text:
|Publication number
|Publication type
|Publication date
|Aug 13, 1957
|Filing date
|Oct 27, 1955
|Priority date
|Nov 12, 1954
|Publication number
|Schlapfer Hans, Bindler Jakob
|Original Assignee
|Geigy Ag J R
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (3), Referenced by (2), Classifications (7)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent" COMPLEX FORMING AMINO ACETIC Acins Hans Schlapfer, Basel, and Jakob Bindler, Riehem near Basel, Switzerland, assignors to J. R. Geigy A.-G.,
Basel, Switzerland No Drawing. Application October 27, 1955,
Serial No. 543,262
Claims priority, application Switzerland November 12, 1954 7 Claims. (Cl. 260514) I In this formula, of X1, X2, X3 and X4,,at least one X monohydroxyalkyl derivatives of these compounds.
represents a Z-hydroxycyclohexyl radical, at least one and preferably two further X each represent the acetic acid radical -CH2COOH, the other X represent(s) a 2- hydroxy-cyclohexyl radical, an acetic acid radical a low molecular alkyl or hydroxyalkyl group or possibly also hydrogen, R1 and R2 represent hydrogen or low molecular aliphatic radicals or, also, together represent a 1.4-alkylene radical, and n represents a whole number of the value of 0 to 3 and preferably of 1 or 2. The new complex forming amino acetic acids are obtained from amino compounds of the general Formula I wherein of X1 to X4 at least one X represents a 2-hydroxycyclohexyl radical, at least one and preferably two further X represent hydrogen and the other X represent(s) a 2 hydroxycyclohexyl radical, hydrogen or a low molecular alkyl or hydroxyalkyl radical and, possibly-also an acetic acid radical, by reacting with compounds introducing the acetic acid radical -CH2COOl-I. Here also the symbol n represents a whole number from 0 to 3 and preferably 1 or 2, and the other symbols have the meanings given above. Monohalogen acetic acids such as monochloracetic acid or monobromoacetic acid, the salts, esters and nitriles thereof and also formaldehyde cyanohydrin or mixtures of alkali cyanides and formaldehyde are used as compounds which introduce the acetic acid radical. Advantageously the amount of these used is adapted to the number of hydrogen atoms bound to basic nitrogen atoms.
Examples of amino compounds usable according to the present invention which contain a 2-hydroxycyclehexyl radical are 2-hydroxycyclohexylamine, bis (Z-hydroxycyclohexylyamine, preferably however, the reaction products of compounds introducing the Z-hydroxycyclohexyl radical with 1.2-diaminoalkanes, 1.2-diaminocycloalkanes, diethylene triarnines, triethylene tetramines, 2'- aminoalkyl 1.2 diaminocycloalkanes and derivatives thereof which are substituted at single nitrogen atoms by low molecular alkyl and hydroxyalkyl radicals or possibly also1acetic acid radicals; further, the reaction products of these compounds introducing the, 2-hydroxycyclohexyl radical with partlyacylated polyamines of the type listed after'saponification of the acylamino groups. For ex- P i tented Aug. 13}, 195 7 ample, reaction products of l-halogen-Z-hydroxycyclohexane or of cyclohexane-LZ-epoxide can be reacted with ethylene diamine, 1.2-propylene diamine, 1.2- or 2.3- butylene diamine, with diethylene triamine, triethylene tetramine, with monoacetyl derivatives of these compounds after saponification, with N-monoalkyl- 0151:};
o homogeneous compounds as well as technical mixtures of these reaction products can be used as starting mate.- rials in the process according to the present invention.
Also the new complexforming Z-hydroxycyclohexyl compounds can be produced starting from amino acetic acids of the general Formula l wherein of X1 to X4 at least one X and preferably two or more represent the acetic acid radical --CH2.COOH and at least one further X represents hydrogen and the other X canalso possibly represent a low molecular alkyl or hydroxyalkyl group, and n, R1 and R2 have the meanings given above, by reaction with compounds introducing the 2-hydroxycyclohexyl radical. As such can be used, as above, 1- chloroor 1-bromo-2-hydroxy-cyclohexane or cyclohexane-l.2-epoxides. Examples of amino acetic acids which correspond to Formula I are iminodiacetic acid, the N.N- diacetic acids of ethylene diamine, of'1.2-propylene diamine, of 1.2- or 2.3-butylene diamine, or 1.2-diaminocyclohexane, the N.N"-diacetic acids of bis-aminoethylmethyl-, ethylor hydroxyethyl-amiue, diethylene triamine-N.N'.N"-triacetic acid, ethylene diamine-N.N- diacetic acid, N-methyl-, -ethylor hydroxyethyl-ethylene diamine-N.N-diacetic acid or N-,methyl-, -ethylor -hy-- droxyethyl-ethylene diamine-N.N-diacetic acid and compounds of a similar structure.
The new amino acetic acids containing the Z-hydroxycyclohexyl radical of the general Formula I are compounds which dissolve well as such as well as in the form of their alkali salts in water. They are capable of binding co-ordinative polyvalent metal ions such as earth alkali and heavy metal ions, in particular those from the group of iron metals, well. They can be converted with iron salts into complex iron compounds which are distinguished by the good stability of the complexes at higher pH values of, for example,-8 to 11. They can be used, therefore, for the improvement of alkaline earth which is poor in iron and, in certain conditions, are still effective when other agents which up to now have been used for this purpose, e. g. diphenylene diamine tetra-acetic acid, are no longer so.
The following examples illustrate the invention without limiting it in any way. The parts are given as parts by weight and the temperatures are in degrees centigrade.
Example I OHz-COOH 100 parts of monochloracetic acid are dissolved in 250 parts of water and neutralised while cooling with ice at a temperature of at most 10" with 131 parts of 32% caustic soda lye. 57.5 parts of Z-aminocyclohexanol are added while stirring to this solution and the whole is heated to 70-75 in a water bath. The reaction solution is kept continually phenolphthalein alkaline by the slow addition of 131 parts of 32% caustic soda lye. On completion of the addition, the solution which is alkaline to mimosa paper, is heated for 5 hours at 90-95, cooled to 35 and while stirring, 128 parts of 30% hydrochloric acid are added. After a short time, the N-(Z-hydroxycyclohexyl)-iminodiacetic acid crystallises out. parts (65% of the theoretical) of practically pure acid are ob- 3 tained which, after recrystallisation from water, melt at l47-149.
Example 2 028400011 'OHi-OO'OH recur-earn CHz-C O OH OH 420 parts of 30% caustic sodalyeareadded dropwise while cooling with ice to a solutionof 300 parts ofmonochloracetic acid in 700 parts of water. After the addition of 158 parts of N-(2-hydroxyacyclohexyl)-ethylene diamine, the whole Iisstirred and .heated to 70-75 and atthe same time, 420 parts of 30% caustic soda lye are added dropwise in such a way that:the reaction is always phenolphthalein. alkaline. To complete the reaction, the components .arestirred at "909 5 for 4 hours. After 383 parts of 30% hydrochloric .acid have beenadded, the solution is concentrated whereupon the N-(Z-hydroxycyclohexyl) ethylene diamine N.N.N triacetic acid formed slowly precipitates. The pure compound is obtained in fine crystals which melt at .-l97199 by recrystallisation from water.
The compound obtained has a high tendency to form complex salts which are very stable andeasily soluble.
If in this example, 172 parts of N-(Z-hydroxy-S-methyl-cyclohexyl)-ethylene diamine are used instead of 158 parts of N-(Z-hydroxy-cyclohexyl)-ethylene diamine and otherwise the same procedure is followed, then N-(2- hydroxy-S-methylrcyclohexyl)-ethlyene diamine-N.N'.N'- triacetic acid is obtained which has the same .good complex forming powers.
Example 3 OH 00011 OH2 O0OH P OH OH 82 parts of dihydrochloride of N.N-bis-(2-hydroxycyclohexyl)-ethylene diamine (prepared from so-called inactive diamine, M. P. 203204) are suspended in a mixture of 290 parts of water and 240 parts of 95 alcohol and the whole is cooled while stirring to'5. .After adding 44.4 parts of 37.3% formaldehyde, a solution of 26.8 parts of 95.1% sodium cyanide in 80 parts of Water is added within Z'minutes whereupon the temperature rises to about 13. The suspension is then brought to 6065 Within 15 minutes after which a solution gradually forms. The solution is stirred for 5 minutes at this temperature, then cooled to l15, the cloudy solution is diluted with 240 parts of water and the dinitrile is shaken out with 250 parts of chloroform. By evaporating the chloroform at 55 at the most, 82-85 parts of crude dinitrile are obtained as a pale viscous oil.
To saponify the dinitrile, it is stirred with 700 parts of 37.3% hydrochloric acid at 05 for 10 hours and then for 1820 hours at room temperature. It is then diluted with 700 parts of water and stirred for hours at 9095. After cooling, the precipitated dihydrochloride of N.N'- bis- 2-hydroxyclclohexyl) -ethy1ene diamine-N.N=diacetic acid is isolated, washed with 7.5% hydrochloric acid and dried. 7680 parts of the dihydrochloride are obtained.
To convert into the free diacetic acid, 80-parts of the dihydrochloride are pasted in 320 parts of Water and the pH value is adjusted to 4 in the warm with caustic soda lye. After standing for a considerable time (more quickly on insertion of a few seed crystals), the diacetic-acid crystallises in fine needles which melt at l64l'65. The yield is 66% of the theoretical.
If, instead of the so-called inactive form, the so-called d.l-form which melts at 125126 is used, then by working in a similar manner, a good yield of the .monolactone of N.N'-bis-(2-hydroxycyclohexyl):ethylene diamine- N.N-.diacetic acid is obtained.
The compounds obtained according to this example form stable complex salts which are easily soluble. They are capable of forming easily soluble and colourless complex iron salts in an alkaline pH range.
If, in the above process, N.N-bis-(Z-hydroxy-S-methylcyclohexyl)-ethy1ene diamine is used instead of N.N'-bis- (Z-hydroxy-cyclohexyl)-ethylene diamine, then N.N'- bis (2 hydroxy-S-methyl-cyclohexyl)-ethylene diamine- N.N'-diacetic acid is obtained. It has similar properties.
Example 4 oat-coon (IIHr-COOH NCHz-CHaNGHzCHz-.N
H oral-coon 61 parts of the trihydrochloride of ,N.N"-bis-(2-hydroxycyclohexyl)-diethylene triamine' (M. P. 230 23 l on decomposition) are dissolved in 180 parts of'wateran'd-the temperature is reduced to 5. Asolution of 24 parts of 95.1% sodium cyanide in'90 parts of water is added drop-' wise While stirring at '5'8 and then 41 parts of 37.3% formaldehyde are added within 1 /2 minutes whereupon the inner temperature rises from "5 to 22. The reaction mixture becomes cloudy during the formaldehyde addition and the trinitrile separates as a smeary mass. After stirring at l2-15 for 15 minutes, the trinitrile is taken up in parts of chloroform, separated and the solvent is evaporated off in the vacuum at a temperature of at most 55. The residue is saponified with 500 parts of 37.3% hydrochloric acid as described in Example 3'and, after evaporating off the hydrochloric acid, is worked up to form the sodium salt. 350 parts of a solutionof the sodium salt of N.N-bis-(2-hydroxycyclohexyl)-diethylene triamine-N.N.N"-triacetic acid are obtained. The content determined titrimetrically of complex forming triacetic acid is 14.5% which corresponds to-a yield of 71.5% of the theoretical.
The solution obtained forms complexes well with'earth' alkali and heavy metal ions, in particular withthosefrom the group of iron metals.
If in the above example 77 partsof the tetrahydrochloride of N.N""-bis-(Z-hydroxycyclohexyl)-triethylene tetramine are used instead of the trihydrochloride of N.N"-bis-(2-hydroxycyclohexyl)-diethylene tria'm'ine-and otherwise the same procedure is followed 'as'in Example 4, then a very strong complexforming solution is also obtained.
Example 5 OHr-COOH OH HO 44.7 parts of so-called inactive bis-(2-hydroxycyclohexyl)-amine (M. P. 153) are dissolved at 60 in a;mix-
10 minutes at this temperature, 'cooled to 10-12" and'40 parts of Water are added. After some time the nitrile separates in crystalline form from the milky dispersion. After stirring for 1 /2 hours at about 12, theproductis drawn off under suction, washed free of salt-with ice water and dried in the vacuum at 30-40. Yield is about 48 parts of crude nitrile.
The crude nitrile is saponified with 10 times the amount.
of 37.3% hydrochloric acid as described in Example 3 and the hydrochloric acid isevaporated off from the saponification solution in the vacuum. The evaporation residue is dissolved in water, caustic sodalye is added until mimosa paper turns brown and the solution is evaporated until it becomes cloudy. The solution is filtered over active charcoal. On standing, the sodium salt of bis-(Z-hydroxycyclohexyl)-aminoacetic 'acid precipitates in the form of lamellar crystals which contain crystal water. The "sodium salt can be purified by recrystallisation from a little dilutedcaustic soda lye.
Ifv the so-called d.l-form of bis- (Z-hydroxycyclohexyl)- amine ,(M; P. 115-117) is used and similar procedure is followed, the isomeric bis-(2-hyroxycyclohexyl)-aminoacetic acid is obtained which melts at 184-185 -In an alkaline pH range the ;bis- (2-hydroxycyclohexyl)- aminoacetic acids are capable of forming stable and easily soluble complex salts, in particular with iron ions.
If in this example instead of the inactive bis-(Z-hydroxycyclohexyl)-amine, the N-Z-hydroxycyclohexyl- N.B-hydroxyethylamine which is obtained from 1.2-chlo- I rohydroxy-cyclohexane with monoethanolamine is used and the procedure described above is followed, then N49- hydroxyethyl-N-Z-hydroxycyclohexylamino-N-acetic acid is obtained which has also good powers of complex formation with iron ions.
Example 6 HOCHrCHz-N-CHa-OlIr-N (EH2 i H: H
Example 7 CHI-c OH H CHr-C 0 0H 66.7 parts of iminodiacetic acid are dissolved in 200 parts of water with the addition of 40 parts of caustic soda. 50 parts of 1.2-cyclohexene oxide are added to the alkaline solution and the reaction mixture is heated while stirring strongly to 80-85". After about 2 hours a practically clear reaction solution is obtained. Stirring is continued for hours to complete the reaction. The solution is then made up to 600 parts with water, 122 parts of 30% hydrochloric acid are added and the whole is left to stand. After a short time, the N-(Z-hydroxycyclohexyl)-irninodiacetic acid begins to crystallise out. 76 parts are obtained (M. P. 147-149"). The product is identical to that obtained according to Example 1.
Example 8 CHr-C O OH CHg-CO OH @l onronrl@ After about. 2 /2 to 3 hours,- the greater part of the epoxide has reacted. It is stirred for a further 5 hours. The solution obtained, which forms complexes well with earth alkali as well as Fe ions, contains 22.1% of the isomeric N.N'-bis-(Z-hydroxycyclohexyl)-ethylene diamine-N.N'-diacetic acids. This corresponds to a yield of 66.5% of the theoretical.
The mixture can be split for example by separating .the dihydrochloride of the diacetic acid obtained according to Example 3 by adding hydrochloric acid and the-isomeric diacetic acid or the monolactone thereof is isolated from the remaining solution. 7
Example 9 H, 0H; 0H,
OH H0 60 parts of 1.2-cyclohexene oxide are added to a solution of 57 parts of 1.2-propylene diamine-N.N'-diacetic acid and 24 parts of caustic soda dissolved in 220 parts of water and the whole is heated while stirring strongly for 7 to 8 hours at -85 A pale brown solution is obtained, the content of isomeric N.N'-bis-(2-hydroxycyclohexyl)-1.2-propylene diamine-N.N'-diacetic acids, determined titrimetrically, is 20.5%, which corresponds to a yield of 60.4% of the theoretical.
The solution of the sodium salt of diacetic acid obtained has similar properties to that obtained according to Example 8.
If. in the above example, 61.3 parts of 2.3-butylene diamine-N.N'-diacetic acid or 69 parts of 1.2-diaminocyclohexane-N.N'-diacetic acid are used instead of 57 parts of 1.2-propylene diamine-N.N-diacetic acid, and otherwise a procedure corresponding to that described in Example 9 is followed, then strongly complex forming aqueous solutions are also obtained.
What we claim is:
1. An amino acetic acid of the general formula:
coon nooo-on, R1 R1 (in,
\(IJII wherein X represents a member selected from the group consisting of lower fl-hydroxyalkyl, Z-hydroxy cyclohexyl and lower a-carboxy alkyl groups, Y represents a 2-hydroxy cyclohexyl group, R1 and R2 each represent a member selected from the group consisting of hydrogen and lower alkyl groups.
3. An amino acetic acid of the formula:
HOOC-CH2 CHa-COOH N- C Hr-C Hz-N CHz-COOH OH "4.A11' amino acetic acid of the formula:
' 11000-011, CHPCOOH -CHrCHz-IL Y OH HO 5. An amine acetic acid of the formula:
,HO'O C-QH: CHz-C OOH OH HO 7. An amino acetic acid of the formula:
' HOOD- 1H1 CHr-COOH References Cited in the file of this patent 10 UNITED STATES PATENTS 2,428,353 Bersworth Oct. '7; 1947 2,532,391 Bersworth Dec. 5, 1950 1 FOREIGN PATENTS 15 719,901" Great Britain Dec. 8', 1954
|Cited Patent
|Filing date
|Publication date
|Jun 21, 1943
|Oct 7, 1947
|Bersworth Frederick C
|Lower aliphatic esters of ethylene-and propylene-diamine n,n'-tetracetic acids
|Mar 15, 1947
|Dec 5, 1950
|Frederick C Bersworth
|Alkylene polyamine derivatives
|Title not available
|Citing Patent
|Filing date
|Publication date
|May 5, 1981
|Feb 21, 1984
|Analytical Radiation Corporation
|Diamine acid fluorescent chelates
|Nov 9, 1983
|Oct 23, 1990
|Irwin Wieder
|Fluorometric analysis method
|U.S. Classification
|562/500, 556/148, 564/462, 562/507, 564/461, 558/430
|Cooperative Classification


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text: i was there for a convention. i had a room with a double bed. the air conditioner was very strong but difficult to regulate and very noisy. otherwise the room was neat and pleasantly furnished. one day there water was shut off for a couple of hours for unknown reason. otherwise everything worked well. the breakfast was good with unlimited... More


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Beautiful location, lodges were very clean and great place to relax and enjoy the surrounding areas. Would definetly go again.
Our first stay at this site. A great get away from our hectic city lifestyle. This was our honeymoon holiday and we enjoyed our experience here and have therefore booked another holiday for our first anniversary. Lovely location and lovely helpful staff. Highly recommend this site for any couples or families!!
Took 9hrs to get there, felt staff on duty we're not welcoming on arrival, situated in very remote place down very narrow roads, we choose the park as it was pet friendly, only to be told you can not leave you pet in log cabin whilst you go out, had we of known this would never of booked we have a 12mth old dog that still likes a sleep in day by its self, also we were at top of park which was not enclosed so was unable to let dog off lead any where on the park. We had sand in hot tub on arrival was told it's needs a clean out. Log cabin was clean and tidy. Shower was very dated and weak. We had alarm clock in bedroom but no plug socket to put it in. Wifi poor reception. There was a fridge with small freezer but no door on the freezer.On a positive we had nice comfy bed and there was a dining room. Would never of booked had we known about pets and were it was situated, was not worth the money we paid. Hot tub was the best part of stay.
Lovely setting, on issue was car parked away from bungalow ,
Ignore negative reviews! Awesome little Bungalow, (Hot tub was a bonus, well maintained, and no faults with jets during our stay!) would 100% stay here again. There are a fair few steps to access this accommodation, worth bearing in mind if mobility is an issue. Otherwise, a very well looked after place, set in beautiful surroundings.
Very enjoyable holiday. Quiet and secluded position down narrow country roads. A good pair of walking shoes required or else a car.
Really nice mini break away. Bungalow was basic but still nice. Hot tub was good couple of jets not working, well used but nice touch. Would stay here again, would upgrade to wooden lodge.
Staff very helpful. Thank you
Lovely location, bungalow small for 4 people. Quite a distance to walk from car park to bungalow but luckily we was allowed to park closer as the park wasn't full. The hot tub was nice but we felt it was a little old and tired as some of the jets didn't work or werent powerful. The bungalow was well equipped and the kitchen had a good range of utensils. The staff were very welcoming and nothing was too much trouble for them. Would definitely go back to the same location, but would opt for a newer more luxurious lodge next time.
It was the second time we have stayed in this location at Leycroft Valley but first time in a bungalow. The accommodation was adequate although the bathroom was in need of updating, it was clean though and had character. The hot tub did break down a number of times though which was a bit of hassle and only two jets worked so not many bubbles! The area is lovely, just a bit too far out of the way as there was no taxis from Perranporth to take us back from the beach and had to walk with a small child in the dark, not so good really. I think they should make it clearer that transport is an issue out of season. We would stay again but in one of the newer lodges and in the season when there are taxis. The staff were lovely though.
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Dr. Gunter works miracles
He amazes me every time. I visited him because I experienced lower back pain. After explaining the symptoms he asked me "did you eat a lot of sausage lately"? "Sausage?" Yes, as a matter of fact, I had a family member from Germany in town and bought (and ate) a bunch of smoked sausages over a period of a week. My point is: Dr. Gunter doesn't just lay you down and adjusts you - he looks for the cause of your symptoms - and he is right on, every single time (who in the world would think of sausages??).
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So Crayon Pop stopped by the studio and decided to play along with us for a small skit, answer a few questions, take some pictures with us in our sticker booth, and give away a bunch of signed CDs, which we're in turn giving away to you. Success! We made a playlist of the full interview, which is in two parts. If you can't see the playlist, for some reason, you can see part 2 of the interview here!
A few things about the interview that we didn't get to mention in the video:
Major respect goes out to Crayon Pop and their crazy schedule. Bar Bar Bar has really blown up for them and they were dead tired when they arrived at the studio yet they were still chipper and adorable in their pink outfits and helmets. If you haven't seen their hilarious video for Bar Bar Bar yet, check out their newest version here:
As a result of it getting so popular, they're pretty much doing loads of shows and appearances. Right after filming with us they drove off to Daejeon for a show which is a location far away from where we are. The day afterwards, they were back in Gangnam for another performance, which – oddly – was at a YouTube conference that Soo Zee was attending. Ha! Soo Zee says they didn't see her in the crowd, though.
Also, this was the first girl group that we interviewed! WOOHOO! What was really cool about it is that they LOVED the fanmail candy you guise sent us. We can't eat all of it ourselves, of course. It's too much for a regular human to eat! Or is it… So we share it with whoever comes by the studio. Crayon Pop dug right in. They loved the fruit taffy, and they tried both French and Russian chocolates! We were thinking to ourselves "they're a girl group, maybe they're probably on a strict diet and can't…oh wait. They're chowing down!" Super cool in our books.
Ok, so we've got four CDs that we're planning on giving away to you guise, and they're all signed! Here's what you gotta do to win!
Head on over to Part 2 of our Interview, and leave Crayon Pop a shootout in the comments. Show em your love and support, and we'll pick one Crayon Pop fan and give you their CD! You gotta be subscribed to us, too, so make sure you've clicked on this button here:
You can also leave your comments here, if you'd prefer to leave a longer answer. Just make sure to leave your YouTube username as well so we can see if you're subscribed :D
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Now, we're not sure when we're going to be able to announce the winners, because we're still in Europe, but we'll announce them in the next Music Monday we do! We're just not sure when that's gonna be. Hopefully soon! Block B's back! We gotta talk about them, right? RIGHT?! OH GAWD AND SHINee!!! WHAT TO DO!!??
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I listened to the song Bar Bar Bar a few weeks ago and fell absolutely
in love with it. I was having a really tough time in my life and theses
girls knew just what I needed. I needed to JUMP!!!!!! HEHEHEHE <3
This song lifted my spirits and just let me let go of all my troubles
and just dance and have fun. Now when I am feeling the little bit down I
put on this song and I just jump away. I want to thank the girls of
crayon Pop so much. They are beautiful and talented girls and I hope
they continue to push me to be the best I can be. Love their other songs
as well!!!!!! There song also motivates me and gets me pumped before I
study and do homework. With them I am determined to not let things get
me down and to finish college. I can do it. Crayon Pop lets go!!!!!
Crayon Pop's music is always so cute and cheerful, And their cheerfulness sticks to me as a result! I enjoy watching there silly video's, and their dances are really really great! The Bar Bar Bar dance is really cute and fun, and so are their older dances. I hope to see more of them in the future doing what they do! :)
My youtube username is: shlomitgoldich
CRAYON POP POP POP!!!!Happy fun Jumping fun time and love Bar Bar Bar & Dancing Queen songs and there different scene of style is fun and witty Go CRAYON POP Go Jumping all around everywhere, CRAYON POP jump jump uh ha uh ha jump jump CRAYON POP make U wanna Jump Jump!!!!!!!! ;)
shout out to my homegirls KU-RAY-ON POP! keep making awesome music.
yt: XoceanxsunX
"this was the first girl group that we interviewed!" Umm…SISTAR? Maybe you meant first girl group in the studio?…
Thanks for the interview. These girls are a breath of fresh air. :)
That was interesting…
I would have chosen death by spider, no matter how painful it may be. At least so I can see my parents and close ones to say good-bye in case I die…
As I witnessed before, seeing loved ones for one last time is what made the one at the death bed happy…
On another note, I can't stop thinking about who else would agree for an EYK interview… For some reason Brian Joo keeps popping up non-stop ( *lol* probably because he speaks english…) and Henry Lau…
And thanks to your " top 7 underrated kpop songs " Royal Pirates come to mind aswell.
Love Crayon Pop <3!!! Wish them the very best for their future releases!!!
i am so glad that EYK did an interview with Crayon Pop!!!! i love their energy and every time i hear them they give me energy. thank you EYK for showing me this group a while back. they are amazing!!!
I got the Crayon pop virus long ago…and there is no cure or vaccine…we are doomed with all their spunk and quirkiness!!! I'm so excited they have become so popular in Korea…hope they have more success to come!
Crayon Pop FTW!
this video wasn't put on the playlist but for all those who haven't seen this wondrous cover of itaewon freedom must watch this http://www.youtube.com/watch?v=2J_xHjg1sRs
just another reason to love crayon pop~
I fell in love with Crayon Pop after seeing Bar Bar Bar and then after that I started watching their other videos like Dancing Queen 2.0 and Saturday Night (the Japanese version). It sucks because I live in the U.S. and I can't watch their other videos to give them my support. Anyways they are by far the best girl rookie group I have ever encountered. I give them my full support and can't wait to see them grow each time with their music. I mean they are unique and look like they have fun with each other. Another reason why I love them is because lately I'm kind of tired of seeing girl groups having the overly sexy image! I want good clean fun and that's what Crayon Pop gives…. clean FUN! I will be so happy to win their CD. I will be forever love you guys and Crayon Pop if i won! Get your Cray~On!… Oh wait thats a GD reference haha! ^.^
My Youtube name is 1snitches1…….Please feel free to contact me to let me know that I won. jk jk =)
I kept thinking Martina was saying "grand pop"
Awww, that segment where they are walking down the street and their manager won't give them money. And then again at the amusement park? I just wanted to hug them all and pay for whatever they wanted! Ok, so that probably sounds like creepy, old sugar-daddy talk…but can you blame me? They are just sooo cute! Crayon Pop Virus! I am infected and I like it!
CRAYON POP IS SO ADORABLE!! I just couldn't handle this interview, they were too adorable and I couldn't see their exhaustion at all, that is such dedication. And I love how you showed them actually eating the candy it was just super adorable to me and i know the people who sent those packages must be exhilarated. My youtube user name is Dapper Dinosaur and I just can't wait for more of their amazing songs!!
I love Crayon Pop I will Always Support Crayon Pop! I love so much there Voices! And I like Eat Yourkimichi because u guys are very funny and make very good videos ps. i have seen all the videos u guys have upload :D Hope I get Picked! :D
Crayon Pop! I don't know how to start, you girls are amazing for breaking the kpop girl group mold and doing a concept that is daring and interesting that I personally would feel awkward doing. Thank you for the song Bing Bing, it's a new obsession for me! Always be happy and positive even in your hardest times, muah love ya!
Just incase; I'll comment here too since my youtube comment was 3 comments. I'm determined to get the CD cus' I'm broke and can't even buy an unautographed one. Disadvantages of being one year younger than the job age. T_T
My youtube name is Lexi H. (The picture is Crayon Pop's Way, haha.)
I've been the biggest fan of Crayon Pop since their debut. Sure, my bias is Way but I honestly cannot choose who my bias is. I'm so happy you guys interviewed them and I will do absolutely anything to get that CD. I'm so dedicated to them, I help update international fans on Tumblr with updates by helping with the fy-crayonpop blog! I'm proud of Yong Pop for their rising fame and I cried with them when they won for Bar Bar Bar. Especially against EXO! Of all people to beat!! ♥ Soyul, Way, Gummi, Choa, and Ellin are the sweetest idols out there and our fandom is strong! The girls have given their fans their numbers and talk to their fanclub members. They're so close to the fans and treat them all as friends, and I love it so so much. Yong Pop push themselves to the limit and try their hardest for everything they've earned; for example, the Girl Group Mud Wrestling. (Which they won beef! Haha~ They're shikshins, so they were excited.) I'm sorry for making this three comments but I love my Yong Pop babies so much and I wish they could be a little more popular. They don't care about having this gorgeous or sexy image, and they could care less about shattering their image. They all are themselves, that's why I love them a lot. The ladies are the quirkiest and act so weird, dorky, and 4D; unlike other girl groups who tend to not spazz out so they can keep an image. In summary; I love Crayon Pop! ♥
My Youtube User name:Alex Vargas
(oh, and i already commented on youtube before i knew about this option… ;A; USERNAME: ShootinStarUnicorn)
welp… i already commented on youtube before i realized we could comment here! ;A; is it okay if i leave a longer answer here? i hope it is… i'm going to do it anyway. yep. it's happening.
let me start by saying that i LOVE CRAYON POP. you guys are beautiful amazing girls who work so hard for your dreams, and endured many days out in the cold trying to gain support. i admire you girls for dealing with the haters and being yourselves, and i hope that you all stay strong and continue being proud girls like you always have been. me and my sister will continue being your dedicated fans, and supporting you even when people put you down. we love you guys so much, almost like family, where we worry about you when you are sick, and laugh when soyul is being cute… ^^ my sister's bias is soyul, so i see a lot of her. ^^ anyway, CRAYON POP 화이팅! 사랑해!! >< WE LOVE YOU GIRLS SO MUCH. KEEP WORKING HARD. <3
i really don't think that just saying all this is enough though… like honestly, you girls in crayon pop don't even know, even the littlest bit, what you have done for me and my sister. especially my sister. i am literally the most grateful person in the world to you guys. so much.
so, i hope you take the time to read this, even if it is long, and to understand exactly why i want this so much, not for me, but for my sister, who probably deserves it the most.
let's go! ^^
okay, so… when my sister first discovered crayon pop in august of 2012, they had 5,000 views on youtube. i remember it so clearly; she thought they were so cute, and was wondering why they had so many haters. she looked everywhere for their songs so she could download them (they weren't on itunes at the time), she followed as many tags on tumblr as she could related to them, and she downloaded the MV to her computer. she was OBSESSED, but not in a creepy way. it was extremely cute, to be honest. and it was the first time i had seen her really into something in a while, something that she could be really excited about. she learned the names of them in a week, and changed her tumblr description so crayon pop was one of her favorite groups. in no time, she was probably the biggest fan of crayon pop, without it being over-the-top and creepy.
i remember that i got her a signed album of crayon pop's for christmas last year; it was signed by all of them, and it was the only album i could find from them on ebay. i spent 200 dollars on it with the help of my mom, and she was so happy when she got it. seriously; she stared at it for at least a half an hour, and when i almost accidentally sat on it in her room she was about ready to have a spazz attack (i definitely learned to be more careful)…
when we were in korea on a trip, she looked everywhere for their albums. we went to at least 8 CD stores looking for them, but none of them had the albums. she was crushed, but she didn't give up until we had gotten from one side of myeongdong to the other. her motivation to walk all that way and find them was more than i had ever seen from her. literally, it was amazing how determined she was to find the CDs, and how disappointed she was when she didn't.
the next time i saw her get really happy about crayon pop was at kcon; we were getting our scratch cards, and she was so stressed as to who she would get. well, we got everything crayon pop, and she was so happy. like, insanely happy. she almost cried (or she might have actually cried, not sure… she was covering her face. ^^). i was so happy for her though, because it was the first time she had really been happy about something in a long time. i new she deserved it.
she works harder then anyone i know in her life. all her junior year, it was her coming home, doing homework, going to sleep and waking up again. she got a 4.0 every single trimester, and got a 33 on her ACT. she is probably one of the most amazing people i have ever met. on top of that, she deals with extreme anxiety disorder, as well as depression. i don't know how she does it, but she keeps herself so organized, so when she was just happy and content for one day after getting that scratch card, i was happy too. i wanted her to be like that for forever. it was crayon pop who made her that happy, and i became even more grateful to them starting that day.
my sister was absolutely adorable when she woke up the next morning. she was so nervous, and she kept straightening her hair in the car. she wanted to get there and stand in line for crayon pop extra early, so that she could meet them and give them a high five, just like the scratch cards promised. so we waited in line for a half an hour, with her tapping her feet and waiting, absolutely determined to see them. but then, 5 minutes past the time we were supposed to be let in, i began to get worried. suddenly the volunteers said that it was cancelled, and my sister's face went from happy to blank to almost in tears, so i knew i had to get her out of there. she's too strong to cry; that's just her personality. she's not like me, who can't stop herself from crying in public of the littlest things. she's so strong. she just sat there, taking it all in. i was determined to make sure she felt happy, and i tried everything to make her feel better, but in the end she left the convention for a while, and i waited by the line just to see if they might switch things around and let us in. they never did, but i had high hopes.
i wasn't sure how she was going to do, but she came back for the concert, and we watched it. i was in the standing section and she was in the side section, but during crayon pop when i looked up at her seat, she was literally the only one in her section who was enthusiastic. other people were just standing there, and they would occasionally sing "jumping and jumping" when they got the chance, but during dancing queen they were mute. my sister, though, knew every single lyric, and her energy was completely full. seriously, i've never seen her be that energetic. ever. it's something that i distinctly remember, because she was the one person in that section pumping her lightstick to the beat of the songs, singing in korean that she had memorized. in that moment she was the biggest crayon pop fan i had ever seen.
now by big, i don't mean big as in she was like stalking them and buying pillows with their faces and buying every single album. first of all, she's saving all her allowance for college, so i don't blame her for not buying the albums (but if she had more money i swear she would own every single one). that's one of the reasons why i want to get this signed album for her, actually. but anyway; she's the biggest fan because she has the most passion for crayon pop out of anyone i've ever seen or heard about. she loves them like family; she worries if they become sick, and always wants them to be happy. she knows more about them as people then anyone else, and maybe i'm wrong, but out of anyone i've come across she's the most passionate.
and i think that she deserves this album the most, out of anyone. she doesn't ever ask for anything that she doesn't need; to prove this, she kept one pair of jeans from eighth grade to her junior year of highschool so she wouldn't have to trouble our mom with asking for a new one. she is so considerate of other people's needs that she tends to throw her wants to the side. this is why i want to get this for her. i want to secretly win the album for her, and then give it to her at christmas. it's a longshot, and there might be other people who want it, but let me tell you, there is no one who wants it and deserves it more than her. and it's the least i can do to show her how much i look up to her, how amazing she is, and how cool life can be when you just have hope that something amazing could happen, even if that means winning a signed album.
so, simon and martina (i seriously praise you for reading all this if you did, like honestly) and crayon pop, i hope after seeing this you understand that winning this album would mean something so much more for my sister than anything else i can think of, besides getting into her dream college. if i could win this, i would be SO GRATEFUL. like, there would be no words. you guys would be creating the biggest smile ever for her, i promise you. PROMISE PROMISE PROMISE.
THANK YOU SIMON AND MARTINA FOR DOING THE INTERVIEW. thank you so much… my sister probably loved watching that too haha~ <3 i love you guys, and i love crayon pop, and spudgy, and meemers (i apologize for my spelling because i am the worst speller… ever…), and… ya know… dah whole crew. <3 <3 <3 please take this all into consideration, and best of luck to all the other entries! <3
well… bye. again, sorry for the length. ^^
You're welcome my darling! <3
Crayon Pop unnies, good job, and fighting!!! I love you guys sooo much, and hope you do many more songs and albums in the future!!! I wish for your fans to grow more and more, so you can make lots of money!!!! Good job Crayon Pop, I will forever be your fan, and infested with the Crayon Pop virus!!!! Fighting!!!! My YouTube name is ThePiggyBunnySaram… I think or else it's humi178. Thank you EYK for the amazing interview!!! Fighting EYK and Crayon Pop!!!!
Love this interview! You guise are so awesome. Actually, I haven't even finished it yet, but there is one thing that I find kind of bothersome: when Martina speaks in Korean there aren't any subtitles. Even though it's usually very short sentences, I don't speak a lick of Korean, so I would love to have subtitles and know what she's saying! This has happened before…just a suggestion!
I am Chinesebookworm on YouTube. Crayon Pop are pops of pretty colour swirling through my mind. Such addicting songs! I like how you can actually work out to them by learning their dances; such perfection! :D
My wishes to Crayon Pop to never lose their fun style and colour! Best of luck in all your endeavours! Fighting!!
Crayon Pop please stay in touch with Simon and Martina. I think they will be very happy to have you as friends! <3
I like the songs and Crayon Pop because it gives us the impression of seeing friends having fun and doing what you love which is singing, no matter in what place, clothes or situation, they are always happy singing. I saw the videos of them, 'Bing bing' and 'Bar bar bar' and fell in love with it their way.
I know that in the midst of so many smiles and laughter came many weeping and sorrow, but they never passed it in their videos. Even when they were prevented from appearing in music programs they always find a way to show their work to their fans and admirers.
I live in a country where the female body is more valuable than what we think (I live in Brazil; my country has many beauties things, but unfortunately also has many flaws and don't like this defect, to me, to make the foreigners _some of these already think so_think that brazilian women are just butt, chest and thighs) and rightfully so don't like seeing girl groups in K-pop, where companies super expose the bodies of these girls instead of the beautiful voice that most of them have.
So, by knowing Crayon Pop I saw a group that to be sexy and cute is not the main point and not the flagship of their presentations; the flagship is the fun and the feeling that anyone can have fun with little things, we can even dance with gym clothes, uniform of the college and nothing else is needed.
In most, I wish them much success and that they keep this formula, because with this little way they will have more and more sucess and fame.
Youtube username: Rafaela Bezerra
Link of username: http://www.youtube.com/channel/UCqSpW1oae-_6DjodKfuA_Fw
I LITERALLY loved these 5 ADORABLE girls since the beginning and was so proud when they began to get noticed for Bar Bar Bar. Their songs and energy truly bring me joy and get me DANCING all the time! I seriously think Crayon Pop is such a UNIQUE girl group and also a talented one. They inspire me to be different and embrace my 'corky-ness ' I love them and EYK so much! Best luck in the future for both!! <3
Username: lazypea93
OMG!!!!! I love u guys (Crayon Pop) so much. I'm always playing your songs on my ipod or trying to dance to them because they are so cute/fun. I love how you aren't like regular girl groups who either try to be really sexy or really cute. All five of you are just crazy, adorable and incredibly talented girls who don't try to be something they aren't, which is why I think you are so awesome. ^^ Way: I think you are so pretty and I love how confident you seem in everything you do. Ellin: I LOVE YOU!!!! You are so adorable and funny. Choa: I love your voice; it's so soothing and beautiful. Gummi: Thank you for taking care and acting like a mother for these four other girls. Your love for them definitely shines in everything that you do. Lastly, Soyul: Our maknae. Your energy is so infectious and you always make me wanna get up and start moving with your cute actions. Thank you for coming together and becoming the group that all of us love and cherish. Also, your songs are definitely the best workout songs ever. Lol. I'm always listening to 'Saturday Night' or 'Bing Bing' when I'm in the gym. I'll always love and support Crayon Pop no matter what, so try not to overwork yourself too much and enjoy all of the recognition that you most definitely deserve. CRAYON POP, AING!!!!! <3 Saranghae. Fighting!!!!
sgnerjk I love it they are so lovely ^^ It would be cool to win one of those albums *-*
Hey Crayon Pop!
I remember the first time I heard your song Saturday Night like it was yesterday, I usually don't like cute concepts that much, but yours was quite different – it wasn't all 'pink and glitter-y' but a 'smiling and having fun' kind of cute and I immediately fell in love with you guys <3 I eventually became addicted to your debut song Bing Bing as well… Bing, bi-bing bing bing~ Your stage outfits are so cute and dorky :D And your dances are so much fun~
I always knew: the world needs more girl groups like you! I wanted humanity to give more attention to so badly~ And look to where you have come now – your song being like the 2013 edition of Gangnam Style (unfortunately, without the international popularity) even though you're from a pretty unknown company ^-^ Time sure flies fast…
Martina MCing your kpop chart update made me really excited and seeing your hilarious interview made my day :) Thanks to Simon and Martina for making this possible as well!
I love buying the music I like physically, and now that you FINALLY released a physical album, I want it so badly^^ And it would be SO freaking cool if I could get it signed <3
Please continue to be such a refreshing and fun group! Crayong Pop, fighting!
P. S. my youtube name is SilentKairyu c:
Shark. Hurts for a bit and then over quickly. Poison is not fun kids… That stuff is horrible. Some nature blogger did a post about the one time that he almost died to a black widow bite and it made me want to never go outside again…
I think it depends on what type of spider with what type of poison. Say it's a painless poison that just makes you sleep and never wake up, rather than a poison that has a bunch of symptoms before death? o.o And it also depends on where you get bit by a shark for you to die. It could bite you on the arm and you could slowly bleed to death, which would still be considered death by shark. Or it could be as fast as lightning if the shark just bit your head off or a part of your torso. o.o
I'm probably thinking about this too much….
I know! That's crazy! A shark will kill you in under a minute. A spider will kill you over the course of hours. Poison's a terrible way to die. Shark: get bit hard, bleed out, and you're done.
I LUV Crayon Pop! Their simplistic fun music and videos are just super awesome!
Pop! Pop! Keu Re Yong Pop! Get! Set! Ready! Go! Jumping! Yeah! Jumping! Yeah! Everybody!
I can't even express how excited I was when I saw EYK was going to
interview Crayon Pop starting with the hint asking for fan questions. It
was two of my favourite things in one place!!! Literally spammed all my
social media with it.
Personally, I've been wanted to do
something Crayon Pop related for a video on my Youtube channel:
tylo7887. Just had an idea last night, but now it's about making sure it
happens, lol. Anyways, love what you guys do, keep it up! EYK fighting!
Crayon Pop Fighting! <3
Pop! Pop! Keu Re Yong Pop! Get! Set! Ready! Go! Jumping! Yeah! Jumping! Yeah! Everybody!
can't even express how excited I was when I saw EYK was going to
interview Crayon Pop starting with the hint asking for fan questions. It
was two of my favourite things in one place!!! Literally spammed all my
social media with it.
Personally, I've been wanted to do
something Crayon Pop related for a video on my Youtube channel:
tylo7887. Just had an idea last night, but now it's about making sure it
happens, lol. Anyways, love what you guys do, keep it up! EYK fighting!
Crayon Pop Fighting!
I like to see how they became famous by their own talent. They have worked hard for the sucess. They are a example that if you work hard your can win
Crayon Pop is awesome. We rarely come across groups that aren't all mini skirts and aegyo AND have catchy, fun music. Crayon Pop is a prime example of cute without the aegyo overdose, and silly while still looking cute. =P And to top it all they are being recognized for that unorthodox awesomeness. Win~ (*>.<*)/ These are songs I can dance along with and even teach to my little cousins; like that cover video shows, Crayon Pop has a universal appeal that many girl groups lack these days. From debut until now, they've never disappointed. I hope they never change.
크레이용팝, 축하해용! 우리에게 좋은 음악을 들려줘서 고마워용. 우리 팬들도 열심히하는 크레이용팝을 위해 열심히 응원할게요. 사랑해용 ♥ 화이팅!
-InvisibleRen @YouTube
I was hit by the crayon pop infection at K-CON 2013! Before i liked Dancing Queen for being so silly out in the streets, but seeing them on stage was amazing! Hope to see them continue to be AMAZING! POP POP KU-REI-YON- POP
(user name awaman12)
팝 팝 크레용 팝!
My Fiance showed me Crayon Pop not long after we got together. Ever since then I have been 100% in love with their music. I love them so much that I am now one of the 4 staff members of "Crayon Pop UK". I believe their song writing team (known as Dumb & Dumber) are pretty much musical genius'. Everything about the ORIGINAL "Dancing Queen" was magical, from the production to the vocals. The girls are very pretty, extremely funny and seem VERY approachable. I'd love to see them live someday. I've also went ahead and bought ALL of their CD's so far, including a signed version of their Bing Bing single, all of which I've given as gifts to my Fiance as a thank you for introducing me to the girls.
To start this off: SNSD was my favorite group, loving them since 2009, but this summer Crayon Pop just totally took my heart with them. Nearly everyone's thinking that they are just "a girl group, jumping around with helmets and stuff" but seriously – for me, it seems like these 5 girls are the kindest and most fun-having girls in the whole K-Pop industry. <3 It's amazing how they made their way from Guerilla performances on a cold winter to #1 on a music show – always wearing a smile and having fun at everything they're doing. :) They are really hardworking and they totally deserve all the recognization for Bar Bar Bar – I really hope they will keep their success! Even though all five of them are amazing and perfect, Soyul completely won my heart and became my Ultimate Bias (Just wanting to let everybody know how PERFECT she is, seriously.) – which I thought would be impossible. At the moment I'm gathering some money, in hope that I can get all of Crayon Pop's releases soon – such a unique group deserves all my support I can give. <3 Let's hope they will get worldwide recognization! :)
(Youtube-Name: CrickBassify | Youtube, y u not let me write long comments! D: )
To start with, Crayon Pop songs are really amazing! They are exactly my style. ♡ Crayon Pop is showing a very cute side of the kpop. The thing I like the most about them is that they're not the typical girl group. They don't wear short skirts, they don't show their legs and I really like the fact that they're fully "covered" most of the time. That means that their fans are not fans because of liking their body (because there are many fans like this out there), but because of their good music and cute personalities. Other things I like about Crayon pop are definitely their personalities. They're just adorable. They're always having fun no matter what. And I love watching their videos at youtube even though I don't understand them. But when they smile, I smile too. Other thing that makes my heart melt is how hard they work for their fans and how great they treat them. They always make street concerts, which helps fans a lot to get closer to their favourite group. ^^ Which is amazing! Crayon Pop is a group which definitely deserves to be recognized more!
Crayon Pop is going to be one of my favourite girl groups forever. CRAYON POP, 화이팅! You girls are an inspiration to me. Keep on working hard and you'll achieve a lot for sure. LOVE YOU. ♥
( my youtube username – crazyxwildxx )
P.S.: I really hope to get the chance to win something like this. I'll be the happiest person! :D ^o^
"That means that their fans are not fans because of liking their body (because there are many fans like this out there), but because of their good music and cute personalities."
I completely agree. Just the same there are a couple of sexy girl groups I see that have one or two amazing singers, and/or have gorgeous members, but I can't get into them because I'm not interested in the music or image. But then there are those groups I love to watch on variety shows and BTS clips because of their personalities, but I don't like their music. Crayon Pop is likable in a lot of aspects and I think one can tell that their fans aren't shallow. Kpop isn't JUST about the face, afterall.


text:
Friday, March 2, 2012
© Copyright 2015 Clayton News Daily
Henry County police are asking for anyone with information about an armed robbery to contact them.
Henry Police Sgt. Joey Smith said officers responded to a report of an armed robbery, Wednesday, around 3 p.m., at 104 Naomi Drive in Stockbridge.
"A female reported that she had been dropped off at this location by a James M. Pippin, and that she had been robbed at gunpoint by Pippin of her personal belongings," said Sgt. Smith.
The victim told police that Pippin then fled the scene in a blue, Dodge pickup driven by a white female, the sergeant said. "Pippin is already wanted on unrelated charges."
The victim was slightly injured, according to police. "A female victim was pushed down, but did not receive medical treatment," said Smith.
Police were told the victim knows the suspect, according to Smith. Henry Police Maj. Jason Bolton described the incident as a "person-to-person robbery."
More like this story
- Man charged in Stockbridge salon robberies ( November 3, 2010 )
- Three arrested in armed-robbery case ( June 27, 2009 )
- Fourth suspect caught in home- invasion robbery ( February 11, 2011 )
- Second suspect sought in home invasion ( May 20, 2010 )
- Local woman charged in Stockbridge robbery ( May 19, 2010 )


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Fibroids can be located in four different places....
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Some New York parents are outraged after learning their children who opted out of Common Core testing are being forced to sit and stare for hours at a time while the other children take exams.
According to the New York State United Teachers Union, at least 15 school districts in the state are choosing the sit-and-stare policy for students who opt out of testing, a local ABC affiliate reported.
"I've been going back and forth with the school principal," said Kimberly Salisbury, whose daughter attends Marion Elementary School. "Basically, she told me my daughter will have to sit in her classroom for the remainder of the test."
Kathryn Wegman, superintendent of the Marion Central School District, said in a statement to 13WHAM News: "[T]he State Education Department regulations and guidance do not provide an alternative setting or activity for those students who might refuse to take a test. The District does not have the right, nor the staff and space to provide an alternative setting."
New York students in grades 3 through 8 will take the tests starting Tuesday and will continue throughout the week.
Miss Wegman said that the district is allowing parents to take their children out of school during this period — an option that may be difficult for working parents.
New York State United Teachers President Richard Iannuzzi recently came out against the sit-and-stare policy.
"This policy aimed at students whose parents elect to opt out their children from state standardized testing in unconscionable," he said in a February statement. "Punishing or embarrassing children because their parents exercised their right to choose not to have their children participate in tests they consider inappropriate is, frankly, abusive."
While the Common Core program creates a set of national standards aimed to ensure that all children are equally prepared as they advance to the next level, the model has come under intense fire for acting as a "one size fits all" learning tool for kids.
Just last week, Indiana became the first state to formally withdraw from using the Common Core standards.


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Moore praises filly following stunning win
Aidan O'Brien's Minding claimed her second Group One prize of the season with a brilliant display in the Dubai Fillies' Mile at Newmarket.
Aidan O'Brien's Minding claimed her second Group One prize of the season with a brilliant display in the Dubai Fillies' Mile at Newmarket.
Hit It A Bomb looks a very bright prospect after landing Listed honours in the Irish Stallion Farms EBF Star Appeal Stakes at Dundalk.
Aidan O'Brien's three-pronged attack on Australia's leading races stepped up a notch on Thursday as Highland Reel, Bondi Beach and Kingfisher set off on the journey Down Under.
Aidan O'Brien is launching a very strong raid on Friday's Dubai Fillies' Mile at Newmarket with both Minding and Coolmore featuring among 10 declared for the Group One contest.
Giant Redwood, Cook Islands and Prospector look to have bright futures as they combined to give Aidan and Joseph O'Brien trebles at Navan.
Ballydoyle ran out a determined winner of the Total Prix Marcel Boussac at Longchamp for Aidan O'Brien and Ryan Moore.
Aidan O'Brien was at Longchamp to see Ballydoyle claim the Prix Marcel Boussac and also struck on home soil as Plinth prevailed in the feature Istabraq Hurdle at Tipperary.
Aidan O'Brien sent just the one runner to Clonmel and it paid dividends as King Leon ran out a resolute winner of the Irish Stallion Farms EBF Captain Christy Rated Novice Chase.
Aidan O'Brien has a powerful squad lined up for Prix de l'Arc de Triomphe weekend subject to ground conditions.
Five horses from Aidan O'Brien's Ballydoyle yard have been placed into quarantine with a view to competing at the Melbourne Spring Carnival in Australia.
Aidan O'Brien's unbeaten Deauville is still among the 18 possibles for the Juddmonte Royal Lodge Stakes at Newmarket on Saturday.
Bondi Beach and Kingfisher could be Aidan O'Brien's first runners in the Emirates Melbourne Cup for seven years.
Wes Hoolahan stole the show for Norwich, Seamus Coleman and James McCarthy shone for Everton, and there was a first senior hat-trick for Irish Under-21 Aidan O'Brien in League One.
Minding overturned her highly-regarded and better fancied Aidan O'Brien stablemate Ballydoyle to grab Group One glory in the Moyglare Stud Stakes at the Curragh.
Order Of St George crowned a mightily successful weekend for Aidan O'Brien with a runaway victory in the Palmerstown House Estate Irish St Leger at the Curragh.
Air Force Blue gave Aidan O'Brien a tenth triumph in the Goffs Vincent O'Brien National Stakes with an authoritative display in the seven-furlong Group One for two-year-olds at the Curragh.
Aidan O'Brien has decided on the Palmerstown House Estate Irish St Leger at the Curragh on Sunday for Order Of St George in preference to the English version at Doncaster.
Aidan O'Brien this evening confirmed Gleneagles will be declared for Saturday's Qipco Irish Champion Stakes at Leopardstown.
The O'Brien family dominated proceedings at Wexford on Saturday with trainer Aidan saddling three winners, with his son and two daughters taking the mounts.
Aidan O'Brien has his fingers firmly crossed the weather will be kind enough to allow Gleneagles to run in the Qipco Irish Champion Stakes at Leopardstown next month.


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Dominican Sisters of Mary remain at No. 1 on the Billboard charts for fifth consecutive week
Catholic PRWire
To schedule interviews:
Kevin Wandra, 404-788-1276
Sacred music album shows no signs of slowing down
ATLANTA, GA (Sept. 18, 2013) - The Dominican Sisters of Mary, Mother of the Eucharist's CD, MATER EUCHARISTIAE, continues its run as one of the most impressive debut albums this year, securing the No. 1 spot on Billboard magazine's Classical Overall and Classical Traditional Charts for the fifth consecutive week, and landing the No. 8 spot on the Christian Contemporary and No. 10 spot on the Christian Gospel charts.
The album also is No. 151 overall of every recording on the Billboard magazine chart. MATER EUCHARISTIAE has topped a group of classical albums from prominent artists such as Andrea Bocelli, The Piano Guys, Sarah Brightman and Lindsey Sterling, among others.
"To sit atop Billboard's Classical overall chart for five weeks in a row is an attainment many artists dream about," said Monica Fitzgibbons, cofounder of De Montfort Music. "Still through their music, the Sisters share that a daily FIAT is the most outstanding achievement one can strive for. That the world would recognize them through their gift of song, shows that there is a true need and desire for truth in beauty. We wish to congratulate the Sisters once again and thank all of those who are helping to encourage and share this wonderful success story!"
Please be sure to watch Sr. Joseph Andrew and Sr. Maria Karol of the Dominican Sisters of Mary, Mother of the Eucharist discuss MATER EUCHARISTIAE with Fr. Mitch Pacwa on "EWTN Live" at 8 p.m. ET, Wednesday, Sept. 18. Also, later tonight, tune in for the rebroadcast of the "making of" MATER EUCHARISTIAE, a 30-minute special that will air at 9:30 p.m. ET Wednesday, Sept. 18 on EWTN.
Please contact Kevin Wandra (404-788-1276, or email@example.com) of Carmel Communications to schedule interviews. For more information about the album, please contact: firstname.lastname@example.com.
http://www.demontfortmusic.com/ GA, 30075 US
Kevin Wandra - ,
Dominican Sisters of Mary, Mother of the Eucharist, Mater Eucharistiae, sacred music
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iHerb Customer Reviews
Face Doctor, FaceDoctoRX, Complexion Soap
1 person found the following review helpful
Posted by Reviewer1229072 on Oct 09, 2011
This is a very soothing regime for me, after using the Surgeon II.... Am very pleased so far with the results I'm seeing.
Best soap for rosacea
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I've tried a few soaps with seabuckthorn for my rosacea and this one seems to work the best. It's not the cheapest but sometimes you get what you pay for. I use this along with a seabuckthorn oil and most of the time it's under control.
does not work ,enlarges pores
1 person found the following review helpful
Posted by 4646709064101718121 on Jul 28, 2014
this soap is pathetic, enlarges pores by refining them , works just for a few days on acne and then worsens it , and if you wash your face during the day with some other soap/ facewash hours after using this the skin reacts very badly , actually read reviews and got this one , this is the reason I am writing a review for the first time because I don't want this to happen to anyone what I went through,
Boyfriend LOVES it
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It smells really soapy but feels great on skin!
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As your local, full-service lumberyard and building material center, we are proud and very grateful to be serving you!
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We strive every day to make our name synonymous with quality, fairness, and unsurpassed service! This is our commitment to you!
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As it gets warmer would love to get out on the water and enjoy Boston.
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Polyester Fleece Performance Hoodie Sweatshirt [E16240]


text: tag:blogger.com,1999:blog-153952852015-10-12T01:12:32.733-07:00For a democratic secular Iran. For peace and prosperity in the Middle East.This weblog was created to act as a platform for the voice of secular pro-democracy activists in and outside Iran who are struggling against the religious dictatorship of the Islamic clerics in Iran. My favourite quote: "Evil only prevails when the good stay silent"Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-34753150719165952282015-08-25T09:59:00.001-07:002015-08-25T10:01:37.257-07:00David Shariatmadari's links with Iranian regime and the Guardian's credibility gap David Shariatmadari, the Guardian editor who recently authored a much-derided hatchet-job on the leading British Muslim liberal Maajid Nawaz, has long been something of an enigma. Homosexual and a self-described "sort of pan-theist", he has nonetheless regularly painted a rosy picture of Iran's theocratic government and has also, according to a variety of Muslim liberals, blocked reformist Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-55211653512817829172015-08-20T03:38:00.001-07:002015-08-20T03:38:25.234-07:00Khomeini's Damnation of Mossadegh What happens when the management of a company choose bad advisors? Well usually bad advise leads to undesirable consequences and the company suffers, but when the management is the US administration that appoints bad foreign advisors, then the undesirable consequences become global catastrophic calamities! I am still so infuriated about Obama apologising to the mullahs in Iran for the Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-35870917421194213092015-08-13T17:02:00.000-07:002015-08-13T17:29:05.988-07:00Baseless Concerns on How Iran's Unblocked Assets Will be Spent There were immediate grave concerns by many on how Iran will be spending the $120 Billion it was to get back as is stipulated in the Vienna JCPOA. These concerns centred on two issues, the Islamic Republic was getting this windfall without having to implement anything in return and that the regime was most likely to spend this money on its proxies such as the Hezbollah, the Syrian regime, the Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-88985608846228756412015-07-17T09:20:00.001-07:002015-07-19T12:52:49.914-07:00Who Has Obama Been Listening to? What does it tell you when the US president justifies the behaviour of the clerical theocracy in Iran with the toppling of Mossadeq in 1953 and thinks the United States should apologise to the mullahs for the overthrow of a "democratically elected regime in Iran"??!!! Watch Obama's apology here: It proves beyond any reasonable doubt that NIAC have got as far as the president's bedroom,Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-21107522051206167752015-06-09T04:52:00.003-07:002015-06-09T05:13:15.708-07:00What Do Iran's Clerics Talk About? What do Iran's clerics talk about? Well the short answer is, not just about the spiritual and religious matters as they should, but just about everything and all topics that they find interesting. In the Iranian comedy movie, the Lizzard, there is a scene where a cleric is talking on state TV about Quentin Tarantino's Pulp Fiction and describing in detail Tarantino's quintessential techniques asAzarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-8976445252814750892015-05-14T04:16:00.000-07:002015-05-14T04:16:43.109-07:00The Fiery Speech by a Female Iranian Teacher Protesting for Better Pay This footage below was sent to me by one of the teachers taking part in the widespread strike by the Iranian teachers. They are demanding better pay and conditions. The video shows a fiery speech made by a female teacher. See the translation below: "Most of the martyrs in the war were from our ranks, the teachers and pupils, so we have paid our fair share for this revolution, but Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-67123879514440388542015-05-11T14:28:00.001-07:002015-05-11T14:28:15.163-07:00A letter to Zarif Letter written by Mitra Pourshajari, whose father, Siamak Mehr, languishes in Iran's jails for having expressed his opinion on his blog, to Islamic republic's foreign minister, Javad Zarif, who told Charlie Rose, no one is jailed in Iran for their opinion! "Mr. Zarif, your Smile Cannot Hide your Fear"Once again, one of the high ranking officials of the Islamic Republic of Iran, its Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-78372029666044169312015-05-03T04:05:00.000-07:002015-05-03T04:05:07.416-07:0068 Minutes with Charlie Rose and Pinocchio "Iran does not jail people for their opinions" That is what the Islamic Republic's Foreign Minister, Javad Zarif told American anchorman, Charlie Rose on Friday. I have often criticised the American interviewers for their velvet glove questioning of the Islamic Republic officials and compared it to the way, they used to interview the former Shah of Iran. Zarif's interview with Charlie Rose Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-23474290607876341012015-04-24T15:17:00.000-07:002015-04-25T01:57:45.107-07:00How the Islamic Republic Out Foxed Mr. Olympia As soon as I heard Ronnie Coleman, the eight times Mr. Olympia bodybuilding champion, was going to Iran to promote his training methods and products, I knew it was going to be a controversial visit and I Tweeted about his visit. The first controversy that came about was when the Islamic Republic authorities learned that Ronnie Coleman's itinerary included a training seminar for a mixed Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-28040800359670024672015-04-10T08:29:00.002-07:002015-04-10T08:50:04.782-07:00The Complete Translation of the Speech Made by the Supreme Leader One may disagree with the utopia that the Supreme Leader of the Islamic Republic has in mind, but one has to admit that he is resolute and unwavering in leading the path to that utopia. I got so fed up with the short cherry picked tweets about his speech, his first reaction to the Lausanne joint statement, that I set out to translate his entire speech myself, below: "And now to the nuclear Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-15159106817050901892015-03-19T01:49:00.000-07:002015-03-19T02:46:53.539-07:00"The Chicken Vaccine Invented by the English and the Jews That Shrinks Iranian Male Penises" The guy in this video [Dr. Ravazadeh] has been on the Iranian State TV on a number of occasions. He is introduced to the viewers as an alternative doctor, promoting traditional Islamic medicine and herbs. Western medicine according to this alternative doctor is part of the overall conspiracy to subdue and control the Iranian population. His outrageous claims often go viral on the Iranian social Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-19009178369886005982015-03-18T06:32:00.000-07:002015-03-18T06:48:26.010-07:00Who Does Obama Invite to the White House? Although the guest list to the recent White House Nowruz party is not made public, but somehow the cat got out of the bag and it was revealed that NIAC's research director, Reza Marashi and its founder, Trita Parsi were amongst the guests. This selfie at the White House Nowruz party was taken by NIAC's founder and then tweeted by the Iran lobby organisation's research director, Reza Marashi. Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-89877666401930861692015-03-13T12:30:00.000-07:002015-03-18T06:32:57.817-07:00Interesting Comment on the Haleh Afshar Post It is now 7 years since I wrote this post about the pretentious Baroness Haleh Afshar, the aristocratic Marxist pretender who now thrives on acting as the reborn Shia Muslim feminist, but last week someone left an interesting comment on that post, which I thought should be shared. I would also like the person who left the comment to get in touch and provide me with more details. Here is the Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-5139671493718690642015-02-16T07:19:00.000-08:002015-02-16T07:19:12.579-08:00The Great Problem of Ignorance Appearing at the Atlantic Council in Washington, DC last week, former six-term congressman Rep. Jim Slattery (D-KS) said: "One of the great problems we have to overcome right now is ignorance, individuals in both countries have poor knowledge of each other." Jim Slattery was making the speech at the Atlantic Council after being the first former US congressman who has visited Iran since 1979. Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-44734233902670317452015-02-04T04:11:00.000-08:002015-02-04T04:11:48.838-08:00Whose side are you on, you fools? 13th September, 2014. The Iranian national volleyball team is playing in Poland. Amongst the crowds, there is one female Iranian fan, who has not succumbed to the suppression of her national symbols by the Islamic Republic occupiers of Iran. Darya Safaei, as in all the other volleyball matches she attends to, is waving the true national flag of Iran - the green, white and red tri-colour with theAzarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-23524061492872977662015-01-16T03:17:00.000-08:002015-01-16T03:17:43.482-08:00Question I asked at the Frontline Club in Jan 2014 Question I asked at the Frontline Club a year ago, on how the new oil exploration technology will change the supply and demand of oil and how it will effect Iran's economy: Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-51108401869809677362015-01-13T04:28:00.000-08:002015-01-13T04:34:51.890-08:00The Cartoon that Resembled Ayatollah Khomeini In 1990, a young 19 year old Iranian cartoonist by the name of Hasan Karimzadeh drew this cartoon which was published in a magazine called Farad. The young cartoonist had intended to make a statement about the budget cuts in football and Iran's football players being at a disadvantage compared to their competitors. Instead his cartoon sparked the wrath of Islamic fanatics who thought the Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-67535535618459152602015-01-11T03:52:00.000-08:002015-01-11T03:56:00.120-08:00"Islam Does Not Allow Killing" There seems to be no end to the naivety of some simpletons in the West. Listening to the LBC radio talk show after the cold blooded terrorist attack on the Charlie Hebdo headquarters in Paris, I was dismayed to learn the penny has still not dropped for so many people here in UK. One listener, who described herself as a homosexual teacher of religious studies at a school in London was more Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-29261333328921460542015-01-04T04:38:00.000-08:002015-01-04T04:38:53.764-08:00The Missing $4.1 Bn from the National Development Fund Rouhani's cabinet members at first flatly and explicitly denied the recent accusations by Iran's Majlis over the illegal withdrawal of $4.1 Bn from the National Development Fund. The row between the two bodies got so heated up that each side threatened the other with legal action. What further added to the confusion and unclarity of the situation was the different and at times, conflicting Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-60727089109116538872014-12-03T04:55:00.004-08:002014-12-03T05:02:11.829-08:00Iran Police Shoots Himself in the Foot It was supposed to be a show of prowess in shooting skills by Iran's anti-terrorist special forces [NOPO]. To begin with, everything was going well. The balloons were going up and between the three of them, they were managing to shoot down the balloons with precision shooting and ease. Just when it was all about to finish well and the special forces were about to leave the crowds dazzled and Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-75083309559013080322014-11-05T11:10:00.001-08:002014-11-05T11:11:22.756-08:00 For they will open the doors of deceit and hypocrisy instead The compulsory fake cries of Rouhani's cabinet members as he recites a eulogy for Ashura. "Lord, do not admire them for closing down the wine taverns/ For they will open the doors of deceit and hypocrisy instead" Azarmehrhttp://email@example.com:blogger.com,1999:blog-15395285.post-44704044904265218062014-10-17T03:18:00.000-07:002014-10-17T03:22:25.344-07:00#EUIranForum - Islamic Republic Needs More PR! I was following via twitter, the Europe-Iran Forum that was held in Grosvenor Square Hotel in London, over the last couple of days. Although the claim was that the Forum intended to gain "practical insight from experts" and get "most relevant, up-to-date information from Iran and Europe", the tweets suggested most speakers were painting an unrealistic super rosey picture of the Islamic Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-27965285870267830882014-09-27T01:22:00.002-07:002014-09-27T01:22:42.521-07:00The Mistranslation that Saved the Day in the UN General Assembly A huge embarrassment of monumental proportions was avoided at the UN General Assembly on Friday, when the translator of Rouhani's speech, conveniently mistranslated the derogatory Persian word of "Zangi" used to describe black people in a negative way, simply as "madman"! Right after Rouhani blamed the terrorism and anti-Western feelings in the region today as a reaction to the racism of theAzarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-32106236589792920762014-09-26T04:09:00.000-07:002014-09-26T04:09:25.090-07:00The Special Ray Produced by Men That Makes Women Age Quickly On the same day that the president of the Islamic Republic of Iran, Hasan Rouhani, was portraying his regime as a beacon of moderation and progress in the region, the following program was broadcast from Iran State TV: The program guest and her daughter were shown wearing the full neghab and in order to convince other Iranian women to do the same, they justified the benefits of wearing a Azarmehrhttp://firstname.lastname@example.com:blogger.com,1999:blog-15395285.post-29851262551688527802014-09-25T03:14:00.002-07:002014-09-25T03:14:30.384-07:00The Epic Documentary on the 1979 Revolution in Iran I have a five year old son whose thoughtful and profound questions often startle me. One such occasion was when I was walking with him to his school and as I was holding his hand, he totally rattled me when out of the blue, he asked me the following question: "Daddy, you know when the baddies came to your old country, why didn't you stay behind and fight them?" Not expecting to be asked such Azarmehrhttp://firstname.lastname@example.com


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Boston Mills Ski ResortAugust 8, 2013Ski Area • Peninsula, United States
Don't hassle me, I'm a local
Foodie. Sports car enthusiast. Music lover. Graphic artist. Gamer. Ex-restaurant chef that still loves to cook for others.
Don't hassle me, I'm a local
Well... at least 2 people have been here... it's better than 1!
Great soups! Chicken and Dumpling, clam chowder and especially Italian Wedding Soup.
Good burgers. Bad city chicken and bad roasted turkey with mashed potatoes. HUGE portions.
I just need a vacation...
We also had a Pepper mint milkshake as well as a chocolate. A They were made the right way, with real cream. All in all, great place. Highly recommend.
Even though some of the burger sounded sloppy they weren't too messy. Fat Doug was my favorite that day. Onion Rings were battered and very good. cont
Our table got.and shared a Lola burger, Thin Lizzy and a Fat Doug. All were excellent. I wish the burgers had more of a charred outside but the meat tasted great. cont.
not very good. go a little bit crazy but the smoke flavor on everything. the rib marinade tasted like old stale beer. go somewhere else.
#22 & #90.,plus some rice paper rolls. Yummy
Great specials on pizza. $9.99 for 2, 12 inch 1 item. Only $1.00 per extra item. I got the deep dish, excellent crust. My new go to place for pizza!
Ditto. The hot columbia raider sandwich is awesome. Drips down your arm.
They now have chocolate ice cream cones!
Carnita tacos. Fajita veg. Hot and corn salsa. Sour cream. Cheese. Lettuce. #priceless (actually $6.65).
Great service and prices. Free drinks and popcorn while you wait. Kevin was very good to deal with. My car loves it's new shoes.


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Mathematics & Statistics (Sci) : Review of trigonometry and other Precalculus topics. Limits, continuity, derivative. Differentiation of elementary functions. Antidifferentiation. Applications.
Terms: Fall 2010
Instructors: Axel W Hundemer, Stephen W Drury (Fall)
4 hours lecture; 1 hour tutorial
Prerequisite: a course in functions
Restriction: Not open to students who have taken CEGEP objective 00UN or equivalent.
Restriction Note B: Not open to students who have taken or are taking MATH 122, except by permission of the Department of Mathematics and Statistics.
Students continue in MATH 141
Each Tutorial section is enrolment limited


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I don't know what I did but for a period of time my TabWidget had white colored tabs which looked really nice. I never set a theme or background/foreground color in my project at all. The next time I compiled it it reverted back to the gray tabs. My application is using the default dark theme. Even if I set the application theme to light, the tabs are still gray. So obviously it was something else that changed the tabs' color. Anyone know how to do this?
I was having a problem due to a bug in Android 1.6's light theme (tab indicator text is white). I was able to override the default theme as follows:
Then I just apply that theme to my application by adding
Check this answer of mine: Background in tab widget ignore scaling
You can also refer to the
In your code, you can set the background for your tabs like this:
in the
than in the listener:
public void onTabChanged(String tabId) { setTabColor();
finally the function, which set the foreground and the background too:
In onCreated() :