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Publications (20)72.85 Total impact
Article: Asymmetric synthesis of azolium-based 1,2,3,4-tetrahydronaphthalen-2-ols through lipase-catalyzed resolutions[Show abstract] [Hide abstract]
ABSTRACT: A series of racemic trans-1,2,3,4-tetrahydronaphthalen-2-ols bearing an azole nucleus at the C-1 or C-3 position has been synthesized by ring opening reactions of the corresponding epoxides using imidazole or 1,2,4-triazole. The kinetic resolutions of these racemates were undertaken through transesterification processes, finding good levels of activities and high to excellent enantiodiscrimination values for the Pseudomonas cepacia lipase immobilized on a ceramic carrier. Investigations into the optimum reaction conditions were carried out by consideration of different organic solvents, temperatures, enzyme loadings, and reaction times. With the best conditions in hand, the experiments were later carried out toward the resolution of the related racemic cis-alcohols, which were previously obtained through a Mitsunobu and deprotection chemical sequence from the trans-stereoisomers.
Article: Deracemisation of profenol core by combining laccase/TEMPO-mediated oxidation and alcohol dehydrogenase-catalysed dynamic kinetic resolution[Show abstract] [Hide abstract]
ABSTRACT: A mild one-pot methodology has been developed to deracemise rac-2-phenyl-1-propanol by combining the use of non-selective laccase/TEMPO-mediated oxidation with enantioselective bioreduction of the racemic aldehyde intermediate under dynamic conditions. The process was easily scalable and stereocontrollable by selecting the suitable biocatalyst.
Article: ChemInform Abstract: Lipase-Catalyzed Desymmetrization of meso-1,2-Diaryl-1,2-diaminoethanes.[Show abstract] [Hide abstract]
ABSTRACT: The synthesis and enzyme-catalyzed desymmetrization of meso-1,2-diaryl-1,2- diaminoethanes have been investigated. A family of aromatic meso-1,2-diamines, containing different substitution patterns in the aromatic ring, was first prepared and then desymmetrized enantioselectively using lipases as biocatalysts. Selective alkoxycarbonylation of one of the amino groups was achieved using allyl carbonates, isolating the corresponding allyl monocarbamates with moderate to high enantiomeric excess at 45 C. Candida antarctica lipase types A (CAL-A) and B (CAL-B) displayed the best activities and stereopreferences, with a dramatic influence being observed depending on the diamine structure. Non substituted and para-substituted aryldiamines led to the formation of allyl carbamates with good enantiomeric excess, using CAL-A for the less hindered substrates and CAL-B for the more hindered ones. On the other hand meta- and ortho-derivatives afforded low or negligible conversions and selectivities, respectively.
Article: ChemInform Abstract: Chemoenzymatic Epoxidation of Alkenes Based on Peracid Formation by a Rhizomucor miehei Lipase-Catalyzed Perhydrolysis Reaction.[Show abstract] [Hide abstract]
ABSTRACT: A chemoenzymatic and selective method for the epoxidation of a series of cyclic and linear alkenes is described. Epoxides have been obtained in moderate to excellent conversions under mild reaction conditions through a two-step sequence, carried out in one-pot. This chemoenzymatic approach is based on a Rhizomucor miehei lipase-catalyzed perhydrolysis reaction to form the corresponding peracid, and subsequent epoxidation of the corresponding alkenes. Reaction parameters with influence in the biotransformation have been optimized specially focusing in the efficient enzymatic peracid formation by means of the correct choice of solvent, oxidant, and peracid precursor. This chemoenzymatic approach has been efficiently applied for the first time, in the regioselective chemical oxidation of (S)-carvone and limonene, both showing an opposite behavior for the oxidation of the internal and external C–C double bond, respectively.
Article: Enzymatic transesterification of pharmacologically interesting β-aminocycloalkanol precursors[Show abstract] [Hide abstract]
ABSTRACT: Chemoenzymatic syntheses of both enantiomers of cis- and trans-2-aminocyclopentanol as well as cis- and trans-2-aminocyclohexanol, which are valuable building blocks for a plethora of ligands and pharmaceuticals have been efficiently carried out. The strategy involves the stereospecific syntheses of racemic aminocycloalkanol precursors via tagging of a phthalimide as a masking group and subsequent lipase-catalyzed kinetic resolution. Most of the lipases exhibited excellent enantioselectivity (E ≫ 200) in the transesterification reactions of trans-derivatives, with both N-protected (R,R)-amino acetates and (S,S)-amino alcohols being isolated in enantiopure form. With regard to cis-derivatives, lipases were also very selective, even though the biotransformations were significantly slower.
Article: Analysis of beer volatiles by polymeric imidazolium-solid phase microextraction coatings: Synthesis and characterization of polymeric imidazolium ionic liquids[Show abstract] [Hide abstract]
ABSTRACT: Two polymeric ionic liquids, 3-(but-3″-en-1″-yl)-1-[2'-hydroxycyclohexyl]-1H-imidazol-3-ium bis(trifluoromethanesulfonyl)imide (IL-1) and 1-(2'-hydroxycyclohexyl)-3-(4″-vinylbenzyl)-1H-imidazol-3-ium bis(trifluoromethylsulfonyl)imide (IL-2), have been synthesized by a free radical polymerization reaction and used as coatings for solid-phase microextraction (SPME). These new fibers exhibit good film stability, high thermal stability (270-290°C) and long lifetimes, and are used for the extraction of volatile compounds in lemon beer using gas chromatography separation and flame ionization detection. The scanning electron micrographs of the fiber surface revealed a polymeric ionic liquid (PIL) film, which is distributed homogeneously on the fiber. The developed PIL fiber showed good linearity between 50 and 2000μg/L with regression coefficients in the range of 0.996-0.999. The relative standard deviations (RSD) obtained in the peak area were found to vary between 1% and 12%, which assured that adequate repeatability was achieved. The spiked recoveries for three beer samples ranged from 78.4% to 123.6%. Experimental design has been employed in the optimization of extraction factors and robustness assessment. The polymeric IL-1 butenyl fiber showed a greater efficiency compared to the PDMS-DVB (65μm) and CAR-PDMS (75μm) for the extraction of all of the analytes studied.
Article: Chemoenzymatic synthesis of optically active 2-(2′- or 4′-substituted-1H-imidazol-1-yl)cycloalkanols: chiral additives for (L)-proline[Show abstract] [Hide abstract]
ABSTRACT: Enantiopure substituted imidazoles obtained by enzymatic kinetic resolution can be promising candidates as co-catalysts for aldol reactions catalysed by (L)-proline. These additives seem to form supramolecular complexes with the catalyst through the formation of H-bonds, leading to significant improvement in both the reaction rates and selectivity of the reaction. Herein, we present our results on the use of these substituted trans-2-imidazoyl-cycloalkanols as additives for the (L)-proline catalyzed direct aldol reaction between ketones and aromatic aldehydes.
Article: Chiral Triazolium Salts and Ionic Liquids: From the Molecular Design Vectors to Their Physical Properties through Specific Supramolecular Interactions[Show abstract] [Hide abstract]
ABSTRACT: An exhaustive experimental study based on X-ray diffraction analysis, NMR, FTIR-ATR (attenuated total reflection), and Raman spectroscopy as well as theoretical calculations is reported in order to understand how the non-covalent intermolecular contacts are fundamental to explain structure-property relationships and allowing us to correlate a basic macroscopic property (i.e., the melting point, T(m) ) with the structural variables of a family of enantiopure 1,4-dialkyl-1,2,4-triazolium salts. The effect of different structural vectors such as the ring size, the spatial disposition of the substituent, the substitution on the oxygen atom, the nature of the anion, or the N4 alkylation of the triazole on the intermolecular interactions of these chiral salts of a well-defined 3D structure is reported. The non-covalent intermolecular contacts mainly implicating the triazolium H3 proton are fundamental to explain structure-property relationships and, therefore, the physical properties of these new chiral salts, rather than simple anion-cation interactions. Overall, our findings highlight the importance of the specific supramolecular interactions for the understanding of the physical properties of triazolium salts and ionic liquids.
Article: Stereoselective Chemoenzymatic Synthesis of Enantiopure 2-(1H-imidazol-yl)cycloalkanols under Continuous Flow Conditions[Show abstract] [Hide abstract]
ABSTRACT: The development of continuous flow processes for the synthesis of chiral enantiopure 1-(2-hydroxycycloalkyl)imidazoles is reported. For the ring-opening reaction microwave batch processes and continuous flow reactions have led to similar results in terms of conversion, although the productivity is clearly improved under flow. The use of continuous flow systems for the lipase-catalyzed kinetic resolution of the racemic 2-(1H-imidazol-yl)cycloalkanols with either immobilized CAL-B or PSL-C has been demonstrated to be significantly more efficient than the corresponding batch processes. The continuous flow biotransformations have allowed us to easily increase the production of these chiral imidazoles, adequate building blocks in the synthesis of chiral ionic liquids.
Article: Polymeric imidazolium ionic liquids as valuable stationary phases in gas chromatography: Chemical synthesis and full characterization[Show abstract] [Hide abstract]
ABSTRACT: Seven new functionalized polymerizable ionic liquids were chemically prepared, and later applied for the preparation of polymeric stationary phases in gas chromatography. These coated GC columns, which exhibited good thermal stabilities (240-300°C) and very high efficiencies (3120-4200 plates/m), have been characterized using the Abraham solvation parameter model. The chromatographic behavior of these polymeric IL columns has been deeply studied observing excellent selectivities in the separation of many organic substances such as alkanes, ketones, alcohols, amines or esters in mixtures of polar and non polar solvents or fragrances. Remarkably, the challenging separation of xylene isomers has been possible using a bis(trifluoromethylsulfonyl)amide based imidazolium IL coated column as a gas chromatography stationary phase.
Article: Characterization of hexacationic imidazolium ionic liquids as effective and highly stable gas chromatography stationary phases[Show abstract] [Hide abstract]
ABSTRACT: Polycationic ionic liquids (ILs) are an attractive class of ILs with great potential applicability as gas chromatography stationary phases. A family of hexacationic imidazolium ILs derived from the cycloalkanol family was chemically first prepared in a straightforward manner and then applied for analytical separation purposes. Four tuneable engineering vectors, namely cation ring size structure, anion nature, spatial disposition of cycloalkanol substituents and O-substitution, were considered as experimental parameters for the design of the desired ionic liquids. A total number of five new phases based on a common benzene core respectively exhibited column efficiencies around to 2500 plates/m, broad operating temperature ranges and also, even more importantly, good thermal stabilities (bleeding temperature between 260 and 365°C), finding variations in the selectivity and analytes elution orders depending on the IL structures. Their solvation characteristics were evaluated using the Abraham solvation parameter model, establishing clear correlations between their cation structure and retention capability with respect to certain analytes. The study of relationships between the ILs structure and solvation parameters gives us an idea of the IL stationary phase to be used for specific separations.
- [Show abstract] [Hide abstract]
ABSTRACT: A novel family of triazolium salt enantiomers has been efficiently synthesized by combining chemical and biocatalytic methods. The stereoselective action shown by hydrolytic enzymes led to the design of simple and general chemoenzymatic routes in which tunable vectors, such as ring size, substituent stereochemistry, oxygen substitution, anion nature, or N4-triazole alkylating chain, were considered to produce 30 enantiopure triazolium salts in very high overall yields. Finally, selected triazolium salts were tested as phase-transfer catalysts in the asymmetric Michael addition of diethyl malonate to trans-chalcone to rationalize their activity and stereopreference. Low to complete conversion values were achieved in the formation of the Michael addition adduct, which mainly gave low levels of stereoselectivity depending on the different structural patterns considered in this systematic study.
Article: Chemoenzymatic Asymmetric Synthesis of Optically Active Pentane-1,5-diamine Fragments by Means of Lipase-Catalyzed Desymmetrization Transformations[Show abstract] [Hide abstract]
ABSTRACT: A novel family of prochiral pentane-1,5-diamines has been efficiently synthesized, possessing stabilities significantly higher than those of corresponding propane-1,3-diamine analogues. Diamines have been later desymmetrized using Pseudomonas cepacia lipase as an efficient biocatalyst for the mono- but also stereoselective protection of one of their amino groups. Reaction parameters such as type and loading of enzyme, temperature, solvent, and acyl donor have been exhaustively analyzed, searching for optimal conditions for the production of interesting optically active nitrogenated compounds. Thus, acylation and alkoxycarbonylation processes have been compared in terms of conversion and enantiomeric excess values. The best results were found in the reaction of prochiral diamines with ethyl methoxyacetate as acyl donor and 1,4-dioxane as solvent, yielding (S)-monoamides in 33-59% isolated yield and 54-99% ee, depending on the aromatic pattern substitution.
Article: Complementary Lipase-Mediated Desymmetrization Processes of 3-Aryl-1,5-Disubstituted Fragments. Enantiopure Synthetic Valuable Carboxylic Acid Derivatives[Show abstract] [Hide abstract]
ABSTRACT: Desymmetrizaton enzymatic processes have been extensively studied searching for optimal methods of producing enantioenriched monoacetates from prochiral diols and diesters. AK lipase has been found as an excellent biocatalyst for the desymmetriaztion of a series of previously synthesized 3-arylpentane-1,5-diols derivatives. The access to (S)- or (R)-monoacetates in high optical purity (86-99% ee) has been possible by using acetylation or hydrolysis reactions, respectively, where the reaction parameters have been optimized in terms of source and amount of biocatalyst, temperature, solvent, and reaction time. The synthetic potential of enantiopure monoesters has been demonstrated by using these interesting chiral building blocks for the preparation of novel enantiopure carboxylic acid derivatives.
Article: From Salts to Ionic Liquids by Systematic Structural Modifications: A Rational Approach Towards the Efficient Modular Synthesis of Enantiopure Imidazolium Salts[Show abstract] [Hide abstract]
ABSTRACT: This paper reports a simple and robust modular synthetic strategy that leads to a large variety of configurationally and structurally diverse imidazole-based chiral ionic liquids (CILs) by lipase-catalyzed resolution. The intimate microscopic interactions of the supramolecular ionic network of these imidazolium chiral salts at the molecular level are investigated both spectroscopically (NMR, FT-IR-ATR) and theoretically, and a topological analysis of the experimental electron densities obtained by X-ray diffraction of single crystals is performed. Our results support the key role played by the relative configuration of the -OR group on the hydrogen-bonding pattern and its strong influence on the final physical properties of the imidazolium salt. We also obtained a reasonable correlation between the observed melting point and the non-covalent interactions. The spectroscopic data and the topological analysis reflect the key role played by hydrogen bonds between the OH and imidazolium C2H groups in both cation-anion and cation-cation interactions, with the presence of an OH group leading to an additional inter-cation interaction. This interaction significantly affects the properties of stereoisomeric salts. Even more interestingly, we also studied the effect of the chirality by comparing enantiopure CILs with their racemic mixtures and found that, with the exception of trans-Cy6-OH-Im-Bn-Br, the melting points of the racemic mixtures are higher than those of the corresponding enantiomerically pure forms. For stereoisomeric examples, we have successfully explained the differences in melting temperatures in light of the corresponding structural data. Chirality should therefore be taken into account as a highly attractive design vector in the preparation of ILs with specifically desired properties.
Article: Computational Study of the Lipase‐Mediated Desymmetrisation of 2‐Substituted‐Propane‐1,3‐Diamines[Show abstract] [Hide abstract]
ABSTRACT: The enantioselectivity displayed by the lipase from Pseudomonas cepacia towards a wide range of prochiral 2-substituted-propane-1,3-diamines was studied by means of molecular dynamics simulations (MDS). In all cases the enzyme allows the recovery of the corresponding amino carbamates of R configuration. However, the enantioselectivity is only synthetically useful if no ortho substituent is present and the aromatic ring is directly bonded to the 2-carbon of the 1,3-diamine core. Analysis of the MDS trajectories revealed that the homologation of 2-aryl substituents by means of a methylene group lowers enantioselectivity by alleviating the conformational tension of the slow-reacting orientations due to unfavourable intramolecular contacts between the ortho carbons of the aryl group and the nucleophilic nitrogen, as well as between the chiral carbon and the oxyanion. Additionally, the relative solvent accessible surfaces of the atoms of the aryl ring nicely correlate with the effect of the location of the substituent on enantioselectivity.
Article: ChemInform Abstract: Enzymatic Desymmetrization of Prochiral 2-Substituted-1,3-diamines: Preparation of Valuable Nitrogenated Compounds[Show abstract] [Hide abstract]
ABSTRACT: ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option.
Article: Influence of the Nucleophile on the Candida antarctica Lipase B-Catalysed Resolution of a Chiral Acyl Donor[Show abstract] [Hide abstract]
ABSTRACT: The resolution of methyl (+/-)-3-hydroxypentanoate catalysed by Candida antarctica lipase B has been performed by using ammonia and benzyl amine as nucleophiles. In all cases, the lipase reacts faster with the R enantiomer of the ester, but when benzyl amine is used, the enantiomeric ratio is approximately three times as high as that measured for ammonia. The analysis of the molecular dynamics simulations carried out over the corresponding deacylation transition state analogues indicated specular binding modes between enantiomers that vary greatly upon the nucleophile used. For the case of ammonia, an intramolecular hydrogen bond between the beta-hydroxyl group and the protons of the nucleophile is established. However, the presence of the substituent in benzyl amine disrupts this interaction. Instead, the acyl chain binds to a more restrictive area of the protein where the higher number of contacts established with the side chains of Thr40, Gln157 and Ile189 have been identified as the reason for the higher enantioselectivity observed in the aminolysis reaction.
Article: ChemInform Abstract: Enzymatic Desymmetrization of Prochiral 2-Substituted-1,3-diamines: Preparation of Valuable Nitrogenated Compounds.[Show abstract] [Hide abstract]
ABSTRACT: A wide range of prochiral 1,3-diamines were first efficiently synthesized and subsequently desymmetrized by using lipase from Pseudomonas cepacia as catalyst and diallyl carbonate as alkoxycarbonylating agent. In all cases, the amino carbamates of R-configuration were recovered. Final selective cleavage of the N-allyloxycarbonyl moiety was carried out under mild reaction conditions, which demonstrates the high versatility and potential of this chemoenzymatic route as a source of intermediates in the synthesis of related optically active nitrogenated derivatives.
Article: Simple and Straightforward Synthesis of Novel Enantiopure Ionic Liquids via Efficient Enzymatic Resolution of (.+-.)-2-(1H-Imidazol-1-yl)cyclohexanol[Show abstract] [Hide abstract]
ABSTRACT: Both enantiomers of enantiopure imidazolium ionic liquids were synthesized by a simple and straightforward procedure from (R,R)- and (S,S)-2-(1H-imidazol-1-yl)cyclohexanol derivatives obtained via lipase-catalyzed resolution. Structural properties and thermal stability of these compounds have been studied to elucidate their potential applications in asymmetric catalysis.
Top Journals
University of Oviedo
Oviedo, Asturias, Spain
- • Department of Organic and Inorganic Chemistry
- • Área de Química Inorgánica
EntreChemOviedo, Asturias, Spain


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Villa Maena
from £70 /night help Price for guests, Nights
1 review
from £70 /night help Price for guests, Nights
Estimated nightly price based on a weekly stay. Excludes fees (if applicable). Enter your dates to see the total cost.
Villa / 3 bedrooms / sleeps 7 Home 287861
Availability Your dates are available
Villa / 3 bedrooms / sleeps 7
|Key Info
Villa Maena is a typical Andalusian farmhouse situated in a very quiet place with stunning views to the mountains and the sea. It has large porch from you can enjoy of a lunch or dinner as in summer how in winter. It has a large table and chair for 8 people.
A great private swimingpool, a large area of barbecue next to the pool . Furniture of terrace and sunbeds.
Rural farmhouse recently renovated retaining all its characteristics without sacrificing the comforts cortijo of modern times.
It has all you need to enjoy of a fantastic holidays.
|Sleeps up to 7, 3 bedrooms
|3 bedrooms, 2 bathrooms of which 1 Family bathrooms and 1 En suites, Solarium or roof terrace
|Will consider
|Corporate bookings, House swap, Long term lets (over 1 month)
|Family friendly
|Great for children of all ages
|Pets welcome, Yes, smoking allowed
Features and Facilities
|Fireplace, Internet access, DVD player, Sea view
|Private outdoor pool (unheated), Children's pool
|TV, Satellite TV, Wi-Fi available
|Kettle, Toaster, Iron, Hair dryer
|Cooker, Microwave, Fridge, Freezer, Washing machine
|Double Beds (2), Single Beds (3), Cots available (1), Dining seats for 8, Lounge seats for 8
|Linen provided, Towels provided, High chair available
|Private outdoor pool (unheated), Balcony or terrace, Private garden, BBQ
|Parking, Lift access, Suitable for people with restricted mobility, Wheelchair users
The Andalucia region
There are beautiful walks all around the area, with several National Parks within a short drive. Almijara y Tejeda Sierras.
Malaga city and airport are 40mins by car. The city has much to offer with the beautiful Cathedral, Picasso museum, tapas bars, restaurants and shopping.
The nearest beach can be found at Torre del Mar a 20 min drive.
40 minutes of the beautiful village of Nerja. Here you will find several beaches, many varied restaurants, bars and nightlife as well as the fascinating Nerja Caves, a major tourist attraction and famous in the world.
The city of Granada is 1.5 hours distance from here with the stunning Alhambra Palace and Moorish influence seen around the city.
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13 Sep 2013
"We loved the house, the view, the area and the welcome."
Sonia and Antonio gave us a lovely welcome and were very helpful throughout our stay. The house was down a winding track outside Competa, traditionally styled with lovely shaded areas with a fantastic pool and panoramic views. Easy access to Malaga, Granada and the coast. Once off the mountains good motorway travel. We loved the house and every minute of our holiday despite the lack of oven (good BBQ built in) and temperamental electricity at times. Would go back in a trice!
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Sofia R.
- 3 Years listed
65% Response rate
Calendar updated:09 Feb 2016
Based in Spain
- English

subset: commoncrawl


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The Checkpoint Crew is back after their two week hiatus, to talk all about OUTLAST Whistleblower, Wolfenstein: The New Order and Watch Dogs. Then in the second segment they share their fun stories about covering Anime North last weekend.
(Outlast, Outlast Whistleblower, PC, PS3, PS4, Watch Dogs, Wolfenstein: The New Order, Xbox 360, Xbox One)


text: Comments (10) + Add comment Comments (10) Featured AstroZombie1 + 1221d ago hahah no......... #1 Agree(2) | Disagree(9) | Report | Reply Wuu + 1221d ago Useless #2 Agree(3) | Disagree(1) | Report | Reply shutUpAndTakeMyMoney + 1221d ago I was an Nvidia fan until last week. They are some lying bastards.. http://www.youtube.com/watc... #2.1 Agree(3) | Disagree(4) | Report | Reply neogeo + 1221d ago slow. I need more POWER! #3 Agree(1) | Disagree(2) | Report | Reply ninjahunter + 1221d ago Eh, good enough to max out most games. Price isnt too shabby. But i feel like there are better alternatives. #4 Agree(1) | Disagree(0) | Report | Reply AKS + 1221d ago I've seen 7850s on sale on newegg in the ~$150 range, which would smoke the GTX 650Ti. BTW, I have two GTX 670 4GB cards in SLI, so this is not AMD v. Nvidia nonsense. I'm just saying there are better options for a similar price compared to this particular card. #5 Agree(2) | Disagree(1) | Report | Reply AKS + 1220d ago Here's an alternative that I'd recommend: http://www.newegg.com/Produ... It's maybe $10 more than the typical GTX 650Ti, but it comes with free 2-day shipping and is much more potent. About the same price, yet the difference in performance is substantial in the 7850's favor. #5.1 (Edited 1220d ago ) | Agree(0) | Disagree(0) | Report | Reply Eldyraen + 1221d ago You need to look at it from a technical standpoint: that's one tiny card and pretty cheap for being able to run most modern games as well as it does. No way I'd downgrade from what I have but the tech is pretty cool due to its size and price (and a nice physx option as they say--and if your main card does die can be a decent temporary solution while you pick up a new or get a fix). Something like that could easily be adapted for laptop use due to size and not inflate the price too much compared to more powerful options (it actually 'fits' laptops quite well). I could easily see something similar going into next gen consoles (size and price) which might not be 'much' in terms of what we pc gamers can achieve but is still a significant boost from current consoles and would bring 'low' settings for pc games up to a more modern standard ;) So the 'potential' is there as the article name implies but it comes down to how it (and other similar cards) are supported by the manufacturers. If something like the 650ti did become mainstream it would only benefit the pc gaming platform as a whole as its a very cheap, reasonably powerful option that could bring all the newer 'tech' some more limelight. The more new hardware becomes mainstream just means the rest of us get an even better experience once its fully supported. #6 Agree(1) | Disagree(0) | Report | Reply yeah0kchief 1221d ago | Spam dredgewalker + 1221d ago Based on the chart i saw at another site it seems like it's a teeny tiny bit better than my gtx 550 ti which is really disappointing. For a newer card it's supposed to be a lot better in benchmarks. #8 Agree(0) | Disagree(0) | Report | Reply Add comment You need to be registered to add comments. Register here or login Username Password Remember Rules & guidelines Login


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shader error
I tried to run a game on my computer and received the following Error: Shader model 2 video card not supported. The game requires 3D Video, System Requirements: Windows XP, Vista, or 7, 512 MB RAM1 Ghz, DirectX 9 compliant with Pixel Shader. My computer is. HP Pavilion a6238x. Microsoft Windows Vista Home Premium Edition Service Pack 2 32-bit.
I updated the graphis driver and the intel chipset. Not sure if i can update or need to purchase new video/graphis card. i did do all the updates on the intel website and on the hp wesite that were available for my computer and i still receive the error.....
Re: shader error[ Edited ]
03-24-2013 04:56 PM - edited 03-24-2013 05:14 PM
You will need to upgrade to a more robust video graphics adapter. Example: ASUS EAH5450 SILENT/DI/1GD3(LP) Radeon HD 5450
Please review: Installing or Replacing a Video Card
Microsoft MVP
Windows Expert - Consumer
Re: shader error
Thank you for the reply i will try that


text:
By Numeric Pipeline
Open iTunes to buy and download apps.
The first thriller by the indie studio that created the million-selling RUNAWAY saga!
A psycho is killing beggars alive in New York. A Y-shaped scar forms in the hands of seemingly unrelated people. The press and the media just don't care, so Henry White, a young NGO volunteer, will be the first to investigate the crimes with his friend Cooper. They are two of the three playable characters in Yesterday, the third being none other than the enigmatic John Yesterday, who is dragged into this twisted plot after his memory is completely wiped.
How far will you go to find out who John Yesterday is?
● An adult, noir thriller full of unexpected twists and turns.
● A magnificient visual style that mixes videogames, movies and comics.
● An innovative interface based on innumerable blow-ups. A perfect game for your tablet!
● Useful and well-designed help for players, via a hotspot marker and text hints.
● A rich musical score that not only fits but also enhances the story.
● A storyline full of discrete references and tributes to movies, series, games, music and novels.
● Included languages: English, French, German, Spanish, Italian.
"An experience you'll be unlikely to forget." - Joystiq
"With all the polish of a major, mainstream release, Yesterday is not a game to be missed." - Gamezebo
Compatible only with iPhone 4, iPod 4, iPhone 4S, iPad, iPad 2, new iPad.
Minimum required : iOS 5. You should update your OS to enjoy the game.
About Pendulo Studios
About Numeric Pipeline
What's New in Version 1.6
Bug fixes for new devices
Customer Reviews
Only 4 and here is why
The game itself is absolutely fantastic! Not too easy but not too hard. With the options of hints if you get stuck. The story itself was pretty incredible with such a twist, I found myself getting emotionally involved and I must know what happens next! My only issue is, the price with the game length. I don't believe that if I can beat a game in less than a day( and that's continuously going back to it throughout the day while having to work and everything else) that it should be any more than say $5? I mean yes this game was great but for the length of it (especially after playing the demo so cutting that part down to about 2 minutes). If you have the money I do recommend this game for people who enjoy point & click and escape games. Now my expectations for other games are going to be raised :p well done!
iPad Air 2
I just wanted to say the problem everyone had been having with the 6 and 6 plus is happening on my iPad Air 2. I can't get past the choose a box to save your game screen. PLEASE FIX, I've had this game a while and now that I'm psyched to play it, I cannot.
Update: first box causes the freeze, second box started the game.
Didn't a first but now I do.
It started off slow and a bit hard for me but when it got past the first chapter I fell in love. Great story line loved the illustration and the voices. Can't wait until #2
Customers Also Bought
- $6.99
- Category: Games
- Updated: Feb 28, 2015
- Version: 1.6
- Size: 1.11 GB
- Languages: English, French, German, Italian, Spanish
- Seller: Numeric Pipeline
- © 2012-2013 Pendulo © 2014 Numeric Pipeline. All rights reserved
Compatibility: Requires iOS 5.1.1 or later. Compatible with iPhone, iPad, and iPod touch.


text:
More than a few years, the issue of escaping quotes in interpolated strings was discussed at some length. Eventually, the list came to a consensus that we should escape them by doubling them, since this would be (or at least very nearly be) backwards compatible and provide a simple solution for this much-wanted feature.
Geir had working code for this and even posted a test jar, IIRC. So, many of us thought that this had made it into the 1.5 codebase. But the code never got checked in and may have been lost. Assuming Geir can't find the old code or the time to duplicate the effort, we should still try to implement this.
This issue is open to remind us of that. If i get around to digging up links to the relevant threads, i will post those in the comments of this issue.
Issue Links
- relates to
VELOCITY-709 String literal "\\" parses incorrectly
- Resolved
|Time In Source Status
|Execution Times
|Last Executer
|Last Execution Date
|1014d 1h 23m
|Nathan Bubna
|28/Mar/10 18:30
This is a question for the email@example.com list. It is not related to this issue. (Hint: use formal syntax)
Hi together,
I'm not sure whether this is the correct way to ask or if that is related but it would be really helpful if you could point me to the correct direction. After upgrading the velocity version to 1.7 I get:
Lexical error, Encountered: "u" (117), after : "" at velocity/mediaImpexTemplate.vm[line 58, column 50]
engine.getTemplate("mediaImpexTemplate.vm", "UTF-8");
the respective line is:
57: ## specifically remove any media code weve been given to ensure the change will sync
58: REMOVE PGMedia;code[unique=true];$catalogVersion[unique=true]
Any idea what I'm doing wrong here?
|Default workflow, editable Closed status [ 12551670 ]
|jira [ 12552545 ]
|jira [ 12406541 ]
|Default workflow, editable Closed status [ 12551670 ]
|Open [ 1 ]
|Resolved [ 5 ]
|Fix Version/s
|1.7 [ 12313453 ]
|Fix Version/s
|2.0 [ 12310291 ]
|Fixed [ 1 ]
Thanks, Jarkko!
This issue relates to
|velocity-555.patch [ 12439986 ]
This special patch implements a few things:
1. Backslashes are treated as regular characters in string literals (except when user defines Unicode characters). Thus e.g. #set($foo = "\") works.
2. Double and single quotes can be escaped by repeating them. #set($foo = "yeah ""YEAH"" yeah!") $foo would print yeah "YEAH" yeah!
Thus this patch should more or less fix issues related to
VELOCITY-587 and VELOCITY-709 as well.
All tests pass but these changes may break some existing user templates. Careful review is needed before commiting this.
|Original Value
|New Value
|Fix Version/s
|1.6 [ 12310290 ]
Lacking a champion for this, i don't think we can plan on this for 1.6.


text:
Wednesday, November 14, 2012
0 Comments | Copyright: IANS
Huma Qureshi's first two films were appreciated and she is getting good offers too. Contented with her career, the actress doesn't see herself as an outsider in the film industry.
"I don't feel I am an outsider. I was already shooting for other films even before the release of my first film 'Gangs of Wasseypur' (GOW). While shooting for GOW, I was simultaneously shooting for Vishal Bhardwaj's 'Ek Thi Daayan', and while shooting for 'Luv Shuv Tey Chicken Khurana', I was shooting for Nikhil Advani's 'D Day'," Huma, who is from Delhi, told IANS.
She started as a model and featured in TV commercials like Vita Marie, Saffola Oil, Mederma Cream, Pears Soap and Nerolac.
Talking about movies, she said: "It's an exciting new phase. Both parts of my first film received critical acclaim, 'Luv Shuv...' was also appreciated by many. I hope it continues to be like this."
"Ek Thi Daayan" and "D Day" haven't come out yet.
She considers herself lucky to have bagged films with established filmmakers.
"I am blessed to have got a chance to work with directors like Anurag Kashyap, Vishal Bhardwaj and Nikhil Advani at such an early age. Moreover, good scripts have been coming my way so I am really excited about it," said the 26-year-old who doesn't want to restrict herself to doing a certain kind of role.
"I have tried to be different in each of my films - be it 'Gangs of Wasseypur' or 'Luv Shuv Tey Chicken Khurana'. My roles in other two films are also different. I can't put myself in a box and be an actor," she said.
When it comes to looks, Huma is different from the typical Bollywood actresses and she says she isn't trying to fit in anyone's shoes.
"I agree that I am different from others. I am not trying to fit in someone else shoes. I am being honest to myself. The audience is loving me the way I am and that's most important for me," she added.
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text: Winchester 94 Lever Action Carbine Top-eject made in 1979, 30-30 Win Listed in category: Guns > Rifles > Winchester Rifles - Modern Lever > Model 94 > Post-64 /UserImages/5263/921862684 4577220.jpg /UserImages/5263/921862684 4577221.jpg Item Details Condition: Used - See Item Description Item #: 921862684 Caliber: .30-30 Winchester Location: TX SKU: Have one to sell? Sell Now! Sell it yourself, Ship it yourself, or use a GA DropOff Location! Classified Ad Details This listing is no longer available or has been sold. Price: $495.00 Login/Register to Buy Shipping: $30.00 Payment Methods: Return Policy: No Returns Seller Details (More items from Two Wright Arms Co) Name: Two Wright Arms Co Seller Since: Oct. 2002 User Level: Trusted Seller FFL Dealer: FFL Dealer Positive feedback: 100% View Seller Security Verification (What's this?) This seller has completed 1248 transactions Address has been verified and will be sent on request at completion of transaction Click here to request seller's GunsAmerica Verified Address Description Shipping and Payment Additional Information Winchester Model 94 Lever Action Carbine, top-eject made in 1979, 30-30 Win with 20" round barrel, blue steel, 6-round tubular magazine, front blade sight, rear elevator sight, smooth walnut stock and forend, receiver is a little rusty and spotty, bore is excellent, action is fully functional and smooth, metal and finish shows minimal handling, overall very good condition for shooter grade gun. ALL PURCHASES MUST BE CONFIRMED BY PHONE. 30.00 shipping (insurance included). Call to confirm purchase and arrange payment and shipping. Trades Accepted: All trade offers are considered. We're looking for cowboy guns, U.S. military guns, muzzleloaders, and antiques, but we'll trade for almost anything. Call for details. We believe in customer service. Once you've arranged payment for your purchase, just give us your FFL dealers name and number, we'll handle the transfer. CALIFORNIA RESIDENTS NEED TO CALL BEFORE PURCHASE. With any firearm, additional photos can be provided if requested. New In Box firearms are warrantied by the factory. Used firearms are sold AS IS, without any warranty or guarantee, expressed or implied. Two Wright Arms Co. has been in business since 1988. Our store has many more guns than we can list. Call or check us out on our website. We buy, sell & trade, and all offers are considered. We deal in all types of firearms. We are located at 1286 Hwy 199 E, Springtown, Tx 76082, just northwest of Ft. Worth, Texas. Credit card users add 3% to purchases. Returns will be charged all credit card and shipping costs. No returns on new guns. Layaway available for in-store purchases only. Call to confirm all purchases.


text:
About the only thing we do not carry is sheet metal body parts. Check the status of your order via our website. We ship Subaru Cam Follower parts out of warehouses located across the country. Stop buying from Subaru Cam Follower parts stores that outsource their phone support abroad. Good customer service is important to us. We love to help you order Subaru Cam Follower parts online. Call us at (800) 240-4620 with any questions regarding Subaru Cam Follower parts.
Robert F. - Fayetteville, AR: Thank you for providing the quote for an air conditioning system for my '85 BMW 318i. I very much appreciate your time. I've previously purchased from you and have been most satisfied with your products and service. You do what you say you will do!! I like that!!


text:
Saucony Fastwitch 6 Runblogger Review
- By Taro
- April 26, 2013
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Based on the feedback we've heard from customers, the Saucony Fastwitch 5 was a bit of a dud for some fans of the Fastwitch series. We're happy to see a … Continue Reading →
Saucony Fastwitch 6 Sneak Peek
- By Matt
- June 14, 2012
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The Fastwitch is a favorite race shoe for runners with a touch of overpronation. Those of you who like the light and fast feel of the current Fastwitch have reason … Continue Reading →


text:
Orlando Jose
Funding via MiCredito
With the idea of diversifying his crops, Darwin will use the loan that he is requesting to plant melons and install an irrigation system that he needs to keep his crops in optimal condition and obtain production that is of good quality. Another one of his projects is to sell tabasco chiles so that he can gradually grow in a line of business that has yet to be exploited in León.
Success!! The loan was 100% repaid


text:
Forgotten Password?
Friday, January 11, 2013 8:40 AM EST
Torrington police ask public for leads on hit-and-run accident
TORRINGTON -- Torrington police are asking for the public's help in solving a hit-and-run crash on Torringford West Street on Tuesday.
The crash happened at 5:40 p.m. on Torringford West Street by Kennedy Drive.
Police described the suspect vehicle as a light-colored sedan, possibly a Toyota, that may have minor to moderate damage on the front bumper.
Torrington police are looking for anyone who many have additional information regarding this incident.
Anyone with information is asked to contact Officer Nicole Santiago at 860-489-2007.


text:
Casa Martinez was a great stay views for days with lots of privacy!! There was some construction going on next door & down the street but that is not a permanent thing. Home is laid out so that 3 couples could also travel together and have ample amount of privacy. A bit more difficult for little children since the rooms...
Rates are calculated based on the latest information provided. Please contact the manager/owner to confirm actual rates for your requested dates.


text:
Art-Trade: Shoko and Zevran by VelvetRueWatch
©2010-2016 VelvetRue
OMMMGGGGGGGGGG!!!! SO CUTE AND HOOOIT! (Big fan of Zevran....)
Wow that is wonderful!
I think that massage led to something else XD
Zevran is so hot! A beautiful picture
Oh, I like it! This pictire's full of passion and tenderness...
So romantic ♥_♥
Hot Zev! Jedi Padme aproves!! +100 I do love the Mahariel/Zev pairing, as well. something so sweet about it.
vale, no me habia dado cuenta de que hay un comentario en español... xD jajaja
bueno, pues en los 2 idiomas, me encanta el dibujo
bueno, pues en los 2 idiomas, me encanta el dibujo
veeery beautiful! ^_^ definetely a fav.
This is a beautiful kiss scene! Kisses are HARD to draw, and this is beautiful and poignant!
Oh that's lovely! Can get enough of this.
Jo que bonito *.*
Awww! That's so sweet! <3<3<3 I love it!
wow! really nicely done!
How beautiful! Great work!
That's so pretty!
this is very sweet!
and the warm colors fit very well to the ambiance
and the warm colors fit very well to the ambiance
Oh this is gorgeous!
oooooo i love it !!!


text:
The White House Inn4 Self rated
Penhallow, ,, Truro, TR4 9LQ
Price FromView Rooms
- Excellent
- 33 guest reviews
"One of the best places I have stopped at really relaxing and friendly and very helpful, good food and drinks.I will be going back for a week..."
"This place had a lot of good reviews so whilst down Cornwall for the weekend decided to book in for one night. We could not believe how fant..."
"Booked as a last minute decision to extend a short break with my boyfriend. Fab value, friendly staff and ex value. The room was spotless an..."
"I've stayed in many pubs for business & this pub was far superior than any other ive stayed in. Great service, great food & excellent rooms...."
"Lovely court yard with fountain and a BBQ area lit up in a green glow. Huge room with lovely soft towels. Friendly staff and a great drink...."
About the hotel
We are only seven miles from Newquay and Truro and less than three miles from the nearest beach and town of Perranporth so if you're looking for a central location without the hustle and bustle of a town then we are a perfect pick for your needs. We are a family run business focusing on family values but we are also ideal for your business needs. We have the best of both worlds here with our play areas indoor and out, our mini golf and electric go kart track but the lodge itself is separate from the main bar and extremely tranquil.
Our extensive menu focuses on home cooked, good value food with a kid's menu and changing specials board. Please be advised we do get extremely busy during peak summer season. We also hold Saturday entertainment nights with some fabulous local talent - however you cannot hear the live music from the comfort of your lodge room.
Read MoreLess
Room Availability
Showing Wednesday 10 February 2016 to Thursday 11 February 2016Change Search
Facilities Show/hide
- Other
- Wedding Licence , Lift to all floors
- Parking
- Car parking available onsite
- Dining
- Restaurant , Bar
- Family friendly
- Children's Facilities - Indoor
- Business
- Wi-Fi Available In Public Areas
Useful Info Show/hide
- From 14:00 hours
- Until 10:00 hours
- 24/07/2014 to 31/12/2023 - Please note, payment will be taken on the card provided prior to arrival. The price shown is based on the occupancy and dates you have searched for. Prices and availability are subject to change based on the arrival date, number of nights and occupancy searched for. All prices are inclusive of all local taxes.
- Pets are not allowed
Customer Reviews
Our reviews are from genuine LateRooms.com customers. We verify that the customer has stayed before leaving a review.
94% would recommend it to a friend
Customer service
Food quality
Room quality
2 night stay at white house inn
One of the best places I have stopped at really relaxing and friendly and very helpful, good food and drinks.I will be going back for a weeks break with wife.Also recommend Ideal for family accommodation.
Read More Less
Amazing Accomodation & Breakfast
This place had a lot of good reviews so whilst down Cornwall for the weekend decided to book in for one night.
We could not believe how fantastic our room was - It was advertised as executive double suite and by god was it that and more. The bathroom was huge, the sitting room huge and the bed was beautiful and so comfortable. Normally you are just there to crash but you could have stayed in this room for the holiday it was that nice. We decided to have an evening meal in the hotel restaurant and again fantastic value and beautiful, mixed grill for me (£14.95 !!!) fab value and an 8oz Sirloin for my wife all beautifully cooked (Well done John the Chef - who I met at last orders). Lovely head waitress and staff were professional & polite, a credit to this place. Breakfast was to the same standard and plenty of choice. I was also impressed that they have taken the time to add to each meal on menu things like nuts, gluten, egg etc etc so anyone with allergies could see at a glance if it was ok for them (both breakfast & dinner menus). I can honestly say I didn't want to leave this place. Perfect for families as it has a comprehensive indoor play area, soft play area, pool, air hockey and more. outside a lovely patio and outdoor play area including a little crazy golf course and go karts for the nippers. Would highly recommend The White House Inn to anyone and can't wait to return - well done all !!!
Read More Less


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YORBA LINDA – Situated among the four faces of the Mount Rushmore presidents were Michelle Hanscom and her two boys, posing arm in arm for a photo in the lobby of the Nixon Presidential Library & Museum.
In honor of Presidents Day Monday, the library offered guests free admission, cherry pie and an opportunity to meet interpreters of presidents George Washington, Abraham Lincoln, Thomas Jefferson and Theodor Roosevelt.
"I wanted to teach my children how important it is to honor the presidents of the past," Hanscom of Huntington Beach said. "This is the reason why they need to know that they have the day off of school."
Jefferson interpreter Dale Reynolds is in his fifth year teaching audiences at the Nixon Library what a "brilliant and smart" man Jefferson was.
"The idea of portraying this great man is to get the information out," Reynolds said. "I have become a more active citizen for learning the tale I've learned about Mr. Jefferson."
The 37th president, Richard Nixon, was not forgotten in the day's history lessons.
"I want to see where he grew up and his home," Hanscom said. "I want to show them (my children) where he was buried and my son wants to see the helicopter."
A question and answer forum featuring all four presidential interpreters in the library's East Room allowed children and guests to ask questions and learn more about each president's accomplishments.


text:
With 1.7 million freelancers, we'll match you with the perfect talent.
The client has made the following changes to the job.
Bidding period ended early.
Client prefers freelancers from:
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a different location.
an online platform to connect student organizations to with student producers to create vivid images, that capture student life on campus like never before. Our goal is to serve as a one stop shop for student videographers and photographers to expand their network and connect with their largest pool of potential clients on university campuses, student organizations.
We are looking for a vibrant, innovative, and proactive individual who is passionate about tech start-ups and web development.
We are looking for someone who can develop a website with the following:
- social media
- digital media hosting
- crowd-sourcing
- video hosting
- search engine optimization
- web analytics
Experience in digital-media web development is preferred but not required. Overall we are looking for someone to round out our team of passionate young entrepreneurs and assist in creating the only student generated video platform online.
Job Description:
Your responsibilities:
- Review business r...
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text:
About this listing
Hello! I am renting a private room with double bed in a sunny bedroom with a big closet in a big new three bedroom house. This bedroom has no TV and shares the bathroom with another bedroom :)
Space where guests can cook their own meals
Towels, bed sheets, soap, and toilet paper
In the building, free or for a fee
The Space
I am renting a fully furnished bedroom, double bed with new mattress, or the complete house fully furnished just as you can see in the pictures, the house has wifi.
The house is new, you will have access to another tv with independent cable in the living room, dining room and fully equipped kitchen, fridge, toaster, sandwich maker, microwave, electric toaster oven .. everything you can think of, we have it!! washer and dryer for your clothes! Parking if you put your car in the garage but to be honest there is no need, it is super safe
Rest assured that whatever you need to make your stay in Queretaro something fun and memorable, you just need to ask and I will be glad to help :)
The house is two blocks from main street where you can take 3 buses that will get you close to what you need, we are 15 min from downtown and 4 min away from tec de monterrey (one bus takes you door to door) . We have a supermarket nearby, delicious tacos just across the avenue and a store across the avenue too.
Do not hesitate, if you'll be in Queretaro for work or you are a foreign student in Tec this is the place to stay. The house is large, we have electric fence, walls three meters (we do not need them but the house looks really cute), the neighborhood is really quiet and safe, not many children around.
Any questions just send me a message!
Guest Access
You will have access to all the amenities in the house
Interaction with Guests
I currently do not live in the house although I am the owner. will be more than happy to help!!
The Neighborhood
Quiet new semi private neighborhood!!
Getting Around
We are three blocks away from the main street ehre three buses will take you anywhere around :)
Absolutely no smoking in the premises. A cleaning fee up to 300 USD could be charged. Please keep the noise down after 10 pm.


text:
Wise Architecture: Y House
HL Architecture: Pavilion for an Artist
Steven Holl Architects: Nanjing Sifang Art Museum
Arquitecturia: Museum of Energy
Laban Dance Hall
The curving facades are clad in transparent or translucent glass panels, depending
on whether the spaces behind them require a view. Lime, turquoise and magenta, semi-translucent polycarbonate panels, punctuated by large clear windows, are mounted in front of the glass panels, giving the building a pale magical glow.
Colors determine the rhythm and orientation both inside and outside the building.
The shadow images of the dancers play an active part of Laban's architectural
identity. By day, the regular activities of Laban, training, rehearsals, research and workshops, are semi-visible through the walls from the outside. By night, Laban acts as a coloured lantern or beacon, radiating light out onto the surrounding area and along Deptford Creek.
Studio MK27: Decameron
Nelson-Atkins Museum of Art in Kansas City extension: BLOCH building


text:
Photos & Multimedia
Photo Gallery
Victory Photo Gallery...contains selected photos from Perry's Victory and International Peace Memorial, including scenic views of the memorial, an inside look at special events, and images from our historic archive.
Panorama from Memorial Observation DeckHigh Quality 1024x768 (1.6MB)
Medium Quality 800x600 (0.6MB)
The observation deck gallery captures the panoramic view of western Lake Erie that one would see from atop the memorial column. From this height of 352 feet Middle Bass Island, North Bass Island, Johnson's Island, Kelley's Island, Pelee Island in Canada, and the Ohio mainland of Catawba Point and Marblehead Peninsula are visible. On a clear day it is possible to see as far as Detroit, Toledo and Cleveland.
South Bass Island Map
South Bass Island Map... A map of the roads and parks on South Bass Island, home of Perry's Victory and International Peace Memorial.
Illustrated Film
The Naval War of 1812 Illustrated... To commemorate the Bicentennial of the war, the American Society of Marine Artists has released a seven-part video, featuring the finest collection of art created over the last two hundred years to illustrate this vital era. The film is offered free to the public as an educational and entertainment documentary.


text:
HOUSTON -- With question marks surrounding three of their top players, the Rockets met with Trevor Ariza on Thursday in hopes of bringing the Los Angeles Lakers forward to Houston, The Associated Press has learned.
Rockets general manager Daryl Morey met with the free agent in Las Vegas, according to a person familiar with the situation who requested anonymity because the negotiations were ongoing.
Morey and David Lee, Ariza's agent, did not immediately return messages left by the AP. The meeting was first reported by KRIV-TV in Houston.
The 6-foot-8 Ariza averaged 8.9 points, 4.3 rebounds and 1.8 assists for the Lakers last season, which ended with the NBA championship.
With at least five teams pursuing Ariza, the Lakers appear unwilling to pay him more than the $5.6 million mid-level exception.
The Cavaliers, Clippers, Raptors and Blazers also are showing interest in Ariza. Portland and Toronto each could offer more than the mid-level exception.
The Rockets could use a versatile forward with a perimeter touch, especially if free agent Ron Artest decides to play elsewhere.
Houston star Tracy McGrady is already expected to miss much of next season as he recovers from a knee injury and center Yao Ming's foot injury could keep him out indefinitely.
Artest's agent, David Bauman, said in a phone interview that he's talked to Morey "eight or 10" times since free agency began early Wednesday, but the two sides have yet to discuss specific numbers or contract details.
"We knew this was going to be a deliberate negotiation," Bauman said.
Artest is looking to cash in after earning $7.4 million in a productive first season in Houston, where he averaged 17.1 points, 5.2 rebounds and shot 39.9 percent from 3-point range.
Bauman also said several teams who reached the postseason have contacted him about Artest. He said the volatile forward has exchanged text messages with "various superstars around the league, all from playoff-caliber teams, all 'final 8' teams in the NBA."
Bauman would not specify which teams have contacted him and said that Artest had not had "face-to-face" contact with Cleveland star LeBron James.
The Cavaliers would be an intriguing possibility for Artest, since he played for Indiana when Cleveland coach Mike Brown was an assistant there and the two have maintained a good relationship. The Cavaliers have already added center Shaquille O'Neal in the most significant move of the offseason so far.
Information from ESPN The Magazine's Chris Broussard and The Associated Press was used in this report.


text:
The hotel was fine but one particular member of staff was very rude and abrupt. She was very unhelpful and effectively told me to go away as she busy. Not the kind of service I expect in a hotel. She also made no allowances for the needs of an elederly member in my family and certainly did not offer to... More
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Home > Categories > Category
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McDonald's - Gorman School Rd. - Gorman, CA
in McDonald's Restaurants
A McDonald's located right off of Interstate 5, in the Tejon Pass.
posted by: bluesnote
location: California
date approved: 10/3/2014
last visited: 3/20/2015
McDonald's - Quaker Hwy - Uxbridge, MA
This McDonald's is on Quaker Hwy near the Worcester-Providence Turnpike (route 146).
posted by: Lat34North
location: Massachusetts
date approved: 10/2/2014
last visited: 8/2/2015
McDonald's - County St - New Bedford, MA
A small McDonald's located on County St at Elm St, New Bedford, MA.
date approved: 9/28/2014
last visited: 8/31/2014
McDonalds Marszalkowska - Warsaw, Poland
This is a McDonalds restaurant in Warsaw, the capital city of Poland
posted by: Torgut
location: Mazowieckie, Poland
last visited: 6/10/2014
McDonalds - 1900 Diamond Hill Rd., Woonsocket, RI
Mc Donalds Restaurant - 1900 Diamond Hill Road, Woonsocket, RI 02895
posted by: walkingwildly
location: Rhode Island
last visited: 5/25/2015
McDonald's rue De La Faune (Saint-Emile), Québec, Canada.
Petit McDonald's dans le secteur nord de la grande Ville de Québec, profitez en pour y faire un arrêt.
posted by: campeur1967
location: Quebec, Canada
date approved: 9/22/2014
last visited: 11/16/2015
McDonald's Boul. Hamel est, Québec, Canada.
Un beau McDonald's rénové, tout près de notre futur Amphithéatre de Québec, prenez la rue Soumande au coin, elle vous y amènera, profitez en pour y prendre un petit lunch.
last visited: 4/5/2015
Gosnells McDonalds - Gosnells, Western Australia
A newly opened Maccas southest of Perth
posted by: blingg
location: Western Australia, Australia
date approved: 9/12/2014
last visited: never
McDonald's stade - Clermont-Ferrand - France
McDonald's restaurant at the entrance of Marcel Michelin stadium /\ Restaurant McDonald's à l'entrée du stade Marcel Michelin
posted by: JMRetSB
location: Auvergne, France
last visited: 9/9/2014
Mc Donald's Ruoholahti - Helsinki, Finland
This is a Mc Donald's restaurant in Ruoholahti district, in Helsinki, capital cinty of Finland
location: Finland
date approved: 9/1/2014
last visited: 12/22/2015
McDonald's - W. Dillion Rd. - Louisville, CO
A McDonalds in a busy shopping center.
location: Colorado
date approved: 8/29/2014
McDonald's - Luxembourg City - Luxembourg
McDonald's in the middle of the City (tourist area).
posted by: eilers1
location: Luxembourg
last visited: 11/25/2015
McDonalds's - 6th St. - Wellington, CO
A Mcdonald's right off of Interstate 25.
date approved: 8/27/2014
McDonalds's - S. Golden Rd. - Golden, CO
A McDonald's in a small town just outside of Denver.
McDonald's #4865 - I-79 / Exit 45 - Canonsburg, Pennsylvania
This McDonald's is located at 100 Bobby Vinton Boulevard, off of I-79 at Interchange 45 in Canonsburg Borough, Washington County, Pennsylvania
posted by: outdoorboy34
location: Pennsylvania
date approved: 8/24/2014
McDonald's #11703 - I-70 / Exit 15 - Washington, Pennsylvania
This McDonald's is located at 1294 West Chestnut Street (US Route 40) in North Franklin Township, Washington County, Pennsylvania
McDonald's #15971 - I-70 / Exit 17 - Washington, Pennsylvania
This McDonald's is located at 999 Jefferson Avenue (State Route 18) in the City of Washington, Washington County, Pennsylvania.
McDonald's - Stockholm, Sweden
McDonald's in the centre of Stockholm.
posted by: marcius
location: Sweden
date approved: 8/23/2014
McDonalds - I-81 Exit 245 - Harrisonburg, VA
About mile southeast of I-81 Exit 245
posted by: vhasler
location: Virginia
date approved: 8/9/2014
McDonald's - S. La Cienega Blvd. - Los Angeles, CA
A McDonald's located west of the city center.
date approved: 8/8/2014
McDonalds - I-81 Exit 222 - Staunton, VA
I-81 Exit 222 on the east side in combo with a BP gas station.
McDonald's Restaurant - Maasbree, Netherlands
Een mooi McDonalds Restaurant in Maasbree, vlakbij de A67
A nice McDonalds Restaurant in Maasbree, near highway A67
posted by: koetje1977
location: Limburg, Netherlands
last visited: 4/7/2015
McDonald's - Waterloo Rd. - Columbia, MD
This McDonald's is located in a busy shopping center.
location: Maryland
date approved: 8/5/2014
last visited: 8/9/2014
McDonald's - Concourse H - Chicago, IL
This is one of many McDonald's inside Chicago's O'Hare International Airport.
location: Illinois
last visited: 10/31/2015
McDonald's - California Science Center - Los Angeles, CA
This McDonald's is located in the food court of the California Science Center.
date approved: 8/4/2014
Copyright (c) 2016 Groundspeak, Inc. All Rights Reserved.


text:
News for Thursday, February 21, 2013
Match Play: Second-round tee times, pairings
A look at the second-round tee times at the WGC-Accenture Match Play Championship on Friday:
Match Play: Sean Martin's second-round predictions
Our Sean Martin makes his bold predictions for the second round at the WGC-Accenture Match Play Championship:
Rude: Tiger falls victim to man with 'nothing to lose'
From his loss in the 1996 U.S. Amateur to countless rounds at Isleworth, Charles Howell III says he had never beaten Tiger Woods. On Thursday, Howell changed all of that by playing carefree.
Notebook: Round 1 will need a third day to complete
Lost in the tremors of that shocking one-two punch – losses by both Rory McIlroy and Tiger Woods – is that the first round of the Accenture Match Play Championship will need a third day to complete.
McIlroy's poor iron play leads to early exit
Rory McIlroy's poor iron play and Shane Lowry's stellar short game allowed Lowry to upset McIlroy in the first round of the WGC-Match Play Championship on Thursday.
Tracker: Tiger, McIlroy ousted in Round 1 of Match Play
In what has to be considered a double knockdown blow for the tournament, the world's top two players will be heading home a bit earlier than expected. Here's how it happened.
Scores: First-round results from Match Play
A look at the results from Thursday's completion of the first round at the Match Play Championship.
Van Pelt, Garcia advance after false start at WGC
Bo Van Pelt needed just one 8-iron and one putt from 45 feet on Thursday to make his win over John Senden official at the WGC-Accenture Match Play Championship. Call it another strange effect of Wednesday's snowstorm.
Henley turns 'butterflies' into Schwartzel upset
Russell Henley performed admirably Thursday against Charl Schwartzel, winning in the first round of the WGC-Accenture Match Play Championship. Henley thrives on such pressure.
Notes: DeChambeau key in Gregory's SMU rebuild
Bryson DeChambeau is SMU's top player, but the way he plays the game is a little out of the ordinary. He's also part of an SMU team looking for a return to national prominence.
In this issue: Feb. 22, 2013
Inside the Feb. 22, 2013 issue of Golfweek:
Sooners one of early spring's hottest teams
Oklahoma has been quite the surprise team this spring. In the Sooners past two tournaments, played in a week's time, they finished first and second, respectively.
Stacy Lewis shoots 63, leads in Thailand
Stacy Lewis shot a 9-under 63 in the first round Thursday to take a three-stroke lead at the LPGA Thailand.


text:
He's supposed to be a tall and skinny guy
This member has provided no bio about themself...
He's supposed to be a tall and skinny guy
I'd play turok source, That'd be badassery lol
oo look another ******* zombie game
ooo look, more ******* zombie ****
Ive been waiting so long for a dinosaur HL2 mod. Downloading
I'm only an artist.
I am in demand for this mod.
fully emersed 3d pokemon world mmo!
Thats because most franchises make the games for Cha-ching, money, where as the modders do it for the enjoyment of it.
Looks alot better than the old beta
This would been awesome
you should talk to the guys at Trescom real soon, I think there site might be closing and they've got tons of experience with tresspasser.
I have a problem, when I download it, I get the old demo version with the trex in the middle of the room, not the updated version.
Oh cool, cant wait.
The story made me have a lil lol, but the work done is really good though.
Lmao, I remember following this years ago when it was still a Half Life 2 mod. I wonder how that woulda turned out if you guys stayed on it.
Wow I remember following this mod years ago when it was supposed to be a Half Life 2 mod, I think they really could done something super if they stayed on it. I remember the old work they had, it was just getting really good then they scrapped it all in favor of the unreal engine. Made me feel sad when that happened.
Wow. This looks awesome.
You might want to look around for recruiting people that would like to join in pokemon communities. See if you can find some talent among the Poke lovers.
Heres some Poke sites. Look for talent in the forums. Advertise man, look in other gaming and moddind forums with signature advertisements for your mod and stuff.
Have you begun work on AI for the dinosaurs and have any of their actions and abilities been drawn out?
That sounds interesting rocketman.
I'm a great artist willing to concept work, I lack others skills(though would like to learn some, 3d modeling perhaps), would be willing to join to help, this is interesting, and would maybe be a step into focusing on a bigger Pokemon gaming experience.
Anyone let me know if you are working on a pokemon mod. I offer support. Message me.
This mod had so much potential. I think its dead though, which is really sad.
Hey, I want sum people to play this game with me, cuz I cant find anyone. My steam is numerodose. If anyone is getting a game started, hit me up
I hope it isnt dead
haha i have one of these knives
Im looking foreward to this. I'd help but I dont really have any skills other than my artistry and concepting. I have some ideas that you might wanna have a look at. Awhile ago I made a petition for a pokemon MMO and Ihave some suggestions for a more mature game. If you send me a message i can send you a link to it. Theres a vast ammount of ideas myself and a few others came up with that you may want to look into and pull into your game. I also dont think you should realease the game with all 150 at once. It'd take to long and the mod would dissapear before it ever got finished. Release a few betas starting with about the first 25pokemon, and then release more pokemon with the next releases. Just message me if theres anything i could help with.


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Father: James F CARR b: CA 1814 in South Carolina
Mother: Martha E WATTS b: CA 1824 in Alabama or Georgia
Marriage 1 Lella Lorene DIXON b: 6 SEP 1863 in Nicholsville, Marengo, Alabama
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text:
100 Doors of Revenge is a new puzzle game from Gipnetix Games, the creators of 100 Doors 2013 and 100 Room. It is considered a sequel to 100 Doors 2013 and is played in the same way. Your goal is to solve the puzzles to unlock the door and travel up to the next floor. As of this post there have been 24 Doors released for 100 Doors of Revenge. Below is a walkthrough for each level.
- For levels 1 through 5, click here.
- For levels 6 through 10, click here.
- For levels 11 through 15, click here.
- For levels 16 through 20, click here.
Level 21 / Door 21 Answer: Enter the code "33322" on the keypad. How we solved it: The X and Y above the door is the clue. Using the pattern on the door, X=3 and Y=2. Since X=3, there are 3 Xs = 333; od since Y =2, there are two Ys = 22.
Level 22 / Door 22 Answer: Enter the code "3759" into the keypad. How we solved it: Press each spider (it will drop from the web). Count the number of presses it takes each spider before it goes back up to it's original spot.
From left to right:
- 1st spider = 3
- 2nd spider = 7
- 3rd spider = 5
- 4th spider = 9
Level 23 / Door 23 Answer: Enter the code "10101020" into the keypad. How we solved it: The hint above the door asks you to add up the roman numerals in each row.
Press the keypad and enter 10101020.
Level 24 / Door 24 Answer: Enter the code "698820" into the keypad. How we solved it: The hint asks you to find the hidden numbers in the room going from top to bottom. There is a 6, and a 9 below it, linked up above the light. There is an "88" on the door handles. There is an XX on the floor mat which is 20 in roman numerals.
Congratulations! You have completed the levels 21 through 24 of 100 Doors of Revenge. Continue to levels 25 through 30.
Related Posts
Tags: 100 doors 2013 revenge, 100 Doors of Revenge 2013, 100 doors of revenge 2013 cheats, 100 doors of revenge 2013 guide, 100 doors of revenge 2013 level 21 answer, 100 doors of revenge 2013 level 22, 100 doors of revenge 2013 level 23 answer, 100 doors of revenge 2013 level 23 cheat, 100 doors of revenge 2013 level 24, 100 doors of revenge 2013 walkthrough, 100 floors of revenge 2013, 100 floors of revenge answer
2 Responses to 100 Doors of Revenge Walkthrough: Levels 21-24
Thnx for posting the level helpbc it helped me really well wen i got stuck on a level thnk u very much cant wait fod more doors to come
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Replogle Geographer Dry Erase 12-inch Diam. Tabletop GlobeItem # HN-RG076
- 12-inch diameter; 16-inch height
- Blue oceans with green land masses
- Metal base with a silver finish
- Silver finish metal semi-meridian
- Write-on/wipe off surface works with dry-erase markers
Similar Globes
Firenze Italian Style 20-in. Diam. Floor Globe Bar
Replogle Hastings 12 in. diam. Tabletop Globe
Replogle Carlyle 12-inch Diam. Tabletop Globe
Replogle Explorer 12-inch Diam. Tabletop Globe
$49.95 - $55.50
Replogle Traveler 12-inch Diam. Tabletop Globe
Replogle Commander II 16-in. Diam. Floor Globe
Recommended Accessories
REVIEW SNAPSHOT®by PowerReviews
- Rotates easily (3)
- Well built / quality (3)
Best Uses
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- Reviewer Profile:
- Budget shopper (3)
Reviewed by 3 customers
- Attractive Design
- Educational
- Quality Construction
- Rotates Smoothly
Best Uses
- School
Comments about Replogle Geographer Dry Erase 12-inch Diam. Tabletop Globe:
The lack of place names is a huge asset to this globe. Lessons can focus on relevant countries and regions without students being distracted by other place names. The globe format gives students a sense of physical relationship between places. It helps to augment this globe with either a map, atlas, or second globe that does list place names. A huge benefit for this map is testing. Places on the map can be numbered and students can be asked to identify the locations by number. Of course, the same task can be accomplished using a flat map but the globe is another important modality for students to gain a perspective about our world.
- Attractive Design
- Quality Construction
- Rotates Smoothly
- No labels
Best Uses
- School
Comments about Replogle Geographer Dry Erase 12-inch Diam. Tabletop Globe:
I homeschool our children and we will use this globe to test their knowledge of the continents and countries. I was disappointed to discover that it comes without any of these labels (countries, continents, etc.). Other than that, it is a cool globe.
- Educational
- Quality Construction
- Rotates Smoothly
Best Uses
- Home Décor
- School
Comments about Replogle Geographer Dry Erase 12-inch Diam. Tabletop Globe:
Perfect for showing my 4 year old niece where I've traveled. The globe is very light, and the turning action is very smooth. No need to worry about bonking little ones on the head, and the materials are strong enough to take lots of handling. I like that national borders are outlined, but there isn't too much geographical detail to clutter up the big picture. A very good globe for teaching kids rough geography in a home or school setting.
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Stock Market & Financial Investment News
News Breaks
February 26, 2013
Range Resources sees 2013 production growth of 20%-25%
The company said, "Looking ahead, 2013 should be even better than 2012. We expect to grow production in the 20% to 25% range utilizing our existing low-cost, high rate of return inventory. Range's liquids production is expected to grow disproportionately greater than overall production in 2013 as we continue to focus the majority of our capital in our liquids-rich areas. With the continued ramp up in production volumes, we expect our cost structure to improve further as volumes grow faster than our absolute costs. Importantly, with our access to the growing global markets for NGLs through our innovative Mariner West and East projects we are increasing our price realizations and improving our profit margins. In addition to the Marcellus, our Horizontal Mississippian oil play is gaining substantial momentum and should add to our liquids production and reserves, while the Cline Shale, Wolfberry and Utica plays have exciting liquids potential. We are looking for 2013 to be a year of increasing production, reserves, cash flow and earnings which should translate into higher per share value for all Range shareholders."
News For RRC From The Last 14 Days
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February 2, 2016
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displaying 1-30 out of 109
I am now motivated.
read the joke
A young man moved into a new apartment on his own, and went to the lobby to put his name on his mailbox.
Epiphany Girls react to winning Schools4All visit from Justin Bieber
Props to the girls for their charity work, but really, if my daugther was acting like this for a singer I would consider myself a failure.
Kissing on a ferry
How many kisses you can get before unwanted watchers catch you in the act?


text:
Hello, I'm Walid Kottb
I was born in Cairo in June 1983. I graduated from Computer Science college, Tiba Academy in 2004. Since my childhood, I had the passion of exploring other cultures. I joined Memphis Tours' team in 2005 as a Tour Manager for about 4 years, then transfered to being a Director of Tour Managers in 2009 till now.
Graduated from Computer Science, Tiba Academy, 2004
4 years as a Tour Manager in Memphis Tours
2 years as a Director of Tour Managers at Memphis Tours
Our expert travel consultants are ready with ideas that will inspire you on your next journey.
We will work with you to create an unforgettable trip that is entirely your own.
While traveling with us, you can trust that any issues, big or small, will be taken care of.


text:
Update on LeonoraLeonora is 42 years old, married, and has two children, one of whom is in school.
Leonora is in the agricultural business raising pigs in the Philippines and also runs a sari-sari store. She requested a PHP 22,000 loan through NWTF to buy additional sacks of feed and vitamins for her pigs. Leonora has been raising pigs for three years now, and has borrowed four times in the past from NWTF to sustain her business. She successfully paid back her previous loans and is now requesting a new loan to further build her pig raising business.
In the future, Leonora would like to save money to expand her business.
Previous Loan DetailsLeonora is 41 years old and married with 2 children. Leonora works hard to provide for her family. She runs a sari-sari store in the Philippines and requested a loan of 20,000 Philippines pesos (PHP) through NWTF to buy more items to sell. Leonora has borrowed and paid 2 loans from NWTF bef... More from Leonora's previous loan »
Additional Information
More information about this loan
On Friday November 8, 2013, Super Typhoon Haiyan made its way through Southeast Asia, causing substantial damage to homes and businesses in areas of the Philippines. Given the state of devastation following this storm, borrowers living and working in these areas may have difficulty making repayments on their loans, thus making their Kiva loans higher risk. More information >>
About Negros Women for Tomorrow FoundationNegros Women for Tomorrow Foundation, Inc. (NWTF) is a non-governmental organization established with an aim to help men and women achieve self-sufficiency, particularly in the province of Negros Occidental's low-income communities. The organization offers its clients a wide variety of products, including loans for micro-entrepreneurs, hospital income benefits, life insurance, accidental death benefits and more. Kiva lenders' funds will be used to expand the reach of these products to low-income urban and rural communities.
Concurrent and Successive Loans
Our Field Partners often work with borrowers over a series of loans as the borrowers build credit, take out bigger loans, and expand their businesses. In order to make it easier for our Field Partners to post loans for borrowers who have been listed on Kiva before, we allow them to post successive and concurrent loans for their Kiva borrowers. This means that our Field Partners are able to post a borrower's second, third, etc., loan on Kiva without having to re-enter all of the borrower's information.
This borrower has been listed on Kiva before, so you'll see an updated loan description, as well as excerpts of the original descriptions from earlier loans. Most borrowers take out loans consecutively, meaning that they receive a second loan after having repaid the first. However, sometimes our Field Partners give out concurrent loans, allowing borrowers to take out one primary loan and a secondary "add-on" loan along with it. These "add-on" loans are typically smaller than the borrower's primary loan and serve a different purpose. Because Field Partners can now post loans as successive and concurrent loans, you will be able to track borrower progress over time and see the various ways a borrower is working with our Field Partners through funds from Kiva's lenders.
About Philippines
377View loans »
Success!! The loan was 100% repaid
- Repayment Term
- 11 months (Additional Information)
- Repayment Schedule
- Monthly
- Pre-Disbursed:
- Feb 27, 2013
- Listed
- Mar 20, 2013
- Currency Exchange Loss:
- Possible
- Ended:
- Dec 17, 2013


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In Uncategorized on June 21, 2011 by harriedcostumer
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Andrew Luck Shaved
It's kind of weird:
It's kind of weird:
Taking 35% of your over 7000 votes, Barbasol takes home the honor of being your choice for Best Shaving Cream. Created in 1919 and used by 1 in 4 men, Barbasol's iconic design has become the poster child for shaving cream. Plus, it's cheap.
Time for your weekly edition of the Deadspin Funbag. Got something on your mind? Email the Funbag. Today, we're covering dogs, douche schools, Coke, and more.
You lathered up a huge list of nominees, and we've shaved them down to find the top five. Now it's time to find the winner.
For the first time in his career, Mark Sanchez has been challenged for the starting job. He responded by growing a horseshoe mustache. It is intense.
A newly published study out of the University of New South Wales concludes that men and women perceive men with facial hair to be more attractive and better father-material than clean-shaven ones. WHO'S THE DISAPPOINTMENT NOW, MOTHER?
Sometime in late January, Dirk Nowitzki shaved. That would be the last time, at least until the disappointing Mavericks clawed their way back to a .500 record. Well, after last night's overtime victory against the Clippers, featuring a season-high 33 from Dirk, Dallas is 35-36. The beard? It is out of control.
We saw nascent stirrings of this on photo day, but it looks like Joba Chamberlain's mustache is officially going to be a thing.
This is it. The very least amount of hair a man can be covered in and still considered to have a mustache and the very most amount of hair a man can be covered in and still be counted among those walking upright and having moved on from dwelling in caves.
Last night's 14-13 Angels win over Boston in extras was a testament to agricultural arson, but some viewers seemed preoccupied with the status of Howie Kendrick's mustache.
Jayson Werth's beard has been the talk of Phillies spring training. Because this is clearly more important than a lack of a bullpen, there's already an official site for photoshops. [Jayson Werth Beards]