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Patent application title: Hair-Styling Foil and Method For Preparing Hair-Fixing Products in Foil Form
Sarah Maillefer (Middes, CH)
Benedikt Zenhaeusern (Giffers, CH)
Ute Doepner-Reichenbach (Koenigstein, DE)
Monika Moenks (Schmitten, CH)
Karin Steinbrecht (Ober-Ramstadt, DE)
IPC8 Class: AA45D1918FI
USPC Class:
Class name: Toilet hair device including means to isolate or part a tress of hair for chemical treatment (e.g., frosting cap or purse)
Publication date: 2008-09-18
Patent application number: 20080223395
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A method for producing a hair-fixing product in the form of a foil is
described whereby first a viscous, rollable composition is prepared by
dissolving or dispersing a polymer in a liquid carrier medium and then
the composition is shaped into a foil by rolling it with the aid of a
rolling device and the liquid carrier medium is evaporated. Also
described are hair-styling foils that contain at least one hair-fixing
polymer and advantageously additional surfactants or polyols and that
preferably are treated with an adhering, powdered, hydrophobic release
1. Method for producing a hair-fixing product in the form of a foil
wherebyfirst a rollable composition is prepared by dissolving or
dispersing a polymer in a liquid carrier medium andthen by means of a
rolling device the composition is rolled into foil shape andat the same
time or subsequently the liquid carrier medium is evaporated.
2. Method as defined in claim 1, characterized in that the polymer is a foil-forming and/or hair-fixing polymer.
3. Method as defined in claim 1, characterized in that the liquid carrier medium is selected from among water, alcohols, ethers, ketones and hydrocarbons and mixtures of said substances, provided that the substance or mixture of substances is liquid at room temperature (25 θC).
4. Method as defined in claim 1, characterized in that the rollable composition contains the polymer in an amount from 10 to 80 wt. % and the liquid carrier medium in an amount from 20 to 90 wt. %.
5. Method as defined in claim 1, characterized in that after evaporation of the liquid carrier medium the amount of polymer in the foil is from 50 to 97 wt. %.
6. Method as defined in claim 1, characterized in that the composition contains at least one water-soluble polymer.
7. Method as defined in claim 1, characterized in that the composition contains pullulan.
8. Method as defined in claim 7, characterized in that the pullulan has an average molecular weight from 10,000 to 5,000,000.
9. Method as defined in claim 7, characterized in that the composition contains at least one additional hair-fixing polymer.
10. Method as defined in claim 9, characterized in that the weight ratio of pullulan to the additional hair-fixing polymer is from 1:10 to 10:1.
11. Method as defined in claim 10, characterized in that the additional hair-fixing polymer is selectedfrom among polymers derived from at least one monomer selected from among vinyllactams, vinyl esters, vinyl alcohols, acrylamides, methacrylamides, alkylacrylamides, dialkylacrylamides, alkylmethacrylamides, dialkylmethacrylamides, dialkylaminoalkylmethacrylamides, dialkylaminoalkylacrylamides, alkyl acrylates, alkyl methacrylates, propylene glycol and ethylene glycol;from among polymers derived from at least one monomer selected from among acrylic acid, methacrylic acid, crotonic acid, maleic acid, maleic anhydride and monoesters of maleic acid;from among polymers derived from at least one monomer selected from among trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium, alkylvinylimidazolium, alkylvinylpyridinium and alkylvinylpyrrolidone;from among polymers derived from at least one kind of monomer containing acid groups and from at least one other kind of monomer containing basic amino groups;from among polymers derived from at least one kind of monomer containing both quaternary amino groups and acid groups or from polymers derived from at least one first kind of monomer containing quaternary amino groups and at least one second kind of monomer containing acid groups.
12. Method as defined in claim 11, characterized in that the additional polymer is selected from among polyvinylpyrrolidone, polyvinylcaprolactam, polyacrylamides, vinylpyrrolidone/vinyl acetate copolymer, crosslinked and uncrosslinked vinyl acetate/-crotonic acid copolymers, terpolymers of vinylpyrrolidone, vinyl acetate and vinyl alkanoate, terpolymers of vinyl acetate, crotonate and vinyl alkanoate, partly esterified copolymers of vinyl methyl ether and maleic anhydride, copolymers of acrylic acid and/or methacrylic acid and alkyl acrylates, alkyl methacrylates, N-alkylacrylamides, N-alkyl-methacrylamides, and/or polystyrene sulfonates, copolymers of alkylacrylamide, alkylaminoalkyl methacrylate and two or more monomers selected from among acrylic acid, methacrylic acid or the C1 to C4 alkyl esters thereof, with at least one of the monomers containing an acid group; copolymers of acrylic acid, methacrylate and methacrylamido-propyltrimethylammonium chloride, copolymers of acrylamidopropyltrimethylammonium chloride and acrylates, copolymers of acrylamide, acrylamidopropyltrimethylammonium chloride, 2-amidopropylacrylamido sulfonate and dimethylaminopropylamine, copolymers of methacryloylethylbetaine and two or more monomers selected from among acrylic acid or the simple esters thereof, methylvinylimidazolium chloride/vinylpyrrolidone copolymers, polyvinylpyrrolidone/dialkylaminoalkyl methacrylate copolymers, quaternized vinylpyrrolidone/dialkylaminoalkyl methacrylate copolymers, homopolymers of dimethyldiallylammonium chloride, copolymers of dimethyldiallylammonium chloride and at least one other monomer, quaternized hydroxyethylcellulose or quaternized guar derivatives, terpolymers of vinylpyrrolidone, vinylcaprolactam and a basic acrylamide monomer or methacrylamide monomer and vinylpyrrolidone/methacrylamidoalkyltrimethylammonium chloride copolymers.
13. Method as defined in claim 1, characterized in that the foil additionally contains at least one substance selected from among emulsifiers, softeners, hair luster-imparting agents, preservatives, fragrances, pigments, product tinting agents and water-insoluble particulate solids.
14. Method as defined in claim 1, characterized in that the thickness of the foil after rolling is less than 0.5 mm.
15. Method as defined in one of the preceding claims, characterized in that gas bubbles are introduced into the foil.
16. Hair-styling foil made by a method as defined in claim 1.
17. Hair-styling foil containing at least 85 wt. % of at least one hair-fixing polymer and more than 3 wt. % of at least one surfactant.
18. Hair-styling foil as defined in claim 17, characterized in that the hair-fixing polymer is selected from among polysaccharide-based polymers and nonionic synthetic polymers.
19. Hair-styling foil as defined in claim 18, characterized in that it contains as the hair-fixing polymer a combination of (a) pullulan and (b) at least one polymer selected from among polyvinylpyrrolidone and polyvinylpyrrolidone/vinyl acetate copolymer, the weight ratio of (a) to (b) being less than 1:1.
20. Hair-styling foil as defined in claim 17, characterized in that the surfactant used is a mixture of at least one cationic and at least one nonionic surfactant, the weight ratio of the cationic to the nonionic surfactant being 1:10 to 10:1.
21. Hair-styling foil containing at least 50 wt. % of hair-fixing polymers and containing pullulan in combination with at least one additional hair-fixing polymer, the weight ratio of pullulan to the additional hair-fixing polymer being less than 1:1.
22. Hair-styling foil as defined in claim 21, characterized in that it contains pullulan in an amount from 15 to 45 wt. % and the additional hair-fixing polymer in an amount from 30 to 70 wt. %, provided that the weight ratio of pullulan to the additional hair-fixing polymer is less than 1:1.
23. Hair-styling foil as defined in claim 17, characterized in that the foil thickness is less than 0.5 mm.
24. Hair-styling foil as defined in claim 17, characterized in that it contains enclosed air bubbles.
25. Hair-styling foil as defined in claim 17, characterized in that additionally it contains at least one polyol.
26. Hair-styling foil as defined in claim 25, characterized in that it contains the polyols in an amount from 1 to 50 wt. % and that said polyols are selected from among glycols, glycerols, sugar alcohols and polyethylene glycols that are liquid at 25 νC.
27. Hair-styling foil containing at least 50 wt. % of hair-fixing polymers, characterized in that the foil is treated with a powdered release agent adhering to the foil.
[0001]The invention has for an object a method for preparing hair-fixing
products in foil form as well as hair-treating agents for fixing hair in
the form of a solid, water-soluble foil, particularly one based on
pullulan and optionally on additional hair-fixing polymers.
[0002]To fix human hair and impart hold to it or to stabilize a completed hairdo, hair-treating agents are used which as a rule are in the form of gels, foams, sprays or lotions based on fluid solvents. The drawback of such solvent-based products is that because of the high solvent and/or propellant content, they are voluminous and heavy and, hence, are not well suited for being carried along by a person. This problem is normally solved by packing the products into very small containers. Such products have the drawback that they are sufficient for only very few applications. Moreover, it is not possible to package them as early as at the time of their preparation as solid, discrete pieces sufficient for an application. Spatial shaping and the preparation of attractive external forms are also not possible. Moreover, low-viscosity gels or thixotropic gels capable of liquefying under pressure can flow off the hands or hair during use.
[0003]JP 01-131109 discloses hair-treating agents in the form of sheets or plates which are prepared by casting a solution into molds and evaporating the solvent. Such sheets or plates are still not entirely satisfactory, particularly as regards surface uniformity, product thickness and related application properties, for example the dissolution rate during use.
[0004]From EP 1 137 916 are known films containing pullulan or modified starch and which are prepared via breakdown of the starch of certain starch derivatives and by drawing a film using the knife-over-roll coating method and overnight conditioning. Although the described films are soluble in glass containing 37° C. water, the dissolution performance relevant for uses as a hair styling foil on moist hands or moist hair is not satisfactory. The knife-over-roll coating method as a rule allows only the preparation of coatings that are 0.5 mm thick. Typical attainable coating thicknesses are 1 to 30 mm. Films having such a thickness do not exhibit satisfactory dissolution characteristics for use as hair-styling foils.
[0005]The purpose of the invention was to provide essentially solvent-free foils which upon contact with moisture, namely with a relatively small amount of water, could readily be made to dissolve by rubbing them with the hands and which after having been worked into the hair would exert a hair-fixing action and permit the shaping of the hair into a hairdo. Rubbing was not supposed to leave behind softened, undissolved foil particles which during styling of the hairdo could lead to undesirable visible or perceivable residues on the head.
[0006]The foils were to be stackable and/or so flexible that they could be rolled up. They were to be resistant to air humidity to an extent such that upon direct contact with one another they would not stick together and even upon extended storage would readily be detached from one another.
[0007]The invention has for an object a method for preparing a hair-fixing product in the form of a foil by [0008]first preparing a rollable composition by dissolving or dispersing a polymer in a liquid carrier medium, then [0009]shaping the composition into a foil by means of a rolling device and [0010]at the same time or subsequently evaporating the liquid carrier medium.
[0011]The invention also has for an object hair-styling foils, particularly hair-styling foils prepared according to the invention, and the use of said foils for hair fixing.
[0012]The rollable composition can have a semisolid, doughy consistency or it can consist of a viscous liquid used to coat an appropriate carrier the desired foil thickness being obtained by rolling on a rolling device. After drying, the finished foil is removed from the carrier.
[0013]Suitable carrier materials are, for example, silicones, metals, metallized polymers, polytetrafluoroethylene, polyether/polyamide block copolymers, polyurethanes, polyvinyl chloride, nylon, alkylene/styrene copolymers, polyethylene, polyesters or other detachable materials. Suitable rolling devices are, in particular, those known to persons skilled in the art of coating and painting technology and which are provided with at least two drums or rollers moving in the opposite direction and known as the forward-roll or reverse-roll coaters of which the reverse-roll method is preferred.
[0014]A foil in the sense of the invention is a solid, essentially solvent-free product of planar, flat geometry and having a thickness that is preferably less than or equal to 1 mm and particularly less than 0.5 mm, for example from 0.05 mm to less than 0.5 mm. The residual solvent content is preferably less than 5 wt. % and particularly less than 1 wt. %.
[0015]Suitable polymers include those that by themselves already exhibit foil-forming and/or hair-fixing properties. It is also possible, however, to use mixtures of polymers so that after evaporation of the solvent the mixture exhibits foil-forming and/or hair-fixing properties. The polymer content of the rollable composition can range from 10 to 80 wt. %, from 20 to 70 wt. % or from 30 to 60 wt. %. After evaporation of the liquid carrier medium, the polymer content of the finished foil can range from 50 to 97 wt. %, from 60 to 95 wt. % or from 80 to 95 wt. %, a content greater than or equal to 85 wt. % being particularly preferred.
[0016]Preferably, at least one of the polymers used is water-soluble. Pullulan is particularly preferred. A suitable pullulan can have an average molecular weight Mr of 10,000 to 5,000,000. Preferably, the composition contains at least one hair-fixing polymer and particularly a combination of pullulan and at least one hair-fixing polymer. The weight ratio of pullulan to the additional, hair-fixing polymer can range from 1:10 to 10:1 and particularly from 1:5 to 5:1 or from 1:2 to 2:1. The ratio is preferably less than 2:1 and most preferably less than 1:1, for example from 1:2 to less than 1:1.
[0017]The hair-fixing polymer can be selected from among anionic, cationic, zwitterionic, nonionic and amphoteric polymers. The polymer can be natural or synthetic. By synthetic polymers are meant polymers which are entirely synthetic and not of natural origin, in particular polymers that can be prepared by free radical-initiated polymerization of ethylenically unsaturated monomers or by polycondensation. By natural polymers are meant polymers of natural origin which subsequently may have been modified chemically or physically. Preferred in particular, however, are polymers that have adequate solubility or dispersibility in the carrier medium, particularly in water, alcohol or water/alcohol mixtures so that in the carrier medium they are present in dissolved or uniformly dispersed form. By hair-fixing polymers are meant according to the invention polymers which when applied as a 0.01 to 5% aqueous, alcoholic or aqueous-alcoholic solution or dispersion are capable of depositing a polymer film on the hair thus fixing the hair.
[0018]Suitable nonionic polymers are homopolymers or copolymers derived from at least one of the following monomers: vinyllactams, particularly vinyl pyrrolidone and vinyl caprolactam, vinyl esters, for example vinyl acetate, vinyl alcohols, acrylamides, methacrylamides, alkyl acrylamides, dialkylacrylamides, alkylmethacrylamides, dialkylmethacrylamides, dialkylaminoalkylmethacrylamides, dialkylaminoalkylacrylamides, alkyl acrylates, alkyl methacrylates, propylene glycol and ethylene glycol, the alkyl groups of these monomers preferably being C1 to C7 alkyl groups and particularly C1 to C3 alkyl groups. Suitable are, for example, the homopolymers of vinylcaprolactam, of vinylpyrrolidone and of N-vinylformamide. Other suitable synthetic film-forming, nonionic, hair-fixing polymers are, for example, the copolymers of vinylpyrrolidone and vinyl acetate, the terpolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate and furthermore polyacrylamides, polyvinyl alcohols and polyethylene glycol/polypropylene glycol copolymers. Particularly preferred are polyvinylpyrrolidone, polyvinylcaprolactam and the copolymers thereof with at least one other nonionic monomer, particularly polyvinylpyrrolidone/vinyl acetate copolymers.
[0019]Suitable anionic hair-fixing polymers are, for example, synthetic homopolymers and copolymers comprising acid groups-containing monomer units, optionally copolymerized with comonomers devoid of acid groups. The acid groups are preferably selected from among --COOH, --SO3H, --OSO3H, --OPO2H and --OPO3H2 among which the carboxyl group is preferred. The acid groups can be unneutralized, partly neutralized or completely neutralized. They are preferably 50 to 100% in anionic or neutralized form. Appropriate neutralizing agents are organic and inorganic bases suitable for cosmetic purposes. Examples of such bases are aminoalcohols, for example aminomethylpropanol (AMP), triethanolamine, monoethanolamine, tetrahydroxypropylethylenediamine, ammonia, NaOH and others. Suitable monomers are unsaturated, free radical-polymerizable compounds with at least one acid group, particularly carboxyvinyl monomers. Suitable acid groups-containing monomers are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid or maleic anhydride and the monoesters thereof.
[0020]Comonomers not substituted with acid groups are, for example, acrylamide, methacrylamide, alkylacrylamide, dialkylacrylamide, alkylmethacrylamide, dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, vinylcaprolactone, vinylpyrrolidone, vinyl esters, vinyl alcohol, propylene glycol, ethylene glycol, amino-substituted vinyl monomers, for example dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate and monoalkylaminoalkyl methacrylate, the alkyl groups of these monomers preferably being C1 to C7 alkyl groups and particularly C1 to C3 alkyl groups.
[0021]Suitable anionic polymers are, in particular, the copolymers of acrylic acid or methacrylic acid with monomers selected from among acrylate or methacrylate esters, acrylamides, methacrylamides and vinylpyrrolidone, homopolymers of crotonic acid and copolymers of crotonic acid with monomers selected from among vinyl esters, esters of acrylic acid or methacrylic acid, acrylamides and methacrylamides. A suitable natural polymer is, for example, shellac. Preferred anionic polymers are the crosslinked and uncrosslinked vinyl acetate/crotonic acid copolymers. Also preferred are the partly esterified copolymers of vinyl methyl ether and maleic anhydride. Other preferred anionic polymers are, for example, the terpolymers of acrylic acid, alkyl acrylate and N-alkylacrylamide and particularly the terpolymers of acrylic acid/ethyl acrylate/N-tert. butylacrylamide and the terpolymers of vinyl acetate, crotonate and vinyl alkanoate, particularly vinyl acetate/crotonate/vinylneodecanoate copolymers; the copolymers of acrylic acid or methacrylic acid and alkyl acrylate or alkyl-methacrylate esters, the alkyl groups preferably containing 1 to 7 carbon atoms, and polystyrenesulfonates
[0022]Suitable hair-fixing amphoteric or zwitterionic polymers are polymers which besides acid or anionic groups contain as additional functional groups basic or cationic groups, particularly primary, secondary, tertiary or quaternary amino groups. Zwitterionic polymers are polymers derived from at least one kind of monomer containing both quaternary amino groups and acid groups, or polymers derived from at least one first kind of monomer containing quaternary amino groups and at least of one second kind of monomer containing acid groups. Amphoteric polymers are derived, for example, from at least one kind of monomer containing acid groups and at least one other kind of monomer containing basic amino groups. Examples of these are the copolymers derived from alkylacrylamide (particularly octylacrylamide), alkylaminoalkyl methacrylate (particularly tert.butylaminoethyl methacrylate) and two or more monomers selected from among acrylic acid, methacrylic acid and the C1 to C4 alkyl esters thereof, among which at least one of the monomers has an acid group, examples being the products available under the tradenames Amphomer® or Amphomer® LV-71.
[0023]Other suitable polymers are the copolymers of acrylic acid, methyl acrylate and methacrylamidopropyltrimethylammonium chloride (INCI designation: Polyquaternium-47), the copolymers of acrylamidopropyltrimethylammonium chloride and acrylates, and the copolymers of acrylamide, acrylamidopropyltrimethylammonium chloride, 2-amidopropylacrylamide sulfonate and dimethylaminopropylamine (INCI designation: Polyquaternium-43). Also suitable are polymers containing a betaine group, for example the copolymers of methacryloylethyllbetaine and two or more monomers of acrylic acid or the simple esters thereof, known under the INCI designation Methacryloyl Ethyl Betaines/Acrylates Copolymer.
[0024]Suitable cationic polymers preferably contain quaternary amino groups. The cationic polymers can be homopolymers or copolymers, with the quaternary nitrogen groups being located either in the polymer chain or preferably as a substituent in one or more of the monomers. The monomers containing ammonium groups may be copolymerized with noncationic monomers. Suitable cationic monomers are the unsaturated, free radical-polymerizable compounds containing at least one cationic group, particularly the ammonium-substituted vinyl monomers, for example trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers with groups containing cyclic cationic nitrogen such as pyridinium, imidazolium and quaternary pyrrolidones, for example alkylvinylimidazolium and alkylvinylpyridinium, or alkylvinylpyrrolidone salts. The alkyl groups of these monomers are preferably the lower alkyl groups, for example C1 to C7 alkyl groups and most preferably C1 to C3 alkyl groups. The monomers containing ammonium groups may be copolymerized with noncationic monomers. Suitable comonomers are, for example, acrylamide, methacrylamide, alkylacrylamide, dialkylacrylamide, alkyl methacrylamide, dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, vinylcaprolactone, vinylcaprolactam, vinylpyrrolidone, vinyl esters, for example vinyl acetate, vinyl alcohol, propylene glycol and ethylene glycol, the alkyl groups of these monomers preferably being C1 to C7 or C1 to C3 alkyl groups.
[0025]Cationic polymers with quaternary amino groups are, for example, the polymers described in the CTFA Cosmetic Ingredient Dictionary under the designation Polyquaternium, for example methylvinylimidazolium chloride/vinylpyrrolidone copolymer (Polyquaternium-16) or the quaternized vinylpyrrolidone/dimethylaminoethyl methacrylate copolymer (Polyquaternium-11) as well as the quaternary silicone polymers and oligomers, for example the silicone polymers with quaternary end groups (Quaternium-80). Suitable among the cationic polymers is, for example, the vinylpyrrolidone/dimethylaminoethyl methacrylate methosulfate copolymer sold under the tradenames Gafquat® 755 N and Gafquat® 734. Other cationic polymers are, for example, the copolymer of polyvinylpyrrolidone and imidazolimine methochloride sold under the tradename LUVIQUAT® HM 550, the terpolymer of dimethyldiallylammonium chloride, sodium acrylate and acrylamide sold under the tradename Merquat® Plus 3300, the terpolymer of vinylpyrrolidone, dimethylaminoethyl methacrylate and vinylcaprolactam sold under the tradename Gaffix® VC 713 and the vinylpyrrolidone/methacrylamidopropyltrimethylammonium chloride copolymer sold under the tradename Gafquat® HS 100.
[0026]Suitable cationic polymers derived from natural polymers are the cationic derivatives of polysaccharides, for example the cationic derivatives of cellulose, starch or guar. Also suitable are chitosan and chitosan derivatives. The cationic polysaccharides have the general formula
wherein [0027]G denotes an anhydroglucose group, for example a starch anhydroglucose or cellulose anhydroglucose group; [0028]B is a divalent connecting group, for example alkylene, oxyalkylene, polyoxyalkylene or hydroxyalkylene; [0029]R1, R2 and R3 independently of each other denote an alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl group each with up to 18 carbon atoms, the total number of carbon atoms in R1, R2 and R3 being at the most 20; [0030]X stands for a common counteranion X.sup.-, for example a halogen, acetate, phosphate, nitrate or alkylsulfate and preferably a chloride. A cationic cellulose is sold by Amerchol under the designation Polymer JR and bears the INCI designation Polyquaternium-10. Another cationic cellulose bears the INCI designation Polyquaternium-24 and is sold by Amerchol under the tradename Polymer LM-200. A suitable cationic guar derivative is sold under the tradename Jaguar® R and bears the INCI designation Guar Hydroxypropyltrimonium Chloride. Particularly preferred cation-active substances are chitosan, chitosan salts and chitosan derivatives. The chitosans are completely or partly deacetylated chitins. The molecular weight of chitosan can be spread over a wide range, for example from 20,000 to about 5 million g/mol. Suitable is, for example, a low-molecular-weight chitosan with a molecular weight of 30,000 to 70,000 g/mol. Preferably, however, the molecular weight is higher than 100,000 g/mol and most preferably 200,000 to 700,000 g/mol. The degree of deacetylation is preferably from 10 to 99% and most preferably from 60 to 99%. A preferred chitosan salt is chitosoniumpyrrolidone carboxylate sold, for example, by the Amerchol company, USA, under the tradename Kytamer® PC. The chitosan it contains has a molecular weight of about 200,000 to 300,000 g/mol and is 70 to 85% deacetylated. Suitable chitosan derivatives are the quaternized, alkylated or hydroxyalkylated derivatives, for example hydroxyethyl-, hydroxypropyl- and hydroxybutylchitosan. The chitosans and chitosan derivatives are preferably in neutralized or partly neutralized form. The degree of neutralization of chitosan or of the chitosan derivative is preferably at least 50% and most preferably between 70 and 100%, based on the number of free basic groups. In principle, all cosmetically harmless inorganic or organic acids can be used as neutralization agents, for example formic acid, malic acid, lactic acid, pyrrolidonecarboxylic acid and hydrochloric acid among others, among which pyrrolidonecarboxylic acid and lactic acid are particularly preferred.
Carrier Medium
[0031]Suitable as the liquid carrier medium are, for example, solvents or dispersing agents, such as water, alcohols, ethers, ketones or hydrocarbons or mixtures of two or more of said substances, as long as the substances or the mixtures thereof are liquid at room temperature (25° C.). The amount of liquid carrier medium contained in the rollable composition can range from 20 to 90 wt. % or from 30 to 70 wt. %. Suitable alcohols are, in particular, the lower monohydric or polyhydric alcohols with 1 to 5 carbon atoms usually employed for cosmetic purposes, for example ethanol, isopropanol, ethylene glycol, glycerol and propylene glycols, particularly 1,2-propylene glycol.
[0032]For further optimization, the foils can contain additives, particularly emulsifiers in an amount of up to 50 wt. %, softeners (for example glycerol, polyethylene glycols) up to 50 wt. %, or hair luster-imparting agents, particularly oils such as, for example, vegetable oils, hydrocarbon oils or silicone oils up to 30 wt. %. Moreover, the product of the invention can contain common additives in an amount typical for hair-treatment agents, namely from 0.01 to 15 wt. % of moisture-retaining substances, fragrances in an amount from 0.1 to 0.5 wt. %, preservatives in an amount from 0.01 to 1.0 wt. %, buffering substances such as, for example, sodium citrate or sodium phosphate, in an amount from 0.1 to 1.0 wt. %, tinting substances, for example fluorescein sodium salt, in an amount from about 0.1 to 1.0 wt. %, hair-care agents such as, for example, plant and herb extracts, protein hydrolyzates and silk hydrolyzates, lanolin derivatives in an amount from 0.1 to 5 wt. %, physiologically harmless silicone derivatives, for example volatile or non-volatile silicone oils or high-molecular-weight siloxane polymers, in an amount from 0.05 to 30 wt. %, light stabilizers, antioxidants, free-radical scavengers, antidandruff agents, in an amount from about 0.01 to 2 wt. %, vitamins, combability improvers, pigments and/or water-insoluble particulate solids.
[0033]A particular embodiment of the invention concerns a hair-styling foil containing at least 85 wt. % and particularly more than or 85 wt. % to 97 wt. % of at least one hair-fixing polymer and more than 3 wt. % and particularly more than 3 wt. % and less than 15 wt. % of at least one surfactant. Suitable hair-fixing polymers are the afore-said hair-fixing polymers particularly those based on polysaccharides and hair-fixing nonionic, synthetic polymers. Particularly preferred is a polymer combination of (a) pullulan and (b) at least one polymer selected from among polyvinylpyrrolidone and polyvinylpyrrolidone/vinyl acetate copolymer, the weight ratio of (a) to (b) preferably being less than 2:1 or less than 1:1 and particularly 1:10 or 1:4 to less than 1:1.
[0034]Suitable surfactants are nonionic, cationic, anionic and amphoteric surfactants. Anionic surfactants are, for example, fatty alcohol sulfates, alkyl ether sulfates and alkylbenzenesulfonates. Suitable amphoteric surfactants are, for example, betaines such as fatty amide alkylbetaines, sulfobetaines and C8 to C22 alkylbetaines. The surfactants are preferably selected from among nonionic and cationic surfactants. Particularly preferred is a surfactant combination of at least one cationic and at least one nonionic surfactant. The weight ratio of cationic to nonionic surfactants is in this case from 1:10 to 10:1, from 1:5 to 5:1 and particularly from 1:1.5 to 1.5:1.
[0035]Suitable cationic surfactants are those containing a quaternary ammonium group and that can be represented by the general formula
wherein R1 to R4 independently of each other denote aliphatic groups, aromatic groups, alkoxy groups, polyoxyalkylene groups, alkylamido groups, hydroxyalkyl groups, aryl groups or alkaryl groups with 1 to 22 carbon atoms, wherein at least one of the R1 to R4 groups has at least 8 carbon atoms and X.sup.- denotes an anion, for example a halogen, acetate, phosphate, nitrate or alkyl sulfate and preferably a chloride. In addition to the carbon atoms and hydrogen atoms, the aliphatic groups can contain crosslinks or other groups such as, for example, additional amino groups.
[0036]Examples of suitable cationic surfactants are the chlorides or bromides of alkyldimethylbenzylammonium salts, alkyltrimethylammonium salts, for example cetyltrimethylammonium chloride or bromide, tetradecyltrimethylammonium chloride or bromide, alkyldimethylhydroxyethylammonium chlorides or bromides, dialkyldimethylammonium chlorides or bromides, alkylpyridinium salts, for example laurylpyridium chloride or cetylpyridinium chloride, alkylamidoethyltrimethylammonium ether sulfates and compounds with a cationic character, such as the amine oxides, for example alkylmethylamine oxides or alkylaminoethyldimethylamine oxides. Cetyltrimethylammonium chloride is particularly preferred.
[0037]Suitable nonionic surfactants are, for example, those listed in the "International Cosmetic Ingredient Dictionary and Handbook", 7th edition, volume 2, in the section on "Surfactants", for example ethoxylated fatty alcohols, ethoxylated nonylphenols, fatty acid mono- and diglycerides, ethoxylated and hydrogenated or nonhydrogenated castor oil, fatty alkanolamides, ethoxylated fatty esters, fatty acid sugar esters and alkylglucosides. Preferred surfactants are, for example: [0038]ethoxylated fatty alcohols, fatty acids, fatty acid glycerides and alkylphenols, particularly the addition products of 2 to 30 moles of ethylene oxide and/or 1 to 5 moles of propylene oxide to C8-C22 fatty alcohols, to C12-C22 fatty acids or to alkylphenols with 8 to 15 carbon atoms in the alkyl group, [0039]C12-C22 fatty acid monoesters and diesters of the addition products of 1 to 30 moles of ethylene oxide to glycerol, [0040]the addition products of 5 to 60 moles and preferably 20 to 50 moles of ethylene oxide to castor oil or to hardened (hydrogenated) castor oil, [0041]fatty acid sugar esters, particularly the esters of sucrose and one or two C8-C22 fatty acids, INCI designations: Sucrose Cocoate, Sucrose Dilaurate, Sucrose Distearate, Sucrose Laurate, Sucrose Myristate, Sucrose Oleate, Sucrose Palmitate, Sucrose Ricinoleate and Sucrose Stearate, [0042]polyglycerol fatty acid esters, particularly those of one, two or more C8-C22 fatty acids and a polyglycerol, preferably one with 2 to 20 glyceryl units, [0043]alkylglycosides, particularly the alkyloligoglycosides, with C6-C22 alkyl groups.
[0044]In a particular embodiment of the invention, bubbles of a suitable gas, preferably air, are enclosed in the foils. Foils with enclosed gas bubbles are characterized by particularly good dissolution properties and especially high ability to be rubbed and worked into the hair. The gas bubbles can be enclosed by a method known to be used for the production of bubbles-containing plastic materials, for example by one of the following methods: [0045](1) using an expanding agent or propellant (blowing agent) [0046](2) foaming by mechanical agitation of the carrier mixture while it is still a liquid or a viscous liquid, [0047](3) by a gas-generating chemical reaction, [0048](4) using a highly volatile solvent and evaporating said solvent at an elevated temperature, [0049](5) injecting a liquefied gas into the still viscous carrier mixture.
[0050]Expanding agents are chemicals which when heated decompose and form a gas, for example nitrogen, carbon dioxide, carbon monoxide, ammonia or hydrogen. Inorganic expanding agents are, for example, carbonates, hydrogen carbonates, borohydrides, silicon oxyhydrides etc. Particularly preferred are organic expanding agents such as those used to produce porous or bubble-containing plastic materials.
[0051]In a preferred embodiment of the invention, the hair-styling foil contains at least 50 wt. % of hair-fixing polymers including pullulan in combination with at least one additional hair-fixing polymer, the weight ratio of pullulan to the additional hair-fixing polymer being less than 1:1, namely the amount of pullulan used is less than the amount of the additional hair-fixing polymer. The amount of pullulan used is preferably from 15 to 45 wt. % and that of the additional hair-fixing polymer is preferably from 30 to 70 wt. %.
[0052]Combinations of pullulan with synthetic styling polymers can produce foils which because of a certain brittleness and fragility are still not fully satisfactory. This can be improved by adding a certain amount of polyols. In another preferred embodiment of the invention, the hair-styling foil therefore contains additionally at least one polyol. A polyol is an organic compound with two or more alcoholic hydroxyl groups. Suitable polyols are, for example, polyhydric alcohols preferably with up to 5 carbon atoms and particularly glycols and glycerol, moreover sugar alcohols and polyethylene glycols that are liquid at 25° C. Glycols are, for example, ethylene glycol, propylene glycol and butylene glycol. Sugar alcohols are, for example, sorbitol, mannitol, malitol and lactitol. Liquid polyethylene glycols are, for example, diethylene glycol, triethylene glycol, tetraethylene glycol etc, and preferably those with a degree of polymerization of up to about 12 and a molecular weight of up to about 600. Preferred is a combination of 50 to 97 wt. % of a hair-fixing polymer with 1 to 50 wt. % and particularly more than 5 wt. %, for example 5 to 20 wt. % or 10 to 15 wt. %, of a polyol, based on the dry, water-free foil, glycerol being particularly preferred. In particular, the presence of a polyol improves the clarity and elasticity of the foil, namely the foils do not break easily.
[0053]At higher environmental temperatures and/or higher air humidity, the risk exists that the hair-styling foils will stick to each other in the package so that it will no longer be possible to remove them from the package readily and separate from one another. This can be improved by use of appropriate release agents. Another preferred embodiment of the invention therefore relates to hair-styling foils that are treated with a powdered release agent. The preferably hydrophobic release agent adheres externally to the foil and prevents sticking of the foils to one another especially during storage or when used at high air humidity. Suitable release agents are, for example, talc, starch and modified starch. The modification of starch can be accomplished by one of the generally known methods including physical, chemical or enzymatic modifications. Physical modifications are, for example heat treatments or treatment with shearing forces. Chemical modifications are, for example, crosslinking, acetylation, esterification, hydroxyethylation, hydroxypropylation, phosphorylation and the use of succinates and substituted succinates. Preferred are modified starches with the INCI designations Aluminum Starch Octenylsuccinates and Corn Starch Modified. The release agent is applied to the finished, dried foils. Typical application quantities are about 0.01 to 0.1 g and preferably 0.02 to 0.05 g per foil with dimensions of 4×4 cm and a thickness of up to 0.5 mm.
[0054]Foils treated with a release agent are characterized by improved nonstickiness so that even after several weeks they can readily be removed from the package without sticking to one another. At the same time, unexpectedly, the release agents do not leave any visible residues on the hair after the foil has been used for hair-styling as directed.
[0055]The foils can be packaged in very compact, space-saving manner, for example in the form of a roll or as pads stacked on top of each other. The foils can be rubbed with wet or moist hands. The completely or partly dissolved foil can then be applied to dry or moist hair after which the hair can be styled into a hairdo in the same manner as when a conventional styling gel is used. The foils can also be applied directly to wet or moist hair and manually worked into the hair.
[0056]The following examples will explain the subject matter of the invention in greater detail.
Example 1
Rollable Composition
TABLE-US-00001 [0057]45 g of polyvinylpyrrolidone (Luviskol ® K90) 5 g of Rewoteric ® AM CAS (cocamidopropyl hydroxysultain, 50% in water) 0.25 g of perfume to 100 g ethanol
Example 2
Styling Foil
TABLE-US-00002 [0058]42.5 g of polyvinylpyrrolidone (Luviskol ® K90) 42.0 g of pullulan 7.5 g of cetyltrimethylammonium chloride 7.5 g of PEG-40 hydrogenated castor oil 0.5 g of perfume
Example 3
Styling Foils
TABLE-US-00003 [0059]A B C Pullulan 29.85 g 59.7 g 42.29 g PVP (Luviskol K90) 59.7 g 29.85 g 42.29 g Cetyltrimethylammo- 4.98 g 4.98 g 7.46 g nium chloride PEG-40 Hydrogenated 4.98 g 4.98 g 7.46 g Castor Oil Perfume 0.5 g 0.5 g 0.5 g
[0060]From compositions A, B and C, rollable doughs were prepared with water as solvent. Foils were prepared by rolling the doughs, and the foils were then dried.
[0061]The foils were judged on the basis of the following criteria: [0062](a) Dissolution properties when rubbed manually with a small amount of water: [0063]very good: ++; good: +; sufficient: 0; poor: - [0064](b) Foaming when worked into the hair: [0065]does not foam: +; foams: - [0066](c) Stickiness: [0067]good stickiness: +; poor stickiness: - [0068](d) Coagulation characteristics when worked into the hair: [0069]does not coagulate, no formation of visible residues: +coagulates, visible residues: - [0070](e) Fixing properties: [0071]good hair fixing: +; weak hair fixing: 0; no hair fixing: -
TABLE-US-00004 [0071]A B C Solubility ++ ++ + Foaming + + + Stickiness + + Coagulation + - + Fixing + + 0
Example 4
Glycerol-Containing Styling Foil
TABLE-US-00005 [0072]A B C Pullulan 28.44 27.15 25.97 PVP (Luviskol K90) 56.87 54.3 51.95 Cetyltrimethylammonium 4.74 4.52 4.33 chloride PEG-40 Hydrogenated 4.74 4.52 4.33 Castor Oil Perfume 0.47 0.45 0.43 Glycerol, 86% 4.74 9.05 12.99 D E F Pullulan 24.9 23.9 22.99 PVP (Luviskol K90) 49.79 47.81 45.98 Cetyltrimethylammonium 4.15 3.98 3.83 chloride PEG-40 Hydrogenated 4.15 3.98 3.83 Castor Oil Perfume 0.41 0.4 0.38 Glycerol, 86% 16.6 19.92 22.99
Example 5
Compositions for Preparing Styling Foils With and Without Glycerol
TABLE-US-00006 [0073]A B Pullulan 3 3 PVP (Luviskol K90) 6 6 PVP (Luviskol K30) 2 2 Cetyltrimethylammonium chloride 0.5 0.5 PEG-40 Hydrogenated Castor Oil 0.5 0.5 Perfume 0.05 0.05 Glycerol. 86% 2.2 -- Water to 100 to 100
[0074]The hair-styling foils obtained from composition A were very elastic and were easy to apply, namely they dissolved readily by using a small amount of water in the hand and they were easy to work into the hair. The foils prepared from composition B, on the other hand, were more brittle, more friable and less readily applied.
Example 6
Styling Foils Treated With a Release Agent
TABLE-US-00007 [0075]A B C Pullulan 21.05 21.05 21.05 PVP (Luviskol K90) 42.11 42.11 42.11 PVP (Luviskol K30) 14.04 14.04 14.04 Cetyltrimethylammonium chloride 3.51 3.51 3.51 PEG-40 Hydrogenated Castor Oil 3.51 3.51 3.51 Perfume 0.35 0.35 0.35 Glycerol, 86% 15.44 15.44 15.44 Post-treatment with Dry Flo Plus.sup.(1) 0.03 g/foil -- -- Post-treatment with Dry Flo PC.sup.(2) -- 0.03 g/foil -- Post-treatment with Dry Flo AF.sup.(3) -- -- 0.03 g/foil .sup.(1)Aluminum Starch Octenylsuccinates; hydrophobic starch .sup.(2)Aluminum Starch Octenylsuccinates; hydrophobic starch .sup.(3)Corn Starch Modified; hydrophobic starch; Ca salt of the ester obtained by reaction of 3-(dodecenyl)dihydro-2,5-furanedione with corn starch.
[0076]Foils 4×4 mm in size were prepared and each was treated with 0.03 g of post-treatment agent. None of the foils were sticky and they were easily separated from each other. Analogous foils that were not post-treated, on the other hand, stuck to each other after they were stored for a while and could no longer be readily separated from one another.
Patent applications by Monika Moenks, Schmitten CH
Patent applications by Sarah Maillefer, Middes CH
Patent applications by Ute Doepner-Reichenbach, Koenigstein DE
Patent applications in class Including means to isolate or part a tress of hair for chemical treatment (e.g., frosting cap or purse)
Patent applications in all subclasses Including means to isolate or part a tress of hair for chemical treatment (e.g., frosting cap or purse)
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Hindhead, Woodcock Inn 1922
This is the 42nd of 258 photos of Hindhead.
Memories of Hindhead, Woodcock Inn 1922
The Only Pub In The Village
The pub has been here for almost a hundred years. The Save the Woodcock Action Group are campaigning hard to prevent this pub from being demolished and redeveloped. We want to revitalise the pub and make it a vibrant community facility again. Please support us. Contact "firstname.lastname@example.com" or "email@example.com" 25th November 2011
Memories of Hindhead
The Undershaw Hotel
I remember having a very nice meal in the Undershaw sometime in the 1990's - it's a shame that it closed down around 2004. The house was built for Conan Doyle in 1897 and this is where he wrote "The Hound of the Baskervilles" and other Sherlock Holmes novels. Unfortunately, property developers who bought the house want ...Read full memory
9 Months Of My Life Spent Here
I was a boy sargeant soldier at Arborfield AAS when I came down with a serious illness and rushed into Cambridge Military Hospital, Aldershot and when I defied the odds and lived , it was discovered that I had pulmonary TB of the right lung. I was transferred to Connaught Military Sanatorium at Hindhead ,Surrey ...Read full memory
Family D'hondt
My grandparents Paula and Gustave D'Hondt managed this hotel during the latter half of the 1930s till it was requisitioned by the army during the war. They then moved with some of their paying guests to Highdown, Hindhead, a large house nearby. Many of their full time residents were ex colonials. They kept chickens during ...Read full memory
My father was headmaster of an East London School when war broke out, and he and the whole school were evacuated to Marchants Hill Camp, Hindhead for the duration. He was Walter Nadal, anybody remember him?
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Der Vermieter
(2 Bewertungen)
Inseriert bei uns seit 31. Jan 2014
Sprachen Englisch
This rental includes Boon Villas complimentary pool/ beach bag with a golf cap with pin marker, a sun visor and a French legionnaires hat for every member of your party.
Named to reflect the peace and tranquillity of its location, Hacienda de la Siesta is situated in a lush green oasis on the edge of a pine forest, near the very popular town of Coin, with its traditional whitewashed walls and unrivalled selection of shops and restaurants. The villa's exterior is in traditional Hacienda style and its interior has been beautifully designed in contemporary style to complement this, by renowned Interior Designer Shane Williams. The mountain views from the villa, are truly spectacular.
Hacienda de la Siesta offers extensive accommodation, its five large bedrooms able to accommodate up to fourteen guests in comfort, as well as offering full facilities for families with children, including a number of cots. Both master bedrooms have en suite bathrooms and large sun terraces and two further bedrooms are located on the same corridor, and so are perfect for children. Additional accommodation is to be found in the villa's annexe, the 'Lemon Suite', a guest lodge with double bedroom and shower room, ideal for larger groups or a travelling chef or nanny.
The large living room is the natural place for day and night-time entertaining, and is fully equipped with wide-screen television with satellite reception, DVD and music system and bar. Next door is a games room with full size snooker table. Wifi and TV are available at no extra charge.
The fully fitted kitchen-diner has everything needed to cater for a house full of guests, with large oven, five-ring hob and double fridge with water purification system, all in open-plan 'Hacienda' style décor. Kitchen, living room and hall all lead onto the main courtyard terrace, for the ideal indoor/outdoor lifestyle.
Outside, surrounded by the villa's mature gardens is a swimming-pool with barbeque area and shady poolside bar, offering the ultimate in holiday relaxation. The gardens are truly magnificent, their manicured lawns and tropical plants all tended by a gardener.
To complete your holiday experience at Hacienda de la Siesta, why not use our concierge services to treat yourself to a massage or the services of a beautician, before leaving for an evening among the glamorous bars and restaurants of Marbella and Puerto Banus.
* Maid services are available at extra cost.
|Flughafen (Málaga):
|30 Kilometer
|22 Kilometer
|3 Kilometer
|4 Kilometer
|1 Woche
|min. Aufenthalt
|04 Sep 2016
|16 Dez 2016
|€ 2.500£ 2.239$ 2.745
|1 Woche
|17 Dez 2016
|07 Jan 2017
|€ 3.000£ 2.687$ 3.294
|1 Woche
|30 %
|Restbetrag 6 Wochen vor Anreise
|Rückerstattbare Kaution:
|€ 600,00£ 537,36$ 658,80
|Im Preis inbegriffen
|Nicht gestattet
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|Im Preis inbegriffen
|Akzeptierte Zahlungsmittel:
|Debit- oder Kreditkarte, Paypal, Banküberweisung
|Reservation fee: 30 %.
Pay balance 6 weeks before arrival.
Refundable security deposit: 600 €
(Security deposit refunded 1 week after departure.)
Final payment non-refundable.
Final cleaning is included in the price.
Payment methods accepted: credit or debit card, PayPal, bank transfer (All bank/PayPal charges incurred will be borne by the rental client).
Before paying, call the property manager to confirm payment details.


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The Dean Palomino Electric Guitar is an affordable way to add deep hollowbody sounds to your music. Whether you're into jazz or blues, you'll get a lot of different tones from the Palomino thanks to its three P-90 pickups and 5-way switch. It has a beautiful maple body with a flame maple top and Florentine cutaway for easy access to the upper frets. The set maple neck has a comfortable C shape with a rosewood fingerboard and pearl block inlys. Gold hardware includes Grover tuners, a floating/adjustable bridge and elegant tailpiece.
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Command & Conquer 3: Kane's Wrath
- Platforms: PC, X360
- Developer: EA Games
- Publisher: Electronic Arts
- Genre: Real-Time, Strategy
- VN:F [1.9.22_1171]User Score: 0 votes
- Add to MyGames
Experience a new story that spans 20 years – from the rebirth of the Brotherhood of Nod after the Second Tiberium War through the dramatic events of the Third Tiberium War and beyond. The story is told through a new set of high-definition live action video sequences starring a celebrity cast. Joe Kucan, the original actor who portrayed the character Kane in Command & Conquer games over the last decade, will reprise his role as the megalomaniacal leader of the Brotherhood of Nod. Other details of the cast have yet to be announced.
Command & Conquer 3: Kane's Wrath also features a new strategic layer of gameplay that allows you to establish bases, build customized armies, and attack your enemies on a global scale – and then dive into the frenzied tactical combat where your skills as a commander will be tested to the limits. The game introduces six new sub-factions and a wealth of new units, structures, and powers to the armies of the Global Defense Initiative, the Brotherhood of Nod, and the enigmatic alien Scrin
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Command & Conquer 3: Kane's Wrath
EA keeps piling up its Command&Conquer titles with Red Alert 3 coming up, but until then we have to suffice with Kane's Wrath, the expansion of Command & Conquer 3 which shows you how NOD managed to rise from its ashes and managed to start the third Tiberium War. Expansions are a strange thing. On […]
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We hold regular club meetings once per month, normally on the 1st Sunday of the month from noon to 4:00 PM. Our regular club meetings are held in the Fellowship Hall at the Harvard Park Baptist Church, 2401 South 9th Street, Springfield, IL. [View Street Map] We extend an invitation to anyone who is interested to attend our meetings as our guest to learn more about our organization.
Our meetings begin with a deluxe pot-luck lunch provided by contributing club members, who always prepare a spread covering several tables with delicious entrées, side dishes, deserts and beverages. Our meeting lunches provide an opportunity for our members to catch up on news, and spend with general fellowship. Lunch is followed by a program, or workshop, and then our business meeting.
Members are encouraged to bring their birds to our monthly meetings to help socialize them, educate fellow members about various species and varieties, and general entertainment and showing off. However, all birds brought to meetings must be owned and observed by the member for a minimum of 90 days prior as a precaution against the possible spread of avian diseases.
|Illini Bird Fanciers 2016 Meetings and Activities Calendar
|Program or Workshop
|1st Sunday, January 3
|Regular IBF Club Meeting
|Wild Parrots of Telegraph Hill Video - Officer/Board Elections
|1st Sunday, February 7
|Regular IBF Club Meeting
|Bird Toy and Stand Workshop - Board Election
|1st Sunday, March 6
|Regular IBF Club Meeting
|Round Table Discussion
|1st Sunday, April 3
|Regular IBF Club Meeting
|Dr. Welle
|1st Sunday, May 1
|Regular IBF Club Meeting
|Spring Bird Fair Planning and Logisitics
|3rd Sunday, May 15
|IBF Spring Bird Fair
|1st Sunday, June 5
|Regular IBF Club Meeting
|Bird Rescure Speaker
|4th Sunday, June 26
|IBF Field Trip
|Behind the scenes tour of Brookfield Zoo
|2nd Sunday, July 10
|Regular IBF Club Meeting
|Annual Summer BBQ Madonia East Park, lakefront pavilion
|1st Sunday, August 7
|Regular IBF Club Meeting
|Lisa Rose will be giving a lecture and trimming
|1st Sunday, September 4
|Regular IBF Club Meeting
|Fall Bird Fair Planning and Logistics
|3rd Sunday, September 18
|IBF Fall Bird Fair
|1st Sunday, October 2
|Regular IBF Club Meeting
|Pumpkin Design and Seed Roasting
|1st Sunday, November 6
|Regular IBF Club Meeting
|Conservation Speaker - Officer/Board Nominations
|1st Sunday, December 4
|Regular IBF Club Meeting
|IBF Christmas Party
|Illini Bird Fanciers, Inc. • PO Box 13006, Springfield, IL 62971 • Tel (217) 391-4673 • firstname.lastname@example.com
|Illini Bird Fanciers, Inc. is a 501(c)(3) non-profit educational organization.
|Copyright © 2011-2016 Illini Bird Fanciers, Inc. All Rights Reserved.


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Training Event Customer Service
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Hi, corporate training company requires freelancers to work on training event projects basis. job role includes but not exhaustive:
1. arrive early at training room to greet participants
2. ensure participants sign the attendance list
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Retiring in Saranac Lake, New York Saranac
Lake is ranked the #1 small town in New York State.
Before Saranac Lake was incorporated as a village in 1892, it was already famous
for its natural beauty and the experienced guides who took visitors on fishing
and hunting trips in this part of the Adirondack Park.
The fact that the Saranac Lake of today is a vibrant, desirable community has
not gone unnoticed on a national level. In 1995, Saranac Lake was ranked #1 out
of all the small towns in New York State and 11th in the entire United States
in the book, The 100 Best Small Towns in America by Norman Crampton. The author
cited Saranac Lake's investments in education, healthcare and community spirit.
In 1998 the National Civic League bestowed All-America City status on Saranac
August 1996 issue of Men's Journal listed Saranac Lake as one of "America's
25 Coolest Mountain Towns." The article listed Saranac lake as a paradise
for both hiker and canoeist. One of the high points of the year in Saranac
Lake is the Winter Carnival held the first week in February. The Ice Palace,
the center of this event, is built a one-mile walk away from Saranac Village at
Will Rogers. The palace is constructed from blocks cut from frozen Lake Flower.
The Winter Carnival Celebrations even include a parade.
In the summer
the Village of Saranac Lake offers free concerts in the park.
Country Community College located in Saranac Lake and Paul Smith's College just
outside of the village offer community members the opportunity to take advantage
of life long learning opportunities. If you would like more information about
retiring in a historic independant living retirement community in the Adirondacks-
please email your name, phone
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here For more information on Retiring in the Adirondacks please
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The NBA has been shaken up by the trade deadline, with several marquee players heading to different homes.
Big names like Carmelo Anthony and Deron Williams have switched teams while a handful of role players will look to reestablish themselves in their new digs.
Heading into the second half of the season, it appears a shift of power to the Eastern Conference has occurred. LeBron James would agree.
However, the Western Conference is still strong and we are in store for a race to the finish.
The recent trades should affect the make-up of the top eight playoff spots. With the current standings aside, here are the up-to-date Western Conference power rankings.


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TJ Dillashaw is a mixed martial arts fighter and former Bantamweight champion currently fighting in the UFC. Duane Ludwig is a former mixed martial arts fighter and is now a coach. Bas Rutten is a re watch video >>
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Inside MMA series hosts Kenny Rice and Bas Rutten interview Dominick Cruz about his return to the octagon after suffering a torn ACL 11 months ago and his desire to reclaim his former belt. While dis watch video >>


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Designed by Phillip Boydell and cut by Monotype in 1950 as the official display face for the Festival of Britain, a national exhibition held throughout the United Kingdom in the summer of 1951. The typeface was used for all official Festival announcements and was made available for general use in 1952.
Photo-Lettering's version was called Fanfare.
Festival Titling in use
The Whitsun Weddings, Faber & Faber edition1964
- Berthold Wolpe
Contributed by Stephen Coles
Staff Pick
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Festival of Britain1951
- London Press Exchange
- Eric Fraser
- Abram Games
Contributed by Stephen Coles
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OK, by now you have heard the big news that Urban Meyer is resigning from the head coaching position at the University of Florida. Meyer leaves UF after six seasons with two national and SEC championships.
Though the Gators struggled this year, only going 7-5, he has an overall mark of 64-15 in his tenure at Florida for an overall winning percentage of 81%.
Who in the world would want to try to follow that?
Somewhere, Steve Spurrier is watching and smiling from ear to ear.
Why? Well, obviously, this is the Spurrier's chance to go back home to "The Swamp" and try for another NC before waiving adios and strutting off to retirement on a golf course near you.
Here are the top 10 reasons, in no particular order, why the 'Ol Ball Coach should be back stalking the sidelines and ranting at referees in Gainesville next season.


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Essential Philip Seymour Hoffman performances
Dan Mahowny in 'Owning Mahowny'
It was actually Roger Ebert who really put "Owning Mahowny" on my radar in 2003. The late critic put the film on his top 10 list and he was completely right. The film remains a bit of a deep cut in Hoffman's career, but no less exemplary for his ability to slip under the skin of a role. It's also a portrait of obsession (gambling) that obviously registers a newfound pang of sadness in the wake of Hoffman's passing. His uncanny way of depicting men with demons will forever be held in a new, unfortunate light, but genius is genius and Hoffman exhibited it here.
- Kristopher Tapley


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The East Chapel Hill (N.C.) High School product has connected on 8-of-13 field goal attempts over this career with a long of 46 yards. Moore gained plenty of experience in '11-12, appearing in 14 games while Casey Barth was sidelined with injuries.
Those experiences helped build confidence and prepare for his first season as UNC's starting placekicker.
"That was crucial because it allowed me at a young age to just get the jitters out," Moore said on Wednesday. "You're not used to going into the game when you're a freshman. You don't know what's going on or what to expect. But luckily I had Casey there, who even when he was injured was able to give some pointers and tips. I think that really benefitted me and hopefully will pay off in the future."
Moore converted just two of three field goal attempts with a long of 30 yards in 2012 while battling through an ankle injury. Once he got healthy in the offseason, Moore dropped 15 pounds while increasing his squat and power clean numbers to improve his power.
The 5-foot-10, 190-pounder spent the offseason working on his form consistency to build a repetitive swing. Instead of trying to overpower the ball, he focused more on smooth swings to maximize leg speed.
Those improvements were on display Monday. Instead of working on routine field goals from 30 or 40 yards, Fedora called for a pair of 57-yard attempts before moving back to 59 following Moore's make.
"In that situation, you focus on getting a good hit on the ball, trying to be smooth and not trying to overkick it," Moore said. "That allows you to not worry about any of the other minute details that you deal with in [shorter] field goals."
Moore's 59-yard attempt fell short of the crossbar.
The challenge kicking from that distance is determining the proper trajectory. Kick the ball too high and there's not enough power to reach the goal posts. Kick too low and Moore has to contend with Darius Lipford and his 39-inch vertical on the other side of the line of scrimmage.
"The main focus is getting great ball contact there and just making sure I follow through as high as I can to try to get the ball up so that it can carry out," Moore said.
While Moore described the 57-yard attempt as a "fun" yardage, a more realistic range for live kicks stretches out to 53 yards.
His steady play in training camp has carried over from spring practice, according to head coach Larry Fedora.
"Thomas was impressive in the spring to me, with his confidence and everything that he had," Fedora said. "He's picked up right where he left off. He's hitting the ball real well; it's coming off his foot. It's popping. And he's putting the ball through the uprights, so that's big for us right now."
Moore's improved leg strength will also be critical on kickoffs. UNC ranked 76th nationally in kickoff yardage last season at 60.35 yards per kick, while Moore kicked off 19 times for an average of 57.2 yards per attempt.
Any improvement in that statistic will go a significant way in helping UNC win the hidden yardage battle.
Follow @insidecarolina


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By 2017, mobile users will be providing personalized data streams for more than 100 apps and services every day. Want to be one of those 100? Karen Pattani-Hason, Head of Agency & Strategic Alliances NAM at Urban Airship, shares some tips on how to build... read more
tag archive
Wings Galaxy Top 50 iPhone Apps
[caption id="" align="alignright" width="300"] Wings Galaxy Makes Top 100[/caption] Thank you everyone for making Wings Galaxy such a huge success. We made the top 50 iPhone apps. That's right, the actual top 50 of ALL iPhone apps! Wings Galaxy has been complimented for great graphics, deep game play and an excellent custom soundtrack. Thanks for all your help. We'll work hard... read more
Wings Galaxy Available Now!
One of the most complicated apps we've ever released. Trust us, we have the bags under our eyes to prove it. What our beta testers said: "Every once in a while a game comes along that really impresses you. Wings Galaxy is that game." "I really like the graphics." "After playing Wings Earth, I was really hoping you would make a space exploration... read more
Wings Earth 2.5 Submitted to Apple
Wings Earth (Wings 2) gets an update with 2.5. Here's the highlights: Major improvement to surface detail. 4 times more pixel density. What's that? In other words, it's more realistic... Added highest-requested feature: turn off crash effects. Added new audio track from Wings Galaxy Ready for future versions of iPhone and iPod software. In other words it won't break when iPhone 3.0 comes out. Or at... read more
Wings Galaxy Sneak Peek!
OMG! Wings Galaxy is finally done! One of the most complex and exciting projects we have ever undertaken has been submitted to Apple for the infamous app review process. We've worked very hard on Wings Galaxy and hope you're excited about the next chapter in one of the most successful iPhone app franchises on the App Store. Like Wings 2 (Earth), Wings Galaxy will not be a copy-cat first person... read more
GasBuddy for iPhone Gets Major 2.0 update!
Our largest update in Bottle Rocket history! GasBuddy is already the most feature-rich fuel finder on the iPod and iPhone. But we've raised the bar again with over 32 important improvements, feature additions and tweaks. We listened to our customers and picked the top 30 requests (plus two more). They are: - Address and name on list views - Additional station logos to help you identify your favorite... read more
Voxie keeps getting better – SMS and Twitter coming soon!
Sneak Peek Alert! Voxie will be adding the ability to update your Twitter account and send texts by speaking both! Will also include about 10 other improvements including better file management and multi-delete features. Coming soon to Voxie and a FREE upgrade to everyone who buys... read more
Seek and Spell is Bottle Rocket Approved!
I know, I know, why would we tell everyone to go buy another company's iPhone app? Especially one made by one of our competitors, Retronyms makers of Recorder and competitor to Voxie Pro Recorder. First off Voxie and Recorder are two different apps that appeal to different types of customers. And second, we're friends with the guys at Retronyms and love their new app Seek and Spell. On a recent trip to... read more
GasBuddy One of Five iPhone Apps That Might Change Your Life
In the April 2009 copy of their premium in-flight magazine Hemispheres, United Airlines picked GasBuddy as one of five iPhone apps that might change your life. Also mentioned were Lonely Planet Audio Phrasebook, SitOrSquat, and FlightTrack. Covering both USA and Canada with 181 web sites and over 1 million volunteer price spotters, GasBuddy is the most complete source of retail gas and... read more
Excellent new Mic Pairs Perfectly with Voxie
[caption id="attachment_445" align="alignright" width="300"] MityMic from TouchMic.com pairs perfectly to Voxie![/caption] The guys at TouchMic.com have done it again. Another great product that works perfectly with Voxie on the iPod Touch 2nd Gen or 3G iPhone. The MityMic is both cool looking and very functional. If you need to conduct interviews, record lectures/meetings or even take... read more


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Lily's Florist is an Australian based delivery florist. Order flowers online for same day delivery to any location is Australia. Fresh flowers from just $29.
The rating shows just the review scores in the category or product area selected.
Ratings guide
All Feefo reviews are gathered anonymously from genuine customers. Read more about how our review system works.
Flowers delivered ontime and exceptional quality and quantity
Not really happy because what I perceived it was not like that and think it is not the value for money offer and it actually spoiled the entire reason for which it was sent.
Hard to rate this as I didn't order yellow lilies, I ordered cream and pink ones, however the yellow, cream and pink stems that were delivered were evidently beautiful with some open some still closed (which I requested) which was good in the end.
Responsive and simple
Unfortunately the product didn't match the picture. We selected a yellow bunch of Lillies in yellow paper for a friends 30th and when they arrived they were mainly natives in green paper with some closed Lillies. I didn't have time to go and get anything else. We were really disapointed.


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Peter McPhailLatest answers
Who is your wife
Don't have one :/
snapchat?Julia NH
tbh idrk you but i was with you and a bunch of people at port on canada day, you seem really chill and you're attractive. hot or not: hotHaley Semtob
Thank you:)
Tbh for likers
who do u think is hot that has already left secord
Probably Mr MacArthur:/
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Gucci u
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Kind of
thoughts: your answers are funny as hell and I've only really seen you once with Nick!
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Likers get tbh!
Is this one of my grade 9 crushes?


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Fixtures and news for 2016/2017Find all the latest fixture dates and news about our club here.
Read more...
Well done to Dylan Spencer, Katie Hopkins, Henrietta Owen, Martha Collings and Emma Harris who represented North West Surrey at the Surrey Schools cross country champs at Reigate today.
Inter Girls Katie Hopkins - 5th Henrietta Owen - 38th
Junior Boys Dylan Spencer - 5th Junior Girls Martha Collings - 9th Year 7 Girls Emma Harris - 84th Dylan, Katie and Martha have been selected to run for Surrey Schools in the South East Inter Counties XC at Bexhill on 6th February. Furthermore, Katie and Dylan by coming in the top six were also automatically selected for the English Schools XC champs at Nottingham on 5th March — at Priory Park Reigate.


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Our Mission
upcoming program
Reach Out
For more than 6 years, Hopeful Holidays has devoted its energy to passionately advocating for the needy in Hunterdon County, giving the gift of hope through the donation of evergreen trees during the holiday season. Find out how you can contribute to the future of someone in need through donations of money and time.
for others
those in need
for the future
Help make someone's holiday a hopeful holiday!
Hopeful Holidays
This drive was a success! For the seventh year in a row we were able to donate Christmas trees to needy families all across the Hunterdon County area. We gave to over eighty families this year and covered almost the entirety of the county. We can't wait for next year!
We just finished our seventh annual Christmas tree drive! We are still looking for more donations for this year's trees. Look forward to our summer drive!
Join Us
Hopeful Holidays participated in The Clinton Sunrise Rotary Club's annual Christmas Tree Festival fundraiser. Our tree's theme was Peace on Earth. If you want to check out our tree in person you can see it in the lobby of the Clinton Holiday Inn!
Our program has grown over the seven years that we have been running it. We need your help to spread this hope. Please contact us with any ideas or forms of support you wish to donate.
Through the gift of an evergreen tree from people who do not know the families that they are helping our goal is to show that there are people that care and want to help. There is hope for the future.


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Dream girl
- 3 total posts
- 1 review
- 2 comments
Reviews by Dream girl
Getting the Body I've Been Working for - Indianapolis, IN
I have been hear stalking this sight for over a year reading every review just abt I am currently researching docs in the D.R. I am looking to go to hopefully hilario Duran that's my dream dra. lol I currently weigh 214 down from 244 in June I hope to get another 30-40lbs by Feb so im looking to... READ MORE
Recent comments from Dream girl
Thanks for your updates I to am 239lbs and having this procedure done and you totally showed great results and you're closer to my body type thankyou READ COMMENT
Who was your ps READ COMMENT


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The Wonder Years
~ Group
The Wonder Years is an American pop punk band from Lansdale, Pennsylvania that formed in July 2005. Since their conception, they have released five full-length albums, two EPs, and several splits/compilations. The group is currently signed to Hopeless Records. Their name originates from a paper that lead vocalist, Dan 'Soupy' Campbell, read that was written by one of his after-school educators titled "The Wonder Years."
Showing official release groups by this artist. Show all release groups instead, or show various artists release groups.


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Hotels in Levisham, United Kingdom
Search & Compare Levisham Hotels
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Trending now in Levisham
Hotels in Levisham
- Most bookedBest Western Forest & Vale HotelNo Guest Reviews yet
21 people looked at this hotel in the last hour
16 people looked at this hotel in the last hour
Most recent review
"Booked a 2 night stay for a local concert, location was great for that and fairly peaceful. The lodge was clean and the owners were very helpful when needed, I would recommend this for a chilled weekend in the area. Parking is in front of the lodge, this i a bit difficult if you are a 2 car fam..."
A Traveller, Aug 2016, GB
11 people looked at this hotel in the last hour
Most recent review
"Good hotel, friendly staff and a big, clean, spacious room with a great shower. Excellent location - Pickering is a lovely small town with good pubs and restaurants (we especially liked the Willowgate Bistro). Dinner on our first night was nice but we found breakfast a bit hit and miss - great fu..."
A Traveller, Jul 2016, GB
7 people looked at this hotel in the last hour
Most recent review
"Put this B&B address into the Sat Nav and go with it. The address we had was, Main Street, Pickering, when in fact the Sat Nav will lead you to Lockton, a small village 10 mins out of Pickering on the Whitby Road. When we arrived we thought we had the wrong address, ie; Hotel, Main Road, Pickerin..."
A Traveller, Sep 2016, GB
6 people looked at this hotel in the last hour
Most recent review
"Great breakfast variety and quality.Recommend fruit salad,porridge and salmon. Tea and cakes on arrival.Fruit and chocolates in the room. Quiet surroundings.Informative hosts. Toilet flush a little difficult, you need the knack! Be aware rooms on first floor may still have people above in the..."
A Traveller, Aug 2016, GB
- YHA Dalby Forest - HostelNo Guest Reviews yet
5 people looked at this hotel in the last hour
4 people looked at this hotel in the last hour
Most recent review
"Easy access to Pickering and no need to use the car for immediate attraction. Plenty of places to eat in the evenings with good menu choices."
A Traveller, Sep 2016, GB
4 people looked at this hotel in the last hour
Most recent review
"Two nights as base for North York Moors Railway and a walk up on the tops/"
A Traveller, Sep 2016, GB
- High Dalby House & CottagesNo Guest Reviews yet
Hotels within 10 miles of Levisham
23 people looked at this hotel in the last hour
Most recent review
"Nice big clean room surrounded by fields plenty of parking fresh cooked breakfast by the owner Neil"
H, Sep 2016, GB
Best hotels in Levisham
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realmagick.com The shrine of knowledge.
Dream Dictionary Helicopter
A selection of articles related to dream dictionary helicopter.
Original articles from our library related to the Dream Dictionary Helicopter. See Table of Contents for further available material (downloadable resources) on Dream Dictionary Helicopter.
- A History Of Dreaming - From Ancient Egypt To Modern Day
- Dreams have been an important part of the human experince since time immemorial. Fragments of the earliest books come from Egypt, where dreams were considered to be the messages sent from the gods. The Egyptians divided their dreams into three categories: 1....
Parapsychology >> Dreams
- Hulse, David Allen
- >From an early age, David Allen Hulse has made a diligent study of the alphabets of the ancient world. Even as a child, David possessed a great affinity for the alphabets of Egypt, Phoenicia, and Greece. In college, a reading of MacGregor Mathers' Kabbalah...
Real Interviews >> Authors
- Hulse, David Allen
- From an early age, David Allen Hulse has made a diligent study of the alphabets of the ancient world. Even as a child, David possessed a great affinity for the alphabets of Egypt, Phoenicia, and Greece. In college, a reading of MacGregor Mathers' Kabbalah...
Real Interviews >> Authors
- What does it mean if I have nightmares about being ill?
- According to a report from the Menninger Clinic Detecting cancer in dream content . Horton PC, Child Guidance Clinic for Control Ct., Meriden, CT, USA. A woman was 3 years post mastectomy when she presented a dream whose manifest content suggested a new...
Parapsychology >> Dreams
- A Treatise on Astral Projection, Part 4: More Rope Techniques
- ROPE is a very effective projection technique, but it still has to be learned to be effective. I would like to elaborate on a couple of points about the technique, inspired by the feedback I have received so far. There is NO visualization required - AT ALL -...
Parapsychology >> Astral Projection
- Apple Divination
- We have all heard and used the expression "An apple a day keeps the doctor away." This expression is based on a very old superstition and is one of many associated with apples. I am quite sure that you have all held an apple in one hand and twisted...
Psychic Abilities >> Divination
- King James Bible: Genesis, Chapter 41
- Chapter 41 41:1 And it came to pass at the end of two full years, that Pharaoh dreamed: and, behold, he stood by the river. 41:2 And, behold, there came up out of the river seven well favoured kine and fatfleshed; and they fed in a meadow. 41:3 And, behold,...
Old Testament >> Genesis
Dream Dictionary Helicopter is described in multiple online sources, as addition to our editors' articles, see section below for printable documents, Dream Dictionary Helicopter books and related discussion.
Suggested News Resources
- From Gotham to Metropolis: A look at NYC's best nicknames
- "The Big Apple, the dream of every lad that ever threw a leg over a thoroughbred and the goal of all horsemen," he wrote in a 1924 column. "There's only one Big ... O.
- TRUMP's NY GOP echo -- CUOMO Empire symbol -- RIKERS reform chief on challenges
- City Council Speaker Melissa Mark-Viverito's outlined that vision during her State of the City speech last month, when she said she wanted to get the jail's population so low that the "dream" of closing it could become a reality. ....
- Letter: Politicians' governing ability seems to be sorely lacking
- Oh well, maybe it's because Mr. Trump has promised to make us great again. Maybe he will let some of us fly in his fancy airplane or helicopter if we vote for him.
- Cheryl Fernandez-Versini does her best I'm A Celebrity's Vicky Pattison impression
- And it sounds like Cheryl Fernandez-Versini has been keeping an eye on Vicky Pattison during her current stint on I'm A Celebrity...
- The Beatles' songs are played 50 million times in first 48 hours of streaming
- Beatles songs were streamed an astonishing 50 million times in the first 48 hours after they became available to listen to live on the internet for the first time.
Suggested Web Resources
- Interpretation of a dream in which you saw «Helicopter» - Globe Views
- Helicopter in the dream, is a symbol of power and wealth. Helicopter for many of us is a transport that is used for personal travels by rich and famous people or ...
- globe-views.com
- Dream interpretation - Planes,helicopters and flying as dream symbols
- Planes and helicopters in dream interpretation. Modern dream symbol research.
- www.unclesirbobby.org.uk
- Dream symbol - upside down helicopter - Dream Symbolism
- Dream symbol - helicopter upside down and about to crash. ... THE INTERPRETATION Helicopters and aircraft are very predictable symbols.
- www.dreamsymbolism.info
- HELICOPTER - Dream Dictionary
- A dream featuring a helicopter suggests that you are experiencing some change in consciousness or awareness, experiencing greater freedom or are ...
- www.dreamdictionarynow.com
- * Helicopter (Dreams) - Definition,meaning - Online Encyclopedia
- Example dream : A helicopter symbolised the dreamers wish to get something going really quickly. [http://www.unclesirbobby.
- en.mimi.hu
Great care has been taken to prepare the information on this page. Elements of the content come from factual and lexical knowledge databases, realmagick.com library and third-party sources. We appreciate your suggestions and comments on further improvements of the site.
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