text:
Game Questions & Answers (Q&A) service lets you ask questions about video games for game consoles or PC games. So ask your Fable 3 question for Xbox 360 and get answers from real gamers or answer questions and share your insights and experience with the rest of the gaming community.
- Developer: Lionhead Studios
- Publisher: Microsoft Game Studios
- Genre: Role-Playing
- Release: Oct 26, 2010
- ESRB: Mature
Question & Answers
How do i get into demon doors
How do i get into the mourningwood demon door?
Answer from: sunnwolf
The mourningwood demon door, which is located in the swampy area on the way to the sewers of bowerstone. in my opinion, it's also the fable 3 demon door with the best name. i mean, mourningwood? really? that's hilarious. at any rate, this particular demon door is looking for 'an enormous weapon greater than anybody else's because he's decided that war will never end until the hero has a weapon that will kill everyone who would consider waging war. nice theory, mr. demon door: wage war to end war. anyway, you probably want to know exactly how to open this demon door. well, it's not as complex as it sounds, although it definitely requires some specific combat: you need to show him a maxed-out legendary weapon, which you can achieve by meeting three distinct objectives that are associated with but vary based on the legendary weapon you have equipped. then, you also need to purchase either the melee or ranged level 5 upgrade, both of which are available only at the very end of the road to rule. do these things, and you'll get to open the mourningwood demon door and reap the rewards: a military costume and a summon creatures potion. yeah, it's kind of a piddly reward for all that work. i guess not every fable 3 demon door can be an all-star, eh?
Answer from: king jaws
You have to have a level 5 melee weapon to open it no less
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text:
Hay Creek Hotels to Open, Manage Porter Square Hotel
Tuesday January 7th, 2014 - 10:35AM
These are shortcuts to your favorite social networking and bookmark sites. Add this story to your Facebook page, del.icio.us, DiggIt, and many others!
CAMBRIDGE, MA—Hay Creek Hotels is under construction with the Porter Square Hotel, with plans for a grand opening in spring 2015.
The property is situated in Porter Square, close to both MIT and Harvard University, as well as numerous commercial and tourist destinations.
The hotel will offer 70 guestrooms and feature a signature-style restaurant and bar with a seasonal open-air patio along Massachusetts Ave. The hotel also will include a private dining room, and meeting and banquet facilities. An outdoor walking garden is planned for meditation, yoga and reading.
The hotel is being constructed by Newton, MA-based Young Construction and is the product of an extensive, community-based design that resonates with the local neighborhood and the city, according to the company.
The project has special meaning to Hay Creek Hotels' President/CEO, Norman MacLeod, who grew up in Cambridge. "I've managed many hotel properties around the world," stated MacLeod, "but nothing is more special than being able to return home to combine my professional experience and local roots in managing this hotel.
"The City of Cambridge is booming right now and the need for a new, upscale independent hotel is paramount" MacLeod added. "There is a special niche of traveler who appreciates a small, non-branded hotel...a non-cookie-cutter property that reflects the special location that it is in."
Tags: Hay Creek Hotels • Porter Square Hotel • Norman MacLeod • Hospitality • Construction/Renovation • Management Companies •
With all of the question marks that always exist when it comes to navigating current conditions and forecasting future ones—i.e. the all-too-common inning analogy—and calls to action to advocate for the hospitality industry, one thing seemed overwhelming clear: the reminder that with all of the concerns and considerations, the hotel business is experiencing opportunity that is at an all-time high.
MORE ON BREXIT: Insight from Ravneet Bhandari
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Anbang to Convert Waldorf Astoria New York Into Condos »
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From JPCL, March 2012
Are You Getting What You Deserve?...
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NFL power rankings: Week 2
See the list » 10 items « Previous List
Associated Press
Week 1 of the NFL is in the books, but what did we learn? We learned the Colts are doomed without Peyton Manning. We learned that the new kickoff rule apparently didn't cripple the most exciting play in the game. And we learned that Tom Brady is still really, really good. Here's our Top 10 for Week 2.
See the list » 10 items « Previous List
- Oldest first
- Newest first
- Most recommended
Payson, UT
Only problem is putting green bay over the pats.
If you watched both games, there is no way the pats aren't number 1. impressive win and domination on the offensive side of the ball.
Green bay looked good, but they nearly lost the game ... and that against a saints team that didn't look that great until the 4th quarter.
- 1:18 p.m. Sept. 14, 2011
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Blanding, UT
packers #1 their thge best
- 7:48 p.m. Sept. 15, 2011
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|Sent on:
|Tuesday, March 27, 2012 11:29 AM
Here we are now headed into Spring and along with that comes the usual Spring Fever! The antsy-ness to get out and do stuff, the joy of spending time outside again, and yes, possibility of meeting that special someone! Well we wanted to give you all three! Thus, we present to you, oh wonderful Tri-Staters:
Shipboard Speed Dating!
Come join us on our wonderfully outfitted private charter boat on Wednesday, April 18th while we cruise up the East River looking for love. There will be a limit of 60 couples due to space requirements so make sure to sign up early! The boat will board at 7:00 pm, leave the dock at precisely 7:30 and will leisurely cruise up the East River. Enjoy an hour of drinks and mingling as you take in the gorgeous views of NYC with a full bar of beers, wines and liquors to get loosened up! Tickets are now more than 30% off from $60 to $39 for boat ticket and speed dating admission (and salsa upstairs afterwards!)
Then we will sit and get to know each other! We will have you sit down with paper and pencils and spend 5 minutes with each of your potential soul mates. At the end of each 5-minute period we'll ring a bell and then shift to meet the next sexy single. Midway through we'll take a 20 minute break to refill that drink or to just take a breather. After the second half we'll collect all the results and you can either mingle or go upstairs to join in the fabulous Salsa night happening on board featuring Feel The Music Dance Studio! We will tally the results and let you know as you leave the boat who your new matches are!
What better way to spend a spring evening than with a drink in hand, water below and potential loves all around?!
Come and set sail for love! Look forward to meeting you all there!
New York Skyport Marina
2430 FDR at E. 23rd Street
New York, NY 10010
TICKETS ARE $39 PER PERSON. MUST USE THIS LINK - http://bit.ly/x2nlu9
Meetup members, Log in
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Reading mode: Light Dark
FujiFilm FinePix F500 EXR (FinePix F505 EXR)
Announced Jan 5, 2011 •
16 megapixels | 3″ screen | 24 – 360 mm (15×)
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Product description
Announced Jan 5, 2011
Discuss in the Fujifilm FinePix Talk forum
Built around the same design and core feature set as its F300 EXR camera, the F500 EXR offers the company's latest 16Mp EXR CMOS sensor that allows full 1080p HD video recording and full-resolution 8fps continuous shooting. It includes the same 15x (24-360mm) optical zoom lens and 460K 3.0" LCD screen as the F300 EXR, as well as Fujifilm's innovative hybrid autofocus system that the company claims is as fast as that on DSLRs. The camera automatically chooses between using the contrast-detection AF method used in compact cameras and the phase-detection method usually used in DSLRs. The key differences between the F550 EXR (released at the same time) and the F500 EXR are the F550's GPS and RAW shooting capabilities.
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|4608 x 3456
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|1/2" (6.4 x 4.8 mm)
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|Auto, 100, 200, 400, 800, 1600, 3200 (6400 and 12800 with boost)
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|24–360 mm
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|1/2000 sec
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|USB 2.0 (480 Mbit/sec)
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|215 g (0.47 lb / 7.58 oz)
|104 x 63 x 33 mm (4.09 x 2.48 x 1.3″)
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Enjoy it now
MetService forecasts rain, cooler temperaturesALANA DIXON
Relevant offers
Make the most of the sunshine today, Southland - it might be a few days before it is this warm again.
The region has been bathed in sunshine since early this morning, with temperatures reaching a high of 19 degrees in both Invercargill and Gore.
The MetService predicts the warm weather will continue for the rest of the day, falling to an overnight high of 7 degrees in Invercargill and 8 degrees in Eastern Southland, before cooling off again tomorrow.
The temperature in Invercargill is expected to drop to a high of 15 degrees tomorrow, with fine spells and a chance of afternoon showers, before hitting a high of 17 degrees again on Friday.
However, the forecast for the weekend is not too flash - highs of 14 degrees and rain are expected on both Saturday and Sunday, the MetService says.
The rain is expected to hang around until Thursday, next week.
In Gore, the forecast is nearly identical - lower temperatures tomorrow, with some showers, before rain sets in on Saturday.
Rain will also follow warm temperatures of 18 and 19 degrees in Wanaka, setting in on Saturday. It is expected to clear there by Wednesday. However, it will be wet and warm, with forecast temperatures expected to hover about 20 degrees.
Queenstown will also fare a bit better than the deep south, the MetService says, with temperatures remaining in the high teens until showers arrive on Saturday, before the temperature reaches 19 degrees on Monday.
- The Southland Times
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text:
It Appears that the Zionists are realizing that they have OVERREACHED AGAIN!!
As they have done so often in the last 2000 years!
Because it caused the breakup of Europe. Not because too many foreigners were brought in.
Merkel's open door policy has brought 'chaos' to Europe,
GOOD NEWS: Rubio Faces Trump-Like Challenger in Primary
See original article at: Rubio faces Trump-like challenger in primary | TheHill
Heh, Heh ...What further evidence does one need to understand the NWO drive to forcibly integrate sub-Saharan congoids w/ N. African Taureg tribesmenFriendofRPO 8 Hours Ago


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RRRC/Hope Springs Rufsail Puppy Futurity winners - Chesapeake Bay Retriever Hunting Dog Pictures
Breed: Chesapeake Bay Retriever
From: Julie Reardon
Website: http://www.rrrclub.com/
Posted: Apr 21, 2009
First time Chesapeake owner Bruce Piner of Fredericksburg, Va., had never tried any kind of retriever competition before he entered his new puppy in the Rappahannock River Retriever Club's puppy futurity. Piner was expecting to have fun, let his pup retrieve a few pigeons, and meet some people to train and possibly duck hunt with, having recently moved to the area from S.C.
But Teach, a brown, 12-week-old male Chesapeake Bay Retriever puppy, not only had fun retrieving pigeons, he earned the blue ribbon at the Hope Springs Rufsail Memorial Puppy Futurity held in Remington Va., April 10th. Judges Heather Hauser and Ginny Reed, both from Pennsylvania, had a talented group of pups and needed a run-off to pick the winner.
It was fitting that Teach, a son of Hope Springs Rufsail JH**WDX and Tugboat Woods Colt MH WDQ, won the event, named in honor of his late mother who died unexpectedly a few weeks before the event. Piner, an ex Marine, named Teach after an infamous pirate from the 17th century.
Teach was bred by Julie Reardon of Hope Springs Farm in Orlean, Va. Among the puppies he bested to earn his blue ribbon was his litter sister Hope Springs Tanganyika, an ash female owned by Reardon and Alan Sandifer of Mississippi. She was equally keen to retrieve, but a bit less willing to return with her pigeon, insisting on parading around and showing it off to the other puppies and making Reardon chase her down before she allowed herself to be caught. For her naughtiness she earned the special Thug puppy award.
The Thug award was given to the puppy that displayed the most creative disobedience. "It's for the puppy who shows talent, but knocks itself out of contention," explained one of the judges. "It's an award for a puppy that you can't give the first place ribbon to, but you'd still like to own it."
The second and third placed pups were large, black 4 month old Labrador Retrievers that traveled from N.C. for the event. The puppy futurity, a non-AKC event, was held during the club's AKC Hunting Test over Easter weekend.


text:
Water's Edge is a small park. When people book, then cancel, it causes two primary issues: 1. Folks who might have stayed there book at alternative places. 2. There are costs associated with running a business. It takes someone time to make the booking, check folks in, update the data base, etc. When the reservation is canceled without benefit of the revenue, certain costs still are incurred. The $ 20 cancelation fee is fair and clearly stated on the website.
Vinita Campgrounds
1. Park Hill Motel & Rv Park
438415 E Highway 60Vinita, OK 74301
2. Water's Edge RV & Cabin Resort
Water's Edge is a small park. When people book, then cancel, it causes two primary issues: 1. Folks who might have stayed there book at alternative …
3. Deer Run RV Park
54200 E Highway 85AAfton, OK 74331
4. Grand Lake RV Resort
31669 S 4510 RdAfton, OK 74331
5. Horse Creek Resort
We have had our rv in this park for over 3 years and have been very pleased. You can't live there, but can go as often as you want. they are very re…
6. Deer Run RV Park
54504 E Bambi DrAfton, OK 74331
7. Bernice Point Resort
500 E Main StBernice, OK 74331
8. Pine Lodge Resort
33635 Dock RdAfton, OK 74331
9. Grand Lake RV Resort
31625 S 4510 RdAfton, OK 74331
10. Grand Country Lakeside RV Park
Great surprise, mowed lawn, tall trees, within yards of Grand Lake, clean showers, no ants or poison ivy, wonderful breeze, pleasant host. And a rea…
11. Monkey Island RV Resort
56140 E 280 RdAfton, OK 74331
12. Cottonwood RV Park
Friendly owners with reasonable rates. Easily located right off the highway with a great country atmosphere. Would recommend this RV park to anyone!…
13. Class A RV Repairs
Serving the Vinita Area.
Showing1-13 of 13results
i would like to thank waters edge rv park we were scheduled to go there for a weekend and left friday at 4'pm on the road we broke down and had to have the truck towed to a dealer and then get another tow truck to take the 5th wheel home, waters edge didnt charge us for a cancellation and was very understanding, i cant wait to go there and stay, especially if the staff is this understanidng. Dale and Cathy Osbortne Broken Arrow Oklahoma


text:
Purple Calla lily (Liliaceae), close-up
Credit: joSon
Creative #: 200298801-001
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text:
Excellent focus point and great color balance cordial greetings from Miami Fl (Like + Favorite)
I'm thankful
2 all friends
4 the comments
& the gifts Fs:4 + Ls:16 :-)
Este foto es maravillosa! Buenas noches desde Paris, Cathy.
Sehr schön dieser Blick zur Seebrücke. Like 19
Gruß Manfred
ขอบคุณมากครับ Fen
Hi, Stathis
very beautiful capture L&F
best regard 蒂芙尼 林
great scenery shot, kind rgrds
Harika bir fotoğraf olmuş. Tebrik ederim. Bursa Burun Estetiği
For me, this is a very interesting capture.
This is an amazing photo.
I think it is a nice picture. Thanks you for sharing. Of course, I LIKE this photo.
See you soon… Best regards from Grasse, in France.
Thank you very much !
Friendly greetings , Mircea R.


text:
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Advocacy, support and services for people with intellectual and developmental disabilities and their families.
Best in the West Newsletters & E-Blasts Golf Classic The Arc Calendar Kathy Moody Memorial Scholarship SNEAK Community
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text:
|Publication number
|Publication type
|Publication date
|May 16, 1972
|Filing date
|Apr 3, 1969
|Priority date
|Apr 3, 1969
|Publication number
|Bodre Robert J, Pinkerton Kirby Allan
|Original Assignee
|Monsanto Co
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (15), Referenced by (38), Classifications (9)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent Bodre et a1.
[ 51 May 16,1972
[54] METHOD OF PREPARING CHROMATOGRAPHIC COLUMNS [72] Inventors: Robert J. Bodre; Kirby Allan Pinkerton, both of Texas City, Tex.
[73] Assignee: Monsanto Company, St. Louis, Mo.
[22] Filed: Apr. 3, 1969 [21] Appl. No.: 813,144
[52] US. Cl ..117/63, 117/95, 117/119.6, 117/161 UT, 55/386, 210/31 C, 210/198 C [51] lnt.Cl. ..C01n 31/08 [58] Field ofSearch ..1 17/62, 63, 95; 55/67, 197, 55/386; 210/31, 31 C, 198 C [56] References Cited UNITED STATES PATENTS 3,547,684 12/1970 Hollis et a1 ..55/67 3,295,296 11/1967 l-lalasz et a1 ...55/67 3,322,695 5/1967 Alfrey et a1. ..260/3l.2 R 3,357,158 12/1967 Hollis ..55/67 3,347,020 10/1967 Van Venrooy ....55/386 3,407,573 10/1968 Crowley ..55/386 Recorder Ii 2 C Primary Examiner-William D. Martin Assismnl ExaminerM, Sofocleous AImrn vC. James Bushman, Elizabeth F, Sporar and M. N. Cheairs [57] ABSTRACT A method of preparing chromatographic columns of the Golay type having substrates of porous polymeric materials which comprises coating the inside surface of a tubular member with a mixture comprising one or more polymerizable monomers, at least one of which is a polyvinyl monomer, and a solvent which is miscible but nonreactive with said monomer, polymerizing the monomer or monomers and removing any unreacted components.
16 Claims, 1 Drawing Figure Response i s o-Pentuno1 1-Butanol o-Butanol i o--Propanal Start Analysis Ethanol Methanol Start Temperature Program PATENTEUMAY 16 I972 E0521 S PSaEw 7.2m
Ecu m d 5 4 3 2 I wmcoamwm 528mm Time (min.)
INVENTOR. Robert J. Bodre BY K. Allan Pinkerton AGENT METHOD OF PREPARING CHROMATOGRAPHIC COLUMNS BACKGROUND OF THE INVENTION The present invention relates to separation columns for use in chromatography. More particularly, the present invention relates to a method for the preparation of porous packed chromatographic columns of the Golay type. The practice of gas chromatography is well known and extensively used. Briefly, the technique involves passing a fluid sample, generally in the gaseous state, through a chromatographic column either with or without the aid of an inert carrier gas, the components of the sample being separated into chromatographic fractions based on the different absorptive affinities of the sample component in or with a liquid or solid. The chromatographic separation column can be of various types depending upon the sample being analyzed, the type of separation desired, etc. Generally, the separation columns comprise tubular conduits packed with the substrate.
The use of capillary columns, particularly of the Golay type, has found widespread use because of the fact that the columns give markedly better resolution than larger diameter columns.
Furthermore, conventional columns in which a porous polymeric material in the form of a gel, powder or bead is used as a substrate, have been found to be useful in separating compounds from water. Unfortunately, because of the extremely small diameter of capillary columns, i.e., Golay columns, it is virtually impossible by ordinary techniques to pack such columns with porous polymeric substrates and thus obtain the advantages of such porous substrates in small diameter columns. Moreover, because of the fact that very small diame ter particles of the porous polymers must be used to obtain maximum separating efficiency, even non-capillary columns have a tendency to severely pack with the result that very high carrier gas pressures are needed to obtain reasonable flow rates through the column.
SUMMARY OF THE INVENTION It is, therefore, an object of the present invention to provide a new and improved method for the preparation of gas chromatographic separating columns.
It is a further object of the present invention to provide a method for preparing gas chromatographic capillary columns having a substrate comprised ofa porous material.
Still a further object of the present invention is to provide new and improved gas chromatographic columns.
These and other objects of the present invention which will be apparent from the description given herein and the appended claims can be accomplished by a method of preparing chromatographic columns comprising coating the inside surface of a tubular member with a mixture comprising at least percent by weight of at least one liquid polyvinyl monomer and a solvent, said solvent being miscible and non-reactive with said monomer, polymerizing said monomer, and removing any unreacted components from said member.
In a more preferred embodiment, the tubular member is filled with water after the inside surface thereof has been coated but prior to polymerizing the monomer.
In an even more preferred embodiment, the mixture contains in addition at least one monoethylenically unsaturated monomer copolymerizable with the polyvinyl monomer.
DESCRIPTION OF THE PREFERRED EMBODIMENTS By the use of the present invention, it is possible to effect in situ preparation of the substrate thus avoiding the necessity for having to pack the column with a solid particulated matter. The substrate produced by the method herein are of the microporous type. Such substrates are generally comprised of cross-linked insoluble organic polymers.
In preparing the columns of the instant invention, a mixture of a suitable monomer and solvent and preferably a free-radical catalyst is first used to coat the inside of the tubular member which is to be used as the column. As used herein, the
terms monomer and solvent are intended to include not only a single monomer or a single solvent but a mixture of monomers or solvents, respectively. Generally speaking, the tubular member will have an internal diameter of from about 0.25 to about 2.00 mm. It is to be understood, however, that the method can be applied to the preparation of columns having large diameters if desired. The length will, of course, depend on the type of separation desired and is, therefore, completely a matter of choice. The column length can, for example, range from several feet to 1,000 feet and longer, columns from 2 to 300 feet, however, being generally preferred.
The polymerizable mixture containing the solvent, the monomers and the catalyst, if used, can be pulled through the tubular member by means of suction, allowed to flow through the column by gravity or forced through with pressure using an inert gas. Once the inside surface of the tubular member has been completely coated, it is desirable to flow an inert gas such as helium, argon or nitrogen through the tubular member for l0l5 minutes in order to insure that no plugs are present and to remove oxygen. Following this, the tubular member is sealed off and the polymerization process begun.
Polymerization of the monomer can be effected by various methods depending on the material of construction of the tubular member. For example, if the tubular member is glass, it can be irradiated with ultraviolet or other forms of radiation such as gamma rays to cause polymerization. Generally, however, the tubular member is metallic in nature and, therefore, polymerization by radiation techniques is not employed. A more preferable means of polymerization is thermal polymerization. When the latter technique is employed, the heating can be accomplished in any suitable manner as, for instance, in a chromatographic oven at temperatures of from 50 220 C. In an especially preferred embodiment, polymerization is effected using a free-radical catalyst at a temperature of from 50 C depending on the particular monomer or monomers present and the catalyst chosen. Regardless of the technique employed, when the polymerization reaction is complete, the tubular member is unsealed and any unreacted components e.g., solvent, unreacted monomer, catalyst, etc., are removed, generally by suction.
In a more preferred embodiment of the present invention, it has been found desirable to choose a solvent which is not only miscible and unreactive with the monomer but which is also immiscible with water and to fill the tubular member with water after the coating step but prior to polymerization. This technique helps in preventing the formation of any plugs of polymer in the column.
While not absolutely necessary, it has been found preferable following removal of the water, if used, and solvent to wash the column by passing through it a suitable liquid washing agent having the characteristics of being miscible with both water and the solvent, more volatile than the solvent and substantially a non-solvent for the polymer which has been formed. Washing agents which are useful include lower al cohols having from one to four carbon atoms such as methanol, ethanol and propanol and lower ketones having up to five carbon atoms such as acetone, methyl ethyl ketone and the like. As will be obvious to those skilled in the art, the washing liquid chosen will depend upon the particular polymer or copolymer which has been prepared in the tubular member and the solvent used.
Prior to use in a chromatographic analysis, the column is generally conditioned or pre-treated by passing an inert gas through it at an elevated temperature as, for example, to 200 C, for several hours. The pre-treatment of the column removes any volatile materials which may remain and which would interfere with subsequent analysis using the column.
Columns produced in this fashion have substrates of microporous, cross-linked polymers which are ideally suited for use in the separation of a host of different compounds. The porous polymeric substrates prepared herein are cross-linked in order that they be thermally stable. To obtain these crosslinked polymers, it is necessary that at least one of the monomers chosen be of the polyfunctional, i.e., polyvinyl, type. For example, a homopolymer produced from divinylbenzene will be a highly cross-linked material. Numerous other polyvinyl or polyfunctional type monomers can be employed in the method of the instant invention. Non-limiting examples include divinylbenzene, divinylxylene, divinylethylbenzene, trivinylbenzene and the like; polyvinyl or polyallyl ethers of glycol, of glycerol, of pentaerythritol, or monoor dithio-derivatives of glycols and of resorcinol; divinyl pyridine, diallyl pyridine, diallyl phthalate, ethylene glycol diacrylate, ethylene glycol dimethacrylate, l,3-butanediol dimethacrylate, divinylsulfone, divinyl ketone, allyl acrylate, diallyl maleate, diallyl fumarate, diallyl succinate, diallyl carbonate, diallyl malonate, diallyl oxalate, diallyl adipate, diallyl se bacate, divinylsebacate, diallyl tartrate, N,N ethylenediacrylamide, N,N'-methylenedimethacrylamide and the like.
Particularly preferred polyvinyl monomers include the following: heterocyclic polyvinyl aromatic hydrocarbons such as divinyl pyridine; monocyclic polyvinyl aromatic hydrocarbons such as divinylbenzene and trivinylbenzene, glycol dimethacrylates such as ethylene glycol dimethacrylate; and polyvinyl ethers of polyhydric alcohols such as divinoxyethane and trivinoxypropane. Especially preferred as polyvinyl monomers are the monocyclic polyvinyl aromatic hydrocarbons, particularly the monocyclic divinyl aromatic hydrocarbons. The above monomers can be used alone or in mixtures. It is necessary that the coating mixture contain at least percent by weight of the polyvinyl monomer. Preferably, however, the polyvinyl monomer will be present in the mixture in amounts offrom 20 to 80 percent by weight.
In a more preferred embodiment of the present invention, there is employed along with the above polyvinyl monomer or monomers one or more monoethylenically unsaturated monomers which are copolymerizable with the polyvinyl monomer. Included in this latter group may be mentioned acrylic acid, methacrylic acid, methyl acrylate, ethyl acrylate, propyl acrylate, isopropyl acrylate, butyl acrylate, [err-butyl acrylate, ethylhexyl acrylate, cyclohexyl acrylate, isobornyl acrylate, benzyl acrylate, phenyl acrylate, alkylphenyl acrylate, ethoxymethyl acrylate, ethoxyethyl acrylate, ethoxypropyl acrylate, propoxypropyl acrylate, propoxymethyl acrylate, propoxyethyl acrylate, ethoxyphenyl acrylate, ethoxybenzyl acrylate, ethoxycyclohexyl acrylate, and the corresponding esters of methacrylic acid; styrene, ethylvinylbenzene, vinyltoluene, vinylnaphthalene, and similar monovinyl aromatic hydrocarbons; vinyl esters of carboxylic acids such as vinyl acetate, vinyl propionate and the like.
Another class of suitable monoethylenically unsaturated monomers include the monovinyl nitrogen heterocyclic compounds such as vinylpyridine, Z-methyl-S-vinylpyridine, 2- ethyl-S-vinylpyridine, 3-methyl-5-vinylpyridine, 2,3-dimethyl- S-vinylpyridine, and 2-methyl-3-ethyl-5-vinylpyridine, 2- methyl-S-vinylquinoline, 4-methyl-4-vinylquinoline, l-methylor 3-methyl-5-vinylisoquinoline, N-vinylcaprolactam and N- vinylbutyrolactam. Especially preferred monoethylenically unsaturated monomers are the monocyclic monovinyl aromatic hydrocarbons such as styrene, ethylvinylbenzene and the like and the monovinyl nitrogen hetercyclic compounds such as vinylpyridine and the like. As in the case of the polyvinyl monomers, the above monomers can be used alone or in mixtures. When a monoethylenically unsaturated monomer is used, it is usually present in the mixture in an amount such that the ratio of the weight of the monoethylenically unsaturated monomer to the weight of the polyvinyl monomer is from 1:9 to 9:1 and more preferably from 1:3 to 3:1.
ln carrying out the method of the present invention, the solvent employed will be one which is miscible with the monomers but possesses limited solubility for any polymer, either homopolymer or copolymer that is produced. Furthermore, the solvent employed must be non-reactive with the monomers. The particular solvent chosen is a matter of choice provided the above characteristics are met. Obviously, any
number of solvents are usable depending upon the particular monomers which are being used and the desired porosity, i.e., the size of the pores and the density of the polymer, the latter characteristics being dependent to some extent upon the kind of solvent employed. Solvents generally employed include liquid aromatic hydrocarbons such as benzene, toluene, xylenes, ethylbenzenes, and the like; higher aliphatic hydrocarbons such as hexane, heptane, iso-octane, octane, and the like; higher alcohols such as isoamyl alcohol, hexanol, iso-butyl alcohol, terr-butyl alcohol and the like; nitrohydrocarbons; and higher alkyl esters of organic acids and mixtures thereof. The solvent, which as stated includes not only a single compound but mixtures containing two or more compounds, is characterized by its substantial insolubility in water. The solvent will usually be present in an amount ranging from about 0.5 to about 20 and more preferably one to five times the weight of the monomer or monomers employed.
When a catalyst is employed in the method of the instant invention, it can be any of the well known free-radical type. Non-limiting examples include peroxygen-type compounds, alkyl hydroperoxides, diperoxy dicarbonate esters, azo-type compounds and the like. Particularly suitable are peroxides such as benzoyl peroxide, tert-butyl peroxide and the like. The catalyst will generally be employed in an amount ranging from 0.01 to 3 percent and preferably 0.2 to 1.3 percent by weight based on the total weight of the monomer or monomers present. it is to be understood, however, that it is not necessary to employ a catalyst inasmuch as the polymerization can be carried out thermally Without the aid of any initiator. Preferably, however, a catalyst such as the above will be employed to accelerate the polymerization.
The following examples will serve to more fully illustrate the instant invention but are not to be construed as limitations on its scope.
EXAMPLE I A solution was prepared containing the following percentages of ingredients by weight: ll percent divinylbenzene, 9 percent ethylvinylbenzene, 20 percent styrene, 20 percent isobutyl alcohol, 39 percent dodecyl alcohol and l percent benzoyl peroxide. A 100 ft. section of copper tubing having an internal diameter of 0.5 mm was coated on the inside with the above mixture by forcing the mixture through under pressure. When the mixture had passed through the tube, a nitrogen purge was placed on one end and allowed to sweep through the tube for around 10 15 minutes. The tube was then filled with water using pressure to effect the filling and both ends of the capillary sealed with tubing caps. The filled tube was placed in any oven, and the temperature slowly raised to 90 C and maintained at this temperature for a period of around l6 hours. After cooling to room temperature, the caps were removed from the tubing and a nitrogen purge was again applied to force out the remaining solvent and inert liquid. Fol lowing this, the tube was washed with around 50 cc of methanol, drained and a nitrogen purge was again placed on the tubing for several minutes until the remaining methanol had been removed.
The column thus produced was used to separate a mixture of C to C alcohols. A Varian Aerograph Model 204 gas chromatograph having a hydrogen flame detector was employed. The carrier gas used was helium at a flow rate of 7.8 ml/min. and a column pressure of 6 psig. The temperature of the column was kept at C for 3 minutes after the start of the analysis after which it was programmed to increase at a 12 C/min. rate until a final temperature of 200 C was reached. FIG. l shows the results of the alcohol analysis.
EXAMPLE 2 A solution was prepared containing the following percentages of components by weight: 1 1 percent divinylbenzene, 9 percent ethylvinylbenzene, 20 percent styrene, 44 percent dodecane, percent toluene and 1 percent benzoyl peroxide. A chromatographic column was prepared using the procedure employed in Example 1.
EXAMPLE 3 A mixture containing 1 1 percent divinylbenzene, 9 percent ethylvinylbenzene, percent styrene, 59 percent isobutyl alcohol and 1 percent benzoyl peroxide is used as per the procedure of Example 1 to prepare a chromatographic column.
EXAMPLE 4 A mixture containing 1 1 percent divinylbenzene, 9 percent ethylvinylbenzene, 20 percent styrene, 59 percent isoamyl alcohol and 1 percent benzoyl peroxide is employed as per the procedure of Example 1 to prepare a chromatographic column.
EXAMPLE 5 A solution containing 1 1 percent divinylbenzene, 9 percent ethylvinylbenzene, 20 percent styrene, 20 percent amyl alcohol, 39 percent butyl alcohol and 1 percent benzoyl peroxide is used to prepare a chromatographic column as per the procedure of Example 1.
EXAMPLE 6 A solution containing 1 1 percent divinylbenzene, 9 percent ethylvinylbenzene, 20 percent styrene, 59 percent dodecyl alcohol and 1 percent benzoyl peroxide is used to prepare a chromatographic column by the procedure of Example 1.
EXAMPLE 7 A mixture of 11 percent divinylbenzene, 9 percent ethylvinylbenzene, 20 percent styrene, 20 percent dodecyl alcohol, 39 percent butyl alcohol and 1 percent benzoyl peroxide is used to prepare a chromatographic column using the procedure of Example 1.
The columns of Examples 2-7 following conditioning, are also used in the chromatographic separation of a sample containing C,-C alcohols and found to work quite satisfactorily. The columns are also found to be very effective in the separation of the organic chlorides, organic acids, ketones and esters, giving excellent resolution between the various peaks.
What is claimed is:
l. A method of preparing chromatographic columns comprising:
coating the inside surface of a tubular member with a mixture comprising at least 10 percent by weight of at least one liquid polyvinyl monomer and a solvent, said solvent being miscible and non-reactive with said monomer and being immiscible with water;
substantially filling said tubular member with water;
thereafter polymerizing said monomer in the filled coated tubular member; and
thereafter removing the water and any unreactcd components from said member.
2. The method of claim 1 wherein said polyvinyl monomer is selected from the group consisting of monocyclic polyw'nyl aromatic hydrocarbons, heterocyclic polyvinyl aromatic hydrocarbons, polyvinyl ethers of polyhydric alcohols, glycol dimethacrylates and mixtures thereof.
3. The method of claim 2 wherein said mixture contains a free-radical catalyst.
4. The method of claim 3 wherein said polymerizing is carried out by heating said member to a temperature of from 50 to C.
5. The method of claim 4 wherein a liquid washing agent is passed monocyclic said member after said water and said solvent have been removed, said agent being miscible with said solvent and said water, more volatile than said solvent and a non-solvent for the polymer formed.
6. The method 0 claim 5 wherein said polyvinyl monomer is a moncyclic divinyl aromatic hydrocarbon.
7. The method of claim 1 wherein said mixture contains in addition at least one liquid monoethylenically unsaturated monomer copolymerizable with said polyvinyl monomer, the ratio of the weight of said monoethylenically unsaturated monomer to the weight of said polyvinyl monomer being from 1:9 to 9:1.
8. The method of claim 7 wherein said monoethylenically unsaturated monomer is selected from the group consisting of monocyclic monovinyl aromatic hydrocarbons, monovinyl nitrogen heterocyclic compounds and mixtures thereof.
9. The method of claim 8 wherein said mixture contains a free-radical catalyst.
10. The method of claim 9 wherein said polymerizing is carried out by heating said member to a temperature of from 50 to 130C.
11. The method of claim 10 wherein said polyvinyl monomer is a monocyclic divinyl aromatic hydrocarbon.
12. The method of claim 11 wherein said monoethylenically unsaturated monomer is a monocyclic monovinyl aromatic hydrocarbon.
13. The method of claim 12 wherein said monocyclic divinyl aromatic hydrocarbon is divinylbenzene.
14. The method of claim 13 wherein said monocyclic monovinyl aromatic hydrocarbon is styrene.
15. The method of claim 13 wherein said monocyclic monovinyl aromatic hydrocarbon is ethylvinylbenzene.
16. The method of claim 13 wherein said monocyclic monovinyl aromatic hydrocarbon is a mixture of ethylvinylbenzene and styrene.
|Cited Patent
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|The Regents Of The University Of California
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|Feb 21, 1995
|Rotundo; David A.
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|Apr 4, 1995
|The Regents Of The University Of California
|Organic containment separator
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|Sep 26, 1995
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Separating materials
|Jul 4, 1994
|Jun 24, 1997
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Separating materials for hydrophobic chromatography
|Sep 22, 1994
|Jul 15, 1997
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Ion exchangers
|Sep 24, 1994
|Sep 16, 1997
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Method and supports for gel permeation chromatography
|Sep 21, 1994
|Sep 23, 1997
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Nucleotide-containing sorbent for affinity chromatography
|Mar 25, 2002
|Apr 11, 2006
|Sequant Ab
|Jun 25, 2003
|Jul 11, 2006
|Dionex Corporation
|Separation system, components of a separation system and methods of making and using them
|Aug 10, 2005
|Jan 6, 2009
|Dionex Corporation
|Monolithic column
|Jan 19, 2006
|Apr 12, 2011
|Dionex Corporation
|Separation system, components of a separation system and methods of making and using them
|Apr 12, 2011
|Dionex Corporation
|Separation system, components of a separation system and methods of making and using them
|Oct 31, 2007
|Aug 5, 2014
|Dionex Corporation
|Disposable monolithic column
|Jun 25, 2003
|Feb 5, 2004
|Isco, Inc.
|Separation system, components of a separation system and methods of making and using them
|Mar 25, 2002
|Jul 15, 2004
|Camilla Viklund
|Aug 10, 2005
|Dec 15, 2005
|Teledyne Isco, Inc.
|Disposable monolithic column
|Jan 19, 2006
|Sep 21, 2006
|Allington Robert W
|Separation system, components of a separation system and methods of making and using them
|Oct 31, 2007
|Jul 31, 2008
|Dionex Corporation
|Separation system, components of a separation system and methods of making and using them
|Oct 31, 2007
|Aug 7, 2008
|Dionex Corporation
|Disposable monolithic column
|Dec 30, 2008
|Jul 23, 2009
|Dionex Corporation
|Monolithic column
|Aug 21, 1990
|Feb 27, 1991
|Philips Electronics N.V.
|Method of manufacturing a separation column and a separation column
|Dec 24, 1984
|Jul 18, 1985
|The Foxboro Company
|Fused silica capillary column
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|Oct 10, 2002
|Zipat Ab
|New material
|May 18, 2012
|Jan 3, 2013
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|Porous materials for solid phase extraction and chromatography and processes for preparation and use thereof
|U.S. Classification
|427/235, 427/385.5, 210/198.2, 210/656, 96/101
|International Classification
|Cooperative Classification
|European Classification


text:
Travel Tips by Country
Recent Middle Eastern travel tips
- Dubai MuseumDubai travel tipsThis Museum is located inside the Al Fahid Fort and is one of the best places to experience some of the truly original Arabic artwork and more. The museum documents the life and history of Dubai and the entire Arabic peninsula [...]D: 2.1mi00
- The Wailing WallJerusalem travel tipsThe Wailing Wall or Western Wall is a world famous site of Jerusalem. This is the last remaining wall of Herod's Temple destroyed by the Romans. There is separate section for men and women at the wall, so be careful which part you go to. [...]D: 2.2mi00
- Recommendation for accommodation in Tel AvivTel Aviv travel tipsHi I travel to Tel Aviv several times a year and I have found that renting an apartment for short term is much cheaper than renting a hotel room. It is also more convenient it lets you feel a part of the city opposed to feeling like a [...]D: 0.3mi10
- The Ancient CityPetra travel tipsPetra is now one of the New 7 Wonders of the World. It is a fabulous place from the Eastern tales, simply breathtaking. The old city was discovered by the modern world only in 1812. It was built by the Nabateans around 100 BC with the [...]D: n/a00
- Minimal stop when flyingKuwait City travel tipsCheck booking fares early & often The flight booking fares always fluctuate, so timing is everything to book a flight ticket. I recommend checking often the ticket fares as soon as you know you will be flying till you get the good deal [...]D: 0.4mi00
- 12 things not to do in DubaiDuba travel tipsDubai is a fun and frivolous playground on the Persian Gulf, but don't consider it the Vegas of the Middle East. While this eclectic city is one of the most permissive, relaxed, cosmopolitan destinations in the region, you do have to [...]D: 1221.9mi00
- Man or mrRiyadh travel tipsNo thing important i like go best place [...]D: n/a00
- Ski DubaiDubai travel tipsSki Dubai is located inside Mall of the Emirates. When I was there I was just amazed about how they had managed to build this thing inside a mall, wow. And guess what, people actually use it. Anyhow, if you ever want to go skiing in the [...]D: 10mi00
- Jumeirah BeachDubai travel tipsJumeirah Beach is an amazingly beautiful beach on the outskirts of Dubai. You should go there and then also visit the Burj al Arab which is quite close. [...]D: 5.8mi00
- Burj Al ArabDubai travel tipsThe Burj Al Arab is supposed to be the most expensive hotel in the world. When I went there I told the guard that I was in Dubai for a travel conference and that we were supposed to get a tour for free. He made some phone calls and I was [...]D: 9.1mi00
Things about Middle East you may be interested in
Riyadh SightsThe more prominent sights in Riyadh are mostly modern designs of man. The first significant sight is the Kingdom Center or the Burj Al Mamlakah. This is the tallest skyscraper the whole kingdom built over an area of 94,230 square meters of land and the whole center covers a total area of 300,000 square meters. The highest mosque in the world is also housed in the center. It won the 2002 Emporis Skyscraper Award, selected as the 'best new skyscraper of the year for design and functionality'. Another tower is the Burj Al Faisaliyah. It was the first skyscraper built in Saudi Arabia and second tallest next to its sister tower the Kingdom [...]
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Tada Optical has a huge selection of signature frames and sunglasses! Competitive optical shop in a province!!!
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Meet the New iPods Friday, May 2nd
Apple stores nationwide will be hosting the "Live On Stage" event introducing new iPods to the public this Friday, May 2 from 6-10 PM.
"Sporting a new design, with enough capacity to hold more than 7500 songs, the new iPod rocks into the Apple Store on Friday, May 2, during a revolutionary event you won't want to miss.
From 6 to 10 p.m., enjoy a live DJ spinning tunes on his iPod. Receive a free event poster (while supplies last). And get a limited edition T-shirt for $10 - or for free if you buy an iPod. That's not all: you can also enter to win a JBL sound system worth $1800.
Special Appearances. Singer-songwriter Liz Phair will appear at the SoHo store and ska band Less Than Jake will appear at The Grove during this special event.
Be the first to get your hands on the incredible new iPod and discover for yourself how the world's greatest portable music player just got even better.
Find an Apple Retail Store near you."
Note: iLounge will be at Apple Store Fashion Island in Newport Beach, California on Friday night. Come join us as we get our hands on a new iPod.
Related Stories
i have and old ipod nano when it goes bad which ipod should i get? The new ipod nano with video camera,the original or the touch? Are they making a 3rd generation ipod touch? Please help me i am stumped.
Posted by Megan Insull in Irvine, CA on September 22, 2009 at 9:39 PM (CDT)
Recent News
- Incipio to acquire Skullcandy
- Apple confirms iOS 10 kernel was left open to improve performance
- Apple leaves iOS 10 kernel open to scrutiny
- Judge throws out 'Error 53' lawsuit against Apple
- Chinese company in iPhone patent fight is all but defunct
- Apple adds nine more apps to universal search in Apple TV
- WSJ: iPhone to see modest changes this year, eliminate headphone jack
- China tightening restrictions on mobile games starting next month
- Supreme Court patent ruling bodes well for future Apple cases
- Apple to pay $400M to consumers over e-book price fixing case
Recent Reviews
- Zagg Slim Book for 9.7" iPad Pro
- Element Case Ronin for iPhone 6/6s
- JBL Clip 2 Wireless Bluetooth Speaker
- Audio-Technica ATH-SR5BT Wireless On-Ear Headphones
- Catalyst Case for iPad mini 4
- Jaybird Freedom Wireless Bluetooth Headphones
- Zagg Flex Arc Wireless Earbuds + Speakers
- Audio-Technica ATH-MSR7NC SonicPro Headphones with Active Noise Cancellation
- Twelve South BookBook for 12.9" iPad Pro
- Spigen Rugged Armor, Style Armor + Wallet S for iPhone SE
Recent Articles
- Inside the betas: iOS 10 Photos gets Advanced Computer Vision
- Inside the betas: iOS 10 Music app delivers 'clarity and simplicity'
- Inside the betas: iOS 10 Maps gets a major redesign
- Inside the betas: iOS 10 shakes up the user experience
- Inside the betas: watchOS 3 promises a real speed boost
- Inside the betas: A sneak peek at what's new in tvOS 10
- Filling the Gap: A look at third-party HomeKit apps
- Instant Expert: Secrets & Features of tvOS 9.2
- Instant Expert: Secrets & Features of iOS 9.3
- Opinion: Why Apple needs a dedicated HomeKit app


text:
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Town Manager
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placerherald.com [cached]
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placerherald.com [cached]
"Since the issues of Rocklin Commons and Crossings are virtually the same and the developer is the same, we think that a settlement on the Crossings would carry over to the Commons," Beck said.
www.placerherald.com [cached]
Rhianna Beck
The Sandpit Nursery
Barabara Beck
Learning Care Group Inc
Thomas Beck
Nentico Lodge
Allison Beck
Federal Mediation and Conciliation Service
Nick Beck
Bristol Austin 7 Club Ltd


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IBEW Local 1620 union supports proposed HECO and NextEra merger
The union representing Hawaiian Electric Company workers is throwing its support behind the proposed merger with NextEra.
The union representing Hawaiian Electric Company workers is throwing its support behind the proposed merger with NextEra.
Monday around 4 p.m. at the corner of Lumiauau and Lumiloki Street, a bus driver for Ground Transport reported window damage to her bus.
The attorney for the family of Sheldon Haleck said that, other than walking in South King Street, Haleck did nothing wrong.
Honolulu firefighters responded to a two-alarm house fire at 1900 9th Avenue in Palolo Tuesday afternoon. The first HFD unit arrived at 3:31…
HONOLULU – Fans will get their first extended glimpse of the University of Hawai'i Rainbow Warrior basketball team when it holds its Green &…
South Street in Kakaako is the next street in the plan, but there are even busier streets being thrown in the mix.
HONOLULU – The University of Hawai'i women's basketball team is set to showcase a preview of the upcoming 2015-16 season with its Green vs. …
Numerous health inspections revealed chronic temperature violations.
A flat-bed truck had dropped a pallet of swimming pool supplies, spilling approximately eight gallons of muriatic acid.
While on tour in 2014, Morgan was critically injured in a serious car accident that prevented the comedian from continuing to work and tour.
The cash-and-carry sale includes a range of unique items and memorabilia from the 87,000 square foot space.
The fast-food chain says it will first serve chicken that receive no antibiotics, followed by pork and beef.
They will be twice the size of a normal Kiss and feature a hazelnut center and rice crisps in the chocolate.
"Back to the Future" Day is Wednesday, and fans are tallying up the 1989 film's predictions of life in the year 2015.
Based on all available data a destructive Pacific-wide tsunami is not expected and there is no tsunami threat to Hawaii.
The renewal of the water system will improve fire protection and water service reliability for residents in the area.
Mark Scott Silva had gone to the home of his estranged wife and threatened a 20-year-old woman there with a handgun.
Work was scheduled from 8:30 a.m.-3:30 p.m. to avoid rush hour traffic.
A great game for you to test your mind and keep it sharp.
Chaplain Dave Rasmussen talks more about how the loss of a loved one can be difficult but can bring the bonds of family closer as well.


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One of the standouts of the numerous offsite exhibitions during Milan Design Week (April 12–17) is the beautiful retrospective of Read More
Streets | Elmgreen & Dragset Imagine "Van Gogh's Ear" as a 30-Foot-Tall Swimming Pool in Rockefeller Center
This week, art duo Elmgreen & Dragset transformed the Fifth Avenue entrance to the Channel Gardens at Rockefeller Center Read More
For the occasion of the current Milano Design Week 2016 (April 12–17), 10 progressive contemporary designers join Nike to Read More
Design | RoboRace is the World's First Driverless F1 Race with Futuristic Cars Designed by Daniel Simon
It turns out autonomous vehicles aren't just the future of pedestrian transportation, they're the future of F1 racing too. Since 2014, Formula E Read More
The decision to use wood—a material that is durable yet prone to change and considerable damage over time—as the primary material throughout its beautiful new Sestuna concept car reflects leading Japanee automaker Toyota's efforts to, in their own words, "give form to the developing Read More
When Renzo Rivolta's iconic Isetta debuted in 1953, the tiny, egg-shaped one-cinylnder car was a design & mobility revelation. Swimming in a sea of monstrous V-8 powered, fin-tailed sedans of the day, the Isetta was design futurism personified, a quality not lost on then-struggling German Read More
A minimalist bicycle design by Ion Lucin, the idea behind the gorgeously simple Baik bike was to create a bicycle design with as little elements and lines as possible. With the help of symmetrical lines and angles, Lucien has created a frame that blends with the rims of the bicycle in an effort Read More
Watchmakers frequently adopt design cues from the car industry, but it's not every day that a watchmaker creates a scratch built supercar concept that beats the pros at their own game. Such is the case with French luxury watchmakers Bell & Ross who have just unveiled the absolutely insane new AeroGT concept supercar (that we can only pray becomes an actual production model) and the matching watch, the BR 03-92 AeroGT that's inspired by it. Read More
Easily the most iconic sport chronograph watch of all time, the Rolex Daytona in white or black face with inverted cosmograph dials, introduced in 1965 as reference 6240 and made famous by race car driving actor Paul Newman, has finally be re-introduced to the brand's high-end lineup after a decades-long absence. Announced at this week's Basel World summit, the new version of the Oyster Perpetual Cosmograph Daytona is rendered in Read More
Nike's been teasing the world with the promise of self-lacing technology since it debuted onscreen in the now-cult classic Air Mag shoes featured in the 1989 film Back to the Future II. Today, as part of the brand's Innovation Summit, Nike design god Tinker Hatfield unveiled the world's first self-lacing sneaker for the masses with the forthcoming Hyperadapt 1.0. Codenamed E.A.R.L. ("Electro Adaptive Reactive Laces"), the technology will automatically Read More


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Swisscom announces iPhone 3G pricing for Switzerland
Swisscom has announced its service plans and pricing for the iPhone 3G in Switzerland. As in many other countries, Swisscom's pricing for the handset is tiered based on which plan the customer chooses for his/her 24-month contract. Unlike most other countries, however, airtime minutes are charged at a pre-determined hourly rate, instead of in bulk by the month. With the CHF 25 (~$25) NATEL liberty piccolo monthly plan, users get 100 MB of data a month and an hourly call rate of CHF 0.70 (~$0.70). The 8GB iPhone 3G will sell for CHF 249 (~$244) with the CHF 25 monthly plan, while the 16GB model will run CHF 349 (~$342). With the CHF 35 (~$34) NATEL liberty mezzo monthly plan, users are provided with 250 MB of data and an hourly call rate of CHF 0.50 (~$0.50); the 8GB iPhone 3G is sold for CHF 199 (~$195) and the 16GB model for CHF 299 (~$293). The NATEL liberty grande plan, which runs CHF 55 (~$54) a month, provides 1,000 MB of data and an hourly call rate of CHF 0.50 (~$0.50), bringing the price of the iPhone down to CHF 99 (~$97) for the 8GB model and CHF 199 (~$195) for the 16GB model. All subscription plans also include Visual Voicemail and free access to over 1,100 hotspots across Switzerland. Finally, Swisscom will also offer the iPhone 3G on a prepaid basis (NATEL easy liberty uno), with the 8GB model selling for CHF 519 (~$509), the 16GB for CHF 619 (~$607). The prepaid hourly call rate will be CHF 0.80 (~$0.80), with a flat data rate of CHF 1 ($0.98) per megabyte of data. Swisscom will launch the iPhone 3G in Switzerland on July 11. [via setteB.IT]
Related Stories
- Apple confirms iOS 10 kernel was left open to improve performance
- Apple leaves iOS 10 kernel open to scrutiny
- Judge throws out 'Error 53' lawsuit against Apple
- Chinese company in iPhone patent fight is all but defunct
- WSJ: iPhone to see modest changes this year, eliminate headphone jack
- Chinese patent ruling may force Apple to stop selling iPhone 6/6 Plus in Beijing
The voice plan portion is "per hour" only for calling other swisscom mobile users and swiss fixed line numbers.
It is 0.50-0.80 CHF "per minute" for calling all the other mobile users.
Posted by Jen on July 1, 2008 at 2:54 PM (CDT)
Recent News
- Incipio to acquire Skullcandy
- Apple confirms iOS 10 kernel was left open to improve performance
- Apple leaves iOS 10 kernel open to scrutiny
- Judge throws out 'Error 53' lawsuit against Apple
- Chinese company in iPhone patent fight is all but defunct
- Apple adds nine more apps to universal search in Apple TV
- WSJ: iPhone to see modest changes this year, eliminate headphone jack
- China tightening restrictions on mobile games starting next month
- Supreme Court patent ruling bodes well for future Apple cases
- Apple to pay $400M to consumers over e-book price fixing case
Recent Reviews
- Zagg Slim Book for 9.7" iPad Pro
- Element Case Ronin for iPhone 6/6s
- JBL Clip 2 Wireless Bluetooth Speaker
- Audio-Technica ATH-SR5BT Wireless On-Ear Headphones
- Catalyst Case for iPad mini 4
- Jaybird Freedom Wireless Bluetooth Headphones
- Zagg Flex Arc Wireless Earbuds + Speakers
- Audio-Technica ATH-MSR7NC SonicPro Headphones with Active Noise Cancellation
- Twelve South BookBook for 12.9" iPad Pro
- Spigen Rugged Armor, Style Armor + Wallet S for iPhone SE
Recent Articles
- Inside the betas: iOS 10 Photos gets Advanced Computer Vision
- Inside the betas: iOS 10 Music app delivers 'clarity and simplicity'
- Inside the betas: iOS 10 Maps gets a major redesign
- Inside the betas: iOS 10 shakes up the user experience
- Inside the betas: watchOS 3 promises a real speed boost
- Inside the betas: A sneak peek at what's new in tvOS 10
- Filling the Gap: A look at third-party HomeKit apps
- Instant Expert: Secrets & Features of tvOS 9.2
- Instant Expert: Secrets & Features of iOS 9.3
- Opinion: Why Apple needs a dedicated HomeKit app


text:
In This Section
AES News
- Let Your Voice Be Heard: 2016 AES Elections
- Members are reminded to cast their ballots in the 2016 election for members of the Board of Governors before the election closes at 5:00 PM (EST) on Friday, July 8, 2016.
- AES President-Elect Alex Case Gives AES Paris Keynote, "Intuition, Rebellion, Courage and Chance"
- AES President-Elect Alex Case enthralled the attendees at the opening ceremony of AES Paris, in a keynote address with the theme of "Intuition, Rebellion, Courage and Chance."
- Check out the AES Paris Photo Album on Facebook
- Check out the AES Paris Photo Album on Facebook - be sure to Tag and Share
- Expanded Exhibits Hall and Tech Program Offerings for Exhibits-Plus and All Access Attendees at AES Paris
- Expanded Exhibits Hall and Tech Program Offerings for Exhibits-Plus and All Access Attendees at AES Paris
Standards Blog
AES Press Release: AES London 2011
AES/APRS Event—I Didn't Get Where I am Today . . .
For Release: May 11, 2011
LONDON: Careers are magically unpredictable. Many successful audio world icons, count a chance meeting, or the whims of fortune for their success. Others had a clear direction, some swear by training and hard earned skills. On Monday, May 16, 14:00 - 15:45 the AES 130th Convention will present I Didn't Get Where I am Today . . . a panel moderated by Peter Filleul of the APRS. The 90-minute seminar will address the roads to success traveled by prominent artist/producer/engineers.
Panelists will describe their career influences, and discuss whether flexibility, a broad outlook and the "maverick" spirit are essential elements to achieving longevity in the audio business. They will muse on the expectations generated by audio education, training and, the tacit suspicion that "Mindset" is more important than 'Skillset" in most employment areas.
Panelists include:
Dennis Weinreich: Bass player turned consummate audio engineer, built a career via music and audio production for film and TV to studio ownership and went on to direct the post-production department at Pinewood Film Studios.
Professor David Fisher: Responsible for the establishment of the only 'Tonmeister' course available in the UK. The development of the audio course at Surrey University is consider to be one of the pinnacles of academic and practical training in audio skills.
Barry Marshall: Successful producer/musician and educator
Elliott Randall: Top session guitar player originally based in California during the era of The Doobie Brothers and Steely Dan for whom he provided legendary recorded performances. Now a true Brit, he is a, composer, producer and pro audio educator.
Panel Moderator, Peter Filleul: Composer/musician, turned industry administrator and representative in the area of producers' rights and audio recording.
Photo: Peter Filleul will moderate a panel at the AES 130th Convention Monday, May 16, 14:00 - 15:45 Novotel London West Convention Center, May 16, 2011.
The Audio Engineering Society was formed in 1948 by a group of concerned audio engineers. The AES counts over 14,000 members throughout the U.S., Latin America, Europe, Japan and the Far East. The organization serves as the pivotal force in the exchange and dissemination of technical information for the industry. For additional information visit http://www.aes.org


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Collagen Eye Patches£8 instead of £82 (from SalonBoxed) for 20 collagen eye patches - save 90%
Save 90%
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The Fine Print
- May buy multiples.
- Voucher valid until 7th Feb 2014.
- Postage costs an additional £3.95 per pack.
- Please allow up to 10 working days for delivery after redeeming.
- Subject to availability.
Full Details
Do you suffer from puffy, swollen eyes or dark circles? Today's deal is a sight for sore eyes…
We're offering you a 20 collagen eye patches for just £8, saving you 90% off SalonBoxed's price of £82 (correct as of 20.1.14).
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Cut & Blow Dry with Highlights or Full Head of Colour Option£12 for a cut and blow dry, or £24 for an extra half head of highlights or full head of colour and conditioning treatment from Te Amo Hair & Beauty Salon - save up to 45%
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Please let me know this plant's name
Location : South India
Plant ID Please
vngarden Seattle, WA Nov 14, 2012
looks like bignonia?
TomH3787 Raleigh, NC(Zone 7b) Nov 14, 2012
Looks like Pandorea jasminoides or something related.
fixpix Oradea, Romania Nov 14, 2012
Doesn't look like my Pandorea.
More like my Podranea ricasoliana.
GeorgeGarden Kerala, India Nov 15, 2012
Thanks a lot. Some of the names I found out are
Podranea ricasoliana
Pink Trumpet Vine
Port St Johns Creeper
Port St Johns-klimop
Tecoma mackenii
Post a Reply to this Thread
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Welcome to the Easy Weddings directory of Canberra and Canberra's premium wedding suppliers. Please click a category below to get started. You can select from invitations, gowns, venues, cakes and everything you'll need for the big day. If you have signed in, you can also add suppliers to your very own wedding directory.
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Hotel Christian IV, Copenhagen
- Free continental breakfast and WiFi
Main amenities
- 42 smoke-free guestrooms
- Near the beach
- Bar/lounge
- Self parking
- 24-hour front desk
- Coffee/tea in common area
- Daily housekeeping
- Computer station
- Front desk safe
- Laundry service
- Multilingual staff
- Concierge services
For families
- Private bathroom
- Daily housekeeping
- Laundry facilities
- Hair dryer
- Blackout drapes/curtains
- Elevator/lift
What's around
- In Copenhagen City Centre
- Rosenborg Castle (0.3 mi / 0.4 km)
- Frederik's Church (0.4 mi / 0.6 km)
- Round Tower (0.5 mi / 0.7 km)
- Danish National Gallery (0.5 mi / 0.8 km)
- Amalienborg Palace (0.5 mi / 0.8 km)
Hotel Christian IV, Copenhagen
Hotel Info: 866-539-8117from $112
- Superior Double Room
- Standard Double Room
- Double Room (Small)
- Standard Single Room, 1 Single Bed
Also popular with travelers from the USA
At a glance
Key facts
Hotel size
- This hotel has 42 rooms
- This hotel is arranged over 5 floors
- Check-in time 2 PM-5:30 AM
- Check-out time is 11 AM
- Express check-in
Required at check in
- Credit card or cash deposit required
- Government-issued photo ID required
Travelling with others
- Children (3 years old and younger) stay free when occupying the parent or guardian's room, using existing bedding
- Pets not allowed
- Free WiFi in public areas
- Free WiFi in rooms
- Self parking *
Other information
- Smoke-free property
- Resort fee included
Nearby Three Star Copenhagen hotels
In the hotel
- Free continental breakfast daily
- Bar/lounge
- Coffee/tea in common area
- Use of nearby fitness center (discount)
- Bicycle rentals on site
- Golf lessons available nearby
- Golfing nearby
- Hiking/biking trails nearby
- Computer station
- 24-hour front desk
- Concierge services
- Tours/ticket assistance
- Dry cleaning/laundry service
- Laundry facilities
- Free newspapers in lobby
- Luggage storage
- Multilingual staff
- Elevator/lift
- Safe-deposit box at front desk
- Television in common areas
In the room
- Iron/ironing board (on request)
- Hypo-allergenic bedding available
- Down comforter
- Blackout drapes/curtains
- Egyptian-cotton sheets
- Private bathroom
- Shower only
- Hair dryer
- Cable TV channels
- Desk
- Free WiFi
- Phone
- Refrigerator (on request)
- Free bottled water
- Daily housekeeping
Top Copenhagen hotels
Recently reviewed hotels in Copenhagen
- CABINN ExpressFrom
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Nearby hotels
Hotel Christian IV, Copenhagen's small print
Also known as
- Christian IV Copenhagen
- Christian IV Hotel
- Hotel Christian
- Hotel Christian IV
- Hotel Christian IV Copenhagen
- IV Hotel
- Christian IV
Mandatory fees
The charges below are included in the total price displayed:
- Resort fee
Optional extras
Self parking costs DKK 225 per night with in/out privileges
Rollaway beds are available for DKK 250 per night
Cribs/Infant beds are available for DKK 75 per night
We have included all charges provided to us by this hotel. However, charges can vary, for example, based on length of stay or the room you book.
Recent reviews
Good 3.7 /5 from 377 reviews
Near Rosenberg park.Ten minutes walking to Nyham area.Markets and restaurants nearby.Excellent price and location.
Enjoyed the stay here--room a little small, but did the trick. Was clean and comfy. The breakfast was great....the girl in the dining room was lovely and helpful. We booked in early after a cruise (0930)--was no problem leaving bags here securely.
Great experience for a short overnight stay. Really nice included breakfast. Service was so nice at the desk as well as from the staff setting up breakfast. We had an early flight before it started, and they gave us a carafe of coffee to share, some croissants wrapped to carry, and even slices of cheese. Really pleased with service! Room/Hotel: There was a lift to our room which was convenient and quick. The room was a very nice size (double superior). Space all around the bed. Plenty of outlets. Good shower water pressure. Hair dryer included in room. Seemed fresh and clean. Free chocolates and water awaited us. Location: Easy walk to Rosenberg gardens just across the street, Nyhavn, and the shopping district. Über to area for Little Mermaid statue and gardens was about 13€ round trip.
The rooms are quite basic and small, but very clean. The location is fabulous. It is near everything and just a half block from Kogens Have and Rosenborg Slop. The breakfast is outstanding. The freshly baked bread each day was a special treat.
Great location across from the Rosenborg Castle. Room somewhat dated, but clean and plenty of space. Always coffee and hot chocolat in lobby. Problem with wi fi signal until they gave us a signal buster, them no problem.
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New answers tagged master-page
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