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Nice to see that your time away from the boards has allowed you to gain perspective and let things go, atcchris. Its a terrible thing when we hold grudges and are unable to move forward. You have truly evolved.
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Nice to see that your time away from the boards has allowed you to gain perspective and let things go, atcchris. Its a terrible thing when we hold grudges and are unable to move forward. You have truly evolved.
Face it. You were wrong back then, and you're wrong now. Just because you're one of the admins doesn't give you a right to come in here and bad-mouth me.
I haven't said anything to you, and I won't, ever, so long as you leave me alone.
Ok fellas I'm going to put this one to rest so everyone will quit with the why did Kurt have to leave. I work with a guy who's brother is a chiropractor and knows the Rams medical staff very well and is friends with several of the players, he gets tickets from Holt on a regular basis. The reason Kurt was basically run out of town because of Brenda, she constantly spoke out against Martz and the FO in the media. Martz and his monster ego could'nt stand for anyone to question his ability so Kurt had to go baby. It had nothing to do with his faith, I went to the same church as Kurt and Brenda and always saw Ernie Conwell and Bruce there too so Ike just left and had Ernie not gotten hurt he may still be here. But I think it was AV that said it, if he had stayed here he would'nt be playing any more, he took some big hits when he was here and that takes it toll. If he had taken some of the hits Bulger has taken over the last few years he would be out of the game by now for sure.
I certainly don't feel like forgiving Martz for it, nor the Rams' front office. Leaders, Winners... they don't treat people like that. The Rams' brain trust is, therefore, incapable of leading and winning, consistently. We are in for more of the same over the years.
As for whether or not Warner would have survived here... who is to say? The Giants didn't provide very good protection for him. The Cardinals haven't either. Again, who is to say what would have happened if Warner had been allowed to lead the team in 2004? I say he'd have taken us to the Super Bowl, and there's no reason to believe we would have lost it. We had the team intact that year.. we just didn't have a QB who could operate under pressure. And what would have happened in 2005? Totally different draft.. totally different actions taken by the front office. Would they have been able to shore up the O-line? Winning begets winning, all things being equal... but.. again.. they front office doesn't have the character it takes to consistently win, so... you might be right about that too.
Warner never would have survived the last few years on the Rams. He was too worn down by the constant hits. At the time he was replaced by Bulger, Bulger was the better QB.
A QB can only take so many hits before he is done. Warner was able to stay clean for a couple of years and get healthy. Now he's in a good situation and he's doing well (though I doubt he'll win the MVP again solely on the basis of two games against the Niners and Dolphins).
Bulger may be wearing down now the way Warner was a few years ago. That does not mean that the Rams kept the wrong QB. Rather, it means that the Rams need to find a way to keep their QB on his feet, whoever that QB might be. Neither Warner in his prime, nor Bulger in his prime, or even Dan Marino in his prime, can read a defense and get rid of the ball quickly enough when there's no pocket to throw from.
Bottom line... this is a silly debate, just as it was years ago. The Rams chose Bulger over Warner due to their performances in the 2002 and 2003 seasons. In those two seasons, their stats were as follows:
9 games played, 182/285 (63.9), 1,796 yards, 4 TDs, 12 Ints., 14 fumbles (5 lost), QB Rating: 68.7
22 games played, 474/746 (63.5), 5,671 yards, 36 TDs, 28 Ints., 10 fumbles (8 lost), QB Rating: 87.2
So, you can say whatever you want about Marz, or Brenda, or Kurt's Bible reading in the locker room, but in the end, it was a football decision. Marc was playing better, was healthier and was, of course, younger.
Some will never let this go, but that's really all there is to it.
Your oversimplification isn't accurate. Bulger wasn't playing good football in 2003. Also, Warner was an injury-riddled 2002 removed from winning an MVP. I think the stat's you provided tell a much bigger picture. Warner led the Rams to two Super Bowls, won 2 MVP's, went to 2 Pro-Bowls, etc., etc., and he was determined to be expendable for less than 9 full games worth of statistics. Now, to top it all off, there was a fix for much of what ailed him(the fumbling) and the Rams had no interest in looking for it.Quote:
Some will never let this go, but that's really all there is to it.
But, like many of these conversations, it quickly gets lost that it's not so much "that" the Rams got rid of Warner, it's "how".
Let me ask you two questions:
1. How do you know that the glove cured the fumbling problems? Maybe it is simply that Warner is not getting hit as much as he did when he was in the Martz Min-Protect Offense.
2. How can you possibly assert that the Rams had "no interest" in looking for a solution to Warner's problems?
The way I see it, the Rams recognized that Warner's horrible 2002 campaign was due, to a large extent, to injuries. That is why, despite the fact that Bulger's passer rating in 2002 was above 100, Warner was named the starter for the season opener.
In that opener, he had an interception and 6 fumbles, and was not 100% healthy. Bulger was brought in and the rest is history.
Now, is it reasonable to assert that Warner should have had another chance in 2003 to reclaim his spot? Absolutely. Bulger's play was uneven during that season, and perhaps Warner should have been given another chance.
My point is this.... Assume that Warner was given another chance and, in fact, reclaimed his spot in 2003. I still don't think that Warner would be the Rams starter today. Warner was already battered at that point, and if he took all the hits that Bulger has taken from 2004 - today, I don't think he'd still be playing. You can only sustain so many hits (particularly when you've had concussions), and Warner needed the transition period as a backup to regain his health.
Its unfortunate that it played out this way. Ultimately, though, the life span of a QB in the Martz system (which, in the short run, might even make a star out of journeyman schlepper J.T. O'WhatsHisFace), is not very long.
Besides, I'm not seeing the statistical evidence of this glove argument. Since he left the Rams, Warner has appeared in 42 games, starting 37, and has fumbled 43 times (more than once per game). Just last year, he appeared in 14 games, starting 11, and fumbled 12 times. Where's this major improvement you are speaking of?
(In case you are wondering, over that same period, Bulger has played in/started 52 games and fumbled only 30 times)
This glove argument is a moving target.
Let me just ask you this... do you really think Warner would be playing, and playing well, today if he had been with the Rams over the past few seasons?


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subset: commoncrawl


text:
Get the Facts
IRIS: A Concern for People Starting HIV Therapy...system. Inflammation can be acute or chronic . Acute inflammation is when your body first responds by sending white blood cells to the damaged area. Your circulatory and immune systems assist in the process. For the most part, acute inflammation is normal and healthy. By contrast, chronic inflammation persists over time. In this case, your body shifts the types of cells that are present. This causes a situation where cells and...
Ask the Experts
Shingles and New MedicationHey, I'm a male, 25 years old, lead a healthy lifestyle, etc. I was diagnosed today with Shingles and given medication to fix that. My doctor told me that there is a possibility that this is an opportunistic infection as a result of a low CD4...
Response from Gerald Pierone, M.D.
AIDS Research and Treatment Center of the Treasure Coast...Shingles is a reactivation of a chronic Varicella-Zoster virus (VZV) infection. This virus becomes dormant after an initial presentation Read more »
shingles affect ELISA ?what's the chance that someone, who is HIV neg., would develop Shingles seven days after having risky sexual contact with a person who has primary HIV and is still in the window period ?
Response from Mark Holodniy, M.D., F.A.C.P., C.I.C.
Stanford University, School of Medicine...Shingles is a reactivation of old chicken pox virus infection, that we have all been exposed to as children. Many, many people without Read more »
shinglesDear Doc,Re: Shingles1). Could mild shingles strikes or reactivate during ARS period?? (Just curius) Is fever and mild shingles alike??2). What CD4 level or counts could shingles starts to reactivate?Thank you.
Response from Judith Feinberg, M.D.
University of Cincinnati, College of Medicine...Shingles look like chicken pox except that they are usually concentrated in one area of the body. Fever is clearly not shingles, and vice versa. It is conceivable that someone could have shingles during seroconversion. Read more »
aids come from what part of the bodywhat part of the body does aids come from
Response from Mark Holodniy, M.D., F.A.C.P., C.I.C.
Stanford University, School of Medicine...The HIV virus affects and can infect many parts of the body. The lymph glands and blood cells called t lymphocytes are most often infected Read more »
Herpes Zoster (Shingles)...neck, and scalp, in and around the ear, or at the tip of the nose. Shingles outbreaks are almost always on just one side of the body. Within a few days, a rash appears on the skin area related to the inflamed nerve. Small blisters form and fill... Read more »
Body Composition Tests...activity level, ethnicity, etc. are entered in a computer. While the person is lying down, electrodes are attached to various parts of the body and a small electric signal is circulated. This signal cannot be felt. BIA measures the resistance... Read more »
Lipodystrophy, Body Changes and HIV/AIDS...two categories: Body shape changes -- Includes fat loss (lipoatrophy) and fat gain(lipohypertrophy) or redistribution in particular areas of the body Metabolic complications -- Includes increases in fats and sugars in theblood HIV+... Read more »
Body Shape Changes (Lipodystrophy)...Lipo Be Treated? The Bottom Line What Is Lipodystrophy? Lipodystrophy, or "lipo" for short, is a collection of body shape changes in people taking antiretroviral medications (ARVs). "Lipo" refers to fat, and "dystrophy" means bad... Read more »
Connect With Others
shingle will happen twice or more?
Posted by JHIV130306, 3 Replies...weeks ago but it seems recovered,however,i today felt that i have the same symptom of developing shingle the other side of my body!!! will this happen this way? anyone had this situation before? please~~~~i'm so scare~~~what can i do? does... Read more »
Posted by Anonymous, 1 Reply...performed oral sex on me, less than 2 minutes, that was the only contact i had with him with out protection. no kiss, or touch were involved, but i did touch some of his shingles. i got a little concern and i finished the sexual act by... Read more »
Posted by Anonymous, 2 Replies...consistant (e.g. always a burning sensation or always a tingling sensation and generally in the same area - not in completely random parts of the body)? Read more »
Shingles = HIV?
Posted by grcboy30, 4 Replies...Hi there. I had chicken pox at 5 years old so can develop shingles. I haven't been to the doctor yet but have what I am pretty sure is shingles on the side of my chest (a pink rash which is itchy Read more »
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text:
So Long, Greyhound Bus Terminal. Hello, Neighborhood Development.
The Greyhound Bus Terminal is no more. And no one's shedding any tears over it.
The First Street NE site, as the Post describes, has been home to shootings, fights, and plenty of loitering. It's also an eyesore in a neighborhood that's got its fair share of transit-related eyesores.
The development of NoMa is moving swiftly along, [...]


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Hi WSUS Admins - Just a reminder - WSUS does support updating Vista clients, but to do so you must have the SP1 installed. As Vista gets out there among us, just wanted to post a reminder. Net: Need WSUS to support your new Vista clients ?? No problem but don't forget you need SP1!
Cheers- Bobbie
Talking of distributing Vista patches - any idea when the Vista Ultimate Extras will start to be available for distribution via WSUS?
I'm also waiting on ultimate extras and language packs to be available for distribution on WSUS. Pretty annoyed the Vista team blog had constantly said that they were available and are now being quiet about the subject.....
As I said somewhere else on this blog, we need an official document on how to setup Vista Home Premium clients without gpedit. I tried the registry method used with WSUS 2 on Windows 2000 clients but AU has changed to Auto Update, and the key names are slightly different on the client, I added the DWORD values and Strings anyways and tried the normal wuauclt /detectnow but netstat -a reveals that it is not contacting my WSUS server as specified by the registry key, it's talking to Microsoft.
I believe I am running WSUS3 SP1 (although I cannot see where to verify this) and have two Vista Business machines in my AD group that is pointed at my WSUS server for updates. One appears in the WSUS list, and is updated, one does not - but will manually update from the MS site.
How can I make the Vista unit and the WSUS server communicate?
I have unsuccessfully searched the web and Technet for answers.
WE have a WSUS server. However when the VISTA update client checks the server for updates it says it is updated even though updates are available and needed by VISTA.
I have the same issue as Hagashen. I have 14 or so Vista Updates WSUS is telling me is approved but not installed. They are the language packs, which I do not use, and Silverlight. I am using WSUS 3.0 SP1. I am seeing similar behavior on XP machines. WSUS tells me that there are 14 updates that are approved but thye do not get installed. They range from critical updates to security updates. The XP client thinks it has everything it needs from WSUS, but if I run a standard Microsoft Update, it tells me the same thing as WSUS, and shows me the same list of needed updates. I have given this a couple of days to work itself out, but no dice. Something is buggy somewhere, Anyone have a clue? Thanks,
Disregard my last posting. I found the Vista Language pack selection in the WSUS config, so no problem there. To overcome my XP problem, I simply performed a manual update to clear up any confusion. Now all systems show 100% updated.
Hello, I am working with WSUS 3.0 and I have a Vista Home Premium which I do not know how to cinfigure it to receive updates from WSUS!
Could you advice me?
Thanks in advance.
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|KABUSHKI KAISHA TOSHIBA Patent applications
|Patent application number
|WIRELESS COMMUNICATION APPARATUS AND METHOD - According to one embodiment, a wireless communication apparatus includes a calculator and a controller. The calculator multiplies a first weighting factor by a first data signal to be transmitted on a first channel, the first weighting factor is based on a second weighting factor multiplied by a second data signal received on the first channel. The controller controls a transmission to transmit to a destination device a control signal if the first data signal transmitted to the partner device exists, and no second data signal to be transmitted on the first channel exists in the device.
|ANTENNA DEVICE - There is provided an antenna device including: a finite ground plane; a feeding point; feed antenna elements arranged in a radial fashion around the feeding point at a height from the finite ground plane; a selector switch to connect a first end of a feed antenna element selected from the feed antenna elements to the feeding point; and parasitic elements arranged correspondingly to the feed antenna elements, in which a first end thereof is connected to the finite ground plane and a portion including a second end thereof is capacitively coupled with the feed antenna element corresponding thereto, wherein a first length of the parasitic element is approximately a quarter of a wavelength of a radio frequency to be used, and a length from the second end of the feed antenna element to the feeding point is shorter than the first length of the parasitic element.
|SIGNAL INTERPOLATION DEVICE AND PARALLEL A/D CONVERTING DEVICE - There is provided a signal interpolation device, including: a first amplifier to generate a first signal representing a difference between an input signal and a first reference voltage; a second amplifier to generate a second signal representing a difference between the input signal and a second reference voltage; a first output amplifier to amplify the first signal to generate a first output signal; a second output amplifier to amplify the second signal to generate a second output signal; a third output amplifier to amplify a sum of a first interpolation signal and the first signal to generate a third output signal, the first interpolation signal representing a voltage generated by dividing a difference between the first reference voltage and the second reference voltage by "2̂n"; and a fourth output amplifier to amplify a difference between the second signal and the first interpolation signal to generate a fourth output signal.
|WIRELESS COMMUNICATION APPARATUS AND WIRELESS COMMUNICATION METHOD - There is provided a wireless communication apparatus performing access control which starts transmission after a backoff time passes since an available state of a channel is detected through carrier sense, the backoff time being set based on a random value selected within a contention window width, including: a remaining time calculating unit calculating a remaining time untill a request delay time time-outs after data is generated and a setting unit setting the contention window width according to the remaining time calculated by the remaining time calculating unit.


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Problem with D70 writing to CF card (odd behaviour)
Started Sep 1, 2006 | Discussions thread
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Azrifel OP
Senior Member • Posts: 1,027
Thanks for your answer.
I can accept that the card might not have been inserted well enough, but it is still strange that the file numbering became a mess and the camera created a new directory.
I hope it never happens again.
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Dana Campbell added the English common name "Bush sulfur" to "Pyrisitia dina (Poey, 1832)".
Dana Campbell set "Image of Eurema dina" as an exemplar on "Pyrisitia dina (Poey, 1832)".
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Beyond the Rim by SmattilaWatch
©2006-2016 Smattila
One of my older works..dunno why I deleted it earlier..hmm well anyway here it is
Beautiful work~ <3
What can I say,great like the other ones.
I really like the bottom big planet, good job !
Very cool nebula!!
Nice work
Nice work
Still looks great!
Amazing. And:
"Beautiful, as usual."
"Beautiful, as usual."
Beautiful, as usual.
I DARE you to make something repulsive!!
Consider this a challenge.
I DARE you to make something repulsive!!
Consider this a challenge.
it's on your msn right?
i was listening to astral projection while getting this pic ) .
It looks Amazing!
I have to wonder what exactly this "Rim" is.
Hmmmm it's a bit difficult to explain what I had in my mind..its bee so long since I made this and I didn't write up the story at that time... The "rim" is a border of space that separates the known and the uknown..
Planeetat nyt menee ja noi asteroidit mut mites toi nebulan rakeisuus ? vai onks se ihan joku NASA:n kuva ? tosin se luo kyl ihan oman tunnelmansa kuvalle..
Ei oo NASA kuva..vaan rakeisuus on ihan tarkotuksellista..yritin tiettyy tunnelmaa saada tähän.. tää on suht vanha kuva jo ja ei ollu PSD fileä tallessa joten en lähteny muutteleen muutaku värejä
it looks so real ^^. nice planets
*GASP* It's so pretty.... Must.... resist... heading for... light.....
Ow! Screens can hurt!
Ow! Screens can hurt!


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She has a 2004 Mercedes C230 with 65 K miles. In the past two years, in addition to the scheduled service, we have put $ 5,000 into it for a bad alternator, broken CD changer and now a leaky sunroof. We are waiting for a new sunroof cassette to be installed, and the sunroof problem alone is going to cost $ 3 K, for the four repair attempts over the past year. For the two most recent repairs, we are paying only for parts, since they are doing the labor under warranty. But a new cassette and sunroof motor are costing $ 2 K in parts alone. We take it to an independent Benz shop, but the parts and labor still add up. In contrast, my 2005 Ford Escape with 66 K miles has required no service other than the scheduled.
I now have her agreeing with the concept of fixing it and getting rid of it before the next expensive gremlin plagues us. The trade in value is about $ 8500 and she owes about $ 4,000 on it.
So she has a long list of amenities that she is looking for, and we are beginning to do some car shopping. Of note, if it does not have heated seats, it is off the list. . She probably wants a new vehicle for the warranty.
So far, we have the 2011 Hyundai Sonata, Kia Optima and Ford Fusion on the list. We went to see and drive the Fusion and the Sonata yesterday. The Fusion was a pretty bland generic sedan, we thought. But the Sonata was pretty darn impressive inside and out. Quiet as a church, smooth ride, great acceleration and impressive MPG. We can probably get it for the mid-$20's with all the stuff she wants going through the Costco Auto Program.
I still want to go look at the Optima based upon how well the Kia Soul has worked out for me. Any other thoughts on a mid-size sedan that we should be looking at? For the reliability factor, I am thinking Asian or Ford. She has pretty much ruled out the Camry and Accord. I am ruling out European models like the Benz, Audi or VW. I know too many people who are trapped in the cycle of expensive maintenance and repairs on the Europeans.


text:
Best-selling erotica author Zane, a.k.a. G-Spot, has helped define sexual lib for the Girls Gone Wild generation. This highly anticipated sex guide gives the kind of getting-busy advice that could earn you a role in her fiction: It's frank, raunchy, and heavy on the attitude. The warning in the first few pages says it all: "If you have sexual hang-ups whatsoever, please put my book down and slowly walk away from it. It is too damn hot for your ass."
Erotica author gives tips.
By Zane; Atria; $25


text:
Everything you see on HGTV is wrong and dangerous.
Money may buy some people happiness, but I'm not one of them. To all those who love cash and luxury: you can enjoy eating lobster tails on your yacht. I'll be here – enjoying the finer, cheaper things in life.
Just because you can buy something, it doesn't mean you can "afford" it.
1. Eat a large meal BEFORE going shopping.
7. A savings account with something in it.
There are few things more truly upsetting than taking perfectly good leftovers and either tossing them out directly or letting them linger in the back of your refrigerator until they're no longer edible.


text:
CARACAS, Venezuela — Ronald Alvarez was driving in chaotic, bumper-to-bumper traffic when he heard a throaty buzz and insistent "Beep! Beep! Beep!"
Motorcyclists in Venezuela's capital are known for zipping between lanes and taking off side mirrors, either inadvertently or with malicious intent. So Alvarez swerved to the side to open up space for this one, rear-ending a car that had slammed on its brakes in the process.
"It is the worst plague there is right now in Caracas," Alvarez said about the proliferation of motorcycles.
Alvarez's complaint is echoed by many residents of this capital of narrow streets, where the transportation infrastructure has been neglected for decades, leading to traffic congestion so bad that it is almost always best navigated on motorcycle. A two-hour car drive to work can take less than half an hour on the back of a bike.
The two-wheel invasion began about a decade ago with the arrival of Chinese-made motorcycles that sell for just a few hundred dollars and has since exploded, causing Caracas residents to rant at the locust-like swarms of motorcycles that blow through red lights and ignore one-way traffic signs with impunity, becoming a serious public health and safety issue.
Gangs of armed, two-wheeled political shock troops backed by the government terrorize voters and break up opposition protests. Motorcycles are also favored by robbers and hit men, and are involved in 90 percent of violent crimes in this murderous city, according to an estimate by a prominent criminologist.
In 2011 the government passed a law that was supposed to help crack down on the lawlessness, but nearly two years later there's practically zero enforcement and people say the problem is getting worse.
"For me, the problem of motorcyclists has become a matter of public health," said Fermin Marmol Garcia, the criminologist who reached the 90 percent figure on motorcycles' involvement in violent crime by analyzing data from the government and NGOs. "It's no longer just a crime issue, a violence issue. It's a matter of public health."
Venezuela is the world's third-worst country for motor vehicle-related deaths with 37.2 per 100,000 inhabitants, according to a World Health Organization global road safety study published this year. Only the Dominican Republic and Thailand scored worse.
It's not clear how many of those involved motorcycles.


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I am sure this hotel is lovely in the ski season ( as the lift is right next door) but in summer it is just as charming. Situated in a small village, with an exquisite church to visit, it offers lovely bedrooms, great food and a view across the mountains that made our hearts sing. And then there is the... More
Top-rated Attractions Nearby
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We stayed in the apartment for 8 days and liked everything about it but the noise from the street - all the time, but it is typical for Italy. The rest was great - location, cleanness, service. A super market is very close too.
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Florence, Maude, Mabel or Iris?(61 Posts)
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- 78% of Canadians would rather spend Valentine's Day with their significant other. With 14% choosing to stay in with their pet and only 8% choosing to snuggle with a celebrity crush.
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- 50% of Canadians are hoping for a romantic dinner out, followed by 30% wanting a quiet night in. Overall, Canadians chose special one-on-one time with their partner over an action-packed adventure like sporting.
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Originally posted by bad man incorporated
Punching in the face, isn't really a "tool". As it looked like that also could have been the attempt here.
Originally posted by OrganizedChaos
Reply to defcon5
Don't get me wrong, I'm not against all officers. Some of them just get caught up in the excitement and lose control. Others are just looking for an opportunity to pound someone.
On a side note, I wonder what the sign said?


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First-principles study on transition metal-doped anatase TiO2
© Wang et al.; licensee Springer. 2014
Received: 1 November 2013
Accepted: 5 December 2013
Published: 28 January 2014
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© Wang et al.; licensee Springer. 2014
Received: 1 November 2013
Accepted: 5 December 2013
Published: 28 January 2014
The electronic structures, formation energies, and band edge positions of anatase TiO2 doped with transition metals have been analyzed by ab initio band calculations based on the density functional theory with the planewave ultrasoft pseudopotential method. The model structures of transition metal-doped TiO2 were constructed by using the 24-atom 2 × 1 × 1 supercell of anatase TiO2 with one Ti atom replaced by a transition metal atom. The results indicate that most transition metal doping can narrow the band gap of TiO2, lead to the improvement in the photoreactivity of TiO2, and simultaneously maintain strong redox potential. Under O-rich growth condition, the preparation of Co-, Cr-, and Ni-doped TiO2 becomes relatively easy in the experiment due to their negative impurity formation energies, which suggests that these doping systems are easy to obtain and with good stability. The theoretical calculations could provide meaningful guides to develop more active photocatalysts with visible light response.
The discovery of water photolysis on a TiO2 electrode by Fujishima and Honda in 1972 [1] has been recognized as a landmark event. Since then, TiO2 has attracted extensive attention as an ideal photocatalytic material because of its excellent properties such as high activity, good stability, nontoxicity and low cost. Thus, it has been widely used in the fields of renewable energy and ecological environmental protection [2–4]. However, as a wide band gap oxide semiconductor (Eg = 3.23 eV), anatase TiO2 can only show photocatalytic activity under UV light irradiation (λ < 387.5 nm) that accounts for only a small portion of solar energy (approximately 5%), in contrast to visible light for a major part of solar energy (approximately 45%). Therefore, how to effectively utilize sunlight is the most challenging subject for the extensive application of TiO2 as a photocatalyst. In the past decades, many efforts have been devoted to extending the spectral response of TiO2 to visible light, including energy band modulation by doping with elements [5–11], the construction of heterojunctions by combining TiO2 with metals such as Pt or Pd [12, 13] and other semiconductors (such as MnO2[14], RuO2[15], and WO3[16]), and the addition of quantum dots [17] or dyes [18] on the surface of TiO2 for better light sensitization.
Because of the unique d electronic configuration and spectral characteristics of transition metals, transition metal doping is one of the most effective approaches to extend the absorption edge of TiO2 to visible light region, which either inserts a new band into the original band gap or modifies the conduction band (CB) or valence band (VB), improving the photocatalytic activity of TiO2 to some degree [19–24]. For example, Umebayashi et al. [5] showed that the localized energy level due to Co doping was sufficiently low to lie at the top of the valence band, while the dopants such as V, Mn, Fe, Cr, and Ni produced the mid-gap states. Yu et al. [21] reported that the density functional theory (DFT) calculation further confirmed the red shift of absorption edges and the narrowing of the band gap of Fe-TiO2 nanorods. Hou et al. [22] showed that new occupied bands were found in the band gap of Ag-doped anatase TiO2. The formation of these new bands results from the hybridization of Ag 4d and Ti 3d states, and they were supposed to contribute to visible light absorption. Guo and Du [23] showed that Cu could lead to the enhancement of d states near the uppermost part of the valence band of TiO2 and the Ag or Au doping caused some new electronic states in the band gap.
Even though the effects of the transition metal-doped TiO2 have been investigated frequently, it remains difficult to make direct comparisons and draw conclusions due to the various experimental conditions and different methods for sample preparation and photoreactivity testing. At the same time, because of the lack of the detailed information about the effects of metal doping on crystal structures and electronic structures, there is still much dispute about these issues. In comparison with the experimental investigation, the theoretical analysis by computer simulation can be a proper method to clarify the effects of transition metal doping in detail.
In order to systematically investigate the influence of transition metal doping into anatase TiO2, we adopted the planewave ultrasoft pseudopotential method within the framework of density functional theory (DFT) to calculate the electronic structures, formation energies, and band edge positions of supercells, in which a Ti atom was substituted by a transition metal atom. Considering the accessibility of the doping metals, the 3d transition metal atoms (M = V, Cr, Mn, Fe, Co, Ni, Cu, and Zn) and the 4d transition metal atoms (M = Y, Zr, Nb, Mo, and Ag) were studied in the present work. Moreover, the present calculation results were compared with the experimental results reported in the literatures. The conclusions are important to understand the reactive mechanism and optimize the performance of TiO2 photocatalysts that are active under visible light irradiation.
DFT calculations [25] were carried out using Cambridge Sequential Total Energy Package (CASTEP, Accelrys Company, San Diego, CA, USA) [26, 27], with the planewave ultrasoft pseudopotential approach. Our geometry optimizations employed a local density approximation (LDA) exchange-correlation functional, while the Perdew-Burke-Ernzerh (PBE) of the generalized gradient approximation (GGA) was chosen to perform calculations to obtain the electronic structures and accurate formation energies. In these calculations, the cutoff energy of the planewave basis set was 380 eV. The Monkhorst-Pack scheme k-point grid sampling was set as 5 × 5 × 2 for the irreducible Brillouin zone. The Pulay density mixing method was used in the computations of self-consistent field, and the self-consistent accuracy was set to the degree that every atomic energy converges to 2.0 × 10-6 eV. The force on every atom was smaller than 0.05 eV/nm. We calculated the total energy and electronic structures in the supercell under these conditions.
Optimized structural parameters for anatase TiO 2 compared with experimental and previous theoretical results
This work
Deviation (%)
Deviation (%)
For TiO2 doped with V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, and Ag, considering the underestimation of the calculations, the band gaps of the transition metal-doped anatase TiO2 are corrected by scissors operator. Scissors operator is used for a purpose as correction to the band gap, which has a clear separation between the CB and VB. For these calculations, the scissors operator is set at 1.02 eV, accounting for the difference between the experimental band gap (3.23 eV) and the calculated band gap (2.21 eV) for pure anatase TiO2. Then, the band gaps of TiO2 doped with V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, and Ag, are determined as 2.84, 3.26, 3.35, 2.86, 2.80, 3.25, 3.20, 2.69, 3.15, 3.25, 3.33, 2.96, and 3.20 eV, respectively. It should be noted that the band gap of transition metal-doped TiO2 is not related to the band gap between the Ti t2g (d xy , d xz , d yz ) and eg (, ) bands, but to the energy separation between the O 2p and the Ti t2g bands of TiO2 that is modified by doping atoms.
In comparison with pure TiO2, the calculation results of the electronic structures of Ti7MO16 can be classified into six groups according to the position of the IELs in Figures 3 and 4: (1) Ti7VO16 and Ti7MoO16; (2) Ti7CrO16; (3) Ti7MnO16, Ti7FeO16, Ti7CoO16, Ti7NiO16, and Ti7AgO16; (4) Ti7CuO16; (5) Ti7ZnO16 and Ti7YO16; and (6) Ti7ZrO16 and Ti7NbO16.
Ti7VO16 and Ti7MoO16. The IELs are located at the bottom of the CB and mixed with the Ti 3d states to form a new CBM, which leads to an obvious band gap narrowing. The position of the IELs might result in a red shift, which gives an explanation of the experimental optical absorption spectra of V-doped TiO2[30]. The positions of the IELs in the Mo-doped system in Figure 4 are similar to those in V-doped TiO2, which may also result in red shift of absorption spectra in experiments.
Ti7CrO16. The IELs are located below the CBM with a small distance. For Cr-doped TiO2, the IELs act as a shallow donor, and their occurrence is mainly due to the Cr 3d states that lie at the bottom of CB as shown in Figure 3. As the EF crosses it, it is partially filled with electrons at the ground state. In this case, the optical transitions are expected to be two transitions. One is the acceptor transition from the VBM to the IELs. The other is a donor transition from the IELs into the CBM. Meanwhile, VB holes and CB electrons appear. The former contributes to the anodic photocurrent, and the latter contributes to the cathodic photocurrent under visible light. Then, the Cr-doped system can serve as a remarkably better photocatalyst.
Ti7MnO16, Ti7FeO16, Ti7CoO16, Ti7NiO16, and Ti7AgO16. The IELs occur in the middle of the band gap, namely the intermediate level. They may reduce the energy required for electron transition, lower the threshold of photoexcitation, and thus expand the optical absorption spectrum without reducing the energy of electrons or holes. The electrons in the VB can be excited to the IELs and then subsequently excited to the CB by the visible light irradiation. So, IELs are beneficial for extending the sensitive light wavelength. The result gives a good explanation of the red shift [31–34]. However, for these kinds of IELs, high impurity doping concentration might form a recombination center for photoexcited electron–hole pairs and results in a decrease in the quantum yield for the photocatalytic reactions [21]. Therefore, we must control the doping concentration to avoid them to act as the recombination center of photo-generated electrons and holes.
Ti7CuO16. The IELs are located above the VB and partially overlap with the VBM. These kinds of IELs could act as trap centers for photoexcited holes, which can also reduce the recombination rate of charge carriers [10]. The holes generated in the VB produce an anodic photocurrent. Because the Cu t2g level is close to the VB, the holes easily overlap in highly impure media [5].
Ti7ZnO16 and Ti7YO16. The IELs are located at the top of the VB and completely mixed with the O 2p states to form a new VBM (seen in Figures 3, 4, and 5). The band gaps of Zn- and Y-doped anatase TiO2 are narrowed to 2.69 and 3.15 eV, respectively, and smaller than that of pure TiO2, which is consistent with the experimental data on the red shift of the absorption edge [35, 36].
Ti7ZrO16, Ti7NbO16. The IELs are not situated at band gap. The electronic structure of Zr-doped TiO2 exhibits similar to that of pure TiO2. Therefore, we can infer that the t2g level due to Zr does not contribute to the photo-response. Similarly, the band gap of Nb-doped anatase TiO2 is larger than that of undoped TiO2 by 0.09 eV, which may result in a blue shift of the absorption edge.
where is the energy of the most stable oxide for doping atoms at room temperature.
Impurity formation energies of 3 d and 4 d transition metal-doped TiO 2 supercells under O-rich condition
Metal doping system
Transition metal-doped TiO2 has been studied using first-principles density functional theory. The calculated results show that owing to the formation of the impurity energy levels, which is mainly hybridized by 3d or 4d states of impurities with O 2p states or Ti 3d states, the response region in spectra could be extended to the visible light region. The position of the impurity energy levels in the band gap determines the effects of metal doping on the photocatalytic performance of TiO2. Most transition metal doping could narrow the band gap of TiO2, lead to the improvement of the photoreactivity of TiO2, and simultaneously maintain strong redox potential. Under O-rich growth condition, formation energies of anatase TiO2 doped with various metals are different. Particularly, the formation energies of TiO2 doped with Cr, Co, and Ni are found to be negative, showing that it is energetically more favorable to substitute Co, Ni, or Cr to a Ti site than other metals. These doping systems can be easily obtained and with good stability.
Theoretical research on transition metal-doped TiO2 is of great importance to develop the photocatalytic applications. First-principles calculation of doped TiO2 is still an ongoing subject, and a few challenging problems require further investigation in an urgent demand. One is the influence of the transition metal doping on the phase transition of TiO2 from anatase to rutile. A theoretical understanding on its mechanism will be useful to optimize the performance of TiO2 in photocatalytic and other applications. Another one is the question about using the virtual crystal approximation method to calculate the doping system for very low concentration, which can cut down the calculation time. With the solution of these problems, one could provide more accurate theoretical models to simulate the practical doping approaches which could lead to important implications in the optimization of the performance of transition metal-doped TiO2 photocatalysts.
This work was supported by the National Nature Science Foundation of China (51162007 and 51202050), Hainan Natural Science Foundation (511110), and Tsinghua University Initiative Scientific Research Program.
This article is published under license to BioMed Central Ltd. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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September 1, 2014
AggieYell Podcast South Carolina Review, Lamar Preview
Game one of the 2014 Texas A&M football season is in the books. The Aggies surpassed the nations expectations when they went into Columbia on Thursday night and defeated South Carolina 52-28. AggieYell.com reviews game one and looks ahead at game two when the Aggies host Lamar this Saturday in the first home game of the season and the first home game since the start of the Kyle Field renovation project.
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Courtney Roland is a staff reporter for AggieYell.com. You can follow her on Twitter at CourtneyRivals.
Mark Passwater is the team analyst for AggieYell.com. You can follow him on Twitter at mbpRivals.


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Five members of an Israeli family including a baby were murdered in their beds in a West Bank settlement in an attack blamed on Palestinians, sparking a huge manhunt and international condemnation.
Media reports said a baby girl of three months, two children aged three and 11, and their parents Ehud and Ruth Vogel were all stabbed to death in the Friday night attack in Itamar near the Palestinian town of Nablus.
In front of the Vogel home, settlers lit candles on Saturday night in memory of their slain neighbours.
According to an unverified report, Fatah's military wing – the al-Aqsa Martyrs' Brigades – claimed responsibility for the attack. A group spokesman told a Palestinian news agency that a terror cell infiltrated the settlement of Itamar and committed the attack.
Gaza residents from the southern city of Rafah hit the streets Saturday to celebrate the terror attack in the West Bank settlement of Itamar where five family members were murdered in their sleep, including three children.
Residents handed out candy and sweets, one resident saying the joy "is a natural response to the harm settlers inflict on the Palestinian residents in the West Bank."
A member of the al-Aqsa Brigades attacked a house in the Itamar settlement, South of Nablus, the group said in a statement on Saturday.UPDATE - The Israeli Navy has interdicted a large shipment of Iranian arms bound for the Gaza strip:
He managed to kill all the five Zionists who were in the house on Saturday morning, the statement added, mentioning that the Palestinian combatant has returned home safely after conducting his mission successfully.
The operation was a natural response to the crimes of the Zionist regime against the Palestinian people in the West Bank and Gaza Strip, the statement added.
The IDF seized a freighter ship with dozens of tons of weaponry from Iran headed for Hamas in the Gaza Strip on Tuesday.
The Victoria was boarded by commandos from the Israeli Navy's Flotilla 13, also known as the Shayetet, arrived in the Ashdod port on Tuesday evening.
An initial inspection of the cargo revealed the ship was carrying weapons. The exact amount is to be determined.
Guy Benson is Townhall.com's Political Editor. Follow him on Twitter @guypbenson. He is co-authors with Mary Katharine Ham for their new book End of Discussion: How the Left's Outrage Industry Shuts Down Debate, Manipulates Voters, and Makes America Less Free (and Fun).
Author Photo credit: Jensen Sutta Photography
BREAKING: Donald Trump Declared Winner of New Hampshire Primary; Kasich Comes in Second | Katie Pavlich
Rush Limbaugh defends Rubio's debate answer: He's absolutely right that Obama knows what he's doing | Allahpundit
Time for Team Hillary to break out the gender card for young liberal women who prefer Sanders | Allahpundit


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Sooo happy with this one! I tried several new things, and i'm quite pleased with them :] However, i have class tomorrow so i must sleep!
I'll edit this description tomorrow P: Hope you like!
I'll edit this description tomorrow P: Hope you like!
heeeeeeey man. where can i get this awsome star texture?....lol
The graphics are beautifully soft. Lovely work.
really nice vintage feeling. congrats
SO good!
i just love outer space
this is great!!
this is great!!
very cool man
you should make a tutorial on one of these ^^


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Golden Globe nominations for TV and film
The Golden Globes for film and television were announced Thursday, confirming that awards season is upon us.
Although the Hollywood Foreign Press Association, the group that hands them out, is regarded as a joke whose votes are easily influenced, their awards are taken somewhat seriously by studios, which use them as a marketing and promotional tool. »Read Full Blog Post(1)
Tame Impala anything but at Turner Hall show
Kevin Parker's perfectionist tendencies went into overdrive on last year's "Lonerism," psychedelic band Tame Impala's sophomore full-length album. Besides insisting on playing nearly all the instruments in the studio, Parker mixed the album two times, flying from his native Australia to New York on both occasions, to get the details just to his liking.
Tame Impala didn't have the luxury of do-overs and fine tuning in its sold-out, 85-minute Turner Hall Ballroom set Sunday. And if Parker attempted to bring that obsessive craftsmanship to a live setting, he would run the risk of sabotaging the set's potential for spontaneity. »Read Full Article(1)
'Rep Lab' cooks up mixed batch of one-acts
In her curtain speech before Saturday night's sold-out performance of "Rep Lab," Sandy Ernst - who oversees the Milwaukee Repertory Theater's justly acclaimed intern program - made clear that the Rep simply couldn't stage its shows without each year's crop of two dozen interns.
But even as we routinely note these interns' presence - in smaller roles, as extras and in program credits, where they are listed as understudies and assistants - we rarely get to really see what they can do. Now in its third year, "Rep Lab" - short plays showcasing intern actors, directors, choreographers and designers - lets us appreciate how good they can be. »Read Full Article
Report: Fallon to replace Leno
Reports have surfaced that late-night host Jimmy Fallon will replace Jay Leno as host of "The Tonight Show" show next year.
NBC, which just finished fifth behind Univision in the February ratings, has denied the report. »Read Full Blog Post(6)


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Funny: X Wing
Inexact title. See the list below. We don't have an article named Funny/XWing, exactly. We do have:
If you meant one of those, just click and go. If you want to start a Funny/XWing page, just click the edit button above. Be careful, though, the only things that go in the Main namespace are tropes. Don't put in redirects for shows, books, etc.. Use the right namespace for those.


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What is also not acknowledged is the fact that nearly 50 percent of these households are either sub-chapter S corporations or partnerships. Thus these policies will directly impact millions of small businesses.
So another way to look at the impact of these proposals is this: If the Obama plan stays as is, the tax burden of an individual owning a small S corporation with taxable income of $250,000 (including personal income and corporate profit) would jump from 33 percent to 39.6 percent, or $16,500, which is 6.6 percent of the household income and close to the average of what these households now give to charity – $20,500.
It's clear the Obama administration doesn't respect the enormous impact these households have on charitable institutions. To the plan's supporters, this increased level of taxation and reduction in the charitable deduction is only fair since they are in favor of redistribution of wealth … in this case, from successful and generous households and away from charity… to the government.
In a report released late last year by Barclays Wealth (in partnership with Ledbury Research), charitable giving may be in for an even more difficult time than we think. It states,
"Throughout history, private charitable giving has undergone cycles of boom and bust. In each, the stimulus was wealth creation and business innovation by private individuals, both of which were turned towards solving the social problems of the day. …governments regularly intervened to provide much needed support, bringing the donor-led philanthropic age to an end."
The report highlights that the last government intervention was "when Roosevelt expanded the role of government to fulfill charitable commitments."
Today, the Obama administration is heading in the same direction. The proposed tax increases undermine wealth creation and business innovation that is desperately needed to spur philanthropy and provide the critical support of charitable institutions. Instead Obama and his administration are intervening through their increased taxation on the households so important to philanthropy and at the same time reducing the incentive to give by capping the charitable deduction at 28 percent.
This should sound an alarm to charities that their future is at risk. Just as when President Roosevelt expanded the role of government which led to a profound negative impact on charitable giving and therefore, charitable institutions, so we are now headed in that same direction should these tax increases and charitable deduction decreases be passed.
At a time when charities are struggling as people continue to pull back in their charitable support these proposals could accelerate the erosion of charitable institutions and their effectiveness just when these institutions are needed more than ever.
Many charities are in the fight for their lives. With Obama's help some will face an early death.


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beautiful couple!
I think both of you look lovely
Beautiful definitely well captured
So cute
She's so pretty!
why dd ??
No offense.... but this looks more like a prom picture then a wedding picture... Also shouldn't she be looking into HIS eyes and not the camera? They are suppose to flaunting that they deeply love each other enough to get married. Not posing for the next runway model.
Maybe I'm just being old fashioned but her dress is... seriously lacking. Even with a short wedding dress, the dress should AT LEAST be modest enough to cover the knees. The cocktail dress definitely does not scream 'classy' on a wedding day. It's a wedding, not a night out. She shouldn't try to flaunt everything down the aisle.
Or this may be an afterparty dress and I'm dumb.
On the other hand, great picture. I hope they remain happy for many years.
Or this may be an afterparty dress and I'm dumb.
On the other hand, great picture. I hope they remain happy for many years.
Seems like she should be looking into the guy's eyes in the left photo.
I need that guy to teach me his tricks. She's gorgeous. T.T
I agree with the comment that stated that the bride's happy face and fantastic smile really makes the photos. I also like the outdoors and the positioning of the couple on the walkway, to suggest that their journey together is out in front of them. Great job! Good luck with your work!
her happy face is the best part of these pics
This a fantastic feature for a Daily Deviation. Good work!
Congrats ~
Awwwww... how sweet!
What an ugly bokeh... :/
May not be the most gorgeous bokeh, but given the equipment and it's a fantastic portrait!
Thats rather shallow.
She is so pretty!
Nice shots! Love it
happy people <3
I always find photos funny when a man is looking at the woman and the woman is looking away or at the camera. Slut.
Beautiful I really like it!!
Congratulations on the DD
Nice pix of cute couple
Congrats on DD
Congrats on DD
Yes!!! so cute!!!!!!!
Flagged as Spam
Even if this is something I don't like, anyone can agree that spammers need to stop.
Die in spam-hell!
lovely looking couple!
That's a nice shot. Wonderfull moments catched
why did such a cute girl marry such a nerdy looking dude?
it is also beautiful
Maybe because they love eatch other??
What a rude comment jez
What a rude comment jez
yeah, I bet hes loaded
They are both good at looking, what's your problem ?
whats your problem with me?
Maybe she's loaded, maybe they consider him the pretty one, maybe one of them is really an extra terrestrial which brainwashed the other into marriage in order to closely study the ritual! Can't make anything but baseless assumptions, looking at a couple of staged photographs. :>


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About Solar Power International
Solar Power International (SPI) generates success for solar energy professionals and the global solar industry. SPI is ranked #109 in the Top 250 Largest Trade Shows (by Trade Show News Network), making SPI the largest solar show in North America. In addition, SPI is a Gold 100 trade show (as ranked by Trade Show Executive), making it the only solar show to make both lists.
The Facts
SPI is North America's premier business-to-business event for professionals in solar energy and related fields.
- More than 15,000 solar energy industry professionals from 75+ countries attend.
- More than 600 leading manufacturers, service providers, and vendors on the Expo floor.
- Four days of power-packed ROI that will help you grow, learn, connect, and compete.
The Features
SPI brings the full range of industry ideas, experts, professionals, and information together in one comprehensive event that delivers:
- Peer-led educational programming designed to exchange ideas, share lessons learned, and provide solutions for your business.
- Unique networking opportunities that allow you to solidify your current relationships and build new ones.
- Connections with industry vendors and professionals from the U.S. and around the world as they showcase their newest products and services.
- Opportunities to expand in and with the U.S. market.


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By Radu Turcas
Open iTunes to buy and download apps.
Do you want to keep track of all the times you had sex, with whom, for how long, what positions, how many times, where and how it was?
Now you can! With iBoogie you can keep track of all times you had sex and many more spicy details.
iBoogie will keep track of your every sex-perience. You just tap the Boogie button and mind your business.
Play your sex playlist directly from the app.
100 funniest sex jokes for after you're done ;).
"great app - works good, as long as you have what to fill in ;)I do!"
"Good App - The idea behind the app is a good one , because I haven't seen anything resembling it before. It is intuitive and quite fun to use it.Have a nice iBoogie time !"
Features of your every performance:
1. Multiple Partners: name, picture, phone number
2. Was it safe sex or not?
3. Country and City, address, GPS Location, driving directions
4. 40+ Sex positions
5. Save your impressions on the sex you just had
6. 5-star rate every time you had sex
iBoogie creates statistics for you:
1. How much sex you had, EVER.
2. All Partners -> all sessions by partners
3. All the Countries and Cities you had sex in and the number of times you did -> all sessions by locations
4. Average sex-perience duration
5. Total sex time
6. 5-star average rating of all boogie - woogie times
7. All sex-sessions
8. Sex-sessions in a certain period of time
Competitive much? You get - Best of - categories are:
1. Best Rated
2. Longest duration
3. Most number of times
Calendar - Search - Edit - Add new in Archive
- Add / Edit sex-periences after you had them - offline mode archive
- Search entire archive by partner's name or initials
- Password protection if you want to set it up
- Archive tabbar badge if you go multiple times it will show you the path
For couples iBoogie offers a default data section where you can store your usual partner, country, city, etc...
Delete entire sex history (all archive) in 2-tap steps.
Hide sex-periences with certain people by deleting all the times you had sex with them with 2-taps.
Youtube: http://www.youtube.com/watch?v=QGjxWwv9KMU
What's New in Version 1.5
Fix partner phone number calling
Don't forget to rate this version of the app as well, your feedback keeps us going :-)
iPhone Screenshot
- $2.99
- Category: Lifestyle
- Updated: Apr 13, 2015
- Version: 1.5
- Size: 2.6 MB
- Languages: English, Arabic, Catalan, Czech, Danish, Dutch, Finnish, French, German, Greek, Hebrew, Hungarian, Indonesian, Italian, Japanese, Korean, Malay, Norwegian Bokmål, Polish, Portuguese, Romanian, Russian, Simplified Chinese, Slovak, Spanish, Swedish, Thai, Traditional Chinese, Turkish, Vietnamese
- Seller: Radu Nicolae Turcas
- © 2011 Radu Turcas
Compatibility: Requires iOS 5.1.1 or later. Compatible with iPhone, iPad, and iPod touch.


text:
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Categories: Amateur, Anal, Blowjob, Facial, Hardcore, Teens
Submited: 5 years old
Views: 5953
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Zybella Blue Packed Full Of Thick Cock And Jizz On Her Face


text:
Auto Answers » View Question
granny ... 3/28/2010
2004 Chevrolet Monte Carlo LS 6 Cyl 3.4L
Rear wheel disc brakes/ PARKING BREAK
How do I adjust a parking brake on rear wheel disc brakes? 2004 Monte Carlo LS
1 Answer
HouseCallAuto 3/28/2010
Adjust the parking brake by turning the nut on the equalizer while spinning both rear wheels by hand. When one wheel starts to drag back off one full turn of the nut.


text:
Ballina, a coastal town in the Northern Rivers region in New South Wales, is only a thirty-minute drive from Byron Bay and favourite holiday destination along the North Coast. With holiday parks on the Richmond River, motels close to the town centre and numerous beach resorts and retreats, there is accommodation in Ballina for you, no matter what kind of trip you have planned.
Nestled between the Richmond River and a series of beautiful beaches, Ballina offers a number of quality camping and holiday spots. Set in secluded bushland areas or adjacent to stunning beaches, these parks are the perfect spot for a family break - complete with pets!
There are a number of motels and serviced apartments on offer in Ballina to suit all budgets. With outdoor dining settings and WiFi internet access, as well as pools, gyms and saunas, you'll be able to experience all the comforts of home while on your break.
With its beautiful subtropical climate, Ballina is home to a number of luxury resorts. Nestled in the hinterland of Ballina, with expansive views of the region, you'll be able to recharge your batteries with these extensive spa offerings - perfect for couples after a really relaxing break.


text:
I need to manage the acquisition of many record at hour. About
1000000 records. And I need to get every second the last insert value for every primary key. It works quit well with sharding. I was thinking to try the use os capped collection to get only the last record for every primary key. In order to do this, I made two separated insert, there is a way, into
mongodb, to make some kind of trigger to propagate the insert into a collection to another collection?
I need to manage the acquisition of many record at hour. About
MongoDB does not have any support for triggers or similar behavior.
The only way to do this is to make it happen in your code. So the code that writes the first entry should also write the second.
People have definitely requested triggers. If they are necessary for your solution, please cast a vote on the feature request.
I disagree with "triggers is needed". People, MongoDB was created to be very fast and to provide as basic functionalities as can be. This is a power of this solution.
I think that here the best think is to create triggers inside Your application as a part of Data Access layer.


text:
Light, subtly floral and totally feminine, Victoria's Secret Chiffon Peony...
Light, subtly floral and totally feminine, Victoria's Secret Chiffon Peony Freesia Eau de Parfum ($22.50) is the perfect summer fragrance! The scent is blended with bloom of peony, fresh South African white freesia, sparkling Italian bergamot and vanilla.
Customer Service | E-mail Newsletter Sign-up | Subscribe to Essence | Give a Gift of Essence | Change Your Address | Renew Your Subscription | Pay Your Bill | Questions & Comments
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text:
Archive for June 2011 | Monthly archive page
I have a favorite new arrangement idea! Pomander carnation arrangements! It's bright, its fun, and its modern. Paying the big bucks for floral designers to make modern arrangements is no longer a must! Besides, wouldn't you rather do it yourself and earn bragging rights! I suggest a round pomander arrangement. It will make you look […]
Diana DeVito
You should make them the day before the wedding to use them in peak condition, however, soak the floral foam in a water/flower food mix to keep them lasting for days!jen nicole
how many days in advance can you make these before the wedding?View All Comments »
Related Posts:
Isn't it nice when people who serve our country get married military style!? I think so. But what about the flowers, What do you do? That's a very common question for those who are planning a military wedding! But don't worry, we have answers! Military weddings have some strict guidelines, but luckily for the military […]
Of course!We offer military a 5% Discount on the entire order of wedding flowers (really helps out!)
You can get the discount (promotion code posted above) at Bloomsbythebox.com, place your order or call us! 908-791-0487!
Thank you so much Fran!Have an awesome day!Fran
What is the discount? Could you please be a little more specific? So that I can share this with my Facebook fans, blog followers and Twitter followers. Thank you!
Have a blessed day,
The Frugal Army Wife
Related Posts:
We all watched the Royal wedding at one point or another, whether it was 4am or on re-runs, we all felt the magnetism of this inspired celebration. Its near impossible to overlook the fairytale joining of Prince William and Catherine Middleton. In fact, the only way to describe the celebration is royally remarkable. It was […]
nice postView All Comments »
Related Posts:
It's summer, and its time to get outside in that gorgeous weather and soak up the sun. Whether its a date, family gathering, or bridal shower a picnic is a traditionally lustrous way to enjoy the season. There is no better way to get loved ones together like food, flowers, and fun in the sun! Designsponge.com offers a […]
I know, it looks so simple and I love these colors!bridal shower invitation wording
This is amazing, I never knew that its going to be so simple. Thanks for the pictorial explanation of the entire process.View All Comments »


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Nihon by flaviobollaWatch
©2011-2016 flaviobolla
Short Speedie after reference.
Visit my new Blog for more Information (currently only in German)
Visit my new Blog for more Information (currently only in German)
I that Kinkakuji?
amazing interpretation of the golden temple, truely beautiful, love the use of refections and how it seems so simple but a look at one area shows its complexity
Oh this is just beautiful! So serene and peaceful.
I've visited the golden shrine myself, really cool to visit if you happen to find yourself in kyoto. you captured the the entire atmosphere of the place really well. Great job
Oh yea! This would look nice as a large wall piece!
The house is perfect - i leave in Japan and i know how the local houses look! You have done it excellent! Keep up with the good work!^*
Very eye catching, this is sweet!
nice job
I took the same picture, I think everyone does very good!!
Wow, such a beautiful place. I absolutely love the colors and the details, they look really wonderful C:
i was there *___*
like it!
like it!
Really well done! Bravo!
wow. i want to live there!! \(^o^)/
my god this is beautiful.


text: The location of this hotel is fantastic. When I booked our flights and hotel together on Orbitz, I was surprised at the low price for this room because the location seemed so ideal. I just assumed we would be sacrificing quality and comfort in the accomodation, because that location at that price seemed too good to be true. I was... More


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August 24, 2015 – National Governors Association
WASHINGTON—Using data to track recent graduates in the workforce helps ensure postsecondary education institutions are preparing graduates for successful careers, according to a report released today by the National Governors Association (NGA).
Accurate information gleaned from education and workforce data is key to well-functioning labor markets. With the platform to guide public education and economic development, governors play a pivotal role in the success of their state's labor market.
Tracking Graduates in the Workforce: Connecting Education and Labor Market Data looks at questions governors can ask when evaluating postsecondary education and training programs in their state. The report also profiles several successful programs already in place throughout the country.
"Tracking graduates' success in the workforce helps employers and employees make important decisions about hiring, wages, training and more," said Hawaii Gov. David Ige. "As governors, we can help make sure our postsecondary programs and workforce training programs are using data effectively and efficiently to improve graduates' chances of finding and keeping good jobs."
To evaluate postsecondary education and training programs, governors should consider:
- How their state is using data to improve educational system outcomes to benefit recent graduates, workers and employers;
- How the state is using education and workforce data to improve postsecondary programs and hold institutions and other state entities accountable; and
- Where recent graduates have successfully found employment.
To learn more about the NGA Center for Best Practices Education Division, please visit http://www.nga.org/cms/center/edu.
Related content:
The information above is for general awareness only and does not necessarily reflect the views of the Office of Economic Adjustment or the Department of Defense as a whole.


text:
"Made me a better skier," noted one tester. The Trinity's relaxed, neutral stance doesn't sacrifice power and control. Note: women with high-volume or hard-to-fit feet might want to consider the Vacuum model ($699), which a boot fitter will heat-mold to your foot.
Brand: Fischer $625
Want to get Outside more?
Sign up for our newsletter and get the latest fitness tips, expert gear reviews, the best travel advice, and more.


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Hoburne Holiday Parks 2013 Summer Discounts upto 17.5%(1 Post)
bowyert1 Thu 04-Jul-13 19:05:01
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Revision history of "Zeus server"
View logs for this page
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Star Racer
by: playstoreshao | 102
by: playstoreshao | 102
You have to drive your space mobile on different tracks and try to defeat all your opponents.
You have 3 different space mobiles to choose and four different racing circuits on distant planets.
Arrived in the checkpoints before the time runs out. Avoid crashing your space mobile or you will lose speed.
Go ahead and win all the tracks...
Left/Right arrows = Move left/right
Arrow key up = Forward/Accelerate
Arrow key down = brake
tags: Free games, Fun games, Casual games, Online games,Drives games,Challenge,Race games,racing,Racer
Tags: star racing , star racer для андроид , star racer , star raicer
from 102 reviews
Free - V1.0.1 - 2M
Sorry ...
This app is no longer available.


text:
Shop Sections
Shop Owner
Hot Springs, SD, United States
Have a question?Contact Shop Owner
Shop Info
Opened on May 26, 2007
- About
- Shop updates (1)
- Policies
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- 230 sales
- 347 admirers
Small Batch Herbal Formulas made in the Black Hills
Sweetgrass Emporium is a line of prairie-inspired herbal beauty and wellness products to deepen your self-care practice and ritual. It is the evolving work of Stephanie Lynn Tanner, holistic nurse and health coach. I specialize in mind-body-soul wellness, the childbearing year, and have been cultivating my relationship with… read more
This shop accepts Etsy Gift Cards.
Featured items from SweetgrassEmporium


text:
A small private jet overshot the runway, took a dramatic bounce on the turf and then flopped onto the roadside embankment.
Investigators were probing claims that the Cessna 525B Citation plane failed to brake upon landing and hit the ground with its engines running.
Originally posted by Zaphod58
reply to post by Lonewulph
It's a Citation. They overshot the runway on landing, bounced when they hit the grass, and you saw the end result.


text:
Print or e-mail your favorites and plan your perfect visit to NYC today.
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Enjoy the Tribeca Film Festival, opening day for the Mets and Yankees, the New York International Auto Show and more.
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Get tips, maps and everything else you'll need during your stay.
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New York City is made up of five boroughs: the Bronx, Brooklyn, Manhattan, Queens and Staten Island. Each one has enough attractions—and enough personality—to be a city all its own. Learn more about them with this guide.
Giorgio Armani has enjoyed a deeply loyal following since the 1980s, but nonetheless it was a bold move to open an exclusive megastore with an Italian restaurant in bad economic times. The project, however, has proven to be a success. The glass-walled restaurant on the top floor is done in black with touches of red, the curvy booths theatrically lit. Chef Sandro Romano translates Armani's tasteful philosophy to include simple yet enticing dishes like gnochetti with red mullet, Treviso radicchio salad and prized Ligurian Taggiasche olives. The dessert menu is rich, and just outside the dining room is Armani's jewel box of a chocolate shop.