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2014 Depth Chart: Detroit Lions
[depth chart last updated 7/3/14]
• So the first question is obvious. How come we have Reggie Bush as a good player and Joique Bell with an identical rating? Truthfully, I think with more carries, Bell would actually show himself to be a better player. This was by far Bush's best all-around season and we still had Bell graded higher and, as a receiver, significantly so. He takes the ball in far less opportune areas (short yardage) and just makes things happen. Of those players with over 50 carries he ranked eighth in forced missed tackles per attempt and he's only getting better.
• It might be a little bit early to put Larry Warford in the "high quality" category, but he did so little wrong it was hard to argue against. In our view he should have been a starting Pro Bowler and the fact Kyle Long was selected before him shows just how twisted the system has become.
• I wanted to put Jason Jones down as "below average" but Khaled talked me out of it. Now as a pass rushing defensive tackle he may well be better than that but at end he's never played well. Tennessee decided to play him there in 2011 after a stellar season the prior year in the interior. It was a disaster and frankly it looked it may go that way again last year before injury cut it short.
Roster Battles
1. Third Wide Receiver
The selection of Eric Ebron means maybe the Lions will view 12 personnel the way most teams view 11 personnel but regardless there will still be three wide receivers on the field and it will be often. Ryan Broyles is looking more and more like a second round bust managing three drops on 11 catchable balls in 114 pass routes. His 0.77 Yards Per Route Run (despite having Calvin Johnson drawing coverage) was an appalling return. Now, teams don't give up on that high a pick without a fight so he'll probably get at least training camp to pick up his game. Both Kris Durham and Kevin Ogletree also had issues so maybe T.J. Jones has a chance. However it pans out this doesn't look like a position of strength for Detroit.
2. Strongside Linebacker
This may not end up being much of a "battle" but perhaps I'm dismissing Ashlee Palmer too easily and draftee Kyle Van Noy will not play to expectations. It's thought the job is his, but rookies have a trait of not being easy to predict. Add to this Palmer, while not doing a great job, wasn't completely awful either and it at least has the makings of a scrap if not an all-out war.
3. Cornerback
Many see the whole corner situation in Detroit as a festering sore and were shocked when the Lions went tight end in the first round and didn't take (or trade down to take) one of the four first round CBs taken after their pick. Indeed they didn't take a corner until the fourth round (Nevin Lawson) which suggests they are happier with what they have than others. Is their reason for optimism? Well Rashean Mathis did a much better job than expected and if he can replicate his late season form he'll be a starter in base. After that though things get hazy. Chris Houston looked terrible before bowing out in week 14 and Darius Slay looked out of his depth (at least early) before having a little late-season success. In the slot, Dwight Bentley had an inconsistent year with unfortunately a lot more poor games than good ones.
Mixed bag is too kind a phrase and I'm expecting a lot of experimentation before they finalize the nickel secondary from that lot.
[NB: I'm now on holiday for a week, so Gordon McGuinness will be taking over completing the depth chart articles in my absence. If you have any updates you can contact him on Twitter: @PFF_Gordon]
Click here to see all of the depth charts we've covered.
Follow Neil on Twitter: @PFF_Neil


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UC Riverside basketball roster
Think about what career is best suited for you, and where you want to study. Request more information now.
Think about what career is best suited for you, and where you want to study. Request more information now.
Think about what career is best suited for you, and where you want to study. Request more information now.
Find information about UC Riverside basketball roster, and registering for discussion sections and departmental electives. Not all recruiting is done like NCAA Division I teams. College coaches at different division levels have different recruiting practices. Finally, check with your major department for assistance with prerequisites, tuition payment deadlines, and UC Riverside Basketball information. Please use the form above to request admissions info for UC Riverside.
Always maintain a positive attitude, especially when you're in pain, or losing a game. Be a good sport, and keep trying. Believe you'll be successful, act like you can still win the game, and then go out and make it happen. Be aggressive, and make a second try on a given play if you have time. It's one thing to make a good effort, but great players keep trying until they succeed, no matter how many years of team practice that takes.
If you get lazy, and decide to take it easy during practice, coaches will take notice. Push yourself, work hard, and you'll improve as a player. It's important to find a position that you really like to play, not just settle for what you're good at. Over the long haul, you'll have a better athletic career. Rowan-Cabarrus Community College ice hockey team may indicate that it's an option to delay college entrance by a year. An extra year in high school or prep school can allow players to mature mentally, bring grades and SAT test scores up, put on weight and gain strength. Beyond consideration for UC Riverside basketball roster, you may think about Lake Area Tech exam preparation for complementary electives to your primary course of study.
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April 24 ) Diving vessel stormed by at least 13 pirates with knives & pistols , near Lingga Islands in Malacca Straits stripping crew of cash & valuables before escaping. More than 100 fishermen either managed to reach shore or were rescued at sea by search teams from navy, coast guard, air force & villagers. Three pirates armed with knives boarded tanker at poop deck. 28 ) M/V Vihan 05 200km/h wind swept away ship from anchoring shelter only 1. Master & 3/o ordered to board patrol boat for cargo documents inspection. 9W, 3 miles off port entrance, Dakar, Senegal pirates armed with knives boarded container ship departing Dakar.


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Welcome to Dottie's Detox Diary: My Kuka Juice Cleanse
Yep, that's right. My seven day Kuka juice cleanse using begins today! (Kuka Juice is located in downtown Greenville and all juice is cold pressed locally. I can't wait to share with you this week why I love Kuka!) More on Kuka
I have wanted to do another cleanse for a while now, so I figured I might as well invite you to come along. #accountability
I am no stranger to detoxing, but I would never identify myself as a 'joyful juicer' or a 'super happy and compliant detoxer.' I can pretty much guarantee that my close friends are rolling their eyes and shaking their heads at my latest antic! Maybe not, but I may not get called to go to Community Tap this week!
My history with juicing began around 2012 after watching the documentary Fat, Sick and Nearly Dead. I am all about trying new things and after seeing Joe's amazing transformation, I decided to give it a go. I settled on the cheapest juicer Target had to offer and got to work. I was immediately horrified at how much produce it takes to get a 8oz of juice. I committed to three days of only juice. I found myself at the local Mexican restaurant double fisting the chips and dip before the sun set on day three.
My juicer sat idle until I begin following Meredith Baird's blog(Anderson friends, y'all know the fabulous Meredith!) and read her book, Everyday Raw Detox. She educated me on the importance of the type of juice you are drinking and how much. Her mixture of ingredients and her recipes created a balance of needed nourishment and cleansing elements. My concept of juicing expanded, and I began experimenting with her recipes. I spent this time focusing on learning more about adding raw juice to my diet rather than attempt another cleanse. I learned to enjoy it more and saw changes in the way I felt and even my complexion. It was also during this time that I added a Vitamix to my kitchen counter. I was immediately hooked, and I still use it pretty much everyday.
And as the story goes, my desire for mimosas outweighs my want of kale juice. My juicer collected dust and my Vitamix makes a mean margarita. I have not committed to another juice only cleanse…until now.
I have sought to be open on my blog about my relationship with food,(article in Whole Magazine), body image, and a full on love hate relationship with fitness. My #30before30 project opened up these ideas to focus much more on my inner health than a desired external result. It has NOT been a linear journey. I have had victories and setbacks, as I am sure most of y'all can agree. I have stocked my shelves with chia seeds, but there is an empty pack of Oreos in my trash can. Following my father's death, I jumped head first into old patterns of escapism , finding comfort in Krispy Kreme and wine. And like so many, I have jumped on and off and on an off. But as I have said before, and believe so deeply, it doesn't matter how many times you 'fall off' as long as you 'get back on.'
What I have been most grateful for during the last several years of reeducating myself on food is that I genuinely FEEL better from the bottom of feet to the top of my head when I nourish myself with the real stuff. And the past nine months have been a case study in how wretched I can feel when I choose to not, but how amazing I feel when I do.
The past few months, I have enjoyed being filled with the joy and energy healthy living gives me.
Whether I am kickboxing with my friend Erika
or pretending to be a ballerina at Barre class, I love that working out is an instant mood lifter.
Instead of doughuts, I am actually cooking my chicken and veggies again. And while I have cut out a lot of the junky junk junk, I still have lots of improvements to make.
WHY THE KUKA CLEANSE? In short, the ladies of Kuka embody living their joy and passion. Their connection with each other, desire for whole living, and general hustle has inspired me since I first discovered their juice. It was really a no brainer that I wanted Kuka to be part of my sharing this week with you guys, and check back daily for more on Kuka...
My desire is to create a space that encourages us to live each day with joyful purpose and intention.
I believe the most important work of our lives is discovering our true identity and living in that truth.
I believe that if we seek to find our worth and value in God alone then we can live with greater peace and joy.
For me this cleanse I am beginning today is about leaning more into the living a healthy life in body and spirit.
Sure, I want to drop a few pounds like most women, but I am embracing this next week with a different pursuit. I truly want to nourish my insides the way I am intentionally nourishing other parts of my life on this journey. My father did not take care of his physical body. In fact, I would argue he abused it—lack of rest, poor diet, no exercise---the list goes on and on. You may even be like him--a person who takes care of everyone but yourself. As I look towards another birthday, I can't help but refocus my motivations for my physical body. This is not a quick fix . And I would not even call it a 'reset.'
It's just another step towards onward and upward.
So, over the next week, I would love for you to follow my detox, and hey—join me if you dare! To follow @DottieCamak, use hashtags: #krazyforkuka #yeahTHATgreenville #whatsgoingongvl #greenvillesc #juicing #coldpressed #dottiesdetox #mykukacleanse #myjuicecleanse
And moving forward, I will still be the girl who takes pictures of my potions
Especially when I put them in a wine glass
I will always tell you when I make something healthy and whole
And shy away from revealing my Bojangles incidents.
I will still raise a glass or three of champagne (and on occasion Rose, if I'm feeling fancy!)
And coffee will be my forever friend
But I'm a total fan of challenges(especially when it means I WON a shopping spree--THANK YOU BARRE EVOLUTION)
So here's to riceless sushi instagrams
But saying yes to living in the present and heck, sometimes that means big old fried sushi rolls and fun! (And POSTING THOSE PHOTOS TOO!)
I am going to choose joy and keep choosing it
And I can bet this next week is going to be a real test!
For all the details on what my seven days will consist of, stay tuned for new content everday! I will let you know all the fun facts!
Follow me for live blogging, updates, and more---
For LIVE updates: TWITTER
To follow, use hashtags: #krazyforkuka #yeahTHATgreenville #whatsgoingongvl #greenvillesc #juicing #coldpressed #dottiesdetox #mykukacleanse #myjuicecleanse


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With record low temperature and the Northern United States coming out of one of the most severe cold snaps in recorded history, the climate change naysayers are having a field day! It's time for them to listen to the Hard Truth!
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Once you've added a video visit "My Queue" to start watching!


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Are your wallets ready? That "rainy day" fund may be about to evaporate as Amazon Prime Day is upon us again. The e-doors officially open tomorrow, July 11, but the sale starts tonight at 9 p.m. EST, so definitely set your alarms if you want in on the deal mayhem. But how exactly should you navigate all of it? What's the winning strategy? Here's everything you need to know, courtesy of the experts at BestBlackFriday.com, who suggest the following tips for winning Prime Day 2017.
A special thank you to the experts at Slickdeals.net and NerdWallet team for sharing additional insights.
Pro-tip digest:
- New deals will be posted every five minutes for 30 hours until 3 a.m. ET on July 12.
- Downloading the free Amazon App is probably the best tool to guarantee that you don't miss the deal that you want. And make sure to turn on the alerts!
- Use your desktop or laptop computer for purchases. While Amazon's app is great for browsing and finding upcoming deals, it's best to make the actual purchases on a computer, especially if you're heavy on the multi-tab usage.
- If you aren't a Prime member, it's a good time to take advantage of a 30-day trial.
- Make sure your Prime account is in good standing and all personal information is correct and updated — deal urgency is obviously a factor here so any lost time could get be a deciding factor in getting that sweet discount.
- Consider competitor store sales. While Amazon is obviously commanding the spotlight on Prime Day, competitors like Macy's, Kohl's, Best Buy and Nordstrom all have big July sales under way. Keep your eyes open — offers.com is one site that's compiling the sales.
Now that you're prepared, here's a breakdown of the most anticipated deals so far. I'll update this list as more deals are announced.
The most anticipated digital doorbusters*:
- Amazon Echo – $89.00 (a whopping $90 savings)
- Amazon Echo Dot – $34.99 ($15 savings)
- Oculus Rift Touch Bundle – $399 ($199 savings, influenced by Prime Day)
- Kindle Paperwhite E-reader – $89.00 ($30 savings)
- Fire HD 8 Kids Edition Tablet, 8″ Display – $89.00 ($40 savings)
- Fire 7 Tablet with Alexa, 7″ Display – $29.99 ($20 savings)
- 32-inch 720p TCL TV – $99.99
- 40-inch 1080p TCL TV – $199.99
- August Smart Lock – $145.39 ($50 expected savings)
Free giveaways:
Whether you're planning on spending money or not, free giveaways are popping up every hour, up to when Prime Day starts. So, even right now you could be enjoying some freebies with a little bit of luck and a tap of your screen. What exactly is up or grabs? So far, giveaways have included a Nintendo Switch, Amazon Echo (surprise, surprise), Samsung Home Theatre System, Apple iPad mini 4, Nikon D3400, PlayStation 4 Slim, iRobot Roomba 614 and 12″ Apple MacBook. You definitely need to keep your eyes on the time, though — a recent giveaway for a MacBook Pro was only open for two minutes before a winner was selected.
To access the giveaways:
- Open your Amazon App, (or click here)
- Click the category icon at the very top left of the app
- Click the 'Win prizes daily up to Prime Day' 'category' button at the top left
- Scroll down under 'Today's Prize' and click any giveaway that interests you
- Watch the 30-second video and press 'continue' to the giveaway
Experts weigh in:
Courtney Jespersen, a retail and shopping expert at NerdWallet, shared some insights for anyone looking to take advantage of the sales:
Prime Day only lasts for 30 hours. The time-sensitive nature of the event can put added pressure on a consumer's decision and might encourage shoppers to make a snap purchase. But there's no excuse for not doing your homework. If you're a price-sensitive shopper already, you'll know a good price when you see it. For instance, audiophiles who have been watching the price of the Echo Speaker week after week will know a major price drop when they see it.
Jespersen added:
But if you've never researched the price of a 70-inch TV before Prime Day, don't buy the first one you see just because Amazon says it's a good sale. The Internet has made it easier than ever to research the price history of a product, just by Googling the product name. In fact, you can search for the name of a product along with "Prime Day 2016" to see how this year's price compares to last year. While you're at it, see what it sold for on Black Friday 2016. Knowing the price history of a product can color your decision.
Watch On Forbes: A Poor Millennial's Guide To Investing
Kimberly Palmer, credit card expert at NerdWallet, also suggests that buying with credit may not be a terrible idea if thought about correctly:
If you've been planning to buy something on Amazon — especially something pricey — then clicking "purchase" on Amazon Prime Day can end up saving you money — up to 20% cashback on many items. The Amazon Prime Store Card already offers 5% cashback on Amazon purchases, so that's an additional 15% cashback. Just be sure that you pay for your purchase with your Amazon Prime Store card; if another card is automatically selected as the default payment, then you can lose out on the cashback.
And if you have your eye on a specific big-ticket item, you might want to buy it early in the day because supplies are limited. To avoid overspending or buying items you don't need, plan what you want to purchase in advance, before July 11, and then wait to actually make the purchase on your card until the cashback deals begin.
Additional Resources:
- Slickdeals.net has a dedicated Amazon Prime Day page showcasing the best deals, coupons, promo codes, and discounts.
- BestBlackFriday.com will be live blogging the entire Prime Day 2017 sale starting from when the first deal goes live. They'll also be taking it a step further and posting last year's Black Friday prices to truly deem them a "deal or dud" status.
So there you have it, folks. Get excited about great deals and have a fun Prime Day!
Tom is a serial e-commerce entrepreneur passionate about the creation + delivery of transformative digital experiences at scale. Connect with him on LinkedIn or follow him on Twitter.
Do you have an unusual story to tell? E-mail firstname.lastname@example.com


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July 3, 2017
Check Out Summer League Live Audio Stream!
Sixers fans, our free summer league audio stream is back for another year.
If you're not able to follow the #SummerSixers on television, we invite you to use your computer or mobile device to listen along. There are a couple of ways to tune in:
The stream for each game the Sixers play in both the Utah Jazz and NBA Summer Leagues over the next two weeks should begin approximately 10 minutes before tip-off. In addition to live coverage split between Sixers Radio Network announcer Tom McGinnis and Sixers.com's Brian Seltzer, the summer league audio broadcasts will feature in-game guest interviews as well.
Be sure to check Sixers.com or any of the team's social channels on gamedays for updated streaming information.


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Northeastern State University computer classes online
Think about what career is best suited for you, and where you want to study. Request more information now.
Think about what career is best suited for you, and where you want to study. Request more information now.
Think about what career is best suited for you, and where you want to study. Request more information now.
Info concerning Northeastern State University computer classes online, and registering for elective seminars and lectures. Which college degrees give you the best chances of finding employment after graduation? In order to earn a higher salary, you may complete an accredited business degree program, or develop additional office experience. Concentrating on Northeastern State University computer classes online, for example, you may gain an advantage in corporate recruiting being done on-campus. Check with the IT certificate department for course registration deadlines, and computer training program requirements. Please use the form above to request admissions info for Northeastern State University.
Doing business online is one of your best options to raise extra income. Success is governed by two main factors, visitor traffic and sales conversions. How many of the right people can you attract to your site, and how many of those people can you persuade to take a given action? There's no rent to pay when starting a business online, unless you count yearly domain name registration and monthly website hosting, both of which are minor. Basically, you need to register a domain name describing the type of business you want to start, and then build the website using a template in HTML, adding a database and programming routines as needed.
Just making a website isn't enough, if no-one can find it on Google, Yahoo, Bing, or Baidu, which collectively account for 94% of all searches. You'll then need online marketing skills, and the ability to drive conversions. To get valid incoming links, write some more articles, and submit to article hubs, or post on Facebook and Google Sites, with 3 to 4 links on each page that deep-link to your own website pages, not just to your homepage. Beyond major requirements within the IT certificate department, you may consider East Carolina University dropping a class as a complementary elective to your primary course of study.
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The Dark Knight Rises Release Date & Preview
This action/drama movie will be released on 20 July 2012. Christopher Nolan is the director and Jonathan Nolan is the writer for this film. Christopher Nolan is the first director to complete a full trilogy of Batman films. Batman is coming back to fight most dangerous enemy Bane. You will also see Catwoman and Batman together in this fantasy movie. Christian Bale is playing role of Bruce Wayne/Batman who is one of the most prominent actors of Hollywood. He has distinction of being first living actor who portray Batman in three Batman films.
One interesting fact about this mega film is its huge budget (total estimated budget of film is around $250,000,000). Warner Bros. Pictures, DC Entertainment and Legendary Pictures are the production companies of this film. This film is one of the most expensive movies of year 2012.
The Dark Knight Rises Star Cast and Crew
This film has mega cast which includes actors like Tom Hardy, Joseph Gordon Levitt, Anne Hathaway, Christian Bale and Liam Neeson. Tom Hardy is playing negative role of 'Bane' in this film. Anne Hathaway is playing role of Catwoman and Christian Bale is coming as Batman. Other stars include Gary Oldman, Cillian Murphy, Marion Cotillard, Morgan Freeman, Michael Caine, Juno Temple, Daniel Sunjata, Joey King, Matthew Modine and Reggie Lee.
The Dark Knight Rises Plot & Story
Jonathan Nolan is the story writer and Christopher Nolan is the screenplay writer for this movie. Plot of movie is about dangerous terrorist leader Bane who arrives in Gotham City. Batman is the hero of Gotham City but Bane pushes him to breaking point.
So get ready to watch most spectacular fight between Batman and Bane in the summer of 2012. Producers spend huge sum of money on shooting of this movie. In one scene around 10,000 extras were used to shoot the Gotham Rogues scene in Heinz Field.
The Dark Knight Rises Release Dates all Around the World
- Italy: 18 July 2012
- Australia, Hong Kong, Hungary, Malaysia, Singapore: 19 July 2012
- Canada, Lithuania, Sweden, UK, USA: 20 July 2012
- Belgium, Finland, France, Netherlands, Norway: 25 July 2012
- Spain: 26 July 2012
- Brazil, South Africa, Turkey: 27 July 2012
- Portugal: 2 August 2012
- Poland: 3 August 2012
- Lebanon: 16 August 2012
The Dark Knight Rises Summary & Synopsis
- Star Cast: Christian Bale, Joseph Gordon Levitt, Tom Hardy, Anna Hathaway
- Director: Christopher Nolan
- Writers: Jonathan Nolan, Christopher Nolan
- Production Company: Warner Bros. Pictures, DC Entertainment, Legendary Pictures
The Dark Knight Rises Wallpapers & Pictures
The Dark Knight Rises Trailer


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New Delhi: Majority of small and medium enterprises have demanded lowering cost of finance and additional fiscal support from the government to provide relief to the sector hit by the demand contraction in the global markets, a survey has said.
Over 90% of small and medium enterprises (SMEs) surveyed by industry body Ficci said that demand slowdown has badly impacted them.
"The participating companies indicated that they have lost most of their major markets primarily in Europe and United States and are struggling to find new markets for their products," the survey based on responses of 116 units said.
SMEs "single point demand" is for better financial accommodation by the banks at lower interest rates, it said, adding about 90% of the units depend on banks to meet their finance needs.
"In order to provide some immediate respite for the SME sector, which is facing a lot of problems ... lowering cost of financing and having additional fiscal support from the government is the need of the hour," it said.
The SMEs said the two per cent subsidy on interest rate announced for the units engaged in exports is not reaching the intended beneficiaries at the ground level, the survey said.
It also pointed that 87% of the units were not aware about the government's schemes for the sector.
"An action programme for better communication of government initiatives for the SME sector is called for," the chamber said.
The government has announced several steps including removal of fringe benefit tax, additional fund under Vishesh Krishi and Gram Udyod Yojna and extension of duty neutralization and interest subsidy schemes.
The sector, which contribute significantly to the country's exports, wants faster processing of loans, government support in modernization, and better marketing support besides other incentives.
FICCI said the SMEs have to bear undue delay in receiving payments from other companies and public enterprises and it leads to blocking of funds for SMEs which affects their day-to-day operations.


text: Monster Trucks Tripp (Lucas Till), a senior high school student who is looking for a way out to get rid of the whole town and all the while, makes himself a monster truck. In those days, a rumor spread that an unusual creature, living underground, emerged as a result of an accident in an oil well nearby. Facing an unexpected turn with this creature, Lucas becomes friendly with this speedy adorable creature. The beast will be the ticket that will lead him to life as he wishes.


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Presidential wanna-be Donald Trump has been playing the "Billionaire card," the "Bully card," the "Washington outsider" card and even the "Man's Man/My physical assets are plenty big card." But the one card he doesn't hold is the Woman's card, which is no longer a joker in a leader's hand. Today, the woman's card is an Ace and that's what scares Donald Trump to death. My advice to Hillary Clinton: Play it Hillary!
Hillary's response to his latest whine was pitch perfect. Deal me in!
When Liberian leader Leymah Gbowee, winner of the 2011 Nobel Peace Prize, speaks people listen. And wait till you hear the challenge she issued to the women gathered at the 2012 Women in the World Summit last week in New York.
I was there for every riveting moment. Here's the column I just wrote about the event for Forbeswoman.


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Not the typical roadside memorial in National City
"Yeah, eight years. We come out every year on the night it happened."
Edward Magdaleno noon, Sept. 21
Went out for my bike ride but knew something was wrong (10/26/2003 8:37am)
Photo by Madzu
Posted September 26, 2008
Edward Magdaleno noon, Sept. 21
Dorian Hargrove 10:30 a.m., Sept. 21
Mike Madriaga 10 a.m., Sept. 21
Daniel Powell 8:30 a.m., Sept. 21
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text:
- Artist
- Period Active
30 Nov 1996 UNITED STATES OF AMERICA
- Type
Male Solo
- Genre
- Debut
30 Nov 1996
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Volume 35, Issue 8
Pages 795–915
Currently known as: Angewandte Chemie International Edition
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199607931
The cover picture shows schematically the structures of dimeric and trimeric complexes of two leucine zipper peptides (designated A and L) and the assigned peaks of the molecular ions in the ESI mass spectrum. The equilibria between the three homo- and heteromeric dimers and the four homo- and heteromeric trimers are recognizable in the spectrum. The development of ESI mass spectrometry and its perspectives for analysis of supramolecular complexes are discussed by M. Przybylski and M. O. Glocker on page 806 ff.
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199607951
Prof. Dr. Michael Przybylski and Dr. Michael O. Glocker
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608061
Soft ionization methods that yield singly and multiply charged ions of intact complexes containing noncovalent interactions enable the direct mass spectrometric analysis of biomacromolecular complexes such as protein dimers, double-stranded polynucleotides, enzyme–substrate and enzyme–cofactor complexes, and host–guest systems. The method of choice for analysis of supramolecular structures in solution is electrospray mass spectrometry, which is the focus of this review.
Priv.-Doz. Dr. Matthias Driess and Prof. Dr. Hansjörg Grützmacher
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608281
Carbon is an "exotic" element. This is the conclusion drawn following the comparison of the structures and electronic properties of olefins, cyclopropanes, and bicyclo[1.1.0]butanes with related compounds composed of the carbene-analogous elements or fragments X,Y of the heavier Group 13–15 elements (shown schematically on the right). The structures and properties of these inorganic compounds are determined by the intrinsic characteristics of the corresponding carbene analogues X:. The structural distortions in doubly bonded systems can be discussed on the basis of the Carter–Goddard–Malrieu–Trinquier (CGMT) model. Thus, rules with broad application concerning the prediction of structures and electronic character can be better derived by studying the compounds with heavy main group elements.
Dr. Aran Paulus
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608571
The smaller the better! Capillary electrophoresis aims at ever smaller amounts of analyte, as demonstrated by the latest developments described here. Recent results fuel the ultimate dream of the chemist: to find the needle in the haystack and play with it, or to separate and identify by spectroscopy a single component in a complex mixture and subsequently manipulate it, even if it is a single molecule.
Prof. Dr. Robert Schöllhorn
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608591
Modulated thin layer precursor systems provide the basis for a novel rational synthesis strategy for the controlled preparation of complex metastable structures. By sequential deposition of the elements required and subsequent thermal treatment, specific superlattices with alternating composition can be synthesized. The picture shows, as an example, a niobium titanium selenide in which the niobium content increases from top to bottom (intra- and interlayer distances increase; one half of the unit cell of the superlattice is shown).
Dr. Kirill Lukin, Dr. Jianchang Li, Dr. Richard Gilardi and Prof. Philip E. Eaton
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608641
The first direct metalation of a β-CH bond activated by nitro groups is seen in the reaction of 1,3,5,7-tetranitrocubane (1) with base (see below). Such β-nitro carbanions were used to synthesize penta- (2) and hexanitrocubanes, the first cubanes containing vicinal nitro groups.
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608661
A new synthetic method—β-metalation of nitrocubanes with amides of tin or lead—was used to make a series (n = 1-4) of stable stannyl and plumbyl derivatives. Appropriate cleavages of the cubyl–lead bonds provided tetrahalotetranitro-cubanes and penta- and hexanitrocubanes (see below; R = Me, Et; R′ = Et, SiMe3; X = Br, I).
Qun Huang, Prof. Xintao Wu, Quanming Wang, Tianlu Sheng and Jiaxi Lu
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608681
A one-dimensional polymeric anion chain, composed of octanuclear cyclic cluster fragments [W4Ag4S16]4− linked through Ag+ ions (see below), has been isolated from the ammonium tetrathiotungstate/silver nitrate system. Lanthanide(III) ions (Nd or La), which are coordinated by eight DMF ligands and play a crucial role in the formation of the cluster compound, are encapsulated between the chains.
Dr. Lutz Eggers, Prof. Volker Buss and Prof. Dr. Gerald Henkel
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608701
The P-helically twisted chromophore of the chiral monomethine dye (R,R)-1 (structure shown on the right) shows a negative Cotton effect for the long-wavelength cyanine band—in apparent violation of established helicity rules. Quantum mechanical calculations and a component analysis support the experimental findings, lending surprisingly additional support for those rules. X = C(CH3)C3H7, counterion: ClO.
Masayuki Nishio, Dr. Hiroyuki Matsuzaka, Dr. Yasushi Mizobe and Prof. Masanobu Hidai
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608721
Surprisingly, nine sulfur atoms are present in the bridging polysulfido ligand in the diiridium complex 1 (shown on the right), which was prepared by the reaction of 2 with S8. Upon treatment with NaBPh4, the nonasulfido ligand in 1 is converted into a bridging disulfido ligand, and this reaction is accompanied by a one-electron oxidation of the diiridium core to give the paramagnetic diiridium cation 3. Cp* = C5Me5.
Dipl.-Chem. Henry Bernhardt, Priv.-Doz. Dr. Wolfgang Weissflog and Prof. Dr. Horst Kresse
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608741
Derivatives of pyridine and benzoic acid having suitable structures can associate through single hydrogen bonds to form liquid crystalline systems. The "know-how" was established by systematically varying the substituents on the benzoic acid (see below): weakly electron-withdrawing substituents are the most efficient for inducing a liquid crystalline state when the substituent on the pyridine ring is an electron donor.
Prof. Dr. Alexander C. Filippou, Dipl.-Chem. Dirk Wössner, Dr. Bernhard Lungwitz and Dr. Gabriele Kociok-Köhn
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608761
The first carbene complexes 1 (R = H, Me; X = Cl, Br) of divalent chromium were obtained selectively by addition of hydrogen halides to the metal–carbon triple bond in [(η5-C5R5)(CO)2Cr≡CNiPr2]. These carbene complexes react with isocyanides, phosphanes, and phosphites to give cationic CrII carbene complexes.
Prof. Dr. Yoshinao Tamaru, Sachio Goto, Akihiro Tanaka, Masamichi Shimizu and Dr. Masanari Kimura
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608781
The first nucleophilic additions of propargylpalladium complexes have been achieved with the reactions (a), R1 = H, Me, Ph, R2 = H, Me, Ph, SiMe3. In these reactions in addition to the homopropargyl alcohol 1, the allenyl alcohol 2 was only formed for R1 = H, R2 = Me, Ph and the ethylallene 3 for R1 = Ph, R2 = H.
Prof. Dr. Waldemar Adam, Dr. Rajiv Kumar, Dr. T. Indrasena Reddy and Dipl.-Chem. Michael Renz
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608801
The threo epoxy alcohol 2 is the major stereoisomer formed in the epoxidation reaction of the chiral allylic alcohol 1 when the zeolite titanium silicate 1 (TS-1) is employed as heterogeneous catalyst and the urea hydrogen peroxide adduct (UHP) as oxygen source. The hydroxy-directing effect is rationalized in terms of hydrogen bond formation analogous to that for the mechanism of peracid epoxidation.
William P. Freeman, Prof. Dr. T. Don Tilley, Glenn P. A. Yap and Prof. Dr. Arnold L. Rheingold
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608821
Nearly equivalent CC distances in the five-membered ring of the dianion C4Me4Si2−, which could be isolated in crystalline form as a potassium salt in the presence of [18]crown-6 (structure on the right), suggest a high degree of delocalization. In contrast, 29Si and 13C NMR spectroscopic investigations of the silolyl anions C4Me4SiR− (R SiMe3, Si(SiMe3)C4Me4) show that delocalization in these systems is minimal.
Dr. Thorsten Bach
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608841
Photochemical reversal of polarity of a carbonyl compound facilitates the construction of N-substituted, α,β-difunctional amino oxetanes 2 by CC bond formation. The reaction with suitable alkene substrates 1 provides the products in good yields and with excellent regio- and diastereoseiectivity. R = H, alkyl; R1 = alkyl, OrBu.
Dipl.-Chem. Markus Müller, Dipl.-Phys. Jörg Petersen, Dipl.-Phys. Rainer Strohmaier, Dipl.-Phys. Christian Günther, Prof. Dr. Norbert Karl and Prof. Dr. Klaus Müllen
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608861
A simple route to the title compounds is accessible by the elegant and structure-specific cycloaddition–cyclodehydrogenation sequence (1 2). Owing to the high temperature stability of the large polybenzoid C54 hydrocarbons, they can be characterized in ordered vapor-deposited monolayers by means of scanning tunneling microscopy and electron diffraction.
Prof. Dr. K. C. Nicolaou, Mitsunobu Sato, Dr. Neil D. Miller, Janet L. Gunzner, Dr. Johanne Renaud and Dr. Edouard Untersteller
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608891
A simple and efficient route to bistetrahydropyranyl systems like 1 relies on the coupling of a stannyl enol ether with an enol triflate in the presence of a catalytic amount of [Pd(PPh3)4] and excess amounts of CuCl and K2CO3. Complex polyether structures are also accessible in good yields, as the synthesis of a structural element of maitotoxin demonstrates.
Dipl.-Chem. Hans H. Cornehl, Dr. Christoph Heinemann, Dr. Joaquim Marçalo, Dr. António Pires de Matos and Prof. Dr. Helmut Schwarz
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608911
Ion–molecule reactions between U2+ and oxygen donors or "charge-stripping" collisions between singly charged UO ions and O2 collision partners generate uranyl(2 +) ions in the gas phase. These do not readily dissociate into singly charged fragments. The standard enthalpy of formation for UO is estimated to be 371 ± 60 kcalmol−1, in accord with the results of ab initio calculations.
Nianyong Zhu, Prof. Dr. Jürgen Pebler and Prof. Dr. Heinrich Vahrenkamp
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608941
The unusually low magnetic moments of octanuclear complexes containing [Fe4S4(NCMLn)4] cluster ions (shown below) are unprecedented in the chemistry of Fe4S4 clusters and ferredoxins. The new compounds are redox-active mixed-valence complexes containing iron centers in the oxidation state +2.5 and show intense intervalence transfer absorptions.
Prof. Dr. José Barluenga, Dr. Miguel Tomás, Dr. Klaus Bieger, Santiago García-Granda and Rafael Santiago-García
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608961
Unusual structure and reactivity characterize 1, an iminophosphorane, which is formed by a 1,5-dipolar cycloaddition from a diazaphosphinine and dimethyl acetylenedicarboxylate. Compound 1 rearranges into 2 in solution, and reacts with electrophiles to give 3a,b.
Dr. Driss Chabach, Dr. André De Cian, Prof. Dr. Jean Fischer, Prof. Dr. Raymond Weiss and Prof. Dr. Mohamed El Malouli Bibout
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199608981
Either a metal atom or the phthalocyanine ligand is the site of the first oxidation of the heteronuclear triple-decker complexes of type 1, depending on whether they contain an oxidizable CeIII ion or not. Now the first X-ray structure of such a heteronuclear triple-decker complex (1, M Ce, M′ Gd, p oep) has also been achieved.
Forrest Stevens, Dr. Daniel J. Dyer and Prof. David M. Walba
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199609001
The formation of chiral structures from achiral or racemic components is of great interest because of its implications, for example, for the origin of biological chirality. Monolayers of racemic molecules can form chiral structures, but the precise origin of these structures has been unclear. Images of both enantiomers (that of the (S) enantiomer is shown on the right) and the racemate of a liquid crystal obtained by scanning tunneling microscopy present strong evidence that the racemate forms domains of enantiomerically pure molecules.
Prof. Scott R. Gilbertson and Robert V. Pawlick
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199609021
Amino acids containing potential ligand sites offer interesting perspectives for peptide–metal complexes. FMOC and BOC forms of a proline derivative with phosphanyl groups have been synthesized, and this amino acid was incorporated into a short peptide possessing β-turn secondary structure. The structures of both the peptide and its rhodium complex 1 were analyzed by 2D NMR spectroscopy.
Dr. Yoshiki Morimoto, Maki Iwahashi, Koji Nishida, Prof. Dr. Yuji Hayashi and Prof. Dr. Haruhisa Shirahama
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199609041
An asymmetric Diels-Alder reaction and an efficient construction of the A,B,D ring framework are the key steps of the highly stereoselective total synthesis of (-)-stenine (1). Alkaloids of this type of interest because of their possible applications in neuropharmacology.
Nathalie Solladié, Dr. Jean-Claude Chambron, Dr. Christiane O. Dietrich-Buchecker and Dr. Jean-Pierre Sauvage
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199609061
A copper(I)-templated synthesis furnishes rotaxanes, in which porphyrin subunits serve as bridges and bulky stoppers and the threaded rings contain chelating phenanthroline groups. A [5]rotaxane is shown schematically on the right, ○ = CuI, thick lines = phenanthroline units, ⋄ = porphyrins.
Dipl.-Biochem. Britta Qualmann, Dipl.-Biochem. Michael Manfred Kessels, Hans-Jürgen Musiol, Dr. Walter Daniel Sierralta, Prof. Dr. Peter Wilhelm Jungblut and Prof. Dr. Luis Moroder
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199609091
A novel approach from dendrimer chemistry for the synthesis of marker molecules containing eight carboranyl amino acids (MeCBA) (see structure on the right) overcomes the known inconveniences in the syntheses of linear peptide constructs. Marker molecules of this type should be able to be used in electron microscopy. R = protected peptide terminus.
Bernd Speiser
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199609131
Dirk Wilmer
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199609141
Klaus Peseke
Version of Record online: 22 DEC 2003 | DOI: 10.1002/anie.199609151


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I promise I haven't lost my mind.
Before Katy died I didn't know what to believe… now I HAVE to believe that I will someday be reunited with my daughter. It's the only thing that gets me through these long days.
Going through life with a piece of your heart missing HURTS. So you search for any little thing to make the pain hurt a little less. For me I NEED to know that Katy is OK that Katy is free from any pain, that she is not severely dehydrated ( her last words ever spoken to me…) Yes, my 6 year old told me she was severely dehydrated when I asked her if she was thirsty. She went into cardiac arrest 3 minutes later. I beg for signs… I pray… I scream… I make deals to whom, I don't know.
But, sometimes my prayers are answered
Since Katy's death I have opened my mind and my heart to see more of the signs around me I often refer to these as God Winks. They can be hearts found in strange places, the song Happy at just the right time, or something small that reminds me of Katy and makes me stop and say thanks.
Then there are the Burning Bush Moments the moments that STOP me in my tracks bring me to my knees and are to obvious to ignore. Katy went to heaven almost 3 years ago and up until yesterday I have only had one other moment like this. ( Some of you may remember my blue jay story) Yesterday I was blessed with a Burning Bush moment and I needed it more than I realized.
I was busy working on KMMF race work. I had a lot of errands to run and although I usually feel gratified when working on Katy's foundation I was feeling a bit melancholy. I went to pick up a large photo of Katy and the woman commented on what a beautiful little girl she was and I just started crying in the middle of the store… I went to pick up a sponsorship of someone that had the honor of meeting Katy and had a story to share and again the tears just fell from my eyes. It was while talking to this woman she reminded me that Katy is always near and I just need to ask God for a sign to let me know all is well. I left there thinking about Katy and how I yearned for a Burning Bush moment.
On my way to work last night I spoke to God and Katy I begged for a sign… I told them how tired I was, how worried about Mike I was. How I needed to know that Katy was OK and that I was doing what I am supposed to be doing. That this is for something and to keep going. I said that I was really tired so I needed it to be VERY obvious. I needed more than a God Wink.
When I got to work the second customer that came in was wearing this shirt… and I nearly hit the ground.
If that is not a Burning Bush I don't know what is.


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The aim of my artistic work is to represent my perception of a particular subject.
Colors can be an important element, but not only. I like using colors for the most part unconventionally and to dissolve contours deliberately. To capture black and white on canvas, I love that as well.
Painting is not a battle for me, but rather leaving one's everday life behind; at the same time it is a carefree release of ideas out of my mind.
Nater Art Naters
Nater Stephan
Landstrasse 64
CH-3904 Naters


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Every morning at 6:36,7:36, 8:36 Becca updates us on what's trending in country music.
RaeLynn talks about her favorite apps AND Tim & Faith showing off their private island.
Brantley Gilbert is a bus body AND Sam Hunt still working on sophomore album.
Remake of "A Star is Born" AND Brad Paisley gets a visit from David Hasselhoff.


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Lampung province is located between 3o 45' and 6o 45' South Latitude and between 103o 40' and 105o 50' East Longitude. This province is bordered by:
North side : South Sumatra Province
South Side : Sunda Strait
West side : Bengkulu Province
East side : Java Sea
Wide Area
The wide area of Lampung province is 33,307 sq km.
Lampung Province is divided among 4 regencies, 1 municipality and 1 administrative town with Bandar Lampung as its capital city.
The humidity of this province is various between 50% and 86%, and the rainfall is ranges between 2,000 and 4,000 mm per year. The temperature ranges between 20o C and 34o C.
The migration flow to Lampung province is supported by the existence of heavy plantation, fishery and industry. In 1994, the total population of this province was 6,200,306 people, with its average density of 196.8 people per Km2. Compared to the average national population growth amounted to 2.144% per year, this province was on the lower level with 2.12% per year during the 1990-1994 period. The projection and composition in 1997 can be seen on the following table.
Lampung society consists of two main groups, respectively has special traditional law. They are Peminggir traditional society and Pepadun traditional society. Peminggir societies, such as, Krui, Ranau, Komering, and Kayu Agung society, live along the coast And, Pepadun society, who customarily conservative, such as, Abung (Abung Siwo Migo), Pubian (Pubian Telu Suku), Tulang Bawang (Migo Pak), Buai Lima (Way Kanan), and Sungkay Bunga Mayang, live in the inland.


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Biography of Andrew F. Downing (1827- )
History of Lincoln County, Missouri (Chicago: Goodspeed Publishing Co., 1888) page 528.
Andrew F. DOWNING, an extensive farmer and stock raiser, and a native of Lincoln County, is a son of James and Martha (CACY) DOWNING, and was born July 9, 1827. He received such education as could be obtained in the primitive schools of his day, and in 1848 was married to Nancy TUCKER, who died in 1857, leaving four children. Six years later Mr. DOWNING wedded Emma A. GUTHRIE, who was born in Missouri, July 5, 1838. They also have four children. Mr. Downing and wife are members of the Cumberland Presbyterian Church, and in politics he was formerly a Whig, and later a Democrat, but for some years past has taken but little interest in politics. He was Master of the Masonic Lodge at Auburn for twelve years. He has a farm of 655 acres, and has a fine herd of short horned cattle, and is a prosperous and thrifty farmer. Mr. DOWNING's father was a hatter by trade, a Whig in politics, and he and wife were members of the Methodist Church. They both died in Missouri.
File submitted to HERITAGE PAGES of LINCOLN COUNTY, MISSOURI by Neal Underwood, 28 Oct. 2000. Link change or
update: 19 November 2000
NOTICE: In keeping with our policy of providing free genealogical information on the Internet, data may be freely used for personal research and by non-commercial entities, as long as this message remains on all copied material. These electronic pages may NOT be reproduced in any format for profit or presentation by other organization or persons. Persons or organizations desiring to use this material for profit or any form of presentation, must obtain the written consent of the file submitter, or their legal representative, and contact the listed county coordinator with proof of this consent.
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