An improved process for forming bridged Group 4 transition metal complexes using boron trihalide and a magnesium dicyclopentadienyl compound to form a dicyclopentadienyl boron halide intermediate for subsequent metallation or other synthetic use and novel metal complexes.

This invention relates to certain bridged Group 4 transition metal complexes possessing an unique bridging structure and to olefin polymerization catalysts obtained from such complexes. In another embodiment the invention relates to an unique process for preparing such metal complexes and intermediate compounds used in such synthesis. More particularly, the unique bridge of the foregoing metal complexes consists of amido-substituted boron atoms characterized in that the amido group contains a ligand containing an element from group 15 or 16 of the Periodic Table of the Elements.
In Angew. Chem. Int. Ed. Engl., 36, 21, p2338-2340 (1997) and in Phosphorus Sulfur, and Silicon, 124 and 125, p561-565 (1997) amido substituted boron bridged ferrocenophanes useful for forming poly(ferrocenes) by a ring opening polymerization were disclosed. The synthesis and characterization of Group 1 and 2 metal and tin complexes of 1,2-bis(dimethylamino)-1,2-di-9-fluorenyldiboranes were disclosed in Chem. Ber., 127, p1901-1908, (1994). Diboranes having structure similar to those employed in the foregoing study were disclosed by the same researchers in Eur. J. Inorg. Chem., p505-509 (1998). Ferrocenophane derivatives of similar bisboranes for further molecular property studies were disclosed by J. Organomet. Chem., 530 p117-120 (1997). In Organometallics, 16, p4546-4550 (1997) boron bridged ansa metallocene complexes including dimethylsulfide and phosphine adducts thereof of possible use in Ziegler-Natta-type olefin polymerizations were disclosed.
In the patent literature, bridged metal complexes for use as olefin polymerization catalyst components, including such complexes containing one or more boron atoms in the bridge are generically disclosed by EP-A-416,815 and WO 98/39369. Certain techniques for preparing boron bridged metallocenes, including the use of deprotonating agents that are weakly nucleophilic bases are disclosed in U.S. Pat. No. 5,962,718.
The present invention relates to an improved process for forming certain bridged Group 4 transition metal complexes corresponding to the formula:
wherein:
M is a Group 4 metal, preferably zirconium, said metal M being in the +2, +3 or +4 formal oxidation state;
Y1 and Y2 are independently anionic, cyclic or non-cyclic, xcfx80-bonded groups,
Q, independently each occurrence, is a neutral, anionic or dianionic ligand group, said Q having up to 50 atoms not counting hydrogen;
j is an integer from 1 to 4, selected with respect to the oxidation state of M and the electronic nature of Q to provide overall charge balance to the compound;
R1 is independently each occurrence hydrogen, a hydrocarbyl group, a tri(hydrocarbyl)silyl group, or a tri(hydrocarbyl)silylhydrocarbyl group, or one of the foregoing multiatomic groups further substituted with one or more di(hydrocarbyl)amino- or hydrocarbyloxy- groups, said R1 group containing up to 50 atoms not counting hydrogen, and optionally both R1 groups may be joined together, optionally by means of one or more divalent bridging groups derived from the foregoing di(hydrocarbyl)amino- or hydrocarbyloxy- substituent groups, thereby forming a dianionic ligand group,
the steps of the process comprising:
(1) contacting a boron trihalide with a magnesium dianionic salt corresponding to the formula Mg(Y1H)(Y2H), wherein Y1 and Y2 are as previously defined to prepare a metal complex according to the formula:
wherein X is halide;
(2) aminating the boron bridging atom thereby forming a compound of Formula 3,
wherein R1 is as previously defined,
(3) deprotonating the product of step (2) of Formula 3 by contact with a deprotonating agent; especially a weak nucleophilic base, and
(4) contacting the product of step (3) with a transition metal salt of the formula MY3y(LB)b, wherein
M is as previously defined;
Y3 is Q or a leaving group, especially halide, more especially bromide or chloride;
y is an integer from 0 to 4 selected to provide charge balance in the transition metal salt;
LB is a Lewis base compound; and
b is an integer from 0 to 3.
According to the present invention there is also provided a process for forming a compound corresponding to the formula:
wherein X is halide, preferably bromide or chloride; and
Y1 and Y2 are independently anionic, cyclic or non-cyclic, xcfx80-bonded groups, the steps of the process comprising:
(1) contacting a boron trihalide with a magnesium dianionic salt corresponding to the formula Mg(Y1H)(Y2H), wherein Y1 and Y2 are as previously defined under reaction conditions to thereby prepare the metal complex of formula 2.
In a final embodiment, the present invention relates to certain novel bridged Group 4 transition metal complexes corresponding to the formula:
wherein:
M is a Group 4 metal, preferably zirconium, said metal M being in the +2, +3 or +4 formal oxidation state;
Y1 and Y2 are independently anionic, cyclic or non-cyclic, xcfx80-bonded groups,
Q is a neutral, anionic or dianionic ligand group depending on the oxidation state of M, said Q having up to 50 atoms not counting hydrogen;
j is an integer from 1 to 4, selected with respect to the oxidation state of M and the electronic nature of Q to provide overall charge balance to the compound; and
R1 is independently each occurrence is a substituted hydrocarbyl group, a substituted tri(hydrocarbyl)silyl group, or a substituted tri(hydrocarbyl)silylhydrocarbyl group, said group being substituted with one or more di(hydrocarbyl)amino- or hydrocarbyloxy- groups and containing up to 50 atoms not counting hydrogen, and optionally both R1 groups may be joined together, optionally by means of one or more divalent bridging groups derived from the foregoing di(hydrocarbyl)amino- or hydrocarbyloxy- substituent groups, thereby forming a dianionic ligand group.
The metal complexes according to Formula 1 or Formula 1xe2x80x2, are usefully employed as components of olefin polymerization catalyst compositions.
All references to the Periodic Table of the Elements herein shall refer to the Periodic Table of the Elements, published and copyrighted by CRC Press, Inc., 1997. Also, any references to a Group or Groups shall be to the Groups or Groups reflected in this Periodic Table of the Elements using the IUPAC system for numbering groups. Where any reference is made herein to any publication, patent application or provisional patent application, the contents thereof are incorporated herein in its entirety by reference. By the term xe2x80x9cX-bondedxe2x80x9d as used herein is meant that bonding occurs through an interaction involving delocalized electrons. By the term, xe2x80x9cleaving groupxe2x80x9d is meant a ligand that is readily displaced by another ligand under ligand exchange conditions.
Suitable Lewis base compounds, LB, in the foregoing reagents and products, include neutral Q groups, especially conjugated dienes, especially 1,4-diphenyl-1,3-butadiene, which are capable of donating an electron pair originating from delocalized xcfx80-electrons contained therein.
All of the foregoing process steps are desirably conducted in an inert solvent, especially an aliphatic or aromatic hydrocarbon or ether, employing temperatures from xe2x88x92100xc2x0 C. to 150xc2x0 C. Amination of the boron bridging atom (step (2)) may be accomplished by the use of either an alkali metal amide- or Grignard amide- reagent of the formula MeNR12, wherein Me is an alkali metal cation or Grignard cation (MgBr+ or MgCl+) (step 2a), or a secondary amine of the formula HNR12, preferably in excess, (or a mixture of the foregoing secondary amine reagent and a tertiary amine of the formula, NR33), wherein R1 is as previously defined and R3 is R1 or C1-4 alkyl (step 2b). By performing the amination after addition of the cyclopentadienyl ligands to the boron bridging group instead of before such addition, the desired product is formed in higher yield and purity. Moreover, use of the foregoing neutral amination conditions of step 2b to prepare the desired product, is not possible, unless steps (1) and (2) are performed in the prescribed order, as disclosed herein.
Step (3) is accomplished by contacting the intermediate compound with the base under deprotonation conditions. Such process conditions are well known in the art. Preferred deprotonation agents are weak, nucleophilic bases, especially an alkalimetal bis(trialkysilyl)amide, most preferably lithium bis(trimethylsilyl)amide. Stronger bases, such as lithium alkyls may be used for the deprotonation step as well, particularly if moderating reaction conditions such as reduced temperatures and/or dilute concentrations of reagents are employed. To form the desired dianionic compound, at least two equivalents of the base are preferably employed.
Suitable transition metal reagents for step (4) of the formula MY3y(LB)b, specifically include ZrCl4, ZrCl3, ZrCl2 (1,4-diphenyl-1,3-butadiene), HfCl4, HfCl3, and adducts thereof with one or more Lewis bases selected from ethers, polyethers, amines, or polyamines, said Lewis base having up to 20 carbons, preferably THF. An especially preferred transition metal reagent is a transition metal/diene compound of the formula:
wherein,
M is Ti, Zr or Hf,
Y3 is a leaving group, especially halide;
R6 independently each occurrence is hydrogen, a hydrocarbyl group, a tri(hydrocarbyl)silyl group, or a tri(hydrocarbyl)silylhydrocarbyl group, said R6 groups containing up to 20 atoms not counting hydrogen; and
LB is a Lewis base, especially an ether, amine, or phosphine of up to 20 carbons.
Use of the foregoing transition metal reagent of formula 3 allows for the preparation of complexes of formula 1 in high racemic purity in the +2 formal oxidation state. Any of the compounds may be raised to a higher oxidation state by contact with an oxidizing agent, preferably a chlorohydrocarbon- or chlorocarbon-compound.
Preferred Group 4 transition metal complexes formed according to the present invention correspond to formula 1a:
wherein
M, Q, j and R1 are as defined above;
R2 is hydrogen, or a hydrocarbyl, halohydrocarbyl, dihydrocarbylamino-hydrocarbyl, tri(hydrocarbylsilyl)hydrocarbyl, Si(R4)3, N(R4)2, or OR4 group of up to 20 carbon or silicon atoms, and optionally two adjacent R2 groups can be joined together, thereby forming a fused ring structure, especially an indenyl ligand or a substituted indenyl ligand, and
R4 is independently hydrogen, a hydrocarbyl group, a trihydrocarbylsilyl group or a tri(hydrocarbyl)silylhydrocarbyl group, said R4 having up to 20 atoms not counting hydrogen.
Preferred metal complexes of formula 1xe2x80x2 are similarly described as for the preferred complexes of formula 1a, excepting that R1 is as previously defined with respect to formula 1xe2x80x2.
When M is in the +4 oxidation state, j=2 and Q independently each occurrence is halide, hydride, hydrocarbyl, trihydrocarbylsilyl, tri(hydrocarbyl)silylhydrocarbyl, hydrocarbyloxide, dihydrocarbylamide, or hydrocarbyleneamide, said Q having up to 20 atoms not counting hydrogen. Alternatively, two Q groups may be joined together to form a hydrocarbadiyl- or hydrocarbylene-group, especially a dianionic derivative of a conjugated, C4-40 diene that together with M forms a metallocyclopentene.
When M is in the +3 oxidation state, j=1 and Q is either 1) a monovalent anionic stabilizing ligand selected from the group consisting of alkyl, cycloalkyl, aryl, silyl, amido, phosphido, alkoxy, aryloxy, sulfido groups, and mixtures thereof, and being further substituted with an amine, phosphine, ether, or thioether containing substituent able to form a coordinate-covalent bond or chelating bond with M said ligand having up to 50 atoms not counting hydrogen; or 2) a C3-10 hydrocarbyl group comprising an ethylenic unsaturation able to form an xcex73 bond with M.
When M is in the +2 oxidation state, j=1 and Q is a neutral conjugated diene, optionally substituted with one or more tri(hydrocarbyl)silyl or tri(hydrocarbyl)silylhydrocarbyl groups, said Q having up to 40 carbon atoms and forming a xcfx80-complex with M.
Specific examples of the above metal complexes wherein M is in the +4 oxidation state are those of formula 1a or 1xe2x80x2, wherein the definitions of M, Z, R1, and R2 are as defined above, j is 2, and wherein Q, independently each occurrence, is a halide, or a hydrocarbyl- or trihydrocarbylsilyl-group of up to 10 atoms not counting hydrogen, or two Q groups together form a divalent derivative of a C4-20 diene coordinated to M in a metallocyclopentene fashion. Most highly preferably Q independently each occurrence is chloride or a C1-6 hydrocarbyl group, or two Q groups together form a 2-methyl-2-butene-1,4-diyl or 2,3-dimethyl-2-butene-1,4-diyl group.
Specific examples of the above metal complexes wherein M is in the +3 oxidation state are those of formula 1a or 1xe2x80x2, wherein the definitions of M, Z, R1, and R2 are as defined above, j is 1, and wherein Q, each occurrence is a monovalent anionic stabilizing ligand selected from the group consisting of aryl and aralkyl groups which are further substituted with one or more amine, aminoalkyl, phosphine, or ether substituents able to form a coordinate-covalent bond or chelating bond with M, said Q having up to 30 non-hydrogen atoms; or Q is a C3-10 hydrocarbyl group comprising an ethylenic unsaturation able to form an xcex73 bond with M. Most highly preferred examples of such Q ligands are 2-N,N-dimethylaminobenzyl, allyl, and 1-methylallyl.
Specific examples of the above metal complexes wherein M is in the +2 oxidation state are those of formula 1a or 1xe2x80x2, wherein the definitions of M, Z, R1, and R2 are as defined above, j is 1, and wherein Q, each occurrence, is a neutral conjugated diene, optionally substituted with one or more tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said Q having up to 30 atoms not counting hydrogen and forming a xcfx80-complex with M. Most highly preferred Q groups are 1,4-diphenyl-1,3-butadiene, 1,3-pentadiene, 3-methyl-1,3-pentadiene, 2,4-hexadiene, 1-phenyl-1,3-pentadiene, 1,4-dibenzyl-1,3-butadiene, 1,4-ditolyl-1,3-butadiene, 1,4-bis(trimethylsilyl)-1,3-butadiene, and 1,4-dinaphthyl-1,3-butadiene.
Preferably in the foregoing formulas 1, 1xe2x80x2 and 1a, Y1 and Y2 are both cyclopentadienyl, alkyl- or polyalkyl- substituted cyclopentadienyl, inden-1-yl, 2-alkyl-4-arylinden-1-yl, or 3-alkylinden-1-yl, or Y1 is cyclopentadienyl, alkyl- or polyalkyl- substituted cyclopentadienyl and Y2 is fluorenyl; and Q is halide, alkyl, trialkylsilyl, N,N-dialkylamido, or 1,4-diphenyl-1,3-butadiene (said alkyl or aryl groups having up to 10 carbons). Even more preferably in formula 1, 1xe2x80x2 and 1a, M is zirconium or hafnium.
Most highly preferred metal complexes of formula 1 are those wherein Y1 and Y2 are both inden-1-yl, 2-methyl-4-phenylinden-1-yl, 2-methyl-4-(2-methylphenyl)inden-1-yl, 3-isopropylinden-1-yl, or 3-t-butylinden-1-yl groups, especially compositions comprising greater than 90 percent rac isomer.
Preferred Group 4 transition metal complexes of formula 1xe2x80x2 are those wherein:
R1 each occurrence is 4-dimethylaminophenyl or two R1 groups together with N are an isoindolenino, N-methylpiperazino, or morpholino group, that is,
Highly preferred Q groups for the foregoing compounds of formula 1xe2x80x2 wherein M is in the +2 formal oxidation state are 1,4-diphenyl-1,3-butadiene, 1,3-pentadiene, 3-methyl-1,3-pentadiene, 2,4-hexadiene, 1-phenyl-1,3-pentadiene, 1,4-dibenzyl-1,3-butadiene, 1,4-ditolyl-1,3-butadiene, 1,4-bis(trimethylsilyl)-1,3-butadiene, and 1,4-dinaphthyl-1,3-butadiene. Highly preferred Q groups for the foregoing compounds of formula 1xe2x80x2 wherein M is in the +3 formal oxidation state are 2-(N,N-dimethylamino)benzyl, 2-(N,N-dimethylaminomethyl)phenyl, and allyl. Highly preferred Q groups for the foregoing compounds of formula 1xe2x80x2 wherein M is in the +4 formal oxidation state are chloride, methyl, benzyl, trimethylsilyl or 2,3-dimethyl-2-butene-1,4-diyl.
Most highly preferred metal complexes of formula 1xe2x80x2 are those wherein Y1 and Y2 are both inden-1-yl, 2-methyl-4-phenylinden-1-yl, 3-isopropylinden-1-yl, or 3-t-butylinden-1-yl groups, especially compositions comprising greater than 90 percent rac isomer.
Specific, but not limiting examples of metal complexes of formula 1 and formula 1xe2x80x2 wherein M is in the +2 formal oxidation state are:
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-dinaphthyl-1,3 -butadiene;
dimethylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-4-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-2,4-hexadiene;
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-cyclopentadienylzirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-cyclopentadienylzirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-cyclopentadienylzirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-cyclopentadienylzirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-cyclopentadienylzirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-dimethylphenyl)inden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-dimethylphenyl)inden-1-yl)zirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-dimethylphenyl)inden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-dimethylphenyl)inden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-dimethylphenyl)inden-1-yl)zirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-difluoromethylphenyl)inden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-difluoromethylphenyl)inden-1-yl)zirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-difluoromethylphenyl)inden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-difluoromethylphenyl)inden-1-yl)zirconium xcex74-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-(3,5-difluoromethylphenyl)inden-1-yl)zirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-isopropyl -4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex75-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium xcex75-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-inden-1-ylzirconium xcex75-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex75-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex75-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-2,4-hexadiene;
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-inden-1-ylzirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex75-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-2,4-hexadiene;
isoindolenidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
isoindolenidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
isoindolenidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-ylzirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-ylzirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-ylzirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex75-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-2,4-hexadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium xcex75-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-inden-1-ylzirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-inden-1-ylzirconium xcex74-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium -xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-2,4-hexadiene;
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium xcex75-1,3-pentadiene;
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-inden-1-ylzirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-inden-1-ylzirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-inden-1-ylzirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-methylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden 1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene ;
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-3-phenyl-1,3-pentadiene;
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium xcex74-1,3-pentadiene;
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-diphenyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-2,4-hexadiene;
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,4-dinaphthyl-1,3-butadiene;
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1-phenyl-1,3-pentadiene; and
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium xcex74-1,3-pentadiene.
Specific, but not limiting examples of metal complexes of formula 1 and formula 1xe2x80x2 wherein M is in the +4 formal oxidation state are:
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium dichloride;
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium dimethyl;
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-cyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dichloride;
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dimethyl;
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-inden-1-yl zirconium dichloride;
dimethylamidoborane-bis-xcex75-inden-1-yl zirconium dimethyl;
dimethylamidoborane-bis-xcex75-inden-1-yl zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-inden-1-yl zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-inden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium dichloride;
dimethylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium dimethyl;
dimethylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dichloride;
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dimethyl;
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium -2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dichloride;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dimethyl;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dichloride;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dimethyl;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dichloride;
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dimethyl;
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dichloride;
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dimethyl;
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dichloride;
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dimethyl;
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dibenzyl;
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium bis(trimethylsilyl);
dimethylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-cyclopentadienyl zirconium dichloride;
diisopropylamidoborane-bis-xcex75-cyclopentadienyl zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-cyclopentadienyl zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-cyclopentadienyl zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-cyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dichloride;
diisopropylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-inden-1-yl zirconium dichloride;
diisopropylamidoborane-bis-xcex75-inden-1-yl zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-inden-1-yl zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-inden-1-yl zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-inden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium dichloride;
diisopropylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dichloride;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium -2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dichloride;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dichloride;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dichloride;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dichloride;
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dichloride;
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dimethyl;
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dibenzyl;
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium bis(trimethylsilyl);
diisopropylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium dichloride;
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium dimethyl;
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-cyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dichloride;
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dimethyl;
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-inden-1-yl zirconium dichloride;
diphenylamidoborane-bis-xcex75-inden-1-yl zirconium dimethyl;
diphenylamidoborane-bis-xcex75-inden-1-yl zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-inden-1-yl zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-inden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium dichloride;
diphenylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium dimethyl;
diphenylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-2-methylinden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dichloride;
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dimethyl;
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium -2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dichloride;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dimethyl;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dichloride;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dimethyl;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dichloride;
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dimethyl;
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dichloride;
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dimethyl;
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dichloride;
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dimethyl;
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dibenzyl;
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium bis(trimethylsilyl);
diphenylamidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-cyclopentadienyl zirconium dichloride;
isoindolinidoborane-bis-xcex75-cyclopentadienyl zirconium dimethyl;
isoindolinidoborane-bis-xcex75-cyclopentadienyl zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-cyclopentadienyl zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-cyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dichloride;
isoindolinidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dimethyl;
isoindolinidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-n-butylcyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-inden-1-yl zirconium dichloride;
isoindolinidoborane-bis-xcex75-inden-1-yl zirconium dimethyl;
isoindolinidoborane-bis-xcex75-inden-1-yl zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-inden-1-yl zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-inden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-2-methylinden-1-yl zirconium dichloride;
isoindolinidoborane-bis-xcex75-2-methylinden-1-yl zirconium dimethyl;
isoindolinidoborane-bis-xcex75-2-methylinden-1-yl zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-2-methylinden-1-yl zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-2-methylinden-1-yl zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(2-methylinden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dichloride;
isoindolinidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dimethyl;
isoindolinidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium -2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dichloride;
isoindolinidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dimethyl;
isoindolinidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dichloride;
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dimethyl;
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dichloride;
isoindolinidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dimethyl;
isoindolinidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
isoindolinidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
isoindolinidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
isoindolinidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
isoindolinidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dichloride;
isoindolinidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dimethyl;
isoindolinidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
isoindolinidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dichloride;
isoindolinidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dimethyl;
isoindolinidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dibenzyl;
isoindolinidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium bis(trimethylsilyl);
isoindolinidoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-cyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-n-butylcyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-yl zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-yl zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-yl zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-yl zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-inden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-2-methylinden-1-yl zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-2-methylinden-1-yl zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-2-methylinden-1-yl zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-2-methylinden-1-yl zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-2-methylinden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium -2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-isopropylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dichloride;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dimethyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dibenzyl;
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium bis(trimethylsilyl);
bis(4-dimethylaminophenyl)borane-bis-xcex75-(3-t-butylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-cyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-inden-1-yl zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-inden-1-yl zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-inden-1-yl zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-inden-1-yl zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-inden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-2-methylinden-1-yl zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-2-methylinden-1-yl zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-2-methylinden-1-yl zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-2-methylinden-1-yl zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-2-methylinden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium -2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dichloride;
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dimethyl;
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dibenzyl;
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium bis(trimethylsilyl);
N-methylpiperazinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium dichloride;
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium dimethyl;
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium dibenzyl;
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-cyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dichloride;
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dimethyl;
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium dibenzyl;
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-n-butylcyclopentadienyl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-inden-1-yl zirconium dichloride;
morpholinoborane-bis-xcex75-inden-1-yl zirconium dimethyl;
morpholinoborane-bis-xcex75-inden-1-yl zirconium dibenzyl;
morpholinoborane-bis-xcex75-inden-1-yl zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-inden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-2-methylinden-1-yl zirconium dichloride;
morpholinoborane-bis-xcex75-2-methylinden-1-yl zirconium dimethyl;
morpholinoborane-bis-xcex75-2-methylinden-1-yl zirconium dibenzyl;
morpholinoborane-bis-xcex75-2-methylinden-1-yl zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-2-methylinden-1-yl zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dichloride;
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dimethyl;
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium dibenzyl;
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-(2-methyl-4-phenylinden-1-yl)zirconium -2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dichloride;
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dimethyl;
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium dibenzyl;
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-(2-ethyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dichloride;
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dimethyl;
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium dibenzyl;
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-(2-isopropyl-4-phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dichloride;
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dimethyl;
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium dibenzyl;
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-(2-methyl-4-naphthylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-(2-methyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-(2-ethyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dichloride;
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dimethyl;
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium dibenzyl;
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-(2-isopropyl-4-bis(3,5-trifluoromethyl)phenylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dichloride;
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dimethyl;
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium dibenzyl;
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium bis(trimethylsilyl);
morpholinoborane-bis-xcex75-(3-isopropylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl;
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dichloride;
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dimethyl;
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium dibenzyl;
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium bis(trimethylsilyl); and
morpholinoborane-bis-xcex75-(3-t-butylinden-1-yl)zirconium-2,3-dimethyl-2-butene-1,4-diyl.
The skilled artisan will recognize that additional members of the foregoing list, such as those wherein zirconium is replaced by hafnium are also included within the invention. Moreover, it should also be recognized that the terms xcex75 or xcex74 may not accurately reflect the actual electronic distribution of the molecule under use conditions, and that molecules including lesser numbers of contributing atoms to the electronic delocation are intended to be included within such descriptions as well.
In general, the process of synthesizing the foregoing compounds and complexes is performed under inert atmosphere using standard organometallic synthetic procedures. The recovery of the desired Group 4 transition metal complex is accomplished by separation of the product from any by-products and devolatilization of the reaction medium. Extraction into a secondary solvent may be employed if desired. Alternatively, if the desired product is an insoluble precipitate, filtration or other separation techniques may be employed. Final purification, if required, may be accomplished by recrystallization from an inert solvent, employing low temperatures if needed.
The complexes are rendered catalytically active by combination with an activating cocatalyst or use of an activating technique, such as those that are previously known in the art for use with Group 4 metal olefin polymerization complexes. Suitable activating cocatalysts for use herein include polymeric or oligomeric alumoxanes, especially methylalumoxane, triisobutyl aluminum modified methylalumoxane, or isobutylalumoxane; neutral Lewis acids, such as C1-30 hydrocarbyl substituted Group 13 compounds, especially tri(hydrocarbyl)aluminum- or tri(hydrocarbyl)boron compounds and halogenated (including perhalogenated) derivatives thereof, having from 1 to 10 carbons in each hydrocarbyl or halogenated hydrocarbyl group, more especially perfluorinated tri(aryl)boron compounds, and most especially tris(pentafluorophenyl)borane; nonpolymeric, compatible, noncoordinating, ion forming compounds (including the use of such compounds under oxidizing conditions), especially the use of ammonium-, phosphonium-, oxonium-, carbonium-, silylium- or sulfonium- salts of compatible, noncoordinating anions, or ferrocenium salts of compatible, noncoordinating anions; bulk electrolysis (explained in more detail hereinafter); and combinations of the foregoing activating cocatalysts and techniques. A preferred ion forming compound is a tri(C1-20-hydrocarbyl)ammonium salt of a tetrakis(fluoroaryl)borate, especially a tetrakis(pentafluorophenyl)borate. The foregoing activating cocatalysts and activating techniques have been previously taught with respect to different metal complexes in the following references: EP-A-277,003, U.S. Pat. No. 5,153,157, U.S. Pat. No. 5,064,802, U.S. Pat. No. 5,321,106, U.S. Pat. No. 5,721,185, U.S. Pat. No. 5,350,723, U.S. Pat. No. 5,425,872, U.S. Pat. No. 5,625,087, U.S. Pat. No. 5,883,204, U.S. Pat. No. 5,919,983, U.S. Pat. No. 5,783,512, WO 99/15534, and U.S. Ser. No. 09/251,664, filed Feb. 17, 1999 (WO99/42467).
Combinations of neutral Lewis acids, especially the combination of a trialkylaluminum compound having from 1 to 4 carbons in each alkyl group and a halogenated tri(hydrocarbyl)boron compound having from 1 to 20 carbons in each hydrocarbyl group, especially tris(pentafluorophenyl)borane, further combinations of such neutral Lewis acid mixtures with a polymeric or oligomeric alumoxane, and combinations of a single neutral Lewis acid, especially tris(pentafluorophenyl)borane with a polymeric or oligomeric alumoxane are especially desirable activating cocatalysts. Preferred molar ratios of Group 4 metal complex: tris(pentafluoro-phenylborane: alumoxane are from 1:1:1 to 1:10:30, more preferably from 1:1:1.5 to 1:5:10.
Suitable ion forming compounds useful as cocatalysts in one embodiment of the present invention comprise a cation which is a Brxc3x8nsted acid capable of donating a proton, and a compatible, noncoordinating anion, Axe2x88x92. As used herein, the term xe2x80x9cnoncoordinatingxe2x80x9d means an anion or substance which either does not coordinate to the Group 4 metal containing precursor complex and the catalytic derivative derived therefrom, or which is only weakly coordinated to such complexes thereby remaining sufficiently labile to be displaced by a neutral Lewis base. A noncoordinating anion specifically refers to an anion which when functioning as a charge balancing anion in a cationic metal complex does not transfer an anionic substituent or fragment thereof to said cation thereby forming neutral complexes. xe2x80x9cCompatible anionsxe2x80x9d are anions which are not degraded to neutrality when the initially formed complex decomposes and are noninterfering with desired subsequent polymerization or other uses of the complex.
Preferred anions are those containing a single coordination complex comprising a charge-bearing metal or metalloid core which anion is capable of balancing the charge of the active catalyst species (the metal cation) which may be formed when the two components are combined. Also, said anion should be sufficiently labile to be displaced by olefinic, diolefinic and acetylenically unsaturated compounds or other neutral Lewis bases such as ethers or nitrites. Suitable metals include, but are not limited to, aluminum, gallium, niobium or tantalum. Suitable metalloids include, but are not limited to, boron, phosphorus, and silicon. Compounds containing anions which comprise coordination complexes containing a single metal or metalloid atom are, of course, well known and many, particularly such compounds containing a single boron atom in the anion portion, are available commercially.
Preferably such cocatalysts may be represented by the following general formula:
(L*xe2x80x94H)d+(A)dxe2x88x92
wherein:
L* is a neutral Lewis base;
(L*xe2x80x94H)+ is a conjugate Brxc3x8nsted acid of L*;
Adxe2x88x92 is a noncoordinating, compatible anion having a charge of dxe2x88x92, and
d is an integer from 1 to 3.
More preferably Adxe2x88x92 corresponds to the formula: [Mxe2x80x2Q4]xe2x88x92;
wherein:
Mxe2x80x2 is boron or aluminum in the +3 formal oxidation state; and
Q independently each occurrence is selected from hydride, dialkylamido, halide, hydrocarbyl, hydrocarbyloxide, halo-substituted hydrocarbyl, halo-substituted hydrocarbyloxy, and halo- substituted silylhydrocarbyl radicals (including perhalogenated hydrocarbyl-perhalogenated hydrocarbyloxy- and perhalogenated silylhydrocarbyl radicals), said Q having up to 20 carbons with the proviso that in not more than one occurrence is Q halide. Examples of suitable hydrocarbyloxide Q groups are disclosed in U.S. Pat. No. 5,296,433.
In a more preferred embodiment, d is one, that is, the counter ion has a single negative charge and is Axe2x88x92. Activating cocatalysts comprising boron which are particularly useful in the preparation of catalysts of this invention may be represented by the following general formula:
(L*xe2x80x94H)+(BQ4)xe2x88x92;
wherein:
L* is as previously defined;
B is boron in a formal oxidation state of 3; and
Q is a hydrocarbyl-, hydrocarbyloxy-, fluorohydrocarbyl-, fluorohydrocarbyloxy-, hydroxyfluorohydrocarbyl-, dihydrocarbylaluminumoxyfluorohydrocarbyl-, or fluorinated silylhydrocarbyl- group of up to 20 nonhydrogen atoms, with the proviso that in not more than one occasion is Q hydrocarbyl. Most preferably, Q is each occurrence a fluorinated aryl group, especially, a pentafluorophenyl group.
Preferred Lewis base salts are ammonium salts, more preferably trialkyl-ammonium- or dialkylarylammonium- salts containing one or more C12-40 alkyl groups. The latter cocatalysts have been found to be particularly suitable for use in combination with not only the present metal complexes but other Group 4 metallocenes as well.
Illustrative, but not limiting, examples of boron compounds which may be used as an activating cocatalyst in the preparation of the improved catalysts of this invention (as well as previously known Group 4 metal catalysts) are tri-substituted ammonium salts such as:
trimethylammonium tetrakis(pentafluorophenyl) borate,
triethylammonium tetrakis(pentafluorophenyl) borate,
tripropylammonium tetrakis(pentafluorophenyl) borate,
tri(n-butyl)ammonium tetrakis(pentafluorophenyl) borate,
tri(sec-butyl)ammonium tetrakis(pentafluorophenyl) borate,
N,N-dimethylanilinium tetrakis(pentafluorophenyl) borate,
N,N-dimethylanilinium n-butyltris(pentafluorophenyl) borate,
N,N-dimethylanilinium benzyltris(pentafluorophenyl) borate,
N,N-dimethylanilinium tetrakis(4-(t-butyldimethylsilyl)-2,3,5,6-tetrafluorophenyl) borate,
N,N-dimethylanilinium tetrakis(4-(triisopropylsilyl)-2,3,5,6-tetrafluorophenyl) borate,
N,N-dimethylanilinium pentafluorophenoxytris(pentafluorophenyl) borate,
N,N-diethylanilinium tetrakis(pentafluorophenyl) borate,
N,N-dimethyl-2,4,6-trimethylanilinium tetrakis(pentafluorophenyl) borate,
dimethyltetradecylammonium tetrakis(pentafluorophenyl) borate,
dimethylhexadecylammonium tetrakis(pentafluorophenyl) borate,
dimethyloctadecylammonium tetrakis(pentafluorophenyl) borate,
methylditetradecylammonium tetrakis(pentafluorophenyl) borate,
methylditetradecylammonium (hydroxyphenyl)tris(pentafluorophenyl) borate,
methylditetradecylammonium (diethylaluminoxyphenyl)tris(pentafluorophenyl) borate,
methyldihexadecylammonium tetrakis(pentafluorophenyl) borate,
methyldihexadecylammonium (hydroxyphenyl)tris(pentafluorophenyl) borate,
methyldihexadecylammonium (diethylaluminoxyphenyl)tris(pentafluorophenyl) borate,
methyldioctadecylammonium tetrakis(pentafluorophenyl) borate,
methyldioctadecylammonium (hydroxyphenyl)tris(pentafluorophenyl) borate,
methyldioctadecylammonium (diethylaluminoxyphenyl)tris(pentafluorophenyl) borate,
methyldioctadecylammonium tetrakis(pentafluorophenyl) borate,
phenyldioctadecylammonium tetrakis(pentafluorophenyl) borate,
phenyldioctadecylammonium (hydroxyphenyl)tris(pentafluorophenyl) borate,
phenyldioctadecylammonium (diethylaluminoxyphenyl)tris(pentafluorophenyl) borate,
(2,4,6-trimethylphenyl)dioctadecylammonium tetrakis(pentafluorophenyl) borate,
(2,4,6-trimethylphenyl)dioctadecylammonium (hydroxyphenyl)tris(pentafluorophenyl)-borate,
(2,4,6-trimethylphenyl)dioctadecylammonium (diethylaluminoxyphenyl) tris(pentafluorophenyl)borate,
(2,4,6-trifluorophenyl)dioctadecylammonium tetrakis(pentafluorophenyl)borate,
(2,4,6-trifluorophenyl)dioctadecylammonium (hydroxyphenyl)tris(pentafluorophenyl)-borate,
(2,4,6-trifluorophenyl)dioctadecylammonium (diethylaluminoxyphenyl)tris-(pentafluoro-phenyl) borate,
(pentafluorophenyl)dioctadecylammonium tetrakis(pentafluorophenyl)borate,
(pentafluorophenyl)dioctadecylammonium (hydroxyphenyl)tris(pentafluorophenyl)-borate,
(pentafluorophenyl)dioctadecylammonium (diethylaluminoxyphenyl)tris(pentafluoro-phenyl) borate,
(pentafluoromethylphenyl)dioctadecylammonium tetrakis(pentafluorophenyl)borate,
(p-trifluoromethylphenyl)dioctadecylammonium (hydroxyphenyl)tris(pentafluoro-phenyl) borate,
(p-trifluoromethylphenyl)dioctadecylammonium (diethylaluminoxyphenyl)tris(pentafluorophenyl) borate,
p-nitrophenyldioctadecylammonium tetrakis(pentafluorophenyl)borate,
p-nitrophenyldioctadecylammonium (hydroxyphenyl)tris(pentafluorophenyl) borate,
p-nitrophenyldioctadecylammonium (diethylaluminoxyphenyl)tris(pentafluorophenyl) borate,
and mixtures of the foregoing,
dialkyl ammonium salts such as:
di-(i-propyl)ammonium tetrakis(pentafluorophenyl) borate,
methyloctadecylammonium tetrakis(pentafluorophenyl) borate,
methyloctadodecylammonium tetrakis(pentafluorophenyl) borate, and
dioctadecylammonium tetrakis(pentafluorophenyl) borate;
tri-substituted phosphonium salts such as:
triphenylphosphonium tetrakis(pentafluorophenyl) borate,
methyldioctadecylphosphonium tetrakis(pentafluorophenyl) borate, and
tri(2,6-dimethylphenyl)phosphonium tetrakis(pentafluorophenyl) borate;
di-substituted oxonium salts such as:
diphenyloxonium tetrakis(pentafluorophenyl) borate,
di(o-tolyl)oxonium tetrakis(pentafluorophenyl) borate, and
di(octadecyl)oxonium tetrakis(pentafluorophenyl) borate;
di-substituted sulfonium salts such as:
di(o-tolyl)sulfonium tetrakis(pentafluorophenyl) borate, and
methylcotadecylsulfonium tetrakis(pentafluorophenyl) borate.
Preferred trialkylammonium cations are methyldioctadecylammonium and dimethyloctadecylammonium. The use of the above Brxc3x8nsted acid salts as activating cocatalysts for addition polymerization catalysts is known in the art, having been disclosed in U.S. Pat. Nos. 5,064,802, 5,919,983, 5,783,512 and elsewhere. Preferred dialkylarylammonium cations are fluorophenyldioctadecylammonium-, perfluoro-phenyldioctacecylammonium- and p-trifluoromethylphenyldi(octadecyl)ammonium cations. It should be noted that certain of the cocatalysts, especially those containing a hydroxyphenyl ligand in the borate anion, may require the addition of a Lewis acid, especially a trialkylaluminum compound, to the polymerization mixture or the catalyst composition, in order to form the active catalyst composition.
Another suitable ion forming, activating cocatalyst comprises a salt of a cationic oxidizing agent and a noncoordinating, compatible anion represented by the formula:
(Oxe+)d(Adxe2x88x92)e.
wherein:
Oxe+ is a cationic oxidizing agent having a charge of e+;
e is an integer from 1 to 3; and
Adxe2x88x92 and d are as previously defined.
Examples of cationic oxidizing agents include: ferrocenium, hydrocarbyl-substituted ferrocenium, Ag+,or Pb+2. Preferred embodiments of Adxe2x88x92 are those anions previously defined with respect to the Brxc3x8nsted acid containing activating cocatalysts, especially tetrakis(pentafluorophenyl)borate. The use of the above salts as activating cocatalysts for addition polymerization catalysts is known in the art, having been disclosed in U.S. Pat. No. 5,321,106.
Another suitable ion forming, activating cocatalyst comprises a compound which is a salt of a carbenium ion and a noncoordinating, compatible anion represented by the formula:
(copyright)+Axe2x88x92
wherein:
(copyright)+ is a C1-20 carbenium ion; and
Axe2x88x92 is as previously defined. A preferred carbenium ion is the trityl cation, that is triphenylmethylium. The use of the above carbenium salts as activating cocatalysts for addition polymerization catalysts is known in the art, having been disclosed in U.S. Pat. No. 5,350,723.
A further suitable ion forming, activating cocatalyst comprises a compound which is a salt of a silylium ion and a noncoordinating, compatible anion represented by the formula:
R33Si(Xxe2x80x2)q+Axe2x88x92
wherein:
R3 is C1-10 hydrocarbyl, and Xxe2x80x2, q and Axe2x88x92 are as previously defined.
Preferred silylium salt activating cocatalysts are trimethylsilylium tetrakispentafluorophenylborate, triethylsilylium tetrakispentafluorophenylborate and ether substituted adducts thereof. The use of the above silylium salts as activating cocatalysts for addition polymerization catalysts is known in the art, having been disclosed in U.S. Pat. No. 5,625,087.
Certain complexes of alcohols, mercaptans, silanols, and oximes with tris(pentafluorophenyl)borane are also effective catalyst activators and may be used according to the present invention. Such cocatalysts are disclosed in U.S. Pat. No. 5,296,433.
Another class of suitable catalyst activators are expanded anionic compounds corresponding to the formula: (A1+a1)b1(Z1J1j1)xe2x88x92c1d1,
wherein:
A1 is a cation of charge +a1,
Z1 is an anion group of from 1 to 50, preferably 1 to 30 atoms, not counting hydrogen atoms, further containing two or more Lewis base sites;
J1 independently each occurrence is a Lewis acid coordinated to at least one Lewis base site of Z1, and optionally two or more such J1 groups may be joined together in a moiety having multiple Lewis acidic functionality,
j1 is a number from 2 to 12 and
a1, b1, c1, and d1 are integers from 1 to 3, with the proviso that a1xc3x97b1 is equal to c1xc3x97d1.
The foregoing cocatalysts (illustrated by those having imidazolide, substituted imidazolide, imidazolinide, substituted imidazolinide, benzimidazolide, or substituted benzimidazolide anions) may be depicted schematically as follows:
wherein:
A1+ is a monovalent cation as previously defined, and preferably is a trihydrocarbyl ammonium cation, containing one or two C10-40 alkyl groups, especially the methylbis(tetradecyl)ammonium- or methylbis(octadecyl)ammonium-cation,
R8, independently each occurrence, is hydrogen or a halo, hydrocarbyl, halocarbyl, halohydrocarbyl, silylhydrocarbyl, or silyl, (including mono-, di- and tri(hydrocarbyl)silyl) group of up to 30 atoms not counting hydrogen, preferably C1-20 alkyl, and
J1 is tris(pentafluorophenyl)borane or tris(pentafluorophenyl)aluminane.
Examples of these catalyst activators include the trihydrocarbylammonium-, especially, methylbis(tetradecyl)ammonium- or methylbis(octadecyl)ammonium- salts of:
bis(tris(pentafluorophenyl)borane)imidazolide,
bis(tris(pentafluorophenyl)borane)-2-undecylimidazolide, bis(tris(pentafluorophenyl)borane)-2-heptadecylimidazolide, bis(tris(pentafluorophenyl)borane)-4,5-bis(undecyl)imidazolide,
bis(tris(pentafluorophenyl)borane)-4,5-bis(heptadecyl)imidazolide,
bis(tris(pentafluorophenyl)borane)imidazolinide,
bis(tris(pentafluorophenyl)borane)-2-undecylimidazolinide, bis(tris(pentafluorophenyl)borane)-2-heptadecylimidazolinide, bis(tris(pentafluorophenyl)borane)-4,5-bis(undecyl)imidazolinide,
bis(tris(pentafluorophenyl)borane)-4,5-bis(heptadecyl)imidazolinide,
bis(tris-(pentafluorophenyl)borane)-5,6-dimethylbenzimidazolide,
bis(tris(pentafluorophenyl)borane)-5,6-bis(undecyl)benzimidazolide,
bis(tris(pentafluorophenyl)alumane)imidazolide,
bis(tris(pentafluorophenyl)alumane)-2-undecylimidazolide, bis(tris(pentafluorophenyl)alumane)-2-heptadecylimidazolide, bis(tris(pentafluorophenyl)alumane)-4,5-bis(undecyl)imidazolide,
bis(tris(pentafluorophenyl)alumane)-4,5-bis(heptadecyl)imidazolide,
bis(tris(pentafluorophenyl)alumane)imidazolinide,
bis(tris(pentafluorophenyl)alumane)-2-undecylimidazolinide,
bis(tris(pentafluorophenyl)alumane)-2-heptadecylimidazolinide,
bis(tris(pentafluorophenyl)alumane)4,5-bis(undecyl)imidazolinide,
bis(tris(pentafluorophenyl)alumane)-4,5-bis(heptadecyl)imidazolinide,
bis(tris(pentafluorophenyl)alumane)-5,6-dimethylbenzimidazolide, and
bis(tris(pentafluorophenyl)alumane)-5,6-bis(undecyl)benzimidazolide.
A further class of suitable activating cocatalysts include cationic Group 13 salts corresponding to the formula:
[Mxe2x80x3Q12Lxe2x80x2lxe2x80x2]+(Arf3Mxe2x80x2Q2)xe2x88x92
wherein:
Mxe2x80x3 is aluminum, gallium, or indium;
Mxe2x80x2 is boron or aluminum;
Q1 is C1-20 hydrocarbyl, optionally substituted with one or more groups which independently each occurrence are hydrocarbyloxy, hydrocarbylsiloxy, hydrocarbylsilylamino, di(hydrocarbylsilyl)amino, hydrocarbylamino, di(hydrocarbyl)amino, di(hydrocarbyl)phosphino, or hydrocarbylsulfido groups having from 1 to 20 atoms other than hydrogen, or, optionally, two or more Q1 groups may be covalently linked with each other to form one or more fused rings or ring systems;
Q2 is an alkyl group, optionally substituted with one or more cycloalkyl or aryl groups, said Q2 having from 1 to 30 carbons;
Lxe2x80x2 is a monodentate or polydentate Lewis base, preferably Lxe2x80x2 is reversibly coordinated to the metal complex such that it may be displaced by an olefin monomer, more preferably Lxe2x80x2 is a monodentate Lewis base;
lxe2x80x2 is a number greater than zero indicating the number of Lewis base moieties, Lxe2x80x2, and
Arf independently each occurrence is an anionic ligand group; preferably Arf is selected from the group consisting of halide, C1-20 halohydrocarbyl, and Q1 ligand groups, more preferably Arf is a fluorinated hydrocarbyl moiety of from 1 to 30 carbon atoms, most preferably Arf is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms, and most highly preferably Arf is a perfluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms.
Examples of the foregoing Group 13 metal salts are alumicinium tris(fluoroaryl)borates or gallicinium tris(fluoroaryl)borates corresponding to the formula: [Mxe2x80x3Q12Lxe2x80x21xe2x80x2]+(Arf3BQ2)xe2x88x92, wherein Mxe2x80x3 is aluminum or gallium; Q1 is C1-20 hydrocarbyl, preferably C1-8 alkyl; Arf is perfluoroaryl, preferably pentafluorophenyl; and Q2 is C1-8 alkyl, preferably C1-8 alkyl. More preferably, Q1 and Q2 are identical C1-8 alkyl groups, most preferably, methyl, ethyl or octyl.
The foregoing activating cocatalysts may also be used in combination. An especially preferred combination is a mixture of a tri(hydrocarbyl)aluminum or tri(hydrocarbyl)borane compound having from 1 to 4 carbons in each hydrocarbyl group or an ammonium borate with an oligomeric or polymeric alumoxane compound.
The molar ratio of catalyst/cocatalyst employed preferably ranges from 1:10,000 to 100:1, more preferably from 1:5000 to 10:1, most preferably from 1:1000 to 1:1. Alumoxane, when used by itself as an activating cocatalyst, is employed in large quantity, generally at least 100 times the quantity of metal complex on a molar basis. Tris(pentafluorophenyl)borane, where used as an activating cocatalyst is employed in a molar ratio to the metal complex of form 0.5:1 to 10:1, more preferably from 1:1 to 6:1 most preferably from 1:1 to 5:1. The remaining activating cocatalysts are generally employed in approximately equimolar quantity with the metal complex.