text:
|Publication number
|Publication type
|Application number
|Publication date
|Jan 24, 2012
|Filing date
|May 20, 2008
|Priority date
|Nov 20, 2001
|Fee status
|Also published as
|Publication number
|Jean-Paul Benayoun, Didier Dhaler, Jacques Kieffer, John White
|Original Assignee
|Bluestar Silicones France
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (10), Referenced by (1), Classifications (27), Legal Events (1)
|External Links: USPTO, USPTO Assignment, Espacenet
This application claims priority under 35 U.S.C. §119 of FR 01/14996, filed Nov. 20, 2001, and is a continuation of U.S. patent application Ser. No. 10/849,466, filed May 20, 2004 now abondoned, and PCT/FR 02/03952 filed Nov. 19, 2002, and designating the United States, published in the French language as WO 2003/044084 A3 on May 30, 2003, each hereby expressly incorporated by reference in its entirety and each assigned to the assignee hereof.
This application is a Continuation-in-Part of PCT Application No. PCT/FR02/03952 designating the United States and filed on Nov. 19, 2002, which claims priority from French Application No. 01/14996 filed on Nov. 20, 2001, the disclosures of which are incorporated herein in their entirety by reference.
The field of the invention is that of crosslinkable or crosslinked silicone compositions capable of being used in particular to form a water-repellant and release coating or film on a fibrous or nonfibrous support, for example made of paper or the like, or alternatively made of natural or synthetic polymers.
More specifically, the invention relates to silicone compositions of the type of those comprising:
The invention also relates to the preparation of silicone compositions of this type.
The invention also relates to the processes for the manufacture of articles made of crosslinked silicone, in particular coatings, e.g. water-repellent and/or release coatings, for fibrous or nonfibrous flexible supports (paper or polymer film), from the compositions targeted above.
For example, these liquid silicone compositions are applied to support films in industrial coating devices comprising rolls operating at a very high speed (for example 600 m/min). It is obvious that, in these very high-speed coating procedures, the viscosity of the liquid silicone coating composition must be precisely adapted to the coating operating conditions.
The liquid silicone coating compositions of more particular interest in the context of the invention are solvent-free.
According to an alternative form, the silicone phase of these liquid silicone coating compositions can be diluted in a solvent. According to another more advantageous alternative form, in particular for reasons of health and safety, the liquid silicone composition is an aqueous dispersion/emulsion.
In practice, the degree of deposition of release silicone is between 0.1 and 2 g/m2, preferably 0.3 and 1 g/m2, which corresponds to thicknesses of the order of a micrometer.
Once applied to the flexible support, the silicone composition crosslinks to form a firm, release and/or water-repellent, coating made of silicone (e.g. elastomer).
In view of the very high-speed industrial coating rates, the kinetics of crosslinking have to be instantaneous and the crosslinking has to be correct, that is to say that the release silicone films have to be sufficiently crosslinked to be able to fulfil as best as possible their release role and to possess the desirable mechanical qualities. The assessment of the quality of the crosslinking of the release silicone film can be carried out in particular through quantitative determination of the uncrosslinked extractable compounds, the amount of which must be as small as possible.
The ability to release of the free outer face of the silicone coating is expressed through the detachment force, which has to be weak and controlled, for the element intended to be positioned on the support coated by the release silicone film. Conventionally, this element can be the adhesive face of a label or of a tape of the same kind.
Thus, in addition to this weak and controlled detachment force, the adhesion of the silicone coating to its support has to be very high. This property of adhesion is assessed, for example, using the rub off trade test, which consists in rubbing the surface of the coating with a finger and then measuring the number of successive passes which result in damage to the coating.
It is also important for these silicone coating compositions which can be crosslinked by hydrosilylation, e.g. ≡SiH/≡SiVi, to have a lifetime at ambient temperature which is as long as possible, when they are in the form of a coating bath in industrial coating devices.
The flexible supports coated with a release silicone film can be, for example:
In the case of solvent-free liquid silicone systems which crosslink by polyaddition (Si—H/Si-alkenyl-Vi-), crosslinking is carried out under thermal activation. These reaction conditions are not suitable for some heat-sensitive supports, such as those comprising polyethylene (PE), such as, for example, PE films or paper coated with PE, or those of the thermally printable paper type. These heat-sensitive supports do not withstand being heated to temperatures of greater than 90° C. All the difficulty thus lies in obtaining, for these heat-sensitive supports, correct crosslinking at low temperature, for example of less than or equal to 110° C. (85-90° C.).
The use of crosslinking agents of the type of those comprising siloxyl units: dimethylhydrosiloxyl (M′), methylhydrosiloxyl (D′), dimethylsiloxyl (D) and trimethylsiloxyl (M), for liquid silicone compositions which can be crosslinked by polyaddition (≡SiH/SiVinyl), to form release coatings on flexible supports (coated or uncoated paper, polymer films, and the like), is generally already disclosed.
This is thus the case in Patent Application EP A-0 523 660, which discloses silicone compositions which can be crosslinked in a few seconds at temperatures below 100° C. and which comprise network (nonlinear) ≡Si-Vi POS resins and ≡SiH POS crosslinking agents of MD′, MDM′ type. It is not at all shown in this document that the crosslinking of the silicone films obtained is correct. The level of extractables is not measured in the examples.
EP-A-0 523 660 does not relate to a specific ≡SiH POS crosslinking agent which confers advantageous properties on the crosslinked coating in terms of reduced level of extractables and of duration of stability of the bath of liquid silicone coating composition, in particular.
In this context, an essential object of the present invention is to provide a novel use of specific ≡SiH POSs as crosslinking agents in liquid silicone coating compositions which can be crosslinked instantaneously at low temperature (≦110°, preferably ≦100° C., e.g. of the order of 85/90° C.) to give a release and/or water-repellent coating for a flexible support, while resulting in crosslinked silicone coatings of very good quality characterized by reduced levels of extractables.
Another essential object of the invention is to provide a novel use of specific ≡SiH POSs as crosslinking agents in liquid silicone coating compositions which can be crosslinked instantaneously at low temperature to give a release and/or water-repellent coating for a flexible support, while exhibiting long bath lifetimes at ambient temperature.
Another essential object of the invention is to provide a novel use of specific ≡SiH POSs as crosslinking agents in liquid silicone coating compositions which can be crosslinked instantaneously at low temperature to give a release and/or water-repellent coating for a flexible support and which result in correctly crosslinked silicone coatings having entirely satisfactory release properties.
Another essential object of the invention is to provide a novel use of specific ≡SiH POSs as crosslinking agents in liquid silicone coating compositions which can be crosslinked instantaneously at low temperature to give a release and/or water-repellent coating for a flexible support and which result in correctly crosslinked silicone coatings having entirely satisfactory attachment properties.
Another essential object of the invention is to provide a novel use of specific ≡SiH POSs as crosslinking agents in liquid silicone coating compositions which can be crosslinked instantaneously at low temperature to give a release and/or water-repellent coating for a flexible support and which result in correctly crosslinked silicone coatings having entirely satisfactory mechanical properties.
Another essential object of the invention is to provide a novel use of specific ≡SiH POSs as crosslinking agents in liquid silicone coating compositions which can be crosslinked instantaneously at low temperature to give a release and/or water-repellent coating for a flexible support and which result in correctly crosslinked silicone coatings having entirely satisfactory water-repelling properties.
Another essential object of the invention is to provide a novel liquid silicone coating composition which can be crosslinked instantaneously at low temperature to give a release and/or water-repellent coating for a flexible support, this composition additionally having the same qualities as those mentioned above for the use.
Another essential object of the invention is to provide a novel liquid silicone coating composition which can be crosslinked instantaneously at low temperature to give a release and/or water-repellent coating for a flexible support, this composition additionally being easy to prepare and economical.
Another essential object of the invention is to provide a process for the production at low temperature of release and/or water-repellent crosslinked silicone coatings on heat-sensitive flexible supports.
These objects, among others, are achieved by the present invention, which relates first to a novel use as crosslinking agent, in a silicone composition capable of crosslinking by polyaddition to form a water-repellent and release coating for a fibrous or nonfibrous support,
The use according to the invention of carefully selected ≡SiH POS crosslinking agents makes it possible to produce release coatings on heat-sensitive supports, such as polyethylene (PE). By virtue of the invention, correct crosslinking of the coating is provided at a low temperature, for example 90° C., under industrial coating conditions.
Furthermore, these novel ≡SiH POS crosslinking agents do not modify the rheological behaviour of the silicone composition, so that it is perfectly capable of being coated on any support and in particular on any flexible support.
This final property is all the more advantageous as, in the context of the invention, the silicone coating compositions can advantageously be "solvent-free". This means that they are devoid of solvent and in particular of organic solvent. The advantages which this provides regarding health and safety are easily understood.
The performance achieved by virtue of the invention in terms of quality of the crosslinking by polyaddition: reactivity/level of crosslinking/kinetics, are entirely advantageous, as testified thereto by the low levels of extractables obtained, as regards the reactivity and the level of crosslinking.
The formula of the ≡SiH POS crosslinking agent indicated above is an overall formula which covers:
Mention may be made, as examples of ≡SiH POS crosslinking agents of -b- type, of mixtures of ≡SiH POS comprising M and D′ units and of POS comprising M, D and D′ units, or mixtures of ≡SiH POS comprising M and D units and of POS comprising M′, D and D′ units, or mixtures of ≡SiH POS comprising M and D′ units and of POS comprising M and D units, or mixtures of ≡SiH POS comprising M′ and D′ units and of POS comprising M and D units.
Preferably, the silicone composition involved in the use according to the invention is composed of ≡SiH POS and of ≡Si-alkenyl (e.g. Vi) POS with a linear, optionally branched, structure, with the exclusion of ≡SiH POS and of ≡Si-alkenyl (e.g. Vi) POS having a network crosslinked structure.
According to an advantageous form of the invention, the support intended to be coated is made of a heat-sensitive material, preferably a flexible material, and more preferably still is chosen from flexible supports comprising polyethylene and/or poly(ethylene terephthalate) and/or polypropylene and/or poly(vinyl chloride) and/or from thermally printable flexible supports; polyethylene films and paper coated with polyethylene being very especially preferred.
According to the invention, for the crosslinking of the coating, the support coated with the polyaddition silicone composition is placed at a temperature of less than or equal to 110° C., preferably of less than or equal to 100° C. and more preferably still of between 75 and 95° C., for less than 60 seconds, preferably less than 10 seconds.
Advantageously, the silicone composition is a mixture formed of:
Preferably, use is made of at least one POS (I.1) of Si-alkenyl type, for example Si-Vi type, and of at least one POS (I.2) of Si—H type.
The POS (I.1) is, by weight, one of the essential constituents of the formulation.
Advantageously, this POS (I.1) is a product comprising units of formula:
in which:
It is advantageous for this polydiorganosiloxane to have a viscosity (at 25° C.) at least equal to 10 mPa·s, preferably between 50 and 1000 mPa·s.
All viscosities concerned with in the present account correspond to a dynamic viscosity quantity at 25° C. referred to as "newtonian", that is to say the dynamic viscosity which is measured, in a way known per se, at a shear rate gradient which is sufficiently low for the viscosity measured to be independent of the rate gradient.
The polyorganosiloxane (I.1) can exhibit a linear, branched or cyclic structure. Its degree of polymerization is preferably between 2 and 5000.
Examples of siloxyll units of formula (I.1) are the vinyldimethylsiloxane unit, the vinylphenylmethylsiloxane unit and the vinylsiloxane unit.
Examples of polyorganosiloxanes (I.1) are dimethylpolysiloxanes comprising dimethylvinylsilyl ends, methylvinyldimethylpolysiloxane copolymers comprising trimethylsilyl ends,
methylvinyldimethylpolysiloxane copolymers comprising dimethylvinylsilyl ends, or cyclic methylvinylpolysiloxanes.
The polyorganosiloxane (I.2) is preferably of the type of those comprising siloxyll units of formula:
in which:
The dynamic viscosity ηd (at 25° C.) of this polyorganosiloxane (I.2) is ≧5, preferably ≧10, and more preferably still is between 20 and 1000 mPa·s.
The polyorganosiloxane (I.2) can exhibit a linear, branched or cyclic structure. The degree of polymerization is greater than or equal to 2. More generally, it is less than 5000.
Examples of units of formula (I.2) are: M′: H(CH3)2SiO1/2, D′: HCH3SiO2/2, D′: H(C6H5)SiO2/2.
Examples of polyorganosiloxane (I.2) are:
The polyaddition silicone composition bases may comprise only linear polyorganosiloxanes (I.1) and (I.2), such as, for example, those disclosed in patents: U.S. Pat. Nos. 3,220,972, 3,697,473 and 4,340,709.
The catalysts (II) are also well known. Use is preferably made of platinum and rhodium compounds. It is possible in particular to use the complexes of platinum and of an organic product disclosed in patents U.S. Pat. Nos. 3,159,601, 3,159,602 and 3,220,972 and European Patents EP-A-0 057 459, EP-A-0 188 978 and EP-A-0 190 530, or the complexes of platinum and of vinylated organosiloxanes disclosed in patents U.S. Pat. Nos. 3,419,593, 3,715,334, 3,377,432 and 3,814,730. The catalyst generally preferred is platinum. In this case, the amount by weight of catalyst (II), calculated as weight of platinum metal, is generally between 2 and 400 ppm, preferably between 5 and 200 ppm, based on the total weight of the polyorganosiloxanes (I.1) and (I.2).
Preferably, the crosslinking POS exhibits an ≡SiH/≡Si-alkenyl (Vi) molar ratio such that:
It is advantageous for the POS (I.1) to be a blocked linear polydiorganosiloxane comprising "Si-alkenyl" functional groups, preferably located at the chain end, exhibiting a viscosity of the order of 100 to 1000 mPa·s and a level of alkenyl functional groups La, expressed as equivalent number of alkenyl functional groups per 100 g of oil, of:
Likewise, the oil of use as crosslinking agent comprising at least one POS comprising ≡SiH functional groups (I.2) exhibits, preferably, a viscosity of the order of 5 to 150 mPa·s.
The complete curable compositions are fluid at standard temperature; their viscosity is generally of the order of 50 to 500 mPa·s at 25° C.
According to an alternative form, the release crosslinkable silicone composition includes:
The adhesion-adjusting system is selected from known systems. It can be those disclosed in French Patent FR-B-2 450 642, U.S. Pat. No. 3,772,247 or European Patent Application EP-A-0 601 938. Mention may be made, by way of examples of the adjusting systems based:
The retardant of the addition reaction (crosslinking inhibitor) can, for its part, be chosen from the following compounds:
These acetylenic alcohols (cf. FR-B-1 528 464 and FR-A-2 372 874), which are among the preferred thermal blockers for the hydrosilylation reaction, have the formula:
in which formula,
The said alcohols are preferably chosen from those exhibiting a boiling point of greater than 250° C. Mention may be made, by way of examples, of:
These α-acetylenic alcohols are commercial products.
Such a retardant is present in a proportion of 3000 ppm at most, preferably in a proportion of 100 to 2000 ppm, with respect to the total weight of the organopolysiloxanes (I.1) and (I.2).
According to another implementational route different from the "solvent-free" one, the composition is provided in the form of an aqueous emulsion/dispersion and then comprises at least one surfactant and optionally at least one agent for fixing the pH.
The agent for fixing and maintaining the pH is preferably a buffer system comprising HCO3 −/CO3 2− and/or H2PO4 −/HPO4 2−. Thus, in order to obtain the desired buffer effect, it will be advisable to introduce, in accordance with the invention, an HCO3 − and/or H2PO4 − salt, such as, for example, NaHCO3 and/or Na2CO3 and/or NaH2PO4 and/or Na2HPO4. It is obvious that any other salt with a different counteranion (e.g. K) might be suitable. In a particularly preferred way, use is in practice made of a buffer system composed of NaHCO3 which is incorporated in the emulsion.
The surfactant or surfactants capable of being present in the emulsion according to the invention as emulsifying agent are nonionic or ionic in nature.
According to an advantageous arrangement, the proportion of water in the emulsion is greater than or equal to 50% by weight, preferably greater than or equal to 55% by weight and, for example, in practice of the order of 55-60% by weight or alternatively of 85 to 90% by weight.
According to another of its subject-matters, the invention relates to a silicone composition capable of crosslinking by polyaddition to form a water-repellent and release coating for a fibrous or nonfibrous support, characterized:
To define the composition according to the invention, reference is made to the characteristics defined above in the context of the description of the use.
According to another of its aspects, the present invention relates to a process for the preparation of a silicone composition which can be used in particular as coating base for the preparation of release and water-repellent coatings, this composition being of the type of that defined above. According to this process, at least one (preferably linear) ≡Si-Vi POS oil (I.1) is mixed with the crosslinking agent composed of at least one ≡Si—H POS oil (I.2) of MM′DD′ type and/or of a mixture of oils comprising (preferably linear) POS molecules each carrying a portion of the MM′DD′ units present in the crosslinking agent. The catalyst (II) is also incorporated in the silicone phase with the optional other ingredients, such as the crosslinking inhibitors.
The mixing means and methodologies are known to a person skilled in the art, whether solvent-free or emulsion compositions.
These compositions can be applied using devices employed on industrial equipment for the coating of paper, such as a five-roll coating head, an air knife system or an equalizer bar system, to flexible supports or materials and can then be cured by moving through tunnel ovens heated to 70-200° C.; the passage time in these ovens depends on the temperature; this time is generally of the order of 5 to 15 seconds at a temperature of the order of 100° C. and of the order of 1.5 to 3 seconds at a temperature of the order of 180° C.
The said compositions can be deposited on any flexible material or substrate, such as paper of various types (supercalendered, coated, and the like), board, cellulose sheets, metal sheets, plastic films (polyester, polyethylene, polypropylene, and the like), and the like.
The amounts of compositions deposited are of the order of 0.5 to 2 g per m2 of surface to be treated, which corresponds to the deposition of layers of the order of 0.5 to 2 μm.
The materials or supports thus coated can subsequently be brought into contact with any pressure-sensitive adhesive material of rubber, acrylic or other nature. The adhesive material is then easily detachable from the said support or material.
According to another of its aspects, the present invention relates to a support, characterized in that it comprises at least one release coating obtained:
The following examples are given by way of indication and may not be regarded as a limitation on the scope and spirit of the invention.
giving the peel strength (PS) for a coating rate of 0.3 m/min and crosslinking temperatures of 86 to 95° C.
The coating of silicone on a Rotomec pilot-scale coating plant at 100 m/min (residence time of 3.6 s in the ovens) on a glassine 9564 support or on OPP CR 30 at different oven temperatures.
The temperature of the silicone layer is measured in-line using an infrared camera.
The coating, after coating and crosslinking, is characterized by the following tests:
TABLE 1 β/δ × 1000 = Test POS POS POS POS Catalyst (M′/D′) × SE No. (I.1) (I.2.1) (I.2.2) (I.2.3) (II) γ/δ = D/D′ 1000 (%) 1 100 4.6 — — 4.4 1.5 0 27 2 100 — — 6.9 4.5 1.2 36 3.5 3 100 2.9 — 2.6 4.4 1.28 22.7 7.5 4 100 — 1.0 4.8 4.5 0.80 23.2 4.0 5 100 1.0 — 5.5 4.4 1.08 28 4.5 6 100 2.3 — 3.5 4.4 0.86 17.4 7.5 Counter- 100 3.5 — 1.7 4.4 0.66 7.96 11.0 test 7 8 100 — 1.0 4.8 4.5 0.80 23.2 4.0 9 100 — 1.2 5.9 4.0 0.80 23.2 4.0 10 100 — 1.4 6.9 4.0 0.80 23.2 4.0 11 100 — 1.6 8.0 4.0 0.80 23.2 5.0
1. Reactivity
The level of extractables is measured as a function of the temperature of the paper. The results are given in Table 1 and in the appended
It is clearly seen that the crosslinking agent according to the invention with the structure ≡SiH POS (I.2.3): M′MD′D (Tests 2, 3 and 4), makes it possible to obtain the lowest levels of extractables, the mark of better reactivity. By virtue of the invention, formulations are accessible which can be crosslinked at low temperature: 80 to 85° C.
Test 3, which corresponds to a mixture of the ≡SiH POS (I.2.1): MDD′, and of the ≡SiH POS (I.2.3): MM′DD′, and Test 4, which corresponds to (I.2.2): MD′M, + (I.2.3): MM′DD′, show, in
A new series of crosslinking agents in accordance (Tests 13, 14, 17 and 19) or not in accordance (Countertests 12, 15, 16 and 18) with the invention was evaluated. The characteristics of these products, ratio γ/δ=D/D′ and β/δ×1000=M′/D′×1000, are given in the following Table 2.
The vinylated oil used is (I.1) as defined above and the catalyst is the catalyst (II) as defined above. The SiH/SiVi ratio is kept constant at 1.8 and the level of Pt is 100 ppm.
β/δ × 1000 =
Rub off
in %
γ/δ = D/D′
The crosslinking agents in accordance with the invention (Tests 13, 14, 17 and 19) have a good hold in the rub off test and exhibit levels of silicone extractables (SE) of less than 5%, it being known that, in accordance with the invention, SE<9-10%, preferably SE≦7.5% and more preferably still SE≦5%.
2. Detachment Force and Ageing, Tesa 7475 (In-Line)
The release properties were measured on coatings produced from a silicone formulation comprising a mixture of POS (I.2.3) crosslinking agent (82%)/POS (I.2.2) (18%). The peel profiles obtained and the stabilities towards ageing of these release properties are shown in
|Cited Patent
|Filing date
|Publication date
|Jul 23, 1980
|May 11, 1982
|Toshiba Silicone Co., Ltd.
|Heat-curable polysiloxane composition
|Nov 21, 1990
|Mar 16, 1993
|Rhone-Poulenc Chimie
|Organopolysiloxane composition containing a cyclopentenyl radical and crosslinkable to give an elastomer
|Jul 17, 1990
|Jun 1, 1993
|Shin-Etsu Chemical Co., Ltd.
|Curable silicone rubber compositions and products of curing thereof
|Jul 14, 1992
|Aug 31, 1993
|Wacker-Chemie Gmbh
|Siloxane copolymers containing alkenyl groups, their preparation and use
|Sep 11, 1995
|May 13, 1997
|Rhone-Poulenc Chimie
|Silicone compositions comprising long chain α-acetylenic alcohol hydrosilylation inhibitors
|Jun 19, 1997
|Aug 24, 1999
|Shin-Etsu Chemical Co., Ltd.
|Curable silicone release composition and release sheet
|Dec 19, 2002
|Sep 25, 2007
|Rhodia Chimie
|Crosslinking agent for a crosslinkable silicone composition with a low level of platinum based on a hydrogenated silicone oil comprising Si-H units at the chain end and in the chain
|Jul 15, 1992
|Mar 5, 1997
|Wacker-Chemie Gmbh
|Alkenyl group containing siloxane copolymers, their preparation and their use
|Nov 24, 1999
|Dec 10, 2003
|Dow Corning Toray Silicone Company, Ltd.
|Silicone composition for forming cured release films
|Title not available
|Citing Patent
|Filing date
|Publication date
|Dec 17, 2009
|Jun 24, 2010
|Applied Materials, Inc.
|High temperature electrostatic chuck bonding adhesive
|U.S. Classification
|427/387, 528/15, 525/477, 528/31, 428/480, 528/32, 428/500, 525/478, 428/447
|International Classification
|Cooperative Classification
|European Classification


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text:
Fleet Tn 2
(Carr 30, J White 74)
North Leigh 2
(Caton 25, Hole 32)
North Leigh twice let slip the lead as they drew at Fleet Town in Southern League Division 1 South & West on Saturday.
However, in the end, Mark Gee's side were grateful for a point after being forced to hold on in the latter stages.
Fleet started brightly, but gradually the Millers got a grip on the game and went ahead on 25 minutes when a corner wasn't cleared and Elliott Osborne-Ricketts returned the ball back into the box where Andy Caton fired home from five yards.
The hosts drew level five minutes later when Rob Carr drove in a shot which took a wicked deflection to beat North Leigh keeper Matt Bulman.
The visitors went back in front almost straight from the kick-off.
Morgan Williams was fouled on the edge of the Fleet box and skipper Stuart Hole curled the free-kick into the top corner of the net.
Caton cleared off the line early in the second half, but the hosts were on top and drew level when Jack White slotted home Carr's cross with 16 minutes remaining.
Both sides had chances, with the two goalkeepers each making good saves, but a draw was a fair result.
North Leigh: Bulman, Else, Hopkins (M Woodley 81), Hole, Gunn, Caton, A Woodley (Turk 75), McNish, Williams, Sanders, Osborne-Ricketts. Subs not used: Ingram, Bowles.
Attendance: 83.
- Do you want alerts delivered straight to your phone via our WhatsApp service? Text NEWS or SPORT or NEWS AND SPORT, depending on which services you want, and your full name to 07767 417704. Save our number into your phone's contacts as Oxford Mail WhatsApp and ensure you have WhatsApp installed.
Latest Sport news
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- Oxford United's new faces help take squad to higher level, says Michael Appleton
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- CRICKET: Oxfordshire Over 60s in last-over victory
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- MOTORSPORT: Nathan Harrison recovers from penalty to move top of the standings
- LACROSSE: Oxford City to hold taster session for all abilities


text:
About اهداف مبارة مصر واغند اليوم
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text:
Lyrics Depot is your source of lyrics to Nitro (youth energy) by Offspring. Please check back for more Offspring lyrics.
Nitro (youth energy) Lyrics
Artist: Offspring
Album: Smash
Our generation sees the world
Not the same as before
We might as well just throw it all
And live like there's no tomorrow
We are the ones
Who are living under the gun every day
You might be gone before you know
So live like there's no tomorrow
Ain't gonna waste this live
The official view of the world has changed
In a whole new way
Live fast cause if you don't take it
You'll never make it
So if you understand me
And if you feel the same
Then you will know what nitro means
You'll live like there's no tomorrow
Ain't gonna waste this live
There's no tomorrow
You ain't gonna live it for me
There's no tomorrow
Offspring Lyrics
Offspring Smash Lyrics
More Offspring Music Lyrics:
Offspring - Americana Lyrics
Offspring - Conspiracy Of One Lyrics
Offspring - Dammit, I Changed Again Lyrics
Offspring - Gone Away Lyrics
Offspring - Kristy, Are You Doing Okay? Lyrics
Offspring - Nothingtown Lyrics
Offspring - One Fine Day Lyrics
Offspring - Takes Me Nowhere Lyrics


text:
Mill Creek Newswire (Page 9)
Comprehensive Real-Time News Feed for Mill Creek, WA. (Page 9)
Results 161 - 180 of 412 in Mill Creek, WA
Legislation seeks changes to I-405 toll lanes w/Photo
... reconnecting to I-5 just north of Lynnwood. Bill sponsor Sen. Andy Hill, R-Redmond, and Rep. Mark Harmsworth, R-Mill Creek, who has a companion bill in the House, said Thursday thousands of constituents in their districts have complained of traffic ... Comment?
Phenix Salons moves to Bothell, gives individual stylists their own suite w/Photo
... 102 in the new Phenix location. Alburtus said she used to work at other salons, recently at a boutique salon in Mill Creek, but decided she wanted more control over her work. "I feel like this is a really good opportunity to kind of dip my toe into ... Comment?
Drivers tell lawmakers of their frustrations, satisfaction with I-405 w/Photo
... steer clear of ordering any significant changes. "I've not encountered any problems," said Duncan Milloy, of Mill Creek. "Paying a modest toll is well worth it to reduce my time on the road." Fourteen people testified to the committee on Senate Bill ... Comment?
Parents at school board meeting voice frustrations with use of isolation rooms w/Photo
... other methods have failed to de-escalate violent outbursts. The district shared a photo of the isolation room at Mill Creek Elementary, which adjoins the classroom and has a window to provide for supervision. But parents say it's not a safe space. ... Comment?
Front Porch: MLK Day events planned in Lynnwood w/Photo
... future forums should be emailed to Chuck Pratt at For more information, go to sno-isle.org/issues-that-matter . Mill Creek's new finance guru: The city has a found a finance director to replace Landy Manuel, who is retiring. Roundy, of Arlington, ... Comment?
Front Porch: Bothell-area road to be closed for 6 weeks w/Photo
Six-week closure of Bothell-area road The Snohomish County Public Works Department plans to shut down 14th Drive SE north of Highway 524 through Feb. 19. The full closure will allow crews to work on the North Creek Interceptor project , a sewer line that serves portions of Bothell, Mill Creek and unincorporated Snohomish County. Even emergency vehicles and school buses will not have access at all times. Comment?
Point in Time count needs volunteers to help homeless w/Photo
... housing. Of those, 81 people were in the South County area including Lynnwood, Mountlake Terrace, Edmonds and Mill Creek. Point in Time organizers have the biggest need for volunteers to go out into the streets throughout Lynnwood, Mountlake Terrace ... Comment?
Pruitt elected to third term as Mill Creek mayor w/Photo
... to help the council set a vision and stay out of the way while City Manager Rebecca Polizzotto carries it out. Mill Creek is among five Snohomish County cities that have a strong city manager or council-manager government. Generally, that means the ... Comment?
Linsenmayer led Wildcat wrestling program for 30 years w/Photo
Richard Linsenmayer, one of only four Washington high school Hall of Fame coaches from Oak Harbor, died Saturday, Dec. 26, in Mill Creek. He was 78. Linsenmayer, who coached at Oak Harbor from 1969-99, was named to the Washington State Wrestling Coaches Hall of Fame in 2002, compiling a 248-126-5 dual meet record during his career. Comment?
Redmond's Sen. Hill helps drive proposed bill focused on issues... w/Photo
... clear project leaders aren't going to take bold action needed to make this successful." Added Harmsworth of Mill Creek, who serves as assistant ranking member on the House Transportation Committee: "Our proposal is to ratchet back the failed system ... Comment?
Front Porch: I-405 toll rate corrections w/Photo
... bills with the wrong amount were sent out. New bills are being sent. If you have questions, call 866-936-8246. Mill Creek swears in new councilmen: The city has scheduled a ceremony at 6 p.m. Tuesday for newly and re-elected councilmen Vincent ... Comment?
2 arrested after brief police chase in Mill Creek w/Photo
A Mill Creek police officer checked the license plate of a new model Scion in a parking lot after noticing suspicious activity, according to a police department press release. The driver reportedly ignored the commands and ran a stop sign. Comment?
A Mill Creek median now easier to spot w/Photo
small island on 527 in Mill Creek just before Dumas Road going south. On dark rainy nights it is impossible to see it until you are about to turn into the turn lane to turn west on Dumas Road. If a reflector or two were put on the island, it would ... Comment?
Genealogy classes to be held at the Northshore Senior Center in Bothell w/Photo
Genealogy is a hobby for some people and fun for others. Northshore Senior Center and Mill Creek Senior Center are offering beginning and intermediate genealogy classes beginning in January. Comment?
Snohomish County Council decision could ignite political fire storm | Cornfield w/Photo
... two sides, ended with Hope winning by 118 votes. Republicans have held onto the seat with Rep. Mark Harmsworth of Mill Creek serving in it today. Toyer took on Dunshee in 2014 and lost, but not badly. He garnered 48.2 percent of the vote without ... Comment?
2 teens connected to fatal shooting charged as adults w/Photo
... reports of gunfire, but they didn't learn anyone had been hit until a car brought Camacho to Swedish Hospital in Mill Creek. His companions unloaded him from their car, placed him in a wheelchair, rolled him into the emergency room and then left. ... Comment?
New Loveland Pizza Joint Coming Soon w/Photo
... sauce that's packed right after the tomatoes are picked in California, said Kevin Woolley, vice president of the Mill Creek, Washington-based company. The other cool thing, they won approval for a beer and wine license. Owner, Kimberly Neeper said ... Comment?
Snohomish "Shop with a Cop" leaves no child blue w/Photo
... merger with the Sheriff's Office. Sgt. Cynthia Caterson started "Shop with a Cop" in Snohomish. She's now at the Mill Creek sheriff's precinct, but she still comes and participates. Pet food and medicine were also donated along with gift cards for ... Comment?
Legislation would change how new I-405 toll lanes are used w/Photo
Frustration with the new express lanes on I-405 spilled into the political arena Wednesday with two Republican lawmakers saying they want to reduce the number of toll lanes and let all drivers use them at night for free. State Rep. Mark Harmsworth, R-Mill Creek, and Sen. Andy Hill, R-Redmond, said complaints from constituents are fueling their effort to change the operation of toll lanes that opened on the 17-mile stretch between Bellevue and Lynnwood in September . Comment?
Too soon to cut I-405 express toll lanes w/Photo
... have reached area lawmakers; two have responded with a bill. The legislation, proposed by Rep. Mark Harmsworth, R-Mill Creek , and Sen. Andy Hill, R-Redmond, would cut the two express lanes going in each direction between Bothell and Bellevue to one ... Comment?
Copyright © 2016 Topix LLC


text:
The Fear Hole
Three scientists, their janitor, and the creatures that emerge from their dimensional vortex.
Clock Suckers
A group of slackers stumble across a time machine...
Based on everyday conversations between two friends.
For a second one.
Dude, for the second one you can just use all the ones that was on the first one, PLUS more, like more weapons, more wounds, more accesories, oh and maybe try to make a fireing gun or somthing.
cool man
that's all i have to say
this is so cool
the music whas the best
it was fun>>
but the skreen was to small for my PC
This has got to be the best madness dressup game ever and go Little Lucky Link :D


text:
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text:
Stanton's is thrilled to announce the 30th ANNIVERSARY CELEBRATION of The Joy of Singing – two full days… read moreJune 27th
recommended by Barb M., Keyboard and Folk Music Specialist Tablature for fretted string instruments was common in the… read more
Stanton's has built a reputation as "The Sheet Music Specialists".
Can't attend one of our clinics? Visit Stanton's Virtual Workshop.
In just a few minutes you can have your favorite song printed and ready to play.
Online Service for Music Educators.
Title: Holiday Plays (Bk/Cd)
Voicing/Format: Perfromance Pack
Publisher: Milliken Publishing, Llc
Composer: Kaplan/Becker
Catalog #: MC004
Description: Bk/Cd Price: $17.95


text:
Find a Local Pharmacy - Sioux City, IA
Find a local pharmacist nearby Sioux City, IA using the pharmacy map on RxList. The pharmacies listed may include chain pharmacies (CVS Pharmacy, Rite Aid Pharmacy, Walgreens, etc.), along with neighborhood pharmacies that offer prescription drugs, and over the counter (OTC) medications.
Pharmacies nearby Sioux City *
Siouxland Community Health Center Pharmacy
1021 Nebraska St
Sioux City, IA 51105
Thompson Dean Drugs
911 W 7th St
Sioux City, IA 51103
Hy-Vee Pharmacy #7070
2611 Pierce St
Sioux City, IA 51104
Saint Lukes Regional Medical Center Pharmacy
2720 Stone Park Blvd
Sioux City, IA 51104
Greenville Pharmacy
2705 Correctionville Rd
Sioux City, IA 51105
Hy-Vee Pharmacy #1610
2827 Hamilton Blvd
Sioux City, IA 51104
Shopko Pharmacy #40
3025 Hamilton Blvd
Sioux City, IA 51104
Hy-Vee Pharmacy #1615
3301 Gordon Dr
Sioux City, IA 51105
Value Medical Pharmacy
2442 Transit Ave Ste 100
Sioux City, IA 51106
Walgreens Pharmacy #10502
1030 W 21st St
South Sioux City, NE 68776
Walmart Pharmacy #1332
1601 Cornhusker Dr
South Sioux City, NE 68776
Continue Care Pharmacy
2609 Apache Ct
Sioux City, IA 51104
Walmart Pharmacy #3590
3101 Floyd Blvd
Sioux City, IA 51108
Hy-Vee Pharmacy #1620
2501 Cornhusker Dr
South Sioux City, NE 68776
Leeds Northside Pharmacy
2729 Outer Dr N
Sioux City, IA 51104
Drilling Morningside Pharmacy
4010 Morningside Ave
Sioux City, IA 51106
Walgreens Pharmacy #5470
4650 Morningside Ave
Sioux City, IA 51106
K Mart Pharmacy #4465
5700 Gordon Dr
Sioux City, IA 51106
CVS Pharmacy #16923
5775 Sunnybrook Dr
Sioux City, IA 51106
Hy-Vee Pharmacy #1614
4500 Sergeant Rd
Sioux City, IA 51106
Walmart Pharmacy #1361
3400 Singing Hills Blvd
Sioux City, IA 51106
Dunes Family Pharmacy
101 Tower Rd Ste 130
Dakota Dunes, SD 57049
Sergeant Bluff Pharmacy
110 Gaul Dr Ste A
Sergeant Bluff, IA 51054
Keller Pharmacy
119 E 3rd St
Ponca, NE 68770
Moville Pharmacy
216 Main St
Moville, IA 51039
USPHS Indian Hospital Pharmacy Inpatient
77 Highway 75
Winnebago, NE 68071
Walmart Pharmacy #1625
1111 Holton Dr
Le Mars, IA 51031
Pioneer Drug
107 E Main St
Elk Point, SD 57025
Hy-Vee Pharmacy #1382
1201 12th Ave SW
Le Mars, IA 51031
Lewis Family Drug #74
7 W 2nd St
Kingsley, IA 51028
Floyd Valley Hospital Pharmacy
714 Lincoln St NE
Le Mars, IA 51031
Thorson Drug
233 Reed St
Akron, IA 51001
Carl T Curtis Health Center Pharmacy
100 Indian Hills Dr
Macy, NE 68039
Mills Pharmacy
120 E Main St
Anthon, IA 51004
Whiting Family Pharmacy
723 Whittier St
Whiting, IA 51063
Remsen Pharmacy
111 S Washington St
Remsen, IA 51050
Sanford Vermillion Medical Center Pharmacy
20 S Plum St
Vermillion, SD 57069
Walmart Pharmacy #3734
1207 Princeton Ave
Vermillion, SD 57069
Davis Pharmacy
5 W Cherry St
Vermillion, SD 57069
Hy-Vee Pharmacy #1820
525 W Cherry St
Vermillion, SD 57069
Booth Drugs
903 Central Ave
Hawarden, IA 51023
Apothecary Shop
100 Valley View Dr Ste 102
Pender, NE 68047
Main Street Apothecary
201 E 2nd St
Laurel, NE 68745
Providence Medical Center Pharmacy
1200 Providence Rd
Wayne, NE 68787
Burgess Health Center Pharmacy
1600 Diamond St
Onawa, IA 51040
Shopko Pharmacy #670
615 Dearborn St
Wayne, NE 68787
Stangel Pharmacy
821 Iowa Ave
Onawa, IA 51040
Shopko Pharmacy #677
2220 Highway 175 West
Onawa, IA 51040
U Save Pharmacy
216 E 7th St
Wayne, NE 68787
Hy-Vee Clinic Pharmacy #3028
321 N Main St
Marcus, IA 51035
Open 24 Hours
Mercy Medical Center Pharmacy
801 5th St
Sioux City, IA 51101
Open 24 Hours
Walgreens Pharmacy #910
100 Pierce St
Sioux City, IA 51101
Featured Drug - Bactrim
What is sulfamethoxazole and trimethoprim (Bactrim, Bactrim DS, Septra, Septra DS, Sulfatrim Pediatric)?
Sulfamethoxazole and trimethoprim are both antibiotics that treat different types of infection caused by bacteria.
The combination of sulfamethoxazole and trimethoprim is used to treat ear infections, urinary tract infections, bronchitis, traveler's diarrhea, and Pneumocystis carinii pneumonia.
Sulfamethoxazole and trimethoprim may also be used for other purposes not listed in this medication guide.
What are the possible side effects of sulfamethoxazole and trimethoprim (Bactrim, Bactrim DS, Septra, Septra DS, Sulfatrim Pediatric)?
Get emergency medical help if you have any of these signs of an allergic reaction: hives; difficulty breathing; swelling of your face, lips, tongue, or throat.
Call your doctor at once if you have a serious side effect such as:
- fever, sore throat, and headache with a severe bli...
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*Generic names for drugs with multiple manufacturers who market these drugs under brand names. Source: IMS Health, Full Year 2008.See Previous Years
Need help identifying pills and medications?
Use the pill identifier tool on RxList.
Featured from the Pharmacist:Antidepressants
What are antidepressants and how do they work?
Antidepressants are a class of drugs that reduce symptoms of depressive disorders by correcting chemical imbalances of neurotransmitters in the brain. Chemical imbalances may be responsible for changes in mood and behavior.
Neurotransmitters are vital, as they are the communication link between nerve cells in the brain. Neurotransmitters reside within vesicles found in nerve cells, which are released by one nerve and taken up by other nerves. Neurotransmitters not taken up by other nerves are taken up by the same nerves that released them. This process is called "reuptake." The prevalent neurotransmitters in the brain specific to depression are serotonin, dopamine and norepinephrine (also called noradrenaline).
In general, antidepressants work by inhibiting the reuptake of specific neurotransmitters, hence increasing their levels around the nerves within the brain, such...Read the Antidepressants article »
Emergency Contact for Sioux City
- In case of Emergency, call 911
Nearby Sioux City Hospitals *
Mercy Medical Center Sioux City
801 5th St
Sioux City, IA 51101
St Luke's Regional Medical Ctr
2720 Stone Park Blvd
Sioux City, IA 51104
Siouxland Surgery Center
600 N Sioux Point Rd
Dakota Dunes, SD 57049
PHS Indian Hospital
75 Highway 77
Winnebago, NE 68071
Floyd Valley Hospital
714 Lincoln St NE
Le Mars, IA 51031
Sanford Vermillion Med Ctr
20 S Plum St
Vermillion, SD 57069
Pender Community Hospital
100 Hospital Dr
Pender, NE 68047
Hawarden Regional Healthcare
1111 11th St
Hawarden, IA 51023
Providence Medical Center
1200 Providence Rd
Wayne, NE 68787
*Provider Directory Terms of Use:
The WebMD 'Provider Directory' is provided by WebMD for use by the general public as a quick reference of information about Providers. The Provider Directory is not intended as a tool for verifying the credentials, qualifications, or abilities of any Provider contained therein. Inclusion in the Provider Directory does not imply recommendation or endorsement nor does omission in the Provider Directory imply WebMD disapproval.
You are prohibited from using, downloading, republishing, selling, duplicating, or "scraping" for commercial or any other purpose whatsoever, the Provider Directory or any of the data listings or other information contained therein, in whole or in part, in any medium whatsoever.
The Provider Directory is provided on an "AS-IS" basis. WebMD disclaims all warranties, either express or implied, including but not limited to the implied warranties of merchantability and fitness for particular purpose. Without limiting the foregoing, WebMD does not warrant or represent that the Provider Directory or any part thereof is accurate or complete. You assume full responsibility for the communications with any Provider you contact through the Provider Directory. WebMD shall in no event be liable to you or to anyone for any decision made or action taken by you in the reliance on information provided in the Provider Directory.
The use of WebMD Provider Directory by any entity or individual to verify the credentials of Providers is prohibited. The database of Provider information which drives WebMD Provider Directory does not contain sufficient information with which to verify Provider credentials under the standards of the Joint Commission on Accreditation of Healthcare Organizations (JCAHO), National Committee for Quality Assurance (NCQA) of the Utilization Review Accreditation Committee (URAC).
By using the WebMD Provider Directory, you agree to these Terms and Conditions.
Women's Health
Find out what women really need.


text:
Court strict on missing of childrenThe article below represents a preview only and is not meant for reuse or republishing. NEW DELHI, May 20 -- High court has expressed a deep concern over cases of missing children increasing with a fast pace in capital. High court has told that ... HT Syndication, 1 month ago
Missing children as bad as terrorism, says Delhi HC - ProKerala.com, 1 month ago
HC says missing children as bad as terrorism - The Gulf Today, 1 month ago
More from: NDTV, Siasat Daily...and 1 other sources
Court asked U.P. government to respond on compensation
NEW DELHI, May 20 -- High Court has asked Uttar Pradesh government to clarify in Hashimpura massacre matter that how much compensation has been paid up till now to the victimized families. High court has also asked Uttar Pradesh Legal Services ...HT Syndication, 1 month ago
Realtime News
on your WebpageAdd Widget >Get your members hooked!


text:
...With years of experience working with college chemistry and physics students, I specialize in tutoring the Physical Science section of the MCAT. Many of my clients have seen a significant improvement in their scores. My approach starts with a general review of high yield concepts and then progr...
New York, NYView Tutor
...As for teaching style, I feel that the concept drives the skill. If you have the idea of what to do on a problem, you do not need to complete 10 similar problems. As such, I like to spend more time on the why than the what.
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...With my MS degree, I had a concentration in biostatistics including: Biostats I - Observational Studies Biosttas II - Clinical Trials Categorical Data Analysis Survival Analysis Survey Sampling For my 10 classes (30 credits), I graduated with a 3.2/4.0 GPA. I had 2 semesters of linear algebra ...
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text:
Jumping on consumer trend for user-generated content and to coincide with the launch of Levi's customised range in Singapore, Levi's have developed a "confession booth" offering consumers the opportunity to create a short video clip on their camera phone or video camera and reveal their (or their mates') inner secrets, or alternatively listen and vote on other peoples.
A clever ploy, as participators are far more likely to act as brand ambassadors and drive WOM for the brand - featuring on a website seems irresistible for almost 300 people so far â€" but will it drive purchase:..?
Levi's Truth Booth
More Stats +/-
Sporty Promotional Cans
Fried Noodle Snacks
Gravity-Defying Street Art
Crowdsourced Political Platforms
Top 80 Wellness Trends in June


text:
How to Access Recycle Bin Folder on External Hard Drive and Delete Files
We use external hard drive normally to back up our data. Some users use it for storing media files. Some other people use it for expanding the storage. Whatever the case we use these USB drives to store lots of files.
External hard drives have also a recycle bin folder. The files you deleted on this drive may stored in this folder. You can access the recycle bin folder on external hard drives and delete the files.
If you have media files deleted from your external hard disk and connected to a TV via supporting DVD player, the file on the recycle bin folder may also playable on your TV. It may cause embarrassment sometimes. The solution is to completely remove the recycle bin stored files on your USB drive.
This Windows tip will provide you answer to your following queries;
How to Access Recycle Bin folder on External Hard Disk?
How to Delete Recycle Bin files on External Hard Disk?
How to Get Extra Storage Space on External Hard Disk?
Now to the point.
How to Access Recycle Bin folder on External Hard Disk on Windows 8
On the Start screen directly type "exp" to find and open "file explorer"
Under the "View" menu click options and open "change folder and search options"
Under "View" tab enable "show hidden files, folders, or drives"
Remove tick mark against "Hide protected operating system files"
You can now see the recycle bin folder when you open the external storage drive. Delete the files inside it.
This way you can access recycle bin, open recycle bin and delete recycle bin files.
Now on other Windows versions.
How to Access Recycle Bin folder on External Hard Disk on Windows 7
On Windows 7 (Home basic I am using) you can find the above same folder options from the following way.
Start > Windows Explorer > Organize >Folder and Search Options
Other steps as above.
How to Access Recycle Bin folder on External Hard Disk on Windows XP
You can locate the folder options on Windows XP as follows
Start > Control Panel > Appearance and Themes > Folder Options
Now you have to learn one more thing. If you don't want to send deleted files to recycle bin follow the below steps.
How to stop deleted files sending or moving to Recycle Bin folder
On your desktop, right click on recycle bin folder and select "properties"
Enable "Don't move files to recycle bin……"
That's all.
Remove recycle bin folder stored files on your external hard disk and get more storage space.
About Article Author
Prashanth KV
A technology enthusiast and addictive blogger who likes to travel and wish to mingle with different community of people from around the world.View more articles by author
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3 Comments
November 13, 06:07 preet
Thanks man, you saved me so much.. DUnno what i would have done if i hadnt read this article, stay blessed
November 14, 07:51 Prashanth KV Author
Welcome preet! u people r my motivation
September 14, 23:08 Himalaya
how can i recover the files from such recycle bin?


text:
Candyland Birthday - Printable Thank You Party Tags [Instant Download]
Product Info
This listing is for a printable PDF file for Thank You Party Tags from the Candyland Party Collection. Tag says "Thanks for being so SWEET".
You can print as many as you need and can cut into squares, or use a craft punch to create 2" scallop circles or 2" regular circles. Attach it to ribbon and tie on party favors, stick onto favor boxes, gift bags, drop into lunchbox for surprise note, hand out to classmates, and reuse again and again.
Please note that no items will be shipped.
***This is an instant download, you can download it as soon as you buy it.***
To open the PDF file, you will need Adobe Reader, which is a free download at adobe.com.
You may use this file for your personal use only. You may not forward, share, sell or distribute the file. It is for non-commercial use only. Sweet Metel Moments retains all rights.
Thanks for visiting my shop!
To learn more about Sweet Metel Moments:
Blog: www.sweetmetelmoments.blogspot.com
Email: sweetmetelmoments [at] gmail [dot] com


text:
The weather at Riverbend last night may have been as nice as I have ever seen. The music was pretty darn good, too. I got to hear the A Z One band and that started off the night with an A+ grade. Robert Randolph and his Family Band played to a huge crowd at the Bud Light stage, which seemed to enjoy their music more than they enjoyed the band's timekeeping skills. (They started late)
Up the hill at the Unum stage, Rusty Wright gained a whole slew of new fans, with his smokin' hot guitar and great blues songs. Look for him tomorrow at the Strut. His stage manager Bob Willie said it ranked in his top 10 acts of all-time at the Unum Stage. Hayes Taylor, stage manager at the Bessie Smith Strut said it was also one he was looking forward to seeing. Clare Dunn provided the guitar lessons next to another great crowd.
50 years after the Beatles invasion of the USA, the WannaBeatles invaded the Unum Stage to as many fans as I have seen up there in many years. They played 4 billion Beatles hits and the crowd loved every minute. Note to promoters and festivals – book this band if you want a happy, big crowd.
Buddy Guy was – well, he was Buddy Guy. He is just special and he also drew one of the largest Sunday night crowds in many years. All in all, it was a beautiful evening.
On tap for tonight – The Bessie Smith Strut on MLK Blvd.
You may know her as Prince's guitar player – yes, that guitar player, but Andy Allo is a whole lot more than a killer guitar player and pretty face in Prince's band. Her album "Superconductor" was produced by Prince and features Trombone Shorty and other guest musicians. Andy Allo appears on the Bessie Smith Hall Stage at 7 p.m.
Prior to Andy Allo taking the stage, Blues and Soul artist Nikki Hill begins at 5:30 p.m. After seeing and hearing Nikki Hill, I am betting that most folks will say, "Where did she come from and where has she been?"
The great Bobby Rush, one of the Blues genre's greatest names, appears on the Bessie Smith Hall Stage at 8:35 p.m. With over 50 years in the blues world, Bobby Rush may be the biggest name to have never made the top ten lists of blues players by many accounts.
On the Trestle Stage down the MLK Blvd. just a bit, Big James & The Chicago Playboys begin at 5:15 and the Rusty Wright Band comes on at 6:45 p.m. Following Rusty Wright, Boukou Groove takes the stage at 8:15 p.m.
If you didn't pre-buy your admission to the Strut, you can buy at the gate for $10, or $7 with a Riverbend wristband.
Riverbend's Artist of the Day is Big James & the Chicago Playboys, playing the Lindsey Street Hall at 1 p.m.
Star seats still remain for Justin Moore, Joan Jett & the Blackhearts, and Young the Giant. Buy them at the main gate when you enter the festival for $20 each in addition to your general admission wristband. I sure will have them for Saturday night, as the Star Seats give a great view of Chattanooga's best fireworks display, including the spectacular Market Street Bridge waterfall extravaganza.
See you there!
Bob Payne grew up in Chattanooga and graduated from Baylor School. He is the Entertainment Editor for the Chattanoogan.com and assistant talent buyer for Friends Of The Festival.
Email Bob Payne at firstname.lastname@example.com or www.facebook.com/davrik2000.
June 28, 2016
The Signal Mountain Playhouse will present Ian Fleming's classic "Chitty Chitty Bang Bang" on July 8, 9, 15, 16, 22, 23, 29 and 30 at the Playhouse amphitheater. Curtain is at 8 p.m. but the ... (click for more)
Being one of the biggest names in pop music, Justin Bieber is no stranger to everything that comes along with the fame – the sold-out arena crowds of screaming fans, the popstar style choices, ... (click for more)
Nikki Lane will be headlining this Friday at Nightfall, the free concert series produced by Chattanooga Presents at Miller Plaza. Her twangy, nostalgic spin on country music will be preceded ... (click for more)
The Signal Mountain Playhouse will present Ian Fleming's classic "Chitty Chitty Bang Bang" on July 8, 9, 15, 16, 22, 23, 29 and 30 at the Playhouse amphitheater. Curtain is at 8 p.m. but the box office opens at 6 p.m. for those who wish to buy tickets and place lawn chairs early. Tickets are sold only at the door; there are no advanced ticket sales. Tickets – cash or checks only ... (click for more)
Being one of the biggest names in pop music, Justin Bieber is no stranger to everything that comes along with the fame – the sold-out arena crowds of screaming fans, the popstar style choices, the pressures of being judged, the list goes on. Most reviews of his shows on this tour haven't been so positive, with the main argument being that he seems to simply ... (click for more)
County Commission members have given up the fight for the annual $900,000 in discretionary funds. Commission Chairman Chester Bankston said there was not enough money available after requests from a number of agencies and departments were cut to balance the budget without a tax increase. Commissioner Sabrena Smedley said the fact that commissioners can no longer allot the ... (click for more)
While investigating a pothole in the bridge on U.S. 27 North over 12 th Street in the construction zone, crews discovered a potential weak spot in the bridge deck that could over time result in more damage to the bridge deck. For the safety of the traveling public, the outside lane in this area will be closed until the contractor makes necessary repairs, TDOT officials ... (click for more)
So, am I the first to notice a trend? How many wrecks does exit 11 need before anyone asks "whats up with that?" I have lost count of the wrecks that continue to happen, even after last year's awful loss of life (which I believe 51 percent of the blame should fall on the THP officer on duty). The problem with this section of interstate are sight lines ... (click for more)
In a puzzling time when the big daily newspapers have veered strongly away from "all the news that is fit to print," allow me to share a story that you very likely will not see on CNN, ABC News, or in the big media conglomerates that influence the way you think, the way you react and – as a result – easily warp our common senses. This story is very true. Late last Sunday afternoon, ... (click for more)


text:
bathurst basin bristol
Credit: Graham Bell
Creative #: 160495451
License type: Rights-managedRights-managed products are licensed with restrictions on usage, such as limitations on size, placement, duration of use and geographic distribution. You will be asked to submit information concerning your intended use of the product, which will determine the scope of usage rights granted.
Collection: Britain On View
Max file size: 5,100 x 3,311 px (17.00 x 11.04 in) - 300 dpi - 9.86 MB
Release info: No release required
Similar imagesSearch ResultsSame series
Bathurst Basin Bristol Stock PhotoArchitecture,Bristol - England,Building Exterior,Color Image,Day,England,History,Horizontal,Medium Group of Objects,Nautical Vessel,No People,Outdoors,Photography,Quayside,Reflection,Rippled,Tranquility,Travel Destinations,UK,WaterfrontPhotographer Graham BellCollection: Britain On View graham bellbathurs basin part of brunels floating harbour, bristol


text:
List all words starting with persimmons
Only the word persimmons was found, nothing longer.
Some random words: eager mugs ivermectin scena fou llama jiff
This is not a dictionary, it's a word game wordfinder.
- Help and FAQ - Examples - Home
Privacy and Cookies Policy - Share - © Copyright 2004-2016 Morewords.com - 4.912mS


text:
Starting from July 6, 2016, Tea Room, Gift Shop and Museum in the London Farmhouse will open every Wednesday to Sunday from 12 to 5 pm.
August 28, 2016 is the last day of Summer Hours in Tea Room, Gift Shop and Museum at the Farmhouse.
Call to Volunteers. Please contact Mary Lou for details of work.


text:
Eagle River Dog Training
1. Home Away From Home Inc. K9 Daycare & Boarding
16444 Brooks LoopEagle River, AK 99577
2. Chugach Kennel
Eagle River, AK 99577
3. Penn Foster
I have two maltase dogs males they use to get along but now all they want to do is fight I believe its jealousey @ need help don't no what to do nex…
4. Canine Psychological Consulting
P.O. Box 872560Wasilla, AK 99687
5. 907Bluepitbullz.com
po box 231101Anchorage, AK 99502
6. Pawsitively Loved
Wasilla, AK 99654
From Business: At Pawsitively Loved our mission is to help as many people as we can, so that their fur-kids can live longer, healthier and happier lives with them! We know that yo…
7. Empowered Animals, LLC
P.O. Box 593Palmer, AK 99645
8. Bratslavsky Tanya & Roman
Anchorage, AK 99501
9. Obedience Training Club Inc
18606 Old Glenn HwyChugiak, AK 99567
10. PetSmart
Bad Experience: An employee said I could have a discount on an item unwrapped that was the last one. When I went to check out the cashier got the…
11. Anchorage Dog Walkers
They are awesome! My dog Gunnar is a large friendly dog who needed to learn to walk on a leash in order to make walking him fun and easy for me. T…
12. Anchorage Dog Walkers
2011 Pembroke StAnchorage, AK 99504
13. Dingo Design Pet Sitting
From Business: Iprovideacompletein-home,familyexperienceforyourpet.Your pet will havealltheluxury available to them that they get at their very own home. Pets have always been my …
14. Canine Connection
15. Alaska K9 Aquatics
549 W Intl Airport RdAnchorage, AK 99518
From Business: ,
16. Alyeska Canine Trainers
549 W Intl Airport RdAnchorage, AK 99518
17. K-9 Training Service
15300 Old Seward HwyAnchorage, AK 99516
18. Coshok's Canine Castle
The people who volunteer at coshoks keep this place going ! Yes the building is older than time itself be needs updates but there is a lot behind th…
19. The Better Companion
1400 E Regine AveWasilla, AK 99654
From Business: ,
20. VCA Big Lake Animal Hospital
7362 W Parks Hwy Ste 793Wasilla, AK 99623
21. First Line K9 Alaska
2005 Casey Cusack LoopAnchorage, AK 99515
Showing1-21 of 21results


text:
quick linksCURRENT ISSUE PREVIOUS ISSUES NEWS INDUSTRY NEWS COLUMNISTS BROWSE EDITORIAL TOPICS WEBINARS
resourcesABOUT MT AUTHOR GUIDELINES CLASSIFIEDS EDITORIAL CALENDAR MEDIA GUIDE MASSAGE MART SCHOOLS & EDUCATION FEEDBACK
Insuring Quality Control in Herb Importation: An Interview with Wilson Lau
Wilson Lau is the vice president of Nuherbs, a Chinese herb importation company based in San Leandro, California. Before joining Nuherbs, he trained as a lawyer specializing in FDA law.
Sit or Stand? Analyzing a Mixed Message
I'm more than a bit confused. At my age, that seems to be a rather common occurrence. However, today more than ever, I'm getting a mixed message.
An MD Who Understands the Opioid Epidemic
Doctors of chiropractic have an important role to play in ending the opioid epidemic and dealing with chronic pain by conservative means (see our top story in this issue) – but who's to blame for opioid dependence and abuse in the first place?
Acupuncture Muscle Trigger Point and Oriental Medicine Sports Therapy
It is difficult to ascertain the internal condition of professional basketball player Lebron James during game one of the 2014 NBA finals, in which he developed debilitating muscle cramps that led to his premature removal from the game.
Drive-Through Disease
Believe it or not, an estimated one-third of your patients have eaten some form of fast food within 24 hours of their appointment with you.
An Emerging Partnership Model
Maryland University of Integrative Health (MUIH) has educated integrative health and wellness practitioners for the last 40 years, originally as an acupuncture clinic and school. The institution's transformative, relationship-centered programs integrate traditional wisdom with contemporary science
The Pertinent Negative
We all have to perform evaluations on patients. Most of us don't like doing it – exams take time, and worse it takes even more time after the evaluation to put together a narrative summary of the findings. Sometimes, this process becomes downright tedious.
Introducing the Acupuncture Today Digital Edition
In response to the changing habits of our readers, Acupuncture Today will introduce a digital edition of the publication (in addition to our print edition) beginning with the August 2016 issue.
Increasing the Value of Spine Care: CMS Approves New Low Back Pain Registry
The Centers for Medicare and Medicaid Services has approved the Spine IQ Low Back Pain Registry as a qualified clinical data registry for the Physician Quality Reporting System (PQRS) in 2016.
AOM Hospital-Based Practice: A Future Reality?
The natural evolution of health care on the planet is integrative health. We may have some challenges ahead, but based on my research, all indicators are pointing in a positive direction. There seems to be an evolving consciousness among our patient population that is "getting it."
Acupuncture's Impact on the World
For several years, I have been hearing about the town of Rothenburg, Germany. It seemed just a dot on a map until I arrived. It is the home of the TCM Kongress which began in 1968. It has been held annually for 47 years and it has only missed one year.
What's New in Phytonutrition: Mangifera Indica, "The King of Fruits"
One hundred percent pure Indian green mango fruit (mangifera indica), harvested at a special degree of ripeness for efficacy and taste, can now be concentrated as a phytonutrient nutraceutical powder.
Beating the Odds: Interview With Para-Powerlifter Adeline Dumapong-Ancheta
Since October 2015, the FICS Foundation, the charitable organization affiliated with the International Federation of Sports Chiropractic (FICS), has been supporting disabled athletes internationally.
Adventures with the San Jiao
Those of us who have been in practice for several decades relish the way meridians and points reveal new diagnostic clues and new insights. I love to encourage my students to see this as an adventure that goes way beyond the textbooks.
A Long-Overdue Win for Oregon Medicaid Patients - and the Implications for Other States
Beginning July 1, 2016, Oregon Medicaid patients with spinal pain (cervical, thoracic, lumbar, pelvic) who are determined to be low risk based on a biopsychosocial assessment tool (STarT Back – Keele University) can receive four chiropractic visits per episode.
What You Say Isn't Always What Patients Hear
A few years ago, my aunt Edna (name changed for the purpose of this story) suffered a stroke. After a short hospital stay, she was transferred to a nursing home for rehabilitation. When she arrived at the nursing home, Edna requested a private room.
How to Stay Sane During the Elections: Understanding Through the Lens of Chinese Medicine
In Chinese Medicine philosophy, everything consists of Yin and Yang. The law of polar opposites – one cannot exist without its opposite.
Kansas Achieves Licensing Law
Kansas Governor Sam Brownback signed House Bill 2615 into law on Friday, May 13, 2016. HB2615 includes provisions for the licensure of acupuncturists in the state of Kansas.
Treating Hip & Groin Pain With Abdominal Release of Upper Lumbar Nerve Impingements
Have you encountered patients with groin and hip pain you can't seem to solve? You know it's not a worn-out hip; you suspect the pain is somehow connected to the spine. But somehow, you just can't help them break through.
Multivitamin Supplement May Reduce Breast Cancer Recurrence
There is a great deal of controversy regarding the value of multiple vitamin supplements in cancer prevention.
Chronic Pain: Become Part of the Solution
I have lectured to more than 7,000 chiropractic physicians over the past five years regarding the chronic pain and opioid epidemic in this country.
Three Tips to Help You Analyze the Acupuncture Case Studies of the NCCAOM Exam
Tip #1
Confirm the answer quickly by the elimination method. Case study:
After two treatments for back pain, a patient presents for a third
session complaining of rapid breathing and wheezing that is made worse
during cold weather.
Tai Chi Documentary Premier
First Run Features recently announced the world theatrical premiere of Barry Strugatz's documentary The Professor: Tai Chi's Journey West, which premiered last month at the Laemmle Music Hall in Los Angeles.
February, 2011, Vol. 11, Issue 02
Squatting: Integrating Fitness In Your Practice
By Ben Benjamin, PhD and Chris White
Editor's Note: Dr. Benjamin continues his series on integrating fitness in your practice with this article, co-authored by Chris White.
The squat is one of seven fundamental movement patterns that were essential to human survival in primitive times.The other six are: lunging, bending, rotating, pushing, pulling, and walking/running. The quality with which an individual executed each movement dictated their physical capacity and ability to survive. Even today, all of the movements we do are a combination of these seven fundamental movements.
The origins of squatting date back to the beginning of time. It was one of the movements most essential to everyday life. Basically, anything that took place on the ground was usually done from a squat position. Based on the idea that form follows function, it's easy to see why many people have lost the ability to squat effectively. The changes brought about by chairs, cars, and computers, to name a few, have turned a squatting society into a sitting society.
Squatting serves many important functions for humans. It was commonly used 10,000 years ago because many daily activities took place on the ground. There weren't any chairs (man-made at least), so squatting allowed a person to sit comfortably and still have use of their hands for tool making, food preparation, and cooking.
The squat position also kept a person rooted on their feet, ready to stand up, move, jump or run at a moment's notice. The mechanical properties of the squat also served a role in the toileting habits of primitive man; when a person is squatting, the right thigh compressing the ascending colon, which literally pushes waste material up and through the transverse colon. From here it can more easily move out of the body.
Many undeveloped and developing countries around the world still use the squat for everyday activities. No matter what country you're in, you might notice that infants and young children are quite good at squatting. It's only when we stop squatting that we lose our ability to do so.
Learning to Squat
When done correctly, squatting is a very comfortable position to be in. At the bottom of the squat, the trunk is allowed to rest comfortably on the legs. This decompresses the lumbar spine and decreases the load on the extensor muscles of the back. At the same time, the posterior thigh is allowed to rest against the back of the lower leg, minimizing tension throughout the quadriceps.
Many Americans need to get back into the habit of squatting in order to strengthen their thighs and buttock muscles. Squatting may also prevent some digestive problems that lead to straining during bowel movements, hemorrhoids and other issues. Women may find the squatting position to be a comfortable stretch during pregnancy, and they may find it useful during delivery as well.
There are many wrong ways to do squats, so you have to teach your clients the right way to do them. Otherwise, they may strain their neck or back, or, particularly, their knees. When most people begin learning how to squat, their knees roll inward, placing enormous stress on the medial knee.
Start by making sure you can do a squat properly, and then use this knowledge to teach your clients to do the same.
See a video on the proper squat: www.youtube.com/watch?v=efiSjiedJAw
Click here for more information about Ben Benjamin, PhD.
Chris White is co-founder of Go Primal Fitness and the Functional Training Institute. With more than 13 years experience in massage therapy, strength training and nutritional coaching, his clients include those with severe spinal injuries and Olympic level athletes.
Join the conversation
Comments are encouraged, but you must follow our User Agreementcomments powered by Disqus
Keep it civil and stay on topic. No profanity, vulgar, racist or hateful comments or personal attacks. Anyone who chooses to exercise poor judgement will be blocked. By posting your comment, you agree to allow MPA Media the right to republish your name and comment in additional MPA Media publications without any notification or payment.


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PC Games
Game Questions & Answers (Q&A) service lets you ask questions about video games for game consoles or PC games. So ask your Deus Ex: Human Revolution question for PC and get answers from real gamers or answer questions and share your insights and experience with the rest of the gaming community.
Boxshot & Details
- Developer: Eidos Montreal
- Publisher: Square Enix
- Genre: Action Adventure
- Release: Aug 23, 2011
- ESRB: Mature
Stuck in this game? Set a specific, clearly defined question and let other gamers answer your question or view answers to previously asked questions. If you think you are an expert then please try to help others with their questions.
Providing made up info to anyone looking for some help.
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|Thread Tools
Join Date: Jul 2004
Posts: 17,075
Location: Minneapolis
Collection Count: Too many to count
News Credits: 3
Ok, I know this is old and it's not my idea. [However,] I've figured out how to make him, and people always seem to want instructions. I hope this . . . helps somebody.
Here's the original pic (not mine):
You will need (all Energon Terrorcons):
No modding or gluing is needed (apart from flattening the peg on Insecticon's drill so it can fit into Ravage's launcher on the weapon assembly). Everything pegs together or is held on with friction.
Start with the body:
Make the chest piece:
Combine the two. [The] bird legs go around Insecticon's torso, [and] Ravage's rear legs fold up and hold under Insecticon's armpits ([it] takes a bit of fiddling; it will be solid if you get it right):
Right arm (reverse for left) - peg on [the] Energon bit [that] goes into hole on Insectcon's arm assembly:
Left leg (reverse for right) - Peg on [the] Energon wing [that] goes into hole on Ravage, and Ravage's paw goes into space in [the] dino head:
Back view of assembled combiner:
Hopefully from the pics, you will be able to figure out how it all goes together. I will answer any questions if you want to make this and need pointers.
The only real issues I've found with it are the knee joints. They hold and he can stand, but you need to careful picking him up, because the legs tend to fall off/come unclipped. I've considered doing a bit of modding to make them more secure.
Everything else is very solid with mindful handling.
Need custom parts? Click here.
Last edited by Superquad7; 10-09-2009 at 03:46 AM..
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text:
Aberlour weather map
- Recent locations
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Forecast summary
Regional forecast for Grampian
Wednesday starting dry but becoming cloudier with rain or showers.
This Evening and Tonight:
A mostly cloudy evening with showers most frequent over Moray and western Aberdeenshire, perhaps the odd rumble of thunder. The showers will become more isolated overnight with some clear intervals developing. Winds becoming light. Minimum Temperature 8 °C.
A dry morning with bright or sunny spells. Cloud increase during the afternoon with showers developing, some heavy. Again the odd rumble of thunder possible especially in Moray. Maximum Temperature 17 °C.
Outlook for Thursday to Saturday:
A mostly bright few days with a mixture of sunny spells and occasional showers, some heavy with the chance of thunder, especially on Friday afternoon. Temperatures close to average.
Updated at: 1556 on Tue 28 Jun 2016
UK forecast for the next 5 days
Rain pushing eastwards for many, sunshine and showers in Scotland.
A bright start in the east, but already wet and windy in the west and this will spread eastwards through the day. Brighter in some central and western areas later, whilst sunshine and heavy showers persist in Scotland.
Winds easing as rain clears to the east, leaving a mostly dry and clear night across the UK. Some places seeing the odd shower, particularly in western Scotland by dawn.
A drier day for many although the odd outbreak of rain in the west and further heavy showers in Scotland. Sunny spells for most, best of the brightness further east.
Outlook for Friday to Sunday:
Cool and breezy with sunshine and showers, turning heavy in the northwest but lengthy, dry and bright spells in the south. Cloudy with further rain in the south on Sunday.
Updated at: 0214 on Wed 29 Jun 2016
Outlook for the UK over the next 6-30 days
UK Outlook for Sunday 3 Jul 2016 to Tuesday 12 Jul 2016:
Remaining changeable and often unsettled for most through this period, with bands of rain expected to push across much of the country, interspersed with sunshine and showers. The wettest weather is always more likely in the north and west where it will occasionally be windy too, whilst the south and east will see the best of any drier and brighter spells along with generally lighter winds. Temperatures on the whole are expected to be near, or slightly below average for the time of year, but feeling cool more generally in the northwest in any wetter and winder spells. Conversely, it will feel warm in any drier and sunnier periods, especially in the south and east.
Updated at: 1255 on Tue 28 Jun 2016
UK Outlook for Wednesday 13 Jul 2016 to Wednesday 27 Jul 2016:
Changeable conditions are likely to persist at first, with rain or showers across many areas, particularly the north or northwest, and temperatures near average. From around the middle of July there is the possibility that a generally more settled spells of weather may develop, potentially bringing longer dry periods to much of the country. With this change there would be more in the way of sunshine with generally warm temperatures and lighter winds. However there is also the possibility of more humid continental air moving up across the southeast at times, bringing very warm temperatures and a risk of some thundery showers here.
Updated at: 1255 on Tue 28 Jun 2016
Location Details
Location: 57.4751, -3.2155
Altitude: 84.0 m above mean sea level