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Kristin Murphy, Deseret News
SALT LAKE CITY — Ready or not, the holiday season has officially arrived. And it's earlier than ever.
Call it "holiday creep," an increasingly early start to the holiday shopping season. Salt Lake City is hardly immune to the national trend.
As strands of Christmas music played in background Saturday morning, Kelli Shaw of Ogden strolled through City Creek Center for her family's annual girls' shopping day. Earlier in the week, Santa Claus arrived at downtown Salt Lake's new shopping center for the unveiling of holiday windows at Macy's and other festivities to kick off the winter holidays.
As a shopper who prefers to complete her holiday shopping early, Shaw said she welcomes the early start.
"I always try to get everything done by December 1 so I can enjoy the holidays," she said.
However, Shaw draws the line at stores being open on Thanksgiving day. "They (retail employees) should be able to be with their families. Shopping should be such a small part of it," she said.
"It's all about food, family and sweat pants."
Retail industry officials say 40 percent of consumers planned to start their holiday shopping before Halloween, suggesting there is demand for earlier shopping opportunities.
Another shopper at City Creek Center, Keith Waters of Orlando, Fla., said "holiday creep" extends to the point that once the actual holidays arrive, he's somewhat tired of the season.
"I'd prefer they didn't but I kind of think the free market takes care of itself," he said.
A Target employee in California started an online petition urging corporate leaders to back off the plan to open its stores at 9 p.m. on Thanksgiving. The petition has more than 200,000 signatures.
The holiday is one of the few that workers had been able to spend with their families, Target worker Casey St. Clair told CNN. St. Clair has worked part-time for the company for six years.
Toys R Us, Wal-Mart, Sears and Kmart are also scheduled to open Thanksgiving night, and an hour earlier than Target.
Shayla Christensen of Blackfoot, Idaho said her family has Thanksgiving dinner at her grandmothers' house each year, with some 60 people in attendance. "You should be able to spend that time with family."
Her sister Megan Christensen concurred: "I don't like that I have to work the day after Thanksgiving. I feel that's bad enough. Everyone should have that time off. It's a time for family."
Mary Talboys, a licensed clinical social worker and director of services for the University Neuropsychiatric Institute, said "holiday creep" can be problematic.
"It's not good. Then the stress gets going earlier in the season. The kids get amped up with expectations," Talboys said.
Even though holiday shopping opportunities abound prior to the traditional post-Thanksgiving kickoff, families should remember what they value about the holiday season, whether it's family gatherings, religious observances or gift giving.
Shoppers who object to retailers extending the shopping season and take offense to workers being required to work on Thanksgiving may want to stay home.
If large numbers of people shop later in the season, "maybe they (retailers) won't do it so early next year," Talboys said.
For Andrea Martinez of Provo, the early start to shopping season helps her keep her holiday stress in check.
"I feel like it's nice to get it out of the way. I get a little anxious during the holidays if I don't have my shopping done. I try to get it done by Black Friday."
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© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Volume 8, Issue 6
Pages 1045–1330
Wanchun Guo, Qian Wang, Prof. Ge Wang, Mu Yang, Prof. Wenjun Dong and Jie Yu
Version of Record online: 23 MAY 2013 | DOI: 10.1002/asia.201390016
Well-defined core–shell Fe3O4@poly 4-vinylpyridine-co-divinyl benzene (Fe3O4@P(4VP-DVB)) magnetic polymer microspheres have been synthesized with the aid of strong hydrogen-bond interactions between magnetic cores and functional monomers, as reported by Ge Wang et al. in their Full Paper on page 1160 ff. Au nanoparticles were embedded into the outer shell of as-synthesized composite microspheres through reduction of HAuCl4 to finally form the Fe3O4@P(4VP-DVB)@Au nanostructure, which exhibited high catalytic activity, facile magnetic recoverability, and high stability for the reduction of 4-nitrophenol.
Zahra Dezhahang, Mohammad Reza Poopari and Prof. Dr. Yunjie Xu
Version of Record online: 23 MAY 2013 | DOI: 10.1002/asia.201390017
Picolylamine-type ligands are multidentate nitrogen-donor ligands with a wide range of applications. In their Full Paper on page 1205 ff. (highlighted on the Inside Cover), Yunjie Xu et al. report the vibrational circular dichroism (VCD) spectra of three related chiral multidentate nitrogen-donor ligands. VCD spectroscopy measures the differential absorption of right versus left circularly polarized light that accompanies a vibrational transition and is highly sensitive to even minor structural changes. By comparing the experimental and the simulated VCD spectral features, the authors identified the dominant conformers of these ligands in solution and interpreted a VCD sign-reversed phenomenon observed in the amide I region using the explicit solvation model.
Version of Record online: 23 MAY 2013 | DOI: 10.1002/asia.201390018
Version of Record online: 23 MAY 2013 | DOI: 10.1002/asia.201390019
Dr. Katherine M. Schultz, Prof. Dr. Dafa Chen and Prof. Dr. Xile Hu
Version of Record online: 17 APR 2013 | DOI: 10.1002/asia.201300232
Plenty of [Fe]s in the fire: Recent studies on the structure and properties of [Fe]-hydrogenase have revealed the presence of a mono-iron-containing active site with ironacyl ligation. A number of synthetic complexes with this type of ligation have been prepared as models of this active site.
Dr. Kun Wang, Prof. Jian-Guo Zhang, Tian-Tian Man, Man Wu and Chun-Chun Chen
Version of Record online: 18 APR 2013 | DOI: 10.1002/asia.201201241
All to do with H2: This Focus Review discusses the development of metal aminoboranes including their synthesis, structure, chemical characterization, and applications. The lightweight nature of the molecules, the simplified procedures for the synthesis of the target compounds, the reversibility of hydrogen storage and dehydrogenation, and the mechanism of thermal decomposition are also discussed.
Corrigendum: Corrigendum: Recent Process and Development of Metal Aminoborane
Vol. 8, Issue 11, 2525, Version of Record online: 28 OCT 2013
Jun Xuan, Bin-Jie Li, Zhu-Jia Feng, Guo-Dong Sun, Huan-Huan Ma, Zhi-Wei Yuan, Dr. Jia-Rong Chen, Dr. Liang-Qiu Lu and Prof. Dr. Wen-Jing Xiao
Version of Record online: 3 APR 2013 | DOI: 10.1002/asia.201300224
All lit up: A novel and efficient desulfonylation method of tosyl amides has been developed by means of visible-light-promoted reductive cleavage of NS bonds. This method has a broad substrate scope, good functional group tolerance, and excellent yields.
Jiangyu Li, Prof. Nianchen Zhou, Prof. Zhengbiao Zhang, Ying Xu, Prof. Xinrong Chen, Prof. Yingfeng Tu, Prof. Zhijun Hu and Prof. Xiulin Zhu
Version of Record online: 15 APR 2013 | DOI: 10.1002/asia.201300154
Put a ring on it: A cyclic azobenzene has a much higher melting point, stronger fluorescence, and better film-forming and SRG-formation ability than its linear precursor. Pcyclic-AzoMMA, with cyclic azobenzene pendant groups, has a much higher Tg value (100 °C) than Plinear-AzoMMA, with linear pendants groups (58 °C), and the modulation depth of the photoinduced SRG of Pcyclic-AzoMMA is thirty times larger than that of Plinear-AzoMMA.
Baode Ma, Ziyuan Ding, Ji Liu, Yanmei He and Prof. Dr. Qing-Hua Fan
Version of Record online: 28 MAR 2013 | DOI: 10.1002/asia.201300150
A PHOX with arms: A series of dendrimers with Ir phosphinooxazoline (PHOX) cores were designed and synthesized and found to be highly effective and recoverable catalysts for asymmetric hydrogenation of 2,4-diaryl-1,5-benzodiazepines. An obvious positive dendritic effect on reactivity was observed, leading to chiral nitrogen-containing heterocycles with excellent enantioselectivities.
Jing Li, Guo-Liang Liu, Xian-He Zhao, Ji-Yuan Du, Hu Qu, Wen-Dao Chu, Ming Ding, Cong-Yang Jin, Meng-Xue Wei and Prof. Dr. Chun-An Fan
Version of Record online: 18 MAR 2013 | DOI: 10.1002/asia.201300139
The pain ends here: A novel synthetic strategy for the construction of (±)-morphine rings B and E was developed, in which SmI2-promoted reductive coupling/desulfurization and tandem alcoholysis/oxa-Michael addition featured as the key steps for the assembly of the C9C14 and C5O bonds, respectively. Asymmetric tandem alcoholysis/oxa-Michael addition was also feasible for the enantiocontrolled synthesis of morphine.
Chang An Wang, Dr. Yuan Zhang, Dr. Jiao Yi Shi and Prof. Dr. Wei Wang
Version of Record online: 9 APR 2013 | DOI: 10.1002/asia.201300152
Lean on me: A soluble, "self-supported" chiral organosilica polymer (ChiOSP) with embedded imidazolidinone catalytic moieties was synthesized by a bottom-up strategy and applied as a highly efficient and recyclable organocatalyst for the asymmetric Diels–Alder reaction.
Prof. Dr. Hidehito Komatsuzaki, Akihiko Shiota, Shogo Hazawa, Muneaki Itoh, Noriko Miyamura, Nahomi Miki, Yoichi Takano, Dr. Jun Nakazawa, Dr. Akiko Inagaki, Prof. Dr. Munetaka Akita and Prof. Dr. Shiro Hikichi
Version of Record online: 19 MAR 2013 | DOI: 10.1002/asia.201300029
Catecholate catwalk: Monomeric manganese(III) catecholato and manganese(II) semiquinonato complexes as the substrate-binding model of catechol dioxygenase have been synthesized and structurally characterized. The semiquinonato complex reacted with molecular oxygen to give ring-cleaved products and benzoquinone in the catalytic condition.
You Xu, Huan Wang, Rongjiao Zhu, Cuibo Liu, Xuan Wu and Prof. Dr. Bin Zhang
Version of Record online: 22 APR 2013 | DOI: 10.1002/asia.201300078
Flaking out: Porous hybrid Cu2O/polypyrrole nanoflakes were synthesized through reductive transformation of CuO nanoplates in the presence of pyrrole. The as-prepared porous hybrid nanostructures exhibited efficient catalytic activity and high stability towards an oxygen reduction reaction in alkaline solution.
Dr. Moumita Bose, Dr. Golam Moula and Prof. Dr. Sabyasachi Sarkar
Version of Record online: 15 APR 2013 | DOI: 10.1002/asia.201300245
A FeW good men: Mössbauer and EPR spectroscopy, magnetism, electrochemistry, and electronic structural analysis based on DFT and TD-DFT calculations of a series of FeW bimetallic complexes show the presence of a ferromagnetically coupled FeIIIWV unit, along with antiferromagnetic intermolecular interactions, from the starting FeII and WVI compounds. A net spin of a S=3 ground state displays a rare X-band EPR in normal mode at g≈7.
Dr. Dmitri V. Konarev, Prof. Sergey I. Troyanov, Dr. Salavat S. Khasanov, Dr. Akihiro Otsuka, Prof. Hideki Yamochi, Prof. Gunzi Saito and Prof. Rimma N. Lyubovskaya
Version of Record online: 11 MAR 2013 | DOI: 10.1002/asia.201300086
The cocoon chain: A new salt, (PPN+)2(C702−)⋅2 C6H4Cl2 (1), which contains polymeric zigzag (C702−)n chains, was obtained; the fullerene C702− units are bonded in the polymer through single CC bonds of length 1.581(5)–1.586(6) Å. Salt 1 shows broad absorption in the NIR region, with maxima at 890, 1200, and 1550 nm. The (C702−)n polymer is diamagnetic and EPR silent, with a negative molar magnetic susceptibility of −3.82×10−4 emu mol−1.
Binbin Hu, Xiaopeng Chen, Yifei Wang, Prof. Dr. Ping Lu and Prof. Dr. Yanguang Wang
Version of Record online: 5 APR 2013 | DOI: 10.1002/asia.201300028
A good sense o pH humor: Various triphenylamine derivatives functionalized with fluorophenyl, methoxyphenyl, and pyridinyl groups as respective donors and acceptors were synthesized and characterized. Their photophysical properties were systematically investigated in solvents of different polarities. Several synthesized compounds, especially tris(4-(pyridin-4-yl)phenyl) amine, exhibited significant pH-dependent absorptions and emissions, thus indicating that these compounds might be used as pH sensors.
Alexey N. Ponomaryov, Namseok Kim, Jaewon Hwang, Prof. Hiroyuki Nojiri, Dr. Johan van Tol, Dr. Andrew Ozarowski, Jena Park, Prof. Zeehoon Jang, Byoungjin Suh, Prof. Sungho Yoon and Prof. Kwang-Yong Choi
Version of Record online: 18 MAR 2013 | DOI: 10.1002/asia.201300054
Cubane Libre: The structures of FeII and NiII cubanes were tuned by changing the steric size of peripheral ligands. The resulting asymmetric and symmetric metallocubanes possess different magnetic properties, as assessed by detailed electron paramagnetic resonance (EPR) measurements.
Version of Record online: 5 APR 2013 | DOI: 10.1002/asia.201201186
Stringing them along: Hierarchical Fe3O4@poly(4-vinylpyridine-co-divinylbenzene)@Au nanostructures were synthesized through a series of simple hydrogen-bond-assisted polymerization and immobilization processes (see scheme). The nanocatalysts exhibited outstanding activity, magnetic recoverability, and high stability for reduction of 4-nitrophenol.
Ramu Surakanti, Sumalatha Sanivarapu, Chiranjeevi Thulluri, Pravin S. Iyer, Raghuram S. Tangirala, Rambabu Gundla, Dr. Uma Addepally, Y. L. N. Murthy, Lakshmi Velide and Dr. Subhabrata Sen
Version of Record online: 19 MAR 2013 | DOI: 10.1002/asia.201201203
DOS and don′ts: A reagent-controlled strategy for the generation of biologically active scaffolds from a chiral lactam has been developed. In silico studies were used to estimate the drug-like properties of these compounds, such as spiroindoline.
Corrigendum: Corrigendum: Synthesis of Privileged Scaffolds by Using Diversity-Oriented Synthesis
Vol. 9, Issue 7, 1706, Version of Record online: 20 JUN 2014
Dr. Waka Nakanishi, Yusuke Shimada and Prof. Hiroyuki Isobe
Version of Record online: 7 MAR 2013 | DOI: 10.1002/asia.201300098
One, two, three: Three congeners of disilanyl double-pillared bisheteroarenes have been synthesized by a concise one-pot synthetic procedure. The step-like structures of the silacyclophanes were revealed by X-ray crystallographic analysis. The step-like structures, however, fluctuated in a solution phase in the presence of steric congestions, and the dynamics were disclosed by NMR spectroscopy.
Wei Yang, Dr. Ke-Zhi Jiang, Xing Lu, Hua-Meng Yang, Dr. Li Li, Prof. Dr. Yixin Lu and Prof. Dr. Li-Wen Xu
Version of Record online: 3 APR 2013 | DOI: 10.1002/asia.201300141
Good, phosphine! An achiral phosphine is an ideal partner in the chiral-primary-amine-catalyzed enantioselective Michael reaction of aliphatic aldehydes with maleimides, thus enabling enantioselective induction in a dual organocatalytic system.
Dr. Jun Nakazawa, Tomoaki Hori, Prof. Dr. T. Daniel P. Stack and Prof. Dr. Shiro Hikichi
Version of Record online: 12 APR 2013 | DOI: 10.1002/asia.201300165
Going nowhere fast: An immobilized SBA*-L-x/Ni complex was prepared with various ligand loadings and used in the oxidation of cyclohexane. The importance of site-density control for the development of immobilized catalysts has been demonstrated.
Lu Wang, Dr. Adriano Ambrosi and Prof. Martin Pumera
Version of Record online: 19 MAR 2013 | DOI: 10.1002/asia.201300122
Impure and simple: Thermally and chemically reduced graphene materials contain significant amounts of carbonaceous impurities that are similar in structure to amorphous carbon. Herein, the claimed electrocatalytic activities of these materials for the oxidation of NADH, acetaminophen, and hydroquinone are shown to mainly be due to the presence of carbonaceous impurities.
Version of Record online: 5 APR 2013 | DOI: 10.1002/asia.201300070
Good vibrations! Vibrational circular dichroism spectra of three related chiral multidentate nitrogen donor ligands allow the identification of the dominant conformers of these ligands in solution (see picture). Different degrees of conformational flexibility of these ligands are also investigated.
Xiu-dong Yang, Chang-ming Dong, Jian Chen, Ya-hui Ding, Qi Liu, Xiao-yan Ma, Dr. Quan Zhang and Prof. Yue Chen
Version of Record online: 10 APR 2013 | DOI: 10.1002/asia.201300051
Talking Tuv: The Tup and Tuv fragments of tubulysins were obtained using chiral sulfinimines, and then tubulysin U and its C-4 epimer were synthesized in a highly selective and efficient manner. C-4 epi-tubulysin U maintained significant growth inhibition activities against cancer cell lines, as assessed by MTT assay.
Fu-Ai Teng, Dr. Yan Cao, Yuan-Jiang Qi, Mingjun Huang, Prof. Zhe-Wen Han, Prof. Stephen Z. D. Cheng, Dr. Wen-Bin Zhang and Prof. Hui Li
Version of Record online: 11 MAR 2013 | DOI: 10.1002/asia.201300043
Shape matters: Sphere–rod shape amphiphiles, in which a [60]fullerene sphere was connected to an oligofluorene rod through a rigid linkage, were synthesized. The spheres and rods packed into an alternating layered structure in the crystals, resembling a "double-cable" structure
Dr. Edith Chardon, Dr. Georges Dahm, Dr. Gilles Guichard and Dr. Stéphane Bellemin-Laponnaz
Version of Record online: 4 APR 2013 | DOI: 10.1002/asia.201201148
Expand and diversify your Ptfolio: N-Heterocyclic carbene-Pt-pyridine complexes have been used to generate an expanded and diversified set of trans NHC-Pt complexes with various amines, polyamines, hydroxylamines, or hydrazine as ligands. Attachment of a fluorophore moiety has also been successfully achieved.
Nobuhiro Shionozaki, Naoki Iwamura, Ryo Tanaka, Prof. Kimiko Makino and Prof. Hiromi Uchiro
Version of Record online: 28 MAR 2013 | DOI: 10.1002/asia.201201230
Livin′ the IMDA loca: The total synthesis of diaporthichalasin has been achieved for the first time. It features an intramolecular Diels–Alder (IMDA) reaction between the diene side chain on a decalin and an α,β-unsaturated lactam in aqueous media. Our findings suggest a novel biosynthetic pathway for diaporthichalasin.
Yi Yuan, Guo-Qiang Zhang, Feng Lu, Prof. Qing-Xiao Tong, Qing-Dan Yang, Hin-Wai Mo, Dr. Tsz-Wai Ng, Dr. Ming-Fai Lo, Dr. Zheng-Qing Guo, Chuan Wu and Prof. Chun-Sing Lee
Version of Record online: 21 MAR 2013 | DOI: 10.1002/asia.201300002
Hidden depths: A new versatile material, 4-(7,10-diphenylfluoranthen-8-yl)-N-[4-(7,10-diphenylfluoranthen-8-yl)phenyl]-N-phenylaniline, with a high glass transition temperature of 220 °C has been synthesized and characterized. Its applications in organic light-emitting diodes have also been investigated (see picture).
Soonchang Hong, Prof. Dr. Kevin L. Shuford and Prof. Dr. Sungho Park
Version of Record online: 19 MAR 2013 | DOI: 10.1002/asia.201300004
A la mode: Au nanorods (NRs) that were synthesized through two different synthetic methods displayed different surface crystallinity and smoothness. Au NRs that were synthesized by using a wet-chemical method showed a smoother surface, {111} single crystallinity, and a much stronger longitudinal surface plasmon (LSP) quadrupole mode than Au NRs that were prepared by using an anodized aluminum oxide (AAO)-template-assisted method.
Jun Xing, Zu Peng Chen, Fang Yuan Xiao, Xue Yan Ma, Ci Zhang Wen, Dr. Zhen Li and Prof. Hua Gui Yang
Version of Record online: 12 MAR 2013 | DOI: 10.1002/asia.201300019
Powerful separation: Multicomponent CuCu2OTiO2 nanojunction systems were successfully synthesized by a mild chemical process (see picture) and exhibited prolonged lifetimes of photogenerated carriers and enhanced photocatalytic properties. An unusual electron–hole transmission pathway for the photocatalytic reaction over CuCu2OTiO2 was also identified.
Dr. Teresa Gómez, Dr. Daniel Moreno, Borja Díaz de Greñu, A. Cristina Fernández, Dr. Teresa Rodríguez, Dr. Josefa Rojo, Dr. José V. Cuevas and Prof. Dr. Tomás Torroba
Version of Record online: 11 MAR 2013 | DOI: 10.1002/asia.201300049
Shining almonds! A new indene derivative is a highly selective and sensitive fluorogenic probe for the fluorescent detection and quantification of cyanide anions from aqueous extracts of green almond seeds, with a 103-fold increase of fluorescence and low detection limit (see figure), thus proving that the system is suitable for fast detection and quantification of cyanide from natural sources.
Dikhi Firmansyah, Adina I. Ciuciu, Vincent Hugues, Dr. Mireille Blanchard-Desce, Dr. Lucia Flamigni and Prof. Daniel T. Gryko
Version of Record online: 5 APR 2013 | DOI: 10.1002/asia.201300058
Mr. Brightside: Imidazo[1,2-a]pyridine derivatives show blue, green, or yellow fluorescence depending on the nature of the substituents. Quadrupolar dyes that feature this scaffold as an electron donor display an advantageous combination of optical properties, including two-photon brightness (40 GM).
Rou Jun Toh, Hwee Ling Poh, Prof. Zdeněk Sofer and Prof. Martin Pumera
Version of Record online: 11 MAR 2013 | DOI: 10.1002/asia.201300068
Performance-enhancing doping: Transition metal-doped graphene hybrids were prepared by exfoliation of metal-doped graphite oxide precursors in either H2 or N2 atmosphere. The electrocatalytic activities of the transition metal-doped graphene hybrids were reflected in an enhancement of the kinetics of oxygen reduction under alkaline conditions, which is important for renewable energy applications such as fuel cells. It was found that hybrid materials exfoliated in N2 atmosphere exhibited greater electrocatalytic activities than those exfoliated in H2 atmosphere.
Dr. Bishnu Prasad Bastakoti, Yin-Chu Hsu, Shih-Hsiang Liao, Prof. Kevin C.-W. Wu, Dr. Masamichi Inoue, Prof. Shin-ichi Yusa, Kenichi Nakashima and Prof. Yusuke Yamauchi
Version of Record online: 25 MAR 2013 | DOI: 10.1002/asia.201300072
Facile strategy delivers: Polymeric micelles consisting of asymmetric triblock copolymers were successfully used for fabrication of robust hybrid nanoparticles with highly biocompatible calcium phosphate shells. Fluorescent dyes can be used as imaging agents for determining the location of the nanoparticles and to give an observable indication of drug delivery, while the calcium phosphate shell can enhance the fluorescence of the encapsulated dye.
Xin-Yu Zhao, Prof. Dr. Ying-Jie Zhu, Feng Chen, Bing-Qiang Lu, Chao Qi, Jing Zhao and Dr. Jin Wu
Version of Record online: 15 APR 2013 | DOI: 10.1002/asia.201300083
Exerting control: A simple, room-temperature synthesis of calcium phosphate hybrid nanoparticles (CaP-HNPs) by using poly(diallyldimethylammonium chloride) (PDADMAC) and poly(acrylate sodium) (PAS) as dual templates is described (see picture). The as-prepared CaP-HNPs are promising anticancer drug (docetaxel; Dtxl) nanocarriers for cancer therapy.
Xin-Yu Zhao, Prof. Dr. Ying-Jie Zhu, Chao Qi, Feng Chen, Bing-Qiang Lu, Jing Zhao and Dr. Jin Wu
Version of Record online: 3 APR 2013 | DOI: 10.1002/asia.201300142
Bon apatite: Hierarchical hydroxyapatite nanostructures that were constructed by the self-assembly of nanorods or nanosheets, including nanorod-assembled hierarchical hollow microspheres, nanorod-assembled hierarchical microspheres, and nanosheet-assembled hierarchical microspheres, have been prepared by using biocompatible biomolecule pyridoxal-5′-phosphate (PLP) as an organic phosphorus source in a rapid microwave-assisted hydrothermal method.
Ming Dong, Prof. Dr. Ya-Wen Wang, Dr. Ai-Jiang Zhang and Prof. Dr. Yu Peng
Version of Record online: 19 MAR 2013 | DOI: 10.1002/asia.201300159
Glowing recommendation: We have demonstrated the selective, sensitive recognition of 2,4,6-trinitrophenol (TNP) with remarkable visual changes in a series of N-acylhydrazone fluorescent chemosensors (see figure). Their host–guest interactions were established from 1H NMR spectroscopic titrations and the corresponding co-crystal structures. An intramolecular charge-transfer process during fluorescence quenching was further disclosed through DFT calculations.

subset: commoncrawl


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Go Ahead, Be Cynical: The Positive Power of Negative Thinking
Study shows positive thinkers don't outperform pessimists.
Study shows positive thinkers don't outperform pessimists.
Pro-regime hackers say the U.S. president's terrorism capabilities 'are quite high.'
This is pretty cool.
3 ways to save yourself--and your team.
Michael Hayden was giving off-the-record interviews by phone while a former MoveOn staffer eavesdropped on train.
Foreign officials joked about buying Kerry meals.
Many companies received stop-work orders that might have been unnecessary.
The Healthcare.gov debacle shows the administration doesn't know how to run the executive branch.
What can we learn from the budget brawls of late?
President greets 2013 Service to America honorees at White House nearly a week after the government reopens.
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23 April 2012 12:07 PM, PDT | POPSUGAR | See recent BuzzSugar news »
Documentarian Morgan Spurlock took on the country's growing health epidemic in Super Size Me and the expansive advertising industry in The Greatest Movie Ever Sold, but now he's tackling an even bigger issue: manscaping. In the trailer for Spurlock's new film, Mansome, Will Arnett and Jason Bateman work with Spurlock to get to the bottom of why men's maintenance has become more important than ever in recent years, with the help of some celebs as well as everyday guys. Clearly this movie isn't as serious as the director's previous projects, but it does look kind of hilarious. Arnett and Bateman have perfected their bro-chemistry (thanks to Arrested Development), and I definitely got a kick out of them in mud masks. While I'm still not sure about the balance between funny and fact, I'm happy to listen to Zach Galifianakis wax poetic about facial hair any day. The flick premiered this week at Tribeca, »
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Information Links
Bots, IoT and cancer research among projects chosen for Publicis90 initiative
The French developer of a bot messaging platform and Israeli start-ups seeking to detect skin cancer and bring the Internet of Things to retail are among the 90 companies to win up to €500,000 in funding as part of Publicis Groupe's anniversary celebrations.
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The Wall investigates the impact of emerging technology and media change in the marketing, media and communications industries.
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EpicMix Racing Announced for 2012-2013 at Vail
Announcing the latest addition to the EpicMix platform: EpicMix Racing! Now you can use your RF enabled pass or lift ticket to race against your family and friends, and compare yourself to Vail's most famous ski racer, Lindsey Vonn!
Vail's Black Forest race area under Chair 2 has always been a popular place for aspiring racers and those who have never raced a gate course and want to give it a try. In the past, you had to sign up using paper forms, and once you raced, you heard your time and that was it. Now, EpicMix Racing will allow you to race the course using the RF chip on your pass or lift card. You can see your times on your EpicMix account, and choose whether or not you would like to share with family or friends. Earn virtual medals, keep track of your progress, and see how you stack up to Lindsey's time for the course.
Not only will you be able to share your time, but those now-familiar green suited EpicMix photographers will be there to capture your race, providing photos for you to share.
Learn more about EpicMix Racing at the official page: http://www.epicmix.com/
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Ship refurbishment specialists Blu Marine complete the £500,000 contract, and P&O has begun operating the ship on its Troon to Larne service.
Blu Marine carried out the work in Belfast Harbour, which mainly involved fitting the P&O Express with a new Club Lounge designed to meet the needs of business travellers. The 90-capacity lounge will offer complimentary news-papers, magazines, drinks and snacks, with facilities in place to allow passengers to use laptops, tablets and mobile phones.
The wider refurbishment saw Blu Marine, which previously worked on P&O's Dover to Calais vessels, add a range of other new facilities to the vessel, which will include a family lounge and bar, food court and kids' area.
Blu Marine employs 94 staff and carries out ship refurbishments around the world from its sites in Belfast, Southampton and Hong Kong.
It is currently in the process of relocating its head office function from Southampton to Belfast.
Maritime Today
The Maritime Industry's original and most viewed E-News Service
The American Waterways Operators (AWO) and ClassNK have signed an agreement under which ClassNK will be authorized to conduct audits of AWO's Responsible Carrier Program,
Radio Holland Canada has won two major contracts to support the Canadian Coast Guard. Public Works and Government Services Canada, which is responsible for government procurement,
Young Brothers, Limited, Hawai'i's largest inter-island cargo service provider, and Conrad Shipyard, signed a contract to build four new tugs, a nearly $80 million
MacGregor, part of Cargotec, has won an order to supply MacGregor offshore cranes and a Triplex handling system for a 14,300gt polar research vessel being built
Hybrid RoPax ferry Texelstroom has been delivered to Koninklijke N.V. Texels Eigen Stoomboot Onderneming (Royal TESO).
This latest generation symmetrical ferry is powered by efficient,
Oil prices closed 2 percent higher after a volatile session on Thursday, with investors less worried about prospects for the global economy after the last pre-vote
Four new fast ferries, owned and managed by Manly Ferries and operating in the busy waters of Sydney Harbour, will use Simrad technology for safe navigation.


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Sarah Stevenson announced that the Forum will NOT meet on Tuesday, July 5.
Keysha Walker announced that the New Generation of African American Philanthropists giving circle's 2016 grant cycle is open through Friday, July 8. Details here. More information at Foundation for the Carolinas website or the NGAAP website.
Nakisa Glover announced that a small group of Forum participants is looking for people willing to provide sites for voter registration drives. Contact Glover by e-mail.
Nakisa Glover announced that she can offer programs explaining SafeLink, the federally subsidized program through Trakfone to provide cell phones to income-eligible families. Brochure here. Contact Glover by e-mail.
Justin Perry announced that OneMeck will sponsor "Let's Build a Community: Getting Intentional About Housing, Education and Equity in Charlotte" on Sunday, July 3 from 4-6 p.m. at the South End Common Market, 1515 S Tryon St. Details here.
Thomas Moore announced that his 11 a.m. church service message this Sunday, July 3, at Covenant United Methodist Church, 6824 Tuckaseegee Rd., will focus on the role music and singing can play in improving health and building community.
Brenda Robinson announced that Aviation Camps of the Carolinas will hold activities four times a year, October, December, March and June, for students to show the many careers tied to aviation. Details to come on her website.
Isaac Applewhite announced that he hoped the Forum would re-extend its June 28 invitation to providers of summer youth programs, to outline their work and help create more awareness of what is available to parents in all parts of the community.
Renea Steele announced that nonprofits, social and civic organizations can raise funds at Time Warner Cable Arena by having their volunteers staff arena vending sites during events. Reach Steele by e-mail.
Raphael Basisa announced that the Charlotte Congolese community is holding its annual fundraising effort to build a Congolese Cultural Center in Charlotte. Details here or Basisa by e-mail.
Henry Rock sent in a message he gave in the AtlanticMedia's Renewal Series on the value of embracing entrepreneurial activity among black male millennials.
Dena Diorio sent in her June 27 Board Bulletin.
Larken Egleston sent in an announcement that the Young Democrats of Mecklenburg County will meet Tuesday, July 19 from 6:30-8 p.m. at AZN Restaurant in SouthPark, 4620 Piedmont Row Dr. Info here.View the
Three development teams presented their plans for the Brooklyn Village redevelopment. BK Partners was selected Wednesday.
Lots of speakers took advantage of Open Forum to raise issues for community discussion.
Two pastors discussed nontraditional ways in which they are working with their flock to improve Charlotte.
Tamika Lewis and Robert Dawkins describe efforts to engage youth in undertaking neighborhood improvements of their choosing.
An update on the renovation under way at West Charlotte Recreation Cetner
Justin Harlow's March update for the Five Points Community Collaborative.
Malachi Greene was remembered today at his beloved Tuesday Morning Breakfast Forum by people touched by a dedicated soul.
Elisa Chinn-Gary, Wilhelmenia Rembert and Queen Thompson: Three women who went first.
Sarah Stevenson's message to Charlotte's young leaders, on the death of MarShawn McCarrel in Ohio.
Charles Thomas named program director for Knight Foundation in Charlotte.
Willie Ratchford welcomed the Forum to its new home at Belmont Regional Center at 700 Parkwood Ave.
CIAA staff present on the upcoming basketball tournament in Charlotte
Tommie Robinson to be on Rachel Martin's Sunday Jan. 10 radio show on NPR.
The Forum moves Jan. 19 to the Belmont Regional Center, 700 Parkwood Ave., Sarah Stevenson announced.
The Tuned In Choir helped make the 2015 Forum Christmas Party a festive gathering.
Co-chairs of the Opportunity Task Force explain what they've learned about economic mobility.
Long-delayed renovation at West Charlotte Rec Center may start in January.
QCityMetro profiles J'Tanya Adams' work spearheading Saturday's Internet and Computer Bazaar to provide more low-income families access to the Internet.
Charlotte Post outlines education workshops about upcoming Kwanzaa celebration.
Observer profiles Sarah Stevenson on the occasion of her 90th birthday.
Dream Builders CEO Kenston Griffin uses this exercise to help adults understand how children learn.
Dream Builders Communications and Profound Gentlemen offered ideas on what works to improve schools.
Carlenia Ivory describes a project working with 21 high school students and their families.
CMS Board Chair Mary McCray offered an update on assignment and the superintendent search.
Brenda Robinson gave this update on the area visits by the Traveling Space Museum and NASA Space Camp.
Dorothy Counts-Scoggins and Bonita Caldwell shared their experiences with leadership.
CMS Supt. Ann Clark and CMS Foundation Executive Director Sonja Gantt.
Blanche Penn: "I'm a freedom fighter."
James Ford with an update on his job at the N.C. Public School Forum, and a defense of helping children, not blaming them for the lack of support from home.
Carlenia Ivory issued an appeal for turnout at a CMS Policy Committee meeting.
Former CMS principal Ken Simmons says "bad" schools" serving minority students can be fixed "overnight."
CMS officials pitch participation in student assignment survey.
Take the community online survey designed to assist the school board redesign CMS student assignment.
Five speakers including Kayla Romero argued OneMeck's case for schools that work for all children.
Brenda Robinson, an African-American "first," uses her aviation experience to give back to young people.
Carlenia Ivory and Dr. Yolonda Holmes make plea for mentors at West Meck High.
Terrell Ivory discusses his recruitment of minority students to Phillips Academy in Massachusetts.
Queen Thompson on why CMS is naming a new school for her grandfather, Lawrence Orr.
Ken Simmons led a group presentation on appoaches to education at majority-African American schools.
Janeen Bryant and six other candidates for CMS Board of Education.
Fulton Meachem and Ken Szymanski, representing two powerful housing interests, discuss affordable housing opportunities in Charlotte.
Jason (Jet) Jones brought his teacher (Maria Macon), his singing, his videos and his enthusiasm for an entrepreneurial approach to the world.
Bonita Caldwell, president of Beatties Ford Memorial Gardens, shared approaches to business leadership.
Juanita Miller, left, Carolyn Logan and Ken Koontz discussed making their way in organizations once closed to African-Americans.
Urban League CEO Dr. Patrick Graham on how League works inside for progress.
Entrepreneurial business owners and executives share some of their experiences.
Laura Clark and Christian Friend outline rebuilding efforts at old Boulevard Homes public housing site.
Officials from Charlotte Works called on CMS, CPCC and employers to make time for youth to learn work skills.
Google Fiber staffers on the status of the rollout of gigabyte-speed Internet access in Charlotte.
Dale Mullennix on Housing First, a trailblazing effort to end chronic homelessness.
Bob Morgan, president of the Charlotte Chamber, painted a picture of a diverse, growing city and a chamber trying to change with it.
Lucy Bush Carter, executive director of Friendship Trays, made this presentation Tuesday about the launch Wednesday of a new culinary job training program.
The Young Entrepreneurs Network is helping young business owners learn the ropes.
Anna Hood and Fannie Flono discuss breaking down barriers in the workplace.
Henry Rock wants to train Charlotteeans to pursue their entrepreneurial dreams.
Three speakers from different organizations focus on minority inclusion in the workplace.
Fulton Meachem talks about the Charlotte Housing Authority about 6 months after his arrival as CEO.
Latasha McIlwaine, left, and two other health service providers addressed the Forum.
Elana Congress discussed health programs at Care Ring; Eric Montgomery discussed estate planning.
Debra Weeks led an update on rebuilding the C.W. Williams Community Health Center.
Charlotte Post covers latest developments in revival of C.W. Williams Community Health Center.
Participants pulled off a total surprise for the guy usually behind the camera as they celebrated Steve Johnston's 69th birthday.
Lucy Bush Carter describes the work and needs of Charlotte's meals-on-wheels program.
Dr. Deborah Walker summarized her four-day presentation on diversity, multiculturalism, equity and inclusion.
Care Ring navigator Elana Congress summarizes upcoming deadlines under Affordable Care Act.
News outlets report on C.W. Williams Health Center audit going to commissioners.
Local papers write about situation at C.W. Williams Community Health Center.
Three nonprofits collaborate to provide medical care and medications to those without other options.
Training is available from Mental Health America of Central Carolinas to help spot mental health issues among family, friends and colleagues.
Staff from Piedmont Health Services and Sickle Cell Agency described their efforts to assist sickle cell patients, and educate the public on disease.
Charlotte artist Tommie Robinson's 2015 exhibition at Latibah Collard Green Museum featured the Environmental Series canvases that were part of his recent work as UNCC artist-in-residence.
Debra Weeks, new CEO of C.W. Williams Community Health Center.
Sandra Clory announced a Tai Chi class she is teaching at Myers Park Baptist Church.
Desmond Wiggan described investment services available from Primerica.
Nelson Adesegha on fallout from Chapter 11 filing at C.W. Williams Community Health Center.
Johnson C. Smith University to present one of its Arch of Triumph Awards to the Forum at its annual gala in April 2015.
Terry Ellington and Lesha Dodson on HIV/AIDS in Charlotte and the Carolinas, and the work of Carolinas Care Partnership.
County Manager Dena Diorio brought key staffers to the Forum to let them explain the county's work.
Greg Phipps, city staff and other City Council members helped present a briefing on Charlotte's proposed budget.
LaWana Mayfield gave an impromptu update on a community meeting on the city budget, and developments on West Boulevard corridor.
Joel Ford offered an update on issues likely to come up in the legislative short session beginning Monday.
An Open Forum began with a discussion of H.B. 2, the "Public Facilities Privacy & Security Act."
Five trailblazers on the early years of African-American participation in local government, and the work yet to be done.
Delegation of mayors from Albania explain their U.S. visit.
Four African-American women who went first reflect on where they've been, and where things stand today.
Kevin Tully explained the role public defenders play in making the criminal justice system work for all.
Alysia Osborne outlined work undertaken by Historic West End Initiative; legislative leaders reported on the concluded session, and on efforts to inspire voter turnout.
Open Forum included comments by Commissioners Chair Trevor Fuller about the difficult community issues that lie ahead.
Mecklenburg legislators give an update on the recently completed General Assembly session in Raleigh.
County Manager Dena Diorio reported on leadership changes, renovations and reorganizations.
Rhonda Foxx announces a Sept. 1 community forum at Rep. Alma Adams' Charlotte office.
Kerr Putney, new Charlotte-Meclenburg Chief of Police, spotlights the need for officers to know their community.
Staff and City Council members explained transit plans for Charlotte, and the financing difficulties ahead.
Mecklenburg Republicans say the party is changing with the passing of a generation.
Retiring CMPD Chief Rodney Monroe and District Attorney Andrew Murray.
Vi Lyles, David Howard and Michael Barnes lay out differences on city budget vote.
Officers from Mecklenburg, 12th District and 9th District Democratic Parties outlined party strategy.
Five candidates for Congress on the June 7 primary ballot in Mecklenburg addressed the Forum.
Election results in Mecklenburg from March 15 primary.
Links to short presentations by candidates on the March 15 primary ballot.
Candidates for public office announce their intentions for 2016.
Election 2015 results.
Jennifer Roberts, Edwin Peacock answer questions at the Forum a week before the Charlotte mayoral election.
District candidates for Charlotte City Council.
Candidates for at-large seats on Charlotte City Council.
Dan Clodfelter, facing an Oct. 6 primary, spoke about mayor's role and his plans for a full term. He was joined by GOP Council candidate John Powell.
Janeen Bryant and six other candidates for CMS Board of Education.
Five of the seven candidates in District City Council contests on the Sept. 15 primary ballot.
Laurence Bibbs, Bruce Clark, Julie Eiselt and Claire Fallon on Council at-large primary.
Seven of the 12 at-large candidates in the Sept. 15 City Council primary.
Five of the six candidates for Charlotte mayor in the September primaries make their case, answer questions.
Alicia Brooks thanked supporters for help during her election to be a District Court judge.
Resident Superior Court Judge Linwood Foust comments on changing demographics on the local bench.
Here are the winners of 2014 elections in Mecklenburg and North Carolina.
John Arrowood is one of 19 candidates for a single N.C. Court of Appeals seat.
Mark Davis, running for re-election to N.C. Court of Appeals, encourages listeners to vote their interests.
Irwin Carmichael and Chris Hailey spar over their proposals for the Sheriff's Department.


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Have you ever looked at a game in progress and wondered, "i dunno wat this is about."
Allow Moonhunter to posit an answer.
A demon who isn't some hideous creature bent on consuming souls, bu is, in fact, a likable chap who enjoys having pleasant chats with people - trying to talk them into becoming his servants.


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Lyrics Depot is your source of lyrics to Angel by Adam Ant. Please check back for more Adam Ant lyrics.
Angel Lyrics
Artist: Adam Ant
Album: Wonderful
Adam Ant/Marco Pirroni/Boz Boorer
Well come tell me your story
I'll tell you mine
Sunday morning Communion
Standing in a line
Feeling like a cannibal
Eating flesh and drinking blood
Diguised as wine
I know someday we're gonna see
Wings spring out from your shoulders
What kind of being are you?
For there are moments upon moments
Upon moments
When you hardly seem to walk the earth
And I realize I've spent my whole life searching
Searching for an angel
For an angel (you're an angel)
So come tell me your story
I'll tell you all
Looking at Rococco statues
And paintings on the wall
Sitting up there high and mighty
Was this Eden was this hell?
I had to know
Adam Ant Lyrics
Adam Ant Wonderful Lyrics
More Adam Ant Music Lyrics:
Adam Ant - 5 Guns West Lyrics
Adam Ant - Antmusic Lyrics
Adam Ant - Christian D'or Lyrics
Adam Ant - Headgear Lyrics
Adam Ant - Making History Lyrics
Adam Ant - Picasso Visita El Planeta De Los Simios Lyrics
Adam Ant - Spanish Games Lyrics
Adam Ant - Strip Lyrics


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List all words starting with celibates
Only the word celibates was found, nothing longer.
Some random words: coacervate obbligati ibogaine hep bhakta craal eicosanoid
This is not a dictionary, it's a word game wordfinder.
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Line rushes: Ducks vs. Sharks
ANAHEIM -- Here is the expected lineup that the Ducks (22-5-4) will start with against the San Jose Sharks on Monday night at Honda Center. After being pulled for the first time in his brief NHL career Friday night, Viktor Fasth (11-2-1, 2.15 GAA, .922 SV%) will be back in net. Ben Lovejoy figures to be back in for a second straight game, which means either Bryan Allen or Luca Sbisa will come out. Allen was scratched Sunday against Detroit.
Bobby Ryan-Ryan Getzlaf-Corey Perry
Kyle Palmieri-Peter Holland-Teemu Selanne
Daniel Winnik-Saku Koivu-Andrew Cogliano
Emerson Etem-David Steckel-Brad Staubitz
Sheldon Souray-Francois Beauchemin
Cam Fowler-Toni Lydman
Bryan Allen or Luca Sbisa-Ben Lovejoy
-- And here is the potential lineup for the Sharks (13-11-6), who are 2-5-2 in their last nine and are coming off a 2-0 loss at Minnesota. One player San Jose won't have is physical defenseman Douglas Murray, who was traded to Pittsburgh on Monday for conditional second-round picks in 2013 and 2014. Ryane Clowe has missed the last three games due to a shoulder injury but he was eyeing a return against Anaheim and could likely be in the lineup. Antti Niemi (12-8-5, 2.27 GAA, .921 SV%) should get the start in goal.
Martin Havlat-Joe Thornton-Brent Burns
Patrick Marleau-Logan Couture-Tommy Wingels
James Sheppard-Joe Pavelski-T.J. Galiardi
Andrew Desjardins-Scott Gomez-Adam Burish
Matt Irwin-Dan Boyle
Justin Braun-Brad Stuart
Marc-Edouard Vlasic-Jason Demers
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Becker Marine Systems will present its product portfolio at the Kormarine 2009 from October 21 to 24. This is the leading Korean exhibition for the global shipbuilding market. At the Becker booth visitors will experience a presentation of the company's wide product range comprising of the Twisted Rudders TLKSR and TLFKSR, the Schilling KSR Rudder and the Mewis Duct. The latter has been recently introduced at the SMM 2008.
Since the launch of the fuel-saving Mewis Duct Becker has signed the first orders. The brand-new product will be installed on three existing vessels as retrofit. Becker expects to improve the propulsion by at least 5% and 7.5% respectively. The new Schilling KSR Rudder, is primarily suitable for tankers and bulk carriers, but also suitable for application to any other type of vessel.
With its Twisted Rudder technology Becker Marine Systems offers rudders with unchallenged manoeuvrability, lowest possible risk of cavitation erosion and reduced fuel consumption. Thus Becker combines the main topics of today's shipbuilding: To increase the efficiency and to protect the environment at the same time. The Twisted Leading Edge Rudder TLKSR has been fitted to over 50% of today's giant container vessels worldwide of 8,000 TEU and above. The twisted rudders have already become a standard for fast container vessels, PCTCs, RoRo, Ropax and cruise vessels.
Maritime Today
The Maritime Industry's original and most viewed E-News Service
Gerardo Borromeo, Vice Chairman of the International Chamber of Shipping (ICS) took the opportunity today to highlight the courage that is currently being displayed by seafarers,
Grant "Twiggy" Baker (ZAF) claimed victory today at the Puerto Escondido Challenge, besting a field of 24 of the world's best big wave surfers in towering 20-to-35
The winners of ISWAN's International Seafarers' Welfare Awards 2016 were announced on 24th June at a high-profile ceremony held in Manila, the Philippines. The


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'Noah' Passes Expectations, Debuts at No. 1 on Box Office
Thanks to the heavy criticism surrounding the movie, "Noah" gets the publicity it needed and successfully took the number one position in the weekend box office. The Darren Aronofsky-directed film racked in an estimated $44 million in ticket sales, a number beyond the studio's expectations.
Paramount Pictures initially forecast a $30-million weekend opening for the biblical movie that used $130 million in budget. It actually gained $95 million overseas. "It was a fantastic result," Paramount's president of domestic marketing and distribution Megan Colligan said in a statement. "I think the movie really surprises people and makes them want to talk about it."
The film faced chagrins before its release. Some religious groups claimed the story had been inaccurately portrayed, prompting Paramount to add a disclaimer to marketing materials saying that "this isn't a literal version of the Bible." There was also a debate whether Paramount would release Aronofsky's preferred cut and whether Russell Crowe got to meet the Pope.
Nevertheless, "Noah" had a fair share of male and female audience as well as major turnout among Christians, Catholic Latinos and African American. "There was a pretty good balance of age ranges but a little bit of an older crowd, which we expected," Colligan said.
Coming second in the weekend box office is last week's champion "Divergent" which generated approximately $26.5 million. One of the newcomers in the list was the biopic "Cesar Chavez". Despite well-reviewed, the film only pulled in an estimated $3 million in its opening weekend, sitting at number 12.
- "Noah" - $44.0 million
- "Divergent" - $26.5 million
- "Muppets Most Wanted" - $11.4 million
- "Mr. Peabody & Sherman" - $9.5 million
- "God's Not Dead" - $9.1 million
- "The Grand Budapest Hotel" - $8.8 million
- "Sabotage" - $5.3 million
- "Need for Speed" - $4.34 million
- "300: Rise of an Empire" - $4.3 million
- "Non-Stop" - $4.1 million
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- Judi Dench Gets Her First Tattoo at Her 81st Birthday
- Keri Russell Reveals Her Baby's Gender and Name
- Debby Ryan Gets Probation After Pleading No Contest to DUI
- Justin Bieber Falls Again on Stage During His Concert


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Museum of Fine Arts
Coolidge Corner Theatre
3 screens
Kendall Theatre
Kendall Square
9 screens
Brattle Theatre
Harvard Square
Embassy Theatre
6 screens
West Newton Cinema
6 screens
'Here are some of the movies I recently saw, and liked and the mini reviews culled from the NYTimes
'Alice Through the Looking Glass' (PG, 1:48) The best, and maybe the only, way to appreciate "Alice Through the Looking Glass" is to surrender to its mad digital excess and be whirled around through time and space in a world of grotesque overabundance. This sequel to Tim Burton's "Alice in Wonderland" is so cluttered with an unwieldy mixture of Victoriana and digital gadgetry that every nook and cranny is crammed with stuff. There's more to gape at than the eye can take in. Otherwise the movie, with its stale inspirational clichés, is a dud. (Stephen Holden)
'The Angry Birds Movie' (PG, 1:37) A superficially amiable ball of fluff based on the spectacularly popular video game. Jason Sudeikis gives voice to an irritable red bird who's suspicious when his homeland is visited by some cheery green pigs. Slapstick, body humor and unsettling possible allegories ensue. (Glenn Kenny)
★ 'A Bigger Splash' (R, 2:04) Tilda Swinton stars in Luca Guadagnino's seductive, reluctant thriller about a rock star, her lover, her former lover and a pretty young thing vacationing under the beautiful Italian sun. Bad things happen, because, you know, life is pain. In the meantime, do enjoy the magnificent digs, the designer threads and the frolicking nude stars. (Manohla Dargis)
'Captain America: Civil War' (PG-13, 2:27) More of a collegial misunderstanding, really, but this episode in the lavish workplace sitcom known as the Marvel Cinematic Universe, in which the Captain (Chris Evans) and Iron Man (Robert Downey Jr.) quarrel about United Nations policy, does have some amusing banter and a few entertaining superhero brawls. (A. O. Scott)
★ 'The Lobster' Colin Farrell and Rachel Weisz star in Yorgos Lanthimos's mordant allegory of managed emotion and mandatory monogamy, set in a chilly, plausibly cruel imaginary world. (Scott)
★ 'Maggie's Plan' Rebecca Miller's new film is a sharp, genial comedy about Maggie, a young New Yorker (Greta Gerwig) who falls in love and starts a family with an older man (Ethan Hawke), after which things get complicated. Ms. Miller's ear for emotional foibles is acute, and the cast is in good form, in particular Julianne Moore as Maggie's rival, a Danish professor. (Scott)
Money Monster George Clooney and Julia Roberts together again. Clooney plays a financial TV persinality ,"Mad Money "style who in the middle of a live broadcast is taken hostage, along with his crew. The ginman (Jack Oconnell) financially ruined by bad investment advice wants explamations and justice. Directed by Jodie Foster.


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Below are top resources on SparkPeople for High Protein Intake.
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We will discuss low carb lifestyles (including Atkins,Protein Power, South Beach and other doctor-recommended low carb plans), trade low carb recipes and team up to do this together!... Read more
For a healthy adult, eating more protein than your recommended daily range once a week or so won't have any major impact on your long-term health or weight loss (assuming you still eat approximately the same amount of calories for the day). Based... Read more
You have most likely heard it said that breakfast is the most important meal of the day. Some research suggests breakfast is an important part of a healthy eating plan that can help you achieve and maintain your best weight. A new study suggests that... Read more


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سکس حیوان و انسان As such, they would not also re-air Miller�s various HBO specials. سکس ایرانی بهنوش Amazingly, this year we are also sharing not only the first name, but both of us are also driving mustangs, and both cars will also rock a similar paint scheme.
سکس ایرانی بهنوش As such, they would not also re-air Miller�s various HBO specials. سکس حیوان و انسان With any luck, this will also be the year for the Ericas Comeback Tour-- Enders taking on the Pro Stock boys, and myself dealing with the Pro Street crowd.
Move your tongue around it, gently sucking and licking.
Hot and Cold Kiss - Lick your partner`s lips so that they`re warm, and then gently blow on them. سکس حیوان و انسان The pitch might originate at an anime studio {like the ones named in the question}.
By this measure, one horse can raise 33 pounds 1,000 vertical feet in a minute, or 330 pounds 100 feet in a minute, or 3,300 pounds 10 feet in a minute, and so on.
سکس ایرانی بهنوش A show getting green-lit depends entirely on the show`s ability to find a sponsor. The piston in a racing engine has a large diameter for the engine size, and it goes up and down a relatively short distance on each cycle. سکس حیوان و انسان The Beatle photo blog has pics of Paul McCartney`s 1976 meeting with comic book genius Jack Kirby.
in whatever way you want, knowing that if the news have changed or if you saved your Newsfeed settings since the last time the script was called, it will return the number of news items you specified with the format you specified.


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Lake On Winter
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Obama list of Historic firsts ….
• First President to Preside Over a Cut to the Credit Rating of the United States Government
• First President to Violate the War Powers Act
• First President to Orchestrate the Sale of Murder Weapons to Mexican Drug Cartels
• First President to issue an unlawful "recess-appointment" while the U.S. Senate remained in session (against the advice of his own Justice Department).
• First President to be Held in Contempt of Court for Illegally Obstructing Oil Drilling in the Gulf of Mexico
• First President to Defy a Federal Judge's Court Order to Cease Implementing the 'Health Care Reform' Law
• First President to halt deportations of illegal aliens and grant them work permits, a form of stealth amnesty roughly equivalent to "The DREAM Act", which could not pass Congress
• First President to Require All Americans to Purchase a Product From a Third Party
• First President to Spend a Trillion Dollars on 'Shovel-Ready' Jobs — and Later Admit There Was No Such Thing as Shovel-Ready Jobs
• First President to sue states for requiring valid IDs to vote, even though the same administration requires valid IDs to travel by air
• First President to Abrogate Bankruptcy Law to Turn Over Control of Companies to His Union Supporters
• First President to sign into law a bill that permits the government to "hold anyone suspected of being associated
with terrorism indefinitely, without any form of due process. No indictment. No judge or jury. No evidence. No trial. Just an indefinite jail sentence."
• First President to Bypass Congress and Implement the DREAM Act Through Executive Fiat
• First President to Threaten Insurance Companies After They Publicly Spoke out on How Obamacare Helped Cause their Rate Increases
• First President to Threaten an Auto Company (Ford) After It Publicly Mocked Bailouts of GM and Chrysler
• First President to "Order a Secret Amnesty Program that Stopped the Deportations of Illegal Immigrants Across the U.S., Including Those With Criminal Convictions"
• First President to Demand a Company Hand Over $20 Billion to One of His Political Appointees
• First President to Terminate America's Ability to Put a Man into Space.
• First President to Encourage Ra
cial Discrimination and Intimidation at Polling Places
• First President to Have a Law Signed By an 'Auto-pen' Without Being "Present"
• First President to Arbitrarily Declare an Existing Law Unconstitutional and Refuse to Enforce It
• First President to Tell a Major Manufacturing Company In Which State They Are Allowed to Locate a Factory
• First President to refuse to comply with a House Oversight Committee subpoena.
• First President to File Lawsuits Against the States He Swore an Oath to Protect (AZ, WI, OH, IN, etc.)
• First President to Withdraw an Existing Coal Permit That Had Been Properly Issued Years Ago
• First President to Fire an Inspector General of Americorps for Catching One of His Friends in a Corruption Case
• First President to Propose an Executive Order Demanding Companies Disclose Their Political Contributions to Bid on Government Contracts
• First President to allow Mexican police to conduct law enforcement activities on American soil
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Russian Troops Protect Secret Biblical Dig In Syria
NASA Finally Find Evidence Of Life On Mars
BERMUDA TRIANGLE: Ship Reappears 90 Years After Going Missing
Researchers Just Found A Huge Underground Helium Pool In Africa
Strike On Power Grid Could Cripple America For A Decade
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How Do You Explain THIS Mandela Effect/CERN Connection??
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White House fence jumper shot, killed in Chester County courthouse w/Photo
A sheriff deputy shot and killed an armed man who had previously scaled the wall of the White House at a suburban Philadelphia courthouse Tuesday in an incident that left a sheriff's deputy injured. Gunshots rang out inside the Chester County Justice Center at 201 W Market St. in West Chester, Pennsylvania shortly before noon Tuesday. Comment?
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We had a wonderful escape to the beautiful laid back island. Anna Maria is rarely mentioned on fodors but is a real gem . The island is seven miles long and consists of three small communities, Bradenton Beach, Holmes Beach, and Anna Maria City., our favorite. There is no building taller than tree stories, most are two, and there are no chain hotels or restaurants. It is a very laid back place without gated communities and with easy welcoming access to beaches both on the Gulf and on Tampa Bay. The beaches have soft white sand; some are large long beaches with facilities; it is equally possible to find isolated stretches with hardly any people
Activities focus on the water. Shore birds abound, On out first afternoon we saw several great blue herons, millions of pelicans, oystercatchers, egrets, ibis, osprey, a wood stork, many of the little shore birds whose names I don't know. dolphins and manatees can be seen and I enjoy watching mullet jump out of the water.
Anna Maria Island, and especially anna Maria, is relatively uncrowded and affords an Old florida vibe.
We rented a cottage on the bay . It was a real treat as the hexagonal shape of the building afforded vast water views from almost every room. We spent our time walking on the beach, swimming in the bay, watching birds, biking around the island, cooking and eating fish at home and out,
exploring many beaches, staring at the sea and the gorgeous Sunshine Skyway bridge, always a presence in the distance Our favorite restaurant is the quirky Mr. Bones, a rib place that also offers Indian inspired rice dishes.
we had not been to AMI for eight years, and, happily, not much has changed. One great addition is the Anna Maria Fish MArket on Holmes Beach, which in addition to excellent fresh fish and shrimp offers excellent salads to go, such as scallop seviche or calamari salad.
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Trip Report Anna Maria Island
We had a wonderful escape to the beautiful laid back island. Anna Maria is rarely mentioned on fodors but is a real gem . The island is seven miles long and consists of three small communities, Bradenton Beach, Holmes Beach, and Anna Maria City., our favorite. There is no building taller than tree stories, most are two, and there are no chain hotels or restaurants. It is a very laid back place without gated communities and with easy welcoming access to beaches both on the Gulf and on Tampa Bay. The beaches have soft white sand; some are large long beaches with facilities; it is equally possible to find isolated stretches with hardly any people
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Great report. I haven't been there yet but it sounds amazing!
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Thanks for the report. We were going to visit AMI for the first time this winter as an alternative to Sanibel where accommodations have gotten so expensive. I was able to find many lovely accommodations that were right on or close to the water--and more affordable than Sanibel. Everyone seems to enjoy the beach there. It looks perfect to me.
We ended up changing our plans when we were invited to a destination wedding in Palm Springs, but we hope to visit next winter. Glad you enjoyed your stay.
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Linda: We love Anna Maria, and were very disappointed in Sanibel. In Anna Maria city, especially, you are so aware of the water everywhere you go and you don't have to pay to park at beaches, which I find much more beautiful. the only thing Sanibel has imo is shelling, and Ding Darling. But actually birds are much more in evidence everywhere in AMI. And since you can rent houses by the week you can not be limited to condos or cottage communities.
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It sounds like an absolutely wonderful and perfect vacation.
Did you catch the sunset at the Sandbar? We used to drive over when working in the area. Would love to go back to relax like you did. Thanks for the trip report.
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AMI is one of my favorite places in Florida (and where many Floridians vacation). It's a great place to kick back and relax. You're right - it is old Florida! Thanks for posting the trip report.
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Oooooooooh! Wish I were there!
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Starrs, Sandbar was always too crowded, but we caught many sunsets on various places on the beach!
yk: me too. we came home to still well over a foot of snow and a big washout in part of our driveway. sigh.
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Thanks for this TR! I'm in Sarasota often visiting my parents and I want to find time to visit AMI. I've heard there's great kayaking. It's definitely on my list.
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What airport is closest to AM? Where is a great place to stay for a family with kids 5 and under?
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I loved reading your report, jubilada. For ages we had family members on Long Boat Key so I have many beautiful memories of Anna Maria Island. It is nice to read it hasn't changed.
The small Sarasota airport would be the closest, signmeup.
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signmeup, although Sarasota airport is definitely closest, Tampa airport is only a little over an hour away and has may more ( and therefore usually cheaper) flight options. Also, you get to drive over the gorgeous Sunshine Skyway bridge, actually worth a trip, IMO.
As to places to stay, it depends on what you like. We prefer to rent our own cottage, there are some condos too, though more in Holmes Beach and Bradenton. We were happy with offerings from Anna Maria Accommodations.
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A great place to eat - just over the Cortez Ave bridge to the mainland in the fishing village of Cortez- is the Starfish Company. http://www.starfishcompany.com/starfishcompany/index.html Also, it's a great place to buy seafood to cook at home. Smoked mullet is a specialty - and my favorite.
Also, if you have a rainy day, go see Snooty the manatee at the South Florida Museum. Snooty is turning 62 or 53 in a couple of weeks - the oldest manatee in captivity. He also has a couple of pool mates who are being rehabilitated and will be released into the wild.
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The United Seamen's Service's 2016 Admiral of the Ocean Sea Awards will be presented to a ferry operator, union leader and a chairman of a classification society at the Sheraton New York Times Square Hotel Oct. 28.
The collision in northern Texas left one injured and three missing Tuesday morning.
The Oakland, Calif. City Council passed an ordinance to ban the storage and handling of coal and coke at bulk terminals in the city, representing the latest blow to Terminal Logistics Solutions' plan for a dry bulk terminal to handle coal and other goods.
Registration takes less than 1 minute.
FedEx Corp. completed its $4.9 billion acquisition of TNT Express and will start integrating the European company into its network immediately.
Pacific Maritime Association President and CEO James McKenna said he expects to hear from International Longshore and Warehouse Union this summer on whether it wants to discuss the extension of the five-year labor contract.
Maritime consultancy Drewry found that approximately 80 percent of shippers won't shift any volume from ocean to air to avoid disruptions caused by the verified gross mass rule scheduled to go into effect July 1.