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Volume 51, Issue 5, 01 September 1969
Atomic and Molecular Scattering from Solids. II. Comparison of Classical Scattering Models in Relation to Experiment51(1969); http://dx.doi.org/10.1063/1.1672253View Description Hide Description
Characteristics of a classical two–dimensional (2d) model of atomic scattering from finite temperature, elastic solids are compared to similar characteristics of "quasi‐1d" scattering models in light of pertinent experimental scattering studies of rare‐gas atomic beams on metals. (The term "quasi‐1d" is used to denote scattering models based on the assumption that tangential interaction is negligible, i.e., dynamical interaction is presumed to occur only in the direction normal to the local surface plane.) The 2d finite‐range interaction field (denoted 2d FRI) is composed of additive Lennard‐Jones (12, 6) pairwise potentials. Compared scatteringcharacteristics include beam directivity and position as well as variation of mean tangential/normal momentum with scattering angle. It is shown that combined "structure" and "thermal" broadening associated with 2d FRI can account for systematic differences between experimentally observed lobe directivity and that predicted by quasi‐1d "soft/hard cube" scattering models. For nongrazing incidence, strong angular variation of tangential momentum over the high‐intensity portion of the scatteredbeams, as predicted by the 2d FRI model, is also in qualitative agreement with experiment. Dominant effects of finite "collision time," as determined by 2d FRI, cast doubt on previous interpretation that observed differences in lobe position for effusive incident beams of different rare gases scattered from a particular hot metal crystal result from simple mass ratio effects. Effects of finite "collision time" are also invoked to interpret recent experimental findings on differences in lobe position for a given rare‐gas beamscattered from different hot metal crystals. It is concluded that quantitative theoretical studies of gas–surface scattering must await development of tractable 3d FRI models.
Quantum Solution of Collinear Reactive Systems: H+Cl2→HCl+Cl51(1969); http://dx.doi.org/10.1063/1.1672254View Description Hide Description
Reaction‐path coordinates are used in the quantum‐mechanical calculation of reactive and nonreactive scattering probabilities for a collinear collision of an atom and a diatomic molecule. The parameters of the potential‐energy surface were varied to demonstrate the influence of various features on the probabilities of reaction and the distribution of vibrational energy in the reaction H+Cl2→HCl+Cl. In addition to the features known previously, the sharpness of the curvature of the reaction path was identified as having a major influence on the vibrational energy of the products. All six open vibrational channels of the products were considered. The advantages and disadvantages of this method of numerical solution of the problem are discussed.
Classical Calculations of Linear Reactive Systems: H+Cl2→HCl+Cl51(1969); http://dx.doi.org/10.1063/1.1672255View Description Hide Description
Classical trajectory calculations were performed for the collinear H+Cl2 system using reaction coordinates and the potential‐energy surfaces described previously for the quantum calculations. The resulting probabilities of reaction and the vibrational‐energy distributions were compared with previous quantum calculations.
Lower‐Energy Electronic States of HNCS, NCS−, and Thiocyanate Salts51(1969); http://dx.doi.org/10.1063/1.1672256View Description Hide Description
The phosphorescenceemission spectra and lifetimes of the thiocyanate salts of K+, Ba2+, Zn2+, Cd2+, Pb2+, and Ag+ have been measured. The converse absorption process has also been detected and studied. It has been established, as a result of these studies, that the lowest‐energy excited state of the thiocyanate ion is of nature in the linear NCS− ion. The 240‐mμ transition of NCS−, previously assigned as a charge‐transfer‐to‐solvent (ctts) transition, has been detected in all thiocyanate salt solutions and in gaseous HNCS. This absorptive transition has been reassigned as a transition of the isolated ion. This transition possesses some intramolecular charge‐transfer nature and should be expected to exhibit the solvent effects previously adduced as evidence for its supposed ctts nature. A third transition has been detected at 197 mμ in HNCS gas and is tentatively assigned to the transition . A number of other topics are also broached. These are isomerism in thiocyanate salts of K+, Zn2+, Cd2+, and Ba2+; polymerization in thiocyanate salts of Ag+ and Pb2+; spin–orbit coupling in the SCN− ion and the effects of associated metal ion thereon; and energy levels of the SCN− ion. All conclusions drawn are based on experiment and/or computation and/or analogy with the known characteristics of some of the excited states of the isoelectronic CS2 and CO2 molecules.
Hydrodynamical Properties of Stiff Linear and Ring Polymers51(1969); http://dx.doi.org/10.1063/1.1672257View Description Hide Description
The intrinsic viscosity and sedimentation coefficient of stiff linear and ringpolymers are calculated by using the method developed by Fixman. The contradictory prediction on the behavior of by Bloomfield–Zimm and Fukatsu–Kurata is discussed in relation to the Kirkwood–Riseman approximation. Our results for the intrinsic viscosity and sedimentation coefficient predict,,which agrees with the experimental observation by Crothers–Zimm on DNA.
Molecular Beam Kinetics: Reactions of K, Rb, and Cs with ICl and IBr51(1969); http://dx.doi.org/10.1063/1.1672258View Description Hide Description
Crossed‐beam studies of the reactions of alkali atoms with ICl and IBr show that the main features are very similar to those found for the Cl2, Br2, and I2reactions: (1) The reaction cross sections are extremely large, >̃150 Å2. (2) Most of the alkali halide product appears in the forward hemisphere with respect to the incident alkali‐atom beam, although there is also considerable intensity (∼15%–25% of the forward peak) throughout the backward hemisphere. (3) The angular distribution of the alkali atoms scattered without reaction falls off much more rapidly at wide angles than for collisions between unreactive molecules of comparable size. (4) Most of the chemical energy released appears as internal excitation of the products. The surface ionization detectors used in these experiments do not reveal whether the product of the M + IX reactions is MI or MX (or both). However, kinematic analysis of the scattering and results of chemiluminescence experiments indicate that (5) MX is the principal product. The electron‐jump model for alkali reactions again offers a plausible chemical basis for the observed reaction dynamics, including Property (5). A qualitative molecular‐orbital argument predicts that the attacking alkali atom transfers its valence electron to an antibonding orbital of IX which is made up primarily of the orbital of the I atom, but the charge shifts to the X atom as the intermediate (IX)− molecule–ion dissociates in the field of the incoming M+ ion.
Theory of Triplet Exciton Annihilation in Polyacene Crystals51(1969); http://dx.doi.org/10.1063/1.1672259View Description Hide Description
An improved theoretical formulation of the triplet exciton bimolecular decay constant in organic crystals is developed which avoids the ad hoc introduction of a "weight factor" used in previous theoretical treatments, allows for explicit calculations of all reaction constants pertinent to mutual exciton annihilation of triplets, and properly accounts for the anisotropy of the interaction responsible for the bimolecular annihilation. A simplified model for the effective density of final electronic states is presented and explicit calculations are performed assuming that only the totally symmetric intramolecular C–C stretching modes are active and by including intermolecular vibrations phenomenologically. Calculations of the bimolecular decay constant and diffusiontensor, both with and without the inclusion of charge‐transferinteractions, are performed for solid naphthalene, anthracene, and tetracene. We obtain ; only for anthracene are experimental values available and here agreement between theory and experiment is excellent. Specifically, compared with . The dependence of the bimolecular rate constant on the rate of encounter of two localized triplet excitons and the transition rate to final state is quantitatively analyzed. The intermediate states involved in the annihilating process are identified theoretically as charge‐transferexcitons. The inverse of triplet–triplet exciton annihilation is predicted to have nonnegligible probability in pentacene and tetracene crystals and the corresponding transition rates are calculated and correlated with the low fluorescent efficiency of these crystals.
Electron Spin Resonance Spectra of Methyl‐Substituted Naphthalene Anion Radicals51(1969); http://dx.doi.org/10.1063/1.1672260View Description Hide Description
An analysis of the ring‐ and methyl‐proton hyperfine splitting constants in ten methyl‐substituted naphthalene anion radicals has been carried out. In addition to the seven radicals in this series studied by earlier investigators, we have obtained experimental data on the 1‐ and 2‐methylnaphthalene anions and on the 1,4,5,8‐tetramethylnaphthalene anion. The new results provide 15 additional ring‐proton splittings and three additional methyl‐proton splittings; earlier work provided 19 and seven splittings, respectively. Hückel molecular orbital calculations were carried out for all the radicals using both an inductive and an inductive‐hyperconjugative model for the effects of methyl‐group substitution. Both models gave comparable results, as did calculations employing the McLachlan method of including configuration interaction in an approximate way. The changes in proton splittings caused by methyl‐group substitution were found to obey an additivity relationship, i.e., methyl‐group substitution at positions and produces a change in the splitting at position equal to the sum of the effects observed at in radicals which are substituted only at or only at . By using the additivity relations, it was found that the MO calculations lead to the wrong assignment of some of the splittings to positions in the 1‐methylnaphthalene anion. Reasonably good agreement was obtained between the calculations and the ring‐proton splittings using a value of the inductive parameter (in units of the carbon–carbon resonance integral ), but there were a number of significant discrepancies. Similarly, good agreement was obtained for the methyl‐proton splittings at the positions, but for reasons which are not understood, the inductive parameter required to fit these data was instead of . The β‐methyl‐proton splittings, however, could not be adequately accounted for by any of the calculations. It was found that deceptively good agreement is obtained between calculated and experimental results if correlations are made in the usual way between actual splittings and spin densities rather than between the changes in these quantities arising from substitution. Several types of relations have been derived among the hyperfine splittings that do not depend on the detailed values of the calculated spin‐density distribution. One of these relates the sum of the methyl‐proton splittings in a substituted radical to the difference between the total extent of the spectrum from the unsubstituted naphthalene anion and the sum of the ring‐proton splittings from the substituted anion. An excellent correlation was obtained from which it was found that the sigma–pi parameter in the relation between methyl splittings and ring‐carbon‐atom spin densities is related to the parameter in the analogous relation for ring‐proton splittings by , or . On the other hand, a detailed comparison of substitution‐induced changes in methyl‐proton splittings with the changes in ring‐proton splittings, which again does not depend in any way on the calculated spin densities, gives inconsistent results. The discrepancies indicate that the sigma–pi relations for either or both the ring‐proton and methyl‐group‐proton splittings are not sufficiently accurate for detailed predictions of the splittings at each position in a radical, although in an over‐all average sense the sigma–pi relations appear to be valid. The analysis does not indicate which of the two relations is more in error. Difficulties thus arise in both the calculations of spin densities arising from methyl‐group substitution and in the sigma–pi parameters relating splittings to spin densities.
Dissociative Thermal Electron Attachment to Some Aliphatic Chloro, Bromo, Iodo Compounds51(1969); http://dx.doi.org/10.1063/1.1672261View Description Hide Description
Thermal electron attachment to several aliphatic fluoro, chloro, and bromo derivatives have been investigated in the range 30°–220°C and activation energies of 0–12 kcal have been determined. The relationship between the energy of activation and change in internal energy for the dissociative electron attachment reaction is uniquely linear with approximately a unit slope. Both chloro and bromo compounds apparently satisfy the same relationship. This empirical relationship can be used to predict bond dissociation energies for aliphatic chloro, bromo, and iodo compounds from the energy of activation for thermal electron attachment. Bond dissociation energies for 1,3‐dichloropropane, 1,2‐dibromoethane, and 1,3‐dibromopropane have been so determined as 75.6, 69.8, 70.9 kcal/mole, respectively. An expression for a two‐dimensional representation of the potential‐energy curve for the negative ion is proposed with which the linear relationship between and can be derived. The proposed potential‐energy curve is empirical, but contains only a single adjustable parameter characteristic of each compound.
Correlation of Electron Beam and Thermal Electron Attachment Studies for Some Chloro, Bromo, Iodo Aromatic Compounds51(1969); http://dx.doi.org/10.1063/1.1672262View Description Hide Description
The relationship between thermal electron attachment and electron beam studies for chlorobenzene, 0‐dichlorobenzene, 0‐chlorotoluene, 3′‐ and 4′‐chloroacetophenone, 1‐chloronaphthalene, bromobenzene, 0‐bromotoluene, 1‐bromonaphthalene, and iodobenzene is shown. The empirical negative‐ion potential‐energy function used to describe electron attachment to aliphatic halides is used for convenience in showing this relationship. Use of the two‐dimensional potential‐energy function permits a more quantitative representation of the mechanisms previously proposed. In some cases, the mechanisms have been altered from the earlier qualitative interpretation. In general the two types of measurement appear to be essentially in complete agreement. The agreement between the results further supports the empirical potential‐energy function for the negative ion. Also, thermal electron attachment to additional aromatic halogen derivatives was investigated by the pulse sampling technique as a function of temperature to further support the mechanism. In particular, the thermal electron attachment of 3′‐ and 4′‐chloroacetophenone shows a unique temperature dependence involving three different phenomena over the temperature range 30°–240°C, which adds further support to the proposed mechanisms. In all the other cases investigated (chlorobenzene, 0‐chlorotoluene, 0‐bromotoluene), the electron attachment shows only one temperature region, again in complete agreement with the proposed mechanisms.
Ring Puckering in Five‐Membered Rings. III. The Microwave Spectrum, Dipole Moment, and Structure of Cyclopentanone51(1969); http://dx.doi.org/10.1063/1.1672263View Description Hide Description
Microwave spectra of cyclopentanone and 2‐d‐cyclopentanone are reported. Eight vibrational satellites have been assigned for cyclopentanone, and two conformers have been observed for 2‐d‐cyclopentanone. The rotational constants of the ground states are: 6621, 3351.54, and 2410.40 MHz for the normal isotopic species of cyclopentanone; 6309, 3322.55, and 2382.82 MHz; and 6258, 3344.54, and 2361.96 MHz for the two conformers of the 2‐deutero isotopic species. It was found that the nature of the ring‐puckering potential is such that the ring is permanently twisted and undergoing bending and twisting vibration quite independently. The lower limit to the height of barrier‐hindering pseudorotation was set about 400 cm−1. The structural parameters, , , ∠(C2–C1–C5), and the twist angle , were calculated by the iterative procedure of the weighed least‐squares analysis. They are 1.504 ± 0.01 Å, 1.557 ± 0.007 Å, 110.5 ± 0.7°, and 23.6 ± 0.4°. The components of dipole moments were determined by the Stark effect: and .
Sharpness of Some Rare‐Gas Resonance Lines51(1969); http://dx.doi.org/10.1063/1.1672264View Description Hide Description
An investigation on the nature of krypton and argon resonance lines emitted from a low‐pressure lamp has been made applying the sensitized photoionization technique and represented in terms of "sharpness." Cowan and Dieke's self‐absorption theory has given a good interpretation of the dependence of the nature of resonance lines on the rare‐gas pressure. The approximate expressions for the total line intensity and the sharpness were obtained from their theory. The experimental results on the effect of neon acting as a foreign gas suggested that the broadening of resonance lines arised from the interaction between neon and rare‐gas atoms, and this interaction was larger in the case of the argon resonance line.
Kinetics of the Homogeneous Exchange Reaction 12C18O+13C16O⇆13C18O+12C16O. Single‐Pulse Shock‐Tube Studies51(1969); http://dx.doi.org/10.1063/1.1672265View Description Hide Description
The isotopic exchange reaction between two CO molecules was studied under homogeneous conditions in a single‐pulse shock tube at high dilution in argon within the 2000–2675°K temperature range. From a total of 100 shocks, run at varying initial pressures and compositions, the following rate law was derived: rate of exchange, where . The possibility of a chain mechanism was ruled out. A two‐step mechanism composed of a vibrational excitation step and an atom‐switching step is proposed. It was found that exchange occurs at high probability when one of the CO molecules is elevated to the 7th–10th vibrational level before colliding with another CO molecule. A dipole interaction stabilizing the transition state is proposed in explanation of the relatively low activation energy of this exchange reaction. Two alternative reaction systems are described, and the corresponding rate constants are computed and compared with the experimental results.
Pulse Radiolysis of Benzene Cyclohexane Mixtures51(1969); http://dx.doi.org/10.1063/1.1672266View Description Hide Description
The radiolysis of benzene and mixtures of benzene and cyclohexane have been studied by the nanosecond pulse‐radiolysis technique. In pure benzene, two short‐lived transitory species are observed with absorption maxima at 320 mμ and and 515 mμ and . The effect of temperature and dilution in C6H12 shows that the 515‐mμ peak is associated with the excimer of benzene. The effect of added solutes and of benzene dilution in C6H12 suggest that the 320‐mμ absorption is associated with a free radical which is formed by the reaction of a benzene triplet with benzene. The effect of benzene concentration on the excited singlet and triplet yields and on the reaction of the ionic species is also studied. It is shown that the geminateion recombination time is shorter in benzene than in C6H12, and that ion recombination is a major source of energy transfer in the radiolysis of benzene/C6H12 mixtures.
NMR Subspectral Analysis Applied to Polyfluorobenzenes C6HnF6−n. IV. 1,2,4‐Trifluorobenzene51(1969); http://dx.doi.org/10.1063/1.1672267View Description Hide Description
The 1H and 19F bands of the nuclear magnetic resonance spectrum of 1,2,4‐trifluorobenzene have been analyzed. The principles of subspectral analysis guided the application of iteration by computer and the use of the ABC parameters of this ABCMXZ system, obtained from a totally decoupled 1H spectrum, in the assignment of all 177 observed peaks.
Electric Field Effects on the Dielectric Properties and Molecular Arrangements of Cholesteric Liquid Crystals51(1969); http://dx.doi.org/10.1063/1.1672268View Description Hide Description
Measurements of dielectric constants of a cholesteryl chloride–cholesteryl myristate mixture having a strongly temperature‐dependent helical pitch have been performed in the presence and absence of an applied dcelectric field. An analysis of the molecular arrangement in samples oriented by wall effects is presented, as well as the perturbations in this arrangement which occur both thermally and by the application of an electric field.Elastic moduli of bending and torsional strain are estimated from the threshold electric fields observed to (a) induce helical perturbation and (b) destroy the helical structure in the transition to a nematic phase.
Satellites Induced by Foreign‐Gas Perturbation of the Lennard‐Jones Type51(1969); http://dx.doi.org/10.1063/1.1672269View Description Hide Description
The paper presents a calculation of the intensity of a spectral line emitted under perturbation by foreign atoms, its purpose being to provide a better understanding of the formation of satellites which often flank resonance lines. As a typical perturbation, a Lennard‐Jones interaction with suitable parameters is assumed for both electronic states involved in the transition. A numerical evaluation of integrals is required in this case, and the work is carried out in the limit of the statistical theory. A satellite appears on the red side of the main line up to a perturber density depending on the parameters in the potential, in our case up to 1021 cm−3. The satellite is located in the vicinity of the frequency , where is the differential energy shift at its minimum. Details of shape and shift depend on the perturber density. Temperature does not appear in this analysis because of its restriction to the statistical theory.
Band Shapes of the Electronic Spectra of Complex Molecules51(1969); http://dx.doi.org/10.1063/1.1672270View Description Hide Description
Structureless bands of ultraviolet absorption spectra of hydroxypyridine derivatives in solution have been examined. It is shown that the log–normal distribution provides a convenient four‐parameter empirical description of the bands and gives a much better fit than the two half‐width Gaussian. The log–normal yields a resolution of overlapping bands by a method of least squares that is very satisfactory. A simple configuration‐coordinate model is presented that lends some physical meaning to the parameters of the log–normal. It yields normalized third and fourth moments that are near those of the log–normal.
Polarization Assignments of the Electronic Spectrum of Purine51(1969); http://dx.doi.org/10.1063/1.1672271View Description Hide Description
Polarized reflection spectra of the (100) face of purine crystals have been measured to 185 mμ. The corresponding absorption spectra which are computed by a Kramers–Kronig transformation of the reflection spectra are analyzed so as to assign the transition moment directions of the electronic absorption bands. The analysis is made assuming the oriented‐gas model and again for a case which treats intermolecular interactions. The polarization of the first absorption band is out‐of‐plane as expected and is consistent with an assignment. The next band at 263 mμ is polarized in‐plane at + 48° from the axis (toward ). The weak band at 250 mμ in the crystal is another perpendicular transition. The strong absorption in the 200‐mμ region and below can be plausibly assigned as two transitions. One (at 200 mμ) is polarized in nearly the same direction as the 263‐mμ band. The other band, at 190 mμ, can have reasonable intensity relative to the solution spectrum only if it is polarized out‐of‐plane. Some evidence for another weak, in‐plane, long‐axis band at about 230 mμ is found.
Effects of Atomic Interactions on the Absorption and Emission of Radiation51(1969); http://dx.doi.org/10.1063/1.1672272View Description Hide Description
The processes of absorption and emission of radiation by a system of two interacting atoms is investigated. Separation between the atoms is assumed to be much larger than the atomic diameter, and interactions considered are those between the individual atoms and the radiation field and the electrostatic interaction between the atoms. Calculations include those for the time‐dependent probability amplitude of the intermediate and final states as well as that of the emission line shape. The line shape of the emitted radiation consists of two peaks whose amplitude, separation, and half‐width are functions of both the internuclear separation of the atoms and the energy difference of the excited states of the two atoms. For a large energy difference, the peaks are distinct; for small energy differences, the peaks are distinct at smaller separations, but merge toward the line shape characteristic of a single, isolated atom as increases.


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Italy Throw England Out of Euro 2012 after Penalty Kicks
Italy's players celebrate their penalty shootout victory over England in their Euro 2012 quarterfinal in Kiev. Photo by Getty Images
Italy have made it to the semi-finals of Euro 2012 as they beat England in the last quarter-final after penalty kicks.
Alessandro Diamanti scored the decisive kick Sunday to send Italy through to the European Championship semifinals with a 4-2 win in the shootout following a 0-0 tie with England.
Italy will next play Germany in the semifinals on Thursday in Warsaw, Poland. Defending champion Spain plays Portugal on Wednesday in Donetsk, Ukraine.
Ashley Young hit the crossbar with England's third, and Ashley Cole's attempt was saved by Gianluigi Buffon.
For England, it was yet another exit from a major tournament in the quarterfinals after a penalty shootout. England lost to Portugal in the same manner at Euro 2004 and the 2006 World Cup.
England briefly led the shootout after Riccardo Montolivo missed Italy's second penalty. His shot went wide of Joe Hart's right post as the England goalkeeper guessed correctly.
Rooney then sent Buffon the wrong way, firing in his spot kick to the keeper's right to give England a 2-1 lead. The momentum shifted after Pirlo's bold piece of skill leveled it 2-2.
The match ended 0-0 after 120 minutes of play. The Italians twice hit the post, but were also let down by poor composure in front of the net. Diamanti clipped the post with a curling cross in the 101st minute, and swept a shot wide in the clearest chance of the second period of extra time.
You are permitted to use any of the articles in this message only if you kindly quote the source - Novinite.com.


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Dana"s First Vlog for UFC 155 introduces Nick "the tooth" a long time friend of Danas. Back at UFC on Fox 5, Nick had a few (too many) drinks one night and talked himself into a fight with Joe Lauzon. See what happens.
Jim Miller: The road back to the promised land Next Post:
Does Hendo's camp have a point about Rousey?


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Check in from 14h / Check out prior to 11h
Del Prado Inn: Find photos, reviews, information, amenities and compare prices for 3 stars hotels in Cusco, Peru.
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First library meets matching milestone
Laramie, WY – The Albany County Public Library is the first in the state to meet the Wyoming Public Library Endowment Fund Challenge.
The library in Laramie has raised more than $100,000 that will be matched 3-to-1 by the state of Wyoming.
Gov. Dave Freudenthal in March 2008 set aside $9.1 million to be allocated to Wyoming's 23 county library systems through local library foundations.
The foundations were required to raise money that would be matched at various levels based on need.
The executive director of the library's Foundation says most donations to the library ranged from pennies in a donation jar to one of $5,000. He says most donations were in the $80 to $100 range.


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Skip to comments.Drudge Photo of Aaron Brown's Firing Has "America Strikes Back" Graphic in Background!
Posted on 11/03/2005 2:48:08 AM PST by governsleastgovernsbest
Check out the logo in the background in this photo, which is currently up on Drudge in regard to the news that CNN anchor Aaron Brown has been fired.
Note the background logo: "America Strikes Back." Coincidence? I don't think so! Nice work, Drudge!
I think Brown is going to end up taking over for Jennings.
Why was he fired?
I think he'll just hide away and write a bitter book about the stupid heathens out here who could not understand his understated and quiet nuance (BARF).
Here's an article that gives background on the firing:
The article buries the most important point at the bottom: Greta Van Susteren's ratings at Fox took off when Brown was put up against her!
What is "CNN"?
On my cable service, CNN is channel 13. How appropriate.
What happened to that tall gal that left Fox to do the morning show for CNN and then was moved to the evening? I never watch CNN, so I have not kept up with their moves.
I think this paragraph is extremely telling. Someone should tell these people it should not be storytelling. It is reporting the news.
That seems like it would be a mistake...
IOW yet again, FOX is number one with a boring talent before the camera because the boring talent has zero competition.
It is as if fox is the only new network in the face of the other wana-bes.
AND fox reruns their stuff at 11!
He was an anchor in Seattle for years.
Every time I see that smirk I wanna hurl...
Based on how sh&ty he was on that show surprised me that he ever got another newscast job - cable or otherwise.
If ABC were to put him in Jennings job it would just help continue the demise of network news broadcasting.
Please, ABC, grab'em up and put him on air - PLEASE!
I have never heard of Arron Brown and I know absolutely nothing about him. Why, you ask? Because I will not degrade myself by watching CNN, and I haven't watched CNN in more than four years.
He was fired because he needed a "much needed break" to spend more time with his family. :-)
CNN thinks Cooper was a star during the hurricane coverage because he got great ratings then tool
Considering Whorealdo and Shep Smith, even I watched Cooper Anderson, or is it Anderson Cooper!?
Yes, everyone enjoys watching Anderson Cooper stand sideways in a hurricane, followed by his shrieking tantrums because the hurricane has been over for five minutes and the government hasn't rebuilt the entire state as Disneyland and moved everyone into the equivalent of Trump Towers, rent free!
SURELY there are people out there that are actually qualified to report the news. Somewhere. Without shrieking and hyperventilating.
Clearly he was not ready for prime time.
CNN has the drunk Cafferty to more than make up for Brown's bias.
Anderson Cooper...will they ever learn?
I confess - I confess.
I have watched CNN recently. Not my choice but CNN is blaring out every time I have to wait in a doctor's office.
What's with this one channel only thing with waiting rooms?
I finally found an Ortho Doc who has Fox on.... and a whole wall devoted to 9/11 WTC pictures. His group are fine - made my broken arm feel a little better not having to watch CNN while waiting for another X-ray.
For the money CNN must have been paying him, you'd think he could afford a handkerchief so he could blow his nose occasionally.
Brown has already worked for ABC. I liked him then. Wonder what changed him?????
right on. And Jerry Rivers and Greta are no better.
He flunked the Tangerine vs Melon section of his Color Differentiation Test. Cooper aced it.
LOL! America is "staying away in droves" from CNN!
I watch South Park at 10:00 p.m.(EST)when Greta is on, and I've never heard of Jerry Rivers either.
Particularly when Brown was interviewed on the golf course saying "hey, what goes up must come down. What's the big deal? Fore!" ;-)
LOL - Yeah, I'll admit to not knowing who either are, other than through these threads.
CNN is smart..they are losing market share....so they will replace him with another liberal....see I told you...Cnn is smart
And the long-form programs, like 60 Minutes, have the TIME to tell a complex story--they just aren't fair and balanced. So you get a 45-minute Democrat Party commercial (or at least a 45-minute anti-conservative message).
...wonderful fairy tales.
he was hurt by a widely reported story in 2003 that he didn't cut short a golf outing to come to work on the day the Columbia space shuttle disintegrated.
That seems like it would be a mistake...
Depends on what he was shooting at the time.
No kidding, its really no wonder Fox is so far out in front. The competition just can't hold it together. I feel like every day I turn around and CNN's changing something or firing someone!
Cafferty is an embarrassment.
Blitzer gets orgasmic at Cafferty's rantings.
Good Lord. I though Wolf had a little more class than that.
Whatever gave you the idea that Blitzed had any class at all?
Good question. I just see his face when I'm channel surfing so I guess I haven't gotten the bigger picture.
CNN is the enemy of civilized society.
LOL. He's got that NPR feel to him, doesn't he.
You know, I've stopped watching the news. I can't find, even on Fox, reporting that give me what I get on freerepublic.
Yeah, I could run over him, and still not know who he is.
Except for that arrogant quote a couple of years ago. He said "He was the face of CNN".
The last time I really watched CNN was when Israel was surrounding Arafat yet again, and Arafat was wigging
(whigging?) out on a call to Amapour.
I agree that his tell-all book is going to be pretty juicy.
There are so many things going wrong at CNN, that there are bound to be some great back-stabbing and passing-the-buck stories!
Disclaimer: Opinions posted on Free Republic are those of the individual posters and do not necessarily represent the opinion of Free Republic or its management. All materials posted herein are protected by copyright law and the exemption for fair use of copyrighted works.


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Roasted Pork Loin with Balsamic Reduction Sauce
Recipe Summary
Recipe Servings: 6 portions
Recipe Preparation Time: 0 minutes
Recipe Cook Time: 50 minutes
4 cups good quality red wine
4 cloves garlic, chopped, divided
1 bottle plus 3/4 cup Lucini® 10 Year Gran Riserva Balsamico, divided
3 teaspoons chopped, fresh rosemary, divided
1/4 cup brown sugar
3 pound boneless pork loin
Salt and freshly ground black pepper
1 tablespoon Lucini® Premium Select Extra Virgin Olive Oil®
To prepare reduction sauce, place wine and 2 cloves chopped garlic in heavy saucepan and, over high heat, reduce to about 1/4 cup. Add bottle of balsamico and, over medium heat, again reduce to about 1/3 cup. Add 1 tsp rosemary, lower heat to simmer and cook about 5 minutes, until very thick. Remove from heat and strain. Set aside at room temperature.
To prepare pork glaze, combine remaining garlic and rosemary, brown sugar and 3/4 cup Balsamico in saucepan over high heat. Bring to a boil, reduce heat to low and cook 5 minutes longer, until brown sugar has dissolved. Set aside.
Preheat oven to 325 degrees. To prepare pork loin, season meat well with salt and pepper. Heat olive oil in very large ovenproof skillet over high heat, until smoking hot. Add pork and sear well, 5 minutes per side. Brush pork liberally with glaze and set skillet in oven. Roast 15 minutes, brush with more glaze and continue roasting 15 - 20 minutes until pork reaches an internal temperature of 140 degrees (use meat thermometer). Remove from oven and let pork stand 5 minutes. Slice and drizzle with reduction sauce. Garnish with additional fresh rosemary, if desired.
Recipe by:
Chef Caprial Pence is the chef and co-owner of Caprial?s Bistro in Portland, Oregon, which opened in 1992. Shortly after graduating from the Culinary Institute of America, Caprial was named Best Chef: Pacific Northwest by the James Beard Foundation, the first female recipient of this prestigious award.


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Lauren Ralph Lauren Leathergoods Oil Milled Card Case with Money Clip
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Shipping your purchase is easy on belk.com. Depending on the destination of your package, you can expect it to arrive within 4-7 business days. Shipping Information
Returns are easy on belk.com. Easy returns


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How do I save an image from the web to a specific folder on my Mac?
When I try to save an image to my Mac - I have the option of saving it to my Desktop, my Docs folder or a few others, but not to a specific folder for different things I'm saving. I can't scroll through my Documents folders for example and save it to one of them.
So i end up saving things to my Desktop and that soon gets out of hand.
How can I save to a specific folder, and a different one each time if I choose. I can do this in Safari, but prefer Firefox.
Chosen solution
please see
- http://www.macworld.com/article/1053969/bigsave.html
- http://www.tuaw.com/2007/05/15/mac-101-mastering-the-save-dialog/
- http://hints.macworld.com/article.php?story=20120303042217490
or consult other mac osx support resources. this is no question about firefox in particular...Read this answer in context 2
Additional System Details
Installed Plug-ins
- Version 220.127.116.1137
- Google Talk Plugin Video Accelerator version:0.1.44.29
- Shockwave Flash 11.8 r800
- The QuickTime Plugin allows you to view a wide variety of multimedia content in web pages. For more information, visit the QuickTime Web site.
- Microsoft Office for Mac SharePoint Browser Plug-in
- Displays Java applet content, or a placeholder if Java is not installed.
- Adobe® Acrobat® Plug-in for Web Browsers, Version 10.1.7
- Adobe Shockwave for Director Netscape plug-in, version 12.0.2
- Plugin that detects installed Citrix Online products (visit www.citrixonline.com).
- WebEx64 General Plugin Container Version 202
- iPhoto6
- DivX VOD Helper Plug-in
- RealPlayer Plugin
- Garmin Communicator Plug-in Version 22.214.171.124
- User Agent: Mozilla/5.0 (Macintosh; Intel Mac OS X 10.6; rv:23.0) Gecko/20100101 Firefox/23.0
More Information
hello vicky, you can right click (or control-click) an image & select save image as... in order to set a custom download folder
Question owner
Thanks Phillipp - when i do that I only see Desktop or Documents or a few folders I've opened recently - I want to be able to choose the folder in my Docs that it gets saved to.
In Safari I can save it to wherever I want. Not Firefox.
hello, i think this is not a browser-dependant function but this dialog is displayed by the operating system. (i'm on windows though and don't know how it is handled on macs) - maybe see http://osxdaily.com/2007/04/25/how-to-enable-expanded-save-dialog-as-default/ for a workaround.
Helpful Reply
What are the Download settings here:
- Firefox > Preferences > General : Downloads : "Always ask me where to save every file"
Question owner
Thanks - this looks like it would do it but i have no idea what it means to 'open the terminal' and paste in the copy they suggest.
Where do I find the terminal??
Question owner
I want to be able to make a choice for each thing saved - not just download them all into a certain folder. Thx Cor-el
Question owner
OK - I found 'terminal' and pasted in that line of copy - but it still doesn't make any difference when I go to save a image from the web. Looks like that's for having an expanded window open when saving something else.
Looks like I'll need to go back to safari or just accept that I'm going to be saving images to my Desktop all the time.
Chosen Solution
please see
- http://www.macworld.com/article/1053969/bigsave.html
- http://www.tuaw.com/2007/05/15/mac-101-mastering-the-save-dialog/
- http://hints.macworld.com/article.php?story=20120303042217490
or consult other mac osx support resources. this is no question about firefox in particular...
Helpful Reply
Ah, wonderful phillipp - the link about mastering the save gave me exactly what i needed.
I had already called Apple support and they couldn't help me - but this is perfect - no more saving things to my Desktop! Thanks so much.
you're very welcome, glad you could solve the issue :-)


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With the purchase of any eligible new Marine Receiver (Model #s:15081862, 14414056 or 14706576)
Valid February 1, 2016 — December 31, 2016
View Details
Boaters in the US can subscribe to SiriusXM Satellite Weather and enjoy detailed weather forecasts, NOWRad weather radar and much more, all delivered instantly to your a-Series, c-Series, e-Series or gS-Series system. Weather data can be displayed in its own dedicated page alongside your navigation data, or you can choose to overlay NOWRad Doppler weather radar on your live chartplotter display. Purchase the SR150 SiriusXM Marine Weather Receiver, the SiriusXM Weather Antenna (Shakespeare SRA-40 with 25' cable, Model 7833874, sold separately) and a subscription to SiriusXM (sold separately) and you can start receiving this crucial weather data:
|5 1/4" Width x 2 1/4" Height x 5 1/4" Depth
Satellite Radio
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|Warranty Details
|Three Years (with Product Registration)
The West Advisor articles have answered boaters' questions and provided solutions to boating problems for more than 20 years. West Marine has compiled one of the Web's most comprehensive collections of technical boating information articles.
Reviewed by 1 customer
Best Uses
Comments about Raymarine SR150 SiriusXM Marine Weather Receiver:
Easy to install - Sea talk adapters not included, Antenna not included.
Resolution is limited, not comparable to information available on web-sites.
But better than nothing.
Weather info is nationwide, you have to de-select a lot, which is not applicable.
Recommend it with restrictions. Service is expensive.


text:
One gubernatorial candidate says he has the solution to providing more affordable housing in Hawaii.
Click here to watch the report.
Republican candidate Duke Aiona says if elected governor, he wants to add 2,100 rental units across the state.
To do so, Aiona wants to reallocate 25 percent of the corporate income tax into the Rental Housing Trust Fund for seven years.
The fund will be used to entice developers to build affordable housing units.
"This additional funding will provide developers and builders of affordable rental with a aknown and stable funding source. The funding source is not a tax increase," said Aiona.
The legislature would need to approve the re-allocation of the money before it could happen.
Aiona says he plans on taking inventory of state lands to see if some of those rentals could be built on state property.


text:
Stay in Lake WorthLake Worth is a bohemian retreat with charming bed and breakfasts and local hotels.
Visit Local AttractionsLake Worth offers great beaches, a fishing pier, one-of-a-kind bars, historic buildings, special events and more.
Enjoy Shopping & EntertainmentLake Worth offers an eclectic mix of antique stores, specialty shops, restaurants, art galleries and music venues.
A diverse enclave, Lake Worth is a true haven for artists and free spirits.


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PEB Awareness
PEBs erection cost is very low as it requires a very little manpower and construction equipment compared to concrete buildings
Product Reference
Zamil Steel is committed to produce contents that contributes to the education of all parties involved in the purchase of a Zamil Steel pre-engineered steel building. Every effort is made to update this contents.
Anchor Bolts
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Zamil Steel Construction Co. wins SAR 12M contract for Saudi Aramco's Fadhili Industrial Support Facilities in Jubail


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Conduct Hydraulic Excavator Operations (RII Unit)
WH&S More Skills
|Mid Year Intake?
|Study Mode
|Entry Requirements
|Flexible Delivery, Part-time internal
No minimum education
Course Description
This unit is part of the Resources and Infrastructure Industry Training Package. It covers the skills and knowledge required to conduct hydraulic excavator operations in coal and metalliferous mining and extractive. This unit is appropriate for those working in operational roles.
Subjects you can Study
Plan and prepare for hydraulic excavator operations; Operate hydraulic excavator; Carry out operator maintenance; Carry out housekeeping activities.
About WH&S More SkillsEstablished in 1995, WH&S More Skills is a Registered Training Organisation that delivers outcomes for people working in the construction, manufacturing, transport, energy and mining industries. It is accredited to provide training and assessment for licences to perform high risk work (LHRW) and other competencies. It can provide formal training and assessment, refresher courses, verification's of competency and skills audits. The provider can also provide on-site and off-site training solutions. Licences to perform high risk work include: Dogging; Rigging (Basic, Intermediate and Advanced); Bridge & Gantry crane (CB); Mobile cranes; Forklifts; Elevated Work Platform; Vehicle Loading crane; Scaffolding; and Materials Hoist. Other competencies include Working Safely at Heights, Confined Space Entry, Earthmoving, Swing stage scaffold (user & installer), Gantry or Overhead crane (RII), Telehandler and EWP Yellow Card. Its 4,000 sqm training facility at Salisbury in Brisbane is equipped with eight training rooms and plant and equipment to undertake all training courses. It offers tailored training plans which integrate with clients safe operating procedures (SOP's) to ensure that training outcomes provide not just a licence for an employee but an overall understanding of how the training relates to their everyday work procedures and a safer working environment. It aims to create a model which delivers organisational cultural change, where a competent individual understands the plant they are being trained on as well as its relationship to an employer's SOP's. WH&S More Skills seeks long term relationships with clients to ensure a consistent training approach across different sites and an understanding of all safety aspects of their sites, plant and work processes. Its training schedule is updated regularly and can be found under 'Course Dates' on the provider's website. RTO code: 32365
StatementCourse code: RIIMPO301D
- Flexible Delivery
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Mobile Plant Operator
Mobile plant operators drive backhoes, bulldozers, excavators, front-end loaders, graders, scrapers, skid-steer loaders, rollers and forklift trucks to level, excavate, move and load earth, rock and other material.


text:
An Onalaska family is trying to get back on their feet after their home was destroyed by a fire.
Firefighters were called to the nine-hundred block of 6th Avenue North Friday morning.
When they arrived on scene flames were already coming from the garage.
The home-owner, Jennifer Smith, and her two daughters were not at home at the time of the fire.
Firefighters say the home is a total loss and the cause is still under investigation
A late morning fire destroys an Onalaska home.
Firefighters were called out to 911 6th Avenue North in Onalaska at about 11:30 am.
When firefighters arrived on scene the garage was fully engulfed in flames.
SLIDESHOW: Pictures from Fire
No one was home at the time, however some firefighters narrowly escaped injuries.
"We had the ceiling come down and take three firefighters out. Foruntately, they were not injured and the electrical box had sparks to the point that the firefighters couldn't attack from that corner," said Onalaska Fire Chief Don Dominick
Firefighters aren't sure of the cause of the fire, but neighbors may have information that could help.
"First she heard a boom. When she looked out the window she saw a bunch of light smoke. She couldn't tell what house it was."
The home is a total loss.


text:
What a difference a month can make
A little more than a month ago, I wrote about an egg factory farmer who left 50,000 egg-laying hens in cages without food and water for more than two weeks to die a slow, painful death. By the time animal control was alerted to their situation, most of the birds had perished. A few thousand … [Read more…]


text:
Sound: The Living End. Started off in the mid '90s, their unique blend of a broad range of musical genres have created a "bastard grandchild" of the Stray Cats, the Sex Pistols, The Beatles and The Clash. With this album, their 15 years of musical Nirvana has been reached with album number 5. Almost all elements that singer/guitarist Chris Cheney, double bassist Scott Owen and drummer Andy Strachan have strive to create have been reached, mixing Led Zeppelin-esque hardness with the bands own signature sound of Australian rock and roll. Ever since their first Self Titled album, the band has strive to broaden their horizons, with the next three albums attempting to catch their unparalleled live show. But now, with Rage Against The Machine producer John Agnello and the mixing capabilities of Brendan O'Brien-who before this album mixed the soon to be released AC/DC album-their mission=accomplished. Even with a serous breakup scare before the albums creation, the newly found sound has kept old and new fans begging for more. // 9
Lyrics: With Cheney's almost band-ending hiatus, the band has faced many a tragedy, but have now used this scare to their advantage. The more mature writing style adopted by Cheney have shades of seriousness mixed with strong thoughts yet also has hints of classic TLE.
01. How Do We Know - the Jack White/Jimmy Page riff that started the new 'flame'. The head-banging quality of this song is exquisite, with the lyrics complementing the desire to fight 'Til The End.
02. Raise The Alarm - songwriter-turned-philosopher Cheney expresses the arguments placed by religion, and provides an atheist/agnostic take on the matter. Could be played a little faster, but still a keeper.
03. White Noise - the first single highlights a more 'refined' sound of the band. With the lyrics providing questions of society today, the topic of hearing 'white noise' from everyone seems so real.
04. Moment In The Sun - with pop influences present, the lyrics provides a powerful message of breaking out while living in ones golden years while also providing it's listeners a smile. Piano parts by The Hold Steady's Franz Nicolay add a nice touch of inspiration.
05. Waiting For The Silence - pure TLE with a mix of simplistic yet heartfelt lyrics and meaningful feel.
06. Make The Call - very small hints of Maiden in the guitar work, but provides a perfect beat to jump around with.
07. Loaded Gun - possibly one of the top 10 Living End songs ever made. About the death of Jean Charles de Menezes after the London bombings, it highlights the problems in the law enforcement department and attacks the seneless 'collateral damage'.
08. Kid - the ultimate TLE pop song. So sweet the sugar sickens you. A bit too repetitive, but still a goodie.
09. 21st Century - a critical look upon the major events over the past years. Makes one ask "how the hell are we supposed to tell the kids?"
10. Hey Hey Disbeliever - another Maiden-influenced track. Simple tune mixed with tongue twister verses make up a solid song.
11. Sum Of Us - a completely unexpected reggae track, it somehow creates the perfect final song for the album. Lyrics provide a powerful message, and Owen's bass line is fitting to such a cool song. // 9
Overall Impression: Compared to their previous albums, it is somewhat a step away from the usual formula but also retains the hallmark TLE sound. Steering away from their S/T punkabilly sound, Roll On's complexity, Modern ARTillery's simplistic songs (except for The Room of course) and State Of Emergency's pop-punk sound, the album is an excellent addition to the bands repertoire. With this new album, the band has finally achieved what it was trying to do after S/T, and does it with flying colours. Although the 11 songs do create a break away from the traditional 14 songs, the album is all quality, not quantity, even after hearing some of their strongest B-sides. A definite keeper. // 10
Sound: The Living End have always been, since I first got into them in 2003, in my top 5 favourite bands of all time. But after listening to "White Noise", I was truly disappointed. It was sad to see these rockabilly boys from Melbourne, Australia had become another industry sellout. I thought they'd snap out of it after their previous work, "State of Emergency," but no, it wasn't to be. Chris Cheney, I was disappointed to see, has begun to dabble in modulation effects. I never thought I'd see the day where a Living End song was based on a riff with a heavy chorus over it. // 4
Lyrics: The lyrics are of the usual high standard that the Living End pulls out album after album. As they always have, the intelligence of their lyrics has progressed from the last album, but their growth seems to be slowing. The music and lyrics fit together well, with Chris Cheney's powerful lyrics and voice floating over the top of the newly buzz-cut Scott Owen's masterful double bass and Andy Strachan's skillful drums. // 8
Overall Impression: It compares badly to all previous albums, I must say. The only tracks that truly stand out are the title track "White Noise," and "How Do We know?" Which is the first track on the album. I won't pay $20 for a record with 2 good tracks on it. But The Living End can only go up from this stage of doing this pop punk bullshit. // 5
Billy Picken
Eamon Fethers
jason white


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Sporting a combination of fighting talk and dirty rock/metal embedding hooks...
'I've heard it all before!' shouts angry, growling 'Lzzy' front woman with Halestorm, on album opener 'It's Not You' – well unfortunately, her particular formulas is not exactly intuitive based. Sporting a combination of fighting talk and dirty rock/metal embedding hooks Halestorm's main flaw lies in their tendency to bury actual vocal ability behind obvious gruff singing patterns, (track 'What Were You Expecting?' Being the main perpetrator).
'Dirty Work' wouldn't be amiss in a downtown LA 80s heavy metal bar, but unfortunately times have changed drastically since then and while remaining unerringly true to their roots, they're not taking groundbreaking steps.
Let @rocksound know on Twitter
A little mayhem never hurt anyone.
For Ghost, anyway...
Prepare to mosh.
This is sweet.
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Facilities & Technology
Blackboard | Classrooms | Computers | Group Study | Printer/Copier/Scanner
Whether it is finding a space to meet for a group project, a one-time classroom session, or computers to use Photoshop, the Library Commons (LC) is available to you. Below are the facilities and technology that we support.
Blackboard is the course management system of the UO, used to host and access syllabi, assignments, grades, discussion tools and more. Students and faculty can log in using their UO username and password to access and create content. Starting Fall 2015, the UO will be switching to Canvas.
Classroom 103 (library classroom)
We have one seminar-style classroom with the capacity of 23. The use of the room is designated for academic activities and can only be reserved by faculty, graduate teaching fellows, teaching assistants, and staff. To make a request to use the classroom, please use LibCal to submit your reservation request. All requests will be reviewed within 24 hours and you will receive a response regarding your reservation (see the room usage policy for more information).
Other classrooms in GSH (117, 123, 130, 131, 132)
The library does not have the ability to make a reservation for the other classrooms in the GSH (117, 123, 130, 131, and 132). Classes are scheduled 8am - 5pm by the registrar. To request usage after 5pm, contact Catering and Conference Services.
There are 7 computers total in the Library Commons (LC). On the 1st floor in the main LC area there are 2 macs and 2 PCs located in carrels against the back of the room. After 5:30pm, upstairs in the mezzanine (room M104) there are 2 PCs and 1 mac that students could use (it is not available before 5:30pm). See the specifics of the hardware and software on the library computers on the Library Systems page.
Group study rooms
We have 4 group study rooms: one with the capacity of 3 and 3 others with the capacity of 6 people. Each group study room includes a display screen with computer input and a white board wall. It is used on a first-come first-served basis but reservations can be made using LibCal, the library's room reservation system. Reservations are limited to 2-hour time slots per day and need to be made 24 hours in advance. Each person can only reserve the rooms for up to 4 hours a week (see room usage policies for more information).
Upstairs in the mezzanine, M104, is available to students after 5:30pm Monday-Friday and all day on Saturday and Sunday. There are 2 PCs, 1 mac, a and a white board. It is used on a first-come first-served basis; reservations cannot be made for this room.
Printer, copier, scanner
A multipurpose color printer, photocopier, and scanner are available in the main LC area. Campus cash is required for printing. Black and white cost 8 cents ($0.08) per page and color printing cost 50 cents ($0.50) per page.
Wireless printing from your laptop is available after a small download. See the Library Systems page for more information about printing.


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Ink Innovations
Ink Innovations (www.inkinnovations.net) says it developed the new Ergo-Force Squeegee Blade for garment printers who wish to optimize the performance of Ink Innovations's aluminum Ergo-Force squeegee handle. According to the company, the 64-durometer Ergo-Force-Blade will deposit greater amounts of ink than typical 70- and 75-durometer blades, yet will have the feel of a stiffer blade, when installed in an Ergo-Force squeegee handle. Ink Innovations explains that the softer squeegee blade conforms better to irregularities of any given substrate and improves coverage significantly when printing over a white underbase. The purple, 64A, Ergo-Force-Blade is made of urethane, can be used with manual and automatic presses, and is made to the industry standard size of 2 in. (51 mm) wide by 0.375 in. (9.5 mm) thick. Each blade is imprinted with a Best Before date.
It is but normal for companies to have its ups and downs. Rolex, on the other hand, appeared to have success coming there way from every end. Rolex was the first to be known by replica watches Rating Center through a Swiss Certificate of Precision award given to one of its wristwatches in 1910, only two years after the brand name's inception. Four years after that, Rolex acquired another acknowledgment -- a class "A" precision certificate which was exclusive to marine watches, exclusive until the Rolex wristwatch that is. This is when the brand Rolex become synonymous to precision and exactness.
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Reuter, Chuck MSN, RN; Fitzsimons, Virginia EdD, RN, FAAN
Chuck Reuter is an army public health nurse in the New Jersey Army National Guard and Virginia Fitzsimons is a professor at Kean University, Union, NJ. Contact author: Chuck Reuter, firstname.lastname@example.com. The authors have disclosed no potential conflicts of interest, financial or otherwise.
Echoes from military and religious history.
The language of nursing has evolved as the profession has matured. The archaic expression doctor's orders, still used to describe the physician's plan of care for a patient, carries an unfortunate connotation of obedience for the nurses who carry out the plans.
The word order was used as early as the 14th century to refer to religious orders. Deep in our history are religious congregations of nurses, both female and male, who took lifetime vows of obedience. Order implies a world that places a high value on rank, class, or special power. We see this perhaps most clearly in the military uses of the word, as in "that's an order!"
Prior to and during Florence Nightingale's time, nurses were trained by physicians to monitor patients and report back. Nursing then was described as "applied hygiene." This is no longer the case, and it's troublesome that we remain subject to these authoritative commands we call physician orders.
Are nurses diminishing themselves by accepting orders? Enlisted members of the U.S. military take an oath to "obey the orders of the President of the United States and the orders of the officers appointed over me." Article 90 of the Uniform Code of Military Justice states that it is unlawful to disobey a lawful order from a superior commissioned officer. During times of war, it is punishable by death.
But nurses take no such oath, and are legally and ethically bound to question an inappropriate order from a physician. In fact, many actions described in physician's orders are simply nursing practices that are fundamental to health maintenance: turn and position every two hours, oral hygiene, side rails up.
The term physician's orders has outlived its appropriateness. Nurses have an ethical duty to be members of collaborative teams. Communication, consultation, and interdisciplinary cooperation are the benchmarks for quality outcomes. Other professionals communicate without issuing orders to each other—by continuing to use this phrase, nurses support a linguistic and symbolic discounting of their autonomous and accountable practice.
In accepting such language, nurses condone the underlying view that nurses are subordinate to the wishes of a physician. Physician orders are inherently authoritarian and transgress traditional etiquette. By contrast, nursing practice acts use language such as this from the New Jersey Nurse Practice Act: "executing medical regimens as prescribed by a licensed or otherwise legally authorized physician or dentist."
Virtually everything that is now called an order—all medications, diet, activity, consultations, and so on—can be called a prescription, a plan, or a regimen. When a physician gives a prescription or a recommendation to a nurse rather than an order, it reinforces a model of partnership and collaboration in patient care. Let's watch our language and strive for more descriptive terms.
In order to make other nurses aware of the importance of language and its effects on our image, nurses can advocate for our profession at individual institutions, bringing attention to such practices as referring to nurses as property of a physician, as in "Pat is Dr. Smith's nurse," or the habit of some physicians in referring to nurses as "the girls on the unit."
Or begin with asking a physician for the prescriptions rather than the orders when admitting a patient. At the next nursing meeting or roundtable in your institution, ask for the replacement of "physician orders" with "prescriptions" on the admission screen or at the next printing of forms. Acknowledge that these prescriptions aren't just from physicians, but are also from NPs and physician assistants.
We are not a lesser profession to order around. The language we use in everyday practice reflects how we perceive ourselves and how our colleagues and the public perceive and speak about us. We are licensed professionals, educators, leaders, lifesavers, and most of all, nurses. Language is power; change needs to begin here.
© 2013 Lippincott Williams & Wilkins. All rights reserved.
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My Latest Time Lapse Showreel
Night Rush Around The World 2
Camera and settings? and tell me about the in-car shots. Did you just stick a monopod out of the sunroof or did you cave a mount?
amazing stuff, really.
Very nice stuff.. do you have some footages for South Africa?
Quality beyond imagination
I was waiting for the opening credits expecting the latest 'Bourne Returns' movie! Very nice indeed.
H.Wolfgang Porter, Composite Media Producer Dreaded Enterprises Unlimited, Inc. www.dreadedenterprises.com


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Before it is even off the drawing board, the clubhouse at Donald Trump's Aberdeenshire golf development has won an award for Scotland's worst building. When one architect, Michael Rasmussen, suggested that the award was justified, Mr Trump's people dismissed his work as "parochial".
The Trump plan won a Zit, bestowed by the architecture magazine Urban Realm as part of its Carbuncle Awards. The nomination for Trump's Menie clubhouse on the magazine's website states: "The initial visuals show it to be uninspiring, unimaginative, and a building that strongly supports the perceived dreariness of Aberdeen."
Mr Rasmussen said that Mr Trump had


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Try Eurocamp Independent
Holidaying in Europe with your own tent, trailer tent, caravan or motorhome
Find a holiday
Step onto Bella Austria and get ready to explore the stunning natural surroundings of the Katschtal Valley.This parc was made for outdoor action; take your pick of scenic treks (walking maps are available at reception) or why not hire bikes and follow the cycle path to the nearby Mur River? When it's time to leave the great outdoors behind, you'll find a small selection of activities back on parc, including a traditional Austrian sauna and the opportunity to book a relaxing massage, too. Take time out from the kids' clubs and book the family on an excursion to discover the real Austria. Parc owners organise ad-hoc self-drive trips at various times throughout the summer - simply ask about availability when you arrive.
Parc size
Small - 230 Pitches:
Opening Dates:
28/04/2017 - 17/09/2017
Nearest Airport:
Klagenfurt (KLU) - 80km
Recommended Port:
Calais - 1274km
Nearest Town:
St Peter am Kammersberg - 2km
Try Eurocamp Independent
Holidaying in Europe with your own tent, trailer tent, caravan or motorhome
Imagine spending your next holiday in the 'sports capital' of Austria and exploring the beautiful, lush valley on your doorstep.Read more about this parc ›
Lose yourself in Les Ecrins National Park - an outdoor Alpine playground millions of years in the making, with rushing rivers and tumbling waterfalls aplenty.Read more about this parc ›
The wine region isn't the only little-known thing about Switzerland. Bella Tola parc is our only Swiss parc with a pool.Read more about this parc ›


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Radmanovic looks like his old self
Vladimir Radmanovic didn't want to talk about his performance against Portland on Sunday. He wasn't smiling. There were no jokes.
"It was just one game," he said, looking dour and annoyed when stopped by a group of reporters. "I took advantage of the chance I got. That's basically it. There's no big talk or philosophy about it. It is what it is."
The "it" was Radmanovic's first significant number of minutes since being demoted from a starter to near-non-existent status. The forward lost his starting role last month when Phil Jackson promoted Luke Walton to starter and put Radmanovic at the end of the bench.
But with Walton out (inflammed toe) and Trevor Ariza floundering in his first start, Radmanovic moved in and scored 16 points on 4-of-6 shooting and grabbed four rebounds in 18 minutes.
"The position I'm in right now is really frustrating," Radmanovic said. "I've tried not to bring it up because we have something really great going on here. But for me personally, from starting and playing decent I believe, to not playing at all is something im still trying to understand and figure out. Whenever I get a chance to play, as a professional, I have to contribute as much as I can."
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Today, my girlfriend and I broke up. When I got home from work, I came home to glitter. EVERYWHERE. Guess who forgot to get the key to his apartment back from his ex-girlfriend. The guy who's having his family over for dinner tonight. FML
by Anonymous / 09/15/2010 at 7:34pm / United States (Texas) / Love
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Whoever said America is the capital of ridiculous lawsuits might want to reconsider. In the UK, an eBay seller is looking to take one of his customers to court for libel over some bad feedback left on his ebay account. Yes, you read correctly, over some bad eBay feedback.
When Chris Read received a cell phone he purchased for £155, he said it was not only scratched and not in the new condition in which it was advertised, it was also the WRONG PHONE. Not wishing to get stuck with something that he did not order, he sent it back, got the refund, then left negative feedback on the seller's profile that said the following:
"Item was scratched, chipped and not the model advertised on Mr Jones's eBay account."
Well apparently the seller "Mr. Jones" did not take very kindly to this seemingly honest recount of the transaction that took place, and he wasn't going to take it:
"I am being punished on eBay because of this as sellers who have negative feedback appear lower down the screen in searches than other people. I'm losing money by the day and my business could go under because of it. I've been left with no option but to take legal action."
Call me crazy, biased, whatever, but if this is true, Jones is being punished on eBay because HE screwed up. If the seller's feedback was unwarranted, then the correct step would have been to appeal to eBay directly, prove that the comments were not accurate, at which point, they would remove them. eBay has measures that protect sellers against habitual "down-voters" and I'll bet "Mr. Jones" did try that, at which point eBay probably laughed in his face.
Barring the obvious fact that a libel suit has to be over an allegation that is actually FALSE, the whole premise is absurd and it just goes to show that you need to be careful when dealing with people on eBay.


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- Genre: Drama, Josei, Slice Of Life
- Status:Ongoing
A letter comes to the three Kohda sisters in Kamakura, bringing the news of their father's death. A father they hadn't seen since he divorced and left home 15 years ago. Despite feeling indifferent about their father, Yoshino, the middle of the three, and Chika, the youngest, go to Yamagata to attend his funeral on oldest sister Sachi's request. There, they meet Suzu, their young and reliable half sister. Umimachi Diary won the Excellence Prize for manga at the 2007 Japan Media Arts Festival Awards. It was also nominated for the 1st Manga Taisho, where it came in 3rd place, for the 12th Tezuka Osamu Cultural Prize, where it came in 2nd place, and for the 13th Tezuka Osamu Cultural Prize.
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- Volume 1
- 4 years agoUmimachi Diary 2: The Fox of Sasuke
- 4 years agoUmimachi Diary 1: When Cicada's Season is Over
By editing this manga you will earn the editor title for this manga!


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Some 20% of sea pollution comes from the deliberate dumping of oil and other wastes from ships, from accidental spills and offshore oil drilling. But of all the sources of marine pollution, the discharge of oily engine wastes and bilge from day-to-day shipping operations may be the worst, because it is steady and occurs everywhere.
Even low levels of contamination can kill larvae and cause disease. Oil slicks kill birds, marine mammals and fish, particularly near coasts, and coagulated oil destroys coastal habitats.
At the beginning of UNEP's work in the Regional Seas, legal agreements dealing with marine pollution tended to focus on sea-based sources, particularly the deliberate dumping of oil and other wastes and spills from maritime accidents and offshore oil drilling. One of the earliest global marine conventions the 1972 London Dumping Convention, was designed to prevent ship-related pollution, paved the way for the first Regional Seas protocol to address the topic: the 1976 Protocol for the Prevention and Elimination of Pollution of the Mediterranean Sea by Dumping from Ships and Aircraft.
In the run-up to WSSD, the Regional Seas programmes identified ship-generated marine pollution, oil spill preparedness and response, and construction of port reception facilities for ships' wastes as a priority.


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Seamless construction and soft fabric that melts onto your body, for comfort unlike any you've experienced before! Discreet nursing clips lay flat under clothing. Removable molded foam cups for the option of a thicker cup lining to hide nipples and breast pads when you need it. Great for maternity use! Colors: Ivory, Butterscotch, Black. Sizes: S, M, L, XL. (See fit tips for sizing chart).
Style #1401 from Bravado. Everyday Value $49.00


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Our policy is that any event with a sound system, wireless microphones or live-streaming must be staffed by one of our full-time techs or workstudy students. To better ensure that we are able to staff your event, we ask that you put in your request at least four weeks ahead of your event date. To request that your event be recorded, simply select "Audio Recording" or "Video Recording" out of the Resources List. You will be contacted by Media Production Services concerning the details of your event within the next two business days. If you do not receive an email from MPS, or have questions regarding event recording, email us at firstname.lastname@example.com.
25Live is the University-wide system for requesting rooms, equipment, and recording for your events. In this system, all requests are categorized into an "event," to which all other resources are linked. This makes it easy to reserve a room, request equipment, and ask for your event to be recorded all in the same form.
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While we wish we could record every event for free, the constraints of time and money mean that we must charge for the majority of events we service. These charges allow us to keep our services consistent and at the highest quality we can provide. Charges for labor are applied hourly, and the final bill will be broken up into 15-minute increments. A minimum charge of $15 will be applied in all cases. Charges for media (i.e. DVD copies of the recording) are applied per disc. For more information, follow the charts below.
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Blue Creek Elementary was selected by North Carolina Beautiful to receive a special beautification prize of 50 azaleas for use in the group's 2009 beatification projects. The award is part of the North Carolina Beautiful's 24th annual Azalea Celebration, which rewards groups for improving their communities through creative landscape projects.
Jenny Johnson, 2nd Grade teacher at Blue Creek Elementary, submitted the entry on behalf of the school. The winning project is to beautify the area around the school's library in the hopes of someday creating an outdoor classroom space. The azaleas will be placed on the perimeter of the area to create a great place to go outdoors and read, teach, and learn.
North Carolina Beautiful has focused on merit-based programs which provide hands-on experience in preserving resources and promoting constructive action toward environmental stewardship.
Copyright © 2016 Onslow County School System


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Here is a table of technical characteristics of the sub-notebooks side by side:
As a final word I want to say that there are no downright bad models among the tested sub-notebooks among the models tested in this part of the roundup. There are devices that didn't leave the best possible impression, but there were just excellent samples, too. I hope you have got some useful information from this roundup.
The choice is yours!


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Trenton, New Jersey 86190
United States
|Areas of Practice
|1) Bankruptcy Law, 2) Commercial Law, 3) Litigation, 4) Creditor Bankruptcy Law, 5) Debtor Bankruptcy Law and 6) Collection Law
|Bradley University (B.S., 1969)
|Most recent firm
|Teich Groh
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USA-NJ-East Hanover
Mid-sized insurance defense firm seeking a full time legal secretary with 5+ years experience. Must be familiar with insurance defense litigation, pleadings and discovery process of NJ State and ...
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Patent Paralegal
Expanding boutique Intellectual Property law firm is seeking a paralegal to support attorneys in all aspects of U.S. and foreign patent prosecution. This is an opportunity to build a valuable, speci...
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A. Harrison Barnes is a well-known attorney throughout the United States. As a member of the Malibu community, Harrison is committed to serving the needs of Malibu residents and businesses in legal matters.
Benjamin P. Smith is a partner in Morgan Lewis's Litigation Practice. He is a trial lawyer with a particular focus on high-stakes disputes in the biotechnology, medical device, and internet industries.


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Damien2+ weeks old
Is there a way I can search only for luxury apartments on your website? It's hard to tell from most of the descriptions and is taking more time to look which I don't have. I want to be able to find 3 places to go check out I want a place with 2 bedrooms, plenty of privacy and top notch security, maintenance and amenities.
Is there a way I can search only for ...


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UK Government names Mark Carney as new Bank Governor
26 November 2012
Bank of Canada Governor Mark Carney will succeed Mervyn King as head of the Bank of England next year, the UK government announced Monday.
In a major coup for Chancellor of the Exchequer George Osborne, Carney will succeed King when he retires in June.
Carney is one of the world's top central bankers. As head of the Financial Stability Board, he is tasked with implementing the regulatory agenda of the Group of 20 leading industrialised and emerging economies.
"He is the most outstanding central banker of his generation," Osborne said.
Osborne added that Carney will serve as BoE governor for five years, three years less than the maximum term.
Write to Jason Douglas at email@example.com


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Through its Climate Mission Goal, NOAA advances scientific understanding of Earth's climate system through sustained observations and monitoring, integrated environmental modeling, and interdisciplinary research. Substantial progress has been made over the last several decades in observations, modeling, and understanding, but the mission remains incomplete. Key scientific uncertainties limit scientists' ability to understand and forecast changes in the climate system. The factors responsible for climate forcing, and those underlying climate variability and change, need to be better characterized and quantified.
To accomplish this Objective, advances need to be made across a broad array of NOAA-sponsored activities, including:
Improvements in climate attribution research are needed to better interpret causes of past, current, and evolving regional climate conditions and their dependence on the larger-scale climate.
Improving the skill of seasonal and intra-seasonal climate forecasts will require engaging more fully with the extramural research community, increasing the members of multi-model ensembles, improving operational data assimilation schemes, and identifying systematic errors in the models.
Early warning systems for critical thresholds and transitions across climate-relevant time and space scales are also needed, including completing the National Integrated Drought Information System (or NIDIS, online at www.drought.gov) and regional early warning system prototypes as resources permit.


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Cuban OK without D-Will, but goes off on KiddCuban said he missed a call from Kidd because the owner and his family were in a D.C. Kidd wasn't the only player to leave from last year's roster but he was the one whose departure made owner Mark Cuban say today: "I was pissed." Cuban went on ESPN Radio… (more)Sources: ESPN.com yahoo.com dimemag.com
Mark Cuban Says Mavs Don't Need Deron Williams; Blake Griffin Makes A ChangeMark Cuban went through a spell during the Mavs' championship run in 2011 where he was as quiet as we've ever heard him. He made no headlines, said no controversial things and didn't even get fined by the NBA. He's making up for lost time this sumSource: dimemag.com


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Economics Departments, Institutes and Research Centers in the World
Economic Commission for Africa
United NationsLocation: Addis Ababa, Ethiopia
Homepage: http://www.uneca.org/
Handle: RePEc:edi:unecaet
Areas or Functions: International Organizations Areas or Functions: International Organizations, Countrywide Studies
Additional details:
People who have registered with RePEc and have claimed to be affiliated with this institution:Find all publications of all authors listed below conveniently compiled on IDEAS. Authors with publications are listed below with . We have lost contact with authors marked with ?, and they do not count towards the ranking of this institution.
- Atta-Mensah, Joseph
- Baek, Seung-Jin
- Chinzara, Zivanemoyo
- Chavula, Hopestone Kayiska
- Karingi, Stephen Njuguna
- Kinda, Somlanare Romuald
- Macculi, Iris
- Oulmane, Nassim
- Valensisi, Giovanni
- Ziegelhöfer, Zacharias
This listing is provided to you by EDIRC at the Economic Research Department, Federal Reserve Bank of St. Louis.
Please send additions and corrections to Christian Zimmermann.


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Today, for my birthday, the only "gift" my parents gave me was the gift of choice: I got to choose which one of them I'll be living with after their upcoming divorce. This was the first time I'd heard anything about a divorce. FML
by HappyBirthdayISuppose / 04/01/2013 at 1:03am / United States (Colorado) / Miscellaneous
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How to Hold a Glamour Party!
The glamour Parties are just soo much fun! But make sure your hostess has done a Skin Care Class first! Mary Kay always said, "If you paint on a bad canvas, the picture just won't look as good." In our case, the canvas is our face! Great skin care provides a great canvas, so makeup will look more polished!
Your Hostess is the only one who is getting a FULL CUSTOMIZED LOOK! All of her guests will just get color sampler cards to play with! This will entice them to host their own party so they too will get a full customized look!
- I highly recommend each consultant to have their very own ColorInsider Book & ColorInsider DVD. It can be purchase on www.marykayintouch.com under Section 2.
- Attend any Glamour Training you can get your hands on at your weekly meetings & guests events
- Check out Makeup Artist Robert Jones — he has workshops and great learning tools
What to do Before the Glamour Class:
- Find out what kind of look your customerCreate your hostesses Customized Glamour Look on the Beauty Profiler on www.marykayintouch.com
- Click here for a list of what to pack for a Glamour Class!
- Click here for the Glamour Order of Application….you will need one of these for the hostess only!
- Click here for the Color Roll Up Bag…you will need one of these for the hostess only, your guests receive the Roll-Up Bag Placemat!
- Click here for the Half Back Hostess Card
- Click here for the Half Back letter you'll want to give each guest during the individual consultation as they book their color appointment.
At The Glamour Class:
- Before Guests Arrive – set up their trays and organize yourself!
- As Guests Arrive – introduce yourself!
- When Class Starts – memorize flip chart verbatim!
- After Class is Completed – individual close with each guest in a separate location from the group…this provides a more personal setting for you to build a relationship with each person there.
- Click here for a breakdown on what your individual close should sound like!