text:
19 Comments
Realtime comments disabled
LLTT22 2059 days ago
Cute!!! :)))
FreakFlagFlyer 2109 days ago
Lab mix? He looks like a great dog.
missg1ggles 2141 days ago
I think my dog was my moms husband in there last life he follows her everywhere and crys every time she leaves lol so I know what you mean lol
Berliner71 2189 days ago
Ok so I read my comment and I admit it doesn't sound right... I meant "I prefer to think of human future lives"..so as to right the wrongs..do this differently, etc
Berliner71 2189 days ago
I prefer to think of our future lives ;). Surrounded by dogs.
LouisahT 2190 days ago
Exploiting your doggie.. that's just terrible.. unforgivable behaviour. poor thing doesn't even realise he's now all over the internet... shame on you samtwitt!
Claudhop81 2191 days ago
HaHa My dog has this same dog bed and he loves it!! We got it from Costco lol
elizarosemurphy 2191 days ago
Aww. So cute :)
benjis_monikuss 2191 days ago
Dear Sam, I was talking to Blue the other day and she was telling me how awesome her bed is. Please buy me one for my birthday =D Love Mon Xx
FairyWings9105 2192 days ago
Precious sleeping baby... I ♥ it! :)
Ces34 2192 days ago
Oh, well some dogs do need some time off, don't you think so?
steff6363 2192 days ago
the dogs life is so hard!!!eat, sleep, play, be hug...
IrinaSR 2192 days ago
I'm a happy dog at the beach
If I had the power of speech
caspeta 2192 days ago
Marystat 2192 days ago
absolutely adorable!
KatMcKenzie29 2192 days ago
that is strange that we all put the same thing ?!
lilystw 2192 days ago
aaaw, that's so cute! :D
bparada_ 2192 days ago
Aaawn so cute!
KatMcKenzie29 2192 days ago
awww so cute :)


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Get a plagiarism check of an answer before you buy it. See more details here
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Woman, 23 years old from United States
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Not a bad way to spend a Tuesday night. Thank you @thebandghost for a blasphemous evening in Tucson #ghost
5 Comments > view all
Fuckin lucky
Fucking awesome
Yeah bud! Good seeing you pre show!
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It's done! 3-year project to widen 57 freeway ends
Nearly 100 transportation officials, lawmakers and others gathered Wednesday morning in Brea to celebrate the successful widening of northbound State Route 57 between Placentia and Brea.
The $104-million project added a new northbound lane to a 5-mile stretch of the SR-57 freeway between Orangethorpe Avenue in Placentia and Lambert Road in Brea. The three-year-long construction project also included work on 12 ramps, 13 bridges and three miles of new sound walls.
Malcolm Dougherty, Director of the California Department of Transportation, thanked local commuters for their patience while work was underway.
"It is always some inconvenience in doing the construction, but now we get to reap the benefits of that construction being complete and improved mobility and reduced congestion," Dougherty said.
Officials with the Orange County Transportation Authority also spoke at the event, as did local lawmakers including County Supervisor Shawn Nelson and the mayors of Brea, Fullerton and Placentia.
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text: Character Pokémon that have been traded Category page 12,920pages on this wiki Edit History Talk0 Sorting type: Most visited Most visited Alphabetical | Pokémon that have been traded between two trainers in the anime. Pages in category "Character Pokémon that have been traded" Jessie's Gourgeist Jessie's Wobbuffet Ash's Buizel O's Ambipom Benny's Lickitung Butterfree (anime) Victreebel (anime) Count Pumpka's Mawile Bianca's Escavalier Gentleman's Raticate Professor Juniper's Accelgor Gyara Magikarp Salesman's Victreebel Gwendela Jimmy's Charmeleon " Cyrus' Sunflora (nicknamed Dorabelle) is a Sunflora owned by Cyrus. None of Sunflora's moves are... Dorabelle Back 1 2 Next Retrieved from "http://pokemon.wikia.com/wiki/Category:Character_Pok%C3%A9mon_that_have_been_traded?oldid=461538"


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Brett's Reviews > The Smell of Sin: And the Fresh Air of Grace
The Smell of Sin: And the Fresh Air of Grace
by Don Everts (Goodreads Author)
by Don Everts (Goodreads Author)
Brett's review
bookshelves: bible-general, christian-living
Aug 29, 11
bookshelves: bible-general, christian-living
Read in August, 2011
Sin stinks. Really! But we often see sin more casually. Maybe we imagine it like a giant carnival. True, there are some weird carnies to avoid, but you can also have time of your life! Or maybe we imagine sin like breaking some dusty old rule in the classroom of life. Yeah, so, I'm passing notes and throwing paper airplanes, but what's the big deal? Well, despite our perceptions, Jesus uses some very powerful - even grotesque - images when talking about the seriousness of sin: a 2x4 splitting your face, sawing off body parts, plucking out your eye. Everts walks his readers through some of Jesus' descriptions of sin, reminding us of the thick stench that sin leaves behind. B
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Baan Havaree Resort, Krabi
- Free WiFi
Main amenities
- 7 smoke-free guestrooms
- Breakfast available
- Free area shuttle
- Airport shuttle
- Air conditioning
- Daily housekeeping
- ATM/banking services
- Laundry service
- Luggage storage
- Tour/ticket assistance
- Lobby TV
- Kayaking
What's around
- Nopparat Thara Beach (1.1 mi / 1.7 km)
- Ao Phra Nang Beach (1.7 mi / 2.8 km)
- Ao Nang Krabi Boxing Stadium (0.5 mi / 0.8 km)
- Ao Phai Plong (2.5 mi / 3.9 km)
- Spirit Mountain (2.7 mi / 4.3 km)
Baan Havaree Resort, Krabi
Hotel Info: 866-539-8117from $29
- Superior Room
- Deluxe Room
Also popular with travelers from the USA
At a glance
Key facts
Hotel size
- This hotel has 7 rooms
- This hotel is arranged over 3 floors
- Check-in time noon-6 PM
- Check-out time is noon
Required at check in
- Credit card or cash deposit required
- Government-issued photo ID required
Travelling with others
- No pets or service animals allowed
- Free WiFi in public areas
- Free WiFi in rooms
- Airport shuttle (available on request) *
- Free area shuttle
Other information
- Smoke-free property
Nearby Two Star Krabi hotels
In the hotel
- English breakfast daily (surcharge)
- Tours/ticket assistance
- Dry cleaning/laundry service
- Luggage storage
- Number of buildings/towers - 1
- ATM/banking
- Television in common areas
In the room
- Air conditioning
- Minibar
- Individually furnished
- Balcony
- Private bathroom
- Bathtub or shower
- Free toiletries
- Hair dryer (on request)
- Cable TV channels
- Desk
- Free WiFi
- Phone
- Refrigerator
- Free bottled water
- Daily housekeeping
- In-room safe
Top Krabi hotels
Recently reviewed hotels in Krabi
- RayavadeeFrom
"Rayavadee was absolutely amazing. The hotel itself was wonderful, our personal bungalow was beautifully designed and extremely comfortable. The two beaches available to guests was…"Apr 14, 2016
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"I checked in one night while waiting for friends to arrive, they have a person to pick you up at the pier and take you to the hotel (just keep looking for Phi Phi Beach Hotel HIP)…"Apr 10, 2016
Special features
On Site
- Fishing on site
- Kayaking on site
- Sailing on site
- Scuba diving on site
- Snorkeling on site
- Bicycle rentals nearby
- Mountain biking nearby
- Rafting nearby
Baan Havaree Resort, Krabi's small print
In accordance with national/local laws, air conditioning may be restricted to certain hours during certain times of the year.
Only registered guests are allowed in the guestrooms.
This property does not have elevators.
For transfers, guests must contact the property before arrival at the number on the booking confirmation.
The name on the credit card used at check-in to pay for incidentals must be the primary name on the guestroom reservation.
Optional extras
Rollaway beds are available for THB 500 per night
Airport shuttle service is offered for an extra charge
We have included all charges provided to us by this hotel. However, charges can vary, for example, based on length of stay or the room you book.
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Arizona Cardinals
Cards' draft looks even better after one season
It's always fun after any NFL Draft to peruse the
internet and read the endless grades experts
hand out to the teams in the league for the players they
But does anybody really know how these players will adjust
to the pro ranks and actually help their team? The answer
to that question is a resounding 'no'.
That's why it's refreshing when draft experts revisit what
happened on draft night, and assign new grades for teams
based on what actually happened on the football field.
ESPN's Mel Kiper Jr. did just that, and the Arizona
received a slightly higher grade for their draft night
activities after one season.
Kiper originally gave the Cards a B- for a draft that
included 5th overall pick Patrick Peterson out of LSU and
running back Ryan Williams from Virginia Tech.
After the season, Kiper gave the Cardinals a B. Why?
What isn't debatable, however, is that
Peterson is the real deal. I gave the Cards an A-minus for
value because Peterson was No. 1 on my Big Board going
into the season. He needed refinement at corner, but his
improvement was steady from Week 1 through Week 17, and
he's right there with Devin Hester already as one of the
most dangerous return men in the league.
Peterson is headed to the Pro Bowl as the NFC kick
returner after tying an NFL record with four punt returns
for touchdowns. He was also the only rookie on the AP All-Pro Team released earlier
this week.
Of course, Williams was unable to help the Cardinals'
revisited grade because he suffered a ruptured patellar
in his right knee in the
preseason and spent the year on injured reserve.
Kiper also lauds fourth round pick Sam Acho, who had
sacks and cracked the starting lineup at outside
linebacker midway through the season, and 6th round pick
David Carter (16 tackles, 1 sack) for adding depth.
Check out Kiper's entire regrading of the 2011 NFL
Draft here (must be an ESPN Insider).
Most Popular
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Marqui Christian, Cardinals' Safety/ 5th Round pick
Tuesday May 3
Marqui Christian discusses what it was like going from playing at a D2 school in Texas to being a me
5 Minute Break with Andy The G
Tuesday May 3
Andy covers the NFL Draft's QB's plus gives his favorite picks of the weekend
Mike Golic, ESPN NFL analyst + talk show host
Tuesday May 3
Golic discusses a crazy NFL Draft + how he's glad there was no social media in his day
Adrian Wilson, Cardinals scout + Ring of Honor member
Tuesday May 3
Wilson talks about the recently drafted Cardinals + his role in finding new talented
Cole Toner - Cardinals 5th Round Pick
Tuesday May 3
Cole and B-Train talk O-Line, where the new Cardinal will play and how he sees himself fitting in wi


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Who to Start Message Board
Keeper Question
It's a h2h 12 team points league and keeper value is based on previous season draft round. Heavy value placed on pitching.
I have Darvish and he would cost me 1st round pick to keep (the last pick in the 1st round). I have been offered three different deals for young pitching with good keeper value.
Darvish for Gerritt Cole (15th rounder to keep)
Darvish for Wacha (16th rounder to keep)
Darvish for Sonny Gray (16th rounder to keep)
Should I make any of these deals or just keep Darvish.?Sort: Newest | Oldest | Most Replied Expand all replies
Captain Awesome Captain Awesome Jan 31, 2014 12:59 PM Flag
Heavy calue placed on pitching...I would keep Darvish or roll the dice on Wacha. But Darvish even though i'm not a fan of getting P in the 1st round
How did Darvish finish in your points standings last year? Would probably swap Darvish for Wacha---16th round versus 1st round just too much difference especially since that frees up your 1st round pick now. Need to project who would be available in your 1st round(ie--how many keepers does everyone have).
none of them keep darvish
Project out who would be available to you with a 1st round pick - then swap Darvish for Wacha.
Ask for 2 pitchers one of those guys and a tier 2-3 guy. Darvish has a 2 year track record on a stud team. FYI I had all 3 of those rookies last year they performed nicelt but they are not guarantees.
Pascal the Gambler Pascal the Gambler Jan 14, 2014 1:21 PM Flag
I would take Cole or Wacha, both better than Gray. Personally, I like Wacha.
PhillyPhanatic85 PhillyPhanatic85 Jan 12, 2014 8:49 PM Flag
Based specifically on those offers, I wouldn't do any of the trades. I would look elsewhere or keep negotiating.
That being said, it also depends somewhat on who your other keepers are. For example, if you're already keeping 3 other pitchers and you only have 1 hitter to keep, it may be better for you to trade Darvish and get an elite bat in the first round.
I would try for a slightly better deal, but if none were available I would take Cole. What tier of players are likely to be available at the end of the first round?
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EPHRAIM HARDCASTLE: Dave makes a swipe at Charles over succession laws
Charles voice concerns that the changes to the succession law had been rushed
David Cameron tells MPs that changes to royal succession laws in case William and Kate have a girl have been 'settled and agreed' with the Palace after extensive consultation – a gentle swipe back at Prince Charles, who has complained that the changes have been rushed and could have unintended consequences.
So what's going on? 'The truth is everyone's at fault,' says my Whitehall source.
'The Prince of Wales knows this has been discussed between different governments and the Palace for over a decade, and the idea the Government would go ahead without the nod from the Queen is ridiculous.
But Charles does enjoy grumbling about legislation even when it doesn't affect his family.
And it's also true Cameron and Clegg are now pushing it all through with indecent haste to jump on the Kate baby bandwagon.'
More from Ephraim Hardcastle for the Daily Mail...
- EPHRAIM HARDCASTLE: The Duchess of Cambridge attempts to shake off 'reluctant royal' reputation 02/05/16
- EPHRAIM HARDCASTLE: Sir Cliff Richard delighted in not being recognised as he strolled in New York 28/04/16
- EPHRAIM HARDCASTLE: At 90, how can the Queen's life be made easier? Well, start by helping her avoid the stairs... 28/04/16
- EPHRAIM HARDCASTLE: Prince Charles forced to play £20billion waiting game 26/04/16
- EPHRAIM HARDCASTLE: Still more fanciable at 50 than rivals half her age, Actress Elizabeth Hurley has entered the EU debate 25/04/16
- EPHRAIM HARDCASTLE: Her Majesty approves of thin icing on GBBO winner's orange drizzle birthday cake 22/04/16
- EPHRAIM HARDCASTLE: BBC royal correspondent's revealing interview with Prince William marks a thaw in relations 21/04/16
- EPHRAIM HARDCASTLE: With Barack Obama's arrival comes feverish planning to keep him, the Queen and David Cameron happy 20/04/16
- EPHRAIM HARDCASTLE: The Queen looks set to lose rather than gain this birthday as her dwindling Empire crumbles 19/04/16
THE British Library produces special postcards of literary luminaries such as poet Sir Andrew Motion and novelists Martin Amis and Salman Rushdie.
But they have been reduced from 60p to 10p. My source says: 'I think they found them hard to "shift", as they say. The many admirers of Sir Andrew (pictured) will be very disappointed.' Looking a bit cheerier might have shifted more cards.
TIPPED for an Oscar for his portrayal of Abraham Lincoln, actor Daniel Day Lewis, 55, originally wrote to director Steven Spielberg saying he wasn't interested in the part. Mischievously, Spielberg has made the letter public.
After changing his mind, Day Lewis became obsessed with the US's 16th president. He welcomed actor Joseph Gordon-Levitt, 31, to the cast with a handwritten note signed 'Abraham Lincoln'. I wonder if Daniel will find any slaves to emancipate in his native Co Wicklow.
WINSOME entertainer Dale Winton's unusual new appearance is a source of comment, according to a showbiz expert. 'On Dale's Great Getaway (ITV) he seemed to have trouble turning his head.
Dale (pictured) says he did indeed go under the surgeon's knife but only for a knee operation – one of the few areas of his body not previously nip and tucked.' Now now! Dale's a favourite with many discerning viewers.
MANCUNIAN crooner Morrissey says the Beckhams should be 'flogged', telling Loaded magazine: 'I'd have the Peckhams (sic) dragged to the edge of the village and flogged because they are insufferable to anyone of intelligence.
God forbid they will be bestowed with titles Sir and Lady Peckham.' If the Beckhams deserve to be flogged, what chastisement should moronic Morrissey attract? He said the Duchess of Cambridge was responsible for the nurse who committed suicide at King Edward VII hospital while she was there.


text:
'Discernible mismatch' between funds required and allocated to MEA: Parliamentary Standing Committee report
The Committee took serious note of the "cavalier approach" of the Ministry of Finance over such a serious issue that "undermines" India's credibility abroad.
Set up committee to adopt acceptable GDP methodology: Parliamentary Panel
A Parliamentary Panel today asked the government to constitute a co...
Parliamentary Standing Committee visits Pathankot, other border areas
The Parliamentary Standing Committee on Home Affairs today visited the ...
BJP sacks 12 MPs from parliamentary committees for not attending meeting
In an unprecedented move, BJP has removed 12 of its MPs from crucial parliamentary committees as punishment for not attending meetings held between the Monsoon and Winter sessions of Parliament.
Four PIOs nominated to Democratic Convention Standing Committees
One of the top fund-raisers for President Barack Obama and now Hillary Clinton, California-based Shefali Razdan Duggal has been nominated.
Three PIOs nominated to Democratic Convention Standing Committees
These Party Leader and Members serve in addition to and together with the over 160 members that are elected in every state to those same committees.
Parliamentary panel raps government for not inking Rafale deal
The Standing Committee on Defence, which submitted it report to the LS, also asked the government to ensure that the IAF achieves it authorised strength of 42 squadrons as against 33 presently.
Parliamentary panel picks holes in government's electrification drive
The panel picked holes in electrification of villages, saying that there are cases where electrification of the villages has been done only in records.
Parliamentary panel 'anguished' at shortage of faculty in IITs, IIMs
The Parliamentary Standing Committee on HRD headed by BJP MP Satyanarayan Jatiya, voiced concern over "acute" shortage of faculty in higher education institutions across the country.
Parliamentary committee for simultaneous Lok Sabha, Assembly polls
A Parliamentary Committee has made a strong pitch for holding of simultaneous assembly and Lok Sabha elections all over the country.
Government to make CCTV cameras mandatory in public transport
For transport vehicles that have seating capacity of less than 23 people will have emergency buttons that will be connected to local police station.
Parliamentary Committee finalises draft report on Lokpal
The amendment bill was introduced in the Lok Sabha on December 18 last year after which it was referred to the Committee on December 22. It was asked to submit its report by March 25 this year.
GPS to be made must in public transport vehicles
In a move to make all public transport vehicles safer for passengers and particularly women, soon these will need to install GPS or any other vehicle tracking device.
GST to help reorient states towards export promotion: Parliamentary panel
The Parliamentary Standing Committee on Commerce in its report said that the Department of Commerce must further deepen its engagement with the states .
Parliamentary panel asks govt to review trade pacts with Japan, Korea
The panel appreciated the measures taken by government to bail out the beleaguered steel industry reeling under an "unprecedented crisis".
Land of wound-up CPSEs should be retained with government: Parliamentary panel
Department-Related Parliamentary Standing Committee on Industry, said it has always taken a firm stand that the fixed assets, particularly land.
National Committee on Trade Facilitation soon: Nirmala Sitharaman
"She (Sitharaman) said that after TFA ratification, the world-wide best trade practices would be shared among the member countries," the statement said.
MUDRA Yojna sluggish, bigger role for MFIs needed: Parliamentary panel
"While MFIs have the advantage of outreach and minimal paperwork, the actual interest rates permissible to MFIs under the MUDRA Yojna was around 19 per cent, which is too high," the report said.
Parliamentary panel raps government for terror attack in Pathankot airbase
Parliamentary panel on Home Affairs said the role of Punjab Police is also very "questionable and suspicious" during the January 2 Pathankot attack.
Electric transport policy on anvil for hilly terrains
At one of the major ports in Haldia, the electric engine and other vehicles are already being successfully run on bio-diesel, he said.
Rohith Vemula suicide: Joint Parliamentary Committee team likely to visit Hyderabad University
The panel has favoured sending a delegation to the institution and also IIT-Chennai, to look into complaints of injustice against Dalit students.
Parliamentary panel asks coal PSUs, government to recover dues
A Parliamentary Panel has asked the government as well as the state-owned firms in the sector to take steps for the recovery.
Parliamentary panel for common electoral roll for Lok Sabha to panchayat polls
The EC had said that in almost all the cases, the same machinery at the field level is entrusted the job of preparing and revising rolls for both types of elections.
Without dissent, parliamentary system is dysfunctional: President Pranab Mukherjee
Emerging economies like China, India, South Africa, Brazil and host of other countries have shown that G-8 countries no longer decide the fate of world economy, he said.
Develop early warning system to detect frauds:Parliamentary panel to MCA
The observations have been made by the Parliamentary Standing Committee on Finance, headed by Congress leader Veerappa Moily, in its report on Demand for Grants (2016-17) of the MCA.
Parliamentary Panel suo motu examines NPAs in public banks
"We examined chairpersons of the PSBs as well as Governor of Reserve Bank (Raghuram Rajan)," Chairman of Public Accounts Committee K V Thomas said.
Parliamentary committee expresses concern over delay in granting bail to undertrials
Members of a Parliamentary committee have expressed concern over delays in granting bail to undertrials for want of money and have suggested involvement of elected representatives to ensure that those in need get good lawyers to contest their cases.
Sania Mirza pens autobiography, to hit stands in July
Sania Mirza has documented her journey to become the World No. 1 in the women's doubles in an autobiography.
Sania Mirza pens autobiography, to hit stands in July
Mirza, who announced her retirement from the singles circuit in 2012 underwent a remarkable transformation between August 2015 and March 2016.
Parliamentary panel favours Vijay Mallya's expulsion from Rajya Sabha
At the same time, the Ethics Committee of Rajya Sabha headed by veteran Congress leader Karan Singh, decided to give Mallya one week time to explain his conduct.
Parliamentary panel for review of fuel adjustment component for benefit of railway passengers
The Standing Committee on Railways in its latest report tabled in Parliament today noted that the Railways had announced the continuation of the FAC.
Parliamentary committee pulls up centre for inadequate budget allocation for MEA
The committee felt that the budgetary allocation was grossly inadequate, given the size and aspirations of the country.
Plan of Multi-Model Transportation Hub at Surat discussed
IRSDC officials held discussions with the representatives of reputed developers and other real estate players for developing Surat in South Gujarat as MMTH.
Parliamentary Committee asks Finance Ministry to implement government assurances in LS
The Committee on Government assurances has also asked the Finance Ministry to impress upon RBI to improve transparency in pricing and loan documentation.
Namma Cycle - an initiative to make Bengaluru adopt green transport
In the IISc experiment, Murali circulated 150 bicycles for students and faculty to move around on the sprawling campus.
Road transport and highways ministry will soon set up empowered committee to clear stalled road projects
Gadkari has also called a conference of bankers and concessionaires in Delhi on January 28 where Jaitley is also expected to be present.
Shriram Transport Finance surges on higher net income growth
Shares of Shriram Transport Finance surged 8 per cent in trade on Monday on higher net income and full provisioning for bad loans.
Overweight on Shriram Transport, target at Rs 1,050: JP Morgan
Credit costs of the company remained elevated on account of the CE merger, and a shift to the 150-day norm.
Parliamentary panel recommends punishment for companies offering bribes to public servants
Government sources said that the panel has recommended anti-bribery guidelines for companies and their employees while dealing with public servants.
Confer executive powers to Niti Aayog for more effective functioning: Standing committee
Since the Aayog is seen as only a think tank and an advisory body that lacks teeth, neither central ministries nor states feel compelled to heed its advice.
I admire Kangana for standing up for herself, says Vidya Balan
Vidya was speaking at the trailer launch of her upcoming film 'Te3n'. Megastar Amitabh Bachchan was also present at the event.
Government making Parliamentary standing committees irrelevant, says opposition
Opposition parties today charged the government with making Parliamentary Standing Committees "irrelevant" by bypassing them while passing legislations.
Need for business-related courts in J&K: Parliamentary Standing Committee
Natchiappan said besides the various government agencies involved, the committee also held meetings with private trade bodies and other stake holders to seek their inputs.
I stand by Kangana in all her legal battles: Actress's father
Kangana's father accompanied her along with other family members to the national capital to receive the National Award.
India's different stands on South China Sea lead to confusion
In two recent international joint statements, India has taken slightly different positions on the biggest point of international conflict that is about to come to a head in the coming days, leading to some confusion.
Complete mid-term review of 12th Plan: Parliamentary Panel to NITI Aayog
Noting that 12th Plan is going to be over in less than a year, the panel said that they are not at all clear about the status of planning process in future.
Cash for favours: Parliamentary panel issues notice to 5 TMC MPs
The ethics committee of Lok Sabha has sought explanation from five Trinamool Congress MPs, who were allegedly caught in a sting operation accepting cash last month.
Transport Corporation of India incorporates a wholly-owned subsidiary in Bangladesh
"Company have successfully incorporated a wholly-owned subsidiary by the name, 'TCI Bangladesh Limited' in Bangladesh," the company said in a filing to BSE.


text:
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PEARL, MS -- Williams Perez tossed eight innings, giving up one unearned run on three hits to lead the Mississippi Braves to a 7-1 victory over the Birmingham Barons Sunday evening at Trustmark Park. With their sixth-consecutive win, the M-Braves maintain a one-game lead in the Southern League South Division Standings.
Mississippi (39-24, 78-54) plated seven runs on 14 hits while Birmingham (29-34, 58-75) scored one unearned run on three hits. Offensively for the M-Braves, Braeden Schlehuber went 3-for-4 at the plate with three ribbies.
Perez faced just two batters over the minimum through eight innings and went back out for the ninth. After the first two batters reached, Perez handed things over to Ryne Harper. Perez (7-6) gave up one unearned run on three hits while fanning six. Harper walked one but recorded three ground outs to end the game.
The M-Braves took a 2-0 lead in the first. Kyle Wren and Gustavo Nunez reached on back-to-back singles. An error by the catcher allowed Wren to advance to third before Kyle Kubitza delivered a RBI-single to right. Cedric Hunter then followed with a base hit to right, scoring Nunez from third.
Hunter led off the bottom of the third with a walk and then stole second. A RBI-single from Seth Loman extended the Braves lead to 3-0. Rich Poythress singled and Mycal Jones singled to drive home Loman. Schlehuber followed with a single to center, scoring Poythress and making it a 5-0 game.
Kleinknecht walked to start the Braves' seventh. Erik Castro then singled and Mycal Jones grounded into a force out, putting runners at the corners. Schlehuber then delivered a two-run double down the left field line, extending the M-Braves lead to 7-0.
In the top of the ninth, Michael Earley singled and Trayce Thompson reached on an error, allowing runners to move to second and third with no outs. Harper came on to relieve Perez. He was able to get Tim Anderson to ground out, but Earley came in to score on the play.
Terance Marin (0-1) gave up five earned runs on 10 hits and two walks. He struck out three in five innings of work and took the loss in his Double-A debut.
In game four of this five-game series at Trustmark Park, M-Braves right-hander Joe Gardner (2-2, 3.21) counters Barons righty Chris Bassitt (3-0, 0.87). First pitch is slated for 7:00 PM Monday. Gates open at 6:00 PM.
Birmingham Barons (29-34, 58-75): 1 R 3 H 1 E
Mississippi Braves (39-24, 78-54): 7 R 14 H 1 E
W: Williams Perez (7-6)
L: Terance Marin (0-1)
Time: 2:42
Attendance: 4,329
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Get the Best Priced BMW 330i Air Fuel Ratio Sensor
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BMW 330i Replacement Air Fuel Ratio Sensor Information
Search our online air fuel ratio sensor catalog and find the lowest priced discount auto parts on the web. We sell wholesale to the public. We offer high quality new, OEM, aftermarket and remanufactured BMW 330i Air Fuel Ratio Sensor parts. We specialize in a wide-variety of high-quality car parts and accessories for your car, truck or SUV. Call toll free to order or place your order online via our secure checkout system. Our online parts catalog uses real-time inventory, so you can be assured the parts you buy are in stock at the time of ordering. Most orders are shipped the same day. They are available for the following BMW 330i years: 2006, 2005, 2004, 2003, 06, 05, 04, 03. This part is also sometimes called BMW 330i Wide Range Air Fuel Sensors. We stock air fuel ratio sensor parts for most BMW models including 325i, X5, X3, 745Li, M3, 545i, 325xi, 530i, 528i, 135i, 335i, 745i, 525i, 328i, 323i, 330Ci, 325Ci, 330xi, 535i, Z4, 328xi, 550i, 645Ci, 530xi, 328i xDrive, 650i, 335xi, 525xi, 535xi, 535i xDrive, 128i, 760Li, 335i xDrive, 528xi, 335d, X6, 528i xDrive, Alpina B7 and 760i.
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Denso 234-5135
Air Fuel Ratio Sensor
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Sale Price: $93.23
Product SKU: 234-5135
Product Note: OE Style -- To 11/2005; Cylinder 4,5,6; O.E. Quality Replacement Sensor
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I was very satisfied in the parts received.
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I'm thinking of traveling to NewZealand next year and want to fly business class with my wife. I'm retired and for many years I was platinum but now I'm a only a silver elite, so no chance of upgrading. I checked on United's web site and the cost for two Business Class tickets was 20K. I went to a ticket broker and the cost was only $7,500 for two Business seats (coach was $4,400 for two tickets). Is there any risk of using a ticket broker and will you still earn one pass miles if I use a ticket consolidator?
Recent ActivityView all Air Travel activity »
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- 25 name on ticket and passport
Business tickets to New Zealand
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This question might be better asked on Flyertalk.
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Is there any risk of using a ticket broker and will you still earn one pass miles if I use a ticket consolidator?
Yes and maybe. Where are you flying from and when are you flying?
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One question to ask of the consolidator is whether the tickets have been purchased with other people's frequent flier miles. Because this is against the "terms of use" the airline can confiscate your ticket and require you to purchase a full-priced ticket in order to fly.
It used to be that there were a number of credit cards that had a "buy one get one free" deal for Biz class tickets. American Express had such a card.
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United doesn't fly to New Zealand. That 20K fare is a full unrestricted fare. Has to be. I took a look at Air New Zealand webpage and they have a special fare (restricted) for $5900 per person roundtrip nonstop from LAX or SFO.
Business class is different on different airlines. What exactly are you getting for your $7500.
itasoftware shows a business class fare of $3625 per person roundtrip connecting both ways in Hawaii.
On another search I found Air Fiji business class for about $3600.
Another search on different dates and the best fare was $4300 on China Southern via Guangzhou, China.
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Qantas is introducing a major business class upgrade. http://tinyurl.com/nwfcdpw
Vic's travels: http://my.flightmemory.com/vogilvie
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I currently pay about $6000 to $7000 Aussie dollars for business class tickets from Australia to LAX or JFK which is a great deal. They used to be more like $8000. I am amazed that it is 10K per ticket from the US to Australia. I've always found tickets originating from Australia dearer. Surely it must be less.
I'd be careful of those discounted fares you describe. Many are purchased with other people's frequent flyer points and if you miss a flight it is money gone down the drain.
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text:
already in thee hole
Sentiment: Strong Buy
how much?
looks like too much i dont want to have to hold this cancer stocks scare me
learn to read a chart dumbazz
Learn to save money and not trade in AH or PRE...lololol
Yes, you might think it is high now. Just lock it up for 6 to 1 year. You will be happy.
Good luck.
Sentiment: Hold
Maybe for the day but give it a year - you'll be glad you bought at any price this month :)
i only want it for the day too much money to tie up for 6 mos to a year


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Black Watch Cruise Review by Linda Gray: Viking Awful!
Overall Member Rating
Viking Awful!
Destination: Transatlantic
Embarkation: Other
This was our first (and only) Fred Olsen cruise. Started well - very friendly and efficient bar and restaurant staff. Small, intimate ship. Food was OK but not the best. Lacked variety - why so much pork???
Then things turned grim. Atrocious weather (in August!) meant that that we had two ports-of-call cancelled. No substitutions arranged by humourless captain. We were begging for landings in the Faeroe Islands, Northern Ireland, Scotland, Isle of Man, Republic of Ireland, England, Wales, Scilly Isles, anywhere!
"Entertainment" was amateurish. The singers/musicians in the upstairs bar were fun but the so-called dancers in the Neptune Lounge were dreadful. Perhaps we've been spoilt by American cruises but these were more like unimaginative, lazy junior school productions! Other passengers were ancient. Lounge looked more like a care home than a cruise ship! Lectures were also delivered in the Neptune Lounge - rubbish venue. Loads of view-obstructing pillars and not More enough seats. Why no proper theatre?
However, we did like that we could order discounted cigarettes and alcohol from our cabin. And they would be delivered discreetly in a brown paper bag!Also, the ship was great for discounting certain drinks. And we had two nights of free drinks - the Captain's Welcome Party and a Gala Party. I can see why this company attracts repeat clients! However, like another reviewer, I too was irked by having to pay a hefty fuel supplement (after paying full price!) when other customers paid only £700 for a £2000 cruise! Not fair! Less
Published 04/26/12
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Read Cruise Critic's Black Watch Review >>
Cabin review: G
We stayed in an outdoor cabin (but no balcony). 2 twin beds (but one doubled as a couch, so not so roomy). Fairly spacious cabin. 2 wardrobes and tea/coffee tray inside one wardrobe. Bathroom OK - usual parameters. Live lectures transmitted to cabins but sometimes no sound!
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Gaza mortar shells target Israeli forces searching for Hamas tunnels; Israel responds with airstrike, tank fire and declares border area a closed military zone; Hamas evacuates two schools as a precautionary measure.21:44 04.05.16 | 4 comments
lets be realistic. Israel can not negotiate any meanigles final agreement neither with Abass, he is to weak, nor with PA Hamas government. So, Israel agrees to the security fence line withdrawal from WB and it withdrew already from Gaza. Hudna agreement will also include the understanding that PA, under any contro (Fatah, Hamas or "Bobe Maise Liberation Movement" will not build up an army to attack Israel. If they do try Israel will act as required. Meanwhile in 50-60 years maybe a new generation of Palestinians will arise with whom a realistic peace agreement can be reached.


text:
A 45 years old woman died while fetching water in Maharashtra's drought-hit Latur district on Tuesday. She was forced to go out in 42 degrees Celsius heat to get water from an almost dry hand-pump.
The post Latur drought: At 42 degree Celsius heat, woman dies while waiting to fetch water appeared first on Firstpost.


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Vivitek has introduced two new models in its lineup of portable, single-chip DLP projectors designed for classroom use. The D825ES and D825EX offer high light output and high contrast ratios but come in at less than $900.
Both of the new models offer a brightness of 2,600 ANSI lumens and a contrast ratio of 2,200:1 (on/off). The D825ES is an SVGA (800 x 600) projector, while the D825EX sports an XGA resolution (1,024 x 768). Both weigh in at 5.7 pounds.
Other features include:
The Vivitek D825ES and D825EX are available now for $719 and $819, respectively. Further information can be found here.
About the Author
David Nagel is editorial director, education for 1105 Media's Public Sector Media Group and editor-in-chief of THE Journal. A 22-year publishing veteran, Nagel has led or contributed to dozens of technology, art and business publications.
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Those who have successfully integrated 3D printing and related activities into their districts have learned how to tap the power of grant funding to cover the expenses and extend their programs in new and innovative ways. This report will provide advice for making your own "grant grab" to bring the benefits of 3D printing to your students.
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Home > Lifestyle > Entertainment > Music
Tuesday, 27 May 2014 | MYT 10:05 AM
Mick Jagger (centre), Ron Wood (left) and Keith Richards. – AFP
Super band is on tour again; Oslo is first stop.
The Rolling Stones were set to resume their world tour in Oslo on Monday (June 2), interrupted more than two months ago due to the suicide of Mick Jagger's partner.
Oslo is the first European stop of the "14 on Fire Tour", and the show has caused a frenzy among the legendary's band's Norwegian fans with the 25,000 tickets selling out in just 13 minutes.
Ticket prices for the concert range from 115 to 310 euros (RM500-RM1,360)
The Stones suspended their tour in March as they were about to perform in Australia after Mick Jagger's partner, L'Wren Scott, committed suicide in her New York flat.
After Oslo, the next stops will be Lisbon, Zurich, Tel-Aviv, the Pinkpop Festival in the Netherlands, Berlin, Paris, Vienna, Dusseldorf, Rome, Madrid and the TW Classic Festival in Belgium, before returning to Scandinavia with shows in Stockholm and Roskilde (Denmark) in the beginning of July. – AFP Relaxnews
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'Honky Tonk Women' too dirty for China as song 'vetoed'
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Keith Richards wants to publish a children's book
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Watch Captain America with GSC Maxx, D-BOX, Dolby Atmos and THX at one go
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|Publication number
|Publication type
|Application number
|Publication date
|Aug 12, 1986
|Filing date
|Aug 31, 1984
|Priority date
|Aug 31, 1984
|Fee status
|Also published as
|Publication number
|Guy Senatore
|Original Assignee
|Phillips Petroleum Company
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (5), Non-Patent Citations (6), Referenced by (13), Classifications (11), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
This invention relates to poly(arylene sulfide)s. It relates to methods for preparing poly(arylene sulfides). In a specific aspect, the invention relates to the production of poly(arylene sulfide)s and products produced therefrom having improved thermal stability.
Polyarylene sulfides are an important class of engineering thermoplastics. The favored commercial process for the production of polyarylene sulfides involves the reaction of an aromatic compound such as dichlorobenzene with a sulfur source such as sodium sulfide in a polar reaction medium such as N-methylpyrrolidone. The polymer produced is resistant to many chemicals and exhibits good thermal stability. However, for the increasing industrial applications of polyarylene sulfide, improved thermal stability is desirable. One application is the use of nonwoven fabrics prepared from polyarylene sulfide fibers as filter bags for industrial smokestacks. For this and similar applications, improved heat stability of the polyarylene sulfide fibers is desirable. For certain applications such as thick films, a polyarylene sulfide having relatively low Tmc is desirable.
It is therefore an object of this invention to provide a method for the preparation of polyarylene sulfides. It is a further object to provide a method for preparing polyarylene sulfides having improved heat stability. In one embodiment, it is an object to produce a polyarylene sulfide fiber or monofilament having improved heat stability. In a further embodiment, it is an object to produce low Tmc polyarylene sulfide.
According to the invention, poly(arylene sulfide) is produced in a reaction mixture which includes a dihaloaromatic compound, a sulfur source, a polar organic compound and an alkali metal or alkaline earth metal dithionite. The presence of dithionite in the reaction mixture enables the preparation of polymer and products therefrom having a reduced Tmc and enhanced heat stability.
The invention method for producing polyarylene sulfides involves a reaction mixture which contains at least one dihaloaromatic compound of the formula ##STR1## wherein each X is selected from the group consisting of chlorine, bromine and iodine, and each R is selected independently from the group consisting of hydrogen and hydrocarbyl in which the hydrocarbyl can be alkyl, cycloalkyl, aralkyl and the like, with the total number of carbon atoms in each haloaromatic molecule being within the range of 6 to about 24. It will generally be expected that at least about 75 mole percent, preferably about 90 mole percent, and most preferably about 99 mole percent or greater of the haloaromatic compound in the reaction mixture will be such that each R is hydrogen. The preferred such major haloaromatic compound for the reaction is p-dichlorobenzene, because of its availability and the properties of the poly(phenylene sulfide) product.
The reaction mixture may optionally contain a dihaloaromatic compound in which the halogens are attached at ortho or meta positions on the ring, which can be otherwise substituted or unsubstituted as discussed above for the R moiety. Such an ortho- or meta-dihaloaromatic compound will generally be present in the reaction mixture in a minor amount relative to the para-dihaloaromatic compound, usually about 0.001 to about 30 mole percent, preferably about 0.01 to about 3 mole percent, based on total haloaromatic compounds.
The reaction mixture may optionally contain a polyhaloaromatic compound having more than two halogens directly attached to an aromatic ring. Such polyhaloaromatic compound may be further substituted or unsubstituted on the ring as discussed above for the R moiety, and will generally be present in the reaction mixture in a minor amount, compared to the amount of the p-dihaloaromatic compound present. The preferred such polyhaloaromatic compound is a substituted or unsubstituted trihaloaromatic compound, preferably 1,2,4-trichlorobenzene. Such a polyhaloaromatic compound will generally be present in the reaction mixture in an amount of from about 0.001 to about 30 mole percent, based on the total moles of haloaromatic compounds in the reaction mixture, preferably about 0.01 to about 3 mole percent.
The reaction mixture will also contain a sulfur-containing compound which serves as the source of sulfur for the sulfide linkages. Suitable sulfur sources include, for example, alkali metal and alkaline earth metal thiosulfates, substituted and unsubstituted thioureas, thiocarbamates, thiocarbonates, carbon disulfide, carbon oxysulfide, mercaptans, mercaptides, thiomides and sulfides having an alpha or beta activating substituent. Such sulfur sources are generally employed in combination with a base, as discussed below, which will generally be present in the reaction mixture in an amount of about 1 to about 6, preferably about 1.8 to about 4 gram equivalents per gram atom of sulfur in the sulfur source, although one skilled in the art will known that the optimum amount of base will depend upon the specific sulfur source selected. Such sulfur sources and the bases employed are known in the art as disclosed in, for example, U.S. Pat. No. 3,919,177.
The more commonly used and presently preferred sulfur sources are alkali metal bisulfides, alkali metal sulfides and elemental sulfur. The alkali metal bisulfides include anhydrous or hydrated bisulfides of sodium, lithium, potassium, rubidium and cesium. It is generally not necessary to use a base when a bisulfide sulfur source is employed. If no base is added, the alkali metal bisulfide will generally be present in an amount of from about 0.8 to about 1.5 gram-moles per gram-mole of the haloaromatic compound. If a base is added to the reaction mixture, it will generally be employed in an amount of from about 0.3 to about 4, preferably from about 0.4 to about 2, gram-equivalent per gram-mole of alkali metal bisulfide. The preferred bisulfide is sodium bisulfide, NaHS.
The metal sulfides, including monosulfides in anhydrous and hydrated form, can be represented by the formula M2 S where M is selected from the group consisting of sodium, potassium, lithium, rubidium and cesium. The preferred sulfide is sodium sulfide, Na2 S.
Elemental sulfur can be used as the sulfur source. When elemental sulfur is used, a base will generally be added to the reaction mixture in an amount within the range of about 1 to about 5, preferably about 1.5 to about 4, gram equivalents per gram atom of sulfur.
The reaction mixture will also include a polar organic compound such as an organic amide, which is liquid at the reaction temperatures and pressures used. The amides can be cyclic or acyclic and will generally have 1 to about 10 carbon atoms per molecule. Examples of suitable amides include formamide, acetamide, N-methylformamide, N,N-dimethylacetamide, N-ethylpropionamide, N,N-dipropylbutyramide, 2-pyrrolidone, N-methyl-2-pyrrolidone, E-caprolactam, N-methyl-6-caprolactam, N,N'-ethylenedi-2-pyrrolidone, hexamethylphosphoramide, tetramethylurea, and the like. N-methyl-2-pyrrolidone is the preferred organic amide.
Bases which can be employed include lithium hydroxide, sodium hydroxide, potassium hydroxide, rubidium hydroxide, cesium hydroxide, magnesium hydroxide, calcium hydroxide, strontium hydroxide, borium hydroxide, sodium carbonate, potassium carbonate, rubidium carbonate, cesium carbonate, and the like. If desired, the hydroxide can be produced in situ, for example, by the reaction of the corresponding oxide with water.
It is preferable to include in the reaction mixture an alkali metal mono, di or poly carboxylate or other suitable chemical agent to increase the molecular weight of the polyarylene sulfide product. Included in the alkali metal carboxylates which can be employed are those represented by the formula RCO2 M wherein R is a hydrocarbyl radical selected from alkyl, cycloalkyl, and aryl and combinations thereof such as alkylaryl, alkylcycloalkyl, arylalkyl, arylcycloalkyl, and the like, the hydrocarbyl radical having 1 to 20 carbon atoms, and M is an alkali metal selected from the group consisting of lithium, sodium, potassium, rubidium and cesium. Preferably, R is an alkyl radical having 1 to about 6 carbon atoms or a phenyl radical and M is lithium or sodium. If desired, the alkali metal carboxylate can be employed as a hydrate or as a solution or dispersion in water.
Examples of some alkali metal carboxylates which can be employed include lithium acetate, sodium acetate, sodium formate potassium acetate, lithium propionate, sodium propionate, lithium 2-methylpropionate, rubidium butyrate, sodium valerate, cesium hexanoate, lithium heptanoate, lithium 2-methyloctonoate, potassium dodecanoate, sodium octadecanoate, lithium cyclohexanecarboxylate, potassium cyclohexylacetate, potassium benzoate, lithium benzoate, sodium benzoate, potassium m-toluate, lithium phenylacetate, sodium 4-phenylcyclohexanecarboxylate, potassium p-tolylacetate, and the like, and mixtures thereof. The preferred alkali metal carboxylate is sodium acetate.
The invention process includes adding an alkali metal or alkaline earth metal dithionite to the reaction mixture in the preparation of a poly(arylene sulfide). The dithionite is preferably selected from sodium and lithium dithionite, most preferably sodium dithionite (Na2 S2 O4). It will be present in the reaction mixture in an amount effective to improve a property, such as Tmc or heat stability, of the poly(arylene sulfide) produced. Generally, the dithionite will be present in the reaction mixture in an amount of about 0.0001 moles to about 0.1 moles, preferably about 0.001 to about 0.01 moles, based on moles of donated sulur in the sulfur-containing compound.
The dithionite can be added to the reaction mixture in one or more aliquots at any point, from the initial dehydration stage to the latter stages of the polymeration reaction. It has been found suitable to charge the dithionite to the reaction vessel with the sulfur sources, the base, the alkali metal carboxylate and the polar organic compound for dehydration of this porion of the reaction mixture prior to addition of the dihalobenzene compound. Additional dithionite can be added to the reaction mixture after dehydration or, as desired, during the reaction.
The invention process can produce poly(arylene sulfide) polymer having a reduced temperature of melt crystallization (Tmc), as determined with a differential scanning calorimeter by cooling molten polymer (360� C.) at a rate of 20� C. per minute. For some applications, including the production of certain types of film and fibers, it is desirable for the poly(arylene sulfide) to have a Tmc lower than about 230� C., preferably within the range of about 160� C. to about 200� C.
The properties of the resin produced by the invention process can vary widely depending upon the specific components of the reaction mixture and the reaction conditions. The presently preferred resin for film, fiber and monofilament applications, including biaxially-oriented film, has a melt flow (as determined by modified ASTM D-1238 at 316� C. with an orifice of 0.0825" diameter and 0.315" length and an effective weight of 5.0 Kg including the weight of the piston) of about 30 to about 300 g/10 min, preferably about 30 to about 250 g/10 min, and a Tmc of about 150� C. to about 230� C., preferably about 160� C. to about 200� C. The preferred resin is formed from a reaction mixture comprising about 0.98 to about 1.05 moles of p-dichlorobenzene, about 0 to about 0.005 moles of trichlorobenzene, about 0.9 to about 1.1 moles of sodium hydroxide, about 0.1 moles to about 0.6 moles of sodium acetate, and about 0.001 to about 0.01 moles of sodium dithionite, in sufficient volume of N-methylpyrrolidone (NMP) to serve as a medium for the polymerization reaction, generally about 2 to about 5 moles of NMP, per 1.0 mole of sodium bisulfide.
The resin produced in the invention process is particularly suited for fiber and monofilament applications because of its superior heat stability. Fiber from the resin can be used, for example, in industrial bag filters because of the chemical resistance and heat stability of the polyarylene sulfide.
The conditions of polymerization of polyarylene sulfides are generally known and can vary widely, but will generally include a temperature within the range of about 420� F. to about 600� F., preferably about 435� F. to about 540� F. The reaction time will usually fall within the range of about 1 hour to about 8 hours. The pressure should be sufficient to maintain N-methylpyrrolidone in liquid phase. The polymer can be recovered as desired, preferably by use of a separation agent as in the process disclosed in U.S. Pat. No. 4,415,729.
In this example the preparation of a poly(phenylene sulfide) control resin is described. To a stirred two-gallon autoclave reactor were charged 562.7 g (6.00 moles) NaSH, 254 g (6.35 moles) NaOH pellets, 147.6 g (1.8 moles) sodium acetate, and 1600 cc N-methylpyrrolidone (NMP). The reactor was purged with N2 and heated to about 160� C. with stirring (250 r.p.m.). Dehydration was started, and about 360 cc distillate (H2 O and NMP) was collected while the temperature rose to about 200� C.
Then 904.1 g p-dichlorobenzene (DCB) and 325 cc NMP were charged. The reaction mixture was heated at about 235� C./40 psig for about 2 hours. Subsequently the temperature was raised to about 265� C., and the reaction mixture was heated at 265� C./170 psig for 3 hours.
The reaction mixture was allowed to cool to room temperature overnight. The formed grey solid poly(phenylene sulfide) resin was ground in a Waring blender, washed twice with water, and dried in a forced air oven at about 120� C. The total polymer yield was 595 grams. The melt flow (flow rate) of this polymer (labeled Resin 1) was 90.4 g/10 min. (determined according to a modified ASTM D1238 procedure, at 316� C., employing an orifice of 0.0825" diameter and 0.315" length, and an effective weight of 5.0 Kg including the weight of the piston).
The melt crystallization temperature (Tmc; determined on a Perkin-Elmer DSC-2C scanning calorimeter by cooling of the polymer melt starting at 320� C.) of Resin 1 was 216� C.
In this example the preparation of poly(p-phenylene sulfide) resin in accordance with the invention method is described. 562.4 g (6.00 moles) of NaSH, 254.0 g (6.35 moles) of NaOH, 147.6 g (1.80 moles) of sodium acetate, 1600 cc N-methylpyrrolidone (NMP) and 2.09 g (0.012 moles) of Na2 S2 O4 (sodium dithionite) were charged to a stirred two-gallon reactor. The N2 -purged mixture was dehydrated at about 185� C., and 400 cc of distillate was collected.
Then 904 g (6.15 moles) of DCB, 2.09 g (0.012 moles) Na2 S2 O4 and 325 cc NMP were charged. The reaction mixture was heated and the polymer was recovered in accordance with the procedure described in Example I. The flow rate of this resin (labeled Resin 2) was 113 g/10 min; its Tmc was 193� C. (about 20� C. lower than that of Resin 1).
A second resin (labeled Resin 3) was prepared in accordance with the above-described process; its flow rate was 190 g/10 min.; its Tmc was 207� C. (about 10� C. lower than that of Resin 1).
In this example the extrusion of fibers from the PPS resins and pertinent fiber properties are described. Resins 1, 2 and 3 were vacuum dried, pelletized in a 1" NRM extruder with 250 mesh screen at 180� F. with N2 purge, and then spun into monofilaments in a 1" Wayne Machine and Die Co. extruder at a temperature of about 300� C., at a rate of 1 cc/minute, employing a 20/60/150/325/60/20 mesh screen pack. The gold-colored filaments were wound up at a rate of about 300 feet per minute, and were drawn over a hot plate at about 100� C.
The drawn fibers (draw ratio: about 4x) were then suspended at zero tension in an oven at about 200� C. Fiber properties after various time periods at 200� C. are summarized in Table I.
TABLE I______________________________________ Knot Time Tenacity2 Elongation2 Strength3Resin (Hrs.) Denier1 (gpd) (%) (gpd)______________________________________1 0 26 5.0 24 3.7(Control) 240 30 4.7 29 3.4 500 27 4.6 25 3.3 1210 27 3.7 19 3.4 1650 28 3.0 12 2.4 2180 29 3.0 8 0.62 0 26 4.1 22 3.9(Invention) 290 26 4.8 23 3.4 940 25 4.1 21 3.3 1280 28 3.5 18 3.0 1680 27 3.9 20 3.4 2340 30 2.2 10 0.63 0 27 4.5 19 3.3(Invention) 290 26 4.9 23 4.2 940 27 4.2 21 3.6 1280 27 4.2 22 3.3 1680 27 3.6 19 3.1 2340 27 3.3 16 0.9______________________________________ 1 weight in grams per 9000 meters 2 at failure; determined by means of an Instrom 1122 tensile tester; expressed in grams per denier 3 ultimate fiber strength (at failure) in knot region; expressed in grams per denier.
Data in Table I show that the fibers of resins 2 and 3 retained their high knot strength, elongation and tenacity after heating for about 1650-1700 hours at 200� C., whereas fibers of control resin 1 showed, after heating for about 1650 hours, a decrease of about 35% in knot strength and of about 50% in elongation. These data indicate that resins 2 and 3, prepared with about 0.4 mole-% Na2 S2 O4 added to the polymerization reaction, exhibited greater thermal stability than the control resin prepared without Na2 S2 O4.
This example illustrates additional polymerization runs employing 6.00 moles NaSH, 6.15 moles NaOH, 1.8 moles Na acetate, 1925 cc NMP, 6.18 moles of DCB and 0.024 moles of Na2 S2 O4, substantially in accordance with the procedure of Example II. Resin 4 was a control run with no added Na2 S2 O4. Resin 5 was prepared by adding the entire amount of Na2 S2 O4 (together with NaSH, NaOH, Na acetate and 1600 cc NMP) before dehydration. Resin 6 was prepared by adding the entire amount of Na2 S2 O4 at the same time when DCB was charged. Resin 7 was prepared in accordance with the procedure described for Resin 2, i.e., 50% of Na2 S2 O4 was added before dehydration, and 50% was added with DCB.
Resins 4-7 were pelletized, spun and oven-aged essentially in accordance with the procedure described in Example III. Fiber properties and thermal aging results are summarized in Table II and III.
TABLE II______________________________________ Knot Tenacity Elong. StrengthResin Denier (gpd) (%) (gpd) Color1______________________________________4 28 4.3 19 3.2 3(Control)5 27 4.0 23 3.6 3(Invention)6 26 4.4 18 3.4 1(Invention)7 27 4.1 22 3.2 2(Invention)______________________________________ 1 Color rating: 1 (lightest), 3 (darkest).
TABLE III______________________________________Aging at 200� C. Aging at 240� C. Days to Days to Days to Days to Days toResin 1/2 Tenac. 1/2 Elong. 1/2 Tenac. 1/2 elong. Failure______________________________________4 77 >100 26 25 >45(Control)5 >100 98 26 25 45(Invention)6 94 99 27 25 45(Invention)7 >100 >100 18 22 >45(Invention)______________________________________
Data in Table II show that fibers of the inventive resins had essentially the same physical properties as the central resin fiber but were generally less colored. Table III shows that at 200� C. the inventive resins 5-7 exhibited superior strength retention than control resin 4, whereas at 240� C. no such advantage prevailed.
In this example representative runs for the preparation of PPS, with and without sodium dithionite addition, in a pilot plant reactor are described.
In aqueous sodium sulfide solution was prepared by mixing 72.7 lb of a 50.58 weight-% NaOH solution with 87.2 lb of a solution containing 59.46 weight-% NaHS and 0.49 weight-% Na2 S. This solution plus 23.5 lb of sodium acetate, 146 grams (0.32 lb) of Na2 S2 O4 (dissolved in 600 mL of distilled water) and about 34 gallons of N-methylpyrrolidone (NMP) were added to an agitated pilot plant reactor, which was purged with N2. The mixture was first heated at about 333� F./17 psig for about 25 minutes with stirring. Then the temperature was gradually raised to about 450� F., at 17 psig, and the mixture was allowed to dehydrate for a period of about 90 minutes.
Subsequently 135 lb of 1,4-dichlorobenzene (DCB) and 0.32 lb of Na2 S2 O4 (dissolved in 600 mL H2 O) were added to the dehydrated reaction mixture. The entire mixture was stirred and heated for about 2 hours at about 450� F. (pressure 30-73 psig), and then, after a heating-up period of 25 minutes, for about 1 hour at 510� F. (pressure: 154-167 psig). Then 153 g of 1,2,4-trichlorobenzene (TCB) and 2 gallons of NMP were added, and the reaction mixture was heated at about 510� C. for additional 2 hours.
The reactor contents were cooled at a rate of about 2� F. per minute. When a temperature of 275� F. (17 psig) was attained, 10 gallons of cold water were added. After the temperature had dropped to about 225� F., the entire reactor contents were transferred to a dilution tank containing about 50 gallons of city water.
The slurry was filtered through a 200 porosity filter cloth in a Straight Line belt filtration unit. The PPS filter cake was resurried with about 120 gallons of cold water and filtered. The PPS was washed with about 80 gallons of hot water (350� F.) containing about 220 grams of CaCl2 and finally with about 80 gallons of hot water (350� F.). The PPS resin, labeled Resin 8, was dried. It had a flow rate of 67 g/10 min, and an ash content of 0.43 weight-%. Na content was 35 ppm; Ca content was 1148 ppm.
A control resin, labeled Resin 9, was prepared essentially in accordance with the above-described procedure of this example, except that no Na2 S2 O4 was added. The melt flow of this resin was 113 g/10 min; and the ash content was 0.45 weight-%. Na content was 48 ppm; Ca content was 1192 ppm.
This example illustrates the use of the resin of Example V in film applications. Resins 8 and 9 were pelletized on a 11/2" D-S extruder at a die temperature of 610�-620� F. and a melt pressure of 1000-1100 psi. PPS pellets were dried overnight in a vacuum oven at about 110� C. and were extruded through a slot die (10 mils�3 inch) at a die temperature of about 515� F.
The extruded sheets made from Resins 8 and 9 were stretched 3.0 x in one direction and 3.2-3.5 x in the perpendicular direction, and were then heatset at 275� C. for 90 minutes. Physical properties of several samples of biaxially oriented films (thickness: 0.03-0.05 mm) are listed in Table IV.
TABLE IV______________________________________Tensile Strength Elon- Den-(MPa) gation sityResin At Yield At Break (%) Haze1 (g/cc) (g)2______________________________________8 95 111 34 10.4 1.365 9.7(Invention) 100 127 63 9.19 94 129 55 7.1 1.367 9.6(Control) 100 132 49 8.7______________________________________ 1 Measured by means of a HunterLab D55H hazemeter, using films of approximately 1.5 mil thickness. 2 Elmendorf tear resistance measured by means of an Elmendorf Model 602 Tear Tester using films of 1.4 mil thickness.
Data in Table IV show that properties of invention and control resin films are comparable. The film sample of invention resin 8 was slightly more hazy (opaque) than the control film.
|Cited Patent
|Filing date
|Publication date
|Oct 29, 1974
|Nov 22, 1977
|Halliburton Company
|Oxygen scavenging methods and additives
|Sep 13, 1982
|Jan 3, 1984
|Bayer Aktiengesellschaft
|Process for the preparation of polyarylene sulphides
|Jun 15, 1983
|Feb 26, 1985
|Phillips Petroleum Company
|Stabilizing melt crystallization temperature in arylene sulfide polymer heat treatment
|Feb 19, 1982
|Sep 1, 1983
|Bayer Ag
|Verfahren zur herstellung von polyarylensulfiden mit erhoehter thermischer und chemischer belastbarkeit
|Feb 19, 1982
|Sep 1, 1983
|Bayer Ag
|Process for the preparation of polyarylene sulphides
|Betz, Handbook of Industrial Water Conditioning, 1976, pp. 86 89.
|Betz, Handbook of Industrial Water Conditioning, 1976, pp. 86-89.
|Nickless, Inorganic Sulphur Chemistry, 1968, pp. 519 521.
|Nickless, Inorganic Sulphur Chemistry, 1968, pp. 519-521.
|Nordell, Water Treatment, 1961, pp. 104 105, 262.
|Nordell, Water Treatment, 1961, pp. 104-105, 262.
|Citing Patent
|Filing date
|Publication date
|Feb 13, 1989
|Aug 8, 1989
|Eastman Kodak Company
|Process for the preparation of copoly(arylene sulfide)
|Feb 13, 1989
|Aug 15, 1989
|Eastman Kodak Company
|Process for the preparation of copoly(arylene sulfide)
|Feb 13, 1989
|Aug 22, 1989
|Eastman Kodak Company
|Process for the preparation of copoly(arylene sulfide)
|Sep 8, 1989
|Jul 3, 1990
|Eastman Kodak Company
|Process for preparation of copoly(arylene sulfide)
|Jun 6, 1990
|Nov 12, 1991
|Eastman Kodak Company
|Copoly(phenylene sulfide)
|Feb 11, 1991
|Jun 2, 1992
|Bayer Aktiengesellschaft
|Process for the preparation of high molecular weight, optionally branched polyarylene sulphides
|Jun 5, 1996
|Jul 7, 1998
|Tonen Chemical Corporation
|Method of maufacturing a tubular extrusion molding product comprising a high molecular weight polyarylene sulfide
|Jan 4, 2008
|Nov 11, 2014
|Sk Chemicals Co., Ltd.
|Polyarylene sulfide resin with excellent luminosity and preparation method thereof
|Feb 13, 2014
|Feb 17, 2015
|Sk Chemicals Co., Ltd.
|Polyarylene sulfide resin with excellent luminosity and preparation method thereof
|Jan 4, 2008
|Jan 28, 2010
|Sk Chemicals. , Ltd.
|Polyarylene sulfide resin with excellent luminosity and preparation method thereof
|Dec 19, 2008
|Mar 17, 2011
|Changchun Hipolyking Co.,Ltd.
|Polythioetherimides and method for producing thereof
|Jun 22, 1989
|Nov 7, 1990
|Eastman Kodak Co
|Process for the preparation of copoly(arylene sulfide).
|Oct 31, 1988
|May 18, 1989
|Eastman Kodak Company
|Process for the preparation of copoly(arylene sulfide)
|U.S. Classification
|528/388, 524/609, 528/381, 524/419, 528/389
|International Classification
|Cooperative Classification
|European Classification
|Aug 31, 1984
Owner name: PHILLIPS PETROLEUM COMPANY A CORP OF DE
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:SENATORE, GUY;REEL/FRAME:004308/0635
Effective date: 19840830
|Sep 5, 1989
|Fee payment
Year of fee payment: 4
|Mar 22, 1994
|Maintenance fee reminder mailed
|Aug 14, 1994
|Lapse for failure to pay maintenance fees
|Oct 25, 1994
|Expired due to failure to pay maintenance fee
Effective date: 19940817


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Looking for LEO or Attorney that wants to teach
Discussion in 'Michigan Glockers' started by MiCPL, Jun 7, 2007.
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text:
Ex-Sofia District Attorney Elected Sofia City Prosecutor
Bulgaria's Supreme Judicial Council elected Hristo Dinev as the new Sofia City Prosecutor.
Dinev, a former Sofia District Attorney was chosen over his contender Boyko Atanasov by 16 to 4 votes, while 3 magistrates abstained, reports Dnevnik.
The Sofia City Prosecution conducts some of the most important investigations in the country, including high-level corruption, crimes committed by people with immunity, financial and tax frauds, and European fund frauds.
The Sofia City Prosecutor's position has been vacant since last April, when Nikolay Kokinov resigned from the post following the publication of leaked wiretaps of a conversation between him, the former Prime Minister Boyko Borisov, and the former Agriculture Minister Miroslav Naydenov.
Later, Kokinov was dismissed from the judiciary by the Supreme Council.
- » Bulgarian PM Slightly Lifts Veil On GERB's Presidential Candidate
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text:
Mabel M. Herbert, 95, Cloverdale, died Saturday at Summerfield Healthcare Center, Cloverdale.
Born in Shaddock, Okla., she was the daughter of Lora E. Buis and Mary Wolket (Hammond) Buis.
She as a 1930 graduate of Belle Union High School, and was a homemaker. She was a 50-year member and past Worthy Matron of Cloverdale O.E.S. 369. She was a member of Past Matrons Club and the Dine and Chat Club, and a member of Putnam County Farm Bureau, for which she was Past Women's District Director of nine counties for 15 years.
She married Glendon W. herbert on Nov. 9, 1935. He died April 11, 1996.
Surviving are a niece, Eloise Wieneke and husband Ron, Indianapolis; and nephew Percy Joe Hamblen and wife Dorothy Jean, Cloverdale.
She was preceded in death by her husband, parents, sisters Lorene DeWeese and Dana Hamblen, a niece and a nephew.
Services will be at 11 a.m. Wednesday at Whitaker Funeral Home, Cloverdale, with Rev. John Nees officiating.
Burial will be in Cloverdale Cemetery.
Visitation is 4-7:30 p.m. Tuesday.


text:
Click here to print the obituary below
Jane Daphne Rilance Keefer
73, of Ocean Isle Beach, died Friday, Jan. 25, 2013, at Lower Cape Fear Hospice & LifeCareCenter, Brunswick House, Bolivia. A memorial service will be at 11 a.m. Tuesday, Jan. 29, at St. James the Fisherman Episcopal Church. Brunswick Funeral Service, Shallotte.
Published in the Wilmington Star-News on Jan. 29, 2013


text:
Harvard Law School reflects on the legacy of Justice Scalia
On Feb. 24, a panel of Harvard Law School professors, all of whom had personal or professional connections to the late Justice Antonin Scalia, gathered to remember his life and work.
On Feb. 24, a panel of Harvard Law School professors, all of whom had personal or professional connections to the late Justice Antonin Scalia, gathered to remember his life and work.
Professor Charles Fried spoke at the Faculty Speaker Series at the Harvard Ed Portal in Allston last week, drawing from his HarvardX course "Contract Law: From Trust to Promise to Contract."
As the U.S. Supreme Court term has gotten underway, Harvard Law School faculty have submitted amicus briefs in upcoming cases involving congressional redistricting and affirmative action in college admissions.
"Choosing Not to Choose: Understanding the Value of Choice," by Professor Cass R. Sunstein '78 (Oxford). Choice, while a symbol of freedom, can also be a burden: If we had to choose all the time, asserts the author, we'd be overwhelmed. Indeed, Sunstein argues that in many instances, not choosing could benefit us—for example, if mortgages could be automatically refinanced when interest rates drop significantly.
In late May, four Harvard Law faculty members, Charles Fried, Michael Gregory, Kathryn Spier and David Wilkins, each shared a snapshot of innovative research with the HLS community, followed by discussion as part of the 2015 Harvard Law School Thinks Big lecture.
Several Harvard Law School faculty members delivered commencement addresses this graduation season, including Cass Sunstein, Charles Fried and Kenneth Feinberg.
Starting this month, Harvard Law Professor Charles Fried, who has been teaching the intricacies of the law to HLS students for nearly 50 years, is expanding his student body dramatically with the start of his online ContractsX course, a seven-week study of contracts for nonlawyers.
In a discussion moderated by Professor John Manning, five Harvard Law School professors, Tomiko Brown-Nagin, John Coates, Richard Fallon, Charles Fried and Intisar Rabb, assessed last year's Supreme Court decisions and shared their thoughts on those rulings.
SCOTUS Blog co-founder and Tom Goldstein, visiting lecturer at Harvard Law School, joined HLS Professor Charles Fried last week in discussing the Court's current docket at an event co-sponsored by the Harvard Law chapters of the American Constitution Society (ACS) and the Federalist Society.
To celebrate the 20th anniversary of his appointment to the United States Supreme Court, Associate Justice Stephen Breyer visited Harvard Law School on Oct. 1 for an informal chat with HLS Dean Martha Minow, and later took part in a panel discussion with several HLS professors who examined his tenure and some of his most notable opinions.


text: swimsuit coverups Archive Brand Highlight: Lavish by Sunsets dachary3 April, 2015No Comments The weather's getting warmer, which means swim season is right around the corner! (Or already here, in some parts of the country!) Since it's that time of year, this week's brand highlight focuses on one of our newest swim brands here at Big Girls Bras: Lavish by Sunsets! Sunsets has been one of our favorite Read More Brand Highlight: Tara Grinna Swimwear dachary Brand Highlight: Miraclesuit Swimwear dachary Brand Highlight: Aerin Rose dachary What's the Best Lingerie for Valentine's Day? dachary Just Released! 4 New Swim Systems Collections, Available Now! dachary What's the Best Bra for a New Year's Eve Party? dachary Aviana Plus Size Bras dachary Brand Highlight: Four Buttons dachary Brand Highlight: Leading Lady dachary Underwear 10%-75% Off! Starting at $5 dachary


text:
Justin Kan is Co-Founder and President of Justin.tv. Justin helped
popularize the term "lifecasting" in 2007 when he began broadcasting his
life 24/7 on Justin.tv. He parlayed that success into the next
iteration of Justin.tv: the largest live video community on the Web,
allowing anyone to broadcast from their computers and mobile phones.
Recently, Justin oversaw the launch of Socialcam, an Android and iPhone
app that makes it easy to share videos with friends.
Neil deGrasse Tyson and Al Gore on the future of our planet — and everything else
More "Innovators" »
My husband and I are business partners who just had our first child — here's how we make it work
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text:
Artillery variants
Group DescriptionGames that can be feature similar gameplay to the 1976 game, Artillery. These are games in which players must fire projectiles at one another while dealing with gravity, force of the shot and angle. Other common elements include wind resistance and obstacles.
Related groups
- Game Concepts: Artillery at Download Central
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Make an offer at www.thehorsebay.com For questions please contact Daylen Stevens @ 417-720-9465 Becca is an 8 yr old palomino Missouri Fox Trotter Mare…Make an Offer
Visit www.thehorsebay.com to make an offer Connie is a four Year old Registered Missouri Fox Trotter Palomino. She has been on many trail rides. Connie…Make an Offer
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