text:
|Publication number
|Publication type
|Application number
|Publication date
|Feb 19, 2002
|Filing date
|Dec 20, 1999
|Priority date
|Dec 20, 1999
|Fee status
|Publication number
|Robert Racz
|Original Assignee
|Basf Corporation
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (57), Referenced by (13), Classifications (14), Legal Events (6)
|External Links: USPTO, USPTO Assignment, Espacenet
1. Field of the Invention
The present invention relates to methods for removing volatile organic material from an aqueous dispersion of a synthetic polymer. In particular, it relates to the removal of volatile organic contaminants (VOCs) from latex dispersions.
2. Description of Related Art
In the polymerization of organic monomers in an aqueous medium to form a dispersion of polymer in water, the resultant dispersion typically contains residual organic impurities which result from incomplete conversion of monomers, impurities in raw materials and undesirable by-products formed during the polymerization reaction. For example, in a styrene-butadiene aqueous emulsion polymer, these impurities can include: unreacted styrene and butadiene; ethyl benzene, an impurity in the styrene; 4-vinyl cyclohexene (VCH), an impurity in the butadiene; 4-phenyl cyclohexene (PCH), a by-product of the polymerization.
Conventionally, organic volatiles have been removed from an aqueous polymer dispersion made by emulsion or suspension polymerization by a process known as steam or inert gas stripping. In this process the dispersion is contacted with steam, air or an inert gas (e.g., nitrogen) at either reduced or elevated temperatures and pressures. This process can be carried out in a variety of different types of equipment, for example, columns, semibatch strippers, thin film evaporators and plate evaporators. However, because of the strong interaction between the organic volatiles and the polymer, to achieve a low level of volatiles in the dispersion requires high ratios of stripping medium/dispersion. To generate this stripping medium requires the use of large amounts of energy and results in high energy costs.
Another method which has been used for removing VOCs from natural and synthetic polymeric dispersions involves contacting the dispersion with an adsorbent material, such as carbon black, activated charcoal, silica gel, aluminum oxide and ferric oxide. A similar method is known for purifying various polymer resins wherein the polymer is first dissolved in a solvent and the resulting solution is contacted with alumino-silicates. Some prior art processes for decolorizing or deodorizing polymeric materials have suggested that stripping and adsorbent treatment could be used alternatively or even serially.
None of the prior art processes for purification of aqueous polymeric dispersions has been able to provide extremely low residual VOC levels under conditions that are both effective and economical.
The present invention overcomes the problems and disadvantages associated with current strategies and designs in purification of polymer dispersions.
The present invention relates to a process for removing VOCs from a polymer dispersion which process, in the preferred embodiment, comprises steam, air or inert gas-stripping the dispersion in the presence of a particulate adsorbent. This process can be employed to purify any polymeric dispersion, emulsion, suspension or solution and is particularly useful in the removal of VOCs from aqueous polymeric latices such as those based on styrene butadiene polymers or acrylic polymers. This process provides for the rapid and economical removal of VOCs. The process of this invention can result in achieving lower residual VOC levels than the prior art methods employing either steam stripping or particulate adsorbent treatment and can be employed to achieve similar VOC levels at lower energy costs than prior art methods. In one embodiment of the process of this invention, a slurry of adsorbent particles in the polymer dispersion is subjected to steam stripping, followed by separating the adsorbent particles from the purified latex dispersion. In another embodiment of this invention, the adsorbent particles are retained in the stripping vessel in the form of a fixed or fluidized bed or otherwise immobilized in said stripping vessel. In yet another embodiment, discrete quantities of the particulate adsorbent material are provided in latex permeable flow-through enclosures (e.g., in a manner analogous to teabags). These adsorbent-containing enclosures can be added to the stripping vessel separately or with the latex feed. Such an arrangement greatly facilitates the separation of spent adsorbents from the purified polymeric stream. If desired, both the stripping media and the adsorbent can be further processed to regenerate the reagents and recover valuable VOCs such as residual monomers.
Other objects, advantages and embodiments of the invention are set forth in part in the description which follows, and in part, will be obvious from this description, or may be learned from the practice of the invention.
FIG. 1 is a process flow diagram illustrating one embodiment of the process of the present invention.
FIG. 2 is a graph showing the level of volatile monomer removal by steam stripping alone, cold adsorbent contact alone, and using an embodiment of the present invention employing steam stripping in the presence of adsorbent particles in a flow-through enclosure.
The process of the present invention can be used to remove volatile organic contaminants (VOCs) from polymeric dispersions, emulsions, or suspensions and, in particular, any stable aqueous dispersion of a water insoluble polymer. Among suitable polymers are those prepared from monomers comprising at least one of the following groups:
CH2═CH—, and
whether homopolymerizable or not. Examples are the α,β-ethylenically unsaturated monocarboxylic acids and esters and amides thereof, α,β-ethylenically unsaturated aldehydes, α,β-ethylenically unsaturated dicarboxylic acids and esters, amides, half esters, and half amides thereof, α,β-ethylenically unsaturated nitrites, hydrocarbons such as α-olefins, conjugated diolefins, vinylaryl compounds, vinyl alkyl ethers, vinyl halides, vinylidene halides, vinyl sulfides, vinyl acyloxy compounds (esters of saturated carboxylic acids and ethylenically unsaturated alkanols), vinyl amines and salts thereof, vinyl ureido monomers, vinyl compounds having heterocyclic nitrogen-containing (HN<) groups, and halogen, hydroxyalkyl, or aminoalkyl substituted derivatives thereof, whether homopolymers or copolymers. The aqueous dispersions of these polymers and methods for their preparation form no part of the present invention, and any such polymer may be treated in accordance with the present invention. Mixtures of different polymer dispersions are useful, as are aqueous dispersions prepared by first polymerizing in solution or suspension in an organic solvent, then dispersing the material in an aqueous medium.
Specific examples of suitable monomers which may be homopolymerized or copolymerized to obtain water insoluble polymers for treatment according to the invention are acrylic acid, methacrylic acid, itaconic acid, maleic acid, phthalic acid, esters and half esters thereof with alkanols having 1 to 20 carbon atoms, such as methanol, ethanol, butanol, pentadecanol and the like, and amides and half amides thereof with ammonia or organic amines, acrolein, methacrolein,, ethylene, propylene, isobutene, butadiene, isoprene, chloroprene, styrene, vinyltoluene, vinyl methyl ether, vinyl isobutyl ether, vinyl chloride, vinyl bromide, vinylidene chloride, vinyl sulfide, vinyl acetate, vinyl propionate, the vinyl pyridines, primary amino compounds such as β-aminoethyl vinyl ether, aminopentyl vinyl ether, secondary amyl t-butyl aminoethyl methacrylate, tertiary amino-containing compounds such as t-dimethylaminoethyl methacrylate, and the allied amine salts such as the chloride or hydroxide, ureido monomers such as are disclosed in U.S. Pat. Nos. 2,881,155; 3,300,429; and 3,356,627, examples being β-ureidoethyl acrylate, β-(N,N′-ethyleneureido) ethyl acid maleate, β-ureidoethyl vinyl ether, N-vinyl-N,N′-ethyleneurea, N-vinyloxyethyl-N,N′-ethyleneurea, N-methacrylamidomethyl-N,N′-ethyleneurea, and N-dimethylaminoethyl-N′vinyl-N,N′-ethyleneurea, β-hydroxymethyl methacrylate, N-hydroxyethylacrylamide, N-methylolacrylamide, and N-(dimethylaminoethyl)acrylamide. Homopolymers, copolymers, and graft, block, or segmented polymers are included. Conventional methods of obtaining the aqueous dispersions are utilized.
The invention will be described hereinafter in terms of one preferred polymer system of the present invention—the styrene butadiene (SBR) latex system. The preferred SBR latex product is a cold polymerized styrene/butadiene containing from about 20-40% styrene produced in a continuous reactor chain (CSTR). This product is advantageously maintained at low cross-linking density by terminating the polymerization reaction at 70-85% monomer conversion.
The polymer systems purified according to the process of the present invention initially contain undesirable amounts of VOCs. The term "VOC" is intended to include any or all volatile organic materials that are desirably removed from these polymer systems. In some polymer systems, the VOCs may comprise mainly unreacted monomers. In other systems, monomer feed contaminates, reaction by-products, catalyst solvents or the like may also be present. In accordance with the customary usage in the particular polymer system art, the term "VOC" may be employed to refer to undesirable residual monomers or art-recognized major impurities or even all volatile materials. In the SBR latex systems of the preferred embodiment, the VOCs typically monitored include either the residual styrene monomers, or to all volatiles, including PCH, VCH and cis- and trans-butene. As is known in the art, VOC levels in any polymer sample can be determined using gas chromatograph (GC) equipment.
Typical VOC (styrene) levels in SBR latex systems of the type described above can be in the range of 25,000 to 50,000 ppm, total VOCs for this same product would be in the range of 27,000 to 55,000 ppm. The process of the present invention can be employed to substantially reduce the VOC levels of a polymer dispersion. While the process of the present invention can be employed to purify polymer dispersions as produced, in the preferred practice, the polymer dispersion to be purified is subjected to a preliminary treatment step designed to reduce the VOCs to levels of about 5000 or less and more preferably to levels of about 2000 ppm or less. This preliminary step, which typically is designed to recover the major portion of residual monomers, can employ any of the known processes such as distillation.
The process of the present invention can be employed to reduce the level of VOCs to below 1000 ppm, more preferably below 500 ppm and most preferably below 100 ppm.
The stripping media employed in the process of the present invention can be any suitable gas or vapor that is effective to remove VOCs from aqueous dispersion environments. Examples of such media include air, steam and nitrogen. Preferred are stripping systems employing steam. Stripping with a gas/vapor stream is a well-known purification step and can be effective under a number of known conditions of pressure and temperature. The present invention contemplates the use of vacuum or atmospheric stripping and at temperatures that may vary according to the particular polymer system employed. For the SBR latex system described above, steam stripping at slight vacuum (e.g., 5-10 psia) is the preferred mode of operation.
The stripping step of the present invention can be carried out in any of the conventionally employed apparatus. This may be either a batch or continuously operating device. The quantity of the stripping medium is dependent on the temperature and pressure of the system, on the type of volatile to be removed, on the initial concentration of that volatile in the dispersion and the desired final level. For the preferred SBR system of this invention, ratios of steam to latex should generally be in the range of from about 0.1 to about 1.0, and preferably about 0.3 to about 0.5. If the contacting is carried out in a batch process, temperature, pressure, flow rate of stripping medium and time are the controlling process parameters. In a continuous contacting device, temperature, pressure, stripping medium/polymer ratio and equivalent theoretical equilibrium stages are the controlling parameters. For the majority of organic volatiles with the majority of aqueous polymer dispersions, removal of the volatiles is controlled by vapor-liquid equilibrium considerations. The precise process conditions for a specific case can be calculated by the application of known thermodynamic principles and chemical engineering principles of mass transfer/separations processes.
In any steam, gas, or vapor stripping process, the exiting vapors or gases may be purified and reused by contacting the gas or vapors with an adsorbent material or catalyst, further stripping the stripping gas or vapor to remove impurities, a combination thereof, or any other means common to those of skill in the art. See, e.g., U.S. Pat. No. 5,414,193, and U.S. Pat. No. 5,322,927, incorporated by reference in their entirety.
The adsorbent material used in the process of the present invention can be any suitable particulate material that is effective to adsorb VOC in the dispersion environment. Suitable adsorbents include activated carbon, carbon black, activated charcoal, bituminous coals, silica gels, clays, alumina based materials, alumino-silicates, metal oxides and shell based materials. Also, useful are polymeric based materials such as polystyrene cross-linked with divinyl benzene. The preferred adsorbent is activated carbon. One suitable form of activated carbon is Cal 12�40, a granular decolorizing carbon sold by Calgon Carbon Corporation. Other suitable commercially available materials include Sylosiv� A10 (an aluminosilicate zeolite from Grace Davidson) and Dowex� L493 (a polymeric adsorbent from Dow-Chemical).
The adsorbent carbon particles should be of a size that they are separable from the polymer dispersion, whether the carbon is in the form of a fixed bed or a moving bed, or is simply slurried with the polymer and then separated by vacuum or pressure filtering, centrifugal filtering, gravity settling, or centrifugal settling. The carbon should be hard and abrasion resistant. The particles are suitably between about five-sixteenths in. and No. 400 mesh, U.S. Sieve Series, from about No. 5 mesh to about No. 50 mesh being preferred for a carbon bed, and smaller particles than No. 50 mesh being preferred when the slurry method is used. The desired particle size depends somewhat upon the apparent viscosity of the aqueous dispersion; a more viscous product requires the use of larger carbon particles in a bed, because of the pressure drop. The capacity for adsorbed materials, as well as selectivity for given impurities as against materials desirably left in the dispersion such as emulsifiers and dispersants, and as against water are in part dependent upon surface area, pore size, water wettability, total pore volume, and surface polarity or degree of oxidation of the surface. Generally, the physically hard "liquid phase carbons" adapted for aqueous systems which have the desired physical strength, and adsorption capacity, are useful. Suitable materials may have a total surface area of from 750 to 2000 square meters per gram, having three classes of pores in a given particle, large ones greater than about 1000 angstroms in diameter, and medium sized pores between 50 and 1000 angstroms in diameter, which interconnect smaller pores being less than 50 angstroms in diameter. One useful activated or adsorbent carbon is petroleum coke prepared by the destructive distillation of petroleum materials having a similar total surface area, and having a large proportion, 50 to 80%, of the pores in the size range of 10 to 40 angstroms, preferably 20 to 30 angstroms, in diameter. Another type is coconut shell charcoal. Passing a sample of the dispersion at the specified temperature through a laboratory size column of the carbon readily establishes whether or not a given carbon will coagulate the dispersion.
The process of the present invention which comprises stripping a polymeric dispersion in the presence of an adsorbent of the type described above can be carried out in a number of ways. In one preferred embodiment, the adsorbent is added to the polymeric dispersion stream to form a slurry which is then fed to the stripping unit. In this embodiment, the solid adsorbents generally can be advantageously present at levels of from about 1% to about 20% by weight based on polymer solids. Preferably, the solid adsorbent is present at levels of from about 2% to 10% and more preferably the adsorbent is employed at levels in the range of from about 4% to 6%. For the most preferred system employing activated carbon particles and the SBR latex dispersion, about 5% activated carbon is used.
The addition of solid adsorbent particles to the polymer dispersion can take place using any known mixing equipment, including inline mixing, injection mixing or batch mixing in the stripping vessel or in a separate mixing vessel. In the preferred SBR/activated carbon system, the activated carbon can be simply added to the stripping vessel containing the dispersion in a batch type operation, or can be continuously added to the latex stream prior to feeding the slurry stream to a continuous stripping vessel.
In the adsorbent slurry embodiment described above, it will be necessary to separate the spent adsorbent from the purified stripped latex. This can be accomplished in several ways as will be appreciated by those skilled in the art of solids separation. In one preferred embodiment, the spent adsorbents can be separated from the purified stripped latex dispersion after the slurry leaves the stripping zone. Depending on whether the stripping is carried out in batch or continuous mode, the downstream removal of spent adsorbent can be either batchwise or continuous. Conventional separation techniques such as filtration, centrifugal separation, gravity separation, and the like, can be used.
Another embodiment of this invention involves the use of flow-through enclosures containing a plurality of adsorbent particles to facilitate the latex dispersion stripping in the presence of adsorbents. These enclosures, which function somewhat in the manner of teabags, are permeable to the flow of the polymer dispersion and thereby facilitate contact between the latex and the adsorbent, but retain the adsorbent particles in the enclosures. This approach allows for a wider choice of adsorbent materials and particle size or particle size distributions, and facilitate the removal of the spent particulates from the latex dispersion after stripping.
The flow-through enclosure can be made in any suitable size and shape and from any suitable porous material. Non-limiting examples of such materials include porous or mesh-like woven or non-woven fabrics made from natural or synthetic materials such as polyethylene, polypropylene, polyesters, polyamides, cotton, paper and the like. Flexible or rigid materials can also be employed, such as metal cage-like structures. The flow-through enclosures may be fabricated in any shape or size appropriate for mixing into the latex dispersion and which facilitates the contact of the adsorbent with the latex. Suitable examples include a rectangular or square pillow shape, a spherical shape, a cylindrical shape and a cone or pyramid shape. The flow-through enclosure may be permanently sealed or it may be provided with means to permit opening and refilling the enclosure with fresh adsorbent when necessary.
In the embodiment of the process of the present invention employing the flow-through enclosures, the enclosures may be added to the polymeric dispersion prior to the stripping vessel, or the enclosure can be added to the stripping vessel directly. For purposes of separation of the enclosures from the purified stripped dispersion, the enclosures can be retained in the stripping vessel, e.g., by a screen or similar retaining mechanism, or the enclosures can be separated from the purified stripped dispersion downstream of the stripper, e.g., by gravity separation or screening.
Another embodiment of this invention involves the retention of the adsorbent elements in the stripping vessel. In this embodiment, a fixed or fluidized bed of the adsorbent material is provided and retained in the stripping vessel, in a manner known to those skilled in the art of solids/fluid contact.
In an alternative embodiment, the adsorbent material can be immobilized in the stripping vessel by providing a porous coating of the adsorbent material on an appropriate inner surface of the vessel. For example, in a continuous stripping column, trays, downcomer or riser structures can be provided with the adsorbent coating.
In all of the described embodiments, the spent adsorbent can be regenerated with optional recovery of valuable VOC removal from the dispersion (e.g., residual monomers). In the case where the adsorbents are retained in the stripping vessel, it is possible to perform this regeneration in batchwise operations in the stripping vessels.
While not wishing to be bound by any particular theory, applicant believes that the process of the present invention achieve lower VOC levels in treated dispersions than are achieved with either stripping or adsorption alone or even their use sequentially. It is believed that the presence of adsorbent particles during the stripping process achieves this unexpected result by capturing VOCs released into the aqueous phase of the dispersion and therefore shifting the equilibrium for the reversible diffusion of VOCs out of and back into the latex solids. This effect synergistically facilitates the stripping media scrubbing of the VOCs that reach the aqueous phase of the dispersion.
The process of the present invention will now be described in connection with FIG. 1 which shows one embodiment thereof.
Polymer dispersion stream 1 containing the output from an SBR polymerization process is continuously fed to a mixing zone 2, which can be a separate mixing vessel or an inline mixing arrangement. Separately, an appropriate quantity of a particulate adsorbent material, e.g., activated carbon, is supplied to the mixing zone through supply conduit 3. The mixed slurry of SBR latex and activated carbon leaving the mixing zone is fed via conduit 4 to the stripping vessel 5. The stripping media, e.g., steam, is fed to the stripping vessel 5 via conduit 6. In the stripping vessel, the mixed slurry is stripped of VOCs and a first portion of the VOCs are removed by the stripping media, e.g., steam, through gaseous effluent stream 7. The mixed slurry treated in the stripping vessel is continuously removed from the vessel by product slurry line 8. This mixed slurry now contains purified latex dispersion and spent adsorbent particles containing adsorbed therein a second portion of the VOCs. This mixed product slurry is then fed to an adsorbent separation zone 9 where the spent adsorbent particles are removed from the purified latex dispersion. Purified product can be recovered via stream 10, while spent adsorbents can be forwarded via conduit 11 to an adsorbent regeneration zone 12. Regenerated adsorbent from zone 12 can be used as the feed or makeup feed for supplying the mixing zone 3. Optionally, the stripping medium leaving the stripping vessel can be forwarded to a recovery zone 13 where valuable VOCs can be recovered in a known manner and the stripping medium can be regenerated for use in feed stream 6.
The following examples are given to illustrate preferred embodiments of this invention and are not intended to limit the invention in any way. It should be understood that this invention is not limited to the above-mentioned embodiments. Numerous modifications can be made by one skilled in the art having the benefits of the teachings given here. Such modifications should be taken as being encompassed within the scope of the present invention as set forth in the appended claims.
The following examples further describe and demonstrate embodiments within the scope of the present invention. The examples are given solely for the purpose of illustration and are not to be construed as limitations of the present invention, as many variations thereof are possible without departing from the spirit and scope of the invention.
To demonstrate the process of the present invention and its advantages, an SBR latex was treated with three separate purification methods: (1) steam stripping, (2) activated carbon adsorption, and (3) according to the present invention, steam stripping in the presence of activated carbon. In all three methods, a batch-type process employing a 2 gallon stirred reactor vessel was employed. In each method 3800 g of SBR latex was added to the vessel. For the activated carbon only treatment, the reactor vessel was stirred at room temperature. In the steam stripping methods, 1200 of excess water was added. The vessel was heated to boiling (60� C.), steam removed and condensed at the rate of 400 g per hr. The vessel was operated at 25-30 in of mercury. Samples of the latex were taken at one hour intervals and analyzed for free styrene content using a GC. The data for all three approaches is set out in Table 1 below.
Free Styrene (ppm)
Stripping with
Steam Only
Activated Carbon Only
Activated Carbon
1 hour
2 hours
3 hours
This data is also shown in graphical form on FIG. 2.
The example demonstrates that the process of the present invention not only permits lower styrene levels to be achieved, but also provides for reaching similar reductions in free styrene as those achieved with conventional steam stripping, but in significantly less time (and therefore using less steam/energy).
The tests of Example 1 were repeated. Similar results were obtained and are set out in Table 2 below.
Free Styrene (ppm)
Stripping with
Steam Only
Activated Carbon Only
Activated Carbon
1 hour
2 hours
3 hours
The test of Examples 1 and 2 was repeated and data collected for total VOCs. The results were similar and are set out in Table 3 below.
Total VOCs (ppm)
Stripping with
Steam Only
Activated Carbon Only
Activated Carbon
1 hour
2 hours
3 hours
Other embodiments and uses of the invention will be apparent to those skilled in the art from consideration of the specification and practice of the invention disclosed herein. All documents referenced herein are specifically and entirely incorporated by reference. The specification and examples should be considered exemplary only, with the true scope and spirit of the invention being indicated by the following claims. As will be easily understood by those of ordinary skill in the art, variations and modifications of each of the disclosed embodiments can be easily made within the scope of this invention as defined by the following claims.
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|Oct 19, 2005
|Apr 27, 2006
|Lg Chem, Ltd.
|Method for preparing styrene-butadiene latex
|Jan 14, 2010
|Aug 5, 2010
|Fina Technology, Inc.
|Styrenic polymer compositions and methods of making and using same
|U.S. Classification
|585/820, 585/825, 528/500, 585/826, 585/830, 585/831, 585/829, 585/827
|International Classification
|Cooperative Classification
|European Classification
|Mar 16, 2000
Owner name: BASF CORPORATION, NEW JERSEY
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:RACZ, ROBERT;REEL/FRAME:010644/0096
Effective date: 20000302
|Feb 13, 2002
Owner name: BASF AG, GERMANY
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:BASF CORPORATION;REEL/FRAME:012635/0958
Effective date: 20020207
|Jul 27, 2005
|Fee payment
Year of fee payment: 4
|Sep 28, 2009
|Maintenance fee reminder mailed
|Feb 19, 2010
|Lapse for failure to pay maintenance fees
|Apr 13, 2010
|Expired due to failure to pay maintenance fee
Effective date: 20100219


text:
Are you having Tax Law troubles? Put your worries to rest. Finding licensed attorneys in the state of Louisiana is easily found using our complete and comprehensive Louisiana Tax Law Attorneys directory. No matter what your concerns regarding Tax Law may be, you will be able to connect with attorneys in Louisiana who can help. These Tax Law Attorneys will offer sound advice and counsel allowing you to make a more informed decision and take command over any of your legal affairs. Find your attorney today.
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text:
Quasiperiodic Heisenberg antiferromagnets in two dimensions
- First Online:
- Received:
DOI: 10.1140/epjb/e2012-21003-x
- Cite this article as:
- Jagannathan, A. Eur. Phys. J. B (2012) 85: 68. doi:10.1140/epjb/e2012-21003-x
- Citations
- 126 Downloads
We describe some of the properties of 2d quantum quasiperiodic antiferromagnets as reported in studies that have been carried out in the last decade. Many results have been obtained for perfectly ordered as well as for disordered two dimensional bipartite quasiperiodic tilings. The theoretical methods used include spin wave theory, and renormalization group along with Quantum Monte Carlo simulations. These methods all show that the ground state of these unfrustrated antiferromagnets have Néel type order but with a highly complex spatial distribution of local staggered magnetization. The ground state properties, excitation energies and spatial dependence, structure factor, and local susceptibilities are presented and discussed. The effects of introducing geometrical disorder on the magnetic properties are discussed.


text:
We'll help you find the right solution for your needs
Does this sound like your topic?
Let us know when your receive great advice so we can thank our lawyers and point others with similar questions in the right direction.Got it!
One other state I got only admiration probation to pay to restitution fees. Not require meet probation or contact. also already allow me move other state. Five months later I got other probation to meet probation officer once a month and go to DV classes.
Will it effect to go back jail if other probation. Can I get beyond reasonable. To prevent not go back jail.
An attorney will need more information to intelligently answer your question. If the court and probation allow a person to be on probation in two different states, then it is allowed. I think I understand your questions even though I am not exactly sure of what you are asking. It sounds like you are on misdemeanor probation in another state. A person doesn't generally have to report to probation in a misdemeanor case. I think you recently went on probation in California for domestic violence. If you have to meet a probation officer for domestic violence, it sounds like it is a felony. However, it still can be a dv misdemeanor. Is it a misdemeanor or a felony in California? You need to talk with an attorney in the state where you are on probation, and tell him/her the circumstances. If you committed a new crime after you are on probation, you can go to jail for the case you are on probation for. If you go to jail, then violate probation on the California case, you can go to jail for a violation of probation in California for failing to comply with probation.
I don't understand what you mean by "Can I get beyond reasonable." You need to be convicted beyond a reasonable doubt by a jury (or judge). If you plead guilty, then you have given up your right to a trial. If you want to withdraw a guilty plea, you need to immediately talk to a lawyer to see if you can set aside the conviction because time will run out soon if it hasn't already. Did you plead guilty? Is your California case still active and pending? It sounds like it is closed since you are on probation.
I would talk to a lawyer immediately because it sounds like you could be facing jail time if a violation of probation is alleged. Perhaps a skilled lawyer can negotiate a no jail deal.Ask a similar question
The short answer is yes, you can have probation from two different counties or two different states.
Assuming the first state allowed you to move, if you were on supervised or formal probation, you would have needed to transfer your probation to California. If it was unsupervised (administrative), then you may not have had to transfer it as long as you were in compliance with the terms ordered.
If you pick up a new case in California (sounds like formal probation if you have to meet with a probation officer), then you have to comply with their rules.
I'm not clear on the rest of your question. If you're being violated here, depending on why you're in violation, could it affect your probation in the first state? Maybe, but it depends on the facts.Ask a similar question
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text:
2332 14th Street SE Rio Rancho, NM 87124MLS ID: 892194 - Property Type: Residential
Listing Price: $499,900
2332 14th Street SE Rio Rancho, New Mexico 87124
Contact The Venturi Team 505-933-6881, or Email 1119 Alameda Blvd NW Albuquerque, NM 87114
Listing Price$499,900
Est. Monthly Payment: $2,589.65See Details
Total Baths3
Full Baths2
1/2 or 3/4 Baths1
Heated Square Feet 2,964
Lot Acres 0.500
Year Built2007
Property TypeResidential
Property TypeResidential
Sub TypeDetached
Upcoming Open House
Request More Info
Jun 25th, 2017
Time: 1:00 pm to 4:00 pm
View custom home! 4 bedroom 2.5 bath.
Meticulously maintained one owner custom home sits in an elevated lot. Come home and unwind in the private backyard w/ unobstructed Sandia mountain view at day and city light at night. Features - Court yard entry, Travertine flooring, Custom Medallion Entry, 14' ceiling, Solid pine doors, Cherry cabinetry, Kohler Aged Pewter & Antique Nickel Fixtures, Stone Accents FP & columns , SS Appliances, Granite counters. Grand owner suit w/fireplace, sitting area, luxurious jetted tub. Office or 4th bedroom w/ french door access to front court yard. Extra deep garage great for workshop. Easy access to Presbyterian Rust Medical Ctr, Cottonwood Mall, Premier Cinema, Restaurants... Why purchase a new build house and pay $15K pave road assessment tax plus $30K to wall your back yard.
{"zipcode": "87124", "price": "499900"}
Show All Rates
Down Payment
Credit Score
Loan Amount
Loan Type
Heated Square Feet 2,964
Property Type Residential
Sub Type Detached
Stories 1
Age of Home 10 - 15
Year Built 2007
Garage Spaces 3
Garage Features Opener(s), Oversized, Workshop Area
Basement no
Sunroom no
Historical Property/Landmark no
Builder Tierrasant
Construction Frame
Exterior Material Stucco
Windows Thermal(multi-part)
Roof Pitched, Positive Pitched, Tile
Lead Base Paint no
Guest House no
Offsite Built no
List Price/SqFt 168.66
Approximate Taxes 3936.64
Tax Exemption Yes
Finance Considered Cash, Conventional, FHA, VA
Bank Owned no
HOA no
HOA Mandatory no
Public Improvement District No
Seller Assist Offered no
Trade or Exchange Considered No
Bedrooms 4
Total Baths 3
Full Baths 2
1/2 Bath 1
MBR on Main yes
Master Bath Description Full Bath
Fireplace yes
Number of Fireplaces 2
Fireplace Type Custom, Gas Log, Glass Door
Flooring Carpet, Travertine
Appliances Blt In Gas Stve/Oven, Dishwasher, Disposal, Microwave, Range Hood, Water Softr. Owned
Interior Features Alarm System, Ceiling Fan(s), Great Room, LR/DR Combo, MB Dbl Sink, MB His/Her, MB Jetted Tub, Pantry, Separate Shower, Study/Office, Walk-In Closet(s)
Disability Access No
Loft no
Heating Central Forced Air, Energy Star (G)
Cooling Energy Star (G), Refrigerated
Water/Sewer Septic Tank, Shared Well
Green Certified yes
Green Certification Type LEED-H Silver
HERS Tested no
Lot Acres 0.500
Lot SqFt 21780
Pool no
General Access Paved Road
Landscape Bubble Drip (G), Front and Back, Xeriscape
Exterior Features Patio Covered, Walled Backyard
Lot Description View
Lot Description Views
Guard House/Service no
Elementary School Maggie Cordova
Middle School Lincoln
High School Rio Rancho
Subdivision Name Rio Rancho Estate
Street Address 2332 14th Street SE
City Rio Rancho
State New Mexico
Zip Code 87124
County Sandoval
Zoning R-1
Zone Atlas 35
Faces West
MLS Area 140 - Rio Rancho South
Main Living Area Level M
Main Living Area Length 22
Main Living Area Width 21
Kitchen Room Level M
Kitchen Length 15
Kitchen Width 15
Dining Room Level M
Dining Room Length 14
Dining Room Width 15
Office Room Level M
Office Length 14
Office Width 15
Master Bedroom Level M
Master Bedroom Length 24
Master Bedroom Width 18
Bedroom 2 Room Level M
Bedroom 2 Length 13
Bedroom 2 Width 12
Bedroom 3 Room Level M
Bedroom 3 Length 14
Bedroom 3 Width 13
Laundry Location Service Room
Laundry Power Gas & Electric
Sunroom Finished no
Sunroom Heated no
Basement SqFt Included no
Basement Heated no
Guest House SqFt Included no
Guest House Finished no
Guest House Heated no
Listing courtesy of Berkshire Hathaway Home Services New Mexico Properties.
Some of the information contained herein has been provided by SWMLS, Inc. This information is from sources deemed reliable but not guaranteed by SWMLS, Inc. The information is for consumers personal, non-commerical use and may not be used for any purpose other than identifying properties which consumers may be interested in purchasing.
Schedule a Showing - MLS ID 892194
Please enter your preferences in the form. We will contact you in order to schedule an appointment to view this property. For more immediate assistance, please call Venturi Realty Group - Keller Williams Realty at 505-933-6881.
Data services provided by IDX Broker


text:
Bahamian Embassy in Port-au-Prince, Haiti
- Address12 Rue Boyer, Petion-Ville, Port-au-Prince, Haiti
- Email[email protected],[email protected]
- Fax(+509) 2256-5729
- Phone(+509) 2256-4407
This map displays the location of Bahamian Embassy in Haiti
Submit Edits for "Bahamian Embassy in Port-au-Prince, Haiti"
About Bahamian Embassy in Port-au-Prince, Haiti
Bahamian Embassy in Haiti runs an inclusive range of consular services to local, Bahamian, and international citizens in Haiti.The Bahamian Embassy in Haiti supports Haitian citizens through its consular services, if they:
- Need general or specific info regarding Bahamian economy, culture, sports, education and more
- Need information regarding requirements and process of getting Bahamian Citizenship
- Specific contacts and information in Bahamas
- Want to apply and obtain Bahamian Visa
Bahamian Embassy in Haiti supports, Bahamian Citizens when in Haiti through its consular services, if they:
- Are in front of an emergency and need information, contacts or other support
- Face difficulties going back to Bahamas
- Need information on Local Medical system of Haiti
- Need info about local resources in Haiti
- Need new Bahamian Passport or Identity Card (if lost, stolen or damaged)
- Want to vote in Bahamian Elections
Visa and Passport services of Bahamian Embassy in Port-au-Prince, Haiti
Bahamian passport and visa from Bahamian Embassy in Haiti are issued only to citizens whose main residence is in Bahamas and Haiti.
The process of issuing Bahamian Visa and Passport of Bahamas can take few weeks.*Please contact with Bahamian Embassy in Haiti if you have any question as regards of visa and passport matters.
Bahamian representations in Haiti
Bahamian Embassy in Haiti is the only Bahamian diplomatic mission in Haiti.
Haitian representations in Bahamas
- Haitian Embassy in Nassau is the only Haitian representation in Bahamas
Bahamian representations worldwide
Bahamian Embassy In Haiti represents one of 34 consular and diplomatic representations of Bahamas all over the world.
Foreign representations in Haiti
Bahamian Embassy In Haiti represents one of 33 foreign consular and diplomatic representations from around the world in Haiti.


text:
Fashion is an everlasting topic since the day we began to pay attention to how we dressed. If you are looking for fashion, this is the right place to come. You can find the right ladies summer cotton dresses here from Fashionmia's latest and hottest collection of ladies summer cotton dresses. We provide customers fashion items like ladies summer cotton dresses with totally affordable price and high quality. Come discover the ladies summer cotton dresses you need from our suggestion and guide to save time in choosing the most suitable ladies summer cotton dresses. Have fun shopping online at Fashionmia.
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Oversized V-Neck Plain Maxi Dress
Floral Printed Hollow Out Round Neck Maxi Dress
Spaghetti Strap Side Slit Plain Midi Bodycon Dress
V-Neck Solid Bodycon Dress In Red
Simple Round Neck Plain Sleeveless Bodycon Dress
Loose Round Neck Pocket Color Block Maxi Dress
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Houndstooth Round Neck Slit Bodycon Dress
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Split Neck Pocket Leaf Printed Midi Skater Dress
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Charming Floral Printed Round Neck Skater Dress
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Printed Round Neck Asymmetric Hem Maxi Dress
Allover Floral Printed Round Neck Belt Skater Dress
Round Neck High-Low Pocket Shift Dress
Round Neck Color Block Printed Shift Dress
Colorful Striped Round Neck Shift Dress
Round Neck Graffiti Short Sleeve Shift Dress
V-Neck Elastic Waist Floral Maxi Dress
Round Neck Bowknot Pocket Plain Skater Dress
Round Neck Plain Drawstring Pocket Bodycon Dress
Round Neck Pocket Gradient Printed Shift Dress
Casual Round Neck Lotus Printed Pocket Shift Dress
Short Sleeve Round Neck Pocket Printed Skater Dress
Oversized Round Neck Draped Pocket Printed Shift Dress
Embroidery Plain Round Neck Pocket Midi Shift Dress
© 2017 FashionMia, Inc.


text:
TFS 2011, HTML5 Gaming
Wednesday, January 18, 2012 from 5:30 PM to 8:30 PM (EST)
Event Details
|January 18
|TFS 2011, HTML5 Gaming
Malvern, PA
|Our monthly meeting will be held at the Microsoft Greater PA Office in Malvern, PA on Wednesday, January 18 from 5:30-8:30. Refreshments are provided courtesy of philly.NET.
We have some great meetings lined up for the next few months. Please take a look at the upcoming schedule on the web site and follow other local user groups on our community calendar.
|Brian Minisi, CEI America What's New in Team Foundation Server 11
Team Foundation Server (TFS) is an enterprise tool for managing your application lifecycle from requirements through code design, implementation, testing and deployment. The ability to trace requirements, tasks, defects, and test cases to checked-in code improves tracking to more quickly and reliably deliver projects. The next version of TFS improves upon the experience of creating a product backlog, planning iterations, and tracking the progress of a Sprint. This session will walk through a lifecycle using the Agile methodology to demonstrate many of the features available in the next version of Visual Studio and TFS. This includes the new Team Explorer, Capacity Planning, Boards, Storyboards, Source Control, and an overview of testing using the Microsoft Test Manager tool.
Brian Minisi has been developing software for 15 years. Brian moved into .NET as part of the early adopters program and has delivered a wide variety of web sites and applications since. Other areas of concentration include Business Intelligence, SQL Server, and ALM solutions using Team Foundation Server. Brian is a Software Architect for CEI America (www.ceiamerica.com), a Microsoft Gold Partner. As a current Microsoft ALM Ranger, Brian participates in delivering out-of-band solutions for Visual Studio and Team Foundation Server.
|6:30 Break
|Meet your peers. Refreshments and drinks courtesy of philly.NET.
|Rob Keiser, philly.NET co-leader, ask questions, get answers from your peers!
|6:45 Quick Tip
|Rich Ross Using LINQ in SharePoint
Rich will show how to use LINQ (linq to objects) to do a group join on 2 SharePoint lists that have a common field, but that field is not a lookup to other list. Although the tip was based on a need in SharePoint, it is valuable to all .net developers since it uses LINQ.
|Dave Isbitski, Microsoft Adventures in HTML5 Gaming
This session will provide you with an overview of SVG and the new HTML5 Canvas. We will cover the history of each, their advantages and what you should pick for your own game. We will then cover the fundamentals of games programs such as the game loop as well as exposure to some frameworks. Particular focus will be spent on the open source Canvas/JS framework EaselJS. Plenty of demos and code will be provided.
Dave Isbitski is a Sr. Developer Evangelist with Microsoft covering Windows, Windows Phone and Xbox. He enjoys talking about technology and has taught full-day courses on numerous Microsoft topics as well as being a presenter at VSLive!,ReMix, XAMLFest, CodeCamps and other community events. Dave can be found on Twitter at @TheDaveDev and his blog http://blogs.msdn.com/davedev.
|8:30 Closing & Raffle!
|Books, software, and other goodies!
When & Where
45 Liberty Boulevard
Great Valley Corporate Center, Suite 210
Wednesday, January 18, 2012 from 5:30 PM to 8:30 PM (EST)
Add to my calendar


text:
To try the thousands of add-ons available here, download Mozilla Firefox, a fast, free way to surf the Web!Close
Welcome to Firefox Add-ons.
Choose from thousands of extra features and styles to make Firefox your own.Close
Review for Tinseltown by JeRrYFaR
Rated 5 out of 5 stars
Agreed.. Awesome.This review is for a previous version of the add-on (2.101208).
To create your own collections, you must have a Mozilla Add-ons account.


text:
Napping Baby Gift Bundle-Didn't find tutorial but some of my creative friends and family should be able to take it from here!
Funny Spatula Father's Day Gift Idea "Dad I flippin' love you!" #grilling | http://www.sassydealz.com/2014/05/funny-spatula-fathers-day-gift-idea.html
Cheap gift ideas for kids by lydia
Rudder bracelet, braided infinity bracelet, antique compass bracelet, bijuteria, gift ideas for boyfriend, birthday gifts for boyfriend by TheOneUnique, $4.59
In A Pickle bag. Super cute bag filled with EVERYTHING you could ever need when in a jam. So giving these as Christmas gifts!
Money Gift Idea - fun gift idea for graduation, birthday or anytime!
gold tip fox paper clip holder
Trinket Tray
adorable cell phone stand: great for your desk! =) #ModCloth
Oma koti onnenpesä: Good Morning


text:
- 30 Day Returns
- Free Shipping
- Huge Selection
- Low Prices
- Stylish Designs
- Amazon Pay
- Description
- Reviews
Enjoy some summer food fun with the Happyday Hooded Dog Shirt by Puppia in Red!
- Watermelon character printed on the back
- Striped pattern and solid schemed
- Comes ready with a leash hole
- Cotton/poly blend
- PUPPIA SMART TAG pendant(QR Code only) is included
The Happyday Hooded Dog Shirt by Puppia is a slice of juicy delight! A cute watermelon slice applique on back with happyday on striped shirt. Leash hole that makes it easy to wear on walks. Shirt is made of 65% cotton, 35% polyester. PUPPIA SMART TAG pendant(QR Code only) is included to keep your pet in the social stream and safe. Great for the picnics and pictures!
Important Sizing Note: The following measurements are the dimensions of the actual product, not of the pet they fit. After measuring your pet, make sure all measurements fit within the following dimensions (with a little room to spare in the chest and neck).
- Back Length: 8"
- Chest: 13" (Most Important)
- Neck: 9"
- Back Length: 9.5"
- Chest: 15" (Most Important)
- Neck: 11"
- Back Length: 12"
- Chest: 15" (Most Important)
- Neck: 12"


text:
If an item you ordered from TextbookRush does not meet your expectations due to an error on our part, simply fill out a return request and then return it by mail within 30 days of ordering it for a full refund of item cost.
Learn more about our returns policy
Description: The primary goal of theGO!Series, aside from teaching computer applications, is ease of implementation, with an approach that is based on clearly-defined projects for students and a one of a kind supplements package.GO!rsquo;s project-based approach clusters the learning objectives around the projects rather than around software features. Teaches students to solve real problems as they practice and learn the features.GO! with Microsoft Word 2007, Brief, 1/econtains a CD-ROM.This edition covers the following topics:formatting and organizing text; using graphics and tables; applying special document formats, columns and mail merges; working with templates, styles, and charts; creating form letters and working in groups.Ideal for students and individuals seeking an introduction to Microsoft Word 2007.
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List price: $55.40Copyright year: 2008Publisher: Prentice Hall PTRPublication date: 5/8/2007Binding: Mixed MediaPages: 384Size: 8.50" wide x 10.50" long x 0.75" tall Weight: 1.738Language: English
Shelley Gaskin, Series Editor for the GO! Series, is a professor of business and computer technology at Pasadena City College in Pasadena, California. She holds a master's degree in business education from Northern Illinois University and a doctorate in adult and community education from Ball State University. Dr. Gaskin has 15 years of experience in the computer industry with several Fortune 500 companies and has developed and written training materials for custom systems applications in both the public and private sector. She is also the author of books on Microsoft Outlook and word processing.
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text:
The Polish Scouting and Guiding Association has received an official letter from the Polish Ministry of Foreign Affairs in ensuring cooperation at visa convenience for scouts attending the World Scout Jamboree in 2023.
"The Polish Ministry of Foreign Affairs wishes to express its full support for the candidacy of Poland as a country hosting the World Jamboree in 2023. We would like to assure you of our hospitality in the area of visa policy, yet warmly invite Scouts from around the world to Poland. "- Wrote the Undersecretary of Polish State of the Ministry of Foreign Affairs, Mr Artur Nowak-Far to the scouts.
The letter declares that the Schengen visa procedures will be applied in such a way as to facilitate the submission of visa applications and waiver of fees representatives of the organizations and participants Scout Jamboree under 25 years of age and emphasizes that the Ministry will make reasonable efforts to cooperate in this regard with the remaining countries of the Schengen Group.


text:
coffeebrk Review
Cute summer case
This case is a good value for the price. It is a fun case for the summer.
- How did the image on site compare with the actual product? It is how it looks on the site
- Was the product free of any manufacturer defects? Yes
- Please tell us about the quality of the product. Good
Was This Review Helpful?


text:
YP - The Real Yellow PagesSM - helps you find the right local businesses to meet your specific needs. Search results are sorted by a combination of factors to give you a set of choices in response to your search criteria. These factors are similar to those you might use to determine which business to select from a local Yellow Pages directory, including proximity to where you are searching, expertise in the specific services or products you need, and comprehensive business information to help evaluate a business's suitability for you. "Preferred" listings, or those with featured website buttons, indicate YP advertisers who directly provide information about their businesses to help consumers make more informed buying decisions. YP advertisers receive higher placement in the default ordering of search results and may appear in sponsored listings on the top, side, or bottom of the search results page.
Probation Office in Miami, FL
1.US Probation & Parole Office
1 NW 62nd St
3.56 mi
Probation Services
2.Corrections-Probation & Parole
7900 NW 27th Ave
4.22 mi
Probation ServicesState GovernmentGovernment OfficesCorrectional Facilities
3.Florida Department-Corrections
7900 NW 27th Ave
4.22 mi
Probation ServicesState GovernmentCorrectional Facilities
4.Probation & Parole Department
7900 NE 2nd Ave
4.56 mi
Probation Services
5.Corrections-Probation & Parole
12295 SW 133rd Ct
14.81 mi
Probation ServicesState GovernmentGovernment OfficesCorrectional Facilities
6.Probation & Parole Office
7900 NW 27th Ave
4.22 mi
State GovernmentProbation ServicesGovernment Offices
This Place is a Joke. The Employees are not only unprofessional but unqualified to monitor criminals. They are the criminals! They let people get away with drug test and they have more sympathy for the criminals than they do the victims. Criminals have a whole support system in there and the victims are left to figure it out. Next time I will leave names but I can honestly say the whole staff should be reviewed for their terrible service. I hope that no one ever has to depend on this probation place because you will never get justice or feel any close to it.
7.Corrections-Probation & Parole
401 NW 2nd Ave Ste S607
1.96 mi
State GovernmentGovernment OfficesProbation Services
8.US Probation & Parole Office
400 N Miami Ave
2.14 mi
Federal GovernmentProbation Services
9.Probation & Parole Circuit Ofc
4343 W Flagler St
Coral Gables,FL
2.77 mi
Probation Services
10.Parole Commission
3601 NW 167th St
Miami Gardens,FL
9.74 mi
State GovernmentProbation ServicesGovernment OfficesSocial Service Organizations
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text:
MARS Windows 2003 reporting
Customer set up SNARE to push the
event logs to mars
I defined the device and checked the receive box. I assume I don't have to put username password as I am receiving. Anyway, to prove it was working I thought I could query on raw events like you can from say a cisco switch. Am I on the right track? Right now I see nothing.
thx again


text:
With Instructables you can share what you make with the world, and tap into an ever-growing community of creative experts.
Tell us about yourself!
Welding Class
Mold Making & Casting Class
Metalworking Class
Simple One Part Mold
Flexible Block Molds
Introduction to Mold Making & Casting
Homemade Bar Clamps
Wine Rack Tower
Encase Your Friends in Carbonite
Liquor Bottle LED Light
2-in-1 Marking Gauge & Beam Compass
DIY Han Solo in Carbonite With Me
Timber Workbench
Elephant Clock
Orrery- A Mechanical Solar System Model from Plywood
Scrap Table
STEAMPUNK R2D2 Starwars Astromech
Creating Costume Armor with Wonderflex
Creating Helmets and Armor from Videogames for Fun and Profit!
Building a Small Format Vacuumformer from an Old Toaster Oven
Mold Making: Two Part Silicone Mold
Making a 28 inch wide Sander/Planer
Complete Helmet Stereo (Headphones and MP3 Player)
Glow table
Dovetailed Wooden Glasses
Wood Burning (Pyrography) Cutting Boards and Spoons as Christmas gifts
Build this Woodworker's Workbench to learn Mortise & Tenon Joinery
Making A Circle Cutting Jig
How to build an Electric Guitar.
Build a Woodworker's Toolbox
Workbench and companion worktable
Making custom latex halloween masks on a budget
The Moon Machine
Plasma Bulb with Clock Gear
Building a Cedar Strip Kayak
Designing and Building Beautiful RC Airplane
Vintage Beat Box Suitcase
The Drill Bit Rack
Circle Cutting Jig For Table Saw
REVOLVE // A hardware-less coffee table
Concrete Countertop With Integrated Sink and Fiber Optics
Wooden Architect Lamp
The DIYLILCNC: Open-Source Plans For a Low-Cost, Easy-to-Build CNC Mill. (v1.0.2)
Vader Gas Bottle Log Burner
Making a Confetti Blank
Bookcase with Hidden Drawer
Simple Styrofoam Hot Wire Cutter
English Best Bitter - All grain brewing for beginners.
Rotomold your own Speakers
The Wordclock Grew Up!
USB Powered LED Articulating Lamp
Laser Cut Analog Clock
A Precise Table Saw from an Electric Hand Saw
Wooden Puzzle Lock For Secret Door
Secret door bookcase
Southwestern egg rolls with avacado dipping sauce (Copycat of Chili's)
Create faceted papercraft-objects
Bench Tool Stands
How to Build Your Own BBQ Barrel
How to build your own Jet Engine
Geared Candleholder
Sliding Puzzle Secret Compartment Table
Leather Briefcase (Covert Edition)
Combination Circular/Table Saw
The Smallest Workshop in the World
Creating your First Multi-touch Table
Travel Bar
High Voltage Ignited Plasma Bulb
Steampunked plasma-beam generator
Steampunk Reverse Peltier Machine (aka The electro-mechanical room freshener)
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Yemi Adewuyi
Yemi is a North Carolina transplant, having previously lived in Texas and New York. In May of 2016, he received a bachelor's degree in Public Policy Studies from Duke University, where he was an Angier B. Duke Scholar. Yemi is deeply interested in social justice and aspires to a career at the intersection of research, community advocacy, and litigation. His past experiences include traveling to South Africa and various parts of the American South to research comparative racial politics and interning with JusticeMatters, a legal clinic in Durham specializing in humanitarian immigration law.
At the Foundation, Yemi works to support ongoing projects and amplify our grantees' voice in public spaces, largely through creating digital content and producing our bi-weekly podcast series. In his free time, he enjoys making music, finding new books to read, and trying out new restaurants in Durham.


text:
Highlights from LSM students
- March
The oldest known parasitic isopod identified by LSM student Christina Nagler.
LMU biologists Christina Nagler and Joachim Haug have identified two 168-million-year-old fossils as the oldest known parasitic representatives of the crustacean group Isopoda, allowing for reconstruction of the evolution of parasitism within Cymothoida in detail. The findings have just appeared in the online journal BMC Evolutionary Biology. The study sheds new light on the evolutionary history of isopods.
Congratulations, Christina!
Micro-computed tomography of the fossil isopod Urda rostrata. Source: C. Nagler, LMU


text:
OData v3: Overview
Download this episode
Pablo Castro a Principal Architect on the OData team at Microsoft, provides an overview of OData version 3.0. This talk was delivered at the March 2012 OData Meetup Event.
For more information about upcoming events or other items related to OData, please visit http://odata.org
Available formats for this video:
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More episodes in this series
OData v3: Actions and Functions
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Azure data and analytics platform
Azure Search. Best practices for web and mobile applications
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OData Meetup 2012: JSON Light Detail
The Discussion
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As part of the NEISD Arts Integration Initiative, Early Childhood, Family Engagement, and Fine Arts departments have collaborated with "Wolf Trap Institute for Early Learning Through the Arts" to provide NEISD prekindergarten students, families, and teachers with an educational arts based experience.
This week, Jeanne Wall, Wolftrap Artist from Virginia, is sharing her "Going Buggy" workshop at nine campuses throughout the District. Jeanne uses imaginative props, storytelling, puppetry, and music to bring to life these educational tales about insects from Africa, Mexico and Native America. Using an interactive style, Jeanne draws her audience into the stories, creating lots of family fun.
Nine campuses are hosting these "buggy" workshops: Montgomery, Royal Ridge, Roan Forest, East Terrell Hills, Wilshire, Walzem, El Dorado, Northern Hills, and Fox Run elementary schools.
Posted on 04/06/2017


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September 17, 2012
Catherine, bioshock, portal, final fantasy 7, toe jam and earl
I am more about the art of of the game. Designing the look of a game can really set your demographics.
My major goal is to continue in the industry and create games that can being people together and inspire the next generation of game designers.
No answer yet
Hey everyone my name is Michelle and I am a computer animator and illustrator. I am really interested in getting to know some of the people in the area that have the passion for game design that I do and I figure this is the way to mett them!
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Pimco appoints four more deputy CIOs after El-Erian quits
By Jennifer Ablan
NEW YORK (Reuters) - Pimco, the world's largest bond fund manager, said on Wednesday the firm had appointed four additional deputy chief investment officers ahead of CEO Mohamed El-Erian's departure.
Mark Kiesel, Virginie Maisonneuve, Scott Mather and Mihir Worah, currently managing directors at Pacific Investment Management Co., will join Dan Ivascyn and Andrew Balls as deputy chief investment officers.
"Our six deputy CIOs demonstrate the strength, depth and breadth of investment talent at Pimco," Bill Gross, co-founder of Pimco, said in a statement. "Individually and as a team they have delivered for clients consistently, and they will now help lead Pimco's investing excellence into the future."
El-Erian, who had been widely seen as the heir apparent to Gross, will leave the firm in mid-March. Gross, who shared the title of co-chief investment officer, will become the sole CIO. El-Erian will remain a consultant at Allianz (ALVG.DE: Quote), the German insurer that owns Pimco.
Even though Allianz quickly appointed Douglas Hodge as chief executive officer last week plus six new deputy CIOs to replace El-Erian, analysts and investors agree that none are real contenders for Gross' job right now.
"I think that it is very clearly an effort on Bill Gross and Pimco's part to reassure clients, in particular, that not only have they worked on succession planning in the past but that there are real people identified in that process to take over if necessary," said Morningstar senior research analyst Eric Jacobson.
He added: "I just don't see any single heir apparent at this point. I do think it remains an open question whether any of these folks are in a position to truly challenge Bill Gross's investment ideas and macro thinking."
The management restructuring comes at a time when many investors are turning their backs on the kind of bond investments Pimco is famous for offering. Continued...


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i like bords and bikes. This is a place to talk about bikes and bords.if you have any coments.
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38 Courtenay Place - Level 3 (part)
Level, 3, 38 Courtenay Place, Wellington Central, Wellington
Price On Application
- Proposed Usage
- Office
- Floor Area
- 137.00 m²
- Property ID
- 1b9d7nx
Enquire about this property
Located on the corner of Courtenay Place and Allen Street, there is 137sqm of character office space available. The Landlord is currently strengthening the building to 75% NBS. This space is a blank canvas, awaiting your fitout.
Please call to arrange a time to inspect - Sam McIlroy 021 730 100


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*Your results may vary. Any specific claims or permanence length of results vary for each patient and are not guaranteed.


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Baron Steven Bentinck is also seeking to sequester the assets of Associated Newspapers, the publishers of the Daily Mail. He brought contempt proceedings against them over an item which appeared in the newspaper in August which, he claimed, meant he was extremely mean towards his wife Nora (above) at the end of their nine-year marriage. His counsel denied this, saying the baron had made substantial provision for his former wife.
Andrew Caldecott QC, for the newspaper, argued that no breach of its undertaking had occurred. The judge said he would give his ruling on Monday.Reuse content


text: Are you a good communicator, friendly, and energetic? We are looking for additional Kids Ministry Office servants during our Sunday morning services and Wednesday evening service. It is the desire of the Kids Ministry Office to welcome and assist our church family and visitors through event sign ups, responding to phone calls, and directing people around campus. Stop by the Kids Ministry Office for more information and to sign up today!


text:
T-Mobile Says It Will Start Using 600 MHz Spectrum This Year
Article Comments 7
Apr 13, 2017, 1:19 PM by Eric M. Zeman @phonescooper
updated Apr 13, 2017, 1:26 PM
Updated: added detail regarding average depth of spectrum winnings
"T-Mobile now has the largest swath of unused low-band spectrum in the country," said T-Mobile CEO John Legere about the company's 600 MHz auction winnings. The company successfully won an average of 31 MHz (ranging between 20 MHz and 50 MHz) of the 70 MHz low-band spectrum auctioned off by TV stations and the FCC. The winnings give T-Mobile 100% coverage of the U.S. and Puerto Rico. "That is a [big freaking deal] for our customers. This spectrum sets us up to bring the Un-carrier — and real competition — to wireless customers everywhere," noted Legere. Further, T-Mobile claims it will put some of the new spectrum (at least 10 MHz) to use later this year. T-Mobile began preparing for the 600 MHz spectrum in 2016, and it already has compatible equipment from Ericsson and Nokia on deck. T-Mobile expects devices with select chipsets from Qualcomm will support the 600 MHz spectrum before the end of 2017. "Our team has a history of deploying network technologies at record-breaking pace — including the fastest recorded LTE deployment in US history," remarked T-Mobile CTO Neville Ray. "We're ready to break records again on 600 MHz." T-Mobile didn't specify which markets might first see access to 600 MHz services, nor did it say what handsets might support the new wireless broadband spectrum.
T-Mobile to Light Up 600 MHz LTE This Summer
T-Mobile today said it plans to begin testing its newly acquired 600 MHz spectrum as soon as this summer. The FCC granted licenses for the spectrum this week following the years-long incentive auction process.
T-Mobile to Deploy 5G On 600 MHz Spectrum Starting in 2019
T-Mobile today said it plans to use some of its recently acquired 600 MHz spectrum to support a future 5G network. The company successfully won an average of 31 MHz (ranging between 20 MHz and 50 MHz) of the 70 MHz low-band spectrum auctioned off by TV stations and the FCC earlier this year.
T-Mobile, US Cellular Named FCC Incentive Auction Winners
The FCC today marked the official end of the incentive auction for 600 MHz airwaves. The agency said 50 wireless companies bid a cumulative $19.8 billion on some 70 MHz of spectrum that was put on offer by 175 television stations.
FCC Sets 126 MHz Clearing Target for Reverse Auction
The FCC today announced it has set an initial spectrum clearing target of 126 MHz during the reverse part of the auction for 600 MHz airwaves. Television broadcasters have agreed to part with this spectrum.
FCC Reverse Auction Drops Clearing Price to $54.6B
The FCC has wrapped up the initial phase of stage two of its incentive auction for 600 MHz airwaves, and drastically lowered the price for that spectrum. The initial clearing cost for all the 600 MHz spectrum was $86.4 billion, but bidders failed to come even close during the first round of bidding.
Penetration is the key!
And once
Which makes me wonder, they just got a big chunk of their network upgraded for 700 mhz support. I wonder how much equipment they will have to recycle when they install the ...
Will Start Using
I dropped them because their service was really bad where I worked.
They have no plans of upgrading the area even though many requests from many people and even in the surrounding residential areas have been made.
Only on the major highway that is a few miles away have they decided to keep the service decent.


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Sat 16th Mar at 8:45pm (doors 7:30pm)
Monkey Business Comedy Club
@ Sir Richard Steele, London
Featuring: Hal Cruttenden, Bobby Maire, Jen Brister, Lucy Beaumont, Martin Besserman
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Monkey Business Comedy Club: Hal Cruttenden, Bobby Maire, Jen Brister, Lucy Beaumont, Martin Besserman
Please visit www.monkeybusinesscomedyclub.co.uk for further information and tickets
Please note that the artists appearing may be subject to change.
Hal Cruttenden
Hal Cruttenden is one of the top comedians working in the UK today, as well as being a highly accomplished writer and actor.
Over the last year he's performed on 'The John Bishop Show' (BBC1), 'Live at the Apollo'(BBC1 and 2), 'The Melbourne Comedy Festival Gala' on Channel 10 Australia as well as 'Have I Got News For You' (BBC1) and frequently being seen on 'Great British Bake Off – Extra Slice' (BBC2).
'An absolute joy to watch' (The Scotsman)
'Hugely talented' (The Times).
Hal Cruttenden was named in Ents24's top 20 hardest-working comedians of 2015.
Hal Cruttenden tour dates
Jen Brister
Jen Brister is a stand up comic, writer and comedy actor.
'Brister ticks all the boxes – she's confident, energetic and knows how to deliver a line for maximum laughs' (The Scotsman)
'Outrageously funny' (Metro)
'Gorgeously talented' (Tim Arthur, Time Out)
'This is as near perfect stand up as I have seen' (Scotsgay).
Jen Brister tour dates
Lucy Beaumont
Lucy is a hugely talented comedy actress and writer. She was nominated in 2014 for Best Newcomer at the Fosters Comedy Awards for her debut show We Can work
It Out. In 2012 she was the winner of The BBC New Comedy Award and won the Chortle Award For Best Newcomer. Lucy was a finalist in the Leicester Mercury Comedian Of The Year 2013 and in August 2011 she was also ranked joint third in the Gilded Balloon's nationwide stand-up comedy competition So You Think You're Funny?.
'She has that intangible something that gives her an innately charismatic stage
presence. She's slight and vulnerable, a bit ditzy, and utterly charming... A star is born' (Chortle)
'Perfect for the times' (The Guardian)
'She's got the timing of Les Dawson... an absolute natural' (Johnny Vegas)
'Devastating comic timing' (The Stage)
'The next Victoria Wood in the making' (Arthur Smith)
'The stage Beaumont is a riot!' (The Scotsman).
Lucy Beaumont tour dates
Martin Besserman
Stand up comedian and regular compere at Monkey Business Comedy Club in Camden.
Martin Besserman tour dates
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Venue Facts
Venue: Sir Richard Steele
97 Haverstock Hill
Chalk Farm
Website: sirrichardsteele.com
→ Hampstead Heath 9 min walk
→ Belsize Park 4 min walk


text:
You can use the TAB key in the Editbox (and in various popup dialogs like $? $input to complete various words)
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nick TAB - Completes channel nicks, query nick or your own nick.
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# TAB - Completes and cycles all joined channel names (and any channels in your Serverlist for the current server), if current window is a channel, the channel name is completed first.
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<@|%|+>nick TAB - Completes channel nicks matching the channel prefix and/or nick. (Based on channel prefix received by the server, e.g @+)