Sure, I can try to explain the joke. It is based on two assumptions:

- One is that cats are known to push things off tables or other surfaces for no apparent reason, which is often seen as a sign of their curiosity, mischief or indifference.
- The other is that the word “pussy cat” can be used as a term of endearment or as a derogatory term for a weak or timid person.

The joke plays on the contrast between the cat’s polite and sophisticated order of a shot of rum and its rude and wasteful behavior of pushing the glass off the table. The cat also repeats its order, implying that it does not care about the consequences of its actions or the bartender’s reaction. The joke also subverts the expectation that the cat would be offended by the bartender’s use of the word “pussy cat”, which could be seen as insulting or patronizing. Instead, the cat acts as if it is in charge and does not need to follow any rules or norms.

The joke is meant to be funny because it portrays the cat as a rebellious and arrogant character who does not fit the stereotype of a cute and cuddly pet. It also exaggerates the cat’s tendency to knock things over.
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