Electric shock occurs when voltage in the form of a current of electrons moves through the body. Action potentials do not operate this way, as it is neither a traditional current nor does it consist of electrons. Ions are released through the membrane and later pumped back into resting position. No particles are flowing in a current. The action potential follows a chart which you can find images of online. The voltage changes from -70 mV to 40 mV before overcorrecting below -70 mV and finally reaching resting position again. Touching exposed nerves would certainly not shock you, though I advise against doing it anyways.
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