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|By PR Newswire
Article Rating:
|March 14, 2014 08:01 AM EDT
MOUNTAIN VIEW, Calif., March 14, 2014 /PRNewswire/ -- Based on its recent analysis of the electronic medical records (EMR) and electronic health records (EHR) market, Frost & Sullivan recognizes Allscripts with the 2014 Australia-New Zealand Excellence in Growth Strategy Award. This award further reflects industry recognition of Allscripts' commitment to open architecture, outcomes, and a client-focused strategy.
"The technologies of EMR and EHR in ANZ are at an inflection point, as practitioners begin to focus on collaboration and integration across departments, stakeholders and devices," said Frost & Sullivan Connected Health Senior Industry Analyst Natasha Gulati. "Allscripts has invested in business processes, products, and companies that have the potential to create a unique connected health platform that integrates a variety of industry participants."
In 2013, Allscripts continued to leverage its open architecture and a leading position in population health management to deliver on client commitments. Allscripts' focus on driving client success through positive patient outcomes helped facilitate its growth in 2013 and underscored the traction of its strategic efforts. Allscripts currently works with approximately 180,000 physicians across 45,000 practices and 2,700 hospitals worldwide.
Acknowledging the need to integrate healthcare records, Allscripts made strategic acquisitions and research and development investments in enabling solutions that aid the integration of heterogeneous systems across diverse care settings. Its main products — the Allscripts Sunrise™ Clinicals solutions suite, the Allscripts dbMotion™ population health management solution and the Allscripts FollowMyHealth™ patient engagement solution — serve both acute and ambulatory customer segments allowing for information exchange and interoperability across care settings.
"As providers move towards integrated care across the entire community, including the home, they need solutions that are open and integrated," said Allscripts Managing Director of Sales for Australia, David Chambers. "As demonstrated by our clients' results, Allscripts provides needed solutions that enable providers and governments to manage the health of entire populations, which can result in better patient engagement, increased quality, and lower costs."
Furthering its commitment to interoperability, Allscripts launched the open application programming interface (API) initiative, which consists of the Allscripts Developer Program, software development kit (SDK) and application store and exchange. It allows clients and third-party development partners to connect data and build innovative solutions to ease providers' pain points around EHR adoption.
"Allscripts is dedicated to its core values and has gained the trust of healthcare providers across the region," noted Gulati. "The company's successful systems and superior quality service provision across ANZ have paved the way for strong growth, particularly through new implementations."
Frost & Sullivan Best Practices Awards recognize companies in a variety of regional and global markets for demonstrating outstanding achievement and superior performance in areas such as leadership, technological innovation, customer service, and strategic product development. Industry analysts compare market participants and measure performance through in-depth interviews, analysis, and extensive secondary research in order to identify best practices in the industry.
About Frost & Sullivan
Frost & Sullivan, the Growth Partnership Company, works in collaboration with clients to leverage visionary innovation that addresses the global challenges and related growth opportunities that will make or break today's market participants.
Our "Growth Partnership" supports clients by addressing these opportunities and incorporating two key elements driving visionary innovation: The Integrated Value Proposition and The Partnership Infrastructure.
- The Integrated Value Proposition provides support to our clients throughout all phases of their journey to visionary innovation including: research, analysis, strategy, vision, innovation and implementation.
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For more than 50 years, we have been developing growth strategies for the Global 1000, emerging businesses, the public sector and the investment community. Is your organization prepared for the next profound wave of industry convergence, disruptive technologies, increasing competitive intensity, Mega Trends, breakthrough best practices, changing customer dynamics and emerging economies?
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SOURCE Frost & Sullivan
Manufacturers are embracing the Industrial Internet the same way consumers are leveraging Fitbits – to improve overall health and wellness. Both can provide consistent measurement, visibility, and suggest performance improvements customized to help reach goals. Fitbit users can view real-time data and make adjustments to increase their activity. In his session at @ThingsExpo, Mark Bernardo Professional Services Leader, Americas, at GE Digital, discussed how leveraging the Industrial Internet a...
Jul. 26, 2016 04:10 PM EDT
You think you know what's in your data. But do you? Most organizations are now aware of the business intelligence represented by their data. Data science stands to take this to a level you never thought of – literally. The techniques of data science, when used with the capabilities of Big Data technologies, can make connections you had not yet imagined, helping you discover new insights and ask new questions of your data. In his session at @ThingsExpo, Sarbjit Sarkaria, data science team lead ...
Jul. 26, 2016 04:00 PM EDT Reads: 1,005
Extracting business value from Internet of Things (IoT) data doesn't happen overnight. There are several requirements that must be satisfied, including IoT device enablement, data analysis, real-time detection of complex events and automated orchestration of actions. Unfortunately, too many companies fall short in achieving their business goals by implementing incomplete solutions or not focusing on tangible use cases. In his general session at @ThingsExpo, Dave McCarthy, Director of Products...
Jul. 26, 2016 03:45 PM EDT Reads: 1,713
WebRTC is bringing significant change to the communications landscape that will bridge the worlds of web and telephony, making the Internet the new standard for communications. Cloud9 took the road less traveled and used WebRTC to create a downloadable enterprise-grade communications platform that is changing the communication dynamic in the financial sector. In his session at @ThingsExpo, Leo Papadopoulos, CTO of Cloud9, discussed the importance of WebRTC and how it enables companies to focus...
Jul. 26, 2016 03:15 PM EDT Reads: 901
Amazon has gradually rolled out parts of its IoT offerings in the last year, but these are just the tip of the iceberg. In addition to optimizing their back-end AWS offerings, Amazon is laying the ground work to be a major force in IoT – especially in the connected home and office. Amazon is extending its reach by building on its dominant Cloud IoT platform, its Dash Button strategy, recently announced Replenishment Services, the Echo/Alexa voice recognition control platform, the 6-7 strategic...
Jul. 26, 2016 03:15 PM EDT Reads: 289
Aspose.Total for .NET is the most complete package of all file format APIs for .NET as offered by Aspose. It empowers developers to create, edit, render, print and convert between a wide range of popular document formats within any .NET, C#, ASP.NET and VB.NET applications. Aspose compiles all .NET APIs on a daily basis to ensure that it contains the most up to date versions of each of Aspose .NET APIs. If a new .NET API or a new version of existing APIs is released during the subscription peri...
Jul. 26, 2016 03:00 PM EDT Reads: 822
Verizon Communications Inc. (NYSE, Nasdaq: VZ) and Yahoo! Inc. (Nasdaq: YHOO) have entered into a definitive agreement under which Verizon will acquire Yahoo's operating business for approximately $4.83 billion in cash, subject to customary closing adjustments. Yahoo informs, connects and entertains a global audience of more than 1 billion monthly active users** -- including 600 million monthly active mobile users*** through its search, communications and digital content products. Yahoo also co...
Jul. 26, 2016 02:30 PM EDT Reads: 480
Ixia (Nasdaq: XXIA) has announced that NoviFlow Inc.has deployed IxNetwork® to validate the company's designs and accelerate the delivery of its proven, reliable products. Based in Montréal, NoviFlow Inc. supports network carriers, hyperscale data center operators, and enterprises seeking greater network control and flexibility, network scalability, and the capacity to handle extremely large numbers of flows, while maintaining maximum network performance. To meet these requirements, NoviFlow in...
Jul. 26, 2016 02:00 PM EDT Reads: 530
As companies gain momentum, the need to maintain high quality products can outstrip their development team's bandwidth for QA. Building out a large QA team (whether in-house or outsourced) can slow down development and significantly increases costs. This eBook takes QA profiles from 5 companies who successfully scaled up production without building a large QA team and includes: What to consider when choosing CI/CD tools How culture and communication can make or break implementation
Jul. 26, 2016 02:00 PM EDT Reads: 1,629
"There's a growing demand from users for things to be faster. When you think about all the transactions or interactions users will have with your product and everything that is between those transactions and interactions - what drives us at Catchpoint Systems is the idea to measure that and to analyze it," explained Leo Vasiliou, Director of Web Performance Engineering at Catchpoint Systems, in this SYS-CON.tv interview at 18th Cloud Expo, held June 7-9, 2016, at the Javits Center in New York Ci...
Jul. 26, 2016 01:45 PM EDT Reads: 1,992
Redis is not only the fastest database, but it is the most popular among the new wave of databases running in containers. Redis speeds up just about every data interaction between your users or operational systems. In his session at 19th Cloud Expo, Dave Nielsen, Developer Advocate, Redis Labs, will share the functions and data structures used to solve everyday use cases that are driving Redis' popularity.
Jul. 26, 2016 12:30 PM EDT Reads: 1,582
UpGuard has become a member of the Center for Internet Security (CIS), and will continue to help businesses expand visibility into their cyber risk by providing hardening benchmarks to all customers. By incorporating these benchmarks, UpGuard's CSTAR solution builds on its lead in providing the most complete assessment of both internal and external cyber risk. CIS benchmarks are a widely accepted set of hardening guidelines that have been publicly available for years. Numerous solutions exist t...
Jul. 26, 2016 11:45 AM EDT Reads: 553
"We're bringing out a new application monitoring system to the DevOps space. It manages large enterprise applications that are distributed throughout a node in many enterprises and we manage them as one collective," explained Kevin Barnes, President of eCube Systems, in this SYS-CON.tv interview at DevOps at 18th Cloud Expo, held June 7-9, 2016, at the Javits Center in New York City, NY.
Jul. 26, 2016 10:45 AM EDT Reads: 1,721
Choosing the right cloud for your workloads is a balancing act that can cost your organization time, money and aggravation - unless you get it right the first time. Economics, speed, performance, accessibility, administrative needs and security all play a vital role in dictating your approach to the cloud. Without knowing the right questions to ask, you could wind up paying for capacity you'll never need or underestimating the resources required to run your applications.
Jul. 26, 2016 10:37 AM EDT Reads: 329
SYS-CON Events announced today that LeaseWeb USA, a cloud Infrastructure-as-a-Service (IaaS) provider, will exhibit at the 19th International Cloud Expo, which will take place on November 1–3, 2016, at the Santa Clara Convention Center in Santa Clara, CA. LeaseWeb is one of the world's largest hosting brands. The company helps customers define, develop and deploy IT infrastructure tailored to their exact business needs, by combining various kinds cloud solutions.
Jul. 26, 2016 10:15 AM EDT Reads: 1,184


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Guess how many hours a day Xbox One users spend behind their controllers?Pocket-lint
The Xbox Live team have revealed some very interesting numbers that might alleviate your console-gaming guilt. If you felt bad grabbing an hour or two on your machine don't fret, the average Xbox One user is at it for five hours.
This being an average suggests some Xbox One owners spend serious time locked into console focus-mode. But, of course, other uses for the console must be taken into account, such as watching TV and live streams, through Twitch - something that has proved incredibly popular since the service went live on the platform.
Twitch says that since its Xbox One app added broadcasting on 10 March nearly 23 million minutes of streamed gameplay have gone online. And if that wasn't impressive enough, more than 2.7 million minutes were broadcast from Xbox One consoles between 10 and 11 March alone .
READ: 'Xbox Broadcast': Twitch streaming now available on Xbox One
It sounds like the Xbox One is the Twitch console of choice, with the PS4 lagging behind. The subtle words from the flag-waving press release read: "It took another console a month to achieve what the Twitch app on Xbox One did within its first week."
Titanfall is the most broadcast game on Twitch with more than 10 million minutes aired from the game to date.
READ: Titanfall review
Nintendo NX: Completely portable, powered by Nvidia Tegra chip, and games that come on cartridges, claim sources
Pokemon Go future features revealed
Pokemon Go Gym tips: How to battle, train and win
Pokemon Go finally launches in Japan, France, Hong Kong
- Nintendo NX: Completely portable, powered by Nvidia Tegra chip, and games that come on cartridges, claim sources
- Pokemon Go finally launches in Japan, France, Hong Kong
- You can now preorder Razer's OSVR HDK 2 virtual-reality headset
- How Xbox One backwards compatibility works: The Xbox 360 games list and more
- Nintendo's new console available to order, but it's not what you expected
- Pokemon Go Gym tips: How to battle, train and win
- Pokemon Go: How to raise your XP level, power up and evolve your Pokemon
- Samsung Galaxy Note 7: Release date, rumours and everything you need to know
- Hyundai Ioniq Electric review: Fully charged
- Motorola Moto E3 (2016) vs Moto G4 vs G4 Plus vs G4 Play: What's the difference?
- Best smartphones 2016: The best phones available to buy today
- Pokemon Go: How to play and other tips and tricks
- Bush E3X preview: The £200 Argos phone looking to topple Moto G
- Microsoft Pix app uses AI to help you take better pictures on iPhone
- Next Sony Xperia flagship: Rumours, release date and everything you need to know

subset: commoncrawl


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Comment Why aren't they boosting Outlook instead? (Score -1) 122
Outlook is supposed to be some premier contact application and yet it doesn't handle any chat or social media and barely does POP3/SMTP. What are they screwing around with Skype for?
That was not the aspect of the xbone launch that people hated. Sony got a huge applause just for saying there was no DRM hindering you from playing your disc on another console.
Sony doesn't do anything original. All of their successes in gaming are "just for".
I just asked myself... what would John DeLorean do? -- Raoul Duke


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text: Home > Lifestyle K-pop star Rain finishes military service Agence France-Presse Posted at Jul 10 2013 06:29 PM | Updated as of Jul 11 2013 06:53 PM Share Facebook Twitter GPlus LinkedIn Pinterest South Korean pop singer Jung "Rain" Ji-Hoon SEOUL - South Korean pop icon Rain was officially released from mandatory military service Wednesday, with hundreds of fans shedding tears of joy over the star's comeback. About 700 devotees from South Korea and abroad exploded into ecstatic cheers as the 31-year-old K-pop star emerged from the defence ministry building in Seoul, where he had gone to receive his discharge papers. Some banner-carrying fans, weary from camping out overnight in drizzling rain, broke into tears as the star walked out wearing a military uniform. "Thank you all for coming to welcome me. I'll do my best. I love you all," Yonhap news agency quoted the singer as saying, as he gave fans a military salute. Rain, whose real name is Jung Ji-Hoon, is one of the biggest names in the world of K-pop, which commands a huge following in South Korea, across much of Asia and beyond. In January, he was confined to barracks for a week after he was caught sneaking out for to meet a love interest while on official duty. He was dating a Kim Tae-Hee, a TV drama star with a massive following in Japan. South Korean men are obligated to serve about two years in the country's armed forces. Military service is taken extremely seriously in South Korea, which remains technically at war with North Korea because their 1950-53 conflict ended with a ceasefire rather than a peace treaty. Apart from those with physical disabilities, exemptions are rare and anyone refusing to serve -- for moral or religious reasons -- faces an automatic jail term. Celebrities are frequently caught attempting to evade military service for fear they might be forgotten by their fans while in uniform. "Gangnam Style" star Psy was forced to serve twice after it emerged he had furthered his showbiz interests during his first stint. Share Facebook Share on Twitter GPlus LinkedIn Pinterest Read More: south korea rain k-pop military service /business/07/28/16/stock-market-rallies-on-optimism-over-duterte-pse-president/news/07/28/16/2-umanoy-gun-for-hire-napatay-sa-navotas-fish-port/business/07/28/16/fed-leaves-rates-unchanged-says-risks-to-outlook-reduced/news/07/28/16/road-rage-suspect-abandons-car-takes-bus/overseas/07/28/16/australia-police-say-pope-aide-probed-over-child-abuse-claims


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|By Marketwired .
Article Rating:
|March 14, 2014 06:16 PM EDT
CALGARY, ALBERTA -- (Marketwired) -- 03/14/14 -- Precision Drilling Corporation (TSX: PD) (NYSE: PDS) ("Precision") announced that it has filed its annual disclosure documents with the Canadian Securities Commissions and the United States Securities and Exchange Commission ("SEC").
Precision's 2013 Annual Report contains the audited consolidated financial statements and management's discussion and analysis for the year ended December 31, 2013. Precision's financial results for the year ended December 31, 2013 were previously released on February 13, 2014.
Precision's Annual Information Form has been filed on the Canadian System for Electronic Document Analysis and Retrieval ("SEDAR") and, along with the Annual Report, filed on Form 40-F on the SEC's Electronic Data Gathering, Analysis and Retrieval ("EDGAR") system.
The documents described above are also available on Precision's website at www.precisiondrilling.com or by emailing Precision at [email protected].
In April, Precision will file with the securities commissions its 2014 Proxy Statement and Information Circular in advance of the annual meeting of shareholders scheduled to take place on May 14, 2014.
About Precision
Precision is a leading provider of safe and High Performance, High Value services to the oil and gas industry. Precision provides customers with access to an extensive fleet of contract drilling rigs, directional drilling services, well service & snubbing rigs, coil tubing services, camps, rental equipment, and water treatment units backed by a comprehensive mix of technical support services and skilled, experienced personnel.
Precision is headquartered in Calgary, Alberta, Canada. Precision is listed on the Toronto Stock Exchange under the trading symbol "PD" and on the New York Stock Exchange under the trading symbol "PDS".
Precision Drilling Corporation
Carey Ford
Vice President, Finance and Investor Relations
Precision Drilling Corporation
800, 525 - 8th Avenue S.W.
Calgary, Alberta, Canada T2P 1G1
"We host and fully manage cloud data services, whether we store, the data, move the data, or run analytics on the data," stated Kamal Shannak, Senior Development Manager, Cloud Data Services, IBM, in this SYS-CON.tv interview at 18th Cloud Expo, held June 7-9, 2016, at the Javits Center in New York City, NY.
Jul. 29, 2016 05:00 AM EDT Reads: 1,418
Machine Learning helps make complex systems more efficient. By applying advanced Machine Learning techniques such as Cognitive Fingerprinting, wind project operators can utilize these tools to learn from collected data, detect regular patterns, and optimize their own operations. In his session at 18th Cloud Expo, Stuart Gillen, Director of Business Development at SparkCognition, discussed how research has demonstrated the value of Machine Learning in delivering next generation analytics to imp...
Jul. 29, 2016 04:45 AM EDT Reads: 2,560
DevOps at Cloud Expo – being held November 1-3, 2016, at the Santa Clara Convention Center in Santa Clara, CA – announces that its Call for Papers is open. Born out of proven success in agile development, cloud computing, and process automation, DevOps is a macro trend you cannot afford to miss. From showcase success stories from early adopters and web-scale businesses, DevOps is expanding to organizations of all sizes, including the world's largest enterprises – and delivering real results. Am...
Jul. 29, 2016 04:45 AM EDT Reads: 2,357
With the proliferation of both SQL and NoSQL databases, organizations can now target specific fit-for-purpose database tools for their different application needs regarding scalability, ease of use, ACID support, etc. Platform as a Service offerings make this even easier now, enabling developers to roll out their own database infrastructure in minutes with minimal management overhead. However, this same amount of flexibility also comes with the challenges of picking the right tool, on the right ...
Jul. 29, 2016 04:30 AM EDT Reads: 1,395
The 19th International Cloud Expo has announced that its Call for Papers is open. Cloud Expo, to be held November 1-3, 2016, at the Santa Clara Convention Center in Santa Clara, CA, brings together Cloud Computing, Big Data, Internet of Things, DevOps, Digital Transformation, Microservices and WebRTC to one location. With cloud computing driving a higher percentage of enterprise IT budgets every year, it becomes increasingly important to plant your flag in this fast-expanding business opportuni...
Jul. 29, 2016 04:15 AM EDT Reads: 2,670
With over 720 million Internet users and 40–50% CAGR, the Chinese Cloud Computing market has been booming. When talking about cloud computing, what are the Chinese users of cloud thinking about? What is the most powerful force that can push them to make the buying decision? How to tap into them? In his session at 18th Cloud Expo, Yu Hao, CEO and co-founder of SpeedyCloud, answered these questions and discussed the results of SpeedyCloud's survey.
Jul. 29, 2016 03:45 AM EDT Reads: 1,036
The Internet of Things will challenge the status quo of how IT and development organizations operate. Or will it? Certainly the fog layer of IoT requires special insights about data ontology, security and transactional integrity. But the developmental challenges are the same: People, Process and Platform. In his session at @ThingsExpo, Craig Sproule, CEO of Metavine, demonstrated how to move beyond today's coding paradigm and shared the must-have mindsets for removing complexity from the develo...
Jul. 29, 2016 02:45 AM EDT Reads: 1,598
SYS-CON Events announced today that MangoApps will exhibit at the 19th International Cloud Expo, which will take place on November 1–3, 2016, at the Santa Clara Convention Center in Santa Clara, CA. MangoApps provides modern company intranets and team collaboration software, allowing workers to stay connected and productive from anywhere in the world and from any device.
Jul. 29, 2016 02:30 AM EDT Reads: 1,456
Large scale deployments present unique planning challenges, system commissioning hurdles between IT and OT and demand careful system hand-off orchestration. In his session at @ThingsExpo, Jeff Smith, Senior Director and a founding member of Incenergy, will discuss some of the key tactics to ensure delivery success based on his experience of the last two years deploying Industrial IoT systems across four continents.
Jul. 29, 2016 02:00 AM EDT Reads: 1,678
Redis is not only the fastest database, but it is the most popular among the new wave of databases running in containers. Redis speeds up just about every data interaction between your users or operational systems. In his session at 19th Cloud Expo, Dave Nielsen, Developer Advocate, Redis Labs, will share the functions and data structures used to solve everyday use cases that are driving Redis' popularity.
Jul. 29, 2016 12:30 AM EDT Reads: 1,700
Basho Technologies has announced the latest release of Basho Riak TS, version 1.3. Riak TS is an enterprise-grade NoSQL database optimized for Internet of Things (IoT). The open source version enables developers to download the software for free and use it in production as well as make contributions to the code and develop applications around Riak TS. Enhancements to Riak TS make it quick, easy and cost-effective to spin up an instance to test new ideas and build IoT applications. In addition to...
Jul. 29, 2016 12:15 AM EDT Reads: 1,993
Predictive analytics tools monitor, report, and troubleshoot in order to make proactive decisions about the health, performance, and utilization of storage. Most enterprises combine cloud and on-premise storage, resulting in blended environments of physical, virtual, cloud, and other platforms, which justifies more sophisticated storage analytics. In his session at 18th Cloud Expo, Peter McCallum, Vice President of Datacenter Solutions at FalconStor, discussed using predictive analytics to mon...
Jul. 29, 2016 12:15 AM EDT Reads: 2,091
Identity is in everything and customers are looking to their providers to ensure the security of their identities, transactions and data. With the increased reliance on cloud-based services, service providers must build security and trust into their offerings, adding value to customers and improving the user experience. Making identity, security and privacy easy for customers provides a unique advantage over the competition.
Jul. 28, 2016 11:45 PM EDT Reads: 1,243
In his session at @DevOpsSummit at 19th Cloud Expo, Yoseph Reuveni, Director of Software Engineering at Jet.com, will discuss Jet.com's journey into containerizing Microsoft-based technologies like C# and F# into Docker. He will talk about lessons learned and challenges faced, the Mono framework tryout and how they deployed everything into Azure cloud. Yoseph Reuveni is a technology leader with unique experience developing and running high throughput (over 1M tps) distributed systems with extre...
Jul. 28, 2016 10:15 PM EDT Reads: 2,228
"We've discovered that after shows 80% if leads that people get, 80% of the conversations end up on the show floor, meaning people forget about it, people forget who they talk to, people forget that there are actual business opportunities to be had here so we try to help out and keep the conversations going," explained Jeff Mesnik, Founder and President of ContentMX, in this SYS-CON.tv interview at 18th Cloud Expo, held June 7-9, 2016, at the Javits Center in New York City, NY.
Jul. 28, 2016 10:15 PM EDT Reads: 1,444


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Where do river otters sleep
kgb answers » Science & Technology » Animals » Where do river otters sleep
Thursday, February 02 2012
Source: http://www.ehow.com/how_2323293_distinguish-between-river-otter-sea.html
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Clear, concise, logical, and practical. Turns mainstream assumptions on their head, where they should stay. Read morePublished on January 8, 2013 by OJ
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(Ahlul Bayt News Agency) - An official source stated that armed groups began an intense armed assault tactic on Monday using live ammo and Molotov cocktails against official and police departments in the city of Hama.
The source said that armed men carrying machineguns are using motorbikes and some of them are stationed on rooftops and that at dawn they began opening fire heavily on departments, targeting windows and entrances. They also threw Molotov cocktails at these departments to set them on fire.
This attack forced workers in some of these departments to remain where they are due to the shooting that prevents them from going in or out.
The source said that the army is still pursuing its mission of removing the roadblocks set by saboteur groups on the city's main entrances, and that a wide scale conflict is taking place since these groups are organized into units and use advanced weapons, in addition to laying traps in main streets.
Armed Terrorist Groups Attack Conscription & Mobilization Centers in Hama, Steal Military ID Cards and Uniforms
The armed groups continued their criminal acts and attacked Conscription and Mobilization Centers in Hama City and stole military ID cards and uniforms, which might be negatively used later to commit aggressive practices which contradict the Military Establishment ethics and accuse the army of doing them.
It is likely that these armed groups might set up roadblocks to stop citizens and assault them or to carry out raids, film them and broadcast them on the instigative channels as being committed by the Syrian army.
Armed Groups Blocked Way of Trucks Laoded with Food Supplies in Idleb
An armed group blocked the way of four cars loaded with food supplies while heading to distribute them to the consumption centers in Hazareen town, Maarat al-Nu'man.
The groups also burglarized another truck carrying 13 tons of sugar with guns and forced its driver to unload the cargo in unknown area.
The car driver Monzer Bakkour told SANA that he was ambushed in Hazareen town within a convoy of four trucks tasked with transporting sugar supplies from Tal Sahlab factory, indicating that the other trucks could escape the ambush.
The group was equipped with different arms, grenades and guns, he added.
The terrorist attacks of the armed groups on citizens and public and private properties increased over the past few days. Last week, these groups attacked a train transporting 500 passengers from Aleppo to Damascus and blew up an oil pipeline near Tal Hosh Dam in Tal Kalakh.
Another armed terrorist group targeted a bus carrying passengers from Damascus to Misyaf which resulted in the martyrdom of a woman and the injury of 15 citizens.
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People who suffer from lower limb paralysis may one day walk again thanks to the EU-funded project, MINDWALKER.
For lower limb disabled people, the lack of mobility often leads to limited participation in social life. Of course, they can use wheelchairs to move around. But their mobility is fairly limited.
To help them perform their usual daily activities in the most autonomous and natural manner, the EU-funded research project MINDWALKER, launched in 2010, has developed an intelligent exoskeleton.
This project is a clever mix of mechanics, electronics, brain activity measurement devices, computer technology, and virtual reality training. It has created a functional prototype of a lower limb exoskeleton that could be activated either through brain waves detected by dry electrodes directly placed on the head in a little cap, by upper body muscle activity measurements (when a person walks, at the same time they move their arms and their shoulders) or by luminous signals.
All these functions were combined to develop an integrated system. This system has been successfully tested in May 2013 on patients in Italy. It is an exoskeleton capable of supporting the weight of an adult, ensuring walking stability and enabling different walking abilities.
The prototype exoskeleton now requires extra research initiatives beyond the scope of the MINDWALKER project in order to become fully exploitable.
Embryologists are studying the earliest stages of pregnancy in the hope of understanding why it sometimes goes wrong.
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Enhancing trust in science through public engagement and open, transparent research is vital if we are to avoid descending into a 'post-factual society', according to Carlos Moedas, the European Commissioner for Research, Innovation and Science.
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Open data can help increase transparency and trust in research.
It has adjusted its plans.
Dr Daniela Thorwarth is working on targeted treatments that could increase cancer cure rates.


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Nikon Consumer DX SLR Talk
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megthebest • Regular Member • Posts: 423
Re: Nikon Consumer DX SLR Talk
In reply to mario7 • Oct 4, 2012
why this name ?... i think could be a mess for someone don't know exactly were to post..
i like more the Nikon D** and D**** DSLR Talk
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Are you feeling stagnant, blase, or needing a little lift?
Next time you feel this way, clean your house and see what happens. You can literally change the vibration or lift the vibration of your house by cleaning and bring in new opportunities quickly. Have you ever walked into a home where things were a little chaotic and in a state of disarray and you felt a little uncomfortable? You know that same feeling you get when you're watching hoarders on television. Or have you walked into a home that was clean, pristine and looked like a museum and you felt really good there? Like when you're watching HGTV and they're doing the grand reveal of the space after they HGTV'd it. Those "feelings" all have to do with the energy in the space.
I self diagnosed myself with a cleaning disorder. Anytime I am stressed, I clean, if I am frustrated, I clean, If I am sad, I clean. Why do you ask, would I do such a foolish thing? Because it makes me feel better. It lifts the vibration of my home, which in turn changes my vibration to a higher one and the end result is a happier gal. Obviously, you don't have to be as obsessive as I am but you get the picture. A little cleaning, goes a long way.
Energy flows from the outside- in and flows from the middle of the house outward in a specific pattern that we Feng Shui people call the " lo shu flight path." When chi is flowing and there's an obstacle in its way, such as a stack of laundry,boxes, or just a bunch of stuff everywhere, the chi cannot flow uniformly and that's when you may start feeling stagnation, tired, depression, low energy, etc.
Energy brings opportunities for money, relationships and health. When energy is met with an obstacle, it diverts from its normal path, which in turn takes longer to complete the "lo shu flight path." For example, picture yourself driving along and all of the sudden the light turns red, which in turn forces you to come to a screeching halt. If you were to keep doing this a dozen times, it would eventually take longer for you to get to your destination. Now use that same analogy and picture the energy flow in your home…every time it's halted by an obstacle, it will take that much longer for the opportunities to come in.
By cleaning up after yourself, cleaning the house, clearing away clutter, and keeping your home pristine, these actions will left the energy of your home and the chi will be able to flow freely and effortlessly and this will help bring in more opportunities for money, relationships, and health. Give it a try and see what happens.
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So, Battlefield 3 is pretty amazing, no? I'd say it pretty much ends any shot Rage had at holding the title of "best-looking PC game," although Rage has its own issues with texture detail that sully its excellent artwork and bursting-with-detail environments.
I'll admit to enjoying the single-player campaigns in games like BF3, and this one so far seems to be pretty engaging. My attempt to take a quick look at the game's graphics melted into several hours of intense gameplay last night. Of course, the single-player graphics are jaw-dropping and look like a true next-generation PC game—at last. The multiplayer beta just didn't show us everything that was possible with this game engine, we can now say for sure. At least, that's my take.
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GE Choice Alert Wireless Alarm Control Center
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About this item
The GE Choice Alert Wireless Alarm Control Center controls all sensors and accessories for the GE Choice Alert Wireless Alarm System. Users can arm/disarm the alarm, monitor sensor alerts, program up to 16 sensors, organize sensors into four easy-to-recognize zones (including one dedicated alert zone), and add/remove any number of Choice Alert accessories.Note:
The Control Center is required to set up a GE Choice Alert Wireless Alarm System.
About this item
Important Made in USA Origin Disclaimer: For certain items sold by Walmart on Walmart.com, the displayed country of origin information may not be accurate or consistent with manufacturer information. For updated, accurate country of origin data, it is recommended that you rely on product packaging or manufacturer information.
The GE Choice Alert Wireless Alarm Control Center controls all sensors and accessories for the GE Choice Alert Wireless Alarm System. Users can arm/disarm the alarm, monitor sensor alerts, program up to 16 sensors, organize sensors into four easy-to-recognize zones (including one dedicated alert zone), and add/remove any number of Choice Alert accessories.Note:
The Control Center is required to set up a GE Choice Alert Wireless Alarm System.
GE Choice Alert Wireless Alarm Control Center
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Operating Distance: Up to 150 feet
|Assembled Product Dimensions (L x W x H):
|1.28 x 4.82 x 4.24 IN
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Q. Is the alarm siren built in to the control module? Can a seperate "wired" siren be added to the system?
- yes the siren is built in. and, no not a wired siren but there is a wireless siren on the product's micro-site http://www.jascoproducts.com/products/pc/GE-Choice-Alert-c64.htmby myles11/22/2010Was this answer helpful? (0) (0)Was this answer helpful?
- you can add a wireless one:GE Choice-Alert™ 45136 Wireless External Siren, it may be in store, if not you can find it online for $45.00.by Adonian7/15/2010Was this answer helpful? (2) (0)Was this answer helpful?
- I dont see how, is made for doors & windows.by dmvictum4/22/2012Was this answer helpful? (0) (0)Was this answer helpful?
- Yes, you could point a motion sensor toward her bed and you'd have to arm it in away mode, or if you could wake up to a small chime then install it in zone 4by myles4/13/2012Was this answer helpful? (1) (0)Was this answer helpful?
Q. If someone breaks in, what's to stop them from grabbing the control-center unit and smashing it on the floor during the 30-second entry delay?
- nothing, or even easier, simply unplug itby myles11/22/2010Was this answer helpful? (0) (0)Was this answer helpful?
- Nothing to stop them. But that is true with most alarm systems that aren't central station monitored.by ma064112/30/2009Was this answer helpful? (1) (0)Was this answer helpful?
Customer Reviews | 6 reviews | 4.2 out of 5
Customer Reviews
Customer review by ArizonaGuy
I bought this along with a garage door sensor to detect and alert when the garage door was being opened. Someone has been trying to get lucky with the outside keypad for the garage door opener and although their chances of success are small, I'd still like to be alerted if the garage door is opened in the middle of the night. I thought the instructions could be better detailed and I found some inaccuracies. It took some fiddling around to get things to work correctly. The "chime" option isn't really a chime, it's just a brief version of the alarm sound, more like a moderately loud beep. I had to subsequently get a signal repeater added to the system as the location where I wanted the receiver unit would not pick up the signal from the garage door sensor. The distance between the garage door sensor and the receiver is only about 30 feet, but there are two walls, one with a lot of metal plumbing and wiring running through it plus an aluminum ladder hanging on it. It all works and I'm very satisfied with it. I like the ability to add more modules in the future. I'm thinking of adding a motion detector.
Customer review by hp1003
Where to start? There are so many great things about this expandable alarm system. It only took about thirty minutes to install & set up the different sensors. It offers many of the same features as a wired $1000 alarm system for less than $100. First, it is expandable so you can add on whenever you need or want to. Second, it comes with four easy to use modes: "Away, Home, Chime, and Alert". The Home mode is an instant siren when a sensor is triggered. The Away mode is great because it gives you a 45 second exit delay and a 30 second entry delay. Away also features a count-down & count-up beep to remind you to turn off the alarm, and let you know the alarm is about to arm. Chime is great if you have children and want to know if they walk out or open a door. Alert is not the alarm, but it beeps when a door is open, and will shut off when the door is closed. You may have to put some time into learning how to arm the different modes, bypass sensors, etc. It is extremely simple, and comes with an easy to follow guide. While this is not a monitored alarm, it is still a great value and works great. For the low price for the alarm and accessories, this is a great alarm system. I would for sure recommend this.
Read all 6 reviews
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Originally posted on Fox Sports | Last updated 8/3/13
(Updates with rest of story.) By DAVE CAMPBELL AP Pro Football Writer The Minnesota Vikings still have a UCLA-educated punter with an erudite degree, one whose background was in soccer before trying his leg at another sport. This guy, though, doesn't play bass guitar in a grunge band. He only tweets a handful of times per week. He probably won't publicize his political views. Jeff Locke has replaced Chris Kluwe, and the newcomer couldn't be much more different than his predecessor, despite their common alma mater. But if there's any position in professional football where pizazz is optional, it's the punter. Kluwe's outsized personality was the exception and, well, part of the reason Locke was drafted by the Vikings in the first place. ''He is a very mature young man,'' special teams coordinator Mike Priefer said, adding: ''I felt like he was a young man who could handle the adversity, handle some pressure and handle the fact that he is going to be our punter this season.'' Lock...
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text:
|Publication number
|Publication type
|Application number
|Publication date
|May 17, 1994
|Filing date
|Jan 22, 1993
|Priority date
|Jun 16, 1988
|Fee status
|Publication number
|David Coates, Ian Sage, Simon Greenfield, George W. Gray, David Lacey, Kenneth J. Toyne, Lawrence K. Chan, Michael Hird
|Original Assignee
|The Secretary Of State For Defence In Her Britannic Majesty's Government Of The U.K. Of Great Britain And Northern Ireland
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (7), Non-Patent Citations (2), Referenced by (3), Classifications (9), Legal Events (4)
|External Links: USPTO, USPTO Assignment, Espacenet
This is a continuation of application Ser. No. 07/659,351, filed Feb. 19, 1991, now abandoned.
This invention relates to novel fluorinated 4"-cyano substituted terphenyls, to novel methods of preparation of such terphenyls, and to liquid crystal materials which incorporate them, in particular liquid crystal materials which show a nematic phase. Such liquid crystal materials may be used industrially as the working fluid of electro-optic display devices.
The use in liquid crystal materials of 4-alkyl and 4-alkoxy-4"-cyano terphenyls is described in GB 1433130, among many other publications and liquid crystal materials containing them are widely used. GB1433130 suggests the possibility of one of the three phenyl rings being laterally substituted, suggested substituents being the bulky methyl group or an unspecified halogen. No example of any such laterally substituted terphenyl is disclosed in GB1433130, no method for their preparation is given, and no preference for any particular halogen substituent is expressed.
GB2039937A describes liquid crystal materials which contain at least one laterally substituted 4-alkyl-4"-cyanoterphenyl of general structure: ##STR1## where R is alkyl, one of X1 or X2 being hydrogen and the other being methyl or a halogen preferably the bulky chlorine. A complex 6 step method for preparation of these terphenyls is described in GB2039937A, but no example of a terphenyl having X1, or X2 as a halogen is described, the implication being that none were made.
Mol. Cryst. Liq. Cryst. (1985) 123 169-177 describes 2 and 2' fluorosubstituted 4-alkyl-4'-cyanobiphenyls, but the data presented therein suggests that lateral fluorination increases the melting point of these compounds, and that their solubility in liquid crystal materials is low.
Laterally fluoro-substituted terphenyls of general structure: ##STR2## where R1 and R2 are alkyl or alkoxy are known and examples are given in EP-A-0132377. The preparation method described therein cannot easily be applied to the preparation of a terminally cyano substituted terphenyl.
The present invention has identified a class of terphenyls which on the basis of the prior art discussed above appear to be newly prepared and which show advantageous properties. A novel process for their synthesis which for the first time makes them also commercially viable has also been discovered.
FIG. 1 shows the synthesis of 4-alkyl-2'-fluoro-4"-cyano 1,1':4,4' terphenyl according to Example 1.
According to the present invention, fluorinated 4"-cyano substituted terphenyls are provided, of general formula I: ##STR3## wherein R1 is selected from alkenyl, H, R, RO, and RCO where R is alkyl or perfluoralkyl containing up to 12 carbon atoms, n is 1, 2 or 3 and the lateral fluoro substituent(s) may be in any of the available lateral substitution positions.
The structural preferences expressed below are inter alia on the basis of usefulness or constituents of liquid crystal mixtures and ease of preparation.
The group R1 is preferably alkyl or alkoxy, and may be straight chain (n), branched (iso) or may contain an asymmetrically substituted carbon atom so as to be a chiral group. When R1 is organic it preferably contains from 2 to 9 carbon atoms, especially from 2 to 7. Particularly useful compounds are those in which R1 is n-alkyl or n-alkoxy, or the chiral groups (+) or (-) 2-methylbutyl, 2-methylbutyloxy, 3-methylpentyl, 3-methylpentyloxy, 4-methylhexyl or 4-methylhexyloxy.
Preferably n is 1 or 2, and preferred structures for the terphenyl of formula I are those having fluoro substituents in the positions listed below in table 1, in which the nomenclature: ##STR4## is used for the lateral substitution positions.
2, 3"-difluoro
3, 3"-difluoro
3, 2"-difluoro
2, 2"-difluoro
3, 3'-difluoro
3, 2'-difluoro
2, 2'-difluoro
2, 3'-difluoro
3', 2"-difluoro
3', 3"-difluoro
2', 2"-difluoro
Of these, 4-alkyl or alkoxy, 2'-fluoro, 3"-fluoro, 2-fluoro, 3'-fluoro, 2', 3"-difluoro, 2, 3"-difluoro, and 3", 5"-difluoro substituted compounds of formula I are particularly preferred, especially 2'-fluoro compounds.
A suitable method for the preparation of a compound of formula I as defined above is one in which a boronic acid of formula II: ##STR5## wherein R1 is as defined in formula I, a and b are 0,1,2 or 3 is coupled with a benzonitrile of formula III: ##STR6## wherein X is chlorine, bromine or iodine, c is 0,1,2 or 3, provided (a+b+c) is 1,2 or 3, to form the compound of formula I.
In this method coupling occurs between the ring positions to which the B(OH)2 and X groups are attached. The indicated fluorine substituent(s) (F) may be in any of the available substitution positions. Preferably (a+b+c) is 1 or 2 and these are one or two fluorine substituents in the compounds of formulae II and III are preferably disposed so as to form compounds of formula I as listed in table I, and suitable fluoro substitution patterns for compounds of formulae II and III will be apparent to those skilled in the art.
Boronic acids II may be prepared starting from known biphenyls IV: ##STR7## wherein Y is chlorine, bromine or iodine, preferably bromine. Biphenyls IV in which R1 is hydrogen may be converted into those which R1 is R or RCO by means of a Friedel-Crafts reaction using an acyl chloride RCOCl to add a group RCO at the available 4-position, which may then be reduced to an alkyl group using for example hydrazine hydrate, or a trialkyl silane, triethyl silane being preferred.
To prepare the boronic acid II, the biphenyl IV is preferably first converted into a Grignard reagent by reaction of the biphenyl IV with magnesium metal in for example an ether such as tetrahydrofuran (THF). Conditions for preparation of Grignard reagents are well known.
The Grignard reagent may then be reacted with a trialkyl borate (R'O)3 B, where R' is alkyl, preferably methyl or isopropyl, conveniently in the same solvent in which the Grignard reagent was prepared. The resulting boronated product is then hydrolysed, for example with a mineral acid, preferably hydrochloric acid. The compound II may then be isolated and purified conventionally. Some methods for preparation of unfluorinated, monofluorinated and difluorinated biphenyls of formula IV are described in detail in WO 89/02425 and PCT/GB 88/00880.
Benzonitriles of formula III are known and are available commercially or may be synthesised, e.g. as described in GB 8804330 A or PCT/GB 89/00178. Preferably X is bromine. The coupling step is preferably carried out in the presence of a coupling agent, such as a palladium (O) catalyst, preferably tetrakis (triphenylphosphine) palladium (O). Conveniently an alcohol solvent may be used for the coupling reaction. The product compound of formula I may then be isolated and purified by conventional methods.
A third aspect of this invention is a liquid crystalline material, containing at least two components, at least one of which is a compound of formula I. This liquid crystalline material is preferably a nematic or cholesteric liquid crystalline material. Such materials may be used on electro-optic display devices such as watches and calculators etc, and also in thermochromic displays in which the colour or reflected light varies with temperature.
Compounds of formula I, in particular the preferred compounds referred to above, have a number of desirable properties which make them very useful components of liquid crystal materials. They often have higher nematic to isotropic (N-I) clearing point temperatures and lower melting points (C-N) than their unfluorinated counterparts. They generally have a high birefringence. They also generally show a higher solubility in commonly used liquid crystal materials than their unfluorinated counterparts. These advantages are not suggested by the prior art referred to above.
Suitable compounds for the other components of the liquid crystal material will be apparent to those skilled in the field, and will depend upon the properties such as dielectric anisotropy, birefringence, working temperature range etc., required in the material for the application for which the material is intended. Some types of suitable material are discussed briefly below.
Preferably as well as containing one or more formula I compounds the mixture contains one or more compounds of formula V: ##STR8## wherein Rb is alkyl or alkoxy, preferably containing 1 to 8 carbon atoms, and preferably straight chain, and wherein m is 0 or 1. Such compounds are included in the subject matter of GB 1433130.
Compounds of formula I have a positive dielectric anistrophy, and the material may for example contain other liquid crystalline compounds which have a positive dielectric anistrophy, for example as described in EP-A-0132377, particularly in FIG. 8 thereof and the related text.
The material may alternatively or also contain liquid crystalline compounds of low dielectric anistrophy, for example to form a mixture of intermediate dielectric anistrophy, or a thermochromic mixture. Some examples of such compounds are described in EP-A-0132377, particularly in FIG. 9 thereof and the related text.
The material may alternately or also contain liquid crystalline compounds having a high clearing point, for example to raise the N-I transition temperature. Some examples of such compounds are described in EP-A-0132377, particularly in FIG. 10 thereof and the related text.
To cause the material of this aspect of the invention to show a cholesteric (Ch) (or chiral nematic) phase the material must contain at least one compound containing an asymmetric carbon atom. This may be a chiral compound of formula I, or alternatively or also the material may for example contain one or more chiral compound of formula V above, e.g. (+) or (-) 4-(2-methylbutyl)-4'-cyano biphenyl or 4-(2-methylbutyloxy)-4'-cyano biphenyl.
The material may also contain one or more pleochroic dyes, for example the dyes described in EP-A-82300891.7.
The proportions of these components used in the material of this aspect of the invention will depend upon the intended application, and the material may usefully contain two or more compounds of formula I having different substituents or different dispositions of substituents on the terphenyl system.
The materials of this aspect of the invention may be used in any of the known forms of liquid crystal display device, for example a twisted nematic effect device, Freedericksz effect device, cholesteric memory mode device, cholesteric to nematic phase change effect device, dynamic scattering effect device, two frequency switching effect device, a "supertwist" effect device, or a thermometer using a thermochromic material. The method of construction and operation of such devices, and characteristics of a liquid crystal material suitable for use therein, are well known in the field. A liquid crystal display device which incorporates as its working fluid a material as described above, constitutes a fourth aspect of this invention.
The invention will now be described by way of example only with reference to FIG. 1 which shows the preparative route used in example 1 starting from 2-fluoro-4-bromo biphenyl to prepare a 4-alkyl-2'-fluoro4"-cyano terphenyl, R in FIG. 1 being alkyl.
In these examples: C-N=solid crystal to nematic liquid crystal transition, N-I=nematic liquid crystal to isotropic liquid transition, SA =smectic A liquid crystal phase. E7, E8 and K15 are Trade Marks of commercially available liquid crystal materials from BDH Ltd., Poole, GB and ZLI 1132 is a Trade Mark of a commercially available liquid crystal material from E. Merck GmbII, Darmstadt DE. The compositions of these materials have been published.
Preparation of compounds of general structure: ##STR9## where R1 is n-alkyl.
To a suspension of aluminium chloride (40 g; 0.3 mol) in dichloromethan (100 ml) was slowly added, with stirring and ice bath cooling, a solution of propionyl chloride (20.9 g; 0.29 mol) and 2-fluoro-4-bromobiphenyl (62.5 g; 0.25 mol) in dichloromethane (10 ml). The mixture was stirred for 16 hrs at 20� C. and then carefully poured into ice/water (500 g), the organic material was extracted into dichloromethane (2�200 ml), washed with brine (2�100 ml) and dried over sodium sulphate. After evaporation of the dichloromethane, the solid was crystallised from two volumes of industrial spirits. Yield 62.3 g; 70%.
The product from step (i) 60 g; 0.196 mol) was dissolved in trifluoroacetic acid (100 ml) and triethyl silane (76 ml; 0.476 mol) was added dropwise while the temperature of the mixture was maintained at 10�-20� C. and then stirred for 16 hrs at 20� C. The reaction mixture was then poured into water (1 L) and extracted with ether (3�100 ml). After drying and evaporation of the ether, the product was distilled under high vacuum (1.5 mmHg). Yield 51.4 g; 90%.
The product from step (ii) (10 g; 0.034 mol) in tetrahydrofuran (35 ml) was added dropwise to a suspension of magnesium turnings (0.88 g) in tetrahydrofuran (5 ml). The mixture was warmed to 75� C. when the Grignard reaction started. Further of the bromo compound was slowly added and the external heat source removed, a gentle reflux being maintained. After complete addition, the mixture was heated for 30 mins under reflux and then cooled to 15� C. A dry nitrogen atmosphere was introduced and trimethyl borate (3.77 g; 0.0363 mol) was slowly added and the mixture stirred at 15�-20� C. for 16 hrs. A 20% soln of hydrochloric acid (50 ml) was slowly added, the organic layer was separated, and the aqueous layer extracted with ether (2�50 ml). The combined organic layers were washed with brine and dried over sodium sulphate. Upon evaporation of the solvents a yellow solid was obtained. Yield 8.7 g; 100%.
The crude product from step (iii) (8.7 g; 0.034 mol) 4-bromobenzonitrile (5.0 g; 0.0275 mol), tetrakis(triphenylphosphine) palladium (0.64 g) and methylated spirits (20 ml) were heated under reflux with vigorous stirring for 5 hrs. After cooling, the organic layer was separated, washed with water, dried over sodium sulphate and evaporated to dryness. The crude product was purified by column chromatography on silica gel followed by crystallisation from ethyl acetate. Yield 5.3 g; 51%.
The properties of some compounds prepared by the method of example 1, using an appropriate acyl chloride in step (i) are listed below:
TABLE 2__________________________________________________________________________RefR1 Liq. Crst. Transitions (�C.)__________________________________________________________________________ ##STR10##__________________________________________________________________________
Other compounds of formula I were prepared using a method analogous to that of example 1, as listed below:
TABLE 3__________________________________________________________________________RefR1 StructureLiq. Cryst. Transitions (�C.)__________________________________________________________________________ ##STR11## ##STR12## ##STR13##__________________________________________________________________________
The following difluorinated terphenyls were prepared using the method of example 1 and appropriately fluorinated starting materials;
TABLE 4__________________________________________________________________________RefR1 StructureLiq. Cryst. Transitions (�C.)__________________________________________________________________________ ##STR14## ##STR15## ##STR16##__________________________________________________________________________ note: () indicates temperature to which nematic N phase supercools.
Some comparative data for unfluorinated analogues of these compounds is listed below:
TABLE 4__________________________________________________________________________RefR1 StructureLiq. Cryst. Transitions (�C.)__________________________________________________________________________ ##STR17##__________________________________________________________________________
From this data it can be seen that the melting point of the fluorinated compounds of the invention is substantially lower than those of the unfluorinated analogues, with little change in the breadth of the nematic phase.
Some data relating to liquid crystalline mixtures containing compounds of the invention is presented in tables 5 and 6 below. These compositions contain biphenyls and terphenyls of formula V. E7 having the composition: ##STR18##
From tables 5 and 6 it can be seen that the fluorinated compounds of the invention have an improved birefringence and solubility in liquid crystals containing them relative to their unfluorinated analogues and that their incorporation in liquid crystal materials such as E8 can improve the N-I transition temperature and birefringence.
It was found to be difficult to freeze a 30 wt % solution of 1b in E7, and this factor allows the N-I and Δn of mixtures to be increased.
TABLE 5______________________________________ ViscosityBirefringence (Δn) (cSt) atin K15 in E7 Solubility in E7 20� C. inat 27� C. at 20� C. (wt %) at ZLIRef below N-I below N-I -10� C. -20� C. 1132 (η)______________________________________T15 0.4138 0.330 9* 1091b 0.4531 0.377 23 20 2281c 0.343 10 1952e 162f 152g 12______________________________________ (*in the biphenyls which make up E7)
TABLE 6______________________________________ E8 E8 + 20 wt % lb______________________________________N-I (�C.) 71 93η(cSt at 20� C.) 54 75.7Δn (20� C.) 0.2463 0.278______________________________________
|Cited Patent
|Filing date
|Publication date
|Mar 15, 1974
|Aug 10, 1976
|The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland
|Liquid crystal compositions
|Aug 20, 1976
|Mar 7, 1978
|The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland
|Optically active cyano-biphenyl compounds and liquid crystal materials containing them
|Dec 5, 1985
|Sep 29, 1987
|The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland
|Compounds containing a fluorobiphenylyl group and their use in liquid crystal material and devices
|Dec 20, 1985
|Apr 4, 1989
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Liquid crystal phase
|Dec 20, 1985
|May 30, 1989
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Smectic A liquid crystal compositions
|Feb 17, 1987
|Jul 9, 1991
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Electrooptical display element
|Feb 27, 1989
|Sep 21, 1989
|Merck Patent Gmbh
|Mol. Cry. & Liq. Cry. vol. 158B pp. 209 240. May 1988.
|Mol. Cry. & Liq. Cry. vol. 158B pp. 209-240. May 1988.
|Citing Patent
|Filing date
|Publication date
|Apr 1, 1994
|Oct 3, 1995
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Cyanophenylpyri (MI)dine derivatives and liquid-crystalline medium
|Dec 13, 1990
|May 21, 1996
|The Secretary Of State For Defence In Her Britannic Majesty's Government Of The U.K. Of Gt. Britain And Northern Ireland
|Light modulating material comprising polymer dispersed liquid crystals
|Jul 13, 2000
|Nov 18, 2003
|Merck Patent Gmbh
|Nematic liquid crystal mixtures and a matrix liquid crystal display
|U.S. Classification
|252/299.66, 252/299.01, 570/127
|International Classification
|Cooperative Classification
|European Classification
|Oct 14, 1997
|Fee payment
Year of fee payment: 4
|Oct 22, 2001
|Fee payment
Year of fee payment: 8
|Feb 20, 2002
Owner name: QINETIQ LIMITED, UNITED KINGDOM
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SECRETARY OF STATE FOR DEFENCE, THE;REEL/FRAME:012831/0459
Effective date: 20011211
|Oct 17, 2005
|Fee payment
Year of fee payment: 12


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Justice League: Crisis On Two Earths (US - DVD R1 | BD RA)
Warner Home Video reveals details on DVD and Blu-ray releases of the feature
Starring: N/A (Animation)
Released: 23rd February 2010
SRP: $24.98 (2-Disc DVD)
Further Details:
Warner Home Video has announced 1-disc DVD ($19.98), 2-disc DVD ($24.98), and 2-disc Blu-ray ($29.99) releases of Justice League: Crisis On Two Earths for the 23rd February. The only extra material on the 1-disc DVD will be first looks at Batman Under the Red Hood, Green Lantern, and Superman/Batman Public Enemies, plus trailers. The 2-disc DVD and Blu-ray will include that along with a new animated short ("The Spectre"), a new featurette ("The New World"), A Better World" Part 1 and 2 which were previously on Justice League Unlimited S2, and more. We've attached a advert with some early package art below:
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< 1k
in the U.S.
since 1880
- Gender: Unknown
Pronunciation of Zurishaddai
How popular is the name "Zurishaddai" in the U.S.?
Out of 5,647,426 records in the U.S. Social Security Administration public data, the name "Zurishaddai" was not present. It is possible the name you are searching has less than five occurrences per year. You might want to use a short version of your first name or perhaps your nickname.
On the other hand, you simply have a name that no one else in America is using. For 135 years only your parents have thought of using your name. Hoorah! You are a unique individual.
What does the name "Zurishaddai" mean?
Z is for zip, the quickness in your step!
U is for unique, your love of life.
R is for reasonable, your understanding way.
I is for impressive, your list of qualities.
S is for sensible, the practical side.
H is for hope, the encouragement you give.
A is for agreeable, the best side of you!
D is for dignity, no one disputes this trait!
D is for dazzle, the sparkle of you.
A is for acquaintance, the many friends you know.
I is for interest, you show in others.
Your name in reverse order is "Iaddahsiruz". A random rearrangement of the letters in your name (anagram) will give "Dadruhizais". How do you pronounce that?
Now try the names of everyone you know including friends, cousins, neighbors, classmates, co-workers or your pets. Even your favorite anime, TV or movie characters! See what their names mean. Remember, this is purely just for fun.
Past life for Zurishaddai born Dec 6, 1998
I do not know how you feel about it, but you were a female in your last earthly incarnation. You were born somewhere around the territory of Portugal approximately on 400. Your profession was jeweler and watch-maker.
As an inquisitive and inventive person, you liked to get to the very bottom of things and to rummage in books. Talent for drama, natural born actor. The world is full of ill and lonely people. You should help those, who are less fortunate than you are.
Name poster for Zurishaddai
(click to save the high quality version)
Here's something for you to ponder on...
The Theory Behind The Name Game - Finding a good baby name is one of the dilemmas that plague parents who live in a modern setting. Parents do have the right to be conscious about the name.


text:
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Gizard the lizard wizard - skyrim mod list, Skyrim mod list & setup. this is my mod list. there are many like it, but this one is mine. my mod list is my best friend. it is my life. i must master it as i must.User:neovalen/skyrim revisited - legendary edition - s.t.e, Introduction and summary . skyrim revisited: legendary edition is a mod guide designed to keep up with the ever changing skyrim mod landscape. key tenets of this mod. Unofficial skyrim legendary edition patch: version history, Unofficial skyrim legendary edition patch: version history by the unofficial patch project team. bugs fixed by official bethesda patches will be stricken through and.
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text:
Medicare and the Budget
Published: October 7, 1997
To the Editor:
The Congressional Budget Office's forecast on the deficit for 1997 is down to about $23 billion (news article, Oct. 4). This is the same amount as the annual total estimated to be lost to the Medicare program from waste and fraud (news article, July 17). Thus, Congress has it within its power to eliminate the deficit now rather than in the year 2002, the target date proposed by the President, simply by effective action to cut Medicare fraud.
Congress should appropriate $150 million to hire 3,000 Medicare auditors and investigators. You would see a drastic reduction in fraud immediately.
Kent, Wash., Oct. 4, 1997


text:
Good and Sad Thoughts
I slept well last night. I havent slept that well in a long time. Maybe the dinner I went to had something to do with it. When I woke up, I felt pretty rested, and I dont remember having any bad dreams.
I did laundry, like usual. Thats my big thing on Sundays. Other than that, its just a little housework and making something for dinner.
D borrowed my car to go meet up with his friend, so it was just me and A for most of the day. She helped out a little around the house, then went out with some friends. So I ended up with some alone time, which I find myself wanting more and more.
I still am seriously considering splitting with D, after my bankruptcy has been discharged, and we can sell the house without a problem. He wants to sell the house anyway, and get something out in the country. But right now, Im leaning toward splitting the sale price of the house with him, and then leaving him.
Ive been thinking about doing that more and more. Part of me doesnt want to, but its such a small part of me that I dont really see staying with him as much of an option anymore.
Hes still drinking, and we never do anything together. I've tried. I dont know if Im supposed to try harder, but he doesnt reach out to me and try to be part of a couple with me. He wont stop drinking, and he wont even consider counseling with me. Im actually quite tired of trying for as long as I have to keep our marriage going. Its kind of like there is nothing there to keep going.
In a way it breaks my heart. After my parents divorce, I never wanted to marry. When D and I first got married, I vowed not to end up like my parents. After A was born, I vowed to never let her feel like I did when my parents went through their divorce.
But shes almost 19, and I guess shell be able to handle it if I leave him. She already has very mixed emotions about the whole thing, now that shes learned that hes drinking again. She told my mother that she cant stand to look at D.
I hope shes talking to her therapist about her feelings, because shes got to be pretty mixed up about his drinking. For years he reassured her that he wouldnt drink. He knows how much its always upset her. It makes me feel like he doesnt care about her feelings or mine anymore.
Im just tired of dealing with him, and wanting so much to leave him and be alone. He doesnt help around the house, even though he usually doesnt go anywhere during the day. No sooner do I clean the house, then he dirties it up, and it frustrates me to no end.
I know I sound like Im bitching, but I'm not. It's more a sadness than anything. If I dont vent some of my feelings about it all, I feel like Ill explode if I think about it anymore.
Maybe Im trying to fight the feeling that I know what I have to do. I dont know. I feel like Im living in a make believe world to think that I can manage to stay with him the rest of my life. But it kind of makes me want to cry. Ive been with him so long, and can never get those years back. And I somehow feel like Ive wasted a lot of years on a marriage that is gone.
Anyway, D got home, and told me there was some kind of problem with my car. Which kind of freaked me out. Tomorrow is my session with Dr H, and the drive is about 40 miles. I NEED my car tomorrow. He says it should get me there, so Im hoping it will.
I hate feeling so needy for Dr H, and feeling like if I miss an appointment with her its going to affect me so negatively. So, I kind of worked myself up, and got really anxious about my car. But Ive been trying to stay calm. Ill just have to see how it goes tomorrow.
I should be ok.
Im really excited to tell Dr H about last night, and also about standing up to my mother the way I did. I think Ive had a pretty good week.