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Wide-Gap p-c-:H Films and Their Application to Amorphous Silicon Solar Cells

Optimization of p-type hydrogenated microcrystalline silicon oxide thin films (p-c-:H) by very high frequency plasma enhanced chemical vapor deposition 40 MHz method for use as a p-layer of a-Si:H solar cells was performed. The properties of p-c-:H films were characterized by conductivity, Raman scattering spectroscopy, and spectroscopic ellipsometry. The wide optical band gap p-c-:H films were optimized by CO2/SiH4 ratio and H2/SiH4 dilution. Besides, the effects of wide-gap p-c-:H layer on the performance of a-Si:H solar cells with various optical band gaps of p-layer were also investigated. Furthermore, improvements of open circuit voltage, short circuit current, and performance of the solar cells by using the effective wide-gap p-c-:H were observed in this study. These results indicate that wide-gap p-c-:H is promising to use as window layer in a-Si:H solar cells.