Highly selective electrocatalytic CO2 reduction to ethanol
Highly selective electrocatalytic CO2 reduction to ethanol by metallic clusters dynamically formed from atomically dispersed copper

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                Download referencesAcknowledgementsThis material is based on work supported by Laboratory Directed Research and Development funding from Argonne National Laboratory, provided by the Director, Office of Science, of the US Department of Energy (DOE) under contract no. DE-AC02-06CH11357. The works performed at Argonne National Laboratory’s Center for Nanoscale Materials and APS, US DOE Office of Science User Facilities, are supported by Office of Science, US DOE under contract no. DE-AC02-06CH11357. Part of the DFT calculations were also performed using the computational resources provided by the Laboratory Computing Resource Center at the Argonne National Laboratory. T.X. acknowledges the financial support from the XSD visiting scientist program at APS at Argonne. C.L.’s work is supported by the US DOE, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences, under contract no. DE-AC02-06CH11357 (Argonne National Laboratory). The views and opinions of the authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof; neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, nor usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. We also acknowledge I. Hwang for verification of our EXAFS simulation by Artemis.Author informationAuthor notesThese authors contributed equally: Haiping Xu, Dominic Rebollar.Authors and AffiliationsChemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL, USAHaiping Xu, Dominic Rebollar, Lina Chong, Cong Liu, John V. Muntean & Di-Jia LiuDepartment of Chemistry and Biochemistry Northern Illinois University, DeKalb, IL, USAHaiping Xu, Dominic Rebollar, Tao Li & Tao XuDepartment of Physics and Astronomy, Valparaiso University, Valparaiso, IN, USAHaiying HeCenter for Nanoscale Materials, Argonne National Laboratory, Lemont, IL, USAYuzi LiuX-ray Science Division, Argonne National Laboratory Argonne, Lemont, IL, USACheng-Jun Sun, Tao Li & Randall E. WinansPritzker School of Molecular Engineering, The University of Chicago, Chicago, IL, USADi-Jia LiuAuthorsHaiping XuYou can also search for this author in
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                        PubMed Google ScholarContributionsD.-J.L. and T.X. designed and supervised the experiment with assistance from C.L. and T.L. C.L. led and H.H. assisted the computational investigations. T.L. led and H.X., L.C., Y.L., C.S., J.V.M. and R.E.W. assisted the characterization of catalysts structure and catalysis products. H.X. and D.R. synthesized catalysts, conducted electrochemical study and data analysis. H.X., H.H., C.L., D.-J.L. and T.X. wrote the manuscript.Corresponding authorsCorrespondence to
                Cong Liu, Tao Li, Di-Jia Liu or Tao Xu.Ethics declarations
              
                Competing interests
                An US patent application (US 2019/0276943 A1) on amalgamated metal—Li catalyst synthesis for CO2 conversion with D.-J. Liu, T. Xu, H. Xu and D. Rebollar as the coinventors was filed by UCHICAGO ARGONNE, LLC. The authors declare no other competing interests.
              
            Additional informationPublisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.Supplementary informationSource dataSource Data Fig. 3Source data of Fig. 3b for the ethanol error bar calculation and total error bar calculation.Source Data Fig. 4Source data of Fig. 4a,b for the error bar calculation.Rights and permissionsAbout this articleCite this articleXu, H., Rebollar, D., He, H. et al. Highly selective electrocatalytic CO2 reduction to ethanol by metallic clusters dynamically formed from atomically dispersed copper.
                    Nat Energy 5, 623–632 (2020). https://doi.org/10.1038/s41560-020-0666-xDownload citationReceived: 15 February 2019Accepted: 02 July 2020Published: 27 July 2020Issue Date: August 2020DOI: https://doi.org/10.1038/s41560-020-0666-x
            