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Photo by: Jonathan Lovekin
BalilahPrint Recipe
200g dried chickpeas
1 tsp bicarbonate of soda
60g chopped flat-leaf parsley
2 spring onions, thinly sliced
1 large lemon
3 tbsp olive oil
2 1/2 tsp ground cumin
salt and freshly ground
black pepper
Balilah can be eaten warm, not hot, or at room temperature as a little between-meal snack. It is also delicious served next to grilled chicken or fish, or can be turned into a salad by adding some leaves, feta and diced tomatoes.
Serves 4
(p 102, Jerusalem)
The method for this recipe is available in the book Jerusalem, available to buy here.
Jerusalem |
Jerusalem | Text © Yotam Ottolenghi and Sami Tamimi | Photography © Jonathan Lovekin


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IFAW is disrupting poaching networks in partnerships with INTERPOL, and others across the globe.
IFAW's political advocacy work
- The PROTECT campaign
- How can I work in my community to help animals?
- How is IFAW working to help animals through the CITES treaty?
- What are IFAW efforts for animal welfare at CMS?
- What is the International Whaling Commission (IWC)?
- What is the Universal Declaration on Animal Welfare (UDAW)?
- How can I learn more about ecological sustainability?
Political advocacy news
Saturday in Washington, DC was drizzling and overcast, but the energy and enthusiasm of the crowd at the March for Science Read more »
Best known for their beautiful long necks and distinctive coat patterns, giraffe (Giraffa camelopardalis) are fascinating Read more »
Today, over a third of the licensed ivory trading outlets in China, including a dozen ivory carving factories, will no Read more »
Best known for their beautiful long necks and distinctive coat patterns, giraffe (Giraffa camelopardalis) are fascinating Watch Video »
This World Wildlife Day, which this year has the theme of #ListentoYoungVoices, I want to encourage everyone to # Watch Video »
Update: On the final day of the Conference, Parties ratified a commitment to stamp out illegal online wildlife trade by Watch Video »
Namibia, South Africa and Botswana urged Convention on International Trade in Endangered Species of Wild Fauna and Flora ( Watch Video »
A specialized training of enforcement authorities in the prevention of wildlife trafficking is being carried out from April 24th to 28th by the High Commissioner for Waters and Forests and the Fight against Desertification of Morocco and the Internat Read more »
Wildlife Groups Seek to Save Species from Silent Extinction In response to recent scientific consensus on giraffes' vulnerability to extinction, five wildlife protection groups today petitioned the U.S. Fish and Wildlife Service to protect Eart Read more »
Japan's so-called 'scientific' whaling program has received further criticism from international experts who found Japan does not need to kill whales for scientific research. In a report published today, the Expert Panel appointed b Read more »
Animal Welfare Coalition Applauds Reintroduction of "Big Cat Public Safety Act" to Prohibit Private Ownership of Dangerous Big Cats
Big Cat Rescue, Born Free USA, the International Fund for Animal Welfare, The Humane Society of the United States and the Humane Society Legislative Fund applaud U.S. Representatives Jeff Denham (R-CA), Walter Jones (R-NC), and Niki Tsongas (D-MA) fo Read more »
By week's end, China will shut down more than 60 ivory carving factories and retailers making good on their promise to end domestic commercial ivory markets in 2017. The International Fund for Animal Welfare (IFAW) offered the following stateme Read more »
The International Fund for Animal Welfare (IFAW) is disappointed that Fisheries and Oceans Canada (DFO) will be opening the commercial seal hunt early this year, allowing sealers to hunt while harp seal pups are still nursing. Traditionally, the annu Read more »
The International Fund for Animal Welfare joins 120 organizations from across civil society, including conservationists, fait Read more »
The Convention on International Trade in Endangered Species of Wild Fauna and Flora (CITES) sponsors a Conference of the Part Read more »
The Convention on International Trade in Endangered Species of Wild Fauna and Flora (CITES) sponsors a Conference of the Part Read more »
The result of a comprehensive analysis of the Convention on International Trade of Endangered Species of Wild Fauna and Flora Read more »
Today IFAW released its newest report, Bidding Against Survival: The Elephant Poaching Crisis and the Role of Auctions in Read more »
It is early August 2014, and so far this year not a single week has passed without law enforcers seizing a consignment of Read more »
Earlier this summer, the New York State legislature reached an agreement to ban the sale and purchase of most elephant and Read more »
New York State is on the verge of enacting a law that will prohibit direct contact between people and big cats—a Read more »

subset: commoncrawl


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Good motherboard for the i5 3570k around 130$ gaming
plan on overclocking the i5 3570k
something not from ASrock
something not from ASrock
6 answers Last reply Best Answer
More about good motherboard 3570k 130 gaming
i got myself the MSI Z77a-G45 for 100$ with a 20$ Mail-in (so 120$ at buy time)
Dark Brown PCB (like all MSI line) Oc really well (wasn't expecting 105 baseclock and 4.83ghz for a cheap board like that but it run for 1 year now withtout any bugs) Blue accentued cooler that looks awesome, SLI, Crossfire and RAID like most 150-160$ board (not like the g43 or g41 that aren't SLI compatible but cheaper)
well that's it !! for a 100$ board, i can't find a better value !!
PS: Gigabyte make fantastic board too, i'm still running a P45 Gigabyte board with a Core 2 quad Q6600 OC to 4.05ghz (450*9) with 1200Mhz ram, running flawlessly from 2007-2008 to now !! That's the best motherboard i had as i pass two ASUS Rampage Formula on the same Q6600 (both failed on me killing the gpu both time and they send me a new one but not pay for the GPU so i simply resell the 3rd board as i don't want to toast another GPU in there...)
I also had a P4P800E-DLX that failed on me with a P4 3.4Ghz SL8K4 OC to 4.35Ghz with ddr400 OC to 512mhz...
I'm not trusting ASUS anymore, i expect my soundcard to broke someday (sad but i really think that, too much badluck with them...)
Best answer
*This should hopefully link to the 1155 motherboard between $100 and $200 (if not, you can get there manually).
My top choice might be this Gigabyte board:
Motherboard site:
*It's also one of the three chosen here:
Related Resources
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Overclocking Motherboards Intel i5
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The world was outraged when a Copenhagen zoo put down a giraffe named Marius and fed him to the lions. But another Danish zoo announced today that it's thinking of doing the same thing. Is there something rotten in the state of Denmark? Or has America just developed more human laws regarding giraffe reproduction?
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Consortium News editor and investigative reporter Robert Parry explains how the sprawling theory has prevented the Democratic Party from examining what it did wrong in the 2016 election.
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RABBITOHS back Matt King will retire at the end of the season, bringing an end to a stellar club and representative career - and one of league's great hairstyles.
The 33-year-old made his first grade debut playing for the Melbourne Storm against the Dragons in round 24, 2003 and has gone on to play 203 first grade games including 91 matches for the Storm, 89 for the Warrington Wolves in the English Super League and 23 to date for South Sydney.
King played in two grand finals for the Storm in 2006 and 2007, winning the premiership in the latter season only for the title to be later stripped away due to the club's salary cap breaches.
He won back-to-back Challenge Cup titles with Warrington in 2009 and 2010, and the League Leaders trophy in 2011 and represented Australia 10 times, while also appearing in nine State of Origin clashes for NSW.
King said he hoped to continue an association with the game and the Rabbitohs following this season.
"I would like to thank every teammate I've ever played with, right back to the under-7s at the Casino Cougars," said King, who also paid tribute to the coaches he's played under over the years.
King has the chance to end his career with a grand final victory and said that would be his main focus, before turning his attention to life after football.
"We still have a job to do here at the Rabbitohs for the rest of the season, and I'm looking forward to playing my role in helping us achieve the highest honours we can this year," he said.
"I will look forward to the next chapter in my life once this season is over, and hopefully I can maintain a connection with the sport."
In honour of Matt King and Scott Prince, who also announced his retirement Monday, here is rugby league's all-time Royal XIII.
1. Garry Jack
2. Johnny King
3. Matt King
4. Chris McQueen
5. Sandor Earl
6. Wally "The King" Lewis
7. Scott Prince
8. Jesse Royal
9. Cameron King
10. Jason King
11. Bill Noble
12. Denis "The Emperor" Fitzgerald
13. Bill Hardcastle


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Here are some things that people are saying so far about The Fleece Era, my poetry collection published earlier this year by Brick Books. I'm grateful to Garry Thomas Morse, Adebe deRango-Adem and the Literary Press Group of Canada for not only taking the time to read my book but also commenting on it.
"At times chilling in its honesty, The Fleece Era nevertheless embraces the complexities of human life with warmth and passion."
Adebe deRango-Adem, Quill and Quire
"The Fleece Era contains some beautiful poetry, but has a
narrative ease to it that will appeal to readers who don't usually read
poetry. The writing is taut yet deep, brimming with energy and openness."
Literary Press Group of Canada
"In her poem 'Neo-Colonialist', Joanna Lilley brushes aside her sensitivities and concerns and adopts a comical tone that is (self-)critical of tropes associated with historical and economical privilege, bringing about a marvelous effect, and this crafty poetic approach amid our obsession with everything North is to be found throughout her collection."
Garry Thomas Morse, Jacket2


text:
Things you view while shopping are saved here.
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Question : Who's offering the cheapest round-trip flight to Jacksonville International Airport (JAX) over the coming months?
Answer : American Airlines is offering the best deal at $278. Better snatch it up quickly because prices range all the way up to $871 over the next three months.
Question : Is the price you found a good deal?
Answer : Ranging from $278 to $871, prices for SJO to JAX do fluctuate more than most routes from Costa Rica. Remember, you can save by booking further in advance.
Question : Looking for the cheapest flight over the next 30 days?
Answer : Apr 26th has seen bookings (as of Apr 24th) as cheap as $278. That comes in 28% below the average price for this route. Saving now means you'll have more cash to spend on your trip.
Question : Will you do what it takes to get the absolute lowest-cost flight?
Answer : For the month of May, the cheapest day to fly is Monday. Having flexibility in your travel plans means you can save more, so be sure to plan ahead when possible.
Question : How many days should you spend in Jacksonville?
Answer : Travelers from SJO to JAX stay nine days on average.


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Sensor of inclination
Found: 4 products← Back to category "Other sensors"
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Wolves and Valentine's Day
The ancient festival of Lupercalia (or wolf festival) was traditionally held on or around February 15th. Some suggest the festival started to honour the she-wolf who nursed Romulus and Remus, the legendary founders of Rome, as babies; other accounts suggest it was a festival of shepherds in honour of the god, Lupercus, who protected their herds from wolves. Regardless of its origins, an underlying theme of Lupercalia was fertility.
In Jasper National Park, the themes of romance and wolves are still common in February. For wolves, breeding season is typically from mid to late February, with new pups born in the spring. At this time of year, you might catch wolf pairs nuzzling, prancing and scent marking. All female wolves are ready to mate at about the same time, a great strategy to keep their mates from looking at other she-wolves. A wolf pair will stay together year round and when the pups arrive, dad plays a role in their upbringing.
Family Day is also celebrated in February and Jasper National Park has a weekend full of activities planned at Marmot Meadows. Family Day also aligns well with wolf family values as wolf packs consist primarily of the breeding (alpha) pair and their young. Wolf pups grow quickly and by February, they will already be out hunting with the pack. Several generations may be found in one pack but eventually young wolves may leave to find their own territory and mate. With romance in the air, this often happens in February but can happen at any time of the year.
February is a great time to get out and explore the natural wonders of Jasper. On your own, with a loved one or with family, your adventure awaits with star-filled nights, longer days and incredible scenery. Keep an eye out and you might even catch a glimpse of wolves snuggling in the snow.
While seeing a wolf in the wild is an incredible experience, it is important to remember that wolves are wild animals. Help keep them alive and wild. Remember: keep your distance, travel smart – be prepared, never feed a wild animal, and keep dogs on leash.
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Welcome to the end of the world4.41 / 5.00 4,607 Views
Living Dolls: No Evil 024
Wouldn'tyou just like to... leave conflict.4.26 / 5.00 1,621 Views
Cortex's Airship
What happened to Cortex's airship?4.23 / 5.00 3,427 Views
Love it.
I almost pissed myseelf at first. I was just like WTF!!
Then it was better XD
hahahahahaha I KNOW RIGHT?
Hmm i don't know what to make of this
Design wise its okay as i can clearly see that it is a parady of south park.
it was too short
i'm not sure if this a part of a series of shorts or not But wouldn't collabing them make it better having more jokes than just the one, giving more impact on the veiw because the humour wasn't bad it did make me laugh.
But any way it was alright
good luck and have a good day :D
it was a parody to silence of the lambs. not south park


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Spent a week there in Sept 2015 with a group of 5 for our yearly fishing trip. Cabin was clean and the owners were very friendly. Fishing was excellent. Will be making a return trip next year. If rustic cabins and great fishing is what...Más
Estamos buscando más información sobre esta habitación
Estamos buscando más información sobre esta habitación
"Number 3 is right on the beach; number 1, 2 are close to the beach and small harbour"
"Don't forget sheets, towels, blankets, tea towels and radish cloths"


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Save $893.00 (80%)
The carpet is itchy. What? You want me to write 50 characters?Read More
This carpet was about the quality of burlap. It is thin and scratchy. Nothing you would ever sit on. We had purchased it for our living room and despite the AWFUL return policy (pay for shipping and restocking fee for opening it) - I bit the bullet and returned it. I would NOT recommend this carpet and now after experiencing the awful return policy, I wouldn't even recommend this site unless you're sure about the quality based on description or reviews.Read More
Rug has a cool contemporary pattern for a great price. Color is not obnoxious.Read More
The actual pattern wore off within 6 months, by the foot of the sofa and the foot of a chair that is often used. Then we turned it around, and the pattern wore off on the other side as well. It continues to "shed" as well. We've had it only two years and it looks like 20. It has made me extremely reticent to purchase another rug on Overstock.Read More
I'm happy with this purchase. Although the color does say light green in the title, it really looks much more yellow/sand on my computer--it's pale lime green in person. That said, I still really like it and luckily it does go well with the rest of my decor (chocolate brown/grays/gray-blue/olive/grass green). It adds much-needed brightness to the room with my dark couches. I've got two kids and a large black dog and it's wearing well after several months of daily use (in our family room)--looks brand new still.Read More
Safavieh Hand-woven Moroccan Reversible Dhurrie Green/ Ivory Wool Rug (8' x 10')
Sale: $227.99


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Size: 4.5"X3.5"
Color: Camouflage
Material: Genuine Leather and Calf hair
Condition: Like New
Brand: Jimmy Choo
Selling (NO TRADES) an authentic men's Jimmy Choo camouflage calf hair wallet. This wallet originally retailed at $425. Genuine Italian leather interior with calf hair imprinted in a camouflage pattern. This wallet was a gift I received in 2013 and it has never been used and has been kept in a protective pouch. It is 100% authentic. I am willing to make a deal if you give me a reasonable offer.
Join the 2,356,536 happy neighbors and get started selling and saving!
There's even a "You Must Be Happy" Guarantee.
©2017 Bookoo, Inc. 2270 US Highway 30, Oswego, IL 60543. Dedicated to our families.


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Jackson Hotels with Indoor Pools
Hotel search
Get Secret Prices on selected hotels
These prices aren't available to everyone.
- Jackson Town Square
- Jackson Hole and Greater Yellowstone Visitor Center
- Snow King Resort
- National Elk Refuge
- Granite Hot Springs
- Alpine Slide of Jackson Hole
- Teton County-Jackson Recreation Center
- Jackson Hole Playhouse
- Teton County Fairgrounds
- Jackson City Hall
- Jackson Hole Rodeo Grounds
- Pink Garter Theater
- Amaze'n Maze in Jackson Hole
- Snake River
- Craig Thomas Discovery and Visitor Center
- Teton Ice Park
- Miller House
Explore Jackson
Hotels with a pool in Jackson
While you visit Jackson, book a hotel with a pool. Start your day with a swim before exploring the city.
Whether you are on a business trip or you are on vacation, on Hotels.com you will find a wide range of accommodation with a pool with the Price Guarantee.
Take a look at the photos and read our guest reviews to find a hotel with the characteristics you are looking for. You will find 5054 hotel reviews that will help you find the perfect hotel with a pool for your stay.
Currently, the hotel with the highest rate from our users is The Lodge at Jackson Hole. Many of the opinions expressed on our site are written by users from South Africa.
With Hotels.com Rewards you will have the get a free night* after collecting 10 nights.
What are you waiting for? Book your pool hotel in Jackson and make your stay in Wyoming unforgettable!
Jackson travel guides
Where to Stay in Jackson Hole - From Rustic Cabins to Refined Rooms
Lodging options abound in Jackson Hole, including conveniently located motels and ski lodges, elegan...
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Shops that feature handcrafted items inspired by mountain and western living dominate Jackson Hole's...
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Jackson Hole is a low-lying valley filled with natural splendor, making it a magnet for skiers, hike...


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Calais forms TIF district to boost growth
The Calais City Council has approved a tax increment financing district that includes much of the downtown as well as other lots to spur economic development.
CEI presents 'Opportunity Award' to St. Croix Tissue
Braving Tuesday's nor'easter to attend CEI's annual meeting in Brunswick, St. Croix Tissue Inc., was awarded CEI's "2017 Award for Expanding Economic Opportunity" for its $120 million...
Jackson Lab nabs $2.8M in fed grants to target breast cancer
Two Jackson Laboratory professors, including the Bar Harbor Lab's CEO, were awarded two U.S. Department of Defense grants totaling $2.8 million to research one of the most deadly breast cancers.
Machias Savings opens Portland branch
Machias Savings Bank has opened a new branch at 193 Middle St. in Portland on Feb. 27.
Longtime Stonington restaurant sees transformation
Fisherman's Friend — a table-service restaurant in Stonington that spanned two locations in 40 years — is being repurposed as a counter-service eatery called Stonecutters Kitchen.
Ellsworth pop-up event spurs downtown growth
A December pop-up event in Ellsworth called the Holiday Marketplace has persuaded several businesses to set up permanent shops in town.
New data: Maine Airbnb hosts earn $26 million in 2016
Airbnb announced today that Maine's 3,700 active hosts earned more than $26 million in supplemental income in 2016 by hosting approximately 174,000 visitors to the state.
After long downturn, seaside inns find new investors
Laurie Schreiber |
Migis Hotel Group's purchase of the Higgins Beach Inn in Scarboroug is part of considerable transactional activity among independently owned hotels along the coast over the past year. Sales of other...
Vitamin helps prevent certain vision loss, JAX researchers find
Taking vitamin B3 in water may slow or prevent the slow vision loss from glaucoma, an eye disease that eventually leads to blindness and has no cure currently, researchers at Jackson Laboratory found.
Chlorine leak at Baileyville mill sends several people to hospital
A leak of toxic chlorine dioxide at the Woodland Pulp mill in Baileyville affected 16 contractors and two employees, sending several to the hospital.


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Dog Walking in Vista East, Orlando
Book a dog walker to give your dog a 30-minute walk around your neighborhood.
Your fun neighborhood dog uncle!
Orlando, FL, 32828
Dog Boarding, House Sitting, Drop-In Visits, Doggy Day Care, Dog Walking
"Scott is one of the best dog sitters my dog has ever had! My frenchie, Cappie, loves hanging out with him. He will take my dog on long walks, or to the dog p... (more)"
I will be your dog's BFF!
South Semoran, Orlando, FL, 32822
Drop-In Visits, Dog Walking
"She was very friendly and had great communication from start to finish. At the end of the walk she gave me all the details of what happened. I would definite... (more)"
Super loving, patient, responsible
Orlando, FL, 32828
House Sitting, Drop-In Visits, Dog Walking
"Delelah did an amazing job with my dog, Vita! Vita absolutely loved her. Delelah walked her, treated her in the same way I do (very important if you are trai... (more)"
Lifelong Animal Lover for your Pets
Orlando, FL, 32812
House Sitting, Drop-In Visits, Dog Walking
"Debbie is awesome. She is reliable and great with out super finicky puppy Hamilton. We use her services every day that we are at work and feel very comfortab... (more)"
Vegetarian with a heart for animals
Orlando, FL, 32828
Dog Boarding, Drop-In Visits, Doggy Day Care, Dog Walking
"Catherine has sitted many times for dogs over the years. She has taken care of all kinds of dogs, from small Yorkshire Terriers to large Huskies, both male a... (more)"
Pappy's Pet Care - "start with trust"
orlando, FL, 32806
Dog Boarding, House Sitting, Drop-In Visits, Doggy Day Care, Dog Walking
"I was leaving for vacation but was apprehensive about leaving my little chihuahua. He is very timid with new people and a sitter would have to "catch" him an... (more)"
I can't wait to meet your animals!
78233, Orlando, FL, 32825
House Sitting, Drop-In Visits, Dog Walking
"Jordan Robichaux loves animals of all kinds. In July 2013 my family went to Port Aransas for 3 nights and 4 days. Jordan stayed at my house and took care o... (more)"
I love Animals
Vista East, Orlando, FL, 32829
House Sitting, Drop-In Visits, Dog Walking
About: I have always had animals growing up. Ive owned dogs, cats, birds, ferrets, and many other animals. I now own a Jack Russel Terrier who I have trai... (more)
Love is a four-legged word!
Vista East, Orlando, FL, 32829
Dog Boarding, Drop-In Visits, Doggy Day Care, Dog Walking
"Chavelly is an amazing caregiver! I have known her for almost a year now. I have a 6 year old Golden Retriever and a 3 year old German Shepherd and they love... (more)"
Dogs are family.
Orlando, FL, 32812
House Sitting, Drop-In Visits, Doggy Day Care, Dog Walking
About: I have been a dog lover my entire life. I love and care for all animals as if they are my own. They will get love, attention, plenty of time runnin... (more)
Dog lover to the core
Orlando, FL, 32822
Dog Boarding, House Sitting, Drop-In Visits, Doggy Day Care, Dog Walking
"Alex is the most loving dog mom I know. My dogs are family to me and I hate leaving them. It is so much easier knowing without a doubt that they will be lo... (more)"
Experience exceptional service and a personalized match
From start to finish, we'll handle all the details for you.Learn About Premier
Rover also offers dog walking in these other Orlando neighborhoods:
|College Park
|Colonicaltown South
|Lake Dot
|Lake Nona South
|Lorna Doone
|Park Central
|Rock Lake
|Rowena Gardens
|Southern Oaks
Rover is the simple, savvy way to find and book a dog walker in Vista East, Orlando, FL. Founded on the belief that everyone should have the opportunity to experience the unconditional love of a dog, Rover makes it easy for dog owners throughout the U.S. to reach walkers who offer dog walking. Just like you, Vista East dog walkers on Rover are dog lovers too. Many of our walkers offer dog walking services and would love to take care of your dog when you can't be there. Book a 30-minute walk anytime you need it, and discover just how many of your neighbors are dog lovers too. You'll be glad to know dog walking booked on Rover is covered by the same great benefits as overnight sitting, including premium pet insurance, photo updates, and 24/7 support.
A Daily Treat: A Blog by Rover
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- 9 Dobermans as Sweet as Sugar
Book a Stay, Donate to a Cause
Sit a Dog, Save a Life lets you raise money for local dogs-in-need by doing something you do already: asking your neighbors to watch your dog instead of leaving them in a kennel. Many Rover walkers in Vista East, Orlando donate a percentage of their earnings to nonprofits through Sit a Dog, Save a Life. When you book with a walker who has the Rover Donation Badge on their profile, you're helping dogs in need, right here in Orlando.
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The book shows you how architecting a modern security visibility infrastructure can help your business adapt to new threats, lengthen the usefulness of your current security investments, and optimize uptime and availability. See the entire threat landscape, understand security visibility basics, support both inline and out-of-band security systems, explore security visibility use cases and ask the right questions about visibility.Sponsored Listing
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Designed for playing movies nicely for the person who likes to watch or present movies on their computer (such as the casual viewer or the video artist). Features full screen or border-less floating windows, on the fly playlist creation and more.10 weekly downloads
RubyCocoa is a Mac OS X framework that allows Cocoa programming in the object-oriented scripting language Ruby.3 weekly downloads
Coconut Library
The Coconut Library is an Objective-C class library for PC-UNIX systems and MacOS X. This library is designed to develop software which works unix systems and MacOS X. And depends on Cocoa library for MacOS or Cacao library for unix systems.
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|By Marketwired .
Article Rating:
|May 27, 2014 08:00 AM EDT
REDWOOD SHORES, CA -- (Marketwired) -- 05/27/14 -- Oracle (NYSE: ORCL)
News Summary
Meeting the demands of today's web and cloud applications, Oracle announces the general availability of MySQL Fabric. MySQL Fabric provides an integrated system that makes it simpler to manage groups of MySQL databases. It delivers both high availability -- via failure detection and failover -- and scalability through automated data sharding.
News Facts
- Continuing to drive MySQL innovation, Oracle announced the general availability of MySQL Fabric, an open source framework to manage farms of MySQL servers.
- Available for download at http://dev.mysql.com/downloads/fabric/, this integrated and extensible system makes it easier to scale out or add high availability to MySQL applications.
- For more details, join the Webcast on Thursday, June 19, 2014 at 9:00 am PT.
MySQL Fabric Capabilities
- Automatic failure detection and failover when used with MySQL Replication for high availability, including:
- Monitoring of the master database; if the server fails, MySQL Fabric selects one of the slave databases and promotes it to be the new master.
- Automatic routing of transactions to the current master and load-balancing of queries across slave databases. Topology and state of the servers are transparent to the application.
- Automated data sharding and re-sharding make it easier for development and operations, or DevOps, teams to manage the process. This enables users to:
- Allow tables to be sharded for scale-out of both reads and writes.
- Select which tables should be sharded and specify the columns to be used as sharding keys, including whether to use a HASH or RANGE based mapping.
- Move existing shards to new servers or split them into multiple shards.
- Extensions to PHP, Python, and Java connectors allow transactions and queries to be routed directly to the correct MySQL Server, eliminating the extra latency caused by passing through a proxy.
Supporting Quote
- "Many of the world's largest websites and cloud-based applications rely on MySQL replication and sharding to deliver high availability and scalability," said Tomas Ulin, vice president, MySQL Engineering, Oracle. "MySQL Fabric makes high availability with automatic failure detection and failover, as well as automated data sharding, accessible to all. With this integrated and open source framework, Oracle makes it easier to safely scale out MySQL applications, either on premises or in the cloud."
Supporting Resources
- MySQL Fabric
- Join the Webcast on Thursday, June 19, 2014 at 9:00 am PT.
- MySQL Fabric is part of the MySQL Utilities 1.4.3 package that can be downloaded here. Terms, conditions and restrictions apply.
- White Paper -- MySQL Fabric -- A Guide to Managing MySQL High Availability and Scaling Out
About Oracle
Oracle engineers hardware and software to work together in the cloud and in your data center. For more information about Oracle (NYSE: ORCL), visit www.oracle.com.
Oracle and Java are registered trademarks of Oracle and/or its affiliates. Other names may be trademarks of their respective owners.
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Teri Whitaker
Email Contact
Danielle Tarp
Blanc & Otus
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Bert Loomis was a visionary. This general session will highlight how Bert Loomis and people like him inspire us to build great things with small inventions. In their general session at 19th Cloud Expo, Harold Hannon, Architect at IBM Bluemix, and Michael O'Neill, Strategic Business Development at Nvidia, discussed the accelerating pace of AI development and how IBM Cloud and NVIDIA are partnering to bring AI capabilities to "every day," on-demand. They also reviewed two "free infrastructure" pr...
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|Publication number
|Publication type
|Application number
|Publication date
|May 28, 1996
|Filing date
|Jul 20, 1994
|Priority date
|Jul 20, 1993
|Fee status
|Also published as
|Publication number
|Jochen Franzen, Reemt-Holger Gabling
|Original Assignee
|Bruker-Franzen Analytik Gmbh
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (13), Non-Patent Citations (4), Referenced by (12), Classifications (12), Legal Events (4)
|External Links: USPTO, USPTO Assignment, Espacenet
The invention relates to a method for carrying out ion-molecule reactions in RF quadrupole Ion Traps for chemically ionizing (CI) the molecules of an analyte gas, or for the analysis of gas mixtures, or for studying ion-molecule reactions in ion traps.
Chemical ionization is generally a 3-stage process. In the first stage primary ions of the reactant gas are generated by electron impact. In the second stage secondary ions of the reactant gas are generated by ion-molecule reactions of the primary ions with the molecules of the reactant gas. In the third stage the required ions of the analyte gas are created by ion-molecule reactions with the secondary ions of the reactant gas. In this process there are very many side-reactions and branches of the reaction path which lead to undesirable reaction products.
Ion-molecule reactions have been studied for a long time to clarify reaction mechanism. It has been particularly the reaction cross-sections which are of interest, and the dependency of the reactions on gas temperature, concentration of the reaction participants, the impact energies, and other parameters.
Study of the ion-molecule reactions has been performed in ion beams, in plasma, in space-charge-bound ion clouds (locked into an electron beam), but particularly also in both types of ion trap mass spectrometer: ion cyclotron resonance spectrometers (ICR) and RF quadrupole ion traps. The reactions are examined by mass-spectrometric analysis of the resulting product ions.
There is particular interest in ion-molecule reactions as probes for certain structural properties of the neutral molecules examined. For this purpose it is necessary to have output ions of high purity for the reactions in order to prevent contamination of the product ion spectrum examined by undesirable by-products.
Elimination of undesirable ions has been well known for a long time now with regard to ICR spectrometers. One has also been able to isolate or store selectively ions of uniform mass-to-charge ratios in quadrupole ion traps.
For the study and application of ion-molecule reactions, however, it is frequently necessary to select specific output ions for a certain reaction using a reaction path which involves predecessor ions and it is therefore desirable to suppress side-reactions. So far there have been special methods available for this.
Chemical Ionization (CI) is a widespread method for ionizing substances. When used properly it provides information about the molecular weight of a substance. Spectra of mixtures can be interpreted more easily because far fewer fragmented ions are created than with electron impact spectra. Measurement of the molecular ions is also important for clarification of the structure of the substances. Chemical ionization is advantageous particularly for applying MS/MS methods to investigating molecular ions. There are other applications in fast quantitative analyses of substances in mixtures.
As various reactant gases and various ionization reactions are available for chemical ionization, the method can be very well adapted to the aim of the investigation. The method is described in all the relevant, more recent mass spectrometry textbooks, for example, in Odham, Larsson and Mardh's "Gas Chromatography/Mass Spectrometry, Applications in Microbiology", Plenum Press, New York and London, 1984.
Chemical ionization is described as "soft" ionization which ionizes more carefully than the relatively "hard" electron impact ionization. Careful ionization means that during the ionization process there is virtually no fragmentation of the molecular ion because only small further quantities of energy are transferred to the molecule in addition to the ionization energy. The usual electron impact ionization with 70 to 100 eV electrons shows no measurable molecular ions for approx. 30% of all substances but only fragmented ions; unambiguous identification of the substances is thus hindered. Almost with regularity, chemical ionization, on the other hand, shows a "pseudomolecular ion" which has been obtained by protonation and the mass of which is just one atomic mass unit larger than that of the molecular ion. By suitably selecting the reactant gas and the ionizing reaction it is possible to suppress almost completely any ensuing fragmentation of the pseudomolecular ion.
Chemical ionization (CI) usually takes place in three ionization stages from a mixture of gases. The gas mixture consists of a largely inert carrier gas which plays no role in the reactions (also called collision gas), a reactant gas for forming the proper reactant ions for chemical ionization, and the analyte or test gas which is to be ionized chemically. The latter can also be a mixture of various substance gases or vapours if at the same time more than one substance is to be subjected to a qualitative or quantitative investigation.
In standard ion sources for chemical ionization, which are operated at a pressure of about 1 millibar, the reactant gas has a much higher concentration than the analyte gas. Therefore, in an initial stage of electron impact ionization (EI) it is predominantly primary ions of the reactant gas which are formed. The EI ions of the analysis gas which are created at the same time are relatively small in number but they subsequently form background noise in the final CI spectrum of the analysis gas ions.
In ion traps which are operated at pressures of 10-4 to 10-3 millibar such a high ratio of concentrations of reaction gas and analysis gas cannot be set because if it were, the reaction times would be too long due to the pressures being much lower. For this reason, in ion traps there are far more fragmented ions resulting from EI ionization if no further protective measures are taken.
The primary ions of the reactant gas which are formed in the phase of electron impact ionization are naturally not uniform but, in turn, consist of the molecular and fragmented ions of the reactant gas, in which one type of ion (ions of a single mass) usually largely predominates. For convenience, this predominant type of primary ion is referred to herein as the "main primary ion". The main primary ions are generally not suitable for subsequent chemical ionization for energy and structural reasons. The main primary ions of the reactant gas, however, then react in a second stage with molecules of the reactant gas in ion-molecule reactions, "main secondary ions" of the reactant gas being formed. The main secondary ions have a structure and an energy balance which allow them to react with the molecules of the analyte gas in a third stage, forming the CI analyte gas ions.
The structure necessary for chemical ionization is generally characterized in that a proton is relatively loosely bound to a residual molecule which otherwise has a very stabile energy balance. Chemical ionization is largely a protonation reaction. In rarer cases it is a methylation reaction or the transfer of an even larger charged fragment. In general the aim is to achieve undisturbed protonation.
Example: during chemical ionization with water as reactant gas the primary ions H2 O+ ' are initially formed. Also created are the subprimary ions OH+, of which there is a large number, but they have no further involvement here. The primary ions H2 O+ ' react with other water molecules according to the equation
forming the free radical OH' and the main secondary ion OH3 +. The main secondary ion OH3 + then reacts with molecule M of the test substance in accordance with the equation
forming the "pseudomolecular ion" MH+. This protonation reaction (2) is the "chemical ionization" proper.
Naturally with all these processes there are a number of side reactions which may lead to other CI analysis gas ions. The side reactions can be caused by subprimary ions but they are chiefly generated by side reactions of the main primary ions which then lead to subsecondary ions. The subsecondary ions can then, with their own CI reactions, lead to slightly different CI analysis gas ions.
Apart from the protonating CI reaction, which is really desired, there are other ionization reactions of the main secondary ion taking place for this reason, which, under certain circumstances, may lead to large quantities of fragmented ions of the test molecule. It depends on the aim of the investigation as to whether these are desirable or undesirable. For energy reasons the fragmented ions are generally all the more frequent, the smaller the ionizing main secondary ions are.
Sometimes there are even two competing CI reactions of the same reactant gas, whereby the formation of fragmented ions is different for the two reaction chains. Example: The frequently used chemical ionization with methane as reactant gas initially leads to the EI ions CH3 + and CH4 + ', the relative frequency of which depends on the energy of the ionizing electrons. These electrons react with other methane molecules forming two different main secondary ions.
Under normal conditions at a pressure of 0.7 millibar about 48% ions are type CH5 + and 40% type C2 H5 +, the remainder being accounted for by even heavier ions. The main reactions for the subsequent chemical ionization are:
whereby the second reaction (6) provides more subsequent fragmentations than the first one.
As is evident from this, chemical ionization can be adapted to the problem of the investigation. Consequently, chemical ionization is generally always "softer" whenever one proceeds to heavier reactant gas ions or selects the correspondingly heavier main secondary ions. If chemical ionization with water (OH3 + as main secondary ion) is still relatively hard, it is increasingly softer in the sequence ammonia (NH4 +), methane (CH5 +, C2 H5 +), isobutane (C4 H9 + and many others).
For chemical ionization in an ion trap a mixture is usually admitted made up of a collision gas of low molecular weight, a reactant gas for forming the output ions for chemical ionization, and an analyte gas to be tested. In ion traps, however, no such high concentration ratio can be set as is permitted by the ion sources usually operated at a pressure of 1 millibar for other types of mass spectrometer. For this reason, in ion traps it is particularly disadvantageous that the fragmented ions of the test substance cannot be removed from electron impact ionization and remain visible in the CI spectrum of the substance.
To eliminate this disadvantage, EP 0 215 615 B1 describes a method whereby initially only light ions in a certain mass range are stored. The range of light ions covers both the primary and secondary reactant gas ions as well as the light fragmented ions which result from the analysis gas molecules by electron impact. In a second stage in which the storage conditions of the ion trap are changed, storage of the CI ions of the analysis substance are then admitted. The CI ions are then identified by the special method of ion ejection by mass-sequential stability at the limit of the stability range in the a,q diagram, including the remaining electron impact ions.
Consequently, the disadvantage of chemical ionization in ion traps compared with standard CI ion sources is partially offset. There is still the deficiency that the remainders of electron impact ionization are not eliminated and also that there is no clear selection of reaction paths.
Due to the publication "A New Mode of Operation for the Three-Dimensional Quadrupole Ion Store (Quistor): The Selective Ion Reactor" by J. E. Fulford and R. E. March (International Journal of Mass Spectrometry and Ion Physics 26 (1978) 155) a method is known where during electron impact ionization the main primary ions in the ion trap are freed of all other ions because the working point of the main primary ions with a pulse of DC voltage is briefly shifted into the corner of the stability diagram. Consequently all the other ions are transferred to instable areas and thus removed from the ion trap. After the end of the pulse the reactions required can then take place with the analysis gas molecules. The resulting product ions are then expelled from the ion trap by a pulse. They pass through a quadrupole filter with which in any experiment one type of ion can be identified. By cyclic repetition of the experiment with different filter values for the quadrupole filter the entire spectrum can be scanned.
The disadvantage of this method is that only the main primary ions of single-stage CI processes can be isolated. The single-stage CI processes in this work are generally based on the so-called charge exchange (CE) reactions but these are much less interesting and are not even classified as CI processes by some authors. Moreover, this method can only provide relatively few of the desired reactant gas ions for physical reasons (depth of potential wall). Even in the event of a combination with one of the modern standard methods of scanning which identify all the ions in the ion trap by mass-sequential ejection, there is still the disadvantage of not being able to eliminate side reactions of the main primary ions.
The present invention seeks to provide a method which permits tailored chemical ionization of the molecules of the test substance by secondary reactant gas ions without the formed CI ions of the test substance being contaminated with fragmented ions from electron impact ionization or with product ions from side reactions. In the same way it should be possible to provide suitable output ions for ion-molecule reactions.
From U.S. Pat. No. 4,761,545, EP 0 362 432 A1, and U.S. Pat. No. 5,134,286 it is known that an ion trap can be subjected to a frequency mixture in such a way that storage of ions with selected mass-to-charge ratios is prevented. The frequency mixture is applied as a mixture of voltages with various frequencies to the electrodes of the ion trap and inside the ion trap generates corresponding alternating fields which can cause the secular oscillations of the ions in the ion trap to perform resonant energy absorption dependent on mass.
If the frequency mixture is applied to the two end caps of the ion trap in phase opposition, a dipolar alternating field is created in the ion trap with excitation of the oscillations in the axial direction of the ion trap. If the frequency mixture is applied to the two end caps in phase, hence phase opposition between the ring electrode on the one hand and the end cap electrodes on the other, a quadrupolar alternating field is generated in the ion trap which can excite the secular oscillation both in the axial and in the radial direction.
In particular it is possible to generate the frequency mixture in such a way that due to integrated frequency gaps only a few types of ion with selected mass-to-charge ratios can be stored. Furthermore it is possible to adapt the frequency mixture during a phase of electron impact ionization so that only certain ions of the resulting ion mixture are stored.
Therefore, it is an object of the invention to select product ions of the desired two first stages of the reaction path in such a way that they are stored on their own and to suppress the product ions of undesirable reaction paths.
The invention resides in a method for carrying out ion-molecule reactions in RF quadrupole ion traps. By superposing the quadrupole field with a dipolar frequency mixture in which there are two accurately selected frequency gaps, only storage of the desired primary and secondary ions of the reactant gas is permitted in the first phase of electron impact ionization of the mixture of analyte and reactant gases. All the other ions are prevented from being stored by excitation of their secular oscillations. In the second ionization phase, in which all the ions in a wide range of mass-to-charge ratios can be stored by switching off the dipolar frequency mixture, it is the secondary ions which ensure chemical ionization of the analysis gas molecules.
This new type of chemical ionization permits the selection of the product ions of a single desired CI reaction and suppresses all the undesirable side-reactions with other ions of the gas mixture introduced.
By analogy, the method can also be used for reaction paths which have more than three stages or which use ions made externally. There are further potential applications in the field of customized ion-molecule reactions as probes for certain characteristics of analyte gas molecules, to clarify molecular structure for example.
In accordance with the invention, there is provided a method of carrying out an ion-molecule reaction on molecules of a sample gas in an RF quadrupole ion trap, which method comprises the steps of (a) carrying out an ionisation reaction to form primary ions, the primary ions being such as to initiate a desired reaction path to the ion-molecule reaction, the reaction path involving at least one secondary ion; (b) operating the ion trap so as to store only ions lying on the desired reaction path, including at least the primary and secondary ions, and optionally containing other ions, for example tertiary ions; (c) causing ions stored in the ion trap, (for example the secondary or tertiary ions) to take part in the ion-molecule reaction with the sample gas, and varying the operation of the ion trap so as to permit storage in the ion trap of the products of the ion-molecule reaction; and (d) measuring the product ions by using the ion trap as a mass spectrometer.
In a preferred aspect of the invention, a frequency mixture is applied during electron impact ionization of a gas mixture so that only the ions which are generated to form desired secondary (or even tertiary) reactant gas ions along a selected reaction path, are stored in the ion trap. Then, by switching the frequency mixture off, storage of all the ions in a mass range of interest is enabled, and the CI ions from the reaction of the secondary (or tertiary) reactant gas ions with the molecules of the test substance can be stored. In an intermediate phase, after switching off the electron impact ionization, alternatively, the remaining primary reactant gas ions can be eliminated by a different frequency mixture if they are not wanted in the phase of chemical ionization proper.
This type of chemical ionization by reactant gas ions of a selected reaction path leads to very clear-cut CI spectra.
Since the formation of the reactant gas ions can be continued over any length of time, the ion trap can be filled with these ions up to the space charge limit. When the space charge limit has been reached, the secular frequencies of the ions stored may be shifted so here too the space charge limit constitutes a limit for filling the ion trap. However, since these ions quantitatively transform into CI ions of the test substance as the method continues, an ideal high yield of CI ions can result.
A number of preferred embodiments of the invention will now be explained in more detail with reference to the accompanying drawings, in which:
FIG. 1 shows a block diagram of a high frequency quadrupole ion trap;
FIG. 2 shows an amplitude profile of a frequency mixture with two integrated gaps; and
FIG. 3 shows a time diagram for the sequence of a complete measuring cycle.
FIG. 1 shows a block diagram of an arrangement including a high frequency quadrupole ion trap, which can prevent storage of ions in a wide range of masses, but permits storage of some selectable types of ion. A processor can calculate the digital values of a superposed quasihomogenous frequency mixture with a few integrated frequency gaps step by step. These values are stored in a digital memory. During certain ion trap operating statuses these values can be read out under clock control and fed to an analog amplifier via a digital-to-analog converter. The voltage mixture generated can be applied across the two end caps of the ion trap to create a dipolar field. Inside the ion trap a dipolar field is then generated with the frequencies of the voltage mixture which excites the secular oscillations of the stored ions. All the ions which undergo resonance of their secular oscillation with one of the frequencies in the mixture are in this way enlarged with respect to oscillation amplitude until they leave the quadrupole field by impact on to the electrodes or by ejection. Only those ions whose secular frequency coincides with the frequencies of the gaps in the z-direction can be stored. These ions are usually decelerated in a collision gas until they collect at the center of the ion trap. Storage of the ions is brought about by a quadrupolar radio frequency field which, under clock generator control, is supplied by an RF amplifier via an RF drive circuit. The voltage of the RF amplifier is usually applied to the ring electrode.
FIG. 2 shows an amplitude profile of a frequency mixture with two integrated gaps. Such a frequency mixture can, for example, be generated as white noise, from which two narrow frequency ranges are eliminated by filtering. However, digital generation is simpler, as shown in FIG. 1. The frequency mixture illustrated here as continuous is then generated from individual frequencies which are close together though. The density of the frequencies must be adequate so that all the adjacent ion masses are included. Such a frequency mixture is termed "quasi homogenous".
The frequency mixture must have an upper limit or else the side band frequencies of the secular oscillation of the desired ion types to be stored will be included and these ions will also be eliminated. The upper limit should in theory be Ω/2, whereby Ω is the frequency of the drive or storage radio frequency. In FIG. 2 this limit is shown for the frequency mixture. The limit corresponds to storage of the so-called cut-off mass, below which no more ion masses can be stored in the ion trap.
FIG. 3 shows a time diagram for the sequence of a complete measuring cycle with a period for ionization (here due to the impact given by electrons which are shot into the ion trap in the form of an electron beam from outside), with a period of selective storage of ions of the reaction path, with a subsequent period for chemical ionization, and a final period for scanning the spectrum of the chemically ionized analysis gas molecules.
The period of selective storage is characterized by the application of the frequency mixture with selected gaps. It covers the period of electron impact ionization and continues after the electron impact ionization has been switched off in order to wait for transformation of the primary ions of the reactant gas to secondary ions. Due to the high concentration of reactant gas this transformation normally takes place very quickly. Naturally, in this period ion-molecule reactions with the analysis gas also take place already. However, the product ions of these reactions cannot be stored. Due to the lower concentration of analysis gas the product ion of the output ions for the reactions by far offsets the losses of output ions.
The period of selective storage ends when the frequency mixture is switched off. The frequency mixture is best switched off when no further increase in output ions for the further ion-molecule reactions is to be expected. From that time on, the product ions of the required CI reaction can be stored. The output ions for this CI reaction are consumed almost completely if the CI period is of adequate length. The ensuing period of spectrum scan shows only a few of the output ions for the reaction.
The CI spectra of the analyte substances obtained in this way are exceptionally clear-cut. They contain no fragmented ions of the electron impact ionization whatsoever and also no ions which have resulted from side reactions.
The reactant ions for the ion-molecular reactions do not have to be generated within the ion trap. They can also be generated outside the ion trap and shot into the trap at low energy. Again they may be primary reactant gas ions from which the secondary reactant ions are formed in the ion trap, or the secondary ions can already be introduced into the trap. In both cases, within the meaning of the invention, there is mass-selective storage of ions which are of interest along the reaction path to the output ions.
If the remaining primary reactant gas ions disturb subsequent ion-molecule reactions, they can be eliminated by changing the frequency mixture for mass-selective storage just before the phase of ion-molecule reactions.
Analysis of the product ions of the ion-molecule reaction or the CI reaction can take place with the ion trap itself which is used as a mass spectrometer in this case. On the one hand, any of the various familiar methods of mass-selective ion ejection can be used but on the other, methods may also be used to analyze the secular frequencies inside the ion trap without ion ejection.
For mass-selective ion ejection the following methods have become known: (a) the "mass-selective instability scan" (U.S. Pat. No. 4,548,884), (b) mass-selective ejection by nonlinear resonances (U.S. Pat. No. 4,975,577), and (c) ejection by electrically generated dipole or quadrupole fields (U.S. Pat. No. 4,882,484, U.S. Pat. No. Re 34,000). All three methods advantageously use a linear increase in the storage RF voltage for mass-sequential ion ejection, as illustrated in FIG. 3.
For the analysis of the secular frequencies Fourier transformation methods have become known which were applied to induced image currents in special electrodes, but also to the frequency of laser-induced fluorescent flashes. These too can be used to scan the mass spectrum.
The foregoing description has been limited to specific embodiments of this invention. It will be apparent, however, that variations and modification may be made to the invention, with the attainment of some or all of its advantages. Therefore, it is the object of the appended claims to cover all such variations and modifications as come within the true spirit and scope of the invention.
|Cited Patent
|Filing date
|Publication date
|Dec 29, 1982
|Sep 10, 1985
|Finnigan Corporation
|Method of mass analyzing a sample by use of a quadrupole ion trap
|Sep 6, 1985
|Aug 11, 1987
|Finnigan Corporation
|Method of operating quadrupole ion trap chemical ionization mass spectrometry
|May 23, 1986
|Aug 2, 1988
|The Ohio State University Research Foundation
|Tailored excitation for trapped ion mass spectrometry
|Oct 31, 1988
|Nov 21, 1989
|The United States Of America As Represented By The Secretary Of The Army
|Method of mass analyzing a sample by use of a quistor
|Dec 29, 1989
|Dec 4, 1990
|The United States Of America As Represented By The Secretary Of The Army
|Method and instrument for mass analyzing samples with a quistor
|Feb 28, 1991
|Jul 28, 1992
|Teledyne Cme
|Mass spectrometry method using notch filter
|Apr 6, 1993
|Jan 10, 1995
|Varian Associates, Inc.
|Methods of using ion trap mass spectrometers
|Sep 4, 1986
|Mar 25, 1987
|Finnigan Corporation
|Method of operating a quadrupole ion trap
|May 11, 1988
|Nov 23, 1988
|Finnigan Corporation
|Method of using an ion trap in the chemical ionization mode
|Oct 7, 1988
|Apr 11, 1990
|Bruker Franzen Analytik GmbH
|Improvement of a method of mass analyzing a sample
|Feb 11, 1992
|Sep 17, 1992
|Teledyne Mec
|Chemical ionization mass spectrometry method using notch filter
|Aug 28, 1992
|Mar 18, 1993
|Teledyne Mec
|Mass spectrometry method using supplemental ac voltage signals
|Nov 10, 1992
|Jun 24, 1993
|Teledyne Mec
|Mass spectrometry method using filtered noise signal
|A New Mode of Operation For The Three Dimensional Quadrupole Ion Store (Quistor): The Selective Ion Reactor, Fulford et al. Int. Jour. of Mass Spectrometry & Ion Physics, 26 (1978) pp. 155 162.
|A New Mode of Operation For The Three-Dimensional Quadrupole Ion Store (Quistor): The Selective Ion Reactor,Fulford et al. Int. Jour. of Mass Spectrometry & Ion Physics, 26 (1978) pp. 155-162.
|Gas Chromatography Mass Spectrometry Applications in Micro biology, Odham et al., pp. 31 34.
|Gas Chromatography Mass Spectrometry Applications in Micro-biology,Odham et al., pp. 31-34.
|Citing Patent
|Filing date
|Publication date
|Jan 19, 1996
|Aug 5, 1997
|Bruker-Franzen Analytik Gmbh
|Method for exciting the oscillations of ions in ion traps with frequency mixtures
|Oct 6, 2000
|Apr 6, 2004
|Technische Universitaet Dresden
|Electron impact ion source
|Apr 2, 2003
|Feb 21, 2006
|The Regents Of The University Of California
|Controlled fusion in a field reversed configuration and direct energy conversion
|May 26, 2009
|Jul 5, 2011
|1St Detect Corporation
|Driving a mass spectrometer ion trap or mass filter
|Dec 8, 2008
|Dec 18, 2012
|1St Detect Corporation
|End cap voltage control of ion traps
|Oct 5, 2010
|Mar 12, 2013
|Mark E. Bier
|Mass spectrometer and method for using same
|Dec 17, 2012
|Apr 22, 2014
|1St Detect Corporation
|End cap voltage control of ion traps
|Apr 2, 2003
|Nov 20, 2003
|Monkhorst Hendrik J.
|Controlled fusion in a field reversed configuration and direct energy conversion
|May 2, 2013
|Aug 20, 2015
|Leco Corporation
|Ion Mobility Spectrometer With High Throughput
|Jun 11, 2001
|Jul 24, 2002
|Archimedes Technology Group, Inc.
|Stochastic cyclotron ion filter (SCIF)
|Jun 11, 2001
|Oct 15, 2003
|Archimedes Technology Group, Inc.
|Stochastic cyclotron ion filter (SCIF)
|Mar 12, 2003
|Oct 8, 2003
|Archimedes Technology Group, Inc.
|Band gap plasma mass filter
|U.S. Classification
|250/282, 250/292
|International Classification
|Cooperative Classification
|European Classification
|Oct 21, 1994
Owner name: BRUKER-FRANZEN ANALYTIK GMBH, GERMANY
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:FRANZEN, JOCHEN;GABLING, REEMT-HOLGER;REEL/FRAME:007376/0851
Effective date: 19940920
|Oct 18, 1999
|Fee payment
Year of fee payment: 4
|Oct 24, 2003
|Fee payment
Year of fee payment: 8
|Oct 15, 2007
|Fee payment
Year of fee payment: 12


text:
Meet Air Matters: the app alerting millions on air quality
It is the most downloaded free app in 2013 among all categories in China's App Store.
Photos: The "ofo bike graveyard" shows Chinese vandalism has reached new heights
Boom. Kudos to the repairmen.
Why Airbnb's new Chinese name is an epic fail
Some said it sounds like a copycat porn company.
Photos: What does Tim Cook dig about China startups ofo and Keep
Keep and ofo apps are popular among Chinese millennials.
The smog refugees from China
The smog has formed new words and business opportunities. Now it has even created a new living class — smog refugees.
The economy behind influencer brands in China
Online influencers in China are turning their online fame to massive fortune, creating their own brands that they market and sell online.
Why I ditched China's No. 1 fitness app "Keep" and went back to the gym
Nothing beats having a personal trainer to correct my exercise postures.
Smog in Beijing terminates the Dutch smog terminator
According to a test report, the Smog-Free Tower is not really freeing people from smog.
A leaked chat sparked a war of words between Xiaomi and LeEco and indicated a broken capital chain
LeEco and Xiaomi had a verbal fight, yet it's not clear who came out on top.
Amy aims to make their intelligent robots real helpers to humans
Amy mainly targets businesses, including hospitals and shopping malls, as well as high-end consumers globally.


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HEIGHT: 6.5 in (17 cm)
DIAMETER: 11.5 in (29 cm)
Brass, Murano Glass
Mid-century Modern
Mid 20th Century
An Italian vintage light pendant, produced by Venini, with white swirled Murano glass globe, capped in polished brass and suspended from a circular, stepped ceiling canopy. Very good condition, with age appropriate wear. Dimensions reflect height from the top of the canopy, to the bottom of the globe.
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Mid-century modern Vilhelm Lauritzen for Louis Poulsen chrome pendant lights.
A pair of vintage early 20th century pendants, each features a bell form Holophane glass shade, suspended from a 'rope' stem.
A vintage pendant light by designer Jorn Utzon in red with a white interior. Wiring and sockets to US standard. Very good condition, consistent with age and use.
A vintage mirrored light fixture with patinated metal center piece holding a socket. Up light reflects off the angled mirror tiles. Age appropriate wear; there are cracks in large and small mirrored panels
A custom pendant fixture produced during the mid-20th century, featuring eight textured Murano glass panels layered around a single tier of three sockets with faux candle covers.
French 1970s pendant light by Maison Charles, highly modern with surrounding curved chrome panels.
A c. 1970s pendant style chrome fixture with two bright red and heavily textured resin globes.
This 1960s Italian modernistic light pendant, comes with five convex panels of bright yellow, textured Murano glass, surrounding a single socket, affixed to a white enamel frame. Very good vintage condition, wear consistent with age and use; height of rod measures 12".
A hanging pendant light, circa 1960s with wide, concave saucer shade in clear Murano glass with white swirling detail, surrounding a single socket, suspended from tapered white enamel canopy. Very good vintage condition, wear consistent with age and use.
An aluminum half circle pendant light by designer Paul Mayen, Mid 20th century, c.1970's.
Modern style dome pendant, with sculptural acrylic shade designed as an ice block.
A c. 1960's French brass chandelier with four arms topped in white frosted glass shades.
A vintage space age pendant light with a white and orange enameled metal shade with brass cap and rod.
Danish Modern hanging lights by Poul Henningsen for Louis Poulsen. The PH5 was originally designed in the 1950's and today is an icon of mid century Danish Design
A 1960's lantern form pendant light with a walnut body, chrome detailing and smokey acrylic inserts. There are four candle form interior lights. This piece has age appropriate wear with some scratching to acrylic, chrome and wood. Made in the United States.
A circa 1970's dome shaped brass pendant light with chrome sockets and finial.
A vintage chandelier with three glass shades in orange, blue and frosted white suspended from a circular flush mount.
Produced in the 1960s by Venini, this egg shaped pendant is decorated with spiraling bands of brown and white.
Pale yellow iridescent glass Art Nouveau hanging lantern in bronze . Good vintage condition with age appropriate wear.
An Italian bell-shaped pendant lamp in blue and white Murano glass, c. 1960's.
A vintage chandelier with a nickeled finish and twelve crystal ball details around the rim. The piece is by noted designer Jacques Adnet.
A Vintage Fredrick Ramond Chrome and Smoked Glass Lantern or Pendant.
Midcentury Spherical Italian clear glass pendant light with white stripes.
A pair of 1960s Italian art glass hanging fixtures by Alessandro Pianon for Vistosi.
A circa 1970's Spage Age light fixture with three enameled tiered circular layers.
Modern 1960s Italian Sciolari 'Cyclone' chandelier by designer Max Sauze.
A mid 20th century eight globe chrome pendant light.
A mid-century glass pendant or lantern rendered in candy stripes of red and white designed by Massimo Vignelli, c. 1950's.
A vintage pendant form chandelier in walnut with three rings of smokey colored plexi-glass around a central white globe shade.
Produced in Italy circa 1970s, ,Armillary Style Globe Pendant light which includes a frosted glass globe surrounded by three layers of polished chrome rings.
This torch cut pendant lamp comes with its original chain and canopy.
This Victorian period lantern pendant, produced circa 1880s, features panels of stained glass, inset within an embossed brass frame, detailed with leaf motif patterns. Very good antique condition, recently rewired. Dimensions provided reflect height of body; overall height to canopy measures 33".
This hanging light pendant, produced circa 1960-1970, comes with cylindrical shade in gilt metal, with amber toned resin detailing. Wiring to US standard. Very good condition, consistent with age and use.
A vintage pendant light by designer Jorn Utzon in blue with a white interior. Wiring and sockets to US standard. Very good condition, consistent with age and use.
A pair of sea foam green glass and metal mid-century pendant lights.
Rare antique Chinese wood statue of Guayin; possibly Tang Dynasty.
Modern late 20th century pair of swivel slipper chairs, with red suede upholstery, raised on chrome pedestal bases.
An undulated globe table lamp in cobalt blue glass on wood base with brass stem, made in Denmark c. 1970's.
A vintage pair of teak side chairs with white linen seats and cane backs.
This vintage clear lucite table lamp is composed of five lucite planks circling a central chome bar on a base.
This decanter in Murano glass is a beautiful pale yellow and comes with a stopper or decanter.
A vintage 1985 abstract folk art sculpture of a red rooster or other bird. The piece is composed or iron objects and has Washington D.C. stamped on base. Signed and dated.
A vintage mixed media abstract expressionist inspired artwork titled "Tomorrow, Tomorrow, Tomorrow"by Barbara Quackenbush (1929-2012). The piece is composed of painting and collage elements. Barbara Quackenbush split time between Harrisonburg, Virginia and Fort Lauderdale, Florida. She graduated from Virginia Commonwealth University and continued her artistic training at George Washington University and the Corcoran School of Art in Washington, D.C. and exhibited locally an nationally throughout her career. She passed away in 2012.
A whimsical sculpture of brass cattails and leaves mounted on a root base. The piece is similar to works produced by Curtis Jere.
A Modernist table lamp, mid-century c. 1970s, with 3 blocks of white lacquered wood connected by chrome rods and lucite forming a classical column pattern.
Pair of 1930s bookends with highly detailed alabaster relief carved male faces.
A pair of ancient Chinese sculptures dating to the Tang Dynasty, depicting grave-quelling earth spirits known as 'zhenmushou'. Made of unglazed pottery.
A mid-20th century Bjorn Wiinblad needlepoint depicting a muscian, under glass in a brass frame.
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text:
21 April 2017, 10:01
And each release will get service and support for 18 months.
13 April 2017, 13:31
'Self Service' refunds announcement pops up in latest Xbox One Insider program alpha.
12 April 2017, 10:01
A new video shows off game streaming with Beam and Windows Game Mode in action.
6 April 2017, 10:01
And you can grab the update now via the Windows 10 Media Creation Tool.
30 March 2017, 10:01
Designed to "spark and unleash creativity, bringing 3D and mixed reality to everyone".
20 March 2017, 13:11
Cloud Imperium Games doesn't want to force users into upgrading to Windows 10.
9 March 2017, 13:21
$6.99 a month OneDrive storage deal touted in the area above your files, folders and drives.
7 March 2017, 10:01
Its more than just prioritisation, processor cores will be directly allocated to gaming.
28 February 2017, 09:31
Users can freely toggle the setting; existing Win32 apps will continue to run fine.
10 February 2017, 12:31
And Windows Insiders get to try out a compact overlay 'PiP' style window feature.


text:
26 Oct 2016 - 28 Oct 2016
The event is over
Indiana Convention Center
Indianapolis / Indiana / United States of America
Midwest Healthcare Engineering Conference & Trade Show (MWHCEC Conference) is a premier event for the healthcare industry, bringing professionals together to continue their education and check out the newest concepts and products in the industry. This 3 days healthcare industry event is being organized by Raybourn Group International (RGI). The venue of this event is Indiana Convention Center which is located in Indianapolis, Indiana, United States of America. The event will be held from 26 October 2016, Wednesday to 28 October 2016, Friday. MWHCEC Conference 2016 will showcase a wide range of products and services related to medical & pharmaceutical sectors from the leading exhibitors. The approximate number of exhibitors that will exhibit at this event is over 100. Over 600 visitors are expected at this healthcare industry event. Visitor profile of this event includes architects, biomedical & clinical engineers, building maintenance personnel, design & construction managers, facility engineers, facility managers & regional directors, healthcare building construction companies, healthcare building equipment & supply manufacturers, healthcare building product manufacturers, healthcare design engineers, healthcare facility managers & plant operations, hospital administrators. The frequency of MWHCEC Conference is annual.
Address : 100 South Capitol Avenue
City : Indianapolis, IN
Country : United States of America
Phone : +1 317-262-3400
Website : Click here for venue website
Situated in downtown Indianapolis, Indiana Convention Center is a major convention center in the nation offering over 1.300.000 square feet (120.000 square meters) of space for convention/meeting uses including over 566.000 square feet (50.000 square meters) of open exhibit space and almost 140.000 square feet (13.000 square meters) of group meeting space.
ACMA Annual Meeting & Conference
American Case Management Association Annual Meeting & Case Management Conference
ATA Annual Conference & Tradeshow
American Telemedicine Association Annual Conference & Tradeshow
ASNR Meeting
American Society of Neuroradiology Annual Meeting
ISMRM Meeting & Exhibition
International Society for Magnetic Resonance in Medicine Meeting & Exhibition
AAN Annual Meeting
American Academy of Neurology Annual Meeting
AANS Scientific Meeting
American Association of Neurological Surgeons Annual Scientific Meeting
AAOE Annual Conference
American Association of Orthopaedic Executives Annual Conference
FDIC International
Fire Department Instructor Conference & Exhibition
ASPAN National Conference
American Society of PeriAnesthesia Nurses National Conference
LeadingAge Indiana Spring Conference & Tradeshow
Raybourn Group International (RGI)
Headquartered in Indianapolis, Raybourn Group International (RGI) is one of just 15% of association management companies (AMCs) accredited by the AMC Institute.
Address: 9100 Purdue Road Suite 200
City: Indianapolis, IN
Country: United States of America
Phone: 800-362-2546
Phone: +1 317-328-4636
Fax: 317-280-8527
Email: info[at]raybourn.com
Website: Click here for organizer website
|Start Date
|26 October 2016, Wednesday
|End Date
|28 October 2016, Friday
|Medical & Pharmaceutical
|Indiana Convention Center
|Indianapolis, IN
|United States of America
|Raybourn Group International (RGI)
|Web Site
|Click for official website
|Open to
|Trade visitors


text:
Commercial Shop/office At Asangaon 405 Square Ft S...
Category : Property for sale Posted : 04/08/2015 Price : 4050000.00 INR Location : Kalyan-Dombivali(Maharashtra)
Airwil Aurum is a high standard commercial project which has been developed along Noida Expressway in Noida Sector 135. Featuring lockable office spaces along with virtual spaces for businesses starting from 200 sq. ft., Airwil Aurum commercial spaces price details are available at Airwil Aurum Price List .
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THAILAND: Town planning laws to control expansion of foreign retailers
Thailand has given the go-ahead to plans to use town planning laws to control the expansion of foreign supermarket retailers, which are forcing many smaller Thai retailers out of business. Interior Deputy Minister Pramual Rujanaseri said that current town planning laws for Bangkok and two neighbouring provinces would be expanded to the country's 73 other provinces. The regulations are likely to keep hypermarkets and superstores out of town and away from freshfood markets and groups of small family-run stores.
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4671Re: [HoustonPeakOil] Re: [hreg] What is holding back American car companies?
Expand Messages
- Aug 2, 2006I didn't hear the program, but maybe you're thinking of the Sterling engine?
--- Ariel Thomann <ajthomann@...> wrote:
> I think it was yesterday afternoon that I heard something on the radio that I can't findPetition to challenge Dwayne Bohac to give back dirty money
> now in the archives of KPFT or KUHF. I was driving, and failed to write down the key
> family surname. It was a lengthy discussion of a type of engine devised by someone from
> a long family line of tinkerers. I understood it could be either diesel or gasoline,
> compatible with hybrid systems, and supposedly far more efficient and cheaper than
> anything out there today. But, of course, suppressed by the big players. Did anybody
> else catch that program?
> Ariel
Mark McDavid for Congress - Tx Dist 138
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text: News Bed-Stuy mother facing murder charges Like Tweet Share Pin Email 0 Comments November 9, 2010 2:56 PM BROOKLYN - A Bedford-Stuyvesant mother is now facing murder charges in connection with her 4-year-old daughter's death. Carlotta Brett-Pierce has been charged with murder, manslaughter and endangering the welfare of a child. Police found her daughter, Marchella, dead in their apartment in September. The city medical examiner's office has said that Marchella Pierce died Sept. 2 of child abuse syndrome, including acute drug poisoning, blunt-impact injuries, malnutrition and dehydration. Brett-Pierce faces 25 years to life in prison if convicted. Share on Facebook Tweet on Twitter advertisement | advertise on News 12 Trending Video 1:40 1 Rangers riding 3-game winning steak into 2nd round of playoffs 3:04 2 Funeral set for FDNY firefighter killed in the line of duty 4:52 3 VIDEO: Interview with Surflight Artistic Director Steve Steiner 1:40 4 Rangers riding 3-game winning steak into 2nd round of playoffs 1:48 5 Group holds shredding event to prevent identity theft advertisement | advertise on News 12


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Experience using statistical packages for analyzing data (Excel, R, SPSS, etc). "You can't manage what you don't measure."....Read more
Pria / Wanita Jujur dan bertanggung jawab. Pendidikan S1 Berpengalaman di bidang yang sama Menguasai komputer Berdomisili di wilayah Bogor About theRead more
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Experienced to use statistical packages for analyzed data (Excel, R, SPSS, etc). Analyze fraud data and behaviour to guide development of product, services, and...Read more
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