text:
Researchers Now Have a Myriad of...
Co-Sourcing Improves Pharmaceutical Laboratory Productivity
Clinical-Style Validation, Regulation, and Quality Control...
Loss of Lives in Clinical Trials...
Western blotting is an analytical technique used to detect the presence of a protein within a complex mixture of proteins such as a tissue extract. Western blots provide a relatively quick means of comparing the levels of a protein of interest between samples, or detecting the presence of posttranslational modifications such as phosphorylation.
In a Western blot, proteins separated by electrophoresis are transferred to a membrane, and the protein of interest is visualized by probing the membrane with an antibody (the primary antibody) that recognizes the target protein. A secondary antibody, conjugated to an enzyme or other label to enable detection, is then allowed to bind to the primary antibody and the blot is imaged.
Presently the most commonly used detection method for Western blotting is chemiluminescence imaged with film, due to high sensitivity and the availability of secondary antibodies conjugated to horseradish peroxidase.
Chemiluminescence produces a low-light signal and is traditionally detected using film. Digital imaging is an attractive alternative to film because it has a substantially larger linear range, and because a digital workflow provides increased reproducibility of imaging conditions and the ability to store and share data.
Recent improvements in charge-coupled device (CCD) camera technology, combined with the development of chemiluminescent substrates optimized for digital imaging (ChemiGlow® from Alpha Innotech), have allowed digital images to meet the performance of film for chemiluminescent Western blots. Figure 1 shows duplicate Western blots imaged for 10-second exposures with either the FluorChem® Q CCD imaging system or with film.
The greater linear dynamic range provided by digital imaging allows more quantitative data to be obtained from Western blots. Figure 1 demonstrates the improved linear range that is obtained with digital imaging relative to film. For the digital image, band intensities are linear over the entire protein range, from 0.01 ng to 5 ng (Figure 1B and expanded scale in 1C). In contrast, the film image (Figure 1D and expanded scale in 1E) has a linear dynamic range approximately two orders of magnitude smaller.
Digital imaging also improves laboratory workflow. Imaging protocols can be saved, and imaging times and lighting conditions controlled precisely, allowing improved reproducibility between experiments. Digital images can also be saved and used directly for analysis and publication, whereas film images generally must be scanned for further analysis, a process that can introduce additional artifacts. Digital imaging is also more cost-effective than film, since it does not require a darkroom or film, and is a more green imaging alternative since it avoids the toxic chemicals involved in film developing.
Mike Collier, Ph.D., is senior applications scientist, Lisa Isailovic ([email protected]
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MDMA (commonly known as the empathogen "ecstasy") is classified as a Schedule 1 drug, which is reserved for compounds with no accepted medical use and a high abuse potential. Two researchers from Stanford, however, call for a rigorous scientific exploration of MDMA's effects to identify precisely how the drug works, the data from which could be used to develop therapeutic compounds.Do you agree that ecstasy should be studied for its potential therapeutic benefits?
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Heterochromia Iridis Center - Brick, NJ
- WebMD Physician Directory of Brick Doctors
- Related Heterochromia Iridis Articles
- Brick Emergency Contacts
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Brick Doctors and Specialists for Heterochromia Iridis
Heterochromia Iridis
Heterochromia iridis facts
- Heterochromia iridis is an uncommon condition in which the two eyes are different in color.
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Other Related Heterochromia Iridis Articles
Emergency Contact for Brick
- In case of Emergency, call 911
Nearby Brick Hospitals results
- 1Ocean Medical Center
425 Jack Martin Blvd
Brick, New Jersey 08724
(732) 840-220
- 2Kimball Medical Center
600 River Ave
Brick, New Jersey 08701
(732) 363-190
- 3Children's Specialized Hospital
94 Stevens Rd Ste 2
Brick, New Jersey 08755
(732) 914-110
- 4Saint Barnabas Behavioral Hlth
1691 US Highway 9
Brick, New Jersey 08755
(732) 914-168
- 5Community Medical Center
99 Route 37 W
Brick, New Jersey 08755
(732) 349-800
- 6Healthsouth Rehabilitation Hosp
14 Hospital Dr
Brick, New Jersey 08755
(732) 244-310
- 7Jersey Shore University Med Ctr
1945 State Route 33
Brick, New Jersey 07753
(732) 775-550
- 8Centrastate Medical Center
901 W Main St
Brick, New Jersey 07728
(732) 431-200
- 9Monmouth Medical Center
300 2nd Ave
Brick, New Jersey 07740
(732) 923-500
- 10Riverview Medical Center
1 Riverview Plz
Brick, New Jersey 07701
(732) 741-270
- 11Bayshore Community Hospital
727 N Beers St
Brick, New Jersey 07733
(732) 739-590
- 12Raritan Bay Medical Center
1 Hospital Plz
Brick, New Jersey 08857
(732) 360-100
- 13Deborah Heart And Lung Center
200 Trenton Rd
Brick, New Jersey 08015
(609) 893-661
- 14Southern Ocean Medical Center
1140 Route 72 W
Brick, New Jersey 08050
(609) 978-890
- 15Buttonwood Hospital
600 Pemberton Browns Mills Rd
Brick, New Jersey 08068
(609) 726-700
- 16Robert Wood Johnson Univ Hosp
1 Hamilton Health Pl
Brick, New Jersey 08690
(609) 586-790
- 17Staten Island Univ Hosp-South
375 Seguine Ave
Brick, New Jersey 10309
(718) 226-200
- 18Univ Med Ctr Princetn Plainsbro
1 Plainsboro Rd
Brick, New Jersey 08536
(609) 853-650
- 19Raritan Bay Medical Center
530 New Brunswick Ave
Brick, New Jersey 08861
(732) 442-370
- 20Robert Wood Johnson Univ Hosp
1 Robert Wood Johnson Pl
Brick, New Jersey 08901
(732) 828-300
- 21Mccosh Health Center Princeton
Washington Rd
Brick, New Jersey 08544
(609) 258-503
- 22St Francis Medical Center
601 Hamilton Ave
Brick, New Jersey 08629
(609) 599-500
- 23Children's Specialized Hospital
200 Somerset St
Brick, New Jersey 08901
(908) 233-372
- 24Saint Peters University Hosp
254 Easton Ave
Brick, New Jersey 08901
(732) 745-860
- 25Roosevelt Care Center
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Brick, New Jersey 08837
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- 26Capital Health Regnl Med Ctr
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* Provider Directory Terms of Use:
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text:
The Best Years (2007– )
Episode List
Season 2
3 Apr. 2009Dangerous Liaisons
Samantha misses an entire semester when her cross-country road-trip goes astray. She meets charming Rich Powell in Panama but after a night together she wakes up alone. Heading back to Charles University as a "froshmore," she finds that things have changed. Noah is now dating Robyn. Kathryn is back but is not no longer her roommate or friend. Alyssia has matriculated and thanks to a deal worked out by Mrs. O'Sullivan, Allysia and Sam are roommates. Also Rich Powell is now a Charles student and Alysia is being set up as the target of a sorority girl prank.
10 Apr. 2009Documentary
Samantha's literature prof takes exception to her late enrollment and tosses her out of class. While Dorothy gets Sam re-instated, Alysia's newest wear-a-nightie-to-class and flirt with Rich trend makes Sam crazy. Meanwhile Noah decides to focus his documentary on the increasing pace of student life on his girlfriend Robyn... that is, if he can get any of her time.
17 Apr. 2009Dermabrasion
Samantha writes a revealing play for her lit class in which she highlights four aspects of herself; Mind, Body, Heart and Spirit. Getting her friends to play the various parts though teaches her some new lessons. Meanwhile, Robyn questions her commitment to pre-med and considers art when her surgeon father visits campus and meets Noah. Del and Kathryn exchange secrets about Sam and Rich as part of their project in abnormal psychology.
24 Apr. 2009Different Hearts
Kat helps Noah with his nightly filming efforts during a campus wide prank war. Alicia wages a prank war of her own against her mother while Samantha and Alicia's new beau, Jake, try to rein her in. Poppy is one of the first victims of the war when she wakes up outside along with all the rest of her dorm room contents.
1 May 2009Destiny
Sam decides to throw Noah a Canadian Thanksgiving party and Del offers to get a caterer. However when Del finds out that his family is broke, a back-up plan is called for. Rich hooks Sam up with veggies for the big dinner but tells her that there relationship is over. Meanwhile Poppy invites her lab partner Travis who brings a special dessert that has everyone laughing by evening's end. Under the influence, Robyn confesses her attraction for Kat and Sam calls Jake to help her make it though the night.
2008Duluth Minnesota
Jake and Sam hook up only to discover that their safe sex might not have been that safe. Meanwhile Kat has a talk with Noah and Robyn and Rich is disappointed that no one gets his sustainability talk.
2009Debtor's Prison
Rich adopts Kat's puppy and it brings chaos to his life. Sam decides she wants another chance with Rich. Poppy's dad comes to town and decides Del's in love with his daughter. Meanwhile Noah struggles with making an interview with Dorothy into a movie.
Sam and Rich decide to challenge themselves to do each something that they're afraid of. Their friends get involved in the challenge as well. Kathryn founds a group. Del analyzes his relationship with Poppy. Poppy builds her time machine. Noah apologizes to Robyn. Rich starts a green pact website and Sam lands a job writing a column for a local paper.
« Season 1 | Season 2


text:
Related Regions:
North America,
United States
53 Resort Reviews
Write New Review
http://www.shantycreek.com (800) 678-4111
My first exposure via the website was okay. The website is nice but it fails to describe what each room entails, which would be helpful in booking rooms. Then, I went through the entire booking process and when I pressed confirm/buy, it said there was an error and told me to call the resort. So this option was totally worthless and a waste of time.
Check-in went well and the lady was very nice. Skiing was nice but Summit Mountain's chairs are extremely slow and old. It was my first time at this resort so after going to Schuss, I realize that Schuss is the place to ski and Summit is pretty much just for the view, hotel, and beginners. Schuss was nice but the lines were busy and it appeared to me that it was because of poorly organized lines and not because it was a holiday.
Dinner at Lakeview Restaurant, which is billed as their upscale, flagship restaurant, on New Year's Eve was a disaster to say the least. We had a reservation at 9pm and arrived promptly, only to be ignored by the host for 15 minutes. The least he could have done was acknowledge our presence and explain what was going on. Apparently they were not prepared for the rush of NYE, even though numerous employees told us that it was this busy every year. If you know it is going to be busy, then be prepared!! Don't use it as an excuse. We were finally seated all the way at the edge of the restaurant by the hallway, despite numerous empty tables in the middle by the windows overlooking Lake Bellaire. The entire dinner, there were kids running around screaming and parents running around screaming at their screaming kids. This was supposed to be a romantic dinner, and claiming this restaurant as upscale was deceptive. The dinner service was awful. The first thing the waitress said to us was, "I hope you're not in a hurry, because we are so busy because of New Year's Eve. It is like this every year". Again, be prepared for the rush. Even though we didn't mind the extra time it was taking, the kids screaming didn't help, nor did the 15 minutes it took to bring a simply glass of wine. Since she warned us that it was so busy, apparently the waitress decided she didn't need to check up on us, or even ask how the food was (it was not good). The only thing that she did right was finally ask us, at the end of the meal, how things were, so we complained and she took the dinners off the bill. What an absolute disappointment after looking forward to a nice meal on NYE. We were so peeved that we skipped the party at Ivan's and went back to the room where we knew nothing else could be screwed up.
We checked out the next day and during checkout, not once did the person ask how my stay was or anything to that effect. They hold the resort out as an nice place. I expect better customer service. Especially considering I spent at least $1,000 in 2 days between lodging, food and skiing. At these rates, in Michigan, I expect more. I will not be returning and I will not recommend this resort to anyone.
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Thanks a lot in advance. I think this is a great free plugin and I like the design of the buttons. Only one problem, it doesn't work yet on my site. I will make a donation once my problem is solved.
At the bottom of this page http://www.onlinecasinoground.nl/apeldoorn-casino/ , I've inserted an example of a "Tangerine button". The font should be white, but it isn't. And the letters light up in blue somehow. How can we solve this?
Help is highly appreciated!


text:
Please Heeeeelp! Gta Sa
Posted 28 August 2006 - 01:06 PM
i follow the pinned! (insert custom cars into gta sa!)
1. xxx.txd open with txdworkshop, save as VCxBoX
2. open gta3.img and "REPLACE" xxx.txd and xxx.dff
3. rebuild archive
4. via FTP to xbox
5. delete cache x,y,z and e:/cache
6. reboot
7. after loading the savegame, the screen freezzzzzzeeee!
probleme?????? i need help!
Posted 28 August 2006 - 04:46 PM
what version of san andreas do you have? the second edition is unmoddable without the patch. more details can be found here and here
Posted 28 August 2006 - 07:39 PM
what version?
i use the patch from your forum for pal!
the dff file are bigger than 1mb!
can i more cars replace and than rebuild the archive?
Posted 28 August 2006 - 07:47 PM
also are you asking, can you add additional cars to the game instead of replacing? as far as i know, no, you need to replace
Posted 29 August 2006 - 11:41 AM
i used a dff with 650kb and it is ok und runs! thanks!
my english is not so good! sorry!
to the asking! i open the gta3.img than replace aaa.dff/aaa.txd than rebuild archive! so! can i replace aaa.dff/txd than replace bbb.dff/txd and than rebuild? or after once car replace rebuild?
Posted 29 August 2006 - 02:47 PM
Posted 29 August 2006 - 11:36 PM
ok! thanks!
Posted 30 August 2006 - 03:25 AM
Posted 30 August 2006 - 09:19 AM
but i think my solution is a bit different, i bought this xbox from someone else, en the previous owner modded san andreas... and it has the files default.xbe, but also default-unpatched.xbe... sow im guessing its already patched, but the mods used are to big... can i trace the mods and delete them, or replace them with good sized mods?
sorry for my poor english, im form holland
Posted 30 August 2006 - 09:49 AM
If I recall correctly though... if you replace a file in the gta3.img file with a modded one, it doesn't update the file size.
So finding the mod may prove more difficult than it appears.
Posted 10 September 2006 - 10:33 AM
when the dff file are bigger than 1mb can i push(make it smaller) it with any prog?
do you understand me?
all download cars.dff are bigger than 1mb.
Posted 10 September 2006 - 03:30 PM
Posted 11 September 2006 - 06:24 AM
however most of them run anywhere from $500 to $2000 (way out of my price range.)
your best bet is to reduce the model manually with 3dsmax like Potman said.
Posted 13 September 2006 - 06:17 PM
and where i find the tool?
Posted 13 September 2006 - 08:04 PM
gmax's free tho, it's similar to 3dsmax, download it somewhere here: http://turbosquid.com/
also u need kam's script for gmax or 3dsmax to export/import gta .dff files, download kam's script here:
Edited by Potman, 13 September 2006 - 08:17 PM.
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text:
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WGP Beta Glucans—Powerful Immune Boosters
…nutrients. By far the most effective I've found are beta glucans. They do a superior job of bolstering your immunity. Recently, a new patented process has developed a 75 percent pure, advanced form called WGP beta glucan. The new WGP beta glucans are known as modulators—meaning they give you steady…Read More


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CHICAGO (July 24, 2013)—Nathan Woessner, 6, of Sterling, Ill., who survived after he was buried for several hours in a sand dune, was home from the hospital Wednesday.
Nathan was discharged Tuesday afternoon from the University of Chicago Medicine Comer Children's Hospital, 12 days after the accident.
The boy was buried for more than three hours on July 12 in a dune called Mount Baldy at Indiana Dunes National Lakeshore.
The hospital said he will continue to undergo rehabilitation.
He walked without assistance Sunday and was cleared to visit the hospital playroom Monday, doctors said.
He's expected to make a full neurological recovery but may suffer lingering lung problems from inhaling sand.
Doctors initially put Nathan in a medically induced coma.


text:
Good Earth/Great Chefs Series: Jeanne Kelly, 'Salad For Dinner: Complete Meals For All Seasons'
Above: Image of author Jeanne Kelley
The Chino Farm will be hosting Jeanne Kelley, Sunday, June 3, 2012 from 11am - 1pm to sign copies of her beautiful new cookbook "Salad For Dinner: Complete Meals for All Seasons" just released by Rizzoli International Press.
There will be an informal reception with select tastings of Jeanne's salads using seasonal lettuces and vegetables fresh from the farm, along with a sample of virgin olive oil to take home from 36 Degrees Olive. Steve Wagner from Stone Brewery will also be on hand pouring beers to pair with salads and signing his book, "The Craft of Stone Brewing Co." Open to the public.
The Chino Farm, 6123 Calzada del Bosque Del Mar: Google Maps


text:
E.D. White grad conducts school song 40 years after composing it
Published: Saturday, September 15, 2007 at 6:01 a.m.
Last Modified: Saturday, September 15, 2007 at 12:25 a.m.
THIBODAUX -- Forty years after he composed it, Gibbens Robichaux finally got a chance to conduct the Edward Douglas White Catholic High School alma mater.
Robichaux, 77, was honored at the schools homecoming Mass Friday, where he was named Alumnus of the Year. In 1947 he graduated from Thibodaux College, the boys school that combined in 1965 with Mt. Carmel Academy to become E.D. White.
At the ceremony Robichaux accepted an engraved wand and a pair of white gloves from his son, Tim Robichaux, who is the schools band director. Gibbens Robichaux was asked to conduct the band, which was gathered in the corner of the gymnasium where the ceremony took place.
His son said that his father is a regular visitor to the school, that he often practices with the band, but has never been asked to conduct the alma mater.
"He still comes around and is so involved. Hes always been a positive role model to the kids," his son said. "He is so deserving."
Gibbens wrote the alma mater in 1967, after the school began soliciting submissions. He was giving music lessons at the time, he said, and
composed the song in a 15 minute break between students.
"It just came to me," he said.
Gibbens history with music stretches back to his time at Thibodaux College, where he was a member of both the football team and the band. He played the glockenspiel and soprano sax.
After he graduated from Thibodaux College, he attended Spring Hill College in Mobile, Ala., and later joined the Air Force. He returned to Thibodaux and worked a number of jobs, including playing the organ at St. Joseph Cathedral.
Gibbens said E.D. White is different from other schools in that it teaches it students something more.
"It all comes down to discipline," he said. "Behind it all is the faith."
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Ernie Rogers specializes in residential and commercial real estate auctions. He has been an experienced and award-winning auctioneer since 1998. He is the 2004-05 Virginia State Champion Auctioneer, and is a past Board Member and Past President of the Virginia Auctioneers Association (2010).
Ernie uses an enhanced accelerated marketing campaign in Virginia, North Carolina, DC and Florida to move properties either by auction or by conventional private treaty. He is the owner of United Country-River City Auction & Realty in Midlothian, Virginia. Whether you want to buy or sell, River City Auction & Realty is the perfect fit for you! He has over 17 years experience in selling real estate. He takes the stress out of the equation!!
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United Country is the nation's largest integrated organization of real estate and auction professionals, we specialize in real estate throughout the country. We specialize in marketing lifestyle real estate in the country and across rural America including small city,
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The founder, Roscoe Chamberlain wanted to provide people living in urban and suburban areas a "roadmap to the country". We have been connecting people to their dream properties since 1925.
In 1928 the company produced the first ever national real estate catalog. Order yourfree copy of the current season TODAY!


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The 4th exploration for Tracklab.
Concept: Studio that works mainly with Music Production. But also Photography and Film.
Does this logo get the message across? Let me know what you think :) Honest feedback is highly appreciated.
Last concept was a bit too heavy on "Film" and didn't get the main point across.
Thanks Dribbble dudes for the comments and feeback on the previous versions, you're a priceless asset.
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Masanura and Tomoko Oh
Entrance to Beppu Peace Park
Pfc. Stuart F. Tower returns to Beppu
The Chickamauga Tree
Plaque "commemorating the kindnesses shown by the troops of the 19th Infantry to the people of Beppu"
My escorts, Lt. and Colonel, Japanese Army, Mr. Masanuri Kise and Tomoko Koh, Mayor's Office
From open ditches (1946) to this (2007)
our Beppu ryokan, Korakura
"Main Street" Beppu
Beppu rickshaw, fashion school ??,entrance to camp, Beppu Main Street, The Rock
Beppu street scene 1946, Ice Cream place that never opened, Stu and his anti-tank gun truck


text:
This new release includes two changes.
The first change is by idea from Doug Farley. When multiple datafiles are generated and updated from a single service check, the previous behaviour was to display data from all files in same graph. Instead graphs are now automatically split into one graph per datafile. This will make graphing of disks much easier in cases where multiple disks are checked by one servicecheck. Splitting graphs into for example MB and percent is still a manual process.
The second change is to use css and generate proper xhtml code. Patches submitted by Ton Voon. A new option has been added nagiosgraph.conf to point to stylesheet.


text:
SOURCE: Reuters
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Ancient Jewish scrolls found in north AfghanistanBreaking News
KABUL (Reuters) - A cache of ancient Jewish scrolls from northern Afghanistan that has only recently come to light is creating a storm among scholars who say the landmark find could reveal an undiscovered side of medieval Jewry.
The 150 or so documents, dated from the 11th century, were found in Afghanistan's Samangan province and most likely smuggled out -- a sorry but common fate for the impoverished and war-torn country's antiquities.
Israeli emeritus professor Shaul Shaked, who has examined some of the poems, commercial records and judicial agreements that make up the treasure, said while the existence of ancient Afghan Jewry is known, their culture was still a mystery....
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text:
|Publication number
|Publication type
|Application number
|Publication date
|Jan 11, 1994
|Filing date
|Jun 30, 1993
|Priority date
|Oct 5, 1992
|Fee status
|Also published as
|Publication number
|Ronald J. Hoxmeier
|Original Assignee
|Shell Oil Company
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (1), Referenced by (15), Classifications (14), Legal Events (3)
|External Links: USPTO, USPTO Assignment, Espacenet
This is a division, of application Ser. No. 07/956,184, filed Oct. 5, 1992 pending.
As is well known, polymers containing both aromatic and ethylenic unsaturation can be prepared by copolymerizing one or more polyolefins, particularly a diolefin, with one or more alkenyl aromatic hydrocarbon monomers. Other diolefins such as 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, 1,3-hexadiene and the like, and other vinyl aromatic hydrocarbons such as o-methylstyrene, p-methylstyrene, p-tertbutylstyrene, 1,3-dimethylstyrene, alphamethyl-styrene, vinylnapthalene, vinylanthracene and the like may be used. The copolymers may, of course, be random, tapered, block or a combination of these. Radial and star polymers are also well known.
Polymers containing ethylenic unsaturation or both aromatic and ethylenic unsaturation may be prepared using free-radical, cationic and anionic initiators or polymerization catalysts. Such polymers may be prepared using bulk, solution or emulsion techniques. In any case, the polymer containing at least ethylenic unsaturation will, generally, be recovered as a solid such as a crumb, a powder, a pellet or the like. Polymers containing ethylenic unsaturation and polymers containing both aromatic and ethylenic unsaturation are, of course, available commercially from several suppliers.
Polymers of conjugated diolefins, polymers of vinyl aromatic hydrocarbons and copolymers of one or more conjugated diolefins and one or more alkenyl aromatic hydrocarbon monomers such as ABA block copolymers, including radial and star versions, are frequently prepared in solution using anionic polymerization techniques. In general, when solution anionic techniques are used, these polymers are prepared by contacting the monomers to be polymerized simultaneously or sequentially with an organoalkali metal compound in a suitable solvent at a temperature within the range from about--150� C. to about 300� C., preferably at a temperature within the range from about 0� C. to about 100� C. Particularly effective anionic polymerization initiators are organolithium compounds having the general formula:
R is an aliphatic, cycloaliphatic, aromatic or alkyl-substituted aromatic hydrocarbon radical having from 1 to about 20 carbon atoms; and n is an integer of 1 to 4.
Such polymers are then often coupled to produce longer linear polymers or radial or star polymers by reacting the living polymer chains or arms with a polyfunctional coupling agent. This process is described in detail in U.S. Pat. No. 4,096,203 which is herein incorporated by reference. A well-known coupling agent for use in making star polymers is a polyalkenyl aromatic coupling agent, specifically divinyl benzene. The present invention provides an alternative coupling agent for use in producing such polymers.
The present invention is a process for producing a novel coupled polymer. The process comprises first anionically polymerizing a vinyl aromatic hydrocarbon, a conjugated diene or both with an organo alkali metal compound to produce living polymer arms. The living polymer arms are contacted with a fullerene which reacts with the living polymer arms, thereby forming a coupled polymer. Finally, the polymerization is terminated. The fullerenes known at the present time are Buckminsterfullerene, C60, and C70, C76, C84, C90, C94, C100 and all the way up to C212. The polymers produced exhibit novel characteristics.
The polymers of the present invention are produced by anionic polymerization employing an organo alkali metal compound, usually an organo monolithium compound, as an initiator. The first step of the process involves contacting the monomer(s) to be polymerized with the organo monolithium compound (initiator) in the presence of an inert diluent thereby forming a living polymer compound having the simplified structure A-Li. The monomer may be a vinyl aromatic hydrocarbon, a conjugated diene or a mixture of the two. Styrene is the preferred vinyl aromatic hydrocarbon and the preferred dienes are butadiene and isoprene.
The inert diluent may be an aromatic or naphthenic hydrocarbon, e.g., benzene or cyclohexane, which may be modified by the presence of an alkene or alkane such as pentenes or pentanes. Specific examples of suitable diluents include n-pentane, n-hexane, isooctane, cyclohexane, toluene, benzene, xylene and the like. The organomonolithium compounds (initiators) that are reacted with the polymerizable additive in this invention are represented by the formula RLi, wherein R is an aliphatic, cycloaliphatic, or aromatic radical, or combinations thereof, preferably containing from 2 to 20 carbon atoms per molecule. Exemplary of these organomonolithium compounds are ethyllithium, n-propyllithium, isopropyllithium, n-butyllithium, sec-butyllithium, tertoctyllithium, n-decyllithium, n-eicosyllithium, phenyllithium, 2-naphthyllithium, 4-butylphenyllithium, 4-tolyllithium, 4-phenylbutyllithium, cyclohexyllithium, 3,5-di-n-heptylcyclohexyllithium, 4-cyclopentylbutyl-lithium, and the like. The alkyllithium compounds are preferred for employment according to this invention, especially those wherein the alkyl group contains from 3 to 10 carbon atoms. A much preferred initiator is sec-butyllithium. See U.S. Pat. No. 3,231,635 which is herein incorporated by reference. The concentration of the initiator can be regulated to control molecular weight. Generally, the initiator concentration is in the range of about 0.25 to 50 millimoles per 100 grams of monomer although both higher and lower initiator levels can be used if desired. The required initiator level frequently depends upon the solubility of the initiator in the hydrocarbon diluent. These polymerization reactions are usually carried out at a temperature in the range of -60� to +300� F. and at pressures which are sufficient to maintain the reaction mixture in the liquid phase.
The living polymer arms may be homopolymers or block, random or tapered block copolymers of one or more of the above monomers. For instance, the living polymer arm may consist of a block of polystyrene and/or a block of a conjugated diene or it may consist of blocks of different conjugated dienes. Blocks containing more than one monomer are made by first anionically polymerizing the first monomer to make a living polymer arm and then continuing the polymerization in the presence of the second monomer, thereby forming a living polymer arm which is comprised of blocks of each of the monomers.
The living polymer arms are then reacted with a fullerene to produce a coupled polymer. The coupling reaction may be carried out in the same solvent as for the polymerization reaction steps for convenience or it may be added as a solid. A list of suitable solvents includes toluene aromatic solvents, ether, tetrahydrofuran and ethers in general. The coupling reaction step temperature may vary between wide limits, for example, from 0� C. to 150� C., preferably from 50� C. to 80� C. The reaction may also take place in an inert atmosphere (no oxygen), for example, nitrogen and under pressure, for example, a pressure of from 1 atm to 100 atm. However, very good results may be achieved at ambient conditions.
Fullerenes are highly stable molecules composed of a large number of carbon atoms. In 1985, Kroto et al. reported in Nature, Volume 318, p. 162, Nov. 14, 1985, that stable clusters of 60 and 70 carbon atoms could be produced. The model proposed for the 60 carbon cluster was a truncated icosahedron composed of 32 faces, 12 pentagonal and 20 hexagonal, which looks somewhat like a soccer ball and is similar to the geodesic domes of Buckminster Fuller. Thus, C60 is commonly referred to as Buckminsterfullerene.
These fullerenes, the C60, and C70 fullerenes, can be made by evaporating graphite in an atmosphere of an inert quenching gas under pressure in an evacuated reactor, collecting the quenched carbon product and contacting it with an extracting non-polar organic solvent under conditions to separate the C60, and C70 compounds therefrom. The process is described in detail in World Patent Application WO92/04279, published Mar. 19, 1992, and based on U.S. patent applications Ser. Nos. 575,254 and 580,246, filed Aug. 30, 1990 and Sep. 10, 1990, respectively (these patent applications are hereby incorporated by reference). Other fullerenes, such as C76, C84, C90, C94, C100 and up to C212, have also been discovered as described in "C60 : From Soot to Superconductors" by F. Diederich and R. L. Whetten, Angew. Chem. Int. Ed. Engl. 30 (1991) No. 6, pp. 678-680, which is also herein incorporated by reference.
The polymers made by this coupling reaction will generally be star shaped polymers because of the large number of active coupling sites which are present on the fullerene compounds. The number of polymer arms will generally vary from about 3 to about 36 arms. However, it is possible to produce polymers with lesser numbers of arms and even substantially linear polymers and polymers with more than 36 arms. All of these polymers are characterized by having a dense center or nucleus of the fullerene compound and a number of arms of linear unsaturated polymers extending outward therefrom.
Following the coupling reaction, the product is neutralized such as by addition of terminators, e.g., hydrogen, water, alcohol, Ni+2, methyl iodide or other reagents, for the purpose of removing the lithium radical forming the nucleus for the condensed polymer product. The product is then removed such as by coagulation utilizing hot water, steam, methanol, isopropanol, etc.
After coupling of the first set of polymer arms, it is possible to make another set of polymer arms by anionic polymerization, preferably different from the first set, and react the second set of polymer arms with the first coupled product before, or preferably after, termination to produce a second coupled product which is an asymmetric star polymer. An asymmetric star polymer is a star polymer in which not all of the arms have the same polymeric structure. It is significant that the efficacy of the fullerene coupling agent is not adversely affected by the termination step. Of course, such asymmetric polymers could also be produced by making a second set of polymer arms before coupling and then coupling both the first and second set of polymer arms with the fullerene at the same time.
Preferred coupled polymers made according to the process of the present invention include star polymers of polystyrene, polybutadiene and polyisoprene. Preferred polymers made according to the present invention include star block copolymers wherein the polymer arms are block copolymers of styrene and either butadiene or isoprene and asymmetric block copolymers which have additional blocks of either polybutadiene or polyisoprene.
The molecular weights of polymers produced hereunder may vary over a wide range with individual arm molecular weights varying from 500 to 500,000. Molecular weights of linear polymers or unassembled linear segments of polymers such as mono-, di-, triblock, and etc., arms of star polymers before coupling are conveniently measured by Gel Permeation Chromatography (GPC), where the GPC system has been appropriately calibrated. Polymers of known molecular weight are used to calibrate and these must be of the same molecular structure and chemical composition as the unknown linear polymers or segments that are to be measured. For anionically polymerized linear polymers, the polymer is essentially monodisperse and it is both convenient and adequately descriptive to report the "peak" molecular weight of the narrow molecular weight distribution observed. Measurement of the true molecular weight of the final coupled star polymer is not as straightforward or as easy to make using GPC. This is because the star shaped molecules do not separate and elute through the packed GPC columns in the same manner as do the linear polymers used for the calibration, and, hence, the time of arrival at a UV or refractive index detector is not a good indicator of the molecular weight. A good method to use for a star polymer is to measure the weight average molecular weight by light scattering techniques. The sample is dissolved in a suitable solvent at a concentration less than 1.0 gram of sample per 100 milliliters of solvent and filtered using a syringe and porous membrane filters of less than 0.5 microns pore size directly into the light scattering cell. The light scattering measurements are performed as a function of scattering angle and of polymer concentration using standard procedures. The differential refractive index (DRI) of the sample is measured at the same wavelength and in the same solvent used for the light scattering. The following references are herein incorporated by reference:
1. Modern Size-Exclusion Liquid Chromatography, M. W. Yau, J. J. Kirkland, D. D. Bly, John Wiley & Sons, New York, N.Y., 1979.
2. Light Scattering from Polymer Solutions, M. B. Huglin, ed., Academic Press, New York, N.Y. 1972.
3. W. Kay and A. J. Havlik, Applied Optics, 12, 541 (1973).
4. M. L. McConnell, American Laboratory, 63, May, 1978.
If desired, these block copolymers can be hydrogenated. Hydrogenation may be effected selectively as disclosed in U.S. Pat. Nos. Re. 27,145 or 5,039,755 which are herein incorporated by reference. The hydrogenation of these polymers and copolymers may be carried out by a variety of well established processes including hydrogenation in the presence of such catalysts as Raney Nickel, noble metals such as platinum and the like, soluble transition metal catalysts and titanium catalysts.
As initially prepared, the coupled block copolymer versions of C60, are strong, elastomeric and very soluble in hydrocarbon solvents. Upon storing a cast film in the dark for several weeks at ambient conditions, the material at first becomes insoluble in hydrocarbon solvents (gel formation indicating crosslinking) and ultimately extremely brittle to the point of shattering upon application of impact. This suggests that the C60 coupling agent core is an efficient generator of free-radicals and thereby serves as a built-in vulcanization agent. This is an extremely novel composition with corresponding novel properties and uses, e.g., in adhesives and asphalt modification applications.
The polymers made according to the present invention can be used for all of the uses known for such polymers made by other methods with other coupling agents such as dibromoethane and divinyl benzene. For example, such polymers can be used in adhesives, coatings, sealants, and blends with other thermoplastics, as viscosity index improvers, in asphalt blends and as potentially extrudable or moldable electrically conducting, semiconducting or superconducting systems.
These experiments demonstrate the coupling of homopolymer arms with C60.
In the first step, living polybutadiene arms (PBD- Li+) of 5,000 molecular weight (as determined by gel permeation chromatography [GPC]) were prepared by adding the appropriate amount of cyclohexane solvent to a 100 ml bottle reactor, charging the reactor with the appropriate amount of butadiene and then adding the required amount of sec-butyl lithium in cyclohexane solution. The reactor was heated in a water bath at 50� C. for 1.5 hours and then cooled. The appropriate amount of Buckminsterfullerene (known colloquially as "Bucky Balls"), C60, was added to the reactor as a solid in a drybox and the reactor was heated again for an hour and a half at 70� C. Upon addition of the Bucky Balls, the color of the solution became dark red. The polymerizations were terminated as described below and after precipitating the polymer with methanol, the polymers were dried in an oven at 50� C. with a purge of nitrogen. The resulting polymers were analyzed by GPC. For all of these experiments Li:C60 =6:1 on a molar basis. Three experiments (Bucky 1-3) were coupled as described above. A second set of experiments (Bucky 4-6) were coupled in the presence of N,N,N',N'-tetramethylethylenediamine (TMEDA). In Bucky 4-6, TMEDA:Li=2:1 on a molar basis. The reactions were terminated with various reagents as shown in Table 1. Ni-2 was added as Ni(2-ethylhexanoate)2 in cyclohexane. Six polymers were made and the amounts of the reactants are shown in Table 1 below.
TABLE 1__________________________________________________________________________Polymer Bucky 1 Bucky 2 Bucky 3 Bucky 4 Bucky 5 Bucky 6__________________________________________________________________________Cyclohexane, g. 50.7 47.6 44.9 46.8 46.9 43.6Butadiene, g. 5.4 5.2 4.90 4.80 5.90 5.20S-BuLi, mg 64 64 64 64 64 64Bucky Balls, mg 120 120 120 120 120 120Termination Acetic Ni+2 MeI Acetic Ni+2 MeIAgent Acid Acid__________________________________________________________________________
The GPC analysis revealed that the coupling efficiencies of Buckys 1, 2 and 3 were 30%, 48% and 60% respectively and the coupling efficiencies of Buckys 4, 5 and 6 were 30%. This was carried out by comparing the GPC traces obtained using a refractive index detector and a UV detector for each sample. Only those species containing Bucky Balls give a UV signal in the GPC trace. This means that 30% to 60% of the polybutadiene was coupled to the Buckminsterfullerene coupling agent. The number of arms was estimated to vary from one to 20 or more arms.
These experiments demonstrate the coupling of block copolymer arms with C60.
Styrene-butadiene diblock arms (SB- Li+) of 5,000 and 10,000 molecular weight, respectively, were made by first making a polystyrene block and then adding a polybutadiene block thereto. A block of 5,000 molecular weight polystyrene was made by adding styrene and s-butyllithium to a reactor charged with cyclohexane and 6% by weight diethyl ether to insure that the 1,2 vinyl content of the polybutadiene block was at least 40%. An orange solution resulted and the solution was heated in a water bath at 50� C. for 1.5 hours and then allowed to cool to room temperature. Then butadiene was added to the reactor which was then heated for another hour at 50� C. resulting in a pale yellow solution. This solution was contacted with Bucky Balls (added as solid C60 for Bucky 7 and 0.4% wt solution of C60 in toluene for Bucky 8) and then coupled, terminated and coagulated as described for Bucky 1 in Example 1. The amounts of the various materials used are shown in Table 2 below (the ratio of Li:C60 was 6:1 on a molar basis for both experiments).
TABLE 2______________________________________Wt. of Wt. of Wt. of Wt. of Wt. of Wt. ofCH Ether Sty. BD S-BuLi C60______________________________________Bucky 7 46.3 3.1 g 1.85 g 3.6 g 21 mg 40 mgBucky 8 46.0 3.6 g 1.70 g 3.3 g 21 mg 40 mg______________________________________
The polymers produced herein, Bucky 7 and Bucky 8, were shown to be 78% and 66% coupled, respectively, by GPC analysis as described in Example 1. The number of arms grafted to C60 are estimated to vary from 1 to about 10 in these experiments.
These experiments demonstrate that, after one set of arms is coupled to C60, another set of arms can be coupled to the initially coupled species thereby greatly increasing the total number of arms coupled to C60.
Styrene-butadiene arms (SB- Li+) of 5000 and 10,000 molecular weight respectively were prepared exactly as in Example 2. Three identical solutions were prepared for Experiments Bucky 9, Bucky 10 and Bucky 11, respectively. Then, to Bucky 9, e.g., was added sufficient Bucky 4 (from Example 1) to give a Li:C60 molar ratio of 7:1. Thus, Bucky 4 already containing a number of arms grafted to C60 is used as the coupling agent in this experiment to add yet additional arms to form an asymmetric radial polymer. Likewise, to Bucky 10 was added Bucky 5 as coupling agent and to Bucky 11 was added Bucky 6 as coupling agent. The results are shown in Table 3 below. Note that the coupling agents have the composition (polybutadiene)n C60 =Bn C60 ; the arms to be coupled have the composition polystyrenepolybutadiene - Li+ =SB- Li+ ; and thus the products of the coupling reactions are (SB)m Bn C60.
TABLE 3______________________________________Experiment Coupling CouplingNo. Agent = Bn C60 Efficiency Product______________________________________Bucky 9 Bucky 4 35% (SB)m Bn C60Bucky 10 Bucky 5 33% (SB)m Bn C60Bucky 11 Bucky 6 16% (SB)m Bn C60______________________________________
As described in Examples 1 and 2, coupling efficiencies were determined from GPC analysis. The coupling efficiency was defined as being equal to the ratio of coupled SB- Li+ arms to the total number of SB- Li+ arms available for coupling.
Polystyryllithium (S- Li+) of 10,000 mole weight was prepared by techniques identical to those described in Example 1 and then coupled by adding solid C60. Thus, to 0.5 mmoles of S- Li+ in cyclohexane (10% by wt S- Li+) was added 0.083 mmoles of C60 (Li:C60 =6:1 on a molar basis). This solution was coupled at 70� C. for 1 hour to give Bucky 12. GPC analysis indicated that Bucky 12 was 56% coupled. This material was analyzed by light scattering techniques to obtain the average molecular weight from which it was determined that the average number of arms coupled to C60 in Bucky 12 is 14 arms/C60 molecule.
|Cited Patent
|Filing date
|Publication date
|Oct 28, 1991
|Jan 5, 1993
|Exxon Research And Engineering Company
|Process of forming polysubstituted fullerenes
|Citing Patent
|Filing date
|Publication date
|Mar 8, 1994
|Dec 13, 1994
|Exxon Research And Engineering Company
|Fullerene compositions and preparation
|Oct 3, 1994
|Aug 13, 1996
|Xerox Corporation
|Ink jettable toner compositions and processes for making and using
|Sep 9, 1996
|Dec 22, 1998
|Ishikawa Seisakusho
|Fullerene compound, manufacturing method, and use
|Dec 26, 2001
|Mar 13, 2007
|Nec Corporation
|Superconducting material and method for producing the same
|Jul 14, 2006
|Jun 15, 2010
|Alarm and alarm management system for remote tracking devices
|Nov 2, 2005
|Aug 16, 2011
|Bridgestone Corporation
|Polyhedral-modified polymer
|Dec 26, 2001
|Jul 4, 2002
|Yoshiyuki Miyamoto
|Superconducting material and method for producing the same
|Nov 2, 2005
|Dec 20, 2007
|Bridgestone Corporation
|Polyhedral-Modified Polymer
|Jul 14, 2006
|Jan 17, 2008
|Remote tracking device and a system and method for two-way voice communication between the device and a monitoring center
|Jul 30, 2007
|Apr 24, 2008
|Securealert, Inc.
|Emergency phone with single button activation
|Sep 23, 2010
|Securealert, Inc.
|Alarm and alarm management system for remote tracking devices
|Nov 2, 2005
|Dec 8, 2010
|Polyhedral-modified polymer
|Nov 2, 2005
|Jun 13, 2012
|Polyhedral-modified polymer
|Nov 2, 2005
|Jan 26, 2011
|Bridgestone Corporation
|Polyhedral-modified polymer
|Nov 2, 2005
|May 11, 2006
|Bridgestone Corporation
|Polyhedral-modified polymer
|U.S. Classification
|525/232, 525/332.5, 977/753, 525/333.3, 525/314, 525/333.2
|International Classification
|Cooperative Classification
|European Classification
|Aug 19, 1997
|Maintenance fee reminder mailed
|Jan 11, 1998
|Lapse for failure to pay maintenance fees
|Mar 24, 1998
|Expired due to failure to pay maintenance fee
Effective date: 19980114


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Jesse Ryder hit a run-a-ball century to put Wellington in
commanding position on the first day of their Plunket Shield
clash with Central Districts today.
Ryder has been in a rich vein of form with the bat since
returning from his self-imposed exile from cricket, and that
continued today as he finished the day unbeaten on 108 as
Wellington amassed 176-2.
After bowling out Central Districts for 260, Wellington now
stand a great chance of toppling the Plunket Shield leaders
and pulling themselves up from fifth position.
Wellington captain Stephen Murdoch won the toss and sent in
the Stags at Karori Park, a decision which paid dividends in
the fifth over when Mark Gillespie struck twice to reduce the
visitors to 23-2.
Several CD batsmen made starts but wickets continued to
tumble as Wellington threatened to bundle out the leaders in
rapid time.
However, 20-year-old Will Young stood firm for the Stags and
stroked his maiden first class century to ensure his side put
up a respectable total.
Young was the last man out for 121 as Wellington claimed all
four bowling bonus points, thanks to three wickets each from
Gillespie and Scott Kuggeleijn, giving themselves a good
change of amassing a first innings lead.
Ryder and Michael Papps (58no) made the most of that
opportunity and, by stumps, had put on an unbeaten 161-run
stand for the third wicket. Ryder was the main aggressor as
he smashed his 13th first class ton, hitting 10 fours and
four sixes.
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Skip to comments.US presses Japan to hand back 300 kg of plutonium
Posted on 01/26/2014 6:24:38 PM PST by TigerLikesRooster
US presses Japan to hand back 300 kg of plutonium
IANS | Tokyo January 27, 2014 Last Updated at 04:34 IST
Japan's key ally the US has been pressing the country to return more than 300 kg of mostly weapon-grade plutonium that it exported to Japan for research purposes during the Cold War era, media reported.
The plutonium that is stored at a fast critical assembly in Tokaimura in Japan's Ibaraki prefecture could be used to produce 40-50 nuclear weapons, reported Japan's Kyodo News, citing unnamed Japanese and US government officials, according to Xinhua.
Japan has strongly resisted the demand raised by US President Barack Obama's administration, but it finally gave in to repeated demands, Kyodo said.
The two countries since last year have been seriously discussing the issue as the US plans to reach an accord with Japan at the third nuclear security summit in March in the Netherlands, according to the report.
The fast critical assembly belonging to the Japan Atomic Energy Agency is the country's only critical assembly designed to study characteristics of fast reactors.
The Japanese ministry of education, culture, sports, science and technology and other researchers have argued that the plutonium in question is needed for research and vital for producing good data, said Kyodo.
At present, Japan has another estimated 44 tonnes of plutonium, but its quality is not on par with the plutonium used for research purposes, Kyodo quoted a Japanese expert as saying.
So he trusts Iran with nukes but not Japan.
Barry wants to give it to the Mooselim Brotherhood?
It seems that he is siding with China on this.
That was my thought, too.
Will not happen! Japan is looking after Japan, no one else maters at this moment.
How does Obama plan to dispose of it?
unilateral disarmament is his dream and eventual dissolution of the USA and rise of United Socialist States of America.
The dots are quickly coming into view - to start connecting them is our job.
Reevaluating America's greatest threats 70 years later...
The penalties for being a faithful ally to the US are pretty severe these days
I say let'm keep it. They are going to need it with China becoming more aggressive with each passing moment.
With the way China is acting? Hell, Japan would be foolish and suicidal to give up their plutonium. In fact, they're foolish if they are not at this very minute building nuclear weapons to minimize the possibility of Chinese aggression—the old "mutually assured destruction" strategy (it worked for us and the Soviets).
Possession is 9/10ths.
"Okay. As soon as you return all of Germany's gold."
Sounds good, doesn't it?
On this matter, Obama has become the mouthpiece of China.
Money talks.
China is behind this. They don't want Japan to have
nukes as it poses a threat to their plans for dominance.
Thus they yank the strings on this administration to try
and get that plutonium out of Japan....wouldn't surprise me if Obungler promised to give that material to China, he's that much of a traitor.
Japan should tell Hussein to take a long walk off a short pier.
China's wanted revenge ever since 1945.
They're already placed in warheads.
I have a feeling they'll be delivered to NoKo one warhead at a time before Barry see them.
I was thinking the very same thing :-)
Molon Labe, Barry.
If I were Obozo I would be careful about pushing the Japanese to return the nuclear makings, if Pearl is any indication, Obozo might not like the way they choose to return it.
Japan's response:
"Okay. As soon as you return all of Germany's gold."
Sounds good, doesn't it?
LOL Now THAT's funny!
The plutonium that is stored at a fast critical assembly in Tokaimura in Japan's Ibaraki prefecture could be used to produce 40-50 nuclear weapons>>>>>>>>>>>>>>>
And why shouldn't it be done? Obama has no intention of protecting Japan from China or North Korea.The Japanese know they are on their own, Obama has more or less betrayed every US ally during his 5 years in office.
Another way to say it:
Japan: "Okay, we'll return the plutonium... to be delivered 7 years from today".
Agree to give it back, but after January 2017. Let a new regime be in place, not Obama.
And Pakistan and North Korea and maybe even Saudi Arabia.
I suspect this is a pro-China move.
Excellent comment. Being an enemy pays big dividends during this regime.
I guess the Japanese aren't Muslim terrorists.
Yeah, but floating it back in Pacific currents one atom at a time probably wasn't what the Administration had in mind. :)
That Plutonium has probably already been used by Japan to make parts that when assembled are working nuclear weapons. Japan is next to two dangerous nuclear powers, Red China & North Korea, and needs the ability to respond to an attack in a credible manner. Due to Japan's WWII history, the country does not want to be known as a nuclear power, but having readily assembled parts is a prudent step. Israel denies having the A-bomb, but can have working nuclear weapons about as soon as it takes to hang one on a jet fighter-bomber.
As the article notes, Japan has 44 tons (roughly,nobody knows for sure) of plutonium and all the technology it needs to build warheads. I doubt they are worried too much about this particular shipment, but it might be embarrassing to admit it's been installed in warheads already.
My first thought as well.
If there were no other reason than not doing it because Barry wanted it, that would be good enough for me.
We have complete jackarses running the country. They reward our enemies and penalize our friends. You don't keep friends that way.
The ONLY reason Zero would not like Japan returning our nukes that way, is it would ruin his vacation spot.
Now if they returned them to the main land, he couldn't contain his joy.
That would set Red China back about 500 MILLION People, more or less.
I like it!
It's a trade to China in exchange for propping up the US Dollar.
You keep the Dollar as reserve currency, and we will take care of that pesky Japan for you by disarming it.
The Senkaku islands would be more easy to take.
That would barely be enough to make China mad. lol
Perfect response!
Why would Japan care whether Germany got its gold back, after all?
Japan needs to build nukes, as does Taiwan.
The US should stockpile U and Pu at Fort Knox (as these is likely no Au there anymore.).
I suspect this has something to do with Project Gojira...
Here, here.
Let them build some decent missiles and put the Chinese on watch.
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text:
Academy Award-winning director Ron Howard attends the American Film Market to meet with buyers and talk about his vision for his new film RUSH on behalf of Exclusive Media Group ("Exclusive").
Ray Romano, Jason Alexander, Cheryl Hines and Wendy Liebman entertain for Harvest Home charity
At Shakespeare Orange County, stage veterans Michael Nehring and Evelyn Carol Case drive this timeless play with class and comedic flair
One of Malibu's most anticipated events, The 8th Annual Miss Malibu USA Pageant, will be held at the prestigious Malibu Golf Club on Sunday, August 19, 2012 from 4pm-7pm
Goldstar is a free online discount ticket selling service
Project Angel Food will be hosting their 17th annual Angel Awards this Saturday evening where they will recognize Pauley Perrette, board member and star of the CBS hit "NCIS," for her philanthropic leadership and her deep commitment to those fighting HIV/AIDS. Chris Salgardo, President of Kiehl's Since 1851
The summer can't be complete without the 2012 Sunset Strip Music Festival and this year it is being headlined by; The Offspring, Marilyn Manson, Steve Aoki and Bad Religion. In addition to the two outdoor stages between San Vicente and Doheny, you will find vendors, VIP rooftop lounge, VIP areas in The Roxy and Key Club, beer garden, autograph tent and interactive experiences all day on The Strip
PAULEY PERETTE ("NCIS"), JACK OSBOURNE, RICHARD GRIECO ("21 Jump Street," "Booker"), TOMMY DAVIDSON ("In Living Color"), John Savage ("Deer Hunter"), Kevyn Major Howard ("Full Metal Jacket"), Lisa Rinna and Harry Hamlin ("Army Wives") top a long list of stars who will be on hand at Cops4Causes inaugural "Heroes helping Heroes" benefit on Tuesday, Sept. 11th at the just-opened hot spot, Pink Taco
Emmy and Golden Globe winning actor Beau Bridges will be honored with the Betty Garrett Lifetime Achievement Award at the 50th Anniversary Gala of Theatre West on Sept. 13th at the Taglyan Cultural Center in Hollywood
Paint collides with canvas live on stage, as masterpieces are born and torn down in a visceral experience that spills off the stage and forever changes the way you see red.
Gathering to break champagne against the bow of Fashion Week LA, Untapped PR presents Untapped Fashion and Music at SUR LOUNGE off Robertson from 7:30 – 11:30pm on September 19th, 2012
Mary Poppins is truly the first "Supernanny" of our times. Go see this current production at the Ahmanson Theatre, and you will see why!
Confidential and Art & Fashion Int. teamed to bring you beautiful models showing the lattes trends of four designers; France, Asia; Mexico, Australia and Venezuela
The celebrated HollyShorts Film Festival enters it's 8th year, and continues to selectively curate in-competition shorts, and play host to invaluable panels, award presentations, crowd pleasing parties, and oh much more
Dogs for the Deaf, Inc.'s mission is to rescue and professionally train dogs to help people and enhance lives, maintaining a lifelong commitment to all dogs we rescue and all people we serve.
On July 31st celebrities and elite music enthusiasts gathered rooftop to watch London born Grammy award winning singer-songwriter Estelle
Have your fortune told as you enjoy a Caribbean/Cajun meal and dance to period music
A Symphony of Hope: The Haiti Project is a fundraising dinner, silent auction, and world premiere live concert to benefit Hands Together
Every year in July The Saban Free Clinic hosts a food & wine festival Extravaganza for the Senses in Hollywood to raise funds for the Clinic from ticket sales, and their silent auction. Why this fab fest is not more known is beyond me
Scripted In Heaven book signing by Author Lourdes Duque Baron, MHA, MSG, is a Catholic baby boomer and the wife of Dr, Robinson V. Baron.


text:
$650 2 bed 2257 19th Ave, Rockford IL, 61104
Previously Listed $650 2 bed
2257 19th Ave, Rockford, 61104
Commute to Downtown Rockford
This apartment is in Rockford. Nearby parks include Southeast Park, Harmon Park and Churchill Park.
2257 19th Ave has a Walk Score of 25 out of 100. This location is a Car-Dependent neighborhood so most errands require a car.
Rockford Cozy 2 bedroom 1 bath duplex at the end of a dead end street. Rent is $650 a month, includes ALL utilities! First and Last months rent due at lease signing...Income verification required. Includes, eat in kitchen, living room,large yard and FREE in unit laundry. Plenty of off road parking. NO PETS! Serious inquiries only. Please contact Tosha 224-717-9042 Call/Text/Emails welcomed Paid Utilities, Washer and Dryer In Unit
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Rockford, Illinois, 61104
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2257 19th Ave is in the city of Rockford, IL. Rockford has an average Walk Score of 41 and has 152,871 residents.Learn More About Rockford


text:
Released: Aug 01st, 2005
Running Time: 112
Director: Jake Cruise
Company: Jake Cruise
Distribution Companies: AVNS Distribution, Inc.
Cast: Dick (II), Jake Cruise, Chris (II), Ethan
Critical Rating: AAA
Genre: Gay Specialty
Daddy Jake Cruise gets it on with three hot younger studs. There's toe- and cocksucking, but no fucking.
Jake Cruise, the hot daddy of the online massage table series, conducts more of his full body encounters with release in this production. The three naked young studs who enjoy Jake's ministrations are so squeaky-clean looking that any one of them could be the poster boy for an abstinence until marriage poster, making it all the more titillating when their cocks respond to Jake's kneading, licking, and stroking. Chris, a lean gay hunk with a killer grin, actually gets in on the action, sucking Jake's cock to orgasm near the end of their session, which also involves a lot of hot foot play - apparently one of Jake's personal fetishes, because some shrimping is included in each segment. Of the three subjects, brunet, buff Dick is perhaps the best looking, but unfortunately he's also the least responsive. All produce great pop-shots (which are repeated in slow motion so that every drip and spray of splooge are captured in riveting detail), but Ethan's is the most impressive, a huge gusher that erupts from his sizeable cock while he stares directly and hotly into the lens.


text:
Riley County citizens will vote in a special election Tuesday on a proposed $12.
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