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in the news | LAST UPDATED : 2 Oct 2016, 03:43 IST
- Jayalalithaa 'recovering well,' says TN Governor after visiting CM in hospital
CHENNAI: Tamil Nadu's acting governor Ch. Vidyasagar Rao visited TN chief minister J Jayalalithaa, who is undergoing treatment at Apollo Hospital, on Saturday evening, and said that she is "recovering well." The governor arrived at the hospital at 6.40 pm and spent around 35 minutes inside. According to an official statement from Raj Bhavan, the governor visited the CM at 6.45 pm. He was briefed by Dr Pratap C Reddy, chairman of Apollo Hospitals, on the treatment being given to the chief minister at the hospital, the release said. "The Governor of Tamil Nadu, Ch. Vidyasagar Rao visited the Hon'ble Chief Minister in the ward where she is being given treatment. The Governor was happy to note that the Hon'ble Chief Minister is recovering well," the release said. The governor stated that he was thankful to the doctors who took him to the ward, and explaining in detail the treatment being given to the CM. He also appreciated the doctors for providing the best medical care and treatment to her, the release said. He also presented a basket of fruits and wished the chief minister a speedy recovery. Earlier, senior AIADMK leader and former Minister B Valaramathi told reporters, "Amma (Jayalalithaa) is healthy. She needs rest as per doctors' advice and will return in good health." She pointed out that Jayalalithaa was performing official duties and had even announced the party's candidates for this month's civic polls while being hospitalised. "Some rumour mongers are spreading misinformation. I request people not to believe those. Even when the chief minister is in hospital, she always thinks about people and their welfare. From the hospital itself, she made decisions regarding the Cauvery issue with the officials and she achieved victory on this too. She announced bonus for government employees. Even when the chief minister was in the hospital, it was AIADMK who released its candidate list first. So people can't digest that. Thats why they have started to spread rumours," she said. She added that the police is taking appropriate action on people spreading rumours about Jayalalithaa's health. Union minister Venkaiah Naidu, who was in the city to take part in some events, wished a "speedy recovery" to the CM. "On this occasion, I wish chief minister will recover speedily and come back and work for the welfare of the people of Tamil Nadu," he said.
- Hospitals put on war casualty alert
Chandigarh: Punjab's health department has made all necessary arrangements for tackling any medical emergencies in view of the escalated tension in border areas. Health minister Surjit Kumar Jyani called a meeting of senior officers on Friday, in which principal secretary Vini Mahajan and other senior officers were also present. Jyani said directions have been given to all officers of the department, especially civil surgeons of border districts of Amritsar, Ferozepur, Fazilka, Tarn Taran, Gurdaspur and Pathankot to remain on alert. All kinds of leaves of medical and paramedical staff in hospitals in border areas have been cancelled. Rural medical officers posted in the districts have also been asked to provide their services in affected areas as required by the health department. Civil surgeons have been told to ensure that all ambulances remain fully functional and adequate stock of medicines and other essential drugs, including availability of blood in blood banks in the government hospitals, is maintained. Adequate funds have already been given to the districts. Even the department of medical education and research has been requested to direct the government medical colleges in Faridkot and Amritsar to ensure availability of adequate number of doctors and paramedical staff, medicines and equipment. Mobile medical units have been withdrawn from their regular tour plans and deputed in all camps where people evacuated from border areas are being lodged.
- DM conducts surprise check of district hospital, finds CMS, 7 doctors missing
Bijnor: Chief medical superintendent (CMS), seven doctors and 14 other staff of the district government hospital were found absent during a surprise inspection by district magistrate Jagat Raj Tripathi on Friday, at a time when the rush of patients suffering from mosquito-borne diseases is at its peak
- Back to hospital after surgery? Here's why
Did you know that patients who are immobilized during a process like surgery run the risk of returning to the hospital within days of being discharge? If not, stay alert during your next hospital visit.For, such cases have increased by 15% in last one year.
- Jayalalithaa advised a few more days in hospital
CHENNAI: Tamil Nadu chief minister J Jayalalithaa has been advised a few days' stay in the hospital for recuperative treatment, a press release from the Apollo Hospitals said. The chief minister was admitted to Apollo Hospitals on Greams Road in Chennai with complaints of fever and dehydration. Bulletins released subsequently said she was responding well to treatment and was on a normal diet. She has been in the hospital since. On Thursday, a press release said she has responded well to treatment. "Necessary evaluation tests are being carried out. The honourable chief minister has been advised a few days stay in the hospital for recuperative treatment," said a release from the hospital COO Subbiah Viswanathan. Earlier, the AIADMK party channel, Jaya TV, said she was fine and will return home soon. ''The CM is recuperating in the hospital based on doctors' advice. Rumour mongers have been warned by the police that they are being monitored and stern action will be taken against them,'' a scroll on the channel said.
- Hospitals' strike: Court order ends deadlock
INDORE: The Indore bench of high court on Thursday issued a stay order on the district administration's decision to temporarily close the Curewell Hospital after a blast occurred in the hospital's compressor plant on September 5. The single bench of Justice Vivek Rusia has also directed the hospital's counsel Vivek Dalal to submit a report before the court, giving details of the compliance with the suggestions made by PWD's executive engineer regarding the air compressor. On Thursday, the administration submitted its reply before the court in which the irregularities on the part of the hospital had been pointed out to justify the order passed by the district administration on September 8. "While running a hospital, all equipment, machinery, staff is required to be up to the mark because any irregularity will play (with) the life of a patient. Therefore, no irregularity in any hospital is acceptable and therefore, the impugned order has rightly been passed," the reply by the administration stated in the affidavit. The affidavit, which was signed by SDM Sandeep Soni also stated that there was no intention of the district collector to permanently stop the functioning of the Curewell Hospital. The IMC had also sought to be made a party in the petition as they had also conducted an enquiry and found many irregularities in the hospital, which was built on a residential area. "The petition had been filed by the Curewell Hospital seeking directions from the high court to quash the order passed by district administration on the grounds that the hospital had not violated any provisions of law and had a valid certificate," Vivek Dalal, petitioner hospital's counsel said. At least nine persons were injured on September 5 due to a blast in the compressor plant at Curewell Hospital. Two of them were in a critical condition. A probe had been initiated by district collector P Narahari two days after the blast and an order declaring temporary closure of the hospital was passed on September 8. The matter has been listed for further hearings on October 14.
- Now, Odisha hospitals can't say no to emergency patient considering paying capacity
BHUBANESWAR: Hospitals can't deny treatment to any emergency patient by considering the patient's paying capacity. The Odisha assembly on last day of its monsoon session on Thursday passed the Odisha Clinical Establishments (control and regulation) Amendment Bill, 2016, under which any clinical establishment has to extend medical examination and treatment to stabilize the emergency medical condition of any individual brought to them as possible with the staff and facilities available with them. Hospitals coming up on government land have to provide a fixed minimum percentage of free treatment to below poverty line (BPL) patients both in indoors and outdoors. The government will decide on the percentage of percentage of free treatment to the BPL families from time to time. Earlier, though the government put pre-condition of providing free treatment to the poor while allotting land for a hospital, it was not part of any Act. Under the amendment, all private hospitals having even single bed has to register itself under the Clinical Establishment Act. Earlier, clinics having up to four beds were exempted from registration. The registration will now be valid for five years instead of the existing two years. "This will reduce workload of registration officials," health minister Atanu Sabyasachi Nayak said. Under the bill, all healthcare facilities irrespective of the systems of medicines such as Ayurveda, homoeopathy, naturopathy or Unani have to register them unlike the earlier norms only for allopathic hospitals.
- Manipal Hospitals deploys cognitive computing platform Watsons for oncology
MANGALURU: Manipal Hospitals on Thursday announced Watsons for oncology, a cognitive computing platform, to provide information and insights to physicians to help them identify personalized, evidence-based cancer care options across India. Manipal oncologists can access IBM Watson for Oncology for patients with breast, colorectal and lung cancer that are registered with a Manipal facility pan-India. Manipal Hospitals further announced the introduction of an expert second opinion cancer care consulting service. Individuals across India who have received a cancer diagnosis but are not a Manipal patient can access a Manipal oncologist for an expert second opinion.On December 2015, Manipal Hospitals announced its intent to adopt Watson for Oncology, making this the first deployment of Watson in India and the first engagement of its kind as the country advances its efforts to transform healthcare. "The introduction of Watson for Oncology will be a game changer for cancer patients across India. With Watson, Manipal oncologists can make an informed treatment decisions for patients based on insights derived from the individuals' unique health status, latest medical research and other relevant data," said Ajay Bakshi, MD and CEO, Manipal Hospitals. "With the launch of Manipal expert opinion service, we are also open to partnering with other hospitals and medical consultants who seek to benefit from Watson for Oncology or individuals who have received a cancer diagnosis and wish to seek the advice of a Manipal doctor," he said.Anand Venugopal, medical superintendent, KMC Hospital Mangaluru, said , "We are extremely pleased to launch this service in our region. Cancer has become a common ailment and with this new technology treatments can be faster and result oriented. People can now reach us directly for consultation within 72 hours by logging onto the Manipal online consult portal or by sending an SMS with the subject line 'WATSON' to 56363."Oncologists in India and across the globe are struggling to keep up with large volume of research, medical records and clinical trials. Further, doctors face an increasing battle to stay up to date about best practices in treatment and care management, he said. Watson ranks identified treatment options and provides links to supporting evidence for each option to help oncologists as they consider treatment options for their patient. Watson for Oncology draws from an impressive corpus of information, and, to date, more than 300 medical journals, more than 200 textbooks, and nearly 15 million pages of text. Watson's machine learning capability means it is continuously learning over time, and doctors have access to peer reviewed studies, clinical guidelines and expert perspectives, he added.
- Dengue affected patient dies in LLR hospital
KANPUR: A dengue positive patient who was undergoing treatment at the dengue ward of the Lala LR hospital for past 10 days, succumbed to her disease on Tuesday. The patient identified Munni Devi wife resident of Billhaur in Kanpur was admitted on bed number 25 of the dengue ward. Munni Devi was under treatment of Dr BP Priyadarshi. As per district medical administration, this is the first confirmed death of dengue recorded in the city. However, four more patients suspected to be suffering from dengue had died since the outbreak of dengue disease in the city. Munni when admitted in the LLR hospital was also being treated for water collection in her stomach. She also had complaint in taking breath. She was first admitted in the Murari Lal Chest hospital (associated hospital of GSVM medical college) but when doctors became suspicious of her suffering from dengue they referred her to LLR hospital. For confirmation of dengue in Munni Devi, her blood samples had been sent to microbiology department of GSVM medical college. After dengue confirmation Munni Devi was being treated accordingly. Her platelet count had fallen. Munni's condition started deteriorating from Monday night and she expired on Tuesday.
- DCR changes to ease licence renewal process for hospitals
Changes in development control regulations (DCR) on September 20, allowing setting up of 20-bed hospital in residential zones, comes as a huge respite for Kolhapur Municipal Corporation (KMC), which has been struggling to clear licence renewal proposals of over 200 hospitals.
- Government Medical College and Hospital to get 20 teaching posts for its OTPT deptartment
NAGPUR: Cabinet nod to filling of 20 posts (16 for teaching) in occupational and physiotherapy (OTPT) in the Government Medical College and Hospital (GMCH) has paved way for permanent affiliation of the Physiotherapy School and Centre (PSC) and Occupational School and Centre (OSC) with the Maharashtra University of Health Sciences (MUHS). It has also cleared the way for seeking eight post graduate seats, four seats each in OT and PT in the college. College has also got Rs194.88 lakh provision for the posts. PSC and OSC had been trying to fill the posts since the setting up of the two schools in 1995. The Maharashtra cabinet on Tuesday gave clearance for the 20 posts. The decision has been welcomed not just by the college but by city's entire medical fraternity. "College dean Dr A Niswade has been keenly pursuing the issue with the authorities. We are now just waiting for the GR. But it will be six months to a year till all the posts are actually filled," said Dr Umanjali Damke, acting superintendent of PSC who has been teaching there for the last 21 years as a lecturer. The posts to be filled include posts of principal, a professor, four associate professors and three lecturers in PSC and OSC each. Beside this, others are administrative posts. The MUHS virtually withdrew the affiliation of the university for want of teachers at OTPT schools. At present, just two teachers at PSC — Dr Damke and Dr Sophiya Azad — and two teachers in OSC have been handling teaching of all the four and half years of the course with an intake of 30 students each in the two subjects. Once the two schools have all the teaching posts, the results which now range from 95% plus are expected to rise to complete 100%. At present, three lecturers have been teaching ten subjects to over 120 students since the last 21 years. "Now we can look forward to not just good teaching but also better patient care. Having teachers in all specialities will boost our knowledge. We will be able to give better services. Having four PG seats in both OT and PT means a lot for not just city but also the region," said a student from the physiotherapy department.
- RMRI for joint research with Mahavir hospital
PATNA: Rajendra Memorial Research Institute (RMRI) director Dr Pradeep Das has said that molecular diagnostic, a fast developing technique in medical sciences, is likely to help in early diagnosis of many diseases, including cancer. Addressing a two-day workshop on "Real Time PCR (polymerase chain reaction)" at Mahavir Cancer Sansthan (MCS) here on Wednesday, Das said this novel technique was available in only a few institutions of the city. He lauded the efforts of MCS to apply this technique for the treatment of cancer patients at affordable cost. The PCR is a technique used in molecular biology to amplify a single copy or a few copies of a piece of DNA across several orders of magnitude, generating thousands to millions of copies of a particular DNA sequence. It is an easy and cheap tool to amplify a focused segment of DNA, Das said and offered to sign an MoU between RMRI and MCS for undertaking collaborative research. MCS director Vijay Kumar Gahlot said that MCS has got a new identity with the opening of Molecular Diagnostic Laboratory. Before establishment of this lab, samples were sent outside Bihar for analysis which was time consuming as well as costly. tnn
- 21-yr-old biker dies in pothole mishap near JJ Hospital
Mumbai: A huge pothole near the state-run JJ Hospital killed a 21-year-old youth, Rizwan Khan, while he was returning home with a friend after buying ice-cream for his family. Rizwan was riding without a helmet and sustained serious head injuries when his bike hit a pothole late on Monday. The pillion rider, his friend Murtaza Sayyad, was also injured in the accident but was discharged from hospital after treatment. Surprisingly, the BMC, which had long ignored the pothole, swung into action after the accident and filled it up the very next morning, on Tuesday. Locals demanded action against the concerned civic officials who they said had neglected their duty and acted only after a life was lost. Rizwan's father Kamaal Khan, along with local residents, submitted a letter to JJ Marg police station demanding action against concerned civic officials. Kamaal said, "The BMC and the government should attend to potholes to avoid such an incident. I am suffering but I want that no one else should suffer because of a pothole. I will request the government to address the issue." "That pothole has been there for more than a month, but civic officials did not pay any attention to it. They attended to the issue only after a youth lost his life. We demand strict action against the concerned officials," said Wasim Syed, a local political activist. Rizwan and Sayyad, both Nagpada residents, had been to an ice-cream parlour in Mazgaon on Monday night. They had ice-cream and Rizwan decided to pack some for his family. He was on his way to drop Sayyad when the accident took place around 11.30pm. "Rizwan was driving at normal speed and there was a taxi ahead of us which went over the pothole. Because of the taxi, Rizwan unable to notice the pothole as we were just behind the vehicle. The bike hit the pothole and we fell on the road. My building is just opposite the accident spot and a friend rushed to help and took us to JJ Hospital," said Sayyad. He also informed Rizwan's family members about the accident. The family decided to shift Rizwan to a private hospital where he was declared dead on early Tuesday.
- GFP demands investigation report on Goa Medical College and Hospital to be made public
Panaji, Sep 28 () Goa Forward Party (GFP) today demanded that state government should make public the "crucial" investigation report on the affairs of Goa Medical College and Hospital (GMCH) prepared by former bureaucrat N D Agarwal.


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Have we got our seasons mixed up? Fall is supposed to be when the harvest of fresh TV events appears. But the first few months of 2013 present us with a prodigious crop of new shows and mini-series - as well as the return of several favorites. Might as well jump right in, since the action begins this week.
- David Hiltbrand, Inquirer TV writer
Spring Arts - Television:
The Americans (FX, Wednesdays at 10 p.m., starting Jan. 30). The Cold War is heating up. Keri Russell ( Felicity) and Matthew Rhys ( Brothers & Sisters) play Reagan-era soccer parents with two daughters - except that they're deep-plant KGB spies. Their secret espionage is further complicated when an FBI agent (Noah Emmerich) moves in next door.

subset: commoncrawl


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Emily Olds
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I am a Social Studies teacher at Monument Mountain Regional High School. I teach psychology, U.S. History, and American Culture Studies. I especially enjoy teaching music and art history. I am an avid ballroom and Latin dancer!Affiliate


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0.63 ct. t.w. Unity Diamond Bezel Pendant in 14k Yellow Gold (I, I1)
by Unity Diamonds | Item #: 481279 | Model #: I4415A16S |
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More beauty from the Unity Diamond Collection, this 0.63 ct. t.w. bezel pendant reflects the brilliance and beauty of much larger solitaire pendants - a dazzling and elegant addition to any ensemble.
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Top Definition
a woman with small, but nice breasts
Girl, unbutton that shirt and let me get a peak of them hidden hills
by d-nizzle July 12, 2006
Trending Now
Can you define these popular missing words?
A girl whose tits look small when wearing a loose shirt (such as a polo shirt), but are actually larger than they seem.
Damn, I thought her tits were small when she had that uniform on, but when I saw her in a bikini I realized she had hidden hills!
by Doctor Swiing August 24, 2007


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I'm making a purchase from a person in Austria. I need someone who speaks german to help me communicate with them.
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Hunan East Gourmet CO
4415 West Broad Street
Richmond, VA 23230
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(804) 353-1001
Cuisine: Chinese Food Restaurants, Delis
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Great little buffet.
by David W.
Their spicy tangy dumplings are boss
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Excellent buffet, as far as buffets go.
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Today With Sean O Rourke Friday 8 November 2013
The mid-morning current affairs magazine with the stories of the day, sharp analysis, sports coverage, in-depth features and consumer interest.
Sean spoke to barber Joe Hourigan.
Sean spoke to Mona Wise, Food Writer, Sunday Times.
Sean spoke to Dr. Pat Collins, NUI Galway, Anthony Ryan, shop owner, Pat McGrath, RTE Western Correspondent, Mary Rodgers, CEO Stateside and Paddy O'Gorman.
Sean spoke to Mrs. Breda Ryan.
Sean spoke to Ted Walsh on AP McCoy's winning his 4000th Race in National Hunt.
for Callan's kicks he goes to Martin O'Neill and Roy Keane's first "Joint" press conference.
Sean spoke to Lorna Siggins, Journalist, Irish Times, Dave O'Connell, Group Editor, Connacht Tribune, Alan Ahearne , NUI, Galway.
De Danann were the guest musicians.
My Irish Molly O
Frankie Gavin And De Dannan
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Frankie Gavin & De Dannan
Golden Eagle
Frankie Gavin And De Dannan
Culture Night is this Friday with more than 3,000 free events.
Provides residential treatment for people suffering from addiction
Presenter: Sean O'Rourke


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Facebook C# SDK
This project received 2 bids from talented freelancers with an average bid price of $8 USD / hour.Get free quotes for a project like this
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In Facebook C# SDK older version like 3, there was a class [url removed, login to view]
But, not present in latest version of Facebook C# SDk 6.4.2
My purpose of using this class is to make redirection from Facebook to my app, in such a way that my app which was inside the Facebook is now working independently.
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Something to dope for words, something were there is no word but this to explain.
You kickin' that cat was dopesick!
από Matthew Kutney 9 Δεκέμβριος 2007
An undesirable person who is unworthy of their own existence. Their drug of choice is usually heroin, but they will smoke, snort, or shoot any substance. You don't want to touch anything this person has touched previously.
Dopesick will sell us some percocet but we have to give him a ride.
από PerCoceT 20 Ιανουάριος 2005


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Environmental Sustainability
With almost 10-million copies already sold and still a bestseller 12 years after it was first released, Yann Martel's Life of Pi is the definitive opposite of a rare book. But there is a new edition of 350 signed copies currently housed in the office of a Vancouver environmental group that collectors will surely notice. That's because the entire edition is printed on paper made in part from agricultural waste.
Martel enthusiastically joined fellow author Alice Munro, who signed 50 waste-based copies of Dear Life in the same cause: saving forests…
A new report by the Book Industry Environmental Council (BIEC) and Green Press Initiative indicates that the U.S. book industry has continued to make progress towards reducing the environmental impacts of books including impacts on forests and climate change. Among the most notable findings was that paper producers who supply book papers reported using an average of 24% recycled fiber, almost a fivefold increase from 2004 when they were believed to be using around 5% recycled fiber.
Almost 40 percent of K-12 and higher education schools are storing or throwing away textbooks that are dated, damaged or have otherwise reached the end of their productive life, leaving significant potential to increase book recycling programs across the country, according to a new study by the National Wildlife Federation.
The report concludes more education about the benefits of textbook recycling is needed to help schools identify options for recycling of unused textbooks. While the report highlights a number of pilot textbook recycling programs being conducted by higher education institutions such as the University of Wyoming, Columbia College, and the University of North Carolina at Greensboro, there are few K-12 school districts participating in similar efforts.
Regular readers of this irregular environmental publishing column know that in January we told you about the Green Press Inititative's (GPI) new Environmentally Responsible Publisher Certification (ERPC).
The program gives publishers a way to gauge (and tout) their environmental responsibility. But what if you don't know where to start?
GPI has launched consulting services to help publishing companies acquire the tools they need to become environmentally responsible.
In January, the Green Press Initiative (GPI)—a nonprofit that works with the book and newspaper publishing industries to conserve natural resources, announced its long-awaited Environmentally Responsible Publisher Certification (ERPC). Not unlike the U.S. Green Building Council's LEED certification for buildings, the GPI's program offers publishers tiers—bronze, silver and gold—for environmental achievement.
Dilemma: When it comes to reading, what's kinder to the environment - an e-reader or books?
Of course I'll: Stick with traditional books. Yes, they use paper and ink, but at least I don't need to plug them in.
Trade-off: There are carbon emissions in the production of books too, not to mention the loss of carbon-gobbling trees felled for paper.
Then I'll: Use the e-reader; as much as I read, it's bound to be a better choice over the long run. Trade-off: At the rate technology evolves, the e-reader I buy today will probably be obsolete within a few years.
Edwards Brothers announced that it has received chain-of-custody certification from the Programme for the Endorsement of Forest Certification (PEFC) for both its Ann Arbor and Lillington, North Carolina, offset manufacturing facilities. Edwards Brothers now carries certifications from PEFC, the Forest Stewardship Council®, and the Sustainable Forestry Initiative® programs.
On America Recycles Day, FutureMark Paper Company rolled out the first high-recycled premium coated paper produced in North America especially for textbooks, cookbooks, children's books and other picture books requiring premium print fidelity. Scholastic, an innovative children's publishing, education and media company, is among the environmentally progressive companies using Future Book paper
The Domtar Corporation's new "Paper Because" video series, which promotes the important role paper plays in our lives, relies on satire to highlight how using paper responsibly makes business sense and how it's also an environmentally sound choice.
Extra caught up with Scholastic's Leslie Garych, vice president of marketing services, and Tracy Van Straaten, vice president of trade publicity, to discuss the finer points of making the transition from a print-only catalog to one available in print and online.


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New... 1st time miscarrying
Comments (10)
I am so sorry :( You will find many nice people to share your feelings with on this board and help you through these tough times.
My baby has passed away, but I have yet to miscarry. This is my first pregnancy. My baby was due June 20.
#1 3/27/2015
i am so sorry to hear :( i was devastated when imiscarried mine last year aswell. he was born on april 8th 2011 would have been due on my sisters birthday november 18
It will be an open wound on your heart for a long time. don't be scared to reach out whenever you need to talk to someone. feel free to inbox me if you just need to talk.
R.I.P. alexander april 8, 2011
I'm so sorry for your loss.
I miscarried last Friday. Sometimes, when I start to think I'm feeling ok, then I'm overcome with feelings of sadness and disappointment. This was my first pregnancy and we've been trying for over 2 years. Some people have said, "Look at the bright side, at least you know you can get pregnant"
I don't know how that is a bright side, in fact, I think there is never a bright side to a miscarriage.
dont let peoples comments make you feel bad either most don't know how to respond to a miscarriage. (my mother in law made a couple rather heartless comments and wouldnt even talk to my husband about it all she said was "things happen for a reason") i have heard almost every comment that you wouldnt want to hear from those who didn't know how to proplerly respond, "don't worry it will all be ok" "things happen for a reason" "you can always try again" "oh well now you can party on your birthday" etc etc etc there were several people i just wanted to punch int eh face but i realize that most people who have never had a miscarriage have NO idea how much it actually hurts to loos a pregnancy. just ignore the comments or thank them for their concern etc and go on with your day.
R.I.P. alexander april 8, 2011
Dd born 9/28/11.
mc 12/4/12.
Our rainbow son arrived 11/18/13!
Dd born 9/28/11.
mc 12/4/12.
Our rainbow son arrived 11/18/13!
thanks and I'm experiencing people don't know what the right thing to say comments. sometimes i just wish people wouldn't say anything at all because of the comments they say. right now the "everything happens for a reason" comment makes me mad. i cause i really want to ask so whats the reason for me to miscarry my baby. nobody do not want to go through that. and i really hate maybe this wasn't the right time comment and now you can drink n go out again n BS like that... ill trade all of that to have my baby again.
I've also heard, at least you didn't feel them move or hear a heartbeat, that would have been worse. Maybe in a way that's true, but still a poor choice of words. I wanted more than anything to hear a heartbeat or feel a kick. It was my first pregnancy. I don't cry much, but when I started bleeding I cried a lot. I knew deep down what was going to happen. Thanksgiving sucked. I was bitter, living away from family,and just unhappy in general. I feel a lot better now but kept my positive preg tests and can't bring myself to delete my pregnancy app from my phone. Monday it told me that I was 9 wks and how baby was developing. Ahhh still coping. Praying for a rainbow baby.
Angel baby 11/12
Rainbow baby boy 4/29/2014!
I also miscarried my first pregnancy two days before Thanksgiving. The past few weeks have been so hard. We found out today through chromosomal analysis that it was because our baby girl had Turner's Syndrome. I was 11w5d when I miscarried. I had a d&c the next day and then a few days later I was in a lot of pain with cramping and very heavy bleeding. Then put on meds to help uterus shrink (so I had more contractions) I pray for all of us, I truly do. This is just so hard to explain and some people who have never had this pain will just never know. I am so afraid to try again, but I would do anything to have a baby. My due date was for June 5 of this year.


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Made of non-woven FSC-certified paper, it comes in nine metre long rolls that have a width of 48.7 cm and an overall coverage of 4.4 square metres. Industrial and yet with a formal elegance, there are seven designs in the Concrete Collection.
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Posts Tagged 'white'
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The 7.9″ Retina Display makes its debut on the iPad mini, maintaining its enormous 2048 x 1536 native resolution. At 326 pixels per inch, the Retina Display can show up to 3.1 million pixels at a time. The Retina Display is also a capacitive touchscreen so you'll be able to utilize all the multi-touch gestures of iOS 7. Its smaller form factor makes it easier to hold in one hand. The iPad mini comes in a silver finish.
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The Apple iPhone 5 has it all – brains and beauty. It features a beautiful and responsive 4″ Retina display to view all your favorite content. 16GB of internal memory means you'll have plenty of space to store your photos, videos and more. Capture incredible memories with the 8MP iSight camera that takes incredibly sharp images and also records video in HD quality. Stay connected with family and friends via the front-facing FaceTime HD camera. Stay online and in-the-know wherever you go via built-in WiFi, Bluetooth and GPS. Powered by the acclaimed iOS 6 and with access to the App[Read More]
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HTC Desire 626; Get more looks, more performance, and more style with the HTC Desire 626 Series. Strike a pose: create your own look with vibrant mix-and-match color options. Immerse yourself: enjoy a 5″ brilliant display, smooth operating speed and a customized thread of your Facebook posts, tweets, scores, news and more in a glance. Finally, a smartphone that gets you.
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The Samsung Galaxy S 4 is thinner and lighter than the S III, yet it packs a larger 5-inch Super AMOLED display, with durable Gorilla Glass 3. Other improvements include a faster 1.9GHz quad-core processor, 13-megapixel camera, super-sensitive touch screen, and infrared universal remote control. The S4 can also detect hand gestures over the display and comes equipped with 16GB internal memory, and a microSD memory card slot for additional storage. Other features of this device include LTE high-speed data, 2-megapixel front camera, removable battery, and quadband GSM along with WCDMA modes for international use. Use this device to access[Read More]
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The iPhone 5C has the things that made iPhone 5 an amazing phone – and more. All in a complete new design. Other Features include: Wi-Fi 802.11 a/b/g/n, dual-band, Wi-Fi hotspot, Bluetooth: v4.0 with A2DP, LE, USB: v2.0, GPS: with A-GPS support and GLONASS, Browser: HTML (Safari), Messaging: iMessage, SMS (threaded view), MMS, Email, Push Email, Non-removable Li-Po 1510 mAh battery, Talktime: Up to 10 h, Standby time: 250 Hours


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5 posts tagged with citizenkane.
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My face fills the screen
Buried deep among the hundreds of old scripts in RKO Pictures' archives was a 1941 melodramatic gem about an amnesia-stricken man who wakes up in the middle of a revolution in Mexico. Never produced, the screenplay for "The Way to Santiago" is credited to Orson Welles.
Video Game's Citizen Kane
With this new video game coming out, we must finally ask: is this the Citizen Kane of video games? [more inside]
The Greatest Films of All Time, 2012
Sight & Sound's prestigious Greatest Films of All Time poll is conducted only once per decade. The latest edition polled 846 film critics (up from 144 in the 2002 edition) and 358 directors. The results were revealed earlier today and, for the first time since 1962, Citizen Kane has not topped either the critics' or the directors' poll. It has been unseated as the Greatest Film of All Time by Vertigo and Tokyo Story. The magazine has also revealed the Critics' Top 50. [more inside]
Magnificent Obsession
The Magnificent Ambersons, Orson Welles' second film, has inspired a legend around the lost footage excised by the studio to make it more appealing to audiences. The film's making is a cautionary tale in letting the studio have creative control, and the finished product pained Welles to his dying day. The mythical status of the lost footage has inspired a few to try and track it down. [more inside]
What evil lurks in the hearts of men?
Orson Welles may be best known as the director and star of Citizen Kane, but before he made movies he was a star of the radio. Although he gained notoriety by narrating War of the Worlds in 1938, he was also the voice of Lamont Cranston, The Shadow, and had a successful run as the creator and star of the Mercury Theater On The Air, which, after gaining sponsorship, became known as the Campbell Playhouse. Even after the heyday of radio, Welles provided his voice for The Black Museum series (based on real-life cases from the files of Scotland Yard), and The Lives of Harry Lime, a prequel to his role in the film The Third Man.
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text: AE Canvas Boat Shoe (2 Colors) 50% Discount Given at Checkout Free Shipping w/ Any SHoe Purchase Flag this deal What's the matter? Choose a reason Dead deal Duplicate Bad link Spam Inaccurate No value Alive again Edit deal EzzyLovesToSave Jun 21, 2013 $10.01 price drop. Reply Load More Comments


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Find out what's new in the latest release build of PADS4 - including ability monitoring audit trail, and new PAD4 Viewer Connection data provider....View More
Good news if you are looking for a stand for the Microsoft Surface Hub. Smart Media Solutions can now confirm that the Presence Mobile Motorised (C5-31U001-2-C-0) is valid for 150...View More
Evoko Minto just got even smarter. It now has a new demo mode which can be used to test the unit without an active call. Another new feature 'Auto Pair Mode' is useful for when...View More
Canon has released two new laser projectors both with a resolution of 1,920 x 1,200. Both the LX-MU800Z and the LX-MU600Z combine the benefits of laser projection to provide...View More
Shipping end of July 2016...Evoko Liso is packed with new smart functions and is more intuitive than ever. It even changes info on the display when someone walks up to it. All...View More
Anders+Kern will be exhibiting the latest meeting room booking panels, CAFM software and meeting collaboration technology on stand S1020 at the Facilities Show 2016....View More
Leading reseller services group, Synaxon UK, and Anders+Kern (A+K), have formed a new partnership giving Synaxon members access to the A+K's range of digital signage,...View More
With the increased interest in combining PADS4 with embedded System-on-Chip (SoC) players for platforms such as the Samsung SSSP and LG WebOS we would like to share some important...View More
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- 01 October 2016
MANILA, Oct. 1 -- Labor Secretary Silvestre H. Bello III, concurrent government chief negotiator on the talks with communist rebels, stressed on addressing the root causes of armed conflicts through socio-economic reforms in order to achieve permanent peace in the country. In a forum on the peace talks between the Philippine Government (GRP) and the National Democratic Front (NDF) organized by the Pamantasan ng Lungsod ng Maynila (PLM) on Monday, September 26, Bello identified extreme poverty, injustices, and corruption in government as underlying factors that bred insurgency and that these concerns must be immediately resolved. "The signing of the agreements is not the peace itself nor the assurance of lasting peace. In order to achieve peace in our country, we should not be signing peace agreements alone but, we should be addressing the root causes of conflict," Bello said. Bello explained that the Comprehensive Agreement on Socio-Economic Reforms (CASER) with the NDF seeks to address these concerns. CASER—which according to Bello is the "heart and soul of the GRP-NDF peace process"—is one of the remaining substantive agenda on the talks, aside from the ...Read more


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What causes muscle weakness? 42 possible conditions
See a list of possible causes in order from the most common to the least.
Muscle weakness. Muscle strength reduced, muscular weakness, weak muscles. True muscle weakness means that full effort does not produce a normal muscle contraction or movement. A voluntary muscle contraction i...
Chronic fatigue syndrome (CFS) is a debilitating disorder characterized by extreme tiredness that can't be explained by an underlying medical condition.
Muscular dystrophies are a group of inherited diseases that damage and weaken your muscles over time. This damage and weakness is due to the lack of a protein.
Dermatomyositis is a rare inflammatory disease. It's an inflammatory myopathy, which is a condition that occurs when your muscles become inflamed.
Low blood sodium, or hyponatremia, occurs when water and sodium are out of balance in your body. A quick drop in sodium levels can cause weakness, headache, nausea, and muscle cramps.
Osteomalacia is a weakening of the bones that can lead to serious health complications. Here's a look at the symptoms and treatment options.
This condition is considered a medical emergency. Urgent care may be required.
A concussion is a mild traumatic brain injury. Usually it occurs after an impact to your head or after a whiplash-type injury. A concussion can cause many severe symptoms that affect brain function.
Hypokalemia occurs when the blood's potassium levels are too low. A normal level of potassium is 3.6-5.2 millimoles per liter. Levels below 3.6 are considered low.
Myasthenia gravis is a neuromusclar disorder. It results in weakness of the skeletal muscles, and can cause double vision and drooping of the eyelid.
This condition is considered a medical emergency. Urgent care may be required.
A stroke (a "brain attack") is a medical emergency in which part of the brain is deprived of oxygen. This occurs when an artery that supplies oxygenated blood to the brain becomes damaged and brain cells begin to die.
You can have a slipped disk in any part of your spine, from your neck to your lower back. Read more about symptoms, causes, diagnosis, and treatment.
Graves' disease is an autoimmune disorder that causes your thyroid gland to create too much thyroid hormone. Learn the symptoms and your treatment options.
Peripheral neuropathy is a disorder that occurs when your peripheral nerves malfunction because they're damaged.
Hypercalcemia is a condition in which you have too much calcium in your blood.
The thyroid gland produces a hormone that controls how your cells use energy (metabolize). Hypothyroidism occurs when the body doesn't produce enough. Untreated, it can cause complications like obesity and heart disease.
One of the nine types of muscular dystrophy, Duchenne muscular dystrophy (DMD) is a genetic condition characterized by progressive weakening of voluntary muscles that leads to death. DMD worsens more rapidly than othe...
This condition is considered a medical emergency. Urgent care may be required.
During a transient ischemic attack (TIA, mini stroke) blood stops flowing to the brain for a short period of time. TIA doesn't kill brain cells like a stroke does. TIA causes symptoms that mimic those of a stroke.
Please consult a healthcare professional if you have health concerns.
Click to add a symptom to your list
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- 3 beds
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BACK ON THE MARKET ** Bank Approved Short Sale. This is a beautiful 3 bedroom home with a study that could be used as a 4th bedroom. The home has a large living room/dining room combo and a nice size eat-in kitchen with all appliances. A beautiful master bedroom with a huge walk-in closet, as well as a garden tub and separate shower in the master bath. This home offers 1,673 sq ft of living space, a nicely landscaped yard, and a large 2 car garage. The home is located in prestigious Victoria Lakes on the Northside of Jacksonville.
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Parking veto stands in cityBy Gordon Dritschilo
Staff Writer | March 19,2013Parking will remain free on Saturdays for the foreseeable future.
Mayor Christopher Louras' veto of a measure to enforce the parking meter ordinance stood at the close of Monday's Board of
Aldermen meeting. Alderman Gary Donahue made a motion to sustain the veto, but that motion failed for lack of a second and, it turns out, was unnecessary.
"We didn't do anything," Donahue said Tuesday. "By not doing anything, we sustained the veto. We didn't take any action and it just died right there."
Donahue said Alderman Jon Kiernan attempted to have the issue sent back to committee, but that motion failed for lack of a second.
Even without the veto, City Attorney Andrew Costello had said the board's action was likely invalid as it was based on a misunderstanding of the ordinance.
When the board met March 4, the members voted unanimously to support what they believed was the current policy of the police chief, who they believed had authority over the subject, to enforce the parking ordinance Monday through Saturday.
Shortly after that vote, however, Mayor Louras said that the police chief had no such policy and blamed the belief to the contrary on a miscommunication. A review of city records found that the board has the authority to set the times of enforcement and voted in 1994 to enforce it Monday through Friday.
For the complete story, see Wednesday's Rutland Herald.MORE IN This Just InKILLINGTON Police are waiting for the results of an autopsy of a 30-year-old woman who was... Full Story
Rutland's application to become a resettlement site for up to 100 Syrian refugees has... Full StoryARLINGTON The Otter Valley boys soccer team earned its second win over Springfield in four days... Full Story
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Breakfast Combo $12.952 Pc. French Toast, 2 Eggs Any Style and Choice of Pepper Bacon orApple Chicken Sausage. Served with Roasted Potatoes or Fresh Fruit Cup


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Immigration Law Helping or Hurting Arizonans?
Immigration Law Helping or Hurting Arizonans?
448 results for 'mexico'. Showing results 379 - 396
Immigration Law Helping or Hurting Arizonans?
BP's CEO Hayward to Step Down in October
Gulf Crews, Residents Plan for Ugly Bonnie
Coming Storm Throws Loop in Oil Cap Progress
Gulf Spill 'Solution' Worse than the Problem?
BP's Gulf Geyser Stops, But Will Cap Hold?
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Testing Begins on New Oil Leak Cap
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British Petroleum Reports Progress on Oil Cap
Rains Force Evacuations along the Rio Grande
Gulf Day of Prayer Set for July 18
Oil Spill Dampens Gulf Residents Busiest Holiday
Hurricane Alex Weakens, Leaves Path of Damage
BP Oil Spill Largest Ever in the Gulf
Texans, Oil Spill Crews Prepare as Alex Strengthens
Strengthening Alex Could Hamper Gulf Cleanup
Tropical Storm Alex Gaining Strength Over Gulf


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>LEGACY OF SILENCE Belva Plain
An impetuous tryst between a German youth and a Jewish girl provides a dramatic framework for this romantic saga of two sisters who flee World War II Berlin for the U.S.—only to pass on their darkest secret. By the bestselling author of Homecoming. (Delacorte, $24.95)
ARE YOU SOMEBODY Nuala O'Faolain In this evocative memoir, a prominent Dublin newspaper columnist traces her adult battles with alcoholism and depression back to the second-class treatment of women in Irish society. (Holt, $21)
EXCALIBUR Bernard Cornwell Medieval times burst to life in Cornwell's canny retelling of the King Arthur myth. In this final installment of the popular Warlord Chronicles, a refreshingly flesh-and-blood Arthur fights off the Saxons as well as depression over his rocky marriage to Guinevere. (St. Martin's, $24.95)
Picks and Pans Review: Worth a Look
updated 08/03/1998 AT 01:00 AM EDT
•originally published 08/03/1998 AT 01:00 AM EDT


text:
|Publication number
|Publication type
|Application number
|Publication date
|Dec 26, 2006
|Filing date
|Apr 22, 2004
|Priority date
|May 20, 2003
|Fee status
|Also published as
|Publication number
|Narasimha-Rao Venkata Bangaru, ChangMin Chun, Hyun-Woo Jin, Jayoung Koo, John Roger Peterson, Robert Lee Antram, Christopher John Fowler
|Original Assignee
|Exxonmobil Research And Engineering Company
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (57), Non-Patent Citations (1), Referenced by (6), Classifications (16), Legal Events (3)
|External Links: USPTO, USPTO Assignment, Espacenet
This application claims the benefit of U.S. Provisional application 60/471,792 filed May 20, 2003.
The present invention is broadly concerned with cermets, particularly cermet compositions comprising a metal oxide. These cermets are suitable for high temperature applications wherein materials with superior erosion and corrosion resistance are required.
Erosion resistant materials find use in many applications wherein surfaces are subject to eroding forces. For example, refinery process vessel walls and internals exposed to aggressive fluids containing hard, solid particles such as catalyst particles in various chemical and petroleum environments are subject to both erosion and corrosion. The protection of these vessels and internals against erosion and corrosion induced material degradation especially at high temperatures is a technological challenge. Refractory liners are used currently for components requiring protection against the most severe erosion and corrosion such as the inside walls of internal cyclones used to separate solid particles from fluid streams, for instance, the internal cyclones in fluid catalytic cracking units (FCCU) for separating catalyst particles from the process fluid. The state-of-the-art in erosion resistant materials are chemically bonded alumina castable refractories. These alumina castable refractories are applied to the surfaces in need of protection and upon heat curing hardens and adheres to the surface via metal-anchors or metal-reinforcements. The alumina castable refractory readily bonds to other refractory surfaces. The typical chemical composition of one commercially available chemically bonded alumina castable refractory is 80.0% Al2O3, 7.2% SiO2, 1.0% Fe2O3, 4.8% MgO/CaO, 4.5% P2O5 in wt %. The life span of the state-of-the-art refractory liners is significantly limited by excessive mechanical attrition of the liner from the high velocity solid particle impingement, mechanical cracking and spallation. Therefore there is a need for materials with superior erosion and corrosion resistance properties for high temperature applications. The cermet compositions of the instant invention satisfy this need.
Ceramic-metal composites are called cermets. Cermets of adequate chemical stability suitably designed for high hardness and fracture toughness can provide an order of magnitude higher erosion resistance over refractory materials known in the art. Cermets generally comprise a ceramic phase and a binder phase and are commonly produced using powder metallurgy techniques where metal and ceramic powders are mixed, pressed and sintered at high temperatures to form dense compacts.
The present invention includes new and improved cermet compositions.
The present invention also includes cermet compositions suitable for use at high temperatures.
Additionally, the present invention includes an improved method for protecting metal surfaces against erosion and corrosion under high temperature conditions.
These and other objects will become apparent from the detailed description which follows.
One embodiment of the invention includes a cermet composition represented by the formula (PQ)(RS) comprising: a ceramic phase (PQ) and a binder phase (RS) wherein,
One component of the cermet composition represented by the formula (PQ)(RS) is the ceramic phase denoted as (PQ). In the ceramic phase (PQ), P is a metal selected from the group consisting of Al, Si, Mg, Ca, Y, Fe, Mn, Group IV, Group V, Group VI elements of the Long Form of The Periodic Table of Elements and mixtures thereof. Q is oxide. Thus the ceramic phase (PQ) in the oxide cermet composition is a metal oxide. Aluminum oxide, Al2O3 is a preferred ceramic phase. The molar ratio of P to Q in (PQ) can vary in the range of 0.5:1 to 1:2.5. As non-limiting illustrative examples, when P=Si, (PQ) can be SiO2 wherein P:Q is about 1:2. When P=Al, then (PQ) can be Al2O3 wherein P:Q is 1:1.5. The ceramic phase imparts hardness to the oxide cermet and erosion resistance at temperatures up to about 1150� C.
The ceramic phase (PQ) of the cermet is preferably dispersed in the binder phase (RS). It is preferred that the size of the dispersed the ceramic particles is in the range 0.5 to 7000 microns in diameter. More preferably in the range 0.5 to 3000 microns in diameter. The dispersed ceramic particles can be any shape. Some non-limiting examples include spherical, ellipsoidal, polyhedral, distorted spherical, distorted ellipsoidal and distorted polyhedral shaped. By particle size diameter is meant the measure of longest axis of the 3-D shaped particle. Microscopy methods such as optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) can be used to determine the particle sizes.
In another embodiment of this invention, the (PQ) phase is tabular alumina. Tabular alumina is a dense refractory aggregate, a well-sintered, coarse crystalline α-Al2O3. The tabular name comes form its hexagonal tablet-shaped crystal composition. It is popular as an aggregate for alumina-based refractory castables. The cermet made using tabular alumina imparts superior mechanical properties through efficient transfer of load from the binder phase (RS) to the ceramic phase (PQ) during erosion processes.
Another component of the oxide cermet composition represented by the formula (PQ)(RS) is the binder phase denoted as (RS). In the binder phase (RS), R is the base metal selected from the group consisting of Fe, Ni, Co, Mn and mixtures thereof. S is an alloying metal consisting essentially of at least one element selected from Cr, Al and Si and at least one reactive wetting element selected from the group consisting of Ti, Zr, Hf, Ta, Sc, Y, La, and Ce. The combined weight of Cr, Al, Si and mixtures thereof are of at least about 12 wt % based on the weight of the binder (RS). The reactive wetting element is about 0.01 wt % to about 2 wt %, preferably about 0.01 wt % to about 1 wt % of based on the weight of the binder. The alloying metal S can further comprise a corrosion resistant element selected from the group consisting of Al, Si, Nb, Mo and mixtures thereof. The corrosion resistance elements provide for superior corrosion resistance. The reactive wetting elements provide enhanced wetting by reducing the contact angle between the ceramic phase (PQ) and molten binder phase (RS) in the temperature range of 1500� C. to 1750� C. One method to add the reactive wetting element such as Ce and La is to add suitable amounts of Misch metal. Misch metal is mixed rare earth elements of the Long Form of the Periodic Table of Elements and is known to one of ordinary skill in the art. These elements can be added as a pure element during mixing of the oxide and metal powder in processing or can be part of the metal powder prior to mixing with oxide powder.
In the oxide cermet composition the binder phase (RS) is in the range of 5 to 70 vol %, preferably 5 to 45 vol %, and more preferably 10 to 30 vol % based on the volume of the cermet. The mass ratio of R to S can vary in the range from 50/50 to 90/10. In one preferred embodiment the chromium content in the binder phase (RS) is at least 12 wt % based on the weight of the binder (RS). In another preferred embodiment the combined zirconium and hafnium content in the binder phase (RS) is about 0.01 wt % to about 2.0 wt % based on the total weight of the binder phase (RS).
The cermet composition can further comprise secondary oxides (P′Q) wherein P′ is selected from the group consisting of Al, Si, Mg, Ca, Y, Fe, Mn, Ni, Co, Cr, Ti, Zr, Hf, Ta, Sc, La, and Ce and mixtures thereof. Stated differently, the secondary oxides are derived from the metal elements from P, R, S and combinations thereof of the cermet composition (PQ)(RS). The ratio of P′ to Q in (P′Q) can vary in the range of 0.5:1 to 1:2.5. The total ceramic phase volume in the cermet of the instant invention includes both (PQ) and the secondary oxide (P′Q). In the oxide cermet composition (PQ)+(P′Q) ranges from of about 30 to 95 vol % based on the volume of the cermet. Preferably from about 55 to 95 vol % based on the volume of the cermet. More preferably from 70 to 90 vol % based on the volume of the cermet.
The volume percent of cermet phase (and cermet components) excludes pore volume due to porosity. The cermet can be characterized by a porosity in the range of 0.1 to 15 vol %. Preferably, the volume of porosity is 0.1 to less than 10% of the volume of the cermet. The pores comprising the porosity is preferably not connected but distributed in the cermet body as discrete pores. The mean pore size is preferably the same or less than the mean particle size of the ceramic phase (PQ).
One aspect of the invention is the micromorphology of the cermet. The ceramic phase can be dispersed as spherical, ellipsoidal, polyhedral, distorted spherical, distorted ellipsoidal and distorted polyhedral shaped particles or platelets. Preferably, at least 50% of the dispersed particles is such that the particle-particle spacing between the individual oxide ceramic particles is at least 1 nm. The particle-particle spacing may be determined for example by micro-copy methods such as SEM and TEM.
The cermet compositions of the instant invention possess enhanced erosion and corrosion properties. The erosion rates were determined by the Hot Erosion and Attrition Test (HEAT) as described in the examples section of the disclosure. The erosion rate of the oxide cermets of the instant invention is less than 1.0�10−6 cc/gram of SiC erodant. The corrosion rates were determined by thermogravimetric (TGA) analyses as described in the examples section of the disclosure. The corrosion rate of the oxide cermets of the instant invention is less than 1�10−11 g2/cm4�s.
The cermet compositions possess fracture toughness of greater than about 1.0 MPa�m1/2, preferably greater than about 3 MPa�m1/2, and more preferably greater than about 5 MPa�m1/2. Fracture toughness is the ability to resist crack propagation in a material under monotonic loading conditions. Fracture toughness is defined as the critical stress intensity factor at which a crack propagates in an unstable manner in the material. Loading in three-point bend geometry with the pre-crack in the tension side of the bend sample is preferably used to measure the fracture toughness with fracture mechanics theory. (RS) phase of the cermet of the instant invention as described in the earlier paragraphs is primarily responsible for imparting this attribute.
The cermet compositions are made by general powder metallurgical technique such as mixing, milling, pressing, sintering and cooling, employing as starting materials a suitable ceramic powder and a binder powder in the required volume ratio. These powders are milled in a ball mill in the presence of an organic liquid such as ethanol for a time sufficient to substantially disperse the powders in each other. The liquid is removed and the milled powder is dried, placed in a die and pressed into a green body. The resulting green body is then sintered at temperatures above about 1200� C. up to about 1750� C. for times ranging from about 10 minutes to about 4 hours. The sintering operation is preferably performed in an inert atmosphere or under vacuum. For example, the inert atmosphere can be argon and the reducing atmosphere can be hydrogen. Thereafter the sintered body is allowed to cool, typically to ambient conditions. The cermet production according to the process described herein allows fabrication of bulk cermet bodies exceeding 7 mm in thickness.
Another aspect of the invention is the avoidance of embrittling inter-metallic precipitates such as sigma phase known to one of ordinary skill in the art of metallurgy. The oxide cermet of the instant invention has preferably less than about 5 vol % of such embrittling phases. The cermet of the instant invention with (PQ) and (RS) phases as described in the earlier paragraphs is responsible for imparting this attribute.
One feature of the cermets of the invention is their microstructural stability, even at elevated temperatures, making them particularly suitable for use in protecting metal surfaces against erosion at temperatures up to about 1150� C. It is believed this stability permits their use for time periods greater than 2 years, for example for about 2 years to about 10 years. In contrast many known cermets undergo transformations at elevated temperatures which results in the formation of phases which have a deleterious effect on the properties of the cermet.
The high temperature stability of the cermets of the invention makes them suitable for applications where refractories are currently employed. A non-limiting list of suitable uses include liners for process vessels, transfer lines, cyclones, for example, fluid-solids separation cyclones as in the cyclone of Fluid Catalytic Cracking Unit used in refining industry, grid inserts, thermo wells, valve bodies, slide valve gates and guides, catalyst regenerators, and the like. Thus, metal surfaces exposed to erosive or corrosive environments, especially at about 300� C. to about 1150� C. are protected by providing the surface with a layer of the cermet compositions of the invention. The cermets of the instant invention can be affixed to metal surfaces by mechanical means or by welding.
Determination of Volume Percent:
The volume percent of each phase, component and the pore volume (or porosity) were determined from the 2-dimensional area fractions by the Scanning Electron Microscopy method. Scanning Electron Microscopy (SEM) was conducted on the sintered cermet samples to obtain a secondary electron image preferably at 1000� magnification. For the area scanned by SEM, X-ray dot image was obtained using Energy Dispersive X-ray Spectroscopy (EDXS). The SEM and EDXS analyses were conducted on five adjacent areas of the sample. The 2-dimensional area fractions of each phase was then determined using the image analysis software: EDX Imaging/Mapping Version 3.2 (EDAX Inc, Mahwah, N.J. 07430, USA) for each area. The arithmetic average of the area fraction was determined from the five measurements. The volume percent (vol %) is then determined by multiplying the average area fraction by 100. The vol % expressed in the examples have an accuracy of +/−50% for phase amounts measured to be less than 2 vol % and have an accuracy of +/−20% for phase amounts measured to be 2 vol % or greater.
Determination of Weight Percent:
The weight percent of elements in the cermet phases was determined by standard EDXS analyses.
The following non-limiting examples are included to further illustrate the invention.
The usefulness of the addition of reactive wetting elements in the binders is to promote wetting of molten binder on ceramics by reducing contact angle. Contact angle measurement was made to quantify the wetting phenomenon. The alloy binder containing various amount of reactive wetting element (i.e., 0.9 wt % Zr and 0.4 wt % Hf) based on the weight of the binder was placed on top of a polished substrate of the single crystal (i.e., C (0001) plane sapphire) and heated to 1700� C. for 10 minutes in high vacuum furnace (1�10−6 torr). After cooling the sample to ambient temperature, the contact angle was then measured by cross sectional electron microscopy. As an example, contact angle data for 304SS is presented in
Alumina powder was obtained from various sources. Table 1 lists alumina powder used for high temperature erosion/corrosion resistant oxide cermets.
Alfa Aesar
Tabular Alumina T-64
Tabular Alumina T-64
Tabular Alumina T-64
Tabular Alumina T-64
Tabular Alumina T-64
Tabular Alumina T-64
Metal alloy powders that were prepared via Ar gas atomization method were obtained from Osprey Metals (Neath, UK). Metal alloy powders that were reduced in size, by conventional size reduction methods to a particle size, desirably less than 20 μm, preferably less than 5 μm, where more than 95% alloy binder powder were screened below 16 μm. As an example, M304SS powder used in the experiment were more than 96.2% alloy binder powder screened below 16 μm.
Erosion Rate was measured as the volume of cermet, refractory, or comparative material removed per unit mass of erodant particles of a defined average size and shape entrained in a gas stream, and had units of cc/gram (e.g., <0.001 cc/1000 gram of SiC). Erodant material and size distribution, velocity, mass flux, angle of impact of the erodant as well as erosion test temperature and chemical environment influence erosion.
Erosion loss of cermet was measured by the Hot Erosion and Attrition Test (HEAT). Cermet specimen blocks of about 2 inch square and about 0.5 inch thickness were weighed to an accuracy of �0.01 mg. The center of one side of the block was subjected to 1200 g/min of SiC particles entrained in an air jet exiting from a riser tube with a 0.5 inch diameter where the end of the riser tube was 1 inch from the target disk. The 58 μm angular SiC particles used as the erodant were 220 grit #1 Grade Black Silicon Carbide (UK Abrasives, Inc., Northbrook, Ill.). The erodant velocity impinging on cermet targets was 45.7 m/sec (150 ft/sec) and the impingement angle of the gas-erodant stream on the target was 450��50�, preferably 45��2� between the main axis of the riser tube and the surface of the specimen disk. The carrier gas was heated air for all tests. The erosion tests in the HEAT unit were performed at 732� C. (1350� F.) for 7 hours. After completion of exposure to the erodant and cooling to ambient temperature the cermet specimens were again weighed to an accuracy of �0.01 mg to determine the weight loss. The erosion rate was equal to the volume of material removed per unit mass of erodant particles entrained in the gas stream, and has units of cc/gram. Improvement in Table 2 is the reduction of weight loss due to erosion compared to a value of 1.0 for the standard RESCOBOND™ AA-22S (Resco Products, Inc., Pittsburgh, Pa.). AA-22S typically comprises at least 80.0% Al2O3, 7.2% SiO2, 1.0% Fe2O3, 4.8% MgO/CaO, 4.5% P2O5 in wt % Micrographs of the eroded surface were electron microscopically taken to determine damage mechanisms. The HEAT test measures very aggressive erodant particles. More typical particles are softer and cause lower erosion rates. For example FCCU catalysts are based on alumina silicates which are softer than aluminas which are much softer than SiC.
70 vol % of 1 μm average diameter of α-Al2O3 powder (99.99% purity, from Alfa Aesar) and 30 vol % of 6.7 μm average diameter modified M304SS powder (Osprey Metals, 96.2% screened below −16 μm) were dispersed with ethanol in HDPE milling jar. The powders in ethanol were mixed for 24 hours with Yttria Toughened Zirconia (YTZ) balls (10 mm diameter, from Tosoh Ceramics) in a ball mill at 100 rpm. The ethanol was removed from the mixed powders by heating at 130� C. for 24 hours in a vacuum oven. The dried powder was compacted in a 40 mm diameter die in a hydraulic uniaxial press (SPEX 3630 Automated X-press) at 5,000 psi. The resulting green disc pellet was ramped up to 400� C. at 25� C./min in argon and held at 400� C. for 30 min for residual solvent removal. The disc was then heated to 1700� C. in high vacuum (10−6 torr) and held at 1700� C. for 1 hour. The temperature was then reduced to below 100� C. at −15� C./min.
The resultant cermet comprised:
Table 2 summarizes the erosion loss of the cermet as measured by the HEAT. The cermet compositions exhibited an erosion rate less than about 1�10−6 cc/gram loss when subject to 1200 g/min of 10 μm to 100 μm SiC particles in air with an impact velocity of at least about 45.7 m/sec (150 ft/sec) and at an impact angle of about 45 degrees and a temperature of at least about 732� C. (1350� F.) for at least 7 hours.
Al2O3-30 vol %
70 vol % of tabular alumina (99.4% purity, from Alcoa, 90% screened below 8 mesh) and 30 vol % of 6.7 μm average diameter M304SS powder (Osprey Metals, 96.2% screened below −16 μm) were placed in HDPE milling jar. The powders were mixed for 24 hours in a ball mill at 100 rpm without liquid medium. The mixed powder was compacted in a 40 mm diameter alumina crucible at 1,000 psi. The compacted pellet was then heated to 1700� C. in high vacuum (10−6 torr) and held at 1700� C. for 1 hour. The temperature was then reduced to below 100� C. at −15� C./min.
The resultant cermet comprised:
The ceramic particles were sized to obtain close packing as an option. In this case mesh size is used as a measurement of particle size. It is obtained by sieving various sized particles through a screen (mesh). A mesh number indicates the number of openings in a screen per square inch. In other words, a mesh size of 100 would use a screen that has 10 wires per linear inch in both a horizontal and vertical orientation yielding 100 openings per square inch. A "+" before the mesh size indicates that particles are retained on and are larger than the sieve. A "−" before the mesh size indicates the particles pass through and are smaller than the sieve. For example, −48 mesh indicates the particles pass through and are smaller than the openings of a 48 mesh (388 μm) sieve. Typically 90% or more of the particles will fall within the specified mesh. Often times, mesh size is expressed by two numbers (i.e., 28/48). This translates to a range in particle sizes that will fit between two screens. The top screen will have 28 openings per square inch and the bottom screen will have 48 openings per square inch. For example, one could narrow down the range of particle sizes in a batch of packing material to contain particles from 388 μm to 707 μm. First, sieve it through a screen with a mesh size of 28 (28 openings per square inch) which particles smaller than 707 μm to pass through. Then, use a second screen with a mesh size of 48 (48 openings per square inch), after the first mesh, and particles smaller than 388 μm will pass through. Between the two screens you would have a range in particles from 388 μm to 707 μm. This batch of ceramic could then be expressed as having a mesh size of 28/48. Table 3 shows a preferred formulation for closely packed ceramic in this invention.
Mesh Size
Micron size (μm)
Fraction (%)
70 vol % of tabular alumina (99.4% purity, from Alcoa) formulation based on table 3 and 30 vol % of 6.7 μm average diameter M304SS powder (Osprey Metals, 96.2% screened below −16 μm) were placed in HDPE milling jar. The powders were mixed for 24 hours in a ball mill at 100 rpm without liquid medium. The mixed powder was compacted in a 40 mm diameter alumina crucible at 1,000 psi. The compacted pellet was then heated to 1700� C. in high vacuum (10−6 torr) and held at 1700� C. for 1 hour. The temperature was then reduced to below 100� C. at −15� C./min.
The resultant cermet comprised:
Each of the cermets of Examples 3, 4, and 5 was subjected to an oxidation test. The procedure employed was as follows:
The thickness of oxide scale formed preferentially on binder phase was ranging about 0.5 μm to about 1.5 μm. The cermet compositions exhibited a corrosion rate less than about 1�10−11 g2/cm4�s with an average oxide scale of less than 30 μm thickness when subject to 100 cc/min air at 800� C. for at least 65 hours.
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|Citing Patent
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Owner name: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY, NEW J
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|May 21, 2010
|Fee payment
Year of fee payment: 4
|May 28, 2014
|Fee payment
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text:
New York Jets' fans and Jets' management are growing tired- very, very tired.
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text:
Vans OTW x Lupe Fiasco Stovepipe
13 December 2012, 16.00 | Posted in collabs, Sneakers | 1 comment »
The Vans OTW Collection proudly presents advocate Lupe Fiasco's signature Stovepipe colorway this holiday season. Fiasco's inspiration for this project references '90s hip-hop culture and fashion, an aesthetic he refers to as "Native Tongues". The leather kicks come with a canvas drawstring backpack and is now available at select Vans OTW Collection retailers. More looks after the jump.
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