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فديو رقص طيز عريانة فديو رقص طيز عريانة It is not a big mistakes. رقص شرقي جامد In a recent episode Snake Eyes was counting on Hi-Tech to tell him where Zartan was, apparently Snake Eyes no longer has any Ninja senses.
All Namekians born from the villain in Dragonball were not named after instruments Piccolo, Drum, etc.
رقص ايتن عامر بالاندر OK people I can tell you that I gave up on the anime some time after episode 50. رقص سعوديات I did pick back up around episode 83 with the hidan and kazuku fight scenes and it was very good. فديو رقص طيز عريانة But the anime got to the point where action scenes were starting to get spaced out very thinly in order to make more episodes.
رقص سعوديات Soon as I saw the first teaser, I knew I shouldn`t put up in any hope into this movie. رقص سعوديات Nothing personal to James as a director. رقص ايتن عامر بالاندر The movie only gives you the who and the what but no why. I did pick back up around episode 83 with the hidan and kazuku fight scenes and it was very good. I wont ruin the story but its nothing like the anime, as i said before the characters are only similar to the anime by name. فديو رقص طيز عريانة The posters suck and the trailers suck.


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Bring your Apple Watch—along with your iPhone—and get familiar with your most personal device yet. We'll show you how to get started using Glances, gestures, watch faces, and more.
Bring your Watch and iPhone in for a hands-on lesson in getting the most from your Watch. Discover new ways to use built-in apps you're familiar with like Mail, Messages, and Maps. Explore apps designed for Watch, and learn how to personalize and organize apps just the way you like.
Learn how to create interactive class materials with iBooks Author and reach your students in all the ways they learn. Find inspiration in how other educators are using iBooks in the classroom. See how simple, yet impactful it is to teach your topic with your unique perspective on iPad and Mac.
iCloud helps you access your files across iPhone, iPad, Mac, and the web. Learn great ways to share files with friends and family, and get peace of mind with backups and automatic syncing.
In this workshop, we'll show you how to use iMovie on your iPhone, iPad, or iPod touch to turn your favorite clips into blockbuster movies or Hollywood-style trailers.
Come get an introductory tour of your iPhone or iPad. We'll show you the basics of navigating, getting organized, and keeping your device up to date.
Learn how to capture and edit great-looking photos using the camera and tools already on your iPhone.
Come get an introductory tour of your Mac. We'll show you the basics of navigating, getting organized, and keeping your software up to date.
Discover built-in features on Apple Watch that help you get through the day. Bring your watch and your iPhone and learn how to set and track your fitness goals, get to your destination turn by turn, take the perfect selfie, and more.
Already familiar with the basics? Come to this workshop to discover great ways to personalize your device. We'll show you how to customize your Home screen, find great apps, and personalize your settings.
Already familiar with the basics? Come to this workshop to discover great ways to personalize your Mac. Find out how to customize your desktop or screen saver and learn handy keyboard shortcuts, gestures, and more.
Learn how Apple Watch makes all the ways you're used to communicating more convenient and intimate. Bring your Apple Watch—along with your iPhone—and we'll show you how to respond to messages and mail, share your location, take a call, and even send your heartbeat to someone you care about.
In this workshop, you'll learn how to stay on track with everyday tasks using notifications, reminders, calendars, locations, and more.
Turn your iPad and iPhone into the ultimate study partner. Discover brilliant shortcuts and features that help you stay on track for assignments, sleep, and even that perfect grade.
Get even more done in class and while you study with features that are already on your Mac. Discover settings to help you capture ideas and notes quickly. Learn top tips and little-known tricks to get you through lectures, study groups, papers, and even the entire year.
Shop the Apple Online Store (1-800-MY-APPLE), visit an Apple Retail Store, or find a reseller.
Copyright © 2013 Apple Inc. All rights reserved.

subset: commoncrawl


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Toddlers Christmas Ornaments
Celebrate your toddler's special time of growing and learning with a personalized ornament that's just for them. From first steps to big brother and little sister ornaments, we carry a wide variety of glass, resin, ceramic and clay ornaments for the sweet little toddler in your life.
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Read what our customers say about our Personalized Christmas Ornaments and their shopping experience!Hover over testimonials to stop scrolling
10/14/2014 - "The ornament was even nicer then i thought it would be. Great understanding of website, fast delivery, price was fair a lot of choices. My daughter will love this engagement ornament. I'm now ready to order more for Christmas and in a few months a wedding one. So glad i found your site. Anonymous Respondent "
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Akshay Kumar Varinder Chawla After rumours were rife that Bollywood 'Khiladi' Akshay Kumar would be playing a gay inRohit Dhawan's forthcoming... ...http://www.ibtimes.co.in/no-gay-role-akshay-kumar-varun-dhawans-dishoom-641695
. The city of Casablanca was close to where the actress was shooting recently for her film Dishoom and she did not want to let go of the... ...http://timesofindia.indiatimes.com/entertainment/hindi/bollywood/news/Jacquelines-wish-of-visiting-Casablanca-comes-true-while-shooting-for-Dishoom/articleshow/48340548.cms
Bahubali, which you presented, is a smash hit. Are you a part of the sequel too? Yes, I sincerely hope so that I am part of the second... ...http://www.newindianexpress.com/entertainment/hindi/A-Content-Producer/2015/08/04/article2955826.ece
Every couple is remarkably different and there is no rule book that governs what will keep our respective partners happy. But there are some... ...http://m.mensxp.com/relationships/better-partner/27106-12-longterm-relationship-hacks-that-work-like-a-charm.html
Amish Tripathi Everyone knows Amish Tripathi as the immensely popular author of the Shiva trilogy that has sold over two million copies and which... ...http://archivev.asianage.com/books/writer-luck-616
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Nike Campaign Features Marvin The Martian Mets Affiliate To Be Called Columbia Fireflies WNBA's Breast Cancer Awareness Week DeKalb Approves $30 Soccer Facility HBO's "Back On Board: Greg Louganis" Judge: No Vote Needed For Rams Stadium Funds Classified Advertisements PGA Championship Seeing Record Sales Former UGA AD Evans Now An Asset To Maryland Big Ten Phasing Out FCS Opponents
Upcoming Conferences and Events
SBD/Morning Buzz
NBC Sports Network Announces Details For "The Rumble On The Rails"
Published May 9, 2013
The U.S. and Russian teams will compete from 6:00-7:30pm in a match that will be carried on Universal Sports Network. Knapp will do play-by-play on Universal Sports, with Roberts serving as a reporter. The network has not settled on an analyst.


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ParagonX9 - Chaoz Airflow
Credits & Info
- Date
- 06/11/2009
- File Info
- Song
- 4 min 14 sec
- Score
- 4.32 / 5.00
Related Content
Heard in 29 Entries!
View all submissions featuring this audio file.
You might also enjoy:
Licensing Terms
You may not use this work for commercial purposes without making specific arrangements with the artist UNLESS your work is a web-based game or animation, in which case you may use this freely.
- Score:
- Rated 4.32 / 5 stars
- Plays & Downloads:
- 449,825 Plays | 426,054 Downloads
- Share Links:
- Genres:
- Electronic - Drum N Bass
- None
Author Comments
Rated 5 / 5 stars
nice beats
The tune sounds something from Sonic or Megaman, Can't puit my finger on it. Regardless of that, it's still a great tune to listen to.
Rated 5 / 5 stars
Best song I've heard in the audio portal in a long time. Keep up the good work :D
Rated 5 / 5 stars
this is amazing 10/10 5/5
Rated 5 / 5 stars
Sorry for the ZERO
I don't quite yet understand Newgrounds, as there's a rating on the left from 0 to 5 and a rating in the review from 1 to 10. Plus the 0 rating means "I hope you die in a fire" and I thought that meant your song is god-like, as in the best song in the world!!! So sorry that I gave you a "zero", but think of it as in ZERO problems with the tune, ok?
Amazing tune, absolutely amazing. Reminds me much of the demo scene.
Rated 5 / 5 stars
Nice job !
another excellent piece by ParagonX9 :)
keep up the great work
feels like a battle type music for a Final Fantasy type game


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What Milwaukee is talking about
As bets go this is way better than bratwurst or pierogies.
When it comes to Super Bowl chest-thumping, the good folks at the Milwaukee Art Museum and the Carnegie Museum of Art in Pittsburgh are letting Gustav Caillebotte and Auguste Renoir do their trash talking for them. Journal Sentinel art and architecture critic Mary Louise Schumacher writes about the unusual wager between the two museums.
So as if Aaron Rodgers, Mike McCarthy and the rest of the Packers don't have enough pressure, there's this – if they win, naked babes will come to Milwaukee. For three months.
Good news for anyone who ever wanted to travel over the Hoan Bridge even slower than motorists on the night of the big lakefront fireworks display – the United Performing Arts Fund has secured permission to use the Hoan for its annual Ride for the Arts on June 5. It's the first time that the ride, which started in 1979, will go over the 2.5-mile span and organizers hope the new route will boost participation, which has dropped off recently.
Good news for Northwestern Mutual Life Insurance policy holders – the Milwaukee-based insurer is paying out almost $4.9 billion in dividends this year.
Among the Packer story offerings in today's Journal Sentinel, former Packers architect Ron Wolf talks to reporter Tom Silverstein about the current team's talent pool.
On the big screen, two midsize Oscar-nominated movies, "Blue Valentine" and "Another Year," are opening this weekend along with two noisy Hollywood movies, "The Mechanic" and "The Rite." The Milwaukee Rep opens "Speaking in Tongues," and the Skylight Opera Theatre opens its production of "Jacques Brel Is Alive and Well and Living in Paris."
Plenty of sports in town this weekend, none involving a pigskin. The Admirals, Bucks and Wave are all hosting foes as well as the Marquette men's basketball team.
And on a sad note, it was 25 years ago today the space shuttle Challenger exploded.
Comments »
Read and share your thoughts on this story.


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FULL ARCHIVE: Click here to access all Times Union stories since March 1986. (Text only; fee to read stories older than 7 days)
SANTA CLARITA, Calif. (AP) — Five people are in critical condition after a... more »
LOS ANGELES (AP) — California Sen. Ron Calderon strolled into the Bellagio... more »
MEMPHIS, Tenn. (AP) — A person of "interest" has been taken into custody in... more »
LAS CRUCES, N.M. (AP) — A pair of small explosions just 20 minutes and a... more »
PHOENIX (AP) — A man accused of decapitating his wife and their pet dogs... more »
MACON, Ga. (AP) — Authorities say the body of an autistic 3-year-old boy... more »
LOWER LAKE, Calif. (AP) — Wildfires blazing in several Western states... more »
HANOVER, Pa. (AP) — Many Americans assumed the Confederate flag was retired... more »
BALTIMORE (AP) — Fresh off its deadliest month in 43 years, Baltimore saw... more »
MEMPHIS, Tenn. (AP) — Memphis police say 1 person of interest in custody in... more »
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NEW YORK (AP) — Verizon and unions representing workers in nine states said... more »
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SELMA, Ala. (AP) — Protest marches have been part of Selma's civil rights... more »
AUSTIN, Texas (AP) — A grand jury has indicted Texas Attorney General Ken... more »
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text:
Welcome to the College of Agricultural Sciences and Natural Resources
CASNR Opening Paragraph
Welcome to the College of Agricultural Sciences and Natural Resources
Explore our website and learn about the opportunities available to you as an OSU Cowboy! With more than 16 majors and 62 study options, more than 60 student organizations and competitive teams and study abroad trips all over the world, there is a place for you in CASNR.
CASNR News
CASNR News (View MORE...)
AFA Leadership Conference
Jul 22, 2015
- The AFA Leaders Conference provides support for college men and women who are preparing for careers in agriculture-related fields, while at the same time supporting the development of human capital for the agriculture and food industry. Leaders Conference bridges the gap between academic, leadership and work experiences while helping students understand the impact of their decisions. The conference also assists students in developing personal and professional skills necessary for lifelong success and provides a forum for updates and discussions on industry trends.
CASNR students named to 2015-16 President's Leadership Council
Jul 09, 2015
- Oklahoma State University has named 126 incoming freshmen to its President's Leadership Council for the 2015-2016 academic year. Of these students, 24 are enrolled in the OSU College of Agricultural Sciences and Natural Resources. President's Leadership Council is a freshmen scholarship and academic leadership program that emphasizes the importance of leadership and service throughout life.
OSU alumnus earns national philanthropy award
Jul 06, 2015
- (COLLEGE STATION, Texas) – Dennis White recently earned national recognition for more than 30 years of generous support for Oklahoma State University. On June 18, the National Agricultural Alumni and Development Association named Dennis as the Ruby C. McSwain Outstanding Philanthropist Award winner.
Document Actions
About the Division
About the Division of Agricultural Sciences and Natural Resources
The College is one of three entities within the Division of Agricultural Sciences and Natural Resources, which is also comprised of the Oklahoma Agricultural Experiment Station and the Oklahoma Cooperative Extension Service. The Hatch Act of 1887 established the Agricultural Experiment Station system. The Smith-Lever Act of 1914 created the Cooperative Extension Service to disseminate information obtained through agricultural research.


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A New York City man who was convicted of raping his former stepdaughter in an attack she revealed in a college application essay won't learn his punishment for another week.
A New York City man who was convicted of raping his former stepdaughter in an attack she revealed in a college application essay won't learn his punishment for another week.
The 62-year-old man had been set for sentencing Monday. But a judge delayed it when he sought time to prepare a response after learning the victim plans to make a written statement.
New York state law allows such postponements. The planned statement wasn't released, and the man's lawyer wouldn't comment on what his client wanted to address. He has denied the rape allegations.
The sentencing is now set for July 7.
- Alaska Airlines has 72-hour sale on fall travel to Hawaii
- Kirkland hunter defends acquaintance who killed treasured lion Cecil
- Seattle baby names: We're trying harder to stand out
- Seahawks safety Kam Chancellor considering training-camp holdout, source says
- Shell icebreaker slips by; authorities force protesters from Portland bridge
Most Read Stories
The Associated Press is withholding the man's name because disclosing it could identify his accuser. The AP generally does not identify sexual assault victims unless they come forward publicly.


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Bradenton Times News Articles
Tuesday, June 23, 2015
As a City of Bradenton resident and successful businesswoman, I recently reviewed the Bradenton Police Department's proposed plan for utilizing the 2015-2016 Edward Byrne Memorial Justice Assistance Grant allocated funds of $24,124.00, and I am astonished that Chief Michael Radzilowski would incautiously expend these funds for surplus office equipment. This proposal in and of itself is redundant, and even more puzzling, due to the fact that Chief Radzilowski is purchasing an additional five individual scanners for each of the Records Clerks.more»
Sunday, June 21, 2015
For the past five years, I've written a column celebrating Father's Day and another for Mother's Day. As the years go by, I find it a bit more difficult to unearth new ground to cover. I sort of took the easy way out last Father's Day and then skipped Mother's Day this year in favor of some hard news. On both occasions, I heard from disappointed readers. So, on this Father's Day, I offer a few of the hard lessons I've learned in one of life's jobs that don't come with an employee manual.more»
Saturday, June 20, 2015
Florida officials continue to sell taxpayers on their proposal to construct aquifer storage and recovery (ASR) wells, but a new peer-reviewed study published in The Journal of Geography and Geology calls the entire science into question and suggests that ASR wells might be little more than big, expensive holes in the ground.more»
Friday, June 19, 2015
Standardized testing is here to stay. The FCAT is out and FSA (Florida Standards Assessment, based on Common Core) is in. The FCAT was fraught with social issues. The FSA appears to be headed in the same direction. Standardized testing sets standards, and Florida has long been in need of educational standards. However, the question is how much testing do we need?more»
Thursday, June 18, 2015
This week, the Florida Elections Commission found probable cause that Manatee County Commissioner John Chappie violated election statutes by paying inflated bonuses to various political operatives. Nothing about Chappie's campaign—which was for an uncontested seat—passes the smell test. What happens next will go a long way in determining whether Florida is interested in preserving even the appearance of fairly contested elections that respect the rule of law.more»
Sunday, June 14, 2015
Every year, it's the same. Month after month, we are told again and again that only growth will save us. More developments, more new homes, more economic impact and new additions to the tax rolls—county commissioners sell us the notion that development is the golden road to prosperity. Then the summer hits and all of the departments that service this growth come before the BOCC hat in hand, only to be told that there is not enough funding to help them provide those services to a larger and more sprawling population. Case in point: this week's presentations by the Manatee Sheriff's Office and the EMS department.more»
Thursday, June 11, 2015
On Tuesday, the Manatee School Board approved signing new Superintendent Dr. Diana Greene to a one-year contract. But despite caving to public pressure to promote the two-year deputy superintendent of curriculum, the public was sent a clear message via the contract's terms: expect more of the same from your board. For a body desperately needing to build trust with its community—which it will ask for hundreds of millions in extra taxpayer dollars next November—that seems like a big step in the wrong direction.more»
Sunday, June 7, 2015
Over the past several weeks, there have been conversations about the possibility of changing the organization of the Manatee County School Board by adding two at-large members to the five-member board. The idea is to get more representation and cure dysfunction. However, our county commission has employed such a model for decades and the experience has been a cautionary tale. Fortunately, there is another way—two of them, in fact.more»
Thursday, June 4, 2015
For weeks, rumors have swirled that in the wake of former Manatee School Superintendent Rick Mills' abrupt retirement, certain forces were working to install former assistant superintendent Robert Gagnon as his replacement. When the board instead, and somewhat reluctantly, voted to give Deputy Superintendent Dr. Diana Greene a one-year contract at last Tuesday's meeting, it raised an immediate question: Who would take her spot as the head of curriculum, where Gagnon had once served? Had that already been decided ahead of the vote?more»
Sunday, May 31, 2015
Graduates of Manatee County's old Bayshore High School seem to get a lot of rare diseases, particularly cancers. There are an alarming amount of autoimmune disorders, as well as birth defects among their offspring. Some think they were exposed to chemicals from improperly maintained underground tanks that contaminated the groundwater and soil. Others think that the former building's history of mold is to blame. They've spent years looking for answers but have only found more questions and a lot of suspicious behavior, reinforcing their belief that the truth is being kept out of sight.more»


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Cross Classic Century 14 Karat Gold Filled / Rolled Gold Pen & Pencil Set
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Renowned Cross quality and a soft rose-gold hue create a pair of writing instruments to be valued for a lifetime. The Classic Century Pen and Pencil Set pairs a ballpoint pen and pencil with cap and barrel in our exquisite 14 Karat Gold Filled/Rolled Gold finisha beautiful and durable treatment that is higher in gold content than traditional gold plate. Includes 1 Black Medium Ballpoint Refill (8513) in Pen and 5 Pencil Leads/ 1 Pencil Eraser in Pencil.
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Cross Refills Black Medium Point Ballpoint Pen
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Cross 0.7mm Pack of 15 Pencil Leads
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Cross Refills Yellow Erasers for Pencil Converter .7...
Item #:8781


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From Kate Upton in "The Three Stooges" to the gents of "Magic Mike," here are the pics that sent us running for the theaters this year
Harry Potter fans get creative with #HarryPotterAMovie hashtag
Jimmy Fallon celebrates Harry Potter's birthday with drunk Ron Weasley
Report: Channing Tatum set to exit 'X-Men' spinoff 'Gambit'
Watch Katniss Fight Jon Snow in Genius 'The Hunger Game of Thrones'…
Chris Pine Joins 'Wonder Woman' in Multi-Picture DC Universe Deal
Brittany Snow Will Return for 'Pitch Perfect 3,' Too
That's A Wrap!
Review: 'Gone Girl'
Review: 'The Boxtrolls'
8 New Details That Will Get You Pumped For The Vampire Diaries…
25 Ridiculous Lessons You Can Learn From E!'s Total Divas
Deadpool: Ryan Reynolds Is Finally Unmasked in the Official Pictures
Woman Drops Child To Catch A Wedding Bouquet & The Chance At…
Feds: Man Tipped Strippers 2200 Times With Company Cash


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Comments about 'Unplugged: Former USU, NFL great Rulon Jones enjoys life in the great outdoors'
- Oldest first
- Newest first
- Most recommended
as a youngster I snuck down to the USU sideline in Logan during the 4th quarter of a BYU game....BYU was blowing out the Aggies, yet Rulon Jones didn't hesitate to sign my football for me, during the game. I've never forgotten that, thanks Rulon, I still have the ball.
- 11:13 p.m. July 5, 2014
- Like (1)
- Report abuse
I'm hoping this guy gets his place in the Broncos Ring of Honor, if that hasn't already. He was a great player, perhaps even Hall of Fame material.
- 4:03 p.m. July 6, 2014
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Sounds like Mr. Jones is one of the few that knows that there is life after football. Good for him and his wonderful family.
- 12:00 a.m. July 7, 2014
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10,000 acres?
One of "several" such hunting ranches?
Sounds like Rulon did pretty danged good!
Well, good for him. He deserves every penny of it!
- 6:57 p.m. July 7, 2014
- Like
- Report abuse
Watching the Broncos playoff game today from my place in the Bronx. I somehow came across this article. Many years ago, early 1980's, I was a young New Yorker who was living in the Denver area. I worked at a place called the "Foot Locker." One day, in came this "Giant" of a man, with very blonde hair and large feet. I was the one who waited on this man, and sold him a pair of athletic shoes. I am 55 years old, now, and recall that day but not the exact conversation of course. I do remember, however, asking this guy if he was a Denver Bronco. He said yes, and smiled. I said, "you're Rulon Jones, right?" He said yes. Rulon, you likely will never see this comment, but you could not have been nicer nor more decent. We talked for a lengthy period of time and I recall to this day your humility. I'm still and will always be a New York Giants fan, but you're one Bronco who made an impression on me way back when. Thank you, and wishing prosperity and health to you and your family.
- 4:13 p.m. Jan. 11, 2015
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Meir Panim Gives the Gift of Camp to Hundreds of Impoverished Children.
During the day, Shea Rubenstein works in real estate development. In the evenings he helps run the Jewish Community Council of Marine Park, an organization he helped establish, to meet the needs of the local community, as its executive vice president.
The Jewish Press: How long ago did you start this organization?
Shea Rubinstein: This organization started about two years ago. Over time, we have focused more on understanding the needs of our community and have developed different programs. I would say that Marine Park is the fastest-growing Jewish community in the world. Seven years ago, there were 50 families in Marine Park; now, we have over 1,000 frum, Shomer Shabbos families, almost all between the ages of 25 and 35. We have 14 shuls and three yeshivos within the district, ken yirbu.
We saw an opportunity to create achdus; it's a small community, outside Flatbush and Midwood, with a younger crowd with similar mindsets. Baruch Hashem, other organizations have been extremely helpful to us in the past. They are dealing with a big workload by representing their own communities. I figured, let's use the same model.
That's how a few individuals – Shua Gelbstein, Jeff Leb, Yossi Sharf and myself – decided to create this JCC of Marine Park. Each of us has our own area of expertise. Shua Gelbstein, who's a practicing attorney, is our legal mind, Yossi Sharf our financial whiz who serves as our treasurer, and Jeff Leb is our political strategist who knows local, City, State and Federal Government like the back of his hand. We all brought different ideas to the table and the JCC of Marine Park was formed.
Of course, we went to the rabbanim. Here we have 14 rabbanim, a Vaad HaRabbanim of Marine Park, and we work closely with them through that vehicle. We come up with ideas, and they give us their da'as Torah. They guide us on how to create achdus, and have our community prioritize issues, rather than relying on neighboring communities.
Where is Marine Park?
Marine Park begins after Midwood, at Nostrand Avenue, and continues until Flatbush Avenue, and from Kings Highway until Ave U. Mill Basin, Gravesend and Flatlands are a few different neighborhoods that border us. Even though we call ourselves JCC of Marine Park, we represent a lot of people in the 20's and 30's.
Tells us how you operate.
We have about 25 volunteers and a call center. People call with any issue, social services, or in need of some of the other projects we've developed. Volunteers take those phone calls and either they answer the questions, send them the paperwork or set up appointments for them with caseworkers or local organizations, when necessary.
Do the volunteers work home?
We have an office on Flatbush Ave and volunteers who get together at night, and work from their homes or offices. You phone the call center and tell them, for instance, "I need health insurance." They'll put you on hold and connect your call through to a woman who helps people with health insurance, HEAP, Medicaid and food stamps. She's a volunteer.
Let's say you need a job; they'll refer you to someone like me. Some people will call because they're in too high a bracket to qualify for Medicaid or food stamps, but they need money; they cannot sustain themselves. The rabbanim take care of qualifying a person for a project we came up with, called Project Mazon.
What is Project Mazon?
Tomchei Shabbos is an amazing organization that does fantastic things. Some people, though, might not be utilizing this wonderful organization. Many of the families in our community suffer in silence – they would rather starve than get a food delivery to their door. Their needs are different in that they have young families. They also need formula and diapers. For these reasons, we began Project Mazon.
We try to get everybody in the community to sign up, to donate five dollars a week via their credit card. They either go to ProjectMazon.org, on the web, or they'll call our office and give their information. We charge their credit card $5 or $10 a week, but the minimum is $5 a week, which is equivalent to a sandwich and a coffee. The money goes into one pot, one bank account.
Then, in order to qualify, any rav in the community has the ability to sign somebody up. So if somebody feels they need it, or if a rav feels that somebody in his shul needs help, he calls one central person. He gives him only the person's phone number and the grocery where they shop. From that week on, every Thursday morning, there's a $50 credit in that person's account, so they can purchase without anyone knowing. They prioritize their own shopping list and buy things that they really need for their family. It's all done anonymously so that people feel comfortable about accepting help. No one in the JCC knows who the recipients are; only the rabbanim know. Obviously, we all trust the rabbanim to qualify the people.
We worked it out with the kosher groceries in Marine Park, and in the high 20's and 30's for now. It takes 10 people giving $5 a week to help one family. So if we opened it up to the entire public, the system would be overwhelmed. I spoke about this recently at the Agudah Convention, and encouraged other communities to each start its own "Project Mazon" to support those who are struggling in their own communities. We have a standing offer to assist any organization that would like to start a similar program in its community with organizational support.
You have two big events coming up for Project Mazon. Can you tell us about those?
Yes, We do have two big events coming up for Project Mazon. The first event is coming up in less than two weeks. On July 21, 2010 – the day after Tisha B'Av is our Second Annual Project Mazon – Glatt Mart Barbeque. It starts at 7:00 p.m. and will be in a large tent at the playground of PS 240 – at 2500 Nostrand Avenue, between Avenues K and L, and it features the delicious meats of Glatt Mart and the wonderful talents of the renowned mentalist Shimi Illuzini. It is the only fundraising event of the year for Project Mazon and we encourage everyone to attend and help support your friends and neighbors who are in need of assistance.
The second event that we are running concurrently is our Project Mazon Raffle where you can win a free two-year car lease for a new Honda Insight! This is sponsored by Plaza Auto Mall car leasing. We are having the raffle is September, IY"H. One ticket is $36 and 4 tickets are $100.
You can find out more about the Barbeque and the Car Raffle at www.ProjectMazon.org, www.KosherQ.org, or email email@example.com.
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By most accounts, the one person with the political muscle to swing enough Democratic votes to override a veto is Sen. Schumer.
The next day, in a speech in New York to the Council on Foreign Relations, Mr. Kerry substantially upped the ante.
In Israel, the judiciary has established itself as superior to ALL other branches of the government.
The Fifteenth Day of the month of Av became a day of national rejoicing. The moment that had seemed hopeless became the moment of Redemption.
I think the melodies in our religious services have a haunting sound to them that just permeates your guts and gets into your soul. If you have any musical inclination, I think they inspire you to compose.
Cavalier analogies to the Holocaust are unacceptable, but Huckabee's analogy was very appropriate.
Pollard was a Jewish-head-on-a-pike for all American Jews to see and to learn the explicit lesson.
If the Iran deal passes, Obama's WH becomes world's leading financier of terrorism against Americans
{Originally posted to the author's website, FirstOne Through} Some passionate and eloquent liberals have bemoaned the state of inclusiveness among Jews today. Leon Wieseltier, editor of the New Republic penned an angry piece "J Street's Rejection Is a Scandal" about the exclusion in 2014 of J Street from the Conference of Presidents of Major American Jewish Organizations. […]
Magnanimity by Moshe Dayan, allowing Muslim control of the Temple Mount, led to today's situation.
It was modeled upon a similar fund that had been set up by Sephardic Jews in Venice. But Amsterdam's Dotar was initially more ambitious in scope.
Rav Aharon Margalit is a bestselling author – his book, As Long As I Live, has been translated into four languages – and a standing-room only lecturer. Both religious and non-religious audiences flock to hear him. What makes him so extraordinary? Rav Margalit is a Chasidic Jew who experienced incredible challenges from a very young […]
J Street is the vanguard (Jewish face)in support of Obama's Vienna Accords Nuclear Deal with Iran
"I hold the woman's place over that of men in every fundamental aspect of public and private life."
During the day, Shea Rubenstein works in real estate development. In the evenings he helps run the Jewish Community Council of Marine Park, an organization he helped establish, to meet the needs of the local community, as its executive vice president.
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Helping Our Children Feel Less Stress and Worry About Their Future
By AllisonCarmen on June 28, 2013
When the Boston Marathon tragedy occurred a few months ago, my friend's daughter came home crying. She was frightened for her own safety and the safety of the people she loves. She worried that the world would never be at peace. Her mother told me that she knew her daughter needed to feel sadness for what happened, but was concerned that this was yet another event that would increase her daughter's negative perspective on life. Another friend's daughter was very upset about what happened in Boston, but she still felt safe and remained hopeful that people are good and we can all find a way to live more peacefully. Both children were clearly affected, but one child despaired and the other still felt hopeful. Of course there are many different reasons these two children reacted differently, including their past experiences, family life and even genetic makeup. However, regardless of all of those factors, the future of each child's emotional and mental well-being will be dictated by their perspective toward life.
As parents, what can we do to help our children maintain an open and hopeful view about all they will face every day? Over the years, I developed the following exercise for my children after reading about an experiment in the Tibetan Book of Living and Dying, by Sogyal Rinpoche. I like to use it when they are stuck and not achieving a particular goal, but its implications are much more far reaching.
Ask your child to pick up a coin. Ask them to imagine that the coin represents whatever is bothering him or her. Sometimes they are upset about a bad grade, a tragic event or problems with friends. The last time I did it with my daughter she was upset about not doing well on a test. She is very concerned with her grades and sometimes fears when something goes wrong that she won't get into a good college or achieve her life goals. I asked her to hold a coin tightly clutched in her fist and extend her arm, with the palm of her hand facing the ground. I told her the coin she was holding represented her life's goals and all that is possible. The way she was holding it, so tightly in this example, shows her belief that she could only achieve her life goals and get into a good college if she did well on this test. I then had her let go and relax her grip and the coin fell to the ground. I explained that it is simply too hard and painful to hold on to anything so tightly with the belief that there is only one way.
Then I said Maybe there is another possibility here: Maybe you can let go of the coin and still keep hold of it. With her arm still outstretched, I asked her to turn her hand over so that her palm faced the sky. I then asked her to relax her hand and see if the coin still rested in her open palm. She let go and the coin was still there resting in her hand. I reminded her that holding the coin this way, relaxed in her palm, represents all the possibilities in her future, including achieving her goals in life no matter how she does on this or any future test. It allowed her to keep her dream of being successful regardless of this particular test or any other event in her life; she needn't grasp it so tightly.
This experiment shows children that life doesn't have to unfold one way, but instead there is open space in which life may unfold in many different ways and result in joy and success. It seems simple but this Maybe exercise teaches our children to hold the very thing they want but also leave space and room for other possibilities. If our children can learn the skill of looking at life other ways, opening up and letting go will be less scary and more inviting. It allows our children to maintain their dreams and goals while experiencing the twists and turns of the journey of life.
As for my friend's daughter that was scared and worried about her future after the Boston Marathon tragedy, this exercise helped her see that there were many possibilities for the future including being safe and helping to achieve a more peaceful society. It gave her back some hope and sometimes that is all it takes to change a perspective and MAYBE change the world.
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Kershaw (9-6) struck out seven, walked none and retired his last 15 batters while working on eight days' rest.
The game got serious in the second half: Chris Paul's Team World rallied to beat Luol Deng's Team Africa 101-97.
Training camp across the NFL began earlier in the week and a number of players suffered injuries.
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CAT ON A HOT TIN ROOF's Scarlett Johansson Stops By THE LATE SHOW Tomorrow
CAT ON A HOT TIN ROOF's Scarlett Johansson will appear on "The Late Show with David Letterman" tomorrow, Wednesday, November 21 between 11:35PM-12:35AM locally on WCBS2.
Tennessee Williams' Cat on a Hot Tin Roof stars Scarlett Johansson as Maggie, Ciarán Hinds as Big Daddy, Benjamin Walker as Brick and Debra Monk as Big Mama, and is directed by Rob Ashford. Cat on a Hot Tin Roof opens Thursday, January 17, 2013. Previews begin Tuesday, December 18. This limited engagement runs for 15 weeks only, through March 30, 2013.
The cast also includes Emily Bergl (Mae), Michael Park (Gooper), Vin Knight (Reverend Tooker), Brian Reddy (Doctor Baugh), Will Cobbs, Tanya Birl, Jordan Dean, Lance Roberts and Cherene Snow. Playing the children are Laurel Griggs, Victoria Leigh, Charlotte Rose Masi, George Porteous and Noah Unger.
The design team is comprised of Christopher Oram (Scenic Design), Julie Weiss (Costume Design), Neil Austin (Lighting Design) and Adam Cork (Composer and Sound Design).
In Cat on a Hot Tin Roof, "Big Daddy" Pollitt, the richest cotton planter in the Mississippi Delta, is about to celebrate his 65th birthday. He is distressed by the rocky relationship between his beloved son Brick, an aging football hero who has turned to drink, and his beautiful and feisty wife Maggie. As the hot summer evening unfolds, the veneer of Southern gentility slips away as unpleasant truths emerge and greed, lies and suppressed sexuality reach a boiling point.
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Grass-fed beef now available at Silver City Food Basket
There are 2 comments on the Silver City Sun-News story from Oct 21, 2012, titled Grass-fed beef now available at Silver City Food Basket. In it, Silver City Sun-News reports that:
Customers at the Silver City Food Basket quickly discovered the single section of freezer space devoted to a new product - locally raised, grass-fed beef.
Join the discussion below, or Read more at Silver City Sun-News.
#1 Oct 21, 2012
Now all you angry white folk out there resisting UN Resolution 21 and the big Green Movement, get in line.
This here is Earth-Friendly 'beef'.
Mmmm-Mm! Be a good cracker. Good cracker!! and enjoy this sinew-on-a-plate.
Like a hippy at an Occupy Wallstreet live-in biting into his girlfriend's hemp underwear; it's chewey and grating, but he FEELS he should enjoy it. Ya know.....for the cause.
#2 Oct 22, 2012
"The grass-fed beef is very lean, and requires somewhat different cooking...add a bit of oil or fat in cooking the meat...Per-pound prices range from $5.99 for ground beef....most customers expect that."
6 Bucks for old hamburg that you have to add YOUR OWN OIL to just to make it palatable. What a bargain.
So...just that? Do we ladle a helping of that Sapphire pond-scum onto it while it's still warm and before they go bankrupt?
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Sell tickets on your event homepage using your own payment gatewayI want to sell tickets to my event
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Vtg Roman Arch Range Shaker Set Salt Pepper Flour Sugar Depression Era Mckee +nr For Sale
YOU ARE offerDING ON THIS Vtg Roman Arch Range Shaker Set Salt, Pepper, Flour, Sugar Depression Era. Made byMcKee.These have theWonderful ScottyDog motif.
Nice Vintage Range Shaker Set
These Shakers,are in very good condition !
The salt & pepper shakersshow some picture wear (see pics )
These also comes with original metal holder!
Each shaker measures approx. 4.50" tall with cap and approx.2.5" wide
Caps are dented but all screw off with ease & the flour cap has had a couple of the holes enlarged.
Very Hard to find set...ready for your retro kitchen!
Please contact me with Questions
Thanks for Looking !
We are offeringthisitem on a3 day salewith . PLEASE READ THIS NOTICE! ALL PAYMENTS $$ AREDUE WITHIN24 HRS OF sales CLOSE, UNLESS ARRANGEMENTS AREMADE PRIORTOofferDING! WEGLADLY ACCEPT PAYMENTS PAYMENT OPTIONS MAY BE AVAILABLE, BUT YOU MUST MAKE ARRANGEMENTS PRIOR TO PLEASE FEEL FREE TOCONTACT Ph: Cell-419-308-0167 PERSONAL REFUND POLICY. We work very very hard to describe in detail our items and their condition. At the same time we try to take excellent care of our customers and we believe our response is proof of that fact. We do accept returns of items that we may have inadvertantly misrepresented and all items are sent insured w/ delivery confirmation included Careful packing & Shippingfor the continental lower 48 U.S.is $12.00 W/ DELIVERY CONFIRMATION & INSURANCEINCLUDED. Others & International Buyers shipping will need shipping to be figured, and must be shipped priority w/ insurance or 1ST class registered mail.
Ohio Residents must add 6.5% Sales Tax, or give us a valid Ohio vendors license.
We offer a wide variety of eclectic items on our sales.
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Vtg Roman Arch Range Shaker Set Salt Pepper Flour Sugar Depression Era Mckee +nr:
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C.J. McCollum hits the floater after dazzling off the dribble at Summer League (VIDEO)
Jul 14, 2013, 3:30 PM EDT
LAS VEGAS — The overall quality of play in Saturday's Summer League game between the Suns and the Blazers was among the best we've seen over the event's first couple of days, and a quick look of the rosters makes it easy to understand why.
Phoenix started four players that played heavy minutes in the rotation a season ago in Kendall Marshall, Markieff Morris, Marcus Morris, and P.J. Tucker, and Portland similarly rolled out legitimate NBA players in Thomas Robinson, Meyers Leonard, and Will Barton.
While the Suns looked much stronger and more dominant, particularly in the second half, the most impressive individual performance of the game went to Blazers' rookie C.J. McCollum, who finished with a game-high 22 points, to go along with three rebounds and four assists.
McCollum did a nice job of getting into the lane, and scored on shots like the one you see in the video clip above more than once. None of them came after a sequence as crazy as this, however, as McCollum lost control of the ball, before regaining it and then using a dynamic dribbling display to get away from the defenders and into the paint to convert the pretty floater inside.
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Andrew Wiggins and Karl-Anthony Towns are about to be finishing alley-oops from the best lob passer in the game.
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Manu Ginobili is a stud.
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Kerr says Luke Walton is a future head coach in the NBA.
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Toronto has shifted the roster to be more defensive, and be able to go smaller.
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Jimmy Kimmell is the best part.
Raptors hire Jerry Stackhouse as assistant coach
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Enter Andrei Kirilenko to save the day?
Report: Kings waiving Eric Moreland
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Will anyone claim him?
Jerry Colangelo: I think LeBron James wants to be part of Team USA
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Cavaliers star has avoided making a public decision
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Lakers were in a bad place when Jackson first stepped away
Mikhail Prokhorov backtracks on promise to marry if Nets didn't win a championship
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Brooklyn owner praises Adam Silver for filling in
LeBron James Twitter Q&A: NFL career, Kobe Bryant's best play, Ronda Rousey and more
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Cavaliers star also addresses his favorites – including place to play, rapper, and teammates
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Who is still out there: Top 10 free agents still on the market
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Bounce passes are less effective in baseball.
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Our Commitment To You
Every item is accompanied by a complete gem analysis & appraisal prepared by a G.I.A. Graduate Gemologist. Insist on this report when purchasing from anyone online - For your peace of mind.
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Is There an Effective Approach to Deterring Students from Plagiarizing?
- Lidija Bilic-Zulle,
- Josip Azman,
- Vedran Frkovic,
- Mladen Petrovecki
- … show all 4 hide
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The purpose of this study was to evaluate the effectiveness of plagiarism detection software and penalty for plagiarizing in detecting and deterring plagiarism among medical students. The study was a continuation of previously published research in which second-year medicals students from 2001/2002 and 2002/2003 school years were required to write an essay based on one of the four scientific articles offered by the instructor. Students from 2004/2005 (N = 92) included in present study were given the same task. Topics of two of the four articles were considered less complex, and two were more complex. One less and one more complex articles were available only as hardcopies, whereas the other two were available in electronic format. The students from 2001/2002 (N = 111) were only told to write an original essay, whereas the students from 2002/2003 (N = 87) were additionally warned against plagiarism, explained what plagiarism was, and how to avoid it. The students from 2004/2005 were warned that their essays would be examined by plagiarism detection software and that those who had plagiarized would be penalized. Students from 2004/2005 plagiarized significantly less of their essays than students from the previous two groups (2% vs. 17% vs. 21%, respectively, P < 0.001). Over time, students more frequently choose articles with more complex subjects (P < 0.001) and articles in electronic format (P < 0.001) as a source for their essays, but it did not influence the rate of plagiarism. Use of plagiarism detection software in evaluation of essays and consequent penalties had effectively deterred students from plagiarizing.
- Title
- Is There an Effective Approach to Deterring Students from Plagiarizing?
- Journal
Science and Engineering Ethics
Volume 14, Issue 1 , pp 139-147
- Cover Date
- 2008-03
- 10.1007/s11948-007-9037-2
- Print ISSN
- 1353-3452
- Online ISSN
- 1471-5546
- Publisher
- Springer Netherlands
- Additional Links
- Topics
- Keywords
- Plagiarism
- Scientific misconduct
- Students, Medical
- Schools, Medical
- Authors
- Lidija Bilic-Zulle (1) (2)
- Josip Azman (3)
- Vedran Frkovic (4)
- Mladen Petrovecki (1) (5)
- Author Affiliations
- 1. Department of Medical Informatics, Rijeka University School of Medicine, 20 Brace Branchetta St., 51000, Rijeka, Croatia
- 2. Rijeka University Hospital Center, Rijeka, Croatia
- 3. Department of Anatomy, Rijeka University School of Medicine, Rijeka, Croatia
- 4. Department of Anesthesiology and Intensive Care, Rijeka University Hospital Center, Rijeka, Croatia
- 5. "Dubrava" University Hospital, Zagreb, Croatia


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Richard G Plate
Gary Martin
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Sounds Like: Joe Bonamassa, Carlos Santana, Kenny Wayne Shepherd, Eric Clapton songs, BB King
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"Growing up in the South Side of Chicago can steer a person in many different directions. However one of the most alluring and adventurous paths is The Blues. That seemed to be guitarist's Paul Stott's destiny in life. In Central Florida, around 2010 he formed the Paul Stott Group and hasn't looked back since, winning the Orange County Blues Society People's Choice Award back to back in 2013 -14. Orlando Guitar Center crowned Paul; King of The Blues Guitar in consecutive years. Paul has assembled a team of top notch musicians to solidify their sound. Richard Plate on harp and lead vocals evokes Little Walter and William Clark's harmonica styles. Rich's voice is soulful with a little grit -a great combination for the blues. Gary Martin on bass is a seasoned veteran and backbone of this group. "Mighty Joe" Adcock on drums lays down some powerful percussion."


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hi all !
i m playing chess from long ..bt still i can,t think next to two step ...i mean i want to play 2 mint chess bt every time..my time is End ..and i lose game..what i should do to improve my 2 mint chess game..plz give me advice ..
Thanks ..i wil wait ur all of reply ..Take care all
I'd play longer games than 2 minutes if you're having trouble thinking of moves to make in that short of time.
I'm guessing this is shahmata again
His rating is pretty low.
thanks for repling ..:) i should play 5 mint game ...
Practice In 10|15 Mins. First. Don't Try 2 Mins. You Will Be Pressured. :]
just think only in shortest time.
2 minute or 5 minute chess won't really improve your chess... you will just repeat the same mistakes... play long, slow games to learn (20 minutes or more), then play quick games for fun.
Ok if u want to improve your chess then first u can play longer games 15min+
Then after u should play 3min or 5min blitz and improve your game by learning ur mistakes in 15min.If u can think quicker in less time ur games automatically improves..
Imo read a book called Bobby Fischer teaches chess. Then pick an opening for both sides and learn about them.
Speed chess is even more fun if you learn the game at slower speeds first.
first try to play 10mints stantdard time then analyze your games with computer for mistakes, try not to repeat same mistakes again and again, by this way you can improve. You must have to overcome and learn with mistakes and inaccuracies and avoid them. try to open up games with sharp tactical openings ie e4, d4.
If that's true, I've wasted my entire life.
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Peter Jackson's sequel took $92m over Christmas Day and Boxing Day
Will Ferrell
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Tuesday 24 June 2008
To have one trade union paralyse Hollywood was strange; two doing it in quick succession feels like carelessness. A threatened walkout by actors, which could begin as early as next week, is throwing major film and television studios into chaos.
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Today's Horoscope by Rick Levine
Everyone seems to be paying extra close attention to what you say today with so many planets traveling through your 3rd House of Communication. However, it's crucial to focus on the integrity of your actions at all times, making certain they are consistent with your thoughts or you may end up in a rather difficult position. However, the current emphasis is on production now, so you must buckle down and do what must be done. Save the speech for another day.
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Cops: East Farmingdale woman stole family's jewelry
Ashley Lucarello is accused of stealing $3,000 worth of jewelry and selling it for cash.
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Hot Halloween tradition continues in Lido Beach 'It's crazy that I survived' Suspect scratches 30 vehicles on Massapequa street One camper's beginning and another's end Splish Splash thrills visitors on Long Island Turtles released back into the wild in Hampton Bays Osprey untangled from fishing line Lemurs can paint! Car lurches into service garage, knocks another car off lift Famous Montauk eatery sold Tour of Stew Leonard's Shooting in Bay Shore leaves man critical


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- Prizes
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Welcome to Lambda Literary's online book club. This book club will highlight a different lesbian, gay, bisexual and transgender book each month. The books selected will be a heady mix of LGBT classics, unheralded gems, and buzz-worthy new releases.
We hope you'll read along with us each month and share your thoughts on the books in the comments section.
We'd also love to hear your suggestions for upcoming selections or comments on the club in general. E-mail William at firstname.lastname@example.com.
This month's selection is Muse by Jonathan Galassi:
From the publisher of Farrar, Straus and Giroux: a first novel, at once hilarious and tender, about the decades-long rivalry between two publishing lions, and the iconic, alluring writer who has obsessed them both.
Paul Dukach is heir apparent at Purcell & Stern, one of the last independent publishing houses in New York, whose shabby offices on Union Square belie the treasures on its list. Working with his boss, the flamboyant Homer Stern, Paul learns the ins and outs of the book trade—how to work an agent over lunch; how to swim with the literary sharks at the Frankfurt Book Fair; and, most important, how to nurse the fragile egos of the dazzling, volatile authors he adores.
But Paul's deepest admiration has always been reserved for one writer: poet Ida Perkins, whose audacious verse and notorious private life have shaped America's contemporary literary landscape, and whose longtime publisher—also her cousin and erstwhile lover—happens to be Homer's biggest rival. And when Paul at last has the chance to meet Ida at her Venetian palazzo, she entrusts him with her greatest secret—one that will change all of their lives forever.
Studded with juicy details only a quintessential insider could know, written with both satiric verve and openhearted nostalgia, Muse is a brilliant, haunting book about the beguiling interplay between life and art, and the eternal romance of literature.
Enjoy and remember: reading is fundamental
By Jonathan Galassi
Hardcover, 9780385353342, 272 pp.
June 2015
Buy Amazon | Publisher | Indiebound


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Jockey Daryl Jacob feels Easter Day could be the perfect type to excel at Aintree in April after he strolled to victory in the Neptune Investment Management Novices' Hurdle at Huntingdon.
The Paul Nicholls-trained youngster was a standout on the formbook, having finished second to Jonjo O'Neill's Taquin De Seuil in a Grade One at Newbury. Because of that he was sent off the 4-9 favourite for the race better known as the Sidney Banks Memorial Novices' Hurdle - despite giving plenty of weight away to all his rivals.
Jacob had already won on the five-year-old at Fontwell and Ascot and took his tally to three from three on him with an all-the-way four-length success over Nataani. Nicholls had taken him out of the Cheltenham novice events earlier in the week, but Jacob feels Aintree could be perfect for him.
Jacob said: "He's a very good novice. I'm three from three on him now and he did it well.
"It wasn't ideal making all the running on him but when we realised nothing else would go on we decided to just keep it as straightforward as possible. He'd won over further so I was prepared to go on. He'll have learned a lot. He's not going to Cheltenham so I imagine it will be Aintree for him. That should suit him well there as it's usually lovely ground."
Jacob had earlier won on David Arbuthnot's Rocky Elsom in the TurfTV Novices' Handicap Hurdle.
Sent off at 9-2, he had only been put up 3lb for a Plumpton win and there appears to be more to come still. Punters would do well to keep in mind when Jacob teams up with Arbuthnot as the pair now operate at a strike-rate of over 25%.
Jacob added: "I've got a good strike-rate to keep up for David so it was nice to win. Rocky is improving and the better ground is helping him. The tongue-tie obviously makes a difference and he's on an upward curve. The front two pulled a long way clear."
With the Cheltenham Festival rapidly approaching, Nicky Henderson showcased that his string are peaking at just the right time with another double.
Fresh from two winners at Doncaster 24 hours earlier, Henderson was on the mark with Tetlami (11-10 favourite) in the Huntingdon Racecourse Novices' Chase and Miss Ballantyne (3-1) in the racinguk.com Mares' Novices' Hurdle.
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Scientists at Brown University's Center for Capture and Conversion of CO2 have discovered that copper foam could provide a new way of converting excess CO2 into useful industrial chemicals, including formic acid.
A catalyst made from a foamy form of copper has vastly different electrochemical properties from catalysts made with smooth copper in reactions involving carbon dioxide, a new study shows.
The research, by scientists in Brown University's Center for the Capture and Conversion of CO2, suggests that copper foams could provide a new way of converting excess CO2 into useful industrial chemicals.
The research is published in the journal ACS Catalysis.
As levels of carbon dioxide in the atmosphere continue to rise, researchers are looking for ways to make use of it. One approach is to capture CO2 emitted from power plants and other facilities and use it as a carbon source to make industrial chemicals, most of which are currently made from fossil fuels. The problem is that CO2 is extremely stable, and reducing it to a reactive and useful form isn't easy.
"Copper has been studied for a long time as an electrocatalyst for CO2 reduction, and it's the only metal shown to be able to reduce CO2 to useful hydrocarbons," said Tayhas Palmore, professor of engineering and senior author of the new research. "There was some indication that if you roughen the surface of planar copper, it would create more active sites for reactions with CO2."
Copper foam, which has been developed only in the last few years, provided the surface roughness that Palmore and her colleagues were looking for. The foams are made by depositing copper on a surface in the presence of hydrogen and a strong electric current. Hydrogen bubbles cause the copper to be deposited in an arrangement of sponge-like pores and channels of varying sizes.
After depositing copper foams on an electrode, the researchers set up experiments to see what kinds of products would be produced in an electrochemical reaction with CO2 in water. The experiments were performed by Sujat Sen and Dan Liu, graduate students in chemistry working in Palmore's lab at Brown's School of Engineering.
The experiments showed that the copper foam converted CO2 into formic acid — a compound often used as a feedstock for microbes that produce biofuels — at a much greater efficiency than planar copper. The reaction also produced small amounts of propylene, a useful hydrocarbon that's never been reported before in reactions involving copper.
"The product distribution was unique and very different from what had been reported with planar electrodes, which was a surprise," Palmore said. "We've identified another parameter to consider in the electroreduction of CO2. It's not just the kind of metal that's responsible for the direction this chemistry goes, but also the architecture of the catalyst."
Now that it's clear that architecture matters, Palmore and her colleagues are working to see what happens when that architecture is tweaked. It's likely, she says, that pores of different depths or diameters will produce different compounds from a CO2 feedstock. Ultimately, it might be possible to tune the copper foam toward a specific desired compound.
Palmore said she's amazed by the fact that there's still more to be learned about copper.
"People have studied electrocatalysis with copper for a couple decades now," she said. "It's remarkable that we can still make alterations to it that affect what's produced."
The work in the study is part of a larger effort by Brown's Center for the Capture and Conversion of CO2. The Center, funded by the National Science Foundation, is exploring a variety of catalysts that can convert CO2 into usable forms of carbon.
"The goal is to find ways to produce some of the world's largest-volume chemicals from a sustainable carbon source that the Earth not only has in excess but urgently needs to reduce," said Palmore, who leads the center. "This is a way for us as scientists to begin thinking of how we produce industrial chemicals in more sustainable ways and control costs at the same time. The cost of commodity chemicals is going nowhere but up as long as production is dependent on fossil fuels."
The Center for Capture and Conversion of CO2 is a Center for Chemical Innovation funded by the National Science Foundation (CHE-1240020).
Kevin Stacey | Eurek Alert!
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Further reports about: > CO2 > chemicals > colleagues > copper > dioxide > experiments > foam
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