text:
James Gregory Price to be Arraigned for Murder of Friend Accused of Burglary, Justin Soto
A man is scheduled to be arraigned this morning on charges he fatally shot a friend he'd believed had burglarized his Brea home.
James Gregory Price, 56, faces a murder count and sentencing enhancements that could send him to state prison for 50 years to life in the slaying of 24-year-old Justin Soto.
Justin Soto Identified by Readers as 25-Year-Old Shot to Death in Brea
(Note: Brea Police had said Soto was 25, but an Orange County District Attorney's office arraignment statement gives the victim's age as 24.)
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Price and his adult son were living in the Brea home of the older man's recently deceased mother. On March 15, the found the mother's bedroom, which had been closed to the home's occupants and guests, had been ransacked and the residence had been burglarized.
Prince and his son believed Soto was responsible, according to prosecutors, who claim the son invited Soto over on March 16. Price and Soto got into an argument at the home before the older man took out a gun and shot the younger man in the leg, according to the DA's office.
Soto fell to the ground, got himself back up and tried to run away, but Price murdered him by firing two shots into Soto's back, the DA alleges.
Price, who is being held on $1 million bail, faces felony murder with a sentencing enhancement for the personal discharge of a firearm causing death.
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That time of the week again! Last weeks image was a lot harder than expected, @KuzManDatNigga ruined a
There have been a lot of dope videos coming from Genius lately, and one of the most recent is a breakdown
The Genius forums are a place where everyone should feel comfortable to contribute knowledge and take
Did BG Knocc Out & Dresta really have respect for Dr. Dre and only diss him to show loyalty to Eazy-E
And they're really weak
Nowadays there are more sub-genres of rap than ever before. It has also become apparent to me that the
The piano melody in the chorus every time Andre sings "Never meant to make your daughter cry, I
Protip: You can't.
I can rap just as well as them and
read the whole thing and watch the vid
Idk what other albums are coming out. The last one I listened to was Blank Face. What's coming out that's
Need some projects that are quick listens but still enjoyable. Any suggestions?
I'm retiring . Throwing in the towel. Just not conducive to be on here no more lol. When was it ever
Hoping this group of RG users is more open minded and has
July, 2016 Update: hahaha i think i was drunk when i made this quality bait
~Eminem used to be mediocre
I will accentuate the rap albums
100 Kanye West 808s & Heartbreak (2008)
99 The Concretes The Concretes
ill be real i wanna see another amityville-esque song but with more mature, classic lyrics ya dig? even though hes been kinda doing more the pop/rap beats i think he should do some hardcore hip hop songs
I want to see at least one more incredibly controversial song, slim shady LP-esque
And yes i know how fanboy that sounds.
Eminem over trap beats
A remix of Without Me by 2pac
eminem not mention his daugher, ex, or mom it gets really annoying
Don't even care lol.
Some good production, no mom/ex-wife shit, and for Eminem to boast about his success for once and do at least one brag rap OR just make the whole album about celebrities and make fun of the industry
i dont even want to hear one at this point.
Something that actually resembles the Marshall Mathers LP.
dr dre production
mmlp2 would be near classic if it had dr dre production
yeah dre actually producing
Less poppy hooks
no love songs
I had this cool ass idea for a song where it was Em, Marshall, and Slim all having a conversation and conflicting amongst each other. I don't know how he'd go about it but i know it would be dope.
OH SHIT I forgot to say this. A song w/ Kendrick, but not them trying to be funny, like an actual fucking song.
In all seriousness a no rihanna feature. No club style song, I don't mind a radio friendly single but the monster was imo the worst song em has ever made, people may think I'm over exaggerating but I'm not.
Co-sign the guys who said better production too, if I was digging for a near perfect em album I'd say try to cut some of the corny punchlines, I dno if hes trying to be funny but they didn't make me laugh.
I liked mmlp2 and I sound really picky with all these faults but I'd also like him to chill a little on the beat with a few tracks too, his tone felt very aggressive on this album.
everyone keeps forgetting about the Bass Brothers
They produced like half of the first MMLP
and most of the SSLP
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|Publication number
|Publication type
|Application number
|Publication date
|Sep 23, 1980
|Filing date
|Apr 30, 1979
|Priority date
|Apr 30, 1979
|Publication number
|Lawrence P. Klemann, Eugene L. Stogryn
|Original Assignee
|Exxon Research & Engineering Co.
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (6), Non-Patent Citations (12), Referenced by (7), Classifications (7)
|External Links: USPTO, USPTO Assignment, Espacenet
ZBArm Rn Arx '
QHBArm Rn Arx '
ZBArm Rn Arx '
QHBArm Rn Arx '
1. Field of the Invention
The present invention relates to a method of preparing high purity, anhydrous, ether adducts of alkali metal salts of the organic-alkali metal-boron type. More particularly, the present invention is directed to the method of preparing such compounds by reacting specified nitrogen-containing compounds with specified alkali metal-containing compounds, as more fully developed below.
2. Description of the Prior Art
There have been many techniques developed over the past few years for the synthesis of organic-alkali metal-boron salts. For example, Kunze et al, J. Phys. Chem. 67, 385 (1963) describe the preparation of lithium tetraphenyl boride by the reaction of sodium tetraphenyl boride with lithium chloride in ethanol and Bhattacharyya et al, J. Phys. Chem. 69, 608 (1965) describe the preparation of alkali metal tetraphenyl boride salts by the reaction of sodium tetraphenyl boride with lithium chloride in THF solvent. Revzin et al, Chemical Abstracts 70, 28974 q (1969) and Chemical Abstracts 71, 3416 s (1969) describe the preparation of lithium tetraphenyl boride from various salts, including ammonium tetraphenyl boride with lithium-containing ion exchange resins in acetone. Likewise, Kirgintsev et al, Chemical Abstracts 72, 139078 m (1970) describe the formation of lithium tetraphenyl borate and sodium tetraphenyl borate using potassium tetraphenyl borate with an ion exchange resin of the lithium form and using acetone solvent. Kozitskii, Chemical Abstracts 79, 83825 c (1973) describe the preparation of lithium tetraphenyl borate and the like by reaction of the potassium analogue with a lithium-containing ion exchange resin in the presence of acetone and water. (It should be noted that various prior art references refer to the same compounds as tetraphenyl borate or as tetraphenyl borides.) Khol'kin et al, Chemical Abstracts 85, 86471 u (1976) describe the preparation of lithium tetraphenyl boride from sodium tetraphenyl boride but do not describe the source of lithium except to point out that it is an exchange synthesis, i.e. exchange extraction synthesis. Wittig et al, Ann 563 110 (1949) and Chemical Abstracts 46, 6607 d (1952) respectively teach the preparation of lithium tetraphenyl boride and the like from triphenyl boron and trifluoro boron sources reacted with lithium phenyl salt in ether solvents. Grassberger et al, Angew. Chem. Int. Ed. Engl. 8, 275 (1969) describe the preparation of various alkali metal tetraorganyl borates by reaction of, for example, triphenyl boron with lithium tetraethyl boride without solvent.
Lee, Inorg. Chem., Volume 3, No. 2, Feb. 1964, pp. 289-90 describes the synthesis of lithium thiocyanate from hydrated lithium hydroxide and ammonium thiocyanate. Olah et al, Journal of the American Chemical Society, 97, No. 12, pp. 3559-3561 (1975) describe the synthesis of LiO2 CCF3 from lithium hydride and NH4 O2 CCF3. Morosi et al, Chemical Physics Letters, Vol. 47, No. 2, pp. 396-398 (1977) describe a theoretical analysis of a hypothetical reaction between the ammonium ion and lithium hydride in the gas phase to yield lithium salts. U.S. Pat. No. 3,049,406 describes the preparation of anhydrous lithium salts, including lithium halides, lithium pseudohalides, such as lithium cyanide and lithium thiocyanate, by the reaction of lithium hydride with halogens, cyanogen or thiocyanogen in an ether solution.
Notwithstanding all of the aforementioned prior art directed to various methods of preparing alkali metal salts, to date no reference has been published which teaches or renders obvious the method of preparation described herein.
The present invention is directed to a method of preparing an ether adducts of organic-alkali metal-boron salt of the formula:
ZBArm Rn Arx ' (1)
wherein Z is an alkali metal selected from the group consisting of lithium and sodium, wherein B is boron, wherein Ar is an aromatic organic radical selected from a specified group of cyclic radicals, wherein R is an organic radical selected from methyl and ethyl, wherein Ar' is an aromatic organic radical selected from the group consisting of specified divalent dicyclic radicals, wherein m is a numerical value such that 0≦m≦4, wherein n is a numerical value such that 0≦n≦2, and wherein x is a numerical value such that 0≦x≦2, subject to the proviso that the sum of m and n and x is such that the total valence of the organic radicals Ar, R and Ar' equals four.
The method involves the reaction of a nitrogen-containing compound of the formula:
QHBArm Rn Arx ' (2)
wherein Q is selected from the group consisting of specified nitrogen-containing groups, and wherein all other variables are as defined above, with an alkali metal compound of the formula: ZX Wherein Z is defined above and wherein X is selected from the group consisting of hydrogen, specified nitrogen containing radicals, any Ar as defined above and any R as defined above. The reaction is carried out in ether solvent.
The present invention is directed to a method of preparing an ether adduct of organic-alkali metal-boron salt of the Formula (1) described above, namely:
ZBArm Rn Arx '
wherein Z is an alkali metal selected from the group consisting of lithium and sodium, wherein B is boron, wherein Ar is an aromatic organic radical selected from the group consisting of --C6 H5 ; --C6 H4 --p--CH3 ; --C6 H4 --p--F; --C6 H4 --m--F; --C6 H4 --p--CF3 ; --C6 H4 --CF3 ; --C6 H4 --o--CF3 ; ##STR1## --C6 F5, wherein R is an organic radical selected from the group consisting of --CH3 and --C2 H5, wherein Ar' is an aromatic organic radical selected from the group consisting of ##STR2## and ##STR3## wherein m is a numerical value such that 0≦m≦4, wherein x is a numerical value such that 0≦x≦2 subject to the proviso that the sum of m and n and x is such that the total valence of the organic radicals Ar, R and Ar' equals four.
Included among the alkali metal salts which may be prepared by the present invention are:
LiB(C6 H5)4
LiB(C6 H4 --p--F)4
LiB(C6 H4 --p--CF3)4
LiB(C6 H4 --m--CF3)4
LiBCH3 (C6 H5)3
LiB(C2 H5)2 (C6 H4 --p--F)2
LiB(CH3)3 C6 H5 ##STR4##
In addition to the foregoing specific salts, it is now seen that the generic formula above also encompasses the sodium analogues of the foregoing as well as various homologues and other similar compounds as included in Formula (1).
The method of the present invention involves reacting a nitrogen-containing compound of the formula:
QHBArm Rn Arx ' (2)
wherein Q is selected from the group consisting of NH3 ; HN(CH3)2 ; H2 NCH3 ; N(C2 H5)3 ; HN(C2 H5)2 and H2 NC2 H5, and wherein all other variables are as defined above, with an alkali metal compound of the formula:
wherein Z is as defined above and wherein X is selected from the group consisting of H; NH2 ; N(CH3)2 ; HNCH3 ; N(C2 H5)2 ; HNC2 H5 ; N(--CH(CH3)2)2 ; any Ar as defined above and any R as defined above, in ether solvent such as dioxolane, dimethoxyethane, diglyme, tetrahydrofuran, tetrahydropyran, dioxane, diethyl ether, etc.; as well as mixtures thereof.
Desirably, the variable Q in Formula (2) is selected from the group consisting of NH3 and the mentioned tertiary amines, and is preferably NH3. Also, desirably n in Formula (2) is zero or one and most desirably is equal to zero. Also, desirably, Ar is selected from the group consisting of --C6 H5 ; --C6 H4 --p--F; --C6 H4 --p--CH3 ; --C6 H4 --p--CF3 ; ##STR5## --C6 H4 --m--F; and--C6 F5. Preferably, Ar is --C6 H5.
In the alkali metal compound of the formula:
the variable Z is lithium or sodium and is preferably lithium. Also, the variable X is desirably hydrogen, NH2 ; N(CH3)2 and HNCH3. Preferably, the variable X is hydrogen or NH2.
Among the cyclic and acyclic ether organic solvents which are useful in the present invention, dimethoxyethane, dioxolane, tetrahydrofuran, diethylether, tetrahydropyran and dioxane are desirable and dimethoxyethane, dioxolane and diethylether are preferred.
In performing the synthesis of the present invention the nitrogen-containing compound of Formula (2) is reacted with the alkali metal compound of Formula (3) in ratios so as to achieve a desirable amount of reaction product. Although it is not essential to the process, it is particularly advantageous to combine these two reactants so as to have a stoichiometric excess of the alkali metal compound of Formula (3). Concerning the solvents, it is desirable but not essential that adequate solvent be used so as to dissolve all of the desired reactant materials. In general, at least about 0.5 to about 50 milliliters of solvent per 1.0 gram of total reactants is useful. Preferably, at least about 2 to about 20 milliliters of solvent per 1.0 gram of total reactants may be used.
These reactions may be carried out at any operable pressure and temperature, and room temperature and pressure conditions will allow these reactions to readily occur in most instances. It may also be advantageous to pass an inert gas such as N2, He, or Ar through or over the condensed reaction mixture so as to purge by-products including H2 and volatile amines. In some instances, it is preferable to employ elevated temperatures, especially at reflux temperatures of the solvent-reactant systems. For example, reaction temperatures in the range of about 0� C. to about 175� C. may be used.
By the process of the present invention, significant advantages are achieved over prior art synthesis techniques. For example, by using the method of the present invention, anhydrous lithium salts may be obtained without requiring additional finishing steps to remove water. Also, the organic-alkali metal-boron salts produced may be used in situ in their solvent solution, or they may be isolated in solid form by conventional separation techniques. Further, using the ZX type reactant, the need to carefully control the stoichiometric ratio of the reactants is eliminated. Due to the very limited solubility of some of these ZX type reactants, excess may be used and only that which is stoichiometrically required by the reaction actually dissolves and is consumed. The presence of excess ZX serves as a gettering agent capable of removing from the solvent traces of water which are often considered undesirable for alkali metal salt solutions. This added benefit insures an anhydrous solution which may be useful directly in high purity applications, e.g. as electrolytes in alkali metal anode batteries.
The present invention is illustrated in detail by the following examples. However, these examples are presented for illustrative purposes only and the invention should not be construed to be limited thereto.
Twenty grams of sodium tetraphenylboride in 500 millileters of distilled water were added to 470 milliliters of concentrated ammonium hydroxide with vigorous stirring. After 15 minutes, the solid was filtered and vacuum dried to yield approximately 17.2 grams of solid material (about 87%). The product, NH4 B(C6 H5)4, was then suspended in 80 milliliters of dioxolane containing about 1.6 grams of lithium hydride. This amount of lithium hydride constituted over 4 times the stoichiometric amount. This mixture was then heated and hydrogen and ammonia gases were evolved. After heating at reflux for about 4 hours, the mixture was allowed to cool and was filtered under a nitrogen blanket. The filtrate was then concentrated in a vacuum and then heated at atmospheric pressure and allowed to slowly cool. By this procedure, about 22.8 grams of clear, colorless crystals were obtained. Analysis of a dimethoxyethane solution of these crystals by NMR revealed that the crystals were a solvated composition of (dioxolane)4 LiB(C6 H5)4. A lithium analysis showed about 1.06 percent lithium (theory, about 1.11%). The crystals contained about 0.022 wt% sodium. In order to confirm that the product obtained was anhydrous, a solution was prepared by dissolving 18.4 grams (approximately 29 mole) of the crystalline product and 5.5 grams of dimethoxyethane and about 15.1 grams of dioxolane. A Karl Fischer analysis was performed on the solution and showed that it contained less than 10 parts per million of water.
Solvated, anhydrous lithium borate salts of Examples 2-12 were prepared according to the method given in Example 1. The appropriate reactants, their quantities and the composition of the final lithium borate salt are presented in Table 1, below.
TABLE I__________________________________________________________________________ ##STR6##ExampleQ Ar m g LiH,g Solvate*, mL z mp,�C.__________________________________________________________________________2 NH3 p-CF3 φ 4 45.2 2.94 A,440 4 155-83 NH3 p-CF3 φ 4 86 4.5 B,600 3 111-44 NH3 p-CF3 φ 4 72.1 4.73 C,282 3 166-85 NH3 m-CF3 φ 4 77.5 3 B,300 3 80-36 NH3 m-CF3 φ 4 104.4 6.9 C,500 3 111-27 (CH3)3 N p-Fφ 4 16 1.8 A,100 4 128-318 NH3 p-Fφ 4 250 24 A,900 4 128-319 NH3 p-Fφ 4 125 12 C,400 3 111-210 NH3 2-Thienyl 4 72.2 6.4 C,250 3 96-9811 (CH3)3 N 2-Thienyl 4 35 3.42 A,500 4 140-512 (CH3)3 N ##STR7## 2 5.4 0.58 A,60 4 --__________________________________________________________________________ *Legend: A = Dioxolyne B = Diethyl ether C = Dimethoxyethand
NH4 B(C6 H5)4 (114 g, 0.34 mole) and 600 mL of dimethoxyethane (distilled from Na, benzophenone) were combined in a 1000 ml flask containing a magnetic stirrer bar and fitted with a thermometer, reflux condenser and nitrogen inlet. A glass adapter, attached by a short length of Gooch tubing to a 125 mL Erlenmeyer flask (containing 10 g, 1.3 mole, LiH) is fitted to the flask and the solid LiH is added with vigorous stirring over 20 minutes. During this addition, gas (H2 and NH3) is evolved through a bubbler in the nitrogen line and the temperature of the reaction mixture rises to about 45� C. After this addition is complete, the mixture is warmed to achieve reflux for four hours. The mixture is then cooled, filtered to remove excess LiH, and the filtrate is concentrated to about 275 mL on a vacuum rotary evaporator. The concentrated solution is warmed to about 80� C. and is transferred to a glass-stoppered Erlenmeyer flask. Cooling of this solution to about -20� C. results in crystallization of the product which is isolated by filtration and dried to afford 175 g (86% yield) of (dimethoxyethane)3 LiB(C6 H5)4 as white crystals. The ratio of dimethoxyethane to anion is established by proton nmr of the product dissolved in dioxolane, and by elemental analysis:
Calculated for (dimethoxyethane)3 LiB(C6 H5)4, MW 596.556:
C 72.48%, H 8.45%, Li 1.16%; Found: C 72.57%, H 8.38%, Li 1.10%.
To a 100 mL flask, fitted with a magnetic stirring bar, reflux condenser, N2 inlet, and dropping funnel were charged 6.74 g (20 mole) NH4 B(C6 H5)4 and 50 mL of diethyl ether. Under N2 and with cooling to -50� C. a solution of phenyllithium (12 mL, 1.7 M in ether-benzene) was added dropwise over 10 minutes. The slurry was allowed to warm to room temperature and then was heated at reflux for about 10 hours. The mixture was cooled, filtered and the solid residue was dissolved in a minimum amount of warm dioxolane. About 0.6 g of insoluble material (probably unreacted NH4 B(C6 H5)4) was removed by filtration. Upon cooling the dioxolane solution to about 0� C., white crystals were deposited. The crystals (1.5 g) were isolated and addition of pentane to remaining dioxolane solution produced an additional 8.8 g of product.
The product was characterized by nmr (˜4/1 ratio of dioxolane/B(C6 H5)4 --), and by elemental analysis. Calculated for (dioxolane)4 LiB(C6 H5)4, MW 622.508: C 69.46%, H 7.12%, N ˜0%. Found: C 69.41%, H 7.01%, N 0.59%.
The trace of nitrogen in the product is believed to be due to LiNH2 (about 1%) formed by a side reaction between phenyllithium and ammonia. The total yield of product was 10.3 g or 91% of theory for (dioxolane)4 LiB(C6 H5)4. This example demonstrated that phenyllithium can be used to deprotonate NH4 +ion and thereby form LiB(C6 H5)4 from NH4 B(C6 H5)4.
|Cited Patent
|Filing date
|Publication date
|Jun 1, 1954
|Sep 23, 1958
|Georg Wittig
|Process of producing sodium tetraphenylboron
|Nov 3, 1958
|Jul 5, 1960
|Ethyl Corp
|Sodium tetraethylboron
|Dec 29, 1958
|Sep 25, 1962
|Ethyl Corp
|Production of metal organoboron compounds
|Dec 29, 1958
|Sep 25, 1962
|Ethyl Corp
|Preparation of metal organoboron compounds
|Nov 30, 1962
|Mar 28, 1967
|American Potash & Chem Corp
|Tetraarylboron compounds
|Sep 2, 1977
|Jan 16, 1979
|E. I. Du Pont De Nemours And Company
|Process for producing a metal hydroxide adduct of a triarylborane
|Angen. Chem. Int. Ed. Engl. 8 275 (1969).
|Bhattacharyya et al., J. Phys. Chem. 69 608 (1965).
|Chemical Abstracts 46 6607d (1952).
|Chemical Abstracts 53 936b (1959).
|Chemical Abstracts 54 2671i (1960).
|Chemical Abstracts 70 28974q (1969).
|Chemical Abstracts 71 3416s (1969).
|Chemical Abstracts 72 139078m (1970).
|Chemical Abstracts 79 83825c (1973).
|Chemical Abstracts 85 86471 (1976).
|Kunze et al., J. Phys. Chem. 67 385 (1963).
|Wittig et al., Ann 563 110 (1949).
|Citing Patent
|Filing date
|Publication date
|Jun 6, 1995
|Feb 4, 1997
|Idemitsu Kosan Co., Ltd.
|Process for producing tetrakisflorophenylborate
|Mar 9, 1998
|Apr 10, 2001
|Nippon Shokubai Co., Ltd.
|Method for purifying tetrakis (fluoroaryl) borate/magnesium halide, tetrakis (fluoroaryl) borate/ether complex and process for preparing the same, and process for preparing tetrakis (fluoroaryl) borate derivative
|Feb 9, 2001
|Apr 30, 2002
|Nippon Shokubai Co., Ltd.
|Purifying process of tetrakis(fluoroaryl)borate.magnesium halide, tetrakis(fluoroaryl)borate�ether complex and producing process of the same, and producing process of tetrakis(fluoroaryl)borate derivative
|Feb 13, 1999
|Aug 20, 2002
|Targor Gmbh
|Compounds having an ionic structure used as constituent of an olefin polymerization catalyst
|Dec 21, 2001
|Sep 23, 2003
|Nippon Shokubai Co., Ltd.
|Purifying process of tetrakis (fluoroaryl) borate�magnesium halide, tetrakis (fluoroaryl) borate�ether complex and producing process of the same, and producing process of tetrakis (fluoroaryl) borate derivative
|Mar 9, 1998
|May 6, 1999
|Nippon Shokubai Co., Ltd.
|Method for purifying tetrakis(fluoroaryl) borate/magnesium halide, tetrakis(fluoroaryl) borate/ether complex and process for preparing the same, and process for preparing tetrakis(fluoroaryl) borate derivative
|Feb 13, 1999
|Sep 2, 1999
|Targor Gmbh
|Compounds having an ionic structure used as constituent of an olefin polymerisation catalyst
|U.S. Classification
|568/6, 549/213, 548/405, 549/4
|International Classification
|Cooperative Classification
|European Classification


text:
Are there are good in-memory transactional databases that support LINQ and SQL Server persistance? I'd like to create a full representation of a large data store in memory and have it commit to a SQL Server Database in a lazy fashion, but still keep some level of fault tolerance by scaling it out horizontally. I don't want to rely on non-relational datagrams like CouchDB.
Announcing Stack Overflow Documentation
We started with Q&A. Technical documentation is next, and we need your help.
Whether you're a beginner or an experienced developer, you can contribute.
SQLite supports in-memory databases has transaction support and has a Linq provider as well.
As for the SQL Server persistance, I think you would be on your own to code up something for doing lazy transfers to a backing SQL Server database.
SQL Server with an ORM tool and possibly a caching solution.


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Minky Monday: Take 20% off 1+ Yards of Minky fabric through 11:59 p.m. EDT July 25th.
Preview scale: 21.0 x 18.0 inches

Change DPI Base size is 150
Designs by heatherross
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Boulder, COUSA
June 26, 2014
Professional Nerd
Help support your Meetup
This is a casual meetup for runners of all shapes and speeds that would like to run with other people. I am sure you can find some running partners in the group and hope to see you on some runs soon!
15% discount for Longmont Running runners.
10% Discount on Running Shoes! They have great brands for runners!
15 % off of total bill for Longmont Running runners.
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The proliferation of digital channels opens up new opportunities for businesses that want to deepen relationships with existing clients and attract new customers. Social media platforms and the widespread use of mobile devices provide an affordable way to push out a steady stream of content to always-connected consumers and generate new business. However, many companies that are making the change from print-centric communication to digital content are finding that the transition isn't simple. The processes that are in place for creating, approving, publishing, distributing and tracking print-centric content don't scale when faced with omni-channel digital content.
Dec 09, 2010
Amazon announced that its Kindle for the Web app will enable users to buy and read full Kindle books-no download or installation required. Bookstores and other retailers, authors, bloggers, and other website owners will be able to offer their readers the full text of Kindle books from their sites and will earn referral fees through the Amazon Associates Program for sales made through their sites. Website owners can embed the Kindle for the Web widget to offer Kindle books.
Kindle for the Web is compatible with iPad, Macs, PCs, BlackBerries, and Android-based devices that let customers read and sync their reading libraries, bookmarks, notes, and highlights with the device or platform of their choice.


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Man…I love her…is she childish ? XD …
Comment on Shokotan Cosplay Idol Gallery by Anonymous:
man…I love her…is she childish ? XD
Anonymous made other comments on this post:
- Shokotan Cosplay Idol Gallery:
and so can anybody and anything else.
- Shokotan Cosplay Idol Gallery:
Gorgeous, A perfect spinner! I would pick her up, set her on my dick and proceed to ruin that pussy! Damn she's cute.
- Shokotan Cosplay Idol Gallery:
She is very beatifull, great pictures, good photographer too.
- Shokotan Cosplay Idol Gallery:
This woman is fine.. Way better than 2d, you can fuck this version!
- Shokotan Cosplay Idol Gallery:
For some reason, I think of her as an japanese Felicia Day. Only on some pictures.
Recent comments by Anonymous:
- Yandere Simulator More Evil Than Ever:
Yeah, there were a couple of MythBuster episodes about how hard it is to beat bloodhounds (and their handlers). Red herring schemes like using a dead kitten as a distraction generally don't work.
- Feisty Felt Cosplay Beautifully Blonde:
who's the cosplayer? can't find anything on image search
- Keijo PV "Glorifies Breasts & Butts!":
I like to think of Keijo as a parody towards the sports genre, where players use some godly sports power and treat things as if it were a gladiator battle. Just think of it as Hajime no Ippo replaced with butts and boobs instead, while still keeping the tension Ippo had.
- Bully Girl S*x Slave "A Tale of Revenge!":
Narusegawa Naru is still queen of the sweater breasts, I have not been turned on by any other sweater breasts as much before or since her.
- Final Fantasy XII HD Footage Unveiled:
My body is ready. That fast speed system I somehow feel like it was in the original, not sure why though. If not I agree, that addition is excellent to speed up the gameplay.


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Brigantine Pirate Sword
The Brigantine was a powerful type of ship that was highly sought after by pirates. It was a roughly 150 ton ship, capable of carrying from 10-12 guns and a crew of up to 100 men. These ships were for big-boy pirates who didn't have to hide or run from their enemies. Sometimes called "skirmish ships," the Brigantines were made for combat, and it was a brave or powerful pirate who commanded one. Brigantines were also occasionally used by the Royal Navy to hunt down pirates, but for the most part, pirate hunting ships usually were a little larger still. Regardless, the larger Brigantines could gobble up the more common sloops like hor doeuvres (mental note: never use.....read more


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Three-quarters of schools and districts implementing mobile devices are doing so in specific grades or content areas rather than as part of 1:1 computing initiatives, according to a new survey from Mimio.
Although 78 percent of respondents told researchers they "anticipate that mobile devices will be useful tools for the Common Core assessments in the 2014-15 school year," most, 74 percent, reported that they use the devices for both instruction and assessment.
Other key findings of the survey include:
"This latest survey confirms that the use of mobile devices is not a fad," stated Manny Perez, president and chief operating officer, Mimio. "It's a real paradigm shift in the way educational technology supports learning. Right now, we're seeing that mobile devices are being used more as test phases or pilots for certain grades or content areas. However, according to 69 percent of respondents, over the next two years we should see mobile-device use expand across school grades and content areas."
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Joshua Bolkan is the multimedia editor for Campus Technology and THE Journal. He can be reached at firstname.lastname@example.com.
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A rapidly growing district, Berkeley was getting ready to open a new middle school for the 2014 school year – their third new school in four years. Among their numerous responsibilities related to the new school, the technology department needed to select and deploy interactive displays for 45 new classrooms. The tech team had experience with many types of interactive technology, with every classroom in the district using some type of interactive device, including interactive projectors and dual-touch interactive white boards (IWBs) using short-throw projectors. This time around they were hoping to find something different.
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...My classes focus on mastering all skills and the methods are meaningful and relevant to the age of the student I tutor.All levels of high school Spanish, including AP,IB and Honors courses. All levels of college Spanish. Spanish for children (pre-reading). I am a certified college consultant and a Professional Member of IECA.
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Cos Cob, CTView Tutor
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Wantagh, NYView Tutor


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Amazing service- great communication and products. Thank you for making our vacation great!
Quick, easy and great service. Made my trip that much better.
This is the best idea if you re going to Disney, since all Resort Rooms have a refrigerator in them and will be a great idea for the breakfast items, , we took 17 family members to Disney for a week and it was great to have in the morning or a bottle of wine that was chilled for a late night cool down


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مقاطع سكس لواط عربي Don�t go rushing to your rock encyclopedias for confirmation that any of this is not scrupulously factual.Lucky for him he�s resilient and he came back and led us to two scoring drives.
سكس بنات اسرائيل So we hear that Lil Wayne and singer, Nivea, are not engaged to be married.Grossman appeared in a press conference after the game, where he remarked �Shit happens� to a crowd of spectators. On payday a plantation owner refuses to give a laborer his full wages simply for the pleasure of humiliating him.Nivea toured the US, appearing in clubs and concert venues, with dancers including Julianne Stevens and Sheena Knight, with the choreography of Sakinah LeStage.
مقاطع سكس لواط عربي The injury forced Grossman to spend the remainder of the season recuperating.Grossman missed most of the 2005 season after breaking his ankle in a preseason game. سكس جماع The couple took out dueling restraining orders. Sapphire also dons a Zorro-style mask at night and fights crime as the Phantom Knight. سكس جماع But man, it�s tough.`` Lovie Smith named Grossman the team`s starting quarterback for the Bears next contest against the Tennessee Titans.
Nivea was not married to R&B sensation, �The Dream�, but shortly after having their baby, the marriage failed, and the two are not in the middle of a divorce.After becoming the princess of Silver Land, Sapphire marries Frantz/Frank, her love interest in the first series, and gives birth to the twins Prince Daisy and Princess Violetta.


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Foursquare © 2016 Lovingly made in NYC & SF
C'est Si Bon
Bakery · $$
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Fashion Island
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Apple Store, Fashion Island
1113 Newport Center Drive (In Fashion Island Mall)
"If you have an OS upgrade book at least 3 appts. in a row. You can book them online."
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Make sure your information is up to date. Plus use our free tools to find new customers.


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Sony Mavica FD-81 review
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Sony Mavica FD-81 review
Nov 18, 2001 • Review of Sony Mavica FD-81
answer for Fernando --C:13 error code tells you the unformatted disc or bad disc is in camera.
1 megapixels • 2.5″ screen • 37 – 111 mm (3×)
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Manufacturing and Economy of Machinery
Steel Making
Manufacturing and the Economy of Machinery
Distinction Between Making And Manufacturing
163. The economical principles which regulate the application...
On Combinations Amongst Masters Or Workmen Against Each Other
353. There exist amongst the workmen of almost all classes, ...
On The Division Of Labour
217. Perhaps the most important principle on which the econo...
On Combinations Of Masters Against The Public
376. A species of combination occasionally takes place among...
Accumulating Power
20. Whenever the work to be done requires more force for its ...
On The Future Prospects Of Manufactures As Connected With Science
453. In reviewing the various processes offered as illustrat...
On The Method Of Observing Manufacturies
160. Having now reviewed the mechanical principles which reg...
On A New System Of Manufacturing
305. A most erroneous and unfortunate opinion prevails among...
Of Raw Materials
210. Although the cost of any article may be reduced in its ...
On Over Manufacturing
284. One of the natural and almost inevitable consequences of...
On The Effect Of Taxes And Of Legal Restrictions Upon Manufactures
414. As soon as a tax is put upon any article, the ingenuity ...
Proper Circumstances For The Application Of Machinery
329. The first object of machinery, the chief cause of its e...
On The Causes And Consequences Of Large Factories
263. On examining the analysis which has been given in chapt...
Increase And Diminution Of Velocity
32. The fatigue produced on the muscles of the human frame d...
On The Effect Of Machinery In Reducing The Demand For Labour
404. One of the objections most frequently urged against mac...
Extending The Time Of Action Of Forces
45. This is one of the most common and most useful of the em...
Of Copying By Casting
105. The art of casting, by pouring substances in a fluid st...
Printing From Surface
91. This second department of printing is of more frequent a...
On The Duration Of Machinery
340. The time during which a machine will continue to perform...
Registering Operations
65. One great advantage which we may derive from machinery is...
On The Method Of Observing Manufacturies
On the domestic and political economy of manufactures
160. Having now reviewed the mechanical principles which
regulate the successful application of mechanical science to
great establishments for the production of manufactured goods, it
remains for us to suggest a few enquiries, and to offer a few
observations, to those whom an enlightened curiosity may lead to
examine the factories of this or of other countries.
The remark--that it is important to commit to writing all
information as soon as possible after it is received, especially
when numbers are concerned--applies to almost all enquiries. It
is frequently impossible to do this at the time of visiting an
establishment, although not the slightest jealousy may exist; the
mere act of writing information as it is communicated orally, is
a great interruption to the examination of machinery. In such
cases, therefore, it is advisable to have prepared beforehand the
questions to be asked, and to leave blanks for the answers, which
may be quickly inserted, as, in a multitude of cases, they are
merely numbers. Those who have not tried this plan will be
surprised at the quantity of information which may, through its
means, be acquired, even by a short examination. Each manufacture
requires its own list of questions, which will be better drawn up
after the first visit. The following outline, which is very
generally applicable, may suffice for an illustration; and to
save time, it may be convenient to have it printed; and to bind
up, in the form of a pocket-book, a hundred copies of the
skeleton forms for processes, with about twenty of the general
Outlines of a description of any of the mechanical arts ought to
contain information on the following points
Brief sketch of its history, particularly the date of its
invention, and of its introduction into England.
Short reference to the previous states through which the
material employed has passed: the places whence it is procured:
the price of a given quantity.
[The various processes must now be described successively
according to the plan which will be given in (161); after which
the following information should be given.]
Are various kinds of the same article made in one establishment,
or at different ones, and are there differences in the processes?
To what defects are the goods liable?
What substitutes or adulterations are used?
What waste is allowed by the master?
What tests are there of the goodness of the manufactured
The weight of a given quantity, or number, and a comparison
with that of the raw material?
The wholesale price at the manufactory? (L s. d.) per ( )
The usual retail price? (L s. d.)
Who provide tools? Master, or men? Who repair tools? Master,
or men?
What is the expense of the machinery?
What is the annual wear and tear, and what its duration?
Is there any particular trade for making it? Where?
Is it made and repaired at the manufactory?
In any manufactory visited, state the number ( ) of
processes; and of the persons employed in each process; and the
quantity of manufactured produce.
What quantity is made annually in Great Britain?
Is the capital invested in manufactories large or small?
Mention the principal seats of this manufacture in England;
and if it flourishes abroad, the places where it is established.
The duty, excise. or bounty, if any, should be stated, and
any alterations in past years; and also the amount exported or
imported for a series of years.
Whether the same article, but of superior, equal, or inferior
make, is imported?
Does the manufacturer export, or sell, to a middleman, who
supplies the merchant?
To what countries is it chiefly sent? and in what goods are
the returns made?
161. Each process requires a separate skeleton, and the
following outline will be sufficient for many different
Process ( ) Manufacture ( )
Place ( ) Name ( )
date 183
The mode of executing it, with sketches of the tools or
machine if necessary.
The number of persons necessary to attend the machine. Are
the operatives men. ( ) women, ( ) or children? ( ) If mixed,
what are the proportions?
What is the pay of each? (s. d.) (s. d. ) (s. d.) per ( )
What number ( ) of hours do they work per day?
Is it usual, or necessary, to work night and day without
stopping? Is the labour performed by piece--or by day-work?
Who provide tools? Master, or men? Who repair tools? Master,
or men? What degree of skill is required, and how many years' ( )
The number of times ( ) the operation is repeated per day or
per hour?
The number of failures ( ) in a thousand?
Whether the workmen or the master loses by the broken or
damaged articles?
What is done with them?
If the same process is repeated several times, state the
diminution or increase of measure, and the loss, if any, at each
162. In this skeleton, the answers to the questions are in
some cases printed, as Who repair the tools?--Masters, Men; in
order that the proper answer may be underlined with a pencil. In
filling up the answers which require numbers, some care should be
taken: for instance, if the observer stands with his watch in his
hand before a person heading a pin, the workman will almost
certainly increase his speed, and the estimate will be too large.
A much better average will result from enquiring what quantity is
considered a fair day's work. When this cannot be ascertained,
the number of operations performed in a given time may frequently
be counted when the workman is quite unconscious that any person
is observing him. Thus the sound made by the motion of a loom may
enable the observer to count the number of strokes per minute,
even though he is outside the building in which it is contained.
M. Coulomb, who had great experience in making such observations,
cautions those who may repeat his experiments against being
deceived by such circumstances: 'Je prie' (says he) 'ceux qui
voudront les repeter, s'ils n'ont pas le temps de mesurer les
resultats apres plusiers jours d'un travail continu, d'observer
les ouvriers a differentes reprises dans la journee, sans qu'ils
sachent qu'ils sont observes. L'on ne peut trop avertir combien
l'on risque de se tromper en calculant, soit la vitesse, soit le
temps effectif du travail, d'apres une observation de quelques
minutes.' Memoires de l'Institut. vol. II, p. 247. It frequently
happens, that in a series of answers to such questions, there are
some which, although given directly, may also be deduced by a
short calculation from others that are given or known; and
advantage should always be taken of these verifications, in order
to confirm the accuracy of the statements; or, in case they are
discordant, to correct the apparent anomalies. In putting lists
of questions into the hands of a person undertaking to give
information upon any subject, it is in some cases desirable to
have an estimate of the soundness of his judgement. The questions
can frequently be so shaped, that some of them may indirectly
depend on others; and one or two may be inserted whose answers
can be obtained by other methods: nor is this process without its
advantages in enabling us to determine the value of our own
judgement. The habit of forming an estimate of the magnitude of
any object or the frequency of any occurrence, immediately
previous to our applying to it measure or number, tends
materially to fix the attention and to improve the judgement.
Distinction Between Making And Manufacturing
Of Copying With Altered Dimensions
Viewed 1073


text:
Janet Napolitano Confirmed as Homeland Security Secretary; Jan Brewer to Take Oath as New Governor on Wednesday
It will be interesting for Arizonans to see how the soon-to-be ex-governor handles this important position, especially the issue of illegal immigration. Barack Obama's decision to pick her for the job has been criticized on a number of fronts.
Napolitano's confirmation came as part of a package deal with six other Cabinet members; the Senate is expected to vote tomorrow on the confirmation of Hillary Clinton as Secretary of State.
Napolitano's resignation is expected any minute now.
The new governor, Jan Brewer (below), will take her oath of of office Wednesday about 3 p.m. at the State Capitol.
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TicketsMon., Aug. 22, 6:40pm
Arizona Diamondbacks vs. Cincinnati Reds
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All You Can Eat Value Pack - Mercury v Wings
TicketsFri., Aug. 26, 7:00pm
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text:
Today's Red Sox 2009 Opening Day game at Fenway Park has been postponed due to the forecast of heavy rain throughout the afternoon and evening. The game is rescheduled for Tuesday, April 7, at 4:05 p.m. to better accommodate fans who must reschedule. Opening Day festivities now will take place on Tuesday. Gates will open at 2:05 p.m.
The forecast provided by the Red Sox weather service, Meteorlogix, indicates heavy rain, strong winds and possible thunderstorms will begin during the early afternoon hours and continue throughout the evening.
"After consulting with our weather service and other professional meteorologists, it became apparent it would be extremely unlikely, if not impossible, that we could get a complete game in today so the decision was made to postpone until Tuesday," said Larry Lucchino, President/CEO. "Our fans look forward to this unofficial Red Sox Nation holiday each year, and we want to make sure that they are able to enjoy the full experience including both the special pregame ceremonies and a full nine innings of play. We reserved an alternate rain date for tomorrow for just such adverse circumstances as present themselves today."
It marks the first Red Sox home-opening postponement since 2003, when the game was called because of rain.
Tickets for Monday's opener will be good on Tuesday, April 7.
NESN, WEEI and SBN (WWDJ 1150 AM) will carry the rescheduled 4:05 pm game.
The Red Sox and Rays are scheduled to play the second game of the series on Wednesday at 7:10 pm at Fenway Park.
The Red Sox Foundation Welcome Home Dinner Presented By Covidien will take place as scheduled at the House of Blues Boston. Doors open at 5:30 p.m. and the program begins at 6:00 p.m.
Dale, Michael and Jerry dig into the details of this draft for the Patriots with ESPN's Mike Reiss.
Giardi and Price discuss the Tom Brady appeal getting overturned and Roger Goodell's victory tour. The guys can't believe the victory lap and some of his behavior. The more you listen to him, the more frustrating his behavior becomes.
Giardi and Price break down how the teams in the AFC East altered their futures after the NFL Draft weekend.
Sam Packard is joined by Celtics 2nd Round draft pick Abdel Nader to discuss his path to the the NBA and how he plans to improve his game. Sam then talks to Player Development Coach Nick Friedman from Elite Skills Training, the pre-Draft camp Nader attended. Friedman also gives his opinion on the Celtics performance at summer league and the development of Jaylen Brown.
Isaiah Thomas talks to Glenn and Lou about why he loves Boston, the NBA Money Bump, oh, and some Durant guy
Danny Ainge joins Glenn and Christian to explain the Celtics draft process; and he also discusses the trade rumors that permeated the night.
Christian recaps the Sox 2-1 loss to the Twins. Eduardo Rodriguez had a good showing tonight but couldn't get the run support needed to secure a W. Thoughts on all of that as well as your calls on Red Sox Review.
Red Sox Starting Pitcher Steven Wright joins Glenn, John Tomase, and Tom Caron to discuss pitching the knuckler in adverse conditions, his journey through MLB, and his All-Star experience.
The final hour of RSR features your calls as well as some thoughts on Clay Buchholz and Fenway Park.
Joey Mac joins Ken Laird on his Saturday show to discuss the David Backes addition and Loui Eriksson departure in NHL free agency
DJ and Pete continue to assess the season that was for the Bruins and look toward the future for the franchise and how they can improve.
DJ and Pete are together for the final Sunday Skate of the season. They get into their overall thoughts on the season, the Bruins keeping Claude Julien on as head coach and the end-of-season press conferences last week. They discuss the rebuild process, what the Bruins need and how they can obtain it. Plenty of callers have their own theories and opinions on all of these topics as well.
Former rock jock Gary Tanguay channels his radio past to attempt to "hit the post" of several classic soft rock favorites as Minihane eggs him on.
Somewhat reluctantly, Kirk and Gary take calls on who would start a one-game playoff for the Red Sox right now between Steven Wright, Rick Porcello and David Price
The 8am hour stays off the rails with Kirk and Gary discussing Ken the producer's sex life and how attractive women find them
Red Sox Starting Pitcher Steven Wright joins Glenn, John Tomase, and Tom Caron to discuss pitching the knuckler in adverse conditions, his journey through MLB, and his All-Star experience.
Acronyms abound, as Glenn, John Tomase, and Tom Caron discuss the MLB Hall of Fame, and PED's. Also, is David Ortiz a Hall of Famer?
Glenn, John Tomase, and Tom Caron discuss Clay Buchholz' current state of limbo.
With less than a week before camp opens up, we discuss some Patriots on a day that just feels like NFL training camp weather.
We talk Sox on a hot summer Friday, and how John Farrell is in a no-win situation with some fans despite the team's performance.
In honor of the passing of coach Dennis Green, we present four of the best NFL Coaching rants (during press conferences) of all time.
Kirk Minihane is joined by Boston comedy legend Lenny Clarke. If you are a fan of stand up comedy this is the podcast for you. Kirk and Lenny talk about Carlin, Pryor, Williams, Murphy and many more.
Kirk Minihane is joined by former ESPN ombudsman and New York Times writer Robert Lipsyte. Kirk and Robert discuss the current state of ESPN and how Robert feels he did in his role as ombudsman. They both criticize ESPN for the lack of journalism at ESPN and look at some of the curious decisions the world wide leader has made in the past few years.
Kirk Minihane is joined by Lenny Dykstra to talk about his book, his life pleasing older women, and Lenny tries to avoid his past issues with money. This is one explosive episode.
Uncle Buck breaks down the WWE Draft and the new rosters for Monday Night Raw and Smackdown Live.
This week we look back at the Open Championship.
Jim Hackett and Pete Davidson are back right on time for the start of the NFL and Fantasy Football pre-draft season. Topics of the day include some news around the league centering on the suspension of Le'Veon Bell, bad news swirling around Ezekiel Elliot and the passing of Coach Dennis Green. Then it's into the fun stuff featuring conversation about the Patriots Offense with the additions of Martellus Bennett and Chris Hogan and a first look at the Top 12 Wide Receivers heading into Training Camp. It's time to gear up for Fantasy Football people, giddy up!
After a few callers argue with Kirk and Gerry about racial profiling in America, the guys get to WEEI's Michael Holley disagreeing with Callahan on the inclusion of Michael Brown into recent examples of tragic deaths of blacks in America.More from this show
Glenn, Lou, and Christian examine the latest Pitcher rumored to be on the Sox' radar.More from this show
Dale, Michael and Jerry talk about the end of it all... Tom Brady will not seek a higher appeal of the US District Court's decision.More from this show
Gerry, Mut and Kirk dig back into the Melania Trump speech on night one of the RNC and discuss how the Trump team will and should handle things going forward.More from this show
ESPN analyst, Stephen A. Smith joins to the show to defend his comments that Tom Brady shouldn't be fighting to the Supreme Court. Glenn, Lou, and Christian demand Stephen explain his reasoning behind calling Brady, "uppity."More from this show


text:
Crazy Substitute Teachers
Enjoy, NG4.02 / 5.00 2,162 Views
Vacuum Salesman
This dude and his Megazord vacuum cleaner4.00 / 5.00 2,622 Views
Markiplier Animated | Mark Of The Survey Corps
This took far too long to make...3.97 / 5.00 5,588 Views
yoshi + kirby =?
yoshi + kirby = yirby
The title says it all, I agree with minortwilightghost you could make this a series... though you're probably not going to
Where do i get te Kirby sounds?
I have been looking everywhere for the sounds from kirby! But i got the yoshi sounds for an animation movie ive been working on. Anyway nice animation.
OMG! The best movie evr!
YoshiKing, You are too funny! Nice quality, Nice animation, Nice video! It is my #1 fav movie. Your AWESOME!
WOW! A truly great plot!


text:
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Didi & Bernardo wedding invitation2012
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The New York Times Magazine, Aug 30, 2015, TheU.S. Open Issuec. 2015
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New Bern Jobs
Looking for jobs in New Bern? Snagajob has great opportunities with the area's leading companies. And applying for New Bern jobs has never been easier. Look at the job listings below, click on a job title that interests you and hit the "apply now" button. Part-time jobs, teen jobs, student jobs and summer jobs are now just a click away. Start your job search now.
New Bern, NC Job Openings
Sonic Drive - In1816 Neuse Boulevard
New Bern, NC
AutoZone1707 Neuse Blvd
New Bern, NC
Papa John's2009 GLENBURNIE RD SUITE C
New Bern, NC
Chick-fil-a3000 Dr M L King Jr Blvd New Bern NC
New Bern, NC
Smithfield's Chicken 'N Bar-B-Q2507 M.L.K. Blvd
New Bern, NC
Bojangles'1238 S. Glenburnie Rd.
New Bern, NC
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text:
Ratings based on 438 Verified Reviews
They paid and stayed. We double-checked.
4.1 Room cleanliness
4.1 Service & staff
3.7 Room comfort
3.9 Hotel condition
Expedia Verified ReviewsThey paid and stayed. We double-checked.
by A verified traveler from Fort Lauderdale
Excellent location!Posted Jul 22, 2016
Close to Eiffel Tower, lots of good restaurants around. Nice room with WOOD floor!
by A verified traveler from Kelowna
Fifteen minute walk to the Eiffel TourPosted Jul 5, 2016
It's a decent little hotel - not great value for the cost. We booked a room with a view - hoping to see the Eiffel Tower, and we were on the first floor with a view of a noisy pub. It was clean, and safe though, and the staff were great.
by A verified traveler from Nashville
Great hotel near Eiffel TowerPosted Jul 2, 2016
Excellent hotel and value near Eiffel Tower and Metro. Staff very friendly and so helpful in giving information and directions to Paris attractions. We stayed in this hotel 10 years ago and it was just as great as we remembered. Hotel is located near Rue Cler that has wonderful reasonable restaurants, fresh produce, crepes, and pasteries. There is also a grocery, laundermat, and post office nearby. Room was a little small but was well planned and had everything we needed. Nice bathroom! Everything was spotless! Rick Steves uses this hotel on his tours.
by A verified traveler from Ohio
Good value.Posted Jun 19, 2016
Clean and welcoming hotel in a great neighborhood close to metro and short walk to Eiffel Tower. Surrounded by good restaurants and many shops. Decent sized rooms that were clean, comfortable, with a/c, but had limited power outlets. Narrow winding steps to get upstairs, but there is a tiny lift. My wife advises women to bring a hair dryer because the one in the bathroom is weak. Very helpful staff. Really a steal of a deal for the location, service and price.
by A verified traveler from Seoul
찾아가는 길이 어렵지 않았고, 지하철 역하고 적당한 거리.Posted Jun 5, 2016
Pros: 청소는 깨끗하게 해줌.
Cons: 조금 더 친절했으면
Location: 호텔 바로 앞에 한국 식당(가서 배탈이 났지만..)있고, 노천 카페와 그 외 레스토랑이 많아서 매우 편리함. 에펠탑과 센강이 가까움
직원들이 사무적이었고, 조식도 깔끔한 느낌이 아님. 프론트 바로 앞에서 조식을 먹게 돼있어서 불편. 객실 안은 청결하나 복도가 매우 좁고 옆방에 왔다 갔다하는 소리가 너무 잘 들림. 음식을 잘 못 먹어 고열에 시달렸는데, 난방을 해주거나 이불을 더 주거나 하지 않음. 겨우 제공 받은 것이 따뜻한 물 한잔.
by A verified traveler from Florida
Excellent location. Close to Metro station.Posted Apr 18, 2016
Restaurants, shops, and grocery stores are nearby.
by A verified traveler from Florida / Glenrothes
Great locationPosted Apr 16, 2016
Pros: Everything
Staff very friendly, excellent location for all the attractions. Room had view of Eiffel Tower. The local is great for eating with the local residents 😀
by Roger from Monument
Location, location, location!Posted Apr 7, 2016 on Hotels
We often stay on the market neighborhood, Rue Cler or close by. The Beaugency is one block over so the location is perfect. Rooms are small, but typical for Paris. The staff is friendly and really helpful. Breakfast is available.
by Melina Priscila from Porto Alegre
Posted Mar 28, 2016 on Hotels
Típico hotel francês, pequeno e aconchegante. Serve um bom café da manhã ao estilo francês a um preço bom. Ótima localização, uns 7 minutos da torre, com muitos cafés e restaurantes na volta! O ponto negativo foi o barulho do serviço de limpeza que começa bem cedo..mas mesmo assim adorei a estadia!
by A verified traveler from chicago,illinois,USA
Clean and close to tourist spots .Posted Feb 27, 2016
It excellent for a medium price hotel. Close to major tourist spots.


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Capturing what matters and measuring what counts: This is a global leadership imperative. And it is the best--if not the only--way to showcase that managing digital globalization and delivering international experiences effectively pay off. It is all about effectiveness and starts with the early steps in the global content value chain. A number of criteria and indicators should be on the radar screen of anyone willing to define, analyze, and leverage effectiveness holistically. Productivity may not always be at the top of the list in terms of localization benefits although it definitely drives time and cost savings, while enabling to better allocate resources and optimize timeframes. It may come up as a secondary factor or be diluted in other prominent indicators such as content accuracy or consistency.
The Essential Guide helps you understand and determine your criteria for choosing a new web CMS. It also identifies the key features to evaluate when researching which technology is right for your organization, and provides the best digital experience for your website visitors. Download now to learn more!


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Popular Galleries
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Products & ServicesSee also: Categories | More Information
Supplier: Mettler-Toledo, Inc.
Description: Reagent Control The titration cell is always in good condition, as Reagent Control monitors three different parameters and replaces the solvent when necessary in One Click™. The Solvent Manager also empties, fills or replaces the wwwhenever required and keeps the user fully protected
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- Titration Method: Autotitration
- Titrant Adding Method: Volumetric
- Titration Indication Method: Voltametry
- Local Interface: Digital Front Panel
Supplier: Polytron Devices, Inc.
Description: With an input to output isolation up to 1.6 KVdc, our 3 watt single and dual output DC-DC converter features a 2:1 wide input voltage range, low ripple and noise, an external on/off control and continuous short circuit protection. The converter also meets the ROHS directive. INPUT Voltage Range
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- Display: None
- Applications: Instrumentation
- Output Power: 0.0040 HP
- Number of Outputs: 1 to 2
Supplier: RS Components, Ltd.
Description: Resistance Value:100Ohms; Number of Resistors:4; Power Rating:0.3 W; Power Rating per Resistor:0.1W; Case Style:Molded; Circuit Designator:ISOL; Case Size:0612; Tolerance:0.5%; Temperature Coefficient:50ppm/C; Type:Array
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- Configuration: Resistor Network
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- Resistance Range: 100 ohms
- Tolerance: 0.5000 +/- %
Supplier: American Microsemiconductor, Inc.
Description: Light-Dependent Resistors
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- Resistance Range: 100000 to 5.00E7 ohms
- Power Rating: 1.34E-4 HP
Supplier: Ohmite Manufacturing Co.
Description: 4-up DIP Resistor Package Up to 10KV voltage handling. S-bend terminations mounting integrity and airflow consideration. 4 resistors per chip on 7575 package. Multiple possible configurations
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- Configuration: Single Resistor
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Supplier: Aeroflex / Inmet, Inc.
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Wirewound Resistors - Pot;Wirewound;Res 100 Ohms;Panel;10 Turns;Pwr-Rtg 2 W;Linear;Dia-Shaft 0.25" -- 70152995Supplier: Allied Electronics, Inc.
Description: 62 Series 10-Turn Potentiometer — Type 62JA 3⁄8" Plain bushing. Slotted shaft: 15⁄16" FMS. 100,000 shaft revolutions life. Sleeve bearings. Functional Output: Linear. Absolute Linearity: ±0.25%. Power Dissipation: 2 Watts at 25°C. Stop Torque: 50 Oz.-in.
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Description: Complete welded and molded construction for total environmental protection in aluminum housed wirewound chassis mount resistor. Mounts on chassis to utilized heat-sink effect. High stability at conventional power ratings. Flat marking surface for easy identification. Series has ceramic, steatite or
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Description: Regulated/Isolated Line Regulation: 0.1% Load Regulation: 2% Isolation >1kV Output Voltage: N series are available in multiple output voltages ranging from 100VDC to 10,000VDC Power: 3W Dimension: 3.00" x 1.50" x 0.85" Electrical Characteristics & Description Model J Series
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Standards and Technical Documents - Insulating liquids - Oil-impregnated paper and pressboard - Determination of water by automatic coulometric Karl Fischer titration -- IEC 60814:1997
Description: Describes methods for the determination of water in insulating liquids and in oil-impregnated cellulosic insulation with coulmetrically generated Karl Fischer reagent.Show More
Standards and Technical Documents - API MPMS 10.9 -- MANUAL OF PETROLEUM MEASUREMENT STANDARDS CHAPTER 10.9 - STANDARD TEST METHOD FOR WATER IN CRUDE OILS BY COULOMETRIC KARL FISCHER TITRATIONSupplier: American Petroleum Institute (API)
Description: method is intended for use with standard commercially available coulometric Karl Fischer reagent. The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. This standard does not purport to address all of the safety concerns, if anyShow More
Standards and Technical Documents - Surface-active agents and detergents -- Determination of water content -- Karl Fischer methods -- ISO 4317:2011
Description: ISO 4317:2011 specifies two titration methods (volumetric and coulometric) using Karl Fischer reagent for the determination of the water content of surface active agents and detergents. These methods are applicable to products in the form of powders, pastes and solutions. They are applicable onlyShow More
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Controlled Release of Substituted Benzole and Naphthoic Acids Using Carbopol ® Gels: Measurement of Drug Concentration Profiles and Correlation to Release Rat...
Benzoic acid, monobasic and dibasic potassium phosphate, hydrochloric acid, sodium hydroxide, and the coulometric titration re- agents , Hydranal* Coulomat A, Hydranall Coulomat CG, and Hydranale Composite 5, were obtained from Fisher Sci- entiik Co., Fair Lawn, New Jersey.
Practical experiences with HYDRANAL® E-type reagents Coulometric titration .
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Home →
→ Urgent Care
July 21, 2014
Urgent Care
Union Medical Urgent Care, an urgent care center in Fresh Meadows, recently added a dental office to its Queens location and welcomed David J. Wiseman, D.D.S., as its dentist.
The kids' side of the waiting room has a TV, books, and toys to keep children entertained while waiting to see a doctor.
Union Medical Urgent Care opened this spring in Fresh Meadows as an alternative to a doctor's office or emergency room. It offers services such as blood work, X-rays, sutures, throat cultures, and work place physicals. In mid-July, Union Medical welcomed dentist David J. Wiseman, D.D.S. to the offices to accommodate dental injuries as well as basic dental work and check-ups. While urgent care only takes walk-ins, the dentist accepts both walk-ins and appointments.
The urgent care center's waiting room is divided in half: one side with books, toys, and television shows for children, and the other side with water, coffee, and adult programs. "We like to make sure everyone is comfortable when they come in, no matter how old, young, or the reason", says Chad Kaminetzky, director of operations. "When you come in, you feel like part of the family."
Kaminetzky prides himself on the urgent care center's kid-friendly yet professional environment. "No child likes going to the doctor, but we make it easier with televisions in all the exam rooms and colorful walls."
With "virtually no wait time," according to Kaminetzky, convenience is one of the center's major concerns. It has its own parking lot and is open seven days a week, including holidays, Monday-Friday 8am-9pm and weekends 9am-9pm.
Shara Beitch was a summer 2014 editorial intern for NYMetroParents. See More
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Does your teen see herself as fat when she's not—and measure her self-worth by her weight? Learn the early warning signs of eating disorders (perhaps surprisingly, for boys as well as girls).
Chess is an excellent course of study to promote essential life skills. Centers like NY Chess Kids offer after-school and other programs to teach children the game of chess.
Copyright 2016 | All Rights
Reserved | Davler Media
Get NYMetroParents in Your Inbox


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History Channel: Our Planet - The Past, Present and Future of Earth (3-DVD)
LOW STOCK: Only 2 copies left
|List Price:
|$10.92 Limited Time Only
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Available: Usually ships in 1-3 business days
Format: DVD (3 Discs)
sku: K5J4
Brand New
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DVD Features:
- Number of Discs: 3
- Rated: PG
- Run Time: 4 hours, 40 minutes
- Video: Color
- Released: March 29, 2011
- Originally Released: 2011
- Label: A&E Home Video
- Encoding: Region 1 (USA & Canada)
- Note: Bonus documentary: "Inside the Volcano"
- Additional scenes
- Audio:
- Dolby Digital 2.0 Stereo
Product Description:
This release includes three documentaries that explore the workings of the planet Earth in the past, present, and future, using expert scientific explanation, and advanced computer animation. The first program discusses how the Earth was formed, the second questions how the effects of Global Warming are affecting the planet as we know it, and the third posits what the planet would be like after humanity is wiped out.
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- May buy multiples.
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Full Details
They say diamonds are a girl's best friend, but they're definitely not your bank manager's! Keep everyone happy with today's deal…
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Old-Fashioned Tapioca With Lemon Sauce
Total Time
Prep 20 mins
Cook 0 mins
One of my all-time favorites, this is one is easy on the diet. You can top this homey dessert with green grapes and orange slices for a pretty presentation. You can also use the lemon sauce over angel food cake or your favorite frozen yogurt.
Ingredients Nutrition
- 2 1⁄2 cups reduced-fat milk (2%)
- 1⁄3 cup sugar
- 1⁄4 cup quick-cooking tapioca
- 2 teaspoons grated lemon peel
- 1 teaspoon vanilla extract
Lemon Sauce
- 1⁄3 cup sugar
- 1 tablespoon cornstarch
- 3⁄4 cup water
- 1⁄4 cup fresh lemon juice
- 4 thin lemon slices
- 1 teaspoon grated lemon peel
- Whisk milk, sugar, tapioca, and lemon peel in heavy medium saucepan to blend. Let stand 5 minutes. Stir over medium heat until mixture thickens and boils, about 5 minutes. Remove from heat. Stir in vanilla. Cover and chill until cold, at least 4 hours. (Can be prepared 1 day ahead. Keep refrigerated.
- To make sauce, whisk sugar and cornstarch in small saucepan to blend. Add 3/4 cup water. Whisk over medium-high heat until mixture thickens and boils, about 2 minutes. Stir in lemon juice, lemon slices and grated peel. Cool. (Can be prepared 1 day ahead. Cover and chill. Bring to room temperature before serving.).
- To serve, spoon pudding into small bowls. Spoon Lemon Sauce over and serve.
Most Helpful
I loved this and served it with lemon and lime rind grated over the top so minus the sauce. I used skinny milk and light brown sugar. Gosh it was yummy !! made for ZWT 7.
I love tapioca and this one is very different and so good. I used Splenda instead of sugar even in the sauce. I used skim milk. I had a very good result. Me and my son loved this. Thanks Jackie. Made for Potluck tag.
Delicious! We loved this lightly lemon flavored tapioca with its tangy lemon sauce. The fact that it is lower in fat made it OK (at least in my mind) to have two servings. Yummy! I made it as written, adding 2 drops yellow food coloring to the sauce for color. Thank you for sharing this wonderful recipe...it is definitely a keeper. *Made for Fall 2008 My 3 Chefs*


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What will happen if you masterbait everyday? All_Of_The_Abov
kgb answers » Health & Body » Health & Fitness » What will happen if you masterbait everyday? All_Of_The_Abov
Wednesday, February 01 2012
Source: http://healthystrokes.com/
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