text: Have they said anything about what will happen to the Well Read achievement, with the release in 5.0.4 of the new Scarlet Halls/Monastery and Scholomance instances? The old SM Library had 13 of the books for this achievement, conveniently, though each of them can be found elsewhere also as far as I know. Old Scholomance also had several ... and was the only location in Azeroth for _The Invasion of Draenor_, apparently. So now that this achievement can't be finished from scratch, will it become a Feat of Strength? Will they put the various books back into Scarlet Halls and Scholomance, or scatter them (or at least the crucial one) in other Azeroth locations? Any word?

subset: commoncrawl


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By Bob Cusack - 03/14/06 12:00 AM EST
Senators pondering a bid for the presidency in 2008 are quickly trying to arrange visits to the hurricane-ravaged Gulf Coast to plug an embarrassing gap in their campaigning travel itinerary.
Last Friday, two days after The Hill published a survey of White House aspirants who had not made their journey, Sen. John McCainJohn McCainOvernight Defense: Pentagon hails Fallujah's recapture | Texts to VA suicide hotline went unanswered Defense contingency misuse threatens national security Former Bush national security official backing Clinton over Trump MORE (R-Ariz.) traveled to the area for the first time since the storm.
Other senators with presidential aspirations are also committed to getting a firsthand look at the devastation. Sens. George Allen (R-Va.) and Joseph Biden (D-Del.) said on NBC's "Meet the Press" that they will be going to the Gulf during upcoming congressional recesses.
On Wednesday, The Hill published a survey of senators who have and have not been to the Gulf Coast since late August. McCain visited at the request of Sen. Trent Lott (R-Miss.), according to the Biloxi Sun Herald.
Sen. Lindsey GrahamLindsey GrahamDefense contingency misuse threatens national security Gun-control supporters plan next steps versus NRA Bipartisan gun measure survives test vote MORE (R-S.C.) visited the affected areas last week and reportedly said, "If all it takes is some money, then you are all going to get some money. Shame on us if we don't learn from this."
Sens. Lisa MurkowskiLisa MurkowskiGOP senator praises Supreme Court's abortion ruling Kerry visits Arctic Circle to see climate impacts Senate panel clears EPA spending bill, blocking rules MORE (R-Alaska) and James Jeffords (I-Vt.) will travel there as well this month.
Possible presidential hopefuls who have not yet committed to visiting are Sens. Evan Bayh (D-Ind.), Russ Feingold (D-Wis.) and Chuck HagelChuck HagelThere's still time for another third-party option Hagel says NATO deployment could spark a new Cold War with Russia Overnight Defense: House panel unveils 5B defense spending bill MORE (R-Neb.). Calls to their offices were not returned.
According to the Sun Herald, McCain said he "wanted to wait until he knew he would not get in the way." McCain toured the whole coast by helicopter.
"They need our help and they're going to need our help for a long time," McCain said after the visit.
Of the 76 senators who responded to The Hill's survey last week, 39 senators had visited the Gulf Coast since Katrina and 37 had not. It is likely that none of the 24 who did not respond had gone because there are no media accounts of those senators traveling there.
Asked on "Meet the Press" why he has not yet seen the damage done by Katrina, Allen said, "We've been trying to figure it out and get a time to go," adding that "it's important" to visit.
Biden said he did not visit initially because he did not want to grandstand.
Louisiana Gov. Kathleen Blanco (D) last week estimated that 30 percent of House lawmakers have visited the affected areas.


text: YMCA Christmas Fun Run By liteonline December 21, 2013 12:08 PM 107.9 LITE FM entertained the runners of the 2013 YMCA Christmas Fun Run with awesome Christmas music! Image of Filed Under: photo galleries Category: Photos Share on Facebook Share on Twitter More Send to a friend! Print this page Pin it! Reddit This! Share on Tumblr! Best of 107.9 Lite FM Win The Perfect Mother/Daughter Night Out With LITE-FM's Mom, Meghan, And Me 'Game of Thrones' Finale Review: 'The Winds of Winter' Lights a Wild Fire for Season 7 Andy Grammer Backstage Meet and Greet Daughtry Closes Out the 2016 Boise Music Festival Recommended For You ZergNet Best of the Web ZergNet


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PrivatAir Saudi Arabia Ltd. (PASA), is a full scale Business Aviation Company based in Jeddah, KSA. PASA is currently looking for a suitable candidate for the position of "Director of Maintenance".
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We have a current requirement for a Support engineer with technical expertise to join our client on a 12 month contract basis. This position is based in Samlesbury, lancashire.The role will entail technical investigation of customer supply queries and provide support for managing Engineering data on the Supply Chain systems. Thus providing assurances all deliverables have provenance and are con...
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Carbon60 has a permanent opportunity in Retford, Nottinghamshire for a B1.2 or B3 licensed engineer to work at a well-established company carrying out base maintenance on light aircraft.The company runs a small fleet of DA42 and is looking for an experienced B1.2/B3 engineer who holds the full type rating and recency on Group 3 aircraft (including composite structures).The ideal licensed engine...
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Salary, as ever, is related to experience. Starting salaries for aircraft engineers tend to be between £20,000 and £25,000 however slightly more experienced aerospace engineers can earn between £28,000 and £40,000. Salary for senior engineers, such as project leaders is usually from £45,000 to £60,000.
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Maritime Today
The Maritime Industry's original and most viewed E-News Service
For Hutchison Port Holdings (HPH), one of the world's leading container terminal operators, Stockholm is strategically important. In April the final permit was
Marine-based commissioning work is now underway at Liverpool2, with Mediterranean Shipping Company (MSC) committing vessel support to Peel Ports to help make the trial a success.
The Moroccan government raised 1.94 billion dirhams ($197 million) by selling a 40 percent stake in state-owned port operator Marsa Maroc in the country's first initial public offering this year,
Hanjin Shipping is planning to return a total of 38 chartered vessels once their contracts end as part of its restructuring efforts, reports korea Herald.
The Baltic Exchange's main sea freight index, tracking rates for ships carrying dry bulk commodities, rose on Monday for a fourth straight session as higher demand


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Showing news for 1st ODI: Sri Lanka v Bangladesh at Colombo (PSS), Jul 20, 2007
First one-day international
Mar 18, 2008: Match reports from Sri Lanka v Bangladesh 2007
Sri Lanka vs Bangladesh, 1st ODI, Colombo
Jayawardene all praise for Fernando
Jul 20, 2007: Sri Lanka captain Mahela Jayawardene heaped praise on his bowlers, especially Dilhara Fernando, after his team had completed a comprehensive 70-runs victory over Bangladesh in the first ODI
Sri Lanka's first cricket stadium with Wi-Fi facilities
Saravanamuttu Stadium undergoes major revamp
Jul 20, 2007: The P. Saravanamuttu Stadium has been the first stadium to be upgraded just days after the local and foreign media lambasted its facilities during the second Test against Bangladesh.
Sri Lanka vs Bangladesh, 1st ODI, Colombo
Formidable Fernando powers Sri Lanka to easy win
Jul 20, 2007: Dilhara Fernando sashayed his way through a brittle top order, and with Farvez Maharoof playing sidekick ensured Sri Lanka sealed a facile win in the first ODI against Bangladesh at Colombo
Sri Lanka vs Bangladesh, 1st ODI, Colombo
Sri Lanka strengthened by Jayasuriya return
Jul 19, 2007: Mahela Jayawardene acknowledged Bangladesh's growing one-day prowess but warned that his team was determined to win the three-match series
How much is a century against Zimbabwe worth? (56)
Cricket stats need to take into account various contextual factors relating to players' and teams' performances if they are to be meaningful
'The dream is to come back and play for three to four years' (39)
Mohammad Asif is playing club cricket in Scandinavia as he strives for a Pakistan comeback and to rebuild his career in the wake of the spot-fixing scandal
What's the verdict on the pink ball in Indian conditions? (27)
Visibility is good, so is durability, and while it does swing a fair amount, it ought to spin as well
Give the World Test Championship a chance (27)
Test cricket needs to be given back to the people. Everybody must buy in to this bigger picture or the moment will pass us by
'I don't mind losing a few on the way to a win' (25)
Angelo Mathews talks about the challenges of leading an inexperienced team, and the possibility of giving up the T20 captaincy


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Hi bookish friends! Are you all ready for BEA? Man I can't believe it's already less than 2 months away SO MUCH EXCITE!! Hopefully the weather will be just as awesome as last year especially that I'm driving up. Did you stop by the blog this week? We have a new giveaway for a hardcopy of Sekret, as well as the book's dream cast which is all kinds of hot! So let's see what new books I got! The last 2 weeks for me have all been ebooks – I think the mailman can't even get to our mailbox due to all the snow anyways >.<
(Click on covers for Goodreads)
I received for review:
*Big thanks to HarperCollins, St. Martin's Press, Little, Brown and Company, and Simon & Schuster for these pretties!*
That's all for me this week!
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Date Posted: Monday, June 27th, 2016
Categories: Department of State Kent County New Castle County News Sussex County The Arts
For Immediate Release THE MEZZANINE GALLERY TO EXHIBIT "JUST ABOVE WATER" FEATURING PHOTOGRAPHS BY MARK HOULDAY The Delaware Division of the Arts Mezzanine Gallery is pleased to present Just Above Water, an exhibition of photographs by Mark Houlday. The exhibition will be on view from July 1-29. Please note: the Mezzanine Gallery will be closed on […]
Date Posted: Wednesday, May 4th, 2016
Categories: Department of State New Castle County News The Arts
Ms. Soysal attributes her interest in street and documentary photography to her fascination with life, people, and stories. Her photographs in My Human and I document dogs with people in a variety of situations from affectionate moments with owners to action shots of dogs working with police trainers.
Date Posted: Thursday, March 24th, 2016
Categories: Department of State Kent County New Castle County News Sussex County The Arts
For Immediate Release THE MEZZANINE GALLERY TO EXHIBIT "SPIRIT OF EDEN: NEMOURS" FEATURING COLOR INFRARED PHOTOGRAPHS BY JOE DEL TUFO The Delaware Division of the Arts Mezzanine Gallery is pleased to present an exhibition of work by Joe del Tufo during the month of April. Spirit of Eden: Nemours will be on view from April […]
Date Posted: Monday, September 28th, 2015
Categories: New Castle County News The Arts
Abstractions presents a selection of photographic interpretations of the natural world. Through recording and reinterpretation of the nature, the artist aims to represent the familiar in new ways.
Date Posted: Wednesday, January 28th, 2015
Categories: News The Arts
The exhibition, titled First Comes Love, presents a series of portraits of LGBTQ couples and is accompanied by their personal stories.
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5 Astral Media Office Interior by Lemay Associés
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Luxury Anantara Resorts opened Anantara Kihavah Villas earlier this year in the beautiful Maldives. Located on the Baa Atoll, only 35 minutes by seaplane from Male International Airport. You can expect the morning sun dappling the crystal-clear waters of a secluded lagoon. And your afternoons spent sunbathing by your private infinity pool, just steps […]- READ MORE -
Room Mate, the design hotel chain founded by award-winning Spanish entrepreneur, Kike Sarasola, has launched an online portfolio of new and stylish rental accommodation Bemate.com, and we caught up with Kike to discuss his plans. The website currently offers 2,500 handpicked apartments for rental, with this number expected to rise with the launch of new locations in […]- READ MORE -


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Watch the UFC 153: Silva vs. Bonnar weigh-ins live on Friday, Oct. 12, on MMAWeekly.com. Friday's weigh-ins kick off at approximately 3 p.m. ET / 12 p.m. PT with Anderson Silva, Stephan Bonnar, Antonio Rodrigo Nogueira, Dave Herman and the rest of the UFC 153 fighters stepping on the scale.
The UFC 153 weigh-in video is provided courtesy of UFC.com.
[embedded content]
For more UFC News and UFC Rumors, follow MMAWeekly.com on Twitter and Facebook.
Watch the UFC 199: Rockhold vs. Bisping 2 pre-fight press conference, streaming live on MMAWeekly.com on Thursday at 4 p.m. ET / 1 p.m. PT. read news >>
Watch the UFC 199: Rockhold vs. Bisping 2 Q&A featuring flyweight champion Demetrious Johnson streaming live from The Forum in Los Angeles at 5 p.m. ET / 2 p.m. PT. read news >>
Watch the official weigh-in for UFC 199: Rockhold vs Bisping 2 streaming live from The Forum in Los Angeles on Friday at 7 p.m. ET / 4 p.m. PT. read news >>
Before UFC 199 can take place on Saturday, the fighters on the card first had to weigh-in at The Forum on Friday, and all the athletes hit their mark on the scales. read news >>
The official weigh-ins for Bellator 156: Galvao vs. Dantas 2 took place this afternoon in front of a packed house at the DoubleTree Hotel in Fresno. read news >>
Watch the Fight Night Ottawa Q&A featuring Chris Weidman, Aljamain Sterling and Stevie Ray streaming live from TD Place Arena on Friday at 3:30 p.m. ET. read news >>
The 26 fighters competing on Saturday's UFC Fight Night: MacDonald vs. Thompson fight card in Ottawa officially weigh in on Friday at the TD Place Arena at 5 p.m. ET. read news >>
By Damon Martin, www.FOXsports.com read news >>


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Double Divine, 5/17/2014 filly by Arctic out of Generally a Lady by Patton. Beautiful movement, natural athletic ability, outstanding conformation and…$6,000
Clever Declan, 6/30/2014 colt by Arctic out ofAneighzing Grace by Montbretia. The movement for dressage, the power and athletic ability for jumping or…$5,000
Polar Prospect, 2015 filly by Arctic out of Polish Prospect by Polish Numbers. Her sire is out of a half sister to the 1997 near triple crown winner Silver…$3,500
Arctic Dierdra, 6/24/2014 filly by Arctic out of Tilly Manilly by Unbridled Desire. The movement for dressage, the power and athletic ability for jumping…$5,000
Dune is a fantastic jumping pony. He is 9 years old and 13.3 hands. He has been shown in hunter and jumper classes, in dressage and cross country. He is…$6,500
Excellent and talented. Roan with a sweet personality. Redeemed Lynx x MRI Beau Bar Desire. He has the prettiest little show trot in the pasture and…$2,500
Double registered APHA and JC. Well started, has done trail riding, gone to a few schooling shows, coursing around small cross country and stadium, could…$7,500
7 Year Old, level headed, calm, full bred Appaloosa gelding!! Well broke and ready to be fine tuned to what ever discipline you see fit. Collects on cue…$5,000


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Click here to print the obituary below
Wayne Morgan Oliver(1967 - 2014)
Wayne Morgan Oliver
Apr. 11, 1967 - Apr. 4, 2014
Resident of Danville
Wayne Morgan Oliver died bravely and peacefully on April 4, 2014. Wayne is survived by his loving mother Janet Noonkester, father Charles Oliver, sisters Sandra & Kristen Oliver, grandmother Diane Morgan, niece & nephew, aunts & uncles, cousins & friends, including his poker buddies. Wayne was born in Walnut Creek and lived in Danville his entire life. He was a sixth generation Danville/Alamo resident and will be interned at the Alamo Cemetery Apr. 29th at 2:30p.m., joining many of his family members.
Published in Contra Costa Times on Apr. 20, 2014


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The ABC's overseas reporters give their interpretation and analysis of the week's major events.
|CleanPistorius saga: as sentencing looms, the long-running case comes to a close
|The long-running legal saga involving Oscar Pistorius is coming to a close. The South African Olympian and Paralympian will be sentenced in just a couple of weeks. Our Africa correspondent has been in court for much of the trial and he was back in Pretoria for the sentencing hearing.
|24 6 2016
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|CleanThe ABC farewells veteran broadcaster Tony Eastley after 37 years
|One of the ABC's finest journalists, and a much loved colleague, Tony Eastley is retiring after 37 years. Tony worked as a foreign correspondent throughout Asia, he's been a television news presenter here at the ABC and for ten years he hosted the morning current affairs program, AM. In this conversation with News 24 presenter Kumi Taguchi, Tony recalls the major news stories he's covered both at home and overseas.
|24 6 2016
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Thecus® announces the AFD42000 Deluxe Coffee Edition
Thecus® announces the AFD42000 Deluxe Coffee Edition
Increase security and effectiveness with RAID 60 espresso.
04/01/2011- Taipei (Taiwan): security is one of the major concerns of IT industry. Even if NAS products are getting more and more efficient and reliable, human factor has to be considered when building an effective datacenter. What kind of catastrophe can happen if the IT engineer on duty falls asleep?
The front view of the AFD4200 Deluxe Coffee Edition
Always leading the market in term of innovations and creativity, Thecus Technology Corp. is very proud to announce its brand new model: the AFD42000 Deluxe Coffee Edition. Featuring a blazing 12 cores CPU, 16GB of DDRR3 Ram and our new firmware, this device also provides the new signature Thecus feature: the Thecus Turbo Coffee Deluxe Edition (TTCDE).
The AFD42000 Deluxe Coffee Edition provides a handy coffee interface and USB3.0 ports.
Thanks to the new smart coffee device, the TTCDE is able to deliver 3 cups per minute. RAID function is also available, allowing your coffee to be fresher or faster, depending on your needs. "My IT Engineers have never been so available and happy, thanks to the new NAS from Thecus. I can enjoy a fresh coffee and my data are safe at the same moment" said one of our customers. The AFD42000 Deluxe Coffee Edition also got a pci-espresso slot, making it compatible with the latest Arabica and Robusta protocols.
The coffee unit is fancy and easy to use.
More info about the AFD42000:
(This special edition is available on April 1st, 2011.)
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Florida: Review Shows Increased Red Light Cameras AccidentsAnalysis suggests Hallandale Beach, Florida red light cameras have failed to reduce accidents.
Sep. 10, 2012
Pope Says Church Should Apologize to Gays for Orlando Shooting
SHOCKER: Police Say Leftists Started Violence at Rally in Sacramento
Putin on Brexit: "Some Don't Want to Dissolve National Borders"
Bill O'Reilly on Brexit Motive: "In Parts of London, You're Not Really in England, You're in Pakistan"
Walls For Me But Not For Thee: Zuckerberg Builds Giant Wall Around Hawaii Property
A review of the accident history at red light camera intersections in Hallandale Beach, Florida suggests automated ticketing machines have failed to yield an overall safety benefit since Arizona-based American Traffic Solutions (ATS) began paying for the right to issue tickets and collect fines at a pair of intersections more than two years ago.
[...]The overall number of accidents went up 46 percent with the greatest increase in rear-end collisions. The city side-stepped the negative result and pointed to a reduction in "red light running" crashes as evidence of the program's success, but at least one of the four collisions marked as related to red light running in the before period was caused by an impaired driver. The presence of a camera would not likely have changed the outcome.
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This pendant is very small, more appropriate for a child. The pendant is very light and small, not much presence on the neckline. If you are purchasing it for a child, it is cute, but it very small for an adult neckline. I would not recommend it for an adult.
It is much smaller than I expected.... Would not order this item again
I will make sure that I wear it on a special occasion! Thanks!
Was much smaller then it looked but still very nice. Makes a lovely piece on a younger or smaller person. Turquoise is not always the color that it shows in the picture but never the less lovely .


text:
SANTA MONICA, CA - Pet retailer, Petco Inc., and its agency The Phelps Group recently enlisted the talented team at Steele to create the illusion of employees interacting with life-sized pet products, all in an effort to show off the Petco staff's knowledge and passion for pets and those who love them.
All four :30 spots - "Cat Condo," "Aquarium," "Kong" and "Hamster Ball" play to viewers' sense of humor, and were composited in high definition using the studio's Quantel eQ system. In "Cat Condo," the customer witnesses an acrobatically-fit employee scale a life-sized cat condo/scratching post.
"These commercials encompass all that we do here, from creative development, set supervision, 3D and 2D animation, digital effects and compositing," says Brian Adler, executive producer, for Steele. "The most challenging of the three spots by far was 'Aquarium,' which involved a dedicated Petco employee swimming with giant fish in a life-size aquarium."
Wide shots of the store's interior were filmed traditionally and combined with photoreal CG fish and digital aquarium architecture, notes, Jerry Steele, president and supervising VFX artist. "The CG elements were then composited with the live-action footage and seamlessly integrated."
Adler first cleared and shot a large space inside a Petco store where the virtual aquarium would eventually reside. He then shot hi-rez stills to serve as backgrounds. The production later moved to an aquatic center where the diver was shot in front of an underwater greenscreen.
Supervising CG artist, Wayne England, created the photoreal fish using NewTek LightWave. Once the fish were animated, lit and textured, Steele composited over 30 layers for most shots. Using Quantel eQ and Henry, he added bubbles, shadows, and lighting effects, manipulating the images to appear as if the fish swam behind the diver and other live action aquarium objects.
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LOS ANGELES — It's Always Sunny in Philadelphia returned to FXX in early January and Ring of Fire (www.ringoffire.com), here, helped take the gang to places they had never gone before for the show's 1 ...
January 28, 2016


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As part of a facilities upgrade to HD and eventually full 5.1 surround-sound mixing, NEP Studio 54 is using a 48-fader, Solid State Logic C100 HD mixing console to handle the audio for Comedy Central's "The Colbert Report." NEP upgraded two studios for full HD production, Studio 52, where Comedy Central's the "Daily Show with Jon Stewart" is produced, and, more recently, Studio 54. The success of the C100 HD in Studio 52 inspired the purchase of a second SSL for Studio 54.
The video and audio control rooms for "The Colbert Report" are located three floors above the production studio. The C100 HD is interfaced directly into the console's preamps to pick up the microphones from the studio floor. The console also interfaces to the rest of the studio system for playback elements, protocols and multitrack segments.
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text:
Sound Off 2006
Sound Off for February 2006
Tuesday, February 28
- I would like to know what year Danni Boatwright of the Survivor TV show graduated from KU and what her degree was in.
Monday, February 27
- I remember Robert Hemenway releasing a statement last year about evolution. Where can I find that statement?
Sunday, February 26
Saturday, February 25
Friday, February 24
- A few weeks ago you had an article about an airline that was going to be out of Topeka's Forbes Field and it was going to Las Vegas. Can you tell me when it was going to be starting up? And they had a special. What about prices?
Thursday, February 23
Wednesday, February 22
Tuesday, February 21
Monday, February 20
Sunday, February 19
- I thought I saw what looked like a large propane tank outside the city's new fire station near 19th and Iowa streets. Is the city using propane to heat the fire station building?
Saturday, February 18
Friday, February 17
Thursday, February 16
- I've been reading about this new gun ordinance that prohibits guns within 200 feet of a bar. I want to know what happens if somebody lives within 200 feet of a bar and has a gun in their home.
Wednesday, February 15
- Why won't the city repaint its crosswalks on the east side of town? I have left several messages with the city over the past six months but there are still many crosswalks that aren't painted.
Tuesday, February 14
- I was wondering what a person should do about a neighbor who leaves his trash cans out at the curb all the time. It looks pretty unsightly.
Monday, February 13
Sunday, February 12
Saturday, February 11
- What are the requirements of diversion for the former owner of the Eldridge Hotel? He was charged with criminal threat and battering a law enforcement officer.
Friday, February 10
- My friend's landlord left her a packet to pay $5 to the city to register her dog. Does the city have a dog registration program, and is there a fee?
Thursday, February 9
- Does the commercial use (charging for KU game parking) of the Catholic Campus Center's new parking garage have any bearing on its tax status?
Wednesday, February 8
- Can you tell me, does KU still offer indoor walking? And, if KU does not offer it, are there any other facilities that offer indoor walking on inclement days?
Tuesday, February 7
- This morning as I drove on Sixth Street between Wakarusa and K-10, three Lawrence police cars were running a speed trap there. I drive this stretch twice daily, and I see the Lawrence police patrolling at least half the time I'm on it. Why is this necessary? When will the speed limit on West Sixth be raised and to what?
Monday, February 6
- How could an accident that knocked down power lines five miles east of Lawrence, which happened on Jan. 28, affect the electricity in a neighborhood near Kasold Drive and Bob Billings Parkway?
Sunday, February 5
- I'm sitting here watching the KU basketball game, and I would like to know the definition of an intentional foul. When is that used? When is it not used? And what does it mean? The NCAA rulebook says that officials call an intentional foul when they believe a player committed a foul without legitimately going after the ball or legitimately trying to defend another player. Severe or excessive contact, which is a flagrant foul, does not determine an intentional foul. Intentional foul examples can include: Making contact with a player who is throwing the ball into play; holding or pushing another player to stop the clock; pushing a player from behind to prevent a basket. The penalty is two free-throw shots for the fouled player, and after the free throws, that team keeps possession of the ball.
Saturday, February 4
Friday, February 3
- Is it true that someone from Kansas Atty. Gen. Phill Kline's office was at the MAINstream Coalition meeting in Lawrence last week, taking pictures?
Thursday, February 2
- I would like to know how the individuals are selected for singing the National Anthem at the KU basketball games, and do they have to be a student?
Wednesday, February 1
- Letter to the editor: Food safety June 29, 2016 · 5 comments
- Multimillion-dollar Bob Billings Parkway traffic-control project starts this week June 28, 2016 · 6 comments
- Letter to the editor: Shooting concerns June 25, 2016 · 6 comments
- Letter to the editor: A safer country June 29, 2016 · 4 comments
- Letter to the editor: Trump questions June 28, 2016 · 12 comments
- Jayhawk Bookstore going out of business, citing slipping textbook sales June 28, 2016 · 10 comments
- Analysis: Brownback's view of Kansas economy as a 'three-legged stool' no longer accurate June 28, 2016 · 48 comments
- Full-fat dairy makes a comeback among the health conscious June 29, 2016 · 2 comments
- Teachers union, district reach tentative agreement on pay raise for educators June 28, 2016 · 2 comments
- U.S. Supreme Court ruling expected to affect abortion clinic restrictions currently on hold in Kansas June 27, 2016 · 17 comments
- Jayhawk Bookstore going out of business, citing slipping textbook sales June 28, 2016
- Greene, Traylor to play in summer league June 28, 2016
- Lawrence Arts Center announces new CEO June 28, 2016
- Kansas Supreme Court accepts latest school funding changes; up next, the adequacy question June 28, 2016
- Brownback describes Kansas Medicaid backlog as 'frustrating' June 28, 2016
- Douglas County Commission to consider moving ahead with jail expansion design June 28, 2016
- Teachers union, district reach tentative agreement on pay raise for educators June 28, 2016
- Regulators OK Westar fee cut; electric customers to see slight drop in their bills June 28, 2016
- ACLU urges judge to rule quickly on Kansas voter registration case June 28, 2016
- Analysis: Brownback's view of Kansas economy as a 'three-legged stool' no longer accurate June 28, 2016


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Those gray clouds that hovered over East Hamilton's practice field on Tuesday got a lot darker for Hurricanes tailback Logan Jackson a few hours later.
Jackson was informed by doctors that he tore the ACL in his left knee in Friday night's 38-0 TSSAA first-round playoff victory over Marshall County and will miss the rest of his senior season.
The Hurricanes (10-1) will host Page (7-4) Friday night in a second-round game. Kickoff is set for 7 p.m.
"I kind of knew Friday night after the doctor talked to me on the sidelines," Jackson said Wednesday. "I found out late (Tuesday) night exactly what happened. I was hoping for the best, but it turned out pretty bad.
"I asked the doctor if I could put on a brace and still play. He told me that would be too risky."
Jackson sustained the injury while making a second-quarter run against Marshall County. He already had scored two touchdowns and rushed for what turned out to be a game-high 89 yards.
Jackson will have surgery on Nov. 21 and begin rehab two days later.
"I want to have the surgery and get it over with, get back in the weight room and get healthy and back on the field as soon as possible," he said. "I hope there will be some colleges that will still give me an opportunity to play for them. That's been a dream of mine since I was a little boy watching my sister cheerlead at Ooltewah games."
Jackson, who rushed for for 1,608 yards and 25 touchdowns, was being recruited by UTC, Furman, Eastern Kentucky, Memphis and Appalachian State.
He made a visit to Tennessee Tech the day after being injured against Marshall County.
"I still wasn't sure how bad the injury was when I went up there," Jackson said. "I was on the sideline, but I didn't wear my (knee) brace. I wasn't using crutches because I wanted to make things look as good as possible.
"The knee didn't bother me much until I sat down. I had a hard time getting up."
When Jackson left Friday's game, Matt Milita and senior Lamond Greer filled in.
Milita, a five-foot-1-inch, 165-pound sophomore speedster, rushed seven times for 78 yards. The 5-8, 185-pound Greer, a senior, picked up 69 yards on 12 carries.
Those two players helped the once-beaten, third-ranked Hurricanes pile up 396 yards of total offense.
The third player figuring into the equation is junior Hunter Parker, a 5-11, 165-pound junior who is the team's starting free safety.
For the season, Greer carried 69 times for 394 yards with four touchdowns. Milita has 362 yards on 39 carries and seven touchdowns.
Parker has not run the ball this season, but has previous backfield experience. Basically, Parker is an insurance policy in case of further injuries.
So, Greer and Milita have a combined 609 yards and 11 touchdowns. That doesn't match Jackson's offensive production by any means, but Gatewood is confident the three players can fill in adequately.
"It'll be a committee deal like it's been in the second halves in most games this year," Gatewood said. "We've got three kids that'll probably run at tailback for us.
"Those three guys are vested in the offense and understand their roles."
Will Greer or Milita be in the starter?
"I don't know," said Gatewood, the only coach in East Hamilton's short four-year history. "I'll have to see how I feel when I wake up Friday morning. Seriously, it hinges on what type offense we're in and what kind of play we're going to run."
Another player that can't be overlooked is quarterback Hunter Moore, who has completed 74 of 121 passes for 1,208 yards and 14 touchdowns.
East Hamilton's leading receiver is senior receiver Cody Knox (5-11, 175), who has 17 receptions for 341 yards and three touchdowns.
TSSAA Second-Round Pairings
All games start at 7 p.m. Local Time
Class A
South Pittsburgh (8-3) at Gordonsville (10-1)
Class 2A
Boyd-Buchanan (10-1) at Oneida (9-1)
Silverdale (10-1) at Knoxville Grace (9-1)
Trousdale County (8-3) at Marion County (8-2)
Class 4A
Notre Dame (9-2) at Giles County (10-0)
Page (7-4) at East Hamilton (10-1)
Class 5A
Ooltewah (8-3) at Lenoir City (9-2)
Class 6A
Riverdale (8-3) at McMinn County (10-1)
Division II-AA
Baylor (8-3) at Memphis University School (8-2)
McCallie (5-5) at Ensworth (10-0)
(E-mail Larry Fleming at firstname.lastname@example.com)
July 1, 2016
The Southern League has announced that Chattanooga Lookouts' All-Star Daniel Palka has been named its Player of the Month for the month of June. The Lookouts outfielder's month got ... (click for more)
Pensacola, Fl.. Chattanooga tagged the Blue Wahoos relievers to go on to win, 7-3, in front of 4,884 at Blue Wahoos Stadium. Ryan Eades improved to 5-3 with six strong innings. He gave ... (click for more)
Eleven players from the Chattanooga area have been voted to the Tennessee Sports Writers Association all-state tennis team. Making the team were Hixson's Alex Condra and Richard Vuong (doubles), ... (click for more)
The Southern League has announced that Chattanooga Lookouts' All-Star Daniel Palka has been named its Player of the Month for the month of June. The Lookouts outfielder's month got off to a great start when he slugged two home runs in back-to-back games against the Birmingham Barons. Palka followed that up with another outstanding week where he hit .345 (10-for-29) with ... (click for more)
Pensacola, Fl.. Chattanooga tagged the Blue Wahoos relievers to go on to win, 7-3, in front of 4,884 at Blue Wahoos Stadium. Ryan Eades improved to 5-3 with six strong innings. He gave up just one run on four hits. He walked three and struck out six. Jake Reed worked the next two innings. He gave up two runs on three hits and two hit batters. He did strike out four. Mason ... (click for more)
Authorities said a Signal Mountain man was driving when his vehicle struck and killed a woman walking along a road at Ringgold, Ga., on Thursday night. Tyler Alexander Lemley, 20, was charged with DUI. Other charges are pending. Kimberly Diane Dotson, 28, of Tunnel Hill, Ga., was walking southbound on the west edge of Sam Lewis Road when she was hit. Lemley was driving ... (click for more)
A Chattanooga woman has filed suit, alleging that her disabled daughter was roughed up by airport police and Transportation Security Administration personnel at the Memphis Airport. Shirley Cohen said she was returning to Chattanooga after taking her 19-year-old daughter to St. Jude Children's Research Hospital for treatment. The lawsuit filed in Memphis says the daughter ... (click for more)
So, am I the first to notice a trend? How many wrecks does exit 11 need before anyone asks "whats up with that?" I have lost count of the wrecks that continue to happen, even after last year's awful loss of life (which I believe 51 percent of the blame should fall on the THP officer on duty). The problem with this section of interstate are sight lines ... (click for more)
There are some institutions in the history of America that should be above the nauseating "political correctness" that is undermining America. One of the biggest is most certainly the United States Marine Corps. But Secretary of the Navy Ray Mabus has apparently and most unfortunately gone soft and the word is that in the coming days about 25 words that are primary to the Corps ... (click for more)


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Reviewed By Yvette M (FRENCH LICK, IN) Reviewed for a 2005 Dodge Ram —6/22/2016 4:53 AM
This thing will really make the turbo scream. I love the sound of it. The installation Wes a bit hard because the intake pipe hits the oil filter.
Reviewed By Todd S (SAINT ALBANS, WV) Reviewed for a 2016 Mazda Miata/MX-5 —3/17/2016 11:38 AM
I used this to cover and insulate the outside of the filter box of the ColdSport cold air intake system for my 2016 MX5 Miata. I found it very easy to work with and if you follow instructions, very easy to apply and have adhere to the outside of the box. Coupled with the Heatshield tape it resulted in a very professional appearance and function.
Discover what it takes to finish these easy DIY car upgrades.
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Ignore Everybody
and 39 Other Keys to Creativity
(If any tax is payable it will be calculated and shown at checkout.)
Preview (read now) Add to my own site Give this ebook to a friend Add to my wishlist Author's page Publisher's page
moreWhen Hugh MacLeod was a struggling young copywriter, living in a YMCA, he started to doodle on the backs of business cards while sitting at a bar. Those cartoons eventually led to a popular blog - gapingvoid.com - and a reputation for pithy insight and humor, in both words and pictures.
MacLeod has opinions on everything from marketing to the meaning of life, but one of his main subjects is creativity. How do new ideas emerge in a cynical, risk-averse world? Where does inspiration come from? What does it take to make a living as a creative person?
Now his first book, Ignore Everyone, expands on his sharpest insights, wittiest cartoons, and most useful advice. A sample:
*Selling out is harder than it looks. Diluting your product to make it more commercial will just make people like it less.
*If your plan depends on you suddenly being "discovered" by some big shot, your plan will probably fail. Nobody suddenly discovers anything. Things are made slowly and in pain.
*Don't try to stand out from the crowd; avoid crowds altogether. There's no point trying to do the same thing as 250,000 other young hopefuls, waiting for a miracle. All existing business models are wrong. Find a new one.
*The idea doesn't have to be big. It just has to be yours. The sovereignty you have over your work will inspire far more people than the actual content ever will.
After learning MacLeod's 40 keys to creativity, you will be ready to unlock your own brilliance and unleash it on the world. less
Penguin Publishing Group; June 2009
176 pages; ISBN 9781101057728
Read online, or download in secure EPUB
Title: Ignore Everybody
Author: Hugh MacLeod
176 pages; ISBN 9781101057728
Read online, or download in secure EPUB
Title: Ignore Everybody
Author: Hugh MacLeod
Buy, download and read Ignore Everybody (eBook) by Hugh MacLeod today!
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River Terrace apartments in Eugene, Oregon offer luxury 1 and 2 bedroom apartments and 2 bedroom townhouses. Full-size, side-by-side washer and dryer included. Outdoor sports court, indoor basketball court, spa and fitness studio are yours to enjoy. Located minutes from Eugene's largest mall, Valley River Center, you'll find plenty of activities to keep you busy.
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|Publication number
|Publication type
|Application number
|Publication date
|Feb 8, 1977
|Filing date
|Mar 21, 1975
|Priority date
|Mar 22, 1974
|Also published as
|Publication number
|Akio Miyamoto, Hiroharu Matsukawa, Nobuo Yamamoto
|Original Assignee
|Fuji Photo Film Co., Ltd.
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (1), Referenced by (9), Classifications (17)
|External Links: USPTO, USPTO Assignment, Espacenet
1. Field of the Invention
This invention relates to a method for desensitization using a desensitizing composition and, more specifically, to a method using a desensitizing composition which reduces or eliminates the effect of a developer (an electron accepting compound, e.g., a solid acid) capable of coloring a color former (a substantially colorless, electron donating organic compound).
2. Description of the Prior Art
It has long been known to form a color image through the reaction of a color former and a color developer. The principle is practically utilized in pressure sensitive copying sheets (as disclosed, for example, in U.S. Pat. Nos. 2,505,470, 2,505,489, 2,550,471, 2,548,366, 2,712,507, 2,730,456, 2,730,457 and 3,418,250) and heat sensitive recording sheets (as disclosed, for example, in Japanese Patent Publication No. 4160/68 and U.S. Pat. No. 2,939,009). Furthermore, a printing method has also been known in which a color image is formed by supplying an ink containing a color former through a medium such as a stencil to a sheet coated with a color developer (as disclosed in German Pat. No. 1,939,962).
Pressure copying sheets can be prepared by dissolving a color former in a solvent such as a chlorinated paraffin, an alkylnaphthalene, an alkylated diphenylethane or an alkylated diphenylmethane, dispersing the color former solution in a binder or microencapsulating the color former solution, and then coating the composition on a support such as a paper or a synthetic resin film, on the one hand, and coating, as a color developer, an acid clay, a phenol-formaldehyde resin, a metal salt of an aromatic carboxylic acid or the like, on the other hand.
Heat sensitive recording sheets can be prepared by coating, on a support, a color former and a color developer together with a heat-fusible substance such as acetanilide. Heat-fusible substances are those substances which melt by heating and dissolve the color former.
In general, a color former and a color developer are coated respectively over the entire surface of a support. Therefore, it is necessary to prevent a color reaction in some way in the portions in which the formation of a color image is not required or permitted. For this purpose, a desensitizing agent is usually coated by printing on certain portions of a color developer coated layer to prevent the color reaction. Known desensitizing agents, for example, include long chain primary alkylamines such as dodecylamine and quaternary ammonium salts such as dodecyltrimethyl-ammonium chloride as described in U.S. Pat. No. 2,777,780; monoalkylamines, alkylamines or tertiary amines comprising ethanolamine adducts with ethylene oxide as described in Japanese Patent Publication No. 29546/71; secondary alkylamines such as didodecylamine, tertiary alkylamines such as triethylamine, primary arylamines such as aniline or aralkylamines such as benzylamine.
However, conventional desensitizing agents have disadvantages and it is, therefore, desired to develop superior desensitizing agents.
Disadvantages of the conventional desensitizing agents are set forth below.
1. Insufficient desensitizing effects are exhibited by conventional desensitizing agents and, in particular, no effects are exhibited for xanthene color formers such as 7-diethylamino-3-dibenzylaminofluoran.
2. Conventional desensitizing agents have an unpleasant amine odor and the surface on which they are coated is colored.
3. The images formed, due to the color reaction, on the surface on which conventional desensitizing agent are coated undergo a marked discoloration and fading.
4. When conventional desensitizing agents are left together with microcapsules, swelling of the membranes of the microcapsules results, and as the case may be, the membranes can even be destroyed.
An object of this invention is to provide a method using a desensitizing agent which exhibits extremely high desensitizing effects on all color formers.
Another object of this invention is to provide a method using a desensitizing agent which neither has an unpleasant odor nor colors the surface on which the desensitizing agent is coated.
A further object of this invention is to provide a method using a desensitizing agent which does not cause any swelling or destruction of microcapsules.
Still a further object of this invention is to provide a method using a desensitizing agent which does not cause any discoloration or fading in the image formed by the color reaction.
After a great amount of research, it has been found that the above objects are completely accomplished with a desensitizing agent comprising the reaction product of (a) an alkylsiloxane, an alkylsilmethylene or an alkylsilane and (b) an alkylene oxide or an alkylene imine (wherein the alkylene imine may be a tertiary amine), by contacting the desensitizing agent or a desensitizing composition containing the desensitizing agent with a color developer.
The above organic silicone reaction products used in this invention (hereinafter compounds of the invention) are known as nonionic surface active agents containing silicon and are those compounds having a Si--O--Si bond, a Si--C--Si bond or a Si--Si bond in the molecule and containing an alkyleneoxy group or alkyleneimino group. These compounds can be synthesized, for example, by the methods as described in U.S. Pat. Nos. 3,057,901 and 3,299,112, Bulletin of the Chemical Society of Japan, 40, 2675 (1967) and Journal of Industrial Chemistry, 71, 1675-1682 (1968).
The reaction products of the alkylsiloxane, the alkylsilmethylene or the alkylsilane and alkylene oxide used in this invention include, preferably, the compounds represented by the following general formula: ##STR1## wherein Y represents ##STR2## Z represents ##STR3##
Et represents --O--CH2 CH2 --;
Pr represents ##STR4## R1, R2, R3, R4 and R5 each represents a hydrogen atom, a hydroxyl group, an alkoxy group (e.g., having 1 to 20 carbon atoms), an alkyl group (e.g., having 1 to 20 carbon atoms) ##STR5## X represents --O-- or --CH2 --; l is an integer of 1 to 50; m is an integer of 1 to 6;
n is an integer of 1 to 50;
a is 0 or 1;
b1 through b4 each represents 0 or 1;
p1 through p5 each represents 0 or an integer of 1 to 15;
q1 through q5 each represents 0 or an integer of 1 to 50;
and t1 through t4 each represents 0 or an integer of 1 to 5.
The positions for (Pr) and (Et) in the above general formula are interchangeable.
Typical examples of the compounds used in this invention are shown in the following: ##STR6##
The desensitizing composition used in this invention contains the above compound as a desensitizing component and, if desired, various additives.
The compound used in this invention can be present in the desensitizing composition in an amount which can vary over a wide range, but it is desired that about 1 to 60 wt%, particularly 15 to 55 wt%, of the compound of this invention be present in the desensitizing composition.
The other components which can be employed in the desensitizing composition of this invention include, for example, materials generally employed in printing inks as described in detail in E. A. Apps, Printing Ink Technology, Leonard Hill, Chapters 2 to 9, London, (1961), and examples of these material are natural or synthetic high molecular weight compounds (in most cases not necessarily, used as a binder) in an amount of about 5 to 30% be weight such as ketone resins, polyamide resins, maleic acid resins, phenol resins, epoxy resins, alkyd resins, melamine resins, urea resins, nitrocellulose, ethylcellulose, butyral resins, polyvinyl alcohol, gelatin or shellac; inorganic and organic materials in an amount of about 5 to 50% by weight such as titanium oxide, zinc oxide, barium sulfate, calcium carbonate, talc, daolin, clay, bentonite or organic bentonite; vegetable oils in an amount of about 5 to 40% by weight such as linseed oil, tung oil, soybean oil or cotton seed oil; organic solvents in an amount of about 5 to 40% by weight such as methanol, ethanol, ethyl acetate, toluene, xylene or hexane, waxes such as paraffin, Japanese wax or microcrystalline wax; anti-offset agents in an amount of about 0.5 to 5% by weight such as starch or dextrin; and other conventional desensitizing agents, e.g., as a replacement for some of the desensitizing agent of this invention.
A mixture of the compound used in this invention and a polyoxyethylenealkylamine is particularly advantageous because of the high desensitizing effects obtained. A preferred polyoxyethylene alkylamine includes an adduct of an alkylamine having 12 to 20 carbon atoms and 5 to 20 moles of ethylene oxide. A suitable amount of the polyoxyethylene alkylamine ranges from about 0 to 500%, preferably 50 to 200%, by weight of the polyoxyethylenealkylamine to the desensitizing agent used in this invention.
It should be noted that the effect of the desensitizing composition as described above is not influenced by the types and the amounts of other components incorporated in the composition, or the form of these other components employed. The desensitizing composition can, thus, be easily prepared and is applied to a color developer layer using methods, for example, printing such as relief printing, flexographic printing or photogravure, spraying using a spray or manually with the composition in a crayon-or eraser-like form. The amount of the desensitizing composition of this invention coated is about 0.8 to 8.0 g/m2, preferably 1.5 to 5.0 g/m2, as the desensitizing agent.
The color developers to which the desensitizing composition used in this invention is applicable are electron-accepting substances. They are well known in the art and include, for example, clay minerals such as acid clay, activated clay or attapulgite; organic acids such as tannic acid, gallic acid or propyl gallate; acid polymers such as phenol-formaldehyde resins or phenolacetylene resins (as described in Japanese Patent Publication No. 20144/67 and Japanese Patent Application (OPI) Nos. 9812/73 and 14409/73); metal salts of aromatic carboxylic acids such as zinc salicylate, tin salicylate, zinc 2-hydroxynaphthoate or zinc 3,5-di-tert-butylsalicylate (as described in Japanese Patent Publication Nos. 32011/73 and 33923/73); and mixtures thereof. The color developer is coated together with a binder such as a styrene-butadiene latex on a support such as paper, a synthetic resin film-laminated paper or other supports, e.g., in an amount of about 0.5 to 8 g (as color developer)/m2.
Color formers which react with the color developer to form a color are electron donating and substantially colorless organic compounds and include triarylmethane compounds, diphenylmethane compounds, xanthene compounds, thiazine compounds, spiropyran compounds and the like. Examples of triarylmethane compounds are 3,3-bis(p-dimethylaminophenyl)-6-dimethylaminophthalide, i.e., crystal violet lactone, 3,3-bis)p-dimethylaminophenyl)phthalide, 3-(p-dimethylaminophenyl)-3-(1,2-dimethylindol-3-yl)phthalide, 3-(p-dimethylaminophenyl)-3-(2-methylindol-3-yl)phthalide, 3-(p-dimethylaminophenyl)-3-(2-phenylindol-3-yl)phthalide, 3,3-bis-(1,2-dimethylindol-3-yl)-5-dimethylaminophthalide, 3,3-bis(1,2-dimethylindol-3-yl)-6-dimethylaminophthalide, 3,3-bis(9-ethylcarbazol-3-yl)-5-dimethylaminophthalide, 3,3-bis(2-phenylindol-3-yl)-5-dimethylaminophthalide and 3-p-dimethylaminophenyl-3-(1-methylpyrrol-2-yl)-6-dimethylaminophthalide. Examples of diphenylmethane compounds are 4,4'-bis-dimethylaminobenzhydrin benzyl ether, N-halophenyl-leucoauramine and N-2,4,5-trichloro-phenyl-leucoauramine. Examples of xanthene compounds are rhodamine B-anilinolactam, rhodamine(p-nitroanilino)lactam, rhodamine B-(p-chloroanilino)lactam, 7-dimethylamino-2-methoxyfluoran, 7-diethylamino-2-methoxyfluoran, 7-diethylamino-3-methoxyfluoran, 7-diethylamino-3-chlorofluoran, 7-diethylamino-3-chloro-2-methylfluoran, 7-diethylamino-2,3-dimethylfluoran, 7-diethylamino-(3-acetylmethylamino)fluoran, 7-diethylamino-(3-methylamino)fluoran, 3,7-diethylaminofluoran, 7-diethylamino-3-(dibenzylamino)fluoran, 7-diethylamino-3-(methylbenzylamino)fluoran, 7-diethylamino-3-(chloroethylmethylamino)fluoran and 7-diethylamino-3-(diethylamino)-fluoran. Examples of thiazine compounds are benzoyl-leucomethylene blue and p-nitrobenzyl-leucomethylene blue. Examples of spiro compounds are 3-methyl-spiro-dinaphthopyran, 3-ethyl-spiro-dinaphthopyran, 3,3'-dichloro-spiro-dinaphthopyran, 3-benzylspiro-dinaphthopyran, 3-methyl-naphtho-(3-methoxy-benzo)-spiropyran and 3-propyl-spiro-dibenzopyran.
The color former is dissolved in a synthetic or natural oil such as an alkylated diphenylmethane, an alkylated diphenylethane, an alkylated diphenyl, an alkylated terphenyl, a chlorinated paraffin, a chlorinated naphthalene, an alkylated naphthalene, kerosine, paraffin oil or naphthene oil, and then coated together with a binder on a support, e.g., in an amount of about 0.02 to 2.5 g (as color former)/m2. Alternatively, the color former can be encapsulated using the method as described in, for example, U.S. Pat. No. 2,800,457, and then coated on a support, if desired, together with additives, e.g., an anti-smudge agent such as starch particles. In addition, the solution of the color former can be coated only on predetermined portions of a support.
The color former and the color developer can be used in a form suitable for pressure sensitive recording sheets or heat sensitive copying sheets as described above or for any other purposes.
This invention will be explained in greater detail by way of the following examples, by which the excellent effects of this invention can be seen.
The color developer sheets, color former sheets and desensitizing compositions, which were used in the examples to demonstrate the effects of the use of desensitizing agents, in the present invention, were prepared in the following manner. Unless otherwise indicated, all parts, percents, ratios and the like are by weight.
100 Parts of acid clay which had been treated with sulfuric acid was dispersed in 280 parts of water containing 10 parts of a 20% sodium hydroxide aqueous solution using a homogenizer, and to this, 10 parts of a 10% aqueous solution of the sodium salt of a methyl vinyl ether-maleic anhydride copolymer and 37 parts of a styrene-butadiene latex were added. The coating composition was coated on a support paper of 50 g/m2 using air knife coating so as to provide a solid content of 10 g/m2 and then dried, thus preparing an Color Developer Sheet A.
170 Parts of p-phenylphenol, 70 parts of a 37% aqueous solution of formaldehyde and 50 parts of water were heated at 160� C in the presence of conc. hydrochloric acid (as a catalyst) to condence the p-phenylphenol and formaldehyde, and then cooled to produce powdered phenol resin.
50 Parts of the phenol resin, 10 parts of polyvinyl alcohol and 500 parts of water were blended in a ball mill for 10 hours to produce coating composition (Coating Composition B).
Coating Composition B was coated on a support paper of 50 g/m2 so as to provide a solid content of 2 g/m2 and then dried, thus preparing Color Developer Sheet B.
4 Parts of sodium hydroxide was dissolved in 200 parts of water, and then 25 parts of 3,5-di-tert-butylsalicylic acid was dissolved therein while stirring.
Moreover, a solution of 7 parts of zinc chloride dissolved in 100 parts of water was slowly added to the above solution while stirring. Then, 50 parts of a 10% aqueous solution of polyvinyl alcohol was added, and blending was effected in a ball mill for 10 hours to produce Coating Composition C.
Coating Composition C was coated on a support paper of 50 g/m2 so as to provide a solid content of 2 g/m2 and then dried, thus preparing Color Developer Sheet C.
A coating composition obtained by blending 35 parts of Coating Composition B, 50 parts of Coating Composition C and 15 parts of pyrophyllite clay in a ball mill for 10 hours, Coating Composition D, was coated on a support paper of 50 g/m2 so as to provide a solid content of 2 g/m2 and then dried to produce Color Developer Sheet D.
10 parts of acid-treated gelatin having an isoelectric point of 8.0 and 10 parts of gum arabic were dissolved in 60 parts of water at 40� C, and 0.2 parts of a sodium alkylbenzenesulfonate was added as an emulsifier thereto. Then, 50 parts of a color former containing oil was emulsified therein.
The above color former containing oil was prepared by dissolving 2.5% by weight of crystal violet lactone and 2.0% by weight of benzoyl-leucomethylene blue in an oil comprising 4 parts of diisopropylbiphenyl and 1 part of kerosene.
When the size of the emulsion droplets reached 8 μ on the average, 100 parts of water at 40� C was added to inhibit further emulsification.
While stirring, 210 parts of water at 30� C was added, and then a 20% hydrochloric acid aqueous solution was added to adjust the pH of the system to 4.4. The system was cooled to 8� C with further stirring, and then 1.5 parts of a 20% glutaraldehyde aqueous solution was added.
Subsequently, 30 parts of a 10% carboxymethyl-starch aqueous solution was poured therein, a 25% sodium hydroxide aqueous solution was added dropwise to adjust the pH to 8.5, and then the temperature of the system was increased to 30� C to form microcapsules having hardened capsule walls.
10 Parts of cellulose flock was dispersed in the composition thus obtained, and then the composition was coated on a paper of 40 g/m2 so as to provide a solid content of 6 g/m2, thus preparing Color Former Sheet A.
A color former-containing oil was prepared by dissolving 1% by weight of crystal violet lactone, 4% by weight of 7-diethylamino-3-dibenzylaminofluoran, 4% by weight of 3-diethylamino-7-phenylaminofluoran, 3% by weight of 3-diethylamino-7,8-benzofluoran, 0.5% by weight of 3,6-bis-methoxyfluoran and 2% by weight of benzoyl-leucomethylene blue in a mixture of 1 part of diisopropylnaphthalene, 1 part of diisopropylbiphenyl and 2 parts of 1-(dimethylphenyl)-1-phenylethane. Color Former Sheet B was prepared using 50 parts of the color former-containing oil in the same manner as in the preparation of Color Former Sheet A.
25 Parts of an alkyd resin which had been modified with linseed oil and 75 parts of titanium oxide were uniformly blended on a three-roller mill to prepare a base composition. 4 parts of the base composition and 1 part of a desensitizing agent as shown in the following table were uniformly blended on a three-roller mill to prepare a desensitizing composition.
A. Each desensitizing composition was coated by printing on Color Developer Sheets A to D so as to provide 5.0 g/m2 of the composition. The desensitized areas on the resulting samples and the color former sheets were stacked facing to each other, and a load of 600 kg/m3 was applied to cause color formation. After irradiation of the sheets with ultraviolet light for 20 minutes by means of a Fade-o-meter, the sheets were left in the dark for 24 hours. The density was determined using a densitometer, and the desenstization was evaluated from the obtained relection visual density (Vis. D).
B. A paper coated with 5.0 g/m2 of each desensitizing composition (a sheet obtained in the same manner as in (A)) was tested by writing manually with red, blue and black ball-pens and a fountain pen, and the discoloration and fading of the colored images were observed after the sheet was left for 1 week.
__________________________________________________________________________ Densitization (Vis. D) Color FormerExample Color Former Sheet A Sheet B Discolora-and Color Color Color Color Color tion andReference Desensitizing Developer Developer Developer Developer Developer Fading ofNo. Agent Sheet A Sheet B Sheet C Sheet D Sheet A Image*__________________________________________________________________________Example 1 Compound 22 0.05 0.05 0.05 0.05 0.07 0Example 2 Compound 18 0.05 0.05 0.06 0.06 0.08 0Example 3 Compound 1 0.05 0.05 0.05 0.05 0.08 0Example 4 Compound 2 0.05 0.05 0.05 0.06 0.07 0Example 5 Compound 3 0.05 0.05 0.05 0.06 0.08 0Example 6 Compound 5 0.05 0.05 0.05 0.05 0.08 0Example 7 Compound 6 0.05 0.05 0.05 0.06 0.08 0Example 8 Compound 7 0.05 0.06 0.06 0.06 0.08 0Example 9 Compound 9 0.05 0.05 0.05 0.05 0.08 0 Example 10 Compound 17 0.05 0.05 0.06 0.06 0.08 0 Mixture of Example 11 Compound 21 0.05 0.05 0.05 0.05 0.07 0 and Compound A (2:1 by weight mixture)ReferenceExample 1 Compound B 0.09 0.10 0.10 0.10 0.17 XReferenceExample 2 Compound C 0.05 0.07 0.06 0.06 0.10 XReferenceExample 3 Compound D 0.05 0.06 0.06 0.06 0.09 XReferenceExample 4 No desensitiz- 1.08 1.05 0.94 1.04 1.10 -- ing treatment__________________________________________________________________________
______________________________________Compound A ##STR7##Compound B Dodecyltrimethylammonium ChlorideCompound C ##STR8##Compound D ##STR9##______________________________________ *O: No discoloration and fading X: Marked discoloration and fading
The same test as described above in Example 11 was carried out using a mixture comprising Compund 17 and a compound of the formula ##STR10## The results obtained were the same as obtained in Example 11.
The result above clearly demonstrate the utility of the compounds used in this invention. That is, the smaller the value of the desensitizing effect (Vis. D), the higher the effect, and a value less than 0.08 denotes a complete desensitizing effect. Therefore, it can be seen that the compounds used in this invention provide complete desensitizing effects on any of the color developers such as acid clay, a phenol-formaldehyde resin and a metal salt of an aromatic carboxylic acid. Moreover, as can be seen from the results above, the compounds used in this invention provide complete desensitizing effects as to a color former sheet containing 7-diethyl-3-dibenzylfluoran as a color former.
Conventional desensitizing agents cause a marked discoloration and fading of the images formed, while the compounds used in this invention scarcely cause a discoloration and fading of the images formed.
In addition, the compounds used in this invention are colorless and odorless and are considered not toxic in practice. Also, the compounds used in this invention do not cause the walls or microcapsules to swell, and thus the effects of this invention are obviously excellent.
While the invention has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.
|Cited Patent
|Filing date
|Publication date
|Jun 19, 1964
|Jan 17, 1967
|Union Carbide Corp
|Siloxane wetting agents
|Citing Patent
|Filing date
|Publication date
|Oct 27, 1976
|Feb 14, 1978
|Fuji Photo Film Co., Ltd.
|Method for desensitization of a color developer
|Jan 31, 1977
|Aug 29, 1978
|Salvat Editores, S. A.
|Process for accelerating the drying of offset inks
|Aug 10, 1977
|Oct 30, 1979
|Fuji Photo Film Co., Ltd.
|Desensitizer compositions
|Aug 30, 1978
|Mar 25, 1980
|Wallace Business Forms, Inc.
|Method of desensitizing carbonless paper
|Oct 12, 1977
|Dec 2, 1980
|Kanzaki Paper Manufacturing Co., Ltd.
|Heat-sensitive record material
|Dec 13, 1979
|Sep 22, 1981
|Mitsubishi Paper Mills, Ltd.
|Desensitizer for no-carbon copy paper
|Jan 21, 1986
|Oct 27, 1987
|Mitsubishi Paper Mills, Ltd.
|Heat-sensitive and heat-transferable recording sheet
|Apr 20, 1988
|Mar 12, 1991
|Imperial Chemical Industries Plc
|Composition and use
|Jun 16, 1993
|Mar 9, 1999
|Xerox Corporation
|Ink jet printing process for desensitizing carbonless paper
|U.S. Classification
|503/201, 503/205, 428/447, 428/914, 428/913, 427/151, 101/465, 427/150, 428/207, 428/446
|International Classification
|Cooperative Classification
|European Classification


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If everything breaks right for China Rats in the next few months, they will be 2013's answer to the Vaccines 2011 campaign. The Leeds band channels more Ramones pop-brut than the Vaccines ever did, but the insistent drums and shout-along refrains are the common thread. "To Be Like I" is a revolving door rock song, spinning and spinning in place, joyfully centered on the title lyric. The band will play SXSW in a few months time, and have a coming single to back "To Be Like I" and the band's other recent raucous single, "N.O.M.O.N.E.Y." With a big following in the UK, in the ever-evolving American "now", China Rats are in the pregnant moment before things either happen or don't, like "To Be Like I", full of potential, brash and uncertainty.
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You may recall that the day before Audi released details and drawings of the Frankfurt-bound Audi urban Concept , the car skinned with psychedelic test mule camouflage raised eyebrows when it made a brief appearance in a busy section of Berlin. Now, Audi has released a teaser made from footage shot that day. Watch it below.
We've stumbled across an interesting idea today that is making us sit up and take notice, partially because it's a very interesting concept and partially because we've wanted Audi to do this for years. As most read yesterday, Ingolstadt plans to show off a super light and super efficient city car dubbed 'Audi urban concept'
Audi's growing prominence within the world's luxury car market is about to be witnessed first hand at the world's largest industry auto show in Frankfurt this September. The New York Times is reporting that the brand has commissioned a 15,000 square meter temporary structure convention hall by Munich-based architecture firm Schmidhuber & Partner.
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AROUND THE JEWISH WORLD Popular Latin dance music prominent at Jewish eventsSeptember 2, 1997 9:00am
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A Soweto principal is under investigation for allegedly assaulting a teacher. Philip Mabalane allegedly assaulted Grade 4 teacher Xolani Miya in front of pupils last week. The incident sparked fury among a group of parents who locked Mabalane out ...Sowetan, 3 weeks ago Terrified teachers boycott classes after pupil hacked with panga at school assembly Sowetan, 4 weeks ago Teacher beats learner for wearing wrong uniform Citizen.co.za, 2 months ago Teacher 'assaults' pupil for wearing wrong school uniform Sowetan, 2 months ago
New arts fest recognises local talent
The inaugural Soweto Street Culture Arts Festival was held in the vibey Vilakazi Street's The Box on Sunday. Featuring local music, stalls, arts and crafts on display, the festival was aimed at recognising black artists and businesses. The ...Citizen.co.za, 3 weeks ago
Two ANC regions stage protests over election lists at party conference
Image by: Siviwe Feketha/Sowetan Disgruntled ANC delegates have converged outside St Georges Hotel in Irene in Pretoria where party leaders are meeting to decide on the list of candidates to represent the organisation in the upcoming local ...Times Live South Africa, 4 weeks ago
Willies Mchunu delivers anti-xenophobia message' enlivened by a brass band' drum majorettes and African dancers
Willies Mchunu. File photo Image by: THULI DLAMINI Sowetan. KwaZulu-Natal Acting Premier Willies Mchunu led Africa Day celebrations in KwaDukuza in his first official engagement on Wednesday. Save & Share Related News Mchunu supporters to ...Times Live South Africa, 1 month ago
The three member group called Four
God family music and their fans - that is the fourth member of 3 man band Four. SowetanLIVE met up with the inaugural winners of X- Factor South Africa David, Jethro and Steven , who make up the group FOUR. We immediately noticed how in sync ...Sowetan, 1 month ago
Pastor Mboro opens two cases of theft over 'stolen' cars
Pastor Paseka (Mboro) Motsoeneng of Incredible Happenings Ministries. File photo. Image by: Gallo Images / Sowetan / Veli Nhlapo Leader of Incredible Happenings Ministries prophet Paseka "Mboro" Motsoeneng has opened two cases of theft against ...Times Live South Africa, 1 month ago
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The Colorado Avalanche are permitted to sign Matt Duchene to a long-term extension as early as this summer. That's what the club should and most likely will do, according to Adrian Dater of the Denver Post. Not only to ensure Duchene remains with the organization beyond 2013-14, but as means to re-establish a proper "locker-room salary hierarchy". Remember, the Avs were pressured to match the Calgary Flames' $10 million offer sheet for Ryan O'Reilly once negotiations with the then-restricted free agent spiralled out of control this winter.
Links from around the rink for April 20
433dDoug Mittler
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447dDoug Mittler
Links from around the rink for March 23
461dDoug Mittler
What's next: Minnesota Wild
473dVictoria Matiash
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474dTim Kavanagh
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474dVictoria Matiash
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Links from around the rink - March 9
475dDoug Mittler
What's next: Dallas Stars
475dVictoria Matiash
What's next: St. Louis Blues
476dVictoria Matiash
What's next: Florida Panthers
476dVictoria Matiash
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476dTim Kavanagh


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New Orleans, LAUSA
June 9, 2011
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