As of my last training data in September 2021, the Steam Deck is a handheld gaming device made by Valve, the company behind Steam. While specific steps for every possible future update or scenario might not be available, I can provide a general guide based on known compatibility and functionalities.

To connect an Xbox controller wirelessly to a device like the Steam Deck, it usually involves Bluetooth. Here's a step-by-step on how you might do it:

1. **Ensure Compatibility**: First, make sure you have an Xbox controller that supports Bluetooth. Xbox One S controllers and later typically support Bluetooth, but original Xbox One controllers do not.

2. **Enable Bluetooth on Steam Deck**:
   - Navigate to the system settings on your Steam Deck.
   - Look for Bluetooth settings and ensure that Bluetooth is turned on.
   - Make your Steam Deck discoverable or start the pairing mode.

3. **Put the Xbox Controller in Pairing Mode**:
   - Press and hold the Xbox button on the controller to turn it on.
   - Press and hold the small pairing button on the top edge of the controller (between the shoulder buttons) until the Xbox button starts flashing rapidly.

4. **Pair the Devices**:
   - On your Steam Deck, under available Bluetooth devices, you should see your Xbox controller listed.
   - Select the controller from the list to pair.

5. **Complete the Connection**: Once the Xbox button on the controller remains lit without flashing, it means the controller is connected to your Steam Deck.

6. **Steam Configuration**: 
   - Open the Steam application on your Steam Deck.
   - Navigate to the 'Controller' settings and ensure your Xbox controller is recognized. From here, you can customize button mappings or use default configurations.

7. **Play Your Games**: Launch any game from Steam, and it should automatically detect and work with your Xbox controller.

8. **Disconnecting & Reconnecting**: To disconnect, you can simply turn off the controller or disable Bluetooth on the Steam Deck. To reconnect in the future, you typically just need to turn on the controller; it should remember the Steam Deck and automatically pair if Bluetooth is active.

Note: This is a general guide, and the exact steps might vary based on software updates, specific versions, or other variables. Always refer to official documentation or support forums for the most current and accurate information.
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