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For rent granny flat nsw
1-15 of 1,666
properties for rent found
- 6HHomely 3 days, 6 hours ago
Brand new granny flat
Address available on request, Nambucca Heads, NSW
This brand new granny flat consists of 2 bedrooms, dishwasher, air conditioning, ceiling fans and a single garage. There is another rented...$2502 bed1 ba
- 4HHomely 4 days, 6 hours ago
Granny Flat
1/6 Miles Street, Mascot, NSW
Large open plan living granny flat, quietly located at the rear of the main house, includes kitchenette & own bathroom. Ample space for...$2701 bed1 ba
- 6HHomely 3 days, 5 hours ago
Good size granny flat
32A Munyang Street, Heckenberg, NSW
This beautiful granny flat has 2 good size bedrooms tucked away in the quite suburbs of Heckenberg. Both bedrooms have built ins for extra...$3502 bed1 ba
- 12HHomely 4 days, 3 hours ago
House & Granny Flat!
69 Carlisle Avenue, Ingleburn, NSW
...& dining area, single undercover carport, small shared garden and courtyard. Rare opportunity to secure a house and granny flat all in one!$5004 bed2 ba
- 5DDomain 1 day, 15 hours ago
Apartment Unit Flat: Granny Fla/42 Victoria Road Pennant...
Granny Fla/42 Victoria Road, Pennant Hills NSW 2120new
1 bedroom self contained granny flat. Large combined lounge and dining room. Large balcony. Elevated land with North-East aspect and district...On Request2 bed1 ba
- 4SSellsgood 2 days, 21 hours ago
Two bedroom granny flat
Coffs Harbour NSW
This two bedroom granny flat is located within walking distance of Bray Street shop and features timberlook flooring throughout, open plan...$2202 bed1 ba
- 7HHomely 3 days, 4 hours ago
2 Bedroom Granny Flat
62A Chiswick Road, Auburn, Sydney NSW
2 bedroom granny Flat features. Available car space. Built in wardrobe. Fly screens on windows. Gas cooking available. Air conditioner...$4302 bed1 ba
- 3HHomely 3 days, 2 hours ago
Brand new granny flat
39A Morshead Street, Ryde, Sydney NSW
Brand new three bedroom granny flat situated in a very convenient location and features: Three bedrooms all with built-ins. Master bedroom with...$5503 bed2 ba
- 4HHomely 3 days, 4 hours ago
Ultra Modern Two Bedroom Granny Flat
2A Douglas Street, Merrylands, NSW
Two Bedroom with built-ins in to both rooms +Tiles throughout +Two split system air conditioners +Large kitchen with gas cooking + Bathroom &...$4002 bed1 ba
- 4HHomely 3 days, 1 hour ago
Architecturally designed new granny flat - open house sat...
7 Bligh Lane, Eastwood, NSW
This light filled architecturally designed granny flat is within walking distance to transport, shops and Macquarie Uni. Spacious and light...$5102 bed1 ba
Apartment Unit Flat: 33 Austral Avenue Westmead
/33 Austral Avenue, Westmead NSW 2145new
Brand new granny flat 2 Bedrooms 1 Bathroom Combined lounge/dining area Tiles & polished floorboards Gas cooking Phone line Separate entrance...$4702 bed1 ba
24A The Crescent, North Narrabeen 2101, NSW
24 A The Crescent,, Penrith, Sydney NSWnew
This gorgeous modern granny flat is a must see! Modern renovated kitchen. Open plan living and dining space. Large bedroom with ensuite...$6021 bed1 ba
- 10HHomely 4 days, 1 hour ago
Modern Open Plan One Bedroom Granny Flat!
24A The Crescent, Penrith, Sydney NSW
This gorgeous modern granny flat is a must see! Modern renovated kitchen. Open plan living and dining space. Large bedroom with ensuite...
Similar properties for rent : for rent granny flat penrith$4501 bed1 ba
- 5HHomely 3 days, 23 hours ago
Stunning two bedroom Granny Flat!
32a Coleborne Avenue, Mortdale, NSW
This near new 2 bedroom villa/granny flat is located in a prime Location at the rear of the complex. Featuring a tiled combined lounge & dining...$4602 bed1 ba
- 3HHomely 4 days, 2 hours ago
Brand New Two Bedroom Granny Flat
12A William Road, Riverwood, NSW
Features: 2 bedroom granny flat, both with built-in wardrobes. Combined lounge and dining area. Modern kitchen. Large combined bathroom and...$4502 bed1 ba


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Vanessa Williams: Why I Love Halloween
The Desperate Housewives Star Talks About Why She Likes to Go All Out-Spooky Decor, Fun Games, Cool Parties-Every Time Oct. 31 Rolls Around
Vanessa Williams can't wait for Halloween. "I start decorating Oct. 1," says the newest housewife to join the Desperate Housewives cast, who hangs bats and spiderwebs and black crows all around her home, and-as mom to daughters Sasha, 10, Jillian, 21, Melanie, 23, and son Devin, 17-has sewn her share of costumes over the years. "It's a favorite holiday for any kid, and I live through my kids," she says. "Plus it's a chance to dress up and be creative, and I love having parties. We do bobbing for apples, and we watch scary movies." Clearly Williams' fondness for the holiday has been deeply instilled into her kids. "My 21-year-old daughter called me today," says Williams. "She said, 'Mom, I'm gonna be you this year for Halloween-can you help me with my outfit?' "
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Ukiah Granite
1. Granite Edge
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2. Victors Granite & Tile
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They require alcohol for both…
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Tina says split rumors are "bull".


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The International Cargo Handling Coordination Association reminded shippers and forwarders that the container weighing rule will go into effect Friday, with no three-month grace period as some have mistakenly understood.
The shipment management software provider officially launched its verified gross mass submission tool, which allows shippers and freight forwarders to use a centralized point to provide the verified container weight data to their carriers.
A.P. Moller-Maersk Group's oil unit lost a bid for the renewal of its 25-year involvement in the Al Shaheen offshore field when the current agreement expires in July 2017.
Registration takes less than 1 minute.
The international financial institution lowered its outlook for global growth as business spending sags in advanced economies, while commodity exporters in emerging markets struggle to adjust to low prices.
Drivers are striking four companies doing business in and around the ports of Los Angeles and Long Beach, claiming they are being misclassified as independent contractors instead of employees.
Rail theft has emerged as a more prevalent problem in Mexico, primarily in the states of Guanajuato and Querétaro, while fuel theft across the nation has also increased.


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Calgary Zoo's king penguins hit the snow Add to ...
CP Video
Last updated
King penguins at Calgary Zoo are making the most of recent snowfall, exploring their outdoor habitat.
Watch More Video:
Pentagon ends ban on transgender troops in U.S. military
'Driven' dogs trained to detect leaking pipelines
Follow Brian Gable as he draws The Globe's 2016 Canada Day cartoon
Watch as house topples over in Japan after landslide
Too much 'thank you': Nine-year-old refugee adjusts to Canadian life
Evacuated residents waiting to return after Mississauga house explosion
Boris Johnson abruptly exits U.K. Conservative leadership race
Obama: 'we can't seal ourselves off from the rest of the world'
'Dudeplomacy' on show between Trudeau, Obama
Trump says Sanders secretly 'hates' Hillary Clinton
Turkey vows to defend against more terror
The Globe and Mail talks to the Canadian who is now the first lady of Iceland
'Three amigos' talk trade, spurn isolationism in Obama's final summit
Obama, Nieto talk Turkey, immigration at Three Amigos Summit
U.S. to admit 30,000 more refugees over two years
'We have to fight fire with fire': Trump calls for return to waterboarding
Obama, Trudeau and Nieto arrive for Ottawa summit
'For heaven's sake man, go!' U.K.'s Cameron tells opposition leader
See inside as bomb-damaged Istanbul airport reopens
At least one dead in house explosion in Mississauga, Ont.


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V.21 No.42 | 10/18/2012
Reel World
Sound Tracking
Santa Fe-based ambient music composer Michael Stearns will be on hand to introduce screenings of the film Samsara on Friday, Oct. 19, at Albuquerque's Guild Cinema. The film is a major collaboration between Stearns and director Ron Fricke.
Today's Events
2nd Annual Feline Film Festival at KiMo Theatre
Meet adoptable kittens and create playful cat crafts with Albuquerque cat lovers.
Grand Opening at Casino at the Downs
Paul Oakenfold • trance at The Stage at Santa Ana Star CasinoMore Recommended Events ››
Kombat Kitty @ Barley Rm • 7.1.2016
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All climb levels welcome!
Come join us for some climbing at French's Dome! French's has a nice variety of climb grades from 5.7 - 5.12. If it's not too crowded with other climbers we will set up a couple ropes on different grades. This is a great place for those who like to lead sport climbs.
We will need at least one person who can lead belay so we can set up some ropes.
Carpool locations:
Suggested carpool donation is $5-8.
1). Gateway Transit Center
NE 99th & Pacific
Meet at the northwest end of covered parking area (Fred Meyer side), at 8:30 am. Targeted departure time 8:45 am.
2). Clackamas Town Center Transit Center 9225 SE Sunnyside Road
Meet at the northeast end of covered parking area, at 8:20. Targeted departure time 8:40 am. I (Stefani) will be at this location. I currently have two spots left in my vehicle. I am leaving earlier since I am organizing. Others may want to meet here and leave a bit later.
NW Forest Pass Parking is required. You can get one at many Bi-Marts, outdoor stores, or the NW Forest Office 70220 E Hwy 26 in Zig Zag (their website says they are open on Saturdays).
We will have a nice leisurely day of climbing and hanging out and chatting while resting between climbs. Bring snacks and water, and of course, climbing gear. If you want to bring some food to share, that might make it fun. I will bring a table and some chips and salsa.
This meet-up was a lot of fun! Thanks to all who came! Everyone had such a positive, supportive, and encouraging spirit. The weather was beautiful. The is rock great! We had several ropes going, climbs ranging from 5.7-5.10+, and a group did the multi-pitch. Because of the close proximity of all of the climbs we were able to socialize a bit more. We set up a table off to the side with some shared food and a place to store gear, so as not to crowd climbs. I really enjoyed getting to know people, and hope to have more opportunities to get to know and climb with you.
2 · August 3, 2014
Its 8:30. I am at Clackamas by the circus tent in the red Honda Fit with a roof rack. :-)
0 · August 2, 2014
Please list below who will be at the Gateway Transit Center.
So far I see Abe Coir
0 · July 31, 2014
Please list below who will be meeting at the Clackamas Town Center . I will be there at 8:20 and have room for two more people.
0 · July 31, 2014
Hey, I have been wanting to check out French's Dome. I am coming with a friend, he has plenty of lead experience. We have a rope and plenty of gear. I plan to drive because I have a commitment later that afternoon and can't stay too long. I climb in the[masked] range, my friend higher. Looking forward to it.
0 · July 27, 2014
I'm a 5.9/5.10 climber. Able to lead belay and clean trad gear if needed. I'm planning on doing some camping that weekend so as of now I'm coming solo.
0 · July 26, 2014
I am going to come from Vancouver, I have a car & 2014- pass, full gear with one, 60m, rope.
I can bring extra harness, chalk bag if is need it....
I can bring one extra person with me, but on the way back I am going to stop in couple places...( timberline lodge, salmon river slab....).
0 · July 26, 2014
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Plug-in hybrid and electric vehicle owners in the state of California will soon have a much easier time charging up.
Read This Article
The midsize sedan is unquestionably the most important segment in the U.S., with sales of some models eclipsing entire automaker lineups.
The 2014 Toyota 4Runner's new tech and new styling makes an old idea better than ever.
It seems every couple of weeks there's a push for or against autonomous driving vehicles.


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Since Manteca's city council passed an ordinance in October 2008 requiring all pit bulls and pit bull mixed breeds be spayed or neutered, illegal pit bulls have been a constant worry for animal control workers, especially Linda Sell.
By WILLIAM DRAA
I've heard tell that dog owners (or "guardians" as some prefer) look like their dogs. I did not realize with how much haste that transpires.
Having a garage sale this weekend?
Tom Hanks is the quintessential Hollywood Nice Guy. Even when he plays a gangster, he's a very nice gangster. And that's why audiences flock to see his movies.
"It is what it is." - Stephen Schluer, president, Manteca Police Officers Association
Everything you need to know about the federal government you can learn in a Manteca Unified school cafeteria this fall.
Ripon is a true valley town with a strong sense of Americana that at times seems of another era.
If PG&E happens to electrocute you, burn your house down, or start a wildfire that wipes out your crop they want to be able to do so without worrying about being held liable for your death or losses.
Get ready for a taste of Kabul at night.
It was, if you will, a Declaration of Reality.
There's been talk of marriage but it never got past the pre-nuptials.
Few people can say that their job is also their daily source of inspiration. Julie De Araujo is one of these lucky few.
I've had a revelation.
Downtown Manteca needs a voice.
Page 124 of 188
Ripon Unified - in conjunction with the League of Women Voters - is conducting an informational workshop for potential candidates seeking to run Nov. 8 in the ...
Debby Moorhead wants the city to step up its efforts to address the growing number of homeless Manteca.
Juvraj Sidhu enjoyed his time at the 2016 STEM Summer Camp.
A Manteca father trying to find his daughter's stolen bicycle challenged a man riding it within a block of his home Friday night and ...
"Climate change is no longer a threat' it is a reality." - President Obama speaking in Yosemite Valley on Saturday
I recently stumbled on some old floppy disks (are there any other kind?) that have some of my old columns going back up to 14 ...
It's time to carbon date yourself.
When I was in the Manteca Bulletin office the other day discussing the content of this column, the boy popped up with how I should ...
Lorene lives near Woodward Park.
I really should have rethought the decision to spend so much money on clothes when I was at my heaviest because I'm suddenly finding ...
Napa Valley may be the Lamborghini of California's wine regions - with the sexy, splashy, and pricey veneer that goes with it - but it doesn ...
President Obama and his family are visiting Yosemite National Park later this week.
Buying the 57,000-square-foot building that once housed Kodak's Qualex film processing division on Industrial Park Drive to serve as a new home for ...
School's out for the summer.
Water conservation will again be the hot button topic at Tuesday's Ripon City Council.
Page 2 of 6
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Top three games to look forward to
Each game counts on the run home, but here's three in particular we can't wait for.
6:00am Jun 26, 2016
Big Red a Bulldog through and through
There were more than a few reasons that Jack Redpath was so keen to extend his tenure at Whitten Oval.
6:00am Jun 25, 2016
The best of the banners... so far
We've picked out a couple of our favourite Danny McGinlay masterpieces.
1:50pm Jun 24, 2016


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|By Marketwired .
Article Rating:
|December 10, 2012 05:47 PM EST
IRVINE, CALIFORNIA -- (Marketwire) -- 12/10/12 -- The launch of Resume Builder Online's new do-it-yourself tool will help qualified professionals searching for the perfect job. In a time when the economy is uncertain and when securing a job means beating out hundreds of other applicants, having a flawless resume can make a huge difference.
Resume Builder Online offers professionals an easy to use system that is catered specifically to an individual's resume needs. Resume Builder Online makes creating the perfect resume easy, as it can be completed in just minutes. The site has an intuitive, easy to follow template, which help individuals to organize their information for their resume. After inputting the relevant information, Resume Builder Online's system properly formats the resume.
The DIY resume builder allows individuals to create a perfect, professional resume in no time at all. The system works in four steps. A job-seeking individual begins by filling in their personal information, and then the resume is formatted and ready to be downloaded. Individuals then save the resume to their computer; this allows for easy editing or for email job applications. Finally, the resume is sent out to future employers for review.
The online resume builder requires that all individuals fill out personal information, such as their name, phone number, mailing address and email address. Additional information that the resume builder suggests should be put into the system are education details, work experience, unique talents, and accomplishments. By using a system that prompts information, nothing will be forgotten making the resume stand out from the crowd. Unlike competing resume builders, Resume Builder Online does not cut corners and ensures each resume is the best it can be.
What makes Resume Builder Online different is that you get more than just a resume; individuals can visit the blog and also learn how to write a fantastic cover letter. Resume Builder Online is also teamed with Indeed.com to make searching for jobs in any area easier.
Perhaps what really sets this resume builder apart from competing services is that it is a free service. While other professional resume writing services charge hundreds of dollars, Resume Builder Online offers a convenient service that won't harm a budget.
Resume Builder Online is a professional resume writing service. The new do-it-yourself resume tool makes creating the perfectly formatted resume convenient and hassle-free. The free service makes finding a job easier, as the DIY resume tool works in conjunction with a helpful blog and a job search engine. For more information, visit Resume Builder Online on Facebook, Twitter or Pinterest. To create your own resume, visit http://www.resumebuilderonline.org.
Resume Builder Online
Stephanie Miller
[email protected]
Machine Learning helps make complex systems more efficient. By applying advanced Machine Learning techniques such as Cognitive Fingerprinting, wind project operators can utilize these tools to learn from collected data, detect regular patterns, and optimize their own operations. In his session at 18th Cloud Expo, Stuart Gillen, Director of Business Development at SparkCognition, discussed how research has demonstrated the value of Machine Learning in delivering next generation analytics to imp...
Jun. 30, 2016 04:00 PM EDT Reads: 999
The cloud promises new levels of agility and cost-savings for Big Data, data warehousing and analytics. But it's challenging to understand all the options – from IaaS and PaaS to newer services like HaaS (Hadoop as a Service) and BDaaS (Big Data as a Service). In her session at @BigDataExpo at @ThingsExpo, Hannah Smalltree, a director at Cazena, provided an educational overview of emerging "as-a-service" options for Big Data in the cloud. This is critical background for IT and data profession...
Jun. 30, 2016 04:00 PM EDT Reads: 347
A strange thing is happening along the way to the Internet of Things, namely far too many devices to work with and manage. It has become clear that we'll need much higher efficiency user experiences that can allow us to more easily and scalably work with the thousands of devices that will soon be in each of our lives. Enter the conversational interface revolution, combining bots we can literally talk with, gesture to, and even direct with our thoughts, with embedded artificial intelligence, wh...
Jun. 30, 2016 03:00 PM EDT Reads: 1,264
Whether your IoT service is connecting cars, homes, appliances, wearable, cameras or other devices, one question hangs in the balance – how do you actually make money from this service? The ability to turn your IoT service into profit requires the ability to create a monetization strategy that is flexible, scalable and working for you in real-time. It must be a transparent, smoothly implemented strategy that all stakeholders – from customers to the board – will be able to understand and comprehe...
Jun. 30, 2016 02:45 PM EDT Reads: 294
When people aren't talking about VMs and containers, they're talking about serverless architecture. Serverless is about no maintenance. It means you are not worried about low-level infrastructural and operational details. An event-driven serverless platform is a great use case for IoT. In his session at @ThingsExpo, Animesh Singh, an STSM and Lead for IBM Cloud Platform and Infrastructure, will detail how to build a distributed serverless, polyglot, microservices framework using open source tec...
Jun. 30, 2016 02:00 PM EDT Reads: 665
Connected devices and the industrial internet are growing exponentially every year with Cisco expecting 50 billion devices to be in operation by 2020. In this period of growth, location-based insights are becoming invaluable to many businesses as they adopt new connected technologies. Knowing when and where these devices connect from is critical for a number of scenarios in supply chain management, disaster management, emergency response, M2M, location marketing and more. In his session at @Th...
Jun. 30, 2016 01:30 PM EDT Reads: 1,337
In his keynote at 18th Cloud Expo, Andrew Keys, Co-Founder of ConsenSys Enterprise, provided an overview of the evolution of the Internet and the Database and the future of their combination – the Blockchain. Andrew Keys is Co-Founder of ConsenSys Enterprise. He comes to ConsenSys Enterprise with capital markets, technology and entrepreneurial experience. Previously, he worked for UBS investment bank in equities analysis. Later, he was responsible for the creation and distribution of life sett...
Jun. 30, 2016 01:00 PM EDT Reads: 1,500
Cloud Expo, Inc. has announced today that Andi Mann returns to 'DevOps at Cloud Expo 2016' as Conference Chair The @DevOpsSummit at Cloud Expo will take place on November 1-3, 2016, at the Santa Clara Convention Center in Santa Clara, CA. "DevOps is set to be one of the most profound disruptions to hit IT in decades," said Andi Mann. "It is a natural extension of cloud computing, and I have seen both firsthand and in independent research the fantastic results DevOps delivers. So I am excited t...
Jun. 30, 2016 12:30 PM EDT Reads: 470
"We work in the area of Big Data analytics and Big Data analytics is a very crowded space - you have Hadoop, ETL, warehousing, visualization and there's a lot of effort trying to get these tools to talk to each other," explained Mukund Deshpande, head of the Analytics practice at Accelerite, in this SYS-CON.tv interview at 18th Cloud Expo, held June 7-9, 2016, at the Javits Center in New York City, NY.
Jun. 30, 2016 12:00 PM EDT Reads: 532
"delaPlex is a software development company. We do team-based outsourcing development," explained Mark Rivers, COO and Co-founder of delaPlex Software, in this SYS-CON.tv interview at 18th Cloud Expo, held June 7-9, 2016, at the Javits Center in New York City, NY.
Jun. 30, 2016 11:45 AM EDT Reads: 589
IoT is rapidly changing the way enterprises are using data to improve business decision-making. In order to derive business value, organizations must unlock insights from the data gathered and then act on these. In their session at @ThingsExpo, Eric Hoffman, Vice President at EastBanc Technologies, and Peter Shashkin, Head of Development Department at EastBanc Technologies, discussed how one organization leveraged IoT, cloud technology and data analysis to improve customer experiences and effi...
Jun. 30, 2016 11:30 AM EDT Reads: 628
Basho Technologies has announced the latest release of Basho Riak TS, version 1.3. Riak TS is an enterprise-grade NoSQL database optimized for Internet of Things (IoT). The open source version enables developers to download the software for free and use it in production as well as make contributions to the code and develop applications around Riak TS. Enhancements to Riak TS make it quick, easy and cost-effective to spin up an instance to test new ideas and build IoT applications. In addition to...
Jun. 30, 2016 11:15 AM EDT Reads: 729
The idea of comparing data in motion (at the sensor level) to data at rest (in a Big Data server warehouse) with predictive analytics in the cloud is very appealing to the industrial IoT sector. The problem Big Data vendors have, however, is access to that data in motion at the sensor location. In his session at @ThingsExpo, Scott Allen, CMO of FreeWave, discussed how as IoT is increasingly adopted by industrial markets, there is going to be an increased demand for sensor data from the outermos...
Jun. 30, 2016 11:00 AM EDT Reads: 452
CenturyLink has announced that application server solutions from GENBAND are now available as part of CenturyLink's Networx contracts. The General Services Administration (GSA)'s Networx program includes the largest telecommunications contract vehicles ever awarded by the federal government. CenturyLink recently secured an extension through spring 2020 of its offerings available to federal government agencies via GSA's Networx Universal and Enterprise contracts. GENBAND's EXPERiUS™ Application...
Jun. 30, 2016 11:00 AM EDT Reads: 483
The cloud market growth today is largely in public clouds. While there is a lot of spend in IT departments in virtualization, these aren't yet translating into a true "cloud" experience within the enterprise. What is stopping the growth of the "private cloud" market? In his general session at 18th Cloud Expo, Nara Rajagopalan, CEO of Accelerite, explored the challenges in deploying, managing, and getting adoption for a private cloud within an enterprise. What are the key differences between wh...
Jun. 30, 2016 11:00 AM EDT Reads: 1,106
Presidio has received the 2015 EMC Partner Services Quality Award from EMC Corporation for achieving outstanding service excellence and customer satisfaction as measured by the EMC Partner Services Quality (PSQ) program. Presidio was also honored as the 2015 EMC Americas Marketing Excellence Partner of the Year and 2015 Mid-Market East Partner of the Year. The EMC PSQ program is a project-specific survey program designed for partners with Service Partner designations to solicit customer feedbac...
Jun. 30, 2016 10:45 AM EDT Reads: 685
The IoT is changing the way enterprises conduct business. In his session at @ThingsExpo, Eric Hoffman, Vice President at EastBanc Technologies, discussed how businesses can gain an edge over competitors by empowering consumers to take control through IoT. He cited examples such as a Washington, D.C.-based sports club that leveraged IoT and the cloud to develop a comprehensive booking system. He also highlighted how IoT can revitalize and restore outdated business models, making them profitable ...
Jun. 30, 2016 10:30 AM EDT Reads: 575
There are several IoTs: the Industrial Internet, Consumer Wearables, Wearables and Healthcare, Supply Chains, and the movement toward Smart Grids, Cities, Regions, and Nations. There are competing communications standards every step of the way, a bewildering array of sensors and devices, and an entire world of competing data analytics platforms. To some this appears to be chaos. In this power panel at @ThingsExpo, moderated by Conference Chair Roger Strukhoff, Bradley Holt, Developer Advocate a...
Jun. 30, 2016 10:15 AM EDT Reads: 992
SYS-CON Events has announced today that Roger Strukhoff has been named conference chair of Cloud Expo and @ThingsExpo 2016 Silicon Valley. The 19th Cloud Expo and 6th @ThingsExpo will take place on November 1-3, 2016, at the Santa Clara Convention Center in Santa Clara, CA. "The Internet of Things brings trillions of dollars of opportunity to developers and enterprise IT, no matter how you measure it," stated Roger Strukhoff. "More importantly, it leverages the power of devices and the Interne...
Jun. 30, 2016 10:00 AM EDT Reads: 557
In addition to all the benefits, IoT is also bringing new kind of customer experience challenges - cars that unlock themselves, thermostats turning houses into saunas and baby video monitors broadcasting over the internet. This list can only increase because while IoT services should be intuitive and simple to use, the delivery ecosystem is a myriad of potential problems as IoT explodes complexity. So finding a performance issue is like finding the proverbial needle in the haystack.
Jun. 30, 2016 09:00 AM EDT Reads: 453


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Babies for Sale in 44130(1 - 15 of 157)
$500 2 Smoothly raised German Shepherd puppies vet checkedGerman Shepherd · Hartville, OH2 Smoothly raised German Shepherd Inquire directly by visiting our site [ www.cutelitters.com ] Healthy socialized 4 females and males pe...Padrine L. · 1 day ago
$850 Golden Retriever Pups Waiting List - Due Mid JulyGolden Retriever · Medina, OH½ English Creme, ½ American Golden Retriever Pups Due Mid July We have a litter of pups due mid July. They are part English Creme and ar...Monica B. · 3 days ago
$575 Shih Pom puppies/Pom Shih puppiesAkron, OHThese adorable pups were born May 18th and are the product of an unplanned breeding of a 7 pound Shih Pom and a 10 pound shih tzu. Super ...Jody S. · 3 days ago
$900 AKC Long Hair German Shepherd PuppyGerman Shepherd · Newton Falls, OHI currently have one male 14 week old black and tan longhair german shepherd. This boy is the pick of the litter and was originally going...Brittany K. · 1 week ago
$700 Goldendoodle puppiesGoldendoodle · Ashland, OHBorn on May 19th Ashland OH. Approximately 60 lbs (fully grown). Mother is a F1 Goldendoodle and Father is a F1 Goldendoodle, both parent...Brenda C. · 2 weeks ago
$1,000 Olde English BulldoggeOlde English Bulldogge · Akron, OHWhat a perfect little lady. Beautiful markings and a great personality. Loves to play and very curious. You want a loving dog with spunk?...
$1,500 Olde English BulldoggeOlde English Bulldogge · Akron, OHEXTREAMLY RARE! Ghost is an almost all white bully with a great face. His face is going to be very short and a great classic look. Very c...
$1,200 Olde English BulldoggeOlde English Bulldogge · Akron, OHBullseye. Very classic looking bull. Awesome dark patch over the eye. Bull's-eye loves to snuggle and get belly rubs. Beautiful long st...
$1,300 Olde English BulldoggeOlde English Bulldogge · Akron, OHChunk is just that. a black and white chunk. He is going to be a big boy. Great bully face and a lets just chill attitude. Very friendly,...
$250 Toy Fox TerrierToy Fox Terrier · Wooster, OHThis little girl is such a cutie, she is 4 months old and will stay small. Such a snuggle lap puppy. loves everyone and she is ready for ...Lynn C. · 2 weeks ago
$250 Fox TerrierFox Terrier · Wooster, OHThis little girl is so lovable and playful. She has had her first shots. She has been wormed and ready for her forever home. She is nine ...Lynn C. · 2 weeks ago
$250 Chihuahua mixChihuahua · Cleveland, OHMale puppy, about 9 weeks old, comes with brand new cage that was bought about a week agoConner B. · 3 weeks ago
$500 English Mastiff/German Shepherd Hybrid puppiesMastiff · Cleveland, OHEnglish Mastiff mom (akc) German Shepherd dad (akc) puppies born 5/23/16. 3 boys 4 girls Both parents great health and temperament. Call ...Jen F. · 3 weeks ago
Please contact Kathy ( [email protected] ) for more details about this pet. Please fill out an adoption form today at www.pawsandprayers.o...http://www.adoptapet.com ·1 day ago on Adopt-a-Pet.comTools
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$300 Adopt Pup Fuchsia -ADOPTION PENDING a Tan/Yellow/Fawn Labrador Retriever / MixedLabrador Retriever · Akron, OHPlease contact D ( [email protected] ) for more information about this pet. FUCHSIA Female 4 mons old 18 lbs $300 Adoption charge These...http://www.adoptapet.com ·4 days ago on Adopt-a-Pet.comTools
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text:
rogerfederer.com - Gästebuch
Navigation mit Access Keys
- [Alt + 0] - Startseite
- [Alt + 1] - Navigation
- [Alt + 2] - Inhalt
- [Alt + 3] - Kontakt
- [Alt + 4] - Sitemap
- [Alt + 5] - Suche
Danke für eure Mitteilungen! Bitte beachtet, dass pro Person und Tag zwei Nachrichten möglich sind und die maximale Länge 500 Zeichen beträgt. Unangebrachte Mitteilungen werden gelöscht.
22.06.2016 | 13:36
I have reported those extremely offensive posts THREE times to no avail!!! Perhaps the report function does not work??
22.06.2016 | 13:13
Please can someone delete those awful messages from a few days back. They have no place anywhere, but especially not on this website. They are extremely offensive and you and we should not have to be subjected to them.
22.06.2016 | 13:06
Hi Roger It was great to see you on the court again at Halle. Watching tennis is never the same without you there. Do hope that you are completely recovered and that you will be mentally strong for what awaits you at Wimbledon. I am really not interested in how many slams you have etc, but hope you go deep into the tournament so we get to see you play a lot! And winning the title of course would be great, but as you say, one game at a time. All the best for next week.
Rf Brand
22.06.2016 | 06:33
I watch a lot of tennis to get pointers on things for my kids to work on and techniques to use. While watching I noticed the brand name RF and how unique it is. I was wondering if you would ever add a word or two with the brand.
22.06.2016 | 04:14
I am impatiently awaiting your next Grand Slam action at Wimbledon and that you play sublimely, beautifully and and win of course!
Jean Claude Grin
22.06.2016 | 01:58
Merci pour tout le plaisir que vous nous avez donné depuis tout ce temps , nous vous souhaitons, ainsi qu'à votre famille, tout le bonheur du monde, jusqu'à la fin des jours
bea uzielli
21.06.2016 | 22:15
I have admired you for years. You are my tennis god. I truly love your game and your cool and calm demeanor. I watch you and you look like you are performing a dance on the courts and you are always there for the ball. It is totally selfish but you have given me such pleasure watching you. I followed Borg for years and watched him at Roland Garros but you are the best. I wish more players would emulate your style. Good luck at Wimbledon I will be watching


text:
Star Tracks
Winfrey spreads the word: She's got her own station. Plus: Jennifer Aniston, Tom & Katie, and more
Credit: Flynet
Published: Monday Sep 25, 2006 | 05:30 PM EDT
More from PEOPLE
Latest News!
- Chris Brown in Legal Trouble Again After Former Manager Accuses Him of 'Brutally Attacking' Him
- Read the Cover Story: Matthew McConaughey: Love, Family & What I've Learned
- WATCH: Judy Garland's Daughter Lorna Luft Sings 'Over the Rainbow' for the First Time, in Tribute to Orlando, Stonewall and Her Late Mother
- Charlotte Tilbury Reveals the Inspiration Behind the Lipstick She Co-Created with Kim Kardashian West
- Free State of Jones: The Incredible True Story of Newton Knight and His Private Rebellion Against the Confederacy


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The Golden Horsequeen train as seen from the top of Playland
Within The Golden Horsequeen, you can eat fried cheese and watch music-wrangling entertainment. Make sure to check your tolerance level so you can catch a rendition of the "train" song with classic pianists, Cory Heffalump and the Heffalumpcories.
Run from Pirate Mode
© copyright 2011–2016
A Pants Aflame production


text:
More rumours surface of mid-size KTM adventure bike
New KTM will supposedly be powered by a parallel twin.
Return of the Salt: Racing should return to Bonneville this year
The Bonneville salt flats have fallen on hard times lately, but it sounds like things are turning around.
British dealer leaks hint at BMW G310 pricing
BMW's new machine will undercut several rival beginner bikes on cost.
Race results: Pikes Peak International Hillclimb
Electric bikes once again proved they have staying power at the PPIHC.
Motorcycle + moose = near escape
Newfoundland man films close call on highway.
Video: "Delivery Expert" vs. bike
Here's yet another video showing why it's smart to wear a camera while you commute. Warning: NSFW language.
Ryan Pyle working on Canadian moto-trip series for China
Moto-adventurer/videographer is crossing his homeland by motorcycle, filming for overseas audience.
Race Report: Assen GP
Who did what in the Netherlands? Find out the surprise winner of the premier class race at the Assen GP.
Race Report: CSBK double-header at St-Eustache
Find out the winners and losers at CSBK's Quebec round.
Yamaha concept bikes take a weird turn
The 05GEN and 06GEN prove Yamaha's designers aren't afraid to think outside the box. Sometimes, they even put the box on wheels and call it a concept vehicle.


text:
Top Stories
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Fenix for Twitter for Android, World Factbook for iOS and more!
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My Budget Book for Android, The Mindfulness App for iOS and more!
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eWeather HD for Android, Stats! for iOS and more!
Behold The Internet's Favourite Bathroom
Remember a few months ago, when we talked about the bathroom supply company on a quest to find America's best restroom — a dubious honour — by polling the internet? Well, today they announced the winner, and somewhat ironically, it recreates nature around those who are answering calls of nature.
This Sink-In-A-Box Tucks Away To Keep Your Bathroom Tidy
New Bathroom Clubs Will Let You Pay To Poop In Private
A new startup is betting that you can't find a suitable public restroom to relieve yourself — and that you'll pay top dollar for a cushy seat when the urge strikes. Posh Stow and Go is billing itself as New York's "first members-only day storage and bathroom facility", with memberships that allow you to pay-as-you-poo.
This Sleek Briefcase Hides An Easy To Clean Portable Pet Potty
These Beautiful Overflowing Baths Are Soak Sanctuaries
This Crazy Garden Bathroom Classes Up Your Drunken Relief
Pull This Mirror Out Of The Wall Instead Of Leaning Forward Awkwardly
Adorable Toilet Paper Tree Lets You Proudly Display Your Extra Rolls
Why hide your toilet paper stock in a cabinet that guests will just have to hunt through when they run out? This stylish laquered steel tree can be mounted to the wall near your loo where it will store up to 14 extra rolls in plain sight, without looking like an eyesore.
No One Can Hear What You're Doing In These Musical Rhythmic Potties
In an attempt to make the often overused and undermaintained portable toilets not the worst part of a music festival in Argentina, the organisers decided to make a bank of stalls one of the musical acts.


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Photo SpecialStars Go Loco for Lollipops!
From Snooki and Miley to Katy and Kim, celebs can't get enough of these classic sugary sweets
Credit: XposurePhotos
Updated: Thursday Jul 08, 2010 | 06:00 AM EDT By: Kate Hogan and Ainka Shackleford
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What am I? Riddle: The eight of us go forth, not back, To protect our
Riddle Info
|Category : What am I?
|Submitted By : Chris
The eight of us go forth, not back,
To protect our
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Rating: 4.00 out of 5
Based on 4 riddle rater's.
The eight of us go forth, not back, To protect our king from a foe's attack. What are we?
Want To See The Answer For The eight of us go forth, not back, To protect our riddle?
Chess pawns.
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|I hold all that has been and all that will be, with
|I am strongest when you see me as round but I am oft
|I come in every shape and size and every color. I br
|From house to house I go, a messenger small and slig
|Two bodies have I though both joined in one. The sti
|I cannot be felt, seen or touched; yet I can be foun
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|When young, I am sweet in the sun. When middle-aged,
|If I'm walking then I must be running. However, if I
|I am not an insect. You see me in everyday life. I s


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Recommended siteA-Z Lyrics Universe
Lyrics/song texts are property and copyright of their owners and provided for educational purposes.
Notes Of Def Lyrics by Lakim Shabazz
Notes Of Def by Lakim Shabazz
(Okay budddy - start playin)
Hush-hush pooh-putts, I lay ya like sheet rock
He thought he'd rock me, what a peacock
You ( ? ) creampuff cornpie
I'd get a million for my rhymes if I took em to a pawnshop
A musical menace, in awareness I make slammin hits
I got flavor more than a banana split
Prepare yourself for a hip-hop, a knock, a blast
A hitman for hire by the name of Lak Shabazz
I elevate till I raise the roof
Girls get naked and give me their bathing suits
Like a magnet I cling to the mic, I don't swing a knife
I'm like GE, I 'bring good things to life'
One of the chosen few holding you under siege
Wanna bleed, I treat you like weed and a fonto leaf
Roll ya, smoke ya, you should hold ya breath
I see smoke comin out your ears from the notes of def
It ain't nothin like ( ? ) listenin to a serious saxophone
That cracks the dome open wide
To a smooth sound, who's bound to do now
Not too many, I see a lot of them go and hide
The subject is that I must get
Hype, this is a chain, a connnection of ruffnecks
You're weak and not wise, you move counterclock-wise
You should know that I swap flies
The microphone gets clutched like a turning kit
Gimme a scratch, watch me burn a bit
Yo, I hold information like a microchip
I'm rough and rugged, I might as well go head and flip
Into a lyrical round-off
All I hear in my ear is that they love the way it sounds off
The way I beat on a rap was quite brutal
I make em completely ineffective, futile
Rhymes I could rock, I'm in a good spot
I turn sell out crowds and pack em in like Woodstock
Been a long time since you heard a rhyme like mine
You're impatiently waiting for the punchline
But it won't come till I'm done, so beware, son
My vocals are deadly, most get scared and run
For reinforcements, I'll enforce this
Law of how to get raw, watch my force rip
Take a sip, the beats'll hit you
Here's a chance to dance, now may the force be with you
Rhymes ( ? ) like kerosine
You ride my saddle, you wanna battle, you get creamed
You better quit I don't think you can deal with
I was made mentally, physically fit
To take heads, cold rip to shreads
Call on the coastguard, I rip the feds
45 King is in the effect mood
He'll produce and get loose with a correct groove
You need to back off, you can't hang with us
We're not dope, we're more like angel dust
The earth is mine, every square mile of it
You miss the flavor, got piles of it
I drew my path for those that follow it
My impact is like that of a hollow tip
I'll arrange the style, don't change the dial
I'm refined with the rhyme that'll make you smile
Cee Just remain serious, no time to play
Stay still, nobody move, watch him display
Talents and techniques as I speak, the weak
Freak cause I'm sleak and unique
Horns are horny, the snare drum makes some retreat
Cee Just on the cut and the King's on the beat
My voice is choice from baritone to bassclef
And these are the notes of def
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Betty White Refuses to Speak to Stepdaughter
"Golden Girls" star Betty White has refused to end a 30-year feud with her stepdaughter Martha Ludden. The veteran actress wed Ludden's father, U.S. TV personality Allen Ludden, in 1963 when his daughter was 13.
Martha resented White for taking the place of her mother, who had died just two years earlier, in 1961, and the pair never got along. The teenager turned her anger into rebellion and her behavior caused friction with her own father.
A source tells the National Enquirer, "Allen used to argue with Martha constantly over her... anger towards Betty. Her tumultuous relationship with her father caused him a lot of grief." Allen was eventually diagnosed with stomach cancer and passed away in 1981 - and White has never forgiven Martha for causing so many problems, according to the tabloid.
The insider says, "I think Betty blamed Martha for making Allen's last years nothing but misery and heartache."
Almost three decades after Allen's death, White is still ignoring all attempts by Martha to reconcile. Martha confirms, "The last time I spoke with my stepmother, Betty White, was 30 years ago."
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text:
|Publication number
|Publication type
|Application number
|Publication date
|Feb 7, 1989
|Filing date
|Sep 14, 1987
|Priority date
|Sep 14, 1987
|Fee status
|Also published as
|Publication number
|Mark S. Schaberg
|Original Assignee
|Minnesota Mining And Manufacturing Company
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (16), Non-Patent Citations (4), Referenced by (2), Classifications (12), Legal Events (7)
|External Links: USPTO, USPTO Assignment, Espacenet
This invention relates to compounded peroxide-curable fluorocarbon elastomer gums and cured articles made therefrom having improved resistance to amines. In another aspect, this invention relates to a method of improving the resistance of peroxide-cure fluorocarbon elastomer articles to amines.
Fluorocarbon elastomers, such as the peroxide curable type, are known for their excellent heat resistance and resistance to many chemical reagents; however, the resistance of fluorocarbon elastomers to fluids containing ammonia or amines is not sufficient for many applications (see West, A. C. and Holcomb, A. G., "Fluorinated Elastomers", Kirk-Othmer, Encyclopedia of Chemical Technology, Vol. 8, pp. 500-515, Table 4, 3d ed., John Wiley & Sons, 1981). Many motor oil formulations include amine-based corrosion inhibitors. These amine-based corrosion inhibitors or antiwear or antioxidant agents reduce the life of conventional fluorocarbon elastomer articles, such as hoses, gasket seals, O-ring seals, diaphragms, etc., due to chemical degradation of the fluorocarbon elastomer by the amine-based corrosion inhibitors.
The reactions leading to chemical degradation of fluorocarbon elastomer products are not well understood, although extensive work has been reported. For example, Abu-Isa et al in Rubber Chemistry and Technology, Vol. 58, p. 326-349 (1985) have shown that the extent of degradation is greater when dithiocarbamate additives are present in oil that comes into contact with the elastomer product.
Briefly, in one aspect, this invention relates to a peroxide-curable fluorocarbon elastomer gum composition comprising a peroxide-curable fluorocarbon elastomer gum with bromine or iodine atom cure sites and, dispersed in the gum, normally solid, inorganic chloride or bromide salt which imparts amine resistance to the cured elastomer article.
The additives are normally solid, metal or ammonium chloride or bromide salts. Examples of such salts are LiCl, LiBr, CaBr2, MnCl2, CoCl2, CoBr2, NiBr2, ZnCl2, ZnBr2, NH4 Cl, and NH4 Br, including hydrates thereof. Preferred salts are non-deliquescent. While the salts can be dispersed as finely-divided solids, in general it is more effective to disperse the salts in the elastomer gum as a solution, for example as a methanol solution.
The amount of the salt used is that quantity sufficient to improve the amine resistance of the fluorocarbon elastomer article. That amount generally does not adversely affect the other chemical and physical properties of the fluorocarbon elastomer article, e.g. hydrocarbon solvent resistance and compression set resistance. In general, the amount of the salt (on an anhydrous basis) dispersed in the fluorocarbon elastomer gum is 0.25 to 5 parts, preferably 0.5 to 1.5 parts, by weight per 100 parts by weight of the fluorocarbon elastomer gum.
It is preferred to compound the inorganic salt of this invention into the fluorocarbon elastomer gum formulation and remove any solvent before adding the peroxide and co-curing agent and other ingredients.
The peroxide-curable fluorocarbon elastomer gums useful in this invention are known in the art. One class is gums which comprise interpolymerized units derived from the fluorine-containing monomers, vinylidene fluoride, hexafluoropropylene, and, optionally, tetrafluoroethylene and a bromine- or iodine-containing cure-site monomer. Another class is gums which comprise interpolymerized units derived from said fluorine-containing monomers and having terminal portions with bonded bromine or iodine atoms as cure sites. Prior art disclosures of fluoropolymers made with bromine- or iodine-containing materials include U.S. Pat. No. 3,351,619 (Warnell) which discloses use of a vinyl ether containing a fluoroalkyl iodide group; U.S. Pat. No. 3,306,879 (Pattison) which discloses the use of such compounds as 2-bromoethyl vinyl ether and 2-iodoethyl vinyl ether; U.S. Pat. Nos. 4,035,565 (Apotheker et al) and 4,263,414 (West) which disclose the use of bromine-containing olefins, such as bromotrifluoroethylene, 1-bromo-2,2-difluoroethylene, and vinyl bromide; U.S. Pat. Nos. 4,251,399 (Tomoda et al), 4,243,770 (Tatemoto et al), and 4,260,698 (Tatemoto et al) which disclose the use of iodinated compounds such as I(CF2 CF2)2 I; European patent application No. 0 079 555 (Kojima et al), published May 25, 1983, which discloses the use of perfluoro(2-bromoethyl vinyl ether), and U.S. Pat. No. 4,564,662 (Albin) which discloses the use of a bromo- and an iodo-containing vinyl ether, which prior art disclosures are incorporated herein by reference for their disclosures of peroxide-curable gums useful in the practice of this invention. The curing of fluorocarbon elastomer gums with organic peroxides is likewise disclosed in said prior art disclosures, which disclosures of curing are incorporated herein by reference.
In one preferred embodiment, the fluorocarbon elastomer gums used in this invention are copolymers whose interpolymerized units comprise, consist of, or consist essentially of 45 to 85 mole percent of units derived from vinylidene fluoride, 10 to 50 mole percent of units derived from hexafluoropropylene, 0 to 30 mole percent of units derived from other highly fluorinated monomers, such as tetrafluoroethylene, and 0.15 to 1.5 mole percent of units derived from said bromine-containing or iodine-containing olefin cure site monomers.
Preferred curing agents are organic peroxides such as benzoyl peroxide, bis(2,4-dichlorobenzoyl)peroxide, dicumyl peroxide, t-butylhydroperoxide, di-t-butyl peroxide, t-butylperoxy benzoate, and lauroyl peroxide. Particularly useful commercially available peroxides are 2,5-dimethyl-2,5-bis(t-butylperoxy)hexane and 2,5-dimethyl-2,5-bis(t-butylperoxy)hexyne-3 which are the active ingredients of products sold as "Luperco" 101XL and 130XL, respectively. The amount of peroxide curing agent to be mixed with the fluorocarbon elastomer gum generally will be 0.1 to 10, preferably 1 to 5, parts per 100 parts of the fluoroelastomer gum. Along with the peroxide curing agent it will generally be desirable to incorporate in, or compound with, the gum a cocuring agent (or coagent), such as is commonly used in peroxide vulcanization of fluorocarbon elastomers to obtain a tighter or faster cure or better compression set. Such cocuring agents generally will be used in amounts of 0.1 to 10, preferably 1 to 5, parts by weight per 100 parts by weight of the fluorocarbon elastomer gum. Cocuring agents which can be used include triallylcyanurate, diallylphthalate, allylmethacrylate and, particularly, triallylisocyanurate.
In many cases, for optimum fluorocarbon elastomer physical properties, such as tensile strength, it will be desirable to include in the compounded gum a reinforcing filler such as carbon black, silica, iron oxide, or zinc oxide, e.g. 5 to 60 parts by weight per 100 parts by weight of the fluorocarbon elastomer gums (e.g. as described in said U.S. Pat. No. 4,263,414). Conventional compounding adjuvants, such as magnesium oxide and calcium oxide as acid acceptors, pigments, plasticizers, and processing aids which are compatible with the gum, can also be added to the gum.
In making the shaped articles of this invention, generally the compounded, peroxide-curable fluorocarbon elastomer gum is extruded, and the extruded article is cured in an autoclave at about 150� C. for 30 minutes to 3 hours, or is molded in a cavity or transfer mold at a temperature in the range of 125� to 250� C. for 1 to 50 minutes or more at about 5 to 10 MPa. The extruded or molded article is then heated in a circulating-air oven and post-cured at about 170� to 260� C. for about 2 to 24 hours, preferably at about 230� C. for 16 hours, yielding a cured (that is, crosslinked or vulcanized) shaped article which is elastomeric (i.e., an article made from materials which, when cured into a test specimen and slowly stretched at room temperature to at least twice its original length and released, returns rapidly to essentially its original length).
The peroxide-curable fluorocarbon elastomer gum composition of this invention can be employed in making molded or extruded articles of manufacture, such as gasket seals, O-ring seals, diaphragms, tubing, ducting, carburetor needle valve tips, fuel pump cups, shaft seals, and other molded goods, and especially those which come into contact with amines. The particular application will usually be determined by the properties of the cured polymer, the requirements of such applications being well known and described, for example, in the prior art publications described hereinbefore.
Objects and advantages of the invention are illustrated in the following examples in which all parts, percentages and ratios are by weight unless otherwise noted.
The following examples illustrate the beneficial results of adding various inorganic chloride or bromide salts to conventional, peroxide-curable, fluorocarbon elastomer gum formulations, compounding, molding, and curing the formulated mixture, and exposing the cured article (a "dumbbell" test specimen) to amine-containing motor oil.
The formulations were prepared by banding the gum on a two-roll mill, adding the salt solution, and then adding the other ingredients as a blend. For convenience in preparing the laboratory test specimens, the salt was dissolved in twice its weight of methanol; where the salt was not sufficiently soluble in methanol, a 50:50 methanol:water medium was used.
The gum was initially banded on a two-roll, uncooled mill, and the salt solution was slowly added until uniformly mixed, the gum being cross-cut several times to yield a gum sheet with salt dispersed therein. The quantity of gum and solvent was sufficiently small that substantially all the solvent volatilized on the mill.
The gum sheet was then banded on a water-cooled mill and a blend of all remaining components was added. The compound was molded and the test samples prepared. The test specimens were press cured for 15 minutes at 7 MPa and 177� C., then post cured in a circulating air oven at 230� C. for 16 hours.
The amine-containing motor oil was prepared by dissolving, in 90 parts by weight of standard A$TM Number 1 oil, 10 parts of a mineral oil concentrate comprising a bis-succinimide, zinc dialkyl dithiophosphate, and organic amines. The concentrate, having an amine equivalent weight of about 1000, is commercially available as "HiTec 854" from Ethyl Petroleum Additives, Inc. and was used because it is regarded in the industry as a medium that normally severely degrades fluorocarbon elastomers.
Exposure of the cured test specimen was by immersion of the specimen as a dumbbell (ASTM Die D) in the amine-containing motor oil at 177� C. for 70 hours. The physical properties of the exposed specimen were measured in accordance with ASTM method D412-80.
Using the procedure described above, solutions of various salts were combined with the compounding gum formulation ("compound") set forth below in Table I.
TABLE I______________________________________Fluorocarbon elastomer gum* 100 parts by weightCarbon black** 30Ca(OH)2 3Peroxide curatives*** 2.5Triallylisocyanurate 2.5______________________________________ *The elastomer used in the examples contained units corresponding to a monomer mixture of 60 wt. % vinylidene fluoride, 39.5 wt. % hexafluoropropylene, and 0.5 wt. % 1,1difluoro-2-bromo ethylene. **The carbon black used is a reinforcing black supplied as "Thermax N990" by J. M. Huber Corp. ***The peroxide curative is a 45% active preparation of 2,5dimethyl-2-5 di(tbutylperoxy) hexane on calcium carbonate, supplied as "Luperco 101XL" by Pennwalt Corp.
Table II sets forth the composition and properties of post-cured test samples of the invention before and after exposure to the amine-containing motor oil (Examples 1-3). For comparison, Table II also sets forth the results for the compound without a salt (Example A) and for the compound with an ineffective halide salt (Example B). The weight of salt used was selected to maintain a constant 0.013 moles of halogen per hundred parts by weight of gum.
TABLE II______________________________________Component Examples(parts by weight) A B 1 2 3______________________________________Compound (see Table I) 138 138 138 138 138NaCl -- 0.76 -- -- --CoCl2.6H2 O -- -- 1.55* -- --NH4 Br -- -- -- 1.27 --ZnBr2 -- -- -- -- 1.46 Post Cured PropertiesTensile, MPa 15.7 13.7 17.1 18.4 15.7Elongation, % 229 219 252 213 228100% Modulus, MPa 3.53 3.36 3.43 4.34 3.63Shore A Hardness 70 71 70 71 72 Properties After Exposure of Post Cured SamplesTensile, MPa 7.05 6.61 10.12 10.30 11.16Elongation, % 135 132 170 150 177100% Modulus, MPa 4.65 4.50 4.19 5.02 4.15Shore A Hardness 71 71 71 71 71______________________________________ *Hydrous weight.
Although the salt concentration was not selected to provide optimum retention of properties, the data in Table II provides a useful comparison of effectiveness at a given low concentration. Both Control Example A (the standard, unmodified compound) and Comparative Example B (to which NaCl was added) lost more than half of their initial tensile strength after exposure to amine-containing motor oil. Each of Examples 1, 2 and 3 retained 60 to 70% of their initial tensile strength after exposure to these severe conditions.
Table III shows the superior amine resistance imparted to the elastomer by specific salts in contrast to the standard, salt-free compound, in Control Example C.
TABLE III__________________________________________________________________________ ExamplesComponent: C 4 5 6 7 8 9 10 11 12 13 14__________________________________________________________________________Compound*, g 138 138 138 138 138 138 138 138 138 138 138 138Salt:type -- LiBr CaBr2 MnCl2 CoBr2 NiBr2 ZnBr2 NH4 Cl NH4 Br LiCl ZnCl2 CoCl2.6H.sub. 2 Oamt., g -- 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.5** Post-Cured Physical PropertiesTensile, MPa 15.0 16.9 14.7 16.0 14.2 15.4 15.9 16.2 16.2 16.1 14.8 13.1Elongation, % 261 326 235 276 312 315 251 233 230 259 250 265100% Modulus, MPa 3.31 3.53 3.85 3.55 3.45 3.43 3.99 3.82 3.94 4.30 3.80 3.10Shore A Hardness 68 67 67 70 68 67 70 69 69 70 70 70 Properties After Exposure of Post-Cured SpecimensTensile, MPa 7.16 10.24 9.29 9.84 10.44 9.74 11.05 10.80 9.96 10.03 9.03 9.36Elongation, % 159 200 164 187 216 202 187 170 161 175 171 192100% Modulus, MPa 3.95 3.23 4.74 3.63 3.07 2.88 4.13 4.19 4.53 4.32 3.87 3.38Shore A Hardness 68 66 68 68 65 67 70 68 68 68 69 68__________________________________________________________________________ *See Table I for formulation. **Hydrous weight.
Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention.
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|U.S. Classification
|524/428, 524/435, 2/910, 524/546, 524/436
|International Classification
|Cooperative Classification
|European Classification
|Sep 14, 1987
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