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The most deliscious of breakfast foods, forget cereal, toast, yogurt. You must go for homestyle breakfast num nums, they look more or less like the traditional breakfast pancake, but in preperation they become truly orgasmic, some are donut shaped, some are snowman, some have bananas inside, some have jelly and butter smeared across, and some are just plain tastey.
"Man aint' nothin better than some Breakfast Num Nums after a nice sesh"
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NPE2012 lesson: Don't take clients for granted
Over the past two-plus years, much has been predicted, written and anticipated about NPE2012. It would appear that the show was quite a success, but just as important, it was a business lesson for us all.
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2010: A year in review, November
After the tsunami of gadgets that washed up on our pages over, well, the rest of the year really, November 2010 was quite a pleasant time to take a closer look at the few that were afforded a big launch that month - as well as some of the sillier news stories floating around.
On the serious side, it was a chance for the mini-Micro Four Thirds that is the Panasonic GF2 to star in one of our photo galleries along with the flagship BlackBerry Bold 9780 and the take two from HP/Palm in the form of the Pre 2. For those looking to burn money, Panasonic also brought out a £65,000, 103-inch, 3D plasma TV and Harrods came up with a way to make the Galaxy Tab even more expensive than it already was by encrusting one in crystals. In fact, it might have been that that finally made Samsung, or its retailers, see sense as prices of the gadget, sans bling, were slashed to below £500 for the first time.
Not quite on the shelves but soon soon to be in front rooms everywhere was the Virgin Media TiVo box that Pocket-lint managed to grab a sneak peak of and, finally, oh so very finally, Gran Turismo 5 actually came out. People bought it and played it and everything.
Elsewhere on the front pages, the hotly anticipated Microsoft Kinect touched down in the UK shifting units-a-plenty, Facebook revamped its Messages services into something more like e-mail and The Beatles arrived on iTunes to the largest single "meh" the world has ever seen.
Phones were on the agenda, as ever, when we caught some blurry snapshots of the next pure Android handset known as the Nexus S and trouble looked to be a-brewing for the enterprising chap on the web offering white iPhone conversions but that was nothing compared to the fate in store for anyone looking to use a DSLR in Kuwait. And last, but not least, November, as ever, was when we announced the short list for the Pocket-lint Gadget Award winners. Did you get one for Christmas?
As for that fun we promised, it was a good month for novelty HDDs with 56 years of Playboy available on one and the DeLorean from Back to the Future turned into another. Alan Partridge returned in Mid Morning Matters online courtesy of Fosters, Sir Clive Sinclair was also back with the new take on the C5 and the Queen even put herself up for a poke by joining Facebook.
Naturally, a month wouldn't be a month without some bizarre litigation of one kind or another and November was all about Nintendo trying to copyright the phrase "on like Donkey Kong". Good luck with that, and after we found the world's largest panoramic photo, we were pretty much stuck for the rest of November trying to find our houses.
And, if we're talking novelty, it was the month where Angry Birds fever really took a hold with cakes, iPhone holders and even a comedy sketch. Just as well we did an excellent series of interviews with HTC for a little balance.
And, if we're talking novelty, it was the month where Angry Birds fever really took a hold with cakes, iPhone holders and even a comedy sketch. Just as well we did an excellent series of interviews with HTC for a little balance.
At internetmatters.org parents can find all the advice they will need to keep their children safe online. Designed specifically for parents, the site offers a wealth of up-to-date, unbiased information and advice about how to deal with online safety. Parents can learn about the latest issues and technologies, get great tips on how to talk about online safety with their children and get the best advice on dealing with issues and taking action. Created with experts, Internet Matters provides detailed information, but also signposts to best-in-class resources from individual expert organisations. Our goal is to ensure parents can always access the information that they need, in a format that is clear and concise.
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A California kayaker said she got the photo of a lifetime when a pair of humpback whales came within feet of her little shell.
"It was incredible. It was a very humbling experience," Hatch said. "I was struck by how obviously sensitive and aware they are of their surroundings."
Hatch, who estimated one of the whales came within 15 feet of her kayak, said Thomae was able to snap a picture of her with one whale close in the background.
"It turned out to be a fantastic day. Better than we ever could dream of," Hatch said. "It was just a stroke of luck that he got the photo the way that he did."
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|Publication number
|Publication type
|Publication date
|Dec 30, 1975
|Filing date
|Jul 17, 1973
|Priority date
|Jul 28, 1972
|Also published as
|Publication number
|Barry Cook
|Original Assignee
|Ciba Geigy Corp
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (3), Referenced by (18), Classifications (23)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent [191 Cook [ Dec. 30, 1975 [30] Foreign Application Priority Data July 28, 1972 United Kingdom 35488/72 [52] US. Cl. 260/293.63; 260/45.8 N; 260/247.5 B; 260/293.53; 260/293.64;
[51] Int. Cl. C07D 211/30 [58] Field of Search 260/293.63, 293.66, 293.64
[56] References Cited UNITED STATES PATENTS 3,498,992 3/1970 Kuhnis et a! 260/293.86 3,640,928 2/1972 Murayama et al 260/293.64 3,850,877 11/1974 Cook 260/293.63
OTHER PUBLICATIONS CA. 76: 14 299K (1972), Leukoeva et al.
Primary Examiner-Sherman D. Winters Attorney, Agent, or FirmNestor W. Shust [5 7] ABSTRACT New piperidine derivatives and in particular esters and amides of substituted (piperidinyl-4) acetic acid are used as stabilisers for polymers, especially for polyolefines.
6 Claims, No Drawings 4-PIPERIDINE ACETAMIDE COMPOUNDS In British Patent Specification No. 1,214,426 there is described the compound having the formula:
n co cu This compound is disclosed as a starting-material for the production of 2,2,6,6-tetramethyl quinuclidine which is said to be pharmacologically active.
A Russian publication Khim. Pharm. Zl-l, 1970, 4, (10), pages 16 to 21 describes compounds having the formula:
R cH COR H 0 3 a e 3 e11 wherein (a) R is CH and R" is OCl-l (b) R is C 14 and R" is OCH (c) R is C H and R" is NH or (d) R is hydrogen and R" is H c R, I
l 1 H H wherein R, and R are the same or different and each is a straightor branched alkyl residue having from 1 to 12 carbon atoms, or R, and R together with the carbon atom to which they are attached form a cycloalkyl group having from 5 to 12 carbon atoms; R, is hydrogen, a straightor branched alkyl residue having from 1 to 4 carbon atoms, an aralkyl residue having from 7 to 9 carbon atoms or a cycloalkyl group having 5 or 6 carbon atoms; R is a metal ion or a hydrocarbyl residue having from 2 to 20 carbon atoms and being either unsubstituted or substituted by halogen or interrupted by one or more oxygen or sulphur atoms; X is O, -S, or NR wherein R has the same significance as R and n is 2, 3 or 4; as well as salts of the amine function of the compounds of formula I.
When n is 2, R may be a divalent, straightor branched aliphatic residue (either saturated or unsaturated) having from 2 to 20 carbon atoms, a divalent alicyclic residue having from 5 to 20 carbon atoms, a divalent aralkyl residue having 8 to 20 carbon atoms, or a divalent aryl residue having 6 to 20 carbon atoms.
Examples of the group R when n is 2 are 1,2-ethylene, 1,2-propylene, 1,4-n-butylene, 1,3-n-butylene, l,6-n-hexylene, 1,7-n-heptylene, l,l0-n-decylene, 1,12-n-dodecylene, 2,2-dimethyl-1 ,3-propylene, 1,2,3- trimethyl-1,4-butylene, 3-thia-1 ,S-pentylene, 3-oxal,5-pentylene, 1,4-but-2-enylene, 1,4-but-2-ynylene, 2,5-hex-3-enylene, 1,2-cyclohexylene, 1,3-cyclohexylene, 1,4-cyclohexylene, hexahydro-p-xylylene, p-xylylene, m-xylylene, l,2-phenylene, 1,4-phenylene, 2,2- biphenylene, 4,4'-biphenylene, 2,6-naphthylene and 2,7-fluorenylene.
When n is 3, R may be a trivalent straightor branched chain aliphatic (either saturated or unsaturated) residue having 3 to 15 carbon atoms, a trivalent alicyclic residue having 5 to 15 carbon atoms, a trivalent aralkyl residue having from 9 to 15 carbon atoms, or a trivalent aryl residue having 6 to 16 carbon atoms.
Examples of the group R when n is 3 are 1,2,3- trisubstituted propane, 1,2,4-tri substituted butane, 2,5-dimethyl-l ,2,6-tri substituted hexane, 1,1,1- trimethylene-propane, 1,2,3-tri-substituted cyclohexane, 1,3,5-tri-substituted cyclohexane, 1,3,5-trimethylenebenzene and 1,2,7-trisubstituted anthracene.
When n is 4, R may be a straightor branched chain tetravalent aliphatic residue (either saturated or unsaturated) having 4 to 12 carbon atoms or a tetravalent alicyclic residue having from 5 to 12 carbon atoms, such as tetramethylenemethane or 1,1 ,4,4-tetramethylene cyclohexane.
When n is 2, 3 or 4 and R is an aliphatic or alicyclic residue each of these residues may be unsubstituted or substituted by halogen or interrupted by one or more oxygen or sulphur atoms or an aryl or aralkyl residue.
When R is a metal ion, it is preferably a transitional metal ion, more preferably an ion of a metal of Group VIII of the Periodic System of Elements and especially an ion of nickel.
Examples of the groups R, and R are methyl, ethyl, n-propyl, iospropyl, n-butyl, sec-butyl, n-hexyl, n-dodecyl, or together with the carbon to which they are bound R, and R can form a group such as: I
Particularly preferred substituents R and R are straight or branched alkyl groups having 1 to 4 carbon atoms and the most preferred value for each of R and R is methyl.
Examples of the groups R and R are hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, benzyl, a-methylbenzyl, a,p-dimethylbenzyl, cyclohexyl, cyclopentyl. Particularly preferred substituents R and R are hydrogen and alkyl having 1 to 4 carbon atoms and the most preferred is hydrogen.
Examples of salts of the compounds of formula I that can be used according to the invention include salts of an inorganic acid, such as phosphates, carbonates, sulphates, chlorides and the like, as well as organic acic salts such as acetates, stearates, maleates, citrates, tartrates, oxalates, benzoates and substituted carbamic acids.
Examples of the esters and amides of formula I are given in the following list:
l,2-ethylene-di[(2',2 ',6',6',-tetramethylpiperidinyl)- 4)acetate] 1,4-butylene-di](2',2',6',6',-tetramethylpiperidinyl- 4)acetate] l, l O-decylene-di](2',2',6',6',-tetramethylpiperidinyl-4 )acetate] 1 ,4-But-2-enylene](2,2,6,6-tetramethylpiperidinyl- 4') acetate] 3-thia-l ,5-pentylene-di[(2',2',6',6,-tetramethylpiperidinyl-4)acetate] piperidinyl-4') acetate l,4-butylene-di[ 2',2',6',6',tetramethylpiperidinyl- 4)thioacetate] 1,1 ,l -tris[(2',2',6',6'-tetramethylpiperidinyl- 4' )acetoxymethyl1-propane Tetrakis[(2',2',6',6,-tetramethylpiperidinyl- 4 )acetoxymethyll-methane 4' )acetyl]ethane-l ,Z-diamine.
phenyl-l ,4-diamine.
l ,l ,4,4-tetrakis[(2',2',6,6',-tetramethylpiperidinyl- 4 )acetoxymethyl]-cyclohexane.
1 ,2-ethylene-di[2',2'-di-isopropyl-6,6-dimethylpiperidinyl-4'1-acetate N,N'-di[(2-ethyl-2'-n-propyl-6,6,-dimethylpiperidinyl-4')acetyl] butane-l ,4-diamine.
l,3-butylene-di[(2,2',6'6-tetramethylpiperidinyl- 4)acetate] 2,2,4-trimethylhexane-l ,6-di[2',2',6',6-tetramethylpiperidinyl-4' )acetate] 1 ,2-ethylene-di[a-methyl(2',2',6',6-tetramethylpiperidinyl-4 )acetate] N,N'-di[a-n-butyl(2',2',6',6'-tetramethylpiperidinyl- 4 )acetyl]-hexane-l ,6-diamine Bis[ (2 ,2 ,6 ,6-tetramethylpiperidinyl-4 )acetate Nickel II 3,5,S-trimethyl-l-[(2',2',6',6'-tetramethylpiperidinyl-4')]-3 [(2",2",6",6"-tetramethylpiperidinyl- 4 acetamidomethylene]cyclohexane 1, l 2-dodecylene-di[ 2,2 ',6 ',6'-tetramethylpiperidinyl-4') acetate] The present invention also provides a first preferred process in which a compound of formula I is produced comprising reacting a compound having the formula:
N K He 9.
wherein R R and R have their previous significance and R is hydrogen or an alkyl group having from 1 to 4 carbon atoms, with a compound having the formula:
R,(xl-l),, Ill wherein R,,, X and n have their previous significance,
The reaction may be conveniently effected with or without the use of a catalyst and a solvent. If a catalyst is used however, it may be a lithium amide, an alkali metal alkoxide, p-toluene sulphonic acid, calcium hydroxide, tetra-butyl titanate or di-butyl tin oxide. if a solvent is used, the solvent is one which is inert to the reactants and the reaction product. Suitable solvents include xylene, toluene, cyclohexane and dioxan.
The reaction is preferably carried out at an elevated temperature, for instance at a temperature within the range of from to 200C. Advantageously, the alcolhol R OH, which is produced during the reaction, is allowed to distil out of the reactor as it is formed.
if desired, the crude reaction product may be purifled, for instance by solvent extraction and by subsequent re-crystallisation from a suitable solvent, or by re-distillation.
The starting-material of formula II may be produced for example by hydrogenation of a compound having the formula:
wherein R R R and R have their previous significance.
In a second process, a compound of formula I is produced by hydrogenating a compound having the formula:
3, to X K V H c wherein R R R R X and n have their previous significance.
The hydrogenation of IV and V may be conveniently effected using molecular hydrogen or using chemical means such as lithium aluminium hydride. If molecular hydrogen is used, the hydrogenation may be conducted in known manner using a hydrogenation catalyst such as palladium, platinum, rhodium or nickel, preferably supported on a carrier such as silica, calcium carbonate or carbon. Advantageously the reaction is conducted at elevated temperature and pressure.
In a third, less preferred embodiment, a compound of formula I is produced by reacting a compound having the formula:
R -cH-Co wherein R R and R have their previous significance and Z is halogen, with a compound having the formula III as hereinbefore defined.
The reaction is conveniently effected in a solvent inert to the reactants and the reaction products. Suitable solvents include benzene, toluene, cyclohexane and dioxan. Advantageously the reaction is effected at an elevated temperature, preferably at the reflux temperature of the reaction mixture.
The starting-material of formula VI may be produced from the compound of formula II by methods wellknown per se.
Salts of the compounds of formula I may be prepared by the reaction of the free base with an organic or inorganic acid in a suitable solvent, e.g., benzene, ether or cyclohexane.
Metal salts of the compounds of formula I may be prepared by reaction of a compound having the formula:
R cH-{p A wherein R R and R have their previous significance and A is an alkali metal ion, preferably sodium, with a compound having the formula:
wherein M is a metal ion, preferably a transition metal ion, especially nickel, Z is halogen and n is 2, 3 or 4.
The reaction is conveniently effected in a solvent such as ethyl alcohol or water.
The present invention further provides a composition comprising an organic material, and, as stabiliser, a minor proportion of a compound of formula I as hereinbefore defined.
Compounds of formula I have been found to impart to polyolefines a high degree of stability towards deterioration normally induced by the effects of ultra-violet radiation or exposure to heat. Moreover, this improved stability is achieved without affecting the colour properties of the treated polyolefine. The stabilisers of the invention provide effective light and/or heat stabilisation especially for lowand high-density polyethylene and polypropylene and polystyrene as well as polymers of butene-l, pentene-l, 3-methylbutene-l, hexene-l, 4-methylpentene-l 4-methylhexene-l and 4,4-dimethylpentene-l and also coand ter-polymers of olefines, particularly of ethylene or propylene.
Other organic materials susceptible to degradation by the effects of light and the properties of which are improved by the incorporation therein of a compound of formula I include natural and synthetic polymeric materials, for instance natural and synthetic rubbers, the latter including, for example, homo-, coand terpolymers of acrylonitrile, butadiene and styrene.
Specific synthetic polymers include polyvinyl chloride and vinyl chloride co-polymers, polyvinyl acetate as well as condensation polymers derived from ether, ester (derived from carboxylic, sulphonic or carbonic acids) amide or urethane compounds; polyvinyl acetals; polyacrylates such as polymers and copolymers of methyl acrylate, ethyl acrylate, methyl methacrylate and ethyl methacrylate; polyamides; urea-formaldehyde and melamine-formaldehyde resins; cellulose plastics such as cellulose acetate, cellulose butyrate and cellulose nitrate. Certain of these polymers can, for instance, form the basis of surface coating media such as paints and lacquers having an oil or resin base, such as an alkyd or polyamide resin.
The amount of the compound of formula I which is incorporated into the organic material in order to achieve maximal protection against degradation by light varies according to the properties of the organic material treated and according to the severity of the light radiation and to the length of exposure. However, for most purposes it is sufficient to use an amount of the compound of formula I within the range of from 0.01% to by weight, more preferably within the range of from 0.1% to 2% by weight based on the weight of untreated organic material.
The compounds of formula I may be incorporated into the polymeric material by any of the known techniques for compounding additives with a polymer. For example, the compound of formula I and the polymer may be compounded in an internal mixer. Alternatively, the compound of formula I may be added as a solution or slurry in a suitable solvent or dispersant, for instance an inert organic solvent such as methanol ethanol or acetone to powdered polymer and the whole mixed intimately in a mixer; and the solvent subsequently removed. As a further alternative the compound of formula I may be added to the polymer during the preparation of the latter, for instance at the latex stage of polymer production, to provide pre-stabilised polymer material.
Optionally, the composition of the invention may contain one or more further additives, especially those used in polymer formulations, such as antioxidants of the phenol'or amine type, UV. absorbers and light protectants, phosphite stabilisers, peroxide decomposers, polyamide stabilisers, basic co-stabilisers, polyvinyl chloride stabilisers, nucleation agents, plasticizers, lubricants, emulsifiers, anti-static agents, flame-protectants, pigments, carbon black, asbestos, glass-fibres, kaolin and talc.
The present invention therefore includes binary, tertiary and multi-component compositions containing, as stabiliser, a compound of formula I together with one or more functional additives for polymers.
Examples of suitable antioxidants are those of the hindered phenol type such as those selected from the following groups:
1. Phenolic compounds having the general formula z)w l wherein Qis A is
-CR cooR") R is hydrogen or lower alkyl R is lower alkyl R" is alkyl group having from 6 14 carbon atoms w is an integer from 0 to 4. Illustrative examples of the compounds shown above are:
di-n-octadecyl-a-( 3 ,5 -di-t-butyl-4-hydroxy-benzyl) malonate di-n-octadecyl-a-(3-t-butyl-4-hydroxy-5-methyl-benzyl)malonate di-n-octadecyl-a,a'bis-(3-t-butyl-4- hydroxy-S-methyl-benzyl)malonate. 2. Phenolic compounds having the general formula Q-R"' Illustrative examples of the compounds shown above are:
2,6-di-t-butyl-p-cresol 2-methyl-4,6-di-t-butylphenol and the like 2,6-di-Octadecyl-p-cresol 3. Phenolic compounds having the formula Q w 2w Q Illustrative examples of the compounds shown are: 2,2'-methylene-bis(6-t-butyl-4-methylphenol) 2,2'-methylene-bis(6-t-butyl-4-ethylphenol) 4,4-butylidene-bis(2,6-di-t-butylphenol) 4,4-(2-butylidene)-bis(2-t-butyl-5-methylphenol) 2,2-methylene-bis[6-(2-t-methylcyclohexyl)-4- methylphenol] 2,2-methylene-bis(3-t-butyl-5-ethylphenol) 4,4'-methylene-bis( 3 ,S-di-t-butylphenol) 4,4-methylene-bis(3-t-butyl-5-methylphenol) 2,2-methylene-bis(3-t-butyl-5-methylphenol) the like. 4. Phenolic compounds having the formula:
ROQ Illustrative examples of such compounds are: 2,5 -di-t-butylhydroquinone 2,6-di-t-butylhydroquinone 2,5-di-t-butyl-4-hydroxyanisole 5. Ighenolic compounds having the formula:
S--Q. Illustrative examples of such compounds are: 4,4-thiobis-(2-t-butyl-S-methylphenol) 4,4'-thiobis-(2-t-butyl-6-methylphenol) 2,2'-thiobis-(6-t-butyl-4-methylphenol) 4,4'-thiobis-(2-methyl-5-t-butylphenol) 6. Phenolic compounds having the formula and Illustrative examples of such compounds are:
octadecyl-(3,5-dimethyl-4-hydroxybenzylthio)-acetate dodecyl-( 3 ,5 -di-t-butyl-4-hydroxybenzylthio )-propionate 7. Phenolic compounds having the formula wherein T is hydrogen R and Q as defined above.
Illustrative examples of such compounds are:
1 ,l ,3-tris( 3,5dimethyl-4-hydroxyphenyl-propane 1,1 ,3-tris(t-butyl-4hydroxy-2-methylphenyl)- butane l ,l ,5 ,5 tetrakis-( 3 '-t-butyl-4'-hydroxy-6'-methylphenyl)-n-pentane 8. Phenolic compounds having the formula:
B CH CH H B QCH C 2 3 CH CH B wherein B, B and B are hydrogen, methyl or Q, provided that when B and B are Q then B is hydrogen or methyl and when B is Q then B and B are hydrogen or methyl.
Illustrative examples of such compounds are:
l,4-di( 3 ,5di-t-butyl-4-hydroxybenzyl)-2,3 ,5,6-tetramethylbenzene l ,3,5-tri(3,5dit-butyl-4-hydroxybenzyl)-2,4,6-
trimethylbenzene 9. Phenolic compounds having the formula (Q) NH L D is alkyl group having from 6 l2 carbon atoms or I W a l Q-O N z wherein Z is O-Q, SD or S(C H )-SD. Illustrative examples of such compounds are: 2,3-bis-(3,5dit-butyl-4-hydroxyphenoxy)-6-(noctyIthio)-l ,3 ,5-triazine 2,4,6-tris-(4-hydroxy-3 ,5-di-t-butylphenoxy)- 1 ,3 ,5
triazine 6-(4-hydroxy-3,5-di-t-butylphenoxy)-2,4-bis-(noctylthioethylthio)-1,3,5-triazine 6-(4-hydroxy-3-methylphenoxy)-2,4-bis-(n-octylthio)-l ,3,5-triazine 6-(4-hydroxy-3t-butylphenoxy)-2,4-bis-(n-octylthioethylthio )-l ,3,5-triazine 6-(4-hydroxy-3methyl-S-t-butylphenoxy)-2,4-bis- (n-octylthio )-l ,3,5-triazine 2,4-bis-(4-hydroxy-3-methyl-5-t-butylphenoxy)-6- (n-octylthio)-l ,3,5-triazine 2,4,6-tris-(4-hydroxy-3methyl-S-t-butylphenoxy)- l ,3,5-triazine 6-(4-hydroxy-3,5-di-t-butylphenoxy)-2,4-bis-(noctylthiopropylthio )-l ,3 ,5-triazine 6-(4-hydroxy-3,5di-t-butylphenoxy)-2,4-bis-(ndodecylthioethylthio)-1 ,3 ,S-triazine 2,4-bis-(4-hydr0xy-3,5-di-t-butylphenoxy)-6'- butylthio- I ,3 ,S-triazine 2,4-bis-(4-hydroxy-3,S-di-t-butylphenoxy)-6-(noctadecylthio)- l ,3 ,S-triazine 2,4-bis-(4-hydroxy-3,5di-t-butylphenoxy)-6-(ndodecylthio)-1,3 ,S-triazine 2,4-bis-(4-hydroxy-3,5di-t-butylphenoxy)-6-(noctylthiopropylthio )-1 ,3 ,5-triazine 2,4-bis-(4-hydroxy-3,5di-t-butylphenoxy)-6-(noctylthioethylthio)-l ,3 ,S-triazine 2,4-bis-(4-hydroxy-3,5di-t-butylphenoxy)-6-(ndodecylthioethylthi0)-l ,3 ,S-triazine. ll. Phenolic compounds having the formula IQ zz zzl m wherein p is an integer from 2 to 4 and R' is a tetravalent radical selected from aliphatic hydrocarbons having from 1 to 30 carbon atoms, aliphatic monoand dithioethers having from 1 to 30 carbon atoms, aliphatic monoand diethers having from 1 to 30 carbon atoms and z is an integer from 0 to 6.
Illustrative examples of such compounds are Sub-class I n-Octadecyl-3-( 3 ,5di-t-butyl-4-hydroxyphenyl)-propionate n-Octadecyl-2-(3,5di-t-butyl-4hydroxyphenyl)-acetate n-Octadecyl-3 ,5 di-t-butyl-4-hydroxybenzoate n-Hexyl-3,5di t-butyl-4-hydroxyphenylbenzoate n-Dodecyl-3,5di-t-butyl4-hydroxyphenylbenzoate Neo-dodecyl-3-(3,5di-t-butyl-4-hydroxyphenyl)- propionate Dodecyl-B-( 3 ,5di-t-butyl-4-hydroxyphenyl )-propionate Ethyl-a-( 4-hydroxy-3 ,5 di-t-butylphenyl )-isobutyrate Ocatadecyl-a-( 4-hydroxy-3 ,5 -di-t-butylphenyl isobutyrate Octadecyl-a-(4-hydroxy-3,5-di-t-butylphenyl)-propionate 13 nol, benzoyl-resorcinol and 3,5-di-tert.butyl-4- hydroxybenzoic acid-2,4-di-tert.butyl phenyl ester and -octadecyl ester and -2-methyl-4,6-di-tert.butyl phenyl ester.
f. Acrylates, for instance a-Cyano-B,B-diphenylacrylic acid ethylor iso-octyl ester, a-carbomethoxy-cinnamic acid, methylor butyl ester and N-(B-carbomethoxy-vinyl)2-methyl indoline.
g. Nickel compounds such as nickel complexes of 2,2'-thiobis-(4-tert.octylphenol), for instance the 1:1 and 1:2 complexes, optionally having other ligands such as n-butylamine, triethanolamine or N-cyclohexyl-diethanol-amine; nickel complexes of bis-(4-tert.octylphenyl) sulphone such as the 2:1 complex, optionally having other ligands such as 2-ethylcaproic acid; nickel dibutyl dithiocarbamates', nickel salts of 4- hydroxy-3,5-di-tert. butylbenzyl-phosphonic acid mono-alkyl esters such as the methyl-, ethylor butyl esters; the nickel complex of 2-hydroxy-4-methyl-phenyl-undecylketonoxime; and nickel-3,5-di-tert.butyl-4- hydroxy benzoate, and
h. Oxalic acid diamides, for instance 4,4'-dioctyloxyoxanilide 2,2'-dioctyloxy-5,5-di-tert.butyl-oxanilide 2 ,2'-di-dodecyloxy-5 ,5 '-di-tert.butyl oxanilide 2- ethoxy-5-tertiarybutyl-2-ethyl-oxanilide 2-ethoxy-2'- ethyl-oxanilide mixtures of oand p-methoxy and ethoxy-di-substituted oxanilides and the compound of formula:
Phosphite stabilisers include triphenyl phosphite, diphenylalkyl phosphites, phenyl dialkyl phosphites, trinonylphenyl phosphite, trilauryl phosphite, trioctadecyl phosphite, 3,9-di-isodecyloxy-2,4,8,lO-tetraoxa-3,9-diphosphaspiro-(5,5)-undecane and tri-(4- hydroxy-3,5-di-tert.butylphenyl)phosphite.
Peroxide-decomposing compounds for polyolefins include esters of B-thiodipropionic acids, for instance the lauryl-, stearyl-, myristylor tridecyl esters, salts of mercaptobenzimidazoles such as the zinc salt and diphenylthiourea.
Suitable polyamide stabilisers include copper salts in combination with iodides and/or further phosphorus compounds and salts of bivalent manganese.
Basic co-stabilisers are, for example, polyvinylpyrrolidone, melamine, benzoguanamine, triallyl cyanurate, dicyandiamide, urea derivatives, hydrazine derivatives, amines, polyamides, polyurethanes, alkali and alkaline earth salts of higher saturated or unsaturated fatty acids such as calcium stearate.
Polyvinyl chloride stabilisers include organotin compounds, organo lead compounds and Ba/Cd salts of fatty acids.
Examples of nucleation agents are 4-tert.butyl benzoic acid, adipic acid and diphenylacetic acid.
As with the compound of formula 1, any further additive is advantageously employed in a proportion within the range of from 0.01% to 5% by weight, based on the weight of untreated organic materials.
Some Examples will now be given. Parts and percentages shown therein are by weight unless otherwise stated.
EXAMPLE 1 18.2 Parts by weight of ethyl (2,2,6,6-tetramethylpiperidinyl-4) acetate, 2.7 parts by weight of butane-l 4-diol and 1 part by weight of lithium amide, were heated at 160C/76O mmHg for 30 minutes and then at 160C/12 mmHg for a further 5 minutes. The resulting mass was cooled and treated with 200 parts by volume of water the resulting crystalline solid was filtered, dissolved in 30 parts by parts by volume of water. The solid was collected by filtration and dried at 60C/12 mmHg to give butylene-l ,4-di[(2,2,6,6'-tetramethylpiperidinyl-4')-acetate] melting at 30C. and having the following elemental analysis by weight:
17.2 Parts by weight of ethyl(2,2,6,6-tetramethylpiperidinyl-4) acetate, 1.4 parts by weight of pentaertythritol, and 1 part by weight of lithium amide were heated together with stirring at c/760 mmHg for 1 hour, then at 160C/12 mmHg for a further 1 hour. The resulting mass was cooled to room temperature, and poured into 100 parts by volume of water, this was then extracted with 4 X 50 parts by volume of ether. The combined ether extracts were dried over magnesium sulphate and the ether removed by distillation. The residual oil was dissolved in petroleum ether (boiling range 6080C.), decolourised with active carbon, and the petroleum ether was removed by distillation at 100C/12 mmHg, to give tetrakis [(2,2,6,6-tetramethylpiperidinyl-4)acetoxymethyl]methane, n 1.4653 having the following elemental analysis by weight:
18.2 Parts by weight of ethyl(2,2,6,6-tetramethylpiperidinyl-4) acetate, 3.5 parts by weight of 1,6- diamino hexane, and 3.6 parts by weight of sodium methoxide were heated at 160C/760 mmHg for 2 hours. The resulting mass was cooled and triturated with 100 parts by volume of petroleum ether (boiling range 6080C.) to give a white solid, this-was collected by filtration, placed in a soxhlet extraction funnel and continuously extracted with ethyl acetate (100 parts by volume). By filtration of the cooled ethyl acetate a white solid was obtained of pure N,N'-di [(2',2',- 6,6-tetramethylpiperidinyl-4 )'-acetyl] hexane-1,6-diamine (containing 1 molecule of ethylacetate entrained in the crystals) melting at 103C. and having the following elemental analysis by weight:
EXAMPLES 4 to s 38 parts of polypropylene were homogenised with 0.076 parts of n-octadecyl-B-(4'-hydroxy-3,5-t-butylphenyl) propionate in a kneading machine over a period of 3 minutes. 0.19 parts of the product of Example 1 was then added and homogenisation continued for another 7 minutes.
The homogenised mixture was removed from the kneader and pressed to a thickness of from 2 to 3 mm.
111 a press.
9 parts of the polypropylene mixture were then charged into a second press in which the press-plates were protected by aluminium foil having a thickness of 0.1 mm. The press was closed and, for 2 minutes, no pressure was applied. The pressure was then increased up to a maximum of 12 tons and this pressure held for 6 minutes, the temperature of the press being 260C. The pressure was released and the material (0.3 mm thick) was cooled under running water.
This material was cut into from 3 to pieces of 35 X 35 mm section and re-charged to the press. The press was closed and no pressure was applied for 2 minutes. Over another 2 minutes the pressure was increased to 8 tons, the press temperature being 260C. This pressure was maintained for 2 minutes and then the pressure released. The polypropylene foil of 0.1 mm thickness was removed and tempered immediately in a circulating air oven maintained at 150C over a period of 60 minutes.
A section measuring 44 X 100 mm was separated from the 0.1 mm tempered polypropylene foil and exposed to light irradiation in a fademeter device consisting of a circular bank of 28 alternating sunlight and blacklight lamps. The sunlight lamps were 2 feet long, 20-watt fluorescent lamps characterised by a peak emission of 3100 Angstrom units; the blacklight lamps were 2 feet long, 20 watt ultraviolet lamps characterised by a peak emission of 3500 Angstrom units. The sample was' rotated concentrically about the bank of lamps so that the radiation therefrom was uniformly distributed over the section under test.
The exposed sample was examined periodically, when portions of it were removed for tenicle testing and the time (T) required for the elongation of the sample to decrease to 50% of the initial elongation was determined.
The time (Tc) required for the elongation of a control sample (not containing the product of Example 1 to decrease to 50% of the initial elongation was then determined.
The performance of the compound of Example 1 as a light stabiliser could then be assessed by determining the factor T/Tc.
The results obtained including the use of other compounds of the invention as stabilisers are set out in the following Table:
TABLE-continued Additive Factor T (for compound) Tc (for control) Example Control 1 acetoxymethyl methane 6 N,N'-Bis(2,2,6,6-
tetramethyl piperidinyl-4 acetyl) Hexane 1,6-diamine 7 Ethane-l ,2-di[ 2 2,6',6'-tetramethylpiperidinylA') acetate tetramethyl piperidinyl-4') acetyl] ethane-1, Z-diamine EXAMPLE 9 C H N Found 68.05 10.76 13.13 Required for C, H., N O 68 .20 10.97 13.26
EXAMPLE 10 A mixture of 34 parts by weight of ethyl (2,2,6,6-tetramethylpiperidinyl-4) acetate, 3.1 parts by weight of ethanediol and 1 part by weight of lithium amide was heated with stirring from room temperature to 160C. over a period of 1 hour. The temperature was maintained at 160C. for a further 30 minutes during which time ethyl alcohol was allowed to distil from the reaction flask.
The resulting mixture was cooled to room temperature and poured into parts by volume of water, the water was extracted with diethyl ether (4 X 50 parts by volume). The combined ether extracts were dried over magnesium sulphate and the ether was removed by evaporation to give a colourless oil which was purified by distillation to give 1,2-ethylenedi[(2,2,6,6-tetramethylpiperidinyl-4) acetate] boiling at 188-90/0.3 mm. and having the following elemental analysis by weight:
EXAMPLE 1 1 A mixture of 13.8 parts by weight of ethyl (2,2,6,6- tetramethylpiperidinyl-4) acetate, 2.6 parts by weight of 2-butene-l-4-diol and 0.5 part by weight of lithium amide was heated at 160C. for 1 hour. Ethyl alcohol, produced during the reaction, was allowed to distil from the reaction flask during this time. The suspension was then cooled and poured into 100 parts by volume of water, the product was extracted with ether, the combined ether extracts were dried over magnesium sulphate and the ether removed by evaporation. Distillation of the residue gave pure l,4-but-2-en-di[(2',2,- 6',6'-tetramethylpiperidinyl-4')acetate], boiling at 2l0C./0.2m.m. and having the following elemental analysis by weight:
C H N Found 69.10 10.28 6.44% Required for 69.29 10.29 6.22% 2fi 4fi 2 4 EXAMPLE 12 C H N Found 72.03 11.31 4.72% Required for 72.29 11.42 4.96% 14 64 2 4 EXAMPLE 13 A mixture of 18.2 parts by weight of ethyl (2,2,6,6- tetramethylpiperidinyl-4) acetate, 4.2 parts by weight of diethyleneglycol and 0.5 part by weight of lithium amide was treated as in Example 1 l to give 3'-oxa-l '-pentylene di [(2,2,6,6-tetramethylpiperidinyl-4 )acetate], boiling at 206-208C./0.3 m.m. and having the following elemental analysis by weight:
C H N Found 66.60 10.53 5.68% Required for 66.63 10.32 5.98% C2GH1BN2O5 EXAMPLE 14 A solution of 2.4 parts by weight of nickel chloride hexahydrate in 40 parts by volume of methyl alcohol was added to a stirred solution of 4.4 parts by weight of sodium [(2,2,6,6-tetramethylpiperidinyl-4)acetate] (prepared by the hydrolysis of ethyl [2,2,6,6-tetramethylpiperidinyl] acetate in dilute sodium hydroxide) in 80 parts by volume of methyl alcohol at reflux temperature. The solution was heated at reflux for a further 4 hours, then cooled and the insoluble removed by filtration. Methyl alcohol was removed by distillation under reduced pressure and the green solid residue was extracted with 100 parts by volume of chloroform. A small amount of insoluble material was removed by 18 filtration and the solution was then evaporated to dryness to give a green solid nickel salt, having the follow ing elemental analysis by weight:
Carbon 44.05% Hydrogen 7.44% Nitrogen 4.80% Nickel 16.5 5%
I claim: 1. A compound of the formula wherein R and R are the same or different and each is a straightor branched alkyl residue having from 1 to 12 carbon atoms or R and R together with the carbon atom to which they are attached, form a cycloalkyl group having from 5 to 12 carbon atoms,
R and R is independently hydrogen, a straightor branched alkyl residue having from 1 to 4 carbon atoms, or aralkyl residue selected from benzyl, amethylbenzyl or 04-, p-dimethylbenzyl, or a cycloalkyl group having 5 or 6 carbon atoms,
R, is a divalent hydrocarbyl residue. having from 2 to 20 carbon atoms and being either unsubstituted or substituted by halogen or interrupted by one or more oxygen or sulphur atoms, or a salt of the amine function thereof.
2. A compound according to claim 1 wherein R and R are each methyl.
3. A compound according to claim 1 wherein R and R are each hydrogen.
4. A compound according to claim 1 wherein R is a divalent straight.- or branched aliphatic residue either saturated or unsaturated having from 2 to 20 carbon atoms, a divalent alicycllc residue having from 5 to 20 carbon atoms, a divalent aralkyl residue having from 8 to 20 carbon atoms or a divalent aryl residue having from 6 to 20 carbon atoms.
5. A compound according to claim 1 which is N,N'- bis-[(2,2,6,6'-tetramethyl-piperidinyl-4)-acetyl]- hexane-l ,6-diamine.
6. A compound according to claim 1 which is N,N'- bis-[(2', 2,6,6'-tetramethyl-piperidinyl-4')-acetyl]- ethane-1,2-diamine.
|Cited Patent
|Filing date
|Publication date
|Sep 29, 1967
|Mar 3, 1970
|Geigy Chem Corp
|Substituted 1,2,3,6-tetrahydro-4-pyridine acetic acid amides
|Jun 5, 1969
|Feb 8, 1972
|Sankyo Co
|Stabilization of synthetic polymers
|Jul 17, 1973
|Nov 26, 1974
|Ciba Geigy Corp
|Piperidine stabilizers for polymers
|Citing Patent
|Filing date
|Publication date
|Jul 17, 1973
|Jul 27, 1976
|Ciba-Geigy Corporation
|Piperidine derivatives
|Mar 18, 1976
|Dec 20, 1977
|American Cyanamid Company
|Light and heat stabilizers for polyolefins
|Sep 22, 1975
|Jan 17, 1978
|Ciba-Geigy Corporation
|Metal salts of hindered piperidine carboxylic acids and stabilized compositions
|May 4, 1977
|Jul 25, 1978
|Ciba-Geigy Corporation
|Modified polyurethanes with increased light stability
|Dec 5, 1975
|Oct 31, 1978
|Ciba-Geigy Corporation
|Stabilizer system for stabilizing styrene polymers
|May 19, 1976
|Dec 26, 1978
|Sankyo Company, Limited
|Stabilization of poly(mono-olefins)
|Nov 13, 1978
|Nov 4, 1980
|Ciba-Geigy Corporation
|Polymeric light stabilizers for plastics
|Nov 16, 1978
|Nov 11, 1980
|Ciba-Geigy Corporation
|Polymeric light stabilizers for plastics
|Nov 7, 1978
|Nov 11, 1980
|Ciba-Geigy Corporation
|Polymeric light stabilizers for plastics
|Nov 29, 1978
|Nov 18, 1980
|Ciba-Geigy Corporation
|Polymeric light stabilizers for plastics
|Dec 4, 1978
|Nov 18, 1980
|Ciba-Geigy Corporation
|Polymeric light stabilizers for plastics
|Nov 28, 1978
|Feb 10, 1981
|Ciba-Geigy Corporation
|Polysilylesters having a polyalkylpiperidine as part of the polymer useful as light stabilizers for plastics
|Dec 4, 1978
|Apr 7, 1981
|Ciba-Geigy Corporation
|Polymeric light stabilizers for plastics
|Nov 14, 1978
|Apr 7, 1981
|Ciba-Geigy Corporation
|Polymeric light stabilizers for plastics
|Aug 5, 1980
|Nov 10, 1981
|Ciba-Geigy Corporation
|Polymeric light stabilizers for plastics
|Jul 20, 1981
|Jan 18, 1983
|American Cyanamid Company
|Hindered amine light stabilizers for polymers
|Mar 4, 1997
|Jan 12, 1999
|The Yokohama Rubber Co. Ltd.
|Rubber composition for tire
|Jul 16, 1979
|Aug 26, 1980
|American Cyanamid Company
|Light and heat stabilizers for polyolefins
|U.S. Classification
|546/190, 546/16, 524/103, 544/130, 546/238, 546/248, 546/237
|International Classification
|Cooperative Classification
|European Classification


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MathKnight and Zachi Evenor
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Realistic Motion Blur to Create a Speeding Car Effect in Photoshop
One of the more difficult tasks in Photoshop has long been to make a car look like it is moving at a significant rate…Read More
One of the more difficult tasks in Photoshop has long been to make a car look like it is moving at a significant rate…Read More
When you are building a composite image, you have to ensure that each of the objects in your composite have a perspective that matches…Read More
In this tutorial, we will take a photo of a car on the street and cut it out and move it over to a…Read More
Vanishing Point in Photoshop is an amazing set of tools that allows us to determine the perspective of an image and then build a…Read More
In this Photoshop CC tutorial, we'll take a look at the power of the Color Range tool in Photoshop. We will look at selecting…Read More
It's all about Grow and Similar today in this tutorial about putting a new sky into your photo. We'll talk about how to select…Read More
Well, you know it had to happen. Fat-shaming or not, we had to talk about making a girl thin in Photoshop using the Liquify…Read More
Camera RAW Filter. This filter allows you to edit any image or graphic in your PSD with the Camera RAW editor. Changing light, color,…Read More
Join my mailing list and I'll send you a free Photoshop course with 30 of my favorite time-saving tips and tricks in Photoshop! Of all the subscribers in the world, tutvid.com subscribers might be the best the best of them all.
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Sounds Like: Wilson Philips
Bio: Hello!
Camaraderie is a three person harmonious acoustic band based in the Bay Area. We specialize in playing covers of popular songs heard on the radio. We've been playing everywhere from open mic nights and restaurants to gigs as big as last years Global Winter Wonderland.
We are currently wor...See Full Bio


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Otolaryngologist (ear, nose, throat)
46 years of experience
46 years of experience
3136 W Club Dr
Salem, VA 24153 Phone number & directions
Salem, VA 24153 Phone number & directions
License & Identifications
A medical license is required for a doctor to practice medicine in a particular state. Requirements vary by state but most require, at a minimum, post-graduate training in the doctor's specific specialty. An NPI number is a national identifier unique to an individual health care provider and is managed by the Center for Medicare & Medicaid Services (CMS).
Learn more about Dr. Jon Hagadorn:
View the full profile to get information on:
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Prepare before visiting Dr. Hagadorn
Face Lift Patient Education Read about facial cosmetic surgery treatments in our face lift patient education guide.Before Visiting Dr. Hagadorn Learn More
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Home Allergies
Seasonal Allergies
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Dr. Jon Hagadorn, MD is board certified in Otolaryngology.
Education & Awards
Dr. Hagadorn graduated from Albany Medical College.
Home > Find an Otolaryngologist > VA > Salem Otolaryngologists > Dr. Jon Hagadorn, MD
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- Additional Information
- Dr. Jon Bruce Hagadorn MD is a male Otolaryngologist, has 46 years of experience and practices in Otolaryngology.
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Dr. Jon Hagadorn practices Otolaryngology near Salem, VA.
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Research Methods in Physical Education and Youth SportThis is the first research methods book to focus entirely on physical education and youth sport. It guides the reader through the whole research process; from the first steps to completion of a dissertation or practice-based project, and introduces key topics such as: formulating a research question qualitative approaches quantitative approaches mixed method research literature review case
Critical Inquiry and Problem Solving in Physical Education
Working with Students in SchoolsCritical inquiry, critical thinking and problem-solving are key concepts in contemporary physical education. But how do physical educators actually do critical inquiry and critical thinking? Critical Inquiry and Problem-Solving in Physical Education explains the principles and assumptions underpinning these concepts and provides detailed examples of how they can be used in the teaching of
Workplace Learning in Physical Education
Emerging Teachers' Stories from the Staffroom and Beyond
Routledge Studies in Physical Education and Youth SportPre-service and beginning teachers have to negotiate an unfamiliar and often challenging working environment, in both teaching spaces and staff spaces. Workplace Learning in Physical Education explores the workplace of teaching as a site of professional learning. Using stories and narratives from the experiences of pre-service and beginning teachers, the book takes a closer look at how
Young People, Physical Activity and the Everyday
Routledge Studies in Physical Education and Youth SportDespite society's current preoccupation with interrelated issues such as obesity, increasingly sedentary lifestyles and children's health, there has until now been little published research that directly addresses the place and meaning of physical activity in young people's lives. In this important new collection, leading international scholars address that deficit by exploring the differences in
Learning and Teaching in Higher Education'This book provides teachers in higher education with what they need - a compelling framework for improving student learning. It combines a comprehensive synthesis of the latest research on learning and teaching with practical strategies for implementing it in their classrooms' - Professor Ken Bain, Author of What the Best College Teachers Do, Vice Provost for Instruction, Montclair State
Professional Development in Higher Education
A Theoretical Framework for Action ResearchThis study offers a theoretical framework for professional development in higher education and examines the priorities for teachers' careers in the 1990s. It may be used as a companion volume to the author's work, "Action Research in Higher Education".
Young People's Voices in Physical Education and Youth Sport
Routledge Studies in Physical Education and Youth SportHow do children and young people experience and understand sport and physical activity? What value do they attach to physical education and physical literacy? This important new book attempts to engage more directly than ever before with the experiences of young people by placing the voices of the young people themselves at the centre of the discussion. As the need to listen to young people
$54.89This rewritten, expanded and updated 7th edition of the long-running bestseller Research Methods in Education encompasses the whole range of methods currently employed by educational research at all stages. It offers plentiful and rich practical advice, underpinned by clear theoretical foundations, research evidence and up-to-date references. Chapters new to this edition cover: Causation,
Developing classroom practices that workPersistently cheeky, disruptive, even aggressive boys can be found in classrooms everywhere, as can the victims of bullying. These boys' behaviours often pose a problem to themselves as well as to others. As the hotly contested debates about boys' education swirl around them, what can teachers actually do to improve boys' performance in the classroom?Teaching Boys provides a practical framework
A Guide for Social Science Students and ResearchersWhy use qualitative methods? What kinds of questions can qualitative methods help you answer? How do you actually do rigorous and reflective qualitative research in the real world? Written by a team of leading researchers associated with NatCen Social Research (the National Centre for Social Research) this textbook leads students and researchers through the entire process of qualitative


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Digital Organising - Mobilising Communities Through Digital Tools
This is a 2 hrs course followed by a 1 hour webinar. The course shows you how to use digital tools to engage with communities. In this course you will:
- Discover examples of where communities have brought about change through using digital tools
- Explore a selection of tools avaialble to enegage with communities
- Consider the different language that should be used depending on the tool being used
- Develop an action plan to continue your learning after the training session
The 1 hour webinar will see you come together 4 weeks after the course to share ideas and troubleshoot any issues.
- Date and Time
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StartPoint Training Room
4 Woodley Precinct
Stockport, United Kingdom
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Akron, OHUSA
December 24, 2012
My name is Marge. I was widowed earlier in this year. My daughters are grown and on their own. I feel ready to socialize and meet new people.
Meetup members, Log in
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C3 SoftWorks Launches PRONTO! - Quick Games to Engage any Audience
January 24, 2012
PRONTO! is an energizing platform to engage your audience and get your training off to a great start! Featuring four games that will energize any training environment with multi-team, question-based adventures that involve pirate battles, castle sieges, grand prix-style car races, and rockets to the moon.
Minneapolis-St. Paul, MN-WI (1888PressRelease)
January 24, 2012
- January 15, 2012-C3 SoftWorks, a leading software provider in the training and educational markets, is pleased to announce the release of PRONTO!
"We know that audience engagement is the first step in effective training and we're confident that PRONTO! can be that catalyst. It's a powerful tool, with a user-friendly interface, that will enhance training, both in the classroom and/or online." - Paul Michaelson, C3 SoftWorks' CEO.
PRONTO! is an energizing platform to engage your audience and get your training off to a great start! Featuring four games that will energize any training environment with multi-team, question-based adventures that involve pirate battles, castle sieges, grand prix-style car races, and rockets to the moon, PRONTO! is a template-based software program that is as elegant in design as it is easy-to-use. PRONTO! includes challenges that incorporate fun, interactive game play and action sequences, giving you a powerful tool to present your training content.
PRONTO! works with wireless keypads, smart phones (iPhones, iPads, Android, Blackberry), laptops and tablets. Each keypad sends important data back to you, so you know what they know instantly! Use PRONTO! via a LIVE webinar (with PING software) or deliver it through the web and report scores to any LMS.
C3 SoftWorks designs educational training game software. Engaging every learner is the first step toward effective instruction and is the guiding principle behind every product we produce. You'll see evidence of this in our easy-to-use training games, which provide you with an interactive game board template platform to effectively deliver your content. With over 25+ years of involvement in education and training, we bring a deep understanding of the instructional challenges you face. Whether you're teaching in the classroom, or over the web, our customizable training game software will help you present your content in the most engaging way.
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When Warren-based, food-business incubator Hope & Main went live last October with 30 entrepreneurs, founder Lisa J. Raiola likened the experience to "giving birth to 30 babies." Over the past year, Raiola estimates more than 50 businesses … more
By Eli Sherman | firstname.lastname@example.com | 10/9/15
The latest power tool in the landscaper's shed has four legs and an insatiable appetite. Goats have become an increasingly popular choice for clearing ivy, vines and underbrush on farms, in parks and in residential areas, making them a … more
By Mary MacDonald | firstname.lastname@example.com | 10/9/15
In 2012, Michael Brown sailed into the Pacific to see for himself what decades of ocean-tossed trash piles contained. The debris field, he said, was filled with plastics. "I went out to see it," he said. "Let me run my fingers through the … more
By Mary MacDonald | email@example.com | 10/9/15
The University of Massachusetts Dartmouth is planning to relaunch and re-brand its innovation incubator in Fall River on Oct. 23. more
By Patricia Daddona
Despite an overall reduction in the number of taxpayer-backed loans made in Rhode Island last fiscal year, small business loan dollar volume grew 2.8 percent thanks largely to an increase in financing for fixed assets, such as real estate and machinery. more
By Eli Sherman
Saying no is tough. That's especially true when those doing the asking are offering help to those less fortunate. But that's exactly what some local nonprofits have to do during the holiday season. "When people ask, we do the best … more
BY Rebecca Keister | Contributing Writer | 10/30/15
When Todd Monjar and Collette Royer met on Match.com two years ago, they shared not only a romantic interest but an idea for creating a meaningful artistic startup. By May of the following year, Monjar, a photographer and entrepreneur, … more
By Patricia Daddona | email@example.com | 10/15/15
Two years ago, Rhode Island joined other New England states in setting a goal of producing 50 percent of its food by 2060. It's an ambitious goal, since at present only about 1 percent of the food now consumed in the state is grown within its … more
| 10/15/15
Debt is a dual-edged sword. For some, it is the bane of economic health. And yet in business, as in personal finance, taking on debt often finances growth, acquisition and activity. Think of mortgages to buy homes or loans to develop a commercial … more
R.I. Commerce Corp. has launched a website focused on developing the Latino business community in Rhode Island. more
By Mary MacDonald


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Chris Powell Makes Fitness A Family Affair
Chris Powell from "Extreme Makeover: Weight Loss Edition" gets his kids in on the workout.
Secrets for Your Best Beach Body from Jessica Simpson's Trainer
Celebrity trainer Harely Pasternak shares his tips for getting in shape for the summer.
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Item #11666
Product Description
Our Cask and Crown Personalized Tray is large in scale and style. Features a hefty steel outer ring and laser engraved personalization. Handles for easy lifting.
Product Details
Leo Iron Drum Table
Was: $249.00
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Leaves Solar Lantern
Was: $39.00
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Barrel Stool
Linked Coin Garden Stool
Regency Trays - Set of 2
Was: $109.00
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Re: Levisa 'Talley' HOLLINGSWORTH, Samuel M. MATHEWS
In reply to:
Levisa 'Talley' HOLLINGSWORTH, Samuel M. MATHEWS
Nelda Conant 12/22/10
I'm not related, but did some looking
I agree that John D is most likely the son of Samuel M.
Along with birth place correlations and migration similarities, there is a round-about census tie
1860 Houston, TX
Mathews, S M [L M] 51 SC
Luisa[levisa] 27[47] GA
E A. 24 AL female
Mary 22 AL
William 18 AL
Robert 16 AL
Lockwood 10 male AL[Francis Lockwood] ********
Coronitia [Cordelia] 8 AL
Nancy 6 AL
1880 Houston TX
Mathews S M 71 SC
Levisa 67 GA
Burson, Mary L. TX gr dau
same household-new family
Mathews, F L 30 AL SC GA*********
Elizabeth J. 24 TX
Jessie May 4 TX dau
Willie C. 1 TX dau
in 1900 Francis Lockwood Mathews is living with John Duke and shown as his brother.
1900 Angelina, TX
Mathews, John 68
Sarah 62 wife
Ryan, Willie E. 20 gr dau
Mathews, Francis L. 50 Brother married**********
I have found nothing to support Levisa being a Hollingsworth, or any other maiden name.
Hope this helps.
More Replies:
Re: Levisa 'Talley' HOLLINGSWORTH, Samuel M. MATHEWS
Nelda Conant 12/31/10


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Around the Circle: Fresh Perspectives on Abstraction at Solomon R. Guggenheim Museum
212-423-3500 guggenheim.org/aroundthecircle $15
This event has already taken place. Click here for the latest events.
With Guggenheim Educators Filip Noterdaeme and Paula Stuttman.
These after-hours tours offer lively opportunities for the public to engage with New Harmony: Abstraction between the Wars, 1919-1939. The first presents an artist's point of view and the second considers how conversation with museum educators shapes the viewing of classics from the Guggenheim collection. Both programs are followed by an exhibition viewing of New Harmony and a reception.
Each session: $15, $10 members, $5 students and interns with valid ID (limited capacity). For tickets and more information, visit guggenheim.org/aroundthecircle.
Venue Description: Celebrated worldwide as one of the most noteworthy art museums and architectural icons of the 20th century, the Guggenheim Museum is all together an essential cultural center, an educational institution, as well as the heart of an international network of museums. Frank Lloyd Wright's iconic inverted ziggurat leads visitors through a series of interconnected rooms and requires them to retrace their steps when exiting. Visitors can experience special exhibitions of modern and contemporary art, lectures by artists and critics, performances and film screenings, classes for teens and adults, and daily tours of the galleries led by experienced docents. Founded on a collection of early modern masterpieces, the Guggenheim Museum today is an ever-increasing institution devoted to the art of the 20th century and beyond. Through extraordinary exhibitions, education programs, research initiatives, and publications, the Solomon R. Guggenheim Foundation achieves its mission of promoting the understanding and appreciation of modern and contemporary art and architecture, and the collection, conservation, and observation of the art of our time.
The Solomon R. Guggenheim Museum is located on the Upper East Side at 1071 Fifth Avenue (at 89th Street) and is open Sundays to Wednesdays from 10am-5:45pm, Fridays from 10am to 5:45pm, and Saturdays from 10am to 7:45pm. The Museum is closed on Thursdays and Christmas Day. Admission into the museum is $22 for adults, $18 for students and seniors (65 years and older) with valid ID. Children under twelve may enter free of cost. The museum is wheelchair accessible except for the High Gallery, located at the top of the first ramp, accessible by two low stairs. The first and second rotunda ramps offer partial views of the High Gallery. The last tickets are issued at 7:15pm.


text: Early signs CIOs believe cloud pays for itselfHoward Solomon - October 9, 2012Cloud computing in its many guises has been around long enough for CIOs to get a rough idea whether there's a return on investment. The feeling — proven by its soaring growth — is that services like Salesforce are a no-brainer. But what about everything else? If you can generalize from a survey of 20 chief information officers, apparently it's thumbs up — with some reservations.As this story from Forbes details, U.S. consulting firm Navint Partners recently surveyed a small group of CIOs from Fortune 500 companies about their experience with cloud services. Most were pleased. Within the story there's also a link to the white paper. (Image from Shutterstock) The results suggest that management worries about cloud's ability to save their organization money can be quickly overcome. Interestingly, the Navint report notes that survey respondents — who were largely American-based CIOs — still ranked security as the top concern (above compliance and integrity), and affirmed data security and privacy as the number one barrier to both public and private cloud adoption. Despite highly advanced security and fraud countermeasures employed by cloud vendors, the report says, CIOs and other executives regard security guarantees and redundancy policies with guarded pessimism. Canadian CIOs feel the same way,I learned, at a recent conference I covered. Cloud still has a way to go. Related Download Sponsor: Acquia Gartner Magic Quadrant for Web Content Management 2015 Download this Magic Quadrant report to learn more about the WCM market and help evaluate vendors based on your specific needs Register Now Leadership Canadian cio, cloud security, cloud services, computing canada


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Unto Thee Tulip Poster - Mini
Unto Thee Tulip Full Color Poster...Makes a Great Addition to Any Home, Office, or Church. Small Enough to Put Anywhere...Size is 5x7 & Laminated. Saying...To Thee O Lord, I Lift My Soul.
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text: Arts Centre Melbourne's $10 million turnaround Print Email Email to a friend Your email Your name Friend's email Friend's name Verification (type the code in the image) Generate New Image Close Related Articles Art you have to be sick to see Public hospitals across Australia hold significant art collections putting some of our most significant artists to work as remote therapists. Riding the political roller coaster Artists and arts organisations need to have the ear of government but getting too close to the Arts Minister of the day can cause a backlash when a new Pharoah arises. Avoiding the over-promisers Even the most successful crowdfunding campaigns can over-promise and under deliver. $12,000 residencies in Asia up for grabs Four different models across 13 countries make the latest Asialink residencies versatile opportunities as catalysts in all kinds of arts careers. (Premium content) Premium content Deborah Stone Thursday 18 September, 2014 After a dismal 2013, Arts Centre Melbourne has delivered a dramatic volte-face to come out in profit. This content is only available to members of ArtsHub Subscribe Now for instant access! A subscription to ArtsHub will enable you to: Access the most comprehensive jobs board for the arts sector, with hundreds of positions posted weekly Learn how and where to get grants, with the most extensive grant finder in the arts industry Monitor Australian art sales and trends with our Auction Tracker Post, manage and monitor your social media campaigns using our extensive social media toolkit Optimise your website for search engines using our auditing service Promote yourself and your career to the largest arts community in Australia by uploading your professional profile Gain an understanding of salaries within the Australian arts industry, by accessing our Salary Survey Access thousands of subscriber-only features, articles and guides Take advantage of exclusive ticket giveaways, offers and competitions Save hundreds of Dollars every year on cinema tickets, magazines, books, travel, shopping and more with the Member Rewards scheme ... and much, much more. Subscribe Now and be part of the Australian arts community Member login Email address Password Forgot password? About the author Deborah Stone is Editor of ArtsHub.


text:
The Dish
All the News That's Fit to Eat
By Laura Marrich
Signing for Her Supper—Friend and former Alibi Food Editor Gwyneth Doland can add one more notch to her crumb-speckled belt, as she's just become a published cookbook author! The book is Cilantro Secrets (Rio Nuevo, paperback, $12.95), which she'll launch at a signing event on Thursday, July 27, at Jennifer James' Gulp (3128 Central SE, 268-4729). From 5:30-8:30 p.m., the girls next door (that is, the Graze chefs) will prepare a selection of herby snacks from the book, offered to the guests of Ms. Doland at no extra charge. Settle into a cilantro mojito and pick Gwyn's brain about mole, the subject of her next book in the Cook West single-ingredient series. Oh, and buy a book. She's got a pile of cilantro-inspired grocery receipts that aren't paying for themselves. "I will write anything on the title page of that book if you pay me $12.95," she says. Cash or check are perfectly acceptable.
Wes Naman
First Taste
Happy Returns
O'Niell's Pub is back
By Laura Marrich
At 7:30 p.m., people begin to stand two bodies deep at the bar, popping out through knuckles of space like olives in a fist. It's an impressive draw for a weekend night, let alone a Thursday. It's just short of amazing when you consider that this particular bar opened one week ago.
Tabatha Roybal
Restaurant Review
Rabieng Thong
Yes, that's their real name
By Jennifer Wohletz
Rabieng Thong? What's in a name, anyway? I can recall my school years like they were yesterday, and I don't think I had a single teacher who ever pronounced my last name correctly without a linguistic tutorial beforehand. I got some pretty festive variations like "Whirlitz," "Whoo-letz" and my personal fave, "Whore-letz." It's Wohletz (Wall-letz), dammit. So I know how the cats at Rabieng Thong feel. It's hard to have name recognition when people keep jacking it up.
EVENT HORIZON (Saturday, Oct 8)
Apples, Pumpkins, Autumn, Oh My!
Third Annual Apple and Pumpkin Fest
By Desiree Garcia
Apple picking and orchard tours, fresh apple cider, hay rides, choose a pumpkin from the pumpkin patch, green chile roasting, ristras, live entertainment and more.
NEWSLETTERS Great Alibi stories, events and deals delivered to your inbox each week. No fooling!
Today's Events
20th Annual Downtown Growers' Market at Robinson Park
Uptown Growers' Market at ABQ Uptown
Dine and Glow at Anderson-Abruzzo Albuquerque International Balloon MuseumMore Recommended Events ››
Mishka Shubaly • 10.4.2016
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BlackBerry For Dummiesby Robert Kao, Dante Sarigumba
View All Available Formats & Editions
The popular BlackBerry is used by millions of office workers and executives and has become an essential business tool. Now with an even faster and more efficient 6.0 operating system, the newest BlackBerry devices have the potential to become pocket-sized replacements for the/b>
- LendMe LendMe™ Learn More
Just what you need to know to take full advantage of your new BlackBerry smartphone
The popular BlackBerry is used by millions of office workers and executives and has become an essential business tool. Now with an even faster and more efficient 6.0 operating system, the newest BlackBerry devices have the potential to become pocket-sized replacements for the laptop. This fifth edition of the most popular BlackBerry guide explores all the features of the new BlackBerry and its upgraded OS.
It covers setting up the device, organizing and managing your appointments and to-do list, accessing the Internet, handling e-mail, working with multimedia, synching your BlackBerry with your desktop, adding apps, and much more.
- The BlackBerry is the most popular handheld device for business users; an updated 6.0 operating system is being introduced for new models with an upgrade available for certain older models
- This edition of the popular BlackBerry guide covers the new OS, setting up your BlackBerry, organizing and managing your calendar, handling e-mail, and accessing the Internet
- Explores working with multimedia and taking great photos with your BlackBerry
- Offers tips and shortcuts plus information about managing power usage, synching your BlackBerry to your desktop, and taking advantage of the expandable memory, as well as great apps you can add
Wise advice from BlackBerry experts makes this the guide you need to get the most juice from your BlackBerry.
Editorial Reviews
Product Details
- 9781118153062
- Publisher:
- Wiley
- Publication date:
- 08/15/2011
- Series:
- For Dummies Series
- Sold by:
- Barnes & Noble
- Format:
- NOOK Book
- Pages:
- 408
- File size:
- Note:
- This product may take a few minutes to download.
Read an Excerpt
Meet the Author
Robert Kao develops applications for the BlackBerry and writes extensively on using the device. Dante Sarigumba is a gizmo enthusiast and software developer with vast experience programming for the BlackBerry platform. They are coauthors of several For Dummies books on the BlackBerry.
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Although the Tour isn't included in this book, it still works for this model. I upgraded to my BB Tour after having a Palm Treo 800w & needed a resource to guide me thru the MANY apps & functions--and not being Windows-based like the Treo, things weren't as "normal" as I was used to. This book proved very helpful. Many of the teeny-tiny icons of indiv keys throughout the book are difficult to see/read, but that didn't make for a negative experience. I'm a very visual person, so I would liked to have seen more pictures, but it wasn't a big deal really. Overall I'm very happy with this book & wouldn't be as adept with using my new favorite gadget as I am without it! Kudos to the authors. Worth the $18 member price paid.
Blackberry for Dummies by Robert Kao and Dante Sarigumba gives you a very basic introduction to the Blackberry, but it left me still wanting more. The book covers the built in Smartphone functions, such as contacts, calendar, to dos, phone and browser. It also covers multimedia features such as the camera, music, video and GPS. The part of tens, a feature of the "For Dummies" series, reviews Blackberry accessories, applications, games and websites optimized for viewing on a mobile phone. In conclusion, Blackberry for Dummies is a great starter manual for Blackberry users who need basic information on where to begin and what to do. If this is your first Blackberry, then this is the book for you. I had to go onto the web to find more technical and advanced help for the Blackberry such as www.blackberry.com forums, www.cranberry.com and RIM's site.
Truly written for "dummies" but not in a bad way! Easily understandable and well organized.


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