Here is a Python script that sorts a list of numbers and words by their total ord() values:

```
def calculate_ord_total(item):
    if isinstance(item, int):
        item = str(item)
    return sum(ord(char) for char in item)

def sort_by_ord_total(items):
    return sorted(items, key=calculate_ord_total)

# Example usage:
mixed_list = [42, 'apple', 33, 'banana', 'kiwi', 21, 'orange']
sorted_list = sort_by_ord_total(mixed_list)

print(f"Original list: {mixed_list}")
print(f"Sorted list: {sorted_list}")
```

This script defines a function calculate_ord_total() to calculate the total ord() values of an item in the list. The sort_by_ord_total() function sorts the list by the total ord() values using the sorted() function with a custom key. The example usage demonstrates how to use the script to sort a mixed list of numbers and words by their total ord() values.
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