text:
Manchester United 3-2 Stoke City
- From the section Football
Late headers by Wayne Rooney and Javier Hernandez rescued Manchester United as the champions fought back from 2-1 down to clinch a dramatic win over Stoke.
Peter Crouch put Stoke ahead when Jonny Evans' clearance hit him and flew in.
Robin van Persie levelled from close range but Marko Arnautovic's curling free-kick restored Stoke's lead.
United were facing a second home defeat of the season but with 12 minutes left Rooney nodded home a corner and moments later Hernandez grabbed the winner.
Relief was the over-riding emotion around Old Trafford at the final whistle following a game in which David Moyes' side laboured for long periods but finished with a flourish to end Stoke's resistance and give their manager a badly needed win.
It was the sort of fightback that was a trademark of Moyes' predecessor Sir Alex Ferguson, who was watching from the stands.
But, in truth, United still appeared a shadow of the side they were under their old boss and Stoke could have been out of sight by half-time.
With only four goals from their first eight games, the Potters were the lowest scorers in the top-flight before kick-off but their manager, former United striker Mark Hughes, still described his old side as "vulnerable" this week.
He was proved right after just four minutes. Erik Pieters broke clear down the left and, although home keeper David De Gea kept out Crouch's first-time shot with an instinctive stop, the ball flew into the United net after Evans smashed it against the Stoke striker.
United's response saw them dominate possession but their threat was restricted by a lack of width or imagination in their passing.
Stoke, in contrast, looked dangerous whenever they broke forward. Crouch went close to making it 2-0 when he hooked a close-range volley over the bar and Steven N'Zonzi saw his snap-shot effort brilliantly kept out by De Gea.
At the other end, Potters keeper Asmir Begovic was only forced into action on the half-hour mark when he tipped over Rooney's 25-yard shot.
United's equaliser came out of nothing after 43 minutes when Begovic kept out Rooney's header but could not react in time to stop Van Persie following up.
Nevertheless, Stoke still deservedly went in ahead at half-time after Phil Jones needlessly barged into Arnautovic on the edge of the area. The Austrian got up to guide a superb free-kick into the top corner for his first Premier League goal.
The home fans expected a response after the interval but they did not get it until Adnan Januzaj was introduced just before the hour mark.
Until then, United had been pedestrian in their passing and had barely threatened Begovic's goal. Afterwards, they began to advance down the flanks and deliver dangerous crosses.
With the pressure building, Rooney met Van Persie's corner with a looping near-post header that dropped into the opposite corner of the net.
And Hernandez, who like Januzaj had started the game on the bench, got the winner two minutes later, timing his run perfectly to convert Patrice Evra's precise cross from the left.
Manchester United boss David Moyes said:
"I thought with 15 to 20 minutes to go the supporters were terrific - they drove the team on and they played a big part in getting the result.
"I thought in the end we had to go for it. I thought we did a lot of good things but an awful lot of really poor things that put us in the situation we were in.
"We got ourselves back in the game just before half-time only to concede from a poor, poor free-kick.
"That got us going in at half-time on a downer but I said at half-time your job is to win the game and you're more than capable of doing it. We needed the substitutes today and they made a big difference."
Stoke manager Mark Hughes:
"I do think it was unjust, in terms of what we produced, the effort we put in and the chances we created.
"I certainly felt in the first half we could have been three or 4-1 to the good in terms of chances created. I didn't think United created much apart from the key moments that took the game away from us.
"We're really disappointed given the level of performance we produced. We had a game plan today which needed commitment, it needed people to be brave and do the hard yards that affected the game, and that's what we did.
"I thought my players were excellent, they took the game to United and really shook them."
Man Utd
- 1de Gea
- 12SmallingSubstituted forA Valenciaat 76'minutesBooked at 90mins
- 3Evra
- 23CleverleySubstituted forHernándezat 68'minutesBooked at 69mins
- 4Jones
- 6Evans
- 17NaniSubstituted forJanuzajat 58'minutes
- 16Carrick
- 20van Persie
- 10Rooney
- 26Kagawa
- 2Rafael
- 13Lindegaard
- 14Hernández
- 18Young
- 25A Valencia
- 31Fellaini
- 44Januzaj
- 1Begovic
- 20Cameron
- 3Pieters
- 15N'Zonzi
- 17ShawcrossBooked at 45mins
- 4HuthBooked at 84mins
- 19Walters
- 8PalaciosBooked at 65minsSubstituted forWhelanat 70'minutes
- 25CrouchBooked at 43mins
- 32IrelandBooked at 63minsSubstituted forAdamat 82'minutes
- 10ArnautovicSubstituted forWilsonat 49'minutesBooked at 67mins
- 6Whelan
- 9Jones
- 12Wilson
- 16Adam
- 24Assaidi
- 28Wilkinson
- 29Sørensen
- Referee:
- Lee Mason
- Attendance:
- 75,274
Match Stats
- Possession
- Home67%
- Away33%
- Shots
- Home19
- Away10
- Shots on Target
- Home5
- Away5
- Corners
- Home12
- Away2
- Fouls
- Home8
- Away18

subset: commoncrawl


text:
SageQuest Named NCTC Exclusive Provider For GPS Fleet Tracking And Business Intelligence
BOSTON, Feb. 13, 2013 /PRNewswire/ -- SageQuest, a leading GPS-based fleet management and business intelligence software as a service (SaaS), has been named an Exclusive Provider by the National Cable Television Cooperative (NCTC). SageQuest is a branded offering from Fleetmatics Group PLC (NYSE: FLTX). "NCTC partners with providers that offer simple solutions for our members, and SageQuest delivers another strong choice when helping our members to cost effectively expand their reach of service and improve profitability," said Corey McCarthy, CFO for NCTC. "We were attracted to the SageQuest platform because of its proven support to cable operators and telecomm companies, as well as its unique business model and member friendly pricing."Cable operator and telecomm company customers of SageQuest include NCTC members Buckeye Cable System, NewWave Communications, Wave Broadband and Midcontinent Communications. The Fleetmatics Group has been invited by NCTC to present SageQuest to its members at their upcoming Winter Education Conference, being held in Las Vegas, Feb. 25-26. "Fuel savings, less accidents, and timely customer service are just a fraction of the benefits our customers realize," said Karl Weber, vice president of sales SageQuest. "Our cable operator and telecomm company customers appreciate the sense of comfort gained from knowing that their drivers are safe and serving customers, as this allows them to focus on other mission critical areas of their business." About Fleetmatics Group Fleetmatics Group PLC is a leading global provider of fleet management solutions for small and mid-sized businesses delivered as software-as-a-service (SaaS). Our solutions enable businesses to meet the challenges associated with managing local fleets, and improve the productivity of their mobile workforces, by extracting actionable business intelligence from real-time and historical vehicle and driver behavioral data.
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text:
... 5/500
Tylenol with Codeine - how many tylenol 3 do you have to take to make it equal to 1 hydrocodone?
- Posted:
- 6 Nov 2009 by menter-z
- Topics:
- tylenol, tylenol with codeine, codeine, hydrocodone
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text:
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text:
|Publication number
|Publication type
|Publication date
|Jun 30, 1959
|Filing date
|Apr 2, 1956
|Priority date
|Apr 2, 1956
|Publication number
|Rudner Bernard
|Original Assignee
|Grace W R & Co
|Export Citation
|BiBTeX, EndNote, RefMan
|Non-Patent Citations (1), Referenced by (18), Classifications (25)
|External Links: USPTO, USPTO Assignment, Espacenet
2,892,841 Patented June 330, 1959 PROCESS FOR AMINATIN G NITROGEN-CON- TAINING HETEROCYCLIC COMPOUNDS Bernard Rudner, Baltimore, Md., assignor to W. R. Grace & Co., New York, N.Y., a corporation of Connecticut No Drawing; Application April 2, 1956 Serial No. 515,347
Claims. (Cl. 260-288) This invention relates to a process for aminating aromatic heterocyclic compounds characterized by the presence of at least one tertiary N atom in a conjugately unsaturated heterocyclic ring. The amino derivatives prepared by the novel method of the present invention are alpha amino derivatives, i.e., those in which the sole hydrogen on the annular carbon atom attached to the annular tertiary N atom by a double bond is replaced by an amino group. In a specific aspect, the present invention is directed to a novel method for preparing alpha amino derivatives of compounds such as pyridine and its fused ring derivatives, for example, Z-aminopyridine, 2-aminoquinoline, and alpha amino (or l-amino) isoquinoline.
Heretofore, Z-aminoquinoline, for example, has been prepared by contacting quinoline 2-sulfonic acid with an ammonia solution containing about 1 part zinc chloride andthe mixture heated for several hours in a closed vessel at about 135 C. Z-aminopyridine has been prepared commercially by reacting pyridine With sodamide, whereby sodamide forms an addition product with pyridine, that upon hydrolysis yields sodium hydroxide, ammonium hydroxide, hydrogen, and 2-aminopyridine. The Z-amino derivatives of both pyridine and quinoline are also prepared by reacting quinoline or pyridine with ammonia in the presence of a Raney nickel catalyst. This latter process is carried out in an autoclave at between about 200 and 490 C. over a period of about 17 hours. While the latter method offers obvious advantages over either of the former processes for preparing the Z-amino compounds, the process is time consuming, requires the addition of external heat, and necessitates special pressure equipment. Accordingly, a process which could be carried out at atmospheric pressure, without the addition of heat, and which would employ cheap reagents should be commercially attractive. With the, advent of an economically very attractive method of preparing chloramine by the vapor phase reaction between ammonia and chlorine gas, a low cost reagent has been provided.
In accordance with the present invention, liquid pyridine, quinoline or isoquinoline is contacted with chloramine at atmospheric pressure and temperatures ranging from about 10 C. to about 100 C. An unreactive solvent may be conveniently used as a reaction medium, but the presence of such a solvent is not essential. The term unreactive describes solvents that do not preferentially combine with the product or the reactant.
As the reaction proceeds there is formed a dark solid which is insoluble in the starting heterocyclic compound. The solid is separated from the reaction mixture, and a major portion of the alpha amino compound thus formed is generally present in this dark solid as the hydrochloride salt. The hydrochloride of the alpha amino compound is recovered from the solid by fractional crystallization or equivalent methods. A minor portion of the alpha amino compound remains in reaction mixture as the free base and may be recovered by preferential extraction, fractional distillation, or other standard physical methods of separation. Alternately, the reaction mixture maybe acylated, e.g. with acetic anhydride; the acylated 0t-amiIlO heterocyclic may then be freed of unacylated parent heterocycle by suitable and common laboratory procedure such as distillation. The acylated product is deacylated by hydrolysis.
While the present process has thus far been described with reference only to chloramine, the present invention also contemplates the use of chloramine diluted with an inert gas such as nitrogen, or with a diluent gas such as ammonia which undergoes reaction to form ammonium chloride, but which does not inhibit formation of the desired aminated products. Generally it will be most convenient to employ the chloramine-ammonia mixture resulting from the above-noted chloramine synthesis. While the process thus far described utilizes excess basic heterocycle as solvent, it is not necessary to so limit the invention. I have found that unreactive solvents such as the alkanes (e.g. hexane) aromatics (e.g. xylene), haloaromatics( e.g. chlorobenzene), ethers (e.g. dioxane) and other classes could be used advantageously in place of excess heterocycle. The qualification unreactive is not limited to organic solvents, since I have found that aqueous pyridine undergoes this reaction.
The following non-limiting examples illustrate the general method of the present invention.
Example I A chloramine-nitrogcn-ammonia gas stream'containing a total of approximately 6.6 g. ClNH was passed, over a period of 30 minutes, into a flask containing ml. of pure pyridine. Within a very few minutes, an exothermic reaction started, the pyridine turned dark brown, and a crystalline precipitate was formed. A cold water bath was used to keep the reaction temperature below 60 C.; in spite of this bath the reaction temperature remained at 48-52 C. Chloramine was absorbed almost quantitatively; even with relatively poor gas-liquid contact less than 4% of the chloramine passed through the pyridine unreacted. Within five minutes after the chloramine stream had been shut-off, all of the chloramine had been reacted (i.e.: had lost its power to oxidize acidified KI solution to iodine). After 24 hours, the reaction mixture was filtered, the dark filtrate allowed to evaporate dry, and the pyridine-washed, brown solid was dried. It weighed 5.1 g., and was shown, by standard analytical procedures, to be a mixture of several compounds including ammonia chloride and Z-aminopyridine hydrochloride. The aminopyridine was isolated as follows: The crude hydrochloride mixture was just neutralized with sodium bicarbonate; it was acylated with excess acetic anhydride, and evaporated in vacuo to dryness. The residual solid was extracted with chloroform in five portions of 100 ml. each and the combined chloroform extract in turn extracted with three 50 ml. portions of 1 N HCl. The acid extract was made just alkaline with solid Na CO and re-extracted with three 100 ml. portions of chloroform. Evaporation of the chloroform solution gave Z-acetylaminopyridine, which, after recrystallization, melted at 70-71 C. (literature value 71 C.). Boiling hydrochloric acid solutions converted this product to 2- aminopyridine hydrochloride, a hygroscopic solidmelting at 215 C. (literature value 217 C.). The action of caustic on the aqueous hydrochloride gave Water-soluble Z-aminopyridine, Ml. 58-85 (literature value 60 C.). Infra-red and ultra-violet absorption studies on the hydrochloride confirmed its identity.
The black reaction filtrate was evaporated to dryness in an air stream at room temperature. From the dark gum thus obtained there were isolated, by fractional solubilization, Z-aminopyridine, M.P. 61 C. (after recrystallization from hexane) and 2-aminopyridine hydrochloride, M.P. 215 C (after, recrystallization, from 2-propanol).
In other experiments with the same reactants, it was demonstrated that externalconditions (viz: solvent used, temperature, pressure) altered the yields, the ratio-of aminopyridine to its hydrochloride, the ratio of both to other organic products and even the nature of the products. Reaction at higher temperatures favored increased yields of organic products, including the desired aminopyridine.
From a reaction run at 10-15 C. there was obtained a. lower yield of products as Well as a lower ratio of aminopyridine hydrochloride to aminopyridine. Visible reaction at -40 C. was very slow; not until the mixture had warmed up to about -.l C. was there a rapidand exothermic formation of a solid. Fractional crystallization of this precipitate from absolute alcohol gave pure 2,-arninopyridine hydrochloride, M.P. 2l52l6 C., which was characterized by its conversion (when treated with the appropriate reactant) to Z-aminopyridine, M.P. 53- 54 C.; 2-benzenesulfonylaminopyridine, M.P. 149-150 C and 2-(4-dimethylaminobenzylidene)aminopyridine, M.P. 119120 C. Evaporation of the black filtrate from which the Z-aminopyridine hydrochloride was obtained) left a dark tar, from which a minor quantity of 2-aminopyridine was isolated. A similarly small quantityv of the same substance was found to be adsorbed on the initial precipitate.
Example 11 In aqueous solution, this reaction goes with greater vigor, and by a somewhat different route, it is believed. A 90:10 water-pyridine mixture (kept in an ice-bath) treated over 74 minutes, with approximately g. of chloramine (in a gaseous mixture as before), gave an immediate, exothermic reaction which raised the solution temperature to 30 C. However, the chloramine uptake was neither as rapid nor as quantitative as in anhydrous reactions; over 10% of the chloramine passed through the reaction mixture unchanged. From the hygroscopic mixture of white, yellow, and brown solids obtained on evaporating the clear reaction medium there were obtained crude 2-aminopyridine and 2-aminopyridine hydrochloride, M.P. 51-53 and ZOO-210 C., respectively. The latter product was contaminated by an appreciable quantity of another salt tentatively identified as l-aminopyridinium chloride,
When the aqueous. reaction was run without any temperature control, the solution temperature rose quickly to 60-65 C., then gradually dropped to about 55 C. The chloramine uptake was almost quantitative. The mottled solid obtained on evaporation analyzed 55.7% ionizable chloride (pure ammonium chloride analyzes 66.4% C1), and was found to be a mixture comprising 2-aminopyridine, Z-aminopyridine hydrochloride, and 1- aminopyridinium chloride. The two isomericsalts were differentiated on the basis of their benzenesulfonyl derivatives, 2-aminopyridine hydrochloride forming an acid and alkali-soluble derivative (Reaction A) and l-aminopyridinium chloride forming an alkali-insoluble, acid-soluble derivative (Reaction B).
(2-benzenesuli0namldopyridine) (pyfidined-benzenesullonyllmlne) Example Ill plete. The dried precipitate was, by chloride analysis, 61% pure 2-an1inoquinoline hydrochloride (see Reaction C).
(z-aminoquiuolinehydrochloride) Part ofthisdesirable product was isolated bytedious fractional recrystallizations from ethanol and chloroform. Recrystallization to a constant melting point gave pure Z-aminoquinoline hydrochloride, M.P. 222-223 C. Its identity was established by conversion (using appropriatereactants) to its freebase, 2-aminoquinoline, M.P. 126- 127 C., and to Z-aminoquinolinepicrate, M.P. 251- 252.5 C. Another portion of the original reaction precipitate was dissolved in a small quantity of hot water, charcoaled, andthen treated with excess 40% aqueous NaOH solution. On cooling, the reaction mixture plates of Z-arninoquinoline precipitated, M.P. 127.5-l27.8 after recrystallization (literature value 129 C.)
Evaporation of the black quinoline filtrate in vacuo gave a dark tar from which Z-aminoquinoline and 2- anu'noquinoline hydrochloride were isolated. Of the several products of this reaction, the aminoquinoline and its hydrochloride were the most important yieldwise, being isolated in'well over 40% of the theoretical yield. The ratio of hydrochloride formed to free amine was almost 10:1.
quinoline, v
25 ml. in 50 ml. mixed xylenes, gave the same-exothermic reaction and dark precipitate. Because of the dilution with an inert solvent, however, the chloramine uptake was not as nearly quantitative as that described in Example III. The tan solid which precipitated was a mixture of several compounds, including ammonium chloride and 1-aminoquinoline hydrochloride in approximately a 3:1 ratio. An aqueous solution of this precipitate, washed with carbon tetrachloride and then charcoaled, gave, on addition of sodium hydroxide, l-aminoisoquinoline. This, product, after recrystallization from water, formed plates melting at 1225-1235 C. (literature value 123 C.). The hydrochloride, prepared by evaporatingto dryness an HCl solution ofthe recrystallized free base, melted at 234:2355 C. (literature value2j33-234" C.). A clari: fied aqueous solution ofztheprecipitate, free of occluded isoquinoline, gave with aqueous picric acid, l-aminoisoquinoline picrate, yellow micro-crystals melting at 290- 291.5 C. (literature value 290-291 C.). The tan reaction precipitate, as isolated, was also found to contain a small quantity of the free base, l-aminoisoquinoline, and a smaller quantity of the isomeric B-aminoisoquinoline. These products were separable from the aforementioned components of the solid by virtue of their water-insolubility. In addition, the water-soluble portion of the precipitate was found to contain, in minor quantities, an ionized organic chloride whose high water solubility, stability toward alkali, and reactions with sodium picrate and potassium hexafluorophosphate suggest that it is Z-aminoisoquinolinium chloride.
Evaporation of the dark filtrate from the reaction mixture gave a black, tacky solid, roughly Vs the weight of the reaction precipitate. Extraction with water gave, after purification, 1-aminoisoquinoliue hydrochloride, M.P. 232- 233.5 C. Extraction with boiling water gave, on cooling, appreciably more l-aminoisoquinoline as flat plates, M.P. 118-121" C. (121-122 C. after two recrystallizations from water). There is some evidence, e.g. reaction with potassium hexafluorophosphate, that both the hot and cold aqueous extracts contain a small quantity of a solid tentatively identified as 2-aminoisoquinolinium chloride. It is rather surprising that such a highly polar compound would be found in the reaction filtrate, instead of the precipitate.
In summary, it should be noted that the reaction of gaseous chloramine with isoquinoline gave a mixture of products including l-aminoisoquinoline (a), l-aminoisoquinoline hydrochloride ([2), 3-aminoisoquinoline (c), and Z-aminoisoquinolinium chloride (d) (see Reaction D below) in an approximate yield ratio of 4:20:1z1.
O1" N-HCl N N-NH:
Example V Replacement of isoquinoline in the preceding example by a like quantity of a-lutidine (2,4-dimethylpyridine), gave a similar reaction, although somewhat less exothermic. The reaction precipitate, lighter in color than that of Example IV, consisted chiefly of ammonium chloride, the hydrochloride and free baseof 2-amino-4,6-di methylpyridine, and a smaller quantity of a dark, waterinsoluble, acid-soluble solid which I have tentatively identified as the novel, 2,4-lutidine-1-imine. The two major products, which occur in the precipitate in approximately a 7:1 ratio, were separated from the rest of the precipitate by dissolving them in cold water. By making this aqueous extract alkaline and chilling, I precipitated 2-amino-4,6-lutidine, dull plates melting at 65-67 C. Its hydrochloride, obtained from the free base by the method described in Example III, melted with decomposition at approximately 221 C. The water-insoluble portion of the reaction precipitate gave, on extraction with HCl, followed by subsequent neutralization, additional 2-amino-4,6-lutidine (this is considered proof that the free base occurs as such in the reaction precipitate). The mother liquor from this neutralization step was found to contain traces of a highly hygroscopic water-soluble solid which gave a precipitate with KPF This suggests that a second water-insoluble component of the initial precipitate was the novel 2,4-lutidine-limine (a), converted by HCl to the water-soluble 1- amino-2,4-lutidinium chloride (b) shown hereunder:
Example VI Oxine, more properly called 8-hydroxyquinoline, 25 g. in ml. dimethylformamide, was saturated with ammonia to form a yellow suspension of its ammonium salt (Reaction G), then subjected to a chloramine gas stream as described in Example I. An exothermic reaction ensued.
The mixture turned in color from yellow to orange to deep red; a phase-change was observed in the solid; and it was necessary to use a cold water-bath to hold the temperature of the reaction mixture down to 55 C. Chloramine uptake was quantitative and rapid. By the time the reaction mixture had cooled to room temperature after gasification, the chloramine had all reacted. The solid was filtered off and examined; it was found to be largely ammonium chloride. However, extraction of the product with 2-pr0panol gave, on evaporation of the solvent, a dark mixture containing Z-amino-S-hydroxyquinoline (as its ammonium salt, M.P. 210 C. (d)), and a smaller quantity of a dark solid believed to be l-amino-8-hydroxyquinolinium betaine.
Evaporation of the reaction filtrate gave an appreciable quantity of dark solid. After removal of the unreacted hydroxyquinoline (2.8% of the starting weight), it was shown to be chiefly 2-amino-8-hydroxyquinoline (a), M.P. 60-61.5 C. There was also present a very small quantity of the compound believed to be the betaine (b).
in 15% NH OH, containing 1 g. of the sulfonic acid, was treated dropwise, over 45 minutes at 10-15 C.,
with three equivalents of aqueous chlorarnine (P pared according to the procedure in Inorganic Syntheses). 'Afterbeing 'allowed'tostand over night, the solution had turnedfrom'yellowto'green. The solution was evaporated to dryness under aspirator vacuum. Extraction of the chloramine-free greenish residue with 2-propanol gave a very'low yield of a chloride-free solidto which was tentatively assigned the structure I-amino-S-hydroxy-S- sulfoquinolinium betaine. Extraction of the Z-propanolinsoluble part of the product with concentrated hydra chloric acid gave, as residue, a mixture of sodium chloride and, presumably, 2-amino-8-hydroxy-5-sulfoquinoline hydrochloride. 'The latter product, on extraction with ethanol and evaporation, was converted to the free base and 'HCl (which was largely lost on evaporation). The product'thus obtained 2-aminoS-hydroxyquinoline-S- 'sulfonic acid,-was a greenish yellow solid that -'decomposed'withoutmelting-above 250 C. It was moderately soluble in' -water,increasingly'so in alkali, and less so in concentrated acid. It formed an S-benzylis'othiuronihm salt that'decomposedat l87-189'.5 C.
In-subsequent experiments itwas found possible to add sodiumlhypochlorite solution to the ammonium salt of oxinesulfonic acid and isolate a small yield of the desired Z-amino derivative. The low yieldand the difliculty in obtaining a pure compound, however, countervail the simplicity ofthe initial operation.
In addition to the above mentioned experiments, the followingresults have been obtained:
Exf Starting base Product and Description of structure reaction VIIL. P-Picoline 2-amlno-6-methy1- Some evidence for forpyrldlne'andhymation of 4-amlno. drochloride Amine to salt ratio approidmately 1:8. Overall yield less than Example I.
(-HOI). V HQN CHI IX... 'i-Plcoline 2-'amino 4-methyl- 'Yleld less than Expyridine and hyample VIII. Proddrochloride uct ratio-almost th same. 7
X'.... 26-lutidin 4-amino-2.6-dimeth- Crude starting -base. ylpyrldine Low yield of prodnot, no hydrochloride. Evidence for N-amlnolutidinium chloride.
XI..- Nicotine-acid..- fi-aminonlcotinic Had to prepare anhyacid drous NHrsalti-lrst. No hydrochloride or otherisomers. Yield E fair.
XIL- Quinaldinc -a-minoquinaldine Poor yield. Strong and hydrochloride evidence ior'l aminoqulnaldinium coni- NH; pound.
It is obvious that novel reaction 'is applicable, to a lwi rang of ubstituted pyridinesjand their fused homologues. For example, a list of other suitable pyridine derivativeswould include pyridoxin, nicotinamide (and its diethyl homologue, the heart stimulant, nikethamide), 2-, 3:, and 4-vinylpyridine; the halopyridines; dipyridyl; I 5,6,7,8-tetrahydroquinoline, 4-benzylisoquinoline, etc. 'In addition to the treatment of pyridine and itsfused'ring derivatives, quinoline and isoquinoline, the process of the present invention provides a method for aminatingthe'carbon atom attached to the tertiary N atom" by 'adouble bond in a wide variety of N-containing heterocycles. This group includes compounds of the oxazole, thiazole, diazole, diazine, and triazinc families, and the purines.
The major'value of my novel process is in the direct preparation of commercial and potentially commercial productsby a simple, hazard-free reaction that requires no autoclaves or similar "expensive equipment. Thus manufacture of Z-aminopyridine, an important dye, drug and polymer intermediate, now requires a hazardous reaction in liquid ammonia,'entailing the use of expensive autoclaves and recycling systems. By my novel reaction, I have prepared Z-aminopyridine at atmospheric pressure,'in an open system requiring no liquid ammonia. Aminonicotinic acid, a valuable anti-metabolite, is at presentprepared by amination of-f3-picoline, acylation of the amino group for protection, oxidation of the --CH to -CO H, and then'hydrolysis to the desired product. My present invention provides a direct amination of nicotinic acid (itself directly obtainable from the picoline), and therefore makes possible a 2-step process for the manufacture of the anti-metabolite.
1. A process'for preparing the alpha amino derivative of an aromatic'compound containing a sole tertiary nitrogen atom in a conjugately unsaturated siX-membered ring, wherein said compound at l0 to C. is subjected to the action of chloramine whereby the hydrogen on the annular carbon atom attached by a double bond to said tertiary nitrogen is replaced by the -NH group of said chloramine and recovering said alpha amino derivative of said aromatic compound from the reaction mixture.
2. A process according to claim 1 wherein the chloramine is introduced as part of a gas stream beneath the surface of the aromatic compound, said compound being in the liquid phase.
3. A process according to claim 1 wherein the chloramine is introduced as part of a gas stream beneath the surface of the aromatic compound, said compound being dissolved in an unreactive solvent.
4. A process according to claim 1 wherein the aromatic compound is pyridine.
5. A process according to claim 1 wherein the aromatic compound is quinoline.
6. A process according to claim 1 wherein the aromatic compound is isoquinoline.
7. A process according to claim 1 wherein the aromatic compound is 2-picoline.
8. A process according to claim 1 wherein the arematic compound is 2,4-lutidine.
9. A process for preparing alpha amino derivatives of aromatic compounds selected from the group consisting of pyridine, picoline, lutidine, quinoline and isoquinoline whichcomprises reacting said-liquid aromatic compound at -l0 to 100 C. with chloramine whereby the hydro- References Cited in the file of this patent C. 'Boa'tman: 'Ph. D. Thesis, The Ohio State University, I951, pp. 32 and 64.
|Citing Patent
|Filing date
|Publication date
|Dec 18, 1958
|Oct 19, 1965
|Colgate Palmolive Co
|N, n-disubstituted-n'-phenylalkyl hydrazines
|Aug 30, 1984
|Dec 9, 1986
|Bayer Aktiengesellschaft
|Process for the preparation of 2-amino-alkylpyridines
|Mar 25, 1998
|Oct 23, 2001
|Guilford Pharmaceuticals Inc.
|Compounds, methods and pharmaceutical compositions for treating neural or cardiovascular tissue damage
|Sep 3, 1997
|Feb 12, 2002
|Guilford Pharmaceuticals Inc.
|Poly(ADP-ribose) polymerase inhibitors and method for treating neural or cardiovascular tissue damage using the same
|Jun 1, 2001
|Feb 19, 2002
|Guilford Pharmaceuticals Inc.
|Methods, compounds and compositions for treating gout
|Nov 15, 2000
|Apr 30, 2002
|Guilford Pharmaceutical Inc.
|Alkoxy-substituted compounds, methods, and compositions for inhibiting PARP activity
|Dec 31, 1998
|May 14, 2002
|Guilford Pharmaceuticals, Inc.
|Phenazine compounds, methods and pharmaceutical compositions for inhibiting PARP
|Sep 1, 1998
|May 28, 2002
|Guilford Pharmaceuticals Inc.
|Carboxamide compounds, methods, and compositions for inhibiting PARP activity
|May 15, 1998
|Jul 30, 2002
|Guilford Pharmaceuticals Inc.
|Alkoxy-substituted compounds, methods and compositions for inhibiting parp activity
|Sep 1, 1998
|Feb 4, 2003
|Guilford Pharmaceuticals Inc.
|Compounds, methods and pharmaceutical compositions for treating neural or cardiovascular tissue damage
|Jul 2, 2001
|Apr 8, 2003
|Guilford Pharmaceuticals Inc.
|Substituted 4,9-dihydrocyclopenta[imn]phenanthridine-5-ones, derivatives thereof and their uses
|Sep 1, 1998
|Oct 21, 2003
|Guilford Pharmaceuticals Inc.
|PARP inhibitors, pharmaceutical compositions comprising same, and methods of using same
|Feb 13, 2001
|Apr 6, 2004
|Guilford Pharmaceuticals, Inc.
|Compounds, methods and pharmaceutical compositions for treating cellular damage, such as neural or cardiovascular tissue damage
|May 15, 2001
|Apr 20, 2004
|Guilford Pharmaceuticals, Inc.
|Sulfonamide and carbamide derivatives of 6(5H)phenanthridinones and their uses
|Feb 6, 2004
|Dec 11, 2007
|Mgi Gp, Inc.
|Compounds, methods and pharmaceutical compositions for treating cellular damage, such as neural or cardiovascular tissue damage
|Feb 6, 2004
|Apr 7, 2005
|Guilford Pharmaceuticals, Inc.
|Compounds, methods and pharmaceutical compositions for treating cellular damage, such as neural or cardiovascular tissue damage
|Nov 27, 2014
|Mar 25, 2015
|Method for synthesizing aminopyridine with pyridine base mixture as well as separation and purification method of aminopyridine
|Sep 2, 1998
|Mar 11, 1999
|Guilford Pharmaceuticals Inc.
|Amino-substituted compounds, methods, and compositions for inhibiting parp activity
|U.S. Classification
|546/143, 546/311, 546/304, 546/159
|International Classification
|Cooperative Classification
|European Classification


text:
"List one thing about your appearance you would change if you could," I challenged my Bible study teens.
"Just one?" they responded in unison.
Each of the seven had her own complaint: high forehead, crooked nose, too fat, too fat, too fat, thin hair, too short.
I reminded them that the Biblical words "fearfully and wonderfully made," used to describe how God knit them together in their mother's wombs, were not followed with "except." God saw them perfect ... just the way they were. Why couldn't they see themselves as He did?
I listed their attributes and their accomplishments; I told them they were precious to God, but these reminders fell on deaf ears.
As we probed deeper, I was astonished to learn that they were unconfident even in the school hallways between classes, wondering if other students were mocking their gait, their bangs, their shoes ... whatever baggage of insecurity they were lugging.
And these were some of the most popular girls in our school.
"First of all, look at each other. Do you see a high forehead, a fat body, a crooked nose?" I asked.
Of course they didn't. They were shocked because they knew each other well and saw their friends as so "together." Surely this group of peers couldn't be as insecure as they!
That conversation took place a few years ago, but it's equally true now. In my speech class assignment on self-concept, students are to write five adjective-noun combinations that describe them.
Typically they are negative (i.e. unkind brother, stupid student, uncoordinated athlete, etc.). Next to each description they are to explain who or what labeled them as such. Parents are the main culprits. But classmates run a close second. Predominantly middle schoolers.
Apparently if a 14-year- old can squash whatever self worth a classmate has managed to salvage up to that point, she claws up a rung or two on the status ladder. How sad!
The hormonal roller coaster ride, the gangly legs, the acne breakouts and the underarm fuzz should be enough to make one feel inadequate. Who needs friends to keep you in low places?
The Bible makes it clear that being a beautiful person does not guarantee a blessed life. Think about it.
Joseph's brothers sold him into slavery.
Rachel was beautiful. And jealous. And manipulative. And died in childbirth.
Saul, Israel's first king, was petrified of his position and was dethroned because of his disobedience.
Samson could have won the Mr. Universe contest, except it's hard to impress the judges when your eyes have been gouged out.
And lest we forget, there was hunk King David who was also an adulterer, a murderer, a poor father, and not such a great husband.
The teens in our Bible study were no different than the ones I teach now. They had bought into the ever-popular air-brushing lie, believing beauty guarantees the perfect marriage and the perfect life.
Halle Berry and Christie Brinkley know otherwise. As gorgeous as they are, their husbands weren't satisfied.
I told the girls I could name on one hand the number of famous movie stars whose marriages survived into their golden years. But actually, I couldn't.
Far too many of us tend to look in the mirror and see only flaws. We fail to understand that true beauty begins when God transforms our hearts.
After all, He is the ultimate makeover artist. His work just happens where it matters -- on the inside.


text:
Lucy Edna Moore, 87, of Tiptonville, died Tuesday, June 9, 2009 at Baptist Memorial Hospital in Union City.
She was a retired employee of Dairy Queen, a Baptist and an avid gardener.
Graveside services will be at 10 a.m. today in Lake Memorial Gardens in Tiptonville with Dr. Carl Mills officiating. Dyersburg Funeral Home is in charge of arrangements.
Survivors include two daughters, Edna Mills and Elaine Haggard, both of Tiptonville; a son, James "Buddy" Moore of Tiptonville; five grandchildren, Mistee Osteen Johnson, Tammy Osteen King, Chris Walton, Lewis Walton Jr. and James "Buddy" Moore Jr.; and numerous great-grandchildren.
She was preceded in death by her husband, Jim Henry "Bud" Moore; and her parents, Oather and Myrtle Wiggins Price.
Pallbearers will be Jimmy Simmons, Johnny Dean, Greg Williams, Craig Williams, Frank Tatum and Dwayne Haggard.
Charles W. Simpson, 75, of Finley died Monday, June 8, 2009 at his residence.
Funeral services will be at 11 a.m., Thursday, June 11, 2009 in the chapel of Curry Funeral Home officiated by Brother Doug Ellingsworth with interment to follow in Fairview Cemetery. Visitation will be 5-8 p.m. Wednesday, June 10, 2009 at Curry Funeral Home.
Pallbearers will be Art McDonald, Terry Simpson, Patrick Koch, Mike Klingeman, Donald Wade and Bob Simpson.
Survivors include a daughter, Dianne Wade and husband, Donnie, of Cuba, Mo.; a son, Rickey Simpson of Finley; two sisters, Martha McCanless of Dyersburg, and Carolyn McDonald and husband, Art, of Finley; four brothers, Ray Simpson of St. Louis, Mo., Hershell Simpson of Finley, Bill Simpson of Covington, and Benny Simpson of Anderson, S.C.; and three grandchildren and seven great-grandchildren. He is also survived by four dear brothers-in-law and sisters-in-law, and several nieces and nephews.
He was preceded in death by his wife, Rose Simpson; his parents T.H. "Bud" Simpson and Rebbie Simpson; and five sisters, Mary Hudson, Glenda Patterson, Lola Mae Simpson, Christine Simpson and Linda Simpson.
Online condolences may be given at www.curryfuneral.com.


text:
Missouri State History Lapbook - PDF Download [Download]
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Product Description
This lapbook is designed for students in grades K-8, and includes both a study guide as well as lapbook pages in a single PDF download. The included state-specific study guide provides background material, historical notes, and other factual information; students will explore state symbols, songs and landmarks, famous people, geographical regions, timelines of historical events, and more. Parents should note that this study guide is identical to the study guide in the sold-separately lapbook journals (which are designed for children in Grades 6-12) so that parents can cover the information once with students of all ages.
The download provides one PDF file, which contains the six booklet templates and instructions. The "lapbook base assembly and layout guide" provides instructions and diagrams to guide students on the assembly process; the student instruction guide covers what should be written inside each booklet. The lapbook booklet templates are designed to be glued onto manila folders (purchased separately). Students will complete booklets with information on the state's population, borders, statehood, land area, and more.
This lapbook resource is in downloadable PDF format. All elements are in a single PDF.
Product Information
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Vendor: Knowledge Box Central
Publication Date: 2012
Availability: In Stock
Series: Knowledge Box Central
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HOME NBA Portland Trail Blazers Gear Portland Trail Blazers Shorts & Pants (27 items) Product ID: 1479964
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HN-JAI006 Jacki Design
Girlie Glam Blue Jewelry Ring and Earring Holder - 4W x 7H in.Item # HN-JAI006
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- Made of polyresin, fabric and wire
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Girlie Glam Blue Jewelry Ring and Earring Holder - 4W x 7H in.
About Jacki Design InternationalBased in Los Angeles, Jacki Designs imports gifts, jewelry, displays, train cases, cosmetic bags, and accessories. They take pride in keeping up with very latest trends and offer superior quality, affordable items perfect for today's homes. Whether you're shopping for wedding accessories or gifts, Jacki Designs has something for you. You'll love the vibrant colors, sparkles, and smart design on all their products.


text: Recent News From AOCDS MEMBER ADVISEMENT: Our Profession April 26, 2016 A just society cannot exist without those sworn to carry out law and order. A just society cannot exist if society's protectors harbor hate and resentment for the very people they are sworn to safeguard. There is no room in the… April 26, 2016 MEMBER ADVISEMENT: Our Profession MEMBER ADVISEMENT: Deputy Courtney Ward March 23, 2016 Deputy Courtney Ward is battling a rare form of cervical cancer and needs our help. She is currently in Maryland undergoing an immunotherapy trial in the hopes of fighting back her cancer which so far has been resistant to treatment. Fourteen months ago,… March 23, 2016 MEMBER ADVISEMENT: Deputy Courtney Ward MEMBER ADVISEMENT: JAIL ISSUE February 11, 2016 AOCDS has recently learned of issues inside the County Central Men's Jail ("CMJ") that have led us to determine the CMJ is an unsafe working environment for our members. The CMJ is also an unsafe housing location for the violent, hardened criminals AOCDS members… February 11, 2016 MEMBER ADVISEMENT: JAIL ISSUE Welcome Thank you for visiting our new website. We are extremely proud to represent more than 2,400 active and retired deputy sheriffs and district attorney investigators who are sworn to protect the residents of Orange County. We hope this website will provide our members with useful information about the services we provide as well as give the public insight into what we do as an organization.


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[PCX] Writing Competition
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October 6th, 2012 (6:14 PM). Edited October 6th, 2012 by Dragonfree.
Teh Spwriter. :3
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Okay, I've sent my judging to Astinus, so expect the results soon. Sorry my reviews are really hypercritical.
I understand how it works; like I said, I chose to review everything because I wanted to, not because I had the impression at any point that everyone was going to. I was just confused by Astinus's comment above which implied
the judges would only be posting reviews for those who posted their entries, even though initially I'd been told I could write reviews to be posted with the scoring and I'd already indicated in a PM that I was reviewing everything.
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text:
trolling a snoring girl
as above
By: loganmex | Comments: 43 | Views: 3004 | Votes: 19 | Shared: 39
Leaked: Feb-9-2015 in WTF, Other Entertainment
Trolling people on chat roulette
As above.
By: imoman | Comments: 35 | Views: 6109 | Votes: 7 | Shared: 0
Leaked: Dec-15-2014 in WTF
Trolling the Israeli Bomb Squad
A bunch of kids decided to troll the police bomb squad, placing a bunch of spray paint in a bag and leaving it in a bus station, than calling in to the police to report a suspicious object. In the pa
By: MakeNotWarLove | Comments: 22 | Views: 870 | Votes: 2 | Shared: 0
Location: Israel | Leaked: Dec-6-2014 in WTF
Trolling the police, Israel style.
This is quite old but still worth a post. A yound weed smoker goes to a police station in Haifa (a city in Israel). In first frame you can see him holding a glass bowl above hes head, and in the b
By: MakeNotWarLove | Comments: 1 | Views: 1173 | Votes: 0 | Shared: 0
Location: Israel | Leaked: Dec-6-2014 in Other Middle East
Annoying Cop Trolling Everyone
By: fobfob77 | Comments: 77 | Views: 3675 | Votes: 3 | Shared: 0
Location: New York, New York, United States | Leaked: Nov-14-2014 in WTF, Vehicles
Farmer trolling the people
in the city with his harmonica
By: Kuzya | Comments: 37 | Views: 661 | Votes: 2 | Shared: 0
Location: Moscow, Moskovskaya oblast, Russia | Leaked: Oct-23-2014 in Other Entertainment
Trolling is now a crime in the UK
http://www.dailymail.co.uk/news/article-2798573/crackdown-cyber-mobs-poisoning-britain-sentence-web-trolls-quadrupled-two-years-shocking-high-profile-online-abuse-cases.html now i ain't no tree hug
By: Lee777 | Comments: 124 | Views: 1524 | Votes: 15 | Shared: 0
Leaked: Oct-20-2014 in Your Say
Police Officer trolls trolling kids...
...there is a youtubechannel of a group of young boys doing pranks in the public life and one of the pranks was to steal a policemens hat... Guy: Sorry, excuse me Policeman: Please... Guy: Do you k
By: Schnitzelfleischwurst | Comments: 2 | Views: 874 | Votes: 2 | Shared: 0
Location: Berlin, Berlin, Germany | Leaked: Oct-16-2014 in Other Entertainment
Gta V Online Mugger trolling
By: The Answer | Comments: 52 | Views: 1699 | Votes: 3 | Shared: 0
Leaked: Sep-28-2014 in Other Entertainment
Trolling 'Hayden' on the bus.
fearless leaders. I text my brother that "Hayden from L.L. is driving the bus!!!!" Pictures or it didn't happen. So, yeah the bet on. I got a shot of his ID, he me if i was "Alright there are ya?"
By: ralph666 | Comments: 56 | Views: 969 | Votes: 24 | Shared: 0
Location: Christchurch, Canterbury, New Zealand | Leaked: Sep-9-2014 in Other Items from Liveleakers
Trolling his grandma
mehh. Is it just me, or more of you think it's setup?
By: laokram | Comments: 11 | Views: 481 | Votes: 3 | Shared: 0
Leaked: Aug-8-2014 in Other
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The Port of Houston authority announced its new policy on container weights, as well as container throughput for the the first quarter and developments with ongoing infrastructure improvement projects.
Overall revenues for NYK, MOL and "K" Line fell 5.4 percent, 6 percent and 8.1 percent, respectively, for the last fiscal year ended March 31, 2016.
The Atlanta, Ga.-based parcel giant posted a net income of $1.1 billion for the first quarter of 2016 on revenues of $14.4 billion, year-over-year increases of 10.2 percent and 3.2 percent, respectively.
Registration takes less than 1 minute.
Many voters in this year's presidential campaign see trade as the enemy preventing prosperity, while many United States businesses see trade as creating new opportunities, according to recent exit polls and a CEO survey conducted by Business Roundtable.
The 3rd Circuit U.S. Court of Appeals decision, which relies on a 1866 Supreme Court opinion, is being heralded as a victory for ocean carriers.
The 2M Alliance, comprised of ocean carriers Maersk Line and MSC, will also add a call in New York to another one of its loops between Asia and the U.S. East Coast.


text:
- Neelys Landing man shot, killed by highway patrol trooper after traffic stop (05/01/16)43
- Cape student sues, accuses school officials of slamming her to ground multiple times (04/28/16)49
- Missouri House votes to allow concealed weapons without permits (04/28/16)8
- River Ridge Winery changes hands (05/02/16)
- Police report filed, but no charges in incident at Cape Central (04/29/16)40
- 2016 All-Missourian Boys Basketball (04/29/16)
- Statement: Man says cops� good work drove him to grow his own marijuana (05/01/16)1
- Bob Evans restaurant in Cape Girardeau among chain's 21 closings (04/26/16)9
- Senator introduces bill for I-57 that would connect Sikeston with Little Rock (04/28/16)4
- Hopper Road to close for months during construction of Veterans Drive (04/27/16)9
Club news 6/9/04
Alpha Mu Master
Alpha Mu Master Chapter of Beta Sigma Phi met at the Royal N'Orleans restaurant for its final meeting of the chapter year. The new year begins in September. New president Linda Metheny conducted the meeting.
A thank-you note was received from Safe House for Women for a recent contribution.
Judie Herbst presented Marsha Parrish, past president, with a gift certificate and the president's gavel for her pin.
Chapter assignments and hostess dates were reviewed for next year and summer event dates and places were discussed. Summer events are: Lunch out at O'Charley's on Tuesday; couch potato party at the home of Bernie Gardner on July 11; lunch out at Great Wall Chinese Buffet on Aug. 10; and barn party at "Charlie's Barn" on Aug. 22.
Program of the year awards were presented to Joyce Hays and Marilyn Schwab. Perfect-attendance awards were presented to Mary Schwab, Vicki McKinney, Schwab, Herbst, Gardner, Metheny and Parrish.
It was announced that Beginning Day will be held Aug. 30 at Francine's Gardens.
Secret pals were revealed, and new secret pal names were drawn for the coming year.
The next regular meeting will be on Sept. 20 at the home of Gwen Nussbaum.
Young Americans 4-H
The Young Americans 4-H Club met May 20 at Grace United Methodist Church. Tori Schweer, vice president, called the meeting to order. There were 19 members, 12 leaders and two guests present.
Scott Givens, from Southeast Missouri Hospital, presented a program on health and fitness. After the program, Gary Schweer and Truman Kinsey led the group in the pledges and Kinsey led the group in a song. Those with May birthdays were recognized.
The minutes were read by Julia Weber and the treasurer's report was given by Michael Weber. In response to participation in "Mail for the military," Clint Heuer and B.J. Heuer received a letter from a soldier stationed in Hawaii.
Reports on crafts and rabbit project meetings were given. Greg Illers gave handouts to members outlining their assignments and responsibilities for the upcoming "Dortha's Day Camp for Clover Kids," which was held Sunday at Cape County Park.
Gary Schweer gave a demonstration on rabbit nutrition, and Joseph Yuede demonstrated how to make a perfect glass of tea. A game was led by Gary Schweer, and the Kinsey family served refreshments.
Hobbs Chapel UMW
The Hobbs Chapel United Methodist Women met Wednesday. June Warder presented an inspiring program and served refreshments.
Rosemary Whittard has been placed in charge of the heifer program. A pipe has been placed in the foyer of the church to receive donations.
The UMW kicked off the program by donating $250 to purchase a water buffalo. Pastor Janet and Chris Simmons will present that donation at the annual conference in Columbia, Mo.
Hobbs Chapel UMW will host the citywide UMW meeting on Oct. 5. This date represents the 135th anniversary of the United Methodist Church in missions.
Lamplighters FCE
The Lamplighters FCE Club met in the home of Roberta Seabaugh on May 20 with 10 members present. The hostess gave a devotional "Shut the Door" based on 2 Kings 4:1-7.
Beverly Meyer made yellow ribbons for members to attach to their mailboxes to honor her son, Russ, who is currently serving in the Marines in Iraq.
Verla Mangels and Linda Sebaugh reported on the FCE District Meeting in Doniphan. The club will furnish three dozen homemade cookies for the FCE-sponsored Red Cross Blood Drive on July 1.
It was decided to furnish a family pass to the Jackson swimming pool and a gift certificate to Dairy Queen to our adopted family. A donation will be made to the Cape Girardeau Baptist Association for the disaster relief program to thank Ron Hahs for work he has done for the club.
Karen McLane gave a program, "Women and clinical depression," and Dorothy Hahs gave a program, "Managing insurance costs."
Sebaugh received honorable mention for the report she did for Missouri FCE Association.
The next meeting will be in the Jackson city park on June 17.
High-Noon Toastmasters
The High-Noon Toastmasters Club met June 1 and elected officers for the coming year. They are Bill Meyer, president; Joan Masters, vice president; Gene Loftis, vice president of public relations and membership; and Russ Kullberg, secretary and treasurer.
The speakers for the day were Kullberg, who spoke on the subject, "To the Moon and Back." The second speaker was Joyanne Bates who gave her first speech, which is called her icebreaker.
Toastmasters meet at 12:10 p.m. every Tuesday at the Church of Christ annex, 328 West End Blvd. in Cape Girardeau. For more information about the club, call 334-3130.
Cape Girardeau County FCE
The Cape Girardeau County FCE Council met in the University Extension Center for its Thursday meeting. Nelda Crader presided with Mary Gosche, human development specialist, in attendance.
Shirley Cracraft reported 40 people attended the Leaders Training held earlier in the year. Members attending the spring district meeting in Doniphan reported an enjoyable and educational event where Betty Shalk, state president, and Lynn Maples, state treasurer, were on the program.
Mary Klaproth spoke briefly on tours that the FCE clubs of the county have sponsored and the tours forthcoming: Muny Opera, July 27; Ozark Folk Center in Mountain View, Ark., Oct. 15 to 17; Branson, Nov. 12 to 14; Lady of the Snows, Dec. 11.
Four clubs from the county will participate in educational booths for the SEMO District Fair.
Crader and vice president Barbara Schaffner will represent Cape County Council at the state conference in Columbia Aug. 25 to 27.
Representatives from the county clubs will also be in attendance.
New business included announcement of county member Shirley Heise (Town and Country Club) having won a scholarship for registration fees with Martha Slaten (Kage Club) alternate to the state conference meeting.
Final preparations were made for the Red Cross Blood Drive on July 1 from 2 to 7 p.m. at the Red Cross Facility at 20 S. Mount Auburn Road in Cape Girardeau.
A discussion was held on the Military Mail project of the various clubs. Goshe brought news of the need for assisting families left at home who are in need of our support.
Gosche also is soliciting clubs for pictures that will identify successful projects each club has experienced during the last year.
These pictures will be used to prepare a trifold to be displayed at the state conference in August.
The fall district meeting was announced to be held in Wayne County.
On Aug. 16, the Perry County Extension Office will be the site of a program planning meeting for all club vice presidents.
Gerald Jones, presiding commissioner of Cape Girardeau County, signed a proclamation for the Town and Country Club declaring May 15 as National Day of the Family for Cape Girardeau County. The Kage Club had their proclamation signed by the mayor of Cape Girardeau, Jay Knudtson. Both clubs provided Golden Books for newborns at St. Francis Medical Center and Southeast Missouri Hospital on the appointed dates.
-- From staff reports


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ASI institutes 'off-season MAP' program
PHILADELPHIA, PA (BRAIN) — For a second consecutive year, Advanced Sports International is offering its dealers a tiered-down "off-season MAP" program on most current-model-year bikes in its Fuji and Kestrel lines, as well as select Breezer models. The first price reduction went into effect Monday, July ...
Posted July 17, 2013 in North America
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and Lazer. VCU joins Fuji University Bike program PHILADELPHIA, PA (BRAIN) Monday April 9 2012 3:57 PM MT— Virginia Commonwealth University is the newest member of Fuji University, a program ...
Posted April 9, 2012 in North America
Suppliers pay scant attention to tourism, event rides, industry executive says
company for Fuji, Breezer, Kestrel, SE and Oval components. Cunnane attended last year's event in Iowa ...
Posted November 7, 2014 in Industry News
Endurance House opens fifth store in Georgia
walking and swimming, including bikes from Fuji, Kestrel, Orbea and others. Endurance House Alpharetta ...
Posted May 15, 2014 in Retail News
BRAIN Dealer Tour plies Austin's prime paths
the Tatas" socks, courtesy of SockGuy. The Fuji bikes also were outfitted with pink ribbon. ...
Posted October 21, 2014 in Retail News
Industry veteran Ellen Johnson joins ASI
lifestyle bikes within our SE, Fuji and Breezer lines, and we look forward to working with Ellen to help us ...
Posted November 5, 2013 in North America
Eastern Panhandle opens flagship store
and adventure sports equipment. EP/BC brands include Specialized, Cannondale, Surly, Fuji and GT. The new ...
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Courting China
in China in 2011. The goal: 30 to 50 percent growth this year. Fuji 2012: 10 Fuji-owned concept ...
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Sport Chalet to be acquired by the owner of EMS and Bob's Stores
Electra, Diamondback, KHS, Pure Fix and Advance Sports International's Fuji and SE Bikes. The stores ...
Posted July 2, 2014 in Retail News
Catalyst Communication to expand BikeLife Cities
BikeLife Cities also received support from the industry, including PeopleForBikes, SRAM, Giant, Fuji, Polar ...
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Beating Stress at China's Anger Bar
Louisa Lim, NPR
Overworked and stressed out? Female bar patrons in one Chinese city can find some relief by beating up the staff... Patrons of the Anger Bar in Nanjing, China, are encouraged to vent their anger by attacking young male employees who wear protective gear and are trained in self-defense.
However, only women customers are permitted to throw punches. Louisa Lim takes us there on a typical Friday night.
Related NPR Stories
Portraits of a Changing China Aug. 6, 2002
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Firefighters put out 2-alarm structure fire in Makaha
Firefighters put out a 2-alarm structure fire in Makaha. The incident was reported just after 5 a.m. Tuesday on Lahaina Street. Officials sa…
Firefighters put out a 2-alarm structure fire in Makaha. The incident was reported just after 5 a.m. Tuesday on Lahaina Street. Officials sa…
At his agency's board meeting, another shoe fell: he can't make hires for those jobs without oversight from the board. It's a first during h…
The Saint Louis junior quarterback announced his college commitment to the University of Alabama, exclusively on KHON2.
Court documents reveal what allegedly happened when Michael Colby was beaten to death.
Police arrested an 18-year-old man who lives across the street for cruelty to animals, then released him pending further investigation.
Realtors say potential buyers are competing with each other, paying tens of thousands of dollars just for one residential parking spot.
It doesn't have a name yet, but we do know it's an action-comedy film and it needs extras.
Honolulu's first rail train was unveiled publicly Monday, a little more than a month after arriving in the islands.
With his supporters fearing Cruz could lose a seventh consecutive state Tuesday, the candidate's formulation hinted at a time when he may gi…
It basically crashes the website, and that's exactly what happened to the Better Business Bureau, which came under attack a few weeks ago.
Located in Volcano, it has one of the largest orchid collections in Hawaii on display.
So far this year, there have been five imported cases of the virus to the islands, in addition to four cases last year.
Enforcement will begin at 6 a.m. Thursday, May 5, in order to give residents time to remove their vehicles.
The tree appears to have split vertically down the middle and then fell, pinning the hiker.
Aukanaii Kalalau, 26, fled from the hospital's adult Behavioral Health unit at around 9:15 a.m.
Hawaiʻi Island police need your help in identifying a suspect in a shoplifting case last month. Officials say just after midnight on April 2…
The first location is expected to open early next year.
Crews put out a structure fire at the Pearl Kai Shopping Center. The incident was reported just after 5 a.m. Monday from workers at Sugarl…
He was last seen within the Wailuku Industrial area riding his beige colored cruiser-type bicycle.
The canoe left Honolua Bay, Maui, on May 1, 1976, to Tahiti.
According to lawmakers, abandoned pets roaming the state number in the thousands.
Lawyer volunteers will be answering your legal questions free of charge.
The free event at also featured food vendors, lei-making and a display of this year's lei contest entries.
The No. 5 University of Hawai'i Rainbow Wahine (16-8) will head to Gulf Shores, Ala. following their at-large selection among the field of t…
Sports Authority will liquidate all stores and close down operations in the months ahead.


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|Showing 1-20
Dhaka Premier League 2016
Muktar, Rubel, Al-Amin clinch three last-over thrillers
Apr 26, 2016: A round-up of all the DPL matches played on April 26, 2016
Bangladesh news
Rubel misses out on BCB contract
Feb 22, 2016: Rubel Hossain, who was a key member of Bangadesh's pace attack during the 2015 World Cup, has been left out of the BCB's list of contracted players for 2016
Dec 24, 2015: And a year of many firsts: a World Cup quarter-final appearance, series wins over Pakistan, India and South Africa, and the unearthing of a bowling star
Bangladesh v South Africa, 2nd ODI, Mirpur
Rubel's comeback promises more
Jul 12, 2015: He took two wickets, he didn't go for too many runs. It wasn't the most eye-catching performance. But Rubel Hossain has shown the capacity to develop as an all-round bowling option
Bangladesh cricket
Rubel slipping in Tests despite best help
Jun 11, 2015: The support of a settled bowling line-up has allowed Rubel Hossain to become a key bowler for Bangladesh in ODIs. His Test career, however, continues to face hurdles
India in Bangladesh 2015
Unlikely to play three seamers - Streak
Jun 7, 2015: Bangladesh bowling coach Heath Streak said it was unlikely that his team would opt for three seamers for the first Test against India
India in Bangladesh 2015
Rubel Hossain returns for India Test
Jun 3, 2015: Fast bowler Rubel Hossain has replaced Shahadat Hossain in Bangladesh's squad for the only Test against India, beginning on June 10
Bangladesh news
Rubel Hossain acquitted by Dhaka court
May 20, 2015: A Dhaka court on Wednesday acquitted Rubel Hossain from a sexual abuse case filed in December last year by Bangladeshi actress Naznin Akhtar
Pakistan in Bangladesh 2015
Rubel out of second Test with side strain
May 4, 2015: Rubel Hossain, the Bangladesh fast bowler, will not be playing in the second Test against Pakistan due to a side strain. Abul Hasan will be his like-for-like replacement
Bangladesh Cricket League One-Day
Mashrafe blitz wins it for South Zone
Apr 6, 2015: Mashrafe Mortaza blasted a 33-ball 50 to help Prime Bank South Zone to a two-wicket win over Walton Central Zone in Fatullah
Bangladesh news
Apr 6, 2015: Police told a Dhaka court on Monday that they had found no proof of the charges brought by an actress against Rubel Hossain. In the final report, it also sought the Bangladesh fast bowler's acquittal
World Cup performers missing at the IPL
Apr 3, 2015:
The lingering image of Rubel Hossain
Mar 24, 2015: Short, slight, fast, skiddy, moves it sideways, in-drifts it, and gets good bounce. And the last Australia probably saw of him was two one-over spells
World Cup 2015: Bangladesh
Rubel accuser 'drops' charges, law may differ
Mar 11, 2015: Rubel Hossain's match-winning performance against England may fetch him an unexpected pay-off - a Bangladeshi actress says she will drop the charges against him
World Cup 2015: Bangladesh
Pace bowlers' success Mashrafe's reward
Mar 10, 2015: Bangladesh's pace bowlers have had their moments even in the recent past, but very few times in this team's history have they been as effective as a collective as they were against England
Bangladesh v SL, Group A, Melbourne
Mashrafe backs quicks to continue good showing
Feb 25, 2015: Bangladesh captain Mashrafe Mortaza believes his team has quality fast bowlers, and that the bouncy wickets in Australia necessitated playing an extra paceman
World Cup 2015
A test of Bangladesh's cricketing systems
Feb 17, 2015: The young Bangladesh side, in many ways, represents the transition and growth of cricket and its infrastructure in the country. The World Cup is a chance to test these systems
Bangladesh news
Cricket takes centerstage for Rubel
Jan 21, 2015: Speaking for the first time since his release from jail, Rubel Hossain has said it was a "mentally" worrying period, but now his sole focus is on the upcoming World Cup
World Cup 2015
Demand rises for Bangladesh pace
Jan 17, 2015: Fast bowling, Bangladesh's most vulnerable and underutilized stock, is going to be in high demand at the World Cup. Taskin Ahmed wants to be among the top wicket-takers at the event while Al-Amin Hossain wants to take "12 to 15" wickets in the first round
Bangladesh news
Court clears Rubel for overseas travel
Jan 14, 2015: A Dhaka court on Wednesday cleared Bangladesh cricketer Rubel Hossain for traveling abroad, three days after he was granted bail in a case filed under the Women and Children Repression Prevention Act
|Showing 1-20
'To enjoy cricket, you must enjoy your downtime'
James Faulkner talks about the IPL, his slower balls, bouncing back from a drunk-driving episode, and bad haircuts
In a little over 12 months, he has firmly established himself as a top-notch bowler, and the captain's go-to man in the toughest situations
The Happy Families Test, and most IPL runs without a ton
Also: the highest successful first-class fourth-innings chases, and the double of 1000 runs and 100 wickets in women's ODIs
'For fast bowling you need an environment that helps you go wild'
Former Pakistan international Aaqib Javed talks about his growth as a fast bowler, the influence of Imran, and coaching UAE
Continuity sets Knight Riders apart
The franchise's success over the last five seasons has been built around consistency of selection and a familial atmosphere within the squad
In a little over 12 months, he has firmly established himself as a top-notch bowler, and the captain's go-to man in the toughest situations
'The worst England tour ever' (14)
Thirty years ago England were battered, bruised, broken and blackwashed in the Caribbean
A look at what lies behind the rise of the West Indian allrounder who just might be the world's hottest T20 property at the moment
Give first-class cricket its due (12)
For struggling Test teams to get better, they need to strengthen their domestic cricket and ensure their best players aren't lost to T20
'For fast bowling you need an environment that helps you go wild' (12)
Former Pakistan international Aaqib Javed talks about his growth as a fast bowler, the influence of Imran, and coaching UAE


text:
Articles tagged with: President Obama
Benghazi, U.S. News »
As Shapiro's remarks specify, the MANPADs Task Force, led by Clinton's State Department, was an "interagency effort." Those agencies included the Defense Chief Leon Panetta's Department of Defense and Department of Homeland Security Secretary Janet Napolitano's DHS. Central Intelligence Agency Director David Petreaus' CIA was also in Libya "collecting intelligence."
U.S. News »
While President Barack Obama gave get-out-of-jail-free-cards to five top Taliban commanders from Guantanamo Bay, Cuba in exchange for POW Bowe Bergahl, U.S. Army Sergeant Derrick Miller remains in Leavenworth prison, in Kansas, sentenced to life with no hope of a sentence reduction, let alone clemency.
Benghazi, World »
"Yes, 'Threat Letters' have been confirmed to exist for a while now. The [United Nations] local staff, for example, were issued with such letters and instructed even to stop collaborating with any U.S. affiliated ventures or programs. These staff stopped working now till the situation is fully assessed. I also understand that the Basra Palace is being shelled almost daily now. Beyond this, it is confirmed that some families wake up in the morning and find threat letters by their door steps and they comply by selling off their property and leaving their places instantly."
Benghazi, U.S. News »
Meanwhile, back in Obama's America, don't call Libya's weapon recovery program "buyback" that then Secretary of State Hillary Clinton funded using $40 million of your tax dollars after the Obama–Clinton regime toppled Col. Muammar Gaddafi because if you do, the State Department will deny it exists. You can however refer to it as the MANPAD program—Man-Portable-Air-Defense Systems or shoulder-fired-anti-aircraft missiles that the U.S. is "helping" Libya to recover and secure among its weapon stockpiles.
U.S. News »
Where have you been all these years? Did you not think it wouldn't happen to you or anyone else? This is what happens when corrupt politicians are not held accountable. They are emboldened. Their abuse of power grows like cancer and more innocent people are caught in their crosshairs. Newsflash: the Obama administration has taken a page out of the Clinton playbook.
Benghazi, World »
According to a well-placed source that was working with the staff at the Libyan Transitional National Council (TNC) which was established after Col. Muammar Gaddafi was killed, at that time, the talk there was very surprising. Apparently the Libyans thought America had only a handful of people in Eastern Libya and Benghazi. They were surprised to learn the real number.
Benghazi, World »
Yes, the talking points were altered to mislead America and protect Hillary but Benghazi is bigger than Hillary. The talking points were also edited to protect the administration's policy and that is what needs to be exposed. They like to arm "rebels"—just don't call them Islamic extremists as we witnessed in Egypt and Libya.
Benghazi, World »
Media & Book News, U.S. News »
On page 606 of the Gang of Eight's 844-page legislation called, "Border Security, Economic Opportunity, and Immigration Modernization Act," under "Subtitle G—Interior Enforcement, Sec. 3701: Criminal street gangs," we learn that gang members (with no prior convictions) can apply for a waiver by simply "renouncing" their associations with street gangs.
U.S. News »
Sen. Rubio, taking a page from Sen. John McCain (R-Ariz.), also claims currently there is a defacto-amnesty which is why America needs a pathway to citizenship. The truth is there is a defacto-amnesty—thanks to President Obama's policies which is why Immigration and Custom Enforcement (ICE) agents have filed a lawsuit against Department of Homeland Security chief Janet Napolitano and ICE Director John Morton, who are preventing them from upholding the law and doing their jobs—because of President Obama's defacto-amnesty policies. Why isn't Sen. Rubio helping the good ICE agents instead of making their lives worse?


text:
The Missouri Valley College baseball team closed out its truncated home schedule Tuesday by losing a pair of non-conference games to Hannibal-LaGrange, 9-8 and 11-3.
The Vikings came back from a 4-0 deficit in the opener with a seven-run fourth inning. Sophomore Troy Langan singled in two runs and scored the go-ahead run on junior Zach Walden's single, following an RBI bunt single by sophomore Cody Moore. A fielder's choice and Moore's steal of home closed the rally.
Valley couldn't hold on, though. Senior Josey Garnett doubled in a run and came in on a grounder in the fifth and senior Marc Luttrell's solo homer tied the game in the sixth.
The Trojans pulled ahead with two runs in the seventh, the first coming in on a double by sophomore Clint Hamilton -- who completed the circuit on a dropped fly ball.
Junior Ruben Salazar smashed a solo shot in the bottom of the seventh, but otherwise Hannibal-LaGrange junior R.J. Bachtold struck out the side.
The finale wasn't close, the Trojans putting up crooked numbers in the third and fourth stanzas for a 9-0 lead. Senior Gabe Marshall's two-run homer opened the scoring, with two passed balls and a grounder adding three more runs.
Garnett plated a pair of runs with a single in the four-run fourth.
The Vikings got all of their runs in the bottom of the fourth, a dropped third strike on what would have been the third out giving them new life. Four hits followed, including freshman Josh Hartin's two-run single.
Senior Roy Whitehead relieved for Hannibal-LaGrange (23-24) and snuffed the rally, then tossed two hitless frames for his third win of the season.
Valley (8-33) will head to Omaha this weekend to play in the Bellevue Tournament.


text:
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Articles - Recent Comments
Page 9 of 635 pages ‹ First < 7 8 9 10 11 > Last ›
What's New in iTunes 12
Getting album art is much less convenient in 12. Can't seem to copy and paste from the web directly into info anymore. Have to download the image then add it from your computer.
Also wish the pop-out player would allow for much larger sizing, if not whole screen. Why not ?
Posted by Anon on October 21, 2014 at 4:30 PM (CDT)
What's New in iTunes 12
Worst. App. Update. Ever.
Having to click on the movies button (or music etc.) THEN click on the store button to get that file type to show up in the store is completely worthless.
But the worst part of this app: taking away the side bar so you can't see all your file types at once! I think the Apple designers did this just to make themselves feel busy. Seriously, worst app update in the history of Apple. Shame on you all for this monstrosity being released on the world.
Posted by cj on October 21, 2014 at 1:05 PM (CDT)
What's New in iTunes 12
I hate the way it looks when i click to album; it's too ugly in comparison to the last versions. I wish I hadn't updated!
Posted by Celia on October 21, 2014 at 9:50 AM (CDT)
An Easy Guide To Setting Up + Using Apple Pay In iOS 8.1
can apple pay and passbook can be used if my iphone is set on a different country?
Posted by danny on October 21, 2014 at 2:21 AM (CDT)
An Easy Guide To Setting Up + Using Apple Pay In iOS 8.1
It isn't Apple Pay that brick and mortar stores don't yet support, it's NFC payments themselves. Apple Pay in a retail store setting is a regular NFC payment. Any store with payment terminals displaying the NFC payment logo will work with an Apple Pay enabled device…
Posted by Ben on October 20, 2014 at 4:49 PM (CDT)
What's New in iTunes 12
I've been using iTunes since it was introduced and I've never had much difficulty adjusting to the new versions. I have to say that this version is the best yet; I just can't stop playing with it.
I love the new 'Recently Added' field in the Album and Artist windows. I often had trouble remembering the latest CDs I had downloaded, so, despite wanting to find an album, I often used the songs window just so that I could use the 'Date Added' column.
Maybe this was a feature that needed to be selected which I overlooked in previous versions, as I'm surprised it wasn't mentioned in the article.
A couple of niggles I still have: When I search for an artist in Album view I'd like to be able to filter the result to just see albums by that artist, excluding other people's albums and compilations they may be on, and albums by artists who have covered their songs, just like you can in Artist view.
And it still annoys me that the Search field doesn't retain my search when I move between My Music and the Store.
But these are minor issues I can live with; overall IMO iTunes 12 is a job well done.
Posted by Stephen on October 20, 2014 at 5:14 AM (CDT)
What's New in iTunes 12
Can anyone please tell me how to get back the fields of Grouping and Episode ID in iTunes??? I can't get to these metadata fields anymore and I just added new TV series content to my media library. Its annoying because my smart playlist goes by grouping and sort by Episode ID.
Posted by Kyle Wong on October 19, 2014 at 10:40 PM (CDT)
What's New in iTunes 12
@ #4 - There's an app called MetaX that, while not necessarily the best or prettiest thing out there, can edit every field iTunes can/will display (even theatrical ratings) and will also embed poster art into the video file's metadata. It's free.
#5 - While I agree that having a separate app for iTMS/App Store (with integration for Mac App Store) would be great, I like the fact that iTunes does it all. It's a media server for the Apple TVs that I own, it's how I play back movies, TV, music, podcasts, and everything else on my Mac both locally and in the cloud, and it helps me manage my massive collection of music and movies (at least 400GiB of music, and 3x that in movies).
@ Nick Guy - the sidebar is still there, kinda; it's buried in the "Playlists" option. However, iDevices don't show up over there anymore. Being that I'm a long-time iTunes user (version 2 on a PowerMac 8500), I actually like the changes made. I'll be giving it a shot on my Windows 7 box soon, hoping Apple cleaned up the code base.
Posted by Bill on October 19, 2014 at 5:04 AM (CDT)
What's New in iTunes 12
wow best
Posted by getahun on October 18, 2014 at 4:46 AM (CDT)
What's New in iTunes 12
I like the way it looks.
One minor nit - the Account Name in the control bar displays my legal name instead of my nickname - it shows William instead of Will.
I really appreciate that the album covers now no longer have fuzzy /cloudy edges. That was an insult to the cover art designers.
TV Shows should still be changed in name to Series, since many series, such as web series, are not television shows except in an abstract sense.
Posted by Will on October 17, 2014 at 9:34 AM (CDT)
Ten Things You Didn't Know About iPad Air 2 + iPad mini 3
Apple has always been known for introducing products with out-of-the-ordinary designs and innovative features that have never failed to take the consumer market by storm and one bets example is the iPad Air.
Posted by underseaglider on October 16, 2014 at 8:01 PM (CDT)
Ten Things You Didn't Know About iPad Air 2 + iPad mini 3
Funny list of descriptive words, JB
Nice found poem!
Posted by choicweb on October 16, 2014 at 3:47 PM (CDT)
Ten Things You Didn't Know About iPad Air 2 + iPad mini 3
Here's a transcript that I captured while listening to the iPad Air 2 intro:
jam packed
jam packed
so many
great experience
huge advantage
Number 1
Number 1
Number 1
Number 1
so thin
unbelievably gorgeous
so incredible
so thin
so much
more beautiful
so much more
out of this world
huge jump forward
blown away
pretty cool
all new
all new
great new
great new
Posted by JB on October 16, 2014 at 3:45 PM (CDT)
Mind The Gap: What's iPad's Role In An iPhone 6 (Plus) World?
YES! iPhone 6 Plus UI is a mess! Case in point: all of Apple's app. Rotate your iPhone 6 Plus so that the home button is at the top. Now run any of Apple's app like iMessage, Calendar, Photos, etc. When you open them the screen is upside down.
Posted by Benjamin on October 14, 2014 at 4:42 PM (CDT)
The Early Guide To Apple Watch Apps
I am pretty excited about the watch and I think Apple was right in creating a good diversity initially.
This is a nice summation of what is currently known and I think it will be expanded as more details are revealed.
A small correction though, you refer to 'Estimated ETA', when ETA, by its very definition, is Estimated Time of Arrival.
Posted by Sreedhar on October 6, 2014 at 12:56 AM (CDT)
What's New In Apple TV 7.0
APPLE TV software 7.0 change icon program coming this fall
Posted by VIKRAM on August 7, 2014 at 8:14 PM (CDT)
What's New In Apple TV 7.0
Is that it? A few cheesy and unnecessary UI changes?
What about functionality changes? What about adding universal search? What about adding a universal provider so I don't have to add my DirecTV account info and activate on every channel?
What about adding to App Store?
What about adding apps like Safari, Find My iPhone, Find Friends, Mail or Messaging? There are a lot of things that can be improved more than just making the UI flat.
Posted by Eric on August 7, 2014 at 2:24 PM (CDT)
What's New In Apple TV 7.0
How do I update to 7.0?? It says my Apple TV is up to date
Posted by Gdjsjznswja on August 6, 2014 at 3:55 PM (CDT)
The Complete Guide to Apple TV Channels
Posted by conpinteyrobqw on August 6, 2014 at 12:50 AM (CDT)
What's New in iTunes 12
I don't bother upgrading to new versions of iTunes any more because I'm tired of doing it, I DON'T WANT MAJOR CHANGES.
Thank you.
Posted by Steve on August 4, 2014 at 6:58 AM (CDT)
What's New in iTunes 12
Why can't there be just an iTunes Store. There you find what you want to download, podcasts, albums, movies, etc. Then, once the download completes a smart sort of invisible app picks up the new arrival, files it to your own folders, which have a smashing media list view. Once launched another smart app handles each MP3, MP4, podcast download with a simple minimalist interface to play.
iTunes now is a gargantuan and it makes no sense as it ttys to be all things to all users. That's not necessary, nor is it simple, nor efficient, nor FUN!
Posted by Tom G on July 31, 2014 at 8:28 PM (CDT)
What's New in iTunes 12
Can't add a year to a file that wasn't added from the iTunes Store, it seems. I have a video file (.mp4) that I copied into iTunes. Accessing the new Get Info screen, I can edit the title, sorting, etc., but there is no way to add the movie's release date. Haven't checked for audio files yet.
They just made organizing your media with iTunes a bit more difficult than it already was. Seems another reason to find another option.
Posted by MJ on July 27, 2014 at 4:34 PM (CDT)
What's New in iTunes 12
Can one still burn to CD and or DVD?
And where is the "Add File/Folder to Library Option," as well as the Import Compression options?
Posted by Ron C. on July 27, 2014 at 3:14 PM (CDT)
What's New in iTunes 12
1. "Album is a compilation of songs by various artists". Now perhaps people will use that properly!
2. The "Add Field" button is interesting.
Posted by Galley in Greenville, SC on July 26, 2014 at 5:58 PM (CDT)
What's New in iTunes 12
iTunes 11 was released Nov 2012, not 2013 as stated in the article.
Posted by Andrew Barry on July 24, 2014 at 10:05 AM (CDT)
Recent News
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- Alleged schematics for iPhone 7 'Pro' show up in Japanese magazine
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All-Star Football Player Bendables. Score a touchdown with these fun toys! All-Star Football Player Benables are a fun gift for your future football fans. Add them to birthday goodie bags at football themed parties. Pose them however you like and have them hanging around your room, locker or workspace. Vinyl. (2 dozen per unit) 4" © OTC
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Khusrau Sees Shirin Bathing in a Stream, from the Khamsa of Nizami, 1539-43
Giclee Print
Item #: 14285684A
Size and print type
15.5" x 22" without border
Ships in 1-2 days
Or 2265 Khusrau sees Shirin bathing in a stream, from the Khamsa of Nizami, 1539-43 (vellum), Persian School, (16th century) / British Library, London, UK / The Bridgeman Art Library
This giclée print offers beautiful color accuracy on a high-quality paper (235 gsm) that is a great option for framing with its smooth, acid free surface. Giclée (French for "to spray") is a printing process where millions of ink droplets are sprayed onto the paper's surface creating natural color transitions.
Other ways to order:
Call Us: 1-800-952-5592 |
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If for any reason you are not completely
satisfied with your purchase, you can
receive a replacement or refund within
30 days Learn More
Ship time indicates the typical time it takes for your item(s) to leave our facilities. This includes any framing or customizing services ordered as well as careful packaging to prevent damage in transit.
Items that ship same day normally leave our facilities on the same business day if your order is placed before 5:00pm EST.
Orders that contain multiple items with different ship times will be shipped out based on the item with the longest ship time.
Shipping FAQ
Shipping Rates
Customer Reviews
Reviewed by 1 customer
- Great Quality Paper
- Perfect Size
- Vibrant Colors
- Visually Appealing
- Vivid Detail
Purchase Reason
- Fill Wall Space
Breath taking!
- Age:
- 45 – 49
- Gender:
- Female
- Display Location:
- Bedroom
Photos To ART
Decorate with photos you love. With Photos to Art, you can transform your favorite snapshots into one-of-a-kind works of art that you'll be proud to hang on your wall. Choose from artistic canvas, custom framing, wood mounting and more to update your décor with art that is totally you.
Custom Framing
Each piece of custom framed art is handcrafted and hand-signed by a professional artisan. Our assortment of high quality frames includes classic styles and the latest design trends, allowing you to fully personalize your art. Choosing a frame is fun, easy and affordable, and your satisfaction is 100% guaranteed.
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