text:
|Publication number
|Publication type
|Publication date
|Aug 20, 1974
|Filing date
|Apr 9, 1973
|Priority date
|Sep 1, 1971
|Publication number
|P Readio, A Schrage
|Original Assignee
|Dart Ind Inc
|Export Citation
|BiBTeX, EndNote, RefMan
|Referenced by (14), Classifications (7), Legal Events (2)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent USE OF XYLENE IN CONTROLLING MELT FLOW OF MODIFIED POLYOLEFIN COMPOSITIONS Albert Schrage, East Orange, and Philip D. Readio, Sparta, N.J., assignors to Dart Industries Inc., Los Angeles, Calif.
No Drawing. Continuation-impart of application Ser. No. 177,143, Sept. 1, 1971, now Patent No. 3,755,495, which is a division of applications Ser. No. 81,526, Oct. 16, 1970, now Patent No. 3,696,169, and Ser. No. 253,090, May 15, 1972, now abandoned, which in turn is a division of application Ser. No. 129,623, Mar. 30, 1971, both now abandoned. This application Apr. 9, 1973, Ser. No. 349,592
Int. Cl. C08f 29/12, 35/06 US. Cl. 260-827 Claims ABSTRACT OF THE DISCLOSURE Si )a in the presence of an organic peroxide, the melt flow may be controlled by including in the reaction mixture a quantity of xylene. The reaction product is particularly suited for reinforcement with filamentary material or as a coating on metallic surfaces.
This application is a continuation-in-part of pending applications, Ser. No. 177,143, filed Sept. 1, 1971, now US. Pat. No. 3,755,495, which is a division of Ser. No. 81,526, filed Oct. 16, 1970, now US. Pat. No. 3,696,169, and Ser. No. 253,090, filed May 15, 1972, now abandoned which is a division of Ser. No. 129,623, filed Mar. 30, 1971, now abandoned.
This invention relates to improvements in modified polyolefin compositions having good adhesiveness characteristics and methods for their preparation.
Modified polyolefin compositions having good adhesiveness characteristics, particularly toward polar materials, are described in application Ser. No. 81,526, filed Oct. 16, 1970. These compositions are formed, in general, by reacting an olefin polymer with certainethylenically unsaturated polymerizable compounds in the presence of an organic peroxide. While the resulting modified polyolefin compositions exhibit adhesiveness characteristics which are far superior to the unmodified polyolefins the melt flow of the compositions is undesirably high. As is well known, polymers having undesirably high melt flow values also undergo a reduction in physical properties such as tensile strength, flexural strength and impact strength.
This invention provides a solution to the problem of unduly high melt flow in these modified polyolefin compositions. Briefly, the invention involves the use of xylene in the reaction of the olefin polymer with the ethylenical- 1y unsaturated polymerizable compound in the presence of the organic peroxide. Xylene is merely charged along with the other reactants to a reactor and the entire mixture is subjected to the usual polymerization conditions. The resulting modified polyolefin compositions have far lower melt flow values than such compositions prepared without the use of xylene.
Briefly described, modified polyolefin compositions of this invention are produced by the process comprising providing an olefin polymer derived from alpha-olefin monomers having 2 to 10 carbon atoms in particulate form; admixing the particulate olefin polymer with xylene,
3,830,872 Patented Aug. 20, 1974 r'rlce organic peroxide and a polymerizable compound defined y I'R3 3 CH1 0 \R/HIS1(R) wherein R R and R are hereinafter defined; reacting the resulting mixture at a temperature below the tacky point of the polymer; and recovering a modified polyolefin composition directly from the reaction in particulate form. Various advantages are achieved with this process among which is included the production of a modified polyolefin composition having improved melt flow and adhesiveness characteristics directly in particulate form. Since the re action is conducted without the necessity of melting the polymer there is no requirement for comminuting or grinding the product to obtain a free-flowing particulate product. Moreover, it is believed that a more uniformly modified composition is obtained from the process due to the high total surface area of the polymer exposed dur ing the reaction as well as the ability to obtain intimate mixing of the ingredients.
The polyolefins suitable for use in the process are those derived from alpha-olefin monomers having 2 to 10 carbon atoms. Included among these are polyethylene, polypropylene, poly(butene-1), poly(4 methyl-pentene 1), ethylene-propylene copolymers, and terpolymers of ethylene-propylene-butene-l.
As mentioned above, in accordance with this invention, these polyolefins are in particulate form such as powders, granules, chips, pellets, and the like, all of which are commercially available. Powdered polyolefins are preferred as the greatest surface area is thus obtained. Powders having an average particle size in the range of about 0.001 mm. to about 4 mm. are particularly preferred, more preferably 0.01 to 1 mm. The use of powdered polyolefins is a specific feature of the process of this invention since such powders are inherently produced in certain olefin polymerization processes, most notably polypropylene and polyethylene. Thus, the process of this invention may easily be incorporated in such olefin polymerization processes as an optional sequence of steps to provide an additional capability ofproducing the modified polyolefin compositions with a minimum of additional equipment.
The polymerizable compounds are those compounds defined by -(O C alkylene) O0- group with or without pendant glycidoxy groups; a
C-O(C1C1o alkylene)- group with or without pendant glycidoxy groups; or a group; a
group with or without pendant glycidoxy groups; and
R is halogen, bromine or chlorine in particular, an alkoxy radical having 1 to carbon atoms, or an acyloxy radical having 1 to 10 carbon atoms.
Preferably, R is either absent or a C -C alkylene group and R and R are as described above.
Included within the above defined group of compounds are the following by structure Such compounds are commercially available.
The organic peroxides useful in the process of this invention include both solid and liquid organic peroxides. In order to insure good distribution of the peroxide throughout the mixture of ingredients prior to reaction it is preferred to use a liquid form of the peroxide. Thus, for convenience, those organic peroxides which are normally liquid or which become liquid at or near the temperature at which the particular reaction is run are preferred over the solid-type organic peroxides. However, by dissolving the solid organic peroxides in a suitable organic solvent, that is one that has no substantial adverse effect on free radical polymerization reactions, a suitable physical form is obtained which can be used with substantially equal success in the process of the invention. Since the solvent, for this purpose, merely functions as a carrier for the solid organic peroxide it makes no difierence whether or not it becomes vaporized prior to reaching reaction temperature since the peroxide at that point in the process has already been distributed throughout the ingredients.
Some examples of suitable peroxides include di-t-butyl peroxide, t-butyl hydroperoxide, methyl ethyl ketone peroxide, t-butyl perbenzoate, t-butyl peracetate, t-butyl peroxypivalate, acetyl peroxide, t-butyl peroctoate, t-butyl peroxyisobutyrate, decanoyl peroxide, lauroyl peroxide, benzoyl peroxide, 2,5-dimethylhexane 2,5 diperoxybenzoate, cyclohexanone peroxide, cumene hydroperoxide, pmenthane hydroperoxide, di t butyl-diperoxyphthalate, cumyl peroxide, caproyl peroxide, and the like. Of course, there are additional organic peroxides in this group but are too numerous to attempt to individually name. As mentioned previously, it is preferred that the organic .peroxide be in a liquid form or capable of dissolution in a substantially inert organic solvent at or near the temperature at which the particular reaction is carried out.
Selection of a particular organic peroxide or mixture of organic peroxides of the type mentioned above may be easily determined based on the temperature at which the particular reaction is to be carried out and the corresponding decomposition rate of the peroxides as evidenced by their respective half-lives. The half-lives of peroxides are well known and may be readily ascertained (see U.S. 3,293,233).
It is pointed out that oxygen preferably should not be employed in the process even though it is sometimes regarded as a free radical initiator. Oxygen is known to cause deleterious effects on polymerizable monomers (see page 36 of the reprint of Chapters I-IV from Monomeric Acrylic Esters by E. H. Riddle, 1954). Since oxygen has some adverse effect on the reaction it is desirable to conduct the reaction in a substantially oxygen-free atmosphere if possible. While small amounts of oxygen can probably be tolerated in the system effort should be made to prevent introduction of additional oxygen over and above what may be initially present. Preferably, the reactor is purged with an inert gas prior to conducting the reaction.
The xylene is added to the olefin polymer particles prior to reaction and is evenly distributed throughout. Preferably, 0.01 to 10 percent by weight of xylene based on the olefin polymer are employed. This amount does not visually appear to change the dry nature of the mixture of ingredients prior to reaction. It is not known as to just how the minor amount of xylene functions in the process. In any event, whatever the mechanism, the result is a desirable reduction in melt flow and further enhancement of the bonding ability of the modified composition as evidenced by an increase in flexural strength of glass fiber reinforcement of the compositions. The most significant increases are obtained when at least 0.5 part by weight of the polymerizable compound is employed.
As described previously, in accordance with the process of the invention, the above ingredients, that is the olefin polymer in particulate form, the polymerizable compound, the xylene and the organic peroxide, are admixed on a substantially dry basis. The amount of liquid is insufiicient to cause any discernible change in the dry-appearance of the mixture.
The admixing of the ingredients may be accomplished by merely charging the ingredients, separately or simultaneously to a mixing apparatus such as a Henschel mixer. After achieving homogenization of the ingredients in the mixer the mixer is transferred to a reaction zone for reaction as hereinafter described. Rather than separately mixing the ingredients remote from the reaction they may also be charged directly to a reactor equipped with some means for agitation or tumbling to achieve homogenization of the ingredients within the reaction zone.
In any event, once the mixture is present in the reaction zone, the zone is preferably purged of any oxygen with an inert gas and the reaction is conducted at a temperature which is below the tacky point of the olefin poly mer to avoid agglomeration of the polymer particles. The tacky point of the olefin polymer is defined as that temperature at which the surfaces of the polymer particles become sufiiciently soft so as to be tacky and tend to stick to one another and to other surfaces. Preferably, some mild agitation is provided to insure good heat transfer and help to maintain the homogeneity of the mixture during reaction. The precise temperature at which the reaction will be carried out will vary depending on the specific olefin polymer, the specific polymerizable compound and the specific organic peroxide or peroxide mixture employed. Generally, it will be somewhere in the range of 0 C. up to below the tacky point of the olefin polymer. For polypropylene the upper temperature limit will be about 150 C., for high density polyethylene (e.g. 0.930 and above) it will be about 120 C. and for low density polyethylene (e.g. below 0.930) it will be about C. Thus, it is apparent that the upper temperature limit will vary considerably depending on the particular polymer.
The pressure at which the reaction is conducted is not critical and, in general, good results can be obtained at pressures in the range of atmospheric up to about 1000 p.s.i. For practical reasons it is convenient to operate from about atmospheric up to about 200 psi. and under conditions to assure that the xylene is maintained in the reaction zone. As indicated previously, the reaction zone is usually purged with an inert gas to remove any oxygen prior to conducting the reaction. In some instances it may be convenient to merely close the system and begin the reaction whereby an autogenous pressure is built up and maintained. In other instances it may be convenient to close the system and pressurize the reaction zone with the inert gas, e.g. carbon dioxide, nitrogen, argon, etc. in order to prevent excessive volatilization of volatile ingredients.
The reaction zone may be of a fluid bed type wherein the admixed ingredients are charged to form the bed. The system is then preferably purged with the inert gas to remove oxygen and closed. An externally heated inert gas is then continuously circulated through the bed as is known in these systems and the reaction proceeds. The movement of the inert gas through the bed conveniently provides agitation sufiicient to aid heat transfer and maintain the homogeneity.
In a variation of the above described fluid bed reaction, it is also possible to form the bed solely from the olefin polymer particles and inject the necessary quantities of the polymerizable compound, xylene and organic peroxide, either separately or as a mixture, into the heated gas stream prior to its passage through the bed of polymer particles. In this manner, the flow of the gas stream serves to agitate the polymer particles and uniformly distribute the polymerizable compound, xylene and organic peroxide throughout the particles as the reaction proceeds.
Another type of reaction zone for conducting the process of this invention is provided by a vessel equipped with helical ribbons. With this system it is not necessary to separately mix the ingredients and then charge them to the vessel as the ribbons in the vessel will adequately mix the materials when separately charged. Heating of the mixture is accomplished through external jacketed heating means. The ribbons function to aid heat transfer and maintain good mixing of the ingredients.
In conducting the reaction it is desirable to completely decompose the organic peroxide before recovering the product as the presence of any residual peroxide, even in small quantities, may adversely affect the resulting composition in subsequent compounding, molding or extruding operations.
The resulting modified polyolefin composition may be easily recovered directly from the reaction zone in particle form and thus is suitable for subsequent operations as mentioned above without any further steps such as comminuting. The composition exhibits increased bonding with such materials as glass, particularly glass fibers used in reinforcing compositions of this type.
The reaction product, that is the resulting composition of this invention is particularly suited for reinforcement with filamentary material such as glass fibers or asbestos in amounts ranging from about 5 to 90% by weight. Such reinforced compositions may be produced in accordance with conventional techniques, see US. 3,416,990, US. 3,453,356, and US. 3,042,570. In addition, the reaction product is useful in coating surfaces, e.g. metallic or glass containers and the like, due to the adhesiveness properties it possesses.
Other additives may be incorporated in the reaction product including fillers, pigments, stabilizers, anti-oxidants, anti-static agents, flame retardants and the like.
The following example will serve to further illustrate the invention.
EXAMPLE I A series of compositions were prepared according to the method set forth below. A mixture comprising 100 parts by weight polypropylene particles (average size in the range of 0.01 mm. to 4 mm.), 0.2 part by Weight 7- methacryloxypropyl trimethoxy silane, 0.5 part by weight t-butyl peracetate (75% solution in benzene) and 2.0 part by weight xylene were mixed in a Waring Blender and charged to a reactor with a paddle stirrer. The dry-appearing free-flowing mixture was stirred to distribute the materials while first purging the system with argon and then heating to about 125 C. under autogenous pressure; The mixture was maintained at about 125 C. for about 4 hours while continuing the stirring and then cooled and subjected to vacuum to remove any volatiles present. The
resulting composition was recovered directly from-the reactor in a particulate form. H
For comparison, a second series of compositions were prepared using the same procedure except that no xylene was employed. The products were recovered in a particulate form.
Each of the above compositions was tested for melt flow (230 C.) in accordance with ASTM D-1238 and then blended with 20 weight percent chopped glass fibers inch, OCF 885) for testing for flexural strength and flexural modulus properties in accordance with ASTM D- 790-66. The results of these evaluations are indicated in the following table.
TABLE I Xylene Flexural (parts Flexural modulus by Melt strength (p.s.i. Sample number weight) flow (p.s.i (X10 Thus, having described the invention in detail it will be understood by those skilled in the art that certain variations and modifications may be made without departing from the spirit and scope of the invention as described herein or in the appended claims.
What we claim is:
1. A process for preparing a modified polyolefin composition having improved melt fiow characteristics which comprises: I
(a) providing an olefin polymer in particulate form, said olefin polymer being derived from alpha-olefin monomers having 2 to 10 carbon atoms,
(b) admixing the olefin polymer in particulate form with an organic peroxide, from 0.01 to 10 percent based on the weight of the olefin polymer of xylene and from 0.01 to 10 percent based on the weight of the olefin polymer of a polymerizable compound to provide a substantially dry mixture, said polymerizable compound being defined by wherein R is hydrogen or an alkyl radical having 1 to 4 carbon atoms;
R is a straight, branched or cyclic al kylene radical having 1 to 10 carbon atoms with or without pendant glycidoxy groups; a substituted or unsubstituted phenylene group with or without pendant glycidoxy groups; a
group; a
-(C1Gm alkyleneJ-(flJ-O- group with or without pendant glycidoxy groups; a
?O(C 1-0 m alkelene) group with or without pendant glycidoxy groups; or a 0 (C -C alkylenekli-O-(C r0 alkylene) group with or without pendant glycidoxy groups; and R is halogen, an alkoxy radical having 1 to 10 carbon atoms, or an acyloxy radical having 1 to 10 carbon atoms; (c) reacting the resulting mixture in a reaction zone at a temperature below the tacky point of the olefin polymer and at a pressure sufficient to maintain the References Cited xylene within the reaction zone, and UNITED STATES PATENTS (d) recovering a modified polyolefin composition directly from the reaction in particulate form. 3,075,948 1/1963 Santenl 260-327 2. A process according to Claim 1, wherein 5 3,505,279 4/1970 Preston et a1. 260-827 3 i H or a CFC1 alkyl group, 3,573,334 3/ 1971 Whe ler 260827 R* is either absent or a 0 -0 alkylene group, and 3,644,245 2/1972 Flanagan at 260827 R is bromine, chlorine, a C -C alkoxy group or a 3,644,141 2/1972 Preston 260-827 3,646,155 2/1972 Scott 260827 C -C acyloxy group.
3. A process according to Claim 1 wherein the re- 10 action is conducted in the absence of oxygen. WILBERT S, SR., Primary Examiner 4. A process according to Claim 1, wherein the U S 01 X R polymerizable compound is 'y-methacryloxypropyl trimethoxy silage, 117-124 E, 132 BS; 260-33.6 SB, 33.6 PQ, 878
5. A process according to Claim 1, wherein the olefin 15 polymer is polypropylene, polyethylene or a copolymer of ethylene and propylene.
|Citing Patent
|Filing date
|Publication date
|Sep 8, 1975
|Sep 13, 1977
|Kabel-Und Metallwerke Gutehoffnungshutte Aktiengesellschaft
|Preparing thermo-plastic or elastomeric materials for cross-linking of grafted silane
|Aug 18, 1975
|Nov 15, 1977
|Kabel-Und Metallwerke Gutehoffnungshutte Ag.
|Grafting of silane on thermoplastics or elastomers for purposes of cross-linking
|Dec 22, 1975
|Sep 26, 1978
|Kabel-Und Metallwerke Gutehoffnungshutte Ag.
|Processing a graft polymer or elastomer
|Mar 10, 1975
|Sep 15, 1981
|Kabel- Und Metallwerke Gutehoffnungshutte Ag
|Grafting of silane on thermoplastics or elastomers for purposes of cross linking
|Sep 17, 1979
|Jul 20, 1982
|Copolymer Rubber & Chemical Corporation
|Method of grafting EPM and EPDM polymers
|Apr 2, 1981
|Oct 12, 1982
|Union Carbide Corporation
|Compositions based on water-curable, silane modified copolymers of alkylene-alkyl acrylates
|Jul 30, 1984
|Mar 24, 1987
|Dynamit Nobel Aktiengesellschaft
|Process for the production of semifinished products and/or molded components from polypropylene
|Oct 16, 1986
|Jul 19, 1988
|Dow Corning Corporation
|Method of preparing allyl-terminated polyisobutylene
|Mar 6, 1996
|Sep 30, 1997
|Nissin Chemical Industry Co., Ltd.
|Acrylic rubber composition
|Jan 18, 1996
|Feb 3, 1998
|Kimberly Clark Co
|Silane modified elastomeric compositions and articles made therefrom
|May 25, 1996
|Feb 17, 1998
|Kimberly-Clark Worldwide, Inc.
|Process for producing a nonwoven web using silane modified elastomeric compositions
|May 28, 1996
|Jul 28, 1998
|Kimberly-Clark Worldwide, Inc.
|Process for producing a film using silane modified elastomeric compositions
|Mar 30, 1998
|Oct 26, 1999
|Union Carbide Chemicals & Plastics Technology Corporation
|Process for the production of a thermosetting composition
|Mar 1, 1979
|Sep 19, 1979
|The Furukawa Electric Co., Ltd.
|Method of crosslinking poly-alpha-olefin series resins
|U.S. Classification
|525/263, 525/288, 524/580, 524/581
|International Classification
|Cooperative Classification
|European Classification
|Feb 17, 1989
Owner name: REXENE PRODUCTS COMPANY
Free format text: CERTIFICATE OF AWMENDMENT OF CERTIFICATE OF INCORPORATION;ASSIGNOR:EL PASO PRODUCTS COMPANY, A CORP. OF DE.;REEL/FRAME:006359/0332
Effective date: 19880830
|Jun 1, 1988
Owner name: EL PASO PRODUCTS COMPANY, 2400 SOUTH GRANDVIEW AVE
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:EL PASO POLYOLEFINS COMPANY;REEL/FRAME:004891/0227
Effective date: 19880318
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:EL PASO POLYOLEFINS COMPANY;REEL/FRAME:004891/0227
Owner name: EL PASO PRODUCTS COMPANY, TEXAS


text:
Tranquil Sarchí is Costa Rica's premier center for crafts and carpentry. People drive here from all over the country to shop for furniture, and tour buses regularly descend upon the souvenir shops outside town. The area's most famous products are its brightly painted oxcarts—replicas of those traditionally used to transport coffee. Sarchí, as Costa Rica's consummate day-trip destination, has developed little acceptable lodging of its own. There are plenty of places to stay, however, in the nearby communities (San Ramón, Atenas, and Alajuela).
Looking back on eight decades on making travel history.More

subset: commoncrawl


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One-month-old girl retrieved from adult bed dies
A one-month-old girl who was found without a pulse and not breathing beside her mother in an adult bed has died, the Milwaukee County Medical Examiner reported Monday.
The father told investigators that the girl, Lilly, slept alone, on her back, in her own bassinet in her parent's room, as recommended by the American Academy of Pediatrics.
On Jan. 10, the report says, Lilly began to cry as her father was getting ready for work. »Read Full Blog Post(3)
Infant dies in car accident
A 3-month-old boy has died from head injuries that he sustained in an April car accident, according to a medical examiner's report released Tuesday.
The boy, David Fateye, died Saturday at Children's Hospital of Wisconsin. »Read Full Blog Post(4)


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The Guggi is a distinctive lookout point offering a unique view of Zug's Old Town with its four defence towers, the castle, the steeple of the Gothic Church of St. Oswald, the Zytturm clock tower as well as the government building by the lake.
The town square by the lake is the centrepiece of Zug. Records show that even back in the 14th century, people's assemblies were summonsed here with the last one being held at this historic location in 1847.


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Ludlow approves $482,000 in bondsMay 09,2013Ludlow voters OK
$482,000 in bonds
LUDLOW Voters approved a new fire truck and infrastructure improvements by comfortable margins at Tuesdays special town meeting.
Article 1 asked voters to pay for a new fire truck with a $180,000 municipal bond over 15 years. The article passed, 72-20.
Article 2 asked voters to pay for infrastructure improvements with a municipal bond of up to $302,000 over 15 years. The article passed, 81-11.
The second bond covers repairs at Bridge No. 17, the Lake Pauline dam, the West Hill culvert, the West Hill storm drain, a culvert at the transfer station and highway garage improvements.
The articles were included in the town budget passed by voters in March, but town officials learned they needed to propose them as separate articles because they involved capital purchases.
Ninety-two out of 1,542 registered voters voted at Tuesdays special town meeting, according to Town Clerk Ulla Cook.MORE IN This Just InKILLINGTON Police are waiting for the results of an autopsy of a 30-year-old woman who was... Full Story
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Avid Audible Subscriber...
"Honor fo the Queen"
Nice series. Find myself wishing for more character building with Honor and the other characters.
I listen to a bit of everything. Mostly Fantasy and paranormal romance with my wife. Along with mysteries/thrillers, even some sci-fi.
"Rich Sci-fi World"
The Second book in the Honor Harrington universe and it's a big step up from the first in the series. This book features Honor and co. visiting the planet Grayson and attempts to sign a treaty to help in the upcoming war against Haven. Haven in the mean time is teaming up with the Masadan's whose arch enemy are the Graysons. Both countries are religious fanatics and believe that women should not be soldiers, much less captains. It's up to Honor to work through the prejudices and get the treaty signed without letting Masada destroy Grayson and try to stop war between Haven and Manticore.
This is a big step up from the first book. The stakes are higher and there's a much more complete story here. Weber lets us know that no one is safe in the Honorverse, and there are repercussions for everyone's actions. I thought that the story was really fleshed out with the politics of Grayson and Masada and their philosophies around religion, women and politics.
Allyson Johnson does a great job with her cast, but there's a point where speech patterns change for a character and she doesn't quite hold it together for the rest of the book which is understandable as it would be very difficult to narrate that for a large portion of the story.
Overall, I really enjoyed this book and I am looking forward to reading more about Honor Harrington and the world he's created.
"What choice do you have?"
Honor of the Queen is the second of the Honor Harrington series, picking up where the last book left off (Captain Harrington assigned a new task, essentially that of protecting a planet and a diplomatic mission). The story itself is entertaining as military-SF and I recommend the book -- not, I should clarify, because David Weber writes great pose but because he tells an engaging story. The series is popcorn fiction at its best, if you know what I mean.
Allyson Johnson narrates the second book much as she did the first, so if you enjoyed the first you'll no doubt enjoy the second. For my own part though ... I have to say that I enjoy Allyson Johnson's "normal voice" reading fine -- she has a pleasant tone, clear diction, and an engaging style. Her character voices, however, I struggle with. In my opinion, she reads most of her characters with an overly expressive emotional range, and with the same affected style where she pauses mid-dialog in almost every conversation (as if none of her characters never think through what they say before they say it). To my ear the voices just do not come sound military or even particularly competent at times. I'm not sure the fault is entirely Allyson Johnson's -- some of Weber's dialog is pretty bad -- but oh how I notice the badness so much more listening to this reading than I do reading the book myself!
Anyway, if you are a Weber fan, you are going to buy it anyway, right? I mean, what choice do you have :) If you are not a Weber fan, I recommend that you read his first Book (On Basilisk Station) before listening to the audio, if that's an option for you. And hey, tastes vary -- you may even love Allyson Johnson's narration. Many do.
"Not at good as book 1"
After finishing this I have to repeat what I said about book 1. The lack of fun and character relationship renders the novel quite plain. The plot is all about bald action with only a few twists here and there. The character relationships are too straightforward. The novel is missing spice and adventure, the thrill, it feels plain. Narrator is quite ok and certainly makes effort to render the novel more interesting.
"I want to love this series"
I would like to LOVE this series but the narrator is not very good at this type of narration. She makes the battle scenes boring and reminds me of a newscastor rather than an actor. She would probably be perfect for some other type of series but this is sci-fi with tech heavy dialogue and intricate descriptions of battle in space. She also seems flat and emotionless during romantic moments, tragic moments and periods of self reflection. The stories come off as one dimensional and at first I thought the problem was with the writer. but, sorry, no. It's the reader. Compare her narration with those of the "Lost Fleet" narrator and see what I'm getting at.
I'm the managing editor of the Fantasy Literature blog. Life's too short to read bad books!
"I'm finished with Honor Harrington"
Though she???s a woman and not a diplomat, Honor Harrington, the highly competent and well-respected Manticoran Navy Captain, has been assigned a diplomatic mission to a planet run by a patriarchal religious cult. Why would the Manticorans send an aggressive woman with no diplomatic skills on this type of mission? There???s only one possible reason: to try to make The Honor of the Queen more interesting...
I wasn???t thrilled with On Basilisk Station, the first book in the Honor Harrington series, because there was too much exposition about military tactics and spaceship dynamics and Honor was too perfect and seemed cold and distant. I decided to read The Honor of the Queen because I already had purchased it in audio and I was hoping Honor would be more relatable as we got to know her better. Actually, she does seem more human, going on an almost murderous rampage at one point and becoming teary-eyed at another. Weber begins to make it clear that Honor has emotions, but we rarely see them and she???s such a Mary Sue that it???s difficult to feel comfortable with her. Even her homicidal rampage was more righteous than reckless.
But my biggest issue with the Honor Harrington series is that the plots so far (I???ve read only the first two books), though exciting at times (e.g., the big space battles at the ends) are constantly being interrupted by dull exposition about base and closing velocities, acceleration rates, missile weights, engagement times, energy ranges, magazine sizes, projected courses, etc.
This material does not have to be dull. As I read, I kept comparing it to Patrick O???Brien???s Aubrey/Maturin (Master and Commander) novels which have analogous plots (just at sea instead of in space). Those books contain a lot of information about warships and naval tactics, but they are immensely entertaining because the protagonists are real people with interests, hobbies, relationships, problems and faults.
To be fair to David Weber, it is certainly possible that my disappointment is partially caused by Allyson Johnson???s narration of the audiobooks. Her voices are pleasant, but she uses little inflection. I downloaded a free print copy of The Honor of the Queen at the Baen Free Library and read several pages that I thought were dull in the audio version. They were better in my head than they were on audio, but I still found myself skimming over some of the exposition (which is difficult to do with an audiobook). I???m not sure that any narrator is skilled enough to make The Honor of the Queen exciting for me or to get me past the glaring problem with the premise of Honor being sent as a diplomat to a misogynist society.
I think I???m finished with Honor Harrington, which is too bad because I spent one of my Audible credits on the third book.
I'll read anything, fiction, nonfiction, sci fi, mystery, young adult, even a romance if it is well written.
"Patrick OBrian goes Sci-Fi"
The story is a little heavy in technical descriptions and battle detail for my taste. The narrator's various accents are very strange, but they are consistent. The story is good and is what kept me going through the first three of the series, but I was disappointed by the somewhat flat handling of character interactons and motivations.
"Cannot connect with this narrator at all"
Best: the story
Least: the narration
The narrator has an odd way of emphasizing too many words. So that there seem to be quotation marks around phrases - not required by the storyline.
The voice chosen for the lead character sounds like a petulant teen. The narrator's own baseline voice would have been a better choice. Captains don't whine.
Read it in print and return the audiobook.
Narration can make or break an audiobook. American narrators often have an odd inflection, that I don't hear in narrators from the UK. It's as if they think it has to be "really serious."
"Great space battles, but dumb plot"
The book is only saved by an exciting space-ship battle at the end. The rest of the time, the heroine does dumb stuff. The rabid patriarchal planet doesn't like women in command, so she runs off in a huff, allowing the rest of the navy to get clobbered. There is some satisfactory revenge as she wins the next space battle and there is real human pathos as she liberates some POW's but then she goes off half-cocked when she finds they've been killed or raped. Weber could've found a more inventive form of revenge. She saves the life of the patriarchal leader, leaving her with physical disabilities, but the leaders had already been pretty much convinced to accept women by then. If we had half star rating, I'd have given this only 2&1/2, not 3 stars.
"Good Followup to Book 1"
The interaction between Honor and the crew. She was facing some difficult choices, and like any commander, some were life threatening. She chose to commit her forces, even though success was not guaranteed.
no answer
When she had to commit a ship to the fight, when she knew it may be destroyed, but it was necessary for mission success.
When she was awarded controll over one of the agro domains.


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Pont du Gain
Les Pâtures, Vinneuf, Yonne, Bourgogne Franche-Comté, France
Copyright: Peter Stockdale
Taken: 1 September 2014
Licensed under a Creative Commons Attribution-ShareAlike licence, see the terms of use
Pont du Gain is a minor waterways place on the River Yonne between Seine - Yonne Jonction (Junction of Rivers Seine and Yonne at Montereau) (18.94 kilometres and 5 locks to the west) and Sens (Cathedral City of Note) (22.46 kilometres and 3 locks to the southeast).
The nearest place in the direction of Seine - Yonne Jonction is Ecluse 13 Vinneuf; 1.13 kilometres away.The nearest place in the direction of Sens is Kilometer Post No 90; 0.08 kilometres away.
|Ecluse 15 Barbey
|6.91 km
|Pont de Misy
|4.67 km
|Ecluse 14 Port-Renard
|2.62 km
|Pont de Vinneuf
|1.20 km
|Ecluse 13 Vinneuf
|1.13 km
|Pont du Gain
|Kilometer Post No 90
|0.08 km
|Pont Morlaix
|0.70 km
|Stop Lock Courlon
|2.16 km
|Pont de Courlon
|2.16 km
|Kilometer Post No 84
|6.26 km
0 votes cast
Mooring here is "unrated" - please vote if you know the place
Users' comments on mooring here
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There is no page on Wikipedia called "Pont du Gain"
Wikipedia pages that might relate to Pont du Gain[Éleuthère Irénée du Pont] [Du Pont family] [Pont du Gard] [Louvre] [Battle of Pont-Barré] [Florida National Bank] [Danisco] [Louis Du Pont Duchambon] [United States Senate elections, 1922] [Verneuil-sur-Avre]
Information retrieved Tuesday 28 June 2016 at 20:42
- Vinnu's FastFood & Catering Services (Indian Restaurant, Chinese Restaurant)
1099 to the northeast.
Local business
- Lac De Vinneuf (Lake)
754 to the southeast.
Information retrieved Tuesday 28 June 2016 at 20:42


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Lowest price$60
Just a 20-minute walk from Founders of Atlantida Plaza and Atlantida Zoo, Hotel Argentina offers 3-star Atlantida hotel accommodations. Eagle's Nest is 1.2 mi (2 km) away.
Along with free continental breakfast, this hotel offers concierge services. Go for a dip in the indoor pool during your stay. Leisure facilities on offer include a spa tub.
Along with free continental breakfast, this hotel offers concierge services. Go for a dip in the indoor pool during your stay. Leisure facilities on offer include a spa tub.
Multilingual staff at the 24-hour front desk can provide tour/ticket assistance. Free WiFi and high-speed (wired) Internet access is available.
One overnight stay in this small resort town. Hotel close to beach & main shopping area. Hotel a little dated but no problem. Very friendly staff. Enjoyed our stay.
TripAdvisor Traveller Rating: 4.5
From 180 reviews
Hotel Argentina - Atlantida
Hotel Info: 1-877-214-4288from $60
- Single Room
- Double Room
- Triple Room
Also popular with travelers from the USA
At a glance
Key facts
Hotel size
- This hotel has 40 rooms
- This hotel is arranged over 2 floors
- 24-hour check-in
- Check-out time is 10:00 AM
Required at check in
- Credit card or cash deposit required
- Government-issued photo ID required
Travelling with others
- No cribs (infant beds)
- Pets not allowed
- Free WiFi and wired Internet access in public areas
- Free WiFi in rooms
- Valet parking *
Other information
- Resort fee included
In the hotel
Food and drink
- Free continental breakfast daily
- Coffee shop/café
- Room service (during limited hours)
Things to do
- Beach towels
- Indoor pool
- Children's pool
- Spa tub
- Bicycle rentals nearby
- Scooter/moped rentals nearby
- 24-hour front desk
- Concierge services
- Tours/ticket assistance
- Luggage storage
- Multilingual staff
- Number of buildings/towers - 2
- Safe-deposit box at front desk
- Library
- Television in common areas
In the room
Home comforts
- In-room climate control (air conditioning)
- Air conditioning
- Ceiling fan
- Minibar
Freshen up
- Private bathroom
- Shower only
- Bidet
- Free toiletries
- Hair dryer
Be entertained
- Cable TV channels
Stay connected
- Free WiFi
- Phone
- Daily housekeeping
- In-room safe (laptop compatible)
Hotel Argentina - Atlantida's small print
Also known as
- Argentina Atlantida
- Hotel Argentina Atlantida
Only registered guests are allowed in the guestrooms.
This property does not have elevators.
Mandatory fees
You'll be asked to pay the following charges at check in or check out:
- All citizens of Uruguay will be charged the national value-added tax (10%) from November 15 to the day after Easter. However, business travelers from firms in Uruguay will be charged the value-added tax year round. Foreigners on a tourist visa are exempt from this tax.
The charges below are included in the total price displayed:
- Resort fee
Optional extras
Self parking costs UYU 300 per night
Valet parking costs UYU 300 per night
We have included all charges provided to us by this hotel. However, charges can vary, for example, based on length of stay or the room you book.


text: how retail keeps hitting new highs?I tought unemployment was an issue and with everyone's net worth down about 40% and retailers downsizing they're pps is going up like they are one of the fastest growing sectors in a very robust economy.Is all due to the hope and dream optomistic recovery phase everyone is hoping for. The problem is as long as gov keeps printing the dow could go to 20000 but milk would cost $20 gal but investment statements would look good right. At this rate there might be one to two retailers with little inventory selling to very little shoppers. But when will that time come 6 months or 6 years.Look at OXM! out of sight and the just got a major baseball contract to supply world series shirts. I bet that will make them a ton of money?


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According to the Spanish Ministry of Culture, El Plan de Fomento de la Lectura is a a Reading Program destined to promote the "reading habit" among Spaniards, understanding the "reading habit" as the key factor for success in terms of personal development and social interaction, without which one could hardly survive within democratic societies. So it "reads" in the Reading & Library Act and Regulations (Ley 10/2007 de 22 de junio).
The Program conceives the reading habit promotion as a task which differs from reading capabilities which start within the family and schools, and that needs people and places which favour the access to books.
Thus, the promotion program for reading habits enhancement is understood as a task common to the whole society as a result of a closer collaboration among the leaders of cultural, social, educative and communication policies. Setting it into practise has led to several collaboration programs and agreements among national public and private organisations which enable the involvement of all individuals in order to consolidate a more reading society.
- Promotion and increase social awareness towards the relevance of reading.
- Improving access to both public and school libraries, as well as a better supply of them.
- Organising cultural and promotional activities in order to focus on reading in many different scopes.
- Aid for disfavoured communities (immigrants, the elderly, handicapped or inmates) to accede to books and reading, backed up by not-for-profit initiatives and other either public or private organisations.
The program structure comprehends six areas:
- Close, detailed Reading Workshop, as an analysis tool.
- Increasing voluntary reading in Educational Centres.
- Promotion of Public Libraries.
- Communication Programs.
- Reading Promotion Programs.
- Promotion of Awareness and Collaboration among Organisations involved.


text:
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– Airy, cushioned formula– Gently blurs imperfections– Buildable
Shipping And Returns
Local Delivery & CollectionFree local delivery with minimum $100 purchase. Delivery will be made within 24 hours unless otherwise stated, orders received after 6pm will be processed on the following day.Maximum 10 local delivery locations in one order – free delivery fee entitlement based on average $100 purchase for every location.Click & Collect service is available at TANGS at Tang Plaza, Click & Collect Counter L4 or TANGS VivoCity, Customer Service Counter L1. Please present your Order Confirmation Receipt to collect your merchandise.
Return & ExchangeWe accept exchange, returns or refund within 30 days of purchase except TANGS Gift Card, Food (seasonal), Hamper, Pre-order, Workshop and Services. Merchandise must be in original condition and packaging together with the Order Confirmation Receipt.Local purchases can only be returned at our TANGS at Tang Plaza, Click & Collect Counter L4 or TANGS VivoCity, Customer Service Counter L1. We do not accept any local returns through mail.
Refund credit will be in the form of TANGS Credit Vouchers. Customers are also required to return any free gift(s) and samples received from the purchase.For more information and overseas delivery, please refer to Delivery & Collection and Return & Exchange
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Shu Uemura
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Nars Dual-Intensity Blush
Clinique Cheek Pop


text:
Home values continue to rise nationwide.
According to Standard & Poor's Case-Shiller Index, home values made another year-over-year increase in June, highlighting what many of today's buyers have already discovered the hard way -- it's getting harder to find "cheap housing".
Since reaching a bottom in 2012, home values have climbed more than 36% nationwide.
These higher home prices may be one of the reasons why, according to the National Association of REALTORS®, more than 3-in-10 buyers are first-time home buyers.
Current mortgage rates are down and national rents are rising. It's often less costly to purchase a home than to rent one.
Plus, it's getting simpler to save for down payment.
In today's market, there are abundance of low- and no-down payment mortgages -- including the recently-introduced HomeReady™ mortgage, which allows just 3% down.
There are more ways to get into a home cheaply than during any period this decade.Click to see today's rates (Sep 25th, 2016)
Standard & Poor's recently released its June 2016 Case-Shiller Index.
The Case-Shiller Index tracks home price changes both from month-to-month, and from year-to-year, in select cities nationwide.
Tracked cities include San Diego, California; Los Angeles, California; and Phoenix, Arizona.
As compared to the year prior, home values are higher in all 20 tracked markets, led by an 12.6 percent gains in Portland, Oregon; and double-digit gains in San Francisco, California.
The "weakest" of the Case-Shiller Index cities was Tampa, Florida. Home values there rose just 2.0 percent over the prior 12 months. Values in New York City also rose just two percent, but the New York market has some mitigating factors. Namely, it's property-type mix.
Despite the relative strength of today's housing market, home buyers should use caution when referencing the Case-Shiller Index as part of a personal POST.
The monthly index is flawed and may push you toward improper conclusions.
The index's first flaw is its most obvious -- its limited sample set.Click to see today's rates (Sep 25th, 2016)
The Case-Shiller Index tracks 20 U.S. metropolitan markets and brands itself a national index. Yet, according to Wikipedia, the U.S. is home to more than 3,100 different municipalities.
This means that the Case-Shiller Index tracks fewer than one percent of all U.S. cities.
Furthermore, its 20 tracked cities tracked aren't even the nation's 20 most populous. Four of the 10 most populous U.S. Cities -- Houston, Texas; Philadelphia, Pennsylvania; San Antonio, Texas; and San Jose, California -- are notably absent from the Case-Shiller Index 20-City Composite.
By contrast, smaller cities such as Minneapolis, Minnesota (#48 in population) and Tampa, Florida (#55 in population) are not excluded.
The "national" Case-Shiller Index, in other words, is not very national at all.
Even on a city-by-city basis, the Case-Shiller Index gets it wrong. This is because the index lumps disparate city neighborhoods into a single, city-wide reading.
In Chicago, for example, some neighborhoods definitely out-gained others.
Values in Lincoln Park and Lakeview change differently from values in Wicker Park and Bucktown, just as values in Manhattan and Brooklyn differ in New York City.
A second Case-Shiller Index flaw is its methodology.
The index considers only "repeat sales" of the same home in its findings, and those homes are required to be single-family, detached properties. This means that condominiums, multi-family homes, and new construction are not included.
In some cities, these "excluded" property types account for a large percentage of total monthly sales.
New York City meets this criteria with its heavy concentration of condos and co-ops, as does Chicago, Boston, and, to a lesser extent, Los Angeles whose footprint extends into Orange County.
With its limited property type set, Case-Shiller captures only a portion of the overall housing market.Click to see today's rates (Sep 25th, 2016)
A third Case-Shiller Index flaw is the "age" of its data.
Because Standard & Poor's publishes on a 60-day delay, the Case-Shiller Index is reporting on a housing market that no longer exists. But, the data is even older than that.
Home sales tracked by the Case-Shiller Index include an average of three months of home sales data. This means that home sales data from April, May, and June are lumped together in the June report; and, because homes can take 60 days or more to close, the index results are based on contracts written as far back as February.
In other words, the Case-Shiller Index is telling us about sales from as many as 7 months ago.
That's of little help to home buyers today.
It's 2016 and the U.S. housing market is different from what it was two seasons ago. Mortgage rates are different, global markets are different, and even the Federal Reserve's monetary policy is different.
This seven-month lag time may not matter much to economists and policy-makers and other people taking a long-view of housing economics. But, to an individual buyer or seller of a home, that time lag renders the index close to useless.
The Case-Shiller Index will never be your "real-time" real estate indicator. However, it can highlight valuation trends, and the trend is toward higher values nationwide
Take a look at today's real mortgage rates now. Your social security number is not required to get started, and all quotes come with instant access to your live credit scores.Click to see today's rates (Sep 25th, 2016)
The information contained on The Mortgage Reports website is for informational purposes only and is not an advertisement for products offered by Full Beaker. The views and opinions expressed herein are those of the author and do not reflect the policy or position of Full Beaker, its officers, parent, or affiliates.
Sarah M. Office Manager
The Mortgage Reports has been an invaluable resource to me -- it helped me to pick the sweet spot to refinance. Thanks!
Don B. Retired
The Mortgage Reports has helped me so much. I can't thank you enough.
Stefan J.
The Mortgage Reports is invaluable. It's our primary source for information on housing finance.
2016 Conforming, FHA, & VA Loan Limits
Mortgage loan limits for every U.S. county, as published by Fannie Mae & Freddie Mac, the Federal Housing Administration (FHA), and the Department of Veterans Affairs (VA)


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Welcome to the new Okanagan Makers events!
Join us throughout the summer in Summerland, Penticton and Oliver, and at our 20th Annual Christmas Show in Penticton this November.
Tune into this website for continued updates on our markets!
Applications for the 20th Annual Okanagan Makers Christmas Craft & Sustainable Living Show are now OPEN!
Click here to send yours in today!
OK Makers are proud to support local community initiatives, and we look for more ways to make a difference in your community.
Some of our past partners include:


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Ottumwa wants residents' feedback on how to better make the city shine.
The goal of the event is to adopt houses for cleanup, target different areas of the community for trash pick-up and generally make Ottumwa a more beautiful place. The annual Make Ottumwa Shine event is held around the last week of April each year. However, the committee may consider moving that date back into early May due to the cold weather this year.
Residents are welcome to attend a meeting on Wednesday to discuss a date for this year's events, along with what type of clean-up events to include.
Program coordinator Jody Gates said Make Ottumwa Shine only continues with the help of volunteers.
"Volunteers are crucial, every year we get anywhere from 50 to maybe 200 and when other entities join us and participate, they bring their volunteers too and we've had as many as 300 volunteers before," Gates said.
The meeting will be held at 4 p.m. in the council chambers at City Hall.


text:
Possible Answer
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Jamie Nell Colby is an American national news correspondent and anchor for Fox News Channel (FNC). She is host of the series, "Strange Inheritance", on Fox Business ... - read more
Please vote if the answer you were given helped you or not, thats the best way to improve our algorithm. You can also submit an answer or search documents about jamie colby measurements.


text:
Chris Young + More Country Stars to Perform at Sports Illustrated Swimsuit Bash
It may still be icy cold in Nashville, but that's not stopping Sports Illustrated from celebrating like it's summertime.
It may still be icy cold in Nashville, but that's not stopping Sports Illustrated from celebrating like it's summertime.
We've been hearing bits and pieces about various elements of 'Avengers: Age of Ultron,' from the origins of Ultron and Vision to who Andy Serkis might be playing in the film. But we haven't heard a whole lot about what's up with Scarlet Witch and Quicksilver, the super-powered twins teased at the end of 'Captain America: The Winter Soldier.' What we do know is that they're going up against the Avengers. What we haven't known is why…until now. Plus, Marvel has released a bunch of photos from the upcoming sequel, in case you felt like Hulking-out.
Sometimes life throws you curveballs and sometimes you respond to the curve and othertimes you just keep swinging away.
This may be the mantra that Dennis Rich, former Sedalia Democrat editor, is enduring...
Forged in the fires of Mount Doom, the Ring of Power was stripped from the hand of Sauron following the final battle with the Last Alliance and became of a keepsake of Prince Isildur. Now corrupted by the One Ring, Isildur fell in battle, losing the ring to the river. From there, "Isildur's Bane" fell into the hands of the creature known as Gollum and from there, into the hands of the Hobbit known as Bilbo Baggins. It was only through the efforts of the Fellowship of the Ring and the brave Frodo Baggins that the One Ring was destroyed forever ... or so we thought. Because the ring has fallen into the hands of a young Texas boy, who was suspended from school for wielding such an accursed tool.
Everybody knows by know of the Stan Lee cameos in the Marvel movies, and 'Captain America: The Winter Soldier' is no exception. You probably also recognized the voice of Gary Sinise as the narrator of the Captain America exhibit at the Smithsonian in the movie. But, did you catch the blink-and-you'll-miss-it cameo by 'Avengers 2' director Joss Whedon? Don't worry, we've got that, and a lot more for you, in the latest patriotic installment of You Think You Know Movies!
Back when Disney paid $3 billion to purchase Lucasfilm, most focused on what they could and would do with the 'Star Wars' franchise. But, let's not forget about that other big Lucasfilm franchise: Indiana Jones. If Disney's dropping stacks on stacks for Lucasfilm, you better believe they're going to want their money's worth, and that includes a new series of Indiana Jones movies. Case in point: Disney has reportedly ready to focus on a reboot of the popular character and want 'Guardians of the Galaxy' star Chris Pratt to take over the whip from Harrison Ford.
Winter Reading is here! The Sedalia Public Library has a new and interesting theme for their program, all to encourage kids to keep reading.
Marvel publisher Dan Buckley gave a three-part interview with comic industry blog ICv2 this week in which he discussed the company's performance in 2014 and its strategies for the year ahead. The interview ranged across digital sales, graphic novel sales, and the impact of the Marvel movies on the comics -- but of particular interest to ComicsAlliance were Buckley's comments on reaching a more diverse audience of new comics customers.
While acknowledging that Marvel and the industry at large has never done much consumer research, Buckley said the company has been "aggressive in trying a lot of diverse product over the last two years," as part of an initiative spearheaded by Editor-in-Chief Axel Alonso. According to Buckley, the results of that outreach have been very positive.
One of the things we always stress to little ones is to read and keep reading. And that's great, it's absolutely essential. But the kids aren't the only ones who need to read.
Textbook distribution begins January 8th continuing on through January 19th with special store hours. . Normal store hours begin January 20th, with the UCM Store being open 7:30 am-5:00 pm...


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Courses are taught by faculty from across the College of Arts and Sciences and each one has an interdisciplinary aspect. We break down departmental barriers to explore important questions through a variety of perspectives.
What does it mean to be human? How do we understand the world we live in? Where did we come from and where are we going? Each MALS course invites broad thinking on issues of importance.
Within the broad parameters of the program, you are free to shape your course of study to suit your intellectual interests, to follow your passion.
Small seminar classes mean that you learn from your classmates as well as your professors. The diversity of the student body, the richness of the life experiences and the variety of their interests creates a stimulating and dynamic learning environment.
While many MALS students are in the program for the pure joy of learning, the program cultivates important skills sought by employers: critical thinking, problem solving, research methods, writing, presentation skills.
You can complete the degree on a part-time basis and classes are held in the evening for the convenience of those who are working. No GRE scores are required for admission.
The MALS program encouraged 2014 alumna Michele Walfred to combine her interests in journalism and art with her growing fascination for the 19th century American immigration experience. Originally motivated to explore her own Irish heritage, her last MALS course, Contemporary Culture: Asian Immigration to America, inspired Walfred to look beyond the familiar and probe deeper into the commonalities between the Irish and Chinese immigrant experiences, and the social, cultural and political reasons for their volatile relationship in a youthful yet expanding America.
Walfred's capstone project, Illustrating Chinese Exclusion (www.thomasnastcartoons.com) explores the 46 cartoons drawn by Thomas Nast for New York-based Harper's Weekly, and compares Nast's depictions to that of George F. Keller, who drew for The San Francisco Illustrated Wasp. It is the first thorough examination of Thomas Nast's work featuring Chinese immigrants, Chinese Americans and U.S.-China relations as subjects for editorial cartoons.
While Illustrating Chinese Exclusion provides a glimpse into the percolating immigrant issues of that era, Walfred's historical spotlight remains relevant today as national conversations about immigration and inclusion/exclusion continue to be passionately discussed.
Nearly 173,000 have visited the website in its first two years. Walfred's MALS project is used as a resource for high school students and colleges such as University of Dayton, University of Connecticut, Louisiana State University, Baruch College-CUNY, St. Joseph's College and Brandeis University to name a few. Her work has been cited by NPR, Politico and The Boston Globe, among others.
"The MALS program changed how I view everything," says Walfred. "I soon found that what you think you know, or what has been handed down to you, is often coming from a limited point of reference. The MALS program has trained me to look around. Indulge my curiosity. Go find out. Explore. Peel back the layers. You will be surprised by what you discover!"
"My current
connection to the arts in the state is closely related to the University
of Delaware. UD was the first intellectual home I had when I moved to
Delaware. One of my first classes at the MALS program was "Art in the
Twentieth Century"... where we explored the renewed impact of the
Mexican Muralism Movement. By opening this world to me the MALS program
nurtured my ongoing involvement with the arts and culture in the
Guillermina Gonzalez is a multicultural professional with
experience in the United States, Mexico, and Europe in her successful
career as an executive in both the corporate and nonprofit sectors. She
began her career working for multinational organizations in marketing
and sales and has since brought her corporate expertise to the nonprofit
sector. Currently, she is the Executive Director of the Delaware Arts
Alliance, the highly active arts advocacy group in the state.
Previously, she served as the Executive Director of the advocacy
organization Voices Without Borders.
Dr. Gonzalez is actively
involved in the community and serves as the Chair of the Americans for
the Arts' State Arts Action Network and Delaware's NPR radio WDDE
Community Advisory Board. She has served on the Delaware State Arts
Council, as well as on boards of Delaware College of Art and Design,
Metropolitan Wilmington Urban League, Latin American Community Center,
and the AARP Executive Council. The University of Delaware's College of
Arts and Sciences distinguished Dr. Gonzalez with the Alumni
Achievement Award in May 2014.
Dr. Gonzalez has an MBA from
Universidad Iberoamericana in Mexico City, where she taught marketing
and business administration. She holds a Certificate in Leadership and
Public Management and a Master of Arts in Liberal Studies from the
University of Delaware. She obtained her doctorate in Business
Administration at Wilmington University in January 2014.


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SLV: Seasonally Strong In February?
In a recent StockTwits post, New York City-based trader Alex Tarhini shared the graphic below, which suggests that the iShares Silver Trust ETF (NYSEARCA:SLV) is seasonally strong in February.
Last Two Years Suggests Caution Is Warranted
Time will tell whether this February ends up being another strong one for SLV, but investors in the ETF have had to weather 3 drops of approximately 30% within just the last two years:
For SLV investors holding the ETF and hoping for further upside this month, but also looking for some downside protection, in this post, we'll look at two ways to hedge it.
Two Ways To Hedge SLV
The first way uses optimal puts*; this way has a cost, but allows uncapped upside. These are the optimal puts, as of Friday's close, for an investor looking to hedge 1000 shares of SLV against a greater-than-20% drop between now and July 19th:
As you can see in the screen capture above, the cost of those optimal puts, as a percentage of position, is 1.18%. Note that, to be conservative, cost here was calculated using the ask price of the optimal puts; in practice an investor can often buy puts for a lower price (i.e., some price between the bid and the ask). By way of comparison, the current cost of hedging the SPDR Gold Shares ETF (NYSEARCA:GLD) against the same decline, over a somewhat longer time frame (until September 20th), is 0.35% of position value.
An SLV investor interested in hedging against the same, greater-than-20% decline between now and July 19th, but also willing to cap his potential upside at 20% over that time frame, could use the optimal collar** below to hedge instead.
As you can see at the bottom of the screen capture above, the net cost of this optimal collar is zero.
*Optimal puts are the ones that will give you the level of protection you want at the lowest possible cost. Portfolio Armor uses an algorithm developed by a finance Ph.D to sort through and analyze all of the available puts for your stocks and ETFs, scanning for the optimal ones.
**Optimal collars are the ones that will give you the level of protection you want at the lowest net cost, while not limiting your potential upside by more than you specify. The algorithm to scan for optimal collars was developed in conjunction with a post-doctoral fellow in the financial engineering department at Princeton University.
The screen captures above come from the latest build of the soon-to-come 2.0 version of the Portfolio Armor iOS app. Optimal collar capability will be available as an in-app subscription in the 2.0 version of the app.
Instablogs are blogs which are instantly set up and networked within the Seeking Alpha community. Instablog posts are not selected, edited or screened by Seeking Alpha editors, in contrast to contributors' articles.
I would appreciate a reply
Thanks for very relevant information,
I hope that clarifies it, but if you have any follow up questions, please feel free to ask.


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Aggressive Inline (video game)
|Aggressive Inline
North American PlayStation 2 cover art
|Z-Axis Games
Full Fat (GBA)
|AKA Acclaim
|PlayStation 2
Game Boy Advance
|Release date(s)
|PlayStation 2[1]
|Single-player, multiplayer
Aggressive Inline is a 2002 aggressive inline skating video game developed by Z-Axis Ltd. and Full Fat and published by Acclaim Entertainment under their AKA Acclaim brand. The game features professional inline skaters, including Chris Edwards, Eito Yasutoko, Franky Morales, Jaren Grob and Taïg Khris.
The gameplay focuses on completing goals given by talking to characters within each level. While some goals involve gaining a certain amount of points in a specific time, many of the goals involve doing tricks on and off of pieces of the environment (for example: one level asks the player to grind three traffic lights, each one placed at a larger distance and facing a different direction). Another innovative feature focused on a player leveling system where the player would perform better in different areas of skating skill by practicing them repeatedly. For instance, if the player does many air tricks throughout the course of the game, each successful trick would create points in the player's air trick statistics. When the points reach a certain amount, the player's air tricks will move up a level, making it easier to perform air tricks faster and more efficiently. The same actions apply to grinding, speed, wall riding, skating backward, etc.
The game received praise for its wide and interactive environments, comfortable control scheme, and innovative gameplay. At the time, it was considered to be a breakthrough competitor to the Tony Hawk's Pro Skater series, even being the first to include some elements that would later become standard in the Tony Hawk games, most notably not confining players to rigidly timed play sessions. In addition, the ability to transition from one trick to another seamlessly without having to do any actions in between made for a more streamlined combo system than the Tony Hawk series and most other action sports titles at the time, where players had to perform transition maneuvers such as ollies or flips to link one trick to another - although some fans of the genre considered this aspect of Aggressive Inline's trick system "too easy." The game generally received good reviews for its style of play, with the average review ratio for the PlayStation 2, Xbox and Gamecube being 85%, with the Game Boy Advance version receiving worse scores than the versions on consoles (mainly because the GBA version had more of a "do these goals, hit this score, reach the finish" system than console).
- Black Sheep - "The Choice Is Yours (Revisited)"
- Boy Hits Car - "I'm a Cloud"
- Eric B & Rakim - "Don't Sweat the Technique"
- Hoobastank - "Crawling in the Dark"
- P.O.D. - "Youth of the Nation"
- Reel Big Fish - "Sell Out"
- Saliva - "Your Disease"
- Student Rick - "Falling For You"
- Student Rick - "Monday Morning"
- Sublime - "Wrong Way"
- The Ataris - "Song 13"
- The Pharcyde - "Passin' Me By"
- The Vandals - "An Idea for a Movie"


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Photographer from South Queensferry / Edinburgh, Scotland. Weddings, portraits, families, real estate, events, industrial, kids, Your idea, pets, landscapes, sporty and Personal learning of photography.
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