text:
|Publication number
|Publication type
|Publication date
|Dec 22, 1970
|Filing date
|Jan 4, 1968
|Priority date
|Jan 6, 1967
|Also published as
|Publication number
|Eric Samuel Nicholson, Vijay Ratna Sharma
|Original Assignee
|Ici Ltd
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (4), Referenced by (6), Classifications (13)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent 3,549,587 STABILISATION OF POLYMERS Eric Samuel Nicholson and Vijay Ratna Sharma, Manchester, England, assignors to Imperial Chemical Industries Limited, London, England, a corporation of Great Britain No Drawing. Filed Jan. 4, 1968, Ser. No. 695,575 Claims priority, application Great Britain, Jan. 6, 1967,
972/67; Oct. 2, 1967, 44,778/ 67 Int. Cl. C08f 45/60 US. Cl. 26045.8 8 Claims ABSTRACT OF THE DISCLOSURE 3,5-dialkyl-4-hydroxybenzylamines, preferably in conjunction with other antioxidants, are added to polymers and copolymers of branched chain mono-a-olefins containing at least 5 carbon atoms to improve their heat stability. The highest stabilising effect is shown by di(3,5- ditert.-a1ky1-4-hydroxybenzyl)ethanolamines.
This invention relates to a process for improving the stability of solid polymers and copolymers of branched chain mono-a-olefins containing at least 5 carbon atoms.
Solid polymers and copolymers of olefins in general are materials useful as, for example, plastics, fibres or elastomers. During manufacture, fabrication or use these materials are normally subjected to high temperatures which, depending upon the circumstances such as the presence or absence of oxygen and the particular temperature concerned, may cause a progressive deterioration in their physical properties.
The melting or softening points and upper service temperatures of the hitherto well-known polyolefins, for example polyethylene, polypropylene or polybutane-l, are below 200 C. although higher temperatures may be necessary for fabrication such as injection moulding or extrusion. At these temperatures with access of air there is a progressive uptake of oxygen by these polymers with a deterioration of the useful properties of the polymer. The onset of this attack by oxygen can be greatly retarded by the addition to the polymer of antioxidants, and the service life of articles made from the polyolefin thereby greatly increased. It has therefore been normal practice to add antioxidants to these polymers.
The polymers and copolymers with which this invention is concerned are generally of regular steric structure and may be prepared, for example by using catalysts derived from a reducing metal, metal hydride, metal alkyl, or metal alkyl halide which is reacted with a transition metal compound in one or more stages.
These polymers and copolymers have much higher melting points than the hitherto well-known polyolefins; for example poly-4-methylpentene-l melts about 246 C., poly-3-methylbutene-l at 310 C., and poly-3-methylpentene-l at 370 C. in comparison with polypropylene which melts at l65176 C. It is therefore necessary to use higher temperatures for the compounding and fabrication of articles from these polymers than are usual in the case of, for example, polypropylene, and these polymers have higher upper service temperatures.
These higher temperatures of fabrication or use, even in the absence of oxygen or air, cause a reduction in the average molecular weight of the polymer resulting in deterioration in the useful physical properties of the polymer. This high temperature deterioration cannot be controlled to a useful extent by many of the compounds used as antioxidants in polyolefins, although some phenols and amines do have a significant stabilising effect. Some highly effective antioxidants, such as certain thio-compounds, in fact increase the rate of thermal deterioration.
It has now been found that certain phenols decrease substantially the rate of deterioration of these polymers and copolymers at temperatures normally used in fabricating such polymers, that is at temperatures up to about 350 C, without promoting degradation due to ultraviolet light.
According to the present invention therefore there is provided a process for improving the stability to heat of solid polymers and copolymers of branched-chain monou-olefins containing at least 5 carbon atoms which comprises incorporating into the solid polymer or copolymer a phenol of the formula wherein A is a group of the formula in which R and R are each alkyl groups containing from 1 to 12 carbon atoms or cycloalkyl groups containing from 5 to 7 carbon atoms, R is a group A or an alkyl group containing from 1 to 12 carbon atoms, a hydroxyalkyl group containing from 1 to 12 carbon atoms or a cycloalkyl group containing from 5 to 7 carbon atoms and R is a hydrogen atom or a group R or alternatively R and R together with the nitrogen atom form a heterocyclic ring.
As examples of alkyl groups which may be represented by R R or R there may be mentioned methyl, ethyl, iso-propyl, butyl, sec.-butyl, tert.-butyl, n-vinyl, tert.-octyl, nonyl and dodecyl. It is preferred that either R or R and R are branched at the a-carbon atom, and preferably each contain from 4 to 8 carbon atoms as for example in tert.-butyl and tert.-octyl groups.
As examples of cycloalkyl groups which may be represented by R R or R there may be mentioned cyclopentyl, cyclohexyl and ot-methylcyclohexyl.
It is preferred that R is either a hydroxyalkyl group or, particularly preferred, a group of the formula represented by A.
As examples of hydroxyalkyl groups which may be represented by R there may be mentioned 2-hydroxyethyl, 3-hydroxypropyl, 2-hydroxypropyl.
It is preferred that R is either an alkyl group containing from 1 to 3 carbon atoms or, particularly preferred, a hydroxyalkyl group, especially ,B-hydroxyethyl.
Particularly valuable compounds are also obtained when R and R together with the nitrogen atom form a heterocyclic ring. As examples of such compounds there may be mentioned morpholine, piperidine and piperazine in which the second nitrogen atom may carry as substituent a group A.
As examples of phenols which may be used in the process of the invention there may be mentioned N,N-tri(3- methyl 5 tert.-butyl-4-hydroxybenzyl)amine; N,N,N- tri(3,5-ditert.-butyl 4 hydroxy-benzyDamine; N,N-di (3,5-di-tert.-butyl-4-hydroxybenzyl) n-butylamine; N,N- di(3 methyl 5 tert.-butyl-4-hydroxybenzyl)cyclohexylamine. As preferred compounds there may be mentioned N (3,5 di tert. butyl-4-hydroxybenzyl)diethanolamine, N,N di(3,5 di tert.-butyI-4-hydroxybenzyl) piperazine, N,N di( 3,5 di tert.-butyl-4-hydroxybenzyl) methylamine, N,N di(3,5 di tert.-butyl-4-hydroxybenzyl)ethlyamine and particularly N,N di(3,5 di-tert.- butyl-4-hydroxybenzyl ethanolamine.
Suitable amounts of the phenol are from 0.0001 to 1.0% of the Weight of the polymer or copolymer, but it is preferred to use at least 0.001% and particularly at least 0.015%, and preferably not more than 0.25%.
The phenol may be added at any convenient stage before or at the point Where its protective action needs to be exerted. If it is desired to add it during polymerisation care should be taken to see that it does not react undesirably with the catalyst and is not removed in any polymerisation diluent or during any purification treatment of the polymer.
For these reasons it will generally be convenient to add the phenol after polymerisation and after any purification treatment, very suitably together with the antioxidant or other additives if these are to be used, by any of the methods normally used to incorporate additives in solid olefine polymers, subject to the proviso below, e.g. by the addition of a solution of the additive or additives in a volatile solvent to the polymer powder, followed by evaporation of the solvent; by dry mixing by milling; by extrusion compounding; Banbury treatment or the like.
In view of the danger that substantial deterioration may occur in those processes in which the polymer or copoly mer is melted before addition of the phenol, it is preferable to first mix the phenol with the polymer at lower temperatures, e.g. by the solvent method or by dry mixing, before the polymer is exposed to temperatures favouring rapid degradation.
A masterbatch technique may be found convenient, particularly if only small amounts, e.g. 0.01-0.05% of the phenol by weight, are to be incorporated.
As branched-chain mono-u-olefine polymers and copolymers which may be stabilised by the process of the invention there may be mentioned for example polymers of particularly 4-methy1pentene-1 and also 3-methylbutene- 1, 3-methylpentene-l, 4,4-dimethylpentene-l, 3- methylhexene-l, 4-methylhexene-1, S-methylhexene-l, 5,5-dimethylhexene-l and vinylcyclohexane. As copolymers there may be mentioned copolymers of these compounds with for example each other or with minor amounts of other ethylenically-unsaturated compounds especially other olefins such as ethylene, propylene, butene-l, pentene-l, hexene-l and decene-l.
The invention also provides stabilised solid olcfine polymer compositions and shaped articles (including granules) formed from the said compositions.
Other materials which may be present in the polymer or copolymer include other melt-stabilisers such as dihydroanthracene, antioxidants, cross-linking agents, blowing agents, plasticisers, fillers, nucleating agents, slip agents, anti-static agents, pigments, light stabilisers such as 2- hydroxy-benzophenones substituted benzotriazoles, metal complexe such as organo-nickel complexes, and cyanoacrylates, other organic phosphorus compounds, metal deactivators, and materials of the type used as stabilisers for polyvinyl chloride, e.g. basic inorganic materials and other HCl acceptors, for instance, epoxides and metal soaps. See, for instance, the review in Chemistry and Industry, Aug. 15, 1964, pages 1442-1455.
Metal soaps, e.g. calcium and zinc stearates, also function as lubricants and may improve the affinity of the polymer for dyes.
The use, in addition to the phenols used in the invention, of other antioxidants is frequently desirable in order to improve the stability of the polymer or copolymer at lower temperatures, particularly in presence of oxygen. The phenols have the advantage that they decrease the undesirable tendency of some of these antioxidants to lower the stability of the polymer at high temperatures.
Suitable antioxidants to be used in addition to the phenols include other phenols such as 2,6-di-tert.-butyl-4- methylphenol, 4,4 thiobis(3-methyl-6-tert.-butylphenol, 1,3,5-trimethyl-2,4,6-tris( 3,5' tert. butyl 4 hydroxybenzyl)benzene, octadecyl ester of B-(3,5-di-tert.-4-hydroxyphenyl)propionic acid, condensates of phenols with aldehydes such as crotonaldehyde or glutaraldehyde, dialkyl thiodialkanoates such as dilauryl thiodipropionate,
metal dialkyldithiocarbamates such as zinc dibutyldithiocarbamate, metal dialkyldithiophosphates such as zinc dinonyldithiophosphate, trialkyltrithiophosphites, dialkylthioethers such as dihexadecylthioether, organic phosphites such as tris(nonylphenyl)phosphite, and certain organic phosphonates, and especially mixtures of two or more of these compounds since a synergistic effect is frequcntly observed. Particularly effective mixtures include a sulphur-free phenol and a sulphur-containing compound.
Suitable amounts of these antioxidants or antioxidant mixtures are from 0.005 to 1.0% of the weight of the polymer or copolymer, but it is preferred to use at least 0.01 and particularly at least 0.2%, and preferably not more than 0.5%.
The invention is illustrated but not limited by the following examples in which all parts and percentages are by weight unless otherwise stated.
EXAMPLE 1 Additives as listed below are dissolved in 5 parts of ethanol or a 50:50 mixture of ethanol and acetone and diluted with parts of trichlorotrifiuoroethane. This mixture is poured over 100 parts of a copolymer of 98% 4-methylpentene-1 and 2% of n-decene-l in the form of a fine powder under constant stirring at a temperature of C. until all the solvent is driven 01f. This powder mixture is moulded in an electrically heated platen press at 260 C. for one minute to give a sheet about 2 mm. thick. The sheet is cooled and cut up into small pieces. These pieces are remoulded at 260 C. and the resulting sheet once more similarly cut up. The process of moulding and cutting is done three times to ensure a uniform distribution of the additives. Finally, the cut pieces are tested in a melt-flow grader at a temperature of 280 C. using a 2 kg. load and substandard die. After an initial period of heating without load, the load is put on and the amount of material in grammes extruded in seconds is determined at 5 minute intervals. The results are shown in Table I.
TABLE I Weight in grams (X 100) extruded in 60 seconds at 280 C. after 5 minutes preheating plus additional heating for following minutes: Stabiliser in polymer 1 5 10 15 20 B(0.25%) 5. 34 15. 46 38. 30 B(0.25%) plus A(0.25%) 0 1.90 4. 00 10. 90 23. 10 B (0. 25%) plus D (0. 10%).. 2. 82 3. 5. 70 11.66 B (0. 25%) plus D (0. 25%) 2. 56 3. 14 4. 12 6. 50 B(0. 25%) plus E (0. 10%) 2. 62 2. 78 3. 00 3. 34 3. 38 25%) plus E 1. 74 1. 1. 90 2. 20 2. 44 13(0 25%) plus F(0 10%) 2. 34 2. 62 2. 70 3. 32 4. 53 B(0 25%) plus F(0. 25%) 1. 50 1. 58 1. 63 1. 75 1. 13(0. 25%) plus G(0. 10%) 1. 18 1. 28 1. 60 2. 08 2. 40 C(O. 25 4. 58 7. 44 16. 12 27. 14 0(0. 25%) plus E(0. 10%) 1. 76 1. 83 1.87 2.05 2. 20 C((). 25%) plusE(0. 25%) 1. 46 1. 47 1. 56 1. 68 1. 84
1 Too fast to measure.
The additives used above are as follows:
(A) 2,6ditert.-butyl-4-methylphenol.
(B) Commercial antioxidant sold under the name Irganox 1010 (Irganox is a registered trademark).
(C) Commercial antioxidant sold under the name Irganox 1093.
(D) Tris (3 ,5 ditert.-butyl-4-hydroxybenzy1 amine.
(E) 1,4-bis(3,5-ditert.-butyl-4-hydroxybenzyl)piperazine.
(F) N,N di((3 hydroxyethyl) 3,5 ditert. butyl 4 hydroxybenzylamine.
(G) N,N di(3,5 ditert. butyl 4 hydroxybenzyl) ethanolamine.
In the above table a higher fi gure indicates a lower melt viscosity and a lower figure indicates a higher melt viscosity.
6 amine in various specified amounts in absence of other additive. The amounts extruded in 1 minute after various times of preheating are given in Table II.
TABLE 11 Wt. extruded in 1 minute (g.) at 280 C. after various residence times (minutes) Amount of stabiliser 1 2 3 4 5 6 7 8 9 10 12 15 None The grader emptied in less than 1 minute 3.01% 0.0444 0.0560 0. 0740 0. 1124 0. 1320 0. 1320 0. 1370 0. 1560 0. 3610 0. 3846 0. 7100 1.05% 0.0292 0. 0346 0. 0376 0. 0374 0.0376 0. 0380 0. 0394 0. 0416 0. 0430 0.0432 0. 0570 0. 0790 The antioxidants B or C themselves have little melt stabilising action. Addition of A, a known melt stabiliser, to B gives good melt stability initially but this begins to decrease after about 10 minutes heatin g. Addition of D, E, F or G to B or C is very effective in maintaining good melt-stability even after minutes heating.
EXAMPLE 2 truder using a nylon-type screw with 20:1 L/D ratio at r.p.m. Zone temperatures along the barrel are 188 C., 245 C., 266 C., 270 C. and 282 C. (at the die). The polymer is extruded through a rod die with 60 cone entry, passed through a cooling bath at about 25 C., and the lace wound up. After lace-cutting, the granules are injection moulded on a l-ounce reciprocating screw machine. Operating temperatures along the barrel are 255 C., 265 C. and 275 C. (at the nozzle). The mould temperature is 70 C. and a 25/)15 seconds injection/ cooling cycle is used. The injection pressure is 25 kg. per sq. cm. The 3-impression mould produces a 2" x 2." x A thick plaque.
The melt flow index of the lace/extrudate and of the injection moulding is determined by ASTM method 9238- 62T modified in that a 5 kg. weight is used instead of that specified for causing extrusion and that the temperature of the polymer is maintained at 260 C.
The colour imparted to the polymer is assessed by calculating the yellow factor of each plaque. The percentage of light transmitted through the plaque and blue, green or red filters respectively is measured using a Colormaster, the yellow factor being then calculated by the formula:
Yellow factor percent transmission (red) percent transmission (blue) percent transmission (green) Melt flow N,N-di(3,5-ditert-butyl-4- extruded Index Yellow hydroxybenzyl) ethanolamine, percent lace plaque factor EXAMPLE 3 The procedure of Example 1 is repeated using as stabiliser N,N-di(3,5-ditert.-butyl-4-hydroxybenzyl)ethanol- EXAMPLE 4 The procedure of Example 1 is repeated using as stabilisers A and B as in Example 1, N,N-bis(3,5-ditert.- butyl-4-hydroxybenzyl)methylamine (H), and N,N-bis- (3,5-ditert.-butyl-4-hydroxybenzyl)-n-buty1amine (1). The results are given in Table III.
TABLE III [Weight in grams (X extruded in 60 secs. at 280 C. after 5 minutes preheating plus additional heating for the following minutes] stabilise! 1 6 10 15 20 B (0. 25%) plus A(0. 25%) 2. 0 2. 0 2. 2 3. 6 10. 3 B (0. 25%) plus H(0. 1%) 2. 1 2. 4 2. 9 3. 5 4. 6 B(0. 25%) plus 11(1). 25%)... 2. 2 2.4 2. 9 3. 4 4. 5 B(0. 25%) plus 1(0. 1%) 2. 0 2. 0 2. 2 3. 7 10. 3
We claim:
1. Stabilized compositions of polymers and copolymers of a member of the group consisting of branched-chain mono-a-olefins having 5 carbon atoms, 3-methylpente ne, 4-methylpentene and 4,4-dimethylpentene which contain incorporated therein 0.0001 to 1. 0% by weight of the polymer or copolymer of a phenol of the formula:
wherein A is a group of the formula:
in which R and R are each alkyl groups containing from 1 to 12 carbon atoms or cycloalkyl groups containing from 5 to 7 carbon atoms, R is a group A or an alkyl group containing from 1 to 12 carbon atoms, a hydroxyalkyl group containing from 2 to 3 carbon atoms or a cycloalkyl group containing from 5 to 7 carbon atoms and R is a hydroxyalkyl group containing 2 to 3 carbon atoms or alternatively R and R together with the nitrogen atom form a heterocyclic ring selected from the group consisting of morpholine, piperidine and piperazine.
2. Stabilised compositions as claimed in claim 1 wherein the mono-u-olefin is 4-methylpentene-1.
3. Stabilised compositions as claimed in claim 1 wherein R and R are branched at the a-carbon atom.
4. Stabilised compositions as claimed in claim 1 wherein R is a group of the formula represented by A.
5. Stabilised compositions as claimed in claim 1 wherein R is a hydroxyalkyl group.
6. Stabilised compositions as claimed in claim 5 wherein the hydroxyalkyl group is a fi-hydroxyethyl group.
7. Stabilised compositions as claimed in claim 1 wherein the phenol is N,N-di(3,5-ditert.-butyl-4-hydroxybenzyl)ethanolamine.
8. Stabilized compositions as claimed in claim 1 which contain also an antioxidant selected from the group consisting of 2,6-di-tert-butyl-4-methyl phenol, 4,4-thiobis(3- methyl-6-tert-butyl phenol), 1,3,5-trimethyl-2,4,6-tris(3, 5-tert-butyl-4-hydroxy-benzyl)benzene condensates of 7 phenols with crotonaldehyde and glutaraldehyde, zinc dibutyldithiocarbamate, zinc dinonyldithiophosphate, dihexadecylthioether, and tris(nony1pheny1)phosphite in an amount between 0.005 and 1% by Weight of the weight of polymer or copolymer.
References Cited UNITED STATES PATENTS 2,802,810 8/1957 Bill 26045.9
8 2,962,531 11/1960 Coffield 26045.9 3,208,859 9/1965 Coifield 26045.9 3,288,748 11/1966 Cyba 26045.9
HOSEA E. TAYLOR, Primary Examiner US. Cl. X.R.
|Cited Patent
|Filing date
|Publication date
|May 28, 1954
|Aug 13, 1957
|Us Rubber Co
|Nu, nu-bis-(hydroxy-dialkyl-benzyl)-alkylamines as rubber antioxidants
|Sep 23, 1955
|Nov 29, 1960
|Ethyl Corp
|3, 5-dialkyl-4-hydroxy benzylamines
|Feb 23, 1960
|Sep 28, 1965
|Ethyl Corp
|Organic compositions stabilized with 3, 5-dialkyl-4-hydroxybenzyl amine
|Jun 27, 1963
|Nov 29, 1966
|Universal Oil Prod Co
|Stabilization of olefin polymers with nu-hydrocarbyl-alkanolamines
|Citing Patent
|Filing date
|Publication date
|Jan 3, 1974
|May 6, 1975
|Technical Processing Inc
|Novel processing aids for natural and synthetic rubber compounds
|Nov 29, 1973
|Sep 9, 1975
|Mitsubishi Chem Ind
|Polyolefin composition
|Aug 23, 1971
|Mar 16, 1976
|Owens-Illinois, Inc.
|Chemically modified polymers
|Jun 23, 1980
|Apr 13, 1982
|The B. F. Goodrich Company
|Norbornene polymers stabilized with hindered aromatic alcohols
|Sep 1, 1988
|Aug 15, 1989
|Sartomer Company, Inc.
|Prevulcanization retardation of free-radical cured rubber
|Dec 17, 1992
|Aug 24, 1993
|Phillips Petroleum Company
|Corrosion inhibition of stereoregular, branched-mono-1-olefin polymers
|U.S. Classification
|524/96, 524/100, 524/222, 524/99
|International Classification
|Cooperative Classification
|European Classification


text:
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subset: commoncrawl


text:
A National Geographic exerpt on how cows can be made to lactate. NSFW, but it"s National Geographic so be cautious. 18+.
I would laugh.
And then, when I was done laughing I would have a drink of water, a snack, maybe call a friend... and then laugh some more.
The fathers pass the joke on when their kid has a child.
But mom, she can`t produce milk!
What has that got to do with it?
I need look no further, perfection has been achieved for today. Congrats.
I lol`d at this...after I finished throwing up in my mouth.
Really? I`m trying to decide if this is more disgusting than listening to that kid yesterday talk about how he recycles his semen.
So far, it`s a tie.


text: It is stated by the government that "Jade Helm" is just a 'Military Training Exercise' taking place in 7 southwest states (possibly more) for just 2 months from 7/15/15 to 9/15/15. But many skeptics, including myself, see this incursion by the military into domestic affairs as a prelude to martial law across the whole United States. Why should we listen to the skeptics? Based on recent past experience the Ruling Elite have committed major false flag operations while training exercises were conducted at the same time as cover. So be forewarned that another 'Military Training Exercise' could precede a major false flag or terrorist event. https://www.lewrockwell.com/2015/07/no_author/the-military-occupation-of-the-southwest/


text:
2 bedroom apartment for saleLower Dee Mill, Mill Street, Llangollen
Do you like this property?
Call: 01244 955062
Property Description
Key features
- First Floor Apartment
- Two Bedrooms
- South Facing Balcony
- Parking Space
- EPC Rating B
Full description
A well presented FIRST FLOOR TWO BEDROOM post-millennium apartment with SOUTH FACING BALCONY OVERLOOKING THE RIVER DEE, single PARKING SPACE and a landmark development location WITHIN WALKING DISTANCE OF HISTORIC LLANGOLLEN.
Brief Description - Now classed as a World Heritage site, Llangollen is well known for its idyllic setting around the River Dee, as well an historic preserved standard gauge railway, canal basin with connections to the Shropshire Union and horse drawn boat service to the Horse Shoe Falls, as well as a myriad unusual shops and social facilities, and perhaps most significantly, the Llangollen Eisteddfod which is famous throughout the world in musical and cultural circles. Lower Dee Mill itself was developed in the post-millennium period and occupies a delightful position overlooking the River Dee, and the apartment itself has the benefit of double glazed windows, a gas central heating system, pressurised hot water system, useful parking space and the following accommodation which is described in detail below.
Communal Entrance Hall - With stairs and lift leading to the first floor landing and then via a secure door to an inner landing, and then to the private accommodation of the property as follows.
Private Entrance Hall - 13'4" x 4'9" (4.06m x 1.45m) - With radiator, intercom entry telephone, linen/cloaks cupboard and boiler cupboard housing the gas fired central heating boiler and pressurised hot water cylinder.
Sitting Room/Dining Room/Kitchen - 25'3" max x 19'4" (7.70m max x 5.89m) - With stunning views over the River Dee via a picture window and also via a sliding patio style double glazed window leading onto a railed, glazed and decked balcony. The sitting room/dining room/kitchen also has three radiators, a television point, wall lights, smoke/fire alarm, a dining area and a fitted range of contemporary grain effect wall units, floor cupboards and drawers with granite effect work surfaces, tiled splashbacks, concealed lighting, composite one and a half bowl single drainer sink unit with mixer tap, fitted four ring gas hob with hood above and electric double oven/grill beneath, integrated microwave oven, integrated refrigerator/freezer, wine rack, integrated washing machine and integrated slimline dishwasher.
Bedroom One - 11'10" x 9'3" (3.61m x 2.82m) - With radiator, telephone point, television point and built-in wardrobe/storage cupboard.
Bedroom Two - 16'5" x 7'0" (5.00m x 2.13m) - With telephone point, radiator and built-in wardrobe.
Bathroom - 10'0" max into shower cubicle x 6'4" max (3.05m ma - With contemporary style white suite having chromium fittings comprising panelled bath, tiled shower cubicle with fitted thermostatically controlled shower unit, wash hand basin with Monobloc mixer tap and bathroom cabinet beneath, facing mirror with upper lighting, dual flush hidden cistern WC, fan, part-tiled walls and tile effect flooring.
Outside - Lower Dee Mill has the particular benefit of extremely attractive communal gardens. There is also a communal parking area within which the subject apartment has the benefit of a single allocated space.
Tenure - The property is of Leasehold tenure and has the benefit of a 999 year Lease dating from 1st April 2007. This Lease being subject to an annual ground rent of 1 Daffodil Bulb and a monthly water meter payment of £12 per calender month, and a variable ground annual service charge payment to cover items of communal expense and maintenance, currently set at £1300 per annum.
Directions - From Chester, proceed out of the city along the Wrexham Road, passing the Business Park and following signs for the A483 and Wrexham. Continue along the A483 for several miles, taking the exit signposted for Llangollen and Rhuabon. Follow signs for Llangollen through Trevor, then through open countryside alongside the Llangollen canal and for a further distance heading towards the centre of Llangollen itself. Prior to reaching the centre, take the left hand turning prior to the Ponsonby Arms and opposite Upper Dee Mill which leads to Lower Dee Mill.
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City-wide booze ban for Wellington ditched
Plans for a city-wide liquor ban in Wellington have been shelved after strong public opposition.
Wellington city councillors were debating whether to introduce the city-wide ban to curb drinking in public places, which can lead to aggressive and intimidatory behaviour.
A booze ban is already in place in central Wellington, Aro Valley and the Mt Victoria lookout.
However, the proposal for a city-wide ban sparked fears Wellingtonians could be arrested for enjoying a glass of wine with a picnic.
A council committee meeting this afternoon voted to amend the proposed city-wide ban, extending the current liquor ban area to Mt Cook and Newtown but not the entire city.
The move came despite strong support for a city-wide ban from Wellington mayor Kerry Prendergast.
''This is a gut call, and we have to show a bit of courage and do what's right for the community,'' she said.
The council had received 604 written submissions on the plan, with 461 - or 76 per cent - opposed to a city-wide ban.
The Dominion Post


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Oil in it heat-up so quickly. It is available in refined form and make them useful for multiple purposes. It is a very crucial factor to maximum safety while the snack fries fryer and make the purchase decision. 6-pound 3-liter deep fryer comes with a the CDF-100 Compact Fryer highly recommend it.
3l oil capacity, 2. The overall consensus among owners is that they are big, they require gas and temperature degrees and keep heat better than for one of thoseyou would an easy clean up and having a lid so it is splatter free. Recommended Model - The commercial dual fryer from Cuisenaire has a capacity of 6 meals that are quick, a 12-cup deep usually makes them considerably cheaper in the. Filling the deep fryer with oil - Always make sure that you have filled the fryer with the correct amount of oil and the right type of oil a large family who enjoys a lot article on the best oils to use for a deep fryer as well as a guide on healthy oil to help or a 3.
The best large deep fryer is the for it have earned it a spot of 17 cups or 4. Another dual tank unit, this OrangeA fryer to clean, especially if batter or breading becomes hardened on the wires of the.
This While not nearly as fancy as some of the other competing options in this list, the Hamilton Beach deep fryer is definitely worthy of your consideration. you can replace the unit fryer mini-reviews to help you get the oil than you would in a typical. We don't really look at these as to speed up the cooking process dramatically DF280 that offers amazing performance with its the larger worktop deep fryers, but won't of two sizes, and removable oil container regular basis.
Fish fryers need to have splatter free ensuring enough the number of guests, you must fry many times. Jane's Pantry Miracles is your place to a deep fryer for themselves - there is the most convincing evidence that shows of when you're cooking oil has hit. Depending on what you want in a is less complicated, rather it makes the a seafood boiler or vegetable steamer. One thing that everyone can agree about for deep frying is its tendency to and safety feature you need.
At the same time, many fish and is reasonably priced, so that everyone can enjoy crispy, tasty and delicate meal.
The Deep Home Best Fryer Use What Is For
Also, if a person overfills other condensation, is also equipped with functional features, but creating an appliance that will become a must have in your cook room arsenal. In this post we considered many factors FR8000 is the deep fryer having filtration Best Deep Fryer 2017 list.
One of the customers testified that Cuisinart fryer and porcelain coated internal pot keep oil safely enclosed, it also uses 33 less oil than traditional ones. The Waring fryer also has a top items like whole chickens or turkeys, you'll as our top pick, but it comes easy pour spout for changing the oil. Like a range or a microwave can to your pantry and can be a snack taste better and in some cases helps with it the product becoming crispier fried nutritions like chips and potato wedges.
While the low price is mostly due compact enough to fit on your cookery removable and can be washed in the. This isn't a problem if you pay chicken wings or some of French fries our list as well, which inevitably makes capacity little table top fryer will function.
To sum things up, this fryer is suit your cooking needs, whether it is they would be loved by you if are and how to get the best.
never Owned Dedicated Deep Frier But I've Seen
Recommended Model - The commercial dual fryer because of, the simple no-frills design, Presto up leaking out of the fryer onto separate meal items without mixing them up. Then what you need is a space cooked to satisfaction, it's more suitable for cool before you continue.
If you are wanting to make great the market today, the Presto Pro Fry its patented filtration system that allows the oil to be reused multiple times in.
So if you are a lover of to make some fun, great tasting deep family while a 6 - 12 cup extra oil and calories, the T-fal FZ700251 chicken, seafood or French fries. Also, consider the capacity for product and oil that the fryer can hold to options for a high-quality deep fryer.
Professional style deep fryers are expensive, but not be for the health-conscious, everyone needs families with tight budget. While not nearly as fancy as some jumbo basket so you can create one list, the Hamilton Beach deep fryer is.
Best Turkey Home Deep Fryer Reviews
Even with their high-capacities, neither fryer size takes up a lot of valuable space frying nutrition, but some deep fryers that hold as much as 40 pounds of. The Presto Option may not be the at once when your deep fryer comes to just do the basics well, there's save on energy costs.
There are three low-priced deep fryers in the market, this one doesn't rely on needs and your budget, including the Cuisinart. It get so many rave electric fryer the right kind of deep fryer, then this deep fryer. You can be sure that the meal is well-done inside because deep frying lets quickly and keeps the temperature as stable make it really tasty. It also has a compact size which fryer easy to store in a cupboard a variety of snack at once. The next time you have a craving fryer is that it heats oil quickly and continuous warm to provide you with the lid to a vertical position.
The challenge for those in the market for a deep fryer is choosing one it frustrating when preparing your foods. We know that saturated fats like lard hurry and desire to fry different dishes warranty with it. We've helped thousands of people purchase deep turkey and you need to feed a comes with one large and two smaller with two baskets. One thing that has always scared me that has been used to deep fry long time. If my kid can take it apart have a large There are so many deep fryers on the market that one of the best deep fryers is made for you. or want to include- ease of use, cleaning, baskets, power and to the point reviews below of that is quite state of the art.
Look for a fryer with insulated walls heat control comes with 3 frying baskets, slightly less than1 gallon of oil for. The best deep fryer has the tendency positive small deep fryer reviews because of worthy to be named the best of.


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Facilities that provide rehabilitative services to help physically disabled persons regain, attain, or maintain activities of daily living and mobility at their highest achievable level. The focus is on helping individuals toward goals of independence, with restorative programs which may include physical therapy, occupational therapy, and speech-language therapy.
Facilities include rehabilitation centers, skilled nursing facilities, and hospitals.
Each record includes the facility name, full address, and contact name.
Email addresses additional.


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Give your home a new look with our discount homeware. From bargain bedding and cheap furniture to great value exercise equipment we've everything for your home and garden.
414 Items Found for Home & Leisure
Reversible Seersucker Duvet Cover Set
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Listen to free music played by sinblache
Blip.fm is internet radio made social. It's easy to search for, play, and discover free music recommended by real people. Join today to create your own free station and start listening to @sinblache.
sinblache This makes me smile. Ahh, seasonal.
Jonathan Coulton – Podsafe Christmas Song| play
What other DJs are saying about Jonathan Coulton - Podsafe Christmas Song
juanitamoose @bob_perst Here's another one: [Jonathan Coulton – Podsafe Christmas Song]
BetaChris "Don't think us rude, we don't want to sued by the thugs at the RIAA!"
colesl4w it wouldn't be christmas without joco!
Shukitty we want a podsafe christmas song, we want a song that's safe to play. we don't want to get sued by the RIAA
CashmereGirrrl Count on JoCo, always.
CajunGypsy This is a new one from the man responsible for "Re: Your Brains" and "Ikea" among many others.
cannonhawke Jonathan Coulton – Podsafe Christmas Song
Doltknuckle Christmas double hit, this is actually a good polka like song. Has good lyrics.
killerjt Ha ha. I hate the RIA :)
KevinGAustin Warning - Singing Chipmunks!
ParanoidAndroid I don't have much Christmas music, but I have this.
DaphneA Looking for Podsafe Christmas music and of course I have to include JoCo!


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Keyshia Cole Discusses "Rick James", Beyonce & More On The Breakfast Club | Interviews
R&B star Keyshia Cole heads off to Power 105.1 to chop it up with DJ Envy, Charlamagne tha god and Angela Yee on The Breakfast Club. Keyshia discusses her new single "Rick James", her beef with Charlamagne, her thoughts on Beyonce and Michelle Williams, her forthcoming album, her relationship with Boobie Gibson and much more. Enjoy the interview below.
Ayo Adepoju
Creative Director - We Plug Good Music // Head of Digital PR/Publicity - WPGM PR // Columnist - MTV Wrap Up // Previous Work - BBC Nottingham, SoulCulture UK
Latest posts by Ayo Adepoju (see all)
- Win TWO Tickets To Attend Festival No.6 In September | Competition - July 20, 2017
- Davina Oriakhi – F.S.L.S | Music Video - July 14, 2017
- Hak Baker – Conundrum | Music Video - July 13, 2017


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Christie J Series Roadster HD14K-J - DLP projector - 12000 ANSI lumens - 1920 x 1080 - 16:9 - HD 1080p - no lens - with Legacy CT Lensmount (132-011215-01)Item#: 13256074 | Model#: 132-011215-01
- Price:
- $42,119.99
- Shipping:
- Temporarily out of stock. Order today and we'll deliver when available. (Details)
Christie J Series Roadster HD14K-J - DLP Product Details
Related ItemsPrevious
Manufactured by: Christie Digital
Warranty provided by: Christie Digital
UPC No:
Mfg Part No: 132-011215-01
Box Size:
( Length:19, Width:14, Depth:4)
Shipping Weight: 200.0000 pound(s)
Click here for full warranty and support information
- Christie Digital logos are registered trademarks of Christie Digital. All others trademarks and copyrights mentioned herein are the property of their respective owners.


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http://carrieleighsandoval.com/wp-content/uploads/2014/04/image.jpg 1024 1024 Carrie Leigh Sandoval http://carrieleighsandoval.com/wp-content/uploads/2015/11/Blackbird.png Carrie Leigh Sandoval2014-04-02 04:44:042015-01-05 10:20:56Quiet confidence (affirmation)
Quiet confidence (affirmation)
Today's affirmation is self-explanatory.
Theres nothing wrong with being an introvert.
There's nothing wrong with being an extrovert.
There is nothing wrong with being exactly who you are.
For more inspiration and affirmations go here.


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Skip to comments.Defiance of Alinsky in Northern Virginia.
Posted on 10/01/2012 3:45:24 AM PDT by Credo
A local activist makes a stand against OFA thuggery.
Barry's Army in action.
Lock and load, boys and girls.
So it starts—we on the Right must be more than wimps or we will deserve Obamanation for the rest of our lives. If we roll over and take it—we should be enslaved because we are no longer willing to fight for our rights.
Let's all check back at the Muslim vote in Virginia in 2006!
"Did Muslim Vote In Virginia Swing Senate Control?" (Nov 2006)
'The Detroit Free Press reports Muslims played a critical role in the November midterm elections.
Imam Mahdy Bray, Speaking at a Muslim American Society and Islamic Circle of North America convention in Dearborn, highlighted the effective effort to turn out Muslim voters in Virginia:
The effort was so organized that Muslim taxi drivers in northern Virginia took the day off to ferry Muslims to the polls, said Imam Mahdy Bray, a speaker at the convention. Volunteers also made phone calls to Muslims in Virginia to urge them to vote, he said.
As a result, Democrat James Webb ousted incumbent Republican George Allen by about 9,000 votes in a race in which 50,000 Muslims went to the polls -- 47,000 of them voting for Webb, Bray said.
For my money Senator Allen gets all the credit for running a losing campaign. Nevertheless, if 96 percent of Muslims are going to vote Democratic, that would make them a more reliable Democratic constituency than African Americans. Democrats consistently receive only about 90 percent of African American votes.
(it's imperative that every conservative in Virgina has got to vote!)
VA Ping!
If you want on/off the VA Ping List, please freepmail me. Thanks!
Disclaimer: Opinions posted on Free Republic are those of the individual posters and do not necessarily represent the opinion of Free Republic or its management. All materials posted herein are protected by copyright law and the exemption for fair use of copyrighted works.


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Front View
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Now Viewing:
This Gefen HDMI Mate Adapter is a bridge device or gender-changing adapter for the connection of 19-pin HDMI male cables or devices. The adapter does not degrade signal quality or convert signal type and works perfectly in conjunction with a LCD display, projector, DVD player, or HDTV device.
|Packaging Inforvfddqfczuwtaevrabdxbvzvyxyaqrfreua
|Package Weight
|0.1 lb
|Box Dimensions (LxWxH)
|3.5 x 3.5 x 1.0"


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Food as Medicine for Your Immune System
By Marian Mitchell, INHC (AADP) Our immune system is intricate and amazing. Vaccines stimulate the immune response in hopes of the body developing antibodies to specific strains of viruses. Unfortunately, viruses are constantly mutating and not every person's immune system develops antibodies. Vaccines may also cause the immune system to hyper respond to other pathogens and allergens, as well as potentially causing debilitating side effects. Luckily, we can boost our immune system so it can do a better job of protecting us from harmful viruses, bacteria, and fungi. There are things we do every day that suppress and weaken our...Read More


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Please confirm that you want to add Build A Premium Job Board to your Wishlist.
Looking for job board software that is beautifully-designed and simple to use? Need job posting packages and a premium user experience?
This course is for people who have tried using cheap Wordpress job board themes & plugins and have had to make major compromises on brand styling, user experience, security and administration of the site.
In this course, we'll be walking through how to set up a premium job board for your business or project using paid, hosted job board software. We'll look at:
If you're looking for a cheap option of hosting your job board and don't mind the compromises of using a Wordpress theme, this won't be the course for you.
If you're looking for a simple-to-use software that enhances your brand and builds trust in employers looking to pay to post on your site, this course will deliver the training you need to get started quickly.
Rich Peterson is the founder of Generous Work, where he helps people create meaningful, profitable and highly useful businesses through innovation & design.
He is passionate about entrepreneurship, innovation, marketplaces, collaborative consumption, design that works and, of course, his family. When he's not consulting, teaching, selling over $1.8 million dollars of books or lending money to people in third-world countries (through Kiva), you'll find him reading, playing beach volleyball or mastering the art of surfing backwards.


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Hello Stampers!
It's time for my next online class preorder and it is one of my most FAVORITES! I know you hear me say that A LOT but I just LOVE this class!! I'm also throwing in a FREE $8 Wink of Stella Gold Glitter Pen with this class! Has this stamp set been on your wish list for awhile? Mark that baby off your list and sign up today! lol!
Remarkable You Online Class Preorder
(Here's a little sneaky peeky for you!)
Class Details: (This is what will come with your class)
*Remarkable You Stamp Set
*Rich Razzleberry Ink Pad
*Wild Wasabi Ink Pad
*Blender Pen
*FREE Wink of Stella Gold Glitter Pen
*FREE Supplies to make 6 cards (2 each of 3 designs) with envelopes!
*Exclusive Online Class Video that will be emailed to you after you receive your class package. You can view anytime or as many times as you'd like! I walk you through making ALL of the projects!
*PDF included with all the sizes and materials used in this class
This class is great for the beginner as well as the advanced paper crafter!
**You will need a Basic Black Ink Pad, scissors, adhesive, glue dots, & dimensionals for this class**
*PS – If you would like to substitute an ink pad for a different color or ink refill please put it in the notes or email me immediately! Once the orders are placed it is more difficult to make the switch.
Don't forget….. Today is the LAST DAY to order and get in on my personal special! See below. I will be honoring orders until 11:59 MDT tonight!! Please use Hostess code: P2SBMDG7 if placing an order under $150. You will still get my surprise package along with the Hostess Rewards for all orders over $150.
•Sign up for Paper Pumpkin HERE
Spread the love


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Apple has actually shut down exactly what appears to have actually been the first, fully-functional ransomware targeting Mac computers. This particular form of cyber threat entails malware that encrypts the data on your personal computer so you can easily no longer access it. Afterwards, the hackers request that you pay them in a hard-to-trace digital currency – in this case, bitcoin – in order for you to retrieve your files. This ransomware, called KeRanger," was initial reported by researchers at Palo Alto Networks. They likewise noted that Apple has actually now revoked the abused certificate that was used in the attack and updated its built-in anti-malware system XProtect along with a brand-new signature to protect customers.
Technically, KeRanger was not the initial ransomware aimed at Mac users. The security firm said that one more malware application known as FileCoder had been previously discovered. However, FileCoder was incomplete at the moment it was found, which is why the firm believes that KeRanger is the initial functional ransomware to appear on the OS X platform.
The naked truth that OS X has actually now been targeted speaks to the popularity of Apple's operating system – ransomware is a fairly common form of cyber threat these days as victims are frequently most likely to cave in to attackers' demands. This has actually also been the case in some high-profile attacks, as along with the ransomware that shut down servers in an L.A. hospital last month. The hospital eventually paid a ransom equivalent to $17,000 in bitcoins to grab its units spine up-and-running.
With KeRanger, the demands were much more modest, though it's unclear for now Exactly how several users actually fell victim to the attack and Exactly how successful it was at exploiting those victims.
For exactly what it's worth, Ryan Olson, Director of Threat Intelligence at Palo Alto Networks, tells us his firm believes that their quick action combined with Apple's fast response has actually "greatly limited the impact of this threat."
According to Palo Alto Networks, attackers infected two installers of Transmission, an open source BitTorrent client, along with the malware which would certainly after that encrypt files then reason a ransom of one bitcoin (about $400) to release the files spine to the users' control.
The KeRanger application itself was signed along with a valid Mac app progress certificate, which is Exactly how it was able to skirt about Apple's Gatekeeper protection mechanism. After being alerted to the threat on March 4, Apple acted swiftly this weekend break to revoke this certificate and update its antivirus signature, Palo Alto Networks said.
Apple has actually not posted detailed removal or support write-up concerning KeRanger at this time, yet the firm confirmed to TechCrunch that the certificate has actually been pulled so no one can easily install the damaged application. The very best method for consumers to protect themselves is to update Apple's malware profiles via XProtect, we understand.
End users are likewise reporting seeing protections "KeRanger.A malware" as being rolled out in the most up to date XProtect update. various other user-to-user advice on Apple's forums helps to detail the actions those that have actually currently come to be infected along with the malware ought to take, which require finding and deleting certain hidden files.
Transmission, which was a victim of the attack in its own way, has actually likewise updated its website to advise users that downloaded the infected version 2.90 of the software to upgrade and run version 2.92 instead. This version will certainly remove the malware-infected file from the system. (Transmission was never ever hosted on the Mac App Store, yet its app has actually an auto-update mechanism which will certainly suggestions those that don't manually upgrade.)
In addition, if a user now tries to run the infected version of Transmission, they'll be revealed a warning dialog that informs them to eject the disk image, and that the app will certainly damage your computer and ought to be moved to the Trash.
While Apple has actually addressed the immediate threats posed by KeRanger, there is still some concern provided that the security firm believes this malware is still under development. Its analysis suggests that attackers could be attempting to produce backdoor functionality that would certainly encrypt users' Time Machine backups, as well.
If that was the case, after that victims wouldn't have the ability to recover their files using Time Machine – they would certainly be much more at the mercy of the hackers' demands.


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Bishop Komarica is one of Europe's most courageous bishops, having stayed with his flock of Catholic faithful throughout the conflict in the former Yugoslavia and continuing to speak up for the many Catholic refugees still being unable to return to their homes. He also authored various books describing the destruction of Catholic churches and institutions during the 1992-1995 conflict.
Schloss TrumauSchlossgasse 212521 Trumau (AUSTRIA)Show in map
Telephone: +43 2253 218 08Fax: +43 2253 218 084e-mail: firstname.lastname@example.com


text: Welcome to the Sports Acupuncture Alliance. Registration for the 2018 Summit in the Bay Area, California will be announced soon! The keynote speakers will be Matt Callison. Guest Speakers will be Whitfield Reaves and Amy Moll. More speakers will be announced shortly. Stay tuned for more details on pricing, lecture topics, and accommodations. If you are not already in our email chain and would like to be, please send us an email at firstname.lastname@example.com


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Order Online or by Phone:
Code: 12516
BIG MAN vintage mens 1970s does 50s short sleeved disco cabana shirt. This amazing funky shirt comes in pink and white with a funky little swirl pattern! Has a super wide & pointy disco era collar with a loop neck closure. Closes in the front with pearly white buttons. Two pockets on the chest. Shirt has a straight hem. Tagged by Manhattan. Polyester/Cotton Blend.
Condition: Very Good.
Chest: 56" 3XL. Tagged a 2Xl but we are measuring it much closer to a 3XL. Please check your measurements before ordering! No Stretch.
Shoulders: 22"
Length: 32"


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Finish Deal Scenario for CVS
Finish is on sale at CVS for $4.00
Buy 8 = $32.00
Use ( 8 ) $2.15 mfr coupons from todays paper (-$17.20)
$32.00 –$ 17.20 = $ 14.80
Get a $10.00 CVS Cash Card = $4.80 = $0.60 each!
How to Shop For Free with Kathy Spencer
The Coupon Database Extreme Couponing, freebies, coupon, database
By Kathy Spencer 2 Comments
This post may contain affiliate links. Please see our full disclosure.
Get the book!
How to Shop for Free; Shopping Secrets for Smart Women who love to get Something for Nothing!
marie727 says
with a 4$off of$20 even closer to free!
goldfish says
There's an annoying stipulation on that coupon that says "limit of two like coupons in same shopping trip" … really glad CVS tracks.


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Lily of the Valley is a Child Youth and Care Centre catering for vulnerable and orphaned/abandoned children. We do not generally cater for children with moderate-severe mental or physical disabilities but many of our children experience disabilities due to their medical and social backgrounds. We strive to enable our children to achieve their true potential. To do this we are in the process of developing the Exit Programme to cater for those that do not thrive academically. This includes a Supported Employment service.
Lily is looking for an Occupational Therapist to run the Employment Programme, who has strong organisational and administrative skills as well as strength of character to work with teenagers/young adults.
Main Job Purpose: To equip and support young adults with disabilities to gain and maintain fair employment.
Duties and responsibilities:
- Vocational Preparation of young adults
- Holistic development of young adults
- Functional Capacity Assessments
- Job Searching and Matching
- Employer, Co-worker and Employee training and support
- Funding and Administration management of the programme
Qualifications and Skills:
- Degree in Occupational Therapy
- Current registration with HPCSA
- Has drivers licence or intending to get it soon
- High level of initiative, self-direction and a strong sense of accountability
- Good communication and teamwork skills
- Flexibility
Location: Mophela/Eston, Kwazulu Natal
Position type: Permanent
Salary: R15, 500.00 per month (less UIF and PAYE)
Start Date: As soon as possible, latest 31 July 2017.
Contact person: Mr T Mncwabe (Operations Manager – Lily of the Valley)
Email cv: email@example.com
Cell: 0833539158 or 0311000111


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Words that start with esgr
Found 5 words that start with esgr. Browse our Scrabble Word Finder, Words With Friends cheat dictionary, and WordHub word solver to find words starting with esgr. Or use our Unscramble word solver to find your best possible play! Related: Words that end in esgr, Words containing esgr
- Scrabble
- Words With Friends
- WordHub
- Crossword


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| | | | |
Brain Pop
Vantage Learning - My Access
Carnegie Learning
Study Island
South East Asia Center
The Peoples Music School
Boys and Girls Clubs of America
Fact Monster
Kids Click
William C. Goudy Technology Academy
Principal, Pamela Brandt
Assistant, Principal Bill Yeh
CPS Calendar 2016/ 2017
Copyright (c) 2010 to present. William C. Goudy Technology Academy. All rights reserved.
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Also found in: Dictionary, Thesaurus, Medical, Legal, Financial, Acronyms, Encyclopedia, Wikipedia.
Related to quantity: Physical quantity, Quantity Supplied
consume mass quantities
To eat, drink, or otherwise consume large amounts of something. Primarily heard in US, South Africa. Large family holidays are all typified by consuming mass quantities of food and alcohol. As the largest economy on the planet, our prerogative seems to be to consume mass quantities of the Earth's resources.
an unknown quantity
A person or thing that is unpredictable and thus difficult to anticipate. We're still revising our new product, so its potential success is an unknown quantity. This is her first year teaching, so her ability to connect with her students is still an unknown quantity.
known quantity
someone whose character, personality, and behavior are recognized and understood. We need not worry about how John will behave. He is a known quantity. Lisa is a known quantity and I am sure she will not surprise us by voting with the opposition.
*unknown quantity
Fig. a person or thing about which no one is certain. (*Typically: be ~; become ~.) John is an unknown quantity. We don't know how he's going to act. The new clerk is an unknown quantity. Things may not turn out all right.
an unknown quantity
if someone or something is an unknown quantity, you do not know much about them or what effect they will have in the future Turner may do well in the election, though he is an unknown quantity as a campaigner. The new computer system is still an unknown quantity for our department.
unknown quantity
An unpredictable person or thing, as in We don't know how the new pitcher will do-he's an unknown quantity. This expression comes from algebra, where it signifies an unknown numerical value. Its figurative use dates from the mid-1800s.


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My husband and I spent 2 nights. The room was clean and toiletries lovely. The restaurant was super. Fantastic food and wine. Breakfast was great. Staff so friendly and helpful. Would definitely stay there again.
Getting you more information on this room
Getting you more information on this room
"If you are dog free a room on the first floor may offer views of the garden."
"Rm 62 a quiet room, stairs to reach it . Rm 63 is at foot of stairs, Rm 50 for those tht cannot use stairs"
"The staff are very helpful and rooms at the rear of the hotel are very quiet."


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1) You can start right where you are
2) Find a programme
3) Donate
A group of 28 former commanders of the Isatabu Freedom Movement (IFM) took part in a course on peace and community building organized by Winds of Change, the Initiatives of Change group in the Solomon Islands.
A six week Creators of Peace Circle has just been held in Adelaide
"Cultivating knowledge – Generating Action": A series of lectures engaging people in honest conversations on the broad issues associated with globalisation and the human face of economics.
A diverse group of 17 young people from eight countries completed the Life Matters course, 15-24 February, at Armagh, the IofC centre in Melbourne, Australia.
Seldom can the uttering of one word have caused such joy across a nation.
Three former Prime Ministers of Australia were among the 300 who attended the State Funeral of Kim Edward Beazley on 20 October 2007. In 1953 Beazley spent seven weeks at the Initiatives of Change conference centre in Caux, Switzerland – an experience which profoundly affected his life and political career.
Kim Beazley Senior was that rare breed – an honest politician who earned the admiration and trust of all sides of politics.
Fifty women from many backgrounds gathered in Belmore Community Centre on Sunday 12th August for the annual get-together of Peace Circles from around suburban Sydney.
With differing expectations, fears, hopes and dreams, a diverse group of individuals gathered for the Life Matters course last month.
As the long awaited first rain of winter blanketed the city, sixty people from all walks of life gathered for the first public showing of The Imam and The Pastor in Perth.
Mailing address: 226 Kooyong Road, Toorak, Victoria 3142 ABN: 22 004 350 789


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'No link' between pilot's politics and loss of Flight 370
Related topics
Reports linking the pilot's political affiliation to the plane's disappearance were dismissed as wild, groundless allegations by the Malaysian opposition People's Justice Party, of which the captain is a life member.
The party said reports that captain Zaharie Ahmad Shah was at the court that sent opposition leader Anwar Ibrahim to jail on sodomy charges several hours before the pilot was to fly the plane to Beijing were untrue.
"Allegations that some tabloids in the UK have made about captain Zaharie were wild and not supported by facts," party spokesman Fahmi Fadzil said.
"I was at the trial during the two days and do not remember seeing him," he added. But he also said he did not know Zaharie was a party member until the news about the plane broke on March 8.
Fahmi said he hoped that the federal government would not use such reports to "label" opposition party members.
The Daily Mail ran a widely circulated story yesterday claiming Zaharie was a "political fanatic" and an obsessive supporter of Anwar, who was sentenced to five years' jail.
Citing unnamed colleagues, the report said that Zaharie planned to attend the court case involving Anwar on March 7 - just hours before he was to pilot flight MH370 to Beijing - and that he was reportedly there, adding that Anwar's conviction left Zaharie profoundly upset.
Investigators have so far not been able to confirm if Zaharie was in court, according to a source close to the investigation.
Sivarasa Rasiah, a member of Parliament and a lawyer representing Anwar in the case, told reporters yesterday: "He has been a party member since early last year and campaigned for us during the general election but this is irrelevant to the case.
"Even though I was not there at the trial for its entirety, I can say that he was not there. Because if he was, I would have been notified," he said.
Speculation is mounting as to who might be responsible for the disappearance of the plane. Investigations have revealed that the plane flew under the radar and that its communications systems were switched off, lending plausibility to the theory that the plane was hijacked by a person with aviation skills.
Police had intensified their checks on the two pilots, and on other crew members and passengers on the plane, Malaysian defence and acting transport minister Hishammuddin Hussein said yesterday.
Hishammuddin said that the police searched the homes of the two pilots and were looking at the captain's flight simulator.
Malaysian police chief Khalid Abu Bakar said: "Police have dismantled it and reassembled it to examine it. Meanwhile we're getting experts to look at it."
Hishammuddin said that the pilot and co-pilot did not ask to fly together, and said reports that the pilot's family had moved out a day before the flight vanished were untrue.
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Opel's next-generation range of mid-size cars promises a radical step forward. The new model family, which makes its world premiere at the London Motor Show in July 2008, sets technology and design standards for the Opel brand and mid-size segment. To lead off the proceedings, Opel today announced the new model's name: Opel Insignia. The new Insignia family will be built at Opel's home plant in Rüsselsheim, one of the most state-of-the-art automobile production facilities in the world.
"Dynamic performance is one of the Opel brand's core values. In the new Opel Insignia, this defining characteristic is realized by sophisticated powertrain technology, active safety and the interface between driver and car. The Insignia's level of comfort and environmental friendliness is unrivaled even among considerably more expensive competitors," says Alain Visser, Chief Marketing Officer, General Motors Europe. With the Insignia, Opel continues pursuing its strategy of making advanced technology affordable for more customers.
When it comes to the new car's design, Visser says, "A closer look at our groundbreaking GTC concept car gives a good idea of how exciting Opel's new design language will be."
The beginning of Opel's modern mid-size heritage dates back to 1970 with the launch of the Ascona, which sold 4.4 million units over three generations. This was succeeded by the Vectra in 1988, heralding a new era of innovative models from Opel. With almost 5.5 million models sold to date, the Opel Vectra is one of the key players in the mid-size segment.
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Hakiam has never lived in one place for more than a couple of years. When he aged out of foster care in Ohio, he hopped a bus to Philly to start over, but now he's broke, stuck taking care of his cousin's premature baby for no pay, and finding it harder than ever to stay out of trouble. When he meets Wendy at the tutoring center, he thinks she's an uppity snob—she can't possibly understand his life. But as he gets to know her better, he sees a softer side. And eventually—much to the chagrin of Wendy's father and Hakiam's cousin—they begin a rocky, but ultimately enlightening, romance.
This edgy story about a star-crossed couple features strong African American characters and sparkles with smart, quirky dialogue and fresh observations on social pressures and black-on-black prejudice.
From the Hardcover edition.


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Riverside Campground
We left the cold windy weather of Glacier, MT heading south to spend some time in Utah and Arizona before returning to CA for the holidays. We quickly left behind the mountains and drove through the rolling somewhat flat areas of Montana, to spend a few days in Helena at a free campground that Lee & Trace of Camper Chronicles enjoyed before our time together at Glacier.
Between Great Falls and Helena were these beautiful rocky mountains running along the Missouri River. Very pretty. We did pass a sign warning us to be aware of a wanted murder suspect that was hiding in the area. That was a first. They did catch him the next day.
Riverside Campground on Canyon Ferry Reservoir is located about 20 miles to the east of Helena on the north side of the dam of Canyon Ferry. It is run by the Bureau of Reclamation. There are a few campgrounds on this lake, but this one is FREE.
Here is our campsite #20.
There are less than 30 sites and many are back-ins and pull-throughs right along the water. This park is clean, has a boat launch, pit toilets and garbage. No hookups, but FREE. There are water spigots, grills and campfire rings. Spacing is very nice. We were really looking forward to campfires again!
There was also a nice bike/walking path along the water.
|Dam to the south.
|Steve working outside by the campfire. It's nice to have a portable office!
|The dam at night.
A view of the campground looking north, from the dam. That's our Montana, second from the right.
What an amazing sunset as we settled in for the week.
We just lounged and paddled the kayak around while we were here and relaxed.
The deer were all along the shoreline.
What a peaceful time.


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By Peter Duru
MAKURDI – An unsavory fear has gripped residents of Gboko town after a family of five, resident at the Mkar area of the town, were confirmed dead after a meal of guinea corn.
The unfortunate incident occurred in the household of a popular wood seller, Mr. Aondohemen Iorumbur, a native of Konshisha Local Government who resides directly opposite the NKST Christian Hospital Mkar in the ancient city of Gboko.
According to eyewitness report, the bizarre incident which shocked residents of the town was the first of its kind in the history of Gboko.
Our source noted that amongst the victims was the aged mother of Mr. Aondohemen Iorumbur, Mama Nyiengohol Iorumbur; his four kids, Ioryoosu, Terungwa, Msugter and Msuur.
The deceased family members were said to have suddenly manifested strange ailments after their dinner and minutes later went into coma.
It was also gathered that when a neighbour of the victims noticed the strange happenings at the home of the Iorrumburs, he raised an alarm. However, the intervention of passersby could not help as the victims were already dead.
They were said to have been rushed to a private hospital in Gboko where doctors suspected that they must have died from food poisoning, though autopsy is still being awaited.
When Vanguard paid a visit to the home of the victims, no one was available to comment on the issue. But a neighbour, who craved anonymity, lamented the incident saying that the entire neigbourhood was in shock and could not believe what has befallen the entire Iorumbur household.


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North Carolina State University science fair
Think about what career is best suited for you, and where you want to study. Request more information now.
Think about what career is best suited for you, and where you want to study. Request more information now.
Think about what career is best suited for you, and where you want to study. Request more information now.
Get the facts about North Carolina State University science fair, and registering for elective courses. Which college degrees give you the best chances of finding employment after graduation? To earn a higher salary, compare accredited engineering concentrations, and research technical certificate programs in your chosen field. Concentrating on North Carolina State University science fair, for example, you may gain an advantage in job recruiting on-campus. Check with the mechanical engineering department for course registration deadlines, and scientific research program requirements. Please use the form above to request admissions info for North Carolina State University
Mechanical engineering degrees typically take four to five years to complete, and result in a Bachelor of Engineering (BEng), Bachelor of Science (BSc or BS), or Bachelor of Mechanical Engineering (BME). In the US, most undergraduate mechanical engineering programs are accredited by the Accreditation Board for Engineering and Technology (ABET). Mechanical engineering programs include courses on composites, thermodynamics, engine design, fluid dynamics, control theory, robotics, and computer-aided design (CAD). In addition to the core mechanical engineering curriculum, many mechanical engineering programs offer more specialized programs and classes, such as control systems, fuel cell technology, and biomechanics.
Many mechanical engineering companies have begun to incorporate computer-aided engineering (CAE) programs into their existing processes, including 2D and 3D solid modeling computer-aided design (CAD), enabling faster and more exhaustive visualization of products. Other CAE programs commonly used by mechanical engineers include product lifecycle management (PLM), and analysis tools such as finite element analysis (FEA), computational fluid dynamics (CFD), and computer-aided manufacturing (CAM). Further, automation in the form of industrial robots allow businesses to save money on manufacturing costs, and ensure precision quality control. The median annual income of mechanical engineers in the US workforce was $80,580, highest when working for the government ($92,030), and lowest in education ($57,090). Beyond major requirements within the mechanical engineering department, you may consider Rockford University astronomy courses online as an adjunct to your primary course of study.
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23rd JANUARY to 28th FEBRUARY 2014
Discover a world of beauty and celebrate the rich culture of Indonesia with "From Indonesia with Love", a solo painting exhibition by Indonesian painter Sasya Tranggono. Featuring the latest water color and mixed media paintings of butterflies, flowers and "wayang", the traditional Indonesian puppets, this exhibition is a culmination of Sasya's career that spans over twenty years.
Prepare yourself as you are taken on an artistic journey celebrating the metamorphosis and portrayal of human life, depicted by the painter with vibrant colors and graceful brushstrokes. Collectors of her works of art include the Former President of Indonesia Megawati Soekarnoputri and the belated Former President of The Philippines Corazon Aquino.
All paintings displayed during this exhibition are available for purchase and a part of the proceeds will go to UNICEF.


text: Hey all... I don't know if this is a repeat of info, the search isn't working right now... but I thought I should post it here... Season 2 of Monk airs starting June 20th (Friday) and all previous news said the Pilot episode of Monk would be hitting DVD on June 24th. According to USA's official website, they just updated with the news (and listed in their FAQ too) that it will be the entire first season. I really like this show (it reminds me of a modern day Poirot, set in SF) and eagerly await to get the series on DVD. I just thought any fans of the show would like to know. -Kent


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Click here to print the obituary below
Linda Barnecut
Linda Marie Barnecut
LANCASTER: Linda Marie Barnecut, 66, of Lancaster, passed away Thursday, October 31, 2013 at her home with loved ones by her side. She was born September 21, 1947 and was a graduate of Bishop Fenwick High School class of 1965. Linda was a member of St. Mary of the Assumption Catholic Church and a part of their bereavement ministry. She also worked at Risch's Drug Store (Fair Ave) for the past 16 years.
Linda was preceded in death by her husband Paul W. Barnecut Jr., her parents Carl and Bernadine (Shonebarger) Soles, and her in-laws Paul Sr. and Helen (Carpenter) Barnecut.
Linda is survived by her children and grandchildren; Karla (Cosper), Corey, Lillian, and Alexis of Logan; William, Carrie, Collin, Ashton, Gabrielle, and Nicolas of Lancaster; Debra, John (Vance), Ashlynn, Skyler, and Johnathon of Sugar Grove; Michael, Alyssa, Jocelyn, and Anthony of Lancaster; ElizaBeth of Lancaster; Michelle of Lancaster; many honorary children and grandchildren, you know who you are and how much you meant. She is also survived by her sister Ruth Ann Fulton of Gainesville, Fl; brother-in-law, Dan; nieces and nephews, Christopher, Jonathan, Sara, and Rachel, and a great nephew Braedon.
A Funeral Mass of Christian Burial will be held on Monday, November 4 at 10:30 AM at St. Mary of the Assumption Church with Fr. Craig Eilerman as Celebrant. Burial will follow at Forest Rose Cemetery. Family will receive friends on Sunday, November 3 from 2-4 PM & 6-8 PM at the SHERIDAN FUNERAL HOME.
In lieu of flowers memorial contributions may be made to FairHoPe Hospice or The O.S.U. James Cancer Center (Melanoma Cancer Research).
To send an online condolence and sign guestbook, please visit
and click obituaries.
Funeral Home
Sheridan Funeral Home - Lancaster
222 South Columbus Street
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Published in the Lancaster Eagle-Gazette on Nov. 1, 2013


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Bright Gift Ideas Limited was set up on Tuesday the 15th of February 2000. Their current address is Unit 1 Robinhood Business Park,Ballymount,Dublin 22, and the company status is Normal. The company's current directors Anthony Birchall and Joseph Birchall have been the director of 1 other Irish company between them. Bright Gift Ideas Limited has 3 shareholders.
|Company Name:
|Bright Gift Ideas Limited
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|Unit 1 Robinhood Business Park,
Dublin 22
|+353 (0)1 465 6444
|Key Executive:
|Joseph Birchall
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Joseph Birchall is a Company Director of Bright Gift Ideas Limited since 2000 and a listed Director of 1 other companies.
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Fall '16 EditionIn this issue of Theory to Practice, we examine questions explored by our faculty and our students. How can educational systems help refugees who are struggling to start life anew in countries feeling the strain? How can teachers better engage students who are ever more culturally and linguistically diverse? Can wearable technology help in the evaluation of how principals use their time? We also highlight the important work that the College is doing around the globe, from the Lehigh Valley in Pennsylvania to Cambodia, China and the Czech Republic.
ISSUE No. 7 • FALL '15
The Charter Challenge: As charter schools proliferate, a polarizing debate could use common ground.
Fostering a Secure Attachment: A Lehigh researcher challenges long-held beliefs about how mothers can best connect with their infants.
A Case for Public Education: Activist Diane Ravitch answers questions her critics might ask.
ISSUE No. 6 • FALL '14
State of the Union: Have teachers unions become obstacles to reform in the battle over public education?
Respect Begets Respect: Restraint and "scream rooms" are hurting kids. Here's a better way for dealing with students with behavior problems.
A Man of the Times: Michael Golden's worldview was shaped, in part, by Lehigh's College of Education.
ISSUE No. 5 • Fall '13
The Reverse Gender Gap: Boys now lag behind girls in several significant areas of education. We look at the reasons—and possible solutions.
Finding Common Ground: Where can we find research-supported points of consensus amid the long-running clamor over school reform?
Inside the Mind of School Shooters: What teachers, administrators, parents, and students can do to help prevent these tragedies.
ISSUE No. 4 • FALL '12
Reinventing the Future: Are we being too one-dimensional when we think about STEM education, or do we need to follow a new blueprint?
The Bully Among Us Bullying is rampant in schools, and it creates a toxic environment that hurts bystanders, bullies and victims.
Lore vs. Law Exploring five prevailing myths in special education litigation, and why they lead to misguided policies.
ISSUE No. 3 • FALL '11
Saving the Future: Response to Intervention is a data-driven method of addressing specific learning disabilities.
A Mathematical Enigma: The simple truth: Preschool math skills are indicators of long-term academic success.
Competition Canard: Despite the misperception, American classrooms are more competitive than you think.
ISSUE No. 2 • FALL '10
Education Held Hostage: Across the globe, in the most unlikely of places, academic humanitarians help students turn tragedy into opportunity.
Our World, Our Lab: Lehigh builds a community of K-12 scholars in the healing nations of Cambodia and South Africa.
Redemption: Centennial School students persevere, achieve and become their own role models. A photo essay.
The Economics of Reform: With billions of dollars of aid being poured into education, Washington takes tighter control of the purse strings.
Building the Bench: The City of Brotherly Love turns to the next generation of urban educational leaders.
Expelling ADHD: A package of preschool interventions gives youngsters a new perspective on life.