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Volume 123, Issue 9, 01 September 2005
- Theoretical Methods and Algorithms
Quasiclassical determination of reaction probabilities as a function of the total angular momentum123(2005); http://dx.doi.org/10.1063/1.2009739View Description Hide Description
This article presents a quasiclassical trajectory(QCT) method to determine the reaction probability as a function of the total angular momentum for any given value of the initial rotational angular momentum. The proposed method is based on a discrete sampling of the total and orbital angular momenta for each trajectory and on the development of equations that have a clear counterpart in the quantum-mechanical (QM) case. The reliability of the method is illustrated by comparing QCT and time-dependent wave-packet QM results for the reaction. The small discrepancies between both sets of calculations, when they exist, indicate some genuine quantum effects. In addition, a procedure to extract the reaction probabilities as a function of when trajectories are calculated in the usual way using a continuous distribution of impact parameters is also described.
Towards accurate all-electron quantum Monte Carlo calculations of transition-metal systems: Spectroscopy of the copper atom123(2005); http://dx.doi.org/10.1063/1.2011393View Description Hide Description
In this work we present all-electron fixed-node diffusionMonte Carlo (FN-DMC) calculations of the low-lying electronic states of the copper atom and its cation. The states considered are those which are the most relevant for the organometallic chemistry of copper-containing systems, namely, the , , and electronic states of Cu and the ground state of . We systematically compare our FN-DMC results to CCSD(T) calculations using very large atomic-natural-orbital-type all-electron basis sets. The FN-DMC results presented in this work provide, to the best of our knowledge, the most accurate nonrelativistic all-electron correlation energies for the lowest-lying states of copper and its cation. To compare our results to experimental data we include the relativistic contributions for all states through numerical Dirac-Fock calculations, which for copper provide almost the entire relativistic effects. It is found that the fixed-node errors using Hartree-Fock nodes for the lowest transition energies of copper and the first ionization potential of the atom cancel out within statistical fluctuations. The overall accuracy achieved with quantum Monte Carlo for the nonrelativistic correlation energy (statistical fluctuations of about and near cancelation of fixed-node errors) is good enough to reproduce the experimental spectrum when relativistic effects are included. These results illustrate that, despite the presence of the large statistical fluctuations associated with core electrons, accurate all-electron FN-DMC calculations for transition metals are nowadays feasible using extensive but accessible computer resources.
Time autocorrelation function analysis of master equation and its application to atomic clusters123(2005); http://dx.doi.org/10.1063/1.2000243View Description Hide Description
We derive the energy fluctuation , and the time autocorrelation and its Fourier transformation—the fluctuation spectra—of the master-equation transition matrix. The contribution from each eigenmode of the transition matrix to these fluctuation quantities reveals the relevant importance of the individual mode in the relaxation processes. The time scales associated with these relaxation processes are determined by the corresponding eigenvalues. Unlike traditional time evolution analysis, the autocorrelation function and fluctuation spectraanalysis does not involve an arbitrary initial population. It is also more suitable for analyzing the underlying dynamic, kinetic behavior near the equilibrium and the behavior of the long-time-scale rare events. We utilize our technique to analyze the solid-liquid phase coexistence of the 13-atom Morse cluster and the fcc-to-icosahedral structure transition of the 38-atom Lennard-Jones cluster. For the processes studied, the fluctuation spectra from the master equation simplify the analysis of the transition matrix, and the important relaxation modes are easily extracted.
Efficient transition path sampling for systems with multiple reaction pathways123(2005); http://dx.doi.org/10.1063/1.2013213View Description Hide Description
A new algorithm is developed for sampling transition paths and computing reaction rates. To illustrate the use of this method, we study a two-dimensional system that has two reaction pathways: one pathway is straight with a relatively high barrier and the other is roundabout with a lower barrier. The transition rate and the ratio between the numbers of the straight and roundabout transition paths are computed for a wide range of temperatures. Our study shows that the harmonic approximation for fluctuations about the steepest-descent paths is not valid even at relatively low temperatures and, furthermore, that factors related to entropy have to be determined by the global geometry of the potential-energysurface (rather than just the local curvatures alone) for complex reaction systems. It is reasonable to expect that this algorithm is also applicable to higher dimensional systems.
- Gas Phase Dynamics and Structure: Spectroscopy, Molecular Interactions, Scattering, and Photochemistry
Imaging photon-initiated reactions: A study of the reaction123(2005); http://dx.doi.org/10.1063/1.2009737View Description Hide Description
The hydrogen or deuterium atom abstraction reactions between and methane, or its deuterated analogues and , have been studied at mean collision energies around 0.34 eV. The experiments were performed in a coexpansion of molecular chlorine and methane in helium, with the atomic Cl reactants generated by polarized laser photodissociation of at 308 nm. The Cl-atom reactants and the methyl radical products were detected using resonantly enhanced multiphoton ionization, coupled with velocity-map ion imaging. Analysis of the ion images reveals that in single-beam experiments of this type, careful consideration must be given to the spread of reagent velocities and collision energies. Using the reactions of Cl with , , and , as examples, it is shown that the data can be fitted well if the reagent motion is correctly described, and the angular scattering distributions can be obtained with confidence. New evidence is also provided that the radicals from the reaction possess significant rotational alignment under the conditions of the present study. The results are compared with previous experimental and theoretical works, where these are available.
Intensity and wavelength control of a single molecule reaction: Simulation of photodissociation of cold-trapped123(2005); http://dx.doi.org/10.1063/1.2011398View Description Hide Description
Photodissociation of cold magnesium hydride ions leading to either or is simulated from first principles. The purpose is to study the possibility of single molecule control of the products in the presence of two laser fields. The system evolves on four electronic potential-energy curves, , , , and . These potential-energy curves are calculated from first principles using multireference self-consistent field theory. The accuracy of the electronic potential curves has been checked by calculating the energies of the rovibrational eigenstates and comparing them to experimental findings. The photodissociation dynamics has furthermore been simulated by solving the time-dependent Schrödinger equation. It is shown that the branching ratio of the two dissociation channels, or , can be controlled by changing the intensity and wavelength of the two driving laser fields.
Frequency-dependent hyperpolarizabilities of the Ne, Ar, and Kr atoms using the approximate coupled cluster triples model CC3123(2005); http://dx.doi.org/10.1063/1.2008211View Description Hide Description
The frequency-dependent electric field-induced second harmonic generation (ESHG) second hyperpolarizabilities of neon, argon, and krypton are calculated using the approximate coupled cluster triples model CC3. Systematic basis set investigations are carried out to establish basis set limits, and scalar relativistic effects are accounted for by direct perturbation theory. To estimate higher-order correlation effects, full configuration-interaction results are used to benchmark the accuracy of CC3. The best theoretical estimates obtained thereby for the static second hyperpolarizabilities are 107.4, 1159, and 2589 a.u. for neon, argon, and krypton, respectively. These values as well as the results for the dispersion curve of the parallel component agree well with the latest experimental values from electric field-induced second harmonic generation. In addition, the dispersion of the perpendicular component and the hyperpolarizability ratios has been studied for the first time on a consistently correlated ab initio level. The analysis of the results indicates that, in particular for neon and krypton, the presently available experimental values are flawed.
Reaction dynamics study of with crossed beams and density-functional theory calculations123(2005); http://dx.doi.org/10.1063/1.2000947View Description Hide Description
The reactions between and have been studied using the crossed-beam technique and density-functional theory(DFT) calculations in the collision energy range from 0.35 to 1.5 eV . Both proton transfer and C–O bond formation are observed. The proton transfer channel forming is the dominant pathway. The center-of-mass flux distributions of the product ions are highly asymmetric, with maxima close to the velocity and direction of the precursor acetylene beam, characteristic of direct reactions. The reaction quantitatively transforms the entire reaction exothermicity into internal excitation of the products, consistent with mixed energy release in which the proton is transferred in a configuration in which both the breaking and the formingbonds are extended. The C–O bond formation channel producing displays a distinctive kinematic picture in which the product distribution switches from predominantly forward scattering with a weak backward peak to sideways scattering as the collision energy increases. At low collision energies, the reaction occurs through an intermediate that lives a significant fraction of a rotational period. The asymmetry in the distribution leads to a lifetime estimate of 600 fs, in reasonable agreement with DFT calculations showing that hydrogen-atom migration is rate limiting. At higher collision energies, the sideways-scattered products arise from repulsive energy release from a bent transition state.
: Saturn-like fullerene derivatives (, Cl, Br)123(2005); http://dx.doi.org/10.1063/1.2012331View Description Hide Description
Based on the recently reported , the geometries and stabilities of its Saturn-like derivatives (, Cl, Br) have been investigated by DFT method. Compared with , the equatorial carbon atoms in have been saturated by halogens and change to hybridization to release the large angle strain. Because the equatorial carbon atoms have been taken out of the system by the halogens "ring," the system has been split into two well-delocalized conjugated annulene subunits, and then the electronic stabilization has been enhanced.
High resolution electronic spectra of 7-azaindole and its Ar atom van der Waals complex123(2005); http://dx.doi.org/10.1063/1.1990119View Description Hide Description
Rotationally resolved fluorescence excitation spectra of the origin band of 7-azaindole and its argon atom van der Waals complex have been recorded and assigned. The derived rotational constants give information about the geometries of the two molecules in both electronic states. The equilibrium position of the argon atom in the azaindole complex is considerably different from its position in the corresponding indole complex. Furthermore, the argon atom moves when the UV photon is absorbed. There are significant differences in the intermolecular potential energy surfaces in the two electronic states. A large, vibration-state-dependent rotation of the electronic transition moment vector of 7-azaindole relative to that of indole suggests that these differences have their origin in electronic state mixing in the isolated molecule, a mixing that is enhanced by nitrogen substitution in the six-membered ring.
On the theory of the reaction, including H and C kinetic isotope effects123(2005); http://dx.doi.org/10.1063/1.2031208View Description Hide Description
The effect of pressure, temperature, isotopes, and C isotopes on the kinetics of the reaction are investigated using Rice-Ramsperger-Kassel-Marcus theory.Pressureeffects are treated with a step-ladder plus steady-state model and tunnelingeffects are included. New features include a treatment of the C isotope effect and a proposed nonstatistical effect in the reaction. The latter was prompted by existing kinetic results and molecular-beam data of Simons and co-workers [J. Phys. Chem. A102, 9559 (1998);J. Chem. Phys.112, 4557 (2000);113, 3173 (2000)] on incomplete intramolecular energy transfer to the highest vibrational frequency mode in . In treating the many kinetic properties two small customary vertical adjustments of the barriers of the two transition states were made. The resulting calculations show reasonable agreement with the experimental data on (1) the pressure and temperature dependence of the effect, (2) the pressure-dependent isotope effect, (3) the strong non-Arrhenius behavior observed at low temperatures, (4) the high-temperature data, and (5) the pressure dependence of rate constants in various bath gases. The kinetic carbon isotopic effect is usually less than 10 per mil. A striking consequence of the nonstatistical assumption is the removal of a major discrepancy in a plot of the ratio versus pressure. A prediction is made for the temperature dependence of the reaction in the low-pressure limit at low temperatures.
A close-coupling study of vibrational-rotational quenching of CO by collision with hydrogen atoms123(2005); http://dx.doi.org/10.1063/1.2032948View Description Hide Description
Quantum-mechanical scattering calculations were performed for the rovibrational relaxation of CO in collisions with H atoms using the close-coupling approach for collision energies between and . We adopted the H–CO interaction potential of Werner, Keller, and Schinke and computed the state-to-state and total cross sections for the quenching of the , levels of CO. Numerous resonances, as a consequence of the van der Waals potential, are observed and the cross sections are found to approach the Wigner limit at low energies. Also, by averaging the cross sections over a Boltzmann distribution of velocities of the incoming atom, quenching rate coefficients are obtained and found to be consistent with previous infinite-order sudden approximation calculations for temperatures between 100 and .
- Condensed Phase Dynamics, Structure, and Thermodynamics: Spectroscopy, Reactions, and Relaxation
Low-frequency Raman spectra of sub- and supercritical : Qualitative analysis of the diffusion coefficient behavior123(2005); http://dx.doi.org/10.1063/1.1992476View Description Hide Description
We report the results of the low-frequency Raman experiments on which were carried out in a wide density range, along the liquid-gas coexistence curve in a temperature range of 293–303 K, and on the critical isochore of in a temperature range of 304–315 K. In our approach, the qualitative behavior of the diffusion coefficient is predicted, assuming the following: first, that the low-frequency Raman spectra can be interpreted in terms of the translation rotation motions; second, that the random force could be replaced by the total force to calculate the friction coefficient; and finally, that the Einstein frequency is associated with the position of the maximum of the low-frequency Raman spectrum. The results show that the diffusion coefficient increases along the coexistence curve, and its values are almost constant on the critical isochore. The predicted values reproduce qualitatively those obtained by other techniques. The values of were also calculated by molecular-dynamics simulation and they qualitatively reproduce the behavior of .
Heterodyned fifth-order two-dimensional IR spectroscopy: Third-quantum states and polarization selectivity123(2005); http://dx.doi.org/10.1063/1.1998829View Description Hide Description
A heterodyned fifth-order two-dimensional (2D) IR spectrum of a model coupled oscillator system, , is reported. The spectrum is generated by a pulse sequence that probes the eigenstate energies up to the second overtone and combination bands, providing a more rigorous potential-energy surface of the coupled carbonyl local modes than can be obtained with third-order spectroscopy. Furthermore, the pulse sequence is designed to generate and then rephase a two-quantum coherence so that the spectrum is line narrowed and the resolution improved for inhomogeneously broadened systems. Features arising from coherence transfer processes are identified, which are more pronounced than in third-order 2D IR spectroscopy because the transition dipoles of the second overtone and combination states are not rigorously orthogonal, relaxing the polarization constraints on the signal intensity for these features. The spectrum provides a stringent test of cascading signals caused by third-order emitted fields and no cascading is observed. In the Appendix, formulas for calculating the signal intensities for resonant fifth-order spectroscopies with arbitrarily polarized pulses and transition dipoles are reported. These relationships are useful for interpreting and designing polarization conditions to enhance specific spectral features.
Thermally activated escape rate for the Brownian motion of a fixed axis rotator in an asymmetrical double-well potential for all values of the dissipation123(2005); http://dx.doi.org/10.1063/1.2008250View Description Hide Description
The Kramers theory of the escape rate of a Brownian particle from a potential well as extended by Mel'nikov and Meshkov, [J. Chem. Phys.85, 1018 (1986)] is used to evaluate the relaxation times and the dynamic susceptibility for the rotational Brownian motion of fixed axis rotators in an asymmetric double-well potential. An expression for the escape rate valid for all values of the dissipation including the very low damping (VLD), very high damping (VHD), and crossover regimes is derived. It is shown that this expression provides a good asymptotic estimate of the inverse of the smallest nonvanishing eigenvalue of the underlying Fokker-Planck operator calculated by using the matrix-continued fraction method. For low barriers, where the Mel'nikov and Meshkov approach is not applicable, analytic equations for the correlation time of the longitudinal dipole correlation function in the VLD and VHD limits are derived and a simple extrapolating equation valid for all values of the damping is proposed.
Rotational motion in the molecular crystals meta- and ortho-carborane studied by deuteron nuclear magnetic resonance123(2005); http://dx.doi.org/10.1063/1.2013254View Description Hide Description
Spin-lattice and spin-spin-relaxation times, one- and two-dimensional spectra as well as two- and four-time correlation functions were measured for the molecular crystals ortho- and meta-carborane using deuteron nuclear magnetic resonance. It is found that in their noncubic phases these crystals exhibit highly anisotropic motions. In order to allow for a quantitative description of the motional geometry of the carboranes several stochastic models are formulated. By comparison of the model calculations with the experimental results it is found that the dynamics of these quasi-icosahedrally shaped molecules is governed by a composite reorientation process. Here the molecules perform threefold jumps around a molecule-fixed axis which itself can be tilted in four different directions with respect to a crystal-fixed axis. The tilt angle increases significantly with increasing temperature. On the basis of measurements of four-time stimulated-echo functions, implications for dynamic heterogeneity also in comparison with that of supercooled liquids are discussed.
Phase changes in Lennard-Jones mixed clusters with composition123(2005); http://dx.doi.org/10.1063/1.2008260View Description Hide Description
We have carried out parallel tempering Monte Carlo calculations on the binary six-atom mixed Lennard-Jones clusters, . We have looked at the classical configurational heat capacity as a probe of phase behavior. All three clusters show a feature in the heat capacity in the region of . The cluster exhibits a further peak in the heat capacity near . We have also investigated dynamical properties of the cluster as a function of temperature using molecular dynamics. We report the interbasin isomerization rate and the bond fluctuation parameter obtained from these calculations. At , the isomerization rate is on the order of ; at , the isomerization rate is greater than . Furthermore, at , the bond fluctuation parameter is less than 3%; at , it is in the range of 10–15% (depending on the sampling time used). Using this information, together with Monte Carlo quenching data, we assign the feature in the heat capacity to a solid-liquidphase change and the peak to a solid-solidphase change. We believe this is the smallest Lennard-Jones cluster system yet shown to exhibit solid-solidphase change behavior.
Density functional theory based molecular-dynamics study of aqueous iodide solvation123(2005); http://dx.doi.org/10.1063/1.2013209View Description Hide Description
We study the solvation of iodide in water using density functional theory based molecular-dynamics simulations. Detailed analysis of the structural and dynamical properties of the first solvation shell is presented, showing a disruptive influence of the ion on the local waterstructure. Iodide-water hydrogen bonding is weak, compared to water-water hydrogen bonds. This effective repulsive ion-water interaction leads to the formation of a quite unstructured solvation shell. The dynamics of water molecules surrounding the iodide is relatively fast. The intramolecular structural and electronical properties of water molecules around the ion are not affected.
Molecular-dynamics simulations of alkaline-earth metal cations in water by atom-bond electronegativity equalization method fused into molecular mechanics123(2005); http://dx.doi.org/10.1063/1.2000245View Description Hide Description
Intermolecular potential for alkaline-earth metal (, , and ) cations in water has been derived using the atom-bond electronegativity equalization method fused into molecular mechanics (ABEEM/MM), and it is consistent with what was previously applied to the hydration study of the monovalent cations. Parameters for the effective interaction between a cation and a water molecule were determined, reproducing the ab initio results. The static, dynamic, and thermodynamic properties of , , and were studied using these potential parameters. requires a more complicated form of the potential function than and in order to obtain better fits. Strong influences of the twofold charged cations on the structures of the hydration shells and some other properties of aqueous ionic solutions are discussed and compared with the results of a previous study of monovalent cations in water. At the same time, comparative study of the hydration properties of each cation is also discussed. This work demonstrates that ABEEM/MM provides a useful tool in the exploration of the hydration of double-charged cations in water.
Temperature-induced dynamical conformational disorder in 4-vinyl benzoic acid molecular crystals: A molecular simulation study123(2005); http://dx.doi.org/10.1063/1.2011387View Description Hide Description
Extensive molecular simulations are carried out as a function of temperature to understand and quantify the conformational disorder in molecular crystals of 4-vinyl benzoic acid. The conformational disorder is found to be dynamic and associated with a flip-flop motion of vinyl groups. The population of minor conformer is less than 3% up to and is 13.2% at and these results are consistent with the experimental observations. At still higher temperatures, the population of minor conformer increases up to 25%. The evolution of structure at both molecular and unit-cell level of the molecular crystal as a function of temperature has been characterized by various quantities such as radial distribution functions, average cell parameters, volume, and interaction energies. The van't Hoff plot shows a nonlinear behavior at lower temperatures as it has been reported recently by Ogawa and co-workers in the case of stilbene, azobenzene [J. Am. Chem. Soc.126, 3539 (2004)], and -(4-methylbenzylidene)-4-methylaniline [Acta Crystallogr, Sect. B. Struct. Sci.B60, 589 (2004)] molecular crystals. A set of rigid body simulations were also carried out to quantify the effect of conformational disorder on structural quantities such as unit-cell volume and interaction energy. The anomalous shrinkage of vinyl bond length as a function of temperature has been explained by combining the results of simulations and a set of constrained optimizations using ab initio electronic structure calculations for various molecular structures differing in torsional angle.


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Serves 6
- 2 1/2 cups Pictsweet frozen Mixed Greens
- 1 pound frozen pizza dough, thawed
- 1 cup Pictsweet frozen Seasoning Blend
- 1 tablespoon olive oil
- 1/2 cup part-skim ricotta cheese
- 1/2 cup whole-grain bread crumbs
- 1/4 cup plus 1 tablespoon grated parmesan cheese
- 1/4 teaspoon dried basil leaves
- 1/4 teaspoon salt
- 1/4 teaspoon pepper
Place frozen greens in saucepan and cover with water. Place on stove top and bring to a boil. Boil 3 minutes. Reduce heat, cover and simmer for 20 minutes. Drain well, pressing out as much liquid as possible (should have about 1 cup). Divide dough into 6 equal pieces; with a rolling pin, roll out each to a 7" round. Set aside on wax paper. Preheat oven to 400 degrees; lightly oil a baking sheet. Sauté seasoning blend in oil until liquid evaporates. Remove from heat and stir in drained greens, ricotta, bread crumbs, 1/4 cup parmesan cheese, basil, salt and pepper. If necessary, reroll dough rounds to 7". Divide greens filling onto one side of each round (about 1/3 cup each). Brush the outer 1/2" of dough round with water. Fold uncovered sides of dough rounds over filling and pinch the edge together. Place on baking sheet; brush tops with water and sprinkle with remaining cheese. Bake in the upper third of oven until browned, about 20 minutes and serve.
Nutritional Info
- Serving Size: Serves 6
- Calories: 310
- Total Fat: 11g
- Cholesterol: 20mg
- Sodium: 660mg
- Total Carbohydrates: 43g
- Dietary Fiber: 2g
- Protein: 13g


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Lung Disease & Respiratory Health Center
Solitary Pulmonary Nodule
In this article
SPN Exams and Tests continued...
A tuberculin skin test is used to help determine whether the SPN has been caused by the bacteria Mycobacterium tuberculosis. The test involves injecting the tuberculin antigen (a substance that triggers the immune system to produce cells that attack and try to destroy the antigen) into the skin and observing the body's response. If the SPN has been caused by tuberculosis, the injection site swells and reddens.
Chest X-rays
- Because SPNs are first detected on chest X-rays, ascertaining whether the nodule is in the lung or outside it is important. A chest X-ray taken from a side position, fluoroscopy, or a CT scan may help confirm the location of the nodule.
- Although nodules of 5 mm diameter are occasionally found on chest X-rays, SPNs are often 8-10 mm in diameter.
- Patients who have an older chest X-ray should show it to their health care provider for comparison. This is important, because the growth rate of a nodule can be determined. The doubling time of most malignant SPNs is one to six months, and any nodule that grows more slowly or more rapidly is likely to be benign.
- Chest X-rays can provide information regarding size, shape, cavitation, growth rate, and calcification pattern. All of these features can help determine whether the lesion is benign or malignant. However, none of these features is entirely specific for lung cancer.
- Characteristics that may help establish the diagnosis with reasonable certainty include (1) a benign pattern of calcification, (2) a growth rate that is either too slow or too fast to be lung cancer, (3) a specific shape or appearance of the nodule consistent with that of a benign lesion, and (4) unequivocal evidence of another benign disease process.
CT scan
- The CT scan is an invaluable aid in identifying features of the nodule and determining the likelihood of cancer. In addition to the features seen on a chest X-ray, a CT scan of the chest allows better assessment of the nodule. The advantages of a CT scan over chest X-ray include the following:
- Better resolution: Nodules as small as 3-4 mm can be detected. Features of the SPN are better visualized on CT scan, thereby aiding the diagnosis.
- Better localization: A nodule's location can be more accurately determined.
- Areas that are difficult to assess on X-rays are visualized better on a CT scan.
- CT scanning provides more details of the internal structures and more readily shows calcifications.
- If the CT scan demonstrates fat within the nodule, the lesion is benign. This is specific for a benign lesion.
- CT scanning helps distinguish between a neoplastic abnormality and an infective abnormality.
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text: On Fri, 2006-11-24 at 16:17 +0800, John McCabe-Dansted wrote: > On 11/23/06, Marc Stiegler <marcs at skyhunter.com> wrote: > Likewise is possible as we have both suggested in this thread, to pass > capabilities around in such a way as you have as much information as > you do under ACL. However this is not true if you do this the > "obvious" way. If we pass rights around by giving other users simple > copies of the caps, all accesses will appear to come from the > sysadmin. > > The typical cap response, is that you *can* do things like attach a > revoking or logging proxy to the cap before passing it on. There are two properties you are looking for here, and they can be distinguished: One is creating a revocable copy of a capability, rather than a co-equal copy. The other is creating a distinct capability that is associated to a different principal at the receiving end of requests invoked on the capability (the service). Creating a revocable or logging proxy implements the first property, but not the second. In fact, it can be an important property of such systems that the service can not distinguish between different copies of the same capability (revocable or not). To do otherwise would be to leak information to the service that it arguably shouldn't have. You are calling for a system where all copies of capabilities are revealed to the service. I am not sure if you only want to transmit a principal ID of the sender or the whole path down a mapping tree. In either case, you are going to face a number of serious problems that are not easily addressed, ranging from resource allocation issues to security issues and finally performance problems in actual implementations. Capability systems usually solve this issue by foregoing the goal of collecting and maintaining global information about what's going on in the system. I agree with your finer point that at some level you want to re-establish such information at least at an intermediate level, for example user-to-user interaction. However, it may be sufficient to reestablish this at the application level, rather than at the capability system level (assuming the cap system is powerful enough to allow that, a non-trivial question IMO). > This > response does not convince the ACL crowd that caps are as good or > better than ACLs, nor do I believe that it should. We need to convince > them that that innocent users *will not* pass rights the obvious way. > We can not assume that non-technical staff will understand the > difference between sending their own caps and sending a cap wrapped in > a revoking or logging proxy. The system should make the "obvious" way > of sharing caps between users non-obvious. Indeed, IMHO the system > should prevent unwrapped caps from ever being sent between users by > always rewrapping the caps. > > Further, when promoting caps we should make it clear that we intend > for the system to ensure that transfers of caps between high-level > entities such as users are always logged and revocable. Even if a > buggy/malicious application conspires to automatically proxy rights > unlogged, then it should be possible to revoke the rights by > destroying the application, and also allow the user to monitor data > entering or leaving their account e.g. to set up an IDS. I think that this makes sense, and it is one reason why I consider revocable copies an essential feature in capability systems. Unfortunately, building a system that has unlimited (by the system) nesting of capability wrappers and no denial-of-service threat scenario is a big challenge (see the current L4 redesign efforts with user-managed kernel memory). > Even if we assume users actions are infallible there is still the case > where they leave their terminal logged in. If the user sessions are persistent, then logging in just means attaching a terminal to a running session. In this case it is easy to choose short time outs and require re-login after that. To the user, this would appear similar to current screensaver+screenlock features. > In the good ol' days we > didn't give users write access to startup scripts or macros, so if > someone found a logged in terminal they couldn't get any rights that > lasted beyond a logout. It would be nice if we could regain this > property, to do this we would have to require users to jump through > hoops to grant permanent rights, either by contacting a sysadmin or > reauthenticating like "sudo myself-admin". In a persistent system, no start-up scripts or macros are required. In any type of system, a proper event notification system can allow the user to implement their own start-up script mechanism for their applications. In general one would want to reduce the role of the system administrator and the system software in general in a modern operating system. The Unix model of root on the one side and the users on the other side has great disadvantages, both in terms of security and in terms of functionality. Thanks, Marcus


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Affiliate - Center for Workshop Education
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A local band, Alternate Ending, is to play at the Knights of Columbus lot at 8 p.m. Sept. 21 during the Tiffin Seneca Heritage Festival.
The group was organized about two years ago but did not start performing together until January. Since then, they have played in Clyde, Tiro and the Tiffin area.
The band includes Dustin Ritchie, vocals; Matt Hill, guitar; Andy Althaus, bass; Jayson Ritchie, drums; and Anthony Runion, sound technician. Their set list includes songs by
Article Photos
Alternate Ending includes (from left) Anthony Runion, Jayson Ritchie, Dustin Ritchie and Matt Hill.
Godsmack, Alice Cooper, Lynrd Skynyrd, Pearl Jam, The Black Crowes, Bad Company, AC/DC, Stone Temple Pilots, Jimi Hendrix and 3 Doors Down.
Dustin Ritchie, who works at Mercy Tiffin Hospital, explained how the band was formed.
"I had won some money in Vegas, and I told myself I was going to buy a guitar with it. I had talked to Matt about giving me some guitar lessons," he said.
Having done some karaoke and "singing into my steering wheel," he had a few songs he wanted to learn on guitar. Ritchie sang as Hill played during the first lesson. Hill must have liked what he heard.
"We were kind of leaving, and he said 'When do you want to start?' I said 'What do you mean?' He said, 'Let's get something going.' I was pretty excited about that because ... Jayson and Matt have always been in bands," Ritchie said. "Jayson's my brother and Matt's my cousin. I've always been around them and always wanted to play in a band with them. It was my opportunity at that time."
Hill and Ritchie began as a duo to see what songs worked best and then added Jayson about a month later. By day, Jayson works at Owens Corning in Tiffin. After trying to locate a bass player, Hill was able to recruit Althaus, a co-worker from Toledo Molding and Die, to the band.
The next project was deciding on a name. The foursome came up with suggestions and then narrowed them down to the one they wanted. Ritchie credited Hill with Alternate Ending.
The band appeared for its first show in January at the Viaduct in Tiffin.
Hill said he has been playing guitar 15 or 16 years.
"My dad was in bands when I was young and I always remember going to wedding receptions when they played. Music has just always been around," Hill said. "He did mostly country and classic rock."
Jayson said he played drums in high school, but his interest in music began earlier than that.
"I got started from my uncle, watching him play. He was in a lot of bands," Jayson said.
Although Althaus started out as a drummer, he now prefers to play guitar. The drum lessons provided a good musical foundation.
"My dad bought me my first drum set for Christmas when I was 10, and I played in the Columbian marching band," Althaus said.
Runion was the final addition to Alternate Ending.
"They played out at a show called 'Biller Bash.' It was the first year for it so it was the first time I had seen them play. They were having issues trying to do the sound board and put on a show at the same time. They got done with the show and I offered to help with the sound. I don't have a musical bone in my body. I love music, but I can't play," Runion said.
"He has a good ear," Dustin interjected.
By the first of the year, the musicians want to add original songs to their show. They have written a handful together, and Ritchie has a few more of his own compositions to contribute. They also hope to do some recording.
"We'll basically work to build a good fan base and then come out with the original stuff," Ritchie said.
The group has a website, www.alternateendingband.com, and a Facebook page.


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Domestic abuse and sexual assault are among the violent crimes we'd like to think don't happen in our communities, but we all know they do occur.
These also are among a nature of crimes in which the victims tend to keep quiet. However, talking is just what they - or others who have knowledge of incidents - should do.
Local health care providers and state lawmakers are addressing these crimes with an extended approach.
Youth Health Service Inc., based in Elkins, recently received federal funding to expand its trauma services and treatment. Known as the FOCUS project, the program allows Youth Health Service to partner with counselors at Davis & Elkins College, West Virginia Wesleyan College, Alderson-Broaddus College and Women's Aid in Crisis to help young people who have or are experiencing domestic violence, sexual assault or stalking.
On the state level, lawmakers are considering two versions of a bill that would require adults to report any suspected sexual abuse to police. While these measures were introduced in light of the Penn State University scandal, our West Virginia leaders are commended for considering the unfortunate scenario of "what if this had happened here."
According to counselors at Youth Health Service, "it is estimated that 1 in 3 young people will experience abuse in a dating or marital relationship and that 1 in 4 girls and 1 in 6 boys experience sexual assault or abuse by their 18th birthday." Sadly, neither the FOCUS project nor the pending state legislation will put an end to these horrific crimes.
What can be accomplished is enhancing programs to bring healing to the victims, and creating a legal obligation for adults to report even the suspicion that these terrible actions are taking place.


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someone who is left handed
I thought she was right handed but i was wrong she is a true south paw.
by nwi July 04, 2006
Trending Now
Can you define these popular missing words?
Top Definition
To be left-handed.
The next batter at the plate was swinging southpaw.
by Turnspike March 16, 2003
Name for a person that fights typically with their left hand as their main striking hand. Their left hand will be out further than their right. Their left hand is always their power hand too.
Josh is a southpaw, I have to watch out for that.
by Tommy March 13, 2005
A boxing stance that most left handed people stand.Their left hand is down and their right hand up gaurding their face.
Jermain Taylor has a nasty left hook when he comes out of his south paw stance.
by Eldge June 18, 2006
Antonym of orthodox, a stance whereby the left hand is further forward than the right, whether because the person is left handed or because they prefer thier main hitting hand forward.
He boxes southpaw, pah.
by Kung-Fu Jesus June 03, 2004
When your boner is curved downward while erect. This is way more rare than an uppercut or right or left hooks, but theyre out there, and they always take the opponent by surprise
Dude check this porn out, that son of a bitch is a Southpaw from hell!
by thefallingdream January 18, 2010
soufpaw right here!! (1)A pride of being capable of writting with your left hand.
(2) Slang for left-handed.
(2) Slang for left-handed.
(1) I'm a southpaw.
(2) Soufpaw shorty righh herr.
(2) Soufpaw shorty righh herr.
by polska zyje nam~ nikolka February 13, 2005


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Dear Polly: I love fish, but my family does not. That's OK, except they always complain about the smell after I cook my fish. Is there some way to get rid of the smell of cooking fish? - J.P.
Dear J.P.: Baking fish in the oven rather than frying it leaves much less odor in the kitchen. If there is still an objectionable odor - or if you must have your fish fried - you can try a little simmering potpourri to clear up the air.


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A Visual Dictionary of Architecture
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(18 customer reviews)
Product Description
The classic, bestselling reference on architecture now revised and expanded!
An essential one-volume reference of architectural topics using Francis D.K. Ching's signature presentation. It is the only dictionary that provides concise, accurate definitions illustrated with finely detailed, hand-rendered drawings. From Arch to Wood, every concept, technology, material and detail important to architects and designers are presented in Ching's unique style.
- Combining text and drawing, each term is given a minimum double-page spread on large format trim size, so that the term can be comprehensively explored, graphically showing relations between concepts and sub-terms
- A comprehensive index permits the reader to locate any important word in the text.
- This long-awaited revision brings the latest concepts and technology of 21st century architecture, design and construction to this classic reference work
It is sure to be by the side of and used by any serious architect or designer, students of architecture, interior designers, and those in construction.
Product Details
- Amazon Sales Rank: #81589 in Books
- Published on: 2011-09-06
- Released on: 2011-08-18
- Original language: English
- Number of items: 1
- Dimensions: 11.95" h x .61" w x 9.00" l, 1.90 pounds
- Binding: Paperback
- 336 pages
- Francis D.K. Ching
Editorial Reviews
Amazon.com Review
A Letter from Author Francis D.K. Ching
The idea for a visual dictionary of architecture evolved slowly over a number of years as I taught in the design studio, read books and articles, and confronted terms that were either new to me, were being used in sometimes contradictory ways, or simply tossed out with the assumption that everyone knew what they meant. And so I often asked myself what did these terms really mean?
Of course, there were already general dictionaries that supplied these meanings if one bothered to look them up, and for more discipline-specific terms, there were architectural, historical, and construction dictionaries available. But few had more than a smattering of illustrations. And since architecture is such a visual art, I believed there was a need for a truly visual dictionary. The few visual dictionaries that were available simply named various things and their constituent parts but neglected to supply definitions and meanings. So there was this void to be filled.
The initial phase of the project, of course, consisted of gathering essential architectural terms and their definitions from various sources. For many, I had to reference textbooks to more fully understand the meaning of a term and then to compose a concise yet accurate definition. At times, defining one term required including other terms embedded in the definition. This led to a natural nesting of terms into sets.
As I continued to compile terms and thought about the project, it became clear that I wanted to not only properly define architectural terms but also gather them in a way that related the terms to each other in a logical and hierarchical way, using both illustrations as well as relative positioning on a page to convey these relationships. So then the truly challenging and fun part of the project was to see how I could organize the terms in such a way that their groupings into sections and subsections made sense.
To do this, I started with fairly obvious divisions, such as design and structures. Once the fundamental term was defined, I then arranged related terms in a hierarchical fashion. For example, design can be defined both as a process and a product, which led to two different sections. In the case of structures, I began with the basic idea of a structure and related concepts that applied to all structures, regardless of material or scale. The second level of terms began with basic types of structural elements, such as arches and beams, and structural systems, such as frames and plate structures, each of which deserved its own section.
Historical terms created its own set of problems regarding inclusion and proper placement. While some terms may be considered obsolete, they remained, in my view, useful as points of reference or retained a certain charm.
Once I had identified the major sections of the dictionary and assigned each term to one of the sections, I imported them into Pagemaker and began laying out the terms and definitions on each page according to their relationships to each other.
I then printed the page out and laid tracing paper over the page and roughed out ideas for illustrations. In many cases, this necessitated moving some of the terms and their definitions around. I then did the final drawings for each page on a single sheet with leader lines and arrows. After these sheets of drawings were scanned, I placed the scans in Pagemaker and adjusted the terms and definitions further to fit. In this second edition, I used Photoshop to eliminate the leader lines and arrows and used the lines and arrows within InDesign. This gave me some leeway in the placement of the images.
It has been a pleasure to develop this second edition and I hope the spirit and flavor of the first edition endures the inclusion of current technology.
It is the only dictionary that provides concise, accurate definitions illustrated with finely detailed, hand-rendered drawings . (Ad-Hoc-News, 22 November 2011)
From the Back Cover
Presented in Francis D.K. Ching's signature style, this long-awaited Second Edition of A Visual Dictionary of Architecture is a remarkable, one-of-a-kind compendium that combines textual definitions and hundreds of superb line drawings to illuminate a comprehensive body of essential terms in architecture, including important interrelationships between building components. Grouped by themes, such as history, systems, structures, forms, construction, environmental issues, and behavior, all terms have their visual complement and can be readily accessed in a number of different ways.
Whether you're an architect, interior designer, construction practitioner, or simply interested in the field of architecture, A Visual Dictionary of Architecture, Second Edition provides an authoritative source of information for tracking down an elusive word—and a delight for simple armchair browsing.
Customer Reviews
Most helpful customer reviews
4 of 4 people found the following review helpful.
Fantastic Resource
By Kevin C. Still
Worth every penny. Having the diagrams along with definitions and examples really helps clarify architectural elements and vocabulary. Highly recommend.
5 of 6 people found the following review helpful.
Great reference tool!
By Afelle
Priceless addition to the serious architecture student's reference library.Any book by Dr. Ching is a worthwhile investment in your education.
2 of 2 people found the following review helpful.
Attractive but difficult to use
By Be Moore
Unnecessarily artistic in its design and layout. I wanted a rather easy to use reference manual. Something with pictures and definitions. Arranged like a reference book. This is a pretty book and is enjoyable to browse but not so useful for quick occasional references.


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6 Bizarre Ways Funerals Will Change in Your Lifetime
While it might seem like the task of burying human remains hasn't changed much in the past 100,000 years, the funeral process has actually evolved quite a bit since our ancestors first invented the concept of "put a body in a hole before the hyenas get here." For example, it wasn't until the Civil War that making a corpse look pretty via embalming became popular, and cremation wasn't even legal in the Western world until 1884.
By the time you attend your last funeral (we're going to go ahead and assume it will probably be your own), the ceremony won't look anything like what we do now. In other words, these aren't your grandma's funeral plans. Unless your grandma is from the future?
#6. Some of Us Are Going to Need Fat Caskets
Digital Vision./Digital Vision/Getty Images
While many companies are concentrating on the fun, technological, and futuristic innovations for the mortuary industry, the real money might be in finding a way to deal with our rapidly expanding waistlines. More than one-third of Americans are classified as clinically obese, and the number is growing, with 50 percent of the population projected to be seriously overweight by 2030. So now we're turning to the same marketing techniques that got us here in the first place and ordering our funeral amenities "supersized."
Ben Sutherland
And gilded.
Back when people didn't drive around parking lots for 10 minutes trying to find a spot 15 feet closer to the entrance, coffins came in 24-inch widths; now the standard is 27 inches. But 3 extra inches is not nearly large enough for some of our more rotund dearly departed. Some funeral homes also supply "oversize" caskets up to 52 inches wide, which might also be a cheaper way to go if you ever know some thin twins who meet their maker on the same day.
Of course, with a bigger casket comes a bigger burial plot. While some cemeteries are starting to sell wider plots, many require customers to buy two plots next to each other to accommodate the larger coffins, meaning the same indignity that larger people suffered on airplanes when forced to buy two seats might actually follow them to the grave. And why not? Land is land. It's not the cemetery's fault that a cadaver is two plots wide.
Even then, we're not done with the ways the world is going to shame the obese once they're dead. Heavier caskets require special loading equipment and hearses, which are already much longer and heavier than your average vehicle, meaning the fatty's beloveds have to rent a special hearse as well. With all the more complex and specialty aspects in mind, a supersized funeral can end up costing $3,000 more than one for an "average"-size person.
Nikada/Vetta/Getty Images
Money is notoriously slimming.
Cremations add a whole new world of problems. Fat burns at a much higher heat than the rest of the body, so the more fat involved, the longer the cremation process takes. It also requires higher temperatures, which, as one German crematorium discovered in 2012, can actually be pretty dangerous. The immolation of a 440-pound corpse caused the oven to burn so hot that the entire building caught on fire.
Matthias Clamer/Stone/Getty Image
"Does anyone else smell BBQ?"
#5. Our Dead Bodies Will Be Earth-Friendly
Alberto Bogo/iStock/Getty Images
Ironically, traditional burials are not the most pro-Earth way of leaving the planet, especially if your body is full of embalming fluid and your coffin is made of lead-lined processed wood. That's why companies are starting to make green coffins that allow people to have traditional burials while barely making a scratch on the environment. Thousands of people in Europe and North America are now requesting green burials, including actress Lynn Redgrave and the founder of the Body Shop, Anita Roddick.
Jacob Wackerhausen/iStock/Getty Images
"I feel a lot better shopping here knowing the owner is organic worm food."
Since the big companies haven't caught on yet, it's often small local businesses keeping up with people's hippie-flavored death needs. For example, while trying to come up with something to make for his grandmother's birthday, carpenter Peter Lindquist decided on the gift every healthy 65-year-old woman would love: a coffin. And he was right. She proved she liked it 27 years later by using it when she died at age 92. Now Lindquist makes simple pine coffins for people who want to be buried in unprocessed local wood.
But using any wood requires cutting down trees. You know what is 100 percent environmentally sound? Pudding. You know what else? Wool. Not only do no sheep die, but the popularity of wool coffins may just be the thing that saves the failing wool industry in Britain. The caskets are made from the wool of up to three sheep and are completely biodegradable. Most companies don't even dye them, which makes the coffins even greener. They can also be made in any size, hold up to 900 pounds, and cost a fraction of what bespoke oversized wooden coffins cost.
Monkey Business Images/Monkey Business/Getty Images
"A couple more stitches and I can have that second piece of pie."
In addition, many companies are also looking to less labor-intensive materials for green burials. Cardboard coffins have become popular, but they do have the rather unfortunate problem of occasionally collapsing before the deceased is actually in the ground -- sometimes during the funeral itself. Other companies make coffins out of recycled newspapers, which not only allow for a sturdier build, but add to the green effect by recycling up to 120 old papers.
You can't buy class.
If you are looking for something even greener, but with slightly grosser results, look no further than the process of resomation. A body is placed in a simple silk bag and submerged in a liquid made from lye and water, and the body is effectively boiled, with the temperature reaching 320 degrees. When the process is finished about three hours later, the bones are still intact but are usually crushed into a powder and returned to the family. The rest of the body isn't necessarily something that relatives are going to want to hold on to: Everything else has been reduced to brown "goo." But hey, anything for the environment, right?
#4. Digital Remains Will Let Us Live Forever
Jeffrey Hamilton/Digital Vision/Getty Images
In the past, you only had to worry about your (probably) eternally damned soul and, to a lesser extent, what happens to your body when you die. But these days people are seriously concerned about something between the ethereal and the physical: their digital remains. Think about it. When you die, will the right people know all of your passwords and have access to your accounts? Should you put that information in your will? Who gets ownership of your music collection, e-books, and domain names? Not surprisingly, companies are springing up to help people deal with all of these things and more. True, we could all just figure this stuff out for ourselves, but this is capitalism at work, damn it!
Jim DeLillo/iStock/Getty Images
"But I'm not dead y-"
"You have a week, tops. Don't be selfish; I've got bills."
Of course, it's not just about who gets what. There are also people you don't want seeing certain things. You might not mind if your brother finds your extensive porn collection, but what if your mother does? Well, these new companies will make sure (for $10 to $30 a year) that your digital information is stored and, when the time comes, they guarantee to distribute the information to the correct people.
Jupiterimages/Stockbyte/Getty Images
"Back Door Sluts 3. He really, really shouldn't have."
What if you want to stay connected all the way to the grave? That is where the eTomb comes in. This is an actual physical tombstone, but with some sexy information-age bells and whistles. Still in development, this special tombstone would contain all the online information about the deceased: their photos, Facebook page, Twitter feed, and so on, and would allow people in the cemetery to access the information through Bluetooth devices. You know how annoying it is to go to dinner when everyone around the table is poking at their smartphones? Now imagine that at a funeral. Solar panels built into the tombstone would keep it charged. Of course, it wouldn't be a true online experience if there weren't trolls, so the eTomb would also have safeguards ensuring that only nice things were posted in this virtual guestbook. All that would be required is for a grieving family member to go through and delete all the horrible messages people leave about you.


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Denzel Washington returns to Broadway this spring to star in a revival of Lorraine Hansberry's "A Raisin in the Sun" alongside Diahann Carroll, who will appear on the Main Stem for the first time in 30 years.
Kenny Leon directs a cast that also includes Sophie Okonedo of the film "Hotel Rwanda" in her Broadway debut and stage regulars Anika Noni Rose, Stephen Tyrone Williams, Jason Dirden and Stephen McKinley Henderson.
The play chronicles three generations of a family living on Chicago's South Side. Last seen on Broadway in 2004 in a production also helmed by Leon with Sean Combs and Audra McDonald, the influential work also served as the source material for "Clybourne Park," which won the 2011 Pulitzer Prize and the 2012 Tony for Best Play.
In addition to their extensive careers onscreen, Washington was a Tony Award best actor winner for his 2010 turn in "Fences," and Carroll a best actress winner in 1962 for "No Strings."
The show is slated for a 14-week limited engagement at the Barrymore Theatre beginning previews March 8 with an April 3 opening night.
Washington's latest film — "2 Guns," co-starring Mark Wahlberg — opened on Thursday.
• Tony Awards 2010: Denzel Washington wins first Tony
• 'Flight' sneak peak: Denzel Washington in free fall


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Kitchen Inspiration: 10 Lovely Kitchen Islandsjentatertots
Lets face it, the kitchen is the new living room. It is a great place to gather with your friends and family. And whether you're entertaining, preparing food, or helping the kids with homework, you can always use more counter space. These 10 lovely kitchens provide kitchen island inspiration that is beautiful yet practical for teeny-tiny kitchens and big sprawling kitchens alike! And I love how the owners repurposed other furniture to create some of them!
Check out how …after the break!
Repurpose a Buffet 1 of 10This beautiful antique buffet adds one-of-a-kind appeal! Use a desk, or a dresser, and install a stone countertop to complete the charming look.
Learn more at BHG
Accent with Beaded Board 2 of 10The beautiful beaded board adds subtle texture and a warm cottage feel.
Learn more at BHG
Use a Small Butcher Block 3 of 10A butcher block is the perfect island solution for those that dwell in small spaces!
Learn more at Apartment Therapy
Paint! 4 of 10Painting is one of the cheapest ways to make a dramatic change. I love the sunny citron vibe that this bright color adds, it completely changes the mood of the room!
Learn more at BHG
Mix Texture 5 of 10Use an antique wood desk to warm up the sleek austere surfaces of your kitchen.
Learn more at Martha Stewart
Mobile DIY Island 6 of 10This DIY island is cute, mobile, and adds that extra prep space when you need it!
Learn more at Fresh Home Ideas
Attach Seating 7 of 10Attaching a comfy bench at the end of the kitchen island makes for a perfect breakfast nook or homework corner.
Learn more at Flickr
Use a Narrow Table 8 of 10This elegant narrow table adds precious extra counter space and helps define the perimeters of the kitchen.
Learn more at Houzz
Extend the Island 9 of 10Extending the counter top can be deceptively easy and is a fabulous way to increase prep area!
Learn more at BHG
Use a Small Cart 10 of 10Small inexpensive carts can be pushed to the side if needed and come in a huge array of styles and varieties!
Learn more at Apartment Therapy
TT&J on Facebook — where I love to share great ideas.
TT&J on Pinterest — my newest favorite place.
15 clever tips to organize your kitchen
25 amazing beauty products you can make in your kitchen
24 ways to decorate your home with a Sharpie
20 DIY headboards you won't find at Pottery Barn
10 everyday household items that double as organizers


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Our own collection only holds a few tees so we will invite the public to submit their tees in four or five categories which we develop (i.e. community-building, corporate, etc.)
To launch the exhibition we are hosting a panel of academics to discuss the multi-dimensional role of the tee-shirt in our culture and globally. To date Dr. Ardis Cameron (University of Southern Maine) and Dr. Erica Rand (Bates College, Lewiston, Maine) have agreed to participate.
If you would be interested in participating in our panel discussion, please let me know (207) 865.3170. We have applied for funding which includes a stipend and travel reimbursal.
Thank you for considering participation in our program. And, Happy Holidays,


text: New from Pointer Footwear comes their popular A.F.D model in two fresh and attention-grabbing colorways for the 2011 fall/winter season. Both iterations of the canvas low-top sneaker feature bright, all-over prints that breathe a breath of fresh air into the otherwise basic yet versatile A.F.Ds. With a pop-art styled camouflage and an ebullient "Sky" option, there is a model available for fans at either end of the allover print spectrum. Available soon for £65 GBP (approximately $106 USD).


text:
Playing Hermione isn't as spellbinding as it seems. Emma Watson says she has struggled during her journey from 9-year-old child actress to 18-year-old movie star.
"In a way, it's hard to grow up inside a film. I lived a period of my life that is full of lessons and changes under the spotlight," the Harry Potter actress tells Vogue Italy.
"People have the strange feeling of knowing me intimately because they have seen my transformation from child to woman, albeit only on screen."
Watson, who appears in a 20-page photo shoot in the magazine's September issue, appears dressed in fairy tale-like gowns and couture dresses by Versace, Chanel and Armani Privé in a dreamy, theatrical setting.
However, for all her misgivings about her celebrity status, Watson insists she "wouldn't want my childhood in show business to have been any different."
The actress adds: "I learned a lot of things, met tons of people from as many different places and had incredible experiences. It was just a bit different, but that's okay."
Still, Watson admits that at times she feels overwhelmed. "Some days I wish my life were simpler," she says, "but the rest of the time I feel like the luckiest girl in the world. After all, whose life is normal?"
Watson, who recently completed her high school finishing exams. also revealed that her role models include Julia Roberts – "As a child I always wanted to be her. She has a magnetic personality and smile" – and Goldie Hawn, "because she's lots of fun and for her showbiz abilities."
2004: Emma Watson comes into her own
2001: Emma Watson becomes Hermione
Emma Watson: 'It's Hard' to Grow Up on Screen


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Sony Digital Voice Recorder - USB Direct Connect, 4GB Memory, LCD Display, MP3 Recording, VOR, Scene Select, Low-Cut Filter, Digital Noise Canceling, Built-in Speaker - ICDSX733Item#: S396-9114 | Model#: ICDSX733
Currently Out Of Stock!
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Sony 4GB Memory USB Digital Voice Recorder Product Details
Sony Digital Voice Recorder
Easily conduct voice or sound recording sessions with this portable digital voice recorder from Sony. This voice recorder provides utmost convenience as it records audio in MP3 format. Its built-in microphone is a great 3 Directional Mocrophone (Zoom/Stereo) so expect tremendous voice and sound clarity. It is equipped with 4GB internal storage to easily store large amounts of audio files you just recorded. And with its USB port, you easily hook this recorder up into your PC without worries. Choose this Digital Voice Recorder right now.
What It Is And Why You Need It:
- Digital Voice Recorder; uses 3 Directional Mocrophone (Zoom/Stereo) for amazing sound quality
- 4GB of internal storage; stores all of your audio files with ease
- Digital Noise Canceling feature; takes away ambient sounds for clearer recording
- USB port; guarantees easy PC connectivity
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Manufactured by: Sony
Warranty provided by: Sony
UPC No: 027242857582
Mfg Part No: ICDSX733
Box Size:
( Length:11, Width:8, Depth:4)
Shipping Weight: 0.9000 pound(s)
Dimensional Weight: 2pounds
What is Dimensional weight?
Click here for full warranty and support information
- Sony logos are registered trademarks of Sony. All others trademarks and copyrights mentioned herein are the property of their respective owners.


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Important News
The following are changes made to federal student aid programs by the recently enacted Consolidated Appropriations Act 2012 and Budget Control Act of 2011. We are also including other changes that may affect your financial aid eligibility or application process for Summer 2012 and 2012-2013.
Summer 2012
Year Round Pell provisions ended at the conclusion of the 2010-11 award year. Students will no longer be able to receive a Second Pell Grant in one award year as of 2011-12. Students who received the annual maximum Pell award in Fall 2011-Spring 2012 will not be eligible for Pell in Summer 2012.
2012 - 2013
Starting award year 2012-2013, we strongly advise students to use the IRS Data Retrieval Tool within the FAFSA to provide income tax information. The IRS Data Retrieval Tool will allow FAFSA applicants to request and retrieve their income tax data from the IRS in order to complete the FAFSA. Please note, if students do not use the IRS Data Retrieval Tool and are selected for financial aid verification, they will be required to obtain an official tax transcript from the IRS. Financial Aid will no longer accept Income Tax Returns.
Verification Changes
Effective 2012-13, students selected for verification can no longer submit signed tax returns. Students who get selected for verification and when completing the FAFSA did not use the IRS Data Retrieval Tool will be required to provide an IRS Tax Transcript or make corrections to their FAFSA by using the IRS Data Retrieval Tool. Due to this new requirement, we strongly encourage all students to utilize the FAFSA-IRS Data Retrieval process when completing their FAFSA to limit requests for the Tax Return Transcripts.
Repeated Coursework
Students may not receive federal aid for courses that were previously taken and passed beyond the first retake. In other words, once a student has passed a course, the student has one additional attempt to complete the same course and still be eligible to receive federal financial aid for that course. There is no limit on the number of attempts allowable if the student does not receive a passing grade. Some courses are repeatable per university policy and are not restricted by these regulations.
Pell Grant Duration of Eligibility
Effective 2012-2013, the duration of a student's eligibility to receive a Federal Pell Grant is reduced from 18 semesters or its equivalent, to 12 semesters or its equivalent. The calculation of the duration of a student's eligibility will include all years of the student's receipt of Federal Pell Grant funding.
Elimination of Subsidized Loan Eligibility for Graduate/Professional Students
Effective for loan periods beginning on or after July 1, 2012, graduate and professional students will no longer receive Subsidized Loans. As a result, graduate and professional students will be awarded Unsubsidized Loans, which means the loan will accrue interest while a student is in school. These changes will not affect the annual and aggregate borrowing limits. The maximum amount a student can borrow will remain at $20,500 per academic year.
Direct Loan Borrower Repayment Incentives Eliminated
The Budget Control Act terminates the authority of the Department of Education to offer any repayment incentives to Direct Loan borrowers to encourage on-time repayment of loans, including any reduction in the interest rate. The law continues to authorize the Department of Education to offer interest rate reductions to Direct Loan borrowers who agree to have electronic payments automatically debited from a bank account.
Direct Loan Origination Fee Rebate Eliminated
Effective for loan periods beginning on or after July 1, 2012, the up-front rebate that has been provided to Direct Loan borrowers at the time of their loan disbursement will be eliminated. As a result, the origination fee for the Direct Stafford Loans will be 1.5% (previously at 1.0%) and the origination fee for the Direct PLUS Loans will be 4.0% (previously at 2.5%).
Grace Period Interest Subsidy Temporarily Eliminated
Interest subsidies provided on Direct Subsidized Loans during the six month grace period will be temporarily eliminated for Direct Loans whose first disbursement is made on or after July 1, 2012 and before July 1, 2014.
Direct Loan Interest Rates
Effective for loan periods beginning on or after July 1, 2012, the subsidized and unsubsidized Direct Stafford Loan interest rate for the 2012-13 academic year will be fixed at 6.8%. The interest rate for the Direct PLUS and Graduate PLUS Loan is fixed at 7.9%.
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text:
Dark eyes that are frightening but comforting at the same time,
A heart that can be warm or its core filled with ice,
Ears that can hear my heart pounding,
Fangs that can rip open my flesh.
Can fall in love but pay the price,
Wander in the night
Drink blood to satisfy their thirst,
Perfect in every way,
Have their horrid past and many different ways of taking it.
In the need of someone but prefer to be alone,
With tenderness underneath.
How long until we understand these creatures?
How long until the war of our worlds ends?
How much longer will we be blind?
There is so much more to a vampire than meets the eye.
The paleness of their skin,
The warmth of their body replaced with an icy feeling,
Each one has their own unique trait,
Every one has a weakness,
Every one has untold petinual.
Vampires what would so many people do without them?
Look behind those eyes,
Look behind their twisted minds,
Look behind their broken souls,
And you find a little piece of you,
Were all the same.
So much we still have to learn about you,
So much we need to understand,
What would we do without you?


text:
Mo. Democrats likely to support gun bill veto override
Measure would nullify federal gun laws in Show-Me State
With the help of some Democrats, Missouri's Republican-led Legislature appears to be in position to override Gov. Jay Nixon's veto of a high-profile bill that seeks to nullify federal gun-control laws in Missouri and make criminals out of federal agents who try to enforce them.
The Democratic governor contends the bill violates the U.S. Constitution.
Several of his fellow Democrats told The Associated Press that they don't disagree, but they say a "no" vote on gun-control legislation in some parts of Missouri could be career ending.
The Republican-led Legislature is to meet in September to consider a veto override.
Copyright 2013 by The Associated Press. All rights reserved. This material may not be published, broadcast, rewritten or redistributed.


text:
|Boxing Champions | Boxing Schedule | Boxing Video | Boxing History | Pound For Pound | Lounge | The Wire | Arcade
Undisputed Champion
Join Date: Apr 2005
Location: Houston
Posts: 2,282
Quoted: 0 Post(s)
Rep Power: 16
Points: 10,127,114.12
Bank: 4,270,497.42
Total Points: 14,397,611.54
Picking up our retired Champions should the paid by sanctions they collect.
So sick of watching greats like Smoky Frazier, Gatti and other greats ending up living miserable lives. The Organizations collect millions in sanctions, penalties, etc and none of those funds to back to the boxers that made them the money. While Sulaiman and others like him make themselves millions from the blood of our heroes, the ones who produced those moneys die living like dogs. They should be accountable for those.
Wilfredo gave us great fights for more than 20 yrs, so where is his retirement money? Some don't needed, but we should take care of the ones who do.
I Also Cook
Join Date: Oct 2012
Posts: 9,937
Quoted: 984 Post(s)
Rep Power: 45
Points: 3,017,001,295,521.36
Bank: 0.00
Total Points: 3,017,001,295,521.36
You're right, but it would take a fighters union to establish something like this. And because boxers are in direct competition with each other, it's too easy for the fat cats to divide and rule.
Join Date: Dec 2007
Location: Reading UK
Age: 26
Posts: 8,880
Quoted: 1225 Post(s)
Rep Power: 49
Points: 2,942,501,217,279,661.00
Bank: 543,700,587,761,420.94
Total Points: 3,486,201,805,041,081.50
Also its worth remembering that most sports only the highest level will offer support in retirement due to the fact that they have such short careers. Most fighters with good judgement and forward planning are able to remain comfortable after they retire.
Undisputed Champion
Join Date: Feb 2012
Posts: 7,634
Quoted: 2 Post(s)
Rep Power: 33
Points: 193,983.82
Bank: 389,482,418,360.95
Total Points: 389,482,612,344.77
Didn't Gatti have something like $3 million in the bank? Hardly living like a dog.
WBC announced that they are setting up a pension fund for boxers not long ago.
If a fighter blows all his money why blame the orgs? Their promoters take a much bigger split.
A fighter that makes a mass fortune would be better off having a financial advisor.
It's the fighters that fight all there careers and make peanuts that should get the most help.
Last edited by Michael Paine; 12-05-2012 at 01:14 PM.
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To the Editor.—
The EDITORIAL COMMENTARY in the August issue of the Archives (136:865-866, 1976) entitled "Chihuahuas and Laetrile, Chelation Therapy, and Honey From Boulder, Colo" was interesting. It was pointed out quite correctly that evidence to date indicates the substance to be "worthless but harmless." As a practicing oncologist, I believe the handling of the laetrile "problem" is nonsensical. The commentary stated that the great danger from laetrile lies in the temptation presented to the cancer victim to resort to it rather than seek early medical attention. My observation is that people who do seek laetrile know they have cancer and have had that diagnosis presented to them by a physician. Any delay in seeking medical attention is seldom due to a distraction by laetrile because such people may fear but do not know that they have cancer.It was also stated that we have been successful in preventing
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text:
Not bad if you believe that attempting to demonstrate ROI for new technologies has led many reckless souls down blind alleys from which they never returned. The endless and inconclusive efforts to cost-justify the PC is a great example. In the end, the PC's proliferation is its best argument. Maybe that's best. Bland statistics often fail where concrete examples succeed — which is sort of the idea behind the Best Practices program.
Starting on page 60 of this issue, you will find a complete listing of all the entries in this year's competition, and overviews of the three grand prize winners (Millennium Pharmaceuticals, Baylor College of Medicine, and Solutia) starting on page 55. Here, however, are some observations from a random walk down BP lane, which should provide a flavor of the impressive range of technologies being used by these companies and the problems they are seeking to solve.
Let's start with data mining. Can it work? The Abramson Family Cancer Research Institute of the Abramson Cancer Center at the University of Pennsylvania ran a pilot program to answer that question. Using statistical analysis tools from SPSS (LexiQuest Mine), researchers developed a text data-mining tool that was used to extract knowledge of disease progression, disease presentation, and co-morbidities when comparing sporadic and genetically linked breast cancer (e.g., BRCA1 or BRCA2). It did work.
The Abramson entry notes: "It's impossible to read every paper published ... Lexi-Quest resolves this issue by 'reading' the papers and presenting their concepts and relatedness, enabling researchers to use 'all of the data' when drawing conclusions from journals." Abramson plans to extend this approach to other diseases and research areas.Stats, LIMS, and Voice Response
Applying the power of statistical analysis to the flood of data was a minor theme among entrants. Translational Genomics Research Institute (TGen) has built a tool to compare gene expression data from different manufacturers' chips. Using liver and heart tissue, TGen conducted expression experiments using chips and analysis platforms from Affymetrix, Agilent, Amersham, and Mergen.
TGen's entry stated: "We hope to have much more confidence in the data obtained by our scientists, and greater power in hypothesis testing while still being able to provide data to public databases quickly, easily, and accurately."
Another interesting entry was submitted by Genentech, which is using interactive voice response (IVR) technology and statistical modeling to keep clinical hospitals stocked with the right number of "clinical trial" kits. Genentech wants to control manufacturing and distribution costs while keeping patients supplied. Patients enroll by phone, and the system automatically models demand and schedules manufacturing and shipping.
Several entries demonstrated the dramatic impact even less glamorous technology can have on research. Aventis recently implemented a sophisticated LIMS (Nautilus from Thermo Electron) in its Cambridge (Mass.) Genomics Center, which serves Aventis researchers throughout the world. The system is up and running in the United States and being rolled out to Germany. Researchers place work orders and track projects over the Web.
According to Aventis, "One unanticipated benefit from the reporting capabilities coupled with the long-term data storage that the LIMS provides is the ease with which samples can be returned to disease groups when needed for further characterization even many months after the samples have been processed and archived away in freezers."
The amassing of enormous computing capacity was evident in many entries. The State University of New York at Buffalo is creating a giant cluster with 2,000 Dell servers that lifts it to #22 among the Top 500 supercomputers. Unraveling structural biology knots is the target of all this computer power.
Predictably, projects often don't unfold as planned, and some companies were quite forthright. Abbott Laboratories' project to create a global database for preclinical biological testing data came to a screeching halt after a few months. Its existing system was a muddle of heterogeneous databases that communicated poorly and needed to be replaced. "As everyone is well aware, projects can spin out of control. Suffice it to say, the first set of rollouts were close to disastrous," the entry reported.
Early planning wasn't the problem. The RFP was detailed. Started in 1999, the project was expected to take two years. Unrealistic assumptions, however, were problematic. After regrouping — one lesson was "Listen to the effort estimates of the staff, not manager projections or vendor predictions" — the project is nearing completion, with about 90 percent of Abbott scientists using the system and a forecast of $6 million in annual savings.
Clearly, a field of 50 entries contains far more material, and some of it will turn up in articles over the next few months. But our attention has already turned to improving next year's competition.
How can we better practice what we preach? Send me your thoughts on ways to improve Bio·IT World's Best Practices Awards at email@example.com Russell is executive editor of Bio·IT World, and his column, The Russell Transcript, will alternate with The Dodge Retort. PHOTO BY WEBB CHAPPELL
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text:
linux-ec2 2.6.32-353.66 source package in Ubuntu
linux-ec2 (2.6.32-353.66) lucid-proposed; urgency=low [ Stefan Bader ] * Rebased to Ubuntu-2.6.32-48.110 * Release Tracking Bug - LP: #1186479 [ Ubuntu: 2.6.32-48.110 ] * (config) Import Xen specific config options from ec2 - LP: #1177431 * SAUCE: xen: Send spinlock IPI to all waiters - LP: #1011792, #1177431 * ax25: fix info leak via msg_name in ax25_recvmsg() - LP: #1172366 - CVE-2013-3223 * Bluetooth: fix possible info leak in bt_sock_recvmsg() - LP: #1172368 - CVE-2013-3224 * tipc: fix info leaks via msg_name in recv_msg/recv_stream - LP: #1172403 - CVE-2013-3235 * rose: fix info leak via msg_name in rose_recvmsg() - LP: #1172394 - CVE-2013-3234 * Bluetooth: RFCOMM - Fix missing msg_namelen update in rfcomm_sock_recvmsg() - LP: #1172369 - CVE-2013-3225 * atm: update msg_namelen in vcc_recvmsg() - LP: #1172365 - CVE-2013-3222 * KVM: Fix bounds checking in ioapic indirect register reads (CVE-2013-1798) - LP: #1158262 - CVE-2013-1798 * llc: Fix missing msg_namelen update in llc_ui_recvmsg() - LP: #1172385 - CVE-2013-3231 * netrom: fix info leak via msg_name in nr_recvmsg() - LP: #1172386 - CVE-2013-3232 * irda: Fix missing msg_namelen update in irda_recvmsg_dgram() - LP: #1172380 - CVE-2013-3228 * iucv: Fix missing msg_namelen update in iucv_sock_recvmsg() - LP: #1172381 - CVE-2013-3229 -- Stefan Bader <email address hidden> Tue, 04 Jun 2013 10:12:05 +0200
Upload details
- Uploaded by:
- Stefan Bader on 2013-06-04
- Uploaded to:
- Lucid
- Original maintainer:
- Ubuntu Kernel Team
- Architectures:
- all i386 amd64
- Section:
- devel
- Urgency:
- Low Urgency
See full publishing history Publishing
|SHA-256 Checksum
|78.1 MiB
|9.0 MiB
|2.1 KiB
Available diffs
- diff from 2.6.32-352.65 to 2.6.32-353.66 (3.9 MiB)
Binary packages built by this source
- linux-ec2-doc: Linux kernel specific documentation for version 2.6.32
This package provides the various documents in the 2.6.32 kernel
Documentation/ subdirectory. These document kernel subsystems, APIs, device
drivers, and so on. See
doc/linux- ec2-doc/ 00-INDEX for a list of what is
contained in each file.
- linux-ec2-source-2.6.32: Linux kernel source for version 2.6.32 with Ubuntu patches
This package provides the source code for the Linux kernel version
This package is mainly meant for other packages to use, in order to build
custom flavours.
If you wish to use this package to create a custom Linux kernel, then it
is suggested that you investigate the package kernel-package, which has
been designed to ease the task of creating kernel image packages.
If you are simply trying to build third-party modules for your kernel,
you do not want this package. Install the appropriate linux-headers
package instead.
- linux-headers-2.6.32-353: Header files related to Linux kernel version 2.6.32
This package provides kernel header files for version 2.6.32, for sites
that want the latest kernel headers. Please read
doc/linux- headers- 2.6.32- 353/debian. README. gz for details
- linux-headers-2.6.32-353-ec2: Linux kernel headers for version 2.6.32 on x86/x86_64
This package provides kernel header files for version 2.6.32 on
This is for sites that want the latest kernel headers. Please read
doc/linux- headers- 2.6.32- 353/debian. README. gz for details.
- linux-image-2.6.32-353-ec2: Linux kernel image for version 2.6.32 on x86/x86_64
This package contains the Linux kernel image for version 2.6.32 on
Also includes the corresponding System.map file, the modules built by the
packager, and scripts that try to ensure that the system is not left in an
unbootable state after an update.
Supports Generic processors.
Geared toward desktop systems.
You likely do not want to install this package directly. Instead, install
the linux-ec2 meta-package, which will ensure that upgrades work
correctly, and that supporting packages are also installed.


text:
Thursday 19 July 2012
The drector general of Civil Defense on Wednesday said this year's general emergency response plan in Makkah and Madinah will be successful.
With more than 10,000 men and 2,000 vehicles including nine helicopters, the forces are prepared for dealing with any emergency, Lt. Gen. Sa'ad bin Abdullah Al-Tuwaijri said.
Al-Tuwaijri was inspecting Civil Defense forces as they implemented the emergency response plan in Makkah.
He watched a demonstration involving a number of the new vehicles that will take part in the Umrah season for the first time, including a multipurpose unit that can be used for fire extinguishing, rescue and providing first aid.
There were others that dealt with accidents involving chemical or radiation leakage.
Al-Tuwaijri inspected field specialist teams and their vehicles.
The plan was approved by Minister of Interior Prince Ahmad and involves 18 government bodies.
It is largely developed in terms of deploying and stationing field units to reduce response times, said Al-Tuwaijri.
More than 2,000 paramedics were deployed to provide first aid to the sick and elderly inside and outside the Grand Mosque. New teams and temporary centers were created to cover all routes to Makkah and support forces there.
Al-Tuwaijri underlined the plan's preventive measures including inspecting safety equipment and measures at more than 6,000 pilgrim accommodation buildings in Makkah and handle any violation that could pose a threat to safety or obstruct Civil Defense staff in case of emergencies.
The department also increased its awareness programs for pilgrims to help them avoid hazards through the use of signboards, leaflets and text messages among others.
Categories: Asia, Saudi Arabia