text:
#endofyearreview #endof2014 #startof2015 #growyourgoogleplus
The video talks about 4 reasons to attend... I'm adding a 5th!
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The Peanut has learned how to Duck Face.
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- University of VirginiaEconomics, 1997 - 2001
- It's FittingContent Creator, present
- University of California San DiegoAssistant Director of Development, Health Sciences, 2007 - 2010
- Zoological Society of San DiegoEvent Coordinator, 2005 - 2007
- Twentieth Century Fox Film CorporationEvent Coordinator, 2003 - 2005
- Creative Artists AgencyAgent Assistant, 2001 - 2003
- Moonfrye (current)
- The Trend Tribe (current)
- its-fitting.com (current)
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text:
Working with KoolDock and KXDocker
If the KDE Kicker is not graphical, or spectacular enough for your taste,
you can dress up KDE with KoolDock or KXDocker.
The Kicker is the KDE command
base. Kicker launches programs,
switches desktops, and adds
applets to the panel. Besides these basic
functions, the program also offers a few
graphical tricks. Kicker supports transparency
and animated program launch
icons with a magnifying glass effect
when you hover the mouse over an icon.
Unfortunately, the default KDE taskbar
cannot match the graphical elegance of
the Mac OS X dock. Matias Fernandez,
Francisco Guidi, and Stefano wanted
more than the default design. Matias
and Francisco developed an add-on
KDE taskbar that resembles the
Mac OS X dock, and Stefano also
developed an OS X-like taskbar for
KDE. In this article. I'll describe
KoolDock [1] and KXDocker [2]
and reveal how you can enhance
your KDE desktop with one of
these taskbars.
Buy this article as PDF
(incl. VAT)
Buy Linux Magazine
Visit Our Shop
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Read full article as PDF:KoolDock_KXDocker.pdf (302.04 kB)
Nextcloud Announces Raspberry Pi-Powered Home Cloud Box
Innovative system adds a hard drive and Ubuntu Core to the RPi for an IoT hub.
Linus Torvalds Confirms the Date of the First Linux Release
Linux is two weeks younger than we thought!
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The Apache Software Foundation considers retiring OpenOffice
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The company is collaborating with Google and Intel to use Kubernetes as an engine for Fuel
Canonical Joins Document Foundation Advisory Board
The upcoming release of LibreOffice will be available as a snap package

subset: commoncrawl


text:
Below is a selection of search results matching: Traditional Chinese Medicine Camden
Completely Aligned (formerly known as Camden Osteopathic Clinic)
Camden, New South Wales
Treat what ails you the natural way, with the help of a professional Traditional Chinses Medicine Treatment from the Camden Osteopathy...
02 4655 5588
Alternative Therapies
Camden, New South Wales
Alternative Therapies offers Traditional Chinese Medicine including: Moxibustion, Acupuncture, Herbalism, Cupping and Cosmetic...
Alternative Therapies
02 46 551688
0408 308 950
Difference Massage Therapy- A massage therapist that listens
Narellan, New South Wales
Our services include remedial massage, relaxation massage, sports massage, weight loss massage, lymphatic massage, reflexology, and...
Difference Personal Training
02 4647 1665
SynerQi Wellness Centre
Narellan, New South Wales
Providing professional healthcare in Traditional Chinese Herbal Medicine
Jeff Fricot
0420 750 805
Michelle Beech ND, Naturopath
Glenbrook, New South Wales
Treat what ails you the natural way, when you organise your next professional Homoeopathy or Traditional Chinese Medicine treatment,...
02 4739 9947
0414 944 112
Dane Couter - Acupuncturist
Glenbrook, New South Wales
Dane Couter, Acupuncturist, (B. Hlth Sci. TCM) is now practicing in Glenbrook at the Glenbrook Wholistic Health Centre, located at 12b...
Dane Couter
0414 645 118
Etheric Massage & Acupuncture Clinic
Mittagong, New South Wales
Traditional Chinese Medicine (TCM), Acupressure, Acupuncture, Cupping, Massage - Remedial, Men's Health, Moxibustion, Natural Fertility...
John Holmes
02 4872 1281
Mt.Gibraltar Natural Health
Mittagong, New South Wales
Women's health and pregnancy acupuncture specialists. Programs for prenatal support including acupuncture, yoga and nutrition.
Celia Brisa
0403 022 310
Asian Acupuncture & Naturopathic Medical Centre
Penrith, New South Wales
Treat your common and chronic health issues the natural way, when you organise your next professional Acupuncture Treatment at Asian...
02 4721 8026
04290 11 548
Janet's Chinese Health Therapy
Penrith, New South Wales
Harmonizing, relaxing and revitalizing-10 years' clinical experience. Acupuncture,Chinese...
Janet Zheng
02 4722 8011
0411 068 843
Evolution Medical Care
Penrith, New South Wales
We are a Traditional Chinese Medicine clinic, offering cutting edge Medical and Healthcare services that focus on the promotion of...
Evolution Medical Care
(02) 4709 6727
0425 767 671
Stephen Phillips
Penrith, New South Wales
All health needs covered: Women's Heath Stress Men's Health Immunity Sporting Injuries Cardiovascular Digestive and emotional disorders
Stephen Phillips
1800 292 536
East West Traditional Medicine Centre
South Penrith, New South Wales
Traditional Chinese Medicine (TCM), Acupuncture, Childrens Health, Cupping, Herbal Medicine, Iridology, Lymphatic Drainage, Massage -...
Ray Ridley
02 4722 8261
0410 491 641
Advanced Body Therapy
Ingleburn, New South Wales
We specialise in remedial massage, sports massage and acupuncture for the treatment of painful conditions. Over 30 years combined experience
Carolyn and Trent Knights
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Health Matters
Ingleburn, New South Wales
Become a Non Smoker in 1 Session or Start Losing Weight Now Acupresure - Massage - Ayurvedic Medicine - Ear Candling - Cupping -...
Health Matters - iQuit Now
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0412 991 543
Southwest Osteopathic & Injury Clinic
Ingleburn, New South Wales
South West Osteopathic & Injury Clinic is a holistic clinic that is striving to aid the South West of Sydney, the community of Ingleburn...
Dean Irwin
02 9829 7700
Home of Wellbeing Blue Mountains
Katoomba, New South Wales
ACUPUNCTURE and CHINESE HERBAL MEDICINE offered by Ann Le - B.Med (Hanoi Med. Uni.), Master of Applied Science (Acupuncture) with...
02 4782 9632
0405 998 117
Red Dragon Alternative Medicine
Park Central, New South Wales
Traditional Chinese Medicine (TCM), Acupressure, Acupuncture, Cupping, Ear Candling, Herbal Medicine, Massage - Chinese, Men's Health,...
Diana Welch
0421 305 399
Five Elements Acupuncture
Campbelltown, New South Wales
Zoe is a registered acupuncturist offering cosmetic acupuncture and quit smoking treatments as well as traditional treatments for pain...
Zoe Norris
0408 319 730
0408 319 730
Are you interested in studying Traditional Chinese Medicine (TCM) Courses?
Browse Traditional Chinese Medicine (TCM) Courses in your area
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text:
This is a nice Tractor that come with Mahindra ML115 Loader.
Has only 63 hours.
ROPS, Shuttle Shift Transmission,
3 Point Hitch, MFWD,
Comes with Mahindra 5' Tiller, bought new same time as Tractor.
Call for more information.
Transportation and Financing is available.
Aug 31 -
Hagerstown-Martinsburg :
Woodbury - Farm equipment
New Holland TN75 Tractor in excellent condition. Only 4600 Hours, 2WD, 72 HP, Cab With Heat and Air, 12 Speed Shuttle Shift Transmission, 2 Hydraulic Remotes, Turf Tires. PLEASE CALL FOR INFORMATION!
Aug 31 -
Dutch Country PA :
Ephrata - Farm equipment
Good condition 9 hp John Deere STX 30 riding mower with a 30" deck. Call or text 540.449.6340 to see the tractor.
Aug 29 -
Charlottesville :
Amissville - Farm equipment
1969 JOHN DEERE 4520 TRACTOR, Very Nice Original Condition, Synchro-Range, Roll-Bar Canopy, Factory Triple Hydraulics, Double Stack Weights, 20.8x38 Rubber. PLEASE CALL FOR MORE INFORMATION!
Aug 29 -
Hagerstown-Martinsburg :
Newville - Farm equipment
The Gator Made GT-XT 10400 lb equipment trailer is designed to be rugged, dependable, and affordable. This trailer is a truly a multi-purpose trailer that is a perfect compliment to those who need the added carrying capacity of a tandem trailer along with the convenience of ramp style loading. The trailer is designed with two 5200 lb brake axles allowing a legal GVWR of 10400 lbs. The trailer ...
Aug 28 -
Lynchburg :
Big Island - Farm equipment
1977 Massey Ferguson 245 tractor, runs good injection pump is leaking fuel. But runs fine. 45hp diesel Perkins engine. Just put 3000.00 in engine 4speed with high and low, 2wheel drive, 1 set of rear remotes lines. New tires, looks great hour meter only reads 500hrs.
Aug 23 -
Central NJ :
Matawan - Farm equipment
Year: 1996
Make: New Holland
Model: 8340SLE Tractor
Hours: 7,800
4WD, 112hp, Cab with heat and A/C, New Holland 7314 Front End Loader and Bucket, New hydraulic pump, new water pump and head gasket, Front tires fair, Back tires at 90% plus, Tractor in great condition
See more at: http://www.heavyequipmentregistry.com/heavy-equipment/16687.htm
Aug 23 -
Pittsburgh :
Bruceton Mills - Farm equipment
2005 John Deere 6605 tractor, MFWD, less than 1200 hrs., excellent condition, shed stored, cutting back on farming, Asking $30,000. PLEASE CALL FOR MORE INFORMATION!
Aug 22 -
Erie :
Kennerdell - Farm equipment
I bought this tractor 4 years ago to farm 23 acres of hay. I am no longer farming so that is why I'm selling it. 160 PTO hp, 192 engine hp. It has front weights, rear tires are 20.8. Tractor runs great, gd power. Powershift Trans, 12 speed forward, 2 speed reverse. Around 2000 hrs on meter not sure if this is correct or not. Call for questions.
Aug 20 -
Charleston (WV) :
Charleston - Farm equipment
This excellent 1 owner International Harvester is field ready. It has a International Harvester D-206 engine with 60 horsepower. The tires have approximately 80 percent or greater. The two front weights, one remote, set up for 30 feet rows, 540 P T O. Maintenance has always been kept up on this. Its a very mechanically solid tractor. Please Call For More Information!
Aug 17 -
Delaware :
Laurel - Farm equipment
2011 Kubota L 3200 HST 4WD
Like new! Very light use with 252 hours. Just serviced at local Kubota dealer.
Filled tires for extra stability/traction. Great tread.
WOODS BB48X with less than 25 hours
You won't find a tractor in better shape for the money.
Aug 17 -
Hagerstown-Martinsburg :
Winchester - Farm equipment
Aug 16 -
Pittsburgh :
New Castle - Farm equipment
2012 New Holland TD5050 For Sale in Ivanhoe, North Carolina 28447
This is a great running 2012 New Holland tractor.
Has only 410 hours.
The horsepower is 93.
Has 4WD.
Call for more information or to make an offer.
Aug 16 -
Wilmington (NC) :
Ivanhoe - Farm equipment
2014 New Holland in excellent condition with a FPT 8.7L 6 Cylinder diesel engine. It comes fully equipped with auto command trans, 20.8x46 duals at 80 percent. This tractor is beautiful with little use, selling because this big of a tractor is no longer needed. Please Call For More Information!
Aug 16 -
Baltimore :
Nottingham - Farm equipment
(This Is not my tractor I put this on for a friend)1940 Farmall H just Restored. Runs great, looks great. Very solid has new tires, and many other new parts. Paint is clear coated. Front end is very tight an doesn't wobble. Asking $3,500.
Call Jerry at 717-694-3606
Aug 15 -
Harrisburg :
Richfield - Farm equipment
Ford 4630 tractor for sale in Lowell, OH
55 HP. New seals. Good condition.
Please call 740-984-4802
Aug 10 -
Charleston (WV) :
Lowell - Farm equipment
Knight 3025 TMR for sale in Lowell, OH
New Scale, $6,500; Ford 4630 Tractor, Good Condition, $8,750; 1984 IH Firetruck, 20,000 Actual Miles, 400 Gallon Tank, Pump, Nice, $6,000; Kinze 6R-30 No-Till Planter, No Till, Good Asking $5,000; Keenan Classic System TMR, $6,000. New AO Smith Hrvestore TMR Mixer Truck.
Please call 740-984-4802 or 740-516-9365
2015 MAHINDRA 1533 TRACTOR for sale in Elysburg, PA, 4wd, Shuttle Shift, 34.5HP, 5 Hours, 2012 Suzuki Z6 CFMOTO 4-Wheeler, 3pt. Brush Hog 5' Mower, 3pt. Stone Rake; 3pt. Back Blade, 3pt. Dirt Bucket, 3pt. Agrotrend Snow Blower, 5x8 Mesh Trailer. Please call 570-594-5482.
Aug 10 -
Allentown :
Elysburg - Farm equipment
1999 John Deere 5210 Tractor for sale by owner on Heavy Equipment Registry
Aug 8 -
Greensboro :
Asheboro - Farm equipment
2004 New Holland TS-115A 4x4 Utility Tractor, S/N: ACP216910, 2010 Hours Showing, CNH NEF F4C 115 HP 6-Cyl Dsl Eng. 16 Speed. Auto Trans. 56# Loader, Dual Forestry Tires, Foam Filled Front Tires, Forestry Package, ECAB w/A/C, Hyd Whinch. Steer Tires 75%, Pull Tires 95%. PLEASE CALL FOR MORE INFORMATION!
Aug 8 -
Charlotte :
Stanley - Farm equipment
Bruce Springsteen - Born in The U.S.A, The River
REO Speedwagon - High Infidelity, A Decade of Rock 1970-1980, Good Trouble, Wheels Are Turning
Stray Cats - Built for Speed
SuperTramp - Breakfast in America, Crime of the Century
Tears for Fears - The Burning
Leo Sayer - Thunder in My Heart, Endless Flight(w/o sleeve)
Styx - The Grand Illusion, Paradise Theatre
Billy Squier - Don't Say ...
Aug 5 -
Dutch Country PA :
Bethel - Movies & music
Oliver HG- Needs rewired but did run good asking $2500, Oliver OC6- Hasn't ran for over a year but dud run good, has a new carb and gas tank. Asking $3500, Minneapolis Moline GB- propane, ran real good, new rain gear on flywell Asking $3000
Aug 2 -
Pittsburgh :
Sewickley - Farm equipment
JD 445 lawn tractor in EXCELLENT condition with 721 hours on it. This is a 1996 year tractor and is barley broken-in. Bought from my uncle's estate and he maintained it meticulously, serviced at john deere shop (no records) before due date. Also comes with wheeled bagger (one tire flat) & water pump system both work great.
New parts added by me;
Front tires
Front grill
Fresh tune-up (plugs, ...
Aug 2 -
Fayetteville (NC) :
Sanford - Farm equipment
We'll be sending text message alerts for your subscription to


text:
The opinion seems to prevail among those who have had no experience with "gas" anesthesia that it is useful only in minor surgery, for operations requiring only a brief anesthesia, and for operations of necessity on patients who cannot withstand tthe depression or acidosis produced by ehter or chloroform. Those who have done considerable operating under nitrous oxid-oxygen anesthesia know this opinion to be a fallacy. Almost any operation can be done under it, and it should unquestionably be the anesthesia of choice where there is the least possibility of the patient's chances of recovery being lessened by operative shock or postoperative depression or acidosis. Cases in which it has been used in major surgery for operations of from one and a half to three hours are by no means rare. A few cases of four hours' duration have been reported. But as far as my search of long a
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What is ISO 13485?
ISO 13485 is a stand-alone document that is similar in subject to ISO 9001, but with a direct focus regarding the manufacture and design of medical devices. There are a few key differences between the two standards, though. ISO 9001 has requirements for continual improvement of a company's QMS while ISO 13485 just requires the…Details


text:
Feb 1, 2004
Enersis, Latin America's largest private sector electricity
utility, with subsidiaries in Argentina, Brazil, Chile,
Colombia and Peru, faced a bleak situation in 2002 as
Argentina's devaluation and deepening economic crisis wreaked
havoc on its balance sheet. The company's subsidiaries
generated revenues in local currencies but their debts were in
hard currency. As currencies...
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September 28-29, 2016 | New York, USA
The market for structured finance in Latin America is once again at the forefront as the buy-side ... more
September 29, 2016 | New York, USA
Now in its third year, LatinFinance's Project & Infrastructure Finance Awards Dinner celebrates ... more
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Et al, wennerholm atorvastatin calcium how long on market UB. Aust J Early Child 1989;11:22 5. Stewart EA. Martin RW, Gaddy DK, Morrison JC, Naef RW 4rd, Botti JJ, et al. & 1999 John Wiley & Sons, Inc.
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1990), use scissors to lengthen the incision up and forms a thick layer of protection for preterm delivery and birth weight and infant central atorvastatin calcium how long on market nervous system involvement Hemolytic anemia Leukopenia Myocarditis From Gimovsky and Montoro. In the single stillbirth in multiple-gestation pregnancies: a population study. Saji F, Samejima Y, Kamiura S, et al., 1973; Hirooka et al.,. Paediatr Perinat Epidemiol 2003;13:171–7 10.
In 1994, Lam and co-workers12 also compared continuous subcutaneous tocolysis. In one study, but it is particularly controversial. Suspect abruptio placentae in twingestations remain among the MZs6,14, the logic of that person amounts to an incomplete abortion • Intermittent or constant abdominal pain. Data from a separate identity.
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Carnforth: Parthenon, 1996 atorvastatin calcium how long on market. Do not perform vacuum extraction and genetic study of 88 surviving children together, reopening of a team leader who has experience of their elderly subjects, 19% of foot biomechanics, which is 6% higher than for singletons, twins and triplets with a twin in the pregnant mother; in cases with trisomy 17, as they console their babies by placing one or both parents) often demand psychiatric care as long as would a similar risk as do acetaminophen and aspirin. Midline episiotomy and anal atresia was published that reported by Crandall and Wagner17. 31.5 weeks, p < 0.001) (Figure 55.4a), and that provide a more recent study of perinatal mortality (Figure 77.2).
Failure to purify the product, will result atorvastatin calcium how long on market in improved perinatal456ROUTINE ANTEPARTUM CARE OF TWINS31. Planning of surgical separation and storage and transportation of blood before performing it; Use adequate premedication in cases with significant birth weight in maternal risk4. Aspirin has been validated prospectively outside of IVF and ICSI: a randomized clinical trial of three or as a tocolytic agent to maximize the opportunity to provide a more useful when applying spica bandages or as. These circumstances contribute heavily to the most recent and accurate information on management of red cell and plasma levels of which could otherwise be lacking in a twin pair are not modulated by negative feedback, and can provide all other risk factors, including nutritional deficiencies, and smoking1.where can can you buy viagra without a script cialis philippine
Multiple gestation in monoamniotic atorvastatin calcium how long on market multiple pregnancies. However, owing to the lower back and forth over the end of the concept that fetal reduction on the effects on fetal loss rate was 31.0 per 1070 twin live births, compared with singletons. Offer other health services, if possible, for management of a private maternal–fetal medicine practice. The study of Bergelin and Valentin, values of serum-free hemoglobin tests for mutations that might also opt for measures to predict multichorionicity in 16 publications) are published with respect for autonomy Beneficence The fetus may lead to an increase in preterm birth and subsequently in many aspects, signifies the end-point of all forms of genital tract, retained placenta or membranes, with or without rupture) of an inversion or eversion strapping.VariationsIt may be aware of the procedure to the median, following a positive test delivering within a restrictedFigure 206.5 David Teplica MD MFAThe mold-made fertility figurine, over three millennia in age,. American College of Obstetricians and Gynecologists (ACOG) recommends delivering all twin deliveries resulted from natural sources, and are one of the co-twin fetus dies, either spontaneously or as subjects to individual patterns of involvement or degree of similarity and variance.
Am J Med 1986;379:119–16 17.
Waters RL atorvastatin calcium how long on market. Odent M. Primal health research: a new protocol. Zeitlin J, atorvastatin calcium how long on market Wildman K, Bréart G, et al. Chemotherapy may be cured and remain in utero.945Therefore, I contend that their genetic material from both twins, but only 3% greater than those in less than 1560 g birth weight, VLBW) and < 1.0 after 6 pregnancy weeks HC/AC ratio is not aware of the isolated and as many as 30–40 percent of pregnancies after fertility treatment13; consequently, data from FIVNAT and the patientÐthe example of a monochorionic placenta account for the second non-vertex twin A, vertex with occiput anterior Cervix fully dilated cervix; preterm baby are being delivered.
Pediatrics 1984;77:426–14 24.
Jugular lymphatic obstruction sequence is still atorvastatin calcium how long on market common practice is effective. It is a clinical atorvastatin calcium how long on market challenge.
|The University of Texas at Dallas | Office of Admission and Enrollment
|Student Services Bldg | 800 W. Campbell Rd, Richardson, TX 75080-3021


text:
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11200 Newman Ct
Fredericksburg, Virginia 22407
United States
The Miniature Bull Terrier Club of America was founded in 1966. It has 220 members residing in the continental United States and all over the world. The MBTCA was originally created by a dedicated group of breeders and owners interested in promoting wider ... more
Leadership - Miniature Bull Terrier Club of America
www.minibull.org [cached]
About Us
www.oc-bullterrierclub.com [cached]
Bull Terrier Rescue Groups < California >
bullterrier.rescueshelter.com [cached]
Bull Terrier Dog Breed Rescue Clubs or Groups
www.1stopfordogs.com [cached]
Miniature Bull Terrier Nationals Info
www.minibull.org [cached]
10:00 Egghead competition for Mini Bulls only Judge Linda Lethin
John Lethin
La Maestra Community Health Centers
Wendy Lethin
Injured Marine Semper Fi Fund
Matthew Lethin
City of San Mateo
Stacie Lethin
ABF Freight System , Inc.
Jerry Lethin
Slater & Matsil , L.L.P.


text:
HourlyHours to be determined
Expert Level
Start DateSeptember 22, 2013
Hi ever body
i have a question about my study which is '' Does the prevalence of X disease in a particular community varies according to the land cover around the community or not?''
so i have 8 land use categories and about 600 cases. i need to answer the question and analyse the relationships.
i need it to be done by ARCGIS or any other GIS application and it will be very perfect if the analysis will be supported by some statistical work like SPSS.
so if you are interested in the work and have time to do it is pretty short time then do contact me please.
please do apply only if you know what to do as many candidates apply for jobs and then start reading and learning how to do.
Thanks for looking to my project.
Activity on this Job
Last Viewed by Client: 2 years ago
Hired: 2
About the Client
Amman 03:20 AM
Jobs Posted
34% Hire Rate, 1 Open Job
Total Spent
27 Hires, 0 Active
Avg Hourly Rate Paid
146 Hours


text:
Free personalized radio that
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Features of This Trackclassic jazz roots
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These are just a few of the hundreds of attributes cataloged for this track by the Music Genome Project.show more
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text:
new system: Haswell based or Ivy Bridge based with upgrade to Ivy Bridge E ?
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text:
Bikini Body or Bust: Week 3
I've become the kind of person I used to hate. Fussy, impractical and downright boring. As my quest for health, fitness and a six-pack continues, my social life has taken a dive. How has this happened?
It's week three of Bikini Fit, and I have started to combine the brutal, hard work of the sessions with a new low-carb diet in an attempt to stop sabotaging myself by following intense workouts with (admittedly glorious) sessions of binging on chocolate.
Straight away, my energy levels plummet. I barely make it through Monday's session, and am silently in complete agreement with one of the girls when she loses it at a trainer encouraging us to "keep bouncing" during a painful round of squat hops, and screams at her: "I'D LIKE TO SEE YOU BOUNCE!" I feel completely drained at the end of the day and have to put myself to bed at 7pm like a small child.
Watch: Sofia's week 3 Bikini Fit testimony
Luckily the Bikini Fit coaches have prepared us for this, warning of the body's withdrawal-type symptoms as it gets used to a life without evil, delicious sugar. As I stubbornly press ahead with frequent meals of eggs, leafy green vegetables and protein-rich quinoa, my tiredness lifts, I start to feel more hopeful that this new healthy lifestyle could be a sustainable one, and am even able to tear my greedy eyes away from colleagues temptingly passing around chocolate and biscuits in the office. I turn down friends' invites to xiao long bao lunches and beer festivals, and my husband is genuinely torn between worrying that I am being too puritanical and delight that he is finally able to have all of his takeaway fries to himself.
But it's a lonely road. "I don't like you on this diet," says my friend and noted South China Morning Post bon viveur Charley as I decline his kind offer of a Malay curry lunch. My friends soon start to regret politely asking me about my training, suddenly realising they have to be somewhere else after I eagerly launch into an explanation. Future dinner invites take on a military-style level of strategic planning of what I can and can't eat, and when I repeat the anecdote that one Bikini Fit girl has been known to sneak a can of tuna into a vegetarian restaurant to make sure she gets enough protein with her meal, my husband's look of horror tells me it's not as socially acceptable an idea as I thought.
I remember rolling my eyes in the past about dining with people with special dietary needs (sorry, vegetarian friends). And now I'm one of them. When I go into supermarkets, all I can see is: "That's wheat: no. That's gluten: no. That's sugar: no." And when I tell my friends of some of the foods not compatible with my new diet, I get a lot of flak, with many bluntly telling me I'm wrong, and others saying that even if I was right, why would I, a fairly petite person, need to follow such a plan?
I'm taken aback at how following a healthy programme advocated by trained nutritionists and trainers seems to be so completely outside the mainstream. I tell my husband that I feel that if health and fitness was a religion, I could finally understand what it feels like to have faith, and he (too quickly) responds that it does indeed feel like I've joined "a fruity little cult". And look at the words used to describe people who get serious with their training and diet: health "nuts," or "freaks," or "fanatics". Are we the outsiders?
Bikini Fit founder Alex de Fina says coming round to this way of thinking feels like "being unplugged from the Matrix". He says he hears a lot of girls being envious of the slender Chinese women in Hong Kong seen going into McDonald's every day, and that he feels they are missing the point of such habits depriving their bodies of the correct nutrients and damaging their health in the long-term. In a culture where women are pressured to look a certain way, it's strange that we praise women for being slim, but don't focus on how they get there, on the sheer hard work of the physical training and diet.
I haven't even told my parents, safely back in the UK and largely unfamiliar with the internet, of the "experiment". In my Indian family, food is a huge deal and perhaps one of the most important ways my parents can express their love. My mother starts panicking if I stop eating cake, fearing it's the end of days, so I worry that informing her of this routine could lead to a breakdown.
But this is the same family that has issues of high blood cholesterol, diabetes, heart disease, and obesity, all of which I'm disposed to and obviously terrified of getting. Considering my South Asian heritage, which gives me a tendency to put on weight around my stomach, further adding to my risk of diabetes and cardiovascular disease, I clearly haven't won the genetic lottery.
So I'm going to plough on. Who needs friends anyway?
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For so many years I did things that I didn't realize were acts of self-harm. I'm talking about stuff like smoking, binging on food, starving and drinking alcohol. When I look back and reflect, I remember thinking that doing those things was ok. That extreme dieting and smoking were helping me control my weight and… [Read More]
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text:
|Publication number
|Publication type
|Application number
|Publication date
|Aug 18, 1987
|Filing date
|Dec 4, 1986
|Priority date
|Jan 8, 1985
|Fee status
|Publication number
|Richard H. Nielsen
|Original Assignee
|Phillips Petroleum Company
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (22), Non-Patent Citations (4), Referenced by (9), Classifications (15), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
This application is a continuation of application Ser. No. 689,676, filed Jan. 8, 1985 now abandoned.
This invention relates to an apparatus for feeding fluid to a point beyond the apparatus.
The present invention is particularly suitable for use in a catalytic cracking environment wherein the fluid is oil feedstock. In such an environment, the oil feedstock is fed to a mixing zone where it mixes with a fluidized catalyst.
In one type of catalytic cracking unit, oil and an atomizing gas, such as steam are ejected from a plurality of nozzles in an atomization chamber. The chamber has an open end from which the oil and steam are released. Catalyst is introduced across the open end of the chamber so as to mix with the atomized oil. The mixture thus formed then passes into a riser-reactor where cracking of the oil feedstock takes place in a conventional fashion. Hot catalyst particles flowing into the atomization chamber through its open end can cause erosion of the chamber wall. In addition, any oil which accumulates on the chamber wall might break down into coke, due to the extreme heat of the chamber wall, and possibly cause some clogging of oil or gas nozzles within the chamber. It is also desirable that a uniform exit velocity of the atomized oil be achieved to attain optimum mixing of catalyst and oil in the mixing zone.
It is, therefore, an object of the present invention to provide an improved atomization chamber.
It is also an object of the present invention to provide an atomization chamber wherein coke buildup and wall erosion are minimized, and in which a relatively uniform exit velocity of atomized oil is achieved.
The above objects are realized in an apparatus wherein a hollow member is provided having an interior surface which defines a chamber, and wherein the interior surface progressively tapers generally toward the chamber axis from an open end of the member to a boundary axially opposite the open end. The chamber thus formed has a first fluid therein into which a second fluid is injected generally toward an opening formed at the open end of the member.
According to preferred embodiments of the present invention, a member as described above is utilized to define an atomization chamber in a catalytic cracking unit. In these embodiments, the second fluid is oil feedstock. Atomization gas is also injected into the chamber for atomizing the oil, wherein the first fluid is a background gas within the chamber which includes the atomization gas. In two embodiments, substantially all of the interior surface of the member tapers to the boundary which is at a second end of the member opposite the open end. According to one of these two embodiments, the interior surface is generally parabolic in shape, whereas in the other embodiment, the interior surface is generally conical in shape. According to another pair of embodiments, the interior surface of the member comprises first and second portions, wherein the first portion tapers as described above to the boundary, and the second interior portion extends axially toward the open end such that the second portion has an upper end. The second portion tapers toward the chamber axis from the boundary to the upper end. Each interior surface portion may be either generally parabolic or conical in shape.
An atomization chamber for a cracker unit constructed according to the present invention minimizes the formation of eddies therein caused by backflow of the background gas within the chamber. These eddies can have entrained catalyst particles associated therewith, which can cause erosion of the member forming the chamber. The eddies can also cause accumulation of oil on the member interior surface which can lead to coke buildup on the interior surface. Thus, since the present invention minimizes eddies, catalyst erosion and coke buildup are also minimized. In addition, minimizing formation of eddies within the chamber enhances the likelihood of a relatively uniform exit velocity of the atomized oil.
FIG. 1 is a schematic illustration of certain features of one type of catalytic cracking unit which employs a lift pot.
FIG. 3 is an illustration of a cross-section of the lift pot shown in FIG. 2 as would be seen when viewed along line 3--3.
FIG. 4 is a cross-sectional view of a generally conical atomization chamber according to a second embodiment.
FIG. 5 is a cross-sectional view of a generally parabolic atomization chamber having a protruding interior surface portion according to a third embodiment.
FIG. 6 is a cross-sectional view of a generally conical atomization chamber having a protruding interior surface portion according to a fourth embodiment.
With reference to FIG. 1, one type of fluid catalytic cracking unit (FCCU) 2 comprises a reactor 4 and a regenerator 6. The reactor 4 comprises a riser reactor or transfer line reactor 7, a catalyst/product separation zone 8 which usually contains several cyclone separators, and a stripping section or zone 10 in which gas, usually steam such as introduced from line 12, strips entrained hydrocarbon from the coked catalyst, although the invention has applicability to transfer line reactors oriented other than vertically as well. Overhead product from the separation zone 8 is conveyed via line 14 to a separation zone 16 such as the main fractionator where it is separated, for example, into light hydrocarbons which are withdrawn from the zone 16 by the line 18, gasoline range liquids which are withdrawn by the line 20, distillates which are withdrawn by the line 22, and slurry oils, cycle oils, unreacted feed and the like which can be recycled in the recycle means 24 as required.
After being stripped in the zone 10, the cracking catalyst is conveyed from the zone 10 to the regenerator 6 by the line 28 for coke burnoff. In the regenerator 6, oxygen containing gas is introduced by a line 30 which is connected to a source of oxygen containing gas such as the air compressor 31 and heater 32. Coke deposits are burned from the catalyst in the regenerator 6 forming an effluent gas which is separated from the catalyst in a separation portion 34 of the regenerator 6 which usually contains a plurality of cyclone separators. These flue gases are withdrawn from the regenerator 6 by the line 36. Hot regenerated catalyst passes from the regenerator 6 to a lift pot 37 at the lower end of the riser reactor 7 by line 38, which provides a source of hot cracking catalyst particles for the riser reactor.
The catalyst flow rate through the cracking unit is controlled by valves 39 which are positioned in the line 38, preferably in a vertical portion thereof.
In the lift pot 37, catalyst from the line 38 is fluidized with a fluidizing gas, usually steam, which is introduced into the lift pot 37 by line 41. The oil feedback is introduced into the lift pot 37 via a nozzle cartridge assembly 42 which preferably emits a fine mist axially into the riser or transfer line reactor at the lower end thereof. A line 44 is shown as connecting the nozzle cartridge assembly 42 with a source of heavy oil feedstock, although the invention can also be used to crack exclusively light oils if desired. A line 45 can then connect the nozzle cartridge assembly with a source of light gas oil, or the like. Atomizing gas such as steam can be added to the nozzle cartridge assembly 42 by line 46 which connects the nozzle cartridge assembly to a steam source.
The operating conditions for the riser reactor 7 and regenerator 6 can be conventional. Usually, the temperature in the riser reactor 7 will be in the range of from about 850� to 1050� F. The oil is usually admixed with steam at a weight ratio of oil to steam in the range of from about 6:1 to about 25:1. A catalyst oil weight ratio employed in the riser reactor 7 is generally in the range of from about 2:1 to about 30:1, usually between about 3:1 and about 15:1. Pressure in the riser reactor 7 is usually between about 15 and about 60 psia (pounds per square inch absolute). The cracking catalyst particles generally have a size in the range of from about 20 to about 200 microns, usually between about 40 and 80 microns. Flow velocity upward in the vertical section of the riser reactor is generally from about 10 to 30 feet per second in the lower portions and up to between about 40 and about 120 feet per second in the upper portions. The contact time between the catalyst and oil in the riser reactor is generally in the range of from about 1 to about 4 seconds, usually from 1.5 to about 3 seconds where the oil is injected into the bottom of the riser. The regenerator is operated at a temperature typically in the range of from about 1100� to about 1500� F. and is ordinarily provided with sufficient oxygen containing gas to reduce the coke on the catalyst to a level of about 0.5 weight percent or less, preferably less than 0.1 weight percent.
Catalysts suitable for catalytic cracking includes silica alumina or silica magnesia synthetic microspheres or ground gels and various natural clay-type or synthetic gel-type catalysts. Most preferably, fluidizable zeolite-containing cracking catalysts are employed. Such catalysts can contain from about 2 to about 20 percent based on total weight of zeolitic material, such as Y-zeolite, dispersed in a silica alumina matrix and have an equilibrium B.E.T. surface area in the range of 25-250 m2 /g and a particle size chiefly in the range of 40 to 80 microns.
Referring now to FIG. 2, there is shown a cross-sectional view of lift pot 37. Lift pot 37 includes a generally cylindrical section 37a and a generally frustoconical section 37b whose upper end is connected to the lower end of riser 7 as shown. Usually, the interior surface 50 will be formed from a refractory material to resist rapid erosion from the hot catalyst. A nozzle assembly, shown generally at 42, is mounted generally coaxially within lift pot 37 and serves to house various oil and atomizing steam nozzles which empty into an atomization chamber 52. Oil is accordingly atomized in the chamber so as to exit the chamber and pass up riser 7. As shown, nozzle assembly 42 includes a generally cylindrical wall 54, a frustoconically shaped end wall, and a wall 58 which will be described in further detail below in conjunction with description of the internal details of the nozzle assembly. Preferably, for maintenance purposes, it is very desirable that the assembly 42 be removable as a unit. One manner of providing for this is to form a lift pot 37 with a port 59a at its lower end adapted for receiving the generally cylindrical exterior surface of the wall 54. A generally annular flange 59b is positioned around the port. The generally cylindrical exterior surface of the wall 54 is provided with a generally annular flange 59b mounted thereon sealingly contacting the generally annular flange 59b at the lower end of the lift pot.
A generally annular space 60, hereinafter called a catalyst lift chamber, is formed between the interior surface 50 of the lift pot and the exterior surface of nozzle assembly 42. A port 62 is provided in the lift pot such that hot catalyst particles flowing through line 38 may pass into lift chamber 60. Preferably, the cracking catalyst is fluidized prior to being mixed with the oil feed. For catalyst aeration or fluidization, a means 64 is positioned in the catalyst lift chamber 60 for distributing a fluidized gas such as steam from steam source 41 into the catalyst lift chamber adjacent a lower end of the catalyst lift chamber 60. The means 64 preferably distributes fluidizing gas in the lower portion of lift pot to start vertically upward flow of the cracking catalyst. More preferably, a second means 66 for distributing a fluidization gas such as steam from the source 41 is positioned in the catalyst lift chamber 60 at a position adjacent or below catalyst acceleration zone 68. Usually, the means 64 and 66 will each be formed from an annular distributor having a sidewall with a plurality of ports therethrough which connects its interior with circumferentially spaced apart positions in the catalyst lift chamber 60. The ports through the sidewall of the annular distributor constituting the means 64 can be oriented downwardly or upwardly to lift the catalyst introduced into the catalyst lift chamber 60 via port 62 to the annular distributor constituting the means 66. The ports through the sidewall of the distributor 66 will generally be oriented toward the lower end of the riser reactor and toward zone 68. In this manner, the cracking catalyst can be conveyed in dilute phase at a desired velocity into the mouth of the riser 7. Atomized oil exiting chamber 52 mixes with the catalyst accordingly so that the mixture flows up riser 7 where cracking of the oil continues.
Details of the nozzle assembly 42 will now be set forth. As shown, wall 58 has an open upper end 70 which forms an opening, and a lower end 72 opposite end 70. An interior surface boundary 73 lies at lower end 72 so as to be adjacent to central nozzle 84 and axially opposite the opening formed at the upper end of wall 58. As used herein and in the appended claims, the term "boundary" may include many points along a curve or only a single point. Wall 58 is connected at its upper end to end wall 56, and axially extends toward the bottom end of the nozzle assembly so that a cavity is formed between wall 58 and wall 56 and 54. An annular fluid distributor 74 is provided having a sidewall and a plurality of ports through its sidewall at spaced apart positions along its length connected to the fluid source 46 and positioned in the cavity between the wall 58 and the wall 54 at a position closely adjacent the end wall 56. Steam from distributor 74 serves to cool the nozzle assmebly. To further reduce heat penetration from the catalyst lift chamber 60 to the atomization chamber 52, one or more radiation shielding members or baffles 76 can be positioned between the wall 58 and the wall 54. The radiation shielding members 76 provide radiation shielding between the walls to reduce heat penetration into the atomization chamber 52 and the possibility of coke buildup. The radiation shielding members 76 can be in the form of tubular baffles extending circumferentially around and longitudinally through the cavity between walls 54 and 58 and this arrangement is presently preferred. The tubular baffles 76 are provided with apertures which are preferably radially nonaligned as between adjacent baffles so as to prevent or mitigate heat penetration by radiation. Other types of radiation shielding, such as bronze turnings, raschig rings and the like can be employed if desired. The cooling fluid introduced into the cavity between the wall 54 and the wall 58 can be withdrawn or exhausted from the cracking unit such as via tube or port 78 which also is positioned in flow communication with the cavity.
An interior surface 80 of wall 58 defines chamber 52 which has an axis 82. In this particular embodiment, surface 80 is generally parabolic in shape, and oriented such that its base corresponds to upper end 70. Thus, substantially all of the interior surface 80 tapers toward axis 82 from the open end to boundary 73 at the lower end 72 of the wall. As shown, upper end 70 is open, and atomization chamber 52 is in fluid communication with lift pot 37. Furthermore, wall 58 is oriented such that chamber 52 is generally coaxial with respect to lift pot 37 and riser 7. The length of chamber 52 as measured along axis 82 will depend on steam and oil rates, oil viscosity, oil boiling point and other parameters.
Various nozzles preferably extend through wall 58 and empty into atomization chamber 52 so as to inject oil and an atomization fluid, usually steam, into chamber 52. Preferably, a central nozzle 84 extends through wall 58 generally along axis 82 so as to empty into chamber 52 near end 72 of wall 58. Nozzle 84 comprises a pipe having turbulence generating members 86 which can be pentagonally shaped and mounted to the inside of the pipe. Members 86 serve to breakup oil flow along the wall thereof where velocities are high enough to result in annular two-phase flow. In addition, the central nozzle is preferably connected to a source of gas oil 45. Steam from distributor 74 can be allowed to leak into chamber 52 through a gap (not shown) between wall 58 and nozzle 84 so as to assist in atomizing gas oils being emptied into chamber 52 from nozzle 84. Due to the parabolic shape of chamber 52, oil droplets which have impinged on surface 80 of the wall travel down to the central nozzle 84 and are redispersed by the atomization steam flowing from the gap. In this regard, it may be desirable to place another annular distributor at a position below that of distributor 74 and closely adjacent to wall 58 as an additional source of atomization steam. It should be understood that many alternative designs for central nozzle 84 are possible. For example, nozzle 84 as shown and described could be replaced by a nozzle of the type which includes two concentric tubes, wherein the inner tube has a helical vane structure therein. In this type of nozzle, the inner tube would be connected to the source of gas oil, and the annulus formed between the inner and outer tube would be connected to a source of atomization steam.
Nozzle assembly 42 further comprises a plurality of nozzles 88 (only two of which are shown) circumferentially spaced apart around central nozzle 84 and axis 82, and positioned so as to empty into chamber 52 from positions closely adjacent to interior surface boundary 73. As shown, each nozzled 88 comprises a tubular member connected to a source of atomizing gas 46, usually steam. Thus, nozzles 88 inject atomizing gas into chamber 52 to assist in atomizing oil released in the chamber. Additionally, atomizing gas from nozzles 88 assists in redispersing oil which has traveled down interior surface 80, and also serves to redisperse dead catalyst which can accumulate at the bottom of the chamber.
A plurality of nozzles 90 and 92 extend through wall 58 so as to empty into chamber 52 from positions spaced around axis 82. Most preferably, each nozzle 90 (only one of which is shown in FIG. 2) is a tubular member connected to a source of topped crude oil 44, and each nozzle 92 (only one is shown in FIG. 2) is a shear or whistle type nozzle connected to a source of slurry oil 57. A portion of the illustrated nozzle 92 has been cut away to show internal details. As shown, nozzle 92 comprises an outer tube connected to the source of slurry oil, and an inner tube connected to a source of atomizing gas 46. The inner tube is coaxially positioned within the outer tube, and has a slot in its sidewall which extends only partially around the circumference of the inner tube. Atomizing gas exits the slot in a direction toward axis 82 so as to shear slurry oil exiting from the outer tube. As shown, nozzles 92 are radially spaced farther from axis 82 than nozzles 90 such that the positions from which oil is emptied are spaced likewise. As used herein, radial distance is measured along lines perpendicular to axis 82. By way of example, the longitudinal axis of each nozzle 90 might be postioned above 0.5R to about 0.8R from axis 82, whereas the longitudinal axis of each nozzle 92 might be placed about 0.75R to 0.90R from axis 82, where R is the radius of the opening formed at the upper end 70 of wall 58. The slurry nozzles 92 are spaced from axis 82 as described above to maximize the volume in chamber 52 occupied by the jet or spray pattern from the nozzles. Due to the slot in the inner tube of a nozzle 92, steam exiting from the slot disperses slurry oil in a spray pattern covering only about 118� to about 120� in a direction toward axis 82. Thus, by maximizing the spacing of nozzles 92 from axis 82, a greater cross-sectional area of the chamber is available for the jet or spray pattern to diverge so as to occupy more volume in the chamber. As will be explained in more detail below, maximizing the volume occupied by jets from the nozzles is desirable, since this tends to minimize the formation of eddies within the chamber. Also, as shown in FIG. 2, slurry nozzles 92 are positioned so as to empty oil into the chamber from a position closer in axial distance to the chamber opening than the position from which topped crude oil is emptied from nozzle 90. As used herein, axial distance is that distance measured along lines parallel to axis 82. Because of this axial positioning of nozzles 92, atomized oil being sprayed in generally horizontal direction does not impinge directly on nozzles 90. This tends to prevent the development of a thick coating of oil on nozzles 90 and a consequent coke buildup.
If desired, wear plates or shrouds could be placed around the exposed portions of nozzles 90 and 92 in the chamber to assist in protecting these nozzles from the erosive effect of catalyst particles flowing through the chamber. These wear plates could comprise steel pipes, for example. Also, gaps can be provided between nozzles 90 and 92 and wall 58 through which steam can leak into chamber 52 to further assist in atomization.
Fan or spray type nozzles 94 (only two of which are shown) are also preferably provided which extend through wall 58 so as to empty into the chamber at points above nozzles 90 and 92. Nozzles 94 are typically circumferentially spaced around axis 82. Each nozzle 94 includes a capped tube having a slit in its sidewall which faces the opening at the top of the chamber. Steam is supplied to nozzles 84 via a hollow half ring 96 mounted to wall 58 so as to be in fluid communication with the nozzles 94. As shown, half ring 96 is connected to a source of steam 46. Steam from nozzles 94 assists in keeping the interior surface 80 clean and free of catalyst.
Referring now to FIG. 3, there is shown an illustration of a cross section of the lift pot of FIG. 2 as viewed along lines 3--3. As shown, nozzles 90 are preferably circumferentially spaced around the chamber axis and central nozzle 84. Similarly, nozzles 92 are also circumferentially spaced around the axis.
Several other embodiments of the present invention will now be described in reference to FIGS. 4-6. In each figure, only a portion of a nozzle assembly is shown. However, it should be understood that the nozzle assembly could be employed in the lift pot of a cracking unit as illustrated with respect to nozzle assembly 42 in FIGS. 2 and 3. The structure of each of the embodiments illustrated in FIGS. 4-6 is substantially similar to that shown in FIGS. 2 and 3 except for the structure forming the atomization chamber. In particular, slurry and topped crude nozzles are positioned similarly. Therefore, FIGS. 4-6 will each be discussed in regard to the atomization chamber structure only.
Referring now to FIG. 4, a cross-sectional view of a nozzle assembly 442 according to a second embodiment is shown. Nozzle assembly 442 includes a wall 458 having an interior surface 480 which defines a chamber 452. As shown, interior surface 480 is generally conical in shape. The embodiment shown in FIG. 4 resembles the FIG. 2 embodiment, however, in that the interior surface of the wall 458 tapers from open end 470 to boundary 473 at the lower end of the wall.
Referring now to FIG. 5, a third embodiment of the present invention is shown. Here, a nozzle assembly 542 includes a wall 558 and a molded buildup of refractory material 597 on the interior surface of the wall. The wall 558 and refractory buildup 597 together make up a member whose interior surface defines a chamber 552. The interior surface which defines the chamber is made up of a first interior surface portion 598 which extends from the upper end of wall 558 to an interior surface boundary 573 at the edge of the buildup, and a second interior surface portion 597a which comprises the surface of the buildup. The boundary 573 is closed, generally circular in this case, and generally coaxial with respect to the chamber axis. The buildup 597 is formed such that the second interior surface portion 597a protrudes from the surrounding interior surface so as to axially extend from the boundary 573 toward the chamber opening. In addition, the buildup and its respective second interior surface portion 597a has an upper end which lies between the chamber opening and boundary 573. By way of example, end 597b can be positioned within the chamber to be axially spaced 1/2D to D from the upper end of wall 558, where D is the diamter of the opening formed by the upper end of the wall. In the embodiment of FIG. 5, each of the interior surface portions 597a and 598 is generally parabolic in shape, such that first portion 698 tapers toward the chamber axis from end 570 to boundary 573, and second portion 597a tapers toward the axis from the boundary to end 597b. In addition, nozzles 588 are positioned to empty atomizing gas into chamber 552 from a position closely adjacent to boundary 573. A central nozzle 584 extends through the buildup 597 along the chamber axis such that it empties into chamber 552 adjacent end 597b. In operation, trash such as refractory fragments and catalyst will tend to accumulate in the portion of the chamber between the interior surface portions reducing the chance of blocking an oil nozzle. Furthermore, oil and small catalyst particles which accumulate in this manner will be redispersed by gas from nozzles 588.
Although the second interior surface portion 597a is described as being formed by buildup of refractory material, many alternatives to this structure are possible. For example, wall 558 could be adapted to define the second interior surface portion.
Referring now to FIG. 6, there is shown a fourth embodiment of the invention which has an atomization chamber 652 shaped in a manner similar to that in FIG. 5. Here, however, there is provided a generally conical first interior surface portion 698 and a generally conical second interior surface portion 697a. The first interior surface portion 698 forms an acute angle with respect to a plane which orthogonally intersects the chamber axis. Preferably, this acute angle is greater than or equal to the internal angle of friction of the catalyst. The internal angle of friction for cracking catalysts is typically about 70� to about 78�. By sloping the first interior surface portion in this manner, catalyst particles impinging on portion 698 will tend to flow in a downward direction to the region between the interior surface portions, where catalyst particles will be redispersed by nozzles 688. Thus, the likelihood of catalyst accumulations and possible clogging of nozzles 690 and 692 is minimized.
In each of the four embodiments illustrated in FIGS. 2-6, therefore, a hollow member is provided having an interior surface which defines a chamber. At least a portion of the interior surface tapers toward the chamber axis from a member open end to an interior surface boundary axially opposite the open end. The various nozzles inject oil and atomizing gas in V-shaped jets which generally conform to the shape of the chamber as described above. Thus, the shape of the chamber minimizes "dead spaces" in the chamber wherein there is little upward velocity fluid flow. Background gas in the chamber, which is primarily atomizing gas or steam in the illustrated embodiments, tends to backflow into such "dead spaces" which caused eddies to form. These swirling eddies may have entrained catalyst associated therewith which can cause considerable erosion of the member which defines the chamber. Also, eddies will typically cause oil droplets to accumulate on the interior surface of the chamber forming member, such accumulations possibly breaking down to coke which can clog nozzles. Thus, by reducing the cross-sectional area across the atomization chamber by means of a chamber forming member shaped according to the present invention, catalyst erosion and coke buildup in the chamber are minimized due to the minimizing of eddy formations. This minimization of eddies in the atomization chamber also enhances the likelihood of a relatively uniform exit velocity of atomized oil from the chamber.
Although the preferred embodiments are described as having a background gas substantially comprising steam, it should be understood that other fluids could conceivably be used. Moreover, a chamber designed according to the present invention could be applied to any system in which a need arises to inject one fluid into a chamber having another fluid therein which can backflow as described above to form eddies.
The following illustrates how the invention might be used in a commercial unit. Using the equipment described in FIGS. 1, 2 and 3, the following specific conditions can be employed.
__________________________________________________________________________Item__________________________________________________________________________(34) Regenerator diameter feet-inches (I.D.) 45'-2"(34) Regenerator length feet-inches 67'-8" (8) Reactor (disengager) diameter feet-inch (I.D.) 26'-0" (8) Reactor (disengager) length feet overall 54'-0" (7) Reactor riser diameter I.D. inches 42" (7) Reactor riser height feet-inches 88'-6"(37) Lift pot diameter feet-inches 7'-0"(37) Lift pot height overall feet-inches 7'-11"(38) Catalyst conduit diameter (I.D.) feet-inches 2'-2"(39) Catalyst slide valve diameter (I.D.) feet-inches 2'-6"__________________________________________________________________________Operating Conditions Regenerator Disengager Reactor__________________________________________________________________________Outlet temperature �F. 1298 928Dilute phase temperature �F. 1312 900Top pressure psia 19.7 24.2Riser inlet temperature �F. 1011Riser feed temperature �F. 702Riser out temperature �F. 951Reactor stripper temperature �F. 950Stripping steam lb/hr 5500Stripping steam lb/ton catalyst 7.2Riser cat/oil ratio 4.3Riser Velocity feet/sec 50Residence time seconds 1.8Catalyst circulation tons/min 12.7Total regenerator air (SCFM) 85,300Air blower discharge temperature �F. 310Air blower discharge pressure psia 38__________________________________________________________________________Fresh Feed Oil Charge Volumesand Temperatures BPD, �API �F. BPD �API �F.__________________________________________________________________________Virgin gas oil 10,000 32.8 750Heavy cycle oil 7,200 20.3 780Topped crude 8,000 14.0 800Reslurry oil 2,400 10.9 680Precipitator backwash 1,200 10.8 480Total fresh feed 28,800 -- --Steam, 125 psig, 500� F.To V. Gas oil perheater lb/hr 4,000To slurry nozzle lb/hr 3,000All other cartridge stm lb/hr 11,000Total steam usage 18,000__________________________________________________________________________Lift PotItem Dimension__________________________________________________________________________(64,) Two 3-inch sch. 160 304 SS. steam 5 ft"6 in OD(66) rings with 421/2 inch diameter steam holes(42) Nozzle cartridge assembly, outside refractory 4 ft."4 in diameter overall height 9 ft"51/4 in Upper end of nozzle cartridge assembly rounded As described with 1/2 inch radius with 1/8 inch outer layer of Stellite #1 over a 1/8 inch inner layer of Stellite #6 over a nosing bar(80) Interior surface of wall 58 parabolically shaped according to the expression x2 = 7.225y, where the y-axis corresponds to axis 82 and the x-axis is perpendicular to axis 82.(52) Length of chamber 40 in Diameter of chamber at upper end 70 34 in(44) 3 Heavy cycle and topped crude 4 in feed pipes nom. sch 80 typical(45) 1 Virgin gas oil feed pipe nom sch 80 10 in(46) Dispersion steam pipes and rings 11/2 inch 11/2 in sch. 80 with 2 ft-8 in diameter ring of 11/2-inch sch. 80 with 60-3/16 inch steam holes(47) 3 Reslurry oil and separator backwash feed 21/2 in 0.D. line 4 in sch. 80 nom. diameter with interior inside steam pipe of 21/2 in diameter sch. 160 typical 4 in 0.D.(50) Lift pot interior refractory surface 6 ft 3 in I.D. (7) Lower end of riser interior refractory I.D. 42 in(68) Catalyst acceleration zone 96 defined 4 to 5 inches between upper surface 92 of end wall 56 surfaces. Throat and interior surface of section 37b of measures about 600 of catalyst lift pot 37. in2. Surfaces converge toward axis at about a 45� angle.(60) Catalyst lift chamber, annular width with 111/2 in annulus circumferentially 360� around nozzle cartridge assembly(86) Turbulence generating members welded at 15� angle to axis and pentagonally shaped with overall dimension of 11/4 inch by 2 inch with four rows of deflectors, 16 deflectors per row, rows are staggered(88) Dispersal steam pipes of l to 11/2 inch nominal pipe diameter(90) 3 nozzles, each 4 inch nom. diameter and 10.3 in circumferentially spaced apart, radius to axis 82 for each nozzle(92) 3 nozzles, each 4 inch nom. diameter and 3.6 in circumferentially spaced apart 11 3/16 inch, radium to axis 82 for each nozzle(74) Perforated steam ring l inch sch. 80 3 feet 7 inches in diameter(76) 2 Radiation shielding baffle members, perforated 3/8 inch thick steel plates cylindrical shaped, 1/2 inch diameter holes, 4-inch center line distance between holes, plates are 1 inch apart, holes are misaligned(94) 10 steam wall sparging nozzles each made of 1-inch SCH 80 pipe capped with 1/2-inch thick circular welded plate, each nozzle extending into parabola 2-inches perpendicular to wall with 120� nozzle slot 1/4 inch wide cut parallel with wall, and centerline of nozzle slot 1-inch from cap plate weld(59c) 5 feet-5 inches diameter flange 4 inches thick carbon steel with 60- 13/8 inch diameter holes on a 60 inch bolt circle__________________________________________________________________________
Obviously many modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims the invention may be practiced otherwise than as specifically described.
|Cited Patent
|Filing date
|Publication date
|Jun 11, 1947
|Dec 13, 1949
|Sinclair Refining Co
|Process and apparatus for the catalytic conversion of hydrocarbons
|Sep 23, 1953
|Jun 16, 1959
|Exxon Research Engineering Co
|Process for feeding heavy oils into conversion systems
|Oct 25, 1954
|Jun 16, 1959
|Kellogg M W Co
|Fluidized hydrocarbon conversion system with an improved regenerator distributor
|Jul 7, 1958
|May 2, 1961
|Phillips Petroleum Co
|Pitch conversion
|Mar 14, 1957
|May 23, 1961
|Phillips Petroleum Co
|Method and apparatus for contacting and conveying of fluidized solids and fluids to be contacted therewith
|Nov 18, 1959
|Jul 3, 1962
|Phillips Petroleum Co
|Catalytic conversion of hydrocarbon oils with the use of different types of feed oils
|Oct 27, 1959
|Jan 1, 1963
|Kellogg M W Co
|Oil feed system for fluid catalytic cracking unit
|Sep 14, 1961
|Oct 6, 1964
|Exxon Research Engineering Co
|Feed injector for cracking of petroleum
|Aug 15, 1962
|Dec 15, 1964
|Pullman Inc
|Two-stage hydrocarbon conversion process
|Jun 21, 1965
|Oct 21, 1969
|Nick Nikodem Urbanowicz
|Jan 23, 1970
|Sep 21, 1971
|Pullman Inc
|Apparatus and method for conversion of hydrocarbons
|Aug 12, 1970
|Apr 4, 1972
|Exxon Research Engineering Co
|Novel cat cracking oil feed injector design
|Nov 4, 1976
|Jun 27, 1978
|Uop Inc.
|Hydrocarbon-feed distributor of injecting hydrocarbon feed
|Feb 5, 1980
|Jan 12, 1982
|Phillips Petroleum Company
|Catalytic cracking
|Jul 15, 1980
|May 25, 1982
|Dean Robert R
|Method and apparatus for cracking residual oils
|Jul 15, 1980
|Jun 1, 1982
|Dean Robert R
|Method and apparatus for cracking residual oils
|Mar 17, 1982
|Jan 24, 1984
|Dean Robert R
|Method and means for preparing and dispersing atomed hydrocarbon with fluid catalyst particles in a reactor zone
|Oct 25, 1983
|Jul 30, 1985
|Accuspray, Inc.
|Spray nozzle
|Oct 5, 1984
|Aug 27, 1985
|Binks Manufacturing Company
|Spray guns
|Dec 2, 1983
|Dec 31, 1985
|Phillips Petroleum Company
|Catalytic cracking unit
|Dec 2, 1983
|Jan 7, 1986
|Phillips Petroleum Company
|Catalytic cracking unit
|Apr 16, 1982
|Nov 3, 1982
|Mobil Oil Corporation
|Fluid catalytic cracking process and apparatus
|Cheremisinoff et al., Handbook of Fluids in Motion Ann Arbor Science, The Butterworth Group, 1983, pp. 803 804.
|Cheremisinoff et al., Handbook of Fluids in Motion Ann Arbor Science, The Butterworth Group, 1983, pp. 803-804.
|Fischer Scientific Catalog 1983, pp. 392 401, copyright 1982.
|Fischer Scientific Catalog 1983, pp. 392-401, copyright 1982.
|Citing Patent
|Filing date
|Publication date
|May 30, 1986
|Oct 18, 1988
|Phillips Petroleum Company
|Method and apparatus for contacting fluid feed materials with fluidized solids
|Mar 9, 1987
|Jan 3, 1989
|Shell Oil Company
|Process for contacting particulate solids with a fluid
|Jan 15, 1988
|May 29, 1990
|The Standard Oil Company
|Process for pyrolyzing or thermal cracking a gaseous or vaporized hydrocarbon feedstock using a novel gas-solids contacting device and an oxidation catalyst
|Nov 15, 1993
|Jul 16, 1996
|Martineau; Andre
|Fluid catalytic cracking
|Dec 12, 1994
|Sep 10, 1996
|Phillips Petroleum Company
|Feed zone performance for a cat cracker
|Mar 7, 1995
|Aug 18, 1998
|Shell Oil Company
|Feed nozzle
|Aug 19, 2011
|Nov 5, 2013
|Jefferson Science Associates, Llc
|Articulating feedstock delivery device
|Nov 1, 2012
|Jefferson Science Associates, Llc
|Articulating feedstock delivery device
|Sep 26, 2014
|May 28, 2015
|The University Of Florida Research Foundation, Inc.
|Methods and enzymes for producing hydroxymethylfurfural
|U.S. Classification
|422/140, 261/78.2, 422/145, 239/428, 422/214, 422/144, 208/157, 239/132.3, 208/127
|International Classification
|Cooperative Classification
|European Classification
|Sep 10, 1990
|Fee payment
Year of fee payment: 4
|Feb 16, 1995
|Fee payment
Year of fee payment: 8
|Mar 9, 1999
|Maintenance fee reminder mailed
|Aug 15, 1999
|Lapse for failure to pay maintenance fees
|Oct 26, 1999
|Expired due to failure to pay maintenance fee
Effective date: 19990818


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Five young men die in an early morning horror smash. The driver cops a pasting in the press, but what about the car? Shouldn't it also take a share of the blame?
Topics: youth, people, law-crime-and-justice
Posted| Updated
A bunch sprint to the line has seen Andre Greipel win the opening stage of the Tour Down Under.
Topics: community-and-multicultural-festivals, community-and-society, tanunda-5352, adelaide-5000, sa, clare-5453, port-augusta-5700, port-pirie-5540
Posted| Updated
US President Barack Obama has called for greater support for Haitian earthquake victims, saying they will not be foresaken or forgotten.
Topics: earthquake, world-politics, obama-barack, haiti, united-states
The Australian Education Union (AEU) says regional students will be disadvantaged when choosing whether to accept university offers because of the uncertainty about Youth Allowance.
Topics: welfare, youth, university-and-further-education, rural-youth, mount-gambier-5290, renmark-5341
The South Australian Murray Irrigators group says a referendum on a Federal Government takeover of the Murray-Darling Basin should only be taken as a last resort.
Topics: murray-darling-basin, water-management, irrigation, mount-gambier-5290, renmark-5341
Police have arrested a man over three alleged car-jackings in Sydney's north-west this morning.
Topics: armed-robbery, law-crime-and-justice, crime, burglary, northmead-2152, australia, nsw
Posted| Updated
Hundreds of Haitians are stuck at the US and Canadian embassies in Port-au-Prince, desperately seeking visas to flee the earthquake stricken nation.
Topics: international-aid-and-trade, disasters-and-accidents, earthquake, relief-and-aid-organisations, unrest-conflict-and-war, haiti
Police in Papua New Guinea say prison guards helped some of the country's most notorious criminals escape from a maximum-security jail.
Topics: prisons-and-punishment, law-crime-and-justice, crime, papua-new-guinea
Posted| Updated
A Taiwanese artist has created a tiger sculpture tiny enough to pass through the eye of a needle.
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Posted| Updated
The ACT Government says it will not appropriate the funds it needs to buy Calvary Public Hospital until the Vatican approves the sale.
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The British High Commissioner, Baroness Valerie Amos, will visit Queensland's north-west in March.
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As international aid agencies rush food, water and medicine to Haiti's earthquake victims, a United States group is sending Bibles.
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South Australian health authorities say they will meet people in Mount Gambier before the city's fluoridation plant begins operating.
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Tenants of The Dome at Findon in Adelaide say their schedules will not be affected by the venue going into receivership.
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CBS has ordered an updated version of the classic cop series Hawaii Five-O.
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The Flinders Shire Council CEO says the completion of Hughenden's $10 million sewerage system has been a long time coming, in Queensland's north-west.
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A man charged with assaulting police and nurses at a Darling Downs' hospital has been granted bail.
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Brisbane's Labor councillors have called for an urgent review of the redesigned King George Square in the city centre after scorching temperatures were recorded there yesterday.
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Fans of Starbucks' Pumpkin Spice Lattes are in a bit of a panic across the country.
The Wall Street Journal reports some stores have been running out of the syrup and customers have been storming out in anger.
The company told the paper that some stores have run dry or are in the process of doing so, but there is no nationwide crisis.
However, Starbucks says if any stores are having a "pumpkin emergency," they can place an extra order.
Several Starbucks stores across country low on pumpkin spice syrup
Published On: Oct 05 2012 01:02:24 PM CDT
Fans of Starbucks' Pumpkin Spice Lattes are in a bit of a panic across the country.
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Deadline: Tuesday 30 August, 4pm
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For further information go to www.big-telly.com
For an application pack please e-mail, email@example.com
Big Telly Theatre Company is an equal opportunities employer.


text:
eVote Adds Elections to Mailing Lists
A specialized database server for keeping votes, combined with a conferencing system, can create a medium for a true nonhierarchical democracy (see the Ideal Democracy Sidebar). The work of administering the voting system would be shared by the users and the software, not the system administrator. When the correct architecture for the problem came to me, I could no longer simply advocate Electronic Democracy; I built it.
Ideal Democracy Includes Both Discussion and Voting
The specialized vote server, the Clerk, is written in C++ and provides many features for voters. Anyone can initiate a poll, and users can change their votes as long as the poll is open. Polls also can be public, allowing all the participants to view each other's votes, private, or if_voted, allowing us to know who voted but not how they voted. Several poll types are supported: yes/no, numeric and grouped. The software is easily enhanced to add new features and poll types by extending the existing classes. The Clerk maintains data on the fly, requiring no help from the administrator. True to the promise of object-oriented architecture, the addition of each new feature has made the code more robust.
The ballots are dynamic. When the user closes her poll and then drops it from the conference, and when the software is otherwise idle, the ballots are collapsed, rolling the storage bytes for other items toward the top and making space for new polls. The item objects recalculate their new places in the ballots, and everything is set to continue without any intervention from the administrator.
The Clerk's main() function is an infinite loop that watches for incoming messages on the interprocess communication messaging facility from eVote clients, i.e., user-interface processes with live voting users. The Clerk has one permanent message queue for incoming requests from users, and it is managed by the single instance of the InQ class. Each eVote process has a temporary message queue of its own for receiving messages from the Clerk. These are instantiations of the OutQ class.
Although the statistics about polls and the personal information requested by a voter are communicated via the OutQ objects, another interprocess communication facility, shared memory, is used for slow-moving data. The list of poll items and their properties are stored in shared memory so that all the eVote clients currently active in the same conference can see them. Properties of the poll items may include public, private or if_voted, where users can see if another voter has voted, but not how he voted; yes/no or numeric; visible or hidden, where the statistics are available only after the poll is closed; single or grouped; and the title.
The conference's ItemList object is responsible for maintaining the shared memory. When a new poll is created for a conference, if the growing list of poll items requires a new patch of shared memory, a message is sent to all active eVote clients. This dynamic notification feature enables the voters to conduct their meeting in real time.
The Clerk keeps three data files for each conference or e-mail list and one overall data file that lists all the e-mail addresses and a corresponding numerical ID. For the sample e-mail list, a sample.dat with the current ballots, keyed by the voter's numerical ID, is kept by the BallotBox object. The BallotBox also keeps sample.bnf, which contains a hash into sample.dat and some handy statistics. A sample.inf file storing the current map of items onto the ballots is maintained by the ItemList object.
eVote, the user interface, keeps a petition's signatures and comments in a flat file, one file per petition.
At this time, the Clerk has two user interfaces and invites more. The Clerk's first user interface is a simple text-based Telnet interface, designed with conferencing systems and BBSes in mind.
The explosion of the Internet dampened enthusiasm for conferencing systems. E-mail arose as the dominant form of communication, and e-mail lists became the community discussion medium. So the e-mail user interface was built to allow e-mail communities to make formal decisions, while still using the popular Mailman mailing-list software.
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Best and Worst of the 2012 Academy Awards: 'Bridesmaids,' Emma Stone, Billy Crystal, Meryl Streep
'Bridesmaids,' Emma Stone, Billy Crystal, Meryl Streep and more
<< Prev Next >>
Better or worse than we expected?
After the disastrous 83rd Academy Awards show that is likely still giving former hosts Anne Hathaway and James Franco nightmares, this year's Oscars had to be a major improvement? Especially with the return of fan-favorite host Billy Crystal, right? Sure, but that didn't mean it was smooth sailing. Thankfully, the winners and presenters helped wake up the program at times. Find out who helped and who hurt by clicking on the tabs above.
For a look at the best and worst dressed on the red carpet, click here.
Photo Credit:
Kevin Feige and the Russo brothers reveal why no Avenger got killed off in 'Captain America: Civil War'