text:
|Publication number
|Publication type
|Application number
|Publication date
|Oct 31, 1978
|Filing date
|Feb 2, 1977
|Priority date
|Feb 2, 1977
|Publication number
|Wim J. M. Pieters, Emery J. Carlson, William E. Gates, William C. Conner, Jr.
|Original Assignee
|Allied Chemical Corporation
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (12), Referenced by (16), Classifications (11)
|External Links: USPTO, USPTO Assignment, Espacenet
This invention relates to an improved copper chloride/alkali metal chloride catalyst on silica or titania carrier, for reaction between hydrogen chloride and elemental oxygen generating chlorine and/or chlorinating an organic material containing hydrogen replaceable by chlorine.
Such catalysts are known in general in the prior art, for example, in U.S. Pat. No. 3,210,158 of Oct. 5, 1965 to Engel et al. In that patent a silica gel preferably having average pore diameter of at least 60 Angstroms, e.g. 140 Angstroms in certain examples, and having surface area of at least 200 square meters per gram is impregnated with a solution of the chlorides of copper, one or more rare earth metals and one or more alkali metals. Conventionally, such catalysts are formed by use of aqueous solutions. The impregnated carrier was dried and heated for 3 hours in an air stream to 250° C.
The catalyst was used for conversion of hydrogen chloride into chlorine at space velocities in the examples of 40 liters of gaseous HCl or 80 liters of gaseous HCl per kilogram of catalyst per hour. These space velocities calculate to residence times of about 50 seconds and about 20 seconds, respectively. The proportions of metal compounds and the temperatures employed are such as to assure that the mixture of metal compounds is entirely or partly present in the molten state. The temperatures in the examples are 300° C., 350° C. and 400° C.
U.S. Pat. No. 3,657,367 of Apr. 18, 1972 to R. J. Blake et al. is representative of prior art disclosures showing chlorination of organic materials in the vapor phase by action of hydrogen chloride and an oxygen-containing gas (i.e. the process known as oxyhydrochlorination, or "OHC"). This patent points out that copper halide catalysts are volatile at the required reaction temperature, resulting in loss of activity over an extended period of time and a tendency of the catalyst to cake during its active life. The patent discloses a catalyst of cupric chloride, potassium chloride or sodium chloride, and a mixture of didymium and lanthanum chlorides, whereby the fluidized catalyst does not tend to cake during its active life at the reaction temperatures which are between about 300° and about 600° C., preferably between about 350° and about 450° C. The preferred residence time is about 1 to about 20 seconds, especially about 2 to 10 seconds. The supports or carriers used in this patent have surface area not over 90 square meters per gram, preferably about 1 to about 30 square meters per gram; they include silica gel but preferably are alpha-alumina or silica-alumina.
A catalyst formed from finely divided pyrogenic oxide such as non-porous pyrogenic silica particles, impregnated with an aqueous solution of a metal compound such as molybdenum, chromium, tungsten, cobalt, vanadium, titanium, platinum, nickel and the like, has been disclosed in U.S. Pat. No. 3,235,508 of Feb. 15, 1966 to K. L. Mills. The catalyst is employed for hydrocarbon cracking and for olefin polymerization.
The present invention is directed to an improved copper chloride/alkali metal chloride catalyst on silica, titania or alpha-alumina carrier or support, for production of chlorine or organic chlorination products, involving reaction between hydrogen chloride and elemental oxygen. The subject catalyst consists essentially of a carrier of open structure, especially such carrier of pyrogenic origin, on which the active ingredients are deposited. By "open structure" is meant that the carrier is formed from colloidal size particles adhering to one another in chains, loops and the like whereby the carrier has relatively low bulk density, typically about 0.03-0.05 gm./ml. for silica carriers. The carrier is composed of adhering silica, titania or alpha-alumina particles, which particles are non-porous and have diameters in the range of about 50 to 1000 Angstroms. The carrier has surface area of at least about 50 square meter per gram, preferably between about 100 and about 400 square meters per gram by the BET method using nitrogen gas.
The finished catalyst consists of granules, and has voids within the granules such that at least 20% of the voids have radii greater than 200 A as measured by nitrogen sorption isotherms. The surface of said granules is occupied by the active catalyst, viz. a first layer or deposit of copper chloride and a second layer composed of at least one alkali metal chloride and permissibly also composed of at least one rare earth metal chloride. By "layer" we mean to include patchy, broken and irregular surface deposits which may interpenetrate each other here and there, or may form substantially continuous coatings.
In the catalyst of this invention, the non-porous particles forming the carrier are preferably particles of pyrogenic silica (also known as "fumed" silica). Preferably the first layer of active catalyst, i.e. copper chloride, is in larger molecular proportion than the second layer. In addition to alkali metal chloride, the second layer of active catalyst also includes, in preferred compositions, a rare earth metal chloride in a molecular proportion less than that of the alkali metal chloride therein. Preferably the alkali metal chloride is potassium chloride.
Preferred catalysts are composed essentially of silica about 30-85% by weight of the total catalyst, rare earth metal chloride at least about 5% by weight of the total catalyst, and potassium chloride at least equal in weight to the rare earth metal chloride; with copper chloride, essentially in cuprous form, essentially the balance of such catalyst and amounting to at least about 10% by weight of the total catalyst. Preferably the rare earth metal chloride comprises lanthanum chloride.
The subject catalyst carrier is anhydrous in the sense that it shows an ignition loss, as prepared, of not over 5% at 1000° C. During preparation of the catalyst, overexposure to moisture should be avoided, since otherwise collapse of the carrier structure may ensue, as a result of hydration of the carrier. Small amounts of moisture in the finished catalyst, such as 5 to 10% by weight of the catalyst, appear to be harmless, however, according to our tests.
Accordingly, the impregnation with the active catalyst ingredients is advisedly accomplished using essentially anhydrous solvents. The cuprous chloride ingredient can be introduced onto the carrier using a volatile organic solvent such as acetonitrile, which is then evaporated to leave a layer of cuprous chloride on the carrier particles. Then the potassium chloride ingredient can be introduced as a solution and the lanthanum chloride as a solution or colloidal dispersion, in a volatile organic solvent such as high strength formic acid. Formic acid is particularly suitable because it does not dissolve the earlier formed deposit of cuprous chloride. The concentration of the active ingredients (copper chloride, potassium chloride, and lanthanum chloride) is preferably adjusted with reference to the surface area of the pyrogenic silica particles so that theoretically on the average, after drying, between 1 and about 10 monolayers, i.e. coatings one molecule thick, of the active ingredients will be formed upon the silica carrier; preferably about 5 monolayers. The cuprous chloride is preferably applied first, we have found; we believe this indicates coordination of some sort occurs, in the active form of the catalyst, between atoms of the anhydrous silica surface and atoms of cuprous chloride.
After each step of impregnating with a solution the composition is dried. The resulting dried, freshly prepared catalyst is frequently not active below 350° C. for oxyhydrochlorination (OHC) reactions such as that of methane. The catalyst becomes active at lower temperatures, by exposure to the stated reactants at a temperature such as 350° C. or above. Once reaction begins, the temperature can be lowered in OHC reactions to well below 350° C., and even well below 300° C. for certain proportions of hydrocarbon:HCl:oxygen; while still maintaining a desirable rate of reaction as indicated by a residence time such as 1.5 to 3 seconds at conversion of hydrocarbon (e.g. methane) in the OHC reaction amounting to at least about 50% and up to 100%.
Hydrogen gas and HCl gas are effective catalyst activators at about 280°-320° C. for OHC reactions of methane. A volume of such gas equal to the volume of the catalyst bed is sufficient.
The temperature level at which our catalyst is active for OHC reactions, we have found, depends on the composition of the reacting gases. When, for example, the inlet composition is about the stoichiometric in CH4 and HCl, and oxygen is at least stoichiometric, for production of CHCl3 and/or CCl4 from methane, HCl, and oxygen -- our catalysts (once activated) are active down to temperatures as low as 175°-190° C.; whereas as compositions containing higher proportions and lower proportions of methane are fed to the catalyst bed, progressively higher temperatures must be used, up to about 350° C. Lowest operating temperatures can be reached when the oxygen is present in the inlet reaction mixture in excess over the above cited stoichiometric proportion.
For any reaction mixture of e.g. oxygen, methane and hydrogen chloride there is a minimum usable operating temperature, or "extinction" temperature, below which the hydrocarbon conversion abruptly drops to nil from generally above 60% at about 1.5-3 seconds residence time. The catalyst is then inactive, but may be reactivated by passing the reactants in contact therewith at temperature of 350° C. or above.
Cupric chloride deposited on the carrier from a solvent such as methanol functions under our conditions as a source of cuprous chloride. The cupric chloride and the solvent should be substantially anhydrous, to maintain the anhydrous condition of the silica carrier; and the solvent should be volatile to allow complete removal by moderate heating, not above 300° C. When cupric chloride is the starting material, we have found that on the pyrogenic form of silica, used as carrier in our catalyst, the cupric state of copper is reduced under our oxyhydrochlorination conditions at least in large part to the cuprous state. The copper chloride ingredient of this catalyst accordingly is essentially cuprous chloride.
Advantages of our catalysts are that they are operative at temperatures well below 400° C., and indeed below 300° C. At 300° C. and below, the active ingredients do not melt, and are quite stable against volatilization, so that the catalyst remains active over long periods and is free from caking. The corrosiveness, at the low temperatures (200°-350° C.) which can be used under circumstances pointed out above, toward "Inconel" 600 chromium-nickel alloy is of the order of only 3 mils per year. The catalyst granules are strong enough to be practical for use in a fluid bed operation. At relatively high HCl proportions in the inlet reaction mixture, significant amounts of free chlorine together with oxyhydrochlorination products are obtained by using catalysts of this invention.
The examples which follow illustrate our invention and set forth the best mode contemplated by us for carrying out the invention but are not to be interpreted in a limiting sense.
Example I illustrates the presently preferred method of preparation of our catalyst; tabulated Runs 1-18 illustrate results obtained by its use in the oxyhydrochlorination of methane to chlorinated products. An unusual observation is that in this reaction a certain amount of free chlorine can be obtained by use of our catalyst, e.g. under the conditions shown in Runs 7 and 16 of Table I.
Example II illustrates an alternative procedure starting with cupric chloride. Table II shows the results obtained.
Example III shows use of titania as carrier; Table III shows results. Similarly, Example IV and Table IV relate to use of alpha-alumina as carrier.
Parts are by weight unless otherwise stated.
41.66% CuCl
11.46% KCl
9.38% LaCl3
37.5% Anhydrous Pyrogenic SiO2
Stir 100 parts of solid CuCl and 235 parts of liquid acetonitrile solvent at room temperature (20° C.) for 45 minutes in a closed flask. Allow to settle and separate the supernatant saturated solution.
Set aside 100 volume parts (85-86 weight parts) of the saturated solution for the next step -- to be used freshly. (The solution contains 10.0 parts of CuCl.)
Weigh out 9 parts of pyrogenic silica particles (such as that sold by Cabot Corp. as "CAB-O-SIL" Grade HS-5, rated at surface area of 325 m2 /gm. and particle diameter of 70 A.; purity 99.8% SiO2), bulk density of 0.037 (max.). Add the saturated CuCl - acetonitrile solution, in fresh form, prepared above. Also add 45 volume parts of additional pure acetonitrile to obtain more fluid consistency, and allow to stand overnight. Affix the flask to a rotary evaporation unit, adding a number of 1/2-inch ceramic balls to enhance mixing. Increase temperature gradually to about 60° C. under vacuum to remove most of the solvent. The resulting solids are dried in a vacuum oven at 90°-100° C. overnight.
Prepare a solution of 2.75 parts of KCl and colloidally disperse 2.25 parts of anhydrous LaCl3 in about 70 volume parts of 97-98% pure formic acid. (If the LaCl3 is in hydrate form, it normally will be dried). Protect the LaCl3 and the solution from moisture.
To a flask containing the SiO2 -CuCl solids, add the above formic acid solution containing KCl and LaCl3. Mix and allow to equilibrate overnight protected from the atmosphere. Place in a rotary evaporator. Use low RPM and bring the temperature up to about 60° C. at full aspirator vacuum. The material will go from a slurry stage to a tacky stage and next to a granular stage. At this point maintain the vacuum but reduce the RPM to zero. This is to maintain a granular form rather than going to a fine dusty material. After about 2 hours total, transfer the flask and its contents to a vacuum oven overnight at about 90°-100° C.
Remove the contents and size or crush and collect that portion between -40 + 100 mesh. The fines passing through 100 mesh, comprising about 1/3 the total solids, may be reconstituted to a coarser mesh by reintroducing solvent such as formic acid or methanol and again going through the evaporation step at low RPM, and drying and crushing to size as above.
Such finished catalyst was examined by the usual nitrogen sorption methods for surface area and pore structure. The following results were obtained.
______________________________________Surface area (sq.m./gm.) = 92.9Pore volume (cc./gm.), total = 0.34Volume of pores having radius ≧ 200 Angstroms = 0.17Volume of pores having radius ≧ 50 Angstroms = 0.26______________________________________
Based on the carrier surface area as 325 m.2 /gm. and assuming the coverage of the catalyst surface is approximately 1,000 square meters per gram of KCl and LaCl3, it can be calculated by the formula below that a layer of KCl/LaCl3 of average thickness about 1.7 molecules would theoretically be formed on the silica carrier by the 2.75 parts of KCl and 2.25 parts of LaCl3 : ##EQU1## By the same formula, the thickness of the underlying cuprous chloride layer calculates to 3.4 molecules.
A silica gel/copper chloride catalyst was prepared in conventional manner using a silica gel carrier of comparable surface area to that of the pyrogenic silica particles serving as carrier for the above-described catalyst of Example I (i.e. gel of area 300 sq.m./gm.), and having relatively large average pore diameter of 120 Angstroms. The support was heated, and then impregnated with aqueous cupric chloride and with aqueous potassium and lanthanum chlorides, in conventional manner; and was screened to -40 to 200 mesh. Its surface area and pore structure were determined in the same manner as for the catalyst of Example I, with the following results:
______________________________________Surface area (sq.m./gm.) = 224Pore volume (cc./gm.), total = 0.89Volume of pores having radius ≧ 200 Angstroms = 0.01Volume of pores having radius ≧ 50 Angstroms = 0.64______________________________________
It will be seen that the pore structure of the catalyst of Example I -- considering the voids within the catalyst granules, between the particles of supported catalyst, as being "pores" -- is radically different from the pore structure of conventional silica gel/copper chloride catalysts.
Catalysts prepared as in Example I above and Example II below were used in oxyhydrochlorination runs with methane, and that of Example III below was used in production of chlorine from HCl and oxygen. The results are summarized in Tables I, II and III, below.
The reactor used consisted essentially of a vertical open ended quartz tube, surrounded by an outer tube or jacket, and supported in an electrically heated furnace. Reactant gases are supplied at the desired temperature through inlet valves and pass out through exit valves controlled by a temperature controller. The jacket is sealed to the inner reactor tube near the top of that tube and closes over below the open bottom end of the reactor tube. The catalyst bed is retained in the reactor by a quartz wool plug at the bottom, then crushed quartz (medium and fine) and on top a quartz wool plug covered by crushed quartz.
The reactant gases enter the jacket through a side arm, flow down the annulus between the jacket and the inner reactor tube to the closed off bottom of the jacket, rise from there into the open end of the reactor tube, pass through the catalyst bed therein, and exit from the top of the reactor tube.
The exit manifold delivers reactants to product separating chromatographic columns and associated detectors, and then to an outlet. The flows of the three principal reactant gases, HCl, O2, CH4 and diluent gas N2 are set and regulated by electronic flow controllers. Total pressure of the combined reactant mixture is recorded by a pressure recorder ahead of the inlet.
Carrier gas helium is controlled by a pressure regulator and diverted to the chromatographic columns by another valve.
The catalyst of Example I was activated for the runs of Table I by starting the operations with volume ratio of O2 :CH4 :HCl typically 2:1:4 and at a temperature of 350° C.
The headings of the tables below are explained as follows, where [ ] represents mols per 100 mols of the inlet reactants (i.e., CH4, O2 and HCl) and [CM] represents total mols of chlorinated methanes per 100 mols of reactants.
"R.T." (residence time) = (catalyst void space)/(inlet gas flow rate at reaction temperature), where catalyst void space is taken as 50% of the volume of the catalyst bed.
"Conv. CH4 " (conversion) = 100 {[CH4 ]in - [CH4 ]out}/[CH4 ]in.
"Select. CH4 " (selectivity) = 100 [CM]/{[CH4 ]in - [CH4 ]out}.
Depth of chlorination = 25{[CH3 Cl] + 2[CH2 Cl2 ] + 3[CHCl3 ] + 4[CCl4 ]}/[CM].
"deacon" = 100 × {[HCl]in + [HCl]formed - [HCl]out}/{[HCl]in + [HCl]formed}, where [HCl]formed is that theoretically formed by reaction of Cl2 with a methane hydrogen atom (forming = CCl + HCl); i.e., [HCl]formed = [CH3 Cl] + 2[CH2 Cl2 ] + 3[CHCl3 ] + 4[CCl4 ].
"% free Cl2 " = volume of chlorine product per 100 volumes of inlet reactants.
Table I:__________________________________________________________________________Use of Catalyst of Example I for OHC of MethaneInlet Composition Conditions ResultsRun (volume percent) Temp R.T. Conv. Select Depth %FreeNo. O2 CH4 HCl ° C. Sec. CH4 CH4 Chlorin. Deacon Cl2__________________________________________________________________________1 17.9 18.7 63.4 318 2.59 63.9 90.1 59.4 66.12 21.7 11.3 67.0 173 2.09 71.3 73.1 78.0 51.73 23.2 15.8 60.9 220 2.88 63.1 92.6 70.9 74.74 24.2 12.7 63.2 203 1.95 83.4 82.6 81.9 72.45 24.6 12.7 63.3 260 1.75 92.0 76.4 81.7 76.56 25.6 12.6 61.8 223 2.26 80.3 65.9 77.3 61.07 26.2 13.1 60.7 260 210 86.5 71.2 78.0 73.2 6.17 (=20% of theory based on inlet HCl)8 26.3 14.4 59.3 279 2.40 82.1 70.7 74.1 75.79 26.5 18.3 55.2 257 2.68 72.6 87.5 72.0 90.710 28.3 15.4 56.3 318 2.25 90.2 65.7 77.5 83.811 31.3 16.0 52.6 228 2.92 77.9 60.4 74.5 63.312 34.3 17.3 48.3 243 2.84 80.4 57.2 74.5 70.013 35.9 13.4 50.7 292 2.14 94.4 57.8 86.2 66.814 36.9 19.2 43.9 245 3.57 54.0 100.0 85.0 100.015 37.3 14.0 48.6 235 2.37 84.6 64.6 80.9 68.316 37.3 19.1 43.6 250 3.54 91.6 59.9 68.9 100.0 7.38 (=34% of theory based on inlet HCl)17 40.1 11.8 48.2 312 1.79 100.0 59.0 90.1 70.518 41.6 12.8 45.6 223 2.11 84.4 67.1 82.4 69.4__________________________________________________________________________
A pyrogenic silica carrier (Cabot Corp. CAB-O-SIL Grade M-5, rated at surface area of 200 sq. m./gm. and particle diameter 120 A; purity 99.8% SiO2) was impregnated in two steps, first with anhydrous CuCl2 dissolved in methanol, second with KCl and anhydrous LaCl3 in formic acid medium as follows: 1.288 gm. CuCl2 was dissolved in 55 ml. of methanol; this solution was combined with 2.0 gm. pyrogenic silica and allowed to stand overnight. The mixture was gently heated under reduced pressure to remove the methanol solvent, leaving the silica impregnated with CuCl2. Separately, 0.392 gm. of KCl was dissolved in 35 ml. of 97-98% pure formic acid and combined with 0.320 gm. LaCl3 (prepared by drying LaCl3 hydrate at 125° C.-150° C. under reduced pressure) to form a sol or sol-like liquid. Next the solid mixture of silica-CuCl2 was combined with the liquid mixture of KCl-LaCl3 -formic acid; and the resulting slurry was allowed to stand overnight after which the mixture was dried at 100° C. at gradually reduced pressure to remove excess formic acid. The solid residue was broken up and put through a 40-mesh screen. Results of using this catalyst at a series of decreasing temperatures, from 370° C. down to 324° C., are shown in Table II. It will be noted that the activity remained high at 324° C., comparable to that at 370° C.
Table II:______________________________________Use of Catalyst of Example II for OHC of Methane ResultsInlet Composition Conditions Depth(volume percent) Temp. R.T. Conv. Select. of Dea-O2CH4 HCl ° C. Sec. CH4 CH4 Chlor. con______________________________________28.1216.12 56.35 370. 2.58 96.9 70.6 89.0 84.58 365. 2.60 96.2 71.4 88.2 83.02 357. 2.63 95.5 75.1 85.4 83.87 350. 2.66 93.5 80.3 85.1 81.23 341. 2.70 92.0 82.9 84.6 81.28 332. 2.74 90.5 80.7 82.0 82.14 324. 2.78 90.2 84.8 83.7 85.84______________________________________
Essentially the procedure of Example I was employed to prepare a catalyst composed of pyrogenic anhydrous titania carrier amounting to about 80% by weight, having surface area of about 50 square meters per gram, and a cuprous chloride layer (13.6% by weight) followed by a potassium chloride (3.8%)/lanthanum chloride(3.1%) layer.
This catalyst promoted formation of chlorine by reaction of HCl and oxygen as indicated in Table III below:
Table III:__________________________________________________________________________Use of Catalyst of Example III for Deacon ReactionInletComposition Conditions Exit Composition(vol. percent) Temp. R.T. (volume percent)O2 HCl N2 ° C. Sec. O2 HCl N2 Cl2 H2 O Deacon__________________________________________________________________________19.1 76.2 4.8 382 1.93 15.1 60.2 4.8 8.0 8.0 21.022.2 73.0 4.8 372 1.96 17.1 52.5 4.8 10.3 10.3 28.119.1 76.2 4.8 362 1.99 18.8 75.1 4.8 0.5 0.5 1.419.1 76.4 4.6 352 2.02 19.1 76.4 4.6 0.0 0.0 0.0__________________________________________________________________________
Essentially the procedure of Example I was employed to prepare a catalyst of alpha-alumina carrier (66%), CuCl (22.7%), KCl (11.3%). The carrier was obtained by heating pyrogenic gamma-alumina particles (surface area found = 91 sq.m./gm.) at 900° C. for 24 hours. Surface area found for the resulting alpha-alumina carrier = 90 sq.m./gm. The pyrogenic gamma-alumina itself is operative as a carrier in our catalysts, but is less stable toward the HCl reactant than is alpha-alumina.
This catalyst employing alpha-alumina as carrier is effective for oxyhydrochlorination of methane at temperatures well below 300° C.; and when excess HCl is employed, over the stoichiometric ratio of 4:1 for conversion of the methane to CCl4, a considerable proportion of free chlorine is obtained, as shown in Table IV below.
Table IV.__________________________________________________________________________Use of Catalyst of Example IV for CombinedOxyhydrochlorination and Chlorine ProductionInlet Composition Conditions Results(volume percent) Temp. R.T. Conv. Select. Free Cl2O2 CH4 HCl ° C. Sec. CH4 CH4 Deacon (Vol. %)__________________________________________________________________________28.66 10.57 60.77 270 2.62 88.47 44.73 85.41 18.44__________________________________________________________________________
The present catalyst, especially with silica as the anhydrous pyrogenic support, is useful in general in oxyhydrochlorination of organic materials by vapor phase reaction between oxygen and hydrogen chloride; e.g. chlorination of an organic compound such as benzene and other aromatics, butanes, propane, ethane and ethylene as well as methane and partial chlorination products from the foregoing.
In oxyhydrochlorination of ethylene to ethylene dichloride, use of temperatures below 300° C., such as 225°-275° C. is known (U.S. Pat. No. 3,210,431 of Oct. 5, 1965 to W. F. Engel). The present cuprous chloride on pyrogenic silica catalyst not only operates in such reactions as low as 125° C. but also shows very high selectivity for chlorination vs. oxidation. Another special feature of OHC of ethylene with our said catalyst is that at temperatures such as 250°-275° C. both ethylene dichloride and vinyl chloride can be produced in the reaction.
Examples of OHC of ethylene are given in Table V below, using a catalyst prpared as in Example I above and generally similar conditions to those of Table I.
Table V.__________________________________________________________________________Use of Catalyst of the Invention for OHC of Ethylene Inlet Compsn. Exit CompositionRun Temp. (vol. percent) (vol. normalized to inlet N2)No. ° C. O2 C2 H4 HCl N2 O2 C2 H4 Cl2 N2 CO2 Cl2 * Deacon__________________________________________________________________________Series A1. 250 13.7 24.4 53.3 8.6 0.07 24.0 8.6 0.2 -- 1002. 223 13.7 24.1 53.6 8.6 0.11 23.5 8.6 -- -- 1003. 188 13.4 24.1 54.0 8.5 0.72 23.2 8.5 -- -- 944. 165 13.1 24.2 54.2 8.5 1.3 22.6 8.5 -- -- 875. 145 13.5 24.1 53.6 8.8 1.9 21.4 8.8 -- -- 876. 125.sup.(E) 13.9 25.9 49.4 10.8 3.8 20.9 10.8 -- -- 82Series B1. 330 15.3 7.87 68.5 8.34 0.2 7.57 8.34 0.31 14.46 862. 310 15.1 7.65 69.0 8.27 1.3 7.67 8.27 0.24 11.74 793. 290 15.1 7.67 68.9 8.28 3.7 7.67 8.28 0.0 7.46 664. 270.sup.(E) 15.1 7.67 69.0 8.20 6.5 7.65 8.20 0.0 2.10 50Series C1. 260 14.3 14.66 63.1 7.98 0.4 14.5 7.98 0.1 -- 872. 211 14.4 14.61 62.9 8.03 1.1 14.0 8.03 0.0 -- 853. 176 14.5 14.77 62.7 8.00 2.6 12.8 8.00 0.0 -- 764. 140.sup.(E) 14.3 14.59 63.2 7.94 4.7 10.3 7.94 0.0 -- 61__________________________________________________________________________ Notes .sup.(E) Temperature so marked is "extinction" temperature, i.e. lower limit for catalyst activity using the specified proportions of the inlet materials. *Some free chlorine was generally formed in the experiments of this Table V, but was determined quantitatively only in the runs of Series B.
When ethane is oxyhydrochlorinated using a catalyst prepared as in Example I, temperatures as low as the range of 125°-150° C. can be used. A level of conversion to chlorinated products of about 75-85% can be obtained in this temperature range using short residence times such as 1.5 to 3 seconds. The Deacon value under these conditions is about 80-85%. The selectivity for chlorination of ethane vs. oxidation is very high below 150° C., as indicated by absence of detectable CO2 in the products obtained under the above-mentioned conditions for OHC of ethane.
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|A method of converting an alkane to an alkyl alcohol
|U.S. Classification
|502/225, 570/224
|International Classification
|Cooperative Classification
|European Classification


text:
For a faux gingerbread cookie smoothie, you'll need almond milk, figs, ground ginger, orange juice, all spice, nutmeg, cinnamon, vanilla extract, almond butter, and kale.
Okay, Oreos aren't technically holiday-specific—but they are delicious! For this baby, you'll need vanilla flax milk, maca powder, banana, and (if you'd like) Oreos.
To say we're obsessed with this coconut milk, nutmeg, banana, cinnamon, ginger, vanilla extract, sugar, and ice smoothie with a gingerbread man on top would be an understatement.
Tell your boss you're leaving work early to make this festive coconut milk, honey, ginger, nutmeg, cinnamon, and banana smoothie. Totally excusable.
This gingerbread-peach smoothie calls for banana, nonfat Greek yogurt, almond milk, honey, flax or chia seeds, oats, vanilla, cinnamon, ground cloves, and nutmeg.
This gingerbread smoothie—made with banana, almond milk, date, chia seeds, cinnamon, mixed spice, walnuts, and ginger—tastes way better than eggnog.
We're taking a break next week, but we still want you to share your smoothies! To kick off the new year, we'll be sharing #SuperFoodSmoothies on our site. Tag @WomensHealthMag in your photos on Instagram for the chance to be featured. Just remember to include the entire recipe in your caption so our readers know how to recreate your yummy creation!
More from Women's Health:
What 9 Women's Health Editors Eat for Breakfast Each Morning
9 Cocoa Powder Smoothies Because CHOCOLATE
5 Foods You Should Eat When You're Trying to Make a Baby

subset: commoncrawl


text:
|13 Nov 2015
Microsoft Windows 7 Ultimate 64-bit 7601 Multiprocessor Free Service Pack 1
Sorry, not my area of expertise for sure. Good luck
|My System Specs
|Thread Tools
|Similar help and support threads
Can't Disable Warning msg in Word
I have a word document with a picture inserted into it. I right clicked the picture and added a hyperlink to an mpg video clip that is stored on my computer. Now, every time I click on the picture, instead of going immediately to the video clip and running it, I get this really annoying warning...
|Microsoft Office
Word 2013
Unable to add attachment as not at home. Will try to do once home but will be like 2 hours at least. Please could someone help with the below: In a word document is it possible to do the following: 1) if "no" is selected from a drop-down menu, can you add rows to a table to ask further...
|Microsoft Office
Word 2013 text boxes
Its easy to draw text box and type in it Is there a way to draw a text box around text that is already present without covering it up ?
|Microsoft Office
Updated to Office 2013 Pro: Word (Desktop) vs Word 2013
Good morning, I recently upgraded from Office 2010 Pro to Office 2013 Pro. However, after the install, all of the office products are showing as <NAME> (desktop) - i.e. Word (desktop), Powerpoint (desktop). Yet, when they are opened, the program is shown as Word 2013, Powerpoint 2013, etc. When...
|Microsoft Office
New Windows 7 computer - how do I transfer old Word to Word 2013?
I made the Easy Transfer using the ET cable yesterday. The files and setting of my old Windows 7 computer are now in my new Windows 7 computer. I have Microsoft Word 2013 on my new computer but it's empty. How can I get the documents from Word 2003 on my old computer to the new one? I also...
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Cannot type korean normally in Word 2013
Hello i got Office 2013 installed here and i can't type korean in Word (while in excel there's no problem)... 안녕 will be ㅇㅏㄴㄴㅕㅇ... Letters just won't get together, never had that problem before so i dunno how to fix..?
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365 Peaceful Days to Color
- Format: Paperback
- Copyright: 11/08/2016
- Publisher: Thunder Bay Press
Note: Not guaranteed to come with supplemental materials (access cards, study guides, lab manuals, CDs, etc.)
Extend Your Rental at Any Time
Need to keep your rental past your due date? At any time before your due date you can extend or purchase your rental through your account.
Rental Options
List Price $17.99 Save
Free Shipping On Every Order
In Stock Usually Ships in 24 Hours
You feed your body daily, but do you feed your soul? This book will encourage a peaceful existence every day of the year with a beautiful pattern to color as well as an interesting piece of trivia. National holidays, famous birth dates, unusual festivals, and days of spiritual, cultural, or historical significance are noted with an image to color in. Use this as a daily meditative practice, or just a few fun minutes to slip away and learn something new. It's the perfect book to feed a peaceful, creative mind!


text:
Oral And Maxillofacial Surgeons in South Delhi
Category : Hospitals, Clinics Posted : 25/05/2017 Price : Check with seller Location : South Delhi(Delhi)
Handlers is premium solution for all kinds of laundry care that handles your clothes with utmost care and skill. We provide Pick up Laundry Service in South Delhi at best India Prices.
Address - East of Kailash New Delhi, 110020, India
Mob. No - 8287512345
Email Id - firstname.lastname@example.com
Website - http://www.handlers.in/


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It's Monday!! Time to Work!! Noooooooooo!!! [VIDEO]
is today one of THOSE days?
is today one of THOSE days?
Message from owner"
Boo has the terrible habit of messing with the door stop to wake us up early in the morning. He doesn't do it because he's hungry, he does it because he feels lonely...
OK, maybe it wont cure your blues permanently...bet this will make ya smile!! Have a good day my friend
You may know Mike Rowe as the voice of Deadliest catch shares a letter his mom wrote! definitely will make your day!
It's tough to walk away from a get house or rental because you aren't proud of the address. After all, not everyone can write 90210 on their envelopes...
compilation of Funny Baby Videos that will certainly make your day...Makes me want to have another one....WAIT, WHAT?!...snap out of it Greg
Im pretty sure my cat does this!!!..I'm afraid, very afraid!!
Daylight Savings may cause some to be late to work this morning or jack up your appointment Here are some random facts about daylight savings time.
If guys were like girls and vice versa on Valentines Day. The tables are turned and each gender is acting like the other!
I've seen this list before. It's a very good list! a list for every woman to see! Pretty much says it all
My dog "Ueey" is such a character, and he is so busy all the time! Just has to always be doing something! He gets bored and starts wrestling with his own foot...
Thats right! its was Fathers Day, The only day of the year you can say "Your not the boss of me...I do what I want!"...enjoy This AWESOME clip Dads, This ones for you.


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Los Angeles - Arnold Schwarzenegger lost out on "millions of dollars" when he was the Governor of California.
The Last Stand actor took a seven-year break from acting to pursue his political dreams and while he loved being able to give something back to the people of America, he admits it wasn't great for him financially.
The 66-year-old Austrian said: "I always saw my movie career as ongoing. I stepped out for seven years to be Governor of California but I was never trying to be a career politician who runs for Congress and the Senate. I just felt since America has given me every opportunity to achieve in life. I should take time out to serve the people regardless of the lack of pay. I gave the money back, as a matter of fact.
"It was around $187 000 a year, which is petty cash... for me! I lost out on earning tens of millions of dollars and it also cost me - political campaigns are expensive - but none of that mattered. I wanted to help the people. It was the most educational thing I've ever done."
Schwarzenegger says he was told not to bother entering the political world because nobody would vote him in.
He said: "I was told if you run for governor you'll lose because people don't take people from show business seriously when it comes to politics... blah, blah, blah. I've heard it all with the impossible thing but I didn't pay any attention because I believed."
24.com publishes all comments posted on articles provided that they adhere to our Comments Policy. Should you wish to report a comment for editorial review, please do so by clicking the 'Report Comment' button to the right of each comment.
{{item.description}} Read More »
Cape Town Northern SuburbsCompuscan IT
GautengProfessional Career ServicesR11 999 - R12 000 Per Month
JohannesburgR700 000 - R900 000 Per Year
TownhousesR 1 295 000
HousesR 3 999 000
HousesR 1 998 000


text:
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First Time User? Enroll now.
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UNC Ear, Nose and Throat at Roanoke Rapids
215 Smith Church Road
Roanoke Rapids, NC 27870
Main: 252-535-2311
Fax: 252-535-3947
UNC REX Healthcare 4420 Lake Boone Trail Raleigh, NC 27607, USA 919-784-3100
Copyright 2017 UNC Health Care. All rights reserved.


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The Westin Leipzig
Taking a view from your hotel window will (finally) make you realize you have chosen the right hotel in the right town. Leipzig with all its sights lies right at your feet.
436 non-smoking rooms on 27 floors, including 32 newly designed and luxuriously furnished Suites and Junior Suites, and 2 rooms for disabled use. All rooms at The Westin Leipzig feature a breathtaking view over Leipzig and are equipped with air-conditioning, mini bar, telephone with voicemail, safe, SAT and pay TV, internet access and wireless LAN.
Conference facilities
The Westin Leipzig offers a congress area of 2,500 m2 and an exhibition area of 1,000 m2 – sufficient space for event ideas for up to 700 persons. The 50 function rooms and the City's largest ballroom with an area of 561 m2 features exclusive furniture and latest state-of-the-art equipment. And if you ever require an outstanding event location: The Westin Leipzig is your individual caterer with the most beautiful and breathtaking venues such as the Panometer, Media City and the Da Capo.
Apart from the Gusto Restaurant, the classical Brühl restaurant, the Japanese Yamato restaurant and the Shinto Bar & Lounge also count among the first addresses in town when it comes to culinary variety on the highest level. The real highlight, however, is at the FALCO gourmet restaurant. Cuisine passion légère by Peter Maria Schnurr – thus the noble and stylish menu presents a wide range of day-fresh and seasonal emotions.
24-hours room service, Business Center, concierge service, limousine service, hairdresser's, laundry and cleaning, 200 parking spaces or WLAN in all public areas - these are just a few examples of the services you can expect at The Westin Leipzig.
At the hotel swimming pool you can relax, take a break from everyday life and restore your body. The area houses the pool, two saunas and infrared cabins, spa and wellness treatments and a fitness offer.


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With a host of excellent packages available, including seats in the Premier Lounge, Legends Lounge and The Gallery restaurant, don't miss out on an unforgettable experience at the home of Leicester City Football Club.
Matchday Hospitality
Enjoy a first-class matchday experience at King Power Stadium with one of the Club's limited Hospitality packages for individual fixtures or for all 19 Premier League clashes throughout the season.
Fosse Club
Our Fosse Club offers members a relaxed, welcoming environment in which to soak up the pre and post-match atmosphere, surrounded by the Club's heritage hosted by an LCFC Legend.
TV Studio
Leicester City TV Studio package, available for either 12 or 16 guests is the only match by match private setting available to purchase at King Power Stadium.
Premier Lounge
Leicester City's First Class Matchday Suite accompanied with Directors Box seating.
Legends Lounge
The Legends Lounge gives the club the chance to pay homage to some of the greatest players ever to pull on City's famous blue shirt.
Banks Lounge
Leicester City's World Cup winner and England legend is honoured in this room, which has beautiful views over the River Soar.


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- Worldwide Rank #46,175,293
- Follower/Following Ratio 0.43
- Daily New Followers 0
صابرهديوة Twitter Stats
@01221468000 - Tracking صابرهديوة Twitter profile since July 20, 2014
صابرهديوة's story
صابرهديوة, also known as @01221468000 has a reasonably significant presence on Twitter and is ranked by us in the 30% percentile for account strength. Active on Twitter since May 2014, صابرهديوة made it to having a respectable 249 Twitter followers and to being ranked 46,175,293 for number of followers among all Twitter users.
Uh-oh... seems like someone has fallen asleep while on duty and is dropping in social relevance. The plot thickens when considering صابرهديوة's follower-to-following ratio, which is 0.43. This actually doesn't reflect so well on this account's strength.
Over the past month, @01221468000's was hardly active on Twitter, with an average of 0 tweet(s) per day in the past 30 days. That's pretty consistent with a total of 19 since @01221468000 joined Twitter.
This account is tracked by us Only July 2014. As of September 24 2017 we track 281010853 Twitter accounts, so feel free to search for other accounts you're interested in and reveal their Twitter story!
صابرهديوة Tweets
@01221468000 has posted 0 tweets in the last 5 days, which translates to an average of 0 tweets per day.
صابرهديوة Twitter Followers
@01221468000 has 249 followers on Twitter.
This account is #46,175,293 in the worldwide rank of the most popular Twitter users.
صابرهديوة Following on Twitter
@01221468000 is following 581 Twitter accounts.
Last month this account followed 11 users.
صابرهديوة Predictions & Milestones
@01221468000 will hit 249 followers in the next 3 months, and 249 in one year.
You are on صابرهديوة's Twitter stats page
We track these Twitter stats since July 20, 2014 . You can see how many followers صابرهديوة lost or gained and what the prediction is for tomorrow or the next 15 days, together with all kinds of other stats like rank compared to all Twitter users, tweets etc.
Why don't you give it a try and compare صابرهديوة to yourself ? Or if you are صابرهديوة get even more feature rich & up-to-date stats with our premium Twitter Stats.
Twitter Counter is the #1 Twitter stats site powered by Twitter. It all started in June 12, 2008 and we grew rather rapidly because of our Twitter Counter badge. The button is a nice small image that shows your visitors how many followers you have on Twitter. Within a year the button was on many many blogs around the world and we displayed more than 100 million buttons in one month. We track follower stats for over 281.010.853 users now.


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Gegard Mousasi announced on Monday that he would be joining Bellator MMA on a six-fight deal, ending his run with the UFC. As he made clear as a guest on "The MMA Hour" with Ariel Helwani, he was miffed by the lack of title opportunities that he received with the promotion — namely the decision for him to not challenge for the interim UFC middleweight championship.
"I thought I was ahead of him," Mousasi said of Robert Whittaker, who fought for and won the interim middleweight title at UFC 213. That's my opinion. I respect Whittaker a lot, he's a nice guy, and congratulations for winning the belt but I think if they would have called me and said, 'O.K., you're fighting for the interim belt,' it would have been more interesting to me… Those things matter."
Mousasi's final fight with the UFC came back in April when he defeated Chris Weidman by TKO at UFC 210. He further solidified himself as a top contender, only to be passed up for Whittaker, who faced perennial contender Yoel Romero for the interim title Saturday night in Las Vegas.
Mousasi debuted with the UFC in April 2013 and went on to post a 9-3 record with the company, including a five-match win streak to end his tenure. He never earned a chance at gold.
"The Dreamcatcher" now has his sights set on capturing the Bellator middleweight and light heavyweight titles, currently held by Rafael Carvalho and former UFC 205-pound contender Ryan Bader, respectively.


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Added to Shopping Bag
David Meister Gold Lame Sequin Mesh Bodice Evening Dress
Listed by Lady Madonna
Size: 8 (M)
Price: Sold for: $89.00
Final Sale (Non-Returnable)
This item is "Final Sale" and may not be returned.
If your item was misrepresented in any way, file a Misrepresentation Claim within 4 days of delivery. Our team will review your claim and you may be eligible for a full refund.
Shopping Bag :
Reserved for -:--
This Item Has Sold
Gold Lame Sequin Mesh Bodice Evening Dress
Size: 8 (M)
Sold for: $89.00 Shipping Included
Retail Price: $648.00
Get notified when it's back
Gold Lame Sequin Mesh Bodice Evening Dress
Shipping Included
Pay with Credit Card, PayPal, or Affirm.
17 people saved this item
Some embellishments may be loose or have come off. Light fabric wrinkling.
David Meister Gold Lame Sequin Mesh Bodice Evening Gown
Tag size 8
Self 100% Polyester
Lining 100% Polyester
Contrast 100% Polyester
Length 59"
Sleeve Length 3.5"
Shoulder to Shoulder 17"
Underarm to underarm 15"
Waist 13.75"
Hips 16"
*Measurements taken when garment was laid flat and un-stretched*
Boat neck with cap sleeves
Illusion neckline
Center twist
Metallic sequins
Concealed back zip closure
* Please note embellishments may come loose in the course of storage and shipping. Suggest close inspection and possible repair before wearing.
Style Tags:
Sat 9/23/17 - Tue 9/26/17 (3-6 days)
This item is Final Sale and may not be returned. We recommend taking a good look at all item details before ordering.
Final Sale items purchased in the U.S. are eligible for a full refund if the listing is misrepresented. Learn More
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Tradesy only allows the sale of authentic designer goods. If you believe your purchase is a replica, send it to our team for a free evaluation. You'll get a full refund if anything's amiss.*Learn More
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Need help? Have questions? Our team in sunny Southern California is available by phone, email, and chat.Help & Support


text:
Be Our Guest
Your first three visits are on us. The YMCA has something for everyone so we encourage you to come try us out for FREE! With our state-of-the-art fitness equipment, lap pool, group exercise classes, child care, youth sports, dance, and more...we know there is something for you at YMCA! Present our Guest Pass for THREE FREE VISITS and see everything the YMCA has to offer you.
For your safety, all guests must present a photo ID. Certain age restrictions may apply. Limit one guest pass per person, per year. GUEST PASS GOOD FOR 3-CONSECUTIVE DAYS ONLY.
If you are interested in a FREE day of fun and fitness print this guest pass and call your nearest YMCA for guest policy.
A guest must be 18 years of age or accompanied by a parent/guardian.


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Sunday, September 12, 2010
Pardon the mess!
I am switching some things around on my blog over the next few days. If something seems a little strange or it is difficult to navigate, I apologize. I hope you will enjoy my blogs new look when I am finished.
Posted by Cheryl at Sunday, September 12, 2010
3 comments:
- jaimie said...
Hi Cheryl,
Are you going to play .... with your bloglayout LOL.
Greetings, Jaimie
- September 13, 2010 at 12:20 AM
- 1CardCreator said...
I love it so far, this is so much easier to read than the green print. ~Diane
- September 13, 2010 at 9:19 AM
- Chrissy D said...
Hello Cheryl - I need to do this too! Hope you have a wonderful day! Thanks for stopping by my blog!
- September 13, 2010 at 10:28 AM
Subscribe to: Post Comments (Atom)


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Bond 77 rolls out new program servicer Down Payment Assistance for first time home buyers still available.
It took a while, however the latest news for first time home buyer down payment assistance in Texas is that the bond 77 Texas Down payment assistance program is back after transitioning to another servicing company.
If you have been waiting for funds to become available after the after the last program servicer terminated their involvement with the program you can now get a new start with the new year. You may want to hurry because program funds are low the current allotment "Lot 17" is expected to be exhausted by January 15, 2012. As always with all Texas first time home buyer down payment assistance programs this program will not receive any funds once funds are exhausted.
UPDATE: This downpayment assistance program is out of funds and was last checked Friday September 22nd. This information is accurate as of that date. Please call our office at our contact page for more information on the 100% financing programs available in your area.
Although additional funds have not been allocated to the Bond 77 down payment assistance program funds that were not used in previous allocations have been recycled and will be available with each allotment.
ARVE Error: id and provider shortcodes attributes are mandatory for old shortcodes. It is recommended to switch to new shortcodes that need only url
Bond 77 allotment 17 funds are now availabe. As noted in my previous post in an effort to lengthen the amount of time that Bond 77 Down Payment assistance is available TDHCA has slashed the amount of down payment assistance available to each buyer by 20%.
The interest rate for the TDHCA Texas down payment assistance for the new allotment #17 is only slightly lower since previous allotments even though market rates have fallen dramatically . The program is rapidly running out of money and is not expected to last much longer. To make sure you receive down payment assistance in Texas you need to have your current lender register your loan immediately and close your loan by February 15th. If you are not working with a lender that can do Texas Down Payment Assistance programs you will want to fill out our online application here and we would be delighted to assist you with your loan as soon as possible before funds are gone. As mentioned on my original post the program will not be re-funded once funds are exhausted. Based on current usage even with the reduced down payment assistance it is estimated that down payment assistance from the state of Texas will be exhausted by the early next year.
If you are already working with another lender you MUST contact them to obtain the assistance. If they cannot do bond 77 we will be happy to assist you and transfer your application to our office. You may start the process by using our online application here.
To qualify for these programs you must be able to qualify for a regular FHA Mortgage. If you cannot qualify and be approved by an approved TDHCA Lender you cannot receive the funds for bond 77. To find out if you qualify you will need to fill out our online application here or simply call our office at the number below and we will be happy to assist you.
Texas Down payment assistance Interest Rates are set in allotments or "LOT"s. Each Bond 77 "lot" is good for a maximum of 90 days. Once Funds are exhausted for a given allotment a borrower must wait for the next allotment to reserve their Texas down payment assistance funds.
Don't Forget you will need to take a HUD approved Home buyer education class to take advantage of this Texas First Time home buyer down payment assistance program.
If you have specific questions about Income Caps, Purchase price limits or other details of the program in your area call our office at the numbers below and speak to a Mortgage Banker. If you are currently working with another lender on your Bond 77 loan you must transfer your loan to our office before we may assist you.
Here are the revised details and rates for TDHCA Bond 77 Lot 17 or allotment #17
- Loan must close by 2/15/2012
- "Lot 17" expires on 1/15/2012 – all loans on this program must close by 2/15/2012. Loans that will close after that date will lose their down payment assistance.
- You can find the current interest rate for bond 77 lot 17 by calling our office
- 4% Down Payment Assistance – DPA, DPA is due on sale, Refinance or no longer occupies the primary residence (In other words, the assistance that you receive you must pay back when you sell or refinance the home during a specified time See the details here)
Future Lot Details – TBD – If their are funds available
Additional program details and qualifications here.
About Us
Get Qualified today by clicking here
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- 4 resources for those impacted by Harvey and Irma - September 15, 2017
- How do I repair storm damage not covered by my insurance ? - August 30, 2017
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text:
Kingston University has warned all staff to watch out for ...Read More »
KU women building bridges and smashing stereotypes
A Kingston University student has come up with an idea ...Read More »
Will your course at KU soon be a fast-track study? The board is 'looking into' implementing two-year degrees
Kingston University is "looking into" proposed two-year degree courses after ...Read More »
Three children on trial for murder of 19-year-old KU stab victim
Three teenagers accused of murdering KU student Hussein Ahmed by ...Read More »
When was the last time you got checked for an STI? Experts issue health warning after 80 per cent of KU students claim to never get tested
Experts have warned that Kingston students are risking their fertility after ...Read More »
KU accused of forcing staff to 'play poker with their careers' by cancelling courses and cutting jobs
Kingston University has been accused of "forcing people to play ...Read More »
From sneaky foxes to proud robins, these are the winners of KUs wildlife photography competition
Sneaky foxes run around in the streets of Kingston and ...Read More »
Rainbow laces tie KU sports teams together for LGBT history month
Shoelaces are normally boring things only there to tie a ...Read More »
Live: Follow the second Big Student Meeting here
The Union of Kingston Students will be debating and voting ...Read More »
Watch: KU student's designs showcased at first ever London Modest Fashion Week
KU law student Anosha Anwary showcased her latest collection from ...Read More »


text:
2725 Tall Trees Avenue, Portage 49024
See more homes for sale in Portage, MI
This property has been Sold!
06/16/2017 at $217,000
4 bedrooms, 3 full baths, main floor laundry, Beautiful ranch home with a full mostly finished basement. Very pretty family rec center plus a 4th bedroom and 3rd full bath. Spacious open floor plan with cathedral ceilings, nice workable kitchen with a breakfast bar to the dining area, patio doors to the private back yard.
Property Information
- Status
- Sold
- Address
- 2725 Tall Trees Avenue
- City
- Portage
- Zip
- 49024
- County
- Kalamazoo
- Township
- Portage City
- Total Finished SqFt
- 2,433
- Above Grade SqFt
- 1,433
- Garage
- 2.0
- Garage Desc.
- 2, Attached
- Water
- Public
- Sewer
- Public
- Year Built
- 1999
- Taxes
- $3,100
Rooms and Land
- Basement
- Full Basement, Other
- Cooling
- Central
- Heating
- Forced Air, Natural Gas
- Acreage
- 0.25
- Lot Dimensions
- 80 x 135
- Appliances
- Dishwasher, Microwave, Range, Refrigerator
- Exterior Materials
- Brick, Vinyl
Listing Video for 2725 Tall Trees Avenue, Portage MI 49024
Mortgage Calculator
Listing Broker
Listing Courtesy of Century 21 C. Howard
Office Address 1522 Gull Road
Listing Agent David Howard
Listings last updated: . Some properties that appear for sale on this web site may subsequently have been sold and may no longer be available.
Our Michigan real estate agents can answer all of your questions about 2725 Tall Trees Avenue, Portage MI 49024. Real Estate One, Max Broock Realtors, and J&J Realtors are part of the Real Estate One Family of Companies and dominate the Portage, Michigan real estate market. To sell or buy a home in Portage, Michigan, contact our real estate agents as we know the Portage, Michigan real estate market better than anyone with over 100 years of experience in Portage, Michigan real estate for sale.
The data relating to real estate for sale on this web site appears in part from the IDX programs of our Multiple Listing Services. Real Estate listings held by brokerage firms other than Real Estate One includes the name and address of the listing broker where available.
IDX information is provided exclusively for consumers personal, non-commercial use and may not be used for any purpose other than to identify prospective properties consumers may be interested in purchasing.
All information deemed materially reliable but not guaranteed. Interested parties are encouraged to verify all information. Copyright© 2017 MichRIC LLC, All rights reserved.


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A relaxing adventure through a dystopian city bursting with life
Submerged is a third-person, combat-free game in which you explore a derelict city after an apocalyptic event flooded the world. You take on the role of Miku, a young girl forced to care for her injured brother after bringing him to the city in their small fishing boat. Navigating the flooded city streets by boat, the core gameplay revolves around scaling the submerged buildings, whilst utilising your telescope to scout the environment for the supplies needed to save the only family you have left. In search of this goal, you explore this strange city, as you encounter an ecosystem of life that has flourished in this colourful new world.
Produced by a small indie developer, Uppercut Games, Submerged thrusts you into an enchantingly desolate world that yearns to be explored. One thing that instantly stands out here is the beautiful art style and animation, which perfectly captures the wonderment of exploring an abandoned cityscape. As you explore you begin to encounter the drowned city's diverse and strange creatures. Giant whales breach the water shaking the small boat you use to explore. Dolphins leap out from the depths twisting through the air, whilst strange, human-like creatures watch you from afar. This odd ecosystem is crowned by a dynamic weather system that depicts a planet still in turmoil, not yet recovered from the apocalyptic event that created it.
Graphically, Submerged isn't exactly pushing the envelope, but it's obvious that graphical fidelity wasn't the goal here. What the game does have is a very unique art style that portrays the sunken city you explore through bright colours interspersed by the stark silhouette of skyscrapers jutting from the dark depths below. The accompanying score, composed by Jeff van Dyck, is atmospheric, yet tense when it needs to be. Although it seems overall the music was intended to offer relaxing melodies to which you can lie back and explore at your own pace.
Submerged map is sizable and encourages exploration, a lot of which is done on a vertical plane. Uppercut Games did a great job of making the city feel bigger than it is, it doesn't feel restrictive in its boundaries. There are no solid, invisible walls that block your path or horizon cut-offs, the sea seems to stretch on forever. When you eventually reach the edge of the map you not greeted by a hard thud, but a gentle redirection back towards the accessible part of the city. This simple design choice makes the city feel expansive and gives the player the impression they are not locked within a zoned off space.
Washing ashore with your wounded brother in a small fishing boat, Submerged is a story that revolves around relationships. As Miku, you scour the ruins looking for the supplies to heal your sibling, as their tragic backstory is revealed through a series of unlockable pictures. Haunted by strange creatures, known as Remnants, Miku scales the drowned buildings trying to understand the intention of these human-like entities. As you progress through the game you will discover hidden objects that piece together the story of a broken world and a broken family. At its heart, Submerged centres on the relationship between Miku and her Brother and what she's willing to do to ensure they survive.
One of the first things you may notice about the gameplay in Submerged is that there is no combat. The gameplay has a somewhat minimalist quality to it, with the focus on climbing mechanics, similar to games such as Prince of Persia. Exploration is key as you scout out supplies with your telescope, use your boat to get to reach the location and then scale the half sunken cityscape to reach your prize. The game features hardly any dialogue, with meaning often relayed through pictures and musical tone. This offers players a relaxed pace where they can explore the city as they see fit without the ever present challenge of combat. This more linear approach to gameplay does begin to cause feelings of repetition the further into the story you get, but the overall narrative is interesting enough to keep you progressing.
Overall Submerged is an interesting and compelling game with a strong narrative focus and minimalist gameplay mechanics. The lack of dialogue gives the player the room to utilise their imaginations when confronted with the game's more vague plotlines. Its greatest feature though is also its only downfall, as the lack of dialogue creates a lack of depth that sometimes leaves the game feeling slightly hollow as a whole experience.
*Transparency: The opinions in this review were formed off the basis of a review copy played on Xbox One.


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06_Smart Communications
How can a wireless carrier grow if most of its subscribers earn only $6 a day or less, and use their mobiles only for text messaging? For Smart Communications, the Philippines's top carrier, the answer was an all-digital "telecom in a sachet": Some 800,000 retailers buy text-messaging airtime in bulk from Smart and resell it (also via text message) in micro-denominations of as little as 50 cents per packet. The result: Smart's 22 million customers get anytime service at a price they can afford. Smart's retailers (typically, neighborhood-store owners) get a "logisticsless" product that doesn't add inventory and delivers 15% margins. And Smart, unlike Western companies, gets paid before it delivers $80 million worth of "e-loads" monthly. Smart, indeed.FCS


text: I have a Cerwin Vega Vega124 just sitting here, waiting for a home. I was thinking with it's power handling, it would be awesome as my home theater sub. However, I've read a few posts that naysay such things for various reasons. Either the sub hasn't got the right T/S parameters, or it was just designed for an ultra-small listening area(such as a car, perhaps!). I was wondering if maybe this driver in particular was versatile enough to be used in both home and auto applications. Here are the specs: FS: 26Hz Qms: 4.31 Vas: 2.85 cu.ft Xmax: .75in Sd: 83.48 sq.in Qes: .358 Re: 3.3 ohms Z: 4 ohms Pe: 400 Qts: .33 1-W SPL: 94 dB 2.83-V SPL: 96 I could use a box 20"h x 16"w x 14"d with a 2" port 4" long. An f3 of 35Hz is respectable, isn't it?


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Part Qualified Accountant
- Recruiter
- Howett Thorpe
- Location
- Farnham
- Salary
- 24000.0000
- Posted
- 14 May 2017
- Closes
- 13 Jun 2017
- Sector
- Accountancy
- Contract Type
- Permanent
- Hours
- Full Time
Established Professional Services Firm require an ambitious Part Qualified Accountant for a diverse role with Progression.
Reference: HT13588
About The Role
Based in Modern offices and working as part of the team this role will entail:
- Statutory Accounts Production
- Company secretarial and company start up work
- Assisting with Tax and VAT computations
- Assisting with Management Accounts and Payroll
- Ad hoc Project work to support senior team members.
About Our Client
- Established Professional Services organisation based in modern offices, with parking.
- Able to support AAT/ACCA studies.
- Flexible working hours.
About You
- You will be either part or qualified AAT, part qualified ACCA or qualified by experience.
- You will have recent exposure to work within a UK based Accountancy Firm, Business Services Organisation or Outsourcing company.
- Whilst you may not have experience of all the duties in this role you will be seeing to secure a diverse role and be keen to develop your knowledge.
Howett Thorpe recruit for roles within accounts payable, credit control, payroll also covering accounts assistants, audit, management accounts, financial accounts, analysts, financial controllers, financial directors, corporate finance, tax including all part qualified and qualified vacancies.
Howett Thorpe are acting as a recruitment agency in relation to this role and comply with all relevant UK legislation and do not discriminate on any protected characteristics. Due to the high volume of applications we currently receive, we are unable to respond to all candidates. If you do not hear from a Consultant within 5 working days please assume that you have not been successful.
Refer a friend
If this job is not of interest to you, but you know a friend or colleague who may be interested, recommend them to us and receive a minimum of £150 in vouchers if we assist them in securing a permanent role and a minimum of £25 in vouchers if we place them in a temporary assignment. (Terms & conditions apply)


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NeoGeo Games
This page contains Cheats for Aero Fighters 2 organized by sections for NeoGeo. This game has "Action Shooter" as genre, made by Video System. If you can't find a hint or secret in our list, then please check this page periodically for the latest updates.
Boxshot & Details
- Developer: Video System
- Publisher: Video System
- Genre: Action Shooter
- Release: Not Set
- ESRB: Not Set
Submit Cheats
If you know cheat codes, secrets, hints, glitches or other level guides for this game that can help others leveling up, then please Submit your Cheats and share your insights and experience with other gamers.
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Software • Safe • Reliable
"We are a web agency based in Germany and working together with Milo Solutions for a couple of month now.The communication with their designers, developers and PM's is excellent - which is very important when working remote.We are overall really happy also with the quality of work and will do more projects with them".Nico Nagel Founder / CEO, Winning Solutions
Our project wasn't well defined and there were some minor issues during the development. These were dealt with quickly and professionally and we were very pleased with the final outcome. We will certainly be using them again in the near future.Kevin Mulherin
MILO is a great team to work with. From start to finish they provided us with quality work, instant problem solving, day to day communication and they responded to our requests every time. Our tasks where done on time and budget and communication was flawless. I highly recommend this team!Wavecon GmbH, Cemil Degirmenci - Board Member
Project Wavecon, Rackonauts
Looking for a job? Click here & check our offers
Research & Development, Careers
Nałęczowska 36c
20-701 Lublin
Research & Development, Sales, HQ
Aleja Bohaterów Września 3/75
02-389 Warsaw
Research & Development
Opening soon...


text:
About this Business
- HoursSunClosedMon-Sat9:00 AM - 5:00 PM
From Our Editors
Book a full day of glamorous salon treatments and enjoy getting primped and polished at Los Gatos's Emerge Beauty. This salon's facial service will leave your skin feeling refreshed and healthy. Want silky smooth skin? Clean up your pores with a skin treatment from this salon. Emerge Beauty's master stylists are trained in beauty services like make up application, and they're ready to help you look your best. Offering extreme privacy, Emerge Beauty provides every guest with discreet hair removal services. Be sure to call ahead ? this salon is strictly by-appointment. The amenities here may be worth a million bucks, but the prices are rather reasonable. If you prefer to pay by credit card, you're in luck. This establishment accepts all major credit cards. Parking is easy at Emerge Beauty, especially those looking to park on the street or in a lot close by. A day at Emerge Beauty will be so relaxing you'll wish you could come every day, so why not book an appointment (or two) today?


text:
Remove Moles Naturally - Key Secrets to Remove Your Moles
With the right guidance you can get rid of warts creams. It is perfectly safe and easy to make, you need a few simple materials such as castor oil, aloe, vitamins and herbs to start, just to name a few. You can get within a week of moths without scarring or painless. And the best thing that you do not have to worry about harmful side effects!
Sometimes the chemicals used to get rid of moles in the skin can make us sick, not to mention the scars. Now a day people will look for alternatives to surgery, and who can blame them, expensive scars and you can follow for life. The whole concept of moles, get rid of getting rid of physical evidence, the skin is not a surprise to people less scarring. You can start today, and to remove moles naturally yourself, you'll be glad to get rid of moles.
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NEW YORK – Martha Stewart Living Omnimedia (MSO) on Thursday posted a better-than-expected quarterly profit but said advertising sales continue to suffer amid the legal woes of its founder.
The media and merchandising company said Martha Stewart's (search) obstruction of justice trial slammed advertising revenue and the company projected a loss for the current quarter. Shares were down 3 percent in early see-saw trading.
Martha Stewart Living said it has "prepared for the various possible outcomes" of Stewart's criminal trial. Jury deliberations in the case began on Wednesday.
In a statement, Chief Executive Sharon Patrick said fourth-quarter results exceeded expectations but "we continued to feel the negative impact of the events surrounding Martha Stewart's personal legal situation."
Net profit totaled $4.6 million, or 9 cents a share, reversing a year-earlier loss of $2 million, or 4 cents a share. Revenue slipped to $70.9 million from $77.6 million in the prior-year quarter.
The company said it expects a loss of 20 cents a share for the current first quarter, hurt by advertising declines. Last year the flagship Martha Stewart Living magazine (search) saw ad pages drop 35 percent.
Analysts' average forecast for the first quarter is a loss of 12 cents a share loss, according to two analysts surveyed by Reuters Research, a unit of Reuters Group Plc.
Martha Stewart, who transformed a catering business into a media empire, is accused of lying to investigators probing a suspicious sale of shares of drugmaker ImClone Systems Inc. (IMCL). She has pleaded innocent.
Her company has not been accused of any crimes. But analysts say its future could hinge on the outcome of the trial because the business is so closely tied to her personal reputation.
Fourth-quarter operating profit was 10 cents a share. That exceeded analysts' average target of 6 cents a share, according to research firm Reuters Research.
The company posted an operating loss of 3 cents a share a year earlier. Excluding a special restructuring charge, it recorded a profit of 6 cents a share.
For the full year 2003, the company lost 4 cents a share on an operating basis, its first annual loss since going public in 1999. But it said its financial position remains strong with $169 million in cash and no debt on its balance sheet.
The company faces a lawsuit from retail partner Kmart Holdings Corp. over disputed royalties Kmart says it is owed. Martha Stewart Living said it plans to fight the suit and enforce the terms of its deal with Kmart.
It said it excluded $3.3 million in disputed royalties from fourth-quarter results because of the litigation.
Overall, quarterly merchandising revenue climbed, helped by sales of holiday products sold at Kmart stores and a new furniture line.
The company's stock has climbed this year on apparent optimism about the possible outcome of Stewart's trial. The shares are up about 40 percent since the beginning of 2003.


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National & World Ag News Headlines
U.S. Milk Production Up During First Quarter of 2017
USAgNet - 04/21/2017
Milk production in the United States during the January through March quarter totaled 53.5 billion pounds, up 1.0 percent from the same time period a year earlier.
The average number of milk cows in the country during the first quarter was 9.37 million head, which is about 25,000 head more than the fourth quarter of 2016 and 57,000 head more than the same period last year.
As of March, California continues to have the highest total production with about 3.5 billion pounds, but was one of just five states that had lower production compared to last year. Texas had the greatest increase in year-to-year output as that state produced 1.06 billion pounds of milk in March, up 16.4 percent from the same month last year.
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Other National Headlines
Bayer Now Expects Monsanto Deal to Close in Early 2018
Russia to Supply Major Wheat Shipment to Venezuela
August Milk Production Grew 2 Percent From 2016
Deere to Open Artificial Intelligence Lab in California
NCGA Yield Contest Entry Forms Now Online
Drought Plagues Sunflower Crop Quality in the Dakotas
Time is RIPE to Transform Agriculture and Feed the World
Copyright © 2017 - USAgNet.com. All Rights Reserved.


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Location: Germany > Baden-Wurttemberg > Grossbettlingen
Ranked #2 of 2 Hotels in Grossbettlinge...
Price Range: $82 - $123 (Based on Average Rates for a Standard Room)
- Reservation Options:
- TripAdvisor is proud to partner with Hotel.de and HRS so you can book your Hotel Restaurant Bauer reservations with confidence. We help millions of travelers each month to find the perfect hotel for both vacation and business trips, always with the best discounts and special offers.
- Also Known As:
- Hotel Restaurant Bauer Germany/Grossbettlingen


text:
Website Océ Display Graphics Systems Inc., A Canon Company
Working at Océ | Join great minds, enjoy great moments
Océ Display Graphics Systems Inc., a business group of Océ, a Canon Company, located in Richmond, BC, develops and manufactures cutting edge digital printing solutions for the fast growing wide format visual communications market. Our inkjet printers produce the brilliant colour images you see on billboards, banners and posters, creating a significant impact on the advertising and promotional industry.
At Océ, we are creating things you have never seen before. We invent and accelerate game-changing technologies for printing. We have a long history of innovations to prove it. Innovations applied in document management, business processes, graphic arts, industrial printing and even fine art preservation.
In the future, anything that can be printed will be printed. We are welcoming team playing pioneers that want to turn this vision into reality – from the world of print, to printing the world. Passionate people like you that make the extraordinary happen. You'll work together across the globe and throughout the value chain, from invention to manufacturing to delivery. You'll grow your talents, celebrate results and feel valued.
Develop your career at Océ. And help us change the game of printing.
We invite you to check us out at www.ocecareers.com
Do you want to accelerate our global Quality Assurance activities?
We seek a component parts focused Supplier Quality Engineer (SQE), with a mechanical engineering background, to join our Quality Assurance team in the Manufacturing and Logistics department. SQEs partner closely with Manufacturing Engineers, Purchasers and Suppliers to ensure robust processes are in place to meet quality and delivery objectives. Specifically, SQEs work jointly with new product introduction teams in the supplier selection process from an audit, technical and quality standpoint to ensure that designed parts can be consistently manufactured to engineering drawing requirements and to acceptable quality standards. This role will support mechanical supplier quality. This role reports directly to the Team Manager, Quality Assurance.
As a Supplier Quality Engineer you will…
- Troubleshoot and conduct root cause analysis and implement corrective actions to resolve mechanical parts quality issues
- Travel to suppliers and lead the creation and development of part quality plans and to perform supplier performance reviews and audits
- Liaise with purchasing and suppliers to evaluate and vet suppliers for technology, quality processes, capacity and accuracy
- Create supplier quality performance tracking and charting
- Recommend appropriate test equipment and procedures for mechanical parts and assemblies verification
- Partner with R&D to provide input on product design from proof of concept to assure manufacturability through to commercialization and reduce number of component quality issues up front
- Sign off on all early supplier involvement (ESIs), process documents
- Manipulate drawings using Solid Works, create ECR's and troubleshoot to problem resolution
- Provide technical input to and attend MRB (Material Review Board)
Key skills and qualifications you bring…
- BSc in Mechanical Engineering or equivalent degree
- Possess 7+ years progressive experience in mechanical engineering in high tech/fast tech manufacturing environment
- Competent in the use of GD&T and proficient in machining
- Proven track record of innovation, process improvement and demonstrated knowledge of design for manufacturability
- Part manufacturing knowledge as it relates to mechanical parts and assemblies
- Ability to troubleshoot mechanical component part failures using standard tooling and measuring equipment
- Full understanding of Quality Tools (six sigma. Fishbone, part quality plans) and procedures
- Ability to travel up to 25% globally
- Proficiency in the use of MS Office, spreadsheet applications and databases
Key competencies you bring …
- Excellent English communication skills, both written and verbal
- Top-notch interpersonal and teamwork skills with strong customer service orientation
- Superior analytical and problem solving skills
- Able to work effectively with minimal supervision or as part of a multi-disciplinary team
- Sound ability to prioritize issues and manage and drive multiple, competing tasks in fast paced, dynamic environment
- Detail oriented, procedural in work flow, aptitude for accuracy
- Possess a strong can do attitude and take hands on approach to deliver superior results
Please apply through our website at http://ocecareers.com/
We thank all applicants for their interest; however, please note that only those candidates under consideration and who are legally entitled to work in Canada will be contacted. No phone calls please.
To apply for this job please visit the following URL: http://www.ocecareers.com →


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Compare Apollo Aspire and Bridgestone B290
- Variant Name
- Models Supported2 Models Supported1 Model Supported
Related Cars using Aspire 205/40 R17 84W Tubeless
Related Cars using B290 135/70 R12 65T Tubeless
- HandlingThis feature explains how good this tyre is in term of handling & response.4/54.7/5
- Fuel SavingThis feature explains how much this tyre helps in improving vehicle fuel efficency.4.4/54.5/5
- Wet GripThis feature explains performance and control in wet road conditions.4.2/54.5/5
- Ride ComfortThis feature explains how smooth and comfortable ride this tyre delivers.4.1/54.8/5
- DurabilityThis feature provides an indication of tyre wear and tyre life4.6/54.6/5
- Reviews & Rating1 Review1 Review
Reviews for Aspire 205/40 R17 84W TubelessWrite a Review
- By Shekhar Posted on 09-03-2015 11:27:544.3
It is no doubt that the world's best tyres are built on pure quality, and this fine product has the privilege of adding to that list. It aids its vehicle with firm grip, and the capacity to weather any road condition. A top notch braking capacity crosses barriers with this tyre, and takes it sailing on smooth and effortless drive. Long life and durability seal the radial's benefits for the long run. The car wearing this tyre is assured a balanced and smooth drive. In addition to all this, the radial grants it a better fuel efficiency. The low noise emissions further wraps up the entire drive experience, filling the drive with quiet and comfort.
Reviews for B290 135/70 R12 65T TubelessWrite a Review
Speed Rating (kmph)This indicates the maximum speed ( in kmph ) for the tyre when the vehicle is at full load.270190Load Rating (Kg)Which corresponds to maximum weight ( In kilogram) a tyre can carry at full speed.500290Width (mm)205135Aspect Ratio (%)t is the ratio of the sidewall height's to the cross section width.4070Rim Size (Inches)This stands for the diameter of the wheel that the tyre is designed to fit.1712Construction TypeR stands for radial-ply construction. B stands for bias ply.RRWarranty (Year)5 Years6 Years
- By Disha Posted on 05-03-2015 17:50:084.6
B290 is a tyre offered by the renowned company named Bridgestone, which is suitable for passenger cars. It is designed mainly for the Indian market and comes in several sizes. It is a perfect match for vehicles like Fiat Linea, Ford Fiesta, Chevrolet Spark, Honda Amaze, Hyundai Elantra and a few others. This model provides utmost grip on both wet and dry road conditions, while preventing the risk of hydroplaning. It offers a better contact area, which is the part that touches the ground. On the whole, this tyre is undoubtedly a right choice that ensures outstanding performance besides giving a smooth ride.


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Editor's choice critique posted!Jun. 30th, 2008 05:06 pm
Newsletter's not out, but the critique has been posted. I'm going to have to read it a few more times, but I was a little flattered by the first paragraph where John Klima says he's been close to choosing one one my chapters for some time, and that "there's something irrisistable about the world she's created and the people who populate it." Before he happily picks it apart. But the important things; I was surprised he didn't say much about the ceremony other than commenting on a lack of clarity. And it's a chapter with a lot of character development and it sounds like he liked that. Most of the improvements he suggested were fairly simple things, and relatively cosmetic. And I had to laugh at one of his last lines, summing up the whole thing, "Morgan is defining and building her relationship with Justin, which will undoubtedly become a great source of potential conflict and tragedy." He obviously sees what everybody else does; it's too good to last.


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Well worth the purchase
By Shannon
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Comments about Corral Boots Corral Black-Gold Embroidery Boots:
Love them!!!
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Godetevi il comfort del Monte Merino Manor, un elegante bed and Breakfast in un ambiente privato del paese. In auto attraverso i pilastri di pietra e l'azionamento albero-baldacchino di sperimentare un senso della storia. Un vicino a Olana State Historic Site e minuti di Hudson, questo maniero fu costruito nel 1870 da medico privato della Chiesa di Frederick, Dr. Gustavo A. Sabine. Attualmente a casa a sette lusso camere, molte con caminetti, vasche idromassaggio e docce termali walk-in, questo bed and breakfast è ideale per una fuga romantica. Sperimentare un squisita tramonto dal portico avvolgente, passeggiare intorno il loto per la dolce melodia di rane albero o solo rilassarsi in una vasca idromassaggio e stendersi al chiaro di luna.
4,8 su settembre 04, 2012
Mount Merino Manor is an absolute MUST if you're staying in the Hudson Valley. The innkeepers have put so much thought into the character and charming details of each room. Exquisite! The grounds are absolutely beautiful. The service is unparalleled...the on-site manager, Wendy, really goes out of her way to help patrons AND she's a wonderful cook. Very highly recommended.
5 su settembre 13, 2010
Patrick and Rita have put together the dreamiest Bed and Breakfast. They have taken advantage of their experiences in design and management, as well as their travels and stays in B&Bs, and combined them with a beautifully restored 1800's home on 100 acres in Hudson, NY. If you have never stayed in a B&B, Mount Merino will spoil you from here on out- your comparison bar will be forever heightened if you have stayed in others. It is elegantly decorated, gorgeously restored, and yet all of the modern amenities and comforts are included. There is no clutter, no kitsch, no DUST, no silk plants! The rooms are large (even the smallest) and the bathrooms are fabulous. The views of the nearby Catskill Mountains from some rooms are fantastic. Nearby is the adorable town of Hudson with plenty of good restaurants and boutique shopping. If you want more, it's not too far from other great towns along the Hudson River. What could be bad?
5 su giugno 01, 2009
We completely enjoyed our short stay at the Manor. The room was very clean and comfortable. The house has the charm of yesteryear but up to date to satisfy the luxury traveler. Stay for the delicious full breakfast! We'll be back.
5 su maggio 07, 2009
We truly enjoyed our stay at Mount Merino Manor. The house is elegant and uncluttered. It is on a large property which gives the house a certain majesty, yet it also felt simultaneously cozy. Perhaps that was also because of the warmth and friendliness of the inn keepers, a young couple. There is considerable attention to detail - The water pressure in the spa shower was fantastic, like a hot waterfall on my head. The linens and towels were very luxurious. Over the two mornings we ate homemade muffins and breads, baked zucchini omelet, French toast, bacon, sausage, fruit and yogurt. All was delicious! It is the best place to stay if you are visiting Olana (like we did) and it is only a few miles down the road from the towns of Hudson and Catskill.
A large one-room suite with a king sleigh bed and two sitting areas. A wall of picture windows with beautiful views of the Hudson River and the Catskill Mountians. Luxury bath with a deep two-person soaking tub and a walk-in spa shower.
Satin draped suite with Queen Bed. Separate sitting room with fainting couch. Private bath with two-person whirlpool tub and large walk-in spa shower
A grand two room suite. Satin draped bedroom with a Queen bed. Spacious sitting room with a decorative fireplace. Private entrance and private deck with sitting area. Luxury private bath with whirlpool tub and a walk-in shower. ADA compliant (handicap accessible)
A grand one-room suite with a Victorian-style king bed, decorative fireplace and views of the Catskill mountains. Luxury bath with two-person whirlpool tub and walk-in shower.
A ligh-filled bedroom with a Queen bed made of cherry and maple inlay. Sitting area with decorative fireplace. Overlooks the sweeping front lawn. Private bath with antique slipper tub and a large walk-in spa shower.
Charming room with Queen bed. Sitting area, decorative fireplace and nature views. Private bath with shower.
Morracan-style room with a Queen bed and private bath with spa-shower, sitting area with a beautiful view of the Catskill Mountains and Hudson River.
Albany, NY (ALB-Albany County) 50 miles
Da New York / sud · Rte 87 nord uscita 21 dopo il casello marca a sinistra verso Oriente 23 Rte · seguire Rte 23 est Rip Van Winkle Bridge · all'intersezione di 23 Rte e Rte 9 G, stay on 23 Rte. L'ingresso al Monte Merino maniero è la prima a sinistra su 23 Rte dopo l'intersezione tra 9 e 23 G - OR- · Taconic Parkway nord uscita 82 Rte (Hudson) · dopo l'uscita fare proprio sulla Rte Nord 82 · North 82 Rte diventa Rte 23 West / Rte Nord 9 a 4 vie semaforo · procedi dritto al semaforo successivo Rte 23 West segni · Mount Merino Manor ingresso sarà a destra dopo il secondo ingresso alla Columbia Greene Community College
Shopping Antiquariato, Gallerie d'arte, Concerti, Cene da gourmet, Interessi Storici, Lago, Musica dal vivo, Cinema, Musei, Parchi Nazionali/Statali, Zona Naturale, Punti vendita, Teatro, Area Picnic, Servizi religiosi, Fiume, Rodeo, Zona sciistica, Azienda vinicola
Bed and Breakfast, Historic Inn
Noleggio bici, Piste ciclabili, Osservazione Uccelli, Nautica, Canottaggio, Piste da sci attraverso la campagna, Sci in discesa, Pesca, Golf, Escursioni, Cavallo, Caccia, Kayak, Mountain Bike, Regate, Shopping, Scenari, Noleggio sci, Noleggio ciaspole, Ciaspolate , Nuoto, Sport acquatici , Rafting sulle onde
Rita Birmingham
As we pulled up the winding drive, it was love at first site, a stately Victorian. Clean lines, good bones, seven fireplaces, crazy views of the mountains, the river, the Rip Van Winkle Bridge, what's not to love ? Strolling through her light filled rooms, we realized this gracious home wanted to be an Inn.


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text: Summer has begun which means the outdoor work of the Friends sculpture care program is in swing. Mr. Hale (pictured) in the Public Garden is one of eight pieces conservators are caring for this year as part of the Friends Sculpture Care Program. Another 10 pieces of public art are in the process of being cleaned and maintained. This work is not only necessary, it is also newsworthy. The Boston Globe recently ran a piece about the behind-the-scenes efforts involved in caring for these historic works of art in the article, "They get the gunk off Boston's outdoor treasures."


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Tag Archives: Bounty Hunters
Attorneys for victim's family file lawsuit against bondsmen, bounty hunters
Attorneys for victim's family file lawsuit against bondsmen, bounty hunters Continue reading
Inside The Dangerous Underground World Of Bounty Hunters And Bail Bondsmen | Business InsiderInside The Dangerous Underground World Of Bounty Hunters And Bail Bondsmen
Inside The Dangerous Underground World Of Bounty Hunters And Bail Bondsmen | Business Insiderhttp://www.businessinsider.com.au/photos-underground-world-of-bounty-hunters-and-bail-bondsmen-2014-9Several years ago, Italian photographer Clara Vannucci was hanging out in a bar in TriBeCa, New York when she met a burly, Greek man name Bobby Zouvelos. … Continue reading
Posted in Fugitive Recovery News Tagged bail bondsmen, Bounty Hunters, dangerous underground world Leave a comment
Bounty hunters under scrutiny by Nampa woman
Bounty hunters under scrutiny by Nampa womanhttp://www.ktvb.com/story/news/local/2014/08/28/bounty-hunters-under-attack-by-nampa-woman/14764831/NAMPA — A Nampa woman has brought a complaint against a local bail bonds company alleging that bounty hunters used too much force when they brought in her brother.
Virginia Sheriff Claims Bounty Hunters Violate the Law
Sheriff: Bounty hunters violate law | WAVY.com | Portsmouth, Va.http://www.wavy.com/dpp/news/local_news/portsmouth/sheriff-bounty-hunters-violate-law A local sheriff told WAVY.com the high-risk tactics used by bounty hunters are overly aggressive and against the law.
Bounty Hunter's in Arizona
Posted in Fugitive Recovery, Fugitive Recovery Training and Information, Fugitive Recovery Training Videos, General Bail Bond / Fugitive Recovery Info (Uncategorized), Videos Tagged Apprehending a Fugitive, Arizona, az, bounty hunter, Bounty Hunters, Bounty hunting, fugitive recovery, Fugitive Recovery Agent Leave a comment
California Bail Bondsmen and Bounty Hunters
For many people, the term "bounty hunter" evokes images from Wild West movies where deputized citizens were given legal authority to bring back wanted individuals "dead or alive" in return for a "handsome reward". Worse yet, is the image portrayed … Continue reading
What is a Bounty Hunter?
What is a bounty hunter? A bounty hunter is a person that works with a bail bondsman to apprehend a subject that has failed to appear to a court date after having posted bail for a pending trial. When an … Continue reading