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Most Cited Inorganica Chimica Acta Articles
The most cited articles published since 2011, extracted from Scopus.
Recent progress on fluorescent chemosensors for metal ionsYongsuk Jeong | Juyoung Yoon
Volume 381, Issue 1, February 2012, Pages 2-14
The recognition and sensing of the biologically and environmentally important metal ions has emerged as a significant goal in the field of chemical sensors in recent years. Among the various analytical methods, fluorescence has been a powerful tool due to its simplicity, high detection limit and application to bioimaging. This review highlights the fluorescent chemosensors for metal ions, which have been recently developed from our laboratory. This review was categorized by target metal ions, such as Cu 2+, Hg 2+, Zn 2+, Pb 2+, Cd 2+, Vanadate, Ag + and Au 3+. Selectivity and sensitivity for these metal ions were achieved by introducing various ligands to core fluorophores, such as, rhodamine, fluorescein, pyrene, anthracene, naphthalimide, coumarin, and BODIPY. © 2011 Elsevier B.V. All rights reserved.
PhotoCORMs: Light-triggered release of carbon monoxide from the coordination sphere of transition metal complexes for biological applicationsUlrich Schatzschneider
Volume 374, Issue 1, August 2011, Pages 19-23
Carbon monoxide is now well-established as a small-molecule biological effector in the human body. Metal-carbonyl complexes are a promising way to achieve safe and controlled delivery of CO for therapeutic applications and thus, such CO releasing molecules (CORMs) have achieved significant attention in the last 10 years. In most CORMs, the liberation of carbon monoxide is triggered by hydrolytic processes in aqueous medium and thus their half-life under physiological conditions determines their potential therapeutic utility. To overcome such limitations, photo-induced CO release from dark-stable metal-carbonyl complex prodrugs is an interesting alternative. Thus, in this review, the current knowledge on PhotoCORMs is summarized and their properties critically evaluated. The main challenge for the future will be to achieve photolytic liberation of carbon monoxide by near-IR excitation in the phototherapeutic window of the cell. Different ways how this goal might be achieved are discussed. © 2011 Elsevier B.V. All rights reserved.
A series of [Cu(N-N)(P-P)]BF 4 complexes: Luminescence quenching caused by electron-configuration transformation in excited stateLiming Zhang | Shumei Yue | Bin Li | Di Fan
Volume 384, Issue , April 2012, Pages 225-232
In this paper, we report a series of [Cu(N-N)(P-P)]BF 4 complexes based on two phosphorous ligands and three 1,10-phenanthrolin derived diimine ligands, including their syntheses, characterizations, crystal structures. Their photophysical properties were experimentally measured and theoretically analyzed by time-dependent density functional theory (TD-DFT). It is found that the introduction of too many fused phenyl rings into diimine ligand leads to luminescence absence of corresponding [Cu(N-N)(P-P)] + complexes at room temperature. A detailed analysis suggests that the thermal activated electron-configuration transformation between the [Cu(N-N)(P-P)] + triplet metal-to-ligand-charge-transfer ( 3MLCT) state and the lowest lying excited state of its diimine ligand ( 3LC) is responsible for the luminescence quenching. © 2011 Elsevier B.V. All rights reserved.
Synthesis, structures, and urease inhibitory activities of oxovanadium(V) complexes with Schiff basesZhong Lu You | Da Hua Shi | Ji Cai Zhang | Yu Ping Ma | Che Wang | Kun Li
Volume 384, Issue , April 2012, Pages 54-61
A series of oxovanadium(V) complexes, [VO 2L 1] 2 (1), [VO 2L 2] 2 (2), [VO 2L 3] 2 (3), [VO 2L 4] 2 (4), [VO(OCH 3)L 5] (5), and [VO(OCH 3)(HOCH 3)L 6] (6) (HL 1 = 2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenol, HL 2 = 4-chloro-2-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenol, HL 3 = 2-methoxy-6-[(2-methylaminoethylimino)methyl]phenol, HL 4 = 4-chloro-2-[(2-methylaminoethylimino)methyl]phenol, HL 5 = N′-(2-hydroxy-3-ethoxybenzylidene)-3-hydroxy-2-naphthohydrazide, and HL 6 = N′-(2-hydroxy-5-chlorobenzylidene)-3-hydroxy-2- naphthohydrazide), have been prepared and structurally characterized by physico-chemical methods and X-ray diffraction. The inhibition rates (%) with the concentration of 100 μM for the complexes on Helicobacter pylori urease are 18.96 ± 0.44 (1), 33.01 ± 1.80 (2), 35.83 ± 0.78 (3), 48.09 ± 1.23 (4), 45.91 ± 2.09 (5), and 90.72 ± 1.91 (6). The relationship between the structures and urease inhibitory activities indicates that the chloro-substituted complexes have stronger activity than the alkoxy-substituted complexes. It is notable that one of the chloro-substituted complexes has very strong urease inhibitory activity, with IC 50 value of 17.35 ± 1.01 μM, which is much lower than that of the acetohydroxamic acid coassayed as a standard urease inhibitor. The kinetic studies reveal that the complex is a mixed-competitive inhibitor of urease. The molecular docking study of the complexes with the Helicobacter pylori urease was performed. © 2011 Elsevier B.V. All rights reserved.
The first vitamin BAnne Christine Chamayou | M. A. Neelakantan | S. Thalamuthu | Christoph Janiak
6 zinc complex, pyridoxinato-zinc acetate: A 1D coordination polymer with polar packing through strong inter-chain hydrogen bonding
Volume 365, Issue 1, January 2011, Pages 447-450
The biologically important pyridoxinato(1-) ligand (anionic vitamin B 6) shows the rare phenolate-hydroxymethyl chelation plus bridging mode through the pyridine-nitrogen atom towards zinc(II) to give the one-dimensional (1D) coordination polymer {(acetato-κO)-aqua-μ-[2- methyl-3-oxy-4,5-di(hydroxymethyl)pyridine-κN:O,O′]zinc(II)} ·monohydrate with polar packing of adjacent chains along the polar c axis (in space group Pc) through strong inter-chain hydrogen bonding. © 2010 Elsevier B.V. All rights reserved.
Rhodium(III) and iridium(III) complexes as anticancer agentsYvonne Geldmacher | Melanie Oleszak | William S. Sheldrick
Volume 393, Issue , December 2012, Pages 84-102
Until recently, Rh(III) and particularly Ir(III) complexes were generally considered as being unlikely candidates for anticancer agents owing to the typical kinetic inertness of their transition metal centres. Systematic studies on the cellular impact of a range of octahedral Rh(III) complexes containing polypyridyl and other aromatic chelates have now, however, demonstrated that high cytotoxicity in cancer cells and in certain cases promising relative tolerance by healthy cells can be achieved by judicious selection of the remaining ligands. Current knowledge on the biological properties of Rh(III) and Ir(III) compounds is reviewed in this article, with particular emphasis being placed on design strategies and on their solution behaviour, DNA binding preferences, structure-activity relationships and apoptosis induction in both adhesive and non-adhesive cells. © 2012 Elsevier B.V. All rights reserved.
Effect of flexibility of organic dicarboxylates anions on the four 3D metal-organic frameworks constructed from flexible benzimidazolyl-based ligandXiu Li Wang | Jin Xia Zhang | Guo Cheng Liu | Hong Yan Lin | Yong Qiang Chen | Zhen Hui Kang
Volume 368, Issue 1, March 2011, Pages 207-215
Four new polymeric frameworks, [Co(bbbi)(L1)] (1), [Cu(bbbi)(L1)] (2), [Co(bbbi)(L2)] (3) and [Ni(bbbi)(L2)] (4), (bbbi = 1,1-(1,4-butanediyl)bis-1H- benzimidazole, H2L1 = 5-nitroisophthalic acid and H2L2 = itaconic acid) have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Complexes 1 and 2 are isomorphous, and they can be described as CsCl-type net utilizing bimetal cores as eight-connected nodes, the bridging bbbi ligands and L1 serve as spacers to yield a unique eight-connected net with 42464 topology. Complexes 3 and 4 are isomorphous. It is interesting that 3D frameworks containing meso-helical chains (left- and right helical chains) have been observed in 3 and 4, in which meso-helical chains are alternately linked by bbbi ligands coordinating to Co1(Ni1) cations with the zigzag shaped conformation to generate a 3D binodal (4,4)-connected net with {53·6· 82}{52·64} topology structure. The bbbi ligands adopt three conformations, namely, the completely "M" shaped conformation in 1 and 2, the zigzag shaped conformation and "Ω" shaped conformation in 3 and 4. The influence of carboxylate anions with different flexibility on the construction of different network topology in the self-assembly process has been discussed. Moreover, the thermal stabilities and the voltammetric behavior of complexes 1-4 have been reported. © 2011 Elsevier B.V. All rights reserved.
Recent developments in the design of bifunctional chelators for metal-based radiopharmaceuticals used in Positron Emission TomographyMark D. Bartholomä
Volume 389, Issue , July 2012, Pages 36-51
In recent years, Positron Emission Tomography (PET) has become a practical, high performance clinical imaging modality for visualization of biological process within the living system. For radiolabeling of targeting vectors, ideally determining the biological fate of the radiolabeled bioconjugate, non-traditional metal-based PET radioisotopes are of particular interest as they offer certain advantages over traditional PET radioisotopes such as longer half-lives that allow delayed imaging or availability by commercial generator systems apart from on-site cyclotron production. However, for the incorporation of the radiometal into the targeting vector, a bifunctional chelator is needed that tightly binds the radiometal at one terminus while the second terminus serves for the covalent conjugation to the biomolecule. Conjugation of a metal chelate functionality to a biovector, however, may impact the in vivo distribution of the biomolecule. This review summarizes the recent developments of bifunctional chelates for two important PET radiometals, copper-64 and gallium-68, and discusses their coordination chemistry in relation to in vivo stability and pharmacokinetics. © 2012 Elsevier B.V. All rights reserved.
Metal complexes of thiosemicarbazones for imaging and therapyJonathan R. Dilworth | Rebekka Hueting
Volume 389, Issue , July 2012, Pages 3-15
This review gives an account of the coordination chemistry of thiosemicarbazone ligands with three (tridentate) or four (tetradentate) potential donor atoms. The syntheses and structures of the ligands complexes are described according to the donor atom combinations and metals involved. The review also covers the biological activities of the ligands and complexes in the context of their applications as therapeutic or diagnostic PET or SPECT imaging agents. © 2012 Elsevier B.V. All rights reserved.
Novel Pd(II) and Pt(II) complexes of N,N-donor benzimidazole ligand: Synthesis, spectral, electrochemical, DFT studies and evaluation of biological activityNour T. Abdel Ghani | Ahmed M. Mansour
Volume 373, Issue 1, July 2011, Pages 249-258
(1H-benzimidazol-2-ylmethyl)-(4-nitro-phenyl)-amine (L) and its Pd(II) and Pt(II) complexes have been synthesized as potential anticancer compounds and their structures were elucidated using a variety of physico-chemical techniques. The activation thermodynamic parameters were calculated using non-isothermal methods. Theoretical calculations invoking geometry optimization, charge distribution and molecular orbital description HOMO and LUMO were done using density functional theory. Natural bond orbital analysis (NBO) was performed for the investigation of major stabilizing orbital interactions. The experimental results, and the calculated molecular parameters, bond distances and angles, revealed a square-planar geometry around the metallic center through the pyridine-type nitrogen of the benzimidazole ring (Npy) and secondary amino group (NHsec) and two chlorine atoms. Electrochemical investigation of the complexes showed some irreversible, reversible, and quasi-reversible redox reactions. The synthesized ligand, in comparison to its metal complexes was screened for its antibacterial activity. The cytotoxicity assay of the complexes against three-cell lines breast cancer (MCF7), colon Carcinoma (HCT) and human heptacellular Carcinoma (Hep-G2) was studied. © 2011 Elsevier B.V. All rights reserved.
Host-guest chemistry of pyrene-based molecular receptorsErendra Manandhar | Karl J. Wallace
Volume 381, Issue 1, February 2012, Pages 15-43
The design and synthesis of molecular fluorescent sensors that are able to detect cations and anions via changes in fluorescence intensity either by a fluorescence "turn on", e.g., excimer formation or by a "turn off", i.e., excimer quenching, is an area of current interest. There has been a plethora of work dedicated to the development of fluorescent chemosensors in the field of supramolecular chemistry. This article will focus on a particular type of molecular receptors, those that contain a pyrene functional group that has been incorporated into the design of the molecular framework. This article will focus on three broad types of pyrene-based molecular receptors: (i) dipodal molecular receptors, (ii) "bowl" shaped receptors in the form of calixarenes and their derivatives, and (iii) metal-induced self-assembled systems. © 2011 Elsevier B.V. All rights reserved.
Synthesis, structural and corrosion inhibition studies on cobalt(II), nickel(II), copper(II) and zinc(II) complexes with 2-acetylthiophene benzoylhydrazoneVinod P. Singh | Pooja Singh | Ashish K. Singh
Volume 379, Issue 1, December 2011, Pages 56-63
Cobalt(II), nickel(II), copper(II) and zinc(II) complexes with 2-acetylthiophene benzoylhydrazone have been synthesized and characterized by elemental analyses, magnetic susceptibility measurements, electronic, IR, NMR and ESR spectral techniques. The molecular structures of ligand and its copper(II) complex have been determined by single crystal X-ray diffraction technique. The Cu(II) complex possesses a CuN2O2 chromophore with a considerable delocalization of charge. The structure of the complex is stabilized by intermolecular π-π stacking and C-H⋯π interactions. Hatbh acts as a monobasic bidentate ligand in all the complexes bonding through a deprotonated C-O- and >CN groups. Electronic spectral studies indicate an octahedral geometry for the Ni(II) complex while square planar geometry for the Co(II) and Cu(II) complexes. ESR spectrum of the Cu(II) complex exhibits a square planar geometry in solid and in DMSO solution. The trend g|| > g⊥ > 2.0023 indicates the presence of an unpaired electron in the dx2-y2 orbital of Cu(II). The electro-chemical study of Cu(II) complex reveals a metal based reversible redox behavior. The Ni(II) complex shows exothermic multi-step decomposition pattern of the bonded ligand. The ligand and its most of the metal complexes show appreciable corrosion inhibition properties for mild steel in 1 M HCl medium. [Co(atbh)2] complex exhibited the greatest impact on corrosion inhibition among the other compounds. © 2011 Elsevier B.V. All rights reserved.
Trinuclear and tetranuclear adduct formation between sodium perchlorate and copper(II) complexes of salicylaldimine type ligands: Structural characterization and theoretical investigationSaptarshi Biswas | Subrata Naiya | Michael G B Drew | Carolina Estarellas | Antonio Frontera | Ashutosh Ghosh
Volume 366, Issue 1, January 2011, Pages 219-226
The synthesis of two new sodium perchlorate adducts (1:2 and 1:3) with copper(II) "ligand-complexes" is reported. One adduct is trinuclear [(CuL1)2NaClO4] (1) and the other is tetranuclear [(CuL2)3Na]ClO4·EtOH (2). The ligands are the tetradentate di-Schiff base of 1,3-propanediamines and salicylaldehyde (H2L1) or 2-hydroxyacetophenone (H 2L2). Both complexes have been characterized by X-ray single crystal structure analyses. In both structures, the sodium cation has a six-coordinate distorted octahedral environment being bonded to four oxygen atoms from two Schiff-base complexes in addition to a chelated perchlorate anion in 1 and to six oxygen atoms from three Schiff-base complexes in 2. We have carried out a DFT theoretical study (RI-B97-D/def2-SVP level of theory) to compute and compare the formation energies of 1:2 and 1:3 adducts. The DFT study reveals that the latter is more stabilized than the former. The X-ray crystal structure of 1 shows that the packing of the trinuclear unit is controlled by unconventional C-H···O H-bonds and Cu2+-π non-covalent interactions. These interactions explain the formation of 1 which is a priori disfavored with respect to 2. © 2010 Elsevier B.V. All rights reserved.
Origin of electronic absorption spectra of MLCT-excited and one-electron reduced 2,2′-bipyridine and 1,10-phenanthroline complexesStanislav Záliš | Cristina Consani | Amal El Nahhas | Andrea Cannizzo | Majed Chergui | František Hartl | Antonín Vlček
Volume 374, Issue 1, August 2011, Pages 578-585
UV-Vis absorption spectra of one-electron reduction products and 3MLCT excited states of [ReICl(CO)3(N,N)] (N,N = 2,2′-bipyridine, bpy; 1,10-phenanthroline, phen) have been measured by low-temperature spectroelectrochemistry and UV-Vis transient absorption spectroscopy, respectively, and assigned by open-shell TD-DFT calculations. The characters of the electronic transitions are visualized and analyzed using electron density redistribution maps. It follows that reduced and excited states can be approximately formulated as [ReICl(CO)3(N,N ̇-)]- and ̇[Re IICl(CO)3(N,Ṅ-)], respectively. UV-Vis spectra of the reduced complexes are dominated by IL transitions, plus weaker MLCT contributions. Excited-state spectra show an intense band in the UV region of ∼50% IL origin mixed with LMCT (bpy, 373 nm) or MLCT (phen, 307 nm) excitations. Because of the significant IL contribution, this spectral feature is akin to the principal IL band of the anions. In contrast, the excited-state visible spectral pattern arises from predominantly LMCT transitions, any resemblance with the reduced-state visible spectra being coincidental. The Re complexes studied herein are representatives of a broad class of metal α-diimines, for which similar spectroscopic behavior can be expected. © 2011 Elsevier B.V. All rights reserved.
Zinc selective chemosensors based on the flexible dipicolylamine and quinolineHong Gyu Lee | Ju Hoon Lee | Seung Pyo Jang | In Hong Hwang | Sung Jin Kim | Youngmee Kim | Cheal Kim | Roger G. Harrison
Volume 394, Issue , January 2013, Pages 542-551
Zinc sensor molecules containing quinoline have been synthesized, which show fluorescence in the presence of Zn 2+. The nitrogen in quinoline is critical to fluorescence and fluorescence enhancement is promoted by deprotonating the sensor's amide. One of the sensors is highly selective for Zn 2+ over Cd 2+ and other cations such as Hg 2+, Fe 2+, Mn 2+ and Ca 2+. This selectivity can be attributed to the increased absorption of the sensor in the presence of Zn 2+ and the strong binding of Zn 2+. Structural studies, including X-ray and NMR, show the ability of dipicolylamine (DPA) to bind in facial and meridional manners to Zn 2+. Crystal structures of different compounds show Zn 2+ coordinating to three, four, and five nitrogens from the compounds. They also indicate that the selectivity of DPA containing compounds towards Zn 2+ may originate from Zn 2+ being stable in different coordination environments. © 2012 Elsevier B.V. All rights reserved.
Studies on the effect of metal ions of hydrazone complexes on interaction with nucleic acids, bovine serum albumin and antioxidant propertiesPalanisamy Sathyadevi | Paramasivam Krishnamoorthy | Eswaran Jayanthi | Rachel R. Butorac | Alan H. Cowley | Nallasamy Dharmaraj
Volume 384, Issue , April 2012, Pages 83-96
Three new transition metal complexes of the type ML 2 (where M = Ni(II), Co(II) or Cu(II); HL = N′-[phenyl(pyridin-2-yl)methylidene]furan- 2-carbohydrazide]) have been prepared by treating [NiCl 2(PPh 3) 2], [CoCl 2(PPh 3) 2] or [CuCl 2(PPh 3) 2] with N′-[phenyl(pyridin-2- yl)methylidene]furan-2-carbohydrazide derived from furoic acid hydrazide and 2-benzoyl pyridine wherein the hydrazone ligand (L) coordinated to the respective metal ions in 1:2 stoichiometry to mononuclear octahedral complex. The crystal structure of the complexes [NiL 2] (1), [CoL 2] (2) and [CuL 2] (3) solved using single crystals revealed a distorted octahedral geometry around the metal ion involving the coordination of an azomethine nitrogen, a pyridine nitrogen and an enolic oxygen derived from deprotonation of the ligand. From the bioinorganic application point of view, a detailed work on the binding of the complexes 1, 2 and 3 with CT DNA as well as BSA was undertaken along with DNA cleavage. In vitro assay on the antioxidant activity of the above complexes and hydrazone ligand revealed that they possess significant antioxidant activity. However, among the newly synthesized hydrazone complexes, complex 3 having coordinated Cu 2+ ion in its molecular structure exhibited superior activity in all the biological studies in comparison with the other two complexes possessing nickel and cobalt ions with same ligand (L). © 2011 Elsevier B.V. All rights reserved.
Cis-Dioxo-molybdenum(VI) Schiff base complexes: Synthesis, crystal structure and catalytic performance for homogeneous oxidation of olefinsSaeed Rayati | Nasim Rafiee | Andrzej Wojtczak
Volume 386, Issue , May 2012, Pages 27-35
The synthesis of two Mo(VI) tetradentate Schiff base complexes derived from 2,2′-dimethylpropylenediamine and aromatic aldehydes, (MoO 2{hnaphnptn} (1) and MoO 2{salnptn(3-OMe) 2} (2)) is reported. Full characterization of these complexes was accomplished with elemental analyses, spectroscopic studies ( 1H NMR, IR, and UV-Vis) and X-ray structure analysis. X-ray crystallography studies reveal that these complexes adopt a distorted octahedral six-coordinate configuration formed by tetradentate Schiff base ligand and two binding oxygen atoms. Catalytic performance of the prepared molybdenum complexes for oxidation of different olefins with tert-butyl hydroperoxide was evaluated. These complexes were found to be an efficient and selective catalyst for the homogeneous oxidation of various olefins. MoO 2{salnptn(3-OMe) 2} with a methoxy groups on the salicylidene ring of the ligand promote the effectiveness of the catalyst. © 2012 Elsevier Inc. All rights reserved.
An integrated system of pyrene and rhodamine-6G for selective colorimetric and fluorometric sensing of mercury(II)B. Nisar Ahamed | Pradyut Ghosh
Volume 372, Issue 1, June 2011, Pages 100-107
A pyrene and rhodamine-6G functionalized simple chemosensor L is studied toward sensing of metal ions in solution extensively. L shows selective color change from colorless to pink in the presence of Hg2+ in acetonitrile and the UV-Vis study shows peak at 525 nm with a value of 5.2 × 10 4 M-1 cm-1 due to selective ring opening of rhodamine spirolactam moiety. The selective sensing of Hg2+ by L in the presence of other metal ions and reversible nature of "OFF-ON-OFF" functionality of L by Hg2+ and EDTA, respectively, are also established. The fluorescence study of L in the presence of Hg2+ shows emission at 550 nm when excited at 525 nm (ring opened rhodamine wavelength) or 340 nm (pyrene wavelength) in dry CH3CN. Thus L acts as a selective colorimetric and fluorometric probe (dual probe) for the Hg 2+ in solution. Metal ion sensing ability of L is also carried out in water as well as in aqueous Hepes buffer. These studies suggest that the fluorescence output of L in presence of Hg2+ in aqueous environment is apparently due to the generation of acid upon addition of Hg2+ salt in water. © 2011 Elsevier B.V. All rights reserved.
Gold nanoparticles for diagnostic sensing and therapyFeng Lu | Tennyson L. Doane | Jun Jie Zhu | Clemens Burda
Volume 393, Issue , December 2012, Pages 142-153
Gold nanoparticles (Au NPs) provide a unique platform for biomedical applications. Au NP-based sensors have been widely employed to detect many different chemicals and disease-related biomolecules. Recent research on drug delivery and therapy with Au NPs has also indicated attractive and promising prospects for future applications. In this invited review we will provide an overview of the use of Au NPs for diagnostic sensing and therapy applications. © 2012 Elsevier B.V. All rights reserved.
A highly selective fluorescence-enhanced chemosensor for Al 3+ in aqueous solution based on a hybrid ligand from BINOL scaffold and β-amino alcoholMing Dong | Yu Man Dong | Tian Hua Ma | Ya Wen Wang | Yu Peng
Volume 381, Issue 1, February 2012, Pages 137-142
A chemosensor (R)-OH bearing an amino alcohol group was synthesized for the highly selective fluorescent recognition of Al 3+ with low limit of detection (16 ppb). "Turn-on" type fluorescence changes were observed upon the addition of Al 3+ in aqueous solution. The significant enhancement (35.4-fold) of fluorescence intensity was ascribed to the complex formation between (R)-OH and Al 3+ which denoted as the chelation-enhanced fluorescence (CHEF) process. © 2011 Elsevier B.V. All rights reserved.
A family of cubane cobalt and nickel clusters: Syntheses, structures and magnetic propertiesShu Hua Zhang | Yi Dong Zhang | Hua Hong Zou | Jing Jing Guo | He Ping Li | You Song | Hong Liang
Volume 396, Issue , February 2013, Pages 119-125
Five tetranuclear complexes with the composition of [M4(L) 4(μ3-OMe)4(MeOH)4], (M = Ni (1) or Co (2), HL is 3,5-dichloro-2-hydroxy-benzaldehyde (Hdchb); M = Ni (3) or Co (4), HL is 2-hydroxy-3-methoxy-benzaldehyde (Hhmb); M = Ni (5), HL is 5-bromo-2-hydroxy-benzaldehyde (Hbhb)), were prepared by reaction of salt perchloride hexahydrate with 2-hydroxy-benzaldehyde ramification under solvothermal conditions. All compounds were characterized by elemental analysis, IR spectroscopy and X-ray single-crystal diffraction. Compounds 1-5 have tetranuclear clusters with a cubane topology in which the metal ions and the oxygen atoms from the methanol ligands occupying the alternate vertices of the cubane. The {M4O4} cores display dominant ferromagnetic interactions from the nature of the binding modes through μ3- OCH3-. No single-molecule magnets (SMMs) behaviors have been observed in complexes 1-3 and 5. In contrast, compound 4 has been observed obviously slow relaxation for the S4 site symmetry and exhibits the behavior of SMMs. The results further support that judicious choice of harmonious mixed ligands provides the means to create a rich variety of new isolated individual {M4O4} cubic system and allows a systematic magnetic study of the effect of intermolecular interactions and correlation.
Synthesis, characterization and in vitro antitumor activity of three organotin(IV) complexes with carbazole ligandBanfeng Ruan | Yupeng Tian | Hongping Zhou | Jieying Wu | Rentao Hu | Chenhao Zhu | Jiaxiang Yang | Hailiang Zhu
Volume 365, Issue 1, January 2011, Pages 302-308
Three novel organotin(IV) complexes with 2-(9H-carbazol-9-yl) acetic acid (HL), of the formulae {[nBu2SnOL]2O}2 (1), [nBuSn(O)OL]6 (2) and [nBu3SnOL]6 (3) were prepared. All compounds were characterized by X-ray crystallography, confirming that complex (1) is tetranuclear one with ladder framework, complex (2) is a hexanuclear organotin(IV) complex with drum structure and complex (3) is a macrocycle with 24-membered stannoxane ring. Furthermore, all complexes were tested in vitro for their cytotoxic activity, using human hepatocellular carcinoma cell line (BEL-7402) and human hepatocellular liver carcinoma cell line (HepG2). Complex (1) displayed the best cytotoxicity and can be pointed out as a promising substrate to be subject of further investigations. © 2010 Elsevier B.V. All rights reserved.
Non-symmetrically substituted N-heterocyclic carbene-Ag(I) complexes of benzimidazol-2-ylidenes: Synthesis, crystal structures, anticancer activity and transmetallation studiesRosenani A. Haque | Mohammed Z. Ghdhayeb | Srinivasa Budagumpi | Abbas Washeel Salman | Mohamed B Khadeer Ahamed | Amin Malik Shah Abdul Majid
Volume 394, Issue , January 2013, Pages 519-525
Non-symmetrically substituted benzimidazolium salts (1 and 2) having bromide counterion undergo metallation with Ag 2O at stiochiometric ratio, giving mononuclear bis-carbene Ag(I) complexes (3 and 4), active as anticancer agents against Human Colorectal (HCT 116) cell lines. Both the complexes provide good activity (IC 50 = 13.9 μM for 3 and 14.6 μM for 4) in the anticancer studies and so distinctly better than the ligand precursors (IC 50 = 119.3 μM for 1, and 70.0 μM for 2). The molecular structure of Ag complexes 3 and 4 is elucidated by X-ray diffraction studies. The Pd(II)- and Au(I)-NHC complexes (5 and 6) were synthesized from 4 via the technique of transmetallation. However, attempts to produce transmetallated complexes using 3 were unsuccessful. © 2012 Elsevier B.V. All rights reserved.
Expanding the scope of "Click" derived 1,2,3-triazole ligands: New palladium and platinum complexesDavid Schweinfurth | Sabine Strobel | Biprajit Sarkar
Volume 374, Issue 1, August 2011, Pages 253-260
Using the 'Click Protocol' the new ligands 1-(cyclohexyl)-4-(2-pyridyl)-1, 2,3-triazole (1), 1-(2-trifluoromethyl phenyl)-4-(2-pyridyl)-1,2,3-triazole (2), 1-(4-hexyl phenyl)-4-(2-pyridyl)-1,2,3-triazole (3), 1-(2-mercaptomethyl phenyl)-4-(2-pyridyl)-1,2,3-triazole (4) and 1-(4-N,N-dimethylamino phenyl)-4-(2-pyridyl)-1,2,3-triazole (5) were prepared by reacting 2-ethynylpyridine with the corresponding azides. In the next step the ligands were reacted with suitable palladium and platinum precursors to yield the cis-dichloro-palladium complexes 1a-4a and platinum complexes 1b-4b. Investigation of the molecular structure of the free ligands 1 and 5 reveals the formation of infinite chains in the 3D structure which are governed by hydrogen bonds between the triazole units. Likewise the 3D structure of 1a shows infinite chains which are held together by multiple remarkably short C-H⋯Cl-Pd contacts. Electrochemical investigation of the free ligands by cyclic voltammetry showed irreversible reduction processes at highly negative potential. Upon metal complexation huge anodic shifts of the reduction potential were observed. To further characterize the electronic properties of all the compounds UV-Vis spectra were also analyzed. © 2011 Elsevier B.V. All rights reserved.
Assembly of anion-controlled cadmium(II) coordination polymers based on flexible bis(imidazole) derivativeXiu Li Wang | Song Yang | Guo Cheng Liu | Jin Xia Zhang | Hong Yan Lin | Ai Xiang Tian
Volume 375, Issue 1, September 2011, Pages 70-76
Four Cd(II) metal-organic complexes, namely, [Cd(Cl)2(bbdmbm)] (1), [Cd(NO3)(N3)(bbdmbm)1.5] (2), [Cd(BBA)2(bbdmbm)(H2O)] (3), [Cd(DNBA)2(bbdmbm) ] (4), (bbdmbm = 1,1-(1,4-butanediyl)bis(5,6-dimethylbenzimidazole), HBBA = 4-bromobenzoic acid, and HDNBA = 3,5-dinitrobenzoic acid) have been obtained from hydrothermal reactions of different Cd(II) salts with the mixed ligands of bbdmbm and five anions (Cl-, NO3-, N 3-, BBA and DNBA). Single crystal X-ray diffraction analyses reveal that the four complexes exhibit different structures. Complex 1 possesses a one-dimensional (1D) helical chain, which is finally extended into a two-dimensional (2D) supramolecular structure through π-π stacking interactions. Complex 2 shows a 1D ladderlike chain bridged by bbdmbm ligands with two kinds of coordination conformations. Complex 3 is a 1D coordination polymer and is ultimately extended into a 2D supramolecular network through H-bonding interactions. Complex 4 displays a dinuclear cluster, which is finally packed into a three-dimensional (3D) supramolecular framework through three kinds of π-π stacking interactions. The Cd(II) exhibits four different coordination modes in complexes 1-4, respectively. The results indicate that the anion ligands with different steric hindrance and size play important roles in the coordination modes of Cd(II) and construction of the title complexes, leading to the structural diversity. In addition, the conformations of bbdmbm ligand also show some effect on the final structures. Fluorescence properties of complexes 1-4 are reported in this paper. © 2011 Elsevier B.V.


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- An Overview of Different Types of Scrying
- Scrying is a method of divination. It consists of gazing into a crystal, a mirror or some water for example, anything shiny really, in order to enter altered mind states...A good cliché that best describes scrying is the gypsy fortune-teller and her large...
Divination >> Scrying
- Psychic Protection - Barriers
- Introduction: The countermeasures given in these short articles are extremely basic. They only contain the bare bones of what is necessary to use them. To understand the principles behind these countermeasures, please get a copy of 'Practical Psychic Self-Defe...
Psychic Abilities >> Psychic Protection
- Reinforcement Effect and Displacement Trend: No Wine in Old Bottles?
- Two phenomena concerning displacement--the reinforcement effect and the displacement trend--have been only meagerly investigated with virtually no further published studies of them since they were first reported decades ago. Because there appears to be...
Journal of Parapsychology >> vol 53, 1989
- Survivalists' Guide for the New Millennium: Chapter 6
- AS THE WORM TURNS Health and well being are part of the natural birthright of the human being. With all of its organs intact, the right diet, exercise and mental focus, a human body can overcome any disease. Even so, the effects of living in this...
Philosophy >> Survivalists Guide for the New Millennium
- Discovery and Development of Reiki
- "The more we care for the happiness of others, the greater our own sense of wellbeing becomes." The Dalai Lama The traditional story of the discovery of Reiki is as historically correct as the biblical report of the life of Jesus - it is molded and...
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- Question the Premises of Society and Science
- Question the ultimate validity of the basic premises of society, in particular, scientific theory. Do not accept concepts or statements as truthful simply due to weight of tradition or learned opinion. The synthesis of these statements is a healthy skepticism...
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Mulesing Method is described in multiple online sources, as addition to our editors' articles, see section below for printable documents, Mulesing Method books and related discussion.
Suggested News Resources
- We Tested Yak Wool, And It's Awesome (but pricey)
- The process of yak wool production includes working around the molting season each spring when the animals shed their soft underlayer so that herders can avoid shearing (a process that in sheep is often linked to mulesing and cruelty).
- Pair tranform barren rice paddies into organic farm
- The low-maintenance breed is fly and lice resistant with no need for shearing, crutching, mulesing or dipping.
- Proposed sheep welfare standards "unachievable"
- It states that tail-docking shall be done only if a failure to do so would lead to a welfare problem and prescribes specific acceptable methods for docking and castration. The draft RWS has been released for public consultation until April 15 this year.
- Draft wool standard might discount mulesed wool
- A PROPOSED sheep and wool welfare standard that prohibits mulesing could wreak havoc on the international wool industry and heavily discount wool from mulesed sheep, according to Italian processor Laurence Modiano. The draft Responsible Wool ...
- Wool processors seek support for sheep pain relief law
- Associated guidelines only state that mulesing should be accompanied by pain relief where practical and cost-effective methods are available, and that operators should seek advice on current pain minimisation strategies.
Great care has been taken to prepare the information on this page. Elements of the content come from factual and lexical knowledge databases, realmagick.com library and third-party sources. We appreciate your suggestions and comments on further improvements of the site.
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- Nakheel takes real estate expertise to Saudi Arabia
- Dubai's master developer Nakheel is taking its real estate development expertise to the Kingdom of Saudi Arabia (KSA), where it will provide technical support to leading developer Al Akaria for a range of new, mixed-use projects in and around Riyadh.
- Nakheel to offer technical support to developer Al Akaria
- Dubai: Nakheel will provide technical support to Saudi Arabia-based developer Al Akaria for a range of new, mixed-use projects in and around the capital Riyadh, the Dubai developer said in a statement on Thursday. The two companies have signed a ...
- Dubai's Nakheel signs agreement with Saudi firm for new Riyadh projects.
- Dubai developer Nakheel has signed an agreement with Saudi Arabian developer Al Akaria to develop new, mixed-use projects in and around Riyadh. The two companies have signed a memorandum of understanding under which Nakheel will support with ...
- New Dubai park, Nakheel, opens (video)
- Dubai Municipality announced the unveiling of the Nakheel park in Al Aweer through its social media networks.
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Y-Not festival, held from 5-7 August in Matlock, has added ten new acts to the line-up.
Up-and-coming grit-poppers Brother, Pete and the Pirates and Yaaks join beatboxer Beardyman and Dananananaykroyd on the billing, which already includes Maximo Park and The Milk.
Indie five-piece The Rifles have also been confirmed, with Futures, Miles Kane, soul-inspired songwriter Jamie Woon and Egyptian Hip Hop completing the new additions.
Tickets are available now at £65 for an adult weekend pass, with under 12s admitted for free.


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Hi All ,
Can any one clarify my doubts regarding LibGen which will generate the cell libraries which are required for the power grid analysis.
1.I have seen five steps in LibGen , XTC , QX , Model Tables , Thunder and Power Grid Views Generation , what happens in each of these steps and what are the required input files for these steps and what are the output reports of these steps?.
2.I read like LibGen is independent of Design but i have seen in the diagram of LibGen like one of the input for LibGen is GDS-II , why GDS-II is required for LibGen?
3. what is the Exact output of the LibGen step?
4.what is the difference between power grid views and power grid view library?
5.what does the main function of thunde?
6.what is the function of Power Meter?
7.how does vstorm calulates the voltage drop by taking the thunder and power meter outputs as inputs for vstorm.
8.what is the impact of electro migration on IR-Drop?
Can any one clarify my doubts.


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India is spoiling its deep-rooted trade and commercial relationship with Iran influenced by the pressure tactics of American imperialists, Communist Party of India (Marxist) General Secretary Prakash Karat has said. He was opening a seminar on 'War on terrorism: a U.S. agenda on the Arab world', organised by the Keluettan Study and Research Centre, here, on Saturday.
Mr. Karat criticised that the gas pipeline project for the cost-effective supply of gas from Iran to India was scuttled as India succumbed to the U.S. pressure. Though the country had earlier depended on Iran to meet around 12 per cent of its total oil resources requirement, things witnessed a change recently following the mounting pressure of the US, he blamed.
"For the past six months, the bank transactions between India and Iran too have been remaining blocked under the strategy of the American imperialists," he said, adding that "Our country was yet to make any payment for the oil resources it purchased from Iran for the last six months."
The CPI (M) leader also accused that India was sacrificing its own interest for endorsing the strategic movement of imperialists to invade into the Arab world for plundering oil resources. "All the Arabian countries are now facing threats against their nationalism as fundamentalists — sponsored by the imperialist forces — make inroads into their regime to hijack Arab democratic aspirations," he said.
Referring to the call of U.S. Secretary of State Hillary Clinton to support the U.S. for their "humanitarian interventions" in Syria, Mr. Karat said "India, as per the U.S. ploy, would never be able to challenge the dictate sacrificing its long-pending aspiration to be a permanent member in the United Nations Security Council." According to Mr. Karat, the term 'humanitarian intervention' was the latest ploy of the United States after its anti-terror campaigns for imperial agendas.
The CPI (M) leader also said the anti-terror movements of the U.S. in Arabian countries largely resulted in demonizing the Islam community and creating sectarian warfare. He called upon the civic community of India to extend moral support to the Arab citizens in their fight to thwart western attempts of hijacking national awakening.
CPI (M) district secretary T.P. Ramakrishnan presided over the inaugural function. Hindu


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Monthly Archives: October 2008
Malawi Here are two additional sectionettes from my "Notices of the AMS" book review entitled "Economic and Common Sense" on Steven Landsburg's book "More Sex is Safe Sex – the unconventional wisdom of economics". Both sectionettes deal with Government intervention in economics. The first is about fertilizer … Continue reading
Posted in Economics Tagged Bailout, Crisis, Fertilizers, Inflation, Malawi, Subsedies Leave a comment
Two Math Riddles
Usually I am not particularly good at telling math riddles or solving them, and I was not planning on presenting math riddles here. But these days, when mathematical blogs break new ground and enter uncharted territories, let me make an exception and tell you … Continue reading
Posted in Riddles Tagged Car talk, Mathematical riddles 17 Comments
About Mathematics
This post collects some brief philosophical thoughts about mathematics that appeared as part of my paper "Combinatorics with a geometric flavor: some examples," from the proceedings of the conference "Vision in Mathematics, towards 2000." I added two small items (the first and … Continue reading
Posted in Philosophy, What is Mathematics Tagged Mathematics 6 Comments
Extremal Combinatorics IV: Shifting
Compression We describe now a nice proof technique called "shifting" or "compression" and mention a few more problems. The Sauer-Shelah Lemma: Let . Recall that a family shatters a set if for every there is such that … Continue reading
Posted in Combinatorics, Open problems Tagged Extremal combinatorics, Shifting 6 Comments
Stand Clear of The Closing Doors, Please
Do you miss New York City? Here is something to remind you click here click also here (video) One more time? Click here. London lovers, however, say that this is nothing compared to
Posted in Uncategorized Tagged Mind the gap, Missing NYC, New York City, Stay clear of the closing doors 2 Comments


text: Communication Intelligence solutions Watch the video Law Enforcement Agencies monitor the data from different types of networks to solve the investigations Read More Intelligence Agencies analyse huge amount of data to identify, prevent and neutralise potential threats Read More Telco Operators need advanced interception capabilities to be compliant with national law Read more Solutions Collect, monitor and analyze every kind of information source. The best way to interpret what happen, prevent the crime and support the communities protection. Unconventional Ip Intelligence Unconventional Ip Intelligence Lawful Interception Lawful Interception Electronic Surveillance... Electronic Surveillance Latest news IPS Lawful Interception solutions compliant to the new VoLTE standard IPS at ISS Latin America 2016 Mexico City IPS at ISS World Asia 2016 - Kuala Lumpur Kuala Lumpur More News


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Turbine 1/2 FNPT Flowmeter, Stainless Steel, 1 to 10 gpm
- Item# 1XPR3
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Using 360° Viewing:
- Rotate: Use top-to-bottom, side-to-side by use of mouse arrow.
- Zoom In: Double click on image.
- Zoom Out/Reset: Put photo at full zoom & then double click.
- Shipping Weight 2.39 lbs.
Product Details
Technical Specs
- Item Flowmeter
- Type Turbine
- Housing Material Stainless Steel
- Fitting Size (In.) 1/2
- Flow Material Water, Oil, Chemicals, Petroleum Products, Fuels, Lubricants
- Fitting Type FNPT
- Accuracy (%) +/-1.5
- Wetted Materials 316 SS, PVDF, Ceramic, Tungsten Carbide
- Pressure Rating (PSI) 1500
- Fluid Temp. Range (Deg. F) 14 to 140
- Max. Viscosity 100cP
- Frequency Range (Hz) 42 to 420
- Sensor Type Magnetic
- Rotor Type PVDF
- Display Type Standard LC Display
- Flow Range 1 to 10 gpm
- Repeatability 0.10%
- Fluid Temp. Range (Deg. C) -10 to 160
- Ambient Temperature 14 to 140 Degrees F
- Typical K Factor 2500 Pulses Per Gallon
- Strainer 55 Mesh
- Agency Compliance FM, CUL, CE, EX, ATEX
- Includes 2 Lithium Batteries
- Power Requirement 2 Lithium Batteries
Compliance and Restrictions
This product contains a chemical that is regulated under California Proposition 65.
Warning: This product contains a chemical known to the State of California to cause cancer.
Warning: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.
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Item # 1YEB3GPI
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The 58 Most Incredible MMA Photos We Posted on Facebook in 2014
Busted faces, dick-cakes, odd couples, Don Frye without a moustache, and Bruce Buffer's terrifying abs of steel. What a year it was.Read More
Busted faces, dick-cakes, odd couples, Don Frye without a moustache, and Bruce Buffer's terrifying abs of steel. What a year it was.Read More
"To be the greatest, you must take chances. To be remembered, you have to risk it all. But this does not always go as planned."Read More
The greatest photos, videos, GIFs, and everything else from our #1 favorite professional hot chick.Read More
What a shame, "Stank Bref Rescue" is a reality show that we really could have gotten behind.Read More
Highly regarded lightweight contenders Edson Barboza and Michael Johnson will face off in the co-main event of UFC Fight Night 61, which goes down February 22nd at Gigantinho Gymnasium in Porto Alegre, Rio Grande do Sul, Brazil.Read More
It's worth a look if you have any patience left for Jones/Cormier pre-fight hype.Read More
Lesnar's return isn't the restoration of MMA's golden age. It's Zuffa throwing two or three fight's worth of kindling onto a dying fire.Read More
Fight Pass has been hacked, with passwords and credit card numbers being released. Change yours now.Read More
And now, Vera and Garza join the legal mass-attack against the UFC that will become a major storyline in 2015. There will surely be more ex-UFC fighters that file similar class-action suits (or join existing ones) in the near future, and we'll keep you posted as that happens.Read More
The MMA equivalent of the 1989 Billy Ripken Fleer card.Read More
Ugly t-shirts, worthless novelties, outdated fighter merchandise, and so much more. A depressing look at the worst UFC-branded items that money can buy.Read More
The World MMA Awards are the awards show that MMA deserves, but not the one it needs right now. Or ever.Read More
So this is basically the legal equivalent of having your wife stand in one grocery store checkout line while you stand in another, and if she gets to her cashier first, you rush over with your stuff or something? I don't know, man. I'm no grocery store expert.Read More
In this final installment of our series on MMA media criticism, Brian J. D'Souza explores the ways in which money generates silence.Read More
And just like that, the last fuck given about the bantamweight division floated away with the passing breeze.Read More
It's official: Dominick Cruz is the most cursed fighter in MMA history.Read More
Aldo has simply run out of fucks to give when it comes to airing his grievances about his longtime promotion.Read More
Scandals, surprise signings, and Brandon Vera holding two title belts (not in the UFC, obviously). Let's grab some eggnog and see what 2015 has in store for us.Read More
Rampage Jackson claims a clause in his contract allowed him to leave Bellator.Read More
Sick of watching the same NOS and Metro PCS commercials 4,000 times just to see Lyoto Machida destroy C.B. Dollaway? Watch the commercial-less finish of the fight here!Read More
Quinton "Rampage" Jackson has reportedly signed with the UFC despite being under contract with Bellator.Read More
Last UFC event of the year, you guys. Let's just get through this.Read More
Some must-see highlights from our bros around the blogosphere.Read More
Come back to CagePotato.com tomorrow night for live results, unless you have better things to do, and if that's the case we totally understand.Read More
"They were using him for the publicity aspect, and he didn't want to lend his name to it."Read More
"I had a lot of good times, but I'm done chasing this f-----g dream. I'm to the point where it's not worth it to get knocked out for pennies."Read More
"Teixeira's manager, Jorge Guimaraes, has called the report premature. Guimaraes says that Teixeira, who was medically suspended after his UFC 179 loss to Phil Davis, has yet to be cleared to return to competition by Brazil's athletic commission."Read More
"I don't think it's really healthy for the world to see their champion -- for the world to see UFC's champion -- saying I would kill someone. That really took me off guard."Read More
More proof that the UFC's PPV business just ain't what it used to be.Read More
"Am I ready [to fight] today? I mean, probably not, but I'd fight anybody right now. Whether that's a smart decision or not remains to be seen."Read More


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Business consultants are the individuals or the team that assists the business to gain the competitive advantage. It enables the business to achieve great heights and profitability. It helps the businesses to grow considerably. There are many real life situations in which the business managers find themselves struck to and are hard to overcome. Thus, they hire the business consultants to get them out of the bad situations and assist in the growth of the businesses.
The consultants try to bring the lost revenues of the companies by improving the business processes. There are many functions that are performed by the small, medium or big business consultants.
What do business consultants do?
The business consultants tend to perform various tasks for the client company. They enable to give advice to the clients for improving the growth of their business. The business consultants are the experts in all the business processes. Many of the small business enterprises tend to hire the business consultants to perform many of its business functions such as procurement, outsourcing, facility management, cost benefit analysis, change management, business review and many more.
The business consultants also play the major role in the team development process in the organization. The consulting firm provides several ideas to engage the employees in various activities and thus boosts the productivity of the employees. The business consultants reduce the time of many processes which enable to provide profitability to the company. Therefore, the business hires the consulting firms who help them to act strategically in various situations.


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| Hotels & Resorts
Welcome to Dolphin Vacations
Dolphin Vacations was founded in 1995 by Marva Donovan. We have grown from a small office with a staff of 3 agents to one of the leading travel agencies in West Michigan. We are proud to have over 35 leisure and corporate travel agents providing outstanding services to our clients.
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Member Since: October 03, 2010
[10] August 18, 2016 at 8:16am
Hillary doesn't belong in jail; she belongs in hell along with her disgusting husband.
In reply to the story Green Party Candidate Jill Stein: Clinton Is 'Too Big To Jail'
[7] August 18, 2016 at 9:04am
Floc responded:
August 18, 2016 at 10:46am
iwontell responded:
[19] June 30, 2016 at 2:07pm
Too many to count.
[1] June 5, 2016 at 2:10pm
And Feb, March, April, May, June, July etc You get the picture.
[9] April 28, 2016 at 5:11am
If he endorsed Cruz I would not agree with him at all. He just happened to endorse Trump, the man who will be our absolute best choice for president. Trump has a big mess to clean up after Obama. America needs a successful businessman, not another money grubbing useless politician.
In reply to common cents's comment on the story Legendary Basketball Coach Bobby Knight: Trump Is the 'Most Prepared Man in History' to Be President
[-2] April 28, 2016 at 9:07am
DT2016 responded:
April 28, 2016 at 10:30pm
DT2016 responded:
[4] April 12, 2016 at 3:14pm
Truer words have never been written. Thanks.
[8] April 12, 2016 at 2:58pm
In reply to angeleyes63's comment on the story Blaze Poll: Who Should Replace Alexander Hamilton on the $10 Bill?
[2] April 12, 2016 at 2:53pm
This is just one more evil step to destroy American history and honor. Disgusting!
In reply to the story Blaze Poll: Who Should Replace Alexander Hamilton on the $10 Bill?
[17] April 12, 2016 at 2:45pm
They are highly qualified for prison. However, the USA is so screwed up that it is never going to
happen. It's a pity what the immoral, Anti-God folks in America have done to contribute to it's destruction. Really sad.
March 29, 2016 at 7:36am
You mean a classless act. I would call him the president from hell.
In reply to VagueSoul25's comment on the story Obama Lectures News Media on Campaign Coverage: Don't 'Dumb Down the News'
March 24, 2016 at 2:57pm
That's an easy question. It's definitely patriot and potus.
In reply to YesNdeedie's comment on the story Dancing With the Stars: Obama Does the Tango in Argentina
[2] March 24, 2016 at 10:01am
Yes, an evil fool as opposed to a harmless one.
In reply to theycallmeNero's comment on the story Obama: Economically Successful Israel Makes Middle East Peace More Difficult
[3] March 24, 2016 at 9:56am
Barry should be stoned.
In reply to AvengerK's comment on the story Obama: Economically Successful Israel Makes Middle East Peace More Difficult
January 29, 2016 at 3:39am
Obummer is full of s–t. Since when does this Moslem give a c–p about Jews?
In reply to ConChef's comment on the story A Team of Hamas 'Warriors' Was Killed This Week. The Reason Has Israelis Worried.
[-1] January 22, 2016 at 6:19am
Anyone who hasn't figured out by now that Biden is either senile or very stupid is not paying
attention to his dumb looking reactions and facial expressions, as well as the fact that
he has never said anything of meaning. Biden would never get Trump's voters. Trump's
voters are smart and they know that he is definitely the best choice of everyone else out
[14] January 21, 2016 at 2:24pm
America needs Trump and I'd like Palin as VP.
In reply to the contribution Get Ready for President Donald Trump
[4] January 22, 2016 at 2:19am
Verycobaltviolet responded:
[1] January 22, 2016 at 8:10am
podunk1 responded:
[1] December 15, 2015 at 8:09am
According to true Judaism- Orthodox Judaism it is a definite no no. Reform Judaism
was started in the late 1700′s and became strong by the mid 1800′s. Since Reform
Judaism dropped many of the Torah (Bible laws) Conservative Judaism came to be.
According to the Torah a female cannot be a Rabbi. The problem with people today is
they just do whatever they want. Those who wish to follow the Torah do so. Being gay, for example is against God's law (the Torah) as well. Climate Change is another ridiculous
belief. Man does not control the climate. God does. Believe what you want but time will tell.
[9] October 15, 2015 at 6:37am
I wonder what Obama and Kerry would do if a maniac Palastinian Arab Moslem came at them with a knife.
All I know is if someone attacked me I would give it back to them with all I can. Aggresion of this sort used to be called cold blooded murder. It still is. However, the Democrat libtards in the US government are so in love with
the enemy that they don't see straight.
[16] October 12, 2015 at 4:43am
I'm sure Jimmy Carter is thrilled that he no longer holds that title.
In reply to Warren Z's comment on the story Obama Doesn't Hesitate When Asked If He Could Win a Third Term — and Levels a Few Insults at Donald Trump to Boot
[3] October 12, 2015 at 12:03pm
VRW Conspirator responded:
[3] September 20, 2015 at 9:09am
Why is this show still being aired? Are there that many idiots around looking for something inane
to watch?
[3] September 20, 2015 at 8:42am
Obama is a Communist. If you are a Communist you don't believe in G-d. Of all the religions; Obama
was exposed to the Muslim religion during his time in Indonesia. So he is partial to Muslims. He hates all other religions. By now he probably thinks he is G-d. Since Obama is human the day will come when he is no more.
In reply to the story Ted Cruz Is Asked If He's 'One of Those' Who Doesn't Believe President Obama Is a Christian. Here's How He Responds.
[-1] September 20, 2015 at 2:50pm
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Not Without My Daughter
- Directed by Brian Gilbert
===Story=== The Arab anti-defamation leagues understandably had a field day with this one. Sally Field plays Betty Mahmoody, an American who marries an Iranian (Alfred Molina) and has a child. They go back to Iran for a visit and, to her horror, he tells her he's decided to stay there. If she wants to leave, she must leave her daughter behind. If she stays, Betty must live in a culture vastly different and, she believes, very dangerous. Part thriller, part culture clash, the film certainly takes advantage of Americans' perceptions of Iran after the unrest of the '70s and early '80s. Molina is truly despicable as the husband, while Field projects a lot of overheated anguish as Betty tries to figure out a way to escape the country with her daughter. Overheated, in fact, is the word for the whole melodrama. ''--Marshall Fine'' ===DVD Features=== *Color *Closed-captioned *Widescreen
|Sally Field
|Betty Mahmoody
|Alfred Molina
|Roshan Seth
|Georges Corraface
Recent threads
- Genre: Drama Movies
- Director: Brian Gilbert
- Producer: MGM/UA
- Length: 116 min
- Aspect ratio: 1.85:1
Theatrical Release North America Jan 11, 1991
Ratings North America PG-13 Europe 15
DVD Release North America Oct 2, 2001


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[Locals Only] A Kiss Could Be Deadly
Flowing in the vein of the Sounds, Shiny Toy Guns and the Lovemakers, Huntington Beach-based quintet A Kiss Could Be Deadly (AKCBD) target the dance-till-you-drop-and-look-damn-hot-doing-it crowd. Bathed in the light of retro new wave and hip electronic sparkle, AKCBD bounce and shimmy with polished, meticulously put-together energy.
On their new self-titled album, the band know what works for them, and they roll with it. They pair electronic glitter with fierce lyrics, crafting a collection of power-pop gems. Programmer/synth-master Chris Qualls is clearly the star, thanks to his talent for sculpting dynamic hooks and riffs. Front woman Lauren Baird brings the obvious sex appeal; her vocals don't have much of a range, but with AKCBD's embellished background noise holding her up, it keeps the sound from getting overly fussy and complex. Guitarist John Bennett, bassist Kelly Cairns (who co-wrote several of the album's songs alongside Qualls) and drummer Danny Deleon were added after AKCBD received positive feedback from the distribution of the band's demos. Good thing, as the addition of these three brings solidity to an otherwise velutinous sound.
"Poison IV" and "Midnight Romance" are the two most likely candidates for Breakthrough Dance Anthem, although any of the other tracks wouldn't be far behind. Closing the album, however, is the completely unexpected "Acoustic Romance," featuring a (surprise!) acoustic guitar flitting around Baird's suddenly soft, vulnerable vocals. It's absolutely gorgeous.
Let's hope that for their next album, A Kiss Could Be Deadly will expand their sound. They have the potential to be a multifaceted powerhouse.
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Caliente Thursday with DJ Kaboom and DJ Erickson
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Clarence 18 Oct 1884 - 16 Mar 1951
Martha 27 Dec 1892 - 05 Apr 1973
Contributed on 12/2/07 by tootied
Email This Contributor
On this site you can upload gravestone photos, locate ancestors and perform genealogy research. If you have a relative buried in Arkansas, we encourage you to upload a digital image using our Submit a Photo page. Contributing to this geneology archive helps family historians and genealogy researchers locate their relatives and complete their family tree.
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In this series, we are going to value the common equity shares of Altria (NYSE:MO), Lorillard (NYSE:LO), Reynolds American (NYSE:RAI), and Philip Morris (NYSE:PM). I have been bearish on these firms in previous articles, and all four issues are showing signs of weakness. In other words, the share prices are declining. That said, in this article, we are going to look at the performances and positions of these firms between 2007 and 2011.
Revenue grew at every firm except Reynolds American. Altria's revenue peaked in 2010. Reynolds American's revenue is well off of the 2008 level. Philip Morris increased revenue 11.3 percent in 2011 compared to 2010. Lorillard's revenue was the most risky and Reynolds American's the least risky.
Net income of every firm except Altria increased. Altria's 2011 net income declined 13.2 percent compared to 2010. Lorillard's 2011 net income increased 8.5 percent compared to 2010. Reynolds American's 2011 net income increased 25.4 percent compared to 2010. Philip Morris's 2011 net income increased 18.3 percent compared to 2010. Lorillard's net income was the least risky and Altria's the most risky.
Cash flow from operations growth was strong from all firms except Altria. Reynolds American's 2011 cash flow from operations was slightly below the 2009 peak. Altria's cash flow was the most risky and Lorillard's the least risky.
Click to enlargeAll of the firms except Reynolds America did a horrible job of increasing equity. Total equity declined substantially.
Altria's and Reynolds American's assets declined. Lorillard's assets were flat. Philip Morris's assets increased slightly.
Across the board the trend is towards increasing liabilities. That said, Reynolds American's liabilities declined slightly. Philip Morris's and Lorillard's liabilities increased substantially.
After declining, Philip Morris's cash balance increased between 2009 and 2011. Lorillard's cash balance peaked in 2010, but overall is trending higher. Reynolds American's cash balance is declining and Philip Morris's cash balance is increasing.
Philip Morris is the dominant player and increased its share of revenue. Reynolds American's share of revenue is declining. Lorillard and Altria's share of revenue has been pretty much flat.
In 2011, Lorillard was the most profitable firm followed by Reynolds American. Lorillard's profit margin is shrinking while Reynolds American's profit margin is expanding. Altria's profit margin is shrinking and Philip Morris's profit margin has been stable.
Because of shrinking total equity, return on equity is substantially higher than it should be for Philip Morris and Altria. Reynolds American's return on equity was 22 percent in 2011.
Lorillard and Philip Morris have done an excellent job of generating return on assets.
To be continued...
Disclosure: I have no positions in any stocks mentioned, and no plans to initiate any positions within the next 72 hours. I wrote this article myself, and it expresses my own opinions. I am not receiving compensation for it (other than from Seeking Alpha). I have no business relationship with any company whose stock is mentioned in this article.


text:
Monmouth 6, Wagner 3
Monmouth 10, Wagner 0
Lauren Sulick hurled the (18-12) Hawks to a pair of wins, stopping host Wagner's four-game winning streak.
In the opener, Emily DeLong tied Monmouth's career home run record of 35 with a two-run blast in the first inning.
The Hawks notched their third straight and fifth in the last seven with an eight-run fourth in the nightcap.
The (12-26, 7-11) Seahawks play Wednesday at St. Francis, Pa.
Wagner drops doubleheader softball games to Monmouth
Monmouth 6, Wagner 3


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|Villa Turquesa
Cabo San Lucas, Pedregal - Pacific
/ Sleeps 20 adults/singles + 8 children / Oceanfront
Location: Cabo San Lucas
Size: 15,000 square feet
Sleeps: 20 adults/singles + 8 children
Bedrooms: 9
Bathrooms: 11
Distance to Town: 1.5 miles
Distance to Beach: 0.8 miles
Nearest Marina: 1 miles
Distance to Airport: 28.9 miles
Click to Talk by Phone!
Feel the cool Saltillo tile underfoot as you stroll through this spacious estate. Enjoy an early outdoor breakfast and then a little private practice on your own putting green. Schedule a rousing shuffleboard competition after lunch. Hold a late-night movie marathon in the theater room. End your day with a steam bath in the master suite.
No matter where you are at Villa Turquesa, there is room for everyone. The main terrace area includes a large infinite-edge lap pool with swim-up bar, shade structure, lounge chairs, and outdoor dining space for up to 60 guests. Enjoy gorgeous blue-water views, fresh breezes and stunning skies from every vantage point.
A great deal of thought has been given to creating fun and relaxation for every guest at Villa Turquesa. This truly is the ultimate choice for a very private, luxury villa vacation in Cabo!
OPTION: This villa can be rented as a 4BR/5BA rental. (Lowest floor containing 5 bedrooms, large home theater, putting green, children�s play area and shuffleboard court will be locked off.) This option offers 10,000 sq feet of indoor space and sleeps up to 12 persons.
NOTE: Villa Turquesa can accommodate wedding parties/special events for up to 100 guests (sit down or stand up). There is a minimum stay requirement, an extra event fee plus any applicable permit fees.
Only approved caterers are allowed to work at this villa.
TRAVEL NEWS:Villa Turquesa: Crown Jewel of Pedregal
FLY IN STYLE: Private Jet Charters to Los Cabos
Platinum 6+ Star Rating
The Platinum rating is set aside only for properties of extraordinary opulence. Every significant feature - location, views, furnishings, amenities, condition and service - is one of ultimate beauty, classic workmanship and unequaled refinement.
|Villa Turquesa can accommodate wedding parties/special events for up to 100 guests (sit down or stand up). There is a minimum stay requirement, an extra event fee plus any applicable permit fees.
About the Area: Pedregal - Pacific
The Pedregal is the �Beverly Hills� of private residential gated communities in Cabo San Lucas. Despite 30 years of steady growth, the Mediterranean-inspired community still manages to hold onto its Old World atmosphere while simultaneously embracing the new. Built into a magnificent granite hillside surrounded by exotic desert vegetation, the area�s 360 acres feature sweeping panoramic views over either Cabo San Lucas Bay or the Pacific. With cobblestone streets, fine restaurants and numerous recreational options, the emphasis is on privacy and a casual, tropical lifestyle. Exquisite showpiece homes abound. Excellent swimming is available at M�dano Beach, less than a mile away. The Pedregal is an oasis of exclusivity just steps to all the action of downtown and the marina. The Pacific side of the Pedregal offers stunning ocean views, with whale watching right from the terrace of your luxurious private villa. The beautiful stretch of beach along the Pacific is perfect for sunbathing and beachcombing. Big Pacific waves make this beach unsuitable for swimming.
|Villa Turquessa is an amazing house that is luxuriously furnished with spectacular sunset views over Allan T | North Houston, Texas
|The Villa Turuessa was truly breathtaking. We took our extended family on a vacation and fell in love with the house. The nine spaciously and well furnished rooms were an added surprise for all of our guests. The sounds systems throughout the house allowed us to enjoy to a variety of music whether we were relaxing in the living room, eating dinner or enjoying the magnificent views form the pool. The daily house service was an added benefit as they also provided timely support for questions and recommendation for Cabo activities. The house is located near the top of the Pedregal subdivision and is positioned on the cliffs which overlooked the Pacific Ocean. The pool was definitely an epicenter for our visit as we spend many an afternoons in the spacious pool along with the swim up bar and the attached hot tub. Having the poolside bartender available is highly recommended. We also m
|Exceptional Luxury House for Large Group Stay! Lumbergh_Bill | Austin, Texas
|This house could not be better for a large group vacation to Cabo! LIKES: - AMAZING views from all over the house and the pool and patio - On-site and very helpful concierge assistance during stay - Easy booking of high quality in-house spa treatments - Exceptional chef-quality kitchen - Beautifully furnished and large spaces for group gatherings on patio and in living areas - Gym with nicer equipment than most hotels! - 8 of the 9 bedrooms are perfectly well-suited for couples, with high quality linens, beautiful furnishings and clean bathrooms with modern fixtures. - Great stereo system and reliable wi-fi throughout the house TIPS: - You must book Chef Lorenzo to cook meals / bartend while at the house! He is reasonably-priced, service-oriented and an amazing cook! - The house would be great for a family / group of families with the media room, bunk room, pool, etc but I would n
Manager Response: Thanks so much for sharing your detailed feedback with us about your wonderful vacation at Villa Turquesa. This spectacular cliffside villa in Cabo San Lucas is one of our very finest vacation rentals, offering breathtaking ocean views, unparalleled luxury and beautiful details and artwork throughout the spacious 15,000-square-foot layout. There are few places like it in the world! We're thrilled to hear you had a fantastic time and that our team took great care of you during your stay. We look forward to the opportunity to helping you arrange a return trip to Los Cabos in the future.
|Review from Phil | Laguna Niguel, CA
|Awesome property! Super nice and comfortable.
|Life moves pretty fast...if you don't stop and take a look aroun Brandon Tesmer | CA
|"Life moves pretty fast...if you don;t stop and take a look around you could miss it!" Ferris Buehler Villa Turquesa with your best friends and family constitutes "taking a look around," and living life to its fullest potential. Thank you to Cabo Villas for making Don Julio Smooth Sailing out of a trip of a life time for 22 friends! Brandon Tesmer
Manager Response: Thank you for your great review! We at Earth, Sea & Sky Vacations are glad to see that Turquesa fit all of your needs! Turquesa is a beautiful and expansive villa with 9 bedrooms that sleeps up to 20 adults + 8 children, making this a great villa for large groups!
|Fantastic A FlipKey verified reviewer | Indianapolis
|For the past 15 years our group travels once a year for a little fun and sun. This was our 4th trip to Cabo and the best one ever. What a great place.
|Turquesa A FlipKey verified reviewer | Dallas
|Turquesa is an amazing home - very warm, personal and welcoming. This home was clearly built and decorated with love and with the idea of welcoming friends and family - it has none of the sterile coldness of some vacation rental properties. The Pedregal location is great - wonderful views, very secure, close to the town. The house staff is efficient and unobstrusive. The home has space for everyone to enjoy - media room, mutliple patios, indoor and outdoor dining, exercise room, suffleboard and more. It truly is a wonderful, well thought out and executed home. The only drawback to this home is the wind. Thw breeze off of the pacific can be quite strong and there is very little to break it. This can make being out near the pool outright impossible at times. That is the only drawback to this otherwise luxurious and lovely home.
|When you book a villa rental with us, you'll get $200 worth of FREE extras:
FREE private airport to villa transfer
FREE margaritas, chips and salsa*
FREE Avis car rental delivery
FREE airport and villa arrival services
FREE 1 x 30-min chair massage
FREE 24/7 in-destination support
|Free extras not available for villas located in La Paz (except 24/7 support). Free massage not avail. 12/21 - 1/4. *Seasonal substitutions may apply.
Vacation Guide and Enter to Win!
Win 3 nights at one of our outstanding Los Cabos Resorts! Click Here...
(USA & Canada)
01-831-724-5800 (International)
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All Rights Reserved ©1994 - Present • Earth, Sea and Sky Vacations Inc. • CST#2060094-40


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How do we teach kids that gender equality is fabulous?
For inclusive storytelling, the audience is as important as the story
Jewish Women's Archive has tips for your best Gloria Steinem and Bella Abzug
Plus Egypt bans the Muslim Brotherhood, and more in the news
Likens Quinn to Bella Abzug in new campaign video
Plus the Jews of 1600 Pennsylvania, and more
In a new HBO documentary, Gloria Steinem is treated like the icon she is. But efforts to praise and eulogize her feminism don't do the subject—or the liveliness of the movement she helped inspire—justice.
A friend says yes; I merely marvel at Lieberman's effect on Jews
A new anthology goes with the flow