text:
|Publication number
|Publication type
|Publication date
|Jul 8, 1975
|Filing date
|May 8, 1972
|Priority date
|May 7, 1969
|Publication number
|Hubele Adolf
|Original Assignee
|Ciba Geigy Ag
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (7), Referenced by (6), Classifications (13)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent Hubele i *July 8, 1975 1 CONTROL OF BACTERIA WITH [56] References Cited DETERGENT OR CLEANING UNITED STATES PATENTS COMPOSITIONS CONTAINING 2,846,399 8/1958 Beaver a a1 252/107 PHENYLTHIOUREAS 2,894,986 7/1959 Beaver et al 260/553 3,200,035 8/1965 Martin et al. 252/106 X ['75] Inventor' Hubele Rlehen swtzerland 3,395,233 7/1968 Duerr et a1. 424/322 Assignee: AG, Basel Switzerland Martin et al v 3,686,418 8/1972 Taber et al. 424/322 1 1 Nome: The Pomon 9f the term of thls 3,811,932 5/1974 Hubele 252/8.8 x
patent subsequent to May 21, 1991, has been disclaimed.
22 Filed; May 8, 1972 Primary Examiner--P. E. Willis, .11.
Attorney, Agent, or F irmFreder1ck H. Rabin [21] App]. No.: 250,937
' Related [1.8. Application Data [62] Division of Ser. No. 34,594, May 4, 1970, TRACT abandoned' B-Chlorallylthioureas as well as their derivatives 0btained by adding Cl or Br at the chlorallyl group are [30] Apphcanon Pnomy Data effective microbicides. They may be used as active May 7, 1969 Switzerland 7008/69 aggms in detergents or for the purpose of imparting to July 25, 1969 Switzerland 1 1440/69 fibrous materials anti-microbial and anti-mycotic resistance as well as for controlling plant-pathogenic bac- [52] US. Cl. 252/106; 252/107; 117/138.5 t i a d fungi. [51] Int. Cl Clld 3/48 [58] Field of Search 252/106, 107; 424/322;
3 117/ 1 38.5 15 Claims, N0 Drawings CONTROL OF BACTERIA WITH DETERGENT OR CLEANING COMPOSITIONS CONTAINING PHENYLTI-IIOUREAS This is a division of application Ser. No. 34,594, filed on May 4, 1970, now abandoned.
This invention provides new biocidal thioureas of the formula which also includes derivatives thereof obtained by the addition of C1 or Br at the chlorallyl group, and in which Ar represents a phenyl group which may be unsubstituted or substituted by one or more of the following residues; halogen, N --CN, SCN, alkyl or haloalkyl with up to 4 carbon atoms the latter group preferably being CF CF CI, -CFCl or CCI As halogens there are to be understood fluorine, chlorine, bromine or iodine, preferably chlorine and bromine.
Those compounds are preferred in which the phenyl group is substituted by not more than three of the said substituents. Especially active compounds of the formula I are those containing substituents in the 3,4 or 3,5-positions of the phenyl nucleus. The substituents are preferably electronegative electron drawing), but this does not exclude the similtaneous presence of electroneutral substituents such as methyl, ethyl, npropyl. isopropyl, n-butyl or sec.-butyl groups.
The active substances of the formula I are active against humanand plant-pathogenic bacteria and fungi.
They have a very good activity against members of the class phycomycetes, for example, phytopathogenic fungi such as Botrytis and Piricularia, but also against various other pathogens on corn, soya beans, maize, rice, vegetables fruit and other cultivated plants.
They are particularly active against the following species of fungi: species of Cochliobolus miyabeanus, species of Corlicium, species of Ceruspora, species of Alternaria,
Venturia inaequalis, Podosphaera leucotricha, Uromyces p/zaseoli, C ercospora apii, Cercospora beticola, Cercospora musae, Piricularia sp., Erysiphe cichoriacearum, Penicillium digitatum, Sphaerot/reca llumuli, Diplocarpon rosae, Uncinula necalor, Coccomyces hiemalis, Cladosporium carpophilum, Erysiphe graminis lwrdei, Munulinia (Sc lerotinia) Laxa, Monolinia (Sclerotinia) fructicola, Piricularz'a oryzae, Puccinia recondita, Puccinia coronata, Pucc'inia glumarum, Puccinia graminis tritici, Aspergillus niger, Aspergillus terreus, Rhizoctonia, Fusarium, Verticillium. This list is not intended to be complete.
The active substances of the invention and preparations containing them also exhibit a toxic action on fungi that attack plants in the earth and some of which cause tracheomycoses, such as Fusarium cubense, Fusarium dianthi, Verticillium alboatrum and Phialophora cinerescens.
The active substances of this formula I can also serve as bacteriostatics, for example, as additions to soap, that is to say, they can be used principally in detergent and cleaning preparations.
For this purpose there have been found especially suitable the compounds of the formula R NH-C-N-CH in which two of the substituents R, R and R" are identical or different from each other and represent C1 or CF and the third represents a hydrogen atom.
The present invention also provides biocidal preparations, which contain as active components at least one thiourea of the formula I, or a derivative thereof produced by the addition of C1 or Br to the clorallyl group, together with one or more of the following additives: solvents, dispersing agents, wetting, agents, adhesives, binding or thickeners or diluents, stabilisers or further The active components can also be used in the textile field. When applied from aqueous dispersions or from solutions in organic solvents they possess an affinity for keratin fibres and can be used for protecting these fibres against attack by micro-organisms.
In the presence of protein materials, for example, blood or serum, and non-ionic, anionic or cationic organic surface-active compounds, such as are present in the form of soaps and synthetic wetting, emulsifying or washing agents, they do not lose their biocidal action. Moreover they have no objectionable odour, they are well tolerated by healthy skin and they cause no poisonous side effects towards warrn blooded animals in the concentrations customarily used in disinfection.
All these properties render the detergent and cleaning preparations of this invention suitable for a very wide range of application. Thus, for example, there may be mentioned their use in the soap industry, in cosmetics, and generally in the care of the body and hygiene as disinfecting and preserving agents for a very wide variety of technical and natural products, and especially as detergent and cleaning preparations having a disinfecting and sanitizing action in houses and in industry. For these purposes they can be used in a very wide variety of forms. As examples there may be mentioned their use in the form of soap solutions, foam baths, sprays, especially foam sprays, solutions in organic solvents and the like. These applications are connected with biocidal finishing which is mainly antibacterial and anti-mycotic.
Of special interest, however, is the use of the detergents and cleaning agents of the invention for imparting an anti-microbial and anti-mycotic finish in or with the protection of textile and non-textile fibrous materials and laminar structures such as films, which may be in any stage of manufacture, against micro-organisms. The treatment of fibrous materials is especially important, because it has been found that the active substances of the formula (I) when applied from an aqueous bath exhibit a substantive affinity for a very wide variety of fibrous materials.
As fibrous materials there come into consideration natural and synthetic fibres. Among natural fibres there may be mentioned, in addition to mineral fibres, for example, asbestos, more especially cellulosic fibres, such as linen, sisal, cocus, bast, and especially cotton and nitrogenous fibres, such as leather and wool. As synthetic fibrous materials there come into consideration both polycondensates such as polyadducts and polymerisation products, that is to say, polymers in a wide sense, and also glass fibres. The polymer fibres may be derived from natural or synthetic polymers. Fibres of nat ural polymers are, for example, regenerated cellulose and cellulose dito tri-acetate-Fibres derived from synthetic polymers are, for example, fibres of polyesters, polyamides, polyurethanes, polyacrylonitrile, polyvinyl chloride and polyethylene. In this manner it is possible to impart to these fibrous materials by simple washing with a detergent or cleaning preparation of the invention a finish that is lastingly biocidal, preferably antibacterial and anti-mycotic, and thus to protect these materials against attack by micro-organisms and other pests. Fibrous materials having a finish of this kind are not only themselves protected against attack by microorganisms and moulds. They also protect their immediate surroundings and thus prevent, for example, the occurrence of unpleasant body and perspiration odours caused by microorganisms, which is especially advantageous with fully synthetic and cellulosic textile fibrous materials. The finish so produced has a good resistance to chlorine and perborate.
The detergent and cleaning preparations of the invention contain, in addition to the active substance of the formula (I), solid or liquid additions that are suitable for this purpose. Such additions are, for example, the usual washing assistants and washing-active substances. Washing-active substances are surface-active compounds. Such surface-active compounds are, for example, soaps, that is to say, salts, especially alkali metal salts, of fattyacids of high molecular weight, or soap-free washing-active substances, for example, anion-active alkyl-aryl sulphonates, tetrapropyl-benzene sulphonates, fatty alcohol sulphonates, condensation products of fatty acids and methyl-taurine, condensation products of fatty acids with salts of oxyethane sulphonic acids, fatty acidprotein condensation products, primary alkyl sulphonates, non-ionic products, for example, condensation products of alkyl-phenols and ethylene oxides and also cation-active compounds. As washing assistants there are to be understood compounds which themselves possess no or only a small washing power, but influence the washing properties of a detergent. Thus, for example, they are able to impart an optimum pI-I-value to the washing liquor or to increase the dirt-tolerance capacity and the washing effect. Examples of such substances are electrolytes, for example, trisodium phosphate, sodium diphosphate, sodium carbonate, sodium bicarbonate, sodium sulphate, sodium metasilicate or water glass, cellulose glycolates, organic complex-formers (softeners), bleaching agents, optical brighteners, light protection agents, anti-oxidants, perfumes etc.
The new preparations of the invention may be in various forms depending on their mode of use, for example, in the form of solid, semi-solid or liquid soaps, in the form of pastes, powders, emulsions, suspensions, solutions in organic solvents, or sprays, powders, granulates, tablets, in capsules of gelatine or other material, or as salves.
The quantities in which the active substances of the formula (I) are used may vary within a wide range. Generally, however, 1 to 30 grammes per litre of liquor produce the desired effect. The detergent and cleaning preparations generally have a content of active substance of 0.3 to l0% by weight, and preferably 0.5 to 3% by weight.
As further ingredients the preparations of the invention may contain, depending on the purpose for which they are to be used, other biocidal substances, preferably fungicides or microbicides.
As components of the combination there may be mentioned, for example, the following active substances:
INORGANIC COMPOUNDS elementary sulphur ammonium polysulphide sodium polysulphide barium polysulphide calcium polysulphide and calcium thiosulphate (lime sulphur) calcium hypochlorite boric acid sodium tetraborate decahydrate (borax) zinc chloride magnesium borate nickel sulphate potassium chromate lead arsenate cadmium chloride cadmium carbonate COPPER COMPOUNDS TIN AND MERCURY COMPOUNDS bis-(tri-n-butyl-tin) oxide triphenyl-tin hydroxide (fentin hydroxide) triphenyl-tin acetate (fentin acetate) bis-(tributyl-tin) succinate mercurous chloride (calomel) mercuric chloride mercuric oxide mercury zinc chromate complex mercuric lactate ethyl-mercuri chloride 2-hydroxyethyl-mercuri acetate ethyl-mercure isothiocyanate 3-ethoxypropyl-mercuri bromide chloromethoxypropyl-mercuri acetate methoxyethyl-mercuri chloride 2-methoxyethyl-mercuri silicate bis-(methyl-mercuri) sulphate bis-(methyl-mercuri) ammonium acetate ethyl-mercuri acetate 2-methoxyethyl-mercuri acetate ethyl-mercuri phosphate isopropylmethyl-mercuri acetate methyl-mercuri cyanide methyl-mercuri benzoate N-cyano-N-(methyl-mercuri)-guanidine methyl-mercuri pentachlorophenolate ethyl-mercuri 2,3-dihydroxypropyl mercaptide methyl-mercuri S-hydroxyquinolate (Ortho LM) N-(methyl-mercuri)-1,4,5,6,7,7-hexachloro-bicycl- [2.2.] hept-5-en-2,3-dicarboximide N-(ethyl-mercuri)-l,4,5,6,7,7-hexachloro-bicyclo- [2.2.1 hept-5-en-2,3-dicarboximide sodium salt of ethyl-mercuri thiosalicylate N-(ethyl-mercuri)-p-toluene sulphonic acid anilide phenyl-mercuri acetate (PAM) phenyl-mercuri propionate phenyl-mercuri triethanolammonium lactate (PAS) phenyl-mercuri urea N-(phenyl-mercuri)-l ,4,5,6,7,7-hexachloro-bicyclo- [2.2.1] hept-S-en-2,3-dicarboximide phenyl-mercuri dimethyl dithiocarbamate phenyl-mercuri formamide phenyl-mercuri chloride phenyl-mercuri acetate phenyl-mercuri benzoate phenyl-mercuri borate phenyl-mercuri hydroxide phenyl-mercuri iodide basic phenyl-mercuri nitrate phenyl-mercuri monoethanolamine lactate phenyl-mercuri salicylate hydroxy-mercuri chlorophenol hydroxy-mercuri trichlorophenol hydroxy-mercuri nitrophenol N-phenyl-mercuri ethylene diamine phenyl-mercuri monoethanolammonium acetate pyridyl-mercuri acetate diphenyl-mercuri 8-hydroxyquinolate mercuric complex with organic phosphates mixture of methyl-mercuri 2,3-dihydroxypropyl mercaptide and methyl-mercuri acetate mixture of ethyl-mercuri 2,3-dihydroxypr0pyl mercaptide and ethyl-mercuri acetate mixture of hydroxy-mercuri chlorophenol and hydroxy-mercuri nitrophenol mercury cadmium organic complex FURTHER ORGANIC METAL COMPOUNDS.
cadmium succinate cadmium di-n-propyl-xanthate cadmium 8-hydroxyquinolate phenylamino-cadmium acetate phenylamino-cadmium dilactate methyl-arsine sulphide zinc octoate zinc oleate IIMPLE ORGANIC COMPOUNDS (ALIPHATICS).
formalin paraform aldehyde acrolein methyl bromide methyl isothiocyanate tetraiodo-ethylene 1,3-dichloropropylene and related chlorinated C hydrocarbons 1-chloro-3-bromopropyIene-( l trans-l ,4-dibr0mobutylene( 2) l,3-dichloropropylene-( l l-chloro-2-nitropropane 2-ch1orol -nitropropane trichloro-nitromethane dichloro-tetrafluoro-acetone sodium salt of propionic acid calcium salt of propionic acid chlorofumaric acid bis-B-chlorethyl ester sorbic acid and its potassium salt 2-propylene-l ,1-diol acetate 2-aminobutane dodecyl-guanidine acetate (dodine) dodecyl-guanidine phthalate a-chloracetyl-l ,3-aminopropionitrile a-bromacetyl-valine amide 1,2-dichlorol -(methylsulphonyl )-ethylene 1,2-dichloro- 1 -(butylsulphonyl)-ethylene trans-1,2-bis-(n-propylsulphonyl)-ethylene BENZENE DERIVATIVES.
p-dichlorobenzene hexachlorobenzene (HCB) l,2,4,5-tetrachloro-4-nitrobenzene (tecnazene) pentachloro-nitrobenzene (quintozene) 1 ,3,5-trichloro-2,4,6-trinitrobenzene isomeric mixture of l ,3 ,4-trichloro-2,6- dinitrobenzene and l ,2,3-trichloro-4,6- dinitrobenzene 2,4,5,6-tetrachloro-isophthalic acid nitrile 2,4-dinitrophenyl thiocy-anate diphenyl (biphenyl) o-nitro-diphenyl 1-chloro-2,4-dinitronaphthalene acenaphthene PI-IENOLS.
salicyl-anilide bismuth salicylate trifluoromethyl-salicyl-anilide halogenated with chlorine or bromine brominated salicyl-anilide (3,5-dimethyl-4-chlorophenoxy)-3thanol DINITROPI-IENOL DERIVATIVES.
2,6-dichloro-4-nitraniline (dichloran) 2-cyanethyl-N-phenyl carbamate propynyl-N-phenyl carbamate a-(2-bromacetoxy)-acetanilide QUINONE DERIVATIVES.
2,3,5,6-tetrachloro-benzoquinone-(1,4) (chloranil) 2,3-dichloro-naphthoquinone-( 1,4) (dichlone) Z-amino-3-chloro-naphthoquinone-( 1,4) 2-chloro-3-acetylamino-napthoquin0ne-( 1,4) 4-methyl-2,3,5,l0-tetrahydro-3,5,lO-trioxo-4I-I4-H- naphth0-( 2,3 ,-b)-l ,4-thiazine 2,3,6,7-tetrachloro-4a,8a-epoxy-l ,2,3,4,4a,8a-
hexahydro- 1 ,4-methanonaphthalene-5 ,8-dione quinone-oxime-benzoyl-hydrazone (benquinox) TRICHLOROMETI'IYLTI-IIO-DERIVATIVES.
N-(trichloromethylthio)-phthalimide (folpet) N-(trichloromethylthio )-cyclohex-4-en-l ,2
dicarboximide (captan) N-( I ,l ,2,2-tetrachlorethylthio)-cyclohex-4-en-1,2-
dicarboximide (captafol) N-methane-sulphonyl-N-trichloromethylthio-pchloraniline N'-dichlorofluoromethylthio-NN-dimethyl-N'- phenyl sulphonamide (dichlofluanide) S-( 2pyridyl- I -0xide )-S -trichloromethyl disulphide hydrochloride ORGANIC PHOSPHATES.
0,0,0-trimethyl thiophosphate 0,0-diethyl-phthalimido-phosphonothioate 5-amino-bis-(dimethylamido)-phosphinyl-3-phenyl- 1,2,4-triazole (triamiphos) 5-methylamino-bis-(dimethylamido)-ph0sphinyl-3- phenyl-l ,2,4-triazole 0,0-diethyl-O-Zpyrazinyl-phosphorthioate O-ethyl-S,S-diphenyl-dithiolphosphate O-ethyl-S-benzyl-phenyldithiophosphate 0,0-diethyl-S-benzyl-thiolphosphate DITHIOCARBAMATES.
zinc salt of dithiocarbazinic acid sodium N-methyl-dithiocarbamate (metham) sodium N-methoxyethyl-dithiocarbamate crotonate sodium N,N-dimethyl-dithiocarbamate (DDC) ammonium N,N-dirnethyl-dithiocarbamate zinc N,N-dimethyl-dithiocarbamate (ziram) iron N.N-dimethyl-dithiocarbamate (ferbam) copper N,N-dimethyl-dithiocarbamate disodium ethylenel ,2-bis-dithiocarbamate (nabam) zinc ethylene-1,Z-bis-dithiocarbarhate (zineb) iron ethylenel ,Z-bis-dithiocarbainate manganous ethylene-1 ,Z-bis-dithiocarbamate (maneb) calcium ethylenel ,Z-bis-dithiocarbamate ammonium ethylene-l ,Z-bis-dithiocarbamate zinc propylene-1,2-bis-dithiocarbamate (mezineb) (propineb) bis-( dimethylthiocarbamyl )-ethylenel ,2-bisdithiocarbamate complex consisting of maneb and zinc salt (mancozeb) tetraethyl-thiuram monosulphide bis-(N,N-dimethyl-dithiocarbamylmercapto)- methylarsine tetramethyl-thiuram disulphide (thiram) dipyrrolidyl-thiuram disulphide N,N-bis-(dimethylamino)-thiuram disulphide polyethylene-thiuram sulphide complex consisting of zineb and polyethylenethiuram disulphide (metiram) O-l-IETEROCYCLES bis-(3,4-dichloro-2(5)-furanoyl)-ether (mucochloric anhydride) Z-methoxymethyl-S-nitrofurane S-nitro-furfuraldoxime-(Z) 5-nitro-furfuryl-amidoxime-(2) l-oxy-3-acetyl-6-methyl-cyclohexene-( 5 )-dione- (2,4) (dehydroacetic acid) l-N-HETEROCYCLES 3-[2-( 3,S-dimethyl-Z-oxycyclohexyl)-2-hydroxyethyl]-glutarimide (cycloheximide) phthalimide 2- AND 3-N-l-IETEROCYCLES 2-n-heptadecylimidazolidine acetate (glyodine) l-hydroxyethyl-2-heptadecyl-imidazolidine 1 -phenyl-3 ,5 -dimethy1.-4-nitrosopyrazole 1-p-chlorphenyl-3,5-dimethyl-4- nitrosopyrazole I-p-sulphamylphenyl-3,5-dimethyl-4-nitrosopyrazole l-hydroxypyridine-2- N-( l-phenyl-Z-nitropropyl)-piperazine 2-dimethylamino-6-methyl-5-n-butyl-4-hydroxypyrimidine N-dodeyl-l ,4,5 ,6-tetrahydropyrimidine N-dodecyl-2-methyl-1,4,5 ,6-tetrahydropyrimidine 2-n-heptadecyl-tetrahydropyrimidine l-( 4-amino-4-propyl-5 -pyrimidyl-methyl )-2-methylpyridinium chloride hydrochloride 2-(2'-furyl)-benzimidazole (furidazole) 3-dodecyll -methyl-2-phenyl-benzimidazolium ferricyanide methyl N-benzimidazol-2-yl carbamate (benomyl) 2-(o-chloranilino)-4,6-dichl0ro-sym.-triazine 2-ethylamino-6-methyl-5-n-butyl-4- hydroxypyrimidine S-I-IETEROCYCLES 5-chloro-4-phenyl-l ,2-dithiol-3-one 2,3-dicyano-l ,4-dithia-anthraquinone (dithianone) 2-( 4-thiazolyl )-benzimidazole NO-. NS- AND OS-HETEROCYCLES 4( 2-chlorophenyl-hydrazon0 )-3-methyl-5- isoxazolone (drazoxolone) thiazolidinone-4-thione-(2) (Rhodanine) 3-( p-chlorophenyl )-5-methyl-rhodanin 3 ,S-dimethyltetrahydrol ,3,5-thiadiazine-2-thione (dazomet) 3,3-ethylene-bis-(tetrahydro-4,6-dimethyl)-2I-I- l,3,5-thiadazine-2-thione (milneb) 3-benzylidene-amino-4-phenyl-thiazoline'2-thione zinc salt of 6-chlorobenzthiazole 2-thiol (a-B-diethylamino-ethoxy-Z-dimethylaminobenzthiazole dihydrochloride monoethanolammonium-benzthiazle-2-thiol lauryl-pyridinium--chloro-2-mercaptobenzthiazole zinc and sodium salts of Z-mercaptobenzthiazole and dimethyldithiocarbamate 6-(B-diethylaminoethoxy)-2- dimethylaminobenzthiazole dihydrochloride 3-trichloromethylthio-benzothiazolone 3-trichloromethylthio-benzoxazolone 3-(trichloromethyl)-5-ethoxy-1,2,4-thiadiazole 6-methyl-2-oxo-l ,3-dithiolo [4,5-b]-quinoxaline (quinomethionate) 2-thio-l,3-dithiolo [4,5-b1-quinoxaline (thioquinox) 2.3-dihydro5 -carboxanilido-6-methyl-l ,4-oxathine 3 ,3 ,4,4-tetrachlorotetrahydrothiophene-l ,l-dioxide 2,3-dihydro-5-carboxanilido-6-methyll ,4-oxathine- 4,4-dioxide QUATERNARY AM MONIUM COMPOUNDS cetyl-trimethylammonium bromide n-alkyl(C, ,C ,C ;)-dimethylbenzyl-ammonium chloride alkenyl-dimethylethylammonium bromide dialkyldimethylammonium bromide alkyldimethylbenzylammonium chloride alkyl C C, tolylmethyltrimethylammonium chloride di-isobutylcresoxyethoxyethyldimethylbenzylammonium chloride p-di-isobutylphenoxyethoxyethyldimethylbenzylammonium chloride benzoyltrimethylammonium bromide N-( butylcarbamoyl FUNGICIDAL ANTIBIOTICS VARIOUS N-( 3-nitrophenyl )-itaconimide phenoxy-acetic acid sodium p-dimethylamino-benzene diazosulphonate acrolein-phenylhydrazone Z-chloracetaldehyde-(Z,4-dinitrophenyl)-hydrazone 2-chlor-3-(tolylsulphonyl)propionitrile l-chlor-2-phenyl-pentan-diol (4,5 )-thione-( 3) p-nonylphenoxypolyethyIene-oxyethanol-iodine complex (a-nitromethyl)-o-chlorobenzylthioethylamine drochloride 3-(p.-t.-butyl-phenylsulphonyl)-acrylonitrile octachlorocyclohexenone pentachlorobenzyl alcohol pentachlorobenzyl acetate pentachlorobenzaldehyde cyanhydrin 2-norcamphane-methanol 2,6-bis-(dimethylaminomethyl)-cyclohexanone decachloroctahydro-l ,3,4-metheno-2H- cyclobuta[cdl-pentalen-2-one l-( 3-chlorallyl )-3 ,5 ,7-triazal -azonia-adamantan chloride coal tar and blast furnace tar MIXTURES mixture nickelsulphate-maneb mixture maneb-mercaptobenzthiazole mixture zineb-mercaptobenzthiazole mixture zineb-nickelous chloride mixture zineb nickelous sulphate mixture ziram-basic copper sulphate mixture ziram-zinc-mercaptobenzthiazole mixture thiram-cadmium chloride hydrate mixture thiram-hydroxy-mercury chlorophenol mixture thiram-phenyl-mercuri acetate mixture polyethylene-bis-thiuramsulphide-copper oxychloride mixture methylarsine-bis-( dimethyldithiocarbamate )-ziram-thiram cadmium dilactatethe reactions being carried out in either order of succession.
For example, thiophosgene may be reacted with the aniline and the resulting isothiocyanate, ARN=C=S, reacted with the amine of the formula III.
In the reverse order of succession a reactive derivative of the thiocarbonic acid may be reacted with an amine of the formula III, and the resulting isothiocyanate of the formula reacted with the aforesaid aniline.
In a more simple and known manner the isothiocyanate of the formula IV may be prepared by reacting 2,3-dichloropropylene-(1) with an inorganic thiocyanate, preferably an alkaline metal or ammonium thiocyanate. If desired the chlorallyl group may be saturated with C1 or Br either before or after the formulation of the thiourea grouping.
The following examples illustrate the invention, the parts being by weight:
Example 1 Manufacture of:
C1 1111- C NH CII 185 parts of 4-chloro-3-trifluoromethyl-aniline in 200 parts by volume of acetonitrile are added to 134 parts of [,B-chlorallyl] -isothiocyanate in 200 parts by volume of toluene and 0.1 part of triethylene diamine. After heating the mixture for 20 hours at C it is evaporated in vacuo to about 400 parts by volume, then diluted with petroleum ether (boiling at 5070C filtered and recrystallised from a mixture of toluene and petroleum ether (boiling at 5070C). The product melts at 1 l5116C (compound No. 1).
In an analagous manner the following compounds of the formula V were obtained:
'R NH 3 C Mi CH C CH Com R R R R; R Melting at pound No. C
2 H C1 C1 H H 81 83 3 H H H H H 93 95 4 H C H H H H 74 76 5 H CH H H H 86 87 6 H CF H H H 79 81 7 H CF H CF H 124 127 8 CH Cl H H H 107 108 9 C1 H NO H H 135 137 [0 Br H CH H Br 140 -141 11 H H C1 H H 97 98 12 H C1 H H H 101 103 13 H C1 CH; H H 92 93 14 H N0 C1 H H 114- 117 15 C1 H C1 C1 H 125 126 16 C1 H H C1 H 115 116 17 H H C H H H 1l3114 18 C1 C1 H H H 121 122 19 Cl H C1 H H 131 132 20 H C1 H C1 H 124 125 Melting at 125 126C (with decomposition) Gil-1r CH Br EXAMPLE 2 a. Dusting powder Equal parts of an active substance of the invention and precipitated silica were finely ground. By admixture with kaolin or talc there can be produced a dusting powder containing preferably 1-6% of active substance.
b. A sprinkling powder For preparing a sprinkling powder there are mixed together and finely ground, for example, the following components:
50 parts of the active substance of the invention parts of highly adsorptive silica parts of Bolus alba (kaolin) 3 5 parts of sodium benzimidazole-6,3-disulphonate 3.5 parts of the reaction product of p.tert.-
octylphenol and ethylene oxide.
l-benzyl-2-stearyl- 0. An emulsion concentrate EXAMPLE 3 In a greenhouse, Zucchetti plants were grown and sprayed once prophylactically with an aqueous liquor containing 0.1% of the active substance. Two days later the plants so treated were infected with spores of Erysiphe cichoriac'earum DC. After 12 14 days the plants treated with the test compound No. 1 showed an attack of 5% and the plants treated with compound No. 8 showed no attack, whereas the untreated control plants suffered a 100% attack.
EXAMPLE 4 A mixture of equal parts of quartz sand and alumina was inoculated with an aqueous suspension of conidia of Fusarium oxysporum, the mixture was charged into pots, and the pots were placed in a cabinet in a greenhouse. Two days later the pots were sown with melon seeds, and then an aqueous liquor containing a quantity of active substance No. 2 equivalent to a rate of kilogrammes per hectare was poured uniformly over the pots.
The pots were kept suitably moist. After 14 days 87% of the sown plants in the series of test treatments developed healthily, whereas 6% developed in the untreated control pots.
EXAMPLE 5 Compound No. Action 9 100% I4 100% I5 100% I6 100% l7 l0()% In an analagous test with vine shoots as test plants and Borrvn's cinerea as test mould, compounds Nos. 21 and 22 each gave a 95% kill. Their action was systemic.
In an analagous test with celery (Apium graveolens) as test plant and Septoria apii as test mould, compounds Nos. 3, 4 and 5 gave a kill of 80% and respectively.
EXAMPLE 6 The active substances of the formula (1) exhibit a remarkably strong action against gram-positive bacteria, especially against staphylococci and streptococci.
The antibacterial activity was determined in dilution tests as follows:
BACTERIOSTASIS AND BACTERICIDIC 20 mg of active substance were dissolved in 10 ml propylene glycol, of which 0.25 ml were added to 4.75 ml of sterile glucose broth, and then diluted 1 10 in small tubes. These solutions were then inoculated with a bacterium and incubated for 48 hours at 37 C (bacteriostatics). After a test period of 24 hours 1 oese (drop) of these cultures was stroked on glucose-agar plates and incubated for 24 hours at 37 C (bactericides). After the stated periods the following limiting concentrations were measured in parts per million of the bacteriostatics or bactericides:
Bacterium Compound No.2 No.7 No.6 No.9 No. 11 12 Trich.menta- 2.5 2.5 30 2O 20 20 grophytes E. coli 20 20 30 60 40 Asp.niger 60 Staphaureus 2.5 0.3 5.5 3 20 25 No.13 No.15 No.16 No.19 No.20 Trich.menta- I0 20 30 30 5 grophytes E.coli 30 3O 20 Asp.niger 60 Staphaureus l0 2 20 30 0.6
means not tested.
Determination of the minimum inhibiting concentration (MIC) against bacteria and moulds in the gradient plate test.
The compounds of the formula 1. were mixed in the form of suitable formulations (for example, as solutions in dimethyl sulphoxide) of definite concentration with warm brain heart infusion agar (bacteria) or mycophil agar (moulds). The liquid mixtures were poured onto a solidified wedge-shaped base layer of agar, and allowed to solidify.
By means of a Pasteur pipette the test organisms were applied in the form of lines perpendicularly to the gradient. After an incubation period of 24 hours at 37C. (bacteria), and 72 hours at 30C. (moulds), the lengths of the germinations grown on the lines of inoculation were measured and expressed in parts per million of active substance.
Com- Minimum inhibiting concentration in ppm. pound Nov Bacteriostasis Fungistasis Staphylococcus Asper- Tricho- Tricho- Epidermo- Micro aureus gillus phyton phyton phyton sporum niger mentagro rubrum floccosum gypseum -phytes l 0.4 60 0.8 5.5 20
I claim: 10 4. The method according to claim 2 in which R and 1. A method for controlling bacteria comprising ap plying to an area infested with said bacteria a detergent or cleaning composition comprising bacteriostatically effective amount of a compound of the formula in which each of R R R R and R is hydrogen, chlorine, bromine, nitro, alkyl of from 1 to 4 carbon atoms, or trifluoromethyl.
2. A method according to claim 1 in which the compound is in which two of R R and R are chlorine or trifluoromethyl, and the other of R R and R is hydrogen.
3. The method according to claim 2 in which R is trifluoromethyl, R is chlorine, and R is hydrogen.
R are chlorine, and R is hydrogen.
5. The method according to claim 1 in which, in the compound, R R R and R are hydrogen, and R is trifluoromethyl.
6. The method according to claim 2 in which R and R are trifluoromethyl, and R is hydrogen.
7. The method according to claim 1 in which, in the compound, R, is chlorine, R R and R are hydrogen, and R is nitro.
8. The method according to claim 1 in which, in the compound, R R R and R are hydrogen, and R is chlorine.
9. The method according to claim 1 in which, in the compound, R R R. and R are hydrogen, and R is chlorine.
10. The method according to claim 1 in which, in the compound, R R and R are hydrogen, R is chlorine, and R is methyl.
11. The method according to claim 1 in which, in the compound, R R and R are hydrogen, R is nitro, and R is chlorine.
12. The method according to claim 1 in which, in the compound, R R and R are chlorine, and R and R are hydrogen.
13. The method according to claim 1 in which, in the compound, R and R are chlorine, and R R and R are hydrogen.
14. The method according to claim 1 in which, in the compound, R and R are chlorine, and R R and R are hydrogen.
15. The method according to claim 2 in which R and R are chlorine, and R is hydrogen.
|Cited Patent
|Filing date
|Publication date
|May 26, 1955
|Aug 5, 1958
|Monsanto Chemicals
|Bactericidal nu-(2-3 dichlorallyl-3-halophenyl) ureas
|Jul 23, 1956
|Jul 14, 1959
|Monsanto Chemicals
|Diphenyl urea derivatives
|Jun 4, 1962
|Aug 10, 1965
|Ciba Ltd
|Treatment of synthetic products, especially synthetic fibers
|Mar 9, 1966
|Jul 30, 1968
|Ciba Ltd
|Method of combatting insects with phenyl-thiourea compounds
|Dec 12, 1968
|Dec 8, 1970
|Ciba Ltd
|Preparations containing urea or thiourea derivatives for use as molluscicides
|Oct 23, 1969
|Aug 22, 1972
|Armour & Co
|N-acyl-n{40 -(halogenated aryl ureas as antibacterial agents)
|May 8, 1972
|May 21, 1974
|Ciba Geigy Ag
|Antimicrobial treatment of fibre products with phenylthioureas
|Citing Patent
|Filing date
|Publication date
|Sep 30, 1988
|Jul 31, 1990
|Ppg Industries, Inc.
|Fungicidal and algicidal detergent compositions
|Dec 28, 1992
|Nov 29, 1994
|Little Chemical Company
|Detergent with cleaning and waste water treating capabilities containing polyacrylate and dimethylthiocarbamate
|Sep 13, 1993
|Oct 17, 1995
|Liang; Paul M. S.
|Method of producing antibacterial fibers
|May 16, 1995
|Mar 30, 1999
|Bayer Corporation
|Universal rinse reagent and method for use in hematological analyses of whole blood samples
|May 30, 2003
|Dec 23, 2004
|Symrise Gmbh & Co. Kg
|Use of dihydroxyphenylmethane derivatives, e.g. styrylresorcinol, for control of microorganisms that cause dandruff, body odor, acne and mycoses
|Oct 30, 2015
|May 6, 2016
|Universite De Haute-Alsace
|Use of bismuth subsalicylate or one of the derivatives thereof as a phytopharmaceutical agent
|U.S. Classification
|514/585, 510/383, 510/382, 510/389, 514/586, 510/319
|International Classification
|Cooperative Classification
|European Classification


text:
New Junior Cycle Science subject specification
Please note that the meeting below has been cancelled to abide by the ASTI and TUI directives.
Yvonne Higgins, ISTA Rep on the NCCA Junior Cycle Science development group, will give a presentation on the new Junior Cycle Science subject specification, on Tuesday, 4th November from 7-9pm. The JC Science subject specification is due to open for consultation on the 25th September, and will be available for viewing on the NCCA website after that date,
Junior Certificate Science 2014 Marking Scheme Meeting
Wednesday, 15th October, 7:30pm, Eureka Centre, UCC.
Maths Week Ireland 2014 October 11th-19th
Maths Week Ireland 2014 will take place from 11th – 19th October. It continues to be the largest festival of its kind in the world. In 2013 over 200,000 participated throughout the island of Ireland.
Junior Certificate Science "Magic Demonstration"
The Monaghan Branch are hosting a Junior Certificate Science "Magic Demonstration" presented by Mr. John Daly on Wednseday 8th October at 7:30pm in Loreto College, Cavan. A "materials pack" of bits and pieces will be presented to the first 15 teachers who register for this event.
Light and Sound
Presentation on Light and Sound with over 30 demonstrations of key concepts.
Date: Wednesday, October 8th
Time: 7pm
Venue: Blackrock College
Whether you're a beginner or an expert there will be something new to learn. All members are welcome.
October Council Meeting
The October Council Meeting will be held at 1.30pm in Collins Barracks on Oct 4th. All Branches are required to send one representative.
Junior Cert Science Exam
A discussion of the 2014 Junior Cert. Science exam will be held on Thursday, 2nd October, from 7-9pm in Sligo Education Centre. All science teachers are welcome. All those who wish to attend, please forward your details to email@example.com.
Review of Leaving Cert Chemistry Paper
The Kerry Branch will hold a discussion on the assessment and marking scheme of the Leaving Cert Chemistry exam on Wednesday, the 1st of October @ 8pm in the Education Centre Tralee. All welcome. Please confirm attendance by email to email@example.com
Review of LC Marking Schemes Galway
The Galway Branch are holding a review of LC Biology, Chemistry or Physics marking scheme on Wednesday October 1st in NUI Galway Education Building on the main campus. This event will run from 7 - 9 pm. Please bring a copy of the relevant marking scheme with you.
IoPI - Frontier of Physics 2014
The Frontiers of Physics Annual Conference for Teachers of Physics, including Junior Science Teachers will take place on Saturday 27th September in the School Of Physical Sciences, DCU.

subset: commoncrawl


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5 Things To Know This AM
This interview is the closest thing we'll ever get to a talk show of life musings with Arizona Muse. (Into The Gloss)
Press is great for a fashion show, but you might as well consider a collection basket if Carmen Dell'Orefice isn't smiling. (Dodge & Burn)
My, oh my, how the Sony Walkman has grown. (Hypebeast)
The whole sportswear as high-fashion trend has a name, and it's pretty much unpronounceable. (SHEfinds)
Hello, Paris! These 10 designers are headed to the City of Lights under the CFDA/Vogue fund. (WWD)
- Politics | Arizona Muse Into The Gloss Interview
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US News
The Doctor Keeping Abortion Accessible
The legal right to a safe abortion is slowly disappearing in parts of America. And it's doctors like Willie Parker who are standing up to defend the ...
Lilli Petersen
May 20, 2016
US News
#TBT Big Moments In Women's History
Women around the world today are running countries and companies. They are challenging the status quo with their revolutionary ideas, writings, and designs. They are activists and Nobel Peace Prize winners, and they can be found battling on the front lines of war. Refinery29 is honoring these accomplishments by looking back...
Jenifer Fenton
May 26, 2016


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Beyoncé Buys $3,500 Worth of SandwichesThat's a lot of bread.
Hillary Clinton Tells Taylor Swift Beyoncé's 'Lemonade' is 'Great'On 'Ellen,' Taylor Swift asked Hillary Clinton, "Have you seen Lemonade, and did you like it?"
Beyoncé Weathers Lightning Storm, Pays Tribute to Prince in MinneapolisA whopping 35,000 fans that filled the TCF Bank Stadium were evacuated until the storm passed.
Did Beyoncé and Jay Z Finish Their Joint Album?The world will get a musical response to 'Lemonade.'
This Beyoncé Inspired Prom Dress is Spot OnThe high school senior recreated the bejeweled look, even styling her hair to match Beyoncé's blonde ponytail.
High School Student Recreates Beyoncé's Met Gala Dress for PromThe dress was recreated out of a mesh material and rhinestones from the craft store Michael's!
Beyoncé Poses with Father Matthew KnowlesBey's mother Tina Lawson posted a cute photo of Beyoncé and father hanging out during a Formation Tour in Houston.
Meghan Trainor on Why She Admires Beyoncé"She's at a place where she does whatever she wants."
Ellen DeGeneres Parodies Beyoncé's 'Lemonade'Wanda with the good weave cameos.
Cars Abandoned on I- 15 as Fans Flee Gridlock for Beyoncé's 'Formation'It didn't matter that San Diego Police Department was nearby, it didn't stop the foot traffic.
Michael Brown's Mother Says Beyoncé Made Her 'Look Regal'"She was wholeheartedly sympathetic, and she talked, she cried, and she shared some things with us."
3 Ways Desert Trip Can Top Itself in 2017This year, the Beatles, the Stone, the Who and Pink Floyd are represented, plus they have Dylan (and Neil Young). Here's what they should do next year.


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UFC middleweight champion and icon Anderson Silva was in attendance prior to UFC 154 kicking off to speak with the media about his plans for 2013.
The champion spoke about a lot of possibilities, but mainly he focused on a super fight against UFC welterweight champion Georges St-Pierre.
If St-Pierre is successful against Carlos Condit on Saturday, all signs are pointing towards a super fight between Silva and the welterweight champion in 2013.
The interesting addition to Silva's talk was his new opinion on a potential match-up with UFC light heavyweight champion Jon Jones.
In the past, both Silva and Jones have declined the possibility of the fight happening, but now the Brazilian legend says if the UFC wants it, then he'll do it.
Check out the video interview below with UFC middleweight champion Anderson Silva:
[embedded content]
When Jon Jones compared himself to Tiger Woods, he replied, "You can't really compare me to Tiger Woods because I've been messing up a lot longer." read news >>
Light heavyweight champ Daniel Cormier and former titleholder Jon Jones will rematch at UFC 200. Cormier says he's not changing his game plan from their first fight. read news >>
Daniel Cormier, be careful what you wish for. Sometimes dreams come true. For Cormier, that day comes at UFC 200. He'll get one more chance to prove that he can beat Jon Jones, widely considered the read news >>
Relive the first match-up between Jon Jones and Daniel Cormier at UFC 182 before their heated rivalry hits the Octagon again at UFC 200. read news >>
UFC light heavyweight champ Daniel Cormier says stem cells have his injured leg on the mend. His only UFC 200 stumbling block? Himself. read news >>
Forget the talk of battling teammates, Arlovski is focused on task at hand vs Overeem this Sunday read news >>
Go inside the training camps of a legend and rising star as they prepare for UFC 198: former middleweight champion Anderson Silva and Uriah Hall. read news >>
Undefeated bantamweight prospect Cristobal Chavez is keeping it simple and focused heading into Monday's Combate Americas 5. read news >>
UFC lightweight champion Rafael dos Anjos enters his fight camp in Singapore, not shying away from Conor McGregor, but he is laser-focused on Eddie Alvarez. read news >>
Former UFC middleweight champion Anderson Silva has been forced to pull out of his UFC 198 bout with Uriah Hall. read news >>


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- Verlander shines, Rodriguez earns 400th save in Detroit win Updated: May-24-16 11:04 pm
DETROIT - After joining some impressive company with his 400th save, Francisco Rodriguez felt all sorts of emotions.
- Herrera benched over hustle as Phillies fall 5-4 to Tigers Updated: May-24-16 12:00 am
DETROIT - Odubel Herrera had three hits and still ended up being benched.
- Tigers beat Rays 9-4 but Zimmermann, Cabrera hurt Updated: May-22-16 8:50 pm
DETROIT - Jordan Zimmermann and Miguel Cabrera helped Detroit to a comfortable lead - then they both had to leave with injuries.
- Archer hit hard as Rays fall 9-4 to Tigers Updated: May-22-16 6:07 pm
DETROIT - Chris Archer is hoping this latest start was merely a minor setback.
- Verlander reaches K milestone, helps Tigers beat Twins 6-3 Updated: May-18-16 6:30 pm
DETROIT - Justin Verlander, sporting a scruffy beard on his 33-year-old face, chuckled when the Detroit Tigers showed a video montage of some of his significant strikeouts during a career that started more than a decade ago.
- Scherzer has 20 Ks, ties MLB record as Nats top Tigers 3-2 Updated: May-12-16 12:40 am
WASHINGTON - Max Scherzer has thrown two no-hitters, come within one strike of a perfect game and met just about every expectation that accompanied the $210 million contract he signed with Washington.
- Tigers succumb to Scherzer's 20 Ks, lose 3-2 to Nats Updated: May-12-16 12:36 am
WASHINGTON - In five seasons with the Detroit Tigers, Max Scherzer pitched well enough to make two All-Star teams, win the 2013 AL Cy Young Award and lead the league in wins in back-to-back seasons.
- Brantley, Napoli lead Indians to sweep of Tigers, 9-4 Updated: May-05-16 10:50 pm
CLEVELAND - Indians manager Terry Francona knew it was only a matter of time until Michael Brantley had a big game.
- Saltalamacchia lifts streaking Tigers over Twins, 6-5 Updated: May-01-16 7:33 pm
MINNEAPOLIS - Not long ago, the Tigers were left reeling after a three-game sweep by the visiting Indians. One week later, Detroit is heading into Cleveland with a five-game winning streak.
- Anthony Gose doubles, homers to lead Tigers over A's 7-3 Updated: Apr-28-16 8:03 pm
DETROIT - Detroit Tigers right-hander Anibal Sanchez thinks he is getting closer to finding the mechanics that deserted him last year.
- Indians overcome Carrasco injury, sweep Tigers Updated: Apr-24-16 5:44 pm
DETROIT - Cleveland manager Terry Francona would normally be happy with a sweep in Detroit, but he had more pressing matters on his mind Sunday afternoon.


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...I have many years of experience in math from basic elementary math to university level calculus. I have a good understanding of concepts and teach students rather than having them memorize problems. I played football for 4 years throughout high school.
Houston, TXView Tutor
...I am currently teaching young children in the Salvation Army's after school program which has proven to be a success in converting the amount of kids failing in school into kids acing subjects. The kids would be between pre-k to 8th grade so I have experience in teaching all sorts of ages. If your interested please email me.Algebra 1 is the most common course that I am teaching right now.
Houston, TXView Tutor
...I studied chemistry at Oberlin College, and then went on to earn both a Master's degree and PhD in physical chemistry from Yale University. After that, I taught chemistry at Southwestern University for two years. I recently moved to Sugar Land, and am looking for a way to continue working with students in a part-time capacity.
Sugar Land, TXView Tutor
...If you have any please ask! I'm happy to answer them.I studied differential equations for my undergraduate mathematics degree at the University of St. Thomas.
Houston, TXView Tutor
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Sugar Land, TXView Tutor


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Ali Haider Gilani denies speaking in favour of Sharia law enfo...The freed son of former prime minister Yousaf Raza Gilani has rejected media reports alleging he is in favour of enforcing Sharia law in the country. Disappointed over media reports, Ali Haider Gilani told a local media outfit his statements had ... Pakistan Today, 1 week ago
Ali Haider Gilani rebuts story quoting him in favour of Sharia law enforcement - The Express Tribune, 1 week ago
How the abducted son of the former Pakistani PM was rescued - Asia Times Online, 1 week ago
16 images for yousaf raza gilani
Half-brother refutes Headley link with Gilani
Pakistan former PM Yousaf Raza Gilani and David Headley Stating that he was not aware of his sibling's links to Lashkar -e-Toiba, David Headley's half-brother Daniyal Gilani has said any attempt to draw links to his family, or former PM Yousaf Raza ...Indian Express, 2 months ago
Nawaz visits Gilanis, discusses Panama issue
LAHORE - Prime Minister Nawaz Sharif yesterday visited former Prime Minister Syed Yousaf Raza Gilani at the latter's Defence residence to discuss the government-opposition row over the Panama leaks issue. The prime minister went to the Gilani ...The Nation Pakistan, 1 week ago PM Nawaz visits Gilani House to congratulate Haider Gilani's ... The Nation Pakistan, 1 week ago PM Nawaz arrives at Yousaf Raza Gilani's residence in Lahore Pakistan Today, 1 week ago PM greets Gilanis on Ali Haider's safe return Pakistan Observer, 1 week ago
More from: Pakistan TV, Arab News...and 3 other sources
Shehbaz greets Gilani on Haider's recovery
LAHORE - Punjab Chief Minister Shehbaz Sharif called on former Prime Minister Syed Yousaf Raza Gilani at his Defense residence yesterday. He congratulated Gilani and his family on safe recovery of Ali Haider Gilani after three years. Abdul ...The Nation Pakistan, 1 week ago Gilani greeted on son's return The Nation Pakistan, 2 weeks ago Punjab CM arrives at Gillani House, greets Yousaf Raza over son's recovery Dunya News, 1 week ago CM congratulates Gilani Pakistan Observer, 2 weeks ago
Gilani gets 10-day protective bail
ISLAMABAD - The Islamabad High Court yesterday granted ten-day protective bail to former prime minister Syed Yousaf Raza Gillani in five corruption cases related to the Trade Development Authority of Pakistan (TDAP) scandal. A single bench of ...The Nation Pakistan, 2 weeks ago Gillani gets bail: Ex-PM gets protective bail in new TDAP cases The Express Tribune, 2 weeks ago IHC grants protective bail to Gillani, his accomplice till May 23 Pakistan Today, 2 weeks ago
Want to cooperate with other parties over Panama Leaks issue: PM Nawaz
PM Nawaz visited Yousaf Raza Gilani's house, felicitated him on son's recovery LAHORE (Dunya News) Prime Minister (PM) Nawaz Sharif on Saturday visited the house of ex-PM Yousaf Raza Gilani in Lahore and congratulated him on his son Ali ...Dunya News, 1 week ago PM Nawaz visits Yousaf Raza Gilani's house, felicitates him on son's recovery Dunya News, 1 week ago
Steven Spielberg wants to make film on ex Pak PM Gilani's son rescue
Hollywood legend Steven Spielberg has offered to make a movie on the abduction and recovery of former Pakistani premier Yousaf Raza Gilani's son Ali Haider, who was rescued from Al Qaeda-linked abductors in Afghanistan this week. Spielberg made ...Hindustan Times, 2 weeks ago Steven Spielberg offers to make movie on Ali Haider Gilani's captivity The Express Tribune, 2 weeks ago Spielberg to make a movie on Pakistan's ex PM's son? Times of India, 2 weeks ago
On one page: PPP to support PTI's anti-corruption drive in Sindh
Former prime minister says politicians should be open to corruption probes Former prime minister Yousaf Raza Gillani. PHOTO: AFP MULTAN: Leaders of the Pakistan Muslim League-Nawaz could sidle up to the military establishment and ...The Express Tribune, 1 month ago Two former prime ministers put on ECL Pakistan Today, 3 weeks ago South Asian ex-Prime Ministers Forum formed to strengthen ... The Nation Pakistan, 2 months ago
ECL: LHC to hear Musa Gilani's petition today
LAHORE: Justice Mamoon Rashid Sheikh of the Lahore High Court on Monday gave counsel daytime to submit arguments on a petition by former MNA Ali Musa Gilani, the son of former prime minister Yousaf Raza Gillani, seeking removal of his name from the ...Daily Times, 1 month ago Petition against MQM chief adjourned indefinitely The Nation Pakistan, 1 month ago Exit control list: Gillani's counsel asked to present arguments The Express Tribune, 1 month ago
Indian interference in Balochistan not new: Gilani
RAHIM YAR KHAN The interference in Balochistan by the Indian intelligence agency had been continuing for many years, former prime minister Yousaf Raza Gilani said. Talking to the media men after arriving at Sheikh Zayed International Airport here ...The Nation Pakistan, 1 month ago
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Yoga, Breast Cancer & Something Magical
Even though I'm not a big fan of yoga somehow my favorite event of the year is the biggest annual yoga outdoor class in the city. How is that? Hmmmm. It's standing with over 2-thousand women on the Philadelphia art museum steps and stretching our arms to the sky all at the same time. It's […]
AmerisourceBergen Leadership Conference
I Dare Me Keynote Charlotte, North Carolina
The Renaissance Ball CCFA
The premier fundraising event for the Philadelphia/Delaware Valley Chapter of the Crohn's & Colitis Foundation of America (CCFA). Emcee
Women's Resource Center Leadership Luncheon
Crystal Tea Room 11am-2pm Emcee


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Burlington airport busier than 2012THE ASSOCIATED PRESS | November 11,2013BURLINGTON The passenger count of people boarding flights at the Burlington International Airport was up 6.7 percent in October from a year earlier, but still off from other recent years.
For the month, 58,359 passengers boarded flights leaving Burlington, up from 54,916 in October 2012.
But figures from the airport show that more than 60,000 people boarded in Burlington every year from 2006 to 2011, with a peak of nearly 70,000 in 2008.
October was the second busiest month so far this year at the airport, topped only by August, when 61,325 people boarded planes.MORE IN Vermont NewsMONTPELIER Gov. Full StoryTwo weeks before Puerto Ricos primary, Democratic presidential candidate Bernie Sanders said a... Full Story
Fugitive captured after traffic stop
WILLISTON — Police have... Full Story
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You can enjoy the best panoramic view from this mountain lodge, which is located at the edge of the wood in the Val di Sole1/21Holiday in the mountains
Italian Alps | Here you can enjoy the mountain panorama directly outside your front door. Mountain lodges are the ideal accommodation to experience the alpine landscape up close.
Per week from GBP 221show 37 offers
2/21Best holiday resort Italy
Rome | There could not have been a more prominent winner! The Italian capital has received the best reviews from our customers, and is therefore the best holiday resort in Italy.
Per week from GBP 294show 524 offers
Secluded country house for up to 12 people in Tuscany.3/21Holiday with your own pool
Italy | Give your Italian holiday the perfect touch in a holiday home with its own pool: Splash about with the whole family in the water or let yourself completely relax.
Per week from GBP 348show 5,183 offers
Holiday apartment for max. 16 persons on the Italian Adriatic Coast4/21Italian country estate
Italy | The best way to enjoy "la dolce vita" is on a tenderly restored country estate which in past times was used for agriculture.
Per week from GBP 343show 732 offers
This castle by the sea on Sicily promises a truly special holiday.5/21This is a holiday home?
Italy | If you're searching for medieval castles, stately homes and other unusual accommodation, you have come to the right place.
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Italian Alps | Cabin holiday
From GBP 221
Rome | Best holiday resort Italy
From GBP 294
Italy | Holiday with your own pool
From GBP 348
Italy | Vacation on an country estate
From GBP 343
Italy | This is a holiday home?
From GBP 191
If vacation had a name
Italy | The country in the shape of a boot south of the Alps captivates especially by its diversity. Whether you would like to go on a culture holiday, a vacation at the seaside, a culinary journey or a sportive experience tour you can choose between the snowy mountain tops of the Alps, the soft rolling hills of Tuscany, the sunny Campania and the sub-tropical Sicily there is something on offer throughout the year.
You will surely find your favourite accommodation amongst the around 28,000 holiday apartments and houses which atraveo offers in Italy. Discover the spirited country south of the Alps and take your time to choose your dream holiday home in your favourite region.
atraveo customers enjoy especially the beautiful Tuscany, the pulsating Adriatic Coast as well as Lake Garda. Especially popular are also the two large Italian islands Sardinia and hot Sicily. Active holiday makers favour particularly South Tyrol – during summer the peaks and valleys of the Alps and Dolomites are ideal for hiking, climbing or mountain biking and during the winter the snowy hillsides and slopes entice numerous winter sports enthusiasts.
More tips for the search for great holiday houses: The sunny Campania, the beautiful Calabria, the colourful Italian Riviera along the Ligurian coast and the Upper Italian lakes such as Lake Maggiore or Lake Como. You can find more information on Italy in our blogs.
Reviews from our customers
This is how holiday rental owners described Gignod
The 55 hamlets ...
show more that make up the municipality are dotted around the foot of the Punta Chaligne.
Some of its more significant monuments include the stumpy square tower dating to around the XI century and the parish church of Sant'Ilario, from the XV century with its solid bell tower and double lancet opening. Inside the church is a particularly significant baroque main altar; the interesting cycle of frescoes from the end of the XV century are also of some worth and possibly represent one of the most important expressions of Aosta painting at that time.
The "Fête du Teteun" is held on the second last Sunday in August in Gignod and is a gastronomic event where you can taste an unusual local dish: cattle udder cleverly prepared and served up in slices is a delicious cured meat that is not readily available for sale.
Gignod is the capital in Valle d'Aosta of the "Pétanque" , a variation on the game of boules typically played in French countries.
In Arsanières you will find an excellent 9 hole golf course, on a natural slope where golf lovers can practice their sport in a particularly scenic spot.
Gignod is located on the road of the ancient Via Francigena, a route that was recently upgraded, dedicated to excursionists in search of old paths taken firstly by the Salassi, then the Romans followed by pilgrims in Medieval times heading to Rome.
In winter and springtime, those who enjoy Alpine skiing can go on excursions from Buthier (1370 m) to Punta Chaligne (2608 m), considered one of the classic destinations of this sport.
For mountain-bike lovers, as well as the various interstate roads, there is also a pleasant route running alongside the forests at the start of the hamlets.
The excursions to Punta Chaligne, Cresta Tardiva (2380 m) and the ascent up Mont Fallère (3061 m), are scenic and enjoyable, as are the numerous walks that can be taken along the network of marked paths.
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Neighbouring holiday resorts Gignod
Property no. 966037
from GBP 343for 1 week
Gignod, Aosta Valley (Gran Paradiso)
Holiday apartment for max. 4 personsApprox. 40 m², 1 bedroom, 1 bathroom, pets are allowed (max. 3), digital TV, Internet, WLAN, washing machine, dishwasher
Property no. 984400
from GBP 343for 1 week
Gignod, Aosta Valley (Gran Paradiso)
Holiday apartment for max. 4 personsApprox. 40 m², 1 bedroom, 1 bathroom, pets are allowed (max. 3), digital TV, Internet, WLAN, washing machine, dishwasher
Property no. 916586
from GBP 388for 1 week
Gignod, Aosta Valley (Gran Paradiso)
Holiday apartment for max. 2 adults + 4 childrenApprox. 50 m², 1 bedroom, 1 bathroom, pets are allowed (max. 2), digital TV, Internet, WLAN, washing machine, dishwasher
Property no. 605533
from GBP 434for 1 week
Gignod, Aosta Valley (Gran Paradiso)
Holiday apartment for max. 4 personsApprox. 40 m², 1 bedroom, 1 bathroom, pets are allowed (max. 2), satellite TV, Internet, WLAN, washing machine, dishwasher, non-smoking, sauna, communal swimming poolThere are 5 further property types with 5 accommodations for this complex
- from GBP 510/week Holiday apartment for max. 6 persons, approx. 70 m², 1 bedroom, property no. 408746 Preview
- from GBP 358/week Holiday apartment for max. 2 persons, approx. 33 m², 1 bedroom, property no. 650484 Preview
- from GBP 358/week Holiday apartment for max. 2 persons, approx. 33 m², 1 bedroom, property no. 794215 Preview
- from GBP 510/week Holiday apartment for max. 5 persons, approx. 70 m², 2 bedrooms, property no. 393121 Preview
- from GBP 434/week Holiday apartment for max. 4 persons, approx. 40 m², 1 bedroom, property no. 686074 Preview


text:
Lease Finance Group - They are a scam
- Phoenix, Arizona
- Jul 20, 2010
- 253 views
- 2 comments
This place is a scam!!!!Do NOT sign a lease with this company.They will take money out of your account without telling you.
If your bill is due then the day its due they will call EVERY number they have on file for you about 12 times each, all day, its crazy!! You cant terminate the lease even if your no longer accepting credit cards.
You can buy it out for your monthy charge (which is about $79 a month) TIMES the number of months left on the lease.The employees are rude and when you have a complaint about something they act like they've heard it a million times.Report
More Review Details
- Monetary loss:
- $4
- Product or service
- Credit Card Equipment
- Review category
- Cards
- Review rating
- 4 out of 5
Oct 03, 2011
This company started sending me notices in May 2001 after I closed my bank account. Because the a man name Jason Branch of Kansas City Missouri and a company named For Him Processing in Kansas were supposed to set up an Internet business for me and several hundred other victims.
I never received any equipment. However Lease Finance Group continued to bill me in spite of me contacting them with my complaint advising that I never received any equipment and reporting that an application was sent through that I had previously voided out with Jason Branch.Â
I refused to pay this lease because to my knowledge there was no application, because I withdrew it in less than 24 hours. This showed up on my credit report and was still on it until in March 2008 as charged off as bad debt. It showed a closed date of Feb. 2002.
I recently started getting notices from Pushpin Holdings LLC. I immediately went on line and found hundreds of complaints. I'd advise anyone who is getting these notices to refuse to pay them. According to the BBB in April 2011 they received their first complaint about Pushpin. Know your rights!
Nov 14, 2010
That is fraudulent because the signiture should
be on the last page but the the first page . I think there will be class action suite against
LFG in N.Y. soon
You will be able to edit the text before publishing.
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Sold > LA > New Orleans > 70115 > Central City > 1719 7th St
1719 7th St New Orleans, LA 70115 (Central City)See your commute times
- Multi-Family Home
- Lot size: 4,340 sqft
- Edit Home Facts
Property Details for 1719 7th St
Description provided by Trulia
This is a Multi-Family Home located at 1719 7th Street, New Orleans, LA. The property has a lot size of 1. The average list price for similar homes for sale is $834,900. This property is in the Central City neighborhood in New Orleans, LA. The average list price for Central City is $188,539.
Public Records for 1719 7th St
Official property, sales, and tax information from county (public) records:
- Lot Size: 4,340 sqft
- County: Orleans
|Listing price for 1719 7th St
|Average listing price for similar homes
|0% below listing price
|Average listing price for all homes in Central City
|0% below listing price


text:
WASHINGTON President Barack Obama and southeast Asian leaders launched an initiative aimed at expanding trade and investment ties between the United States and 10 countries in southeast Asia, the White House said on Monday.
The countries announced the start of the process at a meeting of the Association of Southeast Asian Nations, or ASEAN, in Cambodia, where Obama is visiting Phnom Penh for a regional summit.
Actions outlined in the initiative - the U.S.-ASEAN Expanded Economic Engagement - are aimed at smoothing a path for Asian nations to link up with the Trans-Pacific Partnership, a trade agreement the United States is negotiating with ten countries in Asia and the Western Hemisphere, the White House said.
The joint action could also help Washington solidify its presence in a complex mosaic of regional trade and economic alliances in an economically vibrant region attractive to many U.S. businesses.
By seeking to open the door to the U.S.-led Trans-Pacific Partnership (TPP), the United States is keeping pace with another regional grouping - the Regional Comprehensive Economic Partnership (RCEP) - that is forming among southeast Asian nations and other countries in the region, including China and India.
Generally, that arrangement is expected to be less ambitious than the U.S.-led partnership and there is some concern that if the Washington's demands are too stringent, countries may lose interest in the TPP in favor of the RCEP.
Four members of ASEAN are part of the Trans-Pacific Partnership - Singapore, Brunei, Malaysia and Vietnam.
For its part, the Regional Comprehensive Economic Partnership includes Japan, South Korea, Australia, New Zealand, and the ten ASEAN members - but not the United States.
"ASEAN is the United States' fourth largest export market and fifth largest trade partner," the White House said in a statement. "ASEAN's continued rapid economic development creates opportunities for U.S. exports."
The United States also wants to broaden the reach of the Trans-Pacific Partnership to include ASEAN countries that are not part of the 21-economy Asia Pacific Economic Cooperation forum. These are Cambodia, Laos, and Myanmar.
Under the Expanded Economic Engagement initiative, participating countries will negotiate simplified customs procedures, and common investor protection and business conduct principles, the White House said.
ASEAN members are Brunei, Cambodia, Indonesia, Laos, Malaysia, Myanmar, the Philippines, Singapore, Thailand, and Vietnam. (Reporting by Mark Felsenthal; editing by Christopher Wilson)
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Denny's does it right. Kelly F. teaches them how and keeps them on there toes. Kelly knows the meaning of going the extra mile, especially when no one is watching. I usually come in for my weekly healthy brunch that Kelly always makes sure is just right while keeping m...moree filled on coffee and water. Last Saturday I noticed that she was down under the table across the aisle from me collecting a few food things one of the previous occupants, a little girl, had misplaced. The vacuum couldn't pick these up so Kelly picked them up to present a nice clean under table area to adjacent dinners. That's going past the extra mile. Kudos to Kelly F. This is just one more example of her excellent serving skills that she demonstrates every time that she is on duty. Denny's and we the customers are lucky to have her. Gene Gene Rossano Best Dry Cleaners FL 425 Laurel Rd E Nokomis FL 34275 941-518-6906 email@example.com http://www.BestDryCleanerFL.com On Facebook at, geneatbest On Twitter at, geneatbestview less
Venice Luna Restaurant
1. Luna RistoranteMenu
This is a CASH ONLY Restaurant! Every Meal is HUGE, some of these portions can feed up to 4 people. Especially the Lasagna & the Salad, MY GOD - …
2. Bella Luna Cafe of Venice
200 Miami Ave WVenice, FL 34285
3. Luna Pizza - CLOSED
4. Bella Luna Italian Restaurant
I recently visited Bella Luna on my vacation to punta gorda and I was extremely pleased. The atmosphere is wonderful. My appetizer, fried calamari, …
5. Bella Luna
Stopped in for dinner on May 5, 2011. Waitrwss was fantastic, food was fresh and cooked to perfection! Had the Fra Deavilo which was fresh and cooke…
6. Latte LunaMenu
2715 Manatee Ave WBradenton, FL 34205
7. Red LobsterMenu
6747 S Tamiami TrlSarasota, FL 34231
From Business: Fresh is in our food: Each day, you'll find an updated selection of fresh fish on our Today's Fresh Fish menu, not to mention live Maine lobster, freshly baked Ched…
8. Olive Garden Italian Restaurant
I love Olive Garden have ever since 1994 when I was still married to my children's dad & we had come home on leave from Jacksonville, N.C where he w…
9. Demetrio's Pizza HouseMenu
Real nice atmosphere both buffet and salad bar and They even make your kind of pizza and put it on the buffet now thats my kind of a Restaurant!!
10. Defina's Italian RestaurantMenu
1965 Tamiami Trl SVenice, FL 34293
11. Cassariano Italian EateryMenu
From the service, to the short term waits, to the impeccable dishes... Cassariano's is a Venice institution not to be missed. We ordered the Salmon …
12. Panificio South Venice
4191 Tamiami Trl SVenice, FL 34293
13. Jacksons American Grill - CLOSED
117 W Venice AveVenice, FL 34285
14. Ristorante San Marco
305 B W Venice AveVenice, FL 34285
From Business: San Marco invites you to experience Authentic Italian Dining. Our menu features fresh vegetables, meats, and seafoods, as well as homemade pastas and freshly baked …
15. Ivy Steak HouseMenu
We not only had bad service and met rudi and indifferent staff, the fook was buffet quality and not served hot.
16. Fox's Pizza DenMenu
2045 Tamiami Trl SVenice, FL 34293
17. Cafe Italia Of Venice
900 Venetia Bay BlvdVenice, FL 34285
18. ItalianosMenu
What a shame that this terrific pizza operation seem to be drifting and in need of some magement. One 20 inch pepperoni every Friday night and the q…
19. Art Caffe
390 Nokomis Ave SVenice, FL 34285
20. Upper Crust Cafe & Bakery
213 W Venice AveVenice, FL 34285
21. Valenti's RistoranteMenu
1200 E Venice AveVenice, FL 34285
22. Angelo's Italian Market Inc
Really great Italian Grocer and Restaurant.
23. Benny Bada Bing Pizza & PastaMenu
1815 Tamiami Trl SVenice, FL 34293
24. Italiano'sMenu
4191 Tamiami Trl SVenice, FL 34293
25. Amore'sMenu
Most like New York pizza in Venice. Authentic pasta sauce. The owner backs the bread. Great people.
26. Made In Italy
Made in Italy is the best truly authentic Italian cuisine around. As for Connor G.'s remarks regarding seating, well, you should have been there wh…
27. Trattoria Da MinoMenu
335 W Venice AveVenice, FL 34285
From Business: We are proudly serving rustic Italian food at an competitive price. We serve pizza by the slice, by the pie, pastas, subs, salads, meats and desserts for Lunch and …
28. Leone's Ristorante & PizzeriaMenu
Pros: Pizza is LOADED with stuff. A few pieces of this stuff, and your full in no time. Great Pizza! :) Mum Loves this place. Cons: I like the …
29. Ntinos RestaurantMenu
660 Tamiami Trl SVenice, FL 34285
From Business: Serving breakfast, lunch, & dinner
30. Pasta Mania Inc
22 S Tamiami Trl Of PresidentsSarasota, FL 34231
Perfect. Right right inside the Venice Inlet. Directly across from the North Jetty Fish Camp on the South end of Casey Key FL. Swimming distance from Snake Island the local swimming spot for boaters and kayakers. The facility including docks are in great shape with a pump...more out and gas dock right there. Walk about 100 feet for lunch or dinner in the Crows Nest restaurant. Anther option is to walk out to the west end of the jetty wall and watch the people, boats surfers, and water or hit the Venice beach right there at the jetty. It couldn't be better or more scenic. I put in my kayak, "Jeannie H" an 18 foot white Kevlar sea touring kayak, in at the North Jetty and paddle all around this incredibly beautiful area. The Intra Coastal Waterway, ICW, is right here heading either North to Sarasota, FL. or South to Boca Grande, FL.view less
Having brought my car to Cramer Toyota on 41 Bypass for repair, I decided to walk around while I waited. With low hopes of discovering anything to do and having a grumbling tummy, I hoofed it to Wee Blew Inn. Mike greeted me at the door with a smile and I was seated by the s...morepunky young waitress. I ordered the fish basket, which included perfectly, lightly breaded catfish filets on a sandwich made to order (tasty tarter sauce), thick french fries and the best cole slaw ever: not too sweet, not too spicey and no onions, just the way I like it. Not only will I be returning to Wee Blew Inn for the service, the food was delicious. I wouldn't change a thing about this cute little restaurant and will be bringing family & friends every time we visit Venice. view less


text:
(248) 782-5473
Business Name: Loon Lake Roofing and Siding of Wixom
Address: ---
Phone: (248) 782-5473
City: Wixom 48393, Region: MI, Country: United States
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Call Loon Lake Roofing and Siding of Wixom at (248) 782-5473 for the home improvements that you need: residential home replacement roofing and vinyl siding installation.
Service or Products: Siding, Roofing
Business Hours: Sun-Fri: 8am-9pm, Sat: 8am-5pm
Moxie SEO Austin, Austin TX
1101 W 34th St #660 Austin 78705 512-900-7660
The Master Escape Room, Boca Raton FL
1700 N Dixie Hwy #126 Boca Raton 33432 561-571-5381
Tad James Co, Henderson NV
1450 West Horizon Ridge Parkway #544 Henderson 89012 702-440-4023
ProSpec Home Inspection of Long Island, Merrick NY
1911 State St Merrick 11566 (516) 580-1848
D & D Graphics Onsite, Wixom MI
28317 Beck Rd # E15 Wixom 48393 +1(248) 773-4190
Midwest Sales Assoc, Wixom MI
47529 Avante Dr Wixom 48393-3618 (248) 465-1160
Smirtware Inc, Wixom MI
28265 Beck Rd # 16 Wixom 48393-4719 (248) 344-9860
Trinary Systems Inc, Wixom MI
30553 S Wixom Rd # 100 Wixom 48393-2413 (248) 442-8540
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text:
Super 8 Uniontown PA, Uniontown
- Free continental breakfast, free WiFi, and free parking
Main amenities
- 61 guestrooms
- 24-hour front desk
- Coffee/tea in the lobby
- Air conditioning
- Daily housekeeping
- Conference space
What's around
- State Theatre Center for the Arts (1.7 mi / 2.8 km)
- Nemacolin Castle (10.6 mi / 17 km)
- Laurel Caverns (14.7 mi / 23.6 km)
- Kentuck Knob (17.4 mi / 28.1 km)
- Cucumber Falls (19 mi / 30.6 km)
Super 8 Uniontown PA, Uniontown
Hotel Info: 866-539-8117from $86
- Business Room, 1 King Bed, Non Smoking
- Room, Accessible
- Room, 1 King Bed, Refrigerator
- Room, 2 Queen Beds, Non Smoking
- Room, Accessible
- Room, 1 King Bed, Non Smoking
- Room, 1 King Bed, Smoking
- One King Smoking
- Room, 1 Queen Bed, Accessible, Non Smoking
- King Non Smoking
- Upgraded, 2 Queen Beds, Non Smoking
- One Queen Non Smoking
- One Queen
- Suite, 1 King Bed, Non Smoking
- One King Smoking
- King Non Smoking
- Suite, 1 King Bed, Smoking
- Upgraded, 2 Queen Beds, Smoking
- Room, 2 Queen Beds, Smoking
Also popular with travelers from the USA
At a glance
Key facts
Hotel size
- This hotel has 61 rooms
- This hotel is arranged over 3 floors
- Check-in time starts at 2 PM
- Check-out time is 11:00:00
Required at check in
- Credit card or cash deposit required
- Government-issued photo ID required
Travelling with others
- Pets not allowed
- Free WiFi in public areas
- Free WiFi in rooms
- Free self parking
- RV/bus/truck parking
Nearby Two Star Uniontown hotels
In the hotel
- Free continental breakfast daily
- Coffee/tea in the lobby
- Conference space
- One meeting room
- 24-hour front desk
- Elevator/lift
- In-room accessibility
- Roll-in shower
In the room
- Air conditioning
- Coffee/tea maker
- Iron/ironing board
- Private bathroom
- Hair dryer
- 32-inch flat-screen TV
- Desk
- Free newspaper
- Free WiFi
- Free local calls
- Refrigerator
- Microwave
- Daily housekeeping
- Connecting/adjoining rooms available
Top Uniontown hotels
Recently reviewed hotels in Uniontown
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"The room was large and comfortable. The staff was courteous. There's not much to the breakfast but that's how it was advertised. Very clean too."May 8, 2016
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Nearby hotels
Super 8 Uniontown PA, Uniontown's small print
The property has connecting/adjoining rooms, which are subject to availability and can be requested by contacting the property using the number on the booking confirmation.
We have included all charges provided to us by this hotel. However, charges can vary, for example, based on length of stay or the room you book.
Is the description of this hotel not correct? Tell us


text:
Home > Sport > Football
Sunday, 16 February 2014 | MYT 7:52 PM
LONDON (Reuters) - Reports that the England striker Wayne Rooney has signed a record-breaking new contract with Manchester United are premature, club sources said on Sunday.
The Sun on Sunday newspaper reported that Rooney had signed a new four-and-a-half year deal to stay at Old Trafford, worth 70 million pounds ($117 million) which would make him the best-paid player in the Premier League.
"There is no deal, which is why we haven't announced it," a United spokesman said.
Negotiations are believed to be ongoing.
The 28-year-old Rooney has been the subject of transfer speculation since the end of last season and Chelsea admitted an interest in signing him, but were told he was not for sale
The retention of Rooney would be a major boost for United manager David Moyes who has endured a difficult first season in charge with the champions languishing in seventh place in the Premier League.
(Reporting by Steve Tongue, Editing by Ed Osmond)
Czechs bank on a fit Rosicky to pull the strings
Deep-lying Iniesta aims for more glory
Austria not just making up the numbers in expanded Euro
Leicester will still be the underdogs, says Ranieri
For a hopping great time where else but Kangaroo Island!
Astoria strikes a balance
27 in Blossom Arts photo finals
Investigators raid Google Paris HQ in tax evasion inquiry
'1.5mil business tourists to visit M'sia'
Copyright © 1995- Star Media Group Berhad (ROC 10894D)


text:
Now that it has been more than two months since I posted the chart below, I thought now might be a good time to update the three sectors I have been watching most closely since the March bottom. These sectors are the financials (NYSEARCA:XLF), homebuilders (NYSEARCA:XHB), and consumer discretionary (NYSEARCA:XLY) stocks. As the chart shows, the financials and homebuilders recently moved above their 50 day simple moving average, only to fall sharply below that important technical level over the course of the past three days.
Until the XLF, XHB, and XLY can all close above their 50 day simple moving averages, I am likely to be skeptical of anything that has the appearance of a rally.
Click to enlarge
Disclosure: None


text:
Please select your home edition
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Marine Business
NZ Boating World
Show Menu
Light wind brings a change in the order... Day 4 report
by AsianYachting MultiMedia on 8 Dec 2012
Phuket King's Cup 2012. Last race, day 4. Guy Nowell
Going out to the left paid off big time earlier in the week but today the skippers that went right, picked up a favourable shift and gained over half a leg by the time they reached the bottom mark. As a result of the light wind, windward/leeward courses were set for all classes. While the IRC classes and multihull's completed multiple races, only a couple miles to the north, the cruisers struggled when it turned into a drift-a-thon before they could complete the first lap. This spin of the wheel of fortune has produced different winners and a change in the order in some classes and bolstered the standings in others.
First and second places in Race 8 for Kevin Whitcraft's GP42 Won Ma Rang and the Malaysian Armed Forces DK 47 Utarid skippered by Mohamad Razali Mansor, edged them closer to Frank Pong's R/P 76 Jelik sitting on top of the IRC 0 leaderboard. Changes made to Jelik earlier in the season have improved her light weather performance. In Race 9, Pong pulled out all the stops and romped away to claim the daily double and stay on top - 2 points in front of Whitcraft's Won Ma Rang in second spot. Razali's Utarid started the regatta strong but has been over run lately to be fighting it out with Ben Copley's RP45 Katsu for third and fourth overall.
Fred Kinmonth/Nick Burns Mills 40 EFG Bank Mandrake made a comeback to claim the daily double in Race 8 and by displacing the bigger boats climb up into third overall. As Bill Bremner's Mills King 40 Foxy Lady 6 could only manage two third places, they fall from grace at the top of the pointscore. David Fuller's chartered Beneteau 44.7 Ichi Ban helmed by Jamie Wilmot have hovered around the podium places in most races and scoring second and first today elevates them to top spot and almost in an unbeatable position for the IRC 1 title. A readjustment in Race 3 points has opened the door for Bremner's Foxy Lady 6 to regain top spot but they will have to win the final race tomorrow.
Two first and one second place for Matt Allen's Adams 10 Ichi Ban, seals the IRC 2 title with one race to go. Amazingly, seven weeks ago the boat was sitting neglected in Sydney Harbour and after purchasing plus freighting to Thailand, then hurriedly prepared did not finish worse than second and won on its first outing. Although Peter Dyer's Humphrys 3/4 tonner Kata Rocks made a late lunge taking victory in Race 9, they remain in third overall. Three third places for the Royal Thai Navy 1 skippered by CPO.1 Wiwat Poonpat ended their race to defend the title and will have to settle on being the bridesmaid on this occasion.
Although Hans Rahmann's Voodoo chose the wrong side to finish fifth in Race 8, they rebounded with victory in Race 9 to put themselves in an unbeatable position for the Firefly 850 Sports title. Correction to earlier Race Reports, Roger Kingdon's Moto Inzi is the defending champion and although they have had a slow start this year, two first and one second place in the last three races lifts them to fourth overall. Two third places for Peter Dyer's Dyer Straits is enough to hang onto second overall. John Newnham's Twin Sharks has been up and down the table but they still hold onto third overall.
The battle between Andrew Stransky's Seven Seas 50 Fantasia and Peter Wilcox's Schionning Gforce 1500 Mojo continues unabated. Although they traded first places, third place for Mojo in Race 8 has left them tied on 12 points and all to play for in the final race tomorrow. In a fine display of light weather sailing, John Punch's Stealth 12.6 Sidewinder of Darwin came through with line honours and a 2, 3 score line to regain some confidence in their new ride. Two fourth places for Henry Kaye's Sea Cart 26 Sweet Chariot skippered by Mark Thornborrow secures third overall and can only watch the leaders battle it out for the Multihull title.
Scott Duncanson mercilessly drove Tuay Lek to secure two wins and go directly to the top of the one design Platu 25 class. After leading all regatta, Junichi Ishikawa's The Beaver put in a shocker with two 4th places which drops them down the table to second overall. Makiko Matsuishi's almost all Japanese girl crew on IPPAI claimed the honours in the first race and two second places for Toshio Furuta's Sakura has them closing within two points of second overall.
In the drift-a-thon on the Northern course, Peter Forsythe & Jing Lee's X-55 Xena managed to claim victory and end Richard Dobbs Swan 68 Titania of Cowes run of wins. Thailand's Ithinai Yingsiri X-55 Pine-Pacific also managed to beat Titania but third place for Dobbs and Titania of Cowes does no harm to them in retaining the Premier Cruising title.
After three hours drifting in glassed out conditions, Nick Band's Tartan 48 Emerald Blue came through to claim the daily double. Nick Smith's Ericson 38 Free Wind out sailed the displacement yachts to slot into second place, with Peter Wood's Commanche 42 Windstar pulling up in third place. Despite Bo Sondergaard's S&S 47 Patrice III chartered by Barry Cunningham recalculating the results with a new IRC rating and ending with fourth today, they still hold a shortened two point lead in the Modern Classic Class.
Some things never change and although the 23 yachts in the Bareboat Charter Class looked like painted ships on a glassy sea, the Russian's on Kirill Sakhattzev's First 47.7 Sail Plane still managed to take the win and hold onto top spot in the pointscore. Second place for Aussie Graeme Sheldon's Hanse 400e Agility International keeps them in second overall and three points adrift of the leaders. Although Nikolay Shkurin's Sita slipped into third place today they are well down the order to make any difference in the overall stakes. Twelfth place for Mikhail Beloborodov's Tonicola 2 is still enough to hold onto third overall and ends up tied on 19 points with Nikiforov Evgenii's SunOdyssey 32i Sarawadee.
Since moving to the Cruising Class, William Lo's Hanse 545 No Name has won every race and now takes the lead in the overall stakes. Thailand's Patinyakorn Buranrom on Sansiri came through with second place and although Jack Christensen's Bavaria 49 Linda ended in fourth today, they are tied on 12 points with Sansiri for second overall. Third place for William Sax's Fraser 41 Astraeus is an improvement but not enough to make an impression on the leaders.
Simon Morris claims to have a multinational crew onboard Sirius 1935 to make up for being the only competitor in the Classic Class and guaranteed of victory.
Tomorrow is the final day of racing with the Royal Awards and gala dinner at the Kata Beach Resort & Spa in the evening.
For more info, visit www.kingscup.com.
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Delhomme: A Correction
Nov 20, 2004, 2:12 AM EDT
Comments Off on Delhomme: A Correction
In a post on Wednesday, I incorrectly said that Jake Delhomme didn't take an NFL snap before the 2002 season. He started two games late in the 1999 season, going 42 for 76 (55.3%) for 521 yards (6.9 per attempt), 3 TD's and 5 INT's.
It's certainly possible that Schottenheimer could have coveted Delhomme based on those two games. There still would have been the obstacle of Delhomme's status as either signed or a restricted free agent.
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