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The "Fun in the Sun" event will be held at Lake Eufaula at Checotah. We will be in the Pavilion in the middle of Deep Fork Campground. This is a PPA Continuing Education Event. PPA members will earn a CE Merit for attending.
Tony Corbell will be presenting a variety of light demonstrations to address various types of natural lighting situations you might encounter.
The pre-registration cost is only $30.00 for each individual wanting a merit or $40.00 for a couple or family. You may register on site that morning but individual members will be $35.00 and couples or families will be $45.00.
Lunch is included with your registration.
Join us as Tony show you how to photograph outdoors in various kinds of lighting conditions.
This is an all day event not only for photographers but also a retreat for the entire family. Arrive on Saturday and camp out at the state park for a fun evening. Plain camp sites are available on a "first come, first serve" basis. There are also RV or camper sites with water & electric hookups. You can reserve a site online at https://www.gocampok.com/campground/app/index.php
The annual PPOK Convention, Print Competition and Expo will be held at the Tulsa Downtown Hyatt Regency Hotel located at 100 East 2nd St. (918) 582-9000
We have a special hotel room rate of only $99.00 a night. The group rate deadline is September 7th. Do not let the hotel deadline expire as I am sure they will not extend this deadline. Call them at (918) 582-9000 to make your reservation.
Register Online
Print and Mail Registration
View a Detailed Schedule
Enter Print Competition
Register before Midnight, September 26th to take advantage of the pre-event discounts for registration. After that time, you can only register on site at a higher price.
Details regarding this event and the featured speakers will be announced at a later date.

subset: commoncrawl


text:
The man with 99 lives: He's narrowly escaped three plane crashes and two IRA bombs. So is 'Captain Catastrophe' the luckiest man in Britain?
- Ian Fordrey, 52, sailed on the Herald of Free Enterprise - just before it sank
- He visited a building in Docklands hours before IRA blew it up killing two
- His flying instructor and another pupil died soon after he left the plane
- He's going to Sharm El Sheikh in July. Be afraid, be very afraid
Back in 1987, Ian Fordrey was travelling to Belgium by ferry with colleagues.
Enjoying a drink in the bar, 6ft 4in Ian was telling a story when he raised his hands in the air.
His fingers grazed a ceiling tile which disintegrated at his touch.
Captain Catastrophe: Wherever this man goes, death and disaster follows in his wake. Ian Fordrey is a one-man walking calamity
'I remember saying, "Blimey, this isn't very well built. The place is falling apart",' says 52-year-old Ian, a driving instructor from southwest London. But he thought nothing more of it until a month later.
'I was at home and a news flash came on the television. A ferry had capsized, killing 193 passengers and crew. It was the ferry I'd been on: The Herald Of Free Enterprise.
'I got a cold shiver,' he says. 'I didn't know what to think, except that this was getting spooky.'
Spooky indeed.
For while it's the sort of anecdote that most would dismiss as mere coincidence, it was by no means Ian's first close call and it certainly wasn't his last.
The Herald of Free Enterprise sank killing killing 193 passengers and crew. Captain Catastrophe had sailed on it shortly before it sank
Dubbed 'Captain Catastrophe' by his friends, Ian is the kind of man who drives through a town only to have it go up in flames the moment he leaves.
He's someone who picks a restaurant for lunch and watches it explode before his eyes.
He's dodged three train crashes, three plane crashes, two IRA bombs and four major fires.
'I don't know if I'm the luckiest man, or the unluckiest,' says Ian. 'Disaster has followed me all my life. Every time something happens, I think "Blimey, not again". It's relentless. It's getting to the point where people say Hail Mary and do Signs of the Cross every time I walk into the pub,' he jokes.
His lucky unlucky streak started as a child.
On a school trip to Aviemore in Scotland, aged 11, Ian and his schoolmates arrived at their destination only to find they'd been left dozens of phone messages from worried parents.
The train directly after theirs had crashed.
A year later, on a school trip to Switzerland the same thing happened — the train behind them crashed in the tunnel.
'If I'd have known how things were going to play out, I'd have gone straight to church and doused myself in holy water,' he says.
Since then Ian seems to have been on a mission to prove that, far from having the proverbial nine lives, he has 99.
In 1992, Mr Fordrey had lunch with his ex-wife and a friend at the Sussex Tavern, in London¿s Covent Garden. The following lunchtime the IRA blew it up, killing one person and injuring five others
In 1992, he had lunch with his ex-wife and a friend at the Sussex Tavern, in London's Covent Garden. The following lunchtime the IRA blew it up, killing one person and injuring five others.
Three years later, in 1995, Ian was having flying lessons at Biggin Hill. The day after his lesson he opened the paper to see his instructor and another pupil had been killed — in the same plane he'd flown in.
There had been complete engine failure, just one hour after he'd climbed out of the aircraft.
This isn't the only close call Ian has had in the skies.
Travelling to South Africa the plane he was flying in narrowly missed landing on top of another plane, which had received erroneous information from air control; while above Denmark he flew so close to another aircraft that it skimmed the plane's wing.
The year after his close call at Biggin Hill, he was working for a motorcycle courier company delivering a package to a company in London's Docklands before going home.
The scene after an IRA bomb explosion at South Quay in Docklands. Captain Catastrophe missed that bomb by about 20 minutes
By the time he got home an IRA bomb had destroyed the very same building he delivered the parcel to, killing two and causing £100 million worth of damage.
'I missed that bomb by about 20 minutes — the same thing happened with the Vauxhall helicopter crash (in January last year a helicopter collided with the jib of a construction crane, killing the pilot and one pedestrian). I'd been right there ten minutes earlier. It makes you think,' he says with masterful understatement.
But what on earth does it make him think?
The litany of disasters which have dogged Ian read like a Hollywood film script.
How does he get his head around the fact that death follows him everywhere?
'Sometimes I feel as if somebody's trying to get me — I might have been Attila the Hun in another life,' he jokes.
'I don't know if it's bad karma that so much stuff happens around me, or good karma that's keeping me alive.
'If I was of a more paranoid nature I'd lock myself up in a little shed and promise not to come out until the second coming. I'm not religious at all, but maybe I should be…'
He says he relies on black humour to get him through, but that he feels a level of responsibility for the accidents which follow in his wake.
'Every time I'm close to another disaster I honestly think: "If I'd stayed at home would this have happened?" he says.
Investigators work at the scene of a helicopter crash in Vauxhall, central London. A helicopter crashed into a crane on top of one of Europe's tallest residential blocks killing two people as it burst into flames
'I wish it was funny and slapstick but there's real tragedy and I feel bad and think about it a lot, but what can you do?'
Indeed, if he'd stayed at home, perhaps the Megaro restaurant in Elounda, Crete, would still be standing.
Ian and his then-wife were visiting the town in 2006 and were looking for a spot of lunch when they happened upon the Megaro.
They looked at the menu and Ian wanted to go in but his wife insisted they walk further into town to eat.
They were just 200 yards down the road when she told him to turn around. The restaurant was in flames. There'd been a gas explosion in the kitchen. The chef lost his arm.
'I just said: "For crying out loud…" and my wife said: "Oh, for God's sake." We were both so used to it at that stage.'
'Almost all the bad things happen when I'm on holiday,' he says.
'So anyone who travels with me has raised eyebrows and a sense of "bring it on".
But, actually, people travel with me because they know they'll be safe.
Nothing actually happens to me or the people with me, we all miss disaster.'
Take the time in 2010 when Ian and his ex-wife flew to San Francisco for a holiday. They drove from the airport to the centre of town, where they went to a bar for lunch. Everybody was looking up at the telly and watching 'an orange glow'.
'The little town by the airport, the one we'd driven through an hour earlier, was on fire. The gas mains had ruptured, killed 50 people,' says Ian.
Driving instructor Ian Fordrey of south London is followed by death and disaster wherever he goes
A couple of years later, on another trip to Crete, Ian found somebody in his seat.
'I'd paid for extra leg room but there was an old man in my seat. I left him there and took the seat next to him instead.
'Next thing I know his wife, sitting the other side of him, is screaming. The old boy was slumped over and completely grey. The air hostess called out for doctor and one came and dragged him down the aisle where they resuscitated him. Now every time I book a flight I think of what might happen.'
But that doesn't stop him.
'I live for my holidays,' he says. 'I'm never going to be someone that just sits around.'
And does he worry for the future? That his 99 lives might be up soon?
'I'm an eternal optimist, despite all the carnage around me. I do live life to the full and I live life for now, that's the kind of person I've always been. I'm not scared of dying but I don't want to,' he says.
Yet there are some areas of his life which seem immune from this strange disastrous streak.
He has never been involved in a car crash, for example.
Which is just as well, as he now works as a driving instructor.
Does he tell his pupils what they're letting themselves in for?
'It's not my opening gambit,' he laughs. 'But sometimes it comes out and their mouth drops open and they go quite pale. I think it makes them pass their test more quickly — they want to get out, sharpish!'
And what about any more travel? Has he got holidays booked?
'I'm going to Sharm El Sheikh in July,' he says. You've been warned.
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text:
|Publication number
|Publication type
|Publication date
|Sep 30, 1975
|Filing date
|Dec 5, 1973
|Priority date
|Dec 15, 1972
|Also published as
|Publication number
|Becker Wolf-Jurgen, Schulte Franz-Josef, Siemer Klaus
|Original Assignee
|Bayer Ag
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (4), Referenced by (7), Classifications (17)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent Becker et al.
[ Sept. 30, 1975 [54] APPARATUS FOR ANALYSIS OF LIQUIDS [75] Inventors: Wolf-Jiirgen Becker; Franz-Josef Schulte, both of Leverkusen; Klaus Siemer, Schildgcn, all of Germany [73] Assignees: Bayer Aktiengesellschaft,
Leverkuscn; Erdolchemie Gesellschaft mit beschrankter Haftung, Cologne, both of Germany [22] Filed: Dec. 5, 1973 [2]] App]. No.: 422,059
[30] Foreign Application Priority Data I Dec. 15, 1972 Germany 2261449 [52] US. Cl 23/253 PC; 23/230 PC {51 Int. Cl. GOIN 25/24; G01N 31/12 [58} Field of Search 23/230 PC 253 PC; 73/23. 73/23.], 25
[56] References Cited UNlTED STATES PATENTS 3,205,045 9/1965 Von Lossberg 2. 230 PC 3.304.159 2/]967 3.475, 1 3l l0/l969 Keulemans 3.607.076 9/l97l Paine 23/253 PC Primui'y ExaminerR. E. Serwin Attorney. Agent, or Firm-Burgess, Dinklage & Sprung 7 Claims, 5 Drawing Figures Hinsvark 23/230 PC U.S., Pamm Sept. 30,1975 Sheet 1 of2 v 3,909,202
F/GZ F763 U.S. Patent Se t. 30,1975 sheetzofz 3,909,202
APPARATUS FOR ANALYSIS-OF LIQUIDS This invention relates to an apparatus for the analysis of liquids varying in their composition.
In the analysis of liquids, a specific quantity of liquid has to be injected into the combustion furnace. In the most simple case, microliter injectors are used for this purpose. Difficulties arise when the composition of the liquid to be analysed varies as a function of time. In this case, sampling is no longer representative of the true state of the liquid to be analysed. Forthis reason, automatic microliter injectors, reciprocating pumps or the flat slide valves commonly used in gas chromatography have already been proposed for dosage. Since, in all these dosage systems, the liquid so to. speak forms up at the dosing feeder and does not flow.past the dosing orifice, prolonged dead times cannot be avoided here either.
In addition, continuous-dosage tests have been conducted with rotary cocks. For some years now rotary cocks have been successfully used for gas dosage. Unfortunately, their machining and accurate alignment of the bores involves considerable difficulties. In addition, wetability is governed to a very considerable extent upon the type of test liquid. Tiny droplets remain adhering to edges and grooves so that accurate dosage is not possible. In all the dosage systems described so far, the sample is carried into the analyser by a foreign medium (for example air, piston, etc). Direct, continuous dosage by means of capillaries can only be carried out with extremely pure liquids because a constant throughflow rate must be guaranteed. The relatively long dead time is a disadvantage in this case, too, because the volume of liquid before the capillary is generally relatively large by comparison with the closed volume.
Surprisingly accurate and reproducible dosage can be carried out by means of injection valves. In principle, valves of this kind have already been used in the motor vehicle industry for fuel injection purposes. However, the numerous tests which we have conducted have shown that, even with these valves, reproducibility of the results of analysis is far from satisfactory. Al though dosage is extremely accurate, combustion clearly differs from one liquid particle to an other. In many cases, combustion of the sample is incomplete. Since it is not possible in principle to obtain constant injection into a combustion furnace as a function of the solid angle with different samples and carrier gas streams, an attempt had to be made to find a new method. A
Accordingly, the object of the invention is to provide an system in which sampling isautomatic and which gives accurate, reproducible results, especially in the case of liquids varying in composition as a function of time. One of the conditions in this respect is that combustion should always be complete irrespective of the injection parameters (for example carrier-gas velocity, liquid pressure). t
According to the invention, there is provided an apparatus for the analysis of liquids comprising a'combustion furnace comprising several combustionchambers arranged one inside the other, whereby the sample mixed with a carrier gas flows repeatedly through the hottest zone of the furnace, an injection valve through which the liquid to be analysed continuously flows and which injects the liquid into the combustion furnace,
tion furnace.
'Air is generally used as the carrier gas. In cases where the total carbon content of liquids is determined by pyrolysis, the carrier gas should not contain-any carbon. Accordingly, the gaseous carbon dioxide inthe air used as carrier gas and any hydrocarbon compounds present are best removed by precombustion and CO adsorption. In one advantageous embodiment of the invention, therefore, thecombustion furnace is'provided with an additional combustion-chamber for precombustion of the carrier gas.
In automotivefuel-injection valves, the fuel does not flow through the valve, but is introduced under pressure. If this type of valve were to be used for analytical purposes, unacceptable dead times would occur. Apart from this, the material from which automotive fuelinjection valves are made is unsuitable for corrosive liq uids. Accordingly, conventional injection valves have to be modifiedfor this special purpose. The redesigned injection valve advantageously consists of a valve needle, axially displaceable in a valve housing, which opensan'd closes an annular gap in the valvehousing. The liquid-flow guide is designed in such a way that the liquid to be analysed flows through the annular gap. The valve needle is driven in the usual way by an electromagnet. However, it is important in this respect for the electromagnet to be 7 separated from the liquidcarrying part of the valveby an elastic membrane. It is only in this way that corrosion of the electrical components can be avoided. I
In one preferred embodiment of the valve, the valve needle terminates in a cylindrical plug with a tapered end. The taper angle a should be less than 60, preferably 45. 7
In a further development of the invention, the injection valve is preceded by a pump and an equalising volume and followed by a pressure controller with an adjusting valve. In this way, a constant pilot pressure is obtained at the injection valve.
By virtue of the invention, it is possible to carry out accurate and reproducible analyses of flowing liquids whose composition gradually changes as a function of time. By virtue of the special design of the valve, sampling is largely representative of the true state of the liquid being analysed. The particular construction of the combustion furnace guarantees complete combustion in every case. Another advantage of the new combustion apparatus is the factthat it can bevuniversally used. It is suitable for determining total carbon content and total oxygen demand and equally suitable for analysing heavy metals in liquids. One special field of application for the invention is the analysis of effluents such-as sewage. j 7
One embodiment of the invention is described by way of example in the following-with reference to the accompanying drawings, wherein:
.FIG. 1 shows the combustion furnace with the injection valve. 1 'FIG. 2 shows the injection valve.
FIG. 3 shows the'tip of the valve needle.
:FIG. 4is-a block diagram showing the delivery of test liquid to the injection valve,
FIG. 5 is a block diagram for applications where the analysis system is used for determining the total carbon content of a sewage sample;
As shown in FIG. 1, the injection valve 1 is directly connected to the combustion furnace 2. The sample 3 to be analysed flows through the injection valve 1. The combustion furnace 2 consists of two tubes 4a, 4b arranged one inside the other and surrounded by the outer shell 5. The carrier gas inlet pipe 6 is connected to the inner tube 4a. The hottest zone of the combustion furnace 2 is substantially at the centre. By means of the diverting tube 4b, the carrier gas charged with the injected sample flows three times through the hottest zone. In this way, complete combustion of the injected sample is ensured. The gaseous products of combustion formed are delivered to the analyser through the outlet opening 7.
In many cases, the carrier gas is air. In order to remove the carbon constituents from it, the air is subjected to precombustion and then to CO -adsorption. For this purpose, the furnace 2 may be equipped with an additional combustion chamber 8. The carrier air is guided through this combustion chamber 8 and the CO formed subsequently removed. The furnace as a whole may be made of quartz. It may be electrically heated to l000 l200C. The temperature may be kept constant by means of a control circuit.
FIG. 2 shows the injection valve 1 in detail. The liquid to be analysed is introduced into the valve under an excess pressure of 0.5 to 1.0 bar, and flows continuously through the valve through inlet 9 and bore 10 in a valve housing 11. The liquid enters the valve housing 11 at the tip of the valve needle 12 so that the tip of the valve needle is directly flushed by the liquid. The liquid leaves the valve housing on the opposite side at outlet 9zz,'through outlet bore 10a. This arrangement allows sampling which in every practical case is representative of the actual state of the liquid to be analysed. The shortest time interval between two successive analyses is of the order of two minutes. This dead time is necessary'for the combustion furnace to be flushed after each'injection The construction of the injection valve would allow even shorter intervals.
The valve needle 12 is mounted for axial displacement in the valve housing 11. An annular gap 13 between'the valve needle 12 and the valve housing 11 provides an outlet for discharge of samples from the liquid stream passing through bore 10 which opens when an armature 14 is attracted by a magnetic field generated in an electromagnetic coil 15. When the electrical current is cut off by the coil 15, the annular gap 13 at the cut-away edge 16 is automatically closed by the spring force of a closing spring 17. The volume injected (at least approximately pl) is determined both by the opening time of the valve needle 12 and by the excess pressure of the liquid. Under the preferred working conditions of 0.5 bar excess pressure and 20 pl sample volume, the opening time amounts to around m sec. The valve needle 12 preferably has a lift of about 0.15 mm. The lift can be adjusted by grinding the disc 18.
In order to obtain tight seating of the valve needle 12, it is provided at its lower end with a conical transition section and a cut-away edge 16. This cut-away edge is formed from two frustums with cone angles of 75 and 105, respectively. The valve housing 11 has a conical bore with a cone angle of 90. The cut-away edge 16 is seated on this bore when the valve is closed.
At its end, the conical transition section of the valve needle 12 terminates in a cylindrical plug 19 which projects from the valve housing 11. The annular gap 13 is formed between a bore in the valve housing 11 and the plug 19 of the valve needle 12. The bore in the valve housing preferably has a diameter of 1.15 mm and a length of 0.5 mm. The cylindrical plug 19 preferably has a diameter of 1 mm and a length of 2 mm. It is longer than the bore in the valve housing and, for this reason, always projects beyond the outer edge of the bore, even when the valve is closed. This ensures that the liquid is able to flow out of the valve with hardly any reaction. Since premature spraying is undesirable, the plug 19 of the valve needle terminates in a conical tip. The angle a of the conical tip should be less than 60, and it is preferably 45.
The coil housing 20, the coil support 21 and the armature 14 are made of soft-magnetic steel. However, soft-magnetic steels are not resistant to corrosive liquids, for example effluents contaminated with organic matter in the chemical industry. For this reason, the coil housing 20 is separated off from the liquid-carrying valve housing 11 by a corrosion-resistant membrane 22. The membrane may be made of polytetrafluorethylene (PTFE). The membrane 22 is held between the armature 14 and a ring on the valve needle 12 and between the coil housing 20 and the valve housing 11. In this way, the valve needle 12 remains freely movable. The armature 14 has an internal thread and can be screwed onto the screw thread of the valve needle 12, simultaneously fixing the membrane 22. All parts which come into contact with the liquid to be analysed (i.e. the valve housing 11, the valve needle 12, the inlet and outlet pipes 9 and 9a) have to be resistant to this liquid. In addition, the valve housing 11 and the valve needle 12 have to show high notched-impact strength. For dosing corrosive chemical effluents, highly alloyed steels are used as starting material.
The initial tension of the closing spring 17 can be adjusted by means of the screw 23. It is possible in this way to vary both the return force of the spring 17 and hence the closing pressure of the valve needle 12.
The valve housing 11 is screwed firmly to the coil support 21 and coil housing 20 by means of retaining nuts 24. This method of fixing provides for simple dismantling in order to clean the injection valve or to replace defective components. The current leads 25 for the coil 15 are situated at the upper end of the valve. They are guided through the coil support 21 by means of the insulating bushes 26.
The valve is standard-ground at its lower end 27 and is directly fitted onto the corresponding counterpart of the combustion furnace 2 at this standard-ground lower end as shown in FIG. 1.
Delivery of the sample liquid to the injection valve is illustrated in FIG. 4 which shows an application of the injection valve in automatic effluent analysis systems. The effluent should be as free from solids as possible because solid particles can interfere with operation of the injection valve 1. Solids can be removed from the effluent byfiltration or centrifuging. It has proved to be of advantage to use a gear pump 27 for generating a suitable pilot pressure for the injection valve 1. A pressure controller 28 with an adjusting valve acts as a throttle and keeps the liquid excess pressure at the valve 1 constant. A buffer volume 29 is provided between the valve 1 and the pump 27 in order to neutralise pressure surges of the pump.
One application of the invention is shown by way of example in FIG. 5. FIG. 5 is a block diagram for pyrolytic determination of the total carbon content of a sewage sample. The most important part of the system is the combustion furnace 2 with the injection valve 1. Air is used as the carrier gas. The air preparation unit is connected to the carrier gas inlet 6. The outlet opening 7 of the combustion furnace 2 is connected to a detector unit through various filters.
In the air preparation unit, the gaseous carbon diox ide present in the carrier air and any hydrocarbon compounds present (oil mist etc) is completely removed except for a small constant residue. The air preparation unit consists essentially of zeolite adsorbers 30 and 31 and a precombustion chamber 32 arranged between them. The precombustion chamber 32 consists of a tube 8 arranged in the combustion furnace 2. An airstream of to liters per hour is adjusted by means of a combined pressure controller and adjusting valve 33 and a flow meter 34. A non-return valve 35 between the flow meter 34 and the carrier gas connection 6 prevents the combustion gases from flowing back and the water vapour from condensing in the flow meter 34.
Approximately 20 ,ul of sewage are injected into the inner tube 4a of the combustion furnace 2 by means of the injection valve 1. The hydrocarbon compounds present in the sewage are then completely burnt at around lOOO to 1200C to form carbon dioxide. Complete combustion is obtained both by the high temperatures and by the repeated circulation of the carrier gas charged with the sample through the combustion furnace 2 (cf. FIG. 1). An increase in temperature to beyond 1200C does not bring about any increase in the yield of C0 The CO formed flows through a washing bottle 36 filled with calcium chloride granulate and a dust filter 37 to the CO -meter 38. The washing bottle 36 is used to absorb any water vapour still present. Since the carrier gas is extremely dry, some of the water vapour absorbed is slowly given off again between two injections of effluent. The dew point of the measuring gas is lowered to such an extent that water vapour is prevented from condensing in the following pipes and equipment.
Suitable CO -analysers are commercially available (for example the Uras Z-type manufactured by Messrs. Hartmann & Braun AG, Frankfurt, or the Unor Z-type manufactured by Maihak AG, Hamburg). The individual carbon dioxide concentrations are recorded by the recorder 39. Both are integrated total carbon dioxide concentration and also the maximum carbon dioxide concentration can serve as measures of the carbon content of the water. As already mentioned, the shortest interval between two successive analyses is approximately 2 minutes. This interval is necessary for flushing the carbon dioxide formed out of the combustion furnace.
What we claim is: I
1. An apparatus for the analysis of samples of a liquid comprising:
a. a combustion furnace comprising several tubes arranged one inside the other for passage of the sample serially through the tubes, during the combustion,
b. an injection valve having a bore for continuous flow of a stream of the liquid through the valve, an outlet for discharge of the sample from the stream, mea s for opening and closing said outlet for the discharge of the sample, the injection valve being connected to the combustion furnace for injection of the sample into the combustion furnace,
c. a carrier gas inlet pipe connected to the combustion furnace for introducing the carrier gas into the furnace so that the carrier gas carries the sample through the combustion furnace,
d. an analyzer connected to the outlet of the combustion furnace.
2. An apparatus as claimed in claim 1, wherein the combustion furnace has an additional combustion chamber for precombustion of the carrier gas.
3. An apparatus as claimed in claim 1, wherein the injection valve comprises a valve needle axially displaceable in a valve housing, which needle opens and closes an annular gap in the valve housing, which forms said outlet and through which the sample flows for said injection, wherein the valve needle is connected to an electromagnet which is separated from the liquidcarrying part of the valve by an elastic membrane.
4. An apparatus as claimed in claim 3, wherein the valve needle terminates in a cylindrical plug with a ta pering end whose taper angle a is less than 60 preferably 45.
5. An apparatus as claimed in claim 3, wherein the injection valve is preceded by a pump and an equalising volume and followed by a pressure controller with an adjusting valve which keeps the excess pressure at the injection valve constant.
6. An apparatus as claimed in claim 4, wherein the injection valve is preceded by a pump and an equalising volume and followed by a pressure controller with an adjusting valve which keeps the excess pressure at the injection valve constant.
7. An apparatus as claimed in claim 1, wherein the injection valve is preceded by a pump and an equalising volume and followed by a pressure controller with an adjusting valve which keeps the excess pressure at the injection valve constant.
|Cited Patent
|Filing date
|Publication date
|Sep 6, 1962
|Sep 7, 1965
|Sheppard T Powell
|Apparatus for continuous measurement of organic matter in water
|Jan 28, 1963
|Feb 14, 1967
|Hewlett Packard Co
|Gas chromatographic analysis method for c, h, and n content in solid organic compounds
|Sep 9, 1965
|Oct 28, 1969
|Perkin Elmer Ltd
|Pyrolysis apparatus
|Feb 18, 1969
|Sep 21, 1971
|Procedure and apparatus for determination of water in nitrogen tetroxide
|Citing Patent
|Filing date
|Publication date
|Jun 28, 1989
|Apr 23, 1991
|Monsanto Company
|Apparatus for carrying out catalyzed chemical reactions and for studying catalysis
|Dec 18, 2012
|Caterpillar Inc.
|High strength gray cast iron
|Mar 24, 2008
|Jun 24, 2014
|Thermo Fisher Scientific Inc.
|Combustion tube and method for combusting a sample for combustion analysis
|Dec 31, 2007
|Jul 3, 2008
|Thermo Fisher Scientific Inc.
|Combustion analyzer sample introduction apparatus and method
|Feb 28, 2007
|Aug 28, 2008
|Jaszarowski James K
|High strength gray cast iron
|Mar 24, 2008
|Dec 4, 2008
|Thermo Fisher Scientific Inc.
|Combustion tube and method for combusting a sample for combustion analysis
|Mar 25, 2008
|Sep 24, 2008
|Thermo Fisher Scientific Inc.
|Combustion tube and method for combusting a sample for combustion analysis
|U.S. Classification
|422/80, 422/79, 436/155, 436/139
|International Classification
|Cooperative Classification
|European Classification


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Ian MacKaye net worth: Ian MacKaye is an American musician, producer, and record label owner who has a net worth of $5 million. Ian Thomas Garner MacKaye was born in Washington, D.C. in April 1962. He played piano as a child and then became interested in punk music in 1979. His first band The Slinkees only had one performance. He played bass in The Teen Idles and then was a member of Skewbald/Grand Union. MacKaye joined Minor Threat and the front man from 1980 to 1983. After Minor Threat, he played in three different bands before starting Fugazi in 1987. The band is known as one of the most influential post-hardcore bands and was noted for not playing any concerts that were not affordably priced for fans. Fugazi has not been active since 2003. MacKaye is now the singer and guitar player for The Evens and has released three albums. He and Jeff Nelson started Dischord Records in 1980. The label started as a DIY project but has released over 150 titles. MacKaye is known as a part of the straight edge and hardcore movements. Minor Threat's song "Straight Edge" described being free from drugs and not abusing alcohol. Although not his intention, the song eventually helped lead to the straight edge movement. MacKaye has been friends with Henry Rollins since they were children.
Ian MacKaye Net Worth
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Ian MacKaye
Date of Birth
Apr 16, 1962 (54 years old)
Singer, Record producer, Musician, Songwriter, Guitarist, Film Score Composer
United States of America
5 ft 8 in (1.7526 m)
MacKaye, Ian, Ian McKaye, Ian Thomas Garner MacKaye
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Postgraduate Diploma of Science
University of Melbourne, The
Postgraduate Diploma
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Undergraduate degree in a relevant discipline; Some areas of study require a certain average in the relevant discipline; If a research component is involved, entry may also be subject to availability of an appropriate research topic and supervisor
Course Description
This program enables students to gain research skills and develop current, in-depth knowledge of their chosen scientific field. All study areas have a coursework component, and a majority also have a research component. For high-achieving students, this program is a potential pathway to a research higher degree, if a research component is completed.
Subjects you can Study
Botany; Chemistry; Computer science; Earth sciences; Genetics; Mathematics and statistics; Physics; Zoology
About University of Melbourne, TheThe University of Melbourne has a history of over 160 years of leadership in teaching, learning, innovation, research and research training.
Since its beginnings in 1853, people from all over the world have studied at the University of Melbourne. The University of Melbourne is the highest-ranked university in Australia and ranked number 33 in the world (The Times Higher Education World University Rankings 2014-2015). Graduates have outstanding career prospects - they are ranked Number 18 in the world for graduate employability (QS World University Rankings 2015-2016).
The University of Melbourne is the leading research university in Australia, with more than 100 research centres and institutes. Its research expenditure is second only to that of the Commonwealth Scientific and Industrial Research Organisation (CSIRO), Australia's national science agency. University of Melbourne researchers are at the forefront of international scholarship in fields as diverse as human rights law, climate change, telecommunications and medical research.
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Provider CRICOS: 00116K
Postgraduate Diploma
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Entry Requirements
Undergraduate degree in a relevant discipline; Some areas of study require a certain average in the relevant discipline; If a research component is involved, entry may also be subject to availability of an appropriate research topic and supervisor
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Students who successfully complete this course with a 75% average are eligible for consideration for the Master of Philosophy or Doctor of Philosophy (PhD) in Science.
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How do study fields for Postgraduate Diploma of Science at University of Melbourne, The perform?
Life after Study
Environmental studies
Where are graduates that studied Environmental studies at University of Melbourne, The?
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Where are graduates that studied Sciences at University of Melbourne, The?
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Botanists study the biology of all types of plants to increase scientific knowledge and apply this knowledge in areas such as conservation and management of natural resources, agriculture, forestry, horticulture, medicine and biotechnology.
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19 Feb 2008 — 72 views
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Gaon Sathis not to be regularisedyati Raj Minister Arun Sahu on Tuesday told the State Assembly that the Government has no proposal to regularise the services of the Gaon Sathis working under the Mahatma Gandhi National Rural Employment Guarantee Scheme (MGNRGS). The Minister ... New Delhi Pioneer, 2 weeks ago
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Congress Submits Privilege Notice Against Law Minister
BHUBANESWAR: Opposition Congress today submitted a privilege notice against minister of state for law Arun Kumar Sahu alleging that he misled the assembly while making a statement on April 4. The notice signed by Congress chief whip Taraprasad ...New Indian Express, 3 weeks ago Privilege Notice Against Law Minister New Indian Express, 3 weeks ago Privilege notice against Odisha Law Minister for misleading Assly with wrong fact United News of India, 3 weeks ago
Min Arun Sahu chit firms Youth Icon
ime when a row involving Food Supplies and Consumer Welfare Minister Sanjay Dasburma for his alleged involvement with Artha Tatwa (AT) Group is yet to die down, the BJP on Thursday raised finger at Panchayati Raj and Law Minister Arun Sahu accusing ...New Delhi Pioneer, 3 weeks ago Law minister Youth Icon of Ponzi firm: BJP Odisha Television, 3 weeks ago Naveen-Dasburma Meet Triggers Speculations New Indian Express, 1 month ago Dasburma invested chit fund money in 5 companies: BJP, Cong Odisha Television, 1 month ago
13L Cases Pending in Courts, Says Law Minister
BHUBANESWAR: Minister of State for Law Arun Kumar Sahu on Tuesday informed members in the Assembly that 12,95,281 cases including 1,69,453 in the High Court are pending disposal in the State. In a written reply to a question from Prafulla Samal ...New Indian Express, 2 months ago Over 12.95 lakh cases pending in courts in Odisha: Minister Odisha Television, 2 months ago
Odisha Law Minister to convene meeting on Jagamohana repair tomorrow
Odisha Sun Times Bureau Puri, May 12: Odisha Law Minister Arun Sahu has called for a meeting of the technical core committee of the 12th century Shree Jagannath temple tomorrow in the state capital following rejection of a proposal for repair of ...OdishaSunTimes.com, 2 weeks ago Arun Sahoo has no moral right to defend the govt, says Odisha BJP OdishaSunTimes.com, 3 weeks ago Odisha's Arun Sahu appointed as the Dy High Commissioner to Canada OdishaSunTimes.com, 1 month ago The high and the mighty at Odisha Power list -2016 OdishaSunTimes.com, 3 weeks ago
8.5 lakh IAY houses constructed, government admits
BHUBANESWAR: After dedicating 10 lakh houses under Biju Pucca Ghar Yojana (BPGY) to rural poor last week, the State Government on Saturday admitted that nearly 8.5 lakh houses were constructed under the centrally sponsored Indira Awas Yojana (IAY). ...New Indian Express, 1 day ago 10 lakh pucca houses for rural poor New Indian Express, 1 week ago Naveen yet to walk quota action talk Calcutta Telegraph, 2 months ago
Saint praises Chouhan for mela success
ter Shivraj Singh Chouhan has been engrossed in Simhastha arrangements for the last 3-4 years. The state government had undertaken unique decoration and beautification of Ujjain city, construction of roads, flyovers and bridges, renovation of Neel ...New Delhi Pioneer, 6 days ago
Decks cleared for use of Odia language in all govt work
[embedded content] Bhubaneswar: The obstacles on the way of the implementation of Odia language in all official business were removed today after the State government moved an ordinance in this regard. As per the old Act, the government had ...Odisha Television, 6 days ago State takes ordinance route to execute Odisha Official Language Act OdishaSunTimes.com, 6 days ago Language body hails decision on Odia language HT Syndication, 1 week ago Odisha Bhasha Sangram Samiti hailed the decision of govt on Odia language Orissadiary.com, 1 week ago
Three Odia movies to entertain Raja revellers
ilms released during festivities like Raja guarantee full houses at theatres for at least three weeks despite the invasion of pirated VCDs and DVDs. Most of the Odia films are released coinciding with the festive seasons. Usually Raja and ...New Delhi Pioneer, 1 week ago
Gajapati calls upon ASI to speed up work
BHUBANESWAR: With the repair of Sri Jagannath Temple's 'Jagamohan' hitting hurdles, Puri King Dibya Singh Deb on Monday called upon the Archaeological Survey of India (ASI) to take up the work on a war-footing. He said delay in decision-making has ...New Indian Express, 1 week ago
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Do you know what the translation for the French taupe is? Or which language has two words for blue? Take our quiz to test your knowledge of colours in language. Photo credit: Natalia Deriabina / Shutterstock.com
Although we have a plethora of words in our vocabularies to describe colour, it's unlikely that we each perceive colour in the same way. What if your red is actually my blue, or my yellow is your green? We may never know if a Parisian's rouge is identical to a Varsovian's czerwony, but we can […]
As Katherine Shaw noted in a rather colourful article for this blog, the origins of the English primary colour names are ultimately either non-referential, in that they aren't derived from the colour of some previously known entity, or have such long histories that their origins are simply unknown. This, she notes, is in contrast with […]
There used to be nothing erotic about grey. Until E. L. James it was, for me, the colour of John Major's underpants because that's how Steve Bell always drew them in his cartoons for the British newspaper The Guardian. Grey is the colour of brains (grey matter) but I don't think that's the point of […]
8 tips you need before you start writing a book review: oxford.ly/1ICMepH pic.twitter.com/zZon0nzD2y
Word of the Day: gens - ancient Roman families who shared a name…... ow.ly/kA2z500E8OW
23 words you might be spelling incorrectly: oxford.ly/1OSW0sB pic.twitter.com/mIhhg1zYo2
Word of the Day: sensate - perceiving or perceived by the senses... ow.ly/dwJF500BAXz
Sort your dashes from your dots with 6 punctuation marks you might be misusing: oxford.ly/1K60qNR pic.twitter.com/r3zbp00xod


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Joined: 10 September 2011
Posts: 19147
What's with the Gupta ladies ??
Buaji and Garima said they are surprised that the Raizada's chose Payal. Didn't they hear it when Mami said 'love ka mamla hai' ?
Did they think Nani, mama-mami and Anjali fell in love with Payal?
I so want Khushi to get married to Arnav and move out of that house. The Gupta family is such a disgrace ( except for Babuji ) .
Payal what's with gale mein atak gayyi.?? ...just because you lack any facial expression doesn't mean you won't at least try to read your father's expressions.
Credit goes to Khushi. At least she's thinking and connecting the dots...can't blame her for being a little slow. After all she was raised by a 'family ke naam pe kalank' .
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I totally agree about Payal being selfish. Babuji may not be very clever but he loves Khushi a lot. That's why I am ready to forgive him.
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the current actor playing garima is a door mat
payal - i never warmed up to the actor or character.. so no comments..
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MassDOT Secretary and CEO Richard Davey today joined Gulfstream Aerospace leaders, Westfield-Barnes Regional Airport and local officials to celebrate the ribbon-cutting for the Gulfstream Hangar Expansion Project.
Gulfstream's expansion includes a new 100,000 square foot hangar with office space and will result in 100 new jobs added to Gulfstream's existing airport workforce of 140.
"Massachusetts is leading the nation in economic recovery, thanks to companies like Gulfstream that are expanding right here in the Commonwealth," said Governor Patrick. "Because of our investments in innovation, education and infrastructure, Massachusetts is a great place for business, and I thank Gulfstream for adding these 100 new jobs, and the economic benefits that will follow."
"Aviation is an economic engine across the state, and right here in Westfield it generates more than 2,000 jobs and economic output of $180 million," said Secretary Davey. "Gulfstream's investment combined with MassDOT and other state financial support will further enhance opportunities in this area."
Gulfstream Aerospace manufactures mid-size and large cabin business jet aircraft with Northeast aircraft maintenance repair facilities centered at Westfield-Barnes Regional Airport. The company invested approximately $20 million in the hangar expansion. MassDOT funds totaling $3 million realigned the airport perimeter roadway and provided additional parking, while the Massachusetts Office of Business Development provided $2 million for a new road providing access to Gulfstream and a newly-created industrial park.
"In addition to Gulfstream's commitment to expansion, MassDOT is also pleased to join our partners at the Federal Aviation Administration, the City of Westfield, and the Air National Guard in preserving and enhancing the infrastructure at the Westfield-Barnes Regional Airport," said Christopher Willenborg, MassDOT Aeronautics Division Administrator.
Willenborg said upcoming improvements include reconstruction and pavement replacement of a key airport runway later in 2013.
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Plan Ahead for Memorial Day Weekend Travel posted on May 24
MassDOT encourages travelers to plan ahead and travel safely during the Memorial Day holiday weekend. The heaviest traffic is observed during Thursday, Friday, and Monday afternoons and early evenings. Drivers are encouraged to make travel plans accordingly and if possible avoid peak traffic volumes between …Continue Reading Plan Ahead for Memorial Day Weekend Travel
MBTA: Hoverboards Not Allowed posted on May 24
Effective immediately, hoverboards are prohibited on all MBTA property, including stations, buses, subways, trains, and commuter boats. MBTA subway and bus personnel, along with Keolis Commuter Rail staff have been informed that customers with hoverboards shall not be permitted to bring such devices into MBTA …Continue Reading MBTA: Hoverboards Not Allowed
MBTA General Manager DePaola Retirement posted on May 24
Frank DePaola, P.E., who has served as General Manager of the Massachusetts Bay Transportation Authority (MBTA) since February 2015, announced to staff that he plans to retire after his current appointment expires on June 30. Secretary of Transportation Stephanie Pollack thanked DePaola in a letter …Continue Reading MBTA General Manager DePaola Retirement


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Home / Posts tagged "Tragedy"
The Taylor Report and its Effect on Football
The Taylor report was the final report written in January 1990 by the Rt Hon Lord Justice Taylor about his inquiry after the Hillsborough stadium disaster which claimed 96 lives and...
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Amanda Simon on What we've learned so far about Haye 2.0
They played very well. I was this match. The match was very intrested. But David Haye played very well.
Shoaib Zaheer on What Does Pakistan Bring to the WT20
great article
Amanda Simon on Frampton beats Quigg by split decision to unify IBF/WBA titles
What an watch. I love the way they played. I love to watch this type of matches.


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Bring a buddy.4.55 / 5.00 9,984 Views
Yugi and Kaiba have a duel to the death!4.46 / 5.00 37,065 Views
Vampire Pixel in the Neon City
A sinister deal is underway in the underbelly of Neon City4.33 / 5.00 11,422 Views
This was abysmal quality. The animation was poor the voicing was bad and the story was very lame.
Keep trying but try harder and get some more friends involved and plan things out etc.
Try to be proffesional.
thx and okey
Subs are mis-spelt, not complete and change too fast
Music plays before video begins and will play over other sound if video is played a second time
The black screen with what i assume is the song title is very sudden and in the wrong place, credits go at the end
This only gets the half a star because i like the song, though you didnt create that so it shouldnt really count...
i know it was a wrong thing there i could'nt fix it
This is the better than others you made.


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EXCLUSIVE: MEP plans campaign to have UK civil partnerships recognised in Europe
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An easier way to resolve all of this inequality is to open full marriage to all gay people in the EU. Marriage is the gold standard around the globe, CPs NEVER will be. All this nonsense about who and who does not recognise CPs is absurd and unnecessary. Marriage is the uniform standard, the word alone resolves all of these issues caused by different types of gay legal unions. What an absolute mish mash! The EU needs one standard for all member states, not a series of some with more and some with less rights via non-marital unions. So f—-d up!
well, I said on this site ages ago that they weren't the same, though others have held that CPs were the equivalent of marriage, but I didn't think that it would end with someone losing their home.
I've written to Milliband asking for a response. I can only suggest that others do the same: email@example.com
Yet again, we find only the Lib Dems standing up for LGBT liberation and equality. It's like a stuck record…
Is it intentional discrimination, or bureaucratic inefficiency? Have the French government given an explanation?
apYRs, exactly! If it were equivalent to marriage, then they would be referred to as marriages. The fact of that matter is, they are nothing more than legal unions that are not uniform around the world and never will be. I would have thought that the antimarriage supporters who post here would be offended having their partnerships compared to marriage anyway. If Civil Partnerships were uniform across the EU, then perhaps that would resolve most of the issues, but that is NEVER going to happen. Even it were to happen, they would still face hurdles with other western nations where marriage is available to their GLB citizens. Civil partnerships have absolutely NOTHING to do with marriage, therein lies the problem. Marriage is understood everywhere, in every country. CP's? Not going to happen! That's why 6 countries now offer marriage and a seventh now pending, its growing and will one day surpass CPs, PACS and other pseudo-marriage style unions whether the antimarriage bashers like it or not.
I am a dual national (British and French) and intend to have a PACS rather than a civil partnership with my boyfriend because at least in France they acknowledge it is less than marriage. Its disgraceful that British politicians (with a few exceptions) don't seem to think same-sex couples deserve full marriage equality.
I completely agree with Brian. Why should France and other countries honour a law created in the UK which is not uniform throughout the rest of the world.
I've NEVER thought of this Civil Partnership idea as appropriate and find it discusting that Stonewall would support an act which enshrines in law inequality. I don't want special treatment – I want equal treatment. To me this seems like the days when blacks in America could not drink from the same water fountain as whites. The equivalent to us is we're given a hose to quench our thirst and told this is equality.
Perhaps Ms Bowles should look into the EU over-riding Civil Parterships, Unions, PACS and other second class arrangements and force countries to recognise them as Civil Marriages.
What a load of hassle…
John, PJW, absolutely spot on! Its absurd creating a separate class of people with similar rights to the rest of society. Its a regressive move. Granting people the same rights under one institution. However, in addition to opening marriage to us, I do think those who want to opt for a partnership should be permitted to do so. I for one wouldn't, but we should have choice. Straight couples should also be given the right to opt out of marriage for a partnerhip too. That would be full equality for all. The UK is not that progressive on that point and if it were, we'd be the equality leader of the world, let alone the envy of the entire GLB community around the globe. We missed the chance to do that by settling for something less than equal.
Ooops, "granting people the same rights under one institution would be the appropriate step to take", I meant to have said.
Got the jist of what you are saying Robert – or Brian as I called you earlier :-)
some of you may be interested in these articles from France about this issue.
I'm not too sure that the Dutch gay marriage was simply recognised in Francejust because they called it a marriage, it may be becuase they have already campaigned for their rights in France and the U.K are just now catching up with them. After all for many EU countires the principle of any form of same sex partnership is pretty horrifying for them.
Some of you may be interested in these French articles:
I and my Civil Partner are wanting to move to France but this whole issue has made it impossible for the moment. We are self sufficient financially and so would present no burden to the French state. In fact they would have the benefit of our pink euros.
I agree that we want and demand equality across the whole EU but this issue between France and the UK over PACS/CP should be easily resolveable.
We have been partners for 39 years and jumped at the chance to be recognised under the CP. Now we think we should have waited and just gone to France and taken a PACS. We dont want to dissolve our partnership – in fact we cant (no grounds), so we are in a catch22. Please someone sort it out!
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