text:
|Publication number
|Publication type
|Application number
|Publication date
|Mar 11, 2003
|Filing date
|Mar 14, 2001
|Priority date
|Mar 14, 2001
|Fee status
|Also published as
|Publication number
|Mau-Song Chou, John C. Brock
|Original Assignee
|Trw Inc.
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (2), Non-Patent Citations (1), Referenced by (19), Classifications (6), Legal Events (7)
|External Links: USPTO, USPTO Assignment, Espacenet
1. Field of the Invention
This invention relates generally to a method for detecting trace gases in the air and, more particularly, to a method of radiating a chemical cloud to heat the cloud and increase its temperature relative to the background, and then detecting chemicals in the cloud by spectroscopy.
2. Discussion of the Related Art
It is known in the art to detect certain constituents in a chemical cloud in the air by spectral analysis of the molecules making up the cloud. This type of chemical detection has many applications, including detecting natural gas leaks from underground pipes, chemical clouds from chemical spills, volatile organic vapor (VOC) from chemical processes, pollution from smoke stacks and the like, military chemical warfare agents, and other toxic gases present in the air. Typically, this type of spectral analysis of a chemical cloud is performed remotely, sometimes up to 10-20 km away, because the constituents in the cloud may be toxic, and thus a threat to health, or it may not be possible to directly detect the chemical cloud. The distance the detecting instrument has to be from the cloud for this remote type of passive sensing depends on the particular application, and different systems exist for different applications.
To perform this type of detection and analysis, a spectrometer, such as a Fourier transform infrared (FTIR) spectrometer, is directed towards the chemical agent cloud from a remote location, so that it passively receives emissions therefrom. If the chemical cloud is warmer than the background, such as sky, mountains, or other terrain, along the field-of-view of the spectrometer, target molecules in the cloud will exhibit emissions having an energy greater than the background emissions from the sky. If the chemical cloud is the same temperature as the sky, the target molecules within the cloud are absorbing photons at the same rate that they are emitting photons, so that there is no net energy exchange between the cloud and the background, and no difference relative to the background. As the temperature of the cloud increases, more photons are released from the chemicals in the cloud, which are available to be received by the spectrometer.
The spectral display generated by the spectrometer from the emissions provides emission lines and bands at certain wavelengths that is indicative of the atoms and molecules in the cloud. Because each material has its own spectral "fingerprint" representative of its molecules, the detected spectral display can be compared to a known "fingerprint" of a particular chemical to determine if that chemical exists in the cloud.
A problem exists with the passive remote sensing techniques that are currently used in the art because the temperature difference between the chemical cloud and the sky is often very small. In many cases, the temperature of the cloud is only about 2-3� C. warmer than the temperature of the background. Because of such a small temperature difference, the detectable emissions from the cloud is typically very weak. This results in a poor signal-to-noise ratio, and thus poor detection sensitivity and possibly a high false alarm rate.
What is needed is a remote chemical detection system that causes the chemical cloud to be heated so that the temperature of the cloud is significantly different than the background. It is therefore an object of the present invention to provide a remote chemical detection system of this type.
In accordance with the teachings of the present invention, a technique for the remote detection and analysis of trace chemicals in the air is disclosed. A beam of electromagnetic radiation from an electromagnetic radiation source is used to radiate a suspected chemical cloud. The radiation energy that is absorbed by the cloud is quickly thermalized due to a rapid collision energy transfer between the molecules that absorb the radiation and the surrounding air molecules. This collisional energy redistribution will result in heating the chemicals in the cloud. An increase in the temperature of the cloud will increase the emission intensity of the molecules against the background, resulting in an improvement in the detection of the chemicals.
A tracking telescope is then used to collect the thermal emissions of the target molecules generated by the radiation. The tracking telescope can be located in the vicinity of the electromagnetic radiation source such that the viewing axis of the telescope is preferably coaxial with the propagation direction of the electromagnetic radiation. A spectrometer, such as an FTIR spectrometer, is used to resolve the emissions from the cloud that are enhanced by the radiation and to generate an emissions spectrum. The emissions spectrum is used to identify suspect molecules in the cloud by comparing the detected emissions to the known "fingerprint" vibrational spectrum of the suspect molecules.
The electromagnetic radiation source, telescope and FTIR spectrometer can be housed on a platform to scan over a wide area for surveillance of chemical clouds. Alternatively, the tracking telescope and the FTIR spectrometer can be located at a separate location from that of the electromagnetic radiation source. The viewing axis of the telescope will intersect with the beam of the electromagnetic beam. In this arrangement the location of the chemical cloud can be determined based on the intersection of the electromagnetic radiation beam and the view axis of the telescope.
The electromagnetic radiation can be microwave, millimeter wave, infrared, visible, or ultraviolet radiation. The wavelength of the electromagnetic radiation can be selected to be in resonance with the absorption lines of the chemicals, or of water vapor or oxygen molecules that are commonly present in the cloud. If the wavelength of the electromagnetic radiation is chosen to be in resonance with the absorption lines of the target chemical molecules, the returned emission intensity, as a function of the excitation wavelength, can be used to provide an increased discrimination of the chemicals against possible interference background chemicals.
Additional objects, features and advantages of the present invention will become apparent from the following description and appended claims taken in conjunction with the accompanying drawings.
FIG. 1 is a plan view of a remote spectral analysis sensing system, according to a preferred embodiment of the present invention;
FIGS. 2(a)-2(d) show the spectral footprint of four different chemical agents; and
FIG. 3 is a graph with wavelength on the horizontal axis and the absorption of the agent VX and output intensity of a CO2 laser on the vertical axis showing the overlapping of a CO2 laser with absorption spectrum of the agent VX;
FIG. 4 is a graph with wavelength on the horizontal axis and absorption on the vertical axis showing absorption spectrum of sarin relative to a CO2 laser tuning range; and
FIG. 5 is a graph with frequency on the horizontal axis and absorption coefficient on the vertical axis showing microwave absorption from atmospheric gases.
The following discussion of the preferred embodiments directed to a technique for the remote sensing of a chemical cloud is merely exemplary in nature, and is in no way intended to limit the invention or its applications or uses.
FIG. 1 is a plan view of a spectral sensing system 10, according to an embodiment of the present invention. The system 10 includes a radiation source 12, a telescope 14 and a spectrometer 16. The radiation source 12 can be any suitable laser or microwave source consistent with the discussion herein. The telescope 14 is a Newtonian type telescope, including a collecting mirror 18 for receiving radiation from a scene and a turning mirror 20. However, the telescope 14 can be any suitable telescope for receiving and focusing radiation from a scene consistent with the discussion herein. The spectrometer 16 can be any type of spectral detecting device that provides a spectral display over a predetermined spectrum, such as an FTIR spectrometer, an acousto-optic spectrometer, or a grating dispersed spectrometer. The source 12, telescope 14 and spectrometer 16 can be mounted within a suitable housing, and can be included on a platform capable for scanning over a wide area for increased surveillance. Additionally, the system 10 can be made compact and portable to be readily moved from place to place.
The radiation source 12 emits a radiation beam 22 towards a pair of turning mirrors 24 and 26 to align the beam 22 to be near co-linear with radiation received by the telescope 14 from the scene. The radiation beam 22 can be microwave, millimeter wave, infrared, visible or ultraviolet radiation, depending on the particular application and system being used, as will be discussed below. The radiation beam 22 is directed towards a suspected chemical cloud 28 to excite molecules within the cloud 28 to cause heat to be generated to increase the cloud's temperature relative to the background, usually sky, mountains or other terrain. In alternate embodiments, the radiation beam 22 can be directed towards the cloud 28 in a manner that is not co-linear with the emissions from the cloud 28. In this type of design, the location of the cloud 28 can also be determined as the intersection point between the radiation beam 22 and the field of view of the telescope 14.
The source 12 can be selected so that the wavelength of the radiation beam 22 is in resonance with a particular target molecule or molecules existing in the cloud being detected. The wavelength of the radiation beam 22 can also be selected to be in resonance with the absorption lines of water vapor or oxygen molecules commonly present in air. The resonance causes the target molecules, water vapor or oxygen molecules to rotate or vibrate which causes their energy to increase. Also, electrical transistions may occur in the molecules. The radiation energy absorbed by the water vapor, the oxygen molecules or the target molecules in the cloud 28 is thermalized due to collision energy transfer causing inter-molecular relaxation. At atmospheric pressure, this thermalization is very rapid. This collisional energy redistribution results in heating the molecules in the cloud 28. An increase in the temperature of the cloud 28 will increase the emission intensity of the molecules in the cloud against the background, resulting in an improved detection of the molecules. If the wavelength of the electromagnetic radiation is chosen to be in resonance with the absorption lines of the target molecules, the returned emission intensity, as a function of the excitation wavelength, can be used to provide an additional way for discrimination against possible interference background chemicals. This is because the returned emission intensity from the target molecules should increase substantially as the excitation is tuned to the resonance absorption lines of the target molecules. In the contrast, the emission intensity from background chemicals should not increase appreciably at these excitation wavelengths.
The telescope 14 collects thermal emission returned from the cloud 28. The spectral content of the emission is then analyzed by the spectrometer 16. The emission spectrum, typical in the 8-14 micron region, is used to identify the molecules in the cloud 28 by comparing the detected emissions to the known "fingerprint" vibrational spectrum of predetermined molecules. Alternatively, an imaging spectrometer, such as a hyperspectrometer imager, can be used to obtain spatially resolved spectrum. The contrast from the spatially resolved spectrum can further be used to discriminate against any other interference background chemicals that may be present.
Several electromagnetic radiation sources, including infrared lasers, such as a CO2 laser and a DF laser, and microwaves may be used as the radiation source. The CO2 laser is a preferred excitation source for detection of chemical agent cloud. This is because several phosphonate-type chemical agents, including sarin (GB), soman (GD), tabun (GA) and VX, as shown in FIG. 2, have absorption bands in the 9-10 μ region that can be excited by a CO2 laser.
FIG. 3 illustrates some overlapping of CO2 laser lines with the absorption spectrum of agent VX. The upper curve shows the absorption spectrum of agent VX and the dots on the curve show the overlapping of the absorption curve with relatively strong 12CO2 laser lines. The lower curve shows the intensity distribution of a typical tuned 12CO2 laser. The strong peaks of the VX vapor can be excited by the p-branch of the 9.6-μm band or 10.6-μm band of a 12CO2 laser. A single strong CO2 laser line that overlaps with the strong absorption band may be employed for initial searching of the target chemicals. Further identification of target molecules can be achieved by comparing the returned emission at different CO2 laser lines against the "fingerprint" absorption spectrum of the target chemicals.
FIG. 4 shows another example of the overlapping of sarin (agent GB) with CO2 laser, including both isotopes of 12CO2 and 13CO2. This illustrates that strong absorption bands of the chemicals can be excited by a different isotope of a CO2 laser.
Table 1 shows an estimate of the power required for heating a GB vapor cloud by 10� C. This assumes that a CO2 laser is tuned near the peak absorption of the vapor, the concentration of the GB is assumed to be about 100 ppm in the air, the laser beam on the target cloud is about 5-cm diameter, and the duration of irradiation is about 1 second. Table 1 shows the required CO2 laser power is relatively low, about 28 W, mainly because of relatively strong absorption cross-sections of the phosphonate bands in the 9-10μ region. In addition, the range from the source to the target cloud can be quite long, exceeding more than 5 km, mainly because the air is practically transparent to the CO2 laser in the range of concern.
The DF laser, as well some HF lasers, may also be used as an excitation source. As shown in FIG. 2, many of the chemical agents have absorption bands near the region that overlap with either the DF or HF laser lines. Table 1 shows that the required DF laser for heating a GB vapor cloud of 100 ppm in the air by 10� C. is relatively mild, about 137 W for a duration of 1 second. The estimate again assumes the laser beam on the target cloud is about 5-cm diameter.
When CO2 lasers are used as an excitation source, strong scattered intensity from the CO2 laser may interfere with the FTIR spectral measurements. It is desirable to turn on the laser for a certain duration and then turn off the laser momentary during the FTIR spectral measurements. Although the CO2 laser is turned off momentary, the chemical cloud won't cool off immediately, as it takes some time to lose its heat to the surrounding air.
Microwave radiation may also be used to heat a chemical cloud. One convenient way is to heat the cloud via the excitation of the O2 or H2O vapor that is present in the cloud. The energy absorbed by O2 or H2O can be thermalized rapidly and heat the cloud. Hence, in this approach, a chemical cloud can be heated without prior knowledge of the constituents and their absorption spectra. FIG. 5 shows the absorption bands of O2 or H2O in air from about 15 GHz to 350 GHz. A FTIR spectrometer can be used to identify the chemical constituents by spectral analyzing the returned radiation in the infrared region from about 8 to 14 μm. A microwave source in conjunction with a spectrometer is like providing an "universal detector" capable of detecting various kinds of chemical vapor. However, a relatively high power microwave may be needed since a substantial fraction of the power is absorbed by the O2 or H2O vapor in transmission through the air before reaching the target.
An alternative way is to excite the chemicals directly by tuning the microwave frequency in resonance with the chemical absorption lines. The absorption coefficients for chemical warfare agents are generally not known too well. However, several of other molecules, such as H2S, SO2, and CH3I have been reported. See, for example, N. Gopalsami, S. Bakhtiari, A. C. Raptis, S. L. Dieckman, and DeLucia, "Millimeter-wave Measurements of Molecular Spectra with Application to Environmental Monitoring," IEEE Transactions on Instrumentation and Measurement, Vol. 45, p. 225-230, 1996.
Microwave or millimeter wave radiation has a very different spectral region than infrared radiation, which is the emissions range usually analyzed by the spectrometer 16. Therefore, minimal interference in the measurements from using microwave or millimeter wave radiation is expected. The spectral range of interest for analyzing the returned emissions is typically between 8-14 microns, where many chemical vapors, such as certain chemical agents, emit radiation.
Although the path between the cloud and the sensor unit is also heated, if the excitation via water vapor or oxygen absorption lines is chosen, the return emission is expected to have minimal absorption by the column of the heated air. This is because the absorption by air is quite weak in this spectral region of interest. Although there are weak CO2 absorption bands in the 8-14 micron region due to the hot-band absorption from the μ2 and 2μ2 levels of CO2, these bands are normally fairly weak near ambient temperature. It is anticipated that these absorption bands will not cause any serious interference of the returned signal in the spectral range of 8 to 14 μm of interest, if the temperature rise is kept below 10 to 20� C.
The required microwave power for the source 12 depends upon the necessary temperature difference between the cloud 28 and the background, the range of the cloud 28, and the absorption coefficient and concentration of the absorber. Table 1 shows an estimate of the required microwave power and range for heating a 100-ppm GB vapor cloud by 10� C., via absorption of O2 at about 60 GHz, H2O at 22.3 GHz, and GB vapor at 90 GHz, for a duration of 1 second. The absorption cross-section of O2 and H2O are from Ulaby, et al. The absorption cross section for GB is taking to be an average value of that of H2S, SO2, and CH3I cited in the above reference by Gopalsami, et al. It is assumed that the beam 22 can be focused to a spot size of 5-cm diameter at a 200 meter range and 10-cm diameter at a 5-km range, and that the source 12 is on for 1 second.
There are trade-offs among choice of different absorbers. It appears that O2 yields a relative low required power of about 16 kW mainly caused by relatively high absorption of O2 in the air. However, the range is likely limited to 200 m. On the other hands, H2O yields a substantially high required energy of about 270 kW, although the range can exceed 5 km. GB vapor may not be a good choice of absorber because of exceedingly high required microwave power. Of course, the required microwave power can be substantially reduced if the irradiation can be extended over a longer duration.
Required Laser of Microwave Power for Heating 100-ppm GB chemical Cloud by 10� for 1 second duration
Excitation source
CO2 laser
DF laser
˜9.6 micron
˜3.58 micron
˜60 GHz
˜22.3 GHz
˜90 GHz
Absorbing medium
GB vapor cloud
GB vapor cloud
Watervapor(30% H2O)
GB vapor cloud
Cross section, cm2
3.4 � 10−18
0.7 � 10−18
4.9 � 10−24
1.9 � 10−24
1.0 � 10−21
Beam diameter
5 cm
5 cm
5 cm
10 cm
10 cm
0-5 Km
0-5 Km
0-200 m
0-5 Km
0-5 Km
Required Power
One article has investigated the relationship between improvements in detection sensitivity and the temperature difference between the target vapor cloud and the background temperature. See T. C. Gruber and J. Ditillo, "Quality assurance measurements for passive FTIR data collection," AAPCA Specialty Conference Proceedings SP Optical Remote Sensing for Environmental and Process Monitoring Proceedings of the 1995 Specialty Conference, Sep. 25-27, 1995. The quality in the returned emission spectrum was expressed as a "score". For temperatures closer to or below 2� C., the score is practically zero. Once the temperature passes a threshold value of ˜2� C., the score increases markedly with increasing temperature difference. Hence, an increase in the temperature difference by 10� C. or higher, by means of the laser or microwave heating, provides an improvement in the sensitivity of detecting these molecules substantially.
The foregoing discussion discloses and describes merely exemplary embodiments of the present invention. One skilled in the art will readily recognize from such discussion, and from the accompanying drawings and claims, that various changes, modifications and variations can be made therein without departing from the spirit and scope of the invention as defined in the following claims.
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|Filing date
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|System and method for remote detection and identification of chemical species by laser initiated nonresonant infrared spectroscopy
|Stephen L. Dieckman et al. "Millimiter-Wave Measurements of Molecular Spectra with Application to Environmental Monitoring", IEEE Transactions on Instrumentation and Measurement, vol. 45, No. 1, Feb. 1996 pp. 225-320.
|Citing Patent
|Filing date
|Publication date
|Nov 24, 2003
|Jan 24, 2006
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|Apr 11, 2006
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|Feb 27, 2007
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|Sep 14, 2005
|Sep 18, 2007
|Northrop Grumman Corporation
|Laser desorption and thermal emission spectroscopy for chemical analysis of cryogenic surfaces
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|Sep 16, 2008
|Celight, Inc.
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|Jan 18, 2011
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|May 6, 2004
|Eastman Kodak Company
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|Dec 23, 2004
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|Dec 30, 2004
|Lasen, Inc.
|Aerial leak detector
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|Mar 17, 2005
|Northrop Grumman Corporation
|Detection and analysis of chemical and biological materials by passive emission of terahertz wave against a cold background target
|Nov 24, 2003
|May 26, 2005
|Boright Arthur L.
|Cloud cover assessment: VNIR-SWIR
|Mar 31, 2004
|May 26, 2005
|Boright Arthur L.
|Sub-visible cloud cover assessment: VNIR-SWIR
|May 13, 2004
|May 26, 2005
|The Boeing Company
|Cloud shadow detection: VNIR-SWIR
|Jul 19, 2003
|Sep 22, 2005
|Hafendorfer James T
|Blower support device for utility vehicle
|Sep 14, 2005
|Mar 15, 2007
|Northrop Grumman Corporation
|Laser desorption and thermal emission spectroscopy for chemical analysis of cryogenic surfaces
|Nov 21, 2006
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|Celight, Inc.
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|Naoki Oda
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|Detection and analysis of chemical and biological aerosols
|U.S. Classification
|250/339.08, 250/341.6
|International Classification
|Cooperative Classification
|European Classification
|Mar 14, 2001
Owner name: TRW INC., CALIFORNIA
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20 April 2012
Photo: Corinne DubreuilHeart Award winner, Daniela Hantuchova (SVK)
Daniela Hantuchova of Slovak Republic and Sweden's Sofia Arvidsson were presented with their 2012 Fed Cup by BNP Paribas Heart Awards following the draw ceremonies at their Fed Cup play-off ties in Marbella and Boras on Friday.
The first four Heart Award recipients of 2012 were decided by a public vote on FedCup.com and FedCup.com/es that saw over 10,000 fans make their selection. Catalina Castano of Colombia and Li Na of China were the other two winners and will be presented with their awards at a later date. All four players will receive a silver Baccarat bracelet and a cheque to be donated to a chosen charity.
Hantuchova was recognised in the World Group and World Group II first round category, with two singles wins in Slovak Republic's World Group II first round win over France. She has donated her cheque for $6000 to the children's ward of her hometown hospital in Poprad.
Hantuchova said: "It's something very special to me. Awards like this mean more than any trophy I have because it's for the fans and that's what you play tennis for. Because the match was played in Slovakia, the cheque is going to my home city where I was born in Poprad to the hospital for the kids department."
Arvidsson won the Heart Award for Europe/Africa Zone Group I after remaining unbeaten in singles and doubles to help Sweden qualify for the World Group II play-offs. She has donated a her cheque for $1000 to the cancer charity Barncancer Fonden.
She said: "It means a lot. One of my first awards and a great honour. I should share it with my team because they made me play well and I had so much fun playing Fed Cup. I really like it.
"The cheque is for research for kids with cancer. After Fed Cup, I had a hitting partner in Memphis and he had to go home because his godson was dying of cancer. He was only four years old and he passed away. I hope this can do some good for them."
Juan Briz, Head of Brand and Communication of BNP Paribas in Spain, who presnted the cheque to Hantuchova, said: "The level of passion and excitement for Fed Cup by BNP Paribas has grown considerably during recent years, and this is embodied in the commitment of players such as Daniela Hantuchova. By supporting this Heart Award initiative, which combines social engagement with the promotion of women's tennis, we develop both our active partnership policy with tennis and our social responsibility policies."
ITF President Francesco Ricci Bitti said: "There were some outstanding performances during the Fed Cup ties in February so I'd like to congratulate Daniela, Sofia, Catalina and Li Na for coming out on top of the public vote. The Fed Cup by BNP Paribas Heart Award continues to reward players for the commitment they make to their team and the competition as a whole. I'm sure the four winners will now take great pride in making their donations to charity."
Daniela Hantuchova (SVK) - 20/04/2012
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Altek 211 RTD Calibrator
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Mid-century modern design interpreted with an industrial edge. Such is the modis operandi of Gus* Modern. Every accessory, sofa, sectional, chair and table they design is inspired by simple forms and honest materials. The resulting modern furniture pieces are clean, elegant and versatile, with crisply tailored upholstery and solid, eco-friendly FSC-certified wood frames. Founded in 2000, Gus* Modern is based in Toronto, Ontario, Canada.
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I blame guns.
Most people are too pssy to drink bleach, hang themselves or jump off a building. Guns make it too easy.
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rappers are this soft now...I blame feminism
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Survival of the fittest, the weakest weeding themselves out.
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What Dwells Within Us.....
"Freddy E" is beyond pain, he won't have to be accountable for this act, but for those left behind someone has to be held responsible because not knowing why he did this is simply one of the most painful feelings there is. Freddy E is the one to blame for all of this since it was his life that he decided to end.
I had a good friend take his life a few years ago. I was chilling with another buddy when I got the call. It felt like someone hit me over the head with a sledge hammer. I couldn't breathe, I didn't know if I should stand or sit and I felt nauseous. A numbness washed over me and I felt very light headed. I jetted from my boy's and just walked into the night air. He was gone and not all of the tears in the world would bring him back. For the rest of the week all I could do was think about him alone in his garage with the rope, the decision having already been made. Sliding it around his neck knowing there was no going back and then finally taking that final plunge. Apparently his fingers were broken because at the last second he changed his mind.
His kids arrived home from school to find their dad dead that day, their screams of utter terror awoke his brother who was in the same house with him asleep.
There was no note, no reason WHY!?!?!?!?!?!?!?!?!?!?!?! No reason why, no F'ing reason!!!!!!!!!!!! But as the days passed I learned more of the friend I thought was so buoyant and outgoing. I learned that he was chronically depressed and withdrawn, most days. I learned that his mental state had deteriorated to such a degree that the raw effect his death would have on those he left behind had no meaning. I learned that what I was seeing was a facade hiding a broken and cowardly man.
The ones left behind are always the ones that suffer the worst. You can't save someone that really wants to kill them self because they will find a method and an opportunity. Society can't fix people that don't want to be fixed and it equally can't save someone if they choose the ultimate way out. People are deeper than they appear out in public and the key is asking questions and looking for what dwells within.
Last edited by Slip Stream; 01-08-2013 at 01:29 AM. Reason: Clarity....
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and now she's probably getting dicked down by a well hung Mexican.
He killed himself for nothing
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This review is from: CHENBRO RM42300-F 1.2 mm SGCC 4U Rackmount Server Case 3 External 5.25" Drive Bays
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Practicing Barbecue Safety
Practicing Barbecue Safety
Posted 6/17/2010 Updated 6/17/2010
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by Peter Blackburn
66th Air Base Wing Public Affairs
6/17/2010 -
HANSCOM AFB, Mass.
-- Summer officially gets under way on June 21 and, as always, it brings barbecuing season with it. As cookouts heat up, the Hanscom Fire Department reminds the community to always use proper grilling etiquette and safety practices when cooking outdoors. The first step to having a successful cookout is to understand the safety tips and guidelines that go with it.
One of the most important elements in safe barbecuing is to take note of the grill's actual location. Outdoor cooking should take place a safe distance - the fire department recommends at least 10 feet - from any building structures or combustible material, such as trees or shrubs. Thirty-three percent of home grill fires start on an exterior balcony or unenclosed porch, according to stats provided by the fire department.
"The most common mistake made by grillers during the summer is the location of the barbecue. Most calls we get are people trying to cook under an overhang or in garages," said Hanscom Fire Prevention Assistant Chief Mark Webb. "It's not only about heat, but ventilation is important, as well"
When a grill is in use, it should be supervised closely and should never be left unattended. Also, it is important to keep grills clean, as fires can start due to grease build-up over time.
If an accident does occur, Mr. Webb advises that grillers be prepared.
"You should have a fire extinguisher nearby and make sure the area around the grill is sanitized and nothing is highly flammable," he said. "If there is an accident, get everyone out of the area and a safe distance away and then call the fire department."
According to the National Fire Protection Association, fire departments nationwide respond to an average of 7,900 home fires involving grills, hibachis or barbecues each year, including 5,000 outside fires and 2,900 structure fires. June and July are the peak months for grill fires.
In the event of a fire or any other emergency, call 911. For more information about fire safety and prevention call (781) 377-9402.
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AOL co-founder to invest away from Bay Area
AOL co-founder Steve Case is looking to finance entrepreneurs who are trying to build technology companies outside Silicon Valley, just like he once did.
The startups will be bankrolled by a $200 million fund that Case's Revolution Ventures announced Monday. The Revolution Ventures fund plans to make investments of up to $10 million each in startups during the next three to four years. Like other venture capitalists, Case's fund will receive stakes in the startups in exchange for the investments.
Although ideas submitted from Silicon Valley won't be excluded, Case expects 90 percent of the money to be funneled to entrepreneurs living outside the San Francisco Bay Area. The national focus is similar to a $450 million fund that Revolution LLC launched two years. The older fund makes slightly larger investments of $30 million to $50 million in more mature companies.
The newly minted Revolution Ventures fund has already invested undisclosed amounts in four startups scattered around the country. They are: Chicago's BenchPrep, an online service that helps students prepare for academic tests; New York's Booker Software, an online business management service; Washington, D.C.'s Homesnap, the maker of a mobile residential real estate application for mobile devices; and Boston's RunKeeper, the maker of a free health and fitness app for mobile devices.
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text:
|Name: _________________________
|Period: ___________________
This test consists of 15 multiple choice questions and 5 short answer questions.
Multiple Choice Questions
1. James tells Sadie's housekeeper that he is a ____________ of hers.
(a) Bodyguard.
(b) Cousin.
(c) Uncle.
(d) Suitor.
2. James simply needs to write a ________________ that will reach more people than a novel would.
(a) Pamphlet.
(b) Poem.
(c) Newspaper article.
(d) Play.
3. What does James decide to do in order to go through Anna's things?
(a) Jumps into the truck bed.
(b) Searches the building.
(c) Asks for Hugo's help.
(d) Grabs a box and wanders off.
4. James and Lefty decide to buy four bottles of ______________ and to head out to continue their talks.
(a) Brandy.
(b) Whisky.
(c) Gin.
(d) Vodka.
5. What does James come to find out when he arrives where Anna and he were supposed to meet up?
(a) Anna is dead.
(b) Hugo is waiting for him.
(c) The theater has been demolished.
(d) Sadie is waiting for him.
6. Left spends his evening drilling ____________ on his political views, while Dave and Finn go elsewhere.
(a) Sammy.
(b) Everyone.
(c) Hugo.
(d) James.
7. James begins to realize that his previous life was ________________.
(a) Tragic.
(b) Silly.
(c) Beautiful.
(d) Gone forever.
8. James recalls a time when Magdalen destroyed a manuscript of his ___________ that might have been an epic.
(a) Poetry.
(b) Photographs.
(c) Limericks.
(d) Children's stories.
9. James was thought by Lefty to hold __________-wing opinions, though he took no part in politics.
(a) Every.
(b) No.
(c) Left.
(d) Right.
10. James feels ___________ is a bright, sensual person who is warm-hearted and who would help anyone she could.
(a) Anna.
(b) Mrs. Tinckham.
(c) Magdalen.
(d) Sadie.
11. What did Hugo do with the armaments factory that his parents had given to him? What did he turned it into?
(a) Fireworks company.
(b) A theater.
(c) A library.
(d) A park.
12. Where does Anna want James to meet up with her, as she states in a letter to him?
(a) Theater.
(b) Hugo's place.
(c) His house.
(d) Market.
13. Who does Finn suggest James contact in order to find a new place to stay for a while?
(a) Anna.
(b) Sammy.
(c) Sadie.
(d) Magdalen.
14. What did James do after his many discussions with Hugo in order to hold onto the thoughts?
(a) Took notes.
(b) Create a play.
(c) Talk to others.
(d) Tell Anna.
15. Who does James recognized Sadie's boss to be, even though he has taken on a new name?
(a) Dave.
(b) Lefty.
(c) Hugo.
(d) Sammy.
Short Answer Questions
1. James begins to question why he didn't come _____________ than he did.
2. A high pitched chattering sound made the men think that Hugo was having a _____________.
3. Finn says it is a fine night for ____________ after the men leave the pub and begin to walk around.
4. When James arrives at Sadie's, she tells him that she is dreadfully late for the ___________.
5. What does James take off in order to make a motion to fight the person he finds in the house?
This section contains 456 words
(approx. 2 pages at 300 words per page)


text:
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Sir Miles Warren defends his town hall
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The Rebuild
One of the architects who designed Christchurch's Town Hall is disputing claims the building is damaged beyond repair and not worth saving.
"To say the building is torn apart is absolute nonsense," Sir Miles Warren said yesterday, after Earthquake Recovery Minister Gerry Brownlee called for the civic building to be torn down and replaced.
Warren had been inside the building since the quakes and said that apart from on the lower floor, which had been damaged by the raised water level, it was hard to spot the damage.
"Unless you have a careful eye you would not notice the building had moved.
"You could walk around and not believe anything had happened to it at all."
The Town Hall was the only New Zealand building that had an international reputation for architectural design and acoustics and it would be a tragedy if it was demolished.
"It gives me a thrill every time I go into it - it is an extraordinary space," Warren said.
"The Town Hall is more than just a venue for all forms of music; it really is our living room. It's a great space where we all gather."
The Christchurch City Council has voted unanimously to restore the Town Hall but Brownlee believes the building should go.
In a Perspective piece published in yesterday's Press Brownlee described the building as "broken and unusable" and suggested it no longer met modern needs.
- The Press
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Is it worth spending extra to repair heritage buildings?Related story: Landmark church nearly $1m short


text:
Ocilla, police looking for breakthrough a year after Tara Grins...
There are 138 comments on the The Macon Telegraph story from Oct 14, 2006, titled Ocilla, police looking for breakthrough a year after Tara Grins.... In it, The Macon Telegraph reports that:Her picture is still on storefront windows of restaurants and gas stations in this rural south Georgia town.
Join the discussion below, or Read more at The Macon Telegraph.
#122 Mar 25, 2009
does anyone have any info about tara it is just tragic i wish someone would come foward
#123 Mar 3, 2010
Hey Lil Kim, are you still there?
Since: Jul 10
Waterloo, Canada
#124 Jul 18, 2010
I live out of state, but are there any updates on Tara?
Since: Jul 10
#125 Jul 22, 2010
I am so very Hesitant to even make this post. Im not a medium, or claiming to be, I do however have a wonderful gift, and have been able to solve, predict, see, feel, and just know things.. I call it (being in the zone) I have had this all my life, and it used to scare to to death... but I slowly learned how to use it to my advantage, as long as it was for good, and not evil. enough of that. lemme just say, the guy on the city counsel at the time that she went missing, I have no clue his name, but he was a neighbor as well, his wife is a nurse or something, ANYWAY... I dont know his name, But he was on TV telling about her leaving a porch light on, or some kinda BS.. If you wanna find that young lady, then go with your gut feeling, I know you have one, and you dont even know me, and have never met me, nor have i met ANYONE of you, or her, in that family.. But put his ass on a lie detector, squeeze his nuts, his best friend was a judge there in ocilla, Davis was his name, He has since passed, so get your D.A. use the probable cause to name him as a person of interest and SQUEEZE!!!!! He has aged 40 years since it happened, and your small town click is a bunch of SHIT... Help that precious baby rest in peace, PLEASE.... I didnt check my spelling, and im shaking while i am writing this, but I would BET MY LIFE on what im telling you will be shown to be A FACT !!!!(the blue line) Somottobee.. God Bless.
Since: Jul 10
Location hidden
#126 Jul 25, 2010
im just wondering what people so far away are doing speculating all this stuff about tara.....my roomate is tara's best friend so poeple quit guessing!
#127 Jul 25, 2010
really???? Kiifer where were you two ywears ago....... what a joke
Since: Jul 10
Location hidden
#128 Jul 25, 2010
dont be such a butt im just saying he would do anything to have her rest in peace!
Since: Nov 09
Mons, Belgium
#129 Oct 28, 2010
It's sad that is has come to be five years already and still no answers. I have always had two people in mind that could have done this, the obvious ones that everyone knows about but after re-reading and re-thinking about everything I must include two others also. I'm sorry to say this but IMO that neighbour Mr Portier needs to be looked at more indepth IMO, no matter what people say over there, his actions are almost more weird than HD's actions. Washing the car, having keys to her house and car, he was the first to get to her house and let LE in but who's to say he didn't go snooping around before anyone else got there and most important, he found the glove also. It's also very convenient they were away for most part of that weekend and when Dolly was barking her head of in the wee hours of night, which was unusual because she was an inside dog, he never got out of bed to see if something was wrong. People that know him swear to it he never could have done this but they react with their emotion, for people like me, that live outside and have no immediate intimite ties to the case, it is much easier to see these things in a whole different way and objective instead of emotional. IMHO he is an older men but he still has quite a fit fysique for his age and could easily overpower someone like Tara. The other one that I since have re-included in my list of POI's is AV. The fact all the tv-shows which aired Tara's case keep including him and his banging on her door, in their summary's makes me think GBI has him still on their radar too. Remember, he was very difficult to find the first week after Tara vanished and his alibi was given by a close family member or even his mother I believe, that he was working a few counties away with a relative. Who's to say he and that 'unknown' relative, didn't make the drive over to Ocilla that night and took Tara, if they took here with them they could've put her remains anywhere between Ocilla and that county he was working and staying at that time, maybe that is why she hasn't still be found because she was put outside of Ocilla... JMHO.
I pray for justice soon but I honestly think we shall be praying and hoping for a long time...
United States
#130 Nov 4, 2012
United States
#131 Nov 11, 2012
I think her police officer boyfriend did it
United States
#132 Nov 16, 2012
#133 Jan 14, 2013
Did they really talk to ALL of the neighbors? Or the workers that were working on houses in plain sight of tara grinsteads? I know they didn't. How about the one that was pouring cement in his garage the week of her disappearance?
#134 Jan 15, 2013
Looking like Bush did for chemical in Iraq.
#135 Jan 15, 2013
#137 Jan 6, 2014
lil kim is there anything new on the Tara Grinstead case ?
#138 Jan 7, 2014
Kiifer , the man you talk about squeezing , is he the neighbor who washed Tara s car ?
#139 Jan 8, 2014
Does anyone no when,why, where Mr. Portier washed Tara s car ?
#140 Dec 18, 2014
-- Yes --- Portier
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|Home Software category Just in softwares Submit a program Contact us Link to us
Home > Security & Privacy::Encryption Tools > DRM Plus Encryption Solution 8.7
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text:
Scientists are using pupil measurements to study a wide range of psychological processes and to get a glimpse into the mind.
Speaking of Science
February 1, 2016|
February 2016's selection of notable quotes
February 1, 2016|
February 2016's selection of notable quotes
February 1, 2016|
To protect the global food supply, scientists want to understand—and enhance—plants' natural resistance to pathogens.
February 1, 2016|
How plants fight off pathogens
February 1, 2016|
Diverse fungal species live in and on the human body.
February 1, 2016|
The largely overlooked resident fungal community plays a critical role in human health and disease.
January 31, 2016|
A mouse study suggests a mechanism by which severe infections during pregnancy increase autism risk.
January 27, 2016|
Examining the brains of seven patients who died of the prion disease called Creutzfeldt–Jakob, researchers find signs of Alzheimer's pathology.
January 21, 2016|
Human monoclonal antibodies induced during Ebola infection are able to neutralize related viral species, scientists show.
January 20, 2016|
A public-health nonprofit and an international drugmaker team up to stockpile hundreds of thousands of doses of a promising vaccine and to speed along the approval process.
January 13, 2016|
Scientists link an immune phenotype present at birth to the development of food allergies a year later.


text:
The Long Beach Board of Harbor Commissioners this week appointed Heather A. Tomley as the new Director of Environmental Planning. She will be charged with leading Green Port environmental initiatives.
Tomley has been serving as the City of Long Beach Harbor Department's Acting Director of Environmental Planning since July 2013. She will report to Managing Director of Environmental Affairs and Planning Rick Cameron. Tomley originally joined the Harbor Department as an Environmental Planning Associate in 2005, was promoted to Environmental Specialist and then Senior Environmental Specialist in 2006 and Assistant Director in 2008. Currently on leave, she is scheduled to return March 17 to her new role.
As Director of Environmental Planning, she will lead the division most directly responsible for the Port's signature environmental programs: the Green Port Policy and the San Pedro Bay Ports Clean Air Action Plan. The division coordinates programs to improve air, water and soil quality, preserve wildlife habitat and integrate sustainability into Port practices.
"Heather Tomley's work in the Environmental Planning Division has been instrumental to the greening of the Port. We are confident she will continue to ensure that the Port of Long Beach is a world-leading environmental steward in the industry," said Harbor Commission President Doug Drummond.
Tomley earned her bachelor of science in chemistry and a minor in Psychology from Cal Poly San Luis Obispo, and her master of science in environmental science from the University of North Carolina at Chapel Hill.
Maritime Today
The Maritime Industry's original and most viewed E-News Service
The U.S. Senate has confirmed the nominations of three individuals to serve as Federal Maritime Commissioners: Rebecca F. Dye, Michael A. Khouri and Daniel B. Maffei.
Xeneta, a global benchmarking and market intelligence platform for containerized ocean freight, believes that the UK's decision to leave the European Union will
The PALFINGER Group closed the acquisition of 100 percent of the shares in Herkules Harding Holding AS, i.e. the globally operating Harding Group, supplier of lifesaving
As of July 1, shippers and freight forwarders are required to verify the weight of a container before the container is loaded onto a ship.
The Netherlands'
UK Industry trade body Mersey Maritime has announced a new trade agreement with the Isle of Man Shipping Association (IOMSA) which aims to supercharge bilateral trade,
Port Everglades has signed a partnership agreement with the U.S. Environmental Protection Agency (EPA) to study air emissions.
The EPA's Office of Transportation
Exploration begins by BHP Billiton using the Deepwater Invictus rig and supported by Lloyd's Register's rig integrity team.
Lloyd's Register (LR) announced it
The first production version of Damen's InvaSave ballast water treatment system – intended for use at Groningen Seaports – will be on display at the upcoming 'DelfSail'
Norsafe informs it has signed a new contract with VARD Group, and will supply lifeboats complete with davit systems to a series of 15 new vessels.
Topaz Energy
A new regulation aimed at protecting seafarers who need to enter enclosed spaces, by requiring ships to carry portable atmosphere testing equipment on board, enters into force on July 1, 2016.


text:
At last, my blog book, A Year in Lush Places: Tales from England's Rural Underbelly, is out in paperback.
It's been available in Kindle format for a little while now and I've been like an ant with a overdose of formic acid as I waited for the 'proper' book to arrive.
And now it has, thanks to the good folks at FeedaRead. It will also be available from leading booksellers.
It's a slim little number - it's a novella, you see. Sneeze and you might miss a vital bit of the plot. But if you enjoy the Dorset part of this blog, I think you'll enjoy the book.
Here's the blurb:
Immersed in a sea of Barbour wearers and waves of Daily Mail readers, Maddie Grigg charts the highs and lows of a Dorset year as she attempts to swim against the tide in the lively and lovely village of Lush Places. From singing groups, book clubs and point-to-point, not to mention election wars, the village has it all. A quiet rebel, Maddie is married to a charmer, a man with whom men want to get drunk and women fall in love. Her diary is a story of love, trust and friendship. Inspired by and taken from the affectionate and amusing Blog of Note, The World From My Window, the novella will make you smile and leave you yearning for a life more simple. But you might never eat another pasty again.
It's an ideal size to put in your beach bag and read in one sitting. And then clamour for the BBC to turn it into a prime Sunday evening feel-good serial, with Ray Winstone as Mr Grigg and Joely Richardson as his long suffering wife. Or at the very least call for it to be book of the week on Radio Four's Woman's Hour.
That's about it.
Love Maddie x
Wednesday, 17 July 2013
Paperback alert! The blog book is out...
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