text: Seller: dave86800 (1,134) 100%, Location: Ludlow, Ships to: GB, Item: 112192570398 Free delivery in mainland England and Wales. Please Scroll to bottom of page for Scotland A Fabulous Pair of Louis Cannes Standard Single Ex 7th Heaven Walnut Beds A Fabulous Pair of Louis Cannes Standard Single Ex 7th Heaven Walnut Beds These beds are in good condition. We purchased them privately from a couple who bought them from Seventh Heaven. Seventh Heaven were one of the biggest bed suppliers in the country many years ago. So they are of a very high quality. The beds do come with their original bases enabling you just to place your standard single mattress upon the top etc. The beds stand on lovely boards which are beautifully shaped with a lovely motif to the top. There is a lovely walnut interior. The head board is connected to the foot board with a lovely metal base which is bolted together and the base sits neatly upon the top. The foot board stands on lovely queen ann style cabriole carved legs supporting the foot board and it is similarly shaped with a carved motif to the bottom. These are in truly wonderful condition so please bid with confidence.We can get exact made to measure matresses at 3ft 6inches from Home Furnishers in Hereford starting form £89 each (takes 1-2 weeks ) The height of the head board is 148cm, the height of the foot board is 86cm, the length for the mattress is 193cm and the width is 109cm. THANK YOU FOR VIEWING OUR ITEM Our Furniture All of our furniture is in good condition and is finished to showroom standard. Please be confident when you place a bid We sell most of our furniture to Antique dealers / trade customers all over the country therefore items we have listed on eBay can be bought at any time by one of our trade customers. Due to this we do suggest that if you intend to bid on an item it is not always best to leave it until the last minute as we may have had to end the item early. Once a bid is placed on one of our items the bid stands. Delivery / Collection Information ***LIMITED PERIOD ONLY*** FREE DELIVERY ON THIS ITEM ANYWHERE IN ENGLAND & WALES (For all other destinations please email us at email@example.com or telephone 07702 345 685 for a delivery price) At D & J Hunt Antiques Ltd we do deliver all of our furniture personally therefore you can be assured and have peace of mind that your item will be delivered safely. Collections can be made from our Warehouse please contact us prior to collection to arrange a convenient collection time as we do store much of our furniture at a separate location to the collection address. Please view our feedback so you can be 100% confident when purchasing an item from D & J Hunt Antiques Ltd. We work extremely hard to ensure our standard of service is impeccable and feel our feedback truthfully reflects this. If you have any queries / questions please do email us at: email@example.com or telephone us on 07702 345 685. If for any reason you are not entirely pleased with your purchase please email us prior to leaving feedback and we will do our up most at D & J Hunt Antiques Ltd to rectify any concern that you may have with your item. D & J Hunt Antiques Ltd We accept a cheque or paypal as methods of payment. Our preferred method of payment is a cheque as we are an old fashioned business in a modern world! As we do deliver our items personally we are prepared to accept payment on delivery therefore ' you' as the customer have the added security of knowing the fact that the item and payment exchange hands at the same time. We aim to deliver within 28 days. We are prepared to store an item of furniture that you have purchased from us until it is convenient for you to have it delivered or be collected providing payment is received for the item at the end of the auction. All deliveries in England / Wales are carried out by us: D & J Hunt Antiques Ltd therefore you can be sure that your item is in the safest of hands and delivered more safely than it would have been delivered by any other courier company as you are buying directly from our company. Our only aim is for complete customer satisfaction as without this there would not be a D & J Hunt Antiques Ltd. We want all of our customers to be 110% satisfied with their purchase. It is thoroughly rewarding to have our customers email or write and inform us of how pleased they are with their purchase of furniture and even send us photos of them using their new item! Delivery To Price inclusive of packing and insurance England & Wales FREE Scotland (Below Perth) FREE - Delivery may take up to 6 weeks Ireland £95 + VAT Belgium 150 Euros - 350 Euros Extra Items 100 Euros each France 150 Euros - 350 Euros Extra Items 100 Euros each North Italy 150 Euros - 350 Euros Extra Items 100 Euros each Southern Italy 150 Euros - 350 Euros Extra Items 100 Euros each Spain 150 Euros - 350 Euros Extra Items 100 Euros each Holland 150 Euros - 350 Euros Extra Items 100 Euros each Germany 150 Euros - 350 Euros Extra Items 100 Euros each Portugal 150 Euros - 350 Euros Extra Items 100 Euros each USA/Canada Email for details Please Note If you are not entirely happy with your purchase, please contact us on 07702345685, before leaving feedback - we will be happy to help. Age: 1800-1899, Original/Reproduction: Original, Material: Walnut


text: This Month's IMJ Commentary Editorial Original Papers Case Reports Short Reports Occasional Pieces Book Reviews Research Correspondence Letters to the Editor Archive Communication skills in obstetrics: what can we learn from bereaved parents? Nuzum et al found that how the diagnosis of stillbirth was communicated has a lasting impact on parents. The language used is important. Diversionary techniques created a sense of mistrust. The authors stress the importance of sensitivity and honest open communication. CPD Infants of hypothyroid mothers – are postnatal thyroid function tests necessary? A retrospective study in a regional hospital Hawke et al undertook this study to determine whether the infants of hypothyroid mothers should have an additional follow-on thyroid function test (TFT) when the infant is 14 days old. None of the 121 infants in study had a raised TFT. The study recommends the discontinuation of follow-on TFT testing.CPD Utilising magnetic resonance imaging as the gold standard in management of suspected scaphoid fractures in the emergency department setting Ramasubbu et al state that MRI has almost 100% specificity and sensitivity in the diagnosis of scaphoid fractures. The authors outline a pathway for radiographs and MRI in the investigation of suspected scaphoid fractures.CPD IMO POLICY The 2017 IMO AGM will take place in the Radisson Blu Hotel & Spa, Galway from Wednesday 19th April to Sunday 23rd April 2017 inclusive. The Irish Medical Journal is published by the IMO with the kind support of IMO Financial Services **INSTRUCTIONS FOR AUTHORS**Submitting an article to the Irish Medical Journal? Please click the link above for guidelines Press Office Releases Irish Medical Journal Irish Medical Organisation CPD Quiz Advertising with the IMJ? Place your ad here Classifieds Abstracts Irish Paediatric Association 2016 JOGS Society

subset: commoncrawl


text:
Beaches Living
Cards, Mat
Greeting Cards: Dimensions: 5" x 7" or 5" x 6" 5/8 on professional photo quality stock for photo cards and textured,
deckle-edged with matching envelope for painting and illustrations Price: $12 for 3 cards, $20 for
6 cards plus taxes Shipping: $4 for US/Canada surface mail Customized Pack: ask us about customized
messages for orders of 18 or more Value Pack: quantity order for businesses,
ask us about value stock cards Photographs: Professional quality photograph stock Dimensions and price (plus taxes)8.5"x11" - $35 with mat, $30 no mat11"x14" - $50 with mat, $45 no mat13"x19" - $90 with mat, $80 no mat Large size posters: A series of Toronto District landmark painting printed on professional quality stock with choice of white or cream colour background Dimensions and price (plus taxes)18" x 24" with border - $40 without mat Free shipping with orders of three or more prints. NOTE: 416.690.4269 or The information in this article was current at 06 Dec 2011
Free shipping with orders of three or more prints.
NOTE: 416.690.4269 or
Email - none provided
Print this page
Create your free Hotfrog business profile
Follow Hotfrog on:
Share on:
Hotfrog Small Business Hub


text:
A training session on
Fire and Safety was arranged for faculty and Staff on December 1, 2016 with the
collaboration of Fire and Safety Department, Pakistan Ordinance Factories
(POFs) Wah Cantt. Assistant Technical Officer (ATO), Mr. Bashir Ahmad along
with his team delivered a lecture on subject and briefed audience how to
protect human lives and infrastructure in case fire or emergency situation.
During lecture, trainer informed audience about following topics in detail:
Types/classification of
Reasons of Fire
How to minimize lose
Use of fire extinguishers
Provide first aid in any
emergency situation
Team work required to
handle emergency situation
The trainers also
provided hand on practice to participants about the use of fire extinguishers
to control fire, provide first aid and to handle emergency situation.
View Photo Gallery
Signing up is easy.
Sign in..
© 2009-2017 COMSATS Institute of Information Technology, Islamabad
Park Road, Chak Shahzad, Islamabad


text:
Is Sediabena Sdn Bhd incorrect or missing key business information? Update your Hotfrog listing today.
Contact details
Are these details correct?
Is Sediabena Sdn Bhd in No. 15A, Jalan SS 25/41, Mayang Light Industrial Park, Petaling Jaya Selangor 47301 your business? Claim your listing and attract more leads by adding more content, photos and other business details.
We have more Metals services in Petaling Jaya Selangor available on Hotfrog MALAYSIA. You can update your search for Petaling Jaya Metals by location, keyword or service options.
No. 55, Jalan Pju 1/37, Dataran Prima, Petaling Jaya Selangor 47301
No. 6 & 6A, Jalan Sm/12, Taman Sri Manja, Petaling Jaya Selangor 46000
80A, Jalan Ss218/39, Damansara Utama, Petaling Jaya Selangor 47400
35A, Jalan 1/12, Petaling Jaya Selangor 46000
Small Business Hub
Sharing tips, ideas and advice to help grow your small business.
Create your free Hotfrog business profile
Follow Hotfrog on:
Share on:
Hotfrog Small Business Hub


text:
Sign up for our newsletters
Receive the latest in Footwear, Fashion, Music and Creativity in our newsletters.
High fashion and utilitarian sneaker design intersect in the recently released Missoni x Converse Chuck Taylor All-Star. The iconic profile of the Chuck Taylor is met with the signature pattern of Italian fashion house Missoni as one of the two colors for this collaboration is seen here. Available now at select retailers.
Source: 00 o 00


text:
Miami Retirement Communities
The Palace SuitesMiami, FL 33173 Independent Living, Retirement CommunitiesGet Info
Palace Suites offers up-scale independent living in the heart of Miami with a variety of studio, one- and two-bedroom luxury apartments. With amenities like a cruise ship, Palace Suites has a theater, dining rooms, arts & crafts studio, gym and a pool.
The Residences Of United HomecareMiami, FL 33196 Assisted Living, Independent Living, Retirement CommunitiesGet Info
Here at Residences of United Homecare we provide our residents family like support. We provide assistance and care and treat residents a part of our family


text:
Safeclean Abingdon
carpet cleaners, Rug Cleaning, stain removal
Safeclean provide a trustworthy, knowledgeable, friendly and guaranteed service. We have years of expertise and training offering our customers peace of mind for the cleaning of all carpets.
Call us today to arrange a free no obligation quotation.
Print this page
Safeclean have years of experience providing Allergy, Insecticide and Stain Protection Treatments.
Safeclean's mattress cleaning service includes stain removal.
Safeclean offer a unique service to cleaning your curtains where they hang, saving time, money and disruption for our clients.
Safeclean are experts in providing a clean to enhance and prolong the life of your sofa.
Create your free Hotfrog business profile
Follow Hotfrog on:
Share on:
Hotfrog Small Business Hub


text:
23 Fabulous Picnic Craft Ideas + Restaurant Copycat Recipes
Bonus: Get our newsletter & special offers for free. We will not share or sell your email address. View our Privacy Policy
Latest Comments
"The Hushabye Shell Afghan is a beautiful blanket that would be a great shower gift. The pattern is an easy shell stitch and the colts are great for a boy or girl. I am sure that it will keep baby nice and warm. It is made with a nice four ply yarn and should work up fast. This one to save for a later date."
"The wavy rainbow baby blanket is one of the cutest that I have seen. The colors are so bright that a baby will enjoy looking at it. The blanket could also be worked up in other colors that would be great for that special little one. this is not for a beginner, so if this is your first try at crocheting you may not want to try it. Looking forward to working on this."
"The Springtime Lace Afghan Pattern is so cute. It will make a great baby blanket for that special baby. This could be made in many different colors that will really be pretty. The pattern reads really easy and a beginner could do this.I am looking forward to to this project in the very near future."
"he Cape Cod Afghan is really a cute pattern. It would be a great one for beginners. The pattern only calls for two skeins of yarn. The pattern reads really easy. This could also be used as a baby blanket and would look great in one of those baby colors. This is one pattern that I will definitely save for a later project down the road."
Up-dated Gardening Tools
By: ColorArtz
We are adding the craft to your Craft Projects.
The project was added to your Craft Projects.
Click here to view your Craft Projects.
This Up-dated Gardening Tools idea is great if you've always wished you could make your own garden tools. You won't make them from scratch, but you can personalize them with these air brush tips and tricks from ColorArtz.
- ColorArtz Starter Kit
- Plain Watering Can, Planters
- Blue Painter's Masking Tape
- Newsprint
- ColorArtz Black Tie Optional Stencil Collection
- ColorArtz Bonjour Paris Stencil Collection
- Atomic ColorArtz Paint Pouch
- Purple People Eater ColorArtz Paint Pouch
- Prepare a flat work surface with a drop cloth.
- If you are new to ColorArtz practice on sample.
- Lay items flat.
- Remove stencil backing and place self-adhesive stencil into position. We recommend using stencil adhesive when using non-adhesive stencils for best results.
- Make sure stencil is fully adhered.
- Place sheets of news print overlapping the edges of the stencil and tape down with masking tape. Make sure the entire vase is fully covered and only the areas to be painted are uncovered.
- If multiple colors are desired within one stencil design, lightly mask off areas that will be sprayed a separate color using masking tape.
- Apply first color spraying light mist coats. Do not soak with paint. Be careful not to spray at an angle to avoid lifting the stencil. To reach a darker color, apply many light coats, letting dry a few minutes in between sprays.
- Let project dry.
- Remove tape masking areas to be painted with second color. Tape over the areas painted with the first color. Apply second color. Repeat steps 7 through 9 for each color.
- Hint: Additional colors can be created by overspraying colors starting with the lightest color and moving to darker colors. For example: Mango Tango over Gremlin would create brown.
- Once entire stencil is painted, move stencil to another area, and cover rest of the project with newsprint.
Your Recently Viewed Projects
Images from other crafters
Love these projects? Get MORE delivered to your Inbox – FREE Click Here!
Report Inappropriate Comment
Are you sure you would like to report this comment? It will be flagged for our moderators to take action.
Thank you for taking the time to improve the content on our site.
Something worth saving?
- SAVE all your favorite crafts
- ADD personal notes
- QUICKLY reference your crafts
Free eBooks
- 11 Crochet Shawl Patterns: Crochet Poncho Patterns, Free Easy Crochet Patterns and More
- 12 Knitted Scarf Patterns: Fabulous Free Knitting Patterns for Beginners
- 14 Free Crochet Patterns for Babies and Toddlers
- 16 Free Crochet Hat Patterns, Scarves, and Gloves
- 22 Free Crochet Patterns: Afghan Patterns, Crochet Hats, and More
- 24 Quick and Easy Knitting Patterns
- 7 Adult Coloring Pages
- 8 Free Apron Sewing Patterns
- Easy Lace Knitting Patterns
- Quick & Easy Decoupage: 12 Fabulous Mod Podge Projects for Your Home
Our Newest Projects & Articles
- 25 Recycled Crafts for Easter
- 30 Easter Egg Craft Ideas
- Pom Pom Cupcakes
- 18 Favorite Free Shawl and Poncho Knitting Patterns
- Styrofoam Easter Eggs
- St. Patrick's Day Leprechaun Bottle Toppers
- Easy Sew Pencil Pouch Tutorial
- Pajama Friendly Argyle Throw
- Diagonal Squares Knit Throw
- Two Sides Knit Dishcloth


text:
de Medici is rated 4.5 out of 5 by 604.
Rated 5 out of 5 by Suzan B from
Date published: 2017-01-20
Rated 5 out of 5 by Carla K from
Date published: 2017-01-15
Rated 5 out of 5 by Toni R from The food was delicious and the service was excellent.
Date published: 2017-01-14
Rated 3 out of 5 by Abbey K from
Date published: 2017-01-08
Rated 5 out of 5 by Edward C from
Date published: 2016-12-24
Rated 5 out of 5 by Jo A from
Date published: 2016-12-24
Rated 5 out of 5 by Christine M from
Date published: 2016-12-20
Rated 5 out of 5 by Antoinette M from Please do not ask the wait staff to bring around raw meat to show your cuts of meat. It's a real turn off. No one likes to look at raw meat right before you eat.
Date published: 2016-12-19
Rated 5 out of 5 by Rob F from
Date published: 2016-12-09
Rated 5 out of 5 by jeff q from
Date published: 2016-11-28
- y_2017, m_2, d_24, h_16
- bvseo_bulk, prod_bvrr, vn_bulk_0.0
- cp_1, bvpage1
- co_hasreviews, tv_290, tr_314
- loc_en_US, sid_23723, prod, sort_[SortEntry(order=SUBMISSION_TIME, direction=DESCENDING), SortEntry(order=RATING, direction=DESCENDING)]
- clientName_restaurantcom
Minimum purchase of $50 at restaurant.
de Medici
815 5th ave
San Diego, CA 92101
San Diego, CA 92101
Phone: (619) 702-7228
Cuisine: Italian
Price: $$$$
Do you like this restaurant?


text:
Lost Password?
We offer you this space to share your knowledge about Magento and learn from our experienced customers.
Home › Forums › Theme Forum › HelloCanvas & HelloCanvas iPhone › Change Color › Reply To: Change Color
Just FYI, I am experiencing the same with the "Proceed to Checkout" button in my install. Also, if you resize the screen the green area extends outside the border, appears that the width has been fixed, which is not ideal.
Would be interested in a patch for this screen when available.


text:
Is Limpiado MFI incorrect or missing key business information? Update your Hotfrog listing today.
Contact details
Are these details correct?
Hotfrog Philippines provides information regarding Limpiado MFI in Naval Biliran. Limpiado MFI is located at 144 Canaeja Street, Naval Biliran 6543 and provides Education services. Contact them on (053) 500 9505.
Is Limpiado MFI in 144 Canaeja Street, Naval Biliran 6543 your business? Claim your listing and attract more leads by adding more content, photos and other business details.
We have more Education services in Naval Biliran available on Hotfrog Philippines. You can update your search for Naval Education by location, keyword or service options.
Small Business Hub
Sharing tips, ideas and advice to help grow your small business.
Create your free Hotfrog business profile
Follow Hotfrog on:
Share on:
Hotfrog Small Business Hub


text:
Friends (1979)
60 minutes
Dramedy about the growing pains experiened by three suburban 11-year-olds.
All »
Previous Episodes
0 reviews
s1e5 The Case of Bad Timing
April 22, 1979
Pete's parents worry about their son's impending tonsillectomy. Billy: Philip Tanzini. Pete: Charles Aiken. Mrs. Richards: Karen Morrow. Dr. Ross: John Crawford. Richards: Andy Romano. Cabbie: Richard Yarmy. Nancy: Jill Whelan. Randy: Jarrod Johnson. Cynthia: Alicia Fleer. Summerfield: Roger Robinson. Tug: Charles Lampkin. Mrs. Summerfield: Janet MacLachlan.
Series Finale
No links available
0 reviews
Randy (Jarrod Johnson) cheats to improve his low grades; Cynthia (Alicia Fleer) sneaks out with friends her father finds objectionable. Coach: Jack Knight. Pete: Charles Aiken. Marlene: Kathy Graber. Nancy: Jill Whelan. Jay: J. Michael Terry. Richards: Andy Romano. Mrs. Richards: Karen Morrow. Summerfield: Roger Robinson. Mrs. Summerfield: Janet MacLachlan. Tug: Charles Lampkin. Miss Price: Anne Schedeen. Wilks: Dennis Redfield. Lydia: Penelope Sudrow.
No links available
Show Lists
All »
Shubham Jha added it to Dash lights
1 show
oumarou added it to Favorite Series
3 shows
2 show lists


text:
Is Lim & Lyle Associates incorrect or missing key business information? Update your Hotfrog listing today.
Contact details
Are these details correct?
Hotfrog Singapore provides information regarding Lim & Lyle Associates in Singapore. Lim & Lyle Associates is located at 150 Cecil St #10-01 Wing On Life Building, Singapore 069543 and provides Management services. Contact them on 6225 9135.
Is Lim & Lyle Associates in 150 Cecil St #10-01 Wing On Life Building, Singapore 069543 your business? Claim your listing and attract more leads by adding more content, photos and other business details.
We have more Management services in Singapore available on Hotfrog Singapore. You can update your search for Singapore Management by location, keyword or service options.
Small Business Hub
Sharing tips, ideas and advice to help grow your small business.
Create your free Hotfrog business profile
Follow Hotfrog on:
Share on:
Hotfrog Small Business Hub


text:
- Putting a sparkle on your windows, mirrors, and other surfaces shouldn't bring tears to your eyes. Our powerful, plant-based formula cleans to a streak-free shine without harsh fumes. Our non-toxic Glass and Surface cleaner is safe for glass, mirrors, stainless steel and other surfaces. (from Seventh Generation)BrandAbout Seventh Generation
Seventh Generation Glass and Surface Natural Cleaner, Free and Clear
32fl oz
Like That? You'll Love This.
- $4.19/ea($2.57/pt)
- $4.19/ea($2.57/pt)
- $4.19/ea($2.10/pt)
- $4.19/ea($2.10/pt)
- $4.19/ea($2.10/pt)
- $5.99/ea($0.20/ct)
- Seventh Generation100% Recycled Unscented 2-Ply Bathroom Tissue4ct, 300 sheets ea$4.99/ea($1.25/ct)
- $8.99/ea($2.87/pt)
- Seventh Generation100% Recycled Paper Towels, 2-Ply6ct, 140 sheets ea$13.99/ea($2.33/ct)
- $3.99/ea($2.56/pt)
- $6.29/ea($3.14/pt)
- $6.99/ea($4.48/pt)


text:
Is Kenny Gilroy Interactive incorrect or missing key business information? Update your Hotfrog listing today.
Contact details
Are these details correct?
Hotfrog SouthAfrica provides information regarding Kenny Gilroy Interactive in Sandton Gauteng. Kenny Gilroy Interactive is located at 29 Rosehaven Village, Sandton Gauteng 2010 and provides Computers services. Contact them on 011 883 0866.
Is Kenny Gilroy Interactive in 29 Rosehaven Village, Sandton Gauteng 2010 your business? Claim your listing and attract more leads by adding more content, photos and other business details.
We have more Computers services in Sandton Gauteng available on Hotfrog SouthAfrica. You can update your search for Sandton Computers by location, keyword or service options.
4th Floor Illovo Edge Corner Fricker and Harries Road Sandton Gauteng 2196
Unit B8, The Stables Business Park, 13-3rd Road, Sandton Gauteng 2065
13 KENT DOWNS Benmore Road Sandton Gauteng 2196
i. trade house 42 Andries Street North Sandton Gauteng 2196
Small Business Hub
Sharing tips, ideas and advice to help grow your small business.
Your profile without ads
Have you considered upgrading to Hotfrog AdVantage? No competitor advertising means exclusive focus on your business. You take centre stage.
Create your free Hotfrog business profile
Follow Hotfrog on:
Share on:
Hotfrog Small Business Hub


text:
Writing Contest
What do you believe is or will be a significant environmental issue in the coming years? Let us know in a newspaper opinion editorial style for a chance to win a writing workshop, cash prize, and share your ideas with a larger audience. learn more →
Environment Research Talks 2017
This year, the 3 Minute Thesis (3MT) Graduate Competition will be combined with the Fifth Annual Undergraduate Student Symposium (USS). Together, they make the Environment Research Talks! Come support your fellow students as they present their research and learning in a two-part event. learn more →
President's Faculty Lecture: Dr. Paul Kingsbury
Is the truth really out there? Join us for a fascinating lecture with Dr. Paul Kingsbury on March 15, 2017 as he investigates the paranormal investigators who study phenomena such as UFOs, ghosts and Sasquatch in the Pacific Northwest. learn more →
Kirsten Zickfeld selected as lead author in IPCC Special Report
Geography's associate professor Kirsten Zickfeld has been selected as the lead author for the Intergovernmental Panel on Climate Change. She recently co-authored a study that found warming from short-lived compounds could cause long-term consequences on the sea level even after the pollutants have been cleared. learn more →
Canada's Electric Vehicle Policy Report Card
The Sustainable Transportation Action Research Team (START) issues the Electric Vehicle Policy Report Card to evaluate how efficient Canadian provinces were in advocating for electric vehicles on the road. Six out of ten provinces received a failing grade. learn more →
Human impact on fresh water ecosystems
Jonathan Moore is the lead author of a new study about fish habitat and agricultural development.... read more
Rudy Reimer hosts APTN's Wild Archaeology at SFU
Rudy Reimer takes the Wild Archeology team through the Museum of Archaeology and Ethnology.... read more
Talking climate change
Deborah Hartford, executive director of ACT, discusses climate change with Don Shafer.... read more
Kirsten Zickfeld as lead author in IPCC report
Kirsten Zickfeld was selected as lead author for the Special Report on the 1.5 degree climate... read more


text:
Gorgeous large oval Malachite Brooch set in an ornate, open work 18K Gold frame. The Malachite stone is a deep green color and is an impressive size. The 18K Gold frame was assayed to determine its carat, is simple enough not to compete with the Malachite and ornate enough to compliment it. The overall size of the antique 18K Gold and Malachite Brooch measures 1 1/2" x 1". Dates to circa: 1900. Note this piece could easily be converted to a Pendant by a jeweler, who could for example, add two links to either side of the open-work frame and add chain to each side and a spring ring clasp. The Pendant could be made to be vertical or horizontal. Is a beautiful piece and in fine condition. Shows well in the photographs and even prettier in person! The photos were taken with and without a camera flash. Bright and dark areas are reflections while being photographed.
5 other shoppers have this item in their Cart or Wish List .
Fine Antique and Estate Pieces (Jewelry, Silver & Objects of Art)
Fine Antique & Estate Pieces - over 50 years of experience


text:
Enrollment for the 2017/2018 school year opens to current families enrolled on Tuesday, Jan. 24 at 9 am. Registration to families not currently registered opens on Tuesday, Jan. 31 @ 9 am.
Please call the Playschool office(336) 643-8120 to schedule a convenient time to visit.
The Staff at Children's Christian Playschool
When you shop at Harris Teeter, you can support the Children's Christian Playschool at the same time. Click on the picture below for more information and use our school code:
Our first annual Spaghetti Luncheon/Silent Auction will be held on Sunday, March 12 @ 12:30 pm in the Fellowship Hall. Snow date: Sunday, March 19.
We are raising funds for a new Pre-K room. Our fundraising goal is $10,000. Tickets are $10 per person, $4 per child, ages 3 and up. Under 3 are free. To purchase tickets or donate an item for our auction call (336) 643-8120 or email sumcplayschool.@gmail.com
Thank you for supporting Children's Christian Playschool!


text:
Subscribe to the Magazine!
Email UpdatesSign up to receive the newsletter from Sew News, delivered twice a month. Click here to sign up now.
The Latest Posts
- Prom Night 2017 | Find Easy To Make Clutches + FREE Bow Tie Pattern
- Appleton Dress Sew Along, Week 3: How to Hem Knits
- Appleton Dress Sew Along, Week 2: How to Sew a Knit Neckband
- Sew Happy – an interview with author Sanae Ishida (+ giveaway!)
- Sewing the Gallery Tunic
- Pretty Options for Plus + Curvy Size (And A Giveaway!)
- Appleton Dress Sew Along, Week 1: How to Cut Knits
- Weekend Sewing: The Linden Edition
- National Wear Red Day Is Today! + A Heart Healthy Giveaway!
- Perfect Fit: Bonus Info with Joi Mahon
Read From Our Archives
Monthly Archives: March 2012
7 Sources for Oilcloth Fabric
Oilcloth is one of my favorite spring fabrics, not only because of the bright and cheery prints and colors, but also because it lends itself so well to lots of springy items, like outdoor tablecloths, gardening aprons and rain-resistant totes. … Continue reading
Sew it All TV 13 Days of Giveaways – Day 10!
Another day, another Sew it All TV Giveaway! It's Day 10 and I loved reading all your stories about how you discovered SN, SIA and SIA TV from yesterday. Thanks to all of you who have been with us since … Continue reading
Posted in Uncategorized 48 Comments
Creativ Festival Design Challenge
Attention Canadian readers! We have got a special design challenge just for you! Read below and download the rules and regulations at the bottom for details on how to enter! Designer Style Challenge & Awards Canada's search for outstanding original … Continue reading
Posted in Uncategorized Comments Off
Make a cute ruffled pillow at the Original Sewing & Quilt Expo!
Next week, Ellen and I are headed to the Original Sewing & Quilt Expo in Chicago! I'll be in the Make-It Center teaching how to stitch up a fun ruffled pillow from Sew It All, Volume 3. Yesterday, I practiced by … Continue reading
Posted in Uncategorized 1 Comment
Sew it All TV 13 Days of Giveaways – Day 9!
Welcome to Monday! I hope you were ready for it. And I hope it being Day 9 of our 13 Days of Giveaways makes it a little more bearable. Yesterday we asked, "Do you use commercial patterns, draft your own … Continue reading
Posted in Uncategorized 65 Comments
Sew it All TV 13 Days of Giveaways-Day8!
Thanks to everyone for participating in Day 7 of Sew it All TV 13 Days of Giveaways to celebrate the 3rd season of Sew it All airing on PBS! Yesterday we asked, "Do you do hand embroidery?" Many of you learned hand embroidery when … Continue reading
Posted in Uncategorized 109 Comments
IKEA creates Sewing Kit with Touchscreen-Compatible Thread
What a cool idea! IKEA wanted customers to be able to view their digital catalog on-the-go, so they introduced a new sewing kit that includes conductive thread to customize your gloves or mittens to be touchscreen-compatible. That way, you can … Continue reading
Posted in Uncategorized Tagged IKEA, sewing, sewing kit, sewing thread 1 Comment


text:
Vauxhall Gardens Community Centre
5 Glasshouse Walk, SE11 5ES
Pay what you can: Sliding scale £7-£10
5-Sep-16 to 29-Nov-21
Mon, 6:15pm, 7:30pm
Affective Yoga with Kat Hymas.
Vinyasa Flow yoga classes.
All levels welcome.
"Celebrating and cherishing our physical and emotional well being".
If you have any questions please don't hesitate to get in touch at firstname.lastname@example.com or Facebook @affectiveyoga.
Times and prices are subject to change. Contact venue before setting out.
Please login first.


text:
Please refer to JobSuchmaschine in your application
Amgen is one of the world´s leading independent biotechnology companies, with global revenues in excess of $18 billion and over 18,000 employees. For more than 30 years, Amgen has pioneered biotechnology breakthroughs, to bring state-of-the-art medicines from laboratory to the patient. Amgen has not only discovered and developed innovative human therapeutics, but has invested in cutting edge manufacturing capability and support services to deliver these exciting therapies to medical teams around the world.
Role purpose
We are currently searching for a Compliance Analysis Manager for our European Headquarter in Switzerland. The role is responsible for providing management and executing on strategic direction in the development and execution of Amgen's international monitoring program which is a key element of Amgen's Compliance Program for all regions outside the US. The Compliance Analysis Manager will manage the day to day operations of international transactions monitoring program as well as the International meta Risk Assessment (ImRA) platform in addition to managing other projects within the department.
Main tasks
Lead healthcare compliance transactions monitoring operations and analytics ensuring the company maintains a state of control with respect to its interactions with the healthcare community, and is positioned to adapt to ever-changing business requirements.
Manage and enhance a robust, scalable, proactive, and forward looking transactions monitoring program, which meets or exceeds compliance requirements. This role reports to the head of Outside US Monitoring and executes in alignment with Amgen's effort to effectively globalize its healthcare compliance program internationally — specifically with respect to monitoring activities related to interactions with members of the healthcare community.
Proactively identify and communicate compliance issues and opportunities on an ongoing basis through the development and management of key indicators, trend analysis and other analytics. Work with senior management to drive improvements and increase accountability across the organization and collaborate with Healthcare compliance Policies, Training, Healthcare Compliance and Internal Audit, the Anti-corruption program, and Privacy among others
Drive international monitoring processes and initiatives through matrix leadership and management capabilities with all of the country compliance leads. Partner to achieve excellent results with multiple stakeholders including business leadership in different countries globally. This includes oversight over several systems and vendors that are critical for compliance controls.
Key Responsibilities
Executing against the overall Monitoring strategy and delivering results with key milestones
Development and maintenance of the International Monitoring Dashboards
Development of compliance Key Performance Indicators for routine compliance monitoring internationally, monitoring of trends and other analytics to proactively identify compliance risks within the organization
Developing process to identify hotspots and communicate trends to leadership accordingly through transactional monitoring
Managing process to ensure improvement actions are completed in a timely
Managing the transactional monitoring program (transactions related to Amgen Events, T&E, etc.)
Managing and executing the International meta Risk Assessment platform, the standardized risk assessment program that creates the foundation for the international healthcare compliance training, monitoring and audit programs
Required Qualifications
Doctorate degree & 2 years directly related experience OR
Master's degree & 6 years of directly related experience OR
Bachelor's degree & 8 years of directly related experience OR
Associate's degree & 10 years of directly related experience OR
High school diploma / GED & 12 years of directly related experience
Preferred Experience and Capabilities
Good written and verbal communications skills
Demonstrated ability to manage and lead virtual teams across cultures, geographies, and languages to implement change
Demonstrated matrix leadership ability across cultures, geographies, and languages to implement change is required and experience managing a team is a plus.
Demonstrated ability to work independently, deliver against critical business objectives, implement complex instructions, prioritize, be proactive, resolve conflicts, meet deadlines, follow through on assignments, and be a team player with multiple cultures, geographies and languages
Ability to independently understand, follow and implement complex instructions. Experience with an emphasis on regulatory, financial legal, or compliance processes and requirements
Experience in management and development of processes related to policy implementation, and experience with management of business operations within the parameters of non-US healthcare laws and regulations
Knowledge of the global healthcare industry and the laws and regulations relating to the development, approval, and commercialization of biotechnology/pharmaceutical products
Ability to travel and relocate international is preferred.


text:
Care Available 24 Hours a Day, 7 Days a Week.
Dear Peter, I want to let you know how much I appreciate office staff, home health aides, you. First, there is Jo. She is a real dear and very competent, effective in doing her job. . She's been very helpful to us, assisting with care plan update, checking in with us on caregivers and Roger's needs. When I have to call on a weekend, or you have to call me, I think about how hard your work is because of the 24/7 responsibility. I sincerely appreciate all your help.
Written by: Flossie P
We have been in business for over 12 years in Northampton and
over 90% of our clients need some dementia care. Our caregivers are taught to look for signs
that may make safety in the home an issue. For instance, not turning off the stove, loose rugs on the floor, no
mats in tubs, and no grab bars in the shower or tub.
As our clients' cognition decreases, then we need to be
aware of slips, trips and falls. Their
sense of balance decreases as the dementia increases. We also need to be aware of our clients' who
"sundown" or have a tendency to wander outside. Our caregivers are trained on
the different stages, thus their interactions with the client must be
Homewatch CareGivers® is a trademark owned by Homewatch International, Inc.™ and licensed for use to independently-owned franchised businesses that offer caregiver services to the public. All personal services, elderly care, caregiving and home care services offered OR provided under the Homewatch CareGivers™ mark are offered and provided only by independently-owned franchises and, where required, licensed OR registered businesses and care agencies.


text:
Prepac Coal Harbor Collection Full Mates Black Platform Storage Bed with 6 Drawers
Full Size (54")
Description & Features+
Expand the storage potential of your bedroom with the Coal Harbor Full Mate's Platform Storage Bed with 6 Drawers. Use the six 18" deep drawers (three on each side) included in this mate's bed to stow away blankets, linens and anything else that won't quite fit into your other bedroom furniture, and conserve floor space while you're at it. You won't need a box spring, either, thanks to the slat support system that requires only a mattress. As a final touch, the footboard's angular shape echoes the detail seen in the other members of the Coal Harbor Bedroom Collection, making it easy to unify your bedroom's style.
- Assembled dimensions: 76½" L x 57" W x 18" H
- Suitable for full-sized mattresses
- Sturdy drawers with solid wood sides glide on metal runners with built-in safety stops
- Finger pulls at the bottom of each drawer front for easy opening
- Wood slats positioned length-wise distribute body weight evenly to ensure a good night's sleep
- Internal drawer dimensions: 21½" W x 18" D x 5" H
- Assembly required
- Instruction booklet is included for easy assembly
Featured Products
5-year manufacturer's limited warranty on parts
Store Availability+
From the Manufacturer +
Sponsored Products


text: The prices her are on the high side for Malaysia but the quality of food, excellence of service and location on the beach at sunset make it value for money in European terms. The food was very tasty and beautifully presented. We had soft shell crab to start and then the rock lobster risotto and the "pallet" of Malaysian dishes... More


text:
Cyclocross Nationals Rolling Along in Hartford
The USA Cycling Cyclocross National Championships are taking place this week in Hartford's Riverside Park alongside the Connecticut River.
What the heck is cyclocross?
These off-road bicycle races feature hills, mud, and other obstacles. For as much rolling as you might see, there's also awkward tipping over, tripping, and sliding. Bitter cold does not cancel the races. Rain and snow doesn't either.
Thursdays track conditions included hard ruts resulting from frozen mud. Crashing on that does not tickle. (more…)


text:
Townsville Computer Man
Suburban Australia the managing body of Townsville Computer Man press release.
Suburban Australia have recently invested in a locally hosted IP PBX designed to allow us to serve our clients more effectively.
The IP PBX phone system has been configured to route calls from our 1300 number directly to our operators who can than support our clients sources from both Townsville Computer Man (TCM) and GYMP Media (GM).
Director of SA, Nicholas O'Sullivan said the solution is easy and simple and will be effective.
"The new IP PBX phone system is easy to use and will allow Suburban Australia to achieve our sales targets," said Mr O'Sullivan.
"The system will allow clients to select the service they require, once the area is chosen by using the phone dial pad your call will be routed to either TCM or GM."
The new IP PBX phone solution will ensure Suburban Australia continues to achieve our mission.
Print this page
The new website has been customized to make booking in your next computer repair, "Fast & Friendly."
Create your free Hotfrog business profile
Follow Hotfrog on:
Share on:
Hotfrog Small Business Hub


text:
Big Chief Removals
Removals, Furniture Removals, Moving House
Big Chief Removals is a Sydney based furniture removals company. With Customer care our priority, we are able to give you the type of move that you want. Priding ourselves in a top quality, professional service at an affordable price. Residential Moves is our most common service. All types of furniture moves from small straight forward moves to large complex moves, with everything in between.
Print this page
We have the knowledge and experience to move your valuable possessions safely, with correct equipment and materials. Big Chief removals
To deal with different jobs, we have various size trucks, all fully equipped with the latest equipment and materials to protect your furniture.
Create your free Hotfrog business profile
Follow Hotfrog on:
Share on:
Hotfrog Small Business Hub


text:
You missed it This great deal for Great River Fishing Adventures is over. But don't despair, we've got more great deals every day.
Related Deals That You May Like
Sunset Ranch Golf & Country Club
9 Holes of Golf, Cart Rental, and Clubhouse Credit
Fraser ValleyC$119C$79
1 or 3 Months of Unlimited Boot Camp Classes
Fraser ValleyC$155C$29.99
Shimmy for the Soul
5 or 10 Belly Dancing Classes
Fraser ValleyC$75C$36.99
Pampered Pets and Care
Sedation-Free Teeth Cleaning for Cat or Dog
Fraser ValleyC$300C$149
back by popular demand:
Great River Fishing Adventures
Sturgeon or Salmon Fishing Trip for Two or Four
- Save 60%
- 14 purchased
100% recommendedin LivingSocial customer ratings
With this time-tested team of expert fishing guides at the helm, your next trip down the Fraser River -- one of the world's top sport-fishing destinations -- may just land the big one:
• $199 ($500 value) for a sturgeon fishing trip for two
• $389 ($1,000 value) for a sturgeon fishing trip for up to four
• $199 ($500 value) for a salmon fishing trip for two
• $389 ($1,000 value) for a salmon fishing trip for up to four
What to Expect
The pros at Great River Fishing Adventures explore the mighty Fraser and many of its tributaries on the hunt for a great catch and even better experience. Trips are tailored to fit your unique needs and preferences. For a preview of what you could catch on a guided tour, check out their Pinterest boards.
PAID AND PROMOTIONAL VALUES EXPIRES ON October 16, 2014


text:
David Savona
A Cigar Smoker's Bucket List
Smoking cigars is a rewarding hobby, one that has given me immense amounts of pleasure. I know many of you feel the same way. The other day, over a cigar, I was thinking about certain experiences that take cigar smoking to an even higher level, things that I hope many of you have already done....or will do soon. With that in mind, I present this Cigar Smoker's Bucket List.
New Year, New Resolutions
New Year's resolutions. Most of us make them. Some of us keep them. Many break them. Whatever the final outcome, there's something about seeing January on a calendar that inspires people to change the way they do things.
As I sit here typing, my morning coffee to my right, lit cigar smoldering in the ashtray, I'm thinking about what's to come in 2017. Here are a few of my resolutions:
Smoking An "A"
I love "As," and I'm not talking ABCs. I'm talking about the massive cigars that take a long, long time to smoke.
In the world of Cuban cigars, where sizes are quite specific, the "A" is a gran corona, a cigar measuring 9 1/4 inches with a 47 ring gauge. In the non-Cuban cigar world, "As" can be a little longer, shorter or fatter. What they all share in common is considerable length with relatively slim girth; cigars the width of Churchills that are about two inches longer. They're built for the patient, and they can be absolutely delicious.
A Dinner For Carlos Fuente Sr.
Last Friday night in New York City, at the Grand Havana Room. The lounge area had been transformed into dinner space, a podium brought to the front. The gathering was a special one, an event to raise funds for the Cigar Family Charitable Foundation, and this year it was done in honor of Carlos Fuente Sr., who died in August.
A New Day For Cuban Cigars
The rules have finally been changed on Cuban cigars. The longtime "forbidden fruit" of the cigar industry just became much easier to legally obtain.
New Products Galore
On Sunday I fly out to Las Vegas with the editorial team from Cigar Aficionado to attend the annual IPCPR trade show. It's trade show No. 22 for me, which is hard to believe, and I'm looking forward to it as always. I haven't missed one yet.
Twenty Years of Club Mac
The scene: a luxurious cigar bar in New York City. The year: 1996. A young editor with a head full of black hair is smoking a 50 ring gauge cigar.
Flash forward 20 years. The editor is standing in the same spot. His black hair is now salt-and-pepper. The cigar in his hand, a 60 ring gauge behemoth with a flat head and an ultra-black wrapper, is familiar to modern-day cigar lovers but would have looked entirely alien back in 1996. The cigar bar? Precisely the same as it was two decades ago.
No Smoking Comes To Cuba
I picked up the phone in my hotel and pressed zero. A pleasant voice answered.
"Hola. Necesito un cenicero, por favor," I said. I was looking for an ashtray. My room in the Meliá Cohiba didn't have one.
"No cenicero, señor," came the voice, before switching effortlessly to English. My poor Spanish had betrayed me. "There is no smoking in the rooms here."
Cohiba's Night
The cigars were plentiful and powerful, the rum was exquisite and the crowd was bigger than ever for the final night of Cuba's Habanos Festival.
Well over 1,200 people filed into the vast room on Friday night, each of them handed a new Cohiba Medio Siglo cigar (short as a Siglo I, fat as a Siglo VI) and a goodie bag brimming with Cohiba memorabilia, accessories and cigars.
Twenty Years Of Cuba's Cuaba
By now you know that Cuba is celebrating the 50th anniversary of its grand Cohiba brand. We have a feature story in the new Cigar Aficionado all about Cohiba, there are videos on our site about Cohiba, and here in Havana the Habanos Festival is geared around the storied cigar. But there is another anniversary taking place here as well.
Ratings & Reviews
Search our database of more than 17,000 cigar tasting notes by score, brand, country, size, price range, year, wrapper and more, plus add your favorites to your Personal Humidor.


text:
The Leading eBooks Store Online
3,794,961 members ⚫ 1,236,034 ebooks
New to eBooks.com?Learn more
- Bestsellers - This Week
- Foreign Language Study
- Pets
- Bestsellers - Last 6 months
- Games
- Philosophy
- Archaeology
- Gardening
- Photography
- Architecture
- Graphic Books
- Poetry
- Art
- Health & Fitness
- Political Science
- Biography & Autobiography
- History
- Psychology & Psychiatry
- Body Mind & Spirit
- House & Home
- Reference
- Business & Economics
- Humor
- Religion
- Children's & Young Adult Fiction
- Juvenile Nonfiction
- Romance
- Computers
- Language Arts & Disciplines
- Science
- Crafts & Hobbies
- Law
- Science Fiction
- Current Events
- Literary Collections
- Self-Help
- Drama
- Literary Criticism
- Sex
- Education
- Literary Fiction
- Social Science
- The Environment
- Mathematics
- Sports & Recreation
- Family & Relationships
- Media
- Study Aids
- Fantasy
- Medical
- Technology
- Fiction
- Music
- Transportation
- Folklore & Mythology
- Nature
- Travel
- Food and Wine
- Performing Arts
- True Crime
- Foreign Language Books
Most popular at the top
Troubleshooting and Problem-Solving in the IVF LaboratoryCambridge University Press 2015; US$ 60.00
Helping IVF laboratories and clinics to maintain the highest success rates possible, this is essential reading for every IVF laboratory. more...
Basic Practical Skills in Obstetrics and GynaecologyRoyal College of Obstetricians and Gynaecologists (RCOG) 2010; US$ 84.00
This course manual for the RCOG Basic Practical Skills in Obstetrics and Gynaecology introduces trainees to building safe surgical and obstetric skills. more...
SBAs and EMQs for the MRCOG Part 2OUP Oxford 2015; US$ 48.99
Specifically designed for the MRCOG exam part 2, this book will help candidates prepare for the newly adapted exam. more...
Female PubertySpringer New York 2014; US$ 126.83
Female Puberty: A Comprehensive Guide for Clinicians is a practical reference, covering the full range of issues related to pubertal development. Developed to answer pointed clinical questions and to provide a thorough review of the literature, the book covers both the basics and the complexities of puberty, encompassing psychosocial development to... more...
Proactive Support of LaborCambridge University Press 2009; US$ 72.00
Enhances professional labor and delivery skills by providing the expertise and step-by-step guidance for preventing prolonged labor. more...
Psychoonkologische Betreuung in der Gyn�kologieDe Gruyter 2010; US$ 36.94
The oncological and psychological care of women cancer patients is part of the day-to-day work of a gynecologist. In practice, the gynecologist must be able to give competent answers to questions about the diagnosis and treatment of gynecological tumors. In addition, the gynecologist must show empathy and sensitivity when dealing with... more...
Langzyklus und Langzeiteinnahme mit OCDe Gruyter 2010; US$ 36.94
Many women would like to either partly or completely dispense with their monthly menstruation and its accompanying attributes. Taking oral hormonal contraceptives (OC) is possible. However, currently no OC preparation is authorized specifically for this indication in Germany. In their daily work, gynecologists are often confronted with... more...
Obstetric Anesthesia HandbookSpringer New York 2010; US$ 56.01
The fifth edition of this essential handbook retains its useful illustrations and tables, but has been reorganized for ease of use and fully updated. As well as new chapters, it includes an appendix with the latest national guidelines for obstetric anesthesia. more...
125 Jahre Deutsche Gesellschaft f�r Gyn�kologie und GeburtshilfeSpringer Berlin Heidelberg 2011; US$ 2.65
Die Deutsche Gesellschaft f�r Gyn�kologie und Geburtshilfe, gegr�ndet 1885 in Stra�burg, begeht im Jahr 2010 ihr 125-j�hriges Jubil�um. Der Band, herausgegeben vom gegenw�rtigen Pr�sidenten, zeichnet den Weg des Wissens im Wandel der Zeit nach und benennt die Werte, die sich als best�ndig erwiesen haben. Die Beitr�ge wurden von ausgewiesenen Kennern... more...
Obstetric AnesthesiaOxford University Press 2011; US$ 64.99
Obstetric Anesthesia is an ideal introduction to the specialty as well as an essential daily guide for obstetric patient care and management. more...


text:
Birmingham City 0 Everton 1
DISAPPOINTMENT: OPPORTUNITY IN disguise. Losing Wayne Rooney: an invitation for lesser lights to step up to the plate and shine. Those who cast gloom over Everton's elevated position in the Premiership need only to look back two years to when David Moyes, their manager, led them to seventh place in his first full season in charge. Last year, as the distracting hyperbole over Rooney matched his mercurial contribution, was more of a blip than this heady rise to third place.
Take Thomas Gravesen, their match-winner at St Andrew's. Would he have been granted the attacking licence he and Tim Cahill


text:
Chapter 10. Step-Reaction and Ring-Opening Polymerization
- Darrell Harrison
- 1 years ago
- Views:
1 Chater 0. Ste-Reactin and Ring-ening Plymerizatin 0.. Ste-Reactin Plymerizatin - Kinetics Ste-Reactin Plymerizatin. Difunctinal mnmers Linear lymers B tye, and BB. Plyfunctinal mnmers Functinality > etwrk lymers 3. Plymers retain their functinality as end grus at the cmletin f lymerizatin 4. Single reactin (cf. initiatin, ragatin,and terminatin in chain-reactin lymerizatin)
2 5. M.W. increases slwly Carthers equatin DP extent f reactin 6. High-yield reactins and an exact stichimetric balance are necessary t btain high-m-w linear lymer 7. Frmatin f cyclic byrduct HCH CH H H + - H CH CH,4-dixane lyether majr H CH CH CH CH - H H HCH CH CH C lactam yln 4 majr
5 Kinetics f Ste-Grwth Plymerizatin Flry s assumtin The reactivity f a functinal gru is indeendent f the length f the chain t which it is attached. Examle: dibasic acid + glycl lyester ssumtin. The reactivity f a functinal gru is unaffected by reactins f ther functinal grus in the mlecule
7 The rbability f chemical reactin with the increase f the MW: The rate f mlecular diffusin decreases, i.e., larger time intervals between encunters (fewer encunters f functinal grus er unit time) Greater duratin f each encunter (a larger number f cllisins f functinal grus er encunter)
8 Kinetics. Catalyzed [cat]k k [cat] is unchanged If lymerizatin reactin is first rder w.r.t. each functinal gru ( & B) Plymerizatin rate d[ ] k[ ][ B] [ ] ( ) [ ] dt kt If [] [B] [ ] DP d k[ ] [ ] [ ] dt r By integratin DP [ ] kt + kt [ ] [ ] DP t [ ] [ ] k DP [ ] If k is knwn, time can be calculated. kt
9 . Uncatalyzed (self-catalyzed) HC - CH + H H lymer Carbxylic acid: rle f catalyst [ ] d dt k [ ] [ B] ssume [] [B] [ ] d dt Integratin k[ ] 3 [ ] [ ] kt [] [] ( - ) [ ] ( ) [ ] ( ) DP [ ] kt + kt [ ] + kt M.W. increases mre gradually than when acid catalyst is added.
10 Catayzed [ ] kt DP + DP Uncatayzed DP kt [ ] + t
11 0.3 Stichimetric Imbalance Three ways t limit M.W. in ste lymerizatin. T quench the lymerizatin reactin by raid cling when the desired M.W. is attained.. T use an excess f ne mnmer. 3. T use small amunts f mnfunctinal reactant
12 Stichimetric imbalance factr B r where initial # f functinal grus B initial # f B functinal grus By cnventin r reactin extent f ( - ) ( ) ( ) r r r B B # f mlecular chains at ( ) ( ) ( ) r r r B B B B B r cf.
13 # mnmers ( ) B + Since B r + + r r r verage degree f lymerizatin r r r r r r DP If r If DP r r DP +
14 If mnfunctinal reagent is added Imbalance factr r' B B' where B # f mnfunctinal B grus Factr : each B mlecule is equally as effective as ne excess BB mnmer in limiting the M.W.
15 0.4 M.W. Distributin # f ttal mlecules at # f x-mers x M - (M) x- -M - where extent f reactin rbability f reactin n x x x rbability f finding an unreacted gru x x ( ) initial # f mnmers x ( ) n x mle fractin f x-mers x ( )
16 0.99 Mnmer: the mst abundant secies Wt fractin f x-mers x M x w x M x x cf. x x ( ) where M mass f reeating unit Wt fractin distributin w x x ( ) x The mst abundant secies dw dx x x ( ) + ( ) x ( ) ( + xln) 0 x x ln x ln
17 ( ) ( ) ( ) M M x M xm n M n M x x x x n ( ) x x x cf. ( ) 3 x x x + ( ) ( ) ( ) ( ) M M x M xm w M w M 3 x x x x w + + Plydisersity index cf. M M n w + M M n w s,
18 Fig 0. Mle fractin distributin in linear ste-reactin lymerizatin n x
19 Fig 0. Weight fractin distributin in linear ste-reactin lymerizatin w x
21 0.5 etwrk Ste Plymerizatin Equimlar mixture HC CH CH HCH CH H H HCH CHCH H Functinality verage functinality f av. 5 4 initial # f mnmers # f mlecules at # f functinal grus reacted ( ) Initial # f functinal grus f av
22 ( ) f av f av f av f av DPf av cf. DP t gel int av DP c Critical extent f reactin f If f av.5, c 80% (cf: difunctinal mnmers : DP 5) If mixture 3 ml f, ml f 4 ( 3 ) + ( 3) f av 5.4 c.4 83%
23 f - B - B # f mlecules B C f f B f C f > Functinality Imbalance factr B C C B B C C f f f f r + + C C C C C C C C f f f f f + + ρ extent f reactin fr B extent f reactin fr B rp
24 f- [B B ] i B B f- ( B ( - ρ) ) i B ρ (r ( - ρ) ) i rρ Branching rbability rbability that a functinal gru n a branch unit leads t anther branch unit α i 0 [ ( ) ] i r ρ rρ r rρ ( ρ)
25 3 Trifunctinally branched netwrk lymer i th envele Y i branch ints n the i th envele # f branch ints n (i + ) th envele Y i + Y i α Criterin fr gelatin Y i + > Y i Y i α > Y i α c generally that is α c α > f
26 α c critical branching rbability f f r rρ c ( ρ) c r ( - ρ) c (f - ) r ρ c (r r ρ + f r ρ r ρ) c c [ r + ( f ) rρ] If r If ρ If r ρ c [ + ( f ) ρ] - ll f c [( f ) r] c ( f )
27 HC CH CH H + CH H gelatin t c CH H α c c 0.58 Theretcal (statistical) α ( 3 ) c f c c Carthers equatin (nnstatistical) ( 3 ) + ( 3) f av 5 av.4 c c 83% f.4 Exerimental values f c fall between the values calculated by statistical and nnstatistical methds. Deviatin frm statistical methd () Intramlecular branching reactins leading t wasted ls () Differing reactivities f the functinal grus Reactivity f secndary alchl < Reactivity f rimary alchl In glycerl
29 0.6 Ste-Reactin Clymerizatin HC CH HC CH HCH CH H BB CC : BB : CC : : Randm clymer + CC CC - - CC BB - (CC - CC BB) - lternating clymer
30 Ste lymers : true telechelic lymers H lyether H + C lyurethane C Cl lyether C lyurethane C H H (B) multiblck clymer C lyester C Cl + H lyamide H C lyester C H lyamide H H lyether H + C lyurethane C H lyether C H lyurethane H C B triblck clymer lyether H
31 0.7 Ste Plymerizatin Techniques ) Bulk lymerizatin Free f cntaminants Disadvantage: high viscsity; elevated tem fr effective stirring and remval f byrducts High vacuum t remve byrducts ) Slvent lymerizatin Lw viscsity Remval f byrduct by azetric distillatin Remval f water in situ by use f effective dehydrating agent ecessity f remving slvent
32 3) Interfacial lymerizatin Slutins f tw mnmers in searate, immiscible slvents (ne usually water) Plymer is frmed at the interface e.g., Schtten Baumann synthesis nyln re trick Raid stirring t maximize the interfacial area increases the yield f lymer Characteristics f interfacial lymerizatin () Reactin ges raidly at lw tem. () Reactin is s raid, diffusin f mnmer t the interface is rate determining (3) Mnmer reacts with the grwing chains at the interface mre raidly than it diffuses thrugh the lymer film t initiate new chains; hence M.W.s tend t be significantly higher. (4) n exact stichimetric balance is nt necessary.
33 Interfacial lymerizatin: the nyln re trick
34 4) Phase-transfer catalysis (PTC) queus hase and rganic hase Catalyst: quarternary ammnium salt Functin by transrting a nuclehilic mnmer frm the aqueus hase t rganic hase, where its nuclehilicity is greatly enhanced because f reduced slvatin effects rganic hase aqueus hase rganic hase ClH C CH Cl + C CH CC(CH 3 ) 3 PhCH + (C H 5 ) 3 Cl - ah, H / benzene CH CH C C CC(CH 3 ) 3 rganic hase
35 queus hase Q + X - + M + Y - Q + Y - + M + X - Interface rganic hase [Q +, X - ] + R-Y [Q +, Y - ] + R-X Q + PhCH + (C H 5 ) 3 X - Cl - - M + a + Y - CCHCC(CH 3 ) 3 R-X ClH C CH Cl Q + R 4 +, R 4 P + Quarternary nium salt selected due t its high slubility in the rganic hase Q + transfers anin Y - int the rganic hase as [Q +, Y - ], which then react with an alkyl halide RX t give the substitutin rduct R-Y The rduced Q + X - is raidly recnverted int Q + Y - by anin exchange with nuclehile M + Y - frm the aqueus hase.
36 0.8 Dendritic Plymers Ptential alicatins: drug delivery systems, cntrlled release f agricultural chemicals, mlecular sensrs, rhelgy mdifiers Characteristic features f dendrimers. Three cmnent arts: a central cre, an interir dendritic structure, and an exterir surface. Macrmlecular dimensins are easily cntrlled by a reetitive sequence f synthetic stes. 3. Mre sluble than linear lymers High surface functinality 4. Lack f chain entanglement Lw viscsity 5. Suramlecular assemblies by incrrating guest mlecules amng the interir branches f the dendrimer.
37 Tw araches t cnstruct dendrimers. Divergent synthesis Branch ints are cnstructed in a stewise fashin frm a central cre.. Cnvergent synthesis Branch segments are cnstructed searately and then jined t a multifunctinal cre.
38 Divergent synthesis Plyamidamine (PMM) dendrimers H CH CH CCH 3 (CH CH CCH 3 ) 3 H CH CH H (CH CH CHCH CH H ) 3 H H H H H H H H H H H H H H H H H H H 0th generatin H H # f surface functinal grus 3 x Surface area: 00 times
39 Cnvergent synthesis Br + H H H base H. CBr 4, PPh 3. H H base H H
40 Scheme 0.3 Cnvergent synthesis f a dendrimer frm dendritic segments.
41 Hyerbranched lymers Mre randm architectures and d nt emanate frm a central cre. Synthesized frm B x functinal mnmers Plymerizatin ccurs via dendritic branching with n ssibility f crsslinking
43 Ring-ening Plymerizatin Mechanisms. Mnmer is attacked by inic r crdinatin secies (X*) Ring ening ex X* G G G X G* X G G*... R - CH CH CH CH RCH CH - RCH CH CH CH - CH CH. Mnmer is attacked by X* Crdinatin secies Secnd mnmer Ring ening... G X* G G G* X G* G X G* G ex CH CH H H CH CH CH CH HCH CH CH CH CH CH...
44 Reactivity frm ring strain 3 > 4 > 8 > 7 > 5 > 6 6-membered cyclic esters (lactnes) lyesters 6-membered cyclic amides (lactams) X lyamides 5-membered cyclic esters (lactnes) X lyesters 5-membered cyclic amides (lactams) lyamides Cyclic ethers Reactivity 3 > 4 > 8 > 7 > 5 > 6 X lyether
45 Plyesters Plyamides Ring-ening Plymerizatin f -Carbxy nhydrides The rduct lymer is a ly(amin acid) r lyetide r synthetic rtein. This articular reactin is ntewrthy because it is a chain reactin that ccurs with exulsin f a small mlecule (C ). Such reactins are very rare.
46 Silicnes Plyhshazenes n examle f an lymer with an inrganic backbne that can als be made by ste lymerizatin. n examle f a cmletely inrganic lymer that can be functinalized with rganic grus after lymerizatin.
Experiment 1: Freezing Point Depression
Experiment 1: Freezing Pint Depressin Purpse: The purpse f this lab is t experimentally determine the freezing pint f tw slutins and cmpare the effect f slute type and cncentratin fr each slutin. Intrductin:More information
10.569 Synthesis of Polymers Prof. Paula Hammond Lecture 14: Processing Approaches: Emulsion Polymerization Processes
10.569 Synthesis f Plymers Prf. Paula Hammnd Lecture 14: Prcessing Appraches: Emulsin Plymerizatin Prcesses Trmsdrff Effect (r Aut-acceleratin) Aut-acceleratin usually ccurs in radical chain plymerizatinsMore information
VAPOUR PRESSURE. Ranges of Vapour Pressures for some Important Classes of Organic Compounds at 25 o C
VAPOUR PRESSURE The r pressure (P ) is the pressure f the r f a cmpund in equilibrium with its pure cndensed phase (slid r liquid). Vapur pressures depend strngly n the temperature and vary widely withMore information
Kinetic Molecular Theory of Gases/Ideal Gases. Kinetic Molecular Theory of Gases/Ideal Gases. Kinetic Molecular Theory of Gases/Ideal Gases
CHEMISTRY 000 Tpic #: Intermlecular Frces What Attracts Mlecules t Each ther? Spring 009 Prf. René Beré Kinetic Mlecular Thery f Gases/Ideal Gases In an ideal gas : The distance between gas particles (atmsMore information
Chem 1101. Hydrogen bonds. Highlights of last lecture. Only F, O, and N? Drawing H-bonds. A/Prof Sébastien Perrier
Chem 1101 A/Prf Sébastien Perrier Rm: 351 Phne: 9351-3366 Email: firstname.lastname@example.com Unless therwise stated, all images in this file have been reprduced frm: Blackman, Bttle, Schmid, Mcerin andMore information
Brannon-Peppas theory of swelling in ionic hydrogels
BEH.46/3.96J Mlecular Principles f Bimaterials Spring 3 Brannn-Peppas thery f swelling in inic hydrgels Original thery fr elastic netwrks develped by Flry and Mehrer 1-3, refined fr treatment f inic hydrgelsMore information
Lecture 3: 09.14.05 The first law of thermodynamics
3.012 Fundamentals f Materials Science Fall 2005 Lecture 3: 09.14.05 The first law f thermdynamics Tday: LAST TIME...2 WORK AND HEAT CHANGE THE INTERNAL ENERGY OF A SYSTEM...3 The first law: cnservatinMore information
The Gibbs Free Energy and Cell Voltage
The Gibbs Free Energy and Cell Vltage When an amunt f charge, Q, mves thrugh a ptential difference, E w = - Q E b/c wrk dne by the system E > 0 fr galvanic (vltaic) cells Recall, G = H TS = E + PV TS FrMore information
Multiple Choice (10 points each) Identify the letter of the choice that best completes the statement or answers the question.
General Chemistry II Exam 1 (175 pints) (Answer Key) 1A Name Multiple Chice (10 pints each) Identify the letter f the chice that best cmpletes the statement r answers the questin. E 1. Fr a certain prcessMore information
Carbonyl Fundamentals
Cmpund Structure Carbnyl Fundamentals (All infrmatin and examples brrwed frm Chem. 14D Thinkbk fr Fall 2006, Dr. Hardinger s Lecture Recrdings and Paula Yurkanis Bruce s Organic Chemistry 4 th editin,More information
CHAPTER 12 Page 1. Terms describing how liquids mix miscible: substances that are soluble in each other in any proportion.
CHAPTER 12 Page 1 Slutins A slutin is a hmgeneus mixture The cmpnents f a slutin are: slute: substance (r substances) present in lesser amunt being disslved slvent: substance present in greater amunt dingMore information
Chapter 3 The Study of Hair
Chapter 3 The Study f Hair Vcabulary: Class evidence: Cmparisn micrscpe: a cmpund micrscpe that allws the side-by-side cmparisn f samples, such as f hair r fibers Crtex: Cuticle: Hair fllicle: the activelyMore information
Gak Polymers. Grade Level: 8 th
Gak Plymers Grade Level: 8 th This is a micr lessn designed t last ne 30 minute class perid (with an additinal 15 minutes fr English t Chinese translatin and questins frm the audience). Science/MathematicsMore information
Identify Major Server Hardware Components
98-365 Windws Server Administratin Fundamentals Identify Majr Server Hardware Cmpnents 98-365 Windws Server Administratin Fundamentals Lessn Overview In this lessn, yu will learn: Server frm factrs ServerMore information
Electrochemical cells
Electrchemical cells In this chapter, we turn ur attentin t electrn transfer reactins. T identify an electrn transfer reactins, we must assign xidatin states review rules in Chapter 3. e.g. Zn(s) Cu(NOMore information
3. Prior Distribution
004 Reactin Dynamics, (c) A. Miyshi 3 3. Prir Distributin - statistically equal distributin in final states 3. Rtatinal distributin and rtatinal sum Phtdissciatin f HCN at 5 nm (465 cm ): HCN + hν (465More information
Chemical Equilibrium. Chemical Equilibrium
Chemical Equilibrium Simplificatins/assumptins we've been wrking under: 1. s g t cmpletin ("") 2. Only the frward reactin is invlved 3. s stp when cmpleted Nne f these things are strictly true! What haveMore information
Fundamentals of Electrochemistry CHEM*7234 CHEM 720 Assignment #1 ANSWERS. [ Ag + Ê Á = 1.203 -
Fundamentals f Electrchemistry CHEM*7234 CHEM 720 Assignment #1 ANSWERS 1. (a Ande Reactin Cd Æ Cd 2 2e Cathde Reactin Ag e Æ Ag E = 0.403 V E = 0.800 V Overall Reactin: Cd 2Ag Æ Cd 2 2Ag One apprach isMore information
Chapter 3: Cluster Analysis
Chapter 3: Cluster Analysis 3.1 Basic Cncepts f Clustering 3.1.1 Cluster Analysis 3.1. Clustering Categries 3. Partitining Methds 3..1 The principle 3.. K-Means Methd 3..3 K-Medids Methd 3..4 CLARA 3..5More information
Marketing Consultancy Division (MCD) Export Consultancy Unit (ECU) Export in Focus. Export Market Expansion Strategies. Rabi-I, 1427 (April, 2006)
Marketing Cnsultancy Divisin (MCD) Exprt Cnsultancy Unit (ECU) Exprt in Fcus Exprt Market Expansin Strategies Rabi-I, 1427 (April, 2006) 1 Exprt Market Expansin Strategies Intrductin It is clear that glbalizatinMore information
Electric Circuits II. More about Mutual Inductance. Lecture #22
EE 05 Dr. A. Ziduri Electric Circuits II Mre abut Mutual Inductance Lecture # - - EE 05 Dr. A. Ziduri The material t be cvered in this lecture is as fllws: Mutual Inductance in Terms f Self InductanceMore information
Identify Storage Technologies and Understand RAID
98-365 Windws Server Administratin Fundamentals Identify Strage Technlgies and Understand RAID 98-365 Windws Server Administratin Fundamentals Lessn Overview In this lessn, yu will learn: Lcal strage ptinsMore information
Law of conservation of energy Total energy of an isolated body is constant
Energy is the essence f chemistry It determines which reactin can ccur Reactin either absrbs r releases energy Ttal energy E has tw cntributins a. Ptential energy (PE) E P = mgh m is mass, h is heightMore information
Lecture 16: 11.04.05 Single-Component phase diagrams continued; Thermodynamics of solutions
Lecture 16: 11.04.05 Single-Cmpnent phase diagrams cntinued; Thermdynamics f slutins Tday: LAST TIME...2 Single-cmpnent phase diagrams and the Gibbs phase rule...2 Cnstraints n the shape f phase bundariesMore information
Fabric Inspection Using Four-Point System
Fabric Inspectin Using Fur-Pint System Hw t draw the samples? If there are 10 rlls and each ne is a different type f fabric r a different design, all the rlls have t be checked. Hwever, in mst cases thereMore information
INSTRUCTIONS FOR USE SABRIL (SAY-bril) (vigabatrin) Powder for oral solution
INSTRUCTIONS FOR USE SABRIL (SAY-bril) (vigabatrin) Pwder fr ral slutin Read this Instructins fr Use befre yur child starts taking SABRIL and each time yu get a refill. There may be new infrmatin. ThisMore information
Will a non-spontaneous process occur if the temperature is increased?
Name Chem 163 Sectin: Team Number: ALE 20. Calculating S & Predicting Spntaneity f Reactin (Reference: 20.1-20.2 Silberberg 5 th editin) Will a nn-spntaneus prcess ccur if the temperature is increased?More information
Let s start with an activity http://www.teachersdomain.org/asset/lsps07_int_cellenergy/
Pre Quiz What is the purpse/functin f cellular respiratin? What is the name f the rganelle where cellular respiratin ccurs? Plants and animals perfrm cellular respiratin. (true r false?) What is the energyMore information
This report provides Members with an update on of the financial performance of the Corporation s managed IS service contract with Agilisys Ltd.
Cmmittee: Date(s): Infrmatin Systems Sub Cmmittee 11 th March 2015 Subject: Agilisys Managed Service Financial Reprt Reprt f: Chamberlain Summary Public Fr Infrmatin This reprt prvides Members with anMore information
NOMENCLATURE OF ORGANIC COMPOUNDS 2010, 2003, 1980, by David A. Katz. All rights reserved.
NMENCLATURE F RGANIC CMPUNDS 2010, 2003, 1980, by David A. Katz. All rights reserved. rganic chemistry is the chemistry of carbon compounds. Carbon has the ability to bond with itself to form long chainsMore information
manual Page 1 / 5 effects in an easy good LED strips can be Selection guide applications. 1) Selection (indoors, outdoors) desired number of LEDs
Technical instructin Intrductin LED strips are a new generatin f innvative lighting prducts that allw creating spectacular effects in an easy way. LED strips have ther advantages like small dimensins,More information
Module 2: Nitrogen Management. To view the chapter for this topic click here.
Mdule 2: Nitrgen Management T view the chapter fr this tpic click here. Mdule 2: Nitrgen Management Intrductin Nitrgen (N) is essential fr plant grwth: part f every living cell cmpnent f all amin acidsMore information
Boiling Points and Distillation
iling Pints and Distillatin The actin f biling is a prcess familiar t anybdy wh has cked pasta r brewed tea. s heat is applied t a pan f water, the temperature f the water increases until it reaches 100More information
Chem 115 POGIL Worksheet - Week #7 First Law, Enthalpy, Calorimetry, and Hess s Law
Chem 115 POGIL Wrksheet - Week #7 First Law, Enthalpy, Calrimetry, and Hess s Law Why? In additin t mass changes, chemical reactins invlve heat changes assciated with changes in the substances internalMore information
Lab #3: Spectrophotometry
Lab #3: Spectrphtmetry Backgrund One f the key functins f the hmestatic mechanisms f the human bdy is t maintain the chemical cmpsitin f the fluid envirnment in which the cells f the bdy live. The abilityMore information
Conduction in the Cylindrical Geometry
Cnductin in the Cylindrical Gemetry R. Shankar Subramanian Department f Chemical and Bimlecular Engineering Clarksn University Chemical engineers encunter cnductin in the cylindrical gemetry when theyMore information
Case Scenarios and Sample Claim Form Entries for Outcomes Reporting for Medicare Part B Therapy Services
Case Scenaris and Sample Claim Frm Entries fr Outcmes Reprting fr Medicare Part B Therapy Services The American Speech Language Hearing Assciatin develped the fllwing scenaris t help speech language pathlgistsMore information
METHOD 8031 ACRYLONITRILE BY GAS CHROMATOGRAPHY 1.0 SCOPE AND APPLICATION 1.1 Methd 8031 is used t determine the cncentratin f acrylnitrile in water. This methd may als be applicable t ther matrices. TheMore information
Chapter 6: Continuous Probability Distributions GBS221, Class 20640 March 25, 2013 Notes Compiled by Nicolas C. Rouse, Instructor, Phoenix College
Chapter Objectives 1. Understand the difference between hw prbabilities are cmputed fr discrete and cntinuus randm variables. 2. Knw hw t cmpute prbability values fr a cntinuus unifrm prbability distributinMore information
Flammable and Combustible Liquids - 1910.106(a)
Flammable and Cmbustible Liquids - 1910.106(a) (18) Cmbustible liquid means any liquid having a flashpint at r abve 100 F (37.8 C). Cmbustible liquids shall be divided int tw classes as fllws: (i) ClassMore information
Times Table Activities: Multiplication
Tny Attwd, 2012 Times Table Activities: Multiplicatin Times tables can be taught t many children simply as a cncept that is there with n explanatin as t hw r why it is there. And mst children will findMore information
Using Sentry-go Enterprise/ASPX for Sentry-go Quick & Plus! monitors
Using Sentry-g Enterprise/ASPX fr Sentry-g Quick & Plus! mnitrs 3Ds (UK) Limited, February, 2014 http://www.sentry-g.cm Be Practive, Nt Reactive! Intrductin Sentry-g Enterprise Reprting is a self-cntainedMore information
2. Before we answer the question, here are four important terms relating to redox reactions and galvanic cells.
CHAPTER SEVENTEEN ELECTROCHEMISTRY Fr Review 1. Electrchemistry is the study f the interchange f chemical and electrical energy. A redx (xidatin-reductin) reactin is a reactin in which ne r mre electrnsMore information
How to Avoid Moisture Damage to Walls from Condensation
Hw t Avid Misture Damage t Walls frm Cndensatin Backgrund Infrmatin Exterir building walls are barriers between the atmspheric cnditins n the utside and the atmspheric cnditins n the inside. CertainlyMore information
Nuggets of Knowledge for Chapter 4 Alkanes Chem 2310
I. Intrductin t Alkanes Nuggets f Knwledge fr Chapter 4 Alkanes Chem 2310 Alkanes are hydrcarbns cntaining nly single bnds. We will study them first because they frm the framewrk n which all ther typesMore information
2010 AT&T Business Continuity Study CENTRAL REGION (Missouri) Results
2010 Business Cntinuity Study: Missuri 2010 AT&T Business Cntinuity Study CENTRAL REGION (Missuri) Results Key Findings IT Plans fr 2010 IT budgets fr 2010 are abut the same r higher than thse f the previusMore information
The PMI Advanced. BET SORPTOMETER BET-203A Not just products...solutions!
The PMI Advanced BET SORPTOMETER BET-203A Nt just prducts...slutins! DESCRIPTION PMI s BET-Srptmeter is fully autmated, vlumetric gas srptin analyzer t measure accurately adsrptin and desrptin isthermsMore information
RGANIC CHEMISTRY I PRACTICE PRBLEMS FR BRNSTED-LWRY ACID-BASE CHEMISTRY 1. For each of the species below, identify the most acidic proton and provide the structure of the corresponding conjugate base.More information
Chapter 8 Reduction and oxidation
Chapter 8 Reductin and xidatin Redx reactins and xidatin states Reductin ptentials and Gibbs energy Nernst equatin Disprprtinatin Ptential diagrams Frst-Ebswrth diagrams Ellingham diagrams Oxidatin refersMore information
THE UNEARNED NO CLAIM BONUS. C. P. WELTEN Amsterdam
THE UNEARNED NO CLAIM BONUS C. P. WELTEN Amsterdam I. The claims experience f a mtrcar insurance is assumed t give sme indicatin abut the risk (basic claim frequency) f that insurance. The experience ratingMore information
Care Plan Oversight. Home Health Certification. July 23, 2014. Agenda
Care Plan Oversight Hme Health Certificatin July 23, 2014 Agenda Care Plan Oversight Why We Are Prviding the Educatin Prcedure cdes Descriptin f Services Wh Can Perfrm Frequency f Services Face-t-FaceMore information
Spatial basis risk and feasibility of index based crop insurance in Canada: A spatial panel data econometric approach
Spatial basis risk and feasibility f index based crp insurance in Canada: A spatial panel data ecnmetric apprach Millin A.Tadesse (Ph.D.), University f Waterl, Statistics and Actuarial Science, Canada.More information
Summary of Arrangements Conducted under the Medicare ACO Participation Waiver
Summary f Arrangements Cnducted under the Medicare ACO Participatin Waiver Last Updated: January 1, 2015 1. EHR Subsidy Arrangements (2013 2015). Effective August 14, 2013, the Jhn Muir Physician NetwrkMore information
New York University Computer Science Department Courant Institute of Mathematical Sciences
New Yrk University Cmputer Science Department Curant Institute f Mathematical Sciences Curse Title: Data Cmmunicatin & Netwrks Curse Number:CSCI-GA.2662-00 Instructr: Jean-Claude Franchitti Sessin: 2 AssignmentMore information
Carboxylic Acid Derivatives and Nitriles
Carboxylic Acid Derivatives and itriles Carboxylic Acid Derivatives: There are really only four things to worry about under this heading; acid chlorides, anhydrides, esters and amides. We ll start withMore information
WHITE PAPER. Vendor Managed Inventory (VMI) is Not Just for A Items
WHITE PAPER Vendr Managed Inventry (VMI) is Nt Just fr A Items Why it s Critical fr Plumbing Manufacturers t als Manage Whlesalers B & C Items Executive Summary Prven Results fr VMI-managed SKUs*: Stck-utsMore information
efusion Table of Contents
efusin Cst Centers, Partner Funding, VAT/GST and ERP Link Table f Cntents Cst Centers... 2 Admin Setup... 2 Cst Center Step in Create Prgram... 2 Allcatin Types... 3 Assciate Payments with Cst Centers...More information
2. Couple the two protected amino acids.
General Considerations The Strategy of Peptide Synthesis Making peptide bonds between amino acids is not difficult. The challenge is connecting amino acids in the correct sequence. andom peptide bond formationMore information
CHEM 211 CHAPTER 16 - Homework
CHEM 211 CHAPTER 16 - Homework SHORT ANSWER Consider the Friedel-Crafts alkylation reaction below to answer the following question(s): 1. Refer to the reaction above. Draw the structure of the electrophilicMore information
1.3. The Mean Temperature Difference
1.3. The Mean Temperature Difference 1.3.1. The Lgarithmic Mean Temperature Difference 1. Basic Assumptins. In the previus sectin, we bserved that the design equatin culd be slved much easier if we culdMore information
3.7 ALKYLATIN AND ACYLATIN REACTIN F AMINE 1131 organic phase organic phase organic phase CH 3 (CH ) 6 CH Br CH 3 (CH ) 6 CH Br CH 3 (CH ) 6 CH CN R 4 P Br R 4 P CN R 4 P Br Na CN Na Br Na Br aqueous phaseMore information
Nuggets of Knowledge for Chapter 13: Alkynes. Alkynes are hydrocarbons that contain a carbon-carbon triple bond.
I. Intrductin t Alkynes Classifying alkynes Nuggets f Knwledge fr Chapter 13: Alkynes Alkynes are hydrcarbns that cntain a carbn-carbn triple bnd. Cmpunds that cntain a carbn-carbn triple bnd but are ntMore information
Industrial and Systems Engineering Master of Science Program Data Analytics and Optimization
Industrial and Systems Engineering Master f Science Prgram Data Analytics and Optimizatin Department f Integrated Systems Engineering The Ohi State University (Expected Duratin: 3 Semesters) Our scietyMore information
HUMAN NUTRITION DIGESTION DISSECTION 28 MAY 2014 In this lessn, we: Lessn Descriptin Study the structure f the digestive system f animal by ding a dissectin Summary Structure f the Digestive System TheMore information
Student Academic Learning Services Page 1 of 7. Statistics: The Null and Alternate Hypotheses. A Student Academic Learning Services Guide
Student Academic Learning Services Page 1 f 7 Statistics: The Null and Alternate Hyptheses A Student Academic Learning Services Guide www.durhamcllege.ca/sals Student Services Building (SSB), Rm 204 ThisMore information
Student Exploration: Photosynthesis Lab
Name: Date: Student Explratin: Phtsynthesis Lab Vcabulary: carbn dixide, chlrphyll, glucse, limiting factr, nanmeter, phtsynthesis, wavelength Prir Knwledge Questins (D these BEFORE using the Gizm.) TMore information
DUAL DISPLAY ALCOHOL BREATH TESTER P/N: 6016389JT2 (1) Breath inhaler (2) Clck LCD (3) Alchl tester LCD (4) Pwer buttn (5) MODE buttn (6) SET buttn (7) ADJ buttn (8) Reset buttn (9) Battery cmpartmentMore information
Defining Sales Campaign Automation How e-mail, the Killer App, is best applied to marketing
Defining Sales Campaign Autmatin Hw e-mail, the Killer App, is best applied t marketing Summary: Cmpanies tday are steadily adpting strategies and technlgies t reach prspects, custmers, and partners thrughMore information
CAPTER 9 MODELS OF CEMICAL BONDING 9.1 a) Larger inizatin energy decreases metallic character. b) Larger atmic radius increases metallic character. c) Larger number f uter electrns decreases metallic character.More information
Understand Business Continuity
Understand Business Cntinuity Lessn Overview In this lessn, yu will learn abut: Business cntinuity Data redundancy Data availability Disaster recvery Anticipatry Set What methds can be emplyed by a systemMore information
Calibration of Oxygen Bomb Calorimeters
Calibratin f Oxygen Bmb Calrimeters Bulletin N.101 Prcedures fr standardizatin f Parr xygen bmb calrimeters. Energy Equivalent The calibratin f an xygen bmb calrimeter has traditinally been called theMore information
Integrate Marketing Automation, Lead Management and CRM
Clsing the Lp: Integrate Marketing Autmatin, Lead Management and CRM Circular thinking fr marketers 1 (866) 372-9431 www.clickpintsftware.cm Clsing the Lp: Integrate Marketing Autmatin, Lead ManagementMore information
experiment5 Understanding and applying the concept of limiting reagents. Learning how to perform a vacuum filtration.
81 experiment5 LECTURE AND LAB SKILLS EMPHASIZED Synthesizing an organic substance. Understanding and applying the concept of limiting reagents. Determining percent yield. Learning how to perform a vacuumMore information
Training Efficiency: Optimizing Learning Technology
Ideas & Insights frm 2008 Training Efficiency Masters Series Survey Results Training Efficiency: Optimizing Learning Technlgy trainingefficiency.cm Survey Results: Training Efficiency: Optimizing LearningMore information
CHATE 3 OUTUT STAGES AND OE AMFES Chapter Outline 3. Classificatin f Output Stages 3. Class A Output Stage 3.3 Class B Output Stage 3.4 Class AB Output Stage 3.5 Biasing the Class AB Circuit 3.6 CMOS ClassMore information
In Australia, compulsory third party insurance (CTP) covers
COMPULSORY THIRD PARTY INSURANCE: METHODS OF MAKING EXPLICIT ALLOWANCE FOR INFLATION B. J. BRUTON and J. R. CUMPSTON Australia SUMMARY An inflatin index is essential when cnstructing claim payment mdelsMore information
OBJECTIVE 10: ALERT AND NOTIFICATION OBJECTIVE Demnstrate the capability t prmptly alert and ntify the public within the 10-mile plume pathway emergency planning zne (EPZ) and disseminate instructinalMore information
FundingEdge. Guide to Business Cash Advance & Bank Statement Loan Programs
Guide t Business Cash Advance & Bank Statement Lan Prgrams Cash Advances: $2,500 - $1,000,000 Business Bank Statement Lans: $5,000 - $500,000 Canada Cash Advances: $5,000 - $500,000 (must have 9 mnthsMore information
Conversations of Performance Management
Cnversatins f Perfrmance Management Perfrmance Management at Ohi State The Secnd Cnversatin ~ Develpment 2011 The Ohi State University Office f Human Resurces Cntents Intrductin Welcme t Develping Emplyees...More information
EXPERIMENT 9 (Organic Chemistry II) Pahlavan - Cherif Synthesis of Aspirin - Esterification
EXPERIMENT 9 (rganic hemistry II) Pahlavan - herif Materials Hot plate 125-mL Erlenmeyer flask Melting point capillaries Melting point apparatus Büchner funnel 400-mL beaker Stirring rod hemicals SalicylicMore information
GAS RESOLUTION AND RELEASED MODELS IN REACTOR THERMAL-HYDRAULICS. E. Zaltsgendler, W. S. Liu, R. K. Leung
CA9700843 GAS RESOLUTION AND RELEASED MODELS IN REACTOR THERMAL-HYDRAULICS E. Zaltsgendler, W. S. Liu, R. K. Leung Ontari Hydr Nuclear, Reactr Safety and Operatinal Analysis Department 700 University Avenue,More information
INTRODUCTION : Measurement is designed t prvide quick practice and review pprtunities fr students with learning differences. Each f the 180 warm-up activities has clear and simple directins. The practiceMore information
Traffic monitoring on ProCurve switches with sflow and InMon Traffic Sentinel
An HP PrCurve Netwrking Applicatin Nte Traffic mnitring n PrCurve switches with sflw and InMn Traffic Sentinel Cntents 1. Intrductin... 3 2. Prerequisites... 3 3. Netwrk diagram... 3 4. sflw cnfiguratinMore information
Allcare Pharmacy Group. Implementation Of Microsoft Dynamics Nav
Allcare Pharmacy Grup Implementatin Of Micrsft Dynamics Nav Dermt Ryan Finance Directr BACKGROUND ON ALLCARE PHARMACY GROUP Began as Restructuring f the Independent Pharmacy Ownership Scheme IPOS One fMore information
260 12-1 I. THEORY EXPERIMENT 12 THE SERIES CIUIT In this experiment we will charge and discharge a capacitr thrugh a resistr, and measure the vltage acrss the capacitr as a functin f time. The purpseMore information
TYPE OF ASSISTANCE TYPE OF PROPERTY HAZARD REDUCTION REQUIREMENT. Multifamily property constructed before 1960. Constructed after 1959 and before 1978
HUD Federally-Assisted Lead-Based Paint Final Rule HUD has released the final rule n lead paint hazard reductin in federally assisted husing. The rule applies t all types f federal assistance -- includingMore information
Cold, Hot, or Dilute: Modeling the Viscosity of Heavy Oil for In Situ Processes
Cld, Ht, r Dilute: Mdeling the Viscsity f Heavy Oil fr In Situ Prcesses H.W. Yarrantn*, H. Mtahhari, Department f Chemical and Petrleum Engineering, University f Calgary, Calgary, Alberta, Canada email@example.com information
Fixed vs. Variable Interest Rates
Fixed vs. Variable Interest Rates Understanding the Advantages and Disadvantages f Each Rate Type When shpping fr financial prducts, there are a lt f factrs t cnsider. Much has changed in the financialMore information
THE REMOVAL OF SOLUBLE SILICA FROM FRESH WATER. ENTERING THE SEPi'' 2
THE REMOVAL OF SOLUBLE SILICA FROM FRESH WATER ENTERING THE SEPi'' 2 GEORGE S. BIEN, DAVID E. CONTOIS, and WILLIAM H. THOMAS Scripps Institutin f Oceangraphy, University f Califrnia, La Jlla, CalifrniaMore information
Green Principles Atom Economy Solventless Reactions Catalysis
Lab 5: The Aldol Reaction Solventless vs Traditional Reactions: (Melting Point Study & Recrystallization) (adapted from Doxsee, K.M. and Hutchison, J.E., Green Organic Chemistry and John Thompson; LaneMore information
Wireless Light-Level Monitoring
Wireless Light-Level Mnitring ILT1000 ILT1000 Applicatin Nte Wireless Light-Level Mnitring 1 Wireless Light-Level Mnitring ILT1000 The affrdability, accessibility, and ease f use f wireless technlgy cmbinedMore information
Sinusoidal Steady State Response of Linear Circuits. The circuit shown on Figure 1 is driven by a sinusoidal voltage source v s (t) of the form
Sinusidal Steady State espnse f inear Circuits The circuit shwn n Figure 1 is driven by a sinusidal ltage surce v s (t) f the frm v () t = v cs( ωt) (1.1) s i(t) + v (t) - + v (t) s v c (t) - C FigureMore information
Network Theorems - Alternating Current examples - J. R. Lucas
Netwrk Therems - lternating urrent examples - J. R. Lucas n the previus chapter, we have been dealing mainly with direct current resistive circuits in rder t the principles f the varius therems clear.More information
Chapter 4 Saturation. S o. S w (4.1) where: (4.2) 4.1
4.1 aturatins The pre spaces in undergrund rcks that frm il and gas reservirs are always cmpletely saturated with fluid. In the pres f the reservir, there is never an ccasin r lcatin where nthing existsMore information
Chapter 11 Homework and practice questions Reactions of Alkyl Halides: Nucleophilic Substitutions and Eliminations
Chapter 11 Homework and practice questions Reactions of Alkyl Halides: Nucleophilic Substitutions and Eliminations SHORT ANSWER Exhibit 11-1 Circle your response in each set below. 1. Circle the leastMore information
SWARTHMORE GIFT PLANNING Gift Basics Thank yu fr serving as a 50 th reunin gift planning representative fr yur class. Yur supprt fr the Cllege and yur membership in the Swarthmre Legacy Circle will serveMore information
Consultation on Pensions Tax Relief. Savings and Investments Policy project. Pension Taxation Proposals. Charles McCready, TSIP Programme Director
Cnsultatin n Pensins Tax Relief Savings and Investments Plicy prject Pensin Taxatin Prpsals Charles McCready, TSIP Prgramme Directr Overview The taxatin prpsals have been develped by members f the TSIPMore information
17. REACTINS INVLVING ALLYLIC AND BENZYLIC RADICALS 793 As Eq. 17. shows, the products derived from the reaction of water at the ring carbons are not formed. The reason is that these products are not aromaticMore information
Born-Oppenheimer Approximation is the assumption that the electronic motion and the nuclear motion in molecules can be separated.
Rtatinal transitins Vibratinal transitins Electrnic transitins Brn-Oppenheimer Apprximatin is the assumptin that the electrnic mtin and the nuclear mtin in mlecules can be separated. This leads t mlecularMore information
Aldehydes can react with alcohols to form hemiacetals. 340 14. Nucleophilic substitution at C=O with loss of carbonyl oxygen
340 14. Nucleophilic substitution at C= with loss of carbonyl oxygen Ph In Chapter 13 we saw this way of making a reaction go faster by raising the energy of the starting material. We also saw that theMore information


text: I've received a letter telling me my medical clearance has been delayed (done briefing, not done main board) due to a history of a stress fracture. They require copies of x ray reports and confirmation that I can be active without being in pain, as well as hospital reports. They didn't specify what the fracture was though. I think it is probably my broken nose that happened last June, but that was extremely minor and required no treatment, I just waited for it to be OK and it is absolutely fine. So I am pretty sure I know how to get hospital records (from the hospital...), but how to I confirm "My current level of activity and confirmation that it is/is not pain free"? I mean the fact that I did briefing OK should be testament to this.


text:
12 Thrifty Trash to Treasure Crafts
Bonus: Get our newsletter & special offers for free. We will not share or sell your email address. View our Privacy Policy
Latest Comments
"I like this vintage style Santa graphic, but I read that the designer used a cutting machine to cut a red vinyl decal to afix to the cream painted wood board. I don't know what kind of cutting machine she is talking about and I wonder how pricey it is? I'd like an alternative to getting that Santa on there."
"This wall decor is very chic with any message you write on it! And it couldn't be easier. However, another option to using foam core board would be to actually buy an old thrift store bulletin board and spray paint it black. I think it would give the wall art a little bit more of a lived-in rustic look as the cork board adds texture and interest."
"This DIY holiday project is something that I would like to do at home myself. This craft is not for everyone's taste, but if you like a certain minimalist decorating approach and you've got a creative eye then this is for you! At first I did not even notice the picture frame in the background. It's used to attach the branch to it. Cute idea!"
Vintage Look of Metal Box
By: Heidi Borchers
We are adding the craft to your Craft Projects.
The project was added to your Craft Projects.
Click here to view your Craft Projects.
Looking for fun vintage crafts? Make a Vintage Look of Metal Box from Heidi Borchers. Use aluminum foil to create this awesome craft.
- Wood box
- Aluminum foil
- Corrugated cardboard (I've used a hot sleeve from coffee drink)
- Glue (I've used Aleene's Tacky Glue)
- Acrylic paint - black
- Brush-1/2" flat
- Waxed paper
- Paper towel or soft cloth (for wiping back paint)
- Brayer or rolling pin
- Embellishments - assorted vintage buttons, beads
- Wood beads-3/4" diameter (feet)
- Cotton swabs
- Sealer matte (I used Aleene's sealer)
- Cut and glue the corrugated cardboard to fit the top of the box.
- Scrunch the aluminum foil into a loose ball. Don't scrunch too tightly or it will be difficult to get the foil apart.
- Open up and flatten out the foil….use a brayer to completely flatten. Trim piece to fit the top of box.
- Brush glue onto box lid and over the sides of the box lid.
- Place foil dull side up on tabletop. Place wood box lid on flattened foil sheet. Press and push edges of foil over the top and sides of the box. Trim foil when necessary to help foil to fit the top, sides and into the inside of the box. Repeat with the inside of top and the bottom part of the box.
- Using a cotton swab, carefully press over the foiled area of the corrugated cardboard, to uncovered the texture.
- Use the edge of a pencil to press the foil flat against the wood box.
- When you are finished, the foil should be flatly glued to the box top and bottom and and you should clearly see the texture design in the foil.
- Place foiled box onto a sheet of waxed paper. Pour out a small amount of black acrylic paint. Working on one side at a time, brush the black paint over the foil.
- Wipe paint back immediately with a paper towel leaving paint in the crevices to highlight the texture and crinkled design. Repeat painting on each side, top and bottom of box. Let paint dry completely. To seal the box, spray with a matte sealer.
- To decorate the top, paint a torn piece of corrugated cardboard with black acrylic paint. Glue in place on top of box. Decorate with vintage buttons, beads, and unusual collectibles. Paint wooden beads with black paint. Let dry completely. Glue in place on bottom of box.
For a video tutorial of this project, check out How to Make Look of Forged Metal with Aluminum Foil Video.
Tags / Related Topics
Your Recently Viewed Projects
Images from other crafters
Love these projects? Get MORE delivered to your Inbox – FREE Click Here!
Report Inappropriate Comment
Are you sure you would like to report this comment? It will be flagged for our moderators to take action.
Thank you for taking the time to improve the content on our site.
Something worth saving?
- SAVE all your favorite crafts
- ADD personal notes
- QUICKLY reference your crafts
Free eBooks
- 11 Crochet Shawl Patterns: Crochet Poncho Patterns, Free Easy Crochet Patterns and More
- 12 Knitted Scarf Patterns: Fabulous Free Knitting Patterns for Beginners
- 14 Free Crochet Patterns for Babies and Toddlers
- 16 Free Crochet Hat Patterns, Scarves, and Gloves
- 22 Free Crochet Patterns: Afghan Patterns, Crochet Hats, and More
- 24 Quick and Easy Knitting Patterns
- 7 Adult Coloring Pages
- 8 Free Apron Sewing Patterns
- Easy Lace Knitting Patterns
- Quick & Easy Decoupage: 12 Fabulous Mod Podge Projects for Your Home
Our Newest Projects & Articles
- 11 Easter Crafts for Kids
- 100+ Easter Crafts
- Duo of Bears Unisex Baby T-Shirt
- Cross My Heart Treat Bag
- How to Sew a Zipper into a Lined Skirt
- Tiny Valentine Gift Boxes
- Pretty Hearts Hot Pad
- DIY Mini Pallet Photo Magnets
- Padded Denim Hearts for Decoration or Keyring
- Faux Topiary Heart Place Card Holders


text:
Subject-specific publications
SVQ in Procurement level 2 Standards
£12.00, S021, April 1997
SVQ in Procurement level 3 Standards
£12.00, S022, April 1997
SVQ in Procurement level 4 Standards
£12.00, S023, April 1997
To order any of the publications listed, contact SQA's Business Development & Customer Support Team quoting the publication code (unless otherwise indicated) or print, complete and return our Order Form (414 KB) . You can order any of our publications by credit card, Delta or by Switch.
Business Development & Customer Support Team
Scottish Qualifications Authority
The Optima Building
58 Robertson Street
Tel: 0303 333 0330
Fax: 0345 213 5000
E-mail: firstname.lastname@example.com
We accept payment with the following cards:
Publications Feedback
We are very keen to receive your views on how useful SQA's publications are to you in offering our qualifications. If you have comments on a document, or more general points about our publications, please note them down on our Publication Feedback form.


text:
Researchers Make an Obvious Discovery For Improving Drones
Turns out birds have the right idea when it comes to flight. Who knew?
Turns out birds have the right idea when it comes to flight. Who knew?
As counterfeiters get better and better at faking expensive Swiss watches, the watchmakers themselves now have a new tool to help distinguish their genuine creations from fakes.
The ability to internally bridge the gap between two ends of severed spinal cord would be nothing short of revolutionary for the neurosurgical field. Oh wait, looks like a team from the EPFL has just invented a way to do just that—in mice.
Charging from overhead lines, or via the road, requires an awful lot of infrastructure changes. Fortunately these bus stop-based chargers do not.