text:
|Publication number
|Publication type
|Application number
|Publication date
|Jan 27, 1998
|Filing date
|Aug 2, 1995
|Priority date
|Aug 2, 1995
|Fee status
|Publication number
|Jark Chong Lau, Bryan David Haynes
|Original Assignee
|Kimberly-Clark Worldwide, Inc.
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (97), Non-Patent Citations (8), Referenced by (47), Classifications (19), Legal Events (7)
|External Links: USPTO, USPTO Assignment, Espacenet
This invention relates generally to the production of man-made fibers, and particularly, to the field of production of man-made fibers using melt-blown, coform and spunbond techniques.
The production of man-made fibers has long used melt-blown, coform and spunbond techniques to produce fibers for use in forming non-woven webs of material. FIGS. 1a through 3b illustrate prior art machines which manufacture non-woven webs from melt-blown and spunbond techniques. Additionally, prior art coform techniques are discussed in greater detail hereinafter.
FIGS. 1a-1c illustrate a typical approach for producing melt-blown fibers. Referring to FIG. 1a, a hopper 10 contains pellets of resin. Extruder 12 melts the resin pellets by a conventional heating arrangement to form a molten extrudable composition which is extruded through a melt-blowing die 14 by the action of a turning extruder screw (not shown) located within the extruder 12. As shown in FIG. 1c, the extrudable composition is fed to the orifice 18 through extrusion slot 28. The die 14 and the gas supply fed therethrough are heated by a conventional arrangement (not shown).
FIG. 1b illustrates the die 14 in greater detail. The tip 16 of die 14 contains a plurality of melt-blowing die orifices 18 which are arranged in a linear array across the face 16. Referring now to FIG. 1c, inlets 20 and 21 feed heated gas to the plenum chambers 22 and 23. The gas then exits respectively through the passages 24 and 25 to converge and form a gas stream which captures and attenuates the polymer or resin threads extruded from orifices 18 to form a gas borne stream of fibers 26 as is seen in FIG. 1a.
The melt-blowing die 14 includes a die member 36 having a base portion 38 and a protruding central portion 39 within which an extrusion slot 28 extends in fluid communication with the plurality of orifices 18, the outer ends of which terminate at the die tip. The gas borne stream of fibers 26 is projected onto a collecting device which in the embodiment illustrated in FIG. 1a includes a foraminous endless belt 30 carried on rollers 31 and which may be fitted with one or more stationary vacuum chambers (not shown) located beneath the collecting surface on which a non-woven web 34 of fibers is formed. The collected entangled fibers form a coherent web 34, a segment of which is shown in plan view in FIG. 2. The web 34 may be removed from the belt 30 by a pair of pinch rollers 33 (shown in FIG. 1a) which press the entangled fibers together. The prior art melt-blowing apparatus of FIGS. 1a-1c may optionally include pattern-embossing means as by patterned calender nip or ultrasonic embossing equipment (not shown) and web 34 may thereafter be taken up on a storage roll or passed to subsequent manufacturing steps. Other embossing means may be utilized such as the pressure nip between a calender and an anvil roll, or the embossing step may be omitted altogether.
FIG. 3a illustrates a prior art apparatus 44 for producing spunbond fibers. The spunbond apparatus typically contains a fiber draw unit 46 positioned above an endless belt 78 which is supported on rollers 76. FIG. 3b illustrates the fiber draw unit in greater detail. Fiber draw unit 46 includes upper air regions 48 and 50 and a longitudinal air chamber which contains an upper portion 52, a mid-portion 54, and a lower portion or tail pipe 56. The fiber draw unit also includes a first air plenum 58 and an air inlet 60 leading from the first air plenum 58 to mid-portion 54 of the fiber draw unit. Additionally, a second air plenum 62 also communicates with mid-portion 54 of the fiber draw unit via air inlet 64. The spunbond apparatus 44 also includes standard equipment for melting an extruding resin through dies to create fibers 68. Typically, this equipment feeds resin fed from a supply to a hopper extruder, through a filter, and finally through a die to create the fibers 68.
High velocity air is admitted into the fiber draw unit through plenums 58 and 62 via inlets 72 and 74, respectively. The addition of air to the fiber draw unit through inlets 60 and 64 aspirates air through inlets 50 and 48. The air and fibers then exit through tail pipe 56 into exit area 70. Generally, air admitted into the fiber draw unit through inlets 50 and 48 draws fibers 68 as they pass through the fiber draw unit. The drawn fibers are then laid down on endless belt 78 to form a non-woven web 80 as is seen in FIG. 3a. Rollers 82 may then remove the non-woven web from the endless belt 78 and further press the entangled fibers together to assist in forming the web. The web 80 is then bonded, such as by embossing by calender and anvil, ultrasonic embossing, or other known technique, to form the finished material.
It is well known in the art to vary a number of processing parameters in both melt-blown and spunbond fiber forming processes to obtain fibers of desired properties in order to form fabrics with desired characteristics. However, the majority of prior art techniques for varying fiber characteristics required more time consuming changes in machinery or process, such as changing dies or changing the resins. Therefore, those techniques required that the production line be halted while the necessary changes were made, which resulted in inefficiency when a new material was to be run.
The prior art has previously taught that various effects can be obtained by the manipulation of air flow near the fiber exit in melt-blown and spunbond fiber producing equipment. For example, Shambaugh, U.S. Pat. No. 5,405,559, teaches that the air flow provided in the melt-blown process can be alternately turned on and off on both sides of the die, thus reducing the energy required to produce melt-blown fiber. However, this teaching of Shambaugh has several drawbacks. Under some conditions, the complete shutting off of the air on either side will tend to blow the liquefied resin onto the air plates on the other side of the die, thereby clogging the machinery for typical production airflow rates (especially with high MFR polymers or other polymers normally used in non-woven web production). Further, such techniques would likely result in the deposition of resin globs or "shot", on the production web since the resin would be affected only minimally during the transition from airflow on one side of the die to the other. Finally, while the Shambaugh reference teaches switching air on and off for the purposes of reducing fiber size for a given flow, its main emphasis is that such switching saves energy by reducing the overall airflow requirements in the melt-blown process.
Moreover, the low frequencies taught by Shambaugh would result in poor formation on a high speed machine. Fibers produced as given in the examples are coarser, e.g. larger diameters than typically found in non-woven commercial production. Finally, Shambaugh teaches no applicability of selective alteration of airflow characteristics for varying fiber parameters in a spunbond fiber production environment.
U.S. Pat. No. 5,075,068, teaches the use of a steady state shearing air stream near the exit of the die in the melt-blown process for the purpose of increased drag on fibers exiting the die. The steady state air stream therefore draws the fibers further and enhances the quenching of the fibers. However, this patent teaches a steady state airflow for producing a better fiber, but does not teach that airflow characteristics may be selectively altered to vary the characteristics of fibers in a desired manner.
Finally, U.S. Pat. No. 5,312,500, teaches alternating airflows at the exit of a spunbond fiber draw unit for laying a continuous fiber down in an elliptical fashion to form a non-woven web. This patent teaches that, among other techniques, varying airflows may direct fibers onto a foraminous forming surface to form a non-woven web. By varying the manner in which the fibers are deposited using airflow variation, this reference states that the characteristics of the web may be enhanced. However, this reference does not teach that the airflows may be used to enhance or vary the characteristics of the fibers themselves.
Therefore, it is an object of the present invention to provide novel methods for the production of fibers.
It is a further object of the present invention to provide techniques whereby desired characteristics of fibers may be selected through process control.
It is an additional object of the present invention to provide non-woven webs having desired characteristics through the production of fibers using perturbed airflows during fiber formation.
It is yet another object of the present invention to provide a process and apparatus for the formation of fibers having specific, desired characteristics by the simple, selective variation of the frequency and/or amplitude of perturbation of air flow during the production of the fibers.
It is yet a further object of the present invention to provide processes and apparati, using selective variation of the frequency and/or amplitude of a perturbing airflow in the formation of fibers, which allow for the production of non-woven webs and fabrics having desired characteristics.
The above and further objects are realized in a process and apparatus for the production of fibers in accordance with disclosed and preferred embodiments of the present invention and resulting non-woven webs.
Generally, the present invention relates to an apparatus for forming artificial fibers from a liquefied resin and for forming a non-woven web. The apparatus may include means for generating a substantially continuous airstream for entraining fibers along a primary axis, at least a first extrusion die located next to the airstream for extruding the liquefied resin, and perturbation means for selectively perturbing the air stream by varying the air pressure on either side or both sides of the primary axis. The apparatus may also include a substrate disposed below the first die and substrate translation means for moving the substrate relative to the die, wherein the entrained fibers are deposited on the substrate to form a non-woven web.
The apparatus may include a first supply of air connected to first and second air plenum chambers located on opposite sides of the axis, wherein plenum chambers outlets provide a substantially continuous air stream for fiber attenuation. The perturbation means may include a valve for selectively varying the airflow rate to the first and second plenums, thereby providing airflow perturbation to the entrained fibers. Additionally, airstream perturbation may be achieved by superimposing a perturbed secondary air supply on the first air supply within the plenum chambers. Alternatively, the perturbation means may include first and second pressure transducers adjacent or attached to the first and second plenum chambers and means for selective activation of the first and second pressure transducers for selectively varying the pressure in the first and second plenum chambers. Generally, the perturbation means varies a steady state pressure in the first and second plenum chambers at a perturbation frequency of approximately less than 1000 Hertz and varies an average plenum pressure in the first and second plenum chamber up to about 100% of the total average plenum pressure in the absence of activation of the perturbation means.
The apparatus may also include a fiber draw unit disposed below the first die and adapted to channel the primary air flow therethrough. The fiber draw unit may include a fiber inlet at a top portion thereof for receiving fluid flow and fibers entrained therein and an outlet for dispensing the air entrained fibers onto the substrate. The apparatus may also include a multiple die arrangement for extruding several types of resin simultaneously, as well as means for adding other fibers or particulates (coform).
The apparatus may also include first and second secondary perturbing air supplies disposed on opposite sides of said axis and near the die or fiber draw unit for alternatingly perturbing the substantially continuous flow of air.
The present invention also relates to a method for forming artificial fibers from a liquefied resin and forming a non-woven web thereby, comprising the steps of generating a substantially continuous air stream along a primary axis, extruding the liquefied resin through a first die located adjacent to the air stream, entraining the liquefied resin in the air stream to form fibers, and selectively perturbing the flow of air in the airstream by varying the air pressure on either side of the primary axis.
FIGS. 1a, 1b and 1c illustrate schematic representations of a prior art apparatus for producing melt-blown fibers.
FIG. 2 is a surface representation of a non-woven web made in accordance with prior art methods.
FIGS. 3a and 3b illustrate schematic representations of a prior art apparatus for producing spunbond fibers.
FIG. 4 is a photograph of a surface of a non-woven web manufactured without airstream perturbation.
FIG. 5 is a photograph of a surface of a non-woven web manufactured in accordance with the present invention.
FIGS. 6a, 6b, 6c and 6d illustrate schematic representations of apparati for producing melt-blown fibers according to the present invention.
FIGS. 7a, 7b, 7c, 7d and 7e illustrate schematic representations of three-way valve embodiments which may be utilized in accordance with the present invention.
FIGS. 8a and 8d illustrate plenum pressure as a function of time for a prior art apparatus for producing melt-blown fibers.
FIGS. 8b and 8c illustrate plenum pressure as a function of time for an apparatus for producing melt-blown fibers in accordance with the present invention.
FIG. 9 illustrates fiber diameter distribution for melt-blown fibers manufactured in accordance with the prior art.
FIG. 10 illustrates fiber diameter distribution for melt-blown fibers manufactured in accordance with the present invention.
FIG. 11 illustrates Frazier porosity as a function of perturbation frequency for a melt-blown non-woven web manufactured in accordance with the present invention.
FIG. 12 illustrates hydrohead as a function of perturbation frequency for a melt-blown non-woven web manufactured in accordance with the present invention.
FIG. 13 is a photograph of the surface of a non-woven web manufactured in the absence of airstream perturbation.
FIG. 14 is a photograph of the surface of a non-woven web manufactured in accordance with the present invention.
FIG. 15 illustrates peak load as a function of perturbation frequency of a non-woven web of spunbond fibers.
FIG. 16 is a schematic representation of a coform apparatus configured in accordance with the present invention.
FIGS. 17a, 17b, 17c and 17d and 19 illustrate various apparatus configurations for manufacturing a non-woven web of spunbond fibers in accordance with the present invention.
FIGS. 18a18b, 18c, 18d, 18e and 18f, 20a and 20b, and 21a, 21b, 21c and 21d illustrate various configurations of secondary jets for use with the present invention.
FIGS. 22 and 23 are X-Ray Diffraction Scans of a prior art meltblown fiber and a fiber made in accordance with the present invention.
FIG. 24 is a DSC (Differential Scanning Calorimetry) comparing the calorimetric characteristics of a prior art meltblown fiber and a fiber made in accordance with the present invention.
The following techniques are applicable to the melt-blown, spunbond and coform fiber forming processes. For the sake of clarity, the general principles of the invention will be discussed with reference to these techniques. Following the general description of the techniques, the specific application of these techniques in the melt-blown, spunbond, and coform fields will be described. For ease in following the discussion, sub-headings are provided below; however, these sub-heading are for the sake of clarity and should not be considered as limiting the scope of the invention as defined in the claims. As used herein, the term "perturbation" means a small to moderate change from the steady flow of fluid, or the like, for example up to 50% of the steady flow, and not having a discontinuous flow to one side. Furthermore, as used herein, the term fluid shall mean any liquid or gaseous medium; however, in general the preferred fluid is a gas and more particularly air. Additionally, as used herein the term resin refers to any type of liquid or material which may be liquefied to form fibers or non-woven webs, including without limitation, polymers, copolymers, thermoplastic resins, waxes and emulsions.
As was described previously, the production of fibers having various characteristics has been known in the prior art. However, the preferred embodiments of the present invention provide for a much greater range of variation in fiber characteristics and provide for a greater range of control for forming various non-woven web materials from such fibers. These techniques allow one to "tune in" the characteristics of the non-woven web formed thereby with little or no interruption of the production process. The basic technique involves perturbing the air used to draw the fiber from the die. Preferably, the airflow in which the fiber travels is alternately perturbed on opposite sides of an axis parallel to the direction of travel of the fiber. Thus, the airstream carrying the forming fiber is perturbed, resulting in perturbation of the fiber during formation. Airstream perturbation according to the methods and apparati of the present invention may be implemented in melt-blown and spunbond manufacturing, but is not limited to those processes.
In general, the airflow may be perturbed in a variety of ways; however, regardless of the method used to perturb the airflow, the perturbations have two basic characteristics, frequency and amplitude. The perturbation frequency may be defined as the number of pulses provided per unit time to either side. As is common the frequency will be described in Hertz (number of cycles per second) throughout the specification. The amplitude may also be described by the percentage increase or difference in air pressure (ΔP/P)�100 in the perturbed stream as compared to the steady state. Additionally, the perturbation amplitude may be described as the percentage increase or difference in the air flow rate during perturbation as compared to the steady state. Thus, the primary variables which may be controlled by the new fiber forming techniques are perturbation frequency and perturbation amplitude. The techniques described below easily control these variables. A final variable which may be changed is the phase of the perturbation. For the most part, a 180� phase differential in perturbation is described below (that is, a portion of the airflow on one side of an axis parallel to the direction of flow is perturbed and then the other side is alternately perturbed); however, the phase differential could be adjusted between 0� to 180� to achieve any desired result. Tests have been conducted with the perturbation being symmetric (in phase) and with varying phase relationships. This variation allows for still more control over the fibers made thereby and the resulting web or material.
The perturbation of the air stream and fibers during formation has several positive effects on the fiber formed thereby. First, the particular characteristics of the fiber such as strength and crimp may be adjusted by variation of the perturbation. Thus, in non-woven web materials, increased bulk and tensile strength may be obtained by selecting the proper perturbation frequency and amplitude. Increased crimp in the fiber contributes to increased bulk in the non-woven web, since crimped fibers tend to take up more space. Additionally, preliminary investigation of the characteristics of meltblown fibers made in accordance with the present invention, as compared to those made with prior art techniques, appears to indicate that fibers made in accordance with the present invention exhibit different crystalline and heat transfer characteristics. It is believed that such differences are due to heat transfer effects (including quenching) which result from the movement of fibers in a turbulent airflow. It is further believed that such differences contribute to the enhanced characteristics of fibers and non-woven materials made in accordance with the techniques of the present invention. Additionally, the perturbation of the airflow also results in improved deposition of the fibers on the forming substrate, which enhances the strength and other properties of the web formed thereby.
Furthermore, since the variables of frequency and amplitude of the perturbation are easily controlled, fibers of different characteristics may be made by changing the frequency and/or amplitude. Thus, it is possible to change the character of the non-woven web being formed during processing (or "on the fly"). By this type of adjustment, a single machine may manufacture non-woven web fabrics having different characteristics required by different product specification while eliminating or reducing the need for major hardware or process changes, as is discussed above. Additionally, the present invention does not preclude the use of conventional process control techniques to adjust the fiber characteristics.
Referring now to FIGS. 4 and 5, magnified photographs of melt-blown webs made in accordance with prior art techniques (FIG. 4) and according to the present invention (FIG. 5) may be compared. As is seen in FIG. 4, the individual fibers of the web are relatively linear. However, as is seen in FIG. 5, the fibers in the web made in accordance with the perturbation techniques of the present invention are much more crimped and are not predominantly aligned in the same direction. Thus, as will be seen in the results described below, webs made in accordance with the present invention tend to exhibit greater bulk for a given weight and frequently have greater machine and cross direction strengths (the machine direction is the direction of movement, relative to the forming die, of the substrate on which the web is formed; the cross direction is perpendicular to the machine direction). It is believed that the increased crimp will provide many more points of contact for the fibers of the web which will enhance web strength. As a note, at first glance it would appear that many more and larger voids are present in the web of FIG. 5 as compared to that of FIG. 4; however, in fact, the web of FIG. 5 does not contain more or larger voids than that of FIG. 4. Since the SEM photographs of these Figures present views of the top surface of the material, the increased bulk of the web of FIG. 5 is not seen in the photograph and the bulk manifests in a manner to make it appear that there are a greater number of larger voids. Conversely, since the web of FIG. 4 has less bulk, a greater number of fibers of that web are located in the plane of the photograph, giving the appearance of fewer and smaller voids. As is seen below, the barrier properties of webs made in accordance with the present invention can be selected to be superior to those made in accordance with the prior art, thus demonstrating that the appearance of voids in the photograph of FIG. 5 is misleading.
FIGS. 6a through 6d illustrate various embodiments of the present invention which utilize alternating air pulses to perturb air flow in the vicinity of the exit of a melt-blown die 59. Each melt-blown embodiment of the present invention includes diametrically opposed plenum/manifolds 22 and 23 and air passages 24 and 25 which lead to a tip of the melt die 59 to create a stream of fibers in a jet stream 26. The function of the present invention is to maintain a steady flow and to superimpose an alternating pressure perturbation on that steady flow near the tip of melt die 59 by alternatingly increasing or reducing the pressure of the manifolds 22 and 23. This technique assures controlled modifications in the gas borne stream of fibers 26 and therefore facilitates regularity of pressure fluctuations in the gas borne stream of fibers. Additionally, the relatively high steady state air flow with respect to perturbation air flow amplitude also serves to prevent the airborne stream of fibers from becoming tangled on air plates 40 and 42. The jet structure air entrainment rate (and therefore quenching rate) and fiber entanglement are thus modified favorably.
FIGS. 7a through 7d illustrate a few examples of valves that alternatingly augment the pressure in plenum chambers 22 and 23 shown in FIGS. 6a-6d. Referring to FIG. 7a, perturbation valve 86 is essentially comprised of a bifurcation of main air line 84 into inlet air lines 20 and 21. In the immediate vicinity of the bifurcation, a pliant flapper 98 alternatingly traverses the full or partial width of the bifurcation. This provides a means for alternatingly restricting air flow to one of air inlet lines 20 and 21 thereby superimposing a fluctuation in air pressure in manifolds 22 and 23. Alternatively, an activator may mechanically oscillate the flapper across the bifurcation to produce the appropriate fluctuation in air pressure in plenums 22 and 23. Flapper valve 98 may traverse the bifurcation of mainline 84 in an alternating manner simply by the turbulence of air in mainline 84 using the natural frequency of the flapper. Oscillation frequency of valve 86 as disclosed in FIG. 7a may be varied mechanically by an activator which reciprocates the flapper, or by simply adjusting the length of the flapper 98 to change its natural frequency.
FIG. 7b illustrates a second embodiment of the perturbation valve 86. This embodiment may include a motor 100 which rotates a shaft 102. The shaft 102 may be fixed to a rotation plate 109 which has a plurality of apertures 108 disposed thereon. Behind rotation plate 109 is a stationary plate 104 containing a plurality of apertures 106. Both disks may be mounted so that flow is realized through fixed disk openings only when apertures from the rotation plate 109 are aligned with apertures in the stationary plate 104. The apertures on each plate may be arranged such that a steady flow may be periodically augmented when apertures on each plate are aligned. The frequency of the augmented flow may be controlled through a speed control of motor 100.
FIG. 7c illustrates yet another embodiment of perturbation valve 86. In this embodiment a motor 100 is rotatingly coupled to a shaft 112 which supports a butterfly valve 110 having essentially a slightly smaller cross-section than main air line 84. Turbulence created downstream from rotating butterfly 110 may then provide an alternatingly augmented air pressure in air inlet lines 20 and 21 and also in air plenums 22 and 23 to achieve the flow conditions in accordance with the present invention.
FIG. 7d represents yet another embodiment of a perturbation valve 86 in accordance with the present invention. There, a motor 100 is coupled to a shaft 112 and butterflies 110 and 114 within inlet air lines 20 and 21 respectively. As is seen from FIG. 7d, butterflies 110 and 114 are mounted on shaft 112 approximately 90� to each other. Additionally, each of the butterflies 110 and 114 may include apertures 111 so as to provide a constant air flow to each of the plenums while alternatingly augmenting pressure in each of the plenums 22 and 23 when the appropriate butterfly is in an open position.
FIG. 7e represents still another embodiment of the perturbation valve 86. In this embodiment an actuator 124 is coupled to a shaft 122 which in turn is mounted to a spool 123. Spool 123 includes channels 118 and 120 which communicate with air inlet lines 20 and 21 respectively, depending on the longitudinal position of the spool 123. Each of the channels 118 and 120 is fluidly connected to main channel 116 which is fluidly connected to main air line 84. In this embodiment, perturbation valve 86 may achieve alternatingly augmented air pressures in each of the plenums by reciprocation of rod 122 from actuator 124. Additionally, channels 118 and 120 may simultaneously be connected to main air line 84 while activator 124 reciprocates spool 123 to vary an amount of overlap, and thus air flow restriction, between channels 118 and 120 with lines 20 and 21, respectively, to achieve alternating augmented pressures in the plenum chambers 22 and 23, respectively. Actuator 124 may include any known means for achieving such reciprocation. This may include but is not limited to pneumatic, hydraulic or solenoid means.
FIGS. 8a-8d illustrate, respectively, plenum air pressures in both the prior art melt-blown apparatus and in the melt-blown apparatus according to the present invention. As is seen in FIG. 8a, a prior art air pressure in the plenum chambers is essentially constant over time whereas in FIGS. 8b and 8c the air pressure in the plenum chambers is essentially augmented in an oscillatory manner. As an example, the point at which the mean pressure intersects the ordinate can be about 7 psig. FIG. 8d illustrates a prior art air pressure in the vicinity of a prior art extrusion die where air is turned on and off. In this case, the mean pressure meets the ordinate at about 0.5 psig, for example. The on/off control of prior art air flow as illustrated in FIG. 8d is conducive to die clogging due to the intermittent flow, as explained above. Additionally, the prior art on/off air flow control illustrated in FIG. 8d (implemented by Shambaugh) utilizes a lower average pressure, a lower frequency and less pressure amplitude than the present invention. Although the airflow characteristic illustrated in FIG. 8a is not conducive to die clogging, no control may be implemented over fiber crimping or web characteristics, since the flow is virtually constant with respect to time.
Perturbation valve 86 may be placed in a multitude of arrangements to achieve the alternatingly augmented flow in plenum chambers 22 and 23 of the melt-blown apparatus according to the present invention. For example, FIG. 6b shows another embodiment according to the present invention. In this embodiment, main air line 84 bifurcates constant air flow to inlet air lines 20 and 21 while bleeding an appropriate flow of air to perturbation valve 86 via bleeder valve 88 and line 90. Therefore, in this embodiment plenum chambers 23 and 22 each include two inlets. The first inlet introduces essentially constant flow from air inlet lines 20 and 21. The second inlet of each plenum chamber introduces the alternating flow to the chamber, thereby superimposing oscillatory flow on the constant flow from lines 20 and 21. The amount of air bled from bleeder valve 88 will control the amplitude of the pressure augmentation for precise adjustment of fiber characterization, as explained in greater detail below, while perturbation valve 86 controls frequency.
FIG. 6c represents yet another embodiment of the present invention. In this embodiment, main air line 84 bifurcates into air lines 21 and 20 to supply air pressure to plenum chambers 22 and 23. Additionally, an auxiliary air line 92 bifurcates at perturbation valve 86. The perturbation valve 86 then superimposes an alternatingly augmented air pressure onto plenum chambers 22 and 23 to achieve the oscillatory flow conditions in accordance with the present invention. Here, pressure on the air line 92 controls the amplitude of air pressure perturbation, while perturbation valve 86 controls perturbation frequency, as explained above.
FIG. 6d represents yet another embodiment of the present invention. In this embodiment, main air line 84 bifurcates into inlet air lines 20 and 21 which lead to plenum chambers 22 and 23 respectively. The alternatingly augmented pressure in plenum chambers 22 and 23 may be provided by transducers 94 and 96 respectively. Transducers 94 and 96 are actuated by means of an electrical signal. For example, the transducers may actually be large speakers which receive an electrical signal to pulsate 180� out of phase in order to provide the alternating augmented pressures in plenum chambers 22 and 23. However, any type of appropriate transducer may create an augmented air flow by using any means of actuation. This may include but is not limited to electromagnetic means, hydraulic means, pneumatic means or mechanical means.
As was discussed previously, all of the described embodiments allow for the precise control of the perturbation frequency and amplitude, preferably without interrupting the operation of the fiber forming machinery. As will be described below, this ability to precisely control the perturbation parameters allows for relatively precise control of the characteristics of the fibers and web formed thereby. Typically, there are a wide variety of fiber parameters and while a particular set of parameters may be desired for making one type of non-woven material, such as filter material, a different set of fiber parameters may be desired for making a different type of material, such as for disposable garments.
For example, in filter applications, the material is preferably made of small diameter fibers. However, larger diameter fibers may be desired for other materials. Furthermore, many end products consist of layers of material having a variety of characteristics. For example, disposable diapers generally consist of a wicking layer designed to move moisture away from contact with the skin of an infant and to keep such moisture away. A middle, absorbent layer is used to retain the moisture. Finally, an outer, barrier layer is desired to prevent the absorbed moisture from seeping out of the diaper. The fiber characteristics for each layer of the diaper are different in order to achieve the specific functions of each type of material. With the present techniques, various portions of the web can be formed by varying the perturbation parameters with respect to time so that each layer of the diaper is formed sequentially in one non-woven web. Then the single web may be folded to provide the layered finished material.
Thus, with precise control of the fiber and material characteristics by control of the perturbation characteristics, a great degree of flexibility is possible in the formation of non-woven webs. This control, in turn, allows for greater efficiency and the ability to design a greater range of materials which may be produced with little interruption of the production process.
One shortcoming of prior art melt-blown equipment is the relative inability to precisely control the diameter of fibers produced thereby. The formation of materials with particular characteristics often requires precise control over the diameter of the fibers used to form the non-woven web. With the perturbation technique of the present invention, it is possible to provide for much less variation in fiber diameter than was previously possible with prior art techniques.
FIGS. 9 and 10 illustrate fiber diameter distribution for samples taken from prior art melt-blown techniques and the melt-blown fiber producing technique according to the melt-blown apparatus embodiment of FIG. 6c. FIG. 9 shows a diameter distribution in accordance with the prior art. FIG. 10 represents a fiber diameter distribution chart for melt-blown fibers made in accordance with the inventive technique. The fiber distribution in FIG. 10 illustrates a fiber diameter sample which has a distribution that is centered on a peak between about 1 and 2 microns. Here, the narrow band of fiber distribution achieved by the perturbation method and apparatus illustrates the great extent to which fiber diameter may be controlled by only varying perturbation frequency or amplitude.
FIG. 11 represents the Frazier porosity of a non-woven melt-blown web made in accordance with the present invention as a function of perturbation frequency in the plenum chambers 22 and 23. The Frazier Porosity is a standard measure in the non-woven web art of the rate of airflow per square foot through the material and is thus a measure of the permeability of the material (units are cubic feet per square foot per minute). For all samples the procedure used to determine Frazier air permeability was conducted in accordance with the specifications of method 5450, Federal Test Methods Standard No. 191 A, except that the specimen sizes were 8 inches by 8 inches rather than 7 inches by 7 inches. The larger size made it possible to ensure that all sides of the specimen extended well beyond the retaining ring and facilitated clamping of the specimen securely and evenly across the orifice.
As is illustrated in FIG. 11, the Frazier porosity generally falls first to a minimum and then increases with perturbation frequency from a steady state to approximately 500 hertz. Thus, one can observe that to make a material with a desired Frazier porosity with the present invention, it is only necessary to vary the oscillation frequency (and/or the amplitude). With prior art techniques, changes in porosity often required changes to the die or starting materials or the duplication of machinery. Thus, with the present techniques, it is possible to easily change the porosity of a material once a run is completed; it is only necessary to adjust the perturbation frequency (or amplitude), which can easily be done with simple controls and without stopping production. Therefore, the melt-blowing apparati according to the present invention may quickly and easily manufacture filtering materials of varying porosity by simply changing perturbation frequency.
FIG. 12 illustrates a plot of hydrohead as a function of perturbation frequency. The Hydrohead Test is a measure of the liquid barrier properties of a fabric. The hydrohead test determines the height of water (in centimeters) which the fabric will support before a predetermined amount of liquid passes through. A fabric with a higher hydrohead reading indicates it has a greater barrier to liquid penetration than a fabric with a lower hydrohead. The hydrohead test is performed according to Federal Test Standard No. 191A, Method 5514. Generally, hydrohead first increases and then decreases with increasing perturbation frequency in a frequency range of approximately 75 hertz to 525 hertz. Since perturbation frequency directly affects hydrohead, an appropriate adjustment of the perturbation valve 86 provides the type of barrier to liquid required by a particular application. Perturbation frequency may be used to vary hydrohead to suit the particular use for the material.
The following examples provide a basis for demonstrating the advantages of the present invention over the prior art in the production of melt-blown, coform and spunbond webs and materials. These examples are provided solely for the purpose of illustrating how the methods of the present invention may be implemented and should not be interpreted as limiting the scope of the invention as set forth in the claims.
Process Condition
Die Tip Geometry:
Die Width=20"
30 hpi
Primary Airflow:
Heated (≈608� F. in heater)
488 scfm
Pressure PT =6.6 psig
Auxiliary Airflow:
Unheated (ambient air temp.)
60 scfm
Inlet Pressure=20 psig
Copolymer of butylene and propylene
blue pigment--01%
*800 MFR polypropylene coated with peroxide--final MFR≈1500
Polymer Throughput: 0.5 GHM
Melt Temperature: 470� F.
Perturbation Frequency: 0 Hz, 156 Hz, 462 Hz
Basis Weight: 0.54 oz/yd2
Forming Height: 10"
Test Results
TABLE 1-1______________________________________Perturbation Frequency 0 Hz 156 Hz 462 Hz______________________________________Frazier Porosity 45.18 35.70 65.89(cfm/ft2)Hydrohead (cm) 86.40 103 74.60______________________________________
In this example, the melt-blown process was configured as described above and corresponds to the embodiment shown in FIG. 6c, in which the primary airflow is supplemented with an auxiliary airflow. In the example, the unit hpi characterizes the number of holes per inch present in the die. PT is defined as the total pressure measured in a stagnant area of the primary manifold. GHM is defined as the flow rate in grams per hole per minute; thus, the GHM unit defines the amount, by weight, of polymer flowing through each hole of the melt-blown die per minute. As discussed above, Frazier Porosity is a measure of the permeability of the material (units are cubic feet per minute per square foot). The hydrohead, measured as the height of a column of water supported by the web prior to permeation of the water into the web, measures the liquid barrier qualities of the web.
The above configuration and results provide a baseline comparison of a typical melt-blown production run with no air perturbation (a frequency of perturbation of 0 Hz) with runs conducted with perturbation frequencies of 156 and 462 Hz. As can be seen from Table 1-1, in general, the barrier characteristics of materials made using perturbed airflows improve with increasing perturbation frequency. Thus, by merely varying the perturbation frequency, a relatively easy process, materials or webs with desired barrier characteristics may be made without major changes to the process conditions. This ability to adjust barrier properties was not previously possible in the prior art without substantial changes to the process conditions which required significant time and effort. As can be seen there is an initial decrease in Frazier Porosity (which represents an decrease in the permeability of the web or material to air) at the 156 Hz perturbation frequency. Similarly, at the 156 Hz frequency, there is an increase in the supported hydrohead. Thus, at the 156 Hz frequency, the web material produced is a more effective barrier. At the 462 Hz perturbation frequency, the Frazier Porosity has increased and the Hydrohead has decreased from both the 0 Hz (prior art) and 156 Hz production runs. Thus, at the higher perturbation frequency, the web material is a less effective barrier, but is more suitable for use as an absorbent or wicking material.
The change in barrier properties with respect to change in perturbation frequency is also demonstrated in FIGS. 11 and 12 (for different process conditions from those of Example 1). As FIG. 11 shows, there is an initial drop in Frazier Porosity as the process is changed from no perturbation to a perturbation frequency between 1 and 200 Hz. As the perturbation frequency is increased above about 200 Hz, the Frazier Porosity increases, until the original 0 Hz Frazier Porosity is exceeded between about 300 to 400 Hz. Above 400 Hz, the Frazier Porosity increases relatively steeply with increasing perturbation frequency. Similarly, referring to FIG. 12, supported hydrohead initially increases between about 1 to 200 Hz perturbation frequency. Then the hydrohead steadily decreases with increasing perturbation frequency until the supported hydrohead at between about 400 to 500 Hz is less than that at the 0 Hz (steady flow) frequency. Thus, as these Figures demonstrate, with no variation in the basic process conditions such as polymer type, flow conditions, die geometry, aside from a simple change in the frequency of perturbation of the airflow, a wide variety of different web materials can be made having desired barrier properties. For example, by merely setting the perturbation frequency in the 100 to 200 Hz range, with all of the other process conditions remaining unchanged, a more effective barrier material can be made. Then, if less effective barrier material is desired, the only process change necessary would be an increase in the perturbation frequency, which could be accomplished with a simple control and without necessitating the interruption of the production line. In prior art techniques, alteration of the production run barrier properties may require substantial changes in the process conditions, thereby requiring a production line shut-down to make the changes. In actuality, such changes are not typically made on a given machine; multiple machines typically produce a single type of web material (or an extremely narrow range of materials) having desired properties.
Process Conditions
Die Tip Geometry:
Die Width=20"
30 hpi
Primary Airflow:
Heated (≈608� F. in heater)
317 scfm
Pressure PT =2.6 psig
Auxiliary Airflow:
Unheated (ambient air temp.)
80 scfm
Inlet Pressure=20 psig
Polymer: High MFR PP*
*e.g. 800 MFR polypropylene coated with peroxide--final MFR≈1500
Polymer Throughput: 0.5 GHM
Melt Temperature: 470� F.
Perturbation Frequency: 0 Hz (control), 70 Hz
Basis Weight: 5 oz/yd2
Forming Height: 10"
Test Results
In this example the bulk of the web made using a 70 Hz perturbation frequency was compared to a control web (0 Hz perturbation frequency).
Control--0.072" (thickness)
70 Hz--0.103"
Thus, it can be seen that using a modest 70 Hz perturbation frequency results in a 43% increase in bulk over the prior art. Increased bulk is often desired in the final web or material because the increased bulk often provides for better feel and absorbency.
Furthermore, with respect to desired texture or appearance, the use of the perturbation techniques of the present invention allows for custom texture or appearance control. Referring to the photographs of FIGS. 13 and 14, FIG. 13 represents the appearance of the web produced with the 0 Hz perturbation frequency while the web of FIG. 14 represents that produced using the 70 Hz perturbation frequency. As can be seen from the Figures, the web of FIG. 14 has a leather like appearance and texture which is not present in the web of FIG. 13. Thus, to the extent such appearance and texture is desired, the techniques of the present invention allow for added control and variety in production of various types of webs having such characteristics.
Process Conditions
Die Tip Geometry:
30 hpi
Primary Airflow:
Heated (≈608� F. in heater)
426 scfm
Pressure PT =5 psig
Auxiliary Airflow:
Unheated (ambient air temp.)
80 scfm
Inlet Pressure=20 psig
High MFR PP*, 1% Blue pigment
*e.g. 800 MFR polypropylene coated with peroxide--final MFR≈1500
Polymer Throughput: 0.6 GHM
Melt Temperature: 480� F.
Perturbation Frequency: 0 Hz (control), 192 Hz, 436 Hz
Basis Weight: 0.54 oz/yd2
Forming Height: 10"
Test Results
Softness--Cup Crush--0 Hz--1352 192 Hz--721
Cup Crush is a measure of softness whereby the web is draped over the top of an open cylinder of known diameter, a rod of a diameter slightly less than the inner diameter of the cup cylinder is used to crush the web or material into the open cylinder while the force required to crush the material into the cup is measured. The cup crush test was used to evaluate fabric stiffness by measuring the peak load required for a 4.5 cm diameter hemispherically-shaped foot to crush a 22.9 cm by 22.9 cm piece of fabric shaped into an approximately 6.5 cm diameter by 6.5 centimeter tall inverted cup while the cup shaped fabric was surrounded by an approximately 6.5 cm centimeter diameter cylinder to maintain a uniform deformation of the cup shaped fabric. The foot and cup were aligned to avoid contact between the cup walls and the foot which could affect the peak load. The peak load was measured while the foot was descending at a rate of about 0.64 cm/s utilizing a Model 3108-128 10 load cell available from the MTS Systems Corporation of Cary, N.C. A total of seven to ten repetitions were performed for each material and then averaged to give the reported values.
The lower cup crush number achieved by the material made using the 192 Hz perturbation frequency indicates that the material made thereby is softer. Subjective softness tests such as by hand or feel also confirm that the material made by using the 192 Hz perturbation frequency is softer than that made using the prior art techniques.
TABLE 3-1______________________________________Perturbation Frequency 0 Hz 192 Hz 436 Hz______________________________________MD Peak Load (lbs) 1.989 2.624 2.581MD Elongation (in) 0.145 0.119 0.087CD Peak Load (lbs) 1.597 1.322 1.743CD Elongation (in) 0.202 0.212 0.135______________________________________
As can be seen from Table 3-1, the machine direction strength increases for runs in which the perturbation frequency is greater than 0 Hz. In the production runs of Example 3, the direction of perturbation was generally parallel to the machine direction (MD). Applicants believe that the increased strength in MD is due to more controlled and regular overlap in the lay-down of the web on the substrate as the fibers oscillate as a result of the perturbation. A similar result is demonstrated in FIG. 15 which is a graph showing the variation of Peak Load in MD and CD as a function of perturbation frequency. As is seen in the FIG. 15, strength in the MD increases as the perturbation frequency increases. Typically, CD strength remains relatively constant (with slight variations) regardless of perturbation frequency. It is applicants' belief that increases in CD strength can be achieved by varying the angle of the perturbation relative to the MD. Thus, by having the perturbation occur at some angle between parallel to MD and perpendicular to MD, CD strength can be improved as well as MD strength.
TABLE 3-2______________________________________Perturbation Frequency 0 Hz 192 Hz______________________________________Frazier Porosity 31.5 22.3(cfm/ft2)Hydrohead (cm of H2 O) 90.8 121.6Equiv. Pore Diameter (μm) 13.2 10.8______________________________________
As Table 3-2 demonstrates, and as was demonstrated in Example 1, at relatively low perturbation frequencies (between about 100 to 200 Hz) the barrier properties of a web produced thereby increase. This result is explained by the measured Equivalent Circular Pore Diameter in the 0 Hz case and the 192 Hz case. As is shown in Table 3-2, the pore size for web material produced using a 192 Hz perturbation frequency is 2.4 microns less than that for a material produced with no perturbation. Thus, since the pores in the material are smaller, the permeability of the material is less and the barrier properties are greater.
Process Conditions
Die Tip Geometry:
Die Width=20"
30 hpi
Primary Airflow:
Heated (≈608� F. in heater)
422 scfm
Pressure PT=5 psig
Auxiliary Airflow:
Unheated (ambient air temp.)
40 scfm
Inlet Pressure=15 psig
Copolymer of butylene and propylene
blue pigment--01%
*800 MFR polypropylene coated with peroxide--final MFR≈1500
Polymer Throughput: 0.6 GHM
Melt Temperature: 471� F.
Perturbation Frequency: 0-463 Hz
Basis Weight: 0.8 oz/yd2
Forming Height: 12"
Test Results
TABLE 4-1______________________________________Perturbation Frequency 0 Hz 305 Hz 463 Hz______________________________________Frazier Porosity 46.27 26.85 59.34(cfm/ft2)______________________________________
Once again, it can be seen that the porosity of the web material initially decreases when the airflow is perturbed. However, as the perturbation frequency increases, the porosity also increases. The results in Example 4 agree with the other barrier property results from the other examples and with the results reported in FIGS. 11 and 12.
Although the above referenced examples utilize a polypropylene or mixture of high melt flow polypropylene and polybutylene resins for non-woven web production, a multitude of thermoplastic resins and elastomers may be utilized to create melt-blown non-woven webs in accordance with the present invention. Since it is the structure of the web of the present invention which is largely responsible for the improvements obtained, the raw materials used may be selected from a wide variety. For example, and without limiting the generality of the foregoing, thermoplastic polymers such as polyolefins including polyethylene, polypropylene as well as polystyrene may be used. Additionally, polyesters may be used including polyethylene terepthalate and polyamides including nylons. While the web is not necessarily elastic, it is not intended to exclude elastic compositions. Compatible blends of any of the foregoing may also be used. In addition, additives such as processing aids, wetting agents, nucleating agents, compatibilizers, wax, fillers, and the like may be incorporated in amounts consistent with the fiber forming process used to achieve desired results. Other fiber or filament forming materials will suggest themselves to those of ordinary skill in the art. It is only essential that the composition be capable of spinning into filaments or fibers of some form that can be deposited on a forming surface. Since many of these polymers are hydrophobic, if a wettable surface is desired, known compatible surfactants may be added to the polymer as is well-known to those skilled in the art. Such surfactants include, by way of example and not limitation, anionic and nonionic surfactants such as sodium diakylsulfosuccinate (Aerosol OT available from American Cyanamid or Triton X-100 available from Rohm & Haas). The amount of surfactant additive will depend on the desired end use as will also be apparent to those skilled in this art. Other additives such as pigments, fillers, stabilizers, compatibilizers and the like may also be incorporated. Further discussion of the use of such additives may be had by reference to, for example, U.S. Pat. Nos. 4,374,888 issued on Bornslaeger on Feb. 22, 1983, and U.S. Pat. No. 4,070,218 issued to Weber on Jan. 24, 1978.
Additionally, a multitude of die configurations and die cross-sections may be utilized to create melt-blown non-woven webs in accordance with the present invention. For example orifice numbers of 20 to 50 holes per inch (hpi) are preferred. Moreover, virtually any appropriate orifice diameter may be utilized. Additionally, star-shaped, elliptical, circular, square, triangular, or virtually, any other geometrical shape for the cross-section of an orifice may be utilized for melt-blown non-woven webs.
Applicant hereby incorporate by reference U.S. Pat. No. 4,818,464, issued to Lau on Apr. 4, 1989 which discloses coform methods of polymer processing by combining separate polymer melt streams into a single polymer melt stream for extrusion through orifices in forming non-woven webs. Additionally, applicant hereby incorporates by reference U.S. Pat. No. 4,818,464, issued to Lau on Apr. 4, 1989 which discloses the introduction of superabsorbent material as well as pulp, cellulose, or staple fibers through a centralized chute in an extrusion die for combination with resin fibers in a non-woven web. Referring now to FIG. 16, a description of one form of the coform process is provided. In essence, a coform die is basically a combination of two melt-blown die heads 173, 175. Air flows 176 and 178 are provided around die 172 and air flows 180 and 182 are provided around die 174. A chute 184 is provided through which pulp, staple fibers, or other material may be added to vary the characteristics of the resulting web. Since any of the above described techniques to vary the airflow around a melt-blown die may be used in the coform technique, specific descriptions of all of the valving techniques will not be repeated. However, it will be apparent to one skilled in the art, that to vary the four air flows present in the coform die, the equipment used to control the perturbation of the air flows will have to be doubled.
In the coform technique, there are a variety of possible perturbation combinations. The most basic is to perturb each side of a given die 172 or 174 just as described above with respect to the melt-blown techniques (basically, air flows 176 and 178 alternating with each other and the same for airflows 180 and 182). However, it is also possible to perturb the air flows around die 172 relative to those around die 174. Thus, air flows 176 and 182 could be perturbed in phase with each other, but out of phase with air flows 178 and 180 to achieve a desired characteristic in the fibers or web. To achieve a different effect it may be desirable for air flows 176 and 180 to be perturbed in phase with each other, but out of phase with air flows 178 and 182. It should be readily apparent that with four air flows, many perturbation combinations are possible, all of which are within the scope of the present invention. For example, a centralized chute may be located between the two centralized air flows for introducing pulp or cellulose fibers and particulates. Such a centralized location facilitates integration of the pulp into the non-woven web and results in consistent pulp distribution in the web.
As described above with reference to FIG. 16, coform materials are essentially made in the same manner as melt-blown materials with the addition of a second die. Thus, there are two airflows around each die, for a total of four air flows, which may be perturbed as described above. Additionally, there is typically a gap between the two dies through which pulp or other material may be added to the fibers produced and incorporated into the web being formed. The following example utilizes such a coforming arrangement, but otherwise, with respect to the airflow perturbation, conforms to the previous description of the melt-blown process.
Process Conditions
Die Tip Geometry:
Die Width=20"
Primary Air Flow: 350 scfm per bank (20" bank)
Primary Air Temperature: 510� F.
Auxiliary Air Flow: 40 scfm per MB bank
Polymer: PF-015 (polypropylene)
Pulp/Polymer Ratio: 65/35
Basis Weight: 75 gsm (2.2 osy)
Test Results
TABLE 5-1______________________________________Perturbation Frequency 0 Hz 67 Hz 208 Hz 320 Hz______________________________________MD Peak Load 1.578 1.501 1.67 2.355MD Elongation (%) 23.86 22.48 24.21 20.23CD Peak Load 0.729 0.723 0.759 0.727CD Elongation (%) 49.75 52.46 58.08 71.23Cup Crush (gm/mm) 2518 2485 2434 2281______________________________________
From table 5-1, it can be seen that the results generally agree with those shown in the melt-blown examples. Generally, with increasing perturbation frequency, aligned along the MD, MD strength increased while CD strength remains about the same. Similarly, the softness, measured as cup crush, generally increases as the perturbation frequency increases (a lower cup crush value indicates increased softness). Thus, this example shows that the techniques previously described can be applied to coform-forming technology to achieve the process and material control by simple adjustment of the perturbation frequency in the same manner as they were applied to the melt-blown process.
FIGS. 17a through 17d represent various embodiments which utilize alternatingly augmented air pressure in plenum chambers 58 and 62 of a standard fiber draw unit, as illustrated in FIG. 3b. In a manner similar to that of the valving arrangements for the melt-blown unit, the fiber draw unit may receive alternatingly augmented air pressure into plenum chambers 62 and 58 via lines 74 and 72, respectively, through the bifurcation of main air lines 66 via perturbation valve 86. Alternatively, as is illustrated in FIG. 17b, main air line 66 may be bifurcated by valve 86 into supply lines 130 and 128 with a third bleeder portion supplying perturbation valve 86. While lines 128 and 130 receive air from bleeder valve 88 at a relatively constant pressure, perturbation valve 86 receives bleed air from bleeder valve 88 and perturbs that air to create an oscillatory pressure which is then superimposed onto supply lines 128 and 130 to create alternatingly augmented pressure in lines 74 and 72 for supply to plenum chambers 62 and 58, respectively. In yet another embodiment illustrated in FIG. 17c, main supply line 66 bifurcates into lines 128 and 130. This embodiment utilizes an auxiliary air supply 92 which is perturbed by valve 86 superimposed onto the constant air pressure of lines 128 and 130 to create an alternatingly augmented air flow supply in lines 72 and 74 so as to supply air plenum chambers 62 and 58 of the fiber draw unit, respectively. Finally, FIG. 17d represents still another embodiment of the present invention which utilizes a perturbation valve 86 which provides an alternatingly perturbing air flow prior to the bifurcation of the main air supply line.
FIGS. 18a through 18f illustrate various locations for secondary perturbation jets which may be used with a standard prior art fiber draw unit such as the one illustrated in FIG. 3b to create the proper flow conditions for increasing desirable properties of fibers made in accordance with the present invention. For example, FIG. 18a illustrates the tail pipe 56 of a fiber draw unit which utilizes secondary perturbation jets 132 and 134. As described above, these secondary perturbation jets impose alternating augmented flow in a direction which is perpendicular to the main air flow through the tail pipe 56 of the present invention. This orthogonal relationship between primary and secondary air flow increases both the degree and order of turbulence of the air flow in the vicinity of the tail pipe 56.
As illustrated in FIG. 18b, tail pipe 56 may also include alternatingly, or otherwise activated, co-flowing jets 136 and 138 to create turbulent flow in accordance with the present invention near the tail pipe of the fiber draw unit. FIG. 18c illustrates secondary perturbing jets 142 and 140 disposed near a top portion of the fiber draw unit upstream of plenum chamber inlets 60 and 64. FIG. 18d represents yet another embodiment of the present invention that utilizes alternatingly augmented flow through Coanda nozzles 144 and 146 at an exit of tail pipe 56 to create turbulent air flow in the vicinity of tail pipe 56. Additionally, FIG. 18e illustrates Coanda-like nozzles 190 and 192 disposed at mid portion 54 of the fiber draw unit. Finally, FIG. 18f illustrates jets at inlet portions 48 and 50 of the fiber draw unit. Each of those jets illustrated in FIGS. 18a through 18f may alternatingly perturb air flow through the fiber draw unit in addition to any perturbation which may be implemented upstream of the jets. Additionally, each of the jets illustrated in FIGS. 18a-18f may also be implemented without additional perturbation means upstream therefrom.
FIG. 19 represents yet another embodiment of the present invention. The alternatingly augmented pressure in plenum chambers 147 and 150 may be provided by transducers 148 and 152 via inlets 150 and 154, respectively. Transducers 148 and 152 are preferably actuated by means of an electrical signal. For example, the transducers may actually be large speakers which receive an electrical signal to activate 0� to 180� out of phase in order to provide the alternating augmented pressures in plenum chambers 147 and 150. However, any type of appropriate transducer may create an augmented air flow by using any means of actuation. This may include but is not limited to electromagnetic means, hydraulic means, pneumatic means or mechanical means.
FIGS. 20a and 20b illustrate yet another embodiment of the present invention wherein hot and cold jets are alternatingly used to increase fiber crimp. Referring to FIG. 20a, fiber draw unit 69 includes secondary perturbation jets 156 and 158. Oscillatory jet 156 supplies hot air whereas oscillatory air jet 158 supplies cold air. Alternatively, FIG. 20b illustrates perturbation air jets 164, 166, which alternatingly supply hot air to the primary air flow and fiber bundle exiting from the tail pipe of the fiber draw unit. Both FIGS. 20a and 20b illustrate the fiber bundle deflection upon application of secondary perturbation. This secondary perturbation creates fiber bundle deflection and heating or cooling effects which lead to added crimp of the fibers being distributed within a web on an endless belt. The temperature varied perturbation provides for additional parameters which may be varied and controlled during production. The jets may be symmetrically or asymmetrically oriented to achieve desired fiber characteristics, namely fiber crimp. As with perturbation frequency and amplitude, the temperature of the air may be controlled without interruption of the production process, although this control is more complex. Thus, materials having different properties can be made without requiring the line to be substantially delayed and without the need for additional equipment. This technique may be applied to processes utilizing the homopolymer fibers as well as to multi-component fibers and materials.
FIGS. 21(a) through 21(d) represent yet another embodiment of the present invention, wherein a standard fiber draw unit includes secondary perturbation jets at an exit of the tail pipe thereof wherein at least one bank of perturbation jets is rotated with respect to the machine direction to create a crimp or fiber movement in a cross direction with respect to travel of the belt within the fiber draw unit apparatus to increase tensile strength in the cross direction of the non-woven web. For example, as shown in FIG. 21(a), jet bank 162 is disposed at an angle with respect to the machine direction while jet bank 160 is essentially parallel to the machine direction. FIG. 21(b) illustrates jet banks 202 and 200 which are both disposed at an angle with respect to the machine direction but oppose one another. Furthermore, FIG. 21(c) illustrates yet another configuration for jet orientation. There, jet banks 202 and 204 are each rotated with respect to the machine direction and face in the same direction. Finally, FIG. 21(d) illustrates opposing jet banks 208 and 210.
Finally, FIG. 15 illustrates the peak load of a non-woven web sample as a function of perturbation frequency of secondary perturbation jets for the embodiment utilized in Example 6. As is illustrated in the chart, machine direction strength of the non-woven web increases with increasing perturbation frequency. In the process run used to generate the data for FIG. 15, the direction of perturbation was parallel to the machine direction, as illustrated in FIG. 21(d). Furthermore, by varying the direction of the perturbation jets or airstreams relative to the machine direction, it is possible to increase cross-direction strength.
The following examples show the application of the techniques of the present invention to the production of fibers and non-woven webs in the spunbond process. The processes and apparati are described using terms and units well known in the prior art. The initial example describes fibers and a web formed using prior art techniques to provide a basis for comparison for fibers and webs formed using the techniques of the present invention.
The following examples show the application of perturbing airflows to the spunbond process. In this particular example, the perturbing airflows were applied to the air stream carrying the fibers at the exit of the fiber draw unit (FDU), which corresponds to the embodiment shown in FIG. 21(d). However, as was previously described, the process is equally applicable to perturbing the airflow in the FDU itself, or by application of auxiliary air, or bleeding airflow, at the manifolds prior to the FDU.
Process Conditions
FDU Draw Pressure:
4 psi
Draw unit width=14"
Polymer Throughput:
Polymer: 3445 Polypropylene*
*Exxon brand 3445 polymer, peroxide coated
Melt Temperature: 430� F.
Auxiliary Flow: 40 scfm
Basis Weight: 0.5 osy (17 gsm)
Test Results
TABLE 6-1______________________________________Perturbation Frequency 0 67 227 338 463Hz______________________________________MD Peak Load (lb) 0.921 1.687 1.844 2.108 2.452CD Peak Load (lb) 0.824 0.645 0.462 0.586 0.521MD Elongation (%) 23.85 52.79 18.03 11.08 23.05CD Elongation (%) 60.84 46.5 42.31 38.76 57.10Total Tensile 1.24 1.81 1.90 2.19 2.51(MD2 + CD2)1/2______________________________________
As can be seen from the Table, the use of perturbing airflows in the spunbond process provides substantially increased MD strength (in this example, the perturbing airflows were aligned with the machine direction). As was the case with the melt-blown process with perturbed airflows, the CD strength remained relatively constant after a slight decrease. As the total tensile strength calculation indicates, however, the overall strength of the web is increased by the application of the perturbing airflows. Once again, as was demonstrated with the use of perturbation of airflow in the melt-blown process, the use of airflow perturbation provides for a range of selectable characteristics in the final web material, merely by adjusting the perturbation frequency. This ease of process control is not currently available in the spunbond art. Typically, to prepare spunbond web materials with varying properties, the processing equipment must be completely shut down and the process conditions changed, such as by changing the die or other substantial change to the equipment. Though the present invention does not preclude those processes, with the present process, such changes to the web material may be accomplished on the fly by merely changing the perturbation frequency while the other process conditions remain constant. This feature of the present invention allows for much greater flexibility and efficiency in the operation of spunbond equipment.
In this example, the spunbond process was adapted, using the techniques disclosed herein to provide for perturbing airflows disposed at the exit of the FDU. For the purposes of this example, the perturbing airflows were not disposed immediately opposite each other, as was the case in Example 6, but rather one bank of auxiliary air nozzles was directed parallel to the machine direction, while the other was directed at an angle with respect to the cross direction to provide a slight cross direction trajectory (as shown schematically in FIG. 21(a)).
Process Conditions
Fiber Draw Pressure: 9 psi
Polymer Throughput: 0.75 GHM
Basis Weight: 1.0 oz/yd2
Polymer: 3445 Polypropylene*
*Exxon brand 3445 polymer, peroxide coated
Melt Temperature: 450� F.
Auxiliary Air Flow: 75 scfm
Test Results
TABLE 7-1______________________________________Perturbation Frequency 0 115 195 338 500Hz______________________________________MD Peak Load (lb) 12.00 19.96 21.00 21.13 20.00MD Elongation (%) 34.75 37.36 38.36 39.77 37.48CD Peak Load (lb) 8.965 11.30 10.53 10.34 12.69CD Elongation (%) 40.10 49.78 52.84 43.18 47.94______________________________________
Once again, it can be seen that by simply varying the perturbation frequency of the airflow, a variety of changes can be effectuated in the final non-woven web. Thus, to the extent that a material having different characteristics is desired, varying the perturbation frequency of the perturbing airflow can result in substantial changes in the final non-woven material. This change represents a substantial departure from prior art spunbond techniques in which other process conditions, which are much more difficult to achieve, must be varied to vary the characteristics of the final material.
As is seen from the above Examples 1-7 of meltblown, coform and spunbond non-wovens made in accordance with the present invention, the techniques of the present invention allow for the formation of a non-woven webs of various characteristics with relatively simple adjustments to process controls. While some of the differences can be attributed to the lay-down of the fibers on the forming surface, preliminary investigation indicates that the present inventive techniques also result in fundamental changes to the fibers formed thereby. Referring now to FIGS. 22 and 23, there are shown X-Ray diffraction scans of a meltblown fiber made according to prior art techniques (FIG. 22) and a meltblown fiber made in accordance with the present invention (FIG. 23) both otherwise under identical processing conditions and polymer type. As can be seen from comparison of FIGS. 22 and 23, the X-Ray scan of the meltblown fiber made with the inventive techniques has two peaks, while that of the prior art meltblown fiber has several peaks. It is believed that the differences observed in FIG. 23 result from the presence of smaller crystallites in the fiber, which possibly result from better quenching of the fiber during formation. In summary, these X-Ray diffraction scans indicate that the fibers made in accordance with the present technique are more amorphous than prior art fibers and may have a broader bonding window than fibers made in accordance with prior art techniques.
Additional evidence of the believed characteristic differences between fiber made in accordance with the present invention and those made in accordance with the prior art are shown in FIG. 24. FIG. 24 is a graph showing the results of a Differential Scanning Calorimetry (DSC) test conducted on a prior art meltblown fiber (indicated by the dashed line on the graph) and with a fiber made in accordance with the present techniques (the solid line). The test basically observes the absorbance or emission of heat from the sample while the sample is heated. As can be seen from FIG. 24, the DSC scan of the prior art fiber is significantly different from that of the present fiber. A comparison of DSC scans shows two main features in the present fiber that do not appear in the prior art fiber: (1) heat is given off from 80�-110� C. (apparent exotherm) and (2) a double melting peak. It is believed that these DSC results confirm that the present formation techniques produce fibers having significant differences from fibers produced with prior art techniques. Once again, it is believed that these differences relate to crystalline structure and quenching of the fiber during formation.
While preferred embodiments of the present invention have been described in the foregoing detailed description, the invention is capable of numerous modifications, substitutions, additions and deletions from the embodiments described above without departing from the scope of the following claims. For example, the teachings of the present application could be applied to the atomizing of liquids into a mist (or entraining a liquid in a fluid flow such as air). An apparatus for entraining such liquids is very similar, in cross section, to the melt-blown apparatus shown in FIGS. 6A-6D. In this embodiment, the apparatus simply would not have the typical melt-blown width of several inches to several feet. Additionally, the components of an atomizer would typically be several orders of magnitude smaller. In any event, the perturbation techniques in an atomizing embodiment provide for narrow droplet size distribution and more even distribution of the small liquid droplets in the entraining air flow. This embodiment could be employed in many applications such as creating fuel/air mixtures for engines, improved paint sprayers, improved pesticide applicators, or in any application in which a liquid is entrained in an airflow and an even distribution of the liquid and narrow particle size distribution in the airflow is desired.
|Cited Patent
|Filing date
|Publication date
|Jun 14, 1924
|May 3, 1932
|Du Pont Rayon Co
|Process and apparatus for the manufacture of artificial filaments
|Sep 4, 1929
|Dec 22, 1936
|Celanese Corp
|Production of artificial filaments, yarns, or threads
|Mar 16, 1946
|Nov 6, 1951
|Johns Manville
|Method of forming a multilayered mat of intercrossed filaments
|Mar 10, 1958
|Sep 27, 1960
|Du Pont
|Process for producing shaped articles using sonic vibrations to enhance solidification
|May 27, 1958
|May 2, 1961
|Reeves Bros Inc
|Molded diaphragm of non-woven material
|May 7, 1959
|Oct 30, 1962
|Schweizerische Viscose
|Process for producing synthetic bast of linear polymeric thermoplastic material
|Feb 4, 1958
|Nov 12, 1963
|Courtaulds Ltd
|Production of yarns of irregular denier
|Feb 24, 1961
|Sep 21, 1965
|Owens Corning Fiberglass Corp
|Method and apparatus for producing fibers
|Jul 2, 1962
|Nov 1, 1966
|Saint Gobain
|Apparatus for the production of fibers from organic or inorganic thermoplastic materials
|Nov 22, 1966
|Apr 8, 1969
|Hans Heinrich Wilhelm Hench
|Apparatus for producing strands or granules from liquid material
|Feb 25, 1966
|Apr 15, 1969
|Phillips Petroleum Co
|Filament crimping method
|Dec 29, 1967
|May 6, 1969
|Perry Walter Merton
|Method and apparatus for conveying and for treating glass fibers
|Mar 1, 1967
|May 20, 1969
|Polovets Lidia Mikhailovna
|Shaft for the air flow cooling of fibers spun from a polymeric melt
|Feb 6, 1967
|Apr 28, 1970
|Freudenberg Carl Kg
|Non-woven fabric
|Mar 4, 1969
|Mar 9, 1971
|R & H Molding Inc
|Turbine driven pulsating device
|Aug 8, 1969
|Oct 26, 1971
|Kimberly Clark Co
|Method and apparatus for crosslaying web materials
|Nov 24, 1969
|May 16, 1972
|British Iron And Steel Ass The
|Treatment of molten material
|Jul 18, 1969
|Aug 8, 1972
|Kimberly Clark Co
|Method and apparatus for bias crosslaying a fiber web
|Oct 28, 1971
|Apr 9, 1974
|Todoroki Ind
|Method of manufacturing bulky yarns
|Sep 29, 1972
|Apr 9, 1974
|Asahi Chemical Ind
|Apparatus for producing non-woven fleeces
|Apr 10, 1972
|Jul 23, 1974
|Exxon Research Engineering Co
|Melt-blowing die using capillary tubes
|Jul 7, 1972
|Jul 23, 1974
|Exxon Research Engineering Co
|Melt-blowing die for producing nonwoven mats
|Feb 11, 1974
|Nov 18, 1975
|Jeffers Albert L
|Filament forming apparatus with sweep fluid channel surrounding spinning needle
|May 23, 1974
|May 4, 1976
|Beloit Corporation
|Melt blowing apparatus with parallel air stream fiber attenuation
|Apr 29, 1975
|Jun 29, 1976
|Monsanto Company
|Method and apparatus for charging a bundle of filaments
|Apr 24, 1974
|Jul 20, 1976
|Beloit Corporation
|Twin triple chambered gas distribution system for melt blown microfiber production
|Jul 28, 1975
|Dec 28, 1976
|Barmag Barmer Maschinenfabrik Aktiengesellschaft
|Spinning apparatus with pneumatic filament conveyor tube
|Sep 20, 1974
|Jan 18, 1977
|Baumgartner Papiers S.A.
|Stabilization of tows of filamentary material
|Mar 6, 1975
|Apr 5, 1977
|Saint-Gobain Industries
|Method and apparatus for forming fibers by toration
|Aug 17, 1976
|Nov 22, 1977
|Pavel Mikhailovich Movshovich
|Distributing device for supplying compressed air to chambers of apparatus for making self-twisted product
|Apr 19, 1976
|Jan 24, 1978
|Kimberly-Clark Corporation
|Method of producing a soft, nonwoven web
|Jan 25, 1977
|Jul 25, 1978
|Saint-Gobain Industries
|Method and apparatus for making fibers from thermoplastic materials
|Aug 31, 1977
|Sep 12, 1978
|Saint-Gobain Industries
|Fiberization energy conservation
|Apr 14, 1976
|Oct 3, 1978
|Saint-Gobain Industries
|Method and apparatus for fiberizing attenuable materials and product thereof
|Apr 5, 1977
|Oct 31, 1978
|Saint-Gobain Industries
|Apparatus for forming fibers by toration
|Sep 19, 1977
|Jan 30, 1979
|Saint-Gobain Industries
|Method and apparatus for making fibers from attenuable materials
|Apr 17, 1978
|Mar 27, 1979
|Marcel Levecque
|Fiber formation by use of gas blast attenuation
|Sep 19, 1977
|Jun 26, 1979
|Saint-Gobain Industries
|Method and apparatus for forming fibers by gas blast attenuation
|Jul 12, 1978
|Jan 29, 1980
|Nippon Sheet Glass Co.,Ltd.
|Method for producing fibers from heat-softening materials
|Oct 31, 1977
|Jul 8, 1980
|Montedison S.P.A.
|Process for producing synthetic fibers for use in paper-making
|Aug 20, 1979
|Aug 25, 1981
|Crown Zellerbach Corporation
|System and method for dispersing filaments
|Sep 25, 1980
|Feb 23, 1982
|Owens-Corning Fiberglas Corporation
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|Feb 22, 1983
|Kimberly-Clark Corporation
|Nonwoven laminate for recreation fabric
|Apr 8, 1980
|Apr 19, 1983
|Schwarz Eckhard C A
|Apparatus and process for melt-blowing a fiberforming thermoplastic polymer and product produced thereby
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|Apr 24, 1984
|The Dow Chemical Company
|Process and apparatus for preparing uniform size polymer beads
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|Sep 18, 1984
|Bayer Aktiengesellschaft
|Process for production of synthetic fibers
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|Oct 23, 1984
|Devall Donald L
|Rotary valve
|Nov 17, 1982
|Jul 2, 1985
|Kimberly-Clark Corporation
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|Aug 8, 1985
|Nov 11, 1986
|Surgikos, Inc.
|Nonwoven medical fabric
|Aug 23, 1984
|Nov 18, 1986
|The Dow Chemical Company
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|Feb 17, 1987
|Essex Industries, Inc.
|Gas flow control valve
|May 13, 1985
|May 19, 1987
|The Dow Chemical Company
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|Sep 8, 1987
|Reifenhauser Gmbh & Co. Maschinenfabrik
|Apparatus for stretching the individual strands of a bundle of fibers or threads
|Nov 24, 1987
|Nov 29, 1988
|Windsor Jr John F
|Rotary pressure/purge valve
|Nov 20, 1987
|Apr 4, 1989
|Buehning Peter G
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|Jun 11, 1986
|Apr 4, 1989
|Kimberly-Clark Corporation
|Extrusion process using a central air jet
|Nov 20, 1986
|Apr 4, 1989
|J. H. Benecke, Ag
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|Nov 10, 1987
|Apr 11, 1989
|Reifenhauser Gmbh & Co. Maschinenfabrik
|Apparatus for making a spun-filament fleece
|Nov 20, 1986
|Jul 11, 1989
|J. H. Benecke, Ag
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|Feb 21, 1989
|Feb 12, 1991
|Nippon Petrochemicals Co., Ltd.
|Method of making cross-laminated stretched non-woven fabric
|Oct 11, 1990
|Dec 24, 1991
|Exxon Chemical Patents Inc.
|Method and apparatus for treating meltblown filaments
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|Jan 14, 1992
|Primary air system for a melt blown die apparatus
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|Meltblowing apparatus
|Aug 17, 1990
|Mar 24, 1992
|Reifenhauser Gmbh & Co. Maschinenfabrik
|Method of producing plastic fibers or filaments, preferably in conjunction with the formation of nonwoven fabric
|Nov 8, 1991
|Sep 1, 1992
|Kohler Co.
|Fluid pulse generating apparatus
|Sep 12, 1990
|Sep 22, 1992
|Fuji Photo Film Co., Ltd.
|Method and apparatus for delivering predetermined amounts of fluids
|Jul 18, 1991
|Nov 3, 1992
|Kimberly-Clark Corporation
|Apparatus for forming a nonwoven web
|Jul 11, 1990
|Nov 17, 1992
|Branson Ultaschall Niederlassung Der Emerson Technologies Gmbh & Co.
|Apparatus for pulverizing at least one jet of molten metal
|Jan 27, 1992
|Mar 23, 1993
|Kimberly-Clark Corporation
|Meltblown die head
|Sep 30, 1992
|Sep 7, 1993
|The United States Of America As Represented By The Secretary Of The Navy
|Rotary hydraulic servo or throttle valve
|Jul 23, 1992
|Sep 14, 1993
|E. I. Du Pont De Nemours And Company
|Quenching and coagulation of filaments in an ultrasonic field
|Jan 3, 1992
|Sep 14, 1993
|Kimberly-Clark Corporation
|Filaments, tow, and webs formed by hydraulic spinning
|Feb 19, 1993
|Sep 28, 1993
|Minnesota Mining And Manufacturing Company
|Method of making transparent film from multilayer blown microfibers
|Jul 31, 1992
|Nov 16, 1993
|Eastman Kodak Company
|Apparatus and method for spinning filaments
|Mar 12, 1990
|May 17, 1994
|Nippon Petrochemicals Co., Ltd.
|Non-woven fabric and method and apparatus for making the same
|Mar 29, 1993
|Oct 11, 1994
|Grant Benton H
|Pressurized diaphragm pump and directional flow controller therefor
|Apr 6, 1993
|Nov 15, 1994
|Kimberly-Clark Corporation
|Process for selectively absorbing oily contaminants
|Dec 8, 1993
|Apr 11, 1995
|The Board Of Regents Of The University Of Oklahoma
|Polymer processing using pulsating fluidic flow
|Nov 12, 1993
|Jul 25, 1995
|Reifenhauser Gmbh & Co. Maschinenfabrik
|Nozzle head for a meltblowing aparatus
|Jan 22, 1973
|Jul 25, 1974
|Werkzeuge Und Kunststoffteile
|Monofilament fibre blanket for non-wovens - with spinneret and/or conveyor being moved in a pre-set pattern during extrusion spinning
|May 4, 1990
|Nov 7, 1991
|Reifenhaeuser Masch
|Drawn filament wadding layer - has cooling and process air chambers in filaments path with controlled suction drawing
|May 10, 1990
|Nov 14, 1991
|Reifenhaeuser Masch
|Mfr. of spin-drawn synthetic fibre filament batt - has separate supplies for cooling air and for process fluid in drawing nozzle
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|Title not available
|"A Macroscopic View of the Melt-Blowing Process for Producing Microfibers," Robert L. Shambaugh, J&EC Research, 1988, 27. 23763, pp. 2363-2372.
|"Experimental Investigation of Oscillatory Jet-Flow Effects," M.F. Platzer, L.J. Deal, Jr. and W.S. Johnson, Naval Postgraduate School, Monterey, California, pp. 392-414.
|"Melt Blowing: General Equation Development and Experimental Verification," Marc A.J. Uyttendaele and Robert L. Shambaugh, AICHE Journal, Feb. 1990, vol. 36, No. 2, pp. 175-186.
|"The Manufacture of Continuous Polymeric Filaments by the Melt-Blowing Process," John C. Kayser and Robert L. Shambaugh, Polymer Engineering and Science, Mid-Oct. 1990, vol. 30, No. 19, pp. 1237-1251.
|A Macroscopic View of the Melt Blowing Process for Producing Microfibers, Robert L. Shambaugh, J&EC Research , 1988, 27. 23763, pp. 2363 2372.
|Experimental Investigation of Oscillatory Jet Flow Effects, M.F. Platzer, L.J. Deal, Jr. and W.S. Johnson, Naval Postgraduate School, Monterey, California, pp. 392 414.
|Melt Blowing: General Equation Development and Experimental Verification, Marc A.J. Uyttendaele and Robert L. Shambaugh, AICHE Journal, Feb. 1990, vol. 36, No. 2, pp. 175 186.
|The Manufacture of Continuous Polymeric Filaments by the Melt Blowing Process, John C. Kayser and Robert L. Shambaugh, Polymer Engineering and Science, Mid Oct. 1990, vol. 30, No. 19, pp. 1237 1251.
|Citing Patent
|Filing date
|Publication date
|Jan 23, 1997
|Mar 2, 1999
|Japan Vilene Company, Ltd
|Abrasive sheet made of very fine and ultrafine fibers
|Apr 12, 2000
|Jun 25, 2002
|Kimberly-Clark Worldwide, Inc.
|Methods of making fiber bundles and fibrous structures
|Oct 1, 1999
|Nov 26, 2002
|Kimberly-Clark Worldwide, Inc.
|Absorbent article with central pledget and deformation control
|Oct 1, 1999
|Dec 10, 2002
|Kimberly-Clark Worldwide, Inc.
|Center-fill absorbent article with a wicking barrier and central rising member
|Apr 12, 2000
|May 13, 2003
|Kimberly-Clark Worldwide, Inc.
|Absorbent articles with absorbent free-flowing particles and methods for producing the same
|Apr 16, 2001
|Aug 19, 2003
|3M Innovative Properties Company
|Fiber-forming process
|Dec 21, 2000
|Sep 2, 2003
|Kimberly-Clark Worldwide, Inc.
|Method of increasing the meltblown jet thermal core length via hot air entrainment
|Oct 1, 1999
|Sep 2, 2003
|Kimberly-Clark Worldwide, Inc.
|Absorbent articles with wicking barrier cuffs
|Oct 1, 1999
|Dec 9, 2003
|Kimberly-Clark Worldwide, Inc.
|Center-fill absorbent article with a central rising member
|Nov 20, 2000
|Dec 23, 2003
|3M Innovative Properties Company
|Fibrous nonwoven webs
|Apr 12, 2000
|Dec 23, 2003
|Kimberly-Clark Worldwide, Inc.
|Absorbent articles with nits and free-flowing particles
|Nov 8, 2002
|Jan 13, 2004
|Kimberly-Clark Worldwide, Inc.
|Center-fill absorbent article with a wicking barrier and central rising member
|Jun 27, 2000
|Feb 10, 2004
|Uni-Charm Corporation
|Elastically stretchable nonwoven fabric and process for making the same
|Oct 31, 2002
|Feb 10, 2004
|Kimberly-Clark Worldwide, Inc.
|Absorbent article with central pledget and deformation control
|Nov 27, 2002
|Feb 24, 2004
|Kimberly-Clark Worldwide, Inc.
|Absorbent article having good body fit under dynamic conditions
|Oct 1, 1999
|Mar 2, 2004
|Kimberly-Clark Worldwide, Inc.
|Absorbent article with unitary absorbent layer for center fill performance
|Oct 1, 1999
|Jul 20, 2004
|Kimberly-Clark Worldwide, Inc.
|Center-fill absorbent article with reusable frame member
|Feb 19, 2003
|Nov 30, 2004
|3M Innovative Properties Company
|Fiber-forming apparatus
|Jun 20, 2002
|Mar 1, 2005
|3M Innovative Properties Company
|Attenuating fluid manifold for meltblowing die
|Jul 24, 2001
|May 3, 2005
|Firma Carl Freudenberg
|Method and device for producing a spunbonded nonwoven fabric
|Mar 11, 2002
|May 10, 2005
|Uni-Charm Corporation
|Elastically stretchable nonwoven fabric and process for making the same
|Dec 22, 2003
|Dec 19, 2006
|Kimberly-Clark Worldwide, Inc
|Die for producing meltblown multicomponent fibers and meltblown nonwoven fabrics
|Dec 17, 2004
|Mar 20, 2007
|Firma Carl Freudenberg
|Method and device for producing a spunbonded nonwoven fabric
|Dec 31, 2003
|Aug 21, 2007
|Kimberly-Clark Worldwide, Inc.
|Strong high loft low density nonwoven webs and laminates thereof
|Sep 10, 2004
|Nov 6, 2007
|Kimberly-Clark Worldwide, Inc.
|High loft low density nonwoven webs of crimped filaments and methods of making same
|Sep 3, 2004
|Dec 30, 2008
|3M Innovative Properties Company
|Method for forming spread nonwoven webs
|Mar 19, 2007
|Aug 21, 2012
|Conrad John H
|Method and apparatus for enhanced fiber bundle dispersion with a divergent fiber draw unit
|Jul 24, 2001
|Apr 18, 2002
|Engelbert Locher
|Method and device for producing a spunbonded nonwoven fabric
|Mar 11, 2002
|Sep 12, 2002
|Toshio Kobayashi
|Elastically stretchable nonwoven fabric and process for making the same
|May 20, 2002
|Jan 2, 2003
|3M Innovative Properties Company
|Method for forming spread nonwoven webs
|Dec 21, 2001
|Jun 26, 2003
|Polanco Braulio A.
|High loft low density nonwoven webs of crimped filaments and methods of making same
|Feb 19, 2003
|Aug 7, 2003
|3M Innovative Properties
|Fiber-forming apparatus
|Feb 19, 2003
|Aug 28, 2003
|3M Innovative Properties
|Fiber products
|Jun 20, 2002
|Dec 25, 2003
|3M Innovative Properties Company
|Attenuating fluid manifold for meltblowing die
|Sep 12, 2003
|Mar 18, 2004
|Hamilton Wendy L.
|Absorbent articles with nits and free-flowing particles
|Sep 15, 2003
|May 27, 2004
|Fung-Jou Chen
|Absorbent article with center fill performance
|Dec 5, 2003
|Jun 17, 2004
|3M Innovative Properties Company
|Fibrous nonwoven webs
|Dec 31, 2003
|Oct 7, 2004
|Polanco Braulio A.
|High loft low density nonwoven webs of crimped filaments and methods of making same
|Dec 31, 2003
|Nov 11, 2004
|L. Warren Collier
|Strong high loft low density nonwoven webs and laminates thereof
|Sep 10, 2004
|May 12, 2005
|Polanco Braulio A.
|High loft low density nonwoven webs of crimped filaments and methods of making same
|Dec 17, 2004
|May 12, 2005
|Engelbert Locher
|Method and device for producing a spunbonded nonwoven fabric
|Dec 22, 2003
|Jun 23, 2005
|Kimberly-Clark Worldwide, Inc.
|Die for producing meltblown multicomponent fibers and meltblown nonwoven fabrics
|Sep 3, 2004
|Jun 30, 2005
|3M Innovative Properties Company
|Method for forming spread nonwoven webs
|Mar 19, 2007
|Sep 25, 2008
|Conrad John H
|Method and apparatus for enhanced fiber bundle dispersion with a divergent fiber draw unit
|Jun 27, 2000
|Jan 3, 2001
|Uni-Charm Corporation
|Elastically stretchable nonwoven fabric and process for making the same
|May 29, 2001
|Feb 6, 2002
|Carl Freudenberg KG
|Method and apparatus for making a spunbonded nonwoven
|Jan 19, 2002
|Aug 28, 2002
|Christian Heinrich Sandler GmbH & Co. KG
|Bulky structured melblown nonwoven web
|U.S. Classification
|425/72.2, 425/464, 264/211.14, 425/131.1, 425/140, 264/211.12
|International Classification
|Cooperative Classification
|European Classification
|Aug 2, 1995
Owner name: KIMBERLY-CLARK CORPORATION, WISCONSIN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LAU, JARK CHONG;HAYNES, BRYAN DAVID;REEL/FRAME:007601/0273
Effective date: 19950801
|Apr 21, 1997
Owner name: KIMBERLY-CLARK WORLDWIDE, INC., WISCONSIN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:KIMBERLY-CLARK CORPORATION;REEL/FRAME:008519/0919
Effective date: 19961130
|Jan 5, 1999
|Certificate of correction
|Jun 29, 2001
|Fee payment
Year of fee payment: 4
|Aug 17, 2005
|Maintenance fee reminder mailed
|Jan 27, 2006
|Lapse for failure to pay maintenance fees
|Mar 28, 2006
|Expired due to failure to pay maintenance fee
Effective date: 20060127


text:
Is Paula Abdul joining an updated Star Search?
She's not confirming it -- or denying it.
Check out hilarious photos of Idol judges before they were famous
"Once again, until you hear it from me, you can't believe what you read ;) Lots of love!" she Tweeted Tuesday.
Earlier this week, Entertainment Weekly reported that Abdul, 47, was "finalizing a deal" to star in a reboot of the 1980s-era talent competition, which was hosted by the late Ed McMahon.
See how Paula's wacky looks have changed
The show would premiere this summer and feature Abdul as a combination judge and host, EW.com reported. A rep for ABC did not comment.
Ellen DeGeneres replaced Abdul as a judge on American Idol this season.
Abdul was also rumored to compete on Dancing With the Stars, and be a judge on Simon Cowell's X Factor.
Check out amazing Idol makeovers
Britney Spears is among the stars who got their start on Star Search.

subset: commoncrawl


text:
Drake Bell cancels Jannus Live concert on March 18
Hope you enjoyed Wednesday night's Miranda "iCarly" Cosgrove show at the Tampa Theatre, because it's the last Nickelodeon-based pop concert this area will see for a while.
Drake Bell of Drake and Josh has canceled his March 18 concert at Jannus Live, alongside Emily Osment. Refunds are available at point of purchase.
In a brief, Kanye-style Facebook rant, Jannus Live noted: "BTW, to all the haters and pot-shot specialists: THE WHOLE TOUR WAS CANCELED. NOT JUST JANNUS. THE ENTIRE TOUR." Well then. Glas we cleared that up.
For now, all we know for sure is, if Soundcheck ever starts a dub-reggae band, it's definitely gonna be called Hater and the Pot-Shot Specialists. No question.
Click here for all the Drakey details.
-- Jay Cridlin, tbt*. Photo (2006): Getty Images.


text:
Today is Friday, Dec. 13, the 347th day of 2013 and the 83rd day of autumn.
Today is Friday, Dec. 13, the 347th day of 2013 and the 83rd day of autumn.
TODAY'S HISTORY: In 1577, Sir Francis Drake left England on a three-year voyage around the world.
In 1972, American astronauts Eugene Cernan and Harrison Schmitt began the third and final lunar excursion of the Apollo 17 mission. They remain the most recent humans to set foot on the moon.
In 2002, Cardinal Bernard Law resigned as archbishop of Boston following sex abuse scandals in the archdiocese.
In 2003, former Iraqi President Saddam Hussein was captured by U.S. military forces in a small underground hideout near Tikrit, Iraq.
TODAY'S BIRTHDAYS: Heinrich Heine (1797-1856), poet; Mary Todd Lincoln (1818-1882), first lady; Dick Van Dyke (1925- ), actor; Christopher Plummer (1929- ), actor; Ted Nugent (1948- ), singer-songwriter; Steve Buscemi (1957- ), actor; Rex and Rob Ryan (1962- ), football coaches; Mike Tirico (1966- ), sportscaster; Jamie Foxx (1967- ), actor; Sergei Fedorov (1969- ), hockey player; B.J. Penn (1978- ), mixed martial artist; Taylor Swift (1989- ), singer-songwriter.
TODAY'S FACT: Jamie Foxx is one of five performers to have both a Billboard No. 1 single and an Oscar win. The others are Barbara Steisand, Cher, Frank Sinatra and Bing Crosby.
TODAY'S SPORTS: In 2007, the "Mitchell Report" was released, indicating widespread steroid use in professional baseball and naming dozens of players involved.
TODAY'S QUOTE: "There are more fools in the world than there are people." — Heinrich Heine
TODAY'S NUMBER: 6 — Mary Todd Lincoln's age when her mother died. Abraham Lincoln's mother died when he was 9.
TODAY'S MOON: Between first quarter moon (Dec. 9) and full moon (Dec. 17).


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Experience a magical sail aboard one of our catamarans. A day trip or private charter aboard Blue Water Safaris will take you along our scenic coastline into a secluded cove where you'll marvel at our rich sea life, as you snorkel the clear blue turquoise water of St. Kitts.Details >
Welcome aboard the 78-foot Spirit of St. Kitts, or her sister ship the 67-foot Eagle, both luxurious catamarans. Share fun with new friends from around the world while for day or evening cruises with sailing, snorkeling, having a BBQ on the beach in Nevis.Details >
Your journey starts with a glass of Champagne as you step aboard "Minerva" our 50' sailing yacht.Details >
Speedy 4 Charters has been a leader in deep-sea fishing, snorkeling and sight seeing ventures for over 25 years. Their specialized crew consists of Certified Advanced Open Water Divers who will expertly help you experience the tranquil coastlines and diverse marine life.Details >
St.Kitts Water Sports is #1 water sports Center in the Caribbean. We have more tours and excursions than any other company, we do it all.Details >


text:
Related Products:
This coin captures the true essence of the Snake's personality, which is graceful and soft-spoken.
Coin Highlights:
- Contains 1 oz of .9999 Fine Silver.
- Packaged in an attractive Asian-inspired case - a perfect gift for those born in 2013 or a previous Year of the Snake.
- Mintage of only 28,888 coins.
- Obverse: Right-facing profile of Queen Elizabeth II.
- Reverse: The year and face value, along with a snake with Chinese text.
- Sovereign coin backed by the Canadian government.
The year 2013 is ruled by the Snake. The Year of the Snake also ruled 1905, 1917, 1929, 1941, 1953, 1965, 1977, 1989 and 2001. However, people born in January or February should consult the Chinese lunar calendar.
Add this 1 oz Silver $15 Lunar Snake coin to your cart today!
The Chinese New Year does not automatically fall on January 1st. This celebration is better known as the Spring Festival and coincides with the first day of spring - a date that shifts from year to year depending upon the lunar cycle and solar year.
About the Snake:
People born during the Year of the Snake have a hypnotic beauty and never give themselves totally away. The mysterious Snake is a strategic planner that has everyone guessing its next move. It will keep plotting until it gets what it wants. And when it does, it is not likely to let go. The Snake is a strong individual and is usually destined for great success. Does this sound like someone you know?
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