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Molecular control of reactive gas uptake "on water".

Reactive gas uptake on environmentally realistic aqueous surfaces is expected to be affected by a combination of multiple interactions. This issue is herein explored in experiments where the formation of Me(3)NH(+) on neat and doped water microjets exposed to Me(3)N(g) is monitored within <1 ms by online electrospray ionization mass spectrometry as a function of pH of the bulk liquid (pH(BLK)). Notably, Me(3)N(g) is protonated on the surface of neat water microjets below pH(BLK) approximately 4, rather than at pH(BLK) less than or approximately pK(A)(Me(3)NH(+)) = 9.8 as in bulk water. Me(3)N(g) uptake is significantly enhanced by anionic surfactants and fulvic acid (a surrogate of complex natural organic matter) above pH(BLK) approximately 4, uniformly depressed by cationics (which otherwise counteract FA effects), and unaffected by n-octanol. The direct hydrogen isotope effects associated with enhanced uptake of Me(3)N(g) on H(2)O/D(2)O microjets implicate a process controlled by proton transfer from interfacial donors whose coverage is electrostatically modulated by ionic headgroups. The finding that the combined effect of fulvic acid and tetrabutylammonium bromide closely matches the geometric mean of their separate effects on TMA uptake is evidence of strong dopant interactions.