text:
A hat-trick from striker Carry-Ann helped HFC to a commanding 6-0 victory over Bethwin A to claim the women's trophy at Your Game East London.
HFC, representing a Kick it Out initative in Hackney, produced a string of scintillating performances at the Leyton Orient Community Complex to stake their claim as potential champions at the national finals next month.
HFC had only conceded one goal on their way to the final, which they dominated from the first whistle.
Star player Sarah added two goals, one a superb finish from a mazy dribble while Jade added the other goal courtesy of a powerful long range strike.
Coco United did not enjoy as smooth a ride in the men's final as they were pushed all the way by a determined performance from Urban Renaissance.
Goals from Evan and Sergio gave Coco, an all-Portuguese outfit representing the Foyer Foundation from Stratford, an early 2-0 lead.
But star man and Renaissance captain Aiman cut the lead to one goal after a crisp finish, setting up a tense finish in the final few minutes.
And Coco had giant goalkeeper Nando to thank after producing two super saves to deny Renaissance, a People of Westminster project addressing anti-social issues effecting young people.
Both Coco and HFC will be joined at the national finals by Brent Ladies and Lotus Sports Club, who were named Fair Play winners for their excellent sporting conduct.
The standard of football throughout the day impressed special guests and former England internationals Chris Powell and Luther Blissett.
"Among the players we've seen here, there is a player who has the potential to make it in the Football League or maybe even the Premiership," said former Watford and AC Milan striker Blissett.
"The only thing that will stop them will be the mental application in their heads. Events like this will help inspire them to reach the very top."
Powell said: "These kinds of projects are very important, they encourage young people to get involved in team sports and understand the numerous benefits they can bring."
There were more trophies for HFC star player Sarah Cleary, who walked away with the Five Live Most Valuable Player award for her incredible skills throughout the day.
And she also collected the "Hardest Kick" trophy for her whopping 58mph shot, while NACRO SQ's Sonny picked up the men's trophy after smashing a 76mph thunderbolt.
Entertainment throughout the day was provided by 1Xtra DJs L Double and Cameo, with live acts from MCs Black Twang and Detter-X and beatbox Rashad, who amazed with his array of incredible sounds.
Black Twang and Detter-X could have serious competition from MC Smiler, who walked off with the 1Xtra Best DJ award.
And Andrew Pontiss impressed Five Live commentators David Oates and Jacqui Oatley enough to take the Best Commentator award.
We want to hear about your Your Game experiences, use your own personal web pages or email firstname.lastname@example.com and let us know.
Your Game is a partnership between the BBC and the Football Foundation, with support from Barclays Spaces for Sports.


text:
Rainer Schulz, M.D. PhD
I had established and led an independent research group within the Department of Pathophysiology, University of Essen, Medical School, and have (since January 2011) been appointed as Chairman of Physiology at the Justus-Liebig University Giessen. I have achieved international recognition for my research on myocardial ischemia/reperfusion injury (IRI) and protection from it. My research group uses a translational approach from subcellular particles towards large animal model to define new targets involved in IRI and investigate novel treatment strategies for protecting the heart.
My research is internationally recognised as evidenced by numerous invitations to speak at international scientific meetings. I received the Young Investigator Award from the European Society of Cardiology (ESC), the Fraenkel and Franz-Groedel Award as well as the Basic Science Lecture Award of the German Cardiac Society. I served as Chairman of the Working Group on Cellular Biology of the Heart of the ESC and I am currently member of the International Council of the Society of Heart Research (ISHR) and the program committee of the German Cardiac Society. I have been appointed as Fellow of the ESC and have been invited to join the AHA as fellow.
My research has advanced the field of IRI and protection from it by being the first to: (1) demonstrate an inotropic reserve in chronically ischemic myocardium, a phenomenon used now routinely in daily clinical practice for identification; (2) highlight the cross talk between protein kinases involved in cardioprotection, and (3) demonstrate the mitochondrial location of a highly expressed cellular protein (named connexin 43) being essential for cardioprotection. The latter is of utmost importance since a number of human diseases (including genetic variations) are associated with reduced connexin 43 expression.
Publications and Peer-review:
Since 2001 I have published 134 peer-reviewed articles and written 5 book chapters. My H-index is 46 with the total number of citations being close to 6000. I am Associate Editor of Cardiovascular Research (from February 2011) and the British Journal of Pharmacology (since 2008) and I serve on the Editorial Board of several cardiovascular journals. Apart from regularly reviewing articles for them, I review grant proposals for the German Research Foundation, the British Heart Foundation, and other funding organizations.
I have successfully collaborated with other research teams locally, nationally and internationally as indicated by numerous publications.
Research Group and Funding:
My research group currently comprises 6 postdoc positions and 5 technicians and a number of MD and PhD students. I received continuous grant support from the German Research Foundation as PI and Co-PI and from several pharmaceutical companies to study new compounds targeting IRI. I have been invited to join the faculty and submit grant applications to the ECCPS and PROMISE program (funded by the German Research foundation).
Apart from the regular teaching to MD students I started the IRI part of the BIOME graduate school at the University of Essen. I have lectured to Danish PhD students and routinely to Cardiology trainees, GP's and junior doctors (mainly in Germany but also in other European countries).
Knowledge Transfer/Exchange:
Evidence for this includes: several research collaborations with Industry and other Academic Institutions, consultancies with industry, patient and public engagement in my clinical research and participating in International Working Groups for providing issuing Research Recommendations.
Past-Chairman Working Group on Cellular Biology of the Heart of the European Society of Cardiology,
Member of the ISHR International Council, Member of the Program Committee of the German Cardiac Society
University Education
|Research fellow in the division of cardiology at the University of California, San Diego
|Study of clinical medicine at the University of Essen M.D.
Scientific Career
|Assistant professor, Department of Pathophysiology, University of Essen
|Tenured professor, Institute of Pathophysiology, University of Essen
|Since 2011
|Tenured professor, Director of the Institute of Physiology, University of Giessen
Awards & Honours
|Young Investigator Award of the European Society of Cardiology
|"Fraenkel-Preis" of the German Cardiac Society
|"Franz-Groedel Forschungspreis" of the German Cardiac Society
|Basic Science Lecture of the German Cardiac Society
Current grant support
|German Research Foundation (BO 2955/1-1): STAT3 in cardioprotection
|German Research Foundation (Schu 843/7-2): Cx43 in cardioprotection

subset: commoncrawl


text:
Rider 2, Siena 1 (2ot)
Women's College Soccer
Rider University 2, Siena College 1 (2ot)
LOUDONVILLE, NY- Stayin' Alive.
Fortunately for the 2012 Broncs, they are too young to have known the dance/music genre known as 'disco'.
The Rider women's soccer team is also fortunate to be Stayin' Alive in the playoff hunt.
"The last 50 seconds of the game was unbelievable," said Rider head coach Drayson Hounsome.
Senior Abi Cottam (Leominster, England/Ludlow) scored with six seconds left in the second and final overtime to lead Rider to a Metro Atlantic Athletic Conference victory at Siena Friday afternoon.
"Abi shot wide with 30 second left and was so upset," Hounsome said. Siena had a goal kick but Rider won the header. Cottam then took a pass from freshman Tara Ballay (Delran, NJ/Delran) and scored her fourth goal of the season to win it. "Abi could barely see, she was crying after the missed opportunity," Hounsome said. "She took the pass from Tara and scored. To be able to bounce back so quickly after the disappointment and score such an emotional goal was brilliant."
With the win the Broncs (10-3-3, 5-2-1 MAAC) remain in fourth place in the MAAC, the final playoff spot, heading into the regular season finale Sunday at first-place Marist.
Rider took a 1-0 lead 1:18 into the second half when junior Jennifer Meier (Sayville, NY/St. Anthony's) took a long pass from junior Jody Sokol (Bensalem, PA/Bensalem) and scored her fourth goal of the season.
"Jen scored a great goal," Hounsome said. "She caused a lot of problems for their defense today."
Siena (6-10-1, 2-5-1 MAAC) tied the score with 39 minutes left to play in regulation.
Rider senior goalkeeper Jenn Nichols (Stratham, N.H./Exeter) made five saves.
Rider out-shot the Saints 30-12, including 6-3 in overtime. "We controlled the tempo," Hounsome said. "Overall I think we deserved to win."
Rider is now 2-0-2 in overtime games this year.
The 10 wins is the most for Rider since 2004 when the Broncs finished 12-7-2 and reached the MAAC Title Game.
Rider and Siena tied 0-0 last season in Lawrenceville. The last time Rider beat Siena was 2006.
Rider lost 4-1 to Siena the last time Rider traveled to Loudonville.
With the win the Broncs are 5-0-1 in their last six games.
Rider plays the regular season finale Sunday at first-place Marist. A tie or win Sunday and Rider will be in the playoffs. "We just need to make sure we don't lose," Hounsome said. "We've only lost three times all year, so we're a tough team to beat. We just have to do that one more game."
A loss Sunday and Rider's playoff hopes will rest on Iona tying or losing to Saint Peter's.


text:
Here are the Tide times for Port Taranaki in New Plymouth.
These time are + or - 5 minutes of the true NZ standard Tide table as they are computer generated with a Internet tool
Mokau is about 10 minutes behind Port Taranaki New Plymouth tide. This is because Mokau is north of New Plymouth but South of Waitomo (in the king country) and Hamilton. Check out our Directions and maps pages for more information
We try to sail near high tides as this give you the best view of the river and makes for safe easy sailing. We can sail on other tides but we have to limit the trip to two hours.
This information is given as a guide only and "Mokau River tours" accepts no responsibility for it accuracy or action made using this information. Do not use this data for navigatiion or any activity that can result in harm to anyone or anything
For a Calender View of New Plymouth tides please click here
For Raw tide information on New Plymouth please click here


text: Transformers made for powering large neon signs are inexpensive and very reliable. Most commonly, the secondary is center-tapped, which prevents the use of its full peak-to-peak output in applications where one of the terminals needs to be grounded. In the power supply described in this post, I took out the high-voltage transformer out of its metallic


text:
Established in 1987, Spectra has grown from strength, maintaining its reputation over the years for high quality construction and innovation design of vehicles and other bespoke projects.
Spectra's main emphasis lies in customer satisfaction, from small companies to large multinationals, each customer is valued and offered the same level of attention and worldwide support.
We are a Specialist Engineering and Coach building company providing vehicle building, refurbishment, repairs and bespoke fabrications.
Every project is exclusive and is treated as such, with consideration to specification, design and construction.
Spectra offer the following facilities:


text:
It only takes a minute to get started. Fill out our uncomplicated sign up form and login to the website.
This step is voluntary but will drastically boost your chances of getting interest from other Christian members on the site. Write a little something about yourself, your hobbies and upload a nice photograph of yourself.
Use our website's state-of-the-art search to pinpoint members who satisfy your needs. Or just look through listings of Christian singles and pinpoint members that attract you.
Found someone who ticks all the boxes? Send them a word or two or just a wink and see if they're interested. With a little luck you'll be on your way to an amazing adventure.
It'll only take 30 seconds


text:
London (AFP) Aug 24, 2010
Aid agency Oxfam warned Tuesday of a "double disaster" for millions of people in Niger where heavy rains and flooding are compounding food shortages caused by a prolonged drought.
The United Nations says more than seven million people are facing starvation in Niger -- more than half the population -- following the drought, and Oxfam says the few crops that survived are now being destroyed by floods.
"It's a double disaster. Before the rains, people lacked food, now any small reserves of grain they had have been washed away by the water. Nothing remains," Ibrahim Mahaman, head of a flood-hit village, told the aid agency.
At last six people have died in the sub-Saharan country because of the heavy rains, which has pushed the Niger river to its highest level for more than 80 years and left nearly 70,000 people homeless, according to UN sources.
"Many crops and vegetables that would have provided crucial food to hungry families have been destroyed by floods," said Raphael Sindaye, Oxfam's deputy regional director in west Africa, in a statement issued in London.
"People who were praying for rains for their crops to grow have now lost everything."
He said Oxfam's aid operation was stretched "to the limit" as it tried to deal with "one of the worst food crises to hit the region in living memory".
"Niger urgently needs more money to fund not only the food crisis but also to help those hit by this second emergency," Sindaye said.
Last week, the UN announced a further 15 million dollars (12 million euros) for World Food Programme operations in Niger.
earlier related report
The visit is seen as an opportunity for the two countries to explore ways of expanding their already sizeable trade ties -- and also a chance for two emerging powers to solidify their strategic partnership.
Zuma -- who visits Beijing and Shanghai during a three-day trip he has called "crucial" -- was welcomed by Hu at Beijing's Great Hall of the People before the two leaders went into talks.
"The talks will surely take the relations between the two countries to greater heights," Zuma said in a speech to business leaders.
Among the agreements signed by the two sides was a deal to exempt diplomatic passport holders from visa requirements, China's Xinhua state news agency said.
Chinese Foreign Minister Yang Jiechi said the move would enhance mutual understanding, and facilitate personnel exchanges, Xinhua reported.
The two sides were also due to sign cooperation deals in the areas of mineral resources, transportation and environment management, according to Zuma's office.
China National Nuclear Corp, which runs the nation's growing nuclear energy programme, also is in talks to build a nuclear power plant in South Africa, Dow Jones Newswires quoted a company official as saying Tuesday.
China's Vice Commerce Minister Gao Hucheng said Beijing would encourage domestic companies to invest in South Africa's mining and resources sectors, the agency said.
It also reported South Africa's Standard Bank Group Ltd and state-run China Railway Group Ltd were to sign a memorandum of cooperation in Beijing on investments in African rail projects.
Bilateral trade -- which has been expanding since the establishment of full diplomatic relations in 1998 -- last year totalled about 16 billion dollars, according to figures from both countries.
"Trade statistics with China continue to reflect the potential that still exists for expanding the commercial relationship," the South African foreign ministry said before the visit.
Zuma said Tuesday that the expansion of foreign trade was a way for his country to "improve the quality of life of all South Africans".
China, which last year overtook the United States to become South Africa's largest export destination, mainly imports raw materials such as iron ore, as well as iron and steel, to fuel its booming economy.
Beijing also has unveiled a series of major investments since ploughing 5.5 billion dollars into Standard Bank nearly three years ago.
In May, Chinese companies reached deals to build a 217-million-dollar cement plant and invest 877 million dollars to take control of a small South African mining company and build a new platinum mine.
South African Trade and Industry Minister Rob Davies on Tuesday told business leaders in Beijing that his country's exports were too dependent on primary goods and that he hoped Beijing could buy more "value-added" goods.
Zuma, who is accompanied by a number of key ministers and 350 business leaders, is due to meet Premier Wen Jiabao and other senior Chinese officials on Wednesday. He was due to visit the World Expo in Shanghai on Thursday.
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text:
Goophone Y6 – Specificatii opinie: iPhone 4S clona MT6577 Android cu came 8MP și Ecranul Retina
The Goophone Y6 is an another entry from GPhone pe iPhone 4S clone categorie, acest MT6577 Android OS knock-off is yet another iPhone clone to consider. It is a planned release in the same pacing as the KuPhone S9 4S cu MT6577 CPU precum și.
This yet another iPhone 4S knock-off sports the latest MTK6577 CPU tactat la 1.2GHz Dual Core chip that is really a fast CPU specifications matched with a GPU at a processing power that is clocked at 800MHz. This phone is undeniably a decent and fast performer on HD gaming and multimedia experience.
Se rulează pe Android 2.3.6 Gingerbread. The only thing that makes me think why it isn't on Android ICS is because of the reason to maintain the near-perfect Apple's iPhone OS user interface. You can see it on the pictures, from the settings screens and "slide-la-debloca" ecran. Everything just feels like the same UI of the iPhone. Încă, Gingerbread isn't bad at all.
Prin modul în care, you can always switch on which UI you want to use on the settings. Just select between Apple iOS UI and Android UI.
It has support on many languages such as: Limbi: Englez, Indoneziană, Malaezian, German, Spaniol, Franceză, Italian, Portughez, Vietnameză, Turc, Rus, Limba arabă, Tailandez, Tradițională Chineză, Chineză simplificată. Other languages can be requested upon your order check-out so it will be preset on the Goophone Y6 that will be shipped.
There is also a decent number on the memory side of the Y6, the RAM is 512MB while the ROM is a 4GB that is still expandable up to 32GB with an external SD card.
Ea are o 3.5 inches capacitive multi-touch screen, same as the real iPhone and also have Retina display at a DVGA resolution cu 960×640 pixeli. Its an indication of a very clear, crisp and vivid looking display. Touch points is up to 5-puncte de contact max.
It make sense that this China phone isn't a dual SIM capable but is only a Single SIM. Knowing that the supported SIM on the slot is only a micro-SIM, its definitely an iPhone clone. Ea are 3G / WCDMA sprijini, totally unlocked and will work on any GSM carriers in the world.
Here's why it is better than the KuPhone 4S, the Goophone Y6 has an 8.0 megapixeli aparat de fotografiat principal at rear. Obviously, it will output better image shots. The secondary snapper is a 0.3 megapixeli and has support with video calling even at Skype.
Goophone Y6 Specs and Features
CPU: MTK MT6577 CPU 1.2GHz + GPU 800MHz
Sistem de operare: Android 2.3.6
Limbi: mai multe limbi
- ROM-ul : 4 GB
- Built-in Memory Card (4 GB / 16 GB / 32 GB)
- Dimensiune: 115.35 x 58.45 x 9.38 mm
- Greutate: 138 g
- 3.5 inch Capacitive multi-touch
- Retina screen
- DVGA resolution
- 960 x 640 pixeli
- Supports 5 puncte de contact
- Single SIM (micro SIM card only)
- GSM:850/900/1800/1900 MHz
- WCDMA 3G: 900/2100 MHz
- Suporta servicii GSM în întreaga lume
- Negru
- Alb
GPS: Built-in GPS, supports A-GPS
- Bluetooth A2DP
- WIFI:802.11b / g internet wireless
Aparat foto
- Înapoi: 8.0 Mega pixel camera with auto focus and flash
- max pixel size of images: 2560 x 1920
- Față 0.3 mega pixeli
- Suporta inregistrare video
Special features:
- G-senzor
- Senzor de proximitate
- Senzor de lumină
- Accelerator Sensor
- Radio FM
- U disk support function
Acumulator: Built-in Li-ion Battery at 1800 Evaluarea mAh
- Cască / 3.5 mm audio jack
- Cablu USB
- Încărcător
Preț: $229.00
If you could notice, it is slightly more expensive than the KuPhone 4S S9. Bine, that is somewhat a decision factor. I still like the KuPhone 4S over this one as it has better battery rating and I don't think that the 8MP will be very much of good use to me. The user interface however just seems like a perfect asset.
Here are some of the interesting points of this Goophone Y6:
- good screen, accurate size and 1:1 physical appearance
- fast and high-end hardware specs
- has FM radio support, of course.
Încă, with what you can see on the Goophone Y6, its obviously a decent iPhone 4S clone. It can be hardly recognized that it is actually a China phone and just an iPhone knock-off. With metallic casing and everything iPhone, the Goophone Y6 is definitely worth the bucks. You can check it out on the link below for more technical information and photos. Take note that the Goophone Y6 isn't released yet. Expect that the posted specifications might change. Different resources have different specs details listed on their sites, its a little bit confusing; well honestly. So let's just wait for the final confirmation of the information about this new Goophone Y6. I will update this once we finally have the verified data.


text:
Sephora: Tarte We Wish You Wealth Palette : Combination Sets
Normally combination sets come with tons of stuff that I would never use but this one is packed with great stuff, 16 shadows, 16 glosses, 4 gel eyeliners, illuminator, their fab gel blush, and two brushes. Plus, the packaging is really cute
Oh man, I love trying new stuff!!! And what is better than a box full of cool products? Loving, loving, loving it.
what could be better then makeup that has a good cause?Tags: beauty, makeup, pink, causes, Sephora, luxe, breast cancer awareness, Bare Escentuals, mineralAdded 10 Years Ago from Sephora
A box set of three of Benefit's best sellers - Eye Bright, BADGal Lash, and Dallas. lots of great products!


text: On Wed, Feb 8, 2012 at 8:57 AM, Ibad Kureshi U0850037 <U0850037 at hud.ac.uk> wrote: > Hello, > > I was wondering is someone could tell me how to adjust the step size in a job array. We are running Torque 2.5.7 with the PBS_SCHEDD on a small cluster and our users want to submit arrays. > > One the SGE and the Moab/Torque based systems > > $ -t 1-20:2 > > or > > #PBS -t 1-20:2 > > respectively, gives them 10 jobs with even ID numbers. > > How can this be done with Torque? It throws out "qsub: Bad Job Array Request" error > > Have not been able to find much literature on this. > > Thanks this is not currently supported, but it is a great feature request. unfortunately the only option would be to explicitly specify each array ID: #PBS -t 2,4,6,8,10 ...20


text:
For press inquiries or to schedule an interview with the Attorney General please contact:
503-378-6002 or firstname.lastname@example.com
About Ellen F. Rosenblum
What: Tualatin River paddle and public forum. Attorney General John Kroger and DEQ Northwest Regional Administrator will lead a paddle tour of the Tualatin River, focusing on the environmental issues facing a significant tributary of the Willamette River. The Tualatin faces a variety of environmental threats, including high temperatures, threatened habitat, sewage discharge, agricultural and municipal run-off.
Where: Tualatin Community Park. 8515 S.W. Tualatin Road
When: Wednesday, July 8, 2009. Paddle starts at 3:30 p.m. Town hall starts at 6:30 p.m. Meet at the rustic shelter.
Note: Kayaks, life jackets and paddles available for media.
Are you sure you would like to leave?
You are currently running an old version of IE, please upgrade for better performance.


text:
Hometown girl / adult movie mogul makes Sweet Mess a reality
Published May 10, 2011
Whether they admit it or not, most everybody loves porn. And so does my Milwaukee-born girl Steviee Hughes, who has made a career out of it. She'll be releasing her company Sweet Mess' first feature length film, "The Addams Family: An Exquisite Films Parody" in mid-August.


text:
My firewall is currently a linux box running shorewall, with WAN, LAN, and
DMZ ports. I have a handful of IP's, but being that my network is not
routed, I am using proxy arp. Everything is running great.
Firewall IP: xxx.xxx.48.146
Firewall GW: xxx.xxx.48.145
Server IP's: xxx.xxx.48.147-152
Server GW's: All use xxx.xxx.48.145 (same as firewall)
As you can see, each one of my servers is using a public IP and my ISP's
gateway. As far as they are concerned, they're connected right to my ISP,
not behind a firewall. Thats the beauty of proxy arp.
I have been experimenting with m0n0wall, and have been very happy with it
so far. Tonite I spent some time moving our firewall to m0n0wall, but the
proxy arp part is giving me problems. I am using the same system for both
the linux firewall and m0n0wall, so all the MAC's tied to the arp requests
should be the same.
I've read a few posts about proxy arp on m0n0wall, where Manuel refers to
proxy arp being what allows m0n0wall to answer arp requests for all the
IP's, and then it has to decide what to do with the traffic. He mentions
the solution being 1:1 NAT, but I don't quite understand why NAT is
required or how exactly it should be configured.
I have created individual proxy arp entries for each of the servers, with a
/32. What's left to configure? If I do need to NAT, can I get an example
entry, because I am not understanding the need for NAT or how I would go
about doing this. I just need to know how to tell m0n0wall where to send
these packets. Shorewall has a "IP ADDRESS PROXYARPED - SOURCE INTERFACE -
DESTINATION INTERFACE" configuration that I am used to, which tells it
where to pass the packets off to.


text:
Some time ago (around the time Non prophets came back from hiatus without Matt) Russell said that he had found backup files he had of the non prophets episodes that aren't on the archive page.
I've searched high and low for the link to these and only recently found Season 1 from 2002 on piratebay and few other torrent sites. As these sites have some illegal content here's a link to the google search instead.
The torrent in question contains at least 50 episodes (in 54 audio files), chatlogs from episodes 9-50, couple of promotional files and theme for star wars imperial march.
The chat logs are recorded from the user non-prophets so I assume this is a chunk of what Russell found from his archives, however the torrent has been uploaded in 2012 so I wonder where it came from.
I'd also want to know if anyone has seen Season 2, 3 or what is missing from season 4. They are not on any of the torrent sites, at least not by the non-prophets name.
I tried asking the non prophets via e-mail if these files exist few years back without getting a reply, I also tried to ask around at freethrought radio if they still have the files for the old episodes without luck.
I'd love to listen through these scratchy recordings as they amuse me. Has anyone come across these?


text:
Pierre Woodman
Pierre Woodman born in 1963 in Auvergne, France is a pornographic film director and photographer. He is the author of more than sixty pornographic ilms, more than one thousand hardcore scenes, more than 1500 photosets and more than 7000 castings, he claims to have bedded more than 3000 women.He has been married three times and is the father of two children. He is divorced from the Russian/Latvian porn star [ [Tania Russof]], and since 2002 he has lived with the photo model Sophie Paris.
He has received numerous awards from some of the Adult Industry's most prestigious organisations for the quality of his films, recognition of a style which more closely reflects the production values of traditional cinema than porn. He is considered to be the number 1 producer in the Adult Industry with a 62 countries distribution network.
He continues to work in the fashion world, doing photo-sessions for big-name magazines ( Blast magazine cover and layout Sept 2006) and discovering fashion models from his castings which have gone on to belong to some of the most important modelling agencies as Alla Krivocheeva for Elite or recently the finalist of the Miss Hungary 2005, Budaï Zsuzsanna. He is often to be found in some of the film industry's important events such as the Cannes Festival, and maintains a close relationship with the world of traditional cinema.
Pierre Woodman makes regular press and television appearances all over the world in which his straightforward and sincere way of talking often amazes people.
His pseudonym Woodman comes from his childhood when he lived in the country and being very good at climbing up trees, his classmates at school called him "the man of the woods" which later became shortened to Woodman. That is why, later on, when he started in the world of Show Business he started signing as Pierre Woodman. On the other side of the Atlantic, this name has a double meaning, with strong sexual overtones. This double meaning was explained to him by his friend Jenna Jameson when they first met in Las Vegas in 1995.
Pierre Woodman's castings
Pierre Woodman started with his castings for Private in 1992. At the beginning there was no commercial motivation behind them, but after the conviction of Mike Tyson for rape, he always asked for witnesses to be there when the castings took place. This is how the "Castings X" and the "behind the Scenes" started. Pierre Woodman has spent more than 15 years in Eastern Europe casting new talent, and this is how he discovered some of the biggest stars in the porn world. Woodman's Casting X DVDs that were later put on release (after 1997) gives a good idea of what takes place in his castings.
Many starlets made their debut and/or got famous making movies in the "Castings X" series, including Silvia Saint, Alexa May, [ [Tania Russof]], [ [Monica Sweetheart]], [ [Monique Covét]], [ [Laura Angel]], [ [Sophie Evans]], [ [Cassandra Wilde]], [ [Dora Venter]], [ [Claudia Ferrari]],[ [Nikki Anderson]] and [ [Michelle Wild]].
They take place in hotel rooms, mainly around Eastern Europe, where his recruitment agents bring him their last discoveries. He has also discovered his exclusive girls in shopping malls and other public places. The girls that he casts are generally 18 or 20 years old. Most of them do not really know what Pierre does. For him, the most difficult stage is to get them to go to his hotel room. Once there, with help from his interpreter, he shows the girls a magazine or some pornographic images and invites them to do something similar. Their initial response is usually no, but after having long conversations with them, he often manages to convince them. Pierre Woodman has already released 64 DVDs from his Casting X series, using Hungarian girls (427), Czech girls (336), Russians (176) and other nationalities (+ 200) and in an interview he claimed to have more than 7000 castings in stock. All of this could make the thousandth edition of Pierre Woodman's Casting X a very real possibility.
External links
- Pierre Woodman at the Internet Movie Database
- http://www.woodmanentertainment.com/
- http://www.pierrewoodman.com/
- http://www.adultdvdtalk.com/forum/topic.asp&q=whichpage=1qqqpagesize=15qqqcat_id=1qqqforum_id=1qqqtopic_id=15554qqq15554.htm
- http://www.wood-ent.com/xcalibur/
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The alleged incident, which also involved some pushing from the part of the 'Friends with Benefits' star's guard, took place outside Nobu restaurant in Mayfair, London on Tuesday, August 2.
Justin Timberlake's bodyguard might have assaulted a photographer for blocking the star's path. The "Friends with Benefits" actor dined out with co-star Mila Kunis and some friends at Nobu restaurant in Mayfair, London on Tuesday night, August 2, but before he made his entrance, a member of his security team was snapped kicking a photog.
Photos documenting the chaotic scene outside the restaurant capture the bodyguard swinging his foot toward the photographer, who was already laying on the floor. The alleged altercation reportedly also involved some pushing. Words are, it happened because a large group of photographers were blocking the "SexyBack" singer's entry.
The bodyguard isn't the only one getting feisty in protecting Justin. At a recent press junket for "Friends with Benefits" in Moscow, his co-star Mila told off a reporter for asking him why he is now focusing on movies instead of music. Replying in fluent Russian, she said, "Why movies? Why not? What kind of question is that? Why are you here?"


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Movies lied. TV shows lied. Everyone lied. College is not the giant crazy party that we all believed we were getting ourselves into. I'm taking six classes and believe me when I say the workload is heavy and I probably would have had a melt down by now if Starbucks wasn't on campus. So on behalf of college students everywhere: Asher Roth, we do not love college or want to be here the rest of our lives.
Leaving my organization's e-board meeting I was launched into a plethora of well dressed business students (sipping on coffee like their life depended on it) and I spotted David Dooley on his way to his fraternity's first meeting. I was instantly intrigued by the mixture of shades of blue he was wearing. Overall, I think I just loved the clean classic look he was rocking on campus.
Warning: I may start sounding like Barney on How I Met Your Mother as I talk about beloved suits! It is very important that every male, no matter what age, has a perfectly fitted suit. I absolutely love this suit and think that a dark color should be the first suit you buy. Please, do us all a favor, and do not go in an all-white suit to a professional frat meeting to network. This is not a high school prom, homecoming dance, wedding, baptism or funeral. White suits are not welcomed. Remember, classic is never out of style. This Fashionisto's suit color is right on point.
The accessories are also just as important as the suit. The tie is a very professional and elegant combination of blue and grey and certainly a must with a blue dress shirt. The greatest invention to me in the whole world is the watch! As you may have noticed I have a passion for a good watch. The watch worn here is great because the frame isn't too bulky.
Hint: I'm a big fan of either a suit in a solid dark color like the one this Fashionisto is wearing. My personal favorite type of suit though is a pinstripe suit, like this Michael Kors one. It adds a bit of a twist to the professional everyday outfit!


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Welcome to 2live4.com!We have a wide selection of beautiful nature and panorama photography for you to enjoy on our site. Feel free to browse. Simply click on one of the photo categories above. To be notified when we add new images to the site, sign up for our free email notification by clicking on the Email Sign-Up button above. You can contact us by clicking on the Contact Us button above.
Browse our Photography!
We have split up our photography into sections. Each section has a button on the navigation bar. There are more sections than will fit on a single navigation bar. Therefore, you can switch between sections of the website by using the >> and << buttons. These buttons will appear at the left and right ends of the main navigation bar at appropriate times for your convenience.
Fine Art Prints
We have recently introduced a new fine art photography website to sell our best work online. The site also will be hosting other artists, and will continually have art added to existing galleries, and new galleries generated over time - so please check it out from time to time. You can access my galleries at the following URL:
We also provide frame
and mat service for our fine art.
Are you Prepared?Prepared for what, you might ask.
There are many different potential natural and man-made disasters that could overtake us in the days ahead.
Perhaps you are one of many that has a growing feeling in your gut that "something bad comes this way." Many others share your concern. In fact, a large majority of Americans believe the country is going in the wrong direction. Interesting, since that fact has not changed from the Bush administration to the Obama administration. Think about that.
The problems facing us are much larger than even a US administration.
So, are you going to be prepared, or are you going to be one of the ones trying to buy food at the local supermarket along with everyone else at the same time, when disaster strikes?
I have created a Preparedness Presentation to help you. You can access it HERE. Please review the content, and let me know if I can help.


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Testing the Demon Hunter in PlayStation All-Stars Battle Royale
Gamescom 2012: We test to see if the son of Sparda can still make the angels weep and the devil cry in PlayStation All-Stars Battle Royale.
We'll begin emailing you updates about %gameName%.
At first blush, Dante seemed to be a jack-of-all-trades, master-of-none sort of guy. As one of the latest additions to the PlayStation All-Stars Battle Royale roster--alongside Ratchet and Clank, Spike (Ape Escape), and Sackboy--Dante has a fairly even selection of ranged and melee attacks. But after spending some quality time with the demon hunter, we discovered that his tastes were a bit more refined (and we're not just talking about pizza preferences).
During our sessions, we found that Dante relied heavily on close-quarters melee attacks to rack up energy and get kills. Individually, his ranged attacks served mainly as a harassment tool rather than a separate play style. On the plus side, he's still a highly mobile character, complete with a horizontal dash and attacks that propel him up and down. Overall, Dante was a very difficult character to play well since he wasn't equipped to wade into a crowd of opponents (unlike the unstoppable Spike). Instead, one-on-one fighting was his forte, where he could let his style shine.
SQUARE: Melee Attacks
Dante's signature sword--Rebellion--as well as his new demonic axe and angelic scythe, were controlled with the square button. Devil May Cry (and Marvel vs. Capcom 3) fans will instantly recognize the rising High Time and falling Helm Breaker attacks, staples from the demon hunter's repertoire. Tapping square by itself unleashed a quick succession of hits with the sword, which could be easily followed up with down plus square: an overhead axe smash that caused slight splash damage at the point of impact.
TRIANGLE: Ranged Attacks
Ebony and Ivory, the only ranged weapons to travel with Dante across the entire series, were relegated to the triangle button. Tapping triangle by itself produced a quick barrage of bullets, and he would automatically target the nearest opponent. However, once the barrage ended, Dante--in customary fashion--would take a moment to add some extra flourish when holstering the pistols: a nearly full second process that left him completely vulnerable.
To compensate, this move (and others) could be canceled into others to build, and extend, combos. While it's featured heavily in the trailer above, we had limited success executing this technique on our own. Even so, the guns' low meter gain and limited range stifled their usefulness outside of combos. The most mileage we got from the guns was the Rain Storm. Performed with down plus triangle in midair, this familiar attack unleashes a hail of bullets from above, and could hit multiple targets.
CIRCLE: Utility Attacks
Remember how annoying Ike and Marth's counters were in Super Smash Bros. Brawl? Well, prepare yourself, because Dante is keeping the frustration alive with an extremely similar counter of his own. It will even counter projectiles, but only the first shot of a multi-shot projectile (say, the first bullet from a machine gun) will be nullified. The son of Sparda also has a horizontal air dash that can be performed on the ground or in the air with forward and circle--extremely handy for escaping group rumbles.
SUPERS: The Killing Blow
The ever-useful Stinger attack is alive and well here as well, serving as Dante's level-two super. True to form, it fires him across the field in a horizontal line--killing any and all who get in the way. You just have to watch out for walls; you can't kill walls. Dante's level-one super, a close-range sword combo, was less useful since alert opponents could knock him out of the move before it actually went off. Meanwhile, Dante's level-three super--the Devil Trigger--transformed him into a one-hit killing machine for roughly 10 seconds.
PlayStation All-Stars Battle Royale will be available for the PlayStation 3 and PlayStation Vita on November 20, and those who purchase the game on the PS3 will receive a free download voucher for the Vita version as well.


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Member since 9/20/2012
- 2 total posts
- 1 review
- 1 question
Reviews & Stories
Worth Every Penny Even at This Stage - United Kingdom, GB
Underwent Rhino a week today here in the UK for a reduction in projection and correction of the bridge due to flatness at the top. I did quite a bit of research and the best advice i found was to go for a private hospital that treats all sorts of conditions; not just cosmetic surgery. I went to visit the surgeon on 2 occasions before i went under the knife so he and I knew exactly what was... READ MORE
Questions from rhino_bot
9 Weeks Post Op and Need Advice Please. Hump Developed & Bulbous Tip Has Dropped? (photo)
Hi, i'm currently 9 weeks post OP and feel I need advice from the experts. I have developed a Hump on the bridge that was never present before Rhinoplasty and the tip seems... READ MORE


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Century Media Records - The Number ONE in Metal worldwide
Helen Vogt
Benjamin Buss
Frederic Lesny
Stefan Gemballa
"It was like we've never rehearsed with someone else", remembers Benjamin Buss (guitars, programming) the first time new singer Helen Vogt visited them in their rehearsal-room. After the departure of Stefanie Duchêne, the Gothic Rockers from Saarbrücken tried a whole lot of different vocalists as the follow-up for Stefanie, who decided to concentrate on her private life and take a step off-stage. When they were looking for a new singer they definitely wanted more than just a substitute for Stefanie. Still, the deep female voice was a trademark they wanted to maintain. "We had rehearsed with many extremely good singers, but it always sounded like a band covering FLOWING TEARS. With Helen we just clicked, it was pure magic. Being a fan she knew some of our songs even better than the rest of us guys. She really kicked our butts", smiles Benjamin. After spending six months with rehearsing new singers they were dying to play live again and write new songs. Playing live has always been their most favourite part about being in a band, which they had proved with successful European tours supporting Therion and Voivod (for Jade) as well as Tiamat and Moonspell (for Serpentine). Helen succeeded her "acid test" on Wave Gotik Treffen festival 2003 and after several single-shows they finally warmed up the famous London Astoria for My Dying Bride. German Hammer stated in their live-review: "During 'Swallow' her dark voice carries across well, the same goes with for the brand new, more heavy and darker songs from Razorbliss or the forceful 'Sistersun'. Strengthened like this, the fiery frontwoman even gallantly flirts with the fans towards the end which gains her additional popularity and FLOWING TEARS a place in the hearts of London's crowd." A lot of the material on Razorbliss developed spontaneously with the new whirlwind called Helen encouraging their heavier edge. Thus, it's only obvious that the album rocks even more than FLOWING TEAR's previous ones. Benjamin explains: "Razorbliss is more from the gut than the majority of our previous material. It was almost like we had just founded the band. Everything was new and anything was possible." The idea to have Angel Dust/Mercury Tide frontman Dirk Thurisch do guest-vocals on the heavy "Believe" came up spontaneously during the recording which brought them back to Woodhouse Studios with long-term producer Waldemar Sorychta (Lacuna Coil, Moonspell). Despite all musical changes Razorbliss will surely not disappoint any FLOWING TEARS fan, but rather offers a refined distillate of the band's most outstanding qualities. Draped in an artwork that perfectly expresses the bittersweet nature of their music, the never ending cycle of life and decay, the modern rock yet dreamy qualities within Razorbliss will surely leave a mark on your heart and soul.
by Century Media Records -


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Priority Health requires that all physical therapy and rehabilitation medicine documentation meet national and Medicare standards.
Jump down this page to:
See therapy code modifier GN/GO/GP billing in this Manual.
Under Medicare, no prior authorization is required. However, Medicare imposes an annual dollar limit or "cap" when services reach a dollar amount set annually by Congress.
Providers may bill beyond the annual dollar amount if it is determined that additional services are medically necessary. The provider must document medical necessity in the record and bill with a KX modifier.
Once services reach $3,700 (for PT/speech therapy combined, or for OT), a prospective review is required before additional therapy is offered, or claims may go to member or provider liability.
Learn more about the therapy "cap" and prospective reviews.
Use the Member Inquiry tool to look up a patient's benefits.
Document supervised and unsupervised modalities to identify which services were provided. For example:
Supervised modalities:
Modalities which require constant attendance:
Unsupervised modalities:
These services are provided as part of an initial evaluation or re-evaluation. When performed in the same day as the evaluation service or for routine assessment when documenting the patient's expected progress in accordance with the plan of care, they are not separately reimbursable services.
Therapeutic procedure descriptive notes should reflect code definition. Examples:
Time-based codes are identified by the statement, " ...each 15 minutes." These codes are reported in 15-minute units of time spent providing skilled services.
Time is determined by a timetable that Centers for Medicare & Medicaid Services (CMS) established, which is recognized as the industry standard:
Documentation: Time spent with the patient can be documented in a number of ways:
Billing for ultrasound and electrical stimulation requires documentation of:
Electrical stimulation can be an unattended and/or attended service:
Skilled gait training is required when billing this service. Therapists are expected to provide clear documentation of the skilled assessment of the patient's gait deviations/deficits to support therapeutic intervention/treatment.
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This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
One of the most efficient and versatile ways to synthesize polyolefin nanocomposites is the
Within recent years, much research in academia and industrial laboratories has focused on the field of polyolefin nanocomposites because of their high potential as materials with novel properties such as improved mechanical properties stiffness, strength, toughness, increased heat distortion temperature, reduced permeability, and flame retardancy. An overview can be found in some books and review articles [
Till today most composites are prepared by mechanical blending of the particles or fibers above the melting temperature of the desired matrix [
MAO is prepared by careful hydrolysis of trimethyl aluminium with water and is a mixture of different oligomers (
The MAO reacts, for example, with the OH-groups of silica or with carboxy groups of oxidized carbon nanotubes or is physically absorbed at the surface (
Excess MAO is washed out. In a second step, the metallocene with the desired properties is added, forming catalytically active polymerization sites on the nanosurface. The thickness of the polymer films, formed by addition of ethene or propene, depends on the polymerization conditions, especially the polymerization time, the kind of metallocene catalyst, and the pressure of the monomer. The
Metallocene/methylaluminoxane (MAO) and other single site catalysts are soluble in hydrocarbons, therefore they can be absorbed perfectly on the surface of particles and fibers or they can penetrate the layers of layered silicates and oxides [
The transition metal complexes can be activated by MAO but also by other bulky cocatalysts such as perfluorophenylborate. By changing the ligand structure, these catalysts allow the synthesis of polymers with a tailored microstructure tacticity and stereoregularity as well as new copolymers with superior properties such as film clarity, tensile strength and lower extractables [
These single site catalysts give by
Heterogeneous nanosized Ziegler-Natta catalysts can also be used for
The composite materials show, for example, improved stiffness with negligible loss of impact strength, high gas barrier properties, significant flame retardancy, better clarity, and gloss as well as high crystallization rates. Even low nanoparticle contents are already sufficient to obtain new or modified material characteristics, particularly a faster crystallization rate and a higher crystallization temperature.
Especially polyethylene and isotactic or syndiotactic polypropylene nanocomposites have been investigated and required as materials for electronic, magnetic, and domestic devices and automotive applications with outstanding properties. Carbon nanofibers (CNF) or multiwalled carbon nanotubes (MWCNT) are an especially attractive class of fillers for polymers because of their intriguing mechanical and thermal properties [
We investigated the properties of polyethylene and polypropylene composites by the
The incorporation of nanoparticles caused an expansion of the application area, and particularly led to an improvement of the stiffness and crystallization velocity. Nanoparticles such as silica (monospheres, 200–250 nm), alumina (20 nm), magnesia (100 nm), calcium carbonate (70 nm), titanium carbide (25 nm), silicium carbide (25 nm), cadmium selenide (10 nm) boron nitride (200 nm) were used in the experiments. Selected ethene polymerization results are shown in
The polymerization activity is high and reaches 243,000 kgPE/molZr in 1 hour. The molecular mass is nearly independent of the kind of nanoparticles of the same filler content. Activity and molecular weight (Mw) decrease hardly if the filler content increases from 1.5% to 9.6% in the case of cadmium selenide. These composite materials are of interest for the electronic industries, because a polyethylene film of a high electric resistance covers every nano selenide particle.
The results are similar, if polypropylene nanocomposites are produced using Cat2 and propene (
For the preparation of syndiotactic polypropylene nano-silica-composites Cat3 [(pMePh)2C(Cp)(2,7-bis-tBuFlu)]ZrCl2 was used [
To find the minimum amount of MAO needed to activate the metallocene (Cat3) and in order to determine whether the applied amount of MAO had any influence on the envelopment of the silica spheres, different amounts of MAO were applied to the silica spheres for heterogenization.
All other conditions (solvent volume, polymerization temperature, amount of M200/MAO, polymerization time, catalyst amount) were kept constant. Several polymerizations were performed with each batch of M200/MAO to determine the optimum amount of MAO for the impregnation. The maximum activity of 3400 kgPol/(molZr·h·molMon/L) was reached when a MAO amount of 420 mg/g M200 was used for the impregnation. For higher amounts of 830 mg MAO/g M200, the activity of the corresponding catalysts decreased to 2400 kgPol/(molZr·h·molMon/L), respectively. All detected melting temperatures lay in the region of 140 °C with no distinct trend visible regarding the applied amount of MAO. The same is true for the molar masses ranging from 500,000 to 600,000 g/mol.
The coverage of the silica spheres with syndiotactic polypropylene is shown in
To reach a better dispersion and envelopment of the silica spheres with polypropylene, the influence of the polymerization temperature was investigated. To ensure comparability among the results, one batch of M200/MAO was synthesized as described above and used as cocatalyst for all subsequent slurry polymerizations. In
At 30 °C it was 2300 compared to 5200 kgPol/(molZr·h·molMon/L) and at 60 °C it amounted to 2400 compared to 9500 kgPol/(molZr·h·molMon/L). As expected, the highest melting temperature of 149 °C was reached for polypropylenes synthesized at 0 °C, then decreased to 141 °C at 30 °C polymerization temperature and to 121 °C at a polymerization temperature of 60 °C, corresponding to a sinking syndiotacticity. The concentration of propene in the reaction mixture was varied in the range from 0.6 to 3.5 mol/L. According to
In the gas phase, experiments were carried out using rac-[Et-(IndH4)2]ZrCl2 which produces isotactic polypropylene. The polymerization was carried out at 30 °C for 60 min with a metallocene amount of 6.25 × 10−6 mol. The propylene concentration was 0.2 mol/L and 0.55 g M200/MAO prepared as described above were used as cocatalyst. An activity of 400 kgPol/(molZr·h·molMon/L) could be reached.
To determine whether MAO-impregnated silica balls are suitable for storage 2.55 g silica balls were impregnated with 11 mL of MAO-solution (10% MAO). Polymerizations of propene were carried out at 30 °C directly after preparation, 2 weeks later, and 11 weeks later. As can be seen from
In order to generate the active complex from the zirconocene and the bonded MAO, the metallocene has necessarily to diffuse to the heterogeneous cocatalyst. Thereby the polymerization takes place near to the filler surface (see
Carbon nanofibers (CNF) and carbon nanotubes (CNT) are an especially attractive class of fillers for polymers because of their intriguing mechanical and thermal properties. They represent one of the strongest and toughest materials known. An entire separation, homogeneous distribution and a good adhesion of the polymer matrix and the single- or multi-walled carbon nanotubes (SWCNT, MWCNT) are important to achieve the full potential of the resulting PE/CNT nanocomposite. The pre-treatments and PFT-technique represent promising routes to improve the mechanical properties of nanotube based composites [
The catalyst activity is not significantly influenced by the presence of (dried) nanotubes. The preparation of CNT containing nanocomposites depended on the same factors like the
Polyethylene multiwalled carbon nanotube (MWCNT) composites were prepared with filler contents of 0.6–3.3 wt%.
The activity decreased with the amount of carbon nanotubes in the composite materials to a tenth of the original value while the molecular weight of the produced polyethylene increased from 700,000 to 1,050,000. The melting temperatures between neat and composite PE were nearly constant.
The incorporated amounts of CNT increased Tc of the resulted nanocomposites in comparison to neat PE. The reference PE had a Tc of about 117.6 °C; 1.0 wt% MWCNT led to an increase of about 8.7 K und a maximum was found at 1.6 wt% filler content, which caused an increase of 8.2 K. Even higher filler loadings led to lower Tcs, but still leveled above that found for pure PE. For example a nanocomposite containing 18.0 wt% of CNT had a Tc of 115.4 °C. The half-time crystallization, representing the CNT nucleating effect, for all samples shown in
Carbon nanofiber (nanowires) are interesting as fillers for polypropylene, because they represent an intermediate between traditional bulk carbon fibers of a large diameter and carbon nanotubes with a diameter in the range of a very few nanometers.
They are available in large quantities at low costs, which make them even more attractive [
Isotactic polypropylene (iPP) nanocomposites were prepared by
The morphology and the quality of the adhesion of the PP matrix to the CNF were obtained from SEM micrographs [
Separated polymerization active sites at the surface of fibers form strings of pearl like structures. The polypropylene matrix draws on the fiber, showing the excellent adhesion between the hydrophobic polymer and the hydrophobic fibers. It can also be seen from this picture, that fiber pull-out has occurred to a certain degree which is obvious from the holes in the polymer matrix.
Incorporated carbon nanofiber led only to a slight increase (about 2 °C in comparison to neat sPP or iPP) of the composite melting point and largely unaffected the crystallinity, independently of the weight percentage. In contrast to that, the crystallization temperature and the halftime of crystallization were much more influenced by the presence of CNF and depended strongly on the quality of the filler distribution. For example a nanocomposite prepared by
The use of carbon nanotubes or multiwalled carbon nanotubes as filler increased the properties of the composite materials. The excellent incorporation of single walled CNT is shown in
All nanotubes are separated from each other. The iPP draws on the fiber as in the other cases. MWCNT are of more interest because they are much cheaper and have nearly the same properties.
The morphology of the isotactic PP/MWCNT nanocomposites prepared by
If the MWCNT are oxidized by nitric acid (ox. MWCNT) more defects are formed on the surface and more MAO can be absorbed resulting in more active polymerization sites. Using Cat1 ([Me2Si(2- Me-Ind)2]ZrCl2/MAO) an activity of 25,000 kgPol/(molZr·h·molMon/L) is reached by a polymerization temperature of 30 °C, for Cat2 (see
Under these conditions the CNF are better covered by the polyolefin. It can be seen from
By longer polymerization times, the thickness of the polyolefin covering the fiber increased. The fiber/MAO/zirconocene system works like a supported catalyst. Filler contents between 0.5 and 50 wt% were possible.
CNT act as nucleating agents, therefore improvements on the crystallization behavior were expected. The crystallization temperature (Tc), crystallinity (Xc) and the half-time of crystallization (τ½) play an important role during the processing of these materials. By reduction of the cooling time required for part solidification, cycle times can be shortened. This can be accomplished by the incorporation of nucleating agents into the neat polymer which accelerate the crystallization.
The effect on the crystallization temperature was most emphatic. Pure iPP had a Tc of about 111 °C. The addition of 0.1 wt% MWCNT led to an increased Tc of 4–5 K. At higher filler contents the enhancement of the crystallization temperature rose rapidly to an amount of 9 K above pure iPP which was reached at a MWCNT content of 1.5–2 wt%. In the case of sPP/MWCNT composites the maximum enhancement of Tc was even up to 15 K higher in comparison to neat sPP, which has a crystallization temperature of about 95 °C. The half time of crystallization is the length of time needed for 50% of the crystallizable material to solidify from the melt. It depends on the (isothermal) crystallization temperature and on the filler content. The crystallization kinetic influences the morphology, which in turn affects the mechanical properties of a semi-crystalline polymer. The half-time of crystallization is reduced significantly with low amounts of nanotubes at all temperatures.
At 130 °C the half-time is 8 min for an iPP/MWCNT composite with 0.1 wt% filler, while 2.5 wt% reduced τ1/2 to only 1.5 min. When the percentage of MWCNT was raised to more than 3 wt% no further appreciable reduction of τ1/2 was obtained.
The effect can be seen by the crystallization rate at a constant temperature (
As expected, carbon nano tube filled composite materials show the highest crystallization rate followed by carbon nano fiber and CB filled syndiotactic polypropylenes. The value for sPP/MWCNT composite is about 20 times higher than for unfilled sPP.
The main advantage of CNF or MWCNT filled PP is the change of mechanical properties. High molecular weight isotactic polypropylene filled with MWCNT is an exceptionally strong composite material. The tensile strength of a composite film increases by 20% if only 1 wt% of MWCNT is incorporated but also the form stability and the crystallization rate from a melt increase strongly and make this composite material suitable for new applications such as in the automotive plastic industries.
PP/MWCNT composites as well as the temperature form stability in dependence ot the filler amount. It can be seen, that there is nearly no dependence of the PP molecular weight and the melting temperature from the filling-grate. The polymerization activity of the homopolymerization is more than ten times higher than the activity in the presence of the nanotubes.
The declination by a constant force decreases with the temperature, but less for CNT filled polypropylene. The stiffness of a sample increased therefore with the amount of CNT in the composite.
The temperature at which a deflection of an iPP/MWCNT sample caused by a force is not reversible (temperature form stability) is of unfilled iPP 48.7 °C (
All polymerizations were performed in dry toluene or dry heptane at 30–70 °C in a 1 L glass autoclave under inert gas atmosphere (argon). The first step of preparation was the absorbance of MAO onto the filler surface. The second step was the addition of a transition metal compound and the formation of catalytically active sites on the surface and the addition of ethene or propene. The monomer pressures were in the range of 2–10 bar.
Prior to the impregnation with MAO, the dried monospheres were dispersed in 20 mL of toluene and the desired amount of MAO-solution was added. The mixture was stirred for 24 h at room temperature. It was then filtered using a D4 fritted glass filter, washed with toluene and dried 4 h under vacuum. The
Carbon nanofibers were dispersed in toluene solution, than MAO, an isotactic working zirconocene, and propene were added and the suspension stirred for approximately 30 min.
In the case of multi walled carbon nanotubes (MWCNT), they were sonicated in a toluene suspension, treated by MAO stirred for 24 h, filtered, and washed with hot toluene. After adding the chiral ansa zirconocene Cat2 and propene isotactic high molecular weight polypropylene iPP/MWCNT, composites with 0.9–50 wt% filler content were obtained. The molecular weights (Mw) of the polypropylene matrix in the nanocomposites were carried out by gel permeation chromatography using a Waters GPC 2000 Alliance system equipped with a refractive index detector, viscosimetric detector and a set of three colums, Styragel type. The solvent used was 1,2,4-trichlorobenzene. The analyses were performed at 140 °C and 1.0 mL/min. The molecular weights were in the range of Mw = 1,200,000–1,700,000. The polymerization activity reached 5000 kgPP/molZr·h [propene].
Polyolefin nanocomposites open up an approach to new classes of materials with particularly good property combinations. A soft polyolefin matrix can be combined with hard inorganic particles or strong layers of silicates or graphene or with fibers of extreme high tensile strength. Carbon nanofibers (CNF) or multiwalled carbon nanotubes (MWCNT) are an especially attractive class of fillers for polymers because of their intriguing mechanical and thermal properties. It could be shown, that an easy way to prepare such polyolefin nanocomposites is the
The authors declare no conflict of interest.
The main unit structure of methylaluminoxane (MAO) and the possible formation of a cage structure.
Hydroxyl or carboxyl groups present on the filler surface can react with added MAO to form a heterogeneous cocatalyst. The MAO is now anchored, but still able to form an active complex with the metallocene.
Structures of metallocenes used for the synthesis of polypropylene and polyethylene.
SEM micrograph of sPP/M200 nanocomposite (magnification 10,000×), prepared by 60 °C (see
SEM micrograph of silica (monospheres) in an isotactic polypropylene matrix prepared by
Syndiotactic polypropylene carbon nanofiber (CNF) composite material. The CNF has a diameter of 100 nm.
Isotactic polypropylene (PP) single walled CNT composite, Magnification 150,000×, for enlarged 400,000×.
Transmission electron microscopy (TEM) micrograph of oxidized MWCNT with a ball of iPP at an active site after 20 min polymerization time, magnification 100,000×.
TEM image of polymer encapsulated ox. MWCNT. Almost every nanotube is covered by a thin and homogenous
Crystallization rate in dependence of different syndiotactic PP composite materials and by three isothermal crystallization temperatures, CB = carbon black for comparision.
Dynamic mechanical measurements of iPP/MWCNT composites measuring the form stability in dependence of the filler content and temperature.
Polyethylene nanocomposites prepared with different inorganic nanoparticles and different parts of filler by
|Activity (kgPP/(molZr·h·molMon/L))
|Part of Filler (wt%)
|Molecular weight (Mw: g/mol)
|Melting point (°C)
Polymerization conditions: 5 × 10−8 mol Cat1, 160 mg MAO, 5.5 bar ethene pressure, 200 mL toluene as solvent, 60 °C polymerization temperature, 30 min reaction time.
Polypropylene nanocomposites of different inorganic nanoparticles and different parts of filler by
|Activity (kgPP/(molZr·h·molMon/L))
|Part of Filler (wt%)
|Molecular weight (Mw: g/mol)
|Melting point (°C)
polymerization conditions: 1.3 × 10−6 mol Cat2, 400 mg MAO, 1 bar propene pressure, 400 mL toluene as solvent, 60 °C polymerization temperature, 4 h reaction time.
Polymerization activity and polymer properties in relation to polymerization temperature, propene concentration, and catalyst amount.
|Polymerization Temperature (°C)
|Propene Concentration (mol/L)
|Catalyst Amount (mol)
|Activity (kgPol/(molZr·h·molMon/L))
|Melting Point (°C)
|Molecular Weight (Mw) (g/mol)
|1.30 × 10−6
|1.40 × 10−6
|1.30 × 10−6
|6.00 × 10−7
|7.00 × 10−7
Polymerization conditions: polymerization time (30–180 min, solvent 200 mL of toluene, amount of M200/MAO 0.55 g, amount of triisobutylaluminium (TIBA) 2 mmol, metallocene: Cat3.
Stability of MAO impregnated nano silica balls in syndiotactic propene polymerization.
|Weeks after preparation
|Activity (kgPP/(molZr·h·cMon))
|Filler content (wt%)
Polymerization conditions: polymerization temperature 30 °C; polymerization time 30 min; 2 bar propene pressure; solvent 200 mL toluene; 0.55 g silica/MAO; zirconocene = 1.3 × 10−6 mol/L; TIBA 2 mmol.
Polymerization activity and polymer properties of polyethylene/multiwalled carbon nanotube (MWCNT) composites.
|Amount MWCNT (mg)
|Filling-grade (wt%)
|Activity (kgPE/(molZr·h·cMon))
|Molecular weight (Mv) (g/mol)
|Melting temperature (°C)
|Crystallization temperature (Tc) (°C)
|2.7 × 104
|5.8 × 103
|6.9 × 103
|5.4 × 103
|4.0 × 103
Polymerization time: 30–120 min; solvent: 200 mL toluene; MAO: 300 mg; zirconocene: 2 × 10−6 mol Cat3 ([(pMePh)2C(Cp)(2,7-bis-tBuFlu)]ZrCl2); Mv: viscosity average molecular weight.
Polymerization activities, viscosity average molecular weights, melting temperatures, and form stability temperatures of iPP/MWCNT samples with different amounts of fillers at a force of 1.8 MPa.
|Amount MWCNT (mg)
|Filling-grade (wt%)
|Activity (kgpp/(molZr·h·cMon))
|Molecular weight (Mv) (g/mol)
|Melting temperature (°C)
|Temperature form stability (°C)
|5.6 × 104
|4.3 × 103
|3.8 × 103
|4.6 × 103
Polymerization time: 15–30 min; solvent: 200 mL toluene; MAO: 200 mg; zirconocene: 2 × 10−6 mol Cat2.


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California Family Law: Spousal Support
In California, family law spousal support is often ordered when one party has no income or significantly lower income than the other party. Spousal support can be granted on a temporary, permanent or limited time basis. Each case is decided based on the facts and the presentation of evidence of the parties. If a divorcing couple agrees to a particular arrangement, the court in California will generally take that agreement into consideration and honor it as long as it is within the law.
Spousal Support in California
Each state has its own legal guidelines for spousal support cases. When determining spousal support in California, a court will take into consideration the following factors:
- The length of the marriage or partnership;
- The needs of each party;
- Earnings and earning capacity of each party and what each party can afford to pay;
- Whether having a job would make it too difficult for the custodial spouse to take care of children;
- The age and health of each party;
- Debts, assets and property of each party;
- Whether one spouse or partner helped the other get an education, training, career or professional license;
- Whether domestic violence was part of the marriage or partnership,
- Whether one spouse's career was affected by unemployment, taking care of the children or home; and
- The tax implications of spousal support.
The court will also consider any other factors that are specific and pertinent to your divorce case in coming to a decision about spousal support.
In cases where support is needed during divorce proceedings to help one spouse maintain a household independently and/or care for children from the marriage, the party who needs support can request a temporary support order. The court will consider the factors above and use a formula to determine the amount of award. This is a temporary order that will only last until the end of the divorce proceedings. It can help a party to get through divorce more easily if income is an issue.
Getting Legal Help
If you have further questions about California spousal support law, you should talk with an experienced family law attorney. An attorney can advise you of your likelihood for receiving a support order based on the facts of your divorce case. Spousal support is often granted when a disparity in incomes between divorcing spouses exists. A spousal support award may be ordered to give a payee souse the opportunity to adjust to the changed circumstances presented by divorce.
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- Provide your contact information
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Indonesian Peningkatan Kualitas Publikasi Internasional (PKPI) program
Northern Illinois University offers the opportunity for doctoral students studying at Indonesian universities to participate in the PKPI program at NIU. Students selected for this program will work under the supervision of a selected professor to develop and advance their research projects or articles for publication. The program includes a weekly seminar to prepare scholars for publishing in an academic journal. PKPI is funded by DIKTI, Directorate of Higher Education of the Ministry of Research, Technology and Higher Education of the Republic of Indonesia.
Why NIU?
- Established in 1895, Northern Illinois University is the second largest public university in the state of Illinois. It is located in the city of DeKalb, 65 miles west of Chicago.
- NIU is accredited by the United States Higher Learning Commission and is a member of the country's most prestigious public university association, the Association of Public and Land-Grant Universities (APLU), a non-profit association of public research universities, land-grant institutions, and state university systems, as well as the Universities Research Association (URA), an international consortium of 83 leading research oriented universities. NIU is classified by the Carnegie Foundation for the Advancement of Teaching in the category of Research Universities (high research activity). It also has been awarded an elective classification for Curricular Engagement and Outreach and Partnerships, which recognizes institutions of higher education for their collaboration with their larger communities (local, regional/state, national and global).
- NIU has seven degree-granting colleges, which offer 60 undergraduate majors, 70 graduate programs, and more than 20 fields of studies leading to doctoral degrees.
- NIU has a strong reputation in Indonesia and is developing academic partnerships with several Indonesian universities.
- Notable NIU alumni from Indonesia include Ryaas Rasyid, Affan Gaffar, Anies Baswedan, Riswanda Imawan, Andi Mallarangeng, Ikhlasul Amal, and Ramlan Surbakti.
NIU Graduate Programs include the following fields of studies:
- College of Business: Accounting Science, Business Administration, Management Information Systems, Taxation
- College of Education: Adult and Higher Education, Counseling, Counselor Education and Supervision, Curriculum and Instruction, Early Childhood Education, Educational Administration, Educational Specialist, Educational Psychology, Educational Research and Evaluation, Elementary Education, Foundations of Education, Instructional Technology, Kinesiology and Physical Education, Literacy Education, School Business Management, Special Education, Sport Management.
- College of Engineering and Engineering Technology: Electrical Engineering, Engineering Education, Industrial and Systems Engineering, Industrial Management, Mechanical Engineering.
- College of Health and Human Sciences: Applied Family and Child Studies, Audiology, Communicative Disorders, Family and Consumer Sciences, Health Education, Nursing, Nutrition and Dietetics, Physical Therapy, Public Health.
- College of Law
- College of Liberal Arts and Sciences: Anthropology, Applied Probability and Statistics, Biological Sciences, Chemistry, Communication Studies, Computer Science, Economics, English, Foreign Languages, Geography, Geoscience Education, History, Mathematical Sciences, Mathematics, Middle School Mathematics Education, Philosophy, Physics, Political Science, Psychology, Public Administration, Sociology.
- College of Visual and Performing Arts: Art, Art Education, Music, Theatre Arts.
Opportunities for Sandwich Scholars:
- Access to NIU Founders Memorial Library's extensive reference materials, databases, and the Donn V. Hart Southeast Asia Collection
- Research mentorships with an NIU professor
- Weekly seminar on article development, writing and publishing
- Other seminars on campus, including Friday lecture series hosted by the NIU Center for Southeast Asian Studies
- On-campus housing, which includes a meal plan with some amenities
- O'Hare International Airport pick-up and return
Program Fees and Expenses:
- PKPI Scholars are responsible for covering their own travel and expenses while in the United States and for program fees. Successful applicants are encouraged to apply to DIKTI to cover these costs.
How to apply?
- Please submit a letter of application along with your research plan (research or journal abstract) and curriculum vitae to Professor Judy Ledgerwood, Director, NIU Center for Southeast Asian Studies, at: email@example.com
- Successful applicants will receive a letter of acceptance (LoA) indicating when they could start the sandwich-like program.
More Information
If you have any questions about this program, please contact:
Center for Southeast Asian Studies
Northern Illinois University
520 College View Court
DeKalb, Illinois 60115
Phone: (+1) (815) 753-1771
Fax: (+1) (815) 753-1776
Email: firstname.lastname@example.com
Website: www.cseas.niu.edu


text: Concord Marina Knox Co I stopped by the Marina around 1:30 today. I found a Long-tailed Duck swimming with about 25 Coots in the part of the Marina that faces Kingsgate subdivision. As you follow the one-way road around the hill with the restaurant on top of it, take the lower road and stop next to the cart bins. It was in the flock of Coots at this point. Both the Coots and the Duck hide among the boats if there is boat or human traffic in the vicinity. But I was able to observe it easily for about 10 minutes. This is the marina, not the Concord Yacht Club... Susan Hoyle Knoxville,TN =================NOTES TO SUBSCRIBER===================== The TN-Bird Net requires you to SIGN YOUR MESSAGE with first and last name, CITY (TOWN) and state abbreviation. You are also required to list the COUNTY in which the birds you report were seen. The actual DATE OF OBSERVATION should appear in the first paragraph. _____________________________________________________________ To post to this mailing list, simply send email to: tn-bird@xxxxxxxxxxxxxx _____________________________________________________________ To unsubscribe, send email to: tn-bird-request@xxxxxxxxxxxxx with 'unsubscribe' in the Subject field. ______________________________________________________________ TN-Bird Net is owned by the Tennessee Ornithological Society Neither the society(TOS) nor its moderator(s) endorse the views or opinions expressed by the members of this discussion group. Moderator: Wallace Coffey, Bristol, TN wallace@xxxxxxxxxxxxxxxxxxx ------------------------------ Assistant Moderator Andy Jones Cleveland, OH ------------------------------- Assistant Moderator Dave Worley Rosedale, VA __________________________________________________________ Visit the Tennessee Ornithological Society web site at http://www.tnbirds.org * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ARCHIVES TN-Bird Net Archives at http://www.freelists.org/archives/tn-bird/ MAP RESOURCES Tenn.Counties Map at http://www.lib.utexas.edu/maps/states/tennessee3.gif Aerial photos to complement google maps http://local.live.com _____________________________________________________________


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Sexual selection theory predicts that sex roles will be determined by the operational sex ratio (OSR), the sex ratio among individuals searching for mates at any given time. There are two predictions: (i) the sex which is in `excess' will be the more competitive sex with respect to access to mates; and (ii) the sex of which there is a `shortage' will be the more choosy with respect to potential partners. We examine the second prediction and find that current OSR theory does not consider an important factor which affects mate choice. This factor is sex differences in variation in mate quality. Hence, we develop a new model of mate choice which shows that the parameter which should be optimized during mate choice is the trade-off between reproductive rate and mate quality. If mate choice is too lax, reproductive rate may be high but partners will be of low quality. If mate choice is too stringent, partners will be of high quality but reproductive rate will be low because such partners will be rare. Stringency of mate choice is, therefore, a facet of OSR theory. Indeed, our model shows that OSR theory can be used to integrate the effect of sex differences in both mating rate and variation in mate quality to predict the direction of mate choice. Our model suggests that: (i) mate choice is only selected when individuals of the opposite sex vary in their quality as mates; (ii) if the extent of variation in mate quality is equal within each sex, the sex with the lower potential mating rate will be the more choosy sex; but (iii) if there is sufficiently greater variation in mate quality among the sex with the lower potential reproductive rate, the sex with the higher potential mating rate will be the more choosy sex. Additionally, this approach demonstrates that competition and choice need not necessarily be opposite sex roles, as is commonly assumed. This is because subtly different forms of the OSR are used to predict competitive and choosy behaviour, respectively.
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text:
What If You Were Born Wearing High Heels?
OK, this Julie Rrap image is so last decade, but I just came across it. And I have to say, "Ouch!" Although, maybe the permanent butt lifting qualities would be worth it? I mean, skin heels can't be less comfortable than the "It" Alexander McQueen pumps. [WOW Report]


text:
Contact Us
Erie SeaWolves
UPMC Park
110 E 10th St
Erie, PA 16501
(814) 456-1300 (Phone)
(814) 456-7520 (Fax)
Email: email@example.com
Charitable Donation Requests:
To request a charitable donation for your organization, group or cause, you must fill out a Charitable Donation Request Form Here.
Pocket Schedule Requests:
SeaWolves pocket schedules are available at numerous team partners in the Erie area, in the SeaWolves business office during regular office hours and at the SeaWolves box office during the season.
Pocket schedule requests must be mailed to:
Erie SeaWolves
Attn: Schedule Request
110 East 10th Street
Erie, PA 16501
Please include a self-addressed, stamped return envelope.


text:
I am again stuck. Last week command in msfconsole:
worked fine and all three output type files were created fine.db_nmap -v -sV 18.104.22.168/24 -oA subnet_1
I did not do any changes. Booted today backtrack, run a command
And only one gnmap type is created, no xml and no nmap.db_nmap -v -sV 184.108.40.206/24 -oA subnet_2
If I run
than I get a file with name -oXdb_nmap -v -sV 220.127.116.11/24 -oX subnet_2
Any help with that?