعني أصحاب دين مش لا
+
+313
+00:25:53,010 --> 00:25:57,250
+دينيين ولا متخلين كذلك في موضوع القومية التي تجمع
+
+314
+00:25:57,250 --> 00:26:02,170
+العرب نحن مع أن يتجمع العرب ووالاخر لكن هل ال ..
+
+315
+00:26:02,170 --> 00:26:06,570
+هل .. هل ال .. ال .. ال .. الإسلام جاء للعرب وحدهم
+
+316
+00:26:06,570 --> 00:26:12,070
+أو هل المسلم يعني يعترف بالعرب ولا يعترف ب ..غير
+
+317
+00:26:12,070 --> 00:26:14,830
+العرب من المسلمين هذه المشكلة اللي في موضوع
+
+318
+00:26:14,830 --> 00:26:20,510
+القومية انه بده يقطعنا عن الرابطة الكبيرة وهي
+
+319
+00:26:20,510 --> 00:26:24,970
+رابطة الإسلام المسلم أخه المسلم ليصبح كأنه العربي
+
+320
+00:26:24,970 --> 00:26:29,950
+أخه العرب في القومية العربية وفي الوطنية الفلسطيني
+
+321
+00:26:29,950 --> 00:26:33,270
+أخه الفلسطيني وطن واحد بيجمع الفلسطيني والمصري أخه
+
+322
+00:26:33,270 --> 00:26:37,010
+المصري في الدائرة الصغيرة في الوطنية الفلسطيني أخه
+
+323
+00:26:37,010 --> 00:26:40,790
+الفلسطينيالمصري اخو المصري فقط بس مافيش اخوة تانية
+
+324
+00:26:40,790 --> 00:26:44,910
+لان وطنية واحد حرف وطنه ويهتم في وطنه في القومية
+
+325
+00:26:44,910 --> 00:26:48,670
+العربي اخو العرب التركي اخو التركي بس قومية
+
+326
+00:26:48,670 --> 00:26:52,910
+طورانية وكتير طيب و اين ذهبت المسلم اخو المسلم
+
+327
+00:26:54,010 --> 00:26:57,830
+وإنما المؤمنون إخوة مش هتدائرة أكبر وأوسع وهي
+
+328
+00:26:57,830 --> 00:27:01,850
+الدائرة والقاصرة والرابطة اللي الإسلام والقرآن
+
+329
+00:27:01,850 --> 00:27:05,870
+والدين أمرنا بيها وحثنا عليها بدون إيه نتخلى عنها
+
+330
+00:27:05,870 --> 00:27:09,850
+كلها هتدائرة الكبرى ونلجأ إلى دوائر أصغر عشان
+
+331
+00:27:09,850 --> 00:27:14,530
+نتشرثم ونتفرق ونتجزة وبالتالي نكون ضعفاء دائما
+
+332
+00:27:14,530 --> 00:27:18,590
+والقوة تكون لمن؟ لهم هم هتدعاوة غربية واحنا
+
+333
+00:27:18,590 --> 00:27:24,350
+قبلناهاوطبقناها وهم كما قلنا في بداية الحديث عن
+
+334
+00:27:24,350 --> 00:27:28,990
+القومية ونشأتها هم اتخلوا عنها لأنه اكتووا بنارة
+
+335
+00:27:28,990 --> 00:27:34,210
+والان جاعدين العالم الغربي والأوروبي بيتوحد مع أنه
+
+336
+00:27:34,210 --> 00:27:37,970
+قوميات وجنسيات مختلفة العالم الأوروبي والغربي
+
+337
+00:27:37,970 --> 00:27:42,250
+والأجنبي قوميات وجنسيات كثير وبيتوحدوا مع بعض
+
+338
+00:27:42,250 --> 00:27:46,810
+واحنا مطلوب منك أمم عربية وإسلامية انه نتفرق في
+
+339
+00:27:46,810 --> 00:27:53,820
+هذه الدوائر نقطة الخامسةو في موضوع التجاوزات تفضل
+
+340
+00:27:53,820 --> 00:27:57,380
+اختيالقومية الوطنية ببعض المذاهب والفلسفات
+
+341
+00:27:57,380 --> 00:28:00,560
+اللادينية قررت بينها وبين الفكر المدنسي والاشتراكي
+
+342
+00:28:00,560 --> 00:28:04,240
+أو الفكر العلمي برك الله فيك هيك أصبح الأمر لأن
+
+343
+00:28:04,240 --> 00:28:10,140
+أصبح الدعاة القومية ودعاة الوطنية هم دعاء لهذه
+
+344
+00:28:10,140 --> 00:28:13,560
+المذاهب أو بتبانوا هذا يا إما نجدهم ناس لا دينيين
+
+345
+00:28:13,560 --> 00:28:20,280
+يا يحملوا أفكار ماركسية أو اشتراكية أو علمانية وقد
+
+346
+00:28:20,280 --> 00:28:27,680
+نجد فيهم ناس أصحاب تدينومتخارطين ضمن هذا الكوكتيل
+
+347
+00:28:27,680 --> 00:28:32,040
+الموجود في القومية أو الوطنية مسلم مع مسيحي مع
+
+348
+00:28:32,040 --> 00:28:36,360
+نصراني و هذا المسلم درجة تمكن تلاقيه متدين و ماسك
+
+349
+00:28:36,360 --> 00:28:39,840
+في الدنيا ولكن بينتمل الفكر القومي و الوطني و
+
+350
+00:28:39,840 --> 00:28:44,250
+ماتفرجش عنده كتيرو انا مش حاسس انه يعني في فارق
+
+351
+00:28:44,250 --> 00:28:49,110
+كبير بين ان يكون قوميا او يعني اسلاميا او اتجاه
+
+352
+00:28:49,110 --> 00:28:58,630
+اسلامي يجمع المسلمين في كل اقطار العالم هذه
+
+353
+00:28:58,630 --> 00:29:03,760
+الدعوةالقومية يا أخوات كان لها نتائج و .. نتائج
+
+354
+00:29:03,760 --> 00:29:07,780
+يعني وخيمة ده ما نحن بنحكي عن نتائج الأصل ان تكون
+
+355
+00:29:07,780 --> 00:29:12,560
+نتائج إيجابية وكويسة لكن نجد نتائج هذه الدعوة كلها
+
+356
+00:29:12,560 --> 00:29:18,820
+نتائج سلبية وعواقب وخيمة من جراء تبني القومية في
+
+357
+00:29:18,820 --> 00:29:24,420
+عالمنا الإسلامي ماذا جنينا من وراء القومية؟ ايش
+
+358
+00:29:24,420 --> 00:29:30,640
+هذه النتائج اللي كانت من ورائها؟تفضل يا أختي نشر
+
+359
+00:29:30,640 --> 00:29:34,260
+الأفكار الغربية اللي نجمها أكثر إسلام لقرار القضية
+
+360
+00:29:34,260 --> 00:29:36,920
+السياسية والاجتماع الجواجن عالمنا من دول الإسلام
+
+361
+00:29:36,920 --> 00:29:42,700
+وإحلاق البدالة يا عزيزي فلسفات وعقائد أخرى برك
+
+362
+00:29:42,700 --> 00:29:46,740
+الله فيه إذا هي اللي جانينا في ظل القومية والوطنية
+
+363
+00:29:46,740 --> 00:29:51,920
+لأن أصبعت هي بديل عن الدين انتشرت كل هذه الأفكار
+
+364
+00:29:51,920 --> 00:29:59,880
+الغريبة اللي اختفضت بهافرغت كل قضايانا السياسية
+
+365
+00:29:59,880 --> 00:30:04,180
+والاجتماعية من الإسلام لأن الإسلام لا علاقة له
+
+366
+00:30:04,180 --> 00:30:07,640
+بالذلك ليس هو الرابطة ولا هو الموجه ولا هو المقوم
+
+367
+00:30:07,640 --> 00:30:11,640
+الرابطة هي القومية الرابطة هي الوطنية وماذا سنأخذ
+
+368
+00:30:11,640 --> 00:30:18,860
+من القومية أو من الوطني هل فيها مبادئيعني بديلة
+
+369
+00:30:18,860 --> 00:30:24,880
+أو يعني مثل الإسلام في صلاحيتها ونقاها وسلامتها
+
+370
+00:30:24,880 --> 00:30:30,480
+وأنها جاءت لمصلحة الجميع كما جاء الإسلام في أحكامه
+
+371
+00:30:30,480 --> 00:30:37,600
+ومبادئه كذلك يعني في أمثلة وهي تبين هذه الخطورة
+
+372
+00:30:37,600 --> 00:30:43,120
+التي وقع فيها العرب والمسلمون كنتيجة للدعوة إلى
+
+373
+00:30:43,120 --> 00:30:43,840
+القومية
+
+374
+00:30:46,600 --> 00:30:50,720
+وفي بعض الأمثلة هام وعلى رأسها المثال البارز
+
+375
+00:30:50,720 --> 00:30:57,260
+والواضح وهو ظهور الجامعة العربية أو جامعة الدول
+
+376
+00:30:57,260 --> 00:31:03,840
+العربية وكانت فكرة بديل عن الجامعة الإسلامية التي
+
+377
+00:31:03,840 --> 00:31:08,440
+طرحت من قبل دعاوى مصلحون في ذلك الوقت كانت تفكير
+
+378
+00:31:08,440 --> 00:31:13,200
+بإنشاء جامعة تجمع المسلمين أجمعين طبعا هذا الكلام
+
+379
+00:31:13,200 --> 00:31:17,700
+ليس في صالحالغرب ولا الشرق ولا الاستعمار ولا الدول
+
+380
+00:31:17,700 --> 00:31:24,100
+الكبرى ولا ذات النفوذ فأوقفوا هذا الفكر و هذا
+
+381
+00:31:24,100 --> 00:31:28,120
+التفكير و عملوا على إقصائي و إلغائي و لما وجدوا
+
+382
+00:31:28,120 --> 00:31:32,000
+الأمر ملح وجد و بدهم يجتهدوا يقولوا إذا كان الأمر
+
+383
+00:31:32,000 --> 00:31:39,320
+ولابدفادعو إلى جامعة عربي تجمع العرب وضلنا في
+
+384
+00:31:39,320 --> 00:31:42,860
+الدائرة القومية نفسها الدائرة العربية عشان ما
+
+385
+00:31:42,860 --> 00:31:48,320
+نطلعش و نتوسع إلى الدائرة الإسلامية خليكم في
+
+386
+00:31:48,320 --> 00:31:52,360
+الدائرة الأصغر اعملكوا جامعة للدول العربيةوهذه
+
+387
+00:31:52,360 --> 00:31:57,620
+كانت فكرة يعني انجليزية من بنات أفكار وزير خارجية
+
+388
+00:31:57,620 --> 00:32:03,380
+بريطانيا السابق لو أنتوني ايدن قال للزعماء و
+
+389
+00:32:03,380 --> 00:32:06,900
+القادة في ذلك الوقت في سنة الف وتسعمائة وخمسة
+
+390
+00:32:06,900 --> 00:32:09,620
+وعربين كانت هذه الفكرة و لازالت هذه الجامعة
+
+391
+00:32:09,620 --> 00:32:16,720
+العربية قائمة إلى اليوم وقراراتهاالعديد وعلى مدى
+
+392
+00:32:16,720 --> 00:32:23,000
+الفترات السابقة كلها إلى اليوم قرارات ضعيفة وهشة
+
+393
+00:32:23,000 --> 00:32:30,920
+لا تتجاوز الشجب والاستنكار والإدانةلما يحدث في
+
+394
+00:32:30,920 --> 00:32:36,700
+بلاد المسلمين وإذا يعني بدهم شويه يعصوا ويشدوا
+
+395
+00:32:36,700 --> 00:32:43,020
+فبتكون اللهجة نستنكر بشدة، نستنكر بقوة، فيوم ما
+
+396
+00:32:43,020 --> 00:32:46,340
+يقولوا نستنكر بشدة أو بقوة، إيش بيصير في اليهود؟
+
+397
+00:32:46,900 --> 00:32:49,540
+ببرجوفه بيصيروا يحسبوا 100 ألف حساب لأن اللحظة
+
+398
+00:32:49,540 --> 00:32:53,320
+اختلفت المرات بدل ان ندين الناس تنكر نجب لحالة
+
+399
+00:32:53,320 --> 00:32:57,900
+يعني صاحباتك قلت بشدة بقوة مش عارف كده فكأنه الأمر
+
+400
+00:32:57,900 --> 00:33:01,960
+يعني ضحك على الناس ان احنا المرات جديين و هنعمل
+
+401
+00:33:01,960 --> 00:33:06,360
+كده و ما وهي لا تتجاوز الاستنكار والشجب والإداد
+
+402
+00:33:06,360 --> 00:33:12,580
+أيضا من نتاج الدعوة الى القومية في العالم الإسلامي
+
+403
+00:33:12,580 --> 00:33:18,950
+اتنين فضلا يا ربتمكين الاستعمار الغربي من تحقيق
+
+404
+00:33:18,950 --> 00:33:22,470
+أهدافه الشريرة التي تتمثل في هدم الخلافة الإسلامية
+
+405
+00:33:22,470 --> 00:33:25,810
+وتفتيط الكيان السياسي الإسلامي و القضاء على الوحدة
+
+406
+00:33:25,810 --> 00:33:30,610
+الإسلامية بارك الله فيكي و أحسنت هذا الهدف الخبيث
+
+407
+00:33:30,610 --> 00:33:37,460
+اللي كان من ورانشر القومية في بلاد المسلمين
+
+408
+00:33:37,460 --> 00:33:41,700
+ولطالما رددنا الكلام في هذا الجانب انه كان الهدف
+
+409
+00:33:41,700 --> 00:33:46,640
+الأصلي والأساسي هو هدم الخلافة الإسلامية التي تجمع
+
+410
+00:33:46,640 --> 00:33:51,860
+المسلمين وشتات المسلمين و القضاء على وحدتهم لأنهم
+
+411
+00:33:51,860 --> 00:33:58,130
+علموا أن قوة المسلمين التي تقف ضدهم هي في وحدتهفي
+
+412
+00:33:58,130 --> 00:34:02,290
+أمرين في عقيدتهم و في وحدتهم فعملوا على إضعاف هذه
+
+413
+00:34:02,290 --> 00:34:05,910
+العقيدة عبر نشر الأفكار و المبادئ العلمانية و
+
+414
+00:34:05,910 --> 00:34:09,690
+القومية و الوطنية و غيرها و عملوا على تفتيت هذه
+
+415
+00:34:09,690 --> 00:34:14,750
+الوحدة بزرع هذه الأفكار أيضا اللي هي القومية و
+
+416
+00:34:14,750 --> 00:34:19,550
+الوطنية حتى تفرق المسلمين بعضهم عن بعض فهذه كانت
+
+417
+00:34:19,550 --> 00:34:25,420
+من نتائج الدعوة إلى القوميةوالاستعمار الغربي في
+
+418
+00:34:25,420 --> 00:34:30,440
+احتلاله للبلاد الإسلامية لم يستطع السيطرة عليها
+
+419
+00:34:30,440 --> 00:34:37,320
+واخضاعها إلا بعد أن آتت القومية أكلها وثمارها في
+
+420
+00:34:37,320 --> 00:34:42,540
+البلاد الإسلامية فبدأ يضعف المسلمون بعد أن كانوا
+
+421
+00:34:42,540 --> 00:34:49,190
+يعني قوة عظيمةونشأت هناك القوميات المختلفة العربية
+
+422
+00:34:49,190 --> 00:34:54,210
+والطورانية والجردية والهندية وغيرها من القومية
+
+423
+00:34:54,210 --> 00:34:59,770
+ثلاثة من نتائج الدعوة إلى القومية اتفضل تقدمت
+
+424
+00:34:59,770 --> 00:35:03,410
+الدعوة القومية على أحيان إمارات الجهود اللي كانت
+
+425
+00:35:03,410 --> 00:35:04,330
+هناك قبل الإسلام
+
+426
+00:35:09,510 --> 00:35:16,330
+نعم بارك الله فيك فهذه الدعوات القديمة وهذه التي
+
+427
+00:35:16,330 --> 00:35:20,510
+سماها أصحابها حضارات فهي ليست بحضارات في حقيقة
+
+428
+00:35:20,510 --> 00:35:26,230
+الأمر يعني كان لها بعض الأفكار وبعض الأعمال ولا
+
+429
+00:35:26,230 --> 00:35:31,150
+تصل ولا تلقى الى يعني وصف حضارات الحضارة الفرعونية
+
+430
+00:35:31,150 --> 00:35:34,530
+والحضارة الأشورية والحضارة الفينيقية والحضارة
+
+431
+00:35:34,530 --> 00:35:40,200
+الطورانية كل ذلك من أجل إقصاء الإسلاميعني كله
+
+432
+00:35:40,200 --> 00:35:44,100
+مسموح إلا الإسلام ممكن نرجع إلى الحضارة الفرن أما
+
+433
+00:35:44,100 --> 00:35:46,940
+أن نرجع الإسلام لأ ممكن نرجع إلى الحضارة الأشورية
+
+434
+00:35:46,940 --> 00:35:51,560
+أما الإسلام لأ إلى الفينيقية إلى ال .. كأن الإسلام
+
+435
+00:35:51,560 --> 00:35:57,080
+أصبح عارا أو أصبت عارة بل هو العزة والكرامة والفخر
+
+436
+00:35:57,080 --> 00:36:03,120
+للعرب على مدار التاريخ وماذا فعلت لهم الفرسية أهل
+
+437
+00:36:03,120 --> 00:36:06,320
+الفرس كانوا بيعبدوا النار فهذه حضارة الذي يعبدوا
+
+438
+00:36:06,320 --> 00:36:11,390
+النار والفرعنة ماذا كانوا يعبدونيعبدون فرعاوة يعني
+
+439
+00:36:11,390 --> 00:36:15,650
+يقول لهم انا ربكم اللعنى واستخف قومه فاطعوا هل هذه
+
+440
+00:36:15,650 --> 00:36:20,650
+حضارة ولا هي مجرد بناء الأهرام يعني هذا جزء بناء
+
+441
+00:36:20,650 --> 00:36:24,250
+من البناء ليس الحضارة هي يعني شكل بنائي ولا هندسي
+
+442
+00:36:24,250 --> 00:36:29,850
+ولا الحضارة عبارة عن عقيدة سليمة صحيحة وقيم عليا
+
+443
+00:36:29,850 --> 00:36:33,630
+اين هذه العقيدة الصحيحة او اين هذه القيم العليا
+
+444
+00:36:36,060 --> 00:36:42,140
+أيضًا من أخطر ما جنته أو ما جنيناهم من القومية
+
+445
+00:36:42,140 --> 00:36:43,520
+العربية .. فضل يا رب
+
+446
+00:36:49,800 --> 00:36:56,640
+برك الله فيك، هذا الذي نحن فيه اليوم ونعاني منه من
+
+447
+00:36:56,640 --> 00:37:01,120
+جرائم وهو احتلال اليهود لفلسطين 48 في البداية ثم
+
+448
+00:37:01,120 --> 00:37:07,140
+اكملت الدائرة فاحتلت باقي مدن فلسطين في 67، هذا
+
+449
+00:37:07,140 --> 00:37:13,940
+كان من بركات الستالقومية يعني بركات القومية
+
+450
+00:37:13,940 --> 00:37:18,240
+والوطنية وكذا هذا الذي جنيناه هل يعني جعلت
+
+451
+00:37:18,240 --> 00:37:22,040
+المسلمين كما كانوا يتواهون أو العرب أقوى في صد
+
+452
+00:37:22,040 --> 00:37:27,720
+الهجمة اليهودية والاسلطان اليهودي في ذلك الوقت
+
+453
+00:37:27,720 --> 00:37:31,640
+ويمنع اليهود من احتلال فلسطين انهزم العرب في 48
+
+454
+00:37:31,640 --> 00:37:37,410
+وانهزموا في 67 وكانوا يتبنون الفكر القوميوالوطن
+
+455
+00:37:37,410 --> 00:37:41,310
+فماذا أغنى عنهم فلم تغنى عنهم لا القومية ولا
+
+456
+00:37:41,310 --> 00:37:48,030
+الوطنية في ظل جيوش دخلت الحرب وهزمت وهي تعتقد أنها
+
+457
+00:37:48,030 --> 00:37:53,370
+ستنتصر وس تقوى بهذه الأفكار فيما قلة قليلة فئة
+
+458
+00:37:53,370 --> 00:37:58,950
+قليلة من المسلمين لجيش كامل و لفئةمن أهل الفلسطين
+
+459
+00:37:58,950 --> 00:38:04,530
+في غزة التي نسكنها و نعتز و نفتخر بها صدت هجمة
+
+460
+00:38:04,530 --> 00:38:09,770
+كبرى لجيش الاحتلال و هم قلة قليلة بفضل الله تعالى
+
+461
+00:38:09,770 --> 00:38:16,630
+و بمعيته و بهدايته لأنهم صدقوا الله فصدقهم اللهو
+
+462
+00:38:16,630 --> 00:38:22,310
+ربنا وعدهم بالنصر و صدق وعده معهم و استطاعوا ان
+
+463
+00:38:22,310 --> 00:38:26,370
+يصمدوا و يصبروا و يثبتوا في الحرب الأولى حرب
+
+464
+00:38:26,370 --> 00:38:30,790
+الفرقان و الحرب الثانية حرب حجارة السجيل و العالم
+
+465
+00:38:30,790 --> 00:38:37,250
+شهد لهم كله العالم كله و هذا ليس كلامنا
+
+466
+00:38:37,250 --> 00:38:41,070
+نحن فقط اهل هذه البلد او نعتز به او نفتخر به لان
+
+467
+00:38:41,070 --> 00:38:46,570
+انا اهل هذه البلدالعالم العربي والإسلامي من حولنا
+
+468
+00:38:46,570 --> 00:38:52,170
+اعترف بذلك والعدو أقر بهذه الهزيمة لأنه لم يعترف
+
+469
+00:38:52,170 --> 00:38:56,570
+بإنجازات ولا أنه انتصر في هذه الحرب بل الأهداف
+
+470
+00:38:56,570 --> 00:39:00,990
+التي جاء ليحققها لم يحقق منها شيء غير هدم البيوت
+
+471
+00:39:00,990 --> 00:39:05,170
+وقتل النساء والأطفال والمقاومين يعني لم يقتل منهم
+
+472
+00:39:05,170 --> 00:39:09,650
+العدد الكبير اللي يعني يمكن أن يقتل في حرب مثل هذه
+
+473
+00:39:09,650 --> 00:39:19,040
+الحربولم يحقق العدو أهدافه من ذلك طيب
+
+474
+00:39:19,040 --> 00:39:25,320
+نقف عند موقف الإسلام من القومين نقف عند هذا الموقف
+
+475
+00:39:25,320 --> 00:39:26,820
+والله يعطيكم العافية
+
diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/gvd09JXflFM_postprocess.srt b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/gvd09JXflFM_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..88265413233f4467af12461a13fc44467ead9e21
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/gvd09JXflFM_postprocess.srt
@@ -0,0 +1,1292 @@
+1
+00:00:20,940 --> 00:00:24,320
+الحمد لله يا رب العالمين والصلاة والسلام على أشرف
+
+2
+00:00:24,320 --> 00:00:28,600
+الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحفه
+
+3
+00:00:28,600 --> 00:00:33,580
+أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت
+
+4
+00:00:33,580 --> 00:00:38,700
+العليم والحكيم اللهم علمنا ما ينفعنا وانفعنا بما
+
+5
+00:00:38,700 --> 00:00:46,060
+علمتنا وازدنا علم أمين يا رب العالمين أما بعد بعد
+
+6
+00:00:46,060 --> 00:00:48,940
+طول
+
+7
+00:00:50,100 --> 00:00:54,740
+يعني فترة طويلة من الوقت والمحاضرات أخذت معنى
+
+8
+00:00:54,740 --> 00:00:59,540
+العلمانية انتهينا منها في المحاضرة الماضية بالحديث
+
+9
+00:00:59,540 --> 00:01:03,600
+عن موقف الإسلام من العلمانية ومن دعات العلمانية
+
+10
+00:01:03,600 --> 00:01:10,100
+وهي أول وسيلة من وسائل التغريب ذكرنا أربع وسائل
+
+11
+00:01:10,100 --> 00:01:13,720
+للتغريب كان أولها العلمانية اليوم ان شاء الله
+
+12
+00:01:13,720 --> 00:01:19,460
+نتحدث عن ثاني وسائل التغريب وهيالقومية ومعها
+
+13
+00:01:19,460 --> 00:01:25,700
+الوطنية في النسخة الجديدة أضيفت الوطنية لم تكن في
+
+14
+00:01:25,700 --> 00:01:30,100
+النسخ القديمة عشان هي أكدنا وركزنا على اعتماد
+
+15
+00:01:30,100 --> 00:01:34,620
+النسخة الجديدة لإن فيها بعض الإضافات والزيادة ليست
+
+16
+00:01:34,620 --> 00:01:40,530
+موجودة في النسخة السابقةنتعرف في محاضرة اليوم في
+
+17
+00:01:40,530 --> 00:01:43,630
+هذه الوسيلة الثانية من وسائل التغريب يا أخوات وهي
+
+18
+00:01:43,630 --> 00:01:48,890
+القومية والوطنية على معنى القومية ومعنى الوطنية
+
+19
+00:01:48,890 --> 00:01:56,170
+وهذا الفكرالذي دخل على الفكرة الإسلامية والمبدأ
+
+20
+00:01:56,170 --> 00:02:00,790
+الإسلامي العام والشامل الذي يشمل المسلمين جميعا
+
+21
+00:02:00,790 --> 00:02:05,690
+وإذ بهذا المذهب وهذا الفكر وهذا المبدأ يجزء ويشرذم
+
+22
+00:02:05,690 --> 00:02:10,310
+ويقسم المسلمين إلى قوميات متعددة بعد أن كانوا أمة
+
+23
+00:02:10,310 --> 00:02:16,470
+واحدة وإلى وطنيات أيضا متعددة بعد أن كانوا إخوة في
+
+24
+00:02:16,470 --> 00:02:21,050
+الإسلام والإيمان أصبحوا في القومية إخوة في القومية
+
+25
+00:02:21,050 --> 00:02:25,350
+فقطفي الوطنية .. اخوة في الوطنية فقط لا يجمعهم ذلك
+
+26
+00:02:25,350 --> 00:02:29,990
+الجامع الأكبر والأعم والأشمل وهو جامع الدين
+
+27
+00:02:29,990 --> 00:02:36,710
+والإسلام هذه الفكرة التي نحن بصددها القومية ربما
+
+28
+00:02:36,710 --> 00:02:41,910
+المصطلح حادث أو جديد لكنها فكرة قديمة وفكرة جاهلية
+
+29
+00:02:41,910 --> 00:02:49,720
+كان اهل الجاهلية يستخدمونها ويتبنونها باس باسمو
+
+30
+00:02:49,720 --> 00:02:56,420
+مصطلح و لفظ آخر مختلف فكان يطلق عليها اسم العصابية
+
+31
+00:02:56,420 --> 00:03:04,140
+القبالية حيث كان التعصب للقبيلة كل أفراد القبيلة
+
+32
+00:03:04,140 --> 00:03:09,420
+يتعصبون لقبيلة ينتمون و ينتسبون إلى قبيلة يوالون
+
+33
+00:03:09,420 --> 00:03:14,780
+القبيلة ليس هناك جهة ولا يوالونها غير القبيلة وكان
+
+34
+00:03:14,780 --> 00:03:21,150
+شعارهمالمشهور أنصر أخاك رالمًا أو مظلومًا لابد أن
+
+35
+00:03:21,150 --> 00:03:26,270
+تقف مع ابن قبيلتك وأخاك هنا يعني ابن قبيلتك حيث
+
+36
+00:03:26,270 --> 00:03:33,450
+كانت القبيلة تجمع يعني كجامع ورابط لهؤلاء وعلى هذا
+
+37
+00:03:33,450 --> 00:03:39,090
+الأساس سواء كان هذاالذين يقفون معه ظالمًا أو
+
+38
+00:03:39,090 --> 00:03:45,050
+مظلومًا كانت تنشي بحروب طويلة وكبيرة بين القبائل
+
+39
+00:03:45,050 --> 00:03:48,930
+وبين العرب في الجاهلية قبل الإسلام على أدفه
+
+40
+00:03:48,930 --> 00:03:57,030
+الأسباب مجرد أدفه الأسباب تحدث حروب وحروب طاحنة
+
+41
+00:03:57,030 --> 00:04:01,770
+منها حرب داحس والغبراء وحرب البسوس وغيرها داحس
+
+42
+00:04:01,770 --> 00:04:09,390
+والغبراء استمرت أربعين سنة لأنفرسا سبقت فرسا فرس
+
+43
+00:04:09,390 --> 00:04:16,390
+الغبراء سبقت فرس داحس بين قبيلتي عبس وذبيان فدارت
+
+44
+00:04:16,390 --> 00:04:21,450
+حرب طاحنة استمرت اربعين سنة عشان فرسايا سبقت
+
+45
+00:04:21,450 --> 00:04:26,470
+فرسايا شايفين؟ يعني التفاهل اللي كان في عقول هؤلاء
+
+46
+00:04:26,470 --> 00:04:31,030
+لأدفع الأسباب كانوا يقاتل بعضهم البعض ولمّا جاء
+
+47
+00:04:31,030 --> 00:04:37,740
+الإسلام وأقام دولة جمعت هؤلاءالعرب جميعًا اللي
+
+48
+00:04:37,740 --> 00:04:42,900
+كانوا ينتمون وينتسبون إلى القبائل المختلفة تناسوا
+
+49
+00:04:42,900 --> 00:04:45,980
+هذه النسبة و هذا الولاء و هذا الانتماء لهذه
+
+50
+00:04:45,980 --> 00:04:52,440
+القبائل و الدعوة إلى تلك العصبيات القبلية وأصبحوا
+
+51
+00:04:52,440 --> 00:04:59,240
+أخوة متحابين وقد امتم الله تعالى على العرببهذه
+
+52
+00:04:59,240 --> 00:05:03,500
+النعمة الكبرى وذكرهم واذكروا نعمة الله عليكم إذ
+
+53
+00:05:03,500 --> 00:05:07,460
+كنتم أعداء بالأمس كنتوا أعداء يقادلوا بعضكم بعضا
+
+54
+00:05:07,460 --> 00:05:11,740
+لأطفال الأسباب واذكروا نعمة الله عليكم إذ كنتم
+
+55
+00:05:11,740 --> 00:05:19,180
+أعداء فألف بين قلوبكم فأصبحتم بنعمته إخوانا أصبحوا
+
+56
+00:05:19,180 --> 00:05:24,500
+بنعمة الإسلام العظيمة إخوانا المتحبين بعد أن كانوا
+
+57
+00:05:24,500 --> 00:05:30,490
+متحاربين متقاتلينواخى النبي صلى الله عليه وسلم بين
+
+58
+00:05:30,490 --> 00:05:34,930
+الأوس والخزرج أكبر قبيلتين كانت في المدينة وكان
+
+59
+00:05:34,930 --> 00:05:41,250
+بينهما يعني قتال مستمر وحروب طاحنة فاذ بهم يعني
+
+60
+00:05:41,250 --> 00:05:48,190
+يصبحون أخوة متحابينفاستبدلت الرابطة القبلية
+
+61
+00:05:48,190 --> 00:05:53,590
+والعصبية القبلية برابطة جديدة هي رابطة الإيمان
+
+62
+00:05:53,590 --> 00:06:01,350
+والإسلام والعقيدة إنما المؤمنون إخوةليس العرب
+
+63
+00:06:01,350 --> 00:06:05,550
+وحده، ليست القبيلة الفلانية وحدها، اللي في ما
+
+64
+00:06:05,550 --> 00:06:09,970
+بينها الأخوة والمحبة والولاء، وإنما أصبح كل مؤمن
+
+65
+00:06:09,970 --> 00:06:17,010
+في هذا الكون هو أخه للمؤمن، كان عربيا أو فارسيا أو
+
+66
+00:06:17,010 --> 00:06:22,410
+غير ذلك، المسلم أخ المسلمحديث النبي صلى الله عليه
+
+67
+00:06:22,410 --> 00:06:29,090
+وسلم والآية من قبل إنما المؤمنون إخوة أصبحت بنعمته
+
+68
+00:06:29,090 --> 00:06:38,130
+إخوانا أصبحت هذه الرابطة و هذه العلاقة الجديدة بدل
+
+69
+00:06:38,130 --> 00:06:43,930
+العصبية والقبلية التي كانوا عليهوإذ بهذا العبد
+
+70
+00:06:43,930 --> 00:06:49,430
+الأسود الحباشي الذي كان ينظر إليه بأنه عبد وأسود
+
+71
+00:06:49,430 --> 00:06:55,070
+ومن بلاد الحبشة بلال ابن رباح يصبح أخا لأحد
+
+72
+00:06:55,070 --> 00:07:02,960
+الأحرار البيضخالد ابن رويحة وهو عربي، هذا حبشي
+
+73
+00:07:02,960 --> 00:07:09,820
+وهذا عربي، لا فرق بين عربي وأعجمي ولا أعجمي ولا
+
+74
+00:07:09,820 --> 00:07:15,820
+عربي إلا بالتقوى وأمثلة كثيرة في مؤاخات النبي صلى
+
+75
+00:07:15,820 --> 00:07:20,520
+الله عليه وسلم بين أصحابه وبين المهاجرين من مكة
+
+76
+00:07:20,520 --> 00:07:25,560
+والأنصار في المدينةأخى بين عبد أيضا كان مولى عند
+
+77
+00:07:25,560 --> 00:07:29,960
+النبي صلى الله عليه وسلم هو زيد ابن حارف زيد كان
+
+78
+00:07:29,960 --> 00:07:36,880
+عبد ومولى أخى بينه وبين عمه عمومين حمزة ابن عبد
+
+79
+00:07:36,880 --> 00:07:43,480
+المطلب سيد الشهداء أسد الله حمزةالعربي القرشي
+
+80
+00:07:43,480 --> 00:07:51,600
+الأصيل الزعيم القائد بينه بين عبد بين مولا أي دين
+
+81
+00:07:51,600 --> 00:07:57,920
+هذا دين عظيم الذابت كل هذه الفوارق والفروق بين
+
+82
+00:07:57,920 --> 00:08:03,760
+أتباعه وأصحابه عمار بن ياسر برضه الضعيف الغلبان
+
+83
+00:08:04,530 --> 00:08:11,590
+الفقير اللي كان يعني من عامة الناس يصبح أيضا أخ
+
+84
+00:08:11,590 --> 00:08:15,490
+اللي حذيفة بن اليامان سلمان الفارس من بلاد الفرس
+
+85
+00:08:15,490 --> 00:08:22,180
+ذو اللقنة واللهجة الأعجميةينسبه النبي صلى الله
+
+86
+00:08:22,180 --> 00:08:28,680
+عليه وسلم إلى آل بيته أولاد سلمان من آل البيت هذا
+
+87
+00:08:28,680 --> 00:08:33,380
+واحد منه في نصر وهو الأعجم الفارسي الذي جاء من
+
+88
+00:08:33,380 --> 00:08:39,480
+بلاد فارس ويصبح بلال العبد الحبشي يرتقي أعلى
+
+89
+00:08:39,480 --> 00:08:45,940
+الأماكن ارتقى سطح الكعبة المشرفة يصبح بالأذان الله
+
+90
+00:08:45,940 --> 00:08:50,510
+أكبر الله أكبرالله أكبر ما أعظم هذا الإسلام وهذا
+
+91
+00:08:50,510 --> 00:08:56,050
+الدين العظيم الذي لا يفرق بين أتباع ولا يميز بينهم
+
+92
+00:08:56,050 --> 00:09:01,370
+إن أكرمكم عند الله أتقاكم هذا ميزان التفضيل
+
+93
+00:09:01,370 --> 00:09:06,570
+والتكريم والتفاضل والمنزلة عند الله تعالى ليس
+
+94
+00:09:06,570 --> 00:09:10,750
+السواد ولا البياض ولا الشكل ولا اللون ولا الغنى
+
+95
+00:09:10,750 --> 00:09:18,190
+ولا الرتبة ولا المنزلة ولا غير ذلكوفي مقابل ذلك
+
+96
+00:09:18,190 --> 00:09:23,930
+فما فعله الإسلام ذم الإسلام وذم القرآن وذم النبي
+
+97
+00:09:23,930 --> 00:09:29,710
+صلى الله عليه وسلم العصبية تعصب إلى قبيلته أو إلى
+
+98
+00:09:29,710 --> 00:09:36,810
+حزبه أو جماعته دون عقيدته ودينه فقال من تقرأنا
+
+99
+00:09:36,810 --> 00:09:41,530
+حديثه تفضل فقال صلى الله عليه وسلم ليس مننا من دع
+
+100
+00:09:41,530 --> 00:09:46,670
+إلى عصبية وليس مننا من قاتل على عصبيةو أيضا حديث
+
+101
+00:09:46,670 --> 00:09:51,710
+آخر قريب منه هي عمية
+
+102
+00:09:51,710 --> 00:09:57,520
+يعني، يعني لا يدري تحت أي راية يقاتل؟يدعوا عصبية
+
+103
+00:09:57,520 --> 00:10:02,220
+أو ينصروا عصبية فقتلته جاهلية بارك الله فيك أحسن
+
+104
+00:10:02,220 --> 00:10:04,840
+يعني هذه بعض الأحاديث والأحاديث كثيرة في هذا
+
+105
+00:10:04,840 --> 00:10:09,420
+الجانب اللي يظم فيها النبي صلى الله عليه وسلم
+
+106
+00:10:09,420 --> 00:10:15,380
+العصبية والقبلية والتعصب والدعوة إلى العصبية أو
+
+107
+00:10:15,380 --> 00:10:22,650
+القبليةومن مات وهو يدعو لهذه الدعوة فتكون ميتته و
+
+108
+00:10:22,650 --> 00:10:28,950
+قتلته جاهلين ليست شرعية ولا دينية ولا ميتة في سبيل
+
+109
+00:10:28,950 --> 00:10:33,000
+اللهولذلك سؤال النبي عليه الصلاة والسلام عن الرجل
+
+110
+00:10:33,000 --> 00:10:38,280
+الرجل يقاتل شجاعة طالع قاتل عشان يبقى العنف شجاع
+
+111
+00:10:38,280 --> 00:10:46,020
+والرجل يقاتل حمية دافع بس طالع حمية ونخوة يقاتل مع
+
+112
+00:10:46,020 --> 00:10:50,700
+المسلمين والرجل يقاتل ليرا مكانه عشان يشوفوا الناس
+
+113
+00:10:50,700 --> 00:10:54,100
+ويدونه منزلة ورتمة ويخلوه قائد ويصير زعيم ما شاء
+
+114
+00:10:54,100 --> 00:10:58,260
+الله عليه بطل وقائد وبستحقإذا كانت هكذا نيته في
+
+115
+00:10:58,260 --> 00:11:03,400
+الخروج للقتال أي ذلك في سبيل الله؟ مين يا رسول
+
+116
+00:11:03,400 --> 00:11:07,040
+الله؟ البقاطل الشجاعة ولا نخوة؟ علشان تشوفين يا
+
+117
+00:11:07,040 --> 00:11:10,960
+بنت خالتك في المثل و الناس تشوفه تمتعها و تقول ما
+
+118
+00:11:10,960 --> 00:11:14,580
+شاء الله عليه بطل والله قائد والله قوي والله شجاع
+
+119
+00:11:14,580 --> 00:11:19,000
+مين فيهم في سبيل الله في هدول؟ طبعا ولا واحد فقال
+
+120
+00:11:19,000 --> 00:11:27,020
+عليه الصلاة والسلام ايش بقية الحديث؟ مين بتعرف؟من
+
+121
+00:11:27,020 --> 00:11:33,660
+قاتل لتكون كلمة الله هي العليا فهو في سبيل الله لا
+
+122
+00:11:33,660 --> 00:11:37,140
+هذا ولا هذا ولا هذا اللي ذكرته اللي في سبيل الله
+
+123
+00:11:37,140 --> 00:11:43,600
+من قاتل لتكون كلمة الله هي العليا فهو في سبيل الله
+
+124
+00:11:43,600 --> 00:11:51,600
+في يوم من الأيام لم يرق لبعض اليهود أن يجد
+
+125
+00:11:51,600 --> 00:11:58,120
+المسلمين موحدينومتحابين، أحد اليهود واسمه شاس بن
+
+126
+00:11:58,120 --> 00:12:04,880
+قيس، عارفينه؟ هذا الراجل اليهودي شاف الصحابة من
+
+127
+00:12:04,880 --> 00:12:09,140
+المهاجرين والأنصار قاعدين مع بعضيا الله أكبر هدول
+
+128
+00:12:09,140 --> 00:12:12,980
+اللي مبارح لسه كان في بينهم عداوة وقتال اليوم
+
+129
+00:12:12,980 --> 00:12:17,340
+جاعدين مع بعض ومتحابين وبتصامر ومتحدث فغازه هذا
+
+130
+00:12:17,340 --> 00:12:22,820
+الأمر فبعثه لما ليذكرهم بما كان عليه .. بما كانوا
+
+131
+00:12:22,820 --> 00:12:26,600
+عليه من الماضي من القتال والحروب وكذا راح للأوس
+
+132
+00:12:26,600 --> 00:12:31,520
+ايش انت؟ ايش دعوتك؟ هحطول واحد هيك بين سيام؟ اه مش
+
+133
+00:12:31,520 --> 00:12:37,490
+فيكم خير؟بنسى الواحد الجروح تبعه في يوم و ليلة و
+
+134
+00:12:37,490 --> 00:12:40,050
+لا تنين نسيتوا إيش عملوا فيكوا الأوس؟ نسيتوا إيش
+
+135
+00:12:40,050 --> 00:12:45,450
+عملوا فيكوا الخزرج؟ فكاد أن يفتن بينهم أو بينهما
+
+136
+00:12:45,450 --> 00:12:51,970
+كقبيلتين بل و بالفعل فتن بينهم و كاد يقتتلان الأوس
+
+137
+00:12:51,970 --> 00:12:56,270
+و الخزرج فكانوا يقتتلوا لو لأن تداركهم النبي صلى
+
+138
+00:12:56,270 --> 00:13:02,740
+الله عليه وسلموقال بدعوة الجاهلية وانا بين اظهركم
+
+139
+00:13:02,740 --> 00:13:06,040
+لسه ماموتش انا لسه انا حايل بين اظهركم عايش لسه
+
+140
+00:13:06,040 --> 00:13:10,280
+اذا وانا عايش وفي حياتي كنت رجعوا الى ما كنتم عليه
+
+141
+00:13:10,280 --> 00:13:15,140
+من القتال لا ترجعوا بعدي كفارا يضربوا بعضكم رقابة
+
+142
+00:13:15,140 --> 00:13:20,080
+بعض فلا ترجعوا الى الجاهلية والى ما كنتم عليه كل
+
+143
+00:13:20,080 --> 00:13:25,900
+هذه النصوص والاحاديث تبين يعني ان الاسلام يذوم
+
+144
+00:13:26,670 --> 00:13:31,930
+ويحذر وينفر من الدعوة إلى العصبية وإلى الحزبية
+
+145
+00:13:31,930 --> 00:13:37,350
+المنقوطة وإنما الإنسان يتعصب ويتمسك بدينه وعقيدته
+
+146
+00:13:37,350 --> 00:13:43,610
+ويلتف حولها وينتسب إليها وينتمي إليها ويعتز بها
+
+147
+00:13:43,610 --> 00:13:51,260
+ويفتخر بها دون هذه الدعوة الأخرىوقد ذكرنا ان ميزان
+
+148
+00:13:51,260 --> 00:13:57,080
+التفاضل عند الله بالتقوى ان اكرمكم عند الله اتقان
+
+149
+00:13:57,080 --> 00:14:02,400
+وفي وصيته صلى الله عليه وسلم يوم حجة الوداع اكد
+
+150
+00:14:02,400 --> 00:14:07,080
+هذا المعنى الجميل في وصية طويلة كان منها هذا
+
+151
+00:14:07,080 --> 00:14:11,360
+الكلام الجميل من تقرأنا اياه في وصية الرسول عليه
+
+152
+00:14:11,360 --> 00:14:16,060
+الصلاة والسلام وفي وصيته يوم حجة الوداع اكد هذا
+
+153
+00:14:16,060 --> 00:14:24,570
+المعنى الكريم فقاليا أيها الناس اه الى ان طبعا
+
+154
+00:14:24,570 --> 00:14:32,350
+صلحوها مكتوبة هي الا هي الا الا لافضله
+
+155
+00:14:32,350 --> 00:14:36,530
+بارك
+
+156
+00:14:36,530 --> 00:14:41,090
+الله فيك يه أحسن بخاطب الناس جميعا في هذا الموقف
+
+157
+00:14:41,090 --> 00:14:44,630
+العظيم في يوم حجة الوداع التي حجها النبي صلى الله
+
+158
+00:14:44,630 --> 00:14:52,700
+عليه وسلم وكانت أخر حجة له فأزال فيها الفوارق بين
+
+159
+00:14:52,700 --> 00:15:00,320
+الناس جميعا مدام ربكم واحد وأباكم واحد كلكم لآدم
+
+160
+00:15:00,320 --> 00:15:06,900
+كلنا بني آدم كلنا بشر فلا فضل لعربي على أعجمي ولا
+
+161
+00:15:06,900 --> 00:15:10,120
+لأعجمي على عربي ولا أبيض على أسود ولا أسود على
+
+162
+00:15:10,120 --> 00:15:16,080
+أبيض لماذا لا فضل لهم لأنهم كلهمخلقهم الله تعالى
+
+163
+00:15:16,080 --> 00:15:20,180
+خلق واحد، كلهم ولاة تسعة زي ما نقول، في بعضهم ولاة
+
+164
+00:15:20,180 --> 00:15:24,940
+سبعة، نشتز على ولاة السبعة، في تمانية، بس هؤلاء
+
+165
+00:15:24,940 --> 00:15:29,860
+مابيعيشوش يعني حسب ما يقولون، فهؤلاء الناس يرجعون
+
+166
+00:15:29,860 --> 00:15:35,320
+في نسبهم إلى آدم وحواء، كلنا بني آدم وبني حواء،
+
+167
+00:15:35,320 --> 00:15:38,880
+ليس هناك من يميز في الأصل ولا في الجنس ولا في
+
+168
+00:15:38,880 --> 00:15:46,340
+العرق ولا في كدهواستمر هذا المقياس والمعيار
+
+169
+00:15:46,340 --> 00:15:49,780
+والميزان في عهد الخلفاء الراشدين أبو بكر وعمر
+
+170
+00:15:49,780 --> 00:15:55,860
+وعثمان وعلي رضي الله عنهم أجمعين والصحابة أجمعين
+
+171
+00:15:55,860 --> 00:15:58,980
+وكانت
+
+172
+00:15:58,980 --> 00:16:03,500
+دولة الإسلام في ظل هذه الخلافة الراشدة اللي حكم
+
+173
+00:16:03,500 --> 00:16:10,400
+فيها أولئك الخلفاء المعروفين والمذكورين ضمت أجناسا
+
+174
+00:16:10,400 --> 00:16:17,040
+مختلفةومتنوع منها العرب ومنها الروم ومنها الفرس
+
+175
+00:16:17,040 --> 00:16:20,960
+وأهل الحبشة وغيرهم من الأجناس لم يأتي الإسلام
+
+176
+00:16:20,960 --> 00:16:25,960
+للعرب ما قال يا أيها العرب أنا جئت إليك يا أيها
+
+177
+00:16:25,960 --> 00:16:30,500
+الناس وإني رسول الله إليكم جميع وما أرسلناك إلا
+
+178
+00:16:30,500 --> 00:16:37,640
+كافة للناس مش للعربوما أرسلناك إلا رحمة للعرب فقط
+
+179
+00:16:37,640 --> 00:16:42,060
+ولا للعالمين؟ وهذا القرآن جاء للعرب ولا للعالمين
+
+180
+00:16:42,060 --> 00:16:46,860
+نذيرة؟ العالمين نذيرة لأن هذا القرآن وهذا الإسلام
+
+181
+00:16:46,860 --> 00:16:52,200
+وهذا الدين جاء لجميع الناس فلا فرق ولا تمييز في
+
+182
+00:16:52,200 --> 00:16:59,340
+هذا الدين بين جنس واخروانما الفضل والميزان
+
+183
+00:16:59,340 --> 00:17:06,400
+والتفاضل هو في التقوى والعمل الصالح حتى من علماء
+
+184
+00:17:06,400 --> 00:17:09,720
+المسلمين الكبار الذين اشتهروا في تاريخ الإسلام
+
+185
+00:17:09,720 --> 00:17:15,410
+تاريخ المسلمين أكثرهم لم يكنوا عربامع ان القرآن
+
+186
+00:17:15,410 --> 00:17:19,410
+يعني بلسانة عربية مبين ونزل اول ما نزل على العرب
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+187
+00:17:19,410 --> 00:17:23,570
+وفي البيئة العربية وفي مكة وفي المدينة لكن هو
+
+188
+00:17:23,570 --> 00:17:29,810
+لجميع الناس كما قلنا وكان اكثر علماء وفقهاء
+
+189
+00:17:29,810 --> 00:17:34,670
+المسلمين من غير العرب الإمام البخاري من بخارة
+
+190
+00:17:34,670 --> 00:17:41,510
+وغيرهم من العلماء الكبار يعني كانوا من غير العرب
+
+191
+00:17:41,510 --> 00:17:43,530
+الذين ينطقون بالعربي
+
+192
+00:17:45,960 --> 00:17:51,440
+طب كل هذا مقدم و تمهيد علشان نمهد و نهيئ الأمر
+
+193
+00:17:51,440 --> 00:17:57,060
+لموضوع القومية و فكرة القومية و كيف دخلت القومية
+
+194
+00:17:57,060 --> 00:18:02,820
+على العالم العربي و الإسلامي قبل أن نتعرف على ذلك
+
+195
+00:18:02,820 --> 00:18:11,300
+نلمح و نلحظ أن أصل و أساس هذه الفكرةأصلها و أساسها
+
+196
+00:18:11,300 --> 00:18:16,920
+من وين؟ من أوروبا غرب أجنبي وافق ولم يكن أو لم تكن
+
+197
+00:18:16,920 --> 00:18:22,940
+بين معروفة بين المسلمين عرفتها أوروبا عرفت القومية
+
+198
+00:18:23,710 --> 00:18:31,190
+وتخلت عنها بعد أن اقتوت بنارها هناك قامة حروب في
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+199
+00:18:31,190 --> 00:18:36,590
+أوروبا بين دول كبرى ومعروفة بسبب القوميات والتحذب
+
+200
+00:18:36,590 --> 00:18:42,190
+القومية كان كل صاحب قومية يعتقد بنفسه أن هو الأفضل
+
+201
+00:18:42,190 --> 00:18:47,150
+والذي ينبغي أن يسود هتلر كان يقول عرق القاري هو
+
+202
+00:18:47,150 --> 00:18:51,870
+الأفضل و الدم الألماني هو أفضل الدماءوالاخر
+
+203
+00:18:51,870 --> 00:18:55,530
+نابليون كان ايضا يريد ان يكون امبراطورية والعرق
+
+204
+00:18:55,530 --> 00:18:59,010
+الفرنسي والدم الفرنسي وغيره من هؤلاء الناس اللي
+
+205
+00:18:59,010 --> 00:19:04,610
+كانوا يحاولون يعني ان يسيطروا فتصادموا بالقوميات
+
+206
+00:19:04,610 --> 00:19:08,170
+الأخرى المقابلة هذا صاحب قومي مافي غيرك صاحب قومي
+
+207
+00:19:08,170 --> 00:19:12,090
+اذا انت بتفتخر او تعتز فصار هناك تصامم وتصارع
+
+208
+00:19:12,090 --> 00:19:17,350
+وصراع القوميات مما جعل اوروبا ان تتخلى عن هذه
+
+209
+00:19:17,350 --> 00:19:21,620
+الدعاة لان اوروبا كلها تتجه وامريكا معاهاإلى
+
+210
+00:19:21,620 --> 00:19:26,620
+التوحد وإلى الوحدة وإلى تناسي ما بينهم من الفروق
+
+211
+00:19:26,620 --> 00:19:31,360
+في الولايات المتحدة الأمريكية الاتحاد الأوروبي
+
+212
+00:19:31,360 --> 00:19:35,580
+الأمم المتحدة لأن اجتمعت كل الأمم في أمم متحدة
+
+213
+00:19:35,580 --> 00:19:39,820
+مجلس الأمن وهكذا الناس بتتوحد والعالم بتتوحد وإحنا
+
+214
+00:19:39,820 --> 00:19:44,380
+الشاطر اللي قاعد بينقسم وبيتفرق وبيدعو إلىيعني
+
+215
+00:19:44,380 --> 00:19:47,660
+قوميات الأكراد بدهم ينفصلوا عن تركيا بدهم القومية
+
+216
+00:19:47,660 --> 00:19:50,360
+التركية بدهم ينفصلوا عن العراق بدنا برضه احنا نكون
+
+217
+00:19:50,360 --> 00:19:55,380
+لوحدنا وكذا السودان في جنوب السودان في يعني نصارى
+
+218
+00:19:55,380 --> 00:20:00,600
+وكذا فهذه القومية اخوات كما قلنا الأوروبا تخلت
+
+219
+00:20:00,600 --> 00:20:05,580
+عنها وجربت برضه الوطنية وتخلت عنها ونحن كعرب
+
+220
+00:20:05,580 --> 00:20:11,560
+ومسلمين والحمد لله رب العالمين استوردناها وأخدناها
+
+221
+00:20:11,560 --> 00:20:19,510
+وجربناهاجربناها بعد ما جربوها و فشلوا فيه و اكتووا
+
+222
+00:20:19,510 --> 00:20:22,750
+بنار زي ما يقولوا في المثل اللي بيجرب اللي مجرب
+
+223
+00:20:22,750 --> 00:20:28,610
+ولا اللي بيجرب اللي مجرب عقله مخرب بقى اللغة حافظة
+
+224
+00:20:28,610 --> 00:20:36,960
+فهذا حاجة مجربة و ثبتة فشلوثبت ضررها، هل نبدأ من
+
+225
+00:20:36,960 --> 00:20:40,320
+الصفر و من أول و جديد نبدأ نجرب فيها، بركز ذبطت
+
+226
+00:20:40,320 --> 00:20:43,900
+معانا، مش هتظبط معانا، إذا مع أهلها مش ذبطة، ده
+
+227
+00:20:43,900 --> 00:20:47,100
+تظبط يعني جوها مافلحش في أرضه، ده افلع في أرض
+
+228
+00:20:47,100 --> 00:20:51,400
+الناس، إذا كانت هي مافلحتش، كانت شيوعيةالشيوعية
+
+229
+00:20:51,400 --> 00:20:56,840
+يعني في بلادها سقطت وانتهت ولازال بعض الشيوعيين أو
+
+230
+00:20:56,840 --> 00:21:00,060
+كثير منهم في بلدان أخرى يتغنون إلى اليوم
+
+231
+00:21:00,060 --> 00:21:04,340
+بالشيوعيين إذا في بلادها عند أهلها فشلت وراسبت
+
+232
+00:21:04,340 --> 00:21:07,980
+ومانجحتش في الامتحان وسقطت واحنا بنروح ناخدها
+
+233
+00:21:07,980 --> 00:21:16,060
+وننجح عنها وكانت
+
+234
+00:21:16,060 --> 00:21:22,950
+هذه الدعوة إلى القومية على أشدهاوبدأ كثير من أصحاب
+
+235
+00:21:22,950 --> 00:21:28,310
+القوميات كلهم يدعو إلى قوميته وكلهم يغني على ليلة
+
+236
+00:21:28,310 --> 00:21:35,190
+كما يقول الشعب لكن كان في قوميتين هم أو هما من أشد
+
+237
+00:21:35,190 --> 00:21:41,950
+أو أكثر القوميات تأثيرا وفتنة على العالم الإسلامي
+
+238
+00:21:41,950 --> 00:21:47,490
+اللي هي القومية .. مين و مين؟ قومية طورانية
+
+239
+00:21:47,490 --> 00:21:50,110
+والقومية العربية
+
+240
+00:21:51,810 --> 00:21:56,450
+القوميتين كانوا أثر كبير وبالغ في حياة المسلمين
+
+241
+00:21:57,380 --> 00:22:02,440
+وكانت الاتنين القومية الطورانية والعربية سببا في
+
+242
+00:22:02,440 --> 00:22:07,520
+إلغاء الخلافة الإسلامية العثمانية وسبب في إلغاء
+
+243
+00:22:07,520 --> 00:22:13,800
+فكرة الجامعة الإسلامية بس مش اللي في غزة .. فكرة
+
+244
+00:22:13,800 --> 00:22:19,560
+جامعة إسلامية تانية تجمع المسلمين في جامعة واحدة
+
+245
+00:22:19,560 --> 00:22:27,110
+بدل أو استبدلت بفكرة الجامعة العربية اليومثم ظهرت
+
+246
+00:22:27,110 --> 00:22:32,490
+بعد ذلك الوطنية والدعوة إلى القومية وهي الدعوة
+
+247
+00:22:32,490 --> 00:22:36,770
+التي تجمع الناس على حسب اللغة والمكان والمصالح فكل
+
+248
+00:22:36,770 --> 00:22:42,430
+أهل اللغة تجمعهم لغة واحدة ومكان واحد ومصالح واحدة
+
+249
+00:22:43,010 --> 00:22:47,230
+يدعون إلى الاهتمام بهذا الوطن الذي يعيشون فيه
+
+250
+00:22:47,230 --> 00:22:54,170
+كمكان واحد يجمع أصحاب لغة واحدة ومصالح واحدة
+
+251
+00:22:54,170 --> 00:23:01,050
+والدين ليس هو الأساس الذي يجمعهم ويوحدهمويشترطون
+
+252
+00:23:01,050 --> 00:23:05,250
+ألا يكون الدين عاملا من عوامل التجميل وإلا إذا
+
+253
+00:23:05,250 --> 00:23:11,130
+بدنا نعتمد الدين هيفرق الدين بيننا فكذا اعتبرا
+
+254
+00:23:11,130 --> 00:23:15,570
+الدين عامل فرقة هل الدين في يوم اليوم كان عامل
+
+255
+00:23:15,570 --> 00:23:20,470
+فرقة ولا عامل توحد عامل توحد دائما الدين يدعو إلى
+
+256
+00:23:20,470 --> 00:23:23,870
+التوحد وإلى الوحدة وإلى التقالف وإلى التقارب ونبذ
+
+257
+00:23:23,870 --> 00:23:28,670
+الخلاف ونبذ الفرقة ونبذ كذاولا يدعو الدين إلى
+
+258
+00:23:28,670 --> 00:23:35,730
+التفرق والشقاء إذا ما الأساس الذي تقوم أو يقوم
+
+259
+00:23:35,730 --> 00:23:41,770
+عليه الولاء أو المحبة في دعوة الوطنية؟ مدان بدهمش
+
+260
+00:23:41,770 --> 00:23:46,950
+الدين على أساس إيش بتجمعه في الفكرة الوطنية؟
+
+261
+00:23:46,950 --> 00:23:52,800
+فضلالك، اه حطمة، على فكرة المواطنةأن كنا مواطنين
+
+262
+00:23:52,800 --> 00:23:57,120
+في هذا المكان أو في هذه البلد أو في هذا الوطن
+
+263
+00:23:57,120 --> 00:24:01,680
+فالذي يجمعنا هو جامع المواطن أننا مواطنون وليس ..
+
+264
+00:24:01,680 --> 00:24:05,180
+و ليس أننا أصحاب دين واحد ولا أهل دين واحد ولا
+
+265
+00:24:05,180 --> 00:24:09,000
+أننا كلنا مسلمون أو أننا كلنا كذا مدمن كلنا
+
+266
+00:24:09,000 --> 00:24:13,420
+مواطنون في هذا البلد فهذا الجامع الذي يجمع بيننا
+
+267
+00:24:13,420 --> 00:24:20,890
+والدين عامل يفرقناسواء كان هذا الذي في هذا الوطن
+
+268
+00:24:20,890 --> 00:24:28,090
+مسلم ولا كافر ولا فاسق ولا ملحد ولا كذا كله في هذا
+
+269
+00:24:28,090 --> 00:24:33,670
+الوطن سواء ينظر اليه سواء هذا دعوة الوطنية وسنتعرف
+
+270
+00:24:33,670 --> 00:24:37,810
+عليها اكثر في تعريف بها والحديث عنها احنا الان
+
+271
+00:24:37,810 --> 00:24:41,770
+بتتكلم عن كيف تدرجت الأمور من القومية الى الدعوة
+
+272
+00:24:41,770 --> 00:24:47,920
+الوطنيةما هو الهدف من هذه الدعوة القومية مدام
+
+273
+00:24:47,920 --> 00:24:51,740
+التجمع فيها على أساس المواطنة وإقصاء وإلغاء
+
+274
+00:24:51,740 --> 00:24:53,040
+واستثناء الدين؟
+
+275
+00:24:56,420 --> 00:25:01,500
+يعني بدهم المسلمين هدول يندمجوا وينخلطوا في غيرهم
+
+276
+00:25:01,500 --> 00:25:06,800
+من أمم الكفر تذوب شخصيتهم المتميزة المستقلة
+
+277
+00:25:06,800 --> 00:25:12,860
+المعروفة فيصبح جزء من المواطني زيهم زي غيهم وليس
+
+278
+00:25:12,860 --> 00:25:17,340
+لهم أي ميزة أو تميز أو شخصية مستقلة أو متميزة أو
+
+279
+00:25:17,340 --> 00:25:21,440
+أن دينهم هو الحق أو المهيمن أو المسيطر أو كدههذا
+
+280
+00:25:21,440 --> 00:25:24,560
+قد يكون مقبول في بلاد الغرب في بلاد الكفر لكن في
+
+281
+00:25:24,560 --> 00:25:29,100
+بلاد المسلمين ونحن مسلمين أن يكون الإسلام والدين
+
+282
+00:25:29,100 --> 00:25:33,900
+جزء هامشي جانبي ثانوي ليس هو الجامع الذي يجمع نحن
+
+283
+00:25:33,900 --> 00:25:37,980
+كلنا مسلمون وإذا كان هنا قلة من غير المسلمين فلهم
+
+284
+00:25:37,980 --> 00:25:45,680
+كل الاحترام والتقدير بيننا ديننايأمرنا بذلك، ديننا
+
+285
+00:25:45,680 --> 00:25:50,220
+يأمرنا أن نعطيهم حقوقهم كاملة، مادام المسالمين غير
+
+286
+00:25:50,220 --> 00:25:55,230
+معادين لنا ولا محاربين لناود قصة طويلة لو بدنا
+
+287
+00:25:55,230 --> 00:25:59,310
+نقود فيها يكفي أن نشير إشارة إلى قول الله تعالى لا
+
+288
+00:25:59,310 --> 00:26:05,530
+ينهاكم الله عن الذين لم يقاتلوكم في الدين ولم
+
+289
+00:26:05,530 --> 00:26:12,730
+يخرجوكم من دياركم أن تبروهم وتقصدوا إليه أي واحد
+
+290
+00:26:12,730 --> 00:26:15,530
+لا بيقاتلنا في ديننا ولا بعدينا ولا بيخرجنا من
+
+291
+00:26:15,530 --> 00:26:22,300
+أرضناوعايش معانا بخير وبسلام وما بيعتديش علينا فلا
+
+292
+00:26:22,300 --> 00:26:26,320
+يجوز لنا أن نعتدي عليه بل يجب علينا أن نبره والبر
+
+293
+00:26:26,320 --> 00:26:32,320
+يعني إيه؟ الاحسن أن نحسن إليه وأن نقصط معاه والقصة
+
+294
+00:26:32,320 --> 00:26:36,140
+هو العدل أن نعدل معاه يعني لو كان هو صاحب الحق في
+
+295
+00:26:36,140 --> 00:26:41,000
+قضية بينه وبين مسلم نحكم لغير المسلم بالحق لأن هو
+
+296
+00:26:41,000 --> 00:26:45,200
+صاحب الحق مش عشان هذا مسلم بننميلله لأ إذا كان غير
+
+297
+00:26:45,200 --> 00:26:49,210
+المسلم هو صاحب الحقفي هذه القضية فنحكم بيننا لأن
+
+298
+00:26:49,210 --> 00:26:53,170
+ربنا أمرنا إذا حكمنا أن نحكم بالعدل مش بين
+
+299
+00:26:53,170 --> 00:26:59,030
+المسلمين بس وإذا حكمتم بين الناس أن تحكموا بالعدل
+
+300
+00:26:59,030 --> 00:27:05,770
+فالعدل قيمة يعني ليه من القيم ومبدأ من المبادئ
+
+301
+00:27:05,770 --> 00:27:09,290
+اللي تحكم الجميع مش فقط المسلمين أو تحكم بين
+
+302
+00:27:09,290 --> 00:27:14,330
+المسلمينفإذا إقامة الولاية يا أخوات على أساس الوطن
+
+303
+00:27:14,330 --> 00:27:18,070
+أو غيره من هذه الدعاوى الجاهلية هذا مشروع ثبت فشله
+
+304
+00:27:18,070 --> 00:27:20,810
+سواء في القومية أو في الوطنية عند أصحابه وأهله
+
+305
+00:27:20,810 --> 00:27:23,930
+ونحن حينما جربناه في بلادنا العربية والإسلامية
+
+306
+00:27:23,930 --> 00:27:29,570
+أيضا لم ينجح وثبت فشلهفليس الولاء في الأمة
+
+307
+00:27:29,570 --> 00:27:34,750
+الإسلامية على الأسس الوطنية التي من شأنها أن تفرق
+
+308
+00:27:34,750 --> 00:27:38,790
+المسلمين وتخالف بينهم بل الولاء في المسلمين يقوم
+
+309
+00:27:38,790 --> 00:27:45,580
+على أساس العقيدة الإيمان إنما المؤمنوناخوة
+
+310
+00:27:45,580 --> 00:27:52,520
+والمؤمنون والمؤمنات بعضهم أولياء بعض هذا هو الجامع
+
+311
+00:27:52,520 --> 00:27:58,140
+وهذا هو الرابط الذي يجمع ويربط بين المسلمين بعضهم
+
+312
+00:27:58,140 --> 00:28:03,220
+ببعض ليس القومية ولا الوطنية نتحدث في المحاضرة
+
+313
+00:28:03,220 --> 00:28:05,680
+القادمة ان شاء الله ويارد كنا نحضرها ده الموضوع
+
+314
+00:28:05,680 --> 00:28:11,270
+القادم في تعريف القومية تعرفي على القوميةونشأت
+
+315
+00:28:11,270 --> 00:28:16,920
+القومية في العالم العربي في الآن ملاحظةالنشأة
+
+316
+00:28:16,920 --> 00:28:21,660
+القومية كعنوان عام هذا نشأة القومية في أوروبا مش
+
+317
+00:28:21,660 --> 00:28:25,100
+مطلوب منها يعني نقراها قراءة لكن مش هتفهم المعنى
+
+318
+00:28:25,100 --> 00:28:29,920
+احنا هنبدأ من نشأة القومية في العالم العربي ثم
+
+319
+00:28:29,920 --> 00:28:35,520
+نتعرف بعد ذلك على تجاوزات الفكر القومي واخر شئ
+
+320
+00:28:35,520 --> 00:28:40,380
+نبين فيه موقف الإسلام من دعوة القومية كما بياننا
+
+321
+00:28:40,380 --> 00:28:45,090
+موقف الإسلام من قبلمن دعوة العلمانية أو من مبدأ
+
+322
+00:28:45,090 --> 00:28:49,630
+مذهب العلمانية في المحاضرة القادمة ان شاء الله
+
+323
+00:28:49,630 --> 00:28:54,110
+نتعرف على كل هذه الأمور والله يعطيكم العافية
+
diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/sgC6Q2N9UEQ_raw.json b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/sgC6Q2N9UEQ_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..d4ff4355dcfbc12b292e9b8597c39663ef196b4b
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/sgC6Q2N9UEQ_raw.json
@@ -0,0 +1 @@
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النبي عليه الصلاة والسلام فمطلوب أن نجاري هؤلاء في اختلاطهم في مدرسهم وجامعاتهم ونعمل مثلهم", "tokens": [2407, 6027, 5016, 16254, 12984, 7251, 24793, 1211, 29910, 23275, 35525, 19452, 4032, 41193, 1863, 14407, 14739, 36178, 24793, 5296, 31377, 2304, 6055, 30544, 14407, 13412, 9778, 9381, 36081, 24793, 9673, 14851, 4587, 1211, 36145, 5551, 5016, 3794, 1863, 2423, 8315, 3794, 14739, 6055, 5016, 3794, 1863, 14407, 4032, 28814, 1863, 5551, 3794, 16606, 14407, 14739, 6055, 7435, 2655, 1863, 3555, 14407, 11933, 3794, 16606, 2655, 16095, 23758, 9673, 30543, 5172, 25124, 2288, 3615, 1829, 37037, 15730, 37495, 22653, 9673, 44510, 10721, 25124, 2288, 3615, 1829, 13672, 1829, 45030, 19528, 8315, 11933, 25528, 3224, 28239, 21292, 47356, 31767, 15040, 3660, 16070, 3794, 37440, 6156, 2304, 9566, 1211, 37746, 14739, 8717, 7435, 9640, 1829, 8032, 33604, 1211, 16606, 8978, 1975, 46456, 1211, 41193, 16095, 8978, 3714, 3215, 2288, 3794, 16095, 49610, 10943, 3615, 9307, 16095, 4032, 1863, 25957, 1211, 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اللي في الآخر، فضلا كمان مرة؟", "tokens": [4117, 33911, 25961, 2655, 11203, 995, 38149, 11296, 20666, 47341, 6027, 8978, 5551, 12984, 1863, 16606, 16490, 2288, 29245, 11296, 20449, 16095, 34051, 1975, 46456, 1211, 41193, 11296, 8978, 16095, 34051, 9122, 15730, 12399, 47525, 8315, 8717, 14851, 3615, 43042, 29910, 23275, 5296, 1863, 2288, 7578, 37495, 22653, 23758, 2423, 2407, 11242, 3615, 5551, 12610, 995, 8717, 7435, 3215, 3714, 9957, 9154, 16247, 9778, 2407, 9307, 13672, 1829, 19446, 8608, 2304, 3615, 8315, 16095, 12399, 37893, 13672, 1829, 5551, 46456, 13672, 1829, 8978, 6024, 95, 34740, 12399, 6156, 11242, 15040, 9122, 2304, 7649, 3714, 25720, 22807], "avg_logprob": -0.16607602601198806, "compression_ratio": 1.7720207253886011, "no_speech_prob": 0.0, "words": [{"start": 2111.63, "end": 2111.93, "word": "كيف", "probability": 0.9716796875}, {"start": 2111.93, "end": 2112.79, "word": " كانت", "probability": 0.9814453125}, {"start": 2112.79, "end": 2113.25, "word": " علاقتها", 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الإسلامي والسيار المغازي واضح هذا الدور ولكن كان دورها دور اللائق والملائم لطبيعة تسخي المرضى وتسعفهم وتسخي المجاهدين وتطهو لهم وتحضر لهم الطعام والشراب وغير ذلك مما تقدر عليه المرأة واللي شاركت في الجهاد بسلاحها وعتادها وكذا كانوا قلائل", "tokens": [26890, 4117, 21984, 8978, 4117, 25961, 5296, 11296, 11778, 13063, 11331, 49975, 8978, 25724, 11296, 3215, 9673, 2288, 10721, 3660, 13412, 9640, 4117, 2655, 4032, 41185, 16712, 9640, 1829, 9778, 33688, 3794, 37440, 1829, 16070, 3794, 1829, 9640, 9673, 17082, 31377, 1829, 4032, 46958, 5016, 23758, 32748, 13063, 35525, 19452, 25961, 11778, 13063, 11296, 11778, 13063, 13672, 16373, 4587, 4032, 45340, 1211, 16373, 2304, 5296, 9566, 21292, 27884, 6055, 3794, 9778, 1829, 9673, 43042, 7578, 34683, 3794, 3615, 5172, 16095, 34683, 3794, 9778, 1829, 9673, 7435, 40294, 3215, 9957, 34683, 9566, 3224, 2407, 5296, 16095, 34683, 5016, 11242, 2288, 5296, 16095, 41950, 3615, 10943, 16070, 46309, 16758, 4032, 17082, 13546, 29910, 23275, 3714, 15042, 6055, 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2584.76, "word": " ليس", "probability": 0.961669921875}, {"start": 2584.76, "end": 2584.96, "word": " لها", "probability": 0.975830078125}, {"start": 2584.96, "end": 2585.42, "word": " أساس", "probability": 0.9705403645833334}, {"start": 2585.42, "end": 2586.1, "word": " من", "probability": 0.99072265625}, {"start": 2586.1, "end": 2586.86, "word": " الصحة", "probability": 0.9920247395833334}, {"start": 2586.86, "end": 2587.14, "word": " يعني", "probability": 0.849853515625}, {"start": 2587.14, "end": 2587.68, "word": " ننهي", "probability": 0.876220703125}, {"start": 2587.68, "end": 2587.9, "word": " و", "probability": 0.9951171875}, {"start": 2587.9, "end": 2588.46, "word": " نختم", "probability": 0.9285481770833334}, {"start": 2588.46, "end": 2588.84, "word": " بهذا", "probability": 0.965087890625}, {"start": 2588.84, "end": 2589.54, "word": " الكلام", "probability": 0.9635416666666666}], "temperature": 1.0}, {"id": 112, "seek": 260519, "start": 2590.56, "end": 2605.2, "text": "موضوع 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"probability": 0.9435221354166666}, {"start": 2592.02, "end": 2593.72, "word": " وسائل", "probability": 0.9596354166666666}, {"start": 2593.72, "end": 2594.3, "word": " التغريب", "probability": 0.9912109375}, {"start": 2594.3, "end": 2595.02, "word": " لنتقل", "probability": 0.9019775390625}, {"start": 2595.02, "end": 2595.42, "word": " في", "probability": 0.6611328125}, {"start": 2595.42, "end": 2596.02, "word": " المحاضرة", "probability": 0.984619140625}, {"start": 2596.02, "end": 2596.56, "word": " القادمة", "probability": 0.9900716145833334}, {"start": 2596.56, "end": 2596.68, "word": " إن", "probability": 0.27490234375}, {"start": 2596.68, "end": 2596.84, "word": " شاء", "probability": 0.983642578125}, {"start": 2596.84, "end": 2597.02, "word": " الله", "probability": 0.95556640625}, {"start": 2597.02, "end": 2597.58, "word": " للحديث", "probability": 0.9036865234375}, {"start": 2597.58, "end": 2597.74, "word": " عن", "probability": 0.99267578125}, {"start": 2597.74, "end": 2598.14, "word": " رابع", "probability": 0.9235026041666666}, {"start": 2598.14, "end": 2598.66, "word": " وسائل", "probability": 0.9928385416666666}, {"start": 2598.66, "end": 2599.3, "word": " التغريب", "probability": 0.9979248046875}, {"start": 2599.3, "end": 2600.58, "word": " العولمة", "probability": 0.7809244791666666}, {"start": 2600.58, "end": 2601.62, "word": " وبارك", "probability": 0.86328125}, {"start": 2601.62, "end": 2601.78, "word": " الله", "probability": 0.9404296875}, {"start": 2601.78, "end": 2602.32, "word": " فيكم", "probability": 0.968505859375}, {"start": 2602.32, "end": 2603.54, "word": " والسلام", "probability": 0.9329427083333334}, {"start": 2603.54, "end": 2603.96, "word": " عليكم", "probability": 0.94482421875}, {"start": 2603.96, "end": 2604.38, "word": " ورحمة", "probability": 0.9796142578125}, {"start": 2604.38, "end": 2604.62, "word": " الله", "probability": 0.98046875}, {"start": 2604.62, "end": 2605.2, "word": " وبركاته", "probability": 0.9248046875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2605.69675, "duration_after_vad": 2531.636874999993}
\ No newline at end of file
diff --git a/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/zfc67AZsCsk_raw.srt b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/zfc67AZsCsk_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..de6d4b6896efbc6bfb37006873a89acad48df399
--- /dev/null
+++ b/SKIP:::PL9fwy3NUQKwZZ8ASUiLEKVKvwcEdfmB_y/zfc67AZsCsk_raw.srt
@@ -0,0 +1,1996 @@
+1
+00:00:21,040 --> 00:00:24,220
+الحمد لله يا رب العالمين والصلاة والسلام على أشرف
+
+2
+00:00:24,220 --> 00:00:28,500
+الخلق وسيد المرسلين سيدنا محمد وعلى آله وصحبه
+
+3
+00:00:28,500 --> 00:00:32,880
+أجمعين اللهم لا علم لنا إلا ما علمتنا إنك أنت
+
+4
+00:00:32,880 --> 00:00:38,240
+العليم الحكيم اللهم علمنا ما ينفعنا وانفعنا بما
+
+5
+00:00:38,240 --> 00:00:42,700
+علمتنا وازدنا علمة أمين يا رب العالمين أما بعد
+
+6
+00:00:44,620 --> 00:00:47,760
+لازمنا يا أخوات في الحديث عن وسائل علمانة المجتمع
+
+7
+00:00:47,760 --> 00:00:52,160
+وكنا قد ذكرنا بعض هذه الوسائل أو أكثر هذه الوسائل
+
+8
+00:00:52,160 --> 00:00:59,300
+و هي 6 وسائل كان الوسيلة الأولى الحديث عنها علمانة
+
+9
+00:00:59,300 --> 00:01:06,330
+التعليم ثم علمانة الإعلام مع علمانة القوانينمع
+
+10
+00:01:06,330 --> 00:01:12,010
+العلمانة من خلال الحادثة في الأدب والفكر ثم كان
+
+11
+00:01:12,010 --> 00:01:15,170
+آخر الحديث في المحاضرة الماضية العلمانة من خلال
+
+12
+00:01:15,170 --> 00:01:21,470
+الدسائس الفكرية اللادينية وتوقفنا عنده سادس وسائل
+
+13
+00:01:21,470 --> 00:01:25,730
+علمانة المجتمع و هي العلمانة من خلال إخماد الحركات
+
+14
+00:01:25,730 --> 00:01:27,350
+الإسلامية
+
+15
+00:01:44,420 --> 00:01:47,540
+أو ميارة بمحاربة الحركات الإسلامية ممكن نعبر عنها
+
+16
+00:01:47,540 --> 00:01:52,460
+بانواع آخر وتشويه الصحوة الإسلامية فهناك هجمة شرسة
+
+17
+00:01:52,460 --> 00:01:59,600
+حول الدعوة الإسلامية ودين الإسلام ومن يمثله ومن
+
+18
+00:01:59,600 --> 00:02:03,880
+يحمله ومن يحمل هذا المشروع مشروع الإسلام ويريد أن
+
+19
+00:02:03,880 --> 00:02:09,960
+يستعيد المجد الإسلامي والحكم الإسلامي في الأرض كل
+
+20
+00:02:09,960 --> 00:02:17,550
+هؤلاء يحاربوا ويشوهوا وتشوه صورتهمبدل ان يطعن
+
+21
+00:02:17,550 --> 00:02:21,810
+بالاسلام كدين او كعقيدة، لم يجرؤ احد اليوم ان يطعن
+
+22
+00:02:21,810 --> 00:02:26,630
+به كعقيدة ودين ولكن طعن فيه من خلال من يحمله
+
+23
+00:02:26,630 --> 00:02:31,430
+ويدافع عنه، هذه الوسيلة
+
+24
+00:02:31,430 --> 00:02:36,400
+الحديثة لأعداء الإسلاميعني كانوا قديما يتجرؤون على
+
+25
+00:02:36,400 --> 00:02:41,120
+الإسلام وعلى العقيدة وعلى الدين واليوم لا يتجرؤون
+
+26
+00:02:41,120 --> 00:02:45,060
+لأنهم يعلمون أن هذه الصحوة الإسلامية وهذه الدعوة
+
+27
+00:02:45,060 --> 00:02:49,980
+بدأت تنتشر وتغلغلت في أعماق المجتمعات كلها فصاروا
+
+28
+00:02:49,980 --> 00:02:55,120
+يطعنون ويشوهون صورة من يحمل هذه الدعوة وهذه
+
+29
+00:02:55,120 --> 00:03:02,490
+العقيدة وهذا الإسلامفبعد أن رحل الاستعمار بكل
+
+30
+00:03:02,490 --> 00:03:07,530
+أشكاله من البلاد الإسلامية التي كان يحتلها هو رحل
+
+31
+00:03:07,530 --> 00:03:15,070
+من هنا ولكن ترك وراقه وكلاء ونواب ينوبون عنه في
+
+32
+00:03:15,070 --> 00:03:20,390
+مخططاته هؤلاء الوكلاء والنواب هم من أبناء المسلمين
+
+33
+00:03:20,390 --> 00:03:26,850
+أنفسهم من أبناء جلداتناو استبدل الاستعمار اللذي
+
+34
+00:03:26,850 --> 00:03:32,170
+كان عليه بهذه الزمرة الحاكمة من العرب والمسلمين
+
+35
+00:03:32,170 --> 00:03:35,890
+بعد تمثيليات
+
+36
+00:03:35,890 --> 00:03:40,970
+متكررة فيما عرف بالانقلابات العسكرية كان كل فترة و
+
+37
+00:03:40,970 --> 00:03:44,250
+الأخرى تمر على بعض البلدان العربية والإسلامية
+
+38
+00:03:44,250 --> 00:03:49,710
+انقلابات حتى استقر حكم الحكومات والأنظمةالقائمة
+
+39
+00:03:49,710 --> 00:03:56,990
+اليوم منها من قضى نحبه ومنهم من ينتظر أن ينتهي
+
+40
+00:03:56,990 --> 00:04:01,510
+أجله ودوره لأن الشعوب العربية والإسلامية استيقظت
+
+41
+00:04:01,510 --> 00:04:07,690
+أخيرا والحمد لله على ظلم الظالمين وما عدت تقبل
+
+42
+00:04:07,690 --> 00:04:13,410
+بهذا إلى الأبدولكن هذا الحال الذي كانت عليه هذه
+
+43
+00:04:13,410 --> 00:04:19,950
+الدول وهذه الشعوب من قبل هؤلاء المتنفذون والوكالاء
+
+44
+00:04:19,950 --> 00:04:25,370
+والمعاونون للاستعمار الذين حكموا وتحكموا في رقاب
+
+45
+00:04:25,370 --> 00:04:30,900
+الأمة قاموا بمحاربةالحركات الإسلامية والدعوات
+
+46
+00:04:30,900 --> 00:04:35,100
+الإسلامية والجماعات الإسلامية والصحوة الإسلامية
+
+47
+00:04:35,100 --> 00:04:40,480
+وقاموا بتشويها بأشكال مختلفة ووسائل متعددة من هذه
+
+48
+00:04:40,480 --> 00:04:43,700
+الوسائل يا أخوات ما هي هذه الوسائل التي اعتمدها
+
+49
+00:04:43,700 --> 00:04:48,320
+هؤلاء أو أعداء الإسلام في تشويه ومحاربة الحركة
+
+50
+00:04:48,320 --> 00:04:53,820
+والدعوة الإسلامية فضل الأخت نبدأ من اللي هي ممكن
+
+51
+00:04:53,820 --> 00:05:01,110
+لأن هذه هي وسائلهموهذا هو دايدانوم إجراء محاكمات،
+
+52
+00:05:01,110 --> 00:05:03,570
+طبعا محاكمات ظالمة، الأصل أن يحاكم الإنسان على
+
+53
+00:05:03,570 --> 00:05:08,630
+تهمة، ما هي هذه التهمة؟ مافيش تهمة، تقتلون رجلا أن
+
+54
+00:05:08,630 --> 00:05:11,870
+يقول ربي الله، هذه هي تهمتهم، أن يقول ربي الله
+
+55
+00:05:11,870 --> 00:05:16,390
+ويدعو إلى الإسلام والسجن والقتل لمثل هؤلاء، أيضا
+
+56
+00:05:16,390 --> 00:05:21,370
+من هذه الوسائل، فضلوا، اه حضرتك الملعب من الوظيفة
+
+57
+00:05:21,370 --> 00:05:25,380
+والعمل والتضييق في الرزقإذا كان موظفا طبعا يحرم من
+
+58
+00:05:25,380 --> 00:05:29,780
+وظيفته يمنع من وظيفته من عمله يضيق عليه في رزقه
+
+59
+00:05:29,780 --> 00:05:37,300
+ثلاثة من هذه الوسائل يتهمون
+
+60
+00:05:38,360 --> 00:05:43,940
+بشتى الاتهمات و يشهرون بيها مرة هذا بيقود انقلاب
+
+61
+00:05:43,940 --> 00:05:48,240
+على الحكومة بيقود جماعة بدها هدفها انقلاب على
+
+62
+00:05:48,240 --> 00:05:52,660
+الحكومة تعمل ضد مصلحة الشعب هؤلاء مغالون هؤلاء
+
+63
+00:05:52,660 --> 00:05:57,750
+متطرفون هؤلاء إرهابيون هؤلاء قتلى هؤلاءنسمع هذه
+
+64
+00:05:57,750 --> 00:06:02,130
+النغمات و كأنه فشل الإسلام و المسلمين اللي بيوصفوا
+
+65
+00:06:02,130 --> 00:06:05,910
+بالارهاب و التطرف و بعد ذلك ليس هناك في العالم
+
+66
+00:06:05,910 --> 00:06:10,010
+ارهاب ولا تطرف رغم ان هذه التهمة من أصلها باطلة
+
+67
+00:06:10,010 --> 00:06:15,670
+لكن تهمة هدفها هو التشكيك و التشويه و المحاربة و
+
+68
+00:06:15,670 --> 00:06:22,170
+التشويه لصورة هذه الدعوة و الصحوة الإسلاميةهو أنهم
+
+69
+00:06:22,170 --> 00:06:26,130
+يعملون جهاد خارجية أو ليس عندهم برنامج واضح أن
+
+70
+00:06:26,130 --> 00:06:32,010
+يقدمونه للناس و هذه النغمة التي يعني يرددونها طب
+
+71
+00:06:32,010 --> 00:06:35,630
+ما هي أهداف هؤلاء العلمانيين و نازلنا في الحديث عن
+
+72
+00:06:35,630 --> 00:06:39,610
+العلمانية و هؤلاء دعاتها ما هي أهداف العلمانيين من
+
+73
+00:06:39,610 --> 00:06:43,990
+محاربة الحركات الإسلامية بهذه الطريقة و هذه
+
+74
+00:06:43,990 --> 00:06:47,410
+الوسيلة؟ هناك عدة أهداف من هذه الأهداف واحدة عدم
+
+75
+00:06:47,410 --> 00:06:51,420
+بصول دعات السنة في المارس الإسلامي إلى الحكومةحتى
+
+76
+00:06:51,420 --> 00:06:55,580
+لا يصل من يدعو إلى الإسلام وإلا استئناف الحكم
+
+77
+00:06:55,580 --> 00:07:01,440
+الإسلامي وتطبيق الإسلام في العالم العربي والإسلامي
+
+78
+00:07:01,440 --> 00:07:06,740
+حتى لا يصلوا إلى الحكم وإن فازوا ووصلوا وأخيرا
+
+79
+00:07:06,740 --> 00:07:14,060
+لأنه بالإن إذا كنا كلهم فازوا وانتصروا
+
+80
+00:07:14,060 --> 00:07:19,110
+في الانتخابات التي تجرأينقلبون عليهم كمان ورا في
+
+81
+00:07:19,110 --> 00:07:23,810
+مصر و في غير الأمر الثاني يا أخوات اخد مرة من هنا
+
+82
+00:07:23,810 --> 00:07:28,090
+مرة تفضل حتى لا تسرق الصحاب الاسلامي في جيل المسلم
+
+83
+00:07:28,090 --> 00:07:31,550
+و لا يكون لهم دراسة انحققتهم يعني خلنا نمشي
+
+84
+00:07:31,550 --> 00:07:34,370
+بالترتيب النقطة التانية احنا لسه في الأولى في
+
+85
+00:07:34,370 --> 00:07:38,670
+التانية كمان مرة حتى لا تفقد القوة الدولية مثلا
+
+86
+00:07:38,670 --> 00:07:40,830
+الحساسية و لا القصادية و لا السكينية في بيرات
+
+87
+00:07:40,830 --> 00:07:45,380
+الاسلامبرك الله فيك، كمان فيه هدف من محاربة هؤلاء،
+
+88
+00:07:45,380 --> 00:07:52,280
+مش فقط الهدف الأول، الهدف التاني له بعض خاص بهذه
+
+89
+00:07:52,280 --> 00:07:55,480
+القوات الدولية التي تتحكم و تسيطر في العالم
+
+90
+00:07:55,480 --> 00:08:01,790
+الإسلامي اليومبوصول الإسلاميين إلى الحكم سيفقد
+
+91
+00:08:01,790 --> 00:08:09,610
+هؤلاء سيطرتهم ونفوذهم فبتومش حدا يصل من المسلمين
+
+92
+00:08:09,610 --> 00:08:13,790
+المخلصين لهذا الدين و لهذا الوطن يصلوا إلى الحكم
+
+93
+00:08:13,790 --> 00:08:21,780
+لأن هم قائمينعلى استغلال الحُكّام الذين أنصبوهم و
+
+94
+00:08:21,780 --> 00:08:26,020
+أتوا بيهم بعد رحيلهم فبدونش يفقدوا هذه المصالح
+
+95
+00:08:26,020 --> 00:08:30,800
+التي ترتبط بهؤلاء الذعماء والحُكّام الأمر الثالث
+
+96
+00:08:30,800 --> 00:08:36,740
+فضل نختلف الآخر حتى لا تثر الصحاب الإسلاميين في
+
+97
+00:08:36,740 --> 00:08:39,760
+الجيل المفتوح ولا يكون لها الامتداد في أنحاء
+
+98
+00:08:39,760 --> 00:08:43,100
+المملكةبارك الله فيك و هذا هدف يعني احنا لحظين
+
+99
+00:08:43,100 --> 00:08:49,160
+حطين ملاحظة اضافية يعني و بنمثل لنموذج غزة هنا بعد
+
+100
+00:08:49,160 --> 00:08:53,680
+انتصار يعني الحركة الإسلامية و الصحوة الإسلامية و
+
+101
+00:08:53,680 --> 00:08:57,160
+التوجه الناس الى الإسلام و انتصار الإسلام في قطاع
+
+102
+00:08:57,160 --> 00:09:03,240
+غزة لأنه هو اتجاه الناس في هذا القطاع في معظمهم و
+
+103
+00:09:03,240 --> 00:09:07,000
+أغلبهم فاختاروا الإسلام و المسلمين و من يمثل هذا
+
+104
+00:09:07,000 --> 00:09:11,260
+الإسلاممن هؤلاء الدعاء من هذه الحركات والجماعات
+
+105
+00:09:11,260 --> 00:09:17,300
+فلا يريدون أن ينتقل هذا النموذج الناجح المنتصر إلى
+
+106
+00:09:17,300 --> 00:09:21,000
+بلدان أخرى ففي أي بلد ينجح فيه الإسلاميون أيضا
+
+107
+00:09:21,000 --> 00:09:25,080
+يحارب كما هو حاصل اليوم في مصر و في غيره لا يريدون
+
+108
+00:09:25,080 --> 00:09:30,760
+لأي تجربة إسلامية أن تنجح لأن إن نجحت سينظر الناس
+
+109
+00:09:30,760 --> 00:09:35,910
+أن هذه الإسلام العظيمقد تجح إذا نريد أن نطبقه في
+
+110
+00:09:35,910 --> 00:09:39,030
+باقية البلدان و يطالبوا بذلك، هم لا يريدون هذا
+
+111
+00:09:39,030 --> 00:09:42,210
+الأمر، يريدون أن تبقى العلمانية هي المسيطرة و
+
+112
+00:09:42,210 --> 00:09:46,290
+إقصاء الإسلام و إقصاء الدين لأن هؤلاء يخدمونهم و
+
+113
+00:09:46,290 --> 00:10:06,030
+يخدمون مصالحهم العلياأمر الثالث اتفضل برك
+
+114
+00:10:06,030 --> 00:10:10,790
+الله فيكهم و هذا من أهدافهم التي تعرفنا عليها في
+
+115
+00:10:10,790 --> 00:10:16,770
+أكثر من مكان و موضع أنه يريدوا من الشعوب و الأجيال
+
+116
+00:10:16,770 --> 00:10:21,730
+الإسلامية أن تتقبل أفكارهم و مبادئهم و سلوكهم و
+
+117
+00:10:21,730 --> 00:10:25,670
+قيمهمفان يأتي الناس يدعون إلى الإسلام و إلى الدين
+
+118
+00:10:25,670 --> 00:10:30,570
+و إلى الالتزام بالشرع معناه ذلك هو قضاء على هذه
+
+119
+00:10:30,570 --> 00:10:37,770
+المبادئ التي خططوا لها و تعبوا و أنفقوا أموالا
+
+120
+00:10:37,770 --> 00:10:44,780
+طائلة في سبيل نجاحهاوهذه المبادئ هي التي تضعف
+
+121
+00:10:44,780 --> 00:10:49,200
+الشعوب الإسلامية التي يسيطرون عليها فيريدونها
+
+122
+00:10:49,200 --> 00:10:53,080
+دائما ضعيفة فإذا ما تخلى المسلمون عنها واستبدلوها
+
+123
+00:10:53,080 --> 00:11:01,450
+بقيامهم وعقيدتهم فسترجع القوة للمسلمين كما كانتهذا
+
+124
+00:11:01,450 --> 00:11:07,750
+ما يتعلق بوسائل علمانة المجتمع وكان الأصل أن ننتهي
+
+125
+00:11:07,750 --> 00:11:12,790
+منه في المحاضرة الماضية ولكن لموضوع الامتحان
+
+126
+00:11:12,790 --> 00:11:18,150
+والاختبار اللذي كان فتوقفنا يعني عنده و أعطينا
+
+127
+00:11:18,150 --> 00:11:21,650
+فرصة و مجال للمراجعة أو للأسئلة في المحاضرة
+
+128
+00:11:21,650 --> 00:11:26,090
+الماضية وكان الأصل أن نبدأ بموضوعنا اليوم هو آثار
+
+129
+00:11:26,090 --> 00:11:31,210
+العلمانية في العالم الإسلاميهذه العلمانية وهذا
+
+130
+00:11:31,210 --> 00:11:37,270
+الفكر وهذا المبدأ له آثار وآثار متعددة وفي مجالات
+
+131
+00:11:37,270 --> 00:11:44,390
+عدة وسنذكر أمثلة ونماذج لهذه الآثار في بلدين فقط
+
+132
+00:11:45,050 --> 00:11:50,350
+يعني طبقت فيها هذه العلمانية وكان لها تأثير كبير
+
+133
+00:11:50,350 --> 00:11:56,130
+ناخد نموذج من تركيا لكونها دولة الخلافة الإسلامية
+
+134
+00:11:56,130 --> 00:12:00,270
+ونرا حالها بعد تبني العلمانية كيف اختلف وتغير
+
+135
+00:12:00,270 --> 00:12:07,850
+ونموذج او نموذجين من مصر وهي بلد جامعة الأظهر
+
+136
+00:12:07,850 --> 00:12:13,390
+الشريف والجامع الأظهر الشريف أيضاهذه الأثار أخوات
+
+137
+00:12:13,390 --> 00:12:18,230
+كما قلنا متعددة وفيها مجالات كثيرة منها ما هو في
+
+138
+00:12:18,230 --> 00:12:21,770
+الأفراد أثارها العلمانية في الأفراد ومنها ما هو في
+
+139
+00:12:21,770 --> 00:12:26,490
+المجتمع و الأخلاق ومنها ما هو في الحياة السياسية
+
+140
+00:12:26,490 --> 00:12:31,930
+ومنها ما هو في الحياة الاقتصادية يعني أثار متعددة
+
+141
+00:12:31,930 --> 00:12:37,720
+في جوانب متعددةونبدأ بأثار العلمانية في الأفراد
+
+142
+00:12:37,720 --> 00:12:43,500
+كما تراهم وكما قلنا النموذجين الذين سنأخذهم نموذج
+
+143
+00:12:43,500 --> 00:12:48,500
+من تركيا نموذج واحد هو مصطفى كمال أتى تركهذا الرجل
+
+144
+00:12:48,500 --> 00:12:52,960
+العلماني سنتعرف عليه ونتحدث عنه ومن مصر سنأخذه
+
+145
+00:12:52,960 --> 00:12:58,280
+نموذجيني فقط من عدة نماذج موجودة في الكتاب هنقتصر
+
+146
+00:12:58,280 --> 00:13:02,820
+فيها على الدكتور طه حسين وقاسم امين بعد ذلك يترك
+
+147
+00:13:02,820 --> 00:13:08,200
+للقراءة و الاستفادة منه في القراءة ففيه يعني ثوائط
+
+148
+00:13:08,200 --> 00:13:13,360
+التعرف على هؤلاء العلمانيين المذكورين اللي احنا لم
+
+149
+00:13:13,360 --> 00:13:19,050
+نذكرهمونبدأ الحديث والكلام عن أثار العلمانية في
+
+150
+00:13:19,050 --> 00:13:25,330
+الأفراد بالنموذج التركي الذي يمثله مصطفى كمال أتا
+
+151
+00:13:25,330 --> 00:13:31,790
+ترك هذا الرجل العلماني القومي في نفس الوقت لانه
+
+152
+00:13:31,790 --> 00:13:36,790
+دعل التبني القومية التورانية في مقابل الوحدة
+
+153
+00:13:36,790 --> 00:13:40,030
+الإسلامية التي كان عليها المسلمون والخلافة
+
+154
+00:13:40,030 --> 00:13:44,470
+الإسلامية قبل إلغائها على يديه وعلى يد جماعته
+
+155
+00:13:45,250 --> 00:13:49,710
+اليهود اليهود الدونمة وعلى يد حزبه حزب الاتحاد
+
+156
+00:13:49,710 --> 00:13:55,810
+والتراقب اتصف هذا الرجل العلماني الكبير بأشنع
+
+157
+00:13:55,810 --> 00:14:02,450
+الصفات وأبشع الصفاتاللي يتصف بها إنسان أو رجل فما
+
+158
+00:14:02,450 --> 00:14:08,030
+هي هذه الصفات الشنيعة البشعة التي اتصف بها هذا
+
+159
+00:14:08,030 --> 00:14:12,670
+الرجل العلماني يعني بدنا نستمع إليكم أو منكم إلى
+
+160
+00:14:12,670 --> 00:14:17,510
+هذه الصفات نختلف الآخر يعني هذا كان معروف بالغضب
+
+161
+00:14:17,510 --> 00:14:21,710
+الشديد والسريع والثورة لأقل شيء لأطفال شيء كان
+
+162
+00:14:21,710 --> 00:14:27,530
+يثور مزاجه يعني مزاج عصبي وثائري لأقل شيء وكان
+
+163
+00:14:27,530 --> 00:14:32,310
+أيضاتفضى يا أختي شديد الغرام بالإناث و بشرب الخمر
+
+164
+00:14:32,310 --> 00:14:36,530
+نعم و احنا حاولنا نعمل نقطات متعددة و نفصل كل
+
+165
+00:14:36,530 --> 00:14:40,030
+جزئية يعني يثور بسرعة نقطة عملنا شديد الغرام
+
+166
+00:14:40,030 --> 00:14:45,710
+بالنساء و الإناث و كذا و كذلك شديد الغرام او مغرم
+
+167
+00:14:45,710 --> 00:14:51,310
+بشرب الخمر او الخمور و كان مدمنا على ذلك حتى روي
+
+168
+00:14:51,310 --> 00:14:55,900
+عنههو الكلام للشيخ الدعية الكبير عبد الحميد كيشك
+
+169
+00:14:55,900 --> 00:15:01,000
+في إحدى أشرطاته أنه راجع يوما مخمورا و مسكورا و
+
+170
+00:15:01,000 --> 00:15:10,820
+سكرانإلى ما قبل الفجر أو عند أذانها الفجر فسمع صوت
+
+171
+00:15:10,820 --> 00:15:17,140
+المؤذن يؤذن للفجر فأزعجه ذلك وأمر بهدم المسجد
+
+172
+00:15:17,140 --> 00:15:22,560
+القريب منه الذي سمع صوت الأذان فيه فسيأتي حديث عن
+
+173
+00:15:22,560 --> 00:15:26,220
+المسجد والمساجد يعني بعد قليل في الأعمال التي قام
+
+174
+00:15:26,220 --> 00:15:30,200
+بها هذا الرجل العلماني الخطير على الإسلام
+
+175
+00:15:30,200 --> 00:15:37,770
+والمسلمينوهذا يعني ما تصورونه النقطة الرابعة انه
+
+176
+00:15:37,770 --> 00:15:42,910
+كان يتصف بشدة العداوة والمحاربة
+
+177
+00:15:42,910 --> 00:15:50,590
+والبغض شديد للإسلام تحديدا وهذا يعني معناه اللي هي
+
+178
+00:15:50,590 --> 00:15:54,030
+النقطة الخامسة عدم إيمانه بالله تعالى تلقائي يعني
+
+179
+00:15:54,030 --> 00:15:57,130
+أمر طبيعي مدام هو شديد العداوة لهذا الدين والإسلام
+
+180
+00:15:57,130 --> 00:16:02,730
+هذا الراجل ليس مؤمن يعني بالله أصلالأنه كان ملحدا
+
+181
+00:16:02,730 --> 00:16:08,990
+ويعني بالاسم فقط ينتمي إلى حتى اليهود وهم يدعون
+
+182
+00:16:08,990 --> 00:16:13,070
+الإيمان بالله وإيمانهم أصلا بالله ليس هو الإيمان
+
+183
+00:16:13,070 --> 00:16:17,090
+السليم الصحي كما قال الله تعالى وما يؤمن أكثرهم
+
+184
+00:16:17,090 --> 00:16:21,550
+بالله إلا وهم مشركون حتى من يدعي أنه يؤمن بالله
+
+185
+00:16:21,550 --> 00:16:26,350
+يؤمن بوجود الله لكن صفات هذا الإله ليس صفات الإله
+
+186
+00:16:26,350 --> 00:16:31,580
+الحق كما هو عند اليهود والنصارىأيضًا من ما وصف به
+
+187
+00:16:31,580 --> 00:16:36,500
+هذا الرجل .. فضل .. كان
+
+188
+00:16:36,500 --> 00:16:44,360
+يعني من المعجبين جدًا بالغرب و بأفكاره و مبادئه و
+
+189
+00:16:44,360 --> 00:16:49,020
+هو يعني محسوب على هذا الاتجاه و كان يدعو إليه و
+
+190
+00:16:49,020 --> 00:16:53,340
+يدعو إلى الأخذ بالحضارة الغربية المادية
+
+191
+00:16:55,500 --> 00:16:58,400
+وهو الذي قام بالانقلاب كما قلنا على الخلافة
+
+192
+00:16:58,400 --> 00:17:03,520
+الإسلامية وإلغاءها على يديه في العام الف وتسعمائية
+
+193
+00:17:03,520 --> 00:17:08,460
+أربعة وعشرين على يده ويد حزبه حزب الاتحاد والترقي
+
+194
+00:17:08,460 --> 00:17:13,360
+وجماعته اللي كان ينتسب وينتمي إليه وهو يهود الـ
+
+195
+00:17:13,360 --> 00:17:18,530
+Donemeله من الأعمال العدائية يعني هذه الصفات التي
+
+196
+00:17:18,530 --> 00:17:22,090
+ذكرناها عنها هي بعض صفاته التي اشتهرها فيها لكن له
+
+197
+00:17:22,090 --> 00:17:27,690
+أعمال كثيرة عدائية ضد الإسلام وهي يمكن تصلان إلى
+
+198
+00:17:27,690 --> 00:17:33,470
+حوالي اتناشر عمل مذكور احنا اجتهدنا يعني في وضعها
+
+199
+00:17:33,470 --> 00:17:38,530
+بهذه الصورة كنقات جزئية عشان يسهل التعرف عليها
+
+200
+00:17:38,530 --> 00:17:43,610
+وحفظهاوبدنا برضه نسمع منكم هذه الأعمال على رأسها
+
+201
+00:17:43,610 --> 00:17:49,570
+وقد سبق التنويه إليه، تفضل الأخت الدعوة إلى ألغاء
+
+202
+00:17:49,570 --> 00:17:54,290
+الشريع وإبصاء قضاء المحاكم الدينية، قوضات المحاكم
+
+203
+00:17:54,290 --> 00:17:59,500
+الدينية وإقام المحاكم الحديثة والمحاكم المدنيةبرك
+
+204
+00:17:59,500 --> 00:18:02,940
+الله فيك، لأن هو صاحب هذه الدعوة، إلغاء الشريعة
+
+205
+00:18:02,940 --> 00:18:08,360
+الإسلامية والأحكام والمحاكم الإسلامية وإقامة محاكم
+
+206
+00:18:08,360 --> 00:18:14,100
+مدنية حديثة على الطراز الأوروبي والغربي والأجنبي،
+
+207
+00:18:14,100 --> 00:18:18,800
+اتنين من هذه الأعمال، طيب يا أخوات، تفضل، تفضل،
+
+208
+00:18:18,800 --> 00:18:20,960
+خليني أتفرج، أنا أتفرج في التعاون مع اليهود
+
+209
+00:18:20,960 --> 00:18:26,260
+والإنديينوهذه أكثر من مرة المحنة إليها لأن هو الذي
+
+210
+00:18:26,260 --> 00:18:35,080
+قام بإلغاء الخلافة و طرد الخليفة بنفسه وجماعته
+
+211
+00:18:35,080 --> 00:18:42,030
+لأن هو من .. نعمهو مش صار، هو كان ولا يزال وحتى
+
+212
+00:18:42,030 --> 00:18:46,270
+النخاع وإلى أن مات، معروف هذا يعني بتعونه وعملته
+
+213
+00:18:46,270 --> 00:18:50,970
+اللي ألغره، لأنه لا يمكن لشخص وحده أن يقوم بهذا
+
+214
+00:18:50,970 --> 00:18:55,630
+العمل الكبير، أن يلغي خلافة .. هي مش بجرد قلم،
+
+215
+00:18:55,630 --> 00:18:59,500
+يعني راح يلغيها ب ..لأ راحت بقوة مدعوم فيها يعني
+
+216
+00:18:59,500 --> 00:19:04,280
+من ورائه يهود و انجليز في ذلك الوقت لم يكن امريكا
+
+217
+00:19:04,280 --> 00:19:07,260
+ولا الولايات المتحدة لسه على الساحة بعد الحرب
+
+218
+00:19:07,260 --> 00:19:13,140
+العالمية الاولى الف وتسعمائة واربعتاش الى الف
+
+219
+00:19:13,140 --> 00:19:17,240
+وتسعمائة و تمانتاش بعد ذلك لما انهزمت تركيا يعني
+
+220
+00:19:17,240 --> 00:19:23,480
+مع الحلفاء الألمان اللي كانوا معها وضعفت وبالتالي
+
+221
+00:19:23,480 --> 00:19:30,820
+كان هؤلاءالجهة اللتي قاتلت تركيا وحلفائها في الحرب
+
+222
+00:19:30,820 --> 00:19:36,280
+يدعمون هذا الرجل وجماعته وحزبه وعاونوه وساعدوه على
+
+223
+00:19:36,280 --> 00:19:41,600
+إسقاط وإلغاء الخلافة الإسلامي هيبقوا بالتعاون مع
+
+224
+00:19:41,600 --> 00:19:46,220
+اليهود والإنجليز في ذلك الوقت أيضا من أعماله التي
+
+225
+00:19:46,220 --> 00:19:47,380
+قام بيها
+
+226
+00:19:50,290 --> 00:19:54,150
+والشؤون الدينية عشان اوقاف اشئون دينية هذه يعني
+
+227
+00:19:54,150 --> 00:19:57,650
+الوزارة موجودة في العالم كله مابدناش اوقاف مش
+
+228
+00:19:57,650 --> 00:20:01,330
+محتاجين اليها مدني بديوش الدين ومحارب للدين وبده
+
+229
+00:20:01,330 --> 00:20:04,410
+يلغي التعليم الديني والشرعي وغيره فلا حاجة لانقل
+
+230
+00:20:04,410 --> 00:20:09,130
+وزارة اسمها وزارة اوقاف او شئون دينية وبيهدم مساجد
+
+231
+00:20:09,130 --> 00:20:15,290
+وانا مافيش حاجة الى هذه الوزارة من أصله النقطة
+
+232
+00:20:15,290 --> 00:20:21,530
+الرابعة في أعماله .. فضل أخطر في الآخر هنامنع
+
+233
+00:20:21,530 --> 00:20:24,910
+التعليم الديني، التعليم الشرعي مش بحاجة إلى تعليم
+
+234
+00:20:24,910 --> 00:20:28,530
+ديني ولا لتعليم الشرعي، احنا بحاجة الآن إلى أن
+
+235
+00:20:28,530 --> 00:20:32,770
+نسير سيرة الأوروبيين ونحتذي حذفهم ونسير خلفهم
+
+236
+00:20:32,770 --> 00:20:37,630
+ونسير وراءهم ولدعوة العلمانيين يعني أينما كانوا
+
+237
+00:20:37,630 --> 00:20:47,370
+فضل يا أخت، خمسة؟ نعم، وهذا يعني من الجرائم الكبرى
+
+238
+00:20:48,330 --> 00:20:57,050
+التي يستحق صاحبها القتل الذي يعدم ويقتل علماء فهذا
+
+239
+00:20:57,050 --> 00:21:01,450
+رجل يعني مرتد وخارج عن الإسلام وعن الدين قبل هذا
+
+240
+00:21:01,450 --> 00:21:06,390
+العمل وبهذا العمل يعني يزداد جريمة واجراما حينما
+
+241
+00:21:06,390 --> 00:21:11,410
+يقدم على مثل هذا العمل ان يقتل ويعدم ويقتل العلماء
+
+242
+00:21:11,410 --> 00:21:16,870
+كذلك قام ب .. فضل الغاء الحجاب وفرد السفور و
+
+243
+00:21:16,870 --> 00:21:21,430
+التبرج على النساءبرك الله فيك و جعل ذلك قرارا
+
+244
+00:21:21,430 --> 00:21:27,190
+حاسما نهائيا و يحاسب أو تحاسب عليكو الإمرأة تخالف
+
+245
+00:21:27,190 --> 00:21:33,070
+و إلى وقت قريب كان تحرم المرأة المسلمة من دخول
+
+246
+00:21:33,070 --> 00:21:37,250
+الجامعات و المدارس الحكومية و المؤسسات الحكومية
+
+247
+00:21:37,250 --> 00:21:42,550
+الرسمية إذا كانت محجبة، ممنوع، منعمة، كانت مشكلة
+
+248
+00:21:42,550 --> 00:21:47,270
+كبيرةفي تركيا والان فرنسا طبعا في مشكلة كبيرة من
+
+249
+00:21:47,270 --> 00:21:52,430
+منع المحجبات والمسلمات من دخول المدارس الحكومية
+
+250
+00:21:52,430 --> 00:21:56,390
+والجامعات خاصة و بتقبلها حرة لكن رسمية الدولة
+
+251
+00:21:56,390 --> 00:22:01,830
+علمانية ولا تسمح بذلكوهذا يعني عداء واضح وسافر
+
+252
+00:22:01,830 --> 00:22:06,090
+للدين والإسلام، أول ما انطبقه وقام به كان هذا
+
+253
+00:22:06,090 --> 00:22:10,350
+الراجل وإلى فترة قريبة الشكل العام والمظهر العام
+
+254
+00:22:10,350 --> 00:22:15,050
+لتركيا يعني اللي نكاد نرا فيها إمرأة أو فتاة محجبة
+
+255
+00:22:15,790 --> 00:22:19,270
+الكل يعني بشعوبه مظاهرة و واضحة و كده لكن الان
+
+256
+00:22:19,270 --> 00:22:23,350
+الوضع و الحمد لله تغير و انقلب تلت مائة و ستين
+
+257
+00:22:23,350 --> 00:22:26,990
+درجة كما يقال اصبح المظهر العام يعني القضية مش
+
+258
+00:22:26,990 --> 00:22:31,330
+بالمظهر و الشكل لكن يعني هذا اشارة و دلالة على
+
+259
+00:22:31,330 --> 00:22:37,430
+التغير و الانقلاب والتغير إلى الأفضل والأحسن يعني
+
+260
+00:22:37,430 --> 00:22:40,770
+اتجاه الناس إلى الإسلام والدين بعد فوز حزب العدالة
+
+261
+00:22:40,770 --> 00:22:45,910
+والتنمية في تركيا بقيادة رجل طيب أردوجان رئيس
+
+262
+00:22:45,910 --> 00:22:50,390
+الوزراء ومواقفه المشرفة المعروفة يعني لقضايا العرب
+
+263
+00:22:50,390 --> 00:22:55,950
+والمسلمين وبالأخص قضية شعبفلسطين و تفاصيل كثيرة
+
+264
+00:22:55,950 --> 00:22:59,990
+حول هذا الراجل و حزبه و ما فعله لتركيا و ما يعني
+
+265
+00:22:59,990 --> 00:23:05,690
+فعله لقضيتنا الفلسطينية و كان آخر هذه الجهود بأن
+
+266
+00:23:05,690 --> 00:23:10,950
+تركيا كانت دائما تصر على وجوب و ضرورة اعتذار
+
+267
+00:23:10,950 --> 00:23:16,270
+اليهود عن ما قاموا بهمن الجريمة ضد السفينة التركية
+
+268
+00:23:16,270 --> 00:23:20,450
+سفينة مرمرة و أخيرا استجاب و أذعن اليهود لهذه
+
+269
+00:23:20,450 --> 00:23:26,770
+الشروط و قاموا بالاعتذار و التعويض و كان في وعود
+
+270
+00:23:26,770 --> 00:23:31,730
+أيضا بفك الحصار و هو يراقب تنفيذ هذه الوعود عمرهم
+
+271
+00:23:31,730 --> 00:23:35,090
+اليهود في العالم اعتذروا لحد ولا استسمحوا حد ولا
+
+272
+00:23:35,090 --> 00:23:39,170
+جالوا لحدوهو هذا الراجل الوحيد اللذي أساء وجه
+
+273
+00:23:39,170 --> 00:23:44,870
+اليهود ورئيس حكومتهم في مؤتمر داوز الاقتصادي وهو
+
+274
+00:23:44,870 --> 00:23:48,630
+شمالون باريس حينما بدأ يتكلم على الغياب الفلسطيني
+
+275
+00:23:48,630 --> 00:23:56,230
+وكذا فتركه ومشهر وهذه ههانة كبرى تعتبر لوجه كبير
+
+276
+00:23:56,230 --> 00:24:00,110
+من وجوه اليهود كيف من أنت حتى تهين اليهود اللي كل
+
+277
+00:24:00,110 --> 00:24:04,430
+العالم بيحسب انهم حساب وبيخاف منهم لكن هذا الراجل
+
+278
+00:24:05,330 --> 00:24:09,230
+مصطفى كمال أتى ترك العلماني المحارب والمعادي
+
+279
+00:24:09,230 --> 00:24:13,730
+لإسلام انظروا ماذا فعل وانظروا هذا الراجل المسلم
+
+280
+00:24:13,730 --> 00:24:19,950
+ماذا يفعل الآن ليعيد وجه تركيا الأصيل الإسلامي لأن
+
+281
+00:24:19,950 --> 00:24:23,810
+تركيا أصلا هي بلد إسلامي وليس بلد علماني ولا ملحد
+
+282
+00:24:23,810 --> 00:24:29,650
+ولا كافر فعادها إلى صورتها الطبيعية والأصلية
+
+283
+00:24:29,650 --> 00:24:33,440
+والإسلامي فقلتمصطفى كمال قاتل تركي يعني بيعتبروه
+
+284
+00:24:33,440 --> 00:24:37,360
+رمز يعني من رموز التركي او من رموز الحضارة و
+
+285
+00:24:37,360 --> 00:24:40,420
+المدنية في تركيا بدلا انهم وضعينه صورة كبيرة في
+
+286
+00:24:40,420 --> 00:24:43,260
+مجلس النواب التركي و لا يستطيع حتى الآن يعني يحاول
+
+287
+00:24:43,260 --> 00:24:46,420
+الحزب الحرى و العدالة ازالة هذه الصورة لكن بيواجه
+
+288
+00:24:46,420 --> 00:24:50,600
+مقاومة شديدة من قبل الأحزاب العلمانية الأخرى نعم
+
+289
+00:24:50,600 --> 00:24:55,630
+صحي .. صحيهما ينظرون لنظر غير يعني صحيح القضايا
+
+290
+00:24:55,630 --> 00:25:00,510
+التي اعتاد الناس عليها وعلى تمجيدها عشرات السنين
+
+291
+00:25:00,510 --> 00:25:04,650
+لا يمكن ان تأتي بسنة و تنتين و تلاتة و بجرد قلم ان
+
+292
+00:25:04,650 --> 00:25:11,870
+تغير لأن في ناس يعني محبين ومعجبين ويمجدون ويقدسون
+
+293
+00:25:11,870 --> 00:25:16,120
+هذا الراجل وهم كثر فليس سهلالأ نريد الآن و نحن
+
+294
+00:25:16,120 --> 00:25:19,440
+نسمع على العالم أن نجرح في شخصيات معروفة الناس
+
+295
+00:25:19,440 --> 00:25:24,960
+نقدسها لكن إلها أعمال مسيئة و شاية لكن لما نتكلم
+
+296
+00:25:24,960 --> 00:25:28,360
+الناس عنها كأنه نرتكب جريمة فالناس عندها قداسة
+
+297
+00:25:28,360 --> 00:25:32,020
+لهذه الرمزية و هذه الشخصية و لهذا الرمز و لهذا
+
+298
+00:25:32,020 --> 00:25:36,460
+الحاكم و لهذا الزعيم فليس من السهل فلكن التاريخ لا
+
+299
+00:25:36,460 --> 00:25:40,220
+يرحم أحدا يكتب كل شيءلكن في الناحية العملية
+
+300
+00:25:40,220 --> 00:25:44,100
+الواقعية أحيانا يصطدم الإنسان بالواقع فيصبح عليه
+
+301
+00:25:44,100 --> 00:25:48,880
+أن يغير هذا الواقع بسهولة يحتاج إلى أمد بعيد ووقت
+
+302
+00:25:48,880 --> 00:25:54,640
+حتى يتغير لما إجا راجب طيب أردوغان فليس من السهل
+
+303
+00:25:54,640 --> 00:25:59,500
+عليه بيوم أو سنة أن يغير هذه القناعة مع أن الناس
+
+304
+00:25:59,500 --> 00:26:03,580
+يعني تعلم الحقيقة وتعرف الصواب لكن في الناس في
+
+305
+00:26:03,580 --> 00:26:07,920
+المقابللازالوا مرتبطين بهذا الفكر العلماني
+
+306
+00:26:07,920 --> 00:26:11,720
+وموجودين في تركيا وحاولوا أكثر من مرة لانقلاب على
+
+307
+00:26:11,720 --> 00:26:16,360
+هذه الحكومة الشرعية المنتخبة وكذا جنرالات يعني
+
+308
+00:26:16,360 --> 00:26:23,120
+كبار ويعني ألقي القب عليهم وحكموهم وإلا لو نجحوا
+
+309
+00:26:23,120 --> 00:26:28,220
+رجعت تركيا إلى ما كانت عليها والآن يعني في مصر
+
+310
+00:26:28,220 --> 00:26:31,660
+العزيزة الحبيبة نفس التجربة اللي كانت في تركيا
+
+311
+00:26:32,220 --> 00:26:35,700
+وكانت عندنا في غزة في هذه المحاولة وهي تتكرر في
+
+312
+00:26:35,700 --> 00:26:40,640
+مصر وفي كل مكان والكل يعني جاري على مش شيخ واحد
+
+313
+00:26:40,640 --> 00:26:42,180
+على شيطان واحد
+
+314
+00:26:46,940 --> 00:26:52,460
+أيضا من أعماله التي اشتهرة بها وقام تفضله بها
+
+315
+00:26:52,460 --> 00:26:55,380
+اعتبارك كتير جزء من العالم الغربي هو أصدر قانون
+
+316
+00:26:55,380 --> 00:26:58,500
+الملابس اللي ينص على إبدال الطربوش بالقبعة تأسيان
+
+317
+00:26:58,500 --> 00:27:01,720
+بالغرب؟ في عبارة براك الله فيكي يعني ممكن عكسينا
+
+318
+00:27:01,720 --> 00:27:06,540
+في الكتاب إبدال القبعة بالطربوش لأ هو قبل الطربوش
+
+319
+00:27:06,540 --> 00:27:11,940
+وهو كان رمز ومظهر لالعروبة يعني في ذلك الوقت
+
+320
+00:27:11,940 --> 00:27:16,480
+والإسلام أبدله بالقبة وهي الغربية استبدل التربوش
+
+321
+00:27:16,480 --> 00:27:20,660
+بالقبة وليس العكس حتى في المظهر حتى في الشكل حتى
+
+322
+00:27:20,660 --> 00:27:25,400
+في كده يريد أن يطبع تركيا إلى أوروبا وأنها جزء من
+
+323
+00:27:25,400 --> 00:27:29,720
+أوروبا وليس جزء من العالم الإسلامي وإلى فترة قريبة
+
+324
+00:27:29,720 --> 00:27:36,010
+كانت تركيا كذلك والآن يعني ما ..يصدم العالم الغربي
+
+325
+00:27:36,010 --> 00:27:40,810
+والأمريكي واليهودي معاه كيف تركيا الحديثة اليوم
+
+326
+00:27:40,810 --> 00:27:45,970
+بقيادة أردوجان وحزب العدالة والتنمية تريد أن تلحق
+
+327
+00:27:45,970 --> 00:27:50,490
+تركيا بالعالم الإسلامي في هذه العلاقات والزيارات
+
+328
+00:27:50,490 --> 00:27:55,070
+الخارجية والدولية والاقتصادية وتبتعد عن مين؟
+
+329
+00:27:55,070 --> 00:27:56,810
+المحور الغربي
+
+330
+00:27:59,300 --> 00:28:03,760
+ايضا من مقام بيه هذا الراجل من أعمال ده الأخوات
+
+331
+00:28:03,760 --> 00:28:06,540
+كله مانا شايف بعض الأخوات يعني هما هما ولا هنا هنا
+
+332
+00:28:06,540 --> 00:28:09,780
+حتى
+
+333
+00:28:09,780 --> 00:28:13,610
+اللغة العربية كمان كلغةبرضه مابدوش هي .. مابدوش اي
+
+334
+00:28:13,610 --> 00:28:17,810
+مظاهر .. المظاهر اللتي تمثل الإسلام بصلة للدين
+
+335
+00:28:17,810 --> 00:28:21,470
+بصلة اللغة العربية المعروفة هي لغة مين؟ القرآن ..
+
+336
+00:28:21,470 --> 00:28:24,330
+فمابدوش اي حاجة اللي هي علاقة بالدين بالإسلام
+
+337
+00:28:24,330 --> 00:28:32,630
+بالقرآن فحتى اللغة يعني كمان لم تسلم منه لغة عربية
+
+338
+00:28:32,630 --> 00:28:37,710
+طبعا المقصود اخوات مين كمان ماسمعناش .. اتفضل اخت
+
+339
+00:28:38,330 --> 00:28:43,490
+منع الأذان بالعربية و كمان .. كمان الأذان مش بس
+
+340
+00:28:43,490 --> 00:28:47,850
+اللغة كمان الأذان بدوش أي مظهر كما قولنا قبل قليل
+
+341
+00:28:47,850 --> 00:28:52,710
+لللغة لا في التعليم ولا حتى في الأذان حاول كمان
+
+342
+00:28:52,710 --> 00:28:55,730
+يعني يغير الأذان
+
+343
+00:29:00,500 --> 00:29:03,980
+لماذا لا تجوز؟ هذا لعنة الله على الكافرين ولعنة
+
+344
+00:29:03,980 --> 00:29:08,760
+الله على الكاذبين وهذا من من يلعنهم الله لأنه قام
+
+345
+00:29:08,760 --> 00:29:14,820
+بهذه الأعمال العدائية للدين الذي يعادي الله ورسوله
+
+346
+00:29:14,820 --> 00:29:20,770
+والمؤمنين وكذا يعني خرجها عن الإسلامبهذا الفعل
+
+347
+00:29:20,770 --> 00:29:27,010
+الذي قام به و هو من قبل يجهر بذلك و يصرح بهذا
+
+348
+00:29:27,010 --> 00:29:32,350
+الأمر بعدم إيماني و بعدوتي و هو أصلا يهودي الأصل
+
+349
+00:29:32,350 --> 00:29:37,150
+يعني يهودي الأصل في الأصل هذه واحدة تكفي و هو
+
+350
+00:29:37,150 --> 00:29:40,350
+علماني حاقد على الإسلام و الدين علماني حاقد على
+
+351
+00:29:40,350 --> 00:29:44,250
+الإسلام و الدين لحالة يكفر أعماله العدائيةكفيلة
+
+352
+00:29:44,250 --> 00:29:49,070
+واحدة أيضا بأن تجعله غير مسلم لو ادعى حتى الإسلام
+
+353
+00:29:49,070 --> 00:29:52,910
+و لا يدعي ذلك حتى لو ادعاه وبالتالي تجوز و تحل
+
+354
+00:29:52,910 --> 00:29:58,130
+عليه هذه اللعنة نعم يا أخو مين كانت هنا رافعة أصبع
+
+355
+00:29:58,130 --> 00:30:10,870
+تسألي اتفضل احنا
+
+356
+00:30:10,870 --> 00:30:17,320
+قلنا اهمع أن بعض العلماء يعترض على لعنة أي إنسان
+
+357
+00:30:17,320 --> 00:30:23,840
+في الدنيا لماذا؟ لأنه لندري حاله قبل أن يموت، ربما
+
+358
+00:30:23,840 --> 00:30:28,380
+يعني يرجع إلى الإسلام أو كذلك، بس هذا الراجل لم
+
+359
+00:30:28,380 --> 00:30:32,920
+يعرفعنه أنه رجع عن هذا الأمر لكن الأفضل في كل
+
+360
+00:30:32,920 --> 00:30:36,820
+الأحوال يعني عدم اللعن ليس المسلم باللعن ولا
+
+361
+00:30:36,820 --> 00:30:43,000
+بالطعن ولا الفاحش ولا البذيق يعني نطهر دائما
+
+362
+00:30:43,000 --> 00:30:47,700
+لسناتنا من ذلك لكن الجائز هو اللعنة على عموم
+
+363
+00:30:47,700 --> 00:30:51,620
+الكافرين اللعنة على الكافرين على الكاذبين لكن تقصد
+
+364
+00:30:51,620 --> 00:30:56,440
+شخص بعينه باللعنيعني هذا الكلام اللي عليه كلام عند
+
+365
+00:30:56,440 --> 00:31:00,940
+بعض العلماء و هناك من سمحه و أبعه لأنه يستحق ذلك و
+
+366
+00:31:00,940 --> 00:31:06,160
+نلعنه على أفعالي اللي يقوم عليها و هناك من توقف عن
+
+367
+00:31:06,160 --> 00:31:13,920
+هذا اللعنة و الله تعالى أعلم طيب نقطة تاسعة ولا
+
+368
+00:31:13,920 --> 00:31:19,980
+عشرة عشرة عشرة نينا أخوات ماسمعناها ايش تقول أنا
+
+369
+00:31:19,980 --> 00:31:21,460
+تفضل الأخت
+
+370
+00:31:25,240 --> 00:31:35,020
+يعني من مسجد يحولوا إلى أيش؟ إلى متحف museum دكتور
+
+371
+00:31:35,020 --> 00:31:38,640
+رجعوا مسجد ولا دلوا لحين متحف؟ لا أدري يعني هذا في
+
+372
+00:31:38,640 --> 00:31:41,720
+عهده و وقته لا أدري اليوم يعني هل عاد أو لم يعود
+
+373
+00:31:41,720 --> 00:31:49,240
+رجوع إلى القضية أيضا العمل الهادي عشر يعني واحدة
+
+374
+00:31:49,240 --> 00:31:51,800
+يكفي لتكفيره ماذا فعل
+
+375
+00:31:55,900 --> 00:31:58,940
+برك الله فيك هذا المقطع لحالة واحد بيحمل المصحف و
+
+376
+00:31:58,940 --> 00:32:06,100
+بيرميه على أي شيء يعتبر كفرا واستهزأا واستخفافا
+
+377
+00:32:06,100 --> 00:32:10,140
+بهذا المصحف و بهذا القرآن و بكلام الله تعالى إذا
+
+378
+00:32:10,140 --> 00:32:14,280
+أنا كنت أعلم أن هذا مصحف و أمسكته به و رميته هذه
+
+379
+00:32:14,280 --> 00:32:19,340
+لحالها تكفي لإخراج الإنسان من دينه و أن يصبح كافرا
+
+380
+00:32:19,340 --> 00:32:24,930
+لأن فيه نوع من إهانة واحتقار كلام اللهسبحانه
+
+381
+00:32:24,930 --> 00:32:28,870
+وتعالى فما بالكم لما يعني يرمى هذا المصحف على شيخ
+
+382
+00:32:28,870 --> 00:32:34,610
+الإسلام الذي كان في ذلك الوقت في تركيا وهو مصطفى
+
+383
+00:32:34,610 --> 00:32:40,710
+صبري فكان اعتقد هو يعني يرأس الأوقاف الإسلامية أو
+
+384
+00:32:40,710 --> 00:32:48,410
+المحاكم الشرعية في ذلك الوقت كذلك قام بي .. فضل
+
+385
+00:32:48,410 --> 00:32:52,490
+أختكالقانون الأوروبي هي القانون المدنسويسري
+
+386
+00:32:52,490 --> 00:32:55,880
+والقانون الإيطالي الجماعي والقانون التجاربيبرك
+
+387
+00:32:55,880 --> 00:32:58,400
+الله فيك يعني هذا يكمل النقطة الأولى الدعوة إلى
+
+388
+00:32:58,400 --> 00:33:03,220
+إلغاء الشريعة استبدالها بمين؟ بقوانين مدنية تارة
+
+389
+00:33:03,220 --> 00:33:08,040
+من سويسرا و أخرى من إيطاليا و ثالثة من إنجلترا و
+
+390
+00:33:08,040 --> 00:33:11,580
+من هنا و من هناك يعني بديلا عن هذه القوانين
+
+391
+00:33:11,580 --> 00:33:16,900
+والأحكام الإسلامية والتشريعات الإسلامية هذه مجمل
+
+392
+00:33:16,900 --> 00:33:20,740
+الأعمال العدائية التي قام بها هذا الرجل مصطفى كمال
+
+393
+00:33:20,740 --> 00:33:27,480
+أتاتورك العلماني ضد الإسلاموهذا النموذج التركي أو
+
+394
+00:33:27,480 --> 00:33:33,500
+النموذج من تركيا أما عن النماذج من مصر ونحن نتحدث
+
+395
+00:33:33,500 --> 00:33:36,740
+عن أثار العلمانية في الأفراد فهناك نموذجان كما
+
+396
+00:33:36,740 --> 00:33:41,320
+قلنا من مصر النموذج الأول طه حسين والثاني هو قاسم
+
+397
+00:33:41,940 --> 00:33:46,360
+أمين و ربما يعني مرة معنا طه حسين في أكثر من موضوع
+
+398
+00:33:46,360 --> 00:33:53,040
+و مجال بيتكرر معانا لما له من أثر و دور في الغزو
+
+399
+00:33:53,040 --> 00:33:57,060
+الفكري ممثل بالتغريب طارة و بالاستشراق أخرى و هنا
+
+400
+00:33:57,060 --> 00:34:03,380
+في العلمانية و في كل مكان له دور و أثر المعروف أن
+
+401
+00:34:03,380 --> 00:34:09,290
+طه حسين يا أخوات كان منطلاب الأظهر الشريف وكان
+
+402
+00:34:09,290 --> 00:34:13,830
+يحفظ القرآن في صغاره ليس رجلا أميا ولا جاهلا ولا
+
+403
+00:34:13,830 --> 00:34:18,860
+يعرف شيئا عن الإسلاميعني عشان كده الشعب يقول إن
+
+404
+00:34:18,860 --> 00:34:24,000
+كنت لا تعلم فتلك مصيبة وإن كنت تعلم فالمصيبة أعظمه
+
+405
+00:34:24,000 --> 00:34:26,320
+يعني في ناس جاهلين يقولوا والله ده جاهل بعذره ممكن
+
+406
+00:34:26,320 --> 00:34:29,980
+مش عارف من علمه من وجهه ونقوله حرام ومجوزش وهذه
+
+407
+00:34:29,980 --> 00:34:36,160
+كذا لكن هذا الذي يعلم الحق ثم يخفي أو يخالفه يكون
+
+408
+00:34:36,160 --> 00:34:42,500
+جريمته أعظمودرس في جامعات الغرب الاستشراقية
+
+409
+00:34:42,500 --> 00:34:46,680
+العريقة المعروفة عندهم وخاصة في فرنسا اللي كان
+
+410
+00:34:46,680 --> 00:34:49,840
+يدرس فيها جامعات مونيبليه والسيربون والكلوج دي
+
+411
+00:34:49,840 --> 00:34:55,460
+فرانس وغيرها من الجامعات التي يتباهى يعني اي من
+
+412
+00:34:55,460 --> 00:34:58,500
+الطلاب الذين يدرسون في الخارج انهم تخرجوا من مثل
+
+413
+00:34:58,500 --> 00:35:03,300
+هذه الجامعات وكلها جامعات استشراقية يشرف عليها
+
+414
+00:35:03,300 --> 00:35:10,700
+يعني مستشرقون كبارو يحاولون غسل أدمغات و عقول
+
+415
+00:35:10,700 --> 00:35:15,600
+المسلمين و أبناء المسلمين مما فيها من الدين و
+
+416
+00:35:15,600 --> 00:35:20,220
+الإسلام و إعادة صياغتها مرة أخرى على النمط الغربي
+
+417
+00:35:20,220 --> 00:35:25,650
+و الأوروبيالذي يعني هدفه هو تشويه الإسلام والتشكيك
+
+418
+00:35:25,650 --> 00:35:29,430
+فيه ودرس على أيدي مستشريقين كبار مثل كزانوفا و
+
+419
+00:35:29,430 --> 00:35:34,130
+مارجليوت و دوركايم و ميسينيون كلهم أسماء مستشريقين
+
+420
+00:35:34,130 --> 00:35:39,450
+كبار و معروفين غربيين في هذه الجامعة اللي درس فيها
+
+421
+00:35:39,450 --> 00:35:47,970
+فلما عاد عاد بأفكار يعني غريبة و غربية عنوطني
+
+422
+00:35:47,970 --> 00:35:52,470
+وبلده مصر الإسلامية العربية الإسلامية وعاد بهذه
+
+423
+00:35:52,470 --> 00:35:56,750
+الثقافة الفرنسية ودع إلى الأخذ بالحضارة الغربية
+
+424
+00:35:56,750 --> 00:36:04,070
+حلوها ومرها وخيرها وشرها وما يحب منها وما يكره وما
+
+425
+00:36:04,070 --> 00:36:11,410
+يحسن منها وما يعاب هذه عبارته يعني بالحرف نقلها من
+
+426
+00:36:11,410 --> 00:36:18,300
+كتابي وسيأتي كلامه عنهو اعتبر ان مصر جزء من الغرب
+
+427
+00:36:18,300 --> 00:36:22,520
+و ليس جزء من الشرق يعني و ده كلام غريب و عجيب منه
+
+428
+00:36:22,520 --> 00:36:29,320
+فمصر يعني جزء غربيا و هي الغرب اقرب منها الى الشرق
+
+429
+00:36:29,320 --> 00:36:34,800
+و ده يخلف فيه التاريخ و الجغرافيا و يعني كل
+
+430
+00:36:34,800 --> 00:36:35,980
+المعرفة
+
+431
+00:36:39,380 --> 00:36:44,860
+وأما كتبه التي كتبها فمليئة بالتشكيك والطعن في
+
+432
+00:36:44,860 --> 00:36:49,620
+الإسلام وفي الدين ولو أفكار غريبة وعجيبة عن
+
+433
+00:36:49,620 --> 00:36:54,800
+الإسلام يعني بقرائة ان شاء الله بننهي محاضراتنا من
+
+434
+00:36:54,800 --> 00:37:00,720
+هذه الأفكار أول هذه الأفكار الغريبة والعجيبة التي
+
+435
+00:37:00,720 --> 00:37:04,840
+يقول هذا الرجل تفضلي تعمل تناقض واضح بين نصوص
+
+436
+00:37:04,840 --> 00:37:09,570
+الكتب التقنية ونص الأعلاق العالميةهو هذا كلام
+
+437
+00:37:09,570 --> 00:37:12,710
+صحيح، احنا لا نريد أن نرد على كل قضية وإلا الوقت
+
+438
+00:37:12,710 --> 00:37:16,090
+يعني سيكون مضعف، هيأخد مننا وقت طويل، لكن أحيانًا
+
+439
+00:37:16,090 --> 00:37:21,650
+نرد و أحيانًا قلة الرد أفضل، لأن الأمر أوضح من أن
+
+440
+00:37:21,650 --> 00:37:25,350
+يُرد عليه، قال هناك تناقض، ليس هناك تناقض بين
+
+441
+00:37:25,350 --> 00:37:28,810
+القرآن والعلم كما ادعى وزعم هذا الأمر الثاني
+
+442
+00:37:28,810 --> 00:37:33,410
+الخطير الذي ادعاه هذا الرجل وزعمه، تفضله
+
+443
+00:37:38,840 --> 00:37:44,830
+و اعتبارها ان الرواية عياش خرافيةهل هذا كلام يصدر
+
+444
+00:37:44,830 --> 00:37:50,870
+من مسلم يقرأ القرآن فاطلا عن مسلم يحفظ القرآن ومرت
+
+445
+00:37:50,870 --> 00:37:55,150
+عليه هذه الأيات من سورة البقرة الصريحة الواضحة واذ
+
+446
+00:37:55,150 --> 00:38:02,590
+يرفع إبراهيم القواعد من البيت وإسماعيل ربنا تقبل
+
+447
+00:38:02,590 --> 00:38:10,650
+منّا إنك أنت السميع العليم في سورة البقرةيرفع
+
+448
+00:38:10,650 --> 00:38:15,750
+إبراهيم قواعد من البيت و إسماعيل قال لأ لا إبراهيم
+
+449
+00:38:15,750 --> 00:38:18,830
+ولا إسماعيل بنوا الكعب ولا رفعوها و هذا قصة خرافية
+
+450
+00:38:18,830 --> 00:38:24,070
+و مالهاش أساس من الصحة فهذا كلاميقول هو مسلم يعني
+
+451
+00:38:24,070 --> 00:38:28,770
+هذا الإنكار لما هو معلوم من الدين بالضرورة إنكار
+
+452
+00:38:28,770 --> 00:38:33,030
+آية صريحة من القرآن واحدة هو أيضا يؤدي إلى الكفر
+
+453
+00:38:33,030 --> 00:38:37,630
+والرد واتهام القرآن بإنه بيأتي بروايات خرافية
+
+454
+00:38:37,630 --> 00:38:44,090
+وأساطير نفس دعواء المشركين التلاتة مين من الأخوات
+
+455
+00:38:44,090 --> 00:38:49,110
+ماسمعناهمش أقولكوا سمعناكم طبعا نرجع تاني هما هما
+
+456
+00:38:52,020 --> 00:38:56,420
+كان يدعو العودة إلى الفرنانية يعني وانا متأثرة في
+
+457
+00:38:56,420 --> 00:39:03,380
+نقوس اربعة اه فضل يا عزيزي ضروب
+
+458
+00:39:03,380 --> 00:39:04,920
+يعني أنواع من البغي
+
+459
+00:39:07,650 --> 00:39:10,530
+طيب الفرس قبلناها والرومان قبلناها، هدولة كانوا
+
+460
+00:39:10,530 --> 00:39:15,210
+غزاة وكانوا محتلين ومستعمق، لكن والعرب فشبه
+
+461
+00:39:15,210 --> 00:39:19,250
+الفتحات الإسلامية والفتح الإسلامي بالاستعمار
+
+462
+00:39:19,250 --> 00:39:24,090
+والاحتلال والغزو ويقصد الفاتحين الإسلاميين، خمسة
+
+463
+00:39:24,090 --> 00:39:26,330
+ومن الأمور العجيبة والغريبة عنه ..
+
+464
+00:39:31,040 --> 00:39:35,200
+كيف هذا؟ تركب هذا على بعض و تكون مؤمن و كافر في
+
+465
+00:39:35,200 --> 00:39:38,940
+نفس الوقت و مؤمن بقلبه و كافر بعقل يعني هذا عشان
+
+466
+00:39:38,940 --> 00:39:42,840
+يبرر ما يقوله هو من هذه الأقوال اللي ذكرناها أنا
+
+467
+00:39:42,840 --> 00:39:45,360
+مؤمن والله و بأمن بالله و مش مناهي أنا كافر و بأمن
+
+468
+00:39:45,360 --> 00:39:48,620
+بالقرآن بس في شغلات ما تدخلش العقل في القرآن ما
+
+469
+00:39:48,620 --> 00:39:52,200
+تدخلش okay فانت مؤمن بالله و بالقرآن و في حاجات في
+
+470
+00:39:52,200 --> 00:39:55,970
+القرآن ما تدخلش العجليصير الشهادة معاه عشان يبرر
+
+471
+00:39:55,970 --> 00:40:02,450
+ما ينكره ويرفضه من الحقائق القرأنية ستة دعا إلى ..
+
+472
+00:40:02,450 --> 00:40:06,450
+يدعوا إلى حيث سيرة الغربيين ونسّق طريقهم ونأخذ
+
+473
+00:40:06,450 --> 00:40:09,890
+حضراتهم من كل حدثبرك الله فيك، وده مكرر ومعادو
+
+474
+00:40:09,890 --> 00:40:15,750
+كتير ذكرناه، أيضا وصف القرن الثاني الهجري بإنه عصر
+
+475
+00:40:15,750 --> 00:40:21,090
+شك ومجون ولم يكن فيه يعني من القيم والمبادئ إلا
+
+476
+00:40:21,090 --> 00:40:26,200
+الدعوة إلى الخمر وإلى .. وده كلام طبعا تافهوتفاخر
+
+477
+00:40:26,200 --> 00:40:29,140
+بتبعيته للاستشراك والتبشير والتغريب ودع إلى
+
+478
+00:40:29,140 --> 00:40:33,360
+العلمانية وإلغاء التعليم الديني وقال ببشرية القرآن
+
+479
+00:40:33,360 --> 00:40:37,600
+يعني ده في جزء من كلامه أنه يعني من كلام محمد وده
+
+480
+00:40:37,600 --> 00:40:42,820
+كلها واحدة يعني مفصلة عن بعض تكفي للحكم بردته
+
+481
+00:40:42,820 --> 00:40:50,480
+وتكفيره أخيرا طلع الراجل أو الراجل صراج وحراميقال
+
+482
+00:40:50,480 --> 00:40:54,740
+بأن حاجة دكتوره وعميد الأدب العربي حطوه سارق
+
+483
+00:40:54,740 --> 00:40:59,280
+أفكاره كلها من أفكار المستشريخين والمباشرين فكتابه
+
+484
+00:40:59,280 --> 00:41:03,440
+الشعر الجالي ماخده من مارجليوت معلم ورأيه في
+
+485
+00:41:03,440 --> 00:41:08,020
+المتنبي من إبلاشير وغير ذلك من هذه القراء وأخيرا
+
+486
+00:41:08,020 --> 00:41:12,060
+طب هذا هل توريكاه؟يعني وحده بهذه الأفكار في وقته و
+
+487
+00:41:12,060 --> 00:41:16,960
+زمانه شكلت له لجنة علمية خاصة من الأذر الشريف
+
+488
+00:41:16,960 --> 00:41:23,720
+لمحاكمته ومقضاطة على أقواله هذه وقيل يومه أن كتبه
+
+489
+00:41:23,720 --> 00:41:29,180
+هذه مملوقة بالإلحاد والزنتقةوإذا لم يرجع عنها فحكم
+
+490
+00:41:29,180 --> 00:41:32,100
+حكم المرتد وانا قرأت كثيرا في هذا المجال حكموا
+
+491
+00:41:32,100 --> 00:41:36,100
+عليه في وقتي بالردة إن لم يعد ويتراجع عن آرائي
+
+492
+00:41:36,100 --> 00:41:40,940
+وأفكاري وغالب الظن أنه لم يعد ولم يرجع حسب تحقيقات
+
+493
+00:41:40,940 --> 00:41:45,660
+برضه تبعتها وقرأتها إلى أن ماتلكن حكمه إلى الله
+
+494
+00:41:45,660 --> 00:41:50,160
+أما أفكار وادي كلها فأفكار يعني كفرية وفيها الردة
+
+495
+00:41:50,160 --> 00:41:56,520
+و الكفر بتعنيه في الإسلام و الدين و انتقاده لبعض
+
+496
+00:41:56,520 --> 00:42:00,440
+الحقائق القرآنية كما مر و أنا أتوقف عند الشخصية
+
+497
+00:42:00,440 --> 00:42:02,960
+الثانية و النموذج الثاني من مصر قاسم أمين في
+
+498
+00:42:02,960 --> 00:42:06,360
+المحاضرة القادمة ان شاء الله تعالى الله يعطيكوا
+
+499
+00:42:06,360 --> 00:42:06,620
+العفو
+