text:
|Publication number
|Publication type
|Application number
|Publication date
|Mar 28, 1995
|Filing date
|Dec 23, 1993
|Priority date
|Dec 23, 1993
|Fee status
|Also published as
|Publication number
|Gary C. Rex
|Original Assignee
|Union Carbide Chemicals & Plastics Technology Corporation
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (8), Referenced by (6), Classifications (9), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
The present invention relates to molding compositions and, more particularly, to improved ethylene-vinyl acetate copolymers useful as additives in the molding compositions.
Wet mix molding processes are processes which utilize an unthickened, i.e., liquid molding composition. The molding composition is typically introduced into a mold which contains a substrate such as, for example, a fiberglass mat, and is molded, e.g., by compression molding, to produce a desired article.
Typical wet mix molding processes include, for example, pultrusion molding, preform molding and wet mat molding. Pultrusion molding involves pulling a substrate material through a bath containing the molding composition and then through suitable dies or fixtures which shape and cure the molding composition. Examples of molded articles produced by pultrusion, include, for example, plastic pipes, ladder rails, rods, and support beams such as I-beams. In preform molding, the molding composition is applied to a preformed substrate, usually fiberglass, having the shape of the desired article and cured in a heated matched die mold. Examples of molded articles produced by the preform process include, for example, automobile fenders and hoods, chairs and helmets. In wet mat molding, the molding composition is applied to a sheet of fiberglass mat, placed in a mold of a comparatively simpler geometry than a preform mold and cured. Examples of molded articles produced by wet mat processes include, for example, sheet stock for paneling, table tops and other articles of simple geometry.
Often, pigments are added to molding compositions in order to obtain a desired color in the final molded article. Two problems which are frequently encountered with pigmented molded articles are hazing, which is a lack of color depth, and mottling, which is non-uniform pigmentation.
Powdered polyethylene has been used as a shrink control additive in molding compositions in order to minimize hazing and mottling. However, polyethylene is not soluble in styrene, which is a common monomer used in molding compositions. This can lead to the filtering of polyethylene particles in the substrate materials, e.g., fiberglass, and an uneven distribution of the polyethylene throughout the mold. Moreover, polyethylene does not provide a high degree of shrinkage resistance in a molded part. As a result, molded articles with internally pigmented wet mix formulations which contain polyethylene often exhibit poor surface quality and warpage.
Poly(vinyl acetate) has been known to be an excellent shrink control additive for thermoset molding compositions, but generally has not been used as an additive in internally pigmented molding compositions because hazing and mottling can be severe. In addition, certain ethylene-vinyl acetate copolymers having a broad range of monomer content, e.g., from about 10 to 98 wt. % vinyl acetate, have also been proposed as additives in molding compositions. However, such ethylene-vinyl acetate copolymers have failed to provide a desirable balance of solubility in styrene, good pigmentation qualities, and good shrinkage resistance.
Accordingly, additive compositions comprising ethylene-vinyl acetate copolymers are desired which can provide good pigmentation qualities and shrink resistance as well as solubility in styrene. Improved molding compositions employing the ethylene-vinyl acetate copolymers as additives are also desired.
In accordance with the present invention additive compositions for use in molding compositions are provided. The additive compositions comprise an olefinically unsaturated monomer, such as, an unsaturated aromatic compound having from about 6 to 16 carbon atoms per molecule, e.g., styrene, and an ethylene-vinyl acetate copolymer. Quite surprisingly, it has been found that ethylene-vinyl acetate copolymers having a low degree of crystallinity can provide enhanced performance with respect to hazing and mottling in molding compositions as compared to ethylene-vinyl acetate copolymers having a higher degree of crystallinity. In addition, the additive compositions of the present invention can provide a high degree of solubility in styrene and good shrinkage resistance.
The ethylene-vinyl acetate copolymers of the present invention are polymerized from ethylene and vinyl acetate monomers. The monomer concentration of vinyl acetate is typically from about 30 to 60 wt. %, preferably from about 35 to 50 wt. % more preferably, from about 40 to 50 wt. % and most preferably, from about 45 to 50 wt. % based on the weight of the ethylene-vinyl acetate copolymer, ethylene and vinyl acetate.
The ethylene-vinyl acetate copolymers have a low degree of crystallinity. In addition, the ethylene-vinyl acetate copolymers have a high degree of branching. Typically, the Branch Content will be greater than 10 and preferably greater than 15. As used herein, the term "Branch Content" means the moles of butyl branch per 1000 ethylene units. The Branch Content of an ethylene-vinyl acetate copolymer can be readily determined by integrating the area corresponding to butyl peaks from a carbon-13 nuclear magnetic resonance (C13 NMR) spectrum of the ethylene-vinyl acetate copolymer. Such techniques are known to those skilled in the art and described for example in Randall; JMS--Rev, Macrotool. Chem. & Phys, C29 (2+3), 303-317 (1989) and Wu; J, Polym. Sci.; Vol. 12; pp 901-911 (1974).
The molecular weight of the ethylene-vinyl acetate copolymers of the present invention typically ranges from about 5000 to 500,000 and preferably ranges from about 40,000 to 400,000 grams/gram mole. As used herein the term "molecular weight" means weight average molecular weight. Methods for determining the molecular weight of the ethylene-vinyl acetate copolymers of the present invention are known to those skilled in the art. One suitable method is low angle laser light scattering.
The melt index of the ethylene-vinyl acetate copolymers of the present invention can vary widely, e.g., from about 2 to 80, depending on various factors such as, for example, the vinyl acetate content, molecular weight and the crystallinity as well as perhaps other factors.
The ethylene-vinyl acetate copolymers of the present invention are commercially available. Alternatively, the details concerning the preparation of such copolymers are known to those skilled in the art.
One olefinically unsaturated monomer suitable for use in accordance with the present invention is selected from the group consisting of unsaturated aromatic compounds having from about 6 to 16 carbon atoms per molecule. Preferably, the unsaturated aromatic compounds have from about 8 to 12 carbon atoms per molecule. Specifically preferred unsaturated aromatic compounds include, for example, styrene, vinyl toluene, chlorostyrene, t-butylstyrene and divinylbenzene.
Another class of olefinically unsaturated monomer suitable for use in accordance with the present invention include acrylates and methacrylates having an acrylate functionality of from 1 to 5 acrylate groups per molecule. Typical acrylates and methacrylates include, for example, monomethyl methacrylate, trimethylol propane trimethacrylate, trimethylol propane triacrylate, pentaerythritol trimethacrylate, pentaerythritol acrylate, 1,6-hexane diol dimethacrylate, pentaerythritol tetraacrylate, pentaerythritol tetramethacrylate, ethoxylated or propoxylated derivatives thereof and mixtures thereof.
Still other olefinically unsaturated monomers suitable for use in accordance with the present invention include vinyl monomers, such as, for example, vinyl pyrrolidone and vinyl caprolactam, and acrylamides.
The olefinically unsaturated monomers of the present invention are commercially available. Alternatively, the details concerning the preparation of such monomers are known to those skilled in the art.
The additive compositions of the present invention comprise typically from about 20 to 50 wt. %, preferably from about 25 to 45 wt. and more preferably about 30 to 40 wt. % of the ethylene-vinyl acetate copolymer based on the weight of the additive composition. In addition, the additive compositions also comprise typically from about 50 to 80 wt. %, preferably from about 55 to 75 wt. % and more preferably about 60 to 70 wt. % of the olefinically unsaturated monomer. Mixtures of different olefinically unsaturated monomers and ethylene-vinyl acetate copolymers can also be employed within the above ranges.
The viscosity of the additive compositions of the present invention is typically from about 100 to 10,000 centipoise, preferably from about 200 to 7,000 centipoise, and more preferably from about 500 to 5,000 centipoise. As used herein, "viscosity" means the viscosity of a solution containing 30 wt. % of the ethylene-vinyl acetate copolymer in styrene measured at room temperature. Methods for measuring viscosity are known to those skilled in the art. Preferably, the additive compositions of the present invention have a viscosity which allows them to be readily pumpable and pourable.
The additive compositions of the present invention are particularly suitable for use for example, in molding compositions.
The molding compositions of the present invention comprise the above described additive compositions in addition to an unsaturated resin and an olefinically unsaturated monomer suitable for crosslinking with the unsaturated resin.
Typically, the unsaturated resin has an average molecular weight of at least 500, preferably from about 500 to 2000 grams per gram mole. The unsaturated resins can be any unsaturated resins, or mixtures thereof, known to those skilled in the art. Typical unsaturated resins include, for example, polyester resins, vinyl ester resins and acrylate resins.
The polyester resins are the reaction product of a polyol and at least one olefinically unsaturated dicarboxylic acid or anhydride, and may also include residues of saturated and/or aromatic dicarboxylic acids or anhydrides. Vinyl esters are the reaction products of saturated polyesters possessing secondary hydroxyl functionalities with vinyl group-containing acids or anhydrides such as acrylic acid or methacrylic acid. Typical acrylate resins include, for example, epoxy diacrylates, polyester diacrylates and polyurethane diacrylates. Unsaturated resins suitable for use in accordance with the present invention are described, for example, in the following references: B. Parkyn, F. Lamb, and B. V. Clifton, "Polyesters", Vol, II, London Iliffe Books, LTD, 1967; J. Bjorksten, H. Tovey, "Polyesters and Their Applications", Reinhold Publishing Corp., 1960; and U.S. Pat Nos. 5,166,291 and 4,942,001. Further details concerning the preparation of suitable unsaturated resins are known to those skilled in the art.
Preferably, the olefinically unsaturated monomer used in the molding composition is the same compound as the olefinically unsaturated monomer described above with respect to the additive compositions.
A typical molding composition in accordance with the present invention, will comprise from about 20 to 60 wt. % of the unsaturated resin, from about 5 to 60 wt. % of the olefinically unsaturated monomer and from about 1 to 40 wt. % of the ethylene-vinyl acetate copolymer of the present invention. The above percentages are based on the total weight of the unsaturated resin, the monomer, and the ethylene-vinyl acetate copolymer.
The molding compositions of the present invention may also contain one or more conventional additives such as, for example: an initiator, such as, for example, t-butyl perbenzoate, t-butyl peroctoate, and other peroxy esters, peroxy ketals and the like; fillers; mold release agents; rubbers and elastomers. Often, the molding compositions will also contain a pigment. The details concerning the selection and amounts of such ingredients are known to those skilled in the art.
The particular molding process used to mold articles using the compositions of the present invention is not critical. Preferably, the molding process is a wet mix molding process, e.g., pultrusion, wet mat molding, or preform molding, where the molding composition is applied to a substrate, e.g., fiberglass, and subjected to molding conditions to produce a desired molded article. Typical molding pressures range from about 100 to 1000 psia. Typical molding temperatures range from about 180� to 325� F. Further details concerning suitable molding processes are known to those skilled in the art.
Similarly, the particular molded articles produced with the compositions of the present invention are not critical. Typical articles, include for example, reinforced pipes, ladder rails, rods, support beams, such as I-beams, chairs, automobile fenders and hoods, helmets, battery cases, sheet stock for paneling, and the like.
The following examples are provided for illustrative purposes and are not intended to limit the scope of the claims which follow.
The following ingredients were used in the examples.
Elvax 40w--an ethylene-vinyl acetate copolymer containing 40 weight percent vinyl acetate available from DuPont, Wilmington, Del.
Elvax 150--an ethylene-vinyl acetate copolymer containing 33 percent vinyl acetate available from DuPont, Wilmington, Del.
Elvax 210--an ethylene-vinyl acetate copolymer containing 28 weight percent vinyl acetate available from DuPont, Wilmington, Del.
EY-902--an ethylene-vinyl acetate copolymer containing 41 weight percent vinyl acetate-available from Quantum Chemical, Cincinnati, Ohio.
EY-905--an ethylene-vinyl acetate copolymer containing 51 weight percent vinyl acetate available from Quantum Chemical, Cincinnati, Ohio.
Levapren 450--an ethylene-vinyl acetate copolymer containing 45 weight percent vinyl acetate available from Miles, Inc., Akron, Ohio.
Levapren 456--an ethylene-vinyl acetate copolymer containing 45 weight percent vinyl acetate available from Miles, Inc., Akron, Ohio.
Levapren 500HV--an ethylene-vinyl acetate copolymer containing 50 weight percent vinyl acetate available from Miles, Inc., Akron, Ohio.
Levapren 700 HV--an ethylene-vinyl acetate copolymer containing 70 weight percent vinyl acetate available from Miles, Inc., Akron, Ohio.
LP-40A--an acid-modified polyvinyl acetate polymer available from Union Carbide Corp., Danbury, Conn.
Microthene FN 510--a polyethylene polymer available from Quantum Chemical, Cincinnati, Ohio.
UE 647-35--an ethylene-vinyl acetate copolymer containing 28 weight percent vinyl acetate available from Quantum Chemical, Cincinnati, Ohio.
UE 654-35--an ethylene-vinyl acetate copolymer containing 33 weight percent vinyl acetate available from Quantum Chemical, Cincinnati, Ohio.
Polylite 31-602--orthophthalic-modified unsaturated polyester available from Reinhold Chemical, Research Triangle Park, N.C.
tBPB--tert-butyl perbenzoate available from Akzo Chemical, Chicago, Ill.
USP-245--2,5-dimethyl-2,5-bis-(2, ethyl hexoyl peroxy)hexane available from U.S. Peroxygen, Richmond Calif.
Modifier E--5 wt. % p-benzoquinone in diallyl phthalate available from Aristech Chemical, Pittsburgh, Pa.
CM-2015--35 wt. % carbon black pigment dispersion available from Plasticolors, Inc., Ashtabula, Ohio.
Zelec UN--phosphoric acid ester available from DuPont, Wilmington, Del.
Hubercarb W4--4 micron particle size calcium carbonate available from Huber Corp., St. Louis, Mo.
A known amount of styrene was introduced into a mixing vessel of a Cowles blade mixer. The mixer was then turned on to a revolution per minute (RPM) level which created a slight vortex in the styrene liquid. Hydroquinone was then added to a concentration of 150 ppm to insure the stability of the styrene. Then one-half of the desired amount of the ethylene-vinyl acetate copolymer in particulate form was gradually added in order to avoid clumping of the particles. The slurry was mixed for 30 minutes and then the remaining portion of the copolymer were added and as the viscosity of the solution increased the mixer RPM was increased to maintain a slight vortex. The total amount of copolymer added was sufficient to provide an ethylene-vinyl acetate copolymer concentration of 30 wt. %. The mixing was continued for a total mix time of one hour.
The viscosity of the solution was measured for the compositions in which the ethylene-vinyl acetate copolymer was completely dissolved.
The melt index of the copolymers were measured using a Tinius Olsen Extrusion Plastometer according to the method described in ASTM D1238, condition E.
Table 1 below sets forth the vinyl acetate content, melt index and viscosity for various polymer samples.
TABLE 1______________________________________PHYSICAL PROPERTIES OF VARIOUSETHYLENE-VINYL ACETATE COPOLYMERS Wt % Melt Index Viscosity Vinyl (grams per 30% styreneSample Polymer Acetate 10 min.) sol. (centipoise)______________________________________ 1-C Microthene 0 -- insoluble FN 510 2 Elvax 210 28 -- styrene swollen pellets 3 UE 647-35 28 45.1 very viscous mass, pellets visible 4 Elvax 150 33 40.8 styrene swollen pellets 5 UE 654-35 33 -- very viscous mass, pellets visible 6 Elvax 40w 40 49.8 5,650 7 EY-902 41 68.7 34,000 8 Levapren 450 45 3.7 19,200 9 Levapren 456 45 23.8 4,65010 EY-905 51 10.5 6,20011 Levapren 50 0.913 24,500 500 HV12 Levapren 70 1.78 10,740 700 HV13-C LP-40A 100 -- 5,000______________________________________
Table 1 demonstrates that Sample 1-c, which was a polyethylene homopolymer, was insoluble in styrene. In addition, Samples 2 through 5 were only partially soluble in the styrene. Samples 2 through 5 contained from 28 to 33 wt. % vinyl acetate. Samples 6 through 13c were soluble in the styrene. Samples 13c was a vinyl acetate homopolymer.
Molding compositions were prepared using the following procedure.
All the components, i.e., resins, activators, inhibitors, etc., were weighed individually into a 3.8 liter stainless steel beaker. The order of addition was; (1) polyester and thermoplastic solutions, (2) added styrene, if any, (3) initiators, (4) inhibitor, (5) pigment concentrate, (6) mold releases, and (7) calcium carbonate filler as shown in Table 2. However, after each addition of the above components, the mixture was high sheared for 1-2 minutes, except the filler addition was followed by high shearing for 3-4 minutes. The viscosity was measured using a model RVT Brookfield Synchro-Lectric Viscometer with Spindle#6 at 10 rpm.
Table 2 below sets forth the ingredients and concentrations thereof in the molding compositions. The concentrations are set forth in parts per 100 which is a common term in the molding industry. The concentration of the unsaturated resins a 60% solution of the resin in styrene was equal to 60 parts to provide a resin concentration of 36 parts. Similarly, the concentration of the ethylene-vinyl acetate copolymer as a 30% solution in styrene was 40 parts in order to provide a concentration of the copolymer equal to 12 parts. In the case, of sample 1c and 13c, styrene was added in order to provide the appropriate concentration. The concentrations of all of the other ingredients listed are in parts per hundred based upon the 100 parts of resin copolymer and styrene described above. All of the formulas were compounded to give a viscosity of about 50,000 centipoises by adjusting the level of Hubercarb W4.
TABLE 2__________________________________________________________________________Molding Compositions, Parts per hundredComponents 1 2 3 4 5 6 7 8 9__________________________________________________________________________Polylite 31-6021 60 60 60 60 60 60 60 60 60Levapren 500 HV2 40 -- -- -- -- -- -- -- --Levapren 700 HV2 -- 40 -- -- -- -- -- -- --Levapren 4502 -- -- 40 -- -- -- -- -- --Levapren 4562 -- -- -- 40 -- -- -- -- --Elvax 40w2 -- -- -- -- 40 -- -- -- --Microthene FN -- -- -- -- -- 12 -- -- --5103LP-40A4 -- -- -- -- -- -- 30 -- --styrene -- -- -- -- -- 11 10 -- --EY-9022 -- -- -- -- -- -- -- 40 --EY-9052 -- -- -- -- -- -- -- -- 40tBPB 1 1 1 1 1 1 1 1 1USP-245 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5Modifier E 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4CM-2015 10 10 10 10 10 10 10 10 10Zinc Stearate 3 3 3 3 3 3 3 3 3Zelec UN 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5Hubercarb W4 120 130 145 150 150 150 150 150 150__________________________________________________________________________ 1 60 weight percent solution in styrene 2 30 weight percent solution in styrene 3 particulate 4 40 weight percent solution in styrene
Flat panels for surface, shrink control and pigmentation evaluations were molded on a 200-ton Lawton press containing a matched dye set of 18 inch�18 inch chrome plated molds. The female cavity was installed in the bottom and the male portion was at the top. Both molds were hot oil heated and were controlled so that they could be operated at different temperatures. For the present molding, the top and bottom temperatures were 280�-290� F. 700 g samples of molding compound were employed with 2 plies of 1.5 oz./ft2 swirl fiberglass mat and 1 ply of 10 mil veil/side, and the molded part thickness was 0.100 inch. The molding pressure, which can be varied from 0 to 1000 psig, was run at 500 psig. The panels were laid on a fiat surface, weighted to keep them fiat, and allowed to cool overnight.
The molded panels were measured with a vernier caliper to an accuracy of 0.001 inch from corner to corner in all four directions to determine shrinkage, which is an average of the four readings. These panels contained 16% fiberglass by weight. These measurements were substituted into the equation below:
(b-a)/a=inch/inch shrinkage
where a=the sum of the lengths of the four sides of the mold, and b=the sum of the lengths of the four sides of the molded panels.
The shrink control measurement compares the perimeter of a cold panel to the perimeter of the cold mold. A reported positive number indicates an expansion and vice-versa for a reported negative number as compared to the cold mold. The units mil/inch indicate the amount of expansion (+) or contraction (-) in mils per inch of laminate (or panel perimeter). In accordance with the present invention the shrink control measurement is preferably less than �1.0 inches and most preferably less than 0.6 inches.
Surface quality measurements were performed on a Diffracto D-sight Audit Station-2 manufactured and sold by the Diffracto Co., Ltd. The surface waviness index (SWI) provided by this instrument is the standard deviation of the panel's surface with regard to long term waviness, as compared to the surface of a perfectly flat panel, whose long term waviness is zero. The smaller the SWI number, the smoother the panel.
The pigmentability of the molding compositions was determined by evaluating the panels qualitatively and quantitatively for haze and mottling, then assigning rating numbers. A mottling rating number of 1 means there was no pigment mottling present on the panel. A hazing rating of 1 means that hazing was minimal and the panel had a maximum depth of color. Ratings of 2, 3, 4 and 5 were considered to be good, fair, poor and very poor respectively. Hazing and mottling ratings of 2 or less are preferred. Laking was determined qualitatively. Laking can be described as the presence of regions on the surface of the panel which appear duller or less glossy than other regions.
The experimental molded panels were evaluated for surface quality, shrinkage control, laking, and pigmentability. Results are shown in Table 3 below.
TABLE 3__________________________________________________________________________PIGMENTATION AND SURFACE QUALITYMOLDED ARTICLEProperty1 2 3 4 5 6 7 8 9__________________________________________________________________________Mottling1 5 1 1 1 1 5 5 5Hazing2 5 2 2 2 1 5 3 3LakingNo No No No Yes Yes No No NoSurface30 26 50 45 23 230 23 53 44WavinessIndex- - - - - - - - -Shrink0.569 0.014 0.541 0.305 0.111 1.804 0.018 0.250 0.333Control,mil/in__________________________________________________________________________
Panels #2 and #7 show that copolymers with a vinyl acetate content at or above 70% gave very poor pigmentation and are not of acceptable commercial quality though shrink control and surface quality are excellent. On the other hand, the 100% polyethylene panel, #6, gave excellent pigmentation; however, the shrink control was very poor at -1.804 mils/inch as compared to the other panels. Quite Surprisingly, panels #1, #3, #4, and #5 gave good pigmentation coupled with the unique combination of excellent surface quality and shrink control. This defines preferred range of copolymers having a vinyl acetate content of about 40-50 wt. %, which gave good pigmentation and surface qualities. Because of the presence of laking on panel #5, it would appear that the most preferable range is 45-50% vinyl acetate.
Quite unexpectedly, panels #8 and #9 did not give good pigmentation performance though the additive used was in the preferred range of vinyl acetate content. It was suspected that there was a difference in polymer structure between the ethylene-vinyl acetate samples that gave an acceptable level of hazing and mottling and the ones that did not, i.e., EY-902 and 905.
The copolymer samples were submitted for C13 NMR analysis to ascertain whether or not there were any differences which may be attibutable to the performance differences.
Table 4 below shows the results of the NMR analysis.
TABLE 4______________________________________C13 NMR ANALYSIS Branchingethylene (E) centered triad Contentdistribution (moles B(EEE1 + Average per 1000 EEEV2 + VEV3 = 1) ethylene units) EEV + VE sequence B═butylPolymer EEE E4 VEV length branch______________________________________Levapren 0.677 0.260 0.063 5.2 15.2450Levapren 0.674 0.253 0.073 5.0 15.4456Levapren 0.632 0.297 0.070 4.6 19.9500 HVElvax 0.708 0.240 0.052 5.5 16.840WEY-902 0.712 0.241 0.047 6.0 10.4EY-905 0.648 0.305 0.047 5.0 9.3______________________________________ 1 EEE means the sequence ethylene, ethylene, ethylene. 2 EEV means the sequence ethylene, ethylene, vinyl acetate. 3 VEV means the sequence vinyl acetate, ethylene, vinyl acetate. 4 VEE means the sequence vinyl acetate, ethylene, ethylene.
The branching content for each of the copolymers, using Levapren 450 as an example, was calculated as follows:
A C-13 solution NMR spectrum was generated for the copolymer sample on a QE-300 NMR Spectrometer (manufactured originally by General Electric) using the following experimental Electric) using the following experimental parameters: single pulse gated decoupling sequence, 11 s recycle delay, 30 l pulse angle, 32K data points, and a spectral width of 210 ppm. The peaks in the NMR spectrum were assigned based on the paper by Wu, et. al., supra. The total area for all of the peaks from ethylene, methylenes of the butyl branch, and the methyl and methylene carbons of vinyl acetate occurring between about 20-45 ppm were integrated and set to 1000. The relative area of the peak from the CH3 of the butyl branch occurring at about 14 ppm was then measured to be 6.10. The total relative area of the group of peaks occurring between about 68-76 ppm (from the methine carbon of vinyl acetate) were measured to be 89.55. This area was then multiplied by 2 to account for the two carbons (methyl and methylene) in vinyl acetate (2�89.55=179.1) and subtracted from 1000 to yield the area from ethylene and methylenes of the butyl branch (1000-179.1=820.9). The area of the peak from the methyl of the butyl branch was then multiplied by 3 to account for the three methylene carbons in the butyl branch (3�6.10=18.3) and subtracted from 820.9 to yield the area from ethylene (820.9-18.3=802.6). The ethylene area was then divided by two since there are two carbons in each mole of ethylene (802.6/2=401.3). The moles of butyl branch per 1000 moles of ethylene was then calculated ((6.10/401.3)�1000=15.2).
The C13 NMR data shown in Table 4 reveals that the ethylene centered triad distribution and the average ethylene sequence length for this set of copolymers are essentially the same. The slight differences in the E-centered triad distribution may be traced to the ethylene-vinyl acetate concentrations. The higher the ethylene content, the higher the EEE triad value. However, there is a significant difference in the Branching Contents of the copolymers. The EY-902 and EY-905 have 10.4 and 9.3 butyl branches per 1000 moles of ethylene, respectively. The remaining copolymers have greater than 10, e.g., greater than or equal to 15.2, butyl branches per 1000 moles of ethylene. The fewer number of branches in the EY-902 and EY-905 are believed to allow for the development of crystalline ethylene blocks. This claim is substantiated by the detection of a crystalline melt region in the range of 117�-118� C. in these polymers of lower branch content by Differential Scanning Calorimetry (DSC). The data is presented below in Table 5.
TABLE 5__________________________________________________________________________DSC Analysis of Pure EVAc polymers in 40-50% VAc RangeMold. Glass Transition CrystallinityComp. Prod. Heat Flow, Temp., deg.Ref. # name Temp., deg. �C. W/g �C. Heat, J/g__________________________________________________________________________4 Levapren -17.9 0.205 47.3 4.1 4565 Elvax 40W -14.3 0.184 50.5 17.41 Levapren -8.9 0.193 42.7 6.8 5008 EY-902 -16.1 0.198 47.2, 117.9 13.5, 1.39 EY-905 -16.8 0.193 46.6, 117.7 3.8, 1.43 Levapren -15.6 0.219 45.7, 65.5 5.4, 0.3 450__________________________________________________________________________
The presence of crystalline blocks of ethylene is believed to contribute to the poorer pigmentation performance of the EY-902 and EY-905. Conversely, the absence of crystalline ethylene is believed to contribute to the superior performance of the more amorphous, more highly branched copolymers.
Although the present invention has been described with respect to specific aspects, those skilled in the art will recognize that other aspects are intended to be included within the scope of the claims which follow.
|Cited Patent
|Filing date
|Publication date
|Feb 5, 1970
|May 23, 1972
|Daicel Ltd
|Method of preparing high impact resistance resins by a bulk-suspension two stage process
|Feb 25, 1975
|Oct 26, 1976
|Bayer Aktiengesellschaft
|Polymerizable organic dispersion of unsaturated polyester vinyl monomer and EVA copolymers
|Feb 27, 1978
|Jun 3, 1980
|Bayer Aktiengesellschaft
|Production of graft polymers
|May 23, 1985
|Aug 12, 1986
|Bayer Aktiengesellschaft
|Adhesives with a high level of adhesion on plastics materials
|May 12, 1989
|Jan 7, 1992
|Minnesota Mining And Manufacturing Company
|Radiation-curable pressure-sensitive adhesive having improved adhesion to plasticized vinyl substrates
|Oct 17, 1964
|Jun 8, 1967
|Phoenix Gummiwerke Ag
|Herstellen von Formteilen aus Polyesterformmassen,die AEthylenpolymerisate enthalten
|Aug 12, 1974
|Feb 27, 1975
|Unilever Nv
|Title not available
|Citing Patent
|Filing date
|Publication date
|Sep 18, 1996
|Mar 24, 1998
|Cook Composites And Polymers
|Process for making a paintable polymer article
|Mar 14, 1996
|Apr 21, 1998
|Reichhold Chemicals, Inc.
|Shrink-controlled resin composition
|Mar 23, 1994
|May 4, 1999
|Cook Composites And Polymers Co.
|Thermosetting polyester composites prepared via vacuum-assisted technique with smooth surface appearance
|Feb 18, 2000
|Nov 9, 2004
|Union Carbide Chemicals & Plastics Technology Corporation
|Conductive molding compositions and articles molded therefrom
|Aug 31, 2009
|Oct 7, 2014
|Lg Hausys, Ltd.
|Sheet composition and sheet produced from same
|Aug 31, 2009
|Jun 30, 2011
|Sang-Deuk Choi
|Sheet composition and sheet produced from same
|U.S. Classification
|525/170, 525/302, 525/305
|International Classification
|Cooperative Classification
|European Classification
|Jan 6, 1995
Owner name: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORP
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:REX, GARY CHARLES;REEL/FRAME:007294/0334
Effective date: 19941214
|Sep 25, 1998
|Fee payment
Year of fee payment: 4
|Oct 16, 2002
|Maintenance fee reminder mailed
|Mar 28, 2003
|Lapse for failure to pay maintenance fees
|May 27, 2003
|Expired due to failure to pay maintenance fee
Effective date: 20030328


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text:
EC organises flash mob in Chennai to promote voting
Election Commission organized a flash mob in Chennai to promote voting in Tamil Nadu.
MCA moves SC for organising IPL matches in state as per original schedule
The Mumbai Cricket Association (MCA) and Maharashtra Cricket Associ...
'Digital India to be great theme for cellular service providers'
Gaurang Shah of Geojit BNP Paribas FS talks about how investors should appro...
PM Modi launches scheme to provide free LPG connections to poor
Prime Minister Narendra Modi launched a Rs 8,000 crore scheme to provide 5 crore free LPG connections to poor families as he attacked previous governments for just paying lip service to reducing poverty.
Here are the best NPS funds to invest in
Investing in NPS has become easy but it is not easy to track its performance. Before you invest, find out which pension fund has given the best returns.
Sagarmala project will provide employment to 1 crore people: Rajnath Singh
Home minister Rajnath Singh praised the Sagarmala Project, which was initiated by former prime minister Atal Bihari Vajpayee and is now encouraged by Prime Minister Narendra Modi. He added that he is glad that this project will give employment to 1 crore skilled as well as unskilled people.
Seminar on communal harmony organised in Rajouri
The Army's Ace of Spade division organised an all religion seminar in Jammu and Kashmir to maintain communal harmony in the state.
Credit funds can help generate higher returns
In the past one year, credit funds have returned about 8.91 per cent on average.
What to do when mutual funds underperform
To generate wealth, it is important that investors monitor their portfolio regularly and replace the underperformers with better schemes.
New alignment to provide facilities to pilgrims: Gadkari
Giving detail information about the preparation of the 'Char Dham Yatra', Union minister for road transport and highways Nitin Gadkari said last year an unfortunate incident took place in Badrinath and Kedarnath, killing many people.
Weekly funding meter: Who raised what this week?
Arun Natarajan, Founder, Venture Intelligence, shares information on top investments done this week.
Teams visiting India will be provided security: Rajnath
Regardless of contradictory statements given by Pakistan ministers on the security concern for their cricket players, Union home minister Rajnath Singh said that whichever team will come to play in India, they will be provided security.
'Maruti's Vitara Brezza provides value for money'
Watch the video and know more about the Maruti Suzuki's newly launched Vitara Brezza, its first serious offering in the compact SUV space.
Berkshire AGM 2016: Warren Buffett slams hedge funds
Warren Buffett, at Berkshire Hathaway annual meeting, pointed out that hedge funds are not really a good deal for investors.
SBI seeks to reduce cost of funds: B Sriram
In a interview with ET Now, Management of SBI shares views on consolidation road map for banks and SBI business strategy across the globe in the coming couple of years.
Dynamic bond funds are better than other funds
Expert Dhirender Kumar, CEO, Value Research talks about fixed income funds, what to choose and why.
Personal Finance Corner: Dhirendra Kumar talks about 'International Funds'
In the latest episode of 'Personal Finance Corner', Dhirendra Kumar, CEO, Value Research, talks about 'International Funds'.
Govt is committed to provide 'housing for all': President Mukherjee
Government is committed to provide 'housing for all', said President Pranab Mukherjeein Parliament.
Investor's Guide: All about 'HDFC Balanced Fund'
In the latest episode of Investor's Guide, see all about the HDFC Balanced Fund.
Fund starvation: Boon or Bane
2015 saw bizarre valuations and market going through bear-phase, in turn making market slow this year. Expert views on the start-up fear.
'Budget 2016-17 provides boost to electronics manufacturing sector'
Union minister of communications and IT Ravi Shankar Prasad praised Budget 2016-17. He said that with India emerging as a global hub of electronic manufacturing, the proposals relating to the sector were welcome.
Tax proposals to provide relief to small taxpayers through rebates: FM
Tax proposals to provide relief to small taxpayers through rebates, said finance minister.
DSPBR top 100 Equity: Fund review
Watch the review of DSPBR top 100 Equity fund by Dhirendra Kumar, CEO, Value Research.
Naturals to take over Yuvraj Singh-funded startup Vyomo
The Rs 100 crore that comes from the deal will be used to develop technology and expand aggressively to meet customer demand, Khare said.
'Will look at organic, inorganic plans to raise funds'
In an exclusive chat with ET Now, Ravi Uppal, MD and Group CEO JSPL, tells about the company's growth outlook and future plans.
Our focus is on to provide quality education: President Pranab Mukherjee
My government has taken measures to prove quality education, said President Pranab Mukherjee.
Pro-Afzal Guru slogans: FIR filed against DU professor who organised the event
FIR was filed against DU professor who organised the event where pro-Afzal Guru slogans were raised.
FIIs investing in mutual funds in India: Robert Parker
In a chat with ET Now, Robert Parker of Credit Suisse shares his view on the global market.
SBI Magnum Balanced Fund: A detailed report
Watch the detailed review of SBI Magnum Balanced Fund with Dhirendra Kumar, CEO, Value Research for better investment options.
'Will send Pathankot SIT to India, only if Pak team is provided adequate security for World T20'
Pakistan said that it will send Pathankot SIT to India only if their cricket team is provided adequate security for World T20.
Personal Finance Corner: Pharma funds with Dhirendra
In the latest episode of Personal Finance Corner, see Dhirendra Kumar, CEO, Value Research, talking about the pharma funds.
Govt can provide facilities to Kasab but not me: Adhir Ranjan
Congress leader Adhir Ranjan Chowdhury criticised the government for evicting him from one bungalow to shifting to another.
PM Modi blames previous govt for not providing facilities to poor
Prime Minister Narendra Modi said that his government's first priority is to eradicate poverty and make poor people self-reliant.
Panama Papers: Cameron admits he did have a stake in father's offshore investment fund
Dvid Cameron has admitted he did have a profitable stake in his father's offshore investment fund, but sold it for around £30,000 before he became Prime Minister.
Govt hospitals to provide free medical test from Feb 1: Kejriwal
Inaugurating the six-lane elevated road from Mangolpuri to Madhuban Chowk, Delhi chief minister Arvind Kejriwal said that all government hospitals in Delhi will provide free medicines and medical tests from February 1.
Bennett signs pact with edX to provide online courses
Bennett University, a Times Group initiative, and edX, the non-profit online learning platform founded by Harvard University and the Massachusetts Institute of Technology (MIT), signed a collaborative agreement to provide online courses to its students.
Smart Portfolio: Key holding of HDFC Top 200 Fund
Check the key holding of HDFC Top 200 Fund.
ISI provides financial, military support to LeT, JeM: Headley
Pakistan's intelligence agency ISI provides "financial, military and moral support" to terror outfits LeT, Jaish-e-Mohammad and Hizbul Mujahideen, Pakistan- born terrorist David Coleman Headley said today as he revealed more startling details about 26/11 attacks and his role it.
26/11 attacks: ISI provides financial, military support to Lashkar: Headley
Testifying before a Mumbai court for the second day on Tuesday, terrorist-turned-approver David Coleman Headley disclosed that "Pakistan's ISI provides financial support to Lashkar-e-Taiba(LeT). David Headley said that ISI provides financial, moral as well as military support to Lashkar," special public prosecutor Ujjwal Nikam told reporters after Headley's deposition.
Budget to provide Rs 1.10 lakh crore for Pay panel, OROP
Budget for the next fiscal needs to provide Rs 1.10 lakh crore for implementing the OROP and 7th Pay Commission award, besides a higher allocation for the farm sector, Finance Minister Arun Jaitley said.
View on mutual funds with Dhirendra Kumar
Dhirendra Kumar, CEO, Value Research share his views on investing in mutual funds.
Investor's guide: IDFC Premier Equity Fund
Dhirendra Kumar, CEO, Value Research, reviews the IDFC Premier Equity Fund.
'India to see fund flows once volatility settles'
In a chat with ET Now, Ravi Muthukrishnan, Co-HoR, ICICI Securities, said India will see fund flows once volatility will settle.
Lenders corner Gammon Infra over funds from Brookfield deal
Lenders consortium corner Gammon Infra over funds from Brookfield deal and move Bombay HC to protect deal riders.
Midcaps can give decent returns in five years: Harsha Upadhyaya, Kotak Mutual Fund
Midcaps can give decent returns in five years: Harsha Upadhyaya, Kotak Mutual Fund
Gold gains on fund inflows, oil slips after overnight rally
Gold extended gains on safe-haven bids and fund inflows, while crude oil prices slipped after logging first gain in four months.
Bond funds viable? Dhirendra Kumar's view
Indian bonds, shares and the rupee gained after a key government report on the economy was seen as calling for fiscal prudence and stable inflation, while also acknowledging risks to the growth outlook. Watch Dhirendra Kumar to know whether bond funds are viable option of investment in a volatile market.
Investor's Guide: Top funds for 2016
In this episode of Investor's guide, Dhirendra Kumar, CEO of Value Research suggests the top funds for investors to invest in the markets in this year.
Govt assures banks of fund infusion
Govt has assured that it will help the banks with fund infusion as per their requirement.


text:
Ready for the House
Being a guest poster on this blog, is it strange to write about another blog? I don't think so when it's Ricky Swallow's. The stuff you'll find at Ready for the House is like the ultimate thrift store experience – lamps, vases, t-shirts, records, pants and quilts (among many other things) all collected by the artist. It's a little like taking a peek through Swallow's studio or diary, it give's a new perspective on the work of this amazingly talented artist – clearly a legend.
- Kyle Weeks' photos portray the traditional and contemporary identity of the Himba people
- Ace & Tate commissions Hanna Putz to launch its Creative Fund
- Smart geometry-led identity for east London venue Brilliant Corners by Studio Remote
- Superb designs by Bureau Mirko Borsche for Tush magazine
- Artist Mona Hatoum electrifies the senses in her first retrospective at the Tate Modern
- Maya Fuhr's new project adds a slick, 80s-inspired editorial feel to a hospital setting
- Don't Hug Me I'm Scared - an exclusive interview with Duck, Red Guy and Yellow Guy
- Yoshinori Mizutani captures the colourful, rain soaked commuters of Tokyo
- Poem Baker photographs the Jûngølā drag clowns of London's Deptford
- Stack founder Steven Watson shares five of his top magazines
- Photography: New show at LCC shows young travelling communities of the 90s
- Hilarious and charming new Maynards Bassetts' Liquorice Allsorts ad by Jack Sachs


text:
Confederate Eyeglass
The Case:
A contributor in Terre Haute, Indiana has a tiny brass eyeglass that, when peered through, reveals an image of Confederate president Jefferson Davis.
February 1862: the Confederate South has seized the upper hand in the "War Between the States". In the North, opposition to President Lincoln grows as fears spread his armies will be defeated. Secret societies form in the Union states bordering the South, united in opposition to both Lincoln and the war. Those southern sympathizers operating north of the Mason Dixon line are surprisingly powerful and dangerous.
The owner believes miniature "Davis" eyeglass pieces were a wartime adornment of Confederate supporters in the North who used these objects to secretly identify themselves to one another.
History Detectives travels to New York and Virginia to examine the intricacies of microphotography and the truth behind a possible sympathizer "secret handshake."
Season 4, Episode 2
Elyse Luray Detective:
Wes Cowan Location:
Terre Haute, Indiana
Related Content
Related Links
- Also with Elyse Luray Bob Dylan Guitar Is this the guitar Bob Dylan played at the Newport Folk Festival in 1965?
- Related Investigation Leopold Medal What does this medal reveal about a top-secret American Military project during WWII?
- Also with Elyse Luray Cromwell Dixon Plane Fragment What could this faded scrap of fabric tell us about the first pilot to conquer the Continental Divide?
- Related Investigation Lincoln Oath Was this note penned by Abraham Lincoln?
- Also with Elyse Luray Liberty Bell Pin Was one of America's most iconic symbols melted down into a mere memento?
- Also in Civil War: 1850-1877 Civil War Sabotage? The steamship Sultana exploded one night in 1865, killing more than 1,800 people. Was the disaster a result of Civil War sabotage?
This is a place for opinions, comments, questions and discussion; a place where viewers of History Detectives can express their points of view and connect with others who value history. We ask that posters be polite and respectful of all opinions. History Detectives reserves the right to delete comments that don't conform to this conduct. We will not respond to every post, but will do our best to answer specific questions, or address an error.


text:
Fox has indefinitely delayed production on "The Maze Runner: The Death Cure" as star Dylan O'Brien needs more time to heal from his March 17 injuries after an on-set car accident. 199 palabras más
Etiquetas » Dylan O'Brien
Dylan O'Brien's accident *UPDATE*
Sunday Tyler Posey attended the MTV Movie Awards and told Variety about Dylan O'Brien's health status. He is doing well. He got released from the hospital in Vancouver and is now finally back home. 23 palabras más
Goodbye Arden <3
Unfortunately we have to say goodbye to Arden Cho's character Kira on Teen Wolf for now. Arden posted a video on her YouTube channel yesterday, in which she confirmed her departure from the TV show, thanked all her loyal fans and remembered the great memories she made on set. 13 palabras más
'Teen Wolf' Star Tyler Posey Gives An Update On Dylan O'Brien's Recovery
Friends and co-stars of Dylan O'Brien continue to express their support for the young actor after his frightening accident on the set of Maze Runner: The Death Cure… 189 palabras más
Tyler Posey Gives Dylan O'Brien Health Update After 'Maze Runner' Injury (VIDEO)
Dylan O'Brien is on the road to recovery.
Following an accident this March on the set of "The Maze Runner: The Death Cure" that left O'Brien suffering multiple injuries, the actor's "Teen Wolf" co-star Tyler Posey spoke to 257 palabras más


text:
Used Mazda Tribute for Sale in Springfield, MO
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|by Lisa
The Mazda Tribute GS class is the highest model, but with it the only luxury u really get is the piano finish on the interior everything else is very rough like. the seats are not fully covered in leather, but its still handy for the kids. I have run out of space already with two kids, but I am still happy with it. I love the height and the grey ...
2008 Mazda Tribute i Sport Used Cars in Macks Creek, MO 65786
Price: $4,495
Mileage: 159,063
Location: Macks Creek, MO 65786
2005 Mazda Tribute s Used Cars in Ozark, MO 65721
Price: $5,980
Mileage: 137,396
Location: Ozark, MO 65721
2004 Mazda Tribute ES V6 4WD Used Cars in Warsaw, MO 65355
Price: $4,595
Mileage: 161,688
Location: Warsaw, MO 65355
2002 Mazda Tribute LX V6 4WD Used Cars in Springfield, MO 65802
Price: $4,990
Mileage: 165,101
Location: Springfield, MO 65802
2001 Mazda Tribute ES V6 4WD Used Cars in Nixa, MO 65714
Price: $4,995
Mileage: 182,130
Location: Nixa, MO 65714
2004 Mazda Tribute ES V6 4WD Used Cars in Republic, MO 65738
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Location: Republic, MO 65738
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2008 Mazda Tribute i Sport Used Cars in Springdale, AR 72764
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Mileage: 69,767
Location: Springdale, AR 72764
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2008 Mazda Tribute i Sport Used Cars in Springfield, MO 65804
Price: $6,999
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text:
Location: Baraboo, WI
Tickets: 0
Sorry, tickets are no longer available for this event.
Baraboo Fairgrounds
Baraboo, WI
Starbucks annual shareholders meeting, Seattle, Wash.
AP Photo / Ted S. Warren
March 23, 2016 |
"Experience Hendrix," Fox Theatre, Atlanta, Ga.
Chris McKay / WireImage.com
February 27, 2016 |
If we have information that is incorrect on this itinerary, please
send us an email
© Copyright 2015 Pollstar. All Rights Reserved.
Use of information on this website is subject to
License Agreement.
Tickets for dates listed may not yet be on sale. Dates may change without notice.


text:
|-Harvard Bioscience
|-Intersections, Inc.
|-Telular Corp.
SeeThruEquity Launches First Free Institutional Equity Research Platform
www.seethruequity.com. SeeThruEquity strives to change the dynamic in the equity research space. SeeThruEquity is providing research on U.S. companies with market capitalizations below $1 billion, specifically on smallcap companies that have little or no coverage from the Wall Street analyst community. And, the company is offering unbiased institutional equity research reports free of charge to all. Its goal is to level the playing field for all investors.Amit Tandon, a co-founder and Chief Executive Officer of SeeThruEquity commented, "We believe that smallcap companies represent some of the most exciting investment opportunities in the U.S. capital markets, yet the vast majority of public companies do not have any research coverage whatsoever." "To this end, SeeThruEquity believes that providing free, totally unbiased, and truly independent research will heighten the level of visibility which currently only the largest of companies have. This mission, together with an ability to provide access to institutional equity research to the entire financial community, provides SeeThruEquity the foundation to deliver valuable insights and actionable investment ideas to the entire investment community," added Mr. Tandon. SeeThruEquity is initiating coverage of the following companies with its website launch:
Interested investors can visit
seethruequity.com, and download the reports free of charge.
SeeThruEquity plans to expand coverage strategically and aggressively over the next several months to include more underrepresented and uncovered smallcap companies.
Check Out Our Best Services for Investors
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text:
The students were from Avery County, North Carolina where they don't have commercial buffalo farms.
"We have one farm by us and he has about 13 buffalo on two acres but they just keep them to look at, more like a horse farm," said Brandon Cheek who was visiting the buffalo farm with his fellow members.
Despite chilly wet weather the group toured the fields where herds of buffalo stood grazing. They heard from owners John and Sheila English about the farm and the animals.
The farm also features a trading post and a concession stand. On this day nearly 100 FFA members tasted buffalo burgers, many for the first time.
"It's really different. But it's good," said Lesley Wooten who was eating a burger with friend Thomas Cole. The two said they would be heading back to downtown Indianapolis shorter and would attend more sessions at the convention.
At a table filled with the members talking in a soft southern drawl, there was laughter as one of the boys was heard to say, "I still like beef better."
In March of 1995 the English's purchased their first three buffalo, Cherokee, Dakota and Cheyenne (6 month-old heifers). In Aug. 1995 they added one-year old Chester (a bull). At the time they lived in Cloverdale.
The next year they added five more animals. By now, their 26 acres in Cloverdale were not large enough. So, in November 1996 they bought 102 acres in Bainbridge and moved their farm. One year later their first calf was born. Today, their herd has more than 80 animals and they plan to grow it to over 100 head.
More than 51,000 young people from across the country were taking part 80th National FFA Convention being held in downtown Indianapolis this week.
It is the nation's largest youth convention and Indianapolis' largest convention of any kind.
The National FFA Organization serves a half-million student members preparing for leadership and careers in the science, business and technology of agriculture with 7,300 local school-based chapters in all 50 states, Puerto Rico and the Virgin Islands. FFA seeks to make a positive difference in the lives of students by developing their potential for premier leadership, personal growth and career success through agricultural education.


text:
Scythe intros Slip Stream 120 mm Slim
Scythe Slip Stream 120 mm Slim
Hamburg, Germany. 17. June 2009: Scythe Europe is officially announcing the new Slip Stream 120 mm Slim case fan series which were first displayed at the exhibition CeBIT 2009 (Germany). Due to its thickness of only 12 mm, this new case fans are the best suited for HTPCs and PC cases with limited space where a normal case fan with 25 mm thickness cannot be mounted.
Slip Stream 120 mm Slim case fan is available in 800, 1,200, 1,600, and 2,000 rpm version, and it extends the popular Slip Stream 120 mm case fan family. The lowest model is spinning at 800rpm designed for silent users, and generates an airflow of 19.40 CFM (32 m³/h) at a noise level of 19.53 dBA. For high performance and use in combination with a fan controller, the highest model is the best suited. It is specified with 2,000 rpm and an airflow of 45.47 CFM (78 m³/h) at a noise level of 37.00 dBA. Weight of the fan is 98 g (2.71 oz), and the optimized sleeve bearing has the designated life span of 30,000 hours (MTBF).
MSRP for the Slip Stream 120 mm Slim is set to 8.25 EUR (excluding VAT) or 10.80 USD (excluding TAX).
Model Name:
Slip Stream 120 mm Slim Case Fan
Model No.:
SY1212SL12SL(800 rpm Version)
SY1212SL12L (1,200 rpm Version)
SY1212SL12M (1,600 rpm Version)
SY1212SL12H (2,000 rpm Version)
120 x 120 x 12 mm / 4.72 x 4.72 x 0.47 in
19.53 dBA / 19.40 CFM = 32 m³/h / DC12 V / 0.08 A (800 rpm Version)
21.71 dBA / 24.03 CFM = 41 m³/h / DC12 V / 0.17 A (1,200 rpm Version)
28.89 dBA / 38.05 CFM = 65 m³/h / DC12 V / 0.19 A (1,600 rpm Version)
37.00 dBA / 45.47 CFM = 78 m³/h / DC12 V / 0.25 A (2,000 rpm Version)
98 g / 2.71oz
3-pin (3-pin to 4pin adaptor included)
Bearing Type:
Sleeve Bearing
30,000 hours
8.25 EUR (excluding VAT)
10.80 USD (excluding TAX)
Slip Stream 120 mm Slim Product Page (English)
Slip Stream 120 mm Slim high resolution pictures
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text:
Holiday Inn Express Poughkeepsie, Poughkeepsie
- Free continental breakfast, free WiFi, and free parking
Main amenities
- 121 guestrooms
- Outdoor pool
- Free train station pick-up
- Fitness center
- 24-hour business center
- 24-hour front desk
- Coffee/tea in the lobby
- Air conditioning
- Daily housekeeping
- Computer station
- Front desk safe
- Laundry service
What's around
- Locust Grove (0.3 mi / 0.5 km)
- McCann Golf Course (1.5 mi / 2.4 km)
- Clinton House State Historic Site (2.1 mi / 3.4 km)
- Casperkill Golf Club (2.1 mi / 3.4 km)
- Springside National Historic Site (2.3 mi / 3.7 km)
Holiday Inn Express Poughkeepsie, Poughkeepsie
Hotel Info: 866-539-8117from $117
- Standard Room
- Room, 1 King Bed, Non Smoking
- Room, Non Smoking
- Room, 1 King Bed
- Room, Non Smoking
Also popular with travelers from the USA
At a glance
Key facts
Hotel size
- This hotel has 121 rooms
- This hotel is arranged over 4 floors
- Check-in time starts at 3 PM
- Check-out time is noon
Required at check in
- Credit card or cash deposit required
- Government-issued photo ID required
Travelling with others
- Pets not allowed
- Free WiFi in public areas
- Free WiFi in rooms
- Free train station pickup *
- Free self parking
Nearby Two Star Poughkeepsie hotels
In the hotel
- Free continental breakfast daily
- Coffee/tea in the lobby
- Outdoor pool
- Fitness facilities
- Golfing nearby
- 24-hour business center
- One meeting room
- Computer station
- 24-hour front desk
- Dry cleaning/laundry service
- Laundry facilities
- Free newspapers in lobby
- Number of buildings/towers - 1
- Safe-deposit box at front desk
- Accessible bathroom
- In-room accessibility
- Roll-in shower
In the room
- In-room climate control (air conditioning)
- Air conditioning
- Coffee/tea maker
- Iron/ironing board
- Hypo-allergenic bedding available
- Private bathroom
- Shower/tub combination
- Hair dryer
- Pay movies
- Premium TV channels
- Video-game console
- Desk
- Free newspaper
- Free WiFi
- Free local calls
- Refrigerator
- Microwave
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It's difficult not to be moved by the tragic events surround the recent bombing at the Boston Marathon earlier this week. But it is even more so moving for people that are from that city or region, or have spent any amount of time there.
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During episode 4 of Looking' for a Fight, UFC president Dana White, former champion Matt Serra and Nick "The Tooth" head to Minneapolis to scout a heavyweight prospect. read news >>
"Dana White: Lookin' for a Fight" is back with its fourth episode, which can now be watched in its entirety.Filed under: News, UFC, Videos read news >>
Urijah Faber is heading into a fight of his own, but he believes entertainer Justin Bieber could also be a fighter. read news >>
Michael Bisping is heading to Hollywood. Well, Hollywood by way of Toronto, anyway. The UFC middleweight has landed a role in the latest movie in the "xXx" franchise, "xXx: The Return of Xander Cage. read news >>
Dana White said we might get a women's title fight at UFC 200, and now we have one. Miesha Tate will defend her bantamweight title for the first time when she meets Amanda Nunes. Filed under: Feature read news >>
UFC Fight Night 86 is in the books. The results are as follows (via Bleacher Report's own Craig Amos): UFC Fight Night 86 Main Card Junior Dos Santos def. Ben Rothwell, unanimous decision (50-45, 50- read news >>
Dominick Cruz fought just one time from from late 2011 to early 2016, and he thinks that's a reason no one really cared about his division during that time.Filed under: Featured Videos, News, UFC, Vi read news >>
Undefeated Matt Lopez believes he's in the midst of an MMA growth spurt, and intends to show it in his RFA 37 bout with Eli Finn. read news >>
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With UFC President Dana White in attendance, Resurrection Fighting Alliance put on one of its most exciting shows ever as RFA 37 delivered six stunning finishes. read news >>


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HOUSTON Aug 20 The South Dakota Board of Minerals and Environment on Thursday granted Dallas-based Hyperion LLC a permit to build a 400,000-barrel-per-day (bpd) refinery, which would be the first new refinery built in the United States since 1976, the company said in a statement.
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On a ham shank... How many minutes per pound do I cook it?
kgb answers » Food & Drink » On a ham shank... How many minutes per pound do I cook it?
Wednesday, February 01 2012
Source: http://whatscookingamerica.net/Pork/Ham101.htm
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Representatives from 14 Hoanya Aboriginal communities sign a cooperation agreement during a cultural event on Sunday in Nantou County's Puli Township.Oct 03, 2013FULL STORY
Photo: Tung Chen-kuo, Taipei Times
This photo has been viewed 263 times.
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HN-BREW318 WallPops
Grass - Stickers XLItem # HN-BREW318
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We would love for you to join us in celebration of Pentecost on Sunday, May 15th at 10:30 a.m. This will be a service designed to celebrate the "birth" of the church as recorded in Acts 2. Together we will experience the presence of Jesus Christ!!
Welcome to Spirit of Grace Church. We are a Holy Spirit filled, Holy Spirit led, Christ-centered church. Our goal in every ministry is to worship the Lord Jesus Christ until we sense His presence in all aspects of life. My wife Tricia and I extend the warmest welcome, and pray that you will experience Jesus to be a very personal friend. Whether through this site, in our beautiful facility at 10110 Woodcrest Drive NW in Coon Rapids, MN, or by coming into contact with one of our members throughout the metro area, it is our prayer that you will feel the presence of the Lord in a unique way. May God richly bless you!!
Pastor Tim


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Wolfgang Puck's Rémoulade Sauce
Rosemary, sweet paprika, and garlic make this sauce a tasty burger topping for Wolfgang Puck's Mini Cheeseburgers.
Level: Moderate
Advertisement - Continue Reading Below
- 2 c. heavy cream
- 3 clove garlic
- 2 sprig fresh rosemary
- 1 tbsp. sweet paprika
- 2 tbsp. peanut oil
- ¾ c. brunoise (small dice) of red onion
- ½ c. brunoise (small dice) of red bell pepper
- ½ c. brunoise (small dice) of yellow bell pepper
- In a saucepan, combine the heavy cream, garlic, rosemary, and paprika. Reduce by half. Allow to cool to room temperature.
- In a sauté pan, heat the peanut oil. Sweat the onions, and red and yellow bell peppers until glossy. Transfer to a plate and allow to cool to room temperature.
- Once both mixtures have cooled to room temperature, combine in a bowl and mix thoroughly. Serve immediately.
This Trick For Homemade Fro Yo Will Kill It All Summer Long
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Global Conquest Paintball Event
This "big game" paintball event is probably the best of the season. There is a large diverse range of participants from beginners to advanced, old and young, and both... Learn more
- Location is shown only to members
- Join us!
Hosted by: Jim S.
Attend Faster Horses Music Festival
Faster Horeses is a Country Music Festival at the Michigan Motor speedway. Features 13 of countries biggest bands and many up and comers. Please visit http://... Learn more
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Hosted by: James B.
2016 Summer Beer Festival
Click here to buy tickets: http://www.mibeer.com/summer-festival ------------------------------------------------------------------------ 2016 Summer Beer Festival... Learn more
- Riverside Park - Ypsilanti
- Depot Town (Cross St. East of Huron), Ypsilanti, MI (map)
Hosted by: Tom G.
The Challenge Factory
Update[masked]: Unfortunately we are no closer to finding a location for this potentially awesome business now than we were five months ago. You would not believe how... Learn more
- Needs a location
- Coming soon
Hosted by: Jim S (Assistant Organizer)
Wallyball and Volleyball (dummy)
This event is for communication. Please join if you're interested in wallyball, indoor volleyball, grass volleyball or sand volleyball. The days are getting shorter so... Learn more
- Needs a location
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Hosted by: Dylan C. (Assistant Organizer)
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Yesterday · 10:00 AMPowered Paragliding--Super Low Bargained Group PriceI'm super excited to announce a relationship I'm forming with a brand new company called Michigan Powered Paragliding. I first discovered them though Groupon—as I have... Learn more
2 days ago · 8:00 PMFriday night Volleyball at PittsfieldPeople love their volleyball, so we're adding an extra day. This pick up is for intermediate and above players. You don't have to be a great player, but you must at... Learn more
3 days ago · 7:00 PMEuchre Night in YpsiCome early (by 7pm) to get a table. Informal euchre night, pair up and play competitive or casual euchre.Beginners welcome - someone is always willing to teach the game.... Learn more
4 days ago · 9:30 PMIndoor Volleyball at LakewoodIndoor pickup is back! This pick up is for any level players. You don't have to be a great player, but you must at least have a working knowledge of the game. It will... Learn more
4 days ago · 4:45 PMRun! Training for Tough MudderDear friends, All are welcome, not only Tough Mudders-in-training! I have started preparation for Michigan Tough Mudder 2016. AA Adventure Club Mudder Team looking new... Learn more
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Welcome to Mrs. Studer's 4th Grade Classroom Website
Click on a page tab above for more information.
School Start Time: 7:49 End Time: 2:49
Half Day Dismissal: 11:23
Upcoming Dates:
Book Reports Due May 2nd.
NWEA Spring Tests: May 2nd, 4th, & 6th.
M-STEP Spring Tests: May 9th, 10th, 12th, 13th, 17th, 18th.
Greenfield Village Field Trip: Wed, June 1st.
Field Day: Mon, Jun. 6th.
Beebe Street Park Field Trip: Tues, June 7th.
MOBYMAX SCHOOL CODE= mi3988
Scholastic Books Internet Ordering Code: GPLNR


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Age of Defense is back! Battle through 32 units, unlock 32 unique skills, use tree-based upgrade system and beat over 100 levels!
Lovely School Girl Makeover
Do you love this girl at your one glance? She waked up in the morning but have not make up herself. Pls help do this and makeover her. Don't forget...