text:
|Publication number
|Publication type
|Application number
|Publication date
|Nov 9, 1999
|Filing date
|Apr 2, 1998
|Priority date
|Apr 9, 1997
|Fee status
|Also published as
|Publication number
|Heinrich Odenwalder, Hans Langen, Jorg Hagemann, Klaus Henseler
|Original Assignee
|Agfa-Gevaert Ag
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (5), Referenced by (7), Classifications (13), Legal Events (6)
|External Links: USPTO, USPTO Assignment, Espacenet
This invention relates to a colour photographic silver halide material having improved properties.
The practical requirements placed upon DOP scavengers (scavenging reagents for the developer oxidation product) in colour photographic silver halide materials (colour film and colour paper) are
a) elevated efficacy, i.e. effective avoidance of unwanted co-coupling,
b) extended stability in storage, i.e. avoidance of losses in activity by oxidation before processing;
c) no impairment of image stability, i.e. in the case of film, for example, avoidance of post coupling, in the case of paper, for example, stability of the dyes against moisture, heat and light.
So-called white couplers or compounds having a redox action are used to perform these tasks. These are conventionally either pyrazolone couplers having a methyl group at the coupling site or non-diffusible hydroquinones, disulphonamidophenols and N-aryl-N'-acylhydrazines. These compounds are not, however, capable of adequately fulfilling practical requirements as described above.
It has now been found that surprising improvements may be achieved with certain benzofuranones.
The present invention accordingly provides a colour photographic silver halide material having a support and at least one photosensitive silver halide emulsion layer, which material contains in at least one layer at least one compound of the general formula(I): ##STR2## in which R1 means hydrogen, alkyl or acyl,
R2, R3 mutually independently mean alkyl, cycloalkyl, alkenyl, aryl, halogen, OR4, SR5, NR6 R7, nitro, cyano, SO2 R8, COOR9, COR10 or hetaryl,
R4, R5, R9 mutually independently mean alkyl, cycloalkyl, alkenyl, aryl or hetaryl,
R6, R7 mutually independently mean H, R4, COR10, COOR9, SO2 R8,
R8, R10 mutually independently mean alkyl, cycloalkyl, alkenyl, aryl, hetaryl or NR6 R7,
n, m mean 0, 1, 2, 3 or 4 or two residues R2 or R3 may each mean a fused carbo- or heterocyclic ring or the compounds of formula I are linked to a polymer chain via R1, R2 or R3. At least one of the residues R2 and R3 is preferably located in para position relative to the phenolic oxygen.
Acyl residues R1 can be residues of an aromatic or aliphatic carboxylic acid, carbamic acid, carbonic acid, sulfonic acid, sulfinic acid or phosphonic acid.
The linkage to a polymer chain can be accomplished with an unsaturated group, e.g. a styrene, acrylic acid or methacrylic acid group.
A suitable monomer is e.g.: ##STR3##
The linkage to a polymer chain can further be accomplished by a polymer analogous reaction. E.g. the compound of the following formula ##STR4## can become part of a polymer as follows ##STR5##
In a preferred embodiment, R2 is identical to R3 and n is identical to m.
Preferably, R1 means hydrogen or acyl and R2 and R3 mean alkyl, wherein the sum of the C atoms in the alkyl residues R2 and R3 is ≧8. Preferred acyl residues are the residues of aromatic or aliphatic carboxylic acids.
Examples of compounds of the formula (I), in which R1 is hydrogen, are:
______________________________________No. R2 ═R3______________________________________I-1 4-t-C4 H9 I-2 4-CH3 I-3 4-CH(CH3)2 I-4 4-t-C8 H17 I-5 4-i-C9 H19 I-6 4-i-C12 H25 I-7 4-Cyclopentyl I-8 4-Cyclohexyl I-9 2-CH3 -4-CH3 I-10 2-CH3 -4-t-C8 H17 I-11 2-t-C4 H9 -4-CH3 I-12 2-t-C4 H9 4-t-C4 H9 I-13 2-(CH3)2 -phenyl-4-(CH3)2 -phenyl I-14 2-t-C4 H9 -4-(CH2)2 CO2 CH3 I-15 2-t-C4 H9 -4-OCH3 I-16 2-Cl-4-Cl I-17 2-Phenyl-4-OC4 H9 I-18 2-NHCO-i-C7 H15 -4-O--COOC2 H5 - I-19 1 STR6## - I-20 2 STR7## - I-21 2-S(CH2)11 CH3 -4-CH3 - I-22 3 STR8## - I-23 4-C(CH3)2 -phenyl I-24 4-CO2 C12 H25 I-25 3-CH3 -4-CH3______________________________________
The position of the substituents is relative to the oxygen. Position 3 is in para position relative to the second ring linkage.
Further examples are:
__________________________________________________________________________No. R2 ═R3__________________________________________________________________________ I-264 STR9## - I-275 STR10## - I-286 STR11## - I-297 STR12## - I-308 STR13## - I-319 STR14## - I-320 STR15## - I-331 STR16## - I-342 STR17## - I-353 STR18## - I-364 STR19## - I-375 STR20## - I-386 STR21##__________________________________________________________________________
Production of Compound I-4
24.4 ml of an aqueous, 50 wt. % oxoacetic acid and then 91.7 g of 4-(1,1,3,3-tetra-methylbutyl)phenol are added at room temperature to a mixture of 500 ml of glacial acetic acid and 90 ml of concentrated sulphuric acid. After overnight stirring, the resultant precipitate is removed by suction filtration and washed with glacial acetic acid and then with water.
After drying, 81.1 g (90% of theoretical) of compound I-4 are obtained having a melting point of 125 to 127� C.
The other stated compounds are obtained in a corresponding manner. In the event of diminished reactivity of the phenolic compound, more severe reaction conditions may be necessary, for example by increasing temperature, increasing the concentration of sulphuric acid, performing the reaction in a melt etc. The sulphuric acid may furthermore be entirely or partially replaced by other acids, for example by p-toluenesulphonic acid, methanesulphonic acid, phosphoric acid, polyphosphoric acid, phthalic acid, trifluoroacetic acid, boric acid and the like. Compounds of formula I, in which R1 means an acyl residue are easily obtained from compounds of formula I wherein R1 denotes hydrogen by known methods applying carboxylic acid anhydrides or carboxylic acid chlorides, for example.
The compounds of the formula (I) are preferably used in a quantity of 5 to 1000 mg/M2, in particular of 10 to 500 mg/r2.
The compounds of the formula (I) may also assume salt form (phenolate); suitable cations are metal cations and ammonium ions, in particular alkali metal ions and tri- or tetraalkyl ammonium ions.
Examples of colour photographic materials are colour negative films, colour reversal films, colour positive films, colour photographic paper, colour reversal photographic paper, colour-sensitive materials for the dye diffusion transfer process or the silver dye bleaching process.
The photographic materials consist of a support onto which at least one photosensitive silver halide emulsion layer is applied. Thin films and sheets are in particular suitable as supports. A review of support materials and the auxiliary layers applied to the front and reverse sides of which is given in Research Disclosure 37254, part 1 (1995), page 285.
The colour photographic materials conventionally contain at least one red-sensitive, one green-sensitive and one blue-sensitive silver halide emulsion layer, optionally together with interlayers and protective layers.
Depending upon the type of the photographic material, these layers may be differently arranged. This is demonstrated for the most important products:
Colour photographic films such as colour negative films and colour reversal films have on the support, in the stated sequence, 2 or 3 red-sensitive, cyan-coupling silver halide emulsion layers, 2 or 3 green-sensitive, magenta-coupling silver halide emulsion layers and 2 or 3 blue-sensitive, yellow-coupling silver halide emulsion layers. The layers of identical spectral sensitivity differ with regard to their photographic sensitivity, wherein the less sensitive sublayers are generally arranged closer to the support than the more highly sensitive sublayers.
A yellow filter layer is conventionally located between the green-sensitive and blue-sensitive layers which prevents blue light from penetrating into the underlying layers.
Possible options for different layer arrangements and the effects thereof on photographic properties are described in J. Inf. Rec. Mats., 1994, volume 22, pages 183-193.
Colour photographic paper, which is usually substantially less photosensitive than a colour photographic film, conventionally has on the support, in the stated sequence, one blue-sensitive, yellow-coupling silver halide emulsion layer, one green-sensitive, magenta-coupling silver halide emulsion layer and one red-sensitive, cyan-coupling silver halide emulsion layer; the yellow filter layer may be omitted.
The number and arrangement of the photosensitive layers may be varied in order to achieve specific results. For example, all high sensitivity layers may be grouped together in one package of layers and all low sensitivity layers may be grouped together in another package of layers in order to increase sensitivity (DE-25 30 645).
The substantial constituents of the photographic emulsion layers are binder, silver halide grains and colour couplers.
Details of suitable binders may be found in Research Disclosure 37254, part 2 (1995), page 286.
Details of suitable silver halide emulsions, the production, ripening, stabilisation and spectral sensitisation thereof, including suitable spectral sensitisers, may be found in Research Disclosure 37254, part 3 (1995), page 286 and in Research Disclosure 37038, part XV (1995), page 89.
Photographic materials with camera sensitivity conventionally contain silver bromide-iodide or silver bromide-iodide-chloride emulsions. Photographic print materials contain either silver chloride-bromide emulsions containing up to 80 wt. % of AgBr or silver chloride-bromide emulsions containing above 95 mol. % of AgCl.
Details relating to colour couplers may be found in Research Disclosure 37254, part 4 (1995), page 288 and in Research Disclosure 37038, part II (1995), page 80. The maximum absorption of the dyes formed from the couplers and the developer oxidation product is preferably within the following ranges: yellow coupler 430 to 460 nm, magenta coupler 540 to 560 nm, cyan coupler 630 to 700 nm.
In order to improve sensitivity, grain, sharpness and colour separation in colour photographic films, compounds are frequently used which, on reaction with the developer oxidation product, release photographically active compounds, for example DIR couplers which eliminate a development inhibitor.
Details relating to such compounds, in particular couplers, may be found in Research Disclosure 37254, part 5 (1995); page 290 and in Research Disclosure 37038, part XIV (1995), page 86.
Colour couplers, which are usually hydrophobic, as well as other hydrophobic constituents of the layers, are conventionally dissolved or dispersed in high-boiling organic solvents.
These solutions or dispersions are then emulsified into an aqueous binder solution (conventionally a gelatine solution) and, once the layers have dried, are present as fine droplets (0.05 to 0.8 μm in diameter) in the layers.
Suitable high-boiling organic solvents, methods for the introduction thereof into the layers of a photographic material and further methods for introducing chemical compounds into photographic layers may be found in Research Disclosure 37254, part 6 (1995), page 292.
The non-photosensitive interlayers generally arranged between layers of different spectral sensitivity may contain agents which prevent an undesirable diffusion of developer oxidation products from one photosensitive layer into another photosensitive layer with a different spectral sensitisation.
Suitable compounds (white couplers, scavengers or DOP scavengers) may be found in Research Disclosure 37254, part 7 (1995), page 292 and in Research Disclosure 37038, part III (1995), page 84.
The photographic material may also contain UV light absorbing compounds, optical brighteners, spacers, filter dyes, formalin scavengers, light stabilisers, anti-oxidants, Dmin dyes, additives to improve stabilisation of dyes, couplers and whites and to reduce colour fogging, plasticisers (latices), biocides and others.
Suitable compounds may be found in Research Disclosure 37254, part 8 (1995), page 292 and in Research Disclosure 37038, parts IV, V, VI, VII, X, XI and XIII (1995), pages 84 et seq.,
The layers of colour photographic materials are conventionally hardened, i.e. the binder used, preferably gelatine, is crosslinked by appropriate chemical methods.
Suitable hardener substances may be found in Research Disclosure 37254, part 9 (1995), page 294 and in Research Disclosure 37038, part XII (1995), page 86.
Once exposed with an image, colour photographic materials are processed using different processes depending upon their nature. Details relating to processing methods and the necessary chemicals are disclosed in Research Disclosure 37254, part 10 (1995), page 294 and in Research Disclosure 37038, parts XVI to XXIII (1995), pages 95 el seq. together with example materials.
The compounds of the formula (I) are in particular used in at least one layer adjacent to a green-sensitive silver halide emulsion layer containing at least one magenta coupler, the silver halide emulsion of which layer is a silver bromide-chloride emulsion containing at least 95 mol. % of AgCl.
In this case, pyrazolotriazole magenta couplers may in particular be considered as the magenta coupler.
A colour photographic recording material was produced by applying the following layers in the stated sequence onto a film support made of paper coated on both sides with polyethylene. All quantities are stated per 1 m2. The quantity of silver halide applied is stated as the corresponding quantity of AgNO3.
SAMPLE 1______________________________________Layer 1: (Substrate layer) 0.2 g of gelatine Layer 2: (Blue-sensitive layer) Blue-sensitive silver halide emulsion (99.5 mol. % chloride, 0.5 mol. % bromide, average grain diameter (0.8 μm) prepared from 0.45 g of AgNO3 with 1.18 g of gelatine 0.55 g of yellow coupler Y-1 0.1 g of white coupler W-1 0.2 g of dye stabiliser ST-1 0.29 g of oil former OF-1 0.10 g of oil former OF-2 Layer 3: (Protective layer) 1.10 g of gelatine 0.07 g of compound SC-1 0.07 g of compound SC-2 0.07 g of tricresyl phosphate (TCP) Layer 4: (Green-sensitive layer) Green-sensitised silver halide emulsion (99.5 mol. % chloride, 0.5 mol. % bromide, average grain diameter 0.6 μm) prepared from 0.58 g of AgNO3 with 1.08 g of gelatine 0.52 g of magenta coupler M-1 0.24 g of dye stabiliser ST-2 0.10 g of dye stabiliser ST-3 0.25 g of dibutyl adipate 0.25 g of isooctadecanol Layer 5: (UV protective layer) 1.15 g of gelatine 0.2 g of UV absorber UV-1 0.2 g of UV absorber UV-2 0.2 g of oil former OF-3 0.07 g of compound SC-1 0.07 g of compound SC-2 0.04 g of TCP Layer 6: (Red-sensitive layer) Red-sensitised silver halide emulsion (99.5 mol. % chloride, 0.5 mol. % bromide, average grain diameter 0.5 μm) prepared from 0.30 g of AgNO3 with 0.75 g of gelatine 0.2 g of UV absorber UV-1 0.36 g of cyan coupler C-1 0.12 g of dye stabiliser ST-4 0.24 g of TCP Layer 7: (UV protective layer) 0.35 g of gelatine 0.15 g of UV absorber UV-3 0.15 g of oil former OF-4 Layer 8: (Protective layer) 0.9 g of gelatine 0.3 g of hardener H-1______________________________________
The following compounds were used in the layer structure of Example 1: ##STR22## Samples 2 to 14
Samples 2 to 14 were produced in the same manner as sample 1, except that compounds Y-1, SC-1, SC-2 and M-1 in layers 2, 3, 4 and 5 were replaced by those stated in table 1. Moreover, the applied quantity of silver in layer 4 was reduced to 0.28 g in samples 4 to 9 and to 0.22 g in samples 10 to 14.
TABLE 1______________________________________(C: comparison; I: invention) [Quantity in mg/m2] Sample no. Layer 2 Layers 3 & 5 Layer 4______________________________________ 1 (C) Y-1 [550] SC-1/SC-2 [70/70] M-1 [520] 2 (I) Y-1 [550] I-1 [140] M-1 [520] 3 (I) Y-1 [550] I-5 [140] M-1 [520] 4 (C) Y-1/Y-2 [450/100] SC-1/SC-2 [70/70] M-2 [250] 5 (C) Y-1/Y-2 [450/100] SC-3 [140] M-2 [250] 6 (I) Y-1/Y-2 [450/100] I-4 [140] M-2 [250] 7 (I) Y-1/Y-2 [450/100] I-12 [140] M-2 [250] 8 (I) Y-1/Y-2 [450/100] I-24 [140] M-2 [250] 9 (I) Y-1/Y-2 [450/100] I-26 [140] M-2 [250] 10 (C) Y-3 [520] SC-2 [140] M-3 [140] 11 (C) Y-3 [520] SC-3 [140] M-3 [140] 12 (I) Y-3 [520] I-9 [140] M-3 [140] 13 (I) Y-3 [520] I-15 [140] M-3 [140] 14 (I) Y-3 [520] I-28 [140] M-3 [140] 15 (I) Y-3 [520] I-30 [150] M-3 [140]______________________________________
One sample of each was exposed through a grey wedge with blue, green or red light and processed as follows:
______________________________________a) Colour developer - 45 s - 35� C.______________________________________ Tetraethylene glycol 20.0 g N,N-diethylhydroxylamine 4.0 g (N-ethyl-N-(2-methanesulphonamidoethyl)-4-amino-3- 5.0 g methylbenzene sulphate Potassium sulphite 0.2 g Potassium carbonate 30.0 g Polymaleic anhydride 2.5 g Hydroxyethanediphosphonic acid 0.2 g Optical brightener (4,4'-diaminostilbene sulphonic acid 2.0 g derivative) Potassium bromide 0.02 g______________________________________
make up with water to 1000 ml; adjust pH value to pH=10.2 with KOH or H2 SO4.
______________________________________b) Bleach/fixing bath - 45 s - 35� C.______________________________________ Ammonium thiosulphate 75.0 g Sodium hydrogen sulphite 13.5 g Ethylenediaminetetraacetic acid (iron-ammonium salt) 45.0 g______________________________________
make up with water to 1000 ml; adjust pH value to pH 6.0 with ammonia (25%) or acetic acid.
c) Rinsing--2 min--33� C.
d) Drying
The percentage cyan density (Dcyan) at a magenta density (Dmagenta) of 1.0 was then determined on the sample exposed with green light (table 2). All the samples were then exposed to the light from a daylight-standardised xenon lamp and irradiated with 15�106 lux�h. The percentage reduction in density ΔDyellow, ΔDmagenta and ΔDcyan after irradiation was determined at initial density D =1.0 (table 2).
TABLE 2______________________________________Sample % Dcyan at no. Dmagenta = 1.0 ΔDyellow [%] ΔDmagenta [%] ΔDcyan [%]______________________________________ 1 (C) 10.1 -32 -28 -36 2 (I) 9.9 -23 -27 -27 3 (I) 9.8 -24 -27 -28 4 (C) 7.5 -34 -59 -35 5 (C) 8.6 -25 -34 -26 6 (I) 7.3 -22 -32 -27 7 (I) 7.6 -24 -32 -27 8 (I) 7.5 -23 -33 -26 9 (I) 7.2 -23 -34 -27 10 (C) 5.6 -44 -31 -35 11 (C) 6.3 -30 -16 -28 12 (I)P 5.7 -28 -14 -26 13 (I) 5.4 -30 -15 -27 14 (I) 5.5 -29 -16 -27 15 (I) 5.4 -27 -15 -26______________________________________
As table 2 shows, the compounds according to the invention effectively prevent co-coupling without having a disadvantageous effect on colour stability.
Compounds used for the first time in samples 2 to 14: ##STR23##
A colour photographic recording material for colour negative development was produced (sample 15, comparison), by applying the following layers in the stated sequence onto a 120 μm thick, transparent cellulose triacetate film support provided with a coupling layer. Quantities are stated in g/m2. The applied quantity of silver halide is stated as the corresponding quantities of AgNO3. All the silver halide emulsions were stabilised with 0.1 g of 4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene per 100 g of AgNO3. The silver halide emulsions are characterised by the composition of the halide, and, with regard to grain size, by the median particle size by volume (VSP). The median particle size by volume has the dimension of a length [μm] and is determined using the equation: ##EQU1## wherein ni means the number of particles in the range i and di means the diameter of spheres of an identical volume for the particles in the range i.
__________________________________________________________________________Layer 1: (Anti-halo layer) Black colloidal silver 0.28 UV absorber UV-2 0.20 Gelatine 0.8 Layer 2: (Low sensitivity, red-sensitised layer) Red-sensitised silver bromide-iodide-chloride emulsion (2.4 mol. % iodide; 0.85 10.5 mol. % chloride; VSP 0.35) Gelatine 0.6 Cyan coupler C-2 0.3 Coloured coupler CR-1 2.0 � 10-2 Coloured coupler CY-1 1.0 � 10-2 DIR coupler DIR-1 1.0 � 10-2 Layer 3: (Medium sensitivity, red-sensitised layer) Red-sensitised silver bromide-iodide emulsion (10.0 mol. % iodide; 1.2 VSP 0.56) Gelatine 0.9 Cyan coupler C-2 0.2 Coloured coupler CR-1 7.0 � 10-2 Coloured coupler CY-1 3.0 � 10-2 DIR coupler DIR-1 4.0 � 10-2 Layer 4: (High sensitivity, red-sensitised layer) Red-sensitised silver bromide-iodide emulsion (6.8 mol. % iodide; 1.6 VSP 1.2) Gelatine 1.2 Cyan coupler C-3 0.15 DIR coupler DIR-3 3.0 � 10-2 Layer 5: (Interlayer) Gelatine 1.0 Layer 6: (Low-sensitivity, green-sensitised layer) Green-sensitised silver bromide-iodide-chloride emulsion (9.5 mol. % iodide; 0.66 10.4 mol. % chloride; VSP 0.5) Gelatine 0.9 Magenta coupler M-4 0.3 Coloured coupler MY-1 2.0 � 10-2 DIR coupler DIR-1 5.0 � 10-3 DIR coupler DIR-2 1.0 � 10-3 Oxform scavenger SC-2 5.0 � 10-2 Layer 7: (Medium-sensitivity, green-sensitised layer) Green-sensitised silver bromide-iodide-chloride emulsion (10.0 mol. % iodide; 1.4 VSP 0.56) Gelatine 0.9 Magenta coupler M-4 0.24 Coloured coupler MY-1 4.0 � 10-2 DIR coupler DIR-1 5.0 � 10-3 DIR coupler DIR-2 3.0 � 10-3 Layer 8: (High-sensitivity, green-sensitised layer) Green-sensitised silver bromide-iodide emulsion (6.8 mol. % iodide; 1.7 VSP 1.1) Gelatine 1.2 Magenta coupler M-5 3.0 � 10-2 Coloured coupler MY-2 5.0 � 10-2 DIR coupler DIR-3 5.0 � 10-2 Layer 9: (Interlayer) Polyvinylpyrrolidone 10-2 Gelatine 0.4 Layer 10: (Yellow filter layer) Yellow colloidal silver sol 0.1 Gelatine 0.8 Layer 11: (Low-sensitivity blue-sensitised layer) Blue-sensitised silver bromide-iodide emulsion (6.0 mol. % iodide; 0.4 VSP 0.78) Gelatine 1.0 Yellow coupler Y-4 0.4 DIR coupler DIR-1 3.0 � 10-2 Layer 12: (Medium-sensitivity, blue-sensitised layer) Blue-sensitised silver bromide-iodide-chloride emulsion (8.8 mol. % iodide; 15.0 mol. % chloride; VSP 0.77) 0.12 (12.0 mol. % iodide; 15.0 mol. % chloride; VSP 1.0) 0.28 Gelatine 0.77 Yellow coupler Y-4 0.58 Layer 13: (High-sensitivity, blue-sensitised layer) Blue-sensitised silver bromide-iodide emulsion (12.0 mol. % iodide; 1.2 VSP 1.2) Gelatine 0.9 Yellow coupler Y-4 0.1 DIR coupler DIR-3 2.0 � 10-2 Layer 14: (Protective layer) Micrate silver bromide-iodide emulsion (4.0 mol. % iodide; 0.25 VSP 0.05) UV absorber UV-4 0.2 UV absorber UV-2 0.3 Gelatine 1.4 Layer 15: (Hardening layer) Gelatine 0.2 Hardener H-1 0.86 Persoftal 0.04 Compounds used in Example 2:7 STR24## -8 STR25## -9 STR26## -0 STR27## -1 STR28## -2 STR29## -3 STR30## -4 STR31## -5 STR32## -6 STR33## -7 STR34## -8 STR35## -9 STR36##__________________________________________________________________________
The colourless and coloured couplers were each incorporated together with the same quantity of tricresyl phosphate (TCP) using known prior art emulsification methods.
Samples 16 to 18
The samples differ from sample 15 in that they additionally contain compounds of the formula (I) (g/m2) in layer 1. The samples were then exposed with daylight through a graduated grey wedge. The materials were then processed using the process described in E. Ch. Gehret, The British Journal of Photography 1974, p. 597. Relative red sensitivity and cyan fog were measured on the resultant samples. Table 3 shows the results.
TABLE 3______________________________________ Compound in Relative red Cyan Sample the 1st layer Quantity sensitivity fog______________________________________15 -- -- 100 0.30 Comparison 16 I-4 0.200 123 0.21 Invention 17 I-10 0.160 129 0.18 Invention 18 I-27 0.250 123 0.20 Invention______________________________________
Samples 19 to 24
Samples 19 to 24 differ from sample 15 in that 0.125 mmol of the compounds listed in table 4/m2 were additionally used in layer 5. Samples 23 and 24 instead respectively contained white couplers W-1 and W-2 in a quantity of 0.125 mmol/m2.
The samples were processed in the same manner as samples 15 to 18. Relative magenta density D1 was then measured at point E+logH after 3 days' storage at 20� C. and D2 after 3 days' storage at 60� C./90% relative humidity and the difference D2 -D1 and magenta fog (Dmin) after storage at room temperature were determined (E was determined at point 0.2 above fog). Table 4 shows the results:
TABLE 4______________________________________Sample Compound Dmin D2 -D1______________________________________15 none 0.70 0.25 Comparison 19 I-4 0.48 0.20 Invention 20 I-10 0.51 0.21 Invention 21 I-25 0.51 0.23 Invention 22 I-27 0.49 0.23 Invention 23 W-1 0.50 0.68 Comparison 24 W-2 0.51 0.83 Comparison______________________________________
White coupler W 2 is of the formula: ##STR37##
It may be seen from the results in table 4 that the compounds according to the invention reduce magenta fog without there being an increase in the difference D2 -D1. The difference D2 -D1 is a measure of the stability of the developed image as information may be deduced from it concerning changing print conditions on storage of the developed colour negative image.
|Cited Patent
|Filing date
|Publication date
|Feb 17, 1981
|Dec 28, 1982
|Agfa-Gevaert Aktiengesellschaft
|Color photographic recording material containing non-diffusing electron donor precursor compounds
|Mar 6, 1981
|Jan 18, 1983
|Agfa-Gevaert Aktiengesellschaft
|Photographic recording material for diffusion processes and useful non-diffusing sulfilimine compounds
|Apr 18, 1983
|Apr 24, 1984
|Agfa-Gevaert Aktiengesellschaft
|Photographic recording material for diffusion processes and new non-diffusing sulfilimine compounds suitable for use therein
|May 17, 1993
|Nov 22, 1994
|Ciba-Geigy Corporation
|3-(alkoxyphenyl)benzofuran-2-ones as stabilisers
|Nov 6, 1997
|Jul 23, 1998
|Agfa Gevaert Ag
|Colour photographic material useful for photographic film or paper
|Citing Patent
|Filing date
|Publication date
|Apr 7, 2000
|Sep 4, 2001
|Color photographic silver halide material
|Dec 12, 2000
|May 7, 2002
|Color photographic silver halide material
|Aug 9, 2000
|Jun 11, 2002
|Color photographic silver halide material
|Oct 31, 2001
|Aug 20, 2002
|Color photographic silver halide material
|Sep 9, 2002
|Apr 19, 2005
|Ciba Specialty Chemicals Corp.
|Stabilization of synthetic polymers
|Oct 11, 1999
|Jun 13, 2006
|Ciba Specialty Chemicals Corp.
|Color photographic material
|Sep 9, 2002
|Jun 12, 2003
|Kerstin Schrinner
|Stabilization of synthetic polymers
|U.S. Classification
|430/551, 430/543, 430/607, 430/502
|International Classification
|Cooperative Classification
|European Classification
|Apr 2, 1998
Owner name: AGFA-GEVAERT AG, GERMANY
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ODENWALDER, HEINRICH;LANGEN, HANS;HAGEMANN, JORG;AND OTHERS;REEL/FRAME:009107/0785;SIGNING DATES FROM 19980204 TO 19980209
|Apr 25, 2003
|Fee payment
Year of fee payment: 4
|Dec 17, 2004
Owner name: AGFAPHOTO GMBH, GERMANY
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:AGFA-GEVAERT;REEL/FRAME:016097/0410
Effective date: 20041122
|May 30, 2007
|Maintenance fee reminder mailed
|Nov 9, 2007
|Lapse for failure to pay maintenance fees
|Jan 1, 2008
|Expired due to failure to pay maintenance fee
Effective date: 20071109


text:
Quality Inn Hemet, Temecula
- Free buffet breakfast, free WiFi, and free parking
Main amenities
- 54 guestrooms
- Outdoor pool
- 24-hour front desk
- Coffee/tea in common area
- Air conditioning
- Daily housekeeping
- Front desk safe
- Laundry service
- Meeting rooms
- Multilingual staff
- Free newspapers in the lobby
- Luggage storage
For families
- Free cribs/infant beds
- Microwave
- Refrigerator
- Private bathroom
- Premium TV channels
- Free toiletries
What's around
- Heart of Hemet
- Valley Wide Regional Park (2.1 mi / 3.3 km)
- Ramona Bowl Amphitheatre (3.3 mi / 5.4 km)
- Diamond Valley Lake Marina (4.5 mi / 7.3 km)
- Western Science Center (4.5 mi / 7.3 km)
- Mt. San Jacinto College (4.7 mi / 7.6 km)
Quality Inn Hemet, Temecula
Hotel Info: 866-539-8117from $79
- Standard Room, 2 Queen Beds, Non Smoking
- Standard Room, 1 King Bed, Non Smoking
- Standard Room, 1 King Bed, Non Smoking, Hot Tub
- Standard Room, 1 King Bed, Smoking
Also popular with travelers from the USA
At a glance
Key facts
Hotel size
- This hotel has 54 rooms
- This hotel is arranged over 2 floors
- Check-in time 2 PM-6 AM
- Check-out time is 11 AM
- Express check-in/out
Required at check in
- Credit card or cash deposit required
- Government-issued photo ID required
Travelling with others
- Up to 2 children (13 years old and younger) stay free when occupying the parent or guardian's room, using existing bedding
- Pets allowed (dogs and cats only) *
- Specific rooms only *
- 2 per room (up to 44.09 lb)
- Free WiFi and wired Internet access in public areas
- Free WiFi and wired Internet access in rooms
- Free self parking
- RV/bus/truck parking
Other information
- No alcohol served onsite
Nearby Two Star Temecula hotels
In the hotel
- Free buffet breakfast
- Coffee/tea in common area
- Outdoor pool
- Spa tub
- Meeting rooms
- One meeting room
- 24-hour front desk
- Dry cleaning/laundry service
- Laundry facilities
- Free newspapers in lobby
- Luggage storage
- Multilingual staff
- Safe-deposit box at front desk
- Accessible bathroom
- In-room accessibility
- Roll-in shower
In the room
- In-room climate control (air conditioning)
- Air conditioning
- Coffee/tea maker
- Iron/ironing board
- Premium bedding
- Private bathroom
- Shower/tub combination
- Free toiletries
- Hair dryer
- Pay movies
- Premium TV channels
- Free weekday newspaper
- Free WiFi
- Free local calls
- Refrigerator
- Microwave
- Daily housekeeping
Top Temecula hotels
Recently reviewed hotels in Temecula
- La Quinta Inn & Suites Moreno ValleyFrom
"Ten minutes from the University of Riverside. Easy freeway access. Staff was friendly, and very helpful. Checking was quick. Beds were comfortable. Room was clean. "Jun 17, 2016
- Ramada Temecula Old TownFrom
"The hotel is not really bad but I think we have bad luck because it was very noisy and the room had a bad odor!"Jun 17, 2016
- La Quinta Inn & Suites TemeculaFrom
"even though there was an earthquake. ..we had great time "Jun 17, 2016
- Temecula Creek InnFrom
"To be honest I booked this hotel because it was one of the cheapest higher rated places to stay. It wasn't until after my visit that I realized how much of a deal I had gotten.…"Jun 16, 2016
Nearby hotels
Quality Inn Hemet, Temecula's small print
Also known as
- Quality Hemet
- Quality Inn Hemet
- Hemet Quality Inn
Pet-friendly rooms can be requested by contacting the property at the number on the booking confirmation.
This property does not have elevators.
The name on the credit card used at check-in to pay for incidentals must be the primary name on the guestroom reservation.
Optional extras
Pets are allowed for an extra charge of USD 20.00 per pet, per night
We have included all charges provided to us by this hotel. However, charges can vary, for example, based on length of stay or the room you book.
Is the description of this hotel not correct? Tell us

subset: commoncrawl


text:
Roseville neighbors protest towering duplexes
Builder continues work — bringing in fill dirt to "lower" height?
Julie Stalmer 7:15 p.m., June 25
Posted May 7, 2013
Will Barton was walking home late one night in October 2012 when Philip Martin Hernandez, on a crime rampage with his young wife (Cindy Altamirano Garcia), shot him a few times and left him for dead. As he struggles to heal, health insurance companies create barriers.
Julie Stalmer 7:15 p.m., June 25
Ken Harrison 3:35 p.m., June 25
Walter Mencken 2:02 p.m., June 25
Josh Board 12:58 p.m., June 25
Charlie Morgenstern 11 a.m., June 25
Jay Anderson 10:30 a.m., June 25
Dave Rice 9 a.m., June 25
© 2016 San Diego Reader. All rights reserved. No part of this site may be reproduced without our written permission.
Each newsletter subscription means another chance to win!Close


text:
Barricade and Blueblood · 2:47pm
Well. I've thought about this for a while, and have decided that this is how I'll handle Barricade and Blueblood from now on.
For stories where I've already established my OC Captain Barricade as Fluttershy's mother, those shall be considered alternate universe stories.
However, I like Barricade a lot. So she will be featured in future stories that have Fluttershy's canon mother. Only in those stories, Barricade will be Fluttershy's aunt.
As for Blueblood...
Me liking the idea of Blueblood as a good guy is a fairly recent thing. However there are some older, incomplete stories I've written that have him as a complete jackass. Those stories will not change, nor will my characterization of Blueblood in those stories. And if in future stories I need Bluey to be a jerk, he will be. However, most likely I will be writing Blueblood in a more positive light from now on.
Anyway. Just wanted to get that out there.


text:
North Queensland connectivity wars
Townsville has won the battle of north Queensland connectivity, being described by NBN Co as "the most NBN ready place in Australia."
- Print page
- Email this
- Permalink
Angus Kidman, editor of Life Hacker Australia, says Townsville's National Broadband Network status has made it an even more desirable place to be.
"There is more chance of getting a connection there, so when you combine that with the fact that Townsville is a nice place to live, it is a very logical place to be on the top of that list," he said.
Why did they choose Townsville for the NBN?
Mr Kidman says Townsville was "lucky" to be one of the first places in Australia to receive the NBN.
"When the NBN was first announced in its original form, it was always known that it wouldn't come to everywhere at once," he said.
He says there was a conscious effort to choose regional cities because metros generally already have better connectivity.
"Townsville essentially got lucky ... and that means Townsville was one of the first sites anywhere in Australia to start having NBN stuff built," he said.
The future of the NBN in Cairns
Mr Kidman says Cairns has received some NBN infrastructure in the CBD and there are advanced build plans for the next ring around the city.
"It seems pretty likely that those build plans will go ahead and fibre will go into those areas, but they might decide to cut it off short at the exchange level, rather than bringing it to the premises, meaning reduced speeds between the exchange and the premises," he said.
Mr Kidman says the type of internet connection available is a growing influence on where people choose to live.
"I do think it is something that is going to influence where people live and, as is the way with these things, that is ultimately going to influence the value of some properties," he said.
Is the fibre worth it?
Mr Kidman says the upgraded connection is not so much about the things we already use the internet for, but the things we haven't thought of.
"If you have got a good fibre connection, it really does improve things because the consistency and reliability mean you can do new things," he said.
He says most people focus on the download speeds, but the real benefits are in the upload speeds.
"If you want to share something, if you want to send videos to families or friends or business associates, that is much easier and you find you do it more, and it changes the way you think about doing things," he said.
- Arts and Entertainment
- Business, Economics and Finance
- Community and Society
- Defence and National Security
- Disasters and Accidents
- Education
- Environment
- Government and Politics
- Health
- Human Interest
- Information and Communication
- Law, Crime and Justice
- Lifestyle and Leisure
- Rural
- Science and Technology
- Sport
- Unrest, Conflict and War
- Weather
Latest videos
- Massive python found in Mission Beach bedroom
- Authorities reassure Aurukun community that students won't fall behind
- A woman is missing, feared dead, after a late night swim on a far north Queensland beach
- Bill Shorten pledges $500 million for Great Barrier Reef
- (Warning: Confronting images) Footage of Aurukun women fighting in the street
Latest audio
- Horticulture 'snack' attack
- Martin Kneebone (Fresh Logic) and vegetable growers David Moon, Geoff Story and Andrew Dewar talk about the future of horticulture production on the G
- Craig Zonca and Kallee Buchanan talk women in horticulture, intellectual property and food innovation at the Horticulture Convention 2016
- Agri sector says it's a scapegoat for Great Barrier Reef damage as Qld Govt buys cattle station
- Collaboration between growers, millers and researchers is credited with saving the sugar industry from smut


text:
Sergei Rachmaninoff was born in Oneg, Russia, in 1871. His first piano teacher was his mother, who began teaching young… read moreJune 28th
Stanton's is thrilled to announce the 30th ANNIVERSARY CELEBRATION of The Joy of Singing – two full days… read more
Stanton's has built a reputation as "The Sheet Music Specialists".
Can't attend one of our clinics? Visit Stanton's Virtual Workshop.
In just a few minutes you can have your favorite song printed and ready to play.
Online Service for Music Educators.
Title: Joyful Joyful We Adore Thee
Voicing/Format: Handbells 3-5 Octaves
Publisher: Beckenhorst Press Inc
Arranger: Page, Anna Laura
Catalog #: HB413
Grade: 3 Price: $4.50


text:
Products/Services for Neon Inverter
Dumpers, Tilters, and Inverters - (361 companies)Dumpers, tilters and inverters are used to reposition or empty material handling containers. Dumpers and tilters empty containers (boxes, drums, bins, etc.) by tilting them to allow materials to pour out below. Inverters (upenders) take...Show MoreEquipment TypeBulk Container TypeWeight Capacity
DC-AC Inverters - (636 companies)How to Select DC to AC Inverters. DC/AC Pure Sine Wave Inverter. Image Credit:Analytic Systems Inverter Image Credit: Digi-Key. DC to AC inverters are used for converting direct current (DC) into alternating current (AC). They are also known as DC...Show More
Solar Inverters - (133 companies)Solar Inverters or Photovoltaic (PV) Inverters are electrical devices that convert the direct current (DC) produced by a PV device (cell or array) into alternating current (AC). Solar Inverters Information. Solar inverters or photovoltaic (PV...Show More
Lighting Inverters - (38 companies)Lighting inverters provide alternating current (AC) power for indoor, outdoor and emergency lighting, signage, and associated controls. They are used in conjunction with power supplies and power conditioners, and provide permanent lighting...Show More
Helium Neon Lasers - (36 companies)Helium neon (HeNe) lasers have an emission that is determined by neon atoms by virtue of a resonant transfer of excitation of helium. They operate continuously in the red, infrared and far-infrared regions and emit highly monochromatic radiation...Show More
Power Supplies - (2810 companies)...a DC output voltage from a DC input voltage. Strictly speaking, these devices are converters that convert a DC voltage into another DC voltage with different magnitude. DC-AC converters (inverters) - These devices produce AC voltage from a DC input...Show More
Voltage Converters and Voltage Inverters - (147 companies)Voltage Converters and Voltage Inverters Information. Voltage converters and voltage inverters accept voltage input and provide a scaled voltage output. Conversion types include scaling up a low-level signal, voltage doubling, and inversion...Show More
Ballasts - (447 companies)...for a particular lamp. Description. Ballasts are power supplies or transformers for fluorescent lamps, light sources that consist of a glass tube filled with argon, neon, or other inert gas. When ballasts supply electrical current, the resulting arc...Show More
DC-AC Inverter Chips - (21 companies)DC-AC inverter chips transfer a DC input into AC power by using switching, inversion, or other technology. How to Select DC to AC Converter Chips. Image Credits: JKL Components Corp., Unipower Corp. DC to AC converter chips transfer DC inputs...Show More
Transformers - (1907 companies)Transformers are electrical devices that are designed to transfer energy from one circuit to another by electromagnetic induction. They are used typically to increase or decrease voltage as it passes from one side of the device through the other.Show More
Product News
Econo Lift Limited
Custom Dumpers, Tilters, and Inverters Econo Lift Limited manufactures custom dumpers, tilters, and inverters to match your specifications. (read more)Browse Dumpers, Tilters, and Inverters Datasheets for Econo Lift Limited
CE+T America
High Efficiency Inverters Systems CE+T Power manufactures high efficiency DC-AC inverters systems to match your specifications. If you have a specific cabinet in which the inverter system must be integrated, let us know!. We can either build it for you or help you integrating our high efficiency modular inverters in your cabinet! (read more)Browse DC-AC Inverters Datasheets for CE+T America
Parker Hannifin / Fluid Connectors / Fluid System Connectors
Inverted Flare Fittings Parker's economical inverted flare fittings resist mechanical pullout and can be assembled and disassembled repeatedly. Listed with UL for flammable liquid and gas. Meets functional requirements of SAE J512, ASA and MS (Military Standards). Use with copper, brass, aluminum and welded steel hydraulic tubing that can be flared. (read more)Browse Tube Fittings Datasheets for Parker Hannifin / Fluid Connectors / Fluid System Connectors
Armstrong International
Inverted Bucket Steam Traps The inverted bucket is the most reliable steam trap operating principle known. The heart of its simple design is a unique leverage system that multiplies the force provided by the bucket to open the valve against pressure. Since the bucket is open at the bottom, it resists damage from water hammer, and wear points are heavily reinforced for long life. The inverted bucket has only two moving parts-the valve lever assembly and the bucket. That means no fixed points, no complicated linkage... (read more)Browse Steam Traps Datasheets for Armstrong International
Fuji Electric Corp. of America
FRENIC-Mini (C2) Inverter Fuji Electric 's new FRENIC-Mini (C2) Series provides excellent performance for both single-phase and three-phase applications, and is available in multiple configurations to support 1/8 HP up to 20 HP AC drives / variable frequency drives (VFD) / v/ Hz vector drives. With an expanded range of rated voltages, the new FRENIC-Mini (C2) strikes an optimal balance between price and performance. (read more)Browse AC Motor Drives Datasheets for Fuji Electric Corp. of America
Mitsubishi Electric Automation, Inc.
FR-F800 Inverter The F800 Series is a VFD range which has been optimized for maximum energy savings with pump and fan control. F800 is equally at home in an industrial environment or in the residential / commercial sector as part of an integrated HVAC solution. NEMA 1 / UL-1 rated: F800 is Plenum-Rated and can be mounted as a stand-alone unit when required – no need to provide a separate enclosure*. Built-in BACnet MS/TP or Modbus RTU communications capability for simple integration into HVAC communication... (read more)Browse AC Motor Drives Datasheets for Mitsubishi Electric Automation, Inc.
CE+T America
Standalone Inverters Introduced by CE+T Lower power needs should not mean less efficiency. When the output power need is low, redundancy and modularity are generally not needed, but why should efficiency also be reduced?. The Y-One standalone inverter was developped using our TSI Technology, which will bring you the same features and benefits as in our Modular Inverters product range : high efficiency. multi-source energy conversion. no single point of failure. no transfer time. Static switch function included. Typical Applications... (read more)Browse DC-AC Inverters Datasheets for CE+T America
CE+T America
Winning inverter @ Google IEEE LittleBoxChallenge IEEE) in search of a new technology that could successfully shrink an inverter from the size of a cool-box to the size of a small laptop. CE+T Power 's innovative solution is a huge improvement on the competition 's original specification of 50W per cubic inch. Boasting a powerful 145W per cubic inch, the CE+T Power winning design is also only 13.77 cubic inches in size – smaller than a block of post-it notes, which is far smaller than the brief requested – and uses... (read more)Browse DC-AC Inverters Datasheets for CE+T America
APM Hexseal Corp.
Inverted Bellows Toggle Switch Boot Avoid unintentionally tripping a sensitive breaker/switch into the on/off position by attaching the patented APM Hexseal 1131/60 or 1132/60 inverted bellows toggle switch boot. There are an increasing number of breaker/switches that when covered with an environmental sealing switch cover can trip the breaker/switch into the off/on position due to the mere physics of being covered by the wrong type of cover. Our "Ultra Flex Series " with a bellows design incorporated therein... (read more)Browse Self-sealing Fasteners Datasheets for APM Hexseal Corp.
CE+T America
CE+T's Alto : 20kVA Modular Inverter Following a trend in demand for high power AC Backup Solutions, CE+T Power has developed a compact 20 kVA Modular Inverter, called the ALTO. Description. ALTO is a compact and scalable modular inverter providing a pure sine wave AC supply. Leveraging the existing DC Power system, it provides an excellent high power AC backup solution. It uses the latest inverter technology, providing superior energy efficiency in a compact size. The "Twin Sine Innovation " (TSI) technology... (read more)Browse DC-AC Inverters Datasheets for CE+T America
Low power strategy for a TFT controller
… also introduce the possibility to power down the DAC module (that drives the CRT analogue outputs), when the system is in a low-power configuration and the possibility to disable the clock of the CCFT (backlighting neon ) inverter if we use an …
Catalysis-assisted plasma technology for carbon tetrachloride destruction
The power supply used for these experimentswas either a 50-H~neontrans- former or an 18-kHz inverter neon transformer.
Catalysis-assisted plasma technology for carbon tetrachloride destruction
The power supply used for these experiments was either a 50-Hz neon transformer or an 18-kHz inverter neon transformer.
Paul trapping for micro-particles and its application for crystal growth
Coil Neon voltage inverter IOOY .
Resonance inverter power system for improving plasma sterilization effect
In this study, commercial AC power at 380[V], 60[Hz] is boosted up to 12[kV], 60[Hz] by means of voltage type inverter and neon transformer under the influence of DC voltage without any ripple as induced by diode rectifier …
An experimental study about the treeing phenomena in XLPE subjected to distorted voltages
In the recent years, the number of electrical devices (computers, neon lamps, inverter drives, etc) which cause, in power AC networks, important harmonics has been increasing, so that the effect of such harmonics on the AC voltage waveforms is gaining further and …
Introduction of a severity voltage parameter in a PD testing procedure of enamelled wire twisted pairs
In the recent years, the number of electrical devices (computers, neon lamps, inverter drives, etc), which cause - in power AC networks - the presence of important harmonics, has been increasing, so that the effects of such harmonics on the voltage waveforms is gaining …
Decomposition of Adsorbed Xylene on Adsorbents Using Nonthermal Plasma With Gas Circulation
An ac 60-Hz neon transformer and an inverter -type neon transformer are used for the generation of the nonthermal plasma.
Bench-Scale Test of Toluene Decomposition Using Adsorption and Surface Discharge with Gas Circulation
In the previous study, a xylene decomposition system that combines a process of adsorption with a process of decomposition by nonthermal plasma with gas circulation using ac 60 Hz and inverter -type neon transformers was investigated [23].
CR4 - Thread: electro-mechanical experiment
A cheap way( do demonstrate your experiment) would be to use a conventional 12 volt DC to 120 v AC inverter and run it through a neon transformer (for neon lights) in order to step it up to around 7 to 15KV.


text:
Shorts amateur teensTeen amateurs get sexual experience fucking hard in various positions
Blondes fingering fishnetBitchy blonde in fishnet stockings pees and gets cunt fisted
Blowjob brunettes coupleBlack dude squeezes black butt of Porshe Carrera and fucks her twat
Babes cum in mouth cumshotTwo sluts get fucked awesomely hard by a group of dudes
Anal blondes braFlawless milf oils up herself and drills anal with big toys
Anal blondes close upSlutty blonde Niky Verona gets a rim job and anal fuck in a garage
Babes high heels long hairTall babe in heels fucks herseld shitless with a huge dildo
Couple fingering hot assMilf with huge fake bubbles Carrie Ann gets her asshole fucked by BBC
Amateur reality partyDrunk girl fucked on waterbed
Group orgy jav (japanese adult video) japaneseJapanese Ass Tv Show Contestants In Traditional Kimonos
Spy peeSpy pee train
Bdsm bondage fetishPretty hot babe gets punished and fucked in bondage
Asian bus publicHorny Office Slut Getting Her Pussy Fucked In Bus
Party drunk hotDrunk girl fucked on party
Outdoors cowgirl woodsCowgirl with giant titties fucking in the woods
Babes blowjob cowgirlTwo slutty nurses get naked to fuck a fat male patient
Party public realityReal Teen In Group Hard Core Fucking In A Party
Bdsm bondage tortureEnslaved teen bitch gets tortures and fucked in a missionary
Asian jav (japanese adult video) natural boobsGorgeous Japanese Housewife Fucks In Front Of Her Husband
Public realityThin youthfull babe in public fuckfest video
Amateur coed college girlAll Natural College Student Gets Fucked In Her Dorm Room!
Jav (japanese adult video) japanese school uniformNerdy Asian Schoolgirl Fucks In A Library
Babes blowjob close upPigtailed babe gets her wet twat fucked in a locker room
Hidden cams public realityHidden Cam Caught Couple Fucking In Alley
Gyno clinic doctorGym girl visits gyno clinic
Ass fuck fuckingGot caught fucking in public
Fat chubby largeBeautiful bbw gets fucked in both holes and jizzed on
Amateur hidden cams homemadeHidden Camera Catches Couple Fucking In The Dark
Jav (japanese adult video) japanese officeBusty Milf Gets Her Asian Pussy Fucked In Office Room
Amateur babes blowjobHorny amateur couple Izabella and Kristof fuck in various positions
Amateur cumshots public nudityYoung Teen Girl Fuck In Car In A Public Place
Anal teensPizza girl fucked in the ass
Amateur sleep girlAmateur sleep girl fuck in bed
Foot fetish german stockingsGerman girl fucked in pantyhose and stockings
Anal emo girlEmo girl fucked in the ass for money
AsianAsian Girl Fucked in The Car
Amateur hidden cams realityHidden Cam Catches Couple Fucking In Hotel
Ass fuck teenagerPetite girl fucked in the wc
Amateur hidden cams homemadeHidden Spy Cam Catches Couple Fucking Doggystyle
Hidden cams public realityAmatuer Girl Fucked In The Canteen Caught In Hidden Camera
Amateur hidden cams homemadeHidden Cam Caught Couple Fucking In The Hotel Room
Horny asian girlHorny asian girl fucked in motel
Hidden camsHousewife Spy Cam In Fitting Room!
Amateur oral blowjobSpy cam catches girl giving a blowjob
Asian doggystyle jav (japanese adult video)Pretty Girl Fucked In Her Favorite Missionary Position
Babes big tits blowjobPretty teen girl fucked in a hayloft by a dirty-minded guy
Latin nipples titsLatina girl fucking in the kitchen
Amateur hidden cams voyeurSpy Spanish Hot Girl Fucks for a Job
Hardcore hidden cams voyeurHidden cam fuck in bathroom
Busty ass fuckBad girls fucked in the ass
Asian blowjob doggystyleYoung Asian Girl Fucked In The Locker Room
Ass fuck teenagerDrunk russian girl fucked in ass
Anal double penetration interracialSweet Teen Fucked In Every Hole
Indian busty indiansHot indian girl fucked in the office
Big boobs close-ups maturesGrandma with big tits fucked in the bathtub
Homemade blow jobA girl fucks in public for some money
Amateur matures public nudityWife fucked in a car husband is filming
Amateur anal germanAmazing german amateur girl fucks in bed with BF
High heels ebony long hairCurvy ebony pornstar on high heels is going to fucked in a DP style
Lesbian girl teenagerLesbian girls fucking in rose bath
Gushinglesbos gushinglezzies lesbiansLesbian dildo fucking in kitchen free part2
Blondes babes realityReality video of amazing blonde girl fucked in a doggystyle
Brunette horny girlBrunette getting fucked in the kitchen
Hairy matures russianHairy mom mature russian fuck in bathroom troia bello duro per bene in fondo al culo e spacca tu
Ass fuck fuckingCaptive girl fucked in the forest
Anal facialsBrunette fucked in all wholes en gets facial
Asian hidden cams teensSpycam Girl Fucked during health massage Part 2
School girl fuckedTori black school girl fucked
Homemade ass fuckTeenage girl fucked in ass
Bdsm femdom mistressAwesome Group Outdoor Travel Fucking Hot
Dp penetration babeVenus gets double penetrated and defaced
Amateur homemadeNovice Teen Girl Jerks Off Big Cock And Sucks It Til It Cums
Asian cumshot facialSexy Little Asian Girl Takes A Mouthful Of Cock
Bathroom blowjob threesomeGirls With Big Racks Clean The Bathroom And A Cock


text:
lpn jobs near Las Vegas, NV
Refine your searchClear Filters
Date Added
More Filters
HHA and LPN for home health continuous care patient
AdvisaCare Home Health Care - Las Vegas, NV
At AdvisaCare, we believe each patient is as unique as the care they need so our goal is to offer the right care, customized to each individual, honoring his or...
RN Clinical Supervisor
AdvisaCare Home Health Care - Las Vegas, NV
RN or LPN License. Provide nursing assessments and develop Plans of Care for all current and future patients. A "Can do" Attitude....
On Call Registered Nurse
CompassionCare Hospice - Las Vegas, NV
Considerable reaching, stooping, bending, kneeling and/or crouching. No one should travel the end-of-life journey without compassion, comfort, and support....
RN or LPN (Registered / Licensed Practical Nurse)
Maxim Healthcare Services - Las Vegas, NV
Benefit eligibility is dependent on employment status. Maxim Healthcare Services is a leading provider of home healthcare, medical-related staffing, travel...
LPN (Licensed Practical Nurse)
Maxim Healthcare Services - Las Vegas, NV
Benefit eligibility is dependent on employment status. Maxim Healthcare Services is a leading provider of home healthcare, medical-related staffing, travel...
Boulder City Hospital - Boulder City, NV
Makes hourly rounds on patients or more frequent as needed to ensure safety, perform assessments, reporting significant changes to the Nurse Manager or...
Licensed Practical Nurse (Vocational) - SNF
Premier Health and Rehabilitation Center of Las Vegas - Las Vegas, NV
Current Nevada LPN license. To deliver nursing care to patients requiring long-term acute care. Premier Health and Rehabilitation Center is a 100 – bed Level II...
Registered Nurse (RN)/Licensed Practical Nurse (LPN)
Advent Home Health - Las Vegas, NV
Seeking a per-diem licensed RN and LPN preferably with Home Health experience to administer skilled nursing care to patients on an intermittent basis in their...
Licensed Practical Nurse (LPN) / Licensed Vocational Nurse (LVN)
MENTOR NETWORK - Las Vegas, NV
With program locations throughout the Western United States, CareMeridian offers a distinctive service delivery model, merging an experienced and skilled health...
LPN (Licensed Practical Nurse)
ROYAL SPRINGS HEALTHCARE AND REHAB - Las Vegas, NV
Record time spent performing individual treatment in accordance with ancillary services policy anon the medication / treatment record if applicable....


text:
"Tonight's results are not going to alter Gov. Kasich's campaign plans. Our strategy has been and continues to be one that involves winning the nomination at an open convention," Mr. Weaver said.
Ted Cruz suspends White House bid →
In a separate statement, Kasich chief strategist John Weaver said that "given the current dynamics of the primary [in Indiana], we will shift our campaign's resources West and give the Cruz campaign a clear path in Indiana."
Ted Cruz, John Kasich campaigns join forces to stop Donald Trump →


text:
On Tuesday, June 21st, we were able to once again participate in the annual SOAR Farmer's Market. This year was a success as the big cheesecake disappeared within ten minutes of the initial cut. Dan Alderman had the honor of cutting the first piece. Each year the cake is a big hit and we always come prepared to serve the crowd as much cheesecake as possible. This year we also served boxes full of Eli's Single Serve Strawberry Swirl Cheesecake.
In addition, Maureen Schulman, author of the Eli's Cheesecake Cookbook, held a book signing and customers were able to purchase the cookbook and ask questions.
It is a great joy to see the smiles on peoples' faces after they take a bite out of our cheesecake. We are here to please and are happy to celebrate the start of SOAR's Famer's Market.
This Sunday (June 19, 2016) is Eli's 12th Annual Father's Day 10 Mile Bike Ride! Please join us as we celebrate with the beautiful weather. This bike ride with begin at Eli's Cheesecake World on Sunday morning at 8:45 AM. A free continental breakfast and t-shirt will be available for participants. Riders must be able to maintain a safe speed of at least 6mph during the bike ride.
Make sure to register online at http://bit.ly/1UOkAPu, or contact Sharon Mrowiec at firstname.lastname@example.com OR 773-308-7015 by Friday, June 17th!
Nervous your bike is not in good condition? Get a free safety inspection and 20% off all helmets any day prior to the ride at: Rudy's Cycle & Fitness. (5711 Irving Park Road, Chicago, IL 60634)]]>
What is the best way to kick off the summer? Attending a Farm Stand and Fresh Market, of course! On June 16th, 2016 from 7am-1pm, Eli's Cheesecake will be hosting the grand opening celebration for Eli's new Farmer's Market. The day's activities include a complimentary breakfast buffet from 8am-10am, a ribbon-cutting ceremony at 10am, and a presentation by Jenny Yang from Phoenix Bean.
The Farmer's Stand & Fresh Market is open Thursdays from June 16th-August 25th, 7am-1pm. A variety of fresh fruits and vegetables from Nichol's Farm & Orchard and other great vendors will be featured. Different special events, activities, and speakers will be at each Farm Stand & Fresh Market day. Follow Eli's on social media for more information.
Come and join us for the kick off (June 16th) and every Thursday at Eli's Cheesecake World.]]>
This year we were able to showcase our new cookbook, with the opportunity to purchase at the NRA bookstore. The cookbook premiered coincided with the 35th anniversary of Eli's Cheesecake. The cookbook offers 40 unique recipes from desserts to recipes from Eli's famous steakhouse.
This year at the NRA Show, we introduced eight new products varying from cheesecakes to tarts to a dessert bar. The cheesecakes featured above are the Cookie Butter Cheesecake, made with GMO free ingredients (on the left) and the Chocolate Hazelnut Crunch, made with gluten free ingredients (on the right). For the foodservice industry, distributors, and operators: find more information at http://foodservice.elicheesecake.com/.
StoryTeller Ryan from WCIA 3 visited our booth this year and captured great footage of our products. We are also lucky to host students from the Chicago High School for Agricultural Sciences (CHSAS) at our booth each year to share information about our finest ingredients, such as Wildflower honey, harvested by CHSAS and Nielsen Massey vanilla.
We are already planning for another sensational year for the NRA Show 2017!
On Friday, May 13, 2016 Eli's Cheesecake participated in GNMAA Magnificent Mile's Annual Gala, "Mad About the Mile." The Mag Mile's Annual Gala serves as a fundraiser to provide grants and other financial awards to educational programs as well as neighborhood causes in The Magnificent Mile Neighborhood. It is one of the largest fundraisers of the year! Eli's has been a proud attendee for the past couple of years and this year, Eli's Cheesecake provided a wide selection of desserts for the attendees. Eli's provided three classic cheesecakes–Original Plain, Chocolate Chip, and Strawberry. Aside from cheesecakes, Eli's provided cuties for dessert–our house made Fudge Brownie, Michigan Cherry Oat Bar, and 7-layer Coconut bar.
Check out some of the photos from the event:]]>
At Eli's Cheesecake, we always schedule our Job Shadow visit by food science students for early May. This year, it was on Tuesday, May 10th. The students started the day with a continental breakfast, hosted by Eli's President Marc Schulman. After, they enjoyed an introduction to Eli's history and products by Eli's VP of Marketing, Debbie Marchok, and a short program about our Good Manufacturing Practices (GMPs). After the educational presentations, the CHSAS students and their advisors toured Eli's Bakery with our VP of Purchasing and Operations, Jeff Anderson, where they shadowed the different operational areas to learn how we scale, mix, bake, cut, decorate, evaluate and pack Eli's Cheesecakes and desserts.
Eli's culinary team prepared a luncheon for the students under our Big Top, complete with Eli's desserts. Before lunch, the students competed in a cheesecake decorating competition where they hand-decorated their own cakes with techniques they learned from our pros. The winner was chosen by Laurel Boger, Eli's Executive Pastry Chef.
Congratulations to the Eli's Cheesecake Scholars for 2016 graduating from the Chicago High School for Agricultural Sciences. From left to right: Jeff Anderson (Eli's); Dr. Charles Guengerich (President Emeritus Wright College); Andrew William Peterson-Lipp; Samantha Brandtonies; Samantha Griffin; Keyana Tyiska; Jolene Worthington (Eli's); and Marc Schulman (Eli's).
The Eli's Cheesecake Company is a proud corporate sponsor of CHSAS and appreciates the time and commitment by the CHSAS staff, faculty and students.
At Eli's Cheesecake, culture matters. In honor of Cinco de Mayo, Eli's Cheesecake will be selling and sampling some Latin American-inspired sweets and treats. To make our celebratory sweets distinguishable, we have placed Mexican flags next to each of the items. Here's what you can expect to see and taste:
Our take on this classic Latin American dessert: Tres Leches (3-milk) cake features a Tender genoise soaked in the traditional three milks, layered with rich creamy mousse and topped with a dusting of cocoa create the perfect sweetness and density.
Mango Cheesecake Tart.
Our mango cheesecake tart features our newest flavor addiction–MANGO! Mangos are strongly tied to Mexico, as many are produced and distributed from there into the United States.
If you think our mango cheesecake tarts look delicious, wait until you try our Cookies con Mango!
Below is a list of all the associates who participated in the park clean-up:


text:
V.19 No.43 |
Stinky feet and metaphysical ghosts
Former Alibi Staffer signing novels tonight
By John Bear [ Fri Oct 29 2010 12:34 AM ]
A former Alibi writer will be at the Wyoming Hastings Friday night (10.29) to sign his novels.
Dennis Domrzalski, former Tribune and Weekly Alibi journalist, and current N.M. Business Weekly staff writer will be selling copies of Volumes one and two of his Stinky Feet novels.
E.J. "jami" Morgan, another former journalist and P.I.O., is signing her brand new novel A Kindred Spirit, a metaphysical ghost story, just in time for
They'll be at Hastings, 4315 Wyoming, NE, from 5:30 to 7:30 p.m.
Today's Events
Summer Reading Concert: Watermelon Mountain Jug Band at East Mountain Library
Bluegrass/country music performance.
Stanley Kee Trio • blues at Molly's Bar
Monthly Meeting of the Mind (& Brain) at Church of the Good Shepherd, UCCMore Recommended Events ››
Kombat Kitty @ Barley Rm • 7.1.2016
home | feature | news | film | music | art | food | classifieds | personals | staff | lo-fi | search
© 1996-2016 Weekly Alibi firstname.lastname@example.com
View mobile version


text:
Top infoTECH News
Software News
Hardware News
Security News
Networking News
infoTECH Editor's Pick
infoTECH Awards
What's Hot in Information Technology?
infoTECH Services
infoTECH Media Kit
Cloud Contact Center
IP Phones
IT Cyber Security Training
NextGen Content Delivery (CDN)
Power Protection
Software Licensing
Software Monetization
infoTECH News
[December 11, 2012]
PNC aware of some website problems after hacking group warns of new cyberattack
Dec 11, 2012 (The Pittsburgh Tribune-Review - McClatchy-Tribune Information Services via COMTEX) -- Some PNC Bank customers may experience difficulty logging onto the bank's website, following a warning from a computer hacking group that it planned cyberattacks on PNC and other large banks.
PNC spokeswoman Amy Vargo said on Tuesday that the Downtown-based bank was aware of some intermittent problems, but she encouraged customers to try logging again if they have trouble the first time.
A computer hacking group, which claimed responsibility for disruptive attacks on PNC Bank and a half-dozen other large U.S. banks in September, on Monday said U.S. banks would be hit again in coming days.
The al Qassam Cyber Fighters Group posted to an Internet message board that it would again target Downtown-based PNC, along with JPMorgan Chase, Bank of America, U.S. Bank and SunTrust in a second phase of attacks that previously cut access to bank websites.
In the September cyberattacks on PNC, the bank's consumer website was crippled for two days in what is known as a denial of service attack. The attacks flood a website with traffic in coordinated fashion, essentially preventing legitimate customers from gaining access.
"PNC is aware of the potential denial of service attack," Vargo said. "We are working with appropriate authorities to take precautions." PNC also communicated with customers through its Facebook page on Monday, saying it was aware of the possible attack but that no problems had been reported.
"Please be assured that PNC's website is protected by sophisticated encryption strategies that shield customer information and accounts," the Facebook message said. "We have no information regarding timing, duration or intensity of this potential threat. Please continue to follow our page for additional updates." The bank has said previously that attacks did not compromise customers' personal or financial information.
Experts have said denial of service attacks are meant to disrupt commerce.
In a CNBC interview in October, PNC CEO James Rohr said the bank had been "pummeled" by the cyberattacks.
"We had 38 straight hours of attacks on our systems, and we had the longest attack of all the banks. They just pummeled us," Rohr said.
Many large U.S. banks, including Bank of America, Wells Fargo & Co., U.S. Bank, JP Morgan Chase, Capital One and BB&T were hit with the same type of attacks in September and October.
The government has said it suspects Iran may be behind the attacks. But the Qassam group claims it is retaliating over an anti-Muslim video posted to YouTube that mocks the Islamic Prophet Muhammad.
"The people, whoever it is, supposedly it's Iran, have said that they're going to just continue these attacks," Rohr said.
Alex Nixon is a staff writer for Trib Total Media. He can be reached at 412-320-7928 or firstname.lastname@example.com.
___ (c)2012 The Pittsburgh Tribune-Review (Greensburg, Pa.) Visit The Pittsburgh Tribune-Review (Greensburg, Pa.) at www.pittsburghlive.com/x/pittsburghtrib Distributed by MCT Information Services
InfoTech Spotlight's Homepage
comments powered by Disqus.
blog comments powered by
infoTECH Headlines
Big Data at Your Doorstep
Solve Compliance Challenges in the Banking and Finance Industry with Information Management Technology Solutions
NetApp SolidFire Officially Announces Docker Volume Plug-In
Docker Opens Beta, Intros AWS, Azure Solutions
NetApp SolidFire Officially Announces Docker Volume Plug-In
Legacy Codebases Got You Down? Key Considerations for Modernizing Web Development
Manageability Overtakes Performance as Top Storage Concern in Annual State of Storage Survey
Deploying Technology to Your Global Sales Team? Don't Make This Mistake
Why Knowing How Your Apps are Performing is 'Mission Critical'
Focusing on Only the 'Big' in Big Data Could Reduce the Competitive Advantage and Opportunity it Offers Middle East Organizations
Subscribe to InfoTECH Spotlight eNews
InfoTECH Spotlight eNews delivers the latest news impacting technology in the IT industry each week. Sign up to receive FREE breaking news today!
FREE eNewsletter
Tech Culture Awards Status
Rich Tehrani
Brexit Could be Yuuuge for China
Rich Tehrani
Bitcoin, Blockchain and FinTech to the Brexit Rescue
Rich Tehrani
API of the Week: GoGo, IBM and Weather Company Reduce Flight Turbulence
Rich Tehrani
How Chicago Will Further Hurt its Job Market
Rich Tehrani
Editors Day Santa Clara 2015 Interview with Cloud Cruiser
Editors Day Santa Clara 2015 Interview with Cloud Cruiser
IoT Solutions Theatre: SemperCon
IoT Solutions Theatre: SemperCon
IoT Solutions Theatre: Raveon
IoT Solutions Theatre: Raveon
IoT Solutions Theatre: DropLit
IoT Solutions Theatre: DropLit
IoT Solutions Theatre: Lutmus Automation
IoT Solutions Theatre: Lutmus Automation
infoTECH Whitepapers
SAP Enterprise Mobility: Bringing a Cohesive Approach to a Complex Market
What is Your Mobile Content Policy? A Checklist for Content Risk Mitigation
SANS Whitepaper: Mobile Content and Document Management Best Practices and Decision Checklist
A Snapshot into Cloud Storage Adoption
What is Information Tehnology
What is Information Technology?
The History of Information Technology
Today's Most Desired Information Technology Skills
Information Technology Careers
Ten Information Technology Companies of 2011
Powered by
Technology Marketing Corporation,
800 Connecticut Ave, 1st Floor East,
Norwalk, CT 06854 USA
Ph: 800-243-6002, 203-852-6800;
Fx: 203-853-2845
Contact us
Technology Marketing Corp. 1997-<%= curyear %> Copyright.
infoTECH Resources
Editor's Pick
infoTECH News
Software News
Hardware News
Security News
Networking News
What's Hot
Media Kit
infoTECH Communities
Cloud Call Center
Call Recording
SIP Trunking
Unified Communications
infoTECH Channels
Cloud Contact Center
IP Phones
IT Cyber Security Training
Power Protection
Phone Systems
Software Licensing
Software Monetization
Virtual PBX
Workforce Management
Customer Support Software
Power Protection
Other Industries
IP Communications
Cable Spotlight
Satellite Spotlight
Smart Grid
Sports Techy
M2M Evolution


text:
Has President Obama Illegally Transferred Taxpayer Dollars to Relinquish Internet Control?2h By Susan WrightCrooked. What else is new?The post Has President Obama Illegally Transferred Taxpayer Dollars to Relinquish Internet Control? appeared first on RedState.
Ted Cruz Unloads On SCOTUS Over Abortion Ruling2h By Kimberly RossSenator Ted Cruz just delivered a blistering rebuke of the 5-3 SCOTUS abortion decision which was handed down this morning. Cruz, who Planned Parenthood has called "the biggest threat we face", continues to unashamedly stand for life. The…
Eric Trump Thinks You Are Just As Stupid As His Father Does (VIDEO)3h By streiffDoes his forehead have it's own ZIP Code?The post Eric Trump Thinks You Are Just As Stupid As His Father Does (VIDEO) appeared first on RedState.
Ben Sasse Destroys Washington Post's Biased, Pro-Abortion SCOTUS Coverage4h By Leon H. WolfAfter today's nonsensical and unconstitutional ruling by the high priests of abortion that Texas cannot regulate the safety and health of abortion clinics, the Washington Post took the opportunity to fete their favorite Supreme Court justice (Ruth Bader…
Watercooler 6/27/2016 Open Thread: Brexit4h By grumpy_old_soldierReflections on the Shock of Brexit …this is a verdict that parliamentarians or ideologues will not be able to challenge at some later date. It has ironclad political legitimacy. As our own recent troubles with the First, Second, and Fifth Amendments…
Polling Update: The Swing States are Still Swing States, There are Just a Lot More of Them1:31pm By Leon H. WolfThe 2012 election presented the clearest contrast in any election to date between the national polling and the state level polling. Up until the final days of the campaign, the national polls looked pretty favorable to Romney. The state level polls, on the…
BREAKING. Missouri's Democrat Governor Vetoes Constitutional Carry Law (VIDEO)1:21pm By streiffNothing terrifies a progressive apparatchik like a free citizenThe post BREAKING. Missouri's Democrat Governor Vetoes Constitutional Carry Law (VIDEO) appeared first on RedState.
Donald Trump Lies To the World About His Fundraising Total12:04pm By streifflielielielielielielielielielielielielielielieThe post Donald Trump Lies To the World About His Fundraising Total appeared first on RedState.
I Love George Will11:35am By Susan WrightNicely done, Sir.The post I Love George Will appeared first on RedState.
Iowa GOP Chair: Delegation To Go For Trump At Convention Despite Cruz Winning Iowa11:06am By Ulysses ArnOn Friday during a taping for Iowa Public Television Iowa Republican Party chairman Jeff Kaufmann announced that he has apparently rewritten Iowa's delegate rules and that the whole of Iowa's delegation to the GOP convention in Cleveland will all vote for…
BREAKING: SCOTUS Unanimously Overturns Former Republican Virginia Governor Bob McDonnell's…11:05am By Leon H. WolfOne of the most despicable political weapons Democrats frequently use is the criminalization of ordinary political conduct. Republicans have used it in some cases as well, but by far the practice is more widespread and abused by Democrats, especially with…
Pro-Trump And Anti-Trump Fascists Slug It Out In Sacramento11:00am By streiffBoth sides started yelling in German...The post Pro-Trump And Anti-Trump Fascists Slug It Out In Sacramento appeared first on RedState.
BREAKING: Supreme Court Issues Big Ruling On Texas Abortion Law10:44am By Joe CunninghamA controversial Texas anti-abortion law has suffered a big defeat in the Supreme Court today, as the judges issue a 5-3 decision striking it down as unfairly restrictive of women's abortion rights. The decision saw Justice Anthony Kennedy siding with the…
Anti-Trump Delegate Mutineers Descend on Cleveland10:30am By Leon H. WolfUnlike the abortive attempt to recruit an independent candidate to run against Trump, the effort to simply deny Trump the nomination at the convention seems to be serious and gaining steam. According to Politico, the members have been strategizing via phone…
Obama Appointed Federal Prosecutor Lies To Try To Silence A Outraged Community10:01am By streiffThe First Amendment. You'd think they cover that in law school but you'd be wrongThe post Obama Appointed Federal Prosecutor Lies To Try To Silence A Outraged Community appeared first on RedState.
Coming Soon: Internet at the Speed of Government9:33am By Seton MotleyWhen government "helps" run something – that something is terrible. The bigger a hand government has in running it – the more terrible it is. If it is exclusively government-run – the terrible-ness is ingrained and inherent. And the longer government…
What If They Gave A Convention And No One Came?9:30am By streiffWhen the reek of flopsweat gets between a politician and national television exposure you know there is a real problem.The post What If They Gave A Convention And No One Came? appeared first on RedState.
Poor Old Low Energy Hillary Can't Walk the Gay Pride Walk9:00am By Dan SpencerMakes one wonder whether Hillary is too low energy to withstand the rigors of the presidency.The post Poor Old Low Energy Hillary Can't Walk the Gay Pride Walk appeared first on RedState.
What Does the GOP Stand For in the Age of Trump?4:00am By Leon H. WolfDonald Trump is adamant that everyone in the Republican party should rally around him or "just shut up." To some extent, Republicans are always called upon to do that. The problem, in the era of Trump, is that Republicans aren't and can't be sure…
No Enthusiasm for Hillary or The Donald in New PollingSun 8:00pm By Dan SpencerRecent polling finds voters aren't excited about either Hillary Clinton or Donald Trump.The post No Enthusiasm for Hillary or The Donald in New Polling appeared first on RedState.
- Visit RedState at redstate.com
- Bookmark and Share
Welcome to Politomix -- the political news wire where left, right and center mix.
Politomix aggregates the day's political news on the web and your mobile device.
- American Thinker
- Breitbart
- CanadaFreePress
- FOX News
- FrontPage Magazine
- Hot Air
- Infowars
- Instapundit
- Michelle Malkin
- National Review
- NY Post
- PJ Media
- Reason
- RedState
- The Blaze
- The Daily Caller
- The Gateway Pundit
- Townhall
- Washington Free Beacon
- Washington Times


text:
us standard issue oakley coming from amazon along with failed to count on much as a result of good deal, I must say I'm happily suprised, that they appeared quickly and still have already been used for many weeks now simply by my personal child without having problem and he adores all of them, without a doubt value for money Best. Fast supply. Wonderful support. Thank you Great eyeglasses for that price tag, my personal 2 & Several year-old pleased together. Slightly massive either way of them, and not an excessive amount of. Ende Zurich ray ban prescription that when the lady forms any band it will likely be called 'Rainbow Shutter',a name the girl comprised, i really merely had to purchase these. The woman's daddy is actually soon to discharge a great record associated with their own songs now wants your eyeglasses for you to attribute about the lp deal with. These folks were very inexpensive and tglasses online canadaons as tool securitization'╝łABS'╝ēOn the basis associated with property used in the particular broker'╝īThe special form of your c
We arrived in War early enough and got for the resort. It is very fascinating to obtain this type of equipment given that Asus put in pl
ity of monetary crimes'╝īMany in the subjects are generally expecting tryout prisoners'╝īHaving one particular, then handed out several $ 100 routine maintenance freeŃĆé
ŃĆĆŃĆĆOne number of Supra Shoes sale on salewasher safe it's my job to handwash these only to be safe to use.
Riedel Wine beverage Cups Pair of A couple of O Pinot Black & Nebbiolo Tumblers
Riedel A Cabernet & Chardonnay Wine Glasses 7 Part Value Set
These types of cups are great Minneapolis ray ban clubmaster sale
, however if you simply are not utilizing fine chemical hand bags as well as filter systems, you happen to be getting the tiniest poutlet back into the air.
in emotive crisisŃĆéThird, females privileges awareness to be weak'╝īLack associated with securityŃĆéIn the situation of females put aside to guard loosing her husband'╝īMore at risk of intrusion to
activities'╝īIn order to increase the development of pastime facilities'╝eye framesThere is certainly a lot goods in amazon that it's usually possible to uncover items
just like something unusual you own and obtain a solid idea of it's price.
That may be a roof prism binocular, however consider it really is simply a major chrome cup, with no prisms.
I believe your current Bushnell, in case a Custom Compact, has been possibly a 6X25. I needed one in 7X26 and yes it woul oakley shirt antique reproduction polarise
driving a car they may be thrown within my tote along with whichever other detritus We bring regarding with me at night with coped to date. They don't really come with a tough situation, just the rules delicate carrier, however this does not seem to have been recently a difficulty within the detritus bag to date (even though I'd attempt to place them in a challenging case should they would commit time and babyliss big hair
lly really worth, erotic prices are extremely high, strategies before long, your day showed up, covering result is very good, and also quality involving spectacles body, good purchasing at any given time!
Receivchopper sunglassescarries a central amount of Ten centimeters, would make a fantastic magnifier. Eyeglass lenses are usually much weakened, simply because eyeglasses fail to work by simply magnifying; that they perform by simply correcting concentrate. A standard eye without echoing mistake features a indicative power of approximately 60 diopters.
Stacking lenses mixes their ability simply by straightforward addition of diopter durability, if his or her separation can be minimal. The +1 diopter contact along with a +2 diopter zoom lens kinds any +3 diopter method.
Lenses appear in cheap ray ban wayfarer Cheapan our glasses, along with a fair amount of fulfillment. Not long ago i came across the particular E-cloth alternative in Amazon online, and having recently been positively impressed by general employ E-Cloths I made the decision to try the actual spectacles version. I became therefore satisfied in the easy wash above and also bright clear i ordered far more. In fact the very best cloth to clean contacts that I have realized with a long way, as well as recommended. The actual fabrics have a new dimensions to match into glasses cases,


text:
Recent posts
- A peek of our June shares before they go to the post! Vibrant prints by Angela Ferrari! http://fb.me/5nidGXHWP
- Photographer Mark Yaggie is putting the SUMMER in our Summer Takeover Series! Come bask in the inspirational... http://fb.me/2TvaRgIqt
- HAPPY SUMMER! We made a playlist for your studio, your sunroof, your solstice! Stay tuned for more seasonal... http://fb.me/3Fd6rBREf
Give us a shout with your CV, a little about yourself, and images of previous work that exemplifies what you do.
Say Hello
If you are an artist applying with CSArt Maine and want to share images of your artwork, please share with us via Dropbox, Google Drive, or your personal website.
If you have questions concerning our program, purchases, or where to pick-up, please feel free to ask us at anytime.


text:
Henrik Ibsen News
News about Henrik Ibsen continually updated from thousands of sources around the net.
Antaeus Theatre Company clarifies the bad behavior of 'Hedda Gabler'
Friday Jun 17 | Los Angeles Times | Comment?
Hedda Steam
Friday Jun 3 | The Weekly Standard | Comment?
Tuesday May 31 | The San Diego Union... | Comment?
Henrik Ibsen news is powered by NewsRank™
Trending Now
Updated: Fri Jun 17, 2016 07:21 am
Copyright © 2016 Topix LLC


text:
Daisy Duck's American-sneaking photo of Comet Tours: The Space Flights Continue
Enter into the land of Comet Galactica, zooming aboard an abominably simulated Comet Tours comet speeder to ice locations like Jattooine, the planet of Undor, and the Death Galactic. Your ride has 141 possible results, in which you might encounter such Comet Galactica characters as visitor hunters, F2-L2, Iwoks, and Master Noda.
We suggest you don't try Princess Mode
© copyright 2011–2016
A Pants Aflame production


text:
2014-04-08 11:19:00
Lori Raab/Kelly Bleyer
Bend police are looking for a missing 15 year old with asperger syndrome and autism.
15 year old Ken Schuchman is 5'9" and weighs 140 pounds, with short brown hair and eyes.
He was last seen wearing a "mustard" colored hooded sweatshirt, a "breaking bad" black t-shirt with white lettering, blue jeans, and he was carrying a gray backpack.
He was last seen at his home around 1:30 early this (Tue) morning.
he is likely to be walking and has been known to ride public busses. anyone with information on his whereabouts is asked to call Bend Police. The non-emergency number for 911 is 541-693-6911.
News Release below:
Date: Tuesday, April 08, 2014
Date & Time of Incident: 04/08/14 / 0130
Type of Incident: Missing Person
Location of Incident: 20623 Sierra Drive
Missing Person:
Kenneth Currin Schuchman
15 years of age
White male, 5'09", 140 pounds, short brown hair, brown eyes
Last seen wearing: "mustard" colored hooded sweatshirt, "Breaking Bad" black tshirt with white lettering, blue jeans, carrying a gray backpack.
Diagnosed: Asperger Syndrome and Autism Disorder
The Bend Police Department is actively trying to locate Kenneth Currin Schuchman. He is a 15 year old juvenile diagnosed with Asperger Syndrome and Autism Disorder. He left his residence at about 0130 hours earlier on this date. He is believed to be walking, without access to a vehicle, and has been known to ride public busses.
Anyone with information about Kenneth Schuchman's whereabouts or observes someone that resembles him is asked to contact the Bend Police at 541-693-6911.
Hide Comments
King Solomon Lane closed between Ferguson Road and King David. (7/25)
Jones Road closed between Butler Market Road and Bennington Lane. (8/18)
R.A.B. Construction:
Murphy Road and Parrell Road closed with detours. (9/30)
Powell Butte Highway at Neff and Alfalfa Market Roads (8/31)
Home | EEO | Employment Opportunities | Advertising Information | Links | Contact


text:
Plymouth Building Contractors
Home Improvement Experts
Serving the Plymouth area.
- (877) 959-5206
1. Huff's Septic & Sewer
12700 3A RdPlymouth, IN 46563
2. Creed Septic Systems Specialists
14326 US Highway 6Plymouth, IN 46563
From Business: Creed Septic Systems Specialists have been serving Marshall County, IN and surrounding areas for over three generations. We service commercial and residential custo…
3. Eisenhour Home ImprovementsProducts
14680 Lincoln HwyPlymouth, IN 46563
4. Home Improvement Experts
Serving the Plymouth Area.
From Business: Home Improvement experts will provide you with fast, easy, and affordable quotes on your next building project. You can request quotes and set up scheduling either …
5. AirTight Spray Foam Insulation
i used their product for the attic and crawl space of my home back in 2013. while they didn't have the lowest price, they were extremely close and t…
6. Morton Buildings
From Business: For over 100 years, Morton Buildings has provided quality and service to people looking for an attractive, long-lasting building. Because Morton utilizes post-frame…
7. LawmastersServices
1407 W Hively AveElkhart, IN 46517
From Business: Lawmasters knows that not all roofs are the same. Whether industrial, commercial, or institutional, the roof needs of each building are different. The three major r…
8. Pacemaker BuildingsServices
Great company to work with! I highly recommend.
9. Schweitzer ConstructionServices
Serving the Plymouth Area.
From Business: Schweitzer Construction is a general contracting company that serves clients in the state of Minnesota. It offers a range of general contacting, construction manage…
10. HomeAdvisor
Serving the Plymouth Area.
From Business: HomeAdvisor will match you with the best trusted general contractors in your area to give the lowest affordable quote on your job.
11. Pacemaker BuildingsServices
PO Box 259North Webster, IN 46555
From Business: Pacemaker Buildings is a regional leader in designing, manufacturing and constructing post frame buildings (pole barns) for the agricultural, commercial, equestrian…
12. The Carport Depot
Serving the Plymouth Area.
From Business: The Carport Depot is a leading carport dealer with a huge selection of carports, barns, garages and utility buildings to choose from The Carport Depot will help you…
13. Delaware County Home Builders Inc.
Serving the Plymouth Area.
From Business: We work for you, our valued customer!
14. Roto-Rooter Plumbing & Drain Services
1706 W 6th StMishawaka, IN 46544
From Business: Whether you're experiencing a plumbing emergency, or something as simple as a leaky faucet or running toilet, Roto-Rooter can help you get it fixed quickly. Roto-Ro…
15. Ritschard Bros IncServices
1204 W Sample StSouth Bend, IN 46619
From Business: Please Visit Our Website For More Information
16. American Standards Roofing & Siding
Osceola, IN 46530
17. TMI Contractors
Serving the Plymouth Area.
18. RetroFoam Of Southwest Michigan
Serving the Plymouth Area.
19. Ferguson Waterworks
Very Unprofessional, very bad bookkeeping.
20. Professional Basement Services
I am so happy to have hired these guys! The whole crew was so friendly, worked quickly and did a great job! We hired them because of leaking issues …
21. Royalty Roofing
936 Executive DrWarsaw, IN 46580
From Business: Owner: Andy Royalty Commercial Roofing: Royalty Roofing specializes in roofing projects for commercial, industrial and institutional facilities. We are headquartere…
22. Taylor PaintingServices
11694 LincolnwayOsceola, IN 46561
23. 3-D Structural Solutions IncServices
20115 Jackson RdSouth Bend, IN 46614
From Business: 3-D Structural Solutions provides solutions for the repair and construction of concrete, mud jacking, waterproofing and foundation, serving northern Indiana, southe…
24. Lakeland Asphalt
474 Avenue ABattle Creek, MI 49037
25. Allied Construction Corporation
South Bend, IN 46601
26. Michiana Waterproofing Systems
Berrien Springs, MI 49103
From Business: 30 Year Tuff - N - Dri Waterproofing Systems. 10 or 15 Year Membrane Only. Epoxy Crack Injection.
27. A G S MechanicalServices
South Bend, IN 46614
From Business: Over 30 Years Experience Serving the South Bend/Michiana Area. Residential & Commercial
28. R & R Excavating
Mishawaka, IN 46545
29. Sears Home Improvements - Ventilating Contractors
From Business: Sears Home Improvements is your trusted, long term partner. We've been helping customers improve their homes for over 125 years and we back our work with strong war…
30. Sears Home Improvements-Roofing Contractors
From Business: Trust Sears for reliable roof system products, installation and peace of mind on one of your biggest investments – your home. With a Sears Roofing System, you'll ge…


text:
Image Courtesy of
Brazilian Transsexuals
4.7 rating 439 votes
BioAKA: Laura Ferraz
Birthplace: Brazil
Location: Brazil
Ethnicity: Latina
Height: 5'11"(180cm)
Birthday:October 23, 1982
Added: Nov 1st 2009
Views: 101120
Pay Sites featuringBrazilian Transsexuals
Laura Feraz
Franks T-Girl World
The Grooby Archives
Evil Angel
TS Playground
Her Movies
Laura jest piękna, pociągająca, piękne zalotne spojrzenie, ciekawy jestem czy w środku też jesteś tak piękna!--Miś ,Poland
duza rzecz , wyruchalbym toto ...--OUC! ,Poland
There are NOT many girls hotter than Laura!--Chrisi ,Germany
Her balls are so mouth watering.--Raastible ,United States
Never have I ever wanted to suck a cock soooo bad as his one--Stephen ,United States
I love to sit here and jerk off watching her fuck with that big, beautiful cock. Lucky guys.--CM ,United States
My all time favorite--Dale Fallis ,United States
yum,yum wow!!!--skiing555 ,United States
One the top trannies, perfect on every way.--Joe ,Colombia
Mmmm TnA--Person ,United States
WOW... ANOTHER BIG DICKED BEAUTY!!!--BIGDICKRIDER ,United States
id love all of her inside me!--skiing555 ,United States
Quiero ese hermoso culo violada--Ass Hunter ,Egypt
What a COCK!--shmluv, cleve, oh ,United States
Goddess. I'll save her cum for a month and then drink it out of a big container.--Pehtonk ,United States
She is Laura FeRRaz! Double RR!--Tumbalacatumba ,Brazil
This is what i can say about Laura Feraz. Everything about her is sexy. Nice tits,hot body,perfect ass, and a pretty face!! Thats what i like about shemales like her. You can't tell if she's a women and that's what makes it special! Jason, MI.--Jason McDonald ,United States
Beautiful T-girl. Gorgeous ass and cock.--Juliano ,United States
Top Free Shemale sites
|01. Nu Shemale
|08. PornStarDB
|15. Golden Gay Tube
|22. Shemale Fan Club
|29. Tranny Bananas
|02. Shemale Private
|09. Shemale Photos
|16. Shemale Best label
|23. Asian Shemale Pictures
|30. Big Cock Shemales
|03. Crazy Tranny
|10. Sexy XXX Movs
|17. Babe Shemale
|24. Tranny Models
|31. Hot Shemale Free Porn
|04. Hot Tranny
|11. Teens Porno Movies
|18. Shemale Miss
|25. Tranny Galleries
|32. Shemale Cocktail
|05. Mom XXX Vids
|12. Hardcore New Movies
|19. 18 Teen Clips
|26. Asian Ladyboy XXX
|33. Shemale Plus
|06. Teen Tube Movs
|13. Shemales Hot
|20. All Shemale Stars
|27. Shemale Show
|34. TgirlsThumb
|07. PrettyTranny
|14. Sexy Ladyboy Pics
|21. Tranny Sunny
|28. Hot Tranny Sex
|35. Shemale x Ladyboy
Google Yahoo Best PornStar DB Shemale Private Big Boobs Private
ShemaleStarDB Home Page
All models were at least 18 years old when they were photographed.
© 2009-2014 ShemaleStarDB.com..
Sorry for our mistakes. Post your suggestions and corrections to our site at comments sections.


text:
My Little Pony: Friendship Is Magic Answers for iPhone - iPadHome / iPhone - iPad /
Game Questions & Answers (Q&A) service lets you ask questions about video games for game consoles or PC games. So ask your My Little Pony: Friendship Is Magic question for iPhone - iPad and get answers from real gamers or answer questions and share your insights and experience with the rest of the gaming community.
- Developer: Gameloft
- Publisher: Gameloft
- Genre: Edutainment
- Release: Nov 8, 2012
- ESRB: Not Set
Question & Answers
Level maxed out?
I reaced level 70 and now the experience i collect does not seem to add in anymore. is level 70 the max level?
Answer from: Riodejaneiro422
Sadly, yeah. That is the last level and I am also stuck on it. I hope they update it and more levels are added! But for now, the last level is level 70. :'(
Answer from: inuboy7
Yes the levels stop at 70 hopefully you shared all your levels and goals that way you get free heart gems fir them.
Answer from: annevr1972
Level 70 is indeed the highest. Strange that since i reached i don't get any herts anymore. Before i got about 200 a day and now nothing :((
My Little Pony: Friendship Is Magic - Epic Trailer
- Nov 13, 2013, Views: 908
My Little Pony: Friendship Is Magic - Equestria Girls Movie Trailer
- Nov 13, 2013, Views: 753
My Little Pony: Friendship Is Magic - Season 4 Era Of The Princess Trailer
- Nov 13, 2013, Views: 1017
My Little Pony: Friendship Is Magic - Final Cut
- Nov 13, 2013, Views: 667
- The Journey: Bob's Story, (PC)
- Deus Ex: Mankind Divided, (PS4)
- Skylanders Battlecast Cards To Life, (AND)
- Mafia 3, (PS4)
- Forestry 2017 - The Simulation, (XONE)
- MX Vs. ATV Supercross Encore, (XONE)
- Tayutama 2: You're The Only One, (PC)
- Call Of Duty: Infinite Warfare, (PS4)
- Teddy Together, (3DS)
- Hero Siege: Pocket Edition, (iOS)
- Get 'Em, (iOS)
- Quest To Aztlan, (iOS)
- Paranormal Minis, (iOS)
- Station Manager, (iOS)
- Iron Mission - Classic Arcade Shoot'em Up, (iOS)
- Epic Flail (Noxus Ltd), (iOS)
- 2-bit Cowboy Rides Again, (iOS)
- Dungeons Of Chaos Unity Edition, (iOS)
- Rule With An Iron Fish, (iOS)
- Heroes Of Loot 2, (iOS)
- Fi, Chris And The Apocalypse, (iOS)


text:
John Keating
I am John Keating. I am married to the love of my life, I am father of three beautiful kids,and Poppie to my two grandsons Andre and Carter and my first Grand daughter Stella. I am one who loves to take and give photos to family and friends. I am learning photography on my own and strive to to better with each shot. I love to capture moments in time and give them a new lease on life. Capture Life, Capture Time. Please feel free to comment on my photos, I accept any help or direction
No stories
No collections
Oh noes!
This person hasn't created any collections yet.
Enter "Minimal Photography"!
Recent JPG Live Stories
Latest Photo Links
Photos of the Week: 6/18-6/24 - The Atlantic
231 Views » 0 Comments » 0 Votes
This Shapeshifting Electric Car Rig Will Change the...
199 Views » 0 Comments » 0 Votes
Crazy Fast...Tony Gale On The a6300 | Sony | Alpha...
201 Views » 0 Comments » 0 Votes
Q: uplaoding a Tiff photo
A: Do you know?