text:
|Número de publicación
|Tipo de publicación
|Fecha de publicación
|16 Ago 1960
|Fecha de presentación
|28 Feb 1957
|Número de publicación
|Walter A. Goldtrap
|Exportar cita
|BiBTeX, EndNote, RefMan
|Citas de patentes (9), Citada por (21), Clasificaciones (19)
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet
Aug. 16, 1960 H. M. HAwKlNs ETAL 2,949,447
PROCESSING OP POLYMER MADE 1N SLURRY PROCESS 2 Sheets-Sheet 1 Filed Feb. 28, 1957 N mm oF Aug. 16, 1960 H. M. HAwKlNs ET AL 2,949,447
PROCESSING OE POLYMER MADE IN SLURRY PROCESS 2 Sheets-Shea?. 2
Filed Feb. 28. 1957 MJOM/Ow OF N 596mm ok w INVENTORS H M HAwKlNs W.A. GOLDTRAP BY A TTOR/VEVS NmEOZOE limited States Patent PROCESSING OF PLYMER MADE IN SLURRY PRGCESS Harold M. Hawkins and Walter A. Goldtrap, Bartlesville, Okla., assignors to Phillips Petroleum Company, a corporation of Delaware Filed Feb. 28, 19'57, Ser. No. 643,041
18 Claims. (Cl. 2611-935) This invention relates to solid polyolefns. ln one of its aspects, this invention relates to separation of solid polymers of l-oleiins from polymerization diluent.
kIt has recently been discovered that l-oleiins having a maximum of 8 carbon atoms per molecule and no branching nearer the double bond than the 4-position can be polymerized to solid and semi-solid polymers at loW temperatures and pressures as compared with conventional processes for polymerizing these olens. Such polymerization is generally carried out by rst admixing and at least partially dissolving the olens in a non-polymerizable solvent and carrying out the polymerization in the presence of a catalyst.
In the copending application of l. P. Hogan and R. L. Banks, Serial No. 573,877, tiled March 26, 1956, now Patent 2,825,721, a process is described for producing novel polymers of l-oleins by carrying out the polymerization at a temperature in the range of 100 to 500 F. in theV presence of 0.1 to 10 or more weight percent of chromium as the oxide, including a substantial proportion of hexavalent chromium, usually associated withV at least one porous oxide selected from the group consisting of silica, alumina, zirconia, and thoria. A preferred catalyst is one comprising 0.1 to 10 Weight percent chromium as the oxide on a silica-alumina support such as 90 percent silica-10 percent alumina. This catalyst is ordinarily a highly `oxidized catalyst which has been` activated by hih-temperature treatment under non-reducing conditions and preferably with an oxidizing gas. The polymerization is suitably carried out in the liquid phase such as in solution in a hydrocarbon solvent, especially a parafln or cycloparaiin which is liquid under the polymerization conditions. Also, dioletins can be polymerized by the chromium oxide catalyst to produce solid polymers. The copending application of G. T. Leatherman and C. V. Detter, Serial No. 590,567, led .lune l1, 1956, discloses and claims an improvement in the Hogan and Banks method in that it discloses the polymerization of ethylene or copolymerization of ethylene with another l-oleiin at a temperature below the precipitation temperature of the polymer being formed and in the presence of a poor solvent for the polymer. By such operation, the polymer is formed as discrete particles of high rnolecular weight polymer containing the catalyst. The yield of polymer per pound of catalyst is exceedingly high with this method. In the copending application ofV R. A. Findlay, Serial No. 591,864, filed June 18, 1956, a method is disclosed for precipitating polymer formed by the Hogan et al. method in the solvent which cornprises cooling the solution by evaporation of a portion of the solvent, e.g., auto-refrigeration.
The method of the instant invention is applicable to recovering solid polymer from hydrocarbon diluents broadly and is especially suitable for recovery of solid polymer from hydrocarbon slurries as formed by the Leatherman et al. method and the Findlay method. However, the method is also suitable for recovery of polymer 2,949,447 Patented Aug. 16, 1960 from slurry no matter how prepared. The polymer prepared with chromium oxide catalyst is particularly useful in preparation of moldings, ilm, and many other uses Where a high molecular weight, high softening point article which also has excellent low temperature properties is desired. However, solid olefin polymers prepared by other systems can also be advantageously treated by the process of this invention, for example, those polymers prepared by organometallic catalyst such as those disclosed by Karl Ziegler in Belgian Patent 533,362, November 16, 1954, now Patent No. 2,897,967.
ln any case, to recover solid polymers lfrom diluent, it has been the practice to flash part of the diluent and to centrifuge, lter, etc., to remove additional diluent after which the Wet polymer had to be dried. The subsequent drying steps requires a large volume of heated gas which in turn has to be separated from diluent vapor.
It is an object of this invention to provide an improved method of recovering polymer from diluent.
Itis a furtherY object of this invention to reduce the cost of drying a solid polymer.
lt is' still another object of this invention to provide a continuous method of obtaining solid polymers of l-olens in substantially dry form by recovery of the polymer from the polymerization process.
Still other objects, features and advantages of this invention will be obvious to those skilled in the art having been given this disclosure.
According to this invention, diluent is ilashed from a slurry of polymer in a hydrocarbon diluent leaving polymer in a iiuid bed and a portion of the vaporized diluent is recycled to the fluid bed to maintain the polymer in fluid suspension and to further dry the polymer. polymer is continuously removed from the bed through a solids transfer means and any remaining diluent removed by means of an inert gas.
As has been indicated, the polymeric materials to which this invention is particularly applicable are polymers of l-olens. These polymers can be homopolymers or copolymers and we particularly prefer those polymers prepared from l-olens of 2 to 8 carbon atoms per molecule comprising a major proportion of ethylene or propylene and particularly comprising at least 9() Weight percent of one of those l-oleiins since such polymers when precipitated are solid non-agglutinative particles. Polymers of i-oleiins containing 2 to 8 carbon atoms and having no branching nearer the doublebond than the 4-position have been found in recent years to have superior heat resistance and superior low temperature properties when polymerized at relatively low temperatures and pressures. The `above-identified method of Hogan et al. is one such low temperature-low pressure method. Polymers of ethylene or propylene are particularly useful and copolymers of these materials with each other or in major proportion with other l-olefins of the type indicated have also been found to have many commercial uses such as for ejection molding, film, and the like.
Examples of the preferred l-oletins whose polymers can be dried by the method of this invention include ethylene, propylene, 1-butene, l-pentene, l-hexene, l-octene, 4- methyl-l-pentene, 4-methy1-1-hexene, 4-ethyl-1-hexene, 6-methyl-1-heptene, S-methyl-l-heptene and the like as Well as copolymers of these l-olefns.
The diluents especially useful in polymerization of the l-olens by the method of Hogan et al. are hydrocarbons and preferably parailins including cycloparaiiins. These diluents include parains and cycloparaiins having 3 to 12 carbon atoms per molecule. Any of the parafins or oycloparafns which are a solvent for the monomers at. the temperature in the polymerization range are suitable. While paraiiins and cycloparatlins are preferred, any hy- The drocarbon which is relatively inert, non-deleterious, and liquid under the operating conditions of the polymerization process can be utilized. Diluents that have been used successfully in the polymerization reaction and are operable in this invention include propane, isobutane, normal pentane, isopentane, isooctane (2,2,4-trimethylpentane), cyclohexane iand methylcyclohexane. Using the organometal catalyst, it is generally preferred to use aromatic hydrocarbon diluents such yas benzene and'naphthalene, however, any of the hydrocarbons whichare relatively inert, non-deleterious, and liquid under the operating conditions of the polymerization can be used.
That is, any of the hydrocarbons as listed in the preferred groups can be used in eitherprocess while unsaturated aliphatic and cyclic hydrocarbons are, in general, not used in the polymerization zone since they are likely to enter the polymerization reaction. However, any of these hydrocarbons can be removed from polymer by the method of this invention.-
In the practice of this invention the polymer is prepared either as discrete particles during polymerization or polymer is precipitated in the solvent by cooling such as by heat exchange, additional cold solvent,V autocooling, eg., evaporation, or the like. The slurry is passed to a zone of low pressure causingsolvent` to ash leaving polymer particles which fall to a low level in the zone vforming a bed of polymer. A portion of the ashed solvent is cycled back to this zone and passes through the polymer bed fluidizing same and further drying the poly-V mer. The polymer is withdrawn and any remaining solvent is removed by passing an inert gas therethrough.
As has been indicated, the polymer slurny is prepared by polymerizing the polymer at atemperature wherein the polymer is formed las discrete particles. Such a method is fully described and claimed by Leatherman and Detter, supra. According to that case, ethylene or mixtures of same with other unsaturated hydrocarbons are contacted wit-h a suspension of a chromium-oxide containing catalyst in a liquid hydrocarbon selected from the group consisting of paral'linic hydrocarbons and naphtlienic hydrocarbons. When the hydrocarbon is a paraftinic hydrocarbon the contacting is generally in the range of 230 F. and below and when the hydrocarbon is a naphthenic hydrocarbon the contacting is generally 190 F. or below. On the other hand, when polymeriz ing in solution, the polymerization temperature is maintained at a level suiicient to prevent precipitation. of the polymer. For example, ethylene can be polymerized in cyclohexane in the presence of 0.25 weight percent catalyst consisting of 2.5 weight percent chromium oxide on a 90-10 silica-alumina support, 285 F. and 450 p.s.i., said catalyst having been activated ait 950 F. for four hours.
In a preferred method of operation, the polymer slurry is passed through a pair of sequentially operated pressure let-down valves to the ash zone. The slurry enters the flash zone through a spray nozzle` and most of the solvent is immediately flashed, however, due `to the flashing of solvent, the material is cooled considerably and a portion of the solvent remains as a wet lm on the polymer. The polymer falls onto a lluidized bed and a portion of the solvent isvsuper heated and recycled to the bottom of the i bed to act as the uidiz-ing medium and to essentially dry the polymer. The polymer is continuously removed through a standpipe as a relatively quiescent column. This polymer will be associated with solvent vapors which are removed by sweeping the vapors out by means' of an inert gas such as Warm air. It will be obvious to those skilled in the art that the polymer in solution can be flashed to precipitate polymer and remove solvent. However, this method is not preferred's'ince suchfiiashing will generally cause the polymer' to precipitate las lineV string adfnotvcompact grains as is generally preferred. vSuch strings are not readily tluidized and are more diicult to dry and handle than are the grainy polymer particles.
This invention will be'further described by referring to the accompanying drawings which are:
Figure 1 is a schematic flow diagram of the method of this invention wherein the polymer is formed as discrete particles in the polymerization zone, and
Figure 2 is a schematic flow diagram of an embodiment of this invention wherein the polymer is formed ih solution and auto-cooling is employed to precipitate the polymer.
Referring now to the drawing, catalyst, monomer and diluent are fed to reactor 1 viay conduit-s 2, 3 `and 4 respectively wherein the monomer is polymerized as discrete polymer particles incorporating the catalyst. This reactor 1 is generally provided with some agitation means such as stirrer 5 and since the polymerization reaction is exothermic, the reactor is generally jacketed or contains cooling coils, not shown. The slurry. of polymer in diluent as formed in reactor-1 passes via conduit 6, sequential pressure let-down valves Tand conduit 8 to flash nozzle 9A in flash tank 10 wherein the pressure s suiciently low to ash most of the diluent which passes overhead via conduit 11. This dash solvent will entrain a portion of the polymer. This flashed diluent containing some entrained polymer passes via conduit 1-1 to separator 12 wherein the polymer is removed and is returned via conduit 13 to the ash zone 10; Most of the polymer wet with diluent from nozzle 9 fallsl to fluidized polymer bed 14 in vessel 10 where it is maintained in fluidized state and is supported by grid 23 in the bottom of vessel 10. The..
diluent from separator 12 passes overhead via conduit 15 yand a pontion passed via conduit 46 -to solvent recovery, not shown, -and recycled to the reactor 1. The remaining portion of the diluent stream in conduit 15 is passed via conduit 47, blower 18, conduit 19, heat exchanger 20 and conduit 21 to nozzle Z2. Conduit S3 is provided to add hot diluent -as drying agent if desired which supplements or supplants recycled diluent. The diluent heatedv in exchanger 20 is sprayed into vessel 10 below grid 23 by means of nozzle 22. These heated diluent vapors pass upward through polymer bed 14vuidizing same and further drying the polymer.
A portion of the uidized polymer continuously falls into standpipe 16 and is removed therefrom by -auger 17 driven by motor 54 to final dryer 48. A warm inert gas, such as nitrogen, CO2, or even air, from conduit 49 continuously passes through dryer 48 sweeping out diluent vapors and is expelled via conduit 50 to solvent recovery unit, not shown. This dryer isv equipped with a screw conveyor 56 driven by motor 55. The temperature of the inert gas can vary over a wide range up to the softening temperature of the polymer. Generally the temperatureof this gas will be at least 100 F., however, by
using large volumes, a temperature below the boiling point of the diluent can be used. Air can be employed, however, it is not ordinarily employed since it could form an explosive mixture with thel diluent andl also because of the possibility of oxidation of the polymer. The dry polymer is continuously removed via conduit 51 and passed to further processing as desired.
In the case of solution polymerization the modication of Figure 2 is useful. Catalyst, monomer and solvent are added to reactor 22 via conduits 23, 24 and 25 respectively. This reactor 22 is similar to reactor 1 containing a heat removing means, not shown, and a stirrer 26. This reactor operates at a higher temperature than ydoes reactor 1, eg., a temperature above the precipitation temperature of the polymer. The eifluent polymer solution from reactor 22 passes via conduit 27 tovessel 28 Ywherein the pressure is` lowered somewhat flashing unreacted monomer which is recycled to the reactor via conduitl 29. The solution, free of monomer, thenvpasses "via conduit 30 to catalyst removal zone 31 wherein the catalyst solids are removed from solution by any suitable means such as a centrifuge or ltration. The catalyst is withdrawn va conduit 32. The solution then passes via conduit 33 to cooling zone 34 wherein the `solution is cooled to below the precipi-tation temperature of the polymer by auto-refrigeration due to solvent evaporation and/or by indirect heat exchange. The solvent passes overhead via conduit 35 to compressor 36 and is recycled to the reactor via conduit 37. The resulting slurry in Zone 3ft is pumped via conduit 38 and pump 52 into ash zone 10. The treatment from this point on is the same as shown in Figure 1.
Specz'jc embodiment To further illustrate the operation of our invention, processes will be described for producing solid polyethylene both in the srurry process and in the solution process. The catalyst used in both processes is a microspherical catalyst consisting of 2.5 percent chromium as the oxide on a 90:10 silicazalumina support. This catalyst is activated at 950 F. in dry air for 4 hours.
In the process of Figure 1, pentane, ethylene and catalyst are fed to reactor 1 at a rate to provide a polymer slurry consisting of 25 weight percent polymer and 0.07 weight percent catalyst. This reactor operates at 210 F. and 500 p.s.i.a. The polymer so formed is in the form of discrete, nonagglutinative particles. The 25 percent polymer (containing catalyst) .slurry passes through valves 7 to ash zone 10 wherein the pressure is 100 p.S.i.a. and the temperature is 200 F. Most of the solvent will flash at this pressure and temperature and the solids fall to fluidized bed 14 with the exception of a small amount of polymer which is entrained in the flashing solvent. The solvent vapors along with entrained polymer pass to separator 12` wherein polymer is removed and passed to the fluidized bed via conduit 13. The solvent vapors then pass overhead via conduit 15 and a portion sent to solvent recovery and recycled via conduit 46. A portion of the vapor is passed via conduit 47, blower 18, and conduit 19 to heat exchanger 20 wherein the vapors are heated to 220 F. and are passed to the bottom of the tluidized bed as a uidizing and drying gas. The polymer is removed from zone 14 via standpipe 16 and auger 17. This auger 17 acts as a transfer means and pressure let-down means. The polymer passes to dryer 4S which operates at atmospheric pressure and has warm nitrogen (200 F.) sweeping therethrough. The dry polymer is removed via conduit 51.
In the case of solution polymerization the ethylene, catalyst and solvent, eg., cyclohexane are passed to reactor 22 in proportion to provide an 8 percent polymer solution and 0.25 percent catalyst slurry. The reactor operates at 285 F. and 450 p.s.i.a. The polymer solution, about 8 percent polymer in cyclohexane, along with the catalyst passes to monomer flash zone 28 wherein the pressure is reduced to 100 p.s.i.a. thereby flashing monomer via conduit 29. The solution and catalyst along with additional solvent provided by means of conduit 60 in an amount to provide for a 4 percent polymer solution then pass to catalyst removal zone 31 wherein catalyst is recoved by ltration. This solution then passes to zone 34 wherein the temperature is lowered to 120 F. This cooling can be eiected by auto-cooling, i.e., evaporation of solvent, by indirect heat exchange or by a combination of the two. The resulting slurry then passes via conduit 38 and pump 52 to flash zone 10 which operates at 170 F. and p.s.i.a. In this embodiment wherein the polymer is formed in cyclohexane solution it is generally preferred to use a light hydrocarbon diluent as the vaporizing solvent in zone 10. This material is introduced via conduit 53 and is heated to 190 F. in zone 20. However, it is within the scope of this invention to recycle cyclohexane if desired. Where a second diluent is used, a
separation zone will be employed in conduit 46 and the two solvents recycled in their respective streams.
In still another embodiment, the polymer is precipitated and recovered by filtration. The polymer, lter cake, is then introduced into zone 10 above the uidized bed by means of an auger and an inert diluent such as pentane is introduced via conduit 53v as uidizing and drying means. The ash zone in this case can operate at any desired pressure to obtain the most eicient drying, generally super-atmospheric.
This invention has been described in some of its preferred embodiments. 'I'hose skilled in the art will see many modifications which can be made while still obtaining the advantages of the invention.
We claim:
1. A method for recovering dry polymer of a l-olen of 2 to 8 carbon atoms from a slurry of polymer in a hydrocarbon diluent which comprises ashing diluent from polymer at an upper level in a ash zone, gravitatiug polymer to a fluidized bed of such polymer at a low level in said flash zone, heating additional said hydrocarbon diluent and introducing same in vapor state to said fluidized bed as the fluidizing medium and continuously withdrawing dry polymer from said bed.
2. A method for recovering dry polymer of a l-oleiin of 2 to 8 carbon atoms from a slurry of said polymer in a hydrocarbon diluent at relatively high pressure which comprises passing said slurry to an elevated position in a flash zone at reduced pressure thereby ashing said diluent, gravitating said polymer from said elevated position to a uidized bed of such polymer at a relatively low position in said flash zone, withdrawing ashed diluent from said ash zone, heating a portion of said withdrawn diluent, passing the heated diluent as vapor to said iiuidized bed of polymer as the fluidiz- -ing medium thereby further drying said polymer, withdrawing polymer from said uidized bed and passing an inert gas over said withdrawn polymer.
3. The process of claim 2 wherein the l-olelin polymer is prepared by polymerizing l-oleins comprising at least 50 weight percent of a l-oleiin selected from the group consisting of ethylene and propylene.
4. A process for preparing l-oleiin polymer which comprises forming polymers of l-oleiins of 2 to 8 carbon atoms per molecule and having no branching nearer the double bond than the Ar-position as a slurry in a hydrocarbon diluent at a relatively high pressure, passing said slurry to an elevated position in a zone of relatively low pressure thereby hashing said diluent, gravitating polymer from `said elevated position to a iiuid bed of polymer in the lower portion of said zone of relatively low pressure, withdrawing flashed diluent 'from said zone of relatively low pressure, heating a portion of said withdrawn flashed diluent to a temperature below the softening point of said polymer, passing this heated solvent in vapor phase to said uidized bed `as the uidizing medium, withdrawing polymer from said uidized bed associated with diluent vapor, and sweeping the last said diluent from polymer with an inert gas.
5. A process for preparing l-olen polymers which comprises polymerizing l-oleiin monomers of 2 to 8 carbon atoms per molecule and no branching nearer the double bond than the 4-position at a temperature below the solubility temperature of the polymer being formed and at an elevated pressure in the presence of a hydrocarbon diluent which is liquid at the operating pressure, passing the resulting `slurry to a zone of relatively low pressure thereby flashing diluent from polymer, maintaining the polymer h-aving solvent flashed therefrom in a iluidized bed, withdrawing ashed 4diluent from said zone of relatively low pressure, heating a portion of the withdrawn diluent, passing the heated diluent in vapor phase to said fluidized bed as the uidizing medium, withdrawing polymer from said fluidized bed and sweeping diluent from withdrawn polymer with an inert gas.
` .6. The process of claim wherein the l-olen coin-V pr'ises'"'at least90weight`percent ethylener ,7. vTheprocess ofclaim* whertiin the polymerization f is 'carried 'out in tliepresence of a'rchromim'oxide catalyst andthe diluent is 'selectedfrom the group consisting of Parfnsiand cycloparafrnsbfa toiearbfonatoms. 'Y
8. Theprocess ofclim 7 wherein the'hydrocarbon diluent is a parain.
'9."The process of claim 7` wherein the hydrocarbon diluent is normal pentane.'
10. A process 'for preparing 1-olen polymers which comprises polymerizing l-olen monomers of2'to 8 carbon atoms 'perl molecule and no branching nearer the doublebond than the 4-p0sitio`n at a temperatureA above the solubility temperature of the polymer: being formed and at an elevate-d pressure in the presence of" a hydrocarbon solvent jfor said polymerand which isl liquid under the polymerization pressure and temperature, cooling the resulting solution to atemperature below the `precipitation temperature of said polymer so as to form a polymer slurry, passing the resulting slurry to la zone of relatively low pressure thereby flashing diluent from polymer, "pass,- ing theY polymer from said flashing to a bed of uidized polymer, withdrawing ila-shed solvent from said flashing and heating a portion thereof to providesufiicientheat to maintain the desired temperature inthe flashing zone, passing the t-hus heated `solvent in vapor phase to said'i'uidized bed as fluidizing medium, passing a portion of said polymer `from said uidized bedto a relatively quiescent zone, withdrawing polymer associated with vaporous solvent from saidquiescent zone via la pressure iet-down means, andseparating polymer from said vaporous solvent by means of an inert gas.
11. The process of claim 8 wherein the said 1-oleiin monomers are polymerized in the presence of a chromium oxide catalyst and the hydrocarbon solvent is selected` from the group' consisting of parafns and cycloparaflins of 3 to 12 carbon atoms per molecule.
12. The process of claimV 11 wherein the hydrocarbon solvent is a cyeloparan.
53 13. The proce-ss of claim 12 wherein the hydrocarbon solventfis cyclohexane.y 'i 14: Tle processor-'claim 13 'wherein the 1`olen :monomers -comprise atleast weight 'percent of a 1*-olen ene.`
15. The process of claim 13 wherein the 1-olen monomers comprise at least weight percent ethylene.
16; The process of claim 13 wherein thevl le-oleinA monomers comprise at least 90 Weight percent propylene.
17. A method Afor recovering dry polymer of a l-olen of 2 to 8 carbon atoms from a slurry of polymer in a hydrocarbon' diluent, which comprises ashing diluent from polymer in a' ash zone, maintaining the polymer having diluent flashed therefrom in a fluidized bed, heating. additionalsaid hydrocarbon diluent and introducing same in vapor state to said fluidized bed as the fluidizing medium, and continuously withdrawing dry polymer from said bed.l v
18. A method for recovering dry polymer of a l-olen of 2 to 8 carbon atoms yfrom a slurry of polymer in a liquid diluent which comprises flashing diluent from polymer in :a ash zone, maintaining the polymer having diluent 'ashed therefrom in a iluidized bed, heating additional said liquid diluent and introducing same in vapor state to said luidized bed as the iluidized medium, and continuouslywithdrawing'dry polymer from said bed.
References Cited in the le of this patent UNITED STATES PATENTS 2,187,877 Ferris et al Jan. 23, 1940 2,431,455 Blanding Nov. 25, 1947 2,537,130 Green Jan. 9, 1951 2,565,960 Garber et al Aug. 28, 1951 2,626,856 Alles Jan. 27, 1953 2,635,684 l Joscelyne Apr. 21, 1953 2,756,188 Kaulakis July 24, 1956 2,780,587 Watkins Feb. 5, 1957 2,858,902 come Nov. 4, 1958
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"To me, the relationships formed in this community are a symbol of the relationship between God and humanity. They are the tactile representations of the spiritual and the way I can understand God's love for me."
- a Franciscan Community Volunteer
During their 11 months of post-grad, long-term service the Franciscan Community Volunteers are invited to:
- enter into a process of companionship with the poor, including practicing simplicity, in the Spirit of Saints Francis and Clare
- work closely with the poor and marginalized, dedicated to serving and advocating on their behalf
- share in community living supported by prayer, reflection and discussion on the Gospel
The FCV program is a member of
Catholic Volunteer Network
& Franciscan Service Network
Serving in the spirit of Saints Francis and Clare of Assisi, Franciscan Community Volunteers (FCV) is a ministry of the Franciscan Sisters of Little Falls, Minnesota. Volunteers are not expected to be Catholic, though the program is rooted in the Catholic Franciscan tradition and volunteers are asked to have an openness to participating in this environment.
To learn more about the Franciscan Sisters of Little Falls, MN, visit www.fslf.org

subset: commoncrawl


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Income Tax TreatiesPosted on March 9 2010 by admin
The United States has entered into income tax treaties over fifty countries. Treaties serve to bolster trade and foreign investment. On certain types of income, treaties will reduce the rate of withholding tax that would have been applied to payments between taxpayers of two countries.
Absent a treaty, the US will generally impose a 30 percent withholding tax on items of U.S.-source fixed or determinable annual or periodical gains, profits, and income that are not effectively connected with the conduct of a U.S. trade or business, and paid to a non US person. Fortunately treaties will reduce the rate from 30% to 15%, 10%, 5%, and in certain cases zero withholding will be applied.
For example, the US and Canada recently updated their income tax treaty and reduced the withholding rate on interest payments between both related and unrelated taxpayers to zero.
Whilst the treaty provide for such reductions, the US payers must obtain certain signed document from the foreign person before allowing for a reduction of withholding in an amount less than 30%. Without such support in place at time of payment, the IRS could impose the shortfall in withholding on the US payer. Such forms include but are not limited to:
When filing the US return or US nonresident return, be sure to include Form 8833 to disclose to the IRS the treaty position that you have taken. The IRS website has much more detailed information should you like to learn more about the US treaties that exist. The above information is only general in nature and should not be relied upon for withholding or filing positions.
By Debra Callicutt, CPA
There is nothing more complex than the world of taxes. We know this and yet we chose careers where we face these issues everyday. We get questions day in and day out about new tax laws, forms and news items and how they affect everyday people and businesses. Well, here at Henry & Horne we have set out to do what we do best; help everyday people understand what is going on in the world of state, local, federal, estate and international taxation. We will provide these weekly posts and we encourage you to give us feedback on those posts as well as letting us know what else you would like to know more about. Welcome to "Tax Insights." We hope you find this blog informative and worthy of your time.
Before posting a comment on a blog post please be aware that we do not give free tax advice to non-clients by email, comment response, or phone. Thank you!
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- 180Promote
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Hydrangeas and Butterflies - Such A Perfect Summer Dayby Paula Belle Flores
Collect your choice of gallery quality Giclée, or fine art prints custom trimmed by hand in a variety of sizes with a white border for framing.
Such A Perfect Summer Day - Pink Hydrangeas and Butterflies
hydrangea, pink, green, pattern...
Your patterns are lovely, Paula!
Thank you, dear Micklyn! I'm a newby on seamless patterns so it is really hard for me! :)
Your comment is so good for my soul. xoxo
Your comment is so good for my soul. xoxo
just gorgeous ~ you are so talented! xxx
yummy..go paula!
And you're too sweet, Sharon-the Queen of Seamless Patterns!!!! ♥
Thank you, Garima! I needed your encouragement because, as I said before, seamless patterns are new to me and every beginning is hard! ♥♥
So kind of you Jacqueline and Katy!!!!! ♥♥♥ Your comments are more appreciated then ever! I need encouragements! XXXX
funny i just saw some lovely hydrangeas in a local garden -very pretty paula
Thank you, lovely cat! xxx
very nice!
Beautiful Belle!
GORGEOUS!!! wow
Thank you so much, Nick, Moni, Ben! I'm really happy you like this design! ♥
gorgeous Paula!
Paula this is lovely! Wouldn't mind having this as a wallpaper in my home :)
Looks very William Morris!! Beautifully done!
Beautiful flowers and butterflies!!! :)
Very delicate and delightful, love it!
I love this
awesome pattern, keep it up :D ♥
Love Hydro's! very pretty :)
really pretty illustration!
thank you so much, everyone! this pattern was a real success for me! people say that it's not easy to get an "A" but it's so much harder to keep it! so I have a hard way ahead! lot of work! :) but I certainly enjoy it!
love it!!
Really beautiful!
Great work
See More Comments


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Looks lighter paper so I flew the wind blows and it's own weight! Outstanding functionality to absorb 10 times more water than is proud sponge wipes.
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Disinfectants in the boiling water, nor wash washing machine seem's OK. Not use bleach during production.
Please dispose of end to burning trash.
Also buried in the soil is understood 100% and will be returning to Earth.
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Hot storyFirst Post and I figured I'd write about a quicky.
My friend is chronically late. He's gay and I have no interest in him what so ever and he knows I have a penchant for ending up with a cock in my mouth eventually if he gives me enough time to do so. So I'm waiting for him for lunch at a mall and decide that I have to pee. Being from Hawaii there aren't a lot of places to cruise that don't involve hiding under some brush somewhere on a beach. Hot, yes. Practical, fuck no. So I walked into the bathroom and see a skinny teenager at the urinal looking around like he finished peeing ten minutes ago. I bypass him and take a piss in the stall. My cruising senses were tingling so I strolled out and parked up at the urinal next to his. Taking out my dick I nod at him and start stroking it. I'm 26 and Azn and hwp if you need to know. He looks over at my dick and nods. I walk over to him and start stroking his teenage cock through his fly. It's thick and six inches. He looked like a mixture of polynesian and filipino. Some family walked in and we immediately stopped and tried to look like we were peeing. They left and we went back at it. I wanted that thick cock in my mouth so we moved to the handicap stall. My friend texted me that he had arrived and I told him that I was cruising in the bathroom. I went down on him while he sat there moaning, legs in the air to look like the stall was empty. He started stroking me while i sucked him. He kept pumping in and out of my mouth harder and harder until with one gasp he shoved my head down and shot a load deep in my mouth.


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Sheriff's deputies say 43-year-old Vincent C. Wright, a former master sergeant in the United States Air Force, was killed late Sunday night when he tried to break up an argument at his sister's home.
Lawmen say the argument started between his sister's boyfriend, Jamal Wilson, and his brother over $20 dollars.
Officials say when Vincent tried to break it up, he was fatally stabbed by Wilson, who is now charged with murder.


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Featured stories about Belarusian
Stories about Belarusian
10 October 2015
Belarus Catches Up to Russia With Its Own Pro-government 'Troll Factory'
Leaked emails published on ElectBy suggest pro-government Belarusian Republican Youth Union directs its local chapters to leave negative comments on articles about recent opposition rallies.
5 October 2015
Belarusians Protest Against Russian Military Bases Inside Their Borders
With a 500-strong rally in the capital Minsk and more action on social media, Belarusians spoke out against the planned Russian military aviation base on Belarusian soil.
21 September 2015
New Mobile App Helps Belarusians to Keep an Eye on Violations in Presidential Election
The creators of "Vochy" hope the mobile app helps broaden Belarusian citizens' knowledge of their voter rights and provides an opportunity to quickly report election violations to independent observers.
22 September 2012
Belarus: Early Voting Boosts Turnout Amid Calls to Boycott Elections
The parliamentary election in Belarus is to take place on Sunday, Sep. 23, but the early voting has already begun, and the turnout may end up being high, despite calls...
23 June 2012
Belarus: Views From the Ground
Below is a selection of some "views from the ground" - recent posts by Belarusian bloggers about the situation in the country and what it is like for ordinary people...
11 April 2011
19 December 2010
Belarus: Presidential Election Day Ends in Protests and Crackdown
December 19, the 2010 presidential election day in Belarus, ended in mass protests, arrests and violent clashes with the riot police in Minsk, the capital of Belarus. Below is a...
4 September 2010
28 August 2010
16 June 2010
9 September 2009
29 July 2009
Belarus, Russia: Bloggers React to Graphic Chechen War Video
On July 3, Belarusian blogger Tatsiana Elavaya posted a provocative video showing the assassination of captive Russian soldiers by Chechen guerrillas during the 1999 war in Chechnya. The video had...
3 July 2009
Belarus: President Pardons Emanuel Zeltser
On June 30, a U.S. Congress delegation visited Minsk to meet with Belarusian president Alexander Lukashenko. During this meeting, members of the U.S. delegation asked the president to pardon Emanuel...


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Patrol Division
The police department has four platoons of uniformed officers who provide 24 hour continuous patrol. This is the largest and most visible section of the police department. These officers are responsible for the following: first response to calls for service, field reporting, police patrol, vacation checks, business check, traffic enforcement, and accident investigation. These uniformed officers work 12 hour shifts providing general law enforcement services for the City of Bridgeton.
Traffic Enforcement
a) Radar Speed Trailers
These portable trailers are set up in various parts of the city. The display shows the speed of approaching vehicle serving as a reminder for motorist to watch their speed.
b) Red Light Camera/Photo Enforcement
Automated enforcement commonly referred to as photo enforcement or red light cameras. The system works by capturing digital images and video of a vehicle violating a traffic signal. The images show the light being red, the vehicle in the intersection, the license plate of the vehicle and an image of the driver. A police officer reviews all of the evidence and determines if a violation occurred. If approved by the officer, the registered owner of the vehicle is sent a violation notice by mail.
For more information on photo enforcement, please contact the Bridgeton Police Department at 314-739-7557
Ordinance Enforcement
A full time police officer is assigned as the Ordinance Enforcement Officer. This Officer actively addresses quality of life issues such as abandoned vehicles and unsightly premises.
Ordinance Officer Contact 314-739-7557
Animal Control
A full time animal control employee works for the police department patrolling our neighborhoods for animal related issues.
The city also requires pet owners to license obtain a license for their animals. The animal control employee maintains these licenses along with holding an annual rabies clinic.
Animal Control Contact 314-739-7557


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Small form pluggable low voltage optical transceivers.
The ABCU-57xxxxZ family offers full-duplex throughput of 1000 Mbps by transporting data over shielded and unshielded twisted pair category 5 cable with 5-level PAM (Pulse Amplitude Modulation) signals.
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The AFCT-5765Z family targets applications requiring DMI features, and the AFCT-5760Z family is streamlined for those applications where DMI features are not needed.
Broaden or Narrow Your Search
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MM Corporation
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MM Corporation is a new company that will provide high quality writing services to it's clients. MM Corporation began operations on January 15, 2005. MM Corporation is a partnership, owned and operated by Md. Moshiur Rahman and Mrs. Morsalina Rahman.
Md. Moshiur Rahman and Mrs. Morsalina Rahman both have left their respective jobs in order to specialize in providing article writing services to small, medium sized and giant businesses with the fullest professionalism.
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Rewrite article into 4000 word report - Healthy and Bright Eyes
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text:
Technical Note: A new discrete ordinate first-order rotational Raman scattering radiative transfer model-implementation and first results
Atmospheric Chemistry and Physics (2011)
- DOI: 10.5194/acp-11-10471-2011
Readership Statistics
10 Readers on Mendeley
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text:
Poolmaster Pro Rebounder Poolside Basketball GameItem #MTW136
VIP:$120.59 Get This Price
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Product Description:
Poolmaster® Pro Rebounder Poolside Basketball Game :: When you're tired of dunking your friends in the pool, why not dunk basketballs instead? The above ground Pro Rebounder Poolside Basketball Game is a great way to cool off and have fun this summer. Set it up poolside and fill the base with water or sand to keep it upright. The sturdy base only needs 18"x21" of deck space for support. Comes with all-weather hard-body backboard, durable 14 PVC hoop, hand-woven polyethylene net, pro game ball and inflating needle. 25-1/2"Hx34"W.
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Nov. 25, 2006
Final Stats | UT-Martin Postgame Audio | SIU Postgame Audio | Photo Gallery
By Jeff Honza
CARBONDALE, Ill. - Nick Hill threw a game-winning 45-yard touchdown pass in the final minute of the game and Arkee Whitlock rushed for 207 yards and four touchdowns to lead No. 10 Southern Illinois University (9-3) to a 36-30 come-from-behind victory over No. 12 Tennessee-Martin (9-3) earlier today in the first round of the NCAA Division I Football Championship.
SIU trailed by 20 points early in the third quarter, but rallied behind Whitlock's three second half TDs.
"I can tell you this, I've been down 21, I've been down 28, and as long as the kids don't see you quit as a coach, they don't see you panic," said Saluki head coach Jerry Kill. "I thought the coaches did a great job of keeping their composure.
"We are a young team and we almost fell apart a couple of times, but we kept fighting and never gave up."
Whitlock's 1-yard run gave the Salukis their first lead at 28-27 with 9:42 left in the game.
Taylor Brown's 34-yard field goal regained a 30-28 advantage for the Skyhawks, but the Salukis ended all UTM playoff hopes on their last drive of the game.
SIU took over on downs at its own 20-yard line with 2:39 remaining and marched 80 yards in eight plays behind its first-year starting quarterback.
Hill, who transferred to SIU in 2005 after playing basketball at Western Kentucky, lofted a pass over the head of UTM defender Dante Harrold.
Turner adjusted to make the catch, as the ball was held up in a gusty wind out of the south. He then dashed down the sidelines for the winning score. Braden Jones' two-point conversion followed.
UTM had one chance at the end, but Derrick Belton intercepted a Greg Preston pass on a second-and-six at the Skyhawks' 29-yard line.
UTM had SIU on the ropes in the first half, but failed to deliver the knock-out punch.
The Skyhawks scored two touchdowns in the opening six-and-a-half minutes of the game.
UTM is primarily a running team, but Preston caught SIU off-guard when he threw a big 51-yard completion to Jesse Burton on the Skyhawks' first play from scrimmage.
Two plays later, Don Chapman scored from a yard out to give UTM a 7-0 lead.
Jack Greenwood picked off a Hill pass on SIU's next possession, and returned it for a 51-yard touchdown. Just like that, the Salukis were down, 14-0, with 8:34 left to play in the first quarter.
SIU started to chip away at the lead when Whitlock scored from a yard out, but with the help of a Saluki personal foul, UTM was able to capitalize the next time it had the ball.
The Salukis were whistled for a late hit on a third-and-three. After the 15-yard penalty gave UTM an automatic first down at the Saluki 43-yard line, Preston threw a 28-yard completion to Burton.
Four plays after that, Preston threw a 4-yard touchdown pass to Justin Glover to give UTM a 21-7 halftime lead.
UTM went 80 yards in seven plays on the first drive of the second half. Chapman's 13-yard run capped the march, which put the Skyhawks ahead, 27-7, at the 12:04 mark of the third quarter.
However, the Skyhawks blew the lead and saw their first-ever postseason appearance come to an abrupt end when they were outscored 29-3 the rest of the way.
Whitlock's four rushing TDs tied a career-high, as he posted his third 200-yard game this season. He also became SIU's all-time single-season leader in points scored (150 pts.), surpassing Muhammad Abdulqaadir's 128 points in 2002.
Whitlock has rushed for a total of 775 yards and 14 touchdowns in his last four games alone.
"Arkee's the best player in the country. Not the best running back, the best player," said Kill. "He's unbelievable and I've never seen anything like it in my life. It's fun to watch him."
Hill completed 8-of-14 passes for 129 yards and the game-winning touchdown. He also ran for 19 yards on nine carries.
"Nick never loses his composure," said Whitlock. "He makes mistakes, but can recuperate. He bends, but doesn't break."
Defensively, SIU was led by Patrick Jordan and Trevor Moe, who each finished with 10 tackles. The Saluki defense also had two big sacks, an interception and a fumble recovery.
SIU advanced to the quarterfinals, where it will hit the road to face Montana on Saturday, Dec. 2. Game time is to be announced.
The Salukis (four-straight) and Grizzlies (14-straight) own the nation's top-two longest playoff streaks in I-AA football.
Game Notes: SIU overcame a deficit of 20 or more points to win a game for the first time since it fell behind, 20-0, against Northern Iowa on Oct. 2, 2004...the Salukis rallied to beat the Panthers, 40-36, at McAndrew Stadium that year...the Salukis registered their fifth playoff win in five postseason appearances...both Ohio Valley Conference schools (UT-Martin, Eastern Illinois) lost to Gateway opponents today, dropping the league to a 0-12 mark in postseason play since 1996...SIU trailed an opponent for the first time since losing its lead in the fourth quarter at Youngstown State on Nov. 4...what a week it's been for Whitlock, who was named Gateway Conference Offensive Player-of-the-Week, invited to the Hula Bowl, and rushed for 207 yards and four TDs against a UT-Martin defense that entered the game, allowing under 14 points a game.


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Read Checkpoints Online (members only) Join Now!
The March 2016 issue of Checkpoints features the Academy's mascot. Also read about mysterious microbial communities and more! Checkpoints Online has bonus articles beyond the printed magazine.
Checkpoints Online - March 2016
Bonus Content
- Additional Articles:
- Lorenz retires from top USAFA Endowment post;
- USAFA Gymnastics celebrates 60 years of excellence;
- Maj. Gen. Jackie Van Ovost '88, vice director of the Joint Staff, tours USAFA and speaks at awards event.
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Panch phoron
Recipes / Panch phoron (76)
Bengal Red Lentils With Spices
596 views
or possibly light vegetable oil, 1 Tbsp. Panch phoron mix (equal quantities of cumin seed
Bengali Panch Phoron
329 views
Bengali Panch Phoron, ingredients: 1 Tbsp. Cumin seeds, 1 Tbsp. Fennel seeds, 1
Almost bengali tomato chutney...
26 views
1. Heat the oil and add the panch phoron and wait till the mixture crackles. 2
Bengali Mixed Vegetable Medley
65 views
Ingredients 6 tablespoons oil 1 teaspoon panch phoron (Bengali 5-spice mix) 1 tablespoon
WHB#209 : Chaltar Ambol (Sweet & Sour Elephant Apple)
96 views
accrd. to your taste) Dry red chilli : 1 Panch Phoron : 2 tsp.(is a mixture of cumin seed
Recipe for Rajasthani Panchmel Dal / Panch Kuti Dal for Tata I-Shakti T20 Tadka
13 views
traditional panch phoron - a mix of five spices, used in Bengali cooking. The panch phoron
Super Low Fat Dal #1
322 views
Tempering oil 1 – 4 T ghee 4 t panch phoron, whole (i.e., not ground) 6 whole dried red
Panch Phoron Tarkari & Kulath ki Dal
30 views
chopped cilantro. Panch Phoron Tharkari (Mixed Vegetable Curry with Panch Phoron): This
Panch Phoron Roasted Potatoes
48 views
1½ teaspoons salt 2-3 tablespoons panch phoron (see below) Panch Phoron (Indian Five Spice
Pineapple Kheema (Indian Ground Beef Curry) with Kale and Panch Phoron
32 views
Panch Phoron Recipe type: Entree Cuisine: Indian 1-2 T vegetable oil 2 t whole spice panch
Trusted Results with Panch phoron
Potato Curry with Tamarind Recipe at Epicurious.com
3/4 teaspoon panch phoron (Bengali spice mix) 1/8 teaspoon asafetida powder. 1/2 teaspoon ... Add bay leaves, panch phoron, and asafetida and cook, stirring ...
Potato Curry with Tamarind Recipe at Epicurious.com
Find the recipe for Potato Curry with Tamarind and other curry recipes at Epicurious.com ... Add bay leaves, panch phoron, and asafetida and cook, stirring frequently, until ...
Shopping list for Potato Curry with Tamarind Recipe at ...
panch phoron (bengali spice mix) 3/4. teaspoon. asafetida powder. 1/8. teaspoon. cumin seeds. 1 ... Not printing the way you expected? See our Help page. Epicurious.com ...
panch phoron Recipes at Epicurious.com
show results for food recipes drink recipes member recipes all ... Potato Curry with Tamarind Gourmet, November 2005. Spiced Water Spinach Gourmet, February ...
KAALIM Member Profile - Community - Allrecipes
Detailed information about Allrecipes home cook, KAALIM ... I tossed in some "panch phoron" an Indian five-spice mixture, with the onion while it sauteed, and threw in ...
Panch Phoron (Indian Spice/Seed Mixture) Recipe - The Food ...
GroupRecipes.com the food social network serves up a Panch Phoron (Indian Spice/Seed Mixture) recipe. Step #1 Combine.Step #2 Yer done.Enjoy the Panch ...
panch phoron Recipes at Epicurious.com
show results for food recipes drink recipes member recipes all ... gharki dal (red lentils) Submitted by djd01 on Jan 09, 2009. potato, cauliflower and pea ...


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Grandfathers and the Impact of Raising Grandchildren
Bullock, Karen, Journal of Sociology & Social Welfare
Objectives. As grandparents are continuing to take on the responsible of raising their grandchildren in the absence of parents much attention in the literature is given to women. Little is known about the adjustment that older men make in these families. This study explored the experiences of grandfathers raising grandchildren.
Methods. Data were gathered by semi-structured interviews in a rural community in southeastern North Carolina and analyzed using a qualitative content analysis mode. Twenty-six men, age 65+, who were responsible for the care of at least one grandchild, participated.
Results. Eighty-one percent (N = 21) reported that their perception of powerlessness occurred either in the role transition or in the activities of daily parenting. Many expected to continue experiencing powerlessness throughout the parenting of the child.
Discussion. Grandfathers experience powerlessness that has not been reported in the literature on grandmothers raising grandchildren. Results affirm the need for special attention to elderly men who take on the role of parent for their grandchildren.
Key words: grandparents, rural men, grandfathers, parenting, caregivers
Grandparents have always played important roles in taking care of their children and grandchildren. However, in the United States, we are witnessing an unanticipated change in the role of the elderly. Increasingly, grandparents are raising grandchildren in the absence of the child's parents. Growth in grandparent-headed households has not occurred in a vacuum. Rather, it has been accompanied by a large number of other demographic, social, economic, and political changes (AARP, 1998) that potentially have profound implications for the welfare of both the old and the young. During the past 30 years, grandparents have become full-time parents for grandchildren whose parents are unable to do so. The number of grandchildren living in grandparent-maintained households is increasing steadily, with over 4.5 million such families in 2000 (Bryson 2001), up from 2.2 million in 1970 (Casper & Bryson, 1998). Several studies have focused on grandmothers (Bullock, 2004b; Dowdell, 1995; Edwards, 2003; Goodman & Silverstein, 2002; Roe, Minkler, Saunders, & Thomson, 1996; Solomon, & Marx, 1995; Whitley, Kelley, & Sipe, 2001) and their particular risks of increased psychological stress, physical health problems, social isolation, and inadequate resources when raising grandchildren.
Grandfathers on the other hand have received less attention. Because women tend to provide the bulk of the care provided to family members, an easy oversight is the impact of raising grandchildren on older men. Much of what we do know about grandparents raising grandchildren has come from data on urban families. Far less is known about older men living in rural areas who assume these childcare responsibilities. Many rural communities have suffered depopulation and job loss as their economies have struggled in the changing national and global marketplace (Glasgow, et al, 1993). As these communities depopulate, the informal caregiving base for rural elders shrinks, leaving them with little availability of social support options (Bullock, 2004a) compared to elders living in urban communities (Burnette, 1999a).
It is especially important to focus on grandfathers as a resource in grandparent-maintained families in rural areas due to the fact that rural elders generally have access to fewer community-based health and social services (Stoller, & Lee, 1994). The present research seeks to fill a gap in the literature by offering insight into the experiences and adjustments that older men in rural areas make when they are responsible for the care of at least one grandchild. Most importantly, the present data highlight the existence and concern of this increasingly vulnerable population, which is often overlooked in social welfare policies and practices. …


text:
metal detector Companies in Suriname
Category: Waste & Recycling ×
Subcategory: Waste Treatment ×
Keyword: metal detector ×
Location: Latin America ×
Location: Suriname ×
based in Arganda del Rey, SPAIN
IMABE IBERICA S.A. is a leading European equipment manufacturer of a full range of solid waste processing & recycling equipment. After more than 40 years in the market, our company has developed an outstanding high quality and reliable machinery for recyclables and residues volume reduction and offering nowadays a full range of horizontal balers, twin ram balers, ...
Sutco UK Ltd
based in Purley, UNITED KINGDOM
For more than 10 years Sutco UK has concentrated on the design, production, installation and maintenance of recycling plants. An efficient and technical solution for a better environment is our top priority: for the benefit of the operator, for the benefit of the environment.
De Nora Water Technologies
based in Colmar, PENNSYLVANIA (USA)
De Nora Water Technologies provides a range of trusted disinfection and filtration technologies and aftersales support services for water and wastewater treatment in the energy, marine and municipal markets worldwide. With more than 50 years' experience in water treatment, the company has developed, delivered and installed thousands of installations worldwide across a ...
ProMinent Group - ProMinent GmbH
based in Heidelberg, GERMANY
For more than 50 years, the ProMinent Group has been a manufacturer of components and systems in the field of fluid metering as well as a reliable solution partner for water treatment and water disinfection. Based on innovative products, comprehensive expertise in process technology and distinct application orientation, practical solutions are developed for ...
ERG (Air Pollution Control) Ltd
based in Horsham, UNITED KINGDOM
ERG (Air Pollution Control) Ltd is a leading supplier of air pollution control systems with a successful 30+ year history. We provide turn-key systems to give the best technical solution for the lowest capital and running costs. We have installed over 600 systems globally. To help you comply with emission regulations, we can draw on an unrivalled range of solutions. ...
RODI Systems Corp.
based in Aztec, NEW MEXICO (USA)
RODI Systems is a New Mexico (USA) corporation established in 1995. We began by providing custom designed reverse osmosis (RO), nanofiltration (NF), and ultrafiltration (UF) systems. Our product line quickly evolved to also include multi-parameter control systems designed specifically for membrane-based treatment applications. While we still consider ourselves proficient ...
Sutco RecyclingTechnik GmbH
based in Bergisch, GERMANY
Sutco RecyclingTechnik can deliver treatment and sorting systems for the waste industry. Concept, planning, production, installation, commissioning and service from one company. In addition, we can offer concepts, plannings for a modernization, optimization, the associated reconstruction, disassembly and even the reconstruction on a new site for plants already existing. ...
Hy-Bon Engineering Co.
based in Midland, TEXAS (USA)
Hy-Bon Engineering provides leading edge design and fabrication of customized compressor packages for handling low pressure gas streams. Regardless of the application: whether gas from oilfield stock tanks, casinghead gas, field gas collection, or biogas from wastewater facilities, digester tanks, landfills or breweries, Hy-Bon can design the package required. Hy-Bon also ...
Genesis Water Technologies, Inc
based in Maitland, FLORIDA (USA)
Genesis Water Technologies, Inc. is a USA based manufacturer of advanced, innovative and sustainable treatment solutions for applications in process water, drinking water, water reuse and waste water to our valued clients and collaboration partners worldwide.
Pollution & Process Monitoring Ltd
based in Sevenoaks, UNITED KINGDOM
Pollution and Process Monitoring - PPM is an independent limited company which manufactures and distributes instrumentation for water and wastewater applications. The company was founded in 1990 by a small team of highly qualified engineers that pioneered on-line TOC - Total Organic Carbon monitoring. The company has expanded over the years and now represents a number of ...
Related Terms for metal detector
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Blogs Home - Tags - global_competencies urn:lsid:ibm.com:blogs:entries 1 2015-11-16T08:09:50-05:00 IBM Connections - Blogs urn:lsid:ibm.com:blogs:entry-084ddaee-53c6-48cc-9e2a-76b0158d1836 African-based CIOs - Exploring challenges and capabilities in an evolving market Caitlin Halferty firstname.lastname@example.com 060000YXNY active Comment Entries Likes 2013-02-06T22:08:44-05:00 2014-07-10T14:44:47-04:00
 Caitlin Halferty
 Consultant, IBM Center for Applied Insights

 The IBM CAI blog has moved - please bookmark and follow the new blog at http://www.ibmcai.com

 Yesterday, on Tuesday February 5, 2013, IBM CEO Ginni Rometty addressed more than 200 South African business leaders in Johannesburg. IBM has been doing business in Africa for more than 90 years. Most recently, the company has been expanding its presence by focusing investments in more than 20 African countries.

 Current research suggests the top challenges African-based CIOs face today include:

 Availability of skilled resources

 Network and bandwith availability

 Availability of liquid assets to secure investments in technology

 Ensuring return on IT investment

 Consistent and effective security policies

 Familiarity of users and customers with new technologies

 Tie to legacy environment and tools that constrains the ability to adopt new technologies

 Implementation of technology standards across countries/regions

 Ability to meet regulatory and compliance regulations

 Stabilize and enhance IT infrastructure in support of the business

 Ability to establish meaningful metrics

 Improve risk management posture

 Establish effective governance processes

 As African-based CIOs rise to meet these challenges, should they look to the West or the East for their mentors?

 To further explore how these CIOs strengthen and transform their organizations in light of these challenges, we're assessing competencies and capabilities that span:

 Leadership

 Business strategy and process

 Business management

 Risk management and compliance

 Innovation and growth

 Relationship management and communications

 What competencies and capabilities do you see as most promising?

 We look to answer these questions and several others for you when we publish our research later this year. Post a comment and contribute your opinion to the conversation!
 Caitlin Halferty Consultant, IBM Center for Applied Insights The IBM CAI blog has moved - please bookmark and follow the new blog at http://www.ibmcai.com Yesterday, on Tuesday February 5, 2013, IBM CEO Ginni Rometty addressed... 0 0 1343 urn:lsid:ibm.com:blogs:entries-47e61919-c8c7-40c7-9923-e513ea9bf00f IBM Center for Applied Insights 2015-08-14T14:16:06-04:00


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It wasn't a tale of two halves for Franklin and Martinsville in the John R. Wooden Gymnasium on Friday night.
Their key Mid-State Conference boys basketball matchup was instead a tale of one quarter and then the other three periods.
And for Grizzly Cubs second-year coach Jerry Bomholt, the host Artesians' 59-43 victory was more of a horror story. At least for the last three-fourths of the contest.
"I was extremely disappointed — not with the score, but with how we played," Bomholt said. "We had a chance to dig in the second quarter, but we missed a couple of shots, and then I see the heads go down.
"We can't play that way and be effective."
Franklin had a chance to make a bigger logjam at the top of the Mid-State standings, but Friday's verdict dropped the Cubs to 3-2 in the league and 9-3 overall, ending a three-game winning streak.
Martinsville, meanwhile, bouncing back from a 20-point thumping at Bloomington South last weekend, improved to 4-0 in the Mid-State and 9-4 overall.
"We lost our opportunity to stay in the conference race," Bomholt said. "Now we have to look to other things."
The Artesians also avenged their 51-46 loss to Franklin in last season's annual meeting of ages-old neighboring foes.
The Cubs worked the basketball well in the opening eight minutes and outscored Martinsville 11-5 with the hosts hitting just one of nine shots.
After that, the Artesians put it all together while the visitors fell apart.
Senior guard Troy Spears swished a pair of 3-point baskets to begin the second quarter that saw Martinsville outscore Franklin 17-5.
Spears made four 3-pointers in all and led all scorers with 19 points while grabbing seven rebounds. Right behind was sophomore center Keegan Northern, who tallied 18 and had five rebounds. Senior forward Aaron Tincher added 11 points and nine boards.
After hitting just one basket in the opening period, the Artesians finished the night, making 20 of 41 field-goal attempts (48.8 percent). Franklin hit just 9 of 26 shots after the first quarter and was 13 of 35 for the ballgame (37.1).
Martinsville was especially sharp in the third period, hitting 8 of 11 shots at the basket and scoring 19 points to take a 41-27 lead into the final stanza.
The Cubs were paced by junior guard Dylan Phair, who was the lone Franklin player to score double-digit points with 11. Senior forward Nick King contributed nine points.
Franklin returns to action tonight against visting Southport.


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