text:
|Publication number
|Publication type
|Application number
|Publication date
|May 9, 2000
|Filing date
|Nov 13, 1997
|Priority date
|Nov 18, 1996
|Fee status
|Also published as
|Publication number
|Syouichi Sugitani
|Original Assignee
|Konica Corporation
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (12), Non-Patent Citations (3), Referenced by (5), Classifications (12), Legal Events (4)
|External Links: USPTO, USPTO Assignment, Espacenet
The present invention relates to an image-forming material and its preparation method, and more specifically to an image-forming material which exhibits high sensitivity and high resolution and is excellent in abrasion resistance of an image, and its preparation method.
Conventionally, recording methods have been known in which radiation energy such as laser radiation is converged and irradiated onto a recording material, and a part of the material is fuse deformed, scattered, burnt or vaporize removed. These methods exhibit advantages in that they are dry processes requiring no solution containing chemicals and high contrast is obtained because only the part subjected to exposure of radiation is fuse deformed, scattered and/or vaporize removed, and have been applied to photoresist materials, optical recording materials such as optical disk, etc., image-forming materials in which they themselves are employed to prepare visible images and the like.
For example, Japanese Patent Publication Open to Public Inspection Nos. 59-5447, 59-105638, 62-115153, etc. describe a method and its materials in which a binder resin is photo-dissociated by a pattern exposure to form a resist pattern; Japanese Patent Publication Open to Public Inspection Nos. 55-132536, 57-27788, 57-103137, etc. describe information recording in which an inorganic compound thin layer prepared by an evaporation method is exposed and is fuse deformed; further, Japanese Patent Publication Open to Public Inspection Nos. 64-56591, 1-99887, 6-40163, etc. describe materials employed for recording information by removing a colored binder using light-heat conversion, and U.S. Pat. No. 4,245,003 describes an image-forming material having an image-forming layer comprising graphite or carbon black and a peeling material.
When images are formed using the above-mentioned methods, image defects are sometimes caused on the surface of images due to the fact that abrasion marks are caused by friction between image-forming materials themselves, friction during handling and the like. In order to improve the abrasion resistance of images, Japanese Patent Publication Open to Public Inspection No. 60-255491 describes a technology in which an image-protecting layer is arranged on an image-recording layer. As the thickness of the image-protecting layer increases, the abrasion resistance of images is improved. However, on the other hand, disadvantages are caused in that energy necessary for image recording increases and further, resolution is degraded.
In view of the foregoing, the present invention has been accomplished. An object of the present invention is to provide the improvement in abrasion resistance of the whole of an image-forming material without causing the decrease in sensitivity and resolution.
The image forming material of the present invention and embodiment thereof are described.
The image-forming material comprises an image-forming layer comprising colorant particles and a binder and a protective layer on a support in this order wherein Vickers hardness H of the whole layers on a side having an image forming layer is from 50 to 500.
The image-forming layer is prefer ably prepared by coating a liquid comprising colorant particles and a binder.
The image is preferably formed by that an exposure is performed using a light having high intensity energy on the image forming layer and an exposed area of said image-forming layer is then removed.
In the image-forming material, Vickers hardness h of the image-forming layer is preferably from 50 to 200.
In the image-forming material, the image-forming layer is preferably hardened after coating and Vickers hardness h1 before hardening is from 25 to 180 and Vickers hardness h2 after hardening is from 50 to 200.
The total thickness of the whole layers on a side having an image forming layer is preferably from 0.1 to 10.0 μm.
Particles in the image-forming layer are those comprising a metallic atom.
The metallic atom-containing particles are preferably ferromagnetic metal powder.
In the image-forming material, G'2 /G'1 of the whole layers on a side having an image forming layer is preferably 0.01 or more wherein G'1 represents the storage elastic modulus at 10-4 of dynamic distortion caused by vibration having a constant frequency and G'2 represents the storage elastic modulus at 10-2 of said distortion.
The image-forming layer has a thickness of preferably 0.1 to 5.0 μm.
Colorant particles in the image-forming layer are metallic atom-containing particles. The metallic atom-containing particles are preferably ferromagnetic metal powder.
The binder is preferably at least one selected from polyurethane, polyester, vinyl chloride resin, phenoxy resin and cellulose series resin.
The image forming material, wherein the image-forming material in which Vickers hardness H of an image-forming layer is from 50 to 200, may be prepared by a method that the image-forming layer is hardened after coating and Vickers hardness h1 before coating is from 25 to 180 and Vickers hardness h2 after coating is from 50 to 200 is prepared using at least one selected from calendering and thermosetting treatment after coating and drying the image-forming layer.
The inventors have found that when the hardness and elastic modulus of the image-forming side of the image-forming material are in the range of definite values, image durability is improved and furthermore, when the hardness of the image-forming layer alone is adjusted in a certain range, high image durability is also obtained, and have accomplished the present invention. In the following, more explanation is given on those.
In the present invention, the hardness of all layers on the image-forming side on a support is evaluated in terms of the Vickers hardness and the adjustment of the Vickers hardness of 50 to 500 makes it possible to obtain high image durability. The Vickers hardness being not less than 50, the preferable image durability is obtained and the image is not erased by abrasion and the like. By controlling the Vickers hardness of 500 or more, the layer is suitable to make it possible to form an image because a part subjected to light having high intensity energy can be removed.
The Vickers hardness H, h, h1 and h2 are controlled by selecting the conditions such as species of raw material of image forming layer (for example, binder resin), species and amount of hardener, calendering condition (for example, pressure and temperature), application of thermosetting processing and its time, application of image protective layer, and so on. The suitable Vickers hardness is readily obtained for a person skilled in this art by selecting the above mentioned condition in combination optionally.
The Vickers hardness H, h, h1 and h2 are defined as values obtained as mentioned in the following.
Using a triangular pressure element having vertically opposite angle of 80�,
Load: 0.1 mg to 0.2 g
Indenting speed: 1 to 25 nm/second
Measurement ambient: 20 to 30� C./40 to 80% relative humidity
Indentation depth: 3 μm or less from the surface
Under the above conditions, a diamond trigonal pyramid needle is indented using a piezo-electric actuator. At this time, letting X be the indentation depth indented by the load W, hardness H(a) at a depth of a is expressed as;
W(X)=K∫H(a) (X-a)da(K: constant)
For a uniform material having variation in hardness,
Accordingly, the relationship of the load W(X) versus the square of the indentation depth X results in straight line and H (Vickers hardness) can be obtained according to the slope.
Furthermore the image-forming material which is excellent in abrasion resistance is obtained in such a way that the Vickers hardness h of the image-forming layer is from 50 to 200, and in addition, the image-forming layer is hardened after coating; the Vickers hardness h1 prior to hardening is from 25 to 180 and the Vickers hardness after hardening is from 50 to 200. By rendering the Vickers hardness of the image-forming layer h 50 to 200, the image durability can be enhanced. Furthermore, the formation of coating defects such as abrasion marks and the like caused in production processes can be prevented. In addition, by rendering the Vickers hardness h1 before coating 25 to 180, the formation of coating defects such as abrasion marks and the like caused in the production process before hardening can be prevented.
In the present invention, with the use of hardening agents, the hardness of the image-forming layer can be controlled. As the hardening agents, can be employed, without any limitation, those which can harden the image-forming layer. Examples such as those hardening agents include polyisocyanates, etc. which are employed to synthesize polyurethane in a binder resin described in the following. By hardening the image-forming layer to which any of hardening agents such as those is added, not only the durability of the formed image can be enhanced but also background tints on an exposed part after removal can be eliminated.
Furthermore, by arranging an image-protecting layer composed of a binder as the main component, the hardness of the whole layers arranged on a support can be adjusted to a desired value to yield the high image durability.
Furthermore, by optimizing the storage elastic modulus under a certain stress subjected to the image-forming layer, durability can result in the image-forming layer. Namely, the inventors, based on the study mentioned below, have evaluated the dynamic viscoelasticity of the image-forming layer as a parameter of the storage elastic modulus under a certain distortion force and have enhanced the durability of the image-forming material by optimizing the storage elastic modulus.
One of dynamic qualities of the image-forming layer includes durability against a large and small deformation distortion caused during handling a image-forming material. The degradation of the durability of the image-forming material itself is estimated due to the fact that an internal structure order formed in the image-forming layer is destroyed by the distortion caused in the transporting line in the system at the image forming. This image-forming layer incorporates colorant particles and a high polymer binder, and it is estimated that the dynamic quality largely depends on both qualities. Furthermore, it is found that there is a close relationship between the dynamic quality and a dispersibility of the colorant particles in a binder. For example, it is supposed that an internal structure having a large difference between the elastic modulus under small deformation distortion and that under large deformation distortion corresponds to a structure in which the dispersibility of the colorant in a binder in the image-forming layer is low and the interior of the image-forming layer is not homogeneous and the number of strain concentration points increases and structure destruction is likely caused. On the other hand, it is supposed that the internal structure having a small difference between the elastic modulus under small deformation distortion and that under large deformation distortion is excellent in the dispersibility and the interior of the image-forming layer corresponds to a homogeneous structure and is not destroyed under high distortion. Accordingly it may be noted that the colorant is well dispersed in a binder and the durability of the image-forming layer is improved.
The storage elastic modulus of the coated layer is obtained by subtracting the storage elastic modulus of the support from that of the coated layer and the support as a whole. The storage elastic modulus G' is defined herein as a measurement obtained as follows. As a measurement apparatus, for example, RSA-II (manufactured by Leo Metrics Co.) is employed and using a sample having a length and width of 23 mm and 2 mm, respectively, which is prepared by coating an image-forming layer on a polyethylene terephthalate film, the measurement is obtained by changing applied distortion in the range of 2�10-5 to 2�10-2 at a frequency of 100 rad/second at temperatures of 0 to 40� C.
In the present invention, the storage elastic modulus is obtained as described above and the ratio of G'2 /G'1 of the whole layers on a side having an image forming layer is adjusted to 0.01 ore more, wherein G'1 is the storage elastic modulus at 10-4 of dynamic distortion (applied distortion) and G'2 is the storage elastic modulus at 10-2 of the dynamic distortion (applied distortion), and particularly preferably 0.03 or more and 1.0 or less. According to combinations of employed colorant particles and binders or deposition of dispersion methods, durability against desired deformation distortion can be evaluated using the storage elastic modulus.
The storage elastic modulus is controlled by selecting the conditions such as species of raw material of image forming layer (for example, binder resin), species and amount of hardener, calendering condition (for example, pressure and temperature), application of thermosetting processing and its time, application of image protective layer, and so on. The suitable storage elastic modulus is readily obtained for a person skilled in this art by selecting the above mentioned condition in combination optionally.
In the following, structures of the image-forming material are explained in detail.
(Image-forming Material)
The image-forming material, as the basic structure, is composed of a support having thereon an image-forming layer and a protective layer if desired.
A support employed in the present invention includes, for example, each of plastic films composed of acrylic acid esters, methacrylic acid esters, polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polycarbonate, polyacrylate, polyvinyl chloride, polyethylene, polypropylene, polystyrene, nylon, aromatic polyamide, polyether ether ketone, polysulfone, polyethersulfone, polyimide, polyetherimide, etc. and furthermore, plastic film having layers of 2 or more comprising resins mentioned above. In order to obtain an image having high resolution, the surface roughness Ra, measured using the JIS B 0601, of the surface of the support which contacts with an image-forming layer is preferably less than 0.10 μm and more preferably less than 0.05 μm. With the use of the support as mentioned above, images having high resolution can be obtained. Furthermore, remaining ratio of the part of the image-forming layer where bonding strength is decreased by an exposure of light having high intensity energy and the exposed part is removed can be reduced to obtain an image excellent in contrast.
Furthermore, as the support, one which is stretched in the form of film and thermally set is preferable in terms of dimensional stability and furthermore, which has high transmittance at the wavelength of an exposure light having high intensity energy is preferable and the transmittance is preferably 50% or more and more preferably 70% or more. In addition, in view of the transport and abrasion resistance at the production of the image-forming material, fillers such as titanium oxide, zinc oxide, barium sulfate, calcium carbonate, etc., coloring agents such as bluing agent, antistatic agents and the like may be added. The thickness of a support is from about 10 to about 500 μm and preferably from 25 to 250 μm.
(Image-forming Layer)
The image-forming layer of the image-forming material comprises at least colorant particles and a binder.
Any colorant particles can be employed with no limitation if they enable the decrease in the bonding strength between the image-forming layer and the support. In order to conduct efficiently image formation, colorants which absorb the light having high intensity energy employed for an imagewise exposure are preferable and particularly, colorants having absorption in the range of 350 to 850 nm are preferable so as to read an image.
Colorants such as those mentioned above include metal-containing dyes such as metal phthalocyanines, metal porphyrin, etc. and metal atom-containing particles such as metal powder particles; metal oxide powder particles such as cobalt oxide, iron oxide, chromium oxide, copper oxide, titanium black, etc.; nitride-containing powder such as niobium nitride; metal carbide powder such as tantalum carbide, metal sulfide powder. Of these, in obtaining a high resolution image securing high intensity, inorganic metal particles in which particle size and shape are comparatively uniform are preferable. Examples include metal particles composed of only metals of one or two or more kinds, oxides, nitride or carbide particles of these metals, various magnetic powder particles employed in magnetic ink, etc.
In case the ferromagnetic particles are used in the invention ferromagnetic iron oxide powder, ferromagnetic metal powder, or cubic tabular powder is optionally used and among these ferromagnetic iron oxide powder or ferromagnetic metal powder is suitably used and especially ferromagnetic metal powder is more suitably used.
The ferromagnetic iron oxide includes γ-Fe2 O3, Fe3 O4, and an intermediate iron oxide thereof, Fex O (1.33<x<1.50).
Examples of the ferromagnetic metal powder include ferromagnetic metal powders such as Fe type, Co type, Fe--Al type, Fe--Al--Ni type, Fe--Al--Zn type, Fe--Al--Co type, Fe--Al--Ca type, Fe--Ni type, Fe--Ni--Al type, Fe--Ni--Co type, Fe--Ni--Zn type, Fe--Ni--Mn type, Fe--Ni--Si type, Fe--Ni--Si--Al--Mn type, Fe--Ni--Si--Al--Zn type, Fe--Ni--Si--Al--Co type, Fe--Al--Si type, Fe--Co--Ni--P type, Fe--Co--Al--Ca, Ni--Co type, and magnetic metal powder whose principal components are Fe, Ni and Co. Of them, Fe type metal powders are preferable, and include Co-containing iron oxides such as Co-containing γ-Fe2 O3, Co-coated γ-Fe2 O3, Co-containing γ-Fe3 O4, Co-coated γ-Fe3 O4, and Co-containing magnetic FeOx (4/3<x<3/2). In view of corrosion-resistance and dispersibility the preferred are Fe--Al type ferromagnetic metal powders including Fe--Al type, Fe--Al--Ca type, Fe--Al--Ni type, Fe--Al--Zn type, Fe--Al--Co type, Fe--Ni--Si--Al--Co type and Fe--Co--Al--Ca type. Of these powders, the preferable are ferromagnetic powder in which the content ratio of a Fe atom to an Al atom is 100:1 to 100:20 and the content ratio at 100 Å depth of a Fe atom to an Al atom is 30:70 to 70:30 measured through ESCA (X ray spectroscopy for chemical analysis) or ferromagnetic powder containing at least one of Fe, Ni, Al, Si, Co and Ca in which the Fe content is 90 atom % or more, the Ni content is 1 to 10 atom %, the Al content is 0.1 to 5 atom %, the Si content is 0.1 to 5 atom %, the Co or Ca content (or the sum content of Co and Ca) is 0.1 to 13 atom %, and the content ratio by the number of atom at 100 Å depth, Fe:Ni:Al:Si:(Co and/or Ca) is 100:(not more than 4):(10 to 60):(10 to 70):(20 to 80), measured through ESCA (X ray spectroscopy for chemical analysis).
The shape of the ferromagnetic powder is needle-like, having an average major axial length of less than 0.30 μm and preferably less than 0.20 μm. Employing such a powder, the surface property of the image forming layer is improved.
The metal containing particle content of the image forming layer is 50 to 99 weight %, and preferably 60 to 95 weight %.
The binder resin can be used without limitations, as long as the binder can carry metal containing particles and a colorant absorbing a light of a light source. Typical binders are polyurethanes, polyesters, and vinyl chloride type resins such as vinyl chloride copolymers. Preferably, these resins contain repeated units having at least one polar group selected from --SO3 M, --OSO3 M, --COOM and --PO(OM1)2, wherein M represents a hydrogen atom or an alkali metal atom, M1 represents a hydrogen atom, an alkali metal atom or an alkyl group. These polar groups have a function to enhance dispersibility of magnetic particles and are contained in the resin at a rate ranging from 0.1 to 8.0 mol %, preferably from 0.5 to 6.0 mol %.
The binders can be used either singly or in combination of two or more kinds.
The polar group-containing polyvinyl chloride is prepared by reaction of a hydroxy group containing resin such as vinyl chloride-vinyl alcohol copolymer with a polar group and chlorine atom containing compound such as ClCH2 CH2 SO3 M, ClCH2 CH2 OSO3 M, ClCH2 COOM or ClCH2 P (═O) (OM1)2.
Further, in order to improve thermal stability of a binder, an epoxy group is preferably incorporated in a vinyl chloride copolymer. The content of a unit having an epoxy group in the copolymer is 1 to 30 mol %, preferably 1 to 20 mol %. The monomer to incorporate epoxy is preferably glycidyl acrylate.
The polar group-containing polyester is prepared by condensation reaction of a polyol with a polybasic acid having a polar group. The polybasic acid having a polar group includes 5-sulfoisophthalic acid, 2-sulfoisophthalic acid, 4-sulfoisophthalic acid, 3-sulfophthalic acid, 5-sulfoisophthalic acid dialkyl, 2-sulfoisophthalic acid dialkyl, 4-sulfoisophthalic acid dialkyl and 3-sulfophthalic acid dialkyl, or a metal salt thereof, and the polyol includes trimethylolpropane, hexane triol, glycerin, trimethylolethane, neopentyl glycol, pentaerythritol, ethylene glycol, propylene glycol, 1,3-butane diol, 1,4-butane diol, 1,6-hexane diol, diethylene glycol and cyclohexane dimethanol.
The polar group-containing polyurethane is prepared by reaction of a polyol with a polyisocyanate. The polyol includes polyol polyester prepared by reaction of polyol with a polybasic acid having a polar group. The polyisocyanate includes diphenylmethane-4,4'-diisocyanate, 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 1,5-naphthalene diisocyanate and lydin isocyanate methylester. Another preparation method of the polar group-containing polyurethane includes a reaction of polyurethane having a hydroxy group with a compound containing a polarsuch a and a chlorine atom such as ClCH2 CH2 SO3 M, ClCH2 CH2 OSO3 M, ClCH2 COOM or ClCH2 P(═O)(OM1)2.
Besides the above resins, the binder resin includes vinyl chloride resins such as polyolefins such as butadiene-acrylonitrile copolymers, polyvinyl acetals such as polyvinyl butyrals, cellulose derivatives including nitrocellulose, styrene resins such as styrene-butadiene copolymers, acryl resins such as polymethylmethacrylates, polyamide resins, phenolic resins, epoxy resins, and phenoxy resins.
The above mentioned polyurethan, polyester, vinyl chloride resin, phenoxy resin or cellurose resin is preferably applied for good dispersing coloring particles in image forming layer and adjusting storage modulus of elasticity. Other additive
The image forming layer may contain additives such as durability improvers, dispersing agents, anti-static agents, fillers and hardeners, as long as the effects of the invention are not inhibited.
Fatty acid, fatty acid ester, fatty acid amide, (modified) silicon oil, fluoride resin, carbon fluoride etc are referred as a lubricant. Polyisocyanate and so on are cited as a durability improver. The dispersing agents include fatty acids having 12 to 18 carbon atoms such as lauric acid and stearic acid or their amides, alkali metal salts or alkali earth metal salts, polyalkyleneoxide alkyl phosphates, lecithin, trialkyl polyolefinoxy quaternary ammonium salts and azo compounds having a carboxy group or a sulfon group. The antistatic agents include a cationic surfactant, an anionic surfactant, a nonionic surfactant, a polymeric antistatic agent and conductive fine particles and compounds described on pages 875 and 876, 11290 Chemicals, edited by Kagaku Kogyo Nippo Co. Ltd.
The fillers include inorganic fillers such as carbon black, graphite, TiO2, BaSO4, ZnS, MgCO3, CaCO3, ZnO, CaO, WS2, MOS2, MgO, SnO2, Al2 O3, α-Fe2 O3, α-FeOOH, SiC, CeO2, BN, SiN, MoC, BC, WC, titanium carbide, corundum, artificial diamond, garnet, tripoli, diatomaceous earth, dolomite, and organic fillers such as polyethylene resin particles, fluorine-containing resin particles, guanamine resin particles, acryl resin particles, silicone resin particles, and melamine resin particles. These fillers can be used as a releasing agent. The addition amount of the inorganic or organic fillers is preferably 0.1 to 70 weight %, although the amount varies depending on their specific gravity.
The addition amount of the additives in the image forming layer is 0-20 weight %, and preferably 0-15 weight %.
The thickness of the image forming layer is 0.05 to 5.0 μm, and preferably 0.1 to 3.0 μm. The thickness of the image forming layer is over 0.05 μm, and preferably 0.1 μm or more and not more than 5.0 μm. The image forming layer may be a single layer or multiple layers whose compositions may be the same or different. In the multiple layers, the layer closest to a support preferably contains a colorant capable of absorbing light of a light source in a larger amount. The layer farther from a support may contain a colorant capable of absorbing a light having a wavelength longer than the light of a light source.
Image protective layer
The thickness of the image protective layer is 0.03-5.0 μm, and preferably 0.05-0.5 μm.
The image protective layer is preferably composed of resin binder and fine particle mainly.
The resin for the binder can be used without any limitation, as long as it can carry the fine particles. The binder resin includes polyurethane, polyester, vinyl chloride resins such as vinyl chloride copolymers and vinyl chloride-vinyl acetate copolymers, polyolefins such as butadieneacrylonitrile copolymers, polyvinyl acetals such as polyvinyl butyrals, cellulose derivatives including nitrocellulose, styrene resins such as styrene-butadiene copolymers, acryl resins such as polymethyl methacrylates, polyamide resins, phenolic resins, epoxy resins, phenoxy resins, acetal resin such as polybutyl butyral, polyvinyl acetoacetal, and polyvinylformal, and water soluble resins such as polyvinyl alcohol and gelatin. The resin binders can be used singly or in combination.
The binders can be used either singly or in combination of two or more kinds. The content of binder in the image protective layer is 10-99.5 wt %, and preferably 40-98 wt % of components of the image protective layer.
The image protective layer preferably contains a hardener such as a polyisocyanate in order to enhance its durability. When the image protective layer is hardened, the binder resin of the image protective layer has a functional group capable of reacting with a hardener and cross-linking. For example, when the hardener is an isocyanate compound, a phenoxy, cellulose, polyvinyl acetal, acryl or urethane resin, a polyvinyl chloride resin or a polyester resin is preferably used.
Examples of the fine particle include same material as those for filler, and preferably it is added 0.1-70 wt % according to its gravity. The fine particles are preferably those having narrow particle size distribution and uniform particle size. Actual examples include silicon resin fine particle (trade name Tospearl product of Toshiba Silicon Co,. Ltd), cross linked acryl fine particle MR series, cross linked polystyrene fine particle SGP series, acryl ultra fine particle series MP and so on (product of Sokenkagaku Co,. Ltd.).
The invention is effected by an image protective layer in which some fine particles protrude from the surface. Accordingly, an average particle size r of the fine particles greater than the thickness r of the image protective layer is advantageous, since most particles protrude from the surface of the image protective layer. Therefore, the average particle size r of the fine particles in the invention is preferably 0.3 to 20 μm, and more preferably 0.3 to 4.5 μm. The content of the fine particles in the image protective layer in the invention is 2 to 150 mg/m2, and preferably 2 to 100 mg/m2. In the invention, when the fine particles have a polymerizable functional group on the surface, image durability is greatly improved since adhesion between the image forming layer and the fine particles is enhanced during hardening. The example of the fine particles includes FX-GSZ-07 produced by NIPPON SHOKUBAI Co., Ltd.
In the present invention it is preferable for adjusting the hardenss and storage modulus of elasticity to make a thickness of all layers of 0.1-10 μm.
Preparation Method of Image Forming Layer
The image forming layer is formed by kneading ferromagnetic particles, a binder, and optionally a lubricant, a durability improving agent, a dispersant, an anti-static agent, a filler and a hardener in a solvent to obtain a coating composition, coating the coating composition on the support and drying.
The solvents include alcohols (ethanol, propanol), cellosolves (methyl cellosolve, ethyl cellosolve), aromatic solvents (toluene, xylene, chlorobenzene), ketones (acetone, methylethyl ketone), esters (ethylacetate, butylacetate), ethers (tetrahydrofurane, dioxane), halogenated solvents (chloroform, dichlorobenzene), amide type solvents (dimethylformamide, N-methylpyrrolidone). As for the kneaders for an image forming layer composition, suitable examples include two-roll mills, three-roll mills, ball mills, pebble mills, coball mills, Tron mills, sand mills, sand grinders, Sqegvari attritor, high-speed impeller dispersers, high-speed stone mills, high-speed impact mills, dispersers, high-speed mixers, homogenizers, supersonic dispersers, open kneaders, and continuous kneaders.
In order to form an image forming layer on a support, coating is carried out by, for example, an extrusion method and then it is dried. Magnetic particles are optionally oriented may be carried out.
Calender treatment is preferably carried out in order to make hard the surface of the image forming layer. The calender treatment is, for example, carried out in such way that the support having dried image forming layer is introduced to calendering machine, and calender treatment is carried out. As for calender condition, temperature is preferably 60 to 120� C., more preferably 70 to 110� C. Pressure is preferably line pressure of 100 to 500 Kg/cm, more preferably 200 to 400 Kg/cm. When each of the temperature and pressure is lower than the lower limit, the coated layer is not satisfactory and resolution of the image is lowered. When these are higher than the higher limit, coating layer is cracked and the product is not acceptable.
When the another layer than the image forming layer is provided, each layer may be coated and dried separately, and the layers may be multilayer coated by wet-on wet coating method. In carrying out wet-on-wet multilayer coating, a combination of an extrusion coater with a reverse roll, a gravure roll, an air doctor coater, a blade coater, an air knife coater, a squeeze coater, a dip coater, a bar coater, a transfer roll coater, a kiss coater, a cast coater or a spray coater can be used. The adhesion between upper and lower layers is enhanced, since in the multilayer coating according to the wet-on-wet method the upper layer is coated on the wet lower layer.
The heat curing process may be applied in order to harden the coated layer in place of or in addition to calender treatment. Temperature is 40 to 80� C. and more preferably 50 to 70� C. for the heat curing condition. Curing time is preferably, in case of single layer, 12 to 36 hours and more preferably 18 to 30 hours.
<Image Forming Method>
The image forming material is subjected to imagewise exposing by a high density energy light, and then the exposed portion of image forming layer is removed whereby an image is formed. The image exposure may be conducted from the support side or image forming layer. The high density energy light for image exposure is not limitative as far as it make possible by exposure to make the image forming layer removed by any means. In order to obtain a high resolving power, the light source is preferably an electromagnetic wave capable of making the energy spots smaller, particularly, a UV light having 1 nm to 1 mm wavelength, a visible light or an infrared light. Such a high density energy light includes, for example, a laser light, an emission diode, a xenon flush lamp, a halogen lamp, a carbon arc light, a metal halide lamp, a tungsten lamp, a quarts mercury lamp and a high pressure mercury lamp. The energy applied is optionally adjusted by selecting an exposure distance, an exposure time or an exposure strength according to kinds of image forming materials used.
When an entire exposure is carried out using the high density energy light, the exposure is carried out through a mask material having a negative pattern made of a light shielding material.
When an array light such as an emission diode array is used or exposure using a halogen lamp, a metal halide lamp or a tungsten lamp is controlled using an optical shutter material such as liquid crystal or PLZT, a digital exposure according to an image signal is possible, and direct writing is possible without using the mask material.
However, this method requires additional optical shutter beside the light source. Therefore, the digital exposure is preferably carried out using a laser light.
When the laser light is used, the light can be condensed in the beam form and a latent image is formed using a scanning exposure according to an image. The laser light is easy to condense the exposure spots in small size and therefore, a highly dissolved image can be obtained. The laser light used in the invention is well known. The laser source includes solid lasers such as a ruby laser, a YAG laser, a glass laser, a gas laser such as a He--Ne laser, a Ar laser, a Kr laser, a Co2 laser, a Co laser, a He--Cd laser, a N2 laser, an eximer laser, an semiconductor laser such as a InGaP laser, a AlGaAs laser, a GaAsP laser, a InGaAs laser, a InAsP laser, CdSnP2 laser or a GaSb laser, a chemical laser, and a dye laser. Of these laser light sources, a laser having a 600 to 1200 nm wavelength is preferable in sensitivity in order to produce effectively abrasion, since a light energy can be effectively converted to a heat energy. Among these a laser having a 600 to 1200 nm wavelength is preferable in sensitivity in order to produce effectively abrasion, since a light energy can be effectively converted to a heat energy, further, high luminescent laser having a single wavelength light.
The image forming method comprises the steps of imagewise exposing the image forming layer of the image forming material to a high density energy light, whereby adhesion force at the exposed portions between the support and the image forming layer is reduced, and then removing the image forming layer at exposed portions where the adhesion force is reduced. The reduction of the adhesion force includes the phenomena that the image forming layer is completely scattered by physical or chemical change, the image forming layer is partly destroyed and/or scattered, and physical or chemical change occurs only neighbor of the support without destroying surface of image forming layer.
Hereafter the invention illustrated in view of Examples. Hereafter, "part" means the "part by weight of effective component" without special note.
(Preparation of Image-forming Material)
Corona discharging was applied to the surface of polyethylene terephthalate film support on which an image-forming layer was arranged and on the reverse surface was arranged a backing layer by coating a mixture composed of an organic solvent, a polyester resin, a silicone resin filler and an antistatic agent. An image-forming layer as mentioned below was arranged on the resulting support.
(Image-forming Layer-1)
Fe--Si--Al--Ni--Co series ferromagnetic metal powder 100 parts (Fe : Si : Al : Ni : Co ratio of the number of atoms=100 : 1 : 4 : 3 : 5 (total), average major axial diameter: 0.14 μm, Hc : 1760 oersted, σs : 120 emu/g, BET: 59 m2 /g)
Vinyl chloride series resin containing potassium sulfonate group 6 parts
(MR-110 manufactured by Nippon Zeon Co., Ltd.)
Polyurethane resin containing sodium sulfonate group 6 parts (UR-8300 manufactured by Toyoboseki Co., Ltd.)
Stearic acid 1 part
Myristic acid 1 part
Butyl stearate 1 part
Polyisocyanate compound 5 parts (Coronate L manufactured by Nippon Polyurethane Co., Ltd.)
Cyclohexanone 100 parts
Methyl ethyl ketone 100 parts ps Toluene 100 parts
A composition composed of above materials was knead dispersed using a sand mill and an image-forming layer coating dispersion was prepared. The resulting dispersion was coated on a support using extrusion coating and dried. Calendering was performed under a pressure of 150 kg/cm at 90� C. and an Image-forming Layer-1 having a thickness of 1.0 μm was formed.
(Image-forming Layer-2)
An Image-forming Layer-2 having a thickness of 1.5 μm was prepared in the same way as in the Image-forming Layer-1 except that the same amount of a phenoxy resin (PKHH manufactured by UCC Co.) was employed instead of MR-110 (potassium sulfonate group containing vinyl chloride series resin) manufactured by Nippon Zeon Co., Ltd.
(Image-forming Layer-3)
An Image-forming Layer-3 was prepared in the same manner as in the Image-forming Layer-i except that Co doped FeOx (average major axial diameter=0.45 μAm, Hc =750 oersted, BET=45 m2 /g, x=1.427) was used instead of Fe--Al series ferromagnetic metal powder.
(Image-forming Layer-4)
Carbon black (average particle diameter=0.04 μm) 25 parts Potassium sulfonate group containing vinyl chloride
Series resin (same as above-mentioned) 13 parts
Sodium sulfonate group containing polyurethane 13 parts resin (UR-8700 manufactured Toyoboseki Co. Ltd.)
α-Alumina 8 parts
Stearic acid 1 part
Butyl stearate 1 part
Polyisocyanate compound (same as above-mentioned) 5 parts
Cyclohexanone 80 parts
Methyl ethyl ketone 80 parts
Toluene 80 parts
The Image-forming Layer-4 having a thickness of 2.0 μm was prepared in the same manner as in the Image-forming Layer-1 except that the composition mentioned above was used.
Subsequently, the following composition 1) or 2) was coated on the image-forming layer at a coating amount of 0.1 g/m2 using wire bar coating. Thus, the Image-protecting Layer-1 or Image-protecting Layer-2 was formed.
Composition 1)
Binder resin: Phenoxy resin 3.5 parts (UCAR phenoxy resin PKHH manufactured by Union Carbide Co.)
Hardening agent: diphenylmethane-4,4'-diisocyanate 1.5 parts (Millionate MT manufactured by Nippon Polyurethane Co., Ltd.)
Methyl ethyl ketone 95 parts
Fine particle: silicone resin fine particle (average particle diameter 2.0 μm) 0 or 40 mg/m2 (Tospearl 120 manufactured by Toshiba Silicone Co., Ltd.)
Composition 2)
The same as the Composition 1) except that potassium sulfonate group containing vinyl chloride series resin (MR-110 manufactured by Nippon Zeon Co., Ltd.) was used as a binder resin instead of the phenoxy resin.
As a peeling layer, a transparent polyethylene terephthalate film (S100 manufactured by Diafoil Hoechst Co., Ltd.) was employed and on the peeling layer, an adhesive layer forming coating composition mentioned below was coated and dried to form an adhesive layer having a thickness of 4.0 μm. Thereafter, the adhesive layer surface of the peeling layer was faced with the protective layer surface and underwent pressure treatment using pressure rolls (transporting speed: 30 mm/second, pressure: 2.0 kg/cm) so that no air bubble is included. Thus, an image-forming material was prepared in which the image-forming layer, protective layer and peeling layer were coated in this order.
Ethylene-vinyl chloride copolymer 3.0 parts (Everflex V410 manufactured by Mitsui du Pont Polychemical Co., Ltd.)
Silicon fine particle 0.6 part (Tospearl 145 manufactured by Toshiba Silicone Co., Ltd.)
Toluene 90 parts
Cyclohexanone 6.4 parts
Table 1 shows prepared image-forming materials and Vickers hardness.
TABLE 1______________________________________ Image-forming Protective Vickers Sample No. Layer Layer Calendering Hardness______________________________________1 1 1 No 324 2 1 1 Yes 478 3 1 2 No 286 4 1 2 Yes 421 5 1 None No 82 6 1 None Yes 189 7 2 1 No 336 8 2 1 Yes 496 9 2 2 No 301 10 2 2 Yes 444 11 2 None No 86 12 2 None Yes 192 13 3 1 No 275 14 3 1 Yes 421 15 3 2 No 265 16 3 2 Yes 400 17 3 None No 53 18 3 None Yes 152 Comparative 1 4 1 No 36 Comparative 2 4 1 Yes 44 Comparative 3 4 2 No 42 Comparative 4 4 2 Yes 48 Comparative 5 4 None No 18 Comparative 6 4 None Yes 10______________________________________
(Image-forming Method)
Using a semiconductor laser LT090MD (main wavelength 830 nm) manufactured by Sharp Corporation, an imagewise exposure was performed using a scanning exposure from the support side while focused on the interface between the support and the image-forming layer. Thereafter, the peeling layer was peeled (peeling angle 189�, peeling speed 30 mm/second) and an image was formed by transferring, to the peeling layer side, the part where the bonding strength was reduced.
Sensitivity, and resolution and abrasion resistance of formed images were evaluated according to the following scales.
A solid scanning exposure was performed using a beam diameter of 4 μm so that an image having a size of 0.5 mm�0.5 mm was formed and the scale consisting of five levels was used to evaluate the average exposure amount (E: unit mJ/cm2) on the surface of the image-forming material on which the image was formed.
An image was formed with an average exposure amount on the surface of the image-forming material using a scanning exposure having a beam diameter of 4 μm and a scanning pitch of 4 μm, and evaluation was performed using the scale consisting of four levels according to the number (N) of resolvable lines per 1 mm regarding to the obtained image.
Abrasion Resistance
Tests were performed using a scratch meter. Load of 0 to 200 g was applied using a needle of a diameter of 0.1 mm onto the image-protecting layer of each sample on which a peeling layer was not put yet. Thereafter, the state of each sample surface was visually observed.
4 . . . No change is observed.
3 . . . Change in gloss is observed. However, no abrasion reaches to the image-forming layer.
2 . . . A portion of the image-forming layer is damaged and transmission intensity at the portion decreases.
1 . . . The support of the image-forming layer is damaged.
Table 2 shows above results.
TABLE 2______________________________________ Abrasion Sample No. Sensitivity Resolution Resistance______________________________________1 4 4 3 2 5 4 4 3 4 4 3 4 5 4 4 5 5 4 3 6 5 4 3 7 4 4 4 8 5 4 4 9 4 4 4 10 5 4 4 11 5 4 3 12 5 4 3 13 4 3 4 14 5 4 4 15 4 3 4 16 4 4 4 17 3 4 3 18 3 4 3 Comparative 1 1 2 2 Comparative 2 2 1 2 Comparative 3 1 1 2 Comparative 4 2 1 2 Comparative 5 1 1 1 Comparative 6 1 2 1______________________________________
An image-forming material was prepared in the same manner as in example 1 except that when preparing an image-forming layer coating composition, mix kneading conditions were varied, and was evaluated. Table 3 shows the storage elastic modulus ratio of image-forming materials to the image-forming layer and Table 4 shows results.
TABLE 3______________________________________ Image-forming Kneading Sample No. Layer Calendering Apparatus G '2/G'1______________________________________19 1 Yes Pressure 0.65 Kneader 20 1 Yes Henschel 0.45 Mixer 21 1 Yes Dissolver 0.15 22 1 No Pressure 0.23 Kneader 23 1 No Henschel 0.18 Mixer 24 2 Yes Pressure 0.68 Kneader 25 2 Yes Henschel 0.32 Mixer 26 2 Yes Dissolver 0.06 27 2 No Pressure 0.21Kneader 28 2 No Henschel 0.16 Mixer 29 3 Yes Pressure 0.12 Kneader 30 3 Yes Henschel 0.08 Mixer 31 3 Yes Dissolver 0.01 32 3 No Pressure 0.05 Kneader 33 3 No Henschel 0.03 Mixer Comparative 7 1 No Dissolver 0.0008 Comparative 8 2 No Dissolver 0.001 Comparative 9 3 No Dissolver 0.0005 Comparative 10 4 Yes Pressure 0.008 Kneader Comparative 11 4 Yes Henschel 0.006 Mixer Comparative 12 4 Yes Dissolver 0.0007 Comparative 13 4 No Pressure 0.0005 Kneader Comparative 14 4 No Henschel 0.0002 Mixer Comparative 15 4 No Dissolver 0.00008______________________________________
TABLE 4______________________________________ Abrasion Sample No. Sensitivity Resolution Resistance______________________________________19 5 4 4 20 5 4 4 21 4 4 3 22 4 4 4 23 4 4 3 24 5 4 4 25 5 4 4 26 4 4 3 27 4 4 4 28 4 4 3 29 5 4 4 30 4 4 4 31 4 4 3 32 4 4 4 33 4 4 3 Comparative 7 3 3 2 Comparative 8 3 3 2 Comparative 9 3 3 2 Comparative 10 2 2 1 Comparative 11 2 2 1 Comparative 12 1 1 1 Comparative 13 2 2 1 Comparative 14 2 2 1 Comparative 15 1 1 1______________________________________
According to the present invention, an image-forming material can be obtained which exhibits high sensitivity and resolution, and excellent resistance against abrasion.
|Cited Patent
|Filing date
|Publication date
|Feb 16, 1990
|Apr 28, 1992
|Toda Kogyo Corp.
|Composite carrier particles for electrophotography and process for producing the same
|Nov 19, 1990
|Oct 26, 1993
|Semiconductor Energy Laboratory Co., Ltd.
|Image-forming member for electrophotography and manufacturing method for the same
|Feb 9, 1996
|Nov 25, 1997
|Konica Corporation
|Image forming material, method of preparing the same and image forming method employing the same
|Mar 4, 1997
|Jan 5, 1999
|Konica Corporation
|Image forming material and image forming method employing the same
|Mar 28, 1985
|Nov 6, 1985
|Imperial Chemical Industries Plc
|Laser-imageable assembly and process for production thereof
|May 11, 1993
|Dec 8, 1993
|AGFA-GEVAERT naamloze vennootschap
|A method for obtaining an image using a heat mode recording material
|Aug 3, 1992
|Feb 9, 1994
|AGFA-GEVAERT naamloze vennootschap
|Heat mode recording material and method for obtaining color images
|Title not available
|Title not available
|Title not available
|Title not available
|Aug 14, 1992
|Mar 4, 1993
|E.I. Du Pont De Nemours And Company
|Infra-red direct write imaging media
|EPO Patent Abstracts of Japan, Publication 61061895, Publication date: Mar. 29, 1986.
|EPO--Patent Abstracts of Japan, Publication #61061895, Publication date: Mar. 29, 1986.
|European Search Report EP 97 11 9941.
|Citing Patent
|Filing date
|Publication date
|Sep 24, 1998
|Dec 26, 2000
|Konica Corporation
|Method for forming image having protective layer thereon
|Jun 30, 2003
|Jun 13, 2006
|International Business Machines Corporation
|On-chip inductor with magnetic core
|Apr 7, 2006
|Sep 18, 2007
|International Business Machines Corporation
|On-chip inductor with magnetic core
|Jun 30, 2003
|Dec 30, 2004
|International Business Machines Corporation
|On-chip inductor with magnetic core
|Apr 7, 2006
|Aug 24, 2006
|International Business Machines Corporation
|On-chip inductor with magnetic core
|U.S. Classification
|430/262, 430/273.1, 430/263, 430/270.1
|International Classification
|Cooperative Classification
|European Classification
|Nov 13, 1997
Owner name: KONICA CORPORATION, JAPAN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SUGITANI, SYOUICHI;REEL/FRAME:008887/0279
Effective date: 19971104
|Nov 26, 2003
|Maintenance fee reminder mailed
|May 10, 2004
|Lapse for failure to pay maintenance fees
|Jul 6, 2004
|Expired due to failure to pay maintenance fee
Effective date: 20040509


text:
[Video] Numark Orbit Unboxing & First Impressions
By djblaze | 3 years ago
The Numark Orbit DJ controller was announced earlier this year at NAMM 2013 and we've finally got one in the DJbooth.net Lab for a full out review. The Numark Orbit is very small and compact with rubberized performance-style multi-color-backlit pads on each side to control different DJ software functions, a jog wheel in the center, and accelerometers inside for motion sensor style control. DJ's can perform with the Orbit via USB port (connected to a computer which also charges the unit) or wirelessly on the dancefloor with the crowd. The full review will be completed shortly, but check out the unboxing and first impressions video below to see what comes in the box...
Get The PLUG app by DJBooth and get the best hip-hop writing and news delivered daily.
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subset: commoncrawl


text:
September 6, 2010 | by Sarah.M | Breaking News, Entertainment
(No Ratings Yet)
In the world of scary, freak accidents today, Mike Edwards, a founding member of '70s band Electric Light Orchestra, aka ELO, was killed after a giant bale of hay tumbled down a hill and crashed into his van. The gigantic, 1,323 pound hay bale rolled down a steep field in Devon, southern England, smashed through a hedge and careered on to the road, killing him instantly.
Mike Edwards lived in England and was in the band from 1972 – 1975, playing the cello.
Tags: Breaking News, cellist, electric light orchestra, elo, freak accident, hay bale, US News, World News
Related Posts
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1 Comment
This it totally bizarre. What a crazy freak accident!


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Media priorities right now - 1. Odd-Even 2. Lodha committee 3. Saas bahu 4. Pathankot attack 5. Consulate attack . . . 20. NE earthquake...
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Colombo Skyline
Colombo is the former capital and largest city of Sri Lanka. As the city possesses a natural harbour, it was known to Romans, Arabs, and Chinese traders over 2,000 years ago. Although the British captured Colombo in 1796, it remained a British military outpost until the Kandyan Kingdom was ceded to them in 1815 and they made Colombo the capital of their newly created crown colony of Ceylon. Today more than 640,000 people live in the urban area and more than 5.5 million people live in the urban area of Colombo. This photo of the Colombo skyline has been selected as the Daily Cool Photo on Running Wolf's Rant for the 19th of December 2010.
Yesterday a photo featuring South African fans @ Supersport Park was the Daily Cool Photo on Running Wolf's Rant. Watch this space for daily updates in the Babes and Photography categories on Running Wolf's Rant. You might also want to check out the Movies, Music, Technology, Television, Opinion, Gaming and Humor categories on the blog for other posts that might interest you. Feedback is appreciated and welcome.
Latest posts by Henno Kruger (see all)
- Guardians of the Galaxy Vol. 2 teaser trailer released - October 19, 2016
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From Our Editors
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Clinique for Men Sonic System Deep Cleansing Brush
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ABORTION REFORM: The new tokenism
1970 · Berkeley CA
by CISLER, Lucinda
Berkeley CA: Ramparts Magazine, 1970. Article cut from the magazine. Seven pages, in the magazine cover. VG. (Inventory #: 56204)
by BARBARO, FrancescoParis : Vaenundantur in aedibus Ascensianis , June 2, 1514
by PIGNORIA, LorenzoAugsburg : [C. Daberholtzer for Marcus Welser] At the sign of the Pine , 1613
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text: 15KiB, 328x381, helookslikehim.jpg View SameGoogleiqdbSauceNAO Anonymous Fri 22 Feb 20:52:00 2008 No.9790200 ViewReplyOriginalReport Quoted By: Seriously. Why is he so Mickey Mouse in appearence? Subject Name E-mail Password You might be a bot! Enter a reCAPTCHA to continue. Solution Get another CAPTCHA Get an audio CAPTCHA Get an image CAPTCHA Help


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Product Features:
Condition: brand new
A great way to carrying baby, keep kids close and safe at hands, in crowds, or during family outings. Convenient for you to take care of baby when go shopping, travelling, walking or other outdoor activities. It is also can used inside car as a baby seat cushion. Portable, Breathable, Folding, really Practical!
Material: nylon and plastic buckle
Suitable for babies from approx. 3 to 24 months, weight < 12kg
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Two way carrying position including against chest way and kangaroo style way
Sturdy, adjustable side buckles for quick, one-hand release
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More padding to give greater head and back support
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When the child is older and his/her neck stronger, the head support can be folded down so that the child can be carried facing forward and have a look around
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(Note: PLEASE NOTE that due lighting effects, monitor's brightness / contrast settings etc, it could be some minor differences in the hue of the images and the actual position!)
PLS check the carrier and its fittings before application
It is suitable for the baby of 3-24 months old with the weight not heavy than 12kg. Never use for the little infant that cannot raise its head by itself
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Stock No: 1246.1 , 1245.1
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|Bulk SMS software download
|Date added:
|25 September, 2011
|Editor rating:
Bulk SMS Software Download efficiently sends text message to individual contact numbers or group of contacts in smaller amount of time. Flexible text messaging software for GSM cell phone comes with advanced delay delivery option while sending SMS.Advertisements
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Jewellery For Her
Michael John Jewelry
Stelle Verde black opal necklace
$ 27,000
Known for their intriguing iridescence, opals come in many different colours, from mysterious black to fiery orange. Browse our edit of opal necklaces for an entrancing introduction to this unique gemstone.
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text: These New Posters Make Your Favorite Scifi Movies Look Better Than EverGermain Lussier9/12/16 9:00pmFiled to: This Is AwesomeCraig Drakehero complex galleryGhostbustersBatmanEx MachinaThe ShiningScott PilgrimBig Trouble in Little ChinaA Clockwork OrangemoviesartposterScott Pilgrim Vs. The World9337EditPromoteDismissUndismissHideShare to KinjaToggle Conversation toolsGo to permalink Where can you see Ghostbusters, Batman, Ex Machina, Clockwork Orange, The Shining, Scott Pilgrim, Big Trouble in Little China, and Alien all at the same time? At Craig Drake's latest show at the Hero Complex Gallery, or right here. Advertisement This past weekend, the artist opened his third solo show with art from those properties and more, and it was a beautiful thing. The entrance had themed drinks and lighting to match Ex Machina's dance scene. Inside, not only were there posters, but posters illuminated with LEDs that made them look like televisions. Original paintings and foil variants were everywhere and, in the back, a real life 1966 Batmobile.When we wrote about the show last week, everything was a mystery. Now that mystery has been revealed, and here's all the art in the show. These works speak for themselves. Many of those pieces are available in multiple formats and are still available to purchase. Head to Hero Complex Gallery to do that, and get instructions to head there and see it yourself.Germain email@example.com@GermainLussierEntertainment Reporter for io9/GizmodoMore Awesome Pop Culture ArtThis Voltron Art Gallery Is the Perfect Way to Prepare for the New Netflix ShowThese Hayao Miyazaki-Inspired Art Pieces Are as Beautiful as the Films ThemselvesThe Absolute Coolest Pop Culture Art of 2015Gear from Kinja DealsYour Five Nominations For Best Gaming MousepadYour Top Five Picks For Best Gaming Headset (2016)Save $13 On the Bluetooth-Enabled Xbox One S ControllerReply93 repliesLeave a reply


text:
Question about Philips Magnavox Learning Universal Remote
Posted by stepcan on
i have a smasung tv and i don't have the codes dcan you help me
JVC 27" screen. Trying with remote code search button to find one for this T.V.,red button flashing on remote,stopped,T.V. turned off,can,t turn it on again,manually or otherwise. Where did I, screw up?
My remote says nothing about Magnavox,only PHILIPS universal
inside battery compartment are the # CL034 on one side,14/07 on the other
Call philips customer service center they are open on saturdays
919 573 7854 starting noon easter time.........i thought my model was cl034 however its PM435s. Hope this helps, i help me Thank God
Good luck
Posted on Dec 15, 2007
Wow, I ran into the same problem and could not find my manual. There was NO HELP on line, so I searched all over my place and found the manual. I even have a GE, too. Here are the codes:
0704, 0312, 0018, 0002, 0502, 0006, 0007, 0060, 0835, 0901, 0114, 0103, 0803, 0806, 0310
Also, the manual does not provide and URL's but give the following number for help with setup: 919-573-7854
Posted on Nov 02, 2007
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|By Marketwired .
Article Rating:
|December 6, 2012 05:45 PM EST
SACRAMENTO, CA -- (Marketwire) -- 12/06/12 -- RagingWire Data Centers, the nation's premier data center provider, announced today that after completing a benchmark Net Promoter Score (NPS) survey, the company has received a Net Promoter Score of +59 -- the highest NPS in the data center industry. Additionally, RagingWire's NPS of +59 is significantly above the national average of +23 across all industries.
"As a company, the RagingWire culture is grounded in delivering a world-class customer experience," said George Macricostas, RagingWire's founder and CEO. "Over the last 12-years, we have built our business with a singular focus on the needs of our customers. Our industry-leading Net Promoter Score demonstrates to our customers and our employees that we are on the right path and validates that the RagingWire experience is highly valued."
RagingWire's NPS program was administered by Satmetrix, co-developer of the NPS program and a recognized leader in implementing the NPS customer loyalty program. NPS is based on asking one simple question -- How likely is it that you would recommend [your company] to a friend or colleague? The NPS scale ranges from -100 to +100 and is calculated by subtracting the percentage of survey respondents that had an unfavorable customer experience ("detractors") from the percentage of respondents that have a favorable customer experience ("promoters") and disregarding the neutral respondents. The NPS program focuses on customer experience instead of customer satisfaction, reasoning that the net sum of a customer's positive and negative experiences with a provider are more likely to influence their loyalty to that provider.
"We couldn't be happier with our experience as a RagingWire customer," said Steve Paul, director of engineering at NetSol Technologies (NASDAQ: NTWK). "Our data center installation was hassle-free, and we really feel like the entire RagingWire team is behind us each step of the way -- they go way beyond the usual 24x7 help desk and give us one-on-one customer care."
Since its inception in 2000, RagingWire has been dedicated to a process-driven approach to customer satisfaction and loyalty. From 2000-2010, RagingWire's proprietary customer satisfaction program consistently garnered 95-97% customer satisfaction scores on questions regarding overall satisfaction and probability to positively recommend RagingWire to others. In 2011, our customer retention rate was 98%, with many customers choosing to expand their colocation footprints inside RagingWire data centers over the course of the year. That customer expansion fueled RagingWire's success at its newest data center in Ashburn, Virginia and enabled an expanded wholesale colocation product announced in late November 2012.
About RagingWire Data Centers
RagingWire designs, builds, and operates mission-critical data centers that deliver high-density power and 100% availability. The company has 650,000 square feet of critical data center infrastructure at its campuses in Northern California and Ashburn, Virginia and the highest customer loyalty scores in the industry. Their patented power delivery system and EPA ENERGY STAR rated facilities lead the data center market in reliability and efficiency. With flexible colocation solutions for retail and wholesale buyers, a carrier neutral philosophy, and unmatched customer service, RagingWire meets the needs of top enterprise, Internet, and government organizations. More information is available at http://www.ragingwire.com.
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In past @ThingsExpo presentations, Joseph di Paolantonio has explored how various Internet of Things (IoT) and data management and analytics (DMA) solution spaces will come together as sensor analytics ecosystems. This year, in his session at @ThingsExpo, Joseph di Paolantonio from DataArchon, will be adding the numerous Transportation areas, from autonomous vehicles to "Uber for containers." While IoT data in any one area of Transportation will have a huge impact in that area, combining sensor...
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In the next five to ten years, millions, if not billions of things will become smarter. This smartness goes beyond connected things in our homes like the fridge, thermostat and fancy lighting, and into heavily regulated industries including aerospace, pharmaceutical/medical devices and energy. "Smartness" will embed itself within individual products that are part of our daily lives. We will engage with smart products - learning from them, informing them, and communicating with them. Smart produc...
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More and more brands have jumped on the IoT bandwagon. We have an excess of wearables – activity trackers, smartwatches, smart glasses and sneakers, and more that track seemingly endless datapoints. However, most consumers have no idea what "IoT" means. Creating more wearables that track data shouldn't be the aim of brands; delivering meaningful, tangible relevance to their users should be. We're in a period in which the IoT pendulum is still swinging. Initially, it swung toward "smart for smar...
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In his keynote at 19th Cloud Expo, Sheng Liang, co-founder and CEO of Rancher Labs, will discuss the technological advances and new business opportunities created by the rapid adoption of containers. With the success of Amazon Web Services (AWS) and various open source technologies used to build private clouds, cloud computing has become an essential component of IT strategy. However, users continue to face challenges in implementing clouds, as older technologies evolve and newer ones like Docke...
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In his keynote at 18th Cloud Expo, Andrew Keys, Co-Founder of ConsenSys Enterprise, provided an overview of the evolution of the Internet and the Database and the future of their combination – the Blockchain. Andrew Keys is Co-Founder of ConsenSys Enterprise. He comes to ConsenSys Enterprise with capital markets, technology and entrepreneurial experience. Previously, he worked for UBS investment bank in equities analysis. Later, he was responsible for the creation and distribution of life sett...
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The Internet of Things (IoT), in all its myriad manifestations, has great potential. Much of that potential comes from the evolving data management and analytic (DMA) technologies and processes that allow us to gain insight from all of the IoT data that can be generated and gathered. This potential may never be met as those data sets are tied to specific industry verticals and single markets, with no clear way to use IoT data and sensor analytics to fulfill the hype being given the IoT today.
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text:
Clockwise Pictures
Graphic Designer - Book Designer
Deskripsi Pekerjaan
Job Description :
- Photo retouching
- Book lay out design
- Production design
Requirements :
- Age 22 - 27 years old
- D3/S1 Graphic Design or Visual Comm
- Good at photoshop
- Good taste in art and designs
- Able to operate other graphic softwares (freehand, illustrator) is a plus
- Organised person, good team player and trustworthy
- Minimum 1 year of experience or fresh graduate
Ke halaman yang merekrut lowongan ini
Data pekerjaan
|DKI Jakarta
|Seni / Desain / Fesyen
Deskripsi Perusahaan
Clockwise Pictures ( PT Timero Media) A growing photography & films company located in Jakarta.
There are many different ways how someone can be seen through pictures. When we look back at those pictures, and we instantly see number of obvious things, about how they look, what they do, what they wear, where and when. And through pictures, we can also learn the kind of relationship people have with others, their personalities, the emotion, the charm etc.
Clockwise Pictures works on these very basic elements. We won't change your style just to excite the pictures. 'Be yourself' is the best thing to do. Our pictures will show you how unique you are and they will last for many years to come. We love perfection and give great attention to details. So may it be your pre-wedding portraits or video, family portraits, wedding day pictures or your birthday pictures, we will deliver what's best for you.
Ke halaman yang merekrut lowongan ini
lowongan kerja rekomendasi
Graphic Designer
Graphic Designer
Image Editor (Day Shift & Night Shift)
Graphic Designer
Graphic Designer
- baru
Graphic Designer (Meruya)
Desain Grafis


text:
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Date: 1897 ca.
Description: Elevated view of the University of Wisconsin-Madison's North Hall. The city of Madison and Lake Monona are visible in the background.
Date: 1885 ca.
Description: A view of Lake Monona from the Capitol building, looking down King Street.
Date: 1890 ca.
Description: Advertisement for The Steam Yacht "Mendota." At the top is an engraving of the steam yacht under way loaded with passengers, and below is text. Some of the...
Date: 1885-08-28
Description: Sketch of the shack from which Benedict Goldenberger sold cider vinegar. Possibly on Murray Street.
Date: 1856
Description: Quarter-length oval portrait of J.P. Dickson. He was born in Danville, Caledonia county, Vermont. Dickson emigrated to Wisconsin on June 20th, 1836, and r...
Date: 1877
Description: Head and shoulders portrait of Benjamin Butts, which was part of a composite portrait of Officers, Clerks and Employees of the Wisconsin Assembly. He worke...
Date: 1872 ca.
Description: A lithograph of the layout of Hooley's Opera House.
Date: 1876 ca.
Description: Four men in front of tent in the woods. There is a man with a hatchet next to a clothesline between two trees. This is a Centennial encampment on the shore...
Date: 1855-12-02
Description: The Capital House bill of fare for Sunday, December 2, 1855. Proprietors were Nelson & Russell.
Date: 1898 ca.
Description: View from outdoors of a woman, Mrs. Zimmerman, standing indoors at an open window tending to plants that grow in a window box.
Date: 1887 ca.
Description: View across Park Street towards the northwest of the new Science Hall, shortly after its completion on the University of Wisconsin-Madison campus. Part of...
Date: 1877 ca.
Description: In the distance, women stand in front of the Norwegian Lutheran Seminary. On the right is an octagonal outbuilding, possibly a carriage house. The seminary...
Date: 1842
Description: Shooting of Charles C.P. Arndt by James Vineyard in the territorial council chamber of the legislature. This depiction of the event was created by the staf...
Date: 1885-08-07
Description: House on rock outcropping. The house has two chimneys and is two stories high with porch at left, three windows on first story, one visible on second story...
Date: 1898
Description: The James Duane Doty residence on Doty Street (formerly Clymer Street), the first "Executive Mansion" in Madison, occupied in 1841-1844 by the Territorial...
Date: 1865
Description: Composite photograph of the Wisconsin Assembly.
Description: Quarter-length oval portrait of Darwin Clark. He was born in Otsego County, New York, in 1812, and came to Wisconsin in May of 1836. Clark served as mayo...
Date: 1882 ca.
Description: View of Science Hall on the University of Wisconsin Madison campus from the southwest.
Description: Quarter-length oval portrait of James H. Earnest. He was born in Simpson County, Kentucky, on January 11, 1818. On September 3, 1836, Earnest came to Shu...
Date: 1899-05
Description: A student studies in his dorm room.
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text:
Arthur Series by Marc Brown
In this Arthur book series word search worksheet, students locate the 12 names listed in the puzzle and circle them to solve the word puzzle.
Pre-K - 2nd English Language Arts 3 Views 10 Downloads
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Picture It In Syllables
Developing fluency in young readers is a long and difficult journey. This series of eight activities adds a little fun to the process as children play matching and board games, piece together puzzles, and make flip books. Covering a...
K - 4th English Language Arts CCSS: Adaptable
I Can Read! Sight Words Set #6
Master the sight words big, said, come, and in with a packet of helpful reading activities. Kids work on their reading skills with tracing pages and bingo activities, as well as flash cards, connect-the-dots, and a short word search.
K - 2nd English Language Arts CCSS: Adaptable
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Language Lessons Including Composition and Inductive Grammar
Written by J G Park
Illustrated by
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Delivery time approx. 1 week
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J G Park
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text:
News : Threat to 200 Jobs at Belfast Call Centre
Belfast, Northern Ireland, Oct 27, 2015 -- Around 200 jobs are under threat at an Indian call centre company based in Belfast city centre.
Staff at Tech Mahindra were told of the news on Monday afternoon.
It is understood that the company has lost a contract with EE.
The firm which is based in the BT Tower in Lanyon Place was established in Northern Ireland in 2007.
Posted by Veronica Silva Cusi, news correspondent
Source: http://www.u.tv
Today's Tip of the Day - All Customer Touchpoints Need To Provide Service
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More Editorial From TechMahindra
- Tech Mahindra Recognised as a World Leader for Corporate Action on Climate Change
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- Tech Mahindra Acquires Digital Change Agents: The BIO Agency
About TechMahindra:
Tech Mahindra is a leading provider of solutions and services to the telecommunications industry with a majority stake owned by Mahindra & Mahindra Limited, in partnership with British Telecommunications plc.
Published: Thursday, October 29, 2015
Industry Champion Award Leaderboard
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Regions with the largest quantity of vacancies related to 'Executive Instrumentation' are Maharashtra, Karnataka, Tamil Nadu, Telangana, Haryana or Gujarat. Cities with the highest number of search are Bangalore, Mumbai, Pune, Chennai, Hyderabad or New Delhi.
Top employers offering Executive Instrumentation jobs
Employers posting the most Executive Instrumentation-related jobs are Prime Focus Pvt Ltd, ZAPBUILD TECHNOLOGIES PVT LTD, IT MNC Client, SKP e-Solutions Pvt. Ltd., ABHIBUS Services (India) Pvt Ltd. or Recruise.
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Neuvoo India is the biggest job aggregator in the country with over 1766123 job vacancies available, 1,163 of which are Executive Instrumentation-related.Show more...
Ambavaram, Andhra Pradesh
- 15d ago
FDA audits will be an added advantage. Required Experience. B. E. B.Tech in Instrumentation Engineering... in Instrumentation with Minimum 3 4 years experience in a reputed Pharmaceutical company...
AP Management Consultants |
Hyderabad, Telangana
- 8d ago
Hands on Experience on of followings on Instrumentation. 1. Well versed with programming Siemens S7 PLC. 2. Drives (VFD). 3. Process automation. 4. HT. Breakers up to 33KV. 5. Knowledge in servo...
Innovative Placement |
Aurangabad, Maharashtra
- 14d ago
Qualification. B.Tech. B.E. Electronics Telecommunication, B.Tech. B.E. Instrumentation, ,. Overview. Maintenance of control system like PLC, SCADA, DCS, etc. Maintenance of field instruments...
Pfizer |
Chennai, Tamil Nadu
- 15h ago
Responsibilities. M.Sc. , Analytical Chemistry with over 3. 7 years of Experience preferably in Pharma GMP Industry. Analytical method Development. Analytical method validation for...
AP Management Consultants Pvt Ltd |
(Unspecified city), Telangana
- 8d ago
Hands on Experience on of followings on Instrumentation. 1. Well versed with programming Siemens S7 PLC. 2. Drives (VFD). 3. Process automation. 4. HT. Breakers up to 33KV. 5. Knowledge in servo...
GN Associate |
Rudrapur, Uttarakhand
- 1d ago
Job Description. Exposure of handling the instrumentation breakdown. Industrial Automation and... . Computer skills Windows and MS Office Suite. Education UG. B.Tech B.E. Instrumentation. Doctorate...
Unique Consultancy & Management |
Ghaziabad, Uttar Pradesh
- 15d ago
Diploma in Electronics. Instrumentation with. He Should have 1 3 Years of Experience in Process Industry... Key Skills Instrumentation Engineer. Instrumentation Power Plant. Instrumentation Executive...
United States Pharmacopeia-India (P) Limited |
(Unspecified city), Telangana
- 8d ago
Education. UG. B.Tech B.E. Bio Chemistry Bio Technology, Chemical, Instrumentation. PG Post Graduation... FDA audits will be an added advantage. Required Experience. B. E. B.Tech in Instrumentation Engineering...
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