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CoSALEN as a new catalyst for oxidation of fullerene C60

The effect of CoSALEN on anti-oxidative properties of fullerene C60 in the presence of O2 in cumene was investigated. A comparison was made between the role of the CoSALEN as a catalyst in the C60 oxidation and oxidation in the presence of an initiator, i.e., AIBN. A mechanism is proposed for the catalytic role of CoSALEN in oxidation of C60. Oxidation of octadecylaminofullerene C60 at the same conditions reveals that oxidation could be a result of hydroperoxidation of the unreacted sites of C60. We conclude that C60 as well as its amino-derivatives enhance the efficiency of CoSALEN in the oxidation of cumene due to their radical scavenging property of their unreacted double-bond sites.