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book it
Bookcase: This bookcase by Jaren Goh, described as "vintage with the purpose of blending the flamboyance of the baroque style with the simplicity of the contemporary approach," is the perfect piece to showcase your collection of chick literature and make a statement that goes beyond the bindings. From Fyndes LA, $2399
Tamara Goodwin has always got everything she's ever wanted – wealth, private beaches, designer clothes…Always living in the here and now, never giving a second thought to tomorrow. But suddenly, life for Tamara and her mother changes forever. Left with a mountain of debt, they have no choice but to sell everything they own and move to the country to live with Tamara's aunt and uncle. When a traveling library passes through town, Tamara is intrigued. Lonely and bored, she welcomes a distraction. Her eyes rest on a mysterious large leather bound tome locked with a gold clasp and padlock. With some help, Tamara finally manages to open the book. What she discovers within the pages takes her breath away and shakes her world to its core
The story of one girl's life falling apart and what she finds out along the way as she tries to put it back together again. Natasha Kapoor should be a successful jeweller in East London with a gorgeous husband and everything should be perfect, but it's not. When her grandmother dies and she travels back to the family home, she is given the old scribbled diary of her aunt Cecily, who left behind a broken family and a terrible secret. Revealed from the pages is a tragic tale of love, rivalry and heartbreak. Will Cecily's words, though written forty years ago, inspire Natasha to take a chance on love?
After listening to her closest friends' latest travails in love, parenting, and careers, superstitious bride-to-be Nicole believes she has the perfect recipe for everyone's happiness: a bridal shower "cake pull" in which each ribboned silver charm planted in her cake will bring its recipient the magical assistance she needs to change her destiny. Melissa, still ringless after dating the same man for six years, deserves the engagement ring charm. Seema, who is in love with her best male friend Scott but can't seem to make their relationship more than platonic, would get the chili pepper. And for herself, Nicole wants the shovel to help her get her career back on track. Nic does everything she can to control who gets which silver keepsake – as well as the future it represents. But when the charmed cake is mysteriously shifted from the place settings Nic arranged around it, no one gets the charm she chose for them. And when the other party guests' fortunes begin coming true, Mel, Seema and Nic can't help but wonder, is the cake trying to tell them something?


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Ever since scanning gave retailers a quick read into daily sales, industry pundits have held out the promise of using computers to take care of replenishing in-store stock. The beauty of this process, generally known as computer-assisted ordering, is that computers can generate orders based on a cold, hard analysis of consumer demand, rather than on more ad hoc measures such as filling holes on the shelf or stocking up on the latest manufacturer deal. In theory, CAO would lead to fewer ...
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subset: commoncrawl


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I keep getting the same error on TAD. After about 5 - 6 tries, rebooting 3 times and re-installing once, I still cannot access online. I get an error saying cannot connect to server etc... and then it says to make sure I can connect to www.aoe.com, so, while online was loading, I opened an internet page and typed in www.aoe.com, and POOF! I can connect! But I still can't access multiplayer , so! Any help would be appreciated.
Have a read here -Multiplayer Connectivity - ESO


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Interest Level
Grades PreK - K
Reading Level
Grade level Equivalent: Not Available
Lexile® Measure: Not Available
DRA: Not Available
Guided Reading: Not Available
- Informational
- Alphabet Recognition
- Animals
About This Book
Animalia is a book like no other. Abounding with fanciful, gorgeously detailed art, it is an alphabet book, a guessing game, and a virtual feast for the eyes. Each page features one letter and images related to that letter — as well as a hidden picture of Graeme Base as a child! Animalia will entrance any child or adult who enters its fantastical world.
Items Added to Cart:
1 Paperback
2 Hardcover
1 Teacher's Edition
$48.99 Subtotal


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In some state legislatures and Congress, it has been suggested one means of holding down spending would be to require that when new programs are mandated, budgets for existing ones be pared down. Taxpayers can afford only so much, after all.
Perhaps state legislators should consider a similar strategy for public schools.
A bill approved by the Ohio House of Representatives would require high school students to be taught more about the state and federal constitutions, the Declaration of Independence and other basic documents of government. They would be required to read, and presumably discuss, the documents.
That is an excellent idea, though we join others in wondering why the Bill of Rights was excluded from the legislation.
But critics have another good point: Teachers and students already strain under a mountain of specific curriculum requirements from state and federal governments.
Clearly, there need to be some guidelines, especially in basics such as English, mathematics, science and social studies. But through the years, teachers - and thus, students - have been burdened with a variety of mandates that sometimes should not be viewed as priorities.
On a fairly regular basis, many school districts and states re-examine curriculum requirements. Too often, so politicians can avoid criticism from special interests, they include non-essential studies and activities.
As a result, teachers are unable to concentrate on the really important instruction. Students are bombarded with information. The basics suffer.
Ohio state senators should follow the House's lead and approve the rule requiring more study of basic documents of government. At the same time, they should ask the state Department of Education for suggestions on curriculum mandates that could be eliminated.
It is all about priorities. In an increasingly complex world, public schools should be able to get back to the basics.


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Regional Breakdown
Listing of ReportedCampus
Campus Anti-Semitism
Veteran Holocaust-denier Bradley Smith, who runs a group called
the Committee for Open Debate on the Holocaust, continued his longtime
campaign seeking to place paid advertisements in college and university
newspapers. These ads, in subtle and not-so-subtle ways, cast doubt
on the reality of the Holocaust. This year, he produced both a new
quarter-page ad and a separate 27-page newsprint document designed
as a supplemental insert into campus newspapers. He found nine takers
for his ad and two -the campus newspapers at Hofstra University
and Boise State University - which distributed his insert.
Through the combined efforts of ADL:s Campus/Higher Education Affairs
Department and Regional Offices, often working with Hillel and other
organizations, the alarm has been heard in the campus journalistic
community regarding Smith's campaign. ADL has produced a counteraction
packet that has been distributed to campuses across the country.
The ADL Web site contains an extensive documentation and analysis
of the Holocaust-denial campaign that is widely accessed on many
The League continues to maintain its vigilance and increase efforts
at counteraction. One item of particular note is a forthcoming invitational
colloquium, cosponsored by ADL and The New York Times, in
which top professional journalists from The Times will work
with campus newspaper editors to develop professionally valid standards
of advertising acceptability and suitability. Our hope is that this
program will result in campus journalists coming to understand more
fully that the rejection of Holocaust-denial and other hate group
advertisements is fully in accord with all accepted standards of
freedom of speech and of the press.
Hate on campus has not been restricted to the Holocaust-denial
campaign. ADL has worked with Northwestern University in responding
to the repeated efforts of Matt Hale, head of the white supremacist
group, The World Church of the Creator, to come onto the campus
and register his so-called "church" as a recognized religious
association. ADL worked with the Housing and Student Affairs staff
at Fordham University to craft a response to an outbreak of swastika
graffiti in the dormitories. The League worked with Georgetown University
and with local and Federal law enforcement authorities when a Menorah
on campus was vandalized and subsequently attacked a second time.
Counteraction and Prevention
ADL programs on campus seek to prevent acts of bigotry as well
as respond to them. These programs include the Albert Finkelstein
Memorial Study Mission to Poland, Bulgaria and Israel for Campus
Newspaper Editors, the Bess Myerson Campus Journalism Awards, and
the Samuel and Mildred Levine Institute to Combat Bigotry on
Campus. ADL Campus Affairs staff recently provided a comprehensive
workshop on responding to acts of hate and hate crimes to the entire
corps of Resident Advisers at Ohio State University. ADL's A CAMPUS
OF DIFFERENCE" program is bringing effective anti-bias education
training to many campuses and The "Blacks and Jews in Conversation"
program brings Jewish and African-American state court judges to
campus to promote intergroup dialogue.
Audit of Anti-Semitic Incidents Front Page | Combating
Hate Front Page
1998 Audit of Anti-Semitic Incidents Front
Page | ADL On-line Home
| Search
| About ADL
| Contact
� 2000 Anti-Defamation League


text: In August 2012, state and local governments responsible for U.S. Rt. 340 in the local areas of West Virginia, Virginia and Maryland held a meeting in Bolivar to hear public comments regarding improvements that could be made to Rt. 340 across the jurisdictions (The Journal, Aug. 17, 2012). We would wager that no one in attendance suggested installing two new traffic signals between Harpers Ferry and Charles Town, the result of which has been to further impede the smooth flow of traffic in both directions.


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Tim wrote:
> Hello,
> I am looking into having a 2nd T1 brought into our building. This
> one will be used for Video Conferencing, Websites, and IP phones. We
> need to have they WebSites on the new T1 to be able to see the
> Servers on our current network which is on our current T1 with the
> public IP's it provides as well as non-public through DHCP. Both
> T's will have their own router and firewalls and different IP ranges.
> What would be the easiest way to have the 2 different Networks to be
> able to communicate seemlessly as they were one network while keeping
> the Bandwidth on each T seperate?
> Thanks.
> Tim
Hire a professional.
Q (I'm not kidding)


text:
Notable Features
- Retro styling
- New inline-five-cylinder for 2006
- Manual or automatic
- Coupe or convertible
- Available Engines:
- 100-hp, 1.9-liter I-4 (diesel)
- 150-hp, 2.5-liter I-5 (regular gas)
- Transmissions:
- 5-speed manual w/OD
- 6-speed auto-shift manual w/OD and auto-manual
- 6-speed automatic w/OD and auto-manual
Expert Snapshot
What We Like
- Visual appeal, especially of convertible
- Ride comfort
- Steering response
- Performance of manual-shift diesel
- Resale value
What We Don't Like
- Backseat space
- Cargo space in convertible
- Once innovative design now somewhat dated
3 Styles: View, Compare & Price
Standard Engine
See specs for optional engines
2.5 2dr Hatchback
See Specs
5 cyl.
150-hp, 2.5-liter I-5 (regular gas)
150-hp, 2.5-liter I-5 (regular gas)
Destination charge: $630
TDI 2dr Hatchback
See Specs
4 cyl.
100-hp, 1.9-liter I-4 (diesel)
100-hp, 1.9-liter I-4 (diesel)
Destination charge: $630
2.5 2dr Convertible
See Specs
5 cyl.
150-hp, 2.5-liter I-5 (regular gas)
150-hp, 2.5-liter I-5 (regular gas)
Destination charge: $630
* MPG may vary based on maintenance.
Featured Services for this Volkswagen New Beetle
- Sell your current car quickly and easily on Cars.com.
- Not sure what auto repair should cost you? Use our price estimator.
- Get help with car repair now on Cars.com. Visit Repair & Care


text:
February 2014
Lee Memorial Health System
Lee Memorial Health System Named Employer of Choice
Lee Memorial Health System has been awarded the designation Employer of Choice in recognition of its dedication to a workplace that attracts, optimizes and retains high quality employees. The Employer of Choice designation is awarded by Employer of Choice International, Inc., after completing a rigorous evaluation process and review by an expert panel of independent human resource consultants.
Lee Memorial Health System recognizes the significant value of hiring and retaining employees with the experience and skill necessary to provide the highest quality patient care, says Joyce Gioia, chief operating officer of Employer of Choice International, Inc. and author of the book How to Become an Employer of Choice. Our panel of judges found that Lee Memorial Health System excelled in several categories, including recruitment practices, continuing opportunities for advancement and employee benefits.
With more than 10,500 employees, Lee Memorial Health System is the largest employer in Lee County. Creating an environment of employee engagement and job satisfaction is part of our cultural DNA, says Jim Nathan, president of Lee Memorial Health System. By focusing on teamwork, collaboration and opportunities for advancement, we can attract, develop and retain diverse, talented, caring professionals, and that leads to excellent care for our patients.
Employee loyalty and satisfaction is one measure of success, but it also is vital to patient safety and satisfaction. Lee Memorial Health System s elected Board of Directors established patient safety as the organization s No.1 core value. Every member of the team is important and deserves recognition, says Diane Champion, board director representing District 4 and the board liaison for human resources.
One of the most enjoyable events held each year is a special celebration to honor the successes and milestones of our team members. In 2013, 938 employees were honored who reached benchmark years, including 280 individuals who were recognized for 20, 25, 30, 35, 40 and even 45 years of service, says Jon Cecil.
Jon Cecil, chief human resource officer for Lee Memorial Health System says the Board should be proud of this accomplishment. Our Board of Directors plays a significant role in fostering the right culture of employee satisfaction by setting policies that increase employee engagement and build trust, he says. Their support is very much appreciated and they, too, are to be congratulated by the honor of this award.
This is the third time Lee Memorial Health System has earned the Employer of Choice designation, which previous recognitions in 2005 and 2006


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Malone University takes honors program on the road!
December 13, 2013 | Release # 6798
The Honors Program.
Cambridge High School students got a taste of what lies ahead when Diane Chamber, Ph.D., professor of English and director of the Honors Program at Malone University accompanied "Malone on the Road" initiator Bill Quigley, D.Min. Drs. Chambers and Quigley spoke to six English classes in all – three of them Honors English classes.
They informed the classes about special initiatives the University employs to engage students in learning. Dr. Chambers shared R.S.V.P. catalogs (a project that allows visual arts and writing students to create new work inspired by each other) and additional unique opportunities at the liberal arts university including study abroad, service learning trips, world view forums, and 24-hour theater – where students write, produce and stage complete plays within a 24-hour period!
The pair addressed choices the students have already made, discussed major interests, and encouraged undecided majors not to be discouraged—many university freshmen begin college undecided as to their major.
The idea was presented by Malone University alumna, Sandra Morrison, who earned the master of arts degree in education and now teaches Language Arts classes at Cambridge High School. Morrison believes her students may benefit from meeting and interacting with college professors in addition to the traditional visits from admissions counselors, before making decisions about life after high school.
Dr. Chambers has been teaching English at Malone University since 1996, and serving as Honors Program director since 2001. Prior to that post, she was a graduate assistant and lecturer at The Ohio State University, and has also taught at the University of Minnesota, Duluth and in the public schools in Circle Pines, Minnesota. She has twice been named a Distinguished Faculty Award recipient at Malone – in 2005 for teaching and again in 2012 for service.
For more information about The Honors Program at Malone University, please click here.
Malone University, a Christian university for the arts, sciences, and professions in the liberal arts tradition, affiliated with the Evangelical Friends Church, awards both undergraduate and graduate degrees in more than 100 academic programs. Malone has been recognized by the prestigious Templeton Foundation as a leader in character development, as one of Northeast Ohio's Top Workplaces by the Cleveland Plain Dealer, and is ranked among the top colleges and universities in the Midwest under the category Regional Universities according to U.S.News & World Report's America's Best Colleges 2014,has been awarded the designation Military Friendly School by Victory Media, and is named to AffordableCollegesOnline (ACO)'s Best Lifetime Return on Investment list for the State of Ohio.
Suzanne Thomas, APR
Director of University Relations
Malone University
2600 Cleveland Avenue N.W., Canton, OH, 44709
fgubznf+znybar+rqh Phone: 330-471-8239
Cell: 330-324-2424
Categories: academics


text: The new health care law will likely mean that home-health agencies will take a bit of a financial hit. The decrease is small (about 2.5%) but may result in half of all Medicare home-health agencies operating in the red. As reported by Bloomberg: Medicare payments to home health agencies such as Amedisys Inc. (AMED) Continue Reading


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With a combination of warm ocean breezes, scenic seaside golf courses and endless opportunities for adventure, the Carolina coast holds the cure for any lingering winter blahs. So, pack your bags and point the compass southeast. From North Carolina's Outer Banks to South Carolina's Hilton Head Island, you'll find a reason to escape the mundane and reinvigorate your spirit. Whether it's swimming and shelling or sightseeing and shopping, you'll find the perfect escape along the Carolina shore.
Many happy returns
For several years, Delaware County resident Michelle Gatchell has traveled to the Carolina coast to recharge her batteries. For her, South Carolina's Edisto Island is the ideal destination to experience peace and solitude.
"It's a very cozy island; not a lot of commercialization," Gatchell says. "It's where people from the Carolinas go to get away."
Gatchell says Edisto offers plenty of affordable beach-house rentals with views of the Atlantic, where you will often spot bottlenose dolphins breaking the water's surface. In addition, strolls along the shore can be quite profitable for beachcombers who enjoy collecting shells and fossils, including the occasional shark's tooth. At the north end of the island, you'll find Edisto Beach State Park - an unspoiled 1.5-mile strand lined with some of the tallest palmettos in South Carolina.
To satisfy the appetite you'll work up slogging through the sand, Edisto offers a handful of pizza shops and seaside restaurants with relaxed and unpretentious ambiance.
While Edisto has that remote feel, it's less than an hour away from one of the most vibrant, historic and beautiful cities in the country - Charleston. In Charleston, you can shop for everything from antiques to fresh produce as you make your way through the Old City Market, where descendants of West African slaves work magic with their hands to weave durable and decorative baskets out of sweetgrass. Once you've loaded up your basket with goodies, hop aboard a horse-drawn carriage at the Old City Market to embark on a tour over the cobblestone streets of Charleston, where more than 70 buildings constructed prior to the Revolutionary War still stand.
Speaking of the Revolutionary War, Charleston's Fort Moultrie is the site of the first Patriot victory over the British - a nine-hour battle that played out on June 28, 1776. Fort Moultrie is now part of the Fort Sumter National Monument, where the Civil War began on April 12, 1861. No matter how you look at, this is one of the most historically significant sites in the United States. It's a must-see for any American who appreciates his or her freedoms.
At Charleston's Magnolia Plantation, you'll find the oldest garden in the country - the Barbados Tropical Garden, which was first planted in the 1680s. You can get lost in Magnolia's horticultural maze, which features a quarter-mile of intricate pathways that wind through more than 500 camelia sasanquas. The late Charles Kuralt, who hosted "CBS Sunday Morning" for many years, called Magnolia his "greatest Charleston pleasure."
Tee off
Just minutes from Charleston, you have your choice of three resort communities where great beaches are only outshined by fantastic fairways - Kiawah Island, Seabrook Island and Wild Dunes. Head a little farther south, and Hilton Head Island's more than 20 public courses await. Arnold Palmer, Jack Nicklaus, Robert Trent Jones, Pete Dye and many other iconic names in golf-course design have put their signatures on tracks in this region.
The Kiawah Island Golf Resort features five championship courses, with the Ocean Course leading the way. With panoramic ocean views on every hole, this aptly named course's beauty should pacify you even as your strokes add up. Consistently rated as one of the best and toughest tracks in the nation, the Ocean Course is already gearing up to host the 2012 PGA Championship.
If you want to take your swings at Seabrook's Crooked Oaks or Ocean Winds, plan to stay at the resort, because the two courses aren't open to the general public. Because that's the case, these courses are typically not crowded, allowing you to concentrate on your game and not the guys standing with their hands on their hips in the middle of the fairway.
Known for the humpbacked sand dunes that line its fairways along the Atlantic Ocean, the Links Course at Wild Dunes is another visual stunner. And, if you ever hoped to lose that slice, the course's 17th hole would be a good place to begin. With ocean and dunes on the left and a world of trouble to your right, a straight drive down the narrow fairway is your only option.
Of course, South Carolina doesn't have the market cornered on spectacular golf destinations; its neighbor to the north boasts its share of tantalizing tracks. One of North Carolina's newest gems is the Fred Couples-designed Carolina National Golf Club, located between Myrtle Beach and Wilmington, N.C. This course's 27-hole layout offers five sets of tee placements on each hole, allowing you to match the distance to your ability. Don't feel bad if your ability changes during your round and you opt for a closer tee; this course can be a bit challenging. If you plan to bring the clubs along on your Carolina vacation, you'll have plenty of options. Throughout the two states, there are nearly 1,000 golf courses waiting for your best shots.
Aquarium adventures
Any trip to a coastal region is certain to arouse a natural curiosity about life below the water's surface. Up and down the Carolina coastline, you'll find several aquariums certain to satisfy your desire to learn more, not to mention the fact that your kids will think they're pretty cool. The North Carolina Aquarium system is comprised of three facilities - Roanoke Island in Manteo, Fort Fisher at Kure Beach and Pine Knoll Shores.
Roanoke Island is located along the Outer Banks near Kitty Hawk, where Dayton's Wright Brothers made their famous first flight. Each day at 10:30 a.m., scuba divers jump into the Roanoke aquarium's 285,000-gallon "Graveyard of the Atlantic" tank for all to see. They even wear communication devices that allow them to hear and respond to your questions, such as, "What's that big striped fish swimming around your head?"
Located just south of Wilmington, Fort Fisher's newest attraction is "Exotic Aquatics" - a gallery of four exhibits that includes a 1,000-gallon cylindrical tank filled with venomous sea snakes and another tank loaded with squid-like fluorescent cuttlefish from the Red Sea. Fort Fisher also offers canoe and crabbing exhibitions in its adjacent salt marsh.
Pine Knoll Shores, located along North Carolina's central coastline, is set to reopen in May after undergoing a $25 million expansion. Its new exhibits will include a 306,000-gallon ocean tank, which will showcase the wreckage of a pirate ship and a German sub.
Ripley's Aquarium in Myrtle Beach will thrill you as a moving path guides you through its "Dangerous Reef Tunnel," where sharks and other sea creatures dart around you in the 750,000-gallon water-filled tank outside of the tunnel's glass encasement.
Head south to Charleston and you'll discover the South Carolina Aquarium, which claims to be the city's most-visited attraction. Located along the Charleston Harbor, the aquarium features more than 60 exhibits covering the various aquatic animals that call South Carolina home. With two stories and multiple viewing areas, the aquarium's 300,000-gallon "Great Ocean Exhibit" definitely makes a splash with visitors.
Leave a light on
The Carolina coastline is lined with beacons that shine on the region's rich maritime history. They also lend themselves to fantastic photo ops for you and your family.
It took approximately a million bricks for the Currituck Beach Lighthouse to rise 160 feet above the Atlantic along North Carolina's Outer Banks in 1875. Located in the town of Corolla and open daily for tours, this lighthouse's unpainted brick pattern sets it apart from others in the region.
After you're finished touring the lighthouse, make the short trip north to Knotts Island, where you can choose to take a peaceful hike through the Mackay Island Wildlife Refuge or sit back and tempt your palette at the Martin or Moonrise Bay vineyards.
Recognized by its unique barber-pole stripes, the Cape Hatteras Lighthouse in Buxton, North Carolina, is probably the most famous lighthouse in the country. Built around 1870 at height of 208 feet, it's believed to be the tallest brick lighthouse in the world. While you're there, you will learn all about how the Cape earned the nickname "Graveyard of the Atlantic." But don't let that deter you from riding the waves along the Cape Hatteras National Seashore. According to the National Park Service, you'll find the best surfing on the East Coast here.
Bald Head Island - one of the Brunswick Islands along North Carolina's southern coast - is home to "Old Baldy," the oldest standing lighthouse in the state. Commissioned by Thomas Jefferson and completed in 1817, Old Baldy still stands tall, remaining open to tours daily from dawn until dusk. If you wind your way up the 108 steps to the top, you will be rewarded with breathtaking views of the entire island.
Located near Beaufort, South Carolina, Hunting Island State Park is where you'll find another 19th-century lighthouse open each day for tours and scenic views down the coastline. Hunting Island also is a 5,000-acre nature preserve, which is marked by ancient sand dunes and a semi-tropical maritime forest. There's even a lagoon where seahorses and barracuda reside. And during the summer months, the island is a great place to spot the fascinating loggerhead turtles nesting on the beach.
Garden variety
While Charleston's Magnolia Plantation boasts the nation's oldest garden, Brookgreen Gardens near South Carolina's Pawleys Island certainly has to be one of the country's most spectacular. Best described as a 9,200-acre horticultural extravaganza, Brookgreen features several unique gardens spread out over a property accented by marshes and swamps.
Celebrating its 75th anniversary this spring, Brookgreen's Huntington Sculpture Garden is the oldest public sculpture garden in the country. More than 900 American works, dating from the early 1800s to the present, are beautifully coordinated with the flora throughout the 50-acre display.
While exploring the beauty that lies within Brookgreen's lush gardens can keep you busy for hours, the children may get a bit antsy. It's a good thing Brookgreen is home to a wonderful zoo filled with animals roaming in their natural habitats. Bald eagles, foxes, wild turkeys and alligators are just some of the creatures that call Brookgreen home.
Historic Wilmington, North Carolina, is home to Airlie Gardens, where more than 250,000 azaleas are just about ready to bloom. With 67 acres of southern gardens and 10 acres of freshwater lakes, Airlie bursts into a colorful display right about this time each year. If you visit in late spring or summer, you're likely to hear sweet music in the air from one of the periodic concerts scheduled on the grounds.
The Elizabethan Gardens in Manteo, North Carolina, serves as a living memorial to the original English colonists who came to America in the late 1500s. As you wander through the property, you'll find the Shakespearean Herb Garden in the courtyard filled with healing, culinary and aromatic herbs. When you're ready to take a break from your tour, grab a seat in the garden's thatched-roof gazebo and gaze out over the Roanoke Sound as any lingering winter memories melt away.
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The 76ers have re-signed forward Thaddeus Young to a five-year contract worth $43 million, multiple NBA sources confirmed on Friday.
The fifth year of the contract is Young's option.
The Sixers, who held their first practice of the season on Friday, had pegged re-signing Young as their "top priority" for the NBA's abbreviated free agency period, which officially commenced Friday.
Young did not participate in Friday's session, but is expected to rejoin the team for Saturday afternoon's practice.
The Sixers also re-signed veteran center Tony Battie to a one-year contract that's expected to be near the veteran's minimum.


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Do you know that skin is the biggest organ of your body? But, most people take care only of the skin on their face. It is undeniable that taking care of facia skin is extremely important as it is the first thing that people notice, but it is also not proper to ignore the rest of your body. Many people end up with wrinkles and dry skin on body and are embarrassed to expose. Body sculpting products help not only to tighten the skin of some most difficult areas like buttocks, thighs and tummy, but they also hydrate and brighten the skin. These products have the ability to penetrate deep into your skin and remove cellulite and deposited fat and in the process they also help rejuvenate the skin. CoolSculpting northern VA kills your fat cells.
Some of us believe that a skin moisturizer meant for the face is perfect to be applied on the entire body. This is absolutely wrong as the skin of the body is completely different and has a requirement for stronger and deeper moisturization. When you look for a body sculpting product range, you will come across products that need to be used step by step. These products are thoughtfully created to help you meet all requirements of the skin from moisturizing to brightening and tightening. However, you must understand your body and skin type and the problem areas you need to address. Selection of the product suited for you will help you get a shapely body and a healthier and brighter look.
Believe it or not, if you have been fighting with stretch marks caused due to pregnancy or adolescence, a proper body sculpting product can help you get rid of them. Not only can such products give your tummy, highs and buttocks proper typing but also liked and the stretch marks to almost making them invisible that regular use. Do not think that a body sculpting product range is something that you can do without. These products do wonders for your skin and supply to your skin nutrition and moisturization in right proportions.


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At all performances a special area is set aside in the orchestra stalls (Zone 3) for physically disabled persons in wheelchairs with one accompanying person. A limited number of wheelchairs can be accommodated.
Special discounts apply to tickets in this area:
Up to 80% on the price of tickets and subscriptions.
50% discount for the accompanying person.
To qualify for this discount, an official disabled person's card must be shown (such as that issued in Catalonia by the Catalan government's Department of Social Action and Citizenry).


text:
Chevron Suffers Canadian Setback in Amazon Pollution Case
The Ecuadorians holding a $9.5 billion environmental judgment against Chevron Corporation got some welcome news on Tuesday, when an Ontario court revived their attempt to collect the mega-award in Canada.
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My goal right now is to get rid of visceral fat.
I've looked around a couple other forums of this type too recently...I kind of think there's a higher level of discourse on MDA than some of the others, for whatever reason. Perhaps the personality that Mark S projects encourages it.
I'm glad to be back also.
Last edited by Sam Cree; 08-13-2012 at 07:01 AM.
My goal right now is to get rid of visceral fat.
Welcome back to you too Sam Cree.
Steffturner, I never actually went vegan. I researched it out of interest. I like the idea of a fruit diet.. but humans eat meat. And so do chimps.. but try telling vegans that. I was a member, of a forum, but got so frustrated and eventually I got told off for suggesting an infant be fed goat milk when no breastmilk was available, so I deleted myself. I was sooo mad! Everyone else was suggesting coconut water and banana puree... OMG vegans have been jailed for not feeding their baby properly and the baby died.. again, try telling them that!
So, No, never vegan. BUT.. 2 interesting similarities.. Both primal and vegan discourage dairy and wheat..both not good foods for adult humans.
I've never worried about the ethics of eating animals.. but I am more sensitive to it now and would now prefer fish, home grown/killed and kangaroo. ( kangaroo's live wild, no chemicals in their diets, and one day they just get a bullet to the brain and thats it. they're gone. No transport nightmares or feed lots.)
I'm lucky my husband is very supportive of primal and is looking forward to homecooked lambshanks tonight!
Nothing wrong with thinking for oneself, its the reason we are here is because we thought about SAD and rejected it!
Been here about three years. Can't see straying from the primal path. I only seem to be getting deeper into it. I visit the forum every day but don't post as frequently as many. I do find the forum has less value over time than it did when I was sponging up lots of new info.
3 1/2 years and going strong!
Two years in September.
Still here, but I usually stay in the journals, it can get "weird" in the general forums
"Be careful what you pretend to be because you are what you pretend to be." Kurt Vonnegut
"I love deadlines. I like the whooshing sound they make as they fly by." Douglas Adams
"Moderation sucks." Suse
"Wine is a vegetable." Meaty
"Every decision you make, from what you eat to what you do with your time tonight, turns you into who you are tomorrow and the day after that." Cmdr Chris Hadfield


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I purchased this for my cat sitter so she can use it for her other clients.
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Arte Pizzeria
1  Reviews
Loveland, CO 80537
Arte Pizzeria is locally owned and operated by a native of Naples, Italy. In our authentic Italian recipes we use fresh ingredients and integrate eco-friendly options when possible to help preserve the environment. Each pizza is a unique work of art, crafted individually to order. Experience the artistry in a relaxed environment, enjoy take out or choose the convenience of delivery to your home or office.
Phone Numbers
- main:
(970) 669-9000
- Delivery, Take out, Eat in, Catering
- Pizza, Calzones, Salads, Pastas, Deserts
Languages Spoken
- English
Payment Methods
- Cash , Visa , Mastercard , Debit Card
- Neopolitan Pizz
0.4 Miles
1467 W Eisenhower Blvd, Loveland, CO 80537
"always go here for fast, fresh pizza fast. they'll make your slice to order and deliver to y...">


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Cowboys fired DC Rob Ryan.
Coach Mike Zimmer said Monday that first-round pick Laquon Treadwell isn't playing because "he's still thinking too much."
Bengals coach Marvin Lewis believes Tyler Eifert (ankle) is "close" to returning.
Michael Floyd is in the league's concussion protocol.
Speaking Monday, 49ers coach Chip Kelly hinted Colin Kaepernick could become the team's starter once he's back to full health.
NFL.com's Ian Rapoport reports there is "optimism" Rashad Jennings (thumb) returns for Week 4.
NFL.com's Ian Rapoport reports Jeremy Langford has been diagnosed with a sprained ankle.
Speaking Monday, Chiefs coach Andy Reid said "there's a chance" Jamaal Charles (knee) returns for Week 4.
The Union-Tribune San Diego reports Antonio Gates (hamstring) "wasn't close" to suiting up against the Colts, and will likely miss another game.
Shane Vereen will miss the rest of the season with a triceps injury.
Seahawks coach Pete Carroll said Thomas Rawls (fibula) will miss multiple weeks.
ESPN Packers reporter Rob Demovsky reports Jared Cook's ankle injury is not season-ending.


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No worries,
I prefer swt potato to the pumpkin brownie, u can leave skin same method. Yes u can play 2 whatever u like, I like adding coffee, pecans some cacao nibs & sprinkle of salt on top is nice too
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No worries,
I prefer swt potato to the pumpkin brownie, u can leave skin same method. Yes u can play 2 whatever u like, I like adding coffee, pecans some cacao nibs & sprinkle of salt on top is nice too
I made the brownie again and it was even better this time, so that even my dd said it actually was like brownie.
This recipe's a keeper.
I dunno if anyone suggested it yet, but curried pumpkin (with lamb, onions, celery) worked great for us. I also do pumpkeroni and cheese for my kiddo (basically just like macaroni and cheese, I use cream-cheese to cook the pumkin in, then spread cheese on top and broil it to crispy-golden).
I just had a pumpkin porridge for breakfast (from canned since it's summer here). Got the recipe from chowstalker.
Basically toast nuts in coconut oil, add a half cup pumpkin mash (1 person), spices of your choosing, and 1/4 cup heavy cream. Then beat in two eggs (stir frequently on medium heat) . Top with pumpkin seeds.
Was delicious. :)
Glad u like it lol
Fancy trying it again now !
I honestly eat pumpkin out of the can with cinnamon and stevia. However, I do love mixing it with eggs - I like to mix CHUNKS not puree - SO delicious :)
I like to oven roast peeled cubes of pumpkin tossed in coconut oil, chili powder, salt, and honey. But I have found mileage varies from pumpkin to pumpkin. Some pumpkins are sweet and delicious, and some are incredibly bland. So frustrating.
Turkey Pumpkin Burgers - It's like Thanksgiving at ANY TIME!!! :) I adore pumpkin (or butternut squash) with turkey, seriously an amazing combination! Dice a little shallot and spinach and mix those in the burgers too! So good!
cook, dehydrate and blend to powder. make this: [url=http://www.thepaleomom.com/2012/06/recipe-perfect-pumpkin-pancakes.html]» Perfect Pumpkin Pancakes[/url]
or this [url=http://www.theclothesmakethegirl.com/2011/11/17/velvety-butternut-squash/]Velvety Butternut Squash | theclothesmakethegirl[/url]
and without salt and garlic and change the spices to cinnamon cloves and allspice, its dessert!
works with normal pumpkin too not just butternut. I've done it with kent/jap before.


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Vendor News
Our Vendor News offers news and announcements about vendors in the Chemical Processing industry.
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Our Ecomonic Snapshot offers news about the world economic atomsphere and how it may affect your bottom line.
Industry News
Hydraulic Institute Announces Update of ANSI/HI Standard09/01/2010
1st Pumps Hands-on Maintenance and Reliability Conference07/27/2010
Hydraulic Institute Announces Fall Conference09/28/2009
Pumping Optimization Course Will Be Available At The New Chem Show09/08/2009
Valve Manufacturers Association To Offer Free Seminars08/17/2009
Hydraulic Institute Names New Standards Partners05/15/2009
Keynote Speaker Announced For Water & Wastewater and Automatic Controls Symposium05/05/2009
Free 'Pump and Systems' Conference In UK04/22/2009
Hydraulic Institute Seeks Reviewers For Updated Standards03/17/2009
New Web Site Devoted to Pump Education02/10/2009
Chemetall Oakite Becomes Chemetall
Chemetall Oakite, the industry leader in specialty chemical products, has changed its name to Chemetall.07/01/2008
Membership for ESR Technologys Pump Center hits record
UKs leading organisation of pump users, manufacturers and suppliers celebrates a 10-percent increase in members during the past 12 months.10/19/2007
Ionic liquids boost cellulose as feedstock
Ionic liquids, now being pioneered by BASF, Ludwigshafen, Germany, for acid scavenging in reactors, also promise to play an important role in expanding the use of cellulose as a chemicals feedstock.06/19/2006
Pump repair and restoration guidelines12/18/2005
Koch Membrane Systems launches new corporate web site07/20/2005
Horizon Systems acquires Industrial Components Corporation07/20/2005
K-Tron to present several technical seminars in 200507/20/2005
General Electric sees huge growth in clean energy business07/20/2005
Pump and Pump Systems seminar07/18/2005
Daratech's upcoming conference schedule released06/09/2005


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Manduca dilucida
Manduca dilucida is a moth of the Sphingidae family. It is found from Mexico to Belize, Nicaragua and Costa Rica and possibly across northern South America to Venezuela.[2]
The wingspan is 95-98 mm.
Adults have been recorded in February and from April to October in Costa Rica. There are probably three generations per year.
The larvae feed on Annona reticulata, Annona holosericea, Sapranthus palanga, Amphilophilum paniculatum, Crescentia alata, Tabebuia ochracea, Cordia alliodora and Cornutia grandifolia. There are several colour morphs and five instars. The first instar is pale green with a black horn.
|This Manduca-related article is a stub. You can help Wikipedia by expanding it.


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When Stile Bertone introduced its latest outrageous concept, the Mantide, the company said only one would be produced. Yet the concept generated so much interest at its Shanghai auto show unveiling thatdesigner Jason Castriota said the company may consider a very limited production run.
How limited? Jason said the company might build three or five examples, but he wouldn't rule out producing as many as 10. A production run of only 10 of these Italian supercars may seem small, but it makes more sense when you consider the Mantide's price tag is reportedly just under $2 million.
The car's price is quite a premium over the $105,000 Corvette ZR-1 lurking beneath the swoopy bodywork. However, the Mantide bears little resemblance to the Vette, thanks to a number of new carbon fiber parts, including seats, interior trim, body panels and wheels. The weight savings in combination with the car's improved aerodynamics make the Mantide even faster than the ZR-1.
Due to the car's extremely limited availability and astronomical price tag, most will be lucky to see the car in person. Fortunately, Bertone has announced it will show the Mantide in the U.S. To see it, make plans to attend the 2009 Pebble Beach Concours d'Elegance in August, visit the National Corvette Museum in Kentucky in September, or go toa yet-to-be-announced collector show in New York City later in the fall.
Source: The New York Times


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Manchester United are dealing with a bit of injury woes at the moment, and, especially with an important stretch of games on the horizon, they will need players to step up to their responsibility.
The soccer gods are often cruel to teams and, usually, strike at the most inopportune times. It should be expected to encounter injuries during a long season, especially in a league like the Premier League that can be very physical and demanding.
The Red Devils are no exception. Now, with an all-important derby clash with Manchester City coming up, they are tasked with patching up a few holes left in the squad due to injury.
Let's not beat around the bush, though. With three points separating them for the top spot, this derby has a lot riding on it. In that same regard, it's hard to single out a few players and place all the responsibility on them. You win together and you lose together.
Still, United is expecting certain players who have to fill in for injured squad members to be able to handle it. These are the players I feel must step up in the absence of their teammates.


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Index of content:
Volume 76, Issue 8, 15 April 1982
Spectra and structure of small ring compounds. XLIII. Microwave spectrum of 2,3‐dihydrothiophene76(1982); http://dx.doi.org/10.1063/1.443525View Description Hide Description
The microwave spectrum of 2,3‐dihydrothiophene CHCHSCH2CH2 has been recorded from 18.0 to 39.0 GHz and only a‐type transitions were observed. The R‐branch assignments have been made for the ground and first excited states of the ring puckering mode. The ground staterotational constants are: A = 6863.14±0.07, B = 4707.75±0.01, and C = 2953.43±0.01 MHz. It is shown that the quantity I a +I b −I c = 9.87 U ⋅Å2 cannot arise totally from the four hydrogens on the two CH2 groups, but that the heavy atom skeleton contributes to it which indicates that the heavy atom skeleton is nonplanar. The rotational constants are shown to be consistent with reasonably assumed heavy atom structural parameters and a dihedral angle of puckering of 33°. The dipole moment components could not be accurately determined because of the near degeneracy of the ground and first excited state of the ring puckering mode but they were estimated to be ‖μ a ‖ = 1.5±0.2 D with ‖μ b ‖ and ‖μ c ‖ being relatively small. From relative intensity measurements, it is concluded that the second and third excited states are closely spaced with frequencies of 155±15 cm−1, whereas, the first excited state is nearly degenerate with the ground state. The origin of the difference band series associated with the ring puckering mode and the carbon–hydrogen stretch has been reassigned. Additionally,the first two ring puckering transitions 3←0, 2←1 have been observed in the far infrared spectrum of the gas at 167 and 152 cm−1, respectively. All of these results are consistent with a puckered ring governed by the following potential function: V(X) = 6.50×105 X 4−2.92×104 X 2, with a barrier to inversion of 328 cm−1. These results are compared to the corresponding quantities in similar molecules.
Vibronic absorption spectra of the biphenyl and biphenyl‐d 10 cations in solid argon76(1982); http://dx.doi.org/10.1063/1.443526View Description Hide Description
Matrix photoionization of biphenyl vapor during condensation at 20±2 K with excess argon produced band systems at 382.8 and 669.4 nm which are assigned to biphenyl cation owing to agreement with earlier radiolysis studies. The bands are blue shifted from photoelectron band differences which indicate structural changes between the molecule and the ionic states in the gas phase or between the gas and condensed phase ionic states. Vibrational fine structure in both absorption systems exhibits appropriate deuterium shifts and correlates with symmetric modes in the Raman spectra of C12H10 and C12D10. The sharper 382.8 nm band system reveals a 1771 cm−1 splitting of this ionic state, presumably a result of inter‐ring resonance interactions.
Infrared band intensities of formaldehyde and formaldehyde‐d 276(1982); http://dx.doi.org/10.1063/1.443527View Description Hide Description
The infrared band intensities of formaldehyde and formaldehyde‐d 2 have been measured in the gas phase using an FT–IR spectrometer. The effect of the polymerization of the sample molecule was minimized to measure the correct intensities. When the bands overlapped each other, their individual intensities have been determined by a band simulation calculation taking account of the Coriolis interactions. The signs of the dipole moment derivatives (∂p/∂Q i ) have completely been determined by the least‐squares method, and the results were compared with those obtained by the molecular orbital calculation (CNDO/2) and by the analyses of the Coriolis interactions. The local intensity parameters of the CH2 group of this molecule were calculated and compared with the corresponding ones of ethylene.
Conformational change of protein sodium dodecylsulfate complexes in solution: A study of dynamic light scattering76(1982); http://dx.doi.org/10.1063/1.443528View Description Hide Description
The binding of an ionic detergent [sodium dodecyl sulfate (SDS)] to two proteins [bovine serum albumin (BSA) and ovalbumin (OA)] has been studied by dynamic light scattering to determine the changes of the hydrodynamic size and shape of the proteins as a function of binding. This study has been correlated to a previous viscosity study (Ref. 1) in which the increase in the effective hydrodynamic radius of the detergent–protein complex as the gram ratio of detergent to protein increases has been interpreted as the unfolding of the protein as a direct result of the disruption of the intramolecular hydrophobic associations in the proteins by the SDS molecules. At the maximum binding, the BSA–SDS complex exhibits a hydrodynamic radius of 72 Å while the effective size of the native BSA is 27 Å. The OA–SDS complex has an effective hydrodynamic radius of 64 Å at the maximum binding while that of native OA is 22 Å. The dynamic light scattering experiments allow us to detect the presence of two different size species in the solution, the SDS micelles and the unfolded proteins combined with SDS. However, the shape of the protein–SDS complex at maximum binding cannot be definitely determined from the present measurements alone.
Light scattering and dynamics of interacting Brownian particles76(1982); http://dx.doi.org/10.1063/1.443529View Description Hide Description
The relative motions of interacting Brownian particles in liquids may be described as radial diffusion in an effective potential of the mean force. By using a harmonic approximation for the effective potential, the intermediate scattering function may also be evaluated. For polystyrene spheres of 250 Å mean radius in aqueous enviroment at 1.25×10−3 g cm−3 concentration, the results for the calculated mean square displacement are in qualitative agreement with experimental data from photoncorrelation spectroscopy. Because of the interactions, the functions deviate considerably from the exponential forms for the free particles.
Optical spectra, energy levels, and crystal‐field analysis of tripositive rare earth ions in Y2O3. I. Kramers ions in C 2 sites76(1982); http://dx.doi.org/10.1063/1.443530View Description Hide Description
Optical absorption and fluorescence spectra of the Kramers ions Ce3+, Sm3+, Dy3+, and Yb3+ in the C 2 sites of Y2O3 are reported. A crystal‐field analysis of these data and previously reported data for Nd3+ and Er3+ is performed that is based on a Hamiltonian of C 2 point‐group symmetry, including J‐mixing effects. A best‐fit analysis is performed for the ions Nd3+, Sm3+, Dy3+, and Er3+; resulting rms deviations between calculated and experimental levels range from 5.1 to 7.9 cm−1. Results of this analysis are used to obtain a smoothed set of crystal‐field parameters for the entire lanthanide series; these smoothed parameters are used to predict the energy levels of Ce3+, Yb3+, and Gd3+ in Y2O3. Predictions for Ce3+ and Yb3+ are compared with experimental data.
The three‐dimensional potential energy surface for the ring‐puckering, ring‐deformation, and SiH2 rocking vibrations of 1,3‐disilacyclobutane76(1982); http://dx.doi.org/10.1063/1.443531View Description Hide Description
The mid‐infrared and Raman combination and hot band spectra involving the ring‐puckering (ν22), ring‐deformation (ν6), and SiH2 in‐phase rocking (ν21) vibrations have been analyzed for 1,3‐disilacyclobutane in order to determine the ring‐puckering energy levels for the ground and excited state of the other two vibrations. The puckering levels are only slightly perturbed in the rocking excited state but substantially altered in the ring‐deformation excited state. The parameters of the three‐dimensional potential energy function V = a 1 x 4 1+b 1 x 2 1+b 2 x 2 2+ b 3 x 2 3+c 12 x 2 1 x 2 2+c 13 x 2 1 x 2 3, where the subscripts 1, 2, and 3 refer to ν22, ν6, and ν21, respectively, were adjusted in order to obtain the best fit between the observed and calculated frequencies. For the energy level calculations, the Hamiltonian was symmetry factored into eight separate symmetry blocks. The basis functions for the three‐dimensional calculation were determined by first solving the one‐dimensional problem in x 1 and multiplying the resulting eigenfunctions by harmonic oscillator functions in x 2 and x 3. An excellent correspondence between the calculated and observed frequencies was obtained. The potential surface, which has a barrier to ring inversion of 81 cm−1 and a minimum corresponding to a dihedral angle of puckering of 24.2° provides an accurate representation of the coupling between the puckering and the other two modes. The c 12 constant is negative, indicating that ν22 and ν6 are cooperative modes; c 13 is positive, showing that the simultaneous vibration of ν22 and ν21 results in a higher potential energy.
Self‐induced multipole contribution to the single‐electron crystal field76(1982); http://dx.doi.org/10.1063/1.443477View Description Hide Description
We consider the interaction of electrons in unfilled shells of an ion substituted as an impurity in an insulating host crystal with their self‐fields induced through polarizable ligands. All orders of the interaction (dipole, quadrupole, etc.) are considered, thereby extending previous treatments that included induced dipole interactions only. By means of a correct inclusion of a l l the electrons and the nucleus of the impurity ion and by a proper consideration of the lattice‐induced multipole problem (also described here), we show that previous treatments of the self‐induced dipole problem are incorrect. Our result, up to the quadrupole term, is applied to the classic example of rare earths in LaCl3 and is shown to give a significant contribution to the one‐electron crystal field.
Higher resolution photoionization study of acetylene near the threshold76(1982); http://dx.doi.org/10.1063/1.443505View Description Hide Description
High resolution (0.14 Å FWHM) photoionization efficiency data for near the threshold (1059–1090 Å) have been obtained using the molecular beam method. The positions of the autoionization features resolved on the vibrational step of were found to be consistent with those calculated from the two Rydberg equations where R and n are the Rydberg constant and the principal quantum number, respectively.
Analysis of nearly degenerate bands of spherical top molecules: Matrix elements of the vibrational‐rotational Hamiltonian76(1982); http://dx.doi.org/10.1063/1.443506View Description Hide Description
We formulate a general method for calculating energy eigenvalues and eigenfunctions in a simultaneous analysis of nearly degenerate vibrational‐rotational bands of spherical top molecules. The basis functions are products of rigid rotor and N‐dimensional harmonic oscillator eigenfunctions. General explicit expressions are derived for the matrix elements of vibrational operators in the basis of N‐dimensional harmonic oscillator eigenfunctions. Using these general expressions, the matrix elements of vibrational operators in the basis of five‐dimensional harmonic oscillator eigenfunctions applicable, for example, in the analysis of the nearly degenerate ν2 and ν4 fundamental vibrational‐rotational bands of tetrahedral XY4 molecules like CH4, are calculated explicitly.
Spectral analysis and kinetics of uranyl glasses76(1982); http://dx.doi.org/10.1063/1.443507View Description Hide Description
The absorption spectra of uranyl doped soda–lime and lithium phosphate glasses at 77 K consisted of broad bands. The fluorescence due to various continuous monochromatic excitations showed fine structure and revealed two electronic levels within the full fluorescence band. The energy levels in the visible region were located by spectroscopic measurements and were used to calculate the intramolecular decay rates. There was agreement between the theory and experiment. Besides intramolecular relaxations, intermolecular relaxations were observed and they involved uranyl–acceptor interactions via dipole–quadrupole coupling. Analysis on the spectral kinetics yielded the acceptor concentration, which enhanced with increasing uranyl concentration in soda–lime glass. Such a relationship between the acceptor and uranyl concentrations implied that some acceptors were the by‐products of thermal decomposition of uranyl ions during sample preparation.Fluorescence decay of uranyl dopedlithium phosphate glass consisted of multiple fluorescence decay rates. The thermal dependence of polyphosphate metamorphosis was studied qualitatively by fluorescence decays of uranyl doped samples.
The structure of chain molecules in the liquid state: Low‐frequency Raman spectra of n‐alkanes and perfluoro‐n‐alkanes76(1982); http://dx.doi.org/10.1063/1.443508View Description Hide Description
A model, in which the random elements of the kinetic energy matrix are replaced by statistically weighted averages, is used to explain the principal features of the low‐frequency Raman spectra of a series of liquidn‐alkanes and perfluoro‐n‐alkanes. The spectra of the longer chains of the n‐alkanes are dominated by an intense band that is associated with the longitudinal‐acoustic mode observed in the crystalline state. For the liquid, the frequency ν and the number of carbon atoms n are found to be related as ν = ν0+B/n 2. This relation, which can be derived from the weighted‐average model, implies that the vibration exhibits frequency dispersion and has the character of an optic mode. The dependence of the width of this band on the number of carbons can also be accounted for in terms of the model. The intercept frequency ν0 and the slope B are functions of the energy difference E g between g a u c h e and t r a n s CC bond states. For the perfluoro‐n‐alkanes, E g was estimated from the observed value of the slope. The value derived 1050 cal/mol is roughly twice that reported for the polymethylene chain and is near the value reported by Bates and Stockmayer [J. Chem. Phys. 45, 2321 (1966)] from dipole moment measurements.
Core state vibrational excitations and symmetry breaking in the CK and OK emission spectra of CO276(1982); http://dx.doi.org/10.1063/1.443509View Description Hide Description
The CK and OK emission spectra of gaseous CO2 have been recorded in high resolution. From a Franck–Condon fit to the vibrational structure of the spectra, it is shown that C1sionization leads to a bond length shortening of 2.0 pm, while O1sionization mainly results in a displacement of the carbon atom of 5 pm, thereby breaking the D ∞h symmetry of the molecule. The high resolution allowed the natural lifetime width of the O1svacancy state to be determined to 0.07 eV and by the use of an accurate calibration procedure the adiabatic x‐ray transition energies were determined. These energies were used to obtain accurate binding energies of the core electrons. The O1s binding energies in CO2 were determined to 297.651 and 541.07 eV, respectively.
ENDOR study of an irradiated crystal of L‐alanine: Environment of the stable CH3ĊHCO2 − radical76(1982); http://dx.doi.org/10.1063/1.443510View Description Hide Description
The environment of the stable radical in an x‐ray irradiated crystal of L‐alanine CH3CH(NH3 +)CO2 − was studied at 77 K with the use of ENDOR technique. The analysis indicated that as the C–N bond ruptured and the stable radical was formed, the α carbon atom Cα shifted by a distance of 1.5 Å. As a result, for several protons in the radical environment the distance between the proton and Cα of the radical was found to be much shorter than the corresponding distance in the undamaged crystal; for example, 2.3 Å compared with 3.9 Å in the case of a methyl proton. The transferred N–H hydrogen was found to participate in exchange with the C–H hydrogens of this CH3ĊHCO2 − radical.
ENDOR study of an irradiated crystal of L‐alanine: Structure and the environment of the unstable CH3ĊHCO2 − radical76(1982); http://dx.doi.org/10.1063/1.443511View Description Hide Description
The unstable CH3ĊHCO2 − radical and its environment in an x‐ray irradiated crystal of L‐alanine were investigated at 77 K with the use of ENDOR technique. It was found that upon radical formation, the atoms of the radical shifted substantially from their original positions in the undamaged crystal. Unusually strong positive ENDOR signals were detected from the methyl protons of the radical: some signals were found to be stronger than the ESR signal.
The analysis of the torsional structures of the CH3(D3) asymmetric stretching vibrations of gaseous toluene76(1982); http://dx.doi.org/10.1063/1.443512View Description Hide Description
The torsional structures of the asymmetric stretchings of the methyl group of toluene are analyzed on the basis of the C 2v symmetry. The torsional structures observed in the IR spectrum of gaseous toluene‐h 3 are explained by use of the twofold and sixfold potentials in the first excited state of the CH3 asymmetric stretchings. The fundamentals analyzed are 2996.3 cm−1 for the B 2 mode and 2981.8 cm−1 for the B 1 mode. The Raman bands observed here at 2989 and 3012 cm−1 are assigned to the fundamentals of the A 1 and A 2 modes, respectively. The torsional structures of the CD3 asymmetric stretchings are explained satisfactorily by use of the potential constants obtained in the CH3 system.
Direct spectroscopic evidence for a new, low‐lying electronic triplet state in SO2 at 4.2 K76(1982); http://dx.doi.org/10.1063/1.443513View Description Hide Description
The phosphorescence emission and excitation spectra of crystalline SO2 at 4.2 K exhibit an anomalous energy gap of 83 cm−1 between their respective origins. The phosphorescence excitation, whose sharp origin occurs at 26 387 cm−1, involves a transition between the 1 A 1ground state and the excited 3 B 1 state. However, our data indicate that the phosphorescence emission originates from a second triplet state, which lies 83 cm−1 lower in energy. A very weak absorption at 26 304 cm−1 is observed in the phosphorescence excitation spectrum, which exactly coincides with the observed phosphorescence emission origin. Site‐selection experiments eliminate the possibility that the observed emission is due to defect sites in the crystal, and confirm the existence of the previously unreported low‐lying triplet state. Phosphorescence lifetime data and the observed time‐resolved emission spectra are consistent with this finding.
Optical spectra and Zeeman effect for Pr3+ and Nd3+ in LuPO4 and YPO476(1982); http://dx.doi.org/10.1063/1.443514View Description Hide Description
Absorption spectra of Pr3+ and Nd3+ diluted in LuPO4 and YPO4 crystals have been measured from 4000 to 30 000 cm−1, at liquid He and N2 temperatures. Fluorescence was observed for Pr3+ and Nd3+ in YPO4, and Zeemanspectra were obtained in the visible region. The transitions were assigned and fit to a semiempirical Hamiltonian with adjustable parameters via a least squares procedure. Satisfactory fits and reasonable agreement between calculated and measured g values were obtained.
Vacuum ultraviolet spectroscopy of molecules using third‐harmonic generation in rare gases76(1982); http://dx.doi.org/10.1063/1.443515View Description Hide Description
A variety of spectroscopic studies in the vacuum ultraviolet (VUV) region (100–200 nm) has been performed using tunable, narrow bandwidth (∼0.05 Å) light produced by third‐harmonic generation in rare gases. These experiments include one‐photon absorption and photoionizationspectroscopy and photoionization threshold determinations. Two‐photon ionization studies of NO, using the VUV light to probe Rydberg states and the fundamental light to ionize are also presented. These studies demonstrate the simplicity and utility of a laser‐based, tunable high‐resolution source for VUVspectroscopy.
A light scattering study of orientation of liquid–crystalline rodlike textures of poly(γ‐benzyl‐L‐glutamate) in an electric field perpendicular to the direction of sample cell surface by means of saturation electric birefringence method. III76(1982); http://dx.doi.org/10.1063/1.443516View Description Hide Description
The orientation behavior of liquid crystalline solutions of poly(γ‐benzyl‐L‐glutamate) (PBLG) in chloroform was investigated with respect to characteristic electro‐optical properties of macromolecules using polarizing microscope and small angle light scattering techniques, when an electric field was applied parallel to an incident beam. The birefringence phase exhibited an irregular patchwork of predominantly blue, yellow, and pink regions under cross polars without applying the electric field and the corresponding H v light scattering was circular. When the field was applied, the brightness of the phase decreased with increasing voltage and the corresponding H v patterns became a typical X‐type characterizing the scattering from rodlike textures. The analysis was made for a model system. In this model system, rods orient randomly in the three‐dimensional space in the absence of the electric field, whereas when the electric field is applied, the rods orient predominantly parallel to the electric field. The orientation distribution function of the rods was assumed to be the steady‐state orientation distribution function of macromolecules under an electric field which was proposed to investigate electric properties of a dilute solution of rigid macromolecules by O'Konski e t a l. Thus, the light scattering patterns were calculated as a function of an electric field strength. The calculated results were found to be rather close to the observed ones with a proper choice of parameter associated with the magnitude of the disorder of the optical axes.


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text: Cory Doctorow / 3:00 pm Sat, Apr 26, 2014 RIAA to blame for impoverishment of artists it's using as human shield in anti-streaming lobbying The RIAA and its captive collecting society Soundexchange are illegally lobbying for higher royalties from Internet streaming (despite the fact that companies like Pandora already give virtually all the money they take in to the labels), claiming that they're standing up for older artists. But, as Mike Masnick comprehensively establishes, these older artists have been impoverished by the RIAA, who "left them to rot" through abusive contracts, crooked accounting, and out-and-out theft. Read the rest SHARE / TWEET / 61 COMMENTS Business / mafiaa / music / riaa / short


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Angel Scardy~Angel COTD 11/15/08
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Hi! My name is Angel Scardy~Angel COTD 11/15/08
I am a Siberian from Corydon, IN
Nicknames: I was mostly just called Scardy, but sometimes called Squirms or Scardy Squirms.
Age: 12 years old
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My favorite tricks and treats are: I am really good at climbing a banister. I left claw marks on it so mom always has something to remember me by. and I loved mackeral. I would get mackeral about once a week, and I loved it.
Where I hang out: I loved to be anywhere. I would most commonly be found on the steps. But I could also be found up the tree outside, climbing the banisters to look in the house, and in the neighbor's storage shed next door.
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What I love about my owners: She loved me like no other mother could. She was something special.
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When my cat Macy had kittens, Scardy was one of them. Sadly on July 27th, 2006, mom noticed me limping around. She picked me up, and placed me on the sunroom. She provided me with water, food, and litter. I wouldn't eat or drink, and I just cried helplessly, dragging myself around and knocking the litter, water, and food everywhere. I later died on the porch, and mom later buried me. Mom found out that I got run over by one of the mean old neighbors, Bob. Mom still thinks about me every day. My name is pronounced Scare-dee, but it is spelled Scardy.
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