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TV's Best of the Decade: No. 6 - 'Deadwood'
David Milch created TV's great Western, using Ian McShane and some filthy language
When "Deadwood" first premiered in 2004, I remember that it sent critics and reporters flocking to experts on late 19th Century frontier life, trying to prove that the show's expletive-laden dialogue was inaccurate and anachronistic. The pursuit, while endearing and intellectually driven, could only get part of the story. No, the residences of the actual historical community of Deadwood probably didn't swear in quite the same way David Milch's HBO characters were swearing (i.e. with impunity, but also a modern flair), but so what? Nobody in the history of the world, regardless of their time or their location, has ever talked the way the characters on "Deadwood" talked, so why quibble over a few stray "cocksuckers"?
Although it only aired for three seasons, "Deadwood" put what may be the punctuation mark on one of television's most venerable genres. After watching "Deadwood," is it honestly possible to go back and watch "Bonanza" or "Gunsmoke" or even "Have Gun - Will Travel" as anything other than quaint curios? And what would one gain from trying to make another Western for at least a respectful period? I think we should be ready to go back to the frontier again by 2015, but even then, whichever showrunner attempts the task had better have a very clear purpose.
Coming in at No. 6 on my list of TV's Best of the Decade, and very possibly deserving of a Top Five slot (no arguments here) is HBO's "Deadwood."
More after the break...
Set in a South Dakota camp-town starting in 1876, "Deadwood" focused on nothing less than the ongoing clash between civilization and savagery in the American Way of Life, the contrasting desires between law and order and structure and sheer capitalist anarchy. What does humanity look like without regulation and boundaries? It looks a little bit like Deadwood, a community run, in fact if not in official dictate, by bloodthirsty saloon owner Al Swearengen with an authority first challenged by Timothy Olyphant's Seth Bullock, but eventually by other business interests and finally by that most powerful of adversaries, the United States of America and nothing less than Manifest Destiny.
The run of "Deadwood" was brief. The show's first season was superb. The show's second season elevated it to a place as possibly TV's best drama -- and in 2005, that actually meant something. An otherwise excellent third season, using no less than George Hearst (Gerald McRaney) as an adversary, seemed to fall a little flat, with a short (49 minute) finale that wasn't even written by David Milch (well, except in the sense that ever "Deadwood" episode was written by Milch, which they all kinda were). It wasn't a bad finale. In fact, with Statehood looming, it was an appropriate finale. But it was also a finale that seemed to require some kind of topper, but a fourth season was ruled out and a series of HBO original movies, initially set up as an inevitability, never materialized and that window has now presumably closed. Instead, viewers got "John From Cincinnati."
As a writer, Aaron Sorkin is a smart guy. He likes to throw out concepts, Latin phrases and lyrics from operettas and have the characters explain to each other the things they don't understand. It's a smidge condescending, but it's also fun and intellectually proprietary, so much so that when I use a phrase like "post hoc ergo propter hoc" or quote from Gilbert and Sullivan, people inevitably assume I'm referencing an Aaron Sorkin script.
I mention Sorkin only to make this contrast: As a writer, David Milch is a brilliant guy and in "Deadwood," he refused to hold the audience's hand. In "Deadwood," not only do the characters speak in a twisted prose that's entirely of Milch's designing -- part Shakespeare, part actual frontier dialect, part Biblical and part Mamet, only with more swearing than any of them and when you throw Mamet into the mix, that's something of an achievement -- but they speak in the acknowledged references of the time. If you don't know about annexation law, if you can't distinguish between Native American tribes, if you don't know the racial slurs depicted at different nationalities, if you aren't aware of proper medical jargon of the day, Milch only rarely steps back to explain. It's all just woven into the dialogue and you have to keep up as best you can. Understanding anything is completely dependent upon the context.
And the context is an utter mess, literally. Deadwood is a mud pit, a sewage dump, a hole cut in the ground and filled with tents, rickety shacks and hastily constructed buildings. Every character on the show walked around caked in dirty and, for the men at least, buried under a prodigious growth of facial hair. The language of "Deadwood" was impenetrable for neophytes and the environs weren't much more welcoming. Just as I occasionally had to rewind to parse snatches of dialogue, I also sometimes needed a few episodes to distinguish between one burly bearded gentleman and the next. The "Deadwood" cast may have featured a few familiar faces, but those faces were so obscured as to blend in with the rest of the gang.
Emmy voters literally couldn't see past the grime. In 2005, reflecting the second season, "Deadwood" won an impressive five Emmys: Art direction, cinematography, costumes, hairstyling and makeup. How totally were Emmy voters unable to see what was really happening on "Deadwood"? In three seasons, Ian McShane only earned one Emmy nomination and he lost that year to James Spader for "Boston Legal." One can only imagine how Al Swearengen would have responded to that. Spader, in fact, won all three of the Emmys McShane would have been eligible for, one of those black marks that makes you wonder why we bother covering the Emmys at all. Fortunately, the Television Critics Association gave McShane an award for Individual Achievement in Drama, a vote that earned us a place on the grateful actor's Christmas card list for several years. Yes, I still have the cards.
It's a vote that McShane earned by taking HBO's tradition of fearsome anti-heroes and pushing it past the realm of "Oz" and "The Sopranos" and even "The Wire." Swearengen was a far more effective sociopath than Tony Soprano or Omar Little or Simon Adebisi because he had legitimate institutional power. Swearengen would slit your throat, shoot you or feed you to the pigs without hesitation, but he'd be just as able to greet visiting officials and dignitaries with a rhetorical flourish and a free drink at the Gem, just as adroit shepherding prostitutes as conning a gentleman. It was the part of a lifetime for McShane and although he's gotten some good work out of it (showing a few similar colors in "Kings") and some dismal paycheck work out of it ("Death Race" couldn't possibly have felt good), it will be quite a shock if he finds anything of similar quality until its his turn to play King Lear at the National Theatre [within five years, one would have to guess]. McShane was made for Milch's twisted prose and when Swearengen had to suffer infirmities -- the second season arc with the gleet was excruciating -- McShane nailed the physicality as well.
Going back to awards for a second, I often complain that for a group of actors, the Screen Actors Guild is sorely ignorant regarding what constitutes an acting "ensemble." Case in point: One "Deadwood" ensemble nomination in three eligible years. It's an offensive snub because it's almost impossible to imagine how one could list every member of the "Deadwood" ensemble, every veteran character actor who suddenly found themselves with the parts of a lifetime. We're talking about long-term regulars like (in alphabetical order, for the sake of simplicity) Jim Beaver, Powers Boothe, Sean Bridgers, W. Earl Brown, Dayton Callie, Kim Dickens, Brad Dourif, Zach Grenier, John Hawkes, Ricky Jay, Geri Jewell, Jeffrey Jones, Paula Malcomson, Molly Parker, Ralph Richeson, Leon Rippy, William Sanderson, Brent Sexton, Keone Young, Robin Weigert and Titus Welliver. But we're also talking about short-timers like Ray McKinnon, Franklyn Ajaye, Stephen Tobolowsky, Sarah Paulson and Brian Cox, plus the incomparable Keith Carradine, Gerald McRaney and Garret Dillahunt, who earned a permanent place on list of acting favorites by playing two very different characters in the first and third seasons.
And that makes no mention of Timothy Olyphant, who was the show's ostensible star, always able to find new shadings of teeth-gritting determination. As melancholy as it must have been for McShane to find a career capping role at 62, try being Olyphant, who will be playing what looks to be a variation on Seth Bullock in FX's upcoming "Justified," after picking up a slew of paychecks in movies like "Life Free or Die Hard," "Hitman" and the upcoming "The Crazies."
I mentioned Bullock as the hero and Swearengen as the anti-hero, but "Deadwood" intentionally subverted the traditional black-hat/white-hat moral simplicity of the Western genre. No, this was not a Milch innovation. I require no convincing there. John Ford had been doing it back on "The Searchers" and "The Man Who Shot Liberty Valance." Howard Hawks did it on "Red River" and "Rio Bravo." And Clint Eastwood basically built his career on defining and redefining the conventions of the Western. But even an "Unforgiven" or something like Kevin Costner's underrated "Open Range" comes up short of capturing the murky morality that "Deadwood" trafficked in. That's the advantage of doing 36 hours, rather than two. Within 45 minutes, Swearengen and Bullock were mortal enemies, but as the series progressed, they were able to come together as allies and then split apart, depending on the new threats to life in Deadwood. It was telling that in Season Three, George Hearst, recognized by history as a titan of industry and a future Senator, would be presented as the ultimate villain.
On "Deadwood," America meant Statehood and Statehood meant restrictions and in the town of Deadwood, restrictions were met with only slightly more concern than evident signs of culture. In the series, we saw the idea of the free press in Deadwood (though Jones' A.W. Merrick), the idea of elections (Sanderson's work as E.B. Farnum ranks among my five favorite "Deadwood" performances) and even theater, with Cox's Langrishe arriving in town for the third season, one of several plotlines that never quite got the payoff it deserved. But the press and democracy and the arts were all greeted with distrust or skepticism.
Maybe it's appropriate that an anti-authoritarian show like "Deadwood" didn't get the sort of closure that The Man would try to tell you that TV shows need. Maybe we should relish its idiosyncratic resolution and stop pining for those TV movies that'll never come.
Even without them, "Deadwood" stands at No. 6 on my list of TV's Best of the Decade.
Coming up tomorrow? A likable killer, a man who serves two bosses and a fresh piney scent.
A full explanation of the parameters for this list.


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The National Institutes of Health (NIH) have initiated a series of consensus development exercises that will take place during 1978 and 1979. The major purpose of these exercises or conferences is to make useful new knowledge concerning the prevention, detection, diagnosis, and treatment of major disease entities available to practicing physicians. In the normal course of events, a substantial time lag occurs between the development of new, valid information by the research community and its widespread application in the provision of medical care. In large measure, this delay is the result of a slow diffusion process that relies on medical journals, professional meetings, courses, textbooks, and interpersonal contacts and lacks, therefore, planned promotional guidance. Consequently some new interventions for the treatment of disease are applied too slowly while others may actually be used prematurely.
The consensus development conferences will bring together experts in a specific field for the purpose of
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Firefighters Fall 5K & 8K
218 W. Jefferson St.
Madison, GA 30650
Join us for an annual fall run through one of Georgia's premier historic districts, benefiting Madison's volunteer fire department. The course is an out and back - very fast, and run entirely on paved roads - through beautifully landscaped neighborhoods. You'll forget you're even running when you're amidst one of the "Top 16 Most Picturesque Villages in the World!"
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Saturday: 7:00AM - 11:00AM
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Admission $20
General Information
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Group-friendly, Motorcoach-friendly
Near Interstate Highway
20, 285, 75, 85
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North Hills Lawn Care Company | Lawn Maintenance | Landscapers in Pittsburgh
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Questions for the dining critic? Now's the time to ask
Journal Sentinel dining critic Carol Deptolla will answer your questions about the local dining scene in a noon chat. Share your good or bad restaurant experiences, questions, recommendations or changes you've noticed while dining out and she'll respond during the chat.
Submit your question here, and check back during the lunch hour to see her response. »Read Full Article
Alchemist Theatre's 'King Lear' reigns as family drama
Early in Friday's opening-night performance of Alchemist Theatre's "King Lear," Bo Johnson's aged king called for the map demonstrating his intended division of Britain among his three daughters. Lear's attendants dutifully unfurled it — with the bottom at the top and the top at the bottom. When they tried to hang the map up, it kept falling down.
Director Leda Hoffmann confirmed during intermission that this sequence wasn't planned. But such a topsy-turvy world aptly illustrates the disorder that descends on Britain once the hot-tempered Lear banishes his beloved Cordelia, counting on his remaining two daughters to keep him and Britain safe. »Read Full Article
Check out interactive map of southeast Wisconsin farmers markets
Another beautiful Saturday morning — perfect farmers market weather.
Good thing there are so many of them operating on Saturdays. »Read Full Article


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Universal Fit
Noble Audio Savant
"Overview Unlike most companies, Noble choose to not overwhelm buyers with piles of specifications, preferring instead to accurately describe the sound and allow the decision to be about subjective choices which are far more relevant to the purely personal experience of enjoying music. While specifications can help make decisions sometimes they can also influence our decisions in ways that..." --Loquah
Noble Audio Kaiser K10UA universal aluminum
" I would like to Thank Noble Audio for providing me with a review sample of K10UA in exchange for my honest opinion. Manufacturer website: http://nobleaudio.com/en/shop/universal/ * click on images to expand. I would like to start this K10UA review with a quote from my Noble Savant write up posted a few months ago: "I'm pretty sure I'm gonna eat my words if I get a..." --twister6
Noble Audio Katana
"Disclaimer: This unit was sent to me by Brannan of Noble Audio for the purposes of this review. My first brush with Noble was with the K10. Prior to the K10, I was a firm believer in dynamic Drivers. For those of you that have read my previous reviews (among which are my reviews of the Savant and the K10), you would know that the K10 was really the first BA IEM that I liked enough to buy. My..." --WCDchee
Noble Audio FR
"Disclaimer The FR is a review sample sent from Noble Audio. The reviewer was compensated in the form of a ridiculously cool and form-fitting Noble Audio shirt. Introduction Despite humans having only a single pair of ears, many an audio enthusiast reading this review likely has more than one pair of headphones or IEMs. I myself am guilty of this. If pressed by family and..." --HideousPride
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"Intro: The Noble PR is one of Noble's newest set of universal IEMs, which have a cool feature that allows for you to switch between two "modes". The PR is the reference model of the new line up, the P stands for Pure, meaning it is the ultimate reference sound. "Transparent, detailed, precise. Transparency and precision are all that matters here." The R is another reference mode however it is..." --shiorisekine
Pioneer SE-CL721-K Headphones, Black/Red
"Overall I really like these IEM's, I purchased them after having tried out just about ever skull candy earbud (which are fine for the price you pay). But, I am an audiophile and my full sized gear and my car gear is just so far superior that I was really missing some decent sound where I could't use my other equipment. So, I decided to look for some good earbuds. After..." --tswmcello
Noble Audio Kaiser 10 (Universal)
"Nothing much to add that has not been said about this wonderful IEM. Just wanted to add a few lines. Pros: 1) Great sound. Wonderful mids, best mids I have had and very spacious. Works well with every genre and extremely coherent. 2) Great handiwork, very well finished product. 3) Very easy to drive and sounds good even from poor sources. Cons: (Expensive like most..." --Docterror
Pioneer Core Audio SE-CL07-K Earphones (Black)
The SE-CL07s let you get closer to your music with high performance portable audio earbuds available in assorted colors to match your personality or lifestyle. This set comes with 4 different sleeve sizes, ensuring a perfect fit into any ear canal, a 10 mm large diameter driver for great bass and improved sound quality, and the reliable Pioneer brand, ensuring lasting quality and durability....


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Each year, Oscar nominees juggle an action-packed award season dance card that has them all but commuting from one starry red carpet and black tie gala to the next.
So when it's time for the annual Academy Awards nominees luncheon, the comparatively low-key, wine-filled gathering at the Beverly Hilton in Beverly Hills is a welcome, no-stress respite, resulting in one very star-studded group picture (that included no less than 155 nominees!)
Nearly all the year's nominees – including this season's darlings Leonardo DiCaprio, Alicia Vikander, Brie Larson – showed up on Feb. 8 to raise a group toast, pick up up their official certificates of nomination and pose for a keepsake "class of 2016 photo" on a dais packed with the A-list likes of Sylvester Stallone, Lady Gaga, Jennifer Lawrence, Matt Damon and Steven Spielberg.
Here's a behind a behind-the-scenes look at the coolest lunch in town:
"Follow me!" said Jason Tremblay to his 9-year-old son, Room star, Jacob Tremblay, who sipped a Shirley Temple as the duo made their way onto the outdoor patio before the lunch began. More interested in the maraschino cherry bobbing in his drink than the A-list crowd, Jacob excitedly told his dad: "There's a cherry in it... I'm squishing all the juice out of it!"
Creed star Sylvester Stallone was a a huge hit at the luncheon and for several minutes chatted with an upbeat Dicaprio as lunch-goers were wowed by the disparate pair.
Spotlight producer Michael Sugar complimented his star Rachel McAdams on her blonde highlights before she bumped into Dicaprio, who kissed her on both cheeks before the two took their seats at assigned tables.
Descending the stairs into the ballroom, The Revenant director Alejandro G. Inarritu, fresh from his Directors Guild win on Saturday, tells a friend, "I'm tired.. I'm numb!" Soon he was engaged in a chat with Spielberg.
Spielberg and Dicaprio enjoyed an animated chat while The Martian production designer Arthur Max reminisced about Woodstock (yes, Woodstock) with his delighted table-mate Alicia Vikander, who sipped white wine.
During the lunch, Cheryl Boone Isaacs, president of the Academy of Motion Picture Arts and Sciences, gave the assembled group some advice from the podium: "Simply take a breath and relax!" Larson and Joy nominee Jennifer Lawrence caught up close to where Stallone took a moment to chat with young Tremblay before Tremblay's father snapped a personal photo of the duo. Lawrence embraced Eddie Redmayne, who did the gentlemanly thing and gave his jacket to his wife for warmth.
Oscar producer David Hill took a moment to congratulate a bashful Lady Gaga from the stage for her Super Bowl rendition of the National Anthem.
Larson and McAdams spilled their style secrets to PEOPLE as the Room star reveals, "I've been able to understand clothes and fashion better, it's a great way for me to express what's happening on the inside," adding, "so my goal with each dress that I've worn is just to try to reflect what my soul looks like, which is far more complicated than any dress could ever be."
The Spotlight actress has made the best dressed list on multiple occasions, but even she admits there were times she has been anything but. "I mean, it's always not glamorous when you go home at the end of the night like so sad and you just fall on the floor in a puddle," McAdams tells PEOPLE. "It's so fun, but you really do feel like you turn into a pumpkin – go from Cinderella to a pumpkin – in the best way. I shouldn't say this out loud because Elie Saab might kill me, but I had a great photo shoot with my sister's Chihuahua on the dress after the SAG Awards with the SAG Award."
Another style standout is Danish Girl's Vikander, who has been soaking in her first awards season as an Oscar nominee. "I think I kind of just learned by watching him," she says to PEOPLE about advice she's received from costar Redmayne. "He said try to enjoy it because it is pretty wonderful and that's actually what I'm trying to do and then I've also been shooting at the same time over the last four months on a film and then to kind of be able to enjoy this and then go back and do the proper work and be able to really kind of balance both of them."
And no one has waited for an Oscar nomination quite as long as Stallone. Forty years since his first nomination, the Creed star "never thought [he] would be able to cross this threshold again."
Adds Stallone, "It was wonderful in 1976--that was a minor miracle – but as I get older I realize miracles begin to diminish longer in the tunnel keeps getting longer and the opportunities tend to shrink proportionate to the amount of time that you have left, so bluntly I couldn't be more thrilled in the fact that my daughters actually look at me now as an actor and not a bad golfer."
Watch the 88th Academy Awards on Feb. 28 at 7 ET/4 PT on ABC, and stay tuned to PEOPLE for full Oscars coverage.
Reporting by NICOLE SANDS AND KARA WARNER


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|Visiting Team
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|Wyandotte Roosevelt
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Allen Park's Page Woodhaven's Page All Volleyball StoriesOn Senior Night for the Woodhaven volleyball team, the team looked to go out on top heading into districts next week, but Allen Park had other plans. In three straight sets, the Jaguars defeated the Warriors, 25-11, 25-20, 25-16 for the sweep in Woodhaven. "We weren't looking past Woodhaven, but we felt confident coming into today," Allen Park Coach Chris Bozman said. "(We) had kind of a disappointing finish at News-Herald, and really had a good practice coming out of there." That practice really did some good for the Jaguars team as the only tie in the first set was at one point each. After that, they didn't look back. Allen Park went on five separate runs of at least three points, one being as high as six in a row. It was a strong first set for the Jaguars and Woodhaven Head Coach Dennis Yack knew it set the tone for the rest of the match. "I told my kids after the match, that first game, they took it to us and our morale was shot. We tried to get it back in Games two and three, and it was just too late." Yack said they made some adjustments on defense, and were able to slow them down, but it was too little too late. Jaguars outside hitter Alyssa LaFace dominated much of the match for the Jaguars, racking up spikes and blocks all over the floor. After jumping out to an early 7-2 lead, it seemed like the Warriors were a bit surprised by the fast start from Allen Park. They were able to find some points here and there, even racking up three in a row near the end of the first set, but a strong start from the Jaguars was too much. The second set was much more manageable for the Warriors. They jumped out to a quick 4-0 lead, but the Jaguars clawed their way back, eventually tying the set at nine. From there, the points went back and forth, until LaFace racked up two kills in a row to take a 20-18 lead. Two more spikes by the Jaguars put them up 24-19 a few points later, and finally one more sealed it, but not before one more Warrior point on a bad serve from Allen Park. Now leading 2-0, the Jaguars went in for the kill. Woodhaven, despite being down 2-0, wasn't going to go down easy. The Warriors went up 7-3 early after two aces from senior Hailey Leidel. Three points later, the Warriors were up 8-5 after Jaguar Natalie Schlesinger hit the ball out. Allen Park quickly regrouped and went on a seven-point run to take the lead, 12-8. The Warriors kept it close, getting within two points, but another five-point run near the end of the match put the Warriors away. Two straight spikes off Warrior players ended the match, and the Jaguars walked away with a 3-0 victory. On Wednesday evening the Jaguars will face off against Roosevelt, the only team to hand Allen Park a loss this season. Woodhaven will travel to Carlson to wrap up the season.
VOLLEYBALL: Jags win sets up big showdown for DRL championship
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Last Updated: 10/29/2013 9:31:44 PM EST


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Some teams, like the Philadelphia Eagles, have really awesome uniforms that really add to their image.
Other teams, like the Carolina Panthers, don't have a very good look and instead wear strange colors that make them look downright bizarre.
Here is a ranking of all 32 NFL teams' home uniforms from worst to best.


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Bryn, 5, and Ryen Mahan, 7, give a push to the pumpkin wagon being carted by their father, Jeff, while at Tigges Farms near Greeley last week. Kathy Tigges, co-owner and operator of Tigges Farms, said nice weather in October has helped attendance numbers stay on par so this year compared to previous years. During October, activity at local pumpkin patches and corn mazes is in full swing. In addition to Tigges Farms, there are three other pumpkin patches and/or corn mazes in Weld County, according to the Colorado Department of Agriculture's list; Fritzler Corn Maze near LaSalle, Miller Farms near Platteville and Anderson Farms near Erie.
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France and Switzerland make peace in the Treaty of Geneva. This allows the Swiss to retain most of their Alpine passes, and grants them a subsidy, while in return the French gain the right to enlist Swiss mercenary soldiers.
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Norfolk marketing agency – bringing your business to life
Example Marketing and Web Design is a small agency based in Norfolk. Our aim is to help local businesses grow by reaching the right people with the right messages at the right time. We can support you as much or as little as you need, from full management of all your marketing activity to designing a simple advert. We'll listen to what you want to achieve and make it happen.
You can find out more about the services we offer on this site. Alternatively, give us a call for a chat – we're happy to come and meet you for an initial consultation at no cost.


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2014/15 New year skiing in the Alps
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BPL11 CONCERT: Hot Tuna (Part 6)
Andy Timmons Song Premiere! Be the First to Hear "Winterland"
Mitchell Launches New Line of Electric Guitars and Basses
Blake Shelton Catches Fan's Bra on His Guitar, Stops Show
Waves Audio Introduces SoundGrid Connect
TELEFUNKEN Debuts New Direct Box Line
Focusrite Announces Red 8Pre Interface
PreSonus Ships StudioLive RML-series Rack-Mount Digital Mixers
Line 6 Launches New Spider V Guitar Amp Series
Animals As Leaders' Javier Reyes Premieres Eight-String Classical Guitar Piece
Metallica Premiere "Moth Into Flame" Music Video
Kvelertak Premiere Spooky New Animated Video for "Svartmesse"
The Soul Shakers Premiere New Music Video, "Here to Have a Good Time"
Live Video Footage of Metallica Performing "Moth to the Flame" for the First Time Ever
Listen: "Gratitude" from NYC Tech-Metallers Car Bomb
Slash: "This Is What Creeps Me Outâ€
Animals As Leaders' Javier Reyes Plays "Suspiro" on Eight-String Classical Guitar
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Art in View
January 5, 2012 Tour Maui's splendor — from the slopes of Haleakala to the shores of West Maui — without leaving Village Gallery in Lahaina. more »»
Best faces forward:
December 29, 2011 Fifty-nine works from 57 artists will reveal the composite face of contemporary Hawaii in the fourth triennail Schaefer Portrait Challenge in the Maui Arts & Cultural Center's Schaefer International... more »»
Art in View
December 22, 2011 Maui painter Lisa E. Kasprzycki's " 'Alala,' showcasing the critically endangered Hawaiian crow has won the People's Choice Award in the Malama Wao Akua exhibit. more »»
Big Island master ceramic artist featured in Paia
December 15, 2011 Paia Contemporary Gallery will present master ceramist Stephen Freedman of Hawaii island during its December 2011 Exhibition. The show opens with a reception from 6 to 8 p.m. more »»
Art In View
December 8, 2011 Five exceptional Maui artists —painters George Allan and Diana Lehr, woodworker Al Rabold and jewelry creators J.B. more »»
Art in View
December 1, 2011 Capture a glimpse of rare species, some threatened by extinction, during "Splendor: Portraits of the Natural World" at Haleakala National Park. more »»
Art in View
November 24, 2011 North shore will be buzzing with art demonstrations and gallery specials when Paia celebrates its Friday town party from 6 to 9 p.m. more »»
Art in View
November 17, 2011 David Schoonover was the big winner in Lahaina Arts Society's 2011 Photo Maui Awards, walking away from last Friday's awards ceremony with the competition's two highest awards — Best of Show for... more »»
'I Keia Manawa' opens at Schaefer International Gallery on Sunday
November 10, 2011 Hawaii's past, present and future will intersect at the MACC's Schaefer International Gallery during "I KEia Manawa (In This Time). more »»
Hailing Mother Nature's artwork
November 3, 2011 To celebrate the most acclaimed artist of them all — Mother Nature — the Malama Wao Akua juried exhibition each year displays works that honor Maui County's native species. more »»
Art in View
October 27, 2011 The next generation of Maui's artists will get important tools to further their future careers at the Hui No'eau Visual Arts Center's Portfolio Day, slated for 3 to 7 p.m. Wednesday, Nov. 9. more »»
Art in View
October 20, 2011 Liquids and solids come together in Jack Nordby's ocean-inspired metal pieces. more »»
Art in View
October 13, 2011 Maui Crafts Guild will feature printmaker and ceramicist Michi Itami during an exhibition through Oct. 27, opening with a reception from 6:30 to 9 p.m. Friday at the Paia galler. more »»
Art in View
October 6, 2011 Travel though photographer Amy Neurauter's exhibition of beauty that she captures locally and abroad. Neurauter's show "Transition" opened Sept. more »»
'X' marks the spot for art, history, more
September 29, 2011 Embark on an exciting voyage through time, local places and island people with "The Mapping of Hawaii," a traveling exhibit that traces the history of the Hawaiian islands through maps. more »»
Art in View
September 22, 2011 It's hard not to be drawn to the women. Expressive. Feminine. Provocative. Dynamic. The sirens of Lori Koprowski's "Femme Series" will suck you in. more »»
Art in View
September 15, 2011 Art isn't just auditory for legendary drummer Mick Fleetwood. Best-known for his lifelong contributions to rock, the Kula resident is also a visual artist who creates fine art photography. more »»
Interwoven art, community at Hui
September 8, 2011 Surely the beasts of "Where the Wild Things Are" will inhabit their new homes once they're completed at the Hui No'eau Visual Arts Center in Makawao. more »»
MACC's aloha to the art of fashion
September 1, 2011 If not for master fabric printer Alfred Shaheen, Aloha Fridays would have a lot less aloha. more »»
Art in View
August 25, 2011 The third annual Maui Photo Festival & Workshops are under way, continuing through Sunday at the Hyatt Regency Maui. more »»


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Monochromatic Style: Making It Work For You
Green living room from HGTV1. Pick a color you love. A bit obvious, but this is important in more ways than one. Not only will choosing a shade that makes your heart sing make you less likely to tire of the look, but all those forest green (or raspberry, or teal) pieces will easily find a place elsewhere in your home, if you do move on someday. 2. Let the paint do the work. Walls are the bullies of the interior design playground; they can easily team up with a sofa or chair in a similar shade and force an entire room into submission. In the blue living room above, only the walls, sofa and chair are like-colored, but the final result is unmistakably blue.
Raspberry interior by Miles Redd3. Think mostly monochrome. A space that's truly all one color would be a tad OTT, so break it up with a good dose of something neutral. This could be white ceilings, wood floors or furniture, an area rug or alternately-colored accessories. 4. Vary the textures, vary the hue. Using a variety of textures and finishes is key to making any space feel vibrant and layered, and this goes double for one with a limited palette. Think leather, glossy lacquers, plush velvets and chunky knits to alternately reflect and absorb the light. Varying the hues you choose, for example reds running the gamut from ruby to tomato, adds interest as well. Images: Top photos: Blue living room by Todd Romano via Apartment Therapy and orange bedroom from House Beautiful, Other images: as linked above in the captions -Eleanor


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From Harvard Medical School and Harvard Pilgrim Health Care, Boston, Massachusetts.
Grant Support: In part by the Robert H. Ebert, M.D., Fellowship of the Harvard Pilgrim Health Care Foundation; National Research Service Awards 2T32PE11001-06, 5T32PE11001-07, and 1F32HS00107-01; and an unrestricted grant from Consumer Value Stores, Inc.
Requests for Reprints: Maureen T. Connelly, MD, MPH, Department of Ambulatory Care and Prevention, Harvard Medical School and Harvard Pilgrim Health Care, 126 Brookline Avenue, Suite 203, Boston, MA 02215.
Current Author Addresses: Dr. Connelly: Department of Ambulatory Care and Prevention, Harvard Medical School and Harvard Pilgrim Health Care, 126 Brookline Avenue, Suite 203, Boston, MA 02215.
Ms. Ferrari: Health Publications Group at Harvard Medical School, 164 Longwood Avenue, Boston, MA 02115.
Ms. Hagen: Brown and Toland Physician Services Organization, 1388 Sutter Street, Suite 400, San Francisco, CA 94109.
Dr. Inui: Department of Ambulatory Care and Prevention, Harvard Medical School and Harvard Pilgrim Health Care, 126 Brookline Avenue, Suite 200, Boston, MA 02215.
Background: Numerous medical organizations, including the American College of Physicians, have recommended that women be counseled about postmenopausal hormone replacement therapy (HRT). patients' perspectives on their counseling needs, however, have not been integrated into most counseling guides.
Objective: To use patient self-reports to identify needs for HRT counseling.
Design: Individual, in-depth patient interviews.
Setting: Managed care organization.
Patients: 26 women who had received an initial prescription for HRT.
Measurements: Qualitative, consensus review of the content of interview transcripts.
Results: On average, women reported 15 factors (range, 6 to 24 factors) as critical to their decision-making process. Although most women cited their physician's opinion (96%), reports in the media (81%), and experiences and opinions of friends (77%) as critical to their decisions about HRT, counseling recommendations address none of these concerns.
Conclusions: Many women in a managed care organization who accepted a prescription for HRT identified counseling needs that are not included in widely used HRT guidelines.
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Aquaflex/PCMC's new ELS-Max offers a full servo press in 24", 28" and 32" widths. Able to run up to 1000 FPM, the ELS-Max offers all the features that are capable on wide-web CI presses. The ELS-Max utilizes both plate and anilox sleeves, and PCMC's own designed force loaded doctor blade chambers designed for fast, constant running with extended doctor blade life. The full gamut of drying is available with water based, UV, and solvent. The ELS-Max touts complete job storage and recall from the Rockwell control system which is standard on all PCMC wide and narrow presses.
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12 X 5280' Pacer Food Service Film Roll- ClearProduct Code: RFP996
Availability: In Stock
Reg. Price $258.70
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SHIPS IN 1-2 BUSINESS DAYS This item ships free!
Extended-length film roll delivers bang for the buck. Comes in a convenient cutter box. Use for covering, storing and wrapping. Superior cling with no snarls or tangles. Includes one roll in a cutter box.
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Krav maga prepares people to fight off real-world assailants, unlike boxing, which only prepares people to fight innocent pedestrians wearing red mittens. Be the hero with this Groupon.
Choose Between Two Options
- $29 for 5 krav maga classes (a $140 value)
- $49 for 10 krav maga classes (a $280 value)
Krav maga classes are available at four levels. Beginner sessions focus on the style's basic stances, punches, kicks, and defensive maneuvers. Higher-level classes cover more complex feats, such as defending against armed attackers or multiple attackers. For more details, see the class schedule.
Krav Maga Novi
Krav Maga Novi's instructors help their students to master the krav maga fighting style in their fitness studio, but the techniques were not designed for studio combat. They are intended for street fights—more specifically, self-defense. Krav maga's originator, Imi Lichtenfeld, was a champion wrestler and boxer, but he realized during World War II that traditional fighting styles were inadequate in unofficiated, real-world conflicts. And so he developed krav maga, which is now the official self-defense system of the Israeli armed forces. At Krav Maga Novi, however, instructors teach the style to civilians, from its basic headlocks and punches to techniques for defeating multiple attackers without first convincing them to form a conga line. Classes at the studio can also focus on specialty areas, such as ground fighting, kickboxing, and defeating opponents armed with sticks, knives, and other weapons.
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So MCR invited me to be in the beta of their new "update/upgrade" and I can invite you folks with http://CokeURL.com/wac3 because I don't have any friends who would do it probably. So far I already got to Gold level with very little effort, the max level is called Twilight *sparklesparkle*. I so far entered a sweeps for a $500 gamestop giftcard and getting Gold I was able to get a code for one month Pogo.
I can't seem to get into the Red level rewards anymore, but it's letting me back into the Gold ones - here's a CCP of it - sorry it's a mess but c'est la vie
15% Off when you Spend $40 or more at T-Shirts.com 20% Off Everything at Fanatics.com 25% off at www.Coca-Colastore.com $10 Restaurant.com® E-Gift Certificate $500 Nike® E-Gift Card Sweepstakes $500 GameStop E-Gift Card Sweepstakes


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We stayed one night at the Holiday Inn - Port of Miami. I had requested a room on a high floor with a view of the port...got exactly what I wanted! We were on the 10th floor with a great view. We watched the ships sail out that night and when we woke in the morning, our ship was there! We ate lunch and dinner at the Bayside Marketplace and did a little shopping. We also walked to Walgreens to buy some things we forgot to pack. We had the breakfast buffet at the hotel since it was included in my price...it was good. Then we were off to the port. The doorman at the hotel was very helpful in getting everyone loaded up.
Embarkation: We arrived right around 11am. The cab driver told us we were way too early...he was a little grumpy that morning. Anyway, we were dropped off, passed our luggage to the porter, and walked in the doors. We were on the ship in less than an hour. We went to check out our rooms and drop off our carry-on bags. Both cabins were ready so we dropped stuff off and went to check out the ship.
Our cabin: This was my first cruise with an OV cabin. It was great. The window became my son's favorite place to sit and play his gameboy while waiting for me to get dressed in the morning. Plenty of storage. Our cabin steward "IDA" was fantastic. He met my son in the hallway with a "high-five" and made towel animals every night. He was quick to unlock the fridge and put in some regular coke for me.
Dining: I think everything we ate was better than expected (I didn't expect much after reading several reviews). Within our group we tried the pizza, hot dogs, cheeseburgers, deli sandwiches and fish and chips. I don't believe anyone tried the oriental place. The buffet was always good and the dining room food was excellent. The kids menu in the dining room was the basic hot dogs, chicken strips, etc but our waiter "CHRISTOPHER" always got them what they wanted. (Spaghetti and Mac&Cheese weren't on the menu). He found out my son loved strawberries and my friend's son loved grapes...so every night there was a plate of strawberries and grapes at our table. CHRISTOPHER always made sure we never left hungry. He brought us lots of stuff to try. He was super with the kids! There was a magician that came to the table one night...he was just okay.
Activities: We hung out by the aft pool most of the time. It just seemed better with the kids and it was right by the grill, pizza and ice cream! The kids loved playing in the pool and my only complaint is the area around the pool...it was very slick. There were lots of people who slipped or fell. One child fell so hard he knocked himself out and was taken to the infirmary. From what I hear the main pool was different and not slick. The boys went to Camp Carnival one night for two hours... that was the extent of our break from the kids. They enjoyed it and we went to the show but the rest of the week they went to the shows with us and loved the shows! The shows were well done and I enjoyed the 80's one a lot. The singers were just okay. We missed the Legends show which is at 10:30pm on the last night. We just couldn't stay up that late with the kids so I'm sorry we missed that one.
Ports: We did the stingrays and Island Tour in Grand Cayman. Cave tubing in Belize. Just a tour of the island in Roatan. We didn't get to stop in Costa Maya...very disappointing! Oh well, guess I have to take another cruise and try it again. We enjoyed all the ports but didn't book anything through the ship. Tendering wasn't a problem, we just went to the theatre when they told us and waited until they called our letter. Belize was a rough tender but the kids thought it was fun.
Debarkation: We put our luggage out the night before and went to breakfast to wait for them to call our color. We were off the ship, got our luggage, got picked up by the limo, and I was at Ft. Lauderdale airport for my 1:00pm flight with lots of time to spare.
All in all it was a great trip! I was back to work on Monday and got busy researching my next cruise!


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Our video library provides thorough instructions on using ATU products.
All paint codes for all Acura models are located in the driver side door jam (position 1). The highlighted part displays the color code. These codes can
contain both letters, dashes, and numbers. This is a photo of a real label from an actual Honda Vehicle, but both Honda and Acura vehicles have identical
labels for the paint code. Please use the following link to find touch up paint colors for your Acura: Acura Touch Up Paint.
The paint code for this new model Acura TL is YR562PX, or YR562P.
The paint code for this older Acura Integra is NH583M.
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Framed Art Print
Skate Parkby Shalisa Photography
10% Off + Free Shipping on Everything - Ends Tonight at Midnight PT!
Choose from a variety of frame styles, colors and sizes to compliment your favorite Society6 gallery, or fine art print - made ready to hang. Fine-crafted from solid woods, premium shatterproof acrylic protects the face of the art print, while an acid free dust cover on the back provides a custom finish. All framed art prints include wall hanging hardware.
HDR textured image of Galley Hill skate park in Bexhill UK. Added Skate boarder from Wiki-commons.(by Adam J.W.C)
skate boarding,boarding, skate, skating...


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About Us
"Jane's personal attention and knowledge of the city's history is her hallmark." --Amy French, "Roaming Historian"
Welcome to On the Town!
e are a Toronto touring company that specializes in customized itineraries highlighting Toronto's architecture and culture, using a variety of transportation to suit your group and its needs, escorted by professional, knowledgeable guides. Choose from one of our exciting itineraries or let us create a unique, personalized tour to suit your interests. We can comfortably accommodate groups from 2 persons and up.
When you explore Toronto with the experts at On the Town, you will gain an understanding of Toronto's architectural, historical and cultural heritage, vibrant neighbourhoods, and the many out-of-the way places that the architect Louis Khan called "a treasury of spaces."
From company functions, to conference-goers, groups of seniors, adults, students, family reunions, clubs, and special events, we will work with you to ensure that your experience is fun-filled and unique. We know the ins and outs of Toronto, as well as the museums, restaurants, attractions, shopping, entertainment and other potential leisure activities that will make your group event fun and memorable.
Combine one of our historical, architectural or cultural excursions with a visit to one of Toronto's many exciting museums or attractions with lunch or dinner at a special restaurant. Let us know if you have any special requirements (i.e., vegetarian cuisine) or allergies and we will do our best to accommodate you. Half day and full day excursions are available.
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Walden, Newman will offer keynote presentations
Twentieth Century Fox Television chairs Dana Walden and Gary Newman will offer keynote presentations at the upcoming Banff World Media Festival.
Fest, set for June 12-15 in the Canadian Rockies, brings in broadcasters, producers and execs from the TV landscape to discuss the smallscreen biz.
"Under their leadership, TCFTV has been setting the industry standard for content creation, and these two gifted executives are known for creating some of the boldest and most innovative programming in the history of the medium," said fest director Ferne Cohen. "I'm sure all of our delegates will be eager to hear some of the secrets behind their incredible success."
Fox's recent successes include "How I Met Your Mother," "Glee" and "Modern Family."


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In the Delaware Riverkeeper v. Federal Energy Regulatory Commission (FERC) case, judges ruled that a continuous pipeline project cannot be segmented into multiple parts to avoid a comprehensive National Environmental Policy Act (NEPA) review. This is what Kinder Morgan proposed and did for its Northeast Upgrade Project.
Regulating by emergency orders gives the distinct impression that the government is wholly unprepared to deal with safe handling of ultra-hazardous oils. Maybe it's time to take a good look at what we are doing and where we are heading before creating an energy future that may be slowing national productivity, not building it.
Already, 19 companies, including Walgreens, Whole Foods, and Columbia Sportswear have committed to take action on tar sands fuel for their vehicle fleet and shipping operations. Other companies interested in taking action on tar sands have expressed confusion over the chain of custody for petroleum.
On the day that President Obama finally rejects the Keystone XL pipeline, the connection between tar sands development and climate disruption should be only one of the reasons (although it's certainly reason enough). For someone like Obama, whose first real job was as a community organizer on the south side of Chicago, the effect of the pipeline and its toxic payload on the people and communities in its path will surely also be a factor.


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June 5, 2014
Dart Transit Company over-the-road owner operators will be eligible for a mileage rate increase, effective July 1. The increase brings the loaded mileage rate up 4¢ per mile to $1.00 per mile, and the deadhead rate up 1¢ per mile to $0.91 per mile.
"Dart has operated with independent owner operators for 80 years, and throughout our company's history, we have demonstrated our dedication to owner operator success," said Dart President David Oren. "Thanks to Dart contractors' good service, we are having success working to raise shipper rates and reduce operating expenses. We continue to work to be the best place for owner operators."
Click here or more information.
Is that good? The operating cost in about $0.65 per mile that you run.that's like being a company driver.
We offer e-newsletters that deliver targeted news and information for the entire fleet industry.
The expert, Steve Carlson from Xantrex, will answer your questions
The expert, Brian Fletcher from Eaton, will answer your questions
Tech Startup Overhaul Launches Online Marketplace for Shippers
Mobile Column Lift Designed for Flexibility
Truckstop.com Offers Freight Rate Analysis Tool
Maxion Unveils MaxSmart Wheel-Mounted Sensor


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Mundine on Geale: He Won't Take The Heat, He Ain't Sh*t
Anthony Mundine has added fuel to his already simmering rivalry with Daniel Geale ahead of their much anticipated rematch on Wednesday night, declaring the IBF middleweight champion "ain't sh*t".
Mundine entered a spirited verbal spat with Geale's American promoter Gary Shaw during a media conference on Monday.
"Daniel knows it. When he steps in that ring with me, he knows he's in big trouble. Trust me," Mundine said.
"He's the same fighter as he was when he fought me the first time. He's got more experience and he's more confident, but that's all going to deflate when he's in there with me.
"He ain't going to handle the heat this time. Daniel Geale ain't sh*t."
Geale, who lost a controversial split decision when the pair first met in 2009, said Mundine was in for a rude shock if he expected to be facing the same opponent.
"If he thinks I'm the same fighter, then that is perfect. I know deep down, he knows I'm not the same fighter," Geale said.
"He's in for the biggest shock in the world if he thinks I'm the same fighter.
"Obviously if he fights as well as he talks it's going to be a great fight. I'm looking forward to it. It's going to be a tough fight but with what we've been doing in the gym, I can't see him being able to handle me now."
[QUOTE=stretchedout;12965832]I think that he will win, but I doubt that he dominates Mundine. Could be an interesting fight.[/QUOTE] You will probably be right considering their first fight. [QUOTE=El Angel;12965874]War Geale. Just because Mundine is that damn annoying.[/QUOTE] Exactly.Comment by El Angel on 01-28-2013
War Geale. Just because Mundine is that damn annoying.Comment by stretchedout on 01-28-2013
[QUOTE=ddangerous;12964805]Can't stand Mundine. I hope Geale thoroughly dominates him.[/QUOTE] I think that he will win, but I doubt that he dominates Mundine. Could be an interesting fight.Comment by ddangerous on 01-28-2013
Can't stand Mundine. I hope Geale thoroughly dominates him.Post a Comment - View More User Comments (4)


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Acer Releases Upgraded Version of C7 ChromeBook
Acer recently released the Acer C7 and now they are back at it again, this time with the Acer C710-2605 Chromebook. This affordable laptop features an 11.6 inch display will 1366 x 768 pixels and a Intel Celeron 847 1.1 GHz processor. An impressive 500GB hard drive and 4 GB of RAM, versus the 320 GB hard drive and 2 GB of RAM you get with the C7.


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This editorial discusses the US Preventive Services Task Force Recommendation on Colorectal Cancer Screening.
The US Preventive Services Task Force (USPSTF) has updated its evidence review and continues to recommend colorectal cancer (CRC) screening for persons between the ages of 50 and 75 to reduce CRC mortality.1 The USPSTF declined, however, to express a preference in screening methods, stating "Multiple screening strategies are available to choose from, with different levels of evidence to support their effectiveness, as well as unique advantages and limitations, although there are no empirical data to demonstrate that any of the reviewed strategies provide a greater net benefit."1 Nonetheless, the USPSTF evidence review offers an opportunity to compare the benefits and risks of different screening methods, which is the focus of this editorial.
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Special Collections & Archives is comprised of five units:
The SCA Reading Room (Norlin N345) is open to students, scholars and members of the general public. Due to staffing levels and a busy instruction schedule, combined with materials that are stored offsite, we ask patrons to schedule an appointment in advance to use rare works and primary sources. Please email firstname.lastname@example.com or call 303-492-6144 to schedule an appointment.
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Guitar Tuner iPhone app
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A crackdown is coming to Collingswood this summer. It's going to go down like this:
A person of interest approaches on a bicycle. Appears to be age 12. A police officer moves in quickly and issues the tween a ticket.
What did the kid get nabbed for? Wearing a bike helmet.
The ticket awards one free water ice.
Starting Friday, when school lets out for summer, borough police officers will be on the lookout for youngsters 12 and under who are doing the right thing: wearing their helmets while they ride their bicycles or scooters or while they skateboard or skate.


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15. A picture from a great night.
15. A picture from a great night.
Cafe Fashionista says
Haha! I so love that the entire restaurant formed a conga line! 🙂
Chic 'n Cheap Living says
Your smile and your friend's hands say it all! Hoping for more fun weekends soon!
Chic 'n Cheap Living
Caro says
Love it!
Charlotte says
This sounds like such a great night! And seriouslu–your smile is infectious 🙂
Andrea says
ahh great post! looks and sounds like fun!
This is so much fun!!!!
Kristy says
That looks exactly like the kind of night I'd like to be involved in!
KimBerly says
Great picture! I used to hang out at the one in uptown all the time with my friends when I was about 25. fun times.
Nikki says
That's how 21 is done right 😉
gringationcancun says
sounds like a blast! Hilarious picture
missy. says
it definitely looks like a good time in that picture. plus 2-1? that is fantastic.
Lauryn says
You can tell this was a great night, simply by seeing the looks on your faces! Great photo, and great memories I'm sure 🙂
Naomi Bulger says
Oh, I have photographs just like this. Just looking at them brings back all the happiness of those good times. Love it!
elanor, says
thanks for the comment! 🙂 and it was interesting reading about your right off the bat! i was born in minneapolis, minnesota! how ironic.


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This year there will be four catagories, something for everyone and I encourage you ALL to enter! If you have a doll to take to the final banquet, then you have a doll to enter here!
Let's have lots of eye candy to enjoy!
Catagory One
One doll dressed on theme, can include a small prop, for example Mary's little lamb, or Miss Moffets spider.
Open to everyone
Catagory Two
Diorama, one or more dolls in a setting not to exceed 2 1/2 feet wide by 3 feet long
Open to everyone
Catagory Three
Semi Professional, may have sold some items, costume either designed by you, or made by you from someone else's pattern with their permission and recognition given.
Catagory Four
Professional people who regularly sell their work, and this makes up the bulk of their income.
The final decision as to which Catagory an entry belongs rests with me.
All entries are at your own risk.
All dolls must be secure, either on a stand, sitting or similar.
Can have more than one entry. Small props allowed in every catagory.
Please include details of the doll and the character it represents, e.g. Volks Megu as Cinderella .
Any questions, please email me, firstname.lastname@example.com
Join us on iDolls, a yahoolist for organizing the convention.


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Welcome to Physical organic chemistry
The chair of Physical Organic Chemistry offers a large variety of topics combining the best of several research areas: Synthesis of precursors, modern spectroscopy and simulation with computational methods. If you are interested, please apply for master and PhD positions.
PhD and Master positions in Physical Organic Chemistry now available – if you are interested apply here!
News Highlights
Azulenylcarbenes: Rearrangements on the C11H8 Potential Energy Surface
S. Henkel, C. H. Pollok, T. Schleif, W. Sander, Chem. Eur. J. 22 (2016), 12479-12486
Four isomeric azulenylcarbenes were synthesized in argon matrices by photolysis of the corresponding diazo precursors, and the photochemistry of these carbenes was studied. The carbenes and their rearranged products were characterized by IR, UV/Vis, and EPR spectroscopy, and the experimental data were compared to results from DFT calculations. While 2-, 5- and 6-azulenylcarbene show triplet ground states, 1-azulenylcarbene exhibits a singlet ground state, in accord with theoretical predictions. The rearrangements of the azulenylcarbenes give access to a number of unusual C11H8 isomers, such as other carbenes and strained allenes.
Read our paper in Chem. Eur. J.
Paolo Costa won the Dr.-Heinrich-Kost-Preis of the faculty of chemistry and biochemistry for his PhD thesis
Paolo studied the interplay between solvents and reactive intermediates on the molecular scale. He observed that a diphenyl carbene, matrix isolated in solid argon at cryogenic temperatures changes its spin state from triplet to singlet because of the interaction between a single methanol or water molecule by forming hydrogen bonds. He found the same behaviour for Fluorenyliden and water in argon matrix. Using water matrices the corresponding carbo cations are formed via protonation. Paolo's PhD thesis was supervised by Prof. W. Sander.
Light and Temperature Control of the Spin State of
A Magnetically Bistable Carbene
P. Costa, T. Lohmiller, I. Trosien, A. Savitsky, W. Lubitz, M. Fernandez-Oliva, E. Sanchez-Garcia, and W. Sander, J. Am. Chem. Soc. 138 (2016), 1622-1629.
Bis(p-methoxyphenyl)carbene is the first carbene that at cryogenic temperatures can be isolated in both its lowest energy singlet and triplet states. At 3 K, both states coexist indefinitely under these conditions. The carbene is investigated in argon matrices by IR, UVvis, and X-band EPR spectroscopy and in MTHF glasses by W-band EPR and Q-band ENDOR spectroscopy. UV (365 nm) irradiation of the system results in formation of predominantly the triplet carbene, whereas visible (450 nm) light shifts the photostationary equilibrium toward the singlet state. Upon annealing at higher temperatures (>10 K), the triplet is converted to the singlet; however, cooling back to 3 K does not restore the triplet. Therefore, depending on matrix temperature and irradiation conditions, matrices containing predominantly the triplet or singlet carbene can be generated. Controlling the magnetic and chemical properties of carbenes by using light of different wavelengths might be of general interest for applications such as information storage and radical-initiated polymerization processes.
Switching the Spin State of Diphenylcarbene via Halogen Bonding
S. Henkel, P. Costa, L. Klute, P. Sokkar, M. Fernandez-Oliva, W. Thiel, E. Sanchez-Garcia, and W. Sander, J. Am. Chem. Soc. 138 (2016), 1689-1697.
The interactions between diphenylcarbene DPC and the halogen bond donors CF3I and CF3Br were investigated using matrix isolation spectroscopy (IR, UVvis, and EPR) in combination with QM and QM/MM calculations. Both halogen bond donors CF3X form very strong complexes with the singlet state of DPC, but only weakly interact with triplet DPC. This results in a switching of the spin state of DPC, the singlet complexes becoming more stable than the triplet complexes. CF3I forms a second complex (type II) with DPC that is thermodynamically slightly more stable. Calculations predict that in this second complex the DPC···I distance is shorter than the F3C···I distance, whereas in the first (type I) complex the DPC···I distance is, as expected, longer. CF3Br only forms the type I complex. Upon irradiation I or Br, respectively, are transferred to the DPC carbene center and radical pairs are formed. Finally, on annealing, the formal CX insertion product of DPC is observed. Thus, halogen bonding is a powerful new principle to control the spin state of reactive carbenes.
Reaction of Triplet Phenylnitrene with Molecular Oxygen
J. Mieres-Perez, E. Mendez-Vega, K. Velappan, W. Sander, J. Org. Chem. 80 (2015), 11926-11931.
Triplet carbenes react with molecular oxygen with rates that approach diffusion control to carbonyl O-oxides, whereas triplet nitrenes react much slower. For investigating the reaction of phenylnitrene with O2, the nitrene was generated by flash vacuum thermolysis (FVT) of phenylazide and subsequently isolated in O2-doped matrices. FVT of the azide produces the nitrene in high yield and with only minor contaminations of the rearranged products that are frequently observed if the nitrene is produced by photolysis. The phenylnitrene was isolated in solid Ar, Xe, mixtures of these rare gases with O2, and even in pure solid O2. At temperatures between 30 and 35 K an extremely slow thermal reaction between the nitrene and O2 was observed, whereas at higher temperatures, solid Ar and O2 rapidly evaporate. Only O2-doped Xe matrices allowed us to anneal at temperatures above 40 K, and at these temperatures, the nitrene reacts with O2 to produce nitroso O-oxide mainly in its syn conformation. Upon visible light irradiation (450 nm), the nitroso oxide rapidly rearranges to nitrobenzene.
Soumya has won two Poster Awards for her poster "Matrix Isolation and Solvation studies of Diphenylmethyl Radical". Her poster was awarded at the 2015 GORDON RESEARCH CONFERENCE ON PHYSICAL ORGANIC CHEMISTRY in Holderness, New Hampshire (June 21-26) and at the EUROPEAN SYMPOSIUM ON ORGANIC REACTIVITY in Kiel, Germany (Aug 30 - Sep 04). Soumya presented the results of her research. She was able to generate the diphenylmethyl radical in argon matrix at 3 K and the benzhydryl cation upon irradiation with 308 nm. Further irradiation leads back to the formation of the precursor. She also studied the reversibility between the radical and cation species using infrared (IR) and UV-Vis spectrocopy.
Activation of Molecular Hydrogen by a Singlet Carbene through Quantum Mechanical Tunneling
S. Henkel, W. Sander, Angew. Chem. Int. Ed. 54 (2015), 4603-4607.
Carbenes are among the few metal-free molecules that are able to activate molecular hydrogen. Whereas triplet carbenes have been shown to insert into H2 through a two-step mechanism that at low temperature is assisted by quantum mechanical tunneling (QMT), singlet carbenes insert in concerted reactions with considerable activation barriers, and are thus unreactive towards H2 at cryogenic temperatures. Here we show that 1-azulenylcarbene with a singlet ground state readily inserts into H2, and that QMT governs the insertion into both H2 and D2. This is the first example that shows that QMT can also be important for singlet carbenes inserting into dihydrogen.
Read our publication in Angew. Chem. Int. Ed.
The Fluorenyl Cation
P. Costa, I. Trosien, M. Fernandez-Oliva, E. Sanchez-Garcia, W. Sander, Angew. Chem. Int. Ed. 54 (2015), 2656-2660.
The fluorenyl cation is a textbook example for a 4p antiaromatic cation. However, contrasting results have been published on how the annelated benzene rings compensate the destabilizing effect of the 4p antiaromatic five-membered ring in its core. Whereas previous attempts to synthesize this cation in superacidic media resulted in undefined polymeric material only, we herein report that it can be generated and isolated in amorphous water ice at temperatures below 30 K by photolysis of diazofluorene. Under these conditions, the fluorenylidene is protonated by water to give the fluorenyl cation, which could be characterized spectroscopically. Its absorption in the visible-light range matches that previously obtained by ultrafast absorption spectroscopy, and furthermore, its IR spectrum could be recorded. The IR bands in amorphous ice very nicely match predictions from DFT and DFT/MM calculations, suggesting the absence of strong interactions between the cation and surrounding water molecules.
Read our publication in Angew. Chem. Int. Ed.
The Fluorenyl Cation
RESOLV: Bochum-based researchers test effective new method
A molecule for the textbook
Antiaromatic compounds is what chemists call a class of ring molecules which are extremely instable the opposite of the highly stable aromatic molecules. Because they exist for mere split seconds, they can only be detected by extremely demanding, ultrafast methods. Together with colleagues from Max Planck Institute for Coal Research in Mülheim, researchers from the Cluster of Excellence RESOLV at Ruhr-Universität Bochum have succeeded in isolating the antiaromatic fluorenyl cation at extremely low temperatures in water ice. Thus, they were able to conduct a spectroscopic analysis for the very first time. Their report is published in Angewandte Chemie...(read more)


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Top Definition
Girls that like it threw the backdoor (anal sex)
My sister likes being a backdoor bitch.
by Alex R. February 10, 2004
Trending Now
Can you define these popular missing words?
a girl who flirts with everyone, makes you think shes commited to you, but has half a dozen other boyfriends you don't know about. A cocktease or cock tease. AKA BB.
It's really too bad that you got burnt by that backdoor bitch.
by King Kong March 06, 2004
A woman who pretends to be your friend to you face, but is always using sneaky 1 liners that are nasty.
Heather pretends she likes my cooking and then tells me she just heard about a new cooking class for beginners I should try, she is such a back door bitch.
by vitas smith August 08, 2010


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Protect Social Security customer service
We thought the push to privatize Social Security was dead. Failing to privatize Social Security, the administration has slashed the agency's budget. These tactics ensure that the next time we have to fight to save Social Security, the public's view of the Social Security Administration (SSA) might not be so favorable.
Reclaiming May Day: Marching together for all workers
Reflecting the holiday's origins, when immigrant workers played a big part in the fight for the eight-hour day, this year's observances melded workers' struggles for decent wages and conditions with the struggles of largely working-class immigrant communities for human and civil rights. Hundreds of thousands of immigrants were joined by many union contingents as they marched in cities throughout the country.


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Hayward C-200 Micro Star-Clear Compatible Filter
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The Filbur FC-1215 is the correct compatible replacement for the following pool and spa filters:
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- Aladdin 12001
- Pleatco PA20-4
- Unicel C-4320
The Hayward C-200 Micro Star-Clear Compatible Filter is made of 20 square feet of Reemay spunbound polyester media. This Hayward Micro Star Clear filter contains end caps that are made from durable polyurethane material. The center core of this Hayward pool filter is made of punched PVC pipe for consistent flow.
The Filbur FC-1215 specifications:
- 20 square feet Reemay media
- Diameter: 4 5/8 inches
- Length: 11 7/8 inches
- Top: 2 1/16 inches
- Bottom: 2 1/16 inches
- 3 ounces
Hayward C-200 Micro Star-Clear Compatible Filter Product Reviews :Write a review
- Not reviewed yet


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Watched the newest episode of KotN on Thursday. Let me tell you, I was very excited at the time to see it, but towards the middle of it when they said Brandon and Danielle would be going to the nerd off, I got pissed off. Why? Because TBS has repeatedly shown previews of clips from the show that have not been aired yet. One was Danielle slapping some guy. Why is this important? Because I already knew she would win the nerd-off. I liked Brandon, I was hoping to see him go further and to already know he was going to lose without even watching the nerd-off itself was just very disappointing. Is every episode going to be like this from now on? Will we already know whats going to happen because TBS doesn't know how to hide specific clips for previews? Sigh.
Well thank god there's still Law & Order: SVU.


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Top Definition
a racial slur that is good for any minority group.
god damn, you are such a fazacrab, lets go hang that dirty fazacrab, keep all those fazacrabs from jumping the border, etc.
por daneamous 15 de Outubro de 2007
Trending Now
Can you define these popular missing words?


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Author Archives: Jack Jabbour
KMTS District Basketball: DEMON BOYS WIN IN OVERTIME, RIFLE GIRLS KO DEVILS
PALISADE (2/18/16) – "Our young players want to send our seniors to state, and they did it!" Glenwood Springs boys basketball coach exulted after the Demons overcame a second-half comeback by Battle Mountain for a 43-38 overtime win in the … Continue reading
KMTS Basketball: GLENWOOD BOYS EARN PAYBACK OVER PALISADE
GLENWOOD SPRINGS (2/9/16) – "We were upset about the loss in Palisade," Glenwood senior Cam Horning said after his second-half heroics insured the outcome would be different in a tightly contested duel that wasn't decided until his two free throws … Continue reading
KMTS Basketball: DEMONS ON COMEBACK TRAIL AT EAGLE VALLEY
GYPSUM (2/5/16) – There's nothing more compelling than a fourth-quarter comeback. In Eagle Valley's "Inferno" gymnasium both Glenwood teams ignited in the final eight minutes, the boys winning 77-70 after trailing by 12 late in the third, and the girls, … Continue reading
KMTS Basketball: 'DOGS EDGE DEMONS ON LATE 3-POINTER AND RARE FREE THROWS
PALISADE (2/3/16) – As the Palisade Bulldogs' junior quarterback, P.D. Riddle was used to finding the end zone and helping his football team to a 9-3 record last fall. So maybe it shouldn't be a shock that Riddle would be … Continue reading
KMTS Basketball: RIFLE BOYS REMAIN UNBEATEN IN LEAGUE PLAY
RIFLE(1/28/16) – The contender came into town for a rematch, but the result, though not a knockout, was the same: Rifle's boys basketball team struggled with a determined Palisade team but remained undefeated in Western Slope League play, emerging with … Continue reading
KMTS Basketball: GLENWOOD TEAMS BOUNCE BACK, SWEEP SUMMIT
GLENWOOD SPRINGS(1/21/16) – There is a biblical saying that speaks of beauty coming from ashes. The comparison may be somewhat severe, but there's no denying that the injury misfortune that has plagued the Glenwood Lady Demons, along with a four-game … Continue reading
KMTS Basketball: LADY BEARS TOPPLE LEAGUE LEADERS, BOYS STAY UNBEATEN
GYPSUM (1/15/16) — In a clash of Western Slope gunslingers that did not disappoint, the Rifle Lady Bears, led by sophomore Elly Walters, knocked off previously unbeaten Eagle Valley and league scoring leader Kylie Martin with a fourth-quarter comeback 57-49 … Continue reading
KMTS Basketball: HORNING TOPS 1,000; LADY HUSKIES BREAK THROUGH
EDWARDS (1/8/16) – It was a night for milestones, and like all such events, some were sweet and others bitter. For Cam Horning, the frosting on his Glenwood Springs team's 64-54 victory at Battle Mountain came two minutes after halftime … Continue reading
KMTS Basketball: Glenwood Sweeps Delta in League Openers
GLENWOOD SPRINGS (12/18/15) – The Glenwood Springs Lady Demons, after a 16-4 2014-15 season lost all five starters to graduation. A young and inexperienced team struggled mightily through the pre-season, but first-year coach Rhonda Moser stressed fundamentals and improvement as … Continue reading
KMTS Volleyball: TITANS GO DOWN, BUT PREP FOR NEXT YEAR
Denver (11/14/15) – Tied at 17 in their first-round 3A state playoff match with Colorado's number-one volleyball team, the Coal Ridge Titans suffered a critical loss on an unlucky Friday the 13th. Kaitlyn Detelefsen, the Titans' devastating middle hitter who … Continue reading


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The Charleston Battery will travel to Washington for its first U.S. Open Cup final on Sept. 3 after knocking off the Seattle Sounders on penalty kicks Tuesday in the tournament's other semifinal at Blackbaud Stadium.
Former MLS goalkeeper Dusty Hudockwas the hero, stopping the deciding kick by Seattle substitute Kevin Forrestto give Charleston the edge in the shootout after the game ended in a 1-1 tie. Hudock was a reserve on the Chicago Fire's 1998 MLS Cup championship team.
Both teams showed their intent to reach the Open Cup final by playing reserves in league games this past weekend in order to rest starters for their semifinal.
Seattle went ahead on an own goal by Battery defender John Wilson in the 20th minute, but the Battery leveled 13 minutes later through Randi Patterson's close-range effort.
Aug. 12 in Charleston, S.C.
Charleston Battery 1 Seattle Sounders 1 (Charleston wins 4-3 on penalties).Goals: Patterson 33; own goal 20.
Charleston -- Hudock, Nylen (Velten, 79), Reda, Akwari, Wilson,Williams (Cianciarulo, 96), Alonso, Armstrong, Fuller (Richardson, 102), Patterson, Spicer (King, 73).
Seattle --Eylander, Scott, Jackson, Graham, Sakuda, Gardner (C.O'Brien, 40), Rodriguez, Treschuk (Forrest, 60), Kante (Besagno, 103), Le Toux, Roger Levesque (Cascio, 85).
Att.: 3,798.


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Nike is facing several headwinds right now that could continue to weigh on its stock.
Three of the 10 voting members of the Fed's monetary policy committee wanted to raise the target range for short-term interest rates by a quarter of a point.
So, when is the best time to sell anything?
The Fed wants to raise business confidence? Fed Chair Janet Yellen should try showing some herself.


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Election Day
Do-Now Discussion
Create your own stump speech: Write a six-word sentence that you would use if you were campaigning to be president and that expresses your views on the issues.
Headed to the White House Exhibition
Headed to the White House is the only exhibit of its kind, uniquely created to engage students, teachers and families with the election season. Using the U.S. Constitution as its launch pad, this hands-on exhibit takes visitors from the campaign trail to Inauguration Day all in one visit.
Daily Programs
To complement the Headed to the White House experience, the National Constitution Center will offer a wide variety of museum visitor programming
• Gallery Talks: Upon entering the Headed to the White House exhibit, visitors will be met by a member of the center's education staff, who will present a brief introduction that encourages visitors to consider key questions and themes highlighted through the exhibition's artifacts and displays.
• 270 or Bust: In this quiz-show style game, visitors will assume the role of presidential candidates or campaigns and attempt to earn the required 270 electoral votes to be elected! But, instead of earning the votes though campaigning, they will have to answer questions about various states and the Electoral College, itself! The first visitor or team to reach 270 wins!!
• Election Experience Introduction: This program will serve as an introduction to the "Election Experience" at the center. The presentation guides visitors through the elections season as a whole, and showcases the exhibits and programs available at the museum.
• Constitution 101—The Presidency: So, what does the Constitution actually say about the presidency? At this interactive program, NCC staffers will go explore Article II and the duties and requirements of the executive office.
• Exhibition Guide: The exhibition guide will enrich student visits by highlighting key artifacts and essential themes, guiding students as they learn about the development of the presidential selection process.
School Programs
• Themed Package: The Presidency (Grades 4-12)
Students will learn about presidential elections and campaign platforms and watch some of the most famous campaign ads of all time. This package includes a presidential workshop examining primary sources and the dynamic Destination White House show.
• Exhibit Tours: The Center will offer guided tours of Headed to the White House for interested groups. The tour will take the form of a walkthrough of the election process, beginning with a candidate's decision to run for office and proceeding through the process of primaries and caucuses, nominating conventions, debates, and the general election. Along the way, the tour guide will demonstrate his or her points by using relevant historical examples highlighted within the exhibition space.
Educator Events
• Educator Open House
Educators will get the chance to view before it opens to the public and enjoy exclusive tours, previews of the National Constitution Center's educational programs, and light refreshments. Teachers can also learn about educational resources from a variety of the museum's partners at an information fair on the Grand Hall Overlook. Act 48 credit will be available for certain programs.
• Educator Days
On select weekends throughout the run of the Headed to the White House exhibition educators will be invited to visit the new exhibit with their families at discounted, rate. The days will include special tours, and teachers will be provided information about all of the National Constitution Center's resources.
Civic Holidays
• Women's History Month; Women in the White House
March 2016
In conjunction with the Headed to the White House Exhibition, the Center's Women's History Month programming will feature a program highlighting the nation's First Ladies. Particularly, attention will be paid to First Ladies and women in executive offices who played roles in shaping the administrations of various presidents. Some examples includes: Martha Washington, Dolley Madison, Sarah Polk, Edith Wilson, Frances Perkins, Eleanor Roosevelt, Ladybird Johnson, and/or Madeline Albright.
• Spring Break
March 23-29, 2016
It's a Presidential Party this Spring Break at the National Constitution Center! Head to the museum and learn all about our country's commanders in chief!
• Independence Week: Founding Fathers, First Presidents
June 30-July 4, 2016
Take a closer look at the lives of George Washington, John Adams, Thomas Jefferson, and others—men who not only helped to found our country, but who would be the first to serve it in the office of the presidency.
• Constitution Day
September 16 and 17, 2016
This Constitution Day we will take a closer look at Article II of the Constitution and learn more about the creation of the American Presidency, and the Electoral Process.
• Election Day
November 8, 2016
Commemorate elections past and present at the National Constitution Center!
Traveling History and Civic Program:
• The Presidency
Package show where students learn about presidential elections and campaign platforms and watch some of the most famous campaign ads of all time.
• Constitution Hall Pass: The Presidency
Interactive video traces the history of the American presidency. Constitutional experts and the Center's education staff explore why it was important for our young nation to have an executive branch, and why nevertheless some people were worried about giving it too much power.
Lesson Plans:
• Address America: Your Six-Word Stump Speech
Lesson plan where students investigate national election stump speeches and then create their own. Students identify and analyze the elements of a stump speech by reading excerpts of 2000 – 2008 national election speeches.
• Investigating the Departments of the Executive Branch
In this lesson, students learn about the role of bureaucracy in U.S. government; they then examine the history, leadership, organization, and goals of executive agencies.
• Lincoln: The Constitution and the Civil War
In this lesson, students will analyze the political and constitutional issues that faced President Abraham Lincoln during the Civil War.
• Lincoln's Crossroads
Online game invites students to learn about Lincoln's leadership by exploring the political choices he made. An animated Lincoln introduces a situation, asks for advice and prompts players to decide the issue for themselves, before learning the actual outcome. At the end of the game, players discover how frequently they predicted Lincoln's actions.
• Executive Command Game
Online game offered through icivics where a student can be president and try to accomplish what they set as their agenda while facing the challenges and responsibilities that crop up along the way.
• Lincoln Hats
Craft activity where students make their own version of our 16th president' signature top hat.
• Model White House
Craft activity where students create a mini model of the home of the nation's president.
• President Masks
Craft activity where students can discover their alter ego as President Abraham Lincoln or George Washington as they decorate their own presidential mask.
Interactive Constitution
• Amendments 12