text:
•• describe and analyse the processes involved in the dissolution of ionic compounds in water
•• investigate the use of solubility equilibria by Aboriginal and Torres Strait Islander Peoples when removing
How does solubility relate toxicity from foods, for example: ATSIHC
to chemical equilibrium? – toxins in cycad fruit
•• conduct an investigation to determine solubility rules, and predict and analyse the composition of
substances when two ionic solutions are mixed, for example:
– potassium chloride and silver nitrate
– potassium iodide and lead nitrate
– sodium sulfate and barium nitrate (ACSCH065)
•• derive equilibrium expressions for saturated solutions in terms of Ksp and calculate the solubility of an ionic
substance from its Ksp value ICT N
•• predict the formation of a precipitate given the standard reference values for Ksp.
Chemistry Stage 6 Syllabus © NSW Educational Standards Authority for and on behalf of the
Crown in right of the State of New South Wales, 2017
9780170408998 81
Solubility is an important concept that
4.1 Revision
In this chapter, you will focus on the solubility of ionic compounds in water. Before you look at how ionic
WS compounds and water interact, you will briefly revise the structure of ionic compounds and the structure
of water.
Prior knowledge
2 1 2 1 2 1 2 1
1 2 1 2 1 2 1 2
a b
Lewis diagram Structural formula for water
for water showing the direction of
dipole forces. The electrons
are attracted more strongly
to the oxygen.
c d
Adding d2
Resultant O Overall polarity
dipole forces of water
together H H d1
Since water is polar and there is a large difference in electronegativity between the oxygen and
hydrogen atoms within the molecule, water displays hydrogen bonding, as shown in Figure 4.4.
Another property of water is its ability to act as a solvent. Pure water is liquid from 0°C to 100°C. This
means that it can act as a solvent over this temperature range. Water dissolves and transports a range
of materials across the whole planet and also through each cell of a living organism. Water does this
by forming hydrogen bonds or ion–dipole bonds with a wide range of substances from salts to organic
molecules such as proteins.
Water of crystallisation
Water of crystallisation occurs when water molecules are attracted to the ions of a salt. Many ionic
compounds that crystallise out of an aqueous solution include water molecules in a regular array through
the crystal lattice. The water molecules are in a set ratio to the ionic substance. These compounds are
said to be hydrated. For example, CuSO4⋅5H2O has five water molecules of crystallisation per unit of
Key: Oxygen atom Hydrogen atom Sulfur atom Copper atom Ion–dipole bond
FIGURE 4.5 The crystals of copper(II) sulfate consist of an octahedral arrangement of water molecules and
sulfate ions around the central copper ion.
Refer to
Chemistry in
Focus Year 11
Investigation The water of crystallisation can be evaporated by heating the hydrated compound. When all the
7.4 ('Empirical
formula for water molecules have been removed, the compound is said to be anhydrous. To do this, a known mass of
hydrated copper the hydrated compound is heated so that the mass of water removed can be determined. From this, the
empirical formula of the hydrate can be calculated.
Water of crystallisation
Critical Some salts are different colours in their hydrated and anhydrous forms (for example, CuSO4⋅5H2O is blue, while
and creative
thinking anhydrous CuSO4 is white). Therefore, it is relatively easy to determine when all of the water has evaporated, so
that there is only CuSO4 remaining. However, some ionic salts do not change colour when the water evaporates.
Numeracy Both the hydrated and anhydrous salts are the same colour, usually white. In this case, it is more challenging to
determine the end point (that is, when all of the water has evaporated so that only the anhydrous salt remains).
In this investigation, you will be planning and performing an experiment to determine the formula for the
hydrated salt for several ionic salts.
Write an aim for your investigation.
Hydrated salts for the following ionic compounds will be provided:
•• Barium chloride
•• Calcium chloride
•• Magnesium sulfate
•• Sodium carbonate
Devise a method for your investigation.
How will you know when the investigation has reached its end point?
Record your results in a carefully planned table.
Analyse your data to determine the formula for each of the hydrated salts.
With reference to the data obtained and its analysis, write a conclusion based on the aim for this investigation.
Discuss any limitations in your methodology.
●● A solute dissolves when the energy of the bonds it forms with water is lower than the energy of
the bonds between water molecules or between the ions of the substance being dissolved. The
energy difference explains why some ionic salts dissolve in water and some do not.
The H atoms have a build-up of
positive charge, so they orientate
towards a negative ion.
The O atoms have a build-up
of negative charge, so they
orientate towards a positive ion.
This is now called a hydrated
cation or an 'aquo-cation'.
Cl ion Na ion Water molecule H atom O atom Ion–dipole
that has become attraction
a water ligand
FIGURE 4.6 A simplified model of the solution process for a sodium chloride crystal in water
FIGURE 4.7 The role of energy factors in controlling the solubility of ionic compounds
side of the glass is scratched, then the extra sugar will
precipitate out again. This is because the solution is 70 CaCl2 KNO3 K2Cr2O7
unstable. Toffee is a supersaturated solution of sugar,
so to stop the toffee crystallising, a mixture of sugars
or the addition of some fats can be used to stabilise 50
the solution.
Solubility curves 30
Refer to the solubility curve in Figure 4.9 for this worked example. Numeracy
1 At 20°C, approximately 12 g of K2Cr2O7 •• Find the curve for K2Cr2O7 on the graph. Draw a line from 20°C up to the
will dissolve in 100 g of water. potassium dichromate curve. Then draw a line from this point across to the y axis,
as shown in Figure 4.9. This will indicate the amount that will dissolve at 20°C.
FIGURE 4.9 Calculating
the amounts of potassium 100
dichromate (K2Cr2O7) that
Solubility (g of salt/100 g of water)
To gather data to draw a solubility curve for potassium chloride.
The Bunsen burner will get hot. Do not use the Bunsen burner if the gas tube is damaged. ASSESSMENT
Ensure long hair is tied back and the flame is away from
flammable material. If you burn yourself, place the affected
part under cold running water for 20 minutes and inform
your teacher.
Broken glassware will cut. Inspect and discard any chipped or cracked glassware, no
matter how small the damage. Sweep up broken glass with
a brush and dustpan; do not use your fingers.
What other risks are associated with your investigation? How can you Thermometer Stirring rod
manage these?
Test tube
1 3.00 10.00
2 3.40 10.00
3 3.80 10.00
4 4.20 10.00
5 4.60 10.00
6 5.00 10.00
1 Use the class results to plot a graph of solubility against temperature. Plot the temperature along the
horizontal axis (0–100°C).
2 From the graph, predict the solubility of potassium chloride at 20°C, 40°C, 60°C and 80°C.
●● The solubility of a solute is the maximum mass in grams that can dissolve in 100 g of the
solvent at a given temperature.
Homework ●● A solubility curve shows how much of a solute, such as a salt, can be dissolved at a particular
Solubility and
that could create health issues for humans if they ate small
quantities of these plants. For example, Planchonia careya,
commonly referred to as the cocky apple, had fruit that was
edible, though its bark and roots contained toxins.
Australia's first peoples developed an understanding
about how to process plants to remove or deactivate the
toxins. Some plants required pounding and roasting, while
others required more extensive processing such as washing
or leaching. This enabled them to increase the number of
species that they could use as food sources – it increased
variety in their diet. For example, the cycad, Bowenia
spectabilis, found in tropical north-eastern Queensland is
the most toxic cycad in the world with the highest level of
mercury (Figure 4.11). However, Australia's first peoples ate
the roots of this plant. It may have provided a food source at a FIGURE 4.11 Bowenia spectabilis, a cycad
found in north-eastern Queensland
time of the year when other foods were less readily available.
FIGURE 4.12 Distribution of cycad genuses in Australia – Bowenia (yellow), Cycas (blue), Macrozamia (red) and Lepidozamia (green)
Cycads regenerate quickly after fire; hence, they are an available food source when
other plants are not available since they take longer to regenerate. So, developing techniques
to remove the toxins in cycads improved the lifestyle of Australia's first peoples.
1 Cycads and other very toxic plants, such as the yellow walnut (Beilschmiedia bancroftii),
N required complex processing. The first step was to cook the plant, then in some cases it was
H pounded, sliced or ground into a meal; however, the most important step in removing the
O toxins was leaching.
O O Leaching involves the use of water to dissolve the toxin and remove it from the
plant. Hence, it is used when the toxins are water soluble and there is a readily
available water supply. Cycasin's solubility is 56.6 g L−1 of water. Therefore, leaching
was a very effective process for removing the toxin. The molecular structure of
H cycasin is shown in Figure 4.13. Australia's first peoples placed the parts of the plants
to be leached (for example, seeds or kernels) in a finely woven basket made from
FIGURE 4.13 lawyer cane (Calamus australis), which was placed in a flowing creek so that the toxin
The toxin, cycasin,
would dissolve and flow away with the water. This process could take as little as a few
glucoside, is commonly hours or as long as several days. Accounts vary regarding the treatment, especially how
found in cycads.
long the leaching process occurred.
Concentration of ions
dissolve in the water, and hence, the concentration of salts increases until Dynamic
the water cannot dissolve any more salts. Dynamic equilibrium is reached – equilibrium
the rate at which salts are dissolving in the water is equal to the rate at established
which the salts are moving back into the artefact (Figure 4.14). At this
point, the artefact is removed from the container, the solution is discarded
and the container is refilled with fresh water. The artefact is returned to the
container and the process continues.
Australia's first peoples did not have to replace the water since they Time
placed their baskets in flowing creeks, so the toxins were carried away with
FIGURE 4.14 A graph indicating the change in
the water and it never reached dynamic equilibrium. concentration of ions over time during leaching.
It also indicates when dynamic equilibrium
occurs and it is time to replace the water.
●● Australia's first peoples developed an understanding about how to process plants to remove or
deactivate the toxins.
1 Define the following terms. UNDERSTANDING
a Solubility
b Toxin 4.3 4.4
2 Distinguish between a saturated and a supersaturated solution.
3 Use Figure 4.8 (page 87) to answer the following questions.
a What is the solubility of lead(II) nitrate at 20°C?
b Describe the effect on the solubility of cerium sulfate of increasing the temperature from 0°C to 30°C.
c Quantitatively compare the solubility of potassium dichromate at 50°C to its solubility at 90°C.
d Justify the shape of the graph for the solubility of cerium sulfate as the temperature is increased from
50°C to 90°C.
4 Using Figure 4.8, determine how many moles of potassium chlorate will dissolve at 70°C.
5 Explain why leaching was an effective method for removing toxins from cycads.
Precipitation reactions
Science Source/Charles D. Winters
In chapter 10 of Chemistry in Focus Year 11, you saw that when solutions of certain
ionic compounds were mixed, they sometimes reacted to produce a solid called a
precipitate. This type of reaction was called a precipitation reaction.
For example, when sodium chloride solution is added to silver nitrate solution,
a white solid of silver chloride is formed. When the solution of Na+ and Cl− ions is
mixed with the solution of Ag+ and NO3− ions, the result is a solution containing
all the ions moving randomly throughout (that is, no precipitate is formed).
Remember that each of the ions is surrounded by water molecules. The Ag+ and
Cl− ions are more strongly attracted to each other than they are to the water, so
they cluster together in groups and form a solid, which precipitates out of solution,
FIGURE 4.15 A silver chloride precipitate
as shown in Figures 4.15 and 4.16.
FIGURE 4.16 Explaining the formation of silver chloride precipitate (Note: This is a simplified model of the association process.)
Predicting precipitation
By systematically mixing solutions that
To compare the solubility of a range of ionic substances through precipitation reactions.
ations (all 0.1 mol L−1, except lead(II) nitrate, which is 0.02 mol L−1) in dropper bottles: sodium nitrate
(NaNO3), silver nitrate (AgNO3), lead(II) nitrate (Pb(NO3 )2), ammonium nitrate (NH4NO3), magnesium sulfate
(MgSO4), iron(II) sulfate (FeSO4), copper(II) sulfate (CuSO4), zinc sulfate (ZnSO4), aluminium sulfate (Al2(SO4)3),
barium chloride (BaCl2), calcium chloride (CaCl2), iron(III) chloride (FeCl3)
ASSESSMENT Chemicals could splash on your skin or into your eyes. Wear safety glasses and avoid contact with skin. If contact
occurs, wash thoroughly with soap and water.
Some chemicals are not able to be disposed of down the sink. You can wipe the chemicals up with a paper towel. Refer to
safety data sheets or use the RiskAssess program to identify
alternative methods of disposal.
What other risks are associated with your investigation? How can you manage these?
1 Draw up a grid on an overhead projector sheet with anions written across the top and cations down
the side.
2 Place the grid against a dark background (a dark laboratory bench or sheet of black paper).
3 Place one drop each of the appropriate chemicals on the grid. There should be two drops (one solution on
top of the other solution) in each square of the grid.
4 Record observations.
Record all observations in an appropriate format.
Summarise your results into statements such as 'All nitrates are… '
1 a Compare the results of the experiment with the solubility rules in Table 4.1 (page 97).
b What, if any, were the discrepancies between your results and Table 4.1? Suggest a reason for these
discrepancies and a way of resolving them.
2 Write a balanced net ionic equation for each of the reactions in which a precipitate was obtained.
Summarise the solubility rules according to your results.
Table 4.1 summarises the solubility of common ionic compounds. The table applies to the cations
in groups 1 and 2, NH4+, Al3+, Cr3+, Mn2+, Fe2+, Fe3+, Cu2+, Co2+, Ni2+, Ag+, Zn2+, Sn2+, Cd2+ and Pb2+. The
table is organised in terms of the solubility of various anions. An additional useful generalisation is that
all group 1 and NH4+ salts are soluble.
Chemists are often asked to identify substances such
as cations and anions that may have contaminated
food, soil and water. Precipitation reactions are useful
for finding out whether a particular anion or cation is
present; for example, chemists could use precipitation
reactions to test for lead or cadmium in water supplies.
Precipitation reactions can also be used to remove
unwanted substances from water.
The data in Table 4.1 can be used to predict whether or
not a precipitate will form when particular solutions are FIGURE 4.18 Chemists working in an
analytical laboratory
Magnesium iodide (MgI2) • Write the formula of the compounds present.
1 Precipitate is AgI.
MgI2 + AgNO3 → AgI + Mg(NO3)2 •• Predict the products by swapping the partners of the reacting
compounds and check that the formulae are correct.
Neutral species equation: •• Use Table 4.1 to see if either of the products is insoluble. All
MgI2(aq) + 2AgNO3(aq) → 2AgI(s) + Mg(NO3)2(aq) nitrates are soluble, all iodides are soluble except Ag+ and Pb2+,
so AgI will precipitate.
Write an aim for your investigation.
Write your method in a logical sequence of steps. Hint: You need to use solubility rules.
Record your observations in a carefully planned table.
Consider what your results show. Look at theoretical predictions you made about possible precipitates and
compare your results with these. Are there any differences or inconclusive results? Do you need to repeat any
tests? Do you need to use an alternative solution for confirmation?
With reference to the data obtained and its analysis, write a conclusion based on the aim of this investigation.
1 Define 'precipitate'. UNDERSTANDING
2 Explain what is meant by a 'spectator ion'.
3 Which of the following substances are soluble in water? 4.5
a Sodium hydroxide
b Aluminium oxide
c Copper(II) sulfate
d Silver carbonate
e Lithium chloride
4 Name a different pair of substances (using suitable amounts) that you could dissolve in one sample of
water to produce a solution identical with that containing:
a potassium chloride and zinc nitrate
b ammonium sulfate and sodium carbonate
c magnesium bromide and copper(II) sulfate.
Write the equilibrium expression for each of the following insoluble compounds. Numeracy
1 Calcium hydroxide
Critical and
2 Iron(II) phosphate creative thinking
2+ −
1 Ca(OH)2(s) ⇌ Ca (aq) + 2OH (aq) •• Write the balanced chemical equation for the compound and
its ions.
K sp = [Ca 2 + ] × [OH − ]2 •• Write the equilibrium expression for this heterogeneous
system. Remember to:
only include aqueous species
raise each species to the power of its coefficient in the
balanced chemical equation.
2 Fe3(PO4)2(s) ⇌ 3Fe2+(aq) + 2PO43−(aq) •• Write the balanced chemical equation for the compound and
its ions.
K sp = [Fe2 + ]3 × [PO 34 − ]2 •• Write the equilibrium expression for this heterogeneous
system. Remember to:
only include aqueous species
raise each species to the power of its coefficient in the
balanced chemical equation.
●● Dynamic equilibrium is when the rate at which ions are breaking away from the ionic lattice is
equal to the rate at which ions are rejoining the lattice. It is shown by the expression:
AB2(s) ⇌ A2+(aq) + 2B−(aq)
Relationship between
the Ksp and solubility
When a salt is dissolved in distilled water, there is a direct relationship between the solubility product and
the concentration of each of the ions measured in mol L−1, sometimes referred to as the molar solubility.
This only occurs when there are no other contaminants present, and only the salt and water are present.
Critical and
The solubility of zinc hydroxide is 0.001 g/100 g water at 298 K. Calculate the Ksp for zinc hydroxide. creative thinking
Zn(OH)2(s) ⇌ Zn2+(aq) + 2OH−(aq) •• Write the balanced equation for the solubility of the salt.
Solubility of Zn(OH)2 = 0.001 g/100 g H2O •• Convert the solubility data into mol L−1.
Ksp = [1.01 × 10−4] × [2.02 × 10−4]2 = 4.12 × 10−12 •• Substitute data into equilibrium expression to calculate Ksp.
1 The molar solubility of iron(II) sulfide is 0.0006 g/100 g of water at 25°C. Calculate the Ksp for
iron(II) sulfide.
2 The molar solubility of calcium phosphate is 0.002 g/100 g of water at 25°C. Calculate the Ksp for
calcium phosphate.
2+ 2−
MnCO3(s) ⇌ Mn (aq) + CO3 (aq) •• Write the balanced equation for the solubility of the salt.
2.24 × 10−11 = [s] × [s] •• Substitute data into the equilibrium expression to calculate 's'.
2 −11
s = 2.24 × 10
s = 2.24 × 10 −11
s = 4.73 × 10−6
[Mn2+] = 4.73 × 10−6 mol L−1 •• Calculate the [Mn2+] and [CO32−].
[CO32−] = 4.73 × 10−6 mol L−1
The Ksp for calcium iodate Ca(IO3)2 is 6.47 × 10−6 at 25°C. Calculate the concentrations of the calcium
ions and iodate ions in a saturated aqueous solution of calcium iodate.
2+ −
Ca(IO3)2(s) ⇌ Ca (aq) + 2IO3 (aq) •• Write the balanced equation for the solubility of the salt.
6.47 × 10 −6
s = 3
s = 0.0117
1 The Ksp for silver chloride is 1.77 × 10−10 at 25°C. Calculate the concentrations of the silver ions and
chloride ions in a saturated aqueous solution of silver chloride.
2 The Ksp for barium hydroxide is 2.55 × 10−4 at 25°C. Calculate the concentrations of the barium ions
and hydroxide ions in a saturated aqueous solution of barium hydroxide.
3 The Ksp for copper(II) phosphate, Cu3(PO4)2, is 1.40 × 10−37 at 25°C. Calculate the concentrations of
the copper ions and phosphate ions in a saturated aqueous solution of copper(II) phosphate.
The Ksp can also be used to determine the solubility of the solute at a specific temperature.
The Ksp for calcium iodate, Ca(IO3)2, is 6.47 × 10−6 at 25°C. Calculate the solubility of calcium iodate in Critical and
creative thinking
g/100 g H2O at 25°C and determine whether it would be classified as sparingly soluble or insoluble.
Ca(IO3)2(s) ⇌ Ca2+(aq) + 2IO3−(aq) •• Write the balanced equation for the solubility of the salt.
2+ −1
[Ca ] = s mol L •• Determine the concentration for each of the ions.
•• Using mole ratios from the balanced equation, 1 mole of Ca(IO3)2(s)
[IO3−] = 2s mol L−1 ionises to form 1 mole of Ca2+ ions and 2 moles of IO3− ions.
•• You do not know the solubility of Ca(IO3)2, so give it the value 's' (for
solubility in mol L−1).
•• Therefore, s mol L−1 of Ca(IO3)2 ionises to form s mol L−1 of Ca2+ ions
and 2s mol L−1 of I3− ions.
K sp = [Ca 2 + ] × [IO 3− ]2 •• Write the equilibrium expression.
−6 2
6.47 × 10 = [s] × [2s] •• Substitute data into equilibrium expression to calculate 's'.
Ionic product
As stated earlier, you can only use the symbol Ksp when there is an equilibrium system; that is, when
there is a saturated solution and both solid and ions are present. Equilibrium systems will only occur
for 'sparingly soluble' or 'insoluble' salts. However, if there is a very, very dilute solution of a sparingly
soluble salt, such as lead(II) bromide, then the concentrations of the ions will be too small to produce
any precipitate. In this case, equilibrium will not occur, since there is no solid lead(II) bromide present.
Hence, the reaction quotient for this system is called the ionic product and is denoted as Qsp.
◗◗ If Qsp < Ksp, the forward reaction will be favoured to reach equilibrium (that is, no precipitate has
formed and it is an unsaturated solution).
◗◗ If Qsp = Ksp, the reaction has reached dynamic equilibrium (that is, it is a saturated solution).
◗◗ If Qsp > Ksp, the reverse reaction will be favoured to reach equilibrium (that is, it is a supersaturated
0.500 g of Ba(OH)2 was placed into 200 mL of water at 25°C and stirred. Determine Critical and
whether a precipitate forms. Ksp for Ba(OH)2 at 25°C is 2.55 × 10−4. creative thinking
Ba(OH)2(s) ⇌ Ba2+(aq) + 2OH−(aq) •• Write the balanced equation for the solubility of the salt.
0.500 × 5 = 2.50 g L •• Calculate [Ba(OH)2] in mol L−1.
•• Convert g/200 mL to gL−1.
[Ba(OH)2] = 0.0146 mol L−1
•• Convert gL−1 to mol L−1.
m 2.50
n= = = 0.0146 mol L−1
Qsp = [Ba2+] × [OH−]2 •• Write the equation for the ionic product.
Qsp = [0.0146] × [0.0292]2 = 1.24 × 10−5 •• Substitute data into the equilibrium expression to calculate Qsp.
0.0118 mol L−1 Pb2+ reacted with 0.236 mol L−1 Br−. Determine whether a precipitate formed. Ksp for PbBr2
at 25°C is 6.60 × 10−6.
●● When a salt is dissolved in distilled water, there is a direct relationship between the solubility
product and the concentration of each of the ions measured in mol L−1 (this is referred to as the
molar solubility).
Solubility equilibrium
1 Define the following terms. UNDERSTANDING
a Molar solubility
b Insoluble 4.7
2 Calculate the Ksp for Co(OH)2 at 25°C given that its molar solubility is 1.14 × 10−5 mol L−1.
3 a Calculate the [Fe2+] and [CO32−] in a saturated solution of FeCO3 given that it has a Ksp of 3.13 × 10−11 at 25°C.
b Calculate the [Eu3+] and [OH−] in a saturated solution of Eu(OH)3 given that it has a Ksp of 9.38 × 10−27 at 25°C Numeracy
4.93 × 10 −5
s = = 4.93 × 10−4 … (4.9)
Hence, [Ca2+] = 4.93 × 10−4 mol L−1 when CaSO4 dissolves in 0.100 mol L−1 Na2SO4 solution. This is less
than the [Ca2+] when it was dissolved in water. Therefore, CaSO4 is less soluble in a Na2SO4 solution than
it is in water. This supports the qualitative effect determined using Le Chatelier's principle.
Also, note that in equation 4.9, s = 4.93 × 10−4, which is significantly less than 0.100. Hence, the
assumption made in equation 4.8 is valid.
Compare, both qualitatively and quantitatively, the solubility of silver iodide in water with its solubility Critical and
in 0.250 mol L−1 KI. Ksp for silver iodide is 8.52 × 10−17 at 25°C. creative thinking
AgI(s) ⇌ Ag+(aq) + I−(aq) •• Write the balanced equation for the solubility of the salt.
Solubility of AgI decreases when it is dissolved in KI •• Use Le Chatelier's principle to determine the effect of
solution. increasing the [I−].
•• When the [I−] is increased, according to Le Chatelier's
principle, the system will adjust to minimise this change
by favouring the reverse equation. Hence, increasing the
precipitation of AgI. Therefore, the solubility of AgI decreases.
Ksp = 8.52 × 10−17 = s2
s = 8.52 × 10 −17 = 9.23 ×10 −9
Solubility of Ag+ in water is 9.23 × 10−9 mol L−1.
[I–] = [KI] since KI completely dissociates and there is a 1:1 •• Calculate the solubility of Ag+ in 0.250 mol L−1 KI.
ratio between KI and I–.
[Ag ] = s due to the dissociation of AgI
[I–] = (0.250 + s) due to the dissociation of KI and the
dissociation of AgI
Since s << 0.250
Therefore, (0.250 + s) ≈ 0.250
Substituting into the equilibrium expression:
Ksp = 8.52 × 10−17 = s × 0.250
8.52 × 10 −17
s = = 3.41 × 10 −16
Solubility of Ag+ in 0.250 mol L−1 KI is 3.41 × 10−16 mol L−1.
Solubility of Ag+ in water is 9.23 × 10−9 mol L−1. •• Compare the values for the solubility of Ag+ in water and
0.250 mol L−1 KI.
While the solubility of Ag+ in 0.250 mol L−1 KI is
3.41 × 10−16 mol L−1:
9.23 ×10 −9
= 27 ×10 6
3.41 × 10 −16
Hence, solubility of AgI is about 27 million times less in
0.250 mol L−1 KI compared to its solubility in water.
1 Quantitatively compare the solubility of magnesium carbonate in 0.550 mol L−1 Na2CO3 with its
solubility in 0.375 mol L−1 Na2CO3. Ksp for MgCO3 is 6.82 × 10−12 at 25°C.
2 Qualitatively and quantitatively compare the solubility of Cu(OH)2 in water and 0.075 mol L−1 NaOH.
Ksp for Cu(OH)2 is 2.2 × 10−20 at 25°C.
ASSESSMENT Concentrated HCl is highly corrosive. Use in a fume cupboard or open windows and turn on fans
to create a well‐ventilated space.
Teacher to use a dropper to dispense HCl. Wear safety
glasses and wash hands immediately after use.
10 mol L−1 NaOH is very corrosive. Wear safety glasses to protect eyes from splashes.
Teacher to use a dropper to dispense NaOH. Wash hands
immediately after use.
What other risks are associated with your investigation? How can you manage these?
Record your observations in a carefully planned table.
To determine the Ksp for PbI2.
Lead salts are highly toxic. Use a burette to dispense lead salts. Wear safety glasses and ASSESSMENT
wash hands immediately after use.
Dispose of solutions in the heavy metal waste bottle provided.
What other risks are associated with your investigation? How can you manage these?
1 Use the following equation to determine the concentration of each of the ions in the mixture:
Volume (mL) of ion added to solution
[ion]mixture = [ion]stock solution × Total volume (mL) of solution
2 Use these values to determine the Qsp for each mixture (1–9).
3 Identify the smallest value for Qsp that has a precipitate present.
4 Identify the largest value for Qsp that does not have a precipitate present.
5 Determine the range for the Ksp for PbI2 – it lies between the values found in 3 and 4.
1 Compare your value for the Ksp for PbI2 and compare it to the value on the NESA data sheet.
2 Discuss reasons for any difference in the Ksp for PbI2 between the value obtained in this investigation with
the value provided on the NESA data sheet.
●● The common ion effect is when a common ion is added to a saturated solution that decreases
the solubility of the salt.
UNDERSTANDING 1 Define the 'common ion effect'.
2 Calculate the solubility of lead(II) bromide in 0.10 mol L−1 lead(II) nitrate at 25°C, given that the Ksp for lead(II)
4.8 bromide is 6.60 × 10−6.
3 Use Le Chatelier's principle to justify whether the solubility of nickel(II) carbonate is greater in 0.1 mol L−1
nickel(II) nitrate or in water.
4 Quantitatively compare the solubility of magnesium hydroxide in water with its solubility in 0.20 mol L−1
Critical and sodium hydroxide. The Ksp for magnesium hydroxide is 5.61 × 10−12 at 25°C.
creative thinking
5 By what factor is the solubility of calcium phosphate decreased when it is placed in 0.30 mol L−1 sodium
phosphate compared to its solubility in 0.15 mol L−1 sodium phosphate? The Ksp for calcium phosphate at
25°C is 2.07 × 10−29.
Review quiz
1 Define the following terms. 9 The solubility of silver sulfate is 14.1 gL−1 at 100°C and
a Saturated solution 5.7 gL−1 at 10°C.
b Toxin a Use Le Chatelier's principle to determine whether the
heat of solution for silver sulfate would be endothermic
c Molar solubility
or exothermic.
d Sparingly soluble
b Write the expression for the solubility product for silver
2 Distinguish between ionic product and solubility product. sulfate.
3 The solubility of ionic salts increases linearly as the c Calculate the molar solubility for silver sulfate at 100°C.
temperature increases. Evaluate this statement with d Calculate the solubility product for silver sulfate at
reference to Figure 4.8 (page 87). 100°C.
4 Explain the process of leaching. 10 The solubility of manganese carbonate is 0.0065 g/100 g
H2O at 25°C. Calculate the Ksp for manganese carbonate.
5 Assess the usefulness of leaching for Australia's first
peoples. 11 The yellow solid, silver chromate (Ag2CrO4), dissolves
in water to produce a saturated solution that contains
6 Determine whether a precipitate is formed when the
0.0025 gL−1 silver chromate.
following solutions are mixed. Write a net ionic equation
for any precipitate that forms. a Calculate the molar solubility of silver chromate.
a Sodium chloride and lead nitrate b Calculate the Ksp for silver chromate.
b Magnesium sulfate and zinc chloride c Calculate the molar solubility of silver chromate when
0.0025 gL−1 is dissolved in 0.10 mol L−1 silver nitrate.
c Barium hydroxide and sodium sulfate
d Justify the difference in the value for the molar
d Aluminium chloride and ammonium sulf ite
solubility of silver chromate in parts a and c.
e Copper(II) bromide and sodium carbonate
7 When a potassium hydroxide solution was mixed with
a magnesium nitrate solution, a magnesium hydroxide
precipitate formed.
a Write a net ionic equation for this chemical reaction.
b Write the expression for the solubility product for
magnesium hydroxide.
In a particular investigation, the concentration of
magnesium ions at equilibrium is 0.00100 mol L−1
and the concentration of hydroxide ions is
3.74 × 10−5 mol L−1.
c Calculate the solubility product of magnesium
d Calculate the molar solubility of magnesium hydroxide.
8 Justify whether a saturated solution of iron(II) hydroxide or
iron(III) hydroxide has a greater concentration of iron ions
present at 25°C.
Ksp for iron(II) hydroxide = 4.87 × 10−17
Ksp for iron(III) hydroxide = 2.79 × 10−39
1 Nitric oxide reacts with oxygen to 4 The production of sulfuric acid involves a number of steps,
form nitrogen dioxide: one of which is the gaseous equilibrium reaction between
2NO(g) + O2(g) ⇌ 2NO2(g) sulfur dioxide and oxygen to form sulfur trioxide.
The following table gives the
Literacy A scaled-down version of the reaction was performed in a
equilibrium constant for this reaction 3 L container. Initially, 0.18 mol of sulfur dioxide was added
at different temperatures.
Critical and to 0.15 mol of oxygen. After equilibrium was reached, the
creative thinking
concentration of sulfur trioxide was 0.12 mol.
TEMPERATURE (°C) EQUILIBRIUM CONSTANT Calculate the equilibrium constant for the reaction.
477 112 5 Ammonia is produced from nitrogen and hydrogen in the
727 1.60 Haber process:
N2(g) + 3H2(g) ⇌ 2NH3(g)
1227 2.4 × 10−2
The graph below shows the variations in the
1727 6.4 × 10−4 concentrations of each species over time.
At time C, the temperature was increased.
a Write the equilibrium expression for this reaction.
b Justify whether the formation of nitrogen dioxide is
endothermic or exothermic.
Concentration (mol L–1)
Pressure increases
▻▻ Create a model to demonstrate steady state, dynamic equilibrium and static equilibrium.
▻▻ Research how Australia's first peoples removed toxins from foods other than cycads.


text:
The owner of a Belfast-based brewery has come up with a plan to help the victims of Monday's Boston Marathon bombing.
David Carlson, owner of Marshall Wharf Brewing Co. in Belfast, developed the idea for Buy Boston a Beer and pitched it successfully to other brewery and tavern owners.
About 20 breweries from across Maine and New England have agreed to donate beer to a fundraiser that will be held Wednesday at The Tavern Framingham in downtown Framingham, Mass.
"David got the ball rolling and we offered the spot. It snowballed from there," said Sam Hendler, the owner of Jack's Abby Brewing in Framingham, Mass.
Hendler, who is organizing the fundraiser, said Oxbow Brewing in Newcastle, Shipyard Brewing in Portland, Allagash Brewing in Portland, Maine Beer Co. in Freeport, Atlantic Brewing in Bar Harbor and Marshall Wharf Brewing are the Maine companies that have agreed to donate beer.
Hendler said all the proceeds from the event, which starts at 3 p.m, will go toward the One Fund Boston, a fund established by Massachusetts Governor Deval Patrick and Boston Mayor Thomas Menino to help the victims and their families.
More than 20 kegs of beer have been donated, or about 1,000 pints, according to Hendler.
Carlson could not be reached Tuesday.
Send questions/comments to the editors.
Monday's major league roundup: Mariners down Tampa Bay
Nation & World
Ex-Gov. Kathleen Blanco, who led Louisiana through Katrina, dies at 76
Nation & World
Epstein signed will 2 days before jailhouse suicide, records show
Trump again appears to back away from gun background checks
Monday's Sports Digest: Europe experiments with golf pace penalty

subset: commoncrawl


text:
Dalia's Bridal is a dress and attire shop situated in Buffalo, New York. Finding a wedding gown is a big part of your wedding preparation, so this shop gives brides the opportunity to work one on one with a bridal stylist. Your bridal stylist will put your needs first and assist you as you browse through all the designer sample gowns in the shop. Then, when you find your dream dress, you will be able to take it home that same day.
Services Offered
What makes Dalia's Bridal unique is that all of their gowns are designer samples, so they are priced 40 percent to 70 percent lower than retail prices. Not only will brides be receiving a stylish gown, but they will also be able to save a great deal of money. The shop also has attire for the mother of the bride and the mother of the groom. Some of the brands that the shop features include Allure, Lillian West, Rosa Clara, and Stella York. You can finish off your look with the following accessories:
Recommended by 99% of couples
11 User photos
Jaci · Married on 04/14/2018
I highly recommend Dalia's Bridal to any WNY Bride! They have a wonderful selection of designer gowns and Kate helped me to find my perfect dress. The staff were always kind and provided great customer service. I also had my alterations done through them and Karen did a fantastic job! The dress was not in my size and had to be taken in quite a bit and we also added straps and Karen recommended hanging extra in the back which ended up being one of my favorite things about my dress! So glad I went to Dalia's!Sent on 06/07/2018
Dalia's Bridal's reply:
Christine Morales · Getting married on 06/12/2020
Great experience
Dalia made my experience perfect. I went into the appointment nervous that I wouldn't find what I was looking for and she sensed it right away, she assured me it would be okay and went "shopping" for dresses. The very first first dress she had me try was amazing. After trying on a few more, I couldn't help but want to put that first one back on and it was in fact, THE dress! Dalia is great and it's easy to see that this is genuinely her passion .Sent on 04/11/2019
Dalia's Bridal's reply:
Kaitlyn Harris · Getting married on 05/23/2020
Amazing Experience
The best experience I could have asked for. The patients and attention to detail these ladies have is impeccable. They truly listen to what your looking for in the search to find your dream dress. I said yes to my dress and can not wait for my fiancé to see me walking down the aisle wearing the most beautiful designer gown I've ever laid eyes on!!!!Sent on 06/07/2019
By clicking "Request pricing" I agree to sign up and accept WeddingWire's Terms of Use.Write a review


text:
This guide will tell you how to create that ideal experience for your
app users.
Your app represents the fastest, easiest, and most accessible way
for your brand followers to interact with you and, most importantly,
complete a task or engage with a service. Users are looking for an
app that meets their expectations, and today, those expectations
center on a streamlined and efficient experience.
That's why bugs, outages and network latency issues are more
than just a nuisance -- they can cause permanent brand damage,
and lose you money. A new (or even returning) user who encoun-
ters a bottleneck might never return, so ensuring that your initial
app experience is error-free is critical.
Launch A Mini-Orientation
For New Users
When someone downloads a new or updated app, identifying the
key features and how to best use it can be confusing. A warm wel-
come can make the entire experience more enjoyable and less
frustrating for the user.
In many cases, the app features you think are most valuable go
undiscovered because new users spend little time initially explor-
ing your app - if it's not apparent up front, why go searching for it?
While your app may be easy to navigate and self-explanatory to
you, not all users will give it the time necessary to figure it out on
their own.
Take this example from the Yahoo! app: they created a short, three-
screen orientation for new users that highlights the whats, whens
and whys of the app. Not only does this act as an explanatory intro
for new users, it also highlights the value of the app, and why they
should use it. Plus, for those do-it-yourself users uninterested in a
walk-through, the first screen offers a "skip" option. A simple, mini-
mal-screen approach to new user orientation can go a long way in
ensuring key features are discovered, and shows that your priority
streamlining and simplifying the user's experience.
But what about new app users who haven't created an account?
Or if you're a mobile-first startup that has an app but no web pres-
ence? Many times, people on-the-go download the apps of brands
that they find interesting to do a "test drive." In these situations,
you want to make it exceedingly simple for new users to register
for an account and experience the best of what your app has to
offer (plus, it allows you to save their data for additional insights
down the road).
When new users open your app, ask them whether they are an
existing customer or a casual explorer. Then, guide the casual
explorer through the cool features of your subscription and show-
case how your app can make their life easier. You want to provide
a tempting sneak peak and turn one-shot users into members of
your club. You get new subscribers and your mobile app serves
the dual function of helping current members while also marketing
your business to prospects.
Zipcar, for example, does this exceedingly well. Their app is de-
pendent on registration with the service. They proved a path for
non-users that provides a list of reasons to become a "Zipster,"
and also a step-by-step guide to what sign-up and car reserva-
tions look like. Additionally, Zipcar built an app-specific feature for
non-users, so there is at least something they can do upon open-
ing an app.
The flip side of this is to make sure that the sign-up process is
clear but not intrusive. If there are aspects of your app that can
be utilized without creating an account, it's important not to block
those with repeat prompts to register. The key is to make registra-
tion a breeze, and to highlight the benefits, not to push every user
to create an account repeatedly.
Allow Users To Opt-In For
(Or Out of) Notifications
App messaging has become an increasingly important tactic in en-
gaging app users, to the point where 68% of people have enabled
push notifications and 70% of consumers find all types of push
notifications valuable. But while app users are ready and willing to
engage with push messages, they want to do it on their terms.
Beyond that, it ensures that your users are receiving the messages
that they want to receive. Your app users are not a giant homoge-
nous group of people, and so not all push messages will be rele-
vant to everybody. Allowing for opt-ins ensures that your pro-push
audience is more likely to engage with the messaging and convert.
week to stay on track with their goals, and notifications of when
they are about to be charged. Because these notifications are spe-
cific to the end user and integral to their individual app experience,
they are more likely to opt-in for notifications, and see the value.
Not only do segments enhance your analytics and help you bet-
ter understand your app users, they are also the foundation for
running great app marketing, particularly through push and in-app
messaging. You can (and should) target your marketing campaigns
to specific user segments, using offers customized to that segment
to boost a particular event or conversion.
How does this further engage users in under ten seconds? Be-
cause when you know which users you're targeting for messaging
campaigns, and choose your content accordingly, the chances
that they will immediately engage with those campaigns is higher.
When an offer or message is relevant to them, they will want to act
on it sooner, rather than later.
Say your user segment is "Second Screeners." These are people
who are engaging with an app for a TV show or broadcast network
while the actual show is going on. They're watching their favorite
show and they have their tablet or phone in front of them, discuss-
ing the show, or voting on who to kick out, or maybe just looking
up trivia about the show or actors.
You can determine this group by the time that they're interacting
with the app or, in the case of network apps, the time that they're
interacting with a particular piece of content. Once you've deter-
mined these users, you can send them push notifications to let
them know their favorite show is starting, or use in-app messages
to invite them to watch the next show based on their entertainment
Targeted promotions
sent to a segment of
users that fall under
specific criteria
Fifty percent of people say the #1 reason they download apps are
to receive discounts and special offers. If you have a segment of
users who don't use the app regularly, it could be a sign that they
aren't engaging because they're missing the mobile-only exclu-
sivity. Re-engaging them quickly can be as simple as creating a
rewards-based program, or even implementing a one-time, mo-
bile-only offer.
Here's where app marketing again comes into play. You can use a
push messaging campaign to bring lost users back into your app
with specific discounts or membership perks. Or, the next time a
fairly inactive user opens your app, re-engage them immediately
with an offer just for mobile users. You can also create a purchas-
ing program or points system that users can engage with regularly
to receive great offers.
There are other ways to make it all about the mobile reward. You
can go above and beyond and take a page out of Old Navy's book,
and what they did in building their SnapAppy app. When Old Navy
customers download the app and sign up as users, they have the
ability to play a game in which whenever they snap a picture of an
Old Navy logo they win a chance for a mobile-specific discount or
offer. A wheel pops up in the app and spins to choose your new
offer. While not all brands are going to want to invest the resources
to build this kind of app, it is a good model to study in researching
and creating your own mobile-only offer or rewards program.
Social sharing isn't just for news and media apps. Whether it's "lik-
ing" an app on Facebook or tweeting your tracked run time, social
and email sharing the going-ons in your app experience have be-
come commonplace. Often, it can be a natural extension of your
app, going beyond the norm and making it a part of the overall app
For lifestyle apps, social sharing enables your users to make public
to friends personal "wins," such as their progress against workout
goals, travel plans, or even weight loss over time. This serves as a
way to keep on track, and even offers public endorsement, feed-
back and positivity.
By enabling cross-platform sharing, most notably the ability to
share with friends various activities or content your user enjoys,
your app becomes a more integral piece of their lives. When shar-
ing is made easy, this value is conveyed sooner, improving en-
gagement long-term and prompts immediate usage. Essentially,
when social promotion is available and easy to do, your app users
can more readily share what's important to them, engaging them
with the app immediately and creating a more cohesive experi-
Again, in this scenario it's important to keep in mind that while so-
cial sharing should be readily available, it should never interfere
with the app experience. Make sure your efforts aren't intrusive,
but easily accessible for those who want it.
RunKeeper, one of the most popular fitness apps that tracks your
runs and workouts, has taken their social element and brought
it in-app. Not only does the RunKeeper app provide the ability to
share your run stats across channels, in its latest version it also
built an in-app social stream, where you can post to and track your
friend's activities and photos. For them, the social sharing aspect
is actually an important component to the app experience. They're
betting that users' ability to view their friends' activities will be a
sticking point, and will engage them instantly and often.
Social aspect isn't
obtrusive and
even serves as a
motivating factor for
users to workout
Using a competitive
aspect amongst
friends to keep users
With events, you can see how your app users progress through a
funnel (such as added a product to cart through completed check-
out), and you can also trigger in-app messages upon event com-
pletion to encourage further in-app activity, or provide additional
information. This form of marketing automation takes little time
and effort to set up, and is a way to quickly re-engage users after
they've completed an action, and are considering exiting your app.
In just a few seconds, you can re-gain their attention and direct it
toward a customized message, all without doing any manual work.
adds two tickets to next week's Red Sox game to his cart, you can
enable a triggered in-app message alerting him to the Red Sox v.
Angels game that's happening in two weeks. Not only is this infor-
mation personalized to his interests, it is also relevant to the in-app
action he just took, and thus has a higher chance of converting him
Use Deep Linking With
Push & In-App Messages
Deep linking is something that most brands employ today, regard-
less of whether or not they call it deep linking. It is the practice of
embedding links to pages deep within your website around the
internet – in email signatures, article syndications, social publish-
ing sites, forums, etc. With deep linking, instead of linking directly
to your homepage, you want to highlight the pages that work best
in that context.
Using deep linking, you can direct your user through a mobile ad,
push notification or in-app message to a corresponding screen
within your app.
Let's go back to the sports app example. Say you've sent that
great push message out to Red Sox fans through a personalized,
highly-targeted campaign. Your deep linking here shouldn't direct
the user to your app home screen; it should take him or her direct-
ly to the results screen.
Why is this important? It saves the user time searching for the rele-
vant screen, engaging them immediately with the subject matter at
hand and negating navigation confusion. Making their in-app path
clearer and easier to flow through not only meets difficult user ex-
pectations, but improves the quality and conversion opportunity of
your app marketing campaigns.
Garner User Feedback
Great apps are bi-directional, and rely on user data and feedback
to create a continually better experience. Running customer rela-
tionship surveys is a simple way to gather this information. In the
broadest sense, a customer relationship survey seeks to under-
stand how satisfied customers are with your business. One of the
most widely used survey types is the Net Promoter Score (NPS)
survey, which empowers you to identify users who would be will-
ing to recommend your app to a friend.
Not only does this help you determine where your app needs to
improve (and which features are user favorites), but a survey also
lets your users know that their input is essential to the success of
your app. Much like with allowing for opt-ins, prompting survey
participation makes users feel valued as an integral part of grow-
ing your app.
Promoters can be
further nutured
to rate app in app
store (detractors can Warm messaging
provide feedback)
Easy-to-answer, one
question survey
Evolving To Win In An
App-Driven World
When it comes to the promise of mobile and web apps, we've only
scratched the surface of what they can do to attract, excite and
retain app users. What we do know is that by 2017 there will be 4.4
billion app users worldwide, and they are making it clear what they
want in an app experience. By implementing these ten tactics, you
can improve your app to meet (and even exceed) their expecta-
tions, garnering loyalty and just generating brand loveability.
Want to learn more?
App Analytics and Marketing Software


text:
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This sweet potato is stuffed with beef and blueberries, a combination that you may not have ever seen before. They all combine to form a very well-balanced Paleo meal, and you're getting tons of antioxidants both from the blueberries and the sweet potatoes. The beef gives you protein, while sweet potatoes are a carbohydrate that is digested slowly by the body. There is just as much sweet potatoes as there is beef, with just a bit of blueberries added for good measure. This makes for a microcosm of what it's like to eat a perfectly portioned Paleo meal.
These wings will really hit the spot if you've been craving chicken wings, and are too far from your next meal to hold out. The pecan flavor comes from the smoking process, not from actual pecans. That way you'll get a hint of pecan in every bite, without having to worry about crunchy pieces stuck to the chicken. The cool thing about this recipe is that it makes everything from scratch, so you don't have to resort to getting things out of a bottle. Our suggestion is to make a big batch and store the rest since this isn't exactly fast food. https://www.youtube.com/watch?v=qtCwglD0XdQ
Stuffed burgers are all the rage, and you can get into the craze with the Paleo diet, you just have to stuff the burger with Paleo friendly foods. In this recipe they've used an avocado as the stuffing, which gives these burgers potassium and healthy fat they wouldn't otherwise have. They are grass-fed ground beef for the burger meat, which you'll want to get into the habit of buying since it is closer to the natural way cows would eat. They've also managed to sneak in some sun-dried tomatoes, so you'll be getting additional nutrition from those.
These sweet and sour gummy candies are actually good for you. Pretty weird huh? They are really easy and actually a lot of fun to make. All you do is mix the ingredients, put them into a mold either by pouring or using a plastic bag with a small hole in the corner. Then either put them in the refrigerator or freezer to set depending on how big of a hurry you're in. You could make them any shape or color you'd like. I'm thinking about making some for my Halloween party using these molds. Wilton Pumpkin Patch Silicone Mold, here is a Wilton Heart Mold. I suggest just searching around on Amazon for Wilton silicone mold and then the shape or holiday you'd like it for. I'm sure you can find just what you're looking for.
Hi, Susan! I linked to Thrive Market under the Siete amazon link. That's the only other online place I get them or I purchase them from Whole Foods! They're cheaper on Thrive Market than they are at Whole Foods unless you can find them on sale at the store. You can also purchase them through the siete website directly, however I'm unsure what the price and shipping is! They're so good though! If you haven't tried the tortillas yet, I'd recommend getting the almond flour ones first. They've seemed to hold up better (more sturdy) than the coconut ones if you have wet/heavy ingredients in your taco 🙂
This is one tasty burger, and they chose wisely when they topped it with guacamole. The guac not only adds in a massive amount of flavor, but it also adds healthy fat, potassium, and fiber to the mix. Speaking of fiber, you'll get even more from the buns. That's because they're made from sweet potato noodles which are made using a spiralizer and fresh sweet potatoes. Who ever heard of a burger bun that provides this level of antioxidants? https://www.youtube.com/watch?v=OzXJvzIe6bw
Calamari is definitely something our ancestors would have eaten if they lived near a shore. Knowing how to catch fish and other sea creatures is what helped us beat out the Neanderthals, so we've known a thing or two about seafood for a long time now. This recipe walks you through the steps needed to take calamari and turn it into a delicious salad that works as a starter to a meal, or as a light meal all by itself. If you're not used to eating things like squid you may have to broaden your palate and try new foods. It's what Paleo is all about. https://www.youtube.com/watch?v=srmxhx3sVhI
As discussed in my article questioning nut consumption on a Paleo diet, macadamia nuts are probably the healthiest nuts available because of their high monounsaturated and low polyunsaturated fat content as well as their low levels of anti-nutrients. They can thus be enjoyed without guilt. This hummus recipe is great with anything where you would normally use regular hummus or Baba Ghanoush.
I only used one banana, one egg, and scraped the bottom of my natural almond butter, a dash of cinnamon, and they were great. I would make the full size if I was feeding my husband too but I just wanted to say that if you want to make just enough for yourself it still works great. I maybe had about 3-4 tbsps of almond butter but I'm not sure. I would definitely make these again, they taste just like banana nut bread to me. Yum! https://www.youtube.com/watch?v=IcDZiQVWEPw
These are delicious! I didn't have any coconut flour so I used 1/4 of all plant protein powder and they turned out great. I did separate the egg whites and beat them separately. I couldn't believe how light and fluffy they were, although they were pretty delicate and wanted to fall apart. Next time I think I would add in some starch or binder to hold them together a bit more. https://www.youtube.com/watch?v=WT3-ea4BwiE
This sweet potato is stuffed with beef and blueberries, a combination that you may not have ever seen before. They all combine to form a very well-balanced Paleo meal, and you're getting tons of antioxidants both from the blueberries and the sweet potatoes. The beef gives you protein, while sweet potatoes are a carbohydrate that is digested slowly by the body. There is just as much sweet potatoes as there is beef, with just a bit of blueberries added for good measure. This makes for a microcosm of what it's like to eat a perfectly portioned Paleo meal.
I had to follow your link to the crepe pan out of curiosity! Do you know if it works well for making roti? We have a legit Indian roti pan and I've been asked several times over the years by friends and family where to find a "roti pan" or if they can just use their cast iron skillet? This seems like it's pretty close in comparison and sells for a reasonable price! https://www.youtube.com/watch?v=vyxPH6jPnlw
Kale chips make a great snack because they don't contain anything that's unhealthy for you. In this recipe she's simply using curly kale and olive oil, so you are getting all of the benefits of kale, without any hydrogenated oils or industrial grade salt. You won't believe how crispy and crunchy kale gets when you bake it until you try it. And since it is loaded with fiber, and has respectable amounts of potassium, with Vitamin A and Vitamin C levels that are off the charts, this is one of the healthiest snacks around. It's also low in calories and fat, and the olive oil only adds healthy fat to the equation. https://www.youtube.com/watch?v=0U1qQM2vV_E
These are the best gluten free pancakes I've ever had… and maybe the best pancakes ever, period! They are so good! I added an overripe banana and decreased the coconut milk a tad to keep the consistency right. I topped them with whipped coconut cream and fresh strawberries. OMG. I want to eat them every day from now on. THANK YOU! I wish there was a way to post a picture, because they actually turned out beautifully browned and round, too, which is hard to come by in most grain free pancakes in my experience! https://www.youtube.com/watch?v=FsNAQwZfagA
FYI Scott Madden the Paleo diet is really just a general blueprint and most people just do the best that they can–some also just eat according to what they can handle or need and still consider it "paleo." There are also many different options when it comes to protein powder (many people use pea, hemp etc) and not all of them contain wheat, soy, casein or whey. https://www.youtube.com/watch?v=AtEubaJ30n0
Kale chips are one of the healthiest snacks on the planet, and you don't have to be a gourmet chef in order to get them right. The beauty of eating kale chips is that there's no debate over whether they are Paleo or not. The ingredients are as simple as it gets: as much kale as you want with enough olive oil to coat them, and then some salt and pepper until you're happy with the way they taste. Making them is super easy, and doesn't take long from start to finish, maybe 20 minutes total. Eat these for a protein and fiber packed snack with lots of vitamins and minerals.
Isn't it awesome just how many foods you can have with Paleo. There's virtually nothing that's off limits as long as you're using the right ingredients. In this version of the classic chocolate cream pie, the regular crust has been replaced with an almond-based crust so you'll get more fiber and protein from the crust that you would with any flour-based crust. The chocolate is from cacao paste and isn't filled with dairy or refined sugar. A perfectly chocolatey and healthy pie!
So about the recipe… You have to buy the Paleo wraps online or if you're from my area (Mandeville, Louisiana), my friend at Vive sells them. I'm not always a huge fan of buying Paleo products, but 1) these are only made of coconut, so they're super healthy and 2) these are SO good and will give you so many new options for lunch. After you buy the wraps, make the chicken salad and use a Paleo mayo recipe. Do not get lazy about the Paleo mayo and buy store-bought; the Paleo mayo is much better. Mayo can be tough if you don't follow directions. Happy lunch-making! Share with me in the comments your opinion on this recipe.
If you love the taste of curry but don't know how to make it, this soup can serve as a reliable way to get that flavor without having to memorize a difficult recipe or use curry from a jar. There are plenty of ingredients being used here, but you'll see in the directions that it's just a matter of combining them all together, so it's not complicated. You end up with an amazing curry soup that has interesting things like almonds in it to give it a crunch you don't usually get with curry. They're also giving it healthy fat and additional protein which is very helpful.
Skillet Sausages with Pan Seared Apples Slow-Cooked Hawaiian-Style Kalua Pork Grilled Cuban-Style Citrus Pork Jamaican Jerk Pork With Mango Salsa Curried Pork Chops With Honeydew And Cucumber Vietnamese Pork Spring Rolls Pressure Cooker Ribs With Creamy Coleslaw Bacon-Wrapped Pork Medallions Hawaiian-Style Burgers Pulled Pork Salad Pork Chops With Balsamic Glaze Simple Sausage Casserole Bacon-Wrapped Sausage With Apples Pulled Pork Stuffed Sweet Potatoes Spicy Spare Ribs Apple-Cinnamon Pork Loin Grilled Pork With Basil Rub Cuban Style Pork Chops Pork Chops With Lemon-Cilantro Vinaigrette Cranberry Apple Stuffed Pork Loin Chicken and Pork Stuffed Squash Pork Chops With Peaches Pork Chops in Sweet Sauce Porchetta Maple-Barbecue Ribs Pork Tenderloin With BBQ Peach Sauce Pork Chops With Garlic Sage Butter Nectarine & Onion Pork Chops
Quiche is usually fair game on the Paleo diet because it's primarily made with eggs, and eggs are definitely a Paleo approved food. This particular quiche recipe includes plenty of delicious ingredients, and she's topped it off with a zucchini hash crust so it's crunchy on the top, and full of eggs and yummy vegetables on the bottom. All of the ingredients that are not Paleo in a traditional quiche have been removed and replaced with Paleo perfect items. Flax meal is used as an optional ingredient, and we'd suggest it since it adds beneficial omega-3s to the mix. https://www.youtube.com/watch?v=U63RJiOS3TE
One strong suggestion… if you're against using a non-stick pan or griddle… I HIGHLY recommend this steel crepe pan. I don't know how I've gone without it in my kitchen. It's one of the best purchases I've made (right up there with my Instant Pot) and the crepe pan is super affordable. Season it really well just once and you've got what's basically non-stick steel. It's way better than a cast iron skillet. Yep. I went there. https://www.youtube.com/watch?v=xcA5iLswWPo
It's easy to get plantains and bananas mixed up. While plantains are part of the banana family and the two look alike, plantains are not sweet, and instead are used mostly as a starchy vegetable. Think of plantain chips as veggie chips. They are often sliced and baked with olive oil and salt, creating a nice crunch. Lots of supermarkets carry different versions of plantain chips, but not all plantain chips are Paleo, so you'll want to check the ingredients before buying.
Although not all of these are strict paleo (some contain coconut sugar and other paleo-friendly sweeteners), they are free from refined sugars, dairy, and grains. Stash them in your desk at work, hide them in your glove compartment, or place them in your purse. That way, you have a paleo-friendly snack always within reach and won't be tempted to go off plan. And while you stock up on these favorite finds, be sure to check out our list of The 14 Best & Worst Weight-Loss Paleo Foods.
When I first developed this recipe for Paleo pancakes, I used a tiny bit of coconut flour rather than tapioca starch/flour for structure. The batter was thicker, especially as it sat out, as coconut flour has that tendency, and it was almost impossible to make smaller pancakes. By replacing the coconut flour with a Paleo-friendly starch, the pancakes still have structure but the batter is more flexible. https://www.youtube.com/watch?v=ogf0TuIpffg
This stew is made from a bunch of beef, some blueberries, carrots, and an onion. It may sound like a bit of an odd mix, but trust us, it works. A stew is the perfect platform to construct a great Paleo meal, and here there's plenty of healthy foods being combined. You'll get plenty of protein from all of that beef, as well as important minerals like iron. Blueberries consistently make the news because of their antioxidant value, and carrots have long been known to be healthy due to the beta Carotene they contain. Onions also add to the nutritional value of this meal, and it will definitely keep you satisfied for several hours. https://www.youtube.com/watch?v=DwVwQiqe4eM
One way to avoid eating potatoes as a snack is to replace a popular snack like potato chips with a healthier version. Using zucchini in place of the potatoes is a great idea, and gives you added nutrition. Zucchini makes a great choice to make into a chip because all it requires is some slicing and you have nice round pieces ready to be made into chips. They are easy to make, and the recipe is versatile in how it lets you dust them with whatever seasonings you like. This means you could make them BBQ Zucchini chips, or Ranch Zucchini chips, just by adding different seasonings. Just be sure to check the label on the seasoning packet to see if it's Paleo.
Unlike many traditional stuffed pepper recipes, these stuffed bell peppers are stuffed with things you might actually eat while watching the big game. Basically it entails mixing up a batch of buffalo chicken salad, complete with chicken, hot sauce, and bleu cheese, and then stuffing them into a pepper. This means you'll be getting a nice balance of vegetables and meat, as well as that classic buffalo flavor with the hot sauce and bleu cheese. Plenty of protein in this snack that eats like a meal if you need it to.
I googled first "healthy super bowl snacks" and got a load of quite unhealthy stuff, actually. So with a sigh, I googled "Paleo super bowl snacks" and found this. SO GLAD You posted this list! I may have to battle the grocery shopping hordes tonight and get the ingredients, but I can pig out guilt-free on Sunday! I think I am going to try the zucchini roll ups, deviled eggs and sweet potato enchiladas! https://www.youtube.com/watch?v=oRafxW1OaUc


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I truly believe that if you want to attain the status of being a millionaire, one must make the necessary adjustments in life. The status of being a millionaire entails a lot of sacrifices but what is more realistic is that it is achievable and doable. More than anything else, be a millionaire for it takes to be one – frugal, investment conscious, earning more than what you spend, paying yourself first, diversifying your investments by not putting all your eggs in one basket alone, intuitive, resourcefull, sound knowledge in financial language and accounts, passionate, loves what you are doing, charitable, innovative, seizing initiatives in the market plays, delaying instant gratification and always never sacrificing the needs of your family in terms of financial needs and matters.
Individuals who cannot get approved for loans through traditional financial institutions and lenders often turn to alternate sources of financing such as peer-to-peer lending. Because these tend to be higher-risk loans, interest rates typically range from 6 to 10 percent. You can use programs like Lending Club to get involved with peer-to-peer lending quickly and easily.
most of these site you have to be older then 18, so thus you couldn't do any of them unless in your parents name, also you would need their credit card or pay pal account, which i don't think any parent would let their kid have that account, best advice i can tell you is to try working in lawn care, good for you wanted to start working young, i know how hard it can be living in a small town with poor parents, mabye ask around for idea, beware of the net though, net jobs are mostly scams and they onces that aren't you mostly have to be 18, mabye if you don't need a permit in your town sell cookies, or your old toys in a yard sale. cleaning jobs, are good. good luck, i know what it like being you, work hard
Holly told me she started writing content in 2011. At the time, she still worked a full-time job but created content online part-time to supplement her income. Over time, she was able to double and triple her rates until she could quit her full-time job to write. These days, she makes bank as a freelance writer and teaches others to do the same via her online course, Earn More Writing.
If you've ever wanted to try real estate investing but don't want to deal with all the stress of being a landlord, you might want to consider investing with Fundrise. Fundrise is a new platform that allows you to invest directly in a real estate portfolio that a team of professionals identifies, acquires, and manages on your behalf. With a starting investment as small as $500, you get exposure to dozens of solid, value-producing assets.
One should think about their skills, hobbies and basic daily habits as well. Do you like to cook? Be a personal cook or dinner parties. Baking? Make wedding cakes or cupcakes for weddings/special events. Do you enjoy cleaning? Trying going to banks/repo companies and ask if they are in need of a repo cleaner or market yourself as a all-around cleaner. Know how to mow a lawn? Get paid to do it in your neighborhood. Sell products from large companies – Jewelry in a candle, Sentsy, Health and home products – etc.
We invite readers to respond with questions or comments. Comments may be held for moderation and will be published according to our comment policy. Comments are the opinions of their authors; they do not represent the views or opinions of Money Under 30. Comments have not been reviewed or approved by any advertiser, nor are they reviewed, approved, or endorsed by our partners. It is not our partner's responsibility to ensure all posts or questions are answered.
Rent out a room in your home to travelers. If you live in a city or a popular vacation spot, there are probably lots of people passing through looking for a place to stay for a night or a couple of weeks. Even if you don't live somewhere with a lot of traffic, you can still use a rental website to find people who are willing to pay to stay in your home.[7]
Getaround is the sharing economy's answer to rental agencies. The company allows you to rent out your car on an hourly or daily basis, starting at $5 an hour. Depending on your vehicle's market value, you set the price per hour, and Getaround takes a 40% cut to cover 24/7 roadside assistance and driver insurance. According to the Getaround, earning potential for renting your car when you're not using it is up to $1,000 a year.
Get-rich-quick schemes and fad weight-loss diets are naturally popular because they satisfy the id while also attending to the super-ego. The ego's job is complete when it sees something like this. The appeal of "fast'' stems from the innate desire for instant gratification, so beware of what seems too good to be true (they often are) when you're looking to make money quickly. Be wary. Listen to the conversation deep within the confines of your mind and do your best to tame the proverbial beasts.
Next, you'll need the right tools. You can be as complicated or simple as you want depending on your comfort with audio equipment, but at the minimum you'll want a microphone and software for recording your voice. Companies like Behringer, Blue, Focusrite, and others sell studio-quality plug-and-play podcast setups that can get you recording today.
Take advantage of the growing delivery trend and sign up for a service like Instacart, UberEats, Postmates or Amazon Flex. You get paid per delivery, in most cases, and can even earn tips. A car isn't always required — Postmates lets you use a bike, scooter or your own two feet to make deliveries — but a background check almost always is part of the deal. Learn more about how to get started with Amazon Flex, UberEats and Instacart.
Another way to utilize your talent and business skills is to run corporate workshops online. Businesses are always looking for unique ways to help educate their workforce, and if you can package your talents into a day or half-day long session, you can sell that to companies all over the world to make money online. Start by building a portfolio and then reaching out on LinkedIn to influencers at relevant companies to see if they would be interested in you teaching their team.
If you love kids, sign up for Care.com or SitterCity to spend a few hours a week babysitting. These websites verify both babysitters and those seeking sitters with background checks, so you can ensure you're conversing with a reliable source. Babysitting rates vary based on years of experience, number of children, and hours per week. According to ZipRecruiter, the average hourly rate for a babysitter is $28. Use Care.com's calculator to plug in your experience and find out how much your should be making an hour as a babysitter.
the problem with "CashCrate" is that the amount of money that u get out of it is VERY slim.. and even to get that VERY slim portion of money you have to complete a lot of surveys and to cash-in on the money you earned u must make over $20, trust me. i tried it, it took me over 6-12 months to get the cash.. i used the site like if my life depended on it. it was very hard.
I have read many posts and blogs on earning a million dollars or passive income. For some time, I wonder whether striving to be a millionaire for years or decades (as you wrote) it is the thing that people should be guided in life. Maybe it's better to focus in life on what gives us pleasure and transform it into a business. If in life we make money on our passion, instead of attending to disliked job, we will make money, but it will not be our top priority.
Not all millionaires are frugal. However, many of those who are self-made millionaires practice some form of frugality. Even billionaires like Warren Buffett have some frugal habits. Frugality is about look for ways to get the best value for your money. It doesn't always mean getting the cheapest thing; it's more about the best value. It also means that you don't waste your money on things that you don't need or want. Practicing frugality can help you keep more of your money for the future.
Bankrate.com is an independent, advertising-supported publisher and comparison service. Bankrate is compensated in exchange for featured placement of sponsored products and services, or your clicking on links posted on this website. This compensation may impact how, where and in what order products appear. Bankrate.com does not include all companies or all available products.
I'd love for you to come visit my site and maybe share some of your thoughts. I love exploring the mindset structure behind manifesting millions and always invite others to do it with me. My goal is to help inspire people to breakthrough to brilliant living – whatever that is to them by defining, refining, and acting on designing the ideal lifestyle.
However, it isn't just about the digital nomad lifestyle that gets people so excited. More so than getting rich by any measure, the masses are merely attempting to wrap their minds around generating a respectable amount of cash, enough to satisfy their expenses and leave a little bit of disposable income at the end of the day. While many look to fulfill that desire, very few, in fact, are able to follow through.
27. Sponsored/paid posts – Many blogs publish sponsored and paid posts. Sponsored posts are basically just posts about a specific brand, product or service. A company will pay you to publish an article about it. It's similar with other paid posts as well. Your basically selling the spot for the article on your site. If you decide to take this route, you'll want to build your traffic before you will get many offers.
Try flipping houses if you have experience with making home repairs. As you may know from watching popular home improvement shows, flipping homes involves buying up a lower valued property that needs work, and then fixing it up for resell. To get started, you'll need to have financing either through a bank a partner. Then, you can buy a property that's priced below market value. After you renovate the property, you may be able to sell it for a profit.[10]
Get-rich-quick schemes and fad weight-loss diets are naturally popular because they satisfy the id while also attending to the super-ego. The ego's job is complete when it sees something like this. The appeal of "fast'' stems from the innate desire for instant gratification, so beware of what seems too good to be true (they often are) when you're looking to make money quickly. Be wary. Listen to the conversation deep within the confines of your mind and do your best to tame the proverbial beasts.
Get-rich-quick schemes and fad weight-loss diets are naturally popular because they satisfy the id while also attending to the super-ego. The ego's job is complete when it sees something like this. The appeal of "fast'' stems from the innate desire for instant gratification, so beware of what seems too good to be true (they often are) when you're looking to make money quickly. Be wary. Listen to the conversation deep within the confines of your mind and do your best to tame the proverbial beasts.
If you don't live in a bottle deposit state, you can still cash in on recyclables by selling scrap metal. You may not have enough soda or beer cans lying around to make this worthwhile — and steel prices are so low right now, it's not really worth the bother to go collecting them. But if you do have a lot of aluminum cans on hand, or if you have any scrap metal with copper in it, find a local recycling center and see what you'll get (prices vary wildly by market). Still, unless you have a lot of copper pipes lying around the garage, or bags and bags and bags of old soda cans, realistically, we're probably talking about getting $5 to $20 back.
If you're trained in a marketable skill — like graphic or web design, SEO writing, or video animation — to the point where you can bang out the work in your sleep, you can make a pretty quick buck with it on Fiverr. Whether it's the best long-term strategy for your freelance career is debatable – and it's one of the least lucrative gig economy side hustles out there – but that's not the point; the point is that there's the potential for earning money quickly.
Now you've got many different options to start earning online. If you saw something that really interests you, try it out and learn more about it. If you're really wanting to make a full-time income online, you need to be dedicated to learning how to do what you want to do. There are tons of free resources out there. You just have to search for them!
If you want to become rich by your 30s, you should be looking at wealth-building opportunities that pay off quicker than traditional long-term investments. One of the best ways to do this is to get into the entrepreneurial game and own your own business. Once you own a business, you have unlimited potential to earn, although you also assume more risk.
Become a freelance writer or editor. If you have a passion for storytelling or a background in writing or editing, it's possible to find freelance writing or editing work online. To search available job openings, check out sites like UpWork.com and Problogger.net. You can also check traditional job sites such as Indeed.com and enter "telecommute" or "anywhere" in the location field.
Using the money you already have to make more money is usually a pretty smart move. A service like Lending Club is a great way to act as a lender and earn interest on your money. Essentially, you act as the bank, which is pretty neat. Lending Club is the world's largest online credit marketplace connecting borrowers and investors. Definitely something worth looking into!
For non-tech people (myself included), web design can cause a lot of stress. And stress means opportunity. If you have a knack for web design or web development, you should definitely be capitalizing on it. And since it's such a foreign concept for many, it can be a really lucrative side hustle. You can find all sorts of gigs on Upwork. Also, you need to read this article: How to Make $5,000+ a Month Building Websites Part-Time
This can either be done locally or through an online service like Fiverr. Resumes are something that people can be very insecure and self-conscious about, which means there is always a demand for services that will help spruce them up. Holly Hanna from The Work at Home Woman wrote a really useful article on How to Make Money from Home with Resume Writing.
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Market your course: The beauty of using a course to make money online is that you can continue to sell it for as long as you'd like. Look for niche communities on Facebook, LinkedIn, or Reddit that might benefit from your content. Guest post on relevant blogs and sites. Look for anywhere you might be able to get in front of the right people. With just a few hours a month you can continue to generate sales.
Thank you for sharing this post again from 2017. When I saw the article, Oh, it's been written in 2017 but when I read along, it is still applicable up to now. I noticed that you are not eliminating the dates on your post. Some bloggers recommend to use a plugin to delete the dates so Google don't have to read the post as outdated anymore. I saw that you are not doing that — or you are updating your old articles one by one before sharing it again?
Hunt for under-priced used books that you can sell online. Download an app that reads ISBN numbers so you can scan the barcodes on books. This will pull up the book's current price on Amazon so you can see if it's worth trying to resell it. Then, visit used book stores, thrift stores, and garage sales to look for high value books. Post the books for sale online using sites like Amazon or Ebay.[9]


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Copier Rental Delano MN
We have been in the copier & printer sales & service business for over 2 decades, we earned the reputation that most or all companies that need to rent reliable equipment come to trust, we offer nationwide equipment rentals, short term and long term – Copiers & printers with 24/7 support, including IT support.
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Why Renting Office Equipment Can Be Better Than BuyingOffice life has actually altered considerably considering that the 1980s. The last 30 years have seen impressive breakthroughs in innovation and social perspectives, which have actually considerably transformed everyday life in the workplace.Without a question it is the innovation of the PC that has actually had the a lot of effect on office life. Jobs that would certainly have taken 1980s team hrs to finish can now be automated and performed in seconds. What's even more, email and the web have actually conserved firms time and also loan whilst also allowing a lot of them to carry out business throughout the world.But it isn't simply modern technology that has actually developed; mindsets in the direction of women in the workplace have actually additionally transformed dramatically over the last thirty years. While it was not unusual for a 1980s female to be satisfied in her function as an assistant, her modern-day counterpart can appreciate much better work leads, a greater wage and also more respect.In reality, the general therapy of all office workers has enhanced considerably many thanks to modern-day health and wellness laws that safeguard us from prospective mishaps in the work environment. Not just do these new laws have workers' best rate of interests at heart, they likewise save firms numerous extra pounds in damages each year.An office materials order in the 80's would certainly have consisted mainly of pens, pencils, paper etc. Now they consist of things such as printer ink and printer toner, laptop computer risers and also memory sticks.In the heat of summer, 1980s employees would also have needed to endure uncomfortably high office temperature levels. In today's modern-day workplaces, nevertheless, workers can change the temperature level and appreciate the cooling impact of air-conditioning. In the 80s, it would likewise have actually been common to spend the work day breathing in the used smoke of your coworkers, as anti-smoking regulations were non-existent. Today, employees need to make their method to marked smoking cigarettes locations outside if they want to smoke.So a lot has actually altered over the last thirty years. As modern technology as well as society have advanced, so have our work environments. From keeping great in the summer season to obtaining an immediate reply from an email and even being able to operate in a clean as well as secure environment - today's offices are a far more positive and also efficient location to work.
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The Differences Between Offices Today and Offices in the 80's - Short Term Copier rentalsA question that business proprietors often ask themselves when it concerns workplace equipment is "should I lease or acquire?" It is a quandary that is conveniently responded to, if one requires time to think of the benefits of leasing over purchasing. Obviously, there are lots of factors to consider to consider when making the choice in between leasing and also purchasing, however increasingly businesses are taking the former choice for all the advantages it offers.Here are the advantages of leasing office equipment instead than buying it: Technical developments are being made with enhancing speed these days. What was a legitimate approach of procedure the other day is most likely to be obsolete tomorrow. Leasing gives the flexibility to update outmoded equipment when needed, meaning a workplace take advantage of one of the most modern and also innovative work processes offered. This boosts productivity.Purchasing a depreciating possession lock up funding. Even if acquiring tools with the aid of a bank finance, it's often the instance that the bank will loan just 50% to 70% of the total amount needed. Free capital can be made use of to buy business and also boost earnings. Resources that is locked away in office devices will certainly not be available to do this. Tools leasing does not experience this in advance price, and also can often be given on a 100% basis.Financing payments can be structured in a manner that pleases the spending plan requirements of the business.Equipment rentals are an operating costs of the organisation. This suggests that business can make the most of taxable reductions on its lease repayments over the whole term of the lease, as well as implies that the firm will eventually pay much less tax. When purchasing tools for the workplace, sales taxes are included. Leasing prevents these taxes, too.Leasing workplace devices gives organisations the versatility of taking advantage of advancements in innovation, in addition to cost and budget plan benefits. By maintaining funding initially, the balance sheet is improved which will aid when seeking financing for company growth. A register of devaluation is no more required, repayments under the lease agreement are deducted as general expenses for tax obligation purposes, and also devices insurance is offered at extremely affordable rates.Whether a service chooses to get or lease, it is smart for it to discover all funding options available not just simply get on the first option that they involve - you would be shocked at the wonderful offers that can be discovered with taking the ideal suggestions.