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Anoka-Ramsey nursing department ranking
Think about what career is best suited for you, and where you want to study. Request more information now.
Think about what career is best suited for you, and where you want to study. Request more information now.
Think about what career is best suited for you, and where you want to study. Request more information now.
Get info about Anoka-Ramsey nursing department ranking, and registering for additional elective sections. Which college degrees give you the best chances of finding employment after graduation? Seek out accredited nursing programs for the best training. Given a brief hospital internship or prior work experience, you can expect a great return on your medical education. Concentrating on Anoka-Ramsey nursing department ranking, for example, you may gain an advantage in job recruiting on-campus. Check with the RN department for course registration deadlines, and registered nurse program requirements. Please use the form above to request admissions info for Anoka-Ramsey.
To become a Registered Nurse(RN), you will be required to take courses in medical terminology, patient care and life sciences. Although associate degree programs provide students with adequate nursing training, a bachelor's degree provides greater clinical exposure and a stronger general education. A 4-year BSN program allows students to study specialized areas of nursing, including pediatrics, geriatrics and mental health nursing. An RN has to cope with more responsibility, and must oversee the work of LPNs and CNAs under their supervision. If you wish to continue advancement, a masters degree and several years of experience as a nurse, may qualify you for the Nurse Practitioner (NP) credential. Nursing job openings are projected to grow 16 percent over the coming decade, much faster than the average for all occupations. The average salary for nurses with an Associates degree was $43,700 in 2017, while nurses with a Bachelors degree earned $67,490 per year.
Certification requirements include board certification by the American Nurses Credentialing Center (ANCC) and the American Academy of Nurse Practitioners (AANP). The license period varies by individual state, but is usually valid for either two or three years, at which time you'll need to renew. Registered nurses (RNs) are not required to be certified in a particular specialty by state law. For example, it isn't necessary to be a Certified Medical-Surgical Registered Nurse (CMSRN) to work on a hospital Medical-Surgical (MedSurg) floor, and most MedSurg nurses are not CMSRNs. To keep your license current, you must take continuing education courses, and renew your license every few years. There are a fixed number of credits that each state requires, and if you work in a hospital facility, these courses may be offered on-site. Beyond major requirements within the RN department, you may consider West Virginia State University research labs as a complementary elective to your primary course of study.
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Interact positively with marketing, nursing, and various other departments to stimulate the overall growth of the community..
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From Billboard:
SAN FRANCISCO–Deadmau5 says EDM is not an acronym for electronic dance music. It's for "event-driven marketing."
As DJ shows rake in more money, they're also becoming less about the music, said the 31-year-old Canadian, whose real name is Joel Zimmerman.
"A popular DJ is now heralded more for his production than his music selection," said Zimmerman in a wide-ranging discussion with Billboard editorial director Bill Werde on Friday at the FutureSound conference at Terra in San Francisco.
Appearing without his trademark mouse head, Zimmerman said the EDM business was, for DJs like himself, "minimum work for maximum profit."
But he slammed a Forbes article published August on "The World's Highest Paid DJ's," in which he was listed at No. 6 with a reported $11.5 million in annual earnings, a figure that he argued was inaccurate.
"After I saw the article, I called my manger and said, 'Yo, what the f—? I'm $9 million short, dude. We gotta talk,'" Zimmerman joked. "Nobody is making that kind of profit."
Continue reading the rest of the story on Billboard

subset: commoncrawl


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|Article: Print
|Article: Electronic
Understanding oneself, others, and our interconnectedness in a truly global society can be somewhat difficult. Community-based education allows for the exploration of this phenomenon. Within the United States teacher education programs normally have incorporated community-based learning through placing students in local schools. However, how might an individual's global perspective on science education and society change if that community is within another culture? This paper will discuss one such model that allows students to enhance their critical thinking skills through reflecting, synthesizing, and analyzing their experience abroad in a rural school setting. They will learn first-hand how environmental and science education is being implemented in a developing nation such as Costa Rica or Ghana. The model itself can be adapted for the particular culture and location.
This model is applicable for all students, not just teacher candidates. Everyone can benefit from a more global awareness of different cultures and how those cultures address environmental education. In addition, students will wrestle with specific questions that allow them to consider their place in a scientific society.
|Community-based Education, Science Education, Environmental Education, Global perspective
The International Journal of Science in Society, Volume 3, Issue 3, pp.117-128. Article: Print (Spiral Bound). Article: Electronic (PDF File; 803.927KB).
Assistant Professor, Education Program, Centre College, Danville, Kentucky, USA


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Five circles
Print advertisment created by Café Creative, Hungary for Audi, within the category: Automotive.
More of quality.
We offer our models with extra equipment at an extremely low price.
Creative Director: Zoltan Simon
Art Director: Miklos Zsengeller
Copywriter: Gabor Szucs
The day an Audi can be extra equipped at an extremely low price, it won't be an Audi.
Well those little rings there could be much better executed than copy and paste.
Nice idea
the 5th ring could leave a tyre print when joining the other fours. . . just my opinion ^^
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#coffee4fuel | #coffee4gaming
We throw the phrase around, #coffee4fuel, on pretty much everything that we do here at Madrinas Coffee. Social media bios, press releases, and even our cans say "#coffee4fuel." Not to belabor such a simple message, but the idea that you can grab a can of Madrinas coffee and slug that delicious bad boy for the energizing pick-me-up you need (and deserve) is meant to best illustrate what coffee is for your life - fuel. It's what gets you out of bed and ready to attack the day – everyday – regardless of what it is you do. For some of us here at Madrinas Coffee, that #coffee4fuel is how we power our passion for gaming and e-sports.
We spend most of our time out in the world talking to people about Madrinas Coffee, and giving out our coffee to anyone and everyone that needs a source of all natural fuel. But along that coffee-crazed path, we have also grown an intense passion for gaming and e-sports, and more importantly, the communities surrounding them. In the past, gaming as a hobby seemed exclusively reserved for the kids and the college students of society. Today, more and more people, regardless of age, are picking up gaming as a means to connect with others across the world. Getting home @ 8pm after a 12-14 hour day of straight coffee hustlin' and getting the opportunity to connect with like-minded people for a few hours, on games like Destiny and Overwatch (or whatever game I'm playing) is such a unique shared experience. I meet and connect with so many people while I'm gaming at night. And if I didn't have Madrinas #coffee4fuel, there ain't a way I'd be able to keep my head up and my eyes open for long enough to appreciate that dope experience. It is the burst of energy I need to fuel those few killer hours.
For those that don't bother to game or would like to game but have yet to take the plunge, something great to note: the gaming is the means, but the gamers are the ends. Every night I spend online, I never fail to think, "what a time to be alive." I get to plug into someone's creative, imagined world like WoW, or my friends and I get to be the creators and the imaginers of a world like Minecraft. I meet new people on Halo or on Battlefield, blowing off some leftover competitive steam from earlier that day. All the while, all of this connectivity and community would never be possible without my Madrinas #coffee4fuel powering me through the night - I simply wouldn't have the fuel to enjoy it all. And for those that think, "I don't need coffee for gaming," I challenge you to stay up 'til the A.M. – 2, or even 3 – and tell me that, when you wake up, your brain and body don't need coffee for that boost or recovery from the late night before. If you're staying up late gaming, or if you're doing all that you can to recover from that late night, do as the Madrinas Coffee team does; #coffee4fuel your way through life, and go hard after whatever you've set your mind is on conquering.
Enjoy 50% off anything in our store through the rest of August!
Just use code "GAMINGBLOG" at check out.


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Home › Forums › TaG › Rubig Mega R01 650cc Tag "Monster" Reviews needed › Reply To: Rubig Mega R01 650cc Tag "Monster" Reviews needed
If you are a road course kart driver, you do not want this motor. I melted the clutch in just a few laps. I was told a new after market clutch was on its way. Been a month.
Also the motor mount system does not work on CRG frames as claimed. I had to build my own.
I received email from factory tech telling me it was my fault the clutch melted and that the new one will as well if I "do not respect the motor". "I am using a motor intended for sprint tracks and gearing for speed will only melt the clutch easier".
So with little or no parts available in country; lack of gearing for road tracks, and the need to baby the motor on wall start or standing start races, this is not a good choice for road track racing.
No reflection on Brad or engines4racing as they seem to be lacking in the true (1.5 to 3 mile) road racing experience.
Sept. 30-Oct. 1, 2017
Lancaster, California
Streets of Lancaster Grand Prix
October 13-15, 2017
Mooresville, North Carolina
WKA Manufacturers Cup Series
October 20-22, 2017
New Castle, Indiana
RoboPong 200


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Extension for Magento by Anowave
Extra order fee for Magento 2. Allows store owners to charge customers additional custom extra fee at checkout. Allows for adjusting fee amount and fee name directly from Magento backend. Supports fixed and percentage based fee including flexible fee calculation.
It also supports fee conditions which allow fee to be calculated only after certain conditions are met.
This extension for Magento 2 simplifies the process of adding a new custom extra fee for each order. It allows you to charge customer a fixed extra fee at checkout. It also supports fee based on percentage from order grand total and complex fee calculated per order item individually. You can apply different fee for different products in customer's cart.
By using a flexible conditions configurator, you can adjust under what conditions the extra fee will apply. See Fig. 1
Fig. 1 - Flexible conditions support
The module supports number of complex fee types and gives a wide range of fee options
The module provides the ability to set fee per category. This allows site owner to effectively apply specific fee for group of products that fall into the same conditions. Still, product specific fees can be applied.
For the time being the extension does NOT have online demo due to number of security issues in Magento 2.x so we have prepared an online video in 1080p to demonstrate how extension works. It shows the process of setting a fixed extra fee in Magento 2.
Watch here - https://www.youtube.com/watch?v=GlsdQFusYM8
Our products come with a premium support. To report a bug, use our Premium Help Desk available in your account at Anowave.
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This extension can be installed in a few minutes, by going through the following steps:
If you need to upgrade the database, run the following command line:
php -f bin/magento setup:db-schema:upgrade
To set a global fixed fee for the order follow the steps below:
To set a global fee for the order calculated from the order grand total follow the steps below:
To set a global fee for the order calculated from the order grand total follow the steps below:
To set a global fee for the order calculated from the order grand total follow the steps below:
If you like this product, share it with your friends
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Johnny Manziel has had an interesting off-season to put it lightly. It all started with winning the Heisman, then sitting courtside at NBA games and meeting players. After an amazing performance in the Cotton Bowl, he had a legendary night that started at a Casino and ended in a Dallas Nightclub. Now, he's getting pulled over for speeding.
No one would have known about him getting pulled over, had this Judge not made a terrible decision. Judge Lee Johnson's of Ennis, TX and a Baylor alumni, posted this to his Facebook page:
"Too funny. So it seems that a certain unnamed (very) recent Heisman Trophy winner from a certain unnamed "college" down south of here got a gift from the Ennis P.D. while he was speeding on the 287 bypass yesterday. It appears even though the OU defense couldn't stop him, the City of Ennis P.D. is a different story altogether. Time to grow up/slow down young 'un. You got your whole life/career ahead of you. Gig Em indeed."
Johnson then commented on post saying, "I meant to say 'allegedly' speeding, my bad."
Texas A&M met with Johnny Manziel and his parents after the casino and Dallas nightclub incidents and told him to try to keep a lower profile and that he needed to stay out of the spotlight. Getting pulled over for speeding would not fit the description of what Texas A&M wanted.
That being said, his ticket will be thrown out now that the Judge posted about the case on his Facebook page, which then made it onto Twitter and Reddit. The Judge won't be disbarred, but he might have a hard time running for re-election. For those of you that don't know, most Judge's in the state of Texas are elected, only a few are appointed. Looks like Johnny Football caught another break, this kid is living the dream.


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Let me introduce myself. My name is Mark Sisson. I'm 63 years young. I live and work in Malibu, California. In a past life I was a professional marathoner and triathlete. Now my life goal is to help 100 million people get healthy. I started this blog in 2006 to empower people to take full responsibility for their own health and enjoyment of life by investigating, discussing, and critically rethinking everything we've assumed to be true about health and wellness...Tell Me More
This video was submitted to this year's Primal Blueprint Workout Video contest. This is one in a series of recipe videos, workout videos, Grokfeasts and other contest submissions that will be published all week long. View them all and vote for your favorites later this week. Grok on!
If you'd like to add an avatar to all of your comments click here!
2 Comments on "Primal Blueprint Fitness: Kids Gone Primal"
Thanks for the post dear. I do appreciate this one.
Thank's, I'll look a little deeper into Primal Blueprint and see if it has anything worthwhile for our personal training clients.


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I have multiple projects relating to disability and anthropology in both applied and academic settings. My writing has been featured in Bloom, Somatosphere, and TX SenseAbilities, and I have several publications in process. I also enjoy giving invited talks on current disability research to professionals, families, and disability advocates at conferences and special events. Past themes include sibling experiences with disability, and disability, race, and health.
I launched Disability Fieldnotes: Notes on the Anthropology of Disability, in early-2014. It is one of the few blogs devoted to the intersection of disability studies and anthropology, and Disability Fieldnotes is a space for thoughts and musings on contemporary disability issues, as well as a digital archive of contemporary disability issues, news, and debates.
I am also the Digital Communications Manager for the Society for Medical Anthropology. I handle all aspects of the Society's quarterly newsletter, including manuscript submission, communications, editing, design, and publicity. I also developed a comprehensive social media strategy for the Society, and I maintain its social media accounts.
I am honored to serve on the Board of Directors of Texas Parent to Parent, the largest family-led disability advocacy organization in the state. I am also a Steering Committee member of the Disability Research Interest Group, the primary group for anthropologists researching disability.


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The call center isn't only here to help your customers with their tickets. For customers who do things the old-fashioned way, we can help with over-the-phone ticket sales. We can even anticipate other ways to assist — such directions for an event to parking options — we take our call centre services really serious and go beyond the ticket to help you own your audience.


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Join us at one of our exciting events or contact us to find out how you can sponsor one in your community.
Event Information:
Sat30Jan20162:00 pmChevy Chase Library
Book Talk & Film Clips
Joan will be joining award-winning author, Mike O'Brien of "We Shall Not Be Moved" to discuss the Civil Rights Movement.
DVDs and books will be available for sale.


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We've got the classic, new and hard-to-find books and maps to help you get the most out of your adventures.
Order Your Free Catalog
A delightful narrative of Paul Theroux's journey from Boston to Patagonia by rail, plane and truck. He starts out aboard the subway in Boston -- and ends up many months later at the end of the world, a bit worse for the wear. Along the way he encounters the elderly, nearly blind author Jorge Luis Borges and a cast of other fascinating characters.


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Report from Motorsport News International NASCAR Public Relations Las Vegas 300 Quotebook LAS VEGAS, Nev. (March 15, 1997) Driver quotes following second-round Busch Pole qualifying for the Las Vegas 300 NASCAR Busch Series Grand ...
Report from Motorsport News International
NASCAR Public Relations
Las Vegas 300 Quotebook
LAS VEGAS, Nev. (March 15, 1997)
Driver quotes following second-round Busch Pole qualifying for the Las Vegas 300 NASCAR Busch Series Grand National Division race at Las Vegas Motor Speedway
Joe Bessey No. 6 Power Team Chevrolet
"The car has been real good all day. Yesterday's time shows no reflection of what we were yesterday. I knew we were borderline yesterday of making the top-25, so I tried to squeeze that extra little bit out of the car and I just lost it. The guys didn't really want to requalify today because they knew we were going to be in the show, but I knew starting 26th would be a lot better than standing on our time. This track is so smooth, and yes, I think it can give you a false sense of security going into the corners. Just ask those six guys who have wrecked here. But I think we're going to have a great race Sunday, and I think there's going to be a lot of side-by-side, two and three-wide racing. Goodyear has an excellent tire for this track, and the track is just perfect. I can't wait to get started."
Terry Labonte No. 5 Bayer Chevrolet
"We're pretty much a middle-of-the-pace threat right now. We're still working on it. We tried some new stuff, and I didn't like it, so we're going to go back to the way we were. I guess it's a good thing Dale Jarrett and I have two good (NASCAR) Winston Cup cars. Our two Busch cars aren't too good right now. I've got a good car, but the motor isn't where it should be right now. Dale and I, the two Winston Cup point leaders, should have a heck of a race Sunday in the middle of the pack."
Joe Nemechek No. 87 BellSouth Mobility Chevrolet
"I'm going to say I would be the favorite to win Sunday. We came here to win this race. We came here to sit on the pole, and we came up a couple of spots short. We'll take third. I think we've got a pretty awesome car, and we're due to win one of these races. We've been strong for the past two years. We've led a lot of races, and haven't been able to pull off a victory. It would be nice to do it here. Anything can happen in these races. It's not going to be a runaway. There's too many other smart teams and drivers out here. We're going to do our best. A few cars are running strong right now. Todd Bodine is running good. We're strong. I think you're going to see a lot of green flag racing, so we're going to see who's going to be the best after 60 laps or 100 laps. We've got 70 laps on a set of tires, and they're still running the same as we started. I don't think tires will be a factor. Goodyear did a good job. They tested this tire here over the winter. We ran it an Atlanta, and it ran good. It's awesome here."
Greg Sacks No. 45 Hunter Specialties Pontiac
"We really didn't have to requalify today, but we made some changes and wanted to see how they work. We were down on horsepower yesterday. We made major changes to the carburetion and that should help a lot. This is such a great race track. If you get into a turn a little too high, there is room enough to back out of it and get back on it without getting into the wall. It is a very forgiving track."
Elton Sawyer No. 38 Barbasol Ford
"We're happy to be starting sixth with our Ford. They don't pay for where you start but it's always nice to be in the top-10. The car is working good on new tires but picks up a little push when they begin to wear. That's what we'll be working on in the last practice session."
Michael Waltrip No. 21 Band-Aid Ford
"We had too high a gear yesterday. We've changed that and it should make a difference. We'll see in the final practice session. I have confidence in my crew."
Buckshot Jones No. 00 Aquafresh Pontiac
"We've got a good starting position and we're really competitive with the Chevrolets, especially here where there is room to race side by side. We think we can make an excellent showing tomorrow."
Jack Durbin email@example.com Motorsport News International firstname.lastname@example.com (Moderators for "rec.autos.sport.info") Homepage http://www.freenet.tlh.fl.us/users/indy500/index.html


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Download 3C-HF Score apk 1.0.1 free for Android smartphone
Posted by Zetesis Srl in Medical | May 28, 2012 | 0 Comments
Apk file size: 2.5 MB
The 3C-HF score stratifies the individual patient mortality risk at one year, a time-span that is critical for treatment choices, such as device therapy, but still minimizes the potentially larger impact of comorbidities, rather than cardiac conditions, on outcome.
Risk stratification should be repeated after one year, or in case of any significant change in the considered variables.
Zetesis Srl part of our Medical and have average installs from 100 to 500. Last Update May 28, 2012. Google play rating is 80.0. Current verison is 1.0.1. Actual size 2.5 MB.


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By LYNNE WILBANKS
It's trendy to say you love your country and hate the government. Not sure how that works, because I like my government.
I recently wrote a check to the Internal Revenue Service, and after a momentary grumble, I caught myself. I reminded myself that as an American, I pay fewer taxes than citizens of most industrialized countries, and for the services I receive, it's a bargain.
I hike a lot and have been privileged to see some of the most glorious vistas and historic landmarks in this country, all government-run. Recently after a hike, I took a Yankee friend to eat Alabama barbecue. We didn't give a thought to food safety because the meat was government-inspected. We didn't wear protective face masks necessary in some parts of the world, because we trusted the air quality. We drove on government-built roads, and when my friend flew home, he wasn't worried about his airplane running into another one; the skies are controlled by federal air-traffic controllers; there might even have been a federal marshal on board keeping terrorists at bay. When I returned home, the post office had kindly delivered my mail. On the nightly news, the secretary of transportation discussed what the government was doing about the Toyota safety issue.
In our crowded, complex society, we expect a lot from our government, most of which we take for granted. It provides services and regulates items our Founding Fathers couldn't imagine, from cloning and Internet pornography on the Internet to protection in the friendly skies.
Until the Civil War, a citizen's only contact with his government was picking up his mail at the local post office. Few taxes were collected and few services provided, so it is unclear to me exactly what the tea party folks want. In the 18th century, the national government was so weak it was held together by duct tape and George Washington's leadership. European powers picked on America unceasingly. The water wasn't safe to drink, so everybody drank alcohol, and eventually alcoholism became a major social problem and cause of domestic violence in 19th- century America. The good ol' days weren't all that terrific.
Folks on the news carry signs that they want less government in their lives, but what services are they willing to give up?
In Alabama, federal stimulus money is keeping our state educational system afloat to the tune of a half-billion dollars in 2010 and 2011. Some are afraid of government-run health care, but the federal government has been providing it for people older than 65 for almost 50 years, plus the military, veterans and federal employees. If there were going to be death panels, we would already have seen them, since most people who die are older than 65.
If you ask who I trust to manage my health care: the government, which does a pretty good job at most health and safety issues, or corporate America, whose bottom line is profit, I would say the government.
If I have a claims problem, how responsive is a corporate customer service department going to be? At least with the government, when I have exhausted all possibilities, I can call my member of Congress who wants my vote.
Our 21st-century government is not cheap or perfect, but for the services and protection we receive, I give thanks. I love my country, and I even like my government.
Lynne Wilbanks is a public school teacher who lives in Birmingham. E-mail: firstname.lastname@example.com.


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Mexico vacation villa rental - Villa Amanecer de los Suenos
4br Country House
Mulege,South Lower California,Mexico
Ease yourself into the pool at Villa Amanecer de Los Suenos and gaze out at the glimmering Baja blues of the Sea of Cortez. Its hard not to feel like royalty and why not, when you can lounge at your leisure in the pool, paddle over to the swim-up bar for a cool cocktail, or sunbathe on the sandy area by the infinity pool at the villas lower level! Villa Amanecer de Los Suenos is a place of play for you and yours: the jacuzzi floats 8 revelers, theres ample room and furnishings for patio dining, plus a lovely shade structure, pergolas and barbecue. And the rear patio garden, with its towering rock wall and fire-pit area helps to make the star-filled nights of the East Cape all the cozier.
Homeaway has a HUGE selection of vacation homes from all around the world. Until the rise of Airbnb, they were the biggest. They grew partly by buying up every other vacation home rental site, so even if you don't think you're using Homeaway, you probably are. Go away, with Homeaway.
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Thank you! Your property claim is finished. Please wait for us to contact you to confirm ownership.


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10 years ago in the Profession
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It was a bit tricky to find, but a nearby property provided directions. It turns out to be quite close to the airport, so that made it convenient to return our rental car and take the shuttle back to the hotel. In the morning, ti was a 5 minute trip to the terminal using their large shuttle. The hotel appears to be an older building, but has been nicely refurbished. The room was fine and had the best shower set-up we've found in Europe. The wifi worked fine and they do have a convenient computer to print boarding passes. The breakfast was not, it was only a prepackaged roll and an orange, but it was rather early in the morning, so breakfast at the airport was more timely. There is no nearby restaurant, so plan ahead or call for delivery.
- Official Description (provided by the hotel):
- Welcome to Holiday Inn Express Milan-Malpensa Airport, the closest hotel to the Terminals.Located only 500m from the Milan Malpensa International Airport, the hotel represents the ideal place to either meet for work or relax after a long journey.Take advantage of our complimentary shuttle service to/from Terminal 1 of the airport available on a scheduled basis, and to/from Terminal 2 on request. Alternatively the airport offers a 24h free shuttle between Terminal 1 and Terminal 2 with a bus stop just 200m from the hotel.The brand new Holiday Inn Express Milan-Malpensa Airport combines contemporary style, comfort and convenience thus representing the smartest choice for travellers attentive to value for money. Start your day on a good note with a reinvigorating power shower experience and a complimentary extensive buffet breakfast.Modern technology and fresh look are the strengths of the brand new Holiday Inn Express Milan-Malpensa Airport hotel which offers 124 comfortable bedrooms all equipped with soundproof windows, WiFi internet connection and wooden floor. Ample public areas designed with lively colours and refined materials are available to our guests who will be able to surf the internet by using the dedicated internet points or by simply connecting to the wireless net.Complete the offer free parking facilities and a meeting room able to host up to 40 persons. ... more less
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Prairie Chickens and Other Strange Birds – Adventure Travels!
Adventure Travels – It's 3:30 in the morning, dark, no indication of a dawn. We grind via soggy marshland. April is not always kind. It's cool, wet. What the hell are we doing below near Plover, Wisconsin in the middle of a cold evening? Finally, we get to a reduced building, a blind. If you stand to your complete height, also mine! … you bang you directly the roofing boards. We sit on low benches, peer via slits in the framework. Like a shelter on a battlefield! Then, daytime appears like a mylar helium balloon let fly by a kid with greasy fingers. I 'd missed it, sunrise; possibly I nodded off … I check out the narrow home window; there they are! Dozens of them. Grassy field hens! Dancing extremely, horny, moaning crazily, disclosing the complete majesty of their lovely downy sex apparatus!
Exactly what a great, comic performance! They puff out brilliant orange sacs under their throats, drum their little feet, dance furiously to bring in a friend. Territorial men jump right into the air to alert off various other men, interlopers. After that destination happens! … A successful male acquiesce a lady. She trembles her ruffled plumes. It's done. They're wed, or mated in non-anthropological talk! An area morning meal complies with, consisting of thick hash brown potatoes offered from an enormous, deep-sided baking frying pan. And also meaty points!
This was one of a several amazing trips raised by and taken with priceless close friends, Rob and Susie. All them abnormally various, and all unforgettable and full of weird enjoys the unique fashion of each. Near Lansing, Iowa, we floated along the Mississippi experiencing fantastic bird movements. The were swans as well as masses of coots, goat pastures, hairless eagles, also a mink foraging for food along a wing dam. Prior to this trip, I would certainly never before experienced swans completely flight. Never ever seen numerous coots united on a solitary slice of river … (" Coots" implying birds. Not geezers playing checkers in coffee cafes as well as watering holes!).
That Mississippi River trip might have given us the suggestion for another. We four leased a houseboat from Alma, Wisconsin. Used one night in an inlet. Developed a fire, sang "Old Man River." Fantastic time. On the 2nd night, after a day of hunting the Great River, passing magnificent-looking barge tugs, we beached ourselves in between a set of wing dams. In the middle of the night, we were awakened twice, as soon as by a thump, as soon as by a passing barge prompted slowly along by a brilliantly-lit pull, so beautiful in the darkness of the still river. The smack was, we assumed, a tree branch that had actually lodged itself under our houseboat. Couldn't move the "branch" despite how the 4 of us attempted! Ended up being a whole tree! Needed to mobilize Captain Jack of the rental service and his powerful motorboat. He, too, couldn't think the dimension of the tree that secured us to the coastline. Detected an eagle's nest so large the 4 of us can have relocated with kitchen area home appliances as well as easy chair … perhaps as well a Murphy Bed!
In Mexico, we found a spider monkey protect near Akumal. The 4 of us spent more than an hour connecting with the monkeys in a big, cage-like enclosure. We fed them snacks, as well as they, consequently, picked "artifacts" from our hair and skin (or whatever it was they found and also consumed!). Such fantastic groomers! Analytical but often gentle (save for a couple of little nips, sometimes)! The fish and shellfish restaurant transcended. The palapas-sheltered "Turtle Coastline" was beautiful to see! The ferry journey to as well as from Cozumel was perilous, with massive swells on an upset Caribbean. We all believed we would certainly tip over and also drown in the roiling azure soup! Yet (possibly you read about it in the Playa del Carmen Porque-Pescado!), we survived to cruise an additional day … (Petitions of thanksgiving to Saint Elmo … ).
Most just recently, we traveled to Starved Rock State Park in north main Illinois. A location of magnificent rock formations, falls, streams and wildlife, consisting of funny-looking vacationers. Excellent hiking tracks. Prior to our arrival, not far from the park, we stopped in Lasalle, near Lock 16, to ride an authentic canal boat powered by a solitary mule called "Mo." By the by, we extremely recommend Lock 16 Cafe because enchanting community. Terrific food, wonderful homeowner! Starved Rock (called for a Native-American battle site on which the vanquished were deprived out of their garrison!) is situated on the coasts of the Illinois River. The lodge and also cabins are beautiful, inviting and comfy. Just what's that? Oh sure, we 'd go back there!
We've typically considered a feasible Geezers' Overview of Great Traveling Adventures as well as Good Restaurants That Satisfy a More "Experienced" as well as Thus Critical Traveler (Working title!). As a tasting, and to whet your hunger (you'll please forgive the noticeable effort … ), you ought to attempt Greenfire in Rockford, Illinois. It gets on our "Huge/ Great deals of Stars" listing of great business food. Below's one more … Cafe McGregor in McGregor, Iowa, simply across the Big River from Prairie du Chien, WI. I think we liked Heaven Heron in Winona, MN where we stopped to eat during our vehicle adventure along the Great River Roadway. And, they have an Eagle Gallery and also (a kind of) haven in Winona. Lots of details regarding the Mississippi River Eagle populace, their resurgence from near extinction. The location has a pet dog or mascot eagle that was injured as well as currently resides in peaceful harmony with team and also visitors, and you can have your picture taken with the eagle. She suches as homeowner!
Adventure traveling need not be restricted to the young. Those who are in shape and prepared could experience terrific experiences. The trick is to explore the possibilities. The meadow chicken breeding routine, for example, is a wonderful encounter. Ours was delighted in on a chilly April morning from a blind near Plover, Wisconsin. The Mississippi River is a spectacular all-natural American resource, as well as a viewpoint where to see a terrific variety of wildlife, consisting of swans, coots, hairless eagles, even mink. Home boating on the Mississippi is a remarkable encounter. The sight of fantastic river yank watercrafts plowing through the current, pushing their fantastic barges packed with industrial freight is stunning to look at. Contrast that to noisy semi-trailer trucks gushing exhaust fumes on the countries' interstate freeways, and just one remembered vision will continue to be. We are a nation of impressive national parks, it holds true, however lots of state parks are greater than worth the moment. An archetype is Starved Rock State Park in north central Illinois. Falls, impressive rock developments, hiking trails and abundant with record, and also its place on the coasts of the Illinois River. The point is, journey travel is a prize, as well as one that can be mined by any individual, at any kind of age.


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|Publication number
|Publication type
|Application number
|Publication date
|May 18, 2010
|Filing date
|Jan 21, 2008
|Priority date
|Jan 23, 2007
|Fee status
|Also published as
|Publication number
|Timothy Michael Nisbet, Garo Garbis Vaporciyan, Cornelis Leonardus Maria Vrouwenvelder, Paul Wood
|Original Assignee
|Shell Oil Company
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (25), Non-Patent Citations (3), Referenced by (1), Classifications (5), Legal Events (2)
|External Links: USPTO, USPTO Assignment, Espacenet
This application claims the benefit of European Patent Application No. 07100967.4 filed on Jan. 23, 2007 that is hereby incorporated by reference.
The present invention relates to a process for the preparation of an alkanediol and a dialkyl carbonate. More particularly, the invention relates to a process for the preparation of such compounds from an alkylene carbonate and an alkanol.
A process for preparing a dialkyl carbonate is described in U.S. Pat. No. 5,359,118. The patent discloses a process in which di(C1-C4 alkyl) carbonates are prepared by transesterification of an alkylene carbonate with a C1-C4 alkanol. The alkylene carbonate and an alkanol feedstock are reacted countercurrently in a column with the aid of a catalyst. The catalyst is usually homogeneous, although the use of heterogeneous catalysts is also suggested. The alkylene carbonate is introduced into the upper part of the column and trickles down from above. The alkanol feedstock comprising a pure alkanol and a stream, comprising the alkanol and also the dialkyl carbonate, is fed into the column at a lower part. The alkanol flows upward and reacts countercurrently with the alkylene carbonate to obtain dialkyl carbonate with unreacted alkanol as the top effluent and the alkanediol with any entrained alkanol as the bottom effluent. The top effluent is subjected to distillation treatments to yield an alkanol-rich stream comprising the alkanol and minor amounts of the dialkyl carbonate. This stream is fed to the column as part of the alkanol feedstock. The bottom stream is worked-up resulting in an alkylene glycol stream and a catalyst-containing concentrate that is partly recycled.
The patent discloses the formation of high-boiling by-products, such as polyglycols. In the process these high-boiling by-products are contained in the catalyst-containing concentrate. Part of the concentrate is recycled to the transesterification, whereas another part is discarded.
Although the process discloses the formation of polyglycols, it does not address the problem of the removal of such polyglycols, in particular the dimers of the alkanediol, also known as dialkylene glycols. Moreover, the process presumes that no alkylene carbonate leaves the reactor unconverted. In practice, the transesterification to dialkyl carbonate will not be 100%. Therefore, the bottom product of the process will contain not only polyglycols, as suggested in U.S. Pat. No. 5,359,118, but also some unconverted alkylene carbonate. In view of their boiling points it is very difficult to separate dialkylene glycols from the corresponding alkylene carbonates. This has not been acknowledged in the process according to U.S. Pat. No. 5,359,118. Therefore the bottom product contains contaminants that bear the risk of building up during continuous recycle.
It is an object of the present invention to overcome this drawback.
The present invention provides a process for the preparation of an alkanediol and a dialkyl carbonate comprising:
(a) reacting an alkylene carbonate and an alkanol feedstock in a first reaction zone under transesterification conditions to obtain a product mixture of dialkyl carbonate, unconverted alkanol, the alkanediol, unconverted alkylene carbonate and dimers of the alkanediol;
(b) separating dialkyl carbonate and alkanol from the product mixture to obtain a bottom product stream containing alkanediol, unconverted alkylene carbonate and dimers of the alkanediol;
(c) recovering the dialkyl carbonate; and
(d) separating alkanediol from the bottom product stream to leave a recycle stream comprising unconverted alkylene carbonate and dimers of the alkanediol, which process further comprises
(e) passing at least part of the recycle stream to a second reaction zone in which dimers of the alkanediol are converted to higher-boiling oligomers of alkanediol, yielding an oligomers-containing effluent;
(f) separating the higher-boiling oligomers from the oligomers-containing effluent yielding an alkylene carbonate-containing remaining stream; and
(g) recycling the alkylene carbonate-containing remaining stream to the first reaction zone.
The present invention is based on the finding that the separation of higher-boiling by-products from alkylene carbonates can be rendered easy by converting dialkylene glycols to higher-boiling oligomers of alkanediol. By the subsequent easy separation the build-up of dialkylene glycols is prevented. By the recycle of the remaining alkylene carbonate, this part of the alkylene carbonate in the recycle stream is subjected to the transesterification again, so that it may be converted into the target dialkyl carbonate.
The present invention provides a process for the preparation of an alkanediol and a dialkyl carbonate. The reaction zone in the present invention may be a reactive distillation zone, as described in U.S. Pat. No. 5,359,118. This would entail that the reaction is carried out counter-currently. The transesterification reaction is advantageously conducted in a column furnished with internals, like a distillation column. Hence, it may contain trays with bubble caps, sieve trays, or Raschig rings. The skilled person will realise that several packing types and tray configurations will be possible. Suitable columns have been described in, e.g., Ullmann's Encyclopedia of Industrial Chemistry, 5th ed. Vol. B4, pp 321 ff, 1992. The alkylene carbonate will be fed at the upper part of such a column and will flow down. The alkylene carbonate will generally have a higher boiling point than the alkanol. In the case of ethylene and propylene carbonate the atmospheric boiling points are above 240� C. The alkylene carbonate will flow down over the trays or rings and be brought into contact with the alkanol that flows upward.
In a preferred embodiment the reaction is conducted in a co-current manner. A suitable way to operate is to carry out the reaction in a trickle-flow manner wherein the reactants, part in vapor phase and part in liquid phase, drip down over a heterogeneous catalyst. A more preferred way to operate the process of the present invention is in a reactor with only liquids. A suitable reaction zone of this type is a pipe-type reaction zone wherein the reaction is conducted in a plug flow manner. This will enable the reaction to run to virtual completion. A further possibility is to conduct the reaction in a continuously stirred tank reactor (CSTR). In the latter case the effluent from the CSTR is preferably subjected to a post-reaction in a plug flow reactor so that the reaction runs to virtual completion.
The process of the present invention includes the transesterification of an alkylene carbonate with an alkanol. This transesterification reaction is described in U.S. Pat. No. 5,359,118. The starting materials of the transesterification are preferably selected from C2-C6 alkylene carbonate and C1-C4 alkanols. More preferably the starting materials are ethylene carbonate or propylene carbonate and methanol, ethanol or isopropanol.
Transesterification conditions suitably include the presence of a catalyst. Suitable homogeneous catalysts have been described in U.S. Pat. No. 5,359,118 and include hydrides, oxides, hydroxides, alcoholates, amides, or salts of alkali metals, i.e., lithium, sodium, potassium, rubidium and cesium. Preferred catalysts are hydroxides or alcoholates of potassium or sodium. It is advantageous to use the alcoholate of the alkanol that is being used as feedstock. Such alcoholate can be added as such or be formed in situ.
Other suitable catalysts are alkali metal salts, such as acetates, propionates, butyrates, or carbonates. Further suitable catalysts are described in U.S. Pat. No. 5,359,118 and the references mentioned therein, such as EP 274 953, U.S. Pat. No. 3,803,201, EP 1082, and EP 180 387.
As indicated in U.S. Pat. No. 5,359,118, it is also possible to employ heterogeneous catalysts. In the current process the use of heterogeneous catalysts in the transesterification reaction is preferred. Suitable heterogeneous catalysts include ion exchange resins that contain functional groups. Suitable functional groups include tertiary amine groups and quaternary ammonium groups, and also sulfonic acid and carboxylic acid groups. Further suitable catalysts include alkali and alkaline earth silicates. Suitable catalysts have been disclosed in U.S. Pat. No. 4,062,884 and U.S. Pat. No. 4,691,041. Preferably, the heterogeneous catalyst is selected from ion exchange resins comprising a polystyrene matrix and tertiary amine functional groups. An example is Amberlyst A-21 (ex Rohm & Haas) comprising a polystyrene matrix to which N,N-dimethylamine groups have been attached. Eight classes of transesterification catalysts, including ion exchange resins with tertiary amine and quaternary ammonium groups, are disclosed in J F Knifton et al., J. Mol. Catal, 67 (1991) 389ff.
The transesterification conditions are known to one of ordinary skill in the art and suitably include a temperature from 40 to 200� C., and a pressure from 50 to 5000 kPa (0.5 to 50 bar). When the alkanol is methanol, the pressure is preferably close to atmospheric. The temperature depends on the alkanol feedstock and pressure used, and the reactor used. In counter-current mode the temperature is kept such that it is close to and above the boiling point of the alkanol, e.g. up to 5� C. above the boiling point. In the case of methanol and atmospheric pressure, the temperature is close to and above 65� C., for instance between 65 and 70� C. In case of co-current operation the alkanol may still be liquid. In co-current operation, the pressure ranges suitably from 0.5 to 50 bar, preferably from 2 to 20 bar, and the temperature from 40 to 200� C., preferably from 80 to 160� C.
When the transesterification catalyst is homogeneous such as an alkali metal alcoholate, and when a reactive distillation is being employed, the homogeneous catalyst, may be introduced in the upper part of the reaction zone. The alkanol feedstock is then introduced at a lower point. The feedstock may be completely in vapour phase. However, it is also possible to introduce the feedstock into the column partly in the liquid phase. It is believed that the liquid phase ensures a higher concentration of alkanol in the lower part of the column with a beneficial effect on the overall transesterification. It is distributed over the width of the column via the inlet and the column internals. The ratio between the vapor and the liquid part of the alkanol feedstock may be varied between wide ranges. The vapor/liquid weight ratio is suitably from 1:1 to 10:1 wt/wt.
When a heterogeneous catalyst bed is being used and when a reactive distillation is being employed, the alkylene carbonate is suitably introduced above the catalyst bed and the alkanol below the catalyst bed. When a co-currently operated reactor is being employed the reactants may be pre-mixed or introduced separately into the reactor upstream of the catalyst bed. The person skilled in the art will know that the transesterification is an equilibrium reaction. Therefore, the process may suitably employ an excess of the alkanol. The molar ratio of alkanol to alkylene carbonate is suitably from 1.01:1 to 25:1, preferably from 2:1 to 15:1, more preferably from 3:1 to 7:1. The amount of catalyst can evidently be much smaller. In case of the use of a homogeneous catalyst suitable amounts of such catalysts include from 0.1 to 5.0% wt based on alkylene carbonate, preferably from 0.2 to 2% wt. The weight hourly space velocity may suitably range from 0.1 to 100 kg/kg�hr.
From the reaction zone a mixture of dialkyl carbonate, unconverted alkanol, alkanediol, unconverted alkylene carbonate and dimer of alkanediol is withdrawn. In the case of a counter-current process, such as reactive distillation, a first mixture of alkanol and dialkyl carbonate is withdrawn at the top of the reactive distillation column, and at the bottom a second mixture comprising unconverted alkylene carbonate, alkanediol and dimer of alkanediol. In case of a co-current operation a product mixture comprising the above-mentioned five compounds is obtained.
When the transesterification is being conducted in a reactive distillation unconverted alkanol and dialkyl carbonate are separated together in the reactive distillation zone and withdrawn at the upper part of a reactive distillation column. Unconverted alkylene carbonate and alkanediol are withdrawn from the reactive distillation column at the lower part. In other embodiments the four compounds are withdrawn simultaneously. In one embodiment the unconverted alkanol and the dialkyl carbonate are separated by distillation in one fraction. Suitable distillation conditions are a pressure from 0.1 to 1.0 bar and a temperature from 40 to 200� C. This achieves the separation of a top fraction comprising unconverted alkanol and dialkyl carbonate and a bottom fraction comprising unconverted alkylene carbonate and alkanediol. The top fraction is preferably subjected to another distillation to separate dialkyl carbonate from unconverted alkanol. Such distillation may suitably be achieved at pressures ranging from subatmospheric pressure to superatmospheric pressure. Suitably the pressure may vary from 0.1 to 45 bar. Temperatures may vary in accordance with the pressure selected. The temperature may be from 35 to 300� C. More preferably, the conditions in the distillation include a pressure ranging from 0.1 to 0.5 bar and a temperature ranging from 35 to 150� C. When the dialkyl carbonate and the alkanol form an azeotrope it may be beneficial to use extractive distillation, using an extractant to facilitate the separation between the dialkyl carbonate and the alkanol. The extractant can be selected from many compounds, in particular alcohols such as phenol, or anisole. However, it is preferred to employ an alkylene carbonate as extractant. It is most advantageous to obtain the separation in the presence of the alkylene carbonate that is being used as starting material for the eventual alkanediol.
In another embodiment the product stream is subjected to distillation in such a manner that mainly unconverted alkanol is separated as top fraction. Such a distillation may suitably be carried out at a pressure of 0.1 to 45 bar. Temperatures may vary in accordance with the pressure selected. The temperature may be from 35 to 300� C. More preferably, the pressure is from 0.5 to 1.5 bar and the temperature ranges from 60 to 200� C. In a further distillation the remaining compounds may be separated in dialkyl carbonate as top fraction and a bottom fraction comprising alkanediol and unconverted alkylene carbonate. Conditions for this distillation advantageously include a pressure of 0.1 to 0.5 bar and a temperature of 60 to 190� C.
The dialkyl carbonate recovered in the embodiments may optionally be further purified. This further purification may comprise a further distillation step or an ion-exchange step, as described in U.S. Pat. No. 5,455,368.
Both in the counter-current and the co-current embodiments a bottom product is obtained comprising alkanediol, unconverted alkylene carbonate and dialkylene glycol. To separate alkanediol from this bottom stream the bottom stream is preferably subjected to a further distillation step, suitably at a pressure from 0.01 to 0.4 bar and a temperature of 100 to 200� C. This distillation achieves a separation of alkanediol and a recycle stream comprising unconverted alkylene carbonate. The top fraction in this distillation containing recovered alkanediol may comprise other compounds, such as unconverted alkylene carbonate depending on the sharpness of the separation cut.
At least a part of the recycle stream is passed to the second reaction zone. Suitably the complete recycle stream is fed to the second reaction zone. Optionally, the stream may be split in more portions, the additional portions being bled from the process. It will be understood that in general the bleed stream will be as small as feasible, and preferably, no bleed stream will be used in the process
In the second reaction zone the dimer of the alkanediol is converted to higher-boiling oligomers of the alkanediol. Suitably this is effected by the reaction of the dimer with an alkylene oxide or an alkylene carbonate. When an alkylene carbonate is being used, the reaction conditions and catalyst may be selected from those that are being used in the first reaction zone. The condition for the reaction of alkylene carbonate with alcohols are well known and have been described in U.S. Pat. No. 2,448,767. It is possible to employ the same alkylene carbonate that is being used in the first reaction zone. In such a case the alkylene carbonate that is present in the recycle stream comprising unconverted alkylene carbonate and dimers of the alkanediol may be employed for this reaction. Depending on the content of the dimer of the alkanediol and of the alkylene carbonate in this recycle stream additional alkylene carbonate may be added.
Suitably the molar ratio of alkylene carbonate or alkylene oxide to dimer of alkanediol is at least 1:1. Molar ratios can be much higher and there is usually no upper limit. Since the dimer formation is limited and the reaction of dimer with alkylene carbonate is fast there is usually an excess of alkylene carbonate. An excess ratio of more than 1000:1 is not common.
Preferably, the higher-boiling oligomers of alkanediol are prepared by adding an alkylene oxide to the second reaction zone. In this method it is easy to optimise the molar ratio between the reactants. Further the reaction between the dimer and alkylene oxide is fast and runs easily to completion.
The alkylene oxide in this embodiment contains preferably the same alkylene moiety as the one in the alkylene carbonate. In this way oligomers of the same alkanediol are obtained that may be recovered as useful products.
The reaction conditions for the reaction of the dimer of alkanediol with an alkylene oxide are known in the art. Reaction conditions include a reaction temperature in the range of 70 to 250� C., preferably from 90 to 180� C., a pressure in the range of 0.5 to 15 bar, preferably from 1 to 6 bar. The reaction is preferably conducted in the presence of an alkali catalyst. Suitable catalysts include alkali metal hydroxides, in particular sodium and potassium hydroxide. The catalyst is preferably added in an amount of 0.01 to 5% wt, based on the amount of the dimer, more preferably in an amount of 0.1 to 1% wt, based on the weight of the dimer.
The reaction rate of the oligomer formation is high and the reaction is bound to run to virtual completion. However, the objective of the present invention, i.e. the prevention of the build-up of the dimer of the alkanediol, is achieved, even if the reaction is not complete. This will provide the skilled artisan with freedom to select the most feasible conditions.
After the formation of the oligomers the resulting oligomers-containing effluent is subjected to separation. Suitably the effluent is subjected to distillation. In such distillation the alkylene carbonate present in the effluent can be withdrawn from the upper part of the distillation column as the alkylene carbonate-containing remaining stream, whereas the oligomers together with the alkaline catalyst can be withdrawn at the lower part of the column. The oligomers and catalyst may be discharged or treated to recover the oligomer as useful product and/or recover the alkaline catalyst for re-use. Distillation conditions may be selected by the skilled person. Suitably, the distillation is conducted under vacuum. The pressure is preferably from 10 mbar to 1 bar. The temperature in the distillation may suitably range from 100 to 300� C.
Since the alkylene carbonate-containing remaining stream is recycled to the first reaction zone no alkylene carbonate is wasted and all starting material is converted to the desired products.
The process of the present invention can be employed for a variety of feedstocks. The process is excellently suited for the preparation of ethylene glycol (1,2-ethanediol), propylene glycol (1,2-propanediol), dimethyl carbonate and/or diethyl carbonate and/or diisopropyl carbonate. The process is most advantageously used for the production of ethylene glycol or propylene glycol and diethyl carbonate or diisopropyl carbonate from ethylene carbonate or propylene carbonate and ethanol or isopropanol. The dimer of the alkanediol is suitably converted to the trimer. In this way the separation becomes easy and the addition of extra starting material such as alkylene oxide can be kept minimal. Therefore, the oligomers to be produced are most preferably triethylene glycol and tripropylene glycol.
Ethanol is passed via line 1 into reactor 2. Reactor 2 can suitably be a continuously stirred tank reactor. Via line 3 ethylene carbonate is also fed into reactor 2. A transesterification catalyst may be present or may be fed continuously to the reactor. The catalyst may be mixed with one of the reactants or fed to the reactor via a separate line (not shown). A product comprising a mixture of diethyl carbonate, unconverted ethanol, ethylene glycol and unconverted ethylene carbonate is withdrawn from the reactor 2 via line 4. Via line 4 the mixture is passed to a distillation column 5 where the product is separated into a top fraction comprising diethyl carbonate and ethanol that is withdrawn via line 6, and a bottom fraction comprising ethylene glycol and ethylene carbonate withdrawn via line 7. The mixture comprising diethyl carbonate and ethanol in line 6 is passed to a distillation column 8, where the mixture is separated into ethanol and diethyl carbonate. The diethyl carbonate is discharged via line 9 and recovered as product, optionally after further purification. Ethanol is recovered via line 10 and recycled to reactor 2 via line 1.
The bottom stream in line 7 is subjected to distillation in distillation column 11. In the distillation column 11 a top product comprising ethylene glycol is recovered via line 12. Since the top product may be slightly contaminated with some ethylene carbonate further purification may be considered. The bottom product of distillation column 11 withdrawn via line 13 comprises polyethylene glycol, in particular diethylene glycol, and ethylene carbonate. Through line 13 the bottom product is passed to reactor 14, into which also ethylene oxide is passed via line 15, and homogeneous catalyst via line 16. Reactor 14 is shown as a continuously stirred tank reactor. However, other reactors, such as pipe reactors with a plug flow regime, are also possible. The reaction product from reactor 14 is withdrawn via line 17 and passed to distillation column 18. In distillation column 18 a bottom product is withdrawn via line 19, comprising the oligomers of ethylene glycol, in particular triethylene glycol. The top fraction of distillation column 18, withdrawn via line 20, comprises ethylene carbonate and is recycled to reactor 2.
|Cited Patent
|Filing date
|Publication date
|Dec 5, 1942
|Sep 7, 1948
|Mellon Inst Of Ind Res
|Process of hydroxyethylation
|Feb 22, 1971
|Apr 9, 1974
|Dow Chemical Co
|Synthesis of dimethyl carbonate
|Apr 8, 1976
|Dec 13, 1977
|Anic, S.P.A.
|Process for the preparation of dialkylcarbonates
|Jan 3, 1986
|Sep 1, 1987
|Texaco Inc.
|Process for production of ethylene glycol and dimethyl carbonate
|Dec 28, 1990
|May 11, 1993
|Asahi Kasei Kogyo Kabushiki Kaisha
|Process for continuously producing an aromatic carbonate
|Aug 6, 1993
|Sep 6, 1994
|Bayer Aktiengesellschaft
|Process for the preparation of diaryl carbonates
|May 10, 1993
|Oct 25, 1994
|Bayer Aktiengesellschaft
|Process for the continuous preparation of dialkyl carbonates
|Jan 17, 1997
|May 5, 1998
|Asahi Kasei Kogyo Kabushiki Kaisha
|Method for producing an aromatic polycarbonate having improved melt stability
|Oct 7, 1998
|Dec 5, 2000
|Huntsman Petrochemical Corporation
|Alkylene carbonate process
|Nov 3, 1999
|Mar 27, 2001
|Mobil Oil Corporation
|Process for co-production of dialkyl carbonate and alkanediol
|Nov 12, 2002
|Jul 27, 2004
|Shell Oil Company
|Method for the catalytic conversion of organic carbonate and the use of a lanthanum catalyst therefor
|Sep 10, 2003
|Dec 28, 2004
|Shell Oil Company
|Catalytic conversion of an organic carbonate
|Nov 12, 2002
|Oct 11, 2005
|Shell Oil Company
|Method for the catalytic conversion of alkylene carbonate
|Feb 22, 2007
|Jul 21, 2009
|Shell Oil Company
|Process for the preparation of an alkanediol and a dialkyl carbonate
|Aug 28, 1978
|Mar 21, 1979
|Bayer Ag
|Process for the preparation of dialkyl carbonates
|Oct 18, 1985
|May 7, 1986
|Scientific Design Company Inc.
|Process for preparing alkylene oxides from alkylene carbonates and alkylene carbonates from alkylene oxides
|Dec 16, 1987
|Jul 20, 1988
|Societe Francaise D'organo-Synthese
|Process for the preparation of organic carbonates by transesterification
|May 3, 1993
|Nov 18, 1993
|Bayer Ag
|Process for the continuous production of dialkyle carbonates
|Dec 9, 1997
|Jul 1, 1998
|Basf Corporation
|Liquid heteric-block polyoxyalkylene componds having improved flowability characteristics
|Dec 20, 1996
|Jan 7, 1999
|Asahi Kasei Kogyo Kabushiki Kaisha
|Process for continuously preparing dialkyl carbonates and diols
|Jun 21, 2000
|Jan 3, 2001
|INEOS, naamloze vennootschap
|Method and device for manufacturing products in an industrial manner by means of an alcoxylation reaction
|Mar 27, 2002
|Oct 2, 2002
|Nof Corporation
|Polyethylene glycol and process for producing the same
|Title not available
|Jul 9, 2002
|Jan 23, 2003
|Mitsubishi Chemical Corporation
|Method for producing dialkylcarbonate
|Jun 28, 2004
|Jan 13, 2005
|Shell Internationale Research Maatschappij B.V.
|Process for the preparation of propylene carbonate
|Hong Zhu et al., "Synthesis of Propylene Carbonate and Some Dialkyl Carbonates in the Presence of Bifunctional Catalyst Compositions," Polymers for Advanced Technologies, Wiley & Sons, Bognor Regis, GB, vol. 7, No. 8, Aug. 1, 1996, pp. 701-703 XP000623427.
|J F Knifton et al., J. Mol. Catal, 67 (1991) 389ff.
|Ullmann's Encyclopedia of Industrial Chemistry, 5th ed. vol. B4, p. 321 ff, 1992.
|Citing Patent
|Filing date
|Publication date
|Apr 23, 2008
|Oct 29, 2009
|Evert Van Der Heide
|Process for the preparation of a 1,2-alkylene diol and a dialkylcarbonate
|U.S. Classification
|558/277, 568/858
|International Classification
|Cooperative Classification
|European Classification
|Apr 16, 2008
Owner name: SHELL OIL COMPANY, TEXAS
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Owner name: SHELL OIL COMPANY,TEXAS
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:NISBET, TIMOTHY MICHAEL;VAPORCIYAN, GARO GARBIS;VROUWENVELDER, CORNELIS LEONARDUS MARIA;AND OTHERS;SIGNING DATES FROM 20080204 TO 20080402;REEL/FRAME:020815/0985
|Oct 23, 2013
|Fee payment
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Some very kind words about vEco from Doug Cress, Programme Coordinator for the United Nations' Great Apes Survival Partnership! If you've got a VR headset, give apeAPP VR a spin on your Android or Apple smartphone 🙂 http://www.un-grasp.org/vr/
Category Archive: Internet Technology
May 09
vEco launches VR app in partnership with UNEP-GRASP
vEcotourism.org is both proud and incredibly excited to be launching our first virtual reality mobile app in partnership with the United Nations Environment Programme – Great Apes Survival Partnership (UNEP-GRASP) and the Ape Alliance: apeAPP VR! The app, which will be available on both Android and iOS smartphones, will offer immersive tours of all great ape …
Apr 22
Virtual reality natural history — a sign of the future!
What equipment does a naturalist usually need? vEco's Adviser and Ambassador (and renowned wildlife biologist and conservationist) Ian Redmond suggests a pair of binoculars and a hand lens, but — as he explains in this short video — soon, a virtual reality headset could also be a vital piece of equipment! It's a positive movement; that …
Mar 16
vEco integrated with UN-GRASP's new website!
vEcotourism.org is proud and delighted to announce a major project milestone: we're now integrated into the United Nations Great Apes Survival Partnership's (UN-GRASP's) new website! Click on any of the great ape's species pages and you can now enjoy virtual tours of each great ape's habitat while learning about keeping abreast of GRASP's conservation programs …
Mar 03
The theme of this year's UN World Wildlife Day, on 3rd March, is being #seriousaboutwildlifecrime and the UN-Great Apes Survival Partnership (UN-GRASP) has released a new video, which will be screened at the UN in New York, on the illegal trade in ape infants.
Apr 23
vEcotourism needs your help!
Would you like to get a sneak peek at vEco's latest and greatest innovations? Become a vEconaut! We need your help to test out the freshest content from vEcotourism.org. As a vEconaut, you will help vEcotourism to ensure it produces the best, bug-free vEcotours, bringing immersive and interactive experiences of amazing places and wildlife around …
Oct 02
iOS support in the pipeline
Apple devotees, fear not. Support for iOS devices is nearly here! While the vEcotour experience will necessarily be slightly different on iPhones and iPads than on PCs and Macs (for example, iOS only allows one sound file to be played at a time), we're doing our best to ensure that our tours will be worth …
Mar 09
vEco at the Digital Media and Learning Badges Competition
"Learning happens everywhere and at every age" In this spirit, Virtual Ecotourism participated in the 4th Digital Media and Learning Competition for the first time last week. By recognising and promoting non–traditional learning in the 21st century, this competition brought together designers, entrepreneurs, technologists and educators with leading business and industry organizations to build …
Feb 28
Virtual Ecotourism gets a makeover
Feb 20
vEco flys to San Francisco for the final round of the DML competition
Having successfully advanced through Stage I and Stage II of the Digital Media and Learning Badges for Lifelong Learning Competition, the contest organizers have invited two members of the Virtual Ecotourism team to San Francisco to pitch the project in person! With flowers in our hair, we head to San Francisco for …


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One of the gems encountered on a short walk in Lavras was a...One of the gems encountered on a short walk in Lavras was a liverwort that comes from a family that I had never encountered before – the Noterocladaceae. A bright green, charismatic liverwort, Noteroclada confluens is the sole member within its namesake family. First described in Brazil, this species has also been found in Mexico and some South Atlantic Ocea […]
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Category Archives: Ornamental Plants
Carpentaria acuminata (Arecaceae)
Carpentaria acuminata (Carpentaria Palm) is the sole species in the genus Carpentaria, which is native to tropical coastal regions in the north of Northern Territory, Australia. Due to it's attractive form and red fruits, it is widely grown in Cairns … Continue reading
Clerodendrum splendens (Lamiaceae)
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Loropetalum chinense (Hamamelidaceae)
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Schefflera actinophylla (Araliaceae)
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Hollandaea sayeriana (Proteaceae)
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Vernicia montana (Euphorbiaceae)
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Pittosporum rubiginosum (Pittosporaceae)
The Hairy Red Pittosporum is an endemic shrub that occurs in the dark shade of the rainforest understorey. I have hardly seen this species grow taller than 2-3m tall. The leaves are soft textured, hairy, largish (although very small ones … Continue reading