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Bring a buddy.4.51 / 5.00 6,554 Views
Yugi and Kaiba have a duel to the death!4.47 / 5.00 26,190 Views
Vampire Pixel in the Neon City
A sinister deal is underway in the underbelly of Neon City4.39 / 5.00 8,880 Views
F#@king funny... "Pikachu, RIP HIM A NEW ONE!" One thing though, when Ash told Pikachu to unleash god's wrath, Pikachu should have talked in a demonic voice, it would have been cooler. Besides that, great animation!
brave kid. wanna battle? :3 fuck off l:c
Makes ya think what kind of pokemon he had. :3
damn that was too cool
This is a perfect example Why I hate ALL anime cartoons. Especially Naruto. But good job on the flash itself.
There can never be enough pokemon parodies

subset: commoncrawl


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Was £209.00
2 Bed Caravan
- 3 nights
- Fri 10 Jun 2016
- Silver Plus
- Sleeps 6
Park Holidays UK Owners area: Log in | Sign up
UK Holiday Hotline - 0843 178 7070
Good Morning. We are now closed, please call back between the hours of - 9am to 5pm | Call back or Manage my booking
Rye HarbourRye, Sussex
Rye is one of those must-see places that everyone should visit at least once and where better to stay than at Rye harbour Holiday Park - situated alongside Rye Harbour and adjacent to a nature reserve, giving our guests the very best of both worlds.
Please note that Rye Harbour is offering very limited availability for the 2016 holiday season. Should you experience problems searching for dates please call 0843 178 7070 and will we do our very best to help you with your booking.
The family club house provides regular cabaret shows and tours on the weekend throughout the summer and Sky TV is available for those all-important sporting fixtures. The small indoor pool may not be Olympic sized but it's perfect for children and adults who just want to splash about.
Rye town centre is just 2 miles away from the park and we wouldn't be surprised if you spend several days exploring the history and culture of this fascinating town. Did you know that this part of Rye was once under the sea and the land has been claimed back over the years, Good job if you ask us, we really like having such a nice park so close to Rye.
Impress your friends with your combat and dance skills, see who's the fastest on the race track, test your knowledge on the quiz machines or try and win a prize!
Rye Harbour Family Bar; Sit back and unwind in our family bar with Sky TV
Fishing Available; Enjoy a day relaxing by the local fishing lake nearby. NRA licence required, charges may apply.
Free Wi-Fi Internet Access in Club area. Or enjoy personal Wi-Fi access in your holiday home from just £12 per week.
Why not take a dip in our heated Indoor Pool
Mini Mart Store; for your essential shopping needs.
Dining area and takeaway; Book our new FLEXI-DINE dining package and get the most out of your holiday and save £££s too.
Launderette - For all your laundry needs
Award Winning Beach in the area; under 5 miles distance
Dog exercise area; take Rover for a run.
For an additional charge Pets are welcome in selected pet friendly accommodation at this park.
Duration options:
Was £209.00
Was £226.00
Was £271.00
Was £298.00
Was £420.00
FlyBoard, Jet Ski, Waterski, Wakeboard, Stand Up Paddle Board or enjoy a Fun Ride at the South East's Premier Watersports Centre. Action Watersports can offer you a great watersports experience with a huge choice of activities. All equipment is supplied including wetsuits and buoyancy aids so the ability to swim is not essential, many people enjoy the activities without being good swimmers.Visit site
The True CRIME Museum is a SHOCKING new attraction for everyone fascinated by the dark world of crime. Set in 3,000 sq/ft of seafront caves, it is the largest collection of crime memorabilia in the UK and open daily from 10am – 5pm.Suitable for all ages and with wheelchair access throughout, the museum presents a chilling but fascinating insight into the world of Serial Killers, Forensics, Gangsters, Prisoners, Poisoners and more!Visit site
Book now before summer sizzler checks in...We are issuing an early-booking warning to families following a tip-off from weather experts that this summer is likely to be a scorcher.It means holida
Here comes The Sun – and it's free at Park Holidays UK!Free copies of The Sun are being made available to guests at Park Holiday UK this summer, thanks to a link between Britain's brightest parks an
Staff at Chichester Lakeside Holiday Park in Runcton have teamed with members of the local community to create a five-figure windfall for St Wilfrid's Hospice.A total of just over £4,500 was handed t
Park Holidays UK's reputation as the most Fido-friendly place to stay in Britain has been given another boost by its dog-loving customers. In a recent online survey, we asked our thous


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BizQuiz: Is stationary or mobile equine veterinary practice right for you? (Question 8)
Oct 18, 2011
My ideal practice would be…
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May 01, 2016
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Apr 05, 2016


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Back in the old days when everyone drove around in Caddy's as big as your living room, VW camper vans, and giganto station wagons with wood paneling on the side, it was easy to sleep in your car. Today, not so much. Unless you extend the size of your back seat with a Fuloon Car Travel PVC Inflatable Bed. This bed, complete with pump, inflates to fit neatly into most car's back seats:
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PC Games
This page contains Warcraft 3: Reign Of Chaos Hints for PC called "Easy zoom" and has been posted or updated on May 26, 2007 by geeorgiaxx.
Sponsored Links
Boxshot & Details
- Developer: Blizzard Entertainment
- Publisher: Blizzard Entertainment
- Genre: Strategy Real-Time
- Release: Jul 3, 2002
- ESRB: Teen
Easy zoom
You can zoom in to a 3D actual view of the world by scrolling up with your center mouse wheel, then scrolling down to go back to a top view.
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Please Submit a Problem for any incomplete, non-working or fake cheat listed above.
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Killer Pad (2008) Movie Review
When three pals find a sweet deal on a mansion in the Hollywood Hills they think they have struck party gold. But their dreams of sexy Hollywood ladies are quickly thwarted when they realize that their dream pad is also a direct portal to Hell. From a producer of DUDE WHERE'S MY CAR? and directed by Robert Englund of A NIGHTMARE ON ELM STREET.Cast: Daniel Franzese Eric Jungmann Shane McRae Andy MilonakisDirector: Robert EnglundSpecial Features: Commentary with Director Robert EnglundSystem Requirements:Run Time: 85 Mins.Format: DVD MOVIE Genre: HORROR/COMEDIC HORROR Rating: NR UPC: 031398224471 Manufacturer No: 22447
About Killer Pad (2008)
Year: 2008
Starring: Lin Shaye, Daniel Franzese, Sam McMurray, Eric Jungmann, Corri English, Steve Berens, Kaleti Williams, Katie Chonacas, Noureen DeWulf, Emily Baldoni, Joseph Lawrence, Miller Daurey, Rudy Villagrana, Bergen Williams, Haley Hudson, Joey Lawrence, Greg Cipes, Bobbi Sue Luther, Jennifer Lyons, Cristina Nardozzi, Jay Thomas Bavaro, Nicole Nogrady, Héctor Jiménez, Jessica Halloran, Billie Proffitt, Bobby Lee, Ryan Radis, Andy Milonakis, Kristina Romaine, Edward Carnevale
Director: Robert Englund
How Do You Rate These Movies?
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|Pearl Izumi Summit Shorts - Women's
Striking a balance between dedicated trail and cross-country shorts, the Pearl Izumi Women's Summit Shorts let you crush your favorite stretches of trail without soaking up passing showers. Treated with a water-shedding DWR coating, the Summit is a great choice for variable weather patterns often...
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Pearl Izumi was born out of a father's desire to create a cycling kit for his son. Fast forward decades later and the company is one of the most recognized names in the industry. Apparel is still a staple, however, and its line of women's shorts features cuts and details for every rider. For...
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At either end of the spectrum of base layer sleeves, long sleeves are nice -- but only under long-sleeve jerseys -- and sleeveless is versatile but some of us aren't fond of the occasional chaffing and irritation that the cuffs can cause just behind the underarm. The short-sleeve Pearl Izumi men...
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You are here > Home > Baseball Newsstand > Baseball Primer Newsblog > Discussion
Baseball Primer Newsblog
— The Best News Links from the Baseball Newsstand
Monday, October 08, 2012
Primer Dugout (and link of the day) 10-8-2012
New York Evening World, October 8, 1912:
Elsewhere, Grantland Rice writes that this series could go to the limit and require all seven games.
Jefferson Manship (Dan Lee) Posted: October 08, 2012 at 08:34 AM | 13 comment(s) Login to Bookmark
Tags: dugout, history
Reader Comments and Retorts
Statements posted here are those of our readers and do not represent the BaseballThinkFactory. Names are provided by the poster and are not verified. We ask that posters follow our submission policy. Please report any inappropriate comments.1. Jefferson Manship (Dan Lee) Posted: October 08, 2012 at 08:39 AM (#4258954)
No great players on today's Birthday Team, but quite a few good players.2. Eric J can SABER all he wants to Posted: October 08, 2012 at 08:51 AM (#4258956)
C: Ed Kirkpatrick
1B: Olmedo Saenz
2B/Manager: Danny Murtaugh
3B: Enos Cabell
SS: Donie Bush
LF: Ping Bodie
CF: Catfish Metkovich
RF: Wally Moses
SP: Paul Splittorff
SP: Doc Crandall
SP: Johnny Lush
SP: Mike Morgan
SP: Jim Conway
RP: Jerry Reed
Fun Name: Charlie Manlove
Not that one: Bernie Williams
Never trust a man with two first names: Mike Chris
Elsewhere, Grantland Rice writes that this series could go to the limit and require all seven games.3. Jose Remains The Most Absurd Thing on the Site Posted: October 08, 2012 at 09:23 AM (#4258964)
He wasn't dreaming big enough.
Postseason excitement update: Both Wild Card games end up right around the median. The two LDS games on Saturday were a little duller, but not much. And then... yesterday.
Reds-Giants Game 2 is in the bottom 40 all time (out of 1356 postseason and end-of-season playoff games), but the other three were all varying degrees of very good. Yanks-O's was 76th percentile, Nats-Cards was 89th, and A's-Tigers was 95th. In fact, the Oakland-Detroit game grades out as the 5th-best 9-inning postseason game ever, which I find credible enough from having listened to it on Gameday Audio - it didn't let up at any time in the last three innings.
So one of the guys I coach little league with decided he wanted to figure out a way to get kids playing a bit in the fall. We can't get the town to authorize a fall league (yet) but we decided to run some free mini-clinics the next few weeks on fundamentals starting with throwing this past Saturday. Just a one hour thing, invite the kids and walk them through proper warm up and then focus on technique.4. Dag Nabbit at ExactlyAsOld.com Posted: October 08, 2012 at 09:53 AM (#4258979)
He sends out the e-mail, gets 6 or 7 of us coaches to help out and we got about 35-40 kids which was a pretty good turnout on a Saturday afternoon with football and soccer. The funny part though was an email that one of the kids' grandfather sent us beforehand. You'd think the response would be "hey, thanks for giving up your time and working with my kid" would be the default position (and it was in pretty much every other case) but there is one in every crowd. This guy goes into a big long thing about what our qualifications are and how Bobby Feller (he called him Bobby), Tom Seaver and Nolan Ryan had great mechanics and kids today don't throw like that and what gave us the right to teach the kids.
Fortunately the guy running the thing is more diplomatic than I am and simply explained that his qualifications were quite good for the price (free!) and if he was working with his grandson that was great but a lot of kids don't work with their parents on this stuff.
As noted up at THT, today is 15,000 days since Cleveland's walk-a-thon where they walk more batters in one game by any team since at least 1918. To be fair, it was a 20 inning game.5. Eric J can SABER all he wants to Posted: October 08, 2012 at 10:09 AM (#4258990)
Also, I have an article up at THT on 2012's most exciting and incredible games. I did my own version of daily game tracking in 2012, noting things like comebacks, late drama and so forth, and so here is your chance to find out things like the only game to feature multiple comebacks in extra innings, or the games with the most lead changes, or the only games to feature both teams coming from behind in the ninth to take the lead. And so on. The article worked better than I expected it to.
the only game to feature multiple comebacks in extra innings6. Eric J can SABER all he wants to Posted: October 08, 2012 at 10:30 AM (#4259002)
You missed one of these.
Still a fun article, though, and I say that as someone who was already familiar with quite a few of these games.
Edit: Best thing about the Nats-Mets game linked above is the fact that Ian Desmond came up three times in the eighth inning or later with his team down by a run, and produced the tying run each time (RBI single in the eighth, run-scoring ROE in the tenth, RBI double in the twelfth). That's a WPA of .990; I'd be surprised if any hitter beat that in a game this year. And of course, because Bryce Harper got the walkoff hit, nobody noticed Desmond.
For comparison's sake, my system puts the best day of the year smack in between Dag's top two: May 4, featuring four games of at least 11 innings, two of which had final scores of 9-8, five other one-run games in regulation, and no real blowouts (largest margin of victory was 5). 11 of the 15 games were 60th percentile or better, and all four extra-inning contests make the top 100 for the year; no other day has more than three of those (7/22 and 8/5).7. Eric J can SABER all he wants to Posted: October 08, 2012 at 10:44 AM (#4259017)
Also for comparison's sake, on the team rankings: Dag's #1 team (the Brewers) are my #2, and we agree on the Braves as least-exciting. But I have the Royals on top of the list, and he has them ranked 23rd; that puts them behind, among other teams, the Angels, who I have in the #29 spot.8. RB in NYC (Now Semi-Retired from BBTF) Posted: October 08, 2012 at 10:54 AM (#4259023)
Fortunately the guy running the thing is more diplomatic than I am and simply explained that his qualifications were quite good for the price (free!) and if he was working with his grandson that was great but a lot of kids don't work with their parents on this stuff.Wow. That guy is more diplomatic than I would be, I would've told maybe I wasn't Leo Mazzone for teaching mechanics, but I could perfectly illustrate how he could kiss my ass.
Was there ever a time with Primer Dugout when the article linked was actually discussed?10. Der-K convinces people that Hot Pockets are pies. Posted: October 08, 2012 at 11:38 AM (#4259074)
Sure, lots of times.11. kthejoker Posted: October 08, 2012 at 01:18 PM (#4259194)
Finally watched Buster Keaton's The Cameraman yesterday, which features him pantomiming as a pitcher and hitter-runner at Yankee Stadium.12. Eric L Posted: October 08, 2012 at 02:24 PM (#4259250)
In it, He runs the bases in 16.3 seconds
1) in a suit,
2) throwing in a little prance around second for entertainment value,
3) and sliding into home.
Dude was pretty fast.
Great article on Keaton's love of baseball by Rob Edelman.
A day in the life of an older bb fan: I wrote a check today and dated it 10/8/56 ... nuff said.13. AndrewJ Posted: October 08, 2012 at 09:08 PM (#4259823)
A day in the life of an older bb fan: I wrote a check today and dated it 10/8/56 ... nuff said.
Did the bank teller leap into your arms?
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College News
Student Athlete Advisory Committee Joins Empire 8 for Breast Cancer Awareness
The St. John Fisher College Student Athlete Advisory Committee (SAAC) is coming together with other Empire 8 schools to raise awareness for breast cancer in honor of an alumna who recently beat the disease.
The SAAC will spread the awareness at two athletic events on Saturday, October 20. Student athletes will be selling pink ribbons at Saturday's men's soccer game against Stevens Institute of Technology at noon and the football game against Ithaca College at 4:00 p.m. Two coaches have also volunteered to take a pie-in-the-face for the cause. Sean Coffey, assistant men's basketball coach, and Kerri Brown, assistant women's lacrosse coach, will be waiting for pies in their faces during halftime of each game. Participants should bring $5.00 and a good throwing arm.
The money raised during the event will go to the American Cancer Society in honor of Rochelle Meinking, a former Fisher women's basketball player who has recently battled the disease. She is now in remission.
The Empire 8 Breast Cancer Awareness Initiative is being embraced by the Empire 8 schools throughout the month of October with a variety of events and fundraisers.
Check out photos from Commencement 2016 on Flickr!
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BYU football: 10 players to buy stock in
PROVO — BYU's media day last month brought with it the typical buzz associated with the team and its prospects for the coming season. The team returns a lot of veteran players who are likely due for improvement along with some up-and-comers, who were talked about with optimism by both coaches and players.
So which players seem to have created the most buzz with their offseason workouts and otherwise?
Here's a look at 10 such players who would be smart stock buys for those looking for some quick gains heading into the 2014 football season.
- Oldest first
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Out of all these players, I really hope Zac Stout has a breakout season. It
would be awesome to see him work back to where he plays and succeeds on this
I think Manoa is the most likely to have a breakout year. BYU's defense is designed to let the middle LB's be tackling machines, and they have delivered for years. We keep on cranking them out. In my opinion, Manoa has the talent of Uani Unga with the motor and insanity of Brandon Ogletree. Hopefully, he will add the leadership abilities of Cameron Jensen.
Watch out for Trevor Bateman. He could be a dark horse. Many players and coaches have mentioned how good he was in spring, and speed is the word that always comes up. I know the secondary is very deep. I'm not saying he will start or even play a ton, but watch for him to be impressive when he comes in.
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Oh, please college football season come quick - I can hardly wait!. I think this is going to be a fantastic year for the Cougars. Looking forward to some exiting games and that feeling that comes from winning lots of ball games. Go Cougs!
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Janes, Julius French; pres. and gen'l mgr. Standard Steel Castings Co.; born, Erie, Pa., Sept. 24, 1877; son of Herman and Julia (Williams) Janes; educated, Brooks Military Academy, University School, Phillips Andover Academy, Andover, Mass.; graduated from Yale in 1902; married, Nov. 11, 1904, Ruth Hawkins; issue, one son, Julius French; in sales dept. the Bourne-Fuller Co., three years; salesman with Morgan Lithograph Co.; appointed to joint management of sales dept. and treasurer in 1908; established Standard Steel Castings Co., 1912; member Calvary Presbyterian Church, Hermit and Euclid Clubs. Recreations: Golf, Tennis, Fishing and Motoring.
Biographical Sketch of Julius French Janes
MLA Source Citation:The Book of Clevelanders: A Biographical Dictionary of Living Men of the City of Cleveland. Burrows Book Company. 1914. AccessGenealogy.com. Web. 25 May 2016.
https://www.accessgenealogy.com/ohio/biographical-sketch-of-julius-french-janes.htm- Last updated on Mar 6th, 2012
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When a mysterious relic is stolen from a Madrid museum, people are dying to discover its secrets. Literally. U.S. Treasury agent Alexandra LaDuca returns from Conspiracy in Kiev to track down the stolen artwork, a small carving called The Pietà of Malta. It seems to be a simple assignment, but nothing about this job is simple, as the mysteries and legends surrounding the relic become increasingly complex with claims of supernatural power. As aggressive, relentless, and stubborn as ever, Alex crisscrosses Europe through a web of intrigue, danger, and betrayal, joined by a polished, mysterious new partner. With echoes of classic detective and suspense fiction from The Maltese Falcon to The Da Vinci Code, Midnight in Madrid takes the reader on a nonstop spellbinding chase through a modern world of terrorists, art thieves, and cold-blooded killers.
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10 Ugandan civil society organisations urge the government of Uganda to conduct swift and transparent investigations the recent wave of office break-ins targeting human rights organisations and take steps to put an end to the practice.
Uganda: Government should immediately take steps to end pattern of office break-ins
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Product Information for Tripp Lite Lite SVGA Extension Gold Cable w/RGB Coax
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Marketing InformationTripp Lite's 100 foot SVGA/VGA monitor extension cable is the gold standard in video cables. The mini-coax (RGB) and paired video wire construction delivers superior signal quality. Gold plated connectors and gold plated copper contacts ensure excellent conductivity. Double shielding (foil and braid) provides maximum EMI/RFI protection. Both the high density DB15 male and high density DB15 female connectors are molded and have integral strain relief to ensure they last a long time. Tripp Lite warrants this product to be free from defects in materials and workmanship for life.
General Information
Technical Information
Physical Characteristics
Additional Information
Package Contents100-ft. SVGA/VGA Monitor Extension Cable HD15M to HD15F Gold Connectors w/ RGB Coax
System RequirementsMonitor with HD15 cable


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No Twinks Zone - Scene 5
Get Your Gay Access Now!
DVD Title No Twinks Zone
Category Muscle
Added August 29, 2013
Viewed 8,346 times
Favored 16 times Add to favorites
Duration 20m, 41s
Tags Anal Sex, Blowjobs, Cum on Stomach, Hardcore
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An exotic looking white guy with bleached white hair that stands up on end gets fucked by a more conservative looking brunette man in this hardcore clip. The guy with spiky hair is quite clearly the more submissive and eager cocksucker of the two, getting down on his knees straight away and taking his friend cock and balls in his mouth. Then he bends over, pulling his ass cheeks apart and offering up his tight sphincter for penetration. The older brunette man needs no encouragement, ramming his thick cock into his friends tight ass and beginning to plow him. You've got to hear this twink yelp as he gets reamed in his butthole - it so hot!
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No Twinks Zone
August 29 2013
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2017 Colorado Motorcycle Expo canceled
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text:
|Publication number
|Publication type
|Application number
|Publication date
|Oct 6, 2009
|Filing date
|Jan 5, 2005
|Priority date
|Jan 5, 2005
|Fee status
|Publication number
|Yuk Chan, Terrill B. Atwater
|Original Assignee
|The United States Of America As Represented By The Secretary Of The Army
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (5), Referenced by (2), Classifications (21), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
The invention described herein may be manufactured, used, imported, sold, and licensed by or for the Government of the United States of America without the payment of any royalty thereon or there for.
1. Field of the Invention
The present invention relates generally to electrochemical power sources and, more particularly, to metal-air batteries.
2. Related Art
Metal-air batteries may provide a very desirable power source for many small portable electronic devices. For example, lithium-air batteries may have a relatively large specific capacity of 3,861 Ah/kg and energy density of 13 kW-h/kg while also having relatively small spatial requirements. However, a problem that arises in the use of metal-air batteries involves, e.g., the non-compatibility of the metal with the moisture in the air. In particular, lithium may be oxidized violently in the presence of the moisture or water whereby safety concerns may be raised.
Currently, no suitable means of substantially reducing the effects of moisture in metal-air batteries is available.
In accordance with an embodiment of the present invention, an anode for a metal-air battery comprises an electrode and a metal foil interconnected with the electrode. A barrier layer surrounds the metal foil and comprises a polymer blend that substantially reduces the passage of moisture therethrough while permitting the passage of ions therethrough.
In another embodiment of the present invention, a method of making an anode, comprises preparing a barrier layer, comprising hydrolyzing polyvinylidene fluoride (pVdF) in an alkali-hydroxide solution to form a mixture; separating hydrolyzed pVdF from the pVdF and the alkali-hydroxide solution; dissolving hydrolyzed pVdF, polyethylene oxide (PEO) and lithium hexafluorophosphate in a solvent; and removing the solvent to thereby leave a polymer blend for use as a barrier layer; thereafter, providing a metal foil; and surrounding the metal foil with the barrier layer.
The following detailed description is made with reference to the accompanying drawings, in which:
The FIGURE is an exploded view of an anode in accordance with an embodiment of the present invention.
One embodiment of the present invention concerns an anode for a metal-air battery that is configured to reduce a reaction between the anode, which comprises a lithium metal sheet, and moisture in the air. In one particular embodiment of the invention, a barrier layer is provided that surrounds the metal sheet and functions to substantially reduce passage of moisture while permitting the passage of oxygen and lithium ions therethrough. The barrier layer may comprise a modified polyvinylidene fluoride and a polyethylene oxide blend.
Referring now to the exploded view of the FIGURE, an anode that is in accordance with one embodiment of the present invention is illustrated generally at 10. In this embodiment, the anode 10 comprises a terminal 12, a wire-mesh layer 14, a metal foil 16, and barrier layers 18. The terminal 12 may comprise a conductive substance such as nickel and may be configured in any geometric shape that is suitable for mating with a device (not shown) to be energized. The wire-mesh layer 14 may also comprise nickel and is configured to provide enhanced electrical contact across a surface (not numbered) of the metal foil 16. The metal foil 16 may comprise lithium and may be approximately 0.006 inch in thickness.
In accordance with a feature of the present invention, the barrier layers 18 are provided for substantially reducing contact between the metal foil 16 and moisture in the air. The barrier layers 18 may be joined together, during fabrication of the anode 10, to surround and cover the metal foil 16. It will be understood that while multiple barrier layers 18 are shown, these layers are referred to herein for illustrative purposes and instead of multiple barrier layers, a coating or encapsulating material may be employed to cover the metal foil 16.
As exemplified below, it has been found that the barrier layers 18 may comprise a polymer blend of polyvinylidene fluoride and polyethylene oxide. Also, an alkali-hydroxide solution may be employed in order to modify the chemical and physical characteristics of polyvinylidene fluoride prior to blending with the polyethylene oxide. Further, lithium hexafluorophosphate may be combined with the polymer blend of polyvinylidene fluoride and polyethylene oxide in order to conduct ions from the cathode and anode current collectors. Preferably, each barrier layer 18 comprises polyvinylidene fluoride that is greater than approximately 75 percent by weight and more preferably ranges between approximately 75 percent and 80 percent by weight. Polyethylene oxide preferably ranges between approximately 10 percent and 15 percent by weight and lithium hexafluorophosphate preferably ranges between approximately 10 percent and 15 percent by weight.
It is believed that during operation of the anode 10, the barrier layers 18 allow passage of lithium and oxygen ions in order to facilitate the oxidation and reduction reactions necessary for generation of electrical power. Lithium is oxidized to lithium carbonate and lithium oxide within the barrier.
In accordance with another feature of the present invention, a method of making a barrier layer 18 comprises reacting polyvinylidene fluoride (pVdF) in an excess lithium hydroxide solution. The reaction is continued until a dark brown paste settles to the bottom that may be 90% by weight efficient of initial pVdF. After centrifuging, the brown paste may be removed, rinsed with distilled water and then dried. The dried brown paste, comprising lithiated or hydrolyzed pVdF, may then be formed into a solid polymer blend film that may be used as a barrier layer.
In one particular embodiment, the polymer blend or barrier layer may be prepared by dissolving hydrolyzed pVdF in 1-methyl-2-pyrrolidione (nMP) and then adding polyethylene oxide (PEO) and lithium hexafluorophosphate to form a polymer blend mixture. The polymer blend mixture may then be heated until all three components are dissolved. The mixture may then be allowed to cool to room temperature and formed into a thin layer by coating onto a flat sheet of Teflon or glass.
An anode 10 may then be prepared by pressing together a metal foil, e.g., comprising lithium, with a wire-mesh, e.g., comprising nickel, and then removing excess nickel. A pair of barrier layers, previously prepared of hydrolyzed pVdF/PEO as described above, may then be located on opposing sides of the lithium foil and then pressed together under, e.g., 5000 pounds per square inch of pressure.
A polyvinylidene fluoride (pVdF) was obtained from the Polyscience Corporation of Warrington, Pa. and Lithium hydroxide, a 98% solution, was obtained from Alfa Aesar Corporation of Ward Hill, Mass. Five grams of pVdF was placed into a 50 mL centrifuge tube. Thereafter, a three molar solution of lithium hydroxide was poured into the centrifuge tube until it reached the 50 mL line. The mixture was shaken and left for at least 24 hours. After 24 hours, the mixture turned from a white color to a pinkish color. More solid lithium hydroxide was put into the mixture to increase the degree of reaction. The mixture was shaken and left alone for another 24 hours. This process was repeated until a dark brown paste settled to the bottom of the centrifuge tube. At this point, the mixture was placed in a centrifuge for 10 minutes at 8000 rpm to separate the brown paste from the pinkish pVdF that floated on the top of the mixture. The brown paste was then removed and placed into an extraction thimble used in a Soxhlet apparatus. Distilled water was used to wash the brown paste of any traces of lithium hydroxide (thirty to forty washes). After the brown paste was removed, it was put into a vacuum dryer for about 24 hours at 100� C. The brown paste, now a powder, lithiated pVdF, was removed.
A polymer blend was prepared by dissolving 3.058 g of hydrolyzed pVdF in 1-methyl-2-pyrrolidione (nMP). After the hydrolyzed pVdF dissolved, 0.410 g of polyethylene oxide (PEO), with an average molecular weight of 100K, obtained from the Aldrich Corporation of Milwaukee, Wis., and 0.450 g lithium hexafluorophosphate was added to the dissolved hydrolyzed pVdF solution. Altogether, the hydrolyzed pVdF comprised a weight percent of 78%, PEO comprised a weight percent of 10.5% and lithium hexafluorophosphate comprised a weight percent of 11.5%. The mixture was then heated until all three components were dissolved in nMP. The mixture was then cooled to room temperature and then applied, at a thickness of 0.002 inches, to a clean glass-plate using a coating bar to form a barrier layer. The barrier layer or film was dried at 50� C. until the liquid evaporated and then placed into a vacuum oven for 24 hours at 50� C.
Lithium foil was obtained from the Foote Corporation of Exton, Pa. with a thickness of 0.006 inches for use as an anode. In a dry room, a press available from the Carver Corporation of Wabash, Ind. was employed to press, under 12 tons of pressure, the lithium foil onto a nickel wire-mesh. Excess nickel was removed from the edges of the lithium foil. The polymer blend of hydrolyzed pVdF/PEO or barrier layer was then disposed about the lithium foil and wire-mesh and pressed under 12 tons of pressure. Excess polymer blend was then removed.
The anode was then brought out of the dry room to expose it to ambient humidity. After several weeks, no deterioration of the quality of lithium metal was observed.
An anode was prepared according to Example I excepting that a barrier layer to protect a lithium foil instead comprised, in weight percent, 81% modified pVdF, 9% PEO and 10% lithium hexafluorophosphate. The lithium foil had a weight of 0.0214 g an area of 3.27 cm2.
An anode was prepared according to Example I excepting that a barrier layer to protect a lithium foil instead comprised, in weight percent, 78% modified pVdF, 10% PEO and 12% lithium hexafluorophosphate. The lithium foil had a weight of 0.0227 g an area of 3.17 cm2.
Each of the anodes from the above examples and others, not described herein, was observed for deterioration of the lithium metal foil after exposure to ambient humidity for several weeks. It was found that the polymer blends that were the most successful had a ratio of hydrolyzed pVdF of greater than 75% by weight. The polymer film was pliable and stable.
While the present invention has been described in connection with what are presently considered to be the most practical and preferred embodiments, it is to be understood that the present invention is not limited to these herein disclosed embodiments. Rather, the present invention is intended to cover all of the various modifications and equivalent arrangements included within the spirit and scope of the appended claims.
|Cited Patent
|Filing date
|Publication date
|Sep 20, 1993
|Sep 20, 1994
|Duracell Inc.
|Process for producing manganese dioxide
|Jan 31, 1997
|Jan 6, 1998
|Kejha; Joseph B.
|Polymer alloy electrolytes for electrochemical devices
|Jun 22, 2000
|Dec 10, 2002
|The Gillette Company
|Metal-air battery
|Mar 31, 2003
|Jan 15, 2008
|Sony Corporation
|Feb 3, 2005
|Aug 4, 2005
|Guiping Zhang
|Modified lithium ion polymer battery
|Citing Patent
|Filing date
|Publication date
|Jun 19, 2012
|Sep 17, 2013
|ZAF Energy Systems, Incorporated
|Metal-air battery and gas impermeable anodic conductive matrix
|Aug 16, 2013
|Aug 4, 2015
|ZAF Energy Systems, Incorporated
|Metal-air battery and gas impermeable anodic conductive matrix
|U.S. Classification
|429/231.95, 429/131, 429/144, 429/209, 429/129
|International Classification
|Cooperative Classification
|European Classification
|Aug 27, 2009
Owner name: ARMY, THE UNITED STATES OF AMERICA AS REPRESENTED
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CHAN, YUK;ATWATER, TERRILL B.;REEL/FRAME:023153/0248
Effective date: 20050104
|Sep 28, 2010
|Certificate of correction
|May 17, 2013
|Maintenance fee reminder mailed
|Oct 6, 2013
|Lapse for failure to pay maintenance fees
|Nov 26, 2013
|Expired due to failure to pay maintenance fee
Effective date: 20131006


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Op-Ed: 'Greenwashing' - consumers still bombarded with fake green goods
Paul Wallis
Dec 6, 2009 in
Hype continues to rule the shelves. Pseudo Green remains the color of choice among the corporate world's marketing geniuses. Nearly 20 years after the word greenwashing was invented, it's still a basic fact of abuse of consumer rights.
Greenwashing remains a major issue for consumers, despite much ongoing publicity including
TIME Magazine's September 2009 cover story
and a lot of case studies.
It's not the first time DJ has covered this issue, either. We've done
several pieces
over the last year or so, about the various levels of total breakdown of consumer rights. The fact is that consumers have no idea what they're buying in real terms. Nor do they have much chance of finding out.
Greenwashing is a fully established fact. Consumers, as usual, are taking the brunt of lazy corporations who don't even understand green technology or concepts, but will use them in their marketing. Around the world, words like "natural" , "ecologically friendly" and "biodegradable" are common, and commonly incorrect.
Meaningless words also mean nobody pays a lot of attention to things like required information on packaging for food. The feelgood approach to buying food is a prime marketing technique, and the mere fact of buying a few kg. of preservatives, food coloring, cellulose and sugars may not be the main area of concern.
That's very relevant in marketing of foods, where not only the values of the actual content can be blurred, but consumers can remain sublimely unaware of any hazards. Greenwashing is a real end-user part of the problem, but there are still some other serious problems. Public awareness campaigners might also like to take note of the fact that there's some unfinished business in food labeling, too.
Toxic products don't become less toxic because they're labeled green or anything else. The big green sales points and the small black list of toxins are a common method of obscuring dietary issues. Most people can't read food labeling, largely because of the 2 point fonts and the obscure technical language. Some common preservatives are considered toxic by everyone
the food industry. Sodium nitrite, aka 250, is a case in point. Calling that stuff green is like calling death an alternative lifestyle.
It's in the industrial zone, however, where misrepresentation is the standard sales routine. Pinning down the exact amount of recycled paper in kitchen wipes, for example, is practically impossible, unless there's an obligation for accuracy on the manufacturer. There are almost none, globally, except in Europe and California.
Something called "Gaia Wipes" may well contain fewer Asian outworkers per metre or have dolphins making nests out of them, but you could be buying anything. The cleaner may be ecologically friendly on Mars, but not necessarily on Earth.
In the macro economy, where greenwashing first became a term in 1990, this is widespread practice. The pretense of being green is a lot cheaper and easier on the tiny brains than the practice. Greenpeace created a sub-group operation called
to deal with the problem, and it did at least create a public profile for the more absurd claims of green-ness from the major polluters. The current relatively high level of sensitivity of major corporations is based on that very negative profiling.
That mechanism is notably lacking in consumer level economics. The only working laws are misrepresentation and false advertising. Unless you happen to have a chemical analysis lab and a lawyer familiar with the arguments, it's not easy to prove much.
These areas are actual offenses under commercial law, not environmental or consumer law. Consumer law is becoming more dated by the day as new products come on the market. Food is covered by an interestingly vague series of descriptions depending on where you live. Some would say that consumer protection has gone backwards faster in the food industry than anywhere else. In some cases a thing can be called "organic" if it's not actually made of plastic, in others the definitions have been re-smudged by qualifiers and tack-on regulations.
Therein lies a tale. According to TIME Magazine's article, the value of organic products went up by 100% in the years 2005-7. Apparently the obsessive corporate sales freak show, The Masters of Ignorance, by definition completely unaware of any ramifications of any action, went on the gravy train and simply labeled everything it could organic. That 100% equated to $10 billion in extra sales during the period.
There's no lack of information, but a definite lack of motive force in getting change moving. If you check greenwashing online, you'll get lots of hits.
has an interesting greenwashing site which maintains a current news service regarding offenders and issues.
The moral of the story is that being green isn't getting any easier. Nor are governments noticeably paying a lot of attention. Unless there's law, there are no laws. Greenwashing will be here to stay unless some case law, and preferably class actions, which get more leverage in statute law, start happening where they get noticed.
This opinion article was written by an independent writer. The opinions and views expressed herein are those of the author and are not necessarily intended to reflect those of DigitalJournal.com
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With oil prices well above $100 a barrel, investing in big oil is an obvious choice. Higher crude prices help major oil companies deliver healthier profits, and in turn, drive up their stocks.
"The major integrated oil companies are the safest way to play energy markets," said Bob Carey, chief investment officer at First Trust Advisors. "They are involved in every aspect of oil production, delivery and exploration, and have proven their ability to consistently grow earnings and dividends over time."
Rather than investing in individual stocks, experts recommend broad exposure through the Energy Select Sector SPDR ETF (XLE), which rose more than 6% last month. The fund's top holdings are industry leaders like Exxon Mobil (XOM), Chevron (CVX) and ConocoPhillips (COP).
While major oil companies are typically a safe bet, they could be in trouble if Iran follows through on its threat to shut down access to the Strait of Hormuz, warned Colin Moore, chief investment officer at Columbia Management.
"If something traumatic in the Middle East were to cause an enormous spike in commodity prices, shares of oil and gas companies would fall because the worries about how something like that would impact the global economy would outweigh the benefits," said Moore, who also manages the Columbia Energy & Natural Resources fund (CERIX).
Iran, demand, speculators and potential problems at refineries are all responsible for the nearly 50 cent rise in gas prices over the last two months.
|Zurich Insurance's ex-CEO Martin Senn commits suicide
|How young millionaires are growing their money
|Huge breakthrough in blazing fast internet speeds
|Unstereotyped: Why this black pastor supports Donald Trump
|Lufthansa to halt flights to Venezuela


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- A head-to-head comparison of the ARM Cortex-M4 and –M0 processor cores by Jack Ganssle
- Scaling the peaks to look at the 14nm cliff, Part 2: Tom Beckley from Cadence explains how we're getting to 20nm and then on to 14nm and 10nm
- Freescale starts sampling $0.49 Kinetis L microcontrollers based on ARM Cortex-M0+ processor core
- Scaling the 20nm peaks to look at the 14nm cliff, Part 1: Tom Beckley from Cadence maps the challenges of advanced node design at ISQED
- Want a peek at a possible Qualcomm 3D IC roadmap?
- You say you want a revolution? The Computer History Museum reopens after $19M of polishing. Thank you Bill Gates.
- How about a quick and easy guide to ARM Cortex processor cores? Got one for you from ARM TechCon 2011
- Collaboration is key to making DFM work at 28nm and below
- Ingenious architectural features allow ST to extract maximum performance from new microcontroller family based on ARM Cortex-M4. Cost: less than 6 bucks in 1000s
- 3D Thursday: A funny thing happened to me on the EDPS 3D-IC panel
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Tag Archives: Avengers
Friday Video: Quadcopter version of flying aircraft carrier from Avengers movie
One of the silliest high-concept ideas in the Avengers movie has to be the flying aircraft carrier operated by super-secret agency S.H.I.E.L.D. Well, it's from the comic books, right? Then why does it come as no surprise that someone has … Continue reading
Posted in EDA360 Tagged Avengers, Comic book, Helicarrier, Quadrotor, Russia, S.H.I.E.L.D., Scale model Leave a comment