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Business Development White Papers
Red Hat Jboss Data Grid Supercharges Modern ApplicationsSponsored by: Red Hat
Read this white paper to learn how to supercharge your modern applications and meet both immediate and long term IT goals.
Stop Gathering Requirements and Start Building ThemSponsored by: Global Knowledge
We build requirements at a quantum level to connect the vital elements, which are needed to realize a requirement. Realizing a requirement means joining these elements together and noting them as elements of the requirement and not individual requirements in of themselves.
Using SIPOC to Define ITIL® ProcessesSponsored by: Global Knowledge
This white paper describes a technique for defining processes called SIPOC (Suppliers, Inputs, Process, Outputs, and Customers). SIPOC provides a structured way to define the key elements of any process. SIPOC can be used as a means of defining any of the service management processes presented in ITIL® best practices.
Dell Storage SCv2000 Series: Best performance and protectionSponsored by: Dell, Inc. and Intel®
This infographic introduces the entry-level Dell Storage SCv2000 Series that delivers performance, data protection, and scalability that critical applications need. Check it out now to see how to manage every Dell Storage SC array from one interface.
DevOps on IBM z Systems E-guideSponsored by: IBM
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6 Benefits of Unified Communications as a ServiceSponsored by: XO Communications
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SharePoint at Rackspace: The Leading SharePoint Hosting SpecialistsSponsored by: Rackspace
By putting your SharePoint in the cloud, SharePoint specialists will manage it for your and provide the planning and implementation guidance you need to get back to business.Read this white paper to learn more about the benefits of putting SharePoint in the cloud.
Simplify HR to Drive Performance Leading HR Organization Share Their StrategiesSponsored by: Workday
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How can you harness big data correctly to yield valuable information and give your organization a competitive edge? In this valuable white paper, learn why ERP software is your best business intelligence tool for harvesting and analyzing big data.
How Michigan State University Calculates Likelihood of Philanthropic EngagementSponsored by: IBM
This case study describes how MSU leveraged business intelligence and predictive analytics to gain deep insight into an individual alum's potential to give.
The One that Got Away: How to Identify and Re-Engage Lapsed CustomersSponsored by: Silverpop Systems Inc. an IBM Company
Access this valuable resource to learn how you can reach out to lapsed customers and shore up your customer loyalty and retention using proven data-driven processes. Read on to learn how retailer Milk&More was able to implement these strategies to win over their lapsed customers.
Ultimate Guide to Assessing Your Digital Marketing ProgramSponsored by: Silverpop Systems Inc. an IBM Company
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Case Study: How John Lewis Conquered the WebSponsored by: ComputerWeekly.com
Bill Goodwin tells the inside story of John Lewis £40m website redevelopment project, assesses the technical and business challenges faced and its impact on the business.
ROI Case Study: Salesforce Data.com Tableau SoftwareSponsored by: ComputerWeekly.com
Analyst group Nucleus Research examines how Tableau Software's used Salesforce Data.com to identify sales leads across regions and to manage its customer data within a single, centralised solution.
CIO insights: Moving from the back office to the front lineSponsored by: ComputerWeekly.com
This major global C-level survey from IBM examines the changing role of the CIO and makes recommendations for CIOs who want to move from the back office to the front line of the business.
Big Data analytics: Adoption and employment trendsSponsored by: ComputerWeekly.com
The report is first of its kind to identify current and future adoption rates for big data by type and size of organisation in the UK with information supplied by 1,000 businesses across the country.
A Guide for CIOs: Make Your Mark with Business TransformationSponsored by: Hewlett-Packard Company
Review this informative white paper to discover the importance of implementing a formal transformation program. Gain insight into 2 business transformation success stories, 9 reasons why you should work with an experienced transformation partner, a simple 5-phase business transformation program, and much more.
Benefits Management: How to increase the business value of your IT projectsSponsored by: ComputerWeekly.com
This book extract explains how organisation can uses benefits management techniques to increase the value of IT projects to the business.
Top 10 Business Analysis Trends for 2013Sponsored by: ComputerWeekly.com
A global panel of experts identifies the Top 10 Business Analysis trends in 2013
Are You Ready For a New Era in B2B Collaboration?Sponsored by: IBM
This white paper examines what companies can do to modernize their approach to business-to-business collaboration in response to trends like globalization, consumerization, and mobility.
Key Considerations and Features of AWSSponsored by: Looker
In this e-guide, experts explain various features and benefits of AWS such as on-demand, reserved and spot instances and which one will fit your needs. Inside, learn why Amazon's new Redshift data warehouse is creating a biz buzz among IT pros.
Seven Steps for Effective Leadership DevelopmentSponsored by: Oracle Corporation
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Three Capabilities to Fuel Today's Dynamic Planning, Analysis and ForecastingSponsored by: IBM
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Presentation Transcript: Best practices for integrating and optimizing analytics into your DB2 for z/OS dataSponsored by: IBM
View this presentation transcript and learn how you can integrate and optimize Cognos® BI, SPSS® predictive analytics and DB2 Analytics Accelerator with your DB2 for z/OS data to deliver greater benefit to the business — and speed query response times.


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"How To Email Busy People"
18 Nov, 2012 by Craig Newmark
Print this article Font size -16+
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Father Hands Out Haymakers to Teenage Girl Punks for Attacking His Daughter [Video]Jun 29, 2015 | By Terresa Monroe-Hamilton
This dad punches the crap out of two girls attacking his daughter. Tell me you wouldn't do the same if a pack of thugs were beating on your child. I...Read More
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I-44 South – The Loneliest Road in Oklahoma [VIDEO]
If there was one stretch of road in Oklahoma that everyone dreads, it's I-44 between Lawton and Wichita Falls.
If there was one stretch of road in Oklahoma that everyone dreads, it's I-44 between Lawton and Wichita Falls.
When it comes to entertaining and virtuoso metal YouTube videos, the multitalented Rob Scallon has become the go-to guy.
After months of back-and-forth, the National Football League has decided not to shorten Tom Brady's four-game suspension for tampering with game balls prior to January's AFC Championship game.
We sat down some kids and asked them to give us their own interpretations of Motley Crue's "Dr Feelgood."
This guy may have gone for a bike ride, but that's not how he got his workout on this particular day.
Some people are born with greatness, some have it thrust on them. Everyone else? They're like this guy.
Puscifer are on their way back with the 'Money Shot' album. Get additional details and see the 'Grand Canyon' video here.
While the hay-day of stunt-men may be gone, there are still a few left pushing the boundaries. This truck can fly!
Apparently, in Japan, not only is professional pillow wrestling a sport... there is a ton of people who love watching it.
The Mako shark. Not only the fastest predator in the ocean, officially the most athletic of all the fish.
"What the hell are they screaming about?" Here are 10 Amazing Death Metal Vocalists You Can Actually Understand!
During a Smashing Pumpkins VIP question and answer event on July 13 in Colorado, a fan asked singer Billy Corgan if he thought Courtney Love killed Kurt Cobain.


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San Japan animates downtown (w/video)
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San Japan animates downtown
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Firefighter killed, 2 dozen homes burn in California fires
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iHeartMedia Inc. reports second-quarter loss
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Phelps set to swim four events in S.A.
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12 courses of modernist love in special dinner
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Psst, S.A.! Norman Lear planning Latino 'One Day at a Time'
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21 of S.A.'s hottest fitness coaches
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Your Turn: August 2
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2015 Hyundai Sonata Eco — another competitor in the midsize sedan field.
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U.S. paychecks grow at record slow pace
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'Big Bang Theory' star buys $9 million home
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Associated Press
This undated family photo provided the Show of Support, Hunt for Heroes committee shows Sgt. Maj. William Lubbers, 43, one of four veterans killed when a parade float he was riding on was struck by a freight train at a crossing Thursday, Nov. 15, 2012, in Midland, Texas.
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(240): View more from Maryland
Thanks for last night it was amazing as always
Tap Here to view the Mobile Optimized TFLN
Thanks for last night it was amazing as always
im pretty sure i tried to attack the vending machine last night
It was annoying to wait 4 hour for him to be inside for 5 seconds.
she's sitting here naked with heels and a taco.
I just had a heart to heart with a stripper I'm becoming a dentist.
I will also be strapping forties to the puppies.
Really? How much of his life do you think he remembers? I'm pretty sure 75% of it qualifies as "kind of a blur".
he spent an hour trying to convince us that Ted Nugent is Kid Rock from the future. by the end of it i was very close to believing him.
he shit on the floor last night i'm not venturing down there
I JUST WATCHED PAULA DEEN PUT BUTTER IN HER BLOODY MARY. This is not a drill. Real life.
unless you have a dick and you were thinking of chopping that off
You should make us a hot pocket to split while I go throw up.
Hey don't blame me, picking what flavor of condom to put on my dick is a very difficult selection process
He's not drinking on his 21st. Shooting vodka infused Nerf bullets at him would just make a mess and I don't want to be a creep and spike anything... I don't understand awkward boys
Dude, you stalking his LINKEDIN profile will NOT affect your chances with him. We aren't 40...


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Senior editor, noted cactus-killer.
I'm the Editorial Director of BuzzFeed Life. I like shopping and bubblegum. Ask me about my UK hardcore band.
Preview Your Response
Here Are The Top Stories
- More debris – believed to be part of the missing aircraft MH370 – has been found washed up on the Indian Ocean island of Réunion on Sunday.
- Cilla Black, the legendary English singer and TV star, has died at her home in Spain, according to local police. She was 72 years old.
- A conservation group at Oxford University told BuzzFeed News that media reports of Jericho's death were not true and that the 11-year-old lion was "alive and well".


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Now Foods, Essential Oils, Lavender, 4 fl oz (118 ml)
Items 1-2 of 2 total
A little bit disappointed about the smell.
Posted by Reviewer3142372 on Feb 17, 2010
I bought this product because of all the wonderful reviews and I love lavender smell. However, it is not as good as I expected. The smell is not strong and long-lasting enough when using for washing linens and spraying room.
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Note: iHerb does not imply any medical claims from this review. Disclaimer.
Lavender Oil
Posted by Reviewer1426028 on Sep 08, 2011
Not as good as I expected. I like a stronger lavender smell.


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Related quotes
"The glory of friendship is not the outstretched hand, nor the kindly smile, nor the joy of companionship; it is the spiritual inspiration that comes to one when he discovers that someone else believes in him and is willing to trust him with his friendship."
Contributed by: Maria Green
"I think musically, if you talk to (drummer) Matt Chamberlain, he'll tell you it's really complicated rhythmically."
"I had a moment like that with Wilt (Chamberlain). He knocked me out of bounds, I came back and faked him, came across the middle and dunked on him."
"So Esther's maids and her chamberlains came and told it her. Then was the queen exceedingly grieved; and she sent raiment to clothe Mordecai, and to take away his sackcloth from him: but he received it not."


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Published on
This presentation was made at the Nasscom Tech Series Big Data event held in Chennai on 06-Feb-2013 and was made by Somjit Amrit, the Chief Business Officer for Technosoft Corporation
In this presentation Somjit makes the case for why historically Business and IT haven't gone together hand in hand and goes on to state that Big Data could be what brings them together. He also emphasizes the importance of Big Data in addressing the fourth V namely Veracity (the others being Velocity, Volume and Variety).
Clipping is a handy way to collect important slides you want to go back to later.


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All hotels in Kranjska Gora, Slovenia
1 room, 2 adults
Koroska ulica 14c, Kranjska Gora, Slovenia, 0203 027 9779
Skipass Hotel, Lake Bled - Julian Alps
Lowest price£169
Best Price Guarantee
Kranjska Gora ski hotel with ski rentals, ski passes
- Free buffet breakfast and WiFi
Main amenities
- 10 smoke-free guestrooms
- Restaurant and bar/lounge
- Ski rentals and lessons
- Health club
- Airport shuttle
- Terrace
- Daily housekeeping
- Garden
- Laundry service
- Meeting room
- Tour/ticket assistance
What's around
- Kransjka Gora Ski Resort (0.4 mi / 0.7 km)
- Lake Jasna (0.9 mi / 1.5 km)
- Zelenci Nature Reserve (2.2 mi / 3.5 km)
- Planica Ski Jump (4.7 mi / 7.5 km)
- Finkenstein Castle (15.1 mi / 24.3 km)
Reviews & ratings
A beautiful hotel with excellent, friendly staff who can't do enough for you. The food is excellent and the fitments throughout this newly built hotel are very classy. Just one…
TripAdvisor Traveller Rating: 5
From 128 reviews
Enter dates to check prices
Hotel Info: 020 3027 9803from £169
- Triple Room
- Superior Room
- Classic Room
Recommended hotels
At a glance
Key facts
Hotel size
- This hotel has 10 rooms
- This hotel is arranged over 1 floor
- Check-in time starts at 2 PM
- Check-out time is 11 AM
Required at check in
- Credit card or cash deposit required
- Government-issued photo ID required
- Minimum check-in age is 16
Travelling with others
Extra people
- Rollaway beds available, charges may apply*
- Free WiFi in public areas
- Free WiFi in rooms
- Airport shuttle *
- Accessible parking
Other information
- Smoke-free property
Nearby Four Star Lake Bled - Julian Alps hotels
In the hotel
Food and drink
- Free buffet breakfast
- Restaurant
- Bar/lounge
- Room service
Things to do
- Ski shuttle
- Ski passes available
- Health club
Working away
- One meeting room
- Tours/ticket assistance
- Dry cleaning/laundry service
- Number of buildings/towers - 1
- Year Built 2012
- Elevator/lift
- Garden
- Terrace
- Disabled parking
- Accessible path of travel
- Accessible bathroom
- In-room accessibility
In the room
Home comforts
- Ceiling fan
- Minibar
- Bathrobes
- Slippers
Sleep well
- Premium bedding
- Sleep Number by Select Comfort mattress
Things to enjoy
- Balcony
Freshen up
- Partially open bathroom
- Rainfall showerhead
- Shower only
- Designer toiletries
- Hair dryer
Be entertained
- Flat-screen TV
- Premium TV channels
Stay connected
- Free WiFi
- Phone
Food and drink
- Refrigerator
- Daily housekeeping
- In-room safe
Top Lake Bled - Julian Alps hotels
Recently reviewed hotels in Lake Bled - Julian Alps
- Hotel ibis WoertherseeFrom
"Used the room as a convenient accommodation for festival. Comfortable clean and reasonably priced."Jul 12, 2015
- Hotel Astoria BledFrom
"Quick 2-day visit, first time in Bled. Hotel was perfectly positioned, staff were incredibly helpful and friendly and we are so happy with our little find."Jul 4, 2015
- Hotel KompasFrom
"We arrived in a car and had no problem parking although there were limited spaces. The hotel was larger then we usually stay in but it was very nice. The rooms were average size…"Jul 1, 2015
- Chalet KammleitnFrom
"Had great time there but at the was asked for €3.40 tax which wasn't mentioned while booking.need to work on it."Jun 29, 2015
Special features
DiningSkipass Restaurant - This restaurant specializes in local cuisine.
On Site
- Health club
- Ski lessons on site
- Ski equipment rentals on site
- Ski equipment rental shops nearby
- Cross-country skiing nearby
- Downhill skiing nearby
- Sledding nearby
- Snowboarding nearby
- Snowshoeing nearby
Skipass Hotel, Lake Bled - Julian Alps's small print
Mandatory fees
You'll be asked to pay the following charges at check in or check out:
- A tax is imposed by the city: EUR 1.50 per person, per night for adults; EUR 0.75 per night for guests aged 3-12 years old. This tax does not apply to children under 3 years of age.
Optional extras
Cribs/Infant beds are available for EUR 10 per night
We have included all charges provided to us by this hotel. However, charges can vary, for example, based on length of stay or the room you book.


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Aug 2
I will be singing for the 9:00 & 11:00 am services! Come here the always illuminating Josh Reeves speak as I sing while the fabulous Bill Wolfe accompanies me!Tickets Save
Sep 6
I'll be singing for both services at 9:00 & 11:00 AM. Come on down and hear Moira speak and me sing with a great band led by John-Henri and the boys!Tickets Save
Oct 25
A wonderful community led by Joshua Reeves! I will be singing for BOTH the 9:00AM & the 11:00 AM services accompanied by the fierce Bill Wolfe!Tickets Save
Nov 15
Love to hear Carolyn speak! She is awesome! I will be singing at both the 9:00 AM & the 11:00 AM services. Come on down!Tickets Save
Sounds Like: Adele, Amy Whinehouse, Faith Rivera, Karen Drucker, Peter Mayer
Label: Mind Body Spirit Publishing
Bio: Singer, Songwriter, and Student of Life
Kelly's music is a celebration of awakening. Her work is a masterful combination of deep spiritual messages that touch the heart and lift the soul….set to her fresh and often surprising music style. Her lyrics borrow from ancient wisdom traditions as wel...See Full Bio
: Kelly Corsino has a show on 08/02/2015 at 09:00 AM @ Seal Beach Center fo... in Seal Beach, CA http://t.co/ac4OffCe29 #concert
"Get ready to rock and raise the inner spirit! Kelly Corsino, a 2012 Posi Award Nominee, generously gives her musical gift to the New Thought movement. Her vibrant, luminous voice lifts her positive messages into the realm of magic, where all things are possible. Within refers to the love within all, and it is celebrated in a powerful way through Kelly's voice. When Kelly sings"


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A perfect 10, Underwood's shimmery plum Abed Mahfouz gown was a more sophisticated style than the short glittery numbers she normally dons -- and she's never looked better!
Amber Rose is over all the Kardashian drama.
Maybe she's born with it. Maybe she just uses a lot of lotion.
If there is one lesson to be learned in 2015, it is the following: do not f*** with Nicki Minaj.


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Email AddressVerified
Phone Number▒▒▒▒▒▒▒▒▒ 85
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Reviewed8 Reviews
About Me
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- Elio's Airbnb Symbol
Hey, I'm Elio!
Barcelona, Spain · Member since May 2012
You have reported this user. Undo?
Hii! how is it going? Allow me to introduce myself: my name is Elio. I'm 25. I was born in Argentina, (son of italians) but i've been living in Spain for 5 years now. (sounds like a job interview lol)
I love travelling as much as I can, I enjoy tipical touristic cities as well as more relaxed and chill out not-too-crowded places.
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One of the main reasons I'm sharing my flat it's that I get to know people from all over the world. And make friends, why not?
If you have any questions, don't hasitate in contact me. I reply as a soon as i can,


text: TOP 10 Top 10 Entertainment The 5 Best Cuts Of Beef Share Tweet 0 Shares 4. Tenderloin The tenderloin, referred to in other parts of the world as a filet, is a cut from the loin of beef. The tenderloin exists beneath the ribs and next to the backbone. The tenderloin is, as its name implies, the most tender cut of beef. Those who do not prefer the marbling of the rib eye and strip loin will thoroughly enjoy the tenderloin. Next Page TOP 5 4 3 2 1 Comments Show Comments More Like This Top 10 Dating Everything You Know About Cheating Is Probably A Myth Read More Top 10 Entertainment Ten Insane Movie Stunts You Have To See To Believe Read More Top 10 Dating 11 Places To Touch Her That Will Make Her Melt Read More Top 10 Fitness 10 Foods You Can Eat To Give Your Swimmers More Strength Read More Top 10 Dating Is She Interested Or Just Being Polite? 10 Signs You Should Be Looking Out For Read More Top 10 Better Man Ten Things You Need To Stop Doing Once You Turn 30 Read More Around the Web Special Features Special Feature Revealed: The Final Word On Getting & Maintaining The Body You Want Read More Special Feature Over 100 Ways To Make This The Most Jaw-Dropping Year Of Your Life Read More ad


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APA Referencing Macros 64-bit download - Macros to automate the referencing of
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APA Referencing Macros are Microsoft Word macros that will automate the referencing of essays etc. written to conform to the Style as set out in the Publication Manual of the American Psychological Association, Fifth Edition (2001). They come with a document already formatted with the Title, Author, Institution, Header, Running Head, Headings, Subheadings, first line indent & double spacing. They can reference sources from Books, Reports, Brochures, Audiovisual media, Journals, Newspapers, Magazines, Book Chapters or Articles in a Collection, Translated Works, Entries in Encyclopedia (including CD-ROM), Non periodical Internet Documents, Parts of Non periodical Internet Documents, Articles in Internet Periodicals, Messages Posted to Online Newsgroups, Forums, or Discussion Groups & Internet Journal Articles from Databases. They will show you how to enter each different type of material ie Sentence case for Book Titles, Headline case for Journal Titles etc. They will add the appropriate reference to the References section, including the italics, hanging indent and double spacing, and the appropriate in-text citation. They will add quotation marks to short quotes and indent the paragraph for long quotes. They will save all your references with the document you create for subsequent in-text citation, no need to do all your referencing in one session. They will automatically insert the appropriate number of authors to list in subsequent in-text citations as per APA Style. They will sort the references with the click of a button
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By Ryan Clark | June 10, 2011 | Comments
-- Rock Pink, a charity whose mission is to raise breast health awareness and support local breast cancer programs, is holding an auction for one lucky fan to bowl with TNA Knockout Angelina Love in Orlando, Florida.
The auction can be accessed via eBay.com. It concludes next Friday.
Dwayne "The Rock" Johnson Offers His Thoughts On Hulk Hogan Controversy
Firemen Help With WWE Tough Enough Challenge, More On Daniel Bryan Book Success, ZZ Dressed Down
Kevin Nash Says WWE Has Taken The Market, Gives Credit To Triple H, Talks Being A Dolph Ziggler Fan
More On John Cena Suffering A Broken Nose, Big Jump For WWE Stock, Kevin Nash: Too Sweet
How Did Ring Of Honor's Late Airing Do On Destination America?, TNA Impact Viewership Up
Former WWE Creative Writer Speaks Out About Brock Lesnar Gay Character Storyline Pitch
WWE SmackDown Live Viewing Party
John Cena Injury Update From Last Night's RAW
** SPOILERS ** WWE SmackDown Results For This Week
Sting Not Appearing At WWE SummerSlam After All?, Speculation Among WWE Talents Backstage
Scott Steiner Gives His Thoughts On Hulk Hogan Controversy And Racism
JTG Talks How Black Wrestlers Are Portrayed In WWE, How Cryme Tyme Gimmick Happened


text:
Appartamento Cornelia D
From $705 / week
Description from the manager
Description from the manager
Bedrooms: 2/
Bathrooms: 1/
Sleeps: 6/
Type: House
Appartamento Cornelia D is a cozy apartment situated at a short distance from the shores of Lake Como . It sleeps six people. From Appartamento Cornelia D you will enjoy a broad view of Lake Como and of the Comacina island. Appartamento Cornelia D is 90 square meters (970 square feet). It features a shared swimming pool, a nice private terrace with a view of the lake, a shared garden and winter heating.
You will be approximately 300 meters (330 yards) from Lenno . You will find the closest restaurant at 150 meters (490 feet), a grocery store at 500 meters (550 yards), the stop for the local bus at 200 meters (660 feet) and the closest beach at ...Read more
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Summer In Italy
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Appartamento Cornelia D Ossuccio, Lombardy, Italy
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Wednesday, 30 Nov 2011 06:15 PM
Alibaba Group Holding Ltd. and Softbank Corp. are in advanced talks with Blackstone Group LP and Bain Capital LLC about making a bid for all of Yahoo! Inc., said three people with knowledge of the matter.
The group has prepared financing for a possible bid, said one of the people, who declined to be identified because the discussions are private.
Alibaba hasn't informed Yahoo of its bid and is still talking with other private-equity firms including Providence Equity Partners Inc. about teaming up for a potential offer, one person said. Alibaba prefers not to make a hostile bid for Yahoo and wants to be invited to make an offer for the entire company, the person said. The group may also decide not to make a bid, the person said.
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The blessings of salvation begin on Earth through intimacy with Christ. Jesus desires to commune with us as every part of our being becomes set apart for Him. read more
Page 3 of 33
The blessings of salvation begin on Earth through intimacy with Christ. Jesus desires to commune with us as every part of our being becomes set apart for Him. read more
One of the most stunning comments I ever heard, almost a throwaway remark, came from one of the most famous ministers in the world. He said to me, "R.T., the more God uses me, the less I am able to enjoy it."
This may be incomprehensible to some, but I know exactly what he meant. God has many ways of ensuring that while we enjoy His blessing, we do not become conceited. read more
We cannot know who we are in Christ until we understand God's amazing grace and love for us. His grace allows us to be transparent about our weakness and open to His strength. read more
Countless women worldwide are struggling to survive abusive circumstances. As their Christian sisters, we must pray and mobilize efforts to help them find freedom in Jesus. read more
Knowing how to pray effectively does not come automatically. Effective prayer ministers must be well grounded in God's Word and experienced in following the Spirit's leading. read more
Sometimes our initial pursuit of revival brings reproach. We are tempted as King David was to set God aside. Those who truly hunger, however, will return and grow wiser. read more
Jesus said when a seed falls to the ground and dies, abundant life emerges. Our soulish nature must similarly die in order to release the spiritual life we have in Christ. read more
Parents cannot control their children's relationship with God or "ownership" of faith. They can, however, provide opportunities and examples to inspire spiritual zeal.
As women, we hold a special place in the heart of our Savior. Jesus came to set us free from the captivity of sin and to heal our broken hearts. His touch is as powerful today as it ever was. read more
We must hold on to hope, knowing that the Christian race is not without hurdles. Those who run with perseverance can have confidence they will see the great things God has ordained for their destiny.
READ: Num. 14:6-9; Josh. 1:1-9; Rom. 5:3-5; Eph. 6:18-20; 2 Tim. 3:10-12; 2 Pet. 1:3-11.
HEART ISSUE: Do you desire to see the great things God has for you? Have you made the choice to persevere? Is anything hindering your hope?
PRAYER FOCUS: Father, thank You for Your plan and purpose for my life. Thank You for not giving up on me, even when I was lost in sin. Please restore my hope and strengthen my ability to believe in You. Amen.
Knowing God's truth and trusting His heart are potent weapons against Satan's deception. Resist the enemy's lies. Be courageous, and persevere.
READ: Ps. 51:6; Is. 60:1-2; John 1:1-5; 1 John 1:5-9; 1 John 5:6-11; Rev. 19:11-13.
HEART ISSUE: What lies about yourself might you be believing right now?
PRAYER FOCUS: Father, thank You for Your truth and for revealing Yourself to me. Uncover the lies I've believed about You and give me eyes to see You as You are. Amen.
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Wings of an Angel Paw Print Necklace
Roll over image to zoom in
Rescue animals? They're our angels! Our angel wing necklace combines your unshakable faith with your love of animals for a spectacular statement of love -- and the power of the paw.
- Silver-tone metal & enamel
- Hand-painted
- Pendant: 1.5" H x 1.25" W (3.8 x 3.2 cm)
Silver-tone chain: 19" L (48.2 cm) with 3" L extender (7.6 cm)
- Imported
For bulk pricing on these and other items, please contact our Customer Service department at firstname.lastname@example.com.
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January 17, 2015 - Lovely Wings of an Angel Paw Print Necklace. It is of good quality and looks great on! The design of angel wings embracing a paw print is just so special.
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A company is able to keep a temporary employee for up to one year as of 2015, according to the U.S. Department of Labor. These appointments, when begun, must have a specific end date in order to qualify.Know More
The use of temporary employees is appropriate when a business has need of an employee or employees to complete a short-term task. They are also used when a company has a specific time of higher volume, or if a company is seasonal. Temporary employees are able to earn paid leave and do qualify for Social Security. However, they are usually not eligible for any of the additional benefits typically offered to full-time employees.Learn more about HR
Employees of a company or institution utilizing the employee self-service platform can use the application with a login and password provided by the employer. The web-based resource allows employees to access personal and employment information, according to the University of Washington.Full Answer >
A C-level employee refers to a high-ranking executive employee within a company or organization. The "C" is an abbreviation of "Chief" and denotes a level of power and influence within an organization. C-level employees are given the ability to make high-stake decisions and earn high salaries compared to other employees.Full Answer >
Wages, work hours, environment and hiring practices are a few aspects of employment subject to employment laws, according to the U.S. Department of Labor. Pregnancy protections, child labor and medical leave are also regulated by law. The DOL and individual state labor agencies propose and enforce employment regulations.Full Answer >
The Family and Medical Leave Act entitles eligible employees of covered employers to take unpaid leave for specified family and medical reasons, states the U.S. Department of Labor. The employer must continue to provide health insurance coverage as if the employee had not taken leave.Full Answer >


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Michael Hill profit slumps
Relevant offers
A tax settlement in Australia has made a dent in the profit of listed jeweller Michael Hill this year.
The company booked a profit after tax of A$25 million (NZ$27.4m), down 22 per cent, for the year to June.
During the year the company paid A$5.99m to resolve a dispute with the Australian Taxation Office arising from an intellectual property transfer in 2008.
Another A$2.31m was paid into a tax pool in relation to an ongoing dispute with Inland Revenue.
Shares in Michael Hill fell 5 cents to $1.25 about noon today.
Morningstar analyst Nachi Moghe said the doubling of Michael Hill's tax bill had clearly had an impact on the result, compounded by "sluggish" sales in its main markets.
"Their trading in New Zealand is going backwards; sales have fallen," he said.
"Australia's also kind of flat on a same-store basis.
"The only thing that's positive for them is Canada, which has gone up quite significantly, but Canada's still quite small."
Despite the fall in profit, the company had a near 10 per cent rise in revenue of A$483.9m.
Operating profit was A$455.2m, up 8.9 per cent, and same-store sales across the group were up 5 per cent.
New Zealand, which provides a fifth of the group's sales, saw same-store sales fall 1.9 per cent and revenue decline 1.5 per cent to NZ$109.6m.
Its operating surplus was virtually flat at NZ$22.1m.
Australia, which accounts for nearly two-thirds of the firm's sales, saw same-store sales edge up 0.8 per cent.
Revenue rose 4.4 per cent to A$302m and operating surplus rose 10 per cent to A$46.7m.
Company chairman Michael Hill said the directors were pleased with the bottomline growth in Australia after difficult trading the year before.
They were also pleased with the recovery of the New Zealand business as a new management team settled in, focusing on improving sales and controlling costs.
Canadian revenue grew 30.4 per cent to C$69m (NZ$74.6m), with an operating surplus of C$3.8m, compared with C$1.1m for the previous corresponding period.
Canadian same-stores sales rose 10 per cent, compared with 1.7 per cent the year before, and the company said it was gaining brand awareness in that market.
Michael Hill continued to test the United States market, where it has eight stores and is targeting the bridal sector.
This was a key reason for its reduced operating cashflow, which was $14.6m from $41.6m the previous year.
In the year ahead, the company said, it would continue to refine its recent investment in inventory management systems and would ramp up its work on selling online.
The flat trading conditions kept Michael Hill's dividend unchanged at NZ6.5c, including a NZ4c final dividend.
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text:
5 von 5 Kunden fanden die folgende Rezension hilfreich
a beginners guide to Shambhala,
Rezension bezieht sich auf: Shambhala: The Sacred Path of the Warrior (Taschenbuch)
Shambhala: The Sacred path of the Warrior is a book I read on whimsy. I read this book originally because of the relationship Trungpa had with Allen Ginsberg. I was curious so I picked up a copy of this book. It was enlightening because this is the real deal unlike a lot of the half baked Zen Buddhism invoked by many beatnik types. One need not drop acid to gain wisdom here. If you want the hokey, trippie hippie Buddhism, forget this book. Trungpa is writing of an ancient code of warriorship. It is an inward, spiritual journey drawn from the Tibetan warrior culture. One who reads this and learns the lessons it teaches will be assisted in overcoming self doubt and negativity. This is not a book of violence. It is really a guide towards overcoming violence. It is about learning mastery over oneself. I was inspired to be better after reading this book. It made me believe in the possibility of transcendence. That is saying something, too. It is a very motivational book.
Helfen Sie anderen Kunden bei der Suche nach den hilfreichsten Rezensionen
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Rezensentin / Rezensent
Top-Rezensenten Rang: 4.360.540


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Ghana's mixed fortune as a dumping ground for e-waste
Return to Kuwait: The class of 1990
Levin has written or co-written nine books, including Beyond Remote-Controlled Childhood (in press); So Sexy So Soon; The War Play Dilemma; and Teaching Young Children in Violent Times. She is a founder of Teachers Resisting Unhealthy Children's Entertainment, Defending the Early Years, and the Campaign for a Commercial-Free Childhood.
Parents and teachers should protect children as much as possible from exposure to commercial culture, argue authors.
27 Apr 2013 10:49 GMT | Poverty & Development, US & Canada, Belgium, Denmark, Greece
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Arts & Culture, Asia Pacific, Japan
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An investigation into the role of one of the most influential banks in the world.
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We investigate why the Baltic states of Latvia, Estonia and Lithuania are nervous about Russia's regional ambitions.
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I could never understand holodetzz, not now, not when I was a kid.
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Elizabeth Inn Freeport
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- Continental Breakfast
- Banquet room
- Smoking rooms available
- Room service
- High-speed internet in room
- Refrigerator in room
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Friday Jun 12 Springfield
... and 64 Cuda, The owner Steve was real nice and gave us a tour. Dave P had a lot of questions about working metal and the English wheel. Steve showed us his English wheel and all the modifications he has done to it. It was the same model Dave has. Steve also gave Dave some pointers on shaping metal. Great find! today was a 208 mile day with only one U-turn. Slow day! I also started out hot and then as we drove north it cooled off. Good day. Steve can I mention ...
"Give Thanks with a Grateful Heart" - Thanksgiving
... who only occasionally get together were enjoying being together. It was much like Christmas without the Christmas tree, gifts & religious observance. One of the young cousins led the grace & thanksgiving and the meal got under way at close to 7.30pm. Most people in America have trouble initially with Max's accent but when in the South even more so, and us with their accents. But we knew a number of the people there and had a great night. Our next and 'real' ...
Rolling Ridge Friends
More later as internet connections not too good. Pictures won't upload yet so stay tuned. . .
After packing the coach Friday and Saturday, we hitched up the Escape and headed west. I have included a picture taken by my friend Jim Tschantz. I can't say I don't do windows any more. It was an uneventful trip through Grand Rapids, past Holland and Benton Harbor into Indiana. Being Sunday, traffic was light and road construction ...
Owner of drive-in theater gave us a personal tour!
... at their theater. It seems he had gone to school in Mass and was anxious to talk to folks from the area about changes since he had been there.
He came to our RV several times during the 1st movie (it was a double feature) to offer us to move up closer and some other niceties.
At intermission, he came to talk about Mass. and we asked him if he was a manager there and he proceeds to explain to us that he is the owner of ...
Day 2: Chicago
... chilled all night not doing much! :) Tomorrow looks like we'll spend the day driving through the country side. We're trying to knock out a lot of driving this first week though corn country and then spend more time when the scenery gets becomes something a bit more interesting then the endless corn fields. Goodnight from Lena! Xo (Pics to come, as I don't have any on the iPad!) ...


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Vegan Soul Food Truck Rolls Out in Washington DC
The nation's capital city can expect cruelty-free comfort cuisine from the mobile eatery, Woodlands Vegan Bistro.
Washington DC residents will be able to get faux fried chicken on-the-go with the launch of the soul food restaurant Everlasting Life Café's new food truck, Woodlands Vegan Bistro. According to the Washington Post, the truck's owners Vernon and Mickiyah Woodland reported that the mobile menu will rotate regularly, but they also may serve the brick and mortar establishment's popular comfort classics, such as the "Chick'n" Sandwich and macaroni and cheese, along with healthful sides and beverages such as kale salad, juices, and smoothies. The news source notes that one of Woodland's greatest appeals, besides the food itself, are the large portions that could "rival a Thanksgiving dinner."
Photo credit: Washington Post
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Sussex 214 & 15-2 Durham 301 (Durham lead by 72 runs): Benkenstein and Smith give Sussex a headache
Sunday 01 June 2008
In mid-afternoon yesterday Durham lost their sixth wicket with the score on 235. There was immediately some speculation about whether they had compiled one of the lowest totals of all time to include a double-century partnership, a discussion which gathered momentum at 267 for 9.
This was delightful evidence of the game's perennial ability to provide statistical gems. The stand which led to it was delightful too, containing as it did two thoroughly pleasing innings.
Both Dale Benkenstein and Will Smith scored their first hundreds of the season. If Benkenstein's was the more comfortable and predictable, Smith's was the more important, coming as it did in his first championship match since last July.
They came together with last year's runners-up in a spot of bother at 11 for 4 against the champions. They effected a significant recovery which allowed an important lead, the sunshine having removed the demons from the moist pitch of the previous morning.
It was not quite chanceless and Durham would have been right in it had Carl Hopkinson not spilled a straightforward offering at first slip off Corey Collymore when Smith was but five.
Smith was no doubt helped by the presence of his captain, Benkenstein who is a commanding figure, utterly instrumental in Durham becoming a force in the land. The meagre nine fours contained in his innings did not reflect his assertiveness.
Smith is probably drinking in the last chance saloon. Dropped mid-season in 2007, this was his first championship hundred for Durham, his fourth in all.
On this evidence Sussex may struggle to retain their title. Their slip catching was aberrant throughout and there were signs that Mushtaq Ahmed, who took his 1,400th first-class wicket, is not in the best of order. Having conceded a deficit of 87, they were 15 for 2 by the close, with Stephen Harmison bowling like the wind again.
Harmison had already helped Durham extend the lead, sharing a lively last-wicket stand of 34 with his brother, Ben, that must have irritated Sussex as much as it did those fond of numerical nuggets. For the record, Benkenstein and Smith added 205, the rest contributed 96.
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Transcript of "Fe"
1. Ammonia Synthesis Promoted by Iron Catalysts Literature Report Sandra Bencic Department of Chemistry Michigan State University April, 2001
1. Introduction to Promoted Synthesis of Ammonia Synthesis of ammonia is the most important industrial process for isolation of nitrogen as well as further production of nitrogen compounds of vital importance (urea, nitric acid and fertilizers). This process is nearly a hundred years old, discovered in the beginning of the 20th century by Fritz Haber and developed for industrial production by Carl Bosch. [1] The reaction between gaseous N2 and H2 (N2 + 3H2 _ 2NH3) is exothermic, carried out at high pressures and temperatures and occurs with large yields when iron catalysts are present. The iron catalyst consists of reduced magnetite ore (Fe3O4) which is enriched ("promoted") most frequently with Al- and K- (or Ca, Mg, Si)-oxides while its optimal performance requires reaction temperatures around 400ºC and pressures from 150-300 atmospheres. [2, 3] Being a transition metal with partially occupied d-bands iron represents a surface suitable for adsorption and dissociation of N2 molecules. Because of extremely high importance of this catalytic process, surfaces of iron catalysts are objects of extended surface studies through various techniques. Chemical, structural and kinetic information can be obtained using Auger Electron Spectroscopy (AES), [4, 5, 6, 7, 8, 9, 10] Low-Energy Electron Diffraction (LEED), [11] Temperature-Programmed Desorption (TPD), [6, 11] X-ray Photoelectron Spectroscopy (XPS), [8] Extended X-ray Absorption Fine Stucture (EXAFS), [12] Scanning Electron Microscopy coupled with Energy Dispersive X-ray Spectroscopy (SEM/EDX), [12] Secondary Ion Mass Spectrometry (SIMS) [8] and others. Theoretical models of catalyst surfaces provide different explanations of the process that is still not entirely understood. [13] Studies of catalytic processes are difficult mainly because of pressure and temperature differences between synthesis and study conditions, since synthesis occurs at high temperatures and pressures, while characterization of surfaces needs an UHV environment. Studies of ammonia synthesis on iron catalysts require specially designed chambers and often inspection of surfaces of industrial catalysts occurs. Nevertheless, conditions at which catalytic surfaces are studied are still far from the industrial ones. [4] Following examples yield basic and recent information on surface structures as well as reaction mechanism and kinetics on pure and promoted catalysts. 2
2. Iron Catalyst Surface Properties 2.1. Effect of Surface Orientation on Activity of Iron Catalysts Catalysis for ammonia synthesis was studied on various surface planes of iron crystals with body centered cubic (bcc) conformation and the reaction rate was found to be dependent on orientation of crystals. [2] Spencer et al. intensively studied iron catalysts and found the ratio of reaction rates for ammonia formation at 798 K and 20 atm to be 418:25:1 on Fe(111), Fe(100) and Fe(110) surfaces, respectively. Ammonia formed at a rate of 4.6 ×10-8 moles cm-2 s-1 on Fe(111) face, with activation energy for nitrogen adsorption of 19.4 kcal mole-1. [5] Studies showed that the most active planes on iron catalysts are (111) and (211), while over (100), (110) and (210) planes, the kinetic rates for ammonia synthesis are lower (Fig. 1) [14]. The catalysis experiment was done in a high-pressure cell where synthesis occurred. The generation of ammonia was monitored with a Photoionization Detector (PID), surfaces were analyzed with LEED for structure information, and AES before and after the process, by connecting a UHV chamber to the system. Figure 1: Rates of ammonia formation over iron crystal surfaces with orientations (111), (211), (100), (210) and (110) [14] 3
The reason for variation in catalytic activities at different surfaces was first believed to be the surface roughness and openness. Iron surfaces with the lowest roughness (as shown in Figure 2) and high work functions, Fe(110) and Fe(100), experimentally and theoretically represent surfaces with low catalytic activity. [14] Fe(111) face and Fe(210) face exhibit the highest roughness, associated to high surface free energy and low work function. Fe(111) crystal plane is indeed considered to be the most active clean surface for ammonia catalysis. Fe bcc(111) face Fe bcc(100) face Fe bcc(110) face Fe bcc(211) face Fe bcc(210) face Figure 2: Schemes of iron crystal surfaces with different orientations, showing surface roughness and C7 sites; adapted from [14] Nevertheless, Somorjai [14] proved that rather than roughness, high coordination of sites might be the characteristic that denotes the strength of nitrogen adsorption and kinetics of dissociation, determining the rate of ammonia synthesis. In fact, Fe(211) surfaces are as active as Fe(111) surfaces, but not as rough and open. Both Fe(211) and Fe(111) faces 4
have in common the presence of highly coordinated C7 sites, most likely related to larger electronic fluctuations within the solid and therefore ideal sites for adsorption of nitrogen. On the other hand, Fe(210) surfaces are open, exposing third layer atoms, and they are rough and could be as active as Fe(111) surfaces , but do not contain C7 sites, as seen in Fig. 2. It is experimentally demonstrated that Fe(210) surfaces are not as active as Fe(111) and Fe(211) surfaces. The increased catalytic activity is therefore mostly due to the presence of C7 sites, the most highly coordinated sites in iron crystal. Therefore, they are the ones that provide the strongest adsorption and fastest dissociation of nitrogen on the catalyst surface. 2.2 Dissociative Nitrogen Adsorption as Rate-Determining Step The mechanism for iron-catalyzed ammonia synthesis is stated below in three dominant reaction steps [15]: N2(ads) _ 2N(ads) (1) N(ads) + H(ads) _ NH(ads) (2) NH3(ads) _ NH3(g) (3) It is believed that the overall reaction rate of ammonia synthesis is determined by dissociation of nitrogen adsorbed on catalyst surface in reaction (1). Most of the studies confirm this fact, although there is evidence of experiments performed at higher pressures, suggesting the step (2) to be the rate-determining one. [15] AES analysis of nitrogen residues on surface at high atmospheric pressures confirms high coverage of N(ads) on the surface, which implies that the dissociation of N2(ads) might not be the rate-determining step (in this case, we would expect a higher coverage of N2(ads) during synthesis). TPD data indicated that two forms of nitrogen were present on the surface during synthesis, as observed in two nitrogen desorption peaks that correspond to N2(ads) at 120 K and N(ads) at 800-820 K. [16] Inspection of surfaces of working catalyst also showed that nitrogen is mostly present in its dissociated form, N(ads). [2] Ertl [6] reported a possible explanation for binding of molecular nitrogen on iron, defining it as M-N-N "end-on" configuration. Here, the stabilization of N2 on iron is due 5
to σ-donor coupling to the metal and π-backbonding of iron d-electrons with the 2π* lowest empty orbital in N2. The extent of N2(ads) coverage on Fe surfaces can be followed at elevated temperatures using AES. [2] Slopes of curves representing variation in surface concentration with N2 exposure can be used for obtaining sticking coefficients for dissociative chemisorption of nitrogen. Sticking coefficients are calculated from the Arrhenius equation, s = A exp (-∆E*/RT), where s, A, ∆E* and T represent the sticking coefficient, preexponential factor, activation energy (for the process N2 → 2N) and temperature, respectively. The sticking coefficients for atomic nitrogen on different Fe catalyst faces increase in order Fe(110) < Fe(100) < Fe(111), demonstrating that Fe(111) surfaces are the ones to assure the highest adsorption energy for N2, and the smallest activation energy for dissociation of N2(ads) to N(ads) (Fig. 3). Figure 3: Dependence of relative surface concentration of adsorbed nitrogen on N2 exposure, measured on Fe(111), Fe(100) and Fe(110) surfaces. [2] 6
2.3. Effect of Iron Promoters Although pure Fe(111) and (211) surfaces assure the most suitable conditions for N2 adsorption and dissociation and thus the highest rate for ammonia synthesis, the performance of most other surface planes is not satisfactory. Increased catalytic activity of these surfaces can be achieved with addition of promoter elements. They can be electron donors as potassium, which increases the reaction rate by altering the steadystate concentration of intermediates. Another type of promoters added to iron catalysts are Al-oxide or Ca-oxide, texture promoters, known to stabilize the particle size and increase the surface area of the catalyst. [3] Figure 4: TPD spectra of ammonia desorption form (a) pure iron catalyst surfaces and (b) surfaces promoted with AlxOy/vapor [11] Fe(111) surface barely changes in catalytic performance after addition of AlxOy followed by water vapor pretreatment. [11] Fe(100) and Fe(110) surfaces, rather inactive in pure form, drastically improve in activity when exposed to the same treatment. The 7
explanation for this phenomena is once again formation of C7 sites on Fe(100) and Fe(110) planes due to surface restructuring that occurs during AlxOy/vapor pretreatment. TPD results confirm the fact that restructuring occurs on Fe(100) and Fe(110) surfaces. When monitoring desorption of ammonia from pure single crystal surfaces, Strongin et al. [14] observed three peaks. β1, β2 and β3 ammonia desorption peaks with maxima at 495 K, 568 K and 676 K were found on Fe(111) pure surface. Only β3 desorption peak was seen on Fe(100) and Fe(110) surfaces. Once the surfaces were promoted with AlxOy, the β1 and β2 peaks showed also in desorption from both restructured planes, Fe(100) and Fe(110) (Fig. 5), which now contained active C7 sites. Figure 5: Thermal desorption spectra for N2 from Fe(111) covered with (a) 0.55×1014, (b) 1.5×1014 and (c) 3.5×1014 K atoms cm-2. [6] Ertl [6] compared rates for ammonia synthesis on K-promoted Fe(111) and Fe(100) surfaces, using TPD. He discovered that because of the presence of potassium, an increase in electron density of the substrate induces a local increase in adsorption energy for N2 and a decrease in activation energy needed for its dissociation. In Ertl's experiment, catalyst surfaces were saturated with N2 at 120 K and TPD spectra were recorded during programmed temperature increase. A peak attributed to N2(ads) thermal desorption was observed at 160 K (α1), while an additional peak in TPD spectra was found from the desorption process of N(ads) (α2) at 210 K. The intensity of α2 peak increased with an increase in K concentration on the surface, and at the same time, the α1 peak intensity decreased, as shown in Fig. 5. Similarly, the intensity increase for α2 and a decrease for α1 were observed upon addition of K on Fe(100) surface. Silverman and Boudart [7] inspected promoted catalyst surfaces with quantitative AES. Using a calculation for obtaining concentrations of iron promoters from Auger current, they obtained a complete composition of surface fractions. They also monitored CO chemisorption on iron surface. CO is isoelectric with N 2 and adsorbs on Fe and K2O but it 8
does not adsorb on Al2O3, where only N2 physisorption occurs. Using this approach one can obtain the composition of different surface fragments. The authors deducted that in a fused iron catalyst, the surface is covered with K2O and CaO promoter oxides. Pure Fe islands were present, surrounded by Al2O3 which was found to be lying below the K2O. 3. Microstructure, Morphology Information and Models of Iron Catalysts From the beginning of the 80's until recently, several studies tried to correlate the composition of iron catalyst surfaces with the morphology on a micron scale. [7, 8, 9, 12] The latest publications try to combine all the surface information gathered and model promoted iron catalyst surfaces for a thorough explanation of the catalytic process. [13] Ertl and Prigge [8] imaged iron surfaces with SEM and AES Secondary Electron Distribution (SED) Mapping for determining composition and topography of industrial synthesis catalyst before and after its reduction (activation of the surface). SEM images of a specific area were taken and compared with elemental composition maps. As shown in Table 1, the unreduced catalyst surface consisted of mostly K and O while iron was nearly absent, since covered by the oxide layer. There were only small quantities of Al and Ca found on the surface. Compared to the bulk, iron catalyst surface was enriched with K that was not dissolved in the magnetite crystals, but segregated on grain boundaries. After reduction treatment with H2 + N 2 (3:1) mixture at 500 Torr and 720 K, magnetite (Fe 2O3) was completely reduced to elemental iron. The total surface area was increased due to the presence of segregated Al2O3 that had been dissolved in the magnetite lattice before reduction. Additionally, the surface exhibited smaller uniform pores resulting in an increase in porosity and internal surface area caused by Al2O3. The gain in the free Fe surface was thus assigned as a cause for increased catalyst activity. On the other hand, potassium, responsible for the increase in the rate of nitrogen dissociation, was uniformly distributed on about 30% of the surface. The most plausible explanation for potassium activity was that K + O form a monoatomic layer on top of the Fe substrate. 9
Table 1: Elemental composition of unreduced and reduced catalyst measured with XPS and AES (on various spots on the surface). [8] Fig. 6 shows Auger maps (b, c, d, e, f) of reduced catalyst surface analyzed and showed in a secondary electron image (a). The K coverage is rather uniformly distributed on Fe and this surface exhibits a low Al content. The rest of the surface is quite evenly covered with Al, which is believed to be insoluble in the bulk because of the reduction of magnetite to pure Fe. Similar chemical and morphological trend was observed in SEM/EDS study of real catalyst surfaces done by Weinberg et al. [12] (a) unreduced catalyst (b) reduced catalyst 10
(c) Fe (d) Al (e) K (f) Ca Figure 6: Secondary electron distribution (SED) image of the unreduced (a) and the reduced catalyst (b) with Auger maps for Fe (c), Al (d), K (e) and Ca (f) compositions. [8] Recently, a new model for the promoted iron catalyst surface was presented and explained in detail by Arabczyk [13], taking in account most of the studies and discoveries about iron catalysts discussed in the past. He proposed a double-layer model of promoter oxides on the surface of iron catalyst. The first layer consists of oxygen atoms and adsorption sites for nitrogen dissociation. Since oxygen covers the pure iron surface, the formation of Fe-O bonds increases its surface free energy and the surface roughness. When the surface is covered by oxygen, there are less active sites available. Arabczyk claims that oxygen atoms are necessary for stabilization of promoter atoms 11
(alkali and earth alkali metals) on surface, [10] where K, Ca and Al are compensated and stabilized with 1, 2 or 3 oxygen atoms, respectively. Since the number of oxygen atoms on surface denotes the amount of surface area, the presence of Ca and Al atoms that need more oxygen for compensation implies the presence of a larger surface area, thus a larger roughness. Model calculations for structures of promoter atoms on the iron surface (that took in account the above assumptions) suggest that 50-60% of the sites are occupied by oxygen and 40-50% of the sites can be free for nitrogen adsorption and ammonia synthesis. On the other hand, the presence of aluminum on the surface is crucial for compensation of oxygen and increase of surface energy and surface area. It is also believed that after activation (reduction) of the catalyst, FeAl2O4 forms on the surface that allows growth of an adlayer of the most active Fe(111) surface. On the other hand, the addition of potassium causes a decrease in surface area, but at the same time an increase in the number of free adsorption sites. Equilibrium is maintained between the surface, bulk and the spacers located between iron crystallites. A scheme of the model surface described above clearly shows the presence of the double layer of oxygen and promoter atoms (Fig.7a) and the presence of adsorption sites on the iron catalyst (Fig. 7b). (a) (b) 12
Figure 7: Schematic of a promoted iron catalyst surface: (a) side view and (b) top view showing free adsorption sites. [13] 4. Summary Although promoted iron catalysis for ammonia synthesis is still not entirely understood, there is strong evidence about structure and possible functioning mechanisms. The ratedetermining step for ammonia synthesis is most likely the adsorption and dissociation of nitrogen on the catalyst surface. Pure iron catalyst form is active only in the Fe(111) and Fe(211) conformations because of the presence of highly coordinated C7 sites that provide the strongest adsorption for nitrogen. The addition of Al, K and Ca promoter atoms drastically increases the activity of other Fe planes. It is believed that potassium acts as an electron donor that increases the electron density and thus provides a higher number of active sites on the surface. The presence of aluminum influences the morphology of the catalyst, increasing its porosity and free surface area. Since iron aluminate (FeAl2O4) is formed during the activation of the surface and allows growth of a Fe(111) adlayer, the catalytic activity increases additionally. A model of promoted iron catalyst takes all of the research efforts in account. It introduces a double layer structure on iron surface, active because of increase in surface free area due to oxygen compensated with aluminum atoms in the first layer, together with the increase of free adsorption sites because of potassium presence in the overlayer. In despite of the intense and thorough studies performed since the discovery of ammonia catalyzed formation, the function of promoted iron surfaces is still not completely understood. Future experiments will most likely focus on studies of real catalyst crystals with catalytic history and efforts will be made for exploitation of these processes in a high vacuum and high temperature system, representing actual experimental conditions. 5. Literature 13
[1] http://www.agcentral.com/imcdemo/05Nitrogen/05-10.htm [2] Somorjai G.A., Introduction to Surface Chemistry and Catalysis, Wiley, New York, 1994. [3] Somorjai G.A., Chemistry in Two Dimensions: Surfaces, Cornell University Press, Ithaca and New York, 1981. [4] Arabczyk W., Kalucki K., Narkiewicz U., Moszynski D., Morawski A.W. Proceedings of the 12th International Congress on Catalysis 2000, 130, 3112. [5] Spencer N.D., Schoonmaker R.C., Somorjai G.A. Journal of Catalysis 1982, 74, 129. [6] Ertl G., Lee S.B., Weiss M. Surface Science 1982, 114, 527. [7] Silverman D.C., Boudart M. Journal of Catalysis 1982, 77, 208. [8] Ertl G., Prigge D., Schloegl R., Weiss M. Journal of Catalysis 1983, 79, 359. [9] Lendizon-Bielun Z., Arabczyk W. Applied Catalysys A 2001, 207, 37. [10] Arabczyk W., Narkiewicz U., Kalucki K. Vacuum 1994, 45, 267. [11] Strongin D.R., Bare S.R., Somorjai G.A. Journal of Catalysis 1987, 103, 289. [12] Weinberg G., Beran B., Muhler M., Schlogl R., Dent A., Rayment T. Applied Catalysis A 1997, 163, 83. [13] Arabczyk W., Narkiewics U., Moszynski D. Langmuir 1999, 15, 5785. [14] Strongin D.R., Carrazza J., Bare S.R., Somorjai G.A. Journal of Catalysis 1987, 103, 213. [15] Spencer M.S. Catalysis Letters 1992, 13, 45. [16] Vandervell H.D, Vaugh K.C. Chemical Physics Letters 1990, 171,462. 14


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USDA Releases Crop Report; Ethanol to Soar
Aug. 10 (Bloomberg) -- Corn production in the U.S., the world's largest grower and exporter, will drop 13 percent to a six-year low after the hottest July since 1936 damaged Midwest fields, the government said. Alan Bjerga reports on Bloomberg Television's "Bottom Line." (Source: Bloomberg)
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31:36 - Homebrew VC Partner Hunter Walk, Technalysis Founder Bob O'Donnell and IDC Chief Research Officer Crawford Del Prete discuss Apple to unveil a new TV box this fall and the future of Apple's streaming service. They speak with Bloomberg's Emily Chang on "Bloomberg West." (Source: Bloomberg)


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From Roc-A-Fella Records to Roc Nation
Roc-A-Fella Records was born out of a partnership between then rising mogul Damon Dash and a young Jay Z, who was being rejected by the major labels. The two decided to release independently and sign their own artists. After years of success, Hov's relationship with Dash became strained, and it was agreed without Dash's knowledge that the label would be sold to Def Jam for $10 million. Jay became president of Def Jam (for a brief stint before resigning). Dash attempted to reclaim the Roc brand with Roc4Life under Def Jam (but to no avail). And, in 2008, Jay singed a $150 million deal with Live Nation, including funds to cover overhead of what is now known as Roc Nation, which boasts management of the likes of J. Cole, Rihanna and Wale.
(Photos from left: Roc Nation, Roc-a-Fella Records)
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