text:
|Publication number
|Publication type
|Application number
|Publication date
|Jul 5, 1994
|Filing date
|Mar 12, 1993
|Priority date
|Oct 22, 1992
|Fee status
|Also published as
|Publication number
|Huo Yongqing, Wang Zeyu, Wang Yamin, Lu Yukang
|Original Assignee
|China Petro-Chemical Corporation, Research Institute Of Petroleum Processing
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (13), Referenced by (72), Classifications (19), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
0.01-0.30 RE2 O3 . 0.4-1.0 Na2 O . Al2 O3 . 20-60 SiO2,
______________________________________ d(Å) 100 l/lo______________________________________ 11.17 40 10.01 35 9.76 12 7.45 4 7.08 1.5 6.71 6 6.37 8 6.01 11 5.72 10 5.58 10 5.37 3 5.15 3 5.04 5 4.985 8 4.621 6 4.366 10 4.267 13 4.090 5 4.010 9 3.861 100 3.819 74 3.755 41 3.720 49 3.650 28 3.591 7 3.481 29 3.447 13______________________________________
This invention relates to a novel process for the production of high quality gasoline and liquified petroleum gas (LPG) rich in olefins by catalytic conversion of petroleum hydrocarbons, particularly to a process for producing high octane number gasoline with high total yields and LPG rich in propylene and butylene.
Conventionally, propylene, butylene and gasoline are produced by catalytic or thermal cracking of petroleum fractions such as Fluid Catalytic Cracking(FCC) or Pyrolysis processes.
Pyrolysis is aimed at producing ethylene. The gasoline fraction of the product is rich in aromatics and di-olefins with poor quality. Due to its high temperature (beyond 700° C.) cracking, it needs more expensive material for reactor fabrication. Besides, it also needs purification and sophisticated separation of geseous products.
Catalytic cracking can be operated at a temperature much lower than that of pyrolysis, and can produce also low carbon olefins. As an example, in DD152,356 50wt% of C2 ˜C4 olefins are obtained by employing gasoline or vacuum gas oil as feedstock, amorphous silica-alumina as catalyst, in a fixed bed or a moving bed reactor, at reaction temperature of 600°˜800° C. and contact time of 0.1˜1.5 seconds. In Japanese Laid-open application 60-222,428, C5 ˜C25 paraffinic hydrocarbons or naphtha is used as feedstock, ZSM-5 zeolite as the catalyst, under 600°˜700° C. reaction temperature, and LHSV of 20˜300hr-1, around 30 wt% of C2 ˜C4 olefins can be obtained. More examples are described in U.S. Pat. No. 4,980,053 and CN1004878B, which various boiling range of petroleum fractions, residual oil or crude oil are used as feedstocks. A composite of ZSM-5 and rare earth type Y(REY) or ZSM-5 and ultrastable type Y(USY) zeolites are used as catalysts. Using a fluidized bed or moving bed reactor, under 500°˜600° C., 1.5˜3.0×105 Pa, weight hourly space velocity(WHSV) of 0.2˜2.0h-1 and catalyst/oil ratio of 2˜ 12, a total yield of propylene plus butylenes can reach about 40 wt%.
Conventional FCC process can produce up to 50 wt% or more gasoline, but the LPG yield is not more than 8˜13 wt%, in which propylene plus butylene is less than 10% by weight. Moreover, the gasoline octane number can not usually meet the requirement for blending gasoline commodity. For more than ten years, patent literatures reveals that using ZSM-5 additives in combination with catalytic cracking catalyst can enhance a cracking gasoline octane number and increase a yield of alkylates. As described in U.S. Pat. No. 4,368,114, Joliet sour heavy gas oil(boiling range of 212°˜513° C.) was used as feedstock The catalyst composition comprises a mixture of 25% ZSM-5 zeolite-containing additive was added to Super D cracking catalyst(products of Grace-Davison, its composition: 17% RENaY/Clay.SiO2). When the mixture contains 0.1˜0.5 wt% ZSM-5 zeolite in Super D, at the reaction temperature 574° C., WHSV 20hr-1, and catalyst/oil ratio 3, the yield of the obtained C5 + gasoline is 47˜53.7 vol% with research octane number(RONC) of 90.1˜91.4, and the LPG yield was 30.4˜37.1 vol.% in which the yield of propylene plus butylenes are 15.2˜19.6 vol.%. In U.S. Pat. No. 4,522,705, the feedstock is also Joliet sour heavy gas oil as mentioned above. The catalyst is a mixture of HEZ-53 cracking catalyst(product of Engelhard, contains Y zeolite) and a ZSM-5 zeolite-containing additive, the mixture contains 0.25˜2.0 wt% of ZSM-5 zeolite. The reactions are carried out under 515° C., WHSV 15.5 hr-1, yield of C5 + gasoline is 39.5˜46.6 vol.% with RONC of 90.1˜92.0, and propylene plus butylenes are 15.1˜24.2 vol.%. In U.S. Pat. No. 4,818,738, the feedstock is also the same as described hereinbefore. The catalyst is a mixture of REY cracking catalyst and a ZSM-5 zeolite-containing additive, in which it contains 25% of ZSM-5 zeolite, the mixture was prepared in a ratio of additive to REY cracking catalyst of 1:50 by weight. Under the conventional operating conditions of FCC process, the C5 + gasoline yield is 47.5 vol.% with RONC of 90.8, and iC4 +C3 =+C4 =s yield is 23.9 vol.%. In EP 229,609, a gas oil with a boiling range of 204˜538° C. is used as the feedstock. The catalyst is a mixture of a ZSM-5 zeolite-containing additive and Octacat cracking catalyst(active component: 40% of USY, matrix: kaolin clay and silica-alumina sol binder), in which it contains 1.25˜1.5 wt% of ZSM-5 zeolite. Under reaction temperature of 493°˜498° C. C5 + gasoline is 53.1˜55.4 vol.% with RONC of 92.6˜93.0, LPG 19.6˜21.4 vol.%, and propylene plus butylenes 14.8˜14.9 vol.%.
By adding ZSM-5 additives into FCC catalyst, not only enhances the product gasoline octane number, but also increases the yield of propylene and butylenes in LPG. AS described in U.S. Pat. No. 3,758,403, by adding ZSM-5 additive into a cracking catalyst that contains zeolite which has the pore size larger than 7 angstoms to enhance both the gasoline octane number and propylene plus butylenes yield, when the REY cracking catalyst contains 5˜10% of HZSM-5, a gas oil with boiling range of 204°-316° C. is processed at 482°˜486° C., LHSV of 4 hr-1 and catalyst/oil ratio of 1.5, to obtain the mixture of C5 + gasoline plus alkylates with the RON(+3 ml TEL) being 97.3˜98.6, while the C5 + gasoline yield is in the range of 46.4˜55.3 vol.%, the propylene plus butylenes is 19.8˜24.7 vol.%.
The object of this invention is to provide a process using a composite catalyst which contains three kinds of zeolites to catalytically convert feedstocks of the petroleum fractions with different boiling range, resids or crude oils to LPG rich in propylene and butylenes, and high yield and quality of C5 + gasoline.
Further objects of this invention will become apparent by reading the following description and the attached claims.
This invention provides a novel process for the production of LPG rich in C3 =, C4 ='s and high octane number gasoline by catalytically converting hydrocarbons. It comprises contacting the preheated hydrocarbon feedstock converted in a riser or a fluidized bed reactor with a solid asidic catalyst which contains rare-earth-containing high silica zeolite having the structure of a pentasil (hereinafter referred to as ZRP),REY zeolite and high-silica Y zeolite, and then converting the above materials in the reactor under 480°˜550° C. 130˜350 KPa, WHSV of 1˜150hr-1, catalyst to oil ratio of 4˜15, steam to hydrocarbon feedstock ratio of 0.05˜0.12:1 by weight. The spent catalyst after reaction is stripped, and then conducted to a regenerator where the spent catalyst is regenerated by contacting with air. The regenerated catalyst flows back to the reactor and then the regenerator, and reuse circulatively.
(1) Catalyst
Catalyst according to this invention is revealed in another U.S. patent application "A hydrocarbon conversion catalyst for producing high quality gasoline and C3 and C4 olefins" submitted by the same applicant at the same time. The catalyst contains 10˜40 wt% of three kinds of zeolites ZRP, REY and high silica Y as active components, and the rest part is the matrix which is either full silica-alumina synthetic or semi-synthetic that contains natural kaolin or halloysite with 10-40 wt%(based on catalyst) silica and/or alumina as the binders. In total amount of active components, zeolites ZRP, REY and high silica Y are 3˜50, 12˜75 and 12˜75 wt% respectively.
Said ZRP zeolite is a rare-earth-containing high silica zeolite having the structure of a petasil as revealed in US series number 07/820,385 (1992.1.14) or European application series number 92200061.7 (1992.1. 10) by the same applicant. The chemical formula of ZRP (based on the moles of oxides)can be expressed as:0.01˜0.30RE2 O3 . 0.4˜1.0Na2 O. Al2 O3 . 20˜60SiO2 in its anhydrous state, its XRD data are listed in Table 1. The ratio of adsorption of normal-hexane to cyclohexane of ZRP is 2˜4 times of that of HZSM-5, hence its pore size is smaller than that of ZSM-5. The rare earth ingredient of the zeolite originates from a rare earth containing faujasite used as seed in the synthecis of ZRP zeolite. In this invention, it is preferably to use H-form ZRP, with crystallite size of 2-3 microns.
Said REY zeolite is prepared by exchanging NaY with
TABLE 1______________________________________X-ray diffraction patterns of zeolite ZRPZRP H-ZRP*d(Å) 100 I/Io d(Å) 100 I/Io______________________________________11.17 40 11.18 3710.01 35 10.01 409.76 12 9.75 107.45 4 7.44 37.08 1.5 7.09 1.56.71 6 6.72 3.56.37 8 6.37 76.01 11 6.00 115.72 10 5.71 85.58 10 5.58 95.37 3 5.38 25.15 3 5.14 35.04 5 5.05 54.985 8 4.983 84.621 6 4.620 64.366 10 4.369 74.267 13 4.265 124.090 5 4.085 24.010 9 4.010 73.861 100 3.856 1003.819 74 3.817 723.755 41 3.752 363.720 49 3.719 393.650 28 3.652 263.591 7 3.593 43.481 9 3.479 63.447 13 3.447 11______________________________________ *H-ZRP hydrogenexchanged form
rare earth cation, followed by calcination or without calcination. The rare-earth content of the product is 5˜19% as RE2 O3, crystallite size is 0.5˜10 microns, preferably 0.8˜2 microns.
Said high silica Y zeolite can be prepared by various chemical and/or physico-chemical methods, such as hydrothermal processing, acid extraction, framework dealumination and enrichment with silica, SiCl4 treatment, etc., to obtain a stablized product of zeolite Y, in which the Na2 O content should not exceed 4 wt%, preferably less than 1 wt%, unit cell size of the crystal should not exceed 24.5 angstrons, the silica/alumina ratio(molar) lies in the range of 8˜15 or more, the crystallite size 0.5˜10 microns, preferably 0.8˜2 microns.
Said synthetic matrix is an amorphous silica/alumina or silica/magnesia gel containing SiO2 not more than 70 wt% which is prepared by cogellation or step-wise precipitation. To increase the catalyst bulk density, appropriate amounts of clay can be blended with the synthetic matrix composite.
Said semi-synthetic matrix is a composite of clay and binder. Clays such as kaolin or halloysite are conventionally used as matrices of cracking catalysts, and binders such as alumina, silica or silica-alumina in their sol or gel states are used.
(2) The Feedstock
The hydrocarbon feedstocks used in this invention can be petroleum fractions of different boiling range, resids or crude oils. Particularly, they can be straight run fractions including naphtha, light gas oil, vacuum gas oil and resids, etc; mixture of two or more of the above-mentioned materials in any desirable proportion; above-mentioned materials blending with some amount of, preferably no more than 30wt%, coker gas oil, deasphalted oil or other secondary processed fractions.
As the catalyst of this invention can tolerate high nickel content in the feedstock, resids with nickel content up to 15 ppm and heavy oils blending with processed fractions can also be processed.
(3) Process and Operating Conditions
The novel process of this invention is described hereinbelow. Preheated hydrocarbon feed contacts with a solid acidic catalyst which contains ZRP, REY and high silica Y zeolite in a riser or a fluidized bed reactor. Catalytic conversion was carried out under temperatures of 480°˜550° C., preferably 500°˜535° C.; reaction pressure 130˜350 KPa, preferably 130˜250 KPa; WHSV of 1˜150 hr-1, preferably 3˜80 hr-1 ; catalyst to oil ratio of 4˜15, preferably 5˜10. To ensure the effective atomization of the feed, steam or other gases may be injected into and mixed with the feed at a steam to feed hydrocarbon ratio of 0.05˜0.12:1 by weight. The converted products mixed with coke deposited spent catalyst are seperated from each other while it passes through a series of cyclones. The spent catalyst then passes through a stripper where the adsorbed hydrocarbons are stripped off, and then conducted to the regenerator. In the regenerator, coke deposited on spent catalyst is burnt off by contacting with air in the regenerator under temperature of 580°˜730° C., preferably 650°˜700° C. Regenerated hot catalyst comes back to the reactor where it contacts with hydrocarbon feed and then reaction and regeneration takes place repeatedly. Passing through fractionators and adsorption-stabilization system, the products are seperated into H2 ˜C2, LPG, gasoline, light cycle oil and heavy bottom oil. The heavy bottoms or both heavy bottoms and light cycle oil can be converted by recycling back to the reactor.
In this process, the catalyst in an equilibrium state allows 20,000 ppm of nickel or higher.
The operating conditions described hereinabove are for general cases. They can be adjusted as conforming to the feedstock characteristics and expected products yield distribution.
The novel process of this invention is applicable either to a specially designed unit that is similar to conventional FCC unit or by modifying or revamping an existing FCC unit(such as enlargement of LPG seperators, condensers and compressors capacity etc.).
The process provided by this invention can produce high yields of LPG rich in propylene and butylenes, meanwhile produce high yield of gasoline which has enhanced antiknocking ability and stability; and also produce diesel fraction, its quality is compatible to that produced by conventional fluid catalytic cracking process. Riser pilot plant results show the yields(based on feed) as follows: LPG 30˜40 wt%, in which 67˜75 parts by weight are propylene and butylenes (i.e. total yield of propylene plus butylenes amounted to 20˜30 wt%); C5 + gasoline yields 45˜55 wt% with RONC of 91˜95, motor octane number(MONC) of 80˜84, induction period of 500˜1000 minutes and existent gum of 0˜3 mg/100 ml. LPG plus total liquid products are high up to 90 wt%. LPG to H2 ˜C2 ratio on weight basis is up to 8˜13:1.
The examples given below illustrate further the novel catalytic conversion process provided by this invention, but by no means to limit the scope of this invention.
Feedstock properties relating to the following examples are listed in Table 2.
Catalyst A used in the examples was prepared as follows:
1200 grams of alumina hydrogel(Al2 O3 20 wt%) were mixed thoroughly with 950 grams of halloysite clay(solid content 80wt%) as the matrix slurry. In addition, 71 grams of H-ZRP zeolite(prepared according to the procedures of Example 8 described in US series number 07/820,385 or European series number 92200061.7), 214 grams of REY and 143 grams of DASY zeolite(a high-silica Y zeolite prepared by hydrothermal dealumination
TABLE 2__________________________________________________________________________Feed A B C D E F G H*__________________________________________________________________________Density (20° C.), g/cm3 0.8560 0.8871 0.8572 0.8995 0.8672 0.8612 0.8810 0.7893Conradson Carbon, wt % 0.22 0.22 0.17 0.22 3.81 2.12 0.24 0.23UOP K 12.11 12.0 12.1 11.7 11.9 12.6 -- --H, wt % 13.24 -- 13.57 11.70 -- 13.94 12.82 --C, wt % 86.52 -- 85.92 85.95 -- 85.76 86.45 --Basic Netrogen, ppm 420 -- 357 693 -- 600 576 201Ni, ppm 0.49 -- 0.1 3.6 11.3 3.3 0.3 1.6V, ppm 0.03 -- <0.1 <0.1 0.1 <0.1 0.5 <0.1Boiling Range, °C. 319˜504 243˜507 243˜490 224˜482 >308 >291 286˜534 --__________________________________________________________________________ *Paraffinic base crude oil method, SiO2 /Al2 O3 =8˜9) were blended with 514 grams of decationized water to obtain a homogenized slurry. The two slurries described above were mixed, homogenized and spary dried, then washed and flash dryed.
The process provided by this invention was suitable for conversion of gas oil from a variety of crude oils or mixture of gas oils and other processed fractions.
Catalytic conversion was conducted on a bench scale fluidized-fixed bed unit, using catalyst A, with feedstocks of various hydrocarbons listed in Table 3 at 515° C., 130 KPa, WHSV 14 hr-1, catalyst/oil ratio at 8 and steam to feed hydrocarbon ratio 0.07:1 by weight. The results were listed in Table 3.
TABLE 3______________________________________Feed A B D G______________________________________Product Distribution, wt %H2 ˜C2 2.45 2.65 2.76 2.86LPG 32.43 22.82 22.50 29.05C3 ═ 10.30 7.15 6.55 8.02C4 ═ 7.87 5.55 5.19 7.12Gasoline (C5 + ˜205° C.) 46.99 48.43 46.68 42.89205˜330° C. 9.16 13.34 14.74 10.85>330° C. 4.62 7.41 6.98 5.93Coke 5.35 5.35 6.34 8.42Conversion, wt % 86.22 79.25 78.28 83.22______________________________________
The process provided by this invention was suitable for catalytic conversion of various petroleum fractions and crude oils.
Catalytic conversion, using catalyst A contaminated with 3600 ppm of nickel and feedstocks of various kinds of hydrocarbons was carried out on a fluidized fixed-bed bench scale unit at the same operating conditions as described in Example 1. Results were listed in Table 4. The straight run gasoline in Table 4 was the fraction with boiling point below 200° C. and the light gas oil with the boiling range from 200° to 330° C.
The catalyst was artificially contaminated by nickel. The procedures are described as follows:
With catalyst to nickel naphthenate (7.8% of nickel) ratio of 50:2.564 by weight, firstly dissolved 2.564 kilograms of nickel naphthenate into 50 liters of light gas oil. The mixture was pumped into the feeding system at a constant rate for 24 hours, therein contact and react with 50 kilograms of catalyst in the riser reactor. Nickel deposition takes place on the catalyst. Then replaced the mixture by pure feed hydrocarbons was contacted with the catalyst under the same conditions as mentioned above for another 24 hours. Thus, catalyst contaminated with 3600 ppm of nickel was prepared.
TABLE 4______________________________________ Straight Straight Run RunFeed Gasoline Light Gas Oil F E H______________________________________Product Distri-bution, wt %H2 ˜C2 1.74 2.55 2.45 2.45 3.17LPG 29.37 30.96 29.90 27.78 28.63C3 ═ 6.76 7.09 9.32 9.00 8.20C4 ═ 5.39 5.92 7.43 9.73 6.42Gasoline 61.44 38.05 46.52 45.26 42.34(C5 + ˜205° C.) 205˜330° C. 3.29 9.56 8.56 10.75 19.32>330° C. 0.00 3.84 4.45 4.80Coke 4.16 9.12 7.73 11.50 10.31Conversion, 96.71 80.68 86.60 86.99 84.45wt %______________________________________
The process provided by this invention was suitable for catalytic conversion of high nickel content hydrocarbon feeds.
Catalytic conversion, using catalyst A, without or with contamination of 3600 ppm of nickel, was carried out on a riser pilot plant test unit under pressure of 199 KPa and catalyst to oil ratio of 8. Feed E and F with nickel content of 11.3 ppm and 3.3 ppm respectively were used in this example. Results were listed in Table 5.
TABLE 5______________________________________Feed F F E______________________________________Ni on Catalyst A, ppm 0 3600 3600Reaction Temp., °C. 515 514 515WHSV, hr1 73 74 74Steam/Feed (wt/wt) 0.101 0.099 0.100ProductDistribution, wt %H2 ˜C2 3.27 2.86 2.86LPG 35.60 33.91 31.91C3 ═ 11.41 11.17 10.92C4 ═ 13.94 13.51 17.93C5 + Gasoline 44.18 44.52 43.99205˜330° C. 0.35 1.92 2.27Coke 6.05 6.34 9.51Conversion, wt % 89.10 87.63 88.27______________________________________
For the process provided by this invention, the product distribution could be adjusted by changing the operating conditions.
Catalytic conversion, using catalyst A contaminated with 3600 ppm nickel and feed F, was carried out on riser pilot plant test unit mentioned in Example 3 under pressure of 199 KPa and catalyst/oil ratio of 8. The results were listed in Table 6.
TABLE 6______________________________________Reaction Temp., °C. 500 514 529WHSV, hr1 78 74 71Steam/Feed (wt/wt) 0.103 0.099 0.104ProductDistribution, wt %H2 ˜C2 2.25 2.86 4.49LPG 31.69 33.91 36.87C3 ═ 91.72 11.17 13.47C4 ═ 13.10 14.51 15.18C5 + Gasoline 44.85 44.52 41.24>200° C. 16.06 12.37 11.95Coke 5.15 5.34 5.45Conversion, wt % 83.94 87.63 88.05______________________________________
The process provided by this invention was suitable for various moods of operation.
Catalytic conversion, using catalyst A contaminated with 3600 ppm nickel and feed F, was carried out on a riser pilot plant test unit mentioned in Example 3 at 515° C., 130 KPa and catalyst/oil ratio of 8. The results were listed in Table 7.
TABLE 7______________________________________ Bottoms +Operrating Once- Bottoms LCOMood Through Recycle Recycle______________________________________WHSV, hr1 73 74 76Steam/Feed (wt/wt) 0.101 0.105 0.102Product Distribution, wt %H2 ˜C2 2.86 3.17 3.65LPG 33.91 33.70 34.91C3 ═ 11.17 11.20 11.41C4 ═ 13.95 13.63 14.22205˜330° C. 10.41 11.05 -->330° C. 1.63 -- --Coke 6.34 6.74 7.47Conversion, wt % 87.96 88.95 100.00______________________________________
The process provided by this invention cloud produce high yields of LPG, and gasoline with good antiknocking ability and stability.
Catalytic conversion, using catalyst A contaminated with 3600 ppm nickel and various kinds of feed, was carried out on a riser pilot plant as mentioned in Example 3 and also in a fluidized-fixed bed bench scale unit as mentioned in Example 1 at catalyst/oil ratio of 8, different reaction temperatures and various operating moods. The results were listed in Table 8.
For the novel process provided by this invention, the LPG product was rich in propylene, normal-butylenes and iso-butylenes.
Catalytic conversion, using catalyst A contaminated with 3600 ppm nickel and the feed F, was carried out on a
TABLE 8__________________________________________________________________________ Fixed-FluidedTest Unit Riser Pilot Plant Bed Bench ScaleFeed F A C BOperating Bottoms Bottoms + Once- Once- Once- Once- Once-Mood Recycle LCO Recycle Through Through Through Through Through__________________________________________________________________________Reaction Temp., °C. 500 500 515 530 515 530 515Product Distribution,wt %LPG 29.8 32.1 35.6 36.9 32.45 29.4 22.3Gasoline 45.9 54.1 44.2 41.2 47.0 46.1 48.2Gasoline PropertiesRON(C) 92.6 91.4 94.2 93.0 92.7 95.1 93.9MON(C) 80.9 80.7 81.6 81.2 81.2 82.6 82.5Induction Period, min 825 1110 735 525Existent Gum, mg/100 ml 2 2 0 2__________________________________________________________________________
riser pilot plant as mentioned in Example 3 under the pressure of 199 KPa and catalyst/oil ratio of 8. The results were listed in Table 9.
TABLE 9______________________________________Reaction Temp., °C. 500 515 530 500WHSV, hr-1 63 84 81 84Steam/Feed (wt/wt) 0.108 0.099 0.104 0.105Operating Mood Once- Once- Once- Bottoms Through Through Through RecycleC3.sup.═ yield, wt % 9.72 11.17 13.47 9.83C3.sup.═ /LPG, wt % 30.70 32.94 36.53 32.18C3.sup.═ /(C3 ° + C3.sup.═), 86.4 86.1 88.4 84.7wt %Total C4.sup.═ yield, wt % 12.34 12.90 14.51 11.36iC4.sup.═ yield, wt % 3.93 4.67 4.73 4.35C4.sup.═ /LPG, wt % 41.33 39.84 41.17 38.40C4.sup.═ /(C4 ° + C4.sup.═), 64.50 65.30 70.81 62.41wt %______________________________________
Low yield of dry gas was produced by the process provided by this invention.
Catalytic conversion, using catalyst A contaminated with 3600 ppm nickel and the feed F, was carried out on a riser pilot plant as mentioned in Example 3 under the pressure of 199 KPa and catalyst/oil ratio of 8. The results are listed in Table 10.
TABLE 10__________________________________________________________________________Reaction Temp., °C. 500 514 529 500 515WHSV, hr1 78 84 81 87 86Steam/Feed (wt/wt) 0.103 0.099 0.104 0.101 0.102Operating Mood Once- Once- Once- Bottoms + Bottoms + Through Through Through LCO LCO Recycle RecycleProduct Distribution, wt %H2 ˜C2 2.25 2.86 4.49 3.55 3.65LPG 1.69 33.91 36.87 32.69 34.91Gasoline 44.85 44.52 41.24 53.84 53.97LPG/H2 ˜C2 14.1 11.9 8.2 9.2 9.6__________________________________________________________________________
The process provided by this invention produced lower yields of dry gas and coke, higher yields of LPG, propylene and butylenes, and the product gasoline with improved properties as compared with conventional catalytic cracking process which used additives.
For comparesion of the two processes, both catalytic cracking and catalytic conversion referred to by this invention were carried out on the riser pilot plant test unit as mentioned in Example 3 and using feed E. The difference was, that in catalytic cracking, the conventional cracking catalyst LWC-33 blended with additive B was used, while in catalytic conversion, catalyst A was used. The proportion of ZRP in catalyst A was the same as that of ZSM-5 in the mixture of LWC-33 and additive B. The results were listed in Table 11.
Additive B mentioned hereinabove in this example was a composite of HZSM-5, pseudo-Boehmite and halloysite and was prepared by the same procedures of conventional semi-synthetic cracking catalyst through slurrying, mixing, homogenizing, spray drying, etc. The composition could be expressed as: 20% HZSM-5/15% Al2 O3.65% by weight Halloysite.
LWC-33 is a conventional commercial REY catalyst produced by Lan Zhou Refinery.
TABLE 11______________________________________Catalyst A LWC-33 + B______________________________________Reaction Temp., °C. 500 500 520Product Distribution, wt %H2 ˜C2 2.77 3.00 3.61LPG 30.52 20.40 21.49C3.sup.═ 9.80 6.91 7.11C4.sup.═ 11.85 8.42 9.61Gasoline (C5 + ˜205° C.) 45.05 47.40 48.00205˜330° C. 13.14 18.30 16.80>330° C. -- -- --Coke 8.52 10.90 10.10Loss 1.00 -- --Conversion, wt % 86.86 81.70 83.20Gasoline's RON(C) 92.8 -- -- MON(C) 81.5 77.6 79.3Induction Period, min 825 485 421______________________________________
|Cited Patent
|Filing date
|Publication date
|Oct 6, 1970
|Sep 11, 1973
|Mobil Oil
|Olites catalytic cracking of hydrocarbons with mixture of zsm-5 and other ze
|May 31, 1979
|Dec 30, 1980
|Exxon Research & Engineering Co.
|Hydrocarbon cracking catalyst and process utilizing the same
|Mar 19, 1980
|Sep 15, 1981
|Exxon Research & Engineering Co.
|Hydrocarbon cracking with mixture of zeolites Y and ZSM-5
|Jul 22, 1983
|Sep 16, 1986
|Ashland Oil, Inc.
|Carbo-metallic oil conversion catalysts
|Dec 16, 1985
|Apr 14, 1987
|Mobil Oil Corporation
|Production of lubricant range hydrocarbons from light olefins
|Nov 18, 1986
|Dec 29, 1987
|Mobil Oil Corporation
|Organophosphorus-modified zeolites and method of preparation
|May 7, 1987
|Mar 7, 1989
|Union Oil Company Of California
|Process for the catalytic cracking of feedstocks containing high levels of nitrogen
|Feb 17, 1989
|Nov 14, 1989
|Union Oil Company Of California
|Process for the cracking of feedstocks containing high levels of nitrogen
|Jan 6, 1988
|Nov 14, 1989
|Mobil Oil Corporation
|Cracking catalyst
|May 30, 1980
|Dec 10, 1980
|Exxon Research And Engineering Company
|Zeolite-containing hydrocarbon cracking catalyst and hydrocarbon cracking process utilizing same
|Jan 2, 1987
|Jul 22, 1987
|W.R. Grace & Co.-Conn.
|Catalytic compositions
|Dec 17, 1986
|Jul 29, 1987
|W.R. Grace & Co.-Conn.
|Cracking catalyst
|Aug 17, 1987
|Feb 24, 1988
|Mobil Oil Corporation
|Cracking catalyst, its preparation and use
|Citing Patent
|Filing date
|Publication date
|May 14, 1997
|Dec 8, 1998
|Indian Oil Corporation, Ltd.
|Process for catalytic cracking of petroleum based feed stocks
|Oct 3, 1997
|May 18, 1999
|Nippon Oil Co., Ltd.
|Process for fluid catalytic cracking of oils
|Oct 15, 1998
|Apr 3, 2001
|China Petrochemical Corporation
|Catalyst for catalytic pyrolysis process for the production of light olefins and the preparation thereof
|Feb 22, 1999
|Aug 7, 2001
|Stone & Webster Engineering Corp.
|Cat cracker gas plant process for increased olefins recovery
|Nov 9, 1999
|Jan 15, 2002
|Exxonmobil Chemical Patents, Inc.
|Multiple feed process for the production of propylene
|Dec 12, 2000
|Jan 15, 2002
|Chevron U.S.A. Inc.
|Separation of olefins from paraffins using ionic liquid solutions
|Jun 22, 2000
|Jul 9, 2002
|China Petrochemical Corporation
|Catalytic cracking process for increasing simultaneously the yields of diesel oil and liquefied gas
|May 5, 1998
|Aug 6, 2002
|Exxonmobil Chemical Patents, Inc.
|Method for selectively producing propylene by catalytically cracking an olefinic hydrocarbon feedstock
|Nov 3, 2000
|Dec 17, 2002
|Exxonmobil Chemical Patents Inc.
|Carbon dioxide recovery in an ethylene to ethylene oxide production process
|Jun 5, 2001
|Jun 10, 2003
|Stone & Webster Process Technology, Inc.
|Cat cracker gas plant process for increased olefins recovery
|Oct 12, 2000
|Jul 15, 2003
|Exxonmobil Chemical Patents Inc.
|Olefin recovery in a polyolefin production process
|Dec 3, 2001
|Sep 23, 2003
|Chevron U.S.A. Inc.
|Separation of olefins from paraffins using ionic liquid solutions
|Jun 7, 2001
|Dec 2, 2003
|King Fahd University Of Petroleum And Minerals
|Fluid catalytic cracking process for heavy oil
|Apr 29, 2003
|Aug 3, 2004
|Exxonmobil Chemical Patents Inc.
|Production of olefin dimers and oligomers
|Dec 31, 2001
|Feb 1, 2005
|Chevron U.S.A. Inc.
|Separation of dienes from olefins using ionic liquids
|Jan 24, 2002
|Apr 5, 2005
|Exxonmobil Chemical Patents Inc.
|Production of higher olefins
|Sep 30, 2003
|Jun 14, 2005
|Stone & Webster Process Technology, Inc.
|Deep catalytic cracking process
|Feb 25, 2004
|Jun 27, 2006
|Exxonmobil Chemical Patents Inc.
|Process of making polypropylene from intermediate grade propylene
|Jan 14, 2004
|Oct 31, 2006
|Kellogg Brown & Root Llc
|Integrated catalytic cracking and steam pyrolysis process for olefins
|Mar 22, 2004
|Jul 3, 2007
|Exxonmobil Chemical Patents Inc.
|Olefin oligomerization
|Aug 4, 2003
|Sep 25, 2007
|Stone & Webster Process Technology, Inc.
|Process and apparatus for controlling catalyst temperature in a catalyst stripper
|Feb 22, 2005
|Jun 3, 2008
|Exxonmobil Chemical Patents Inc.
|Production of higher olefins
|Jun 27, 2007
|Jul 29, 2008
|Equistar Chemicals, Lp
|Hydrocarbon thermal cracking using atmospheric distillation
|Mar 21, 2005
|Jan 20, 2009
|Stone & Webster Process Technology, Inc.
|Deep catalytic cracking process
|Aug 11, 2006
|Feb 17, 2009
|Kellogg Brown & Root Llc
|Dual riser FCC reactor process with light and mixed light/heavy feeds
|May 19, 2004
|Jun 15, 2010
|Petroleo Brasileiro S.A. - Petrobras
|Process for the fluid catalytic cracking of mixed feedstocks of hydrocarbons from different sources
|Feb 8, 2011
|Kellogg Brown & Root Llc
|Recycle of olefinic naphthas by removing aromatics
|Jun 30, 2005
|Mar 6, 2012
|Uop Llc
|Protection of solid acid catalysts from damage by volatile species
|Dec 15, 2009
|Nov 13, 2012
|Stone & Webster Process Technology, Inc.
|Method for contaminants removal in the olefin production process
|Mar 13, 2009
|Dec 3, 2013
|China Petroleum & Chemical Corporation
|Process for converting inferior feedstock to high quality fuel oil
|Mar 12, 2008
|Dec 17, 2013
|Kellogg Brown & Root Llc
|Systems and methods for residue upgrading
|Aug 7, 2008
|Apr 15, 2014
|China Petroleum & Chemical Corporation
|Catalytic conversion process
|May 7, 2012
|Dec 30, 2014
|Exxonmobil Chemical Patents Inc.
|Process for the production of xylenes and light olefins
|May 7, 2012
|Jan 20, 2015
|Exxonmobil Chemical Patents Inc.
|Process for the production of xylenes
|Mar 23, 2011
|Aug 11, 2015
|Saudi Arabian Oil Company
|Integrated hydrocracking and fluidized catalytic cracking system and process
|Mar 23, 2011
|Aug 11, 2015
|Saudi Arabian Oil Company
|Cracking system and process integrating hydrocracking and fluidized catalytic cracking
|May 7, 2012
|Nov 10, 2015
|Exxonmobil Chemical Patents Inc.
|Process for the production of xylenes and light olefins
|May 7, 2012
|Nov 10, 2015
|Exxonmobil Chemical Patents Inc.
|Process for the production of xylenes and light olefins
|May 23, 2013
|Mar 15, 2016
|Saudi Arabian Oil Company
|Catalyst for enhanced propylene in fluidized catalytic cracking
|Dec 20, 2001
|Jul 11, 2002
|Michelin Recherche Et Technique,
|Assembly consisting of a tire, a rim and an adapter
|Dec 31, 2001
|Jul 3, 2003
|Boudreau Laura C.
|Separation of dienes from olefins using ionic liquids
|Feb 1, 2002
|Aug 7, 2003
|Tapia Alejandro L.
|Housing assembly for providing combined electrical grounding and fiber distribution of a fiber optic cable
|Apr 29, 2003
|Dec 4, 2003
|Georges Mathys
|Production of olefin dimers and oligomers
|Sep 30, 2003
|Apr 1, 2004
|Warren S. Letzsch
|Deep catalytic cracking process
|Jan 24, 2002
|Jul 8, 2004
|Martens Luc R.M.
|Production of higher olefins
|Mar 22, 2004
|Dec 2, 2004
|Mathys Georges M.K.
|Olefin oligomerization
|Aug 4, 2003
|Feb 10, 2005
|Warren Letzsch
|Process and apparatus for controlling catalyst temperature in a catalyst stripper
|Jan 14, 2004
|Jul 14, 2005
|Kellogg Brown And Root, Inc.
|Integrated catalytic cracking and steam pyrolysis process for olefins
|Mar 21, 2005
|Jul 28, 2005
|Letzsch Warren S.
|Deep catalytic cracking process
|Feb 22, 2005
|Aug 18, 2005
|Martens Luc R.
|Production of higher olefins
|Feb 25, 2004
|Aug 25, 2005
|Van Egmond Cor F.
|Process of making polypropylene from intermediate grade propylene
|May 19, 2004
|Jul 27, 2006
|Baptista Claudia Maria De Lace
|Process for the fluid catalytic cracking of mixed feedstocks of hydrocarbons from different sources
|Jun 30, 2005
|Jan 4, 2007
|Voskoboynikov Timur V
|Protection of solid acid catalysts from damage by volatile species
|Aug 11, 2006
|Feb 14, 2008
|Kellogg Brown & Root Llc
|Dual riser FCC reactor process with light and mixed light/heavy feeds
|Nov 7, 2007
|Jun 5, 2008
|Saudi Arabian Oil Company
|Advanced control of severe fluid catalytic cracking process for maximizing propylene production from petroleum feedstock
|Mar 12, 2008
|Sep 18, 2008
|Anand Subramanian
|Systems and methods for residue upgrading
|Nov 6, 2008
|Apr 16, 2009
|Saudi Arabian Oil Company
|Automation and Control of Energy Efficient Fluid Catalytic Cracking Processes for Maximizing Value Added Products
|Feb 28, 2008
|Sep 3, 2009
|Alan Claude
|Recycle of olefinic naphthas by removing aromatics
|Aug 7, 2008
|Aug 26, 2010
|China Petroleum & Chemical Corporation
|catalytic conversion process
|Sep 16, 2010
|Saudi Arabian Oil Company
|Control of Fluid Catalytic Cracking Process for Minimizing Additive Usage in the Desulfurization of Petroleum Feedstocks
|Mar 13, 2009
|Jan 6, 2011
|China Petroleum & Chemical Corporation
|process for converting inferior feedstock to high quality fuel oil
|Jun 16, 2011
|Van Egmond Cornelis F
|Method for contaminants removal in the olefin production process
|Oct 15, 1998
|Apr 21, 1999
|China Petrochemical Corporation
|A process for production of ethylene and propylene by catalytic pyrolysis of heavy hydrocarbons
|Nov 13, 1997
|Jun 16, 1999
|INDIAN OIL CORPORATION Ltd.
|Process for the production of high yield of LPG and light olefins
|Aug 7, 2008
|Jan 27, 2016
|China Petroleum & Chemical
|A process of catalytic conversion
|Mar 30, 2011
|Oct 6, 2011
|Indian Oil Corporation Ltd
|A process for simultaneous cracking of lighter and heavier hydrocarbon feed and system for the same
|Jul 25, 2012
|Feb 7, 2013
|Saudi Arabian Oil Company
|Integrated selective hydrocracking and fluid catalytic cracking process
|Oct 11, 2012
|Apr 18, 2013
|Indian Oil Corporation Ltd.
|A process for enhancing nickel tolerance of heavy hydrocarbon cracking catalysts
|Mar 20, 2013
|Sep 26, 2013
|Saudi Arabian Oil Company
|Integrated hydroprocessing, steam pyrolysis catalytic cracking process to produce petrochemicals from crude oil
|Jul 23, 2013
|Jan 30, 2014
|Indian Oil Corporation Limited
|Catalyst composition for fluid catalytic cracking, process for preparing the same and use thereof
|Dec 2, 2014
|Jun 11, 2015
|Saudi Arabian Oil Company
|Integrated solvent-deasphalting and fluid catalytic cracking process for light olefin production
|May 22, 2015
|Nov 26, 2015
|Saudi Arabian Oil Company
|Framework substituted zeolite catalyst for fluidized catalytic cracking and method for fluidized catalytic cracking
|U.S. Classification
|208/120.15, 502/65, 208/120.01, 502/67, 208/122
|International Classification
|Cooperative Classification
|European Classification
|Mar 12, 1993
Owner name: CHINA PETRO-CHEMICAL CORPORATION AND RESEARCH INST
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:YONGONG, HUO;ZEYU, WANG;YAMIN, WANG;AND OTHERS;REEL/FRAME:006470/0979;SIGNING DATES FROM 19930224 TO 19930225
|Sep 30, 1997
|Fee payment
Year of fee payment: 4
|Jan 4, 2002
|Fee payment
Year of fee payment: 8
|Jan 30, 2002
|Maintenance fee reminder mailed
|Jan 3, 2006
|Fee payment
Year of fee payment: 12


text:
View More Photos
hotel reviewsbased on 808
Hotel freebies include Free Breakfast and Free Parking
The Cedarbrook Lodge is widely regarded as one of the premier hotels in Seattle. Located less than five minutes from the Sea-Tac International Airport, it is a superb choice for business travelers to the area. Guests rave about... more
Ranked #1 of 10 Best Hotels in Seattle
or book with

subset: commoncrawl


text:
This clip on promotional book light is the perfect promotional gift for all the book worms on your list.
Everyone will notice your company logo on this unique custom notebook that features a clear window ID pouch.
This paper surface promo mouse pad doubles as a 50 sheet non-adhesive writing pad with non-slip chipboard backing.
A custom magnet is the perfect way to keep your logo displayed everyday!
Take a bite out of success with this apple shaped magnetic power custom imprinted clip!
A custom magnet is the perfect way to keep your logo displayed everyday!
A fun and stylish specialty promo magnet in the shape of a teddy bear.
This attention getting postcard with custom business card magent is a practical and cost efficent way to market your brand!
The slanted top gives added depth and highlights to this custom paperweight.
This recycled cardboard custom journal book features a hand sewn binding that gets back to the roots of your eco-message.
Imprinted coupon holder with a magnetic strip attached to the back.
An apple a day keeps your logo in play - Imprinted Sticky Notes by BIC.
An efficient way to clip notes to refrigerators or filing cabinets with our personalized clip.
You will turn any drab and boring workspace into a breath of fresh air with this vibrant custom desk accessories set imprinted with your full color logo.
Add some bold color to your office workspace with this vibrant desktop custom stapler imprinted with your logo.
Show how much you care with this heart shaped promotional magnet.
The perfect promo magnet, with big solid imprints!
Unique custom business card magnet will display your logo on their fridges and cabinets all day!


text:
- Overcast, mist
- Temperature: 53 °F
Mon, 06/27/2016 - 06:53
- Overcast
- Temperature: 51 °F
Mon, 06/27/2016 - 06:35
Crescent City
- Overcast, mist
- Temperature: 53 °F
Mon, 06/27/2016 - 06:56
Crescent City
Yesterday we told you about three candidates vying for the Eureka City Manager position. That number has now been pared down to one.
The finalist is from out of the area and the city is still awaiting a background check. An official announcement could be made as soon as tomorrow. The search began after former city manager Bill Panos resigned in October to take a job with the Wyoming governor's office.


text:
Anurag Kashyap adds `Bachchan anthem` in `Bombay Talkies`
Mumbai:Filmmaker Anurag Kashyap`s short story in `Bombay Talkies` will have a special song, a kind of tribute to megastar Amitabh Bachchan, who has been regaling Indian audiences for four decades. The song can, in fact, be called the `Bachchan anthem`.
"Amitabh Bachchan is an icon in the film industry and has given blockbuster memorable films as his body of work. The song will have a lot of kids, dressed in different avatars donned by Big B over the years in his movies," said a source associated with the project.
The lyrics of the song go like this - "Sitaaron ki shaan hai jo, vo Bachchan, cinema ka imaan hai jo, vo bachchan, reelon se dilon tak, aya re aya re... chhaaya re, bachcha bachcha gaaye, from bachpan bachpan."
The video of the song, composed by Amit Trivedi, will feature children dancing with several of Amitabh`s stills from his iconic films in the backdrop. The video is choreographed by Remo D`Souza.
`Bombay Talkies` is co-directed by four directors, including Kashyap, Karan Johar, Zoya Akhtar and Dibakar Banerjee. The four directors have put together four short stories to make one project. The film is slated to release May 3.
More from India
More from World
More from Sports
More from Entertaiment
- Do you know what is the FIRST thing Salman Khan asks when he meets someone? Click here
- Katrina Kaif or Jacqueline Fernandez – Who will be chosen by Salman Khan?
- Hrithik Roshan escapes Istanbul attacks, reaches India safely!
- Elli Avram looks red HOT in this latest picture!
- Priyanka Chopra spills the beans about Deepika Padukone's next Hollywood venture!
- Ranbir Kapoor to do a cameo in Shah Rukh Khan – Anushka Sharma starrer?
- Katrina Kaif or Jacqueline Fernandez – Who will be chosen by Salman Khan?
- Priyanka Chopra spills the beans about Deepika Padukone's next Hollywood venture!
- Disappointment for Ranbir Kapoor; Sanjay Dutt biopic delayed? Details inside
- 'Rustom' POSTER: Akshay Kumar's intense act will leave you asking for more!


text:
Relevant offers
This Anzac Day will mark the 97th commemoration since the Gallipoli landings and the 90th anniversary of the Poppy Day Appeal.
The 2012 Poppy Appeal began on Monday and the street collection is today.
Money raised will go to RSA organisations across New Zealand to support their work with veterans as well as ex-servicemen and women and their dependants.
RSA chief executive Dr Stephen Clarke says the first Poppy Appeal was held in 1922 and since then the annual appeal has only grown.
A total of $1.7 million was raised in 2011 and Dr Clarke says it remains the most important source of support and funding for the RSA movement across the country.
"All the money raised locally is spent locally – so money raised in a community is spent on the welfare needs of ex-servicemen and women in that community.
"The history of poppies as a mark of respect and remembrance is a remarkable one which goes back to World War I and the work of Madame Guerin on behalf of the victims of war in northern France," Dr Clarke says.
The first poppies distributed in New Zealand were manufactured by French war widows and the staging of the first Poppy Appeal in 1922 makes it one of the longest continuing appeals held annually in this country.
- Auckland City Harbour News
Sponsored links
Boxing legend David Tua fronts Onehunga Park Up For Homes event
Police sting catches four outlets selling booze to minors
Auckland's new bus network gets the tick of approval
Auckland Zoo puts out call for baby capybara name suggestions
Auckland councillor concerned over Freyberg Square redevelopment
Ram-raids force dairy owners to sleep on floor of east Auckland shop
Untold story of Jane Furlong subject of new book
Flagship Auckland creek redevelopment program set to begin
Eat My Lunch founder recognised by former school
New Zealand's refugee quota is 'embarrassingly small'
Central and East Auckland's bus routes up for approval
Eden premier rugby shaping up to defend Portola Cup
Auckland circus school offers scholarships
New Zealander dies after being hit by truck in California
Ram-raids force dairy owners to sleep on floor of east Auckland shop
First home buyer angry after Auckland property developer hikes costs by 20 per cent
Zilda Williams strips back the botox, boob jobs and touch-ups of glamour modelling
Taupaki School principal moving on
Auckland Zoo puts out call for baby capybara name suggestions
Digger truck driver pleads not guilty over Auckland overbridge crash
Nikon Auckland Photo Day 2016 winners announced
Police sting catches four outlets selling booze to minors
Police arrest seventh person connected to Northland meth bust
Are our classrooms becoming overcrowded?


text:
Portugal defeated Croatia, reaching Euro 2016 quarter finalsSport June 26, 1:51
Jabhat al-Nusra group impeding ceasefire in Syria - Russia's reconciliation centerWorld June 26, 1:50
Brexit makes EU's disintegration practically inevitable, says SorosWorld June 25, 23:01
Finland collecting signatures for referendum on leaving EUWorld June 25, 22:56
Snowden criticizes Russia's new package of antiterrorist lawsSociety & Culture June 25, 22:53
Pope Francis I wishes normalizartion of relations to Armenia, TurkeyWorld June 25, 21:32
Wales beats Northern Ireland, reaches Euro 2016 quarter finalsSport June 25, 21:31
Russia, China sign deal to cooperate in building heavy helicopterBusiness & Economy June 25, 20:46
Putin: Russia, China have common approach to international, regional problemsRussian Politics & Diplomacy June 25, 18:13
{{element.title}}{{element.heading}} {{element.date}}
MOSCOW, March 12. /TASS/. Russia's federal drug control service (FSKN) has briefed its US counterparts on more than one thousand drug traffickers operating in the United States.
According to a news release published on the FSKN website, FSKN detectives had gathered evidence exposing hundreds of dealers operating in the US in last summer's large-scale anti-drug operation against a trans-national crime syndicate.
"The operation eliminated a large trans-national crime ring whose members had created a large network to mail synthetic drugs from Southeast Asia to destinations around the world, including the European Union, the United States, Canada, Australia, New Zealand, Japan and other countries," the FSKN said in the news release.
The crime network incorporated some 10,000 dealers in 47 countries, including 1,103 in the United States. Orders were accepted through on-line shops in China, which offered more than 30 types of most widely used narcotics.
"The investigation has found that about 8,000 'regular clients' were registered at the drug traffickers' websites. Since the beginning of 2011 this crime ring dispatched 5,195 drug parcels to the United States using the DHL mailing service.


text:
It's a tee. It's a dress. It's the new Graphic T-shirt Dress.
calendars reflections venice italy water marine boats
great calendar
Thank you!
The calendar is beautiful, have a great sensitivity June :) I believe that I will like to have it nearby…
BEAUTIFUL! A lovely calendar June, well done.
I got the calendar, it is very very beautiful :)Grazie June
So glad it finally arrived and you're pleased with it!! :-)
I like September & November.Stunning calendar.
Nice theme.
10% off
for joining the Redbubble mailing list
Receive exclusive deals and awesome artist news and content right to your inbox.
Free for your convenience.


text:
Shorts amateur teensTeen amateurs get sexual experience fucking hard in various positions
Babes chubby fingeringBlonde lesbians please each other with skillful pussy drilling
Blondes fingering fishnetBitchy blonde in fishnet stockings pees and gets cunt fisted
Big tits fisting high heelsLesbian brunette drills pussy with a dildo and enjoys deep fisting
Blowjob deepthroat miniskirtMilf Gives Friend A Nice Warm Friendly Bj
Babes blondes blowjobFunny pigtailed babe with blond hair licks cock and gives a ride
Outdoor brunettes upskirt18 year old teen goes to a forest to masturbate freely
Amateur babes blowjobSkinny amateur babe Flora with tiny tits gives a hot mouth job
Mature granny mature amateurWicked granny wishes to get banged with strapon
Asslicking rimjob rimmingSluts Love Giving Rimjobs To Lucky Studs
Amateur hot ass blowjobPetite teen plays with massive cock and gives a handjob
Brunette long hair pantiesBreathtaking sweetheart Ferrera Gomez spurts her satin nightie to give her pulsating cunt true r
Big tits blonde blowjobStunning Blonde Agrees To Give Best Friend A Bj On Couch
Amateur german maturesMature whore forced drinking and sucking cock!
Blowjobs grannies maturesGranny Knows How to Give a Blowjob
Pornstar deepthroat blowjobCassandra Nix and Jessie Andrews enjoys to give oral!
Bisexual femdom bizarreWife uses a buttplug to give her husband anal pleasure
Sclip hazeher comFreshman pledges forced to suck cock
Glasses older grandOld woman forced to suck
Blowjobs redheads teensSweet 18yo knows how to give blowjob
Big tits blowjob milfsTv Hosts Show How To Give The Best Head To Their Guests
Anal blowjobsAss to Mouth & Rimjob
Blonde blowjob ffmNasty Threeway With Blond That Gives Rimjob And Takes Anal
Blonde blowjob homemadeHomemade Flick Of Kinky Blond Blowing And Giving Rimjob
Handjob hospital nurseThree Hot Asian Nurses Demonstrate How To Give Handjob
Blowjobs hardcore babysittersBabysitter Forced to Fuck Husband By Wife...TOHT
Babe milf pornstarHow To Make A Homemade Porno: Part One
Amateur brunette handjobMature Slut Loves To Give Hand Jobs
Bdsm masturbation sex toysLily is forced to Cum
Big ass ebony interracialLots Of Bust And Bootie To Give To A White Cutie
Anal blowjobs titsTied up and force to fuck
Amateur bdsm blowjobsDIVORCED MOM GETS STONED..FORCED TO LICK ASS
Blowjobs cumshots milfsForced to suck
Blowjobs teens vintageGirls Learn How To Give A Blowjob
Anal bdsm lesbiansTied & Forced to Eat Ass She just want to get her picture take.
Deepthroat rough bondageBlonde sex slave tied with her hands behind forced to suck cock i
Blondes pigtails hardcoreBlonde cutie Jenny learns to give services to two guys
Rimjob blowjob milfHot brunette milf gives rimjob and blowjob
Threesome blowjob collegeMom shows daughter how to give some head to a firm pipe
Big tits brunette milfSpectacular chinese honey Kayme Kai disrobes down in front of the camera to give her twat some s
Amateur bdsm facialsSUBMISSIVE WIFE FORCED TO SUCK NEIGHBOR
Teenager kinky bdsmSkinny tattoo girl forced to masturbation
Bra close up cowgirlSweeties train to give a handjob using some lubricants
Big tits spankingBusty babe tied and forced to fuck doggystyle in extreme bondage
Public sex deepthroatBusty delicious blonde immobilized and forced to fuck in public g
Public sex groupSexy delicious sex slave abused and forced to fuck in immense pub
Babes bdsm dominationRoped woman forced to orgasm
Public sex outdoorSlut with tiny tits forced to undress in public and humiliated in
Kinky roped andRoped and forced to masturbation
Public spanking bondageBusty brunette tied with and on bdsm devices then forced to fuck
Anal sex assBeautifull patient with large breasts forced to fuck in brutal an
Car pov (point of view) realityPretty Older Woman Shows How To Give Head In A Car
Femdom bondage bdsmMan sex slave in middle of mistress ritual is forced to fuck in s
Babes blowjobs hardcoreRedhead forced to suck
Bdsm domination kinkyTeased and denied then forced to cum
Lesbian licking officeBoss Demands Her Employee To Give In To Her Lesbian Desires
Bisexuals femdom interracialCuckold's Girlfriend Fucks a Black Guy Guy is forced to watch his girlfriend get fucked by a
Blowjob doggystyle lickingBlonde Bomb Shell Bends To Gives Oral Pleasure
Bdsm lesbians spankingForced Lesbian Orgasm
Amateur blowjobs teensRedhead Teen forced to fuck to pay back lost money
Sclip hazeher comSorority girls forced to eat pussy for 1st time
Strap-on college femdomMischa has plenty of chisel to give with her strapon.
Haze hazing teenStraight frat pledges forced to suck cock
Big tits deepthroat blowjobAdrianna Nicole, Dana DeArmond enjoys to give fellatios!
Busty big boobsShe begs him to give her a baby
Bisexuals blowjobs femdomHubby forced to suck cock
Long hair hardcore thongsStellar Brooklyn Daniels gives her paramour a lengthy slow bj then rises to give him a stiffie r
Cumshots handjobs old + youngMom teaches how to give perfect tugjob
Blowjob group orgy pornstarHasty rail to the Top
Amateur homemadeBlond Girl Give A Blowjob Then Gets Eaten Out At A Spa
Amateur pov (point of view) publicHot Blonde Loves To Get Naughty In Public Places
Anal big tits blondesTopnotch blonde model Lea Lexis drills her oiled butthole
Hardcore stockingsPromiscuous Sable rails a large hard latino man-meat for sensation.


text:
14 Years Ago: Blake Shelton Scores First No. 1 Hit With 'Austin'
Fourteen years ago today (Aug. 11, 2001), Blake Shelton scored his first No. 1 hit with his debut single, "Austin."
Fourteen years ago today (Aug. 11, 2001), Blake Shelton scored his first No. 1 hit with his debut single, "Austin."
Twelve years ago today (Aug. 9, 2003) was a big day for Alan Jackson. It was on this day that his duet with Jimmy Buffett, "It's Five O'Clock Somewhere," hit the top of the charts, where it stayed for eight weeks.
Before Mike Myers became synonymous with the green ogre named Shrek, his fellow SNL castmate Chris Farley was actually cast in the role and had recorded about 80-90% of his dialogue. Then, in 1997, Farley tragically died of a drug overdose, DreamWorks was forced to recast the role and, in doing so, radically rethink their version of Shrek. Today, the first footage of Farley as Shrek has popped up online and shows a very different character than the one we have come to know and love.
Tonight at 8:00 on KMOS-TV-JFK and LBJ: A Time for Greatness on KMOS-TV.
President LBJ is chiefly remembered for the Vietnam War. But 50 years ago, he engineered two of the most important laws Congress ever passed, the 1964 Civil Rights Act and the 1965 Voting Rights Act...
A public visitation and funeral for singer Lynn Anderson will take place this week in Nashville. The 67-year-old "(I Never Promised You a) Rose Garden" singer died on Thursday (July 30) in Nashville after suffering a heart attack. She'd been battling pneumonia.
Sixteen years ago today (Aug. 3, 1999) was a bittersweet day for the friends and family of Patsy Cline. It was on this day that the singer was posthumously awarded a star on the Hollywood Walk of Fame, in honor of her many career achievements.
Join KMOS-TV for two new specials about the Atomic Bomb
Tonight at 7:00 KMOS-TV presents The Bomb in commemoration of the 70th anniversary of the detonation of the atomic bomb...
What is the greatest American film of all time? According to BBC.com, who just released a brand new ranking of more than a century of great U.S. cinema, the old favorites are still the best; perennial pick for best film ever, Orson Welles' Citizen Kane, came in first in a poll of "62 international film critics ... from the United Kingdom and continental Europe to South America, Australia, India, and the Middle East" and the United States as well.


text:
Out of Stock
- Earn 1% back on qualifying purchases
- The more you shop, the more your earn
- Use your points for great HobbyTron deals
- Bonus points on special promotions
Ships Tomorrow!
4 Rating (1 Customer Reviews)
Similar Products
Electric CYMA CM047C AK74M Rifle FPS-450 Full Metal, Folding Stock Airsoft Gun
Save: $75.05 (36%)
CYMA CM039C Tactical AK-47 FPS-475 Electric Airsoft Rifle
Save: $77.05 (31%)
CSI M4 Commando FPS-470 Electric Airsoft Rifle
Save: $60.05 (30%)
CYMA CM028C AK-47 Rifle FPS-420 Electric Airsoft Gun
Save: $80.04 (32%)
Umarex H&K MP5 A4 Competition FPS-395 Electric Airsoft Rifle
Save: $16.00 (10%)
Umarex Tavor TAR-21 LE DST FPS-345 Electric Airsoft Rifle
Save: $89.00 (34%)
Cybergun Kalashnikov Spestnaz AK-47 FPS-485 Electric Airsoft Rifle
Save: $70.04 (30%)
G&G Combat Machine R16 Raider FPS-430 Electric Airsoft Rifle
Save: $60.05 (29%)
Mini 101 M16 Automatic FPS-180 Electric Airsoft Rifle
Save: $13.04 (43%)
Electric M4 ZM81B FPS-280 Airsoft Rifle
Save: $44.97 (38%)
Thompson M1A1 Military FPS-466 Electric Airsoft Rifle
Save: $100.04 (34%)
AK-47 FPS-300 Electric Airsoft Rifle
Save: $50.05 (33%)
Electric D2802 M4 FPS-220 Airsoft Rifle
Save: $32.57 (43%)
Well D2811 UZI FPS-195 Electric Airsoft Rifle
Save: $35.00 (41%)
FirePower M4A1 FPS-220 Electric Airsoft Rifle
Save: $110.04 (79%)
This replica of the HK UMP was seen used in the Matrix Trilogy films and looks and feels like the real thing. The gun will chronograph at over 350fps, has an all metal design and the clip contains a brass inlay that makes it look like you are shooting real ammunition. The gun comes with a bottom-mounted RIS rail that can be used for your favorite tactical light or red dot laser. Also has an adjustable hop-up system.
- All Metal Replica Design
- Extremely High Rate of Fire
- Metal Barrel and Gears
- Star UMP AEG Rifle
- Clip
- Battery and Charger
- Professional Hard Case
- Magazine Capacity: 110
- Size: 13.5 Inches
Electric Airsoft Rifles use batteries as their power source, they're usually fully automatic, and they shoot very fast. If you are looking for continuous fire fun, this is the type of Airsoft Gun for you - just hold down the trigger and watch those BBs stream out, one after the other, in a straight, swift line - which means fun and entertainment, plain and simple. This Electric Airsoft Rifle doesn't require any pumping just simply point and shoot.
For questions regarding this product please email our friendly customer service team.
Customer Reviews
Overall Raing: 4 out of 5 stars
Top Customer Reviews
By: Joey 06-20-2012
this gun is the best gun i have ever owned full steel all around a great gun except the fire rate it sucks my ***** it is like i can walk faster than this ***** fire rate get a red dot on it but not from this sight go to airsoftgi.com but this is the highest quality for a good price best ump ive ever seen
Call our Customer Service at 818-675-9000 if you find a lower price on any of our items we'll match it.*
Need Help? Call our Customer Service Team at 818-675-9000. They can help with any questions you may have.
- Your Stuff
- Your Account
- Order Status
- Rewards Program
- Wish List
- Refer A Friend
- #HobbyTronFan
- Giveaways
- Customer Service
- Contact Us
- Order Status
- Policies
- Testimonitals
- Learn
- Blog
- Videos
- Learning Center
- HobbyTron.com
- Daily Deals
- Coupons
- Affiliate Program
- Wholesale
- Site Map


text:
Avenue Q: The Irreverent Adult Puppet Musical at Bus Barn Theater
* Additional fees apply. No coupon or promo codes necessary to enjoy the displayed discount price.
The last date listed for Avenue Q was Thursday June 13, 2013 / 8:00pm.
Most Popular Theater Event Nearby
Roundabout Theatre Company's Cabaret: Broadway's Decadent Hit Musical
- Full Price:
- $55.00 - $110.00
- Our Price:
- $40.00 - $65.00
Step out of the modern world and into the glittering underworld of pre-WWII Berlin to join the fun… More
Venue Details
Reviews & Ratings
Featured review from Kim
view more less of this review
So funny! These dirty little puppets will have you laughing!
star this review starred report as inappropriate
This is a wonderful production and should not be missed. The singing is excellent and the actors really know how to make their muppet style puppets come to life. While it is "adult" the use of profanity and adult themes is done tastefully and...continued
star this review starred report as inappropriate
Fabulous production from beginning to end!
star this review starred report as inappropriate
Small intimate theater put on a great production. Can't go wrong for the price.
The show contains mature language and content.
About the Ticket Supplier: Los Altos Stage Company
The mission of the Los Altos Stage Company is to engage the community and artists in creating and experiencing intimate, professional-quality theater.


text:
Sometimes you call your Masseuse because you want a feel-great massage. I have been dealing with chronic pain lately and I called the right company. I can actually feel my body back in alignment. I feel great! Christopher
Dallas Oriental Massage
1. Lasting Lines Clinic & School
Went to see Renee today for mole removal. The office was super clean and she was very nice and welcoming. I am already pleased with my results and a…
2. Clifford Pain Relief Chiropractic
Dr. Clifford and his staff are consummate professionals. I have been going for help with my migraine headaches and several other back, neck and sho…
3. Clinical Therapeutic MassageServices
Janet is Amazing. She has a kind personality and her massage worked for me. She gave me the massage my body needed to prepare for surgery and to hea…
4. Southwest Center Physical TherapyServices
7338 S Westmoreland RdDallas, TX 75237
5. Trinity Mills ChiropracticServices
Dr. Harris is really, really a Great chiropractor. I've been to many chiropractors before, but he really has great hands, and he is warm and caring…
6. Fitzpatrick Acupuncture of DallasServices
12740 Hillcrest Rd Ste 125Dallas, TX 75230
From Business: Acupuncture and manual therapy are well-regarded methods for treating pain anywhere in the body. Posture assessment, manual muscle testing, range of motion measurem…
7. The New You Med Spa
5555 E Mockingbird Ln Suite 300ADallas, TX 75206
From Business: Offering day spas and massage therapy services. A premier Medical Spa in Dallas featuring the highest grade equipment to perform aesthetic procedures with precision…
8. Art of Touch MassageServices
Best massage in town! Clean and private facility, real therapeutic massage, effective relief! Definitely recommend San!
9. Divine Injury Clinic
9304 Forest Ln Suite 123Dallas, TX 75243
10. Bynum, Kathleen MServices
5323 Miller AveDallas, TX 75206
11. Peony Oriental Massage
1529 E Interstate 30 Ste 105Garland, TX 75043
12. Oriental MassageServices
3198 W Parker Rd Ste 3114Plano, TX 75075
13. Oriental Massage
1615 Precinct Line RdHurst, TX 76054
14. Twin Oriental Massage - CLOSED
1305 Brown Trl Ste GBedford, TX 76022
15. Duncanville Electrolysis And Laser CenterServices
122 W Center StDuncanville, TX 75116
From Business: We provide hair removal for all skin types in a professional, private setting.
16. Elite MassageServices
4950 Keller Springs Rd Ste 430 Ste 430Addison, TX 75001
From Business: Elite Massage is a professional, knowledgeable, massage establishment that has been located in Dallas for over 18 years with a strong commitment to excellence. We a…
17. Adrian JanetServices
I was involed in an auto accident and was not covered by insurance at the time. I was injured and needed to see a doctor. I called an attorney and …
18. Mylinda Renay Salon Spa & BoutiqueServices
This review is to comment on how awesome my full head of hair extensions are. Mylinda is the best hair stylist, in the entire Dallas Fort Worth me…
19. Norman Rittenberry DC
Dr. Rittenberry is great. I have been going here two years now. I found him in the phone book and came because his ad said Sat. Appointment - the be…
20. Massage EnvyServices
975 W John Carpenter Fwy Suite 112Irving, TX 75039
From Business: Our therapists are here to alleviate every ache, pain or stress — no matter how small — because we agree on one thing: The good life should actually feel that way.
21. Optimum Chiropractic & Wellness CenterServices
First of all, the doctor never leaves me waiting in the waiting room - my treatment always begins on time. His adjustments are gentle and effective…
22. Al Massage
Best massage. Highly recommended
23. Arlington Chiropractic Care & Work Injury-Accident-Laser Decompression Health Centre
1419 W Arkansas LnArlington, TX 76013
24. Traxler ChiropracticServices
Traxler Chiropractic is chiropractic care that stands out from all the rest. I have been to several chiropractors over the years but none of them he…
25. Lemongrass SalonServices
1161 E. Southlake Blvd., Ste 290Southlake, TX 76092
26. North Texas School Of Swedish Massage
I love massage schools - they are such a good value! I stumbled across this one online and thought I'd give them a try. They offer massages from cur…
27. Avatar SalonServices
Request Alaina Rose if you want a great hairstyle and blonde perfection. I always walk out feeling and looking amazing.
28. Salon NarcisseServices
I have been going to this wonderful day spa for over 10 yrs and can't say enough nice things about it. Salon Narcisse keeps up with the latest styl…
29. Hightower SalonsServices
I went in the place at least 2 times if not 3 times. NO ONE came up to me to ask if they could help me. One time I actually stayed almost 10 minutes…
30. Perfect Touch Day SpaServices
This is the only place I will go for massages! They have many spa packages to choose from. My all time favorite is the four hands massage! Everyone …
Really excellent deep tissue massage. I have arthritis in both my neck and low back. After one hour on the table I leave feeling relaxed and pain free. Well worth the drive from Frisco.
great massage to help relax the muscles after an intense work out. it helps me a lot with tight muscles. I definitely recommend this spa. I will come often.


text:
Is your resume in need of a little disruption?
Startups are all about
making things work better.
Our resume writing service is all about doing that for your CV.
StartUpHire is the place to find Manager,-Sales-Training jobs in and near . Review the list below of Manager,-Sales-Training jobs. These Manager,-Sales-Training jobs represent some of the most rewarding careers available. You can refine your job search for Manager,-Sales-Training jobs in by adding a job title, company name, or keyword to the search box above … or click the "Advanced Search" link for more options. Don't see the employment opportunity you're looking for? Check back soon for more Manager,-Sales-Training jobs in , or sign up for an email alert (link in upper left) to receive periodic updates on new Manager,-Sales-Training jobs in , .
City:Palo Alto State:CA Salary:Depends On Experience Job Type:Part Time Posted Date:05/11/2016 Job Details Job Title: TRX and Resistance Training Teacher Location: 440 Kipling Street, Palo Alto, CA 94301 Why work for us?We are a group of enthusiastic and6/1/2016 Palo Alto, CA Save This Job
Job Details Requisition Number16-0337 Post Date6/15/2016 TitleService Team Manager CityRaleigh StateNC Description Tamarac, a division of Envestnet, Inc. (NYSE:ENV), is a leading independent provider of technology-enabled investment and practice management solutions for5/17/2016 Raleigh, NC Save This Job
Requisition Number16-0270 Post Date5/11/2016 TitleService Team Manager CitySeattle StateWA Description Tamarac, a division of Envestnet, Inc. (NYSE:ENV), is a leading independent provider of technology-enabled investment and practice management solutions for independent5/17/2016 Seattle, WA Save This Job
San Francisco or Mountain View The Twilio platform enables companies to integrate communications directly into their applications via simple cloud API?s and with on-demand global reach. Twilio is therefore challenged with abstracting away a world of complexity so that our4/23/2016 San Francisco, CA Save This Job
San Francisco The Twilio platform enables companies to integrate communications directly into their applications via simple cloud API?s and with on-demand global reach. Twilio is therefore challenged with abstracting away a world of complexity so that our customers can go global4/23/2016 San Francisco, CA Save This Job
Location:Methuen, MA Job Code:SMNJ0516 Description Our rapidly growing medical robotics division is searching for a service manager. This position will provide leadership in achieving the highest service quality level for all parts, products and systems while ensuring compliance6/22/2016 Methuen, MA Save This Job
Oklahoma City, OK, US Worker Category :Full-time Job Class Remedi SeniorCare is one of the nation?s TOP TEN long term care pharmacies. We offer nursing homes and assisted-living facilities everything they need to provide better care to their residents by delivering highly5/26/2016 Oklahoma City, OK Save This Job
ABOUT THE ORGANIZATIONAbout Chromatin, Inc. ? Chromatin, Inc. produces high quality of sorghum hybrids for both traditional agriculture markets and new applications. It provides water usage efficient grain, forage and sweet sorghum seeds to growers and producers who are attracted5/21/2016 Lubbock, TX Save This Job
Location US-WI-Brookfield Posted 29 days ago Job Category Information Technology Job Type Full-Time Experience Not Specified Apply Now Share this job with Job Description As the Connecture Client Service Manager-DRX Medicare, you will be responsible for managing the5/15/2016 Brookfield, WI Save This Job
San Francisco, CAFull-time Company Description Smaato is the global real-time advertising platform for mobile publishers and app developers. Smaato runs the world?s largest independent mobile ad exchange and has been pioneering innovative, mobile-first solutions for publishers4/23/2016 San Francisco, CA Save This Job
Job Description Associate Technology Project Manager - (16000186) The Technical Associate Project Manager will provide daily support to the Project Managers assisting with the successful delivery of initiatives sponsored by business units or internal technology groups.6/17/2016 Overland Park, KS Save This Job
Job Description Manager, Internal Controls & SOX Compliance - (1603U) What you'll do: Everyday Health (EVDY: NYSE) is seeking a motivated manager to oversee our Internal Controls & Sarbanes-Oxley compliance at our New York, NY corporate office. In this role, you will work6/2/2016 New York, NY Save This Job
All times are in India Standard Time. ID 2016-2669 Job Location US-CA-San Francisco Posted Date 4/26/2016 More information about this job: Overview: Pharmaca Integrative Pharmacy ASSISTANT RETAIL MANAGER Stop by our store located at: 925 Cole Street, San Francisco, CA5/26/2016 San Francisco, CA Save This Job
All times are in India Standard Time. ID 2016-2640 Job Location US-WA-Seattle Posted Date 4/7/2016 More information about this job: Overview: Header810x300 Pharmaca Integrative Pharmacy ASSISTANT RETAIL MANAGER Stop by our store located at: 1815 N. 45th St., Suite 110,4/26/2016 Seattle, WA Save This Job
San Jose, CAFull-time Company Description Hoopla was founded to help organizations motivate people to perform their best. Our inspiration comes from a variety of sources, including sports, motivational psychology, game mechanics, and a competitive drive. We are motivated by the4/26/2016 San Jose, CA Save This Job
ID 2016-2146 Job Location US-PA-Plymouth Meeting Posted Date 2/12/2016 More information about this job: Overview: Accolade is the leading technology-enabled consumer healthcare engagement services company for large employers, payers and provider organizations. We help4/23/2016 Plymouth Meeting, PA Save This Job
This newly created position reports to the Director, Quality Assurance Compliance and is responsible for assuring GCP compliance with Alder SOPs, ICH and FDA/EMA regulations. Specific responsibilities will include: Provide GCP compliance support: participate in Clinical Project6/24/2016 Bothell, WA Save This Job
Job Description Associate Project Manager - (16000174) OVERALL PURPOSE OF JOB: ? Provide daily support for Project Managers to assist with the successful delivery of products and services offered by UnitedLex. Provide detailed documentation during initiation, planning,6/17/2016 Overland Park, KS Save This Job
at PulsePoint New York Why settle with being one of five Product Managers, deliberating on the next version of the "Share" button? Instead, come to PulsePoint, a Small Company where you can make a BIG IMPACT and help us achieve our mission of Making Ads Matter. At PulsePoint,5/27/2016 New York, NY Save This Job
Tracking Code 251-093 Job Description This position will be responsible for building and leading the T2 Biosystems team responsible for providing service and support to T2 Biosystems customers. The candidate must have a combination of advanced technical and leadership skills to5/26/2016 Lexington, MA Save This Job


text:
Personalise your news, save articles to read later and customise settings
If you have trouble accessing our login form below, you can go to our login page.
The Age
Previous thumbnails
Next thumbanils
Fire fighters and water bombing helicopters fill up at Lake Glenmaggie. Photo: Michael Clayton-Jones
Please enter your friend's name
Please enter a valid email address
Please enter your name
Please enter your comment
Thank You.
Your email has been sent.
Some funny moments from the longest campaign trail in recent memory to decide who will next lead Australia. Follow us on
Fairfax Media's talented team of artists, illustrators and cartoonists give us their very own humorous version of the news of the day.
Prime Minister Malcolm Turnbull officially launches the Liberal 2016 Federal Campaign with wife Lucy and Liberal party members Julie ...
A large crowd is seen attending the Equal Love Rally for Marriage Equality! June 25, 2016 in Melbourne, Australia. The rally is aiming to ...
Fairfax photographer James Brickwood documents NRL player Mark Hughes' inspirational Kokoda trek for the Mark Hughes Foundation.The Kokoda ...
Sorry. An error occurred when submitting the form.
Please try again later.
Funny moments of Election 2016
Federal Election 2016 - final week
Canberra Times Sunday Selfies
Photos of the week
Best & worst dressed celebrities of the week
Summer and Bushfires go hand in hand in Australia and the first month of 2013 has already seen a few move through Victoria, including the Gippsland towns of Glenmaggie and Licola.
Skip to:
Compare record low loan rates from 3.66% p.a. now
More Info
Plus receive $50 credit when you apply online. T&Cs apply
Check it Out
Compare 0% p.a. balance transfer credit cards now
Find Out More
Samsung Galaxy phones on the Telstra 4G network
Compare now
Plans and prices for Apple's latest iPhones available now


text:
Primary tabs
Ongoing SmackDown coverage through the night
September 26, 2008
Refresh to see the latest results:
- WWE Champion Triple H & Jeff Hardy def. Montel Vontavious Porter & The Brian Kendrick
- Maria & Brie Bella def. Natalya & Victoria
- The Great Khali vs. Vladimir Kozlov (No Contest)
- Chavo Guerrero def. Jimmy Wang Yang
- Carlito & Primo def. Curt Hawkins & Zack Ryder (new WWE Tag Team Champions)
WWE Universe: Don't forget, next week, on Oct. 3, SmackDown is moving to MyNetwork TV.
More on the move ...
WWE Shows Latest Results
Raw results, June 27, 2016: Rollins and The Club make savage statement by laying out Ambrose and CenaFull Results
SmackDown Results, June 30, 2016: Ambrose rises above the insanity in a furious Champion vs. Champion MatchFull Results


text:
You are currently viewing our Mac titles. These are our other Game Programming topics:
On this page you will find our Apress Books in the area of Mac.
View books as a
or a
5 Book(s)
$31.99 $19.19
View Book
$27.99 $16.79
Receive updates on titles & discounts
Pro Bash Programming, Second Edition
Regular Price: $34.99
Buy today for $10.00
Process Mining
Regular Price: $49.99
Buy today for $20.00


text:
Sort by: [Top
Recent Book Searches:
0812233131 / 978-0812233131 / Hierarchy and Its Discontents: Culture and the Politics of Consciousness in Caste Society / Steven M. Parish
0812233174 / 978-0812233179 / Beyond the Red Notebook: Essays on Paul Auster (Penn Studies in Contemporary American Fiction) /
0812233190 / 978-0812233193 / Forbidden Texts: Erotic Literature and Its Readers in Eighteenth-Century France (New Cultural Studies Series) / Jean Marie Goulemot
0812233239 / 978-0812233230 / William Langland's Piers Plowman: The C Version : A Verse Translation (Middle Ages Series) / William Langland
0812233352 / 978-0812233353 / Japanese Studio Crafts: Tradition and the Avant-Garde / Rupert Faulkner
0812231953 / 978-0812231953 / From Margins to Mainstream: Feminism and Fictional Modes in Italian Women's Writing, 1968-1990 / Carol Lazzaro-Weis
0812231988 / 978-0812231984 / Women Preaching Revolution: Calling for Connection in a Disconnected Time / Elaine J. Lawless
0812232143 / 978-0812232141 / The Death of the Troubadour: The Late Medieval Resistance to the Renaissance (Middle Ages) / Gregory B. Stone
0812232232 / 978-0812232233 / Science Fiction Culture (Feminist Cultural Studies, the Media and Political Culture) / Camille Bacon-Smith
0812232364 / 978-0812232363 / Creative Women in Medieval and Early Modern Italy: A Religious and Artistic Renaissance /
081223250X / 978-0812232509 / Learning from Disaster: Risk Management After Bhopal (Law in Social Context) /
0812232585 / 978-0812232585 / Critical Care Nursing:a History (Studies in Health, Illness, and Caregiving) / FAIRMAN
0812232658 / 978-0812232653 / The Embodiment of Characters: The Representation of Physical Experience on Stage and in Print, 1728-1749 (New Cultural Studies Series) / Jones Deritter
0812232666 / 978-0812232660 / Cultural Politics-Queer Reading (New Cultural Studies Series) / Alan Sinfield
0812232747 / 978-0812232745 / The Evolution of International Human Rights: Visions Seen (Pennsylvania Studies in Human Rights) / Paul Gordon Lauren
081223300X / 978-0812233001 / The Complete Potter: Porcelain (The Complete Potter) / Caroline Whyman
0812233123 / 978-0812233124 / Gendered Modernisms: American Women Poets and Their Readers /
081223328X / 978-0812233285 / The Teaching and Acquisition of South Asian Languages /
0812233409 / 978-0812233407 / Human Rights, Labor Rights, and International Trade (Pennsylvania Studies in Human Rights) /
0812232127 / 978-0812232127 / Taxes on Knowledge in America: Exactions on the Press from Colonial Times to the Present / Randall P. Bezanson
0812232178 / 978-0812232172 / The Romance of Origins: Language and Sexual Difference in Middle English Literature / Gayle Margherita
0812232186 / 978-0812232189 / Mark Twain in the Company of Women / Laura E. Skandera-Trombley
0812232216 / 978-0812232219 / Quest for Conception: Gender, Infertility, and Egyptian Medical Traditions / Marcia C. Inhorn
0812232283 / 978-0812232288 / Crisis and Continuity: Land and Town in Late Medieval Castile (Middle Ages Series) / Teofilo F. Ruiz
0812232283 / 978-0812232288 / Crisis and continuity Land and town in late Medieval Castle /
0812232356 / 978-0812232356 / Infertility and Patriarchy: The Cultural Politics of Gender and Family Life in Egypt / Marcia C. Inhorn
0812232437 / 978-0812232431 / Women in Pain: Gender and Morbidity in Mexico / Kaja Finkler
0812232887 / 978-0812232882 / On Original Sin and a Disputation With the Jew, Leo, Concerning the Advent of Christ, the Son of God: Two Theological Treatises : Odo of Tournai (Middle Ages Series) / Odo, Irven M. Resnick
0812232003 / 978-0812232004 / The Failure of the Criminal Procedure Revolution / Craig M. Bradley
0812232224 / 978-0812232226 / Imageless Truths: Shelley's Poetic Fictions / Karen A. Weisman
Browse ISBN Directory:
9789004099340-9789004101050 9789004101067-9789004102880 9789004102897-9789004104686 9789004104693-9789004106642 9789004106659-9789004108431 More...
More About Using This Site and Buying Books Online:
Be Sure to Compare Book Prices Before Buy
This site was created for shoppers to compare book prices and find cheap books and cheap college textbooks. A lot of discount books and discount text books are put on sale by many discounted book retailers and discount bookstores everyday. You just need to search and find them. Our site provides many book links to some major bookstores for book details and book coupons. But be sure not just jump into any bookstore site to buy. Always click "Compare Price" button to compare prices first. You would be happy that how much you could save by doing book price comparison.
Buy Books from Foreign Country
Our goal is to find the cheapest books and college textbooks for you, both new and used books, from a large number of bookstores worldwide. Currently our book search engines fetch book prices from US, UK, Canada, Australia, New Zealand, Netherlands, Ireland, Germany, France, and Japan. More bookstores from other countries will be added soon. Before buying from a foreign book store or book shop, be sure to check the shipping options. It's not unusual that shipping could take 2 -3 weeks and cost could be multiple of a domestic shipping charge.
Buy Used Books and Used Textbooks
Buying used books and used textbooks is becoming more and more popular among college students for saving. Different second hand books could have different conditions. Be sure check used book condition from the seller's description. Also many book marketplaces put books for sale from small bookstores and individual sellers. Make sure to check store review for seller's reputation when available. If you are in a hurry to get a book or textbook for your class, you would better choose buying new books for prompt shipping.
Please See Help Page for Questions
regarding ISBN / ISBN-10 / ISBN10, ISBN-13 / ISBN13, EAN / EAN-13, and Amazon


text:
Strategy Guide
Video game advice from everyone's favorite intergalactic space alien, Guido!
Sci-Fi Guys
Hilarious antics in space!
Another Day
An experiment with a Wacom pad that evolved into much more.
as gains c to buy premium items?
Man you can farm experience points to get OP and beat the game :/
geame is too difficult which makes it hard work not fun, and you cant return displaced cores :/
xD THE Menu Is In Spanish, Good game i rate 5/5 Stars
i agree with eskens completely and that symbol means something i cant remember


text:
The amount of money the public pays for NFL stadiums varies wildly by city Here is why Phil Mickelson calls this year's US Open course 'the... ...http://www.businessinsider.in/38-year-old-star-Italian-goalie-has-a-great-explanation-for-why-he-cut-back-on-pasta-and-wine/articleshow/52737843.cms
Warriors players ripped LeBron James for breaking an unwritten rule and baiting Draymond Green with a 'disrespectful' move Report: Some powerful... ...http://www.businessinsider.in/Denver-Broncos-defensive-coach-says-his-name-was-spelled-wrong-on-his-championship-ring/articleshow/52734467.cms
The 3 plays in sports everybody will be talking about today IPL growth rate jumps to two digits, churns out Rs 2,500 crore in season 9... ...http://www.businessinsider.in/Report-Some-powerful-people-at-Baylor-are-fighting-to-have-Art-Briles-firing-reduced-to-a-1-year-suspension/articleshow/52732481.cms
Dramatic home run clinches first-ever spot in the College World Series for UC Santa Barbara Draymond Green's suspension comes with a twist that... ...http://www.businessinsider.in/Pittsburgh-Penguins-win-the-Stanley-Cup/articleshow/52721788.cms
It's a great time of year. Summer is upon us, and we have not only one, but two professional sports championships in full swing. The top two NBA... ...http://in.sys-con.com/node/3842779
ENJOY Watch Pittsburgh Penguins vs...
1 Followers
0 Followers
0 Followers
0 Followers
0 Followers


text:
Forest Park Tower
2306 Park Place Avenue Fort Worth Texas 76110
Are you the property manager?
Historic High-Rise Apartments. Built in 1927 atop a bluff overlooking the Trinity River, the Forest Park Tower is a designated Fort Worth cultural landmark. Both extraordinary and unique, the Forest Park Tower is conveniently located in the historic Berkley Place and Mistletoe Heights neighborhoods adjacent to the Medical District, the Fort Worth Zoo, the Trinity Hike and Bike Trail, the Cultural District, and Downtown Fort Worth. CALL FOR SPECIALS!
Other Apartments Nearby
|1 Bed
|$1050 - $1420
|2 Beds
|$1620 - $2135
|3 Beds
|$2420 - $2430
Zip Codes Near Fort Worth, TX
Cities Near Fort Worth, TX
Neighborhoods Near Fort Worth, TX
- Northwest Dallas
- Villages at Lakewest
- Fredrick Douglas
- Southwest Dallas
- Kingsbridge Crossing
- Broadstone Wycliff
- Middlebrook Place Townhomes
- Cedar Springs Apartments
- Cedar Springs Crossing
- Jefferson at Cedar Springs
- Skyline Center
- Stemmons Place
- Hawthorne Street Townhomes
- West Trinity Industrial District
- Hawthorne Townhomes
- Webb Chapel Park
- Casa Place Apartments
- Evergreen Hills
- Walnut Gardens
- Webb Chapel Estates
- All Fort Worth Neighborhoods
Colleges Near Fort Worth, TX
- North Lake College, TX
- University of Dallas, TX
- AIMS Academy, TX
- Mediatech Institute Irving, TX
- Parker College of Chiropractic, TX
- Dallas Christian College, TX
- Platt College, TX
- Mountain View College, TX
- Arlington Medical Institute, TX
- Dallas Baptist University, TX
- University of Texas Southwestern Medical Center, TX
- Wade College, TX
- Graduate Institute of Applied Linguistics, TX
- University of Texas Arlington, TX
- Arlington Baptist College, TX
- Remington College Fort Worth, TX
- Westwood College Ft Worth, TX
- Texas Wesleyan University, TX
- Tarrant County College, TX
- University of North Texas Health Science Center, TX


text:
By Catholic Online (NEWS CONSORTIUM)
4/15/2014 (2 years ago)
Catholic Online (www.catholic.org)
President Obama has attempted 442 tax increases during his six years as president so far, and more are likely to come as the administration looks for ways to pay for their proposals. According to Americans for Tax Reform, the numbers suggest why it's important to have a president who likes taxing to be opposed by a partisan Congress.
Obama has proposed hundreds of tax increases and more could come within the last two years.
By Catholic Online (NEWS CONSORTIUM)
Catholic Online (www.catholic.org)
4/15/2014 (2 years ago)
Published in Politics & Policy
Keywords: Obama, tax increases, IRS, proposals, congress, churches
LOS ANGELES, CA (Catholic Online) - The Americans for Tax Reform has published, on Tax Day, no less, a year-by-year summary of President Obama's attempted tax hikes on the American people. Many of the tax hikes have been stopped by Congress, however some have been implemented.
According to ATR, Obama has attempted 442 tax hikes plus another 10 embedded in Obamacare.
Pray to protect our Church!
Included in his tax hikes, proposals, and spoken intentions, Obama has hiked taxes on tobacco products, considered a tax on soda pop and other sugary beverages, and "other broad-based tax increases." Included is consideration of a European style "value added tax."
The ATR provided the annual breakdown:
-79 tax increases for FY 2010
-52 tax increases for FY 2011
-47 tax increases for FY 2012
-34 tax increases for FY 2013
-137 tax increases for FY 2014
-93 tax increases for FY 2015
Our attention is drawn to FY 2014, when Obama became a lame duck president, that's when an executive's true colors tend to show.
The problem with tax increases isn't the taxes themselves, actually. Although many Americans are appalled at the amount taken from them each year, and are naturally resistant to paying even more, the real tragedy is that the United States government rakes in the world's largest haul of taxes, yet never seems to be able to cover its own expenses.
The government spends money wildly, an average of at least $10 billion per day or more. Much of that money is spend on wars, wasteful programs, and perks and privileges for the nation's ruling aristocracy. Both corporate welfare and social welfare consume massive amounts of money with corporate welfare - that is corporate subsidies paid to "create jobs" and "stimulate the economy" while propping up already profitable, or otherwise failing businesses, outpaces social welfare by two-to-one.
American politicians are simply playing for the next election, and to win they need generous campaign contributions from those who can pay. Specifically, those are wealthy individuals and big businesses. Meanwhile, Obama and others like him have no problem taking from the average person using finger-wagging taxes such as sin taxes, to pay those subsidies out to corporations and people that simply don't work.
This is why the middle class is shrinking.
Obama is no friend of the middle class, whose only remaining usefulness is taxation. Unfortunately, what goes for Obama likely goes for many other members of our government, both right and left.
As Obama and others look for new sources of revenue, a novel solution may be at hand. The idea of taxing churches has entered the public discourse on where the administration can go next for some quick cash.
By David Drudge (CALIFORNIA NETWORK)
It pays to know the Clintons. A report released by the Democrats ahead of the Republican report, intended to show Republican misuse of power, has revealed possible corruption. LOS ANGELES, CA (California Network) - The Democrats wanted to show the Republicans as ... continue reading
By Marshall Connolly (CALIFORNIA NETWORK)
Hank Paulson, former Treasury Secretary and former CEO of Goldman Sachs has endorsed Hillary Clinton because of her globalist credentials. This underscores why Clinton is bad for America. LOS ANGELES, CA (California Network) - Globalism is a philosophy that suggests ... continue reading
By David Drudge (CALIFORNIA NETWORK)
Hillary Clinton, Queen of the delete key, has deleted 75 meetings with key donors from record. These meetings were with major donors while she was secretary of state. The federal government turned these details over after the Associated Press sued. LOS ANGELES, CA ... continue reading
By Kenya Sinclair (CALIFORNIA NETWORK)
Mentally handicapped or a vigilante? Presumptive Republican nominee Donald Trump's would-be assassin may have been on to something. LOS ANGELES, CA (Catholic Online) - Less than two weeks ago, 19-year-old Michael Sandford attempted to steal a police officer's gun ... continue reading
By David Drudge & Kenya Sinclair (CALIFORNIA NETWORK)
Under Obama, immigrants are now exempted from joining the military in the event of a draft. Until now, legal immigrants have been required to pledge to serve in the military if needed, like any other citizen must do. Now, they no longer have to do so, or even state ... continue reading
By David Drudge (CALIFORNIA NETWORK)
By virtue of her own criminality, or at least ignorance, Hillary Clinton should be disqualified from the office of President. LOS ANGELES, CA (California Network) - Hillary Clinton withheld several important work-related emails. She was ordered not to delete or ... continue reading
By David Drudge (CALIFORNIA NETWORK)
There are now more armed federal agents and bureaucrats than U.S. Marines, a study has found. A taxpayer watchdog organization has shed new light on the militarization of our nation. According to "Open the Books," a taxpayer watchdog organization, there are over ... continue reading
By Marshall Connolly, (California Network)
Did Bernie Sanders win California? According to many Sanders supporters the answer is yes, and it was stolen away by a corrupt election apparatus bent on suppressing votes for Sanders, and aided by a news media that was quick to call the race for Clinton in the crucial ... continue reading
By David Drudge (California Network)
"All of the money she is raising is blood money," Donald Trump correctly pointed out about Hillary Clinton. Trump intends to regain control of his campaign following a shakeup as he begins to speak to the public about Hillary Clinton's hypocrisy and lust for power at ... continue reading
By Marshall Connolly, (California Network)
The Obama administration has insisted that churches will pay for elective abortions after rejecting a "right of conscience" petition from pro-life groups. The Department of Health and Human Services has ruled that an amendment to the law, known as the Weldon Amendment, ... continue reading


text:
KAUAN meteorite crash delay
That's fucking metal
where was spartan Putin with his meteorite laser-shooting eyes
wow fuckin metal
Digging: Ott - Mir
Literally the definition of metal. Meteors fucking strike when you produce an album.
Best reason for an album delay I've ever heard of
m/ (2)
Digging: Astronoid - Air
] / [ / /
] / [ / /
] [ /] [ / /
] [ / ] [ / /
] [ ] [ / /
]___[ ]___[ / /
History demands this album be monumental
m/ (3)
this band's music is super relaxing [:
this is so fucking metal
folk doom? wut, these guys are like neofolk with a lil post rock
Digging: YG - Still Brazy
haven't heard their first album tho, so maybe that one's got some dooooom
Digging: Thenighttimeproject - Thenighttimeproject
"when the city was attacked by a hailstorm of meteorites, whose power was 30x that of an atomic bomb!"
fucking lol
"meteorite is just "official" version. Here is plenty of people, who think, it was a rocket"
fucking lol³
Holy shit
Digging: Pearl Jam - Ten
Jesus fuck XD I have never heard of an album delay because of that. Holy shit lol
• Michael Gira Accused of Rape• R.I.P. Lemmy• R.I.P. David Bowie• Scott Weiland dead at 48 • The Story So Far's vocalist dropk..• Rush drummer retires• Killswitch Engage debut new single• Brand new Brand New Single• Deftones stream new single• Riverside guitarist dies
• Aerosmith announce last tour• New Pretty Addicted single• Gemini Syndrome new album • RIP Bernie Worrell• New Periphery Song• Yellowcard call it quits• New Forevermore Song/Video• Soilwork stream new track• Tyondai Braxton Charity EP• Chevelle stream Young Wicked• Evergrey reveal album details• Another blink-182 single• New Fall Out Boy Song• Bring Me the Horizon share new vi..• New Eritherium track» see all news
Bands: A B C D E F G H I J K L M N O P Q R S T U V W X Y Z


text:
Why change, La Mesa?
Developer describes future vision of the Village
Jay Anderson 10:30 a.m., June 25
Image by Dennis Bersales
Posted February 23, 2011
"We decided we wanted something that doesn't exist," Bobby Bray (the Locust), a student of interdisciplinary computing and the arts at UCSD, says at the Camel's Breath Inn in Mission Valley. "So we rolled up ...
Jay Anderson 10:30 a.m., June 25
Dave Rice 9 a.m., June 25
Dorian Hargrove 4:30 p.m., June 24
Garrett Harris 4 p.m., June 24
Jeff Smith 3:30 p.m., June 24
Matt Potter 2:35 p.m., June 24
Walter Mencken 2 p.m., June 24
© 2016 San Diego Reader. All rights reserved. No part of this site may be reproduced without our written permission.
Each newsletter subscription means another chance to win!Close


text:
Business Owner? Add your logo and more…
Veterinary Activities in Preston (Lancashire)
Write review
220 Watling St RoadFulwoodPrestonLancashirePR2 8AD
Show map
01772 7...
01772 700 671
Fax: 01772 7...
cb cbc - 22/08/2013 | report this review
All fields are required. Your review will appear immediately.
By leaving this review, you agree with our Terms of membership
Similar nearby businesses
Tickford St, Newport Pagnell, MK16 9BA
Hillock Lane, Preston, PR4 1TP
58 New Lane, Preston, PR1 9JJ
65 Liverpool Road, Preston, PR4 5HA
90 Moor Lane, Preston, PR1 1JQ
7 Rope Walk, Preston, PR3 1NS
© 2016 The Independent - part of the network