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Volume 113, Issue 24, 22 December 2000
- Theoretical Methods and Algorithms
Incorporating physical implementation concerns into closed loop quantum control experiments113(2000); http://dx.doi.org/10.1063/1.1326905View Description Hide Description
In quantum control experiments, it is desirable to build features into the field that address physical concerns such as simplicity, robustness, dynamical coherence, power expenditure, etc. With a judicious choice for the cost functional, it is possible to incorporate such secondary features into the field, often without altering the experimental procedure or apparatus. Through simulated closed-loop population transfer experiments, we demonstrate the benefit of carefully designed cost functionals. As specific examples, we address two common physical concerns: removing extraneous structure from the control pulse and finding robust fields. Removing unnecessary field components is critical if information about the mechanism is to be interpreted from the structure of the optimal pulse. Robust fields produce a stable outcome despite noise in the field and, perhaps, environmental inhomogeneities in the quantum system as is typical of condensed phase experiments.
Spectral decomposition and Bloch equation of the operators represented by fixed-centroid path integrals113(2000); http://dx.doi.org/10.1063/1.1327293View Description Hide Description
Interesting approaches to study statical and dynamic properties of quantum systems, e.g., the quantum transition state theory and the centroid molecular dynamics, have been previously derived using fixed centroid path integrals. We show that these constrained propagators can be alternatively defined using an operator formalism. An interesting result is the finding of the differential equations that determine the temperature dependence of these propagators. One equation applies to path integrals with fixed-centroid position (i.e., those used in quantum transition state theory), and the other one to path integrals with fixed-centroid position and momentum (i.e., those used in centroid molecular dynamics). Both equations are solved for a harmonic oscillator, so that the spectral decomposition of the operators represented by fixed-centroid path integrals is derived for this particular case. Their eigenvalues build an alternating geometric series, showing explicitly the impossibility of considering such operators as true density operators, i.e., some eigenfunctions are associated to "negative probabilities." The eigenfunctions are shown to be a generalization of the coherent and squeezed states of the harmonic oscillator. The physical meaning of centroid molecular dynamics, an approximation to study the time evolution of these mixed states, is clarified by considering the time evolution of the corresponding eigenfunctions. The mixed states constructed with "negative probabilities" display vanishing small position and momentum dispersion in the high temperature limit.
Some relationships within the nonlocal (pair–site) chemical reactivity formalism of density functional theory113(2000); http://dx.doi.org/10.1063/1.1327265View Description Hide Description
General and exact relationships within the nonlocal (pair–site) reactivity context are explicitly derived in the framework of density functional theory. The equations are expressed in terms of linear response functions and associated kernels of the Fukui function and its derivatives with respect to the electron number at constant external potential. It is shown that under a local approximation for the general nonlocal pair–site kernels, the nonlocality character of the chemical response must appear only implicitly through the changes in the chemical potential of the system. In the framework of a more general nonlocal reactivity theory, new relations can be written through the incorporation of more spatial coordinates. The case of a three-site equation between Fukui functions has been explored.
Extended kinetic models with waiting-time distributions: Exact results113(2000); http://dx.doi.org/10.1063/1.1326912View Description Hide Description
Inspired by the need for effective stochastic models to describe the complex behavior of biological motor proteins that move on linear tracks, exact results are derived for the velocity and dispersion of simple linear sequential models (or one-dimensional random walks) with general waiting-time distributions. The concept of "mechanicity" is introduced to conveniently quantify departures from simple "chemical," kinetic rate processes, and its significance is briefly indicated. The results are extended to more elaborate models that have finite side branches and include death processes (to represent the detachment of a motor from the track).
Quantum codes for controlling coherent evolution113(2000); http://dx.doi.org/10.1063/1.1326071View Description Hide Description
Control over spin dynamics has been obtained in nuclear magnetic resonance(NMR) via coherent averaging, which modifies the effective internal Hamiltonian, and via quantum codes, which can protect against decoherent evolution. Here, we discuss the design and implementation of quantum codes that enable modification of the internal Hamiltonian. A detailed example is given of a quantum code for protecting two data spins from evolution under a weak coupling term in the Hamiltonian, using an "isolated" ancilla that does not evolve on the experimental time scale. The code is realized in a three-spin system by liquid-state NMR spectroscopy on 13C-labeled alanine, and tested for two initial states. It is also shown that with internal interactions and isolated ancillae, codes exist that do not require the ancillae to initially be in a (pseudo-) pure state. Finally, it is shown that even with nonisolated ancillae, quantum codes exist which can protect against evolution under weak coupling. An example is presented for a six-qubit code that protects two data spins to first order.
Atoms in molecules, an axiomatic approach. I. Maximum transferability113(2000); http://dx.doi.org/10.1063/1.1327268View Description Hide Description
Central to chemistry is the concept of transferability: the idea that atoms and functional groups retain certain characteristicproperties in a wide variety of environments. Providing a completely satisfactory mathematical basis for the concept of atoms in molecules, however, has proved difficult. The present article pursues an axiomatic basis for the concept of an atom within a molecule, with particular emphasis devoted to the definition of transferability and the atomic description of Hirshfeld.
A mobile charge densities in harmonic oscillators (MCDHO) molecular model for numerical simulations: The water–water interaction113(2000); http://dx.doi.org/10.1063/1.1324711View Description Hide Description
In this work we present a new proposal to modelintermolecular interactions and use it for water molecules. The parameters of the model were fitted to reproduce the single molecule's electrostaticproperties, a sample of 352 points in a refined ab initio single molecule deformation potential energy surface (PES), and the theoretical limit of the dimerization energy, −20.8 kJ/mol. The model was able to reproduce a sample of 180 additional points in the single molecule deformation PES, and 736 points in a pair-interaction surface computed at the level with the counterpoise correction. Though the model reproduced the diagonal of the polarizability tensor, it could account for only 60% of the three-body nonadditive contributions to the interaction energies in 174 trimers computed at the level with full counterpoise correction, but reproduced the four-body nonadditivities in 34 tetramers computed at the same level as the trimers. The model's predictions of the structures, energies, and dipoles of small clusters resulted in good agreement with experimental data and high quality ab initio calculations. The model also reproduced the second virial coefficient of steam at various temperatures, and the structure and thermodynamicalproperties of liquid water. We found that the short-range water–water interactions had a critical influence on the proper performance of the model. We also found that a model based on the proper intermolecular interactions requires the inclusion of intramolecular flexibility to be adequate.
Efficient particle-mesh Ewald based approach to fixed and induced dipolar interactions113(2000); http://dx.doi.org/10.1063/1.1324708View Description Hide Description
We have implemented classical Ewald and particle-mesh Ewald (PME) based treatments of fixed and induced point dipoles into the sander molecular dynamics (MD) module of AMBER 6. During MD the induced dipoles can be propagated along with the atomic positions either by iteration to self-consistency at each time step, or by a Car–Parrinello (CP) technique using an extended Lagrangian formalism. In this paper we present the derivation of the new algorithms and compare the various options with respect to accuracy, efficiency, and effect on calculated properties of a polarizable water model. The use of PME for electrostatics of fixed charges and induced dipoles together with a CP treatment of dipole propagation in MD simulations leads to a cost overhead of only 33% above that of MD simulations using standard PME with fixed charges, allowing the study of polarizability in large macromolecular systems.
- Gas Phase Dynamics and Structure: Spectroscopy, Molecular Interactions, Scattering, and Photochemistry
The electronic structure and electron affinities of higher chlorine oxide radicals from photoelectron spectroscopy of anions113(2000); http://dx.doi.org/10.1063/1.1326067View Description Hide Description
The electronic structure of radicals were experimentally investigated using anion photoelectron spectroscopy of the respective anions at several photon energies. The electron affinities of and were obtained for the first time and were found to be very high, and respectively. Three low-lying excited states were observed for with excitation energies of 2.10 eV and The and states were found to be nearly degenerate. Two low-lying states were observed for at and whereas no excited state was observed for even at our highest photon energy of 157 nm (7.866 eV). The photoelectron spectra were assigned and compared with available theoretical calculations. The excellent agreement between the experimental and theoretical results confirmed the previous calculations.
Transient resonance Raman spectroscopy and density functional theory investigation of iso-polyhalomethanes containing bromine and/or iodine atoms113(2000); http://dx.doi.org/10.1063/1.1326064View Description Hide Description
We report additional transient resonance Raman spectra and density functional theory computations for the products formed following ultraviolet photoexcitation of solution phase polyhalomethanes containing bromine and/or iodine atoms. We show that the iso-polyhalomethane photoproduct is responsible for the intense transient absorption band observed in the 350–470 nm region after ultraviolet excitation of polyhalomethanes in the solution phase. We examine the trends and correlation in the density functional theory optimized geometry and intense electronic absorption transition in the 350–470 nm region for the iso-polyhalomethanes containing bromine and/or iodine atoms. We explore the chemical reactivity of the iso-polyhalomethane species using density functional theory computations for the reaction of with ethylene as an example. Our results and comparison with experimental data in the literature indicate that the iso-polyhalomethane species is most likely the methylene transfer agent in the cyclopropanation reactions of olefins using ultraviolet photoexcitation of polyhalomethanes in the solution phase. We briefly discuss the possibility that the photochemistry and chemistry of the iso-polyhalomethanes may give significant release of reactive halogens to the atmosphere.
Vibration–rotation transfer in molecular super rotors113(2000); http://dx.doi.org/10.1063/1.1326072View Description Hide Description
The collisional behavior of molecules in very high rotational levels of is considered. Highly efficient vibration–rotation transfer is predicted in these "super rotors" particularly when the conditions for quasiresonant transfer are fulfilled. This requires simultaneous near-resonance in energy and in angular momentum. Values of for which quasiresonant vibration–rotation transfer (QRT) occurs become smaller as initial rotor state increases and transfer is likely to become particularly fast for predicted to occur when This behavior is contrasted with the inefficiency of pure rotational transfer within the level for fast-rotating molecules. QRT will take place for quite cold collisions and thus will provide competition for the spinning-up process used to create the super rotors.
The spectrum and high-level ab initio calculations of the complex between NO and113(2000); http://dx.doi.org/10.1063/1.1326068View Description Hide Description
The results of two separate studies of the complex between NO and are reported. The spectrum of the transition of the complex between NO and is presented of improved quality over that reported previously, and the appearance of the spectrum is discussed. The results of high-level ab initio calculations on the state are also reported. The indications are that the NO moiety is more freely rotating in the complex than is and that a wide angular space is sampled in the zero-point energy level. The appearance of the REMPI spectrum suggests that the state is (close to) linear, and RCCSD(T)//QCISD calculations on the state, using Rydberg-function-augmented basis sets, suggest that the lowest energy linear isomer is the linear orientation. It is clear, however, that the understanding of this complex, and its spectroscopy, is far from complete, and will be challenging.
Cluster photofragmentation dynamics: Quasiclassical trajectory studies of and113(2000); http://dx.doi.org/10.1063/1.1326066View Description Hide Description
Quasiclassical trajectory calculations with modelpotential energy surfaces have been used to elucidate the formation dynamics of open-shell radical clusters by "gentle-recoil" photolysis of closed-shell hydride clusters. Specifically, modelsurfaces for and have been constructed and used to explore photofragmentation dynamics at 193 and 248 nm for comparison with previous experimental results. A remarkable efficiency (as high as 25%) for forming highly excited radical Ar–SH and clusters is calculated, despite photolysis recoil energies more than 100-fold in excess of the dissociation limit. This surprisingly high survival probability is traced to two dynamical sources. First, ejection of the light H atom from effectively removes all but a small fraction of the excess photolysisenergy from the nascent radical cluster in the center-of-mass frame. Second, although trajectory calculations indicate that nearly 50% of the surviving clusters contain energies up to two-fold higher than the dissociation limit, these clusters are classically bound due to novel angular momentum barriers predicted by Pollak [J. Chem. Phys. 86, 1645 (1987)] for a polyatomic system. Finally, an analysis is presented that indicates the "gentle-recoil" photolysis mechanism may permit efficient formation of highly internally excited, chemically reactive radical clusters of OH and SH with light species such as and
Dipole bound and valence state coupling in argon-solvated nitromethane anions113(2000); http://dx.doi.org/10.1063/1.1326476View Description Hide Description
The coupling between the dipole bound and valence electronic states of the nitromethane anion has been investigated via Rydbergelectron transferspectroscopy and field detachment spectroscopy of the bare and argon-solvated anions. The unique aspects of the nitromethane system are highlighted by comparing the solvation behavior of nitromethane anion with that of acetonitrile, a system in which the dipole bound state is well-isolated from the resonance arising from excess electron occupation of its high lying lowest unoccupied molecular orbital.
Thermodynamic study of the gaseous molecules AlN, and by Knudsen cell mass spectrometry113(2000); http://dx.doi.org/10.1063/1.1326848View Description Hide Description
The Knudsen effusion mass spectrometric method has been employed to measure the equilibrium partial pressures of the molecule over the AlN–Au–graphite system. Theoretical computations were carried out to determine the structure, molecular parameters, and thermodynamic properties of The partial pressures have been combined with the calculated thermal functions to determine the atomization enthalpy, and enthalpy of formation, in kJ mol−1, of and for respectively. Upper values for the dissociation energy of AlN, and for the atomization enthalpy of have been obtained. These results are discussed and compared with recent theoretical literature values.
Ab initio and quasiclassical trajectory study of the reaction on the lowest potential energy surface113(2000); http://dx.doi.org/10.1063/1.1327263View Description Hide Description
In this work we have carried out ab initio electronic structure calculations, CASSCF/CASPT2 with the Pople's 6-311G(2d) basis set on the ground singlet potential energy surface involved in the title reaction. Transition states, minima and one surface crossing have been characterized, obtaining three NNO isomers with the energy ordering: NNO Approximately 1250 ab initio points have been used to derive an analytical PES which fits most of the stationary points, with a global root-mean-square deviation of 1.12 kcal/mol. A quasiclassical trajectory study at several temperatures (300–1500 K) was performed to determine thermal rate constants, vibrational and rovibrational distributions and angular distributions. The dynamics of this barrierless reaction presents a predominant reaction pathway (96% at 300 K) with very short-lived collision complexes around the NNO minimum, which originate backward scattering and a similar fraction of vibrational and translational energy distributed into products. At higher temperatures other reaction pathways involving NON structures become increasingly important as well as the N-exchange reaction (3.02% of the branching ratio at 1500 K), this latter in accord with experimental data. It is concluded that the physical electronic quenching of by NO should be negligible against all possible reaction channels.
Severely perturbed vibrational structure in the 266–310 nm electronic transition of113(2000); http://dx.doi.org/10.1063/1.1326070View Description Hide Description
The laser induced fluorescence(LIF)spectra of are measured under jet-cooled conditions in the wide UV region of 266–310 nm, and 173 vibronic bands are identified. Among them, 77 and 68 vibronic bands were found to exhibit Σ–Σ type and Π–Σ type rotational structures, respectively. From the rotational analysis, the band-origin wave numbers and the rotational constants of the upper Σ and Π vibronic levels and K-type doubling parameters for the Π vibronic levels are determined. The rotational constants for the Σ and Π vibronic levels exhibit, respectively, similar distributions with almost the same mean values, and 0.398(17) cm−1, indicating that the Σ and Π vibronic levels have the same electronic origin and that the average C–C bond distance of the upper electronic state in the observed energy range is about 1.331(25) Å, which is longer than the electronic ground state by 0.054(25) Å. The convolution and Fourier-transform analyses are performed separately for the spectra composed only of Σ–Σ type and Π–Σ type vibronic bands to derive estimates of the vibrational fundamentals in the upper electronic state. The low fundamental of 940(60) cm−1 derived from these analyses and the seemingly regular progression in the convoluted spectra indicate that the bright character is carried primarily by the transitions to the vibrational levels in the electronically excited state and is distributed into a large number of the originally dark transitions to the vibrational levels in the electronically excited state, resulting in the exceedingly complex vibronic band system. © 2000 American Institute of Physics.
Vibrational wave packets in the and states of Determination of improved and spectroscopic constants113(2000); http://dx.doi.org/10.1063/1.1326065View Description Hide Description
Vibrational wave packets in the and excited states of have been studied on the ∼100 fs time scale by pump–probe laser spectroscopy. The temporal behavior of the wave packets was monitored by photoionizing the electronically excited molecule with a time-delayed probe pulse and recording the time and energy-integrated photoelectron signal as a function of time delay between the pump and probe pulses. For the experiments, wave packets were produced by exciting the transition in the ∼740–790 nm region and subsequently detected by photoionizing the molecule at wavelengths between 565 nm and 600 nm. By simulating the experimentally observed transients with the density matrix formalism (and explicitly accounting for laser chirp and coherences), improved values for the equilibrium internuclear separation for the state and for the state were determined to be and respectively. Similar experiments were conducted for the state. Wave packets composed of vibrational levels perturbed by the bound state were produced on the potential surface by driving the transition in the 575–610 nm spectral interval.
Statistical rate theory for the reaction system: SACM/CT calculations between 0 and 5000 K113(2000); http://dx.doi.org/10.1063/1.1314374View Description Hide Description
The potential energy surface of the reaction system is characterized by ab initio calculations. The complex-forming bimolecular reaction is then treated by statistical rate theory, using statistical adiabatic channel and classical trajectory calculations for the and association/dissociation processes. Specific rate constants of both reactions as well as thermal rate constants are calculated over wide ranges of conditions. Open shell quantum effects are important up to room temperature. The good agreement with experimental results suggests that the ab initio potential is of sufficient accuracy. There is no evidence for non-statistical effects or for a significant contribution from electronically excited states. The comparison with rate data for the reaction, because of the remaining uncertainty in the heat of formation of HO, is somewhat inconclusive. Apart from this problem, the calculated rate constants appear reliable between 0 and 5000 K.
Effect of pressure and temperature on the competition between nondissociative and dissociative electron attachment to113(2000); http://dx.doi.org/10.1063/1.1311800View Description Hide Description
Branching between the nondissociative, and dissociative, products of the electron attachment reaction has been examined as a function of buffer gas pressure and temperature. A strong positive pressure dependence is observed for the nondissociative channel, where at 303 K, the increases from 31% at 1 Torr to 94% at 675 Torr total pressure. Conversely, the dissociative channel displays a strong positive temperature dependence. The effect of pressure and temperature on the relative amounts of and observed is discussed in terms of the competition between the collisional stabilization and dissociation rates of the excited intermediate. The decomposition of is modeled with Rice–Ramsperger–Kassel decomposition kinetics weighted by the vibrational energy distribution of neutrals. This model provides an excellent simulation of the experimental pressure and temperature dependencies of the electron attachment process.


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NW Side Costume Store Gearing Up For Last-Minute Halloween Shoppers
6 Best Halloween Makeup Instructional VideosPair that Halloween costume with the perfect makeup with the help of these YouTube instructional videos.
Trump Wigs, Jurassic Park Costumes Among Big Halloween Sellers At NW Side ShopThe cool weather in the past week has some people thinking about fall -- and Halloween costumes.
Costume Store Manager Says Customers Using 'Breaking Bad' Haz Mat Suits To Design Ebola CostumesWhat do you get when you cross the TV show "Breaking Bad" with current events? The answer is: one of this year's most popular - and perhaps most tasteless - Halloween costumes.
Best Trendy Halloween Costumes Of 2014Need some inspiration for this season's Halloween costume? Check out these trendy Halloween costumes inspired by pop culture.
How To Make DIY Halloween MasksUse everyday materials to design your own Halloween masks in just a few hours.
How To Get Your Halloween Costume On A Budget In ChicagoWith a little imagination, you can put together a great costume for the price of candy using items from these Chicago shops.
Best Halloween Costumes of 2013Halloween is right around the corner! Have you thought of your costume yet? We list the top costumes of 2013 that are sure to be hit.
Meredith Sinclair Gives Halloween Shopping Tips
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Members of the Satsuma Board of Education reflected on an exciting first year of operations during their meeting Tuesday night, at which they reinstated their president and vice president to office for 2013-14 and welcomed back Jimmy Upton, who was reappointed by the Satsuma City Council to the board for an additional five-year term.
Linda Robbins and James Woosley will serve as president and vice president, respectively. In its first year, the board "has far exceeded what we ever thought we could do," Robbins said after the meeting.
The system's first high school graduation ceremony was the highlight of the year, with a filled stadium of spectators, Upton said. "It was a real feel of true community," Robbins added.
School superintendent Joe Walters gave the board an update on several housekeeping issues, including efforts to clear out the 16 portable classrooms, which the school system no longer needs. He hopes to sell or donate them this summer, he said.
Walters also said the HVAC system at the high school, which remains under a service contract inherited from the Mobile County school system, was undergoing repairs to improve its automation. Right now, he said, in an effort to reduce energy costs, employees must shut off the classroom units by hand, sometimes having to climb up on the roof to do so.
The board will hold two public hearings during the summer for review of the school system's budget for the coming year, which must be approved in September. For the fiscal year ending June 30, 2013, the overall budget is about $11.6 million.
The board called a public hearing for Thursday, June 27, at 5 p.m. to hear comments on a proposed change to the school system's attendance policy. Under the change, students would be allowed eight parent notes per school year in order to receive excused absences. After the eighth note, a doctor's excuse would be required.
The next school board meeting will follow the public hearing on Thursday, June 27.
The school system is on a summer work schedule through July 26. Office hours for both schools and the Central Office are 7:30 a.m. to 5 p.m. Monday through Thursday and 7:30 to 11:30 a.m. on Fridays.
All members of the board plan to attend the Alabama Association of School Boards conference next week at the Perdido Beach Hotel in Orange Beach. The conference will give them the opportunity to fulfill training requirements set out by state Superintendent Tommy Bice in December.
According to the new guidelines, starting July 1, 2013, all school board members are required to complete six hours of training annually, and at least two hours of that training must be whole-board, interactive training – that is, sessions attended by most of the board members.
School board members can also earn the hours through conferences, webinars, online courses and on-site training. Members are also required to have orientation training. All training must either be provided by AASB, or approved in advance.


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Are Mexicans Violent Because of Their Aztec Blood?
DEAR MEXICAN: Recently, a co-worker turned me on to a website that features videos of unspeakable atrocities the drug cartels are committing in Mexico, many of them graphically displaying murders and beheadings. I just recently saw one of a woman getting her head cut off with a knife! I wish I had never seen this, but it can't be unseen. Most Mexicans I have met are very nice, generous people. Mexico is also such a strong Catholic country, and the church preaches to be good and helpful to your fellow man. So, how can it be possible that these types of evil people really exist there? Is it because they still have the Aztec blood running in them? As we know from history, the Aztecs were notorious butchers and cannibals.
Puzzled By Narco Violence
DEAR GABACHA: As we also know from history, the English used to draw and quarter people, then place their body parts in different areas of the country—so what's your point? Do we blame the English for the atrocities that some American soldiers have committed in Iraq and Afghanistan? Do we blame them for Ed Gein? Or for the lynchings of African-Americans that gabachos committed through the mid-20th Century? Of course not—such talk of sanguinary determinism is as stupid as racists freaking out that a Mexican-American boy from San Antonio sang the National Anthem before an NBA Finals game dressed in a mariachi suit. (Would Know Nothings have freaked out if a gabacho in a kilt had done the same? Is the Mexican government now corruption-free?) Refry this: Drug cartels commit atrocious crimes because drug cartels are criminal enterprises—and last time I saw The Godfather, criminal enterprises try to strike fear in one another by being more brutal toward their enemies (and even innocents) than the other guys. But if you want me to play your game, why didn't you include the Spanish side of the mestizo equation in your pregunta? After all, they plundered their way through the Americas in ways that would make the Aztecs seem as peaceful as Quakers.
Ask the Mexican at firstname.lastname@example.com, be his fan on Facebook, follow him on Twitter or ask him a video question at youtube.com/askamexicano!
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DEAR MEXICAN: I've been playing pickup basketball at a gym in Alhambra near El Sereno. Some of the guys who play are covered head-to-toe in tattoos and have their heads shaved. Are they cholos or La Eme, or is this the current fashion? They seem like nice-enough guys, but they have tattoos all over their necks and heads. Do fellows get those outside of prison? If so, why do they do that?
Afraid to Call a Foul
DEAR GABACHO: What does it matter to you? All you should care about during a basketball game is kicking the other team's ass and humiliating whoever is guarding you. Why do the guys you play with have so many tattoos and shave their heads? Why don't you ask them? If they're willing to rub their sweaty bodies against you, I'm sure they're more than happy to explain why they look the way they do. But you probably won't because that'll ruin your hipster fantasy of being so down with la raza that you can post up on a Mexican Mafia member in the barrio without getting killed. Are they cholos? Maybe, but you didn't describe their tattoos, so I won't make any assumptions, as you do. For all you know, the opposing center who most likely schools your ass three times a week could be a Cal Tech cabrón.
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Subwoofer Rumble
Hi, new to the forum. I've always used AVS whenever researching home audio equipment or had general. audio questions, so I'm glad I finally joined the forum. Within the last few months, I've finally upgraded my equipment from a Sony htib. The difference is night and day and I've found a new hobby that I really enjoy. Although recently purchasing my first home and having a second baby due soon, I can't go as crazy as I'd like. Anyways, my question is regarding subwoofer rumble, and it's totally a newbie question. In the last two weeks, I've upgraded my subwoofer from a cheap 10" Sony, to a Polk PSW110, to finally a Bic America F12. Neither the Sony or the Polk rumbled like the Bic and I'm wondering what's causing it. It just gets a little annoying during deep bass scenes when the subwoofer itself is making noise. I may be expecting too much out of it, but neither of my previous subs did it. I know it's not anything around the sub vibrating, it's the actual subwoofer. I know it's not the floor neither, I've held the sub in the air and it still does it. Also, I've shaken the sub and it doesn't sound like anything is loose in there. Each subwoofer was calibrated to 75db so I don't believe that it's happening because it's simply louder. Can it be the fact that the bic can get deeper but at the same time not handle it too well? If that is the case, I'd rather have a sub with less extension but can handle itself. Any feedback would be awesome, and I apologize ahead of time for such an amateur question.
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Gold - G Line
The Gold Line is an 11.2-mile electric commuter rail transit line that will connect Union Station to Wheat Ridge, passing through northwest Denver, Adams County and Arvada. It is part of the Eagle P3 Project. The Gold Line has eight stations: Union Station, 41st•Fox, Pecos Junction, Clear Creek•Federal, 60th & Sheridan•Arvada Gold Strike, Olde Town Arvada, Arvada Ridge and Wheat Ridge•Ward It is scheduled to open to the public in 2016.
Testing underway, construction continuesTesting is underway on the G Line while construction activities continue.
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Gold Line GroundbreakingRTD received a $1.03 billion Full Funding Grant Agreement from the Federal Transit Administration on Aug. 31, 2011. See the event here.
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Man charged in crash into Rutland Town homeStaff Report | January 24,2013Vermont State Police have made an arrest in the hit-and-run crash at a Cedar Avenue home.
Police said early Thursday morning that Stephen C. Hopkins had been cited to appear next month in Rutland criminal court on a charge of leaving the scene of an accident.
Hopkins is accused of running a 2002 Chevrolet Cavalier into the northwest corner of a house, doing significant damage to the building.MORE IN This Just InMerchants Bank will merge with a New York-based bank, according to a statement issued Monday on... Full StoryBRATTLEBORO A Wardsboro man who Vermont State Police say shot his neighbor to death last week... Full StoryREADING A thief has made off with five chain saws belonging to the town of Reading, police said. Full Story
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Original articles from our library related to the Outland Comic Reprints. See Table of Contents for further available material (downloadable resources) on Outland Comic Reprints.
- Mythic Heroes of Celtic Ireland
- The Celtic mythology of Ireland is best summarized as consisting of four broad cycles. This month's article deals with mythic Celtic mortals, figures who populate the stories in the second and third cycles below. Four Cycles of Irish Mythology Foundation...
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- The Mabinogion
- Welsh mythological prose finds its most enchanting breath in the Mabinogion, a collection of stories about the gods and goddesses of the Celtic Britons. More formally the work is known as the Four Branches of the Mabinogi. Although the full set of tales...
Deities & Heros >> Celtic, Welsh, Irish & Brittish
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The Springfield Museums' monthly tour and lecture schedule continues in March with the popular Thursday Museums à la Carte lectures, held weekly at 12:15 pm in the Michele and Donald D'Amour Museum of Fine Arts. Admission is $4 ($2 for members of the Springfield Museums); visitors are invited to bring lunch (cookies and coffee are provided). The programs are sponsored by Big Y World Class Market. For more information about Museums à la Carte, call 413.263.6800, ext. 488.
- March 6 – Unlaunch'd Voices: An Evening with Walt Whitman. Through poetry and readings of actual letters, actor Stephen Collins enables audiences to experience Whitman's growth into a mature artist at peace with "himself, God and death."
- March 13 – Stories of a Fiddler. Sarah Michel, a.k.a "Sarah The Fiddler," will cover various fiddle styles from Irish to Bluegrass, along with stories of Sarah's own experiences in New England Fiddle Contests.
- March 20 – Introduction to Arts of the Islamic World. Kendra Weisbin, guest curator of George Walter Vincent Smith Islamic Gallery, will offer a broad introduction to the art of the Islamic world, and discuss some of the highlights from the Museums' collection.
- March 27 – Leaving van Gogh: Fact and Fiction in a Historical Novel. Author Carol Wallace discusses the challenge and inspiration involved in bringing Vincent to fictional life – and death.
Also scheduled in March are informal half-hour "mini-tours" every Sunday at 1 pm by volunteer docent educators. The tours highlight a different element of the unique collections of one of the four museums, and are free with Museum admission (check with the Welcome Center staff or the Museums' website for an updated schedule of mini-tours). Topics for March are:
- March 2 – Mr. Barney: the Man Who Put America on Ice-Skates! Bobby Girard, Wood Museum of Springfield History.
- March 9 – How the Hudson River School Landscape Artists captured the American Soul during the 19 Century, Kate Belhumeur, D'Amour Museum of Fine Arts.
- March 16 – Man & War, Betty Romer, DMFA.
- March 23 – Fakes and Forgeries: Intent to Deceive Special Exhibition, Adele Gladstone-Gilbert, DMFA.
- March 30 – Revolution vs. Tradition: A look at Modernism and Regionalism in the early 20th Century, Pat McCarthy, DMFA.


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Best of British Eco Supplies
Welcome to GreenBuying.co.uk, your number one choice for UK sourced eco business and school supplies. Unlike other websites which sell green supplies as an "add-on", green products is all that we do. So buying from this site will build your green credentials whilst supporting the environment and British manufacturers. We maintain competitive prices and an efficient delivery service.
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Video: The Concert Corner - Previewing Carrie Underwood, Big Boi and more
If this week is any indication of the summer concert season in Milwaukee, then prepare yourself for a very exciting couple of months. The live music options this week are just staggering - from the first big arena tour of the year with Carrie Underwood, to the Miltown Beatdown finals, to the four-day Foster Fest event, to an intimate show with Sara Bareilles and a Friday concert with one-half of Outkast, Big Boi.
I boil down all the highlights for this week's Concert Corner chat with CineStars' Brittany Umar. »Read Full Blog Post
2 artists win downtown Milwaukee public art showdown
Pavilions inspired by Milwaukee's historic bridge wars and off-kilter city grid, and giant webs of brightly colored bungee cord that will accent architecture and cross spans of Wisconsin Ave. were the two projects that won out during a public art showdown at City Hall on Tuesday evening.
A dozen finalists got on stage and pitched their ideas for the Creational Trails placemaking initiative, which will take place along 10 blocks of W. Wisconsin Ave. during the summer and fall. At stake was $50,000. »Read Full Article(6)
Lady Gaga to headline Summerfest June 26
Be on the lookout for a parade of meat dresses, clam-shell bras, maybe even a flying dress or two, when a swarm of Milwaukee's Little Monsters invades the Summerfest grounds June 26 to see Lady Gaga headline the Marcus Amphitheater.
Gaga is the first confirmed headliner for the 2014 edition of the Big Gig, running June 25 to 29 and July 1 to 6. It will be her first Milwaukee appearance since a wild sold-out show at the Bradley Center in 2010, where thousands of revelers showed up in outlandish Gaga-inspired get-ups. »Read Full Article(32)
Trailer for 'Godzilla' reboot, with effects by Kenosha native Jim Rygiel
The first trailer has been released for "Godzilla," the reboot of the classic Japanese monster film, whose visual effects have been designed by Kenosha native Jim Rygiel, who won three Oscars for "The Lord of the Rings" films.
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Busta Rhymes and Q-Tip 'The Abstract and the Dragon' trailer
I've been impatiently waiting for Busta Rhymes and Q-Tip's The Abstract and The Dragon for a few months now. We have already posted the video for their banging first single "Thank You". They recently released a trailer featuring busta rhymes taking a journey through him and Q-Tip's 20 plus year relationship. It's full of vintage performance footage and interviews. The Abstract and The Dragon drops on at Midnight on 12-12-13 (for all the Midnight Marauders). Check out the trailer below then watch the Arsenio clip featured in the trailer in case you didn't get to see that when it happened many moons ago. Man, I am old. »Read Full Blog Post(1)
British tabloid publishes photos from Ryan Braun's wedding
The British tabloid Daily Mail published a few fuzzy photos of Ryan Braun's marriage to model Larisa Fraser in its online edition Tuesday morning - tabloid headline and all.
The couple was married Saturday in a family ceremony in Malibu, Calif. »Read Full Blog Post(19)
On Tap Today: Free goodbye party for the Onion, A.V. Club Milwaukee and RadioMilwaukee's Mark Keefe
Milwaukee band Kane Place Record Club will perform at a free goodbye party for the Onion's local print edition, A.V. Club Milwaukee arts and entertainment website and RadioMilwaukee program director Mark Keefe, at Turner Hall Ballroom Tuesday. Journal Sentinel photo by Bill Schulz. »Read Full Blog Post


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I wish to run optimization for getting the maximum frequency tuning range of a VCO. This means that i need two frequencies corresponding to Vtune=0 V and Vtune=1.2V. (Vtune is the voltage applied to the varactors)
The optimization should then take the difference of the two frequencies and maximize it based on the parameters given.
To achieve this, i added two tests providing the two frequencies and naming them Freq0 and Freq1 but ADE-GXL does not allow to write an expression including outputs from two different tests.
Is there a way to write an expression like Freq1-Freq0 and then add a specification to maximize it? Please see attached screenshot for reference.
Kind help from the Cadence officials will be appreciated. Any other method which i can do?
What you need is the calcVal() function. You can use calcVal("outName" "testName"). The easiest way is to bring up the calculator, and then drag from the ADE XL output pane - pick the output you wish to reference - and then drag into the calculator input buffer. This will automatically generate the calcVal() expression for you. Then you can have an output on one of the two tests which references the other test; ADE XL/GXL will take care of ensuring that the tests are run in the right order so that it can do the calculation.
In reply to Andrew Beckett:
Thanks Andrew and Firas Barakat who sent a detailed email to answer the question. I am able to combine the two outputs of different tests in one expression.
Kind Regards.
In reply to hmcheema:


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The Last Day of August
- Studio: Striped Entertainment
- Release Date: Oct 4, 2013
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This static, talky effort ultimately doesn't justify its feature-length running time despite some strong performances and the occasional moving moment.
Decently crafted but with not quite enough up its narrative sleeve to make a memorable impact, writer-director Craig DiFolco's debut feature leaves one waiting for explosive revelations that never arrive.
The film benefits from nice performances and nice work by Mr. DiFolco (making his directorial debut), even if the ending is not as psychologically complex as earlier scenes lead us to hope.


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realmagick.com The shrine of knowledge.
Anime Genres
A selection of articles related to anime genres.
Original articles from our library related to the Anime Genres. See Table of Contents for further available material (downloadable resources) on Anime Genres.
- Black Gospel Music
- Black Gospel music is also known as Urban Contemporary Gospel music. Its roots were the Negro spiritual songs that were sang by the African slaves while tilling the rich cotton fields of their white Southern masters in the early 18th century.
>> Poetry & Fable
Anime Genres is described in multiple online sources, as addition to our editors' articles, see section below for printable documents, Anime Genres books and related discussion.
Suggested News Resources
- Cowboy Bebop - Whatever Happens, Happens.
- Bebop was the perfect ending to the era of 90s anime, as it exhibited some of the decade's most important themes: loneliness, existentialism, and death, as well as proving how far the anime genre had come since the 80s. While many influential series ...
- Whats the anime for you? A look at the 5 types of anime?
- So anime has five types. Each of these five types—shonen, shojo, seinen, josei, and kodomomuke—is focused on a specific target demographic. They are not genres (action, romance, coming of age, etc.
- What's The Best (And Worst) Anime Ending You've Ever Seen?
- The odd sequence of "easy come easy go" vignettes that follows for Spike's makeshift family of Jet, Faye, Ed, and Ein, encompassing all sorts of tones, genres, and little endings both happy and sad, only equal out to zero in his own eyes.
- The Beginner's Guide to Anime, No. 148 – Rozen Maiden
- The series examined this time seems to combine a wide range of elements: drama, comedy, fantasy, the supernatural, Japanese fashion, and arguably elements of anime's "harem", "magical girl" and "death game" genres, which will be explained later on.
- Netflix animated over new Anime series 'Perfect Bones'
- Netflix hopes you'll find Perfect Bones to be "Anime-zing". If Netflix is keen on taking over the entertainment world, as appears to be the case, there are certain genres it just can't ignore. Such as Anime.
Great care has been taken to prepare the information on this page. Elements of the content come from factual and lexical knowledge databases, realmagick.com library and third-party sources. We appreciate your suggestions and comments on further improvements of the site.
Anime Genres Topics
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Wot r ur kids txting? If you're wondering -- or 1dering -- there's a new online translation tool that helps decipher the code.
Mobile phone maker LG Electronics MobileComm USA has launched "DTXTR," a Web service which translates teen text speech into plain English.
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MAS Boston operates the new Islamic Cultural Center in Roxbury (ISBCC). MAS Boston is a grassroots, community organization that works to educate, organize, and empower the Muslim community to be active, contributing citizens who play a significant role towards positive social and spiritual change. We strive to achieve this mission by: 1) teaching young Muslims social responsibility and equipping them for leadership, 2) educating and organizing the Muslim community towards civic engagement, and 3) developing interfaith and intercommunity understanding and cooperation, and creating coalitions on issues of shared concern.
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The Foundations of Business Cycle Theory (Elgar Mini Series)
These three volumes, sold in a set, cover the foundations of business cycle theory from the mid-19th century, through to the work immediately affected by the publication of Keynes's General Theory. It uncovers some theories that were overshadowed by the advent of Keynes's work.
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Hadrian Greece
A selection of articles related to hadrian greece.
Original articles from our library related to the Hadrian Greece. See Table of Contents for further available material (downloadable resources) on Hadrian Greece.
- Hulse, David Allen
- >From an early age, David Allen Hulse has made a diligent study of the alphabets of the ancient world. Even as a child, David possessed a great affinity for the alphabets of Egypt, Phoenicia, and Greece. In college, a reading of MacGregor Mathers' Kabbalah...
Real Interviews >> Authors
- Hulse, David Allen
- From an early age, David Allen Hulse has made a diligent study of the alphabets of the ancient world. Even as a child, David possessed a great affinity for the alphabets of Egypt, Phoenicia, and Greece. In college, a reading of MacGregor Mathers' Kabbalah...
Real Interviews >> Authors
- Conium maculatum (Poison Hemlock)
- In ancient Greece Poison Hemlock was a regularly used punishment for criminals. In 399 BC the great philosopher Socrates was killed this way; his crime consisted of teaching people to think for themselves - a great evil in old dictatorial Greece. Thanks to...
Remedies >> Remedies C
- The Horned God in India and Europe
- Of all of the Gods that we honor in Paganism today probably the most revered is the Horned God, in the shape and form of Cernunnos. Pick up some modern Pagan literature and chances are he is in there, listen to conversation at a Moot and you will hear him...
Deities & Heros >> Celtic, Welsh, Irish & Brittish
- The Pagan Origins Of Christian Mythology
- The Judeo-Christian religions were founded in a region of the world where savior religions existed for thousands of years. Much of the symbolism and many of the stories in the Bible may be traced to earlier myths of the Persians, Egyptians, and other people...
Religions >> Christianity & Paganism
- Grimassi, Raven
- Raven Grimassi is the author of several books on Wicca and Witchcraft, including The Wiccan Mysteries, which was awarded Book of the Year and First Place-Spirituality Book by the Coalition of Visionary Retailers in 1998. Raven Grimassi was born in 1951 to an...
Real Interviews >> Authors
Hadrian Greece is described in multiple online sources, as addition to our editors' articles, see section below for printable documents, Hadrian Greece books and related discussion.
Suggested Pdf Resources
- www.ascsa.edu.gr
- the altars of hadrian in athens and hadrian's panhellenic program'
- Hadrian.2 The existence, however, of so many altars in Athens raises, ... Greek peoples is natural, and Hadrian's willingness to accept divine honors and his.
- www.ascsa.edu.gr
- 4 - Universität zu Köln
- HADRIAN AND GREEK SENATORS. 'Studies of this kind proceed by experiment and are subject to hazard'. (R.
- www.uni-koeln.de
- Hadrian's Second Jewish Revolt: Political or Religious - Western
- promise of Hadrian to the Jews to rebuild the Jewish temple, which he later ... explanation was Hadrian's infinity for Greek culture, this infinity could have shaped ...
- www.wou.edu
- Hadrian's Religious Policy: An Architectural Perspective By Chelsie
- The thesis discusses in turn: Hadrian's building projects within the city of Rome, his villa at Tibur, and various projects in the provinces of Greece and Judaea.
- thescholarship.ecu.edu
Suggested News Resources
- The Week in Pictures: March 3 - 10
- Refugees and their children watch cartoons projected on the side of a van on the Greek-Macedonian border near Idomeni, Greece, on March 5, 2016. Thousands of migrants and refugees are stranded at a border camp in Idomeni, unable to cross into ...
- Today's top pics: Paris fashion collection and more
- A woman holds the hand of a toddler walking on a railway track at the northern Greek border station of Idomeni, Monday, March 7, 2016.
- Photos of the Day: March 7
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- The Northern Lights, or Aurora Borealis, shine over the Sycamore Gap at Hadrian's Wall. Owen Humphreys – Associated Press. Gallery: The Northern Lights, or Aurora Borealis, shine over the Sycamore Gap at Hadrian's Wall in Northumberland, northeast ...
- Grimm's 100th Episode Will Only Complicate Nick and Adalind's Relationship
- Nick (David Giuntoli) and Adalind (Claire Coffee) are still trying to figure out how to define their relationship and feelings for each other in the middle of a war between the uprising wesen in the Black Claw and the government-controlled Hadrian's Wall.
Suggested Web Resources
- Hadrian - Wikipedia, the free encyclopedia
- [edit]. Hadrian and Antinous – busts in the British Museum. In September 128, Hadrian ...
- en.wikipedia.org
- Arch of Hadrian (Athens) - Wikipedia, the free encyclopedia
- The Arch of Hadrian (Greek: Αψίδα του Αδριανού Apsida tou Adrianou), most commonly known in Greek as Hadrian's Gate (Πύλη του Αδριανού Pyli tou ...
- en.wikipedia.org
- Hadrian - Ancient History Encyclopedia
- Nov 15, 2012 Hadrian (76-138 CE) was the fourteenth Emperor of Rome (10 August ... His love for Greece and Greek literature was such that he was known ...
- www.ancient.eu
- Emperor Hadrian - The Roman Empire
- Details the events in the life of the Emperor Hadrian.
- www.roman-empire.net
- Hadrian | Roman emperor | Britannica.com
- Jul 12, 2015 Roman emperor (117–138 ce), the emperor Trajan 's cousin and successor, who was a cultivated admirer of Greek civilization and who unified ...
- www.britannica.com
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Paranormal State
My Journey into the Unknown
by Ryan Buell, Stefan Petrucha
- #5 in Nonfiction, Entertainment, Performing Arts, Television
- #5 in Nonfiction, Entertainment, Television
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On the hit A&E series Paranormal State, Ryan Buell and his team of investigators delve deep into the mysterious world of ghosts, demonic disturbances, and sixth-sense sightings that shadows our everyday reality. Now, in this official companion book to the series, Buell takes you one step further, revealing the secrets of the show's most intense cases and the shocking, never-before-told story of his own brush with the supernatural—the otherworldly experience that first inspired him to found the Paranormal Research Society.
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Paranormal state
Awesome book. Miss the show. Get better real soon Ryan! <3by T on May 01, 2013
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Very Interesting read....keeps you h
Loved the way this book was constructed, for beginners to exeptionally knowledgeable.by Roxana on October 20, 2013
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I found this book enlightening. It told me things about him I never knew before.by zadah on January 23, 2014
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- HarperCollins, September 2010
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Golden Axe Story
A selection of articles related to golden axe story.
Original articles from our library related to the Golden Axe Story. See Table of Contents for further available material (downloadable resources) on Golden Axe Story.
- Serveral Simple But Useful Meditations
- MEDITATIONS Before you start any kind of meditation, here are a few tips: Pick a place where you will not be disturbed. If you want, you may put on some relaxing music or nature sounds to keep you from possible distractions. Get into an upright position...
Mind >> Meditation
- Story of the Soul Tarot Layout
- "I looked on my right hand, and beheld, but there was no man that would know me: refuge failed me; no man cared for my soul." Psalm 142, Verse 4 KJV "Three things distinguish living from the soul versus living from the ego only. They are: the...
Divination >> Tarot Cards
- Story of the Celts: The Ancient Celts
- The Ancient Celts [ 8 ] What is surprising to most modern readers is just how widespread across Europe the Celts once were. The Celts have been called the "Fathers of Europe," that is north of the Greco-Roman Mediterranean. Long before the Germanic...
History & Anthropology >> Celtic & Irish
- Story of the Celts: The Celts in Britain
- The Celts in Britain [ 27 ] What is obvious when studying the Celts, as when studying anything, is that different experts say different things--there are always men of knowledge who have conflicting views about specifics. The dates of when the Celts came to...
History & Anthropology >> Celtic & Irish
- After Midnight: A True Ghost Story
- The nervous chatter of the tourists echoed through the musty catacombs of the ancient city of Edinburgh. If I lingered behind the crowd, would that improve my chances of seeing a ghost? Or perhaps any spectral visitor would be put off by the unstable energies...
Ghosts >> Ghost Stories
- Story of the Celts: The Celts of Ireland
- The Celts of Ireland [ 33 ] The Celts arrived in Ireland by 350 B.C (some say earlier) and they thrive there to this day. A claim might be made that the Celtic Irish are among the world's oldest nationality groups. Despite periods when foreigners tried in...
History & Anthropology >> Celtic & Irish
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Old Testament >> Numbers
Golden Axe Story is described in multiple online sources, as addition to our editors' articles, see section below for printable documents, Golden Axe Story books and related discussion.
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