text:
|Publication number
|Publication type
|Application number
|Publication date
|Oct 9, 1990
|Filing date
|Jun 30, 1989
|Priority date
|Jun 30, 1989
|Fee status
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|Publication number
|Chandra V. Desphandey, Rointan F. Bunshah, Hans J. Doerr
|Original Assignee
|The Regents Of The Univ. Of Calif.
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|BiBTeX, EndNote, RefMan
|Patent Citations (8), Referenced by (86), Classifications (16), Legal Events (6)
|External Links: USPTO, USPTO Assignment, Espacenet
1. Field of the Invention
This invention relates to the process of depositing diamond, doped diamond and cubic boron nitride-diamond composite films. More specifically it relates to deposition of these films at high rates over large areas, based on Activated Reactive Evaporation (ARE) as first described in U.S. Pat. No. 3,791,852.
2. Description of the Background Art
The publications and other reference materials referred to herein to describe the background of the invention and to provide additional detail regarding its practice are hereby incorporated by reference. For convenience, the reference materials are numerically referenced and grouped in the appended bibliography.
Techniques used in recent years to deposit films of diamond-like carbon (i-C), diamond and boron nitride onto substrates have included chemical vapor deposition (CVD) and plasma assisted chemical vapor deposition (PACVD) involving plasma decomposition of hydrocarbon/boron containing gases. Ion beam assisted/enhanced deposition has also been used.
Diamond microcrystals were prepared using chemical vapor deposition and related techniques, at low pressures for the first time by Derjaguin and co-workers(1) by a chemical transport method. Subsequently Angus et al.(2) reported deposition of diamond onto natural diamond powder from methane gas at 1050° C. and 0.3 torr pressure. They also proposed a qualitative model explaining the kinetics of diamond growth from the vapor phase. More recently Matsumoto et al.(3,4), have reported synthesis of diamond microcrystals by chemical vapor deposition from a mixture of methane and hydrogen gas in open flow systems. They have shown that the growth of diamond films can be enhanced if a heated tungsten filament is used in the CVD set up. Spitsyn et al.(5) in their paper have discussed the kinetics of diamond growth from CH4 +H2 gas mixtures. They have argued that atomic hydrogen plays a unique role in the growth of diamond from vapor phase.
Whitmell et al.(6) were the first to report the use of plasma decomposition techniques in the deposition of amorphous carbon-like films onto a negatively biased d.c. electrode using methane gas. However, the growth of films in their earlier experiment was thickness limited. This was believed to be due to the formation of an insulating film (i-C) on the surface of the d.c. biased electrode which after a critical thickness was reached, prevented the bombardment of the growing film with energetic ions from the plasma. Following that report, Holland (7) proposed a modification where an r.f. potential was applied to the electrode to achieve a constant film bombardment during growth. Using this technique Holland et al.(8,9) successfully deposited diamond-like carbon films on a variety of substrates. Over the years, many researchers have used similar processes (i.e. r.f. decomposition of hydrocarbon gas) to prepare diamond-like carbon films.(10,11) Similar techniques have been used to deposit BN films, where boron containing gases are used instead of hydrocarbon gases.
The remote plasma deposition technique developed by Lucovsky et al.(12) also falls under the category of a PACVD type process. In this process a mixture of reactive and inert gas is dissociated using r.f. excitation. The activated species, e.g., oxygen, from the plasma react down stream with the process gas such as SiH4 (for SiO2 deposition) to form complexes such as H3 Si-O-SiH3 in the gas phase which subsequently condense on the substrate. Bombardment by energetic neutrals dissociate the complex to produce the compound films. This technique has been successfully used by Richard et al.(13) to prepare SiO2, Si3 N4 at low deposition temperatures. They have proposed to extend this technique to the deposition of diamond by using CH4 as a process gas and H2 or a H2 +He gas mixture for activation.
Aisenberg and Chabot(14) were the first to report deposition of diamond-like carbon films by ion-beam deposition of carbon. Attempts to deposit similar films using magnetron sputtering and r.f. sputtering were only partially successful. It is likely that negligible substrate bombardment in the case of magnetron sputtering and substrate overheating in case of r.f. sputtering may have restricted the formation of i-C films in the above two techniques.
However, the dual ion beam technique used by Weissmantel(15,16) has proved to be quite successful in synthesis of diamond-like carbon films. He used a primary beam to deposit carbon with the growing film being simultaneously bombarded by Ar+ ions generated from the second ion source. Weissmantel has successfully used this technique to deposit i-C, i-BN as well as i-C/i-BN composite coatings.
In plasma decomposition techniques, the rate of deposition of the carbon films critically depends on the rate of dissociation of the hydrocarbon gas. To increase the dissociation rate, one has to increase the gas pressure and/or the r.f. power used to excite the plasma. However, the increase in r.f. power also increases the energy of the bombarding species. Moreover, increased dissociation of hydrocarbon gas produces a greater amount of hydrogen that can be trapped into the growing films--thereby producing excessive stress in the film.
A modification has been suggested where independent sources are used, one to dissociate the hydrocarbon gas, and the other for film bombardment. One such modification is due to Nyaiesh et al.(17) who have used separate r.f. sources, one to dissociate the hydrocarbon gas and the other for substrate biasing which in turn controls the bombardment of growing film. Though this technique has shown some improvement in deposition rate, the authors note that the substrate bias was affected by the power applied to the r.f. oven. Moreover, they report that input power to the r.f. oven was limited due to deposits formed by polymerization onto the chamber walls, which reduced the deposition rate.
Another approach is proposed by Kamo et al.(18), Saito et al.(19), and also by Doi et al.(20,21), where a microwave discharge is used to decompose the hydrogen gas and an independent r.f. source is used for substrate biasing. These authors have reported deposition of i-C, diamond and boron doped diamond films using this technique. However, this technique does not appear to be much different than that of Nyaiesh et al.(17) and would therefore suffer from similar limitations. In fact, the optimum deposition rate reported by Doi et al.(21) is about 1 um/hr. which seems to be very low. Moreover, even with the above-proposed modifications, it is not possible to control the hydrogen content of the films independently of the other process variables.
Although the ion beam technique provides advantages as regards independent control of substrate bombardment, deposition rate and hydrogen content, it suffers from the following two major limitations: (1) low deposition rates due to the low sputtering yield of carbon; and (2) limitations for large area deposition due to limitations in the available sizes of the ion sources.
Strel'nitskii et al.(23) have reported deposition of i-C films using energetic C+ ions from an arc source.
As is apparent from the above background, there presently is a continuing need to provide improved processes for depositing diamond and diamond-like films on substrates. Such improved processes should be able to provide control over the rate of generation of reaction vapors e.g. C, B, etc. independently of other process parameters. The process should also provide control over the plasma volume chemistry independent of the other process variables and provide control over the film bombardment independent of the other process variables. These attributes in such a process will make it possible to deposit diamond, doped diamond and cubic boron nitride-diamond films at higher rates and over large areas.
This invention provides an improved method of synthesis of diamond films on a suitable substrate using plasma assisted physical vapor deposition techniques. The method is based on controlling the plasma chemistry in the reaction zone between the source of carbon and the substrate.
Graphite or other material used as a source for carbon is vaporized in the vacuum chamber using an electron beam, or cathodic arc to provide carbon vapors in the reaction zone. Hydrogen containing gas is introduced into the reaction zone. Gas activation as well as carbon vapor activation is achieved using a filament/anode geometry, where electrons emitted thermionically from a heated tungsten filament are accelerated towards a positively biased electrode. It is believed that the atomic hydrogen produced by electron collision with molecular hydrogen plays a crucial role in synthesis of the diamond. Atomic hydrogen thus produced enhances the evaporation rate of carbon by producing volatile carbon-hydrogen complexes at the surface of the carbon evaporation source. This reaction is stimulated by the electrons bombarding or near to the carbon source. Collision between atomic hydrogen and the evaporated carbon and/or carbonhydrogen molecules is believed to produce molecular precursors which are responsible for the synthesis and depositing of diamond films on the substrate.
The microstructure of the diamond deposit and therefore its physical and mechanical properties can be varied by changing substrate temperature and substrate bombardment. An important advantage of the above process results from its ability to control the plasma volume chemistry independent of the source and substrate reactions. This makes it possible to obtain high deposition rates and also better control over the film properties. In addition, the process may be carried out at substrate temperatures of 20-600° C.
The above-discussed and many other features and attendant advantages of the present invention will become apparent as the invention becomes better understood by reference to the following detailed description when considered in conjunction with the accompanying drawings.
The single figure of the drawing is a schematic vertical sectional view of a vacuum chamber and associated equipment suitable for performing the process of the invention and incorporating the presently preferred embodiment of the apparatus of the invention.
The preferred apparatus for carrying out the process of the present invention is a modification of the apparatus disclosed in U.S. Pat. No. 3,791,852, for carrying out Activated Reactive Evaporation (ARE) and the apparatus described by Chopra et al.(22) for carrying out Activated Dissociation Reduction Reaction processes, the contents of which are hereby incorporated by reference. The apparatus includes a vacuum chamber which may comprise a conventional cover or dome 10 resting on a base 11 with a sealing gasket 12 at the lower rim of the cover 10. A support and feed unit 13 for a source carbon rod used for evaporation 14 may be mounted in the base 11. The unit 13 includes a mechanism (not shown) for moving the carbon rod 14 upward at a controlled rate. Cooling coils 15 may be mounted in the unit 13 and supplied with cooling water from a cooling water source, 16. An electron gun 20 is mounted in unit 13 and provides an electron beam along the path 21 to the upper surface of the carbon rod 14, with the electron gun being energized from a power supply 22.
A substrate 24 on which the diamond film is to be deposited, is supported in a frame 25 on a rod 26 projecting upward from the base 10. The substrate 24 may be heated by an electric resistance heater 27 supported on a bracket 28. Energy for the heater 27 is provided from a power supply 29 via a cable 30. The temperature of the substrate 24 is maintained at a desired value by means of a thermocouple 32 in contact with the upper surface of the substrate 24, with the thermocouple connected to a controller 33 by line 34, with the controller output signal regulating the power from the supply 29 to the heater 27.
The desired low pressure is maintained within the vacuum chamber by a vacuum pump 36 connected to the interior of the chamber via a line 37. Gas from a gas supply 39 is introduced into the zone between the carbon rod 14 and substrate 24 via a line 40 and nozzle 41. A shutter 43 is mounted on a rod 44 which is manually rotatable to move the shutter into and out of position between the carbon rod 14 and substrate 24.
A tungsten filament 46 is supported from the base 11 in the reaction zone between the source 14 and the substrate 24. The filament 46 is thermionically heated using a supply 47 via line 48. An anode, typically a metal plate 49, is supported from base 11 opposite to the filament 46. An electric potential is provided for the anode 49 from a voltage supply 50 via line 51.
Various components utilized in the apparatus described above are conventional. The evaporation chamber 10 is preferably a 24 inch diameter and 35 inch high water cooled stainless steel bell jar. The vacuum pump is preferably a 10 inch diameter fractionating diffusion pump, with an anti-migration type liquid nitrogen trap. The source carbon unit 13 is preferably 1 inch diameter rod fed electron beam gun, self-accelerated 270° deflection type, such as Airco Temescal Model RIH-270. The power supply 22 is preferably an Airco Temescal Model CV30 30kW unit which may be operated at a constant voltage such as 10 kilovolts, with a variable emission current.
Various sizes and shapes of substrates can be utilized. Various substrates such as stainless steel, molybdenum, glass, quartz, silicon etc. have been used. In a preferred embodiment, the substrate is based about 8" above the surface of the carbon source 14. The heater 27 may be a 4 kilowatt tungsten resistance heater providing for heating the substrate to 700° C. and higher. Temperatures in the range of 600 to 1000° C. may be used. However, it was discovered that substrate temperatures in the range of 20-600° C. are also suitable for growing smooth, non-faceted, optically transparent films. Preferably, the substrate is not heated, but rather allowed to remain at room temperature or the temperature to which the substrate is warmed during the deposition process. The reactions that produce molecular precursors required for synthesis of diamond film take place primarily in the vapor phase in the reaction zone and/or on the surface of the carbon evaporation source. These reactions are independent of substrate temperature. However, as discussed below the properties and structure of the film is dependent on substrate temperature and bombardment.
The source of carbon may be a solid rod or billet. For the feed unit mentioned above, the rod is 0.975 inches diameter and 6" long. Appropriate alloys can be used to obtain p or n type doping in the films. An arc source can also be used to provide carbon vapors.
Hydrogen gas which dissociates to form atomic hydrogen is introduced via a series of needle valves. The preferred range of pressure is 2×10-4 to 20×10-3 torr. In addition to hydrogen, hydrocarbon gases such as methane, ethane, etc. can be used to provide atomic hydrogen and the molecular fragments necessary for diamond growth. Mixtures of the above gases with hydrogen are also used. Additionally, argon has also been used with hydrogen and/or hydrocarbon gases to enhance the plasma volume chemistry in the region between the source and the substrate and to increase the density of precursors necessary for the growth of diamond films.
The filament 46 provides electrons for dissociating and ionizing the gases and the evaporated carbon vapor. The filament 46 is thermionically heated using a d.c. supply 47. A.C. can also be used for heating the filament. The electrons emitted from the heated filament 46 are accelerated to an anode 49, to which a d.c. potential is applied from a d.c. supply 50. The usual potential is in the range of about 80 volts, however higher voltages may be used if desired, by using a R.F. plasma Therm d.c. power supply. An a.c. potential as well as r.f. excitation with effective d.c. bias in similar voltage range has also been used.
As examples diamond films can be produced by using the above apparatus utilizing carbon evaporation in H2, CH4, H2 +CH4, H2 +Ar,H2 +Ar+CH4 gases and gas mixtures.
Doped diamond films are also possible. Boron is an excellent p-type dopant for diamond. For n-type doping Al and Li can be used. Boron doped films can be prepared by evaporating carbon in a plasma of Ar+CH4 (or Ar+CH4 +H2 or any other hydrocarbon gas preferably with SP3 bonding) and boron containing gas such as B2 H6. For aluminum doping, metal-organic compounds such as trimethyl aluminum vapors can be used. For lithium doping, Li can be co-evaporated with carbon in Ar+CH4 plasma. Cubic boron nitride (CBN)-diamond composite films can be prepared by co-evaporating Boric acid/boric oxide and carbon in CH4 +N2 /CH4 +H2 plasma. The possible reactions leading to the formation of the CBN-diamond composite films are:
CH4 →C+CHx +H
CHx +CHx +H→C-C+H
The above are a few of the likely reactions. In addition, a variety of other reactions can take place depending on the energy, concentration and nature of the reactive species (excited, ionized, etc.) in the plasma volume. Glow discharge optical spectroscopy can be used to study the plasma chemistry and optimize plasma conditions to obtain CBN-diamond films.
Examples of practice are as follows:
The vacuum chamber was initially pumped down to 10-6 torr pressure and then purged with inert gas to 10-4 torr for a few times. The chamber was again pumped down to 10-6 torr. This procedure was used to minimize the presence of extraneous gases.
When pressure in the chamber was again down to 10-6 torr, the filament 46 was slowly heated to the desired temperature of about 1000° C. One of the above gases was then introduced in the vacuum chamber at a controlled rate to obtain a desired pressure. Pressure ranged from 2×10-2 torr to about 1×10-3 torr. Anode potential was then applied to obtain required anode current. The electron beam was turned on to heat the upper end of the carbon rod 14. The shutter 43 was in position blocking the substrate 24. When steady state conditions were obtained, the shutter 43 was moved to one side and films were deposited on the substrate 24. The process was continued until the desired thickness of film was obtained after which the shutter 43 was moved to the blocking position and the various supplies were turned off.
The same system and process as in Example 1 was used. The carbon was evaporated in an H2 plasma. The H2 flow rate was maintained at 150 SCCM and the chamber pressure was kept constant around 10-3 torr. The plasma was excited using anode/cathode geometry. Plasma cathode voltage was adjusted so as to maintain mean electron energy in the range of 10-15 eV. The substrates were biased to -600 volts. Films were deposited under these conditions onto room temperature silicon substrates. The films showed predominantly diamond phase. Surface smoothness of the films was better than 200 Angstroms.
Films were deposited onto quartz substrates under conditions similar to Example 2. The films showed excellent transmission down to 190 nm. Optical gap of the films was measured to be around 5.2 eV corresponding to diamond phase.
Films were deposited onto a NaCl substrate under conditions similar to Example 2. Electron diffraction of the film confirmed the diamond phase in the films.
Films were deposited on Si, NaCl, glass and quartz substrates under the conditions similar to Example 2, except that the substrates were kept at a floating potential and substrate temperature was maintained around 300° C. Films deposited under these conditions also showed diamond phase. The films showed surface smoothness of better than 200 Angstroms and excellent UV-VIS-IR transmission.
Films were deposited under conditions similar to Example 2 except that the substrates were grounded.
Films were deposited under conditions similar to Example 2 except H2 +Ar (70:30) was used instead of H2.
Films were deposited under similar conditions as Example 2 except that H2 +CH4 (4:1) was used instead of H2 to form the plasma.
Films were deposited under similar conditions as Example 2 except that H2 +Ar+CH4 (1:1:1) was used instead of H2 to form the plasma.
Films were depOsited under conditions similar to Example 3 except that H2 +Ar (1:1) was used instead of H2 to form the plasma.
Films were deposited under conditions similar to Example 4 except that H2 +Ar (70:30) was used instead of H2 to form the plasma.
Films were deposited under conditions similar to Example 3 except that H2 +CH4 (4:1) was used instead of H2 to form the plasma.
Films were deposited under conditions similar to Example 4 except H2 +CH4 (4:1) was used instead of H2 to form the plasma.
Films were deposited under conditions similar to Example 3 except that H2 +Ar+CH4 (1:1:1) was used instead of H2 to form the plasma.
The gas pressure within the chamber, the anode potential and electron beam current required to produce the diamond films are interrelated and may be varied over a substantial range. With higher electron beam currents it is required to increase the partial pressure of hydrogen gas and the anode potential to obtain desired films. For example, successful formation of diamond films can be achieved in the range of 600 watts -1.5 kw with gas partial pressure in the range of 10-3 to 2×10-2 torr.
H2, CH4, H2 +CH4, Ar+CH4, Ar+H2 +CH4 gases have been used. Use of hydrocarbon gas such as CH4 and its mixture with H2 and/or Ar enhance the electronmolecular reactions producing appropriate precursors necessary for growth of diamond films.
The acts of precursor formation and deposit growth are separate steps in this process. The character of the deposit changes with substrate temperature and bombardment. For given conditions the deposit transforms from transparent/insulating type to absorbent/conducting type back to transparent/insulating type with increasing substrate temperature. The above transformation corresponds to the formation of diamond-like i-C films, graphitic films, diamond films, respectively. At low substrate temperature, the film growth is essentially controlled by the reaction occurring in the region between the source and the substrate.
As the temperature of the substrate increases beyond a critical value, substrate reactions also comes into play. At this temperature the condensing species tend to nucleate into graphitic structure. When the temperature is further increased a point is reached beyond which transparent diamond films can be formed. It is believed that the condensation of the graphitic phase in this temperature range is prevented by the competitive process of etching of graphite by atomic hydrogen since the etching rate increases with temperature.
It has been found that the film properties can be controlled by changing the partial pressure of reactive gas, evaporation rate and substrate temperature/bombardment. As an example, with a carbon evaporation rate of 0.2 gms/min and a hydrogen partial pressure of 10 millitorr, transparent and insulating films of diamond are deposited at a ate of 3 um/hr at source-to-substrate distance of 8". Higher deposition rates could be achieved by adjusting the electron beam current and H2 partial pressure appropriately or decreasing the source to substrate distance. Higher or lower rates may be obtained by varying the process parameters of the system. The carbon evaporation rate may be controlled by varying output of electron gun 20 and gas pressure may be controlled by adjusting a valve 59 in the gas line 40.
Having thus described exemplary embodiments of the present invention, it should be noted by those skilled in the art that the within disclosures are exemplary only and that various other alternatives, adaptations and modifications may be made within the scope of the present invention. Accordingly, the present invention is not limited to the specific embodiments as illustrated herein, but is only limited by the following claims.
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2. J. C. Angus, H. A. Will and W. S. Steinko, J. Apl. Phys. 39(6), 2915, 1968.
3. S. Matsumoto, Y. Saito, M. Kano and N. Setaka, Jap. J. Appl. Phys., 21, L163, 1982.
4. S. Matsumoto, Y. Saito, M. Tsutsumi and N. Setaka, Jour. Mater. Sci. 17, 3106, 1982.
5. B. V. Spitsyn, B. V. Derjaguin, L. L. Builov, A. A. Klochkov, A. E. Gorodetskii and A. V. Smoi'yanihov, Sov. Phys. Dokl, 21 676, 1976.
6. D. S. Whitmell and R. W. Williamson, Thin Solid Films, 35, 255, 1976.
7. L. Holland, U. K. Patent No. 1582231, Aug. 76.
8. L. Holland and S. M. Ojha, Thin Solid Films, 38, L17, 1976.
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10. H. Vora and T. J. Moravac, J. Appl. Phys., 52, 6151, 1981.
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12. G. Lucovsky, P. D. Richards and R. J. Markura, paper presented at workshop of Dielectric Systems for III-V Semiconductors, San Diego, CA, May 26-27, 1984.
13. P. D. Richard, R. J. Markunas, G. Lucovsky, G. G. Fountain, A. N. Mansour and D. V. Tsu, J. Vac. Sci. echnology, J. Vac. Sci. Technol. A3(3), 867, 1985.
14. S. Ainsberg and R. Chabot, J. Appl. Phys. 42, 2953, 1971.
15. C. Weissmantel, Thin Solid Films, 35, 255, 1976.
16. C. Weissmantel, K. Breuer and B. Winde, Thin Solid Films, 100, 383, 1983.
17. A. R. Nyaiesh, R. E. Kirby, F. K. King and E. L. Garwin, J. Vac. Sci. Technol. A3(3), 610, 1985.
18. M. Kamo, Y. Sato, M. Matsumoto and N. Setaka, J. Cryst. Growth, 62, 642, 1983.
19. Y. Saito, S. Matsuda and S. Nogita, Mat. Sci. Letter, 3, 565, 1986.
20. A. Doi, N. Fujimori and T. Yoshioka, Proc. Int. Ion Energy Congress. p. 1137, Institute of Electronic Engineering of Japan, Tokyo, 1983.
21. N. Fujimori, T. lmai and A. Doi, Vacuum 36, 99, 1986.
22. K. L. Chopra, V. Agarwa, V. D. Vankar, C. V. Deshpandey and R. F. Bunshah, Thin Solid Films, 126, 307, 1985.
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|Sep 6, 2005
|Cardinal Cg Company
|Soil-resistant coating for glass surfaces
|Feb 2, 1999
|Nov 15, 2005
|Cardinal Cg Company
|Soil-resistant coating for glass surfaces
|Aug 6, 1999
|Dec 13, 2005
|Cardinal Cg Company
|Low-emissivity, soil-resistant coating for glass surfaces
|Jan 24, 2000
|Mar 14, 2006
|Sony Corporation
|Method and apparatus for film deposition
|May 22, 2003
|Oct 9, 2007
|Medtronic, Inc.
|Method of manufacture of smart microfluidic medical device with universal coating
|Aug 2, 2004
|Nov 13, 2007
|Cardinal Cg Company
|Soil-resistant coating for glass surfaces
|Dec 22, 2004
|Nov 13, 2007
|Cardinal Cg Company
|Graded photocatalytic coatings
|Jul 3, 2003
|Jun 24, 2008
|Aeromet Technologies, Inc.
|Simple chemical vapor deposition system and methods for depositing multiple-metal aluminide coatings
|Aug 20, 2004
|Feb 17, 2009
|Cardinal Cg Company
|Methods and apparatuses for depositing film on both sides of a pane
|Jul 12, 2005
|Oct 20, 2009
|Cardinal Cg Company
|Low-maintenance coatings
|Jan 17, 2006
|Apr 27, 2010
|Applied Materials, Inc.
|Remote plasma pre-clean with low hydrogen pressure
|Jul 12, 2005
|May 11, 2010
|Cardinal Cg Company
|Low-maintenance coatings
|Apr 9, 2007
|Jan 11, 2011
|Vapor Technologies, Inc.
|Valve component for faucet
|Jun 18, 2008
|Jan 11, 2011
|Masco Corporation Of Indiana
|Dec 2, 2005
|Apr 12, 2011
|Cardinal Cg Company
|Hydrophilic coatings, methods for depositing hydrophilic coatings, and improved deposition technology for thin films
|Apr 16, 2007
|Aug 2, 2011
|Cardinal Cg Company
|Opposed functional coatings having comparable single surface reflectances
|May 16, 2005
|Jan 10, 2012
|Cardinal Cg Company
|Methods and equipment for depositing hydrophilic coatings, and deposition technologies for thin films
|Jun 15, 2010
|Feb 21, 2012
|Vapor Technologies Inc.
|Valve component for faucet
|Jul 1, 2008
|Feb 28, 2012
|Vapor Technologies Inc.
|Method of producing an article having patterned decorative coating
|Aug 18, 2010
|Jul 17, 2012
|Vapor Technologies Inc.
|Faucet with wear-resistant valve component
|Sep 3, 2010
|Aug 13, 2013
|Cardinal Cg Company
|Low-maintenance coatings, and methods for producing low-maintenance coatings
|Dec 17, 2009
|Oct 15, 2013
|Vapor Technologies Inc.
|Faucet component with coating
|Sep 3, 2010
|Apr 15, 2014
|Cardinal Cg Company
|Low-maintenance coating technology
|Jun 19, 2008
|Sep 23, 2014
|Mt Coatings, Llc
|Simple chemical vapor deposition systems for depositing multiple-metal aluminide coatings
|Sep 9, 2013
|Jul 12, 2016
|Delta Faucet Company
|Faucet component with coating
|Feb 11, 2002
|Aug 14, 2003
|Board Of Trustees Operating Michigan State University
|Process for synthesizing uniform nanocrystalline films
|Nov 20, 2003
|Jun 24, 2004
|Xi Chu
|Prosthetic valves and methods of manufacturing
|Jan 7, 2004
|Jul 15, 2004
|Hideo Yamanaka
|Film forming method and film forming apparatus
|Jul 3, 2003
|Jan 6, 2005
|Aeromet Technologies, Inc.
|Simple chemical vapor deposition system and methods for depositing multiple-metal aluminide coatings
|Jan 17, 2006
|May 24, 2007
|Applied Materials, Inc.
|Remote plasma pre-clean with low hydrogen pressure
|Apr 16, 2007
|Oct 25, 2007
|Cardinal Cg Company
|Opposed functional coatings having comparable single surface reflectances
|Jul 4, 2006
|Sep 10, 2009
|Masataka Hasegawa
|Carbon film
|Oct 12, 2011
|Nov 20, 2012
|Cardinal Cg Company
|Low-maintenance coatings
|Oct 12, 2011
|Apr 16, 2013
|Cardinal Cg Company
|Low-maintenance coatings
|Feb 26, 1992
|Sep 23, 1992
|General Motors Corporation
|Carbon-alloyed cubic boron nitride films
|Feb 26, 1992
|Nov 19, 1992
|General Motors Corporation
|Carbon-alloyed cubic boron nitride films
|Mar 22, 1995
|Jan 29, 1997
|Southwest Research Institute
|Treatments to reduce frictional wear between components made of ultra-high molecular weight polyethylene and metal alloys
|Mar 22, 1995
|Feb 25, 1998
|Southwest Res Inst
|Treatments to reduce frictional wear between components made of ultra-high molecular weight polyethylene and metal alloys
|U.S. Classification
|427/577, 427/530, 427/249.8, 423/446, 427/906, 427/528, 427/523
|International Classification
|Cooperative Classification
|European Classification
|Jun 30, 1989
Owner name: REGENTS OF THE UNIVERSITY OF CALIFORNIA, THE, 300
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:DESPHANDEY, CHANDRA V.;BUNSHAH, ROINTAN F.;DOERR, HANS J.;REEL/FRAME:005099/0274
Effective date: 19890628
|Apr 4, 1994
|Fee payment
Year of fee payment: 4
|Mar 17, 1998
|Fee payment
Year of fee payment: 8
|Apr 23, 2002
|Maintenance fee reminder mailed
|Oct 9, 2002
|Lapse for failure to pay maintenance fees
|Dec 3, 2002
|Expired due to failure to pay maintenance fee
Effective date: 20021009


text:
Staff blogs
James Love
Manon Ress
Thiru Balasubramaniam
Andrew Goldman
Claire Cassedy
Diane Singhroy
Kim Treanor
KEI Staff
2017 R&D Cost Transparency Proposals in the United States
Submitted by Zack Struver on 10. March 2017 - 12:17
On March 9, 2017, KEI was scheduled to testify before the Maryland House Committee on Health on HB 666, a bill that would require an annual report on R&D costs from drug companies that sell high-priced medicines in the state of Maryland.
In advance of the hearing, I prepared a note that summarizes provisions in both transparency and pharmaceutical price gouging legislation that would require the disclosure of the costs associated with research and development. This note is a less detailed version of this 2016 summary.
This year, so far, legislators in 13 states have introduced 21 bills that would require some degree of transparency.

subset: commoncrawl


text:
Whats your favorite type of clothing or style or shoes on a women.
Most Helpful Guy
1. For going out: A nice, tight, little black dress.
2. For day-to-day, a slightly oversized men's dress shirt and tight, low-rise jeans.
3. Hate, HATE, *HATE* panty hose! If you have to wear something of that kind on your legs, they should be stockings with garters. (Tights in the winter are OK with a short skirt.)
4. NEVER wear stockings or the like with open-toed shoes - you look like my grandma.
5. Heels. High.
6. I prefer open-toed shoes to closed.
7. Cute toes are a must! French pedicures get me revved like nothing else.11|01|0
OMG The little black dress is amazing. It's the first thing that came to mind!


text:
I love to work on the edges of communication and innovation to create human-centered experiences, products, and services that provoke thoughts and smiles. With talented friends and great companies I bridge the gap between physical and digital, data and emotions, industry and nature. Have a look below at my interactive installations ,products , services and award winning campaigns
As an artist I create interactive installations that aim to deliver an empowering experience.
As an entrepreneur I create, design and market sustainable and pioneering products and new services.
As creative I have created truly global and award winning work for brands and agencies like Coca Cola, Heineken, Nike, Wieden+Kennedy, BBH Shanghai, Akqa and many others.


text:
Beware of The Jones Act: Carnival Inspiration Cruise Review by So Cal Cruise Mom
Overall Member Rating
Beware of The Jones Act
Destination: Mexican Riviera
Embarkation: Los Angeles
With a 9-hole mini golf course, Carnival WaterWorks water park, and a tropical resort-style pool, guests were enjoying the outside entertainment as the ship set sail to Catalina Island.
My interior cabin, without a window, can accommodate four guests, yet is cozy for two people. The bed was comfortable and the bath efficient.
There are two main dining rooms on the cruise and a sushi bar. Up on the Lido deck is a Mongolian BBQ, New York style deli, pizzeria, and bountiful salad bar. I dined in the main dining room and met my table mates. The vegetarian dishes were terrific.
I was having a great time on the Inspiration watching the entertainment and strolling the various decks, until I received a call from home. My daughter had recently been involved in an auto More accident and my family needed me.
Since our first port was Catalina Island, I took an early boat the next morning into the city of Avalon and walked to The Catalina Express ticket office to see how quickly I could return to Long Beach. It's about a one-hour boat ride to Long Beach.
After purchasing a one-way ticket home, I hopped back onto a boat to the Inspiration. I needed to inform guest services of my predicament. To my shock, a guest service agent informed me that I was not allowed to disembark in an American port due to the Jones Act. I could leave the ship in Ensenada, Mexico, but not in Catalina, California.
How would I get back to the Carnival cruise terminal in Long Beach from Ensenada? Take a taxi to an airport, purchase a ticket to fly to Long Beach or LAX, and then take a cab to the cruise terminal? Or I could hire a taxi or bus to the Mexican/California border, then catch a cab to Long Beach? Both made my head dizzy with fear and anxiety.
The guest service agent gave me another option after seeing my face pale with worry. She could email a message to a Customs official about my dilemma. There was no guarantee that Customs would allow me to disembark in an American port, however, if they granted my permission, I would have to pay a $300 fine for leaving the cruise ship. $300? That is how much I paid for my share of the cruise. Instead of a $600 trip, it would now cost $900.
The guest service agent asked if I would be waiting in my cabin until she received a reply from Customs. I asked if I could leave the ship to sightsee Catalina Island and then come back to hear my fate? She gave me a phone number to contact her and asked for my cell phone number.
Jack and I didn't take any excursion in Catalina. I packed my bags, and we took a Shore boat into Avalon. Thoughts raced through my head as we tried to figure out my best strategy to get home. Could Carnival Cruise Lines and Customs force me to stay onboard until we arrived in Ensenada? You bet. What if I just stayed in Avalon until my Catalina Express boat set sail? That would probably bring on a whole new slew of problems.
Just before noon, I couldn't wait any longer and called the phone number the guest service lady handed me. It was a ship-to-shore number. An automated operator informed me that each minute would cost $9.75. Since I wasn't speaking to a live person, I could easily accumulate $100 worth of minutes, before my call was connected to a live voice. Instead, I boarded a Shore boat and returned to the Carnival Inspiration.
Good News! The Custom official approved my disembarkation, the bad news, I would have to pay a $300 fine now.
I was so relieved that I would now be home to my family within hours and not have to deal with trying to get home from Mexico, that I paid my fine and walked off the ship.
When I returned home, I did my research about the Jones Act. President Woodrow Wilson signed the Jones Act in 1917. Also known as the Merchant Marine Act of 1920, it's intention was to ensure that the U.S. has a strong merchant marine during times of war. All goods that move between two domestic ports must do so on ships that are U.S. flagged and staffed. It prohibits foreign ships from touching two U.S. ports consecutively. I was considered "goods."
Today only 1% of the large commercial vessels are built in the United States. Most of the ships are built in Italy and Finland and fly foreign flags to avoid paying higher taxes and wages to American employees.
There is also a piece of U.S. legislation called the Passenger Vessel Services Act of 1886, which relates to cabotage. It states that "No foreign vessels shall transport passengers between ports or places in the United States, either directly or by way of a foreign port, under a penalty of $200 (now $300) for each passenger so transported and landed."
Cruise ships pass the cost to passengers, however exemptions are available in case of a family emergency. To penalize a passenger who paid for a four-day cruise, yet needs to leave the cruise vacation early, is unfair. Less
Published 01/09/13
Cabin review: A
Port and Shore Excursions
Read Cruise Critic's Carnival Inspiration Review >>
First and last cruise ever!
The service makes this cruise ...
First time cruiser, wasn't sur...
Not bad for what it is
Pleasantly surprised by Carniv...
Truly "The Fun Ship"
Annual family vacation
Sponsored Links


text:
$ 34.99
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text:
Adelina Patti(1843-1919), Singer; sister of Carlotta Patti
Sitter associated with 55 portraits
Celebrated soprano; the daughter of two Italian singers, she first sang at a concert in 1850, and made her operatic debut as Lucia, 1859. Thereafter she became an international opera star and enjoyed unparalleled popularity in a wide variety of roles, being admired both for her resonant singing voice and her dramatic talent. A particular favourite in Britain, she retired to a house in Wales.
by Nadar (Gaspard Félix Tournachon)
albumen cabinet card, circa 1887
NPG x197481
by Herbert Rose Barraud, published by Eglington & Co
carbon print, published 1889
NPG Ax5451
by Herbert Rose Barraud, published by Eglington & Co
carbon print, published 1889
NPG x12688
Members of the cast of 'Iolanthe' and others
by and after Elliott & Fry
bromide print, 1890s
NPG Ax139921
by Walery, published by Sampson Low & Co
carbon print, published January 1890
NPG Ax38315
published by Ogden's
cigarette card, published circa 1894-1907
NPG x197013
by Walery
carbon print, published 1 May 1895
NPG Ax28878
published by Rotary Photographic Co Ltd
bromide postcard print, 1900s
NPG x196880
by Hayman Seleg Mendelssohn
halftone reproduction tear sheet, published 22 April 1903
NPG x136554
printed by M & N Hanhart
coloured lithograph, 1860s
published by Charles Sheard, after Unknown artist
lithograph, circa 1870s
by Adolphe Paul Auguste Beau
albumen print on card mount, 1861
NPG x31027
Adelina Patti in costume for six different roles
by Camille Silvy
albumen photomontage, 1866 (circa 1861)
NPG Ax59127
Adelina Patti in costume for six different roles
by Camille Silvy
albumen photomontage, 1866 (circa 1861)
NPG Ax59128
by W. & D. Downey
copy print, 1868
NPG x32979
Related People
- Rolf, Baron Cederström (husband)
- Henri Roger de Cahuzac, Marquis de Caux (husband)
- Carlotta Patti (sister)
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text:
Immediately sign me up for an educational opportunity...do that and I'll link up with facebook (I may anyway now ;-) )
ahhh...dreams.....yup those still feel good
Think ill check out the movie that was mentioned as well to see how they manipulate another wealthy persons life story outta spite or bandwagon banking. It's always good for a laugh though usually movies like that usually end up offending someone, and not saying anything against this movie but most movies like this usually are just taking shots at people.
ahh well it led me to this article which made me realize he has donated one of the largest sums of money ever...right up there with rockefeller
For this, what ever I personally think of Facebook is regardless to this level of generosity tax write off or not... I may just think a bit differently of this man now. But I will never know him and therefor could never really size him up. So a standing ovation and a welcome big guy to the world of philanthropy, it is refreshing to see wealthy people who can use the paper they have piled up to write out a new lease on life for many people who have yet to be fortunate enough to reach any level of enlightenment.
Thanks for putting substance behind the practice you preach.
You have exemplified social networking and now you promoting good communication with solid cognition in the form of monies for a scholastic Facelift.
Hats off.


text:
What is JotForm?
JotForm is a free online form builder which helps you create online forms without writing a single line of code. No sign-up required.
At JotForm, we want to make sure that you're getting the online form builder help that you need. Our friendly customer support team is available 24/7.
We believe that if one user has a question, there could be more users who may have the same question. This is why many of our support forum threads are public and available to be searched and viewed. If you'd like help immediately, feel free to search for a similar question, or submit your question or concern.
JotForm Support
Hello Isaac,
You need to grab your form's desired embed code and add it in your web page. The following guides should help you:
Hope this helps.
Do get back to us if you have any questions.
Thank you!
Hi Ashwin,
I'm using the Embed Code drag and drop in a Weebly template, and I've tried the Embed and Popup codes, but is there a better one, one for my platform?
You can try the Iframe method if the regular embed code and popup doesn't work for you. Here's a complete guide how to embed your form to weebly.com http://www.jotform.com/help/215-Adding-a-Form-to-Weebly.
I have moved your new concern about missing information received in email here http://www.jotform.com/answers/439059. We'll be answering you on that thread.


text:
Phyllo (Filo) Strudel With Port Wine Sauce
Be the first to review
READY IN: 1hr
Recipe by Wish I Could Cook
From the cookbook "The Accidental Vegetarian" by Simon Rimmer. The author describes this recipe as the one that "made" his restaurant 'Greens' in Manchester, England. He adds that if one is to make only one recipe from his cookbook, this is the one to make. I agree! After making this several times, I've decided the wine sauce isn't worth the effort. The strudel itself is where the yum comes from. (And feel free to substitute puff pastry to make this an easy dinner.)
See Discussion:
Ingredients Nutrition
For the strudel
- 7 ounces button mushrooms, halved
- 1 garlic clove, crushed
- 7 ounces leeks, chopped (white parts)
- 9 ounces ricotta cheese
- 9 ounces cream cheese, room temperature
- 3 tomatoes, skinned, seeded and chopped
- 18 sheets phyllo dough (9x6 inch)
- melted butter
- olive oil (for frying)
- salt
For the sauce
- 1 (750 ml) bottle red wine
- 1 bay leaf (optional)
- 2 tablespoons olive oil
- 1 large onion, sliced
- 3 ounces button mushrooms, sliced
- 2 garlic cloves, crushed
- glug port wine
- 1⁄2 cup vegetable stock
- 2 tablespoons cold butter, cubed
- pepper
Directions See How It's Made
- For the strudel:.
- Heat olive oil in pan, add mushrooms and garlic and saute for a few minutes or until starting to become soft. Drain well.
- Saute the leeks until tender.
- Mix the cheeses together with salt, pepper and other seasonings of your liking (I use herbes de provence.) Fold in the mushrooms, leeks and tomatoes. Chill for a couple of hours.
- Preheat oven to 400°F Lay out 6 sheets of phyllo on a lightly floured surface and brush with melted butter. Cover with layer two, more melted butter, then layer three. Brush butter only on the edges of the top layer.
- Divide the chilled filling into six long "sausages" and place one on the bottom edge of the phyllo rectangle. Fold the bottom edge over the filling, tuck in the sides and roll up into a tight parcel. Brush with butter and place on baking sheet.
- Bake for 25 minutes until crisp and golden.
- For the sauce:.
- Pour the wine into a pan, bring to boil and reduce by half. (Add the bay leaf to the wine if you want it a little more "herby.").
- Heat the olive oil in a saute pan and cook the onion, mushrooms and garlic with a seasoning of your choice.
- Add a big glug of port and reduce by half.
- Pour in the reduced wine and bring back to a boil. Then add the stock. Bring back to a boil and cook for 15 minutes.
- Just before serving whisk in the cold butter to give it a really great shine.
- To serve, pour a little sauce on each plate and set a strudel on top.


text:
Oblivion » Search results
Jump to page
0 30New Sigil Stone and TricksWell there's nothing special to be written in small description Some tricks few people know or maybe no one noticed it yet about enchanting weapsReleased: 27/07/2017 - 01:36PMUpdated: 27/07/2017 - 01:36PM
by leetpixie2
2 32Oblivion How to Add New Furniture Markers To A Piece Of FurnitureThis is a small tutorial showing Modder's how to add Furniture Markers to a piece of Furniture in NifskopeReleased: 25/07/2017 - 07:00PMUpdated: 25/07/2017 - 07:00PM
by Stephen999
9 95OCSS - English VersionAn English translation of tbsk's Oblivion Combat Skill System (OCSS).Released: 25/07/2017 - 01:54PMUpdated: 25/07/2017 - 01:55PM
by a_rod
0 18Comfortable Clothing RevisitedThe menfolk of Cyrodiil receive another makeover, thanks to Comfortable Clothing by LoginToDownload and the wonders of dynamic adding. Number 18 in the Clothing Building Block series.Released: 25/07/2017 - 12:37PMUpdated: 25/07/2017 - 12:37PM
by Myrystyr
1 16Shady NickA CM follow i made as a tribute to my best friend.Released: 24/07/2017 - 08:33PMUpdated: 24/07/2017 - 08:36PM
by gardara
1 31Drink More PotionsThis mod allows you to drink more potions.Released: 24/07/2017 - 01:01PMUpdated: 24/07/2017 - 01:03PM
by MarkusMarcion
19 280Dreadlocks (replacer)Replaces the Redguards "Ridge Rows" hairdo with fancy dreads.Released: 23/07/2017 - 04:35PMUpdated: 25/07/2017 - 12:07AM
by T3alrose
9 115LittleHotkeyOverhaulExtendedToggle between 2 weapons which each has an own quickbar; spells get directly triggered by hit on hotkey; now extended by a hotkeybar in gamemode when weapon is out for better overviewReleased: 23/07/2017 - 05:01AMUpdated: 24/07/2017 - 10:02PM
by jobra888
0 9DD Alchemy Ingredient Transfer Script ResourceThis resource is a script that you can attach to a container to allow the player to choose between "Browse Ingredients" and "Transfer Ingredients" when activating the container.Released: 22/07/2017 - 01:36PMUpdated: 23/07/2017 - 10:22PM
by iamnone
2 54Sigil keep selectorExplore the random sigil keeps according to your decisions. Don't let the game choose any longer instead of you. Don't lose your time saving, reloading and crashing to desktop to reach the random sigil keep you want.Released: 22/07/2017 - 01:17PMUpdated: 22/07/2017 - 10:59PM
by Oblivionaddicted
0 14Psycho RaceThe looks of an Imperial with red eyes and elven spikes.Released: 22/07/2017 - 11:25AMUpdated: 22/07/2017 - 12:22PM
by UndeadDremora
2 33Girlish Bare Shoulder Dresses RevisitedGirlish Bare Shoulder Dresses by Miche and Retma, now available for purchase at selected vendors. The latest attempt to clear away containers cluttering up our game. Number 4 in the Nailflan Couture series.Released: 21/07/2017 - 04:08PMUpdated: 21/07/2017 - 04:08PM
by Myrystyr
8 106ClassicRucksack ResourceReleased: 20/07/2017 - 03:04AMUpdated: 20/07/2017 - 03:04AM
by jobra888
1 24Alluring Potion Bottles - OOOExtended patchSince I noticed the bashed patch is having important issues importing Alluring' Potion Bottle's graphic changes while keeping the stats of OOOExtended, I decided to manually adapt the former to the latter.Released: 20/07/2017 - 12:12AMUpdated: 20/07/2017 - 12:12AM
by Saldron613
2 93Power of ChaosThe Mod add a new unique Magic for a true Dark Lords in the Game!Released: 20/07/2017 - 12:04AMUpdated: 10/08/2017 - 01:34PM
by nibiros13
2 137Midas Magic Addon SetsMidas Magic Addon sets Midas Magic Creatures Addon Midas Magic for NPC AddonReleased: 18/07/2017 - 11:25PMUpdated: 20/07/2017 - 12:33PM
by tokage3
2 80Military Tent - Player HomeReleased: 18/07/2017 - 03:50PMUpdated: 18/07/2017 - 03:50PM
by Brucejones2
11 445Sexy Armor For SaleThis mod is a non-replacer version of duddly01's HGEC Sexy Armor Replacer (also known as HGEC More Revealing Standard Armor). You can purchase the sexy armor variants at Hammer and Tongs in Skingrad or Stonewall Shields in the Imperial City.Released: 18/07/2017 - 01:21PMUpdated: 18/07/2017 - 01:48PM
by iamnone
1 33HGEC Mystix RevisitedHGEC Mystix clothing and armour by Shadowborne, now available for purchase in the Imperial City Market District, and lootable from bandits. Number 17 in the Clothing Building Block series.Released: 18/07/2017 - 12:01PMUpdated: 18/07/2017 - 12:01PM
by Myrystyr
2 18Servant of the Dawn 2.25 for SI- Mod traducido al Castellano¿Cansado de ser el recadero del mundo entero? ¿El héroe de todos, dedicado en cuerpo y alma a salvar el mundo? ¿ Encarnas un personaje con tendencia malvada/caótica? Entonces, este mod es para ti. Prosigue la trama principal desde el punto de vista del debilitado Amanecer Mítico y conviértete en un servidor de Lord Dagon.Released: 18/07/2017 - 12:05AMUpdated: 18/07/2017 - 12:08AM
by JFORTE77
26 674cloud ruler temple - cloudsan immersion mod for the blades templeReleased: 17/07/2017 - 04:51PMUpdated: 17/07/2017 - 04:51PM
by discovery1
6 82LittleHotkeyOverhaulI didn't like it to hit the quickkey and then the cast button. I found 8 hotkeys are not enough. I like to specify a special key to swap between two weapons.Released: 17/07/2017 - 03:01PMUpdated: 21/07/2017 - 05:00AM
by jobra888
45 1,192Elven armor replacerReplaces elven armor with new remodelled version.Released: 16/07/2017 - 03:03AMUpdated: 17/07/2017 - 09:55PM
by Naihaan Kragnaidael
4 208Weightless Arrows-Potions-Other ConsumablesSimply Removes Weight from Arrows, Potions, and Other Consumables (eg. Soul Gems, Sigil Stones, and Ingredients).Released: 15/07/2017 - 05:40PMUpdated: 15/07/2017 - 05:43PM
by SiphX2012
2 38Peasant CoutureCute Dirndl and Folk Dress Collection by Nailflan, now combined into one mod, with clothing dynamically added to a variety of NPCs, and all available for purchase at Colovian Traders in Skingrad. Number 3 in the Nailflan Couture series.Released: 15/07/2017 - 12:27PMUpdated: 15/07/2017 - 12:27PM
by Myrystyr
1 49Elemental StavesAdds three staves to Rindir Staves that infuse the wielder with an elemental power and the ability to command that element to gain even greater powerReleased: 15/07/2017 - 09:56AMUpdated: 15/07/2017 - 09:56AM
by RogerRed
9 105Oblivion Uncut - Adaptation to OOOA compatibility patch between the two mods, which can work together, but then the new additions of O. Uncut remain like in vanilla.Released: 14/07/2017 - 04:02PMUpdated: 17/07/2017 - 11:20PM
by Saldron613
2 65MagicEffectsExtractedExtracted magiceffects that can be placed in the world and are even movable.Released: 13/07/2017 - 08:30PMUpdated: 14/07/2017 - 03:26AM
by jobra888
1 50Better Cities adapted to OOOI edited the already existing compatibility patch and made characters and creatures from Better Cities more static, like in OOO. Plus several other tweaks to make both mods work together more seamessly.Released: 13/07/2017 - 06:31PMUpdated: 17/07/2017 - 10:50AM
by Saldron613
15 406Nicoroshi CreationsCollection of all Nicoroshi's released works as of 10.7.07Released: 12/07/2017 - 06:39PMUpdated: 26/07/2017 - 08:11AM
by hortik
Jump to page


text:
Just because Polaroid is out of the game doesn't mean instant photography is dead. Thankfully, Fujifilm has brought back the retro fun of instant cameras with their Instax line – just in time for the Holidays!
Both the Fuji Instax Camera Mini 50S and Mini 7S are sleek and stylish in design, producing clear credit card sized photos complete with the vibrant colour Fujifilm is known for. If you don't mind upgrading a size, the Instax 210 shoots slightly larger photos using Instax Instant Wide Film. The super-wide format allows you to fit more in your frame. Every Instax camera comes with auto flash, auto focus, and electronic shutter speed of 1/64th to 1/200th of a second to ensure that every moment is captured in an instant.
Compared to Polaroid, Instax film is easier to find and much easier on the wallet, with a pack of 20 selling for $19.99 on Amazon. Digital is great but now you can share the "moment" and add life to a holiday party – instantly!
Plus it's a stylists dream – you can match and choose your outfit like your very own Clueless Cher. Even Rachel Zoe gives this little instant her instant approval.
Guest Writer ~ Elivia Spence


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«BEST» - Free Download Excel 5 For Macs For Dummies Ebook Online PDF
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Queen Helene Mint Julep Masque Reviews
The BestThis stuff is guaranteed to clear up any blackheads I have and start the process of getting rid of any other blemishes I have. This is the one product that I always make sure to keep stocked. It definitely lives up to it's claims. However, I found that leaving it on for any longer than 20 minutes, it irritated and left my skin all red, so don't forget to wash it off! — 8 years agoohhayhi | 6 reviews
An Immediate Skin FixI have been using this mask since I first got blemishes at puberty, and it is amazing no matter what my skin issue is. I mostly use it now when my skin feels extra oily or is breaking out, and it gets it under control. It also has a soothing and cooling effect that makes me feel totally refreshed. You can use it as a spot treatment too. I put it on my T-zone during breakouts, put a towel on my pil...read morelow, and sleep in it. By morning I'm totally cleared up. The only drawback, though I don't mind the smell, is that it lingers long after you rinse the masque off. — 8 years agomelissakz | 15 reviews
Good for acne troubled skinI use this often and it definetly is a good buy at a low price. This shrinked my pores and sucked away oil. Didn't do wonders for acne but dried them up a tiny bit. My skin was smooth as a result no blackheads. — 8 years, 1 month agoTweetybird11000 | 97 reviews
Best mask ever!!!!This is truly one of the best products out there. My mom actually bought it for me when I was a teenager and had acne flareups a lot. Ever since then, I can not live without it in my medicine cabinet. All your skin needs is some noxema and this mask twice a week and you will see a new person in the mirror. I swear! — 8 years, 3 months agoCarrieFan4Life | 7 reviews
amazing mask, try itI tried this after the rave reviews here. I'm so glad I did... this mask is amazing. I was sceptical at first, but after two weeks ( I use it twice a week) I notice that my skin is so clear, I have a lot less breakouts and blackheads, and my pores are somewhat smaller. Isn't that amazing? I have oily/combination skin and break out a lot. Thanks MUA-ers for helping me find this wonderful mask. — 8 years, 3 months agoftanadi | 13 reviews
Cheap and Effective!I have awful skin - acne, random bumps, red splotches, etc. The bright green Mint Julep Masque makes me look like an alien but it always leaves my skin looking better without being irritating or drying. For a particularly bad blemish, I love to dab some masque on the spot and leave it on overnight! — 8 years, 3 months agoElyseJ | 3 reviews
A great find at a great price!I had read about this in a magazine sometime back and decided to try it..I found it for 99 cents at the local dollar store. Wow. I definitely noticed a difference! The good: My skin looked very nice afterward and it wasn't stripped of moisture. Blackheads and pores were definitely smaller and diminished. It wasn't hard to take off and it was fairly easy to apply. The bad: A tad thick....too...read morethpaste smell, which isn't unpleasant just...toothpaste-y, if that's a word. All in all an awesome product! — 8 years, 3 months agothefragile7393 | 15 reviews
I've been using this for years!It's a great-smelling, economical product that actually works. Very easy to use, I apply it once a week to help rid my skin of blackheads. Sometimes I use it even when I haven't had a breakout simply for its relaxing properties. Another plus about this particular product is that it is easy to wash off. Some other brands and types of masques tend to be difficult to rinse, or get stuck in eyebrows and such... — 8 years, 3 months agoChristel | 11 reviews
awesome price and lives up to its wordi have very sensitive skin so im very picky when it comes putting things on my face because i tend to break out like crazy if one certain ingredient irritates my face but my coworker recommended me trying this mask and ever since i tried it for the first time it was great reduced the size of my pores, smells refreshing, and it made my skin nice and smooth.. definetly the best drug store mask out there! — 8 years, 4 months agohokucoconut | 3 reviews
This Stuff Is Just What My Skin NeededThis stuff is amazing. I can really feel it working. It improves the appearance of my skin making it look clear and even-toned. I even use this as a spot treatment for blemishes. I put it on at night and in the morning my blemishes are significantly reduced in size and redness. — 8 years, 4 months agoKgirl24 | 72 reviews
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text: Hey guys I've been learning the workflows used to produce the concept art for "The Last Of Us" so I tried to create something reminiscent from the beautiful game. This is heavily inspired by the work of John Sweeney. I will be posting more of the results of developing this process asap! All C + C Welcome!


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Road Safety Week is ongoing in India, which commenced from January 11, 2016. Several automobile manufacturers have joined the initiative to spread road safety awareness among the public. The Indian Government is trying to improve road safety in the country.
The Indian Government plans on introducing a Road Transport and Safety Bill. One of the main focus will be the mandatory inclusion of airbags within all vehicles sold in the country. Unfortunately, a deadline for this has not been set and the bill is yet to be introduced in the Parliament.
Currently, over five lakh vehicle-related accidents take place in India every year. Out of which, 1.5 lakh individuals lose their lives and many more are left injured. Officials also believe that vehicle owners should be given better training and issuing of driving license should be stringent.
Nitin Gadkari, the Union Minister of Road Transport, Highways and Shipping promised a website that would identify accident-prone zones across the nation. A total amount of Rs. 11,000 crore has been allotted to rectify accident prone zones across India.
Road Safety Authorities are aiming at reducing accidents by almost 50 percent within five years. Individuals too need to take a decision to be safer on the roads. Talking on mobile phones should be avoided and use of seat belt and helmet should be a conscious choice and not forced upon.


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SHANK2 encodes a protein that is a member of the Shank family of synaptic proteins that may function as molecular scaffolds in the postsynaptic density (PSD). Additionally we are shipping SHANK2 Proteins (3) and many more products for this protein.
Showing 10 out of 141 products:
Human Polyclonal SHANK2 Primary Antibody for EIA, WB - ABIN954795
Berkel, Marshall, Weiss, Howe, Roeth, Moog, Endris, Roberts, Szatmari, Pinto, Bonin, Riess, Engels, Sprengel, Scherer, Rappold: Mutations in the SHANK2 synaptic scaffolding gene in autism spectrum disorder and mental retardation. in Nature genetics 2010
Show all 5 references for ABIN954795
Mouse (Murine) Polyclonal SHANK2 Primary Antibody for WB - ABIN656710
Pinto, Pagnamenta, Klei, Anney, Merico, Regan, Conroy, Magalhaes, Correia, Abrahams, Almeida, Bacchelli, Bader, Bailey, Baird, Battaglia, Berney, Bolshakova, Bölte, Bolton, Bourgeron, Brennan, Brian et al.: Functional impact of global rare copy number variation in autism spectrum disorders. ... in Nature 2010
Show all 3 references for ABIN656710
Human Monoclonal SHANK2 Primary Antibody for AA, ICC - ABIN863121
Kim, Kim, Yang, Park, Yu, Kim: Shank 2 expression coincides with neuronal differentiation in the developing retina. in Experimental & molecular medicine 2009
Show all 2 references for ABIN863121
Human Polyclonal SHANK2 Primary Antibody for ELISA, WB - ABIN1535365
Taylor, Noguchi, Totoki, Toyoda, Kuroki, Dewar, Lloyd, Itoh, Takeda, Kim, She, Barlow, Bloom, Bruford, Chang, Cuomo, Eichler, FitzGerald, Jaffe, LaButti, Nicol, Park, Seaman, Sougnez, Yang, Zimmer et al.: Human chromosome 11 DNA sequence and analysis including novel gene identification. ... in Nature 2006
variants in the SHANK2 gene in a schizophrenia patient cohort
Knockdown of endogenous Shank2E or overexpression of a dominant-negative Shank2E mutant inhibited the glucocorticoid-mediated increase in CFTR (show CFTR Antibodies).
syndapin I (show PACSIN1 Antibodies) functions reflected direct, SH3 domain (show ITSN1 Antibodies)-mediated associations and functional interactions with ProSAP1/Shank2.
Lack of association between NLGN3 (show NLGN3 Antibodies), NLGN4 (show NLGN4X Antibodies), SHANK2 and SHANK3 (show SHANK3 Antibodies) gene variants and autism spectrum disorder in a Chinese population.
deletion of ProSAP1/Shank2 results in an early, brain-region-specific upregulation of ionotropic glutamate (show GRIN1 Antibodies) receptors at the synapse and increased levels of ProSAP2/Shank3 (show SHANK3 Antibodies)
we confirmed that de novo SHANK2 deletions are present in patients with ASD (show ARSD Antibodies) and showed that several SHANK2 variants reduce the number of synapses in vitro
dominant negative effect translates into dose-dependent altered cognitive behavior of SHANK2-R462X-expressing mice, with an impact on the penetrance of ASD (show ARSD Antibodies)
we identified de novo copy number variations in the SHANK2 synaptic scaffolding gene in two unrelated individuals with autism-spectrum disorder (ASD (show ARSD Antibodies)) and mental retardation
betaPix (show ARHGEF7 Antibodies) up-regulates NHE3 (show SLC9A3 Antibodies) membrane expression and activity by Shank2-mediated protein-protein interaction and by activating Rho GTPases in the apical regions of epithelial cells
Shank2 increased the membrane expression and basal activity of NHE3 (show SLC9A3 Antibodies) and attenuated the cAMP-dependent inhibition of NHE3 (show SLC9A3 Antibodies) activity.
Shank2(-) (/) (-) (Shank2 knock-out, KO) mice to investigate the controversial pain sensitivity issue and found that Shank2 KO mice showed reduced tactile perception and analgesia to chronic pain.
trans-synaptic Zn mobilization by clioquinol, a Zn chelator and ionophore, rescues the social interaction deficits in Shank2-/- and Tbr1 (show TBR1 Antibodies)+/- mice
Since mutations in all three human SHANK genes are linked to neuropsychiatric disorders such as autism and schizophrenia, Shank mutant mice serve as corresponding in vivo model systems--{REVIEW}
Shank2 appears to be a key molecule regulating epithelial fluid secretion.
Scaffolding proteins ProSAP1/2 were found within the postsynaptic specializations of synapses within the PNS, indicating a similar molecular assembly of central and peripheral postsynapses.
Shank2 negatively regulates CFTR (show CFTR Antibodies) and this may play a significant role in maintaining epithelial homeostasis
Data suggest that Shank 2 is expressed in the neurons of the developing retina and could play a critical role in the neuronal differentiation of the developing retina.
This gene encodes a protein that is a member of the Shank family of synaptic proteins that may function as molecular scaffolds in the postsynaptic density (PSD). Shank proteins contain multiple domains for protein-protein interaction, including ankyrin repeats, an SH3 domain, a PSD-95/Dlg/ZO-1 domain, a sterile alpha motif domain, and a proline-rich region. This particular family member contains a PDZ domain, a consensus sequence for cortactin SH3 domain-binding peptides and a sterile alpha motif. The alternative splicing demonstrated in Shank genes has been suggested as a mechanism for regulating the molecular structure of Shank and the spectrum of Shank-interacting proteins in the PSDs of adult and developing brain. Two alternative splice variants, encoding distinct isoforms, are reported. Additional splice variants exist but their full-length nature has not been determined.
SH3 and multiple ankyrin repeat domains 2
, SH3 and multiple ankyrin repeat domains protein 2-like
, GKAP/SAPAP interacting protein
, SH3 and multiple ankyrin repeat domains protein 2
, cortactin SH3 domain-binding protein
, cortactin-binding protein 1
, proline-rich synapse associated protein 1
, proline-rich synapse-associated protein 1
, GKAP/SAPAP-interacting protein
, SH3/ankyrin domain gene 2
, proline rich synapse associated protein 1
, cortBP1


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What is JotForm?
JotForm is a free online form builder which helps you create online forms without writing a single line of code. No sign-up required.
At JotForm, we want to make sure that you're getting the online form builder help that you need. Our friendly customer support team is available 24/7.
We believe that if one user has a question, there could be more users who may have the same question. This is why many of our support forum threads are public and available to be searched and viewed. If you'd like help immediately, feel free to search for a similar question, or submit your question or concern.
Can I download specific records to excel?Asked by ourpalsplace on February 18, 2016 at 05:33 PM
We are capturing new volunteer registrations using jotform. Is there a way to download new / specific records vs all records in the view submissions?
JotForm Support
That's possible using the search box, so only the results from the search query will be exported to Excel.
If you mean filter the columns, that's also possible by unchecking them on the submissions settings.


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New York, Nov. 7 (AFP): The Matrix: Revolutions, the third and final film in the sci-fi series starring Keanu Reeves, made history on Wednesday with a simultaneously debut in 80 countries around the world.
US critics panned the $200 million-plus epic, but fans ignored them and lined up outside cinemas from Moscow to Beijing to Los Angeles, often crawling out of bed early or staying up late at night.
Under an unprecedented distribution system, the film was launched at 1400 GMT around the world, so Los Angeles fans of the saga had to be at the movie theatre at 6 am, while those in Tokyo saw it at 11pm and those in the Peruvian capital were served breakfast for a 9 am showing.
The film in which Reeves plays Neo, a hero on a mission to save mankind and fight against machines dominating a world of virtual reality was shown in 3,500 cinemas across the US alone, according to the industry review Variety.
Reeves and co-star Jada Pinkett Smith were in Tokyo, where they watched a countdown event at the the Shinjuku Milano-za movie theatre, illuminated by green flood lights the movies theme colour.
Yoshihisa Fujieda, 27, came to the theatre with three dozen fans dressed as characters from the movie. They met through an Internet site for Japanese Matrix fans.
I like the movies extraordinary action scenes. I am dying to know how it will end," said Fujieda, a farmer who travelled more than two hours on trains from his home town of Narita.
He wore the costume of characters The Twins, with his face painted white, wearing white dreadlocks, in a white suit.
Other fans dressed as the villain Agent Smith in dark suits and tie.
In Moscow, Russian communists staged a flash mob at the movie screening, seizing the opportunity to heighten their appeal to young people ahead of a December poll.
Two rows of young militants lined the staircase descending from Moscows largest cinema into Pushkin square, each wearing a red T-shirt with a florescent letter to read out We are the NEO-communists and Destroy the Matrix.


text:
Have an opinion?
"It seems to be correct," would be better, I think. But, nothing is REALLY wrong with 'it looks correct.' You don't really need to say the 'to be' part, I think. Just, 'it looks correct,' or, 'it seems to be correct.'
I'd say "Is this correct"? instead
yes that works
"It looks correct to me".
You cannot undo this action. The opinion owner is going to be notified and earn 7 XPER points.


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Sunday, January 26, 2014
JOHNNY ANGELS... Who Is Johnny Angel?
Above the two young men who recorded under the name of Johnny Angel.
Left Johnny Angel aka Mike Russo from Philadelphia and Right Johnny Angel from Gallup in New Mexico.
Many Records are listed in the doo wop guides with the name of Johnny Angel but I don't know which of the two Angel's are relationed with each song....
-Starlight/The Story Of Love. Power Records-1958.
-We're Old Enough/Where's My Love. Jamie Records-1959 (as Johnny Angel & The Creations).
-Doubt/Falling Teardrops. Imperial Records-1960.
-Lonely Nights/Seven Words. Jaf Records-1961.
-Without Her Heart/Lady of Spain. Felsted Records-1961 ( as Johnny Angel & The Halos).
-One More Tomorrow/Mashed potato. Felsted Records-1962 ( as above).
-Looking for A Fool/Roller Motion. Felsted Records-1962 ( as above).
-This Is The Night For Love/You've Been Wrong. Swan Records-1966.
Posted by Whitedoowopcollector at 12:00 AM
1 comment:
- Timmy Ryan said...
The mystery of the two Johnny Angels!!! Love it......hopefully somebody out there can shed some light?
- September 5, 2016 at 7:44 AM
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|"William A. Rowe, Jr." <wr...@rowe-clan.net>
|Re: Time for 2.0.51 and 2.1.0
|Thu, 02 Sep 2004 16:09:44 GMT
At 09:25 AM 9/2/2004, Henri Gomez wrote: >Bad news for me and many others since without AJP support included in >2.0.x, users will still require to have mod_jk to link there HTTPD to >Tomcats. > >Could we hope the dev team to relax the situation for mod_proxy/ajp in >future 2.0.x release, since Graham, Mladen and Jean-Frederic works >hard to make mod_proxy as stable as possible even now with AJP support >? Henri, meaning no disrespect to this team (they have accomplished some fantastic things) ... it took us a very long time to beyond the initial release to get proxy to something resembling the stability of 1.3, and mod_cache is still getting there. Admins understand why n.x -> (n+1).0 can sometimes break things. That's the natural aversion to .0 releases. They can even understand if n.x.z -> n.(x+1).0 breaks things. But please don't expect them to sympathize when n.x.z -> n.x.(z+1) starts breaking things, this undermines the confidence in one of the most successful open source projects in the world. When we say x.even releases are -stable- we mean, don't expect things to break when you upgrade. When we say x.odd releases are development, that means ya - it might break on a point bump, live with it and let us know so the subsequent x.even release is golden. We are trying to move from the 1.3 and early 2.0 models of change this, dabble in that, add this, break that and keep the users chasing a moving target. The beginnings of the 2.0 release were pretty violent in terms of the changes needed to move from 2.0.36 to 2.0.39 to 2.0.43, and it didn't do alot for us in terms of uptake for the httpd-2 server. Since .43 the consistency has changed alot - and we want to continue to improve the quality, and not introduce potentially shaky changes. You have a simple option though - grab 2.0. Replace the modules/proxy/ tree with 2.1-dev and voila - buildconf - configure - make install. Or use 2.1-dev and help the effort of identifying when 2.1-dev reaches release quality. Mladen provided both alternatives in the current mod. Bill
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"I've lost a Vuelta before by 13 seconds so I'm going to fight for every second I can at this point' – Team Sky's…
Team Sky's man, Elia Viviani, was the one to win through the chaotic yet intense sprint of the EuroEyes Cyclassics Hamburg. Viviani crossed the…
One of the most important stages of the major British cycling race is officially set to start in a town that is known to…
You can do it! No one can ever doubt it. If you decide to do an Ironman, then anything is possible, you can even…
Belgian cyclist, Dylan Teuns has officially recorded his eighth win in just two weeks after being able to get the stage and overall victory at…
This page presented by Amazon Exercise & Fitness
You will be allotted a certain amount of time for each event and your goal is to cover as much distance as you can in that amount of time. You will be given 5-10 minutes to transition to each event. Points will be awarded for distance covered and racers will be ranked according to total points accumulated. Medals awarded to first through third place for age and gender groups. You can register as an individual or perform the race with a team!
Race Distances
Swimming: Pool 10 minutes
Transition 1: 10 minutes
Biking: Spinning Bikes 30 minutes
Transition 2: 5 minutes
Running: Gym Track 20 minutes
Member Individual: $25
Non-Member Individual: $40
Member Team: $20/person
Non-Member Team: $35/person
Start Time
First wave starts at 9:00am. Wave start times will be assigned after registration. Your start time will be emailed to you prior to the race.
Must Be 12 or older to register.
Frequently Asked Questions
2014 Indoor Triathlon
1. What is the password so I can register online?
The password you need to register at RunReg.com is ymca. The password is case sensitive.
2. How do you count laps in the pool?
We measure your swim distance in lengths, not laps. Each time you touch the wall counts as one length. Lengths will be rounded up to the next nearest half length.
3. Do I have to swim a certain stroke?
No, you can swim any stroke you like, including dog paddle, side stroke, elementary backstroke, etc. Any forward movement in the water must be done with feet off the bottom of the pool.
4. What if I need a break during the swim?
You may rest on the walls, hold onto the lane line, or stand on the bottom of the pool to rest. (Any forward movement in the water must be done with feet off the bottom of the pool). You may stop and rest for as long as you like, but keep in mind the clock is ticking!
5. Can I wear a life jacket or use a snorkel during the swim?
No. We do not allow any floatation devices or snorkels/fins to be used during the swim.
6. What is the transition from the swim to the bike like?
After the final second of the swim, you have 10 minutes to transition to the bike. You will use the boys and girls locker rooms to do so. This 10 minutes is for you to change into biking/running clothing and to adjust your bike seat and handle bars. You should bring your running stuff with you to the cycling portion as you will not have enough time to go back to the locker room. This transition will go faster than you think!
7. What type of bikes do we use?
All participants will use the spin bikes. All bikes are equipped with pedal cages for normal shoes or SPD clips for cycling shoes. There is also a water bottle holder.
8. How do you track the distance on the spin bikes.
Since it is a spin bike, the implication is that the person with the highest sustained RPM will record the highest score. Each bike has a computer that calculates distance by counting the number of times the flywheel goes around. The distance on the bike is not meant to correspond exactly to the actual distance one would cycle outside.
9. What is the resistance like on the spin bike?
Each participant will be able to set their own resistance at a level that is comfortable for their ability. Keep in mind, injuries can occur if you spin too fast. We recommend each participant set the tension at a level that is safe and comfortable based on their cycle experience.
10. What is the transition like between the bike and the run?
Participants will have 5 minutes from when the bike ends until their run starts. They may bring a different pair of shoes to run in, a water bottle, etc.
11. How will my distance be calculated for the run?
Each lap is rounded up to the nearest half lap.
12. Can I use a personal music player during the bike and the run?
No. We may need to give you directions and we want you to be able to hear us.
13. How are the points calculated?
The athlete who swam the furthest will be awarded 100 points. All other participant scores are a percentage of this based on their distance. For example, if the best swimmer swam 50 lengths, that person is awarded 100 points. Someone who swims 40 lengths is awarded 80 points. This scoring concept is also done for the bike and the run. The three scores will be added up and the total will be the athletes final score. For example, a person may receive 80 points for the swim, 25 points for the bike, and 58.5 points for the run. Their total score will then be (80+25+58.5) 163.5 points.
14. How old does someone have to be to participate?
Participants must be 12 years old or older to participate.
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"I've lost a Vuelta before by 13 seconds so I'm going to fight for every second I can at this......
Team Sky's man, Elia Viviani, was the one to win through the chaotic yet intense sprint of the EuroEyes......
One of the most important stages of the major British cycling race is officially set to start in a town that is......
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WASHINGTON – Economists sometimes describe a country as having a "Goldilocks" economy, because it has achieved moderate, sustainable growth rates that are "neither too hot nor too cold, but just right." They might also seek Goldilocks's views on export-promotion policy.
Export promotion might appear to be a virtuous exercise, regardless of whom it supports. Some government agencies, such as the United States' Small Business Administration and National Export Initiative, target small firms that are most in need of help. Others, as in Brazil or South Korea, select large companies that are best placed to make profits.
There are good arguments for and against both approaches. Small firms need support, because they lack the knowledge and experience needed to operate abroad. They may not wish to invest alone in know-how that their competitors can easily replicate. Moreover, they usually lack the necessary finance, and often find that their local bankers – unable to distinguish between a realistic market-entry strategy and wishful thinking – are unwilling to lend.
But, though small companies' needs may be great, the reasons why many remain small may have little to do with their limited export capabilities. Instead, they may suffer from low productivity, poor product quality, bad customer service, or any of a host of other internal constraints. Helping such firms to access foreign markets might do little to alleviate their fundamental weaknesses (which may have constrained their export potential in the first place). The result is that export support is often wasted.


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Drake surprises fan performing Hotline Bling at Bat Mitzvah
Drake performed his super-hit 'Hotline Bling' at a fan's Bat Mitzvah on Saturday (20.02.16).
The 29-year-old rapper surprised a young girl when he turned up out of the blue to the bash in New York and started singing the catchy track followed by his song with Fetty Wap, 'My Way'.
In a series of videos posted on social media Drake - who is half Jewish - can be seen belting out his tunes as the unnamed girl can be seen singing a long with her friends.
During his rendition of 'Hotline Bling', he goes up to the party girl, who is wearing a sparkly dress, while she danced in front of him.
Meanwhile, Drake himself had his own Bar Mitzvah when he was 13 and he re-created it on 'Saturday Night Live' in 2014, with a monologue about being Jewish and he also released a music video for 'HYFR', which was his celebration re-imagined.
He also sings about performing at a Jewish celebration in his song with Rihanna 'Take Care'.
He sings: "Just performed at a Bar Mitzvah over in the states. Used half of the money to beat my brother's case."


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