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Public Safety Curriculums Become Part Of Grainger's Tools For TomorrowA® Scholarship Program
CHICAGO, April 8, 2014 /PRNewswire/ -- Grainger (NYSE: GWW), the leading broad line supplier of maintenance, repair and operating (MRO) products serving businesses and institutions, today announced the expansion of its Grainger Tools for Tomorrow® scholarship program to offer financial assistance to qualified students enrolled in public safety programs. Public safety is one of the fastest growing fields of study at community colleges. According to a 2013 report by the National Center for Education Statistics, the number of students choosing homeland security, law enforcement or fire safety programs increased 174 percent between 2000 and 2011. In support of the growing need for public safety professionals, Grainger believed it was important to offer scholarships to students pursuing careers in law enforcement, emergency preparedness, emergency medical services and fire safety."We have the privilege of providing products and services to many first responder and public safety organizations," said Ben Nichols, vice president with Grainger. "With this comes a unique perspective and appreciation for what these women and men face on a daily basis. We are proud to expand this scholarship program, especially as interest in public safety continues to grow." Grainger works with the American Association of Community Colleges (AACC) to highlight the importance of community colleges and their programs. Grainger offers qualified community college students financial scholarships in industrial skilled trade programs, including plumbing, welding, automotive and HVAC. Nearly 650 students earned Grainger Tools for Tomorrow scholarships since the program's inception in 2006. "Grainger's support of students in industrial trade and public safety programs makes it easier for those interested in these careers to get the information and training needed to join the workforce. In an increasingly competitive global economy, America's economic strength depends on the education and skills of its workers," says Dr. Bryan Albrecht, President of Gateway Technical College. In addition to expanding the Grainger Tools for Tomorrow scholarship focus, Grainger also has invited 25 new community college partners to participate in the program. The company now will offer a total of 250 scholarships, of $2,000 each, starting in the 2014-2015 school year. One half of these scholarships are reserved for U.S. military veteran students. The invitation to 25 new schools and expansion to include scholarships for students in public safety programs represent the program's largest expansion since 2010, when Grainger doubled the number of scholarships offered. For more information about the Grainger Tool for Tomorrow® scholarship program, please visit www.graingercsr.com/skilledtrades. Learn more about how businesses and community colleges can work together to boost local workforce development by downloading an interactive skilled trades playbook at www.skilledtradesplaybook.org. About Grainger W.W. Grainger, Inc., with 2013 sales of $9.4 billion, is North America's leading broad line supplier of maintenance, repair and operating products, with operations in Asia, Europe and Latin America. SOURCE W.W. Grainger, Inc.
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DALLAS, Feb. 4, 2013 (GLOBE NEWSWIRE) -- FFE Transportation Services, Inc. ("FFE") (Nasdaq:FFEX) today announced its new Guaranteed Service for temperature controlled LTL shipments. Beginning February 4, 2013, this service guarantees that time sensitive shipments will deliver within FFE's committed service schedule on the day promised, or it is free. FFE's Less Than Truckload ("LTL") coverage footprint and strategically located service center network provides customers with a single source solution to local, regional, or nationwide temperature controlled LTL needs.
CONTACT: Frozen Food Express Industries, Inc. Russell Stubbs, President and CEO John Hickerson, EVP and COO John McManama, SVP and CFO (214) 630-8090 Dave Mossberg, Investor Relations Three Part Advisors, LLC 817 310-0051

subset: commoncrawl


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E-M5 IQ versus E-P5 IQ
Started Sep 13, 2013 | Discussions thread
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torske • New Member • Posts: 1
E-M5 IQ versus E-P5 IQ
Comparing the E-M5 versus the E-P5 in the "New studio comparison tool" the images from the E-M5 look much sharper than the images from the E-P5. I thought the IQ of these two cameras should be approximately the same. Anyone who have good explanation for this?
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This 16-week program examines cognitive behavioral bibliotherapy to typical therapist-directed cognitive behavior therapy for children and adolescents with Obsessive Compulsive Disorder.
This study is designed to compare self-directed bibliotherapy and therapist-directed cognitive behavioral therapy for children and adolescents with Obsessive Compulsive Disorder (OCD). Both treatments involve exposure and response prevention (EX/RP), in which the child confronts OCD fears and is asked to refrain from compulsive rituals (such as repetitive handwashing, counting, etc.). Participants are requested to complete an initial evaluation to determine diagnosis, and four follow-up evaluations to assess symptom severity and change due to treatment for a total of 16 weeks. Participant involvement to self-directed bibliotherapy versus traditional cognitive-behavioral treatment will be determined through random assignment.
In the bibliotherapy condition, the child or adolescent will meet with a therapist twice over the course of treatment, along with a parent. The therapist will discuss a self-directed program of EX/RP to be implemented at a pace deemed appropriate by child and parent at their own home. The child and parent will be provided with a manual designed to instruct them how to cope with Obsessive Compulsive Disorder. This treatment involves the parent and child reading the book, performing exercises, and monitoring symptoms on a weekly basis for 8 weeks.
In the therapist-directed treatment condition, the child or adolescent will meet weekly with a therapist along with their parent. The therapist, parent, and child will work together to design and implement a program of EX/RP. This treatment involves performing exercises, monitoring symptoms on a weekly basis, and completing homework assignments. Parents will be asked to help coach their child with at-home exercises challenging the Obsessive Compulsive Disorder. This treatment lasts 12 weeks.
Evaluations will be conducted following the completion of each treatment to assess the efficacy of each treatment on OCD symptoms. The treatment and evaluations for OCD are provided free of charge.
Allocation: Randomized, Control: Active Control, Endpoint Classification: Efficacy Study, Intervention Model: Parallel Assignment, Masking: Open Label, Primary Purpose: Treatment
Obsessive-Compulsive Disorder
Cognitive Behavioral Bibliotherapy, Cognitive Behavioral Therapy
Anxiety Disorder Center; Institute of Living
United States
University of Connecticut Health Center
Published on BioPortfolio: 2014-07-24T14:17:29-0400
Cognitive Behavioral Therapy Plus Drug Treatment for Obsessive Compulsive Disorder
This study will evaluate the effectiveness of two cognitive behavioral therapies (CBTs) in treating obsessive compulsive disorder (OCD) in patients who are taking medication but still have...
Cognitive Behavioral Therapy for Pediatric Obsessive-Compulsive Disorder
This study will examine the way cognitive behavioral therapy changes the structure of the brain in patients with obsessive-compulsive disorder and will thereby determine what makes cogniti...
Treatment of Obsessive Compulsive Disorder in Children
This study will determine whether cognitive behavioral therapy delivered by either psychologists or psychiatrists can improve the effectiveness of serotonin reuptake inhibitor treatment in...
Videophone Administered Cognitive-Behavioral Therapy for Pediatric Obsessive-Compulsive Disorder
Although cognitive-behavioral therapy (CBT) is the most effective intervention for pediatric obsessive-compulsive disorder (OCD), many people do receive CBT initially. Given this, alternat...
"Association Splitting" in Obsessive-Compulsive Disorder (OCD)
Over a period of 3 weeks, association splitting is compared to cognitive remediation (CogPack training) as an add-on intervention to cognitive-behavioral therapy (CBT). Blind to treatment ...
The present study examined the effects of homework compliance on outcome from cognitive behavioral therapy (CBT) for children with obsessive-compulsive disorder (OCD) and the extent to which these eff...
Tics Moderate Sertraline, but Not Cognitive-Behavior Therapy Response in Pediatric Obsessive-Compulsive Disorder Patients Who Do Not Respond to Cognitive-Behavior Therapy.
The purpose of this study was to investigate whether the presence of tic disorder is negatively associated with sertraline (SRT) outcomes, but not with continued cognitive-behavioral therapy (CBT), in...
Sertraline Treatment of Nonresponders to Extended Cognitive-Behavior Therapy in Pediatric Obsessive-Compulsive Disorder.
The purpose of this study was to investigate the effect of sertraline (SRT) in children and adolescents with obsessive-compulsive disorder (OCD) who did not respond to two consecutive courses of cogni...
Creation and validation of the Cognitive and Behavioral Response to Stress Scale in a depression trial.
The Cognitive and Behavioral Response to Stress Scale (CB-RSS) is a self-report measure of the use and helpfulness of several cognitive and behavioral skills. Unlike other measures that focus on langu...
Cognitive behavioral treatments of obsessive-compulsive disorder. A systematic review and meta-analysis of studies published 1993-2014.
Obsessive-compulsive disorder is ranked by the WHO as among the 10 most debilitating disorders and tends to be chronic without adequate treatment. The only psychological treatment that has been found ...
Cognitive Therapy
A direct form of psychotherapy based on the interpretation of situations (cognitive structure of experiences) that determine how an individual feels and behaves. It is based on the premise that cognition, the process of acquiring knowledge and forming beliefs, is a primary determinant of mood and behavior. The therapy uses behavioral and verbal techniques to identify and correct negative thinking that is at the root of the aberrant behavior.
Delirium, Dementia, Amnestic, Cognitive Disorders
Cognitive disorders including delirium, dementia, and other cognitive disorders. These may be the result of substance use, trauma, or other causes.
Mice, Inbred Mrl Lpr
A mouse substrain that is genetically predisposed to the development of systemic lupus erythematosus-like syndrome, which has been found to be clinically similar to the human disease. It has been determined that this mouse strain carries a mutation in the fas gene. Also, the MRL/lpr is a useful model to study behavioral and cognitive deficits found in autoimmune diseases and the efficacy of immunosuppressive agents.
Measurable biological (physiological, biochemical, and anatomical features), behavioral (psychometric pattern) or cognitive markers that are found more often in individuals with a disease than in the general population. Because many endophenotypes are present before the disease onset and in individuals with heritable risk for disease such as unaffected family members, they can be used to help diagnose and search for causative genes.
Art Therapy
The use of art as an adjunctive therapy in the treatment of neurological, mental, or behavioral disorders.
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Pediatrics is the general medicine of childhood. Because of the developmental processes (psychological and physical) of childhood, the involvement of parents, and the social management of conditions at home and at school, pediatrics is a specialty. With ...
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Hossam el-Hamalawy's Library tagged → View Popular, Search in Google
Aug 01, 14
أحد رموز معسكر "السلام" الصهيوني
Jan 01, 12
In 2006, Alterman was among a group of US pundits who argued in favor of the US continuing its financial support of Mubarak's regime despite the brutal crackdowns on pro-democracy protesters.
Nov 24, 11
Now, that's when I know we are on the right track
Aug 24, 11
Eltahawy has come under sustained criticism from many of her former comrades of the Jan 25 revolution, who feel she intentionally tries to portray a conciliatory tone towards the USA and Israel to keep her profile in the US. She has been accused of valuing her speaking fees more than her principals, by few of the titans of the Egyptian/Arabian twitterati.
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Chris Rizo Jun. 24, 2008, 8:18pm
Mark Shurtleff (R)
SALT LAKE CITY (Legal Newsline)-Utah Attorney General Mark Shurtleff was released from a hospital late Monday after doctors determined he is not suffering from a potentially deadly infection.
The Republican attorney general has developed a staph infection, and is being treated with intravenous antibiotics.
Lab tests showed the infection was not methicillin-resistant Staphylococcus aureus, a bacterial strain of staph that's resistant to a broad spectrum of antibiotics.
Doctors at University Hospital performed surgery Monday to be sure the infection had not spread to the plates and screws in Shurtleff's leg, placed last year after he injured his left leg in a motorcycle crash.
On Sept. 22, he crashed while test-driving a Harley Davidson Road King motorcycle for the "Fall Ride for Fallen Officers" charity ride benefiting the Utah Law Enforcement Memorial Foundation.
Because of the current infection, Shurtleff has been forced to cancel his June 30 trip to Israel.
From Legal Newsline: Reach reporter Chris Rizo by e-mail at firstname.lastname@example.com.


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I took white lunch sacks that I bought from Wal-mart and cut the very bottom half off and taped it to the folder under their shirts they made. This will make a little pocket that opens up. I wrote the words "Tabitha's Sewing Pattern's" on the front of it and stuck the sewing pattern down in the pocket. Then the kids taped the three other pictures to the right of the folder, "Peter, Tabitha, Needle and Thread, and a Coat. The coat will come in black and white for the kids to color it. The rest of the pictures will come colored.
The kids used the shirt pattern
(available for free below). They cut the shirt pattern out and laid it on
some felt and cut it out.
They hot glued the shirts to their folders on the inside of the folder on the right hand side and decorated them using some left over materials that I had in my closet from home. It was interesting to see how they decorated them. Cute, huh!
You can purchase the colored folders at www.Smead.com.
A hole punch was used on the folders so they could go in a large white binder folder.We will be making several different Bible story lapbooks so they can fill their binder up.
The kids did, The Life Of Tabitha "Dorcas" Lapbook. They learned that Tabitha, also known as Dorcas, was a woman that was full of goodworks and almsdeeds. In scripture she was referred to as a disciple. She sewed garments and coats for widows. Then one day she died. Peter was sent to her and raised her back from the dead. He put all the widows out of the room and kneeled down beside her and turned the body toward him and said, "Tabitha Arise!" She opened her eyes and saw Peter.
Tabitha Raised From The Dead Bible Story
Act 9:36 Now there was at Joppa a certain disciple named Tabitha, which by interpretation is called Dorcas: this woman was full of good works and almsdeeds which she did.
Act 9:37 And it came to pass in those days, that she was sick, and died: whom when they had washed, they laid her in an upper chamber.
Act 9:38 And forasmuch as Lydda was nigh to Joppa, and the disciples had heard that Peter was there, they sent unto him two men, desiring him that he would not delay to come to them.
Act 9:39 Then Peter arose and went with them. When he was come, they brought him into the upper chamber: and all the widows stood by him weeping, and shewing the coats and garments which Dorcas made, while she was with them.
Act 9:40 But Peter put them all forth, and kneeled down, and prayed; and turning him to the body said, Tabitha, arise. And she opened her eyes: and when she saw Peter, she sat up.
Act 9:41 And he gave her his hand, and lifted her up, and when he had called the saints and widows, presented her alive.
Act 9:42 And it was known throughout all Joppa; and many believed in the Lord.
God showed his mighty strength through Peter and raised Tabitha back from the dead. Many believed in the Lord because of this miracle. We still serve the same God today that existed in the Bible. He still works miracles, if you believe. The Bible say's that if we have the faith of the grain of a mustard seed we can say unto this mountain to be removed and it would have to obey us. Our faith is what fails, not God. Miracles ONLY happen through faith. It can and still does happen today. Jesus is so mighty and great. He is all powerful. He is a miracle worker and can work through us just like he did with Peter.
Did you know that even the disciples faith failed? They tried to heal a child that had a devil and it would not come out. The disciples came to Jesus and asked, "Why could we not cast him out?" and Jesus told them because of their unbelief. This kind goes out by prayer and fasting.
Mat 17:14 And when they were come to the multitude, there came to him a certain man, kneeling down to him, and saying,
Mat 17:15 Lord, have mercy on my son: for he is lunatick, and sore vexed: for ofttimes he falleth into the fire, and oft into the water.
Mat 17:16 And I brought him to thy disciples, and they could not cure him.
Mat 17:17 Then Jesus answered and said, O faithless and perverse generation, how long shall I be with you? how long shall I suffer you? bring him hither to me.
Mat 17:18 And Jesus rebuked the devil; and he departed out of him: and the child was cured from that very hour.
Mat 17:19 Then came the disciples to Jesus apart, and said, Why could not we cast him out?
Mat 17:20 And Jesus said unto them, Because of your unbelief: for verily I say unto you, If ye have faith as a grain of mustard seed, ye shall say unto this mountain, Remove hence to yonder place; and it shall remove; and nothing shall be impossible unto you.
Mat 17:21 Howbeit this kind goeth not out but by prayer and fasting.
The child was Lunatick.
What does Lunatick mean?
Middle or passive voice from a presumed derivative of G4582; to be moon struck, that is, crazy: - be lunatic.
When we fast and pray, something very powerful happens. This is very hard for some people to wrap their minds around. Some folks may have never even heard of it before.
As far as my personal walk with Jesus goes, I believe in fasting and prayer. If you don't understand what fasting is, it is when you don't eat or drink anything at all for a certain amount of time and pray to God for what it is you need. Many people in the Bible fasted. Some fasted water and food, and some fasted like Daniel. Just depending on what your reading in the Bible, they fasted differently and for different amounts of time.
If you need something from the Lord, a miracle, try fasting and prayer. It works. Sometimes God may have a timing for something. God will show you and answer you about your situation. Everyone's situation is different. But rest assured God will answer you if you need to talk to him about something. Just listen to him and obey what he tells you.


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Fallout is one of the greatest RPG games out there. It's set in the post-nuclear, dangerous world of violence and radiation. The game consists of a very detailed and interesting storyline, tactical turn-based combat, and revolutionary character creation style. You can play Fallout for months, but still it's not boring because of many ways of finishing the game. You can be a bad-ass gangster, or a world-saving hero. This is a must-see for all RPG games fans, and it's undoubtedly one of the best gaming classics. Unique, amazing storyline makes Fallout addicting! The Linux copy uses the classic DOS version.
This is the last planned release before switching to the Fallout 2 engine, beta stage. Quick overview of this release: lots of cool features from Crafty's update to the Sfall plugin, Fallout Fixt now installs to a subfolder to avoid overwriting any of your Fallout data, lots more text fixes, some crash fixes, fixes for some goofs I made, a few more options for Fixes Only custom installs, and fo1_screen_refresh is back. Oh and Fixt is on GitHub now.
Scroll down for screenshots; below screenshots is the changelogs.
1. "Friendly Foe" always on, without the Perk (via Crafty's sfall upgrade)
2. Free/Total weight displayed in inventory and trade screens (via Crafty's sfall upgrade)
3. "Take All" & "Put All" buttons! (via Crafty's sfall upgrade)
4. Leveling past 21! (via Crafty's sfall upgrade)
5. More installer options allowed for Fixes Only custom-mode: Water timer, Vault 13 invasion.
6. More installer options allowed for Fixes Only custom-mode: Level and Title on levelup.
Changes since 0.80alpha:
- Fallout Fixt now installs in a subfolder titled "Fallout Fixt" of where you tell it to install. (Thanks Lexx!)
-- This means you won't overwrite anything from your current Fallout installation. Hooray!
-- You still need to select your current Fallout folder as the install directory, because Fixt needs to know where to find the main data files.
- Fallout Fixt installer no longer backs up savegames during install. This was causing issues on some systems.
-- The silver lining is that since it's being installed in a subfolder now, your original savegames will stay untouched regardless.
- Fixed crash when giving holodisk to Jon Zimmerman.
- Razor no longer dissapears forever.
- Fixed crash moving items between containers in inventory. (Thanks Crafty!)
- Talius' dialog options regarding the spy are now available as they should have been.
- No more broken Start Menu links.
- Display of title and/or level on levelup now works properly on Fixes Only installs.
- "Free combat running fix" in Sfall now disabled by default as it caused confusing functionality.
- Updated troubleshooting guide, and added index to top of file.
- URLs for Troubleshooting Guide and Changelog now open the file directly as a download rather than with Dropbox's file viewer.
- More text & dialog changes/fixes. 200+ files modified. (Thanks robbforce!)
Changes since alpha 7.1:
- Now has the most current files for Katja's graphics.
- Additional options available in the Fixes Only download's "MOSTLY PURIST" custom install:
-- Display player's level on levelup
-- Display player's title on levelup (Titles are from the Fallout manual)
-- Restore Vault 13 invasion of after 500 days (Default in Fallout v1.0)
-- Days Left for Water Chip can be 120 instead of 150. (Overseer says "4 to 5 months left" in the intro movie)
- Includes ddraw (Sfall) version 1.19, by Timeslip & improved by Crafty. This plugin provides many graphical and game enhancements and features, which are customizable, including the following and many more:
-- Hold down Shift to highlight items and containers on-screen.
-- Various commands can be bound to keys or key combinations. (All are disabled by default)
-- Can no longer press zero (0) to force-exit dialog.
-- Fixes for high CPU usage.
-- Display karma changes in the message box. (Disabled by default)
-- Buttons with "Take All" function similar to Fallout 2.
-- Remove inability of Vault Dweller to get critical successes or critical failures in the first few days of the game.
-- Doors can no longer dodge bullets.
-- Shows free weight as well as total weight in Barter and Inventory screens.
-- Can no longer use drugs to cheat with skill-gain books and getting Perks you shouldn't have access to.
-- Can no longer use the "A" key to run forever for free in combat.
-- Leveling past 21. (Disabled by default of course)
-- Friendly Foe functionality is now default and the Perk is removed from the game.
- "Fixes Only" installs can no longer start with 64000 Days Left for the Water Chip timer.
-- Existing "Fixes Only" games with >150 Days Left will be reset to 150.
- Fixed crash upon ending dialog with the dying mutant.
- Fixed some installer options that weren't working as intended.
- Made a change to attempt to fix an issue where Vats self-destruct timer would always set to 0 (instant), regardless of option chosen.
- Reverted an attempted fix of empty caravan encounters, that unintentionally caused *more* empty caravan encounters. :(
- Reverted 2 fixes/changes that caused unintentional issues gaining access to the Vats Control Computer.
- fo1_screen_refresh is once again included.
- Weapon Drop Mod no longer enabled by default on "Standard" and "Full" installations. My sincere apologies, I thought I already reverted this in the last release.
- All instances of "nevermind" changed back to "never mind". (Thanks Prisoner416)
- Several minor fixes to spelling and grammar.
- Additions to CREDITS.TXT (French translation team, SFALL team, Engine Conversion team, Breakin'Benny, gvx, Prisoner416)
- Removed debug message that displayed if player was accompanied by Brotherhood of Steel Assault Paladins.
- Added steps to Troubleshooting Guide regarding inability to save games, sound issues, and "Not enough disk space".
- Various behind-the-scenes changes in preparation for the full migration to Fallout 2 engine.
- Fallout Fixt source code (installers, scripts, batch files, reference materials, global variables, default settings) is now publicly available at Github.com
- Fallout Fixt dialog and text files are now publicly available at Github.com - For translations into non-English languages and tracking fixes/changes/additions to the English versions.
- All bugs, ideas, and feature requests are to be reported at the Fallout Fixt bug reports wiki at Falloutmods.wikia.com
- Bug reports entered on forum threads (RPGCodex/NMAFallout/GOG/Steam/etc) will no longer be considered 'official bug reports' for the following reasons:
-- EASE: It doesn't require registration and shouldn't take much longer than it would to post it on the forum.
-- EXCLUSIVITY: You're robbing the ability to interact with your bug report from people who don't visit that forum.
-- DUPLICATE WORK: Someone (usually me) has to to personally go through all the threads to add them to the wiki.
-- HUMAN ERROR: It's easy for thread-post bug reports to be accidentally overlooked or forgotten.
-- EFFICIENCY: It results in duplicate reports and requires cross-referencing multiple sources.
-- TIME: It's in everyone's best interest for me to spend my time focusing on actually fixing the bugs.
The Fallout game series are some of the greatest RPG games out there. Set in the post-nuclear, dangerous world of violence and radiation. The game consists...
Short summary of how the setting will look and feel like and some core feautures/descriptions for the mod.
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This mod removes the swearing from Fallout. It has a built in language filter, but it doesn't work so well so here's one that does. Enjoy If you enjoyed...
!!! WARNING - DO NOT INSTALL THIS IF ALREADY USING FALLOUT FIXT !!! This add-on makes it possible to get good endings for The Hub & The Followers Of The...
The same as "Full Custom", but for those with German version. 280 MB to download, up to 700 MB installed (if all options selected). Restores censored...
The full mod. 200 MB to download, up to 540 MB installed (if all options selected). All content is available. Available installation types: Fixes Only...
The "patch". 90 MB to download, up to 150 MB installed (if all options selected). Some new content available. Good for purists. Available installation...
Removes verbal blasphemy. Two folders: Base, Patch. 1. Copy the contents of Base to the installed folder and overwrite. 2. If the game has the Unofficial...
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fullscreen=flase? Heh. Not that it matters. :-)
If I uninstall the game and savegames remain, upon reinstalling the game Desura stalls infinitely on "gathering information". If I press Cancel, the app just quits. A bug in Desura, I'm sure.
I should also mention that the reason it doesn't just delete the directory is because of MOD support. We could probably do this better though, since Fallout doesn't have MODs.
The "fallout" directory alone is not enough to stall Desura on reinstall. There has to be some stuff inside it, too.
Oh no. Don't attempt to delete any folders! Fallout stores it's saved games inside the game folder and even some newer titles do, Blocks That Matter for example.
Yes that is a bug in Desura. Sometimes if the directory exists it gets freaked out and won't move on anyway.
Is this NATIVE GNU/Linux version of Fallout? Also, does it contain official patches or some other improvements?
edit: sorry desura decided my reply was to go some where i did not want it to go.
No, it is running through DosBox just like it does in Windows. BTW, GOG.com has some old DosBox based games which also work in Linux.
Actually the Windows version is an updated version of the Windows EXE so it runs on modern Window systems. The Linux one is the DOS version 1.1 which was the last patch they made to the DOS version.
I have uploaded a new version for Linux that should hopefully help everyone out that has been having problems.
If you notice any more problems let me know.
In Linux, I had to set output=overlay in dosbox.conf to get sensible performance.
Ubuntu 11.10 64-bit, using the proprietary nvidia driver.
This could also fix your problems: Indiedb.com
I run the exact same setup. Ubuntu 11.10 but with a Radeon 6850 with the binary drivers and didn't have problem.
Do you have the OpenGL drivers installed? It is setup to run with OpenGL. If that is a problem you can change the output to "surface" which a slightly slower but more compatible I believe.
Highest Rated (2 agree) 10/10
Old classic. I played with it first in 2010, but I loved it. I think this game must be the idol of every game.
Jul 9 2011 by Attila1945


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Relationship between Perceived Self-Efficacy and Information Literacy among Library and Information Science Undergraduates in a Nigerian University of Education
Adetoro, Niran, Simisaye, O, Oyefuga, A B, Ife Psychologia
Information Literacy is a critical input in today's learning environment and indeed for lifelong learning. Information literacy could be contingent upon an intrinsic element such as self-efficacy belief. Thus, this study investigates the relationship between perceived self-efficacy and information literacy among library and information science (LIS) undergraduates in Tai Solarin University of Education, Ijebu - Ode Nigeria (TASUED). Ex-post facto research design was adopted. Using total enumeration technique, data were gathered from all the 108 LIS undergraduates in TASUED using an instrument tagged Self-efficacy and Information literacy questionnaire (SILQ) with reliability values: (a = 0.78) information literacy and (a = 0.75) self-efficacy. All questionnaires were returned, however 100 (93%) were found usable. The study found out that respondents had high self-efficacy beliefs on more items on the scale; the level of information literacy was high in eight of the fifteen indicators on the scale. Perceived self-efficacy had a significant relationship with information literacy (r=0.329; p<0.01). There was no significant difference in the information literacy of LIS undergraduates based on gender (t=2.26 df=98; p<0.05). There is significant difference in perceived self-efficacy based on gender (t=0.085; df=98; p>0.05). The study recommends standardized information literacy competency training and periodic morale boosting orientation and re-orientation programs for the undergraduates.
Keywords: Perceived self-efficacy, Information literacy, Library and information science, Undergraduates, Nigeria.
Information professionals had for long sought to understand the factors that propels an information seeker towards finding relevant information. Focus of research has been on the factors that play important roles in information use; the process of information search, retrieval and continuous learning. These investigations have assumed greater importance today because of the growing influence of information technology (IT) on information management generally.
The information environment of the 21st century thrives on some competencies that are necessary for life long learning. As such, the idea of information literacy (IL) , which emerged with the advent of information technology had grown, taken shape and strengthened to become recognized as a critical literacy for the 21st century (Bruce, 2002). Webber and Johnston (2002) define information literacy as the adoption of appropriate information behavior to obtain, through whatever channel or medium, information well fitted to information needs, together with critical awareness of the importance of wise and ethical use of information in society.
There are many definitions of information literacy, however, the American Library Association (1989) provides the world with a simple and direct conceptualization of an information literate person as someone who must be able to recognize when information is needed and have the ability to locate, evaluate and use effectively, the needed information. Information literacy has increasingly been an area of interest to librarians and information professionals (Virkus, 2003). This has been demonstrated through a number of projects, conferences, workshops, working groups and adaptations of information literacy competency standards by professional organizations, institutions and countries (Maughan, 2001; Virkus, 2003). Information literate persons are people who have learned how to learn, how knowledge is organized, how to find information and how to use information. They are prepared for lifelong learning.
Information literacy would enable an undergraduate to perceive, encode, decode, retain and use effectively information or learning materials. Through information literacy, students become more thoughtful and versatile in seeking and using information. In recent times, information literacy has been identified as a key graduate outcome and an integral part of undergraduate curriculum model (Radomski, 2000; Wright and Mcgurk, 2000). …


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Rhythms Propel Wamidan Concertby Steve Charles • April 13, 2014 Share:
The evening after former National Security Director Admiral Bobby Inman offered his views on geopolitics from the Salter Hall stage, Wamidan transformed that same space into a musical trip around the world.
Playing songs from Australia, Jamaica, Uganda, and Cameroon, and performing dances from Kenya and Argentina last Wednesday, the College's world musical ensemble filled the room with exotic tunes and rhythms that highlighted the strong percussion and dance abilities of the group.
"This group has been very good throughout the academic year," said Wamidan Artistic Director and Wabash Associate Professor of Music James Makubuya. "And it all came together and translated into this final concert."
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Text Illustration Search Results for Trusting God, stories
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FAITHFUL INSTRUCTIONS There was a man who got lost in the desert. After wandering around for a long time his throat became very dry, about that tim...
Contributor: SermonCentral
Scripture: John 1:1-1:1, Deuteronomy 30:11-30:20
Shared: 9/16/2002
THE CHRISTMAS STORM: A Modern Parable by Paul Harvey "This is about a modern man, one of us, he was not a scrooge, he was a kind, decent, mostly...
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Scripture: John 1:14
Shared: 12/10/2002
Cast: Narrator 1, Narrator 2, Jesus and Nick the Vic Narrator 1: Our reading is taken this morning from Joh...
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Shared: 2/17/2008
My pet finch Coffee runs into a serious problem once in a while. Her claws grow so long she loses the ability to control them. They get stuck in the n...
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Scripture: Romans 8:28
Tags: Surrender, Rest In God, Trust In God, Pruning, God's Care
Shared: 11/25/2014
"" As an aged Christian lay dying, a friend called to say farewell. "I have just had three other visitors," said the dying man,...
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Shared: 9/2/2007
HOW BIG IS YOUR GOD? Tony Campolo was once confronted by an atheist who was one of his students. The young man told Campolo, "For me to believe in...
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Scripture: Psalms 53:1
Tags: Atheism
Shared: 9/7/2011
Every branch that bears fruit must be pruned to bear much more fruit. I have a tomato plant that has been living for over two years now. Every winter...
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Scripture: John 17:13, John 17:13-17:21
Tags: Growth In Christ
Shared: 6/14/2008
"Great Is thy Faithfulness" is not the result of some tragic event in Thomas Chisholm's life but a powerful witness to his daily walk with Jesus as he...
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Scripture: Acts 10:44-10:48, Lamentations 3:22-3:23
Shared: 1/22/2007
Max Lucado (Angels were Silent) Describes how in a similar way we cry out for something to cut through the clutter of life, turning to faith and re...
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Scripture: Psalms 23:1, Romans 11:3-11:6
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TRUST IN GOD "Trust in yourself and you are doomed to disappointment Trust in money and you may have it taken from you; But trust in God, and yo...
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Scripture: Proverbs 3:5-3:6, Proverbs 31:1-31:31
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7 Things to Know About Divorcing During Your Senior Years
You thought it was until death do you part, but now you're part of a trend: the divorce rate for those ages 50 and older has doubled in the last 20 years.
You thought it was until death do you part, but now you're part of a trend: the divorce rate for those ages 50 and older has doubled in the last 20 years.
For most seniors and especially retirees, insurance payments can seem like an unnecessary expense. But not in these five common scenarios.
Personal emergency response systems, sensors, medication reminders and even virtual pets help the elderly keep their independence and age in place.
Adults age 55 and over are returning to the workforce in larger numbers, and the trend doesn't expect to slow for the next decade.
Here are the telltale signs to watch for and steps you can take to reduce the chances of the seniors you love of being taken advantage of.
The cognitive decline that accompanies aging can lead to major money problems.
The victims -- often elderly, with limited income and living alone -- were bilked out of nearly $23 million in fees for "free" medical alert units.
Housing is most people's biggest monthly expense, and the one most likely to be a budget buster. For many seniors, that problem is likely to get much worse.
Welcome to Citrus County, Fla., where more than a third of residents are seniors. It's not just a stereotype of Florida. It's a peek into America's future.
'Tis the season when con artists are most likely to call seniors and scam them out of cash. Here's how to protect yourself.
A worrisome number of seniors are spending too much time -- and too much money -- at casinos and other places to gamble. Millions are said to be addicted.
Ever wonder what the social safety net battle looks like from the other side? Here's a look at the eight groups that have been hurt the worst by budget cuts.
We all want to help our parents meet the goal of aging in place independently and happily. Here are five things you can do to improve the odds of that in the years ahead.
Recent studies show that rich people live longer than poor ones...and the trend is getting even more pronounced.
Playing the online game Spent forces you to make the wrenching decisions that America's poor, especially the elderly, face on a daily basis
The student debt crisis isn't just an issue for fresh-faced Gen Y'ers. Thanks in part to the Great Recession, an older cadre is finding itself buried under the weight of billions of dollars in unserviceable loans.
For the past few years, it has seemed like depressing economic news has been America's only actual growth industry, and all that negativity is still echoing in our heads. Across the age spectrum, we're downbeat about the future, even as the signs are finally looking up.
Conservative politicians have spent the past few months venting their ire on America's entitlement programs, and the alleged mass of lazy layabouts who make use of them. But a closer look at who actually lands in the social safety net reveals some surprising facts.
It's a tough time to be old in America, and it's worse than you may realize: According to a recent report, on average, if government benefits were taken out of the equation, the elderly would have far less income than they'd need to survive. Here's where the problem is worst.
In a shaky economy, senior citizens have become a prime target for scammers. Here are some of the common scams -- and warning signs -- to watch out for, along with some tips on how to protect your elderly loved ones.
Genworth Financial's Cost of Care survey tracked average prices of home care, assisted living facilities and nursing homes across the country, and unsurprisingly, found staggering variations. The priciest state for nursing home care in the U.S. averages more than four times as much as the cheapest.
For children, excursions with grandmother are an adventure. As time passes, however, the ride into the golden years can get bumpy; if you're financially unprepared, it can take a dramatic turn for the worse, and even drive you and your family into bankruptcy. Here are some steps you can take to prevent that.
Picture this: You're a middle-aged worker, raising your kids and worried about your job and mortgage, and suddenly your 75-year-old mother breaks her...
Being old and poor doesn't sound like much fun. Here's what you need to know to avoid that fate -- or get help if you can't. One quarter of baby...
A major public initiative to crack down on investment fraud by training thousands of doctors to spot older patients who may be particularly...
When Dan Callahan, a public relations professional from Missouri, learned in 2003 that the Medicaid qualifications were going to get tougher, he and...
Former White House reporter Helen Thomas' rant against Israel was more than a "senior moment," but the forced retirement of the 89-year-old is a...
The Obama Administration has begun mailing checks to seniors hitting the "donut hole" in their Medicare prescription drug coverage. The help for seniors to cover the gap is part of the health-care reforms Congress passed earlier this year.
There are cell phones and computer tech support for the elderly, and now a computer designed for grandparents -- the GO Computer that is clearly...
Poverty among the elderly is now nearly twice the normal rate. Traditionally, 10 percent of Americans over age 65 live below the poverty line, but...


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Editor rating : 8
Price: 56,900
Editor rating : 8
Price: 24,999
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Price: 14,999
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Price: 89,900
Editor rating : 7.5
Price: 39,990
Rumours suggesting that Apple could release a bigger screen iPhone just keep growing. Now a Chinese tech site, GizChina, has put out pictures of what it claims is the iPhone 5S and the iPhone 6 from a Foxconn Factory. You can check out all the pictures here.
The post also states that the rumour appeared on Sina Weibo (China's version of Twitter) claiming that the both the iPhone 5S and iPhone 6 had been spotted at by a supplier. It adds that the the iPhone 5S looks pretty similar to iPhone 5, but the iPhone 6 sports a 5-inch display, longer body and thinner profile.
This isn't the first rumour around two versions of the iPhone. Previously iLounge had reported that Apple was likely to launch as many as three new versions of the iPhone this year. It said that one would be a 4-inch-screened iPhone 5S and a supposedly larger-screened 4.8-inch "iPhone Math" model before the end of June, while a third model with a 12-megapixel camera would arrive before Christmas.
Also Apple Insider had reported that Apple is testing the new iPhone 5S and another smartphone. The report added that the smartphone could be out by June or July and was based on a note circulated to investors by Jefferies analyst Peter Misek where he states that Apple is testing two iPhone prototypes, one being the iPhone 5S and the other a low-cost iPhone.
The analyst had also stated that the iPhone 5S has a new "super HD camera/screen, a better battery, and NFC," and "possible updates include an IGZO screen for Retina+" The device could come in six to eight colours like the iPod Touch (fifth generation).
Macrumours had also posted images from the French site Nowhereelse.fr which the French site claims are speaker enclosures for both the upcoming iPhone 5S and a future iPhone 6.
Does a bigger screen iPhone make more sense for Apple? According to Marco Arment, creator of popular iOS app Instapaper, it certainly does. He writes on his blog,
First and foremost, there's significant demand for larger-screened phones. As much as we make fun of the Galaxy Note, it sells surprisingly well, especially outside of the United States. Other large Android phones sell very well almost everywhere.
The iPhone has lost a significant number of sales by buyers either wanting a larger screen or being drawn to how much better the large screens look in stores.
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I understand that questions like this have being answered before, however mine is slightly different.
Basically I run automated tests which mean that the mouse cursor is moving around the screen clicking things for a bit of time. I am completely out of action while this is going on.
I have already tried to use VirtualBox to set up a linux OS that I can use while the tests are running, but the Computer still only likes to use one cursor and either the tests fail or I cant use virtualbox.
Is there anyway I can use two cursors on the same Screen at the same time? I have dual monitors and a dual core cpu if that helps.


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May 4, 2016
GULLANE, Scotland (AP) -- By the time Tiger Woods finally made his way up to the 18th green, the bleachers were half empty and long shadows crept across the fairway.
The major championships are usually grinds, and for anyone playing in the afternoon Thursday, the first round of the British Open was even more of a grind than ever. The wind was blowing harder than expected, the golf course was drying up by the minute, and anything around par was a score to be respected.
And there was Woods, feeling awfully good about a 2-under 69 that had to give him hope his five-year drought in the major championships might come to an end this week at Muirfield.
Woods was three shots off the lead held by Zach Johnson with three rounds to be played.
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Credit Records and Consumer Reports
|Identifying information : name and spouse's name, Social Security number, address and telephone number;
|Financial status : amount of income (present and past), employer (present and past), occupation, sources of income;
|Credit history : previous types, extent, and sources of credit granted;
|Existing lines of credit : payment habits, outstanding obligations and debts, extent of current lines of credit;
|Public Record Information : lawsuits, judgments, tax liens, bankruptcies, arrests, convictions (TRW has a policy of not including pending lawsuit or criminal history items);
|Prior requesters : names of subscribers who requested information on the individual in the past.
While individually many of these items are not particularly sensitive, together they reveal a lot about a person's lifestyle and habits. Credit bureaus can track individuals as they move from neighborhoods, jobs, lifestyles, and income levels.
Credit reports are compiled primarily by credit bureaus, investigative-reporting agencies, and private-detective agencies, which sell their services to "subscribers" -- creditors,


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Can anyone point me in the direction of information on delayed vaccination information? Things such as schedules and reasoning for such schedules?
This is something we are really looking into but I'm having a hard time finding reliable information and don't want to just guess on what's best. Also, when it comes to doctors, out of curiosity, did you have a hard time choosing to use a delayed schedule and what your doctors have said to that?


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My new neon tetras
Day 15 of my tank and this will be the thread for all the new updates!!
So i brought 10 Neon Tetras for £1o but wheni got home i had 11! They are very cool to watch....
They seem to have made little groups inside the one main group.
Hears the video.
Hey...you are getting lots of color!!!!!!! very nice.....I love my neons!!!!! dont they have homework in England?.......seems like your always on this forum:lol:
Cause we have home work!! Im on here most of the time coz im passionate about my fish! Got a baby mollie and a tiny red tailed shark today vid being uploaded!
Your red tail shark is going to out grow your tank. If I were you which I am not I would return it and get another type of fish instead unless you are planning on up gradeing to at least a 55 gallon tank soon. I know you said hes tiny right now but he will grow and haveing a tank to small will only stunt his growth and shorten his life. You can read more about them here:
Red Tail Shark
Yes i know i know i picked him coz he was so cute! When he gets a good size he is either going back or to my friends tank...
You are getting a lot of variety...can you please get a piece of poster board for a backgound so we can see the fish better.....
Gotta love the neons! Your tank is looking nice too. Lots of great color going on. :)
Thank you!! And i will try to get a black backing trying atm but got no money!!!!
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Heres a few pics of my Opaline Gourami and 2 new baby mollies!
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The Pelican PL1510 is a rugged case made from ultra-high impact structural copolymer shell. Unbreakable, watertight, airtight, dust-proof, chemical resistant and corrosion proof. These are some of the features of this Pelican Protector Case that offers total protection for your equipment. It is made of ultra-high impact structural polycarbonate open cell core with solid wall design that makes it extremely strong and durable. Its exclusive polymer O-ring and double-throw latches seal perfectly and includes an automatic pressure valve for quick equalization after changes in atmospheric pressure.
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Index of content:
Volume 99, Issue 3, 01 August 1993
The electronic spectrum of chlorofluorocarbene99(1993); http://dx.doi.org/10.1063/1.465313View Description Hide Description
A vibronically and partially rotationally resolved electronic spectrum of chlorofluorocarbene has been observed using the technique of pyrolysis jet spectroscopy. A vibrational analysis has established the origin of the electronic transition to be at 25 277.8 cm−1. The pattern of isotope effects for the CF35Cl and CF37Cl species was used to confirm the vibrational assignments. The rotational analysis of three bands established that the transition moment is perpendicular to the molecular plane and can be assigned as à 1 A'–X̃ 1 A'. The ground and excited state geometries were derived from the rotational analysis and compared to ab initio predictions. The transition was found to be the direct analog of the 600 nm band system of dichlorocarbene.
Determination of potential energy curves for HeNe+ from mobility data, spectroscopic measurements, and theoretical calculations99(1993); http://dx.doi.org/10.1063/1.465314View Description Hide Description
Potential energy curves for the three lowest states of HeNe+(X 2Σ1/2 +,A 1 2Π3/2,A 2 2Π1/2) are determined from a combination of mobility and spectroscopic measurements, in conjunction with a theoretical expression giving the A 1 curve in terms of the X and A 2 curves plus the energy splitting between the 2 P 3/2 and 2 P 1/2 states of Ne+. The results are also consistent with measurements of the scattering of beams of fast Ne+ions by He gas. The best available ab initio potentials give mobilities in poor agreement with experiment, largely because of poor predictions of the positions of the potential minima. It is also shown that, contrary to initial expectations, mixture formulas for mobility based on simple momentum‐transfer theory are valid for open‐shell systems with multiple interaction potentials. Illustrative calculations are given for the mobility of Ne+ in a He+Ne mixture; both HeNe+ and Ne2 + have multiple potentials.
Rotational spectrum of the trimethylamine‐hydrogen iodide dimer: An ion pair (CH3)3NH+⋅⋅⋅I− in the gas phase99(1993); http://dx.doi.org/10.1063/1.465315View Description Hide Description
The ground‐state rotational spectra of the two isotopomers [(CH3)3N,HI] and [(CH3)3N,DI] of a dimer formed between trimethylamine and hydrogen iodine have been observed in the gas phase by the pulsed‐nozzle, F–T microwave technique. The spectroscopic constants B 0, D J , D JK , χ(14N) and χ(I) have been determined for both isotopomers and have the values 894.0954(2) MHz, 0.010 17(18) kHz, 5.880(10) kHz, −2.451(8) MHz, and −341.204(14) MHz, respectively for [(CH3)3N,HI]. It is concluded, by comparing the iodine nuclear quadrupole coupling constant χ(I) and the intermolecular stretching force constant k σ with those of model hydrogen‐bonded (H3P...HI) and ion‐pair (Na+...I−) analogs, that (CH3)3NH+...I− is the appropriate description for the gas‐phase dimer. An experimentally defined fractional ionic character indicates that the extent of proton transfer increases smoothly along the series [(CH3)3N,HX], where X=F, Cl, Br, and I. Simple energetic considerations are shown to be in agreement with this conclusion.
Intermolecular bonding and vibrations of 2‐naphthol⋅H2O (D2O)99(1993); http://dx.doi.org/10.1063/1.465316View Description Hide Description
A combined experimental and theoretical study of the 2‐naphthol⋅H2O/D2O system was performed. Two different rotamers of 2‐naphthol (2‐hydroxynaphthalene, 2HN) exist with the O–H bond in cis‐ and trans‐position relative to the naphthalene frame. Using Hartree–Fock (HF) calculations with the 6‐31G(d,p) basis set, fully energy‐minimized geometries were computed for both cis‐ and trans‐2HN⋅H2O of (a) the equilibrium structures with trans‐linear H‐bond arrangement and C s symmetry and (b) the lowest‐energy transition states for H atom exchange on the H2O subunit, which have a nonplanar C 1 symmetry. Both equilibrium and transition state structures are similar to the corresponding phenol⋅H2O geometries. The H‐bond stabilization energies with zero point energy corrections included are ≊5.7 kcal/mol for both rotamers, ≊2.3 kcal/mol stronger than for the water dimer, and correspond closely to the binding energy calculated for phenol⋅H2O at the same level of theory. Extension of the aromatic π‐system therefore hardly affects the H‐bonding conditions. The barrier height to internal rotation around the H‐bond only amounts to 0.5 kcal/mol. Harmonic vibrational analysis was carried out at these stationary points on the HF/6‐31G(d,p) potential energy surface with focus on the six intermolecular modes. The potential energy distributions and M‐matrices reflect considerable mode scrambling for the deuterated isotopomers. For the a' intermolecular modes anharmonic corrections to the harmonic frequencies were evaluated. The β2 wag mode shows the largest anharmonic contributions. For the torsional mode τ (H2O H‐atom exchange coordinate) the vibrational level structure in an appropriate periodic potential was calculated. On the experimental side resonant‐two‐photon ionization and dispersed fluorescenceemission spectra of 2HN⋅H2O and d‐2HN⋅D2O were measured. A detailed assignment of the bands in the intermolecular frequency range is given, based on the calculations. The predicted and measured vibrational frequencies are compared and differences discussed.
Solvent effects on molecular spectra. I. Normal pressure and temperature Monte Carlo simulations of the structure of dilute pyrimidine in water99(1993); http://dx.doi.org/10.1063/1.465317View Description Hide Description
In this series, our aim is to develop a new scheme based upon a perturbation expansion of the weak intermolecular interactions for the solvent (solvatochromatic) shift of the center of an electronic absorption band in a condensed phase. It is tested by calculation of the shift of the 1(n,π*) absorption and fluorescence spectra of pyrimidine in water. Herein, NPT‐ensemble Monte Carlo simulations are performed to determine the structure of dilute pyrimidine in water at 25 °C and 1 atm. pressure. Six different intermolecular effective pair potentials are used to produce a wide range of hydrogen‐bond structures ranging from 0 to 2 hydrogen bonds per pyrimidine molecule, suitable for subsequent investigations into the correlation of spectral shift with solvent structure. One potential obtained using Kollman's Lennard‐Jones parameters combined with ab initio electrostatic‐potential charges produces the most accurate potential function; this correctly reproduces the observed enthalpy of hydration and partial specific volume of pyrimidine, and produces a chemically reasonable description of the hydrogen‐bond structure.
Solvent effects on molecular spectra. II. Simulations of hydrated clusters and dilute solutions of pyrimidine in its lowest (n,π*) singlet excited state99(1993); http://dx.doi.org/10.1063/1.465318View Description Hide Description
Hydrogen bonding between pyrimidine in its lowest (n,π*) singlet excited state and water in dilute solution is investigated using NPT‐ensemble Monte Carlo simulations, and the properties of the pyrimidine–water complex are examined using molecular dynamics. The 1(n,π*) excitation, known experimentally to be delocalized in the gas phase, is shown to remain delocalized when pyrimidine undergoes hydrogen bonding. Assuming that the intermolecular interactions are electronic state independent, Kollman's Lennard‐Jones interactions are combined with molecular charges obtained in four different ways, generating a variety of intermolecular pair potentials. It is found that, in solution, both pyrimidine–water–hydrogen bonds are considerably weakened in the excited state; however, on average, one hydrogen bond per pyrimidine remains. The excited statehydrogen bonding gives rise to structures in the liquid more like those found in van der Waals bonded systems than in strongly hydrogen‐bonded systems such as ground‐state pyrimidine in water. A blue shift of the absorption band origin is correctly predicted and its magnitude and Franck–Condon contribution are in reasonable agreement with experiment. For pyrimidine–water clusters, minor changes in the intermolecular potential surfaces are shown to cause major qualitative differences in the excited state cluster dynamics, mimicking the observed spectral properties of several different hydrogen‐bonded pyrimidine clusters.
Solvent effects on molecular spectra. III. Absorption to and emission from the lowest singlet (n,π*) state of dilute pyrimidine in water99(1993); http://dx.doi.org/10.1063/1.465319View Description Hide Description
A model is developed for the solvent shift of the center of an electronic absorption or emission band and is applied to the interpretation of the spectra of dilute pyrimidine in water. It is based on the use of standard simulation techniques such as molecular dynamics and Monte Carlo to calculate the liquid structure around the chromophore in its initial electronic state; the solvent shift is then deduced by considering the changes in the electrostatic distribution of the chromophore on vertical Franck–Condon excitation. During the solvent‐shift evaluation only, spherical boundary conditions are used and the sample, containing both the solute and a large number of explicitly polarizable solvent molecules, is placed inside a dielectric continuum. The results show that the solvent shifts of both the absorption and fluorescence spectra of pyrimidine in water are comprised of approximately equal contributions from specific hydrogen‐bonding interactions and long‐range–plus–nonspecific dipole solvation effects. The solvent shift is shown to be very sensitive to the structure of the liquid. A specific aim of our approach is to develop a method applicable to molecular electronic devices, and to inorganic complexes.
Resonance Raman spectrum of the allyl‐d 5 radical and the force field analysis of the allyl radical99(1993); http://dx.doi.org/10.1063/1.465320View Description Hide Description
Resonance Raman spectra of the allyl‐d 5 radical have been obtained with excitation between 247 and 223 nm. Analysis of the spectra yields the first observation of fundamental frequencies, ν4, ν5, and ν7 and overtone frequencies 2ν9, 2ν10, and 2ν12. The new vibrational data are combined with previously observed frequencies of allyl‐h 5 and allyl‐d 5 radical to produce the force field analysis for the allyl radical. This study suggests reassignment of several previously observed infrared (IR) bands. Experimental frequencies and assignments for allyl‐h 5 and allyl‐d 5 are compared with results from ab initio calculations. Force constants obtained in the present work are compared with the force constants of other sp 2 hybridization molecules such as benzene, allene, and ethylene.
Photoabsorption and photoionization cross sections of gas phase GeH4 and Rydberg structures of GeH4 and SiH499(1993); http://dx.doi.org/10.1063/1.465321View Description Hide Description
The photoabsorption and photoionization cross sections of GeH4 from the ionization threshold to 1060 Å have been measured using synchrotron radiation as the continuum light source. The cross sections for the production of neutral products in the same spectral region have also been determined. Weak diffuse structures were observed in both the photoabsorption and photoionizationspectra. The steplike ionization structures in the ionizationspectrum were observed. The adiabatic ionization potential was determined to be at 1177.6±0.5 Å which is in excellent agreement with a value recently reported by Ruscic et al. [J. Chem. Phys. 92, 1865 (1990)] using a photoionization mass spectrometry technique. Rydberg series in the 1060–1180 Å region converging to the ground state of GeH4 + have been tentatively assigned. In addition, the assignments of Rydberg states of SiH4 reported in the literature have been re‐examined in light of the recently reported ionization potential [Berkowitz et al., J. Chem. Phys. 86, 1235 (1987)].
The trans‐bending and F–F stretching vibrations of HF dimer in νHF=1: The influence of intermolecular vibrational excitation on the predissociation dynamics99(1993); http://dx.doi.org/10.1063/1.465322View Description Hide Description
The optothermal detection method has been used to obtain near infrared spectra for combination bands of HF dimer associated with the F–F stretching (ν4) and trans‐bending (ν5) vibrations, built upon the HF fundamental stretches (ν1 and ν2). These spectroscopic results are used to estimate the intermolecular trans‐bend and F–F stretch frequencies, as well as the associated tunneling frequencies, all corresponding to the excited HF stretch vibrational states. Photofragment angular distributions have also been obtained for these excited states. These provide new insights into the effects of intermolecular vibrational excitation on the vibrational predissociation dynamics of this dimer. The initial state dependence of the final rotational state distributions suggests that the intermolecular stretch and bend are decoupled, with the energy in the F–F stretch evolving directly into relative translation of the photofragments, while excitation of the bend has no effect on the average kinetic energy release.
Classical formulation of the spectroscopy of nonadiabatic excited‐state dynamics99(1993); http://dx.doi.org/10.1063/1.465323View Description Hide Description
A general classical formulation of the spectroscopy of nonadiabatically coupled electronic states is developed within the theoretical framework of the classical electron analog model due to Meyer and Miller. Adopting the Heisenberg representation for the calculation of the electric polarization, several approaches are presented to establish a quantum‐classical correspondence. It is shown that a consistent classical formulation is obtained by replacing the quantum‐mechanical commutators, which appear in quantum‐mechanical perturbation theory, by the corresponding classical Poisson brackets which come from classical perturbation theory. The more usual practice of replacing the Heisenberg dipole operators directly by the corresponding classical dipole functions is shown to be an approximation to classical perturbation theory. For a coupled electronic three‐state system explicit expressions are derived for the nonlinear polarization. Furthermore the practical application to femtosecond pump‐probe spectroscopy is discussed in some detail.
Shape‐resonance‐enhanced continuum–continuum coupling in photoionization of CO299(1993); http://dx.doi.org/10.1063/1.465324View Description Hide Description
We have measured photoionization branching ratios and photoelectron asymmetry parameters for photoionization of CO2 leading to the first four electronic states of CO2 + over the photon energy range from 20 to 50 eV. The motivation for this work was the prediction by Lucchese [J. Chem. Phys. 92, 4203 (1990)] that the σ u shape resonance in the (4σ g )−1 C̃ 2Σ g +ionization channel would influence the photoionization dynamics in the other valence‐shell continua through continuum–continuum channel interaction, with the main effect occurring in the (3σ u )−1 B̃ 2Σ u + channel. Indeed, clear evidence for this phenomenon is observed in this channel, the most prominent indication being a broad, shallow minimum in the asymmetry parameter at ∼40 eV. Comparisons of the present results with theory and other measurements reflect good overall agreement and provide some guidance regarding the effectiveness of alternative approximations used in the theoretical calculations.
The determination of excited‐state geometries by analyzing resonance Raman spectra. Example—1(π−π*) state of o‐chloranil99(1993); http://dx.doi.org/10.1063/1.465325View Description Hide Description
Resonance Raman spectra of o‐chloranil were obtained by exciting the energetically lowest π–π* transition. Raman signals of three totally symmetric stretching modes (C=C, C=O, and C–C) showed pronounced intensity alterations. The intensity changes of these modes were analyzed using a dispersion formula which is based on the Kramers–Heisenberg–Dirac equation. Three‐dimensional Franck–Condon integrals were calculated with the algorithm of Kupka and Cribb. The mathematical fitting of the experimentally derived spectra yielded the displacements of the potential curves along the considered normal coordinates and data of the Duschinsky mode mixing. The geometrical shifts along directions of ground‐state normal coordinates were transformed to bond‐length changes with the use of the eigenvector matrix L of the ground‐state vibrations. L was obtained by a complete force field analysis. The excited‐state geometry of o‐chloranil is characterized by the contraction of the di‐keto system accompanied by a weakening of the acrolein unit. The largest changes appear in the butadiene subsystem, where a conversion of bond order occurs between the double bonds and the single bond.
The conformational problem studied through the torsional Raman spectra of CH2DCH2D, CHD2CHD2, and CH2DCHD299(1993); http://dx.doi.org/10.1063/1.465326View Description Hide Description
The torsional Raman spectra of CH2DCH2D, CHD2CHD2, and CH2DCHD2, recorded with an improved conventional Raman spectrometer, are interpreted here in the frame of an exact rotational–torsional Hamiltonian. The kinetic and potential operators of this Hamiltonian are discussed in detail, showing that the term responsible for the existence of two distinguishable conformers is of kinetic nature. For CH2DCH2D and CHD2CHD2 it is shown how to separate the rotational and the torsional motions by means of an appropriate choice of the molecular axis system. The wave numbers and intensities of both torsional Raman spectra are satisfactorily reproduced within the limits of the experiment with the following effective potential parameters: CH2DCH2D, V 3=1002 cm−1, V 6=6.0 cm−1; CHD2CHD2, V 3=995 cm−1, V 6=7.3 cm−1. For CH2DCHD2, only partially tractable in the present approach, an approximate estimate of V 3=995 cm−1 has been obtained. Besides the quantitative interpretation of the torsional spectra, a discussion of the main facts of the conformational problem in connection to the spectroscopic observation is presented. In particular, the induced conformational transitions described here may contribute to the understanding of the elementary photoisomerization processes in molecules of the type AX2Y–AX2Y.
The molecular parameters of the antimony monodeuteride radical from diode laser spectroscopy99(1993); http://dx.doi.org/10.1063/1.465327View Description Hide Description
Extensive measurements of the 3Σ ground stateinfrared spectrum of the antimony monodeuteride radical (SbD) have been carried out using a diode laserspectrometer. Transitions of the fundamental band of all three components of two isotopomers of SbD were measured with a nominal accuracy of ±0.001 cm−1. Only transitions of the O+ component of the v=1←2 hotband were intense enough to be observed. The entire data set was fitted as a single 3Σ state and accurate molecular parameters determined. The LMR data of Stackmann et al. [Mol. Phys. (in press)] on SbH provided invaluable aid with the assignment. Measurements were also carried out on two isotopomers of SbH in order to improve the molecular parameters available for these species.
Femtosecond four wave mixing spectroscopy of conjugated polymers99(1993); http://dx.doi.org/10.1063/1.465328View Description Hide Description
Time‐resolved four wave mixing (4WM) signals of conjugated polymers are calculated using a density matrix approach and the Hartree–Fock approximation. The influence of the Coulomb interaction as well as size effects on the nonlinear optical response are examined. For the Hückel model (no Coulomb interaction), quantum beats due to the coherent excitation of several band states are found for small sizes, and photon echo‐like behavior is obtained for infinite size. The Coulomb interaction changes the nature of the response and gives rise to a broad delayed signal whose temporal profile is determined by the dephasing time.
Dielectric relaxation studies of glass formation in some esters of phthalic acid99(1993); http://dx.doi.org/10.1063/1.465329View Description Hide Description
Dielectric relaxation studies have been made on a series of dialkyl esters of phthalic acid over a frequency range of 20 Hz to 1 MHz and over a temperature range of 77 to 573 K. Studies have also been made above room temperature (up to 363 K) at microwave frequencies of 5.3, 10, and 32 GHz. All the samples in their supercooled liquid state reveal yet another process in addition to the primary or α process. Careful measurements have been made to resolve the secondary or β process from the α process at temperatures above T g . The activation energy of the β process decreases from 39 KJ/mole to 20 KJ/mole with increase in the size of the alkyl group. It is also noted that the bifurcation of liquid relaxation into α and β processes occurs at much higher temperature with increase in the alkyl group. A sharp increase with temperature in the magnitude of the β process in the vicinity of the glass transitionT g temperature, is noted. The relevance of these observations to glass formation in liquids is discussed.
Single crystal electron paramagnetic resonance of γ‐irradiated Hofmann‐type benzene clathrates: Electron capture by Ni(II) center of a polymeric network99(1993); http://dx.doi.org/10.1063/1.465330View Description Hide Description
The electron paramagnetic resonance(EPR) spectra of γ‐irradiated single crystals of M(NH3)2Ni(CN)4⋅2C6H6 (M=Cd and Zn) are studied at 77 K. On the basis of the analysis of spin Hamiltonian parameters, one of the radicals is identified to be Ni(I) species formed due to the electron trap on the Ni(II) center of the polymeric network. The other radical is proposed to be the electron loss M(III) center. Radicals originating from the guest benzene molecules are not formed.
Alternate schemes for the coherent laser control of chemical reactions99(1993); http://dx.doi.org/10.1063/1.466180View Description Hide Description
Several schemes are presented for the coherent laser control of chemical reactions. They are based on the principle of interference between quantum mechanical excitation pathways first proposed by Brumer and Shapiro [Acc. Chem. Res. 22, 407 (1989)]. The conclusion that these schemes may by useful for coherent laser control is based on the fact that, for each of the schemes, the quantum mechanical interference effect has been observed previously in nonlinear optical experiments; however, no attempt to control the interference was attempted in these experiments.
Guided‐ion beam studies of the reactions of protonated water clusters, H(H2O)+ n (n=1–4), with acetonitrile99(1993); http://dx.doi.org/10.1063/1.465331View Description Hide Description
Reactions of protonated water clusters, H(H2O) n + (n=1–4), with acetonitrile are studied by using guided‐ion beam mass spectrometry. Absolute reaction cross sections are determined as a function of the collision energy from thermal energy to over 10 eV. Proton transfer,charge transfer, and dissociativeproton transfer are the reactions seen for n=1. For n=2–4, proton transfer is accompanied by solvent transfer such that the dominant product at low collision energies is H(CH3CN)(H2O) n−1 + in each case. At higher collision energies, additional water ligands are lost and the collision‐induced dissociation products, H(H2O) n‐m + where m=1 to n−1, are also observed. The total reaction cross sections are large and decrease slightly with the number of water molecules. The results indicate that energy transfer in these complexes is efficient and thus are consistent with reactions that proceed via hydrogen‐bonded intermediate complexes.


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Knott County Cooperative Extension
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Yellow Wheat and Cypresses
Art Print
Item #: 11839614A
14" x 11" without border
Ships within 24 hours
High-quality printing gives this fine art print its vivid and sharp appearance. Produced on medium weight cover stock, this art reproduction is coated with a silken finish that protects the inks and creates an elegant look. The versatile art print strikes a balance between quality and affordability.
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- Attractive Frame Design
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This is the perfect picture for our living room, in size, color, a striking picture. When you enter our apartment you see it right away. A fantastic greeting for visitors!
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Owings, MD | May 10th, 2014
Canon 5D MkII
Available for adoption! I'm a sucker for big, dark, gaited horses. Mickey is a 16hh Tennessee Walker/Draft cross and happens to have quite a bit of white on him. Don't tell my husband, but I think I'm in love! This ugly face was made for Brocca, who happened to be trying to steal my camera bag from my back.
© 2014 Kristina Truluck
Facebook | Flickr | 500px
This work may not be reproduced/used by anyone in any manner without my written permission.
I don't mind sharing on social media sites such as Tumblr, Pinterest, etc. as long as you credit
me as the photographer and link back to either my DA account, Facebook page, or Flickr account.
You are so welcome! I don't know if I invited you or not but I have a Facebook Photography page and a website where I feature my artwork. I have not been on here for a while so I can't remember who I have told things to and who I haven't. I make cards, Stickers, Prints (You can also get just the print unframed as well as on; Art, Canvas, Metal, or a Poster), You can get iPhone, iPod, and iPad covers with my photography or digital art design on it. If you would like to check it out I put the links down below, also if you have a page or website you would like me to look at to help support your work PLEASE! Let me know, I would be more than happy to help you out!