Use ventilation, local exhaust or breathing protection.
Fresh air, rest. Refer for medical attention.
MAY BE ABSORBED! Dry skin. Redness.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
Wear safety spectacles or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Nausea. Vomiting. See Inhalation.
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention .
CLASSIFICATION & LABELLING
Evacuate danger area! Consult an expert! Remove all ignition sources. Cover the spilled material with dry earth, sand or other non-combustible material. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Personal protection: self-contained breathing apparatus.
According to UN GHS Criteria
Transportation UN Classification
UN Hazard Class: 3; UN Pack Group: I
PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance MOBILE LIQUID.
Physical dangers The vapour is heavier than air and may travel along the ground; distant ignition possible. The vapour mixes well with air, explosive mixtures are easily formed. As a result of flow, agitation, etc., electrostatic charges can be generated.
Boiling point: 20-200°C Relative density (water = 1): 0.70-0.80 Solubility in water: none Relative vapour density (air = 1): 3 - 4 Flash point: <-21°C Auto-ignition temperature: ~250°C Explosive limits, vol% in air: 1.3-7.1 Octanol/water partition coefficient as log Pow: 2-7
EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion.
Effects of short-term exposure The substance is irritating to the eyes, skin and respiratory tract. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The substance may cause effects on the central nervous system.
Inhalation risk A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.
Effects of long-term or repeated exposure The substance defats the skin, which may cause dryness or cracking. The substance may have effects on the central nervous system and liver. This substance is possibly carcinogenic to humans.
OCCUPATIONAL EXPOSURE LIMITS
TLV: 300 ppm as TWA; 500 ppm as STEL; A3 (confirmed animal carcinogen with unknown relevance to humans)
The substance is harmful to aquatic organisms.
Depending on the degree of exposure, periodic medical examination is suggested. The product may contain additives which may alter the health and environmental effects.
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Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.
Tumia uingizaji hewa, hewa ya nje ya mahali hapo au ulinzi wa kupumua. Hewa safi, pumzika. Mwongozee kwa matibabu. Huenda Ilichukuliwa! Ngozi kavu. Mwekundu. glavu za kinga. Mavazi ya kujilinda. Ondoa nguo zilizochafuliwa. Osha na kisha osha ngozi kwa maji na sabuni. Vaa miwani ya usalama au ulinzi wa macho pamoja na ulinzi wa kupumua. Kwanza, futa kwa maji mengi kwa dakika kadhaa (ondoa lensi za mawasiliano ikiwa inawezekana), kisha tafuta matibabu. Kutoweza kula. Kutochoka. Angalia kupumua. Usile, usinywe, au uvimbe sigareti wakati wa kazi. Osha kinywa. Usichoche kupumua. Mpe glasi moja au mbili za maji ya kunywa. Tafuta matibabu. Classification & LABELING Evacuate eneo hatari! Mshauri mtaalamu! Ondoa vyanzo vyote vya kuwasha. Funika vifaa vilivyomwagika kwa udongo kavu, mchanga au vifaa vingine visivyoweza kuwaka. Usifue maji hayo kwenye mfereji wa maji machafu. Usiruhusu kemikali hii iingie katika mazingira. Ulinzi wa kibinafsi: vifaa vya kupumua vya kujitegemea. "Kwa mujibu wa UN GHS, ""Utaratibu wa Uhamisho wa Umoja wa Mataifa, darasa la hatari: 3; kundi la pakiti: I; habari za kimwili na kemikali: hali ya kimwili: muonekano: kioevu cha kuhamisha.""" Hatari za kimwili Mvuke ni nzito kuliko hewa na inaweza kusafiri kando ya ardhi; kuwaka mbali inawezekana. Mvuke huchanganyika vizuri na hewa, mchanganyiko wa mlipuko hufanyizwa kwa urahisi. Kama matokeo ya mtiririko, agitation, nk, malipo electrostatic inaweza kuzalishwa. Kiwango cha kuchemsha: 20 ° C, ukali wa kiasi (maji = 1): 0.70-0.80; ufumbuzi katika maji: hakuna; Kiwango cha mvuke: 3 - 4; Kiwango cha moto: < -21 ° C; Kiwango cha mlipuko: ~ 250 ° C; Kiwango cha mlipuko: ~ 1.3-7.1; Kiwango cha mlipuko: ~ 0.7; Kiwango cha mlipuko: ~ 0.7; Kiwango cha mlipuko: ~ 0.7; Kiwango cha mlipuko: ~ 0.7; Kiwango cha mlipuko: ~ 0.7; Kiwango cha mlipuko: ~ 0.7; Kiwango cha mlipuko: ~ 0.7; Kiwango cha mlipuko: ~ 0.7; Kiwango cha mlipuko: ~ 0.7 Athari za mfiduo wa muda mfupi Dutu ni irritating kwa macho, ngozi na njia za kupumua. Kioevu hiki kikimezwa, kunyonya ndani ya mapafu kunaweza kusababisha nimoniti ya kemikali. Dutu hiyo yaweza kusababisha athari kwenye mfumo wa neva wa kati. Hatari ya kupumua: Uchafuzi mbaya wa hewa unaweza kufikiwa haraka sana kwa mvuke wa dutu hii kwa joto la 20 ° C. Athari za mfiduo wa muda mrefu au mara kwa mara Dutu hiyo huondoa ngozi, ambayo inaweza kusababisha ukame au kupasuka. Dutu hiyo yaweza kuwa na athari kwenye mfumo wa neva wa kati na ini. Huenda dutu hiyo ikawa na kansa kwa wanadamu. Kiwango cha Uwezo wa Utafiti wa Kazi (TEL) ni 300 ppm (TWA) na A3 (A1c) (Uwezo wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti wa Utafiti). Ikitegemea kiwango cha kuambukizwa, uchunguzi wa kitiba wa mara kwa mara unapendekezwa. Bidhaa inaweza kuwa na nyongeza ambayo inaweza kubadilisha afya na athari za mazingira. Haki zote zimehifadhiwa. Vifaa vilivyochapishwa vinagawanywa bila dhamana ya aina yoyote, iwe imeelezwa au imeelezwa. ILO, WHO, na Tume ya Ulaya hazina jukumu la tafsiri na matumizi ya habari zilizomo katika nyenzo hizi.