text:
|Publication number
|Publication type
|Application number
|Publication date
|Dec 9, 1986
|Filing date
|Jul 7, 1983
|Priority date
|Jul 7, 1982
|Fee status
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|Publication number
|Rudolf Eidenschink, Joachim Krause, Beatrice M. Andrews, George W. Gray, Neil Carr
|Original Assignee
|Merck Patent Gesellschaft Mit Beschrankter Haftung, The Secretary Of State For Defense In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (25), Non-Patent Citations (16), Referenced by (13), Classifications (106), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
R1 --Q1 --(CH2)m --(COO)n --(CH2)p
R1 --Q1 --(CH2)4 --Q2 --R2, (a)
R1 --Q1 --(CH2)6 --Q2 --R2, (b)
R1 --Q1 --CH2 --COO--CH2 --Q2 --R2, or (c)
R3 --Cy--Phe--CH2 CH2 --COO--Phe--R2 (d)
It is an object of this invention to provide new, stable, liquid-crystalline or mesogenic compounds which are suitable for use as components of liquid-crystal dielectrics.
Upon further study of the specification and appended claims, further objects and advantages of this invention will become apparent to those skilled in the art.
These objects have been achieved by providing the compounds of Formula I,
R1 --Q1 --(CH2)m --(COO)n --(CH2)p --Q2 --R2 I
R1 and R2 are each independently alkyl or alkoxy each of 1-12 C atoms, F, Cl, Br, CN or --Q3 --R3 and one of R1 or R2 can also be H;
Q1, Q2 and Q3 are each independently 1,4-phenylene, 1,4-cyclohexylene, 1,4-bicyclo(2,2,2)-octylene or 1,3-dioxane-2,5-diyl, each of which is unsubstituted or substituted by 1-4 fluorine, chlorine and/or bromine atoms;
R3 is alkyl or alkoxy each of 1-8 C atoms, H, F, Cl, Br or CN;
m is 1, 2, 3, 4, 5 or 6; n is 0 or 1; and p is 0, 1, 2, 3, 4 or 5; the sum of (m+p) being 2, 4 or 6 and the sum of (m+n+p) being at least 3;
and wherein Q3 is only a 1,4-phenylene radical which is unsubstituted or substituted by a fluorine, chlorine or bromine atom, when n=1, and/or (m+p)=6, and/or at least one of the radicals R1 to R3 is F, Cl or Br, and/or none of the radicals R1 to R3 is CN, and/or two of the radicals R1 or R3 are CN.
For the sake of simplicity, in the following, "Phe" is 1,4-phenylene, "Cy" is 1,4-cyclohexylene, "Bi" is bicyclo(2,2,2)octylene, and "Dio" is 1,3-dioxane-2,5-diyl. It is possible for these groups, in particular 1,4-phenylene, to be unsubstituted or substituted by 1-4 fluorine, chlorine and/or bromine atoms, when so referred. Furthermore, the group --(CH2)m --(COO)n --(CH2)p -- is briefly designated "Z" in the following text.
Similar compounds are known, for example from German Offenlegungsschrift No. 2,617,593. That text discloses, for example, a general formula ##STR1## wherein one of the groups X and Y is cyano and the others can, inter alia, also be alkyl or alkoxy and A can, inter alia, also be --(CH2)4 --.
Like similar compounds, for example like those known from German Offenlegungsschrift No. 2,617,593, whose disclosure is incorporated by reference herein, the compounds of Formula I can be used as components of liquid-crystal dielectrics, in particular for displays based on the principle of the twisted cell, the guest-host effect, the effect of the deformation of aligned phases or the effect of dynamic scattering.
It has been found that the compounds of Formula I are excellently suitable for use as components of liquid-crystal dielectrics. In particular, they make it possible to prepare stable liquid-crystal phases which have a broad nematic range and a low viscosity.
In addition, the provision of the compounds of Formula I broadens considerably, in a very general manner, the range of liquid-crystal substances which are suitable, from various points of view relating to applied technology, for the production of nematic mixtures.
The compounds of Formula I possess a broad field of application. Depending on the choice of substitutents, these compounds can be used as the base materials from which liquid-crystal dielectrics are principally composed; however, it is also possible to add liquid-crystal base materials belonging to other classes of compounds to the compounds of Formula I, in order, for example to reduce the viscosity or the double refraction of such a dielectric. The compounds of Formula I, particularly those containing cyclohexane or dioxane rings having substitutents in the cis-position, and also those wherein R1 and/or R2 are H, Cl, Br or CN, are also suitable for use as intermediate products for the preparation of other substances which can be used as constituents of liquid-crystal dielectrics.
In the pure state, the compounds of Formula I are colorless and form liquid-crystal meso-phases of low viscosity within a temperature range which is advantageously situated for electro-optical use. They are very stable chemically.
The invention thus relates to the compounds of Formula I and to a process for their preparation, comprising
treating with a reducing agent, a compound which otherwise corresponds to Formula I, but contains one or more reducible groups and/or C--C bonds instead of H atoms; or,
in order to prepare esters of Formula I (n=1), reacting a carboxylic acid of Formula II
R1 --Q1 --(CH2)m --COOH II
wherein R1, Q1 and m are as defined above, or one of its reactive derivatives, with an alcohol or phenol of Formula III
HO--(CH2)p --Q2 R2 III
wherein R2, Q2 and p are as defined above or with one of its reactive derivatives; or,
in order to prepare dioxane derivatives of Formula I wherein at least one of the radicals Q1 to Q3 is a 1,3-dioxane-2,5-diyl group, reacting an appropriate aldehyde with an appropriate 1,3-diol; or,
in order to prepare nitriles of Formula I (R1, R2 and/or R3 =CN), dehydrating an appropriate carboxamide; or,
in order to prepare ethers of Formula I (R1, R2 and/or R3 =alkoxy), etherifying an appropriate hydroxy compound; and/or,
if appropriate, reacting a chlorine or bromine compound of Formula I (R1, R2 and/or R3 =Cl or Br) with a cyanide.
The present invention also relates to the use of the compounds of Formula I as components of liquid-crystal dielectrics. The invention also relates to liquid-crystal dielectrics containing at least one compound of Formula I and also to electro-optical display elements containing dielectrics of this type.
Unless indicated expressly otherwise, in the preceding and following text R1, R2, R3, Q1, Q2, Q3, m, n and p are as defined above.
Accordingly, the compounds of Formula I embrace compounds of the partial formulae Ia to Ip:
R1 --Q1 --(CH2)q --Q2 --R.sup. Ia
wherein q is 4 or 6, specifically:
R1 --Q1 --(CH2)4 --Q2 --R2 Ib
R1 --Q1 --(CH2)6 --Q2 --R2 Ic;
R1 --Q1 --(CH2)m --COO--(CH2)p --Q2 --R2 Id
R1 --Q1 --CH2 --COO--CH2 --Q2 --R2 Ie
R1 --Q1 --CH2 --COO--(CH2)3 --Q2 --R2 If
R1 --Q1 --CH2 --COO--(CH2)5 --Q2 --R2 Ig
R1 --Q1 --(CH2)2 --COO--Q2 --R2 Ih
R1 --Q1 --(CH2)2 --COO--(CH2)2 --Q2 --R2 Ii
R1 --Q1 --(CH2)2 --COO--(CH2)4 --Q2 --R2 Ij
R1 --Q1 --(CH2)3 --COO--CH2 --Q2 --R2 Ik
R1 --Q1 --(CH2)3 --COO--(CH2)3 --Q2 --R2 Il
R1 --Q1 --(CH2)4 --COO--Q2 --R2 Im
R1 --Q1 --(CH2)4 --COO--(CH2)2 --Q2 --R2 In
R1 --Q1 --(CH2)5 --COO--CH2 --Q2 --R2 Io
R1 --Q1 --(CH2)6 --COO --Q2 --R2 Ip.
Among these, the compounds of the Formulae Ia, Ib, Ic and Ie are particularly preferred.
Compounds of Formula I containing two rings embrace those of the partial Formulae Iq to Iaf, of which those of the Formulae Iq, Ir, Iu, Iv, Iaa and Iaf are particularly preferred:
R1 --Phe--Z--Phe--R2 Iq
R1 --Phe--Z--Cy--R2 Ir
R1 --Phe--Z--Bi--R2 Is
R1 --Phe--Z--Dio--R2 It
R1 --Cy--Z--Phe--R2 Iu
R1 --Cy--Z--Cy--R2 Iv
R1 --Cy--Z--Bi--R2 Iw
R1 --Cy--Z--Dio--R2 Ix
R1 --Bi--Z--Phe--R2 Iy
R1 --Bi--Z--Cy--R2 Iz
R1 --Bi--Z--Bi--R2 Iaa
R1 --Bi--Z--Dio--R2 Iab
R1 --Dio--Z--Phe--R2 Iac
R1 --Dio--Z--Cy--R2 Iad
R1 --Dio--Z--Bi--R2 Iae
R1 --Dio--Z--Dio--R2 Iaf.
Among the compounds of Formula I containing three rings, those of the partial Formulae Iag to Iaj are particularly preferred:
R1 --Phe--Phe--Z--Phe--R2 Iag
R1 --Cy--Phe--Z--Phe--R2 Iah
R1 --Phe--Z--Phe--Cy--R2 Iai
R1 --Cy--Phe--Z--Cy--R2 Iaj.
Among the compounds of the Formula I containing four rings, those of the partial Formuale Iak to Iap are particularly preferred:
R1 --Phe--Phe--Z--Phe--Phe--R2 Iak
R1 --Cy--Phe--Z--Phe--Cy--R2 Ial
R1 --Dio--Phe--Z--Phe--Dio--R2 Iam
R1 --Phe--Cy--Z--Cy--Phe--R2 Ian
R1 --Cy--Cy--Z--Cy--Cy--R2 Iao
R1 --Dio--Cy--Z--Cy--Dio--R2 Iap.
In the compounds of Formula I and also Ia to Iap, the alkyl and/or alkoxy radicals can be linear or branched. Preferably, they are linear, have 2, 3, 4, 5 or 6 C atoms and are, accordingly, preferably, ethyl, propyl, butyl, pentyl, hexyl, ethoxy, propoxy, butoxy, pentoxy or hexyloxy, and also methyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, methoxy, heptyloxy, octyloxy, decyloxy, undecyloxy and dodecyloxy.
Compounds of Formula I and also Ia to Iap having branched wing groups R1, R2 or R3 can occasionally be of importance because of superior solubility in the customary liquid-crystal base materials, but are especially of importance as chiral doping substances if they are optically active. As a rule, branched groups of this type contain not more than one chain branching. Preferred branched radicals R1 and R2 are isopropyl, 2-butyl(=1-methylpropyl), isobutyl(=2-methylpropyl), 2-methylbutyl, isopentyl(=3-methylbutyl), 2-methylpentyl, 3-methylpentyl, 2-ethylhexyl, 2-heptylpentyl, isopropoxy, 2-methylpropoxy, 2-methylbutoxy, 3-methylbutoxy, 2-methylpentoxy, 3-methylpentoxy, 2-ethylhexyloxy, 1-methylhexyloxy and 1-methylheptyloxy.
Specifically, R1 and R2 are preferably alkyl, alkoxy or CN. Preferred compounds among the compounds of Formulae I and also Ia to Iap are those in which at least one of the radicals contained therein has one of the preferred meanings indicated. Minor groups of compounds which are particularly preferred are those of the Formulae Iaq to Ibf:
R3 --Phe--(CH2)q --Phe--R3 Iaq
Alkoxy--Phe--(CH2)q --Phe-Alkoxy Iar
NC--Phe--(CH2)q --Phe--CN Ias
R1 --Phe--(CH2)q --Phe--CN Iat
R3 --Phe--(CH2)q --Phe--CN Iau
Alkyl--Phe--(CH2)q --Phe--CN Iav
Alkoxy--Phe--(CH2)q --Phe--CN Iaw
R3 --Cy--Phe--(CH2)q --Phe--Cy--R3 Iax
Alkyl--Cy--Phe--(CH2)q --Phe--Cy--Alkyl Iay
R1 --Phe--CH2 --COO--CH2 --Q2 --R2 Iaz
R1 --Phe--CH2 --COO--CH2 --Phe--R3 Iba
R1 --Phe--CH2 --COO--CH2 --Phe--CN Ibb
R3 --Phe--CH2 --COO--CH2 --Phe--R3 Ibc
(wherein the two R3 groups and the two alkyl or alkoxy groups can be identical or different)
R3 --Phe--CH2 --COO--CH2 --Phe--CN Ibd
R3 --Cy--Phe--CH2 --COO--CH2 --Phe--R3 Ibe
(wherein the two R3 groups can be identical or different)
R3 --Cy--Phe--CH2 --COO--CH2 --Phe--CN Ibf.
In the compounds of Formulae I and also Ia to Ibf, preferred stereoisomers are those wherein the substituents on the cyclohexene and/or the dioxanediyl radicals are in each case in the trans-position in relation to one another.
The compounds of Formula I are prepared by methods which are in themselves known, such as are described in the literature (for example in the standard works, such as Houben-Weyl, Methoden der Organischen Chemie ("Methods of Organic Chemistry"), Georg-Thieme-Verlag, Stuttgart), specifically under reaction conditions which are known and suitable for the reactions mentioned. In these methods it is also possible to make use of variants which are in themselves known, but are not mentioned here in greater detail.
If desired, the starting materials can also be formed in situ, in a process in which they are not isolated from the reaction mixture, but are immediately reacted further to give the compounds of Formula I.
The compounds of Formula Ia are preferably prepared by reducing a compound which otherwise corresponds to Formula I, but contains one or more reducible groups and/or C--C bonds instead of H atoms.
Suitable reducible groups are preferably carbonyl groups, especially keto groups, and also, for example, free or esterified hydroxyl groups or halogen atoms attached to an aromatic ring. Preferred starting materials for the reduction correspond to the Formula I, but contain the group --CO--(CH2)m-1 -- instead of the group --(CH2)m -- and/or the group --(CH2)p-1 --CO-- instead of the group --(CH2)p -- and/or a cyclohexene ring instead of a cyclohexane ring.
Examples of preferred starting materials for the reduction are ketones of the formula
R1 --Q1 --(CO)r --(CH2)s --(CO)t --Q2 --R2
wherein r is 0 or 1, s is 2, 3, 4 or 5, t is 0 or 1, the sum of (r+t) is 1 or 2 and the sum of (r+s+t) is 4 or 6. Specifically these are compounds of the following formulae:
In these compounds the radical Q1 or Q2 which is attached to the CO group is preferably Phe. These ketones can be obtained, for example, by a Friedel-Crafts reaction between the corresponding aromatic compounds of the formulae R1 --Phe--H or H--Phe--R2 and the corresponding acid chlorides of the formulae
Cl--CO--CH2 CH2 --CO--Cl, Cl--CO--(CH2)3 --Q2 --R2,
R1 --Q1 --(CH2)3 --CO--Cl, Cl--CO--(CH2)4 --CO--Cl,
Cl--CO--(CH2)5 --Q2 --R2
R1 --Q1 --(CH2)5 --CO--Cl.
Examples of starting materials containing cyclohexene rings are those of Formula V ##STR2## wherein u and v are each 0 or 1.
The starting materials of Formula V can be obtained, for example, by reacting 4-R3 -cyclohexanones with organometallic compounds of the formula Li--(Phe)u --Z--(Phe)v --Li or corresponding Grignard compounds, the resulting carbinols being subsequently dehydrated.
The reduction is preferably effected by catalytic hydrogenation at temperatures of about 0� to about 200� and under pressures of about 1 to about 200 bar in an inert solvent, for example an alcohol, such as methanol, ethanol or isopropanol, an ether such as tetrahydrofuran (THF) or dioxane, an ester, such as ethyl acetate, a carboxylic acid, such as acetic acid, or a hydrocarbon, such as cyclohexane.
Suitable catalysts are preferably noble metals, such as Pt or Pd, which can be employed in the form of oxides (for example PtO2 or PdO), on a support (for example Pd on charcoal, calcium carbonate or strontium carbonate) or in a finely divided form (for example Pt black). The mentioned ketones of Formula IV can also be reduced by the Clemmensen method (using zinc, amalgamated zinc or tin and hydrochloric acid, preferably in an aqueous alcoholic solution or in a heterogeneous phase using water/benzene or water/toluene at temperatures of about 80� to 120�) or the Wolff-Kishner method (using hydrazine, preferably in the presence of an alkali, such as KOH or NaOH, in a high-boiling solvent, such as diethylene glycol or triethylene glycol, at temperatures of about 100� to 200�).
Esters of Formula I (n=1) can also be obtained by esterifying corresponding carboxylic acids of Formula II (or their reactive derivatives) with alcohols or phenols of Formula III (or their reactive derivatives).
Suitable reactive derivatives of the mentioned carboxylic acids are, in particular, the acid halides, above all the chlorides and bromides, and also the anhydrides, for example also mixed anhydrides of the formula R1 --Q1 --(CH2)m --CO--O--COCH3, azides or esters, especially alkyl esters of 1-4 C atoms in the alkyl group.
Suitable reactive derivaties of the alcohols or phenols mentioned are, in particular, the corresponding metal alcoholates or phenates of the formula MO--(CH2)p --Q2 --R2 in which M is one equivalent of a metal, preferably an alkali metal, such as Na or K.
The esterification is advantageously carried out in the presence of an inert solvent. Solvents which are very suitable are, in particular, ethers, such as diethyl ether, di-n-butyl ether, THF, dioxane or anisole, ketones, such as acetone, butanone or cyclohexanone, amides, such as dimethylformamide (DMF) or phosphoric acid hexamethyl triamide, hydrocarbons, such as benzene, toluene or xylene, halogenated hydrocarbons, such as carbon tetrachloride or tetrachloroethylene, and sulfoxides, such as dimethyl sulfoxide or sulfolane. Water-immiscible solvents cn be used advantageously at the same time for removing, by azeotropic distillation, the water formed in the esterification. An excess of an organic base, for example pyridine, quinoline or triethylamine, can also occasionally be used as the solvent for the esterification. The esterification can also be carried out in the absence of a solvent, for example by merely heating the components in the presence of sodium acetate. The reaction temperature is usually -50� to +250�, preferably -20� to +80�. At these temperatures the esterification reactions are complete, as a rule, after 15 minutes to 48 hours.
In individual cases, the reaction conditions for the esterification depend largely on the nature of the starting materials used. Thus a free carboxylic acid is as a rule reacted with a free alcohol or phenol in the presence of a strong acid, for example a mineral acid, such as hydrochloric acid or sulfuric acid. A preferred mode of reaction is to react an acid anhydride or, in particular, an acid chloride with an alcohol, preferably in a basic medium, bases of importance being, in particular alkali metal hydroxides, such as sodium hydroxide or potassium hydroxide, alkali metal carbonates or bicarbonates, such as sodium carbonate, sodium bicarbonate, potassium carbonate or potassium bicarbonate, alkali metal acetates, such as sodium acetate or potassium acetate, alkaline earth metal hydroxides, such as calcium hydroxide, or organic bases, such as triethylamine, pyridine, lutidine, collidine or quinoline. A further preferred embodiment of the esterification comprises first converting the alcohol or the phenol into the sodium alcoholate or phenate or potassium alcoholate or phenate, for example by treatment with ethanolic sodium hydroxide or potassium hydroxide solution, isolating this alcoholate or phenate and suspending it by stirring in acetone or diethyl ether, together with sodium bicarbonate or potassium carbonate, and adding a solution of the acid chloride or anhydride in diethyl ether, acetone or DMF to this suspension, preferably at temperatures of about -25� to +20�.
Dioxane derivatives of Formula I (wherein one of the groups Q1, Q2 and/or Q3 is 1,3-dioxane-2,5-diyl are preferably prepared by reacting an appropriate aldehyde, for example of the formulae R1 --CHO, R2 --CHO, O═CH--Z--Q2 --R2 or R1 --Q1 --Z--CHO (or a reactive derivative thereof) with an appropriate 1,3-diol, for example of the formulae (HOCH2)2 CH--Z--Q2 R2, R1 --Q1 --Z--CH(CH2 OH)2, R1 CH(CH2 OH)2 or (HOCH2)2 CH--R2 (or one of its reactive derivatives), preferably in the presence of an inert solvent, such as benzene or toluene and/or a catalyst, for example a strong acid, such as sulfuric acid, benzenesulfonic acid or p-toluenesulfonic acid, at temperatures of about 20 to about 150, preferably 80� to 120�. Suitable reactive derivatives of the starting materials are primarily acetals, for example of the formulae R1 --CH(OR4)2, R2 --CH(OR4)2, (R4 O)2 CH--Z--Q2 --R2, R1 --Q1 --Z--CH(OR4)2, R5 --CH(OCH2)2 CH--Z--Q2 --R2, R1 --Q1 --Z--CH(CH2 O)2 CH--R5, R1 --CH(CH2 O)2 --CH--R5 or R5 --CH(OCH2)2 CH--R2, wherein R4 is alkyl of 1-4 C atoms, or two radicals R4 together being alkylene having 2 or 3 C atoms and R5 is H, alkyl of 1-4 C atoms or phenyl.
The mentioned aldehydes and 1,3-diols and also their reactive derivatives are in some cases known. In all cases they can be prepared without difficulty by standard processes of organic chemistry from compounds known from the literature. For example, the aldehydes can be obtained by oxidizing corresponding alcohols or by reducing corresponding carboxylic acids or derivatives thereof, and the diols by reducing corresponding diesters.
In order to prepare nitriles of Formula I (R1, R2 and/or R3 =CN), especially those of the Formulae Ias, Iat, Iau, Iav, Iaw, Ibb, Ibd and Inf, corresponding acid amides, for example those of the Formulae H2 NCO--Q1 --Z--Q2 --R2 or R1 --Q1 --Z--Q2 --CONH2, can be dehydrated. The amides can be obtained, for example, from corresponding esters or acid halides by reaction with ammonia. Examples of suitable dehydrating agents are inorganic acid chlorides, such as SOCl2, PCl3, PCl5, POCl3, SO2 Cl2 or COCl2, and P2 O5, P2 S5 or AlCl3 (for example in the form of the double compound with NaCl), and aromatic sulfonic acids and sulfonyl halides. This reaction can be carried out in the presence or absence of an inert solvent at temperatures of about 0� to 150�; examples of suitable solvents are bases, such as pyridine or triethylamine, aromatic hydrocarbons, such as benzene, toluene or xylene, or amides, such as DMF.
Alkoxy compounds of Formula I (R1, R2 and/or R3 =alkoxy) can be obtained by alkylating corresponding hydroxy compounds, preferably corresponding phenols, it being preferred first to convert the hydroxy compound into a corresponding metal derivative, for example into the corresponding alkali metal alcoholate or alkali metal phenate by treatment with NaOH, KOH, Na2 CO3 or K2 CO3. This alcoholate or phenate can then be reacted with the corresponding alkyl halide or sulfonate or dialkyl sulfate, preferably in an inert solvent, such as acetone, DMF or dimethyl sulfoxide or an excess of aqueous or aqueous-alcoholic NaOH or KOH, at temperatures of about 20� to 100�.
In order to prepare nitriles of Formula I (R1, R2 and/or R3 =CN) corresponding chlorine or bromine compounds of the Formula I (R1, R2 and/or R3 =Cl or Br) can also be reacted with a cyanide, preferably a metal cyanide, such as NaCN, KCN or Cu2 (CN)2, for example in the presence of pyridine in an inert solvent, such as DMF or N-methylpyrrolidone, at temperatures of 20� to 200�.
All of the starting materials required in the mentioned processes for preparing all of the compounds of this invention are known and/or readily preparable using fully conventional methods beginning with known compounds.
The dielectrics according to this invention comprise 2 to 15, preferably 3 to 12, components, including at least one compound of Formula I. The other constitutents are preferably selected from the nematic or nematogenic substances, especially the known substances, belonging to the classes comprising azoxybenzenes, benzylideneanilines, biphenyls, terphenyls, phenyl or cyclohexyl benzoates, phenyl or cyclohexyl cyclohexanecarboxylates, phenylcyclohexanes, cyclohexylbiphenyls, cyclohexylcyclohexanes, cyclohexylnaphthalenes, 1,4-bis-cyclohexylbenzenes, 4,4'-bis-cyclohexylbiphenyls, phenylpyrimidines, cyclohexylpyrimidines, phenyldioxanes or cyclohexyldioxanes and, if appropriate, halogenated stilbenes, benzyl phenyl esters, tolanes and substituted cinnamic acids.
The most important compounds which are suitable as constitutents of liquid-crystal dielectrics of this type can be characterized by Formula III
wherein A and E are each a carbocyclic or heterocyclic ring system belonging to the group comprising 1,4-disubstituted benzene and cyclohexane rings, 4,4'-disubstituted biphenyl, phenylcyclohexane and cyclohexylcyclohexane systems, 2,5-disubstituted pyrimidine rings and 1,3-dioxane rings, 2,6-disubstituted naphthalene, dihydronaphthalene, tetrahydronaphthalene, quinazoline and tetrahydroquinazoline; G is
______________________________________--CH═CH-- --N(O)═N----CH═CY-- --CH═N(O)----C.tbd.C-- --CH2 --CH2 ----CO--O-- --CH2 --O----CO--S-- --CH2 --S----CH═N-- --COO--Phe--COO--______________________________________
or a C--C single bond; Y is halogen, preferably chlorine, or --CN; and R6 and R7 are alkyl, alkoxy, alkanoyloxy or alkoxycarbonyloxy having up to 18, preferably up to 8, carbon atoms, or one of these radicals is also CN, NC, NO2, CF3, F, Cl or Br.
In most of these compounds, R6 and R7 are different from one another, one of these radicals being an alkyl or alkoxy group in most cases. However, other variants of the envisaged substitutents are also customary. Many of such substances or mixtures thereof are commercially available.
The dielectrics according to this invention usually contain about 0.1 to 60, preferably 5 to 40, % of one or more compounds of Formula I.
The dielectrics according to this invention are prepared in a manner which is in itself customary. As a rule, the components are dissolved in one another, preferably at an elevated temperature.
The liquid-crystal dielectrics according to this invention can be modified in such a manner by means of suitable additives that they can be used in all the hitherto disclosed types of liquid-crystal display elements. Additives of this type are known to those skilled in the art and are described in detail in the literature. For example, conducting salts, preferably ethyldimethyldodecylammonium 4-hexyloxybenzoate, tetrabutylammonium tetraphenylboranate or complex salts of crown ethers (compare, for example, I. Haller et al., Mol. Cryst. Liq. Cryst., Volume 24, pages 249-258 (1973)) can be added to improve the conductivity; dichroic dyestuffs can be added in order to prepare colored quest-host systems; or substances can be added to modify the dielectric anisotropy, the viscosity and/or the orientation of the nematic phases. Substances of this type are described, for example, in German Offenlegungsschriften Nos. 2,209,127, 2,240,864, 2,321,632, 2,338,281, 2,450,088, 2,637,430, 2,853,728 and 2,902,177.
Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The following preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever. In the following examples and in the preceding text, all temperatures are set forth uncorrected in degrees Celsius and all parts and percentages are by weight, unless otherwise indicated.
In the examples, m.p. is the melting point and c.p. is the clear point of a liquid crystal substance.
A mixture of 48.6 g of 1,2-bis-(p-trans-4-propylcyclohexylbenzoyl)-ethane (obtainable from trans-1-phenyl-4-propylcyclohexane and succinyl chloride in the presence of AlCl3), 30 g of KOH, 50 ml of 85% hydrazine and 500 ml of triethylene glycol is warmed at 120� for 1 hour. The temperature is raised slowly until the dihydrazone formed is decomposed. The mixture is boiled for a further 4 hours and cooled and worked up in a customary manner to give 1,4-bis-(p-trans-4-propylcyclohexylphenyl)butane, m.p. 136�, c.p. 158�.
The following compounds are obtained analogously by Wolff-Kishner reduction of the appropriate diketones:
1,6-Bis-p-methoxyphenylhexane, m.p. 71�, c.p. -25�
1,4-Bis-(p-trans-4-propylcyclohexylphenyl)-butane, m.p. 136�, c.p. 158�, is obtained analogously to Example 1 by a Wolff-Kishner reaction from 47.2 g of 1-(p-trans-4-propylcyclohexylbenzoyl)-3-(p-trans-4-propylcyclohexylphenyl)-propane [obtainable from 4-(p-trans-4-propylcyclohexylphenyl)-butyryl chloride and trans-1-phenyl-4-propylcyclohexane].
A solution of 51.4 g of 1,4-bis-(p-trans-4-propylcyclohexylbenzoyl)-butane (obtainable from trans-1-phenyl-4-propylcyclohexane and adipoyl chloride in the presence of AlCl3) in 500 ml of THF is hydrogenated over 5 g of 10% Pd-on-C at 40� and 1 bar until absorption of H2 ceases. The mixture is filtered and evaporated to give 1,6-bis-(p-trans-4-propylcyclohexylphenyl)-hexane, m.p. 107�, c.p. 129�.
The following are obtained analogously by hydrogenating the corresponding diketones:
A solution of 45.4 g of 1,4-bis-(p-propylcyclohexen-1-ylphenyl)-butane [obtainable by reacting 1,4-bis-(p-bromomagnesiophenyl)-butane with 4-propylcyclohexanone, subsequently hydrolyzing the product to give 1,4-bis-(p-(4-propyl-1-hydroxycyclohexyl)-phenyl)-butane and dehydrating the latter with p-toluenesulfonic acid in boiling toluene] in 600 ml of THF is hydrogenated over 5 g of PdO at 40� and 1 bar until hydrogen absorption ceases. The mixture is filtered and evaporated and the resulting cis-trans mixture is dissolved in 200 ml of DMF, 14 g of K tert-butylate is added and the mixture is heated at 100� for 24 hours under N2. After cooling, the mixture is poured into water and the resulting 1,4-(bis-(p-trans-4-propylcyclohexylphenyl)-butane is filtered off; m.p. 136�, c.p. 158�.
The following are obtained analogously by hydrogenating the corresponding cyclohexene derivatives:
28.8 g of p-(trans-4-pentylcyclohexyl)-phenylacetic acid is boiled for 1 hour with 24 g of SOCl2 ; the mixture is evaporated; the crude acid chloride obtained is dissolved in 150 ml of toluene, 8 ml of pyridine and 13.3 g of p-cyanobenzyl alcohol are added; and the mixture is boiled for 2 hours. Cooling and working up in a customary manner give p-cyanobenzyl p-(trans-4-pentylcyclohexyl)-phenylacetate, m.p. 85�, c.p. 30�.
The following are obtained analogously by esterifying the corresponding acids:
p-cyanobenzyl p-methoxyphenylacetate
p-cyanobenzyl p-ethoxyphenylacetate
p-cyanobenzyl p-propoxyphenylacetate
p-cyanobenzyl p-(trans-4-propylcyclohexyl)-phenylacetate
p-cyanobenzyl p-(trans-4-butylcyclohexyl)-phenylacetate
p-fluorobenzyl p-(trans-4-pentylcyclohexyl)-phenylacetate
p-chlorobenzyl p-(trans-4-pentylcyclohexyl)-phenylacetate
p-bromobenzyl p-(trans-4-pentylcyclohexyl)-phenylacetate
trans-4-propylcyclohexylmethyl p-methoxyphenylacetate
3-p-cyanophenylpropyl p-cyanophenylacetate
5-p-cyanophenylpentyl p-fluorophenylacetate
p-cyanophenyl 3-phenylpropionate
p-cyanophenyl 3-(p-trans-4-propylcyclohexyl-phenyl)propionate, m.p. 91�, c.p. 108�
p-ethoxyphenyl 3-(p-trans-4-propylcyclohexyl-phenyl)propionate
p-butoxyphenyl 3-(p-trans-4-propylcyclohexyl-phenyl)propionate, m.p. 75�, c.p. 101�
p-propylphenyl 3-(p-trans-4-propylcyclohexyl-phenyl)propionate
p-pentylphenyl 3-(p-trans-4-propylcyclohexyl-phenyl)propionate, m.p. 65�, c.p. 74�
p-heptylphenyl 3-(p-trans-4-propylcyclohexyl-phenyl)propionate
p-fluorophenyl 3-(p-trans-4-propylcyclohexyl-phenyl)propionate, m.p. 97�, c.p. 55� (monotropic)
p-cyanophenyl 3-(p-trans-4-pentylcyclohexyl-phenyl)propionate
p-ethoxyphenyl 3-(p-trans-4-pentylcyclohexyl-phenyl)propionate
p-butoxyphenyl 3-(p-trans-4-pentylcyclohexyl-phenyl)propionate
p-propylphenyl 3-(p-trans-4-pentylcyclohexyl-phenyl)propionate
p-pentylphenyl 3-(p-trans-4-pentylcyclohexyl-phenyl)propionate
p-heptylphenyl 3-(p-trans-4-pentylcyclohexyl-phenyl)propionate
p-fluorophenyl 3-(p-trans-4-pentylcyclohexyl-phenyl)propionate
2-p-cyanophenylethyl 3-p-methoxyphenylpropionate
4-p-cyanophenylbutyl 3-p-chlorophenylpropionate
p-cyanobenzyl 4-p-ethoxyphenylbutyrate
3-p-cyanophenylpropyl 4-p-ethoxyphenylbutyrate
p-cyanophenyl 5-p-ethoxyphenylpentanoate
2-cyanophenylethyl 5-p-ethoxyphenylpentanoate
p-cyanobenzyl 6-p-ethoxyphenylhexanoate
p-cyanophenyl 7-p-ethoxyphenylheptanoate.
A mixture of 1 g of hexanal, 2.5 g of 2-(4-p-propylphenylbutyl)-propane-1,3-diol (obtainable by reacting diethyl malonate with 4-p-propylphenylbutyl bromide to give diethyl 2-(4-p-propylphenylbutyl)-malonate and reducing the latter with LiAlH4), 0.01 g of p-toluenesulfonic acid and 15 ml of toluene is boiled for 3 hours under a water separator and is cooled, washed with water and evaporated. This gives 2-pentyl-5-(4-p-propylphenylbutyl-1,3-dioxane.
The following are obtained analogously by reacting the corresponding aldehydes with the corresponding diols:
65 g of POCl3 is added dropwise at 50� and while stirring to a solution, in 500 ml of DMF, of 31.3 g of p-carbamoylbenzyl p-ethoxyphenylacetate (obtainable by esterification). After stirring for a further hour, the mixture is poured onto ice and worked up in a customary manner to give p-cyanobenzyl p-ethoxyphenylacetate, m.p. 59�, c.p. -40�.
The following are obtained analogously by dehydrating the corresponding amides:
A mixture of 26.8 g of 1-p-propylphenyl-4-p-hydroxyphenylbutane, 6.9 g of K2 CO3, 25 g of hexyl iodide and 250 ml of DMF is heated at 80� for 16 hours, while stirring, and is then cooled and worked up in a customary manner. This gives 1-p-propylphenyl-4-p-hexoxyphenylbutane.
The following are obtained analogously by etherification:
A mixture of 34.9 g of p-bromobenzyl p-ethoxyphenylacetate (obtainable by esterification), 10 g of Cu2 (CN)2, 120 ml of pyridine and 60 ml of N-methylpyrrolidone is heated at 150� for 2 hours. The mixture is cooled; a solution of 120 g of FeCl3.6H2 O in 600 ml of 20% hydrochloric acid is added; and the mixture is warmed at 70� for 1.5 hours while stirring and worked up in a customary manner to give p-cyanobenzyl p-ethoxyphenylacetate, m.p. 59�, c.p. -40�.
The following are obtained analogously from 1,4-bis-p-bromophenylbutane and from 1,6-bis-p-bromophenylhexane, respectively:
The following are examples of dielectrics according to the invention containing at least one compound of Formula I:
A mixture of:
15% of p-(trans-4-propylcyclohexyl)-benzonitrile
11% of p-(trans-4-butylcyclohexyl)-benzonitrile
21% of p-(trans-4-pentylcyclohexyl)-benzonitrile
15.5% of 1,6-bis-(p-methoxyphenyl)-hexane
21% of 4-ethyl-4'-(trans-4-pentylcyclohexyl)-biphenyl
12% of 4-(trans-4-pentylcyclohexyl)-4'-(trans-4-propylcyclohexyl)-biphenyl and
4.5% of 4-cyano-4'-(trans-4-pentylcyclohexyl)-biphenyl has m.p. 0�, c.p. 94�.
A mixture of:
15% of p-(trans-4-propylcyclohexyl)-benzonitrile
27% of trans-1-p-ethylphenyl-4-propylcyclohexane
10% of trans-1-p-ethoxyphenyl-4-propylcyclohexane
7% of 4-cyano-4'-(trans-4-pentylcyclohexyl)-biphenyl
8% of 1,4-bis-(p-trans-4-propylcyclohexylphenyl)butane
10% of 4-(trans-4-pentylcyclohexyl)-4'-(trans-4-propylcyclohexyl)-biphenyl
8% of p-propylphenyl p-(trans-4-propylcyclohexyl)benzoate
6% of p-propylphenyl p-(trans-4-pentylcyclohexyl)benzoate
9% of 4-ethyl-4'-(trans-4-propylcyclohexyl)-biphenyl has m.p. -5�, c.p. 85�.
The preceding examples can be repeated with similar success by substituting the generically or specifically described reactants and/or operating conditions of this invention for those used in the preceding examples. From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention, and without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.
|Cited Patent
|Filing date
|Publication date
|May 8, 1970
|Mar 13, 1973
|Fisons Pharmaceuticals Ltd
|Pharmaceutically active bis-carboxychromone compounds
|Mar 10, 1971
|Jan 22, 1974
|Ethyl Corp
|Preparation of aromatic hydrocarbons
|Oct 26, 1973
|Dec 17, 1974
|Canon Kk
|Binder resins for electron photography and the like and method of productive thereof
|Oct 1, 1973
|Dec 16, 1975
|Rockwell International Corp
|Low melting point disubstituted-p,p'-phenyl cinnamate liquid crystals
|Dec 4, 1974
|Dec 16, 1975
|Hoffmann La Roche
|Liquid crystalline cinnamic acid esters
|Apr 16, 1976
|Jul 12, 1977
|The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland
|Biphenyl derivative compounds and liquid crystal materials and devices containing such compounds
|Oct 21, 1975
|Dec 27, 1977
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Biphenyl esters and liquid crystalline mixtures comprising them
|Aug 2, 1977
|Sep 12, 1978
|The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland
|Liquid crystalline materials
|Oct 25, 1977
|Apr 17, 1979
|Hisamitsu Pharmaceutical Co. Inc.
|Pyridylalkyl esters of 2-(p-isobutylphenyl)acetic acid and propionic acids and use
|Jan 5, 1979
|Oct 21, 1980
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Liquid crystalline cyclohexane derivatives
|May 23, 1979
|Apr 14, 1981
|The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland
|Liquid crystal compounds
|Dec 3, 1980
|Feb 2, 1982
|Timex Corporation
|4-Substituted phenyl 4'-(5-n-alkyl-1,3-dioxan-2-yl)benzoates
|Nov 3, 1980
|Jun 8, 1982
|Eli Lilly And Company
|Synthesis of substituted benzyl esters
|Aug 5, 1980
|Jun 15, 1982
|Hisamitsu Pharmaceutical Co. Inc.
|Phenyl-i-propionic acid esters and pharmaceutical use thereof
|Jan 27, 1981
|Nov 2, 1982
|The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland
|Liquid crystal compounds containing an alicyclic ring and exhibiting a low dielectric anisotropy and liquid crystal materials and devices incorporating such compounds
|Jun 10, 1982
|Jul 12, 1983
|Dainippon Mk & Chemicals Inc.
|1-Cyclohexyl-2-cyclohexylphenylethane derivatives
|Oct 29, 1981
|Aug 23, 1983
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Liquid crystalline cyclohexylphenyl derivatives
|Jan 7, 1982
|Dec 6, 1983
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Liquid crystalline cyclohexylcarbonitrile derivatives
|Jan 6, 1982
|Feb 14, 1984
|Dainippon Ink And Chemicals, Inc.
|Dicyclohexylethane derivatives
|Jan 22, 1982
|Mar 27, 1984
|Hoffmann-La Roche Inc.
|Disubstituted ethanes
|Sep 1, 1982
|Jun 19, 1984
|Dainippon Inc.
|Nematic halogen Compound
|Apr 22, 1976
|Nov 11, 1976
|Secr Defence Brit
|Diphenylderivate und ihre verwendung
|Oct 8, 1982
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|Hoffmann La Roche
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|Jul 28, 1982
|MERCK PATENT GmbH
|Liquid crystal mixture
|Title not available
|Chemical Abstract 93:85211n, (1980).
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|Chemical Abstract vol. 39, pp. 291-296.
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|M. F. Ansell and B. Gadsby, Reduced Cyclic Compounds Part VIII, pp. 2994-2997.
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|Citing Patent
|Filing date
|Publication date
|Jul 11, 1985
|May 17, 1988
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Liquid crystal phase
|Oct 3, 1986
|May 30, 1989
|Merck Patent Gesellschaft Mit Beschrankter Haftung
|Ring compounds
|Sep 29, 1986
|Nov 7, 1989
|Crystaloid Electronics Co.
|Liquid crystalline materials and method of making same
|Sep 25, 1986
|Jun 5, 1990
|Crystaloid Electronics, Inc.
|Liquid crystalline materials and method of making
|Mar 2, 1990
|Jul 16, 1991
|Hoffmann-La Roche Inc.
|3E-cyclohexylalkoxy derivatives
|Jan 22, 1991
|Apr 20, 1993
|Hoffmann-La Roche Inc.
|Liquid crystals
|Dec 30, 1991
|May 11, 1993
|Sharp Kabushiki Kaisha
|Derivatives of α-(4-substituted phenyl)ethyl alcohols and liquid crystal compositions containing the same
|May 2, 1989
|Aug 24, 1993
|Hoffmann-La Roche Inc.
|Ibimethylenoxy containing liquid crystal compounds
|Dec 13, 1993
|Sep 13, 1994
|Hoffmann-La Roche Inc.
|Cyclohexane compounds used in liquid crystalline mixtures
|Jan 4, 1994
|Dec 31, 1996
|Canon Kabushiki Kaisha
|Mesomorphic compound, liquid crystal composition containing same, and liquid crystal device using same
|Dec 16, 1997
|Oct 1, 2002
|Chisso Corporation
|Difluorophenyl derivatives, liquid-crystal compounds, and liquid-crystal composition
|Jun 12, 2012
|Aug 21, 2014
|Merck Patent Gmbh
|Bimesogenic compounds
|Feb 20, 2014
|Aug 21, 2014
|Ofs Fitel, Llc
|Index matched grating inscription
|U.S. Classification
|252/299.6, 558/411, 568/631, 560/64, 585/20, 560/61, 570/131, 560/1, 558/426, 560/59, 560/72, 560/73, 568/665, 568/634, 252/299.67, 568/664, 549/369, 560/106, 570/129, 560/102, 560/62, 558/431, 570/188, 568/626, 560/120, 568/579, 549/375, 252/299.5, 570/130, 560/118, 568/655, 568/642, 252/299.61, 560/107, 560/65, 570/183, 585/25, 570/186, 252/299.64, 560/105, 252/299.66, 549/374, 558/415, 570/127, 568/632, 570/187, 568/669, 585/24, 570/182, 585/21, 549/370, 568/630, 252/299.63, 252/299.65, 568/647
|International Classification
|Cooperative Classification
|European Classification
|Jul 9, 1986
Owner name: SECRETARY OF STATE FOR DEFENCE IN HER BRITANNIC MA
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text:
RTE does not apply to nursery admission: Tharoor
New Delhi: Minister of State for Human Resource Development Shashi Tharoor on Friday said the right to education (RTE) does not apply to nursery admissions.
"The RTE doesn`t apply to nursery admissions as the law specifies eight years of compulsory schooling from the age of six to 14. Nursery children are younger than that," Tharoor said at a programme organised by a private television channel.
"As a social mechanism, a school`s admission policy has to take into account the enormous pressure of applications. The ministry can only help in encouraging a certain policy. But when children get into the six-14 age-group, I assure nobody will be left out. Nursery admissions are a little more complicated and the ministry cannot decide," Tharoor said.
There has been a confusion on whether the right to education applies to nursery admissions as Right to Education Act stipulates that a child between the age group of six to 14 would be covered under the legislation.
The government, through notifications, has allowed unaided private schools to formulate their own criteria for nursery admissions. However, it has been challenged in the Delhi High Court through a petition.
RTE criteria otherwise are applicable to private schools as well.
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SlamBots iOS
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text: Twitter gnews140 GNews140 - Cameron, Carla and David Beckham Sorry, your browser is unable to play this video. Please install Adobe Flash™ and try again. Alternatively upgrade to a modern browser. Ariane Sherine dives back into the Twitterverse for this week's roundup including David Cameron's sliding popularity, fictional Sarkozy affairs and David Beckham's achilles tendon Follow gnews140 on Twitter Ariane Sherine, Matt Hall and Andy Gallagher, theguardian.com Friday 19 March 2010 08.15 EDT Last modified on Friday 6 May 2016 02.53 EDT Share on Facebook Share on Twitter Share via Email Share on Pinterest Share on LinkedIn Share on Google+ Share on WhatsApp Share on Messenger This article is 6 years old Topics Twitter David Cameron Nicolas Sarkozy Carla Bruni-Sarkozy David Beckham Reuse this content


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Bring a buddy.4.54 / 5.00 9,624 Views
Yugi and Kaiba have a duel to the death!4.48 / 5.00 35,165 Views
Vampire Pixel in the Neon City
A sinister deal is underway in the underbelly of Neon City4.34 / 5.00 11,060 Views
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O melhor video que já vi até agora de Amor Anime!
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Tradute if u want
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text:
FRANCE: Pernod board declares dividend
Pernod Ricard's board of directors agreed on 18 December 2003 to pay an interim dividend of € 0.90 per share with a € 0.45 tax credit for retail investors. This interim dividend will be paid on 13 January 2004.
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just wondering if 2.25 tyres would fit on this frame?
Added bike check My custom bmx 8/29/2014 11:14 AM
Added a comment to vinnie.morgan.31's bike check 8/29/2014 11:02 AM
0 0 0
This setup has 1 comment.
just wondering if 2.25 tyres would fit on this frame?
This setup has 1 comment.
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NILES, OH - The Mahoning Valley Scrappers are excited to announce they will be hosting the second annual High School Valley All-Star Classic, presented by Baird Brothers Fine Hardwoods and media partners 21 WFMJ and WBCB, on Saturday, June 14, 2014 at Eastwood Field. The High School Valley All-Star Classic will feature elite high school players from the Mahoning Valley.
Tickets for the High School Valley All-Star Classic will go on sale on March 1st and will be $5 for General Admission Seats. They will be available at the Eastwood Field Box Office, by calling 330-505-0000 or online at www.mvscrappers.com.
The Mahoning Valley Scrappers are the Short Season Single A Affiliate of the Cleveland Indians and play all home games at Eastwood Field. Notable alumni include C.C. Sabathia, Vinnie Pestano, Jason Kipnis, and Victor Martinez. For more information about individual game tickets, ticket packages or group outings visit www.mvscrappers.com or call the front office at (330) 505 - 0000.
Today on MiLB.com
Top Stories on MiLB.com
- Chiefs teammates help save house from fire
- Toolshed Q&A: Dodgers' Knapp discusses Urias
- On the Road: Riggsbee a Bulls mainstay
- Triple-A ballot filled with big names, prospects
- Roundup: Bucs' Kuhl, Phillies' Crawford shine
- Boyd fuels JetHawks rout with nine-RBI night
- Dickerson extends hit streak to 24 on birthday
- Tulsa's Bellinger drills another two homers


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|By Marketwired .
Article Rating:
|June 18, 2014 04:00 AM EDT
LONDON, UNITED KINGDOM -- (Marketwired) -- 06/18/14 --
- New Piksel Digital Signage (DS4) platform integrates digital signage capabilities with existing Online Video Platform (OVP) offering
- End-to-end solution enables organizations to manage and publish content to web, connected devices and fourth screen
- Allows companies to deliver sophisticated, real-time communications to their global employee network
Piksel, a global provider of video monetization software and services, today announced the launch of its Digital Signage platform DS4 in Europe. Piksel's DS4 solution empowers global organizations to deliver information to their workforce instantaneously, including the delivery of corporate news to the connected devices of remote workers.
The rise of remote working has created an unprecedented communications challenge for global companies, who need to be able to share information with their staff in a quick and reliable way. Increasingly, organizations are looking to implement digital signage solutions, which enable them to reach their entire workforce with a unified message. Demand for such systems grew in almost every market segment in Europe in 2013, and a recent report from IHS predicted that the corporate sector will account for 704.7K displays in 2014. In order to meet this increased need for efficient, multimedia internal communications, Piksel has developed DS4, an end-to-end digital signage offering that enables organizations to design, manage, store and broadcast branded multimedia content. Piksel's DS4 can deliver content to a wide range of mediums including digital screens, directional signs, corporate Intranets and remote staff's Android or Windows mobile devices.
The solution is available as a Software-as-a-Service (SaaS) or as an on premise platform. It can be combined with Piksel's Online Video Platform (OVP) to streamline the managing and publishing of media assets. Able to integrate with existing architecture, Piksel's DS4 provides a one-stop platform, which allows the delivery of live, VOD and OVP content to multiple devices. The content creation software embedded in the offering is particularly suited to any company interested in sharing company owned channel content to multiple end points, including the fourth screen.
Mark Christie, Chief Technology Officer, Piksel, commented: "Video is increasingly recognized by internal communications services as a powerful tool, with which they can help employees to be fully involved in their company's corporate culture, even when working remotely. The flexibility of DS4 enables organizations to harness the power of video to deliver targeted corporate content to fragmented workforces, whether on local displays around the offices or on remote workers' mobile devices. The market is primed for a fully integrated solution which can deliver content to every screen, and the launch of our DS4 solution will provide European companies with the ability to make their internal communication resonate with their employee base."
Global businesses have already adopted DS4 as part of their unified communications processes. Piksel's roster of customers includes:
- Airbus - The integration of DS4, combined with Piksel's OVP offering and a video library share within Airbus's infrastructure, enabled the world's leading aircraft manufacturer to place video at the core of its internal communications strategy. Vital content now reaches Airbus' 119,000 strong workforce on every continent, through 500 screens installed in the group's offices worldwide.
- Axa - The world leader in financial services decided to use digital media to inform, motivate and engage its 160,000 employees in real-time. To enable the group to reach this goal, Piksel implemented DS4 to develop a 3D video website tailored for Axa's employees, as well as an internal TV channel broadcasted to the 35 main offices in France. This allowed Axa to distribute customized TV programs locally as well as deliver branded content to 180 screens targeting 120,000 staff.
- Kering - The holding company specializing in apparel and accessories, well known for its Gucci, Alexander McQueen, Stella McCartney and Puma brands, required an end-to-end system to distribute content to the 120 countries it serves. Deploying Piksel's DS4 allowed the company to build its brand within the group by leveraging the power of video. Piksel's DS4 enabled Kering to create a global corporate TV network distributing company news and automatically integrating external information feeds including Reuters news, weather forecast, and more from its Paris headquarters.
Piksel will be demonstrating DS4 at the Internal Communication Conference on June 18th (Museum of London Docklands, London, UK).
Note to editors: If you would like to request a briefing with Piksel at Internal Communications Conference or find out more about the company's solutions, please contact Platform's Catrin Owen: (T) +44 (0)207 486 4900 or [email protected].
About Piksel
We help the world's leading brands maximize their reach and return with video.
Comprised of a global team of experts we call 'Televisionaries,' Piksel has helped to design, build, and manage online video services for major media companies like AT&T, BSkyB, Mediaset, and Sky Deutschland, as well as enterprise brands like Airbus, Barnes & Noble, and Volkswagen.
Headquartered in New York City, Piksel offices can be found throughout Europe and the Americas, serving more than 1,600 clients in over 50 countries.
Follow the company on Twitter at www.twitter.com/piksel
Piksel Media Contact:
Tarley Jordan
Marketing and Communications Manager
E: Email Contact
Platform PR for Piksel:
Matt Steven
Account Executive
E: Email Contact
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