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Volume 63, Issue 6, 15 September 1975
Collective electron effects of O2 − in potassium superoxide63(1975); http://dx.doi.org/10.1063/1.431676View Description Hide Description
A temperature variation study of dc conductivity, magnetic susceptibility, and ESR on powdered potassium superoxide has been carried out. Also reported is a room temperature measurement of the electronic absorptionspectrum. We find that at temperatures above the structural phase transition temperature T c (193.5°K) reported by Carter and Templeton, the susceptibility is given by χ = c/(T + ϑ) with ϑ ∼ 250°K. Below T c , χ = c′/(T + ϑ) with ϑ′ ∼ 18°K. There is no magnetic ordering down to liquid nitrogen temperature. ESR spectra shows two distinct lines above T c . The broad line is Lorenzian in shape with a width at half‐maximum of about 700 G. The narrow line has a width of 25 G and the area under this resonance is 10−4 times that under the broad one. The broad line splits into two below T c . The number of spins contributing to the broad resonance has a temperature dependence which is qualitatively similar to that of the susceptibility. The narrow ESR line persists through the phase transition. At temperatures greater than 250°K, KO2 is semiconducting with an activation energy of 1.3 eV. The yellow color of KO2 at room temperature is due to an absorption band peaked at 350 nm degrading to 600 nm. A simple theoretical model based on correlation and disorder is proposed which can explain most of these experimental data.
Ambiguities in the interpretation of proton magnetic relaxation data in water solutions of Gd3+ ions63(1975); http://dx.doi.org/10.1063/1.431677View Description Hide Description
We report measurements of the solventproton spin–lattice relaxation rate 1/T 1 in a water solution of GdCl3, pH 5.5, at 5, 15, and 25 °C. The data were obtained as a function of magnetic field, from 5 Oe to 12 kOe, corresponding to proton Larmor frequencies in the range 20 kHz to 50 MHz. The data are compared with theory, and it is shown that a satisfactory fit may be obtained for a range of values of the parameters of the theory. We give the results of a least squares fit of the theory to the data for two extremes of the range, one limit corresponding to the condition that the residence lifetime τ M of a proton in the first hydration shell of the Gd3+ aquoion be comparable to the spin–lattice relaxation timeT 1M of the proton on the ion, the other limit corresponding to τ M ≪T 1M . It is shown that knowledge of the temperature dependence of 1/T 1 cannot distinguish between the two limits, and indeed, that unless a value for τ M is obtained from independent experiments, the ambiguous results cannot be resolved. The source of the ambiguities is discussed in some detail since it is particularly clear in the present system, but considerably less so in systems containing complexes of macromolecules with paramagnetic ions, to which the present experiment is pertinent. It is also pointed out that, while there are many references to values for τ M in the published literature, no experiments have been published that report values of τ M for protons on the Gd3+ ion.
Relaxation of CO2(1001), CO2(0201), and N2O(1001) vibrational levels by near‐resonant V→V energy transfer63(1975); http://dx.doi.org/10.1063/1.431678View Description Hide Description
Laser‐excited vibrational fluorescence experiments on CO2 and N2O combination levels were performed using a tunable optical parametric oscillator. Rate constants near gas kinetic were obtained and assigned to the near‐resonant V→V transfer of an asymmetric stretching quantum. Stimulated emission occurring at 4.3 μ was observed during 2.7 μ excitation of CO2 to the (1001) combination level.
Limit cycle oscillations in the reversible Oregonator63(1975); http://dx.doi.org/10.1063/1.431679View Description Hide Description
The five‐step Oregonator model of the oscillatory Belousov–Zhabotinskii reaction has been expanded by taking into account the reversibility of the various steps. Forward and reverse rate constants have been assigned to four of the five steps by direct analogy to the detailed Field, Körös, and Noyes model of the Belousov–Zhabotinskii reaction. The rate constants and stoichiometry of the fifth step were parametrized and the stability of the steady state was investigated as a function of both of these parameters and the over‐all distance of the system from equilibrium. It was found that there is a critical distance from equilibrium which must be exceeded before the steady state becomes unstable. Numerical integration of the differential equations resulting from the model indicated that the system executes apparent limit cycle oscillations when the steady state is unstable. Introduction of reversibility into the Oregonator leads to a striking change in the range of values of the fifth step stoichiometric parameter over which oscillations will occur. This change is discussed in terms of the chemistry of the Belousov–Zhabotinskii reaction. Under some conditions the reversible Oregonator shows excitability such that a small finite perturbation of an infinitesimally stable steady state may be greatly amplified before the system returns to rest. An apparently analogous phenomenon appears in the Belousov–Zhabotinskii reaction itself.
On the glass transition in organic halide–alcohol mixtures63(1975); http://dx.doi.org/10.1063/1.431680View Description Hide Description
The glass transition temperatures of binary mixtures of various aliphatic organic halides with the lower normal alcohols have been determined. For each halide a correlation is found between the alcohol glass temperature and the initial slope at the pure alcohol end of the curve of glass temperature against the mole fraction of halide. This correlation is related to the hydrogen bondingproperties of the halide. For several proton donor halides a wide composition range for the glass transition is found. The excess glass temperature above that expected for an ideal mixture of these halides with the alcohols shows a maximum value of 5° or more. For some of these halides the excess glass temperature becomes negative in halide rich mixtures. These results are taken to indicate the formation of alcohol–halide clusters in alcohol rich mixtures and dissolution of hydrogen bonded alcohol aggregates in halide rich mixtures.
Spectra and structure of organophosphorus compounds. XIV. Infrared and Raman spectra, vibrational assignment and the asymmetric potential function for ethylphosphine and ethylphosphine‐d 263(1975); http://dx.doi.org/10.1063/1.431681View Description Hide Description
The infrared spectra of gaseous and solid CH3CH2PH2 and CH3CH2PD2 have been recorded from 200 to 3500 cm−1. The Raman spectra of gaseous, liquid, and solid CH3CH2PH2 and CH3CH2PD2 have been recorded from 100 to 3500 cm−1. The g a u c h e and t r a n s isomers have been observed in the fluid phases and only the t r a n s exists in the solid state. A vibrational assignment of the 24 normal modes has been made. Fundamental and hot band transitions have been observed for both the methyl and phosphino torsions. The methyl barrier in the t r a n s d 0 molecule was determined to be 3.74±0.05 kcal/mole and 3.14±0.05 for the g a u c h e d 0 molecule. The potential function for internal rotation around the C–P bond in CH3CH2PD2 was determined and the following potential constants found: V 2=207±6 cm−1, V 3=785±5 cm−1, and V 6=−25±3 cm−1. The energy difference between the potential energy minima of the g a u c h e and t r a n s conformations is 150 cm−1, the t r a n s being the more stable form. The calculated g a u c h e–g a u c h e barrier is 635 cm−1 (1.82 kcal/mole) and the t r a n s–g a u c h e barrier is 944 cm−1 (2.70 kcal/mole). A similar potential function was determined for the CH3CH2PH2 isomer but the fit to this one‐dimensional model was not as good as that for the deuterium compound probably because of greater coupling in the light molecule.
Pretransitional behavior of conductivity and dielectric properties above a smectic C–nematic transition in 4‐4′‐di(n‐alkyloxy)azoxybenzenes63(1975); http://dx.doi.org/10.1063/1.431682View Description Hide Description
Electrical conductivity and dielectric relaxationmeasurements have been made in the nematic phases of the 4‐4′‐di(n‐alkoxy)azoxybenzenes. The higher members of this series have a smecticC phase at lower temperatures. In that case, we have observed that (1) the ratio of the conductivities parallel and perpendicular to the local optical axis is abnormally low (<1) above the smectic–nematic phase transition and increases with temperature, and (2) the activation energy corresponding to the molecular rotational diffusion in the frequency range 0.1–10 MHz is significantly larger than for the lower homologs. We tentatively suggest that our results are due to fluctuations of the smectic order in the nematic phase as first pointed out by Chystiakov and Chaikowsky [Mol. Cryst. Liq. Cryst. 7, 269 (1969)] through observation of x‐ray diagrams.
Energy transfer and spectral line shapes of impurities in crystals63(1975); http://dx.doi.org/10.1063/1.431683View Description Hide Description
The problem of electronic energytransport is solids in discussed. A model system of two molecules interacting with a lattice of phonons is considered. The spectral line shapes and energytransport are treated in various limiting cases, and the connection between these two phenomena is discussed.
127I Mössbauer studies of thyroid compounds63(1975); http://dx.doi.org/10.1063/1.431684View Description Hide Description
Mössbauer effect absorption spectra have been observed with 127I in the thyroid compounds MIT, DIT, T3, and T4. DIT and T4 were found to have similar spectra. The spectrum from MIT was statistically different from DIT and T4. T3 had a spectrum intermediate between MIT and DIT, although not statistically different from either. The effective charge on the iodine nucleus was more positive in MIT than in the other three compounds. All of the compounds exhibited a small s hybridization.
A Monte Carlo method for obtaining the interionic potential of mean force in ionic solution63(1975); http://dx.doi.org/10.1063/1.431685View Description Hide Description
A Monte Carlo method for obtaining the solvent‐averaged interionic potential of mean force is described. The potential of mean force is obtained for two charged hard spheres immersed in a dipolar hard sphere solvent. The ions and solvent particles have the same hard sphere diameters and the ions bear single charges of opposite sign. The solvent particles are characterized by a reduced dipole moment μ*=1.0 which corresponds to a dielectric constant ε?7.8. The Monte Carlo result is compared with the ''primitive model'' and other approximations which have been suggested for the potential of mean force. These approximations are all found to be inadequate for small ionic separations. Some implications with respect to ''ion pairing'' are mentioned.
A model potential for chemisorption: H2+W(001)63(1975); http://dx.doi.org/10.1063/1.431663View Description Hide Description
A potential function to describe the interaction of a diatomic molecule with a solid surface is formulated as a modified LEPS potential. The surface is approximated by a rigid background potential, periodic in the plane of the surface. It is assumed that the individual atom–atom and atom–surface potentials are known and can be reasonably approximated by Morse functions. H2+W (001) is presented as an example. One adjustable Sato parameter is introduced and by varying this parameter a wide range of potentials can be generated. The functional form is sufficiently simple so that classical trajectory studies of the reaction dynamics are feasible. Several illustrative trajectories are presented.
Ultrasonic studies of liquids using hole theory63(1975); http://dx.doi.org/10.1063/1.431664View Description Hide Description
Hole theory of the liquid state has been used for the study of the propagation of ultrasonic waves in some organic liquids. Expressions are obtained for the ultrasonic absorption and dispersion and their variation with temperature and pressure using the concept of holes in a liquid. Available experimental data on the temperature and pressure variation of ultrasonic absorption and dispersion in liquids has been used to verify the validity of the aforesaid expressions. It has been found that the expressions could explain the variation of velocity and absorption in associated, polyatomic, and viscousliquids fairly well. However, the applicability of these equations to nonassociated liquids, especially variation of their absorption with temperature, has been found to be quite poor.
PNO–CI and CEPA studies of electron correlation effects. III. Spectroscopic constants and dipole moment functions for the ground states of the first‐row and second‐row diatomic hydrides63(1975); http://dx.doi.org/10.1063/1.431665View Description Hide Description
A systematic investigation of the ground state potential curves and dipole moment functions has been performed for the diatomic hydrides LiH to HCl on the basis of variational configuration interactionwavefunctions PNO–CI and the coupled electron pair approximation CEPA. The basis sets of Gaussian‐type orbitals are derived by simple rules from optimized atomic sets available in the literature. Between 95% (LiH) and 85% (HCl) of the valence shell correlation energies are accounted for in the CEPA calculations. Core–valence intershell correlation has been included for several members of each row, and its effect on the potential curves is analyzed. Comparison of the spectroscopic constants derived from the CEPA potential curves with experiment shows a high reliability of the theoretical values. The standard deviations over both rows are as follows: r e :0.003 Å, ω e :14 cm−1, α e :0.005 cm−1, and ω e x e :1.5 cm−1. The errors of the calculated dissociation energies go up to 0.3 eV but behave very regularly. They are believed to allow for predictions which are correct to about ±0.05 eV. The following new D 0 values are recommended (empirical values in parenthesis): NH:3.40 (3.2±0.16); NaH:1.88 (2.05±0.2); MgH:1.23 (2.0±0.5); PH:3.02 (3.5±0.3). Various vibrational matrix elements have been calculated from the dipole moment curves. The μ0 values show errors of 0.02–0.04 D. The differences between diagonal elements as well as the transition elements for the first few levels deviate by only about 10% from the available experimental data.
Molecular dynamics of the rough sphere fluid. I. Rotational relaxation63(1975); http://dx.doi.org/10.1063/1.431666View Description Hide Description
A systematic study is made of rotational relaxation in rough sphere fluids for densities ranging from 0.1 to 0.666 of the closest packed density. Many of the current models of rotational relaxation are tested against the results of molecular dynamics. It is found that for densities higher than 0.40 of the closest packed density only the Fokker–Planck model is consistent with experiment. The various extended diffusion models, the jump diffusion model, and the rotational diffusion model are not only internally inconsistent, but also do not agree with experiment. No theory is consistent with experiment at intermediate densities where the collisional and the inertial time scales are comparable. In addition to the foregoing, it appears that the rough spheres tumble more freely in the solid state than they do in the fluid state at the melting density.
Lifetimes for OH and OD electronic states with resonance transitions in the region between 1700 and 1950 Å63(1975); http://dx.doi.org/10.1063/1.431667View Description Hide Description
The upper states of the OH and OD bands in the 1700–1950 Å region have been studied with our phase‐shift radiative lifetime apparatus. We have found lifetimes varying from 1.8±0.2 to 2.9±0.4 ns. Lifetimes for OH and OD are essentially the same, indicating that the upper states are likely to be depopulated via purely radiative processes under our experimental conditions. Lifetimes have also been obtained for the C 2Σ+–A 2Σ+ transition in OH and OD. Our results are consistent with the preliminary analysis of Pryce (private communication) that the 1700–1950 Å bands in OH are partly due to the C 2Σ+–X 2Π i transition.
A CIDEP study of p‐benzosemiquinone63(1975); http://dx.doi.org/10.1063/1.431668View Description Hide Description
Chemically induced dynamic electron polarization (CIDEP) from photolytically generated p‐benzosemiquinone radicals is studied by time resolved steady state experiments. The experimental time resolved intensity curves are fitted to curved derived from theory. Two different polarization contributions are observed with ethylene glycol as solvent. A hyperfine independent initial polarizationP ∞(I) =−0.107 is due to a triplet mechanism (TM) and a hyperfine dependent polarization (−0.032?P*⩽0.032) is caused by a radical pair mechanism (RPM) due to the radical termination reaction.P ∞(I) =−0.034 when isopropanol is used as solvent. The solvent dependence of P ∞(I) is consistent with the microscopic theory and the observed values of P ∞(I) are indicative of a triplet lifetime in the range 0.1–10 nsec and a zero field parameter ‖D‖≳700 G. The magnitude and hyperfine dependence of P* is in accord with the microscopic theory for an exponentially decaying exchange interactionJ (r) with the maximum value J 0≳109 rad/sec. The separation at which J (r) is decreased by a factor 105 equals the distance of closest approach (?6.5 Å).
Raman and depolarized Rayleigh scattering in the liquid state: Reorientational motions and correlations in orientation for symmetric top molecules63(1975); http://dx.doi.org/10.1063/1.431669View Description Hide Description
Reorientational motions perpendicular to the major axis of symmetric top molecules in the liquid state have been examined as a function of temperature by investigating isotropic and anisotropicRaman scattering vibrational band contours. These studies yield information about single molecule reorientation for the systems C6H6, C6D6, CH3CN, CD3CN, CH3I, DCCl3, and HCBr3. Depolarized Rayleigh scatteringmeasurements on the same systems, also as a function of temperature, are combined with data on single particle reorientations to yield information about correlations in orientations between pairs of molecules. These correlations between molecules are found to be important for most symmetric top molecules in the liquid state and the temperature dependence of the Raman and Rayleigh band shapes and bandwidths suggest that hard core forces dominate the cooperative motions in the systems studied.
A spectroscopic study of fluorescence from the second excited singlet state of thiophosgene vapor63(1975); http://dx.doi.org/10.1063/1.431670View Description Hide Description
The S 2–S 0absorption, emission, and excitation spectra of thiophosgene vapor have been measured and the observed single vibronic transitions assigned. Comparison of the absorption and excitation spectra reveals that emission is excited only when transitions to the upper state terminate in 3 m 4 n , m or n=0 or 1, and that the upper state is depopulated by rapid radiationless processes when higher vibrational levels are populated. The most prominent bands in the emission spectrum are those in which the transitions terminate in 1 p 3 q 4 r with 1⩽p⩽10, 1⩽q⩽5, and 1⩽r⩽4. All three types of spectra are consistent with a pyramidal excited state in which the equilibrium internuclear distances are substantially greater than those of the ground state. The implications of this fluorescence ''anomaly'' with respect to the nature of radiationless processes in the thiophosgene are discussed.
Raman spectroscopic investigation of the structure of silicate glasses. I. The binary alkali silicates63(1975); http://dx.doi.org/10.1063/1.431671View Description Hide Description
The Raman spectra of some binary alkali silicate glasses and crystals have been measured and the results interpreted. The glasses are of composition M2O⋅xSiO2, 1⩽x⩽4 and M = Li, Na, K. There is a strong resemblance between glassy and crystalline spectra which is consistent with a considerable amount of structural disorder of the glass. The reason is that the disorder acts as a perturbation on the spectrum of an elementary vibrating unit from which the glass is largely constructed. As a result, the general nature of the glassstructure may be determined. Furthermore, glasses of the same x but with different alkali have different amounts of short‐range order. This is demonstrated by showing that the widths of certain Raman peaks increase with increasing disorder of the Si–O network of the glass. A strong argument is made against the microcrystallite theory of glassstructure. For any composition x, glasses increase in disorder in the direction K → Na → Li. The crystallization rates increase in the same direction, just the opposite of what would be expected on the basis of a microcrystallite theory. Finally, evidence is given for the existence of microscopic concentration fluctuations in presumably single‐phase disilicate glasses.
Model for multiple‐collision trajectories in nonreactive atom–diatom collisions63(1975); http://dx.doi.org/10.1063/1.431672View Description Hide Description
The extent of the complex (multiple‐collision) region (CR) is investigated for a classical nonreactive collinear atom–diatom system. A simple model to estimate the extent of the CR is given, based on the different roles the repulsive and attractive parts of the interaction potential V have in the collision. The model is extended to obtain more detailed information on the CR, such as the extent of m‐collision regions within the CR. In the extended model, a multiple‐collision trajectory is treated as a sequence of single‐collision trajectories on a purely repulsive interaction potential V r . The vibrational excitation produced by V and V r is compared, and it is pointed out that if the motion of the system with V is to be described adequately by V r , it is necessary that multiple‐collision trajectories do not occur.


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Bootnotes > Verity Stob
Brexit at the next junction: Verity's guide to key post-vote skills
STOB Pay attention, campers. I have conducted an impartial analysis of the post-Brexit landscape and identified a list of concrete, must-have programming skills for your edification.
Washed out summer? Fear ye not: DVDs for DevOps droogs
Stob Hurrah! Summer is at last well under way, so how better to pass the weekends than pulling the curtains on the rainscape, lolling on the sofa and inhaling a few dozen hours of downloaded TV? I am aware that such an introduction sets up certain expectations.
The Sons of Kahn and the Witch of Wookey
Stob Editor's Note: Verity Stob's Chronicles of Delphi [King James ed.] began in 1996. The most recent translations can be found here: The Sons of Kahn and the assembly language of the internet, here: The Sons of Kahn and the Pascal spring and here: Sons of Kahn: The Apocrypha.
Alice, Bob and Verity, too. Yeah, everybody's got a story, pal
Stob Once there were a million A&B stories on the Naked Web. Now there are a million-and-one.
Learn you Func Prog on five minute quick!
Stob Functional Programming is the great paradigm shift that is sweeping through software development.
A Bombe Called Christopher, or A Very Poor Imitation
Stob Some weeks ago, on the back of superlative-laced recommendatory posts like this one, I took myself off to the Fosse des Puces high art cinema to see The Imitation Game, the new biopic about Alan "Weird Al" Turing starring Benedict Cumberbatch.
V. R. R. Stob's magnificent saga A Game Of Dog-and-Bones
Stob Laud Satya Nadella stood at the leaded casement of his garret, contemplating the ominous, brooding sky to the south. The flag over the Maeiouster's Hub Complex barely stirred in the still air, so that he could not only see the sigil of his once-proud house - gules and vert oblongs accroupis sur a respectant brace, azure dexter and jaune sinister, of quatrocons, conjoined to the Mark of Registered Trade - but also make out the motto VENIT FENESTRAE (which, as everybody knows, is Old Visbasian for "Windows is coming") proudly emblazoned in the finest, most delicate Comic Sans that the T-shirt weavers of Old Redmond could fashion.
Today's bugs have BRANDS? Be still my bleeding heart [logo]
Stob In view of the ongoing security-holed far-too-open source situation, I have decided to convene an emergency meeting of ERCOCC, the El Reg Committee Of Competent Coders, to review what has occurred and how we should go forward.
Eight EXCELLENT languages for the fondleslab-friendly Intranet of Thingies
Stob What are you up, Verity? Ensconced in one of your comfortable, miles-from-any-critical-path projects?
Three Men in a Tardis
Stob Significant anniversaries bunch together like buses. Three are assaulting me simultaneously, give or take a month or two.
Down with Unicode! Why 16 bits per character is a right pain in the ASCII
Stob I recently experienced a Damascene conversion and, like many such converts, I am now set on a course of indiscriminate and aggressive proselytising.
Verity's summer songs for programmers: Sing your pals to sleep()
Stob "What better way to dispel the rainy gloom of an English summer," mused Ms Stob, in an introduction presumably written some time in March, "than a mass office sing-along to a selection of IT-themed pastiches?"
Bjarne Again: Hallelujah for C++
Stob Now it has been scientifically demonstrated that we Delphi users are the happiest of all programmers, proper significance can at last be attached to the rare woes that occasionally break through our Stepford Coder personas.
In space, no one can hear your laptop Blue Screen
Stob Reg columnist Verity Stob says she's uncovered the following string of eye-opening electronic missives between the International Space Station's crew members. First, some context:
Six things a text editor must do - or it's a one-way trip to the trash
Stob When I heard, in a tutorial video, the multi-platform programmer's editor Sublime described as "the cool kids' code editor" (or possibly "the Cool Kid's code editor" - the speaker didn't enunciate his capitals and apostrophes very clearly) I was puzzled. As the goto (or, rather, the call-by-reference) consultant on Agile Harlem Shake in the northwest corner of our floor, surely no such assertion could plausibly be made without first interviewing me?
Who ate all the Pis?
Stob 10/11/2012
8086 and All That. Revisited
Stob Editor's Note: Verity Stob's celebrated history of computing was first published in EXE magazine in 1997, but has been unobtainable on the internets for several years. Now, thanks to the painstaking reconstruction of small pieces of parchment, and a small monetary inducement, we can now bring it to you as a Seasonal Treat. With added Annotations.
The Sons of Kahn and the assembly language of the internet
Stob Editor's Note: Verity Stob's Chronicles of Delphi [King James ed.] began in 1996. The most recent translations can be found here: The Sons of Kahn and the Pascal spring and here: Sons of Kahn: The Apocrypha.
Google defames Reg columnist Verity Stob
Google's latest improvement to its web search has produced a catastrophic consequence. The Chocolate Factory now adds biographical information to the search result for a person, drawing on the fantastically accurate well of truth that is Wikipedia, and also adding Google's best guess of an identifying photograph.
Stob on Quatermass: Was this British TV's finest sci-fi hour?
Stob Special In the pub, with my editor. "Those sci-fi classics of the fifties," he mused. "Not the Hammer remakes - the originals. Are they really classics? How do they compare with modern Doctor Who? Are they even watchable?"
Five go wild with the Administration Tools Pack
Stob As you have surely heard, it's Alan Turing's centenary this year, and the Bletchley Park museum is celebrating by releasing a game of Monopoly themed on the life of that mathematical genius. I'll pause for a sentence or two here, while you let your boggle levels equalise, because, given Turing's life story, this is a quite a bizarre concept to digest. For example, what are the Chance cards going to be like?
How I Learned to Stop Worrying and Love IPv6
Stob IPv4 addresses are a rapidly dwindling commodity [...] ICANN distributed the last big chunks of available IPv4 addresses to the five continental Regional Internet Registries earlier this year. The RIRs in turn are running out of supplies to allocate to ISPs and other network operators - El Reg
Welcome, friend, to Metroland
Stob When I saw that my editor had written 'Metro isn't the problem: catapulting into Metro land (and back again) is', I said: 'There's an idea - I could do try out the Betj pastiche macro in my HTML editor'. And scurried out the door before anybody thought to stop me.
Stuck in a dull conference? You need Verity's survival guide
Stob The technical conference season is once more upon us. The speakers at these affairs spend a lot of time sharing their software design patterns and anti-patterns with us; as a regular attendee it seemed to me that we punters were overdue for revenge. Here is some of their own medicine.
Hold on, Booker prize judges - Stob's penned a steampunk hit
Stob Somewhere on the hard drive of every programmer-wannabe-writer's laptop there is the first chapter of an unfinished steam punk novel. Here's mine.
Molesworth and the New Latin
Stob 'In his speech [...] the Education Secretary Michael Gove appeared to accept in its entirety the argument that ICT had become little more than training in office skills and something far more rigorous was required [...] While Alex Hope's slogan "coding is the new Latin" did not appeal to some, it must have appealed to the classicist in Michael Gove' - Rory Cellan-Jones, BBC website
The Sons of Khan and the Pascal Spring
Stob [We last heard from the Sons of Khan in 2010. The scriptures continue - Ed.]
Riders of the Bearded Sage
Stob Ever since Richard Stallman hit the news ...
Doctor Who and the Unsatisfactory Five Hole Tape Punch
Stob Stob This sentence is false... As soon as I heard about the sponsored Doctor Who-themed parties, I just knew that they would want an article on the early years of Doctor Who IT to include in the special pack. However, since nobody has actually asked me for it yet, you get first dibs.
Verity's secret shame revealed
Stob I defrosted my ideas box, and found several morsels which wouldn't make a whole meal in themselves, but nonetheless needed eating.
Here lies
Stob Stob After I've gone In a melancholy mood, this week. Went back home to have a look at Dad's bench. He was a Classics scholar, actually; went up to Cambridge and everything. And so above his name and dates on the brass plaque screwed into the wood, instead of "He loved this place" or something equally fatuous, it says:
Educating Verity the OU way
Stob I think I mentioned that I was doing an Open University PGDip course in software development. (For those not familiar with the institution, the Open University has rightly been described as a sort of mental gym. You join with great enthusiasm; then, after three months, having attended just twice, you can drop out and ask for the balance of your subscription back.)
Verity Stob and the super subjunction
Stob Just downloaded the beta version of English V3.31, and I have to say I am very excited about it. This is definitely going to be a feather in the cap of Anglophones everywhere, and way better than the notorious V2.99 release of French (or the 'deux point neufty-neuf' as it has become known). There's a ton of new features to talk about, so let me dive in right away with some toothsome details.
No stranger to the moleskin trouser
Stob A website called MySpace is 'in a death spiral' according to Mr Robert Scoble, who attributes this unhappy state to its being implemented using Microsoft .NET technology, and because it is headquartered in Los Angeles, where apparently there aren't enough good programmers.
In defence of Comic Sans
Stob Stob Good Morning!!!
The Girl with the NSObject Class Reference tattoo
Stob What better occupation, at this time of year, than to polish up one's IT skills with some background reading? What have the great programming publishers got lined up for our delectation in 2011?
I was timeboxed in a holistic scrum
Stob Do you suffer from unsatisfactory projectile climaxes? Is your software construction methodology previous generation? Do you require the predictable outcome of pre-planning with the flexibility of iteration and the lightness of touch of partially de-hierarchicalised management approaches?
Verity Stob faces execution, Wikipedia-style
A 22-year career chronicling the world of computing programming counts for nothing, it seems. Columnist and author Verity Stob may be nominated for deletion from Wikipedia for not being "notable" enough.
Diary of an Overflow Addict
Stob Thursday Medals 0 Rep 0
Sons of Kahn: The Apocrypha
Stob The Sons of Kahn move on
Lord Peter views the logfile
Stob "What is design? Dorothy Sayers (English writer and dramatist - quoted by Brooks) suggests that design has three phases" - InfoQ reviewing Fred 'Mythical Man' Brook's latest tome.
A Rumba with a Roomba
Stob Don't tell me. I've heard it already. You've got the iPadFever. Or Obsession for iPhone 4. Or iMac Mini Madness.

subset: commoncrawl


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Chile has about 10% of the shale fracking potential of Argentina---which makes it huge. The shale is twice as thick when compared to most shale deposits in the United States. Of course, more shale could create more problems. But, as it stands, the potential production from Chile is huge. In Argentina, apache has now brought on 79 wells from fracking. Chevron/Exxon are now moving in to drill even more. The price of natural gas is controled by the country, has been increased. The promise of $7.50 to Chevron/Exxon has brought an interest to drilling. The cross the border of exported natural gas to Chile is still curtailed. This of course is tied to the president of Chile and her decisions about the matter. But, with the once popular president now facing crowds of millions who want her removed---things could change. More oil and gas companies would move into Argentina, once she is removed. The present fear of nationalization is real. The main story for Methanex is the affect on natural gas use---wind farms, geothermal plants, and Bolivian natural gas pipelines does affect the future supply of natural gas production/consumption. The moves by Argentina affecting biodiesel is another issue to be considered, since Argentina is a world leader for this fuel. As of the present time, no fracking wells are in operation in Chile---but this could soon change. Published reports on the thickness of shale in Chile could bring big oil into the region. Of course, hot water into the ground does require new requirements ie equipment and settlement ponds that affect ground water. As for the Falkland Islands---no fracking in deep water. Argentina tries to keep hatred present in the people in order to stay in office. The blocking of the Magellan for trade from Chile to the Falklands could be lifted, in time. The potential for oil/gas in the Falklands is huge. Will the southern region be a major oil/gas producer? The answer is yes in time.
Sentiment: Hold


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Organization for Youth Empowerment
Rating: 4.88 stars 8 8 reviews
3351 18th St Nw Washington DC 20010 USA
OYE is a youth-led organization that develops the leadership and capacity of at-risk Honduran youth. OYE's integrated development approach combines academic scholarships, youth capacity building, and community engagement to inspire and equip young people with the awareness and skills they need to take control of their own lives. The final goal is the empowerment of socially conscious youth who will emerge as leaders and agents of positive change in the Honduran community.
Since 2005, 339 students have received life-changing OYE scholarships and become youth leaders, role-models, and mentors in their community.
Target demographics:
Low-income, at-risk youth in El Progreso, Honduras
Direct beneficiaries per year:
628 youth participants directly affecting 3,640 community youth
Geographic areas served:
El Progreso, Honduras and surrounding area.
Academic Program, Capacity Building and Leadership Program, Institutional Strengthening Program, and Community Engagement Program which includes: OYE El Ritmo, OYE's radio program; Jovenes, a quarterly youth magazine; COPA OYE, an annual sports tournament; Cultural Exchange Program and La Calle, a local public art/mural project.
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Reviews for Organization for Youth Empowerment
Working with OYE showed me that in a short time you can help change lives and that there are people in the world who are "paying it forward" and working to connect our global community. The staff was great, the mission was clear, and the experience was unlike any other. Every teen, every college student around the world should take the time out to empower these exceptional teens working through inconveniences in the name of progress!
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I've personally experienced the results of this organization in...
watching the first class of OYE grow up to be the current staff members, and watching my own students connect to the experiences of children living in the "third world" take opportunities/ and nurture relationships that they take for granted,
If I had to make changes to this organization, I would...
expand its reach to other Latin American nations.
I had the pleasure of volunteering with OYE about 5 years ago when the organization was still in its beginning stages. It has been amazing for me to see how this grassroots organization has grown over the years. It is incredible how the ideals of just a couple of young people, transformed into action, has created such positive change for the lives of the children they reach and the community as a whole. It has truly been inspirational for me to have been involved with OYE.
More Feedback
I've personally experienced the results of this organization in...
seeing the young people involved grow into educated, empowered, and successful adults.
If I had to make changes to this organization, I would...
can't think of anything!
OYE provided me with one of the most rewarding experiences of my life! Their organization and strong outreach into all segments of El Progresso's population allowed them to have a strong and positive impact on the community around them. Their willingness to tackle a variety of problems and give responsibility to the students themselves allows participants to gain life and career skills that are useful and critical for their individual futures. OYE's capacity to work globally with American students like myself ensures that it will maintain a strong presence in the long run. Whether it is a trip to a local orphanage or skill or doing its multi-faceted radio program, OYE is a testament to the future solutions for the El Progresso community and beyond. I look forward to being witness to its ever growing progress in the future.
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I've personally experienced the results of this organization in...
my participation and working alongside them in all of their endeavors.
If I had to make changes to this organization, I would...
stick to a specific activity each day rather than trying to cover a multitude of issues every day.
OYE, MI Voz Es Poder! What an incredible organization and unparalleled experience. Nowhere else in the world have I come across an organization with such a clear and positive mission--empower youth to create socially conscious agents of change--that permeates all the work it does. Oye was created by youth, is run by youth, and directly benefits youth. Its goals are achieved everyday by its existence, but its programs and projects fortify and deepen its impact. OYE equips 90 students with scholarships and capacity/life building skill classes. These students learn about topics ranging from sexual education to project management. After learning they begin teaching, OYE's youth participate in projects that they manage amplifying the voice and positive impact of OYE.
Beyond all its other great attributes, OYE's highest quality in its love. Once you come to OYE as a students, volunteer, employee, or donor you are part of this community. The office becomes a second home, and you know that no matter what happens there is always a place for you within OYE's 4 walls.
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I've personally experienced the results of this organization in...
The first time I volunteered at OYE I met a child who would hardly look at me let alone speak to me. Six months later that same child was quickly becoming a leader in his radio project. After another four months I returned again, and now I would be working directly with this boy who before could hardly look at me. Now the shy timid youth was the coordinator of his own art program and leading 15 other youth. All because OYE believed in him and gave him the responsibility.
If I had to make changes to this organization, I would...
Its har to say what I would like to change about the organization. The greatest thing I'd like to see happen is that all of the people supporting these project and these kids have the chance to visit Honduras and experience them first hand. Working as the volunteer coordinator I believe that there is something incredibly powerful about visiting an organization like OYE, and it doesn't matter how old you are or how much experience you have there is always something new to learn.


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|NBA Basketball
|Player News
|Latest News
|Mar. 19 9:27 PM PT10:27 PM MT11:27 PM CT12:27 AM ET4:27 GMT12:27 9:27 PM MST11:27 PM EST8:27 UAE05:270:27 ET10:27 PM CT3:27 - Williams scored 30 points Friday off the bench for Los Angeles.
Analysis: Williams took advantage since Kobe Bryant didn't play again because of his chronically sore right shoulder.
|Mar. 13 8:52 PM PT9:52 PM MT10:52 PM CT11:52 PM ET3:52 GMT11:52 8:52 PM MST10:52 PM EST7:52 UAE (+1)04:5223:52 ET9:52 PM CT2:52 - Williams returned from a five-game absence with a hamstring injury with 15 points in Sunday's loss to the Knicks.
Analysis: He made 7 of 12 shots in 26 minutes, adding five assists.
|Mar. 3 6:38 PM PT7:38 PM MT8:38 PM CT9:38 PM ET2:38 GMT10:38 7:38 PM MST9:38 PM EST6:38 UAE (+1)03:3821:38 ET8:38 PM CT1:38 - Williams is out for at least a week due to a hamstring injury.
Analysis: Williams' production has slowly declined since January and he isn't considered a great fantasy option at this point.
|Feb. 25 9:56 PM PT10:56 PM MT11:56 PM CT12:56 AM ET5:56 GMT13:56 10:56 PM MST12:56 AM EST9:56 UAE06:560:56 ET11:56 PM CT4:56 - Williams had 22 points in the Lakers' 128-119 loss at Memphis on Wednesday.
Analysis: Williams has topped 20 points in three of the last five games, averaging 19.2 over that stretch.
|Feb. 11 9:53 PM PT10:53 PM MT11:53 PM CT12:53 AM ET5:53 GMT13:53 10:53 PM MST12:53 AM EST9:53 UAE06:530:53 ET11:53 PM CT3:53 - Williams scored 28 points in the Lakers' 120-11 loss at Cleveland on Wednesday.
Analysis: Williams is averaging 15.4 points on the season. He's scored at least 20 points in 13 games, but the Lakers have lost 10 of them.
|Jan. 28 6:00 PM PT7:00 PM MT8:00 PM CT9:00 PM ET2:00 GMT10:00 7:00 PM MST9:00 PM EST6:00 UAE (+1)03:0021:00 ET8:00 PM CT0:00 - Williams will miss Thursday's game against Chicago due to an upper respiratory infection.
Analysis: Williams was forced to exit Wednesday's practice early due to the illness. It's unclear whether he'll be healthy enough to play in Friday's matchup with the Clippers.
|Jan. 17 8:47 PM PT9:47 PM MT10:47 PM CT11:47 PM ET4:47 GMT12:47 9:47 PM MST11:47 PM EST8:47 UAE05:4723:47 ET10:47 PM CT2:47 - Williams put up 20 points Sunday.
Analysis: Williams made 7 of 12 field goal attempts, including 1 of 2 from deep, and connected on 5 of 6 foul shots.
|Jan. 16 8:44 PM PT9:44 PM MT10:44 PM CT11:44 PM ET4:44 GMT12:44 9:44 PM MST11:44 PM EST8:44 UAE05:4423:44 ET10:44 PM CT2:44 - Williams contributed 20 points Saturday.
Analysis: Williams shot 5 for 16 from the field, including 3 of 4 on 3s, and made 7 of 8 free throws. He should put up numbers Sunday if Kobe Bryant is out.
|Jan. 15 10:50 PM PT11:50 PM MT12:50 AM CT1:50 AM ET6:50 GMT14:50 11:50 PM MST1:50 AM EST10:50 UAE07:501:50 ET12:50 AM CT4:50 - Williams continued his recent scoring binge with 21 points in Thursday's loss at Golden State.
Analysis: The veteran guard has been on a tear during the new year, averaging 23.3 points in eight games in 2016. Williams had a 44-point effort against Oklahoma City last Friday.
|Jan. 13 10:20 PM PT11:20 PM MT12:20 AM CT1:20 AM ET6:20 GMT14:20 11:20 PM MST1:20 AM EST10:20 UAE07:201:20 ET12:20 AM CT4:20 - Williams scored nine of his 19 points in the fourth quarter Tuesday.
Analysis: Williams' clutch play was good for owners who award clutch points. He still missed 10 of 14 shots in an awful effort in a terrible NBA game in front of Yasiel Puig, Jack Black and Aziz Ansari.
|Jan. 10 8:51 PM PT9:51 PM MT10:51 PM CT11:51 PM ET4:51 GMT12:51 9:51 PM MST11:51 PM EST8:51 UAE05:5123:51 ET10:51 PM CT2:51 - Williams led the team with 18 points Sunday.
Analysis: Fresh off a 44-point explosion, Williams struggled from the field by shooting 5 for 17, while also committing six turnovers.
|Jan. 9 9:56 PM PT10:56 PM MT11:56 PM CT12:56 AM ET5:56 GMT13:56 10:56 PM MST12:56 AM EST9:56 UAE06:560:56 ET11:56 PM CT3:56 - Williams exploded for a season-best 44 points including five 3-pointers, along with two steals Friday.
Analysis: Williams has explosive potential as he showed when he did damage from both the foul line (15-15) and 3-point range (5-14), while knocking down 12 of 25 field goal attempts.
|Jan. 6 9:19 PM PT10:19 PM MT11:19 PM CT12:19 AM ET5:19 GMT13:19 10:19 PM MST12:19 AM EST9:19 UAE06:190:19 ET11:19 PM CT3:19 - Williams looked sort of like Kobe Bryant on Tuesday.
Analysis: Williams missed all seven shots from the field, though he made all 10 at the line for his points.
|Jan. 4 9:29 PM PT10:29 PM MT11:29 PM CT12:29 AM ET5:29 GMT13:29 10:29 PM MST12:29 AM EST9:29 UAE06:290:29 ET11:29 PM CT3:29 - Williams scored 30 points Sunday.
Analysis: Williams has 54 points the last two games with Kobe Bryant out so he is taking advantage to get his numbers.
|Jan. 1 8:58 PM PT9:58 PM MT10:58 PM CT11:58 PM ET4:58 GMT12:58 9:58 PM MST11:58 PM EST8:58 UAE05:5823:58 ET10:58 PM CT2:58 - Williams rang in the New Year with 24 points Friday.
Analysis: Williams matched a season high in what was surely an emotional night against the team he broke in with, the Sixers.
|Dec. 20 10:14 PM PT11:14 PM MT12:14 AM CT1:14 AM ET6:14 GMT14:14 11:14 PM MST1:14 AM EST10:14 UAE07:141:14 ET12:14 AM CT4:14 - Williams made 4 of 6 of his 3-point attempts on the way to 20 points on Saturday.
Analysis: He made 5 of 11 shots overall and added three steals in his first 20-point game in two weeks and fourth of the season.
|Oct. 29 9:52 PM PT10:52 PM MT11:52 PM CT12:52 AM ET4:52 GMT12:52 9:52 PM MST11:52 PM EST8:52 UAE05:520:52 ET10:52 PM CT2:52 - Williams scored 21 points in his first game with Los Angeles on Wednesday.
Analysis: Williams somehow missed a leaning 4-footer at the buzzer in the one-point loss much to the chagrin of a bemused Kobe Bryant. "When I let it go, I thought it was a bucket," Williams said. "It's a routine play for me."
|Oct. 17 7:08 PM PT8:08 PM MT9:08 PM CT10:08 PM ET2:08 GMT10:08 7:08 PM MST9:08 PM EST6:08 UAE (+1)04:0822:08 ET9:08 PM CT1:08 - Williams returned with 19 points Thursday in exciting preseason action.
Analysis: Williams sat out Saturday with a sore groin.
|July 5 5:21 PM PT6:21 PM MT7:21 PM CT8:21 PM ET0:21 GMT8:21 5:21 PM MST7:21 PM EST4:21 UAE (+1)02:2120:21 ET7:21 PM CT23:21 - The Los Angeles Lakers say they plan to sign guard Lou Williams, last season's Sixth Man of the Year.
Analysis: Williams averaged a career-high 15.5 points and helped Toronto win a franchise-record 49 games in 2014-15, his lone season there. The Lakers have upgraded their guard rotation by adding Williams after drafting Ohio State's D'Angelo Russell with the No. 2 pick. Deals can't be signed until Thursday, but general manager Mitch Kupchak says Sunday in a release that the Lakers are negotiating with both players and intend to sign them once the free agent moratorium ends.


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An F-22 has crashed in South California – $190m that US taxpayers won't see again, in a $71.6 billion program to build an aircraft that can't even reliably deliver oxygen to the pilot.
The US Air Force has at least scrapped its Enterprise Resource Planning software project after spending US$1 billion, concluding that finishing it would cost far too much more money for too little gain. It'll now keep using the old systems, which apparently work just fine, until at least 2017.
But remember, defense spending is sacrosanct on a bipartisan basis. Social Security and Medicare will now need to be cut further …
Just in case you were wondering how other nations do things, though – the answer is "just as badly".
Slow, leaky, rusty: Britain's £10bn submarine beset by design flaws
Bonus Read: A "red team" of US Navy hackers managed to hack the maintenance systems of the F-35, the most expensive fighter plane in history. But don't worry, the US is the only country that has hackers…
This post was read 117 times.


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Forum indexCanon EOS-1D / 5D / 6D TalkChange forum
Thinking about upgrading. Thoughts?
Started Apr 4, 2013 | Discussions thread
Shop cameras & lenses ▾
laubjerg • New Member • Posts: 6
Re: Thinking about upgrading. Thoughts?
In reply to Vader90 • Apr 6, 2013
Having recently made precisely that step I can only recommend it. The 5D is another type of camera entirely. With it you get the pro Canon handling layout. You get dedicated buttons that you suddenly don't know how you lived without. Its a pleasure to just hold the 5D.
And you make the step to full frame with it. There is just no going back - not for me anyway. But like others have stated, brace yourself for the lense impact
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Have questions for Jordin Sparks?
Season six "American Idol" winner and "Sparkle" star Jordin Sparks is coming to the Boston Store at Southridge Mall Friday to promote her new fragrance, "Ambition." I'm slated to get a few minutes to ask her a few questions Friday, but I have a question for her fans first: what do you think I should ask Jordin Sparks?
Darkness over the top - but in a good way
Justin Hawkins, frontman for British band The Darkness, had some choice words to say in a Journal Sentinel interview for those who think his glam rock group is a joke.
But let us examine some of the damning evidence at the band's Rave show Saturday, shall we? »Read Full Article
Fitzwater brings Piaf alive in Skylight's 'Onstage'
The music and life story of popular French singer Edith Piaf get under one's skin.
Singer-actress Leslie Fitzwater, who has brought Piaf to the stage several times over the course of her career, opened her one-woman "Edith Piaf Onstage" at the Skylight Music Theatre on Friday evening. »Read Full Article
First Stage's ambitious 'Promised Land' is a dream deferred
Ruth, an African-American girl in her early teens, is lost. Her father is long gone. Her overworked mother is rarely around. Her beloved brother is dead. It's 1969, and, while Ruth should be in school, she is watching TV instead.
In "To the Promised Land" - unveiled by First Stage Children's Theater on Friday night - playwright Jonathan Gillard Daly links Ruth's struggles with another coming-of-age story that unfolded in Milwaukee, where a young Golda Meir underwent her own journey of self-discovery. Daly places both girls in the same house on Walnut St., nearly 60 years apart. »Read Full Article


text: Disney/Pixar Cars 2 SHAKE 'N GO!® World Grand Prix - Shop.Mattel.com Flag this deal What's the matter? Choose a reason Dead deal Duplicate Bad link Spam Inaccurate No value Alive again Edit deal kimeeb Sep 21, 2012 You're welcome!! How have you been? Reply FibroMom Sep 21, 2012 I know a few little boys that would LOVE to have this under their Christmas Trees! NICE Price on such a fun toy! Thanks for sharing this Great Deal! :) Reply 1 like Load More Comments


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Flannel Friday
Brandi Klassen of Marshfield holds her son Blake, 1, as he greets "Doc" between wagon rides in downtown Montpelier during Flannel Friday festivities in the Capital City.
The day after Thanksgiving is the traditional start to the holiday shopping season and a day many spend at the mall or big-box stores. In an effort to persuade shoppers to spend their money closer to home, merchants in downtown Montpelier have developed a local alternative to Black Friday and dubbed it Flannel Friday. Shoppers wearing the classic Vermont attire were treated to sale prices and specials at many stores. Above, Brandi Klassen, of Marshfield, holds her son Blake, 1, as he greets Doc between free wagon rides. Left, employees and customers, many clad in flannel, watch as Myra O'Neill, of Somerville, Mass., spins the Wheel of Deals at Onion River Sports. Below, Skip, the Vermont Mountaineers' mascot, sports his flannel shirt while crossing the street Friday in Montpelier. Barre merchants get into the act today with a downtown open house and a full day of festivities and shopping.MORE IN Central VermontBARRE One of Barres best success stories Bond Auto Parts apparently encountered an offer... Full StoryMONTPELIER Secretary of State Jim Condos said Thursday that Iberdrola Renewables offer to make... Full StorySPRINGFIELD A local man who robbed six banks, a gas station and a pharmacy in Vermont and New... Full Story
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Your Feedback Matters!
Please take some time to fill out our end of the year coach survey. Both surveys will allow you to choose House or Travel programs, and should only take a minute to complete!
Travel Baseball Tryout Information
2017 9U, 10U and 11U Travel Baseball rosters to be posted on Sunday 8/21/16.
2017 Iron Horse Baseball Tryout dates. The schedule is as follows:
- 9u 8/15 and 16 // 530pm check in
- 10u 8/8 and 9 // 530pm check in
- 11u 8/8 and 9 // 400pm check in
- 12u 8/16 and 17 // 600pm check in *** TIME CHANGE****
- 13u 8/18 and 19 // 530pm check in
- 14u Red 8/13 // 10am check in
- 14u Blue 8/15 // 530pm check in
- 15u 8/15 and 16 // 530pm check in
- 16u Red 8/8 and 9 // 530 check in
- 16u Blue and White 8/22 // 530 check in ***UPDATED***
- 18u TBD
All tryouts are at the Lou Gehrig complex.Check in at the concesion stand. Must be appropriate age as of April 30, 2017. All players new to Lou Gehrig should bring a birth certificate. Please contact us if you have any questions or concerns.
Steve Balcerzak - President of Baseball (firstname.lastname@example.com)
Kyle Schraufstetter - VP of Baseball (email@example.com)
LG Scholarship Opportunity!
It is time for our Annual Lou Gehrig Memorial Scholarship opportunity. With the money raised from Old Fashioned Day, we like to give back to the Lou Gehrig Community. What better way to give back than to allow our children an opportunity to earn a college scholarship! If your child is or has been a baseball or softball player, umpire, part of the Lou Crew or concession stand worker at Lou Gehrig for 5 or more years and is going to college in the fall or is currently in college, they are eligible. Please click the link below for the application and more detailed information. The deadline is August 8, 2016 for this upcoming school year.
Softball Champs!
Baseball Champs!
Like us on Facebook!
Lou Gehrig is now on Facebook! Like our page at https://www.facebook.com/lgybs/ for an additional way to get more LG info and news!
Become a Lou Gehrig Sponsor.
Sponsors are necessary to fund the many programs that Lou Gehrig Youth Baseball and Softball offer. It is also a great way to advertise directly to potential customers and clients. It is a WIN WIN!!!!
For more information visit:
LGYBS Complex Info
We hope you all enjoy spending time at our facilities throughout the season. So that everyone continues to enjoy them we ask that the following rules be followed:
- No pets allowed on the premise - NO exceptions
- Please do not allow your children to play on unoccupied fields
- Please supervise young children at all times
- Please keep our restrooms clean
We thank you for your support and are looking forward to another GREAT season at LGYBS!


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Top Choice Modern Danish in Copenhagen
Alberto K
Perched on the 20th floor of the Radisson Blu Royal Hotel, Alberto K is a culinary high, both literally and metaphorically. Award-winning head chef Jeppe Foldager marries modern French techniques with local produce …
Top Choice Modern Danish in Copenhagen
Top Choice Modern Danish in Aalborg
Mortens Kro
Hands down both the best and priciest in town, sleek Mortens Kro is owned by celebrity chef Morten Nielsen. It's a stylish, well-hidden place where top-quality local, seasonal produce is showcased: home-smoked trout…
Top Choice Danish in Copenhagen
A verified institution, Schønnemann has been lining bellies with smørrebrød (open sandwiches) and snaps since 1877. Originally a hit with farmers in town peddling their produce, the restaurant's current fan base inc…
Top Choice Seafood in Copenhagen
Kødbyens Fiskebar
Concrete floors, industrial tiling and a 1000-litre aquarium meets impeccable seafood at this Michelin-listed must, slap bang in Vesterbro's trendy Kødbyen ('Meat City' district). Ditch the mains for three or four s…
Top Choice Modern Scandinavian in Copenhagen
Top Choice Italian in Copenhagen
Pop – et Spiseri
Petite Pop is run by four Danish women passionate about Italian nosh. There's no conventional menu; just the one four-course menu with matching wines and coffee for Dkr600. Whether it's pappa al pomodoro (Tuscan bre…
Top Choice Seafood in Kerteminde
Fiske Restaurant Rudolf Mathis
One of Funen's best restaurants occupies a striking waterside building south of Kerteminde harbour. This is classic seafood served in innovative ways that recognise delicate flavours and pair perfectly with locally …
Top Choice Danish in Vordingborg
If you're in the region it's definitely worth visiting Babette, 1km north of the centre, for a full gastronomic and aesthetic treat. The restaurant (named after the film Babette's Feast) is well known for its origin…
Top Choice French in Svendborg
There's a clever blend of rustic-France-meets-Denmark at this appealing little bistro, tucked into a half-timbered house. Cheese or charcuterie for lunch, a small, sweet menu of selections for dinner (coq au vin, br…


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Investors Seem Pleased With Raja Arrest
India's telecom sector is probably one of the few industries that has had not one but two of its federal ministers arrested. Fourteen years after then telecom minister, Sukh Ram, was arrested on corruption charges, another telecom minister, Andimuthu Raja, met the same fate on Wednesday as the country's Supreme Court kept an eagle eye on the probe into what could be India's most expensive government scandal.
After questioning Mr. Raja at least four times in the middle of a prolonged campaign by opposition parties, the federal Central Bureau of Investigation arrested Mr. Raja, the former telecom secretary Siddartha Behura and the minister's former personal secretary, accusing them of irregularities in the licensing of telephone spectrum in 2008.


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Think about real life, pick up a ball and spin the opposite way without breaking your wrist. If you bowl the correct way, you should not notice this at all. (For instance, right handed person hitting a 10 pin by standing left all the way, aiming at the gutter and spinning to the left) There should never be any situation in the game where you change your actual throw, just the direction.
For people who can't bowl straight, STOP TRYING, your probably better than you would be anyway.
</rant from a varsity bowler>


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What is included with this book?
The most comprehensive, widely used, and evidence-based pharmacotherapy text available
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Hailed by Doody's Review Service as "one of the best in pharmacy" Pharmacotherapy: A Pathophysiologic Approach is unmatched in its ability to help students develop a mastery of evidence-based medicine for optimum patient outcomes. The eighth edition will feature the addition of SI units throughout and an increased number of global examples and clinical questions.
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Section 1: Foundation Issues Section Editor: L. Michael Posey
1. Pharmacoeconomics: Principles, Methods, and Applications
2. Health Outcomes and Quality of Life
3. Health Literacy and Medication Use
4. Cultural Competency
5. Principles and Practices of Medication Safety
6. Evidence Based Medicine
7. Documentation of Pharmacy Services
8. Clinical Pharmacokinetics and Pharmacodynamics
9. Pharmacogenetics
10. Pediatrics
11. Geriatrics
12. Palliative Care
13. Pharmacoepidemiology
14. Clinical Toxicology
15. Emergency Preparedness: Identification and Management of Biologic Exposures
16. Emergency Preparedness: Identification adn Management of Chemical and Radiologic Exposures
Section 2: Cardiovascular Disorders Section Editor: Robert L. Talbert
17. Cardiovascular Testing
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19. Hypertension
20. Systolic Heart Failure
21. Diastolic Heart Failure and the Cardiomyopathies
22. Acute Decompensated Heart
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27. Stroke
28. Dyslipidemia
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30. Use of Vasopressors and Inotropes in the Pharmacotherapy of Shock
31. Hypovolemic Shock
Section 3: Respiratory Disorders Section Editor: Robert L. Talbert
32. Introduction to Pulmonary Function Testing
33. Asthma
34. Chronic Obstructive Pulmonary Disease
35. Pulmonary Hypertension
36. Drug-Induced Pulmonary Diseases
37. Cystic Fibrosis
Section 4: Gastrointestinal Disorders Section Editor: Joseph T. DiPiro
38. Evaluation of the Gastrointestinal Tract
39. Gastroesophageal Reflux Disease
40. Peptic Ulcer Disease
41. Inflammatory Bowel Disease
42. Nausea and Vomiting
43. Diarrhea, Constipation, and Irritable Bowel Syndrome
44. Portal Hypertension and Cirrhosis
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46. Pancreatitis
47. Viral Hepatitis
48. Drug Therapy Individualization in Patients with Hepatic Disease or Genetic Alterations in Drug Metabolizing Activity
49. Celiac Disease
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50. Clinical Assessment of Kidney Function
51. Acute Kidney Injury
52. Chronic Kidney Disease: Progression-Modifying Therapies
53. Chronic Kidney Disease: Management of Complications
54. Hemodialysis and Peritoneal Dialysis
55. Drug-Induced Kidney Disease
56. Glomerulonephritis
57. Drug Therapy Individualization for Patients with Renal Insufficiency
58. Disorders of Sodium and Water Homeostasis
59. Disorders of Calcium and Phosphorus Homeostasis
60. Disorders of Potassium and Magnesium Homeostasis Donald F. Brophy and Todd W. B. Gehr
61. Acid-Base Disorders
Section 6: Neurologic Disorders Section Editor: Barbara G. Wells
62. Evaluation of Neurologic Illness
63. Alheimer's Disease
64. Multiple Sclerosis
65. Epilepsy
66. Status Epilepticus
67. Acute Management of the Brain Injury Patient
68. Parkinson's Disease
69. Pain Management
70. Headache Disorders
Section 7: Psychiatric Disorders Section Editor: Barbara G. Wells
71. Evaluation of Psychiatric Illness
72. Childhood Disorders
73. Eating Disorders
74. Substance Related Disroders: Overview and Depressahts, Stimulants and Hallucinogens
75. Substance-Related Disorders: Alcohol, Nicotine, and Caffeine
76. Schizophrenia
77. Major Depressive Disorders
78. Bipolar Disorder
79. Anxiety Disorders I: Generalized Anxiety, Panic, and Social Anxiety Disorders
80. Anxiety Disorders II: Posttraumatic Stress Disorder and Obsessive-Compulsive Disorder
81. Sleep Disorders
82. Disorders Associated with Intellectual Disabilities
84. Thyroid Disorders
85. Adrenal Gland Disorders
86. Pituitary Gland Disorders
Section 9: Gynecologic and Obstetric Disorders Section Editor: Barbara G. Wells
87. Pregnancy and Lactation: Therapeutic Considerations
88. Contraception
89. Menstruation-Related Disorders
90. Endometriosis
91. Hormone Terapy in Women
Section 10: Urologic Disorders Section Editor: L. Michael Posey
92. Erectile Dysfunction
93. Benign Prostatic Hyperplasia
94. Urinary Incontinence
Section 11: Immunologic Disorders Section Editor: Gary C. Yee
95. Function and Evaluation of the Immune System
96. Systemic Lupus Erythematosus and Other Collagen-Vascular Diseases
97. Allergic and Pseudoallergic Drug Reactions
98. Solid-Organ Transplantation
Section 12: Rheumatologic Disorders Section Editor: L. Michael Posey
99 Osteoporosis and Other Metabolic Bone Diseases
100. Rheumatoid Arthritis
101. Osteoarthritis
102. Gout and Hyperuricemia
Section 13: Ophthalmic and Otolaryngological Disorders Section Editor: L. Michael Posey
103. Glaucoma
104. Allergic Rhinitis
Section 14: Dermatologic Disorders Section Editor: L. Michael Posey
105 Dermatologic Drug Reactions and Common Skin Conditions
106. Acne Vulgaris
107. Psoriasis
108. Atopic Dermatitis
Section 15: Hematologic Disorders Section Editor: Gary C. Yee
109. Anemias
110. Coagulation Disorders
111. Sickle Cell Disease
112. Drug-Induced Hematologic Disorders
Section 16: Infectious Diseases Section Editor: Joseph T. DiPiro
113. Laboratory Tests to Direct Antimicrobial Pharmacotherapy
114. Antimicrobial Regimen Selection
115. Central Nervous System Infections
116. Lower Respiratory Tract Infections
117. Upper Respiratory Tract Infections
118. Influenza
119. Skin and Soft Tissue Infections
120. Infective Endocarditis
121. Tuberculosis
122. Gastrointestinal Infections and Enterotoxigenic Poisonings
123. Intraabdominal Infections
124. Parasitic Diseases
125. Urinary Tract Infections and Prostatitis
126. Sexually Transmitted Diseases
127. Bone and Joint Infections
128. Sepsis and Septic Shock
129. Superficial Fungal Infections
130. Invasive Fungal Infections
131. Infections in Immunocompromised Patients
132. Antimicrobial Prophylaxis in Surgery
133. Vaccines, Toxoids, and Other Immunobiologics
134. Human Immunodeficiency Virus Infection
Section 17: Oncologic Disorders Section Editor: Gary C. Yee
135. Cancer Treatment and Chemotherapy
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137. Lung Cancer
138. Colorectal Cancer
139. Prostate Cancer
140. Lymphomas
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142. Acute Leukemias
143. Chronic Leukemias
144. Multiple Myeloma
145. Myelodysplastic Syndromes (Web-only)
146. Skin Cancer
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148. Hematopoietic Stem Cell Transplantation
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149. Assessment of Nutrition Status and Nutrition Requirements
150. Medication Administration Considerations With Specialized Nutrition Support
151. Parenteral Nutrition
152. Enteral Nutrition
153. Nutritional Considerations in Major Organ Failure
154. Obesity


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Mayatex™ Chaparral Blanket
The Mayatex™ Chaparral Western Saddle Blanket will dazzle in the show ring or brighten up your daily ride with its multi-colored, beautiful pattern! Read more...
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Kyosho Inferno GT2 VE Race Spec Audi KYO30935B
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This is the Kyosho Inferno GT2 VE Race Spec Audi. With its roots from the 1/8 scale nitro, the Kyosho Inferno GT2 boasts a super robust and efficient drive train and tough chassis as well as a variety of parts support and availability making it the perfect high performance brushless platform.
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