text:
|Publication number
|Publication type
|Publication date
|Dec 16, 1975
|Filing date
|Jul 23, 1973
|Priority date
|Jul 23, 1973
|Also published as
|Publication number
|Anthony F Finelli
|Original Assignee
|Goodyear Tire & Rubber
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (7), Referenced by (9), Classifications (14)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent 11 1 1111 3,926,919
Finelli Dec. 16, 1975 POLYURETHANES CHAIN-EXTENDED 3,188,302 6/1965 Lorenz 260/77.5 AM WITH 2 2'-DlAMINO 3.194.793 7/ 1965 Kogon 260/75 NH 3,291,859 12/1966 Tobolsky 260/75 NH 1 Inventori Anthony Finelli, Akron, Ohio 3.446.781 5/1969 Brownward 260/75 NH [73] ASS-lgnee2 The Goodyear Tire & Rubber 3,660,326 5/1972 Mallabar 260/77.5 AM
Company, Akron, Ohio Primary ExammerH. S. Cockeram 1 Flledi J y 23, 1973 Attorney, Agent, or Firm-F. W. Brunner; H. C. 211 Appl. No.: 381,464 Young 52 us. c1 260/75 NH; 260/2 N; 260/13; [57] ABSTRACT 260/32.8 N; 260/33.6 UB; 260/77.5 CR; A cyred polyurethane P p y reactmg 26 /77 5 2 77 5 AN 2,2'-d1aminodiphenyldisulfide with at least a part or 51 Int. (:1. ..C08G 18/28; C08G 18/32; o excess isocyanato groups in a Composition or 0 18/62 mixture derived by the method which comprises mix- [58] Field of sear-611.... 260/75 NH, 77.5 AN, 830 P, ing an excess of polyisocyanate having an isocyanate 2 0/75 NH, 775 AM functionality of 2 to 3 with a polymeric polyol having an hydroxyl functionality of 2 to 3 and a molecular [56 References Cited weight in the range of about 500 to about 6000, and
UNITED STATES PATENTS preferably in the range of about 800 to about 5000. 2,830,038 4/1958 Pattison 260/830 P v5 Claims, N0 Drawings 3,158,586 11/1964 Krause 260/830 P POLYURETHANES CHAIN-EXTENDED WITH 2 ,2 -DIAMINODIPHENYLDISULFI DE This invention relates to polyurethanes. It more partlcularly relates to isocyanate-terminated polyol prepolymers which have been extended or cross-linked with a diamine curative.
Diamines play a unique part in shaping the characteristics and structure of polyurethanes. Their polyurea long sought after quality. Typically, polyurethanes.
with good tensile and elongation can also be characterized by having medium to high moduli which is more characteristic of a plastic than a rubber. Therefore, if a rubbery polyurethane is desired, then a polyurethane must be sought with good tensile and elongation and a relatively low modulus. Discovery of a suitable curative for this purpose would be important.
The most commonly used diamine curing agents are hindered substituted aromatic diamines of which 3,3- dichlorobenzidine (ODCB) and 4,4-methylene-bis-(2- chloroaniline) (MOCA) are representative. To a lesser extent unhindered aromatic diamines such as 4,4- methylenedianiline (MDA) and the phenylene diamines are used. A main advantage of the hindered diamine curing agents is their substantially longer pot life which can typically facilitate greater ease in molding operations. However, this very substantial benefit is achieved with some disadvantageous results for some purposes. For example, prepolymers of tolylene diisocyanateand a mixture of propylene adipate and tetramethylene adipate when cured with either of ODCB or MOCA have been found to yield polyurethanes with good tensile and elongation but with a modulus characteristic of a plastic rather than a rubber.
It is, therefore, an object of this invention to provide a useful cured polyurethane resulting from extending or cross-linking an isocyanate-terminated prepolymer of a polyol with a particular diamine.
In accordance with this invention a polyurethane has been discovered which is prepared by the method which comprises reacting 2,2'-diaminodiphenyldisulfide with at least a part or all of excess isocyanato groups in a composition of mixture derived by the method which comprises mixing an excess of a polyisocyanate having an isocyanate functionality of 2 to 3 with a polymeric polyol having an hydroxyl functionality'of 2 to 3 and a molecular weight in the range of about 500 to about 6000, and preferably in the range of about 800 to about 5000.
More specifically, the invention is preferably a cured polyurethane prepared by reacting the 2,2-diaminodiphenyldisulfide with a prepolymer prepared by the method which comprises reacting a polyisocyanate having an isocyanate functionality of about 2 to about 3 with a polymeric polyol having an hydroxyl functionality of about 2 to about 3 with a ratio of the isocyanate groups of the polyisocyanate to the hydroxyl groups of 2 the polyol in the range of about 1.3 to about 12. preferably about l.5 to about 3, and where the ratio of the amine groups of the said diamine to the excess isocyanato groups over the said hydroxyl groups is in the range of about 0.5 to about 1.1, preferably about 0.8 to about 1.0.
It should be understood that the method of preparing the polyurethane of this invention can be modified by the addition of up to about 1 to about 3 equivalents of monomeric hydrocarbon polyols having 2 to 3 hydroxyl groups and containing about 2 to about 15 carbon atoms to the said polymeric polyols. In this case, the ratio of isocyanato groups of the polyisocyanate is to the combined hydroxyl groups of the polymeric and monomeric polyols. Representative of such polyols are ethylene glycol, 1,3-propane diol, l,4-butane diol, 1,5- pentane diol, 1,6-hexane diol and decamethylene glycol.
The polyurethane reaction mixtures used in this invention are typically liquid mixtures commonly used to prepare polyurethanes, and particularly flexible polyurethanes, by the well-known one-shot, prepolymer or semiprepolymer techniques. The materials are typically reacted at temperatures in the range of about 20 to about 150C. and usually from about 20 to about 100C.
Generally, the polyurethane reaction mixtures are prepared from at least one reactive hydrogen-containing polymeric material, such as the polyol, as determined by the Zerewitinoff method, at least one organic polyisocyanate and the curative. It is to be understood that the polyurethanes referred to in this specification may also contain polyurea linkages. A solvent can be used with the reaction mixture to facilitate its use in the form of a fluid mixture or solution although it is preferred to use the reaction mixture with only a minor amount of solvent, if any. If solvent is used, it can be added to form a mixture containing from about 40 to about percent solids. However, a higher or lower concentration of solids can be used. When the solids concentration is low, the individual applications will deposit a thin layer of the polyurethane polymer, and a large amount of the solvent will have to be removed during the curing process. A solids concentration of 45 percent or higher is generally desired, if a solvent is used.
Other methods known to those skilled in the art of preparing polyurethane reaction mixtures with or without solvents being present may also be used.
A catalyst or accelerator can be used to facilitate the reaction. which results in substantially reduced setup time, and thus enhances the thixotropic properties of the polyurethane mixture. Well-known polyurethane catalysts are useful for this purpose such as tertiary amines and the tin salts of fatty acids and also accelerators such as mercaptobenzothiazole.
The reactive hydrogen-containing polymeric material used typically comprises at least one member selected from the group consisting of polyester polyols, polyether polyols and hydroxyl-terminated unsaturated polymeric polyols. The hydroxyl-terminated unsaturated polymeric polyols typically have a molecular weight of from about 2000 to about 4000 and a hydroxyl functionality of from about 2 to about 3. The reactive hydrogen-containing material generally used, other than the hydroxyl-terminated unsaturated polymeric polyol, has a molecular weight in the range of from about 700 to about 5000, and usually from about 3 1000 to about 3000. (If the molecular weight of the reactive hydrogen-containing material is too low, the polyurethane will not have sufficient elasticity.) Generally, the polyester polyols are the preferred active hydrogen-containing material where high strength and solvent resistance are desired. 1
Representative examples of polyester polyols are the condensation products of low molecular weight polyols with an organic polycarboxylic acid or anhydride. Representative low molecular weight polyols are glycols such as ethylene glycol, propylene glycol, butylene glycol, pentylene glycol. decamethylene glycol, etc. Representative examples of the organic dicarboxylic acids that can be used are succinic acid, glutaric acid, adipic acid, phthalic acid, terephthalic acid, isophthalic acid, suberic acid, sebacic acid, pimelic acid and azelaic acid. The anhydrides of such acids can be used in place of the acid. If desired, from about 1 to percent by weight of a triol or higher polyfunctional polyol or polyfunctional acid can be present to produce branching in the polyurethane polymer.
Further examples of polyesters are caprolactone polyesters. The caprolactone polyesters are substantially linear, hydroxyl-terminated polymers prepared by reacting a caprolactone having 6 to about 8 carbon atoms in the ring, preferably 6 carbon atoms, with a glycol having 4 to 7 carbon atoms and preferably 4 to 6 carbons. Various suitable caprolactones include 6- caprolactone, zeta-caprolactone and eta-caprolactone. Alkyl substituted caprolactones can be used with alkyl substituents containing 1 to 2 carbon atoms selected from methyl and ethyl radicals such as methyl 5- caprolactone. Desirably, the caprolactone polyester has a molecular weight in the range of about 800 to about 2200, preferably about 1200 to about 2100, with corresponding hydroxyl numbers in the range of about 140 to about 45 and about 95 to about 55 respectively.
Polyether polyols useful in preparing the polyurethanes of this invention can be prepared by polymerizing or copolymerizing alkylene. oxides such as ethylene oxide, propylene oxide, and butylene oxides, by polymerizing or copolymerizing the low molecular weight glycols, or by the reaction of one or more such alkylene oxides with the glycols or with triol, or with a polycarboxylic acid such as phthalic acid. The polyether polyols include polyalkylenearyl ether glycols or triols,
polytetramethylene ether glycols, polyalkylene etherthioether glycols or triols and alkyd resins. Generally the polytetramethylene ether glycols are the preferred polyether glycols.
It is usually preferred that the hydroxyl-terminated unsaturated polymeric pol yol has a molecular weight of from about 2000 to about 4000 and a corresponding hydroxyl number of from about 50 to about 25. The hydroxyl-terminated unsaturated polymeric polyols used in this invention are unsaturated polymers of the type prepared by polymerizing unsaturated monomers comprising from about 70 to about 100 percent conjugated dienes selected from the group consisting of 1,3- butadiene and isoprene and up to about 30 percent sytrene with the aid of organic peroxy catalysts to provide polymers which are generally terminated at both ends of their chain with hydroxyl groups and have a hydroxyl functionality of from about 2 to about 3 and usually from about 2.1 to about 2.8. The preferred hydroxyl-containing polymeric polyols are polybutadiene polyols, polyisoprene polyols, butadiene-styrene copolymer polyols having about 80 to 90 percent units thereof. The organic polyisocyanates can be aromatic,
aliphatic or cycloaliphatic or combinations of these types.
Representative examples of such polyisocyanates include the toluene diisocyanates, m-phenylene diisocyanate, 4-chlorol ,3-phenylene diisocyanate, 4,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, 1,10-decamethylene diisocyanate, 1,4- cyclohexylene diisocyanate, 4,4'-methylene-bis(cyclohexylisocyanate), 3,3-dimethyl-4,4'-diphenylmethane diisocyanate and l,S-tetrahydronaphthalene diisocyanate and mixtures of such diisocyanates. For the purposes of the present invention, the toluene diisocyanates, diphenylmethane-4,4'-diisocyanate, 3,3 dimethyl-4,4-bis-phenylene diisocyanate, 4,4-methylene-bis(cyclohexylisocyanate) and 3,3'-dimethyl-4,4- diphenylmethane diisocyanate are preferred. For convenience, these diisocyanates are referred to as TDI, MDl, TODl, H MDl and DMMDl, respectively.
Various non-reactive solvents known to those skilled in the polyurethane art can be used for the preparation of the prepolymer solutions and polyurethane reaction mixtures, if a solvent is desired. Representative examples of the solvents are aromatic solvents such as benzene, xylene and toluene and the liquid lower ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone and diisobutyl ketone. If the polyurethane reaction mixtures are to be used to prepare the cured polyurethanes in confined areas which are subject to explosive hazards, nonflammable chlorinated solvents can be used to form nonflammable polyurethane reaction mixtures. Mixtures of solvents may also be used to obtain satisfactory spreading properties and evaporation rates when the polyurethane spray composition is applied to a polymeric surface.
To enhance the cured polyurethanes hydrolysis resistance, about 1 to about 15, preferably about 2 to about 5, weight percent of an epoxy resin and at least sufficient to give an excess of epoxide groups relative to the total excess of amino groups of the diamine curative over the said excess isocyanato groups.
Thus, an excess of epoxide groups is required over the excess amino and/or hydroxyl groups of the curative, such as at least about 5 to about 50 equivalent percent excess, based on two epoxy groups per amino (NH group, to provide a polyurethane composition containing sufficient free epoxide groups.
Hydrolysis resistance is typically determined by immersion in distilled water at 158F. A substantial retention of tensile strength and elongation after 12 days immersion can be related to a substantial resistance to hydrolysis. The tensile and elongation are normally determined at about 25C. by methods typically used by those skilled in the art.
Typical epoxy resin compounds can be used in this invention and are well known to those skilled in the epoxy resin art. The general characteristic of this class of material is the presence of epoxy groups, which are of the formula:
Ordinarily, epoxy resins contain a plurality of terminal epoxy groups. Usually epoxy resins are of moderately high molecular weight, containing more than 10, and usually more than carbon atoms per molecule, although in this invention epoxy compounds containing fewer carbons may be used.
The epoxy group content of such resins is usually expressed as the epoxide equivalent or grams of resin containing a gram equivalent of epoxide. The equivalent of a commercial resin is generally expressed as a range, such as ll75, l50200, etc. Epoxy resins having low epoxide equivalents, in the range of from about 125 to about 250, are usually preferred because of their lower viscosities, although higher equivalents, including 125 to about 525 with melting points up to about 75C., offer advantages where viscosity is not a factor,
Epoxy resins are typically prepared by reaction of a polyfunctional epoxy compound with a compound containing two or more hydroxy radicals, producing epoxy resins comprising one or more ether linkages, joining organic radicals and terminating in epoxy groups.
The members of a preferred class of epoxy resins for use in the process of this invention arethe products of reactions of polyfunctional epoxy compounds with aromatic polyhydric phenolic compounds. The polyfunctional epoxy compound used in this connection may be a diepoxide, distinguished from the class of epoxy resins by its relatively low molecular weight, illustrative of which are diepoxybutadiene, and bis( 2,3- epoxy-2-methylpropyl)ether. More usually, the polyfunctional epoxy compound is a haloepoxy compound, most commonly, epichlorhydrin. Reaction of epichlorhydrin, for example, with an aromatic polyhydric phenolic compound results in the formation of a polymer containing ether linkages between arylene radicals derived from the initial aromatic polyhydric compound and hydroxy-alkylene radicals derived from the initial haloepoxy compound, the polymers terminating in epoxyalkyl radicals. The aromatic polyhydric compound may comprise a monocyclic phenol such as a resorcinol, a polycyclic phenol such as p,p -(dihydroxy)-bisphenol, or phenolic resin such as a phenol-formaldehyde resin. In particular, there are preferred in the process of this invention, epoxy resins derived from the reaction of epichlorhydrin and bisphenols. Illustrative of various suitable bisphenols are, for example, p,p-oxybisphenol, p,p -methylene bisphenol, 2,2- bis( 4-hydroxyphenyl )prop ane, 2,2-bis( 4-hydroxy-2- methylphenyl )propane, 2,2-bis( 2-t-butyl-4-hydroxyphenol )propane, 2,2- bis( 2,5-dimethyl-4-hydroxyphenyl)propane, 2,2-bis( 2-chloro-4-hydroxyphenyl)- propane, 2,2-bis( 2-bromo-6-fluoro-4-hydroxyphenyl propane, l, l-bis( 4-hydroxyphenyl )ethane, l, l-bis( 4- hydroxyphenyl )isobutane, l l-bis( 2-isopropyl-4- hydroxyphenyl )isobutane, 2,2-bis( 4-hydr'oxyphenyl butane, 4,4-bis( 4-hydroxyphenyl)heptane, l, l-bis( 4- hydroxyphenyl )dodecane, and 2,2-bis( 4-hydroxyphenyl)hexadecane.
Preferred resins for this invention are derived from epichlorhydrin and 2,2-bis(4-hydroxyphenyl)propane with an epoxide equivalency of about 150 to about 220, preferably about 175 to about 210. Resins which are pourable liquids at about 25C. are preferred but others can be used in solution. Typical resins are those obtainable under the tradenames Epon 828 and Epon 1001 from the Shell Chemical Company.
Further illustrative examples of suitable epoxy resins and methods of preparation may be found in US. Pat. No. 3,350,406.
The practice of this invention is further illustrated by reference to the following examples which are intended to be representative rather than restrictive of the scope of the invention. Unless otherwise indicated. all parts and percentages are by weight.
EXAMPLE I A prepolymer was prepared by reacting 100 parts -ethylene-20-propylene adipate of 1800 molecular weight, 200 parts tetramethylene adipate of 2000 molecular weight and an amount of 80/20 mole ratio of 2,4/2,6-tolylene diisocyanate to yield an isocyanate/hydroxyl mole ratio of 2: l.
The prepolymer was diluted in toluene, methyl ethyl ketone and 10 percent cellulose acetate butyrate in methyl ethyl ketone as follows: /30/30/5. The diluted prepolymer analyzed 2.0 weight percent excess isocyanato groups (NCO) based on the solution. An extender solution was prepared from 2.4 parts 2,2- diaminodiphenyldisulfide in 6 parts methyl ethyl ketone. This was added to 50 parts diluted prepolymer. A film was drawn on a polyethylene slab and allowed to stand at room temperature (about 25 C.) to evaporate the solvents. The film was then placed in an oven at 50C. for 16 hours. The film showed the following physical properties as determined at about 25C. by methods normally used by those having skill in the rubber testing art.
2,2'-diaminodiphenyldisulfide shows a substantially lower modulus than the elastomer from MOCA extension prepared'according to the method of Example I but substituting MOCA for the 2,2-diaminodiphenyldisulfide as shown in Table 2.
Table 2 Tensile (psi) 5800 Elongation (7:) 630 Thickness (inches) 0.016 Modulus (psi):
100 percent 700 300 percent 1300 500 percent 3300 EXAMPLE II A prepolymer was made and diluted as in Example I and then cured with various amounts of 2,2- diaminodiphenyldisulfide. The make up is shown in Table 3. Films were drawn on polyethylene slabs, al-
lowed to cure at room temperature and identified in Table 4 as samples l. ll and Ill.
Table 3 I ll lll Diluted prepolymer 50 50 50 2.2-Diaminodiphenyldisulfide 2.9 1.6 2.9 Z-Mercaptohenzothiazole 0.5 0.5 I .0 Methyl ethyl ketone 60 6.0 6.0 Pot life (minutes) 80 74 58 The Z-mercaptobenzothiazole helps reaction and lessen the long pot life.
to speed the EXAMPLE Ill The prepolymer from Example 1 at 3.6 percent free or excess NCO was used in a molten casting with the 2.2'-diaminodiphenyldisulfide mixed with 80-ethylene- -propylene adipate according to the following rec- Polyester prepolymer 200 parts 2.2'-diaminodiphenyldisulfide 18.0 parts 80-eth \'lene-20-propylene adipate 1800 molecular weight) 15.0 parts Table 5 Tensile (psi) 3000 Elongation (7:1 680 Modulus (psi):
100 percent 400 300 percent 550 Crescent tear (lbs/in) 225 After 3 days in water at 158F:
Tensile/Elongation 2000/805 Gchman low temperature torsion test The sample showed exceptional flex properties in the Ross Flex Test:
Number of flexes 413.048
Rating I (no growth in hole) Volume change in 70/30 isooctane/toluene for- 4 days at room temperature 178% 8 EXAMPLE IV A casting for cure at room temperature was made from the prepolymer of Example I and 2,2-diamin0diphenyldisulfide in polyester according to the following recipe as shown in Table 6.
Table 6 Prepolymer 200 parts 12 '-diaminodiphenyldisulfidc 18.5 -ethylene-20-propylene adipate 1800 molecular weight) 20 The molten prepolymer was at 180F. and the molten diamine/polyester was at 220F. The mix was used to cast a tensile sheet. It was allowed to cure at room temperature. The material showed a Shore A hardness of 81 and a tensile (psi)/elongation of 3700/690.
While certain representative embodiments and details have been shown for the purpose of illustrating the invention, it will be apparent to those skilled in this art that various changes and modifications may be made therein without departing from the spirit or scope of the invention.
What is claimed is:
1. A cured polyurethane prepared by the method which comprises curing a composition derived by the method which comprises mixing an excess of a polyisocyanate having an isocyanate functionality of 2 to 3 with a polymeric polyol having an hydroxyl functionality of 2 to 3 and a molecular weight in the range of about 500 to about 6000 by reacting therewith, the primary diamine, 2,2'-diaminodiphenyldisulfide at a temperature in the range of about 20C to about C, where the ratio of isocyanato groups of the polyisocyanate to the hydroxyl groups of the polymeric polyol is in the range of about 1.3 to about 12 and where the ratio of amine groups of said 2,2-diaminodiphenyldisulfide to excess isocyanato groups of said polyisocyanate over hydroxyl groups of said polymeric polyol is in the range of about 0.5 to about 1.1.
2. The cured polyurethane of claim 1 prepared by reacting 2,2"diaminodiphenyldisulfide with a prepolymer prepared by the method which comprises reacting a polyisocyanate having an isocyanate functionality of about 2 to about 3 with a polymeric polyol having an hydroxyl functionality of about 2 to about 3 with a ratio of the isocyanato groups of the polyisocyanate to the hydroxyl groups of the polyol in the range of about 1.3 to about 1 2, and where the ratio of the amine groups of the said diamine to the excess isocyanato groups over the said hydroxyl groups is in the range of about 0.5 to about 1.1.
3. The cured polyurethane of claim 1 modified by the addition of up to l to about 3 equivalents of monomeric hydrocarbon polyols having 2 to 3 hydroxyl groups and containing 2 to about 15 carbon atoms.
4. The cured polyurethane of claim 1 prepared by reacting the materials at a temperature in the range of about 20 to about 150C. where the ratio of the isocyanato groups of the polyisocyanate to the hydroxyl groups of the polymeric polyol is in the range of about 1.5 to about 3, where the ratio of the amino groups of said diamine to excess isocyanato groups of said hydroxyl groups is in the range of about 0.8 to about 1.0, where said polyisocyanates are selected from toluene diisocyanates, m-phenylene diisocyanate. 4-chloro-l .3-phenylene diisocyanate, 4,4 -tetramethylene diisocyanate, l,6-hexamethylene diisocyanate, l l -decamethylene diisocyanate, l ,4-cyclohexylene diisocyanate. 4.4 -methylene-bis( cyclohexylisocyanate), 33 -dimethyl-4.4 '-diphenylmethane diisocyanate and l,S-tetrahydronaphthalene diisocyanate and mixtures of such diisocyanates and where the polymeric polyols are selected from at least one of the group consisting of polyester polyols, polyether polyols and hydroxyl-terminated unsaturated polymeric polyols.
5. The cured polyurethane according to claim 4 where the polyester polyols have a molecular weight in the range of about 1000 to about 3000 and are selected 10 from condensation products of low molecular weight glycols and organic dicarboxylic acids and from caprolactone polyesters derived from e-caprolactone and a glycol containing 4 to 6 carbon atoms. where the polyether polyols have a molecular weight in the range of about 1000 to about 3000 and are selected from polyols prepared by polymerizing or copolymerizing alkylene oxides, by polymerizing or copolymerizing low molecular weight glycols or by the reaction of alkylene oxides with low molecular weight glycols and where said hydroxyl-terminated unsaturated polymeric polyols have a molecular weight in the range of about 2000 to about 4000 with an hydroxyl functionality of about 2 to 3 of the type prepared by polymerizing unsaturated monomers comprising from about to about percent conjugated dienes selected from 1,3-butadiene and isoprene and up to about 30 percent sytrene.
|Cited Patent
|Filing date
|Publication date
|May 7, 1957
|Apr 8, 1958
|Du Pont
|Poly (polyalkylene ether urethane) polymers containing terminal epoxide groups
|Mar 14, 1960
|Nov 24, 1964
|United Shoe Machinery Corp
|Sealant from an isocyanate-terminated polyol, a diglycidyl polyether, and a polyol
|Jan 30, 1959
|Jun 8, 1965
|Du Pont
|Diamine cured fluid polyether urethane compositions
|Dec 13, 1961
|Jul 13, 1965
|Du Pont
|Polyurethanes cured with mixtures of aromatic primary and secondary diamines
|Aug 12, 1963
|Dec 13, 1966
|Arthur V Tobolsky
|Block copolymers formed by the reaction of an isocyanate-terminated polymer with a dual functional free radical initiator and an ethylenically unsaturated monomer
|Apr 4, 1966
|May 27, 1969
|Goodyear Tire & Rubber
|Soluble cured polyester polyurethanes
|May 20, 1969
|May 2, 1972
|Dunlop Co Ltd
|Polyurethane prepolymer composition containing the reaction produc of a carboxylic acid and a monomeric isocyanate
|Citing Patent
|Filing date
|Publication date
|Feb 5, 1976
|Apr 12, 1977
|The Goodyear Tire & Rubber Company
|Polytetramethylene ether urethane cured with 2,2'-diaminodiphenyl disulphide
|Mar 9, 1976
|May 3, 1977
|The Goodyear Tire & Rubber Company
|Sulfuric acid-resistant polyurethane composition and method of preparation
|Nov 24, 1975
|Jul 26, 1977
|The Goodyear Tire & Rubber Company
|Nonstaining polyurethane from cycloaliphatic or aliphatic diisocyanates and polyhexenediol-phthalates
|Dec 19, 1977
|Jun 19, 1979
|The Goodyear Tire & Rubber Company
|Tire having polyurethane laminate thereon
|Nov 14, 1977
|Aug 14, 1979
|The Goodyear Tire & Rubber Company
|Polyurethane tire and wheel assembly
|Jul 29, 1985
|May 5, 1987
|Bayer Aktiengesellschaft
|Process for the preparation of stabilized polyamines, stabilized polyamines with retarded reactivity and their use for polyurethane production
|Feb 5, 1975
|Jun 28, 1988
|The Goodyear Tire & Rubber Company
|Polyurethane composition
|Oct 30, 2001
|Oct 31, 2006
|Basf Coatings Ag
|Polyurethanes containing sulphide groups, polymeric mixtures based thereon, production and use thereof
|Oct 30, 2001
|May 20, 2004
|Wilma Locken
|Polyurethanes containing sulphide groups, polymeric mixtures based thereon, production and use thereof
|U.S. Classification
|528/288, 528/290, 528/354, 524/39, 528/64, 524/589, 524/361, 528/45
|International Classification
|Cooperative Classification
|European Classification


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Los Angeles, CA
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Laura Hayden
Laura Hayden leaves no sordid stone unturned in her stand-up comedy. The mastermind behind the multi-media show "I Didn't Mean To Be A Virgin In The 80's,"All topics are fair game for Laura, from her own stories of coming of age to the bizarre and all too funny real life experiences she witnesses as a physical therapist.
Laura has appeared in clubs, theatres, casinos and shacks all over the United States and several countries. As a PhD in Physical Therapy, Laura studied the importance of laughter in coping with the stress of caregiving. She applies her experience as a medical professional and her talent as a comedian to teach other people to use laughter to stay grounded and energized while they help their patients recover. As a stand-up comedian she has performed at festivals in New York, Boston, Las Vegas, Los Angeles and Seattle. Other credits include The Night Shift with Kevin Ferguson, Funny.com, Dead American, LATALK radio and XM radio. Learn more about Laura by visiting www.laurahayden.com.
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text:
Beautiful! Stunning! Enough superlatives, this place was a little jewel, a peaceful haven in a perfect place, to give us a restful end to an exciting trip.
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text:
What is Your Fragrance Aura?
Their result for What is Your Fragrance Aura? ...
The Wood Nymph
70% Woodsy
There's nothing that worries your Woodsy essence. A deep thinker with a grasp on reality, you choose your friends by their character and their ethics. You enjoy serene times alone and the sound of a creekbed in the forest. Your fragrance aura is in the heart of the forest sounds, along with the essence of moist wood, a crackling fire, fresh fern, and clean air. You also enjoy the soft, bark sents of sandalwood, patchouli, cinnamon and cedarwood.
Their Analysis (Vertical line = Average)
They scored 29% on Floral, higher than 5% of your peers.
They scored 37% on Oriental, higher than 27% of your peers.
They scored 47% on Fresh, higher than 37% of your peers.
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All possible test results
The Connoisseur
Leather You enjoy the finer things in life. Your fragrance aura is Leather. Your pursuits are grande, while you enjoy luxury and quality. You are as co... Read more
Purity of Heart
Floral You avoid confrontation at all costs, and seek the counsel of good, trustworthy friends. You seek beauty in the smallest of details. The fragran... Read more
Free Spirit
Fresh You love the smell of the ocean, soap and clothes fresh from the laundry. Your instinct is to create new alliances with trusted individuals. Your fragrance aura is Fresh, and yo... Read more
The Wood Nymph
Woodsy There's nothing that worries your Woodsy essence. A deep thinker with a grasp on reality, you choose your friends by their character and their e... Read more
New Experiences in Ancient Practices
Oriental This term has been used somewhat inaccurately to describe the deep, camphor and sweet incense smells of resins used in the Middle East, Africa... Read more
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Bloque III - JL (2)
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More than tweaking needed
Longboat Key Vice Mayor Terry Gans has it right.
Few people would agree with that idea, or with two bills that would allow guns to be carried in the open. But there's a legitimate case for how open carry can improve safety.
Underground utilities; Colony; Trump
How to pay for underground utility lines in Longboat's neighborhoods is a perplexing dilemma. But commissioners were right deciding to let the voters decide.
In this crucial moment of a free-fall, American voters need great wisdom to discern who has the Right Stuff to revive our founding heritage and guide us to be great again.
Our heritage, family values and principles depend on the continuous retelling of such important events.
Don't worry: State law won't let dogs sit at your table
Sir Isaac Newton and the late economist Friedrich Hayek have rational explanations for why the Donald is running so far ahead of the Republican pack. It's physics and math.


text:
This profile was last updated on . and contains contributions from the Zoominfo Community.
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Dorchester NSC
Email: a***@***.org
110 Claybourne Street
Dorchester, Massachusetts 02124
United States
The Dorchester NSC provides Head Start, Fuel Assistance, Weatherization services, GED classes, After-School Enrichment Program, Earned Income Tax Credit (EITC) program, SummerWorks jobs program for low-income youths, and information and referral services.... more
Hesper Smyth
Corbin Design
George Smyth
WPN Chameleon Limited
Peggy Smyth
Watson's Mill
Paul Smyth
Tenants' Union of NSW
Maggie Smyth
Village Realty Inc.


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- A recent suicide has highlighted tensions between locals in south-west Queensland and the companies looking to tap the region's Coal Seam Gas reserves. George Bender took his life after battling for a decade to stop CSG companies coming onto his land. His family has vowed to continue the fight. ...Thursday 29 October 2015
- A Federal Government frontbencher is calling on state governments to change long-standing laws so as to allow farmers to ban coal seam gas companies from entering their land. Nationals Senator Fiona Nash made the call on Q and A last night during an emotional debate on the CSG issue, sparked by a ...Tuesday 27 October 2015
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Minister for Resources and Northern Australia Senator Matt Canavan 'certainly making all the right moves at this point' says AgforceQueensland LNP Senator Matt Canavan is one of the new faces in Prime Minister Malcolm Turnbull's new Cabinet... as the Minister for Resources and Northern Australia....Tuesday 19 July 2016
- On our final Election Express Saturday Extra welcomes back three of our editors located in must watch electorates. Jackie Pearson on the NSW Central Coast covering the Dobell and Robinson electorates; Les Pearson in the mid north region of South Australia covering Grey and Wakefield and Libby ...Saturday 2 July 2016
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Happily Ever After- A New Short Film About the Highs and Lows of Love
Happily Ever After is a new short film about a couple who falls in love, and tries to stay in love, through the obstacles of life.
Not only is Happy Ever After both entertaining and inspirational, but also a true animated work of art. This short film exuberates coloring that catch you eye and don't allow you to look away, even if you wanted to. With high quality graphics, a relatable story line and fast-paced sequences, this short film has the ability to connect with anyone who has ever been in love.
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The Heysham Douglas ferry route connects England with Isle of Man. Currently there is just the 1 ferry company operating this ferry service, Steam Packet. The crossing operates up to 13 times each week with sailing durations from around 3 hours 30 minutes.
Heysham Douglas sailing durations and frequency may vary from season to season so we'd advise doing a live check to get the most up to date information.
Prices shown represent the average one way price paid by our customers. The most common booking on the Heysham Douglas route is a car and 2 passengers.
"heysham to douglas"
easy to find terminal and check in shame our boat delayed 90 minites at haysham but boat and staff on board helpful and caring
'Keith' travelled Heysham Douglas with Steam PacketRead More Read Less
"steam packet to Douglas"
Good trip Very helpful staff
'Stanley Barfoot' travelled Heysham Douglas with Steam PacketRead More Read Less
"Great Service"
Great service. The WiFi was not working. The normal lounge was actually better than the premium lounge. It wasn't worth the extra money.
'Anonymous' travelled Heysham Douglas with Steam PacketRead More Read Less
"Pleasant voyage"
Thankfully, the seas were calm and I found the journey in each direction relatively hassle-free, check in was uncomplicated and there was sufficient seating on the main deck (in the cafe) for all. It would have been helpful if all the TVs showed the text because they were inaudible over the sounds of the engines, however, sound was unnecessary when what was showing was a football match. Don't forget your reading matter to keep you amused. If the trip were cheaper I might make it again!
'Dr W Kilworth-Mason' travelled Heysham Douglas with Steam PacketRead More Read Less
The village of Heysham can be found on the north west coast of England in the county of Lancashire. The town overlooks Morecambe Bay and is a pretty little coastal village a short distance from both Lancaster and Morecambe. The village has many beautiful 17th century cottages and is well known for its colourful floral displays, which have won Britain in Bloom's Gold Small Village prize on two occasions. Situated quite close to the village are two nuclear power stations but also areas of woodland, open grassland, sandy beaches and rock pools.
Ferry services from the village's harbour depart to the Isle of Man, operated by the Isle of Man Steam Packet Company, and to Ireland. The port's facilities include a waiting lounge with TV, some vending machines, a snack bar and restaurant, disabled toilets and a children's play area.
Douglas is the Isle of Man's largest town and lies on the east coast of the island, on the edge of a two mile sweeping bay and beach. The offers visitors many things to do and see and its promenade is always a hive of activity. Popular things to do in the town include the guided Story of Mann trail which takes visitors around some of the most famous sites, beginning at the Manx Museum. For petrol heads, the TT Grandstand is always popular and is where spectators can get the best view of the start and finish line of the world famous Isle of Mann TT Race. A trip to the Great Union Camera Obscura on Douglas Head is also worth a visit.
Ferry services from Douglas, operated by The Steam Packet Company, depart to Heysham, Liverpool, Dublin and Belfast. Both conventional and fast ferries are available, although the fast ferries only operate between March and November. Facilities on board the boats include shops, cafes and bars.


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Lyrics Depot is your source of lyrics to Sailor Man by Turbonegro. Please check back for more Turbonegro lyrics.
Sailor Man Lyrics
Artist: Turbonegro
Album: Ass Cobra
Oh so handsome -
Oh so strong -
Tell me stories of distant shores -
All night long -
I shiver all over -
When I see your lovly tan -
And I can tell by your clear blue eyes -
Your a sailor man -
Oh sailor man -
From polar land -
Oh sailor man -
Come take my hand -
Oh sailor man - Take me along -
Show me the porta-prince and Hong Kong -
Oh sailor man -
I sure hope you don't drown-
I'd rather have you showing me Cape Town -
You know your to New York, New York -
Where we can go to bars -
A strong blonde handsome sailor -
Norwegians call you Lars -
Oh sailor man -
From polar land -
Oh sailor man -
Come take my hand -
Oh sailor man -
I'd gladly die -
To see the ports of Rostock and Shanghai -
Sailor Man -
Oh, sailor man -
Please take my hand -
Oh tender sailor man
Turbonegro Lyrics
Turbonegro Ass Cobra Lyrics
More Turbonegro Music Lyrics:
Turbonegro - Armed And Fairly Well-Equipped Lyrics
Turbonegro - Black Rabbit Lyrics
Turbonegro - Do You Do You Dig Destruction Lyrics
Turbonegro - Letter From Your Mamma Lyrics
Turbonegro - Letter From Your Momma Lyrics
Turbonegro - Locked Down Lyrics
Turbonegro - Young Boys Feet Lyrics


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Children / Mother- Inspirational Quotes, Motivational Thoughts and Pictures
<<< Home >>>
...Thoughts to Contemplate - Reflect - Discover - Explore - Inspire & Enrich Yourself...
Happy Mother's Day.
Children are the flower of life .......Happy Children's Day
!!!! Happy Mother's Day !!!!
Beautiful children quotes
Mother's love ;quotes ,story,thought
Best Mother Quote
Quote for Successful mothers
A very happy Mother's day- Dear mom
Happy Mother's Day ! in advance
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digital video
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Canon's new flagship Full HD camcorder
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Freetalk Everyman Webcam
Freetalk Everyman review: We really like the sleek lines of this webcam
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Sony Vegas Pro 10 review: This advanced video editor can now do 3D
Flip MinoHD 8GB pocket camcorder
Flip MinoHD 8GB review: an HD pocket camcorder for bloggers and casual shooters
Sony Bloggie Touch MHS-TS20 (8GB)
Sony Bloggie Touch review: a Full HD pocket cam aimed at bloggers
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muvee Pixie
Lightweight video authoring utility Pixie automatically creates finished movies from styles
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Sanyo's stylish and ultra-portable HD pocket camcorder
Adobe Premiere Elements 9
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We review Panasonic's first consumer-level 3D camcorder
Roxio Creator 2011
Roxio's latest media suite lets you transform your own 2D images and video into 3D.
Panasonic HM-TA1 Full HD pocket camcorder
Panasonic's pocket digital camcorder offers Full HD recording, attractive looks and good image quality
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text:
Drake "Started From the Bottom" Video: Released!
While Rihanna and Chris Brown generated the most buzz at the Grammy Awards, Sunday night was also big for a man often linked to both: Drake.
The Canadian rapper was among the 2013 Grammy Award winners and released his latest video along with his new album's title, Nothing Was the Same.


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What's New
Earn & Get a Wal-Mart Gift Card in August Earn & Get an August Gift Cashin' In Mystery Multiplier Young at Heart Instant Win Free Mystery Gift Earn & Get a Wal-Mart Gift Card in July! Earn & Get a July Gift! Free Gift Thursdays 15X Point Multiplier Young at Heart Free Lottery Scratch-Off Game Win A Gift Bag and More!


text:
Seek Com Au Jobs in State of Victoria
First Personnel - Melbourne, Victoria
We are looking for people who are reliable, punctual, have a can do attitude, can get along well with others and work well in a team environment. - Reliable, punctual, have a can do attitude Vehicle Final...
from: meega.net (+1 source) - Today
One Legal - Melbourne, Victoria
This position has the very rare benefit of working a 9.5 day fortnight with every second Friday afternoon off! For this great role you will be an experienced Legal Secretary with some previous experience...
from: meega.net - 2 days ago
Ericsson - Docklands
At Ericsson, our vision is that of a Networked Society, where every person and every industry is empowered to reach their full potential. Our strategy to achieve it is founded on three pillars: Mobility...
from: Ericsson - 13 days ago
For more Legal Secretary positions, see our other adverts on Seek, or check out our website at: www.onelegal.com.au Level 4, 115 Elizabeth Street Janie Thomas MELBOURNE VIC 3000
from: jobx.com.au - 4 days ago
Kaleidoscope Legal - Melbourne
Legal secretaries crave the opportunity to work with this firm so do not miss out on your opportunity to be considered. As a staff member, you will reap the rewards that only a top tier law firm can offer...
from: jobadder.com - Yesterday
One Legal - Melbourne, Victoria
Assisting a great senior level Partner who is described as easy-going, friendly yet highly professional and one of the best in this area of law, you'll be working on some of the largest Mergers and Takeovers...
from: meega.net - 26 days ago
Melbourne CBD, VIC
The role will see you managing Building Services projects across a variety of sectors. As a recognised project leader you will play a key part in mentoring up-and-coming engineers and provide superior...
from: hays.com.au - Yesterday
Melbourne CBD, VIC
Using your breadth of HR and strategic HR project management expertise, the role will involve reporting into the HR Manager and consulting with senior stakeholders to successfully manage all stages of...
from: hays.com.au (+1 source) - 15 days ago
Profusion - Melbourne
For an immediate interview, apply now directly to Dave Marshall (0292846382) at Profusion via the link below.. Min 8+ years work experience in Technology (Feel free to connect with me on Linkedin to hear...
from: jobadder.com - Yesterday
Melbourne CBD, VIC
Your successful application will outline CA/CPA qualifications and experience, ideally obtained from within another volume residential building business or construction organisation. This experience will... $80000
from: hays.com.au - Yesterday
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Spanish speaking attorneys are wanted for immediate hire! If you have experience or merely just an interest in employment law, you are encouraged to apply....
Jul 20 - Sacramento, CA
Call Bret at 916-870-0497 for immediate consideration. Capitol Commercial Plumbing, Inc....
Jul 19 - Sacramento, CA
An immediate one-time sign-on bonus of up to $10,000. Training & Advancement....
Jul 9 - United States
Show flexibility in terms of your schedule to ensure the smooth and efficient operation of the restaurant as directed by the restaurant manager or immediate...
Jun 22 - Woodland, CA
Acceptance Insurance has an immediate opening for a Retail Sales Agent at our Sacramento, Fulton Ave. Are you looking for a retail sales position that offers...
May 24 - Sacramento, CA
Merchandisers needed immediately in Scaramento, CA
WIS is hiring and we want you to join our dynamic TeamPart-Time Field Merchandisers-- Hiring today for ongoing Inventory work, projects, resets and basic Merchandising. Start Immediately!Please email with a summary of your experience/resume. You will be contacted immediately for consideration.Compensation and travel will be decided during the phone interview.Employment type: part-time WIS ...
Jul 25 -
Sacramento - Retail & wholesale
Immediate Hire Laborers– Daily Job as Quick as Today!
Local Sacramento warehouse looking for Laborer workers for all shifts starting as soon as tonight. We are looking to hire someone immediately.Requirements:Must have a VALID Drivers LicenseMust be able to START IMMEDIATELY & Available for On Call PositionsMust be able to pass Background and Drug Screening if requestedALL Warehouse Experience is a PLUS!Could turn into Potential Full Time ...
Jul 21 -
Sacramento - General labor
Entry Level Sales Consultant - Full Time - Immediate Hire
Capital Energy Partners is looking for a candidate with excellent communication skills, a desire to learn and an extraordinary drive to be successful!We are thrilled about our recent expansion to Sacramento this past year! We are working with Solplicity, one of the world's largest brands in the Clean Energy and Solar Power and we are looking to hire FIVE Sales Consultants immediately! All of ...
Jul 19 -
Elk Grove - Sales & biz dev
Sales & Marketing Consultant - Full Time / Immediate Hire
Sales and Marketing Consultant - Full Time - Entry Level - NewCapital Energy Partners is excited about our recent expansion into Califonia this past year! Our niche has been our ability to act as the liaison between our major clients and their customers. Through our unique, relationship oriented approach we have been able to provide our clients tremendous results in the areas of customer ...
Jul 19 -
Davis - Sales & biz dev
We are looking to fill 4 positions ASAP -No Experience Necessary, We Will Train-Opportunity for Growth-Full Time Positions-Must Have a Strong Work Ethic-Desire to Succeed-Must be able to interact with Customers-Restaurant/Retail/Customer Service Experience a Plus-Sports Fan-Leadership Skills.-$450-1000 weekly*
Jul 19 -
Sacramento - Sales & biz dev
Jul 14 -
Sacramento - General labor
Home Health Licensed Vocational Nurses (LVN) IMMEDIATE OPENINGS
Immediate placement!! We need Licensed Vocational Nurses (LVN) to work to care for a patient in the comfort of their own home. Reliable professionals needed!!!! Job duties include ensuring client safety and providing care. One on one care utilizing your health care skills as well as having the luxury of being in a home environment. Positions available in Vacaville, Fairfield, Vallejo and ...
Jul 14 -
Vacaville - Medical & healthcare
*IMMEDIATE HIRE* - Entry Level Customer Service & Marketing
*IMMEDIATE HIRE* - Entry Level Customer Service & MarketingARE YOU LOOKING FOR AN EXCITING CAREER WITH UNLIMITED GROWTH POTENTIAL?PROFIT MARKETING is one of the LEADING marketing firms providing exceptional service to large corporations in the SACRAMENTO area. We recently opened up a NEW OFFICE and are looking to fill positions in multiple departments.These positions are ENTRY LEVEL to ...
Jul 11 -
Sacramento - Marketing & PR
Empire Ranch Alzheimer's Special Care Center has an immediate opening for a *Cook*. Empire Ranch is a premier memory care facility dedicated to facility...
Mar 31 - Folsom, CA
Team Leader - Immediate Hire
Do you want change in your career path?Are you an ambitious customer service professional ready to lead from the front?Our client supports their company leaders and wants to provide them with an opportunity for growth in a profession! The Job Window has an exciting opening for an entry level Team Leader on behalf of our client, a creative promotional marketing firm representing some of the ...
Jul 6 -
Sacramento - Retail & wholesale
PART TIME PHYSICIAN 25 year old National Healthcare Management Company seeking several physicians to handle disability exams in California - Sacramento and
Jul 21 - Sacramento, CA
Jul 5 -
Davis - Sales & biz dev
Immediate Clientele- Career Advancement. Interviewing hair stylists and assistant managers for Vacaville salons....
Jul 25 - Vacaville, CA
Jul 5 -
Elk Grove - Sales & biz dev
Immediate Hire / No Experience Necessary / Entry Level Positions
IMMEDIATE HIRE - NO EXPERIENCE NECESSARY - FULL TIME POSITIONSENTRY LEVEL POSITIONS IN:SALES/ MARKETING / CUSTOMER SERVICE - RAPID ADVANCEMENT IN OUR NEW OFFICE! We have expanded new offices!!!! Expanded new divisions!!!! Planning 4-5 more expansions this year! We provide aggressive marketing and advertising campaigns for national accounts in the area!We provide customers with the everyday ...
Jul 4 -
Sacramento - Marketing & PR
IMMEDIATE HIRE: No Experience Necessary! PAID TRAINING!
RETAIL MARKETING / CUSTOMER SERVICE-RAPID ADVANCEMENTWe have expanded new offices!!!! Expanded new divisions!!!! Planning 4-5 more expansions this year.We provide direct marketing campaigns for national accounts in Sacramento.We provide customers with the everyday value and uncompromising customer service that has made us so successful. We are now accepting applications for Retail and Event ...
Jun 27 -
Sacramento - Customer service
Entry Level – Immediate Hire - Marketing
Entry Level – 8 POSITIONS – FILLING IMMEDIATELYDegree...No Experience? Experience... No Degree? We are expanding and are looking for 8 individuals for entry level in all aspects of our business such as: ENTRY LEVEL MANAGEMENTMARKETING REPSCAMPAIGN DEVELOPMENT TRAINING MANAGERSSALES LEADERSMANAGEMENT / ASSISTANT MANAGEMENT We are a promotional advertising company with exceptional customer ...
Jun 27 -
Folsom - Marketing & PR
Entry Level – 8 Positions – Immediate Hire
30 Call Center Representatives NEEDED IMMEDIATELY!
30 Call Center Representatives Needed- Bilingual Spanish Needed!!Pay $10.50 an hourHours:If you're interested in this position, please apply and send your resume as soon as possible so that we can get the process started for you. Function as the front-line contact for all members by responding to a high-volume of incoming calls from members and prospective members.Respond accurately to ...
Jun 23 -
Folsom - Customer service
Multiple Entry Level Positions Available: Immediate Hire
Entry level Openings: Immediate hire Sports and Construction Backgrounds Needed Full/Paid Training for New Department Openings Looking to hard workers with upbeat attitudes! Marketing and Sales for A wide variety of Clients in the Region. We are looking for candidates that can teach and train. You must also be able to work hands-on with customers and clients. Must be able to teach, train, and ...
Jun 6 -
Sacramento - Everything else
After Hours Dispatchers- Work from home. Immediate openings!!
We are looking for two after hours dispatchers to work from home booking calls for a 35 year old heating and air conditioning company. Duties include but are not limited to: · Answering calls filtered through to the dispatch phone· Book calls as needed on dispatch schedule· Page calls to on-call technicians as needed· Be available to do on-site training (initially) and ...
Jun 3 -
Rancho Cordova - Construction & trades
Recruiting Coordinator / Office Coordinator - Immediate Opening
A well established and forward thinking company is looking for a Recruiting Coordinator. This position will be directly supporting the Corporate Recruiter and recruiting department.Qualifications:* Must have HR/Recruiting experience - professionally or in higher education* Must have superior typing speed WITH accuracy (60+ WPM)* Intermediate to advanced competency in Excel and Word* Creative ...
Jun 2 -
Sacramento - Administrative & office
Jun 1 -
Sacramento - Retail & wholesale
CR England has an IMMEDIATE NEED for Truck Drivers! We offer weekly pay, flexible home time, paid vacation, health benefits, and much more....
Jun 19 - California
Apr 2 - California
Bring to the immediate attention of the dentist any suspected lesion in the mouth or on the teeth. Coast Dental is a network of dental practices throughout...
Jul 11 - Elk Grove, CA
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March 13, 2013
The U.S. national DEF pump price remained level at $2.79 per gallon for the third consecutive month in February 2013.
Prior to this period, the national average has only held steady month-to-month once, which occured in April 2012. The national Canadian DEF pump price also held level at CAD $0.80 per liter in February. The average price has not changed since the first pump came online in October 2011.
We offer e-newsletters that deliver targeted news and information for the entire fleet industry.
The expert, Brian Fletcher from Eaton, will answer your questions
Kenworth Launches Essentials App for Mobile Devices
EZ Drain Valve Made For Vaporizer Drain Systems
VeeBoards Corner Protectors are Stackable
TomTom Partnership Adds Real-Time Accounting


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Flash Everyone at Mansion, Michael Jackson-Style
You know those Michael Jackson tributes that have been popping up on the web recently, where there's a random group of people that randomly bust out with the "Thriller" dance at a random place in a random time?
Well, those are called flash mobs, and this Wednesday, Mansion (1235 Washington Avenue, Miami Beach) will be hosting one.
Kind of.
The Opium Group is putting the group together to promote the official Miami premiere of the new Michael Jackson movie, This Is It. OG also promises to post the "flash mob" video on YouTube.
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It's a decent PR move, considering that the MJ hysteria still has momentum and everyone just loves viral videos, but the fact that we already know that Mansion is planning this event takes the whole "flashiness" out of the equation of creating, well, a mob.
To participate in the flash mob/PR event/played-out viral video stunt/whatever, head over to Mansion today at 7 p.m. for its open auditions. The only restrictions are that participants must be 21 and older and you have to be available for both today's rehearsal and the subsequent event on Wednesday, but besides that, anything goes.
Members of the mob will receive complimentary admission and free drinks from 11 p.m. to 1 a.m on Wednesday night. Everyone else will just have to look past the abundance of red leather jackets and be totally surprised by the impromptu performance.
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Two men have been found guilty of tying up and robbing an Upper Hutt couple of thousands of dollars in cash after breaking into their home armed with sawn-off shotguns.
Jeremy Brian Gorinski, 34 and Dinesh Kumar Manoharan, 36, are both charged with the aggravated robbery of Malcolm and Yvonne Wiffen on June 19 last year and had pleaded not guilty.
The Crown said they broke into the Wiffens' Silverstream home, held guns to their heads, demanded money and gold, got into their safe and left them tied up on their living room floor with pillowcases on their heads.
They left with between $50,000 and $70,000.
Both their lawyers had said the men were not at the scene of the crime and were never identified by the Wiffens.
The Wellington District Court jury had been out seven hours.
- The Dominion Post
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Australian parent Woolworths closes six Countdowns
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Horror house raises concerns about CYF handling of young family
Australia parent Woolworths closes six Countdowns
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Richard Hoagland spent two decades raising a family using a dead man's name
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Ben Gardner
- 6' 4", 270 lbs
- San Diego Chargers
- BornApr 29, 1991 (Age: 25)
- Drafted 2014: 7th Rnd, 231st by DAL
- Experience2nd season
- CollegeStanford
Go to
Chargers' 53-man roster projection includes Zach Mettenberger as third QB
Zach Mettenberger's offseason work has been uneven, but the talent is there to keep him on the Chargers' 53-man roster.about 37 days ago | Eric Williams | ESPN.com
Philip Rivers and Jason Verrett match wits at Chargers' OTA practice
The matchup between quarterback Philip Rivers and cornerback Jason Verrett highlighted the San Diego Chargers' OTA practice on Tuesday.about 57 days ago | Eric Williams | ESPN.com
First look at 2016 San Diego Chargers' 90-man roster
The Chargers didn't make any trades during this year's draft, adding eight picks and 20 undrafted free agents to increase the roster to 90.about 86 days ago | Eric Williams | ESPN.com
Chargers position outlook 2016: Defensive line
Adding depth on the defensive line will be a priority for the Chargers whether it's via free agency or the draft.about 157 days ago | Eric Williams | ESPN.com
Dallas Cowboys cut 20 players, including Dustin Vaughan
Dustin Vaughan was one of 20 players cut from the Dallas Cowboys by Saturday's deadline.about 326 days ago | Todd Archer |
Cowboys' decisions Saturday go beyond finalizing 53-man roster
The Cowboys have been aggressive in making adjustments to their roster in the days after cutting down to 53 players.about 326 days ago | Todd Archer |
Cowboys face difficult decisions on defensive line
As they prepare for the final cuts this Saturday, the defensive line competition is the most difficult to figure.about 327 days ago | Todd Archer |
Dustin Vaughan gets the win; does he get roster spot?
Dustin Vaughan had every opportunity to earn the Cowboys' No. 3 quarterback spot Thursday against the Texans, but did he do enough?about 328 days ago | Todd Archer |
Cowboys have jobs open; who will secure them?
Several members of the Cowboys will try to secure spots on the final 53-man roster with their performances Thursday against the Texans.about 328 days ago | Todd Archer |
Cowboys' roster projection: Getting below 53 players
A look at positions that could see upgrades and additions or could give the Cowboys some pieces to deal from the projected final roster.about 331 days ago | Todd Archer |
- more


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Forum indexSony Alpha / Nex E-mount (APS-C) TalkChange forum
Any Egret fans?
Started Oct 22, 2012 | Discussions thread
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martindesu • Senior Member • Posts: 1,245
Any Egret fans?
Oct 22, 2012
Saw this beauty last weekend, and instantly wished I had my 18-200LE on the front of my NEX-7.
I have to shoot manual instead, with a Canon FDn 50mm f/1.4.
I know that forum member Danny is an avid avian enthusiast - have you seen Kosagi before?
Comments always welcomed.
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CommonWealth REIT (CWH) Tops Q3 FFO by 2c
- Top 10 News for 7/25 - 7/29: Earnings and Mergers and ... Chioptle Making Burgers?
- Tech shares and muted GDP growth push S&P 500 to record
- No clean bill of health for EU banks in stress test
- Private equity firms focused on Hewlett Packard asset sales: sources
- Tesla (TSLA) Gains as Panasonic Seeks to Raise $3.9B for Gigafactory
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Today's EPS Names:
TBNK, PBHC, SAL, More
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CommonWealth REIT (NYSE: CWH) reported Q3 FFO of $0.86, $0.02 better than the analyst estimate of $0.84. Revenue for the quarter came in at $238.79 million versus the consensus estimate of $227.26 million.
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Ball Breaker
Bhakti Baxter's highly anticipated exhibit, "Rompelotas," is the locally based artist's first Miami solo show in four years and includes sculpture, painting, collage, and installation-based work. The exhibit's name is a play on the Spanish term rompe pelotas, which translates to "ball breaker." Look for some ball-busting legerdemain from Baxter, whose exhibition aspires to "juggle the laws of gravity, density, and the malleability of mass while striking a balance between play and placement."
Tuesdays-Saturdays, 11 a.m. Starts: Oct. 8. Continues through Nov. 12, 2011
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Uncut raves about Lilium!
posted at 07/05/2010Lilium - Felt
Glitterhouse Records
"Brilliant third album by Mojave desert dweller.
When not playing bass with David Eugene Edwards' various bands (Wovenhand, 16 Horsepower), Pascal Humbert returns to his Mojave desert home and writes hallucinatory, sand-blasted music so downbeat it makes Calexico sound like a Vaudeville band. Its creator being neither a lyricist nor a singer, Felt relies upon Hugo Race and female singer Kal Cahoone to provide suitable brooding words and vocals to Humbert's dusky, slow-moving and oddly menacing soundscapes, populated by drifting trumpet snatches, weeping dobros and pedal steels, throbbing double bass and subtle electronic washes. The effect is as endlessly mesmerizing as the desert landscape that inspired it." (Uncut ****)
Latest News
Jul 27
| WOVENHAND - COME BRAVE Glitterhouse very proudly presents 'Come Brave', the 1st song taken from the new Wovenhand album 'Star Treatment' coming Sep 9th at Glitterhouse Records (EU) and Sargent House (US)... read more
Jul 16
| SLIM CESSNA'S AUTO CLUB - #7 VIDEO - DOWNLOAD Here's the new Slim Cessna's Auto Club video taken from the forthcoming record 'The Commandments according to SCAC'... read more
Jul 04
| BLAUDZUN - JUPITER Blaudzun surprised his fans and followers last Friday by dropping 'Jupiter', the title song for his new album... read more
Jun 15
| HUGO RACE FATALISTS - BALLAD OF EASY RIDER - VIDEO Here's Hugo Race Fatalists 'Ballad of Easy Rider' taken from the amazing new album '24 Hours To Nowhere', out now at Glitterhouse... read more
Jun 03
| BLAUDZUN - TOUR / ALBUM NEWS No music, no artwork and no title known yet, just a street date: October 7th 2016. That's when Blaudzun will put out new music... read more
Jun 03
| SPAIN - CAROLINA - OUT NOW AT GLITTERHOUSE RECORDS! Winter is now officially over and the new Spain album will make you feel like contemplating the world on a gentle summer's evening... read more
May 26
| HUGO RACE FATALISTS - 24 HOURS TO NOWHERE - OUT NOW Hugo Race, formerly of The Wreckery and the Bad Seeds and now an internationally based producer, writer and performer with bands like The True Spirit and Dirtmusic... read more
May 25
| HUGO RACE FATALISTS - LOST IN THE MATERIAL WORLD Enjoy 'Lost in The Material World' taken from Hugo Race Fatalists' astonishing new album '24 Hours to Nowhere' coming May 27th at Glitterhouse Records... read more
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Apr 29
| WOVENHAND ANNOUNCES 2016 TOUR & NEW ALBUM David Eugene Edwards leads his Denver, Colorado based band Wovenhand back to Europe this September to playing 29 cities in 12 countries and once again enchant audiences with their very own brand of Rock and Roll... read more


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Comments Thread For: Terence Crawford Will Return on Rios-Alvarado Card
Hot lightweight prospect Terence Crawford will return March 30 in a vacant NABO title match, according to Top Rank matchmaker Brad Goodman.
The bout will be on the off-TV undercard of Brandon Rios-Mike Alvarado 2 at the Mandalay Bay in Las Vegas, Nev. Two opponents being discussed at this stage are Dorin Spivey and Lonnie Smith.
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Sleeping Dogs
Random House Publishing Group, Jan 26, 2011 - Fiction - 320 pages
He came to England to rest. He calls himself Michael Shaeffer, says he's a retired American businessman. He goes to the races, dates a kinky aristocrat, and sleeps with dozens of weapons. Ten years ago it was different. Then, he was the Butcher's Boy, the highly skilled mob hit man who pulled a slaughter job on some double-crossing clients and started a mob war. Ever since, there's been a price on his head.
Now, after a decade, they've found him. The Butcher's Boy escapes back to the States with more reasons to kill. Until the odds turn terrifyingly against him . . . until the Mafia, the cops, the FBI, and the damn Justice Department want his hide . . . until he's locked into a cross-country odyssey of fear and death that could tear his world to pieces . . .
"Exciting . . . Suspenseful . . . A thriller's job is to make you turn the pages until the story's done and your eyes hurt and the clock says 3 a.m. . . . I wouldn't try to grab this one away from somebody only half-way through. No telling what might happen."
-- Michael Dirda, The Washington Post Book World
From the Paperback edition.
What people are saying - Write a review
Sleeping dogsUser Review - Not Available - Book Verdict
Perry is the author of four previous novels: Island ( LJ 1/88), Big Fish ( LJ 3/15/85), The Butcher's Boy ( LJ 8/82), and Metzger's Dog ( LJ 9/15/83). His new work brings Charles Ackerman--a.k.a., the ... Read full review
Review: Sleeping Dogs (The Butcher's Boy #2)User Review - -ed- Erwin - Goodreads
In this sequel to The Butcher's Boy, Perry shines. This is a fabulous character, the best hitman-hero. Read full review


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Coral Gables Woman's Aston Martin Stolen After She's Tied Up During Home Invasion
A Coral Gables woman was the victim of a shocking home invasion last night. A man broke into her home, tied her up, and then used her own Aston Martin as the get-away car.
According to NBC Miami, the incident happened at about 11:30 p.m. last night in the 100 block of Arvida Parkway.
A masked masked and armed man broke into the home while the woman was alone. He forced the woman down onto the floor and then tied her up.
He then found her keys at took off in her 2011 Aston Martin Vantage. That's a car that retails for over $100,000. The car in question was black with the Florida license plate X454EK. The car was the only item stolen.
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The woman managed to untie herself after the ordeal and called police. She was not harmed.
Anyone who has information about the case is asked to call Miami-Dade Crime Stoppers at 305-471-TIPS.
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You Pay: $84.60
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The PAG 9450 is a 650mm heavy-duty, coiled 12-30 VDC Power cable. This cable extends the length or serves as the main power cable for sources using a 4-Pin XLR connector; it features a male 4-Pin XLR connector on one end and a female 4-Pin connector on the other end.
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Originally posted on Oregon Sports News | Last updated 8/16/13
From HawkBlogger.com, a partner of Oregon Sports News The end of training camp public practices is hardly a meaningful NFL milestone. There's almost two weeks until rosters have to be trimmed to 75 players (August 27th). Still, there were players that stood out over the last two weeks that deserve some recognition. STANDOUT PLAYER - Offense >>> WR Jermaine Kearse HONORABLE MENTIONS: WR Doug Baldwin, RB Christine Michael, WR Stephen Williams No player made a bigger leap from last year to this year than Kearse. He is playing with the confidence of an early-round pick, and his results have been pretty darn close to that level. He is the second-best separation receiver on the team behind Doug Baldwin, can play all three receiver positions, and has the most diverse route repertoire of the bunch. He caught go-routes down the sideline, crossers, curls, seams, posts, back shoulder, slants and more. He is not excellent at any one thing, but he is above average at al...
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The Wally's House and Hunt Wally attraction as seen from the top of the yard
After you tour through Wally's house, you'll flow with the crowd into his Film Silo in the former servants' quarters. There you can observe Wally while he is animating a scene from his over-familiar film, a humorous take on In the Heat of the Night. Be sure to compliment him on his handsome bedknob!
Please don't try Princess Mode
© copyright 2011–2016
A Pants Aflame production


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Chiefs depart Ballast Point
Head brewer Yuseff Cherney joins exodus of executives
Ian Anderson 6 p.m., July 29
My tattoo says, "God only gives His toughest tasks... ...to His strongest soldiers" I got this tattoo because they say "God will never give you more than you can handle". I have handled more than my fair share and I feel I have earned this one. I KNOW I'm one of His Strongest! :) <3 Darla Tiesing Cox
Posted November 22, 2013
P.S. I am 40 yrs old and I now live in Paradise Hills. I came to San Diego from the San Francisco area and I am originally from St. Louis, MO. I have lived in California for 4 yrs now. I am currently a professional Burlesque Performer with Hubba Hubba Revue and many others.


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Instead of stacking your heavy plates on top of each other, consider investing in a few dinner plate cradles to keep them upright and easy to pull out of the cupboard.
Under The Table and Dreaming: 50 Crafts and Projects Using Recycled, Repurposed, Upcycled Cans {Saturday Inspiration Ideas}
Lovely Plant Holders Repurposed in Bathroom - 30 Brilliant Bathroom Organization and Storage DIY Solutions
50 Insanely Clever Organizing Ideas
Super-organized utility closet (shoe organizer for cords/batteries/flashlights)
Fabulous Folger's Coffee Plastic Container Upcycle I have saved my coffee containers for the possibility of reusing for my classroom. So happy I found this.
battery storage...I finally bought one of these nifty organizers...love it!
For the pantry
Home Organizing Ideas - Can We Ever Get Enough of Them??? - Princess Pinky Girl We love these genius home organization tips! Buying and selling a home is easy with LystHouse.com - The best way to buy and sell homes. Start Searching for Homes for Sale Now! http://www.lysthouse.com
Storage ideas for every room in the home.
kids bathroom - I just had a "duh" moment! My kids freak when their toothbrushes touch! lol
trash bag storage under sink
ok seriously should have already thought of this!!! Use empty Lysol wipes containers to keep plastic grocery bags! Keep in your car for wet swimsuits, dirty diapers, trash, etc. Totally portable, and she even shows you how to put the bags in so they pop out one after another!
Paper towel holder for garbage bags
Pool Organization ABFOL 5 and giveaway
PVC Pipe Toothbrush Holders. Gets them off the counter and out of the germ zone.
Modify to use in classroom: Car Trash Can from Cascade container. Easy!
Everything is off the floor
Each member of the family has a mesh lingerie laundry bag, and a hook. They put their dirty socks and underwear in the bag each night. On laundry day, you wash the whole mesh zipped up bag, and give it back! No more sorting through and figuring out which socks are for which person.
Silverware tray to keep our toothbrushes off the counter and out of a cup. Dollar store tray.
Organization Tips for Your Kitchen.. this list is amazing
solution for under the bathroom sink!
solution for under the bathroom sink!


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Salgaocar, Dempo quit FC Goa after ISL sets aside ban on them22 July 2016 21:19 IST
Dattaraj Salgaocar and Shrinivas Dempo, the co-owners of FC Goa and prime promoters of football in Goa, have decided to quit FC Goa after the ban on them was set aside by the Indian Super ... READ
FC Goa retains Spanish midfielder Jofre19 July 2016 20:23 IST
FC Goa have retained Spanish midfielder Jofre Mateu Gonsales for the third season of the Hero Indian Super League. READ
Monsoon turns Goa beaches into football grounds28 June 2016 18:42 IST
As monsoon picks up and tourist activities cease on the shoreline, football enthusiasts have started to throng Goa beaches turning them into mini football ground. READ
Salgaocar, Sporting withdraw from I-League, allege pro-ISL stance by AIFF24 June 2016 20:25 IST
Two of Indian football's traditional outfits, Salgaocar FC and Sporting Clube de Goa, on 24 June decided to "withdraw" from the forthcoming season of I-League over the AIFF's decision to restructure the domestic league system. READ
FC Goa challenges ISL Regulatory Commission's order09 May 2016 23:10 IST
Indian Super League (ISL) side FC Goa, which was slapped a Rs 11 crore fine and their co-owners Shrinivas Dempo and Dattaraj Salgaocar banned for two and three seasons respectively, has challenged the order of ... READ
Why the FC Goa ruling could be a spanner in Indian football's growth06 May 2016 20:43 IST
Little more than five months on from a nerve-wracking final of the Hero Indian Super League's second season, that saw Chennaiyin FC crowned champions in the most dramatic of fashions, Indian football is still suffering ... READ
FC Goa Fined 11 Cr, Owners Banned For Indiscipline05 May 2016 22:03 IST
The Indian Super League Regulatory Commission on Thursday handed a hefty fine of Rs 11 crores to FC Goa and banned the owners of the football club -- Dattaraj Salgaocar (three years) and Srinivas Dempo ... READ
Elano didn't assault FC Goa co-owner, claims NDTV02 May 2016 16:37 IST
Elano Blumer's arrest following the 2015 Indian Super League (ISL) final in Goa on December 20 led to a massive controversy, with the Brazilian football star being accused of assaulting FC Goa co-owner and industrialist ... READ
What pains Chennaiyin FC if Dempo is VP of AIFF?05 April 2016 11:28 IST
Chennaiyin FC, reigning Indian Super League champions, on Monday raised the issue of conflict of interest against FC Goa co-owner Srinivas Dempo and asked the All India Football Federation (AIFF) to take action against him. ... READ
AIFF 'forget' to inform suspended Romeo and Mandar to present explanations05 March 2016 13:01 IST
Romeo Fernandes and Mandar Rao Dessai, two of India's brightest sparks while playing for the Indian Super League (ISL) franchise FC Goa over the last two seasons, have suddenly found themselves in limbo over participation ... READ


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Brian Whitehead Overview
Brian Whitehead is currently associated with two companies, according to public records. The companies were formed over a four year period with the most recent being incorporated eleven years ago in August of 2004. All companies are still active.
Background + Contact Information Available for Brian S. Whitehead
Contact + Background Information
- Phone, Address & Email
- Criminal & Civil Court Records
- Bankruptcies, Liens, & Judgments
- Properties, Businesses, Licenses, & More
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Companies for Brian Whitehead
Connections for Brian Whitehead
A connection is made when two people are officers, directors, or otherwise associated with the same company. Brian has three known connections and has the most companies in common with Carl Morgan.
Carl L. Morgan has the following companies in common with Brian Whitehead
Steve W. Whitehead has the following companies in common with Brian Whitehead
Monte Morrish has the following companies in common with Brian Whitehead
Known Addresses for Brian Whitehead
Other companies at ths same address
Similar Records
Brian J Whitehead
Annapolis, MD
Annapolis, MD
Managing Member at Hub Fort Myers, LLC
Managing Member at Hub - Florida, LLC
Managing Member at Hub Pompano Beach, LLC
Managing Member at Hub One Singer Island, LLC
Principal at Hub Singer Resort, LLC
Brian T Whitehead
Hyattsville, MD
Hyattsville, MD
Manager at Towne Lake, LLC
Managing Member at Floors of Florida, LLC.
President at Blinds Expo
Brian L Whitehead
Moore Haven, FL
Moore Haven, FL
Managing Member at Goody?S LLC
Texas Secretary of State
Data last refreshed on Monday, July 25, 2016
Data last refreshed on Monday, July 25, 2016