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Energy & Renewables Companies in Colorado
Current filtering criteriaYou can remove a filter by clicking on the x
Blue Sun Biodiesel
based in Westminster, COLORADO (USA)
Blue Sun is working to incorporate biodiesel into the existing petroleum fuels infrastructure by focusing on an integrated approach to addressing market needs. Blue Sun`s agriculture research and development plan is focused on developing low-cost oilseed crops that are well-adapted to the hot, semi-arid growing conditions of the High Plains.
Data West Corporation
based in Durango, COLORADO (USA)
We specialize in helping customers like you deal with real-life challenges in the utility billing environment. We designed BillMaster from the ground up to create a software system that is comprehensive, efficient, easy to use, and which contains the specialized features and capabilities - from special meter functions to taxes - that the utility industry needs.
Energy Central
based in Aurora, COLORADO (USA)
Energy Central is a hub on the Internet for electric power professionals searching for information, products and services related to the energy industry. By teaming with companies that service the energy industry, Energy Central provides a broad base of information products - news, directories, events, databases, books, periodicals, reports - all focused on a single ...
Harner Environmental Management
based in Littleton, COLORADO (USA)
Offers ecological and environmental consulting services to resource development companies, including design, implementation, and management of ecological and environmental studies. Specializes in vegetation, soils, wildlife, aquatic biology, and reclamation services. Industries served: mining, utilities, gas and oil, and transportation industries and government agencies.
based in Fort Collins, COLORADO (USA)
Czero is a team of concerned engineers focused on developing and disbursing innovative technologies that reduce energy consumption and harmful emissions that threaten our environment. Our background is primarily research and development in automotive and heavy duty trucks and we continue to work there, but are also developing renewable energy technology development for ...
US-Reports, Inc.
based in Loveland, COLORADO (USA)
We provide AAI Compliant Phase One`s, Transactions Screen Assessments, and Desktop Reports - all with an Environmental Professionals opinion given in a clear and consistent format. As a Nationwide company all ordering and retrevial of reports is web based - quick and simple. Flat fees, no contracts, excellent turnaround time, and HIGH Quality reports! It`s what we do - ...
based in Littleton, COLORADO (USA)
What is NorgrenIQ? A holistic approach combining advanced technology, an innovative process, and expert partnerships to provide a best-in-class, complete air management solution. Our team will analyze, design, install and maintain custom systems to increase efficiencies and decrease electric costs. When properly applied, expect a return on investment (ROI) of 15-40% ...
Stoel Rives LLP
Office in Denver, COLORADO (USA)
Stoel Rives enjoys a 100-year tradition of excellence as a leading U.S. law firm. With nearly 400 lawyers practicing across the full spectrum of corporate law and business litigation, and offices in eight states, we provide legal services to clients with local, regional, national and international operations.
Colorado State University (CSU)
based in Colorado, COLORADO (USA)
Colorado State University (CSU) is one of our nation`s leading research universities with world-class research in infectious disease, atmospheric science, clean energy technologies, and environmental science. As the Colorado Agricultural College, six years before the Colorado Territory became a state. Last year, CSU awarded degrees to more than 5,000 graduates, and this ...
A2BE Carbon Capture, LLC
based in Boulder, COLORADO (USA)
Jim Sears and Mark Allen founded A2BE Carbon Capture to take on the challenge of commercializing technologies that have meaningful prospects for rebalancing the carbon content of the atmosphere. Such technologies must be capable of being sustainable deployed in developed and developing regions of the world and provide positive economic returns such that market mechanisms ...
Solar Sphere, Inc.
based in Denver, COLORADO (USA)
SpheralSolar.com is an e-commerce site specializing in a wide variety of residential and commercial alternate energy products including DIY Solar Kits, Solar Generators, Solar Training Videos, Solar Survival Gear, Charge Controllers, Inverters and Solar Lighting. The site is the online arm of Sphere Solar, nations leading distributors of alternate energy products, linked ...
Carbon Zero Engineering, LLC
based in Highlands Ranch, COLORADO (USA)
At Carbon Zero Engineering, we specialize in the design and manufacturing of hydrogen fuel cell power plants for the commercial transport industry. We offer retrofit services for end users with existing vehicles as well as collaborate with OEMs to create turn-key, drop-in solutions right off the production line.
Leitwind AG / SPA
Office in Grand Junction, COLORADO (USA)
The LEITWIND success story starts with ropeways, a core expertise of LEITWIND's parent company HTI. It has evolved from a group of ropeway builders which has, for decades, installed leading-edge technology into spectacular mountain terrain. One of the interesting features of ropeways is the electric direct drive: Its simple, rugged construction has proven its outstanding ...
Main Street Power Company, Inc
based in Boulder, COLORADO (USA)
Main Street Power Company, Inc. is a Power Purchase Agreement (PPA) provider, owner and operator of solar projects across North America. Main Street Power specializes in securing innovative financing solutions through PPAs for its distributed generation and large-scale utility clients. We are committed to forming partnerships with installation professionals, general ...
Car-May L.L.C.
based in Berthoud, COLORADO (USA)
Car-May designs and manufactures superior fluid control systems for a broad range of metering and dispensing applications.The revolutionary Travcyl™ pump design provides exceptional accuracy and control for a variety of dispensing and low-flow metering uses. The pharmaceutical, medical, and biotech industries employ these fluid systems for manufacturing, process control ...
Office in Denver, COLORADO (USA)
Ubisense is a global leader in Enterprise Location Intelligence solutions. We work with manufacturing, communications and utilities companies, enabling them to improve operational effectiveness, increase efficiency and boost profitability. With the latest location technology at their fingertips, the possibilities are endless. Our solutions help users at every level and in ...
Vista GeoScience LLC
based in Golden, COLORADO (USA)
Vista GeoScience is a conglomeration of expertise that has served the environmental remediation and exploration industries since 1986. The combined staff previously ran operations at Direct Geochemical, TEG Rocky Mountain, ESN Rocky Mountain, and Pelorus Environmental & Biotechnology Corp., among others.
RJ Mann & Associates
based in Brighton, COLORADO (USA)
RJ Mann & Associates, Inc. has been servicing the oil and gas markets in the Rocky Mountain region for nearly 20 years. We specialize in servicing and supplying instrumentation, engine controls, emissions products, and compressor components in the oil and gas market. We offer a full range of engine controls panels, air to fuel ratio controllers, engine ignitions, ...
Merrick & Company
based in Aurora, COLORADO (USA)
At Merrick, you'll discover innovation for a changing world. Growing demand for expert solutions that effectively manage project development, optimize operations, and support client needs are allowing us to explore and deliver new opportunities to our clients for lasting, future-smart, and sustainable results. Beyond ordinary, Merrick delivers innovation for your ...
HRL Compliance Solutions, Inc. (HCSI)
based in Grand Junction, COLORADO (USA)
HCSI is a full service environmental consulting firm providing services locally and nationally to private enterprises and both governmental and non-governmental organizational entities. HRL Compliance Solutions, Inc. was established as a small business enterprise dedicated to providing environmental consulting, site assessment and remediation, and waste management ...


text:
- Report: #336907
Report - Rebuttal - Arbitrate
Complaint Review: Samsung Electronics America Inc
Samsung Electronics America Inc105 Challenger Rd Ridgefield Park, New Jersey U.S.A.
Samsung Samsung Electronics America Inc Defective Monitor(s) and Horrible Customer Service Ridgefield Park New Jersey
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As I had not read the warranty fully and as I was not informed of the fact beforehand I was surprised that the replacement was refurbished. I have bought refurbished equipment before and had a good experience so the annoyance was only minor at that point. However, the replacement monitor would not work either. I even took it to a local tech support office and had them check it and they received the same result.
I contacted Samsung with the issue and they offered another replacement. I requested that I not be delivered another refurbished monitor as it would obviously already have been broken at some point and I did not want another broken monitor. No matter who I talked to I kept receiving the same canned reply, "After 90 days it is our policy to make replacements from refurbished stock." My reply to this was that nowhere in their policy did it make provision for receiving two defective monitors in a row, that I had no confidence in their product, and that receiving a new monitor would ease my concerns and probably not cost them any more than the two they had already sent.
They wouldn't budge over the phone so I sent letters to Samsung, Dell, and the BBB about the issue. The BBB replied that the issue did not fall withing the service they provided. Dell replied that beyond 30 days third party equipment was not covered by them. Samsung simply did not reply.
About one month later I received a call from Samsung asking if I had received my replacment monitor, yet. I explained the situation to the representative and he informed me that he would request that I be contacted by management to resolve the issue. A couple days later someone did indeed contact me and informed me that I would be receiving a NEW monitor and actually a similar model (206).
One week later I received an email that my monitor had shipped. A few days after that it arrived at the local UPS store for exchange. Upon my arrival the clerk brought out a box with REFURBISHED in large type across the top of the box. On the inside was the same model I already had and not the one promised on the phone conversation earlier.
I have contacted the company (yesterday) with the assuring message on their site that they respond to messages within 24 hours. I have not, as yet, received a reply.
All told, this process has been going on two months with no resolution in sight.
Great Falls, Montana
This report was posted on Ripoff Report on 06/03/2008 08:22 PM and is a permanent record located here: http://www.ripoffreport.com/r/Samsung-Electronics-America-Inc/Ridgefield-Park-New-Jersey-07660/Samsung-Samsung-Electronics-America-Inc-Defective-Monitors-and-Horrible-Customer-Service-336907. The posting time indicated is Arizona local time. Arizona does not observe daylight savings so the post time may be Mountain or Pacific depending on the time of year.
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first of all thank you for this plugin it's really usefull to be able to track statistics for marketpress.
I just have a question about the capabilities required to access the statistic pages.
I'd need to change these so editors can view them.
I have changed the current code so it's possible for people to do that but i'm not sure it's a good solution as any update of the plugin will remove my code.
I've also tried with a plugin i usually use to give people access to things they aren't supposed to but the admin slug is not correctly set, maybe because of the restrictions set in the code itself.
Again thanks for your help :)


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Articles from 02/2011
U.S. Secretary of Education Arne Duncan to Keynote Iowa Education Summit
Friday, February 25, 2011
U.S. Education Secretary Arne Duncan will be the keynote speaker at Gov. Terry Branstad's Iowa Education Summit to be held Monday, July 25, and Tuesday, July 26, in Des Moines. The goal of the summit, which Gov. Branstad announced during his inaugural address last month, is to build a consensus for how Iowa can on…
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Iowa's High School Graduation Rate Increases
Thursday, February 17, 2011
The graduation rate for Iowa's Class of 2010 increased over the previous year, according to figures released by the Iowa Department of Education. In fact, all but one student subgroup saw an increase in its graduation rate, with significant increases among both English-Language Learner and Hispanic students. â…
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about Iowa's High School Graduation Rate Increases
More Iowa Seniors Participate, Succeed in Advanced Placement Courses
Wednesday, February 9, 2011
The number of Iowa high school seniors who participate and succeed in Advanced Placement courses continues to grow, according to the 7th Annual AP Report to the Nation released by the College Board. A total of 5,135 members of Iowa's Class of 2010 took at least one AP exam while in high school, a 9.5% increase over the…
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Copycat Alert: Chennai Express Takes Inspiration From Mungaaru Male!
Bollywood superstar Shahrukh Khan's many movies have come under remake scanner in the last several years. Especially, his hit films in the recent years had close resemblances with Kannada movies. Now, his latest movie Chennai Express directed by Rohit Shetty, a Kannadiga, too has some connections to Sandalwood.
Before getting into the latest issue, let us look at his earlier movies, which were accused of being remakes of Kannada flicks. Way back in 2004, when his Swades hit the screens, Kannada audience were surprised looking at the storyline of the Hindi movie!
It is because the film had a similar story to Shivaraj Kumar starrer Chigurida Kanasu. The Kannada movie was a screen-adaptation of Jnanapeeth laureate Shivaram Karanth's acclaimed literary work of the same name. It was directed by TS Nagabharana.
Chigurida Kanasu was a commercial disaster but it bagged four state awards. It was the story about a man from Delhi, searching his roots and landing in his native place. After coming to a village called Bangaadi, he decides to change the fate of the village.
Whereas in Swades, Shahrukh Khan, an NRI, returns to India and does the same thing as Shivanna did in Chigurida Kanasu. Later, Kannada media picked up the issue and TS Nagabharana too said that the Hindi movie resembled Chigurida Kanasu to a large extent.


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UPDATE: The Santorum campaign may have spent much more than 5 percent of its overall ad budget online, after all. Because the campaign has not filed all of its Federal Election Commission spending reports yet, it is unclear what the final tally will be; however, at this stage it appears closer to 30 percent of the reported ad budget was spent online – mainly on search advertising for fundraising. ClickZ will have a final tally and approximate percentage of budget when available.
Rick Santorum's campaign spent no money on online ads before last week's Wisconsin GOP primary, which turned out to be his last chance to prove himself as a viable contender. In fact, while the campaign spent around $1 million on ads all together online, it may have been better characterized by the Super PAC ads attacking him there.
Super PACs like pro-Mitt Romney group Restore Our Future dropped nearly that same amount online in key primary states as Santorum surged in the polls. In fact, the pro-Romney group spent around $800,000 on web ads in to attack the former Pennsylvania senator in Alabama, Illinois, Michigan, Mississippi, Oklahoma, Ohio, and Tennessee, and Wisconsin.
The Democratic Governors Association and NARAL Pro-Choice America also chipped in a few thousand bucks to slam the conservative Republican online.
The Santorum camp did run web ads, though. Ads on Facebook were targeted geographically to voters, display ads ran in ad networks for fundraising, and splashy ads were placed on local sites in primary states to help get out the vote. The campaign also geo-targeted Facebook posts to people in specific primary states, so as not to bother people outside voting states about going to the polls. All in all, digital ad spending was minimal though – only around 5 percent or less of the total ad budget, according to sources familiar with the campaign. [Please see update above.]
Santorum also partook in what's become a trend this election season – hawking campaign tchotchkes and apparel in exchange for donations. In Santorum's case, the fundraising gimmick came in the form of sweater vests, logo-emblazoned versions of his signature bare armed uniform.
"Perfect for demonstrating solidarity with true conservatives, this vest is a great way to show your support for Rick," read the Santorum website. "It's 100% cotton, made in the USA, comes in grey, and is yours for your contribution of $100 or more. Don't let sleeves slow you down – donate today!"
The 2012 election has also been a big one for produced web videos, and other GOP primary campaigns including Romney's and Tim Pawlenty's nearly-forgotten campaign have excelled at cranking out quality videos. The Santorum camp, on the other hand, wasn't exactly known for many popular web videos. He did have some web hits, though – namely the Rombo ad in which a machine gun wielding Romney attacks Santorum. One of the most watched Santorum related videos didn't come from the campaign at all; it was a pop-song homage featuring the teenage female stylings of First Love crooning lyrics like "We've got a man who understands that god gave the bill of rights."
The Rombo arsenal included Restore Our Future ads for RickFacts.com, a site that promised to expose the truth about Santorum's record in the Senate. The site – which now redirects to RestoreOurFuture.com – featured TV ads from the group that had been running in Michigan and Arizona heading into the GOP primaries in those states, as well as spots seen in other primary states.
Ron Paul's campaign also went on the attack early on, running web ads calling Santorum a "Serial Hypocrite" in the hopes of siphoning New Hampshire primary votes away from him.
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- Report: #369883
Report - Rebuttal - Arbitrate
Complaint Review: Michael Matthews
Michael Matthews100 Ashley Forest Dr. Fayetteville, Georgia U.S.A.
Michael Matthews AKA Mike Sat on his a*s while I supported him, left me with numerous bills and bad checks Fayetteville Georgia
*Author of original report: I am a raving idiot
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Kodak, Tennessee
This report was posted on Ripoff Report on 09/04/2008 06:24 PM and is a permanent record located here: http://www.ripoffreport.com/r/Michael-Matthews/Fayetteville-Georgia-30214/Michael-Matthews-AKA-Mike-Sat-on-his-ass-while-I-supported-him-left-me-with-numerous-bill-369883. The posting time indicated is Arizona local time. Arizona does not observe daylight savings so the post time may be Mountain or Pacific depending on the time of year.
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Wow- I'm amazed at all the posts on here- about people having Dr. appts. and ultrasounds so early....I don't even have my OB intake with the nurse until I'm like 7 weeks- then I don't see my Dr. until I'm 9 1/2 weeks. I love my Dr. to death- he has delivered all my babies- but I want to stomp my feet and pout like a baby- I want to see my sweet little one on an ultrasound now!!!!! BOO-HOO! =)
Is there anyone else out there that has to wait like me??


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We are proud to be the only locally owned computer retail business in Sooke. As such, it is our goal to be a vital part of our community participating in communMore
$1 mil. - $5 mil.in Revenue
5 - 10EmployeesContact people at this company
2B-6686 Sooke Road PO Box 79SookeBritish ColumbiaV9Z 0E4Canadaview map
(778) 425-1994(778) 425-1993Fax
Enterprise_Iteration-NT.1579[03] SEIDXWK-35


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Arsenal Message Board
another year of miserable AFC *unts
another year of Manc clubs & the Chavs outspending AFC... like normal.
& the only chance the club has to compete is the will & the smarts of the manager. The Board many yrs ago bought into his style & vision. They are happy that AW keeps top 4 with a 'chance' of winning otherwise he wouldn't get paid in the top ten of all world football managers.
Truth be told AW wants to win like he did in 2004 or not at all. Players would have left AFC even if they won the PL 2 or 3 yrs ago. RVP has got his retirement fund & Cesc was completing his dream... Nasri was just a ****. (Na na na na na na na)
Why 'o why dont the miserable 'regulars' (chokes) just go support the Spuds!?!!?Sort: Newest | Oldest | Most Replied Expand all replies
Eric Cantona Eric Cantona Aug 20, 2012 12:20 Flag
Arsenal has, so far, spent more than City and about the same as United.
- 1 Reply to Eric Cantona
thank you for your insight you jumped up small minded a .nal idiot.
go & add up the top teams wage bills & prove AFC spend more... pri ck!!!


text:
Jeremy RiveraShared publicly -
Howdy, I'm Jeremy Rivera. I specialize is SEO, PPC & Badassery. The majority of my awesomeness centers around content writing & how people can harness the power of their website content for success. Ask me how your site can be more rad.
I currently live in Nashvile, Tn with my tough-as-nails wife and curious little monkey (daughter). I speak a lot of languages conversationally and hope to upgrade that to fluently one of these days.
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Purpose: To help children battling cancer build resilience through experiential learning & mentorship with a Navy SEAL
Our Mission
The One Summit mission is to help children with cancer build courage and self-confidence, which promotes a foundation for resilience as they battle their disease. One Summit teams children with a U.S. Navy SEAL mentor for a day of indoor rock climbing activities. This event and the sustained relationships that are formed, will give the children the strength and support they can rely upon as they undergo one of life's greatest challenges – battling cancer.


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Here's an update on Irving's Code Enforcement
Irving announces its Code Enforcement Department has achieved positive year-end results.
Performance measures are results of specific actions that are tied to the city's Strategic Plan. Some of the results for 2013-14 are as follows:
–Multifamily obtained a 55.5 percent reduction of Risk Level 3 properties and improved the risk rating of 46 properties overall
–Property code voluntary compliance remained steady at 97 percent
–Average case duration – 16.4 days (down from 28.9 days five years ago)
–Corridors proactive inspections equaled 88 percent
Teresa Adrian is the Code Enforcement director. The complaint hotline is 972-721-4829 or 972-721-4949.


text:
- Report: #917282
Report - Rebuttal - Arbitrate
Complaint Review: Portfolio Recovery Associates, LLC
Portfolio Recovery Associates, LLCP.O. Box 12914 Norfolk, Missouri United States of America
Portfolio Recovery Associates, LLC Received via mail a false claim collection letter for amount of $9,871.72! Perfect credit history~not on Credit Report. Norfolk, Missouri
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I have excellent credit and no Write Offs and/or late payments reflecting on my Credit Report.
Emailed Portfolio requesting to dispute and to cease & desist collection efforts because this is a false claim.
Requested proof to show debt is a ligitimate outstanding debt as it does not reflect on Credit Report which I request on an annual basis.
Lebanon, CT
This report was posted on Ripoff Report on 07/25/2012 11:46 AM and is a permanent record located here: http://www.ripoffreport.com/r/Portfolio-Recovery-Associates-LLC/Norfolk-Missouri-23541/Portfolio-Recovery-Associates-LLC-Received-via-mail-a-false-claim-collection-letter-for-917282. The posting time indicated is Arizona local time. Arizona does not observe daylight savings so the post time may be Mountain or Pacific depending on the time of year.
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I don't know much php code and styling but I do things correct by finding answer on google.
I have a website which have white background I want to change it to light green.
In admin > editor, I can only see style.css. No default or any other .css file.
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- Report: #919595
Report - Rebuttal - Arbitrate
Complaint Review: Olshan Foundation Repair Co.
Olshan Foundation Repair Co.3913 Flowers Road Atlanta, Georgia United States of America
Olshan Foundation Repair Co. Installed 10 piers which would not correct anything and did it in a comletely shoddy manner and in violation of county building code Atlanta, Georgia
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When the men came to do the work, they installed the 10 piers and were ready to leave when I told them they still needed to level the floors inside. They did not know that they were supposed to do that. After making several calls, a few additional men came and they worked long and hard at leveling the floors. Knowing nothing about what was required to correct the problem I thought the work was complete. I even wrote the office a nice letter of appreciation.
Almost immediately, we heard strange noises coming from the crawlspace but had no idea what it was. About 15 months later I called Olshan and asked if they could come correct the problem and find out about the strange sounds. They said they would come out but, since the one year warrantee was up, any work would cost $75 per pier, per agreement. They came out and said all 10 piers had failed and needed to be corrected. I decided not to have them do the work since none of the initial work corrected the problem.
I have been looking for another reputable company to correct Olshan's work since then and just found 3 companies: AquaGuard Basement Systems out of Marietta, GA, Craigs Remodeling and Repair of Watkinsville, GA, and our son's pastor who was a home builder for many years and still does a few jobs on the side. All three contractors said the work performed by Olshan was totally shoddy, would never correct the problem, was not in compliance with county code, which I have since verified, and needed to be removed before the problem could be corrected properly. The estimates were from $5000 to $19000.
I have called the Knoxville office thinking it was Olshan's home office but they simply called the Atlanta office who called me to find out what my problem was. I told them and they let me know that they had been combined with the Birmingham office and would get back to me. They have never called again. I called the Texas home office and the man in charge of problems such as mine said to email him the pictures taken showing the shoddy work and he would call me right back with an honest opinion as to what could be done. He never has returned my call so I emailed him again in June and have never had a response. That tells me no one at Olshan at any level cares that their local offices are doing a shoddy job, making false claims as to warranty, and hoping the inocent public never hears about it. That is the reason for this complaint being filed. I have also filed a complaint with the BBB.
I have had the work done by our son's pastor for $5000 and am totally convinced we will not have future problems. I want to warn the public to beware of Olshan Foundation Co. of Atlanta, GA. The work probably won't be done correctly, and if it isn't, don't espect anyone up the line to care. They are a total ripoff.
This report was posted on Ripoff Report on 07/30/2012 09:12 AM and is a permanent record located here: http://www.ripoffreport.com/r/Olshan-Foundation-Repair-Co/Atlanta-Georgia-30360/Olshan-Foundation-Repair-Co-Installed-10-piers-which-would-not-correct-anything-and-did-919595. The posting time indicated is Arizona local time. Arizona does not observe daylight savings so the post time may be Mountain or Pacific depending on the time of year.
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Resica Elementary School welcomed the community to a "historical" celebration of the arts created and performed by the students of Resica Elementary School on May 10. This school year children learned about different periods in art history and the artists who created some of the world's most famous and compelling works of art. Each wing of the building featured a different period from art history, including ancient art, medieval art, Renaissance, Impressionism/Expressionism and modern art sections/wings of the school.
Each wing had an art historical craft for children to create. A new addition to the Art Celebration was the fifth-grade Living Artist Exhibition. There were a variety of musical performances by students and members of our community. The event also featured demonstrations of art techniques and artwork by local artists.
Location, ST | website.com


text:
House of Mirrors
- Posted by Ivanhoff
- on May 1st, 2012
There is a saying that the market reflects the price of everything and the value of nothing. Wall Street is such a house of mirrors. There are very few original thinkers. If you have a good track record (read you were right at least once big time) and you sound and act confident, not only no one is going to question you, but also you are likely to have tremendous impact on the market.
Are there way too many "second level" thinkers in this market, who prefer to take the short cuts and let's say look only at charts and follow established names? Everyone is taking the path of least resistance, not only because it takes less efforts, but because it has worked most of the time. Who is left to do the real homework? I am certainly guilty of charge.
I am sure that even David Einhorn was pleasantly surprised by the reaction his comments caused during Herbal Life's conference call. Here is what one of the StockTwits's users rightfully pointed out earlier today:
ronbo811: $HLF stock went from $6 in 2009 to $73 and today everyone just realized the comp is a scam after a couple questions at a meeting?…Really? May. 1 at 11:18 AM
He makes a really good point. Benjamin Graham liked to say that "Price is what you pay. Value is what you get". The reality is that value is what you think you get. Price is what the market is willing to pay for it. Value could be very subjective, even in the stock market. What is worth zero to you, is worth $1 billion to Facebook, for example.
And another comment:
KidDynamiteBlog: $HLF funny thing is that if I hadn't come to the conclusion that I was wrong I would have bought even more stock and made a killing! May. 1 at 1:07 PM
Everything looks so clear and easy in hindsight, but it is never so in real time.
The market has become so short-sighted, impulsive and reflective. Or maybe it has always been like that.
Prices change when expectations change and the latter change under the influence of outside factors. In short-term perspective, price could go anywhere and the major catalyst that impacts expectations is price action itself.
Disclosure: I traded $HLF during the day. I didn't mention it on my StockTwits stream, because it was a short-term trade that was hard to follow.
The information in this blog post represents my own opinions and does not contain a recommendation for any particular security or investment. I or my affiliates may hold positions or other interests in securities mentioned in the Blog, please see my Disclaimer page for my full disclaimer.blog comments powered by Disqus
My name is Ivaylo Ivanov (@ivanhoff). I am Founder of MarketWisdom.com - 14-day Free Trial to Swing Trades, Education & Mentoring. Author of The 5 Secrets To Highly Profitable Swing Trading, The Next Apple and CRASH (More)
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Miami's Pérez Art Museum Appoints Three New Deputy Directors
Museum of Contemporary Art San Diego Cutting Jobs and Closing Main Building Due to Expansion
Court Rules That Nazi-Looted Works in the Norton Simon Museum's Collection Stay with the Museum
After Unveiling $56 Million Renovation, Speed Art Museum Lays Off Seven Employees
Defendant Pleads Guilty in First Cultural Destruction Trial at The Hague
J. Michael Bewley Donates Twelve Works to the San Jose Museum of Art
Robin Pogrebin of the New York Times states that the Dallas Museum of Art will be receiving a gift of funding as well as art—in the form of 138 works—from the estate of collector and benefactor Dorace Fichtenbaum, who died in 2015 on July 11.
The pieces, mostly works on paper, are from a range of artists—Yayoi Kusama, Otto Dix, Jasper Johns, Eva Hesse, and Jean Dubuffet, among others—in addition to various African and Native American works of art. The museum's senior curator of European and American art, Olivier Meslay, who is in charge of handling the bequest, said "For us it was a sudden wealth…a changing gift."
In anticipation of the twentieth anniversary of its founding, Pavel Zoubok Gallery has announced that it will soon join forces with George Adams Gallery by relocating to a shared space on the first floor of Pavel Zoubok's current location at 531 West 26th Street and adopting a "more flexible, collegial and intimate" gallery model.
"In bringing together our two distinct but congenial sensibilities, and our respective expertise, George and I look forward to redefining the role of the gallery as a dynamic venue for the presentation of contemporary and historical works of art," Pavel Zoubok said in a statement. The two galleries will continue to work independently, but also in partnership, to acquire works and organize exhibitions as well as to launch a new series of monthly salon evenings that will feature artists, writers, and curators.
Established in 1997, Paul Zoubok Gallery began as a parttime public gallery located in a loft in SoHo before it moved to Madison Avenue and then settled into its current home in Chelsea. George Adams Gallery grew from the Frumkin/Adams Gallery which was founded in 1988. After Adams's partner, Allan Frumkin, retired in 1995 it was renamed.
Steve McQueen, the 1999 Turner Prize recipient and director of the Oscar-winning film 12 Years a Slave (2013), has been named the winner of this year's British Film Institute Fellowship. He is the youngest director to receive the Institute's highest accolade.
"I first walked into the BFI library and cinema twenty-eight years ago," McQueen said. "To think that I will now be a fellow and honorary member, with such a distinguished list of people, is mind-blowing. I'm humbly honored."
Josh Berger, chair of the institute, said, "As winner of both the Turner Prize and an Academy Award, Steve is pre-eminent in the world of film and the moving image. He is one of the most influential and important British artists of the past twenty-five years and his work, both short and longform, has consistently explored the endurance of humanity—even when it is confronted by inhumane cruelty—with a poetry and visual style that he has made his own."
McQueen has directed a range of award-winning features, including Hunger (2008), which won the Camera d'Or at the Cannes Film Festival; Shame (2011), which won two best film awards when it premiered at the Venice Film Festival; and 12 Years a Slave (2013), which took home the Oscar for best picture.
Born in London in 1969, the video artist has exhibited works at the Art Institute of Chicago, the Musee d'Art Moderne de la Ville de Paris, MoMA, and Documenta X and XI. McQueen received an ICA Futures Award in 1999, a DAAD artist's scholarship to Berlin and the Turner Prize in 1999, and was selected to represent Britain in the Venice Biennale in 2009.
Previous fellows include Cate Blanchett, Stephen Frears, Christopher Lee, Tim Burton, and Hugh Grant.
Hannah McGivern of the Art Newspaper writes that the Basilica of San Francesco in Assisi has been declared safe after an earthquake that registered at a little over six on the Richter scale struck central Italy. The thirteenth-century basilica, filled with frescoes by Giotto, Cimabue, Simone Martini, and Pietro Lorenzetti, was damaged in an earthquake back in 1997.
The Comando Carabinieri Tutela Patrimonio Culturale, Italy's art and antiquities police force, are looking over a number of cultural heritage sites throughout the Marche, Umbria, and Lazio regions. Officers will secure the sites against looting, and store any artworks that might be at risk. The culture ministry's crisis unit will meet on August 25 to decide what courses of action must be taken to further secure other artworks and cultural heritage sites.
Thus far, sixty-three deaths have been recorded, says CNN. The most violent tremor, also the first, occurred near the town of Accumoli at 3:36 AM, followed by two more shocks. Accumoli and Amatrice, a mountain village about eight miles south of Accumoli, were hit the worst. The mayor of Amatrice said "Half the town no longer exists," according to a report in the New York Times. Getting help to Amatrice is difficult because of damages done to a bridge and numerous roads. Many are digging through the rubble with their bare hands to help, trying to reach trapped people. A courtyard in the back of a palazzo in the town has been turned into a temporary morgue. Andrea Gentili, a civil protection worker, said to the Associated Press, "We need chain saws, shears to cut iron bars, and jacks to remove beams. Everything, we need everything."
The Tehran Museum of Contemporary Art is working to digitize all of the works in its collection, including Pablo Picasso's Artist and His Model, Andy Warhol's Suicide, and Jackson Pollock's Mural on Indian Red Ground, in order to feature them on its website, Zahra Alipour of |www.al-monitor.com/pulse/originals/2016/08/tehran-museum-of-contemporary-art-tmoca-website-vault.html|Al-Monitor| reports. The museum will not organize any permanent displays from its collection until the project is finished due to a lack of space as well as security concerns.
In 2015, the culture ministry confirmed that twenty-seven artworks were stolen from the museum. After the works were successfully recovered they were put on display at a gallery in Tehran to assure the public of their safe return.
Speaking of the museum's heightened security, Amir Rad, director of the new media center, said, "The museum vault is like a large box that is very safe. The bureaucracy seen in everyday dealings in Iran is even more intense at the museum. Removing or bringing in any work of art from the museum requires several rounds of communication and numerous permits. I think the vault is an untouched treasury."
The museum's digital project will allow the institution to exhibit virtual versions of artworks as an additional security measure. "The plan is to eventually upload all the pieces onto the website along with up-to-date information," Rad said. "We are also thinking of offering special services to researchers and curators. As of now, sixty art pieces by foreign painters have been uploaded to the website."
The institution is currently holding discussions with the German government and plans to send sixty works to Berlin for an exhibition to be held this winter.
Roy Lichtenstein, Figures with Sunset, 1978 on display at SF MoMA is one of the works included in the loan of the Fisher Collection. Photo: Santiago Mejia
In 2009, when SF MoMA announced that it would be housing the Fisher Collection, more than one thousand contemporary artworks amassed by Gap founders Donald and Doris Fisher, the museum said that it was entering into a "groundbreaking partnership."
This "pioneering partnership" with the Fishers has raised questions regarding the level of influence private collectors exercise over public institutions. After investigating the stipulations of the deal, Charles Desmarais of San Francisco Chronicle reports that the museum has agreed to display no more than 25 percent of works from other lenders or donors in the Doris and Donald Fisher Collection Galleries on the fourth, fifth, and sixth floors. This means that the museum has to display the collectors' works in about 60 percent of SF MoMA's indoor galleries for the duration of the loan, which ends in May 2116, but can be extended in twenty-five-years increments.
While naming galleries after donors and exhibiting collections that were gifted or loaned to institutions are not unprecedented practices, many museums try to maintain transparency about conditions behind the exhibition of works. The stipulation the Fisher Foundation made with the museum means curators will need to include the Fishers' works in a variety of shows.
Some of the artworks in SF MoMA's Fisher Collection belong to the Fisher Foundation while others still belong to Doris Fisher. The museum has agreed to return the works that belong to Doris Fisher at her request. Of the works on display from the Fisher Collection, 260 belong to the Fisher Foundation, which means they aren't available for private use for the duration of the loan. The museum confirmed to San Francisco Chronicle that only five of the works exhibited will be returned to Doris Fisher. SF MoMA stated that the artworks "are being transferred at the Fishers' discretion, in due course, over time, from the private collection to the foundation collection"; however, it did not clarify how many of the roughly 835 other works still belong to Doris.
Donald Fisher originally approached director Neal Benezra about funding a Fisher wing at the museum in 2005, but Benezra declined his offer. "I thought about it a lot," Benezra said. "What Don was offering was, on the one hand, extremely generous… but Don wanted something that I felt we couldn't offer him... a kind of curatorial control over what got shown. I felt that, as generous as this offer was, our integrity would be at risk because the museum really needs to control, from a curatorial point of view, if nothing else, how art is presented in our building." The executive committee of SF MoMA's board of trustees agreed with Benezra's decision.
After Fisher renewed discussions with SF MoMA in 2009 regarding a home for his collection, the partnership was formed and plans were launched for the museum's new Snøhetta-designed expansion, which opened to the public on May 14.
Young Italians and legal residents turning eighteen years old in 2016 will each receive a "culture bonus" of roughly $560 from the federal government to spend on "cultural products and events." The initiative will kick off on September 15, 2016 and run through December 31, 2017, El Mundo reports.
The total allocation, for which approximately 550,000 eighteen-year olds will be eligible, will cost an estimated $330 million in public funds. To receive the bonus, those born in 1998 must register on the website www.18app.it and download the "18app" app on their mobile phone. The money can be spent on books, theater, concerts, exhibitions, and museums, but not on the purchase of recorded music. This was immediately denounced by Enzo Mazza, president of the Italian Music Industry Federation, who said that the cultural bonus discriminates against the recording industry.
In an article published by the Corriere della Sera, government undersecretary Tommaso Nannicini stated that 18app sends a clear signal: "The message is that our community embraces your adulthood and reminds you of the importance of cultural consumption; not only for your personal enrichment but also to strengthen the country's social fabric."
Nannicini further emphasized that this cultural bonus "for once" will allow funds to promote culture and will not be "allocated through bureaucracy" but by the youths' own decisions.
According to The Telegraph, prime minister Matteo Renzi announced the initiative last November, ten days after the terrorist attacks in Paris. After he declared the government would increase funding for security by one billion euros he decided to match that sum for euros spent on culture. "We will not give in to terror," Renzi said. "We have centuries of history that proclaim the fact that culture will beat ignorance, that beauty is more tenacious than barbarism."
After seven days of testimony in a Chicago courtroom, the federal judge presiding over the unusual authentication case––in which a former corrections officer sued artist Peter Doig for denying that he painted an artwork––ruled that Doig could not have authored the work.
Canadian Robert Fletcher was seeking nearly $8 million in damages after Doig said he did not produce an untitled desert landscape painting that Fletcher owned. The denial ruined Fletcher's plans to sell the work for millions, since Doig's canvases regularly raise more than $10 million at auction. Fletcher decided to sell the painting after a friend, who saw it hanging in his home five years ago, informed him that it was the work of a famous artist. Fletcher had consulted a Chicago dealer named Peter Bartlow to help him find a buyer.
Complicating the case was Fletcher's claim that he met Doig in the 1970s while the artist was serving time in a correctional facility in Ontario for LSD possession. Fletcher said that he had paid Doig $100 for the work, which is signed "Pete Doige 76." According to the Scottish-born artist, this was impossible since he has never been incarcerated.
After some investigating, Doig and his legal team realized there was a man who served time in Thunder Bay Correctional Center whose last name was similar. They argued that Pete Doige, a carpenter who died in 2012, was the actual artist of the work. Marilyn Doige Bovard, Doige's sister, testified that her brother had created the disputed painting and identified the signature on the back as his.
Despite Bovard's testimony, Fletcher still remains convinced that Doig made the work. According to the former corrections officer, the empty desert scene is clearly one of Doig's trademark landscapes. Judge Gary Feinerman declared that any similarities between the two works is "purely coincidental."
After the trial ended, Doig said, "Today's verdict is the long overdue vindication of what I have said from the beginning four years ago: a young talented artist named Pete Edward Doige painted this work, I did not. That the plaintiffs in this case have shamelessly tried to deny another artist his legacy for money is despicable. The deceased artist's family and my family and friends have suffered mightily. Thankfully, justice prevailed, but it was way too long in coming. That a living artist has to defend the authorship of his own work should never have come to pass."
Fletcher and his attorney, William Zieske, have not yet decided whether they will appeal the court's decision.
ArtCenter/South Florida has announced that Natalia Zuluaga has been appointed artistic director. She will collaborate with the executive director to oversee programming, artist residencies, and community outreach events.
"ArtCenter is at a pivotal crossroads, exploring new paradigms for the visual arts community in Miami and Natalia has already proven to be the perfect choice to help steer our new journey," executive director Maria del Valle said.
Zuluaga currently runs [NAME] Publications. She has curated exhibitions and organized public programs at the Judd Foundation, the Hessel Museum, and CAM-Releigh. From 2007 to 2012, she worked for the Cisneros Fontanals Art Foundation, managing its exhibition and publishing initiatives. Zuluaga earned her MFA in visual arts from Florida International University and her MA in curatorial studies from Bard College.
On Facebook, the curator Defne Ayas announced her withdrawal from the first Antarctic Biennale. She walked away from the project because she claims a number of key decisions were not approved by her, including its overall framing, the text for the announcement, and the biennial's age limit (the show's open call states that they're looking for "adventurous artists under thirty-five").
Nadim Samman, another curator for the exhibition, says that "the Antarctic Pavilion is a long-term project, whose uncertain status vis-a-vis the Venice Biennale's nationally overdetermined structure is a provocation: A quasi-institutional claim to represent a transnational sphere, out of line with the festival's politics of territorial representation. It points to Antarctica as a Giardini of sorts, in which the sovereignty-obsessed cultural ambitions relevant two centuries ago still seem to hold sway—and proposes alternative futures."
The biennial was started by the artist Alexander Ponomarev, who has a background in nautical engineering and has done a number of projects in Antarctica.


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- Report: #219068
Report - Rebuttal - Arbitrate
Complaint Review: Netzero
Netzeronetzero.net Internet U.S.A.
Netzero Draws from account after membership cancelled Ripoff Internet
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Even though I had cancelled in April and received a confirmation e-mail, I still had to contact them in September 2006 to see why money was still being drawn. They said they would refund my money, and they did.
Months later, in November 2006, my account was drawn from again by Netzero. So I had to call them again, give them all my information again and explain the problem AGAIN.
It turns out my account was never shut down, regardless of my attempts to cancel, in April, again in September, and again in November.
I would not recommend Netzero to anyone after all the trouble and inconvenience this has caused me. If you give them your credit card number they will continue to try to take your money, even if you cancelled your account with them six months ago.
Corsicana, Texas
This report was posted on Ripoff Report on 11/04/2006 08:30 AM and is a permanent record located here: http://www.ripoffreport.com/r/Netzero/internet/Netzero-Draws-from-account-after-membership-cancelled-Ripoff-Internet-219068. The posting time indicated is Arizona local time. Arizona does not observe daylight savings so the post time may be Mountain or Pacific depending on the time of year.
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Index of content:
Volume 106, Issue 20, 22 May 1997
Time domain modeling of spectral collapse in high density molecular gases106(1997); http://dx.doi.org/10.1063/1.473893View Description Hide Description
In many cases, the widely used matrix inversion approach to describe the spectral interference in collisionally perturbed molecular spectra is not feasible if the particular molecular interactions do not allow the sudden impact approximation (infinitely short collision duration). To overcome this problem, we present a time domain model that describes collisional broadening and narrowing phenomena without requiring the sudden approximation. The key element of the model is a Monte Carlo type sampling process to quantify the temporal autocorrelation of the molecular dipole moment. The spectrum is then obtained numerically via fast Fourier transform. The model does not require a frequency-dependent relaxation operator; the finite collision duration is simply an adjustable parameter in the time domain process. Our approach, which is generally applicable to any set of transition lines, is derived from concepts of both conventional quantum-mechanical and semiclassical theory of line interference. Coherent transfer effects from rotationally inelastic collisions are described as randomly occurring events which affect frequency, amplitude, and phase of the sampled oscillation. Effects of vibrational dephasing are included as well. To demonstrate its feasibility, we apply the model here to the 2.7 μ absorptionspectrum of carbon dioxide diluted in high density air ( ). The successful modeling of the experimental data, especially the full collapse of and branches at ultrahigh densities, accounts for interbranch mixing and for incoherent effects. The calculations make extensive use of the new Hitran (HITEMP) molecular database. Results include revised estimates for the collision duration of with nitrogen and oxygen at room temperature.
Compositional control of rovibrational wave packets in the "shelf" state of via quantum-state-resolved intermediate state selection106(1997); http://dx.doi.org/10.1063/1.473894View Description Hide Description
Compositional control in the preparation of rovibrational wave packets is demonstrated in the state of gas-phase molecules using ultrafast pump–probe laser spectroscopy combined with quantum-state-resolved intermediate state selection. The intermediate state, from which subsequent ultrafast excitation occurs, is a stationary rovibrational level in the state of produced by cw laser excitation from the ground state. The effect that the intermediate state has on the final composition of the wave packet is investigated by comparing the transients resulting from ultrafast pump–probe excitation of two different intermediate states ( versus ). In these experiments the pump wavelength is compensated so that in each case the same -state eigenstates ( ) make up the wave packet, but with different amplitudes. Theory predicts, and experiments confirm, that the relative amplitudes of the rovibrational eigenstates are strongly dependent upon the intermediate state and determine the spatial and temporal evolution of the wave packet. Evidence for this includes differences in the observed pump–probe transients and dramatically different amplitudes of the beat frequencies in the Fourier analysis of the time-domain transients. Theoretical three-dimensional wave packet simulations highlight how the composition of the wave packet is used to vary its spatial and temporal evolution.
Inhomogeneous and single molecule line broadening of terrylene in a series of crystalline -alkanes106(1997); http://dx.doi.org/10.1063/1.473895View Description Hide Description
We present a study of single molecule linewidth broadening of terrylene in dodecane, tetradecane, and hexadecane matrices. The Shpolskii bulk absorption spectra exhibit increase of the bandwidths and site complexity with increasing -alkane chain length. Single molecule lines are broadened above the lifetime limit even at 1.6 K in all three solvents. The linewidth distributions suggest the existence of relaxing two-level systems coupled to the molecular transitions. Spectral diffusion was observed in the forms of spontaneous and photoinduced frequency jumps. Temperature dependencies of the single molecule linewidths show a wide range of power-law dependencies below 3 K and, in some cases, exponentially activated behavior above 3 K. Possible origins of the line broadening are discussed.
Electric field-gradient contributions to the chemical shifts of liquid water106(1997); http://dx.doi.org/10.1063/1.473896View Description Hide Description
Contributions to the gas-to-liquid chemical shifts of water arising from the electric field gradient of the surrounding molecules have been calculated as a function of the temperature. Since the theoreticalmodel is based on perturbation theory, this part of the chemical shift may be calculated from quadrupole shielding polarizabilities and statistical mechanical ensemble averages of external electric field-gradients. The contributions from the electric field gradients are found to be substantial and are calculated to −9.7 ppm for the oxygen shift and 0.7 ppm for the proton shift at room temperature.
Absorption, resonance Raman, and Raman excitation spectra of hafnium trimers106(1997); http://dx.doi.org/10.1063/1.474083View Description Hide Description
We report on the optical, resonance Raman, and excitation profile spectra of mass selected hafnium trimers in argon matrices at 14 K. The absorptionspectrum consists of four overlapping transitions in the range 605–620 nm. The Raman spectrum is too complex to be attributed to a single ground state. We may explain the observed spectrum by assuming five low-lying excited states and at 319.0, 413.4, 609.6, 642.8 (weak), and respectively. The ground state shows complex structure which may be interpreted as the result of a strong, but linear Jahn–Teller effect. Evidence is obtained for two pseudo-rotational progressions having states of vibronic angular momentum of based upon normal frequencies of 142.8 and This indicates a fluxional ground state with symmetry in the limit. No such effects are apparent in the low-lying excited states, although modes of are observed and in some cases geometrical information may be inferred. The state is geometrically an equilateral triangle ( symmetry). The state shows an vibration, but without an observed nontotally symmetric mode no geometrical information can be obtained. The state shows only a nontotally symmetric mode at while the state and the state both appear to have symmetry. Raman excitation profiles appear as several distinct types and correlate well with the four absorption bands at 606, 610, 615, and 619 nm.
Dibromine monoxide, The rotational spectrum and molecular properties106(1997); http://dx.doi.org/10.1063/1.473920View Description Hide Description
The rotational spectra of and in their ground vibrational states as well as in its state have been studied in selected regions between 90 and 523 GHz. Transitions involving a large range of quantum numbers, and have been observed permitting precise rotational and a large set of centrifugal distortion constants to be determined. All isotopic species as well as the excited state data were fit simultaneously. Ground-state effective and average structural parameters as well as an estimate of the equilibrium structure have been derived. The quartic distortion constants were used for a calculation of the harmonic force field. The complete quadrupoletensor has been determined. Its diagonalization reveals a largely covalent BrO bond with little -bonding. The derived properties of are compared with those of related compounds such as HOBr, and HOCl.
Electronic excitation transfer in Lennard-Jones fluid: Comparison between approaches based on molecular dynamics simulation and the many-body Smoluchowski equation106(1997); http://dx.doi.org/10.1063/1.473897View Description Hide Description
Molecular dynamics simulations were performed to study the kinetics of long-range irreversible/reversible electronic excitation transfer in a Lennard-Jones fluid where the translationaly mobile choromophores are thought to be embedded. The simulations are based on the Förster master rate equation approach which can be rederived from a stochastic Liouville formalism for excitation transfer between two identical chromophores in the weak dipole–dipole coupling regime. For energy transfer between two dissimilar partners, rate equations utilized are obtained from the first principle. The simulated kinetic results in this regime are then compared with the reaction-diffusion theoretical framework for excitation transfer. The theory is based on a many-body Smoluchowski equation for the reactant molecule reduced distribution function and makes use of a superposition approximation to truncate the hierarchy of equations. The comparison of the results show the scope and utility of the theoretical approach in the high friction limit when it is solved for the absorbing boundary condition at contact. In the low friction limit, like collisional quenching, the present reaction-diffusion formalism is found to perform poorly. When the stochastic Liouville equation in the strong dipolar coupling regime is solved combined with the molecular dynamics trajectories, the time dependent reaction probability of the donor shows oscillatory behavior and the diffusion coefficient of the medium has been found to have but little effect on this.
Vibrational spectra of hexa-atomic silicon-carbon clusters. I. Linear106(1997); http://dx.doi.org/10.1063/1.473898View Description Hide Description
Fourier transform infrared measurements on the spectra of the products of the evaporation of silicon/carbon mixtures trapped in Ar at ∼10 K, combined with the results of ab initio calculations published earlier, and density functional theory(DFT) calculations carried out in the present work, have resulted in the detection for the first time of the linear cluster. Two vibrational fundamentals have been assigned, the stretching mode and the Si–C stretching mode The observed frequencies, relative intensities, and isotopic shifts are in very good agreement with the results of the DFT calculations and confirm the previously predicted, linear symmetric geometry for the ground state of
Wavelength and intensity-dependent transient degenerate four-wave mixing in pseudoisocyanine J-aggregates106(1997); http://dx.doi.org/10.1063/1.473899View Description Hide Description
The results of transient degenerate four-wave mixing(DFWM) and "pump-probe" spectroscopy in aggregates of 1,-diethyl-2,2-cyanine (pseudoisocyanine, PIC) chloride at 300 K are reported. Spectral dispersion of DFWM efficiency within the -band and near exciton resonance has been measured. Time response of both transient absorption changes and DFWM signal is found to be strongly dependent on pump photon fluence and wavelength. This behavior is qualitatively explained within a physical model of nonlinear optical dynamics in aggregate domains which accounts for exciton annihilation, and the effect of nonthermal phonons produced as a result of decay of two-exciton states. Intensity-dependent evolution of excess dynamic disorder due to nonthermal phonons manifests itself in pump-probe experiments as dispersion-type differential spectrum appearing at high pump intensity. The third-order nonlinear susceptibility of PIC aggregates has been calculated supposing highest density packing. The nonlinear figure of merit of aggregates was evaluated which is intensity dependent due to exciton annihilation and associated subsequent processes.
Absolute HCO concentration measurements in methane/air flame using intracavity laser spectroscopy106(1997); http://dx.doi.org/10.1063/1.473900View Description Hide Description
Intracavity laser absorption spectroscopy was used to measure the absorption spectra of a premixed, flat methane/air flame at a total pressure of 30 Torr. The spectra were measured in the spectral range of A flat flame burner was placed inside the cavity of a broadband dye laser pumped by a cw argon-ion laser. The spectrum of the laser output was measured by a high resolution spectrograph (with a spectral resolution of 0.003 nm). The spectrum of HCO radicals transition) was measured with a high signal-to-noise ratio at different positions above the burner, providing the first quantitative measurement of the absolute concentrations of the HCO radical in flames. The linewidths of the individual rotational lines in the spectrum can be closely fitted by the equation where and The rotational temperature of the HCO radicals was evaluated from the spectra, but the error and the data scatter are relatively high since the lines with a high rotational quantum number are strongly superimposed with lines from different branches. The "hot band," which can be assigned to the transition (0,0,1)–(0,9,1), was observed in spectra measured at high temperature. The value is evaluated from the position of this "hot band." The concentration profile of the HCO radical has a maximum value of about which is in reasonable agreement with computer simulation results, when the uncertainties of the absorption cross section and of the rate constants for HCO reactions are taken into account. The relatively strong lines of the radical spectrum (the transition) were also recorded in the studied wavelength range. The spectra of these two radicals can be measured simultaneously which is advantageous in combustion diagnostics.
Doppler-free two-photon absorption spectroscopy of the transition of trans-glyoxal106(1997); http://dx.doi.org/10.1063/1.473922View Description Hide Description
Doppler-free two-photon absorptionspectra of the transition of trans-glyoxal have been measured by means of two-photon absorptionspectroscopy with counter-propagating light beams of identical photons within an external cavity. The relative energies of transition lines are measured with accuracy better than 0.0001 . Rotational lines are fully resolved, and 1809 lines of the transition are assigned for . Rotational constants of the and states are determined by a least-squares fitting of eigenvalues of the -reduced rotational Hamiltonian to energies of the assigned lines. Energy shifts, intensity anomalies, and line splittings are observed for several lines. When an external magnetic field is applied, remarkable changes are observed for these lines. They are identified as originating from perturbations between the and states, which become appreciable when perturbing levels are close in energy. Splittings into three lines are observed for strongly perturbed levels of , and these splittings are identified as the hyperfine splitting caused by mixing of the state.
Depolarized dynamic light scattering from three low molecular weight glass forming liquids: A test of the scattering mechanism106(1997); http://dx.doi.org/10.1063/1.474117View Description Hide Description
Depolarized dynamic light scattering (DDLS) experiments are performed on the glass forming materials ortho terphenyl (OTP), bis-methyl-methoxy-phenyl-cyclohexane (BMMPC), and bis-methyl-phenyl-cyclohexane (BMPC). Depolarized spectra are obtained for the bulk liquids and for solutions of varying concentration in Effective optical anisotropies of the molecules are obtained from the solution spectra. A detailed analysis of the DDLS spectra, as well as a comparison with the results of quasielastic neutron scattering (QENS) experiments, indicates that the DDLS spectra in the bulk liquids result from at least two physical mechanisms: (i) The low frequency part of the spectrum, in the frequency range of the α peak, arises mainly from the molecular reorientation mechanism. The integrated intensity of this contribution is proportional to the square of the effective molecular anisotropy. (ii) At higher frequencies (but still below the Boson peak), the predominant contribution to the DDLS spectrum arises from interaction-induced scattering. The intensity of this contribution increases with increasing temperature (decreasing density) in the way expected for the cancellation effect. The implications of these results for the comparison of DDLS and QENS experiments and for the comparison of the data to the predictions of mode coupling theories of glass forming liquids are discussed.
The rovibrational spectrum of hydroxylamine: A combined high resolution experimental and theoretical study106(1997); http://dx.doi.org/10.1063/1.473901View Description Hide Description
This paper reports the rovibrational spectrum of hydroxylamine recorded by interferometric Fourier transform spectroscopy with a resolution of up to close to the Doppler limit at room temperature, from up to the visible range of the spectrum. Detailed rotational analyses for 32 bands include all nine fundamentals and numerous overtones up to Approximate absolute band strengths, band centers and vibrational assignments are presented for a total of 72 bands up to the OH stretching overtone. The spectra are interpreted in terms of multidimensional vibrational calculations with potential and dipole surfaces constructed by multidimensional spline interpolation from more than ab initio points. The full three dimensional treatment of the torsion-inversion problem reveals well separated time scales for the two processes with a cis potential well supporting localized wave functions for the zero point and fundamental levels. Up to five dimensional normal coordinate models are employed for the analysis and dynamic interpretation of the complete vibrational spectrum up to Good quantitative agreement between observed spectra and results from ab initio calculations is obtained with a simple harmonic scaling procedure without any further empirical refinement. The comparison of various coupling schemes reveals an efficient path for the coupling between the OH and manifolds mediated through the OH bending mode. The implications for the effective homogeneous broadening at high energies are discussed.
Photon correlation spectroscopy of interacting and dissociating hemoglobin106(1997); http://dx.doi.org/10.1063/1.473892View Description Hide Description
Experimental and theoretical analysis of the effect of both intermolecular interactions and dissociation on the diffusionalproperties of carbon–monoxide bovine hemoglobin in solution are reported here. When performing accurate photoncorrelation spectroscopy measurements versus protein concentration, even on dilute solutions, one finds that the first cumulant diffusion coefficient of the macromolecule has a relevant dependence upon pH (5⩽pH⩽9.5), ionic strength (10–100 mM), and, particularly, on hemoglobin concentration mg/ml). The results cannot be interpreted by considering the occurrence of either proteindissociation or intermolecular interactions only. As a consequence a simple theoretical expansion of the first cumulant diffusion coefficient, to first order in concentration, is derived here with the inclusion of protein interactions and dissociation. A fit procedure based on this expression leads to a good description of the dissociation and an accurate estimate of the native protein charge and of its single particle diffusion coefficient in the full range of solution parameters.
Dipole and quadrupole plasmon resonances in large sodium clusters observed in scattered light106(1997); http://dx.doi.org/10.1063/1.473902View Description Hide Description
We study the dependence of the optical properties of clusters as a function of cluster size. The Mie theory is used to describe intensities of light scattered by growing clusters in directions orthogonal to the direction of the incident light beam. We assigned the maxima in scattered intensities to secondary fields due to plasmons excited in clusters with appropriate radius. The maxima in measured intensities of scattered light in "perpendicular" and "parallel" polarization geometry are attributed to excitation of dipole plasmon when cluster radius approaches 55 nm and of quadrupoleplasmon when cluster size approaches 118 nm, respectively.
Proton-coupled electron transfer reactions in solution: Molecular dynamics with quantum transitions for model systems106(1997); http://dx.doi.org/10.1063/1.473903View Description Hide Description
A general minimal model for proton-coupled electron transfer (PCET) reactions in solution is presented. This model consists of three coupled degrees of freedom that represent an electron, a proton, and a solvent coordinate. Altering the parameters in this model generates a wide range of PCET dynamics. This paper focuses on three model systems corresponding to three different mechanisms: a concerted mechanism in which the proton and electron are transferred simultaneously, a sequential mechanism in which the proton is transferred prior to the electron, and a sequential mechanism in which the electron is transferred prior to the proton. The surfacehopping method 'molecular dynamics with quantum transitions' (MDQT) is applied to these model systems. The proton and electron coordinates are treated quantum mechanically, and the solvent coordinate is treated classically. Thus the adiabatic quantum states are two-dimensional wavefunctions that depend on both the electron and the proton coordinates. The MDQT method incorporates nonadiabatic transitions between these mixed proton/electron adiabatic quantum states. The MDQT simulations presented in this paper provide insight into the fundamental physical principles and the dynamical aspects of PCET reactions.Nonadiabatic effects are shown to play an important role in determining the rates and mechanisms of PCET reactions. This represents the first application of MDQT to a system in which both a proton and an electron are treated quantum mechanically.
Reaction on the potential energy surface: Dependence on translational and internal energy and on isotopic composition, 93–1313 K106(1997); http://dx.doi.org/10.1063/1.473904View Description Hide Description
Rate constants have been measured for the reactions of with and as a function of ion-neutral average center-of-mass kinetic energy, at several temperatures over the range 93 K–565 K using a selected ion flow drift tube apparatus. For the reaction we also report measurements made using a high-temperatureflowing afterglow (HTFA) instrument over the temperature range 300 K–1313 K. The rate constants are found to have a very large isotope effect, with the rate constant a factor of 15 higher than the rate constant at 93 K. The rate constants generally have a minimum with respect to temperature and except for the higher-temperature data for where the rate constants show only an increase with increasing kinetic energy. The data indicate that increasing rotational temperature decreases the rate constants and that rotational energy behaves similarly to translational energy. Single excitations of bending and twisting vibrations have a negligible effect on the rate constant. Either the stretching vibrations or overtones of the bending vibrations increase the rate constants. If the stretches are responsible for the increase in the rate constants, the derived rate constant for a single quantum of stretch excitation is a factor of 6 larger than the rate constant for The rate constants are approximately equal to the averages of the rate constants for the pure isotopes. The product branching ratio shows no dependence on rotational temperature or low-frequency vibrations. A theoretical study of the minimum energy reaction path was performed to help elucidate the reaction dynamics. The minimum energy reaction surface was characteristic of the standard double minimum pathway for ion molecule reactions. The height of the central barrier was found to be close to the energy of the reactants and varied with isotopic substitution. Conformationally different transition states are found for these isotopic reactions.Theoretical studies at the QCISD(T) level of theory find distinct transition states corresponding to The transition state barriers increase in the order and in agreement with experimental reaction rates. The main features of the reactivity are explained by the characteristics of the reaction surface.
A quasiclassical trajectory study of H+CO Angular and translational distributions, and OH angular momentum alignment106(1997); http://dx.doi.org/10.1063/1.473923View Description Hide Description
We present a quasiclassical trajectory study of the H+COreaction dynamics, with emphasis on product angular and translational distributions, and OH angular momentum alignment. A new potential surface has been developed for this study, based on modifications of a previously developed full dimensional empirical HCOpotential surface. The modifications include correcting errors that cause the HO⋅⋅⋅CO dissociation barrier to be too loose, and adjusting the depth of the HCO minimum and the heights of several barriers, in order to bring them into agreement with their best estimates determined from ab initio calculations. We compare cross sections, energy partitioning, and mechanistic information calculated using the unmodified and modified surfaces with experimental results. Results from the modified surface improve the comparison with experiment for the product OH energy partitioning, but the product CO internal excitation is still high. The translational distributions have the same shape as measured distributions, and the average translational excitation matches some experiments but is lower than others. The angular distribution calculated at 2.6 eV on the modified surface is in good agreement with experimental results, showing both forward and backward scattered peaks, with a slight preference for backward scattering. By studying the average lifetime of the HOCO collision complex, we find that the lifetime is comparable to the rotational period so that there is considerable forward scattering (half rotation) and backward scattering (full rotation). The OH product angular momentum alignment indicates no preference for polarization of the OH rotational angular momentum vector. This result–an essentially isotropic distribution–agrees within the experimental uncertainty for measurements of OH polarization dependent differential cross sections and center-of-mass frame alignment parameters, but not with OH
Collision induced deactivation of the bending mode vibrational level of the excited and ground electronic states of by rare gases106(1997); http://dx.doi.org/10.1063/1.473905View Description Hide Description
Collisional deactivation of the vibrational level of the bending mode by rare gases has been studied for both the excited and ground electronic states of Quenching constants have been determined. While a non-SSH behavior has been observed in the dependence of the relaxation probability upon the mass of the collision partner in the ground state denoting a possible predominance of an intramolecular energy transfer process, the cross sections fit quite well the Parmenter and co-workers' potential well depth correlation rule for both the electronic states indicating that their interactions with the quenchers occur for both of them under the influence of long range attractive forces.
Quantum control of in the gas phase and in condensed phase solid Kr matrix106(1997); http://dx.doi.org/10.1063/1.473906View Description Hide Description
We present experimental results and theoretical simulations for an example of quantum control in both gas and condensed phase environments. Specifically, we show that the natural spreading of vibrational wavepackets in anharmonic potentials can be counteracted when the wavepackets are prepared with properly tailored ultrafast light pulses, both for gas phase and for embedded in a cold Kr matrix. We use laser induced fluorescence to probe the evolution of the shaped wavepacket. In the gas phase, at 313 K, we show that molecular rotations play an important role in determining the localization of the prepared superposition. In the simulations, the role of rotations is taken into account using both exact quantum dynamics and nearly classical theory. For the condensed phase, since the dimensionality of the system precludes exact quantum simulations, nearly classical theory is used to model the process and to interpret the data. Both numerical simulations and experimental results indicate that a properly tailored ultrafast light field can create a localized vibrational wavepacket which persists significantly longer than that from a general non-optimal ultrafast light field. The results show that, under suitable conditions, quantum control of vibrational motion is indeed possible in condensed media. Such control of vibrational localization may then provide the basis for controlling the outcome of chemical reactions.


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